Sample records for oilfield brine contaminated

  1. A cost-effective statistical screening method to detect oilfield brine contamination

    SciTech Connect (OSTI)

    Alyanak, N.; Grace, J.T.; Campbell, M.D. [United Resources International, Houston, TX (United States)

    1995-12-01T23:59:59.000Z

    A statistical screening method has been developed using Tolerance Limits for barium (Ba{sup +2}) to identify contamination of a fresh-water aquifer by oilfield brines. The method requires an understanding of the local hydrochemistry of oilfield brines, inexpensive, Publicly available hydrochemical data, a single sample analysis from the suspect well and the application of a simple statistical procedure. While this method may not provide absolute evidence of oilfield brine contamination of a fresh-water aquifer, it does identify conditions where brine contamination is a strong probability over other possible sources of chlorides.

  2. Cathodic protection in oilfield brine

    SciTech Connect (OSTI)

    Turnipseed, S.P. (Chevron U.S.A. Inc., Houston, TX (US))

    1991-12-01T23:59:59.000Z

    In this paper the use of cathodic protection (CP) to mitigate internal and corrosion-related failures that occur in the produced brine phase of oilfield tanks and production vessels is discussed. Unique considerations covered include brine properties, CP system selection, installation details, monitoring, and coatings.

  3. Exposure and effects of oilfield brine discharges on western sandpipers (Calidris mauri) in Nueces Bay, Texas

    SciTech Connect (OSTI)

    Rattner, B.A.; Melancon, M.J. [National Biological Survey, Laurel, MD (United States); Capizzi, J.L. [Texas A& M Univ., College Station, TX (United States); King, K.A. [Fish and Wildlife Service, Phoenix, AZ (United States); LeCaptain, L.J. [Fish and Wildlife Service, Spokane, WA (United States)

    1995-05-01T23:59:59.000Z

    Discharge of oilfield brines into fresh and estuarine waters is a common disposal practice in Texas. Petroleum crude oil (PCO) extraction from underground stores includes the removal of a significant amount of water along with the oil. Several methods may be used to separate the oil and water fractions, including tank batteries, heat separation, and skimming ponds. Disposal of the resultant produced water (oilfield brine) may be accomplished by deep-well injection or discharge to surface waters. In Texas, an estimated 766,000 barrels of oilfield brine were discharged daily into tidal waters in 1979. The maximum concentration for oil and grease in these discharges permitted by the Texas Railroad Commission is 25 ppm. Several studies have shown that oilfield brines are toxic to a wide range of marine life, yet little is known about their effects on birds and mammals. Exposure to petroleum in oilfield wastes could evoke toxicological effects in some waterbird species. Avian responses to PCO exposure are highly variable, including cessation of growth, osmoregulatory impairment, endocrine dysfunction, hemolytic anemia, altered blood chemistry, cytochrome P450 induction, reduced reproductive success, and mortality. Oilfield brine discharges may soon be the largest and most pervasive source of contaminants entering Texas estuaries. Migratory and resident birds feeding in the vicinity of discharge sites may be ingesting food items contaminated with petroleum hydrocarbons, heavy metals and salts in sufficient quantities to evoke toxicity. The present study of wintering western sandpipers (Calidris mauri) that feed and roost near discharge sites sought to examine oilfield brine exposure and effects through quantification of contaminant burdens, morphological characteristics, and cytochrome P450-associated monooxygenase activities. 20 refs., 2 tabs.

  4. Analysis of hydrocarbon removal methods for the management of oilfield brines and produced waters 

    E-Print Network [OSTI]

    Furrow, Brendan Eugene

    2005-11-01T23:59:59.000Z

    and globally, the petroleum industries challenge has been to develop a high-tech and cost effective method to purify the large volumes of oilfield brines and produced water. Currently, most of the produced water requires several pre- and post- treatment methods...

  5. New Energy Efficient Method for Cleaning Oilfield Brines with Carbon Dioxide 

    E-Print Network [OSTI]

    Little, C. T.; Seibert, A. F.; Bravo, J. L.; Fair, J. R.

    1991-01-01T23:59:59.000Z

    Water contaminated with hydrocarbons often results during the production of oil. The polluted water, which may be naturally occurring or a result of water or steam flooding operations, must be cleaned before disposal or re-injection. These brines...

  6. Development of a flow injection analysis method for the determination of acrylamide copolymers in oilfield brines

    SciTech Connect (OSTI)

    Taylor, K.C.; Burke, R.A.; Schramm, L.L. [Petroleum Recovery Inst., Calgary, Alberta (Canada); Nasr-El-Din, H.A. [Saudi Aramco, Dhahran (Saudi Arabia)

    1995-11-01T23:59:59.000Z

    An automated method for the determination of acrylamide polymers by flow injection analysis (FIA) has been developed and optimized for routine use. The method has been extensively tested for interferences common in oilfield brines. Potential interferences were examined from Na{sup +}, Ca{sup 2+}, Cr{sup 3+}, Al{sup 3+}, Zr{sup 3+}, NH{sub 4}{sup +}, Cl{sup {minus}}, OH{sup {minus}}, CO{sub 3}{sup 2{minus}}, sample coloration, and commonly used surfactants. The analysis is specific for amides, and the sensitivity to concentration of amide groups in the polymer was shown to be constant as the degree of polymer hydrolysis was varied. The range of the method is 0.1 to 100 mg/L. Sample throughput is 30 samples/h with triplicate analysis. Relative standard deviations of 0.2% are readily obtained from standard solutions and 0.5% from complex samples (at 50 mg/L). The method is applicable to the determination of aqueous, acrylamide-based polymers in process streams, surface waters and oilfield brines.

  7. Comparative analyses of soil contaminant levels and plant species diversity at developing and disused oil well sites in Qianjiang oilfield, China

    SciTech Connect (OSTI)

    Xiong, Z.T.; Hu, H.X.; Wang, Y.X. [Wuhan Univ., Hubei (China)] [and others] [Wuhan Univ., Hubei (China); and others

    1997-04-01T23:59:59.000Z

    Oilfield development contaminates soils and waters with crude oil, brine and heavy metals. Oil well sites are probably the most contaminated places in oilfields. During drilling and crude oil extraction from underground stores, a significant amount of oil and brine discharges into soils at oil well sites by blowouts, container spillages and pipeline ruptures. In oilfields in China, it was estimated that about 0.77 - 1.85% crude oil discharged into soils at oil well sites during oilfield development. Exposure to oil and salt contaminants could evoke toxicological effects in plants. Responses of plants to the contaminant exposure include inhibition of photosynthesis and nitrogen fixation, cessation of growth, reduced reproductive success and mortality. These harmful impacts on plants would be expected to result in remarkable loss of biodiversity. Qianjiang oilfield has been developed for about thirty-five years. Oil well sites in it have long been contaminated with oil and brine since, and plants at the well sites are rare. In the last three years however some wells have fallen into disuse. In result, a few plant species have intruded into the disuse well sites and formed new populations, and plant species diversity in these places has increased thereby. For benefit of restoration of the disuse well sites, it is interesting to know the relationships between contaminant levels and plant biodiversity. The present paper focuses the attention on comparative analyses of soil contaminations by crude oil, salt and some heavy metals and plant species diversity at developing and disuse oil well sites. 15 refs., 3 tabs.

  8. Determination of imidazoline and amido-amine type corrosion inhibitors in both crude oil and produced brine from oilfield production

    SciTech Connect (OSTI)

    Matherly, R.M.; Jiao, J. [Baker Performance Chemicals, Houston, TX (United States); Blumer, D.J. [ARCO Alaska Inc., Anchorage, AK (United States); Ryman, J.S. [Baker Performance Chemicals, Anchorage, AK (United States)

    1995-12-01T23:59:59.000Z

    The classical method for the determination of corrosion inhibitors in oilfield brines is the dye transfer method. Within this method are many variations which the analyst may use to determine the amount of corrosion inhibitor in either water or crude oil. These methods, however, suffer from many interferences which result in both false positive and negatives for corrosion inhibitor content. These methods essentially detect all amines as corrosion inhibitors. Improved high pressure liquid chromatography (HPLC) methods have been developed for the analysis of quaternary salt type corrosion inhibitors in brine waters, however, these methods do not appear to work in crude oil or for other forms of corrosion inhibitors such as the imidazolines, and amido-amines. This paper presents a method for the quantitative analysis of the imidazoline and amido-amine type corrosion inhibitors in both oilfield water and crude oil samples by HPLC. The corrosion inhibitor of interest is first separated from the matrix on a small column, then derivatized to form a product which is both sensitive and selective on a fluorescence detector. Detection limits for imidazolines are around 0.2 mg/L, amides and amines are similar. The advantage of this procedure is it can be used to determine the amount of corrosion inhibitor in both oil and brine water phases as well as on solid surfaces.

  9. Evaluations of Radionuclides of Uranium, Thorium, and Radium Associated with Produced Fluids, Precipitates, and Sludges from Oil, Gas, and Oilfield Brine Injection Wells in Mississippi

    SciTech Connect (OSTI)

    Ericksen, R.L.

    1999-10-28T23:59:59.000Z

    There is an unsurpassed lack of scientific data with respect to the concentrations and isotopic compositions of uranium, thorium, and radium in the produced formation fluids (brine), precipitates, and sludges generated with the operation of oil and gas wells in Mississippi. These radioactive elements when contained in the formation fluids have been given the term NORM, which is an acronym for naturally occurring radioactive materials. When they are technologically enhanced during oil and gas production activities resulting in the formation of scale (precipitates) and sludges they are termed TENORM (technologically enhanced naturally occurring radioactive materials). As used in this document, NORM and TENORM will be considered equivalent terms and the occurrence of NORM in the oilfield will be considered the result of production operations. As a result of the lack of data no scientifically sound theses may be developed concerning the presence of these radionuclides in the fluid brine, precipitate (scale), or sludge phases. Over the period of just one year, 1997 for example, Mississippi produced over 39,372,963,584 liters (10,402,368,186 gallons or 247,675,433 barrels) of formation water associated with hydrocarbon production from 41 counties across the state.

  10. EVALUATIONS OF RADIONUCLIDES OF URANIUM, THORIUM, AND RADIUM ASSOCIATED WITH PRODUCED FLUIDS, PRECIPITATES, AND SLUDGES FROM OIL, GAS, AND OILFIELD BRINE INJECTION WELLS IN MISSISSIPPI

    SciTech Connect (OSTI)

    Charles Swann; John Matthews; Rick Ericksen; Joel Kuszmaul

    2004-03-01T23:59:59.000Z

    Naturally occurring radioactive materials (NORM) are known to be produced as a byproduct of hydrocarbon production in Mississippi. The presence of NORM has resulted in financial losses to the industry and continues to be a liability as the NORM-enriched scales and scale encrusted equipment is typically stored rather than disposed of. Although the NORM problem is well known, there is little publically available data characterizing the hazard. This investigation has produced base line data to fill this informational gap. A total of 329 NORM-related samples were collected with 275 of these samples consisting of brine samples. The samples were derived from 37 oil and gas reservoirs from all major producing areas of the state. The analyses of these data indicate that two isotopes of radium ({sup 226}Ra and {sup 228}Ra) are the ultimate source of the radiation. The radium contained in these co-produced brines is low and so the radiation hazard posed by the brines is also low. Existing regulations dictate the manner in which these salt-enriched brines may be disposed of and proper implementation of the rules will also protect the environment from the brine radiation hazard. Geostatistical analyses of the brine components suggest relationships between the concentrations of {sup 226}Ra and {sup 228}Ra, between the Cl concentration and {sup 226}Ra content, and relationships exist between total dissolved solids, BaSO{sub 4} saturation and concentration of the Cl ion. Principal component analysis points to geological controls on brine chemistry, but the nature of the geologic controls could not be determined. The NORM-enriched barite (BaSO{sub 4}) scales are significantly more radioactive than the brines. Leaching studies suggest that the barite scales, which were thought to be nearly insoluble in the natural environment, can be acted on by soil microorganisms and the enclosed radium can become bioavailable. This result suggests that the landspreading means of scale disposal should be reviewed. This investigation also suggests 23 specific components of best practice which are designed to provide a guide to safe handling of NORM in the hydrocarbon industry. The components of best practice include both worker safety and suggestions to maintain waste isolation from the environment.

  11. Risk assessment of nonhazardous oil-field waste disposal in salt caverns.

    SciTech Connect (OSTI)

    Elcock, D.

    1998-03-10T23:59:59.000Z

    Salt caverns can be formed in underground salt formations incidentally as a result of mining or intentionally to create underground chambers for product storage or waste disposal. For more than 50 years, salt caverns have been used to store hydrocarbon products. Recently, concerns over the costs and environmental effects of land disposal and incineration have sparked interest in using salt caverns for waste disposal. Countries using or considering using salt caverns for waste disposal include Canada (oil-production wastes), Mexico (purged sulfates from salt evaporators), Germany (contaminated soils and ashes), the United Kingdom (organic residues), and the Netherlands (brine purification wastes). In the US, industry and the regulatory community are pursuing the use of salt caverns for disposal of oil-field wastes. In 1988, the US Environmental Protection Agency (EPA) issued a regulatory determination exempting wastes generated during oil and gas exploration and production (oil-field wastes) from federal hazardous waste regulations--even though such wastes may contain hazardous constituents. At the same time, EPA urged states to tighten their oil-field waste management regulations. The resulting restrictions have generated industry interest in the use of salt caverns for potentially economical and environmentally safe oil-field waste disposal. Before the practice can be implemented commercially, however, regulators need assurance that disposing of oil-field wastes in salt caverns is technically and legally feasible and that potential health effects associated with the practice are acceptable. In 1996, Argonne National Laboratory (ANL) conducted a preliminary technical and legal evaluation of disposing of nonhazardous oil-field wastes (NOW) into salt caverns. It investigated regulatory issues; the types of oil-field wastes suitable for cavern disposal; cavern design and location considerations; and disposal operations, closure and remediation issues. It determined that if caverns are sited and designed well, operated carefully, closed properly, and monitored routinely, they could, from technical and legal perspectives, be suitable for disposing of oil-field wastes. On the basis of these findings, ANL subsequently conducted a preliminary risk assessment on the possibility that adverse human health effects (carcinogenic and noncarcinogenic) could result from exposure to contaminants released from the NOW disposed of in salt caverns. The methodology for the risk assessment included the following steps: identifying potential contaminants of concern; determining how humans could be exposed to these contaminants; assessing contaminant toxicities; estimating contaminant intakes; and estimating human cancer and noncancer risks. To estimate exposure routes and pathways, four postclosure cavern release scenarios were assessed. These were inadvertent cavern intrusion, failure of the cavern seal, failure of the cavern through cracks, failure of the cavern through leaky interbeds, and partial collapse of the cavern roof. Assuming a single, generic, salt cavern and generic oil-field wastes, potential human health effects associated with constituent hazardous substances (arsenic, benzene, cadmium, and chromium) were assessed under each of these scenarios. Preliminary results provided excess cancer risk and hazard index (for noncancer health effects) estimates that were well within the EPA target range for acceptable exposure risk levels. These results lead to the preliminary conclusion that from a human health perspective, salt caverns can provide an acceptable disposal method for nonhazardous oil-field wastes.

  12. Brine contamination of ground water and streams in the Baxterville Oil Field Area, Lamar and Marion Counties, Mississippi. Water resources investigation

    SciTech Connect (OSTI)

    Kalkhoff, S.J.

    1993-12-31T23:59:59.000Z

    The report defines the extent of oil-field-brine contamination in ground water and streams in the Baxterville oil field area. The report is based largely on data collected during the period October 1984 through November 1985. Water samples were collected from streams and wells in the study area. Data from a previous study conducted in the vicinity of the nearby Tatum Salt Dome were used for background water-quality information. Natural surface-water quality was determined by sampling streamflow from a nearby basin having no oil field activities and from samples collected in an adjacent basin during a previous study.

  13. Oilfield property development: Risk assessment, management and control

    SciTech Connect (OSTI)

    Robertson, M.; Robles, H.; Manweiler, D. [Environmental Science & Engineering, Inc., Fountain Valley, CA (United States)

    1996-08-01T23:59:59.000Z

    Several regulatory authorities in California have developed new regulations/guidelines for oilfield remediation and subsequent development. The sole intent of the new regulations/guidelines is to protect public health; however, these efforts are often misdirected. In fact, many of the regulations/guidelines impose remediation or construction standards that, in effect, render the development of such properties impractical. These standards include or require stringent contaminant cleanup standards, minimum development setbacks from active and abandoned wells, natural-gas venting provisions for abandoned wells, and the widespread use of soil-gas barriers. Clearly, these regulatory changes have been made without due consideration of risk. Because, in actuality, the risks posed by former oilfield properties are insignificant when compared to other non- oilfield properties. The history of oilfield development in Southern California has shown that although some physical and chemical hazards do exist, oilfield development, properly managed, can usually be accomplished with acceptable residual risk. Rigid control measures, based on inaccurate assumptions, merely inhibit the useful development of valuable property and misdirect resources that could be more effectively applied where the risks are real and significant. To protect public health and allow for efficient resource allocation, risk control measures must be both adequate and proportional to the actual health risks and hazards posed. This paper reviews the history of oil production in Southern California, explains the known health risks associated with oilfield property development, and describes a risk management approach that will address these risks at an acceptable cost.

  14. Forecasting oilfield economic performance

    SciTech Connect (OSTI)

    Bradley, M.E. (Univ. of Chicago, IL (United States)); Wood, A.R.O. (BP Exploration, Anchorage, AK (United States))

    1994-11-01T23:59:59.000Z

    This paper presents a general method for forecasting oilfield economic performance that integrates cost data with operational, reservoir, and financial information. Practices are developed for determining economic limits for an oil field and its components. The economic limits of marginal wells and the role of underground competition receive special attention. Also examined is the influence of oil prices on operating costs. Examples illustrate application of these concepts. Categorization of costs for historical tracking and projections is recommended.

  15. ROCKY MOUNTAIN OILFIELD TESTING CENTER

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to SPT for modifications and re-testing. A 4-12" cased well at the Rocky Mountain Oilfield Testing Center (RMOTC) in Casper Wyoming was selected. The well conditions were:...

  16. Oilfield surveillance using personal computers

    SciTech Connect (OSTI)

    Moore, J.B.

    1985-03-01T23:59:59.000Z

    Personal computers and hand-held calculators were used in the development of an oilfield surveillance and data gathering system. Producing wells, steam injection wells, water plants, steam generators, and well workovers are all monitored through the use of personal computers. Personal computers provide an accurate and timely method of verifying and editing data as well as providing immediate retrieval of information vital to the daily operation of a thermal recovery oilfield.

  17. Economic disposal of solid oilfield wastes

    SciTech Connect (OSTI)

    Bruno, M.S.; Qian, H.X.

    1995-09-01T23:59:59.000Z

    A variety of solid oilfield wastes, including produced sand, tank bottoms, and crude contaminated soils, are generated during drilling, production, and storage processes. Crude oil and crude-contaminated sands or soils are generally designated as nonhazardous wastes. However, these materials still must be disposed of in an environmentally acceptable manner. The problems can become most pressing as oil fields in urban areas reach the end of their productive lives and the productive lives and the properties are redeveloped for residential use. An economically and environmentally sound solution is to reinject the solid waste into sand formations through slurry fracture muds and cuttings in Alaska, the Gulf of Mexico, and the North Sea; naturally occurring radioactive materials in Alaska and the Gulf of Mexico; and large volumes of produced oily sand in the provinces of Alberta and Saskatchewan, Canada. The technique offers a number of economic and environmental advantages for disposal of solid oilfield wastes. When reinjecting into depleted oil sands, the crude waste is simply being returned to its place of origin. The long-term liability to the operator is eliminated, in marked contrast to surface storage or landfill disposal. Finally, fracture-injection costs are less than typical transport and landfill disposal costs for moderate to large quantities of solid waste

  18. Oilfield flooding polymer

    DOE Patents [OSTI]

    Martin, Fred D. (Socorro, NM); Hatch, Melvin J. (Socorro, NM); Shepitka, Joel S. (Socorro, NM); Donaruma, Lorraine G. (Syosset, NY)

    1986-01-01T23:59:59.000Z

    A monomer, polymers containing the monomer, and the use of the polymer in oilfield flooding is disclosed. The subject monomer is represented by the general formula: ##STR1## wherein: n is an integer from 0 to about 4; m is an integer from 0 to about 6; a is an integer equal to at least 1 except where m is equal to 0, a must equal 0 and where m is equal to 1, a must equal 0 or 1; p is an integer from 2 to about 10; b is an integer equal to at least 1 and is of sufficient magnitude that the ratio b/p is at least 0.2; and q is an integer from 0 to 2. The number of hydroxy groups in the monomer is believed to be critical, and therefore the sum of (a+b) divided by the sum (m+p) should be at least 0.2. The moieties linked to the acrylic nitrogen can be joined to provide a ringed structure.

  19. Pseudokarst topography in a humid environment caused by contaminant-induced colloidal dispersion

    E-Print Network [OSTI]

    Sassen, Douglas Spencer

    2004-09-30T23:59:59.000Z

    with traditional piping erosion. In areas of sinkholes, geophysical measurements of apparent electrical conductivity delineated anomalously high conductivity levels that are interpreted as a brine release from a nearby oil-field waste injection well...

  20. Pseudokarst topography in a humid environment caused by contaminant-induced colloidal dispersion 

    E-Print Network [OSTI]

    Sassen, Douglas Spencer

    2004-09-30T23:59:59.000Z

    with traditional piping erosion. In areas of sinkholes, geophysical measurements of apparent electrical conductivity delineated anomalously high conductivity levels that are interpreted as a brine release from a nearby oil-field waste injection well...

  1. Oilfield Flare Gas Electricity Systems (OFFGASES Project)

    SciTech Connect (OSTI)

    Rachel Henderson; Robert Fickes

    2007-12-31T23:59:59.000Z

    The Oilfield Flare Gas Electricity Systems (OFFGASES) project was developed in response to a cooperative agreement offering by the U.S. Department of Energy (DOE) and the National Energy Technology Laboratory (NETL) under Preferred Upstream Management Projects (PUMP III). Project partners included the Interstate Oil and Gas Compact Commission (IOGCC) as lead agency working with the California Energy Commission (CEC) and the California Oil Producers Electric Cooperative (COPE). The project was designed to demonstrate that the entire range of oilfield 'stranded gases' (gas production that can not be delivered to a commercial market because it is poor quality, or the quantity is too small to be economically sold, or there are no pipeline facilities to transport it to market) can be cost-effectively harnessed to make electricity. The utilization of existing, proven distribution generation (DG) technologies to generate electricity was field-tested successfully at four marginal well sites, selected to cover a variety of potential scenarios: high Btu, medium Btu, ultra-low Btu gas, as well as a 'harsh', or high contaminant, gas. Two of the four sites for the OFFGASES project were idle wells that were shut in because of a lack of viable solutions for the stranded noncommercial gas that they produced. Converting stranded gas to useable electrical energy eliminates a waste stream that has potential negative environmental impacts to the oil production operation. The electricity produced will offset that which normally would be purchased from an electric utility, potentially lowering operating costs and extending the economic life of the oil wells. Of the piloted sites, the most promising technologies to handle the range were microturbines that have very low emissions. One recently developed product, the Flex-Microturbine, has the potential to handle the entire range of oilfield gases. It is deployed at an oilfield near Santa Barbara to run on waste gas that is only 4% the strength of natural gas. The cost of producing oil is to a large extent the cost of electric power used to extract and deliver the oil. Researchers have identified stranded and flared gas in California that could generate 400 megawatts of power, and believe that there is at least an additional 2,000 megawatts that have not been identified. Since California accounts for about 14.5% of the total domestic oil production, it is reasonable to assume that about 16,500 megawatts could be generated throughout the United States. This power could restore the cost-effectiveness of thousands of oil wells, increasing oil production by millions of barrels a year, while reducing emissions and greenhouse gas emissions by burning the gas in clean distributed generators rather than flaring or venting the stranded gases. Most turbines and engines are designed for standardized, high-quality gas. However, emerging technologies such as microturbines have increased the options for a broader range of fuels. By demonstrating practical means to consume the four gas streams, the project showed that any gases whose properties are between the extreme conditions also could be utilized. The economics of doing so depends on factors such as the value of additional oil recovered, the price of electricity produced, and the alternate costs to dispose of stranded gas.

  2. Nuclear Tools For Oilfield Logging-While-Drilling Applications

    SciTech Connect (OSTI)

    Reijonen, Jani [Schlumberger PTC, 20 Wallace Rd., Princeton Junction, NJ 08550 (United States)

    2011-06-01T23:59:59.000Z

    Schlumberger is an international oilfield service company with nearly 80,000 employees of 140 nationalities, operating globally in 80 countries. As a market leader in oilfield services, Schlumberger has developed a suite of technologies to assess the downhole environment, including, among others, electromagnetic, seismic, chemical, and nuclear measurements. In the past 10 years there has been a radical shift in the oilfield service industry from traditional wireline measurements to logging-while-drilling (LWD) analysis. For LWD measurements, the analysis is performed and the instruments are operated while the borehole is being drilled. The high temperature, high shock, and extreme vibration environment of LWD imposes stringent requirements for the devices used in these applications. This has a significant impact on the design of the components and subcomponents of a downhole tool. Another significant change in the past few years for nuclear-based oilwell logging tools is the desire to replace the sealed radioisotope sources with active, electronic ones. These active radiation sources provide great benefits compared to the isotopic sources, ranging from handling and safety to nonproliferation and well contamination issues. The challenge is to develop electronic generators that have a high degree of reliability for the entire lifetime of a downhole tool. LWD tool testing and operations are highlighted with particular emphasis on electronic radiation sources and nuclear detectors for the downhole environment.

  3. Applications of geographic information systems (GIS) in decision analysis for monitoring aquifer systems during oilfield development projects

    SciTech Connect (OSTI)

    Blundell, S.; Baldwin, D.O.; Anderson, N.J. [Integrated Geoscience, Inc., Helena, MT (United States)

    1996-06-01T23:59:59.000Z

    Geographic Information Systems (GIS) coupled with numerical ground water models provide a powerful Decision Support System (DSS) and visualization tool for monitoring aquifer systems during oilfield development projects. A GIS is a coupled software/hardware system that stores, processes, and displays a variety of data structures (raster, vector, TIN, CAD) that have been geographically referenced to some common map projection and coordinate system. Georeferencing allows the analyst to integrate diverse types of data layers into thematic maps for analysis of spatial trends and analyses. The integration of quasi 3-D numerical ground water models with GIS provides project managers with a Decision Support System (DSS) to assess potential impacts to aquifer systems during oilfield development projects. The rapid advancement in desktop PC computing power and data storage has allowed software developers to produce 32-bit GIS and data integration software applications. A variety of image processing, GIS, and numerical ground water modeling software will be used to demonstrate techniques for monitoring and visualizing the migration of an oilfield brine plume leaking during an oilfield development project. Emphasis will be placed on the integration of data structures and on database design to create a DSS within a desktop GIS to serve Project Managers during oilfield development.

  4. Repassivation of 13% Cr steel dependent on brine pH

    SciTech Connect (OSTI)

    Skogsberg, J.W.; Walker, M.L.

    2000-02-01T23:59:59.000Z

    A joint laboratory project, involving an oil production and oil well service company, investigated repassivation of martensitic 13% Cr steel. The rate at which this alloy is repassivated after losing its protective passive oxide layer to hydrochloric acid (HCI) depended on the pH of the spent acid returns. Test samples of 13% Cr cut from oilfield tubing were subjected to a fluid sequence of (1) initial brine, (2) HCI, (3) spent acid, and (4) final brine. In 9 days, the samples regained their passive oxide layers. When spent acid was taken out of the fluid sequence, the samples regained passive oxide layers in 3 days.

  5. Rocky Mountain Oilfield Testing Center RMOTC at the Naval Petroleum...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    OILFIELD TESTING OILFIELD TESTING CENTER CENTER 2 2 HISTORY OF TEAPOT DOME Mark Milliken 3 3 TEAPOT DOME LOCATION 4 4 Salt Creek 670 MMBBLS 722 BCF Teapot Dome 27 MMBBLS 57 BCF N P...

  6. Portable brine evaporator unit, process, and system

    DOE Patents [OSTI]

    Hart, Paul John (Indiana, PA); Miller, Bruce G. (State College, PA); Wincek, Ronald T. (State College, PA); Decker, Glenn E. (Bellefonte, PA); Johnson, David K. (Port Matilda, PA)

    2009-04-07T23:59:59.000Z

    The present invention discloses a comprehensive, efficient, and cost effective portable evaporator unit, method, and system for the treatment of brine. The evaporator unit, method, and system require a pretreatment process that removes heavy metals, crude oil, and other contaminates in preparation for the evaporator unit. The pretreatment and the evaporator unit, method, and system process metals and brine at the site where they are generated (the well site). Thus, saving significant money to producers who can avoid present and future increases in transportation costs.

  7. Multistage Stochastic Programming Approach for Offshore Oilfield Infrastructure Planning

    E-Print Network [OSTI]

    Grossmann, Ignacio E.

    Multistage Stochastic Programming Approach for Offshore Oilfield Infrastructure Planning under is implemented in the GAMS grid computing environment. Computational results on a variety of oilfield development cycle of a typical offshore oilfield project consists of the following five steps: (1) Exploration

  8. Offshore Oilfield Development Planning under Uncertainty and Fiscal Considerations

    E-Print Network [OSTI]

    Grossmann, Ignacio E.

    1 Offshore Oilfield Development Planning under Uncertainty and Fiscal Considerations Vijay Gupta1 of oilfields in remote locations that are often hundreds of miles offshore. Surprisingly, there has been a net by the terms of the contract between oil companies and governments. Figure 1: A unified framework for Oilfield

  9. Risk assessment of nonhazardous oil-field waste disposal in salt caverns.

    SciTech Connect (OSTI)

    Elcock, D.

    1998-03-05T23:59:59.000Z

    In 1996, Argonne National Laboratory (ANL) conducted a preliminary technical and legal evaluation of disposing of nonhazardous oil-field wastes (NOW) into salt caverns. Argonne determined that if caverns are sited and designed well, operated carefully, closed properly, and monitored routinely, they could be suitable for disposing of oil-field wastes. On the basis of these findings, Argonne subsequently conducted a preliminary evaluation of the possibility that adverse human health effects (carcinogenic and noncarcinogenic) could result from exposure to contaminants released from the NOW disposed of in domal salt caverns. Steps used in this evaluation included the following: identifying potential contaminants of concern, determining how humans could be exposed to these contaminants, assessing contaminant toxicities, estimating contaminant intakes, and calculating human cancer and noncancer risk estimates. Five postclosure cavern release scenarios were assessed. These were inadvertent cavern intrusion, failure of the cavern seal, failure of the cavern through cracks, failure of the cavern through leaky interbeds, and a partial collapse of the cavern roof. Assuming a single, generic, salt cavern and generic oil-field wastes, potential human health effects associated with constituent hazardous substances (arsenic, benzene, cadmium, and chromium) were assessed under each of these scenarios. Preliminary results provided excess cancer risk and hazard index (referring to noncancer health effects) estimates that were well within the US Environmental Protection Agency (EPA) target range for acceptable exposure risk levels. These results led to the preliminary conclusion that from a human health perspective, salt caverns can provide an acceptable disposal method for nonhazardous oil-field wastes.

  10. Difunctional carboxylic acid anions in oilfield waters

    SciTech Connect (OSTI)

    MacGowan, D.B.; Surdam, R.C.

    1988-01-01T23:59:59.000Z

    Recent models of porosity enhancement during sandstone diagenesis have called upon the metal complexing ability of difunctional carboxylic acid anions in subsurface waters to explain aluminosilicate dissolution. Although carboxylic acid anions have been known to exist in oilfield waters since the turn of the century, until now the existence of significant concentrations of difunctional carboxylic acid anions has not been documented. Data from this study show that difunctional carboxylic acid anions can exist in concentrations up to 2640 ppm, and can account for nearly 100% of the organic acid anions in some oilfield waters. Formation water samples with exceptionally high concentrations of difunctional carboxylic acid anions are found in reservoirs which are at maximum levels of thermal exposure, and which are presently in the 80-100/sup 0/C thermal window. Plagioclase dissolution experiments performed with natural oilfield waters and artificial solutions indicate that waters with high difunctional acid anion concentrations are capable, by organo-metallic complexation, of being apparently oversaturated with respect to total aluminum concentrations compared to the inorganic solubility of kaolinite by several orders of magnitude. Dissolution experiments simulating a specific geologic environment (Stevens Sandstone, southern San Joaquin Basin, California; using natural oilfield waters and Stevens Sandstone core samples), produced plagioclase and calcite dissolution textures similar to those noted in well cores from the Stevens Sandstone, as well as raising total aluminum concentrations in these experimental solutions several orders of magnitude over the solubility of kaolinite.

  11. An Iterative Aggregation/Disaggregation Approach for the Solution of a Mixed Integer Nonlinear Oilfield

    E-Print Network [OSTI]

    Grossmann, Ignacio E.

    Oilfield Infrastructure Planning Model Susara A. van den Heever* and Ignacio E. Grossmann** Department of Chemical Engineering, Carnegie Mellon University Pittsburgh, PA, 15213 August 1999 Keywords Oilfield planning, MINLP, aggregation, decomposition Abstract A multiperiod MINLP model for offshore oilfield

  12. Biochemical processes for geothermal brine treatment

    SciTech Connect (OSTI)

    Premuzic, E.T.; Lin, M.S.; Bohenek, M.; Joshi-Tope, G.; Zhou, W.; Shelenkova, L.; Wilke, R.

    1998-08-01T23:59:59.000Z

    As part of the DOE Geothermal Energy Program, BNL`s Advanced Biochemical Processes for Geothermal Brines (ABPGB) project is aimed at the development of cost-efficient and environmentally acceptable technologies for the disposal of geothermal wastes. Extensive chemical studies of high and low salinity brines and precipitates have indicated that in addition to trace quantities of regulated substances, e.g., toxic metals such as arsenic and mercury, there are significant concentrations of valuable metals, including gold, silver and platinum. Further chemical and physical studies of the silica product have also shown that the produced silica is a valuable material with commercial potential. A combined biochemical and chemical technology is being developed which (1) solubilizes, separates, and removes environmentally regulated constituents in geothermal precipitates and brines, (2) generates an amorphous silica product which may be used as feedstock for the production of revenue generating materials, (3) recover economically valuable trace metals and salts. Geothermal power resources which utilize low salinity brines and use the Stretford process for hydrogen sulfide abatement generate a contaminated sulfur cake. Combined technology converts such sulfur to a commercial grade sulfur, suitable for agricultural use. The R and D activities at BNL are conducted jointly with industrial parties in an effort focused on field applications.

  13. BIOCHEMICAL PROCESSES FOR GEOTHERMAL BRINE TREATMENT

    SciTech Connect (OSTI)

    PREMUZIC,E.T.; LIN,M.S.; BOHENEK,M.; JOSHI-TOPE,G.; ZHOU,W.; SHELENKOVA,L.; WILKE,R.

    1998-09-20T23:59:59.000Z

    As part of the DOE Geothermal Energy Program, BNL's Advanced Biochemical Processes for Geothermal Brines (ABPGB) project is aimed at the development of cost-efficient and environmentally acceptable technologies for the disposal of geothermal wastes. Extensive chemical studies of high and low salinity brines and precipitates have indicated that in addition to trace quantities of regulated substances, e.g., toxic metals such as arsenic and mercury, there are significant concentrations of valuable metals, including gold, silver and platinum. Further chemical and physical studies of the silica product have also shown that the produced silica is a valuable material with commercial potential. A combined biochemical and chemical technology is being developed which (1) solubilizes, separates, and removes environmentally regulated constituents in geothermal precipitates and brines (2) generates an amorphous silica product which may be used as feedstock for the production of revenue generating materials, (3) recover economically valuable trace metals and salts. Geothermal power resources which utilize low salinity brines and use the Stretford process for hydrogen sulfide abatement generate a contaminated sulfur cake. Combined technology converts such sulfur to a commercial grade sulfur, suitable for agricultural use. The R and D activities at BNL are conducted jointly with industrial parties in an effort focused on field applications.

  14. analyzing oilfield waters: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Eugene 2005-11-01 34 GEOLOG is an independent and privately owned oilfield services company with a strong track record of growth and international Specialized in Surface...

  15. ROCKY MOUNTAIN OILFIELD TESTING CENTER PROJECT TEST RESULTS

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    MOUNTAIN OILFIELD TESTING CENTER MAG-WELL DOWNHOLE MAGNETIC FLUID CONDITIONERS PROJECT TEST RESULTES Prepared for: Industry Publication Prepared by: MICHAEL R. TYLER RMOTC Field...

  16. ROCKY MOUNTAIN OILFIELD TESTING CENTER PROJECT TEST RESULTS

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    JANUARY 27, 1998 Report No. RMOTC97PT22 ROCKY MOUNTAIN OILFIELD TESTING CENTER PROJECT TEST RESULTS PETRO-PLUG BENTONITE PLUGGING Prepared for: INDUSTRY PUBLICATION Prepared by:...

  17. ROCKY MOUNTAIN OILFIELD TESTING CENTER PROJECT TEST RESULTS

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    FEBRUARY 19, 1997 FC9532 95EC1 ROCKY MOUNTAIN OILFIELD TESTING CENTER AJUST A PUMP TEST Rosemond Manufacturing, Inc. (RMI) Prepared for: INDUSTRY PUBLICATION Prepared by:...

  18. Using artificial neural networks to predict the quality and performance of oilfield cements

    SciTech Connect (OSTI)

    Coveney, P.V.; Hughes, T.L. [Schlumberger Cambridge Research Ltd., Cambridge (United Kingdom); Fletcher, P. [Schlumberger Dowell, Skene, Aberdeen (United Kingdom)

    1996-12-31T23:59:59.000Z

    Inherent batch to batch variability, ageing and contamination are major factors contributing to variability in oilfield cement slurry performance. Of particular concern are problems encountered when a slurry is formulated with one cement sample and used with a batch having different properties. Such variability imposes a heavy burden on performance testing and is often a major factor in operational failure. We describe methods which allow the identification, characterization and prediction of the variability of oilfield cements. Our approach involves predicting cement compositions, particle size distributions and thickening time curves from the diffuse reflectance infrared Fourier transform spectrum of neat cement powders. Predictions make use of artificial neural networks. Slurry formulation thickening times can be predicted with uncertainties of less than {+-}10%. Composition and particle size distributions can be predicted with uncertainties a little greater than measurement error but general trends and differences between cements can be determined reliably. Our research shows that many key cement properties are captured within the Fourier transform infrared spectra of cement powders and can be predicted from these spectra using suitable neural network techniques. Several case studies are given to emphasize the use of these techniques which provide the basis for a valuable quality control tool now finding commercial use in the oilfield.

  19. 1989 U. S. A. oilfield service, supply and manufacturers directory

    SciTech Connect (OSTI)

    Not Available

    1989-01-01T23:59:59.000Z

    This book lists and describes principal activities of more than 3,600 companies providing oil-field services, wholesale and retail products, and companies involved in the design, manufacture and construction of oilfield equipment. It gives company address and phone; principal officers; telex, cable, and facsimile numbers; branch offices; and subsidiaries.

  20. Thirty years of fiberglass pipe in oilfield applications: A historical perspective

    SciTech Connect (OSTI)

    Oswald, K.J. [Smith Fiberglass Products Inc., Little Rock, AR (United States)

    1996-05-01T23:59:59.000Z

    A 30-year history of the use of fiberglass piping (FRP) systems for oil production piping is presented. Speculation about future uses of FRP in the oilfields is discussed. Problems encountered during the introduction of this type of pipe to the oilfields, and the evolution of early oilfield FRP systems is described. Improvements in FRP during the period of recent oilfield growth are reported. A representative list of significant uses of FRP in oilfield applications today is presented.

  1. High performance phenolic piping for oilfield applications

    SciTech Connect (OSTI)

    Folkers, J.L. [Ameron International, Burkburnett, TX (United States); Friedrich, R.S.; Fortune, M. [Ameron International, South Gate, CA (United States)

    1997-08-01T23:59:59.000Z

    The performance advantages of phenolic resins have been enticing for composites manufacturers and users for many years. The use of these materials has been limited, however, by the process, handling and assembly difficulties they present. This paper introduces an innovative modification which has allowed the development of a filament wound piping system for oilfield applications which previously had been beyond the performance envelope of fiberglass pipe. Improvement in temperature resistance and response to steam exposure, as compared to conventional epoxy products, are of particular benefit. Fabrication innovations are also included which can be used where impact resistance or fire performance are needed.

  2. Oilfield rock bits: Are they a commodity

    SciTech Connect (OSTI)

    Caldwell, R.

    1994-05-01T23:59:59.000Z

    This paper discusses the quality of various types of rock drill bits and evaluates cost of these bits against service and performance to determine if bits should be viewed as a commodity when drilling a production or exploration well. Continuing advancements in materials technology, machining capabilities, hydraulics arrangements, bearing configuration, seal technology and cutter design continue to push the performance curve for oilfield rock bits. However, some very important advancements are patented, proprietary features of individual manufacturers. This paper reviews some of these design and performance features to help determine if they are worth the extra investment based on actual field drilling experience.

