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1

Fischer-Tropsch Fuels  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Fischer-Tropsch Fuels Fischer-Tropsch Fuels Background The Fischer-Tropsch (F-T) reaction converts a mixture of hydrogen and carbon monoxide-derived from coal, methane or biomass-to liquid fuels. The Department of Energy (DOE) refers to the coal-based process as Coal-to-Liquids. The F-T process was discovered by German scientists and used to make fuels during World War II. There has been continued interest of varying intensity in F-T technology

2

Fischer-Tropsch process  

DOE Patents [OSTI]

A Fischer-Tropsch process utilizing a product selective and stable catalyst by which synthesis gas, particularly carbon-monoxide rich synthesis gas is selectively converted to higher hydrocarbons of relatively narrow carbon number range is disclosed. In general, the selective and notably stable catalyst, consist of an inert carrier first treated with a Group IV B metal compound (such as zirconium or titanium), preferably an alkoxide compound, and subsequently treated with an organic compound of a Fischer-Tropsch metal catalyst, such as cobalt, iron or ruthenium carbonyl. Reactions with air and water and calcination are specifically avoided in the catalyst preparation procedure.

Dyer, Paul N. (Allentown, PA); Pierantozzi, Ronald (Orefield, PA); Withers, Howard P. (Douglassville, PA)

1987-01-01T23:59:59.000Z

3

Biomass Derivatives Competitive with Heating Oil Costs.  

Broader source: Energy.gov [DOE]

Presentation at the May 9, 2012, Pyrolysis Oil Workship on biomass derivatives competitive with heating oil costs.

4

Biomass Derivatives Competitive with Heating Oil Costs.  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Biomass Derivatives Competitive with Heating Oil Costs Transportation fuel Heat or electricity * Data are from literature, except heating oil is adjusted from 2011 winter average *...

5

Catalysts for Fischer-Tropsch  

SciTech Connect (OSTI)

The slurry-phase Fischer-Tropsch (F-T) process has attracted considerable attention recently. The process can make liquid fuels by reacting hydrogen-lean synthesis gas produced from modern energy-efficient gasifiers. continuing assessment of Fischer-Tropsch Synthesis (FTS) has a high priority within an indirect liquefaction program, a part of the liquid fuels program sponsored by the U.S. Department of Energy (DOE) and executed by the Pittsburgh Energy Technology Center (PETC). Funding for the indirect liquefaction program in 1990:0090 is anticipated to be about $8.5 million compared to $6.6 million in 1989 and a like amount in the year before. The studies within the program are conducted by industry, universities, national laboratories and in-house PETC research and development. This article reviews preparation and properties of iron-based catalysts, including recent patent activities and in-depth process analysis of slurry-phase FTS. The review provides an analysis of Fischer-Tropsch catalyst research and development trends and describes options to increase selectivity for iron-based catalysts in a slurry phase.

Srivastava, R.D. (Burns and Roe Services Corp. (US)); Rao, V.U.S.; Cinquegrane, G.; Stiegel, G.J. (Pittsburgh Energy Technology Center, Pittsburgh, PA (US))

1990-02-01T23:59:59.000Z

6

Platinum-Modulated Cobalt Nanocatalysts for Low-Temperature Aqueous-Phase Fischer-Tropsch Synthesis  

E-Print Network [OSTI]

Fischer-Tropsch synthesis (FTS), which converts fossil fuel- based syngas to liquid fuel products over Ru as the source for the production of syngas, with the surging consumption of fossil fuels, FTS is once again catalytic process for liquid fuel generation, which converts coal/shale gas/biomass-derived syngas (a

Li, Weixue

7

Tailored fischer-tropsch synthesis product distribution  

DOE Patents [OSTI]

Novel methods of Fischer-Tropsch synthesis are described. It has been discovered that conducting the Fischer-Tropsch synthesis over a catalyst with a catalytically active surface layer of 35 microns or less results in a liquid hydrocarbon product with a high ratio of C.sub.5-C.sub.20:C.sub.20+. Descriptions of novel Fischer-Tropsch catalysts and reactors are also provided. Novel hydrocarbon compositions with a high ratio of C.sub.5-C.sub.20:C.sub.20+ are also described.

Wang, Yong (Richland, WA); Cao, Chunshe (Kennewick, WA); Li, Xiaohong Shari (Richland, WA); Elliott, Douglas C. (Richland, WA)

2012-06-19T23:59:59.000Z

8

Fischer-Tropsch Wastewater Utilization  

DOE Patents [OSTI]

The present invention is generally directed to handling the wastewater, or condensate, from a hydrocarbon synthesis reactor. More particularly, the present invention provides a process wherein the wastewater of a hydrocarbon synthesis reactor, such as a Fischer-Tropsch reactor, is sent to a gasifier and subsequently reacted with steam and oxygen at high temperatures and pressures so as to produce synthesis gas. The wastewater may also be recycled back to a slurry preparation stage, where solid combustible organic materials are pulverized and mixed with process water and the wastewater to form a slurry, after which the slurry fed to a gasifier where it is reacted with steam and oxygen at high temperatures and pressures so as to produce synthesis gas.

Shah, Lalit S. (Sugar Land, TX)

2003-03-18T23:59:59.000Z

9

Effect of surface modification by chelating agents on Fischer-Tropsch performance of Co/SiO2 catalysts  

SciTech Connect (OSTI)

The silica support of a Co-based catalyst for Fischer?Tropsch (FT) synthesis was modified by the chelating agents (CAs) nitrilotriacetic acid (NTA) and ethylenediaminetetraacetic acid (EDTA). After the modification, characterization of the fresh and spent catalysts shows reduced crystallite sizes, a better-dispersed Co3O4 phase on the calcined samples, and increased metal dispersions for the reduced samples. The CA-modified catalysts display higher CO conversions, product yields, reaction rates, and rate constants. The improved FT performance of CA-modified catalysts is attributed to the formation of stable complexes with Co. The superior performance of the EDTA-modified catalyst in comparison to the NTA-modified catalyst is due to the higher affinity of the former for complex formation with Co ions. 1. INTRODUCTION Fischer?Tropsch (FT) synthesis has been recognized as one of the most promising technologies for the conversion of coal, natural gas, and biomass-derived syngas into liquid fuels and chemicals.1 Limited oil reserves, energy supply security concerns, carbon credits,1 pollution abatement laws, and, most notably, uncertainty about fuel prices have increased the prospect of commercializing the FT process. Catalysts that are typically used for FT synthesis include supported Co or Fe. Cobased catalysts have the advantage of higher syngas conversion, more high-

Bambal, Ashish S. [WVU; Kyugler, Edwin L. [WVU; Gardner, Todd H. [U.S. DOE; Dadyburjor, Dady B. [WVU

2013-01-01T23:59:59.000Z

10

HEFA and Fischer-Tropsch Jet Fuel Cost Analyses | Department...  

Energy Savers [EERE]

HEFA and Fischer-Tropsch Jet Fuel Cost Analyses HEFA and Fischer-Tropsch Jet Fuel Cost Analyses This is a presentation from the November 27, 2012, Sustainable Alternative Fuels...

11

Opportunities for the Early Production of Fischer-Tropsch (F...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

for the Early Production of Fischer-Tropsch (F-T) Fuels in the U.S. -- An Overview Opportunities for the Early Production of Fischer-Tropsch (F-T) Fuels in the U.S. -- An Overview...

12

INTEGRATED FISCHER TROPSCH MODULAR PROCESS MODEL  

SciTech Connect (OSTI)

With declining petroleum reserves, increased world demand, and unstable politics in some of the world’s richest oil producing regions, the capability for the U.S. to produce synthetic liquid fuels from domestic resources is critical to national security and economic stability. Coal, biomass and other carbonaceous materials can be converted to liquid fuels using several conversion processes. The leading candidate for large-scale conversion of coal to liquid fuels is the Fischer Tropsch (FT) process. Process configuration, component selection, and performance are interrelated and dependent on feed characteristics. This paper outlines a flexible modular approach to model an integrated FT process that utilizes a library of key component models, supporting kinetic data and materials and transport properties allowing rapid development of custom integrated plant models. The modular construction will permit rapid assessment of alternative designs and feed stocks. The modeling approach consists of three thrust areas, or “strands” – model/module development, integration of the model elements into an end to end integrated system model, and utilization of the model for plant design. Strand 1, model/module development, entails identifying, developing, and assembling a library of codes, user blocks, and data for FT process unit operations for a custom feedstock and plant description. Strand 2, integration development, provides the framework for linking these component and subsystem models to form an integrated FT plant simulation. Strand 3, plant design, includes testing and validation of the comprehensive model and performing design evaluation analyses.

Donna Post Guillen; Richard Boardman; Anastasia M. Gribik; Rick A. Wood; Robert A. Carrington

2007-12-01T23:59:59.000Z

13

Novel Fischer-Tropsch catalysts  

DOE Patents [OSTI]

Novel polymer-supported metal complexes of the formula: PS --R Me(CO).sub.n H.sub.m where: PS represents a divinylbenzene crosslinked polystyrene in which the divinylbenzene crosslinking is greater than 1% and less than about 18%; R represents a cycloalkadienyl radical of 4 through 6 carbon atoms; Me represents a Group VIII metal; CO represents a carbonyl radical; H represents hydrogen; n represents an integer varying from 0 through 3; m represents an integer varying from 0 through 2 inclusively with the further provision that 2n+m must total 18 when added to the electrons in R and Me, or n+m must total 0; are prepared by: brominating PS --H by treating same with bromine in the presence of a thallium salt in a partially or fully halogenated solvent to form PS --Br; treating said PS --Br so produced with a lithium alkyl of 1 through 12 carbon atoms in an aromatic solvent to produce PS --Li; substituting said PS-- Li so produced by reaction with a 2-cycloalkenone of 4 to 6 carbon atoms in the presence of an ether solvent and using a water work-up to form a cycloalkenylalcohol-substituted PS ; dehydrating said alcohol so produced by heating under a vacuum to produce a cycloalkadienyl-substituted PS ; reacting the cycloalkadienyl-substituted PS with metal carbonyl in the presence of a partially or fully halogenated hydrocarbon, aromatic hydrocarbon of 6 through 8 carbon atoms, ethers, or esters of 4 through 10 carbon atoms as a solvent to produce a polystyrene-supported cycloalkadienyl metal carbonyl. The novel compounds are used as improved Fischer-Tropsch catalysts particularly for the conversion of CO+H.sub.2 to gaseous and liquid hydrocarbons at milder conditions than with prior catalysts.

Vollhardt, Kurt P. C. (Kensington, CA); Perkins, Patrick (Berkeley, CA)

1981-01-01T23:59:59.000Z

14

Novel Fischer-Tropsch catalysts  

DOE Patents [OSTI]

Novel polymer-supported metal complexes of the formula: PS --R Me(CO).sub.n H.sub.m where: PS represents a divinylbenzene crosslinked polystyrene in which the divinylbenzene crosslinking is greater than 1% and less than about 18%; R represents a cycloalkadienyl radical of 4 through 6 carbon atoms; Me represents a Group VIII metal; CO represents a carbonyl radical; H represents hydrogen; n represents an integer varying from 0 through 3; m represents an integer varying from 0 through 2 inclusively with the further provision that 2n+m must total 18 when added to the electrons in R and Me, or n+m must total 0; are prepared by: brominating PS --H by treating same with bromine in the presence of a thallium salt in a partially or fully halogenated solvent to form PS --Br; treating said PS --Br so produced with a lithium alkyl of 1 through 12 carbon atoms in an aromatic solvent to produce PS --Li; substituting said PS-- Li so produced by reaction with a 2-cycloalkenone of 4 to 6 carbon atoms in the presence of an ether solvent and using a water work-up to form a cycloalkenylalcohol-substituted PS ; dehydrating said alcohol so produced by heating under a vacuum to produce a cycloalkadienyl-substituted PS ; reacting the cycloalkadienyl-substituted PS with metal carbonyl in the presence of a partially or fully halogenated hydrocarbon, aromatic hydrocarbon of 6 through 8 carbon atoms, ethers, or esters of 4 through 10 carbon atoms as a solvent to produce a polystyrene-supported cycloalkadienyl metal carbonyl. The novel compounds are used as improved Fischer-Tropsch catalysts particularly for the conversion of CO+H.sub.2 to gaseous and liquid hydrocarbons at milder conditions than with prior catalysts.

Vollhardt, Kurt P. C. (Kensington, CA); Perkins, Patrick (Berkeley, CA)

1980-01-01T23:59:59.000Z

15

Novel Fischer-Tropsch catalysts  

DOE Patents [OSTI]

Novel polymer-supported metal complexes of the formula PS -R Me(CO).sub.n H.sub.m where: PS represents a divinylbenzene crosslinked polystyrene in which the divinylbenzene crosslinking is greater than 1% and less than about 18%; R represents a cycloalkadienyl radical of 4 through 6 carbon atoms; Me represents a Group VIII metal; CO represents a carbonyl radical; H represents hydrogen; n represents an integer varying from 0 through 3; m represents an integer varying from 0 through 2 inclusively with the further provision that 2n+m must total 18 when added to the electrons in R and Me, or n+m must total 0; are prepared by: brominating PS -H by treating same with bromine in the presence of a thallium salt in a partially or fully halogenated solvent to form PS -Br; treating said PS -Br so produced with a lithium alkyl of 1 through 12 carbon atoms in an aromatic solvent to produce PS -Li; substituting said PS - Li so produced by reaction with a 2-cycloalkenone of 4 to 6 carbon atoms in the presence of an ether solvent and using a water work-up to form a cycloalkenylalcohol-substituted PS ; dehydrating said alcohol so produced by heating under a vacuum to produce a cycloalkadienyl-substituted PS ; reacting the cycloalkadienyl-substituted PS with metal carbonyl in the presence of a partially or fully halogenated hydrocarbon, aromatic hydrocarbon of 6 through 8 carbon atoms, ethers, or esters of 4 through 10 carbon atoms as a solvent to produce a polystyrene-supported cycloalkadienyl metal carbonyl. The novel compounds are used as improved Fischer-Tropsch catalysts particularly for the conversion of CO+H.sub.2 to gaseous and liquid hydrocarbons at milder conditions than with prior catalysts.

Vollhardt, Kurt P. C. (Kensington, CA); Perkins, Patrick (Berkeley, CA)

1981-01-01T23:59:59.000Z

16

Novel Attrition-Resistant Fischer Tropsch Catalyst  

SciTech Connect (OSTI)

There is a strong national interest in the Fischer-Tropsch synthesis process because it offers the possibility of making liquid hydrocarbon fuels from reformed natural gas or coal and biomass gasification products. This project explored a new approach that had been developed to produce active, attrition-resistant Fischer-Tropsch catalysts that are based on glass-ceramic materials and technology. This novel approach represented a promising solution to the problem of reducing or eliminating catalyst attrition and maximizing catalytic activity, thus reducing costs. The technical objective of the Phase I work was to demonstrate that glass-ceramic based catalytic materials for Fischer-Tropsch synthesis have resistance to catalytic deactivation and reduction of particle size superior to traditional supported Fischer-Tropsch catalyst materials. Additionally, these novel glass-ceramic-based materials were expected to exhibit catalytic activity similar to the traditional materials. If successfully developed, the attrition-resistant Fischer-Tropsch catalyst materials would be expected to result in significant technical, economic, and social benefits for both producers and public consumers of Fischer-Tropsch products such as liquid fuels from coal or biomass gasification. This program demonstrated the anticipated high attrition resistance of the glass-ceramic materials. However, the observed catalytic activity of the materials was not sufficient to justify further development at this time. Additional testing documented that a lack of pore volume in the glass-ceramic materials limited the amount of surface area available for catalysis and consequently limited catalytic activity. However, previous work on glass-ceramic catalysts to promote other reactions demonstrated that commercial levels of activity can be achieved, at least for those reactions. Therefore, we recommend that glass-ceramic materials be considered again as potential Fischer-Tropsch catalysts if it can be demonstrated that materials with adequate pore volume can be produced. During the attrition resistance tests, it was learned that the glass-ceramic materials are very abrasive. Attention should be paid in any further developmental efforts to the potential for these hard, abrasive materials to damage reactors.

Weast, Logan, E.; Staats, William, R.

2009-05-01T23:59:59.000Z

17

Fuel and fuel blending components from biomass derived pyrolysis oil  

DOE Patents [OSTI]

A process for the conversion of biomass derived pyrolysis oil to liquid fuel components is presented. The process includes the production of diesel, aviation, and naphtha boiling point range fuels or fuel blending components by two-stage deoxygenation of the pyrolysis oil and separation of the products.

McCall, Michael J.; Brandvold, Timothy A.; Elliott, Douglas C.

2012-12-11T23:59:59.000Z

18

BASELINE DESIGN/ECONOMICS FOR ADVANCED FISCHER-TROPSCH TECHNOLOGY  

SciTech Connect (OSTI)

Bechtel, along with Amoco as the main subcontractor, developed a Baseline design, two alternative designs, and computer process simulation models for indirect coal liquefaction based on advanced Fischer-Tropsch (F-T) technology for the U. S. Department of Energy's (DOE's) Federal Energy Technology Center (FETC).

None

1998-04-01T23:59:59.000Z

19

Separation of catalyst from Fischer-Tropsch slurry  

SciTech Connect (OSTI)

This paper describes a process for the separation of catalysts used in Fischer-Tropsch synthesis. The separation is accomplished by extraction in which the organic compounds in the wax are dissolved and carried away from the insoluble inorganic catalyst particles that are primarily inorganic. The purified catalyst can be upgraded by various methods.

White, C.M.; Quiring, M.S.; Jensen, K.L.; Hickey, R.F.; Gillham, L.D.

1998-04-01T23:59:59.000Z

20

Toward a More Comprehensive Greenhouse Gas Emissions Assessment of Biofuels: The Case of Forest-Based Fischer–Tropsch Diesel Production in Finland  

Science Journals Connector (OSTI)

Technology and feedstock production chain-specific factors, market-mediated factors and climate policy time frame issues are reflected using as a case study Fischer–Tropsch diesel derived from boreal forest biomass in Finland. ... Hochman, G.; Rajagopal, D.; Zilberman, D.The effect of biofuels on crude oil markets AgBioForum 2010, 13 ( 2) 112– 118 ...

Sampo Soimakallio

2014-02-04T23:59:59.000Z

Note: This page contains sample records for the topic "oils biomass-derived fischer-tropsch" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Migration of potassium in an iron-based Fischer-Tropsch/zeolite composite catalyst.  

E-Print Network [OSTI]

??Includes abstract. The product of the Fischer-Tropsch synthesis is low in aromatics and as a result has relatively poor gasoline quality (with respect to the… (more)

Gwagwa, Xoliswa Yolanda.

2008-01-01T23:59:59.000Z

22

On-Road Use of Fischer-Tropsch Diesel Blends  

SciTech Connect (OSTI)

Alternative compression ignition engine fuels are of interest both to reduce emissions and to reduce U.S. petroleum fuel demand. A Malaysian Fischer-Tropsch gas-to-liquid fuel was compared with California No.2 diesel by characterizing emissions from over the road Class 8 tractors with Caterpillar 3176 engines, using a chassis dynamometer and full scale dilution tunnel. The 5-Mile route was employed as the test schedule, with a test weight of 42,000 lb. Levels of oxides of nitrogen (NO{sub x}) were reduced by an average of 12% and particulate matter (PM) by 25% for the Fischer-Tropsch fuel over the California diesel fuel. Another distillate fuel produced catalytically from Fischer-Tropsch products originally derived from natural gas by Mossgas was also compared with 49-state No.2 diesel by characterizing emissions from Detroit Diesel 6V-92 powered transit buses, three of them equipped with catalytic converters and rebuilt engines, and three without. The CBD cycle was employed as the test schedule, with a test weight of 33,050 lb. For those buses with catalytic converters and rebuilt engines, NO x was reduced by 8% and PM was reduced by 31% on average, while for those buses without, NO x was reduced by 5% and PM was reduced by 20% on average. It is concluded that advanced compression ignition fuels from non-petroleum sources can offer environmental advantages in typical line haul and city transit applications.

Nigel Clark; Mridul Gautam; Donald Lyons; Chris Atkinson; Wenwei Xie; Paul Norton; Keith Vertin; Stephen Goguen; James Eberhardt

1999-04-26T23:59:59.000Z

23

ATTACHMENT IX Review of Air Products Fischer-Tropsch Synthesis Work  

E-Print Network [OSTI]

IX.1-Draft ATTACHMENT IX Review of Air Products Fischer-Tropsch Synthesis Work During the 1980s, Air Products & Chemicals worked on several aspects of the Fischer-Tropsch synthesis. These included, exhibited similar activity and product selectivity, showing that the preparative method was reproducible

Kentucky, University of

24

Monetization of Nigeria coal by conversion to hydrocarbon fuels through Fischer-Tropsch process  

SciTech Connect (OSTI)

Given the instability of crude oil prices and the disruptions in crude oil supply chains, this article offers a complementing investment proposal through diversification of Nigeria's energy source and dependence. Therefore, the following issues were examined and reported: A comparative survey of coal and hydrocarbon reserve bases in Nigeria was undertaken and presented. An excursion into the economic, environmental, and technological justifications for the proposed diversification and roll-back to coal-based resource was also undertaken and presented. The technology available for coal beneficiation for environmental pollution control was reviewed and reported. The Fischer-Tropsch synthesis and its advances into Sasol's slurry phase distillate process were reviewed. Specifically, the adoption of Sasol's advanced synthol process and the slurry phase distillate process were recommended as ways of processing the products of coal gasification. The article concludes by discussing all the above-mentioned issues with regard to value addition as a means of wealth creation and investment.

Oguejiofor, G.C. [Nnamdi Azikiwe University, Awka (Nigeria). Dept. of Chemical Engineering

2008-07-01T23:59:59.000Z

25

Separation of Fischer-Tropsch from Catalyst by Supercritical Extraction.  

SciTech Connect (OSTI)

The objective of this research project is to evaluate the potential of supercritical fluid (SCF) extraction for the recovery and fractionation of the wax product from the slurry bubble column (SBC) reactor of the Fischer-Tropsch (F-T) process. The wax, comprised mostly of branched and linear alkanes with a broad molecular weight distribution up to C{sub 100}, will be extracted with a hydrocarbon solvent that has a critical temperature near the operating temperature of the SBC reactor, i.e., 200-300{degrees}C. Initial work is being performed using n-hexane as the solvent.

Joyce, P.C.; Thies, M.C.

1997-10-31T23:59:59.000Z

26

Fischer-Tropsch synthesis over iron-rhodium alloy catalysts  

SciTech Connect (OSTI)

To investigate the nature of iron-rhodium alloy catalysts during the Fischer-Tropsch synthesis, a combination of experimental techniques were applied. Infrared spectroscopy was mainly used to extract direct information on the surface of catalysts under the reaction conditions. In addition, Mossbauer spectroscopy was employed to study the iron alloy catalysts. Further characterization of the catalysts was performed by chemisorption measurements. Hydrocarbon products of the CO + H/sub 2/ synthesis reaction were analyzed by gas chromatography. The working surface of a silica-supported rhodium catalyst was found to be saturated with molecular carbon monoxide. The intensity of the linear carbonyl absorption band remained constant compared to that for room temperature CO adsorption, while that of the bridge-bonded carbonyl absorption band was drastically reduced during the Fischer-Tropsch synthesis. The bridge-bonded adsorption sites are assumed to be the active sites for dissociating carbon monoxide. The hydrogenation rate of the linearly adsorbed carbon monoxide was much slower than the steady state reaction rate. The alloy catalyst did not form a bulk carbide, but the presence of surface carbon was suggested by the large shift of the linear carbonyl absorption band. On the other hand, infrared spectra on an iron catalyst showed only weak bands, indicating a high degree of CO dissociation. On a silica-supported iron-rhodium alloy catalyst, surface analysis by infrared spectroscopy presents evidence of well-mixed alloy formation. Three models of carbon monoxide adsorption were identified.

Choi, S.

1983-01-01T23:59:59.000Z

27

Chapter 13 - Substitute Natural Gas and Fischer-Tropsch Synthesis  

Science Journals Connector (OSTI)

Publisher Summary This chapter presents the direct conversion of syngas to hydrocarbons, either substitute natural gas, or higher hydrocarbons via the Fischer–Tropsch synthesis. Substitute natural gas (SNG), also known as synthetic natural gas, is methane that is formed during gasification. The syngas generally contain carbon dioxide that can be hydrogenated to produce methane. Fischer–Tropsch (FT) synthesis is a polymerization reaction. An alkane chain, absorbed on a catalyst site, reacts with carbon monoxide and hydrogen to add a methyl unit (CH2). The heat of reaction per methyl group, estimated from the gas phase heat of formation for dodecane, is –155.5 kJ/mole. This heat of reaction is about 20% of the heat of combustion of the feed gases. FT diesel fuel, due to its high alkane content, has very high cetane numbers. Blends of FT and conventional diesel are sold as premium products in Europe. Normal alkanes, however, have high melting points compared to branched or cyclic hydrocarbons. An FT diesel produced simply by distilling an FT fluid would have poor low temperature properties. Most FT diesel, however, is not simply an FT fluid distillation product, but a blend of this distillation product and products of hydrocracked FT wax.

David A Bell; Brian F Towler; Maohong Fan

2011-01-01T23:59:59.000Z

28

Supported fischer-tropsch catalyst and method of making the catalyst  

SciTech Connect (OSTI)

A Fischer-Tropsch catalyst and a method of making the catalyst for a Fischer-Tropsch process utilizing the catalyst by which synthesis gas, particularly carbon-monoxide rich synthesis gas, is selectively converted to higher hydrocarbons of relatively narrow carbon number range is disclosed. In general, the selective and notably stable catalyst, consist of an inert carrier first treated with a Group IV B metal compound (such as zirconium or titanium), preferably an alkoxide compound, and subsequently treated with an organic compound of a Fischer-Tropsch metal catalyst, such as cobalt, iron or ruthenium carbonyl. Reactions with air and water and calcination are specifically avoided in the catalyst preparation procedure.

Dyer, Paul N. (Allentown, PA); Pierantozzi, Ronald (Orefield, PA); Withers, Howard P. (Douglassville, PA)

1987-01-01T23:59:59.000Z

29

Spray drying and attrition behavior of iron catalysts for slurry phase Fischer-Tropsch synthesis  

E-Print Network [OSTI]

This thesis describes results of a study aimed at developing and evaluating attrition resistant iron catalysts prepared by spray drying technique. These catalysts are intended for Fischer-Tropsch (F-T) synthesis in a slurry bubble column reactor...

Carreto Vazquez, Victor Hugo

2004-11-15T23:59:59.000Z

30

ATTRITION RESISTANT IRON-BASED FISCHER-TROPSCH CATALYSTS  

SciTech Connect (OSTI)

Fischer-Tropsch (FT) synthesis to convert syngas (CO + H{sub 2}) derived from natural gas or coal to liquid fuels and wax is a well-established technology. For low H{sub 2} to CO ratio syngas produced from CO{sub 2} reforming of natural gas or from gasification of coal, the use of Fe catalysts is attractive because of their high water gas shift activity in addition to their high FT activity. Fe catalysts are also attractive due to their low cost and low methane selectivity. Because of the highly exothermic nature of the FT reaction, there has been a recent move away from fixed-bed reactors toward the development of slurry bubble column reactors (SBCRs) that employ 30 to 90 {micro}m catalyst particles suspended in a waxy liquid for efficient heat removal. However, the use of FeFT catalysts in an SBCR has been problematic due to severe catalyst attrition resulting in fines that plug the filter employed to separate the catalyst from the waxy product. Fe catalysts can undergo attrition in SBCRs not only due to vigorous movement and collisions but also due to phase changes that occur during activation and reaction.

K. Jothimurugesan; James G. Goodwin, Jr.; Santosh K. Gangwal

1999-10-01T23:59:59.000Z

31

Improved Fischer-Tropsch catalysts for indirect coal liquefaction  

SciTech Connect (OSTI)

The Fischer-Tropsch synthesis (FTS)reaction is the established technology for the production of liquid fuels from coal by an indirect route using coal-derived syngas (CO + H{sub 2}). Modern FTS catalysts are potassium- and copper-promoted iron preparations. These catalysts exhibit moderate activity with carbon monoxide-rich feedstocks such as the syngas produced by advanced coal gasification processes. However, the relatively large yields of by-product methane and high-molecular-weight hydrocarbon waxes detract from the production of desired liquid products in the C{sub 5}-C{sub 16} range needed for motor and aviation fuel. The goal of this program is to decrease undesirable portions of the FTS hydrocarbon yield by altering the Schultz-Flory polymerization product distribution through design and formulation of improved catalysts. Two approaches were taken: (1) reducing the yield of high-molecular-weight hydrocarbon waxes by using highly dispersed catalysts produced from surface-confined multiatomic clusters on acid supports and (2) suppressing methane production by uniformly pretreating active, selective conventional FTS catalysts with submonolayer levels of sulfur.

Wilson, R.B. Jr.; Tong, G.T.; Chan, Y.W.; Huang, H.W.; McCarty, J.G.

1989-02-01T23:59:59.000Z

32

Low oxygen biomass-derived pyrolysis oils and methods for producing the same  

DOE Patents [OSTI]

Low oxygen biomass-derived pyrolysis oils and methods for producing them from carbonaceous biomass feedstock are provided. The carbonaceous biomass feedstock is pyrolyzed in the presence of a catalyst comprising base metal-based catalysts, noble metal-based catalysts, treated zeolitic catalysts, or combinations thereof to produce pyrolysis gases. During pyrolysis, the catalyst catalyzes a deoxygenation reaction whereby at least a portion of the oxygenated hydrocarbons in the pyrolysis gases are converted into hydrocarbons. The oxygen is removed as carbon oxides and water. A condensable portion (the vapors) of the pyrolysis gases is condensed to low oxygen biomass-derived pyrolysis oil.

Marinangeli, Richard; Brandvold, Timothy A; Kocal, Joseph A

2013-08-27T23:59:59.000Z

33

Attrition resistant catalysts for slurry-phase Fischer-Tropsch process  

SciTech Connect (OSTI)

The Fischer-Tropsch (F-T) reaction provides a way of converting coal-derived synthesis gas (CO+H{sub 2}) to liquid fuels. Since the reaction is highly exothermic, one of the major problems in control of the reaction is heat removal. Recent work has shown that the use of slurry bubble column reactors (SBCRs) can largely solve this problem. Iron-based (Fe) catalysts are preferred catalysts for F-T because they are relatively inexpensive and possess reasonable activity for F-T synthesis (FTS). Their most advantages trait is their high water-gas shift (WGS) activity compared to their competitor, namely cobalt. This enables Fe F-T catalysts to process low H{sub 2}/CO ratio synthesis gas without an external shift reaction step. However, a serious problem with the use of Fe catalysts in a SBCR is their tendency to undergo attrition. This can cause fouling/plugging of downstream filters and equipment, make the separation of catalyst from the oil/wax product very difficult if not impossible, an d result in a steady loss of catalyst from the reactor. The objectives of this research were to develop a better understanding of the parameters affecting attrition of Fe F-T catalysts suitable for use in SBCRs and to incorporate this understanding into the design of novel Fe catalysts having superior attrition resistance.

K. Jothimurugesan

1999-11-01T23:59:59.000Z

34

The selective catalytic cracking of Fischer-Tropsch liquids to high value transportation fuels. Final report  

SciTech Connect (OSTI)

Amoco Oil Company, investigated a selective catalytic cracking process (FCC) to convert the Fischer-Tropsch (F-T) gasoline and wax fractions to high value transportation fuels. The primary tasks of this contract were to (1) optimize the catalyst and process conditions of the FCC process for maximum conversion of F-T wax into reactive olefins for later production of C{sub 4}{minus}C{sub 8} ethers, and (2) use the olefin-containing light naphtha obtained from FCC processing of the F-T wax as feedstock for the synthesis of ethers. The catalytic cracking of F-T wax feedstocks gave high conversions with low activity catalysts and low process severities. HZSM-5 and beta zeolite catalysts gave higher yields of propylene, isobutylene, and isoamylenes but a lower gasoline yield than Y zeolite catalysts. Catalyst selection and process optimization will depend on product valuation. For a given catalyst and process condition, Sasol and LaPorte waxes gave similar conversions and product selectivities. The contaminant iron F-T catalyst fines in the LaPorte wax caused higher coke and hydrogen yields.

Schwartz, M.M.; Reagon, W.J.; Nicholas, J.J.; Hughes, R.D.

1994-11-01T23:59:59.000Z

35

Potential for Coal-to-Liquids Conversion in the United States-Fischer-Tropsch Synthesis  

SciTech Connect (OSTI)

The United States has the world's largest coal reserves and Montana the highest potential for mega-mine development. Consequently, a large-scale effort to convert coal to liquids (CTL) has been proposed to create a major source of domestic transportation fuels from coal, and some prominent Montanans want to be at the center of that effort. We calculate that the energy efficiency of the best existing Fischer-Tropsch (FT) process applied to average coal in Montana is less than 1/2 of the corresponding efficiency of an average crude oil refining process. The resulting CO{sub 2} emissions are 20 times (2000%) higher for CTL than for conventional petroleum products. One barrel of the FT fuel requires roughly 800 kg of coal and 800 kg of water. The minimum energy cost of subsurface CO{sub 2} sequestration would be at least 40% of the FT fuel energy, essentially halving energy efficiency of the process. We argue therefore that CTL conversion is not the most valuable use for the coal, nor will it ever be, as long as it is economical to use natural gas for electric power generation. This finding results from the low efficiency inherent in FT synthesis, and is independent of the monumental FT plant construction costs, mine construction costs, acute lack of water, and the associated environmental impacts for Montana.

Patzek, Tad W. [University of Texas, Department of Petroleum and Geosystems Engineering (United States)], E-mail: patzek@mail.utexas.edu; Croft, Gregory D. [University of California, Department of Civil and Environmental Engineering (United States)

2009-09-15T23:59:59.000Z

36

EA-1642: Design and Construction of an Early Lead Mini Fischer-Tropsch  

Broader source: Energy.gov (indexed) [DOE]

42: Design and Construction of an Early Lead Mini 42: Design and Construction of an Early Lead Mini Fischer-Tropsch Refinery at the University of Kentucky Center for Applied Energy Research Near Lexington, Kentucky EA-1642: Design and Construction of an Early Lead Mini Fischer-Tropsch Refinery at the University of Kentucky Center for Applied Energy Research Near Lexington, Kentucky SUMMARY DOE's National Energy Technology Laboratory prepared this environmental assessment to analyze the potential environmental impacts of providing funding for the proposed Early Lead Mini Fischer-Tropsch Refinery. The early lead facility would be located at the University of Kentucky Center for Applied Energy Research in Fayette County Kentucky. PUBLIC COMMENT OPPORTUNITIES None available at this time. DOCUMENTS AVAILABLE FOR DOWNLOAD

37

FISCHER-TROPSCH FUELS PRODUCTION AND DEMONSTRATION PROJECT  

SciTech Connect (OSTI)

This project has two primary purposes: (1) Build a small-footprint (SFP) fuel production plant to prove the feasibility of this relatively transportable technology on an intermediate scale (i.e. between laboratory-bench and commercial capacity) and produce as much as 150,000 gallons of hydrogen-saturated Fischer-Tropsch (FT) diesel fuel; and (2) Use the virtually sulfur-free fuel produced to demonstrate (over a period of at least six months) that it can not only be used in existing diesel engines, but that it also can enable significantly increased effectiveness and life of the next-generation exhaust-after-treatment emission control systems that are currently under development and that will be required for future diesel engines. Furthermore, a well-to-wheels economic analysis will be performed to characterize the overall costs and benefits that would be associated with the actual commercial production, distribution and use of such FT diesel fuel made by the process under consideration, from the currently underutilized (or entirely un-used) energy resources targeted, primarily natural gas that is stranded, sub-quality, off-shore, etc. During the first year of the project, which is the subject of this report, there have been two significant areas of progress: (1) Most of the preparatory work required to build the SFP fuel-production plant has been completed, and (2) Relationships have been established, and necessary project coordination has been started, with the half dozen project-partner organizations that will have a role in the fuel demonstration and evaluation phase of the project. Additional project tasks directly related to the State of Alaska have also been added to the project. These include: A study of underutilized potential Alaska energy resources that could contribute to domestic diesel and distillate fuel production by providing input energy for future commercial-size SFP fuel production plants; Demonstration of the use of the product fuel in a heavy-duty diesel vehicle during the Alaska winter; a comparative study of the cold-starting characteristics of FT and conventional diesel fuel; and demonstration of the use of the fuel to generate electricity for rural Alaskan villages using both a diesel generator set, and a reformer-equipped fuel cell.

Stephen P. Bergin

2003-04-23T23:59:59.000Z

38

Combined Steam Reforming of Methane and Fischer–Tropsch Synthesis for the Formation of Hydrocarbons: A Proof of Concept Study  

Science Journals Connector (OSTI)

The concept of combining the reactions of methane steam reforming and the Fischer–Tropsch synthesis is explored in an attempt to convert methane directly to hydrocarbons. Consideration of the thermodynamics ... c...

Meleri Johns; Paul Collier; Michael S. Spencer; Tony Alderson…

2003-10-01T23:59:59.000Z

39

The Impact of Biomass Pretreatment on the Feasibility of Overseas Biomass Conversion to Fischer?Tropsch Products  

Science Journals Connector (OSTI)

The Impact of Biomass Pretreatment on the Feasibility of Overseas Biomass Conversion to Fischer?Tropsch Products ... One of the most promising options to produce transportation fuels from biomass is the so-called biomass-to-liquids (BtL) route, in which biomass is converted to syngas from which high-quality Fischer?Tropsch (FT) fuels are synthesized. ... Alternatively to converting biomass into liquids or coal-like material, new and dedicated feeding systems for biomass can be developed. ...

Robin W. R. Zwart; Harold Boerrigter; Abraham van der Drift

2006-08-29T23:59:59.000Z

40

Fischer Tropsch synthesis in supercritical fluids. Quarterly technical progress report, October 1, 1993--December 31, 1993  

SciTech Connect (OSTI)

Objectives for the first quarter for Task A, Diffusion Coefficients of F-T Products in Supercritical Fluids, were to measure diffusion coefficients of 1-tetradecene in subcritical propane and the diffusion coefficients of 1-octene and 1-tetradecene in subcritical propane and the diffusion coefficients of 1-octene and 1-tetradecene in subcritical and supercritical ethane. We planned to use ethane as a solvent because its lower critical temperature enabled measurements without modification of the existing unit. Our objective was to investigate the behavior of the diffusion coefficients in crossing from subcritical to supercritical conditions. Objectives for Task B, Fischer Tropsch reaction related studies, were: (1) to install and test the temperature probe and the flammable gas detector: (2) to conduct Fischer-Tropsch experiments at baseline conditions and at a high pressure in order to test the newly constructed fixed bed reactor assembly. Accomplishments and problems, are presented.

Akgerman, A.; Bukur, D.B.

1993-12-31T23:59:59.000Z

Note: This page contains sample records for the topic "oils biomass-derived fischer-tropsch" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Slurry phase Fischer-Tropsch synthesis: Cobalt plus a water-gas shift catalyst  

SciTech Connect (OSTI)

This report details experiments performed on three different copper-based catalysts: Cu/Cr[sub 2]O[sub 3], Cu/MnO/Cr[sub 2]O[sub 3] and Cu/ZnO/Al[sub 2]O[sub 3]. Of these three catalysts, the Cu/ZnO/Al[sub 2]O[sub 3] exhibits the greatest stability when slurried in octacosane. More than 1000 hours-on-stream indicate that the catalyst activity is not detrimentally affected by high pressure, high H[sub 2]/CO ratio, or the presence of alkenes. All of these are necessary stability characteristics for the water-gas shift catalyst, if it is to be used in combination with a cobalt Fischer-Tropsch catalyst. A review of documented reduction procedures for cobalt-based Fischer-Tropsch catalysts is presented.

Yates, I.C.; Satterfield, C.N.

1988-01-01T23:59:59.000Z

42

Development and process evaluation of improved Fischer-Tropsch slurry catalysts. Final report  

SciTech Connect (OSTI)

This report describes results of a study aimed at developing and evaluating improved catalysts for a slurry Fischer-Tropsch (FT) process for converting synthesis gas to high quality transportation fuels (gasoline and distillate). The improvements in catalyst performance were sought by studying effects of pretreatment conditions, promoters and binders/supports. A total of 20 different, iron based, catalysts were evaluated in 58 fixed bed reactor tests and 10 slurry reactor tests. The major accomplishments and conclusions are summarized below. The pretreatment conditions (temperature, duration and the nature of reducing gas) have significant effect on catalyst performance (activity, selectivity and stability) during Fischer-Tropsch synthesis. One of precipitated unsupported catalysts had hydrocarbon selectivity similar to Mobil`s I-B catalyst in high wax mode operation, and had not experienced any loss in activity during 460 hours of testing under variable process conditions in a slurry reactor. The effect of promoters (copper and potassium) on catalyst performance during FT synthesis has been studied in a systematic way. It was found that potassium promotion increases activities of the FT and water-gas-shift (WGS) reactions, the average molecular weight of hydrocarbon products, and suppresses the olefin hydrogenation and isomerization reactions. The addition of binders/supports (silica or alumina) to precipitated Fe/Cu/K catalysts, decreased their activity but improved their stability and hydrocarbon selectivity. The performance of catalysts of this type was very promising and additional studies are recommended to evaluate their potential for use in commercial slurry reactors.

Bukur, D.B.; Mukesh, D.; Patel, S.A.; Zimmerman, W.H.; Rosynek, M.P. [Texas A& M Univ., College Station, TX (United States); Kellogg, L.J. [Air Products and Chemicals, Inc., Allentown, PA (United States)

1990-04-01T23:59:59.000Z

43

Ultra-clean Fischer-Tropsch (F-T) Fuels Production and Demonstration Project  

SciTech Connect (OSTI)

The objective of the DOE-NETL Fischer-Tropsch (F-T) Production and Demonstration Program was to produce and evaluate F-T fuel derived from domestic natural gas. The project had two primary phases: (1) fuel production of ultra-clean diesel transportation fuels from domestic fossil resources; and (2) demonstration and performance testing of these fuels in engines. The project also included a well-to-wheels economic analysis and a feasibility study of small-footprint F-T plants (SFPs) for remote locations such as rural Alaska. During the fuel production phase, ICRC partnered and cost-shared with Syntroleum Corporation to complete the mechanical design, construction, and operation of a modular SFP that converts natural gas, via F-T and hydro-processing reactions, into hydrogensaturated diesel fuel. Construction of the Tulsa, Oklahoma plant started in August 2002 and culminated in the production of over 100,000 gallons of F-T diesel fuel (S-2) through 2004, specifically for this project. That fuel formed the basis of extensive demonstrations and evaluations that followed. The ultra-clean F-T fuels produced had virtually no sulfur (less than 1 ppm) and were of the highest quality in terms of ignition quality, saturation content, backend volatility, etc. Lubricity concerns were investigated to verify that commercially available lubricity additive treatment would be adequate to protect fuel injection system components. In the fuel demonstration and testing phase, two separate bus fleets were utilized. The Washington DC Metropolitan Area Transit Authority (WMATA) and Denali National Park bus fleets were used because they represented nearly opposite ends of several spectra, including: climate, topography, engine load factor, mean distance between stops, and composition of normally used conventional diesel fuel. Fuel evaluations in addition to bus fleet demonstrations included: bus fleet emission measurements; F-T fuel cold weather performance; controlled engine dynamometer lab evaluation; cold-start test-cell evaluations; overall feasibility, economics, and efficiency of SFP fuel production; and an economic analysis. Two unexpected issues that arose during the project were further studied and resolved: variations in NOx emissions were accounted for and fuel-injection nozzle fouling issues were traced to the non-combustible (ash) content of the engine oil, not the F-T fuel. The F-T fuel domestically produced and evaluated in this effort appears to be a good replacement candidate for petroleum-based transportation fuels. However, in order for domestic F-T fuels to become a viable cost-comparable alternative to petroleum fuels, the F-T fuels will need to be produced from abundant U.S. domestic resources such as coal and biomass, rather than stranded natural gas.

