Sample records for oils biomass-derived fischer-tropsch

  1. Determination of the Effect of Coal/Biomass-Derived Syngas Contaminants on the Performance of Fischer-Tropsch and Water-Gas-Shift Catalysts

    SciTech Connect (OSTI)

    Trembly, Jason; Cooper, Matthew; Farmer, Justin; Turk, Brian; Gupta, Raghubir

    2010-12-31T23:59:59.000Z

    Today, nearly all liquid fuels and commodity chemicals are produced from non-renewable resources such as crude oil and natural gas. Because of increasing scrutiny of carbon dioxide (CO{sub 2}) emissions produced using traditional fossil-fuel resources, the utilization of alternative feedstocks for the production of power, hydrogen, value-added chemicals, and high-quality hydrocarbon fuels such as diesel and substitute natural gas (SNG) is critical to meeting the rapidly growing energy needs of modern society. Coal and biomass are particularly attractive as alternative feedstocks because of the abundant reserves of these resources worldwide. The strategy of co-gasification of coal/biomass (CB) mixtures to produce syngas for synthesis of Fischer-Tropsch (FT) fuels offers distinct advantages over gasification of either coal or biomass alone. Co-feeding coal with biomass offers the opportunity to exploit economies of scale that are difficult to achieve in biomass gasification, while the addition of biomass to the coal gasifier feed leverages proven coal gasification technology and allows CO{sub 2} credit benefits. Syngas generated from CB mixtures will have a unique contaminant composition because coal and biomass possess different concentrations and types of contaminants, and the final syngas composition is also strongly influenced by the gasification technology used. Syngas cleanup for gasification of CB mixtures will need to address this unique contaminant composition to support downstream processing and equipment. To investigate the impact of CB gasification on the production of transportation fuels by FT synthesis, RTI International conducted thermodynamic studies to identify trace contaminants that will react with water-gas-shift and FT catalysts and built several automated microreactor systems to investigate the effect of single components and the synergistic effects of multiple contaminants on water-gas-shift and FT catalyst performance. The contaminants investigated were sodium chloride (NaCl), potassium chloride (KCl), hydrogen sulfide (H{sub 2}S), carbonyl sulfide (COS), ammonia (NH{sub 3}), and combinations thereof. This report details the thermodynamic studies and the individual and multi-contaminant results from this testing program.

  2. Impact of Contaminants Present in Coal-Biomass Derived Synthesis Gas on Water-gas Shift and Fischer-Tropsch Synthesis Catalysts

    SciTech Connect (OSTI)

    Gokhan Alptekin

    2012-09-30T23:59:59.000Z

    Co-gasification of biomass and coal in large-scale, Integrated Gasification Combined Cycle (IGCC) plants increases the efficiency and reduces the environmental impact of making synthesis gas ("syngas") that can be used in Coal-Biomass-to-Liquids (CBTL) processes for producing transportation fuels. However, the water-gas shift (WGS) and Fischer-Tropsch synthesis (FTS) catalysts used in these processes may be poisoned by multiple contaminants found in coal-biomass derived syngas; sulfur species, trace toxic metals, halides, nitrogen species, the vapors of alkali metals and their salts (e.g., KCl and NaCl), ammonia, and phosphorous. Thus, it is essential to develop a fundamental understanding of poisoning/inhibition mechanisms before investing in the development of any costly mitigation technologies. We therefore investigated the impact of potential contaminants (H{sub 2}S, NH{sub 3}, HCN, AsH{sub 3}, PH{sub 3}, HCl, NaCl, KCl, AS{sub 3}, NH{sub 4}NO{sub 3}, NH{sub 4}OH, KNO{sub 3}, HBr, HF, and HNO{sub 3}) on the performance and lifetime of commercially available and generic (prepared in-house) WGS and FT catalysts; ferrochrome-based high-temperature WGS catalyst (HT-WGS, Shiftmax 120�, Süd-Chemie), low-temperature Cu/ZnO-based WGS catalyst (LT-WGS, Shiftmax 230�, Süd-Chemie), and iron- and cobalt-based Fischer-Trospch synthesis catalysts (Fe-FT & Co-FT, UK-CAER). In this project, TDA Research, Inc. collaborated with a team at the University of Kentucky Center for Applied Energy Research (UK-CAER) led by Dr. Burt Davis. We first conducted a detailed thermodynamic analysis. The three primary mechanisms whereby the contaminants may deactivate the catalyst are condensation, deposition, and reaction. AsH{sub 3}, PH{sub 3}, H{sub 2}S, HCl, NH{sub 3} and HCN were found to have a major impact on the Fe-FT catalyst by producing reaction products, while NaCl, KCl and PH{sub 3} produce trace amounts of deposition products. The impact of the contaminants on the activity, selectivity, and deactivation rates (lifetime) of the catalysts was determined in bench-scale tests. Most of the contaminants appeared to adsorb onto (or react with) the HT- and LT-WGS catalysts were they were co-fed with the syngas: � 4.5 ppmv AsH{sub 3} or 1 ppmv PH{sub 3} in the syngas impacted the selectivity and CO conversion of both catalysts; � H{sub 2}S slowly degraded both WGS catalysts; - A binary mixture of H{sub 2}S (60 ppmv) and NH{sub 3} (38 ppmv) impacted the activity of the LT-WGS catalyst, but not the HT-WGS catalyst � Moderate levels of NH{sub 3} (100 ppmv) or HCN (10 ppmv) had no impact � NaCl or KCl had essentially no effect on the HT-WGS catalyst, but the activity of the LT-WGS catalyst decreased very slowly Long-term experiments on the Co-FT catalyst at 260 and 270 °C showed that all of the contaminants impacted it to some extent with the exception of NaCl and HF. Irrespective of its source (e.g., NH{sub 3}, KNO{sub 3}, or HNO{sub 3}), ammonia suppressed the activity of the Co-FT catalyst to a moderate degree. There was essentially no impact the Fe-FT catalyst when up to 100 ppmw halide compounds (NaCl and KCl), or up to 40 ppmw alkali bicarbonates (NaHCO{sub 3} and KHCO{sub 3}). After testing, BET analysis showed that the surface areas, and pore volumes and diameters of both WGS catalysts decreased during both single and binary H2S and NH3 tests, which was attributed to sintering and pore filling by the impurities. The HT-WGS catalyst was evaluated with XRD after testing in syngas that contained 1 ppmv PH{sub 3}, or 2 ppmv H{sub 2}S, or both H{sub 2}S (60 ppmv) and NH{sub 3} (38 ppmv). The peaks became sharper during testing, which was indicative of crystal growth and sintering, but no new phases were detected. After LT-WGS tests (3-33 ppmv NH{sub 3} and/or 0-88 ppmv H{sub 2}S) there were a few new phases that appeared, including sulfides. The fresh Fe-FT catalyst was nanocrystalline and amorphous. ICP-AA spectroscopy and other methods (e.g., chromatography) were used to analyze for

  3. Fischer-Tropsch process

    DOE Patents [OSTI]

    Dyer, Paul N. (Allentown, PA); Pierantozzi, Ronald (Orefield, PA); Withers, Howard P. (Douglassville, PA)

    1987-01-01T23:59:59.000Z

    A Fischer-Tropsch process utilizing a product selective and stable catalyst by which synthesis gas, particularly carbon-monoxide rich synthesis gas is selectively converted to higher hydrocarbons of relatively narrow carbon number range is disclosed. In general, the selective and notably stable catalyst, consist of an inert carrier first treated with a Group IV B metal compound (such as zirconium or titanium), preferably an alkoxide compound, and subsequently treated with an organic compound of a Fischer-Tropsch metal catalyst, such as cobalt, iron or ruthenium carbonyl. Reactions with air and water and calcination are specifically avoided in the catalyst preparation procedure.

  4. Process for upgrading wax from Fischer-Tropsch synthesis

    DOE Patents [OSTI]

    Derr, W.R. Jr.; Garwood, W.E.; Kuo, J.C.; Leib, T.M.; Nace, D.M.; Tabak, S.A.

    1987-08-04T23:59:59.000Z

    The waxy liquid phase of an oil suspension of Fischer-Tropsch catalyst containing dissolved wax is separated out and the wax is converted by hydrocracking, dewaxing or by catalytic cracking with a low activity catalyst to provide a highly olefinic product which may be further converted to premium quality gasoline and/or distillate fuel. 2 figs.

  5. Process for upgrading wax from Fischer-Tropsch synthesis

    DOE Patents [OSTI]

    Derr, Jr., W. Rodman (Vincentown, NJ); Garwood, William E. (Haddonfield, NJ); Kuo, James C. (Cherry Hill, NJ); Leib, Tiberiu M. (Voorhees, NJ); Nace, Donald M. (Woodbury, NJ); Tabak, Samuel A. (Wenonah, NJ)

    1987-01-01T23:59:59.000Z

    The waxy liquid phase of an oil suspension of Fischer-Tropsch catalyst containing dissolved wax is separated out and the wax is converted by hydrocracking, dewaxing or by catalytic cracking with a low activity catalyst to provide a highly olefinic product which may be further converted to premium quality gasoline and/or distillate fuel.

  6. Fischer-Tropsch wax characterization and upgrading: Final report

    SciTech Connect (OSTI)

    Shah, P.P.; Sturtevant, G.C.; Gregor, J.H.; Humbach, M.J.; Padrta, F.G.; Steigleder, K.Z.

    1988-06-06T23:59:59.000Z

    The characterization and upgrading of Fischer-Tropsch wax was studied. The focus of the program was to maximize the yield of marketable transportation fuels from the Fischer-Tropsch process. The wax was characterized using gel permeation chromatography (GPC), high resolution mass spectrometry (HRMS), infrared spectroscopy (IR), gas chromatography (GC), nuclear magnetic resonance (NMR) and various other physical analyses. Hydrocracking studies conducted in a pilot plant indicate that Fischer-Tropsch wax is an excellent feedstock. A high yield of excellent quality diesel fuel was produced with satisfactory catalyst performance at relatively mild operating conditions. Correlations for predicting key diesel fuel properties were developed and checked against actual laboratory blend data. The blending study was incorporated into an economic evaluation. Finally, it is possible to take advantage of the high quality of the Fischer-Tropsch derived distillate by blending a lower value light cycle oil (produced from a refinery FCC unit) representing a high aromatic and low cetane number. The blended stream meets diesel pool specifications (up to 60 wt % LCO addition). The value added to this blending stream further enhances the upgrading complex return. 22 refs., 39 figs., 48 tabs.

  7. Platinum-Modulated Cobalt Nanocatalysts for Low-Temperature Aqueous-Phase Fischer Tropsch Synthesis

    SciTech Connect (OSTI)

    Wang, Hang [Peking University; Zhou, Wu [ORNL; Liu, JinXun [Dalian Institute of Chemical Physics; Si, Rui [Brookhaven National Laboratory (BNL); Sun, Geng [Peking University; Zhong, Mengqi [Peking University; Su, Haiyan [Peking University; Zhao, Huabo [Peking University; Rodrigues, Jose [Brookhaven National Laboratory (BNL); Pennycook, Stephen J [ORNL; Idrobo Tapia, Juan C [ORNL; Li, Weixue [Dalian Institute of Chemical Physics; Kou, Yuan [Peking University; Ma, Ding [Peking University

    2013-01-01T23:59:59.000Z

    Fischer Tropsch synthesis (FTS) is an important catalytic process for liquid fuel generation, which converts coal/shale gas/biomass-derived syngas (a mixture of CO and H2) to oil. While FTS is thermodynamically favored at low temperature, it is desirable to develop a new catalytic system that could allow working at a relatively low reaction temperature. In this article, we present a one-step hydrogenation reduction route for the synthesis of Pt Co nanoparticles (NPs) which were found to be excellent catalysts for aqueous-phase FTS at 433 K. Coupling with atomic-resolution scanning transmission electron microscopy (STEM) and theoretical calculations, the outstanding activity is rationalized by the formation of Co overlayer structures on Pt NPs or Pt Co alloy NPs. The improved energetics and kinetics from the change of the transition states imposed by the lattice mismatch between the two metals are concluded to be the key factors responsible for the dramatically improved FTS performance.

  8. Moderated ruthenium fischer-tropsch synthesis catalyst

    DOE Patents [OSTI]

    Abrevaya, Hayim (Wilmette, IL)

    1991-01-01T23:59:59.000Z

    The subject Fischer-Tropsch catalyst comprises moderated ruthenium on an inorganic oxide support. The preferred moderator is silicon. Preferably the moderator is effectively positioned in relationship to ruthenium particles through simultaneous placement on the support using reverse micelle impregnation.

  9. Fischer-Tropsch Wastewater Utilization

    DOE Patents [OSTI]

    Shah, Lalit S. (Sugar Land, TX)

    2003-03-18T23:59:59.000Z

    The present invention is generally directed to handling the wastewater, or condensate, from a hydrocarbon synthesis reactor. More particularly, the present invention provides a process wherein the wastewater of a hydrocarbon synthesis reactor, such as a Fischer-Tropsch reactor, is sent to a gasifier and subsequently reacted with steam and oxygen at high temperatures and pressures so as to produce synthesis gas. The wastewater may also be recycled back to a slurry preparation stage, where solid combustible organic materials are pulverized and mixed with process water and the wastewater to form a slurry, after which the slurry fed to a gasifier where it is reacted with steam and oxygen at high temperatures and pressures so as to produce synthesis gas.

  10. Effect of surface modification by chelating agents on Fischer-Tropsch performance of Co/SiO2 catalysts

    SciTech Connect (OSTI)

    Bambal, Ashish S. [WVU; Kyugler, Edwin L. [WVU; Gardner, Todd H. [U.S. DOE; Dadyburjor, Dady B. [WVU

    2013-01-01T23:59:59.000Z

    The silica support of a Co-based catalyst for Fischer?Tropsch (FT) synthesis was modified by the chelating agents (CAs) nitrilotriacetic acid (NTA) and ethylenediaminetetraacetic acid (EDTA). After the modification, characterization of the fresh and spent catalysts shows reduced crystallite sizes, a better-dispersed Co3O4 phase on the calcined samples, and increased metal dispersions for the reduced samples. The CA-modified catalysts display higher CO conversions, product yields, reaction rates, and rate constants. The improved FT performance of CA-modified catalysts is attributed to the formation of stable complexes with Co. The superior performance of the EDTA-modified catalyst in comparison to the NTA-modified catalyst is due to the higher affinity of the former for complex formation with Co ions. 1. INTRODUCTION Fischer?Tropsch (FT) synthesis has been recognized as one of the most promising technologies for the conversion of coal, natural gas, and biomass-derived syngas into liquid fuels and chemicals.1 Limited oil reserves, energy supply security concerns, carbon credits,1 pollution abatement laws, and, most notably, uncertainty about fuel prices have increased the prospect of commercializing the FT process. Catalysts that are typically used for FT synthesis include supported Co or Fe. Cobased catalysts have the advantage of higher syngas conversion, more high-

  11. Novel Attrition-Resistant Fischer Tropsch Catalyst

    SciTech Connect (OSTI)

    Weast, Logan, E.; Staats, William, R.

    2009-05-01T23:59:59.000Z

    There is a strong national interest in the Fischer-Tropsch synthesis process because it offers the possibility of making liquid hydrocarbon fuels from reformed natural gas or coal and biomass gasification products. This project explored a new approach that had been developed to produce active, attrition-resistant Fischer-Tropsch catalysts that are based on glass-ceramic materials and technology. This novel approach represented a promising solution to the problem of reducing or eliminating catalyst attrition and maximizing catalytic activity, thus reducing costs. The technical objective of the Phase I work was to demonstrate that glass-ceramic based catalytic materials for Fischer-Tropsch synthesis have resistance to catalytic deactivation and reduction of particle size superior to traditional supported Fischer-Tropsch catalyst materials. Additionally, these novel glass-ceramic-based materials were expected to exhibit catalytic activity similar to the traditional materials. If successfully developed, the attrition-resistant Fischer-Tropsch catalyst materials would be expected to result in significant technical, economic, and social benefits for both producers and public consumers of Fischer-Tropsch products such as liquid fuels from coal or biomass gasification. This program demonstrated the anticipated high attrition resistance of the glass-ceramic materials. However, the observed catalytic activity of the materials was not sufficient to justify further development at this time. Additional testing documented that a lack of pore volume in the glass-ceramic materials limited the amount of surface area available for catalysis and consequently limited catalytic activity. However, previous work on glass-ceramic catalysts to promote other reactions demonstrated that commercial levels of activity can be achieved, at least for those reactions. Therefore, we recommend that glass-ceramic materials be considered again as potential Fischer-Tropsch catalysts if it can be demonstrated that materials with adequate pore volume can be produced. During the attrition resistance tests, it was learned that the glass-ceramic materials are very abrasive. Attention should be paid in any further developmental efforts to the potential for these hard, abrasive materials to damage reactors.

  12. Catalyst structure and method of Fischer-Tropsch synthesis

    DOE Patents [OSTI]

    Wang, Yong; Vanderwiel, David P.; Tonkovich, Anna Lee; Gao, Yufei; Baker, Eddie G.

    2004-06-15T23:59:59.000Z

    The present invention includes Fischer-Tropsch catalysts, reactions using Fischer-Tropsch catalysts, methods of making Fischer-Tropsch catalysts, processes of hydrogenating carbon monoxide, and fuels made using these processes. The invention provides the ability to hydrogenate carbon monoxide with low contact times, good conversion rates and low methane selectivities. In a preferred method, the catalyst is made using a metal foam support.

  13. Catalyst structure and method of fischer-tropsch synthesis

    DOE Patents [OSTI]

    Wang, Yong [Richland, WA; Vanderwiel, David P [Richland, WA; Tonkovich, Anna Lee Y [Pasco, WA; Gao, Yufei [Kennewick, WA; Baker, Eddie G [Pasco, WA

    2002-12-10T23:59:59.000Z

    The present invention includes Fischer-Tropsch catalysts, reactions using Fischer-Tropsch catalysts, methods of making Fischer-Tropsch catalysts, processes of hydrogenating carbon monoxide, and fuels made using these processes. The invention provides the ability to hydrogenate carbon monoxide with low contact times, good conversion rates and low methane selectivities. In a preferred method, the catalyst is made using a metal foam support.

  14. Cobalt Fischer-Tropsch catalysts having improved selectivity

    DOE Patents [OSTI]

    Miller, James G. (Pearl River, NY); Rabo, Jule A. (Armonk, NY)

    1989-01-01T23:59:59.000Z

    A cobalt Fischer-Tropsch catalyst having an improved steam treated, acid extracted LZ-210 support is taught. The new catalyst system demonstrates improved product selectivity at Fischer-Tropsch reaction conditions evidenced by lower methane production, higher C.sub.5.sup.+ yield and increased olefin production.

  15. Sensitivity of Fischer-Tropsch Synthesis and Water-Gas Shift Catalysts to Poisons from High-Temperature High-Pressure Entrained-Flow (EF) Oxygen-Blown Gasifier Gasification of Coal/Biomass Mixtures

    SciTech Connect (OSTI)

    Burtron Davis; Gary Jacobs; Wenping Ma; Khalid Azzam; Dennis Sparks; Wilson Shafer

    2010-09-30T23:59:59.000Z

    The successful adaptation of conventional cobalt and iron-based Fischer-Tropsch synthesis catalysts for use in converting biomass-derived syngas hinges in part on understanding their susceptibility to byproducts produced during the biomass gasification process. With the possibility that oil production will peak in the near future, and due to concerns in maintaining energy security, the conversion of biomass-derived syngas and syngas derived from coal/biomass blends to Fischer-Tropsch synthesis products to liquid fuels may provide a sustainable path forward, especially considering if carbon sequestration can be successfully demonstrated. However, one current drawback is that it is unknown whether conventional catalysts based on iron and cobalt will be suitable without proper development because, while ash, sulfur compounds, traces of metals, halide compounds, and nitrogen-containing chemicals will likely be lower in concentration in syngas derived from mixtures of coal and biomass (i.e., using an entrained-flow oxygen-blown gasifier) than solely from coal, other byproducts may be present in higher concentrations. The current project examines the impact of a number of potential byproducts of concern from the gasification of biomass process, including compounds containing alkali chemicals like the chlorides of sodium and potassium. In the second year, researchers from the University of Kentucky Center for Applied Energy Research (UK-CAER) continued the project by evaluating the sensitivity of a commercial iron-chromia high temperature water-gas shift catalyst (WGS) to a number of different compounds, including KHCO{sub 3}, NaHCO{sub 3}, HCl, HBr, HF, H{sub 2}S, NH{sub 3}, and a combination of H{sub 2}S and NH{sub 3}. Cobalt and iron-based Fischer-Tropsch synthesis (FT) catalysts were also subjected to a number of the same compounds in order to evaluate their sensitivities.

  16. E-Print Network 3.0 - advanced fischer-tropsch technology Sample...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    reactors (F-T) has... The Fischer Tropsch (F-T) synthesis was originally devel- oped in Germany in the 1920s by Franz Fischer... into syngas and, then, Fischer-Tropsch synthesis...

  17. Fuel and fuel blending components from biomass derived pyrolysis oil

    DOE Patents [OSTI]

    McCall, Michael J.; Brandvold, Timothy A.; Elliott, Douglas C.

    2012-12-11T23:59:59.000Z

    A process for the conversion of biomass derived pyrolysis oil to liquid fuel components is presented. The process includes the production of diesel, aviation, and naphtha boiling point range fuels or fuel blending components by two-stage deoxygenation of the pyrolysis oil and separation of the products.

  18. Romania program targets methanol and Fischer-Tropsch research

    SciTech Connect (OSTI)

    Not Available

    1987-03-01T23:59:59.000Z

    Currently, the chemical organic industry, the petrochemical and engine fuels industry in Romania are entirely based on hydrocarbons from oil. To reduce the oil dependence of this sector and to ensure the stipulated growth rate of 8-9%, research and development programs have been set up with a view to the diversification of raw materials. In research on hydrocarbons from alcohol conversion, three process variants are known, i.e. olefins from methanol, gasolines from methanol and a combined gasolines and aromatic hydrocarbons from methanol. The Romanian process of methanol conversion to hydrocarbons is very flexible, with all the variants mentioned being carried out in the same plant by modifying the catalysts. In research on hydrocarbons from synthesis gas a modern process is being developed for gasification of brown coal in a fluidized bed, under pressure, in the presence of oxygen and water vapors. In the field of carbon oxide hydrogenation, studies have been carried out on selective Fischer-Tropsch processes in which the reaction products are high value hydrocarbon fractions.

  19. Fischer-Tropsch synthesis process employing a moderated ruthenium catalyst

    DOE Patents [OSTI]

    Abrevaya, Hayim (Wilmette, IL)

    1990-01-01T23:59:59.000Z

    A Fischer-Tropsch type process produces hydrocarbons from carbon monoxide and hydrogen using a novel catalyst comprising moderated ruthenium on an inorganic oxide support. The preferred moderator is silicon. Preferably the moderator is effectively positioned in relationship to ruthenium particles through simultaneous placement on the support using reverse micelle impregnation.

  20. Cobalt Fischer-Tropsch catalysts having improved selectivity

    DOE Patents [OSTI]

    Miller, James G. (Pearl River, NY); Rabo, Jule A. (Armonk, NY)

    1989-01-01T23:59:59.000Z

    The promoter(s) Mn oxide or Mn oxide and Zr oxide are added to a cobalt Fischer-Tropsch catalyst combined with the molecular sieve TC-103 or TC-123 such that the resultant catalyst demonstrates improved product selectivity, stability and catalyst life. The improved selectivity is evidenced by lower methane production, higher C5+ yield and increased olefin production.

  1. Fischer-Tropsch synthesis process employing a moderated ruthenium catalyst

    DOE Patents [OSTI]

    Abrevaya, H.

    1990-07-31T23:59:59.000Z

    A Fischer-Tropsch type process produces hydrocarbons from carbon monoxide and hydrogen using a novel catalyst comprising moderated ruthenium on an inorganic oxide support. The preferred moderator is silicon. Preferably the moderator is effectively positioned in relationship to ruthenium particles through simultaneous placement on the support using reverse micelle impregnation. 1 fig.

  2. BASELINE DESIGN/ECONOMICS FOR ADVANCED FISCHER-TROPSCH TECHNOLOGY

    SciTech Connect (OSTI)

    None

    1998-04-01T23:59:59.000Z

    Bechtel, along with Amoco as the main subcontractor, developed a Baseline design, two alternative designs, and computer process simulation models for indirect coal liquefaction based on advanced Fischer-Tropsch (F-T) technology for the U. S. Department of Energy's (DOE's) Federal Energy Technology Center (FETC).

  3. Development of a Fischer-Tropsch Gasoline Process for the Steam Hydrogasification Technology

    E-Print Network [OSTI]

    Li, Yang

    2013-01-01T23:59:59.000Z

    M. ,   et   al. ,   Gasoline  conversion:  reactivity  al. ,   Methanol   to   gasoline   over   zeolite   H-­?of a Fischer-Tropsch Gasoline Process for the Steam

  4. Emissions from Trucks using Fischer-Tropsch Diesel Fuel

    SciTech Connect (OSTI)

    Paul Norton; Keith Vertin; Brent Bailey; Nigel N. Clark; Donald W. Lyons; Stephen Goguen; James Eberhardt

    1998-10-19T23:59:59.000Z

    The Fischer-Tropsch (F-T) catalytic conversion process can be used to synthesize diesel fuels from a variety of feedstocks, including coal, natural gas and biomass. Synthetic diesel fuels can have very low sulfur and aromatic content, and excellent autoignition characteristics. Moreover, Fischer-Tropsch diesel fuels may also be economically competitive with California B- diesel fuel if produced in large volumes. overview of Fischer-Tropsch diesel fuel production and engine emissions testing is presented. Previous engine laboratory tests indicate that F-T diesel is a promising alternative fuel because it can be used in unmodified diesel engines, and substantial exhaust emissions reductions can be realized. The authors have performed preliminary tests to assess the real-world performance of F-T diesel fuels in heavy-duty trucks. Seven White-GMC Class 8 trucks equipped with Caterpillar 10.3 liter engines were tested using F-T diesel fuel. Vehicle emissions tests were performed using West Virginia University's unique transportable chassis dynamometer. The trucks were found to perform adequately on neat F-T diesel fuel. Compared to a California diesel fuel baseline, neat F-T diesel fuel emitted about 12% lower oxides of nitrogen (NOx) and 24% lower particulate matter over a five-mile driving cycle.

  5. On-Road Use of Fischer-Tropsch Diesel Blends

    SciTech Connect (OSTI)

    Nigel Clark; Mridul Gautam; Donald Lyons; Chris Atkinson; Wenwei Xie; Paul Norton; Keith Vertin; Stephen Goguen; James Eberhardt

    1999-04-26T23:59:59.000Z

    Alternative compression ignition engine fuels are of interest both to reduce emissions and to reduce U.S. petroleum fuel demand. A Malaysian Fischer-Tropsch gas-to-liquid fuel was compared with California No.2 diesel by characterizing emissions from over the road Class 8 tractors with Caterpillar 3176 engines, using a chassis dynamometer and full scale dilution tunnel. The 5-Mile route was employed as the test schedule, with a test weight of 42,000 lb. Levels of oxides of nitrogen (NO{sub x}) were reduced by an average of 12% and particulate matter (PM) by 25% for the Fischer-Tropsch fuel over the California diesel fuel. Another distillate fuel produced catalytically from Fischer-Tropsch products originally derived from natural gas by Mossgas was also compared with 49-state No.2 diesel by characterizing emissions from Detroit Diesel 6V-92 powered transit buses, three of them equipped with catalytic converters and rebuilt engines, and three without. The CBD cycle was employed as the test schedule, with a test weight of 33,050 lb. For those buses with catalytic converters and rebuilt engines, NO x was reduced by 8% and PM was reduced by 31% on average, while for those buses without, NO x was reduced by 5% and PM was reduced by 20% on average. It is concluded that advanced compression ignition fuels from non-petroleum sources can offer environmental advantages in typical line haul and city transit applications.

  6. Separation of catalyst from Fischer-Tropsch slurry

    DOE Patents [OSTI]

    White, Curt M. (Pittsburgh, PA); Quiring, Michael S. (Katy, TX); Jensen, Karen L. (Pittsburgh, PA); Hickey, Richard F. (Bethel Park, PA); Gillham, Larry D. (Bartlesville, OK)

    1998-10-27T23:59:59.000Z

    In a catalytic process for converting synthesis gas including hydrogen and carbon monoxide to hydrocarbons and oxygenates by a slurry Fischer-Tropsch synthesis, the wax product along with dispersed catalyst is removed from the slurry and purified by removing substantially all of the catalyst prior to upgrading the wax and returning a portion to the Fischer-Tropsch reaction. Separation of the catalyst particles from the wax product is accomplished by dense gas and/or liquid extraction in which the organic compounds in the wax are dissolved and carried away from the insoluble inorganic catalyst particles that are primarily inorganic in nature. The purified catalyst free wax product can be subsequently upgraded by various methods such as hydrogenation, isomerization, hydrocracking, conversion to gasoline and other products over ZSM-5 aluminosilicate zeolite, etc. The catalyst particles are returned to the Fischer-Tropsch Reactor by slurring them with a wax fraction of appropriate molecular weight, boiling point and viscosity to avoid reactor gelation.

  7. Separation of catalyst from Fischer-Tropsch slurry

    DOE Patents [OSTI]

    White, C.M.; Quiring, M.S.; Jensen, K.L.; Hickey, R.F.; Gillham, L.D.

    1998-10-27T23:59:59.000Z

    In a catalytic process for converting synthesis gas including hydrogen and carbon monoxide to hydrocarbons and oxygenates by a slurry Fischer-Tropsch synthesis, the wax product along with dispersed catalyst is removed from the slurry and purified by removing substantially all of the catalyst prior to upgrading the wax and returning a portion to the Fischer-Tropsch reaction. Separation of the catalyst particles from the wax product is accomplished by dense gas and/or liquid extraction in which the organic compounds in the wax are dissolved and carried away from the insoluble inorganic catalyst particles that are primarily inorganic in nature. The purified catalyst-free wax product can be subsequently upgraded by various methods such as hydrogenation, isomerization, hydrocracking, conversion to gasoline and other products over ZSM-5 aluminosilicate zeolite, etc. The catalyst particles are returned to the Fischer-Tropsch Reactor by mixing them with a wax fraction of appropriate molecular weight, boiling point and viscosity to avoid reactor gelation. 2 figs.

  8. ATTACHMENT IX Review of Air Products Fischer-Tropsch Synthesis Work

    E-Print Network [OSTI]

    Kentucky, University of

    IX.1-Draft ATTACHMENT IX Review of Air Products Fischer-Tropsch Synthesis Work During the 1980s, Air Products & Chemicals worked on several aspects of the Fischer-Tropsch synthesis. These included, exhibited similar activity and product selectivity, showing that the preparative method was reproducible

  9. Monetization of Nigeria coal by conversion to hydrocarbon fuels through Fischer-Tropsch process

    SciTech Connect (OSTI)

    Oguejiofor, G.C. [Nnamdi Azikiwe University, Awka (Nigeria). Dept. of Chemical Engineering

    2008-07-01T23:59:59.000Z

    Given the instability of crude oil prices and the disruptions in crude oil supply chains, this article offers a complementing investment proposal through diversification of Nigeria's energy source and dependence. Therefore, the following issues were examined and reported: A comparative survey of coal and hydrocarbon reserve bases in Nigeria was undertaken and presented. An excursion into the economic, environmental, and technological justifications for the proposed diversification and roll-back to coal-based resource was also undertaken and presented. The technology available for coal beneficiation for environmental pollution control was reviewed and reported. The Fischer-Tropsch synthesis and its advances into Sasol's slurry phase distillate process were reviewed. Specifically, the adoption of Sasol's advanced synthol process and the slurry phase distillate process were recommended as ways of processing the products of coal gasification. The article concludes by discussing all the above-mentioned issues with regard to value addition as a means of wealth creation and investment.

  10. Fischer-Tropsch synthesis over iron-rhodium alloy catalysts

    SciTech Connect (OSTI)

    Choi, S.

    1983-01-01T23:59:59.000Z

    To investigate the nature of iron-rhodium alloy catalysts during the Fischer-Tropsch synthesis, a combination of experimental techniques were applied. Infrared spectroscopy was mainly used to extract direct information on the surface of catalysts under the reaction conditions. In addition, Mossbauer spectroscopy was employed to study the iron alloy catalysts. Further characterization of the catalysts was performed by chemisorption measurements. Hydrocarbon products of the CO + H/sub 2/ synthesis reaction were analyzed by gas chromatography. The working surface of a silica-supported rhodium catalyst was found to be saturated with molecular carbon monoxide. The intensity of the linear carbonyl absorption band remained constant compared to that for room temperature CO adsorption, while that of the bridge-bonded carbonyl absorption band was drastically reduced during the Fischer-Tropsch synthesis. The bridge-bonded adsorption sites are assumed to be the active sites for dissociating carbon monoxide. The hydrogenation rate of the linearly adsorbed carbon monoxide was much slower than the steady state reaction rate. The alloy catalyst did not form a bulk carbide, but the presence of surface carbon was suggested by the large shift of the linear carbonyl absorption band. On the other hand, infrared spectra on an iron catalyst showed only weak bands, indicating a high degree of CO dissociation. On a silica-supported iron-rhodium alloy catalyst, surface analysis by infrared spectroscopy presents evidence of well-mixed alloy formation. Three models of carbon monoxide adsorption were identified.

  11. Supported fischer-tropsch catalyst and method of making the catalyst

    SciTech Connect (OSTI)

    Dyer, Paul N. (Allentown, PA); Pierantozzi, Ronald (Orefield, PA); Withers, Howard P. (Douglassville, PA)

    1987-01-01T23:59:59.000Z

    A Fischer-Tropsch catalyst and a method of making the catalyst for a Fischer-Tropsch process utilizing the catalyst by which synthesis gas, particularly carbon-monoxide rich synthesis gas, is selectively converted to higher hydrocarbons of relatively narrow carbon number range is disclosed. In general, the selective and notably stable catalyst, consist of an inert carrier first treated with a Group IV B metal compound (such as zirconium or titanium), preferably an alkoxide compound, and subsequently treated with an organic compound of a Fischer-Tropsch metal catalyst, such as cobalt, iron or ruthenium carbonyl. Reactions with air and water and calcination are specifically avoided in the catalyst preparation procedure.

  12. Spray drying and attrition behavior of iron catalysts for slurry phase Fischer-Tropsch synthesis

    E-Print Network [OSTI]

    Carreto Vazquez, Victor Hugo

    2004-11-15T23:59:59.000Z

    This thesis describes results of a study aimed at developing and evaluating attrition resistant iron catalysts prepared by spray drying technique. These catalysts are intended for Fischer-Tropsch (F-T) synthesis in a slurry bubble column reactor...

  13. TECHNOLOGY DEVELOPMENT FOR IRON FISCHER-TROPSCH CATALYSTS

    SciTech Connect (OSTI)

    Davis, B.H.

    1998-07-22T23:59:59.000Z

    The goal of the proposed work described in this Final Report was the development of iron-based Fischer-Tropsch catalysts that combined high activity, selectivity and life with physical robustness for slurry phase reactors that will produce either low-alpha or high-alpha products. The work described here has optimized the catalyst composition and pretreatment operation for a low-alpha catalyst. In parallel, work has been conducted to design a high-alpha iron catalyst that is suitable for slurry phase synthesis. Studies have been conducted to define the chemical phases present at various stages of the pretreatment and synthesis stages and to define the course of these changes. The oxidation/reduction cycles that are anticipated to occur in large, commercial reactors have been studied at the laboratory scale. Catalyst performance has been determined for catalysts synthesized in this program for activity, selectivity and aging characteristics.

  14. Iron on mixed zirconia-titania substrate Fischer-Tropsch catalyst and method of making same

    DOE Patents [OSTI]

    Dyer, Paul N. (Allentown, PA); Nordquist, Andrew F. (Whitehall, PA); Pierantozzi, Ronald (Macungie, PA)

    1986-01-01T23:59:59.000Z

    A Fischer-Tropsch catalyst comprising iron co-deposited with or deposited on particles comprising a mixture of zirconia and titania, preferably formed by co-precipitation of compounds convertible to zirconia and titania, such as zirconium and titanium alkoxide. The invention also comprises the method of making this catalyst and an improved Fischer-Tropsch reaction process in which the catalyst is utilized.

  15. ATTRITION RESISTANT IRON-BASED FISCHER-TROPSCH CATALYSTS

    SciTech Connect (OSTI)

    K. Jothimurugesan; James G. Goodwin, Jr.; Santosh K. Gangwal

    1999-10-01T23:59:59.000Z

    Fischer-Tropsch (FT) synthesis to convert syngas (CO + H{sub 2}) derived from natural gas or coal to liquid fuels and wax is a well-established technology. For low H{sub 2} to CO ratio syngas produced from CO{sub 2} reforming of natural gas or from gasification of coal, the use of Fe catalysts is attractive because of their high water gas shift activity in addition to their high FT activity. Fe catalysts are also attractive due to their low cost and low methane selectivity. Because of the highly exothermic nature of the FT reaction, there has been a recent move away from fixed-bed reactors toward the development of slurry bubble column reactors (SBCRs) that employ 30 to 90 {micro}m catalyst particles suspended in a waxy liquid for efficient heat removal. However, the use of FeFT catalysts in an SBCR has been problematic due to severe catalyst attrition resulting in fines that plug the filter employed to separate the catalyst from the waxy product. Fe catalysts can undergo attrition in SBCRs not only due to vigorous movement and collisions but also due to phase changes that occur during activation and reaction.

  16. KINETICS OF SLURRY PHASE FISCHER-TROPSCH SYNTHESIS

    SciTech Connect (OSTI)

    Dragomir B. Bukur; Gilbert F. Froment; Lech Nowicki; Jiang Wang; Wen-Ping Ma

    2003-09-29T23:59:59.000Z

    This report covers the first year of this three-year research grant under the University Coal Research program. The overall objective of this project is to develop a comprehensive kinetic model for slurry phase Fischer-Tropsch synthesis on iron catalysts. This model will be validated with experimental data obtained in a stirred tank slurry reactor (STSR) over a wide range of process conditions. The model will be able to predict concentrations of all reactants and major product species (H{sup 2}O, CO{sub 2}, linear 1- and 2-olefins, and linear paraffins) as a function of reaction conditions in the STSR. During the reporting period we have completed one STSR test with precipitated iron catalyst obtained from Ruhrchemie AG (Oberhausen-Holten, Germany). This catalyst was initially in commercial fixed bed reactors at Sasol in South Africa. The catalyst was tested at 13 different sets of process conditions, and had experienced a moderate deactivation during the first 500 h of testing (decrease in conversion from 56% to 50% at baseline process conditions). The second STSR test has been initiated and after 270 h on stream, the catalyst was tested at 6 different sets of process conditions.

  17. KINETICS OF SLURRY PHASE FISCHER-TROPSCH SYNTHESIS

    SciTech Connect (OSTI)

    Dragomir B. Bukur

    2004-09-29T23:59:59.000Z

    This report covers the second year of this three-year research grant under the University Coal Research program. The overall objective of this project is to develop a comprehensive kinetic model for slurry phase Fischer-Tropsch synthesis on iron catalysts. This model will be validated with experimental data obtained in a stirred tank slurry reactor (STSR) over a wide range of process conditions. The model will be able to predict concentrations of all reactants and major product species (H{sub 2}O, CO{sub 2}, linear 1- and 2-olefins, and linear paraffins) as a function of reaction conditions in the STSR. During the second year of the project we completed the STSR test SB-26203 (275-343 h on stream), which was initiated during the first year of the project, and another STSR test (SB-28603 lasting 341 h). Since the inception of the project we completed 3 STSR tests, and evaluated catalyst under 25 different sets of process conditions. A precipitated iron catalyst obtained from Ruhrchemie AG (Oberhausen-Holten, Germany) was used in all tests. This catalyst was used initially in commercial fixed bed reactors at Sasol in South Africa. Also, during the second year we performed a qualitative analysis of experimental data from all three STSR tests. Effects of process conditions (reaction temperature, pressure, feed composition and gas space velocity) on water-gas-shift (WGS) activity and hydrocarbon product distribution have been determined.

  18. Potential for Coal-to-Liquids Conversion in the United States-Fischer-Tropsch Synthesis

    SciTech Connect (OSTI)

    Patzek, Tad W. [University of Texas, Department of Petroleum and Geosystems Engineering (United States)], E-mail: patzek@mail.utexas.edu; Croft, Gregory D. [University of California, Department of Civil and Environmental Engineering (United States)

    2009-09-15T23:59:59.000Z

    The United States has the world's largest coal reserves and Montana the highest potential for mega-mine development. Consequently, a large-scale effort to convert coal to liquids (CTL) has been proposed to create a major source of domestic transportation fuels from coal, and some prominent Montanans want to be at the center of that effort. We calculate that the energy efficiency of the best existing Fischer-Tropsch (FT) process applied to average coal in Montana is less than 1/2 of the corresponding efficiency of an average crude oil refining process. The resulting CO{sub 2} emissions are 20 times (2000%) higher for CTL than for conventional petroleum products. One barrel of the FT fuel requires roughly 800 kg of coal and 800 kg of water. The minimum energy cost of subsurface CO{sub 2} sequestration would be at least 40% of the FT fuel energy, essentially halving energy efficiency of the process. We argue therefore that CTL conversion is not the most valuable use for the coal, nor will it ever be, as long as it is economical to use natural gas for electric power generation. This finding results from the low efficiency inherent in FT synthesis, and is independent of the monumental FT plant construction costs, mine construction costs, acute lack of water, and the associated environmental impacts for Montana.