  3. New Energy Efficient Method for Cleaning Oilfield Brines with Carbon Dioxide

    E-Print Network [OSTI]

    Little, C. T.; Seibert, A. F.; Bravo, J. L.; Fair, J. R.

    pressure. The important discoveries of this study and an economic comparison of the carbon dioxide treatment process with other potential processes are presented in this paper. INTRODUCTION During the operation of producing petroleum from subsurface... studies (1,2,3). The most comprehensive work regarding the environmental effects of these aqueous effluents was studied by Middleditch and coworkers (4,5). The current U.S. Environmental Protection Agency limits for organics in aqueous discharges...

  4. Analysis of hydrocarbon removal methods for the management of oilfield brines and produced waters

    E-Print Network [OSTI]

    Furrow, Brendan Eugene

    2005-11-01T23:59:59.000Z

    According to the Texas Railroad Commission (TRC), ????over 250 billion gallons of produced water is taken out of Texas Soil every year, and more than 35% of this water is not currently fit to use.?? Therefore, it can be assumed that domestically...

  5. Oil and gas: Oilfield class actions

    SciTech Connect (OSTI)

    McArthur, J.B.

    1997-06-01T23:59:59.000Z

    The use of class actions is getting alot of attention in the oilfield. Plaintiffs have filed class actions challenging two of the most rooted industry practices, oil posted prices and deregulated natural gas affiliate deduction and charges. The classes will include tens or hundreds of thousands of plaintiffs and may transform two of the industry`s most settled practices. The emotions surrounding the class action risk obscuring the fact that it is an old and oft-used tool in oilfield litigation. The class action {open_quotes}provides a means by which, where a large group of persons are interested in a matter, one or more may sue or be sued as representatives of the class without needing to join every member of the class.{close_quotes} The procedure avoids waste by combining scattered disputes, even if some injured might sue individually, and it enables plaintiffs who could not afford to sue to be represented anyway. The lawyers draw their fees from any recovery. Almost all oilpatch class actions are brought to resolve a {open_quotes}common question{close_quotes} under Federal Rules of Civil Procedure 23(b)(3) or state counterparts. The rule`s {open_quotes}opt-out{close_quotes} provisions give class actions a tremendous boost because members stay in unless they take steps to get out. This article discusses present and future class actions.

  6. Emergency preparedness for the small oilfield contractor

    SciTech Connect (OSTI)

    Reavis, H.C.

    1995-12-01T23:59:59.000Z

    Changes in the oil and gas industry have been dramatic in recent years. Operators have consolidated field office facilities and downsized staffing at many of their remaining facilities. As a result, operators are turning to independent Contractors as a method of controlling both peak personnel demands and selected production functions. With these changes in the business environment, the role of the specialized contractor has been greatly expanded. Tasks Diane performed by operator employees are now ongoing services provided by the contractor. Their performance can Taken be exemplary until a major emergency occurs. Emergency response can no longer be considered a secondary issue. Every contractor, small or large, must be equally prepared for an emergency. Their ability to address emergency incidents will have a direct effect in their success. This paper is a presentation of the actual learning experiences of one oilfield contractor confronted with the ask of emergency preparedness, more specifically a small contractor. Oilfield service contractors commonly employ field personnel who work for extended periods of time without direct supervision. These employees may singularly or collectively float between sites or anchor one site. Operating sites might be localized or spread over a vast geographical area. Because of the uniqueness of their situation, direct supervision is minimal and the employees will shoulder greater responsibilities and authority. The contractor must evaluate operating conditions and develop an approach which will achieve the optimum results.

  7. A test program for the evaluation of oilfield thread protectors

    SciTech Connect (OSTI)

    Dale, B.A.; Moyer, M.C.; Sampson, T.W.

    1985-02-01T23:59:59.000Z

    Transportation, handling, and corrosion damage to the threads of oilfield tubulars cost the industry millions of dollars each year. This problem has intensified with the increased use of proprietary connections, which represent a significant percentage of the total tubular cost. The thread protector is the primary means of protecting the threads from impact and corrosion damage. A test program has been designed and a test facility built. To evaluate the performance of oilfield protectors, a wide variety of thread protectors were tested, including metal, plastic, and composite (metal-elastomer) designs. This paper discusses this testing and outlines a guide for the selection of oilfield thread protectors for various service conditions.

  8. ROCKY MOUNTAIN OILFIELD TESTING CENTER PROJECT TEST RESULTS

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    IN-SITU H 2 S BIOREMEDIATION JULY 11, 1994 FC9509 95PT3 Rocky Mountain Oilfield Testing Center 907 North Poplar, Suite 100, Casper, WY 82601 (307) 261-5000, ext. 5060; FAX (307)...

  9. ROCKY MOUNTAIN OILFIELD TESTING CENTER PROJECT TEST RESULTS

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    OILWELL POWER CONTROLLER JULY 26, 1994 FC9501 94PT1 ROCKY MOUNTAIN OILFIELD TESTING CENTER RMOTC TEST RESULTS OF OILWELL POWER CONTROLLER July 26,1994 MICHAEL R. TYLER FIELD...

  10. ROCKY MOUNTAIN OILFIELD TESTING CENTER PROJECT TEST RESULTS

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    82601 1994 RMOTC ('107) 261-5000, ext. 5060 RESULTS OF THE V-GER LUBRICATOR SYSTEM TEST AT THE ROCKY MOUNTAIN OILFIELD TESTING CENTER (RMOTC) Michael Tyler, Marvin Hendricks,...

  11. ROCKY MOUNTAIN OILFIELD TESTING CENTER PROJECT TEST RESULTS

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    FC9510 95PT4 ROCKY MOUNTAIN OILFIELD TESTING CENTER D-JAX PUMP-OFF CONTROLLER PROJECT TEST RESULTES Prepared for: Industry Publication Prepared by: MICHAEL R. TYLER RMOTC Field...

  12. Corrosion monitoring with hydrogen probes in the oilfield

    SciTech Connect (OSTI)

    Thomason, W.H.

    1984-05-01T23:59:59.000Z

    An overview of the application of hydrogen probes for corrosion monitoring in the oilfield is presented. The three basic types of hydrogen probes are described and their relative merits discussed. The construction and installation of a simple and inexpensive electrochemical hydrogen probe is described. Experiences with hydrogen probes in oilfield operations are discussed, and it is concluded from these experiences that production systems where hydrogen probes can provide useful corrosion data are limited.

  13. Environmental impact assessment of the Dulang oilfield development project

    SciTech Connect (OSTI)

    Hasan, M.N. (U. Kebangsaan Malaysia (MY)); (Ismail, M.Y. (Petronas Cangali Sdn. Bhd. (MY)))

    1988-01-01T23:59:59.000Z

    The authors discuss an environmental impact assessment (EIA) of the Dulang Oilfield Development Project, conducted to determine whether the project could proceed in a safe and environmentally acceptable manner. This is the first EIA for an offshore oilfield in Malaysian waters, and was conducted in anticipation of the Environmental Quality (Prescribed Activities) (Environmental Impact Assessment Order(1987)) which requires an EIA to be conducted for major oil and gas field development projects.

  14. Environmental effects of oilfield chemicals on composite

    SciTech Connect (OSTI)

    Sorem, R.M. [Univ. of Kansas, Lawrence, KS (United States). Dept. of Mechanical Engineering

    1998-12-31T23:59:59.000Z

    This paper presents a feasibility study of the effects of oilfield chemicals on composite materials. In this initial study only hydrochloric acid is considered. Initial attempts were made to test stressed specimens, but results were very poor. Subsequent testing was performed to determine how the composite material constituents reacted to the hydrochloric acid. The initial testing was performed on tubular specimens with axial and essentially hoop wound fibers of different materials with different resins. The specimens were loaded in bending to induce representative strains in the tubing. All specimens failed. The second tests consisted of only an environmental soak to determine the amount of mass uptake as well as the reduction in strength. The strength reduction results will be presented at a later time. Testing was performed on S-2 glass, carbon and Kevlar 49 as well as three different resins.

  15. Workflow Instance Detection: Toward A Knowledge Capture Methodology for Smart Oilfields

    E-Print Network [OSTI]

    Prasanna, Viktor K.

    Workflow Instance Detection: Toward A Knowledge Capture Methodology for Smart Oilfields Fan Sun, and act as a knowledge base to assist with troubleshooting and training new employees. A smart oilfield

  16. A MANUAL FOR CATALOGING and INDEXING DOCUMENTS FOR DATABASE ACQUISITION

    E-Print Network [OSTI]

    Schwartz, S.R.

    2010-01-01T23:59:59.000Z

    · INJECTION ~LLS·LEGAL ASPECTS·OILFIELD BRINES·PERMEABILITY·ASPECTS; DE.14 = OILFIELD BRINES; DE.15 = PERMEABILITY;

  17. History of the development of the Wilmington oilfield and its EOR projects

    SciTech Connect (OSTI)

    Colazas, X.C. [City of Long Beach, CA (United States)

    1994-12-31T23:59:59.000Z

    The City of Long Beach sits atop one of the largest oil fields in the world, the Wilmington Oilfield. Four areas are described: historical development of the Wilmington Oilfield, the environmental problem of subsidence, the present development and future plans for the Wilmington Oilfield including the EOR projects, and the projects about to be undertaken.

  18. SPE 159835-PP Event-driven Information Integration for the Digital Oilfield

    E-Print Network [OSTI]

    Prasanna, Viktor K.

    SPE 159835-PP Event-driven Information Integration for the Digital Oilfield Om Prasad Patri facilitate components of the oilfield to communicate in real-time across different software platforms. Consider a typical application scenario - a pump failure event in an oilfield, which should elicit response

  19. A Semantic Framework for Integrated Asset Management in Smart Oilfields Ramakrishna Soma

    E-Print Network [OSTI]

    Hwang, Kai

    A Semantic Framework for Integrated Asset Management in Smart Oilfields Ramakrishna Soma Department transformation of oilfield operations where infor- mation integration from a variety of tools for reservoir mod to be portable across oilfield assets, to allow different classes of end users to interact with the integrated

  20. Comparison study of solid/liquid separation techniques for oilfield pit closures

    SciTech Connect (OSTI)

    Wojtanowicz, A.K.; Field, S.D.; Osterman, M.C.

    1987-07-01T23:59:59.000Z

    Vacuum filtration, belt-press filtration, screw-press filtration, and centrifuging techniques were evaluated in full-scale experiments for use in oilfield waste volume reduction. Centrifuging and belt-press filtration proved applicable to oilfield pit cleanups. Also, an effective chemical conditioning (coagulation and flocculation) was found for deliquoring seven types of oilfield waste slurries before separation.

  1. * Author currently at Chevron Corp., Houston, TX, USA Intelligent model management and Visualization for smart oilfields

    E-Print Network [OSTI]

    Prasanna, Viktor K.

    and Visualization for smart oilfields Charalampos Chelmis 1 , Amol Bakshi 3* , Burcu Seren 2 , Karthik Gomadam 3 of SPE copyright. Abstract Simulation models are commonly used as an aid to decision making for oilfield. As the composition of the engineering team changes over the lifetime of the oilfield and new modeling requirements

  2. CHEMISTRY OF SILICA IN CERRO PRIETO BRINES

    E-Print Network [OSTI]

    Weres, O.

    2012-01-01T23:59:59.000Z

    chemistry of silica in Cerro Prieto brine may profitably be14 mg·l-1 AND SYNTHFTIC CERRO PRIETO BRINES High Ca We112Q.by the CFE Laboratory at Cerro Prieto and kindly provided to

  3. Brining studies at Pepper Products Inc.

    E-Print Network [OSTI]

    Okoro, John Daniel

    1988-01-01T23:59:59.000Z

    of Department) A. B. Childers (Member) V. E. Sweat (Member) December 1988 Abstract Optimum brining conditions, causes of secondary fermentation, and salt fluctuation were investigated. Jalapeno peppers held in brine solution undergo lactic acid... fermentation, controlled by level of acidification and concentration of salt. Only brining at 7. 5% NaCl, with no added acetic acid, resulted in loss of all fermentable sugars. However, salt concentration fluctuated widely in this sample. Brining in 25...

  4. Modeling gas and brine migration for assessing compliance of the Waste Isolation Pilot Plant

    SciTech Connect (OSTI)

    Vaughn, P. [Applied Physics, Inc., Albuquerque, NM (United States); Butcher, B. [Sandia National Labs., Albuquerque, NM (United States); Helton, J. [Arizona State Univ., Tempe, AZ (United States); Swift, P. [Tech. Reps., Inc., Albuquerque, NM (United States)

    1993-10-01T23:59:59.000Z

    At the request of the WIPP Project Integration Office (WPIO) of the DOE, the WIPP Performance Assessment (PA) Department of Sandia National Laboratories (SNL) has completed preliminary uncertainty and sensitivity analyses of gas and brine migration away from the undisturbed repository. This paper contains descriptions of the numerical model and simulations, including model geometries and parameter values, and a summary of major conclusions from sensitivity analyses. Because significant transport of contaminants can only occur in a fluid (gas or brine) medium, two-phase flow modeling can provide an estimate of the distance to which contaminants can migrate. Migration of gas or brine beyond the RCRA ``disposal-unit boundary`` or the Standard`s accessible environment constitutes a potential, but not certain, violation and may require additional evaluations of contaminant concentrations.

  5. Proceedings of the 1991 SPE international symposium on oilfield chemistry

    SciTech Connect (OSTI)

    Not Available

    1991-01-01T23:59:59.000Z

    This book contains the proceedings of the 1991 SPE Symposium in Oilfield Chemistry. Included are the following papers: Extended analysis of live reservoir oils by gas chromatography, The effect of hydroxy aluminum disoaps on the viscosity of light alkanes and carbon dioxide, Field application of laboratory friction pressure correlations for borate crosslinked fluids.

  6. Simulation system provides unique training method for the oilfield

    SciTech Connect (OSTI)

    Beck, K. [Halliburton Energy Service, Dallas, TX (United States). Dallas Technology Center; Schwendemann, K. [Halliburton Energy Service, Carrollton, TX (United States). Dallas/Fort Worth Technology Center

    1997-02-01T23:59:59.000Z

    Integrated services and turnkey operations are becoming the norm for the industry, and oilfield service companies are finding themselves linked with operators and contractors in long-term service contracts that would never have been considered in the 1980`s. In this paper, the authors discuss a unique simulator that can resolve the training needs that have surfaced as a result of the rapidly changing operational concepts in the oilfield environment. They will present the concepts of the equipment simulator and capabilities of the global simulator methodology, and they will use an actual case history to describe in detail how the equipment simulator was used offshore on a recent well-test job in the Gulf Coast area to introduce a new well-test tool and to train a new design engineer. With this information, the authors conclude that the use of the simulator will provide unparalleled training support for oilfield equipment and system applications and facilitate efficient development of integrated solutions for oilfield projects.

  7. A new method of coating oilfield core for laboratory studies

    SciTech Connect (OSTI)

    Menzie, D.E.; Dutta, S.; Shadizadeh, R.S.

    1988-05-01T23:59:59.000Z

    A new method has been developed for coating oilfield core for laboratory studies. It consists of applying a steel coating and aluminum wraps around the outer surface of a core. The strength of the coating, the short time needed to apply it, and its low cost are the major advantages of this new method.

  8. A contingency plan helps companies prepare for oilfield, pipeline spills

    SciTech Connect (OSTI)

    Duey, R.

    1996-02-01T23:59:59.000Z

    There are many hazards associated with oilfield, pipeline spills such as fires, litigation, fines, etc. Operators and companies need to have a plan in place and make sure their employees know what to do when disaster strikes. This paper describes emergency preparedness plans.

  9. New oilfield air bit improves drilling economics in Appalachian Basin

    SciTech Connect (OSTI)

    Brannon, K.C.; Grimes, R.E. [Hughes Christensen Co., Houston, TX (United States); Vietmeier, W.R. [Hughes Christensen Co., Imperial, PA (United States)

    1994-12-31T23:59:59.000Z

    Petroleum exploration in the Appalachian Basin of the northeastern United States has traditionally relied on compressed air, rather than drilling fluid, for its circulating medium. When compared to drilling mud, compressed air provides such advantages as increased rates of penetration, longer bit life, decreased formation damage, no lost circulation and saves the expense associated with mud handling equipment. Throughout the 1970s and early 1980s, roller cone mining bits and surplus oilfield bits were used to drill these wells. While the cutting structures of mining bits were well-suited for air drilling, the open roller bearings invariably shortened the useful life of the bit, particularly when water was present in the hole. This paper will highlight the development of a new IADC Class 539Y oilfield roller cone bit that is establishing performance records in air drilling applications throughout the Appalachian Basin. Essentially, the latest generation evolved from a roller cone bit successfully introduced in 1985 that combined a specialized non-offset cutting structure with a premium oilfield journal bearing package. Since its introduction, several sizes and types of oilfield air bits have been developed that have continually decreased drilling costs through enhanced performance and reliability. The design and evolution of rock bit cutting structures and bearing packages for high-performance oilfield air drilling applications will be detailed. Laboratory drilling test data will demonstrate the difference in drilling efficiencies between air drilling and conventional fluid drilling. Case studies taken from throughout the Appalachian Basin will be presented to illustrate the improvements in cost per foot, penetration rate, total footage drilled, drilling hours, and bit dull grades.

  10. Improved Water Flooding through Injection Brine Modification

    SciTech Connect (OSTI)

    Robertson, Eric Partridge; Thomas, Charles Phillip; Morrow, Norman; (U of Wyoming)

    2003-01-01T23:59:59.000Z

    Crude oil/brine/rock interactions can lead to large variations in the displacement efficiency of waterflooding, by far the most widely applied method of improved oil recovery. Laboratory waterflood tests show that injection of dilute brine can increase oil recovery. Numerous fields in the Powder River basin have been waterflooded using low salinity brine (about 500 ppm) from the Madison limestone or Fox Hills sandstone. Although many uncertainties arise in the interpretation and comparison of field production data, injection of low salinity brine appears to give higher recovery compared to brine of moderate salinity (about 7,000 ppm). Laboratory studies of the effect of brine composition on oil recovery cover a wide range of rock types and crude oils. Oil recovery increases using low salinity brine as the injection water ranged from a low of no notable increase to as much as 37.0% depending on the system being studied. Recovery increases using low salinity brine after establishing residual oil saturation (tertiary mode) ranged from no significant increase to 6.0%. Tests with two sets of reservoir cores and crude oil indicated slight improvement in recovery for low salinity brine. Crude oil type and rock type (particularly the presence and distribution of kaolinite) both play a dominant role in the effect that brine composition has on waterflood oil recovery.

  11. Development Operations Hypersaline Geothermal Brine Utilization...

    Open Energy Info (EERE)

    Hypersaline Geothermal Brine Utilization Imperial County, California Jump to: navigation, search OpenEI Reference LibraryAdd to library Report: Development Operations Hypersaline...

  12. Chemistry of Silica in Cerro Prieto Brines

    E-Print Network [OSTI]

    Weres, Oleh

    2012-01-01T23:59:59.000Z

    LBL-10166 CERRO-PRIETO-12 XICAN-AMERICANCOOPERATIVE' PROGRAM T THE CERRO PRIETO GEOTHERMAL FIELD ICHEMISTRY OF SILICA IN CERRO PRIETO BRINES Oleh Weres Leon

  13. Chemistry of Silica in Cerro Prieto Brines

    E-Print Network [OSTI]

    Weres, O.

    2010-01-01T23:59:59.000Z

    LBL-10166 CERRO-PRIETO-12 XICAN-AMERICANCOOPERATIVE' PROGRAM T THE CERRO PRIETO GEOTHERMAL FIELD ICHEMISTRY OF SILICA IN CERRO PRIETO BRINES Oleh Weres Leon

  14. Evaluation of oilfield corrosion inhibitors by electrochemical impedance spectroscopy (EIS)

    SciTech Connect (OSTI)

    Chen, H.J. [Chevron Petroleum Technology Co., La Habra, CA (United States)

    1994-12-31T23:59:59.000Z

    The performance of commercially available oilfield corrosion inhibitors has been evaluated by electrochemical impedance spectroscopy (EIS) in CO{sub 2} saturated 5% sodium chloride solution. The results demonstrate that EIS is a feasible method for ranking oilfield corrosion inhibitor performance, and the inhibitors exhibit inhibition through different mechanisms. EIS can provide information on the inhibited film growth, and generate the parameters which are specific to a particular corrosion inhibition system. It is found that the high breakpoint frequency at 45{degree} phase angle has excellent correlation with the corrosion rate in the inhibited system. The identification of this correlation is significant because there are advantages associated with measuring this parameter. A patent application has been filed for this discovery.

  15. Monitoring microbial corrosion in large oilfield water systems

    SciTech Connect (OSTI)

    Chen, E.Y.; Chen, R.B.

    1983-03-01T23:59:59.000Z

    Monitoring of microbial corrosion is always difficult because of the sessile nature of bacteria and the lack of meaningful correlation between routine bacteria counts and bacterial activity. This problem is further aggravated in a large oilfield water system because of its size and sampling difficulties. This paper discusses some monitoring techniques currently used in the oil industry, their limitations and the possible areas for improvement. These suggested improvements either are presently being implemented or will be implemented in the Aramco systems.

  16. Monitoring microbial corrosion in large oilfield water systems

    SciTech Connect (OSTI)

    Chen, E.Y.; Chen, R.B.

    1984-07-01T23:59:59.000Z

    Monitoring of microbial corrosion is always difficult because of the sessile nature of bacteria and the lack of meaningful correlation between routine bacteria counts and bacterial activity. This problem is further aggravated in a large oilfield water system because of size and sampling difficulties. This paper discusses some monitoring techniques currently used in the oil industry, their limitations, and possible areas for improvement. These improved techniques are in use or will be implemented in the Aramco systems.

  17. The idea of digital oilfields, i.e., with unmanned exploration unities, is a strong trend in the oil & gas

    E-Print Network [OSTI]

    Barbosa, Alberto

    Abstract The idea of digital oilfields, i.e., with unmanned exploration unities, is a strong trend oilfields is roughly an interplay of several technologies that provides resources for gathering raw data

  18. THE MECHANISM OF INTRAGRANULAR MIGRATION OF BRINE INCLUSIONS IN SALT

    E-Print Network [OSTI]

    Machiels, A.J.

    2010-01-01T23:59:59.000Z

    of Brine Inclusions in a Salt Repository", ORM. -5526 (JulyOF BRINE INCLUSIONS IN SALT A.J. Machiels, S. Yagnik, D.R.OF BRINE INCLUSIONS IN SALT by A.J. Machiels S. Yagnik D.R.

  19. Towards a Model-based Application Integration Framework for Smart Oilfields Cong Zhang, Amol Bakshi, Viktor Prasanna

    E-Print Network [OSTI]

    Prasanna, Viktor K.

    Towards a Model-based Application Integration Framework for Smart Oilfields Cong Zhang, Amol Bakshi- duction has led to an industry-wide push to develop smart oilfields for the future. Applications for smart oilfields are characterized with heterogeneous data and resources, com- plicated business processes

  20. Biomass production from inland brines

    SciTech Connect (OSTI)

    Reach, C.D. Jr.

    1985-01-01T23:59:59.000Z

    The feasibility of utilizing inland saline waters to produce biomass through the application of marine aquaculture was investigated. From available data, the diatom Phaeodactylum tricornutum and the crustacea Artemia salina were selected as the experimental marine organisms. The proposed diatom served to establish primary productivity and concurrently provide a food source for the herbivorus crustacea. The objective of the first phase research was to investigate the ability of P. tricornutum and A. salina to survive in the inland saline environment. Clarified activated sludge and anaerobic digester effluents were evaluated as nutrient sources for the diatom cultures. Experimental results indicated that diatom and crustacea growth in the inland brine was equivalent to control cultures utilizing seawater. Wastewater effluents were successful as nutrient sources for the diatom cultures. Bioassay experiments conducted with petroleum related brines yielded mixed results respect to the survival and growth of the P. tricornutum and A. salina organisms. A second series of experiments involved cholornaphthalene, chlorophenanthene, and chlorophenanthrene, and chloroanthracene as the experimental hydrocarbons. Results of the diatom studies show chloroanthracene to induce toxic effects at a concentration of 500 ug/L. Artemia studies showed no acutely toxic effects relative to the test hydrocarbons at 50 and 100 ug/L.

  1. Thirty years of fiberglass pipe in oilfield applications: A historical perspective

    SciTech Connect (OSTI)

    Oswald, K.J. [Smith Fiberglass Products Inc., Little Rock, AR (United States)

    1995-10-01T23:59:59.000Z

    Oilfield piping must handle mixtures containing many fluids which are highly corrosive to metals. Salt water, sour crude, hydrogen sulfide and carbon dioxide are only a few of the corrosives which are handled continuously on a large scale in oilfields throughout the world. This paper presents a 30 year history of the use of fiberglass piping systems to manage corrosion problems in oil production piping, and speculates about future uses of fiberglass piping in the oilfields. A description of the problems encountered during the introduction of this type of pipe to the oilfields is given, and the evolution of early oilfield fiberglass piping systems is described. Improvements in fiberglass piping during the period of recent oilfield growth are reported, and the contributions of fiberglass pipe in the field of corrosion control during this period of growth are discussed. A representative list of significant uses of fiberglass pipe in oilfield applications today is presented, predictions about the future of fiberglass tubular products in oilfield corrosion applications are made.

  2. ORIGINAL ARTICLE On the origin of oil-field water in the Biyang Depression of China

    E-Print Network [OSTI]

    Zhan, Hongbin

    ORIGINAL ARTICLE On the origin of oil-field water in the Biyang Depression of China Yong Fu Æ Springer-Verlag 2008 Abstract We have surveyed groundwater samples col- lected from oil and gas reservoirs of diagenesis of the oil-field water, respectively. The con- centrations of calcium and magnesium ions are found

  3. Simulation system provides unique training method for the oilfield

    SciTech Connect (OSTI)

    Beck, K.; Schwendemann, K.

    1996-12-31T23:59:59.000Z

    Today`s oilfield service environment has undergone significant change from that which existed ten years ago. Integrated services and turnkey operations are becoming the norm for the industry, and oilfield service companies are finding themselves linked with operators and contractors in long-term service contracts that would never have been considered in the 80`s. While these new alliances may prove to be the catalyst for energizing economic growth in the oilfield, they bring with them their own set of operational problems. For example, the integrated solutions approach requires that all parties have a thorough understanding of overall economic and operational project parameters as well as a defined area for which each must take responsibility. Obviously, therefore, to meet the demands of the integrated solutions concept, {open_quotes}the partners{close_quotes} must be able to properly assess all project needs so that the solution provided accomplishes the economic and operational goals for all involved. This means that each must have a detailed technical understanding of a wide variety of equipment, systems and available resources. This is the area in which a major drawback to the integrated solutions concept often occurs - it has been difficult to provide a fast, efficient method to keep users abreast of the continuing enhancements to a technology that already appears to be state-of-the art! Additionally, development of unique systems often results from the combined efforts of integrated teams, and in order to ensure that the systems will provide the expected results, it is equally as important to be able to provide training for the personnel that are responsible for the day-to-day use and maintenance of the new systems.

  4. Oilfield Equipment Market Trends | OpenEI Community

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere I Geothermal Pwer PlantMunhall,Missouri: EnergyExcellenceOffice of State LandsOhio: Energy ResourcesOilfield

  5. A software system for oilfield facility investment minimization

    SciTech Connect (OSTI)

    Ding, Z.X. [Coastal Corp., Houston, TX (United States); Startzman, R.A. [Texas A and M Univ., College Station, TX (United States)

    1996-08-01T23:59:59.000Z

    Minimizing investment in oilfield development is an important subject that has attracted a considerable amount of industry attention. One method to reduce investment involves the optimal placement and selection of production facilities. Because of the large amount of capital used in this process, saving a small percent of the total investment may represent a large monetary value. The literature reports algorithms using mathematical programming techniques that were designed to solve the proposed problem in a global optimal manner. Owing to the high-computational complexity and the lack of user-friendly interfaces for data entry and results display, mathematical programming techniques have not been given enough attention in practice. This paper describes an interactive, graphical software system that provides a global optimal solution to the problem of placement and selection of production facilities in oil-field development processes. This software system can be used as an investment minimization tool and a scenario-study simulator. The developed software system consists of five basic modules: (1) an interactive data-input unit, (2) a cost function generator, (3) an optimization unit, (4) a graphic-output display, and (5) a sensitivity-analysis unit.

  6. Bioaugmentation for the treatment of oilfield drilling waste

    SciTech Connect (OSTI)

    Barber, T.P. [BioGEE International, Inc., Houston, TX (United States)

    1997-06-01T23:59:59.000Z

    Disposal of oilfield drilling pit waste is a problem for the petroleum industry. In the past, drilling pits were covered with dirt of the waste was excavated and hauled to a landfill. Bioremediation can clean-up the waste and save the oilfield drillers money and headaches. Bioremediation is the technique of using microbes capable of metabolizing hydrocarbons into environmentally safe water and carbon dioxide. Drilling companies can utilize bioremediation to treat the petroleum wastes in-situ rather than transport the waste. BioGEE has developed a procedure to use in-situ bioremediation on drilling wastes. After environmental conditions are adjusted, hydrocarbon degrading microbes and nutrients are applied. Drilling wastes consist primarily of hydrocarbons. An average well has a total petroleum hydrocarbon (TPH) level of 44,880 PPM. Using BioGEE`s bioremediation technology, TPH levels have successfully been lowered to below the maximum allowable level of 10,000 PPM to 6,486 PPM of TPH in 47 days.

  7. Assembly cell layout and Kanban system design for an oilfield services company

    E-Print Network [OSTI]

    Liu, Junying, M. Eng. Massachusetts Institute of Technology

    2010-01-01T23:59:59.000Z

    The thesis describes the layout design of new gauge assembly lab for an oilfield services company. A relationship diagram was created to categorize all the workstations and activities in the assembly line. Three layouts ...

  8. Indication of transpressional tectonics in the Gullfaks oil-field, northern North Sea

    E-Print Network [OSTI]

    Fossen, Haakon

    Indication of transpressional tectonics in the Gullfaks oil-field, northern North Sea Haakon Fossen, the structure is characterized by a very marked late Kimmerian unconformity which sepa- rates extensively

  9. Field geologist's training guide: An introduction to oilfield geology, mud logging and formation evaluation

    SciTech Connect (OSTI)

    Whittaker, A.

    1985-01-01T23:59:59.000Z

    This handbook presents a basic overview of and introduction to petroleum geology, oilfield terminolgy and formation evaluation procedures. The chapters introduce many key concepts. Petroleum geology, oilfield fluids, rig types and their components, wellsite equipment and the environment in which field geologists work are presented in detail. Drilling and completing a well and formation evaluation procedures are examined from the logging geologist's perspective. The appendices contain a wide range of information such as general abbreviations, glossary, and bit classification.

  10. Helicopter Surveys for Locating Wells and Leaking Oilfield Infrastructure

    SciTech Connect (OSTI)

    Hammack, R.W.; Veloski, G.A.; Hodges, G. (Fugro Airborne Surveys)

    2006-10-01T23:59:59.000Z

    Prior to the injection of CO2 into geological formations, either for enhanced oil recovery or for CO2 sequestration, it is necessary to locate wells that perforate the target formation and are within the radius of influence for planned injection wells. Locating and plugging wells is necessary because improperly plugged well bores provide the most rapid route for CO2 escape to the surface. This paper describes the implementation and evaluation of helicopter and ground-based well detection strategies at a 100+ year old oilfield in Wyoming where a CO2 flood is planned. This project was jointly funded by the U.S. Department of Energy’s National Energy Technology Laboratory and Fugro Airborne Surveys

  11. Brine flow in heated geologic salt.

    SciTech Connect (OSTI)

    Kuhlman, Kristopher L.; Malama, Bwalya

    2013-03-01T23:59:59.000Z

    This report is a summary of the physical processes, primary governing equations, solution approaches, and historic testing related to brine migration in geologic salt. Although most information presented in this report is not new, we synthesize a large amount of material scattered across dozens of laboratory reports, journal papers, conference proceedings, and textbooks. We present a mathematical description of the governing brine flow mechanisms in geologic salt. We outline the general coupled thermal, multi-phase hydrologic, and mechanical processes. We derive these processes' governing equations, which can be used to predict brine flow. These equations are valid under a wide variety of conditions applicable to radioactive waste disposal in rooms and boreholes excavated into geologic salt.

  12. THERMAL GRADIENT MIGRATION OF BRINE INCLUSIONS IN SALT

    E-Print Network [OSTI]

    Yagnik, S.K.

    2010-01-01T23:59:59.000Z

    OF BRINE INCLUSIONS IN SALT Suresh K. Yagnik February 1982 TOF BRINE INCLUSIONS IN SALT by Suresh K. Yagnik Materialsb u i l t in future. The salt deposits, however, are known

  13. Batteries from Brine | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't Your Destiny: The FutureComments fromofBatteries from Brine Batteries from Brine March 31, 2014

  14. Biennial Workshop on Aerial Photography, Videography, and High Resolution Digital Imagery for Resource Assessment

    E-Print Network [OSTI]

    Hung, I-Kuai

    for Resource Assessment May 15-17, 2007 * Terre Haute, Indiana USING REMOTELY SENSED DATA TO QUANTIFY for Resource Assessment May 15-17, 2007 * Terre Haute, Indiana Figure 1. Scar of oilfield brine contaminated to the successful modeling of numerous natural resource and cultural processes (Jensen, 2005). Because oilfield

  15. Multiphase production through hilly terrain pipelines in Cusiana oilfield, Colombia

    SciTech Connect (OSTI)

    Hill, T.J.; Fairhurst, C.P.; Nelson, C.J.; Becerra, H.; Bailey, R.S.

    1996-12-31T23:59:59.000Z

    The Cusiana oilfield in Colombia is currently producing about 180,000 bpd through a complex multiphase flowline network. The terrain of the area is very hilly, with substantial elevation changes along the length of the lines. Prediction of pressure drop using industry standard correlations has been very variable in its accuracy. A revised pressure drop method, including the effect of slug formation and decay, has been produced, with appreciably better performance. Field data on flow regime characteristics from several of the lines are presented to show a transition from surging/slugging to a steady {open_quote}homogeneous{close_quote} flow at relatively low mixture velocity. The effect of slug flow on slugcatcher performance has also been assessed, both by direct measurement, and by use of a dynamic simulator. The simulator is used to test new control schemes prior to implementation. At low flowing velocities one line has been seen to undergo large pressure swings and to exhibit slug production due to liquid accumulation and sweepout. This effect is described, and re-produced using a transient simulator.

  16. Generalized computer-assisted operations; A comprehensive system for day-to-day oilfield operations

    SciTech Connect (OSTI)

    Dunham, C.L.; Anderson, S.R. (Shell Oil Co. (US))

    1991-03-01T23:59:59.000Z

    This paper reports that Shell Oil Co. and a U.S. subsidiary, Shell Western E and P Inc., developed a comprehensive, generalized, computer-assisted-operations (CAO) system for day-to-day oilfield operations. The system addresses many of the daily operating needs of data acquisition, well and facility monitoring and control, problem detection and diagnosis, design and/or redesign of artificial-lift systems, and oilfield data management. It is generalized in that one system, with common computer hardware, software, and techniques, serves several different oil fields with diverse operating requirements and conditions.

  17. History and Analysis of Distributed Acoustic Sensing (DAS) for Oilfield Applications

    E-Print Network [OSTI]

    Kimbell, Jeremiah

    2013-05-15T23:59:59.000Z

    detection, gas breakthrough, artificial lift optimization, smart-well completion monitoring, near-wellbore monitoring, real-time hydraulic fracture optimization and geophysical monitoring. They also postulated that permanently installed fiber... ............................................................. 6 2. DOWNHOLE DISTRIBUTED ACOUSTIC SENSING .................................... 8 2.1 System Components .......................................................................... 8 2.2 Oilfield Applications...

  18. Oilfield testing center aids industry in evaluating cutting-edge innovations

    SciTech Connect (OSTI)

    Duey, R.

    1996-01-01T23:59:59.000Z

    The Rocky Mountain Oilfield Testing Center at Teapot Dome keeps a producing field open for research and development. Using a producing oil field for research is the surest way to determine the success or failure of a new invention or technique. The field has 600 producing wells and 68 injection wells.

  19. Field testing of new multilateral drilling and completion technology at the Rocky Mountain Oilfield Testing Center

    SciTech Connect (OSTI)

    Giangiacomo, L.A. [Fluor Daniel NPOSR, Inc., Casper, WY (United States). Rocky Mountain Oilfield Testing Center

    1998-12-31T23:59:59.000Z

    The Rocky Mountain Oilfield Testing Center (RMOTC) has played an important role in bringing new multilateral well technology to the marketplace. Multilateral technology is more complex than most new technologies being brought to the oilfield. It is very difficult to test new designs in the laboratory or conventional test wells. They must be tested downhole in specialized wells to work out design and procedural details. Most of the applications for multilateral technology are in high cost drilling areas, such as offshore or in remote, environmentally sensitive areas. For this reason, opportunities for testing the new technology in the course of routine drilling and completion operations are scarce. Operators are not willing to risk expensive rig time, or losing a wellbore itself, on a test. RMOTC offers a neutral site where the technology can be tested in a relatively low cost environment. There are two drilling rigs and three workover and completion rigs available. Most associated services such as warehouse, roustabouts, backhoe, welders, and mechanics are also available on site, while specialized oilfield services and machine shops are available in nearby Casper. Technologies such as the hollow whipstock, adjustable stabilizer, downhole kickoff assembly, single trip sidetrack tool, stacked multidrain system, rotary steerable systems, and procedures for abandoning an open hole lateral have benefited through the use of RMOTC`s facilities. This paper details the capabilities of the new technologies and the benefits of testing them in a real oilfield environment before taking them to market.

  20. Pore water evolution in oilfield sandstones: constraints from oxygen isotope microanalyses of quartz cement

    E-Print Network [OSTI]

    Haszeldine, Stuart

    Pore water evolution in oilfield sandstones: constraints from oxygen isotope microanalyses to trace the origin and evolution of pore waters in three distinct reservoirs of the Brae Formation water evolution was reconstructed from the time of deposition of the sandstones in the Upper Jurassic

  1. Assessment of Injection Well Construction and Operation for Water Injection Wells and Salt Water Disposal Wells

    E-Print Network [OSTI]

    ) that use this process (minus the evaporation) to provide a brine solution for oilfield applications

  2. The Impact of Tax Shocks and Oil Price Volatility on Risk - A Study of North Sea Oilfield Projects 

    E-Print Network [OSTI]

    Kretzschmar, Gavin Lee; Moles, Peter

    2006-01-01T23:59:59.000Z

    We examine the impact of market volatility and increased fiscal take on risk in strategic natural resource projects. An increase in 2006 UK oilfield taxation is used as a natural experiment for assessing the impact of a ...

  3. Application of chlorine dioxide as an oilfield facilities treatment fluid

    SciTech Connect (OSTI)

    Romaine, J.; Strawser, T.G.; Knippers, M.L.

    1995-11-01T23:59:59.000Z

    Both mechanical and chemical treatments are used to clean water flood injection distribution systems whose efficiency has been reduced as a result of plugging material such as iron sulfide sludge. Most mechanical treatments rely on uniform line diameter to be effective, while chemical treatments require good contact with the plugging material for efficient removal. This paper describes the design and operation of a new innovative application using chlorine dioxide for the removal of iron sulfide sludge from water flood injection distribution systems. This technology has evolved from the use of chlorine dioxide in well stimulation applications. The use of chlorine dioxide for continuous treatment of injection brines will also be discussed. Exxon USA`s Hartzog Draw facility in Gillette, Wyoming was the site for the application described. 4,500 barrels of chlorine dioxide was pumped in three phases to clean sixty-six miles of the water flood distribution system. Results indicate that chlorine dioxide was effective in cleaning the well guard screens, the injection lines, frac tanks used to collect the treatment fluids and the injection wells.

  4. Radionuclide transport in sandstones with WIPP brine

    SciTech Connect (OSTI)

    Weed, H.C.; Bazan, F.; Fontanilla, J.; Garrison, J.; Rego, J.; Winslow, A.M.

    1981-02-01T23:59:59.000Z

    Retardation factors (R) have been measured for the transport of /sup 3/H, /sup 95m/Tc, and /sup 85/Sr in WIPP brine using St. Peter, Berea, Kayenta, and San Felipe sandstone cores. If tritium is assumed to have R=1, /sup 95m/Tc has R=1.0 to 1.3 and therefore is essentially not retarded. Strontium-85 has R = 1.0 to 1.3 on St. Peter, Berea, and Kayenta, but R=3 on San Felipe. This is attributed to sorption on the matrix material of San Felipe, which has 45 volume % matrix compared with 1 to 10 volume % for the others. Retardation factors (R/sub s/) for /sup 85/Sr calculated from static sorption measurements are unity for all the sandstones. Therefore, the static and transport results for /sup 85/Sr disagree in the case of San Felipe, but agree for St. Peter, Berea, and Kayenta.

  5. Geochemistry of Aluminum in High Temperature Brines

    SciTech Connect (OSTI)

    Benezeth, P.; Palmer, D.A.; Wesolowski, D.J.