Stephen P. Bergin

2006-06-30T23:59:59.000Z

44

Fischer-Tropsch Synthesis: Characterization and Reaction Testing of Cobalt Carbide  

SciTech Connect (OSTI)

Hydrogenation of carbon monoxide was investigated for cobalt carbide synthesized from Co{sub 3}O{sub 4} by CO carburization in a fixed-bed reactor. The cobalt carbide synthesized was characterized by BET surface area, X-ray diffraction, scanning electron microscopy, X-ray absorption near edge spectroscopy, and extended X-ray absorption fine structure spectroscopy. The catalysts were tested in the slurry phase using a continuously stirred tank reactor at P = 2.0 MPa, H{sub 2}/CO = 2:1 in the temperature range of 493-523 K, and with space velocities varying from 1 to 3 Nl h{sup -1} g{sub cat}{sup -1}. The results strongly suggest that a fraction of cobalt converts to a form with greater metallic character under the conditions employed. This was more pronounced on a Fischer-Tropsch synthesis run conducted at a higher temperature (523 versus 493 K).

Khalid S.; Mohandas J.C.; Gnanamani M.K.; Jacobs G.; Ma W.; Ji Y.; Davis B.H.

2011-08-15T23:59:59.000Z

45

Separation of Fischer-Tropsch Wax from Catalyst by Supercritical Extraction  

SciTech Connect (OSTI)

The proposed process of using supercritical fluid extraction in conjunction with the Fischer-Tropsch slurry bubble column reactor has been examined using the ASPEN Plus simulator by the research group at North Carolina State University. Qualitative results have been obtained for varying the following process parameters: solvent-to-wax ratio, solvent type (pentane or hexane), extraction temperature and pressure, and recovery unit temperature and pressure. The region of retrograde behavior was determined for pentane and hexane. Initial results show hexane to be the superior solvent; compared to pentane, hexane requires lower quantities of solvent makeup (the amount of solvent which needs to be added to account for solvent that cannot be recycled), and also results in a lower average molecular weight of slurry in the reactor. Studies indicate that increasing the extraction temperature, extraction pressure, recovery temperature, or solvent to wax ratio decreases the amount solvent makeup required. Decreasing the recovery pressure was found to decrease the makeup flowrate.

Joyce, P.C.; Thies, M.C.

1997-01-31T23:59:59.000Z

46

Separation of Fischer-Tropsch wax from catalyst by supercritical fluid extraction. Technical progress report, October--December 1994  

SciTech Connect (OSTI)

Goal is to evaluate the potential of supercritical fluid extraction for separating the catalyst slurry of a Fischer-Tropsch slurry bubble column reactor into two fractions: a catalyst-free wax containing <10 ppM solids and a concentrated catalyst slurry ready for recycle/regeneration. Efforts focused on programming and testing of the SAFT equation and automation of the continuous-flow apparatus.

Thies, M.C.

1994-12-31T23:59:59.000Z

47

Kinetic studies for elucidation of the promoter effect of alkali in Fischer-Tropsch iron catalysts  

SciTech Connect (OSTI)

The kinetics of the formation of hydrocarbons in Fischer-Tropsch synthesis and of consecutive reactions, i.e., hydrogenation and double bond isomerization of primarily formed 1-alkenes, were studied in a slurry-phase reactor using alkalized and nonalkalized precipitated iron catalysts. Both consecutive reactions have an order of about -2 with respect to carbon monoxide and an order of about 1 with respect to 1-alkenes. The order with respect to hydrogen is 1 for the hydrocarbon formation and also 1 for the consecutive hydrogenation, but 0 for the consecutive isomerization. The reaction orders are not changed by addition of K{sub 2}CO{sub 3} to the catalyst. The kinetics of consecutive reactions can be interpreted by competitive adsorption of 1-alkene and carbon monoxide. Alkali addition causes an increase in the strength of carbon monoxide adsorption and consequently a decrease in 1-alkene adsorption so that the rates of the consecutive reactions are reduced. This hypothesis could be proved by studies of 1-hexene hydrogenation in the presence and absence of carbon monoxide for alkalized and nonalkalized iron catalysts. The kinetics were studied in the ranges 1.3 < P{sub CO}(10{sup 5} Pa) < 7, 1.6 < P{sub H{sub 2}}(10{sup 5} Pa) < 9, and 490 K < T < 530 K.

Herzog, K.; Gaube, J. (Institut fuer Chemische Technologie der Technischen Hochschule Darmstadt, Darmstadt (West Germany))

1989-02-01T23:59:59.000Z

48

Incorporation of catalytic dehydrogenation into Fischer-Tropsch synthesis to lower carbon dioxide emissions  

DOE Patents [OSTI]

A method for producing liquid fuels includes the steps of gasifying a starting material selected from a group consisting of coal, biomass, carbon nanotubes and mixtures thereof to produce a syngas, subjecting that syngas to Fischer-Tropsch synthesis (FTS) to produce a hyrdrocarbon product stream, separating that hydrocarbon product stream into C1-C4 hydrocarbons and C5+ hydrocarbons to be used as liquid fuels and subjecting the C1-C4 hydrocarbons to catalytic dehydrogenation (CDH) to produce hydrogen and carbon nanotubes. The hydrogen produced by CDH is recycled to be mixed with the syngas incident to the FTS reactor in order to raise the hydrogen to carbon monoxide ratio of the syngas to values of 2 or higher, which is required to produce liquid hydrocarbon fuels. This is accomplished with little or no production of carbon dioxide, a greenhouse gas. The carbon is captured in the form of a potentially valuable by-product, multi-walled carbon nanotubes (MWNT), while huge emissions of carbon dioxide are avoided and very large quantities of water employed for the water-gas shift in traditional FTS systems are saved.

Huffman, Gerald P

2012-09-18T23:59:59.000Z

49

ULTRA-CLEAN FISCHER-TROPSCH FUELS PRODUCTION AND DEMONSTRATION PROJECT  

SciTech Connect (OSTI)

The Syntroleum plant is mechanically complete and currently undergoing start-up. The fuel production and demonstration plan is near completion. The study on the impact of small footprint plant (SFP) fuel on engine performance is about half-completed. Cold start testing has been completed. Preparations have been completed for testing the fuel in diesel electric generators in Alaska. Preparations are in progress for testing the fuel in bus fleets at Denali National Park and the Washington Metropolitan Transit Authority. The experiments and analyses conducted during this project show that Fischer-Tropsch (FT) gas-to-liquid diesel fuel can easily be used in a diesel engine with little to no modifications. Additionally, based on the results and discussion presented, further improvements in performance and emissions can be realized by configuring the engine to take advantage of FT diesel fuel's properties. The FT fuel also shows excellent cold start properties and enabled the engine tested to start at more the ten degrees than traditional fuels would allow. This plant produced through this project will produce large amounts of FT fuel. This will allow the fuel to be tested extensively, in current, prototype, and advanced diesel engines. The fuel may also contribute to the nation's energy security. The military has expressed interest in testing the fuel in aircraft and ground vehicles.

Steve Bergin

2003-10-17T23:59:59.000Z

50

Improved Fischer-Tropsch catalysts for indirect coal liquefaction. Final report  

SciTech Connect (OSTI)

The Fischer-Tropsch synthesis (FTS)reaction is the established technology for the production of liquid fuels from coal by an indirect route using coal-derived syngas (CO + H{sub 2}). Modern FTS catalysts are potassium- and copper-promoted iron preparations. These catalysts exhibit moderate activity with carbon monoxide-rich feedstocks such as the syngas produced by advanced coal gasification processes. However, the relatively large yields of by-product methane and high-molecular-weight hydrocarbon waxes detract from the production of desired liquid products in the C{sub 5}-C{sub 16} range needed for motor and aviation fuel. The goal of this program is to decrease undesirable portions of the FTS hydrocarbon yield by altering the Schultz-Flory polymerization product distribution through design and formulation of improved catalysts. Two approaches were taken: (1) reducing the yield of high-molecular-weight hydrocarbon waxes by using highly dispersed catalysts produced from surface-confined multiatomic clusters on acid supports and (2) suppressing methane production by uniformly pretreating active, selective conventional FTS catalysts with submonolayer levels of sulfur.

Wilson, R.B. Jr.; Tong, G.T.; Chan, Y.W.; Huang, H.W.; McCarty, J.G.

1989-02-01T23:59:59.000Z

51

SEPARATION OF FISCHER-TROPSCH WAX FROM CATALYST BY SUPERCRITICAL EXTRACTION  

SciTech Connect (OSTI)

The objective of this research project was to evaluate the potential of supercritical fluid (SCF) extraction for the recovery and fractionation of the wax product from the slurry bubble column (SBC) reactor of the Fischer-Tropsch (F-T) process. The wax, comprised mostly of branched and linear alkanes with a broad molecular weight distribution up to C{sub 100}, is to be extracted with a hydrocarbon solvent that has a critical temperature near the operating temperature of the SBC reactor, i.e., 200-300 C. Aspen Plus{trademark} was used to perform process simulation studies on the proposed extraction process, with Redlich-Kwong-Soave (RKS) being used for the thermodynamic property model. In summary, we have made comprehensive VLE measurements for short alkane + long alkane systems over a wide range of pressures and temperatures, dramatically increasing the amount of high-quality data available for these simple, yet highly relevant systems. In addition, our work has demonstrated that, surprisingly, no current thermodynamic model can adequately predict VLE behavior for these systems. Thus, process simulations (such as those for our proposed SCF extraction process) that incorporate these systems can currently only give results that are qualitative at best. Although significant progress has been made in the past decade, more experimental and theoretical work remain to be done before the phase equilibria of asymmetric alkane mixtures can be predicted with confidence.

Patrick C. Joyce; Mark C. Thies

1999-03-31T23:59:59.000Z

52

Studying Fischer-Tropsch catalysts using transmission electron microscopy and model systems of nanoparticles on planar supports.  

SciTech Connect (OSTI)

Nanoparticle model systems on planar supports form a versatile platform for studying morphological and compositional changes of catalysts due to exposure to realistic reaction conditions. We review examples from our work on iron and cobalt catalysts, which can undergo significant rearrangement in the reactive environment of the Fischer-Tropsch synthesis. The use of specially designed, silicon based supports with thin film SiO{sub 2} enables the application of transmission electron microscopy, which has furnished important insight into e.g. the mechanisms of catalyst regeneration.

Thune, P. C.; Weststrate, C. J.; Moodley, P.; Saib, A. M.; van de Loosdrecht, J.; Miller, J. T.; Niemantsverdriet, J. W. (Chemical Sciences and Engineering Division); (Eindhoven Univ. of Technology); (Sasol Technology)

2011-01-01T23:59:59.000Z

53

Separation of Fischer-Tropsch wax from catalyst by supercritical fluid extraction. Technical progress report, January--March 1995  

SciTech Connect (OSTI)

Objective is to evaluate the potential of supercritical fluid extraction for separating the catalyst slurry of a Fischer-Tropsch (F- T) slurry bubble column reactor into a wax and a concentrated catalyst slurry that is ready for recycle/regeneration. The automated apparatus was evaluated using a toluene-petroleum pitch system. The Statistical Associating Fluid Theory (SAFT) equation will be used to fit the VLE and LLE data for F-T wax-solvent systems; this equation was successful in predicting both phase compositions and average molecular weight distributions.

Thies, M.C.

1995-08-01T23:59:59.000Z

54

SEPARATION OF FISCHER-TROPSCH WAX PRODUCTS FROM ULTRAFINE IRON CATALYST PARTICLES  

SciTech Connect (OSTI)

In this reporting period, a fundamental filtration study was continued to investigate the separation of Fischer-Tropsch Synthesis (FTS) liquids from iron-based catalyst particles. The overall focus of the program is with slurry-phase FTS in slurry bubble column reactor systems. Hydrocarbon products must be separated from catalyst particles before being removed from the reactor system. An efficient wax product/catalyst separation system is a key factor for optimizing operating costs for iron-based slurry-phase FTS. Previous work has focused on catalyst particle attrition and the formation of ultra-fine iron carbide and/or carbon particles. With the current study, we are investigating how the filtration properties are affected by these chemical and physical changes of the catalyst slurry during activation/synthesis. In this reporting period, a series of crossflow filtration experiments were initiated to study the effect of olefins and oxygenates on the filtration flux and membrane performance. Iron-based FTS reactor waxes contain a significant amount of oxygenates, depending on the catalyst formulation and operating conditions. Mono-olefins and aliphatic alcohols were doped into an activated iron catalyst slurry (with Polywax) to test their influence on filtration properties. The olefins were varied from 5 to 25 wt% and oxygenates from 6 to 17 wt% to simulate a range of reactor slurries reported in the literature. The addition of an alcohol (1-dodecanol) was found to decrease the permeation rate while the olefin added (1-hexadecene) had no effect on the permeation rate. A passive flux maintenance technique was tested that can temporarily increase the permeate rate for 24 hours.

James K. Neathery; Gary Jacobs; Burtron H. Davis

2005-03-31T23:59:59.000Z

55

SEPARATION OF FISCHER-TROPSCH WAX PRODUCTS FROM ULTRAFINE IRON CATALYST PARTICLES  

SciTech Connect (OSTI)

In this reporting period, a fundamental filtration study was continued to investigate the separation of Fischer-Tropsch Synthesis (FTS) liquids from iron-based catalyst particles. The overall focus of the program is with slurry-phase FTS in slurry bubble column reactor systems. Hydrocarbon products must be separated from catalyst particles before being removed from the reactor system. An efficient wax product/catalyst separation system is a key factor for optimizing operating costs for iron-based slurry-phase FTS. Previous work has focused on catalyst particle attrition and the formation of ultra-fine iron carbide and/or carbon particles. With the current study, we are investigating how the filtration properties are affected by these chemical and physical changes of the catalyst slurry during activation/synthesis. The shakedown phase of the pilot-scale filtration platform was completed at the end of the last reporting period. A study of various molecular weight waxes was initiated to determine the effect of wax physical properties on the permeation rate without catalyst present. As expected, the permeation flux was inversely proportional to the nominal average molecular weight of the polyethylene wax. Even without catalyst particles present in the filtrate, the filtration membranes experience fouling during an induction period on the order of days on-line. Another long-term filtration test was initiated using a batch of iron catalyst that was previously activated with CO to form iron carbide in a separate continuous stirred tank reactor (CSTR) system. The permeation flux stabilized more rapidly than that experienced with unactivated catalyst tests.

James K. Neathery; Gary Jacobs; Burtron H. Davis

2004-09-30T23:59:59.000Z

56

Separation of Fischer-Tropsch Wax Products from Ultrafine Iron Catalyst Particles  

SciTech Connect (OSTI)

In this reporting period, a study of ultra-fine iron catalyst filtration was initiated to study the behavior of ultra-fine particles during the separation of Fischer-Tropsch Synthesis (FTS) liquids filtration. The overall focus of the program is with slurry-phase FTS in slurry bubble column reactor systems. Hydrocarbon products must be separated from catalyst particles before being removed from the reactor system. An efficient wax product/catalyst separation system is a key factor for optimizing operating costs for iron-based slurry-phase FTS. Previous work has focused on catalyst particle attrition and the formation of ultra-fine iron carbide and/or carbon particles. With the current study, we are investigating how the filtration properties are affected by these chemical and physical changes of the catalyst slurry during activation/synthesis. The change of particle size during the slurry-phase FTS has monitored by withdrawing catalyst sample at different TOS. The measurement of dimension of the HRTEM images of samples showed a tremendous growth of the particles. Carbon rims of thickness 3-6 nm around the particles were observed. This growth in particle size was not due to carbon deposition on the catalyst. A conceptual design and operating philosophy was developed for an integrated wax filtration system for a 4 liter slurry bubble column reactor to be used in Phase II of this research program. The system will utilize a primary inertial hydroclone followed by a Pall Accusep cross-flow membrane. Provisions for cleaned permeate back-pulsing will be included to as a flux maintenance measure.

James K. Neathery; Gary Jacobs; Amitava Sarkar; Burtron H. Davis

2005-09-30T23:59:59.000Z

57

SBA-15-supported iron catalysts for Fischer-Tropsch production of diesel fuel  

SciTech Connect (OSTI)

Iron supported on SBA-15, a mesoporous structured silica, has been developed as a catalyst for the Fischer-Tropsch synthesis of hydrocarbons. The catalysts retain the high surface area of the support, {approximately}500 m{sup 2}/g, average pore size, and pore volume. Inclusion of aluminum into the SBA-15 did not significantly alter these parameters. XRD, XAFS, and Moessbauer spectroscopies were used to characterize the catalyst before and after being subjected to the reaction conditions. Prior to reaction, the iron was distributed among {alpha}-Fe{sub 2}O{sub 3}, ferrihydrite, and minor {gamma}Fe{sub 2}O{sub 3}. After reaction, the iron phases detected were nonmagnetic iron oxides, iron carbide, and metallic iron. The length of the induction period typically seen with iron-based F-T catalysts was strongly dependent on the amount of aluminum present in the catalyst. With no aluminum, the induction period lasted about 25 h, whereas the induction period decreased to less than 5 h with an Al:Si mass ratio of 0.010. A further increase in aluminum content lengthened the induction period, but always remained less than that without aluminum. Catalyst activity and product selectivity were also strongly dependent on aluminum content with the maximum diesel fuel fraction, C{sub 11+}, occurring with the Al:Si ratio of 0.010 and a CO conversion of 37%. The small concentration of aluminum may serve to increase the rate of iron carbide formation, whereas higher concentrations may begin to inhibit the rate. 23 refs., 6 figs., 2 tabs.

Dae Jung Kim; Brian C. Dunn; Frank Huggins; Gerald P. Huffman; Min Kang; Jae Eui Yie; Edward M. Eyring [University of Utah, Salt Lake City, UT (United States). Department of Chemistry

2006-12-15T23:59:59.000Z

58

Technology development for iron Fischer-Tropsch catalysts. Technical progress report No. 2, December 26, 1990--March 26, 1991  

SciTech Connect (OSTI)

The objectives of this contract are to develop a technology for the production of active and stable iron Fischer-Tropsch catalysts for use in slurry-phase synthesis reactors and to develop a scaleup procedure for large-scale synthesis of such catalyst for process development and long-term testing in slurry bubble-column reactors. With a feed containing H{sub 2} and CO in the molar ratio of 0.5 to 1.0, the catalyst performance target in the slurry bubble-column reactor is 88% CO + H{sub 2} conversion at a minimum space velocity of 2.4 NL/hr/gFe. The desired sum of methane and ethane selectivities is no more than 4%, and the conversion loss per week is not to exceed 1%.

Not Available

1991-12-31T23:59:59.000Z

59

Technology development for iron Fischer-Tropsch catalysts. Technical progress report No. 5, September 26, 1991--December 26, 1991  

SciTech Connect (OSTI)

Objective is to develop producing active, stable iron Fischer-Tropsch catalysts for use in slurry-phase synthesis reactors and to synthesize such catalysts on a large scale for process development and long-term testing in slurry bubble-column reactors. A mixed oxalate of Fe, Cu, and K was prepared; a catalyst will be prepared from this material. An evaluation run was performed on an Fe-based UCI catalyst, which was shown to produce low levels of C{sub 1} and C{sub 2} paraffins; e.g., at the end of the run, when the catalyst was converting 60% of the CO, the C{sub 1} and C{sub 2} paraffin selectivities were 4.2 and 1.0, respectively.

Frame, R.R.; Gala, H.B.

1992-12-22T23:59:59.000Z

60

Technology development for iron Fischer-Tropsch catalysts. Technical progress report No. 1, September 26, 1990--December 26, 1990  

SciTech Connect (OSTI)

The objectives of this contract are to develop a technology for the production of active and stable iron Fischer-Tropsch catalysts for use in slurry-phase synthesis reactors and to develop a scale-up procedure for large-scale synthesis of such catalysts for process development and long-term testing in slurry bubble column reactors. With a feed containing H{sub 2}:CO in the ratio of 0.5 to 1.0, the catalyst performance target in the slurry bubble column reactor is 88% CO + H{sub 2}conversion at a minimum space velocity of 2.4 NL/h/gFe. The methane + ethane selectivity is desired to be no more than 4% and the conversion loss per week is not to exceed 1%.

Not Available

1990-12-31T23:59:59.000Z

Note: This page contains sample records for the topic "oils biomass-derived fischer-tropsch" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Effect of Surface Modification by Chelating Agents on Fischer- Tropsch Performance of Co/SiO{sub 2} Catalysts  

SciTech Connect (OSTI)

The silica support of a Co-based catalyst for Fischer-Tropsch (FT) synthesis was modified by the chelating agents (CAs) nitrilotriacetic acid (NTA) and ethylenediaminetetraacetic acid (EDTA). After the modification, characterization of the fresh and spent catalysts show reduced crystallite sizes, a better-dispersed Co{sub 3}O{sub 4} phase on the calcined samples, and increased metal dispersions for the reduced samples. The CA-modified catalysts display higher CO conversions, product yields, reaction rates and rate constants. The improved FT performance of CA-modified catalysts is attributed to the formation of stable complexes with Co. The superior performance of the EDTA-modified catalyst in comparison to the NTA-modified catalyst is due to the higher affinity of the former for complex formation with Co ions.

Bambal, Ashish S.; Kugler, Edwin L.; Gardner, Todd H.; Dadyburjor, Dady B.

2013-11-27T23:59:59.000Z

62

Evaluation of a biomass derived oil for use as additive in paving asphalt  

SciTech Connect (OSTI)

Treatment and disposal costs of sewage sludge can represent up to 50% of a municipality`s annual wastewater treatment budget. Sewage sludge (30% solids) accounts 5% of Canadian landfill by weight, and the ever increasing volume of sludge coupled with the decreasing options available for disposal creates a growing problem for major municipalities. Current disposal options are agricultural application, incineration and landfill. Concern about heavy metal migration and public pressure to find a local solution has severely curtailed the spreading of sludge on agricultural land. Incineration is the major option for larger centers but the relatively high cost for incineration, ranging from $350 to $1000/t dry sludge, has caused a great deal of interest in methods of improving the cost effectiveness of incineration or in new equivalent technologies. The high cost and more stringent environmental regulations for incinerating municipal sludges have led to developing more efficient sludge management technologies that are not agricultural based. This paper describes applications of oils from sludge processing.

Houde, J. Jr.; Clelland, I.; Sawatzky, H. [CANMET, Ottawa, Ontario (Canada)

1995-12-31T23:59:59.000Z

63

Investigation of Effects of Coal and Biomass Contaminants on the Performance of Water-Gas-Shift and Fischer-Tropsch Catalysts  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Effects of Coal Effects of Coal and Biomass Contaminants on the Performance of Water-Gas-Shift and Fischer-Tropsch Catalysts Background Coal-Biomass-to-Liquids (CBTL) processes gasify coal, biomass, and mixtures of coal/ biomass to produce synthesis gas (syngas) that can be converted to liquid hydrocarbon fuels. Positive benefits of these processes include the use of feedstocks from domestic sources and lower greenhouse gas production than can be achieved from using conventional petroleum-based fuels. However, syngas generated by coal and biomass co-gasification contains a myriad of trace contaminants that may poison the water- gas-shift (WGS) and Fischer-Tropsch (FT) catalysts used in the gas-to-liquid processes. While the effect of coal contaminants on FT processes is well studied, more research

64

Slurry phase Fischer-Tropsch synthesis: Cobalt plus a water-gas shift catalyst. [Quarterly] report, June 30, 1988--September 30, 1988  

SciTech Connect (OSTI)

This report details experiments performed on three different copper-based catalysts: Cu/Cr{sub 2}O{sub 3}, Cu/MnO/Cr{sub 2}O{sub 3} and Cu/ZnO/Al{sub 2}O{sub 3}. Of these three catalysts, the Cu/ZnO/Al{sub 2}O{sub 3} exhibits the greatest stability when slurried in octacosane. More than 1000 hours-on-stream indicate that the catalyst activity is not detrimentally affected by high pressure, high H{sub 2}/CO ratio, or the presence of alkenes. All of these are necessary stability characteristics for the water-gas shift catalyst, if it is to be used in combination with a cobalt Fischer-Tropsch catalyst. A review of documented reduction procedures for cobalt-based Fischer-Tropsch catalysts is presented.

Yates, I.C.; Satterfield, C.N.

1988-12-31T23:59:59.000Z

65

Assessment of Fuel-Cycle Energy Use and Greenhouse Gas Emissions for Fischer?Tropsch Diesel from Coal and Cellulosic Biomass  

Science Journals Connector (OSTI)

Assessment of Fuel-Cycle Energy Use and Greenhouse Gas Emissions for Fischer?Tropsch Diesel from Coal and Cellulosic Biomass ... There are two general designs for FTD production:(7, 30) recycling (RC) design and once-through (OT) design, as illustrated in Figure 2. ... Wang, M. Q.GREET 1.0 — Transportation Fuel Cycles Model: Methodology and Use, Argonne National Laboratory: Argonne, IL, ANL/ESD-33. ...

Xiaomin Xie; Michael Wang; Jeongwoo Han

2011-03-03T23:59:59.000Z

66

Technology development for iron Fischer-Tropsch catalysts. Technical progress report No. 10, December 26, 1992--March 26, 1993  

SciTech Connect (OSTI)

The objectives of this contract are to develop a technology for the production of active and stable iron Fischer-Tropsch catalysts for use in slurry-phase synthesis reactors and to develop a scaleup procedure for large-scale synthesis of such catalysts for process development and long-term testing in slurry bubble-column reactors. With a feed containing hydrogen and carbon monoxide in the molar ratio of 0.5 to 1.0 to the slurry bubble-column reactor, the catalyst performance target is 88% CO + H{sub 2} conversion at a minimum space velocity of 2.4 NL/hr/gFe. The desired sum of methane and ethane selectivities is no more than 4%, and the conversion loss per week is not to exceed 1%. Contract tasks are as follows: 1.0: Catalyst development; 1.1--Technology assessment; 1.2--Precipitated catalyst preparation method development; 1.3--Novel catalyst preparation methods investigation; 1.4--Catalyst pretreatment; 1.5--Catalyst characterization; 2.0--Catalyst testing; 3.0--Catalyst aging studies, and 4.0--Preliminary design and cost estimate of a catalyst synthesis facility. This paper reports progress made on Task 1.2 and 2.0.

Frame, R.R.; Gala, H.B.

1993-12-31T23:59:59.000Z

67

Technology development for iron Fischer-Tropsch catalysts. Technical progress report No. 9, September 26, 1992--December 26, 1992  

SciTech Connect (OSTI)

The objectives of this contract are to develop a technology for the production of active and stable iron Fischer-Tropsch catalysts for use in slurry-phase synthesis reactors and to develop a scaleup procedure for large-scale synthesis of such catalysts for process development and long-term testing in slurry bubble-column reactors. With a feed containing hydrogen and carbon monoxide in the molar ratio of 0.5 to 1.0 to the slurry bubble-column reactor, the catalyst performance target is 88% CO + H{sub 2} conversion at a minimum space velocity of 2.4 NL/hr/gFe. The desired sum of methane and ethane selectivities is no more than 4%, and the conversion loss per week is not to exceed 1%. Contract Tasks are as follows: 1.0--Catalyst development, 1.1--Technology assessment, 1.2--Precipitated catalyst preparation method development, 1.3--Novel catalyst preparation methods investigation, 1.4--Catalyst pretreatment, 1.5--Catalyst characterization, 2.0--Catalyst testing, 3.0--Catalyst aging studies, and 4.0--Preliminary design and cost estimate of a catalyst synthesis facility. This paper reports progress on Task 1.3.

Frame, R.R.; Gala, H.B.

1992-12-31T23:59:59.000Z

68

Technology development for iron Fischer-Tropsch catalysts. Technical progress report No. 6, December 26, 1991--March 31, 1992  

SciTech Connect (OSTI)

The objective of this contract are to develop a technology for the production of active and stable iron Fischer-Tropsch catalysts for use in slurry-phase synthesis reactors and to develop a scaleup procedure for large-scale synthesis of such catalysts for process development and long-term testing in slurry bubble-column reactors. With a feed containing H{sub 2} and CO in the molar ratio of 0.5 to 1.0 to the slurry bubble-column reactor, the catalyst performance target is 88% CO + H{sub 2} conversion at a minimum space velocity of 2.4 NL/hr/gFe. The desired sum of methane and ethane selectivities is no more than 4%, and the conversion loss per week is not to exceed 1%. Contract Tasks are as follows: 1.0--Catalyst development, 1.1--Technology assessment, 1.2--Precipitated catalyst preparation method development, 1.3--Novel catalyst preparation methods investigation, 1.4--Catalyst pretreatment, 1.5--Catalyst characterization, 2.0--Catalyst testing, 3.0--Catalyst aging studies, and 4.0--Preliminary design and cost estimate of a catalyst synthesis facility. This paper reports progress made on catalyst development.

Frame, R.R.; Gala, H.B.

1992-12-31T23:59:59.000Z

69

Separation of Fischer-Tropsch wax from catalyst by supercritical extraction. Quarterly report, July 1, 1996 - September 30, 1996  

SciTech Connect (OSTI)

The objective of this research projects is to evaluate the potential of SCF extraction for separating the catalyst slurry of a Fischer- Tropsch (F-T) slurry bubble column (SBC) reactor into two fractions: (1) a catalyst-free wax containing less than 10 ppm particulate matter and (2) a concentrated catalyst slurry that is ready for recycle or regeneration. The wax will be extracted with a hydrocarbon solvent that has a critical temperature near the operating temperature of the SBC reactor, i.e. 200-300{degrees}C. Initial work is being performed using n-hexane as the solvent. The success of the projects depends on two major factors. First, the supercritical solvent must be able to dissolve the F-T wax; furthermore, the must be accomplished without entraining the solid catalyst. Second, the extraction must be controlled so as not to favor the removal of the low molecular weight wax compounds, i.e., a constant carbon-number distribution of the alkanes in the wax slurry must be maintained at steady-state column operation. The project includes three tasks (1) equilibrium solubility measurements, (2) thermodynamic modeling, and (3) process design studies.

Joyce, P.C.; Thies, M.C. [USDOE Pittsburgh Energy Technology Center, PA (United States); Sherrard, D.; Biales, J.; Kilpatrick, P.; Roberts, G. [North Carolina State Univ., Raleigh, NC (United States). Dept. of Chemical Engineering

1996-12-31T23:59:59.000Z

70

Separation of Fischer-Tropsch wax from catalyst using supercritical fluid extraction. Quarterly technical progress report, July 1, 1995--September 31, 1995  

SciTech Connect (OSTI)

Programming and testing of the highly complex Statistical Associating Fluid Theory (or SAFT) equation of state is essentially complete. As an accuracy check, results from our program were compared and found to be in excellent agreement with those of two other research groups (one in the US and two in Europe) for both a nonassociating (methane-hexadecane) and an associating (carbon dioxide-methanol) system. This equation is being used to model the solubility our model Fischer-Tropsch compounds in supercritical solvents such as hexane. SAFT has been chosen for this work because of its fundamental rigor. Therefore, extension of our model compound results to the poorly defined Fischer-Tropsch waxes should be more successful compared to more empirical equations such as Peng-Robinson. Computer-controlled automation of one of our dynamic supercritical fluid (SCF) extraction apparatus is complete. The apparatus collects samples automatically, dramatically reducing operator manpower and fatigue, and is also capable of controlling the operating pressure more precisely (i.e., within {plus_minus}2 psi). This apparatus (SFE I) will be used for future experiments with actual Fischer-Tropsch waxes. Modification/construction of another apparatus (SCF II) that will be used for our model component-SCF phase equilibria/solubility studies is nearly complete; it is currently being leak-tested. This apparatus was built to handle the low mass flow rates that will be required when measuring solubility data for the more expensive model compounds, such as n-C40. Anticipated results for the next quarter include VLE measurements for hexane-squalane at temperatures to 573 K.

Thies, M.C.; Joyce, P.C.

1996-02-01T23:59:59.000Z

71

Fischer-Tropsch chemistry: structure of a seminal eta/sup 2/-CH cluster derivative, HFe/sub 4/(eta/sup 2/-CH)(CO)/sub 12/  

SciTech Connect (OSTI)

Results of x-ray crystallographic studies of the complex HFe/sub 4/(eta/sup 2/-CH)(CO)/sub 12/ are reported. The complex may provide information that relates to intermediates in some metal-surface catalyzed Fischer-Tropsch reactions. The complex was found to contain a butterfly array of four Fe atoms, each with three terminal carbonyl ligands, with the carbidic C atom nestled near the center of the top of the wings of the Fe/sub 4/ array where it forms a strong C-H-Fe interaction. Measurements of the bond distances are given. (BLM)

Beno, M.A. (Argonne National Lab., IL); Williams, J.M.; Tachikawa, M.; Muetterties, E.L.

1980-06-18T23:59:59.000Z

72

Atomic-Scale Design of Iron Fischer-Tropsch Catalysts: A Combined Computational Chemistry, Experimental, and Microkinetic Modeling Approach  

SciTech Connect (OSTI)

Work continued on the development of a microkinetic model of Fischer-Tropsch synthesis (FTS) on supported and unsupported Fe catalysts. The following aspects of the FT mechanism on unsupported iron catalysts were investigated on during this third year: (1) the collection of rate data in a Berty CSTR reactor based on sequential design of experiments; (2) CO adsorption and CO-TPD for obtaining the heat of adsorption of CO on polycrystalline iron; and (3) isothermal hydrogenation (IH) after Fischer Tropsch reaction to identify and quantify surface carbonaceous species. Rates of C{sub 2+} formation on unsupported iron catalysts at 220 C and 20 atm correlated well to a Langmuir-Hinshelwood type expression, derived assuming carbon hydrogenation to CH and OH recombination to water to be rate-determining steps. From desorption of molecularly adsorbed CO at different temperatures the heat of adsorption of CO on polycrystalline iron was determined to be 100 kJ/mol. Amounts and types of carbonaceous species formed after FT reaction for 5-10 minutes at 150, 175, 200 and 285 C vary significantly with temperature. Mr. Brian Critchfield completed his M.S. thesis work on a statistically designed study of the kinetics of FTS on 20% Fe/alumina. Preparation of a paper describing this work is in progress. Results of these studies were reported at the Annual Meeting of the Western States Catalysis and at the San Francisco AIChE meeting. In the coming period, studies will focus on quantitative determination of the rates of kinetically-relevant elementary steps on unsupported Fe catalysts with/without K and Pt promoters by SSITKA method. This study will help us to (1) understand effects of promoter and support on elementary kinetic parameters and (2) build a microkinetics model for FTS on iron. Calculations using periodic, self-consistent Density Functional Theory (DFT) methods were performed on models of defected Fe surfaces, most significantly the stepped Fe(211) surface. Binding Energies (BE's), preferred adsorption sites and geometries of all the FTS relevant stable species and intermediates were evaluated. Each elementary step of our reaction model was fully characterized with respect to its thermochemistry and comparisons between the stepped Fe(211) facet and the most-stable Fe(110) facet were established. In most cases the BE's on Fe(211) reflected the trends observed earlier on Fe(110), yet there were significant variations imposed on the underlying trends. Vibrational frequencies were evaluated for the preferred adsorption configurations of each species with the aim of evaluating the entropy-changes and preexponential factors for each elementary step. Kinetic studies were performed for the early steps of FTS (up to CH{sub 4} formation) and CO dissociation. This involved evaluation of the Minimum Energy Pathway (MEP) and activation energy barrier for the steps involved. We concluded that Fe(211) would allow for far more facile CO dissociation in comparison to other Fe catalysts studied so far, but the other FTS steps studied remained mostly unchanged.

Manos Mavrikakis; James A. Dumesic; Rahul P. Nabar

2006-09-29T23:59:59.000Z

73

Fossil-fuel processing technical/professional services: comparison of Fischer-Tropsch reactor systems. Phase I, final report  

SciTech Connect (OSTI)

The Fischer-Tropsch reaction was commercialized in Germany and used to produce military fuels in fixed bed reactors. It was recognized from the start that this reactor system had severe operating and yield limitations and alternative reactor systems were sought. In 1955 the Sasol I complex, using an entrained bed (Synthol) reactor system, was started up in South Africa. Although this reactor was a definite improvement and is still operating, the literature is filled with proponents of other reactor systems, each claiming its own advantages. This report provides a summary of the results of a study to compare the development potential of three of these reactor systems with the commercially operating Synthol-entrained bed reactor system. The commercial Synthol reactor is used as a benchmark against which the development potential of the other three reactors can be compared. Most of the information on which this study is based was supplied by the M.W. Kellogg Co. No information beyond that in the literature on the operation of the Synthol reactor system was available for consideration in preparing this study, nor were any details of the changes made to the original Synthol system to overcome the operating problems reported in the literature. Because of conflicting claims and results found in the literature, it was decided to concentrate a large part of this study on a kinetic analysis of the reactor systems, in order to provide a theoretical analysis of intrinsic strengths and weaknesses of the reactors unclouded by different catalysts, operating conditions and feed compositions. The remainder of the study considers the physical attributes of the four reactor systems and compares their respective investment costs, yields, catalyst requirements and thermal efficiencies from simplified conceptual designs.

Thompson, G.J.; Riekena, M.L.; Vickers, A.G.

1981-09-01T23:59:59.000Z

74

FischerTropsch synthesis on a model Co/SiO2 catalyst , Zhoujun Wang a  

E-Print Network [OSTI]

, although made vulnerable by the dramatic changes in crude oil prices, is still one of the few technologies and Texas A&M University, College Station, TX 77843, United States a r t i c l e i n f o Article history on crude oil, and much effort has been made to develop renewable energy technologies, such as solar, wind

Goodman, Wayne

75

Fischer-Tropsch slurry phase process variations to understand wax formations: Quarterly report for period October 1, 1987 to December 31, 1987  

SciTech Connect (OSTI)

Effects of high syngas conversion on the secondary reactions of olefins formed by Fischer-Tropsch synthesis on a reduced fused magnetite catalyst were simulated by studies of olefins in the presence of hydrogen and low concentrations of CO, or none at all. kinetic models were developed for the effect of CO partial pressure on hydrogenation rates at 232)degree)C and 0.30 to 0.79 MPa. In the absence of carbon monoxide, olefin hydrogenation was more rapid than in its presence. A model indicated that a hydrogenated carbon monoxide species on the catalyst may be responsible for the inhibition of olefin hydrogenation, and that olefin adsorption is rate-limiting. The formation of secondary olefins appeared to follow similar trends with carbon monoxide partial pressure. Olefin incorporation was not observed in the small amount of Fischer-Tropsch products obtained in these experiments. The chain growth probability, alpha, appeared to correlate with the H/sub 2/CO feed ratio. 14 refs., 13 figs., 1 tab.

Satterfield, C.N.

1987-01-01T23:59:59.000Z

76

Preliminary life-cycle assessment of biomass-derived refinery feedstocks for reducing CO{sub 2} emissions  

SciTech Connect (OSTI)

The US by ratification of the United Nations Framework Convention on Climate Change has pledged to emit no higher levels of greenhouse gases in the year 2000 than it did in 1990. Biomass-derived products have been touted as a possible solution to the potential problem of global warming. However, past studies related to the production of liquid fuels, chemicals, gaseous products, or electricity from biomass, have only considered the economics of producing these commodities. The environmental benefits have not been fully quantified and factored into these estimates until recently. Evaluating the environmental impact of various biomass systems has begun using life-cycle assessment. A refinery Linear Programming model previously developed has been modified to examine the effects of CO{sub 2}-capping on the US refining industry and the transportation sector as a whole. By incorporating the results of a CO{sub 2} emissions inventory into the model, the economic impact of emissions reduction strategies can be estimated. Thus, the degree to which global warming can be solved by supplementing fossil fuels with biomass-derived products can be measured, allowing research and development to be concentrated on the most environmentally and economically attractive technology mix. Biomass gasification to produce four different refinery feedstocks was considered in this analysis. These biomass-derived products include power, fuel gas, hydrogen for refinery processing, and Fischer-Tropsch liquids for upgrading and blending into finished transportation fuels.

Marano, J.J. [Burns and Roe Services Corp., Pittsburgh, PA (United States); Rogers, S. [Dept. of Energy, Pittsburgh, PA (United States); Spath, P.L.; Mann, M.K. [National Renewable Energy Lab., Golden, CO (United States)

1995-12-31T23:59:59.000Z

77

Atomic-Scale Design of Iron Fischer-Tropsch Catalysts; A Combined Computational Chemistry, Experimental, and Microkinetic Modeling Approach  

SciTech Connect (OSTI)

This work focuses on (1) searching/summarizing published Fischer-Tropsch synthesis (FTS) mechanistic and kinetic studies of FTS reactions on iron catalysts; (2) preparation and characterization of unsupported iron catalysts with/without potassium/platinum promoters; (3) measurement of H{sub 2} and CO adsorption/dissociation kinetics on iron catalysts using transient methods; (3) analysis of the transient rate data to calculate kinetic parameters of early elementary steps in FTS; (4) construction of a microkinetic model of FTS on iron, and (5) validation of the model from collection of steady-state rate data for FTS on iron catalysts. Three unsupported iron catalysts and three alumina-supported iron catalysts were prepared by non-aqueous-evaporative deposition (NED) or aqueous impregnation (AI) and characterized by chemisorption, BET, temperature-programmed reduction (TPR), extent-of-reduction, XRD, and TEM methods. These catalysts, covering a wide range of dispersions and metal loadings, are well-reduced and relatively thermally stable up to 500-600 C in H{sub 2} and thus ideal for kinetic and mechanistic studies. Kinetic parameters for CO adsorption, CO dissociation, and surface carbon hydrogenation on these catalysts were determined from temperature-programmed desorption (TPD) of CO and temperature programmed surface hydrogenation (TPSR), temperature-programmed hydrogenation (TPH), and isothermal, transient hydrogenation (ITH). A microkinetic model was constructed for the early steps in FTS on polycrystalline iron from the kinetic parameters of elementary steps determined experimentally in this work and from literature values. Steady-state rate data were collected in a Berty reactor and used for validation of the microkinetic model. These rate data were fitted to 'smart' Langmuir-Hinshelwood rate expressions derived from a sequence of elementary steps and using a combination of fitted steady-state parameters and parameters specified from the transient measurements. The results provide a platform for further development of microkinetic models of FTS on Fe and a basis for more precise modeling of FTS activity of Fe catalysts. Calculations using periodic, self-consistent Density Functional Theory (DFT) methods were performed on various realistic models of industrial, Fe-based FTS catalysts. Close-packed, most stable Fe(110) facet was analyzed and subsequently carbide formation was found to be facile leading to the choice of the FeC(110) model representing a Fe facet with a sub-surface C atom. The Pt adatom (Fe{sup Pt}(110)) was found to be the most stable model for our studies into Pt promotion and finally the role of steps was elucidated by recourse to the defected Fe(211) facet. Binding Energies(BEs), preferred adsorption sites and geometries for all FTS relevant stable species and intermediates were evaluated on each model catalyst facet. A mechanistic model (comprising of 32 elementary steps involving 19 species) was constructed and each elementary step therein was fully characterized with respect to its thermochemistry and kinetics. Kinetic calculations involved evaluation of the Minimum Energy Pathways (MEPs) and activation energies (barriers) for each step. Vibrational frequencies were evaluated for the preferred adsorption configuration of each species with the aim of evaluating entropy-changes, pre exponential factors and serving as a useful connection with experimental surface science techniques. Comparative analysis among these four facets revealed important trends in their relative behavior and roles in FTS catalysis. Overall the First Principles Calculations afforded us a new insight into FTS catalysis on Fe and modified-Fe catalysts.