  19. Attrition resistant catalysts for slurry-phase Fischer-Tropsch process

    SciTech Connect (OSTI)

    K. Jothimurugesan

    1999-11-01T23:59:59.000Z

    The Fischer-Tropsch (F-T) reaction provides a way of converting coal-derived synthesis gas (CO+H{sub 2}) to liquid fuels. Since the reaction is highly exothermic, one of the major problems in control of the reaction is heat removal. Recent work has shown that the use of slurry bubble column reactors (SBCRs) can largely solve this problem. Iron-based (Fe) catalysts are preferred catalysts for F-T because they are relatively inexpensive and possess reasonable activity for F-T synthesis (FTS). Their most advantages trait is their high water-gas shift (WGS) activity compared to their competitor, namely cobalt. This enables Fe F-T catalysts to process low H{sub 2}/CO ratio synthesis gas without an external shift reaction step. However, a serious problem with the use of Fe catalysts in a SBCR is their tendency to undergo attrition. This can cause fouling/plugging of downstream filters and equipment, make the separation of catalyst from the oil/wax product very difficult if not impossible, an d result in a steady loss of catalyst from the reactor. The objectives of this research were to develop a better understanding of the parameters affecting attrition of Fe F-T catalysts suitable for use in SBCRs and to incorporate this understanding into the design of novel Fe catalysts having superior attrition resistance.

  20. Low oxygen biomass-derived pyrolysis oils and methods for producing the same

    SciTech Connect (OSTI)

    Marinangeli, Richard; Brandvold, Timothy A; Kocal, Joseph A

    2013-08-27T23:59:59.000Z

    Low oxygen biomass-derived pyrolysis oils and methods for producing them from carbonaceous biomass feedstock are provided. The carbonaceous biomass feedstock is pyrolyzed in the presence of a catalyst comprising base metal-based catalysts, noble metal-based catalysts, treated zeolitic catalysts, or combinations thereof to produce pyrolysis gases. During pyrolysis, the catalyst catalyzes a deoxygenation reaction whereby at least a portion of the oxygenated hydrocarbons in the pyrolysis gases are converted into hydrocarbons. The oxygen is removed as carbon oxides and water. A condensable portion (the vapors) of the pyrolysis gases is condensed to low oxygen biomass-derived pyrolysis oil.

  1. Development of Detailed Kinetic Models for Fischer-Tropsch Fuels

    SciTech Connect (OSTI)

    Westbrook, C K; Pitz, W J; Carstensen, H; Dean, A M

    2008-10-28T23:59:59.000Z

    Fischer-Tropsch (FT) fuels can be synthesized from a syngas stream generated by the gasification of biomass. As such they have the potential to be a renewable hydrocarbon fuel with many desirable properties. However, both the chemical and physical properties are somewhat different from the petroleum-based hydrocarbons that they might replace, and it is important to account for such differences when considering using them as replacements for conventional fuels in devices such as diesel engines and gas turbines. FT fuels generally contain iso-alkanes with one or two substituted methyl groups to meet the pour-point specifications. Although models have been developed for smaller branched alkanes such as isooctane, additional efforts are required to properly capture the kinetics of the larger branched alkanes. Recently, Westbrook et al. developed a chemical kinetic model that can be used to represent the entire series of n-alkanes from C{sub 1} to C{sub 16} (Figure 1). In the current work, the model is extended to treat 2,2,4,4,6,8,8-heptamethylnonane (HMN), a large iso-alkane. The same reaction rate rules used in the iso-octane mechanism were incorporated in the HMN mechanism. Both high and low temperature chemistry was included so that the chemical kinetic model would be applicable to advanced internal combustion engines using low temperature combustion strategies. The chemical kinetic model consists of 1114 species and 4468 reactions. Concurrently with this effort, work is underway to improve the details of specific reaction classes in the mechanism, guided by high-level electronic structure calculations. Attention is focused upon development of accurate rate rules for abstraction of the tertiary hydrogens present in branched alkanes and properly accounting for the pressure dependence of the ?-scission, isomerization, and R + O{sub 2} reactions.

  2. Technology Development for Iron and Cobalt Fischer-Tropsch Catalysts Quarterly Report

    E-Print Network [OSTI]

    Kentucky, University of

    , selectivity and water-gas shift activity were studied over a wide range of syngas conversion. Three catalyst water gas shift reaction rates and CO2 2 #12;3 selectivity during Fischer-Tropsch synthesis on Fe are higher than that on Co/SiO (21%). A multi-o 2 compartment kinetic model of catalytic surfaces is being

  3. The limiting mutual diffusion coefficients of Fischer-Tropsch synthesis products in near-critical hydrocarbons

    E-Print Network [OSTI]

    Noel, James Michael

    1994-01-01T23:59:59.000Z

    The Fischer-Tropsch synthesis (FTS) is used to convert synthesis gas into petroleum products such as gasoline and diesel fuel. It was developed in Germany during WW 11 as an alternative fuel source during the fuel embargo and is still used as a...

  4. Fischer-Tropsch Database Calculations Conversions: CO, H2, and Syngas

    E-Print Network [OSTI]

    Kentucky, University of

    Fischer-Tropsch Database Calculations Conversions: CO, H2, and Syngas f in out in n n n = - 100 n contraction (%) #12;Syngas ratio (H2:CO): sr H in CO in n n = 2 _ _ n: (mols per hour) sr: Syngas ratio Rates active metal (g) r: Rate (mols / hr / g metal) #12;Rate Syngas: syngas H COr r r= +2 r syngas: Syngas

  5. FISCHER-TROPSCH FUELS PRODUCTION AND DEMONSTRATION PROJECT

    SciTech Connect (OSTI)

    Stephen P. Bergin

    2003-04-23T23:59:59.000Z

    This project has two primary purposes: (1) Build a small-footprint (SFP) fuel production plant to prove the feasibility of this relatively transportable technology on an intermediate scale (i.e. between laboratory-bench and commercial capacity) and produce as much as 150,000 gallons of hydrogen-saturated Fischer-Tropsch (FT) diesel fuel; and (2) Use the virtually sulfur-free fuel produced to demonstrate (over a period of at least six months) that it can not only be used in existing diesel engines, but that it also can enable significantly increased effectiveness and life of the next-generation exhaust-after-treatment emission control systems that are currently under development and that will be required for future diesel engines. Furthermore, a well-to-wheels economic analysis will be performed to characterize the overall costs and benefits that would be associated with the actual commercial production, distribution and use of such FT diesel fuel made by the process under consideration, from the currently underutilized (or entirely un-used) energy resources targeted, primarily natural gas that is stranded, sub-quality, off-shore, etc. During the first year of the project, which is the subject of this report, there have been two significant areas of progress: (1) Most of the preparatory work required to build the SFP fuel-production plant has been completed, and (2) Relationships have been established, and necessary project coordination has been started, with the half dozen project-partner organizations that will have a role in the fuel demonstration and evaluation phase of the project. Additional project tasks directly related to the State of Alaska have also been added to the project. These include: A study of underutilized potential Alaska energy resources that could contribute to domestic diesel and distillate fuel production by providing input energy for future commercial-size SFP fuel production plants; Demonstration of the use of the product fuel in a heavy-duty diesel vehicle during the Alaska winter; a comparative study of the cold-starting characteristics of FT and conventional diesel fuel; and demonstration of the use of the fuel to generate electricity for rural Alaskan villages using both a diesel generator set, and a reformer-equipped fuel cell.

  6. KINETICS OF SLURRY PHASE FISCHER-TROPSCH SYNTHESIS

    SciTech Connect (OSTI)

    Dragomir B. Bukur; Gilbert F. Froment; Tomasz Olewski

    2006-09-29T23:59:59.000Z

    This report covers the fourth year of a research project conducted under the University Coal Research Program. The overall objective of this project is to develop a comprehensive kinetic model for slurry-phase Fischer-Tropsch synthesis (FTS) employing iron-based catalysts. This model will be validated with experimental data obtained in a stirred-tank slurry reactor (STSR) over a wide range of process conditions. The model will be able to predict molar flow rates and concentrations of all reactants and major product species (water, carbon dioxide, linear 1- and 2-olefins, and linear paraffins) as a function of reaction conditions in the STSR. During the fourth year of the project, an analysis of experimental data collected during the second year of this project was performed. Kinetic parameters were estimated utilizing product distributions from 27 mass balances. During the reporting period two kinetic models were employed: a comprehensive kinetic model of Dr. Li and co-workers (Yang et al., 2003) and a hydrocarbon selectivity model of Van der Laan and Beenackers (1998, 1999) The kinetic model of Yang et al. (2003) has 24 parameters (20 parameters for hydrocarbon formation, and 4 parameters for the water-gas-shift (WGS) reaction). Kinetic parameters for the WGS reaction and FTS synthesis were estimated first separately, and then simultaneously. The estimation of these kinetic parameters employed the Levenberg-Marquardt (LM) method and the trust-region reflective Newton large-scale (LS) method. A genetic algorithm (GA) was incorporated into estimation of parameters for FTS reaction to provide initial estimates of model parameters. All reaction rate constants and activation energies were found to be positive, but at the 95% confidence level the intervals were large. Agreement between predicted and experimental reaction rates has been fair to good. Light hydrocarbons are predicted fairly accurately, whereas the model underpredicts values of higher molecular weight hydrocarbons. Van der Laan and Beenackers hydrocarbon selectivity model provides a very good fit of the experimental data for hydrocarbons up to about C{sub 20}. However, the experimental data shows higher paraffin formation rates in C{sub 12}-C{sub 25} region which is likely due to hydrocracking or other secondary reactions. The model accurately captures the observed experimental trends of decreasing olefin to paraffin ratio and increasing {alpha} (chain growth length) with increase in chain length.

  7. KINETICS OF SLURRY PHASE FISCHER-TROPSCH SYSTHESIS

    SciTech Connect (OSTI)

    Dragomir B. Bukur; Gilbert F. Froment; Tomasz Olewski

    2005-09-29T23:59:59.000Z

    This report covers the third year of this research grant under the University Coal Research program. The overall objective of this project is to develop a comprehensive kinetic model for slurry phase Fischer-Tropsch synthesis (FTS) on iron catalysts. This model will be validated with experimental data obtained in a stirred tank slurry reactor (STSR) over a wide range of process conditions. The model will be able to predict molar flow rates and concentrations of all reactants and major product species (H{sub 2}O, CO{sub 2}, linear 1- and 2-olefins, and linear paraffins) as a function of reaction conditions in the STSR. During the reporting period we utilized experimental data from the STSR, that were obtained during the first two years of the project, to perform vapor-liquid equilibrium (VLE) calculations and estimate kinetic parameters. We used a modified Peng-Robinson (PR) equation of state (EOS) with estimated values of binary interaction coefficients for the VLE calculations. Calculated vapor phase compositions were in excellent agreement with experimental values from the STSR under reaction conditions. Occasional discrepancies (for some of the experimental data) between calculated and experimental values of the liquid phase composition were ascribed to experimental errors. The VLE calculations show that the vapor and the liquid are in thermodynamic equilibrium under reaction conditions. Also, we have successfully applied the Levenberg-Marquardt method (Marquardt, 1963) to estimate parameters of a kinetic model proposed earlier by Lox and Froment (1993b) for FTS on an iron catalyst. This kinetic model is well suited for initial studies where the main goal is to learn techniques for parameter estimation and statistical analysis of estimated values of model parameters. It predicts that the chain growth parameter ({alpha}) and olefin to paraffin ratio are independent of carbon number, whereas our experimental data show that they vary with the carbon number. Predicted molar flow rates of inorganic species, n-paraffins and total olefins were generally not in good agreement with the corresponding experimental values. In the future we'll use kinetic models based on non-constant value of {alpha}.

  8. Incorporation of catalytic dehydrogenation into fischer-tropsch synthesis to significantly reduce carbon dioxide emissions

    DOE Patents [OSTI]

    Huffman, Gerald P.

    2012-11-13T23:59:59.000Z

    A new method of producing liquid transportation fuels from coal and other hydrocarbons that significantly reduces carbon dioxide emissions by combining Fischer-Tropsch synthesis with catalytic dehydrogenation is claimed. Catalytic dehydrogenation (CDH) of the gaseous products (C1-C4) of Fischer-Tropsch synthesis (FTS) can produce large quantities of hydrogen while converting the carbon to multi-walled carbon nanotubes (MWCNT). Incorporation of CDH into a FTS-CDH plant converting coal to liquid fuels can eliminate all or most of the CO.sub.2 emissions from the water-gas shift (WGS) reaction that is currently used to elevate the H.sub.2 level of coal-derived syngas for FTS. Additionally, the FTS-CDH process saves large amounts of water used by the WGS reaction and produces a valuable by-product, MWCNT.

  9. Slurry phase Fischer-Tropsch synthesis: Cobalt plus a water-gas shift catalyst

    SciTech Connect (OSTI)

    Yates, I.C.; Satterfield, C.N.

    1988-01-01T23:59:59.000Z

    This report details experiments performed on three different copper-based catalysts: Cu/Cr[sub 2]O[sub 3], Cu/MnO/Cr[sub 2]O[sub 3] and Cu/ZnO/Al[sub 2]O[sub 3]. Of these three catalysts, the Cu/ZnO/Al[sub 2]O[sub 3] exhibits the greatest stability when slurried in octacosane. More than 1000 hours-on-stream indicate that the catalyst activity is not detrimentally affected by high pressure, high H[sub 2]/CO ratio, or the presence of alkenes. All of these are necessary stability characteristics for the water-gas shift catalyst, if it is to be used in combination with a cobalt Fischer-Tropsch catalyst. A review of documented reduction procedures for cobalt-based Fischer-Tropsch catalysts is presented.

  10. Processes and catalysts for conducting fischer-tropsch synthesis in a slurry bubble column reactor

    DOE Patents [OSTI]

    Singleton, Alan H. (Marshall Township, Allegheny County, PA); Oukaci, Rachid (Allison Park, PA); Goodwin, James G. (Cranberry Township, PA)

    1999-01-01T23:59:59.000Z

    Processes and catalysts for conducting Fischer-Tropsch synthesis in a slurry bubble column reactor (SBCR). One aspect of the invention involves the use of cobalt catalysts without noble metal promotion in an SBCR. Another aspect involves using palladium promoted cobalt catalysts in an SBCR. Methods for preparing noble metal promoted catalysts via totally aqueous impregnation and procedures for producing attrition resistant catalysts are also provided.

  11. Processes and catalysts for conducting Fischer-Tropsch synthesis in a slurry bubble column reactor

    DOE Patents [OSTI]

    Singleton, A.H.; Oukaci, R.; Goodwin, J.G.

    1999-08-17T23:59:59.000Z

    Processes and catalysts are disclosed for conducting Fischer-Tropsch synthesis in a slurry bubble column reactor (SBCR). One aspect of the invention involves the use of cobalt catalysts without noble metal promotion in an SBCR. Another aspect involves using palladium promoted cobalt catalysts in an SBCR. Methods for preparing noble metal promoted catalysts via totally aqueous impregnation and procedures for producing attrition resistant catalysts are also provided. 1 fig.

  12. A study of Fischer-Tropsch model compounds reacting over ZSM-5

    E-Print Network [OSTI]

    Riley, Mark Garner

    1984-01-01T23:59:59.000Z

    . Anthony The decomposition of three Fischer-Tropsch model compounds, 1-decanol. decanal, and n-heptane, over ZSM-5 catalysts ion exchanged with nickel, zinc, and hydrogen was studied. The mechanisms of decomposition and the reaction kinetics... LITERATURE CITED 49 APPENDIX A CATALYST PREPARATION Nickel Exchange Hydrogen Exchange 51 51 51 Zinc Exchange X-ray Diffraction Pattern 52 53 Table of Contents (Continued) Page APPENDIX B RUN CONDITIONS AND PRODUCT DISTRIBUTIONS 54 APPENDIX C...

  13. Simulation of Fischer-Tropsch Fixed-Bed Reactor in Different Reaction Media

    E-Print Network [OSTI]

    Bani Nasser, Laial Ahmad

    2013-11-04T23:59:59.000Z

    -phase FTS in fixed-bed reactor as the liquid phase provides an optimum medium for the highly exothermic reaction due to its heat capacity and density [4]. Besides its excellent temperature control, this medium facilitates the in-situ extraction of heavy...] ( ) Co/MgO/SiO2 [20] ( ) Co/kieselguhr [21] ( ) Co/Al2O3 [22] 1.2.2 Commercial Scale Fischer-Tropsch Reactors FTS is an extremely exothermic process, which...

  14. Iron Aerogel and Xerogel Catalysts for Fischer-Tropsch Synthesis of Diesel Fuel

    SciTech Connect (OSTI)

    Bali, S.; Huggins, F; Huffman, G; Ernst, R; Pugmire, R; Eyring, E

    2009-01-01T23:59:59.000Z

    Iron aerogels, potassium-doped iron aerogels, and potassium-doped iron xerogels have been synthesized and characterized and their catalytic activity in the Fischer-Tropsch (F-T) reaction has been studied. Iron aerogels and xerogels were synthesized by polycondensation of an ethanolic solution of iron(III) chloride hexahydrate with propylene oxide which acts as a proton scavenger for the initiation of hydrolysis and polycondensation. Potassium was incorporated in the iron aerogel and iron xerogel by adding aqueous K{sub 2}CO{sub 3} to the ethanolic solutions of the Fe(III) precursor prior to addition of propylene oxide. Fischer-Tropsch activities of the catalysts were tested in a fixed bed reactor at a pressure of 100 psi with a H{sub 2}:CO ratio of 2:1. Iron aerogels were found to be active for F-T synthesis, and their F-T activities increased on addition of a K containing promoter. Moessbauer spectroscopic data are consistent with an open, nonrigid iron(III) aerogel structure progressing to an iron carbide/metallic iron catalyst via agglomeration as the F-T synthesis proceeds in the course of a 35 h fixed bed reaction test.

  15. Development and process evaluation of improved Fischer-Tropsch slurry catalysts. Final report

    SciTech Connect (OSTI)

    Bukur, D.B.; Mukesh, D.; Patel, S.A.; Zimmerman, W.H.; Rosynek, M.P. [Texas A& M Univ., College Station, TX (United States); Kellogg, L.J. [Air Products and Chemicals, Inc., Allentown, PA (United States)

    1990-04-01T23:59:59.000Z

    This report describes results of a study aimed at developing and evaluating improved catalysts for a slurry Fischer-Tropsch (FT) process for converting synthesis gas to high quality transportation fuels (gasoline and distillate). The improvements in catalyst performance were sought by studying effects of pretreatment conditions, promoters and binders/supports. A total of 20 different, iron based, catalysts were evaluated in 58 fixed bed reactor tests and 10 slurry reactor tests. The major accomplishments and conclusions are summarized below. The pretreatment conditions (temperature, duration and the nature of reducing gas) have significant effect on catalyst performance (activity, selectivity and stability) during Fischer-Tropsch synthesis. One of precipitated unsupported catalysts had hydrocarbon selectivity similar to Mobil`s I-B catalyst in high wax mode operation, and had not experienced any loss in activity during 460 hours of testing under variable process conditions in a slurry reactor. The effect of promoters (copper and potassium) on catalyst performance during FT synthesis has been studied in a systematic way. It was found that potassium promotion increases activities of the FT and water-gas-shift (WGS) reactions, the average molecular weight of hydrocarbon products, and suppresses the olefin hydrogenation and isomerization reactions. The addition of binders/supports (silica or alumina) to precipitated Fe/Cu/K catalysts, decreased their activity but improved their stability and hydrocarbon selectivity. The performance of catalysts of this type was very promising and additional studies are recommended to evaluate their potential for use in commercial slurry reactors.

  16. Synthesis of octane enhancers during slurry-phase Fischer-Tropsch

    SciTech Connect (OSTI)

    Marcelin, G.

    1992-09-24T23:59:59.000Z

    The objective of this project is to investigate three possible routes to the formation of ethers, in particular methyl tert-butyl (MTBE), during slurry phase Fischer-Tropsch reaction. The three reaction schemes to be investigated are: addition of i-butylene during the formation of methanol and/or higher alcohols directly from CO and H[sub 2] during slurry-phase Fischer-Tropsch; addition of i-butylene to FT liquid products including alcohols in a slurry-phase reactor containing an MTBE or other acid catalyst; and addition of methanol to slurry phase FT synthesis making iso-olefins. During the seventh quarter we continued the shake down experiments for the SBCR and conducted an initial aborted run. We have also re-started experiments on Scheme 1, i.e., the addition of iso-butylene during CO hydrogenation. Using a dual bed arrangement, we have demonstrated the synthesis of MTBE from syngas and iso-butylene.

  17. Calculation of Vapor-Liquid-Liquid Equilibria for the Fischer-Tropsch Reactor Effluents using Modified Peng-Robinson

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Calculation of Vapor-Liquid-Liquid Equilibria for the Fischer- Tropsch Reactor Effluents using ignored the non-ideal phase equilibrium problem of a FT reactor. The rigorous calculation method is based A modified Peng­Robinson equation of state is used to develop the methods for calculating the thermodynamic

  18. Ultra-clean Fischer-Tropsch (F-T) Fuels Production and Demonstration Project

    SciTech Connect (OSTI)

    Stephen P. Bergin

    2006-06-30T23:59:59.000Z

    The objective of the DOE-NETL Fischer-Tropsch (F-T) Production and Demonstration Program was to produce and evaluate F-T fuel derived from domestic natural gas. The project had two primary phases: (1) fuel production of ultra-clean diesel transportation fuels from domestic fossil resources; and (2) demonstration and performance testing of these fuels in engines. The project also included a well-to-wheels economic analysis and a feasibility study of small-footprint F-T plants (SFPs) for remote locations such as rural Alaska. During the fuel production phase, ICRC partnered and cost-shared with Syntroleum Corporation to complete the mechanical design, construction, and operation of a modular SFP that converts natural gas, via F-T and hydro-processing reactions, into hydrogensaturated diesel fuel. Construction of the Tulsa, Oklahoma plant started in August 2002 and culminated in the production of over 100,000 gallons of F-T diesel fuel (S-2) through 2004, specifically for this project. That fuel formed the basis of extensive demonstrations and evaluations that followed. The ultra-clean F-T fuels produced had virtually no sulfur (less than 1 ppm) and were of the highest quality in terms of ignition quality, saturation content, backend volatility, etc. Lubricity concerns were investigated to verify that commercially available lubricity additive treatment would be adequate to protect fuel injection system components. In the fuel demonstration and testing phase, two separate bus fleets were utilized. The Washington DC Metropolitan Area Transit Authority (WMATA) and Denali National Park bus fleets were used because they represented nearly opposite ends of several spectra, including: climate, topography, engine load factor, mean distance between stops, and composition of normally used conventional diesel fuel. Fuel evaluations in addition to bus fleet demonstrations included: bus fleet emission measurements; F-T fuel cold weather performance; controlled engine dynamometer lab evaluation; cold-start test-cell evaluations; overall feasibility, economics, and efficiency of SFP fuel production; and an economic analysis. Two unexpected issues that arose during the project were further studied and resolved: variations in NOx emissions were accounted for and fuel-injection nozzle fouling issues were traced to the non-combustible (ash) content of the engine oil, not the F-T fuel. The F-T fuel domestically produced and evaluated in this effort appears to be a good replacement candidate for petroleum-based transportation fuels. However, in order for domestic F-T fuels to become a viable cost-comparable alternative to petroleum fuels, the F-T fuels will need to be produced from abundant U.S. domestic resources such as coal and biomass, rather than stranded natural gas.

  19. Fischer-Tropsch Synthesis: Characterization and Reaction Testing of Cobalt Carbide

    SciTech Connect (OSTI)

    Khalid S.; Mohandas J.C.; Gnanamani M.K.; Jacobs G.; Ma W.; Ji Y.; Davis B.H.

    2011-08-15T23:59:59.000Z

    Hydrogenation of carbon monoxide was investigated for cobalt carbide synthesized from Co{sub 3}O{sub 4} by CO carburization in a fixed-bed reactor. The cobalt carbide synthesized was characterized by BET surface area, X-ray diffraction, scanning electron microscopy, X-ray absorption near edge spectroscopy, and extended X-ray absorption fine structure spectroscopy. The catalysts were tested in the slurry phase using a continuously stirred tank reactor at P = 2.0 MPa, H{sub 2}/CO = 2:1 in the temperature range of 493-523 K, and with space velocities varying from 1 to 3 Nl h{sup -1} g{sub cat}{sup -1}. The results strongly suggest that a fraction of cobalt converts to a form with greater metallic character under the conditions employed. This was more pronounced on a Fischer-Tropsch synthesis run conducted at a higher temperature (523 versus 493 K).

  20. Sensitivity of Fischer-Tropsch Synthesis and Water-Gas Shift Catalysts to Poisons from High-Temperature High-Pressure Entrained-Flow (EF) Oxygen-Blown Gasifier Gasification of Coal/Biomass Mixtures

    SciTech Connect (OSTI)

    Burton Davis; Gary Jacobs; Wenping Ma; Dennis Sparks; Khalid Azzam; Janet Chakkamadathil Mohandas; Wilson Shafer; Venkat Ramana Rao Pendyala

    2011-09-30T23:59:59.000Z

    There has been a recent shift in interest in converting not only natural gas and coal derived syngas to Fischer-Tropsch synthesis products, but also converting biomass-derived syngas, as well as syngas derived from coal and biomass mixtures. As such, conventional catalysts based on iron and cobalt may not be suitable without proper development. This is because, while ash, sulfur compounds, traces of metals, halide compounds, and nitrogen-containing chemicals will likely be lower in concentration in syngas derived from mixtures of coal and biomass (i.e., using entrained-flow oxygen-blown gasifier gasification gasification) than solely from coal, other compounds may actually be increased. Of particular concern are compounds containing alkali chemicals like the chlorides of sodium and potassium. In the first year, University of Kentucky Center for Applied Energy Research (UK-CAER) researchers completed a number of tasks aimed at evaluating the sensitivity of cobalt and iron-based Fischer-Tropsch synthesis (FT) catalysts and a commercial iron-chromia high temperature water-gas shift catalyst (WGS) to alkali halides. This included the preparation of large batches of 0.5%Pt-25%Co/Al{sub 2}O{sub 3} and 100Fe: 5.1Si: 3.0K: 2.0Cu (high alpha) catalysts that were split up among the four different entities participating in the overall project; the testing of the catalysts under clean FT and WGS conditions; the testing of the Fe-Cr WGS catalyst under conditions of co-feeding NaCl and KCl; and the construction and start-up of the continuously stirred tank reactors (CSTRs) for poisoning investigations. In the second and third years, researchers from the University of Kentucky Center for Applied Energy Research (UK-CAER) continued the project by evaluating the sensitivity of a commercial iron-chromia high temperature water-gas shift catalyst (WGS) to a number of different compounds, including KHCO{sub 3}, NaHCO{sub 3}, HCl, HBr, HF, H{sub 2}S, NH{sub 3}, and a combination of H{sub 2}S and NH{sub 3}. Cobalt and iron-based Fischer-Tropsch synthesis (FT) catalysts were also subjected to a number of the same compounds in order to evaluate their sensitivities at different concentration levels of added contaminant.

  1. Kinetic studies for elucidation of the promoter effect of alkali in Fischer-Tropsch iron catalysts

    SciTech Connect (OSTI)

    Herzog, K.; Gaube, J. (Institut fuer Chemische Technologie der Technischen Hochschule Darmstadt, Darmstadt (West Germany))

    1989-02-01T23:59:59.000Z

    The kinetics of the formation of hydrocarbons in Fischer-Tropsch synthesis and of consecutive reactions, i.e., hydrogenation and double bond isomerization of primarily formed 1-alkenes, were studied in a slurry-phase reactor using alkalized and nonalkalized precipitated iron catalysts. Both consecutive reactions have an order of about -2 with respect to carbon monoxide and an order of about 1 with respect to 1-alkenes. The order with respect to hydrogen is 1 for the hydrocarbon formation and also 1 for the consecutive hydrogenation, but 0 for the consecutive isomerization. The reaction orders are not changed by addition of K{sub 2}CO{sub 3} to the catalyst. The kinetics of consecutive reactions can be interpreted by competitive adsorption of 1-alkene and carbon monoxide. Alkali addition causes an increase in the strength of carbon monoxide adsorption and consequently a decrease in 1-alkene adsorption so that the rates of the consecutive reactions are reduced. This hypothesis could be proved by studies of 1-hexene hydrogenation in the presence and absence of carbon monoxide for alkalized and nonalkalized iron catalysts. The kinetics were studied in the ranges 1.3 < P{sub CO}(10{sup 5} Pa) < 7, 1.6 < P{sub H{sub 2}}(10{sup 5} Pa) < 9, and 490 K < T < 530 K.

  2. Incorporation of catalytic dehydrogenation into Fischer-Tropsch synthesis to lower carbon dioxide emissions

    DOE Patents [OSTI]

    Huffman, Gerald P

    2012-09-18T23:59:59.000Z

    A method for producing liquid fuels includes the steps of gasifying a starting material selected from a group consisting of coal, biomass, carbon nanotubes and mixtures thereof to produce a syngas, subjecting that syngas to Fischer-Tropsch synthesis (FTS) to produce a hyrdrocarbon product stream, separating that hydrocarbon product stream into C1-C4 hydrocarbons and C5+ hydrocarbons to be used as liquid fuels and subjecting the C1-C4 hydrocarbons to catalytic dehydrogenation (CDH) to produce hydrogen and carbon nanotubes. The hydrogen produced by CDH is recycled to be mixed with the syngas incident to the FTS reactor in order to raise the hydrogen to carbon monoxide ratio of the syngas to values of 2 or higher, which is required to produce liquid hydrocarbon fuels. This is accomplished with little or no production of carbon dioxide, a greenhouse gas. The carbon is captured in the form of a potentially valuable by-product, multi-walled carbon nanotubes (MWNT), while huge emissions of carbon dioxide are avoided and very large quantities of water employed for the water-gas shift in traditional FTS systems are saved.

  3. ULTRA-CLEAN FISCHER-TROPSCH FUELS PRODUCTION AND DEMONSTRATION PROJECT

    SciTech Connect (OSTI)

    Steve Bergin

    2003-10-17T23:59:59.000Z

    The Syntroleum plant is mechanically complete and currently undergoing start-up. The fuel production and demonstration plan is near completion. The study on the impact of small footprint plant (SFP) fuel on engine performance is about half-completed. Cold start testing has been completed. Preparations have been completed for testing the fuel in diesel electric generators in Alaska. Preparations are in progress for testing the fuel in bus fleets at Denali National Park and the Washington Metropolitan Transit Authority. The experiments and analyses conducted during this project show that Fischer-Tropsch (FT) gas-to-liquid diesel fuel can easily be used in a diesel engine with little to no modifications. Additionally, based on the results and discussion presented, further improvements in performance and emissions can be realized by configuring the engine to take advantage of FT diesel fuel's properties. The FT fuel also shows excellent cold start properties and enabled the engine tested to start at more the ten degrees than traditional fuels would allow. This plant produced through this project will produce large amounts of FT fuel. This will allow the fuel to be tested extensively, in current, prototype, and advanced diesel engines. The fuel may also contribute to the nation's energy security. The military has expressed interest in testing the fuel in aircraft and ground vehicles.

  4. Baseline design/economics for advanced Fischer-Tropsch technology. Quarterly report, January--March 1992

    SciTech Connect (OSTI)

    Not Available

    1992-09-01T23:59:59.000Z

    The objectives of the study are to: Develop a baseline design for indirect liquefaction using advanced Fischer-Tropsch (F-T) technology. Prepare the capital and operating costs for the baseline design. Develop a process flow sheet simulation (PFS) model. This report summarizes the activities completed during the period December 23, 1992 through March 15, 1992. In Task 1, Baseline Design and Alternates, the following activities related to the tradeoff studies were completed: approach and basis; oxygen purity; F-T reactor pressure; wax yield; autothermal reformer; hydrocarbons (C{sub 3}/C{sub 4}s) recovery; and hydrogenrecovery. In Task 3, Engineering Design Criteria, activities were initiated to support the process tradeoff studies in Task I and to develop the environmental strategy for the Illinois site. The work completed to date consists of the development of the F-T reactor yield correlation from the Mobil dam and a brief review of the environmental strategy prepared for the same site in the direct liquefaction baseline study.Some work has also been done in establishing site-related criteria, in establishing the maximum vessel diameter for train sizing and in coping with the low H{sub 2}/CO ratio from the Shell gasifier. In Task 7, Project Management and Administration, the following activities were completed: the subcontract agreement between Amoco and Bechtel was negotiated; a first technical progress meeting was held at the Bechtel office in February; and the final Project Management Plan was approved by PETC and issued in March 1992.

  5. Development of a Fischer-Tropsch Gasoline Process for the Steam Hydrogasification Technology

    E-Print Network [OSTI]

    Li, Yang

    2013-01-01T23:59:59.000Z

    aromatics production from syngas. Mo/HZSM-5 catalyst hadwith CO 2 containing syngas mixture. The product liquid isfor   biomass-­?derived  syngas,  2003,  DTIC  Document.  

  6. Synthesis of octane enhancer during slurry-phase Fischer-Tropsch. Quarterly technical progress report No. 4, July 1, 1991--September 30, 1991

    SciTech Connect (OSTI)

    Marcelin, G.

    1991-12-15T23:59:59.000Z

    The objective of this project is to investigate three possible routes to the formation of ethers, in particular methyl tert-butyl ether (MTBE), during slurry phase Fischer-Tropsch reaction. The three reaction schemes to be investigated are: Addition of isobutylene during the formation of methanol and/or higher alcohols directly from CO and H{sub 2} during slurry-phase Fischer-Tropsch. Addition of isobutylene to FT liquid products including alcohols in a slurry-phase reactor containing an MTBE or other acid catalyst. Addition of methanol to slurry phase FT synthesis making iso-olefins.

  7. Synthesis of octane enhancers during slurry-phase Fischer-Tropsch. Quarterly technical progress report No. 5, October 1, 1991--December 31, 1991

    SciTech Connect (OSTI)

    Marcelin, G.

    1992-06-10T23:59:59.000Z

    The objective of this project is to investigate three possible routes to the formation of ethers, in particular methyl tert-butyl ether (MTBE), during slurry phase Fischer-Tropsch reaction. The three reaction schemes to be investigated are: Addition of isobutylene during the formation of methanol and/or higher alcohols directly from CO and H{sub 2} during slurry-phase Fischer-Tropsch. Addition of isobutylene to FT liquid products including alcohols in a slurry-phase reactor containing an MTBE or other acid catalyst. Addition of methanol to slurry phase FT synthesis making iso-olefins.

  8. Synthesis of octane enhancers during slurry-phase Fischer-Tropsch. Quarterly technical progress report No. 3, April 1, 1991--June 30, 1991

    SciTech Connect (OSTI)

    Marcelin, G.

    1991-10-15T23:59:59.000Z

    The objective of this project is to investigate three possible routes to the formation of ethers, in particular methyl tert-butytl ether (MTBE), during slurry phase Fischer-Tropsch reaction. The three reaction schemes to be investigated are: (1) Addition of isobutylene during the formation of methanol and/or higher alcohols directly from CO and H{sub 2} during slurry-phase Fischer-Tropsch; (2) addition of isobutylene to FT liquid products including alcohols in a slurry-phase reactor containing an MTBE or other acid catalyst; and, (3) addition of methanol to slurry phase FT synthesis making iso-olefins.

  9. SEPARATION OF FISCHER-TROPSCH WAX PRODUCTS FROM ULTRAFINE IRON CATALYST PARTICLES

    SciTech Connect (OSTI)

    James K. Neathery; Gary Jacobs; Burtron H. Davis

    2005-03-31T23:59:59.000Z

    In this reporting period, a fundamental filtration study was continued to investigate the separation of Fischer-Tropsch Synthesis (FTS) liquids from iron-based catalyst particles. The overall focus of the program is with slurry-phase FTS in slurry bubble column reactor systems. Hydrocarbon products must be separated from catalyst particles before being removed from the reactor system. An efficient wax product/catalyst separation system is a key factor for optimizing operating costs for iron-based slurry-phase FTS. Previous work has focused on catalyst particle attrition and the formation of ultra-fine iron carbide and/or carbon particles. With the current study, we are investigating how the filtration properties are affected by these chemical and physical changes of the catalyst slurry during activation/synthesis. In this reporting period, a series of crossflow filtration experiments were initiated to study the effect of olefins and oxygenates on the filtration flux and membrane performance. Iron-based FTS reactor waxes contain a significant amount of oxygenates, depending on the catalyst formulation and operating conditions. Mono-olefins and aliphatic alcohols were doped into an activated iron catalyst slurry (with Polywax) to test their influence on filtration properties. The olefins were varied from 5 to 25 wt% and oxygenates from 6 to 17 wt% to simulate a range of reactor slurries reported in the literature. The addition of an alcohol (1-dodecanol) was found to decrease the permeation rate while the olefin added (1-hexadecene) had no effect on the permeation rate. A passive flux maintenance technique was tested that can temporarily increase the permeate rate for 24 hours.

  10. SEPARATION OF FISCHER-TROPSCH WAX PRODUCTS FROM ULTRAFINE IRON CATALYST PARTICLES

    SciTech Connect (OSTI)

    James K. Neathery; Gary Jacobs; Burtron H. Davis

    2004-09-30T23:59:59.000Z

    In this reporting period, a fundamental filtration study was continued to investigate the separation of Fischer-Tropsch Synthesis (FTS) liquids from iron-based catalyst particles. The overall focus of the program is with slurry-phase FTS in slurry bubble column reactor systems. Hydrocarbon products must be separated from catalyst particles before being removed from the reactor system. An efficient wax product/catalyst separation system is a key factor for optimizing operating costs for iron-based slurry-phase FTS. Previous work has focused on catalyst particle attrition and the formation of ultra-fine iron carbide and/or carbon particles. With the current study, we are investigating how the filtration properties are affected by these chemical and physical changes of the catalyst slurry during activation/synthesis. The shakedown phase of the pilot-scale filtration platform was completed at the end of the last reporting period. A study of various molecular weight waxes was initiated to determine the effect of wax physical properties on the permeation rate without catalyst present. As expected, the permeation flux was inversely proportional to the nominal average molecular weight of the polyethylene wax. Even without catalyst particles present in the filtrate, the filtration membranes experience fouling during an induction period on the order of days on-line. Another long-term filtration test was initiated using a batch of iron catalyst that was previously activated with CO to form iron carbide in a separate continuous stirred tank reactor (CSTR) system. The permeation flux stabilized more rapidly than that experienced with unactivated catalyst tests.

  11. Separation of Fischer-Tropsch Wax Products from Ultrafine Iron Catalyst Particles

    SciTech Connect (OSTI)

    James K. Neathery; Gary Jacobs; Amitava Sarkar; Burtron H. Davis

    2005-09-30T23:59:59.000Z

    In this reporting period, a study of ultra-fine iron catalyst filtration was initiated to study the behavior of ultra-fine particles during the separation of Fischer-Tropsch Synthesis (FTS) liquids filtration. The overall focus of the program is with slurry-phase FTS in slurry bubble column reactor systems. Hydrocarbon products must be separated from catalyst particles before being removed from the reactor system. An efficient wax product/catalyst separation system is a key factor for optimizing operating costs for iron-based slurry-phase FTS. Previous work has focused on catalyst particle attrition and the formation of ultra-fine iron carbide and/or carbon particles. With the current study, we are investigating how the filtration properties are affected by these chemical and physical changes of the catalyst slurry during activation/synthesis. The change of particle size during the slurry-phase FTS has monitored by withdrawing catalyst sample at different TOS. The measurement of dimension of the HRTEM images of samples showed a tremendous growth of the particles. Carbon rims of thickness 3-6 nm around the particles were observed. This growth in particle size was not due to carbon deposition on the catalyst. A conceptual design and operating philosophy was developed for an integrated wax filtration system for a 4 liter slurry bubble column reactor to be used in Phase II of this research program. The system will utilize a primary inertial hydroclone followed by a Pall Accusep cross-flow membrane. Provisions for cleaned permeate back-pulsing will be included to as a flux maintenance measure.

  12. Synthesis of octane enhancers during slurry-phase Fischer-Tropsch. [801Methyl tert-butyl ether

    SciTech Connect (OSTI)

    Marcelin, G.

    1992-06-24T23:59:59.000Z

    The objective of this project is to investigate three possible routes to the formation of ethers, in particular methyl tert-butyl ether (MTBE), during slurry phase Fischer-Tropsch reaction. The three reaction schemes to be investigated are: (1) Addition of isobutylene during the formation of methanol and/or higher alcohols directly from CO and H{sub 2} during slurry-phase Fischer-Tropsch. (2) Addition of isobutylene to FT liquid products including alcohols in a slurry-phase reactor containing an MTBE or other acid catalyst. (3) Addition of methanol to slurry phase FT synthesis making iso-olefins. During the sixth quarter we completed the construction of the slurry bubble column reactor (SBCR), conducted initial shake-down experiments in a cold-flow mode, and finalized the selection process of the acid catalysts for conversion of syngas-produced alcohols and isobutylene to MTBE (scheme 2). Tasks 3, 4, and 5 are awaiting complete implementation of the SBCR system.

  13. Effect of Surface Modification by Chelating Agents on Fischer- Tropsch Performance of Co/SiO{sub 2} Catalysts

    SciTech Connect (OSTI)

    Bambal, Ashish S.; Kugler, Edwin L.; Gardner, Todd H.; Dadyburjor, Dady B.

    2013-11-27T23:59:59.000Z

    The silica support of a Co-based catalyst for Fischer-Tropsch (FT) synthesis was modified by the chelating agents (CAs) nitrilotriacetic acid (NTA) and ethylenediaminetetraacetic acid (EDTA). After the modification, characterization of the fresh and spent catalysts show reduced crystallite sizes, a better-dispersed Co{sub 3}O{sub 4} phase on the calcined samples, and increased metal dispersions for the reduced samples. The CA-modified catalysts display higher CO conversions, product yields, reaction rates and rate constants. The improved FT performance of CA-modified catalysts is attributed to the formation of stable complexes with Co. The superior performance of the EDTA-modified catalyst in comparison to the NTA-modified catalyst is due to the higher affinity of the former for complex formation with Co ions.