    1999-05-18T23:59:59.000Z

    The objective ofthis research is to provide quantitative data on the equilibrium and thermodynamic properties of aluminum minerals required to model changes in permeability and brine chemistry associated with fluid/rock interactions in the recharge, reservoir, and discharge zones of active geothermal systems. This requires a precise knowledge of the thermodynamics and speciation of aluminum in aqueous brines, spanning the temperature and fluid composition rangesencountered in active systems. The empirical and semi-empirical treatments of the solubility/hydrolysis experimental results on single aluminum mineral phases form the basis for the ultimate investigation of the behavior of complex aluminosilicate minerals. The principal objective in FY 1998 was to complete the solubility measurements on boehmite (AIOOH) inNaC1 media( 1 .O and 5.0 molal ionic strength, IOO-250°C). However, additional measurements were also made on boehmite solubility in pure NaOH solutions in order to bolster the database for fitting in-house isopiestic data on this system. Preliminary kinetic Measurements of the dissolution/precipitation of boehmite was also carried out, although these were also not planned in the earlier objective. The 1999 objectives are to incorporate these treatments into existing codes used by the geothermal industry to predict the chemistry ofthe reservoirs; these calculations will be tested for reliability against our laboratory results and field observations. Moreover, based on the success of the experimental methods developed in this program, we intend to use our unique high temperature pH easurement capabilities to make kinetic and equilibrium studies of pH-dependent aluminosilicate transformation reactions and other pH-dependent heterogeneous reactions.

  6. A new localized corrosion monitoring technique for the evaluation of oilfield inhibitors

    SciTech Connect (OSTI)

    Fu, S.L.; Griffin, A.M.; Garcia, J.G. Jr. [Nalco/Exxon Energy Chemicals, L.P., Sugar Land, TX (United States); Yang, B. [Nalco Chemical Co., Naperville, IL (United States)

    1996-08-01T23:59:59.000Z

    Flow induced localized corrosion (FILC) is one of the major problems in the oilfield. Presently very few effective techniques are available for monitoring localized corrosion in oilfields. A new electrochemical technique was developed to provide a simple and effective way to monitor localized corrosion. The technique requires a potentiostat and a ZRA (zero resistance ammeter) as the measurement instrument. A special setup was designed to create a small anode and a large cathode. The technique was tested in a recirculating flow loop simulating FILC conditions. This technique was used to demonstrate the effectiveness of a corrosion inhibitor in mitigating localized corrosion. It can be further applied, both in the laboratory and in the field, to other areas where FILC is severe. 35 refs., 12 figs.

  7. Origin and geochemical evolution of the Michigan basin brine

    SciTech Connect (OSTI)

    Wilson, T.P.

    1989-01-01T23:59:59.000Z

    Chemical and isotopic data were collected on 126 oil field brine samples and were used to investigate the origin and geochemical evolution of water in 8 geologic formations in the Michigan basin. Two groups of brine are found in the basin, the Na-Ca-Cl brine in the upper Devonian formations, and Ca-Na-Cl brine from the lower Devonian and Silurian aged formations. Water in the upper Devonian Berea, Traverse, and Dundee formations originated from seawater concentrated into halite facies. This brine evolved by halite precipitation, dolomitization, aluminosilicate reactions, and the removal of SO{sub 4} by bacterial action or by CaSO{sub 4} precipitation. The stable isotopic composition (D, O) is thought to represent dilution of evapo-concentrated seawater by meteoric water. Water in the lower Devonian Richfield, Detroit River Group, and Niagara-Salina formations is very saline Ca-Na-Cl brine. Cl/Br suggest it originated from seawater concentrated through the halite and into the MgSO{sub 4} salt facies, with an origin linked to the Silurian and Devonian salt deposits. Dolomitization and halite precipitation increased the Ca/Na, aluminosilicate reactions removed K, and bacterial action or CaSO{sub 4} precipitation removed SO{sub 4} from this brine. Water chemistry in the Ordovician Trenton-Black River formations indicates dilution of evapo-concentrated seawater by fresh or seawater. Possible saline end-members include Ordovician seawater, present-day upper Devonian brine, or Ca-Cl brine from the deeper areas in the basin.

  8. The architecture of a plug-and-play kernel for oilfield software applications

    SciTech Connect (OSTI)

    Ward, V.L.; Seaton, C.P. [Schlumberger Dowell, Tulsa, OK (United States)

    1996-12-01T23:59:59.000Z

    It is now common practice for engineers to use PC software to design and evaluate oilfield services. Rapidly changing technology in PC software has made it necessary for organizations to release new applications quickly to remain competitive. The authors designed a plug-and-play kernel for the computer aided design and evaluation (CADE) applications to reduce development time and time to market. The paper discusses the kernel used in the CADE software in detail.

  9. Data-Driven Reservoir Management of a Giant Mature Oilfield in the Middle Mohaghegh, S.D., West Virginia University & Intelligent Solutions, Inc., Gaskari, R. and Maysami, M., Intelligent

    E-Print Network [OSTI]

    Mohaghegh, Shahab

    SPE 170660 Data-Driven Reservoir Management of a Giant Mature Oilfield in the Middle East Mohaghegh management applied to a mature giant oilfield in the Middle East is presented. This is a prolific brown field

  10. Method of isolating an oilfield flowline sample for analysis without shearing the sample

    SciTech Connect (OSTI)

    Brickhouse, P.E.

    1990-03-06T23:59:59.000Z

    This patent describes a method for isolating an oil field production flowline sample for analysis without shearing the sample. It comprises: placing an isolation chamber in fluid communication with a sampling port of an oilfield production flowline. The isolation chamber comprising a closed vessel, a first entry port into the vessel, and a first exit port out of the vessel controlled by a first valve. The sampling port is controlled by a valve; opening a sampling port valve while the first valve is closed to permit pressure within the isolation chamber to equalize the pressure within the first entry port and the flowline; opening the first valve to permit oilfield production to pass from the flowline through the sampling port and the first entry port into the isolation chamber and out of the first valve; closing the first valve; closing the sampling port valve; allowing the oilfield production fluid contained within the isolation chamber to separate for a period of time, and removing a sample of fluid from the isolation chamber for examination.

  11. Controls on the distribution of alkylphenols and BTEX in oilfield waters

    SciTech Connect (OSTI)

    Dale, J.D.; Aplin, A.C.; Larter, S.R.; Bennett, L.B.; Macleod, G. [Univ. of Newcastle, Newcastle upon Tyne (United Kingdom)

    1996-10-01T23:59:59.000Z

    Controls on the abundance of alkylphenols and BTEX in oilfield waters are poorly understood, but are important because these species are the main dissolved pollutants in produced waters and may also be used as indicators of both the proximity and migration range of petroleum. Using (1) measurements of alkyl phenols and BTEX in oilfield waters and associated petroleums, and (b) oil/water partition coefficients under subsurface conditions we conclude that: (1) The distribution of alkylphenols and BTEX in formation waters are controlled by partition equilibrium with petroleum. Phenol and benzene typically account for 50% of total phenols and total BTEX respectively. (2) The concentrations of alkylphenols and BTEX in produced waters equilibriated with oil in reservoirs or in separator systems vary predictably as a function of pressure, temperature and salinity. This suggests that oil/water partition is the primary control influencing the distribution of alkylphenols and BTEX in oilfield waters and that other processes such as hydrolysis processes at the oil-water contact are secondary.

  12. The feasibility of deep well injection for brine disposal

    E-Print Network [OSTI]

    Spongberg, Martin Edward

    1994-01-01T23:59:59.000Z

    feasibility. The methodology is utilized to make a preliminary evaluation of a proposed brine injection project in the Dove Creek area of King and Stonewall Counties, North Central Texas. Four known deep aquifers are modeled, using the SWIFT/486 software...

  13. acartia tonsa brine: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    be determined in advance. We estimate the optimal design of an average-sized ice rink, including pipe diameter, depth and brine type (ethylene glycol and ammonia). We also...

  14. Study on fine geological modelling of the fluvial sandstone reservoir in Daqing oilfield

    SciTech Connect (OSTI)

    Zhoa Han-Qing [Daqing Research Institute, Helongjiang (China)

    1997-08-01T23:59:59.000Z

    These paper aims at developing a method for fine reservoir description in maturing oilfields by using close spaced well logging data. The main productive reservoirs in Daqing oilfield is a set of large fluvial-deltaic deposits in the Songliao Lake Basin, characterized by multi-layers and serious heterogeneities. Various fluvial channel sandstone reservoirs cover a fairly important proportion of reserves. After a long period of water flooding, most of them have turned into high water cut layers, but there are considerable residual reserves within them, which are difficult to find and tap. Making fine reservoir description and developing sound a geological model is essential for tapping residual oil and enhancing oil recovery. The principal reason for relative lower precision of predicting model developed by using geostatistics is incomplete recognition of complex distribution of fluvial reservoirs and their internal architecture`s. Tasking advantage of limited outcrop data from other regions (suppose no outcrop data available in oilfield) can only provide the knowledge of subtle changing of reservoir parameters and internal architecture. For the specific geometry distribution and internal architecture of subsurface reservoirs (such as in produced regions) can be gained only from continuous infilling logging well data available from studied areas. For developing a geological model, we think the first important thing is to characterize sandbodies geometries and their general architecture`s, which are the framework of models, and then the slight changing of interwell parameters and internal architecture`s, which are the contents and cells of the model. An excellent model should possess both of them, but the geometry is the key to model, because it controls the contents and cells distribution within a model.

  15. Up-Scaling Geochemical Reaction Rates Accompanying Acidic CO2-Saturated Brine Flow in Sandstone Aquifers

    E-Print Network [OSTI]

    New York at Stoney Brook, State University of

    1 Up-Scaling Geochemical Reaction Rates Accompanying Acidic CO2-Saturated Brine Flow in Sandstone models. As a step toward this, network flow models were used to simulate the flow of CO2-saturated brine

  16. Nevada: Geothermal Brine Brings Low-Cost Power with Big Potential...

    Energy Savers [EERE]

    Nevada: Geothermal Brine Brings Low-Cost Power with Big Potential Nevada: Geothermal Brine Brings Low-Cost Power with Big Potential August 21, 2013 - 12:00am Addthis Utilizing a 1...

  17. Gas Content of Gladys McCall Reservoir Brine A Topical Report

    Office of Scientific and Technical Information (OSTI)

    gas t o brine ratio. This w i l l result i n cubic feet of methane, ethane, propane, etc. per barrel of brine, Then, the contributions from sample points are added until...

  18. Geochemical evidence for possible natural migration of Marcellus Formation brine to

    E-Print Network [OSTI]

    Geochemical evidence for possible natural migration of Marcellus Formation brine to shallow possible migration of Marcellus brine through naturally occurring pathways. The occurrences of saline water, because of natural hydraulic connections to deeper formations. formation water isotopes Marcellus Shale

  19. Comparison study of solid-liquid separation techniques for oilfield pit closures

    SciTech Connect (OSTI)

    Wojtanowicz, A.C.; Field, S.D.; Osterman, M.C.

    1986-01-01T23:59:59.000Z

    Extensive bench-scale and full-scale experiments were conducted at the LSU Solids Control Environmental Laboratory in order to evaluate application of the solids-liquid separation technology to oilfield waste pit volume reduction. The experiments addressed chemical conditioning of various pit slurries such as water-base and oil-base mud reserve pit slurries, mixed sludge from offshore operations, and oil production pit slurry. Effective treatment was found for the majority of the waste samples with pH adjustment and with nonionic and low-charge anionic, high molecular weight polymers. Ultimate dewaterability of various samples was determined by use of the belt press bench simulator. Bench simulators of belt press filtration, vacuum filtration and centrifuge sedimentation were used for design and optimization of the full-scale tests. Alternative solid-liquid separation techniques such as vacuum filtration, belt press filtration, screw press filtration and centrifuging were pilot-tested using field-size equipment and 200 bbls samples of water-base mud, reserve pit slurry and production pit sludge. The test data were analyzed at various operating conditions using a new graphical technique. Also, four typical oilfield solid-bowl centrifuges and a modern solid-bowl dewatering decanter were compared in a series of full-scale tests. Finally a preliminary process study on the mechanism of centrifuge separation of flocculated sludges was performed.

  20. The application of a new polymer mud to horizontal drilling in the Dagang Oilfield

    SciTech Connect (OSTI)

    Yan, J.; Jiang, G.; Zong, R.

    1995-10-01T23:59:59.000Z

    A new kind of polymer muds, which is generally referred to as the amphionic polymer mud, has been applied to the two horizontal well drilling for the first time in the Dagang Oilfield, located in east China. In this mud system, two amphionic polymers are usually used as the main additives, the one with high molecular weight is an inhibitive encapsuler and filtration control agent, and the other one with low molecular weight is a deflocculant. The amphionic polymer, just as its name, is defined as the polymer that both organic cations and anions simultaneously exist in their molecular chains. The design criteria, formulations and properties of this mud system are discussed. As a case history, the field performance of this new polymer mud in the different sections of the second well (by name Guan H-1, a medium-radius horizontal well) is also given. It was shown from the laboratory and field tests that the amphionic polymer mud not only has all the advantages of the polymer muds commonly used, but is able to overcome the disadvantages of those muds, indicated by its highly inhibitive character while maintaining excellent mud performances. For this reason, the major drilling problems for horizontal wells in the Dagang Oilfield, such as hole cleaning, wellbore stability, lubricity, lost circulation and formation damage, which were hardly solved by the use of other water-based muds, could be solved successfully by the use of the amphionic polymer mud at much lower cost than the oil-based mud.

  1. The effect of polyacrylamide polymers and formaldehyde on selected strains of oilfield related bacteria

    SciTech Connect (OSTI)

    Farquhar, G.B. [Texaco E.P.T.D., Houston, TX (United States)

    1996-08-01T23:59:59.000Z

    A preliminary study of the effect of two polyacrylamide polymers and formaldehyde on certain strains of oil field related bacteria was performed. Since at this stage of the development of planning the proposed North Sea polymer flood field samples of native bacteria populations and fluid samples were not available, the preliminary study was made using pure strains of bacteria associated with the oilfield environment. The tests were run using ideal growth conditions of temperature and culture media. The purpose of the study was to determine the effect of proposed polyacrylamide polymer flooding materials on the growth of selected strains of bacteria belonging to families common to the oilfield environment. The effect of 100 ppm of formaldehyde on these organisms also was investigated. The results of the tests showed that these bacteria responded differently to exposure to formaldehyde, polyacrylamide polymers and mixtures of both. These results indicate another possible mechanism for the occurrence of high bacteria related corrosion rates reported to occur on the producing side of polymer floods.

  2. Constraints on origin and evolution of Red Sea brines from helium and argon isotopes

    E-Print Network [OSTI]

    Winckler, Gisela

    Constraints on origin and evolution of Red Sea brines from helium and argon isotopes Gisela November 2000 Abstract Brines from three depressions along the axis of the Red Sea, the Atlantis II II and the Discovery brines originating from locations in the central Red Sea show 4 He

  3. Don Juan Pond, Antarctica: Near-surface CaCl2-brine feeding Earth's most saline

    E-Print Network [OSTI]

    Marchant, David R.

    Don Juan Pond, Antarctica: Near-surface CaCl2-brine feeding Earth's most saline lake lineae (RSL), thought to represent seasonal brines, has sparked interest in analogous environments watershed and show that this, together with small amounts of meltwater, are capable of generating brines

  4. Dynamics and storage of brine in mid-ocean ridge hydrothermal systems

    E-Print Network [OSTI]

    Wilcock, William

    Dynamics and storage of brine in mid-ocean ridge hydrothermal systems Fabrice J. Fontaine1 and brine phases. Time series of vent temperature and salinity (chlorinity) show that some black-smoker vent below seawater for over a decade, which raises important questions concerning the fate of brines

  5. of brine heterogeneity in modern sedimentary basins (6) imply inefficiency of mixing and the

    E-Print Network [OSTI]

    Boyce, C. Kevin

    of brine heterogeneity in modern sedimentary basins (6) imply inefficiency of mixing and the potential for preservation of individual, metal- charged brine reservoirs that could be tapped at some later. The observation that the texturally later brines have higher metal contents is consistent with this model

  6. Brine fluxes from growing sea ice A. J. Wells,1,2

    E-Print Network [OSTI]

    Wettlaufer, John S.

    Brine fluxes from growing sea ice A. J. Wells,1,2 J. S. Wettlaufer,1,2,3 and S. A. Orszag2] It is well known that brine drainage from growing sea ice has a controlling influence on its mechanical oceans. When the ice has exceeded a critical thickness the drainage process is dominated by brine

  7. On the Reliability of Numerical Solutions of Brine Transport in Groundwater: Analysis of In ltration

    E-Print Network [OSTI]

    Bergamaschi, Luca

    On the Reliability of Numerical Solutions of Brine Transport in Groundwater: Analysis of In#12, brine transport List of symbols c normalized salt concentration c k l value of concentration on triangle:37; p.2 #12; Reliability of Numerical Simulations of Brine Transport in Groundwater 3 equivalent

  8. Accurate Thermodynamic Model for the Calculation of H2S Solubility in Pure Water and Brines

    E-Print Network [OSTI]

    Zhu, Chen

    Accurate Thermodynamic Model for the Calculation of H2S Solubility in Pure Water and Brines Zhenhao mineral solubility in H2S saturated brines. An example calculation for galena solubility is given. 1 gasification process.5,6 Sequestration of the gases into geological brine formation is one of the promising

  9. WERE AQUEOUS RIPPLES ON MARS FORMED BY FLOWING BRINES? MICHAEL P. LAMB, JOHN P. GROTZINGER

    E-Print Network [OSTI]

    WERE AQUEOUS RIPPLES ON MARS FORMED BY FLOWING BRINES? MICHAEL P. LAMB, JOHN P. GROTZINGER are not observed. Recent thermodynamic modeling indicates that these brines could have had higher densities (by up whether ripples could have been stable bed forms under flowing Martian brines. To this end, we compiled

  10. Advanced biochemical processes for geothermal brines: Current developments

    SciTech Connect (OSTI)

    Premuzic, E.T.; Lin, M.S.; Bohenek, M. [Brookhaven National Lab., Upton, NY (United States). Energy Science and Technology Div.; Bajsarowicz, V. [CET Environmental Services, Inc., Richmond, CA (United States); McCloud, M. [C.E. Holt/California Energy, Pasadena, CA (United States)

    1997-07-07T23:59:59.000Z

    A research program at Brookhaven National Laboratory (BNL) which deals with the development and application of processes for the treatment of geothermal brines and sludges has led to the identification and design of cost-efficient and environmentally friendly treatment methodology. Initially the primary goal of the processing was to convert geothermal wastes into disposable materials whose chemical composition would satisfy environmental regulations. An expansion of the r and D effort identified a combination of biochemical and chemical processes which became the basis for the development of a technology for the treatment of geothermal brines and sludges. The new technology satisfies environmental regulatory requirements and concurrently converts the geothermal brines and sludges into commercially promising products. Because the chemical composition of geothermal wastes depends on the type of the resource, the emerging technology has to be flexible so that it can be readily modified to suit the needs of a particular type of resource. Recent conceptional designs for the processing of hypersaline and low salinity brines and sludges will be discussed.

  11. Oil production enhancement through a standardized brine treatment. Final report

    SciTech Connect (OSTI)

    Adewumi, A.; Watson, R.; Tian, S.; Safargar, S.; Heckman, S.; Drielinger, I.

    1995-08-01T23:59:59.000Z

    In order to permit the environmentally safe discharge of brines produced from oil wells in Pennsylvania to the surface waters of the Commonwealth and to rapidly brings as many wells as possible into compliance with the law, the Pennsylvania Oil and Gas Association (POGAM) approached the Pennsylvania State University to develop a program designed to demonstrate that a treatment process to meet acceptable discharge conditions and effluent limitations can be standardized for all potential stripper wells brine discharge. After the initial studies, the first phase of this project was initiated. A bench-scale prototype model was developed for conducting experiments in laboratory conditions. The experiments pursued in the laboratory conditions were focused on the removal of ferrous iron from synthetically made brine. Iron was selected as the primary heavy metals for studying the efficiency of the treatment process. The results of a number of experiments in the lab were indicative of the capability of the proposed brine treatment process in the removal of iron. Concurrent with the laboratory experiments, a comprehensive and extensive kinetic study was initiated. This study was necessary to provide the required data base for process modeling. This study included the investigation of the critical pH as well as the rate and order of reactions of the studied elements: aluminum, lead, zinc, and copper. In the second phase of this project, a field-based prototype was developed to evaluate and demonstrate the treatment process effectiveness. These experiments were conducted under various conditions and included the testing on five brines from different locations with various dissolved constituents. The outcome of this research has been a software package, currently based on iron`s reactivity, to be used for design purposes. The developed computer program was refined as far as possible using the results from laboratory and field experiments.

  12. Proper use of sodium bisulfite with minimal salt penetration during brine immersion freezing of shrimp

    E-Print Network [OSTI]

    Broussard, Suzanne Rene

    1988-01-01T23:59:59.000Z

    solution reduced the 41 120 100 0 0 80 E CL CL CV g 60 CL 40 20 ? ~ 0:23, CaCI2. NaCI ? ? & 5:18, Caclz. NaCI ? ? 0 8:15, CaCI2. NaCI 0 4 6 Days on Ice 10 Figure 13-Residual sulfur dioxide on thawed brine frozen shrimp frozen... freezing for two trials. 34 13-Residual sulfur dioxide on thawed brine frozen shrimp frozen in different brine immersion media 41 Figure 14- Black spot development on thawed brine frozen shrimp frozen in different brine immersion media Page 42...

  13. An Examination of Cultural Values and Employees' Perceptions of Support on Affective Reaction and the Desire to Participate in a Formal Mentoring Program in an Oilfield Services Corporation

    E-Print Network [OSTI]

    Hayes, Hanna Bea

    2012-07-16T23:59:59.000Z

    support), affective reaction (job satisfaction and organizational commitment), and the intent to participate in a formal mentoring program in an oilfield services organization. A 44-item electronic survey was utilized to collect data. The questionnaire...

  14. EA-1956: Site-Wide Environmental Assessment for the Divestiture of Rocky Mountain Oilfield Testing Center and Naval Petroleum Reserve No. 3, Natrona County, Wyoming

    Broader source: Energy.gov [DOE]

    DOE prepared an EA that assesses the potential environmental impacts of the proposed discontinuation of DOE operations at the Rocky Mountain Oilfield Testing Center (RMOTC) and the proposed divestiture of Naval Petroleum Reserve Number 3 (NPR-3)

  15. Primary and secondary recovery in the Sho-Vel-Tum oilfield, Oklahoma: Topical report

    SciTech Connect (OSTI)

    Johnson, H.R.; Biglarbigi, K.; Schmidt, L.; Ray, R.M.; Kyser, S.C.

    1987-10-01T23:59:59.000Z

    This study was undertaken as part of a comprehensive review of the potential for enhanced oil recovery in Oklahoma. Due to the past production and future potential production from the Sho-Vel-Tum oilfield, the largest producing field in the State of Oklahoma and the eleventh largest in the United States (15), it was subjected to the detailed analyses reported in this document. The original oil in place at Sho-Vel-Tum is estimated in this study to be 3.237 billion barrels of oil. Of this total, 1.235 billion barrels have been produced from the field through 1984 by primary and secondary (waterflood) applications, while reserves are estimated to be an additional 169 million barrels. By subtraction, 1.833 billion barrels still remain as a target for future development, including enhanced oil recovery. 17 refs., 10 figs., 4 tabs.

  16. Standard guide for evaluating and qualifying oilfield and refinery corrosion inhibitors in the laboratory

    E-Print Network [OSTI]

    American Society for Testing and Materials. Philadelphia

    2006-01-01T23:59:59.000Z

    1.1 This guide covers some generally accepted laboratory methodologies that are used for evaluating corrosion inhibitors for oilfield and refinery applications in well defined flow conditions. 1.2 This guide does not cover detailed calculations and methods, but rather covers a range of approaches which have found application in inhibitor evaluation. 1.3 Only those methodologies that have found wide acceptance in inhibitor evaluation are considered in this guide. 1.4 This guide is intended to assist in the selection of methodologies that can be used for evaluating corrosion inhibitors. 1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory requirements prior to use.

  17. Reduction of risk to the marine environment from oilfield chemicals - balancing environmental and technical needs

    SciTech Connect (OSTI)

    O`Neill, J.E.; Hill, D.G.

    1996-12-31T23:59:59.000Z

    The study argues that the regulation of offshore use of hazardous chemicals for oilfield stimulation and Completion applications is an important but not a total solution to reduce marine pollution from offshore sources. The aim of the study is to demonstrate that for a complete solution, chemical reformulation must be considered hand-in-band with improved operational practices to provide a maximum effect on overall risk reduction. The study is directed at one major service company`s approach to the whole issue of chemical management in the 1990s, based mainly on North Sea experience in cementing, drilling fluid and stimulation activities. Oilfield chemicals are incorporated into a fluid design to solve a specific technical problem in a well, such as well completion, stimulation and damage removal. While it is desirable to replace all the harmful chemicals, the practicalities of doing so are limited if the industry is to continue to produce efficiently. Other alternatives need consideration. By their very chemistry, some chemicals have primary active ingredients which may be harmful if discharged into the environment. Improving the characteristics of chemicals to marine life requires the change of previously acceptable products, such as the elimination of banned materials as well as incorporating components with reduced toxicity and greater biodegradability. The idealistic goal is the immediate replacement of all chemicals by nontoxic, biodegrade alternatives; the practical solution is replacement reformulation where possible and the improved isolation the oilwell and marine environments through improvements in continuous-mix technology along with reduction of the chemicals by better job design.

  18. Beneficial reuse of oilfield waste outside of the oil and gas industry

    SciTech Connect (OSTI)

    Marinello, S.A.; Herbert, B.F.; Lillo, H. [and others

    1995-12-31T23:59:59.000Z

    If a beneficial reuse of an oilfield waste can be found, that specific byproduct is no longer a waste, but a product. With such downstream use, the environmental liabilities of the former waste are, except for any packaging or transportation requirements, potentially eliminated. There is a problem, however, with the lack of an active infrastructure to implement the process. Some states have limited programs, but participation is a problem. It is apparent that a {open_quotes}Waste Clearinghouse{close_quotes} addressing oilfield waste in conjunction with major industrial waste and feed streams is needed, but implementation remains in the future. An active network of participating suppliers and users would be the goal of such action. The benefits for industry would be a reduction in waste disposal and associated liabilities and {open_quotes}virgin{close_quotes} feedstock requirements. From the operators viewpoint, this scenario would require a compilation of the different waste/byproduct streams and their characteristics and a prioritizing of those wastes by characteristics that might affect their reuse potential. These might include: (1) the greatest likelihood of finding a market; (2) the highest potential waste volume reduction; (3) the highest cost of disposal and (4) the greatest associated hazards. For the industry as a whole, an inventorying of these byproducts and characteristics would be tied to the identification of consumers/outlets for specific byproducts. This might be accomplished through the funding of consultants/contractors specializing in clearinghouse activities and/or research into potential applications and uses. The industry needs to change it`s view of waste/byproduct streams in order to be more aware of potential downstream uses. Existing examples of reuse can be used as models for further efforts.

  19. Analysis of anions in geological brines using ion chromatography

    SciTech Connect (OSTI)

    Merrill, R.M.

    1985-03-01T23:59:59.000Z

    Ion chromatographic procedures for the determination of the anions bromide, sulfate, nitrite, nitrate, phosphate, and iodide in brine samples have been developed and are described. The techniques have been applied to the analysis of natural brines, and geologic evaporites. Sample matrices varied over a range from 15,000 mg/L to 200,000 mg/L total halogens, nearly all of which is chloride. The analyzed anion concentrations ranged from less than 5 mg/L in the cases of nitrite, nitrate, and phosphate, to 20,000 mg/L in the case of sulfate. A technique for suppressing chloride and sulfate ions to facilitate the analysis of lower concentration anions is presented. Analysis times are typically less than 20 minutes for each procedure and the ion chromatographic results compare well with those obtained using more time consuming classical chemical analyses. 10 references, 14 figures.

  20. 2 INVESTIGATION OF CRUDE OIL/BRINE/ROCK INTERACTION 2.1 EXPERIMENTAL STUDY OF CRUDE/BRINE/ROCK INTERACTION AT

    E-Print Network [OSTI]

    Schechter, David S.

    44 2 INVESTIGATION OF CRUDE OIL/BRINE/ROCK INTERACTION 2.1 EXPERIMENTAL STUDY OF CRUDE of imbibition or oil production rate, particularly after seven days or more aging time with oil. However in this section and expand the understanding of the interactions of the Spraberry reservoir rock, oil and brine

  1. Effects of drilling fluids on marine bacteria from a Nigerian offshore oilfield

    SciTech Connect (OSTI)

    Okpokwasil, G.C.; Nnubia, C. [Univ. of Prot Harcourt (Nigeria)

    1995-11-01T23:59:59.000Z

    Two marine bacterial isolates from drill mud cuttings obtained from Agbara oilfield, Staphylococcus sp. and Bacillus sp., were cultured aerobically in the presence of varying concentrations (0, 25, 50, and 75 {mu}g/ml) of drilling fluids to determine the effects of concentration of toxicants on their growth. With the exception of Clairsol, Enviromul, and Bariod mineral oil, which had little or no effect, the exponential growth of Bacillus sp. was depressed by all other test chemicals. Additionally, all test chemicals except Clairsol had no effect on lag phase of growth of Bacillus sp. With Staphylococcus sp. the depressive effect on the exponential phase of growth was shown by almost all test chemicals. There was enhancement of both growth rate and generation times of Staphylococcus sp. and decrease of those of Bacillus sp. with increasing concentrations of drilling fluids. These results show that while some drilling fluids may be stimulatory or depressive to bacterial growth, others may be without effect. 23 refs., 6 figs., 3 tabs.

  2. Pressure Buildup and Brine Migration During CO2 Storage in Multilayered Aquifers

    E-Print Network [OSTI]

    Zhou, Quanlin

    . Introduction Carbon dioxide capture combined with geologic stor- age (CCS) in suitable subsurface formations-6584.2012.00972.x potentially creating far-ranging pressure buildup and brine displacement in deep CO2 storage of resident brine caused by CCS operations require modeling/analysis tools of considerable complexity (Celia

  3. Conservative behavior of uranium vs. salinity in Arctic sea ice and brine Christelle Not a,

    E-Print Network [OSTI]

    Available online 23 December 2011 Keywords: Uranium Salinity Sea ice Brine Seawater Arctic UraniumConservative behavior of uranium vs. salinity in Arctic sea ice and brine Christelle Not a, ,1 disequilibrium The conservative behavior of uranium (U) with respect to salinity in open ocean waters is widely

  4. RIS-M-2260 HEAT GRADIENT INDUCED MIGRATION OF BRINE INCLUSIONS IN ROCK SALT

    E-Print Network [OSTI]

    RISØ-M-2260 HEAT GRADIENT INDUCED MIGRATION OF BRINE INCLUSIONS IN ROCK SALT Mathematical treatment project. Abstract. A mathematical model for the brine migration in rock salt around an infinite line heat source is set up. The tempera- ture field around the time dependent heat source is calculated by use

  5. Validation of classical density-dependent solute transport theory for stable, high-concentration-gradient brine displacements in

    E-Print Network [OSTI]

    Hassanizadeh, S. Majid

    -concentration-gradient brine displacements in coarse and medium sands S.J. Watson a,1 , D.A. Barry a,1 , R.J. Schotting b,*, S by a brine solution, under either constant head or constant volume flux conditions. The experimental data, significantly less ex- perimental research has been conducted to investigate high-concentration (e.g., brine

  6. PII S0016-7037(01)00901-2 Effect of light and brine shrimp on skeletal 13

    E-Print Network [OSTI]

    Grottoli, Andréa G.

    PII S0016-7037(01)00901-2 Effect of light and brine shrimp on skeletal 13 C in the Hawaiian coral, or high concentrations of brine shrimp. Decreases in light from 100% resulted in significant decreases. Increases in brine shrimp concentrations resulted in increased skeletal 13 C levels. This unexpected outcome

  7. Dense water formation on the northwestern shelf of the Okhotsk Sea: 1. Direct observations of brine rejection

    E-Print Network [OSTI]

    Talley, Lynne D.

    Dense water formation on the northwestern shelf of the Okhotsk Sea: 1. Direct observations of brine 2004; accepted 21 April 2004; published 1 July 2004. [1] Dense Shelf Water (DSW) formation due to brine this period. The density increase terminated abruptly in late February, while the active brine rejection

  8. PII S0016-7037(01)00579-8 The origin and evolution of base metal mineralising brines and hydrothermal fluids,

    E-Print Network [OSTI]

    Banks, David

    PII S0016-7037(01)00579-8 The origin and evolution of base metal mineralising brines are the source of the mineralising fluids. Cl and Br systematics suggest that the brines were formed either cation composition (Na, Ca, K, Mg) of the brines is not consistent solely with evaporation processes

  9. Secondary oil recovery from selected Carter sandstone oilfields, Black Warrior basin, Alabama. [Annual] yearly report, December 1, 1992--November 30, 1993

    SciTech Connect (OSTI)

    Anderson, J.C.

    1994-03-01T23:59:59.000Z

    In this Class I PON, Anderman/Smith Operating Company is targeting three Carter sandstone oilfields (Black Warrior basin) for secondary recovery. Waterfloods are underway in two of the areas -- Central Bluff and North Fairview units. For the third area, South Bluff, negotiations are underway to unitize the field. Once South Bluff is unitized, waterflooding will commence.

  10. INEEL Biotechnology for Oilfield Application--Microbial Enhanced Oil Recovery FY-03 Report

    SciTech Connect (OSTI)

    G. A. Bala; D. F. Bruhn; S. L. Fox; K. S. Noah; K. D. Schaller; E. P. Robertson; X. Xie

    2003-11-01T23:59:59.000Z

    The Idaho National Engineering and Environmental Laboratory (INEEL) Biotechnology for Oilfield Operations program supports development, engineering, and application of biotechnology for exploration and production. This continuing INEEL program also supports mitigation of detrimental field conditions. The program is consistent with the United States Department of Energy mission to ¡§promote activities and policies through its oil technology and natural gas supply programs to enhance the efficiency and environmental quality of domestic oil and natural gas exploration, recovery, processing, transport, and storage.¡¨ In addition, the program directly supports the focus areas of Reservoir Life Extension; Advanced Drilling, Completion and Stimulation Systems; Effective Environmental Protection; and Cross Cutting Areas. The program is enhanced by collaborative relationships with industry and academia. For fiscal year 2003, the program focused on production and characterization of biological surfactants from agricultural residuals and the production and application of reactive microbial polymers. This report specifically details: 1. Use of a chemostat reactor operated in batch mode for producing surfactin, with concomitant use of an antifoam to prevent surfactant loss. The program achieved production and recovery of 0.6 g/L of surfactin per 12 hr. 2. Characterization of surfactin produced from agricultural residuals with respect to its ability to mediate changes in surface tension. Conditions evaluated were salt (as NaCl) from 0 to 10% (w/v), pH from 3 to 10, temperature from 21 to 70¢XC, and combinations of these conditions. When evaluated singularly, pH below 6 and salt concentrations above 30 g/L were found to have an adverse impact on surfactin. Temperatures of 70¢XC for 95 days had no effect. When the effect of temperature was added to the pH experiment, there were no significant changes, and, again, surface tension, at any temperature, increased at pH below 6. When temperature (70¢XC) was added to the experiments with salt, the impacts of salt up to 30 g/L were negligible. When all three parameters were combined in one experiment, no increase in surface tension was observed at 80 g/L NaCl, pH 10, and 70¢XƒnC. The upper temperature limit of the surfactin was not determined in these experiments. 3. Impact of alkaline soluble, pH reactive biopolymers to alter permeability in Berea sandstone cores. The contributing effect of salt (as NaCl to 2%, w/v), temperatures to 60¢XC, and crude oil were evaluated. Residual resistance factors were increased 800 fold, compared to cores without biopolymer. This could lead to alternate technology for permeability modification, thus extending the life of a reservoir and preventing premature abandonment.

  11. Strontium isotope quantification of siderite, brine and acid mine drainage contributions to abandoned gas well discharges in the Appalachian Plateau

    SciTech Connect (OSTI)

    Chapman, Elizabeth C.; Capo, Rosemary C.; Stewart, Brian W.; Hedin, Robert S.; Weaver, Theodore J.; Edenborn, Harry M.

    2013-04-01T23:59:59.000Z

    Unplugged abandoned oil and gas wells in the Appalachian region can serve as conduits for the movement of waters impacted by fossil fuel extraction. Strontium isotope and geochemical analysis indicate that artesian discharges of water with high total dissolved solids (TDS) from a series of gas wells in western Pennsylvania result from the infiltration of acidic, low Fe (Fe < 10 mg/L) coal mine drainage (AMD) into shallow, siderite (iron carbonate)-cemented sandstone aquifers. The acidity from the AMD promotes dissolution of the carbonate, and metal- and sulfate-contaminated waters rise to the surface through compromised abandoned gas well casings. Strontium isotope mixing models suggest that neither upward migration of oil and gas brines from Devonian reservoirs associated with the wells nor dissolution of abundant nodular siderite present in the mine spoil through which recharge water percolates contribute significantly to the artesian gas well discharges. Natural Sr isotope composition can be a sensitive tool in the characterization of complex groundwater interactions and can be used to distinguish between inputs from deep and shallow contamination sources, as well as between groundwater and mineralogically similar but stratigraphically distinct rock units. This is of particular relevance to regions such as the Appalachian Basin, where a legacy of coal, oil and gas exploration is coupled with ongoing and future natural gas drilling into deep reservoirs.

  12. Seizing a species : the story of the Great Salt Lake brine shrimp harvest

    E-Print Network [OSTI]

    Wotipka, Samuel Alex

    2014-01-01T23:59:59.000Z

    In the early 1950s, C.C. "Sparkplug" Sanders began harvesting brine shrimp from Utah's Great Salt Lake. Sanders built up a small business selling their eggs, called "cysts, to aquarium stores across the country. During the ...

  13. Soils and Brine Geochemistry and Mineralogy of Hyperarid Desert Playa, Ouargla Basin,

    E-Print Network [OSTI]

    Ahmad, Sajjad

    Soils and Brine Geochemistry and Mineralogy of Hyperarid Desert Playa, Ouargla Basin, Algerian. The chemical and mineralogical specificity of this hyperarid ecosystem has been compared to other areas under

  14. Behavior of type 304 and type 316 austenitic stainless in 55% lithium bromide heavy brine environments

    SciTech Connect (OSTI)

    Itzhak, D.; Elias, O. (Ben-Gurion Univ., Beer-Sheva (Israel). Dept. of Materials Engineering)

    1994-02-01T23:59:59.000Z

    Cylindrical tensile specimens of AISI type 304 (UNS S30400) and type 316 (UNS S31600) stainless steels (SS) were tested under constant-load conditions in 55% lithium bromide (LiBr) heavy brines at temperatures of 120 C and 140 C. Elongation and open-circuit potential (OCP) were recorded during the tensile test. Potentiodynamic polarization measurements were conducted, and the failed surface fractures were examined by scanning electron microscopy. The tested SS were subjected to stress corrosion under the test environments. Sensitivity was affected strongly by pH values. In LiBr brine of pH = 11.6, the passivation processes were more effective than in brine of pH = 6 [approximately] 8. Because of effective passivation behavior in brine of pH = 11.6, lower values of [delta]l[sub 0] were measured, indicating lower dislocation relaxation processes and high resistance to stress corrosion cracking.

  15. Pathogenicity of a pseudomonad bacterium to larvae of penaeid and brine shrimp

    E-Print Network [OSTI]

    Huang, Chu-Liang

    1982-01-01T23:59:59.000Z

    OF SCIENCE August 1982 Major Subject: Veterinary Microbiology PATHOGENICITY OF A PSEUDOMONAD BACTERIUM TO LARVAE OF PENAEID AND BRINE SHRIMP A Thesis by CHU-LIANG HUANG Approved as to style and content by: (Chairman of Committee) (Member) (Member...) (Member) (Head of Department) August 1982 ABSTRACT Pathogenicity of a Pseudomonad Bacterium to Larvae of Penaeid and Brine Shrimp (August 1982) Chu-Liang Huang, B. S , National Taiwan University Chairman of Advisory Committee: Dr. Donald H. Lewis A...

  16. Study of thermal-gradient-induced migration of brine inclusions in salt. Final report

    SciTech Connect (OSTI)

    Olander, D.R.

    1984-08-01T23:59:59.000Z

    Natural salt deposits, which are being considered for high-level waste disposal, contain a small volume fraction of water in the form of brine inclusions distributed throughout the salt. Radioactive decay heating of the nuclear wastes will impose a temperature gradient on the surrounding salt which mobilizes the brine inclusions. Inclusions filled completely with brine (the all-liquid inclusions) migrate up the temperature gradient and eventually accumulate brine near the buried waste forms. The brine may slowly corrode or degrade the waste forms, which is undesirable. Therefore it is important to consider the migration of brine inclusions in salt under imposed temperature gradients to properly evaluate the performance of a future salt repository for nuclear wastes. The migration velocities of the inclusions were found to be dependent on temperature, temperature gradient, and inclusion shape and size. The velocities were also dictated by the interfacial mass transfer resistance at brine/solid interface. This interfacial resistance depends on the dislocation density in the crystal, which in turn, depends on the axial compressive loading of the crystal. At low axial loads, the dependence between the velocity and temperature gradient is nonlinear. At high axial loads, the interfacial resistance is reduced and the migration velocity depends linearly on the temperature gradient. All-liquid inclusions filled with mixed brines were also studied. For gas-liquid inclusions, helium, air and argon were compared. Migration studies were also conducted on single crystallites of natural salt as well as in polycrystalline natural salt samples. The behavior of the inclusions at large-ange grain boundaries was observed.