Manos Mavrikakis; James Dumesic; Rahul Nabar; Calvin Bartholonew; Hu Zou; Uchenna Paul

2008-09-29T23:59:59.000Z

78

EA-1642-S1: Small-Scale Pilot Plant for the Gasification of Coal and Coal-Biomass Blends and Conversion of Derived Syngas to Liquid Fuels via Fischer-Tropsch Synthesis, Lexington, KY  

Broader source: Energy.gov [DOE]

This draft Supplemental Environmental Assessment (SEA) analyzes the potential environmental impacts of DOE’s proposed action of providing cost-shared funding for the University of Kentucky (UK) Center for Applied Energy Research (CAER) Small-Scale Pilot Plant for the Gasification of Coal and Coal-Biomass Blends and Conversion of Derived Syngas to Liquid Fuels via Fischer-Tropsch Synthesis project and of the No-Action Alternative.

79

Poisoning of a silica-supported cobalt catalyst due to presence of sulfur impurities in syngas during Fischer-Tropsch: Effects of chelating agent  

SciTech Connect (OSTI)

The effects of sulfur impurities on the performance of cobalt-based Fischer?Tropsch catalysts are evaluated under industrially relevant operating conditions of temperature, pressure, and impurity levels. Chelating agents (CAs) were used to modify the SiO2 support, and the performances of the CA-modified catalysts are compared with conventional Co/SiO2 catalysts. For both the Co/SiO2 and CA-modified catalysts, the presence of sulfur in the inlet syngas results in a notable drop in the CO conversion, an undesired shift in the hydrocarbon selectivity toward short-chain hydrocarbons, more olefins in the products, and lower product yields. In the post-poisoning stage, i.e., after termination of sulfur introduction in the inlet syngas, the CA-modified catalysts recover activity and selectivity (to some extent at least), whereas such trends are not observed for the base-case, i.e., unmodified Co/SiO2 catalyst. The improved performance of the CA-modified catalysts in the presence of sulfur is attributed to higher densities of active sites.

Bambal, Ashish S. [WVU; Guggilla, Vidya S. [WVU; Kugler, Edwin L. [WVU; Gardner, Todd H. [U.S. DOE; Dadyburjor, Dady B. [WVU

2014-01-01T23:59:59.000Z

80

Assessment of fuel-cycle energy use and greenhouse gas emissions for Fischer-Tropsch diesel from coal and cellulosic biomass.  

SciTech Connect (OSTI)

This study expands and uses the GREET (Greenhouse Gases, Regulated Emissions, and Energy Use in Transportation) model to assess the effects of carbon capture and storage (CCS) technology and cellulosic biomass and coal cofeeding in Fischer-Tropsch (FT) plants on energy use and greenhouse gas (GHG) emissions of FT diesel (FTD). To demonstrate the influence of the coproduct credit methods on FTD life-cycle analysis (LCA) results, two allocation methods based on the energy value and the market revenue of different products and a hybrid method are employed. With the energy-based allocation method, fossil energy use of FTD is less than that of petroleum diesel, and GHG emissions of FTD could be close to zero or even less than zero with CCS when forest residue accounts for 55% or more of the total dry mass input to FTD plants. Without CCS, GHG emissions are reduced to a level equivalent to that from petroleum diesel plants when forest residue accounts for 61% of the total dry mass input. Moreover, we show that coproduct method selection is crucial for LCA results of FTD when a large amount of coproducts is produced.

Xie, X.; Wang, M.; Han, J. (Energy Systems)

2011-04-01T23:59:59.000Z

Note: This page contains sample records for the topic "oils biomass-derived fischer-tropsch" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Fischer Tropsch synthesis : influence of Mn on the carburization rates and activities of Fe-based catalysts by TPR-EXAFS/XANES and catalyst testing.  

SciTech Connect (OSTI)

Fe-based catalysts containing different amounts of Mn were tested for Fischer-Tropsch synthesis using a stirred tank reactor at 270 C, 1.21 MPa, and H{sub 2}:CO = 0.7. Catalyst activation by carburization with 10% CO/He was followed by Temperature Programmed Reduction/X-ray Absorption Spectroscopy (TPR-EXAFS/XANES) from room temperature to 300 C. {gamma}-Fe{sub 2}O{sub 3} was converted into iron carbides, whereas MnO{sub x} was reduced to oxygen deficient MnO. Mn hindered Fe carburization, such that the carburized catalyst displayed higher Fe{sub 3}O{sub 4} content than the catalyst without Mn. EXAFS fitting indicates that the carburized catalyst contained a mixture of Hgg carbide, Fe{sub 3}O{sub 4}, and Mn oxides. Increasing Mn content led to higher CH{sub 4} and light product selectivities, and lower light olefin selectivities. Higher and stable conversions were obtained with a catalyst containing an almost equimolar Fe/Mn ratio relative to the catalyst without Mn. Selectivity trends are attributed to the higher WGS rates observed on the FeMn catalysts, consistent with the structural differences observed.

Ribeiro, M. C.; Jacobs, G.; Pendyala, R.; Davis, B. H.; Cronauer, D. C.; Kropf, A. J.; Marshall, C. L. (Chemical Sciences and Engineering Division); (Univ. of Kentucky)

2011-03-24T23:59:59.000Z

82

Separation of Fischer-Tropsch wax from catalyst using supercritical fluid extraction. Quarterly technical progress report, April 1, 1996--June 30, 1996  

SciTech Connect (OSTI)

The objective of this research project is to evaluate the potential of SCF extraction for separating the catalyst slurry of a Fischer- Tropsch (F-T) slurry bubble column (SBC) reactor into two fractions: (1) a catalyst-free wax containing less than 10 ppm particulate matter and (2) a concentrated catalyst slurry that is ready for recycle or regeneration. The wax will be extracted with a hydrocarbon solvent that has a critical temperature near the operating temperature of the SBC reactor, i.e., 200-300{degrees}C. Initial work is being performed using n-hexane as the solvent. The success of the project depends on two major factors. First, the supercritical solvent must be able to dissolve the F-T wax; furthermore, this must be accomplished without entraining the solid catalyst. Second, the extraction must be controlled so as not to favor the removal of the low molecular weight wax compounds, i.e., a constant carbon-number distribution of the alkanes in the wax slurry must be maintained at steady-state column operation. To implement our objectives, the following task structure is being implemented: Task 1 equilibrium solubility measurements; Task 2 thermodynamic modeling; and Task 3 process design studies. Progress reports are presented for each task.

Joyce, P.C.; Thies, M.C.

1996-11-01T23:59:59.000Z

83

Separation of Fischer-Tropsch wax from catalyst using supercritical fluid extraction. Quarterly technical progress report, 1 January 1996--31 March 1996  

SciTech Connect (OSTI)

The objective of this research project is to evaluate the potential of supercritical fluid extraction for separating the catalyst slurry of a Fischer-Tropsch (F-T) slurry bubble column (SBC) reactor into two fractions: (1) a catalyst-free wax containing less than 10 ppm particulate matter and (2) a concentrated catalyst slurry that is ready for recycle or regeneration. The wax will be extracted with a hydrocarbon solvent that has a critical temperature near the operating temperature of the SBC reactor, i.e., 200--300 {degrees}C. Initial work is being performed using n-hexane as the solvent. The success of the project depends on two major factors. First, the supercritical solvent must be able to dissolve the F-T wax; furthermore, this must be accomplished without entraining the solid catalyst. Second, the extraction must be controlled so as not to favor the removal of the low molecular weight wax compounds, i.e., a constant carbon-number distribution of the alkanes in the wax slurry must be maintained at steady-state column operation. During this quarter work focused on task 1b, experimental measurement of selected model systems. Vapor-liquid equilibrium experiments for the n- hexane/squalane system, which we initiated in the previous quarter, were continued and results are discussed in this report.

Joyce, P.C.; Thies, M.C.

1996-09-01T23:59:59.000Z

84

New approach to the generation of metal-bearing, medium-pore, shape-selective zeolites for Fischer-Tropsch catalysis. Spectroscopic studies of zeolites  

SciTech Connect (OSTI)

Two recent developments in zeolite synthesis and modification were successfully combined to demonstrate a new approach to the generation of metal-bearing, medium-pore, shape-selective zeolites for use as catalysts in Fischer-Tropsch conversions. The steps are: (1) synthesis of an aluminoferrisilicate zeolite having the ZSM-5-type structure; (2) removal of the organic base template incorporated in the channel system during synthesis; (3) formation of a polycyano inclusion compound in the AFS zeolite; and (4) reduction of the inclusion compound by hydrogen at approx. 400/sup 0/C. PAS and EPR spectroscopy have been used to establish that the as-synthesized AFS zeolite contains Fe/sup 3 +/ ions in both framework and non-framework sites. FMR spectroscopy has been used to confirm the formation of the metallic (Fe) and bimetallic (Fe/Ru and Fe/Co) particles as products of the reduction of the inclusion compounds by hydrogen. The application of other spectroscopic techniques in recent studies of cations, complexes, and metal particles in zeolites is reviewed: high-resolution solid-state NMR, nuclear-spin-relaxation studies, FMR, EXAFS, and XANES.

Iton, L.E.; Beal, R.B.; Hodul, D.T.

1983-01-01T23:59:59.000Z

85

Separation of Fischer-Tropsch wax from catalyst using supercritical fluid extraction. Quarterly technical progress report, 1 October 1995--31 December 1995  

SciTech Connect (OSTI)

The objective of this research project is to evaluate the potential of supercritical fluid (SCF) extraction for separating the catalyst slurry of a Fischer-Tropsch slurry bubble column (SBC) reactor into two fractions: (1) a catalyst-free wax containing less than 10 ppm particulate matter and (2) a concentrated catalyst slurry that is ready for recycle or regeneration. The wax will be extracted with a hydrocarbon solvent that has a critical temperature near the operating temperature of the SBC reactor, i.e., 200-300{degrees}C. Initial work is being performed using n-hexane as the solvent. During the reporting period, work on the small-scale, continuous-flow apparatus continued. Initial experiments have been performed on a binary mixture of n-hexane (solvent) and squalane (model compound) at 200{degrees}C. A total of fifteen samples were collected at 135, 160, and 208 psig, with pressures being controlled to within {plus_minus}2 psi. Results indicate that the equilibrium phase compositions can in principle be measured to a reproducibility of {plus_minus}0.5% in the squalane-rich bottomphase and {plus_minus}2% in the hexane-rich top phase, with respect to the minor component. However, other data measured at these same conditions at another time exhibited scatter that was as much as 5 times greater. We believe that improvements in (1) the method of preheating the feed to the view cell/phase separator and to (2) the sample collection technique are required before data of high accuracy can consistently be generated. The apparatus modifications required to effect these improvements are currently underway and should be completed by the middle of February.

Thies, M.C.; Joyce, P.C.

1996-06-01T23:59:59.000Z

86

Shape-selective catalysts for Fischer-Tropsch chemistry : atomic layer deposition of active catalytic metals. Activity report : January 1, 2005 - September 30, 2005.  

SciTech Connect (OSTI)

Argonne National Laboratory is carrying out a research program to create, prepare, and evaluate catalysts to promote Fischer-Tropsch (FT) chemistry - specifically, the reaction of hydrogen with carbon monoxide to form long-chain hydrocarbons. In addition to needing high activity, it is desirable that the catalysts have high selectivity and stability with respect to both mechanical strength and aging properties. The broad goal is to produce diesel fraction components and avoiding excess yields of both light hydrocarbons and heavy waxes. Originally the goal was to prepare shape-selective catalysts that would limit the formation of long-chain products and yet retain the active metal sites in a protected 'cage.' Such catalysts were prepared with silica-containing fractal cages. The activity was essentially the same as that of catalysts without the cages. We are currently awaiting follow-up experiments to determine the attrition strength of these catalysts. A second experimental stage was undertaken to prepare and evaluate active FT catalysts formed by atomic-layer deposition [ALD] of active components on supported membranes and particulate supports. The concept was that of depositing active metals (i.e. ruthenium, iron or cobalt) upon membranes with well defined flow channels of small diameter and length such that the catalytic activity and product molecular weight distribution could be controlled. In order to rapidly evaluate the catalytic membranes, the ALD coating processes were performed in an 'exploratory mode' in which ALD procedures from the literature appropriate for coating flat surfaces were applied to the high surface area membranes. Consequently, the Fe and Ru loadings in the membranes were likely to be smaller than those expected for complete monolayer coverage. In addition, there was likely to be significant variation in the Fe and Ru loading among the membranes due to difficulties in nucleating these materials on the aluminum oxide surfaces. The first series of experiments using coated membranes demonstrated that the technology needed further improvement. Specifically, observed catalytic FT activity was low. This low activity appeared to be due to: (1) low available surface area, (2) atomic deposition techniques that needed improvements, and (3) insufficient preconditioning of the catalyst surface prior to FT testing. Therefore, experimentation was expanded to the use of particulate silica supports having defined channels and reasonably high surface area. This later experimentation will be discussed in the next progress report. Subsequently, we plan to evaluate membranes after the ALD techniques are improved with a careful study to control and quantify the Fe and Ru loadings. The preconditioning of these surfaces will also be further developed. (A number of improvements have been made with particulate supports; they will be discussed in the subsequent report.) In support of the above, there was an opportunity to undertake a short study of cobalt/promoter/support interaction using the Advanced Photon Source (APS) of Argonne. Five catalysts and a reference cobalt oxide were characterized during a temperature programmed EXAFS/XANES experimental study with the combined effort of Argonne and the Center for Applied Energy Research (CAER) of the University of Kentucky. This project was completed, and it resulted in an extensive understanding of the preconditioning step of reducing Co-containing FT catalysts. A copy of the resulting manuscript has been submitted and accepted for publication. A similar project was undertaken with iron-containing FT catalysts; the data is currently being studied.

Cronauer, D. C. (Chemical Sciences and Engineering Division)

2011-04-15T23:59:59.000Z

87

Low-Emissions Burner Technology using Biomass-Derived Liquid...  

Broader source: Energy.gov (indexed) [DOE]

Emissions Burner Technology using Biomass-Derived Liquid Fuels Low-Emissions Burner Technology using Biomass-Derived Liquid Fuels This factsheet describes a project that developed...

88

Exploring Hydrogen Generation from Biomass-Derived Sugar and...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Exploring Hydrogen Generation from Biomass-Derived Sugar and Sugar Alcohols to Reduce Costs Exploring Hydrogen Generation from Biomass-Derived Sugar and Sugar Alcohols to Reduce...

89

Stability of Biomass-derived Black Carbon in Soils . | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Stability of Biomass-derived Black Carbon in Soils . Stability of Biomass-derived Black Carbon in Soils . Abstract: Black carbon (BC) may play an important role in the global C...

90

Biomass-Derived Energy Products and Co-Products Market  

E-Print Network [OSTI]

Biomass-Derived Energy Products and Co-Products Market This report identifies the bio-fuels and co & Earth Science & Technology ­ University of Hawai`i at Manoa #12;Biomass-Derived Energy Products and Co agency thereof. #12;Biomass Derived Energy Products and Co- Products Market and Off-take Study Hawaii

91

Catalytic Conversion of Biomass-derived Feedstock (HMF) into...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Industrial Technologies Industrial Technologies Biomass and Biofuels Biomass and Biofuels Find More Like This Return to Search Catalytic Conversion of Biomass-derived Feedstock...

92

Biomass-derived Hydrogen-evolution catalyst and electrode - Energy...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Hydrogen and Fuel Cell Hydrogen and Fuel Cell Find More Like This Return to Search Biomass-derived Hydrogen-evolution catalyst and electrode Brookhaven National Laboratory Contact...

93

Multi-stage Fischer-Tropsch process  

SciTech Connect (OSTI)

A process is described for producing paraffinic hydrocarbons from carbon monoxide and hydrogen comprising: (a) introducing carbon monoxide and hydrogen into a reaction zone wherein the carbon monoxide and hydrogen contact in a first bed a first catalyst having a high olefin selectivity selected from the group consisting of Fe/Ce/Zn/K, Fe/Mn/K and Fe/Co/K; and (b) contacting the resulting olefin in a second bed with a second catalyst having a high selectivity for converting olefins to heavier paraffinic hydrocarbons selected from the group consisting of Ru/TiO/sub 2/, Ru/SiO/sub 2/ and Ru/Al/sub 2/O/sub 3/.

Kim, C.J.; Fiato, R.A.

1986-11-25T23:59:59.000Z

94

Process Intensification in Hydrogen Production from Biomass-Derived Syngas  

Science Journals Connector (OSTI)

Process Intensification in Hydrogen Production from Biomass-Derived Syngas ... A “one-box” process has been proposed and studied in order to economically produce pure hydrogen from biomass-derived syngas in the presence of its common impurities through the use of the water gas shift (WGS) reaction. ... (1) Hydrogen burns cleanly and produces more energy on a per mass basis than any other fuel; if widely adopted for both mobile and stationary power generation, it would reduce the emissions of pollutants typically associated with power production, and would potentially diminish the prospect of global warming. ...

Mitra Abdollahi; Jiang Yu; Hyun Tae Hwang; Paul K. T. Liu; Richard Ciora; Muhammad Sahimi; Theodore T. Tsotsis

2010-09-15T23:59:59.000Z

95

Biomass-Derived Hydrogen from a Thermally Ballasted Gasifier  

E-Print Network [OSTI]

Biomass-Derived Hydrogen from a Thermally Ballasted Gasifier DOE Hydrogen Program Contractors biomass #12;Approach Outline Gasifier Pilot Plant· Develop subsystems for the hydrogen production system and pyrolysis occur simultaneously in a single reactor · Exothermic combustion provides heat · Endothermic

96

An efficient didehydroxylation method for the biomass-derived polyols glycerol and erythritol. Mechanistic studies of a formic acid-mediated  

E-Print Network [OSTI]

-oils from biomass pyrolysis4 and because of its promising role in hydrogen storage through the fixationAn efficient didehydroxylation method for the biomass-derived polyols glycerol and erythritol,2-deoxygenation method, involving an unexpected mechanism, was found for simple diols and for biomass

97

Chemical Kinetic Modeling of Fuels  

Broader source: Energy.gov (indexed) [DOE]

petroleum based fuels * Non-petroleum based fuels: - Biodiesel and new generation biofuels - Fischer-Tropsch (F-T) fuels - Oil sand derived fuels Reduce mechanisms for...

98

Emission characteristics of GTL fuel as an alternative to conventional marine gas oil  

Science Journals Connector (OSTI)

The study examine the gaseous, smoke and particulate matter emission characteristics of a turbocharged heavy-duty diesel engine operated on conventional marine gas oil and gas-to-liquid Fischer–Tropsch fuel under modes of propulsion and generator operation. The gas-to-liquid showed average reductions up to 19% in nitrogen oxides, 25% in carbon monoxide, 4% in carbon dioxide and 30% in smoke with slight increase in unburned hydrocarbon emissions. Particulate number concentrations for gas-to-liquid were up to 21% higher, whereas particulates mass showed a 16% decrease at medium and high loads, while increasing by 12–15% under lower load conditions. Very low aromatic content of gas-to-liquid fuel and nearly zero sulfur level are responsible for particulate reduction.

Sergey Ushakov; Nadine G.M. Halvorsen; Harald Valland; Dag H. Williksen; Vilmar Æsøy

2013-01-01T23:59:59.000Z

99

Activation studies with promoted precipitated iron Fischer-Tropsch catalysts  

E-Print Network [OSTI]

the Ruhrchemie catalyst, the catalyst activity and stability changed markedly with reduction procedure. Hs reduction at 220'C was repeated since it gave very loiv activity. The reproducibility of this test ivas good. Hs reduction at 250 gave higher catalyst...

Manne, Rama Krishna

1991-01-01T23:59:59.000Z

100

Cobalt-ruthenium catalysts for Fischer-Tropsch synthesis  

SciTech Connect (OSTI)

A hydrocarbon synthesis process is described which comprises reacting hydrogen and carbon monoxide in the presence of a catalyst comprised of cobalt and ruthenium on titania, at reaction conditions suitable for the formation of higher hydrocarbons. The catalyst is prepared by impregnating titania with solutions of cobalt and ruthenium salts, drying the impregnated support, reducing the cobalt and ruthenium, treating the reduced metals with an oxygen containing stream at conditions sufficient to form oxides of cobalt and oxides of ruthenium and reducing the cobalt and ruthenium oxides.

Iglesia, E.; Soled, S.L.; Fiato, R.A.

1989-04-18T23:59:59.000Z

Note: This page contains sample records for the topic "oils biomass-derived fischer-tropsch" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Development and Demonstration of Fischer-Tropsch Fueled Heavy...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

(F-T) Fuels in the U.S. -- An Overview APBF-DEC Heavy Duty NOx AdsorberDPF Project: Heavy Duty Linehaul Platform Project Update Coal-Derived Liquids to Enable HCCI Technology...

102

Subtask 3.4 - Fischer - Tropsch Fuels Development  

SciTech Connect (OSTI)

Under Subtask 3.4, the Energy & Environmental Research Center (EERC) examined the opportunities and challenges facing Fischerâ??Tropsch (FT) technology in the United States today. Work was completed in two distinct budget periods (BPs). In BP1, the EERC examined the technical feasibility of using modern warm-gas cleanup techniques for FT synthesis. FT synthesis is typically done using more expensive and complex cold-gas sweetening. Warm-gas cleanup could greatly reduce capital and operating costs, making FT synthesis more attractive for domestic fuel production. Syngas was generated from a variety of coal and biomass types; cleaned of sulfur, moisture, and condensables; and then passed over a pilot-scale FT catalyst bed. Laboratory and modeling work done in support of the pilot-scale effort suggested that the catalyst was performing suboptimally with warm-gas cleanup. Long-term trends showed that the catalyst was also quickly deactivating. In BP3, the EERC compared FT catalyst results using warm-gas cleanup to results using cold-gas sweetening. A gas-sweetening absorption system (GSAS) was designed, modeled, and constructed to sweeten syngas between the gasifier and the pilot-scale FT reactor. Results verified that the catalyst performed much better with gas sweetening than it had with warm-gas cleanup. The catalyst also showed no signs of rapid deactivation when the GSAS was running. Laboratory tests in support of this effort verified that the catalyst had deactivated quickly in BP1 because of exposure to syngas, not because of any design flaw with the pilot-scale FT reactor itself. Based on these results, the EERC concludes that the two biggest issues with using syngas treated with warm-gas cleanup for FT synthesis are high concentrations of CO{sub 2} and volatile organic matter. Other catalysts tested by the EERC may be more tolerant of CO{sub 2}, but volatile matter removal is critical to ensuring long-term FT catalyst operation. This subtask was funded through the EERCâ??U.S. Department of Energy (DOE) Joint Program on Research and Development for Fossil Energy-Related Resources Cooperative Agreement No. DE-FC26-08NT43291. Nonfederal funding for BP1 was provided by the North Dakota Industrial Commissionâ??s (NDIC) Renewable Energy Council.

Joshua Strege; Anthony Snyder; Jason Laumb; Joshua Stanislowski; Michael Swanson

2012-05-01T23:59:59.000Z

103

VLE MEASUREMENTS FOR ASYMMETRIC MIXTURES OF FISCHER-TROPSCH HYDROCARBONS  

SciTech Connect (OSTI)

The ability to model the thermodynamic phase behavior of long-chain and short-chain alkane mixtures is of considerable industrial and theoretical interest. However, attempts to accurately describe the phase behavior of what we call asymmetric mixtures of hydrocarbons (AMoHs) have met with only limited success. Vapor-liquid equilibrium (VLE) data are surprisingly scarce, and the limited data that are available suggest that cubic equations of state may not be capable of fitting (much less predicting) the phase behavior of AMoHs. The following tasks, which address the problems described above, were accomplished during the one-year period of this Phase I UCR grant: (1) A continuous-flow apparatus was modified for the measurement of AMoHs and used to measure VLE for propane + hexadecane mixtures at temperatures from 473 to 626 K and pressures up to the mixture critical pressures of about 100 bar. (2) The extent to which cubic vs. modern, statistical mechanics-based equations of state (EoS) are applicable to AMoHs was evaluated. Peng-Robinson (PR) was found to be a surprisingly accurate equation for fitting AMoHs, but only if its pure component parameters were regressed to liquid densities and vapor pressures. However, even this form of PR was still not a predictive equation, as there was a significant variation of kij with temperature. In spite of its deficiencies in terms of vapor-phase predictions and modeling of the critical region, PC-SAFT was found to be the most appropriate EoS for truly predicting the phase behavior of highly asymmetric mixtures of alkanes. (3) Finally, a dense-gas extraction (DGE) apparatus was designed and constructed for the fractionation of F-T waxes into cuts of pure oligomers. Such oligomers are needed in g-sized quantities to perform VLE measurements with long-chain alkanes with carbon numbers greater than 40. The dense gas and the solute mixture to be extracted are contacted in a packed column that has a separation power significantly greater than what can be achieved in one equilibrium stage. Thus, wax oligomer purities are expected to be much better than what can be obtained by conventional supercritical extraction processes.

Mark C. Thies

2004-01-12T23:59:59.000Z

104

Hydrogen Production from Biomass-Derived Syngas Using a Membrane Reactor Based Process  

Science Journals Connector (OSTI)

(1) One of the benefits of adopting H2 as an energy source, in addition to reducing CO2 emissions, is that it can be produced from readily available and plentiful raw materials such as coal and renewable biomass; this then diminishes the need to use the world’s dwindling crude-oil resources. ... For that, coal must be first gasified with air or pure O2 at high temperatures(2) to produce coal-gasifier off-gas (or syngas), containing as key species H2, CO, CO2, H2O, CH4, and other byproducts such as organic vapors, tars, H2S, and NH3, etc.,(2) the exact composition depending on the operating conditions, e.g., pressure, temperature, type of coal and oxidant used and their flow rates, and gasifier configuration, etc.(2) ... A novel MR system termed as the “one-box” process, in which syngas cleanup, hydrogen production via the WGS reaction, and product separation are combined in the same unit, was successfully utilized for producing hydrogen from a feed with a simulated biomass-derived syngas containing common impurities such as H2S and NH3, a model organic vapor (toluene), and a model tar-like species (naphthalene). ...

Jiang Yu; Mingyang Tan; Paul K. T. Liu; Muhammad Sahimi; Theodore T. Tsotsis

2013-12-27T23:59:59.000Z

105

Pressurised Combustion of Biomass-Derived, Low Calorific Value, Fuel Gas  

Science Journals Connector (OSTI)

During a 3 year (1996 – 1998) project, partly funded by the EU as part of their JOULE 3 programme, experimental and theoretical research will be done on the pressurised combustion of biomass-derived, LCV, fuel ga...

J. Andries; P. D. J. Hoppesteyn…

1997-01-01T23:59:59.000Z

106

Methods and apparatuses for preparing upgraded pyrolysis oil  

DOE Patents [OSTI]

Methods and apparatuses for preparing upgraded pyrolysis oil are provided herein. In an embodiment, a method of preparing upgraded pyrolysis oil includes providing a biomass-derived pyrolysis oil stream having an original oxygen content. The biomass-derived pyrolysis oil stream is hydrodeoxygenated under catalysis in the presence of hydrogen to form a hydrodeoxygenated pyrolysis oil stream comprising a cyclic paraffin component. At least a portion of the hydrodeoxygenated pyrolysis oil stream is dehydrogenated under catalysis to form the upgraded pyrolysis oil.

Brandvold, Timothy A; Baird, Lance Awender; Frey, Stanley Joseph

2013-10-01T23:59:59.000Z

107

Biomass-Derived Platform Chemicals: Thermodynamic Studies on the Conversion of 5-Hydroxymethylfurfural into Bulk Intermediates  

Science Journals Connector (OSTI)

Biomass-Derived Platform Chemicals: Thermodynamic Studies on the Conversion of 5-Hydroxymethylfurfural into Bulk Intermediates ... This work was undertaken to obtain new thermochemical data for 5-hydroxymethylfurfural (HMF) and parent compounds. ... Cellulose and other carbohydrates (e.g., glucose and fructose) can be converted into furanic biofuels via 5-hydroxymethylfurfural (HMF), using relatively simple processes such as condensation and hydrogenation reactions. ...

Sergey P. Verevkin; Vladimir N. Emel’yanenko; Elena N. Stepurko; Richardas V. Ralys; Dmitry H. Zaitsau; Annegret Stark

2009-09-11T23:59:59.000Z

108

Hydrodeoxygenation processes: Advances on catalytic transformations of biomass-derived platform chemicals into hydrocarbon fuels  

Science Journals Connector (OSTI)

Abstract Lignocellulosic biomass provides an attractive source of renewable carbon that can be sustainably converted into chemicals and fuels. Hydrodeoxygenation (HDO) processes have recently received considerable attention to upgrade biomass-derived feedstocks into liquid transportation fuels. The selection and design of HDO catalysts plays an important role to determine the success of the process. This review has been aimed to emphasize recent developments on HDO catalysts in effective transformations of biomass-derived platform molecules into hydrocarbon fuels with reduced oxygen content and improved H/C ratios. Liquid hydrocarbon fuels can be obtained by combining oxygen removal processes (e.g. dehydration, hydrogenation, hydrogenolysis, decarbonylation etc.) as well as by increasing the molecular weight via C–C coupling reactions (e.g. aldol condensation, ketonization, oligomerization, hydroxyalkylation etc.). Fundamentals and mechanistic aspects of the use of HDO catalysts in deoxygenation reactions will also be discussed.

Sudipta De; Basudeb Saha; Rafael Luque

2014-01-01T23:59:59.000Z

109

FY 2012 Progress Report for Fuel & Lubricant Technologies  

Energy Savers [EERE]

For example, oil-sand-derived fuels from Canada, Fischer-Tropsch fuels made from natural gas, and biofuels derived from fats and vegetable oils will play increasingly important...

110

Lattice-Matched Bimetallic CuPd-Graphene Nanocatalysts for Facile Conversion of Biomass-Derived Polyols to Chemicals  

Science Journals Connector (OSTI)

Lattice-Matched Bimetallic CuPd-Graphene Nanocatalysts for Facile Conversion of Biomass-Derived Polyols to Chemicals ... A bimetallic nanocatalyst with unique surface configuration displays extraordinary performance for converting biomass-derived polyols to chemicals, with potentially much broader applications in the design of novel catalysts for several reactions of industrial relevance. ... Dehydrogenated species are instantaneously converted to LA(37, 41) (with OH–) or alcoholic chemicals(15, 39) (by in situ formed hydrogen) in alkaline medium. ...

Xin Jin; Lianna Dang; Jessica Lohrman; Bala Subramaniam; Shenqiang Ren; Raghunath V. Chaudhari

2013-01-08T23:59:59.000Z

111

Hydroprocessing of Biomass-Derived Oils and Their Blends with Petroleum Feedstocks: A Review  

Science Journals Connector (OSTI)

The main focus of this review is to provide an understanding of the effects of biomass feedstocks on process operation, catalyst performance and deactivation, feedstock conversion, and product yield and quality. ...

Mustafa Al-Sabawi; Jinwen Chen

2012-06-21T23:59:59.000Z

112

Miscibility of Ethanol in Diesel Fuels  

Science Journals Connector (OSTI)

The fuels selected were as follows:? US-1D, US-2D, kerosene, light cycle oil, #1 fuel oil, Fischer Tropsch Liquid 2 (FTL-2, FTL refers to a broad-cut fraction of Fischer?Tropsch products not meeting diesel volatility specifications.), ... The close proximity of a mixture's UCST to the fuel's cloud point masked the classical UCST phase behavior for the FTL fuels and light cycle oil; however, the general trends persisted. ...

K. R. Gerdes; G. J. Suppes

2001-01-12T23:59:59.000Z

113

Biomass-Derived Platform Chemicals: Thermodynamic Studies on the Extraction of 5-Hydroxymethylfurfural from Ionic Liquids  

Science Journals Connector (OSTI)

Biomass-Derived Platform Chemicals: Thermodynamic Studies on the Extraction of 5-Hydroxymethylfurfural from Ionic Liquids ... Furthermore, the solubility of 5-hydroxymethylfurfural (HMF) in these solutes and the solubility of the solutes in 1-butyl-3-methylimidazolium methanesulfonate ([C4mim][CH3SO3]) was assessed. ... In the past 20 years, a large body of work has been conducted on the condensation of fructose and other carbohydrates to 5-hydroxymethylfurfural (HMF), which, due to its multifunctionality, has been claimed a prime platform chemical derived from biomass (Scheme 1). ...

Annegret Stark; Bernd Ondruschka; Dzmitry H. Zaitsau; Sergey P. Verevkin

2012-10-15T23:59:59.000Z

114

Chemoselective Hydrogenation of Biomass-Derived 5-Hydroxymethylfurfural into the Liquid Biofuel 2,5-Dimethylfuran  

Science Journals Connector (OSTI)

Chemoselective Hydrogenation of Biomass-Derived 5-Hydroxymethylfurfural into the Liquid Biofuel 2,5-Dimethylfuran ... In recent years, 2,5-dimethylfuran (DMF), which is produced by the selective hydrogenation of biomass-derived 5-hydroxymethylfurfural (HMF) and is considered as a new-fashioned liquid biofuel for transportation, has received much more attention from many researchers in the world. ... Among the various desired compounds via the oriented transformation,(15-19) 5-hydroxymethylfurfural (HMF) is considered as a versatile platform compound (Scheme 1) and a crucial intermediate for connecting biomass resource and fossil industry,(20-24) and this is because that it can be further transformed into a series of high-quality fuels such as ethyl levulinate (EL),(25-27) 5-ethoxymethylfurfural (EMF),(28-30) 2,5-dimethylfuran (DMF),(31-33) and C9–C15 alkanes(34-36) and high-value chemicals such as levulinic acid (LA),(37-39) 2,5-dihydroxymethylfuran (DHMF),(40-42) 2,5-diformylfuran (DFF),(43-45) and 2,5-furandicarboxylic acid (FDCA). ...

Lei Hu; Lu Lin; Shijie Liu

2014-05-23T23:59:59.000Z

115

Chemical looping combustion of biomass-derived syngas using ceria-supported oxygen carriers  

Science Journals Connector (OSTI)

Abstract Cu, Ni and Fe oxides supported on ceria were investigated for their performance as oxygen carriers during the chemical looping combustion of biomass-derived syngas. A complex gas mixture containing CO, H2, CO2, CH4 and other hydrocarbons was used to simulate the complex fuel gas environment derived from biomass gasification. Results show that the transfer of the stored oxygen into oxidants for the supported Cu and Ni oxides at 800 °C for the combustion of syngas was effective (>85%). The unsupported Cu oxide showed high oxygen carrying capacity but particle sintering was observed at 800 °C. A reaction temperature of 950 °C was required for the supported Fe oxides to transfer the stored oxygen into oxidants effectively. Also, for the complex fuel gas environment, the supported Ni oxide was somewhat effective in reforming CH4 and other light hydrocarbons into CO, which may have benefits for the reduction of tar produced during biomass pyrolysis.

H.B. Huang; L. Aisyah; P.J. Ashman; Y.C. Leung; C.W. Kwong

2013-01-01T23:59:59.000Z

116

One-Step Conversion of Biomass-Derived 5-Hydroxymethylfurfural to 1,2,6-Hexanetriol Over Ni–Co–Al Mixed Oxide Catalysts Under Mild Conditions  

Science Journals Connector (OSTI)

One-Step Conversion of Biomass-Derived 5-Hydroxymethylfurfural to 1,2,6-Hexanetriol Over Ni–Co–Al Mixed Oxide Catalysts Under Mild Conditions ... A sustainable process with a one-step conversion of biomass-derived 5-hydroxymethylfurfural (HMF) to 1,2,6-hexanetriol is presented. ... The conversion of biomass-derived 5-hydroxymethylfurfural (HMF) was examined over Ni–Co–Al mixed oxide catalysts derived from corresponding hydrotalcite-like compounds (HTlcs). ...

Shengxi Yao; Xicheng Wang; Yijun Jiang; Feng Wu; Xinguo Chen; Xindong Mu

2013-10-01T23:59:59.000Z

117

Dried chitosan-gels as organocatalysts for the production of biomass-derived platform chemicals  

Science Journals Connector (OSTI)

Aldol condensations between sugar-derived dehydrated aldehydes (e.g. furfural) and acetone have been proposed as a route to provide useful biomass-derived chemicals. In the quest of sustainable catalytic ways for such aldol condensations, this paper assesses the use of dried chitosan-gels as naturally-immobilized, readily available and non-hazardous amino-based organocatalysts. At room temperature chitosan dried gels are not suitable catalysts for the desired reaction. However, at higher temperatures (>90 °C) reaction proceeds efficiently either in solvent-free systems (with addition of catalytic amounts of water) or in water. The set-up of closed reactor set-ups (thermoshakers or microwave reactions) proved highly beneficial for the reaction outcome. Furthermore, chitosan dried gels were successfully re-used for a number of cycles. An efficient catalyst drying method (either lyophilization or scCO2 drying) was crucial to achieve virtually full conversions in 4 h. After pertinent further process optimization, dried chitosan-gels may become very useful catalysts for their use in biomass-based reactions in biorefineries.

Henning Kayser; Christoph R. Müller; Carlos A. García-González; Irina Smirnova; Walter Leitner; Pablo Domínguez de María

2012-01-01T23:59:59.000Z

118

Deconstruction of Lignin Model Compounds and Biomass-Derived Lignin using Layered Double Hydroxide Catalysts  

SciTech Connect (OSTI)

Lignin is an underutilized value stream in current biomass conversion technologies because there exist no economic and technically feasible routes for lignin depolymerization and upgrading. Base-catalyzed deconstruction (BCD) has been applied for lignin depolymerization (e.g., the Kraft process) in the pulp and paper industry for more than a century using aqueous-phase media. However, these efforts require treatment to neutralize the resulting streams, which adds significantly to the cost of lignin deconstruction. To circumvent the need for downstream treatment, here we report recent advances in the synthesis of layered double hydroxide and metal oxide catalysts to be applied to the BCD of lignin. These catalysts may prove more cost-effective than liquid-phase, non-recyclable base, and their use obviates downstream processing steps such as neutralization. Synthetic procedures for various transition-metal containing catalysts, detailed kinetics measurements using lignin model compounds, and results of the application of these catalysts to biomass-derived lignin will be presented.

Chmely, S. C.; McKinney, K. A.; Lawrence, K. R.; Sturgeon, M.; Katahira, R.; Beckham, G. T.

2013-01-01T23:59:59.000Z

119

Dynamic molecular structure of plant biomass-derived black carbon (biochar)  

SciTech Connect (OSTI)

Char black carbon (BC), the solid residue of incomplete combustion, is continuously being added to soils and sediments due to natural vegetation fires, anthropogenic pollution, and new strategies for carbon sequestration ('biochar'). Here we present a molecular-level assessment of the physical organization and chemical complexity of biomass-derived chars and, specifically, that of aromatic carbon in char structures. BET-N{sub 2} surface area, X-ray diffraction (XRD), synchrotron-based Near-edge X-ray Absorption Fine Structure (NEXAFS), and Fourier transform infrared (FT-IR) spectroscopy are used to show how two plant materials (wood and grass) undergo analogous, but quantitatively different physical-chemical transitions as charring temperature increases from 100 to 700 C. These changes suggest the existence of four distinct categories of char consisting of a unique mixture of chemical phases and physical states: (i) in transition chars the crystalline character of the precursor materials is preserved, (ii) in amorphous chars the heat-altered molecules and incipient aromatic polycondensates are randomly mixed, (iii) composite chars consist of poorly ordered graphene stacks embedded in amorphous phases, and (iv) turbostratic chars are dominated by disordered graphitic crystallites. The molecular variations among the different char categories translate into differences in their ability to persist in the environment and function as environmental sorbents.

Keiluweit, M.; Nico, P.S.; Johnson, M.G.; Kleber, M.

2009-11-15T23:59:59.000Z

120

Volatility of Mixtures of JP-8 with Biomass Derived Hydroprocessed Renewable Jet Fuels by the Composition Explicit Distillation Curve Method  

Science Journals Connector (OSTI)

Volatility of Mixtures of JP-8 with Biomass Derived Hydroprocessed Renewable Jet Fuels by the Composition Explicit Distillation Curve Method ... Energy Fuels, 2012, 26 (3), ... There are many reasons for this, the most important of which are guarding against potential supply disruptions, overcoming the dependence on foreign sources of petroleum, overcoming the vulnerability of large centralized refineries (to both weather events and terrorist acts), and mitigation of the rising costs of current fuel streams. ...

Jean Van Buren; Kathryn Abel; Tara M. Lovestead; Thomas J. Bruno

2012-02-28T23:59:59.000Z

Note: This page contains sample records for the topic "oils biomass-derived fischer-tropsch" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Environmentally Friendly Oxidation of Biomass Derived 5-Hydroxymethylfurfural into 2,5-Diformylfuran Catalyzed by Magnetic Separation of Ruthenium Catalyst  

Science Journals Connector (OSTI)

Environmentally Friendly Oxidation of Biomass Derived 5-Hydroxymethylfurfural into 2,5-Diformylfuran Catalyzed by Magnetic Separation of Ruthenium Catalyst ... In this study, aerobic oxidation of 5-hydroxymethylfurfural (HMF) to 2,5-diformylfuran (DFF) was studied over a magnetic catalyst [Fe3O4@SiO2-NH2-Ru(III)]. ... 5-Hydroxymethylfurfural (HMF), which is generated by the dehydration of C6-based carbohydrates, is considered to be a key platform molecule. ...

Shuguo Wang; Zehui Zhang; Bing Liu; Jinlin Li

2014-03-12T23:59:59.000Z

122

Synthesis of Aromatic-Rich Gasoline-Range Hydrocarbons from Biomass-Derived Syngas over a Pd-Promoted Fe/HZSM-5 Catalyst  

Science Journals Connector (OSTI)

Synthesis of Aromatic-Rich Gasoline-Range Hydrocarbons from Biomass-Derived Syngas over a Pd-Promoted Fe/HZSM-5 Catalyst ... The cool syngas was then compressed to a storage tank or sent to a burner. ...

Qiangu Yan; Yongwu Lu; Caixia Wan; Jun Han; Jose Rodriguez; Jing-jing Yin; Fei Yu

2014-02-26T23:59:59.000Z

123

Glycolaldehyde as a Probe Molecule for Biomass Derivatives: Reaction of C—OH and C?O Functional Groups on Monolayer Ni Surfaces  

Science Journals Connector (OSTI)

Controlling the activity and selectivity of converting biomass derivatives to syngas (H2 and CO) is critical for the utilization of biomass feedstocks as renewable sources for chemicals and fuels. ...