  14. Platinum-Modulated Cobalt Nanocatalysts for Low-Temperature Aqueous-Phase Fischer-Tropsch Synthesis

    E-Print Network [OSTI]

    Li, Weixue

    catalytic process for liquid fuel generation, which converts coal/shale gas/biomass-derived syngas (a century. Since it is now possible to use diverse resources, such as coal, biomass, and shale gas Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academic of Sciences, Dalian, 116023

  15. Evaluation of a biomass derived oil for use as additive in paving asphalt

    SciTech Connect (OSTI)

    Houde, J. Jr.; Clelland, I.; Sawatzky, H. [CANMET, Ottawa, Ontario (Canada)

    1995-12-31T23:59:59.000Z

    Treatment and disposal costs of sewage sludge can represent up to 50% of a municipality`s annual wastewater treatment budget. Sewage sludge (30% solids) accounts 5% of Canadian landfill by weight, and the ever increasing volume of sludge coupled with the decreasing options available for disposal creates a growing problem for major municipalities. Current disposal options are agricultural application, incineration and landfill. Concern about heavy metal migration and public pressure to find a local solution has severely curtailed the spreading of sludge on agricultural land. Incineration is the major option for larger centers but the relatively high cost for incineration, ranging from $350 to $1000/t dry sludge, has caused a great deal of interest in methods of improving the cost effectiveness of incineration or in new equivalent technologies. The high cost and more stringent environmental regulations for incinerating municipal sludges have led to developing more efficient sludge management technologies that are not agricultural based. This paper describes applications of oils from sludge processing.

  16. Slurry phase Fischer-Tropsch synthesis: Cobalt plus a water-gas shift catalyst. [Quarterly] report, June 30, 1988--September 30, 1988

    SciTech Connect (OSTI)

    Yates, I.C.; Satterfield, C.N.

    1988-12-31T23:59:59.000Z

    This report details experiments performed on three different copper-based catalysts: Cu/Cr{sub 2}O{sub 3}, Cu/MnO/Cr{sub 2}O{sub 3} and Cu/ZnO/Al{sub 2}O{sub 3}. Of these three catalysts, the Cu/ZnO/Al{sub 2}O{sub 3} exhibits the greatest stability when slurried in octacosane. More than 1000 hours-on-stream indicate that the catalyst activity is not detrimentally affected by high pressure, high H{sub 2}/CO ratio, or the presence of alkenes. All of these are necessary stability characteristics for the water-gas shift catalyst, if it is to be used in combination with a cobalt Fischer-Tropsch catalyst. A review of documented reduction procedures for cobalt-based Fischer-Tropsch catalysts is presented.

  17. FischerTropsch synthesis on a model Co/SiO2 catalyst , Zhoujun Wang a

    E-Print Network [OSTI]

    Goodman, Wayne

    , although made vulnerable by the dramatic changes in crude oil prices, is still one of the few technologies and Texas A&M University, College Station, TX 77843, United States a r t i c l e i n f o Article history on crude oil, and much effort has been made to develop renewable energy technologies, such as solar, wind

  18. Fischer-Tropsch slurry phase process variations to understand wax formations: Quarterly report for period October 1, 1987 to December 31, 1987

    SciTech Connect (OSTI)

    Satterfield, C.N.

    1987-01-01T23:59:59.000Z

    Effects of high syngas conversion on the secondary reactions of olefins formed by Fischer-Tropsch synthesis on a reduced fused magnetite catalyst were simulated by studies of olefins in the presence of hydrogen and low concentrations of CO, or none at all. kinetic models were developed for the effect of CO partial pressure on hydrogenation rates at 232)degree)C and 0.30 to 0.79 MPa. In the absence of carbon monoxide, olefin hydrogenation was more rapid than in its presence. A model indicated that a hydrogenated carbon monoxide species on the catalyst may be responsible for the inhibition of olefin hydrogenation, and that olefin adsorption is rate-limiting. The formation of secondary olefins appeared to follow similar trends with carbon monoxide partial pressure. Olefin incorporation was not observed in the small amount of Fischer-Tropsch products obtained in these experiments. The chain growth probability, alpha, appeared to correlate with the H/sub 2/CO feed ratio. 14 refs., 13 figs., 1 tab.

  19. Synthesis of octane enhancers during slurry-phase Fischer-Tropsch. Quarterly technical progress report No. 6, January 1, 1992--March 31, 1992

    SciTech Connect (OSTI)

    Marcelin, G.

    1992-06-24T23:59:59.000Z

    The objective of this project is to investigate three possible routes to the formation of ethers, in particular methyl tert-butyl ether (MTBE), during slurry phase Fischer-Tropsch reaction. The three reaction schemes to be investigated are: (1) Addition of isobutylene during the formation of methanol and/or higher alcohols directly from CO and H{sub 2} during slurry-phase Fischer-Tropsch. (2) Addition of isobutylene to FT liquid products including alcohols in a slurry-phase reactor containing an MTBE or other acid catalyst. (3) Addition of methanol to slurry phase FT synthesis making iso-olefins. During the sixth quarter we completed the construction of the slurry bubble column reactor (SBCR), conducted initial shake-down experiments in a cold-flow mode, and finalized the selection process of the acid catalysts for conversion of syngas-produced alcohols and isobutylene to MTBE (scheme 2). Tasks 3, 4, and 5 are awaiting complete implementation of the SBCR system.

  20. Synthesis of octane enhancers during slurry-phase Fischer-Tropsch. Quarterly technical progress report No. 7, April 1, 1992--June 30, 1992

    SciTech Connect (OSTI)

    Marcelin, G.

    1992-09-24T23:59:59.000Z

    The objective of this project is to investigate three possible routes to the formation of ethers, in particular methyl tert-butyl (MTBE), during slurry phase Fischer-Tropsch reaction. The three reaction schemes to be investigated are: addition of i-butylene during the formation of methanol and/or higher alcohols directly from CO and H{sub 2} during slurry-phase Fischer-Tropsch; addition of i-butylene to FT liquid products including alcohols in a slurry-phase reactor containing an MTBE or other acid catalyst; and addition of methanol to slurry phase FT synthesis making iso-olefins. During the seventh quarter we continued the shake down experiments for the SBCR and conducted an initial aborted run. We have also re-started experiments on Scheme 1, i.e., the addition of iso-butylene during CO hydrogenation. Using a dual bed arrangement, we have demonstrated the synthesis of MTBE from syngas and iso-butylene.

  1. The upgrading of Fischer-Tropsch liquids over ZSM-5 using model compounds

    E-Print Network [OSTI]

    Smith, David Duane

    1982-01-01T23:59:59.000Z

    . Using the synthetic oxygenate mixture the selectivity of aromatics and LPG increasec with temperature at the expense of lower olerins and C5+ oils. The methane selectivity was very low. At a temperature of 573 K the aromatic yield was 5. s weight.... 1 percent LPG. The remainder was ethylene, propylene, and a small amount of 23 methane. The 1-butane however yielcea 30. 1 precent aromatics, 27. 3 percent oils ana 32. 3 percent LPG. The increase in aromatic yiela from 1-butene when compared...

  2. DEVELOPMENT OF A COMPUTATIONAL MULTIPHASE FLOW MODEL FOR FISCHER TROPSCH SYNTHESIS IN A SLURRY BUBBLE COLUMN REACTOR

    SciTech Connect (OSTI)

    Donna Post Guillen; Tami Grimmett; Anastasia M. Gribik; Steven P. Antal

    2010-09-01T23:59:59.000Z

    The Hybrid Energy Systems Testing (HYTEST) Laboratory is being established at the Idaho National Laboratory to develop and test hybrid energy systems with the principal objective to safeguard U.S. Energy Security by reducing dependence on foreign petroleum. A central component of the HYTEST is the slurry bubble column reactor (SBCR) in which the gas-to-liquid reactions will be performed to synthesize transportation fuels using the Fischer Tropsch (FT) process. SBCRs are cylindrical vessels in which gaseous reactants (for example, synthesis gas or syngas) is sparged into a slurry of liquid reaction products and finely dispersed catalyst particles. The catalyst particles are suspended in the slurry by the rising gas bubbles and serve to promote the chemical reaction that converts syngas to a spectrum of longer chain hydrocarbon products, which can be upgraded to gasoline, diesel or jet fuel. These SBCRs operate in the churn-turbulent flow regime which is characterized by complex hydrodynamics, coupled with reacting flow chemistry and heat transfer, that effect reactor performance. The purpose of this work is to develop a computational multiphase fluid dynamic (CMFD) model to aid in understanding the physico-chemical processes occurring in the SBCR. Our team is developing a robust methodology to couple reaction kinetics and mass transfer into a four-field model (consisting of the bulk liquid, small bubbles, large bubbles and solid catalyst particles) that includes twelve species: (1) CO reactant, (2) H2 reactant, (3) hydrocarbon product, and (4) H2O product in small bubbles, large bubbles, and the bulk fluid. Properties of the hydrocarbon product were specified by vapor liquid equilibrium calculations. The absorption and kinetic models, specifically changes in species concentrations, have been incorporated into the mass continuity equation. The reaction rate is determined based on the macrokinetic model for a cobalt catalyst developed by Yates and Satterfield [1]. The model includes heat generation due to the exothermic chemical reaction, as well as heat removal from a constant temperature heat exchanger. Results of the CMFD simulations (similar to those shown in Figure 1) will be presented.

  3. Biomass-derived Syngas Utilization for Fuels and Chemicals - Final Report

    SciTech Connect (OSTI)

    David C. Dayton

    2010-03-24T23:59:59.000Z

    Executive Summary The growing gap between petroleum production and demand, mounting environmental concerns, and increasing fuel prices have stimulated intense interest in research and development (R&D) of alternative fuels, both synthetic and bio-derived. Currently, the most technically defined thermochemical route for producing alternative fuels from lignocellulosic biomass involves gasification/reforming of biomass to produce syngas (carbon monoxide [CO] + hydrogen [H2]), followed by syngas cleaning, Fischer-Tropsch synthesis (FTS) or mixed alcohol synthesis, and some product upgrading via hydroprocessing or separation. A detailed techno-economic analysis of this type of process has recently been published [1] and it highlights the need for technical breakthroughs and technology demonstration for gas cleanup and fuel synthesis. The latter two technical barrier areas contribute 40% of the total thermochemical ethanol cost and 70% of the production cost, if feedstock costs are factored out. Developing and validating technologies that reduce the capital and operating costs of these unit operations will greatly reduce the risk for commercializing integrated biomass gasification/fuel synthesis processes for biofuel production. The objective of this project is to develop and demonstrate new catalysts and catalytic processes that can efficiently convert biomass-derived syngas into diesel fuel and C2-C4 alcohols. The goal is to improve the economics of the processes by improving the catalytic activity and product selectivity, which could lead to commercialization. The project was divided into 4 tasks: Task 1: Reactor Systems: Construction of three reactor systems was a project milestone. Construction of a fixed-bed microreactor (FBR), a continuous stirred tank reactor (CSTR), and a slurry bubble column reactor (SBCR) were completed to meet this milestone. Task 2: Iron Fischer-Tropsch (FT) Catalyst: An attrition resistant iron FT catalyst will be developed and tested. Task 3: Chemical Synthesis: Promising process routes will be identified for synthesis of selected chemicals from biomass-derived syngas. A project milestone was to select promising mixed alcohol catalysts and screen productivity and performance in a fixed bed micro-reactor using bottled syngas. This milestone was successfully completed in collaboration withour catalyst development partner. Task 4: Modeling, Engineering Evaluation, and Commercial Assessment: Mass and energy balances of conceptual commercial embodiment for FT and chemical synthesis were completed.

  4. EA-1642-S1: Small-Scale Pilot Plant for the Gasification of Coal and Coal-Biomass Blends and Conversion of Derived Syngas to Liquid Fuels via Fischer-Tropsch Synthesis, Lexington, KY

    Broader source: Energy.gov [DOE]

    This draft Supplemental Environmental Assessment (SEA) analyzes the potential environmental impacts of DOE’s proposed action of providing cost-shared funding for the University of Kentucky (UK) Center for Applied Energy Research (CAER) Small-Scale Pilot Plant for the Gasification of Coal and Coal-Biomass Blends and Conversion of Derived Syngas to Liquid Fuels via Fischer-Tropsch Synthesis project and of the No-Action Alternative.

  5. Six-flow operations for catalyst development in Fischer-Tropsch synthesis: Bridging the gap between high-throughput experimentation and extensive product evaluation

    SciTech Connect (OSTI)

    Sartipi, Sina, E-mail: S.Sartipi@tudelft.nl, E-mail: J.Gascon@tudelft.nl; Jansma, Harrie; Bosma, Duco; Boshuizen, Bart; Makkee, Michiel; Gascon, Jorge, E-mail: S.Sartipi@tudelft.nl, E-mail: J.Gascon@tudelft.nl; Kapteijn, Freek [Department of Chemical Engineering, Catalysis Engineering, Delft University of Technology, Julianalaan 136, 2628 BL Delft (Netherlands)] [Department of Chemical Engineering, Catalysis Engineering, Delft University of Technology, Julianalaan 136, 2628 BL Delft (Netherlands)

    2013-12-15T23:59:59.000Z

    Design and operation of a “six-flow fixed-bed microreactor” setup for Fischer-Tropsch synthesis (FTS) is described. The unit consists of feed and mixing, flow division, reaction, separation, and analysis sections. The reactor system is made of five heating blocks with individual temperature controllers, assuring an identical isothermal zone of at least 10 cm along six fixed-bed microreactor inserts (4?mm inner diameter). Such a lab-scale setup allows running six experiments in parallel, under equal feed composition, reaction temperature, and conditions of separation and analysis equipment. It permits separate collection of wax and liquid samples (from each flow line), allowing operation with high productivities of C5+ hydrocarbons. The latter is crucial for a complete understanding of FTS product compositions and will represent an advantage over high-throughput setups with more than ten flows where such instrumental considerations lead to elevated equipment volume, cost, and operation complexity. The identical performance (of the six flows) under similar reaction conditions was assured by testing a same catalyst batch, loaded in all microreactors.

  6. Assessment of fuel-cycle energy use and greenhouse gas emissions for Fischer-Tropsch diesel from coal and cellulosic biomass.

    SciTech Connect (OSTI)

    Xie, X.; Wang, M.; Han, J. (Energy Systems)

    2011-04-01T23:59:59.000Z

    This study expands and uses the GREET (Greenhouse Gases, Regulated Emissions, and Energy Use in Transportation) model to assess the effects of carbon capture and storage (CCS) technology and cellulosic biomass and coal cofeeding in Fischer-Tropsch (FT) plants on energy use and greenhouse gas (GHG) emissions of FT diesel (FTD). To demonstrate the influence of the coproduct credit methods on FTD life-cycle analysis (LCA) results, two allocation methods based on the energy value and the market revenue of different products and a hybrid method are employed. With the energy-based allocation method, fossil energy use of FTD is less than that of petroleum diesel, and GHG emissions of FTD could be close to zero or even less than zero with CCS when forest residue accounts for 55% or more of the total dry mass input to FTD plants. Without CCS, GHG emissions are reduced to a level equivalent to that from petroleum diesel plants when forest residue accounts for 61% of the total dry mass input. Moreover, we show that coproduct method selection is crucial for LCA results of FTD when a large amount of coproducts is produced.

  7. Analysis of Nitro-Polycyclic Aromatic Hydrocarbons in Conventional Diesel and Fischer--Tropsch Diesel Fuel Emissions Using Electron Monochromator-Mass Spectrometry

    SciTech Connect (OSTI)

    Havey, C. D.; McCormick, R. L.; Hayes, R. R.; Dane, A. J.; Voorhees, K. J.

    2006-01-01T23:59:59.000Z

    The presence of nitro-polycyclic aromatic hydrocarbons (NPAHs) in diesel fuel emissions has been studied for a number of years predominantly because of their contribution to the overall health and environmental risks associated with these emissions. Electron monochromator-mass spectrometry (EM-MS) is a highly selective and sensitive method for detection of NPAHs in complex matrixes, such as diesel emissions. Here, EM-MS was used to compare the levels of NPAHs in fuel emissions from conventional (petroleum) diesel, ultra-low sulfur/low-aromatic content diesel, Fischer-Tropsch synthetic diesel, and conventional diesel/synthetic diesel blend. The largest quantities of NPAHs were detected in the conventional diesel fuel emissions, while the ultra-low sulfur diesel and synthetic diesel fuel demonstrated a more than 50% reduction of NPAH quantities when compared to the conventional diesel fuel emissions. The emissions from the blend of conventional diesel with 30% synthetic diesel fuel also demonstrated a more than 30% reduction of the NPAH content when compared to the conventional diesel fuel emissions. In addition, a correlation was made between the aromatic content of the different fuel types and NPAH quantities and between the nitrogen oxides emissions from the different fuel types and NPAH quantities. The EM-MS system demonstrated high selectivity and sensitivity for detection of the NPAHs in the emissions with minimal sample cleanup required.

  8. New approach to the generation of metal-bearing, medium-pore, shape-selective zeolites for Fischer-Tropsch catalysis. Spectroscopic studies of zeolites

    SciTech Connect (OSTI)

    Iton, L.E.; Beal, R.B.; Hodul, D.T.

    1983-01-01T23:59:59.000Z

    Two recent developments in zeolite synthesis and modification were successfully combined to demonstrate a new approach to the generation of metal-bearing, medium-pore, shape-selective zeolites for use as catalysts in Fischer-Tropsch conversions. The steps are: (1) synthesis of an aluminoferrisilicate zeolite having the ZSM-5-type structure; (2) removal of the organic base template incorporated in the channel system during synthesis; (3) formation of a polycyano inclusion compound in the AFS zeolite; and (4) reduction of the inclusion compound by hydrogen at approx. 400/sup 0/C. PAS and EPR spectroscopy have been used to establish that the as-synthesized AFS zeolite contains Fe/sup 3 +/ ions in both framework and non-framework sites. FMR spectroscopy has been used to confirm the formation of the metallic (Fe) and bimetallic (Fe/Ru and Fe/Co) particles as products of the reduction of the inclusion compounds by hydrogen. The application of other spectroscopic techniques in recent studies of cations, complexes, and metal particles in zeolites is reviewed: high-resolution solid-state NMR, nuclear-spin-relaxation studies, FMR, EXAFS, and XANES.

  9. Emissions and in-cylinder combustion characteristics of Fischer-Tropsch and conventional diesel fuels in a modern CI engine

    E-Print Network [OSTI]

    Sappok, Alexander G. (Alexander Georg)

    2006-01-01T23:59:59.000Z

    Increasingly stringent emissions regulations, rising oil prices, and an increased focus on environmental awareness are driving the search for clean, alternative fuels. Derived from natural gas, coal, and even biomass ...

  10. KINETIC MODELING OF A FISCHER-TROPSCH REACTION OVER A COBALT CATALYST IN A SLURRY BUBBLE COLUMN REACTOR FOR INCORPORATION INTO A COMPUTATIONAL MULTIPHASE FLUID DYNAMICS MODEL

    SciTech Connect (OSTI)

    Anastasia Gribik; Doona Guillen, PhD; Daniel Ginosar, PhD

    2008-09-01T23:59:59.000Z

    Currently multi-tubular fixed bed reactors, fluidized bed reactors, and slurry bubble column reactors (SBCRs) are used in commercial Fischer Tropsch (FT) synthesis. There are a number of advantages of the SBCR compared to fixed and fluidized bed reactors. The main advantage of the SBCR is that temperature control and heat recovery are more easily achieved. The SBCR is a multiphase chemical reactor where a synthesis gas, comprised mainly of H2 and CO, is bubbled through a liquid hydrocarbon wax containing solid catalyst particles to produce specialty chemicals, lubricants, or fuels. The FT synthesis reaction is the polymerization of methylene groups [-(CH2)-] forming mainly linear alkanes and alkenes, ranging from methane to high molecular weight waxes. The Idaho National Laboratory is developing a computational multiphase fluid dynamics (CMFD) model of the FT process in a SBCR. This paper discusses the incorporation of absorption and reaction kinetics into the current hydrodynamic model. A phased approach for incorporation of the reaction kinetics into a CMFD model is presented here. Initially, a simple kinetic model is coupled to the hydrodynamic model, with increasing levels of complexity added in stages. The first phase of the model includes incorporation of the absorption of gas species from both large and small bubbles into the bulk liquid phase. The driving force for the gas across the gas liquid interface into the bulk liquid is dependent upon the interfacial gas concentration in both small and large bubbles. However, because it is difficult to measure the concentration at the gas-liquid interface, coefficients for convective mass transfer have been developed for the overall driving force between the bulk concentrations in the gas and liquid phases. It is assumed that there are no temperature effects from mass transfer of the gas phases to the bulk liquid phase, since there are only small amounts of dissolved gas in the liquid phase. The product from the incorporation of absorption is the steady state concentration profile of the absorbed gas species in the bulk liquid phase. The second phase of the model incorporates a simplified macrokinetic model to the mass balance equation in the CMFD code. Initially, the model assumes that the catalyst particles are sufficiently small such that external and internal mass and heat transfer are not rate limiting. The model is developed utilizing the macrokinetic rate expression developed by Yates and Satterfield (1991). Initially, the model assumes that the only species formed other than water in the FT reaction is C27H56. Change in moles of the reacting species and the resulting temperature of the catalyst and fluid phases is solved simultaneously. The macrokinetic model is solved in conjunction with the species transport equations in a separate module which is incorporated into the CMFD code.

  11. Shape-selective catalysts for Fischer-Tropsch chemistry : iron-containing particulate catalysts. Activity report : January 1, 2001 - December 31, 2004.

    SciTech Connect (OSTI)

    Cronauer, D.; Chemical Engineering

    2006-05-12T23:59:59.000Z

    Argonne National Laboratory is carrying out a research program to create, prepare, and evaluate catalysts to promote Fischer-Tropsch (FT) chemistry--specifically, the reaction of hydrogen with carbon monoxide to form long-chain hydrocarbons. In addition to needing high activity, it is desirable that the catalysts have high selectivity and stability with respect to both mechanical strength and aging properties. It is desired that selectivity be directed toward producing diesel fraction components and avoiding excess yields of both light hydrocarbons and heavy waxes. The goal is to produce shape-selective catalysts that have the potential to limit the formation of longchain products and yet retain the active metal sites in a protected 'cage'. This cage also restricts their loss by attrition during use in slurry-bed reactors. The first stage of this program was to prepare and evaluate iron-containing particulate catalysts. This activity report centers upon this first stage of experimentation with particulate FT catalysts. (For reference, a second experimental stage is under way to prepare and evaluate active FT catalysts formed by atomic-layer deposition [ALD] of active components on supported membranes.) To date, experimentation has centered upon the evaluation of a sample of iron-based, spray-dried catalyst prepared by B.H. Davis of the Center of Applied Energy Research (CAER) and samples of his catalyst onto which inorganic 'shells' were deposited. The reference CAER catalyst contained a high level of dispersed fine particles, a portion of which was removed by differential settling. Reaction conditions have been established using a FT laboratory unit such that reasonable levels of CO conversion can be achieved, where therefore a valid catalyst comparison can be made. A wide range of catalytic activities was observed with SiO{sub 2}-coated FT catalysts. Two techniques were used for SiO{sub 2}coating. The first involved a caustic precipitation of SiO{sub 2} from an organo-silicate onto the CAER catalyst. The second was the acidic precipitation of an organo-silicate with aging to form fractal particles that were then deposited onto the CAER catalyst. Several resulting FT catalysts were as active as the coarse catalyst on which they were prepared. The most active ones were those with the least amount of coating, namely about 2.2 wt% SiO{sub 2}. In the case of the latter acid technique, the use of HCl and HNO{sub 3} was much more effective than that of H{sub 2}SO{sub 4}. Scanning electron microscopy (SEM) was used to observe and analyze as-received and treated FT catalysts. It was observed that (1) spherical particles of CAER FT catalyst were made up of agglomerates of particles that were, in turn, also agglomerates; (2) the spray drying process of CAER apparently concentrated the Si precursor at the surface during drying; (3) while SEM pointed out broad differences in the appearance of the prepared catalyst particles, there was little indication that the catalysts were being uniformly coated with a cage-like protective surface, with perhaps the exception of HNO{sub 3}-precipitated catalyst; and (4) there was only a limited penetration of carbon (i.e., CO) into the FT catalyst during the conditioning and FT reaction steps.

  12. Shape-selective catalysts for Fischer-Tropsch chemistry : atomic layer deposition of active catalytic metals. Activity report : January 1, 2005 - September 30, 2005.

    SciTech Connect (OSTI)

    Cronauer, D. C. (Chemical Sciences and Engineering Division)

    2011-04-15T23:59:59.000Z

    Argonne National Laboratory is carrying out a research program to create, prepare, and evaluate catalysts to promote Fischer-Tropsch (FT) chemistry - specifically, the reaction of hydrogen with carbon monoxide to form long-chain hydrocarbons. In addition to needing high activity, it is desirable that the catalysts have high selectivity and stability with respect to both mechanical strength and aging properties. The broad goal is to produce diesel fraction components and avoiding excess yields of both light hydrocarbons and heavy waxes. Originally the goal was to prepare shape-selective catalysts that would limit the formation of long-chain products and yet retain the active metal sites in a protected 'cage.' Such catalysts were prepared with silica-containing fractal cages. The activity was essentially the same as that of catalysts without the cages. We are currently awaiting follow-up experiments to determine the attrition strength of these catalysts. A second experimental stage was undertaken to prepare and evaluate active FT catalysts formed by atomic-layer deposition [ALD] of active components on supported membranes and particulate supports. The concept was that of depositing active metals (i.e. ruthenium, iron or cobalt) upon membranes with well defined flow channels of small diameter and length such that the catalytic activity and product molecular weight distribution could be controlled. In order to rapidly evaluate the catalytic membranes, the ALD coating processes were performed in an 'exploratory mode' in which ALD procedures from the literature appropriate for coating flat surfaces were applied to the high surface area membranes. Consequently, the Fe and Ru loadings in the membranes were likely to be smaller than those expected for complete monolayer coverage. In addition, there was likely to be significant variation in the Fe and Ru loading among the membranes due to difficulties in nucleating these materials on the aluminum oxide surfaces. The first series of experiments using coated membranes demonstrated that the technology needed further improvement. Specifically, observed catalytic FT activity was low. This low activity appeared to be due to: (1) low available surface area, (2) atomic deposition techniques that needed improvements, and (3) insufficient preconditioning of the catalyst surface prior to FT testing. Therefore, experimentation was expanded to the use of particulate silica supports having defined channels and reasonably high surface area. This later experimentation will be discussed in the next progress report. Subsequently, we plan to evaluate membranes after the ALD techniques are improved with a careful study to control and quantify the Fe and Ru loadings. The preconditioning of these surfaces will also be further developed. (A number of improvements have been made with particulate supports; they will be discussed in the subsequent report.) In support of the above, there was an opportunity to undertake a short study of cobalt/promoter/support interaction using the Advanced Photon Source (APS) of Argonne. Five catalysts and a reference cobalt oxide were characterized during a temperature programmed EXAFS/XANES experimental study with the combined effort of Argonne and the Center for Applied Energy Research (CAER) of the University of Kentucky. This project was completed, and it resulted in an extensive understanding of the preconditioning step of reducing Co-containing FT catalysts. A copy of the resulting manuscript has been submitted and accepted for publication. A similar project was undertaken with iron-containing FT catalysts; the data is currently being studied.

  13. Background and Motivation Biomass derived syngas contains

    E-Print Network [OSTI]

    Das, Suman

    Background and Motivation · Biomass derived syngas contains: CO, H2, small hydrocarbons, H2S prepared by SEA contain smaller metal particle sizes and have higher dispersion · The quantity of reducible

  14. Low-Emissions Burner Technology using Biomass-Derived Liquid...

    Broader source: Energy.gov (indexed) [DOE]

    Emissions Burner Technology using Biomass-Derived Liquid Fuels Low-Emissions Burner Technology using Biomass-Derived Liquid Fuels This factsheet describes a project that developed...

  15. Exploring Hydrogen Generation from Biomass-Derived Sugar and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Exploring Hydrogen Generation from Biomass-Derived Sugar and Sugar Alcohols to Reduce Costs Exploring Hydrogen Generation from Biomass-Derived Sugar and Sugar Alcohols to Reduce...

  16. Biomass Derivatives Competitive with Heating Oil Costs.

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:Year in Review: Top Five EERE Blog Posts of 2014 Year in Review: Top FiveeSCRM Program` [ R R

  17. Biomass-Derived Energy Products and Co-Products Market

    E-Print Network [OSTI]

    Biomass-Derived Energy Products and Co-Products Market This report identifies the bio-fuels and co & Earth Science & Technology ­ University of Hawai`i at Manoa #12;Biomass-Derived Energy Products and Co agency thereof. #12;Biomass Derived Energy Products and Co- Products Market and Off-take Study Hawaii

  18. Multi-stage Fischer-Tropsch process

    SciTech Connect (OSTI)

    Kim, C.J.; Fiato, R.A.

    1986-11-25T23:59:59.000Z

    A process is described for producing paraffinic hydrocarbons from carbon monoxide and hydrogen comprising: (a) introducing carbon monoxide and hydrogen into a reaction zone wherein the carbon monoxide and hydrogen contact in a first bed a first catalyst having a high olefin selectivity selected from the group consisting of Fe/Ce/Zn/K, Fe/Mn/K and Fe/Co/K; and (b) contacting the resulting olefin in a second bed with a second catalyst having a high selectivity for converting olefins to heavier paraffinic hydrocarbons selected from the group consisting of Ru/TiO/sub 2/, Ru/SiO/sub 2/ and Ru/Al/sub 2/O/sub 3/.

  19. Biomass-Derived Hydrogen from a Thermally Ballasted Gasifier

    E-Print Network [OSTI]

    Biomass-Derived Hydrogen from a Thermally Ballasted Gasifier DOE Hydrogen Program Contractors biomass #12;Approach Outline Gasifier Pilot Plant· Develop subsystems for the hydrogen production system and pyrolysis occur simultaneously in a single reactor · Exothermic combustion provides heat · Endothermic

  20. Biomass Derivatives Competitive with Heating Oil Costs. | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative FuelsBSCmemo.pdf BSCmemo.pdf BSCmemo.pdfBetterBIOENERGY

  1. Chemical Kinetic Modeling of Fuels

    Broader source: Energy.gov (indexed) [DOE]

    petroleum based fuels * Non-petroleum based fuels: - Biodiesel and new generation biofuels - Fischer-Tropsch (F-T) fuels - Oil sand derived fuels Reduce mechanisms for...

  2. An efficient didehydroxylation method for the biomass-derived polyols glycerol and erythritol. Mechanistic studies of a formic acid-mediated

    E-Print Network [OSTI]

    -oils from biomass pyrolysis4 and because of its promising role in hydrogen storage through the fixationAn efficient didehydroxylation method for the biomass-derived polyols glycerol and erythritol,2-deoxygenation method, involving an unexpected mechanism, was found for simple diols and for biomass

  3. Cobalt-ruthenium catalysts for Fischer-Tropsch synthesis

    SciTech Connect (OSTI)

    Iglesia, E.; Soled, S.L.; Fiato, R.A.

    1989-04-18T23:59:59.000Z

    A hydrocarbon synthesis process is described which comprises reacting hydrogen and carbon monoxide in the presence of a catalyst comprised of cobalt and ruthenium on titania, at reaction conditions suitable for the formation of higher hydrocarbons. The catalyst is prepared by impregnating titania with solutions of cobalt and ruthenium salts, drying the impregnated support, reducing the cobalt and ruthenium, treating the reduced metals with an oxygen containing stream at conditions sufficient to form oxides of cobalt and oxides of ruthenium and reducing the cobalt and ruthenium oxides.

  4. Nel (2004), “Clean Coal Conversion Options using Fischer-Tropsch

    E-Print Network [OSTI]

    Andre ? P. Steynberg; Herman G. Nel

    facilities producing these products individually. There may be good strategic reasons to use clean coal

  5. Opportunities for the Early Production of Fischer-Tropsch (F...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Presentation: U.S. Department of Energy 2002deershen.pdf More Documents & Publications Coal-Derived Liquids to Enable HCCI Technology WA99018TEXACOENERGYSYSTEMSWaiverofD...

  6. Development and Demonstration of Fischer-Tropsch Fueled Heavy...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    (F-T) Fuels in the U.S. -- An Overview APBF-DEC Heavy Duty NOx AdsorberDPF Project: Heavy Duty Linehaul Platform Project Update Coal-Derived Liquids to Enable HCCI Technology...

  7. IMPROVED IRON CATALYSTS FOR SLURRY PHASE FISCHER-TROPSCH SYNTHESIS

    SciTech Connect (OSTI)

    Dr. Dragomir B. Bukur; Dr. Lech Nowicki; Victor Carreto-Vazquez; Dr. Wen-Ping Ma

    2001-11-28T23:59:59.000Z

    PureVision Technology, Inc. (PureVision) of Fort Lupton, Colorado is developing a process for the conversion of lignocellulosic biomass into fuel-grade ethanol and specialty chemicals in order to enhance national energy security, rural economies, and environmental quality. Lignocellulosic-containing plants are those types of biomass that include wood, agricultural residues, and paper wastes. Lignocellulose is composed of the biopolymers cellulose, hemicellulose, and lignin. Cellulose, a polymer of glucose, is the component in lignocellulose that has potential for the production of fuel-grade ethanol by direct fermentation of the glucose. However, enzymatic hydrolysis of lignocellulose and raw cellulose into glucose is hindered by the presence of lignin. The cellulase enzyme, which hydrolyzes cellulose to glucose, becomes irreversibly bound to lignin. This requires using the enzyme in reagent quantities rather than in catalytic concentration. The extensive use of this enzyme is expensive and adversely affects the economics of ethanol production. PureVision has approached this problem by developing a biomass fractionator to pretreat the lignocellulose to yield a highly pure cellulose fraction. The biomass fractionator is based on sequentially treating the biomass with hot water, hot alkaline solutions, and polishing the cellulose fraction with a wet alkaline oxidation step. In September 2001 PureVision and Western Research Institute (WRI) initiated a jointly sponsored research project with the U.S. Department of Energy (DOE) to evaluate their pretreatment technology, develop an understanding of the chemistry, and provide the data required to design and fabricate a one- to two-ton/day pilot-scale unit. The efforts during the first year of this program completed the design, fabrication, and shakedown of a bench-scale reactor system and evaluated the fractionation of corn stover. The results from the evaluation of corn stover have shown that water hydrolysis prior to alkaline hydrolysis may be beneficial in removing hemicellulose and lignin from the feedstock. In addition, alkaline hydrolysis has been shown to remove a significant portion of the hemicellulose and lignin. The resulting cellulose can be exposed to a finishing step with wet alkaline oxidation to remove the remaining lignin. The final product is a highly pure cellulose fraction containing less than 1% of the native lignin with an overall yield in excess of 85% of the native cellulose. This report summarizes the results from the first year's effort to move the technology to commercialization.

  8. Activation studies with promoted precipitated iron Fischer-Tropsch catalysts

    E-Print Network [OSTI]

    Manne, Rama Krishna

    1991-01-01T23:59:59.000Z

    the Ruhrchemie catalyst, the catalyst activity and stability changed markedly with reduction procedure. Hs reduction at 220'C was repeated since it gave very loiv activity. The reproducibility of this test ivas good. Hs reduction at 250 gave higher catalyst...

  9. ADDENDUM -EXXON FISCHER-TROPSCH WORK Fischer Synthesis Process

    E-Print Network [OSTI]

    Kentucky, University of

    -loaded catalyst is determined by relating the rate of diffusion of CO and H2 to a rate of reaction in the porousCCO/d?] = De,H [dCH/d?] [A.1] where the flux is expressed as a product of the effective diffusivity, De's Law constant. The other boundary condition can be defined for two cases as: inert core dCCO/d ? = 0

  10. Subtask 3.4 - Fischer - Tropsch Fuels Development

    SciTech Connect (OSTI)

    Joshua Strege; Anthony Snyder; Jason Laumb; Joshua Stanislowski; Michael Swanson

    2012-05-01T23:59:59.000Z

    Under Subtask 3.4, the Energy & Environmental Research Center (EERC) examined the opportunities and challenges facing Fischerâ??Tropsch (FT) technology in the United States today. Work was completed in two distinct budget periods (BPs). In BP1, the EERC examined the technical feasibility of using modern warm-gas cleanup techniques for FT synthesis. FT synthesis is typically done using more expensive and complex cold-gas sweetening. Warm-gas cleanup could greatly reduce capital and operating costs, making FT synthesis more attractive for domestic fuel production. Syngas was generated from a variety of coal and biomass types; cleaned of sulfur, moisture, and condensables; and then passed over a pilot-scale FT catalyst bed. Laboratory and modeling work done in support of the pilot-scale effort suggested that the catalyst was performing suboptimally with warm-gas cleanup. Long-term trends showed that the catalyst was also quickly deactivating. In BP3, the EERC compared FT catalyst results using warm-gas cleanup to results using cold-gas sweetening. A gas-sweetening absorption system (GSAS) was designed, modeled, and constructed to sweeten syngas between the gasifier and the pilot-scale FT reactor. Results verified that the catalyst performed much better with gas sweetening than it had with warm-gas cleanup. The catalyst also showed no signs of rapid deactivation when the GSAS was running. Laboratory tests in support of this effort verified that the catalyst had deactivated quickly in BP1 because of exposure to syngas, not because of any design flaw with the pilot-scale FT reactor itself. Based on these results, the EERC concludes that the two biggest issues with using syngas treated with warm-gas cleanup for FT synthesis are high concentrations of CO{sub 2} and volatile organic matter. Other catalysts tested by the EERC may be more tolerant of CO{sub 2}, but volatile matter removal is critical to ensuring long-term FT catalyst operation. This subtask was funded through the EERCâ??U.S. Department of Energy (DOE) Joint Program on Research and Development for Fossil Energy-Related Resources Cooperative Agreement No. DE-FC26-08NT43291. Nonfederal funding for BP1 was provided by the North Dakota Industrial Commissionâ??s (NDIC) Renewable Energy Council.

  11. Biomass-Derived Hydrogen from a Thermally Ballasted Gasifier

    SciTech Connect (OSTI)

    Robert C. Brown

    2007-04-06T23:59:59.000Z

    The goal of this project is to develop an indirectly heated gasification system that converts switchgrass into hydrogen-rich gas suitable for powering fuel cells. The project includes investigations of the indirectly-heated gasifier, development of particulate removal equipment, evaluation of catalytic methods for upgrading producer gas, development of contaminant measurement and control techniques, modeling of the thermal performance of the ballasted gasifier, and estimation of the cost of hydrogen from the proposed gasification system. Specific technologies investigated include a thermally ballasted gasifier, a moving bed granular filter, and catalytic reactors for steam reforming and water-gas shift reaction. The approach to this project was to employ a pilot-scale (5 ton per day) gasifier to evaluate the thermally ballasted gasifier as a means for producing hydrogen from switchgrass. A slipstream from the gasifier was used to evaluate gas cleaning and upgrading options. Other tests were conducted with laboratory-scale equipment using simulated producer gas. The ballasted gasifier operated in conjunction with a steam reformer and two-stage water-gas shift reactor produced gas streams containing 54.5 vol-% H2. If purge gas to the feeder system could be substantially eliminated, hydrogen concentration would reach 61 vol-%, which closely approaches the theoretical maximum of 66 vol-%. Tests with a combined catalyst/sorbent system demonstrated that steam reforming and water-gas shift reaction could be substantially performed in a single reactor and achieve hydrogen concentrations exceeding 90 vol-%. Cold flow trials with a laboratory-scale moving bed granular filter achieved particle removal efficiencies exceeding 99%. Two metal-based sorbents were tested for their ability to remove H2S from biomass-derived producer gas. The ZnO sorbent, tested at 450? C, was effective in reducing H2S from 200 ppm to less than 2 ppm (>99% reduction) while tests with the MnO sorbent were inconclusive. A computer model was developed that successfully predicted the thermal performance of the ballasted gasifier. An economic comparison of an air-blown gasification plant and a ballasted gasifier plant found that operating costs for ballasted gasification plant are about 31% higher than for the air blown gasifier plant. Hydrogen from the ballasted gasification plant and air blown gasification plant are projected to be $2.43/kg and $1.85/kg, respectively. This is lower than U.S. DOE’s 2010 target price of $2.90/kg and comparable to U.S. DOE’s 2015 target price of $2.00/kg.

  12. E-Print Network 3.0 - above-ground biomass derived Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Powered by Explorit Topic List Advanced Search Sample search results for: above-ground biomass derived Page: << < 1 2 3 4 5 > >> 1 Figure 2. Above ground woody biomass across a...

  13. Methods and apparatuses for preparing upgraded pyrolysis oil

    DOE Patents [OSTI]

    Brandvold, Timothy A; Baird, Lance Awender; Frey, Stanley Joseph

    2013-10-01T23:59:59.000Z

    Methods and apparatuses for preparing upgraded pyrolysis oil are provided herein. In an embodiment, a method of preparing upgraded pyrolysis oil includes providing a biomass-derived pyrolysis oil stream having an original oxygen content. The biomass-derived pyrolysis oil stream is hydrodeoxygenated under catalysis in the presence of hydrogen to form a hydrodeoxygenated pyrolysis oil stream comprising a cyclic paraffin component. At least a portion of the hydrodeoxygenated pyrolysis oil stream is dehydrogenated under catalysis to form the upgraded pyrolysis oil.

  14. Labscale Evaluation of Biomass-Derived Elements Used in Anaerobic Digestion

    E-Print Network [OSTI]

    Labscale Evaluation of Biomass-Derived Elements Used in Anaerobic Digestion This report presents performance data for an anaerobic digestion system (at a 10-liter scale) utilizing corncob biochar as biofilm support. The system operated on grease-trap wastewater and high-rate anaerobic digestion of this material

  15. E-Print Network 3.0 - acid sunflower oil Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Sciences and Ecology 49 Chapter 1: An Introduction to the Hydroprocessing of Biomass Derived Pyrolysis An introduction to the hydrotreatment of pyrolysis oil is given...

  16. E-Print Network 3.0 - acid rich oils Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Collection: Biology and Medicine 14 Chapter 1: An Introduction to the Hydroprocessing of Biomass Derived Pyrolysis An introduction to the hydrotreatment of pyrolysis oil is given...

  17. Catalytic Tar Reforming for Cleanup and Conditioning of Biomass-derived Syngas

    SciTech Connect (OSTI)

    Dayton, D. C.; Bain, R. L.; Phillips, S. D.; Magrini-Bair, K.; Feik, C. J.