  17. Developing a Process for Commercial Silica Production from Geothermal Brines

    SciTech Connect (OSTI)

    Bourcier, W; Martin, S; Viani, B; Bruton, C

    2001-04-11T23:59:59.000Z

    Useful mineral by-products can be produced from geothermal brines. Although silica has many commercial uses, problems remain in producing a marketable product. We are conducting laboratory and modeling studies aimed at optimizing for rubber additive use, the properties of silica precipitates from Salton Sea and Coso-like geothermal fluids, Our goal is to develop a robust technique for producing silicas that have desirable physical and chemical properties for commercial use, while developing a generic understanding of silica precipitation that will allow extraction to be extended to additional fluid types, and to be easily modified to produce new types of marketable silica. Our experiments start with an acidified geothermal fluid similar to those treated by pH modification technology. Silica precipitation is induced by adding base and/or adding Mg or Ca salts to affect the nature of the precipitate. For the analog Salton Sea fluids, adding base alone caused silica to precipitate fairly rapidly. To date, we have characterized precipitates from experiments in which the final pH varied from 4 to 8, where NaOH and Na{sub 2}C0{sub 3} were added as bases, and CaCl{sub 2} and MgCl{sub 2} were added as salts. SEM photos of the silica precipitates from the Salton Sea and Cos0 fluids show that the silica particles are clusters of smaller silica particles down to the resolution of the SEM (about 80-100 nm in diameter). The particle sizes and surface areas of silicas from the Salton Sea and Coso analog brines are similar to the properties of the Degussa silica commonly used as a rubber additive. An evaluation of the strength of the silica-organic bond as tested by dispersion in oil (polybutadiene) was inconclusive. Neither the Degussa materials nor our laboratory precipitates dispersed readily in nor dispersed down to the fundamental particle size. Preliminary NMR data indicates that the Degussa silica has a smaller degree of silica polymerization (a slightly smaller average number of Si-0 bonds per silica tetrahedron) than the synthetic samples, but a comparable degree of hydrogen bonding of the surface silanol sites.

  18. Hard-bottom macrofauna of the East Flower Garden brine seep: impact of a long term, point-source brine discharge

    E-Print Network [OSTI]

    Gittings, Stephen Reed

    1983-01-01T23:59:59.000Z

    canyon transect were sta- tions R6 and R7, both of which were on top of Cottonwick Rock, ap- proximately 2 m above the canyon floor. Figure 5 (p. 12) shows that salinity and sulfide at these stations were at normal marine levels. Though the total...HARD-BOT1'OM MACROFAUNA OF THE EAST FLOWER GARDEN BRINE SEEP: IMPACT OF A LONG TERM, POINT-SOURCE BRINE DISCHARGE A Thesis by STEPHEN REED GITTINGS Submitted to the Graduate College of Texas A&M University in partial fulfillment...

  19. Recovery of energy from geothermal brine and other hot water sources

    DOE Patents [OSTI]

    Wahl, III, Edward F. (Claremont, CA); Boucher, Frederic B. (San Juan Capistrano, CA)

    1981-01-01T23:59:59.000Z

    Process and system for recovery of energy from geothermal brines and other hot water sources, by direct contact heat exchange between the brine or hot water, and an immiscible working fluid, e.g. a hydrocarbon such as isobutane, in a heat exchange column, the brine or hot water therein flowing countercurrent to the flow of the working fluid. The column can be operated at subcritical, critical or above the critical pressure of the working fluid. Preferably, the column is provided with a plurality of sieve plates, and the heat exchange process and column, e.g. with respect to the design of such plates, number of plates employed, spacing between plates, area thereof, column diameter, and the like, are designed to achieve maximum throughput of brine or hot water and reduction in temperature differential at the respective stages or plates between the brine or hot water and the working fluid, and so minimize lost work and maximize efficiency, and minimize scale deposition from hot water containing fluid including salts, such as brine. Maximum throughput approximates minimum cost of electricity which can be produced by conversion of the recovered thermal energy to electrical energy.

  20. Numerical simulations of lab-scale brine-water mixing experiments.

    SciTech Connect (OSTI)

    Khalil, Imane; Webb, Stephen Walter

    2006-10-01T23:59:59.000Z

    Laboratory-scale experiments simulating the injection of fresh water into brine in a Strategic Petroleum Reserve (SPR) cavern were performed at Sandia National Laboratories for various conditions of injection rate and small and large injection tube diameters. The computational fluid dynamic (CFD) code FLUENT was used to simulate these experiments to evaluate the predictive capability of FLUENT for brine-water mixing in an SPR cavern. The data-model comparisons show that FLUENT simulations predict the mixing plume depth reasonably well. Predictions of the near-wall brine concentrations compare very well with the experimental data. The simulated time for the mixing plume to reach the vessel wall was underpredicted for the small injection tubes but reasonable for the large injection tubes. The difference in the time to reach the wall is probably due to the three-dimensional nature of the mixing plume as it spreads out at the air-brine or oil-brine interface. The depth of the mixing plume as it spreads out along the interface was within a factor of 2 of the experimental data. The FLUENT simulation results predict the plume mixing accurately, especially the water concentration when the mixing plume reaches the wall. This parameter value is the most significant feature of the mixing process because it will determine the amount of enhanced leaching at the oil-brine interface.

  1. Investigation of scaling and inhibition mechanisms and the influencing factors in static and dynamic inhibition tests

    SciTech Connect (OSTI)

    Yuan, M.D.; Jamieson, E.; Hammonds, P. [Baker Petrolite, Aberdeen (United Kingdom)

    1998-12-31T23:59:59.000Z

    This paper presents results of some recent laboratory study on barium sulfate scale inhibition in oilfield brines and investigation of several factors potentially effecting scale inhibition efficiency. In addition to well known mechanisms of scale nucleation inhibition and crystal growth retardation, dispersion/anti-conglomeration appears to be a significant inhibition mechanism associated with some scale inhibitors, which may play an important role in a dynamic flowing system. The contamination of a brine by an organic chelating agent such as EDTA or citric acid did not, in this study, show any significant effect on the barium sulfate inhibition efficiency of any of the three generically different scale inhibitors included. Experiments show that, in a properly enclosed system, the pH of an oilfield brine even with hydrogen bicarbonate presence can be sufficiently buffered with acetic acid. These new results are believed to be useful in evaluating/selecting scale inhibitors and improving barium sulfate scale inhibition test methods.

  2. West Hackberry Strategic Petroleum Reserve site brine-disposal monitoring, Year I report. Volume III. Biological oceanography. Final report

    SciTech Connect (OSTI)

    DeRouen, L.R.; Hann, R.W.; Casserly, D.M.; Giammona, C.; Lascara, V.J. (eds.)

    1983-02-01T23:59:59.000Z

    The Department of Energy's Strategic Petroleum Reserve Program began discharging brine into the Gulf of Mexico from its West Hackberry site near Cameron, Louisiana in May 1981. The brine originates from underground salt domes being leached with water from the Intracoastal Waterway, making available vast underground storage caverns for crude oil. The effects of brine discharge on aquatic organisms are presented in this volume. The topics covered are: benthos; nekton; phytoplankton; zooplankton; and data management.

  3. Sorption of cesium and strontium from concentrated brines by backfill barrier materials

    SciTech Connect (OSTI)

    Winslow, C D

    1981-03-01T23:59:59.000Z

    The sorption of radionuclides from potentially intruding groundwater at a nuclear waste repository is a major chemical function of backfill barriers. In this study, various materials (including clays, zeolites and an inorganic ion exchanger) were screened for the sorption of the fission products cesium and strontium in concentrated brines. Representative brines A and B for the Waste Isolation Pilot Plant (WIPP), a proposed radioactive waste repository and test facility in bedded salt were used. Sorption properties were quantified using empirical distribution coefficients, k/sub d/. Of the materials examined, sodium titanate had the highest k/sub d/ for the sorption of Sr(II) in both brine A (k/sub d/ = 125 ml/g) and brine B(k/sub d/ = 500 to 600 ml/g). A mordenite-type zeolite was the most effective getter for Cs(I) in brine A (k/sub d = 27 ml/g), while illite yielded the highest k/sub d/ for Cs(I) in brine B (k/sub d/ = 115 ml/g). The relative merit of these k/sub d/ values is evaluated in terms of calculated estimates of breakthrough times for a backfill barrier containing the getter. Results show that a backfill mixture containing these getters is potentially an effective barrier to the migration of Sr(II) and Cs(I), although further study (especially for the sorption of cesium from brine A) is recommended. Initial mechanistic studies revealed competing ion effects which would support an ion exchange mechanism. K/sub d/'s were constant over a Sr(II) concentration range of 10/sup -11/ to 10/sup -5/ M and a Cs(I) concentration range of 10/sup -8/ to 10/sup -5/ M, supporting the choice of a linear sorption isotherm as a model for the results. Constant batch composition was shown to be attained within one week.

  4. Recovery of Fresh Water Resources from Desalination of Brine Produced During Oil and Gas Production Operations

    SciTech Connect (OSTI)

    David B. Burnett; Mustafa Siddiqui

    2006-12-29T23:59:59.000Z

    Management and disposal of produced water is one of the most important problems associated with oil and gas (O&G) production. O&G production operations generate large volumes of brine water along with the petroleum resource. Currently, produced water is treated as a waste and is not available for any beneficial purposes for the communities where oil and gas is produced. Produced water contains different contaminants that must be removed before it can be used for any beneficial surface applications. Arid areas like west Texas produce large amount of oil, but, at the same time, have a shortage of potable water. A multidisciplinary team headed by researchers from Texas A&M University has spent more than six years is developing advanced membrane filtration processes for treating oil field produced brines The government-industry cooperative joint venture has been managed by the Global Petroleum Research Institute (GPRI). The goal of the project has been to demonstrate that treatment of oil field waste water for re-use will reduce water handling costs by 50% or greater. Our work has included (1) integrating advanced materials into existing prototype units and (2) operating short and long-term field testing with full size process trains. Testing at A&M has allowed us to upgrade our existing units with improved pre-treatment oil removal techniques and new oil tolerant RO membranes. We have also been able to perform extended testing in 'field laboratories' to gather much needed extended run time data on filter salt rejection efficiency and plugging characteristics of the process train. The Program Report describes work to evaluate the technical and economical feasibility of treating produced water with a combination of different separation processes to obtain water of agricultural water quality standards. Experiments were done for the pretreatment of produced water using a new liquid-liquid centrifuge, organoclay and microfiltration and ultrafiltration membranes for the removal of hydrocarbons from produced water. The results of these experiments show that hydrocarbons from produced water can be reduced from 200 ppm to below 29 ppm level. Experiments were also done to remove the dissolved solids (salts) from the pretreated produced water using desalination membranes. Produced water with up to 45,000 ppm total dissolved solids (TDS) can be treated to agricultural water quality water standards having less than 500 ppm TDS. The Report also discusses the results of field testing of various process trains to measure performance of the desalination process. Economic analysis based on field testing, including capital and operational costs, was done to predict the water treatment costs. Cost of treating produced water containing 15,000 ppm total dissolved solids and 200 ppm hydrocarbons to obtain agricultural water quality with less than 200 ppm TDS and 2 ppm hydrocarbons range between $0.5-1.5 /bbl. The contribution of fresh water resource from produced water will contribute enormously to the sustainable development of the communities where oil and gas is produced and fresh water is a scarce resource. This water can be used for many beneficial purposes such as agriculture, horticulture, rangeland and ecological restorations, and other environmental and industrial application.

  5. Dewetting of silica surfaces upon reactions with supercritical CO2 and brine: Pore-scale studies in micromodels

    E-Print Network [OSTI]

    Kim, Y.

    2013-01-01T23:59:59.000Z

    accumulation of residual water in pendular structuresAfter drainage, the residual water remained as thick filmsdisplaced brine), the residual water was initially retained

  6. Developing a process for commercial silica production from Salton Sea brines

    SciTech Connect (OSTI)

    Bourcier, W; McCutcheon, M; Leif, R; Bruton, C

    2000-09-25T23:59:59.000Z

    The goal of this joint LLNL-CalEnergy project is to develop a method for precipitating marketable silica from spent Salton Sea Geothermal Field (SSGF) brines. Many markets for silica exist. We have initially targeted production of silica as a rubber additive. Silica reinforced rubber gives tires less rolling resistance, greater tear strength, and better adhesion to steel belts. Previous silica precipitates produced by CalEnergy from Salton Sea brines were not suitable as rubber additives. They did not to disperse well in the rubber precursors and produced inferior rubber. CalEnergy currently minimizes silica scaling in some of their production facilities by acidifying the brine pH. The rate of silica precipitation slows down as the pH is lowered, so that energy extraction and brine reinfection are possible without unacceptable amounts of scaling even with more than 700 ppm SiO{sub 2} in solution. We are adding a step in which a small amount of base is added to the acidified brine to precipitate silica before reinfection. By carefully controlling the type, rate, and amount of base addition, we can optimize the properties of the precipitate to approach those of an ideal rubber additive.

  7. Evaluation of Membrane Treatment Technology to Optimize and Reduce Hypersalinity Content of Produced Brine for Reuse in Unconventional Gas Wells 

    E-Print Network [OSTI]

    Eboagwu, Uche

    2012-10-19T23:59:59.000Z

    Over 18 billion barrels of waste fluids are generated annually from oil and gas production in the United States. As a large amount of water is used for oilfield operations, treating and reusing produced water can cut the consumption of fresh water...

  8. Contaminant treatment method

    DOE Patents [OSTI]

    Shapiro, Andrew Philip (Schenectady, NY); Thornton, Roy Fred (Schenectady, NY); Salvo, Joseph James (Schenectady, NY)

    2003-01-01T23:59:59.000Z

    The present invention provides a method for treating contaminated media. The method comprises introducing remediating ions consisting essentially of ferrous ions, and being peroxide-free, in the contaminated media; applying a potential difference across the contaminated media to cause the remediating ions to migrate into contact with contaminants in the contaminated media; chemically degrading contaminants in the contaminated media by contact with the remediating ions; monitoring the contaminated media for degradation products of the contaminants; and controlling the step of applying the potential difference across the contaminated media in response to the step of monitoring.

  9. Formation and character of an ancient 19-m ice cover and underlying trapped brine in an ``ice-sealed'' east

    E-Print Network [OSTI]

    Priscu, John C.

    Formation and character of an ancient 19-m ice cover and underlying trapped brine in an ``ice bed year-round. New ice-core analysis and tempera- ture data show that beneath 19 m of ice is a water°C. The ice cover thickens at both its base and surface, sealing concentrated brine beneath. The ice

  10. Brine transport studies in the bedded salt of the Waste Isolation Pilot Plant (WIPP)

    SciTech Connect (OSTI)

    McTigue, D.F.; Nowak, E.J.

    1987-01-01T23:59:59.000Z

    Brine flow has been measured to unheated boreholes for periods of a few days and to heated holes for two years in the WIPP facility. It is suggested that Darcy flow may dominate the observed influx of brine. Exact solutions to a linearized model for one-dimensional, radial flow are evaluated for conditions approximating the field experiments. Flow rates of the correct order of magnitude are calculated for permeabilities in the range 10/sup -21/ to 10/sup -20/ m/sup 2/ (1 to 10 nanodarcy) for both the unheated and heated cases. 20 refs., 3 figs., 1 tab.

  11. Brine release based on structural calculations of damage around an excavation at the Waste Isolation Pilot Plant (WIPP)

    SciTech Connect (OSTI)

    Munson, D.E.; Jensen, A.L.; Webb, S.W. [Sandia National Labs., Albuquerque, NM (United States); DeVries, K.L. [RE/SPEC, Inc., Rapid City, SD (United States)

    1996-02-01T23:59:59.000Z

    In a large in situ experimntal circular room, brine inflow was measured over 5 years. After correcting for evaporation losses into mine ventilation air, the measurements gave data for a period of nearly 3 years. Predicted brine accumulation based on a mechanical ``snow plow`` model of the volume swept by creep-induced damage as calculated with the Multimechanism Deformation Coupled Fracture model was found to agree with experiment. Calculation suggests the damage zone at 5 years effectively exends only some 0.7 m into the salt around the room. Also, because the mecahnical model of brine release gives an adequate explanation of the measured data, the hydrological process of brine flow appears to be rapid compared to the mechanical process of brine release.

  12. PII S0016-7037(00)00369-0 Ra isotopes and Rn in brines and ground waters of the Jordan-Dead Sea Rift Valley

    E-Print Network [OSTI]

    Yehoshua, Kolodny

    PII S0016-7037(00)00369-0 Ra isotopes and Rn in brines and ground waters of the Jordan-Dead Sea Valley waters being mixtures of fresh water with saline brines. Ra is efficiently extracted from surrounding rocks into the brine end member. 228 Ra/226 Ra ratios are exceptionally low 0.07 to 0.9, mostly

  13. PII S0016-7037(99)00441-X Sub sea floor boiling of Red Sea Brines: New indication from noble gas data

    E-Print Network [OSTI]

    Winckler, Gisela

    PII S0016-7037(99)00441-X Sub sea floor boiling of Red Sea Brines: New indication from noble gas in revised form December 8, 1999) Abstract--Hydrothermal brines from the Atlantis II Deep, Red Sea, have been depressions filled by highly saline brines (Hartmann et al., 1998a). The Atlantis II Deep, located

  14. Brine-assisted anatexis: Experimental melting in the system haplograniteH2ONaClKCl at deep-crustal conditions

    E-Print Network [OSTI]

    Manning, Craig

    Brine-assisted anatexis: Experimental melting in the system haplogranite­H2O­NaCl­KCl at deep2O ¼ 0:34 it is 0.55. This "brine trend" is similar to, but more pronounced than, the trend-rich granites. Minimum-melting curves in the presence of brines of constant XH2O have strongly positive d

  15. NOBOB-S: Salinity/Brine Exposure as a Biocide for Application to NOBOB Residuals

    E-Print Network [OSTI]

    , eggs and spores of many taxa within the sediments and residual water of their ballast tanks (Niimi a voluntary "best management practices" approach for residual ballast water and sediment for NOBOB vesselsNOBOB-S: Salinity/Brine Exposure as a Biocide for Application to NOBOB Residuals Primary

  16. Nonlinear Thermal Transport and Brine Convection in First Year Sea Ice

    E-Print Network [OSTI]

    Nonlinear Thermal Transport and Brine Convection in First Year Sea Ice M.J. McGuinness \\Lambda , H a programme recently set up to directly measure the thermal conductivity of young sea ice. An array of thermistors frozen into first­year Antarctic sea ice provides temperature against depth data, which is fitted

  17. Selenium Biotransformations in an Engineered Aquatic Ecosystem for Bioremediation of Agricultural Wastewater via Brine Shrimp

    E-Print Network [OSTI]

    Selenium Biotransformations in an Engineered Aquatic Ecosystem for Bioremediation of Agricultural Wastewater via Brine Shrimp Production Radomir Schmidt,, Prapakorn Tantoyotai, Sirine C. Fakra, Matthew A, Saskatchewan S7N 5E2, Canada United States Department of Agriculture, Agricultural Research Service, SJVASC

  18. Sulfate Removal from Reject Brined in Inland Desalination with Zero Liquid Discharge 

    E-Print Network [OSTI]

    Almasri, Dema A

    2013-07-03T23:59:59.000Z

    Sulfate is one of the most problematic ions present in reject brine in desalination systems due to its high potential of scale formation and membrane fouling; making it an obstacle in the application of zero liquid discharge. The ultra-high lime...

  19. Salt Brine Blending to Optimize Deicing and Anti-icing Performance and Cost

    E-Print Network [OSTI]

    Minnesota, University of

    Salt Brine Blending to Optimize Deicing and Anti-icing Performance and Cost Effectiveness Stephen J in Method? #12;Deicing and Anti-icing Treatments ·Sodium Chloride (NaCl) ·Cargill, NA Salt ·Magnesium Chloride (MgCl2) w/additives ·Envirotech Serv., Scotwood Ind., NA Salt ·Calcium Chloride (CaCl2) ·Tiger

  20. Investigation of oil injection into brine for the Strategic Petroleum Reserve : hydrodynamics and mixing experiments with SPR liquids.

    SciTech Connect (OSTI)

    Castaneda, Jaime N.; Cote, Raymond O.; Torczynski, John Robert; O'Hern, Timothy John

    2004-05-01T23:59:59.000Z

    An experimental program was conducted to study a proposed approach for oil reintroduction in the Strategic Petroleum Reserve (SPR). The goal was to assess whether useful oil is rendered unusable through formation of a stable oil-brine emulsion during reintroduction of degassed oil into the brine layer in storage caverns. An earlier report (O'Hern et al., 2003) documented the first stage of the program, in which simulant liquids were used to characterize the buoyant plume that is produced when a jet of crude oil is injected downward into brine. This report documents the final two test series. In the first, the plume hydrodynamics experiments were completed using SPR oil, brine, and sludge. In the second, oil reinjection into brine was run for approximately 6 hours, and sampling of oil, sludge, and brine was performed over the next 3 months so that the long-term effects of oil-sludge mixing could be assessed. For both series, the experiment consisted of a large transparent vessel that is a scale model of the proposed oil-injection process at the SPR. For the plume hydrodynamics experiments, an oil layer was floated on top of a brine layer in the first test series and on top of a sludge layer residing above the brine in the second test series. The oil was injected downward through a tube into the brine at a prescribed depth below the oil-brine or sludge-brine interface. Flow rates were determined by scaling to match the ratio of buoyancy to momentum between the experiment and the SPR. Initially, the momentum of the flow produces a downward jet of oil below the tube end. Subsequently, the oil breaks up into droplets due to shear forces, buoyancy dominates the flow, and a plume of oil droplets rises to the interface. The interface was deflected upward by the impinging oil-brine plume. Videos of this flow were recorded for scaled flow rates that bracket the equivalent pumping rates in an SPR cavern during injection of degassed oil. Image-processing analyses were performed to quantify the penetration depth and width of the oil jet. The measured penetration depths were shallow, as predicted by penetration-depth models, in agreement with the assumption that the flow is buoyancy-dominated, rather than momentum-dominated. The turbulent penetration depth model overpredicted the measured values. Both the oil-brine and oil-sludge-brine systems produced plumes with hydrodynamic characteristics similar to the simulant liquids previously examined, except that the penetration depth was 5-10% longer for the crude oil. An unexpected observation was that centimeter-size oil 'bubbles' (thin oil shells completely filled with brine) were produced in large quantities during oil injection. The mixing experiments also used layers of oil, sludge, and brine from the SPR. Oil was injected at a scaled flow rate corresponding to the nominal SPR oil injection rates. Injection was performed for about 6 hours and was stopped when it was evident that brine was being ingested by the oil withdrawal pump. Sampling probes located throughout the oil, sludge, and brine layers were used to withdraw samples before, during, and after the run. The data show that strong mixing caused the water content in the oil layer to increase sharply during oil injection but that the water content in the oil dropped back to less than 0.5% within 16 hours after injection was terminated. On the other hand, the sediment content in the oil indicated that the sludge and oil appeared to be well mixed. The sediment settled slowly but the oil had not returned to the baseline, as-received, sediment values after approximately 2200 hours (3 months). Ash content analysis indicated that the sediment measured during oil analysis was primarily organic.

  1. Effect of petroleum oil, pesticides, PCBs and other environmental contaminants on the hatchability of Artemia salina dry eggs

    SciTech Connect (OSTI)

    Kuwabara, K.; Nakamura, A.; Kashimoto, T.

    1980-07-01T23:59:59.000Z

    Artemia salina Leach is well-known as the brine shrimp used as tropical fish food and its dry eggs are easily obtained at a pet-shop at any season. One or two days after placing the dry eggs into salt water, the nauplius larvae of Artemia begins to hatch. In this paper, the methodlogy on a hatchability test for environmental contaminants and their effects on the dry egg hatchabilities are presented.

  2. Chemistry of brines in salt from the Waste Isolation Pilot Plant (WIPP), southeastern New Mexico: a preliminary investigation

    SciTech Connect (OSTI)

    Stein, C.L.; Krumhansl, J.L.

    1986-03-01T23:59:59.000Z

    We present here analyses of macro- and microscopic (intracrystalline) brines observed within the WIPP facility and in the surrounding halite, with interpretations regarding the origin and history of these fluids and their potential effect(s) on long-term waste storage. During excavation, several large fluid inclusions were recovered from an area of highly recrystallized halite in a thick salt bed at the repository horizon (2150 ft below ground level). In addition, 52 samples of brine ''weeps'' were collected from walls of recently excavated drifts at the same stratigraphic horizon from which the fluid inclusion samples are assumed to have been taken. Analyses of these fluids show that they differ substantially in composition from the inclusion fluids and cannot be explained by mixing of the fluid inclusion populations. Finally, holes in the facility floor that filled with brine were sampled but with no stratographic control; therefore it is not possible to interpret the compositions of these brines with any accuracy, except insofar as they resemble the weep compositions but with greater variation in both K/Mg and Na/Cl ratios. However, the Ca and SO/sub 4/ values for the floor holes are relatively close to the gypsum saturation curve, suggesting that brines filling floor holes have been modified by the presence of gypsum or anhydrite, possibly even originating in one or more of the laterally continuous anhydrite units referred to in the WIPP literature as marker beds. In conclusion, the wide compositional variety of fluids found in the WIPP workings suggest that (1) an interconnected hydrologic system which could effectively transport radonuclides away from the repository does not exist; (2) brine migration studies and experiments must consider the mobility of intergranular fluids as well as those in inclusions; and (3) near- and far-field radionuclide migration testing programs need to consider a wide range of brine compositions rather than a few reference brines.

  3. West Hackberry Brine Disposal Project pre-discharge characterization. Final report

    SciTech Connect (OSTI)

    DeRouen, L.R.; Hann, R.W.; Casserly, D.M.; Giammona, C. (eds.) [eds.

    1982-01-01T23:59:59.000Z

    The physical, chemical and biological attributes are described for: (1) a coastal marine environment centered about a Department of Energy Strategic Petroleum Reserve (SPR) brine disposal site 11.4 km off the southwest coast of Louisiana; and (2) the lower Calcasieu and Sabine estuarine systems that provide leach waters for the SPR project. A three month sampling effort, February through April 1981, and previous investigations from the study area are integrated to establish baseline information for evaluation of impacts from brine disposal in the nearshore marine waters and from freshwater withdrawal from the coastal marsh of the Chenier Plain. January data are included for some tasks that sampled while testing and mobilizing their instruments prior to the February field effort. The study addresses the areas of physical oceanography, estuarine hydrology and hydrography, water and sediment quality, benthos, nekton, phytoplankton, zooplankton, and data management.

  4. Recovery Act: Molecular Simulation of Dissolved Inorganic Carbons for Underground Brine CO2 Sequestration

    SciTech Connect (OSTI)

    Goddard, William

    2012-11-30T23:59:59.000Z

    To further our understanding and develop the method for measuring the DICs under geological sequestration conditions, we studied the infrared spectra of DICs under high pressure and temperature conditions. First principles simulations of DICs in brine conditions were performed using a highly optimized ReaxFF-DIC forcefield. The thermodynamics stability of each species were determined using the 2PT method, and shown to be consistent with the Reax simulations. More importantly, we have presented the IR spectra of DIC in real brine conditions as a function of temperature and pressure. At near earth conditions, we find a breaking of the O-C-O bending modes into asymmetric and symmetric modes, separated by 100cm{sup -1} at 400K and 5 GPa. These results can now be used to calibrate FTIR laser measurements.

  5. Aromatic hydrocarbons associated with brines from geopressured wells. Annual report, fiscal 1985

    SciTech Connect (OSTI)

    Keeley, D.F.; Meriwether, J.R.

    1985-01-01T23:59:59.000Z

    Samples of cryocondensates - materials condensed at - 78.5/sup 0/C were taken on a regular basis from the gas stream for the USDOE geopressured wells. Most of the data has been taken from the Gladys McCall well as it has flowed on a regular and almost continous basis. The cryocondensates, not the ''condensate'' from gas wells, are almost exclusively aromatic hydrocarbons, primarily benzene, toluene, ethylbenzene, and the xylenes, but contain over 95 compounds, characterized using gas chromatographic-mass spectroscopy. The solubility in water and brine of benezene, toluene, ethylbenzene and o-xylene, some of the components of the cryocondensate, as well as distribution coefficients between water or brine and a standard oil have been measured. 25 refs.

  6. Biochemical solubilization of toxic salts from residual geothermal brines and waste waters

    DOE Patents [OSTI]

    Premuzic, Eugene T. (East Moriches, NY); Lin, Mow S. (Rocky Point, NY)

    1994-11-22T23:59:59.000Z

    A method of solubilizing metal salts such as metal sulfides in a geothermal sludge using mutant Thiobacilli selected for their ability to metabolize metal salts at high temperature is disclosed, The method includes the introduction of mutated Thiobacillus ferrooxidans and Thiobacillus thiooxidans to a geothermal sludge or brine. The microorganisms catalyze the solubilization of metal salts, For instance, in the case of metal sulfides, the microorganisms catalyze the solubilization to form soluble metal sulfates.

  7. Biochemical solubilization of toxic salts from residual geothermal brines and waste waters

    DOE Patents [OSTI]

    Premuzic, E.T.; Lin, M.S.

    1994-11-22T23:59:59.000Z

    A method of solubilizing metal salts such as metal sulfides in a geothermal sludge using mutant Thiobacilli selected for their ability to metabolize metal salts at high temperature is disclosed. The method includes the introduction of mutated Thiobacillus ferrooxidans and Thiobacillus thiooxidans to a geothermal sludge or brine. The microorganisms catalyze the solubilization of metal salts. For instance, in the case of metal sulfides, the microorganisms catalyze the solubilization to form soluble metal sulfates. 54 figs.

  8. Sulfate Removal from Reject Brined in Inland Desalination with Zero Liquid Discharge

    E-Print Network [OSTI]

    Almasri, Dema A

    2013-07-03T23:59:59.000Z

    SULFATE REMOVAL FROM REJECT BRINED IN INLAND DESALINATION WITH ZERO LIQUID DISCHARGE A Thesis by DEMA ALMASRI Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements... and help. I am thankful for my colleagues for their inspiration and assistance throughout the years in Texas A&M at Qatar. I am also grateful to my exceptional friends that were always there during my ups and downs. I am thankful for my irreplaceable...

  9. Energy optimization in ice hockey halls I. The system COP as a multivariable function, brine and design choices

    E-Print Network [OSTI]

    Andrea Ferrantelli; Paul Melóis; Miska Räikkönen; Martti Viljanen

    2013-05-03T23:59:59.000Z

    This work is the first in a series of articles addressing the energy optimization in ice hockey halls. Here we adopt an analytical method, called functional optimization, to find which design and operating conditions maximize the Coefficient Of Performance of the entire cooling system (brine pumps and cooling tower), which we call ${\\rm COP}_{sys}$. This is addressed as a function of several variables, like electric consumption and brine physical properties. By maximizing such function, the best configuration and brine choices for the system can thus be determined accurately and rigorously. We investigate the importance of pipe diameter, depth and brine type (ethylene glycol and ammonia) for average-sized ice rinks. An optimal brine density is found, and we compute the weight of the electric consumption of the brine pumps on ${\\rm COP}_{sys}$. Our formulas are validated with heat flow measurement data obtained at an ice hockey hall in Finland. They are also confronted with technical and cost-related constraints, and implemented by simulations with the program COMSOL Multiphysics. The multivariable approach here discussed is general, and can be applied to the rigorous preliminary study of diverse situations in building physics and in many other areas of interest.

  10. Tolerance to cadmium and cadmium-binding ligands in Great Salt Lake brine shrimp (Artemia salina)

    SciTech Connect (OSTI)

    Jayasekara, S.; Drown, D.B.; Sharma, R.P.

    1986-02-01T23:59:59.000Z

    Information on the accumulation of cadmium in cytosolic proteins of Great Lake brine shrimp (Artemia salina) was obtained from animals collected directly from the lake and also from animal hatched and maintained in three sublethal concentrations of cadmium (0.5, 2.0, 5.0 ppm) in saltwater aquaria. Brine shrimp growth under these conditions was monitored by measuring body lengths during a 7-day exposure period. Heat-stable, cadmium-binding ligands were isolated and identified by Sephadex G-75 chromatography and atomic absorption spectrophotometry. Cadmium was found to be equally distributed between high and low molecular weight proteins in animals collected from the lake and the 0.5 ppm cadmium group. There was also a slight growth stimulation noted in the 0.5-pm group. Higher cadmium incorporation was noted in low molecular weight fractions with increasing cadmium concentration in the exposure media. Low molecular weight fractions were also found to have high uv absorption characteristics at 250 nm and low absorption at 280 nm. Molecular weight of the cadmium-binding ligands was found to be 11,000 as estimated by the gel filtration method. De novo synthesis of this protein was increased as a function of cadmium concentration in the media. However, slow accumulation of cadmium in other protein fractions was also noticed in higher cadmium exposure groups, suggesting the existence of possible tolerance mechanisms in brine shrimp exposed to suspected acute cadmium concentrations.

  11. Utilizing rare earth elements as tracers in high TDS reservoir brines in CCS applications

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    McLing, Travis; Smith, William; Smith, Robert

    2014-01-01T23:59:59.000Z

    In this paper we report the result of research associated with the testing of a procedures necessary for utilizing natural occurring trace elements, specifically the Rare Earth Elements (REE) as geochemical tracers in Carbon Capture and Storage (CCS) applications. Trace elements, particularly REE may be well suited to serve as in situ tracers for monitoring geochemical conditions and the migration of CO?-charged waters within CCS storage systems. We have been conducting studies to determine the efficacy of using REE as a tracer and characterization tool in the laboratory, at a CCS analogue site in Soda Springs, Idaho, and at amore »proposed CCS reservoir at the Rock Springs Uplift, Wyoming. Results from field and laboratory studies have been encouraging and show that REE may be an effective tracer in CCS systems and overlying aquifers. In recent years, a series of studies using REE as a natural groundwater tracer have been conducted successfully at various locations around the globe. Additionally, REE and other trace elements have been successfully used as in situ tracers to describe the evolution of deep sedimentary Basins. Our goal has been to establish naturally occurring REE as a useful monitoring measuring and verification (MMV) tool in CCS research because formation brine chemistry will be particularly sensitive to changes in local equilibrium caused by the addition of large volumes of CO?. Because brine within CCS target formations will have been in chemical equilibrium with the host rocks for millions of years, the addition of large volumes of CO? will cause reactions in the formation that will drive changes to the brine chemistry due to the pH change caused by the formation of carbonic acid. This CO? driven change in formation fluid chemistry will have a major impact on water rock reaction equilibrium in the formation, which will impart a change in the REE fingerprint of the brine that can measured and be used to monitor in situ reservoir conditions. Our research has shown that the REE signature imparted to the formation fluid by the introduction of CO? to the formation, can be measured and tracked as part of an MMV program. Additionally, this REE fingerprint may serve as an ideal tracer for fluid migration, both within the CCS target formation, and should formation fluids migrate into overlying aquifers. However application of REE and other trace elements to CCS system is complicated by the high salt content of the brines contained within the target formations. In the United States by regulation, in order for a geologic reservoir to be considered suitable for carbon storage, it must contain formation brine with total dissolved solids (TDS) > 10,000 ppm, and in most cases formation brines have TDS well in excess of that threshold. The high salinity of these brines creates analytical problems for elemental analysis, including element interference with trace metals in Inductively Coupled Plasma Mass Spectroscopy (ICP-MS) (i.e. element mass overlap due to oxide or plasma phenomenon). Additionally, instruments like the ICP-MS that are sensitive enough to measure trace elements down to the parts per trillion level are quickly oversaturated when water TDS exceeds much more than 1,000 ppm. Normally this problem is dealt with through dilution of the sample, bringing the water chemistry into the instruments working range. However, dilution is not an option when analyzing these formation brines for trace metals, because trace elements, specifically the REE, which occur in aqueous solutions at the parts per trillion levels. Any dilution of the sample would make REE detection impossible. Therefore, the ability to use trace metals as in situ natural tracers in high TDS brines environments requires the development of methods for pre-concentrating trace elements, while reducing the salinity and associated elemental interference such that the brines can be routinely analyzed by standard ICP-MS methods. As part of the Big Sky Carbon Sequestration Project the INL-CAES has developed a rapid, easy to use proces

  12. PILOT TESTING: PRETREATMENT OPTIONS TO ALLOW RE-USE OF FRAC FLOWBACK AND PRODUCED BRINE FOR GAS SHALE RESOURCE DEVELOPMENT

    SciTech Connect (OSTI)

    Burnett, David

    2012-12-31T23:59:59.000Z

    The goal of the A&M DOE NETL Project No. DE-FE0000847 was to develop a mobile, multifunctional water treatment capability designed specifically for “pre-treatment” of field waste brine. The project consisted of constructing s mobile “field laboratory” incorporating new technology for treating high salinity produced water and using the lab to conduct a side-by-side comparison between this new technology and that already existing in field operations. A series of four field trials were performed utilizing the mobile unit to demonstrate the effectiveness of different technology suitable for use with high salinity flow back brines and produced water. The design of the mobile unit was based on previous and current work at the Texas A&M Separation Sciences Pilot Plant. The several treatment techniques which have been found to be successful in both pilot plant and field tests had been tested to incorporate into a single multifunctional process train. Eight different components were evaluated during the trials, two types of oil and grease removal, one BTEX removal step, three micro-filters, and two different nanofilters. The performance of each technique was measured by its separation efficiency, power consumption, and ability to withstand fouling. The field trials were a success. Four different field brines were evaluated in the first trial in New York. Over 16,000 gallons of brine were processed. Using a power cost of $.10 per kWh, media pretreatment power use averaged $0.004 per barrel, solids removal $.04 per barrel and brine “softening” $.84 per barrel. Total power cost was approximately $1.00 per barrel of fluid treated. In Pennsylvania, brines collected from frac ponds were tested in two additional trials. Each of the brines was converted to an oil-free, solids-free brine with no biological activity. Brines were stable over time and would be good candidates for use as a make-up fluid in a subsequent fracturing fluid design. Reports on all of the field trials and subcontractor research have been summarized in this Final Report. Individual field trial reports and research reports are contained in the companion volume titled “Appendices”

  13. Advanced biochemical processes for geothermal brines FY 1998 annual operating plan

    SciTech Connect (OSTI)

    NONE

    1997-10-01T23:59:59.000Z

    As part of the overall Geothermal Energy Research which is aimed at the development of economical geothermal resources production systems, the aim of the Advanced Biochemical Processes for Geothermal Brines (ABPGB) effort is the development of economic and environmentally acceptable methods for disposal of geothermal wastes and conversion of by-products to useful forms. Methods are being developed for dissolution, separation and immobilization of geothermal wastes suitable for disposal, usable in inert construction materials, suitable for reinjection into the reservoir formation, or used for recovery of valuable metals.

  14. Bioremediation of contaminated groundwater

    DOE Patents [OSTI]

    Hazen, Terry C. (Augusta, GA); Fliermans, Carl B. (Augusta, GA)

    1995-01-01T23:59:59.000Z

    An apparatus and method for in situ remediation of contaminated subsurface soil or groundwater contaminated by chlorinated hydrocarbons. A nutrient fluid is selected to stimulate the growth and reproduction of indigenous subsurface microorganisms that are capable of degrading the contaminants; an oxygenated fluid is selected to create a generally aerobic environment for these microorganisms to degrade the contaminants, leaving only pockets that are anaerobic. The nutrient fluid is injected periodically while the oxygenated fluid is injected continuously and both are extracted so that both are drawn across the plume. The nutrient fluid stimulates microbial colony growth; withholding it periodicially forces the larger, healthy colony of microbes to degrade the contaminants. Treatment is continued until the subsurface concentration of contaminants is reduced to an acceptable, preselected level. The nutrient fluid can be methane and the oxygenated fluid air for stimulating production of methanotrophs to break down chlorohydrocarbons, especially trichloroethylene (TCE) and tetrachloroethylene.

  15. Bioremediation of contaminated groundwater

    DOE Patents [OSTI]

    Hazen, T.C.; Fliermans, C.B.

    1995-01-24T23:59:59.000Z

    An apparatus and method are described for in situ remediation of contaminated subsurface soil or groundwater contaminated by chlorinated hydrocarbons. A nutrient fluid is selected to stimulate the growth and reproduction of indigenous subsurface microorganisms that are capable of degrading the contaminants. An oxygenated fluid is selected to create a generally aerobic environment for these microorganisms to degrade the contaminants, leaving only pockets that are anaerobic. The nutrient fluid is injected periodically while the oxygenated fluid is injected continuously and both are extracted so that both are drawn across the plume. The nutrient fluid stimulates microbial colony growth. Withholding it periodically forces the larger, healthy colony of microbes to degrade the contaminants. Treatment is continued until the subsurface concentration of contaminants is reduced to an acceptable, preselected level. The nutrient fluid can be methane and the oxygenated fluid air for stimulating production of methanotrophs to break down chlorohydrocarbons, especially trichloroethylene (TCE) and tetrachloroethylene. 3 figures.