Weiting Yu; Mark A. Barteau; Jingguang G. Chen

2011-11-08T23:59:59.000Z

124

ULTRA-CLEAN FISCHER-TROPSCH FUELS PRODUCTION AND DEMONSTRATION PROJECT  

SciTech Connect (OSTI)

The Report Abstract provides summaries of the past year's activities relating to each of the main project objectives. Some of the objectives will be expanded on in greater detail further down in the report. The following objectives have their own addition sections in the report: SFP Construction and Fuel Production, Impact of SFP Fuel on Engine Performance, Fleet Testing at WMATA and Denali National Park, Demonstration of Clean Diesel Fuels in Diesel Electric Generators in Alaska, and Economic Analysis. ICRC provided overall project organization and budget management for the project. ICRC held meetings with various project participants. ICRC presented at the Department of Energy's annual project review meeting. The plant began producing fuel in October 2004. The first delivery of finished fuel was made in March of 2004 after the initial start-up period.

Steve Bergin

2004-10-18T23:59:59.000Z

125

Processes and palladium-promoted catalysts for conducting Fischer-Tropsch synthesis  

DOE Patents [OSTI]

A process for hydrocarbon synthesis comprising the step of reacting a synthesis gas in the presence of a cobalt catalyst promoted with palladium.

Singleton, Alan H. (Baden, PA); Oukaci, Rachid (Gibsonia, PA); Goodwin, James G. (Cranberry Township, PA)

2000-01-01T23:59:59.000Z

126

Safety and Techno-Economic Analysis of Solvent Selection for Supercritical Fischer-Tropsch Synthesis Reactors  

E-Print Network [OSTI]

of the fixed-bed reactor, among other disadvantages, is that the reaction is very exothermic, which is a concern in terms of safety hazards and also in terms of cost of heat removal. With the slurry reactor, a problem is that in the liquid media... at different lengths.4 After the reaction takes place, the amount of carbon monoxide consumed decreases and carbon dioxide is produced as a side product.9 The FTS reaction is an extremely exothermic process, which represents serious challenges...

Hamad, Natalie

2012-02-14T23:59:59.000Z

127

Effect of Liquid Composition on the Slurry Fischer-Tropsch Synthesis. 1. Rate of Reaction  

SciTech Connect (OSTI)

With a reduced fused magnetite catalyst, the rate of reaction in the presence of phenanthrene is nearly twice that observed in the presence of n-octacosane even though the solubility of H/sub 2/ and CO is moderately less in phenanthrene. The rate in the presence of triphenylmethane was about the same as in n-octacosane. In the presence of a perfluoropolyether, the rate of reaction was markedly reduced, even though H/sub 2/ and CO solubilities are much higher than in hydrocarbons. This was attributed to substantial mass transfer resistances through an encapsulating hydrocarbon layer around the catalyst particles. The effect of the nature of a liquid on several other reactions is also discussed.

Satterfield, C.N.; Stenger, H.G.

1984-04-01T23:59:59.000Z

128

Effect of Liquid Composition on the Slurry Fischer-Tropsch Synthesis. 2. Product Selectivity  

SciTech Connect (OSTI)

With a reduced, fused magnetite catalyst, secondary reactions, consisting of olefin hydrogenation, olefin isomerization, and incorporation of ethylene and/or ethyl alcohol into product, were slightly greater in octacosane than in phenanthrene at 232/sup 0/C but essentially the same at 263/sup 0/C. This is attributed to competitiv adsorption effects with phenanthrene which adsorbs significantly onto the catalyst at 232/sup 0/C, but not at 263/sup 0/C. All secondary reactions are enhanced by conditions minimizing CO adsorption. Oxygenates were greatly diminished at high conversions. C/sub 2/ incorporation into product stops chain growth by a scavenging effect. In the presence of a perfluoropolyether (Fomblin), in which hydrocarbons are immiscible, catalyst is preferentially wetted by hydrocarbons and secondary reactions are greatly enhanced by mass transfer resistances.

Stenger, H.G.; Satterfield, C.N.

1984-04-01T23:59:59.000Z

129

Separation of Fischer-Tropsch Wax from Catalyst by Supercritical Extraction  

SciTech Connect (OSTI)

Further progress in achieving the objectives of the project was made in the period of January I to March 31, 1998. The direct numerical simulation of particle removal process in turbulent gas flows was completed. Variations of particle trajectories are studied. It is shown that the near wall vortices profoundly affect the particle removal process in turbulent boundary layer flows. Experimental data for transport and deposition of fibrous particles in the aerosol wind tunnel was obtained. The measured deposition velocity for irregular fibrous particles is compared with the empirical correlation and the available data for glass fibers and discussed. Additional progress on the sublayer model for evaluating the particle deposition and resuspension in turbulent flows was made.

Mark C. Thies; Patrick C. Joyce

1998-01-31T23:59:59.000Z

130

Fischer-Tropsch synthesis over a fused iron catalyst in a three phase slurry reactor  

E-Print Network [OSTI]

variables and ranges were temperature, 235 C to 280 C, pressure, 200 to 400 psig, space velocity, 0, 71 to 4. 5N liter/hr gram unreduced catalyst and H /CO feed, 0. 64 to 2. 4. Increases in temperature and space velocity were found to shift product... Neter; L Drierite Tube; N Vater Saturator; N Vet Test Meter. 24 Catalyst Transfer Configuration for Catalyst Charging. 26 3-4 Carle Refinery Gas Analyzer Chromatogram for Gas Phase Analysis of Light Gases from Run 510. 29 3-5 Varian Aerograph...

Buck, Henry J

2012-06-07T23:59:59.000Z

131

Influence of Biodiesel Addition to Fischer?Tropsch Fuel on Diesel Engine Performance and Exhaust Emissions  

Science Journals Connector (OSTI)

Zhu, R.; Wang, X.; Miao, H.; Huang, Z.; Gao, J.; Jiang, D.Performance and Emission Characteristics of Diesel Engines Fueled with Diesel-Dimethoxymethane (DMM) Blends Energy Fuels 2009, 23, 286– 293 ... Results showed that, without changing the fuel supply system and the combustion system of a diesel engine, when using blended fuel with increased DMM percentage, break-specific fuel consumption (BSFC) is higher for a smaller lower heating value of DMM, while thermal efficiency increases a little. ... To investigate influences of fuel design on regulated and non-regulated emissions of heavy-duty diesel engines, a Mercedes-Benz OM 906 Euro 3 engine was run with common diesel fuel (DF), first- and second-generation alternative fuels (Gas-to-liq. ...

Md. Nurun Nabi; Johan Einar Hustad

2010-04-14T23:59:59.000Z

132

Making Fischer?Tropsch Fuels and Electricity from Coal and Biomass: Performance and Cost Analysis  

Science Journals Connector (OSTI)

We employ a unified analytical framework to systematically analyze 16 separate process designs, simulating for each detailed mass/energy balances using Aspen Plus software, and calculating their full lifecycle greenhouse gas (GHG) emissions. ... In the plant designs with electricity as a major coproduct, designated as “once-through” (OT) configurations (Figure 1b), the syngas passes only once through the synthesis reactor, and all of the unconverted syngas plus light gases from FTL refining are compressed and supplied to the power island where a gas turbine/steam turbine combined cycle (GTCC) provides the power needed to operate the plant, as well as a substantial amount of export power (up to 37% of the total plant output of fuel (LHV) and power—see Table 3). ... (27) The gasifier is followed by a tar cracking unit, modeled as an ATR with a syngas exit temperature of 882 °C that converts into syngas the heavy hydrocarbons that form at typical biomass gasification temperatures and that would otherwise condense and cause operating difficulties downstream. ...

Guangjian Liu; Eric D. Larson; Robert H. Williams; Thomas G. Kreutz; Xiangbo Guo

2010-12-06T23:59:59.000Z

133

Development of a Fischer-Tropsch Gasoline Process for the Steam Hydrogasification Technology  

E-Print Network [OSTI]

Industrial   &  engineering  chemistry  research,  2005.  Industrial   &   engineering   chemistry   research,  Industrial   &   engineering   chemistry  research,  1995.  

Li, Yang

2013-01-01T23:59:59.000Z

134

Co/Pillared Clay Bifunctional Catalyst for Controlling the Product Distribution of Fischer?Tropsch Synthesis  

Science Journals Connector (OSTI)

The results indicate that the activities of the catalysts (i.e., CO conversions) increase in the order of Co/Na-Clay ? Co/Si-PILC ? Co/acid-clay ? Co/Al-PILC PILC ? Co/SiO2. ... After calcination at 773 K for 4 h, zirconia-pillared clay (Zr-PILC) was obtained. ... Following the same procedure as used for preparing Zr-PILC, Al-PILC and Si-PILC were obtained. ...

Qing-Qing Hao; Guang-Wei Wang; Zhao-Tie Liu; Jian Lu; Zhong-Wen Liu

2010-08-30T23:59:59.000Z

135

Fischer?Tropsch Synfuels from Biomass: Maximizing Carbon Efficiency and Hydrocarbon Yield  

Science Journals Connector (OSTI)

This paper collects yield and efficiency estimates for FT synfuel production from biomass feedstocks. ... In comparison to other biofuels, advantages include (i) flexible use of all kinds of biomass feedstocks (including waste materials) and, therefore, no competition with the production of food, (ii) relatively high yields per arable land (100?180 GJ ha?1 year?1), and (iii) high fuel qualities to be used in present distribution infrastructures and high-efficiency engine technologies. ... Flow scheme for the conversion of biomass feedstocks to liquid hydrocarbon fuels (BTL) and formal chemical reactions. ...

Dominik Unruh; Kyra Pabst; Georg Schaub

2010-03-30T23:59:59.000Z

136

Performance Synergies between Low-Temperature and High-Temperature Fischer?Tropsch Diesel Blends  

Science Journals Connector (OSTI)

With both LTFT and HTFT diesels being nontraditional, alternative diesel fuels that can be used directly in the current fuelling infrastructure, the objective of this study was to investigate the potential synergies in fuel properties with blends of LTFT diesel and HTFT DHT diesel. ... Regulated exhaust emissions measured over the engine dynamometer test cycle in grams of pollutant per unit of mechanical energy delivered by the engine (g/kW h) included total hydrocarbon (THC), generally referred to as HC, CO, carbon dioxide (CO2), NOx, and PM. ... However, the general consumer should most probably not be able to notice the difference in volumetric fuel consumption. ...

Delanie Lamprecht; Luis P. Dancuart; Kaveer Harrilall

2007-08-31T23:59:59.000Z

137

Ultra-Clean Fischer-Tropsch Fuels Production and Demonstration Project  

SciTech Connect (OSTI)

The Report Abstract provides summaries of the past year's activities relating to each of the main project objectives. Some of the objectives will be expanded on in greater detail further down in the report. The following objectives have their own addition sections in the report: Dynamometer Durability Testing, the Denali Bus Fleet Demonstration, Bus Fleet Demonstrations Emissions Analysis, Impact of SFP Fuel on Engine Performance, Emissions Analysis, Feasibility Study of SFPs for Rural Alaska, and Cold Weather Testing of Ultra Clean Fuel.

Steve Bergin

2005-10-14T23:59:59.000Z

138

Technology Development for Iron and Cobalt Fischer-Tropsch Catalysts Quarterly Report  

E-Print Network [OSTI]

as an account of work sponsored by an agency of the United States Government. Neither the United States agency thereof. #12;2 Abstract CAER Tight control of catalyst distribution within SBCRs should . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 Abstract . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

Kentucky, University of

139

A study of Fischer-Tropsch model compounds reacting over ZSM-5  

E-Print Network [OSTI]

on small hydrocarbons have been studied by many investigators. The conversion of methanol to I , hydrocarbons has been studied by Chang and Silvestri (1977), Derouane, et ' al. (1978), Anderson, et al. (1979), Dejaifve, et al. (1980), and Vedrine, et al... on small hydrocarbons have been studied by many investigators. The conversion of methanol to I , hydrocarbons has been studied by Chang and Silvestri (1977), Derouane, et ' al. (1978), Anderson, et al. (1979), Dejaifve, et al. (1980), and Vedrine, et al...

Riley, Mark Garner

2012-06-07T23:59:59.000Z

140

Separation of Fischer-Tropsch Wax from Catalyst by Supercritical Extraction  

SciTech Connect (OSTI)

Further progress in achieving the objectives of the project was made in the period of January I to March 31, 1998. The direct numerical simulation of particle removal process in turbulent gas flows was completed. Variations of particle trajectories are studied. It is shown that the near wall vortices profoundly affect the particle removal process in turbulent boundary layer flows. Experimental data for transport and deposition of fibrous particles in the aerosol wind tunnel was obtained. The measured deposition velocity for irregular fibrous particles is compared with the empirical correlation and the available data for glass fibers and discussed. Additional progress on the sublayer model for evaluating the particle deposition and resuspension in turbulent flows was made.

Mark C. Thies; Patrick C. Joyce

1998-04-30T23:59:59.000Z

Note: This page contains sample records for the topic "oils biomass-derived fischer-tropsch" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Emissions Characteristics of a Turbine Engine and Research Combustor Burning a Fischer?Tropsch Jet Fuel  

Science Journals Connector (OSTI)

GTL and CTL technologies were discovered in Germany in the mid-1910s and further developed in 1923 by German scientists Drs. ... The Department of Energy (DOE) National Energy Technology Laboratory and the Fuels Branch of the Air Force Research Laboratory (AFRL/PRTG) established a collaborative research and development program in 2000 to study and demonstrate clean aviation fuels as part of the DOE Ultra Clean Transportation Fuels Initiative. ... 21 Gaseous emissions were quantified using an MKS MultiGas 2030 Fourier-transform infrared based gas analyzer and a flame ionization detector based total hydrocarbon analyzer. ...

Edwin Corporan; Matthew J. DeWitt; Vincent Belovich; Robert Pawlik; Amy C. Lynch; James R. Gord; Terrence R. Meyer

2007-07-17T23:59:59.000Z

142

Combustion and \\{NOx\\} emissions of biomass-derived syngas under various gasification conditions utilizing oxygen-enriched-air and steam  

Science Journals Connector (OSTI)

The purpose of this study is to investigate the \\{NOx\\} emissions from combustion of syngas derived from gasification of three different biomass feedstock (i.e., pine, maple–oak mixture, and seed corn) at different oxygen-enriched-air and steam conditions. Three different oxygen-enriched-air and steam conditions were tested for each feedstock, thus resulting in nine different sets of syngas. The biomass-derived syngas was burned in an industrial burner that was integrated into the gasification system. The gasifier and burner are rated at 800 kW and 879 kW thermal, respectively. For each set of biomass-derived syngas, \\{NOx\\} emissions were measured at different burner operating conditions including various heat rates and equivalence ratios using emission analyzers with chemiluminescence technology. All the combustion test conditions are in the lean mixture ranges in order to avoid the peak temperature limitation of both the burner and combustion chamber. Results show that \\{NOx\\} emissions using syngas obtained from woody feedstock decrease almost linearly as the combustion mixture becomes leaner and the heat rate decreases. When compared to natural gas, syngas from both woody feedstock generates higher \\{NOx\\} emissions even when the heat rates are comparable, indicating that fuel \\{NOx\\} formation is highly important in biomass-derived syngas combustion. In contrast to syngas from woody feedstock, syngas from seed corn results in peak \\{NOx\\} emissions before \\{NOx\\} decreases with leaner conditions. The trend is observed for all fuel flow rates and all oxygen-enriched-air and steam conditions of seed corn-derived syngas. Among the three feedstock, seed corn has the highest nitrogen content which yields the highest ammonia concentration in syngas, which, in turn, results in the highest \\{NOx\\} emissions for all test conditions. Overall, the \\{NOx\\} emissions from seed corn-derived syngas combustion are approximately in the range of 450–900 ppm higher compared to those from wood-derived syngas combustion.

Cuong Van Huynh; Song-Charng Kong

2013-01-01T23:59:59.000Z

143

Low Emissions Burner Technology for Metal Processing Industry using Byproducts and Biomass Derived Liquid Fuels  

SciTech Connect (OSTI)

This research and development efforts produced low-emission burner technology capable of operating on natural gas as well as crude glycerin and/or fatty acids generated in biodiesel plants. The research was conducted in three stages (1) Concept definition leading to the design and development of a small laboratory scale burner, (2) Scale-up to prototype burner design and development, and (3) Technology demonstration with field vefiication. The burner design relies upon the Flow Blurring (FB) fuel injection based on aerodynamically creating two-phase flow near the injector exit. The fuel tube and discharge orifice both of inside diameter D are separated by gap H. For H < 0.25D, the atomizing air bubbles into liquid fuel to create a two-phase flow near the tip of the fuel tube. Pressurized two-phase fuel-air mixture exits through the discharge orifice, which results in expansion and breakup of air bubbles yielding a spray with fine droplets. First, low-emission combustion of diesel, biodiesel and straight VO (soybean oil) was achieved by utilizing FB injector to yield fine sprays for these fuels with significantly different physical properties. Visual images for these baseline experiments conducted with heat release rate (HRR) of about 8 kW illustrate clean blue flames indicating premixed combustion for all three fuels. Radial profiles of the product gas temperature at the combustor exit overlap each other signifying that the combustion efficiency is independent of the fuel. At the combustor exit, the NOx emissions are within the measurement uncertainties, while CO emissions are slightly higher for straight VO as compared to diesel and biodiesel. Considering the large variations in physical and chemical properties of fuels considered, the small differences observed in CO and NOx emissions show promise for fuel-flexible, clean combustion systems. FB injector has proven to be very effective in atomizing fuels with very different physical properties, and it offers a path forward to utilize both fossil and alternative liquid fuels in the same combustion system. In particular, experiments show that straight VO can be cleanly combusted without the need for chemical processing or preheating steps, which can result in significant economic and environmental benefits. Next, low-emission combustion of glycerol/methane was achieved by utilizing FB injector to yield fine droplets of highly viscous glycerol. Heat released from methane combustion further improves glycerol pre-vaporization and thus its clean combustion. Methane addition results in an intensified reaction zone with locally high temperatures near the injector exit. Reduction in methane flow rate elongates the reaction zone, which leads to higher CO emissions and lower NOx emissions. Similarly, higher air to liquid (ALR) mass ratio improves atomization and fuel pre-vaporization and shifts the flame closer to the injector exit. In spite of these internal variations, all fuel mixes of glycerol with methane produced similar CO and NOx emissions at the combustor exit. Results show that FB concept provides low emissions with the flexibility to utilize gaseous and highly viscous liquid fuels, straight VO and glycerol, without preheating or preprocessing the fuels. Following these initial experiments in quartz combustor, we demonstrated that glycerol combustion can be stably sustained in a metal combustor. Phase Doppler Particle Analyzer (PDPA) measurements in glycerol/methane flames resulted in flow-weighted Sauter Mean Diameter (SMD) of 35 to 40 ?m, depending upon the methane percentage. This study verified that lab-scale dual-fuel burner using FB injector can successfully atomize and combust glycerol and presumably other highly viscous liquid fuels at relatively low HRR (<10 kW). For industrial applications, a scaled-up glycerol burner design thus seemed feasible.

Agrawal, Ajay; Taylor, Robert

2013-09-30T23:59:59.000Z

144

XII.1-Draft ATTACHMENT XII  

E-Print Network [OSTI]

XII.1-Draft ATTACHMENT XII Review of Fischer-Tropsch Work by Gulf Oil The Gulf-Badger process leads analysis conducted by Gulf Oil, and later the process and engineering design provided by Badger (XII.1). A simplified process scheme is shown in XII.1 (XII.2). The process was first discovered from exploratory work

Kentucky, University of

145

A First-Principle Study of Chain Propagation Steps in the Fischer?Tropsch Synthesis on Fe(100)  

Science Journals Connector (OSTI)

This finding is consistent with the LEED and TDS observations that propyl is the dominant product instead of propane in the hydrogenation reaction of propylene on Fe(100) below 200 K.(51) ... thanks the Canadian Government for a Canada Research Chair in Theoretical Inorganic Chemistry. ...

John M. H. Lo; Tom Ziegler

2008-08-09T23:59:59.000Z

146

Síntese de Fischer-Tropsch sobre perovskitas LayCu0,4Fe0,6O3.  

E-Print Network [OSTI]

??A produção atual de 52 milhões mdia-1 de gás natural e os grandes projetos para esta expansão vem estabelecendo novas fronteiras para a indústria nacional… (more)

José Roberto de Souza

2010-01-01T23:59:59.000Z

147

Separation of Fischer-Tropsch Wax from Catalyst Using Near-Critical Fluid Extraction: Analysis of Process  

E-Print Network [OSTI]

", can be produced from materials such as coal, natural gas, waste biomass, and petroleum coke. A great of coal and natural gas exist in many geographical regions that lack sufficient petroleum. Therefore

Kilpatrick, Peter K.

148

Selective adsorption of manganese onto cobalt for optimized Mn/Co/TiO2 FischerTropsch catalysts  

E-Print Network [OSTI]

, Debye Institute for Nanomaterials Science, Utrecht University, Sorbonnelaan 16, 3584 CA Utrecht Adsorption (SEA) method was applied to the rational design of a promoted Co catalyst for Fischer­Tropsch (FT (SEA) method, which has been successfully applied to prepare highly dis- persed, monometallic catalysts

Regalbuto, John R.

149

Characterization of new Co and Ru on -WC catalysts for Fischer-Tropsch reaction. Influence of the carbide surface state.  

E-Print Network [OSTI]

[8]. Among the group VI transition metal carbides, the hexagonal tungsten carbide WC is a remarkable proceeds on supported transition metal catalysts, Co or Fe on oxide supports generally Al2O3 or SiO2 [1 of the carbide surface state. A. Griboval-Constant(1) *, J.-M. Giraudon(1) , I. Twagishema(1) , G. Leclercq(1

Paris-Sud XI, Université de

150

Characterization of new Co and Ru on -WC catalysts for Fischer-Tropsch reaction. Influence of the carbide surface state.  

E-Print Network [OSTI]

of the metallic particles [8]. Among the group VI transition metal carbides, the hexagonal tungsten carbide WC monoxide and hydrogen. FT synthesis proceeds on supported transition metal catalysts, Co or Fe on oxide of the carbide surface state. A. Griboval-Constant(1) *, J.-M. Giraudon(1) , I. Twagishema(1) , G. Leclercq(1

Paris-Sud XI, Université de

151

Separation of Fischer-Tropsch wax from catalyst by supercritical extraction. Quarterly progress report, October 1, 1996--December 31, 1996  

SciTech Connect (OSTI)

One of the major objectives of this research project is to predict the phase behavior of model wax compounds in dense supercritical fluids such as hexane. Because initial results with the SAFT equation have been less promising than expected, the group at North Carolina State University has focused their recent attention on cubic equations of state, in particular the Peng-Robinson and Soave-Redlich-Kwong versions. The focus of this work has been on developing correlations that can be used to predict binary interaction parameters (i.e., k{sub ij}s) for a given binary wax-solvent system. As a first step, k{sub ij}s were first calculated from experimental data on systems containing alkanes between nC{sub 4} and nC{sub 23} at temperatures between 25 and 357{degrees} C. Attempts were then made to correlate these parameters with specific pure component properties of the alkanes of interest. Reasonably good agreement between experimental and predicted k{sub ij}s was found using a correlation that incorporates both temperature and the molecular size of the alkanes. As phase equilibrium data becomes available for higher molecular weight model wax compounds, the ability of the correlation to handle such systems will need to be tested. The phase equilibrium apparatus is currently undergoing modifications that will allow the system to run components that are solids at ambient temperatures. Some problems are still being resolved, as the heavy component tends to precipitate in the sample lines. Modifications have been made that should allow the system to operate reliably.

Joyce, P.C.; Thies, M.C.

1997-01-01T23:59:59.000Z

152

Fischer-Tropsch Fuels from Coal and Biomass Thomas G. Kreutz, Eric D. Larson, Guangjian Liu, Robert H. Williams  

E-Print Network [OSTI]

...................................................................................................................................8 2.2.2 Biomass as feedstock

153

Life Cycle Analysis of the Production of Aviation Fuels Using the CE-CERT Process  

E-Print Network [OSTI]

FTR: Fischer-Tropsch reactor LCA: life cycle analysis LCI:software. Life cycle analyses (LCA) using a modified GREETfor the process. Keywords: LCA, Fischer-Tropsch, avation

Hu, Sangran

2012-01-01T23:59:59.000Z

154

Bisolute Sorption and Thermodynamic Behavior of Organic Pollutants to Biomass-derived Biochars at Two Pyrolytic Temperatures  

Science Journals Connector (OSTI)

The structural characteristics and isotherms shape of the biochar were more dependent on the pyrolytic temperature than on the biomass feedstocks, which included orange peel, pine needle, and sugar cane bagasse. ... , a garden waste and ubiquitous forest biomass), orange peel (OP, Citrus reticulate, an industrial source of oils, not pre-extracted) and sugar cane bagasse (SB, Saccharum sinense, a byproduct of the sugar cane industry), were selected as biomass feedstocks because they are easily available. ... Low temperature biochars (LTB) at 300 °C and high temperature biochars (HTB) at 700 °C were produced by pyrolyzing different biomass feedstocks under oxygen-limited conditions as described in previous reports. ...

Zaiming Chen; Baoliang Chen; Dandan Zhou; Wenyuan Chen

2012-11-02T23:59:59.000Z

155

Transportation fuels from synthetic gas  

SciTech Connect (OSTI)

Twenty-five experimental Fischer-Tropsch synthesis runs were made with 14 different catalysts or combinations of catalysts using a Berty reactor system. Two catalysts showed increased selectivity to transportation fuels compared to typical Fischer-Tropsch catalysts. With a catalyst consisting of 5 wt % ruthenium impregnated on a Y zeolite (run number 24), 63 to 70 wt % of the hydrocarbon product was in the gasoline boiling range. Using a 0.5 wt % ruthenium on alumina catalyst (run number 22), 64 to 78 wt % of the hydrocarbon product was in the diesel fuel boiling range. Not enough sample was produced to determine the octane number of the gasoline from run number 24, but it is probably somewhat better than typical Fischer-Tropsch gasoline (approx. 50) and less than unleaded gasoline (approx. 88). The diesel fuel produced in run number 22 consisted of mostly straight chained paraffins and should be an excellent transportation fuel without further refining. The yield of transportation fuels from biomass via gasification and the Fischer-Tropsch synthesis with the ruthenium catalysts identified in the previous paragraph is somewhat less, on a Btu basis, than methanol (via gasification) and wood oil (PERC and LBL processes) yields from biomass. However, the products of the F-T synthesis are higher quality transportation fuels. The yield of transportation fuels via the F-T synthesis is similar to the yield of gasoline via methanol synthesis and the Mobil MTG process.

Baker, E.G.; Cuello, R.

1981-08-01T23:59:59.000Z

156

Synthesis Gas Production with an Adjustable H2/CO Ratio through the Coal Gasification Process: Effects of Coal Ranks And Methane Addition  

Science Journals Connector (OSTI)

With the decline of oil reserves and production, the gas-to-liquids (GTL) part of Fischer–Tropsch (F-T) synthesis technology has become increasing important. ... The Department of Energy (DOE) Energy Information Administration (EIA) estimates that over 50% of the coal reserve base in the United States (U.S.) is bituminous coal, about 30% is sub-bituminous, and 9% is lignite. ...

Yan Cao; Zhengyang Gao; Jing Jin; Hongchang Zhou; Marten Cohron; Houying Zhao; Hongying Liu; Weiping Pan

2008-03-25T23:59:59.000Z

157

Efficient Utilization of Greenhouse Gases in a Gas-to-Liquids Process Combined with CO2/Steam-Mixed Reforming and Fe-Based Fischer–Tropsch Synthesis  

Science Journals Connector (OSTI)

In the reforming unit, CO2 reforming and steam reforming of methane are combined together to produce syngas in flexible composition. ... In the burner-type reformer, NG is used as a heating fuel, in order to reduce the consumption of NG, the vent gas can be applied to the burner to replace some part of NG as fuel. ...

Chundong Zhang; Ki-Won Jun; Kyoung-Su Ha; Yun-Jo Lee; Seok Chang Kang

2014-06-16T23:59:59.000Z

158

Fischer?Tropsch Synthesis: Influence of Mn on the Carburization Rates and Activities of Fe-Based Catalysts by TPR-EXAFS/XANES and Catalyst Testing  

Science Journals Connector (OSTI)

However, the structure of the catalyst changes as a function of reaction time, with the mixed oxide phase decomposing into iron carbides, magnetite, and MnO, thereby resulting in lower olefin selectivities. ... (7-10) Nevertheless, in examining the Fe K-edge results, although we observed differences in rates of carburization between catalyst samples with and without Mn, we did not detect discernible line shape differences in the XANES spectra between the intermediary iron oxides along the TPR trajectory. ... (35) Epsilon carbide is typically formed at lower temperatures (350 °C; cementite is formed at temperatures above 350 °C. ...

Mauro C. Ribeiro; Gary Jacobs; Ramana Pendyala; Burtron H. Davis; Donald C. Cronauer; A. Jeremy Kropf; Christopher L. Marshall

2011-02-24T23:59:59.000Z

159

Moessbauer spectroscopy studies of iron-catalysts used in Fischer-Tropsch (FT) processes. Quarterly technical progress report, January--March, 1994  

SciTech Connect (OSTI)

The objective of this project is to carry out a Moessbauer spectroscopy study of Iron-based catalysts to identify iron phases present and correlate with water gas shift and FT activities. A total of 15 catalysts were evaluated so far. Results are presented on the amounts in each catalyst of the following phases: superparamagnetic phase, hematite ({alpha}-Fe{sub 2}O{sub 3}), magnetite (Fe{sub 3}O{sub 4}), Chi-carbide phase ({chi}-Fe{sub 5}C{sub 2}), and an epsilon-carbide phase ({var_epsilon}-Fe{sub 2.2}C).

Huffman, G.P.; Rao, K.R.P.M.

1994-12-31T23:59:59.000Z

160

Potential for Reduction of Exhaust Emissions in a Common-Rail Direct-Injection Diesel Engine by Fueling with Fischer–Tropsch Diesel Fuel Synthesized from Coal  

Science Journals Connector (OSTI)

In the constant speed/varying load test modes, the use of CFT also resulted in a general reduction of regulated emissions. ... (5, 6) Moreover, FT diesel fuels can be used in contemporary diesel engines without any modification and with a negligible or weak improvement of engine efficiency. ... Liu, Z.; Shi, S.; Li, Y.Coal liquefaction technologies—Development in China and challenges in chemical reaction engineering Chem. ...

Chonglin Song; Guohong Gong; Jinou Song; Gang Lv; Xiaofeng Cao; Lidong Liu; Yiqiang Pei

2011-11-28T23:59:59.000Z

Note: This page contains sample records for the topic "oils biomass-derived fischer-tropsch" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Comparative Study on Engine Performance and Diesel Emissions with European Diesel Fuel (DF)?Diethylene Glycol Dimethyl Ether (DGM) and Fischer?Tropsch (FT)?DGM Blends  

Science Journals Connector (OSTI)

† Department of Energy and Process Engineering ... The general picture of the methyl- and methylene-related vibrations in the DF used here confirms the results of the GC analyses; i.e., that the DF resembles a n-alkane-dominated hydrocarbon mixture. ... To investigate influences of fuel design on regulated and non-regulated emissions of heavy-duty diesel engines, a Mercedes-Benz OM 906 Euro 3 engine was run with common diesel fuel (DF), first- and second-generation alternative fuels (Gas-to-liq. ...

Md. Nurun Nabi; Rudolf Schmid; Johan Einar Hustad

2010-03-30T23:59:59.000Z

162

New approach to the generation of metal-bearing, medium-pore, shape-selective zeolites for Fischer-Tropsch catalysis. [Aluminoferrisilicate  

SciTech Connect (OSTI)

A new method of combining the shape-selective characteristics of zeolites with a group VIII metal component is described. It involves the following sequence of steps: (1) synthesis of an aluminoferrisilicate (AFS) zeolite, having a crystal structure analogous to zeolite ZSM-5, but which incorporates ferric ions into the structure during synthesis; (2) removal of the organic base used as a template in crystallization of the AFS zeolite; (3) reaction of the AFS zeolite with a transition metal complex anion in aqueous solution to precipitate an inclusion compound in the AFS zeolite, and (4) reduction of the inclusion compound with hydrogen at elevated temperature.

Iton, L.E.; Beal, R.B.; Hodul, D.T.

1983-01-01T23:59:59.000Z

163

NETL: Gasifipedia  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Fuels: Fischer-Tropsch Synthesis Fuels: Fischer-Tropsch Synthesis F-T Efficiency & Performance - DOE R&D Comparing liquid transportation fuels production from coal gasification to fuels from traditional production methods is a difficult undertaking because of the vastly diverse configuration options available for gasification processing. Traditionally, fuels like gasoline and diesel are refined from crude oil, a (comparatively) more uniform feedstock than coal -or, for that matter, biomass, petcoke, refinery waste, etc. Each potential feedstock, even between different coal ranks, has variable characteristics that can necessitate design changes (ash content, sulfur concentration, feed handling issues, etc.). Additionally, as a relatively new approach to producing liquid fuels, gasification has not had years of refinement to develop a "best," most productive or cost-efficient approach, in part, due to the aforementioned flexibility in choosing feedstock, product, synthesis gas (syngas) cleaning and conditioning units. In fact, besides multiple gasifier options and configurations, the liquid fuel synthesis component itself can be approached multiple ways: methanol-to-gasoline or Fischer-Tropsch (FT) synthesis, to name the two most important. Essentially, comparing petroleum-refinery produced transportation fuels and gasification-derived fuels requires design assumptions and limiting the scope of the comparison in order to arrive at meaningful conclusions.

164

Fischer-T.qxd  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Fischer-Tropsch One in a series of fact sheets United States Environmental Protection Agency EPA420-F-00-036 March 2002 www.epa.gov Transportation and Air Quality Transportation and Regional Programs Division C L E A N A L T E R N A T I V E F U E L S C L E A N E R A I R For the past 50 years, Fischer-Tropsch fuels have powered all of South Africa's vehicles-from buses to trucks to taxicabs. The fuel is primarily sup- plied by Sasol, a world leader in Fischer-Tropsch technologies. Sasol's South African facility produces more than 150,000 barrels of high- quality fuel from domestic low-grade coal daily. The popular fuel is cost-com- petitive with crude oil- based petroleum products in South Africa. During the next several years, experts predict use of Fischer-Trop- sch fuels will grow as a high-end blend stock in

165

OIL SHALE  

E-Print Network [OSTI]

Seyitömer, Himmeto?lu and Hat?lda? oil shale deposits. The results demonstrate that these oil shales are

Fields (in-situ Combustion Approach; M. V. Kök; G. Guner; S. Bagci?

166

Bio-oil Stabilization and Upgrading by Hot Gas Filtration  

Science Journals Connector (OSTI)

Removal of char and minerals from pyrolysis oil for the production of biomass-derived boiler and turbine fuels has been demonstrated at Solar Energy Research Institute (SERI)/National Renewable Energy Laboratory (NREL) using a ceramic cloth hot gas filter (HGF). ... Non-condensable gaseous products were vented through a 2 ?m filter for collection of any residual aerosol and then to a totalizing dry-gas meter for flow rate measurement. ... The composition of the feed and product vapors to and from the HGF test stand was monitored continuously with the molecular beam mass spectrometer (MBMS), and the composition of the product gases from the HGF test stand was monitored continuously by gas chromatography (GC). ...

Robert M. Baldwin; Calvin J. Feik

2013-04-22T23:59:59.000Z

167

Renewable Chemical Commodity Feedstocks from Integrated Catalytic Processing of Pyrolysis Oils  

Science Journals Connector (OSTI)

...hydrogen is from large steam reformers and...amounts of undesired methane are produced, which...such as by the reforming of biomass-derived...aqueous-phase reforming of biomass-derived...Survey of the Economics of Hydrogen Technologies...Hydrogen from catalytic reforming of biomass-derived...

Tushar P. Vispute; Huiyan Zhang; Aimaro Sanna; Rui Xiao; George W. Huber

2010-11-26T23:59:59.000Z

168

Fischer-Tropsch Synthesis: Influence of CO Conversion on Selectivities H2/CO Usage Ratios and Catalyst Stability for a 0.27 percent Ru 25 percent Co/Al2O3 using a Slurry Phase Reactor  

SciTech Connect (OSTI)

The effect of CO conversion on hydrocarbon selectivities (i.e., CH{sub 4}, C{sub 5+}, olefin and paraffin), H{sub 2}/CO usage ratios, CO{sub 2} selectivity, and catalyst stability over a wide range of CO conversion (12-94%) on 0.27%Ru-25%Co/Al{sub 2}O{sub 3} catalyst was studied under the conditions of 220 C, 1.5 MPa, H{sub 2}/CO feed ratio of 2.1 and gas space velocities of 0.3-15 NL/g-cat/h in a 1-L continuously stirred tank reactor (CSTR). Catalyst samples were withdrawn from the CSTR at different CO conversion levels, and Co phases (Co, CoO) in the slurry samples were characterized by XANES, and in the case of the fresh catalysts, EXAFS as well. Ru was responsible for increasing the extent of Co reduction, thus boosting the active site density. At 1%Ru loading, EXAFS indicates that coordination of Ru at the atomic level was virtually solely with Co. It was found that the selectivities to CH{sub 4}, C{sub 5+}, and CO{sub 2} on the Co catalyst are functions of CO conversion. At high CO conversions, i.e. above 80%, CH{sub 4} selectivity experienced a change in the trend, and began to increase, and CO{sub 2} selectivity experienced a rapid increase. H{sub 2}/CO usage ratio and olefin content were found to decrease with increasing CO conversion in the range of 12-94%. The observed results are consistent with water reoxidation of Co during FTS at high conversion. XANES spectroscopy of used catalyst samples displayed spectra consistent with the presence of more CoO at higher CO conversion levels.

W Ma; G Jacobs; Y Ji; T Bhatelia; D Bukur; S Khalid; B Davis

2011-12-31T23:59:59.000Z

169

Fischer?Tropsch Synthesis: An In-Situ TPR-EXAFS/XANES Investigation of the Influence of Group I Alkali Promoters on the Local Atomic and Electronic Structure of Carburized Iron/Silica Catalysts  

Science Journals Connector (OSTI)

After 10 h of treatment the samples containing K, Rb, and Cs were completely carburized, and residual quantities of iron oxides were detected in both unpromoted and Li-promoted samples. ... To further constrain the model, global parameters (i.e., over all samples) were used for the isotropic lattice expansion (?) and Debye?Waller factor (?2) parameters for carbide (i.e., combined epsilon and Hägg) and oxide (i.e., Fe3O4) fractions. ... Au particles smaller than about 30 Å were also reactive to air, leading to oxidn. of up to 15% of the atoms of the gold particles, depending on the size; larger particles were not oxidized. ...

Mauro C. Ribeiro; Gary Jacobs; Burtron H. Davis; Donald C. Cronauer; A. Jeremy Kropf; Christopher L. Marshall

2010-04-01T23:59:59.000Z

170

„Peak Oil  

Science Journals Connector (OSTI)

Wissenschaftliche Voraussagen deuten auf „Peak Oil“, das Maximum globaler Erdölförderung, in unserer ... der demokratischen Systeme führen. Psychoanalytische Betrachtung darf „Peak Oil“ für die Zivilisation als e...

Dr. Manuel Haus; Dr. med. Christoph Biermann

2013-03-01T23:59:59.000Z

171

NETL F 451.1/1-1, Categorical Exclusion Designation Form  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

for Synthetic Jet Fuel Production Design and evaluate cost-competitiveness of co-gasification facility for producing primarily Fischer-Tropsch synthetic jet fuel. Includes...

172

Biofuel Boundaries: Estimating the Medium-Term Supply Potential of Domestic Biofuels  

E-Print Network [OSTI]

pathways, such as gasification. However, the current studysuch as MSW, the gasification to Fischer- Tropsch fuelof research on biomass gasification to FT-fuels compared to

Jones, Andrew; O'Hare, Michael; Farrell, Alexander

2007-01-01T23:59:59.000Z

173

June 3, 2014 Webinar - Features, Events, and Processes: Practical...  

Broader source: Energy.gov (indexed) [DOE]

& Publications HEFA and Fischer-Tropsch Jet Fuel Cost Analyses Proceedings of 3rd USGerman Workshop on Salt Repository Research, Design, and Operation Eastern Wind Integration...

174

Otimização da produção de hidrogênio pela reforma a vapor do metano em reator com membrana laboratorial.  

E-Print Network [OSTI]

??Hydrogen is used as fuel and as a feedstock in important processes such as ammonia and methanol production and Fischer-Tropsch synthesis, besides the increasing use… (more)

Leandro Cardoso Silva

2008-01-01T23:59:59.000Z

175

STATEMENT OF CONSIDERATIONS REQUEST BY TEXACO ENERGY SERVICES...  

Broader source: Energy.gov (indexed) [DOE]

the integration of four existing commercial modules (gasification, air separation, combined cycle process, and Fischer-Tropsch (F-T) technology into a unified whole unit...

176

Peak Oil  

Science Journals Connector (OSTI)

At the start of the new millennium, the expression “Peak Oil” was unknown. Nevertheless, a discussion about when the world’s rate of oil production would reach its maximum had already ... . King Hubbert presented...

Kjell Aleklett

2012-01-01T23:59:59.000Z

177

Peak Oil  

Science Journals Connector (OSTI)

Between 2000 and 2010, world oil prices advanced from approximately $25 per barrel to more than $100 per barrel. The price appreciation of oil over the decade was around ten times the rate of inflation.

Robert Rapier

2012-01-01T23:59:59.000Z

178

Utilizing the heat content of gas-to-liquids by-product streams for commercial power generation  

E-Print Network [OSTI]

and sulphur. They have no aromatics due to the isomerisation of the highly paraffinic Fischer-Tropsch liquids into GTL fuels and are practically100%iso-paraffinic,thustheyhaveveryhighcetaneratings. The... and sulphur. They have no aromatics due to the isomerisation of the highly paraffinic Fischer-Tropsch liquids into GTL fuels and are practically100%iso-paraffinic,thustheyhaveveryhighcetaneratings. The...

Adegoke, Adesola Ayodeji

2006-10-30T23:59:59.000Z

179

Conversion of Biomass Derived Products by Anodic Activation  

Science Journals Connector (OSTI)

Fatty acids and carbohydrate carboxylic acids are homo- and heterocoupled to intermediates for polyesters, new oleochemicals and potential enzyme inhibitors. — L-Ketogulonic acid is decarboxylated quantitatively ...

Hans J. Schäfer; Silke Kratschmer…

1998-01-01T23:59:59.000Z

180

Nonenzymatic Sugar Production from Biomass Using Biomass-Derived ?-Valerolactone  

Science Journals Connector (OSTI)

...than one glucan or xylan monomer (supplementary...by-products on the surface of cellulose, which...reactive cellulose surface (16). Water-insoluble...solids isolated after treatment with GVL...of our standard treatment. Moreover, when...overall conversion of xylan to known products...