    2006-01-01T23:59:59.000Z

    Biomass gasification is being investigated to produce clean syngas from biomass or biorefinery residues as an intermediate that can be used directly as a fuel for integrated heat and power production or further refined and upgraded by various processing technologies. Conditioning of biomass-derived syngas, with an emphasis on tar reforming, to make it a suitable feed for high temperature, pressurized liquid fuels synthesis is the goal of current research efforts.

  18. Materials Degradation In Biomass-Derived Oils Presentation for BETO 2015 Project Peer Review

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustion | Department of EnergyDevelopment Accident TolerantDepartmentLaboratory and10 Technologies

  19. Dynamic molecular structure of plant biomass-derived black carbon (biochar)

    SciTech Connect (OSTI)

    Keiluweit, M.; Nico, P.S.; Johnson, M.G.; Kleber, M.

    2009-11-15T23:59:59.000Z

    Char black carbon (BC), the solid residue of incomplete combustion, is continuously being added to soils and sediments due to natural vegetation fires, anthropogenic pollution, and new strategies for carbon sequestration ('biochar'). Here we present a molecular-level assessment of the physical organization and chemical complexity of biomass-derived chars and, specifically, that of aromatic carbon in char structures. BET-N{sub 2} surface area, X-ray diffraction (XRD), synchrotron-based Near-edge X-ray Absorption Fine Structure (NEXAFS), and Fourier transform infrared (FT-IR) spectroscopy are used to show how two plant materials (wood and grass) undergo analogous, but quantitatively different physical-chemical transitions as charring temperature increases from 100 to 700 C. These changes suggest the existence of four distinct categories of char consisting of a unique mixture of chemical phases and physical states: (i) in transition chars the crystalline character of the precursor materials is preserved, (ii) in amorphous chars the heat-altered molecules and incipient aromatic polycondensates are randomly mixed, (iii) composite chars consist of poorly ordered graphene stacks embedded in amorphous phases, and (iv) turbostratic chars are dominated by disordered graphitic crystallites. The molecular variations among the different char categories translate into differences in their ability to persist in the environment and function as environmental sorbents.

  20. Deconstruction of Lignin Model Compounds and Biomass-Derived Lignin using Layered Double Hydroxide Catalysts

    SciTech Connect (OSTI)

    Chmely, S. C.; McKinney, K. A.; Lawrence, K. R.; Sturgeon, M.; Katahira, R.; Beckham, G. T.

    2013-01-01T23:59:59.000Z

    Lignin is an underutilized value stream in current biomass conversion technologies because there exist no economic and technically feasible routes for lignin depolymerization and upgrading. Base-catalyzed deconstruction (BCD) has been applied for lignin depolymerization (e.g., the Kraft process) in the pulp and paper industry for more than a century using aqueous-phase media. However, these efforts require treatment to neutralize the resulting streams, which adds significantly to the cost of lignin deconstruction. To circumvent the need for downstream treatment, here we report recent advances in the synthesis of layered double hydroxide and metal oxide catalysts to be applied to the BCD of lignin. These catalysts may prove more cost-effective than liquid-phase, non-recyclable base, and their use obviates downstream processing steps such as neutralization. Synthetic procedures for various transition-metal containing catalysts, detailed kinetics measurements using lignin model compounds, and results of the application of these catalysts to biomass-derived lignin will be presented.

  1. Dual Layer Monolith ATR of Pyrolysis Oil for Distributed Synthesis Gas Production

    SciTech Connect (OSTI)

    Lawal, Adeniyi [Stevens Institute of Technology, Castle Point Hoboken NJ 07030

    2012-09-29T23:59:59.000Z

    We have successfully demonstrated a novel reactor technology, based on BASF dual layer monolith catalyst, for miniaturizing the autothermal reforming of pyrolysis oil to syngas, the second and most critical of the three steps for thermochemically converting biomass waste to liquid transportation fuel. The technology was applied to aged as well as fresh samples of pyrolysis oil derived from five different biomass feedstocks, namely switch-grass, sawdust, hardwood/softwood, golden rod and maple. Optimization of process conditions in conjunction with innovative reactor system design enabled the minimization of carbon deposit and control of the H2/CO ratio of the product gas. A comprehensive techno-economic analysis of the integrated process using in part, experimental data from the project, indicates (1) net energy recovery of 49% accounting for all losses and external energy input, (2) weight of diesel oil produced as a percent of the biomass to be ~14%, and (3) for a �demonstration� size biomass to Fischer-Tropsch liquid plant of ~ 2000 daily barrels of diesel, the price of the diesel produced is ~$3.30 per gallon, ex. tax. However, the extension of catalyst life is critical to the realization of the projected economics. Catalyst deactivation was observed and the modes of deactivation, both reversible and irreversible were identified. An effective catalyst regeneration strategy was successfully demonstrated for reversible catalyst deactivation while a catalyst preservation strategy was proposed for preventing irreversible catalyst deactivation. Future work should therefore be focused on extending the catalyst life, and a successful demonstration of an extended (> 500 on-stream hours) catalyst life would affirm the commercial viability of the process.

  2. Separation of Fischer-Tropsch Wax Products from Ultrafine Iron Catalyst Particles

    SciTech Connect (OSTI)

    James K. Neathery; Gary Jacobs; Amitava Sarkar; Burtron H. Davis

    2006-03-31T23:59:59.000Z

    The morphological and chemical nature of ultrafine iron catalyst particles (3-5 nm diameters) during activation/FTS was studied by HRTEM, EELS, and Moessbauer spectroscopy. With the progress of FTS, the carbide re-oxidized to magnetite and catalyst activity gradually decreased. The growth of oxide phase continued and average particle size also increased simultaneously. The phase transformation occurred in a ''growing oxide core'' manner with different nano-zones. The nano-range carbide particles did not show fragmentation or attrition as generally observed in micrometer range particles. Nevertheless, when the dimension of particles reached the micrometer range, the crystalline carbide phase appeared to be sprouted on the surface of magnetite single crystal. In the previous reporting period, a design and operating philosophy was developed for an integrated wax filtration system for a 4 liter slurry bubble column reactor to be used in Phase II of this research program. During the current reporting period, we have started construction of the new filtration system and began modifications to the 4 liter slurry bubble column reactor (SBCR) reactor. The system will utilize a primary wax separation device followed by a Pall Accusep or Membralox ceramic cross-flow membrane. As of this writing, the unit is nearly complete except for the modification of a moyno-type pump; the pump was shipped to the manufacturer to install a special leak-free, high pressure seal.

  3. Separation of Fischer-Tropsch Wax Products from Ultrafine Iron Catalyst Particles

    SciTech Connect (OSTI)

    James K. Neathery; Gary Jacobs; Amitava Sarkar; Adam Crawford; Burtron H. Davis

    2006-09-30T23:59:59.000Z

    In the previous reporting period, modifications were completed for integrating a continuous wax filtration system for a 4 liter slurry bubble column reactor. During the current reporting period, a shakedown of the system was completed. Several problems were encountered with the progressive cavity pump used to circulate the wax/catalyst slurry though the cross-flow filter element and reactor. During the activation of the catalyst with elevated temperature (> 270 C) the elastomer pump stator released sulfur thereby totally deactivating the iron-based catalyst. Difficulties in maintaining an acceptable leak rate from the pump seal and stator housing were also encountered. Consequently, the system leak rate exceeded the expected production rate of wax; therefore, no online filtration could be accomplished. Work continued regarding the characterization of ultra-fine catalyst structures. The effect of carbidation on the morphology of iron hydroxide oxide particles was the focus of the study during this reporting period. Oxidation of Fe (II) sulfate results in predominantly {gamma}-FeOOH particles which have a rod-shaped (nano-needles) crystalline structure. Carbidation of the prepared {gamma}-FeOOH with CO at atmospheric pressure produced iron carbides with spherical layered structure. HRTEM and EDS analysis revealed that carbidation of {gamma}-FeOOH particles changes the initial nano-needles morphology and generates ultrafine carbide particles with irregular spherical shape.

  4. Reducing fischer-tropsch catalyst attrition losses in high agitation reaction systems

    DOE Patents [OSTI]

    Singleton, Alan H. (Baden, PA); Oukaci, Rachid (Gibsonia, PA); Goodwin, James G. (Cranberry Township, PA)

    2001-01-01T23:59:59.000Z

    A method for reducing catalyst attrition losses in hydrocarbon synthesis processes conducted in high agitation reaction systems; a method of producing an attrition-resistant catalyst; a catalyst produced by such method; a method of producing an attrition-resistant catalyst support; and a catalyst support produced by such method. The inventive method of reducing catalyst attrition losses comprises the step of reacting a synthesis gas in a high agitation reaction system in the presence of a catalyst. In one aspect, the catalyst preferably comprises a .gamma.-alumina support including an amount of titanium effective for increasing the attrition resistance of the catalyst. In another aspect, the catalyst preferably comprises a .gamma.-alumina support which has been treated, after calcination, with an acidic, aqueous solution. The acidic aqueous solution preferably has a pH of not more than about 5. In another aspect, the catalyst preferably comprises cobalt on a .gamma.-alumina support wherein the cobalt has been applied to the .gamma.-alumina support by totally aqueous, incipient wetness-type impregnation. In another aspect, the catalyst preferably comprises cobalt on a .gamma.-alumina support with an amount of a lanthana promoter effective for increasing the attrition resistance of the catalyst. In another aspect, the catalyst preferably comprises a .gamma.-alumina support produced from boehmite having a crystallite size, in the 021 plane, in the range of from about 30 to about 55 .ANG.ngstrons. In another aspect, the inventive method of producing an attrition-resistant catalyst comprises the step of treating a .gamma.-alumina support, after calcination of and before adding catalytic material to the support, with an acidic solution effective for increasing the attrition resistance of the catalyst. In another aspect, the inventive method of producing an attrition-resistant catalyst support comprises the step of treating calcined .gamma.-alumina with an acidic, aqueous solution effective for increasing the attrition resistance of the .gamma.-alumina.

  5. Processes and palladium-promoted catalysts for conducting Fischer-Tropsch synthesis

    DOE Patents [OSTI]

    Singleton, Alan H. (Baden, PA); Oukaci, Rachid (Gibsonia, PA); Goodwin, James G. (Cranberry Township, PA)

    2000-01-01T23:59:59.000Z

    A process for hydrocarbon synthesis comprising the step of reacting a synthesis gas in the presence of a cobalt catalyst promoted with palladium.

  6. Development of a Fischer-Tropsch Gasoline Process for the Steam Hydrogasification Technology

    E-Print Network [OSTI]

    Li, Yang

    2013-01-01T23:59:59.000Z

    Industrial   &  engineering  chemistry  research,  2005.  Industrial   &   engineering   chemistry   research,  Industrial   &   engineering   chemistry  research,  1995.  

  7. Ultra-Clean Fischer-Tropsch Fuels Production and Demonstration Project

    SciTech Connect (OSTI)

    Steve Bergin

    2005-10-14T23:59:59.000Z

    The Report Abstract provides summaries of the past year's activities relating to each of the main project objectives. Some of the objectives will be expanded on in greater detail further down in the report. The following objectives have their own addition sections in the report: Dynamometer Durability Testing, the Denali Bus Fleet Demonstration, Bus Fleet Demonstrations Emissions Analysis, Impact of SFP Fuel on Engine Performance, Emissions Analysis, Feasibility Study of SFPs for Rural Alaska, and Cold Weather Testing of Ultra Clean Fuel.

  8. Fischer-Tropsch synthesis in the slurry phase on iron catalysts

    E-Print Network [OSTI]

    Brown, Russell Floyd

    1986-01-01T23:59:59.000Z

    and noted that the iron catalyst produced more carbon dioxide than the cobalt catalyst, while the cobalt catalyst produced more water. Iron catalysts are also known to produce a higher yield of oxygenstes and offer the advantages of low cost and a wide... conductivity 40 minutes '0 O 0 0 0 o 2 0 '0 Ll 9 2 H 8. A o g Q Ni Valve Snitch Propane Propylene Iso-butane N-Butane I-Butane Isobutylene ~ Trans-2-butane Ctg-2-butane Valve Suicch Ethylene Ethane Valve Snitch 0 2 N CH...

  9. Potential for Coal-to-Liquids Conversion in the United States--FischerTropsch Synthesis

    E-Print Network [OSTI]

    Patzek, Tadeusz W.

    Potential for Coal-to-Liquids Conversion in the United States--Fischer­Tropsch Synthesis Tad W-mine development. Consequently, a large-scale effort to convert coal to liquids (CTL) has been proposed to create that coal into a synthetic liquid fuel, or synfuel. The plan is con- troversial, but Gov. Schweitzer ­ half

  10. Hydrodynamics of bubble columns with application to Fischer-Tropsch synthesis

    E-Print Network [OSTI]

    Raphael, Matheo Lue

    1988-01-01T23:59:59.000Z

    produced hold-up vaiues similar to those of pure liquids, whereas. exper r rent, zvith parafiiu waxes (FT-200 ancl PT-:300) at 265 'C produced iigh hold- p values ar. d large aznounts of foam. But, at 200 'C lov; hold-up raiues were c'iitaired anc small... by the column diameter and superficial gas velocity. In the bubbly flow regime?bubbles may be small and spherical, or larger and non spherical because of the flow of liquid around them. As the superficial gas velocity is increased slug flov' is developed...

  11. Technology Development for Iron and Cobalt Fischer-Tropsch Catalysts Quarterly Report

    E-Print Network [OSTI]

    Kentucky, University of

    as an account of work sponsored by an agency of the United States Government. Neither the United States agency thereof. #12;2 Abstract CAER Tight control of catalyst distribution within SBCRs should . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 Abstract . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

  12. ULTRA-CLEAN FISCHER-TROPSCH FUELS PRODUCTION AND DEMONSTRATION PROJECT

    SciTech Connect (OSTI)

    Steve Bergin

    2004-10-18T23:59:59.000Z

    The Report Abstract provides summaries of the past year's activities relating to each of the main project objectives. Some of the objectives will be expanded on in greater detail further down in the report. The following objectives have their own addition sections in the report: SFP Construction and Fuel Production, Impact of SFP Fuel on Engine Performance, Fleet Testing at WMATA and Denali National Park, Demonstration of Clean Diesel Fuels in Diesel Electric Generators in Alaska, and Economic Analysis. ICRC provided overall project organization and budget management for the project. ICRC held meetings with various project participants. ICRC presented at the Department of Energy's annual project review meeting. The plant began producing fuel in October 2004. The first delivery of finished fuel was made in March of 2004 after the initial start-up period.

  13. HEFA and Fischer-Tropsch Jet Fuel Cost Analyses | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarly Career Scientists'Montana.ProgramJulietip sheetK-4In 2013 many autoThis road map is a summary of- -

  14. Opportunities for the Early Production of Fischer-Tropsch (F-T) Fuels in

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustion | Department ofT ib l L d F SSales LLCDiesel Enginesthe U.S. -- An Overview | Department of

  15. Safety and Techno-Economic Analysis of Solvent Selection for Supercritical Fischer-Tropsch Synthesis Reactors

    E-Print Network [OSTI]

    Hamad, Natalie

    2012-02-14T23:59:59.000Z

    of the fixed-bed reactor, among other disadvantages, is that the reaction is very exothermic, which is a concern in terms of safety hazards and also in terms of cost of heat removal. With the slurry reactor, a problem is that in the liquid media... at different lengths.4 After the reaction takes place, the amount of carbon monoxide consumed decreases and carbon dioxide is produced as a side product.9 The FTS reaction is an extremely exothermic process, which represents serious challenges...

  16. Effect of Liquid Composition on the Slurry Fischer-Tropsch Synthesis. 1. Rate of Reaction

    SciTech Connect (OSTI)

    Satterfield, C.N.; Stenger, H.G.

    1984-04-01T23:59:59.000Z

    With a reduced fused magnetite catalyst, the rate of reaction in the presence of phenanthrene is nearly twice that observed in the presence of n-octacosane even though the solubility of H/sub 2/ and CO is moderately less in phenanthrene. The rate in the presence of triphenylmethane was about the same as in n-octacosane. In the presence of a perfluoropolyether, the rate of reaction was markedly reduced, even though H/sub 2/ and CO solubilities are much higher than in hydrocarbons. This was attributed to substantial mass transfer resistances through an encapsulating hydrocarbon layer around the catalyst particles. The effect of the nature of a liquid on several other reactions is also discussed.

  17. Effect of Liquid Composition on the Slurry Fischer-Tropsch Synthesis. 2. Product Selectivity

    SciTech Connect (OSTI)

    Stenger, H.G.; Satterfield, C.N.

    1984-04-01T23:59:59.000Z

    With a reduced, fused magnetite catalyst, secondary reactions, consisting of olefin hydrogenation, olefin isomerization, and incorporation of ethylene and/or ethyl alcohol into product, were slightly greater in octacosane than in phenanthrene at 232/sup 0/C but essentially the same at 263/sup 0/C. This is attributed to competitiv adsorption effects with phenanthrene which adsorbs significantly onto the catalyst at 232/sup 0/C, but not at 263/sup 0/C. All secondary reactions are enhanced by conditions minimizing CO adsorption. Oxygenates were greatly diminished at high conversions. C/sub 2/ incorporation into product stops chain growth by a scavenging effect. In the presence of a perfluoropolyether (Fomblin), in which hydrocarbons are immiscible, catalyst is preferentially wetted by hydrocarbons and secondary reactions are greatly enhanced by mass transfer resistances.

  18. Development and Demonstration of Fischer-Tropsch Fueled Heavy-Duty Vehicles

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-UpHeat Pump Models |Conduct, Parent Companya new high capacity anodewith Control

  19. Innovative Gasification to Produce Fischer-Tropsch Jet and Diesel Fuel

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-UpHeatMulti-Dimensionalthe U.S.Indiana CollegeManagerInnovative Gasification to Produce

  20. Biomass-Derived Hydrogen from a Thermally Ballasted Gasifier Robert C. Brown, Glenn Norton, Andy Suby, Jerod Smeenk, Keith Cummer, and Josh Nunez

    E-Print Network [OSTI]

    Biomass-Derived Hydrogen from a Thermally Ballasted Gasifier Robert C. Brown, Glenn Norton, Andy fuel cells. We have developed a thermally ballasted gasifier that uses a single reactor for both compared to conventional gasifiers. The carbon monoxide, along with steam used to fluidize the reactor, can

  1. Low Emissions Burner Technology for Metal Processing Industry using Byproducts and Biomass Derived Liquid Fuels

    SciTech Connect (OSTI)

    Agrawal, Ajay; Taylor, Robert

    2013-09-30T23:59:59.000Z

    This research and development efforts produced low-emission burner technology capable of operating on natural gas as well as crude glycerin and/or fatty acids generated in biodiesel plants. The research was conducted in three stages (1) Concept definition leading to the design and development of a small laboratory scale burner, (2) Scale-up to prototype burner design and development, and (3) Technology demonstration with field vefiication. The burner design relies upon the Flow Blurring (FB) fuel injection based on aerodynamically creating two-phase flow near the injector exit. The fuel tube and discharge orifice both of inside diameter D are separated by gap H. For H < 0.25D, the atomizing air bubbles into liquid fuel to create a two-phase flow near the tip of the fuel tube. Pressurized two-phase fuel-air mixture exits through the discharge orifice, which results in expansion and breakup of air bubbles yielding a spray with fine droplets. First, low-emission combustion of diesel, biodiesel and straight VO (soybean oil) was achieved by utilizing FB injector to yield fine sprays for these fuels with significantly different physical properties. Visual images for these baseline experiments conducted with heat release rate (HRR) of about 8 kW illustrate clean blue flames indicating premixed combustion for all three fuels. Radial profiles of the product gas temperature at the combustor exit overlap each other signifying that the combustion efficiency is independent of the fuel. At the combustor exit, the NOx emissions are within the measurement uncertainties, while CO emissions are slightly higher for straight VO as compared to diesel and biodiesel. Considering the large variations in physical and chemical properties of fuels considered, the small differences observed in CO and NOx emissions show promise for fuel-flexible, clean combustion systems. FB injector has proven to be very effective in atomizing fuels with very different physical properties, and it offers a path forward to utilize both fossil and alternative liquid fuels in the same combustion system. In particular, experiments show that straight VO can be cleanly combusted without the need for chemical processing or preheating steps, which can result in significant economic and environmental benefits. Next, low-emission combustion of glycerol/methane was achieved by utilizing FB injector to yield fine droplets of highly viscous glycerol. Heat released from methane combustion further improves glycerol pre-vaporization and thus its clean combustion. Methane addition results in an intensified reaction zone with locally high temperatures near the injector exit. Reduction in methane flow rate elongates the reaction zone, which leads to higher CO emissions and lower NOx emissions. Similarly, higher air to liquid (ALR) mass ratio improves atomization and fuel pre-vaporization and shifts the flame closer to the injector exit. In spite of these internal variations, all fuel mixes of glycerol with methane produced similar CO and NOx emissions at the combustor exit. Results show that FB concept provides low emissions with the flexibility to utilize gaseous and highly viscous liquid fuels, straight VO and glycerol, without preheating or preprocessing the fuels. Following these initial experiments in quartz combustor, we demonstrated that glycerol combustion can be stably sustained in a metal combustor. Phase Doppler Particle Analyzer (PDPA) measurements in glycerol/methane flames resulted in flow-weighted Sauter Mean Diameter (SMD) of 35 to 40 ?m, depending upon the methane percentage. This study verified that lab-scale dual-fuel burner using FB injector can successfully atomize and combust glycerol and presumably other highly viscous liquid fuels at relatively low HRR (<10 kW). For industrial applications, a scaled-up glycerol burner design thus seemed feasible.

  2. REVERSIBLE SOLID OXIDE CELLS Mogens Mogensen1

    E-Print Network [OSTI]

    .6 US$/GJ, the H2 production price is estimated to 4.8 US$/GJ equivalent to 30 US$/barrel crude oil for manufacturing of synthetic diesel from synthesis gas using Fischer-Tropsch are being built due to the high oil price. The synthesis gas is made by steam refor

  3. Oil

    E-Print Network [OSTI]

    unknown authors

    Waste oils offer a tremendous recycling potential. An important, dwindling natural resource of great economic and industrial value, oil products are a cornerstone of our modern industrial society. Petroleum is processed into a wide variety of products: gasoline, fuel oil, diesel oil, synthetic rubber, solvents, pesticides, synthetic fibres, lubricating oil, drugs and many more ' (see Figure 1 1. The boilers of Amercian industries presently consume about 40 % of the used lubricating oils collected. In Ontario, the percentage varies from 20 to 30%. Road oiling is the other major use of collected waste oils. Five to seven million gallons (50-70 % of the waste oil col1ected)is spread on dusty Ontario roads each summer. The practice is both a wasteful use of a dwindling resource and an environmental hazard. The waste oil, with its load of heavy metals, particularly lead, additives including dangerous polynuclear aromatics and PCBs, is carried into the natural environment by runoff and dust to contaminate soils and water courses.2 The largest portion of used oils is never collected, but disappears into sewers, landfill sites and backyards. In Ontario alone, approximately 22 million gallons of potentially recyclable lube oil simply vanish each year. While oil recycling has ad-114 Oil

  4. Separation of Fischer-Tropsch Wax from Catalyst Using Near-Critical Fluid Extraction: Analysis of Process

    E-Print Network [OSTI]

    Kilpatrick, Peter K.

    ", can be produced from materials such as coal, natural gas, waste biomass, and petroleum coke. A great of coal and natural gas exist in many geographical regions that lack sufficient petroleum. Therefore

  5. Síntese de Fischer-Tropsch sobre perovskitas LayCu0,4Fe0,6O3.

    E-Print Network [OSTI]

    José Roberto de Souza

    2010-01-01T23:59:59.000Z

    ??A produção atual de 52 milhões mdia-1 de gás natural e os grandes projetos para esta expansão vem estabelecendo novas fronteiras para a indústria nacional… (more)

  6. Characterization of new Co and Ru on -WC catalysts for Fischer-Tropsch reaction. Influence of the carbide surface state.

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    [8]. Among the group VI transition metal carbides, the hexagonal tungsten carbide WC is a remarkable proceeds on supported transition metal catalysts, Co or Fe on oxide supports generally Al2O3 or SiO2 [1 of the carbide surface state. A. Griboval-Constant(1) *, J.-M. Giraudon(1) , I. Twagishema(1) , G. Leclercq(1

  7. Characterization of new Co and Ru on -WC catalysts for Fischer-Tropsch reaction. Influence of the carbide surface state.

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    of the metallic particles [8]. Among the group VI transition metal carbides, the hexagonal tungsten carbide WC monoxide and hydrogen. FT synthesis proceeds on supported transition metal catalysts, Co or Fe on oxide of the carbide surface state. A. Griboval-Constant(1) *, J.-M. Giraudon(1) , I. Twagishema(1) , G. Leclercq(1

  8. Fischer-Tropsch Fuels from Coal and Biomass Thomas G. Kreutz, Eric D. Larson, Guangjian Liu, Robert H. Williams

    E-Print Network [OSTI]

    ...................................................................................................................................8 2.2.2 Biomass as feedstock

  9. E-Print Network 3.0 - advanced heterogeneous catalysts Sample...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and Hydrogen Summary: Fischer-Tropsch synthesis using Co and Ru supported on silica aerogels as catalysts 21 Metal impregnation... Hexane Fischer-Tropsch Synthesis over an...

  10. E-Print Network 3.0 - ammonia synthesis catalyst Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and Hydrogen Summary: Fischer-Tropsch synthesis using Co and Ru supported on silica aerogels as catalysts 21 Metal impregnation... Hexane Fischer-Tropsch Synthesis over an...

  11. Bench- and Pilot-Scale Studies of Reaction and Regeneration of Ni-Mg-K/Al2O3 for Catalytic Conditioning of Biomass-Derived Syngas

    SciTech Connect (OSTI)

    Magrini-Bair, K. A.; Jablonski, W. S.; Parent, Y. O.; Yung, M. M.

    2012-05-01T23:59:59.000Z

    The National Renewable Energy Laboratory (NREL) is collaborating with both industrial and academic partners to develop technologies to help enable commercialization of biofuels produced from lignocellulosic biomass feedstocks. The focus of this paper is to report how various operating processes, utilized in-house and by collaborators, influence the catalytic activity during conditioning of biomass-derived syngas. Efficient cleaning and conditioning of biomass-derived syngas for use in fuel synthesis continues to be a significant technical barrier to commercialization. Multifunctional, fluidizable catalysts are being developed to reform undesired tars and light hydrocarbons, especially methane, to additional syngas, which can improve utilization of biomass carbon. This approach also eliminates both the need for downstream methane reforming and the production of an aqueous waste stream from tar scrubbing. This work was conducted with NiMgK/Al{sub 2}O{sub 3} catalysts. These catalysts were assessed for methane reforming performance in (i) fixed-bed, bench-scale tests with model syngas simulating that produced by oak gasification, and in pilot-scale, (ii) fluidized tests with actual oak-derived syngas, and (iii) recirculating/regenerating tests using model syngas. Bench-scale tests showed that the catalyst could be completely regenerated over several reforming reaction cycles. Pilot-scale tests using raw syngas showed that the catalyst lost activity from cycle to cycle when it was regenerated, though it was shown that bench-scale regeneration by steam oxidation and H{sub 2} reduction did not cause this deactivation. Characterization by TPR indicates that the loss of a low temperature nickel oxide reduction feature is related to the catalyst deactivation, which is ascribed to nickel being incorporated into a spinel nickel aluminate that is not reduced with the given activation protocol. Results for 100 h time-on-stream using a recirculating/regenerating reactor suggest that this type of process could be employed to keep a high level of steady-state reforming activity, without permanent deactivation of the catalyst. Additionally, the differences in catalyst performance using a simulated and real, biomass-derived syngas stream indicate that there are components present in the real stream that are not adequately modeled in the syngas stream. Heavy tars and polycyclic aromatics are known to be present in real syngas, and the use of benzene and naphthalene as surrogates may be insufficient. In addition, some inorganics found in biomass, which become concentrated in the ash following biomass gasification, may be transported to the reforming reactor where they can interact with catalysts. Therefore, in order to gain more representative results for how a catalyst would perform on an industrially-relevant scale, with real contaminants, appropriate small-scale biomass solids feeders or slip-streams of real process gas should be employed.

  12. Catalysis for Mixed Alcohol Synthesis from Biomass Derived Syngas: Cooperative Research and Development Final Report, CRADA Number CRD-08-292

    SciTech Connect (OSTI)

    Hensley, J.

    2013-04-01T23:59:59.000Z

    The Dow Chemical Company (Dow) developed and tested catalysts for production of mixed alcohols from synthesis gas (syngas), under research and development (R&D) projects that were discontinued a number of years ago. Dow possesses detailed laboratory notebooks, catalyst samples, and technical expertise related to this past work. The National Renewable Energy Laboratory (NREL) is conducting R&D in support of the United States Department of Energy (DOE) to develop methods for economically producing ethanol from gasified biomass. NREL is currently conducting biomass gasification research at an existing 1/2 ton/day thermochemical test platform. Both Dow and NREL believe that the ability to economically produce ethanol from biomass-derived syngas can be enhanced through collaborative testing, refinement, and development of Dow's mixed-alcohol catalysts at NREL's and/or Dow's bench- and pilot-scale facilities. Dow and NREL further agree that collaboration on improvements in catalysts as well as gasifier operating conditions (e.g., time, temperature, upstream gas treatment) will be necessary to achieve technical and economic goals for production of ethanol and other alcohols.

  13. Moessbauer spectroscopy studies of iron-catalysts used in Fischer-Tropsch (FT) processes. Quarterly technical progress report, January--March, 1994

    SciTech Connect (OSTI)

    Huffman, G.P.; Rao, K.R.P.M.

    1994-12-31T23:59:59.000Z

    The objective of this project is to carry out a Moessbauer spectroscopy study of Iron-based catalysts to identify iron phases present and correlate with water gas shift and FT activities. A total of 15 catalysts were evaluated so far. Results are presented on the amounts in each catalyst of the following phases: superparamagnetic phase, hematite ({alpha}-Fe{sub 2}O{sub 3}), magnetite (Fe{sub 3}O{sub 4}), Chi-carbide phase ({chi}-Fe{sub 5}C{sub 2}), and an epsilon-carbide phase ({var_epsilon}-Fe{sub 2.2}C).

  14. Synthesis of octane enhancers during slurry-phase Fischer-Tropsch. Quarterly technical progress report No. 9, October 1, 1992--December 31, 1992

    SciTech Connect (OSTI)

    Marcelin, G.

    1993-06-30T23:59:59.000Z

    Figure 7 summarizes the carbon selectivities observed towards the main products. During Period IV, the main products observed were the heavy hydrocarbons, with selectivity for MTBE being less than 3--5%. The only time that high MTBE selectivity was noted was during period III, when the i-butylene feed was shut-off. The large amounts of heavy products and the low selectivity to MTBE were surprising in view of our previous experiments in the gas phase and the high methanol-to-i-butylene ratio used in these runs. In the gas-phase and with methanol/i-butylene = 0.5, over 95% selectivity to MTBE was observed with this catalyst at this temperature. The higher level of methanol used here would be expected to further improve the MTBE selectivity. Perhaps one reason for the poor MTBE selectivity relates to the relative solubilities of the reactants in the Synfluid changing the effective methanol/i-butylene ratio. Figure 8 shows the relative molar concentration of i-butylene during Period III. At 180 minutes, the gas supply of that reactant was shut-off, yet the analyses show that i-butylene continued to elute from the reactor for at least an additional 2 hours. It seems reasonable that the i-butylene is highly soluble in the Synfluid since they are both nonpolar hydrocarbons. Likewise, one would expect the methanol to not be quite as soluble and thus the methanol/i-butylene ratio in the liquid medium may be very low, favoring the oligomerization of i-butylene. Indeed, the only time that MTBE selectivity was high was after the i-butylene supply was shut-off. We intend to quantify these solubilities in future experiments.

  15. Synthesis of octane enhancers during slurry-phase Fischer-Tropsch. Quarterly technical progress report No. 8, July 1, 1992--September 30, 1992

    SciTech Connect (OSTI)

    Marcelin, G.

    1993-07-07T23:59:59.000Z

    The initial work on the synthesis of MTBE during CO hydrogenation shows that MTBE cannot be formed directly on metal sites and likely requires the presence of an acid site. However, MTBE can be made successfully when an acid site, provided by the zeolites, is present in the vicinity of the methanol-synthesis metal sites. When i-butylene was added during CO hydrogenation over a composite catalyst consisting of Li-Pd/SiO{sub 2} and a hydrogen-zeolite, MTBE was formed in measurable amounts. The major by-product of this reaction scheme was isobutane and the dimer of i-butylene. In general, ZSM-5 was found to be superior to LZ210-12 HY zeolite. CO hydrogenation over a bifunctional PdNaY catalyst shows that branched hydrocarbons as well as MEOH can be made successfully at the same time. Addition of i-butylene over this catalyst only (i.e. without other zeolite) results in the formation of trace amounts of MTBE.

  16. New approach to the generation of metal-bearing, medium-pore, shape-selective zeolites for Fischer-Tropsch catalysis. [Aluminoferrisilicate

    SciTech Connect (OSTI)

    Iton, L.E.; Beal, R.B.; Hodul, D.T.

    1983-01-01T23:59:59.000Z

    A new method of combining the shape-selective characteristics of zeolites with a group VIII metal component is described. It involves the following sequence of steps: (1) synthesis of an aluminoferrisilicate (AFS) zeolite, having a crystal structure analogous to zeolite ZSM-5, but which incorporates ferric ions into the structure during synthesis; (2) removal of the organic base used as a template in crystallization of the AFS zeolite; (3) reaction of the AFS zeolite with a transition metal complex anion in aqueous solution to precipitate an inclusion compound in the AFS zeolite, and (4) reduction of the inclusion compound with hydrogen at elevated temperature.

  17. Biomass Energy for Transport and Electricity: Large scale utilization under low CO2 concentration scenarios

    SciTech Connect (OSTI)

    Luckow, Patrick; Wise, Marshall A.; Dooley, James J.; Kim, Son H.

    2010-01-25T23:59:59.000Z

    This paper examines the potential role of large scale, dedicated commercial biomass energy systems under global climate policies designed to stabilize atmospheric concentrations of CO2 at 400ppm and 450ppm. We use an integrated assessment model of energy and agriculture systems to show that, given a climate policy in which terrestrial carbon is appropriately valued equally with carbon emitted from the energy system, biomass energy has the potential to be a major component of achieving these low concentration targets. The costs of processing and transporting biomass energy at much larger scales than current experience are also incorporated into the modeling. From the scenario results, 120-160 EJ/year of biomass energy is produced by midcentury and 200-250 EJ/year by the end of this century. In the first half of the century, much of this biomass is from agricultural and forest residues, but after 2050 dedicated cellulosic biomass crops become the dominant source. A key finding of this paper is the role that carbon dioxide capture and storage (CCS) technologies coupled with commercial biomass energy can play in meeting stringent emissions targets. Despite the higher technology costs of CCS, the resulting negative emissions used in combination with biomass are a very important tool in controlling the cost of meeting a target, offsetting the venting of CO2 from sectors of the energy system that may be more expensive to mitigate, such as oil use in transportation. The paper also discusses the role of cellulosic ethanol and Fischer-Tropsch biomass derived transportation fuels and shows that both technologies are important contributors to liquid fuels production, with unique costs and emissions characteristics. Through application of the GCAM integrated assessment model, it becomes clear that, given CCS availability, bioenergy will be used both in electricity and transportation.

  18. Development and Application of Advanced Models for Steam Hydrogasification: Process Design and Economic Evaluation

    E-Print Network [OSTI]

    Lu, Xiaoming

    2012-01-01T23:59:59.000Z

    simulation model of a Battelle biomass-based gasification, Fischer–Tropsch liquefaction and combined-cycle power plant.

  19. Mixed Alcohol Synthesis Catalyst Screening

    SciTech Connect (OSTI)

    Gerber, Mark A.; White, James F.; Stevens, Don J.

    2007-09-03T23:59:59.000Z

    National Renewable Energy Laboratory (NREL) and Pacific Northwest National Laboratory (PNNL) are conducting research to investigate the feasibility of producing mixed alcohols from biomass-derived synthesis gas (syngas). PNNL is tasked with obtaining commercially available or preparing promising mixed-alcohol catalysts and screening them in a laboratory-scale reactor system. Commercially available catalysts and the most promising experimental catalysts are provided to NREL for testing using a slipstream from a pilot-scale biomass gasifier. From the standpoint of producing C2+ alcohols as the major product, it appears that the rhodium catalyst is the best choice in terms of both selectivity and space-time yield (STY). However, unless the rhodium catalyst can be improved to provide minimally acceptable STYs for commercial operation, mixed alcohol synthesis will involve significant production of other liquid coproducts. The modified Fischer-Tropsch catalyst shows the most promise for providing both an acceptable selectivity to C2+ alcohols and total liquid STY. However, further optimization of the Fischer-Tropsch catalysts to improve selectivity to higher alcohols is highly desired. Selection of a preferred catalyst will likely entail a decision on the preferred coproduct slate. No other catalysts tested appear amenable to the significant improvements needed for acceptable STYs.

  20. Catalysts for conversion of syngas to liquid motor fuels

    DOE Patents [OSTI]

    Rabo, Jule A. (Armonk, NY); Coughlin, Peter K. (Yorktown Heights, NY)

    1987-01-01T23:59:59.000Z

    Synthesis gas comprising carbon monoxide and hydrogen is converted to C.sub.5.sup.+ hydrocarbons suitable for use as liquid motor fuels by contact with a dual catalyst composition capable of ensuring the production of only relatively minor amounts of heavy products boiling beyond the diesel oil range. The catalyst composition, having desirable stability during continuous production operation, employs a Fischer-Tropsch catalyst, together with a co-catalyst/support component. The latter component is a steam-stabilized zeolite Y catalyst of hydrophobic character, desirably in acid-extracted form.

  1. OIL SHALE

    E-Print Network [OSTI]

    Fields (in-situ Combustion Approach; M. V. Kök; G. Guner; S. Bagci?

    Seyitömer, Himmeto?lu and Hat?lda? oil shale deposits. The results demonstrate that these oil shales are

  2. Guidelines for Transportation, Handling, and Use of Fast Pyrolysis Bio-Oil. Part 1. Flammability and Toxicity

    SciTech Connect (OSTI)

    Oasmaa, Anja; Kalli, Anssi; Lindfors, Christian; Elliott, Douglas C.; Springer, David L.; Peacocke, Cordner; Chiaramonti, David

    2012-05-04T23:59:59.000Z

    An alternative sustainable fuel, biomass-derived fast pyrolysis oil or 'bio-oil', is coming into the market. Fast pyrolysis pilot and demonstration plants for fuel applications producing tonnes of bio-oil are in operation, and commercial plants are under design. There will be increasingly larger amounts of bio-oil transportation on water and by land, leading to a need for specifications and supporting documentation. Bio-oil is different from conventional liquid fuels, and therefore must overcome both technical and marketing hurdles for its acceptability in the fuels market. A comprehensive Material Safety Data Sheet (MSDS) is required, backed with independent testing and certification. In order to standardise bio-oil quality specifications are needed. The first bio-oil burner fuel standard in ASTM (D7544) was approved in 2009. CEN standardisation has been initiated in Europe. In the EU a new chemical regulation system, REACH (Registration, Evaluation and Authorisation of Chemicals) is being applied. Registration under REACH has to be made if bio-oil is produced or imported to the EU. In the USA and Canada, bio-oil has to be filed under TOSCA (US Toxic Substances Control Act). In this paper the state of the art on standardisation is discussed, and new data for the transportation guidelines is presented. The focus is on flammability and toxicity.

  3. California's Energy Future - The View to 2050

    E-Print Network [OSTI]

    2011-01-01T23:59:59.000Z

    the biomass and coal to “syngas” (a mixture of hydrogen andfor making fuels from syngas, known as Fischer-Tropsch, is

  4. California’s Energy Future: The View to 2050 - Summary Report

    E-Print Network [OSTI]

    Yang, Christopher

    2011-01-01T23:59:59.000Z

    the biomass and coal to “syngas” (a mixture of hydrogen andfor making fuels from syngas, known as Fischer-Tropsch, is

  5. June 3, 2014 Webinar - Features, Events, and Processes: Practical...

    Broader source: Energy.gov (indexed) [DOE]

    & Publications HEFA and Fischer-Tropsch Jet Fuel Cost Analyses Proceedings of 3rd USGerman Workshop on Salt Repository Research, Design, and Operation Eastern Wind Integration...

  6. Biofuel Boundaries: Estimating the Medium-Term Supply Potential of Domestic Biofuels

    E-Print Network [OSTI]

    Jones, Andrew; O'Hare, Michael; Farrell, Alexander

    2007-01-01T23:59:59.000Z

    pathways, such as gasification. However, the current studysuch as MSW, the gasification to Fischer- Tropsch fuelof research on biomass gasification to FT-fuels compared to

  7. Otimização da produção de hidrogênio pela reforma a vapor do metano em reator com membrana laboratorial.

    E-Print Network [OSTI]

    Leandro Cardoso Silva

    2008-01-01T23:59:59.000Z

    ??Hydrogen is used as fuel and as a feedstock in important processes such as ammonia and methanol production and Fischer-Tropsch synthesis, besides the increasing use… (more)

  8. STATEMENT OF CONSIDERATIONS REQUEST BY HEADWATERS TECHNOLOGY...

    Broader source: Energy.gov (indexed) [DOE]

    a cooperative agreement for the performance of work entitled, "Production and Optimization of Coal-Derived High Hydrogen Content Fischer-Tropsch Liquids". The purpose of the...

  9. Essays on Macroeconomics and Oil

    E-Print Network [OSTI]

    CAKIR, NIDA

    2013-01-01T23:59:59.000Z

    the Oil Industry . . . . . . . . . . . . . . . . . . . . . .in the Venezuelan Oil Industry . . . . . . . . . . . . .and Productivity: Evidence from the Oil Industry . .