  16. Contamination analysis unit

    DOE Patents [OSTI]

    Gregg, Hugh R. (Livermore, CA); Meltzer, Michael P. (Livermore, CA)

    1996-01-01T23:59:59.000Z

    The portable Contamination Analysis Unit (CAU) measures trace quantifies of surface contamination in real time. The detector head of the portable contamination analysis unit has an opening with an O-ring seal, one or more vacuum valves and a small mass spectrometer. With the valve closed, the mass spectrometer is evacuated with one or more pumps. The O-ring seal is placed against a surface to be tested and the vacuum valve is opened. Data is collected from the mass spectrometer and a portable computer provides contamination analysis. The CAU can be used to decontaminate and decommission hazardous and radioactive surface by measuring residual hazardous surface contamination, such as tritium and trace organics It provides surface contamination data for research and development applications as well as real-time process control feedback for industrial cleaning operations and can be used to determine the readiness of a surface to accept bonding or coatings.

  17. Contamination analysis unit

    DOE Patents [OSTI]

    Gregg, H.R.; Meltzer, M.P.

    1996-05-28T23:59:59.000Z

    The portable Contamination Analysis Unit (CAU) measures trace quantities of surface contamination in real time. The detector head of the portable contamination analysis unit has an opening with an O-ring seal, one or more vacuum valves and a small mass spectrometer. With the valve closed, the mass spectrometer is evacuated with one or more pumps. The O-ring seal is placed against a surface to be tested and the vacuum valve is opened. Data is collected from the mass spectrometer and a portable computer provides contamination analysis. The CAU can be used to decontaminate and decommission hazardous and radioactive surfaces by measuring residual hazardous surface contamination, such as tritium and trace organics. It provides surface contamination data for research and development applications as well as real-time process control feedback for industrial cleaning operations and can be used to determine the readiness of a surface to accept bonding or coatings. 1 fig.

  18. Advanced Membrane Filtration Technology for Cost Effective Recovery of Fresh Water from Oil & Gas Produced Brine

    SciTech Connect (OSTI)

    David B. Burnett

    2004-09-29T23:59:59.000Z

    Produced water is a major waste generated at the oil and natural gas wells in the state of Texas. This water could be a possible source of new fresh water to meet the growing demands of the state after treatment and purification. Treatment of brine generated in oil fields or produced water with an ultrafiltration membranes were the subject of this thesis. The characterization of ultrafiltration membranes for oil and suspended solids removal of produced water, coupled with the reverse osmosis (RO) desalination of brine were studied on lab size membrane testing equipment and a field size testing unit to test whether a viable membrane system could be used to treat produced water. Oil and suspended solids were evaluated using turbidity and oil in water measurements taken periodically. The research considered the effect of pressure and flow rate on membrane performance of produced water treatment of three commercially available membranes for oily water. The study also analyzed the flux through the membrane and any effect it had on membrane performance. The research showed that an ultrafiltration membrane provided turbidity removal of over 99% and oil removal of 78% for the produced water samples. The results indicated that the ultrafiltration membranes would be asset as one of the first steps in purifying the water. Further results on selected RO membranes showed that salt rejection of greater than 97% could be achieved with satisfactory flux and at reasonable operating cost.

  19. Fluid sampling and chemical modeling of geopressured brines containing methane. Final report, March 1980-February 1981

    SciTech Connect (OSTI)

    Dudak, B.; Galbraith, R.; Hansen, L.; Sverjensky, D.; Weres, O.

    1982-07-01T23:59:59.000Z

    The development of a flowthrough sampler capable of obtaining fluid samples from geopressured wells at temperatures up to 400/sup 0/F and pressures up to 20,000 psi is described. The sampler has been designed, fabricated from MP35N alloy, laboratory tested, and used to obtain fluid samples from a geothermal well at The Geysers, California. However, it has not yet been used in a geopressured well. The design features, test results, and operation of this device are described. Alternative sampler designs are also discussed. Another activity was to review the chemistry and geochemistry of geopressured brines and reservoirs, and to evaluate the utility of available computer codes for modeling the chemistry of geopressured brines. The thermodynamic data bases for such codes are usually the limiting factor in their application to geopressured systems, but it was concluded that existing codes can be updated with reasonable effort and can usefully explain and predict the chemical characteristics of geopressured systems, given suitable input data.

  20. Modeling Coupled THMC Processes and Brine Migration in Salt at High Temperatures

    SciTech Connect (OSTI)

    Rutqvist, Jonny; Blanco Martin, Laura; Mukhopadhyay, Sumit; Houseworth, Jim; Birkholzer, Jens

    2014-08-14T23:59:59.000Z

    In this report, we present FY2014 progress by Lawrence Berkeley National Laboratory (LBNL) related to modeling of coupled thermal-hydrological-mechanical-chemical (THMC) processes in salt and their effect on brine migration at high temperatures. LBNL’s work on the modeling of coupled THMC processes in salt was initiated in FY2012, focusing on exploring and demonstrating the capabilities of an existing LBNL modeling tool (TOUGH-FLAC) for simulating temperature-driven coupled flow and geomechanical processes in salt. This work includes development related to, and implementation of, essential capabilities, as well as testing the model against relevant information and published experimental data related to the fate and transport of water. we provide more details on the FY2014 work, first presenting updated tools and improvements made to the TOUGH-FLAC simulator, and the use of this updated tool in a new model simulation of long-term THM behavior within a generic repository in a salt formation. This is followed by the description of current benchmarking and validations efforts, including the TSDE experiment. We then present the current status in the development of constitutive relationships and the dual-continuum model for brine migration. We conclude with an outlook for FY2015, which will be much focused on model validation against field experiments and on the use of the model for the design studies related to a proposed heater experiment.

  1. Summary Results for Brine Migration Modeling Performed by LANL LBNL and SNL for the UFD Program

    SciTech Connect (OSTI)

    Kuhlman, Kristopher L

    2014-09-01T23:59:59.000Z

    This report summarizes laboratory and field observations and numerical modeling related to coupled processes involving brine and vapor migration in geologic salt, focusing on recent developments and studies conducted at Sandia, Los Alamos, and Berkeley National Laboratories. Interest into the disposal of heat-generating waste in salt has led to interest into water distribution and migration in both run-of-mine crushed and intact geologic salt. Ideally a fully coupled thermal-hydraulic-mechanical-chemical simulation is performed using numerical models with validated constitutive models and parameters. When mechanical coupling is not available, mechanical effects are prescribed in hydraulic models as source, boundary, or initial conditions. This report presents material associated with developing appropriate initial conditions for a non-mechanical hydrologic simulation of brine migration in salt. Due to the strong coupling between the mechanical and hydrologic problems, the initial saturation will be low for the excavation disturbed zone surrounding the excavation. Although most of the material in this report is not new, the author hopes it is presented in a format making it useful to other salt researchers.

  2. Contamination Control Techniques

    SciTech Connect (OSTI)

    EBY, J.L.

    2000-05-16T23:59:59.000Z

    Welcome to a workshop on contamination Control techniques. This work shop is designed for about two hours. Attendee participation is encouraged during the workshop. We will address different topics within contamination control techniques; present processes, products and equipment used here at Hanford and then open the floor to you, the attendees for your input on the topics.

  3. Bioremediation of contaminated groundwater

    DOE Patents [OSTI]

    Hazen, T.C.; Fliermans, C.B.

    1994-01-01T23:59:59.000Z

    Disclosed is an apparatus and method for in situ remediation of contaminated subsurface soil or groundwater contaminated by chlorinated hydrocarbons. A nutrient fluid (NF) is selected to simulated the growth and reproduction of indigenous subsurface microorganisms capable of degrading the contaminants; an oxygenated fluid (OF) is selected to create an aerobic environment with anaerobic pockets. NF is injected periodically while OF is injected continuously and both are extracted so that both are drawn across the plume. NF stimulates microbial colony growth; withholding it periodically forces the larger, healthy colony of microbes to degrade the contaminants. Treatment is continued until the subsurface concentration of contaminants is acceptable. NF can be methane and OF be air, for stimulating production of methanotrophs to break down chlorohydrocarbons, especially TCE and tetrachloroethylene.

  4. Water 2013, 5, 480-504; doi:10.3390/w5020480 ISSN 2073-4441

    E-Print Network [OSTI]

    to characterize geochemical processes in a complex coastal groundwater system and to provide constraints of native groundwater, intruded seawater, non-native injected water, and oil-field brine water. In some with oil-field brines. Groundwater 3 H above 1 tritium unit (TU) was observed only in a few select wells

  5. Barton, M.D.and Johnson, D.A., 2000 -Alternative Brine Sources for Fe-Oxide (-Cu-Au) Systems: Implications for Hydrothermal Alteration and Metals; in Porter, T.M. (Ed.),

    E-Print Network [OSTI]

    Barton, Mark D.

    Barton, M.D.and Johnson, D.A., 2000 -Alternative Brine Sources for Fe-Oxide (-Cu-Au) Systems-Gold &Related Deposits: AGlobal Perspective, Australian Mineral Foundation, Adelaide, pp 43-60 ALTERNATIVE BRINE, and the broader geologic setting(s). Geologic and geochemical evidence show that the ore-forming fluids are brines

  6. Bioremediation of contaminated sediments

    SciTech Connect (OSTI)

    Hughes, J.B.; Jee, V.; Ward, C.H. [Rice Univ., Houston, TX (United States)

    1995-10-01T23:59:59.000Z

    Contaminants in bottom sediments have historically been considered to have minimal environmental impact because they are buried, sorbed or electrostatically bound to clay particles, or incorporated into humus. Physical and chemical conditions such as alkalinity, pH, and redox of the sediments also play a part in sequestering contaminants. As long as the sediments are undisturbed, the contaminants are considered stabilized and not an immediate environmental problem. Resuspension of bottom sediments makes contaminants more available for dispersal into the marine environment. Events that can cause resuspension include storm surges, construction activity, and dredging. During resuspension, sediment particles move from an anaerobic to aerobic environment, changing their redox characteristics, and allowing the indigenous aerobic bacteria to grow and utilize certain classes of contaminants as energy sources. The contaminants are also more available for use because the mixing energy imparted to the particles during resuspension enhances mass transfer, allowing contaminants to enter the aqueous phase more rapidly. The contaminants targeted in this research are polynuclear aromatic hydrocarbons (PAHs), a class of contaminant commonly found in bottom sediments near highly industrialized areas. PAH sources include fossil fuel combustion and petroleum spills. Previous research has shown that PAHs can be biodegraded. Size and structure, i.e., number and configuration of condensed rings, can affect compound disappearance. The focus of this research was to examine the relationship between resuspension and biodegradation of PAHs in lab scale slurry reactors. The rate and extent of contaminant release from the sediments into an uncontaminated water column was determined. Oxygen demand of initially anaerobic sediments were investigated. Then rate and extent of phenanthrene biodegradation was examined.

  7. Data Center Economizer Contamination and Humidity Study

    E-Print Network [OSTI]

    Shehabi, Arman

    2010-01-01T23:59:59.000Z

    Data Center Economizer Contamination and Humidity Studyoccupants. To investigate contamination levels, particlemethod of collecting contamination readings. The system,

  8. Subsurface contaminants focus area

    SciTech Connect (OSTI)

    NONE

    1996-08-01T23:59:59.000Z

    The US Department of Enregy (DOE) Subsurface Contaminants Focus Area is developing technologies to address environmental problems associated with hazardous and radioactive contaminants in soil and groundwater that exist throughout the DOE complex, including radionuclides, heavy metals; and dense non-aqueous phase liquids (DNAPLs). More than 5,700 known DOE groundwater plumes have contaminated over 600 billion gallons of water and 200 million cubic meters of soil. Migration of these plumes threatens local and regional water sources, and in some cases has already adversely impacted off-site rsources. In addition, the Subsurface Contaminants Focus Area is responsible for supplying technologies for the remediation of numerous landfills at DOE facilities. These landfills are estimated to contain over 3 million cubic meters of radioactive and hazardous buried Technology developed within this specialty area will provide efective methods to contain contaminant plumes and new or alternative technologies for development of in situ technologies to minimize waste disposal costs and potential worker exposure by treating plumes in place. While addressing contaminant plumes emanating from DOE landfills, the Subsurface Contaminants Focus Area is also working to develop new or alternative technologies for the in situ stabilization, and nonintrusive characterization of these disposal sites.

  9. Energy optimization in ice hockey halls I. The system COP as a multivariable function, brine and design choices

    E-Print Network [OSTI]

    Ferrantelli, Andrea; Räikkönen, Miska; Viljanen, Martti

    2012-01-01T23:59:59.000Z

    This work is the first of a series of articles addressing the energy optimization in ice hockey halls. Here we outline an analytic method to predict in which design and operating conditions the COP of the entire cooling system (refrigerator and cooling tower) ${\\rm COP}_{sys}$ is maximum. ${\\rm COP}_{sys}$ is investigated as a function of several variables, like electric consumption and brine physical properties. With this method, the best configuration and brine choices for the system can therefore be determined in advance. We estimate the optimal design of an average-sized ice rink, including pipe diameter, depth and brine type (ethylene glycol and ammonia). We also single out an optimal brine density and show the impact of the electric consumption of the pump on ${\\rm COP}_{sys}$. Our theoretical predictions are validated with heat flow measurement data obtained at an ice hockey hall in Finland. They are also confronted with technical and cost-related constraints, and implemented by simulations with the pr...

  10. Predicting PVT data for CO2brine mixtures for black-oil simulation of CO2 geological storage

    E-Print Network [OSTI]

    Santos, Juan

    Predicting PVT data for CO2­brine mixtures for black-oil simulation of CO2 geological storage efficiency of the black-oil approach promote application of black-oil simulation for large-scale geological into geological formations has been considered as a potential method to mitigate climate change. Accurate

  11. Macro-and Microscale Waterflooding Performances of Crudes which form w/o Emulsions upon Mixing with Brines

    E-Print Network [OSTI]

    Firoozabadi, Abbas

    Macro- and Microscale Waterflooding Performances of Crudes which form w/o Emulsions upon Mixing with Brines N. Rezaei and A. Firoozabadi*,, Reservoir Engineering Research Institute, 595 Lytton Avenue, Palo ABSTRACT: We study the micro- and macroscale waterflooding performances of unusual crudes which naturally

  12. 2. INVESTIGATION OF CRUDE OIL/BRINE/ROCK INTERACTION 2.1 STUDY OF WATERFLOODING PROCESS IN NATURALLY FRACTURED

    E-Print Network [OSTI]

    Schechter, David S.

    , followed by waterflooding, were performed at reservoir conditions to investigate rock wettability. A two Berea and Spraberry cores at reservoir conditions to illustrate the actual process of waterflooding- 31 - 2. INVESTIGATION OF CRUDE OIL/BRINE/ROCK INTERACTION 2.1 STUDY OF WATERFLOODING PROCESS

  13. Unconventional gas sources. Executive summary. [Coal seams, Devonian shale, geopressured brines, tight gas reservoirs

    SciTech Connect (OSTI)

    Not Available

    1980-12-01T23:59:59.000Z

    The long lead time required for conversion from oil or gas to coal and for development of a synthetic fuel industry dictates that oil and gas must continue to supply the United States with the majority of its energy requirements over the near term. In the interim period, the nation must seek a resource that can be developed quickly, incrementally, and with as few environmental concerns as possible. One option which could potentially fit these requirements is to explore for, drill, and produce unconventional gas: Devonian Shale gas, coal seam gas, gas dissolved in geopressured brines, and gas from tight reservoirs. This report addresses the significance of these sources and the economic and technical conditions under which they could be developed.

  14. Unnatural landscapes in ecology: Generating the spatial distribution of brine spills

    SciTech Connect (OSTI)

    Jager, Yetta [ORNL; Efroymson, Rebecca Ann [ORNL; Sublette, K. [University of Tulsa; Ashwood, Tom L [ORNL

    2005-01-01T23:59:59.000Z

    Quantitative tools are needed to evaluate the ecological effects of increasing petroleum production. In this article, we describe two stochastic models for simulating the spatial distribution of brine spills on a landscape. One model uses general assumptions about the spatial arrangement of spills and their sizes; the second model distributes spills by siting rectangular well complexes and conditioning spill probabilities on the configuration of pipes. We present maps of landscapes with spills produced by the two methods and compare the ability of the models to reproduce a specified spill area. A strength of the models presented here is their ability to extrapolate from the existing landscape to simulate landscapes with a higher (or lower) density of oil wells.

  15. Brine-in-crude-oil emulsions at the Strategic Petroleum Reserve.

    SciTech Connect (OSTI)

    Nemer, Martin B.; Lord, David L.; MacDonald, Terry L.

    2013-10-01T23:59:59.000Z

    Metastable water-in-crude-oil emulsion formation could occur in a Strategic Petroleum Reserve (SPR) cavern if water were to flow into the crude-oil layer at a sufficient rate. Such a situation could arise during a drawdown from a cavern with a broken-hanging brine string. A high asphaltene content (> 1.5 wt %) of the crude oil provides the strongest predictor of whether a metastable water-in-crude-oil emulsion will form. However there are many crude oils with an asphaltene content > 1.5 wt % that don't form stable emulsions, but few with a low asphaltene content that do form stable emulsions. Most of the oils that form stable emulsions are %E2%80%9Csour%E2%80%9D by SPR standards indicating they contain total sulfur > 0.50 wt %.

  16. Modeling for Airborne Contamination

    SciTech Connect (OSTI)

    F.R. Faillace; Y. Yuan

    2000-08-31T23:59:59.000Z

    The objective of Modeling for Airborne Contamination (referred to from now on as ''this report'') is to provide a documented methodology, along with supporting information, for estimating the release, transport, and assessment of dose to workers from airborne radioactive contaminants within the Monitored Geologic Repository (MGR) subsurface during the pre-closure period. Specifically, this report provides engineers and scientists with methodologies for estimating how concentrations of contaminants might be distributed in the air and on the drift surfaces if released from waste packages inside the repository. This report also provides dose conversion factors for inhalation, air submersion, and ground exposure pathways used to derive doses to potentially exposed subsurface workers. The scope of this report is limited to radiological contaminants (particulate, volatile and gaseous) resulting from waste package leaks (if any) and surface contamination and their transport processes. Neutron activation of air, dust in the air and the rock walls of the drift during the preclosure time is not considered within the scope of this report. Any neutrons causing such activation are not themselves considered to be ''contaminants'' released from the waste package. This report: (1) Documents mathematical models and model parameters for evaluating airborne contaminant transport within the MGR subsurface; and (2) Provides tables of dose conversion factors for inhalation, air submersion, and ground exposure pathways for important radionuclides. The dose conversion factors for air submersion and ground exposure pathways are further limited to drift diameters of 7.62 m and 5.5 m, corresponding to the main and emplacement drifts, respectively. If the final repository design significantly deviates from these drift dimensions, the results in this report may require revision. The dose conversion factors are further derived by using concrete of sufficient thickness to simulate the drift walls. The gamma-ray scattering properties of concrete are sufficiently similar to those of the host rock and proposed insert material; use of concrete will have no significant impact on the conclusions. The information in this report is presented primarily for use in performing pre-closure radiological safety evaluations of radiological contaminants, but it may also be used to develop strategies for contaminant leak detection and monitoring in the MGR. Included in this report are the methods for determining the source terms and release fractions, and mathematical models and model parameters for contaminant transport and distribution within the repository. Various particle behavior mechanisms that affect the transport of contaminant are included. These particle behavior mechanisms include diffusion, settling, resuspension, agglomeration and other deposition mechanisms.

  17. Organic contaminant separator

    DOE Patents [OSTI]

    Del Mar, P.

    1993-12-28T23:59:59.000Z

    A process is presented of sample preparation prior to analysis for the concentration of an organic contaminant in an aqueous medium by (a) passing an initial aqueous medium including a minor amount of the organic contaminant through a composite tube comprised of a blend of a polyolefin and a polyester, the composite tube having an internal diameter of from about 0.1 to about 2.0 millimeters and being of sufficient length to permit the organic contaminant to adhere to the composite tube, (b) passing a solvent through the composite tube. The solvent is capable of separating the adhered organic contaminant from the composite tube. Further, an extraction apparatus is presented for sample preparation prior to analysis for the concentration of an organic contaminant in an aqueous medium. The apparatus includes a composite tube comprised of a blend of a polyolefin and a polyester. The composite tube has an internal diameter of from about 0.1 to about 2.0 millimeters and has sufficient length to permit an organic contaminant contained within an aqueous medium passed therethrough to adhere to the composite tube. 2 figures.

  18. Original article Salmonella typhimurium contamination

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Original article Salmonella typhimurium contamination from farm to meat in adult cattle 3 June 1997) Summary ― The aim of this work was to study the increase in hair contamination this contamination and the contamination of carcasses and of the ground beef made from these animals. l3ctween April

  19. CO2-Brine Surface Dissolution and Injection: CO2 Storage Enhancement Paul Emeka Eke, SPE, Mark Naylor, Stuart Haszeldine and Andrew Curtis, Scottish Centre for Carbon Storage,

    E-Print Network [OSTI]

    ) is capable of reducing atmospheric emissions of greenhouse gases from coal or gas fired power plants or supercritical phase, as water-alternating gas cycles, or as carbonated brine. These result in different

  20. Effects of a sulfide system produced by a natural brine seep on sandy-bottom community structure at the East Flower Garden Bank, northwest Gulf of Mexico

    E-Print Network [OSTI]

    Woods, Edward Andrew

    1982-01-01T23:59:59.000Z

    30%. Videophotography and doppler-based rangefinder measurements were used to map the seep area. Current measurements of the brine stream were made using a Savonius rotor attached to the manipulator Analysis of data was carried out using...

  1. Managing contaminated sites

    SciTech Connect (OSTI)

    Asante-Duah, D.K.

    1997-12-31T23:59:59.000Z

    This book summarizes the generic principles of contaminated site management. The book walks the reader through contaminated site identification, risk assessment and the evaluation of remediation alternatives. The book is divided into two major sections, problem diagnosis and development of site restoration. In problem diagnosis, the general principles of site investigation are discussed, including the objectives and differences between tier 1,2, and 3 investigations. The principles of data collection and analysis are presented. A small quantitative discussion of statistical analysis is presented but in keeping with the objectives of the text is not sufficient comprehensive or detailed to provide much of a guide for the practitioner. Chapters on contaminant fate and transport processes and risk assessment help the reader understand the role of these issues in site investigation and remedial planning. A chapter is also included on elements of a site characterization activity, which summarizes some of the key considerations in conducting a site investigation.

  2. Bioremediation techniques on crude oil contaminated soils in Ohio. First quarterly report, October 1, 1995--December 31, 1995

    SciTech Connect (OSTI)

    Hodges, D.

    1996-03-27T23:59:59.000Z

    The objective of this project is to develop environmentally-sound and cost-effective remediation techniques for crude oil contaminated soils. By providing a guidance manual to oil and gas operators, the Ohio Division of Oil and Gas regulatory authority hopes to reduce remediation costs while improving voluntary compliance with soil clean-up requirements. This shall be accomplished by conducting a series of field tests to define the optimum range for nutrient, oxygen and organic enhancement to biologically remediate soils contaminated with brines and crude oil having a wide range of viscosity. Task one of the bioremediation project began on July 3, 1995 with the selection and preparation of a site in Smith township. Mahoning County. The plots were arranged and parameters were varied. Plots, 1, 3, 5, 7, 9 and 11 were contaminated with 159 liters (42 gal. ) of Corning grade crude oil and plots 2, 4, 6, 8 and 12 were contaminated with 159 liters (42 gal.) of Pennsylvania grade crude oil. Plots 13 through 21 were contaminated with 159 liters (42 gal.) of Pennsylvania grade crude oil and 477 liters (126 gal.) of Clinton sandstone brine with a 160,000 mg/liter concentration of chloride. Treatment and administration of variables were conducted from August 17, 1995 to October 26, 1995. During this period samples were collected twice from each plot and analyzed for the parameters specified in the contract. Results from both sampling events of total petroleum hydrocarbons suggest that crude oil spread on surface is not easily mixed into soils as tillage depth, resulting in considerably variable composite samples from plot to plot.

  3. Benefits and costs of brine extraction for increasing injection efficiency in geologic CO2 sequestration

    SciTech Connect (OSTI)

    Davidson, Casie L.; Watson, David J.; Dooley, James J.; Dahowski, Robert T.

    2014-01-01T23:59:59.000Z

    Pressure increases attendant with CO2 injection into the subsurface drive many of the risk factors associated with commercial-scale CCS projects, impacting project costs and liabilities in a number of ways. The area of elevated pressure defines the area that must be characterized and monitored; pressure drives fluid flow out of the storage reservoir along higher-permeability pathways that might exist through the caprock into overlying aquifers or hydrocarbon reservoirs; and pressure drives geomechanical changes that could potentially impact subsurface infrastructure or the integrity of the storage system itself. Pressure also limits injectivity, which can increase capital costs associated with installing additional wells to meet a given target injection rate. The ability to mitigate pressure increases in storage reservoirs could have significant value to a CCS project, but these benefits are offset by the costs of the pressure mitigation technique itself. Of particular interest for CO2 storage operators is the lifetime cost of implementing brine extraction at a CCS project site, and the relative value of benefits derived from the extraction process. This is expected to vary from site to site and from one implementation scenario to the next. Indeed, quantifying benefits against costs could allow operators to optimize their return on project investment by calculating the most effective scenario for pressure mitigation. This work builds on research recently submitted for publication by the authors examining the costs and benefits of brine extraction across operational scenarios to evaluate the effects of fluid extraction on injection rate to assess the cost effectiveness of several options for reducing the number of injection wells required. Modeling suggests that extracting at 90% of the volumetric equivalent of injection rate resulted in a 1.8% improvement in rate over a non-extraction base case; a four-fold increase in extraction rate results in a 7.6% increase in injection rate over the no-extraction base case. However, the practical impacts on capital costs suggest that this strategy is fiscally ineffective when evaluated solely on this metric, with extraction reducing injection well needs by only one per 56 (1x case) or one per 13 (4x case).

  4. Mercury contamination extraction

    DOE Patents [OSTI]

    Fuhrmann, Mark (Silver Spring, MD); Heiser, John (Bayport, NY); Kalb, Paul (Wading River, NY)

    2009-09-15T23:59:59.000Z

    Mercury is removed from contaminated waste by firstly applying a sulfur reagent to the waste. Mercury in the waste is then permitted to migrate to the reagent and is stabilized in a mercury sulfide compound. The stable compound may then be removed from the waste which itself remains in situ following mercury removal therefrom.

  5. Subsurface Contamination Control

    SciTech Connect (OSTI)

    Y. Yuan

    2001-12-12T23:59:59.000Z

    There are two objectives of this report, ''Subsurface Contamination Control''. The first is to provide a technical basis for recommending limiting radioactive contamination levels (LRCL) on the external surfaces of waste packages (WP) for acceptance into the subsurface repository. The second is to provide an evaluation of the magnitude of potential releases from a defective WP and the detectability of the released contents. The technical basis for deriving LRCL has been established in ''Retrieval Equipment and Strategy for Wp on Pallet'' (CRWMS M and O 2000g, 6.3.1). This report updates the derivation by incorporating the latest design information of the subsurface repository for site recommendation. The derived LRCL on the external surface of WPs, therefore, supercede that described in CRWMS M and O 2000g. The derived LRCL represent the average concentrations of contamination on the external surfaces of each WP that must not be exceeded before the WP is to be transported to the subsurface facility for emplacement. The evaluation of potential releases is necessary to control the potential contamination of the subsurface repository and to detect prematurely failed WPs. The detection of failed WPs is required in order to provide reasonable assurance that the integrity of each WP is intact prior to MGR closure. An emplaced WP may become breached due to manufacturing defects or improper weld combined with failure to detect the defect, by corrosion, or by mechanical penetration due to accidents or rockfall conditions. The breached WP may release its gaseous and volatile radionuclide content to the subsurface environment and result in contaminating the subsurface facility. The scope of this analysis is limited to radioactive contaminants resulting from breached WPs during the preclosure period of the subsurface repository. This report: (1) documents a method for deriving LRCL on the external surfaces of WP for acceptance into the subsurface repository; (2) provides a table of derived LRCL for nuclides of radiological importance; (3) Provides an as low as is reasonably achievable (ALARA) evaluation of the derived LRCL by comparing potential onsite and offsite doses to documented ALARA requirements; (4) Provides a method for estimating potential releases from a defective WP; (5) Provides an evaluation of potential radioactive releases from a defective WP that may become airborne and result in contamination of the subsurface facility; and (6) Provides a preliminary analysis of the detectability of a potential WP leak to support the design of an airborne release monitoring system.

  6. Carbon contamination topography analysis of EUV masks

    E-Print Network [OSTI]

    Fan, Y.-J.

    2010-01-01T23:59:59.000Z

    induced carbon contamination of extreme ultraviolet optics,"and A. Izumi. "Carbon contamination of EL'V mask: filmEffect of Carbon Contamination on the Printing Performance

  7. Management of Transuranic Contaminated Material

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    1982-09-30T23:59:59.000Z

    To establish guidelines for the generation, treatment, packaging, storage, transportation, and disposal of transuranic (TRU) contaminated material.

  8. Radioactive Contamination of Danish Territory

    E-Print Network [OSTI]

    » & Risø-R-462 Radioactive Contamination of Danish Territory after Core-melt Accidents 1982 Risø National Laboratory, DK-4000 Roskilde, Denmark #12;RISØ-R-462 RADIOACTIVE CONTAMINATION contamination of Danish territory in the event of a core-melt accident at the Barseback nuclear power plant

  9. Radioactive Contamination of Danish Territory

    E-Print Network [OSTI]

    Risø-R-462 Radioactive Contamination of Danish Territory after Core-melt Accidents at the Barsebäck;#12;RIS0-R-462 RADIOACTIVE CONTAMINATION OF DANISH TERRITORY AFTER CORE-MELT ACCIDENTS AT THE BARSEBACK. An assessment is made of the radioactive contamination of Danish territory in the event of a core-melt accident

  10. Containment of subsurface contaminants

    DOE Patents [OSTI]

    Corey, J.C.

    1994-09-06T23:59:59.000Z

    A barrier is disclosed for reducing the spread of a plume of subsurface contaminants. The apparatus includes a well system for injecting a fluid, such as air, just outside and below the periphery of the plume. The fluid is injected at a pressure sufficient to lower the hydraulic conductivity of the soil from the point of injection to the surface thus establishing a curtain-like barrier to groundwater movement. The barrier is established upgradient of the plume to divert groundwater away, or preferably completely around the plume to reduce the flow of groundwater into or out of the plume. The barrier enables the remediation of the confined contamination and then, when the injection of the fluid is halted, the barrier quickly dissipates. 5 figs.

  11. Containment of subsurface contaminants

    DOE Patents [OSTI]

    Corey, John C. (Aiken, SC)

    1994-01-01T23:59:59.000Z

    A barrier for reducing the spread of a plume of subsurface contaminants. The apparatus includes a well system for injecting a fluid, such as air, just outside and below the periphery of the plume. The fluid is injected at a pressure sufficient to lower the hydraulic conductivity of the soil from the point of injection to the surface thus establishing a curtain-like barrier to groundwater movement. The barrier is established upgradient of the plume to divert groundwater away, or preferably completely around the plume to reduce the flow of groundwater into or out of the plume. The barrier enables the remediation of the confined contamination and then, when the injection of the fluid is halted, the barrier quickly dissipates.

  12. GROUND WATER CONTAMINATION

    SciTech Connect (OSTI)

    Unknown

    1999-09-01T23:59:59.000Z

    As required by the terms of the above referenced grant, the following summary serves as the Final Report for that grant. The grant relates to work performed at two separate sites, the Hoe Creek Underground Coal Gasification Site south of Gillette, Wyoming, and the Rock Springs In-Situ Oil Shale Retort Site near Rock Springs, Wyoming. The primary concern to the State of Wyoming at each site is ground water contamination (the primary contaminants of concern are benzene and related compounds), and the purpose of the grant has been to provide tiding for a Geohydrologist at the appropriate State agency, specifically the Land Quality Division (LQD) of the Wyoming Department of Environmental Quality. The LQD Geohydrologist has been responsible for providing technical and regulatory support to DOE for ground water remediation and subsequent surface reclamation. Substantial progress has been made toward remediation of the sites, and continuation of LQD involvement in the remediation and reclamation efforts is addressed.

  13. Indexing contamination surveys

    SciTech Connect (OSTI)

    Brown, R.L.

    1998-02-06T23:59:59.000Z

    The responsibility for safely managing the Tank Farms at Hanford belongs to Lockheed Martin Hanford Corporation which is part of the six company Project Hanford Management Team led by Fluor Daniel Hanford, Inc.. These Tank Farm Facilities contain numerous outdoor contamination areas which are surveyed at a periodicity consistent with the potential radiological conditions, occupancy, and risk of changes in radiological conditions. This document describes the survey documentation and data tracking method devised to track the results of contamination surveys this process is referred to as indexing. The indexing process takes a representative data set as an indicator for the contamination status of the facility. The data are further manipulated into a single value that can be tracked and trended using standard statistical methodology. To report meaningful data, the routine contamination surveys must be performed in a manner that allows the survey method and the data collection process to be recreated. Three key criteria are necessary to accomplish this goal: Accurate maps, consistent documentation, and consistent consolidation of data meeting these criteria provides data of sufficient quality to be tracked. Tracking of survey data is accomplished by converting the individual survey results into a weighted value, corrected for the actual number of survey points. This information can be compared over time using standard statistical analysis to identify trends. At the Tank Farms, the need to track and trend the facility`s radiological status presents unique challenges. Many of these Tank Farm facilities date back to the second world war. The Tank Farm Facilities are exposed to weather extremes, plant and animal intrusion, as well as all of the normal challenges associated with handling radiological waste streams. Routine radiological surveys did not provide a radiological status adequate for continuing comparisons.

  14. Purifying contaminated water

    DOE Patents [OSTI]

    Daughton, Christian G. (San Pablo, CA)

    1983-01-01T23:59:59.000Z

    Process for removing biorefractory compounds from contaminated water (e.g., oil shale retort waste-water) by contacting same with fragmented raw oil shale. Biorefractory removal is enhanced by preactivating the oil shale with at least one member of the group of carboxylic, acids, alcohols, aldehydes, ketones, ethers, amines, amides, sulfoxides, mixed ether-esters and nitriles. Further purification is obtained by stripping, followed by biodegradation and removal of the cells.

  15. Project House Dedication - 8 

    E-Print Network [OSTI]

    Unknown

    2011-08-17T23:59:59.000Z

    ) (11) Burke, N. E., Curtice, S., Little, C.T" and Seibert, A. F" Remoyal of Hydrocar;bons fr;om Oil-Field Brines by Flocculation with Car;bon Dioxide, SPE International Symposium on Oilfield Chemistry, SPE 21046, P 457 (1991). 102 in equilibrium...., Little, C.T., and Seibert, A. F., Remoyal of Hydrocarbons fz;om Oil-Field Brines by Flocculation with Caz;bon Dioxide, SPE International Symposium on Oilfield Chemistry, SPE 21046, P 457 (1991). ESL-IE-91-06-23 Proceedings from the 13th National...

  16. Understanding Contamination; Twenty Years of Simulating Radiological Contamination

    SciTech Connect (OSTI)

    Emily Snyder; John Drake; Ryan James

    2012-02-01T23:59:59.000Z

    A wide variety of simulated contamination methods have been developed by researchers to reproducibly test radiological decontamination methods. Some twenty years ago a method of non-radioactive contamination simulation was proposed at the Idaho National Laboratory (INL) that mimicked the character of radioactive cesium and zirconium contamination on stainless steel. It involved baking the contamination into the surface of the stainless steel in order to 'fix' it into a tenacious, tightly bound oxide layer. This type of contamination was particularly applicable to nuclear processing facilities (and nuclear reactors) where oxide growth and exchange of radioactive materials within the oxide layer became the predominant model for material/contaminant interaction. Additional simulation methods and their empirically derived basis (from a nuclear fuel reprocessing facility) are discussed. In the last ten years the INL, working with the Defense Advanced Research Projects Agency (DARPA) and the National Homeland Security Research Center (NHSRC), has continued to develop contamination simulation methodologies. The most notable of these newer methodologies was developed to compare the efficacy of different decontamination technologies against radiological dispersal device (RDD, 'dirty bomb') type of contamination. There are many different scenarios for how RDD contamination may be spread, but the most commonly used one at the INL involves the dispersal of an aqueous solution containing radioactive Cs-137. This method was chosen during the DARPA projects and has continued through the NHSRC series of decontamination trials and also gives a tenacious 'fixed' contamination. Much has been learned about the interaction of cesium contamination with building materials, particularly concrete, throughout these tests. The effects of porosity, cation-exchange capacity of the material and the amount of dirt and debris on the surface are very important factors. The interaction of the contaminant/substrate with the particular decontamination technology is also very important. Results of decontamination testing from hundreds of contaminated coupons have lead to certain conclusions about the contamination and the type of decontamination methods being deployed. A recent addition to the DARPA initiated methodology simulates the deposition of nuclear fallout. This contamination differs from previous tests in that it has been developed and validated purely to simulate a 'loose' type of contamination. This may represent the first time that a radiologically contaminated 'fallout' stimulant has been developed to reproducibly test decontamination methods. While no contaminant/methodology may serve as a complete example of all aspects that could be seen in the field, the study of this family of simulation methods provides insight into the nature of radiological contamination.

  17. Problems #3, Math 204, Dr. M. Bohner. Sep 10, 2003. Due Sep 15, 11 am. 12. A tank has ten gallons of water in which two pounds of salt has been dissolved. Brine with

    E-Print Network [OSTI]

    Bohner, Martin

    of water in which two pounds of salt has been dissolved. Brine with 1.5 pound of salt per gallon enters

  18. Effect of debonded interfaces on corrosion of mild steel composites in supercritical CO2-saturated brines

    SciTech Connect (OSTI)

    John, Han [Los Alamos National Laboratory; Carey, James W [Los Alamos National Laboratory; Zhang, Jinsuo [Los Alamos National Laboratory

    2010-10-07T23:59:59.000Z

    The geologic sequestration of CO{sub 2} is a proposed method to limit greenhouse gas emissions and has been the subject of many studies in the last decade. Wellbore systems achieve isolation of the storage reservoir through a combination of steel (generally carbon steel) and Portland cement. CO{sub 2} leakage along the steel-cement interface has the potential to accelerate corrosion. We conduct experiments to assess the corrosion risk at cement-steel interface under in situ wellbore conditions. Wellbore interfaces were simulated by assemblies constructed of J55 mild steel and Portland class G (Epoxy was used in this study to separate) cement and corrosion was investigated in supercritical CO{sub 2} saturated brines, (NaCl = 1 wt%) at T = 50 C, pCO{sub 2} = 1200 psi with interface gap size = 100 {micro}m and {infinity} (open surface). The experiments were carried out in a high-pressure, 1.8 L autoclave. The corrosion kinetics were measured employing electrochemical techniques including linear polarization resistance and electrochemical impedance spectroscopy techniques. The corrosion scales were analyzed using secondary electron microscopy, back scattering electron microscopy, energy dispersive spectroscopy and x-ray diffraction. Corrosion rates decreased as time with or without interface gap. In this case corrosion rates are controlled by scale protectivity through the interface gap. Scaled steel corrosion rates were two orders of magnitude less compared with fresh steel. The corrosion scale is pseudo crystalline at the open interface. Well-crystallized scale was observed at interface gap sizes 100 {micro}m. All corrosion scales were composed of iron carbonates.

  19. Understanding Mechanisms of Radiological Contamination

    SciTech Connect (OSTI)

    Rick Demmer; John Drake; Ryan James, PhD

    2014-03-01T23:59:59.000Z

    Over the last 50 years, the study of radiological contamination and decontamination has expanded significantly. This paper addresses the mechanisms of radiological contamination that have been reported and then discusses which methods have recently been used during performance testing of several different decontamination technologies. About twenty years ago the Idaho Nuclear Technology Engineering Center (INTEC) at the INL began a search for decontamination processes which could minimize secondary waste. In order to test the effectiveness of these decontamination technologies, a new simulated contamination, termed SIMCON, was developed. SIMCON was designed to replicate the types of contamination found on stainless steel, spent fuel processing equipment. Ten years later, the INL began research into methods for simulating urban contamination resulting from a radiological dispersal device (RDD). This work was sponsored by the Defense Advanced Research Projects Agency (DARPA) and included the initial development an aqueous application of contaminant to substrate. Since 2007, research sponsored by the US Environmental Protection Agency (EPA) has advanced that effort and led to the development of a contamination method that simulates particulate fallout from an Improvised Nuclear Device (IND). The IND method diverges from previous efforts to create tenacious contamination by simulating a reproducible “loose” contamination. Examining these different types of contamination (and subsequent decontamination processes), which have included several different radionuclides and substrates, sheds light on contamination processes that occur throughout the nuclear industry and in the urban environment.

  20. Biogeochemical Processes In Ethanol Stimulated Uranium Contaminated...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Processes In Ethanol Stimulated Uranium Contaminated Subsurface Sediments. Biogeochemical Processes In Ethanol Stimulated Uranium Contaminated Subsurface Sediments. Abstract: A...