Jeremy S. Luterbacher; Jacqueline M. Rand; David Martin Alonso; Jeehoon Han; J. Tyler Youngquist; Christos T. Maravelias; Brian F. Pfleger; James A. Dumesic

2014-01-17T23:59:59.000Z

Note: This page contains sample records for the topic "oils biomass-derived fischer-tropsch" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Valorization of Biomass: Deriving More Value from Waste  

Science Journals Connector (OSTI)

...fields, or lignin as a fuel to power paper mills...chemical 1000 Transportation fuel 200–400 Cattle feed...increasing quantities by the biodiesel industry and could become...conversion to transportation fuel and 10 times that...feedstocks involves the introduction of oxygen-containing...

Christopher O. Tuck; Eduardo Pérez; István T. Horváth; Roger A. Sheldon; Martyn Poliakoff

2012-08-10T23:59:59.000Z

182

Essays on Macroeconomics and Oil  

E-Print Network [OSTI]

Oil Production . . . . . . . . . . . . . . . . . . . . . . . . . . .Oil Production in Venezuela and Mexico . . . . . . . . . .Oil Production and Productivity in Venezuela and

CAKIR, NIDA

2013-01-01T23:59:59.000Z

183

Essays on Macroeconomics and Oil  

E-Print Network [OSTI]

the Oil Industry . . . . . . . . . . . . . . . . . . . . . .in the Venezuelan Oil Industry . . . . . . . . . . . . .and Productivity: Evidence from the Oil Industry . .

CAKIR, NIDA

2013-01-01T23:59:59.000Z

184

The carbon footprint and non-renewable energy demand of algae-derived biodiesel  

Science Journals Connector (OSTI)

Abstract We determine the environmental impact of different biodiesel production strategies from algae feedstock in terms of greenhouse gas (GHG) emissions and non-renewable energy consumption, we then benchmark the results against those of conventional and synthetic diesel obtained from fossil resources. The algae cultivation in open pond raceways and the transesterification process for the conversion of algae oil into biodiesel constitute the common elements among all considered scenarios. Anaerobic digestion and hydrothermal gasification are considered for the conversion of the residues from the wet oil extraction route; while integrated gasification–heat and power generation and gasification–Fischer–Tropsch processes are considered for the conversion of the residues from the dry oil extraction route. The GHG emissions per unit energy of the biodiesel are calculated as follows: 41 g e-CO2/MJb for hydrothermal gasification, 86 g e-CO2/MJb for anaerobic digestion, 109 g e-CO2/MJb for gasification–power generation, and 124 g e-CO2/MJb for gasification–Fischer–Tropsch. As expected, non-renewable energy consumptions are closely correlated to the GHG values. Also, using the High Dimensional Model Representation (HDMR) method, a global sensitivity analysis over the entire space of input parameters is performed to rank them with respect to their influence on key sustainability metrics. Considering reasonable ranges over which each parameter can vary, the most influential input parameters for the wet extraction route include extractor energy demand and methane yield generated from anaerobic digestion or hydrothermal gasification of the oil extracted-algae. The dominant process input parameters for the dry extraction route include algae oil content, dryer energy demand, and algae annual productivity. The results imply that algal biodiesel production from a dried feedstock may only prove sustainable if a low carbon solution such as solar drying is implemented to help reducing the water content of the feedstock.

Pooya Azadi; George Brownbridge; Sebastian Mosbach; Andrew Smallbone; Amit Bhave; Oliver Inderwildi; Markus Kraft

2014-01-01T23:59:59.000Z

185

NETL: LabNotes - May 2010  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Researchers Gain New Insight into Activating Fischer-Tropsch Catalysts Researchers Gain New Insight into Activating Fischer-Tropsch Catalysts An array of model Fischer-Tropsch catalyst particles. The image on the left shows an array of model Fischer-Tropsch catalyst particles, as seen using a special scan- ning tunneling microscope at NETL. The image on the right is an enlargement of the surface of one of these particles showing a regular array of closely packed oxygen atoms, which appear as small circular ‘bumps’ in the images. The Fischer-Tropsch (F-T) process is a set of chemical reactions that historically has been used to produce a petroleum substitute from coal, natural gas, or biomass by nations looking for an alternative to importing it. The F-T process has received intermittent attention as a source of low-sulfur diesel fuel whenever the cost of petroleum gets sufficiently

186

Fuels - Biodiesel  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

* Biodiesel * Biodiesel * Butanol * Ethanol * Hydrogen * Natural Gas * Fischer-Tropsch Batteries Cross-Cutting Assessments Engines GREET Hybrid Electric Vehicles Hydrogen & Fuel Cells Materials Modeling, Simulation & Software Plug-In Hybrid Electric Vehicles PSAT Smart Grid Student Competitions Transportation Research and Analysis Computing Center Working With Argonne Contact TTRDC Clean Diesel Fuels Background Reducing our country's dependence on foreign oil and the rising costs of crude oil are primary reasons for a renewed interest in alternative fuels for the transportation sector. Stringent emissions regulations and public concern about mobile sources of air pollution provide additional incentives to develop fuels that generate fewer emissions, potentially reducing the need for sophisticated, expensive exhaust after-treatment devices.

187

Economical production of transportation fuels from coal, natural gas, and other carbonaceous feedstocks  

SciTech Connect (OSTI)

The Nation`s economy and security will continue to be vitally linked to an efficient transportation system of air, rail, and highway vehicles that depend on a continuous supply of liquid fuels at a reasonable price and with characteristics that can help the vehicle manufacturers meet increasingly strict environmental regulations. However, an analysis of US oil production and demand shows that, between now and 2015, a significant increase in imported oil will be needed to meet transportation fuel requirements. One element of an overall Department of Energy`s (DOE) strategy to address this energy security issue while helping meet emissions requirements is to produce premium transportation fuels from non-petroleum feedstocks, such as coal, natural gas, and biomass, via Fischer-Tropsch (F-T) and other synthesis gas conversion technologies.

Srivastava, R.D.; McIlvried, H.G. [Burns and Roe Services Corp., Pittsburgh, PA (United States); Winslow, J.C.; Venkataraman, V.K.; Driscoll, D.J. [Dept. of Energy, Pittsburgh, PA (United States). Federal Energy Technology Center

1998-12-31T23:59:59.000Z

188

OIL IMPORTS: For and Against  

Science Journals Connector (OSTI)

OIL IMPORTS: For and Against ... The eight—Ashland Oil, Atlantic Richfield, Cities Service, Marathon Oil, Mobil Oil, Standard Oil (Ind.), ...

1969-07-28T23:59:59.000Z

189

Bioconversion of Heavy oil.  

E-Print Network [OSTI]

??70 % of world?s oil reservoirs consist of heavy oil, and as the supply of conventional oil decreases, researchers are searching for new technologies to… (more)

Steinbakk, Sandra

2011-01-01T23:59:59.000Z

190

5 World Oil Trends WORLD OIL TRENDS  

E-Print Network [OSTI]

5 World Oil Trends Chapter 1 WORLD OIL TRENDS INTRODUCTION In considering the outlook for California's petroleum supplies, it is important to give attention to expecta- tions of what the world oil market. Will world oil demand increase and, if so, by how much? How will world oil prices be affected

191

of oil yields from enhanced oil recovery  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

oil yields from enhanced oil recovery (EOR) and CO oil yields from enhanced oil recovery (EOR) and CO 2 storage capacity in depleted oil reservoirs. The primary goal of the project is to demonstrate that remaining oil can be economically produced using CO 2 -EOR technology in untested areas of the United States. The Citronelle Field appears to be an ideal site for concurrent CO 2 storage and EOR because the field is composed of sandstone reservoirs

192

Hydrotreating of oil from eastern oil shale  

SciTech Connect (OSTI)

Oil shale provides one of the major fossil energy reserves for the United States. The quantity of reserves in oil shale is less than the quantity in coal, but is much greater (by at least an order of magnitude) than the quantity of crude oil reserves. With so much oil potentially available from oil shale, efforts have been made to develop techniques for its utilization. In these efforts, hydrotreating has proved to be an acceptable technique for upgrading raw shale oil to make usuable products. The present work demonstrated the use of the hydrotreating technique for upgrading an oil from Indiana New Albany oil shale.

Scinta, J.; Garner, J.W.

1984-01-01T23:59:59.000Z

193

MTG Revisited  

Science Journals Connector (OSTI)

Publisher Summary The first commercial plant based on this unique chemistry has been onstream for five years in New Zealand, where it converts 140 million standard cubic feet per day of natural gas mainly from the offshore Maui gas field, to methanol, thence to 14,500 barrels per day of gasoline for premium unleaded specifications. The plant is designed to supply one third of New Zealand's current gasoline demand, and was key to their attainment of 50% self-sufficiency in transport fuels, a strategic goal of the government. In a historical sense, the MTG (Methanol-to-Gasoline) Process was the first major advance in synfuels technology in half a century since the Fischer-Tropsch Process. Developed in the wake of the Arab oil embargo, MTG technology was a timely response to the subsequent "energy crisis". The chapter also presents a brief discourse on the still unsolved reaction mechanism.

Clarence D. Chang

1991-01-01T23:59:59.000Z

194

Near Shore Submerged Oil Assessment  

E-Print Network [OSTI]

) oil spill in the Gulf of Mexico, submerged oil refers to near shore oil which has picked up sediments You Should Know About Submerged Oil 1. Submerged oil is relatively uncommon: DWH oil is a light crude

195

OIl Speculation  

Gasoline and Diesel Fuel Update (EIA)

Investor Investor Flows and the 2008 Boom/Bust in Oil Prices Kenneth J. Singleton 1 August 10, 2011 1 Graduate School of Business, Stanford University, kenneths@stanford.edu. This research is the outgrowth of a survey paper I prepared for the Air Transport Association of America. I am grateful to Kristoffer Laursen for research assistance and to Kristoffer and Stefan Nagel for their comments. Abstract This paper explores the impact of investor flows and financial market conditions on returns in crude-oil futures markets. I begin by arguing that informational frictions and the associated speculative activity may induce prices to drift away from "fundamental" values and show increased volatility. This is followed by a discussion of the interplay between imperfect infor- mation about real economic activity, including supply, demand, and inventory accumulation, and speculative

196

A Review and Perspective of Recent Bio-Oil Hydrotreating Research  

SciTech Connect (OSTI)

The pathway for catalytic hydrodeoxygenation of biomass derived fast pyrolysis oil represents a compelling route for production of liquid transportation fuels. There has been continued progress and advancements in both the public and private research areas towards driving this technology to completion. Published research and patent literature have demonstrated that continued development of HDO as a part of a processes for production liquid transportation using biomass is being advanced for both fuel blend stocks and for refinery intermediates for co-processing. Much of the research has still focused on “quality” metrics around single or groups of unit operations generating partially treated bio-oil streams without assessing upstream and downstream implications. However, there is an encouraging amount of research that is now being targeted and assessed with attempts to understand the impact on the final fuel product, regardless of the route. Much of the most important research is moving towards continuous, industrially relevant processes where data can be generated to adequately inform process and economic modeling. As the technology for producing liquid transportation fuels from pyrolysis/HDO/coprocessing is driving towards commercialization, further research should be prioritized on the basis of impact to a techno-economic analyses.

Zacher, Alan H.; Olarte, Mariefel V.; Santosa, Daniel M.; Elliott, Douglas C.; Jones, Susanne B.

2014-02-28T23:59:59.000Z

197

A Systems Approach to Bio-Oil Stabilization - Final Technical Report  

SciTech Connect (OSTI)

The objective of this project is to develop practical, cost effective methods for stabilizing biomass-derived fast pyrolysis oil for at least six months of storage under ambient conditions. The U.S. Department of Energy has targeted three strategies for stabilizing bio-oils: (1) reducing the oxygen content of the organic compounds comprising pyrolysis oil; (2) removal of carboxylic acid groups such that the total acid number (TAN) of the pyrolysis oil is dramatically reduced; and (3) reducing the charcoal content, which contains alkali metals known to catalyze reactions that increase the viscosity of bio-oil. Alkali and alkaline earth metals (AAEM), are known to catalyze decomposition reactions of biomass carbohydrates to produce light oxygenates that destabilize the resulting bio-oil. Methods envisioned to prevent the AAEM from reaction with the biomass carbohydrates include washing the AAEM out of the biomass with water or dilute acid or infusing an acid catalyst to passivate the AAEM. Infusion of acids into the feedstock to convert all of the AAEM to salts which are stable at pyrolysis temperatures proved to be a much more economically feasible process. Our results from pyrolyzing acid infused biomass showed increases in the yield of anhydrosugars by greater than 300% while greatly reducing the yield of light oxygenates that are known to destabilize bio-oil. Particulate matter can interfere with combustion or catalytic processing of either syngas or bio-oil. It also is thought to catalyze the polymerization of bio-oil, which increases the viscosity of bio-oil over time. High temperature bag houses, ceramic candle filters, and moving bed granular filters have been variously suggested for syngas cleaning at elevated temperatures. High temperature filtration of bio-oil vapors has also been suggested by the National Renewable Energy Laboratory although there remain technical challenges to this approach. The fast pyrolysis of biomass yields three main organic products: condensable vapors, non-condensable gases, and liquid aerosols. Traditionally these are recovered by a spray quencher or a conventional shell and tube condenser. The spray quencher or condenser is typically followed by an electrostatic precipitator to yield 1 or 2 distinct fractions of bio-oil. The pyrolyzer system developed at Iowa State University incorporates a proprietary fractionating condenser train. The system collects the bio-oil into five unique fractions. For conditions typical of fluidized bed pyrolyzers, stage fractions have been collected that are carbohydrate-rich (anhydrosugars), lignin-rich, and an aqueous solution of carboxylic acids and aldehydes. One important feature is that most of the water normally found in bio-oil appears in the last stage fraction along with several water-soluble components that are thought to be responsible for bio-oil aging (low molecular weight carboxylic acids and aldehydes). Research work on laser diagnostics for hot-vapor filtration and bio-oil recovery centered on development of analytical techniques for in situ measurements during fast pyrolysis, hot-vapor filtration, and fractionation relative to bio-oil stabilization. The methods developed in this work include laser-induced breakdown spectroscopy (LIBS), laser-induced incandescence (LII), and laser scattering for elemental analysis (N, O, H, C), detection of particulates, and detection of aerosols, respectively. These techniques were utilized in simulated pyrolysis environments and applied to a small-scale pyrolysis unit. Stability of Bio-oils is adversely affected by the presence of particulates that are formed as a consequence of thermal pyrolysis, improving the CFD simulations of moving bed granular filter (MBGF) is useful for improving the design of MBGF for bio-oil production. The current work uses fully resolved direct numerical simulation (where the flow past each granule is accurately represented) to calculate the filter efficiency that is used in the CFD model at all flow speeds. This study shows that fully-resolved direct numerical simulation (DNS

Brown, Robert C; Meyer, Terrence; Fox, Rodney; Submramaniam, Shankar; Shanks, Brent; Smith, Ryan G

2011-12-23T23:59:59.000Z

198

Cooperative Research in C1 Chemistry  

SciTech Connect (OSTI)

C1 chemistry refers to the conversion of simple carbon-containing materials that contain one carbon atom per molecule into valuable products. The feedstocks for C1 chemistry include natural gas, carbon dioxide, carbon monoxide, methanol and synthesis gas (a mixture of carbon monoxide and hydrogen). Synthesis gas, or syngas, is produced primarily by the reaction of natural gas, which is principally methane, with steam. It can also be produced by gasification of coal, petroleum coke, or biomass. The availability of syngas from coal gasification is expected to increase significantly in the future because of increasing development of integrated gasification combined cycle (IGCC) power generation. Because of the abundance of remote natural gas, the advent of IGCC, and environmental advantages, C1 chemistry is expected to become a major area of interest for the transportation fuel and chemical industries in the relatively near future. The CFFLS will therefore perform a valuable national service by providing science and engineering graduates that are trained in this important area. Syngas is the source of most hydrogen. Approximately 10 trillion standard cubic feet (SCF) of hydrogen are manufactured annually in the world. Most of this hydrogen is currently used for the production of ammonia and in a variety of refining and chemical operations. However, utilization of hydrogen in fuel cells is expected to grow significantly in the next century. Syngas is also the feedstock for all methanol and Fischer-Tropsch plants. Currently, world consumption of methanol is over 25 million tons per year. There are many methanol plants in the U.S. and throughout the world. Methanol and oxygenated transportation fuel products play a significant role in the CFFLS C1 program. Currently, the only commercial Fischer-Tropsch plants are overseas, principally in South Africa (SASOL). However, new plants are being built or planned for a number of locations. One possible location for future F-T plant development in the U.S. is in the Alaskan oil fields.

Gerald P. Huffman

2000-10-27T23:59:59.000Z

199

China's Global Oil Strategy  

E-Print Network [OSTI]

capability to secure oil transport security. Additionally,international oil agreements: 1) ensuring energy security;security, and many argue that as the second-largest consumer of oil

Thomas, Bryan G

2009-01-01T23:59:59.000Z

200

Understanding Crude Oil Prices  

E-Print Network [OSTI]

2007”. comparison, Mexico used 6.6— Chinese oil consumption17. Oil production from the North Sea, Mexico’s Cantarell,Mexico, Italy, France, Canada, US, and UK. Figure 10. Historical Chinese oil

Hamilton, James Douglas

2008-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "oils biomass-derived fischer-tropsch" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Understanding Crude Oil Prices  

E-Print Network [OSTI]

2004. “OPEC’s Optimal Crude Oil Price,” Energy Policy 32(2),023 Understanding Crude Oil Prices James D. Hamilton Junedirectly. Understanding Crude Oil Prices* James D. Hamilton

Hamilton, James Douglas

2008-01-01T23:59:59.000Z

202

Understanding Crude Oil Prices  

E-Print Network [OSTI]

business of having some oil in inventory, which is referredKnowledge of all the oil going into inventory today for salebe empty, because inventories of oil are essential for the

Hamilton, James Douglas

2008-01-01T23:59:59.000Z

203

Understanding Crude Oil Prices  

E-Print Network [OSTI]

2004. “OPEC’s Optimal Crude Oil Price,” Energy Policy 32(2),percent change in real oil price. Figure 3. Price of crude023 Understanding Crude Oil Prices James D. Hamilton June

Hamilton, James Douglas

2008-01-01T23:59:59.000Z

204

Understanding Crude Oil Prices  

E-Print Network [OSTI]

2004. “OPEC’s Optimal Crude Oil Price,” Energy Policy 32(2),percent change in real oil price. Figure 3. Price of crudein predicting quarterly real oil price change. variable real

Hamilton, James Douglas

2008-01-01T23:59:59.000Z

205

China's Global Oil Strategy  

E-Print Network [OSTI]

by this point, China’s demand Oil Demand vs. Domestic Supplycurrent pace of growth in oil demand as staying consistentand predictions of oil supply and demand affected foreign

Thomas, Bryan G

2009-01-01T23:59:59.000Z

206

Understanding Crude Oil Prices  

E-Print Network [OSTI]

and Income on Energy and Oil Demand,” Energy Journal 23(1),2006. “China’s Growing Demand for Oil and Its Impact on U.S.in the supply or demand for oil itself could be regarded as

Hamilton, James Douglas

2008-01-01T23:59:59.000Z

207

Understanding Crude Oil Prices  

E-Print Network [OSTI]

2007”. comparison, Mexico used 6.6— Chinese oil consumption17. Oil production from the North Sea, Mexico’s Cantarell,

Hamilton, James Douglas

2008-01-01T23:59:59.000Z

208

Desulfurization of heavy oil  

Science Journals Connector (OSTI)

Strategies for heavy oil desulfurization were evaluated by reviewing desulfurization literature and critically assessing the viability of the various methods for heavy oil. The desulfurization methods includin...

Rashad Javadli; Arno de Klerk

2012-03-01T23:59:59.000Z

209

China's Global Oil Strategy  

E-Print Network [OSTI]

China’s domestic oil supply will peak, and demand Robertpeak will come around 2020, 24 and that by this point, China’s demand Oil

Thomas, Bryan G

2009-01-01T23:59:59.000Z

210

Tall oil pitch  

Science Journals Connector (OSTI)

n....Undistilled residue from the distillation of crude tall oil. It is generally recognized that tall oil pitches contain some high-boiling esters and neutral...

2007-01-01T23:59:59.000Z

211

China's Global Oil Strategy  

E-Print Network [OSTI]

Analysts agree that the Persian Gulf region will continue tos oil imports. 17 The Persian Gulf region is particularlyaccess to oil from the Persian Gulf because of conflict

Thomas, Bryan G

2009-01-01T23:59:59.000Z

212

oil1990.xls  

Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

(dollars) (dollars) (dollars) (dollars) Table 1. Consumption and Expenditures in U.S. Households that Use Fuel OilKerosene, 1990 Residential Buildings Average Fuel Oil...

213

Oil Sands Feedstocks  

Broader source: Energy.gov (indexed) [DOE]

Centre for Upgrading Technology 'a Canada-Alberta alliance for bitumen and heavy oil research' Oil Sands Feedstocks C Fairbridge, Z Ring, Y Briker, D Hager National Centre...

214

Crude Oil Domestic Production  

U.S. Energy Information Administration (EIA) Indexed Site

Data Series: Crude Oil Domestic Production Refinery Crude Oil Inputs Refinery Gross Inputs Refinery Operable Capacity (Calendar Day) Refinery Percent Operable Utilization Net...

215

Biochemically enhanced oil recovery and oil treatment  

DOE Patents [OSTI]

This invention relates to the preparation of new, modified organisms, through challenge growth processes, that are viable in the extreme temperature, pressure and pH conditions and salt concentrations of an oil reservoir and that are suitable for use in microbial enhanced oil recovery. The modified microorganisms of the present invention are used to enhance oil recovery and remove sulfur compounds and metals from the crude oil. 62 figures.

Premuzic, E.T.; Lin, M.

1994-03-29T23:59:59.000Z

216

Biochemically enhanced oil recovery and oil treatment  

DOE Patents [OSTI]

This invention relates to the preparation of new, modified organisms, through challenge growth processes, that are viable in the extreme temperature, pressure and pH conditions and salt concentrations of an oil reservoir and that are suitable for use in microbial enhanced oil recovery. The modified microorganisms of the present invention are used to enhance oil recovery and remove sulfur compounds and metals from the crude oil.

Premuzic, Eugene T. (East Moriches, NY); Lin, Mow (Rocky Point, NY)

1994-01-01T23:59:59.000Z

217

Challenge # 1. Feedstock & Production | Department of Energy  

Energy Savers [EERE]

at the Pyrolysis Oil Workshop. pyrolysischallenge1.pdf More Documents & Publications Biomass Derivatives Competitive with Heating Oil Costs. Biomass Program Perspectives on...

218

Ships After Oil  

Science Journals Connector (OSTI)

Ships After Oil ... Special self-propelled tenders planned for offshore drilling operations in Gulf ...

1956-07-02T23:59:59.000Z

219

OIL & GAS INSTITUTE Introduction  

E-Print Network [OSTI]

OIL & GAS INSTITUTE CONTENTS Introduction Asset Integrity Underpinning Capabilities 2 4 4 6 8 9 10 COMPETITIVENESS UNIVERSITY of STRATHCLYDE OIL & GAS INSTITUTE OIL & GAS EXPERTISE AND PARTNERSHIPS #12;1 The launch of the Strathclyde Oil & Gas Institute represents an important step forward for the University

Mottram, Nigel

220

Oil | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Oil Oil Oil Oil Prices, 2000-2008 For the first time since 1995, U.S. oil production has surpassed imports. Explore the trend with our interactive chart. | Graphic by Daniel Wood, Energy Department. For the first time since 1995, U.S. oil production has surpassed imports. Explore the trend with our interactive chart. | Graphic by Daniel Wood, Energy Department. Oil is used for heating and transportation -- most notably, as fuel for gas-powered vehicles. America's dependence on foreign oil has declined in recent years, but oil prices have increased. The Energy Department supports research and policy options to increase our domestic supply of oil while ensuring environmentally sustainable supplies domestically and abroad, and is investing in research, technology and

Note: This page contains sample records for the topic "oils biomass-derived fischer-tropsch" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Oil Dependencies and Peak Oil's Effects on Oil Consumption.  

E-Print Network [OSTI]

?? During the year of 2007, the world has experienced historically high oil prices both in nominal and in real terms, which has reopened discussions… (more)

Tekin, Josef

2007-01-01T23:59:59.000Z

222

Turbine cooling waxy oil  

SciTech Connect (OSTI)

A process for pipelining a waxy oil to essentially eliminate deposition of wax on the pipeline wall is described comprising: providing a pressurized mixture of the waxy oil and a gas; effecting a sudden pressure drop of the mixture of the oil and the gas through an expansion turbine, thereby expanding the gas and quickly cooling the oil to below its cloud point in the substantial absence of wax deposition and forming a slurry of wax particles and oil; and pipelining the slurry.

Geer, J.S.

1987-10-27T23:59:59.000Z

223

Essays on Macroeconomics and Oil  

E-Print Network [OSTI]

Oil Production in Venezuela and Mexico . . . . . . . . . .Venezuela with Mexico, another major oil pro- ducing countryOil Production and Productivity in Venezuela and Mexico . . . . . . . .

CAKIR, NIDA

2013-01-01T23:59:59.000Z

224

Essays on Macroeconomics and Oil  

E-Print Network [OSTI]

Oil Production in Venezuela and Mexico . . . . . . . . . .Oil Production and Productivity in Venezuela and Mexico . . . . . . . .2.6: Oil Production in Venezuela and Mexico 350 Productivity

CAKIR, NIDA

2013-01-01T23:59:59.000Z

225

AN ENGINE OIL LIFE ALGORITHM.  

E-Print Network [OSTI]

??An oil-life algorithm to calculate the remaining percentage of oil life is presented as a means to determine the right time to change the oil… (more)

Bommareddi, Anveshan

2009-01-01T23:59:59.000Z

226

Economics of Peak Oil  

Science Journals Connector (OSTI)

Abstract ‘Peak oil’ refers to the future decline in world production of crude oil and the accompanying potentially calamitous effects. The peak oil literature typically rejects economic analysis. This article argues that economic analysis is indeed appropriate for analyzing oil scarcity because standard economic models can replicate the observed peaks in oil production. Moreover, the emphasis on peak oil is misplaced as peaking is not a good indicator of scarcity, peak oil techniques are overly simplistic, the catastrophes predicted by the peak oil literature are unlikely, and the literature does not contribute to correcting identified market failures. Efficiency of oil markets could be improved by instead focusing on remedying market failures such as excessive private discount rates, environmental externalities, market power, insufficient innovation incentives, incomplete futures markets, and insecure property rights.

S.P. Holland

2013-01-01T23:59:59.000Z

227

Apparatus for distilling shale oil from oil shale  

SciTech Connect (OSTI)

An apparatus for distilling shale oil from oil shale comprises: a vertical type distilling furnace which is divided by two vertical partitions each provided with a plurality of vent apertures into an oil shale treating chamber and two gas chambers, said oil shale treating chamber being located between said two gas chambers in said vertical type distilling furnace, said vertical type distilling furnace being further divided by at least one horizontal partition into an oil shale distilling chamber in the lower part thereof and at least one oil shale preheating chamber in the upper part thereof, said oil shale distilling chamber and said oil shale preheating chamber communication with each other through a gap provided at an end of said horizontal partition, an oil shale supplied continuously from an oil shale supply port provided in said oil shale treating chamber at the top thereof into said oil shale treating chamber continuously moving from the oil shale preheating chamber to the oil shale distilling chamber, a high-temperature gas blown into an oil shale distilling chamber passing horizontally through said oil shale in said oil shale treating chamber, thereby said oil shale is preheated in said oil shale preheating chamber, and a gaseous shale oil is distilled from said preheated oil shale in said oil shale distilling chamber; and a separator for separating by liquefaction a gaseous shale oil from a gas containing the gaseous shale oil discharged from the oil shale preheating chamber.

Shishido, T.; Sato, Y.

1984-02-14T23:59:59.000Z

228

Advanced Fuels Synthesis  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Advanced Fuels Synthesis Advanced Fuels Synthesis Coal and Coal/Biomass to Liquids Advanced Fuels Synthesis The Advanced Fuels Synthesis Key Technology is focused on catalyst and reactor optimization for producing liquid hydrocarbon fuels from coal/biomass mixtures, supports the development and demonstration of advanced separation technologies, and sponsors research on novel technologies to convert coal/biomass to liquid fuels. Active projects within the program portfolio include the following: Fischer-Tropsch fuels synthesis Small Scale Coal Biomass Liquids Production Using Highly Selective Fischer Tropsch Catalyst Small Scale Pilot Plant for the Gasification of Coal and Coal/Biomass Blends and Conversion of Derived Syngas to Liquid Fuels Via Fischer-Tropsch Synthesis Coal Fuels Alliance: Design and Construction of Early Lead Mini Fischer-Tropsch Refinery

229

EA-1642S: Finding of No Significant Impact  

Broader source: Energy.gov [DOE]

Small-Scale Pilot Plant for the Gasification of Coal and Coal-Biomass Blends and Conversion of Derived Syngas to Liquid Fuels via Fischer-Tropsch Synthesis, Lexington, Kentucky

230

CX-002358: Categorical Exclusion Determination  

Broader source: Energy.gov [DOE]

Fischer-Tropsch Fuels DevelopmentCX(s) Applied: B3.6Date: 05/10/2010Location(s): Grand Forks, North DakotaOffice(s): Fossil Energy, National Energy Technology Laboratory

231

CX-011112: Categorical Exclusion Determination  

Broader source: Energy.gov [DOE]

Innovative Gasification to Produce Fischer-Tropsch Jet and Diesel Fuel CX(s) Applied: A9 Date: 08/15/2013 Location(s): Iowa Offices(s): Golden Field Office

232

Feasibility of Steam Hydrogasification of Microalgae for Production of Synthetic Fuels  

E-Print Network [OSTI]

and is followed by steam methane reforming ( SMR). The finalReaction: Steam Methane Reforming: Fischer–Tropsch Reaction:methane and steam in steam methane reforming generates the

Suemanotham, Amornrat

2014-01-01T23:59:59.000Z

233

NOx Emissions of Alternative Diesel Fuels:? A Comparative Analysis of Biodiesel and FT Diesel  

Science Journals Connector (OSTI)

This study explores the diesel injection and combustion processes in an effort to better understand the differences in NOx emissions between biodiesel, Fischer?Tropsch (FT) diesel, and their blends with a conventional diesel fuel. Emissions studies were ...

James P. Szybist; Stephen R. Kirby; André L. Boehman

2005-05-14T23:59:59.000Z

234

CX-009372: Categorical Exclusion Determination  

Broader source: Energy.gov [DOE]

Small Scale Coal-Biomass to Liquids Using Highly Selective Fischer-Tropsch Synthesis CX(s) Applied: A9 Date: 09/17/2012 Location(s): California Offices(s): National Energy Technology Laboratory

235

EA-1642S: Final Supplemental Environmental Assessment  

Broader source: Energy.gov [DOE]

Small-Scale Pilot Plant for the Gasification of Coal and Coal-Biomass Blends and Conversion of Derived Syngas to Liquid Fuels via Fischer-Tropsch Synthesis, Lexington, Kentucky

236

Analyzing Biomass Conversion into Liquid Hydrocarbons  

Science Journals Connector (OSTI)

Variants of the Fischer–Tropsch producer-gas conversion into liquid hydrocarbons are analyzed under the ... is attained in the reactions occurring in the biomass gasification. When the raw material is wood ... th...

V. D. Meshcheryakov; V. A. Kirillov

2002-09-01T23:59:59.000Z

237

Die Rolle der Kohlenwasserstoffe bei der Herstellung synthetischer Fettprodukte durch Oxydation in Deutschland  

Science Journals Connector (OSTI)

Es werden ein Gesamtüberblick über die Fischer-Tropsch-Synthese gegeben und die besonderen Reaktionsbedingungen beschrieben, die eine Paraffin-Bildung bei der Synthese begünstigen. Im Zusammenhang damit werden...

Anton Zwergal

238

Effect of engine operating parameters and fuel characteristics on diesel engine emissions  

E-Print Network [OSTI]

To examine the effects of using synthetic Fischer-Tropsch (FT) diesel fuel in a modern compression ignition engine, experiments were conducted on a MY 2002 Cummins 5.9 L diesel engine outfitted with high pressure, common ...

Acar, Joseph, 1977-

2005-01-01T23:59:59.000Z

239

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

coal through the Fischer-Tropsch process, and compressed or liquefied gas derived from biomass. For an entity to be eligible to claim the credit they must be liable for reporting...

240

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

coal through the Fischer-Tropsch process, and compressed or liquefied gas derived from biomass. The incentive must first be taken as a credit against the blender's alternative fuel...

Note: This page contains sample records for the topic "oils biomass-derived fischer-tropsch" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Theoretical Cluster Studies on the Catalytic Sulfidation of MoO3 Xue-Rong Shi,,,  

E-Print Network [OSTI]

, State Key Laboratory of Coal ConVersion, Institute of Coal Chemistry, Chinese Academy of Sciences (HDN) processes and exhibit also high activity for methanation and for the Fischer-Tropsch synthesis and sulfur adsor- bates as well as hydrogen

242

UHV Studies on CO and Methanol Adsorption and Decomposition on Pristine and Oxidized Alumina-Supported Co Nanoparticles  

Science Journals Connector (OSTI)

Although cobalt is an important Fischer-Tropsch catalyst, there is only limited fundamental knowledge about the factors determining the elementary steps, such as the dissociation of CO, the influence of adsorbed ...

T. Nowitzki; V. Zielasek; M. Bäumer

2009-01-01T23:59:59.000Z

243

Yosemite Waters Vehicle Evaluation Report: Final Results  

SciTech Connect (OSTI)

Document details the evaluation of Fischer-Tropsch diesel, a gas-to-liquid fuel, in medium-duty delivery vehicles at Yosemite Waters. The study was conducted by NREL at the company's Fullerton, California, bottling headquarters.

Eudy, L.; Barnitt, R.; Alleman, T. L.

2005-08-01T23:59:59.000Z

244

Chemicals from coal  

SciTech Connect (OSTI)

This chapter contains sections titled: Chemicals from Coke Oven Distillate; The Fischer-Tropsch Reaction; Coal Hydrogenation; Substitute Natural Gas (SNG); Synthesis Gas Technology; Calcium Carbide; Coal and the Environment; and Notes and References

Harold A. Wittcoff; Bryan G. Reuben; Jeffrey S. Plotkin

2004-12-01T23:59:59.000Z

245

Greenhouse Gas Emissions from Aviation and Marine Transportation: Mitigation Potential and Policies  

E-Print Network [OSTI]

to create a synthetic bio- based fuel that is chemicallyBoeing/NASA Synthetic bio-based fuels, Fischer-Tropsch (FT)ICAO 2009b). Synthetic bio-based fuels include bio-based jet

McCollum, David L; Gould, Gregory; Greene, David L

2010-01-01T23:59:59.000Z

246

Autothermal oxidative pyrolysis of biomass feedstocks over noble metal catalysts to liquid products.  

E-Print Network [OSTI]

??Two thermal processing technologies have emerged for processing biomass into renewable liquid products: pyrolysis and gasification/Fischer-Tropsch processing. The work presented here will demonstrate oxidative pyrolysis… (more)

Balonek, Christine Marie

2011-01-01T23:59:59.000Z

247

Catalytic Reforming of Biomass Raw Fuel Gas to Syngas for FT Liquid Fuels Production  

Science Journals Connector (OSTI)

The gasification of biomass to obtain a syngas provides a competitive means for clean FT (Fischer-Tropsch) liquid fuels from renewable resources. The feasibility of the process depends on the upgrading of raw ...

Tiejun Wang; Chenguang Wang; Qi Zhang…

2009-01-01T23:59:59.000Z

248

The Prospects for Coal-To-Liquid Conversion: A General Equilibrium Analysis  

E-Print Network [OSTI]

We investigate the economics of coal-to-liquid (CTL) conversion, a polygeneration technology that produces liquid fuels, chemicals, and electricity by coal gasification and Fischer-Tropsch process. CTL is more expensive ...

Chen, Y.-H. Henry

249

Coal liquefaction and gas conversion: Proceedings. Volume 2  

SciTech Connect (OSTI)

Volume II contains papers presented at the following sessions: Indirect Liquefaction (oxygenated fuels); and Indirect Liquefaction (Fischer-Tropsch technology). Selected papers have been processed separately for inclusion in the Energy Science and Technology Database.

Not Available

1993-12-31T23:59:59.000Z

250

Oil and Gas Supply Module  

Gasoline and Diesel Fuel Update (EIA)

Onshore Lower 48 Oil and Gas Supply Submodule, Offshore Oil and Gas Supply Submodule, Oil Shale Supply Submodule1, and Alaska Oil and Gas Supply Submodule. A detailed description...

251

Oil and Gas Supply Module  

Gasoline and Diesel Fuel Update (EIA)

Onshore Lower 48 Oil and Gas Supply Submodule, Offshore Oil and Gas Supply Submodule, Oil Shale Supply Submodule, and Alaska Oil and Gas Supply Submodule. A detailed description of...

252

Oil and Gas Exploration  

E-Print Network [OSTI]

Metals Industrial Minerals Oil and Gas Geothermal Exploration Development Mining Processing Nevada, oil and gas, and geothermal activities and accomplishments in Nevada: production statistics, exploration and development including drilling for petroleum and geothermal resources, discoveries of ore

Tingley, Joseph V.

253

China's Global Oil Strategy  

E-Print Network [OSTI]

21, 2008. Ying, Wang. “ China, Venezuela firms to co-developApril 21, “China and Venezuela sign oil agreements. ” Chinaaccessed April 21, “Venezuela and China sign oil deal. ” BBC

Thomas, Bryan G

2009-01-01T23:59:59.000Z

254

Using Oils As Pesticides  

E-Print Network [OSTI]

Petroleum and plant-derived spray oils show increasing potential for use as part of Integrated Pest Management systems for control of soft-bodied pests on fruit trees, shade trees, woody ornamentals and household plants. Sources of oils, preparing...

Bogran, Carlos E.; Ludwig, Scott; Metz, Bradley

2006-10-30T23:59:59.000Z

255

Residential heating oil price  

Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

heating oil price decreases The average retail price for home heating oil fell 6.3 cents from a week ago to 2.91 per gallon. That's down 1.10 from a year ago, based on the...

256

Residential heating oil price  

U.S. Energy Information Administration (EIA) Indexed Site

heating oil price decreases The average retail price for home heating oil fell 7.5 cents from a week ago to 2.84 per gallon. That's down 1.22 from a year ago, based on the...

257

Residential heating oil price  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

heating oil price decreases The average retail price for home heating oil fell 7.6 cents from a week ago to 2.97 per gallon. That's down 1.05 from a year ago, based on the...

258

Residential heating oil price  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

heating oil price decreases The average retail price for home heating oil fell 3.6 cents from a week ago to 3.04 per gallon. That's down 99.4 cents from a year ago, based on the...

259

US Crude oil exports  

Gasoline and Diesel Fuel Update (EIA)

2014 EIA Energy Conference U.S. Crude Oil Exports July 14, 2014 By Lynn D. Westfall U.S. Energy Information Administration U.S. crude oil production has grown by almost 50% since...

260

Oil shale retorted underground  

Science Journals Connector (OSTI)

Oil shale retorted underground ... Low-temperature underground retorting of oil shale produces a crude oil with many attractive properties, Dr. George R. Hill of the University of Utah told a meeting of the American Institute of Mining, Metallurgical, and Petroleum Engineers last week in Los Angeles. ... Typical above-ground retorting of oil shale uses temperatures of 900° to 1100° F. because of the economic need ... ...

1967-02-27T23:59:59.000Z

Note: This page contains sample records for the topic "oils biomass-derived fischer-tropsch" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Biochemical upgrading of oils  

DOE Patents [OSTI]

A process for biochemical conversion of heavy crude oils is provided. The process includes contacting heavy crude oils with adapted biocatalysts. The resulting upgraded oil shows, a relative increase in saturated hydrocarbons, emulsions and oxygenates and a decrease in compounds containing organic sulfur, organic nitrogen and trace metals. Adapted microorganisms which have been modified under challenged growth processes are also disclosed. 121 figs.

Premuzic, E.T.; Lin, M.S.

1999-01-12T23:59:59.000Z

262

Exploiting heavy oil reserves  

E-Print Network [OSTI]

North Sea investment potential Exploiting heavy oil reserves Beneath the waves in 3D Aberdeen the potential of heavy oil 8/9 Taking the legal lessons learned in the north Sea to a global audience 10 potential Exploiting heavy oil reserves Aberdeen: A community of science AT WORK FOR THE ENERGY SECTOR ISSUE

Levi, Ran

263

Utah Heavy Oil Program  

SciTech Connect (OSTI)

The Utah Heavy Oil Program (UHOP) was established in June 2006 to provide multidisciplinary research support to federal and state constituents for addressing the wide-ranging issues surrounding the creation of an industry for unconventional oil production in the United States. Additionally, UHOP was to serve as an on-going source of unbiased information to the nation surrounding technical, economic, legal and environmental aspects of developing heavy oil, oil sands, and oil shale resources. UHOP fulGilled its role by completing three tasks. First, in response to the Energy Policy Act of 2005 Section 369(p), UHOP published an update report to the 1987 technical and economic assessment of domestic heavy oil resources that was prepared by the Interstate Oil and Gas Compact Commission. The UHOP report, entitled 'A Technical, Economic, and Legal Assessment of North American Heavy Oil, Oil Sands, and Oil Shale Resources' was published in electronic and hard copy form in October 2007. Second, UHOP developed of a comprehensive, publicly accessible online repository of unconventional oil resources in North America based on the DSpace software platform. An interactive map was also developed as a source of geospatial information and as a means to interact with the repository from a geospatial setting. All documents uploaded to the repository are fully searchable by author, title, and keywords. Third, UHOP sponsored Give research projects related to unconventional fuels development. Two projects looked at issues associated with oil shale production, including oil shale pyrolysis kinetics, resource heterogeneity, and reservoir simulation. One project evaluated in situ production from Utah oil sands. Another project focused on water availability and produced water treatments. The last project considered commercial oil shale leasing from a policy, environmental, and economic perspective.

J. Bauman; S. Burian; M. Deo; E. Eddings; R. Gani; R. Goel; C.K. Huang; M. Hogue; R. Keiter; L. Li; J. Ruple; T. Ring; P. Rose; M. Skliar; P.J. Smith; J.P. Spinti; P. Tiwari; J. Wilkey; K. Uchitel

2009-10-20T23:59:59.000Z

264

Manufacture of refrigeration oils  

SciTech Connect (OSTI)

Lubricating oils suitable for use in refrigeration equipment in admixture with fluorinated hydrocarbon refrigerants are produced by solvent extraction of naphthenic lubricating oil base stocks, cooling the resulting extract mixture, optionally with the addition of a solvent modifier, to form a secondary raffinate and a secondary extract, and recovering a dewaxed oil fraction of lowered pour point from the secondary raffinate as a refrigeration oil product. The process of the invention obviates the need for a separate dewaxing operation, such as dewaxing with urea, as conventionally employed for the production of refrigeration oils.

Chesluk, R.P.; Platte, H.J.; Sequeira, A.J.