  10. Essays on Macroeconomics and Oil

    E-Print Network [OSTI]

    CAKIR, NIDA

    2013-01-01T23:59:59.000Z

    Oil Production . . . . . . . . . . . . . . . . . . . . . . . . . . .Oil Production in Venezuela and Mexico . . . . . . . . . .Oil Production and Productivity in Venezuela and

  11. Energy densification of biomass-derived organic acids

    DOE Patents [OSTI]

    Wheeler, M. Clayton; van Walsum, G. Peter; Schwartz, Thomas J.; van Heiningen, Adriaan

    2013-01-29T23:59:59.000Z

    A process for upgrading an organic acid includes neutralizing the organic acid to form a salt and thermally decomposing the resulting salt to form an energy densified product. In certain embodiments, the organic acid is levulinic acid. The process may further include upgrading the energy densified product by conversion to alcohol and subsequent dehydration.

  12. Characterization of Catalysts for Aftertreatment and Biomass-derived Fuels:

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-Up fromDepartmentTieCelebrate Earth Day withCharacterization and Valorization of

  13. Heterogeneous Catalyst for Improved Selectivity of Biomass-Derived

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsingFun with Bigfront.jpgcommunity200cellHeat TransferHelpingEnergyHermanMolecules -

  14. Hydrogen Production: Biomass-Derived Liquid Reforming | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:Year in3.pdfEnergy Health andof Energy EmbrittlementFact Sheet Hydrogen

  15. Biomass-derived Hydrogen-evolution catalyst and electrode - Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth (AOD)ProductssondeadjustsondeadjustAboutScienceCareers Apply for aCouldBiofuelHelpBiologyB I I O O m m

  16. Stability of Biomass-derived Black Carbon in Soils . | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administrationcontroller systemsBiSiteNeutron Scattering4 By I. Tudosa,Spreading

  17. Bioconversion of Heavy oil.

    E-Print Network [OSTI]

    Steinbakk, Sandra

    2011-01-01T23:59:59.000Z

    ??70 % of world?s oil reservoirs consist of heavy oil, and as the supply of conventional oil decreases, researchers are searching for new technologies to… (more)

  18. 5 World Oil Trends WORLD OIL TRENDS

    E-Print Network [OSTI]

    5 World Oil Trends Chapter 1 WORLD OIL TRENDS INTRODUCTION In considering the outlook for California's petroleum supplies, it is important to give attention to expecta- tions of what the world oil market. Will world oil demand increase and, if so, by how much? How will world oil prices be affected

  19. Hydrotreating of oil from eastern oil shale

    SciTech Connect (OSTI)

    Scinta, J.; Garner, J.W.

    1984-01-01T23:59:59.000Z

    Oil shale provides one of the major fossil energy reserves for the United States. The quantity of reserves in oil shale is less than the quantity in coal, but is much greater (by at least an order of magnitude) than the quantity of crude oil reserves. With so much oil potentially available from oil shale, efforts have been made to develop techniques for its utilization. In these efforts, hydrotreating has proved to be an acceptable technique for upgrading raw shale oil to make usuable products. The present work demonstrated the use of the hydrotreating technique for upgrading an oil from Indiana New Albany oil shale.

  20. Near Shore Submerged Oil Assessment

    E-Print Network [OSTI]

    ) oil spill in the Gulf of Mexico, submerged oil refers to near shore oil which has picked up sediments You Should Know About Submerged Oil 1. Submerged oil is relatively uncommon: DWH oil is a light crude

  1. Oil spill response resources

    E-Print Network [OSTI]

    Muthukrishnan, Shankar

    1996-01-01T23:59:59.000Z

    . ACKNOWLEDGMENTS. TABLE OF CONTENTS . . Vn INTRODUCTION. . Oil Pollution Act. Oil Spill Response Equipment . . OB JECTIVES . 12 LITERATURE REVIEW. United States Contingency Plan. . Response Resources Definition of Clean in Context to an Oil Spill. Oil... this fitle. Title IV expands federal authority in managing oil spill clean up operations and amends the provisions for oil spill clean up under the Federal Water Pollution Control Act. It also called for Oil spill plans for vessels and facilities starting...

  2. A Review and Perspective of Recent Bio-Oil Hydrotreating Research

    SciTech Connect (OSTI)

    Zacher, Alan H.; Olarte, Mariefel V.; Santosa, Daniel M.; Elliott, Douglas C.; Jones, Susanne B.

    2014-02-28T23:59:59.000Z

    The pathway for catalytic hydrodeoxygenation of biomass derived fast pyrolysis oil represents a compelling route for production of liquid transportation fuels. There has been continued progress and advancements in both the public and private research areas towards driving this technology to completion. Published research and patent literature have demonstrated that continued development of HDO as a part of a processes for production liquid transportation using biomass is being advanced for both fuel blend stocks and for refinery intermediates for co-processing. Much of the research has still focused on “quality” metrics around single or groups of unit operations generating partially treated bio-oil streams without assessing upstream and downstream implications. However, there is an encouraging amount of research that is now being targeted and assessed with attempts to understand the impact on the final fuel product, regardless of the route. Much of the most important research is moving towards continuous, industrially relevant processes where data can be generated to adequately inform process and economic modeling. As the technology for producing liquid transportation fuels from pyrolysis/HDO/coprocessing is driving towards commercialization, further research should be prioritized on the basis of impact to a techno-economic analyses.

  3. Cooperative Research in C1 Chemistry

    SciTech Connect (OSTI)

    Gerald P. Huffman

    2000-10-27T23:59:59.000Z

    C1 chemistry refers to the conversion of simple carbon-containing materials that contain one carbon atom per molecule into valuable products. The feedstocks for C1 chemistry include natural gas, carbon dioxide, carbon monoxide, methanol and synthesis gas (a mixture of carbon monoxide and hydrogen). Synthesis gas, or syngas, is produced primarily by the reaction of natural gas, which is principally methane, with steam. It can also be produced by gasification of coal, petroleum coke, or biomass. The availability of syngas from coal gasification is expected to increase significantly in the future because of increasing development of integrated gasification combined cycle (IGCC) power generation. Because of the abundance of remote natural gas, the advent of IGCC, and environmental advantages, C1 chemistry is expected to become a major area of interest for the transportation fuel and chemical industries in the relatively near future. The CFFLS will therefore perform a valuable national service by providing science and engineering graduates that are trained in this important area. Syngas is the source of most hydrogen. Approximately 10 trillion standard cubic feet (SCF) of hydrogen are manufactured annually in the world. Most of this hydrogen is currently used for the production of ammonia and in a variety of refining and chemical operations. However, utilization of hydrogen in fuel cells is expected to grow significantly in the next century. Syngas is also the feedstock for all methanol and Fischer-Tropsch plants. Currently, world consumption of methanol is over 25 million tons per year. There are many methanol plants in the U.S. and throughout the world. Methanol and oxygenated transportation fuel products play a significant role in the CFFLS C1 program. Currently, the only commercial Fischer-Tropsch plants are overseas, principally in South Africa (SASOL). However, new plants are being built or planned for a number of locations. One possible location for future F-T plant development in the U.S. is in the Alaskan oil fields.

  4. A Systems Approach to Bio-Oil Stabilization - Final Technical Report

    SciTech Connect (OSTI)

    Brown, Robert C; Meyer, Terrence; Fox, Rodney; Submramaniam, Shankar; Shanks, Brent; Smith, Ryan G

    2011-12-23T23:59:59.000Z

    The objective of this project is to develop practical, cost effective methods for stabilizing biomass-derived fast pyrolysis oil for at least six months of storage under ambient conditions. The U.S. Department of Energy has targeted three strategies for stabilizing bio-oils: (1) reducing the oxygen content of the organic compounds comprising pyrolysis oil; (2) removal of carboxylic acid groups such that the total acid number (TAN) of the pyrolysis oil is dramatically reduced; and (3) reducing the charcoal content, which contains alkali metals known to catalyze reactions that increase the viscosity of bio-oil. Alkali and alkaline earth metals (AAEM), are known to catalyze decomposition reactions of biomass carbohydrates to produce light oxygenates that destabilize the resulting bio-oil. Methods envisioned to prevent the AAEM from reaction with the biomass carbohydrates include washing the AAEM out of the biomass with water or dilute acid or infusing an acid catalyst to passivate the AAEM. Infusion of acids into the feedstock to convert all of the AAEM to salts which are stable at pyrolysis temperatures proved to be a much more economically feasible process. Our results from pyrolyzing acid infused biomass showed increases in the yield of anhydrosugars by greater than 300% while greatly reducing the yield of light oxygenates that are known to destabilize bio-oil. Particulate matter can interfere with combustion or catalytic processing of either syngas or bio-oil. It also is thought to catalyze the polymerization of bio-oil, which increases the viscosity of bio-oil over time. High temperature bag houses, ceramic candle filters, and moving bed granular filters have been variously suggested for syngas cleaning at elevated temperatures. High temperature filtration of bio-oil vapors has also been suggested by the National Renewable Energy Laboratory although there remain technical challenges to this approach. The fast pyrolysis of biomass yields three main organic products: condensable vapors, non-condensable gases, and liquid aerosols. Traditionally these are recovered by a spray quencher or a conventional shell and tube condenser. The spray quencher or condenser is typically followed by an electrostatic precipitator to yield 1 or 2 distinct fractions of bio-oil. The pyrolyzer system developed at Iowa State University incorporates a proprietary fractionating condenser train. The system collects the bio-oil into five unique fractions. For conditions typical of fluidized bed pyrolyzers, stage fractions have been collected that are carbohydrate-rich (anhydrosugars), lignin-rich, and an aqueous solution of carboxylic acids and aldehydes. One important feature is that most of the water normally found in bio-oil appears in the last stage fraction along with several water-soluble components that are thought to be responsible for bio-oil aging (low molecular weight carboxylic acids and aldehydes). Research work on laser diagnostics for hot-vapor filtration and bio-oil recovery centered on development of analytical techniques for in situ measurements during fast pyrolysis, hot-vapor filtration, and fractionation relative to bio-oil stabilization. The methods developed in this work include laser-induced breakdown spectroscopy (LIBS), laser-induced incandescence (LII), and laser scattering for elemental analysis (N, O, H, C), detection of particulates, and detection of aerosols, respectively. These techniques were utilized in simulated pyrolysis environments and applied to a small-scale pyrolysis unit. Stability of Bio-oils is adversely affected by the presence of particulates that are formed as a consequence of thermal pyrolysis, improving the CFD simulations of moving bed granular filter (MBGF) is useful for improving the design of MBGF for bio-oil production. The current work uses fully resolved direct numerical simulation (where the flow past each granule is accurately represented) to calculate the filter efficiency that is used in the CFD model at all flow speeds. This study shows that fully-resolved direct numerical simulation (DNS

  5. Crude Oil

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"Click worksheet9,1,50022,3,,,,6,1,,781Title: Telephone:shortOilCompanyexcluding taxes)Countries0 0 0 0 0

  6. Understanding Crude Oil Prices

    E-Print Network [OSTI]

    Hamilton, James Douglas

    2008-01-01T23:59:59.000Z

    business of having some oil in inventory, which is referredKnowledge of all the oil going into inventory today for salebe empty, because inventories of oil are essential for the

  7. China's Global Oil Strategy

    E-Print Network [OSTI]

    Thomas, Bryan G

    2009-01-01T23:59:59.000Z

    nations began to seek out oil reserves around the world. 3on the limited global oil reserves and spiking prices. Manyto the largest proven oil reserves, making up 61 percent of

  8. China's Global Oil Strategy

    E-Print Network [OSTI]

    Thomas, Bryan G

    2009-01-01T23:59:59.000Z

    Michael T. Klare, Blood and Oil: The Dangers of America’sDowns and Jeffrey A. Bader, “Oil-Hungry China Belongs at BigChina, Africa, and Oil,” (Council on Foreign Relations,

  9. Understanding Crude Oil Prices

    E-Print Network [OSTI]

    Hamilton, James Douglas

    2008-01-01T23:59:59.000Z

    Figure 5. Monthly oil production for Iran, Iraq, and Kuwait,day. Monthly crude oil production Iran Iraq Kuwait Figure 6.and the peak in U.S. oil production account for the broad

  10. Understanding Crude Oil Prices

    E-Print Network [OSTI]

    Hamilton, James Douglas

    2008-01-01T23:59:59.000Z

    2004. “OPEC’s Optimal Crude Oil Price,” Energy Policy 32(2),023 Understanding Crude Oil Prices James D. Hamilton Junedirectly. Understanding Crude Oil Prices* James D. Hamilton

  11. Understanding Crude Oil Prices

    E-Print Network [OSTI]

    Hamilton, James Douglas

    2008-01-01T23:59:59.000Z

    2004. “OPEC’s Optimal Crude Oil Price,” Energy Policy 32(2),percent change in real oil price. Figure 3. Price of crudein predicting quarterly real oil price change. variable real

  12. Understanding Crude Oil Prices

    E-Print Network [OSTI]

    Hamilton, James Douglas

    2008-01-01T23:59:59.000Z

    per day. Monthly crude oil production Iran Iraq KuwaitEIA Table 1.2, “OPEC Crude Oil Production (Excluding Lease2008, from EIA, “Crude Oil Production. ” Figure 16. U.S.

  13. Understanding Crude Oil Prices

    E-Print Network [OSTI]

    Hamilton, James Douglas

    2008-01-01T23:59:59.000Z

    2004. “OPEC’s Optimal Crude Oil Price,” Energy Policy 32(2),percent change in real oil price. Figure 3. Price of crude023 Understanding Crude Oil Prices James D. Hamilton June

  14. Understanding Crude Oil Prices

    E-Print Network [OSTI]

    Hamilton, James Douglas

    2008-01-01T23:59:59.000Z

    Natural Gas, Heating Oil and Gasoline,” NBER Working Paper.2006. “China’s Growing Demand for Oil and Its Impact on U.S.and Income on Energy and Oil Demand,” Energy Journal 23(1),

  15. China's Global Oil Strategy

    E-Print Network [OSTI]

    Thomas, Bryan G

    2009-01-01T23:59:59.000Z

    capability to secure oil transport security. Additionally,international oil agreements: 1) ensuring energy security;security, and many argue that as the second-largest consumer of oil

  16. China's Global Oil Strategy

    E-Print Network [OSTI]

    Thomas, Bryan G

    2009-01-01T23:59:59.000Z

    China made an Iranian oil investment valued at $70 billion.across Iran, China’s oil investment may exceed $100 billionthese involving investment in oil and gas, really undermine

  17. Understanding Crude Oil Prices

    E-Print Network [OSTI]

    Hamilton, James Douglas

    2008-01-01T23:59:59.000Z

    2007”. comparison, Mexico used 6.6— Chinese oil consumption17. Oil production from the North Sea, Mexico’s Cantarell,Mexico, Italy, France, Canada, US, and UK. Figure 10. Historical Chinese oil

  18. China's Global Oil Strategy

    E-Print Network [OSTI]

    Thomas, Bryan G

    2009-01-01T23:59:59.000Z

    by this point, China’s demand Oil Demand vs. Domestic Supplycurrent pace of growth in oil demand as staying consistentand predictions of oil supply and demand affected foreign

  19. Understanding Crude Oil Prices

    E-Print Network [OSTI]

    Hamilton, James Douglas

    2008-01-01T23:59:59.000Z

    and Income on Energy and Oil Demand,” Energy Journal 23(1),2006. “China’s Growing Demand for Oil and Its Impact on U.S.in the supply or demand for oil itself could be regarded as

  20. Large-Scale Utilization of Biomass Energy and Carbon Dioxide Capture and Storage in the Transport and Electricity Sectors under Stringent CO2 Concentration Limit Scenarios

    SciTech Connect (OSTI)

    Luckow, Patrick; Wise, Marshall A.; Dooley, James J.; Kim, Son H.

    2010-08-05T23:59:59.000Z

    This paper examines the potential role of large scale, dedicated commercial biomass energy systems under global climate policies designed to meet atmospheric concentrations of CO2 at 400ppm and 450ppm by the end of the century. We use an integrated assessment model of energy and agriculture systems to show that, given a climate policy in which terrestrial carbon is appropriately valued equally with carbon emitted from the energy system, biomass energy has the potential to be a major component of achieving these low concentration targets. A key aspect of the research presented here is that the costs of processing and transporting biomass energy at much larger scales than current experience are explicitly incorporated into the modeling. From the scenario results, 120-160 EJ/year of biomass energy is produced globally by midcentury and 200-250 EJ/year by the end of this century. In the first half of the century, much of this biomass is from agricultural and forest residues, but after 2050 dedicated cellulosic biomass crops become the majority source, along with growing utilization of waste-to-energy. The ability to draw on a diverse set of biomass based feedstocks helps to reduce the pressure for drastic large-scale changes in land use and the attendant environmental, ecological, and economic consequences those changes would unleash. In terms of the conversion of bioenergy feedstocks into value added energy, this paper demonstrates that biomass is and will continue to be used to generate electricity as well as liquid transportation fuels. A particular focus of this paper is to show how climate policies and technology assumptions - especially the availability of carbon dioxide capture and storage (CCS) technologies - affect the decisions made about where the biomass is used in the energy system. The potential for net-negative electric sector emissions through the use of CCS with biomass feedstocks provides an attractive part of the solution for meeting stringent emissions constraints; we find that at carbon prices above 150$/tCO2, over 90% of biomass in the energy system is used in combination with CCS. Despite the higher technology costs of CCS, it is a very important tool in controlling the cost of meeting a target, offsetting the venting of CO2 from sectors of the energy system that may be more expensive to mitigate, such as oil use in transportation. CCS is also used heavily with other fuels such as coal and natural gas, and by 2095 a total of 1530 GtCO2 has been stored in deep geologic reservoirs. The paper also discusses the role of cellulosic ethanol and Fischer-Tropsch biomass derived transportation fuels as two representative conversion processes and shows that both technologies may be important contributors to liquid fuels production, with unique costs and emissions characteristics.

  1. Understanding Crude Oil Prices

    E-Print Network [OSTI]

    Hamilton, James Douglas

    2008-01-01T23:59:59.000Z

    2007”. comparison, Mexico used 6.6— Chinese oil consumption17. Oil production from the North Sea, Mexico’s Cantarell,

  2. Biochemically enhanced oil recovery and oil treatment

    SciTech Connect (OSTI)

    Premuzic, Eugene T. (East Moriches, NY); Lin, Mow (Rocky Point, NY)

    1994-01-01T23:59:59.000Z

    This invention relates to the preparation of new, modified organisms, through challenge growth processes, that are viable in the extreme temperature, pressure and pH conditions and salt concentrations of an oil reservoir and that are suitable for use in microbial enhanced oil recovery. The modified microorganisms of the present invention are used to enhance oil recovery and remove sulfur compounds and metals from the crude oil.

  3. Biochemically enhanced oil recovery and oil treatment

    DOE Patents [OSTI]

    Premuzic, E.T.; Lin, M.

    1994-03-29T23:59:59.000Z

    This invention relates to the preparation of new, modified organisms, through challenge growth processes, that are viable in the extreme temperature, pressure and pH conditions and salt concentrations of an oil reservoir and that are suitable for use in microbial enhanced oil recovery. The modified microorganisms of the present invention are used to enhance oil recovery and remove sulfur compounds and metals from the crude oil. 62 figures.

  4. OIL & GAS INSTITUTE Introduction

    E-Print Network [OSTI]

    Mottram, Nigel

    OIL & GAS INSTITUTE CONTENTS Introduction Asset Integrity Underpinning Capabilities 2 4 4 6 8 9 10 COMPETITIVENESS UNIVERSITY of STRATHCLYDE OIL & GAS INSTITUTE OIL & GAS EXPERTISE AND PARTNERSHIPS #12;1 The launch of the Strathclyde Oil & Gas Institute represents an important step forward for the University

  5. Eco Oil 4

    SciTech Connect (OSTI)

    Brett Earl; Brenda Clark

    2009-10-26T23:59:59.000Z

    This article describes the processes, challenges, and achievements of researching and developing a biobased motor oil.

  6. Understanding Crude Oil Prices

    E-Print Network [OSTI]

    Hamilton, James Douglas

    2008-01-01T23:59:59.000Z

    consumption would be reduced and incentives for production increased whenever the price of crude oil

  7. AN ENGINE OIL LIFE ALGORITHM.

    E-Print Network [OSTI]

    Bommareddi, Anveshan

    2009-01-01T23:59:59.000Z

    ??An oil-life algorithm to calculate the remaining percentage of oil life is presented as a means to determine the right time to change the oil… (more)

  8. Essays on Macroeconomics and Oil

    E-Print Network [OSTI]

    CAKIR, NIDA

    2013-01-01T23:59:59.000Z

    is described below. Data Crude oil production data is fromproductivity measure is crude oil production per worker, andwhich is measured as crude oil production per worker, is

  9. Essays on Macroeconomics and Oil

    E-Print Network [OSTI]

    CAKIR, NIDA

    2013-01-01T23:59:59.000Z

    Venezuelan Oil Industry Total Wells Drilled and InvestmentWells Drilled and Investment in the Venezuelan Oil Industryopenness of the oil sector to foreign investment contributes

  10. Essays on Macroeconomics and Oil

    E-Print Network [OSTI]

    CAKIR, NIDA

    2013-01-01T23:59:59.000Z

    Oil Production in Venezuela and Mexico . . . . . . . . . .Venezuela with Mexico, another major oil pro- ducing countryOil Production and Productivity in Venezuela and Mexico . . . . . . . .

  11. Essays on Macroeconomics and Oil

    E-Print Network [OSTI]

    CAKIR, NIDA

    2013-01-01T23:59:59.000Z

    Oil Production in Venezuela and Mexico . . . . . . . . . .Oil Production and Productivity in Venezuela and Mexico . . . . . . . .2.6: Oil Production in Venezuela and Mexico 350 Productivity

  12. Apparatus for distilling shale oil from oil shale

    SciTech Connect (OSTI)

    Shishido, T.; Sato, Y.

    1984-02-14T23:59:59.000Z

    An apparatus for distilling shale oil from oil shale comprises: a vertical type distilling furnace which is divided by two vertical partitions each provided with a plurality of vent apertures into an oil shale treating chamber and two gas chambers, said oil shale treating chamber being located between said two gas chambers in said vertical type distilling furnace, said vertical type distilling furnace being further divided by at least one horizontal partition into an oil shale distilling chamber in the lower part thereof and at least one oil shale preheating chamber in the upper part thereof, said oil shale distilling chamber and said oil shale preheating chamber communication with each other through a gap provided at an end of said horizontal partition, an oil shale supplied continuously from an oil shale supply port provided in said oil shale treating chamber at the top thereof into said oil shale treating chamber continuously moving from the oil shale preheating chamber to the oil shale distilling chamber, a high-temperature gas blown into an oil shale distilling chamber passing horizontally through said oil shale in said oil shale treating chamber, thereby said oil shale is preheated in said oil shale preheating chamber, and a gaseous shale oil is distilled from said preheated oil shale in said oil shale distilling chamber; and a separator for separating by liquefaction a gaseous shale oil from a gas containing the gaseous shale oil discharged from the oil shale preheating chamber.

  13. Libyan oil industry

    SciTech Connect (OSTI)

    Waddams, F.C.

    1980-01-01T23:59:59.000Z

    Three aspects of the growth and progress of Libya's oil industry since the first crude oil discovery in 1961 are: (1) relations between the Libyan government and the concessionary oil companies; (2) the impact of Libyan oil and events in Libya on the petroleum markets of Europe and the world; and (3) the response of the Libyan economy to the development of its oil industry. The historical review begins with Libya's becoming a sovereign nation in 1951 and traces its subsequent development into a position as a leading world oil producer. 54 references, 10 figures, 55 tables.

  14. Effect of engine operating parameters and fuel characteristics on diesel engine emissions

    E-Print Network [OSTI]

    Acar, Joseph, 1977-

    2005-01-01T23:59:59.000Z

    To examine the effects of using synthetic Fischer-Tropsch (FT) diesel fuel in a modern compression ignition engine, experiments were conducted on a MY 2002 Cummins 5.9 L diesel engine outfitted with high pressure, common ...

  15. Coal liquefaction and gas conversion: Proceedings. Volume 2

    SciTech Connect (OSTI)

    Not Available

    1993-12-31T23:59:59.000Z

    Volume II contains papers presented at the following sessions: Indirect Liquefaction (oxygenated fuels); and Indirect Liquefaction (Fischer-Tropsch technology). Selected papers have been processed separately for inclusion in the Energy Science and Technology Database.

  16. Theoretical Cluster Studies on the Catalytic Sulfidation of MoO3 Xue-Rong Shi,,,

    E-Print Network [OSTI]

    , State Key Laboratory of Coal ConVersion, Institute of Coal Chemistry, Chinese Academy of Sciences (HDN) processes and exhibit also high activity for methanation and for the Fischer-Tropsch synthesis and sulfur adsor- bates as well as hydrogen

  17. CALIFORNIA ALTERNATIVE FUELS MARKET ASSESSMENT

    E-Print Network [OSTI]

    , Contract Manager Ray Tuvell, Manager EMERGING FUELS & TECHNOLOGY OFFICE Rosella Shapiro, Deputy Director gas, propane, ethanol, electricity, alternative diesel fuels such as biodiesel and Fischer Tropsch, natural gas vehicles, propane vehicles, electric vehicles, ethanol fuel, E-85, biodiesel, Fischer

  18. NETL F 451.1-1/1 Categorical Exclusion (CX) Designation Form

    Broader source: Energy.gov (indexed) [DOE]

    - 103111 Grand Forks, ND Fischer-Tropsch Fuels Development Construction of a cold-syngas cleanup reactor for the FT portion of the overall project that is designed to use...

  19. Yosemite Waters Vehicle Evaluation Report: Final Results

    SciTech Connect (OSTI)

    Eudy, L.; Barnitt, R.; Alleman, T. L.

    2005-08-01T23:59:59.000Z

    Document details the evaluation of Fischer-Tropsch diesel, a gas-to-liquid fuel, in medium-duty delivery vehicles at Yosemite Waters. The study was conducted by NREL at the company's Fullerton, California, bottling headquarters.

  20. E-Print Network 3.0 - aqueous-phase rh-norbos catalysts Sample...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Pt-99 wt.% Al2O3... Fischer-Tropsch synthesis using Co and Ru supported on silica aerogels as catalysts 21 Metal impregnation Source: Consortium for Fossil Fuel Science, C1...

  1. A tribute to Tom Ziegler Biographical sketch --From Copenhagen to Calgary

    E-Print Network [OSTI]

    Ziegler, Tom

    with research on solid oxide fuel cells (SOFC) and Fischer­Tropsch synthesis, again with substantial support- lecular dynamics method that makes it possible to optimize transition-state structures on the free energy

  2. Greenhouse Gas Emissions from Aviation and Marine Transportation: Mitigation Potential and Policies

    E-Print Network [OSTI]

    McCollum, David L; Gould, Gregory; Greene, David L

    2010-01-01T23:59:59.000Z

    to create a synthetic bio- based fuel that is chemicallyBoeing/NASA Synthetic bio-based fuels, Fischer-Tropsch (FT)ICAO 2009b). Synthetic bio-based fuels include bio-based jet

  3. Autothermal oxidative pyrolysis of biomass feedstocks over noble metal catalysts to liquid products.

    E-Print Network [OSTI]

    Balonek, Christine Marie

    2011-01-01T23:59:59.000Z

    ??Two thermal processing technologies have emerged for processing biomass into renewable liquid products: pyrolysis and gasification/Fischer-Tropsch processing. The work presented here will demonstrate oxidative pyrolysis… (more)

  4. The Prospects for Coal-To-Liquid Conversion: A General Equilibrium Analysis

    E-Print Network [OSTI]

    Chen, Y.-H. Henry

    We investigate the economics of coal-to-liquid (CTL) conversion, a polygeneration technology that produces liquid fuels, chemicals, and electricity by coal gasification and Fischer-Tropsch process. CTL is more expensive ...

  5. CX-002358: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Fischer-Tropsch Fuels DevelopmentCX(s) Applied: B3.6Date: 05/10/2010Location(s): Grand Forks, North DakotaOffice(s): Fossil Energy, National Energy Technology Laboratory

  6. CX-011112: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Innovative Gasification to Produce Fischer-Tropsch Jet and Diesel Fuel CX(s) Applied: A9 Date: 08/15/2013 Location(s): Iowa Offices(s): Golden Field Office

  7. CX-009372: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Small Scale Coal-Biomass to Liquids Using Highly Selective Fischer-Tropsch Synthesis CX(s) Applied: A9 Date: 09/17/2012 Location(s): California Offices(s): National Energy Technology Laboratory

  8. Oil and Gas Supply Module

    Gasoline and Diesel Fuel Update (EIA)

    Onshore Lower 48 Oil and Gas Supply Submodule, Offshore Oil and Gas Supply Submodule, Oil Shale Supply Submodule1, and Alaska Oil and Gas Supply Submodule. A detailed description...

  9. Oil and Gas Supply Module

    Gasoline and Diesel Fuel Update (EIA)

    Onshore Lower 48 Oil and Gas Supply Submodule, Offshore Oil and Gas Supply Submodule, Oil Shale Supply Submodule, and Alaska Oil and Gas Supply Submodule. A detailed description of...

  10. REVIEW PAPER Biodeterioration of crude oil and oil derived

    E-Print Network [OSTI]

    Appanna, Vasu

    , the majority of applied microbiologi- cal methods of enhanced oil recovery also dete- riorates oil and appearsREVIEW PAPER Biodeterioration of crude oil and oil derived products: a review Natalia A. Yemashova January 2007 Ó Springer Science+Business Media B.V. 2007 Abstract Biodeterioration of crude oil and oil

  11. Using Oils As Pesticides

    E-Print Network [OSTI]

    Bogran, Carlos E.; Ludwig, Scott; Metz, Bradley

    2006-10-30T23:59:59.000Z

    Petroleum and plant-derived spray oils show increasing potential for use as part of Integrated Pest Management systems for control of soft-bodied pests on fruit trees, shade trees, woody ornamentals and household plants. Sources of oils, preparing...

  12. Oil and Gas Exploration

    E-Print Network [OSTI]

    Tingley, Joseph V.

    Metals Industrial Minerals Oil and Gas Geothermal Exploration Development Mining Processing Nevada, oil and gas, and geothermal activities and accomplishments in Nevada: production statistics, exploration and development including drilling for petroleum and geothermal resources, discoveries of ore

  13. Understanding Crude Oil Prices

    E-Print Network [OSTI]

    Hamilton, James Douglas

    2008-01-01T23:59:59.000Z

    an alternative investment strategy to buying oil today andinvestments necessary to catch up. This was the view o?ered by oilinvestment strategy. date t) in order to purchase a quantity Q barrels of oil

  14. Gas and Oil (Maryland)

    Broader source: Energy.gov [DOE]

    The Department of the Environment has the authority to enact regulations pertaining to oil and gas production, but it cannot prorate or limit the output of any gas or oil well. A permit from the...

  15. China's Global Oil Strategy

    E-Print Network [OSTI]

    Thomas, Bryan G

    2009-01-01T23:59:59.000Z

    21, 2008. Ying, Wang. “ China, Venezuela firms to co-developApril 21, “China and Venezuela sign oil agreements. ” Chinaaccessed April 21, “Venezuela and China sign oil deal. ” BBC

  16. Oil Sands Feedstocks

    Broader source: Energy.gov (indexed) [DOE]

    NCUT National Centre for Upgrading Technology 'a Canada-Alberta alliance for bitumen and heavy oil research' Oil Sands Feedstocks C Fairbridge, Z Ring, Y Briker, D Hager National...

  17. Utilizing the heat content of gas-to-liquids by-product streams for commercial power generation

    E-Print Network [OSTI]

    Adegoke, Adesola Ayodeji

    2006-10-30T23:59:59.000Z

    -SeparationUnit........................................................................18 3.4.3SyngasGeneration..........................................................................18 3.4.4Fischer-Tropsch(FT)Synthesis.....................................................20 viii CHAPTER Page 3.4.5Product...Description TherearethreestagesinvolvedintheconversionofnaturalgasintoGTLfuels-Syngas generation,Fischer-Tropsch(FT)synthesis,andProductupgrade.Adetailedresultofthe processmodelinginAspenPlusisincludedinAppendixB,whiletheactualprocessmap isshowninFigureA1inAppendixAandFigure3.1below. 17...

  18. F-T process using an iron on mixed zirconia-titania supported catalyst

    DOE Patents [OSTI]

    Dyer, Paul N. (Allentown, PA); Nordquist, Andrew F. (Whitehall, PA); Pierantozzi, Ronald (Macungie, PA)

    1987-01-01T23:59:59.000Z

    A Fischer-Tropsch catalyst comprising iron co-deposited with or deposited on particles comprising a mixture of zirconia and titania, preferably formed by co-precipitation of compounds convertible to zirconia and titania, such as zirconium and titanium alkoxide. The invention also comprises the method of making this catalyst and an improved Fischer-Tropsch reaction process in which the catalyst is utilized.

  19. SRC Residual fuel oils

    DOE Patents [OSTI]

    Tewari, Krishna C. (Whitehall, PA); Foster, Edward P. (Macungie, PA)

    1985-01-01T23:59:59.000Z

    Coal solids (SRC) and distillate oils are combined to afford single-phase blends of residual oils which have utility as fuel oils substitutes. The components are combined on the basis of their respective polarities, that is, on the basis of their heteroatom content, to assure complete solubilization of SRC. The resulting composition is a fuel oil blend which retains its stability and homogeneity over the long term.

  20. Biochemical upgrading of oils

    DOE Patents [OSTI]

    Premuzic, E.T.; Lin, M.S.

    1999-01-12T23:59:59.000Z

    A process for biochemical conversion of heavy crude oils is provided. The process includes contacting heavy crude oils with adapted biocatalysts. The resulting upgraded oil shows, a relative increase in saturated hydrocarbons, emulsions and oxygenates and a decrease in compounds containing organic sulfur, organic nitrogen and trace metals. Adapted microorganisms which have been modified under challenged growth processes are also disclosed. 121 figs.

  1. Utah Heavy Oil Program

    SciTech Connect (OSTI)

    J. Bauman; S. Burian; M. Deo; E. Eddings; R. Gani; R. Goel; C.K. Huang; M. Hogue; R. Keiter; L. Li; J. Ruple; T. Ring; P. Rose; M. Skliar; P.J. Smith; J.P. Spinti; P. Tiwari; J. Wilkey; K. Uchitel

    2009-10-20T23:59:59.000Z

    The Utah Heavy Oil Program (UHOP) was established in June 2006 to provide multidisciplinary research support to federal and state constituents for addressing the wide-ranging issues surrounding the creation of an industry for unconventional oil production in the United States. Additionally, UHOP was to serve as an on-going source of unbiased information to the nation surrounding technical, economic, legal and environmental aspects of developing heavy oil, oil sands, and oil shale resources. UHOP fulGilled its role by completing three tasks. First, in response to the Energy Policy Act of 2005 Section 369(p), UHOP published an update report to the 1987 technical and economic assessment of domestic heavy oil resources that was prepared by the Interstate Oil and Gas Compact Commission. The UHOP report, entitled 'A Technical, Economic, and Legal Assessment of North American Heavy Oil, Oil Sands, and Oil Shale Resources' was published in electronic and hard copy form in October 2007. Second, UHOP developed of a comprehensive, publicly accessible online repository of unconventional oil resources in North America based on the DSpace software platform. An interactive map was also developed as a source of geospatial information and as a means to interact with the repository from a geospatial setting. All documents uploaded to the repository are fully searchable by author, title, and keywords. Third, UHOP sponsored Give research projects related to unconventional fuels development. Two projects looked at issues associated with oil shale production, including oil shale pyrolysis kinetics, resource heterogeneity, and reservoir simulation. One project evaluated in situ production from Utah oil sands. Another project focused on water availability and produced water treatments. The last project considered commercial oil shale leasing from a policy, environmental, and economic perspective.

  2. Manufacture of refrigeration oils

    SciTech Connect (OSTI)

    Chesluk, R.P.; Platte, H.J.; Sequeira, A.J.

    1981-12-08T23:59:59.000Z

    Lubricating oils suitable for use in refrigeration equipment in admixture with fluorinated hydrocarbon refrigerants are produced by solvent extraction of naphthenic lubricating oil base stocks, cooling the resulting extract mixture, optionally with the addition of a solvent modifier, to form a secondary raffinate and a secondary extract, and recovering a dewaxed oil fraction of lowered pour point from the secondary raffinate as a refrigeration oil product. The process of the invention obviates the need for a separate dewaxing operation, such as dewaxing with urea, as conventionally employed for the production of refrigeration oils.

  3. Carcinogenicity Studies of Estonian Oil Shale Soots

    E-Print Network [OSTI]

    A. Vosamae

    determine the carcinogenicity of Estonian oil shale soot as well as the soot from oil shale fuel oil. All

  4. Crude Oil Analysis Database

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Shay, Johanna Y.

    The composition and physical properties of crude oil vary widely from one reservoir to another within an oil field, as well as from one field or region to another. Although all oils consist of hydrocarbons and their derivatives, the proportions of various types of compounds differ greatly. This makes some oils more suitable than others for specific refining processes and uses. To take advantage of this diversity, one needs access to information in a large database of crude oil analyses. The Crude Oil Analysis Database (COADB) currently satisfies this need by offering 9,056 crude oil analyses. Of these, 8,500 are United States domestic oils. The database contains results of analysis of the general properties and chemical composition, as well as the field, formation, and geographic location of the crude oil sample. [Taken from the Introduction to COAMDATA_DESC.pdf, part of the zipped software and database file at http://www.netl.doe.gov/technologies/oil-gas/Software/database.html] Save the zipped file to your PC. When opened, it will contain PDF documents and a large Excel spreadsheet. It will also contain the database in Microsoft Access 2002.

  5. World Oil: Market or Mayhem?

    E-Print Network [OSTI]

    Smith, James L.

    2008-01-01T23:59:59.000Z

    The world oil market is regarded by many as a puzzle. Why are oil prices so volatile? What is OPEC and what does OPEC do? Where are oil prices headed in the long run? Is “peak oil” a genuine concern? Why did oil prices ...

  6. Oil and Gas (Indiana)

    Broader source: Energy.gov [DOE]

    This division of the Indiana Department of Natural Resources provides information on the regulation of oil and gas exploration, wells and well spacings, drilling, plugging and abandonment, and...

  7. Essays on Macroeconomics and Oil

    E-Print Network [OSTI]

    CAKIR, NIDA

    2013-01-01T23:59:59.000Z

    reserves. In the data, crude oil reserve addi- tions consistForce and Proven Reserves in the Venezuelan Oil Industry .such as crude oil production, proved reserves, new reserves,

  8. Oil and Gas Production (Missouri)

    Broader source: Energy.gov [DOE]

    A State Oil and Gas Council regulates and oversees oil and gas production in Missouri, and conducts a biennial review of relevant rules and regulations. The waste of oil and gas is prohibited. This...

  9. Oil shale technology

    SciTech Connect (OSTI)

    Lee, S. (Akron Univ., OH (United States). Dept. of Chemical Engineering)

    1991-01-01T23:59:59.000Z

    Oil shale is undoubtedly an excellent energy source that has great abundance and world-wide distribution. Oil shale industries have seen ups and downs over more than 100 years, depending on the availability and price of conventional petroleum crudes. Market forces as well as environmental factors will greatly affect the interest in development of oil shale. Besides competing with conventional crude oil and natural gas, shale oil will have to compete favorably with coal-derived fuels for similar markets. Crude shale oil is obtained from oil shale by a relatively simple process called retorting. However, the process economics are greatly affected by the thermal efficiencies, the richness of shale, the mass transfer effectiveness, the conversion efficiency, the design of retort, the environmental post-treatment, etc. A great many process ideas and patents related to the oil shale pyrolysis have been developed; however, relatively few field and engineering data have been published. Due to the vast heterogeneity of oil shale and to the complexities of physicochemical process mechanisms, scientific or technological generalization of oil shale retorting is difficult to achieve. Dwindling supplied of worldwide petroleum reserves, as well as the unprecedented appetite of mankind for clean liquid fuel, has made the public concern for future energy market grow rapidly. the clean coal technology and the alternate fuel technology are currently of great significance not only to policy makers, but also to process and chemical researchers. In this book, efforts have been made to make a comprehensive text for the science and technology of oil shale utilization. Therefore, subjects dealing with the terminological definitions, geology and petrology, chemistry, characterization, process engineering, mathematical modeling, chemical reaction engineering, experimental methods, and statistical experimental design, etc. are covered in detail.

  10. Marathon Oil Company

    E-Print Network [OSTI]

    unknown authors

    Marine oil shale from the Shenglihe oil shale section in the Qiangtang basin, northern Tibet, China, was dated by the Re-Os technique using Carius Tube digestion, Os distillation, Re extraction by acetone and ICP-MS measure-ment. An isochron was obtained giving an age of 101±24 Ma with an initial

  11. Synthetic aircraft turbine oil

    SciTech Connect (OSTI)

    Yaffe, R.

    1982-03-16T23:59:59.000Z

    Synthetic lubricating oil composition having improved oxidation stability comprising a major portion of an aliphatic ester base oil having lubricating properties, formed by the reaction of pentaerythritol and an organic monocarboxylic acid and containing a phenylnaphthylamine, a dialkyldiphenylamine, a polyhydroxy anthraquinone, a hydrocarbyl phosphate ester and a dialkyldisulfide.

  12. Chinaâs Oil Diplomacy with Russia.

    E-Print Network [OSTI]

    Chao, Jiun-chuan

    2011-01-01T23:59:59.000Z

    ??In Chinaâs view, it is necessary to get crude oil and oil pipeline. Under Russia and China strategic partnership, China tries to obtain âlong term… (more)

  13. OIL SHALE DEVELOPMENT IN CHINA

    E-Print Network [OSTI]

    J. Qian; J. Wang; S. Li

    In this paper history, current status and forecast of Chinese oil shale indus-try, as well as the characteristics of some typical Chinese oil shales are given.

  14. Peak oil: diverging discursive pipelines.

    E-Print Network [OSTI]

    Doctor, Jeff

    2012-01-01T23:59:59.000Z

    ??Peak oil is the claimed moment in time when global oil production reaches its maximum rate and henceforth forever declines. It is highly controversial as… (more)

  15. Petroleum Oil | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Petroleum Oil Petroleum Oil The production of energy feedstock and fuels requires substantial water input. Not only do biofuel feedstocks like corn, switchgrass and agricultural...