  1. WETTABILITY AND PREDICTION OF OIL RECOVERY FROM RESERVOIRS DEVELOPED WITH MODERN DRILLING AND COMPLETION FLUIDS

    SciTech Connect (OSTI)

    Jill S. Buckley; Norman R. Morrow

    2004-11-01T23:59:59.000Z

    Contamination of crude oils by surface-active agents from drilling fluids or other oil-field chemicals is more difficult to detect and quantify than bulk contamination with, for example, base fluids from oil-based muds. Bulk contamination can be detected by gas chromatography or other common analytical techniques, but surface-active contaminants can be influential at much lower concentrations that are more difficult to detect analytically, especially in the context of a mixture as complex as a crude oil. In this report we present a baseline study of interfacial tensions of 39 well-characterized crude oil samples with aqueous phases that vary in pH and ionic composition. This extensive study will provide the basis for assessing the effects of surface-active contaminant on interfacial tension and other surface properties of crude oil/brine/rock ensembles.

  2. Contaminated nickel scrap processing

    SciTech Connect (OSTI)

    Compere, A.L.; Griffith, W.L.; Hayden, H.W.; Johnson, J.S. Jr.; Wilson, D.F.

    1994-12-01T23:59:59.000Z

    The DOE will soon choose between treating contaminated nickel scrap as a legacy waste and developing high-volume nickel decontamination processes. In addition to reducing the volume of legacy wastes, a decontamination process could make 200,000 tons of this strategic metal available for domestic use. Contaminants in DOE nickel scrap include {sup 234}Th, {sup 234}Pa, {sup 137}Cs, {sup 239}Pu (trace), {sup 60}Co, U, {sup 99}Tc, and {sup 237}Np (trace). This report reviews several industrial-scale processes -- electrorefining, electrowinning, vapormetallurgy, and leaching -- used for the purification of nickel. Conventional nickel electrolysis processes are particularly attractive because they use side-stream purification of process solutions to improve the purity of nickel metal. Additionally, nickel purification by electrolysis is effective in a variety of electrolyte systems, including sulfate, chloride, and nitrate. Conventional electrorefining processes typically use a mixed electrolyte which includes sulfate, chloride, and borate. The use of an electrorefining or electrowinning system for scrap nickel recovery could be combined effectively with a variety of processes, including cementation, solvent extraction, ion exchange, complex-formation, and surface sorption, developed for uranium and transuranic purification. Selected processes were reviewed and evaluated for use in nickel side-stream purification. 80 refs.

  3. West Hackberry Strategic Petroleum Reserve site brine-disposal monitoring, Year I report. Volume II. Physical and chemical oceanography. Final report

    SciTech Connect (OSTI)

    DeRouen, L.R.; Hann, R.W.; Casserly, D.M.; Giammona, C.; Lascara, V.J. (eds.)

    1983-02-01T23:59:59.000Z

    This project centers around the Strategic Petroleum Site (SPR) known as the West Hackberry salt dome which is located in southwestern Louisiana, and which is designed to store 241 million barrels of crude oil. Oil storage caverns are formed by injecting water into salt deposits, and pumping out the resulting brine. Studies described in this report were designed as follow-on studies to three months of pre-discharge characterization work, and include data collected during the first year of brine leaching operations. The objectives were to: (1) characterize the environment in terms of physical, chemical and biological attributes; (2) determine if significant adverse changes in ecosystem productivity and stability of the biological community are occurring as a result of brine discharge; and (3) determine the magnitude of any change observed. Contents of Volume II include: introduction; physical oceanography; estuarine hydrology and hydrography; analysis of discharge plume; and water and sediment quality.

  4. Direct releases to the surface and associated complementary cumulative distribution functions in the 1996 performance assessments for the Waste Isolation Pilot Plant: Direct brine release

    SciTech Connect (OSTI)

    STOELZEL,D.M.; O'BRIEN,D.G.; GARNER,J.W.; HELTON,JON CRAIG; JOHNSON,J.D.; SCOTT,L.N.

    2000-05-19T23:59:59.000Z

    The following topics related to the treatment of direct brine releases to the surface environment in the 1996 performance assessment for the Waste Isolation Pilot Plant (WIPP) are presented (1) mathematical description of models, (2) uncertainty and sensitivity analysis results arising from subjective (i.e., epistemic) uncertainty for individual releases, (3) construction of complementary cumulative distribution functions (CCDFs) arising from stochastic (i.e., aleatory) uncertainty, and (4) uncertainty and sensitivity analysis results for CCDFs. The presented analyses indicate that direct brine releases do not constitute a serious threat to the effectiveness of the WIPP as a disposal facility for transuranic waste. Even when the effects of uncertain analysis inputs are taken into account, the CCDFs for direct brine releases fall substantially to the left of the boundary line specified in the US Environmental Protection Agency's standard for the geologic disposal of radioactive waste (4O CFR 191.40 CFR 194).

  5. Modifications of Carbonate Fracture Hydrodynamic Properties by CO{sub 2}-Acidified Brine Flow

    SciTech Connect (OSTI)

    Deng, Hang; Ellis, Brian R.; Peters, Catherine A.; Fitts, Jeffrey P.; Crandall, Dustin; Bromhal, Grant S.

    2013-08-01T23:59:59.000Z

    Acidic reactive flow in fractures is relevant in subsurface activities such as CO{sub 2} geological storage and hydraulic fracturing. Understanding reaction-induced changes in fracture hydrodynamic properties is essential for predicting subsurface flows such as leakage, injectability, and fluid production. In this study, x-ray computed tomography scans of a fractured carbonate caprock were used to create three dimensional reconstructions of the fracture before and after reaction with CO{sub 2}-acidified brine (Ellis et al., 2011, Greenhouse Gases: Sci. Technol., 1:248-260). As expected, mechanical apertures were found to increase substantially, doubling and even tripling in some places. However, the surface geometry evolved in complex ways including ‘comb-tooth’ structures created from preferential dissolution of calcite in transverse sedimentary bands, and the creation of degraded zones, i.e. porous calcite-depleted areas on reacted fracture surfaces. These geometric alterations resulted in increased fracture roughness, as measured by surface Z{sub 2} parameters and fractal dimensions D{sub f}. Computational fluid dynamics (CFD) simulations were conducted to quantify the changes in hydraulic aperture, fracture transmissivity and permeability. The results show that the effective hydraulic apertures are smaller than the mechanical apertures, and the changes in hydraulic apertures are nonlinear. Overestimation of flow rate by a factor of two or more would be introduced if fracture hydrodynamic properties were based on mechanical apertures, or if hydraulic aperture is assumed to change proportionally with mechanical aperture. The differences can be attributed, in part, to the increase in roughness after reaction, and is likely affected by contiguous transverse sedimentary features. Hydraulic apertures estimated by the 1D statistical model and 2D local cubic law (LCL) model are consistently larger than those calculated from the CFD simulations. In addition, a novel ternary segmentation method was devised to handle the degraded zones, allowing for a bounding analysis of the effects on hydraulic properties. We found that the degraded zones account for less than 15% of the fracture volume, but cover 70% to 80% of the fracture surface. When the degraded zones are treated as part of the fracture, the fracture transmissivities are two to four times larger because the fracture surfaces after reaction are not as rough as they would be if one considers the degraded zone as part of the rock. Therefore, while degraded zones created during geochemical reactions may not significantly increase mechanical aperture, this type of feature cannot be ignored and should be treated with prudence when predicting fracture hydrodynamic properties.

  6. Contaminants in Vadose Zone Environments

    SciTech Connect (OSTI)

    Wellman, Dawn M.; Freshley, Mark D.; Johnson, Timothy C.; Miracle, Ann L.

    2012-11-01T23:59:59.000Z

    Contaminants in vadose zone environments pose a long-term source and threat to groundwater resources, human health, and the environment. Several technical, regulatory, and policy challenges and opportunities are associated with contamination in vadose zone environments, particularly in remediation. In this special issue, ten papers present novel approaches to characterize, monitor, remediate, and predict the transport and fate of contaminants in vadose zone environments.

  7. Emission Standards for Contaminants (Iowa)

    Broader source: Energy.gov [DOE]

    These regulations list emissions standards for various contaminants, and contain special requirements for anaerobic lagoons. These regulations also describe alternative emissions limits, which may...

  8. CharacteristicGalerkin and Mixed Finite Element Approximation of Contamination by Compressible

    E-Print Network [OSTI]

    Chou, So-Hsiang

    for the brine, radionuclides, and heat and by a mixed finite element method for the pressure and velocity disposal buried in a salt dome. The salt dissolves to generate a brine, radioactive elements decay), the viscosity of the fluid, is dependent on â?? c, the concentration of the brine in the fluid. For simplicity we

  9. Calcite dissolution kinetics and solubility in Na-Ca-Mg-Cl brines of geologically relevant composition at 0.1 to 1 bar pCO2 and 25 to 80°C 

    E-Print Network [OSTI]

    Gledhill, Dwight Kuehl

    2006-08-16T23:59:59.000Z

    injection of CO2. This study measured calcite solubility and dissolution rates in geologically relevant Na-Ca-Mg-Cl synthetic brines (35 to 200 g L-1 TDS). In brines < 50 g L-1 TDS, the EQPITZER calculated calcium carbonate ion activity product (IAP...

  10. Wetting behavior of selected crude oil/brine/rock systems. Topical report, March 1, 1995--March 31, 1996

    SciTech Connect (OSTI)

    Zhou, X.; Morrow, N.R.; Ma, S.

    1996-12-31T23:59:59.000Z

    Previous studies of crude oil/brine/rock (COBR) and related ensembles showed that wettability and its effect on oil recovery depend on numerous complex interactions. In the present work, the wettability of COBR ensembles prepared using Prudhoe Bay crude oil, a synthetic formation brine, and Berea Sandstone was varied by systematic change in initial water saturation and length of aging time at reservoir temperature (88 C). All displacement tests were run at ambient temperature. Various degrees of water wetness were achieved and quantified by a modified Amott wettability index to water, the relative pseudo work of imbibition, and a newly defined apparent advancing dynamic contact angle. Pairs of spontaneous imbibition (oil recovery by spontaneous imbibition of water) and waterflood (oil recovery vs. pore volumes of water injected) curves were measured for each of the induced wetting states. Several trends were observed. Imbibition rate, and hence water wetness, decreased with increase in aging time and with decrease in initial water saturation. Breakthrough recoveries and final oil recovery by waterflooding increased with decrease in water wetness. Correlations between water wetness and oil recovery by waterflooding and spontaneous imbibition are presented.

  11. Environmental assessment of the brine pipeline replacement for the Strategic Petroleum Reserve Bryan Mound Facility in Brazoria County, Texas

    SciTech Connect (OSTI)

    Not Available

    1993-09-01T23:59:59.000Z

    The Department of Energy (DOE) has prepared an environmental assessment (EA), DOE/EA-0804, for the proposed replacement of a deteriorated brine disposal pipeline from the Strategic Petroleum Reserve (SPR) Bryan Mound storage facility in Brazoria County, Texas, into the Gulf of Mexico. In addition, the ocean discharge outfall would be moved shoreward by locating the brine diffuser at the end of the pipeline 3.5 miles offshore at a minimum depth of 30 feet. The action would occur in a floodplain and wetlands; therefore, a floodplain/wetlands assessment has been prepared in conjunction with this EA. Based on the analyses in the EA, DOE has determined that the proposed action is not a major Federal action significantly affecting the quality of the human environment within the meaning of the National Environmental Policy Act (NEPA) of 1969 (42 USC. 4321, et seg.). Therefore, the preparation of an Environmental Impact Statement (EIS) is not required, and the Department is issuing this Finding of No Significant Impact (FONSI). This FONSI also includes a Floodplain Statement of Findings in accordance with 10 CFR Part 1022.

  12. Contamination and solid state welds.

    SciTech Connect (OSTI)

    Mills, Bernice E.

    2007-05-01T23:59:59.000Z

    Since sensitivity to contamination is one of the verities of solid state joining, there is a need for assessing contamination of the part(s) to be joined, preferably nondestructively while it can be remedied. As the surfaces that are joined in pinch welds are inaccessible and thus provide a greater challenge, most of the discussion is of the search for the origin and effect of contamination on pinch welding and ways to detect and mitigate it. An example of contamination and the investigation and remediation of such a system is presented. Suggestions are made for techniques for nondestructive evaluation of contamination of surfaces for other solid state welds as well as for pinch welds. Surfaces that have good visual access are amenable to inspection by diffuse reflection infrared Fourier transform (DRIFT) spectroscopy. Although other techniques are useful for specific classes of contaminants (such as hydrocarbons), DRIFT can be used most classes of contaminants. Surfaces such as the interior of open tubes or stems that are to be pinch welded can be inspected using infrared reflection spectroscopy. It must be demonstrated whether or not this tool can detect graphite based contamination, which has been seen in stems. For tubes with one closed end, the technique that should be investigated is emission infrared spectroscopy.

  13. Semi-analytical model of brine and CO2 leakage through an abandoned plugged well. Applications for determining an Area of Review and CO2 leakage rate

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Semi-analytical model of brine and CO2 leakage through an abandoned plugged well. Applications for determining an Area of Review and CO2 leakage rate Arnaud Réveillère, Jérémy Rohmer, Frédéric Wertz / contact the leak, and of CO2,g as a first approach. Compared to the state of the art, it adds the possibility

  14. New constraints on methane fluxes and rates of anaerobic methane oxidation in a Gulf of Mexico brine pool via in situ mass spectrometry

    E-Print Network [OSTI]

    Girguis, Peter R.

    , likely exceeding reserves of conventional oil and gas (Collett and Kuuskraa, 1998). In deep-ocean regionsNew constraints on methane fluxes and rates of anaerobic methane oxidation in a Gulf of Mexico Keywords: Methane flux Mass spectrometer Brine pool Methane oxidation Gulf of Mexico a b s t r a c t Deep

  15. (Data in metric tons of lithium content unless otherwise noted) Domestic Production and Use: The only commercially active lithium mine in the United States was a brine

    E-Print Network [OSTI]

    94 LITHIUM (Data in metric tons of lithium content unless otherwise noted) Domestic Production and Use: The only commercially active lithium mine in the United States was a brine operation in Nevada. The mine's production capacity was expanded in 2012, and a new lithium hydroxide plant opened in North

  16. Bioaugmentation for Reduction of Diffuse Pesticide Contamination

    E-Print Network [OSTI]

    Bioaugmentation for Reduction of Diffuse Pesticide Contamination A Bioprophylactic Concept Karin/Repro, Uppsala 2013 #12;Bioaugmentation for Reduction of Diffuse Pesticide Contamination. A Bioprophylactic Concept. Abstract Pesticides and their residues frequently contaminate surface waters and groundwater so

  17. Contamination of shallow wells in Nigeria from surface contaminant migration

    SciTech Connect (OSTI)

    Ademoroti, C.M.A. (Univ. of Benin (Nigeria))

    1987-01-01T23:59:59.000Z

    Contaminated wells, located in six south/western and western states of Nigeria, were sampled and analyzed for pollution characteristics. Results of analysis indicated migration of contaminants into the wells from places where there was a potential source. There was a significant microbiological population in the wells placed near domestic waste sites. Also, there were excessive levels of trace heavy metals in those placed near metal dumping sites. On the other hand, the contaminants were minimal in wells that were not close to polluting sources. The studies revealed that groundwater contamination occurred primarily by dumping of wastes, wrong placement of waste disposal facilities, and improper construction of wells. The groundwater sources (wells, etc.) are used when pipe-borne water facilities are inadequate.

  18. ROCKY MOUNTAIN OILFIELD TESTING CENTER

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    data (provided by Centech) was not sufficient to facilitate a quantitative material balance. The total effluent volume was 7.5% higher than the processed-feed volume; therefore,...

  19. ROCKY MOUNTAIN OILFIELD TESTING CENTER

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    management and operating contractor for the Department of Energy's Naval Petroleum Oil Shale Reserves in Colorado, Utah, and Wyoming. NPR-3 lies along the southeastern portion...

  20. ROCKY MOUNTAIN OILFIELD TESTING CENTER

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    management and operating contractor for the Department of Energy's Naval Petroleum Oil Shale Reserves in Colorado, Utah, and Wyoming. As part of RMOTC's continuing mission to...

  1. ROCKY MOUNTAIN OILFIELD TESTING CENTER

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (NPOSR), Inc., the Management and Operating Contractor for the DOE Naval Petroleum Oil Shale Reserves in Colorado, Utah and Wyoming. RMOTC's goal is to partner with the oil and...

  2. ROCKY MOUNTAIN OILFIELD TESTING CENTER

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of Finite Conductivity," SPE Drilling Engineering, June, p. 127. Lee, K. and G. Smith. 1975. "Measured Properties of Bare and Insulated Antennas in Sand," IEEE...

  3. Reactive transport modeling to study changes in water chemistry induced by CO2 injection at the Frio-I brine pilot

    SciTech Connect (OSTI)

    Kharaka, Y.K; Doughty, C.; Freifeld, B.M.; Daley, T.M.; Xu, T.

    2009-11-01T23:59:59.000Z

    To demonstrate the potential for geologic storage of CO{sub 2} in saline aquifers, the Frio-I Brine Pilot was conducted, during which 1600 tons of CO{sub 2} were injected into a high-permeability sandstone and the resulting subsurface plume of CO{sub 2} was monitored using a variety of hydrogeological, geophysical, and geochemical techniques. Fluid samples were obtained before CO{sub 2} injection for baseline geochemical characterization, during the CO{sub 2} injection to track its breakthrough at a nearby observation well, and after injection to investigate changes in fluid composition and potential leakage into an overlying zone. Following CO{sub 2} breakthrough at the observation well, brine samples showed sharp drops in pH, pronounced increases in HCO{sub 3}{sup -} and aqueous Fe, and significant shifts in the isotopic compositions of H{sub 2}O and dissolved inorganic carbon. Based on a calibrated 1-D radial flow model, reactive transport modeling was performed for the Frio-I Brine Pilot. A simple kinetic model of Fe release from the solid to aqueous phase was developed, which can reproduce the observed increases in aqueous Fe concentration. Brine samples collected after half a year had lower Fe concentrations due to carbonate precipitation, and this trend can be also captured by our modeling. The paper provides a method for estimating potential mobile Fe inventory, and its bounding concentration in the storage formation from limited observation data. Long-term simulations show that the CO{sub 2} plume gradually spreads outward due to capillary forces, and the gas saturation gradually decreases due to its dissolution and precipitation of carbonates. The gas phase is predicted to disappear after 500 years. Elevated aqueous CO{sub 2} concentrations remain for a longer time, but eventually decrease due to carbonate precipitation. For the Frio-I Brine Pilot, all injected CO{sub 2} could ultimately be sequestered as carbonate minerals.

  4. Groundwater Contamination Potential from Stormwater

    E-Print Network [OSTI]

    Clark, Shirley E.

    1 Groundwater Contamination Potential from Stormwater Infiltration Robert Pitt, University (CSOs). Introduction (cont.) · Scattered information is available addressing groundwater impacts cities · EPA 1983 NURP work on groundwater beneath Fresno and Long Island infiltration basins · NRC 1994

  5. Method for testing earth samples for contamination by organic contaminants

    DOE Patents [OSTI]

    Schabron, J.F.

    1996-10-01T23:59:59.000Z

    Provided is a method for testing earth samples for contamination by organic contaminants, and particularly for aromatic compounds such as those found in diesel fuel and other heavy fuel oils, kerosene, creosote, coal oil, tars and asphalts. A drying step is provided in which a drying agent is contacted with either the earth sample or a liquid extract phase to reduce to possibility of false indications of contamination that could occur when humic material is present in the earth sample. This is particularly a problem when using relatively safe, non-toxic and inexpensive polar solvents such as isopropyl alcohol since the humic material tends to be very soluble in those solvents when water is present. Also provided is an ultraviolet spectroscopic measuring technique for obtaining an indication as to whether a liquid extract phase contains aromatic organic contaminants. In one embodiment, the liquid extract phase is subjected to a narrow and discrete band of radiation including a desired wave length and the ability of the liquid extract phase to absorb that wavelength of ultraviolet radiation is measured to provide an indication of the presence of aromatic organic contaminants. 2 figs.

  6. Method for testing earth samples for contamination by organic contaminants

    DOE Patents [OSTI]

    Schabron, John F. (Laramie, WY)

    1996-01-01T23:59:59.000Z

    Provided is a method for testing earth samples for contamination by organic contaminants, and particularly for aromatic compounds such as those found in diesel fuel and other heavy fuel oils, kerosene, creosote, coal oil, tars and asphalts. A drying step is provided in which a drying agent is contacted with either the earth sample or a liquid extract phase to reduce to possibility of false indications of contamination that could occur when humic material is present in the earth sample. This is particularly a problem when using relatively safe, non-toxic and inexpensive polar solvents such as isopropyl alcohol since the humic material tends to be very soluble in those solvents when water is present. Also provided is an ultraviolet spectroscopic measuring technique for obtaining an indication as to whether a liquid extract phase contains aromatic organic contaminants. In one embodiment, the liquid extract phase is subjected to a narrow and discrete band of radiation including a desired wave length and the ability of the liquid extract phase to absorb that wavelength of ultraviolet radiation is measured to provide an indication of the presence of aromatic organic contaminants.

  7. Asymptotic distribution theory for contamination Francisco Vera

    E-Print Network [OSTI]

    Lynch, Jim

    Asymptotic distribution theory for contamination models Francisco Vera , David Dickey and James and the second to the other sources (the contamination component). Here the goal is two-fold: (i) detect the overall presence of Contamination and (ii) identify observations that may be contaminated. A locally most

  8. AFLATOXIN CONTAMINATION OF COMMERCIALLY GROWN TRANSGENIC

    E-Print Network [OSTI]

    Cotty, Peter J.

    108 AFLATOXIN CONTAMINATION OF COMMERCIALLY GROWN TRANSGENIC BT COTTONSEED P.J. Cotty and C. Bock cotton may have reduced susceptibility to aflatoxin contamination as a result of pink bollworm resistance) from one highly contaminated (>6,000 ppb aflatoxin B1) Bt seed lot indicated that most contamination

  9. Effect of Oxygen Co-Injected with Carbon Dioxide on Gothic Shale Caprock-CO2-Brine Interaction during Geologic Carbon Sequestration

    SciTech Connect (OSTI)

    Jung, Hun Bok; Um, Wooyong; Cantrell, Kirk J.

    2013-09-16T23:59:59.000Z

    Co-injection of oxygen, a significant component in CO2 streams produced by the oxyfuel combustion process, can cause a significant alteration of the redox state in deep geologic formations during geologic carbon sequestration. The potential impact of co-injected oxygen on the interaction between synthetic CO2-brine (0.1 M NaCl) and shale caprock (Gothic shale from the Aneth Unit in Utah) and mobilization of trace metals was investigated at ~10 MPa and ~75 °C. A range of relative volume percentages of O2 to CO2 (0, 1, 4 and 8%) were used in these experiments to address the effect of oxygen on shale-CO2-brine interaction under various conditions. Major mineral phases in Gothic shale are quartz, calcite, dolomite, montmorillonite, and pyrite. During Gothic shale-CO2-brine interaction in the presence of oxygen, pyrite oxidation occurred extensively and caused enhanced dissolution of calcite and dolomite. Pyrite oxidation and calcite dissolution subsequently resulted in the precipitation of Fe(III) oxides and gypsum (CaSO4•2H2O). In the presence of oxygen, dissolved Mn and Ni were elevated because of oxidative dissolution of pyrite. The mobility of dissolved Ba was controlled by barite (BaSO4) precipitation in the presence of oxygen. Dissolved U in the experimental brines increased to ~8–14 ?g/L, with concentrations being slightly higher in the absence of oxygen than in the presence of oxygen. Experimental and modeling results indicate the interaction between shale caprock and oxygen co-injected with CO2 during geologic carbon sequestration can exert significant impacts on brine pH, solubility of carbonate minerals, stability of sulfide minerals, and mobility of trace metals. The major impact of oxygen is most likely to occur in the zone near CO2 injection wells where impurity gases can accumulate. Oxygen in CO2-brine migrating away from the injection well will be continually consumed through the reactions with sulfide minerals in deep geologic formations.

  10. Surface Contamination Surface contamination from radioactive isotopes is a source of background in the Borex-

    E-Print Network [OSTI]

    Chapter 5 Surface Contamination Surface contamination from radioactive isotopes is a source of background in the Borex- ino detector. Surface contaminants can be in the form of macroscopic dust particles contamination is primarily a problem because the radioactive contaminants can be trans- ferred from the surfaces

  11. Using a multiphase flow code to model the coupled effects of repository consolidation and multiphase brine and gas flow at the Waste Isolation Pilot Plant

    SciTech Connect (OSTI)

    Freeze, G.A. [INTERA Inc., Albuquerque, NM (United States); Larson, K.W.; Davies, P.B.; Webb, S.W. [Sandia National Labs., Albuquerque, NM (United States)

    1995-10-01T23:59:59.000Z

    Long-term repository assessment must consider the processes of (1) gas generation, (2) room closure and expansions due to salt creep, and (3) multiphase (brine and gas) fluid flow, as well as the complex coupling between these three processes. The mechanical creep closure code SANCHO was used to simulate the closure of a single, perfectly sealed disposal room filled with water and backfill. SANCHO uses constitutive models to describe salt creep, waste consolidation, and backfill consolidation, Five different gas-generation rate histories were simulated, differentiated by a rate multiplier, f, which ranged from 0.0 (no gas generation) to 1.0 (expected gas generation under brine-dominated conditions). The results of the SANCHO f-series simulations provide a relationship between gas generation, room closure, and room pressure for a perfectly sealed room. Several methods for coupling this relationship with multiphase fluid flow into and out of a room were examined. Two of the methods are described.

  12. Cleaning Contaminated Water at Fukushima

    SciTech Connect (OSTI)

    Rende, Dean; Nenoff, Tina

    2013-11-21T23:59:59.000Z

    Crystalline Silico-Titanates (CSTs) are synthetic zeolites designed by Sandia National Laboratories scientists to selectively capture radioactive cesium and other group I metals. They are being used for cleanup of radiation-contaminated water at the Fukushima Daiichi nuclear power plant in Japan. Quick action by Sandia and its corporate partner UOP, A Honeywell Company, led to rapid licensing and deployment of the technology in Japan, where it continues to be used to clean up cesium contaminated water at the Fukushima power plant.

  13. Cleaning Contaminated Water at Fukushima

    ScienceCinema (OSTI)

    Rende, Dean; Nenoff, Tina

    2014-02-26T23:59:59.000Z

    Crystalline Silico-Titanates (CSTs) are synthetic zeolites designed by Sandia National Laboratories scientists to selectively capture radioactive cesium and other group I metals. They are being used for cleanup of radiation-contaminated water at the Fukushima Daiichi nuclear power plant in Japan. Quick action by Sandia and its corporate partner UOP, A Honeywell Company, led to rapid licensing and deployment of the technology in Japan, where it continues to be used to clean up cesium contaminated water at the Fukushima power plant.

  14. Contamination Cross-contamination occurs when bacteria, or "germs," are moved from one food to another.

    E-Print Network [OSTI]

    Combat Cross Contamination Cross-contamination occurs when bacteria, or "germs," are moved from one food to another. To combat cross-contamination, keep foods SEPARATE!! At the grocery store, keep raw

  15. Evaluation of experimentally measured and model-calculated pH for rock-brine-CO2 systems under geologic CO2 sequestration conditions

    SciTech Connect (OSTI)

    Shao, Hongbo; Thompson, Christopher J.; Cantrell, Kirk J.

    2013-11-01T23:59:59.000Z

    pH is an essential parameter for understanding the geochemical reactions that occur in rock-brine-CO2 systems when CO2 is injected into deep geologic formations for long-term storage. Due to a lack of reliable experimental methods, most laboratory studies conducted under geological CO2 sequestration (GCS) conditions have relied on thermodynamic modeling to estimate pH. The accuracy of these model predictions is typically uncertain. In our previous work, we have developed a method for pH determination by in-situ spectrophotometry. In the present work, we expanded the applicable pH range for this method and measured the pH of several rock-brine-CO2 systems at GCS conditions for five rock samples collected from ongoing GCS demonstration projects. Experimental measurements were compared with pH values calculated using several geochemical modeling approaches. The effect of different thermodynamic databases on the accuracy of model prediction was evaluated. Results indicate that the accuracy of model calculations is rock-dependent. For rocks comprised of carbonate and sandstone, model results generally agreed well with experimentally measured pH; however, for basalt, significant differences were observed. These discrepancies may be due to the models’ failure to fully account for certain reaction occurring between the basalt minerals the CO2-saturated brine solutions.

  16. Method for remote detection of trace contaminants

    DOE Patents [OSTI]

    Simonson, Robert J.; Hance, Bradley G.

    2003-09-09T23:59:59.000Z

    A method for remote detection of trace contaminants in a target area comprises applying sensor particles that preconcentrate the trace contaminant to the target area and detecting the contaminant-sensitive fluorescence from the sensor particles. The sensor particles can have contaminant-sensitive and contaminant-insensitive fluorescent compounds to enable the determination of the amount of trace contaminant present in the target are by relative comparison of the emission of the fluorescent compounds by a local or remote fluorescence detector. The method can be used to remotely detect buried minefields.

  17. Constraining the reservoir model of an injected CO2 plume with crosswell CASSM at the Frio-II brine plot

    SciTech Connect (OSTI)

    Daley, T.M.; Ajo-Franklin, J.; Doughty, C.A.

    2011-02-15T23:59:59.000Z

    Crosswell CASSM (continuous active-source seismic monitoring) data was acquired as part of the Frio-II brine pilot CO{sub 2} injection experiment. To gain insight into the CO{sub 2} plume evolution, we have integrated the 3D multiphase flow modeling code TOUGH2 with seismic simulation codes via a petrophysical model that predicts seismic velocity for a given CO{sub 2} saturation. Results of forward seismic modeling based on the CO{sub 2} saturation distribution produced by an initial TOUGH2 model compare poorly with the CASSM data, indicating that the initial flow model did not capture the actual CO{sub 2} plume dynamics. Updates to the TOUGH2 model required to better match the CASSM field data indicate vertical flow near the injection well, with increased horizontal plume growth occurring at the top of the reservoir sand. The CASSM continuous delay time data are ideal for constraining the modeled spatiotemporal evolution of the CO{sub 2} plume and allow improvement in reservoir model and estimation of CO{sub 2} plume properties.

  18. A Mixed Finite Element Approximation for Compressible Flow of Contamination from Nuclear

    E-Print Network [OSTI]

    Chou, So-Hsiang

    of this system using a finite element method for the brine, radionuclides, and heat combined with a mixed finite; and ¯(â??c), the viscosity of the fluid is depen­ dent on â?? c, the concentration of the brine in the fluid + (ff L \\Gamma ff T )u i u j =juj). Brine: @ @t (OEaeâ??c) = \\Gammar \\Delta (aeâ??cu) +r \\Delta (aeE c (u

  19. Reliability and Consistency of Surface Contamination Measurements

    SciTech Connect (OSTI)

    Rouppert, F.; Rivoallan, A.; Largeron, C.

    2002-02-26T23:59:59.000Z

    Surface contamination evaluation is a tough problem since it is difficult to isolate the radiations emitted by the surface, especially in a highly irradiating atmosphere. In that case the only possibility is to evaluate smearable (removeable) contamination since ex-situ countings are possible. Unfortunately, according to our experience at CEA, these values are not consistent and thus non relevant. In this study, we show, using in-situ Fourier Transform Infra Red spectrometry on contaminated metal samples, that fixed contamination seems to be chemisorbed and removeable contamination seems to be physisorbed. The distribution between fixed and removeable contamination appears to be variable. Chemical equilibria and reversible ion exchange mechanisms are involved and are closely linked to environmental conditions such as humidity and temperature. Measurements of smearable contamination only give an indication of the state of these equilibria between fixed and removeable contamination at the time and in the environmental conditions the measurements were made.

  20. Indigenous Resource Management and Environmental Contamination

    E-Print Network [OSTI]

    Holder, Stanley Richard

    2008-07-28T23:59:59.000Z

    Heavy metals are potential contaminants which can produce negative impacts on human health which vary from metal to metal, and are also dependent upon concentration and duration of exposure to the contaminant. This study ...

  1. Control of Viral Contamination of Food and Environment

    E-Print Network [OSTI]

    Cliver, Dean O.

    2009-01-01T23:59:59.000Z

    M. , & Sattar, S. A. (2000a). Contamination of foods by food2004). Norovirus cross-contamination during food handlingcoli in mussels after contamination and depu- ration.

  2. Bacterial and Protozoal Contamination of Nearshore Marine Environments

    E-Print Network [OSTI]

    Atwill, Rob; Conrad, Patricia A.

    2010-01-01T23:59:59.000Z

    Tate. Reducing microbial contamination in storm runoff fromManagement of microbial contamination in storm runoff fromBacterial and Protozoal Contamination of Nearshore Marine

  3. Cultivation, Capital, and Contamination: Urban Agriculture in Oakland, California

    E-Print Network [OSTI]

    McClintock, Nathan

    2011-01-01T23:59:59.000Z

    urban gardens. Land Contamination & Reclamation 12 Schiff,Potentially toxic metal contamination of urban soils andAlloway, B. J. 2004. Contamination of soils in domestic

  4. Maternal Contributions to the Development of Contamination Sensitivity

    E-Print Network [OSTI]

    Beebe, Heidi

    2012-01-01T23:59:59.000Z

    The development of contamination sensitivity to "disgusting"of conservation and contamination: Invisible particles as areference to disgust and contamination sensitivity. Child

  5. Preventing Food Contamination: A Need for Innovation in Food Production

    E-Print Network [OSTI]

    Reynolds, Mark

    2013-01-01T23:59:59.000Z

    174 Preventing Food Contamination A Need for Innovation infurther prevent microbial contamination. Due largely becausequick migration of the contamination in the example given

  6. Distribution of Chromium Contamination and Microbial Activity in Soil Aggregates

    E-Print Network [OSTI]

    Tokunaga, Tetsu K.

    2010-01-01T23:59:59.000Z

    Distribution of Chromium Contamination and Microbialand predict the fate of Cr contamination. Typical methods ofOur previous work on Cr contamination was done using such

  7. Webinar: NREL's Fuel Cell Contaminant Database

    Broader source: Energy.gov [DOE]

    Video recording and text version of the webinar titled "NREL's Fuel Cell Contaminant Database," originally presented on May 27, 2014.

  8. Spin Contamination in Inorganic Chemistry Calculations

    E-Print Network [OSTI]

    Schlegel, H. Bernhard

    R EVISED PAG E PR O O FS ia617 Spin Contamination in Inorganic Chemistry Calculations Jason L . In such cases, 0 is said to be spin contaminated owing to incorporation of higher spin state character of Iron­Sulfur ia618 Clusters). It is important to note that while spin-contaminated and broken

  9. Etiology and Management of Aflatoxin Contamination

    E-Print Network [OSTI]

    Cotty, Peter J.

    25 Etiology and Management of Aflatoxin Contamination Peter J. Cotty*, Claudia Probst and Ramon Jaime-Garcia Abstract Aflatoxins are potent poisons that contaminate crops in warm regions worldwide and re- duce health and economic welfare in several portions of Africa. Crops are contaminated in two

  10. Scatterometer Contamination Mitigation Michael Paul Owen

    E-Print Network [OSTI]

    Long, David G.

    Scatterometer Contamination Mitigation Michael Paul Owen A dissertation submitted to the faculty Michael Paul Owen All Rights Reserved #12;#12;ABSTRACT Scatterometer Contamination Mitigation Michael Paul are contaminated by land proximity or rain events produce wind estimates which have increased bias and variability

  11. CTF Surface Contamination and External Backgrounds

    E-Print Network [OSTI]

    Chapter 9 CTF Surface Contamination and External Backgrounds The preceding chapter included Contamination and External Backgrounds 424 it can do so), leading to a low-energy tail of events in the energy Runs 2300­2563 unless stated otherwise. #12;Chapter 9. CTF Surface Contamination and External

  12. Data Center Economizer Contamination and Humidity Study

    E-Print Network [OSTI]

    LBNL-2424E Data Center Economizer Contamination and Humidity Study A. Shehabi, W. Tschudi, A Emerging Technologies Program Data Center Economizer Contamination and Humidity Study Lawrence Berkeley to specifying as little outside air as permissible for human occupants. To investigate contamination levels

  13. Mathematical formulations for contaminant partitioning in rivers

    SciTech Connect (OSTI)

    Fowler, K.M.; Whelan, G.; Onishi, Y.

    1997-09-01T23:59:59.000Z

    This mathematical model for contaminant transport in rivers provides a preliminary assessment of the contaminant mass and concentration using environmental partitioning. First, the model uses the advection-dispersion equation to model the river flow and contaminant transport in the water. Second, the model uses compartment modeling to partition the contaminant mass into water, sediment, bed sediment, air, fish, vegetation and free product environmental compartments. Finally, the model calculates contaminant concentration in each environmental compartment. As long as this approach is applied with an understanding of its assumptions and limitations, it can be very useful as a preliminary assessment model for contaminant transport in rivers. The purpose of developing this approach was to provide a simple mathematical model that accounts for the time-varying partitioning of contaminant concentration at a given location along the river. This approach is intended to be used as part of the Multimedia Environmental Pollutant Assessment System (MEPAS). Currently MEPAS, and other multimedia contaminant environmental transport and exposure risk assessment methodologies, assumes that once the contaminant enters the water, it is instantaneously and completely dissolved. This assumption, that the contaminant is only present in the dissolved phase tends to over predict water contaminant levels. This approach is intended to address the partitioning of contaminants into environmental compartments in addition to the water column.

  14. In situ removal of contamination from soil

    DOE Patents [OSTI]

    Lindgren, Eric R. (Albuquerque, NM); Brady, Patrick V. (Albuquerque, NM)

    1997-01-01T23:59:59.000Z

    A process of remediation of cationic heavy metal contamination from soil utilizes gas phase manipulation to inhibit biodegradation of a chelating agent that is used in an electrokinesis process to remove the contamination, and further gas phase manipulation to stimulate biodegradation of the chelating agent after the contamination has been removed. The process ensures that the chelating agent is not attacked by bioorganisms in the soil prior to removal of the contamination, and that the chelating agent does not remain as a new contaminant after the process is completed.

  15. In situ removal of contamination from soil

    DOE Patents [OSTI]

    Lindgren, E.R.; Brady, P.V.

    1997-10-14T23:59:59.000Z

    A process of remediation of cationic heavy metal contamination from soil utilizes gas phase manipulation to inhibit biodegradation of a chelating agent that is used in an electrokinesis process to remove the contamination. The process also uses further gas phase manipulation to stimulate biodegradation of the chelating agent after the contamination has been removed. The process ensures that the chelating agent is not attacked by bioorganisms in the soil prior to removal of the contamination, and that the chelating agent does not remain as a new contaminant after the process is completed. 5 figs.

  16. Sequestration of CO2 in Mixtures of Bauxite Residue and Saline Robert Dilmore, Peng Lu, Douglas Allen, Yee Soong,*, Sheila Hedges, Jaw K. Fu,4

    E-Print Network [OSTI]

    Zhu, Chen

    sources (such as fossil fuel-fired power plants) and the long-term storage of CO2 in underground, brine-b utilizing mixtures of caustic bauxite residue slurry (pH 13) and produced oil-field brine to sequester

  17. Situ treatment of contaminated groundwater

    DOE Patents [OSTI]

    McNab, Jr., Walt W. (Concord, CA); Ruiz, Roberto (Tracy, CA); Pico, Tristan M. (Livermore, CA)

    2001-01-01T23:59:59.000Z

    A system for treating dissolved halogenated organic compounds in groundwater that relies upon electrolytically-generated hydrogen to chemically reduce the halogenated compounds in the presence of a suitable catalyst. A direct current is placed across at least a pair, or an array, of electrodes which are housed within groundwater wells so that hydrogen is generated at the cathode and oxygen at the anode. A pump is located within the well housing in which the cathode(s) is(are) located and draws in groundwater where it is hydrogenated via electrolysis, passes through a well-bore treatment unit, and then transported to the anode well(s) for reinjection into the ground. The well-bore treatment involves a permeable cylinder located in the well bore and containing a packed bed of catalyst material that facilitates the reductive dehalogenation of the halogenated organic compounds by hydrogen into environmentally benign species such as ethane and methane. Also, electro-osmatic transport of contaminants toward the cathode also contributes to contaminant mass removal. The only above ground equipment required are the transfer pipes and a direct circuit power supply for the electrodes. The electrode wells in an array may be used in pairs or one anode well may be used with a plurality of cathode wells. The DC current flow between electrode wells may be periodically reversed which controls the formation of mineral deposits in the alkaline cathode well-bore water, as well as to help rejuvenate the catalysis.

  18. Probe for contamination detection in recyclable materials

    DOE Patents [OSTI]

    Taleyarkhan, Rusi

    2003-08-05T23:59:59.000Z

    A neutron detection system for detection of contaminants contained within a bulk material during recycling includes at least one neutron generator for neutron bombardment of the bulk material, and at least one gamma ray detector for detection of gamma rays emitted by contaminants within the bulk material. A structure for analyzing gamma ray data is communicably connected to the gamma ray detector, the structure for analyzing gamma ray data adapted. The identity and concentration of contaminants in a bulk material can also be determined. By scanning the neutron beam, discrete locations within the bulk material having contaminants can be identified. A method for recycling bulk material having unknown levels of contaminants includes the steps of providing at least one neutron generator, at least one gamma ray detector, and structure for analyzing gamma ray data, irradiating the bulk material with neutrons, and then determining the presence of at least one contaminant in the bulk material from gamma rays emitted from the bulk material.