1981-12-08T23:59:59.000Z

265

Carcinogenicity Studies of Estonian Oil Shale Soots  

E-Print Network [OSTI]

determine the carcinogenicity of Estonian oil shale soot as well as the soot from oil shale fuel oil. All

A. Vosamae

266

Crude Oil, Heating Oil, and Propane Market Outlook  

Gasoline and Diesel Fuel Update (EIA)

Oil, Heating Oil, and Propane Market Outlook Oil, Heating Oil, and Propane Market Outlook 8/13/01 Click here to start Table of Contents Crude Oil, Heating Oil, and Propane Market Outlook Short-Term World Oil Price Forecast Price Movements Related to Supply/Demand Balance OPEC Production Likely To Remain Low U.S. Reflects World Market Crude Oil Outlook Conclusions Distillate Prices Increase With Crude Oil Distillate Stocks on the East Coast Were Very Low Entering Last Winter Distillate Demand Strong Last Winter More Supply Possible This Fall than Forecast Distillate Fuel Oil Imports Could Be Available - For A Price Distillate Supply/Demand Balance Reflected in Spreads Distillate Stocks Expected to Remain Low Winter Crude Oil and Distillate Price Outlook Heating Oil Outlook Conclusion Propane Prices Follow Crude Oil

267

Crude Oil Analysis Database  

DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

The composition and physical properties of crude oil vary widely from one reservoir to another within an oil field, as well as from one field or region to another. Although all oils consist of hydrocarbons and their derivatives, the proportions of various types of compounds differ greatly. This makes some oils more suitable than others for specific refining processes and uses. To take advantage of this diversity, one needs access to information in a large database of crude oil analyses. The Crude Oil Analysis Database (COADB) currently satisfies this need by offering 9,056 crude oil analyses. Of these, 8,500 are United States domestic oils. The database contains results of analysis of the general properties and chemical composition, as well as the field, formation, and geographic location of the crude oil sample. [Taken from the Introduction to COAMDATA_DESC.pdf, part of the zipped software and database file at http://www.netl.doe.gov/technologies/oil-gas/Software/database.html] Save the zipped file to your PC. When opened, it will contain PDF documents and a large Excel spreadsheet. It will also contain the database in Microsoft Access 2002.

Shay, Johanna Y.

268

World Oil: Market or Mayhem?  

E-Print Network [OSTI]

The world oil market is regarded by many as a puzzle. Why are oil prices so volatile? What is OPEC and what does OPEC do? Where are oil prices headed in the long run? Is “peak oil” a genuine concern? Why did oil prices ...

Smith, James L.

2008-01-01T23:59:59.000Z

269

Vegetable oil fuel  

SciTech Connect (OSTI)

In this article, the future role of renewable agricultural resources in providing fuel is discussed. it was only during this century that U.S. farmers began to use petroleum as a fuel for tractors as opposed to forage crop as fuel for work animals. Now farmers may again turn to crops as fuel for agricultural production - the possible use of sunflower oil, soybean oil and rapeseed oil as substitutes for diesel fuel is discussed.

Bartholomew, D.

1981-04-01T23:59:59.000Z

270

US oil consumption, oil prices, and the macroeconomy  

Science Journals Connector (OSTI)

Since the oil price shock of 1973–74, researchers have waged ... national income. Studies examining the relationship between oil prices, oil consumption, and real output have produced remarkably ... to dramatical...

Ali F. Darrat; Otis W. Gilley; Don J. Meyer

1996-01-01T23:59:59.000Z

271

Lower oil prices also cutting winter heating oil and propane...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Lower oil prices also cutting winter heating oil and propane bills Lower oil prices are not only driving down gasoline costs, but U.S. consumers will also see a bigger savings in...

272

Effects of Oil and Oil Dispersants on the Marine Environment  

Science Journals Connector (OSTI)

13 April 1971 research-article Effects of Oil and Oil Dispersants on the Marine Environment R. G. J. Shelton In the context of marine pollution, the term 'oil' can cover a very wide range of substances and usually...

1971-01-01T23:59:59.000Z

273

Enhanced Oil Recovery to Fuel Future Oil Demands | GE Global...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

to Fuel Future Oil Demands Enhanced Oil Recovery to Fuel Future Oil Demands Trevor Kirsten 2013.10.02 I'm Trevor Kirsten and I lead a team of GE researchers that investigate a...

274

Oil and Gas (Indiana)  

Broader source: Energy.gov [DOE]

This division of the Indiana Department of Natural Resources provides information on the regulation of oil and gas exploration, wells and well spacings, drilling, plugging and abandonment, and...

275

Waste oil reduction: GKN  

SciTech Connect (OSTI)

This report details the steps required to establish a waste oil management program. Such a program can reduce operational costs, cut wastewater treatment costs and produce a better quality wastewater effluent through such means as: reducing the volume of oils used; segregating oils at the source of generation for recovery and reuse; and reducing the quality of oily wastewater generated. It discusses the metal-working fluid recovery options available for such a program, namely settling, filtration, hydrocyclone, and centrifugation. Included are source lists for vendors of oil skimmer equipment and coolant recovery systems.

Hunt, G.

1995-08-01T23:59:59.000Z

276

Understanding Crude Oil Prices  

E-Print Network [OSTI]

disruptions, and the peak in U.S. oil production account foroil increased 81.1% (logarithmically) between January 1979 and the peak

Hamilton, James Douglas

2008-01-01T23:59:59.000Z

277

What substitutes for oil?  

Science Journals Connector (OSTI)

... bagasse, ethyl alcohol, vegetable oils, methane and hydrogen; as well as hydro and nuclear power generation, conservation methods, and solar, wind and tidal energy.

David Spurgeon

1978-06-29T23:59:59.000Z

278

Crude Oil Prices  

Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

Information AdministrationPetroleum Marketing Annual 2001 41 Table 21. Domestic Crude Oil First Purchase Prices (Dollars per Barrel) - Continued Year Month PAD District II...

279

Crude Oil Prices  

U.S. Energy Information Administration (EIA) Indexed Site

Information AdministrationPetroleum Marketing Annual 2002 41 Table 21. Domestic Crude Oil First Purchase Prices (Dollars per Barrel) - Continued Year Month PAD District II...

280

Crude Oil Prices  

Gasoline and Diesel Fuel Update (EIA)

Information AdministrationPetroleum Marketing Annual 2000 41 Table 21. Domestic Crude Oil First Purchase Prices (Dollars per Barrel) - Continued Year Month PAD District II...

Note: This page contains sample records for the topic "oils biomass-derived fischer-tropsch" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Crude Oil Prices  

Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

Information AdministrationPetroleum Marketing Annual 1999 41 Table 21. Domestic Crude Oil First Purchase Prices (Dollars per Barrel) - Continued Year Month PAD District II...

282

Crude Oil Prices  

U.S. Energy Information Administration (EIA) Indexed Site

Information AdministrationPetroleum Marketing Annual 1998 41 Table 21. Domestic Crude Oil First Purchase Prices (Dollars per Barrel) - Continued Year Month PAD District II...

283

NETL: Oil & Gas  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Oil & Gas Publications KMD Contacts Project Summaries EPAct 2005 Arctic Energy Office Announcements Software Stripper Wells Efficient recovery of our nation's fossil fuel resources...

284

PIA - Northeast Home Heating Oil Reserve System (Heating Oil...  

Office of Environmental Management (EM)

Home Heating Oil Reserve System (Heating Oil) More Documents & Publications PIA - WEB Physical Security Major Application PIA - GovTrip (DOE data) PIA - WEB Unclassified...

285

Lead Corrosion and Oil Oxidation  

Science Journals Connector (OSTI)

... tests the horn was AISI 304, the balls were variously high purity Al, Cu, SAE 52100 steel, and Pb. The oil was a refined paraffinic mineral oil into which ... oil Bearing

J. K. APPELDOORN; P. PACOR; V. RIDDEI

1972-10-20T23:59:59.000Z

286

Oil shale technology  

SciTech Connect (OSTI)

Oil shale is undoubtedly an excellent energy source that has great abundance and world-wide distribution. Oil shale industries have seen ups and downs over more than 100 years, depending on the availability and price of conventional petroleum crudes. Market forces as well as environmental factors will greatly affect the interest in development of oil shale. Besides competing with conventional crude oil and natural gas, shale oil will have to compete favorably with coal-derived fuels for similar markets. Crude shale oil is obtained from oil shale by a relatively simple process called retorting. However, the process economics are greatly affected by the thermal efficiencies, the richness of shale, the mass transfer effectiveness, the conversion efficiency, the design of retort, the environmental post-treatment, etc. A great many process ideas and patents related to the oil shale pyrolysis have been developed; however, relatively few field and engineering data have been published. Due to the vast heterogeneity of oil shale and to the complexities of physicochemical process mechanisms, scientific or technological generalization of oil shale retorting is difficult to achieve. Dwindling supplied of worldwide petroleum reserves, as well as the unprecedented appetite of mankind for clean liquid fuel, has made the public concern for future energy market grow rapidly. the clean coal technology and the alternate fuel technology are currently of great significance not only to policy makers, but also to process and chemical researchers. In this book, efforts have been made to make a comprehensive text for the science and technology of oil shale utilization. Therefore, subjects dealing with the terminological definitions, geology and petrology, chemistry, characterization, process engineering, mathematical modeling, chemical reaction engineering, experimental methods, and statistical experimental design, etc. are covered in detail.

Lee, S. (Akron Univ., OH (United States). Dept. of Chemical Engineering)

1991-01-01T23:59:59.000Z

287

Societal lifecycle costs of cars with alternative fuels/engines  

Science Journals Connector (OSTI)

Effectively addressing concerns about air pollution (especially health impacts of small-particle air pollution), climate change, and oil supply insecurity will probably require radical changes in automotive engine/fuel technologies in directions that offer both the potential for achieving near-zero emissions of air pollutants and greenhouse gases and a diversification of the transport fuel system away from its present exclusive dependence on petroleum. The basis for comparing alternative automotive engine/fuel options in evolving toward these goals in the present analysis is the “societal lifecycle cost” of transportation, including the vehicle first cost (assuming large-scale mass production), fuel costs (assuming a fully developed fuel infrastructure), externality costs for oil supply security, and damage costs for emissions of air pollutants and greenhouse gases calculated over the full fuel cycle. Several engine/fuel options are considered—including current gasoline internal combustion engines and a variety of advanced lightweight vehicles: internal combustion engine vehicles fueled with gasoline or hydrogen; internal combustion engine/hybrid electric vehicles fueled with gasoline, compressed natural gas, Diesel, Fischer–Tropsch liquids or hydrogen; and fuel cell vehicles fueled with gasoline, methanol or hydrogen (from natural gas, coal or wind power). To account for large uncertainties inherent in the analysis (for example in environmental damage costs, in oil supply security costs and in projected mass-produced costs of future vehicles), lifecycle costs are estimated for a range of possible future conditions. Under base-case conditions, several advanced options have roughly comparable lifecycle costs that are lower than for today's conventional gasoline internal combustion engine cars, when environmental and oil supply insecurity externalities are counted—including advanced gasoline internal combustion engine cars, internal combustion engine/hybrid electric cars fueled with gasoline, Diesel, Fischer–Tropsch liquids or compressed natural gas, and hydrogen fuel cell cars. The hydrogen fuel cell car stands out as having the lowest externality costs of any option and, when mass produced and with high valuations of externalities, the least projected lifecycle cost. Particular attention is given to strategies that would enhance the prospects that the hydrogen fuel cell car would eventually become the Car of the Future, while pursuing innovations relating to options based on internal combustion engines that would both assist a transition to hydrogen fuel cell cars and provide significant reductions of externality costs in the near term.

Joan M Ogden; Robert H Williams; Eric D Larson

2004-01-01T23:59:59.000Z

288

CONGRESS BLASTS OIL INDUSTRY  

Science Journals Connector (OSTI)

IN PACKED HEARINGS last week before angry members of Congress, the heads of BP, ExxonMobil, Chevron, ConocoPhillips, and Shell Oil defended their industry in light of the April 20 BP oil rig explosion in the Gulf of Mexico, which has led to the worst ...

JEFF JOHNSON

2010-06-21T23:59:59.000Z

289

Oil Quantity : The histori  

E-Print Network [OSTI]

model for Prudhoe Bay. Figure 11: Historical Prudhoe Bay oil production data, modeled economically Production (million bbl per Month) Historical Production Best Fit (Hist. Tax w/ELF, Ref. P) High Price 120 140 160 19 Oil Quantity Con Wel N E A N N ng Results e Bay : The histori Bay over tim : Prudhoe Ba

Lin, C.-Y. Cynthia

290

The Geopolitics of Oil  

Science Journals Connector (OSTI)

...reduce their production by a similar...barrels ofoil a day. Although the...barrels of oil per day. It is likely...Virtually all the OPEC producers, particularly...their oil. In 1973, 90 percent...increase indigenous production, and ac-celerate...

1980-12-19T23:59:59.000Z

291

Balancing oil and environment... responsibly.  

SciTech Connect (OSTI)

Balancing Oil and Environment…Responsibly As the price of oil continues to skyrocket and global oil production nears the brink, pursuing unconventional oil supplies, such as oil shale, oil sands, heavy oils, and oils from biomass and coal has become increasingly attractive. Of particular significance to the American way is that our continent has significant quantities of these resources. Tapping into these new resources, however, requires cutting-edge technologies for identification, production, processing and environmental management. This job needs a super hero or two for a job of this size and proportion…

Weimer, Walter C.; Teske, Lisa

2007-01-25T23:59:59.000Z

292

Essays on Macroeconomics and Oil  

E-Print Network [OSTI]

Oil Production in Venezuela and Mexico . . . . . . . . . .and Productivity in Venezuela and Mexico . . . . . . . . OilEllner, ”Organized Labor in Venezuela 1958-1991: Behavior

CAKIR, NIDA

2013-01-01T23:59:59.000Z

293

Chinaâs Oil Diplomacy with Russia.  

E-Print Network [OSTI]

??In Chinaâs view, it is necessary to get crude oil and oil pipeline. Under Russia and China strategic partnership, China tries to obtain âlong term… (more)

Chao, Jiun-chuan

2011-01-01T23:59:59.000Z

294

Peak oil: diverging discursive pipelines.  

E-Print Network [OSTI]

??Peak oil is the claimed moment in time when global oil production reaches its maximum rate and henceforth forever declines. It is highly controversial as… (more)

Doctor, Jeff

2012-01-01T23:59:59.000Z

295

Slide 1  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

and Impact Identification of inexpensive, highly selective catalysts for upgrade of biomass derivatives produced from sugars or pyrolysis bio-oil is essential for...

296

oil | OpenEI  

Open Energy Info (EERE)

oil oil Dataset Summary Description This dataset comes from the Energy Information Administration (EIA), and is part of the 2011 Annual Energy Outlook Report (AEO2011). This dataset is table 134, and contains only the reference case. The data is broken down into Crude oil, dry natural gas. Source EIA Date Released April 26th, 2011 (3 years ago) Date Updated Unknown Keywords 2011 AEO EIA end-of-year reserves gas oil Data application/vnd.ms-excel icon AEO2011: Oil and Gas End-of-Year Reserves and Annual Reserve Additions- Reference Case (xls, 58.4 KiB) Quality Metrics Level of Review Peer Reviewed Comment Temporal and Spatial Coverage Frequency Annually Time Period 2008-2035 License License Open Data Commons Public Domain Dedication and Licence (PDDL) Comment Rate this dataset

297

Chapter 5 - Crude Oil  

Science Journals Connector (OSTI)

Abstract Oil has been the number one source of energy in the world since the middle of the twentieth century. The world is very dependent on petroleum for transportation fuels, petrochemicals and asphalt. But ever increasing demand has caused the price of oil to spike in recent years, and only the world economic crisis has been able to temper demand and bring the price down to more reasonable levels. However, the demand and price are likely to shoot up again when the economy recovers. At the same time, the peak oil theory of M. King Hubbert predicts that world oil production is likely to peak soon. This prediction raises questions about what source of energy will come to the fore when oil is not able to keep up.

Brian F. Towler

2014-01-01T23:59:59.000Z

298

Selected Abstracts & Bibliography of International Oil Spill Research, through 1998  

E-Print Network [OSTI]

Kuwait, Middle East, oil and gas fields, oil refinery, oil waste, oil well,Equipment Kuwait Oil Co. 1991. Mideast well fire, oil spillKuwait, Persian Gulf, Saudia Arabia, Oil spill, cleanup, oil spills, crude, oil spill incidents, oil spills-pipeline, warfare, oil skimmers, oil wells,

Louisiana Applied Oil Spill Research & Development Program Electronic Bibliography

1998-01-01T23:59:59.000Z

299

OpenEI - oil  

Open Energy Info (EERE)

/0 en AEO2011: Oil and Gas /0 en AEO2011: Oil and Gas End-of-Year Reserves and Annual Reserve Additions http://en.openei.org/datasets/node/805 This dataset comes from the Energy Information Administration (EIA), and is part of the 2011 Annual Energy Outlook Report (AEO2011). This dataset is table 134, and contains only the reference case. The data is broken down into Crude oil, dry natural gas. 

License
Type of License: 

300

HS_Oil_Studyguide.indd  

Broader source: Energy.gov (indexed) [DOE]

Oil Oil Fossil Energy Study Guide: Oil Pet roleum-or cr ude oil-is a fossil fuel that is found in large quantities beneath the Earth's sur face and is often used as a fuel or raw material in the chemical indust r y. It is a smelly, yellow-to-black liquid and is usually found in underg round areas called reser voirs. If you could look down an oil well and see oil where Nature created it, you might be surprised. You wouldn't see a big underground lake, as a lot of people think. Oil doesn't exist in deep, black pools. In fact, an underground oil formation-an "oil reservoir"-looks very much like any other rock formation. Oil exists in this underground formation as tiny droplets trapped inside the open spaces, called "pores," inside rocks. Th

Note: This page contains sample records for the topic "oils biomass-derived fischer-tropsch" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

MS_Oil_Studyguide.indd  

Broader source: Energy.gov (indexed) [DOE]

LOOKING DOWN AN OIL WELL LOOKING DOWN AN OIL WELL Ever wonder what oil looks like underground, down deep, hundreds or thousands of feet below the surface, buried under millions of tons of rock and dirt? If you could look down an oil well and see oil where nature created it, you might be surprised. You wouldn't see a big underground lake, as a lot of people think. Oil doesn't exist in deep, black pools. In fact, an underground oil formation-called an "oil reservoir" -looks very much like any other rock formation. It looks a lot like...well, rock. Oil exists underground as tiny droplets trapped inside the open spaces, called "pores," inside rocks. Th e "pores" and the oil droplets can be seen only through a microscope. Th e droplets cling to the rock, like drops of water cling

302

Oil and Gas Supply Module  

U.S. Energy Information Administration (EIA) Indexed Site

Oil and Gas Supply Module Oil and Gas Supply Module This page inTenTionally lefT blank 119 U.S. Energy Information Administration | Assumptions to the Annual Energy Outlook 2013 Oil and Gas Supply Module The NEMS Oil and Gas Supply Module (OGSM) constitutes a comprehensive framework with which to analyze crude oil and natural gas exploration and development on a regional basis (Figure 8). The OGSM is organized into 4 submodules: Onshore Lower 48 Oil and Gas Supply Submodule, Offshore Oil and Gas Supply Submodule, Oil Shale Supply Submodule[1], and Alaska Oil and Gas Supply Submodule. A detailed description of the OGSM is provided in the EIA publication, Model Documentation Report: The Oil and Gas Supply Module (OGSM), DOE/EIA-M063(2011), (Washington, DC, 2011). The OGSM provides

303

Oil Price Volatility  

U.S. Energy Information Administration (EIA) Indexed Site

Speculation and Oil Price Volatility Speculation and Oil Price Volatility Robert J. Weiner Robert J. Weiner Professor of International Business, Public Policy & Professor of International Business, Public Policy & Public Administration, and International Affairs Public Administration, and International Affairs George Washington University; George Washington University; Membre Associ Membre Associ é é , GREEN, Universit , GREEN, Universit é é Laval Laval EIA Annual Conference Washington Washington 7 April 2009 7 April 2009 1 FACTORS DRIVNG OIL PRICE VOLATILITY FACTORS DRIVNG OIL PRICE VOLATILITY ► ► Market fundamentals Market fundamentals . . Fluctuations in supply, Fluctuations in supply, demand, and market power demand, and market power Some fundamentals related to expectations of Some fundamentals related to expectations of

304

Winter Crude Oil and  

Gasoline and Diesel Fuel Update (EIA)

4 4 Notes: While the relatively low stock forecast (although not as low as last winter) adds some extra pressure to prices, the price of crude oil could be the major factor affecting heating oil prices this winter. The current EIA forecast shows residential prices averaging $1.29 this winter, assuming no volatility. The average retail price is about 7 cents less than last winter, but last winter included the price spike in November 2000, December 2000, and January 2001. Underlying crude oil prices are currently expected to be at or below those seen last winter. WTI averaged over $30 per barrel last winter, and is currently forecast to average about $27.50 per barrel this winter. As those of you who watch the markets know, there is tremendous uncertainty in the amount of crude oil supply that will be available this winter. Less

305

Oil Market Assessment  

Gasoline and Diesel Fuel Update (EIA)

Logo Oil Market Assessment - September Logo Oil Market Assessment - September 12, 2001 EIA Home Page Based on Energy Information Administration (EIA) contacts and trade press reports, overall U.S. and global oil supplies appear to have been minimally impacted by yesterday's terrorist attacks on the World Trade Center and the Pentagon. Rumors of scattered closures of U.S. refineries, pipelines, and terminals were reported, and Louisiana Offshore Oil Port operations were partially suspended. While the NYMEX and New York Harbor were temporarily closed, operations are expected to resume soon. Most, if not all petroleum industry infrastructure is expected to resume normal operations today or in the very near term. Prices at all levels (where markets were open) posted increases yesterday, but many prices fell today, as initial reactions

306

Residential Heating Oil Prices  

Gasoline and Diesel Fuel Update (EIA)

This chart highlights residential heating oil prices for the current and This chart highlights residential heating oil prices for the current and past heating season. As you can see, prices have started the heating season, about 40 to 50 cents per gallon higher than last year at this time. The data presented are from EIA's State Heating Oil and Propane Program. We normally collect and publish this data twice a month, but given the low stocks and high prices, we started tracking the prices weekly. These data will also be used to determine the price trigger mechanism for the Northeast Heating Oil Reserve. The data are published at a State and regional level on our web site. The slide is to give you some perspective of what is happening in these markets, since you probably will get a number of calls from local residents about their heating fuels bills

307

India: Becoming well oiled  

Science Journals Connector (OSTI)

... been stirred into vigorous action and its redoubled efforts to find more oil onshore and offshore are beginning to yield results. From onshore fields in Assam and Gujarat, production this ... figure will go up to 11 million tonnes.

Correspondent

1976-04-01T23:59:59.000Z

308

Production of Shale Oil  

E-Print Network [OSTI]

Intensive pre-project feasibility and engineering studies begun in 1979 have produced an outline plan for development of a major project for production of shale oil from private lands in the Piceance Basin in western Colorado. This outline plan...

Loper, R. D.

1982-01-01T23:59:59.000Z

309

Steadying of oil prices  

Science Journals Connector (OSTI)

Oil prices have fallen below the 30 dollar mark ... in the lower half of OPEC’s target price band. Will OPEC manage to maintain high prices and revenues by restricting production?

Klaus Matthies

310

Imbibition assisted oil recovery  

E-Print Network [OSTI]

analyzed in detail to investigate oil recovery during spontaneous imbibition with different types of boundary conditions. The results of these studies have been upscaled to the field dimensions. The validity of the new definition of characteristic length...

Pashayev, Orkhan H.

2004-11-15T23:59:59.000Z

311

Sound Oil Company  

Broader source: Energy.gov (indexed) [DOE]

Sound Oil Company Sound Oil Company file:///C|/Documents%20and%20Settings/blackard/Desktop/EIA/LEE0152.HTM[11/29/2012 2:30:44 PM] DECISION AND ORDER OF THE DEPARTMENT OF ENERGY Application for Exception Name of Petitioner: Sound Oil Company Date of Filing: August 16, 1994 Case Number: LEE-0152 On August 16, 1994, Sound Oil Company (Sound) of Seattle Washington, filed an Application for Exception with the Office of Hearings and Appeals of the Department of Energy. In its Application, Sound requests that it be relieved of the requirement that it file the Energy Information Administration's (EIA) form entitled "Resellers'/Retailers' Monthly Petroleum Product Sales Report" (Form EIA-782B). As explained below, we have determined that the Application for Exception should be denied.

312

Oil Reserves and Production  

Science Journals Connector (OSTI)

...research-article Oil Reserves and Production Eric Drake The growth of world energy requirements over the last...remaining proved recoverable reserves will probably decline continuously...to grow. The declining reserves will be insufficient to...

1974-01-01T23:59:59.000Z

313

Crude Oil Prices  

Gasoline and Diesel Fuel Update (EIA)

20.86 20.67 20.47 20.24 20.32 19.57 See footnotes at end of table. 21. Domestic Crude Oil First Purchase Prices Energy Information Administration Petroleum Marketing Annual...

314

Crude Oil Prices  

Gasoline and Diesel Fuel Update (EIA)

19.11 18.73 18.63 17.97 18.75 18.10 See footnotes at end of table. 21. Domestic Crude Oil First Purchase Prices Energy Information Administration Petroleum Marketing Annual...

315

Oil shale research in China  

SciTech Connect (OSTI)

There have been continued efforts and new emergence in oil shale research in Chine since 1980. In this paper, the studies carried out in universities, academic, research and industrial laboratories in recent years are summarized. The research areas cover the chemical structure of kerogen; thermal behavior of oil shale; drying, pyrolysis and combustion of oil shale; shale oil upgrading; chemical utilization of oil shale; retorting waste water treatment and economic assessment.

Jianqiu, W.; Jialin, Q. (Beijing Graduate School, Petroleum Univ., Beijing (CN))

1989-01-01T23:59:59.000Z

316

Biocatalysis in Oil Refining  

SciTech Connect (OSTI)

Biocatalysis in Oil Refining focuses on petroleum refining bioprocesses, establishing a connection between science and technology. The micro organisms and biomolecules examined for biocatalytic purposes for oil refining processes are thoroughly detailed. Terminology used by biologists, chemists and engineers is brought into a common language, aiding the understanding of complex biological-chemical-engineering issues. Problems to be addressed by the future R&D activities and by new technologies are described and summarized in the last chapter.

Borole, Abhijeet P [ORNL; Ramirez-Corredores, M. M. [BP Global Fuels Technology

2007-01-01T23:59:59.000Z

317

Oil spill response resources  

E-Print Network [OSTI]

from Marathon Oil Company for their encouragement and support. Last, but not least, I would like to thank Lynette Schlandt for her help during my stay at this University. vu TABLE OF CONTENTS Page ABSTRACT. . . . . nl DEDICATION... tool for control. The State of Texas passed and implemented OSPRA (Oil Spill Prevention and Response Act) of 1991. The most significant requirement for both these laws was the need for a Facility Response Plan for the companies. This would help a...

Muthukrishnan, Shankar

2012-06-07T23:59:59.000Z

318

Oil/gas collector/separator for underwater oil leaks  

DOE Patents [OSTI]

An oil/gas collector/separator for recovery of oil leaking, for example, from an offshore or underwater oil well. The separator is floated over the point of the leak and tethered in place so as to receive oil/gas floating, or forced under pressure, toward the water surface from either a broken or leaking oil well casing, line, or sunken ship. The separator is provided with a downwardly extending skirt to contain the oil/gas which floats or is forced upward into a dome wherein the gas is separated from the oil/water, with the gas being flared (burned) at the top of the dome, and the oil is separated from water and pumped to a point of use. Since the density of oil is less than that of water it can be easily separated from any water entering the dome.

Henning, Carl D. (Livermore, CA)

1993-01-01T23:59:59.000Z

319

Optimising the Use of Spent Oil Shale.  

E-Print Network [OSTI]

??Worldwide deposits of oil shales are thought to represent ~3 trillion barrels of oil. Jordanian oil shale deposits are extensive and high quality, and could… (more)

FOSTER, HELEN,JANE

2014-01-01T23:59:59.000Z

320

WASTEWATER TREATMENT IN THE OIL SHALE INDUSTRY  

E-Print Network [OSTI]

during oil shale retorting: retort water and gas condensate.commercial oil shale plant, retort water and gas condensateunique to an oil shale retort water, gas condensate, and

Fox, J.P.

2010-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "oils biomass-derived fischer-tropsch" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Enhanced Oil Recovery | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Enhanced Oil Recovery Enhanced Oil Recovery Cross-section illustrating how carbon dioxide and water can be used to flush residual oil from a subsurface rock formation between...

322

Oil Prices and Long-Run Risk.  

E-Print Network [OSTI]

??I show that relative levels of aggregate consumption and personal oil consumption provide anexcellent proxy for oil prices, and that high oil prices predict low… (more)

READY, ROBERT

2011-01-01T23:59:59.000Z

323

heavy_oil | netl.doe.gov  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Heavy Oil Publications KMD Contacts Project Summaries EPAct 2005 Arctic Energy Office Announcements Software Stripper Wells Heavy oil is a vast U.S. oil resource that is...

324

Deepwater Oil & Gas Resources | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Deepwater Oil & Gas Resources Deepwater Oil & Gas Resources The United States has significant natural gas and oil reserves. But many of these resources are increasingly harder to...

325

Oil and Gas Supply Module  

Gasoline and Diesel Fuel Update (EIA)

1 1 U.S. Energy Information Administration | Assumptions to the Annual Energy Outlook 2012 Oil and Gas Supply Module The NEMS Oil and Gas Supply Module (OGSM) constitutes a comprehensive framework with which to analyze crude oil and natural gas exploration and development on a regional basis (Figure 8). The OGSM is organized into 4 submodules: Onshore Lower 48 Oil and Gas Supply Submodule, Offshore Oil and Gas Supply Submodule, Oil Shale Supply Submodule[1], and Alaska Oil and Gas Supply Submodule. A detailed description of the OGSM is provided in the EIA publication, Model Documentation Report: The Oil and Gas Supply Module (OGSM), DOE/EIA-M063(2011), (Washington, DC, 2011). The OGSM provides crude oil and natural gas short-term supply parameters to both the Natural Gas Transmission and Distribution Module and the Petroleum

326

Economic effects of peak oil  

Science Journals Connector (OSTI)

Assuming that global oil production peaked, this paper uses scenario analysis to show the economic effects of a possible supply shortage and corresponding rise in oil prices in the next decade on different sectors in Germany and other major economies such as the US, Japan, China, the OPEC or Russia. Due to the price-inelasticity of oil demand the supply shortage leads to a sharp increase in oil prices in the second scenario, with high effects on GDP comparable to the magnitude of the global financial crises in 2008/09. Oil exporting countries benefit from high oil prices, whereas oil importing countries are negatively affected. Generally, the effects in the third scenario are significantly smaller than in the second, showing that energy efficiency measures and the switch to renewable energy sources decreases the countries' dependence on oil imports and hence reduces their vulnerability to oil price shocks on the world market.

Christian Lutz; Ulrike Lehr; Kirsten S. Wiebe

2012-01-01T23:59:59.000Z

327

Abandoned oil fields in Oklahoma  

SciTech Connect (OSTI)

Data are presented for approximately 165 abandoned oil fields in Oklahoma that have produced 10,000 or more barrels of oil prior to abandonment. The following information is provided for each field: county; DOE field code; field name; AAPG geologic province code; discovery date of field; year of last production, if known; discovery well operator; proven acreage; formation thickness; depth of field; gravity of oil production; calendar year; yearly field oil production; yearly field gas production; cumulative oil production; cumulative gas production; number abandoned fields in county; cumulative production of oil from fields; and cumulative production of gas from fields. (ATT)

Chism, J.

1983-08-01T23:59:59.000Z

328

Used oil re-refining  

SciTech Connect (OSTI)

Used oils, especially used lubricating oils which are normally considered waste and are discarded or burned, are reclaimed for reuse by a re-refining procedure involving the steps of: heat soaking the used oil; distilling the heat soaked oil; passing the distillate through a guard bed of activated material; hydrotreating the guard bed treated distillate under standard hydrotreating conditions. If the used oil to be re-refined contains a quantity of water and/or fuel fraction which the practioner considers sufficiently large to be detrimental, the used oil may be subjected to a dewatering/defueling step prior to being heat soaked.

Reid, L. E.; Ryan, D. G.; Yao, K. C.

1985-04-23T23:59:59.000Z

329

MECS Fuel Oil Tables  

U.S. Energy Information Administration (EIA) Indexed Site

: Actual, Minimum and Maximum Use Values for Fuel Oils and Natural Gas : Actual, Minimum and Maximum Use Values for Fuel Oils and Natural Gas Year Distillate Fuel Oil (TBtu) Actual Minimum Maximum Discretionary Rate 1985 185 148 1224 3.4% 1994 152 125 1020 3.1% Residual Fuel Oil (TBtu) Actual Minimum Maximum Discretionary Rate 1985 505 290 1577 16.7% 1994 441 241 1249 19.8% Natural Gas (TBtu) Actual Minimum Maximum Discretionary Rate 1985 4656 2702 5233 77.2% 1994 6141 4435 6758 73.4% Source: Energy Information Administration, Office of Energy Markets and End Use, 1985 and 1994 Manufacturing Energy Consumption Surveys. Table 2: Establishments That Actually Switched Between Natural Gas and Residual Fuel Oil Type of Switch Number of Establishments in Population Number That Use Original Fuel Percentage That Use Original Fuel Number That Can Switch to Another Fuel Percentage That Can Switch to Another Fuel Number That Actually Made a Switch Percentage That Actually Made a Switch

330

Enhanced Oil Recovery and Other Oil Resources projects  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Enhanced Oil Recovery and Other Oil Resources Enhanced Oil Recovery and Other Oil Resources Enhanced Oil Recovery and Other Oil Resources CO2 EOR | Other EOR & Oil Resources | Environmental | Completed Oil Projects Project Number Project Name Primary Performer DE-FE0013723 Development of Nanoparticle-Stabilized Foams To Improve Performance of Water-less Hydraulic Fracturing The University of Texas at Austin DE-FE0010799 Small Molecular Associative Carbon Dioxide (CO2) Thickeners for Improved Mobility Control University of Pittsburgh DE-FE0006011 Development of Real Time Semi-autonomous Geophysical Data Acquisition and Processing System to Monitor Flood Performance White River Technologies DE-FE0005979 Nanoparticle-stabilized CO2 Foam for CO2 EOR Application New Mexico Institute of Mining and Technology

331

Oil Prices, Opec and the Poor Oil Consuming Countries  

Science Journals Connector (OSTI)

In 1950, the year O.P.E.C. (Organisation of Petroleum Exporting Countries) was formed, the world oil industry was dominated by a group of seven oligopolistic major international oil companies, who were collective...

Biplab Dasgupta

1976-01-01T23:59:59.000Z

332

Production of dimethylfuran for liquid fuels from biomass-derived carbohydrates  

Science Journals Connector (OSTI)

... be accomplished in two steps: first, removing three oxygen atoms by dehydration to produce 5-hydroxymethylfurfural (HMF); and second, removing two oxygen atoms by hydrogenolysis to produce DMF by ...

Yuriy Román-Leshkov; Christopher J. Barrett; Zhen Y. Liu; James A. Dumesic

2007-06-21T23:59:59.000Z

333

Catalytic Transformations of Biomass-Derived Materials into Value-Added Chemicals  

Science Journals Connector (OSTI)

This manuscript reviews recent literatures on synthesis of furfurals (5-hydroxymethylfurfural, furfural, 5-methyl-2-furaldehyde) from...d-galactose, d-arabinose, xylose, l-rhamnose, lactose, cellobiose, sucrose) ...

Atsushi Takagaki; Shun Nishimura; Kohki Ebitani

2012-09-01T23:59:59.000Z

334

Biomass-derived volatile fatty acid platform for fuels and chemicals  

Science Journals Connector (OSTI)

The typical biorefinery platforms are sugar, thermochemical (syngas), carbon-rich chains, and biogas platforms, each offering unique advantages and disadvantages. The sugar platform uses hexose and pentose sugars...

Ho Nam Chang; Nag-Jong Kim; Jongwon Kang…

2010-02-01T23:59:59.000Z

335

Simulating Adsorptive Expansion of Zeolites: Application to Biomass-Derived Solutions in Contact with Silicalite  

Science Journals Connector (OSTI)

(2) Research on generating these new second-generation biofuels requires the study of catalytic and separation processes for transforming plant material composed mainly of cellulose, hemicelluloses, and lignin into more useful platform chemicals. ... For the furfural and HMF solutes, the ideal solution equation of state gives the following relationship between the solute chemical potential in solution and its concentration:where ?i is the chemical potential of the ith species in solution, Ci is the concentration, Co is a reference concentration, R is the gas constant, T is absolute temperature, and ?solv?i(C0) is the molar Gibbs free energy of solvation from gas to solution phase at the reference concentration and temperature T. ... Physical Chemistry Chemical Physics (2008), 10 (32), 4817-4826 CODEN: PPCPFQ; ISSN:1463-9076. ...

Julian E. Santander; Michael Tsapatsis; Scott M. Auerbach

2013-03-15T23:59:59.000Z

336

An efficient didehydroxylation method for the biomass-derived polyols glycerol and erythritol.  

E-Print Network [OSTI]

materials, the conversion of biomass commonly requires thee?cient approach to the conversion of biomass to value-addedbiomass-derived polyols (glycerol and erythritol) that results in the conversion

2009-01-01T23:59:59.000Z

337

Dynamic molecular structure of plant biomass-derived black carbon (biochar)  

E-Print Network [OSTI]

Mechanism study of wood lignin pyrolysis  by using TG?FTIR hemicellulose,  cellulose and lignin pyrolysis.  Fuel 2007, bark,  cellulose,  and  lignin:  Implications for the 

Keiluweit, M.

2010-01-01T23:59:59.000Z

338

Exploring Hydrogen Generation from Biomass-Derived Sugar and Sugar Alcohols to Reduce Costs  

Office of Energy Efficiency and Renewable Energy (EERE)

New aqueous phase reforming process uses liquid feedstocks to produce energy from hydrogen with reduced costs.

339

Low-Emissions Burner Technology using Biomass-Derived Liquid Fuels  

Broader source: Energy.gov [DOE]

Factsheet summarizing Univ. of Alabama project to save energy and reduce emissions with fuel-flexible burners

340

One-step catalytic conversion of biomass-derived carbohydrates to liquid fuels  

DOE Patents [OSTI]

The invention relates to a method for manufacture of hydrocarbon fuels and oxygenated hydrocarbon fuels such as alkyl substituted tetrahydrofurans such as 2,5-dimethyltetrahydrofuran, 2-methyltetrahydrofuran, 5-methylfurfural and mixtures thereof. The method generally entails forming a mixture of reactants that includes carbonaceous material, water, a metal catalyst and an acid reacting that mixture in the presence of hydrogen. The reaction is performed at a temperature and for a time sufficient to produce a furan type hydrocarbon fuel. The process may be adapted to provide continuous manufacture of hydrocarbon fuels such as a furan type fuel.

Sen, Ayusman; Yang, Weiran

2014-03-18T23:59:59.000Z

Note: This page contains sample records for the topic "oils biomass-derived fischer-tropsch" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

E-Print Network 3.0 - above-ground biomass derived Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

biomass estimates from lidar. Forest above- ground biomass... that the height of medium energy returns (RH50) is better related to above- ground biomass than the height at...

342

Hydrogen Generation from Biomass-Derived Carbohydrates via Aqueous-Phase Reforming  

Broader source: Energy.gov [DOE]

Presentation by Virent Energy Systems, Inc. at the October 24, 2006 Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group Kick-Off Meeting.

343

Development of a co-firing fuel from biomass-derived binder and crushed coal.  

E-Print Network [OSTI]

??The focus of this work was the development of a co-firing boiler fuel for use in the coal power plant industry. This fuel, known as… (more)

Friend, Andrew

2013-01-01T23:59:59.000Z

344

Comparison of Biomass-Derived Turbine Fuels with the Composition-Explicit Distillation Curve Method  

Science Journals Connector (OSTI)

Thermophysical Properties Division, National Institute of Standards and Technology Boulder, Colorado 80305, United States ... In recent years, civilian and military users of aviation kerosene (for gas turbine engines) have been interested in expanding the scope of fuel feed stocks to include nonpetroleum sources. ... JP-7 was developed in the 1950s to meet the more stringent requirements necessary for the development of high-altitude reconnaissance aircraft that fly at speeds exceeding Mach 3. The extreme temps. ...

Thomas J. Bruno; Evgenii Baibourine

2011-03-06T23:59:59.000Z

345

Compare All CBECS Activities: Fuel Oil Use  

Gasoline and Diesel Fuel Update (EIA)

of fuel oil in 1999. Only six building types had any statistically significant fuel oil usage, with education buildings using the most total fuel oil. Figure showing total fuel oil...

346

Used Oil and Filter Disposal Used Oil: Create a segregated storage area or container. Label the container "Waste Oil Only".  

E-Print Network [OSTI]

Used Oil and Filter Disposal Used Oil: Create a segregated storage area or container. Label the container "Waste Oil Only". Maintain a written log to document all amounts and types of oil added to the container. No solvents, oil contaminated with solvents, PCBs, non-petroleum based oils, or any other

Maroncelli, Mark

347

Spot-Oiling Johnsongrass.  

E-Print Network [OSTI]

I TEXAS AGRICULTURAL EXTENSIO-N SERVICE G. G. Gibson, Director, College Station, Texas [Blank Page in Original Bulletin] I the bast I ir used the low I . .. 1 the fol or mort , needed SPOT-OILING JOHNSONGRASS H. E. Rea, M. J. Norris..., and Fred C. Elliott* Texas A. & M. College System ~HNSONGRASS CAN BE killed to the i ground by the application of 1 / 3 teaspoonful of a herbicidal oil to the crown of each stem. Eradication of established Johnsongrass can be obtained in a single...

Elliott, Fred C.; Norris, M. J.; Rea, H. E.

1955-01-01T23:59:59.000Z

348

STEO September 2012 - oil production  

U.S. Energy Information Administration (EIA) Indexed Site

oil production forecast to rise almost 700,000 bpd this oil production forecast to rise almost 700,000 bpd this year, help cut U.S. petroleum imports U.S. crude oil production is expected to average 6.3 million barrels per day in 2012. That's up nearly 700,000 barrels per day from last year and the highest annual oil output since 1997 says the U.S. Energy Information Administration in its new monthly short-term energy outlook for September. EIA analyst Sam Gorgen explains: "Higher oil supplies, especially from North Dakota and Texas, boosted U.S. oil production. The number of on-shore drilling rigs targeting oil nationwide has increased by around 200 so far this year to just under 1,400 rigs." Higher domestic oil production will help cut U.S. petroleum imports. The share of total U.S.

349

Regional Residential Heating Oil Prices  

Gasoline and Diesel Fuel Update (EIA)

One of the first places where consumers are feeling the impact of One of the first places where consumers are feeling the impact of this winter's market pressures is in home heating oil prices. This chart shows prices through February 28, the most recent EIA data available. The general level of heating oil prices each year is largely a function of crude oil prices, and the price range over the course of the heating season is typically about 10 cents per gallon. Exceptions occur in unusual circumstances, such as very cold weather, large changes in crude oil prices, or supply problems. Heating oil prices for East Coast consumers started this winter at just over $1 per gallon, but rising crude oil prices drove them up nearly 21 cents through mid-January. With the continuing upward pressure from crude oil markets, magnified by a regional shortfall of heating oil

350

Oil and Gas Conservation (Montana)  

Broader source: Energy.gov [DOE]

Parts 1 and 2 of this chapter contain a broad range of regulations pertaining to oil and gas conservation, including requirements for the regulation of oil and gas exploration and extraction by the...