  16. Balancing oil and environment... responsibly.

    SciTech Connect (OSTI)

    Weimer, Walter C.; Teske, Lisa

    2007-01-25T23:59:59.000Z

    Balancing Oil and Environment…Responsibly As the price of oil continues to skyrocket and global oil production nears the brink, pursuing unconventional oil supplies, such as oil shale, oil sands, heavy oils, and oils from biomass and coal has become increasingly attractive. Of particular significance to the American way is that our continent has significant quantities of these resources. Tapping into these new resources, however, requires cutting-edge technologies for identification, production, processing and environmental management. This job needs a super hero or two for a job of this size and proportion…

  17. Essays on Macroeconomics and Oil

    E-Print Network [OSTI]

    CAKIR, NIDA

    2013-01-01T23:59:59.000Z

    Oil Production in Venezuela and Mexico . . . . . . . . . .and Productivity in Venezuela and Mexico . . . . . . . . OilEllner, ”Organized Labor in Venezuela 1958-1991: Behavior

  18. Selected Abstracts & Bibliography of International Oil Spill Research, through 1998

    E-Print Network [OSTI]

    Louisiana Applied Oil Spill Research & Development Program Electronic Bibliography

    1998-01-01T23:59:59.000Z

    Kuwait, Middle East, oil and gas fields, oil refinery, oil waste, oil well,Equipment Kuwait Oil Co. 1991. Mideast well fire, oil spillKuwait, Persian Gulf, Saudia Arabia, Oil spill, cleanup, oil spills, crude, oil spill incidents, oil spills-pipeline, warfare, oil skimmers, oil wells,

  19. Imbibition assisted oil recovery

    E-Print Network [OSTI]

    Pashayev, Orkhan H.

    2004-11-15T23:59:59.000Z

    analyzed in detail to investigate oil recovery during spontaneous imbibition with different types of boundary conditions. The results of these studies have been upscaled to the field dimensions. The validity of the new definition of characteristic length...

  20. Oil Market Assessment

    Reports and Publications (EIA)

    2001-01-01T23:59:59.000Z

    Based on Energy Information Administration (EIA) contacts and trade press reports, overall U.S. and global oil supplies appear to have been minimally impacted by yesterday's terrorist attacks on the World Trade Center and the Pentagon.

  1. Production of Shale Oil

    E-Print Network [OSTI]

    Loper, R. D.

    1982-01-01T23:59:59.000Z

    Intensive pre-project feasibility and engineering studies begun in 1979 have produced an outline plan for development of a major project for production of shale oil from private lands in the Piceance Basin in western Colorado. This outline plan...

  2. Oil shale research in China

    SciTech Connect (OSTI)

    Jianqiu, W.; Jialin, Q. (Beijing Graduate School, Petroleum Univ., Beijing (CN))

    1989-01-01T23:59:59.000Z

    There have been continued efforts and new emergence in oil shale research in Chine since 1980. In this paper, the studies carried out in universities, academic, research and industrial laboratories in recent years are summarized. The research areas cover the chemical structure of kerogen; thermal behavior of oil shale; drying, pyrolysis and combustion of oil shale; shale oil upgrading; chemical utilization of oil shale; retorting waste water treatment and economic assessment.

  3. Biocatalysis in Oil Refining

    SciTech Connect (OSTI)

    Borole, Abhijeet P [ORNL; Ramirez-Corredores, M. M. [BP Global Fuels Technology

    2007-01-01T23:59:59.000Z

    Biocatalysis in Oil Refining focuses on petroleum refining bioprocesses, establishing a connection between science and technology. The micro organisms and biomolecules examined for biocatalytic purposes for oil refining processes are thoroughly detailed. Terminology used by biologists, chemists and engineers is brought into a common language, aiding the understanding of complex biological-chemical-engineering issues. Problems to be addressed by the future R&D activities and by new technologies are described and summarized in the last chapter.

  4. Oil/gas collector/separator for underwater oil leaks

    DOE Patents [OSTI]

    Henning, Carl D. (Livermore, CA)

    1993-01-01T23:59:59.000Z

    An oil/gas collector/separator for recovery of oil leaking, for example, from an offshore or underwater oil well. The separator is floated over the point of the leak and tethered in place so as to receive oil/gas floating, or forced under pressure, toward the water surface from either a broken or leaking oil well casing, line, or sunken ship. The separator is provided with a downwardly extending skirt to contain the oil/gas which floats or is forced upward into a dome wherein the gas is separated from the oil/water, with the gas being flared (burned) at the top of the dome, and the oil is separated from water and pumped to a point of use. Since the density of oil is less than that of water it can be easily separated from any water entering the dome.

  5. Optimising the Use of Spent Oil Shale.

    E-Print Network [OSTI]

    FOSTER, HELEN,JANE

    2014-01-01T23:59:59.000Z

    ??Worldwide deposits of oil shales are thought to represent ~3 trillion barrels of oil. Jordanian oil shale deposits are extensive and high quality, and could… (more)

  6. Oil Prices and Long-Run Risk.

    E-Print Network [OSTI]

    READY, ROBERT

    2011-01-01T23:59:59.000Z

    ??I show that relative levels of aggregate consumption and personal oil consumption provide anexcellent proxy for oil prices, and that high oil prices predict low… (more)

  7. Seismic stimulation for enhanced oil recovery

    E-Print Network [OSTI]

    Pride, S.R.

    2008-01-01T23:59:59.000Z

    aims to enhance oil production by sending seismic wavesbe expected to enhance oil production. INTRODUCTION The hopethe reservoir can cause oil production to increase. Quite

  8. Seismic stimulation for enhanced oil recovery

    E-Print Network [OSTI]

    Pride, S.R.

    2008-01-01T23:59:59.000Z

    that in a declining oil reservoir, seismic waves sent acrosswells. Because oil reservoirs are often at kilometers orproximity to the oil reservoir. Our analysis suggests there

  9. Design Concepts for Co-Production of Power, Fuels & Chemicals Via Coal/Biomass Mixtures

    SciTech Connect (OSTI)

    Rao, A. D.; Chen, Q.; Samuelsen, G. S.

    2012-09-30T23:59:59.000Z

    The overall goal of the program is to develop design concepts, incorporating advanced technologies in areas such as oxygen production, feed systems, gas cleanup, component separations and gas turbines, for integrated and economically viable coal and biomass fed gasification facilities equipped with carbon capture and storage for the following scenarios: (i) coproduction of power along with hydrogen, (ii) coproduction of power along with fuels, (iii) coproduction of power along with petrochemicals, and (iv) coproduction of power along with agricultural chemicals. To achieve this goal, specifically the following objectives are met in this proposed project: (i) identify advanced technology options and innovative preliminary design concepts that synergistically integrate plant subsections, (ii) develop steady state system simulations to predict plant efficiency and environmental signature, (iii) develop plant cost estimates by capacity factoring major subsystems or by major equipment items where required, and then capital, operating and maintenance cost estimates, and (iv) perform techno- economic analyses for the above described coproduction facilities. Thermal efficiencies for the electricity only cases with 90% carbon capture are 38.26% and 36.76% (HHV basis) with the bituminous and the lignite feedstocks respectively. For the coproduction cases (where 50% of the energy exported is in the form of electricity), the electrical efficiency, as expected, is highest for the hydrogen coproduction cases while lowest for the higher alcohols (ethanol) coproduction cases. The electrical efficiencies for Fischer-Tropsch coproduction cases are slightly higher than those for the methanol coproduction cases but it should be noted that the methanol (as well as the higher alcohol) coproduction cases produce the finished coproduct while the Fischer-Tropsch coproduction cases produce a coproduct that requires further processing in a refinery. The cross comparison of the thermal performance between the various coproduct cases is further complicated by the fact that the carbon footprint is not the same when carbon leaving with the coproduct are accounted for. The economic analysis and demand for a particular coproduct in the market place is a more meaningful comparison of the various coproduction scenarios. The first year cost of electricity calculated for the bituminous coal is $102.9/MWh while that for the lignite is $108.1/MWh. The calculated cost of hydrogen ranged from $1.42/kg to $2.77/kg depending on the feedstock, which is lower than the DOE announced hydrogen cost goal of $3.00/kg in July 14, 2005. Methanol cost ranged from $345/MT to $617/MT, while the market price is around $450/MT. For Fischer-Tropsch liquids, the calculated cost ranged from $65/bbl to $112/bbl, which is comparable to the current market price of crude oil at around $100/bbl. It should be noted, however, that F-T liquids contain no sulfur and nitrogen compounds. The calculated cost of alcohol ranged from $4.37/gal to $5.43/gal, while it ranged from $2.20/gal to $3.70/gal in a DOE funded study conducted by Louisiana State University. The Louisiana State University study consisted of a significantly larger plant than our study and benefited from economies of scale. When the plant size in our study is scaled up to similar size as in the Louisiana State University study, cost of alcohol is then reduced to a range of $3.24/gal to $4.28/gal, which is comparable. Urea cost ranged from $307/MT to $428/MT, while the market price is around $480/MT.

  10. Used Oil and Filter Disposal Used Oil: Create a segregated storage area or container. Label the container "Waste Oil Only".

    E-Print Network [OSTI]

    Maroncelli, Mark

    Used Oil and Filter Disposal Used Oil: Create a segregated storage area or container. Label the container "Waste Oil Only". Maintain a written log to document all amounts and types of oil added to the container. No solvents, oil contaminated with solvents, PCBs, non-petroleum based oils, or any other

  11. Fuel-blending stocks from the hydrotreatment of a distillate formed by direct coal liquefaction

    SciTech Connect (OSTI)

    Andile B. Mzinyati [Sasol Technology Research and Development, Sasolburg (South Africa). Fischer-Tropsch Refinery Catalysis

    2007-09-15T23:59:59.000Z

    The direct liquefaction of coal in the iron-catalyzed Suplex process was evaluated as a technology complementary to Fischer-Tropsch synthesis. A distinguishing feature of the Suplex process, from other direct liquefaction processes, is the use of a combination of light- and heavy-oil fractions as the slurrying solvent. This results in a product slate with a small residue fraction, a distillate/naphtha mass ratio of 6, and a 65.8 mass % yield of liquid fuel product on a dry, ash-free coal basis. The densities of the resulting naphtha (C{sub 5}-200{sup o}C) and distillate (200-400{sup o}C) fractions from the hydroprocessing of the straight-run Suplex distillate fraction were high (0.86 and 1.04 kg/L, respectively). The aromaticity of the distillate fraction was found to be typical of coal liquefaction liquids, at 60-65%, with a Ramsbottom carbon residue content of 0.38 mass %. Hydrotreatment of the distillate fraction under severe conditions (200{sup o}C, 20.3 MPa, and 0.41 g{sub feed} h{sup -1} g{sub catalyst}{sup -1}) with a NiMo/Al{sub 2}O{sub 3} catalyst gave a product with a phenol content of {lt}1 ppm, a nitrogen content {lt}200 ppm, and a sulfur content {lt}25 ppm. The temperature was found to be the main factor affecting diesel fraction selectivity when operating at conditions of WHSV = 0.41 g{sub feed} h{sup -1} g{sub catalyst}{sup -1} and PH{sub 2} = 20.3 MPa, with excessively high temperatures (T {gt} 420{sup o}C) leading to a decrease in diesel selectivity. The fuels produced by the hydroprocessing of the straight-run Suplex distillate fraction have properties that make them desirable as blending components, with the diesel fraction having a cetane number of 48 and a density of 0.90 kg/L. The gasoline fraction was found to have a research octane number (RON) of 66 and (N + 2A) value of 100, making it ideal as a feedstock for catalytic reforming and further blending with Fischer-Tropsch liquids. 44 refs., 9 figs., 12 tabs.

  12. Spot-Oiling Johnsongrass.

    E-Print Network [OSTI]

    Elliott, Fred C.; Norris, M. J.; Rea, H. E.

    1955-01-01T23:59:59.000Z

    I TEXAS AGRICULTURAL EXTENSIO-N SERVICE G. G. Gibson, Director, College Station, Texas [Blank Page in Original Bulletin] I the bast I ir used the low I . .. 1 the fol or mort , needed SPOT-OILING JOHNSONGRASS H. E. Rea, M. J. Norris..., and Fred C. Elliott* Texas A. & M. College System ~HNSONGRASS CAN BE killed to the i ground by the application of 1 / 3 teaspoonful of a herbicidal oil to the crown of each stem. Eradication of established Johnsongrass can be obtained in a single...

  13. Oil | Department of Energy

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustion |Energy UsageAUDITVehicles »Exchange VisitorsforDepartment ofNo FearOfficeOil Oil For the

  14. Virent is Replacing Crude Oil

    Broader source: Energy.gov [DOE]

    Breakout Session 2A—Conversion Technologies II: Bio-Oils, Sugar Intermediates, Precursors, Distributed Models, and Refinery Co-Processing Virent is Replacing Crude Oil Randy Cortright, Founder & Chief Technology Officer, Virent

  15. Enhanced Oil Recovery of Viscous Oil by Injection of Water-in-Oil Emulsion Made with Used Engine Oil

    E-Print Network [OSTI]

    Fu, Xuebing

    2012-08-20T23:59:59.000Z

    was proposed for emulsion generation because of several key advantages: more favorable viscosity that results in better emulsion injectivity, soot particles within the oil that readily promote stable emulsions, almost no cost of the oil itself and relatively...

  16. Oil and Gas Program (Tennessee)

    Broader source: Energy.gov [DOE]

    The Oil and Gas section of the Tennessee Code, found in Title 60, covers all regulations, licenses, permits, and laws related to the production of natural gas. The laws create the Oil and Gas...

  17. Oil and Gas Conservation (Montana)

    Broader source: Energy.gov [DOE]

    Parts 1 and 2 of this chapter contain a broad range of regulations pertaining to oil and gas conservation, including requirements for the regulation of oil and gas exploration and extraction by the...

  18. Process for the production of refrigerator oil

    SciTech Connect (OSTI)

    Kunihiro, T.; Tsuchiya, K.

    1985-06-04T23:59:59.000Z

    A process for producing a high quality refrigerator oil from an oil fraction boiling at a temperature within boiling point of lubricating oil by contacting said oil fraction with a solvent to extract undesirable components thereby lowering % C..cap alpha.. of said oil fraction, hydrogenating said solvent extracted fraction under the specific conditions, and then contacting said hydrogenated oil with a solid absorbant to remove impurities; said oil fraction being obtained from a low grade naphthenic crude oil.

  19. Nineteenth oil shale symposium proceedings

    SciTech Connect (OSTI)

    Gary, J.H.

    1986-01-01T23:59:59.000Z

    This book contains 23 selections. Some of the titles are: Effects of maturation on hydrocarbon recoveries from Canadian oil shale deposits; Dust and pressure generated during commercial oil shale mine blasting: Part II; The petrosix project in Brazil - An update; Pathway of some trace elements during fluidized-bed combustion of Israeli Oil Shale; and Decommissioning of the U.S. Department of Energy Anvil Points Oil Shale Research Facility.

  20. Analysis Patterns for Oil Refineries

    E-Print Network [OSTI]

    Lei Zhen; Guangzhen Shao

    We present analysis patterns to describe the structure of oil refineries. The Refinery Produc tion Unit Pattern describes the structure of units and unit groups. The Oil Storage Pattern describes the structure of tanks and tank groups. The Oil Delivery Pattern describes the structure of stations for import and export of oil. The Production Process Pattern describes the productionprocess. The audience for this paper includes analysts, designers, and programmers who are involved in developing Refinery Information Systems.

  1. Oil and Gas Air Heaters

    E-Print Network [OSTI]

    Kou, G.; Wang, H.; Zhou, J.

    2006-01-01T23:59:59.000Z

    , the relation of hot-air temperature, oil or gas consumption and fresh airflow is determined based on energy equilibrium....

  2. Dynamic molecular structure of plant biomass-derived black carbon (biochar)

    E-Print Network [OSTI]

    Keiluweit, M.

    2010-01-01T23:59:59.000Z

    Mechanism study of wood lignin pyrolysis  by using TG?FTIR hemicellulose,  cellulose and lignin pyrolysis.  Fuel 2007, bark,  cellulose,  and  lignin:  Implications for the 

  3. One-step catalytic conversion of biomass-derived carbohydrates to liquid fuels

    DOE Patents [OSTI]

    Sen, Ayusman; Yang, Weiran

    2014-03-18T23:59:59.000Z

    The invention relates to a method for manufacture of hydrocarbon fuels and oxygenated hydrocarbon fuels such as alkyl substituted tetrahydrofurans such as 2,5-dimethyltetrahydrofuran, 2-methyltetrahydrofuran, 5-methylfurfural and mixtures thereof. The method generally entails forming a mixture of reactants that includes carbonaceous material, water, a metal catalyst and an acid reacting that mixture in the presence of hydrogen. The reaction is performed at a temperature and for a time sufficient to produce a furan type hydrocarbon fuel. The process may be adapted to provide continuous manufacture of hydrocarbon fuels such as a furan type fuel.

  4. Hydrogen Generation from Biomass-Derived Carbohydrates via Aqueous-Phase Reforming

    Broader source: Energy.gov [DOE]

    Presentation by Virent Energy Systems, Inc. at the October 24, 2006 Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group Kick-Off Meeting.

  5. Conversion of Biomass-Derived Small Oxygenates over HZSM-5 and its Deactivation Mechanism

    SciTech Connect (OSTI)

    Ramasamy, Karthikeyan K.; Gerber, Mark A.; Flake, Matthew D.; Zhang, He; Wang, Yong

    2014-02-28T23:59:59.000Z

    HZSM-5 catalyst deactivation was studied using aqueous feed mixtures containing ethanol, ethanol+ acetic acid, ethanol+ethyl acetate, or ethanol+acetaldehyde in a fixed bed reactor at 360°C and 300psig. Compared to ethanol alone experiment, addition of other oxygenates reduced catalyst life in the order of: ethyl acetate

  6. The Effects of Trace Contaminants on Catalytic Processing of Biomass-Derived Feedstocks

    SciTech Connect (OSTI)

    Elliott, Douglas C.; Peterson, Keith L.; Muzatko, Danielle S.; Alderson, Eric V.; Hart, Todd R.; Neuenschwander, Gary G.

    2004-03-25T23:59:59.000Z

    Trace components in biomass feedstocks are potential catalyst poisons when catalytically processing these materials to value-added chemical products. Trace components include inorganic elements such as alkali metals and alkaline earths, phosphorus or sulfur, aluminum or silicon, chloride, or transition metals. Protein components in biomass feedstocks can lead to formation of peptide fractions (from hydrolysis) or ammonium ions (from more severe breakdown) both of which might interfere with catalysis. The effects of these components on catalytic hydrogenation processing has been studied in batch reactor processing tests

  7. An efficient didehydroxylation method for the biomass-derived polyols glycerol and erythritol.

    E-Print Network [OSTI]

    2009-01-01T23:59:59.000Z

    unsaturated aldehyde acrolein, usually with low selectivity.dehydration of glycerol to acrolein via a 1,2-hydrogen shiftthe intervention of the expected acrolein intermediate. We

  8. Conversion system overview assessment. Volume III. Solar thermal/coal or biomass derived fuels

    SciTech Connect (OSTI)

    Copeland, R. J.

    1980-02-01T23:59:59.000Z

    The three volumes of this report cover three distinct areas of solar energy research: solar thermoelectrics, solar-wind hybrid systems, and synthetic fuels derived with solar thermal energy. Volume III deals with the conversion of synthetic fuels with solar thermal heat. The method is a hybrid combination of solar energy with either coal or biomass. A preliminary assessment of this technology is made by calculating the cost of fuel produced as a function of the cost of coal and biomass. It is shown that within the projected ranges of coal, biomass, and solar thermal costs, there are conditions when solar synthetic fuels with solar thermal heat will become cost-competitive.

  9. Development of a co-firing fuel from biomass-derived binder and crushed coal.

    E-Print Network [OSTI]

    Friend, Andrew

    2013-01-01T23:59:59.000Z

    ??The focus of this work was the development of a co-firing boiler fuel for use in the coal power plant industry. This fuel, known as… (more)

  10. Catalytic Conversion of Biomass-derived Feedstock (HMF) into Value Added

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation Proposed New Substation Sites ProposedOccupational Health Services|Dimethyl Ether. |Chemicals

  11. Low-Emissions Burner Technology using Biomass-Derived Liquid Fuels |

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarly Career Scientists'Montana.ProgramJulietipDepartmentJuneWhenJulyBadges atEnergyVehicles

  12. Exploring Hydrogen Generation from Biomass-Derived Sugar and Sugar Alcohols

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarly Career Scientists'Montana.Program -DepartmentNovember 1,Energy from abundant,GeothermalAmerica's

  13. OIL ANALYSIS LAB TRIVECTOR ANALYSIS

    E-Print Network [OSTI]

    OIL ANALYSIS LAB TRIVECTOR ANALYSIS This test method is a good routine test for the overall condition of the oil, the cleanliness, and can indicate the presence of wear metals that could be coming of magnetic metal particles within the oil. This may represent metals being worn from components (i

  14. Oil shale: Technology status report

    SciTech Connect (OSTI)

    Not Available

    1986-10-01T23:59:59.000Z

    This report documents the status of the US Department of Energy's (DOE) Oil Shale Program as of the end of FY 86. The report consists of (1) a status of oil shale development, (2) a description of the DOE Oil Shale Program, (3) an FY 86 oil shale research summary, and (4) a summary of FY 86 accomplishments. Discoveries were made in FY 86 about the physical and chemical properties and behavior of oil shales, process chemistry and kinetics, in situ retorting, advanced processes, and the environmental behavior and fate of wastes. The DOE Oil Shale Program shows an increasing emphasis on eastern US oil shales and in the development of advanced oil shale processing concepts. With the award to Foster Wheeler for the design of oil shale conceptual plants, the first step in the development of a systems analysis capability for the complete oil shale process has been taken. Unocal's Parachute Creek project, the only commercial oil shale plant operating in the United States, is operating at about 4000 bbl/day. The shale oil is upgraded at Parachute Creek for input to a conventional refinery. 67 refs., 21 figs., 3 tabs.

  15. Exploiting heavy oil reserves

    E-Print Network [OSTI]

    Levi, Ran

    North Sea investment potential Exploiting heavy oil reserves Beneath the waves in 3D Aberdeen.hamptonassociates.com pRINTED BY nB GroUP Paper sourced from sustainable forests CONTENTS 3/5 does the north Sea still industry partnership drives research into sensor systems 11 Beneath the waves in 3d 12/13 does

  16. African oil plays

    SciTech Connect (OSTI)

    Clifford, A.J. (BHP Petroleum, Melbourne, Victoria (Australia))

    1989-09-01T23:59:59.000Z

    The vast continent of Africa hosts over eight sedimentary basins, covering approximately half its total area. Of these basins, only 82% have entered a mature exploration phase, 9% have had little or no exploration at all. Since oil was first discovered in Africa during the mid-1950s, old play concepts continue to bear fruit, for example in Egypt and Nigeria, while new play concepts promise to become more important, such as in Algeria, Angola, Chad, Egypt, Gabon, and Sudan. The most exciting developments of recent years in African oil exploration are: (1) the Gamba/Dentale play, onshore Gabon; (2) the Pinda play, offshore Angola; (3) the Lucula/Toca play, offshore Cabinda; (4) the Metlaoui play, offshore Libya/Tunisia; (5) the mid-Cretaceous sand play, Chad/Sudan; and (6) the TAG-I/F6 play, onshore Algeria. Examples of these plays are illustrated along with some of the more traditional oil plays. Where are the future oil plays likely to develop No doubt, the Saharan basins of Algeria and Libya will feature strongly, also the presalt of Equatorial West Africa, the Central African Rift System and, more speculatively, offshore Ethiopia and Namibia, and onshore Madagascar, Mozambique, and Tanzania.

  17. World Oil Transit Chokepoints

    Reports and Publications (EIA)

    2012-01-01T23:59:59.000Z

    Chokepoints are narrow channels along widely used global sea routes, some so narrow that restrictions are placed on the size of vessel that can navigate through them. They are a critical part of global energy security due to the high volume of oil traded through their narrow straits.

  18. Naphthenic lube oils

    SciTech Connect (OSTI)

    Hettinger Jr., W. P.; Beck, H. W.; Rozman, G. J.; Turrill, F. H.

    1985-05-07T23:59:59.000Z

    A process is disclosed for increasing the volume of lubricating oil base stocks recovered from a crude oil. A fraction having an atmospheric boiling range of about 675/sup 0/ to 1100/sup 0/ F. is recovered by vacuum distillation. This fraction is treated with furfural to extract a hydrocarbon mixture containing at least 50 volume % aromatic hydrocarbons. The raffinate is a lubricating oil base stock very high in paraffinic hydrocarbons and low in naphthenic hydrocarbons. The fraction extracted by the furfural contains at least about 50 volume % aromatic hydrocarbons and less than about 10 volume % paraffinic hydrocarbons. The mixture is hydrotreated to hydrogenate a substantial portion of the aromatic hydrocarbons. The hydrotreated product then is catalytically dewaxed. After removal of low boiling components, the finished lubricating oil base stock has a viscosity of at least about 200 SUS at 100/sup 0/ F., a pour point of less than 20/sup 0/ F. and contains at least 50 volume % of naphthenic hydrocarbons, a maximum of about 40 volume % aromatic hydrocarbons, and a maximum of about 10 volume % paraffinic hydrocarbons.

  19. Oil and Global Adjustment

    E-Print Network [OSTI]

    Brad Setser

    2007-01-01T23:59:59.000Z

    The current account surplus of the world’s major oil exporting economies – defined as the IMF’s fuel-exporting emerging economies plus Norway – increased from $110b to about $500b between 2002 and 2006. 2 In 2006, the current account surplus of the Gulf

  20. Structural Oil Pan With Integrated Oil Filtration And Cooling System

    DOE Patents [OSTI]

    Freese, V, Charles Edwin (Westland, MI)

    2000-05-09T23:59:59.000Z

    An oil pan for an internal combustion engine includes a body defining a reservoir for collecting engine coolant. The reservoir has a bottom and side walls extending upwardly from the bottom to present a flanged lip through which the oil pan may be mounted to the engine. An oil cooler assembly is housed within the body of the oil pan for cooling lubricant received from the engine. The body includes an oil inlet passage formed integrally therewith for receiving lubricant from the engine and delivering lubricant to the oil cooler. In addition, the body also includes an oil pick up passage formed integrally therewith for providing fluid communication between the reservoir and the engine through the flanged lip.

  1. Oil consumption, pollutant emission, oil proce volatility and economic activities in selected Asian Developing Economies.

    E-Print Network [OSTI]

    Rafiq, Shuddhasattwa

    2009-01-01T23:59:59.000Z

    ??It is now well established in the literature that oil consumption, oil price shocks, and oil price volatility may impact the economic activities negatively. Studies… (more)

  2. Just oil? The distribution of environmental and social impacts of oil production and consumption

    E-Print Network [OSTI]

    O'Rourke, D; Connolly, S

    2003-01-01T23:59:59.000Z

    bution of the impacts of oil production and consumption. Theof harmful effects from oil production and use. A criticaland procedural impacts of oil production and consumption

  3. Unconventional Oil and Gas Resources

    SciTech Connect (OSTI)

    none

    2006-09-15T23:59:59.000Z

    World oil use is projected to grow to 98 million b/d in 2015 and 118 million b/d in 2030. Total world natural gas consumption is projected to rise to 134 Tcf in 2015 and 182 Tcf in 2030. In an era of declining production and increasing demand, economically producing oil and gas from unconventional sources is a key challenge to maintaining global economic growth. Some unconventional hydrocarbon sources are already being developed, including gas shales, tight gas sands, heavy oil, oil sands, and coal bed methane. Roughly 20 years ago, gas production from tight sands, shales, and coals was considered uneconomic. Today, these resources provide 25% of the U.S. gas supply and that number is likely to increase. Venezuela has over 300 billion barrels of unproven extra-heavy oil reserves which would give it the largest reserves of any country in the world. It is currently producing over 550,000 b/d of heavy oil. Unconventional oil is also being produced in Canada from the Athabasca oil sands. 1.6 trillion barrels of oil are locked in the sands of which 175 billion barrels are proven reserves that can be recovered using current technology. Production from 29 companies now operating there exceeds 1 million barrels per day. The report provides an overview of continuous petroleum sources and gives a concise overview of the current status of varying types of unconventional oil and gas resources. Topics covered in the report include: an overview of the history of Oil and Natural Gas; an analysis of the Oil and Natural Gas industries, including current and future production, consumption, and reserves; a detailed description of the different types of unconventional oil and gas resources; an analysis of the key business factors that are driving the increased interest in unconventional resources; an analysis of the barriers that are hindering the development of unconventional resources; profiles of key producing regions; and, profiles of key unconventional oil and gas producers.

  4. Shale oil recovery process

    DOE Patents [OSTI]

    Zerga, Daniel P. (Concord, CA)

    1980-01-01T23:59:59.000Z

    A process of producing within a subterranean oil shale deposit a retort chamber containing permeable fragmented material wherein a series of explosive charges are emplaced in the deposit in a particular configuration comprising an initiating round which functions to produce an upward flexure of the overburden and to initiate fragmentation of the oil shale within the area of the retort chamber to be formed, the initiating round being followed in a predetermined time sequence by retreating lines of emplaced charges developing further fragmentation within the retort zone and continued lateral upward flexure of the overburden. The initiating round is characterized by a plurality of 5-spot patterns and the retreating lines of charges are positioned and fired along zigzag lines generally forming retreating rows of W's. Particular time delays in the firing of successive charges are disclosed.

  5. Oil shale retort apparatus

    DOE Patents [OSTI]

    Reeves, Adam A. (Grand Junction, CO); Mast, Earl L. (Norman, OK); Greaves, Melvin J. (Littleton, CO)

    1990-01-01T23:59:59.000Z

    A retorting apparatus including a vertical kiln and a plurality of tubes for delivering rock to the top of the kiln and removal of processed rock from the bottom of the kiln so that the rock descends through the kiln as a moving bed. Distributors are provided for delivering gas to the kiln to effect heating of the rock and to disturb the rock particles during their descent. The distributors are constructed and disposed to deliver gas uniformly to the kiln and to withstand and overcome adverse conditions resulting from heat and from the descending rock. The rock delivery tubes are geometrically sized, spaced and positioned so as to deliver the shale uniformly into the kiln and form symmetrically disposed generally vertical paths, or "rock chimneys", through the descending shale which offer least resistance to upward flow of gas. When retorting oil shale, a delineated collection chamber near the top of the kiln collects gas and entrained oil mist rising through the kiln.

  6. Oil Price Volatility

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia,(Million Barrels) Crude Oil Reserves in Nonproducing ReservoirsYear-Month WeekReservesYear Jan Feb0

  7. Crude Oil Prices

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia,(Million Barrels) Crude Oil Reserves in Nonproducing Reservoirs (MillionExpectedChangesAdministration Cost and

  8. Emulsified industrial oils recycling

    SciTech Connect (OSTI)

    Gabris, T.

    1982-04-01T23:59:59.000Z

    The industrial lubricant market has been analyzed with emphasis on current and/or developing recycling and re-refining technologies. This task has been performed for the United States and other industrialized countries, specifically France, West Germany, Italy and Japan. Attention has been focused at emulsion-type fluids regardless of the industrial application involved. It was found that emulsion-type fluids in the United States represent a much higher percentage of the total fluids used than in other industrialized countries. While recycling is an active matter explored by the industry, re-refining is rather a result of other issues than the mere fact that oil can be regenerated from a used industrial emulsion. To extend the longevity of an emulsion is a logical step to keep expenses down by using the emulsion as long as possible. There is, however, another important factor influencing this issue: regulations governing the disposal of such fluids. The ecological question, the respect for nature and the natural balances, is often seen now as everybody's task. Regulations forbid dumping used emulsions in the environment without prior treatment of the water phase and separation of the oil phase. This is a costly procedure, so recycling is attractive since it postpones the problem. It is questionable whether re-refining of these emulsions - as a business - could stand on its own if these emulsions did not have to be taken apart for disposal purposes. Once the emulsion is separated into a water and an oil phase, however, re-refining of the oil does become economical.

  9. Using simple models to describe oil production from unconventional reservoirs.

    E-Print Network [OSTI]

    Song, Dong Hee

    2014-01-01T23:59:59.000Z

    ??Shale oil (tight oil) is oil trapped in low permeability shale or sandstone. Shale oil is a resource with great potential as it is heavily… (more)

  10. Life cycle analysis of lubricants from rape seed oil in comparison to conventional lubricants

    E-Print Network [OSTI]

    G. A. Reinhardt; R. Herbener; S. O. Gärtner

    Introduction and procedure Comparing with biomass-derived lubricants, in many cases conventional lubricants turn out to have disadvantages for their environmental impact, especially where losses occur during regular operation (e.g. in chainsaws) or where a leakage leads to immediate emissions into the environment as for agricultural machinery. Bio lubricants are supposed to be environmentally friendly, among other

  11. Unconventional oil market assessment: ex situ oil shale.

    E-Print Network [OSTI]

    Castro-Dominguez, Bernardo

    2010-01-01T23:59:59.000Z

    ??This thesis focused on exploring the economic limitations for the development of western oil shale. The analysis was developed by scaling a known process and… (more)

  12. Assessment of Gasification-Based Biorefining at Kraft Pulp and Paper Mills in the United States, Part A: Background and Assumptions

    SciTech Connect (OSTI)

    Larson, E. D.; Consonni, S.; Katofsky, R. E.; Iisa, K.; Frederick, W. J., Jr.

    2008-11-01T23:59:59.000Z

    Commercialization of black liquor and biomass gasification technologies is anticipated in the 2010-2015 time frame, and synthesis gas from gasifiers can be converted into liquid fuels using catalytic synthesis technologies that are already commercially established in the gas-to-liquids or coal-to-liquids industries. This set of two papers describes key results from a major assessment of the prospective energy, environmental, and financial performance of commercial gasification-based biorefineries integrated with kraft pulp and paper mills [1]. Seven detailed biorefinery designs were developed for a reference mill in the southeastern United States, together with the associated mass/energy balances, air emissions estimates, and capital investment requirements. The biorefineries provide chemical recovery services and co-produce process steam for the mill, some electricity, and one of three liquid fuels: a Fischer-Tropsch synthetic crude oil (which could be refined to vehicle fuels at an existing petroleum refinery), dimethyl ether (a diesel engine fuel or propane substitute), or an ethanol-rich mixed-alcohol product. This paper describes the key assumptions that underlie the biorefinery designs. Part B will present analytical results.

  13. Economical utilization of natural gas to produce synthetic petroleum liquids

    SciTech Connect (OSTI)

    Agee, K.L.; Agee, M.A. [Syntroleum Corp., Tulsa, OK (United States); Willingham, F.Y.; Trepper, E.L. [Bateman Engineering, Inc., Denver, CO (United States)

    1996-12-31T23:59:59.000Z

    A new process for converting pipeline quality or subquality natural gas into liquid fuels and other petroleum products is described. The technology, developed by Syntroleum Corporation, utilizes autothermal reforming with air to produce a nitrogen-diluted synthesis gas having a near ideal ratio for converting into synthetic hydrocarbons via Fischer-Tropsch (F-T) synthesis. A proprietary F-T catalyst system, designed to operate in a nitrogen-diluted atmosphere, achieves conversion rates comparable to conventional F-T processes without the need for recycle and the associated recompression equipment. This results in potential plant capital costs low enough to make conversion of remote and or subquality gas into synthetic fuels economical, based on current oil prices. The process is energy self-sufficient and compact enough to be constructed in 5,000 to 10,000 b/d plants on floating or platform facilities to utilize offshore gas reserves. The liquid fuels produced by the process are free of sulfur and aromatics. The process has been demonstrated at pilot-scale. Numerous engineering studies and cost estimates have been conducted to provide the information needed for economic evaluation and confident scale-up. This paper also outlines improvements to the process currently under development and how the process presents new opportunities for gas processors.

  14. Calorimetric study of adsorption of aliphatic hydrocarbons on reduced cobalt catalyst

    SciTech Connect (OSTI)

    Ostrovskii, V.E.; Medvedkova, E.A.

    1986-06-01T23:59:59.000Z

    A study has been made of the heats of adsorption and the adsorption isotherms of saturated and unsaturated hydrocarbons on Co at 298/sup 0/K; the content of organic matter in the catalyst has been determined after use in the Fischer-Tropsch synthesis. It is concluded that the Fischer-Tropsch process includes stages of diffusion of the original reactants and the products through a liquid film of hydrocarbons coating the catalyst; the hydrocarbon molecules are adsorbed on the surface in the ''lying down'' position; the adsorption of paraffins is reversible and is described by the BET theory; olefins form an irreversibly chemisorbed monolayer, above which reversible adsorption takes place; the ease of desorption of the paraffins explains their preferential formation in the Fischer-Tropsch synthesis.

  15. International Oil Supplies and Demands

    SciTech Connect (OSTI)

    Not Available

    1991-09-01T23:59:59.000Z

    The eleventh Energy Modeling Forum (EMF) working group met four times over the 1989--90 period to compare alternative perspectives on international oil supplies and demands through 2010 and to discuss how alternative supply and demand trends influence the world's dependence upon Middle Eastern oil. Proprietors of eleven economic models of the world oil market used their respective models to simulate a dozen scenarios using standardized assumptions. From its inception, the study was not designed to focus on the short-run impacts of disruptions on oil markets. Nor did the working group attempt to provide a forecast or just a single view of the likely future path for oil prices. The model results guided the group's thinking about many important longer-run market relationships and helped to identify differences of opinion about future oil supplies, demands, and dependence.

  16. International Oil Supplies and Demands

    SciTech Connect (OSTI)

    Not Available

    1992-04-01T23:59:59.000Z

    The eleventh Energy Modeling Forum (EMF) working group met four times over the 1989--1990 period to compare alternative perspectives on international oil supplies and demands through 2010 and to discuss how alternative supply and demand trends influence the world's dependence upon Middle Eastern oil. Proprietors of eleven economic models of the world oil market used their respective models to simulate a dozen scenarios using standardized assumptions. From its inception, the study was not designed to focus on the short-run impacts of disruptions on oil markets. Nor did the working group attempt to provide a forecast or just a single view of the likely future path for oil prices. The model results guided the group's thinking about many important longer-run market relationships and helped to identify differences of opinion about future oil supplies, demands, and dependence.

  17. BP Oil Spill November 10, 2011

    E-Print Network [OSTI]

    Lega, Joceline

    BP Oil Spill Qiyam Tung November 10, 2011 1 Introduction Figure 1: BP Oil spill (source: http://thefoxisblack.com/2010/05/02/the-bp-oil-spill-in-the-gulf-of-mexico/) Last year, there was a major oil spill caused major techniques to minimize the threat once it happened. What kind of damage would an oil spill like this cause

  18. The twentieth oil shale symposium proceedings

    SciTech Connect (OSTI)

    Gary, J.H.

    1987-01-01T23:59:59.000Z

    This book contains 20 selections. Some of the titles are: The technical contributions of John Ward Smith in oil shale research; Oil shale rubble fires: ignition and extinguishment; Fragmentation of eastern oil shale for in situ recovery; A study of thermal properties of Chinese oil shale; and Natural invasion of native plants on retorted oil shale.

  19. Carbo-metallic oil conversion

    SciTech Connect (OSTI)

    Myers, G.D.

    1987-11-24T23:59:59.000Z

    This patent describes a method for catalytically cracking reduced crude oil feeds comprising Conradson carbon in the presence of a premised catalyst temperature of about 760/sup 0/C (1400/sup 0/F). The cracking is carried out to form hydrocarbon products comprising gasoline, which method comprises maintaining the functions of oil feed, Conradson carbon, hydrogen in deposited carbonaceous material, and water addition to the oil feed to be converted in accordance with the relationship of operating parameters for a catalyst to oil ratio in the range of about 4.5 to 7.5.

  20. Maps of crude oil futures

    SciTech Connect (OSTI)

    Masters, C.D.

    1986-05-01T23:59:59.000Z

    The Crude Oil Futures presentation shows their concept of the quantity of oil possibly present (the combination of conventional demonstrated reserves plus undiscovered recoverable resources) within the areas outlined. The Crude Oil Futures is not as an exploration map but as a perspective on the distribution of world oil. The occurrence of oil is, after all, a function of particular geologic factors that are not everywhere present. Furthermore, large amounts of oil can occur only where the several necessary independent variables (geologic factors) combine optimally. In the Western Hemisphere, similar minimal crude oil futures are shown for North America and South America. This similarity is a reflection not of similar geology but rather of the fact that most of the oil has already been produced from North America, whereas South America as a whole (except for Venezuela) possesses a geology less likely to produce oil. In Europe, Africa, and Asia, four regions are dominant: the Middle East, Libya, North Sea, and west Siberia. Paleogeography and source rock distribution were keys to this distribution - the Middle East and Libya reflecting the Tethyan association, and the North Sea and west Siberia benefitting from the Late Jurassic marine transgression into geographic environments where ocean circulation was restricted by tectonic events.

  1. Oil and macroeconomy in China.

    E-Print Network [OSTI]

    Hu, Lin

    2008-01-01T23:59:59.000Z

    ??This paper uses two different approaches to investigate the relationship between the oil price shock and the macroeconomy in China. The first approach is the… (more)

  2. Oil and Gas Exploration (Connecticut)

    Broader source: Energy.gov [DOE]

    These regulations apply to activities conducted for the purpose of obtaining geological, geophysical, or geochemical information about oil or gas including seismic activities but excluding...

  3. Solar retorting of oil shale

    DOE Patents [OSTI]

    Gregg, David W. (Morago, CA)

    1983-01-01T23:59:59.000Z

    An apparatus and method for retorting oil shale using solar radiation. Oil shale is introduced into a first retorting chamber having a solar focus zone. There the oil shale is exposed to solar radiation and rapidly brought to a predetermined retorting temperature. Once the shale has reached this temperature, it is removed from the solar focus zone and transferred to a second retorting chamber where it is heated. In a second chamber, the oil shale is maintained at the retorting temperature, without direct exposure to solar radiation, until the retorting is complete.