  19. Migrating Contaminant Sticks To Minerals | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Migrating Contaminant Sticks To Minerals Aluminum oxide in common soil minerals captures uranium Using computational chemistry models, scientists at Pacific Northwest National...

  20. Carbon contamination topography analysis of EUV masks

    SciTech Connect (OSTI)

    Fan, Y.-J.; Yankulin, L.; Thomas, P.; Mbanaso, C.; Antohe, A.; Garg, R.; Wang, Y.; Murray, T.; Wuest, A.; Goodwin, F.; Huh, S.; Cordes, A.; Naulleau, P.; Goldberg, K. A.; Mochi, I.; Gullikson, E.; Denbeaux, G.

    2010-03-12T23:59:59.000Z

    The impact of carbon contamination on extreme ultraviolet (EUV) masks is significant due to throughput loss and potential effects on imaging performance. Current carbon contamination research primarily focuses on the lifetime of the multilayer surfaces, determined by reflectivity loss and reduced throughput in EUV exposure tools. However, contamination on patterned EUV masks can cause additional effects on absorbing features and the printed images, as well as impacting the efficiency of cleaning process. In this work, several different techniques were used to determine possible contamination topography. Lithographic simulations were also performed and the results compared with the experimental data.

  1. Chemistry of fluid inclusions in halite from the Salina group of the Michigan basin: Implications for Late Silurian seawater and the origin of sedimentary brines

    SciTech Connect (OSTI)

    Das, N.; Horita, J.; Holland, H.D. (Harvard Univ., Cambridge, MA (USA))

    1990-02-01T23:59:59.000Z

    Fluid was extracted from 18 fluid inclusions in halite of the Late Silurian Salina Group exposed in the Crystal Mine on the outskirts of Detroit, Michigan. Compared with modern seawater evaporated to the same degree, the inclusion fluids are severely depleted in SO{sub 4}{sup {minus}2}, somewhat depleted in Na{sup +} and Mg{sup +2}, and greatly enriched in Ca{sup +2}. The composition of the inclusion fluids can be derived from Silurian seawater with a composition close to that of modern seawater, if it is assumed that the composition of the Silurian seawater was modified by dolomitizing CaCO{sub 3}-rich sediments and by albitizing silicate minerals during its evolution into evaporite brines. Since the evolution of the brines involved a number of chemical reactions, it is impossible to recover the initial concentration of all of the major ions in the parent Silurian seawater from the composition of the inclusion fluids alone. It is likely, however, that the m{sub K+}/m{sub Br-} ratio and the functions in Late Silurian seawater had values close to those of modern seawater. Measurements of the isotopic composition of sulfur and of Sr in anhydrite within and associated with the halite host of the fluid inclusions are consistent with previous measurements of {delta}{sup 34}S in Silurian marine anhydrites and with the {sup 87}Sr/{sup 86}Sr ratios of Late Silurian marine carbonates.

  2. The CPA Equation of State and an Activity Coefficient Model for Accurate Molar Enthalpy Calculations of Mixtures with Carbon Dioxide and Water/Brine

    E-Print Network [OSTI]

    P. C. Myint; Y. Hao; A. Firoozabadi

    2015-04-20T23:59:59.000Z

    Thermodynamic property calculations of mixtures containing carbon dioxide (CO$_2$) and water, including brines, are essential in theoretical models of many natural and industrial processes. The properties of greatest practical interest are density, solubility, and enthalpy. Many models for density and solubility calculations have been presented in the literature, but there exists only one study, by Spycher and Pruess, that has compared theoretical molar enthalpy predictions with experimental data. In this report, we recommend two different models for enthalpy calculations: the CPA equation of state by Li and Firoozabadi, and the CO$_2$ activity coefficient model by Duan and Sun. We show that the CPA equation of state, which has been demonstrated to provide good agreement with density and solubility data, also accurately calculates molar enthalpies of pure CO$_2$, pure water, and both CO$_2$-rich and aqueous (H$_2$O-rich) mixtures of the two species. It is applicable to a wider range of conditions than the Spycher and Pruess model. In aqueous sodium chloride (NaCl) mixtures, we show that Duan and Sun's model yields accurate results for the partial molar enthalpy of CO$_2$. It can be combined with another model for the brine enthalpy to calculate the molar enthalpy of H$_2$O-CO$_2$-NaCl mixtures. We conclude by explaining how the CPA equation of state may be modified to further improve agreement with experiments. This generalized CPA is the basis of our future work on this topic.

  3. Biotreatment of groundwater contaminated with MTBE: interaction of common environmental co-contaminants

    E-Print Network [OSTI]

    Biotreatment of groundwater contaminated with MTBE: interaction of common environmental co November 2005 Key words: aerobic, biodegradation, BTEX, co-contaminant, MTBE, TBA Abstract Contamination of groundwater with the gasoline additive methyl tert-butyl ether (MTBE) is often accompanied by many aromatic

  4. Method of removing contaminants from plastic resins

    DOE Patents [OSTI]

    Bohnert, George W. (Harrisonville, MO); Hand, Thomas E. (Lee's Summit, MO); DeLaurentiis, Gary M. (Jamestown, CA)

    2008-11-18T23:59:59.000Z

    A method for removing contaminants from synthetic resin material containers using a first organic solvent system and a second carbon dioxide system. The organic solvent is utilized for removing the contaminants from the synthetic resin material and the carbon dioxide is used to separate any residual organic solvent from the synthetic resin material.

  5. Method for removing contaminants from plastic resin

    DOE Patents [OSTI]

    Bohnert, George W. (Harrisonville, MO); Hand, Thomas E. (Lee's Summit, MO); DeLaurentiis, Gary M. (Jamestown, CA)

    2008-12-30T23:59:59.000Z

    A method for removing contaminants from synthetic resin material containers using a first organic solvent system and a second carbon dioxide system. The organic solvent is utilized for removing the contaminants from the synthetic resin material and the carbon dioxide is used to separate any residual organic solvent from the synthetic resin material.

  6. Method of removing contaminants from plastic resins

    DOE Patents [OSTI]

    Bohnert,George W. (Harrisonville, MO); Hand,Thomas E. (Lee's Summit, MO); Delaurentiis,Gary M. (Jamestown, CA)

    2007-08-07T23:59:59.000Z

    A method for removing contaminants from synthetic resin material containers using a first organic solvent system and a second carbon dioxide system. The organic solvent is utilized for removing the contaminants from the synthetic resin material and the carbon dioxide is used to separate any residual organic solvent from the synthetic resin material.

  7. Remediation and Recovery of Uranium from Contaminated

    E-Print Network [OSTI]

    Lovley, Derek

    that Geobacter species can effectively remove uranium from contaminated groundwater by reducing soluble U emplaced in flow- through columns of uranium-contaminated sediments readily removed U(VI) from the groundwater, and 87% of the uranium that had been removed was recovered from the electrode surface after

  8. Method of removing oxidized contaminants from water

    DOE Patents [OSTI]

    Amonette, J.E.; Fruchter, J.S.; Gorby, Y.A.; Cole, C.R.; Cantrell, K.J.; Kaplan, D.I.

    1998-07-21T23:59:59.000Z

    The present invention is a method for removing oxidized contaminant(s) from water. More specifically, the invention has the steps of contacting water containing the oxidized contaminant(s) with a layered aluminosilicate having Fe(II). The aluminosilicate may contain naturally occurring Fe(II), or the Fe(II) may be produced by reducing Fe(III) that is initially present. Reduction may be either by exposure to a chemical or biological reductant. Contacting the water containing oxidized contaminant(s) may be by (1) injection of Fe(II)-containing layered aluminosilicate, via a well, into a saturated zone where it is likely to intercept the contaminated water; (2) injection of contaminated water into a vessel containing the Fe(II)-bearing layered aluminosilicate; and (3) first reducing Fe(III) in the layered aluminosilicate to Fe(II) by injection of a biological or chemical reductant, into an aquifer or vessel having sufficient Fe(III)-bearing aluminosilicate to produce the necessary Fe(II). 8 figs.

  9. In situ bioremediation of petrol contaminated groundwater

    E-Print Network [OSTI]

    Blouin-Demers, Gabriel

    21/11/08 1 In situ bioremediation of petrol contaminated groundwater Guido Miguel Delgadillo EVS and facts · Likelihood of contamination · Benefits of in situ bioremediation So... Ask not what groundwater · Intrinsic BR vs. Engineered BR Anaerobic Bioremediation (1) Background · Anaerobic conditions most likely

  10. Minimizing electrode contamination in an electrochemical cell

    DOE Patents [OSTI]

    Kim, Yu Seung; Zelenay, Piotr; Johnston, Christina

    2014-12-09T23:59:59.000Z

    An electrochemical cell assembly that is expected to prevent or at least minimize electrode contamination includes one or more getters that trap a component or components leached from a first electrode and prevents or at least minimizes them from contaminating a second electrode.

  11. Reduced-Order Model for the Geochemical Impacts of Carbon Dioxide, Brine and Trace Metal Leakage into an Unconfined, Oxidizing Carbonate Aquifer, Version 2.1

    SciTech Connect (OSTI)

    Bacon, Diana H.

    2013-03-31T23:59:59.000Z

    The National Risk Assessment Partnership (NRAP) consists of 5 U.S DOE national laboratories collaborating to develop a framework for predicting the risks associated with carbon sequestration. The approach taken by NRAP is to divide the system into components, including injection target reservoirs, wellbores, natural pathways including faults and fractures, groundwater and the atmosphere. Next, develop a detailed, physics and chemistry-based model of each component. Using the results of the detailed models, develop efficient, simplified models, termed reduced order models (ROM) for each component. Finally, integrate the component ROMs into a system model that calculates risk profiles for the site. This report details the development of the Groundwater Geochemistry ROM for the Edwards Aquifer at PNNL. The Groundwater Geochemistry ROM for the Edwards Aquifer uses a Wellbore Leakage ROM developed at LANL as input. The detailed model, using the STOMP simulator, covers a 5x8 km area of the Edwards Aquifer near San Antonio, Texas. The model includes heterogeneous hydraulic properties, and equilibrium, kinetic and sorption reactions between groundwater, leaked CO2 gas, brine, and the aquifer carbonate and clay minerals. Latin Hypercube sampling was used to generate 1024 samples of input parameters. For each of these input samples, the STOMP simulator was used to predict the flux of CO2 to the atmosphere, and the volume, length and width of the aquifer where pH was less than the MCL standard, and TDS, arsenic, cadmium and lead exceeded MCL standards. In order to decouple the Wellbore Leakage ROM from the Groundwater Geochemistry ROM, the response surface was transformed to replace Wellbore Leakage ROM input parameters with instantaneous and cumulative CO2 and brine leakage rates. The most sensitive parameters proved to be the CO2 and brine leakage rates from the well, with equilibrium coefficients for calcite and dolomite, as well as the number of illite and kaolinite sorption sites proving to be of secondary importance. The Groundwater Geochemistry ROM was developed using nonlinear regression to fit the response surface with a quadratic polynomial. The goodness of fit was excellent for the CO2 flux to the atmosphere, and very good for predicting the volumes of groundwater exceeding the pH, TDS, As, Cd and Pb threshold values.

  12. An integrated experimental and numerical study: Developing a reaction transport model that couples chemical reactions of mineral dissolution/precipitation with spatial and temporal flow variations in CO2/brine/rock systems

    Broader source: Energy.gov [DOE]

    Project objectives: Generate and characterize mineral dissolution/precipitation reactions in supercritical CO2/brine/rock systems under pressure-temperature-chemistry conditions resembling CO2injection into EGS. Characterize three-dimensional spatial and temporal distributions of rock structures subject to mineral dissolution/precipitation processes by X-ray tomography, SEM imaging, and Microprobe analysis.

  13. (Data in metric tons of lithium content unless otherwise noted) Domestic Production and Use: The only active lithium carbonate plant in the United States was a brine operation in

    E-Print Network [OSTI]

    94 LITHIUM (Data in metric tons of lithium content unless otherwise noted) Domestic Production and Use: The only active lithium carbonate plant in the United States was a brine operation in Nevada. Two companies produced a large array of downstream lithium compounds in the United States from domestic or South

  14. Influences of climate on aflatoxin producing fungi and aflatoxin contamination

    E-Print Network [OSTI]

    Cotty, Peter J.

    Influences of climate on aflatoxin producing fungi and aflatoxin contamination Peter J. Cotty a human exposure, crop contamination with aflatoxins causes significant economic loss for producers, marketers, and processors of diverse susceptible crops. Aflatoxin contamination occurs when specific fungi

  15. Particle Contamination on a Thermal Flying-Height Control Slider

    E-Print Network [OSTI]

    Liu, Nan; Bogy, David B.

    2010-01-01T23:59:59.000Z

    the investigation of particle contamination on a TFC slider.on particle ?ows and contamination of air bearing sliders.and Conclusion The particle contamination on a TFC slider is

  16. Complexity of Groundwater Contaminants at DOE Sites

    SciTech Connect (OSTI)

    Hazen, T.C.; Faybishenko, B.; Jordan, P.

    2010-12-03T23:59:59.000Z

    The U.S. Department of Energy (DOE) is responsible for the remediation and long-term stewardship of one of the world's largest groundwater contamination portfolios, with a significant number of plumes containing various contaminants, and considerable total mass and activity. As of 1999, the DOE's Office of Environmental Management was responsible for remediation, waste management, or nuclear materials and facility stabilization at 144 sites in 31 states and one U.S. territory, out of which 109 sites were expected to require long-term stewardship. Currently, 19 DOE sites are on the National Priority List. The total number of contaminated plumes on DOE lands is estimated to be 10,000. However, a significant number of DOE sites have not yet been fully characterized. The most prevalent contaminated media are groundwater and soil, although contaminated sediment, sludge, and surface water also are present. Groundwater, soil, and sediment contamination are present at 72% of all DOE sites. A proper characterization of the contaminant inventory at DOE sites is critical for accomplishing one of the primary DOE missions -- planning basic research to understand the complex physical, chemical, and biological properties of contaminated sites. Note that the definitions of the terms 'site' and 'facility' may differ from one publication to another. In this report, the terms 'site,' 'facility' or 'installation' are used to identify a contiguous land area within the borders of a property, which may contain more than one plume. The term 'plume' is used here to indicate an individual area of contamination, which can be small or large. Even though several publications and databases contain information on groundwater contamination and remediation technologies, no statistical analyses of the contaminant inventory at DOE sites has been prepared since the 1992 report by Riley and Zachara. The DOE Groundwater Data Base (GWD) presents data as of 2003 for 221 groundwater plumes at 60 DOE sites and facilities. Note that Riley and Zachara analyzed the data from only 18 sites/facilities including 91 plumes. In this paper, we present the results of statistical analyses of the data in the GWD as guidance for planning future basic and applied research of groundwater contaminants within the DOE complex. Our analyses include the evaluation of a frequency and ranking of specific contaminants and contaminant groups, contaminant concentrations/activities and total contaminant masses and activities. We also compared the results from analyses of the GWD with those from the 1992 report by Riley and Zachara. The difference between our results and those summarized in the 1992 report by Riley and Zachara could be caused by not only additional releases, but also by the use of modern site characterization methods, which more accurately reveal the extent of groundwater contamination. Contaminated sites within the DOE complex are located in all major geographic regions of the United States, with highly variable geologic, hydrogeologic, soil, and climatic conditions. We assume that the information from the 60 DOE sites included in the GWD are representative for the whole DOE complex. These 60 sites include the major DOE sites and facilities, such as Rocky Flats Environmental Technology Site, Colorado; Idaho National Laboratory, Idaho; Savannah River Site, South Carolina; Oak Ridge Reservation, Tennessee; and Hanford Reservation, Washington. These five sites alone ccount for 71% of the value of the remediation work.

  17. A Comparison of the Corrosion Resistance of Iron-Based Amorphous Metals and Austenitic Alloys in Synthetic Brines at Elevated Temperature

    SciTech Connect (OSTI)

    Farmer, J C

    2008-11-25T23:59:59.000Z

    Several hard, corrosion-resistant and neutron-absorbing iron-based amorphous alloys have now been developed that can be applied as thermal spray coatings. These new alloys include relatively high concentrations of Cr, Mo, and W for enhanced corrosion resistance, and substantial B to enable both glass formation and neutron absorption. The corrosion resistances of these novel alloys have been compared to that of several austenitic alloys in a broad range of synthetic brines, with and without nitrate inhibitor, at elevated temperature. Linear polarization and electrochemical impedance spectroscopy have been used for in situ measurement of corrosion rates for prolonged periods of time, while scanning electron microscopy (SEM) and energy dispersive analysis of X-rays (EDAX) have been used for ex situ characterization of samples at the end of tests. The application of these new coatings for the protection of spent nuclear fuel storage systems, equipment in nuclear service, steel-reinforced concrete will be discussed.

  18. The CPA Equation of State and an Activity Coefficient Model for Accurate Molar Enthalpy Calculations of Mixtures with Carbon Dioxide and Water/Brine

    E-Print Network [OSTI]

    Myint, P C; Firoozabadi, A

    2015-01-01T23:59:59.000Z

    Thermodynamic property calculations of mixtures containing carbon dioxide (CO$_2$) and water, including brines, are essential in theoretical models of many natural and industrial processes. The properties of greatest practical interest are density, solubility, and enthalpy. Many models for density and solubility calculations have been presented in the literature, but there exists only one study, by Spycher and Pruess, that has compared theoretical molar enthalpy predictions with experimental data. In this report, we recommend two different models for enthalpy calculations: the CPA equation of state by Li and Firoozabadi, and the CO$_2$ activity coefficient model by Duan and Sun. We show that the CPA equation of state, which has been demonstrated to provide good agreement with density and solubility data, also accurately calculates molar enthalpies of pure CO$_2$, pure water, and both CO$_2$-rich and aqueous (H$_2$O-rich) mixtures of the two species. It is applicable to a wider range of conditions than the Spy...

  19. Novel Cleanup Agents Designed Exclusively for Oil Field Membrane Filtration Systems Low Cost Field Demonstrations of Cleanup Agents in Controlled Experimental Environments

    SciTech Connect (OSTI)

    David Burnett; Harold Vance

    2007-08-31T23:59:59.000Z

    The goal of our project is to develop innovative processes and novel cleaning agents for water treatment facilities designed to remove fouling materials and restore micro-filter and reverse osmosis (RO) membrane performance. This project is part of Texas A&M University's comprehensive study of the treatment and reuse of oilfield brine for beneficial purposes. Before waste water can be used for any beneficial purpose, it must be processed to remove contaminants, including oily wastes such as residual petroleum hydrocarbons. An effective way of removing petroleum from brines is the use of membrane filters to separate oily waste from the brine. Texas A&M and its partners have developed highly efficient membrane treatment and RO desalination for waste water including oil field produced water. We have also developed novel and new cleaning agents for membrane filters utilizing environmentally friendly materials so that the water from the treatment process will meet U.S. EPA drinking water standards. Prototype micellar cleaning agents perform better and use less clean water than alternate systems. While not yet optimized, the new system restores essentially complete membrane flux and separation efficiency after cleaning. Significantly the amount of desalinated water that is required to clean the membranes is reduced by more than 75%.

  20. Civil and Environmental Engineering CSU Center for Contaminant Hydrology

    E-Print Network [OSTI]

    Civil and Environmental Engineering CSU ­ Center for Contaminant Hydrology Coordinator The Center for Contaminant Hydrology (CCH) ( HYPERLINK "http://www.engr.colostate.edu/CCH/" www

  1. assessing contaminant attenuation: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Conceptual model for human exposures to contamination in a solar energy facility. Click Kemner, Ken 5 DIAGNOSTIC ASSESSMENT 2 OF CONTAMINATED SITE PROBLEMS...

  2. Geochemical Controls on Contaminant Uranium in Vadose Hanford...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Controls on Contaminant Uranium in Vadose Hanford Formation Sediments at the 200 Area and 300 Area, Hanford Site, Geochemical Controls on Contaminant Uranium in Vadose Hanford...

  3. Microscopic Reactive Diffusion of Uranium in the Contaminated...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Reactive Diffusion of Uranium in the Contaminated Sediments at Hanford, United States. Microscopic Reactive Diffusion of Uranium in the Contaminated Sediments at Hanford, United...

  4. Perched-Water Analysis Related to Deep Vadose Zone Contaminant...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Perched-Water Analysis Related to Deep Vadose Zone Contaminant Transport and Impact to Groundwater. Perched-Water Analysis Related to Deep Vadose Zone Contaminant Transport and...

  5. Different Strategies for Biological Remediation of Perchlorate Contaminated Groundwater

    E-Print Network [OSTI]

    Wang, Yue

    2012-01-01T23:59:59.000Z

    Perchlorate Contamination in Groundwater: Legal, Chemical,of Perchlorate-Contaminated Groundwater. Federal Facilitiesof perchlorate from groundwater by activated carbon tailored

  6. H2FIRST Hydrogen Contaminant Detector Task: Requirements Document...

    Broader source: Energy.gov (indexed) [DOE]

    contamination detection and identifies the technical requirements for implementing a hydrogen contaminant detector (HCD) at a station. The rollout of hydrogen fueling stations,...

  7. Mitigation of radiation induced surface contamination

    DOE Patents [OSTI]

    Klebanoff, Leonard E. (Dublin, CA); Stulen, Richard H. (Livermore, CA)

    2003-01-01T23:59:59.000Z

    A process for mitigating or eliminating contamination and/or degradation of surfaces having common, adventitious atmospheric contaminants adsorbed thereon and exposed to radiation. A gas or a mixture of gases is introduced into the environment of a surface(s) to be protected. The choice of the gaseous species to be introduced (typically a hydrocarbon gas, water vapor, or oxygen or mixtures thereof) is dependent upon the contaminant as well as the ability of the gaseous species to bind to the surface to be protected. When the surface and associated bound species are exposed to radiation reactive species are formed that react with surface contaminants such as carbon or oxide films to form volatile products (e.g., CO, CO.sub.2) which desorb from the surface.

  8. Method of treating fluoride contaminated wastes

    SciTech Connect (OSTI)

    Davis, P.K.; Kakaria, V.K.

    1988-04-05T23:59:59.000Z

    A method for treating spent aluminum smelting potliner material containing fluoride contaminants is described which comprises: adding silica to the material to form a mixture thereof; elevating the temperature of the mixture within the range of 1,000/sup 0/ to 1,700/sup 0/C. to form a slag; providing sufficient silica in the mixture and forming the slag in the presence of sufficient water for pyrohydrolysis conditions resulting in the volatilization of substantially all of the fluoride contaminants mostly in the form of hydrogen fluoride; and cooling the slag remaining after volatilizatiion of substantially all of the fluoride contaminants to produce an insoluble silicate glass-residue containing any remaining portion of the fluoride contaminants in an immobile state.

  9. Guide to treatment technology for contaminated soils

    SciTech Connect (OSTI)

    Tran, H.; Aylward, R.

    1992-08-04T23:59:59.000Z

    This document is a guide for the screening of alternative treatment technologies for contaminated soils. The contents of this guide are organized into: 1. Introduction, II. Utilizing the table, III. Tables: Contamination Versus Technology, TV. Contaminant Waste Groups, and V. References. The four Contaminations Versus Technology tables are designed to identify the effectiveness and/or potential applicability of technologies to some or all compounds within specific waste groups. The tables also present limitations and special use considerations for the particular treatment technology. The phase of development of the technology is also included in the table. The phases are: Available, Innovative, and Emerging technologies. The technologies presented in this guide are organized according to the method of treatment. The four (4) treatment methods are Biological, Solidification/Stabilization, Thermal, and Chemical/Physical Treatment. There are several processing methods; some are well developed and proven, and others are in the development stage.

  10. Estimating exposure of terrestrial wildlife to contaminants

    SciTech Connect (OSTI)

    Sample, B.E.; Suter, G.W. II

    1994-09-01T23:59:59.000Z

    This report describes generalized models for the estimation of contaminant exposure experienced by wildlife on the Oak Ridge Reservation. The primary exposure pathway considered is oral ingestion, e.g. the consumption of contaminated food, water, or soil. Exposure through dermal absorption and inhalation are special cases and are not considered hereIN. Because wildlife mobile and generally consume diverse diets and because environmental contamination is not spatial homogeneous, factors to account for variation in diet, movement, and contaminant distribution have been incorporated into the models. To facilitate the use and application of the models, life history parameters necessary to estimate exposure are summarized for 15 common wildlife species. Finally, to display the application of the models, exposure estimates were calculated for four species using data from a source operable unit on the Oak Ridge Reservation.

  11. DIAGNOSTIC ASSESSMENT 2 OF CONTAMINATED SITE PROBLEMS

    E-Print Network [OSTI]

    Ma, Lena

    in the environment and undergo complex interactions in more than one environmental medium. Contaminated sites should released into the environment will be controlled by a complex set of processes (such as intermedia

  12. Modelling Bioremediation of Uranium Contaminated Aquifers 

    E-Print Network [OSTI]

    Rotter, Ben E G

    2008-01-01T23:59:59.000Z

    Radionuclide extraction, processing and storage have resulted in a legacy of radionuclide-contaminated groundwater aquifers worldwide. An emerging remediation technology for such sites is the in situ immobilisation of ...

  13. Method for removing contaminants from plastic resin

    DOE Patents [OSTI]

    Bohnert, George W. (Harrisonville, MO); Hand, Thomas E. (Lee's Summit, MO); DeLaurentiis, Gary M. (Jamestown, CA)

    2008-12-09T23:59:59.000Z

    A resin recycling method that produces essentially contaminant-free synthetic resin material in an environmentally safe and economical manner. The method includes receiving the resin in container form. The containers are then ground into resin particles. The particles are exposed to a solvent, the solvent contacting the resin particles and substantially removing contaminants on the resin particles. After separating the particles and the resin, a solvent removing agent is used to remove any residual solvent remaining on the resin particles after separation.

  14. Programmatic methods for addressing contaminated volume uncertainties.

    SciTech Connect (OSTI)

    DURHAM, L.A.; JOHNSON, R.L.; RIEMAN, C.R.; SPECTOR, H.L.; Environmental Science Division; U.S. ARMY CORPS OF ENGINEERS BUFFALO DISTRICT

    2007-01-01T23:59:59.000Z

    Accurate estimates of the volumes of contaminated soils or sediments are critical to effective program planning and to successfully designing and implementing remedial actions. Unfortunately, data available to support the preremedial design are often sparse and insufficient for accurately estimating contaminated soil volumes, resulting in significant uncertainty associated with these volume estimates. The uncertainty in the soil volume estimates significantly contributes to the uncertainty in the overall project cost estimates, especially since excavation and off-site disposal are the primary cost items in soil remedial action projects. The Army Corps of Engineers Buffalo District's experience has been that historical contaminated soil volume estimates developed under the Formerly Utilized Sites Remedial Action Program (FUSRAP) often underestimated the actual volume of subsurface contaminated soils requiring excavation during the course of a remedial activity. In response, the Buffalo District has adopted a variety of programmatic methods for addressing contaminated volume uncertainties. These include developing final status survey protocols prior to remedial design, explicitly estimating the uncertainty associated with volume estimates, investing in predesign data collection to reduce volume uncertainties, and incorporating dynamic work strategies and real-time analytics in predesign characterization and remediation activities. This paper describes some of these experiences in greater detail, drawing from the knowledge gained at Ashland1, Ashland2, Linde, and Rattlesnake Creek. In the case of Rattlesnake Creek, these approaches provided the Buffalo District with an accurate predesign contaminated volume estimate and resulted in one of the first successful FUSRAP fixed-price remediation contracts for the Buffalo District.

  15. A petroleum contaminated soil bioremediation facility

    SciTech Connect (OSTI)

    Lombard, K.; Hazen, T.

    1994-06-01T23:59:59.000Z

    The amount of petroleum contaminated soil (PCS) at the Savannah River site (SRS) that has been identified, excavated and is currently in storage has increased several fold during the last few years. Several factors have contributed to this problem: (1) South Carolina Department of Health ad Environmental control (SCDHEC) lowered the sanitary landfill maximum concentration for total petroleum hydrocarbons (TPH) in the soil from 500 to 100 parts per million (ppm), (2) removal and replacement of underground storage tanks at several sites, (3) most recently SCDHEC disallowed aeration for treatment of contaminated soil, and (4) discovery of several very large contaminated areas of soil associated with leaking underground storage tanks (LUST), leaking pipes, disposal areas, and spills. Thus, SRS has an urgent need to remediate large quantities of contaminated soil that are currently stockpiled and the anticipated contaminated soils to be generated from accidental spills. As long as we utilize petroleum based compounds at the site, we will continue to generate contaminated soil that will require remediation.

  16. Owls as Biomonitors of Environmental Contamination Steven R. Sheffield1

    E-Print Network [OSTI]

    Owls as Biomonitors of Environmental Contamination Steven R. Sheffield1 Abstract.--Much like of environmental contamination. These species provide an "early warning system" for toxic contaminants (Pandion haliaetus) have been widely used as biomonitors of aquatic contamination. However, few higher

  17. INVESTIGATION OF IONIC CONTAMINATION REMOVAL FROM SILICON DIOXIDE SURFACES

    E-Print Network [OSTI]

    Suni, Ian Ivar

    INVESTIGATION OF IONIC CONTAMINATION REMOVAL FROM SILICON DIOXIDE SURFACES H. Lin, A. A. Busnaina, and I. I. Suni T he removal of ionic contaminants from silicon surfaces surface contamination level canM Communications L td. INTRODUCTION with increasing frequency and power, and decreases Contamination removal is one

  18. Method of producing hydrogen, and rendering a contaminated biomass inert

    DOE Patents [OSTI]

    Bingham, Dennis N. (Idaho Falls, ID) [Idaho Falls, ID; Klingler, Kerry M. (Idaho Falls, ID) [Idaho Falls, ID; Wilding, Bruce M. (Idaho Falls, ID) [Idaho Falls, ID

    2010-02-23T23:59:59.000Z

    A method for rendering a contaminated biomass inert includes providing a first composition, providing a second composition, reacting the first and second compositions together to form an alkaline hydroxide, providing a contaminated biomass feedstock and reacting the alkaline hydroxide with the contaminated biomass feedstock to render the contaminated biomass feedstock inert and further producing hydrogen gas, and a byproduct that includes the first composition.

  19. agricultural soil contaminated: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Optimal Agricultural Countermeasure Strategies for a Hypothetical Contamination Environmental Management and Restoration Websites Summary: Optimal Agricultural...

  20. Bacterial and Protozoal Contamination of Nearshore Marine Environments in California, with Ecologically Sustainable Management

    E-Print Network [OSTI]

    Atwill, Edward R.; Conrad, Patricia A.

    2008-01-01T23:59:59.000Z

    Title: Reducing microbial contamination in runoff fromBacterial and Protozoal Contamination of Nearshore Marine

  1. 24/02/2012 12:49SPE Projects, Facilities & Construction -CO2/Brine Surface Dissolution and Injection: CO2 Storage Enhancement Page 1 of 1http://www.spe.org/ejournals/jsp/journalapp.jsp?pageType=Preview&jid=EFC&pdfChronicleId=090147628022501b&mid=SPE-12471

    E-Print Network [OSTI]

    Haszeldine, Stuart

    24/02/2012 12:49SPE Projects, Facilities & Construction - CO2/Brine Surface Dissolution of Petroleum Engineers SPE Projects, Facilities & Construction Volume 6, Number 1, March 2011, pp. 41-53 SPE

  2. Basic radiological studies contamination control experiments

    SciTech Connect (OSTI)

    Duce, S.W.; Winberg, M.R.; Freeman, A.L.

    1989-09-01T23:59:59.000Z

    This report describes the results of experiments relating to contamination control performed in support of the Environmental Restoration Programs Retrieval Project. During the years 1950 to 1970 waste contaminated with plutonium and other transuranic radionuclides was disposed of in shallow land-filled pits and trenches at the Idaho National Engineering Laboratory. Due to potential for migration of radionuclides to an existing aquifer the feasibility of retrieving and repackaging the waste for placement in a final repository is being examined as part of a retrieval project. Contamination control experiments were conducted to determine expected respirable and nonrespirable plutonium contaminated dust fractions and the effectiveness of various dust suppression techniques. Three soil types were tested to determine respirable fractions: Rocky Flats Plant generic soil, Radioactive Waste Management Complex generic soil, and a 1:1 blend of the two soil types. Overall, the average respirable fraction of airborne dust was 5.4% by weight. Three contamination control techniques were studied: soil fixative sprays, misting agents, and dust suppression agents. All of the tested agents proved to be effective in reducing dust in the air. Details of product performance and recommended usage are discussed.

  3. International symposium on oilfield chemistry: Proceedings

    SciTech Connect (OSTI)

    NONE

    1995-11-01T23:59:59.000Z

    This volume contains 66 papers presented at the symposium related to the following topics in oil field chemistry: waste treatment of produced waters; methods for enhanced recovery of petroleum (mainly surfactants, polymers, and carbon dioxide injection); cement hydration and additives; drilling fluid stability; paraffin deposition in wells and pipelines; scale control and corrosion inhibitors; displacement fluid wettability and environmental transport; fracturing fluids; formation damage; asphaltene removal; and plugging agents. All papers have been processed separately for inclusion on the data base.

  4. ROCKY MOUNTAIN OILFIELD TESTING CENTER MICROTURBINE PROJECT

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    electrical power. 1 MICROTURBINE-GENERATOR SYSTEM: There are several manufacturers of gas microturbine-generators. The system that was tested was a Capstone Turbine Corporation...

  5. Copyright 2005 POSC Intelligent Oilfield Operations

    E-Print Network [OSTI]

    Brock, David

    POSC Source: Downes & Mui, "Unleashing the Killer App" #12;Oil fields of the future: real-time oil, London Members + SIG Members: > 80 Oil BP, ChevronTexaco, ExxonMobil, Hydro, ONGC, Pioneer, Shell Economics Reservoir Engineering Expl Geology Petrophysics Petroleum Engineering Drilling Engineering

  6. Rangely Oilfield Geothermal Area | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnualProperty Edit with form History Facebook iconQuito,Jump to:Radiant ElectricRamkyRange

  7. Oilfield Equipment Market | OpenEI Community

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere I Geothermal Pwer PlantMunhall,Missouri: EnergyExcellenceOffice of State LandsOhio: Energy

  8. Rangely Oilfield Geothermal Area | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere IRaghuraji Agro Industries Pvt Ltd Jump to: navigation, search Name:Rancia 2

  9. Regulatory strategies for remediation of contaminated sediments

    SciTech Connect (OSTI)

    Zar, H. [Environmental Protection Agency, Chicago, IL (United States)

    1995-12-31T23:59:59.000Z

    A number of federal and state laws may be used to obtain remediation of contaminated sediments in the US. Until recently, the most prominent approaches at the federal level were the use of Superfund authorities for sites on the National priority List and navigational dredging activity by the Corps of Engineers. However, with the increasing concern about contaminated sediments, regional offices of the US Environmental Protection Agency (EPA) and state agencies have begun to use a greater variety of regulatory approaches, both individually and in combination. These efforts have been particularly evident in the Great Lakes and are now being extended nationwide, as embodied in the EPA`s Contaminated Sediment Management Strategy. This paper will describe some of the regulatory approaches being applied, case examples in the Great Lakes area, and the expected directions of these efforts, as embodied in the national strategy.

  10. Contaminant trap for gas-insulated apparatus

    DOE Patents [OSTI]

    Adcock, James L. (Knoxville, TN); Pace, Marshall O. (Knoxville, TN); Christophorou, Loucas G. (Oak Ridge, TN)

    1984-01-01T23:59:59.000Z

    A contaminant trap for a gas-insulated electrical conductor is provided. A resinous dielectric body such as Kel-F wax, grease or other sticky polymeric or oligomeric compound is disposed on the inside wall of the outer housing for the conductor. The resinous body is sufficiently sticky at ambient temperatures to immobilize contaminant particles in the insulating gas on the exposed surfaces thereof. An electric resistance heating element is disposed in the resinous body to selectively raise the temperature of the resinous body to a molten state so that the contaminant particles collected on the surface of the body sink into the body so that the surface of the resinous body is renewed to a particle-less condition and, when cooled, returns to a sticky collecting surface.

  11. Apparatus for measuring surface particulate contamination

    DOE Patents [OSTI]

    Woodmansee, Donald E. (Simpsonville, SC)

    2002-01-01T23:59:59.000Z

    An apparatus for measuring surface particulate contamination includes a tool for collecting a contamination sample from a target surface, a mask having an opening of known area formed therein for defining the target surface, and a flexible connector connecting the tool to the mask. The tool includes a body portion having a large diameter section defining a surface and a small diameter section extending from the large diameter section. A particulate collector is removably mounted on the surface of the large diameter section for collecting the contaminants. The tool further includes a spindle extending from the small diameter section and a spool slidingly mounted on the spindle. A spring is disposed between the small diameter section and the spool for biasing the spool away from the small diameter section. An indicator is provided on the spindle so as to be revealed when the spool is pressed downward to compress the spring.

  12. In situ remediation of uranium contaminated groundwater

    SciTech Connect (OSTI)

    Dwyer, B.P.; Marozas, D.C. [Sandia National Labs., Albuquerque, NM (United States)

    1997-12-31T23:59:59.000Z

    In an effort to develop cost-efficient techniques for remediating uranium contaminated groundwater at DOE Uranium Mill Tailing Remedial Action (UMTRA) sites nationwide, Sandia National Laboratories (SNL) deployed a pilot scale research project at an UMTRA site in Durango, CO. Implementation included design, construction, and subsequent monitoring of an in situ passive reactive barrier to remove Uranium from the tailings pile effluent. A reactive subsurface barrier is produced by emplacing a reactant material (in this experiment - various forms of metallic iron) in the flow path of the contaminated groundwater. Conceptually the iron media reduces and/or adsorbs uranium in situ to acceptable regulatory levels. In addition, other metals such as Se, Mo, and As have been removed by the reductive/adsorptive process. The primary objective of the experiment was to eliminate the need for surface treatment of tailing pile effluent. Experimental design, and laboratory and field preliminary results are discussed with regard to other potential contaminated groundwater treatment applications.

  13. In situ remediation of uranium contaminated groundwater

    SciTech Connect (OSTI)

    Dwyer, B.P.; Marozas, D.C.

    1997-02-01T23:59:59.000Z

    In an effort to develop cost-efficient techniques for remediating uranium contaminated groundwater at DOE Uranium Mill Tailing Remedial Action (UMTRA) sites nationwide, Sandia National Laboratories (SNL) deployed a pilot scale research project at an UMTRA site in Durango, CO. Implementation included design, construction, and subsequent monitoring of an in situ passive reactive barrier to remove Uranium from the tailings pile effluent. A reactive subsurface barrier is produced by emplacing a reactant material (in this experiment various forms of metallic iron) in the flow path of the contaminated groundwater. Conceptually the iron media reduces and/or adsorbs uranium in situ to acceptable regulatory levels. In addition, other metals such as Se, Mo, and As have been removed by the reductive/adsorptive process. The primary objective of the experiment was to eliminate the need for surface treatment of tailing pile effluent. Experimental design, and laboratory and field results are discussed with regard to other potential contaminated groundwater treatment applications.

  14. How to deal with radiologically contaminated vegetation

    SciTech Connect (OSTI)

    Wilde, E.W.; Murphy, C.E.; Lamar, R.T.; Larson, M.J.

    1996-12-31T23:59:59.000Z

    This report describes the findings from a literature review conducted as part of a Department of Energy, Office of Technology Development Biomass Remediation Task. The principal objective of this project is to develop a process or group of processes to treat radiologically contaminated vegetation in a manner that minimizes handling, processing, and treatment costs. Contaminated, woody vegetation growing on waste sites at SRS poses a problem to waste site closure technologies that are being considered for these sites. It is feared that large sections of woody vegetation (logs) can not be buried in waste sites where isolation of waste is accomplished by capping the site. Logs or large piles of woody debris have the potential of decaying and leaving voids under the cap. This could lead to cap failure and entrance of water into the waste. Large solid objects could also interfere with treatments like in situ mixing of soil with grout or other materials to encapsulate the contaminated sediments and soils in the waste sites. Optimal disposal of the wood includes considerations of volume reduction, treatment of the radioactive residue resulting from volume reduction, or confinement without volume reduction. Volume reduction consists primarily of removing the carbon, oxygen, and hydrogen in the wood, leaving an ash that would contain most of the contamination. The only contaminant that would be released by volume reduction would by small amounts of the radioactive isotope of hydrogen, tritium. The following sections will describe the waste sites at SRS which contain contaminated vegetation and are potential candidates for the technology developed under this proposal. The description will provide a context for the magnitude of the problem and the logistics of the alternative solutions that are evaluated later in the review. 76 refs.