351

Residential heating oil prices decrease  

U.S. Energy Information Administration (EIA) Indexed Site

heating oil prices decrease The average retail price for home heating oil fell 1.7 cents from a week ago to 4.02 per gallon. That's up 1.7 cents from a year ago, based on the...

352

Residential heating oil price decreases  

Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

heating oil price decreases The average retail price for home heating oil fell 7.8 cents from a week ago to 3.14 per gallon. That's down 81.1 cents from a year ago, based on the...

353

Residential heating oil price decreases  

Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

heating oil price decreases The average retail price for home heating oil fell 10.5 cents from a week ago to 3.22 per gallon. That's down 73.6 cents from a year ago, based on the...

354

Residential heating oil price decreases  

Gasoline and Diesel Fuel Update (EIA)

heating oil price decreases The average retail price for home heating oil fell 1.8 cents from a week ago to 2.82 per gallon. That's down 1.36 from a year ago, based on the...

355

Residential heating oil prices decline  

Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

heating oil price decreases The average retail price for home heating oil fell 2 cents from a week ago to 3.36 per gallon. That's down 52.5 cents from a year ago, based on the...

356

Residential heating oil prices increase  

U.S. Energy Information Administration (EIA) Indexed Site

heating oil prices increase The average retail price for home heating oil rose 3.9 cents last week to 3.96 per gallon. That's down 2.6 cents from a year ago, based on the...

357

Residential heating oil price decreases  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

05, 2014 Residential heating oil price decreases The average retail price for home heating oil fell 1.9 cents from a week ago to 3.43 per gallon. That's down 39 cents from a year...

358

Residential heating oil price decreases  

U.S. Energy Information Administration (EIA) Indexed Site

4 Residential heating oil price decreases The average retail price for home heating oil fell 1.6 cents from a week ago to 3.42 per gallon. That's down 39.5 cents from a year ago,...

359

Residential heating oil prices decrease  

Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

heating oil price decreases The average retail price for home heating oil fell 2.9 cents from a week ago to 3.45 per gallon. That's down 36.6 cents from a year ago, based on the...

360

Residential heating oil prices decline  

U.S. Energy Information Administration (EIA) Indexed Site

heating oil price decreases The average retail price for home heating oil fell 3.3 cents from a week ago to 3.38 per gallon. That's down 43.9 cents from a year ago, based on the...

Note: This page contains sample records for the topic "oils biomass-derived fischer-tropsch" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Residential heating oil prices increase  

U.S. Energy Information Administration (EIA) Indexed Site

5, 2014 Residential heating oil prices increase The average retail price for home heating oil rose 6.5 cents from a week ago to 4.24 per gallon. That's up 14.9 cents from a year...

362

Residential heating oil price decreases  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

6, 2014 Residential heating oil price decreases The average retail price for home heating oil rose 1.6 cents from a week ago to 4.24 per gallon. That's up 8.9 cents from a year...

363

Residential heating oil prices decline  

Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

heating oil price decreases The average retail price for home heating oil fell 6.3 cents from a week ago to 3.08 per gallon. That's down 90.3 cents from a year ago, based on the...

364

Residential heating oil price decreases  

U.S. Energy Information Administration (EIA) Indexed Site

heating oil price decreases The average retail price for home heating oil fell 3.8 cents from a week ago to 3.33 per gallon. That's down 59.1 cents from a year ago, based on the...

365

Residential heating oil prices increase  

U.S. Energy Information Administration (EIA) Indexed Site

heating oil prices increase The average retail price for home heating oil rose 5.4 cents from a week ago to 4.04 per gallon. That's up 4.9 cents from a year ago, based on the...

366

Residential heating oil prices increase  

U.S. Energy Information Administration (EIA) Indexed Site

heating oil prices increase The average retail price for home heating oil rose 2.9 cents from a week ago to 3.98 per gallon. That's up 6-tenths of a penny from a year ago, based...

367

Residential heating oil prices increase  

U.S. Energy Information Administration (EIA) Indexed Site

3, 2014 Residential heating oil prices increase The average retail price for home heating oil rose 4.4 cents from a week ago to 4.06 per gallon. That's up 4.1 cents from a year...

368

Residential heating oil prices decline  

U.S. Energy Information Administration (EIA) Indexed Site

heating oil prices decline The average retail price for home heating oil is 3.48 per gallon. That's down 4.5 cents from a week ago, based on the residential heating fuel survey by...

369

Residential heating oil prices decrease  

U.S. Energy Information Administration (EIA) Indexed Site

5, 2014 Residential heating oil prices decrease The average retail price for home heating oil fell 1.8 cents from a week ago to 4.00 per gallon. That's down 2-tenths of a cent...

370

Residential heating oil prices increase  

U.S. Energy Information Administration (EIA) Indexed Site

heating oil prices increase The average retail price for home heating oil rose 12 cents from a week ago to 4.18 per gallon. That's up 13 cents from a year ago, based on the...

371

Cooling power of quenching oils  

Science Journals Connector (OSTI)

Industrial oils 20 and 20V have the best cooling powers of all quenching oils (used in the USSR). They secure high cooling rates at low temperatures, have a satisfactory...

L. V. Petrash

1959-07-01T23:59:59.000Z

372

Virent is Replacing Crude Oil  

Broader source: Energy.gov [DOE]

Breakout Session 2A—Conversion Technologies II: Bio-Oils, Sugar Intermediates, Precursors, Distributed Models, and Refinery Co-Processing Virent is Replacing Crude Oil Randy Cortright, Founder & Chief Technology Officer, Virent

373

THERMAL PROCESSING OF OIL SHALE/SANDS  

E-Print Network [OSTI]

)-based simulation tools to a modified in-situ process for production of oil from oil shale. The simulation tools

Michal Hradisky; Philip J. Smith; Doe Award; No. De-fe

2009-01-01T23:59:59.000Z

374

invert(ed) (oil) emulsion (drilling) mud  

Science Journals Connector (OSTI)

invert(ed) (oil) emulsion (drilling) mud, water-in-oil (drilling) mud ? Wasser-in-Öl-(Bohr)...m, (f)

2014-08-01T23:59:59.000Z

375

water-in-oil (drilling) mud  

Science Journals Connector (OSTI)

water-in-oil (drilling) mud, invert(ed) (oil) emulsion (drilling) mud ? Wasser-in-Öl-(Bohr)...m, (f)

2014-08-01T23:59:59.000Z

376

Process for the production of refrigerator oil  

SciTech Connect (OSTI)

A process for producing a high quality refrigerator oil from an oil fraction boiling at a temperature within boiling point of lubricating oil by contacting said oil fraction with a solvent to extract undesirable components thereby lowering % C..cap alpha.. of said oil fraction, hydrogenating said solvent extracted fraction under the specific conditions, and then contacting said hydrogenated oil with a solid absorbant to remove impurities; said oil fraction being obtained from a low grade naphthenic crude oil.

Kunihiro, T.; Tsuchiya, K.

1985-06-04T23:59:59.000Z

377

Fuel-blending stocks from the hydrotreatment of a distillate formed by direct coal liquefaction  

SciTech Connect (OSTI)

The direct liquefaction of coal in the iron-catalyzed Suplex process was evaluated as a technology complementary to Fischer-Tropsch synthesis. A distinguishing feature of the Suplex process, from other direct liquefaction processes, is the use of a combination of light- and heavy-oil fractions as the slurrying solvent. This results in a product slate with a small residue fraction, a distillate/naphtha mass ratio of 6, and a 65.8 mass % yield of liquid fuel product on a dry, ash-free coal basis. The densities of the resulting naphtha (C{sub 5}-200{sup o}C) and distillate (200-400{sup o}C) fractions from the hydroprocessing of the straight-run Suplex distillate fraction were high (0.86 and 1.04 kg/L, respectively). The aromaticity of the distillate fraction was found to be typical of coal liquefaction liquids, at 60-65%, with a Ramsbottom carbon residue content of 0.38 mass %. Hydrotreatment of the distillate fraction under severe conditions (200{sup o}C, 20.3 MPa, and 0.41 g{sub feed} h{sup -1} g{sub catalyst}{sup -1}) with a NiMo/Al{sub 2}O{sub 3} catalyst gave a product with a phenol content of {lt}1 ppm, a nitrogen content {lt}200 ppm, and a sulfur content {lt}25 ppm. The temperature was found to be the main factor affecting diesel fraction selectivity when operating at conditions of WHSV = 0.41 g{sub feed} h{sup -1} g{sub catalyst}{sup -1} and PH{sub 2} = 20.3 MPa, with excessively high temperatures (T {gt} 420{sup o}C) leading to a decrease in diesel selectivity. The fuels produced by the hydroprocessing of the straight-run Suplex distillate fraction have properties that make them desirable as blending components, with the diesel fraction having a cetane number of 48 and a density of 0.90 kg/L. The gasoline fraction was found to have a research octane number (RON) of 66 and (N + 2A) value of 100, making it ideal as a feedstock for catalytic reforming and further blending with Fischer-Tropsch liquids. 44 refs., 9 figs., 12 tabs.

Andile B. Mzinyati [Sasol Technology Research and Development, Sasolburg (South Africa). Fischer-Tropsch Refinery Catalysis

2007-09-15T23:59:59.000Z

378

Nineteenth oil shale symposium proceedings  

SciTech Connect (OSTI)

This book contains 23 selections. Some of the titles are: Effects of maturation on hydrocarbon recoveries from Canadian oil shale deposits; Dust and pressure generated during commercial oil shale mine blasting: Part II; The petrosix project in Brazil - An update; Pathway of some trace elements during fluidized-bed combustion of Israeli Oil Shale; and Decommissioning of the U.S. Department of Energy Anvil Points Oil Shale Research Facility.

Gary, J.H.

1986-01-01T23:59:59.000Z

379

Heating Oil and Propane Update  

Gasoline and Diesel Fuel Update (EIA)

Maps of states participating in Winter Fuels Survey Residential propane PADD map Residential heating oil PADD map...

380

Oil shale: Technology status report  

SciTech Connect (OSTI)

This report documents the status of the US Department of Energy's (DOE) Oil Shale Program as of the end of FY 86. The report consists of (1) a status of oil shale development, (2) a description of the DOE Oil Shale Program, (3) an FY 86 oil shale research summary, and (4) a summary of FY 86 accomplishments. Discoveries were made in FY 86 about the physical and chemical properties and behavior of oil shales, process chemistry and kinetics, in situ retorting, advanced processes, and the environmental behavior and fate of wastes. The DOE Oil Shale Program shows an increasing emphasis on eastern US oil shales and in the development of advanced oil shale processing concepts. With the award to Foster Wheeler for the design of oil shale conceptual plants, the first step in the development of a systems analysis capability for the complete oil shale process has been taken. Unocal's Parachute Creek project, the only commercial oil shale plant operating in the United States, is operating at about 4000 bbl/day. The shale oil is upgraded at Parachute Creek for input to a conventional refinery. 67 refs., 21 figs., 3 tabs.

Not Available

1986-10-01T23:59:59.000Z

Note: This page contains sample records for the topic "oils biomass-derived fischer-tropsch" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

OIL ANALYSIS LAB TRIVECTOR ANALYSIS  

E-Print Network [OSTI]

OIL ANALYSIS LAB TRIVECTOR ANALYSIS This test method is a good routine test for the overall condition of the oil, the cleanliness, and can indicate the presence of wear metals that could be coming of magnetic metal particles within the oil. This may represent metals being worn from components (i

382

Baltic oil: Moving offshore  

Science Journals Connector (OSTI)

... the consortium of Soviet, Polish and East German oil interests, will sink its first offshore bore-hole in the Baltic. This move follows four years of intensive prospecting, which ... findings. For a time, plans were afort to buy or hire a Vexco drilling rig, but when these had to be abondoned for lack of hard currency, the shut ...

Vera Rich

1980-06-19T23:59:59.000Z

383

Oil from Coal  

Science Journals Connector (OSTI)

... sources are not capable of indefinite expansion, since their industrial stability is dependent upon adequate markets for the main products—coke of various kinds or gas. They were, however, ... gallon and remain in operation until 1950, and that it should be extended to include diesel oil used in motor vehicles. It might be feared that this extension would involve ...

C. H. LANDER

1938-04-09T23:59:59.000Z

384

Naphthenic lube oils  

SciTech Connect (OSTI)

A process is disclosed for increasing the volume of lubricating oil base stocks recovered from a crude oil. A fraction having an atmospheric boiling range of about 675/sup 0/ to 1100/sup 0/ F. is recovered by vacuum distillation. This fraction is treated with furfural to extract a hydrocarbon mixture containing at least 50 volume % aromatic hydrocarbons. The raffinate is a lubricating oil base stock very high in paraffinic hydrocarbons and low in naphthenic hydrocarbons. The fraction extracted by the furfural contains at least about 50 volume % aromatic hydrocarbons and less than about 10 volume % paraffinic hydrocarbons. The mixture is hydrotreated to hydrogenate a substantial portion of the aromatic hydrocarbons. The hydrotreated product then is catalytically dewaxed. After removal of low boiling components, the finished lubricating oil base stock has a viscosity of at least about 200 SUS at 100/sup 0/ F., a pour point of less than 20/sup 0/ F. and contains at least 50 volume % of naphthenic hydrocarbons, a maximum of about 40 volume % aromatic hydrocarbons, and a maximum of about 10 volume % paraffinic hydrocarbons.

Hettinger Jr., W. P.; Beck, H. W.; Rozman, G. J.; Turrill, F. H.

1985-05-07T23:59:59.000Z

385

China and Peak Oil  

Science Journals Connector (OSTI)

In the mid-1950s there was a severe oil shortage in China. Fighter jets and tanks stood still and the buses on Beijing’s streets were fueled from large bags of gas on their roofs. Several drilling teams travel...

Kjell Aleklett

2012-01-01T23:59:59.000Z

386

North Slope: Oil Rush  

Science Journals Connector (OSTI)

...place of about 46,000, situated on the Chena slough of the Tanana River. It has become...permafrost. The Trans Alaska PipelineW carrying hot oil, may face worse problems. [L. A...Despite all the unanswered questions about hot pipelines and permafrost, the restoring...

Luther J. Carter

1969-10-03T23:59:59.000Z

387

Peak oil supply or oil not for sale?  

Science Journals Connector (OSTI)

Abstract The restrictions imposed by climate change are inevitable and will be exerted either via precautionary mitigation of (mainly energy-related) CO2 emissions or via irreversible impacts on ecosystems and on human habitats. Either way, oil markets are bound to incur drastic shrinking. Concern over peak oil supply will crumble when the irrevocable peak oil demand is created. Replacing oil in the world's energy economies requires redirected market forces, notably in the form of steadily increasing oil end-use prices. Yet, thus far, crude oil prices have obeyed the market fundamentals of expanding-contracting demand and oligopolistic supply. A hockey stick supply curve supports high sales prices, providing large rents to submarginal sources. Cutting oil demand and maintaining high prices implies reducing the supply hockey stick's length by curtailing some oil producers. In such a scenario, the alliances, goals, and tactics of oil geopolitics are set to change. We identify a distribution over friendly and hostile oil suppliers, with others drifting in between the two sides. Conflicts and warfare are less aimed at conquering oil fields for exploitation than at paralyzing production capabilities of opponents or of unreliable transient sources. Covert warfare and instigation of internal conflicts are likely tactics to exhaust hostile opponents.

Aviel Verbruggen; Thijs Van de Graaf

2013-01-01T23:59:59.000Z

388

Structural Oil Pan With Integrated Oil Filtration And Cooling System  

DOE Patents [OSTI]

An oil pan for an internal combustion engine includes a body defining a reservoir for collecting engine coolant. The reservoir has a bottom and side walls extending upwardly from the bottom to present a flanged lip through which the oil pan may be mounted to the engine. An oil cooler assembly is housed within the body of the oil pan for cooling lubricant received from the engine. The body includes an oil inlet passage formed integrally therewith for receiving lubricant from the engine and delivering lubricant to the oil cooler. In addition, the body also includes an oil pick up passage formed integrally therewith for providing fluid communication between the reservoir and the engine through the flanged lip.

Freese, V, Charles Edwin (Westland, MI)

2000-05-09T23:59:59.000Z

389

oil supply | OpenEI  

Open Energy Info (EERE)

oil supply oil supply Dataset Summary Description CIA: World Factbook assessment of proved reserves of crude oil in barrels (bbl). Proved reserves are those quantities of petroleum which, by analysis of geological and engineering data, can be estimated with a high degree of confidence to be commercially recoverable from a given date forward, from known reservoirs and under current economic conditions. Estimated as of January 1st, 2010. Source CIA Date Released January 01st, 2010 (4 years ago) Date Updated Unknown Keywords crude oil energy energy data international oil oil supply Data text/csv icon 2010 Proved Oil Reserves (csv, 4.6 KiB) text/plain icon Original Text Format (txt, 6.5 KiB) Quality Metrics Level of Review Some Review Comment Temporal and Spatial Coverage Frequency

390

Measuring Dependence on Imported Oil  

Gasoline and Diesel Fuel Update (EIA)

Dependence on Imported Oil Dependence on Imported Oil by C. William Skinner* U.S. dependence on imported oil** can be measured in at least two ways. The differences hinge largely on whether oil imports are defined as net imports (total imports minus exports) or as total imports. EIA believes that the net-imports definition gives a clearer indication of the fraction of oil consumed that could not have been supplied from domestic sources and is thus the most appropriate measure. With this issue of the Monthly Energy Review, the Energy Information Administration (EIA) introduces a revised table that expresses depend- ence on imports in terms of both measures. How dependent is the United States on foreign oil? How dependent are we on oil from the Persian Gulf or other sensitive areas? Do we import more than we produce domes-

391

Regional Residential Heating Oil Prices  

Gasoline and Diesel Fuel Update (EIA)

Slide 2 of 11 Notes: One of the first places where consumers are feeling the impact of this winterÂ’s market pressures is in home heating oil prices. This chart shows prices through February 7, the most recent EIA data available. The general level of heating oil prices each year is largely a function of crude oil prices, and the price range over the course of the heating season is typically about 10 cents per gallon. Exceptions occur in unusual circumstances, such as very cold weather, large changes in crude oil prices, or supply problems. Heating oil prices for East Coast consumers started this winter at just over $1 per gallon, but rising crude oil prices drove them up nearly 21 cents per gallon through mid-January. With the continuing upward pressure from crude oil markets, magnified by a regional shortfall of

392

Oil consumption, pollutant emission, oil proce volatility and economic activities in selected Asian Developing Economies.  

E-Print Network [OSTI]

??It is now well established in the literature that oil consumption, oil price shocks, and oil price volatility may impact the economic activities negatively. Studies… (more)

Rafiq, Shuddhasattwa

2009-01-01T23:59:59.000Z

393

MECS Fuel Oil Figures  

U.S. Energy Information Administration (EIA) Indexed Site

: Percentage of Total Purchased Fuels by Type of Fuel : Percentage of Total Purchased Fuels by Type of Fuel Figure 1. Percent of Total Purchased Fuel Sources: Energy Information Administration. Office of Energy Markets and End Use, Manufacturing Energy Consumption Survey (MECS): Consumption of Energy; U.S. Department of Commerce, Bureau of the Census, Annual Survey of Manufactures (ASM): Statistics for Industry Groups and Industries: Statistical Abstract of the United States. Note: The years below the line on the "X" Axis are interpolated data--not directly from the Manufacturing Energy Consumption Survey or the Annual Survey of Manufactures. Figure 2: Changes in the Ratios of Distillate Fuel Oil to Natural Gas Figure 2. Changes in the Ratios of Distillate Fuel Oil to Natural Gas Sources: Energy Information Administration. Office of

394

fuel_oil.pdf  

U.S. Energy Information Administration (EIA) Indexed Site

Fuel Oil Usage Form Fuel Oil Usage Form 1999 Commercial Buildings Energy Consumption Survey (CBECS) 1. Timely submission of this report is mandatory under Public Law 93-275, as amended. 2. This completed report is due by 3. Data reported on this questionnaire are for the entire building identified in the label to the right. 4. Data may be submitted directly on this questionnaire or in any other format, such as a computer-generated listing, which provides the same i nformation and is conve nient for y our company. a. You may submit a single report for the entire building, or if it i s easier, a separate report for each of several accounts in the building. These will then be aggregated by the survey contractor. b. If you are concerned about your individual account information, you may c

395

Shale oil recovery process  

DOE Patents [OSTI]

A process of producing within a subterranean oil shale deposit a retort chamber containing permeable fragmented material wherein a series of explosive charges are emplaced in the deposit in a particular configuration comprising an initiating round which functions to produce an upward flexure of the overburden and to initiate fragmentation of the oil shale within the area of the retort chamber to be formed, the initiating round being followed in a predetermined time sequence by retreating lines of emplaced charges developing further fragmentation within the retort zone and continued lateral upward flexure of the overburden. The initiating round is characterized by a plurality of 5-spot patterns and the retreating lines of charges are positioned and fired along zigzag lines generally forming retreating rows of W's. Particular time delays in the firing of successive charges are disclosed.

Zerga, Daniel P. (Concord, CA)

1980-01-01T23:59:59.000Z

396

Oil shale retort apparatus  

DOE Patents [OSTI]

A retorting apparatus including a vertical kiln and a plurality of tubes for delivering rock to the top of the kiln and removal of processed rock from the bottom of the kiln so that the rock descends through the kiln as a moving bed. Distributors are provided for delivering gas to the kiln to effect heating of the rock and to disturb the rock particles during their descent. The distributors are constructed and disposed to deliver gas uniformly to the kiln and to withstand and overcome adverse conditions resulting from heat and from the descending rock. The rock delivery tubes are geometrically sized, spaced and positioned so as to deliver the shale uniformly into the kiln and form symmetrically disposed generally vertical paths, or "rock chimneys", through the descending shale which offer least resistance to upward flow of gas. When retorting oil shale, a delineated collection chamber near the top of the kiln collects gas and entrained oil mist rising through the kiln.

Reeves, Adam A. (Grand Junction, CO); Mast, Earl L. (Norman, OK); Greaves, Melvin J. (Littleton, CO)

1990-01-01T23:59:59.000Z

397

Heating oils, 1982  

SciTech Connect (OSTI)

Properties of 235 heating oils marketed in the United States were submitted for study and compilation under agreement between BETC and API. The fuels were manufactured by 25 petroleum refining companies in 88 domestic refineries. The data are tabulated according to six grades of fuel and subdivided into five geographic regions in which the fuels are marketed. The five regions containing a total of 16 marketing districts are shown on a map in the report. Trend charts are included showing average properties of the six grades of fuel for the past several years. Summaries of the results of the tests by grade and by region for 1982 compared with data for 1981 are tabulated. Analyses of grade 6 foreign import oils are presented.

Shelton, E.M.

1982-08-01T23:59:59.000Z

398

Heating oils, 1980  

SciTech Connect (OSTI)

Properties of 247 heating oils marketed in the United States were submitted for study and compilation under agreement between the Bartlesville Energy Technology Center and the American Petroleum Institute. The fuels were manufactured by 26 petroleum refining companies in 87 domestic refineries. The data are tabulated according to six grades of fuel and subdivided into five geographic regions in which the fuels are marketed. The six grades of fuel are defined by the American Society for Testing and Materials Specification D396. The five regions containing a total of 16 marketing districts are shown on a map in the report. Trend charts are included showing average properties of the six grades of fuel for the past several years. Summaries of the results of the tests by grade and by region for 1980 compared with data for 1979 are shown in tables. Analyses of grades 2, 5(light), and 6 foreign import oils are presented.

Shelton, E.M.

1980-10-01T23:59:59.000Z

399

Heating oils, 1981  

SciTech Connect (OSTI)

Properties of 249 heating oils marketed in the United States were submitted for study and compilation under agreement between the Bartlesville Energy Technology Center (BETC) and the American Petroleum Institute (API). The fuels were manufactured by 28 petroleum refining companies in 92 domestic refineries. The data are tabulated according to six grades of fuel and subdivided into five geographic regions in which the fuels are marketed. The six grades of fuels are defined by the American Society for Testing and Materials (ASTM) Specification D396. The five regions containing a total of 16 marketing districts are shown on a map in the report. Trend charts are included showing average properties of the six grades of fuel for the past several years. Summaries of the results of the tests by grade and by region for 1981 compared with data for 1980 are shown in Tables 1 through 6. Analyses of grade 6 foreign import oils are presented in Table 13.

Shelton, E.M.

1981-08-01T23:59:59.000Z

400

Emulsified industrial oils recycling  

SciTech Connect (OSTI)

The industrial lubricant market has been analyzed with emphasis on current and/or developing recycling and re-refining technologies. This task has been performed for the United States and other industrialized countries, specifically France, West Germany, Italy and Japan. Attention has been focused at emulsion-type fluids regardless of the industrial application involved. It was found that emulsion-type fluids in the United States represent a much higher percentage of the total fluids used than in other industrialized countries. While recycling is an active matter explored by the industry, re-refining is rather a result of other issues than the mere fact that oil can be regenerated from a used industrial emulsion. To extend the longevity of an emulsion is a logical step to keep expenses down by using the emulsion as long as possible. There is, however, another important factor influencing this issue: regulations governing the disposal of such fluids. The ecological question, the respect for nature and the natural balances, is often seen now as everybody's task. Regulations forbid dumping used emulsions in the environment without prior treatment of the water phase and separation of the oil phase. This is a costly procedure, so recycling is attractive since it postpones the problem. It is questionable whether re-refining of these emulsions - as a business - could stand on its own if these emulsions did not have to be taken apart for disposal purposes. Once the emulsion is separated into a water and an oil phase, however, re-refining of the oil does become economical.

Gabris, T.

1982-04-01T23:59:59.000Z

Note: This page contains sample records for the topic "oils biomass-derived fischer-tropsch" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

STEO December 2012 - oil production  

U.S. Energy Information Administration (EIA) Indexed Site

Rise in 2012 U.S. oil production largest since 1859, output in 2013 seen Rise in 2012 U.S. oil production largest since 1859, output in 2013 seen topping 7 million bpd U.S. crude oil production is now expected to rise by about 760,000 barrels per day in 2012, the biggest annual increase in oil output since U.S. commercial crude oil production began in 1859. American oil producers are expected to pump a daily average of 6.4 million barrels of crude oil this year, according to the U.S. Energy Information Administrator's new monthly energy forecast. The annual increase in oil output tops the previous record set in 1951 and marks the largest yearly production increase ever. Most of the increase in crude oil production is driven by drilling activity in shale formations located in Texas, North Dakota and Montana. U.S. crude oil production next year is expected to top 7 million barrels per day for the first time

402

Using simple models to describe oil production from unconventional reservoirs.  

E-Print Network [OSTI]

??Shale oil (tight oil) is oil trapped in low permeability shale or sandstone. Shale oil is a resource with great potential as it is heavily… (more)

Song, Dong Hee

2014-01-01T23:59:59.000Z

403

Chapter 1 - Refining Heavy Oil and Extra-heavy Oil  

Science Journals Connector (OSTI)

The definitions of heavy oil, extra-heavy oil, and tar sand bitumen are inadequate insofar as the definitions rely upon a single physical property to define a complex feedstock. This chapter presents viable options to the antiquated definitions of the heavy feedstocks (heavy oil, extra-heavy oil, and tar sand bitumen) as well as an introduction to the various aspects of heavy feedstock refining in order for the reader to place each feedstock in the correct context of properties, behavior, and refining needs.

James G. Speight

2013-01-01T23:59:59.000Z

404

Unconventional oil market assessment: ex situ oil shale.  

E-Print Network [OSTI]

??This thesis focused on exploring the economic limitations for the development of western oil shale. The analysis was developed by scaling a known process and… (more)

Castro-Dominguez, Bernardo

2010-01-01T23:59:59.000Z

405

Crude Oil Prices Table 21. Domestic Crude Oil First Purchase...  

Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

Information Administration Petroleum Marketing Annual 1995 41 Table 21. Domestic Crude Oil First Purchase Prices (Dollars per Barrel) - Continued Year Month PAD District II...

406

Validated HPLC Method and Temperature Stabilities for Oil-Soluble Organosulfur Compounds in Garlic Macerated Oil  

Science Journals Connector (OSTI)

......HPLC Method and Temperature Stabilities for Oil-Soluble Organosulfur Compounds in Garlic Macerated Oil Miyoung Yoo Sunyoung Kim Sanghee Lee Dongbin...enhance the utilization of garlic macerated oil as functional foods, oil-soluble organosulfur......

Miyoung Yoo; Sunyoung Kim; Sanghee Lee; Dongbin Shin

2013-11-01T23:59:59.000Z

407

Consumer Winter Heating Oil Costs  

Gasoline and Diesel Fuel Update (EIA)

5 5 Notes: Using the Northeast as a regional focus for heating oil, the typical oil-heated household consumes about 680 gallons of oil during the winter, assuming that weather is "normal." The previous three winters were warmer than average and generated below normal consumption rates. Last winter, consumers saw large increases over the very low heating oil prices seen during the winter of 1998-1999 but, outside of the cold period in late January/early February they saw relatively low consumption rates due to generally warm weather. Even without particularly sharp cold weather events this winter, we think consumers are likely to see higher average heating oil prices than were seen last winter. If weather is normal, our projections imply New England heating oil

408

Retail Diesel Fuel Oil Prices  

Gasoline and Diesel Fuel Update (EIA)

Along with heating oil prices, the distillate supply squeeze has Along with heating oil prices, the distillate supply squeeze has severely impacted diesel fuel prices, especially in the Northeast. Diesel fuel is bascially the same product as home heating oil. The primary difference is that diesel has a lower sulfur content. When heating oil is in short supply, low sulfur diesel fuel can be diverted to heating oil supply. Thus, diesel fuel prices rise with heating heating oil prices. Retail diesel fuel prices nationally, along with those of most other petroleum prices, increased steadily through most of 1999. But prices in the Northeast jumped dramatically in the third week of January. Diesel fuel prices in New England rose nearly 68 cents per gallon, or 47 percent, between January 17 and February 7. While EIA does not have

409

Northeast Home Heating Oil Reserve  

Gasoline and Diesel Fuel Update (EIA)

Northeast Home Heating Oil Reserve Northeast Home Heating Oil Reserve Information on the Northeast Home Heating Oil Reserve is available from the U.S. Department of Energy (DOE) Office of Petroleum Reserves web site at http://www.fossil.energy.gov/programs/reserves/heatingoil/. Northeast Home Heating Oil Reserve (NEHHOR) inventories now classified as ultra-low sulfur distillate (15 parts per million) are not considered to be in the commercial sector and therefore are excluded from distillate fuel oil supply and disposition statistics in Energy Information Administration publications, such as the Weekly Petroleum Status Report, Petroleum Supply Monthly, and This Week In Petroleum. Northeast Home Heating Oil Reserve Terminal Operator Location (Thousand Barrels) Hess Corp. Groton, CT 500*

410

International Oil Supplies and Demands  

SciTech Connect (OSTI)

The eleventh Energy Modeling Forum (EMF) working group met four times over the 1989--90 period to compare alternative perspectives on international oil supplies and demands through 2010 and to discuss how alternative supply and demand trends influence the world's dependence upon Middle Eastern oil. Proprietors of eleven economic models of the world oil market used their respective models to simulate a dozen scenarios using standardized assumptions. From its inception, the study was not designed to focus on the short-run impacts of disruptions on oil markets. Nor did the working group attempt to provide a forecast or just a single view of the likely future path for oil prices. The model results guided the group's thinking about many important longer-run market relationships and helped to identify differences of opinion about future oil supplies, demands, and dependence.

Not Available

1991-09-01T23:59:59.000Z

411

International Oil Supplies and Demands  

SciTech Connect (OSTI)

The eleventh Energy Modeling Forum (EMF) working group met four times over the 1989--1990 period to compare alternative perspectives on international oil supplies and demands through 2010 and to discuss how alternative supply and demand trends influence the world's dependence upon Middle Eastern oil. Proprietors of eleven economic models of the world oil market used their respective models to simulate a dozen scenarios using standardized assumptions. From its inception, the study was not designed to focus on the short-run impacts of disruptions on oil markets. Nor did the working group attempt to provide a forecast or just a single view of the likely future path for oil prices. The model results guided the group's thinking about many important longer-run market relationships and helped to identify differences of opinion about future oil supplies, demands, and dependence.

Not Available

1992-04-01T23:59:59.000Z

412

The twentieth oil shale symposium proceedings  

SciTech Connect (OSTI)

This book contains 20 selections. Some of the titles are: The technical contributions of John Ward Smith in oil shale research; Oil shale rubble fires: ignition and extinguishment; Fragmentation of eastern oil shale for in situ recovery; A study of thermal properties of Chinese oil shale; and Natural invasion of native plants on retorted oil shale.

Gary, J.H.

1987-01-01T23:59:59.000Z

413

Rheological Behavior of Castor Oil Biodiesel  

Science Journals Connector (OSTI)

Rheological Behavior of Castor Oil Biodiesel ... This work aims at assessing the rheological behavior of castor oil, castor oil biodiesel, and undegraded and degraded biodiesel at different exposure times and temperatures. ... Castor oil biodiesel presents viscosity higher than diesel oil, but this drawback can be corrected by means of blends of both components at different proportions. ...

Marta M. Conceição; Roberlúcia A. Candeia; Hermesson J. Dantas; Luiz E. B. Soledade; Valter J. Fernandes, Jr.; Antonio G. Souza

2005-07-08T23:59:59.000Z

414

BP Oil Spill November 10, 2011  

E-Print Network [OSTI]

BP Oil Spill Qiyam Tung November 10, 2011 1 Introduction Figure 1: BP Oil spill (source: http://thefoxisblack.com/2010/05/02/the-bp-oil-spill-in-the-gulf-of-mexico/) Last year, there was a major oil spill caused major techniques to minimize the threat once it happened. What kind of damage would an oil spill like this cause

Lega, Joceline

415

Engine combustion, performance and emission characteristics of gas to liquid (GTL) fuels and its blends with diesel and bio-diesel  

Science Journals Connector (OSTI)

Abstract Crude oil price hikes, energy security concerns and environmental drivers have turned the focus to alternative fuels. Gas to liquid (GTL) diesel is regarded as a promising alternative diesel fuel, considering the adeptness to use directly as a diesel fuel or in blends with petroleum-derived diesel or bio-diesel. GTL fuel derived from Fischer–Tropsch synthesis is of distinctly different characteristics than fossil diesel fuel due to its paraffinic nature, virtually zero sulfur, low aromatic contents and very high cetane number. GTL fuel is referred to as a “clean fuel” for its inherent ability to reduce engine exhaust emission even with blends of diesel and bio-diesel. This paper illustrates feasibility of GTL fuel in context of comparative fuel properties with conventional diesel and bio-diesels. This review also describes the technical attributes of GTL and its blends with diesel and bio-diesel focusing their impact on engine performance and emission characteristics on the basis of the previous research works. It can introduce an efficacious guideline to devise several blends of alternative fuels, further the development of engine performance and constrain exhaust emission to cope with the relentless efforts to manufacture efficient and environment friendly powertrains.

H. Sajjad; H.H. Masjuki; M. Varman; M.A. Kalam; M.I. Arbab; S. Imtenan; S.M. Ashrafur Rahman

2014-01-01T23:59:59.000Z

416

Gasoline from natural gas by sulfur processing. Quarterly report No. 5 for the period July 1994--September 1994  

SciTech Connect (OSTI)

Natural gas is an abundant resource in various parts of the world. The major component of natural gas is methane, often comprising over 90% of the hydrocarbon fraction of the gas. The expanded use of natural gas as fuel is often hampered because of difficulties in storing and handling a gaseous fuel. This is especially true for natural gas in remote areas such as the North Slope of Alaska. The successful implementation of a natural gas-to-gasoline process would decrease dependence on imported oil for transportation fuels. These factors make it very desirable to convert natural gas to more valuable liquids. There are commercial processes for converting natural gas to gasoline-range liquids. These processes, such as the Fischer-Tropsch synthesis and Mobil`s MTG (Methanol To Gasoline), start with the steam reforming of methane. Steam reforming of methane requires the removal of sulfur compounds present in natural gas down to less than 0.1 ppm. This additional gas cleanup step, with its additional cost, is necessary because the catalysts are quickly poisoned by sulfur compounds.

Erekson, E.J.; Miao, F.Q.

1994-10-01T23:59:59.000Z

417

Assessment of Gasification-Based Biorefining at Kraft Pulp and Paper Mills in the United States, Part A: Background and Assumptions  

SciTech Connect (OSTI)

Commercialization of black liquor and biomass gasification technologies is anticipated in the 2010-2015 time frame, and synthesis gas from gasifiers can be converted into liquid fuels using catalytic synthesis technologies that are already commercially established in the gas-to-liquids or coal-to-liquids industries. This set of two papers describes key results from a major assessment of the prospective energy, environmental, and financial performance of commercial gasification-based biorefineries integrated with kraft pulp and paper mills [1]. Seven detailed biorefinery designs were developed for a reference mill in the southeastern United States, together with the associated mass/energy balances, air emissions estimates, and capital investment requirements. The biorefineries provide chemical recovery services and co-produce process steam for the mill, some electricity, and one of three liquid fuels: a Fischer-Tropsch synthetic crude oil (which could be refined to vehicle fuels at an existing petroleum refinery), dimethyl ether (a diesel engine fuel or propane substitute), or an ethanol-rich mixed-alcohol product. This paper describes the key assumptions that underlie the biorefinery designs. Part B will present analytical results.

Larson, E. D.; Consonni, S.; Katofsky, R. E.; Iisa, K.; Frederick, W. J., Jr.

2008-11-01T23:59:59.000Z

418

EA-1642: Final Environmental Assessment | Department of Energy  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

642: Final Environmental Assessment 642: Final Environmental Assessment EA-1642: Final Environmental Assessment Design and Construction of an Early Lead Mini Fischer-Tropsch Refinery at the University of Kentucky Center for Applied Energy Research Near Lexington, Kentucky The U.S. Department of Energy and National Energy Technology Laboratory prepared this environmental assessment to analyze the potential environmental impacts of providing funding for the proposed Early Lead Mini Fischer-Tropsch Refinery. DOE/EA-1642: Design and Construction of an Early Lead Mini Fischer-Tropsch Refinery at the University of Kentucky Center for Applied Energy Research Near Lexington, Kentucky (July 2009) More Documents & Publications EA-1642: Finding of No Significant Impact EA-1642S: Supplemental Draft Environmental Assessment

419

EA-1642: Finding of No Significant Impact | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Finding of No Significant Impact Finding of No Significant Impact EA-1642: Finding of No Significant Impact Design and Construction of an Early Lead Mini-Fischer-Tropsch Refinery at the University of Kentucky Center for Applied Energy Research Near Lexington, Kentucky The Department of Energy has prepared an Environmental Assessment for providing funding to advance the design and construction of a proposed Early Lead Mini-Fischer-Tropsch Refinery to be located at and operated by the University of Kentucky Center for Applied Energy Research north of Lexington, Kentucky Finding of No Significant Impace for Design and Construction of an Early Lead Mini-Fischer-Tropsch Refinery at the University of Kentucky Center for Applied Energy Research Near Lexington, Kentucky More Documents & Publications

420

EA-1642S: Small-Scale Pilot Plant for the Gasification of Coal and  

Broader source: Energy.gov (indexed) [DOE]

642S: Small-Scale Pilot Plant for the Gasification of Coal and 642S: Small-Scale Pilot Plant for the Gasification of Coal and Coal-Biomass Blends and Conversion of Derived Syngas to Liquid Fuels via Fischer-Tropsch Synthesis, Lexington, KY EA-1642S: Small-Scale Pilot Plant for the Gasification of Coal and Coal-Biomass Blends and Conversion of Derived Syngas to Liquid Fuels via Fischer-Tropsch Synthesis, Lexington, KY SUMMARY This draft Supplemental Environmental Assessment (SEA) analyzes the potential environmental impacts of DOE's proposed action of providing cost-shared funding for the University of Kentucky (UK) Center for Applied Energy Research (CAER) Small-Scale Pilot Plant for the Gasification of Coal and Coal-Biomass Blends and Conversion of Derived Syngas to Liquid Fuels via Fischer-Tropsch Synthesis project and of the No-Action Alternative.

Note: This page contains sample records for the topic "oils biomass-derived fischer-tropsch" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Calorimetric study of adsorption of aliphatic hydrocarbons on reduced cobalt catalyst  

SciTech Connect (OSTI)

A study has been made of the heats of adsorption and the adsorption isotherms of saturated and unsaturated hydrocarbons on Co at 298/sup 0/K; the content of organic matter in the catalyst has been determined after use in the Fischer-Tropsch synthesis. It is concluded that the Fischer-Tropsch process includes stages of diffusion of the original reactants and the products through a liquid film of hydrocarbons coating the catalyst; the hydrocarbon molecules are adsorbed on the surface in the ''lying down'' position; the adsorption of paraffins is reversible and is described by the BET theory; olefins form an irreversibly chemisorbed monolayer, above which reversible adsorption takes place; the ease of desorption of the paraffins explains their preferential formation in the Fischer-Tropsch synthesis.

Ostrovskii, V.E.; Medvedkova, E.A.

1986-06-01T23:59:59.000Z

422

Argonne Transportation Technology R&D Center - Alternative Fuels -  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Fischer-Tropsch Fuels Fischer-Tropsch Fuels SunDiesel fuel This Sun Diesel BTL fuel, made from wood chips, results in lower particulate matter and nitrogen oxide emissions. Fischer-Tropsch (F-T) fuels are synthetic diesel fuels produced by converting gaseous hydrocarbons, such as natural gas and gasified coal or biomass, into liquid fuel. These fuels are commonly categorized into the following groups: Biomass to liquids (BTL) Gas to liquids (GTL) Coal to liquids (CTL) Argonne engineers are investigating the performance and emissions data of F-T fuels for both older and newer vehicles. The goal is to provide this data to the U.S. Department of Energy, the auto industry and energy suppliers. Part of the lab's strategy also includes publishing the data to solicit ideas and input from the fuels and combustion community.

423

Solar retorting of oil shale  

DOE Patents [OSTI]

An apparatus and method for retorting oil shale using solar radiation. Oil shale is introduced into a first retorting chamber having a solar focus zone. There the oil shale is exposed to solar radiation and rapidly brought to a predetermined retorting temperature. Once the shale has reached this temperature, it is removed from the solar focus zone and transferred to a second retorting chamber where it is heated. In a second chamber, the oil shale is maintained at the retorting temperature, without direct exposure to solar radiation, until the retorting is complete.

Gregg, David W. (Morago, CA)

1983-01-01T23:59:59.000Z

424

Oil cooled, hermetic refrigerant compressor  

DOE Patents [OSTI]

A hermetic refrigerant compressor having an electric motor and compressor assembly in a hermetic shell is cooled by oil which is first cooled in an external cooler 18 and is then delivered through the shell to the top of the motor rotor 24 where most of it is flung radially outwardly within the confined space provided by the cap 50 which channels the flow of most of the oil around the top of the stator 26 and then out to a multiplicity of holes 52 to flow down to the sump and provide further cooling of the motor and compressor. Part of the oil descends internally of the motor to the annular chamber 58 to provide oil cooling of the lower part of the motor, with this oil exiting through vent hole 62 also to the sump. Suction gas with entrained oil and liquid refrigerant therein is delivered to an oil separator 68 from which the suction gas passes by a confined path in pipe 66 to the suction plenum 64 and the separated oil drops from the separator to the sump. By providing the oil cooling of the parts, the suction gas is not used for cooling purposes and accordingly increase in superheat is substantially avoided in the passage of the suction gas through the shell to the suction plenum 64.