  4. Oil cooled, hermetic refrigerant compressor

    DOE Patents [OSTI]

    English, William A. (Murrysville, PA); Young, Robert R. (Murrysville, PA)

    1985-01-01T23:59:59.000Z

    A hermetic refrigerant compressor having an electric motor and compressor assembly in a hermetic shell is cooled by oil which is first cooled in an external cooler 18 and is then delivered through the shell to the top of the motor rotor 24 where most of it is flung radially outwardly within the confined space provided by the cap 50 which channels the flow of most of the oil around the top of the stator 26 and then out to a multiplicity of holes 52 to flow down to the sump and provide further cooling of the motor and compressor. Part of the oil descends internally of the motor to the annular chamber 58 to provide oil cooling of the lower part of the motor, with this oil exiting through vent hole 62 also to the sump. Suction gas with entrained oil and liquid refrigerant therein is delivered to an oil separator 68 from which the suction gas passes by a confined path in pipe 66 to the suction plenum 64 and the separated oil drops from the separator to the sump. By providing the oil cooling of the parts, the suction gas is not used for cooling purposes and accordingly increase in superheat is substantially avoided in the passage of the suction gas through the shell to the suction plenum 64.

  5. Oil cooled, hermetic refrigerant compressor

    DOE Patents [OSTI]

    English, W.A.; Young, R.R.

    1985-05-14T23:59:59.000Z

    A hermetic refrigerant compressor having an electric motor and compressor assembly in a hermetic shell is cooled by oil which is first cooled in an external cooler and is then delivered through the shell to the top of the motor rotor where most of it is flung radially outwardly within the confined space provided by the cap which channels the flow of most of the oil around the top of the stator and then out to a multiplicity of holes to flow down to the sump and provide further cooling of the motor and compressor. Part of the oil descends internally of the motor to the annular chamber to provide oil cooling of the lower part of the motor, with this oil exiting through vent hole also to the sump. Suction gas with entrained oil and liquid refrigerant therein is delivered to an oil separator from which the suction gas passes by a confined path in pipe to the suction plenum and the separated oil drops from the separator to the sump. By providing the oil cooling of the parts, the suction gas is not used for cooling purposes and accordingly increase in superheat is substantially avoided in the passage of the suction gas through the shell to the suction plenum. 3 figs.

  6. European Market Study for BioOil (Pyrolysis Oil)

    E-Print Network [OSTI]

    European Market Study for BioOil (Pyrolysis Oil) Dec 15, 2006 Doug Bradley President Climate Change Solutions National Team Leader- IEA Bioenergy Task 40- Bio-trade 402 Third Avenue ·Ottawa, Ontario ·Canada K. Market Determining Factors 5. EU Country Perspectives 6. Potential European Markets 6.1. Pulp Mill Lime

  7. Oil burner nozzle

    DOE Patents [OSTI]

    Wright, Donald G. (Rockville Center, NY)

    1982-01-01T23:59:59.000Z

    An oil burner nozzle for use with liquid fuels and solid-containing liquid fuels. The nozzle comprises a fuel-carrying pipe, a barrel concentrically disposed about the pipe, and an outer sleeve retaining member for the barrel. An atomizing vapor passes along an axial passageway in the barrel, through a bore in the barrel and then along the outer surface of the front portion of the barrel. The atomizing vapor is directed by the outer sleeve across the path of the fuel as it emerges from the barrel. The fuel is atomized and may then be ignited.

  8. Residential heating oil price

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLas ConchasPassive Solar HomePromisingStories »Submitter A B CAdministrationheating oil price

  9. Residential heating oil price

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLas ConchasPassive Solar HomePromisingStories »Submitter A B CAdministrationheating oil

  10. fuel_oil.pdf

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"Click worksheet9,1,50022,3,,,,6,1,,781Title: Telephone:short version)ec 1827 TableB (11-19-10)Fuel Oil

  11. Crude Oil Domestic Production

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"Click worksheet9,1,50022,3,,,,6,1,,781Title: Telephone:shortOilCompanyexcluding taxes)Countries0 0 0 0

  12. Crude Oil Production

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"Click worksheet9,1,50022,3,,,,6,1,,781Title: Telephone:shortOilCompanyexcluding taxes)Countries08,909

  13. Residual Fuel Oil

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia,(Million Barrels) Crude Oil Reserves in NonproducingAdditions to Capacity on CokersA2. ForJanuary 2013 (Thousand

  14. Oil resources: the key to prosperity or to poverty? : Influence of oil price shocks on spending of oil revenues.

    E-Print Network [OSTI]

    Selivanova, Olga

    2008-01-01T23:59:59.000Z

    ??Abundant natural resources, in particular oil, play an important role in the economics of many countries. The oil price shocks that have been happening continuously… (more)

  15. WASTEWATER TREATMENT IN THE OIL SHALE INDUSTRY

    E-Print Network [OSTI]

    Fox, J.P.

    2010-01-01T23:59:59.000Z

    III, "Method of Breaking Shale Oil-Water Emulsion," U. S.and Biological Treatment of Shale Oil Retort Water, DraftPA (1979). H. H. Peters, Shale Oil Waste Water Recovery by

  16. CORROSION OF METALS IN OIL SHALE ENVIRONMENTS

    E-Print Network [OSTI]

    Bellman Jr., R.

    2012-01-01T23:59:59.000Z

    temperature, type of shale and oil content of shale iscontent of the shale, and shale oil content of the rock cantemperatures. Lean and Rich Shale Oil shales vary in their

  17. Membrane degumming of crude vegetable oil

    E-Print Network [OSTI]

    Lin, Lan

    1997-01-01T23:59:59.000Z

    Crude vegetable oils contain various minor substances like phospholipids, coloring pigments, and free fatty acids (FFA) that may affect quality of the oil. Reduction of energy costs and waste disposal are major concerns for many oil refiners who...

  18. CORROSION OF METALS IN OIL SHALE ENVIRONMENTS

    E-Print Network [OSTI]

    Bellman Jr., R.

    2012-01-01T23:59:59.000Z

    CORROSION OF METALS IN OIL SHALE ENVIRONMENTS A. Levy and R.of Metals in In-Situ Oil Shale Retorts," NACE Corrosion 80,Corrosion of Oil Shale Retort Component Materials," LBL-

  19. WASTEWATER TREATMENT IN THE OIL SHALE INDUSTRY

    E-Print Network [OSTI]

    Fox, J.P.

    2010-01-01T23:59:59.000Z

    III, "Method of Breaking Shale Oil-Water Emulsion," U. S.Waters from Green River Oil Shale," Chem. and Ind. , 1. ,Effluents from In-Situ oil Shale Processing," in Proceedings

  20. CORROSION OF METALS IN OIL SHALE ENVIRONMENTS

    E-Print Network [OSTI]

    Bellman Jr., R.

    2012-01-01T23:59:59.000Z

    Elevated Temperature Corrosion of Oil Shale Retort Componentin In-Situ Oil Shale Retorts," NACE Corrosion 80, Paper No.6-10, 1981 CORROSION OF METALS IN OIL SHALE ENVIRONMENTS A.

  1. WASTEWATER TREATMENT IN THE OIL SHALE INDUSTRY

    E-Print Network [OSTI]

    Fox, J.P.

    2010-01-01T23:59:59.000Z

    is in intimate contact with oil and shale during In in-situin contact with the oil and shale. These methods and othersWaters from Green River Oil Shale," Chem. and Ind. , 1. ,

  2. WASTEWATER TREATMENT IN THE OIL SHALE INDUSTRY

    E-Print Network [OSTI]

    Fox, J.P.

    2010-01-01T23:59:59.000Z

    Waters from Green River Oil Shale," Chem. and Ind. , 1. ,Effluents from In-Situ oil Shale Processing," in Proceedingsin the Treatment of Oil Shale Retort Waters," in Proceedings

  3. CORROSION OF METALS IN OIL SHALE ENVIRONMENTS

    E-Print Network [OSTI]

    Bellman Jr., R.

    2012-01-01T23:59:59.000Z

    CORROSION OF METALS IN OIL SHALE ENVIRONMENTS A. Levy and R.of Metals in In-Situ Oil Shale Retorts," NACE Corrosion 80,Elevated Temperature Corrosion of Oil Shale Retort Component

  4. Crude oil and crude oil derivatives transactions by oil and gas producers.

    E-Print Network [OSTI]

    Xu, He

    2007-01-01T23:59:59.000Z

    ??This study attempts to resolve two important issues. First, it investigates the diversification benefit of crude oil for equities. Second, it examines whether or not… (more)

  5. www.fightbac.o anola oil is

    E-Print Network [OSTI]

    Ca co Th Ca "Canola" c which is Addition Ca he Ca in Th ca Ca m C know? anola oil is ooking oils. he average anola oil is comes fro s another nal Inform anola oil is eart healthy anola oil is n the world. he part of th anola meal anola oil ca many crop va ano the lowest . canola see a good sou m

  6. Fuel Cell Distributed Power Package Unit: Fuel Processing Based On

    E-Print Network [OSTI]

    Gas or Biogas or Biomass derived Pyrolysis oil In-situ heat generation on catalyst lowers capital cost is burnt off during regenerationDiesel, NG, Propane, Biogas, Biomass Pyrolysis Oil Fuel Flexibility ·In

  7. Process oil manufacturing process

    SciTech Connect (OSTI)

    Corman, B.G.; Korbach, P.F.; Webber, K.M.

    1989-01-31T23:59:59.000Z

    A method is described for producing a naphthenic process oil having reduced sulfur, nitrogen and polynuclear aromatics contents from a naphthenic feed containing same and having an atmospheric boiling range of about 650/sup 0/ to about 1200/sup 0/F. comprising: A. passing the feed into a first hydrotreating stage having a hydrotreating catalyst therein, the stage maintained at a temperature of about 600/sup 0/ to about 750/sup 0/F. and at a hydrogen partial pressure of about 400 to about 1500 psig, to convert at least a portion of the sulfur to hydrogen sulfide and the nitrogen to ammonia; B. passing the hydrotreated feed from the first hydrotreating stage in an intermediate stripping stage wherein hydrogen sulfide, ammonia, or both is removed; C. passing the hydrotreated feed from the intermediate stage into a second hydrotreating stage having therein a hydrotreating catalyst selected from the group consisting of nickel-molybdenum, cobalt-molybdenum, nickel-tungsten and mixtures thereof, the second hydrotreating stage maintained at a temperature lower than that of the first hydrotreating stage and at a hydrogen partial pressure ranging between about 400 and about 1,500 psig; D. monitoring the polynuclear aromatics content, the degree of saturation, or both of the product exiting the second hydrotreating stage; and, E. adjusting the temperature in the second hydrotreating stage to keep the polynuclear aromatics content, the degree of saturation, or both below a limit suitable for process oil.

  8. Oil market in international and Norwegian perspectives.

    E-Print Network [OSTI]

    Singsaas, Julia Nazyrova

    2009-01-01T23:59:59.000Z

    ??Crude oil is the most important energy source in global perspective. About 35 percent of the world’s primary energy consumption is supplied by oil, followed… (more)

  9. Optimize carbon dioxide sequestration, enhance oil recovery

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Optimize carbon dioxide sequestration, enhance oil recovery Optimize carbon dioxide sequestration, enhance oil recovery The simulation provides an important approach to estimate...

  10. Optimize carbon dioxide sequestration, enhance oil recovery

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Optimize carbon dioxide sequestration, enhance oil recovery The simulation provides an important approach to estimate the potential of storing carbon dioxide in depleted oil fields...

  11. Method of inducing surface ensembles on a metal catalyst

    DOE Patents [OSTI]

    Miller, Steven S. (Morgantown, WV)

    1989-01-01T23:59:59.000Z

    A method of inducing surface ensembles on a transition metal catalyst used in the conversion of a reactant gas or gas mixture, such as carbon monoxide and hydrogen into hydrocarbons (the Fischer-Tropsch reaction) is disclosed which comprises adding a Lewis base to the syngas (CO+H.sub.2) mixture before reaction takes place. The formation of surface ensembles in this manner restricts the number and types of reaction pathways which will be utilized, thus greatly narrowing the product distribution and maximizing the efficiency of the Fischer-Tropsch reaction. Similarly, amines may also be produced by the conversion of reactant gas or gases, such as nitrogen, hydrogen, or hydrocarbon constituents.

  12. Method of inducing surface ensembles on a metal catalyst

    DOE Patents [OSTI]

    Miller, S.S.

    1987-10-02T23:59:59.000Z

    A method of inducing surface ensembles on a transition metal catalyst used in the conversion of a reactant gas or gas mixture, such as carbon monoxide and hydrogen into hydrocarbons (the Fischer-Tropsch reaction) is disclosed which comprises adding a Lewis base to the syngas (CO + H/sub 2/) mixture before reaction takes place. The formation of surface ensembles in this manner restricts the number and types of reaction pathways which will be utilized, thus greatly narrowing the product distribution and maximizing the efficiency of the Fischer-Tropsch reaction. Similarly, amines may also be produced by the conversion of reactant gas or gases, such as nitrogen, hydrogen, or hydrocarbon constituents.

  13. Process for oil shale retorting

    DOE Patents [OSTI]

    Jones, John B. (300 Enterprise Bldg., Grand Junction, CO 80501); Kunchal, S. Kumar (300 Enterprise Bldg., Grand Junction, CO 80501)

    1981-10-27T23:59:59.000Z

    Particulate oil shale is subjected to a pyrolysis with a hot, non-oxygenous gas in a pyrolysis vessel, with the products of the pyrolysis of the shale contained kerogen being withdrawn as an entrained mist of shale oil droplets in a gas for a separation of the liquid from the gas. Hot retorted shale withdrawn from the pyrolysis vessel is treated in a separate container with an oxygenous gas so as to provide combustion of residual carbon retained on the shale, producing a high temperature gas for the production of some steam and for heating the non-oxygenous gas used in the oil shale retorting process in the first vessel. The net energy recovery includes essentially complete recovery of the organic hydrocarbon material in the oil shale as a liquid shale oil, a high BTU gas, and high temperature steam.

  14. e n e r g y Unconventional Oil Production

    E-Print Network [OSTI]

    Stuck In A Rock; A Hard Place; M. Engemann; Michael T. Owyang

    Highly variable oil prices and increasing world demand for oil have led producers to look for alternative sources of transportation fuel. Two popular alternatives are oil sands (aka tar sands) and oil shale. However, obtaining usable oil from oil sands or oil shale is more capital-intensive and more expensive than obtaining oil from conventional reserves. At what price of oil do these alternatives become cost-effective? Oil Sands Oil sands are a mixture of sand, water, clay and heavy, viscous oil called bitumen. The largest known deposits of oil sands are in Alberta, Canada, and the Orinoco Oil

  15. The Politics of Mexico’s Oil Monopoly

    E-Print Network [OSTI]

    Huizar, Richard

    2008-01-01T23:59:59.000Z

    2005), p. 59. Table 5: Oil production in barrels per daynot have much impact in oil production. In fact, oil exportscurrent oil reserves and oil production? 2) For how long can

  16. Separation of oil-soluble sulfonates from sulfonated oils

    SciTech Connect (OSTI)

    Ul'yanenko, V.I.; Yur'eva, N.P.; Sergeev, V.P.

    1987-01-01T23:59:59.000Z

    The authors aimed at developing a method for the complete recovery, from oil solutions, of oil-water-soluble sulfonates meeting the specifications, along with oils at least 99% pure, suitable for further processing. As the starting material the authors used an experimental batch of sulfonated and neutralized distillate lube stocks produced by selective solvent treatment. In determining the optimal extraction parameters, the authors investigated the influence of the solvent to original feed (S:F) weight ratio and the influence of the isopropyl alcohol (IPA) concentration on the composition of the sulfonates and oils recovered at 60/sup 0/C with a settling time of 2 h. The optimal conditions for two-stage extraction were found through a study of the influence of temperature and settling time on the compositions of the sulfonates and oils with S:F = 1.2:1 and with an IPA concentration of 40%. The process technology for two-stage recovery of oils and sulfonates from oil solutions was worked out in a pilot unit.

  17. RESEARCH OIL RECOVERY MECHANISMS IN HEAVY OIL RESERVOIRS

    SciTech Connect (OSTI)

    Anthony R. Kovscek; William E. Brigham

    1999-06-01T23:59:59.000Z

    The United States continues to rely heavily on petroleum fossil fuels as a primary energy source, while domestic reserves dwindle. However, so-called heavy oil (10 to 20{sup o}API) remains an underutilized resource of tremendous potential. Heavy oils are much more viscous than conventional oils. As a result, they are difficult to produce with conventional recovery methods such as pressure depletion and water injection. Thermal recovery is especially important for this class of reservoirs because adding heat, usually via steam injection, generally reduces oil viscosity dramatically. This improves displacement efficiency. The research described here was directed toward improved understanding of thermal and heavy-oil production mechanisms and is categorized into: (1) flow and rock properties; (2) in-situ combustion; (3) additives to improve mobility control; (4) reservoir definition; and (5) support services. The scope of activities extended over a three-year period. Significant work was accomplished in the area of flow properties of steam, water, and oil in consolidated and unconsolidated porous media, transport in fractured porous media, foam generation and flow in homogeneous and heterogeneous porous media, the effects of displacement pattern geometry and mobility ratio on oil recovery, and analytical representation of water influx. Significant results are described.

  18. Research on oil recovery mechanisms in heavy oil reservoirs

    SciTech Connect (OSTI)

    Kovscek, Anthony R.; Brigham, William E., Castanier, Louis M.

    2000-03-16T23:59:59.000Z

    The research described here was directed toward improved understanding of thermal and heavy-oil production mechanisms and is categorized into: (1) flow and rock properties, (2) in-situ combustion, (3) additives to improve mobility control, (4) reservoir definition, and (5) support services. The scope of activities extended over a three-year period. Significant work was accomplished in the area of flow properties of steam, water, and oil in consolidated and unconsolidated porous media, transport in fractured porous media, foam generation and flow in homogeneous and heterogeneous porous media, the effects of displacement pattern geometry and mobility ratio on oil recovery, and analytical representation of water influx.

  19. No Oil: The coming Utopia/Dystopia and Communal Possibilities

    E-Print Network [OSTI]

    Miller, Timothy

    2006-03-01T23:59:59.000Z

    supplies of conventional oil, and exploitable supplies of alternative forms of oil and related hydrocarbons, including tar sands and oil shale. Because new supplies of conventional oil are declining steadily, there is quite a lot of activity in the oil... to exploit the huge deposits of oil sands in Canada. Oil sands and oil shale look good because they contain vast amounts of oil. The problem is that of turning the reserves, locked into other geological formations, into useful oil. According to current...

  20. Water issues associated with heavy oil production.

    SciTech Connect (OSTI)

    Veil, J. A.; Quinn, J. J.; Environmental Science Division

    2008-11-28T23:59:59.000Z

    Crude oil occurs in many different forms throughout the world. An important characteristic of crude oil that affects the ease with which it can be produced is its density and viscosity. Lighter crude oil typically can be produced more easily and at lower cost than heavier crude oil. Historically, much of the nation's oil supply came from domestic or international light or medium crude oil sources. California's extensive heavy oil production for more than a century is a notable exception. Oil and gas companies are actively looking toward heavier crude oil sources to help meet demands and to take advantage of large heavy oil reserves located in North and South America. Heavy oil includes very viscous oil resources like those found in some fields in California and Venezuela, oil shale, and tar sands (called oil sands in Canada). These are described in more detail in the next chapter. Water is integrally associated with conventional oil production. Produced water is the largest byproduct associated with oil production. The cost of managing large volumes of produced water is an important component of the overall cost of producing oil. Most mature oil fields rely on injected water to maintain formation pressure during production. The processes involved with heavy oil production often require external water supplies for steam generation, washing, and other steps. While some heavy oil processes generate produced water, others generate different types of industrial wastewater. Management and disposition of the wastewater presents challenges and costs for the operators. This report describes water requirements relating to heavy oil production and potential sources for that water. The report also describes how water is used and the resulting water quality impacts associated with heavy oil production.

  1. Enhanced oil recovery system

    DOE Patents [OSTI]

    Goldsberry, Fred L. (Spring, TX)

    1989-01-01T23:59:59.000Z

    All energy resources available from a geopressured geothermal reservoir are used for the production of pipeline quality gas using a high pressure separator/heat exchanger and a membrane separator, and recovering waste gas from both the membrane separator and a low pressure separator in tandem with the high pressure separator for use in enhanced oil recovery, or in powering a gas engine and turbine set. Liquid hydrocarbons are skimmed off the top of geothermal brine in the low pressure separator. High pressure brine from the geothermal well is used to drive a turbine/generator set before recovering waste gas in the first separator. Another turbine/generator set is provided in a supercritical binary power plant that uses propane as a working fluid in a closed cycle, and uses exhaust heat from the combustion engine and geothermal energy of the brine in the separator/heat exchanger to heat the propane.

  2. Oil field management system

    DOE Patents [OSTI]

    Fincke, James R.

    2003-09-23T23:59:59.000Z

    Oil field management systems and methods for managing operation of one or more wells producing a high void fraction multiphase flow. The system includes a differential pressure flow meter which samples pressure readings at various points of interest throughout the system and uses pressure differentials derived from the pressure readings to determine gas and liquid phase mass flow rates of the high void fraction multiphase flow. One or both of the gas and liquid phase mass flow rates are then compared with predetermined criteria. In the event such mass flow rates satisfy the predetermined criteria, a well control system implements a correlating adjustment action respecting the multiphase flow. In this way, various parameters regarding the high void fraction multiphase flow are used as control inputs to the well control system and thus facilitate management of well operations.

  3. International Oil and Gas Board International Oil and Gas Board...

    Open Energy Info (EERE)

    Oil and Gas Board Address Place Zip Website Abu Dhabi Supreme Petroleum Council Abu Dhabi Supreme Petroleum Council Abu Dhabi http www abudhabi ae egovPoolPortal WAR appmanager...

  4. Combustion heater for oil shale

    DOE Patents [OSTI]

    Mallon, R.; Walton, O.; Lewis, A.E.; Braun, R.

    1983-09-21T23:59:59.000Z

    A combustion heater for oil shale heats particles of spent oil shale containing unburned char by burning the char. A delayed fall is produced by flowing the shale particles down through a stack of downwardly sloped overlapping baffles alternately extending from opposite sides of a vertical column. The delayed fall and flow reversal occurring in passing from each baffle to the next increase the residence time and increase the contact of the oil shale particles with combustion supporting gas flowed across the column to heat the shale to about 650 to 700/sup 0/C for use as a process heat source.

  5. Combustion heater for oil shale

    DOE Patents [OSTI]

    Mallon, Richard G. (Livermore, CA); Walton, Otis R. (Livermore, CA); Lewis, Arthur E. (Los Altos, CA); Braun, Robert L. (Livermore, CA)

    1985-01-01T23:59:59.000Z

    A combustion heater for oil shale heats particles of spent oil shale containing unburned char by burning the char. A delayed fall is produced by flowing the shale particles down through a stack of downwardly sloped overlapping baffles alternately extending from opposite sides of a vertical column. The delayed fall and flow reversal occurring in passing from each baffle to the next increase the residence time and increase the contact of the oil shale particles with combustion supporting gas flowed across the column to heat the shale to about 650.degree.-700.degree. C. for use as a process heat source.

  6. OIL & GAS HISTORY 1 History in California

    E-Print Network [OSTI]

    OIL & GAS HISTORY 1 History in California 4 Superior figures refer to references at the end of the essay. OIL AND GAS PRODUCTION California oil was always a valued commodity. When the Spanish explorers landed in California in the 1500s, they found Indians gathering asphaltum (very thick oil) from natural

  7. THE RIMINI PROTOCOL Oil Depletion Protocol

    E-Print Network [OSTI]

    Keeling, Stephen L.

    Soaring oil prices have drawn attention to the issue of the relative supply and demand for crude oil1 THE RIMINI PROTOCOL an Oil Depletion Protocol ~ Heading Off Economic Chaos and Political Conflict During the Second Half of the Age of Oil As proposed at the 2003 Pio Manzu Conference

  8. EMPLOYEE BENEFIT SERVICE Signature Service Oil Change

    E-Print Network [OSTI]

    New Mexico, University of

    UNM Staff EMPLOYEE BENEFIT SERVICE Jiffy Lube Signature Service Oil Change Fast - No Appointment We change your oil with up to 5 quarts of major brand motor oil We install a new oil fi We visually inspect. ASE training programs · Jiffy Lube uses top quality products that meet or exceed vehicle warranty

  9. Canadian Oil Sands: Canada's Energy Advantage

    E-Print Network [OSTI]

    Boisvert, Jeff

    crude oil production, global energy demand, the estimated reserves and resources at Syncrude, views that the world will need oil for decades to come, the expectations regarding oil sands productive capacityCanadian Oil Sands: Canada's Energy Advantage 0 #12;Forward looking information 1 In the interest

  10. Estimates of Oil Reserves Jean Laherrere

    E-Print Network [OSTI]

    O'Donnell, Tom

    Estimates of Oil Reserves Jean Laherrere e-mail: jean.laherrere@wanadoo.fr sites: http will solve the present problems on welfare, retirement and they would dearly love to see the reserves of oil or oil reserves is a political act. The SEC, to satisfy bankers and shareholders, obliges the oil

  11. Cheaper oil extraction Taking a closer look

    E-Print Network [OSTI]

    solvent for commercial-scale enhanced oil recovery to increase the amount of crude oil that canCONTENTS Cheaper oil extraction Taking a closer look at the eye Computational Science takes inside for more details #12;Greener, cheaper oil extraction Geographical and geological concerns

  12. Liens for Oil and Gas Operations (Nebraska)

    Broader source: Energy.gov [DOE]

    This section contains regulations concerning lien allowances made to operators of oil and gas operations.

  13. Favorable conditions noted for Australia shale oil

    SciTech Connect (OSTI)

    Not Available

    1986-09-01T23:59:59.000Z

    After brief descriptions of the Rundle, Condor, and Stuart/Kerosene Creek oil shale projects in Queensland, the competitive advantages of oil shale development and the state and federal governments' attitudes towards an oil shale industry in Australia are discussed. It is concluded that Australia is the ideal country in which to start an oil shale industry.

  14. Bureau of Land Management Oil Shale Development

    E-Print Network [OSTI]

    Utah, University of

    Bureau of Land Management Oil Shale Development Unconventional Fuels Conference University of Utah May 17, 2011 #12;#12;Domestic Oil Shale Resources Primary oil shale resources in the U.S. are in the Green River Formation in Wyoming, Utah, and Colorado. 72 % of this oil shale resource is on Federal

  15. Fire and explosion hazards of oil shale

    SciTech Connect (OSTI)

    Not Available

    1989-01-01T23:59:59.000Z

    The US Bureau of Mines publication presents the results of investigations into the fire and explosion hazards of oil shale rocks and dust. Three areas have been examined: the explosibility and ignitability of oil shale dust clouds, the fire hazards of oil shale dust layers on hot surfaces, and the ignitability and extinguishment of oil shale rubble piles. 10 refs., 54 figs., 29 tabs.

  16. 1 What is Oil ? General information

    E-Print Network [OSTI]

    Kammen, Daniel M.

    such as shale oil or synthetic crude oil from tar sands (see Table 4.1). A whole range of petroleum products69 1 What is Oil ? General information Petroleum is a complex mixture of liquid hydrocarbons in sedimentary rock. Coming from the Latin petra, meaning rock, and oleum, meaning oil, the word "petroleum

  17. Research on Oil Recovery Mechanisms in Heavy Oil Reservoirs

    SciTech Connect (OSTI)

    Louis M. Castanier; William E. Brigham

    1998-03-31T23:59:59.000Z

    The goal of this project is to increase recovery of heavy oils. Towards that goal studies are being conducted in how to assess the influence of temperature and pressure on the absolute and relative permeability to oil and water and on capillary pressure; to evaluate the effect of different reservoir parameters on the in site combustion process; to develop and understand mechanisms of surfactants on for the reduction of gravity override and channeling of steam; and to improve techniques of formation evaluation.

  18. Plant-wide Control for Better De-oiling of Produced Water in Offshore Oil & Gas

    E-Print Network [OSTI]

    Yang, Zhenyu

    Plant-wide Control for Better De-oiling of Produced Water in Offshore Oil & Gas Production Zhenyu (PWT) in offshore oil & gas production processes. Different from most existing facility- or material offshore and the oil industry expects this share to grow continuously in the future. In last decade, oil

  19. Oil and Gas CDT Development of a SUNTANS Baroclinic Model for 3D Oil

    E-Print Network [OSTI]

    Henderson, Gideon

    Oil and Gas CDT Development of a SUNTANS Baroclinic Model for 3D Oil Pollution Tracking Heriot) Key Words Oil Spill, HF Radar, Trajectory Forecasting, Hydrodynamic Modelling, Oil Chemistry Overview In an oil spill emergency, an operational system must forecast ocean and weather conditions in addition

  20. 2 SPRAY OILS--BEYOND 2000 Modern use of petroleum-derived oils as agricultural crop

    E-Print Network [OSTI]

    Agnello, Arthur M.

    2 SPRAY OILS--BEYOND 2000 Abstract Modern use of petroleum-derived oils as agricultural crop among oils of common origin and manufacture. The importance of the emulsifier used with the oil of these products. Introduction Petroleum oils have been in use as crop protectants for over a hundred years

  1. OilEd: a Reason-able Ontology Editor for the Semantic Web

    E-Print Network [OSTI]

    Stevens, Robert

    the full power of an expressive web ontology language (OIL). OilEd uses reasoning to support ontology been merged under the name DAML+OIL, although there are some differences between the approaches usedOilEd: a Reason-able Ontology Editor for the Semantic Web Sean Bechhofer, Ian Horrocks, Carole

  2. OIL IN THE OPEN WATER Oil in the open water may a ect the health of

    E-Print Network [OSTI]

    OIL IN THE OPEN WATER Oil in the open water may a ect the health of microscopic plants and animals. Far beneath the surface, corals and other deepwater communities might also be a ected. OIL AND HUMAN AND SEDIMENTS · Water quality surveys · Transect surveys to detect submerged oil · Oil plume modeling · Sediment

  3. Energy Policy 34 (2006) 515531 Have we run out of oil yet? Oil peaking analysis from

    E-Print Network [OSTI]

    price shocks and economic downturns. Over the next 30 years oil demand is expected to grow by 60Energy Policy 34 (2006) 515­531 Have we run out of oil yet? Oil peaking analysis from an optimist of conventional oil production from an optimist's perspective. Is the oil peak imminent? What is the range

  4. Oil shale: The environmental challenges III

    SciTech Connect (OSTI)

    Petersen, K.K.

    1983-01-01T23:59:59.000Z

    This book presents the papers of a symposium whose purpose was to discuss the environmental and socio-economic aspects of oil shale development. Topics considered include oil shale solid waste disposal, modeling spent shale disposal, water management, assessing the effects of oil shale facilities on water quality, wastewater treatment and use at oil shale facilities, potential air emissions from oil shale retorting, the control of air pollutant emissions from oil shale facilities, oil shale air emission control, socioeconomic research, a framework for mitigation agreements, the Garfield County approach to impact mitigation, the relationship of applied industrial hygiene programs and experimental toxicology programs, and industrial hygiene programs.

  5. Figure 4. World Oil Prices

    U.S. Energy Information Administration (EIA) Indexed Site

    4. World Oil Prices" " (2007 dollars per barrel)" ,2007,2008,2009,2010,2011,2012,2013,2014,2015,2016,2017,2018,2019,2020,2021,2022,2023,2024,2025,2026,2027,2028,2029,2030...

  6. Method for enhanced oil recovery

    DOE Patents [OSTI]

    Comberiati, Joseph R. (Morgantown, WV); Locke, Charles D. (Morgantown, WV); Kamath, Krishna I. (Chicago, IL)

    1980-01-01T23:59:59.000Z

    The present invention is directed to an improved method for enhanced recovery of oil from relatively "cold" reservoirs by carbon dioxide flooding. In oil reservoirs at a temperature less than the critical temperature of 87.7.degree. F. and at a pore pressure greater than the saturation pressure of carbon dioxide at the temperature of the reservoir, the carbon dioxide remains in the liquid state which does not satisfactorily mix with the oil. However, applicants have found that carbon dioxide can be vaporized in situ in the reservoir by selectively reducing the pore pressure in the reservoir to a value less than the particular saturated vapor pressure so as to greatly enhance the mixing of the carbon dioxide with the oil.

  7. Oil and Gas Conservation (Nebraska)

    Broader source: Energy.gov [DOE]

    This section establishes the state's interest in encouraging the development, production, and utilization of natural gas and oil resources in a manner which will prevent waste and lead to the...

  8. Method for retorting oil shale

    DOE Patents [OSTI]

    Shang, Jer-Yu; Lui, A.P.

    1985-08-16T23:59:59.000Z

    The recovery of oil from oil shale is provided in a fluidized bed by using a fluidizing medium of a binary mixture of carbon dioxide and 5 steam. The mixture with a steam concentration in the range of about 20 to 75 volume percent steam provides an increase in oil yield over that achievable by using a fluidizing gas of carbon dioxide or steam alone when the mixture contains higher steam concentrations. The operating parameters for the fluidized bed retorted are essentially the same as those utilized with other gaseous fluidizing mediums with the significant gain being in the oil yield recovered which is attributable solely to the use of the binary mixture of carbon dioxide and steam. 2 figs.

  9. Oil shale, tar sands, and related materials

    SciTech Connect (OSTI)

    Stauffer, H.C.

    1981-01-01T23:59:59.000Z

    This sixteen-chapter book focuses on the many problems and the new methodology associated with the commercialization of the oil shale and tar sand industry. Topics discussed include: an overview of the Department of Energy's oil shale R, D, and D program; computer simulation of explosive fracture of oil shale; fracturing of oil shale by treatment with liquid sulfur dioxide; chemistry of shale oil cracking; hydrogen sulfide evolution from Colorado oil shale; a possible mechanism of alkene/alkane production in oil shale retorting; oil shale retorting kinetics; kinetics of oil shale char gasification; a comparison of asphaltenes from naturally occurring shale bitumen and retorted shale oils: the influence of temperature on asphaltene structure; beneficiation of Green River oil shale by density methods; beneficiation of Green River oil shale pelletization; shell pellet heat exchange retorting: the SPHER energy-efficient process for retorting oil shale; retorted oil shale disposal research; an investigation into the potential economics of large-scale shale oil production; commercial scale refining of Paraho crude shale oil into military specification fuels; relation between fuel properties and chemical composition; chemical characterization/physical properties of US Navy shale-II fuels; relation between fuel properties and chemical composition: stability of oil shale-derived jet fuel; pyrolysis of shale oil residual fractions; synfuel stability: degradation mechanisms and actual findings; the chemistry of shale oil and its refined products; the reactivity of Cold Lake asphaltenes; influence of thermal processing on the properties of Cold Lake asphaltenes: the effect of distillation; thermal recovery of oil from tar sands by an energy-efficient process; and hydropyrolysis: the potential for primary upgrading of tar sand bitumen.

  10. Enhanced oil recovery in Rumania

    SciTech Connect (OSTI)

    Carcoana, A.N.

    1982-01-01T23:59:59.000Z

    The paper describes the application of the fire-floods to a broad range of Romanian oil reservoirs and crude properties and reviews the field tests of polymer flooding, surfactant flooding and alkaline flooding. A commercial scale project with cyclic steam injection is presented and also the use of the domestic CO/sub 2/ sources to enhanced oil recovery. The results and the difficulties encountered are briefly discussed and also the potential of EOR methods in Romania are presented. 17 refs.

  11. Heavy Oil Upgrading from Electron Beam (E-Beam) Irradiation

    E-Print Network [OSTI]

    Yang, Daegil

    2011-02-22T23:59:59.000Z

    -heavy oil, and oil shale. Tremendous amounts of heavy oil resources are available in the world. Fig. 1.1 shows the total world oil reserves, and indicates that heavy oil, extra heavy oil, and bitumen make up about 70% of the world?s total oil resources...

  12. Enhanced oil recovery in Rumania

    SciTech Connect (OSTI)

    Carcoana, A.N.

    1982-01-01T23:59:59.000Z

    The wide oil field experience of the Romanian oil men in producing hydrocarbon reservoirs is based on an old tradition, but only after 1945 reservoir engineering studies were started in Romania. Beginning with 1950 conventional recovery methods expanded continually. During the last 10 years, however, the crude oil, as energy resource, has become of tremendous importance. The need for increasing the ultimate oil recovery has been felt in Romania as everywhere else. To attain this goal EOR methods were and are tested and expanded on a commercial scale. The paper describes the application of the fire-floods to a broad range of Romanian oil reservoirs and crude properties and reviews the field tests of polymer flooding, surfactant flooding and alkaline flooding. A commercial scale project with cyclic steam injection is presented and also the use of the domestic CO/sub 2/ sources to enhance oil recovery. The results and the diffuculties encountered are briefly discussed and also the potential of EOR methods in Romania are presented.

  13. Oil transportation in the global landscape : the Murmansk Oil Terminal and Pipeline proposal evaluated

    E-Print Network [OSTI]

    Roy, Ankur, 1976-

    2003-01-01T23:59:59.000Z

    Oil and transportation have been commingled since the first oil reserves were discovered. The importance of energy, namely oil, and the transportation of that energy from the producers to the consumers is persistently ...

  14. Oil Mist Compliance

    SciTech Connect (OSTI)

    Lazarus, Lloyd

    2009-02-02T23:59:59.000Z

    This report summarizes activities at the KCP related to evaluating and modifying machine tools in order to be in compliance with Section 23 of DOE 10 CFR 851, Worker Safety and Health Program. Section 851.23 (a) states that “Contractors must comply with the following safety and health standards that are applicable to the hazards in their covered workplace”, and subsection 9 contains the following applicable standard: “American Congress of Governmental Industrial Hygienists (ACGIH), ‘Threshold Limit Values for Chemical Substances and Physical Agents and Biological Exposure Indices,’ (2005) (incorporated by reference, see §851.27) when the ACGIH Threshold Limit Values are lower (more protective) than permissible exposure limits in 29 CFR 1910.” In the 2005 ACGIH – Threshold Limit Value book a Notice of Change was issued for exposure to mineral oil mist used in metalworking fluids (MWFs). The effects of planning for the new facility and which machine tools would be making the transition to the new facility affected which machine tools were modified.

  15. Clay-Oil Droplet Suspensions in Electric Field.

    E-Print Network [OSTI]

    Kjerstad, Knut Brøndbo

    2012-01-01T23:59:59.000Z

    ?? Silicone oil droplets containing synthetic smectite clay submerged in another immiscible organic oil have been studied by observing clay particle movement, oil circulation and… (more)

  16. Crude Existence: The Politics of Oil in Northern Angola

    E-Print Network [OSTI]

    Reed, Kristin

    2009-01-01T23:59:59.000Z

    waged for control of oil reserves. A brutal war wracked theguarantee rights to the oil reserves, offer an opportunitygles over control of oil reserves, but it also encompasses

  17. Northeast Home Heating Oil Reserve - Guidelines for Release ...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Heating Oil Reserve Northeast Home Heating Oil Reserve - Guidelines for Release Northeast Home Heating Oil Reserve - Guidelines for Release The Energy Policy and Conservation...

  18. Drunk On Oil: Russian Foreign Policy 2000-2007

    E-Print Network [OSTI]

    Brugato, Thomas

    2008-01-01T23:59:59.000Z

    Julia. “ World Stocks Sag as Oil Price Surges. ” The NewCollapse: Grain and Oil,” On the Issues, Am. Enterpriseet. al. , “Unrelenting Oil Addiction,” Russ. in Global

  19. Biocorrosive Thermophilic Microbial Communities in Alaskan North Slope Oil Facilities

    E-Print Network [OSTI]

    Duncan, Kathleen E.

    2010-01-01T23:59:59.000Z

    in Alaskan North Slope oil production facilities. Title:Profiling Despite oil production from several major16) was isolated from oil-production water and has optimal

  20. Dynamics of the Oil Transition: Modeling Capacity, Costs, and Emissions

    E-Print Network [OSTI]

    Brandt, Adam R.; Farrell, Alexander E.

    2008-01-01T23:59:59.000Z

    J. Regular conventional oil production to 2100 and resource10% of total US oil production in 2004, almost entirelysteam-induced heavy oil production in Cali- fornia [30].

  1. The effect of biofuel on the international oil market

    E-Print Network [OSTI]

    Hochman, Gal; Rajagopal, Deepak; Zilberman, David D.

    2010-01-01T23:59:59.000Z

    producer sur- plus from oil production and fuel consumption,to reduction in crude oil production. The competitive modelsurplus from oil consumption and production. Our baseline

  2. Oil and Natural Gas Subsector Cybersecurity Capability Maturity...

    Broader source: Energy.gov (indexed) [DOE]

    Oil and Natural Gas Subsector Cybersecurity Capability Maturity Model (February 2014) Oil and Natural Gas Subsector Cybersecurity Capability Maturity Model (February 2014) The Oil...

  3. Dynamics of the Oil Transition: Modeling Capacity, Costs, and Emissions

    E-Print Network [OSTI]

    Brandt, Adam R.; Farrell, Alexander E.

    2008-01-01T23:59:59.000Z

    response to high oil prices and geopolitical threats tofor the e?ect of the oil price through the price elasticityprojections, corresponding oil price series are extracted

  4. Modeling of Energy Production Decisions: An Alaska Oil Case Study

    E-Print Network [OSTI]

    Leighty, Wayne

    2008-01-01T23:59:59.000Z

    ENHANCED OIL RECOVERY of carbon value and enhanced oil recovery The potential forCO 2 injection for enhanced oil recovery may differ from the

  5. Crude Existence: The Politics of Oil in Northern Angola

    E-Print Network [OSTI]

    Reed, Kristin

    2009-01-01T23:59:59.000Z

    Front in Cabinda, 47 Security: oil operations, 182 –83,Like an Oil Company: Space, Security and Global Capital inarms deals and private security than oil exploitation (HRW

  6. Conversion Technologies for Advanced Biofuels - Bio-Oil Upgrading...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Oil Upgrading Conversion Technologies for Advanced Biofuels - Bio-Oil Upgrading PNNL report-out at the CTAB webinar on Bio-Oil Upgrading. ctabwebinarbiooilsupgrading.pdf More...

  7. Growing Energy - How Biofuels Can Help End America's Oil Dependence...

    Broader source: Energy.gov (indexed) [DOE]

    Growing Energy - How Biofuels Can Help End America's Oil Dependence Growing Energy - How Biofuels Can Help End America's Oil Dependence America's oil dependence threatens our...