English, William A. (Murrysville, PA); Young, Robert R. (Murrysville, PA)

1985-01-01T23:59:59.000Z

425

Oil cooled, hermetic refrigerant compressor  

DOE Patents [OSTI]

A hermetic refrigerant compressor having an electric motor and compressor assembly in a hermetic shell is cooled by oil which is first cooled in an external cooler and is then delivered through the shell to the top of the motor rotor where most of it is flung radially outwardly within the confined space provided by the cap which channels the flow of most of the oil around the top of the stator and then out to a multiplicity of holes to flow down to the sump and provide further cooling of the motor and compressor. Part of the oil descends internally of the motor to the annular chamber to provide oil cooling of the lower part of the motor, with this oil exiting through vent hole also to the sump. Suction gas with entrained oil and liquid refrigerant therein is delivered to an oil separator from which the suction gas passes by a confined path in pipe to the suction plenum and the separated oil drops from the separator to the sump. By providing the oil cooling of the parts, the suction gas is not used for cooling purposes and accordingly increase in superheat is substantially avoided in the passage of the suction gas through the shell to the suction plenum. 3 figs.

English, W.A.; Young, R.R.

1985-05-14T23:59:59.000Z

426

European Market Study for BioOil (Pyrolysis Oil)  

E-Print Network [OSTI]

European Market Study for BioOil (Pyrolysis Oil) Dec 15, 2006 Doug Bradley President Climate Change Solutions National Team Leader- IEA Bioenergy Task 40- Bio-trade 402 Third Avenue ·Ottawa, Ontario ·Canada K. Market Determining Factors 5. EU Country Perspectives 6. Potential European Markets 6.1. Pulp Mill Lime

427

Rheological properties of heavy oils and heavy oil emulsions  

SciTech Connect (OSTI)

In this study, the author investigated the effects of a number of process variables such as shear rate, measurement temperature, pressure, the influence of pretreatment, and the role of various amounts of added water on the rheology of the resulting heavy oil or the emulsion. Rheological properties of heavy oils and the corresponding emulsions are important from transportation and processing standpoints.

Khan, M.R. [Texaco, Inc., Beacon, NY (United States). Fuels and Lubricants Technology Dept.

1996-06-01T23:59:59.000Z

428

Rerefined Oil: An Option that Saves Oil, Minimizes Pollution  

Science Journals Connector (OSTI)

...of the annual oil consumption of the United States...desirably, burned as a fuel under carefully...percent of U.S. consumption of petroleum. About...oil was burned as fuel. Another 200 million...from gasoline and diesel fuel, carbon...me-tallic particles from engine wear, and metals...

THOMAS H. MAUGH II

1976-09-17T23:59:59.000Z

429

Oil burner nozzle  

DOE Patents [OSTI]

An oil burner nozzle for use with liquid fuels and solid-containing liquid fuels. The nozzle comprises a fuel-carrying pipe, a barrel concentrically disposed about the pipe, and an outer sleeve retaining member for the barrel. An atomizing vapor passes along an axial passageway in the barrel, through a bore in the barrel and then along the outer surface of the front portion of the barrel. The atomizing vapor is directed by the outer sleeve across the path of the fuel as it emerges from the barrel. The fuel is atomized and may then be ignited.

Wright, Donald G. (Rockville Center, NY)

1982-01-01T23:59:59.000Z

430

Oil resources: the key to prosperity or to poverty? : Influence of oil price shocks on spending of oil revenues.  

E-Print Network [OSTI]

??Abundant natural resources, in particular oil, play an important role in the economics of many countries. The oil price shocks that have been happening continuously… (more)

Selivanova, Olga

2008-01-01T23:59:59.000Z

431

WASTEWATER TREATMENT IN THE OIL SHALE INDUSTRY  

E-Print Network [OSTI]

is in intimate contact with oil and shale during In in-situin contact with the oil and shale. These methods and othersWaters from Green River Oil Shale," Chem. and Ind. , 1. ,

Fox, J.P.

2010-01-01T23:59:59.000Z

432

This Week In Petroleum Crude Oil Section  

Gasoline and Diesel Fuel Update (EIA)

Crude oil futures and estimated contract prices (dollars per barrel) Contract 1 Contract 2 Contract 3 Contract 4 Crude oil futures price contract 1 graph Crude oil futures price...

433

WASTEWATER TREATMENT IN THE OIL SHALE INDUSTRY  

E-Print Network [OSTI]

Waters from Green River Oil Shale," Chem. and Ind. , 1. ,Effluents from In-Situ oil Shale Processing," in Proceedingsin the Treatment of Oil Shale Retort Waters," in Proceedings

Fox, J.P.

2010-01-01T23:59:59.000Z

434

CORROSION OF METALS IN OIL SHALE ENVIRONMENTS  

E-Print Network [OSTI]

CORROSION OF METALS IN OIL SHALE ENVIRONMENTS A. Levy and R.of Metals in In-Situ Oil Shale Retorts," NACE Corrosion 80,Elevated Temperature Corrosion of Oil Shale Retort Component

Bellman Jr., R.

2012-01-01T23:59:59.000Z

435

WASTEWATER TREATMENT IN THE OIL SHALE INDUSTRY  

E-Print Network [OSTI]

III, "Method of Breaking Shale Oil-Water Emulsion," U. S.and Biological Treatment of Shale Oil Retort Water, DraftPA (1979). H. H. Peters, Shale Oil Waste Water Recovery by

Fox, J.P.

2010-01-01T23:59:59.000Z

436

CORROSION OF METALS IN OIL SHALE ENVIRONMENTS  

E-Print Network [OSTI]

temperature, type of shale and oil content of shale iscontent of the shale, and shale oil content of the rock cantemperatures. Lean and Rich Shale Oil shales vary in their

Bellman Jr., R.

2012-01-01T23:59:59.000Z

437

Peak Oil Futures: Same Crisis, Different Responses  

Science Journals Connector (OSTI)

Peak oil theory predicts that global oil production will soon start a terminal decline. ... resource and technology will be available to replace oil as the backbone resource of industrial society. ... understand ...

Jörg Friedrichs

2012-01-01T23:59:59.000Z

438

Oil droplets as light absorbents in seawater  

Science Journals Connector (OSTI)

This paper presents spectra of light absorption coefficient of oil-in-water emulsion, derived using the Mie theory. In order to achieve that concentration of oil, degree of oil...

Otremba, Zbigniew

2007-01-01T23:59:59.000Z

439

Membrane degumming of crude vegetable oil  

E-Print Network [OSTI]

Crude vegetable oils contain various minor substances like phospholipids, coloring pigments, and free fatty acids (FFA) that may affect quality of the oil. Reduction of energy costs and waste disposal are major concerns for many oil refiners who...

Lin, Lan

2012-06-07T23:59:59.000Z

440

Crude oil and crude oil derivatives transactions by oil and gas producers.  

E-Print Network [OSTI]

??This study attempts to resolve two important issues. First, it investigates the diversification benefit of crude oil for equities. Second, it examines whether or not… (more)

Xu, He

2007-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "oils biomass-derived fischer-tropsch" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Fuel Cell Distributed Power Package Unit: Fuel Processing Based On  

E-Print Network [OSTI]

Gas or Biogas or Biomass derived Pyrolysis oil In-situ heat generation on catalyst lowers capital cost is burnt off during regenerationDiesel, NG, Propane, Biogas, Biomass Pyrolysis Oil Fuel Flexibility ·In

442

Foamy Oil Flow and its Role in Heavy Oil Production  

Science Journals Connector (OSTI)

Two?phase oil?gas flow in porous media is often encountered during oil production from oil bearing sedimentary rocks. Traditionally such flow is modeled by extending the Darcy’s law to two?phase flow by employing the concept of saturation dependent relative permeability. This model is remarkably successful as long as the fluid distribution within the porous medium is controlled by capillary forces. Under this condition the two fluids appear to flow in their own continuous flow channels. This flow description is applicable to most reservoir flow scenarios encountered in light oil production. However in primary production of heavy oil under solution?gas drive this flow model often fails to provide a satisfactory match of the observed behaviour.

Brij B. Maini; Bashir Busahmin

2010-01-01T23:59:59.000Z

443

www.fightbac.o anola oil is  

E-Print Network [OSTI]

Ca co Th Ca "Canola" c which is Addition Ca he Ca in Th ca Ca m C know? anola oil is ooking oils. he average anola oil is comes fro s another nal Inform anola oil is eart healthy anola oil is n the world. he part of th anola meal anola oil ca many crop va ano the lowest . canola see a good sou m

444

Crude Oil Supply  

Gasoline and Diesel Fuel Update (EIA)

Crude Oil Supply Domestic Production (a) .......................................... 6.22 6.29 6.42 7.02 7.11 7.29 7.61 7.97 8.26 8.45 8.57 8.86 6.49 7.50 8.54 Alaska .................................................................. 0.58 0.53 0.44 0.55 0.54 0.51 0.48 0.52 0.51 0.47 0.42 0.49 0.53 0.51 0.47 Federal Gulf of Mexico (b) .................................... 1.34 1.19 1.18 1.36 1.30 1.22 1.27 1.29 1.34 1.36 1.37 1.45 1.27 1.27 1.38 Lower 48 States (excl GOM) ................................ 4.31 4.57 4.80 5.11 5.28 5.56 5.87 6.16 6.41 6.61 6.77 6.91 4.70 5.72 6.68 Crude Oil Net Imports (c) ......................................... 8.55 8.88 8.52 7.89 7.47 7.61 7.94 7.36 6.66 6.78 6.83 6.06 8.46 7.60 6.58 SPR Net Withdrawals ..............................................

445

Process oil manufacturing process  

SciTech Connect (OSTI)

A method is described for producing a naphthenic process oil having reduced sulfur, nitrogen and polynuclear aromatics contents from a naphthenic feed containing same and having an atmospheric boiling range of about 650/sup 0/ to about 1200/sup 0/F. comprising: A. passing the feed into a first hydrotreating stage having a hydrotreating catalyst therein, the stage maintained at a temperature of about 600/sup 0/ to about 750/sup 0/F. and at a hydrogen partial pressure of about 400 to about 1500 psig, to convert at least a portion of the sulfur to hydrogen sulfide and the nitrogen to ammonia; B. passing the hydrotreated feed from the first hydrotreating stage in an intermediate stripping stage wherein hydrogen sulfide, ammonia, or both is removed; C. passing the hydrotreated feed from the intermediate stage into a second hydrotreating stage having therein a hydrotreating catalyst selected from the group consisting of nickel-molybdenum, cobalt-molybdenum, nickel-tungsten and mixtures thereof, the second hydrotreating stage maintained at a temperature lower than that of the first hydrotreating stage and at a hydrogen partial pressure ranging between about 400 and about 1,500 psig; D. monitoring the polynuclear aromatics content, the degree of saturation, or both of the product exiting the second hydrotreating stage; and, E. adjusting the temperature in the second hydrotreating stage to keep the polynuclear aromatics content, the degree of saturation, or both below a limit suitable for process oil.

Corman, B.G.; Korbach, P.F.; Webber, K.M.

1989-01-31T23:59:59.000Z

446

Soybean Oil as Diesel Fuel  

Science Journals Connector (OSTI)

Soybean Oil as Diesel Fuel ... TESTS are reported from Japan on the use of soybean oil as Diesel fuel in a 12-horsepower engine of 150-mm. ... This trouble was overcome by passing through some of the Diesel cooling water to heat the fuel tank and supply line. ...

C.H.S. TUPHOLME

1940-10-10T23:59:59.000Z

447

Oil shale - Heir to the petroleum kingdom  

Science Journals Connector (OSTI)

Oil shale - Heir to the petroleum kingdom ... A discussion of oil shale provides students with real-world problems that require chemical literacy. ...

Y. Schachter

1983-01-01T23:59:59.000Z

448

low-solids oil emulsion (drilling) mud  

Science Journals Connector (OSTI)

low-solids oil emulsion (drilling) mud, low-solids oil-in-water (drilling) mud ? öl-in-Wasser-(Bohr)...m, (f) mit geringem Feststoffanteil

2014-08-01T23:59:59.000Z

449

Compositional changes in heavy oil steamflood simulators.  

E-Print Network [OSTI]

??The numerical simulation of heavy oil steamfloods has generally been conducted assuming that the oil is non-volatile. Reservoir simulation has traditionally ignored compositional effect s… (more)

Lolley, Christopher Scott

2012-01-01T23:59:59.000Z

450

Marine Fuel Oil on a Mixed Base  

Science Journals Connector (OSTI)

Three grades of high–viscosity marine fuel oil are manufactured according to TU 38. ... developing the composition and technology for production of marine fuel oils [1– 4].

S. V. Kotov; A. G. Oltyrev; I. N. Kankaeva…

2001-05-01T23:59:59.000Z

451

Oil & Gas Technology Center | GE Global Research  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Global Research Oil & Gas Technology Center GE Global Research Oil & Gas Technology Center Mark Little, SVP and chief technology officer for GE, and Eric Gebhardt, vice president...

452

Review of EIA Oil Production Outlooks  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Review of EIA oil production outlooks For 2014 EIA Energy Conference July 15, 2014 | Washington, DC By Samuel Gorgen, Upstream Analyst Overview Gorgen, Tight Oil Production Trends...

453

Oil market in international and Norwegian perspectives.  

E-Print Network [OSTI]

??Crude oil is the most important energy source in global perspective. About 35 percent of the world’s primary energy consumption is supplied by oil, followed… (more)

Singsaas, Julia Nazyrova

2009-01-01T23:59:59.000Z

454

U.S. Crude Oil Export Policy  

Gasoline and Diesel Fuel Update (EIA)

or use therein. * Crude exported from Alaska's Cook Inlet. * Heavy California crude oil. * Exports connected to refining or exchange of petroleum reserve oil. * Re-exportation...

455

Distillate Fuel Oil Sales for Residential Use  

Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

End Use Product: Residential - Distillate Fuel Oil Residential - No. 1 Residential - No. 2 Residential - Kerosene Commercial - Distillate Fuel Oil Commercial - No. 1 Distillate...

456

Oil and Gas Research| GE Global Research  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Oil & Gas We're balancing the increasing demand for finite resources with technology that ensures access to energy for generations to come. Home > Innovation > Oil & Gas Innovation...

457

Enhanced Oil Recovery | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Enhanced Oil Recovery Enhanced Oil Recovery Thanks in part to innovations supported by the Office of Fossil Energy's National Energy Technology Laboratory over the past 30 years,...

458

United Oil Company | Open Energy Information  

Open Energy Info (EERE)

Company Jump to: navigation, search Name: United Oil Company Place: Pittsburgh, Pennsylvania Product: Vegetable-Oil producer Biodiesel producer based in Pittsburgh, PA References:...

459

AEO Early Release 2013 - oil  

U.S. Energy Information Administration (EIA) Indexed Site

Growing U.S. oil output and rising vehicle fuel economy to cut Growing U.S. oil output and rising vehicle fuel economy to cut U.S. reliance on foreign oil The United States is expected to continue cutting its dependence on petroleum and liquid fuels imports over the rest of this decade because of growing domestic crude oil production and more fuel-efficient vehicles on America's highways. The new long-term outlook from the U.S. Energy Information Administration shows America's dependence on imported petroleum and liquid fuels will decline from 45 percent of domestic demand last year to 34 percent by 2019. U.S. dependence on imported oil had reached 60 percent as recently as 2005. EIA Administrator Adam Sieminski explains: "The United States will be able to meet more of its own energy needs because of two key

460

Heavy oil transportation by pipeline  

SciTech Connect (OSTI)

Worldwide there are a number of pipelines used to transport heavy crude oils. The operations are facilitated in a variety of ways. For example, the Alyeska pipeline is an insulated pipeline transporting warm oil over 800 miles. This 48-inch line experiences limited heat loss due to the insulation, volume of oil contained, and heat gain due to friction and pumping. Some European trunk lines periodically handle heavy and waxy crudes. This is achieved by proper sizing of batches, following waxy crudes with non-waxy crudes, and increased use of scrapers. In a former Soviet republic, the transportation of heavy crude oil by pipeline has been facilitated by blending with a lighter Siberian crude. The paper describes the pipeline transport of heavy crudes by Interprovincial Pipe Line Inc. The paper describes enhancing heavy oil transportation by emulsion formation, droplet suspension, dilution, drag reducing agents, and heating.

Gerez, J.M.; Pick, A.R. [Interprovincial Pipe Line Inc., Edmonton, Alberta (Canada)

1996-12-31T23:59:59.000Z

Note: This page contains sample records for the topic "oils biomass-derived fischer-tropsch" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Process for oil shale retorting  

DOE Patents [OSTI]

Particulate oil shale is subjected to a pyrolysis with a hot, non-oxygenous gas in a pyrolysis vessel, with the products of the pyrolysis of the shale contained kerogen being withdrawn as an entrained mist of shale oil droplets in a gas for a separation of the liquid from the gas. Hot retorted shale withdrawn from the pyrolysis vessel is treated in a separate container with an oxygenous gas so as to provide combustion of residual carbon retained on the shale, producing a high temperature gas for the production of some steam and for heating the non-oxygenous gas used in the oil shale retorting process in the first vessel. The net energy recovery includes essentially complete recovery of the organic hydrocarbon material in the oil shale as a liquid shale oil, a high BTU gas, and high temperature steam.

Jones, John B. (300 Enterprise Bldg., Grand Junction, CO 80501); Kunchal, S. Kumar (300 Enterprise Bldg., Grand Junction, CO 80501)

1981-10-27T23:59:59.000Z

462

Consumer Winter Heating Oil Costs  

Gasoline and Diesel Fuel Update (EIA)

6 6 Notes: The outlook for heating oil costs this winter, due to high crude oil costs and tight heating oil supplies, breaks down to an expected increase in heating expenditures for a typical oil-heated household of more than $200 this winter, the result of an 18% increase in the average price and an 11% increase in consumption. The consumption increase is due to the colder than normal temperatures experienced so far this winter and our expectations of normal winter weather for the rest of this heating season. Last winter, Northeast heating oil (and diesel fuel) markets experienced an extremely sharp spike in prices when a severe weather situation developed in late January. It is virtually impossible to gauge the probability of a similar (or worse) price shock recurring this winter,

463

Method of inducing surface ensembles on a metal catalyst  

DOE Patents [OSTI]

A method of inducing surface ensembles on a transition metal catalyst used in the conversion of a reactant gas or gas mixture, such as carbon monoxide and hydrogen into hydrocarbons (the Fischer-Tropsch reaction) is disclosed which comprises adding a Lewis base to the syngas (CO + H/sub 2/) mixture before reaction takes place. The formation of surface ensembles in this manner restricts the number and types of reaction pathways which will be utilized, thus greatly narrowing the product distribution and maximizing the efficiency of the Fischer-Tropsch reaction. Similarly, amines may also be produced by the conversion of reactant gas or gases, such as nitrogen, hydrogen, or hydrocarbon constituents.

Miller, S.S.

1987-10-02T23:59:59.000Z

464

RESEARCH OIL RECOVERY MECHANISMS IN HEAVY OIL RESERVOIRS  

SciTech Connect (OSTI)

The United States continues to rely heavily on petroleum fossil fuels as a primary energy source, while domestic reserves dwindle. However, so-called heavy oil (10 to 20{sup o}API) remains an underutilized resource of tremendous potential. Heavy oils are much more viscous than conventional oils. As a result, they are difficult to produce with conventional recovery methods such as pressure depletion and water injection. Thermal recovery is especially important for this class of reservoirs because adding heat, usually via steam injection, generally reduces oil viscosity dramatically. This improves displacement efficiency. The research described here was directed toward improved understanding of thermal and heavy-oil production mechanisms and is categorized into: (1) flow and rock properties; (2) in-situ combustion; (3) additives to improve mobility control; (4) reservoir definition; and (5) support services. The scope of activities extended over a three-year period. Significant work was accomplished in the area of flow properties of steam, water, and oil in consolidated and unconsolidated porous media, transport in fractured porous media, foam generation and flow in homogeneous and heterogeneous porous media, the effects of displacement pattern geometry and mobility ratio on oil recovery, and analytical representation of water influx. Significant results are described.

Anthony R. Kovscek; William E. Brigham

1999-06-01T23:59:59.000Z

465

Separation of oil-soluble sulfonates from sulfonated oils  

SciTech Connect (OSTI)

The authors aimed at developing a method for the complete recovery, from oil solutions, of oil-water-soluble sulfonates meeting the specifications, along with oils at least 99% pure, suitable for further processing. As the starting material the authors used an experimental batch of sulfonated and neutralized distillate lube stocks produced by selective solvent treatment. In determining the optimal extraction parameters, the authors investigated the influence of the solvent to original feed (S:F) weight ratio and the influence of the isopropyl alcohol (IPA) concentration on the composition of the sulfonates and oils recovered at 60/sup 0/C with a settling time of 2 h. The optimal conditions for two-stage extraction were found through a study of the influence of temperature and settling time on the compositions of the sulfonates and oils with S:F = 1.2:1 and with an IPA concentration of 40%. The process technology for two-stage recovery of oils and sulfonates from oil solutions was worked out in a pilot unit.

Ul'yanenko, V.I.; Yur'eva, N.P.; Sergeev, V.P.

1987-01-01T23:59:59.000Z

466

Research on oil recovery mechanisms in heavy oil reservoirs  

SciTech Connect (OSTI)

The research described here was directed toward improved understanding of thermal and heavy-oil production mechanisms and is categorized into: (1) flow and rock properties, (2) in-situ combustion, (3) additives to improve mobility control, (4) reservoir definition, and (5) support services. The scope of activities extended over a three-year period. Significant work was accomplished in the area of flow properties of steam, water, and oil in consolidated and unconsolidated porous media, transport in fractured porous media, foam generation and flow in homogeneous and heterogeneous porous media, the effects of displacement pattern geometry and mobility ratio on oil recovery, and analytical representation of water influx.

Kovscek, Anthony R.; Brigham, William E., Castanier, Louis M.

2000-03-16T23:59:59.000Z

467

No Oil: The coming Utopia/Dystopia and Communal Possibilities  

E-Print Network [OSTI]

supplies of conventional oil, and exploitable supplies of alternative forms of oil and related hydrocarbons, including tar sands and oil shale. Because new supplies of conventional oil are declining steadily, there is quite a lot of activity in the oil... to exploit the huge deposits of oil sands in Canada. Oil sands and oil shale look good because they contain vast amounts of oil. The problem is that of turning the reserves, locked into other geological formations, into useful oil. According to current...

Miller, Timothy

2006-03-01T23:59:59.000Z

468

Water issues associated with heavy oil production.  

SciTech Connect (OSTI)

Crude oil occurs in many different forms throughout the world. An important characteristic of crude oil that affects the ease with which it can be produced is its density and viscosity. Lighter crude oil typically can be produced more easily and at lower cost than heavier crude oil. Historically, much of the nation's oil supply came from domestic or international light or medium crude oil sources. California's extensive heavy oil production for more than a century is a notable exception. Oil and gas companies are actively looking toward heavier crude oil sources to help meet demands and to take advantage of large heavy oil reserves located in North and South America. Heavy oil includes very viscous oil resources like those found in some fields in California and Venezuela, oil shale, and tar sands (called oil sands in Canada). These are described in more detail in the next chapter. Water is integrally associated with conventional oil production. Produced water is the largest byproduct associated with oil production. The cost of managing large volumes of produced water is an important component of the overall cost of producing oil. Most mature oil fields rely on injected water to maintain formation pressure during production. The processes involved with heavy oil production often require external water supplies for steam generation, washing, and other steps. While some heavy oil processes generate produced water, others generate different types of industrial wastewater. Management and disposition of the wastewater presents challenges and costs for the operators. This report describes water requirements relating to heavy oil production and potential sources for that water. The report also describes how water is used and the resulting water quality impacts associated with heavy oil production.

Veil, J. A.; Quinn, J. J.; Environmental Science Division

2008-11-28T23:59:59.000Z

469

Total OECD Oil Stocks*  

Gasoline and Diesel Fuel Update (EIA)

6 6 Notes: The most recent data show OECD inventories remaining at very low levels. EIA expects inventories to remain low through the coming year. This increases the potential for price volatility through the rest of the winter, and into the next gasoline season. Inventories are a good measure of the supply/demand balance that affects prices. A large over-supply (production greater than demand) will put downward pressure on prices, while under-supply will push prices upward. As global oil production changed relative to demand, the world moved from a period of over-supply in 1998 to one of under-supply in 1999 and 2000. OECD inventories illustrate the changes in the world petroleum balance. OECD inventories rose to high levels during 1997 and 1998 when production exceeded demand and prices dropped to around $10 per barrel in

470

Total OECD Oil Stocks*  

Gasoline and Diesel Fuel Update (EIA)

The most recent data show OECD inventories remaining at very low The most recent data show OECD inventories remaining at very low levels. EIA expects inventories to remain low through the coming year. This increases the potential for price volatility through the winter, and even extending to the next gasoline season. Inventories are a good measure of the supply/demand balance that effects prices. A large over-supply (production greater than demand) will put downward pressure on prices, while under-supply will push prices upward. As global oil production changed relative to demand, the world moved from a period of over-supply in 1998 to one of under-supply in 1999 and 2000. OECD inventories illustrate the changes in the world petroleum balance. OECD inventories rose to high levels during 1997 and 1998 when production exceeded demand and prices dropped to around $10 per barrel in

471

Total OECD Oil Stocks*  

Gasoline and Diesel Fuel Update (EIA)

9 9 Notes: The most recent data show OECD inventories remaining at very low levels. EIA expects inventories to remain low through the coming year. This increases the potential for price volatility through the winter, and even extending to the next gasoline season. Inventories are a good measure of the supply/demand balance that effects prices. A large over-supply (production greater than demand) will put downward pressure on prices, while under-supply will push prices upward. As global oil production changed relative to demand, the world moved from a period of over-supply in 1998 to one of under-supply in 1999 and 2000. OECD inventories illustrate the changes in the world petroleum balance. OECD inventories rose to high levels during 1997 and 1998 when production exceeded demand and prices dropped to around $10 per barrel in

472

Diesel fuel oils, 1980  

SciTech Connect (OSTI)

Properties of diesel fuels produced during 1980 were submitted for study and compilation under a cooperative agreement between the Department of Energy, Bartlesville Energy Technology Center, Bartlesville, Oklahoma and the American Petroleum Institute. Tests of 192 samples of diesel fuel oils from 95 refineries throughout the country were made by 28 petroleum groups according to type of diesel fuel. Each group of analyses is subdivided into five tabulations according to five general regions of the country where the fuels are marketed. The regions, containing a total of 16 districts, are shown on a map in the report. Data from 13 laboratory tests on each individual diesel fuel sample are listed and arranged by geographic marketing districts in decreasing order of sales volumes. Charts are included showing trends of averages of certain properties for the four types of diesel fuels for the years 1960-1980. Summaries of the results of the 1980 survey, compared with similar data for 1979, are shown.

Shelton, E.M.

1980-12-01T23:59:59.000Z

473

Heating oils, 1983  

SciTech Connect (OSTI)

Properties of 195 heating oils marketed in the United States were submitted for study and compilation under agreement between the Bartlesville Energy Technology Center (BETC) and the American Petroleum Institute (API). The fuels were manufactured by 25 petroleum refining companies in 83 domestic refineries. The data are tabulated according to six grades of fuel and subdivided into five geographic regions in which the fuels are marketed. The six grades of fuels are defined by the American Society for Testing and Materials (ASTM) Specification D396. The five regions containing a total of 16 marketing districts are shown on a map in the report. Trend charts are included showing average properties of the six grades of fuel for the past several years. Summaries of the results of the tests by grade and by region for 1983 are compared with data for 1982. 7 figures, 12 tables.

Shelton, E.M.

1983-08-01T23:59:59.000Z

474

NETL: Oil & Natural Gas Projects: Alaska Heavy Oils  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Fluid and Rock Property Controls On Production and Seismic Monitoring Alaska Heavy Oils Last Reviewed 12/20/2012 Fluid and Rock Property Controls On Production and Seismic Monitoring Alaska Heavy Oils Last Reviewed 12/20/2012 DE-NT0005663 Goal The goal of this project is to improve recovery of Alaskan North Slope (ANS) heavy oil resources in the Ugnu formation by improving our understanding of the formationÂ’s vertical and lateral heterogeneities via core evaluation, evaluating possible recovery processes, and employing geophysical monitoring to assess production and modify production operations. Performers Colorado School of Mines, Golden, CO 80401 University of Houston, Houston, TX 77204 Earthworks, Newtown, CT 06470 BP, Anchorage, AK 99519 Background Although the reserves of heavy oil on the North Slope of Alaska are enormous (estimates are up to 10 billion barrels in place), difficult

475

International Oil and Gas Board International Oil and Gas Board...  

Open Energy Info (EERE)

Oil and Gas Board Address Place Zip Website Abu Dhabi Supreme Petroleum Council Abu Dhabi Supreme Petroleum Council Abu Dhabi http www abudhabi ae egovPoolPortal WAR appmanager...

476

State Oil and Gas Board State Oil and Gas Board Address Place Zip Website  

Open Energy Info (EERE)

State Oil and Gas Board Address Place Zip Website State Oil and Gas Board Address Place Zip Website Alabama Oil and Gas Board Alabama Oil and Gas Board Hackberry Lane Tuscaloosa Alabama http www gsa state al us ogb ogb html Alaska Division of Oil and Gas Alaska Division of Oil and Gas W th Ave Suite Anchorage Alaska http dog dnr alaska gov Alaska Oil and Gas Conservation Commission Alaska Oil and Gas Conservation Commission W th Ave Ste Anchorage Alaska http doa alaska gov ogc Arizona Oil and Gas Commission Arizona Oil and Gas Commission W Congress Street Suite Tucson Arizona http www azogcc az gov Arkansas Oil and Gas Commission Arkansas Oil and Gas Commission Natural Resources Dr Ste Little Rock Arkansas http www aogc state ar us JDesignerPro JDPArkansas AR Welcome html California Division of Oil Gas and Geothermal Resources California

477

EIA - Projections of Oil Production Capacity and Oil Production In three  

Gasoline and Diesel Fuel Update (EIA)

Projections of Oil Production Capacity and Oil Production in Three Cases (1990-2030) Projections of Oil Production Capacity and Oil Production in Three Cases (1990-2030) International Energy Outlook 2006 Projections of Oil Production Capacity and Oil Production In Three Cases Data Tables (1990-2030) Formats Table Data Titles (1 to 6 complete) Projections of Oil Production Capacity and Oil Production In Three Cases Tables. Need help, contact the National Energy Information Center at 202-586-8800. Projections of Oil Production Capacity and Oil Production In Three Cases Tables. Need help, contact the National Energy Information Center at 202-586-8800. Table E1 World Oil Production Capacity by Region and Country, Reference Case Projections of Oil Production Capacity and Oil Production In Three Cases Tables. Need help, contact the National Energy Information Center at 202-586-8800.

478

Interior acts on oil shale  

Science Journals Connector (OSTI)

Interior acts on oil shale ... The Interior Department has taken the first step to open up the vast oil-shale deposits on public lands. ... According to Secretary of the Interior Stewart L. Udall, the new program is designed to encourage competition in developing oil-shale resources, prevent speculation and windfall profits, promote mining operation and production practices that are consistent with good conservation management, encourage the fullest use of the resources, and provide reasonable revenues to the states and to the Federal Government. ...

1967-02-06T23:59:59.000Z

479

Combustion heater for oil shale  

DOE Patents [OSTI]

A combustion heater for oil shale heats particles of spent oil shale containing unburned char by burning the char. A delayed fall is produced by flowing the shale particles down through a stack of downwardly sloped overlapping baffles alternately extending from opposite sides of a vertical column. The delayed fall and flow reversal occurring in passing from each baffle to the next increase the residence time and increase the contact of the oil shale particles with combustion supporting gas flowed across the column to heat the shale to about 650 to 700/sup 0/C for use as a process heat source.

Mallon, R.; Walton, O.; Lewis, A.E.; Braun, R.

1983-09-21T23:59:59.000Z

480

Combustion heater for oil shale  

DOE Patents [OSTI]

A combustion heater for oil shale heats particles of spent oil shale containing unburned char by burning the char. A delayed fall is produced by flowing the shale particles down through a stack of downwardly sloped overlapping baffles alternately extending from opposite sides of a vertical column. The delayed fall and flow reversal occurring in passing from each baffle to the next increase the residence time and increase the contact of the oil shale particles with combustion supporting gas flowed across the column to heat the shale to about 650.degree.-700.degree. C. for use as a process heat source.

Mallon, Richard G. (Livermore, CA); Walton, Otis R. (Livermore, CA); Lewis, Arthur E. (Los Altos, CA); Braun, Robert L. (Livermore, CA)

1985-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "oils biomass-derived fischer-tropsch" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

Oil Shale Research in the United States  

Broader source: Energy.gov [DOE]

Profiles of Oil Shale Research and Development Activities In Universities, National Laboratories, and Public Agencies

482

EMPLOYEE BENEFIT SERVICE Signature Service Oil Change  

E-Print Network [OSTI]

UNM Staff EMPLOYEE BENEFIT SERVICE Jiffy Lube Signature Service Oil Change Fast - No Appointment We change your oil with up to 5 quarts of major brand motor oil We install a new oil fi We visually inspect. ASE training programs · Jiffy Lube uses top quality products that meet or exceed vehicle warranty

New Mexico, University of

483

Liens for Oil and Gas Operations (Nebraska)  

Broader source: Energy.gov [DOE]

This section contains regulations concerning lien allowances made to operators of oil and gas operations.

484

Favorable conditions noted for Australia shale oil  

SciTech Connect (OSTI)

After brief descriptions of the Rundle, Condor, and Stuart/Kerosene Creek oil shale projects in Queensland, the competitive advantages of oil shale development and the state and federal governments' attitudes towards an oil shale industry in Australia are discussed. It is concluded that Australia is the ideal country in which to start an oil shale industry.

Not Available

1986-09-01T23:59:59.000Z

485

Bureau of Land Management Oil Shale Development  

E-Print Network [OSTI]

Bureau of Land Management Oil Shale Development Unconventional Fuels Conference University of Utah May 17, 2011 #12;#12;Domestic Oil Shale Resources Primary oil shale resources in the U.S. are in the Green River Formation in Wyoming, Utah, and Colorado. 72 % of this oil shale resource is on Federal

Utah, University of

486

Fire and explosion hazards of oil shale  

SciTech Connect (OSTI)

The US Bureau of Mines publication presents the results of investigations into the fire and explosion hazards of oil shale rocks and dust. Three areas have been examined: the explosibility and ignitability of oil shale dust clouds, the fire hazards of oil shale dust layers on hot surfaces, and the ignitability and extinguishment of oil shale rubble piles. 10 refs., 54 figs., 29 tabs.

Not Available

1989-01-01T23:59:59.000Z

487

Declining oil prices boost chemical profits  

Science Journals Connector (OSTI)

Declining oil prices boost chemical profits ... As a consequence of the oil price drop, the composition of feedstocks to steam crackers, which are sources for major-volume olefins and many aromatics, is being changed. ... Where possible, more heavy feedstocks obtained from crude oil—naphthas and gas oils—are used in place of light hydrocarbons such as ethane. ...

1986-04-07T23:59:59.000Z

488

1 What is Oil ? General information  

E-Print Network [OSTI]

of petroleum products manufactured from crude oil. Many are for specific purposes, for example motor gasoline gasoline to heavier ones such as fuel oil. Oil #12;Crude oil Natural gas liquids Other hydrocarbons Aviation gasoline White spirit + SBP Gasoline type jet fuel Lubricants Unleaded gasoline Bitumen Leaded

Kammen, Daniel M.

489

OIL & GAS HISTORY 1 History in California  

E-Print Network [OSTI]

OIL & GAS HISTORY 1 History in California 4 Superior figures refer to references at the end of the essay. OIL AND GAS PRODUCTION California oil was always a valued commodity. When the Spanish explorers landed in California in the 1500s, they found Indians gathering asphaltum (very thick oil) from natural

490

Research on Oil Recovery Mechanisms in Heavy Oil Reservoirs  

SciTech Connect (OSTI)

The goal of this project is to increase recovery of heavy oils. Towards that goal studies are being conducted in how to assess the influence of temperature and pressure on the absolute and relative permeability to oil and water and on capillary pressure; to evaluate the effect of different reservoir parameters on the in site combustion process; to develop and understand mechanisms of surfactants on for the reduction of gravity override and channeling of steam; and to improve techniques of formation evaluation.

Louis M. Castanier; William E. Brigham

1998-03-31T23:59:59.000Z

491

OilEd: a Reason-able Ontology Editor for the Semantic Web  

E-Print Network [OSTI]

the full power of an expressive web ontology language (OIL). OilEd uses reasoning to support ontology been merged under the name DAML+OIL, although there are some differences between the approaches usedOilEd: a Reason-able Ontology Editor for the Semantic Web Sean Bechhofer, Ian Horrocks, Carole

Stevens, Robert

492

Plant-wide Control for Better De-oiling of Produced Water in Offshore Oil & Gas  

E-Print Network [OSTI]

Plant-wide Control for Better De-oiling of Produced Water in Offshore Oil & Gas Production Zhenyu (PWT) in offshore oil & gas production processes. Different from most existing facility- or material offshore and the oil industry expects this share to grow continuously in the future. In last decade, oil

Yang, Zhenyu

493

Oil and Gas CDT Development of a SUNTANS Baroclinic Model for 3D Oil  

E-Print Network [OSTI]

Oil and Gas CDT Development of a SUNTANS Baroclinic Model for 3D Oil Pollution Tracking Heriot) Key Words Oil Spill, HF Radar, Trajectory Forecasting, Hydrodynamic Modelling, Oil Chemistry Overview In an oil spill emergency, an operational system must forecast ocean and weather conditions in addition

Henderson, Gideon

494

OIL IN THE OPEN WATER Oil in the open water may a ect the health of  

E-Print Network [OSTI]

OIL IN THE OPEN WATER Oil in the open water may a ect the health of microscopic plants and animals. Far beneath the surface, corals and other deepwater communities might also be a ected. OIL AND HUMAN AND SEDIMENTS · Water quality surveys · Transect surveys to detect submerged oil · Oil plume modeling · Sediment

495

Oil shale: The environmental challenges III  

SciTech Connect (OSTI)

This book presents the papers of a symposium whose purpose was to discuss the environmental and socio-economic aspects of oil shale development. Topics considered include oil shale solid waste disposal, modeling spent shale disposal, water management, assessing the effects of oil shale facilities on water quality, wastewater treatment and use at oil shale facilities, potential air emissions from oil shale retorting, the control of air pollutant emissions from oil shale facilities, oil shale air emission control, socioeconomic research, a framework for mitigation agreements, the Garfield County approach to impact mitigation, the relationship of applied industrial hygiene programs and experimental toxicology programs, and industrial hygiene programs.

Petersen, K.K.

1983-01-01T23:59:59.000Z

496

Enhanced Oil Recovery | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Enhanced Oil Recovery Enhanced Oil Recovery Enhanced Oil Recovery Cross-section illustrating how carbon dioxide and water can be used to flush residual oil from a subsurface rock formation between wells. Cross-section illustrating how carbon dioxide and water can be used to flush residual oil from a subsurface rock formation between wells. Crude oil development and production in U.S. oil reservoirs can include up to three distinct phases: primary, secondary, and tertiary (or enhanced) recovery. During primary recovery, the natural pressure of the reservoir or gravity drive oil into the wellbore, combined with artificial lift techniques (such as pumps) which bring the oil to the surface. But only about 10 percent of a reservoir's original oil in place is typically produced during primary recovery. Secondary recovery techniques extend a

497

International Energy Outlook 1999 - World Oil Markets  

Gasoline and Diesel Fuel Update (EIA)

oil.gif (4669 bytes) oil.gif (4669 bytes) A moderate view of future oil market developments is reflected in IEO99. Sustained high levels of oil prices are not expected, whereas continued expansion of the oil resource base is anticipated. The crude oil market was wracked with turbulence during 1998, as prices fell by one-third on average from 1997 levels. Even without adjusting for inflation, the world oil price in 1998 was the lowest since 1973. The declining oil prices were influenced by an unexpected slowdown in the growth of energy demand worldwide—less than any year since 1990—and by increases in oil supply, particularly in 1997. Although the increase in world oil production in 1998 was smaller than in any year since 1993, efforts to bolster prices by imposing further limits on production were

498

Long Term World Oil Supply  

Gasoline and Diesel Fuel Update (EIA)

0 0 Notes: The following pages summarize a recent EIA presentation on estimates of the world conventional oil resource base and the year when production from it will peak and then begin to decline. A version of this presentation was given by former EIA Administrator Jay Hakes to the April 18, 2000 meeting of the American Association of Petroleum Geologists in New Orleans, Louisiana. Specific information about this presentation may be obtained from John Wood (john.wood@eia.doe.gov), Gary Long (gary.long@eia.doe.gov) or David Morehouse (david.morehouse@eia.doe.gov). Long Term World Oil Supply http://www.eia.doe.gov/pub/oil_gas/petroleum/presentations/2000/long_term_supply/sld001.htm [8/10/2000 4:56:23 PM] Slide 2 of 20 http://www.eia.doe.gov/pub/oil_gas/petroleum/presentations/2000/long_term_supply/sld002.htm [8/10/2000 4:56:24 PM]

499

crude oil | OpenEI  

Open Energy Info (EERE)

crude oil crude oil Dataset Summary Description This dataset comes from the Energy Information Administration (EIA), and is part of the 2011 Annual Energy Outlook Report (AEO2011). This dataset is table 132, and contains only the reference case. The data is broken down into Production, lower 48 onshore and lower 48 offshore. Source EIA Date Released April 26th, 2011 (3 years ago) Date Updated Unknown Keywords 2011 AEO crude oil EIA prices Data application/vnd.ms-excel icon AEO2011: Lower 48 Crude Oil Production and Wellhead Prices by Supply Region- Reference Case (xls, 54.9 KiB) Quality Metrics Level of Review Peer Reviewed Comment Temporal and Spatial Coverage Frequency Annually Time Period 2008-2035 License License Open Data Commons Public Domain Dedication and Licence (PDDL)

500

RMOTC - Testing - Enhanced Oil Recovery  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Enhanced Oil Recovery Enhanced Oil Recovery Notice: As of July 15th 2013, the Department of Energy announced the intent to sell Naval Petroleum Reserve Number 3 (NPR3). The sale of NPR-3 will also include the sale of all equipment and materials onsite. A decision has been made by the Department of Energy to complete testing at RMOTC by July 1st, 2014. RMOTC will complete testing in the coming year with the currently scheduled testing partners. For more information on the sale of NPR-3 and sale of RMOTC equipment and materials please join our mailing list here. RMOTC will play a significant role in continued enhanced oil recovery (EOR) technology development and field demonstration. A scoping engineering study on Naval Petroleum Reserve No. 3's (NPR-3) enhanced oil recovery