  8. Oil Shale and Other Unconventional Fuels Activities | Department...

    Broader source: Energy.gov (indexed) [DOE]

    Naval Reserves Oil Shale and Other Unconventional Fuels Activities Oil Shale and Other Unconventional Fuels Activities The Fossil Energy program in oil shale focuses on...

  9. Biocorrosive Thermophilic Microbial Communities in Alaskan North Slope Oil Facilities

    E-Print Network [OSTI]

    Duncan, Kathleen E.

    2010-01-01T23:59:59.000Z

    anaerobic thermophilic oil reservoir and well communities.been detected in hot oil reservoirs and production fluids (other thermophilic oil reservoirs and wells suggests that

  10. An MBendi Profile: World: Oil And Gas Industry -Peak Oil: an Outlook on Crude Oil Depletion -C.J.Campbell -Revised February 2002 Search for

    E-Print Network [OSTI]

    An MBendi Profile: World: Oil And Gas Industry - Peak Oil: an Outlook on Crude Oil Depletion - C - Contact Us - Newsletter Register subscribe to our FREE newsletter World: Oil And Gas Industry - Peak Oil the subsequent decline. q Gas, which is less depleted than oil, will likely peak around 2020. q Capacity limits

  11. Crude oil prices and petroleum inventories : remedies for a broken oil price forecasting model.

    E-Print Network [OSTI]

    Grimstad, Dan

    2007-01-01T23:59:59.000Z

    ??The empirical relationship between crude oil prices and petroleum inventories has been exploited in a number of short-term oil price forecasting models. Some of the… (more)

  12. Future North Sea oil production and its implications for Swedish oil supply regarding the transport sector.

    E-Print Network [OSTI]

    Sällh, David

    2012-01-01T23:59:59.000Z

    ?? Historically, it has been negative to be dependent on only one resource, in the current situation this resource represents oil. The oil dependence is… (more)

  13. Bio-oil fractionation and condensation

    DOE Patents [OSTI]

    Brown, Robert C; Jones, Samuel T; Pollard, Anthony

    2013-07-02T23:59:59.000Z

    A method of fractionating bio-oil vapors which involves providing bio-oil vapors comprising bio-oil constituents is described. The bio-oil vapors are cooled in a first stage which comprises a condenser having passages for the bio-oil separated by a heat conducting wall from passages for a coolant. The coolant in the condenser of the first stage is maintained at a substantially constant temperature, set at a temperature in the range of 75 to 100.degree. C., to condense a first liquid fraction of liquefied bio-oil constituents in the condenser of the first stage. The first liquid fraction of liquified bio-oil constituents from the condenser in the first stage is collected. Also described are steps for subsequently recovering further liquid fractions of liquefied bio-oil constituents. Particular compositions of bio-oil condensation products are also described.

  14. Oil shale retorting method and apparatus

    SciTech Connect (OSTI)

    York, E.D.

    1983-03-22T23:59:59.000Z

    Disclosed is an improved method and apparatus for the retorting of oil shale and the formation of spent oil shale having improved cementation properties. The improved method comprises passing feed comprising oil shale to a contacting zone wherein the feed oil shale is contacted with heat transfer medium to heat said shale to retorting temperature. The feed oil shale is substantially retorted to form fluid material having heating value and forming partially spent oil shale containing carbonaceous material. At least a portion of the partially spent oil shale is passed to a combustion zone wherein the partially spent oil shale is contacted with oxidizing gas comprising oxygen and steam to substantially combust carbonaceous material forming spent oil shale having improved cementation properties.

  15. Oil Price Shocks: Causes and Consequences

    E-Print Network [OSTI]

    Lutz Kilian; Key Words

    Research on oil markets conducted during the last decade has challenged long-held beliefs about the causes and consequences of oil price shocks. As the empirical and theoretical models used by economists have evolved, so has our understanding of the determinants of oil price shocks and of the interaction between oil markets and the global economy. Some of the key insights are that the real price of oil is endogenous with respect to economic fundamentals, and that oil price shocks do not occur ceteris paribus. This makes it necessary to explicitly account for the demand and supply shocks underlying oil price shocks when studying their transmission to the domestic economy. Disentangling cause and effect in the relationship between oil prices and the economy requires structural models of the global economy including oil and other commodity markets.

  16. Crude oil prices: Are our oil markets too tight?

    SciTech Connect (OSTI)

    Simmons, M.R. [Simmons and Co. International, Houston, TX (United States)

    1997-02-01T23:59:59.000Z

    The answer to the question posed in the title is that tightness in the market will surely prevail through 1997. And as discussed herein, with worldwide demand expected to continue to grow, there will be a strong call on extra oil supply. Meeting those demands, however, will not be straightforward--as many observers wrongly believe--considering the industry`s practice of maintaining crude stocks at ``Just in time`` inventory levels. Further, impact will be felt from the growing rig shortage, particularly for deepwater units, and down-stream capacity limits. While these factors indicate 1997 should be another good year for the service industry, it is difficult to get any kind of consensus view from the oil price market. With most observers` information dominated by the rarely optimistic futures price of crude, as reflected by the NYMEX, the important fact is that oil prices have remained stable for three years and increased steadily through 1996.

  17. Oil history, potential converge in Azerbaijan

    SciTech Connect (OSTI)

    Narimanov, A.A. [State Oil Co. of Azerbaijan, Baku (Azerbaijan); Palaz, I. [Amoco Production Co., Houston, TX (United States)

    1995-05-22T23:59:59.000Z

    Azerbaijan, the oldest known oil producing region in the world, still holds great potential for new discoveries and increased production. A multi-billion dollar production sharing agreement was recently signed with a consortium of primarily western oil companies to develop three oil fields in the Caspian Sea. Soon, Azerbaijan will offer new exploration acreage both offshore and onshore. This paper describes the history of oil production in Azerbaijan, offshore developments, tectonics, stratigraphy, petroleum traps, mud volcanoes, and short summaries of several oil producing areas. Current production is about 9 million tons/yr of oil and 7 billion cu m/yr of natural gas.

  18. Oil shale technology. Final report

    SciTech Connect (OSTI)

    NONE

    1995-03-01T23:59:59.000Z

    This collaborative project with industrial participants studied oil shale retorting through an integrated program of fundamental research, mathematical model development and operation of a 4-tonne-per-day solid recirculation oil shale test unit. Quarterly, project personnel presented progress and findings to a Project Guidance Committee consisting of company representatives and DOE program management. We successfully operated the test unit, developed the oil shale process (OSP) mathematical model, evaluated technical plans for process scale up and determined economics for a successful small scale commercial deployment, producing premium motor fuel, specility chemicals along with electricity co-production. In budget negotiations, DOE funding for this three year CRADA was terminated, 17 months prematurely, as of October 1993. Funds to restore the project and continue the partnership have not been secured.

  19. Shale Oil Value Enhancement Research

    SciTech Connect (OSTI)

    James W. Bunger

    2006-11-30T23:59:59.000Z

    Raw kerogen oil is rich in heteroatom-containing compounds. Heteroatoms, N, S & O, are undesirable as components of a refinery feedstock, but are the basis for product value in agrochemicals, pharmaceuticals, surfactants, solvents, polymers, and a host of industrial materials. An economically viable, technologically feasible process scheme was developed in this research that promises to enhance the economics of oil shale development, both in the US and elsewhere in the world, in particular Estonia. Products will compete in existing markets for products now manufactured by costly synthesis routes. A premium petroleum refinery feedstock is also produced. The technology is now ready for pilot plant engineering studies and is likely to play an important role in developing a US oil shale industry.

  20. CONTROL STRATEGIES FOR ABANDONED IN-SITU OIL SHALE RETORTS

    E-Print Network [OSTI]

    Persoff, P.

    2011-01-01T23:59:59.000Z

    recovery Vent gas '\\Raw shale oil Recycled gas compressorThis process produces shale oil, a low BTU gas, and char,Oil Shale Process" in Oil Shale and Tar Sands, J. W. Smith

  1. The Politics of Mexico’s Oil Monopoly

    E-Print Network [OSTI]

    Huizar, Richard

    2008-01-01T23:59:59.000Z

    based on the current oil reserves and oil production? 2) Forto either increase its oil reserves or decrease its oilthe world in terms of oil reserves by having 16,041 million

  2. Pipeline Flow Behavior of Water-In-Oil Emulsions.

    E-Print Network [OSTI]

    Omer, Ali

    2009-01-01T23:59:59.000Z

    ??Water-in-oil (W/O) emulsions consist of water droplets dispersed in continuous oil phase. They are encountered at various stages of oil production. The oil produced from… (more)

  3. Cursed Resources? Political Conditions and Oil Market Volatility*

    E-Print Network [OSTI]

    Edwards, Paul N.

    a country's political conditions affect oil production within its borders. We show production, with very democratic regimes exhibiting less volatility in their oil production than more of oil production volatility. Our finding has implications both for understanding world oil markets

  4. Modeling of Energy Production Decisions: An Alaska Oil Case Study

    E-Print Network [OSTI]

    Leighty, Wayne

    2008-01-01T23:59:59.000Z

    and Weimer, D.L. (1984) Oil prices shock, market response,OPEC behavior and world oil prices (pp. 175-185) London:many decades. Recent high oil prices have caused oil-holding

  5. Modeling of Energy Production Decisions: An Alaska Oil Case Study

    E-Print Network [OSTI]

    Leighty, Wayne

    2008-01-01T23:59:59.000Z

    Oil Production The production of crude oil can generally beNorth Slope crude, Q it is the oil production per perioddiscoveries, production, costs, and prices of crude oil. ”

  6. Crude Existence: The Politics of Oil in Northern Angola

    E-Print Network [OSTI]

    Reed, Kristin

    2009-01-01T23:59:59.000Z

    threatening to onshore oil investments in Cabinda. It usedto a $2.2 billion oil and gas investment in Block 14. Oil,the full burden of capital investment, oil corporations also

  7. The effect of biofuel on the international oil market

    E-Print Network [OSTI]

    Hochman, Gal; Rajagopal, Deepak; Zilberman, David D.

    2010-01-01T23:59:59.000Z

    Fig. 1, where aggregate demand for oil is denoted D + D ? ,oil-exporting and oil-importing countries’ demand functionsinelastic global demand for crude oil, the elasticity of the

  8. Measurement of Oil and Gas Emissions from a Marine Seep

    E-Print Network [OSTI]

    Leifer, Ira; Boles, J R; Luyendyk, B P

    2007-01-01T23:59:59.000Z

    2007, Measurement of Oil and Gas Emissions from a Marine2007, Measurement of Oil and Gas Emissions from a MarineTides and the emission of oil and gas from an abandoned oil

  9. Heavy oil production from Alaska

    SciTech Connect (OSTI)

    Mahmood, S.M.; Olsen, D.K. [NIPER/BDM-Oklahoma, Inc., Bartlesville, OK (United States); Thomas, C.P. [Idaho National Engineering Lab., Idaho Falls, ID (United States)

    1995-12-31T23:59:59.000Z

    North Slope of Alaska has an estimated 40 billion barrels of heavy oil and bitumen in the shallow formations of West Sak and Ugnu. Recovering this resource economically is a technical challenge for two reasons: (1) the geophysical environment is unique, and (2) the expected recovery is a low percentage of the oil in place. The optimum advanced recovery process is still undetermined. Thermal methods would be applicable if the risks of thawing the permafrost can be minimized and the enormous heat losses reduced. Use of enriched natural gas is a probable recovery process for West Sak. Nearby Prudhoe Bay field is using its huge natural gas resources for pressure maintenance and enriched gas improved oil recovery (IOR). Use of carbon dioxide is unlikely because of dynamic miscibility problems. Major concerns for any IOR include close well spacing and its impact on the environment, asphaltene precipitation, sand production, and fines migration, in addition to other more common production problems. Studies have indicated that recovering West Sak and Lower Ugnu heavy oil is technically feasible, but its development has not been economically viable so far. Remoteness from markets and harsh Arctic climate increase production costs relative to California heavy oil or Central/South American heavy crude delivered to the U.S. Gulf Coast. A positive change in any of the key economic factors could provide the impetus for future development. Cooperation between the federal government, state of Alaska, and industry on taxation, leasing, and permitting, and an aggressive support for development of technology to improve economics is needed for these heavy oil resources to be developed.

  10. Low pour crude oil compositions

    SciTech Connect (OSTI)

    Motz, K.L.; Latham, R.A.; Statz, R.J.

    1990-05-22T23:59:59.000Z

    This patent describes and improvement in the process of transporting waxy crude oils through a pipeline. It comprises: incorporating into the crude oil an effective pour point depressant amount of an additive comprising a polymer selected from the group consisting of copolymers of ethylene and acrylonitrile, and terpolymers of ethylene, acrylonitrile and a third monomer selected from the group consisting of vinyl acetate, carbon monoxide, alkyl acrylates, alkyl methacrylates, alkyl vinyl ethers, vinyl chloride, vinyl fluoride, acrylic acid, and methacrylic acid, wherein the amount of third monomer in the terpolymer ranges from about 0.1 to about 10.0 percent by weight.

  11. Residential heating oil price increases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLas ConchasPassive Solar HomePromisingStories »Submitter A Bheating oil priceheating oil price

  12. Residential heating oil price increases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLas ConchasPassive Solar HomePromisingStories »Submitter A Bheating oil priceheating oil price9,

  13. Residential heating oil price increases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLas ConchasPassive Solar HomePromisingStories »Submitter A Bheating oil priceheating oil

  14. Residential heating oil prices decline

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLas ConchasPassive Solar HomePromisingStories »Submitter A Bheating oil priceheatingheating oil

  15. Industrial Utilization of Coal-Oil Mixtures

    E-Print Network [OSTI]

    Dunn, J. E.; Hawkins, G. T.

    1982-01-01T23:59:59.000Z

    Coal-oil mixtures (COM) are receiving increasing interest as economical alternatives to residual fuel oil and natural gas used in heavy industrial and utility applications. Four basic approaches are currently employed in the manufacture of COM...

  16. Completion of Oil Wells May 4, 2003

    E-Print Network [OSTI]

    Rudge, John

    Completion of Oil Wells John Rudge May 4, 2003 1 Introduction After the initial drilling of an oil the small gap, lubrication theory can be used to study the flow. Non-dimensionalise all lengths on the gap

  17. An experimental investigation into oil mist lubrication

    E-Print Network [OSTI]

    Kannan, Krishna

    2000-01-01T23:59:59.000Z

    Oil mist lubrication offers many advantages over sump lubrication. Unfortunately, mist lubrication generates sub-micrometer sized aerosol particles (fines) that escape from the oil mist lubrication system. These particles are an environmental hazard...

  18. Low-rank coal oil agglomeration

    DOE Patents [OSTI]

    Knudson, Curtis L. (Grand Forks, ND); Timpe, Ronald C. (Grand Forks, ND)

    1991-01-01T23:59:59.000Z

    A low-rank coal oil agglomeration process. High mineral content, a high ash content subbituminous coals are effectively agglomerated with a bridging oil which is partially water soluble and capable of entering the pore structure, and usually coal derived.

  19. Microbial enhanced oil recovery and compositions therefor

    DOE Patents [OSTI]

    Bryant, Rebecca S. (Bartlesville, OK)

    1990-01-01T23:59:59.000Z

    A method is provided for microbial enhanced oil recovery, wherein a combination of microorganisms is empirically formulated based on survivability under reservoir conditions and oil recovery efficiency, such that injection of the microbial combination may be made, in the presence of essentially only nutrient solution, directly into an injection well of an oil bearing reservoir having oil present at waterflood residual oil saturation concentration. The microbial combination is capable of displacing residual oil from reservoir rock, which oil may be recovered by waterflooding without causing plugging of the reservoir rock. Further, the microorganisms are capable of being transported through the pores of the reservoir rock between said injection well and associated production wells, during waterflooding, which results in a larger area of the reservoir being covered by the oil-mobilizing microorganisms.

  20. Method of removing polychlorinated biphenyl from oil

    DOE Patents [OSTI]

    Cook, G.T.; Holshouser, S.K.; Coleman, R.M.; Harless, C.E.; Whinnery, W.N. III

    1982-03-17T23:59:59.000Z

    Polychlorinated biphenyls are removed from oil by extracting the biphenyls into methanol. The mixture of methanol and extracted biphenyls is distilled to separate methanol therefrom, and the methanol is recycled for further use in extraction of biphenyls from oil.

  1. Oil, Gas, and Mining Leases (Nebraska)

    Broader source: Energy.gov [DOE]

    This section contains rules on oil, gas, and mining leases, and grants authority to the State of Nebraska and local governments to issue leases for oil and gas mining and exploration on their lands.

  2. Oil and Gas Conservation (South Dakota)

    Broader source: Energy.gov [DOE]

    The Minerals and Mining Program oversees the regulation of oil and gas exploration, recovery, and reclamation activities in South Dakota. Permits are required for drilling of oil or gas wells, and...

  3. Regulation of Oil and Gas Resources (Florida)

    Broader source: Energy.gov [DOE]

    It is the public policy of the state to conserve and control the natural resources of oil and gas, and their products; to prevent waste of oil and gas; to provide for the protection and adjustment...

  4. Interstate Oil and Gas Conservation Compact (Montana)

    Broader source: Energy.gov [DOE]

    This legislation authorizes the State to join the Interstate Compact for the Conservation of Oil and Gas. The Compact is an agreement that has been entered into by 30 oil- and gas-producing states,...

  5. Oil and Gas on Public Lands (Texas)

    Broader source: Energy.gov [DOE]

    The School Land Board may choose to lease lands for the production of oil and natural gas, on the condition that oil and gas resources are leased together and separate from other minerals. Lands...

  6. Conservation of Oil and Gas (Texas)

    Broader source: Energy.gov [DOE]

    This legislation prohibits the production, storage, or transportation of oil or gas in a manner, in an amount, or under conditions that constitute waste. Actions which may lead to the waste of oil...

  7. Interstate Oil and Gas Conservation Compact (Maryland)

    Broader source: Energy.gov [DOE]

    This legislation authorizes the State to join the Interstate Compact for the Conservation of Oil and Gas. The Compact is an agreement that has been entered into by 30 oil- and gas-producing states,...

  8. Virginia Gas and Oil Act (Virginia)

    Broader source: Energy.gov [DOE]

    The Gas and Oil Act addresses the exploration, development, and production of oil and gas resources in the Commonwealth of Virginia. It contains provisions pertaining to wells and well spacing,...

  9. The effect of biofuel on the international oil market

    E-Print Network [OSTI]

    Hochman, Gal; Rajagopal, Deepak; Zilberman, David D.

    2010-01-01T23:59:59.000Z

    to reduction in crude oil production. The competitive modelbarrel of crude oil is allocated to gasoline production. The

  10. The effect of biofuel on the international oil market

    E-Print Network [OSTI]

    Hochman, Gal; Rajagopal, Deepak; Zilberman, David D.

    2010-01-01T23:59:59.000Z

    world consumption of crude oil, consumption grew from 2005mark). Although consumption of crude oil in the Middle East,

  11. Measurement of Oil and Gas Emissions from a Marine Seep

    E-Print Network [OSTI]

    Leifer, Ira; Boles, J R; Luyendyk, B P

    2007-01-01T23:59:59.000Z

    with offshore oil production, Geology, 27(11), 1047-1050,Coal Oil Point, California, Marine and Petroleum Geology 22(

  12. POLYVINYLCHLORIDE WASTE WITH OIL SHALE ASH TO CAPTURE

    E-Print Network [OSTI]

    V. Oja; A. Elenurm; I. Rohtla; E. Tearo; E. Tali

    alkaline oil shale ash. Solid heat carrier (Galoter process)-type oil shale retorting units, where the

  13. Process for tertiary oil recovery using tall oil pitch

    DOE Patents [OSTI]

    Radke, C.J.

    1983-07-25T23:59:59.000Z

    A process and compositions for enhancing the recovery of acid crudes are disclosed. The process involves injecting caustic solutions into the reservoir to maintain a pH of 11 to 13. The fluid contains an effective amount of multivalent cation for inhibiting alkaline silica dissolution with the reservoir. A tall oil pitch soap is added as a polymeric mobility control agent. (DMC)

  14. Overview of Aviation Fuel Markets for Biofuels Stakeholders

    SciTech Connect (OSTI)

    Davidson, C.; Newes, E.; Schwab, A.; Vimmerstedt, L.

    2014-07-01T23:59:59.000Z

    This report is for biofuels stakeholders interested the U.S. aviation fuel market. Jet fuel production represents about 10% of U.S. petroleum refinery production. Exxon Mobil, Chevron, and BP top producers, and Texas, Louisiana, and California are top producing states. Distribution of fuel primarily involves transport from the Gulf Coast to other regions. Fuel is transported via pipeline (60%), barges on inland waterways (30%), tanker truck (5%), and rail (5%). Airport fuel supply chain organization and fuel sourcing may involve oil companies, airlines, airline consortia, airport owners and operators, and airport service companies. Most fuel is used for domestic, commercial, civilian flights. Energy efficiency has substantially improved due to aircraft fleet upgrades and advanced flight logistic improvements. Jet fuel prices generally track prices of crude oil and other refined petroleum products, whose prices are more volatile than crude oil price. The single largest expense for airlines is jet fuel, so its prices and persistent price volatility impact industry finances. Airlines use various strategies to manage aviation fuel price uncertainty. The aviation industry has established goals to mitigate its greenhouse gas emissions, and initial estimates of biojet life cycle greenhouse gas emissions exist. Biojet fuels from Fischer-Tropsch and hydroprocessed esters and fatty acids processes have ASTM standards. The commercial aviation industry and the U.S. Department of Defense have used aviation biofuels. Additional research is needed to assess the environmental, economic, and financial potential of biojet to reduce greenhouse gas emissions and mitigate long-term upward price trends, fuel price volatility, or both.

  15. Estimating Surface Oil Extent from the Deepwater Horizon Oil Spill using ASCAT Backscatter

    E-Print Network [OSTI]

    Long, David G.

    Estimating Surface Oil Extent from the Deepwater Horizon Oil Spill using ASCAT Backscatter Richard Provo, UT 84602 Abstract--The damping effects of oil on capillary ocean waves alter the backscattered backscatter from the ocean surface uncontaminated by surface oil. Large differences between expected

  16. BP Oil Spill and Air Chemistry Crude oil contains various hydrocarbons

    E-Print Network [OSTI]

    Toohey, Darin W.

    BP Oil Spill and Air Chemistry Crude oil contains various hydrocarbons NOAA and CIRES here at CU went to the oil spill in an aircraft that was equipped with instruments to measure the air quality. 1/3 of the oil dissolved into the water column (methane completely, benzene and ethane almost completely) Showed

  17. Method to separate and recover oil and plastic from plastic contaminated with oil

    DOE Patents [OSTI]

    Smith, Henry M. (Overland Park, KS); Bohnert, George W. (Harrisonville, MO); Olson, Ronald B. (Kansas City, MO); Hand, Thomas E. (Lee's Summit, MO)

    1998-01-27T23:59:59.000Z

    The present invention provides a method to separate and recover oils and recyclable plastic from plastic contaminated with oil. The invention utilizes the different solubility of oil in as liquid or supercritical fluid as compared to a gas to effect separation of the oil from the plastic.

  18. Method to separate and recover oil and plastic from plastic contaminated with oil

    DOE Patents [OSTI]

    Smith, H.M.; Bohnert, G.W.; Olson, R.B.; Hand, T.E.

    1998-01-27T23:59:59.000Z

    The present invention provides a method to separate and recover oils and recyclable plastic from plastic contaminated with oil. The invention utilizes the different solubility of oil in a liquid or supercritical fluid as compared to a gas to effect separation of the oil from the plastic. 3 figs.

  19. Canadian oil market review shows growing influence of heavy oil and bitumen

    SciTech Connect (OSTI)

    Not Available

    1986-09-01T23:59:59.000Z

    Canadian oil demand and consumption, crude oil received at refineries, oil well productivity including shut-in production, and exports and imports are discussed. Both light and heavy oil, natural gas, and bitumen are included in the seasonally-adjusted data presented.

  20. Tea Oil Camellia: a New Edible Oil Crop for the United States John M. Ruter

    E-Print Network [OSTI]

    Radcliffe, David

    1 Tea Oil Camellia: a New Edible Oil Crop for the United States© John M. Ruter The University@uga.edu INTRODUCTION Camellia oleifera has been cultivated in China as a source of edible oil. oleifera as a commercial oil seed crop for the southeast (Ruter, 2002). Considerable research is being

  1. Interactive coastal oil spill transport model

    E-Print Network [OSTI]

    Thalasila, Nanda K.

    1992-01-01T23:59:59.000Z

    . 6 fuel oils, diesel or No. 2 fuel oils, and light petroleum products such as kerosenes or gasolines. Crude oils of different ge- ologic and geographic sources vary widely in composition. Thousands of individual compounds, mostly hydrocarbons... Composition (by Weight) of Various Petroleum Substances, (adapted from Moore, Dwyer, and Katz 1972) 16 IV Comparison of Solubilities for Various Petroleum Substances, (adapted from Moore, Dwyer, and Katz 1972) 17 V Biodegradation Rates of Crude Oils...

  2. Straight Vegetable Oil as a Diesel Fuel?

    SciTech Connect (OSTI)

    Not Available

    2006-04-01T23:59:59.000Z

    Two-page fact sheet discussing the pitfalls of using straight vegetable oil (SVO) as a transportation fuel.

  3. FLUIDIZED BED COMBUSTION UNIT FOR OIL SHALE

    E-Print Network [OSTI]

    M. Hammad; Y. Zurigat; S. Khzai; Z. Hammad; O. Mubydeem

    combustion performance using oil shale as fuel in direct burning process. It is a steel column of 18 cm

  4. Division of Oil, Gas, and Mining Permitting

    E-Print Network [OSTI]

    Utah, University of

    " or "Gas" does not include any gaseous or liquid substance processed from coal, oil shale, or tar sands

  5. Carbon sequestration in depleted oil shale deposits

    SciTech Connect (OSTI)

    Burnham, Alan K; Carroll, Susan A

    2014-12-02T23:59:59.000Z

    A method and apparatus are described for sequestering carbon dioxide underground by mineralizing the carbon dioxide with coinjected fluids and minerals remaining from the extraction shale oil. In one embodiment, the oil shale of an illite-rich oil shale is heated to pyrolyze the shale underground, and carbon dioxide is provided to the remaining depleted oil shale while at an elevated temperature. Conditions are sufficient to mineralize the carbon dioxide.

  6. 1 Copyright 2013 by ASME Proceedings of the ASME Fluids Engineering Summer Meeting

    E-Print Network [OSTI]

    Ghajar, Afshin J.

    , USA T.J. O'Hern Engineering Sciences Center Sandia National Laboratories Albuquerque, New Mexico, USA of coal slurry to produce synthetic fuels during the Fischer-Tropsch process. Vertical vibration of larger amplitudes. Therefore, a new experimental set up was designed, built, verified by comparison

  7. Neutrons for Catalysis: A Workshop on Neutron Scattering Techniques for Studies in Catalysis

    E-Print Network [OSTI]

    Pennycook, Steve

    -EM Fischer Tropsch Catalysis on Fe- or Co-catalysts, ,,CTL" Coal to Liquids ­ ,a rough (?) analogy #12;Peter Albers, AQ-EM Carbonaceous Deposits on Catalysts #12;Peter Albers, AQ-EM IINS on Coked Catalysts from Industrial Plants High-temperature and low-temperature cokes deposited on catalysts during

  8. OATAO is an open access repository that collects the work of Toulouse researchers and makes it freely available over the web where possible.

    E-Print Network [OSTI]

    Mailhes, Corinne

    process simulation software ­ ProSimPlus® ­ to allow physical modeling as well as mass and energy balances is based on the gasification of the biomass followed by Fischer-Tropsch Synthesis (FTS), producing naphtha Sustainability assessment of an integrated High Temperature Steam Electrolysis - enhanced Biomass to Liquid Fuel

  9. Published on Web Date: December 01, 2010 r 2010 American Chemical Society 3451 DOI: 10.1021/jz1012627 |J. Phys. Chem. Lett. 2010, 1, 34513458

    E-Print Network [OSTI]

    Kenis, Paul J. A.

    , methane, and ethylene with high current efficiency. These products can be used as feed- stocks dependence on imported pe- troleum, the development and expansion of natural gas to liquid (GTL) and coal monoxide, which is then converted into liquid fuels via the Fischer-Tropsch process,2,3 and both are well

  10. innovative research fa l l 2 0 0 6

    E-Print Network [OSTI]

    New Mexico, University of

    , to make fuel cells, to cleanly liquefy coal, and to meet the dramatically increasing global demand of the Journal of Catalysis,two editions of the Handbook of Heterogeneous Catalysis, as well as a special issue control, methane com- bustion, selective hydrogenation, Fischer- Tropsch synthesis,methanol steam

  11. Optimal Simultaneous Production of Hydrogen and Liquid Fuels from Glycerol: Integrating the

    E-Print Network [OSTI]

    Grossmann, Ignacio E.

    of the ratio CO / H2 (bypass, PSA and water gas shift). Next, the removal of CO2 is performed by means of PSA and the syngas is fed to the Fischer - Tropsch reactor. The products obtained are separated while the heavy with the current automobile and gasoline supply chains. However, the profitability of biofuels depends heavily

  12. Engineering Project Solar-Boosted

    E-Print Network [OSTI]

    at the Australian National University. #12;4 Abstract Solar gasification of biomass presents an attractive avenue fuels and chemicals derived via the Fischer-Tropsch process (Dry 2002). Supercritical water gasification (SCWG) has been shown to rapidly achieve char-free gasification, yielding a gas rich in H2, CH4, CO

  13. William W. Hay Railroad Engineering Seminar Freight Railroad Energy

    E-Print Network [OSTI]

    Barkan, Christopher P.L.

    (importance v difficulties) North American freight RRs (defining characteristics) Energy density of diesel fuel & alternatives (Btu's per gallon) Biodiesel, Fischer-Tropsch syn fuel & DME Liquefied natural of European RRs (lessons learned) Dual-mode locomotives ("electro-diesels") Unconventional alternatives

  14. Attrition resistant bulk iron catalysts and processes for preparing and using same

    DOE Patents [OSTI]

    Jothimurugesan, Kandaswamy (Ponca City, OK); Goodwin, Jr., James G. (Clemson, SC); Gangwal, Santosh K. (Cary, NC)

    2007-08-21T23:59:59.000Z

    An attrition resistant precipitated bulk iron catalyst is prepared from iron oxide precursor and a binder by spray drying. The catalysts are preferably used in carbon monoxide hydrogenation processes such as Fischer-Tropsch synthesis. These catalysts are suitable for use in fluidized-bed reactors, transport reactors and, especially, slurry bubble column reactors.

  15. Exergy Analysis of a GTL Process Based on Low-Temperature Slurry F-T Reactor Technology with a Cobalt Catalyst

    E-Print Network [OSTI]

    Kjelstrup, Signe

    and Hans Tropsch; their aim was to use a mixture of CO and H2 (referred to as synthesis gas, syngas) to produce hydrocarbons, chemicals, and liquid fuels. The production of syngas was achieved by coal into syngas and, then, Fischer-Tropsch synthesis of syngas into synthetic liquid fuels. A first plant

  16. XIII.1-Draft ATTACHMENT XIII

    E-Print Network [OSTI]

    Kentucky, University of

    XIII.1-Draft ATTACHMENT XIII Review of Fischer-Tropsch Work by Statoil Three patents on Fischer are summarized below (XIII.1-XIII.3). These individuals summarize the background for their invention. Anderson amount (0.1 - 5%, preferably 0.1 to 2 wt.%) of a metal #12;XIII.3-Draft oxide promoter in addition

  17. Microemulsion impregnated catalyst composite and use thereof in a synthesis gas conversion process

    DOE Patents [OSTI]

    Abrevaya, Hayim (Chicago, IL); Targos, William M. (Palatine, IL)

    1987-01-01T23:59:59.000Z

    A catalyst composition for synthesis gas conversion comprising a ruthenium metal component deposited on a support carrier wherein the average metal particle size is less than about 100 A. The method of manufacture of the composition via a reverse micelle impregnation technique and the use of the composition in a Fischer-Tropsch conversion process is also disclosed.

  18. Microemulsion impregnated catalyst composite and use thereof in a synthesis gas conversion process

    DOE Patents [OSTI]

    Abrevaya, H.; Targos, W.M.

    1987-12-22T23:59:59.000Z

    A catalyst composition is described for synthesis gas conversion comprising a ruthenium metal component deposited on a support carrier wherein the average metal particle size is less than about 100 A. The method of manufacture of the composition via a reverse micelle impregnation technique and the use of the composition in a Fischer-Tropsch conversion process is also disclosed.

  19. ELSEVIER Surface Science 303 (lYY4) 206-230 ;,,.;_:_.y y .../. .' ..`,. :> .,

    E-Print Network [OSTI]

    Miller, William H.

    by means of the Fischer- Tropsch technique, and the steam reforming of natural gas to form so-called syngas. Representative examples are the ammonia synthesis via Haber-Bosch, the synthesis of alco- hols and hydrocarbons of products, and (7) diffusion of products from the surface. One typically treats these elementary reactions

  20. Comparative Analysis of the Production Costs and Life-Cycle GHG Emissions of FT-Liquid Fuels from Coal and

    E-Print Network [OSTI]

    Jaramillo, Paulina

    Coal and Natural Gas Figure S1 shows a graphical description of the life cycle of coal-to-liquids (CTL) and gas-to-liquids (GTL). Figure S1: Life Cycle of Coal-Based and Natural Gas-Based Fischer-Tropsch LiquidComparative Analysis of the Production Costs and Life- Cycle GHG Emissions of FT-Liquid Fuels from

  1. 1 Copyright 2012 by ASME Proceedings of ASME Turbo Expo 2012

    E-Print Network [OSTI]

    cycles for three interesting coal fired, gasification based, plants with CO2 capture: a Fischer Tropsch synthesis processes with once-through reactor (CTL-OT-CCS), and an integrated gasification combined cycle systems typically comprise a Heat Recovery Steam Cycle (HRSC) fed with waste heat from gas turbines and

  2. Modelling of a solar-powered supercritical water biomass gasifier Laurance A Watson1

    E-Print Network [OSTI]

    is incorporated that recovers the waste heat proceeding biomass gasification. Under the ideal assumptions applied exercise to design a solar supercritical water gasification (SCWG) reactor. A formative reactor concept the waste heat (steam) of a downstream Fischer- Tropsch process. An intermediate heat exchange unit

  3. Process for producing dimethyl ether form synthesis gas

    DOE Patents [OSTI]

    Pierantozzi, Ronald (Macungie, PA)

    1985-01-01T23:59:59.000Z

    This invention pertains to a Fischer Tropsch process for converting synthesis gas to an oxygenated hydrocarbon with particular emphasis on dimethyl ether. Synthesis gas comprising carbon monoxide and hydrogen are converted to dimethyl ether by carrying out the reaction in the presence of an alkali metal-manganese-iron carbonyl cluster incorporated onto a zirconia-alumina support.

  4. Cooking with Healthier Fats and Oils When you do use fats

    E-Print Network [OSTI]

    Bandettini, Peter A.

    Cooking with Healthier Fats and Oils When you do use fats and oils, choose those with less Oil Use this chart to help you choose products with less saturated fat. Look for the to findLessOfteneOftenChooseMor Canola Oil Safflower Oil Sesame Oil Sunflower Oil Corn Oil Olive Oil Soybean Oil Margarine (tub) Peanut

  5. Carcinogenicity Studies of Estonian Oil Shale Soots

    E-Print Network [OSTI]

    A. Vosamae

    Several series of chronic experiments in white mice and white rats were carried out in order to determine the carcinogenicity of Estonian oil shale soot as well as the soot from oil shale fuel oil. All the investigated samples of soot showed a relatively low (from 14 to 1200 ppm) benzo

  6. Canadian Oil Sands: Canada An Emerging Energy

    E-Print Network [OSTI]

    Boisvert, Jeff

    of the oil sands over the next 25 years. The use of the term "reserves" in the global context is really, royalty and regulatory regimes and the accuracy of the estimates of Canadian Oil Sands' reserves volumes1 Canadian Oil Sands: Canada ­ An Emerging Energy Superpower 0 University of Alberta February 8

  7. IMPROVING SANDSTONE MATRIX STIMULATION OF OIL

    E-Print Network [OSTI]

    Abu-Khamsin, Sidqi

    IMPROVING SANDSTONE MATRIX STIMULATION OF OIL WELLS BY GAS PRECONDITIONING M. A. Aggour, M. Al, Dhahran, Saudi Arabia ABSTRACT Experience has shown that for sandstone formations, oil wells respond to matrix acidizing in a different manner as compared to gas wells. For oil wells, the improvement

  8. IXTOC OIL SPILL ASSESSMENT FINAL REPORT

    E-Print Network [OSTI]

    Mathis, Wayne N.

    IXTOC OIL SPILL ASSESSMENT FINAL REPORT EXECUTIVE SUMMARY Prepared for : Bureau of Land Management in input of tar/oil to the Texas Gulf Coast (Geyer ;, 1981) have less of an obvious ecological impact, if any . The Brittany coast of France has been affected for several years by the acute oil input from

  9. OIL in a Nutshell I. Horrocksb

    E-Print Network [OSTI]

    van Harmelen, Frank

    OIL in a Nutshell D. Fensela I. Horrocksb F. van Harmelena,c S. Deckerd M. Erdmann e M. Kleina a VU) and is available at http://www.ontoknowledge.org/oil. Why we need a joint standard for describing ontologies. In this paper, we sketch a proposal for such a standard. It is called OIL, the Ontology Interchange Language

  10. Oil Price and the Dollar Virginie Coudert

    E-Print Network [OSTI]

    Boyer, Edmond

    Oil Price and the Dollar Virginie Coudert , Val´erie Mignon , Alexis Penot§ 6th April 2005 Abstract The aim of this paper is to test whether a stable long-term relationship exists between oil prices and causality study between the two variables. Our results indicate that causality runs from oil prices

  11. A Systems Approach to Managing Oil

    E-Print Network [OSTI]

    van Dorp, Johan René

    A Systems Approach to Managing Oil Transportation Risk in Prince William Sound Jason R. W. Merrick Received April 21, 2000; revised June 12, 2000; accepted June 26, 2000MANAGING OIL TRANSPORTATION RISK about the safety of oil transportation in the Prince William Sound, Alaska. As a result, a large number

  12. Enhanced oil recovery using hydrogen peroxide injection

    SciTech Connect (OSTI)

    Moss, J.T. Jr.; Moss, J.T.

    1995-02-01T23:59:59.000Z

    NOVATEC received an US Patent on a novel method to recovery viscous oil by hydrogen peroxide injection. The process appears to offer several significant improvements over existing thermal methods of oil recovery. Tejas joined NOVATEC to test the process in the laboratory and to develop oil field applications and procedures.

  13. Fish Oil Industry in South America

    E-Print Network [OSTI]

    Fish Oil Industry in South America UNITED STATES DEPARTMENT OF THE INTERIOR FISH AND WILDLIFE FISHERIES, H. E. Crowther, Director Fish Oil Industry in South America By -J. R. SANCHEZ TORRES Chief, "Fish Oils, " M. E. Stansby, editor, Avi Publishing Company, Westport, Connecticut, 1967. Circular 282

  14. What's Driving Oil Prices? James L. Smith

    E-Print Network [OSTI]

    O'Donnell, Tom

    Issues in Energy Federal Reserve Bank of Dallas November 2, 2006 The Price of OPEC Oil ($/bbl) $0 $20 $40;8 DIFFERENCES AMONG OPEC MEMBERS Proved Oil Crude Oil Reserves to GDP Reserves Production Production Ratio Member $ per capita bbl per capita bbl per capita years Algeria 3,113 373 15 25 Indonesia 1,290 20 2 11

  15. Oil Trading Simon Basey / November 28, 2013

    E-Print Network [OSTI]

    Sheldon, Nathan D.

    . A hurricane develops in the Gulf of Mexico and threatens to shut in crude production. d. New data indicatesOil Trading Simon Basey / November 28, 2013 #12;2 What does IST do? Imports crude oil and other Markets BP's equity crude oil, NGLs and natural gas Generates entrepreneurial trading income Manages BP

  16. Politics of oil and revolution in Iran

    SciTech Connect (OSTI)

    Bakhash, S.

    1982-01-01T23:59:59.000Z

    Elements of continuity and change in Iran's post-revolution oil strategy, the domestic forces that helped to shape oil policy, the regional repercussions of the Iranian revolution, and the manner in which the Iranian authorities have reacted to changes in the oil market over the past three and half years are examined.

  17. Oil shale technology and evironmental aspects

    SciTech Connect (OSTI)

    Scinta, J.

    1982-01-01T23:59:59.000Z

    Oil shale processes are a combination of mining, retorting, and upgrading facilities. This work outlines the processing steps and some design considerations required in an oil shale facility. A brief overview of above ground and in situ retorts is presented; 6 retorts are described. The development aspects which the oil shale industry is addressing to protect the environment are presented.

  18. Australian developments in oil shale processing

    SciTech Connect (OSTI)

    Baker, G.L.

    1981-01-01T23:59:59.000Z

    This study gives some background on Australian oil shale deposits, briefly records some history of oil shale processing in the country and looks at the current status of the various proposals being considered to produce syncrudes from Australian oil shales. 5 refs.

  19. Optimize carbon dioxide sequestration, enhance oil recovery

    E-Print Network [OSTI]

    - 1 - Optimize carbon dioxide sequestration, enhance oil recovery January 8, 2014 Los Alamos simulation to optimize carbon dioxide (CO2) sequestration and enhance oil recovery (CO2-EOR) based on known production. Due to carbon capture and storage technology advances, prolonged high oil prices

  20. Kuwait: World Oil Report 1991

    SciTech Connect (OSTI)

    Not Available

    1991-08-01T23:59:59.000Z

    This paper reports that the major event in Kuwait today is the ongoing effort to control blowouts stemming from Iraqi demolition of oil wells and producing facilities last February. A total of 732 wells---about two- thirds of all wells in Kuwait---were blown up. All but 80 caught on fire.