  15. Bioremediation of Petroleum Hydrocarbon Contaminated Sites

    SciTech Connect (OSTI)

    Paul Fallgren

    2009-03-30T23:59:59.000Z

    Bioremediation has been widely applied in the restoration of petroleum hydrocarbon-contaminated. Parameters that may affect the rate and efficiency of biodegradation include temperature, moisture, salinity, nutrient availability, microbial species, and type and concentration of contaminants. Other factors can also affect the success of the bioremediation treatment of contaminants, such as climatic conditions, soil type, soil permeability, contaminant distribution and concentration, and drainage. Western Research Institute in conjunction with TechLink Environmental, Inc. and the U.S. Department of Energy conducted laboratory studies to evaluate major parameters that contribute to the bioremediation of petroleum-contaminated drill cuttings using land farming and to develop a biotreatment cell to expedite biodegradation of hydrocarbons. Physical characteristics such as soil texture, hydraulic conductivity, and water retention were determined for the petroleum hydrocarbon contaminated soil. Soil texture was determined to be loamy sand to sand, and high hydraulic conductivity and low water retention was observed. Temperature appeared to have the greatest influence on biodegradation rates where high temperatures (>50 C) favored biodegradation. High nitrogen content in the form of ammonium enhanced biodegradation as well did the presence of water near field water holding capacity. Urea was not a good source of nitrogen and has detrimental effects for bioremediation for this site soil. Artificial sea water had little effect on biodegradation rates, but biodegradation rates decreased after increasing the concentrations of salts. Biotreatment cell (biocell) tests demonstrated hydrocarbon biodegradation can be enhanced substantially when utilizing a leachate recirculation design where a 72% reduction of hydrocarbon concentration was observed with a 72-h period at a treatment temperature of 50 C. Overall, this study demonstrates the investigation of the effects of environmental parameters on bioremediation is important in designing a bioremediation system to reduce petroleum hydrocarbon concentrations in impacted soils.

  16. Programmatic methods for addressing contaminated volume uncertainties

    SciTech Connect (OSTI)

    Rieman, C.R.; Spector, H.L. [U.S. Army Corps of Engineers Buffalo District, Buffalo, NY (United States); Durham, L.A.; Johnson, R.L. [Argonne National Laboratory, Environmental Science Div., IL (United States)

    2007-07-01T23:59:59.000Z

    Accurate estimates of the volumes of contaminated soils or sediments are critical to effective program planning and to successfully designing and implementing remedial actions. Unfortunately, data available to support the pre-remedial design are often sparse and insufficient for accurately estimating contaminated soil volumes, resulting in significant uncertainty associated with these volume estimates. The uncertainty in the soil volume estimates significantly contributes to the uncertainty in the overall project cost estimates, especially since excavation and off-site disposal are the primary cost items in soil remedial action projects. The U.S. Army Corps of Engineers Buffalo District's experience has been that historical contaminated soil volume estimates developed under the Formerly Utilized Sites Remedial Action Program (FUSRAP) often underestimated the actual volume of subsurface contaminated soils requiring excavation during the course of a remedial activity. In response, the Buffalo District has adopted a variety of programmatic methods for addressing contaminated volume uncertainties. These include developing final status survey protocols prior to remedial design, explicitly estimating the uncertainty associated with volume estimates, investing in pre-design data collection to reduce volume uncertainties, and incorporating dynamic work strategies and real-time analytics in pre-design characterization and remediation activities. This paper describes some of these experiences in greater detail, drawing from the knowledge gained at Ashland 1, Ashland 2, Linde, and Rattlesnake Creek. In the case of Rattlesnake Creek, these approaches provided the Buffalo District with an accurate pre-design contaminated volume estimate and resulted in one of the first successful FUSRAP fixed-price remediation contracts for the Buffalo District. (authors)

  17. System for removing contaminants from plastic resin

    DOE Patents [OSTI]

    Bohnert, George W. (Harrisonville, MO); Hand, Thomas E. (Lee's Summit, MO); DeLaurentiis, Gary M. (Jamestown, CA)

    2010-11-23T23:59:59.000Z

    A resin recycling system that produces essentially contaminant-free synthetic resin material in an environmentally safe and economical manner. The system includes receiving the resin in container form. A grinder grinds the containers into resin particles. The particles are exposed to a solvent in one or more solvent wash vessels, the solvent contacting the resin particles and substantially removing contaminants on the resin particles. A separator is used to separate the resin particles and the solvent. The resin particles are then placed in solvent removing element where they are exposed to a solvent removing agent which removes any residual solvent remaining on the resin particles after separation.

  18. Hydrogen Contamination Detector Workshop | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onYouTube YouTube Note: Since the.pdfBreaking of Blythe SolarContamination Detector Workshop Hydrogen Contamination

  19. West Hackberry Strategic Petroleum Reserve site brine disposal monitoring, Year I report. Volume V. Supporting data for estuarine hydrology, discharge plume analysis, chemical oceanography, biological oceanography, and data management. Final report

    SciTech Connect (OSTI)

    DeRouen, L.R.; Hann, R.W.; Casserly, D.M.; Giammona, C.; Lascara, V.J. (eds.)

    1983-02-01T23:59:59.000Z

    This project centers around the Strategic Petroleum Site (SPR) known as the West Hackberry salt dome which located in southwestern Louisiana, and which is designed to store 241 million barrels of crude oil. Oil storage caverns are formed by injecting water into salt deposits, and pumping out the resulting brine. Studies described in this report were designed as follow-on studies to three months of pre-discharge characterization work, and include data collected during the first year of brine leaching operations. The objectives were to: (1) characterize the environment in terms of physical, chemical and biological attributes; (2) determine if significant adverse changes in ecosystem productivity and stability of the biological community are occurring as a result of brine discharge; and (3) determine the magnitude of any change observed. Volume V contains appendices for the following: supporting data for estuarine hydrology and hydrography; supporting data analysis of discharge plume; supporting data for water and sediment chemistry; CTD/DO and pH profiles during biological monitoring; supporting data for nekton; and supporting data for data management.

  20. Use of data obtained from core tests in the design and operation of spent brine injection wells in geopressured or geothermal systems

    SciTech Connect (OSTI)

    Jorda, R.M.

    1980-03-01T23:59:59.000Z

    The effects of formation characteristics on injection well performance are reviewed. Use of data acquired from cores taken from injection horizons to predict injectivity is described. And methods for utilizing data from bench scale testing of brine and core samples to optimize injection well design are presented. Currently available methods and equipment provide data which enable the optimum design of injection wells through analysis of cores taken from injection zones. These methods also provide a means of identifying and correcting well injection problems. Methods described in this report are: bulk density measurement; porosity measurement; pore size distribution analysis; permeability measurement; formation grain size distribution analysis; core description (lithology) and composition; amount, type and distribution of clays and shales; connate water analysis; consolidatability of friable reservoir rocks; grain and pore characterization by scanning electron microscopy; grain and pore characterization by thin section analysis; permeability damage and enhancement tests; distribution of water-borne particles in porous media; and reservoir matrix acidizing effectiveness. The precise methods of obtaining this information are described, and their use in the engineering of injection wells is illustrated by examples, where applicable. (MHR)

  1. Passive treatment of wastewater and contaminated groundwater

    DOE Patents [OSTI]

    Phifer, Mark A. (N. Augusta, SC); Sappington, Frank C. (Dahlonega, GA); Millings, Margaret R. (N. Augusta, SC); Turick, Charles E. (Aiken, SC); McKinsey, Pamela C. (Aiken, SC)

    2007-11-06T23:59:59.000Z

    A bioremediation system using inorganic oxide-reducing microbial consortia for the treatment of, inter alia coal mine and coal yard runoff uses a containment vessel for contaminated water and a second, floating phase for nutrients. Biodegradable oils are preferred nutrients.

  2. Passive treatment of wastewater and contaminated groundwater

    DOE Patents [OSTI]

    Phifer, Mark A.; Sappington, Frank C.; Millings, Margaret R.; Turick, Charles E.; McKinsey, Pamela C.

    2006-12-12T23:59:59.000Z

    A bioremediation system using inorganic oxide-reducing microbial consortia for the treatment of, inter alia coal mine and coal yard runoff uses a containment vessel for contaminated water and a second, floating phase for nutrients. Biodegradable oils are preferred nutrients.

  3. Effects of Nitrogen contamination in liquid Argon

    E-Print Network [OSTI]

    R. Acciarri; M. Antonello; B. Baibussinov; M. Baldo-Ceolin; P. Benetti; F. Calaprice; E. Calligarich; M. Cambiaghi; N. Canci; F. Carbonara; F. Cavanna; S. Centro; A. G. Cocco; F. Di Pompeo; G. Fiorillo; C. Galbiati; V. Gallo; L. Grandi; G. Meng; I. Modena; C. Montanari; O. Palamara; L. Pandola; F. Pietropaolo; G. L. Raselli; M. Roncadelli; M. Rossella; C. Rubbia; E. Segreto; A. M. Szelc; S. Ventura; C. Vignoli

    2008-04-08T23:59:59.000Z

    A dedicated test of the effects of Nitrogen contamination in liquid Argon has been performed at the INFN-Gran Sasso Laboratory (LNGS, Italy) within the WArP R&D program. A detector has been designed and assembled for this specific task and connected to a system for the injection of controlled amounts of gaseous Nitrogen into the liquid Argon. Purpose of the test is to detect the reduction of the Ar scintillation light emission as a function of the amount of the Nitrogen contaminant injected in the Argon volume. A wide concentration range, spanning from about 10^-1 ppm up to about 10^3 ppm, has been explored. Measurements have been done with electrons in the energy range of minimum ionizing particles (gamma-conversion from radioactive sources). Source spectra at different Nitrogen contaminations are analyzed, showing sensitive reduction of the scintillation yield at increasing concentrations. The rate constant of the light quenching process induced by Nitrogen in liquid Ar has been found to be k(N2)=0.11 micros^-1 ppm^-1. Direct PMT signals acquisition at high time resolution by fast Waveform recording allowed to extract with high precision the main characteristics of the scintillation light emission in pure and contaminated LAr. In particular, the decreasing behavior in lifetime and relative amplitude of the slow component is found to be appreciable from O(1 ppm) of Nitrogen concentrations.

  4. Oxygen and Nitrogen Contamination During Arc Welding

    E-Print Network [OSTI]

    Eagar, Thomas W.

    ) ) : ,- Oxygen and Nitrogen Contamination During Arc Welding T. W. Eagar Department of }faterials, shielded metal arc, self-shielded metal arc, and submerged arc welding are reviewed. Calcu- lations upon heating is also discussed. Introduction Oxygen and nitrogen ~ontamination of weld metal

  5. Contaminant Transport in Municipal Water Systems

    E-Print Network [OSTI]

    Stockie, John

    Chapter 1 Contaminant Transport in Municipal Water Systems Presented at the 3rd PIMS Industrial the inverse problem. We begin in the following sections with an overview of the physics of ow in water forcing to raise the hydraulic head of the water in the network. The nodes are either junctions, tanks

  6. The Health Risks: Seafood Contamination, Harmful Algal

    E-Print Network [OSTI]

    health products from the sea. What is the central issue? Why should I care? How will OHH researchThe Health Risks: Seafood Contamination, Harmful Algal Blooms and Polluted Beaches Seafood associated public health costs. Announcing a New Interagency Report on Oceans and Human Health Research

  7. Active airborne contamination control using electrophoresis

    SciTech Connect (OSTI)

    Veatch, B.D.

    1994-06-01T23:59:59.000Z

    In spite of our best efforts, radioactive airborne contamination continues to be a formidable problem at many of the Department of Energy (DOE) weapons complex sites. For workers that must enter areas with high levels of airborne contamination, personnel protective equipment (PPE) can become highly restrictive, greatly diminishing productivity. Rather than require even more restrictive PPE for personnel in some situations, the Rocky Flats Plant (RFP) is actively researching and developing methods to aggressively combat airborne contamination hazards using electrophoretic technology. With appropriate equipment, airborne particulates can be effectively removed and collected for disposal in one simple process. The equipment needed to implement electrophoresis is relatively inexpensive, highly reliable, and very compact. Once airborne contamination levels are reduced, less PPE is required and a significant cost savings may be realized through decreased waste and maximized productivity. Preliminary ``cold,`` or non-radioactive, testing results at the RFP have shown the technology to be effective on a reasonable scale, with several potential benefits and an abundance of applications.

  8. RESEARCH ARTICLE Assessment of metal contaminations leaching

    E-Print Network [OSTI]

    Short, Daniel

    RESEARCH ARTICLE Assessment of metal contaminations leaching out from recycling plastic bottles syntheses, partic- ularly antimony, human exposure to metal release from plastic bottles has been a serious from a series of recycling plastic bottles upon treatments. Methodology In this study, leaching

  9. A new tool for contamination analysis

    SciTech Connect (OSTI)

    Meltzer, M.; Gregg, H.

    1996-06-01T23:59:59.000Z

    The Contamination Analysis Unit (CAU) is a sensing system that facilitates a new approach to industrial cleaning. Through use of portable mass spectrometry and various desorption techniques, the CAU provides in-process, near-real-time measurement of surface cleanliness levels. It can be of help in significantly reducing hazardous waste generation and toxic air emissions from manufacturing operations.

  10. contaminated The U.S.Army Corps of EngineersCenterfor ContaminatedSediments

    E-Print Network [OSTI]

    US Army Corps of Engineers

    and OceanWaters 53 Bioassays 53 ContaminantPathway Test '%Dredging Operationsand Enviro '% USACE Risk Assessment Guidance for Con- Research (DOER) Program : &ina6d gebents %Environmental Impact EvaIua USACE

  11. Method to remove uranium/vanadium contamination from groundwater

    DOE Patents [OSTI]

    Metzler, Donald R. (DeBeque, CO); Morrison, Stanley (Grand Junction, CO)

    2004-07-27T23:59:59.000Z

    A process for removing uranium/vanadium-based contaminants from groundwater using a primary in-ground treatment media and a pretreatment media that chemically adjusts the groundwater contaminant to provide for optimum treatment by the primary treatment media.

  12. Method to Remove Uranium/Vanadium Contamination from Groundwater

    DOE Patents [OSTI]

    Metzler, Donald R.; Morrison Stanley

    2004-07-27T23:59:59.000Z

    A process for removing uranium/vanadium-based contaminants from groundwater using a primary in-ground treatment media and a pretreatment media that chemically adjusts the groundwater contaminant to provide for optimum treatment by the primary treatment media.

  13. Analytical modeling of contaminant transport and horizontal well hydraulics 

    E-Print Network [OSTI]

    Park, Eungyu

    2004-09-30T23:59:59.000Z

    This dissertation is composed of three parts of major contributions. In Chapter II, we discuss analytical study of contaminant transport from a finite source in a finite-thickness aquifer. This chapter provides analytical solutions of contaminant...

  14. HOSPITAL VENTILATION STANDARDS AND ENERGY CONSERVATION: CHEMICAL CONTAMINATION OF HOSPITAL AIR. FINAL REPORT.

    E-Print Network [OSTI]

    Rainer, David

    2012-01-01T23:59:59.000Z

    STANDARDS AND ENERGY CONSERVATION: CHH1ICAL CONTAMINATION OFSTANDARDS AND ENERGY CONSERVATION CHEMICAL CONTAMINATION OFSTANDARDS AND ENERGY CONSERVATION: CHEMICAL CONTAMINATION OF

  15. CONTAMINATION OF GROUNDWATER BY ORGANIC POLLUTANTS LEACHED FROM IN-SITU SPENT SHALE

    E-Print Network [OSTI]

    Amy, Gary L.

    2013-01-01T23:59:59.000Z

    of California. LBL-10526 CONTAMINATION OF GROUNDWATER BYABSTRACT for contamination ter shale was studied in a seriesassessment of the ial contamination of ground~ water by c

  16. Narratives of Contamination: Representations of Race, Gender, and Disease in Nineteenth Century Cuban Fiction

    E-Print Network [OSTI]

    Zander, Jessica Selene

    2012-01-01T23:59:59.000Z

    Narratives of Contamination: Representations of Race,Fall 2012 Narratives of Contamination: Representations ofAbstract Narratives of Contamination: Representations of

  17. Carbon contamination of extreme ultraviolet (EUV) mask and its effect on imaging

    E-Print Network [OSTI]

    Fan, Yu-Jen

    2009-01-01T23:59:59.000Z

    induced carbon contamination of extreme ultraviolet optics."potential LWR due to the contamination topography may be anet aI. , "Accelerated contamination testing of EUV masks."

  18. New Challenges in Contamination Control: The Leadership Role of IEST in Shaping Future Research and Practices.

    E-Print Network [OSTI]

    Xu, Tengfang; Eudy, Jane; Berndt, Charles

    2007-01-01T23:59:59.000Z

    New Challenges in Contamination Control: The Leadership RoleS&P) portion of the Contamination Control (CC) program,engineers, and contamination control professionals from all

  19. Factors Affecting Indoor Air Concentrations of Volatile Organic Compounds at a Site of Subsurface Gasoline Contamination

    E-Print Network [OSTI]

    Fischer, M.L.

    2011-01-01T23:59:59.000Z

    OF SUBSURFACE GASOLINE CONTAMINATION Marc L. Fischer, AbraOF SUBSURFACE GASOLINE CONTAMINATION Marc L. Fischer, Abrareporting indoor air contamination (6,7). Estimation of

  20. Analysis of Optics and Mask Contamination in SEMATECH EUV Micro-Exposure Tools

    E-Print Network [OSTI]

    Wuest, Andrea

    2008-01-01T23:59:59.000Z

    of Optics and Mask Contamination in SEMATECH EUV MioroTools IEUVI Optics Contamination/Lifetime TWG Sapporo,of spot inside visible contamination. sputter time (min) c

  1. Removal of contaminated sediments: Equipment and recent field studies

    SciTech Connect (OSTI)

    Herbich, J.B. [Texas A and M Univ., College Station, TX (United States); [Consulting and Research Services, Inc., College Station, TX (United States); [Consulting and Research Services, Inc., Wailuku, HI (United States)

    1995-12-31T23:59:59.000Z

    The problem of contaminated marine sediments has emerged as an environmental issue of national importance. Harbor areas in particular have been found to contain high levels of contaminants in bottom sediments due to wastes from municipal, industrial, and riverine sources. This paper briefly examines the extent and significance of marine sediment contamination in the US, and reviews the state of the art of contaminated sediment cleanup and recent field studies or demonstrations.

  2. Recommendation 195: Mitigation of Contamination in Bear Creek Burial Grounds

    Broader source: Energy.gov [DOE]

    The ORSSAB requests DOE provide possible remedial actions to mitigate releases of contamination from Bear Creek Burial Grounds.

  3. CONTAMINATED SOIL VOLUME ESTIMATE TRACKING METHODOLOGY

    SciTech Connect (OSTI)

    Durham, L.A.; Johnson, R.L.; Rieman, C.; Kenna, T.; Pilon, R.

    2003-02-27T23:59:59.000Z

    The U.S. Army Corps of Engineers (USACE) is conducting a cleanup of radiologically contaminated properties under the Formerly Utilized Sites Remedial Action Program (FUSRAP). The largest cost element for most of the FUSRAP sites is the transportation and disposal of contaminated soil. Project managers and engineers need an estimate of the volume of contaminated soil to determine project costs and schedule. Once excavation activities begin and additional remedial action data are collected, the actual quantity of contaminated soil often deviates from the original estimate, resulting in cost and schedule impacts to the project. The project costs and schedule need to be frequently updated by tracking the actual quantities of excavated soil and contaminated soil remaining during the life of a remedial action project. A soil volume estimate tracking methodology was developed to provide a mechanism for project managers and engineers to create better project controls of costs and schedule. For the FUSRAP Linde site, an estimate of the initial volume of in situ soil above the specified cleanup guidelines was calculated on the basis of discrete soil sample data and other relevant data using indicator geostatistical techniques combined with Bayesian analysis. During the remedial action, updated volume estimates of remaining in situ soils requiring excavation were calculated on a periodic basis. In addition to taking into account the volume of soil that had been excavated, the updated volume estimates incorporated both new gamma walkover surveys and discrete sample data collected as part of the remedial action. A civil survey company provided periodic estimates of actual in situ excavated soil volumes. By using the results from the civil survey of actual in situ volumes excavated and the updated estimate of the remaining volume of contaminated soil requiring excavation, the USACE Buffalo District was able to forecast and update project costs and schedule. The soil volume tracking methodology helped the USACE Buffalo District track soil quantity changes from projected excavation work over time and across space, providing the basis for an explanation of some of the project cost and schedule variances.

  4. Mirror contamination and secondary electron effects during EUV reflectivity analysis

    E-Print Network [OSTI]

    Harilal, S. S.

    Mirror contamination and secondary electron effects during EUV reflectivity analysis M. Catalfanoa, USA; b SEMATECH Inc., Albany, NY 12203, USA ABSTRACT We investigated Ru mirror contamination film at different angles. During the contamination process, the EUV reflectivity of the Ru film

  5. Low energy electron bombardment induced surface contamination of Ru mirrors

    E-Print Network [OSTI]

    Harilal, S. S.

    Low energy electron bombardment induced surface contamination of Ru mirrors A. Al-Ajlonya , A., Albany, NY 12203, USA ABSTRACT The impact of secondary electrons induced contamination of the Ru surface, carbon contamination, Ruthenium capping 1. INTRODUCTION Extreme ultraviolet (EUV) radiation induced

  6. Guidance on Microbial Contamination in Previously Flooded Outdoor Areas

    E-Print Network [OSTI]

    Guidance on Microbial Contamination in Previously Flooded Outdoor Areas Environmental Health Buford Highway NE (F-60) Atlanta, GA 30341 March 2011 #12;2 Guidance on Microbial Contamination in Previously Flooded Outdoor Areas Problem Statement Microbial contamination--both bacterial and viral

  7. Monitoring and Managing Contamination in the San Francisco Estuary

    E-Print Network [OSTI]

    2000Update Monitoring and Managing Contamination in the San Francisco Estuary of the Estuary Pulse status of chemical contamination in the Estuary and efforts by environmental managers to reduce and prevent contamination problems. Most of the monitoring results in the report are a product of the San

  8. Ris-R-1462(EN) Airborne contamination in the indoor

    E-Print Network [OSTI]

    Risø-R-1462(EN) Airborne contamination in the indoor environment and its implications for dose K. Byskov, X.L. Hou, H. Prip, S.K. Olsen, T. Roed Title: Airborne contamination in the indoor environment of contaminant aerosol were examined, and since the previous measurements had indicated that elemental iodine

  9. INFLUENCE OF CONTAMINATION OF ENVIRONMENT AND BREEDING CONDITIONS ON DEVELOPMENT

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    INFLUENCE OF CONTAMINATION OF ENVIRONMENT AND BREEDING CONDITIONS ON DEVELOPMENT OF COCCIDIOSIS, 17700 Surgères, France Résumé INFLUENCE DE LA CONTAMINATION DU MILIEU ET DES CONDITIONS D'ÉLEVAGE SUR LE extent contamination of animals and modifying the susceptibility of those subjected to breeding stress

  10. Kefir grain tolerance to Escherichia coli contamination--industrial advantages

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    NOTE Kefir grain tolerance to Escherichia coli contamination--industrial advantages Piotr the possibility of the re-use of kefir grains grown at 18 °C for 24 h in pasteurized Escherichia coli contaminated milk up to 6.1×102 cfu.mL-1 . The contamination rate was adapted to a realistic situation which may

  11. In-Situ Thermal Remediation of Contaminated Soil1

    E-Print Network [OSTI]

    Lapin, Sergey

    Chapter 1 In-Situ Thermal Remediation of Contaminated Soil1 Written by Huaxiong Huang,2 Serguei Lapin and Rex Westbrook 1.1 Background Recently, a method for removing contaminants from soil (several as follows. Over a period of several weeks, electrical energy is introduced to the contaminated soil using

  12. Toxic Contaminants and Their Effects on Resident Fish

    E-Print Network [OSTI]

    Science-Policy Exchange September 10, 2009 #12;Take-away themes Toxic contaminants are present are source areas for toxic contaminants for multiple fish stocks A better understanding of the effects and restore fish and ecosystem health #12;Take-away themes Toxic contaminants are present in the Columbia

  13. Soil contamination standards for protection of personnel

    SciTech Connect (OSTI)

    Rittmann, P.D.

    1998-04-16T23:59:59.000Z

    The objective of this report is to recommend soil contamination levels that will ensure that radionuclide intakes by unprotected workers are likely to give internal doses below selected dose limits during the working year. The three internal dose limits are 1, 100, and 500 mrem per year. In addition, photon, beta, and alpha instrument readings are estimated for these soil concentration limits. Two exposure pathways are considered: the first is inhalation of resuspended dust and the second is ingestion of trace amounts of soil. In addition, radioactive decay and ingrowth of progeny during the year of exposure is included. External dose from the soil contamination is not included because monitoring and control of external exposures is carried out independently from internal exposures, which are the focus of this report. The methods used are similar to those used by Carbaugh and Bihl (1993) to set bioassay criteria for such workers.

  14. {gamma}-Radiolysis of NaCl Brine in the Presence of UO{sub 2}(s): Effects of Hydrogen and Bromide

    SciTech Connect (OSTI)

    Metz, Volker; Bohnert, Elke; Kelm, Manfred; Schild, Dieter; Kienzler, Bernhard [Institute for Radioactive Waste Disposal (FZK-INE), Forschungszentrum Karlsruhe / Research Center Karlsruhe, Helmholtz-Platz, Eggenstein-Leopoldshafen, D-76344 (Germany); Reinhardt, Juergen; Buchmeiser, Michael R. [Leibniz-Institut fuer Oberflaechenmodifizierung, IOM, Permoserstr. 15, Leipzig, D-04318 (Germany)

    2007-07-01T23:59:59.000Z

    A concentrated NaCl solution was {gamma}-irradiated in autoclaves under a pressure of 25 MPa. A set of experiments were conducted in 6 mol (kg H{sub 2}O){sup -1} NaCl solution in the presence of UO{sub 2}(s) pellets; in a second set of experiments, {gamma}-radiolysis of the NaCl brine was studied without UO{sub 2}(s). Hydrogen, oxygen and chlorate were formed as long-lived radiolysis products. Due to the high external pressure, all radiolysis products remained dissolved. H{sub 2} and O{sub 2} reached steady state concentrations in the range of 5.10{sup -3} to 6.10{sup -2} mol (kg H{sub 2}O){sup -1} corresponding to a partial gas pressure of {approx}2 to {approx}20 MPa. Radiolytic formation of hydrogen and oxygen increased with the concentration of bromide added to solution. Both, in the presence of bromide, resulting in a relatively high radiolytic yield, and in the absence of bromide surfaces of the UO{sub 2}(s) samples were oxidized, and concentration of dissolved uranium reached the solubility limit of the schoepite / NaUO{sub 2}O(OH)(cr) transition. At the end of the experiments, the pellets were covered by a surface layer of a secondary solid phase having a composition close to Na{sub 2}U{sub 2}O{sub 7}. The experimental results demonstrate that bromide counteracts an H{sub 2} inhibition effect on radiolysis gas production, even at a concentration ratio of [H{sub 2}] / [Br{sup -}] > 100. The present observations are related to the competitive reactions of OH radicals with H{sub 2}, Br{sup -} and Cl{sup -}. A similar competition of hydrogen and bromide, controlling the yield of {gamma}-radiolysis products, is expected for solutions of lower Cl{sup -} concentration. (authors)

  15. Fixation of Radiological Contamination; International Collaborative Development

    SciTech Connect (OSTI)

    Rick Demmer

    2013-03-01T23:59:59.000Z

    A cooperative international project was conducted by the Idaho National Laboratory (INL) and the United Kingdom’s National Nuclear Laboratory (NNL) to integrate a capture coating with a high performance atomizing process. The initial results were promising, and lead to further trials. The somewhat longer testing and optimization process has resulted in a product that could be demonstrated in the field to reduce airborne radiological dust and contamination.

  16. Gaseous and particulate contamination in space

    E-Print Network [OSTI]

    Yang, Xiaofang

    1989-01-01T23:59:59.000Z

    understancling of the Space Station environment. Experinrents were performed on Apollo missions 15, 16, and li to learn as nmch as possible about the induced environment. Apollo 17 carriecl an ultraviolet pectrophotorneter that vcas capable of detecting a... number column density (NCD) ol. ' 10 molecules, 'cm of atomic hyclrogen. The NCD is the concentration integrated over a line-of-sight distance. Additional contamination data. were obtained with a mass spectrometer on the Apollo 15 and 16...

  17. Purifying contaminated water. [DOE patent application

    DOE Patents [OSTI]

    Daughton, C.G.

    1981-10-27T23:59:59.000Z

    Process is presented for removing biorefactory compounds from contaminated water (e.g., oil shale retort waste-water) by contacting same with fragmented raw oil shale. Biorefractory removal is enhanced by preactivating the oil shale with at least one member of the group of carboxylic acids, alcohols, aldehydes, ketones, ethers, amines, amides, sulfoxides, mixed ether-esters and nitriles. Further purification is obtained by stripping, followed by biodegradation and removal of the cells.

  18. Bioremediation of uranium contaminated soils and wastes

    SciTech Connect (OSTI)

    Francis, A.J.

    1998-12-31T23:59:59.000Z

    Contamination of soils, water, and sediments by radionuclides and toxic metals from uranium mill tailings, nuclear fuel manufacturing and nuclear weapons production is a major concern. Studies of the mechanisms of biotransformation of uranium and toxic metals under various microbial process conditions has resulted in the development of two treatment processes: (1) stabilization of uranium and toxic metals with reduction in waste volume and (2) removal and recovery of uranium and toxic metals from wastes and contaminated soils. Stabilization of uranium and toxic metals in wastes is accomplished by exploiting the unique metabolic capabilities of the anaerobic bacterium, Clostridium sp. The radionuclides and toxic metals are solubilized by the bacteria directly by enzymatic reductive dissolution, or indirectly due to the production of organic acid metabolites. The radionuclides and toxic metals released into solution are immobilized by enzymatic reductive precipitation, biosorption and redistribution with stable mineral phases in the waste. Non-hazardous bulk components of the waste volume. In the second process uranium and toxic metals are removed from wastes or contaminated soils by extracting with the complexing agent citric acid. The citric-acid extract is subjected to biodegradation to recover the toxic metals, followed by photochemical degradation of the uranium citrate complex which is recalcitrant to biodegradation. The toxic metals and uranium are recovered in separate fractions for recycling or for disposal. The use of combined chemical and microbiological treatment process is more efficient than present methods and should result in considerable savings in clean-up and disposal costs.

  19. Chemical contaminants on DOE lands and selection of contaminant mixtures for subsurface science research

    SciTech Connect (OSTI)

    Riley, R.G.; Zachara, J.M. (Pacific Northwest Lab., Richland, WA (United States))

    1992-04-01T23:59:59.000Z

    This report identifies individual contaminants and contaminant mixtures that have been measured in the ground at 91 waste sites at 18 US Department of Energy (DOE) facilities within the weapons complex. The inventory of chemicals and mixtures was used to identify generic chemical mixtures to be used by DOE's Subsurface Science Program in basic research on the subsurface geochemical and microbiological behavior of mixed contaminants (DOE 1990a and b). The generic mixtures contain specific radionuclides, metals, organic ligands, organic solvents, fuel hydrocarbons, and polychlorinated biphenyls (PCBs) in various binary and ternary combinations. The mixtures are representative of in-ground contaminant associations at DOE facilities that are likely to exhibit complex geochemical behavior as a result of intercontaminant reactions and/or microbiologic activity stimulated by organic substances. Use of the generic mixtures will focus research on important mixed contaminants that are likely to be long-term problems at DOE sites and that will require cleanup or remediation. The report provides information on the frequency of associations among different chemicals and compound classes at DOE waste sites that require remediation.

  20. Residual radioactive contamination from decommissioning: Technical basis for translating contamination levels to annual dose

    SciTech Connect (OSTI)

    Kennedy, W.E. Jr.; Peloquin, R.A. (Pacific Northwest Lab., Richland, WA (USA))

    1990-01-01T23:59:59.000Z

    This document describes the generic modeling of the total effective dose equivalent (TEDE) to an individual in a population from a unit concentration of residual radioactive contamination. Radioactive contamination inside buildings and soil contamination are considered. Unit concentration TEDE factors by radionuclide, exposure pathway, and exposure scenario are calculated. Reference radiation exposure scenarios are used to derive unit concentration TEDE factors for about 200 individual radionuclides and parent-daughter mixtures. For buildings, these unit concentration factors list the annual TEDE for volume and surface contamination situations. For soil, annual TEDE factors are presented for unit concentrations of radionuclides in soil during residential use of contaminated land and the TEDE per unit total inventory for potential use of drinking water from a ground-water source. Because of the generic treatment of potentially complex ground-water systems, the annual TEDE factors for drinking water for a given inventory may only indicate when additional site data or modeling sophistication are warranted. Descriptions are provided of the models, exposure pathways, exposure scenarios, parameter values, and assumptions used. An analysis of the potential annual TEDE resulting from reference mixtures of residual radionuclides is provided to demonstrate application of the TEDE factors. 62 refs., 5 figs., 66 tabs.

  1. Analysis of Optics and Mask Contamination in SEMATECH EUV Micro-Exposure Tools

    E-Print Network [OSTI]

    Wuest, Andrea

    2008-01-01T23:59:59.000Z

    Analysis of Optics and Mask Contamination in SEMATECHMioro^Exposure Tools IEUVI Optics Contamination/Lifetime TWG

  2. Field-based detection and monitoring of uranium in contaminated groundwater using two immunosensors

    E-Print Network [OSTI]

    Melton, S.J.

    2010-01-01T23:59:59.000Z

    D. R. , Sustained removal of uranium from contaminated9. 18. Brina, R. , Uranium removal from contaminated water

  3. BIOREMEDIATION OF URANIUM CONTAMINATED SOILS AND WASTES.

    SciTech Connect (OSTI)

    FRANCIS,A.J.

    1998-09-17T23:59:59.000Z

    Contamination of soils, water, and sediments by radionuclides and toxic metals from uranium mill tailings, nuclear fuel manufacturing and nuclear weapons production is a major concern. Studies of the mechanisms of biotransformation of uranium and toxic metals under various microbial process conditions has resulted in the development of two treatment processes: (i) stabilization of uranium and toxic metals with reduction in waste volume and (ii) removal and recovery of uranium and toxic metals from wastes and contaminated soils. Stabilization of uranium and toxic metals in wastes is accomplished by exploiting the unique metabolic capabilities of the anaerobic bacterium, Clostridium sp. The radionuclides and toxic metals are solubilized by the bacteria directly by enzymatic reductive dissolution, or indirectly due to the production of organic acid metabolites. The radionuclides and toxic metals released into solution are immobilized by enzymatic reductive precipitation, biosorption and redistribution with stable mineral phases in the waste. Non-hazardous bulk components of the waste such as Ca, Fe, K, Mg and Na released into solution are removed, thus reducing the waste volume. In the second process uranium and toxic metals are removed from wastes or contaminated soils by extracting with the complexing agent citric acid. The citric-acid extract is subjected to biodegradation to recover the toxic metals, followed by photochemical degradation of the uranium citrate complex which is recalcitrant to biodegradation. The toxic metals and uranium are recovered in separate fractions for recycling or for disposal. The use of combined chemical and microbiological treatment process is more efficient than present methods and should result in considerable savings in clean-up and disposal costs.

  4. Dredging, remediation, and containment of contaminated sediments

    SciTech Connect (OSTI)

    Demars, K.R.; Richardson, G.N.; Yong, R.N.; Chaney, R.C. [eds.

    1995-12-31T23:59:59.000Z

    This conference was held June 23--24, 1994 in Montreal, Canada. One purpose of this conference was to provide a multidisciplinary forum for exchange of state-of-the-art information on identifying tests, methods, procedures, and materials, used in support of dredging, treatment, and containment of contaminated sediments that are in need of standardization. Another objective was to provide a forum for discussion of past dredging practices and future directions, including the effects of sediment properties and behavior, equipment requirements, and the impact of regulations. Individual papers have been processed separately for inclusion in the appropriate data bases.

  5. Excited state contamination in nucleon structure calculations

    E-Print Network [OSTI]

    Jeremy Green; Stefan Krieg; John Negele; Andrew Pochinsky; Sergey Syritsyn

    2011-11-28T23:59:59.000Z

    Among the sources of systematic error in nucleon structure calculations is contamination from unwanted excited states. In order to measure this systematic error, we vary the operator insertion time and source-sink separation independently. We compute observables for three source-sink separations between 0.93 fm and 1.39 fm using clover-improved Wilson fermions and pion masses as low as 150 MeV. We explore the use of a two-state model fit to subtract off the contribution from excited states.

  6. Portable spotter for fluorescent contaminants on surfaces

    DOE Patents [OSTI]

    Schuresko, Daniel D. (Oak Ridge, TN)

    1980-01-01T23:59:59.000Z

    A portable fluorescence-based spotter for polynuclear aromatic hydrocarbon contamination on personnel and work area surfaces under ambient lighting conditions is provided. This instrument employs beam modulation and phase sensitive detection for discriminating between fluorescence from organic materials from reflected background light and inorganic fluorescent material. The device uses excitation and emission filters to provide differentiation between classes of aromatic organic compounds. Certain inorganic fluorescent materials, including heavy metal compounds, may also be distinguished from the organic compounds, despite both having similar optical properties.

  7. SUMMARY REPORT FOR ZINC 65 CONTAMINATION CONTROL

    SciTech Connect (OSTI)

    Korinko, P.

    2011-07-14T23:59:59.000Z

    Radioactive zinc, {sup 65}Zn, was detected after extraction of 215 TPBARs in from TVA reactor fuel cycle 6. A team consisting of Tritium Engineering, Tritium Operations, Tritium Radiation Control, and Savannah River National Laboratory personnel evaluated the risk and response and developed short, medium and long term goals for contamination control. One of the goals was incorporated into site Performance Based Incentive CO 3.4, to optimize the filter geometry and operating conditions for the Tritium Extraction Facility. This goal included a scoping study to determine if the contamination could be contained within the high radiation environment of the furnace module as well. In order to optimize the filters studies were conducted to independently evaluate the effect of pore size on pumping efficiency and zinc trapping efficiency (1). A study was also conducted to evaluate the effect of temperature on the trapping efficiency and adhesion (2). In addition, the potential for chemically trapping zinc in the lithium trap was evaluated using a thermodynamic study (3) followed by preliminary experimental testing (4). Based on the work that was completed it is determined that a 20 {mu}m filter heated to between 120 and 200 C will act as an effective physical trap for zinc vapors. It may be possible to chemically react zinc with copper or cobalt to form zinc intermetallic compounds or alloys but additional work under more prototypic conditions are required.

  8. Mechanisms of contaminant migration from grouted waste

    SciTech Connect (OSTI)

    Magnuson, S.O. [EG and G Idaho, Inc., Idaho Falls, ID (United States); Yu, A.D. [Westinghouse Savannah River Co., Aiken, SC (United States)

    1992-12-31T23:59:59.000Z

    Low-level radioactive decontaminated salt solution is generated at the Savannah River Site (SRS) from the In-Tank Precipitation process. The solution is mixed with cement, slag, and fly ash, to form a grout, termed ``Saltstone``, that will be disposed in concrete vaults at the Saltstone Disposal Facility (SDF) [1]. Of the contaminants in the Saltstone, the greatest concern to SRS is the potential release of nitrate to the groundwater because of the high initial nitrate concentration (0.25 g/cm{sup 3}) in the Saltstone and the low Safe Drinking Water Act (SDWA) maximum contaminant level (MCL) of 44 mg/L. The SDF is designed to allow a slow, controlled release over thousands of years. This paper addresses a modeling study of nitrate migration from intact non-degraded concrete vaults in the unsaturated zone for the Radiological Performance Assessment (PA) of the SRS Saltstone Disposal Facility [3]. The PA addresses the performance requirements mandated by DOE Order 5820.2A [4].

  9. Contamination surveys for release of material

    SciTech Connect (OSTI)

    Durham, J.S.; Johnson, M.L. [Pacific Northwest Lab., Richland, WA (United States); Gardner, D.L. [Westinghouse Hanford Co., Richland, WA (United States)

    1994-05-01T23:59:59.000Z

    This report describes, and presents the technical basis for, a methodology for performing instrument surveys to release material from radiological control, including release to controlled areas and release from radiological control. The methodology is based on a fast scan survey, a large-area wipe survey, and a series of statistical, fixed measurements. The methodology meets the requirements of the US Department of Energy Radiological Control Manual (RadCon Manual) (DOE 1994) and DOE Order 5400.5 (DOE 1990) for release of material in less time than is required by a conventional scan survey. Implementation of the proposed methodology with a confidence interval of 67% will meet the material release requirements. The material evaluation process will allow material that has not been exposed to contamination to be released from radiological control without a survey. For potential radioactive contaminants that are not reserved in DOE Order 5400.5, the methodology will allow material to be released from radiological control. For other radionuclides, with the exception of some difficult-to-detect radionuclides, material may be released for controlled use. Compared with current techniques, the proposed methodology will reduce the amount of time required to perform surveys.

  10. In-situ remediation system and method for contaminated groundwater

    DOE Patents [OSTI]

    Corey, J.C.; Looney, B.B.; Kaback, D.S.

    1989-05-23T23:59:59.000Z

    A system for removing volatile contaminants from a subsurface plume of contamination comprising two sets of wells, a well for injecting a fluid into a saturated zone on one side of the plume and an extracting well for collecting the fluid together with volatilized contaminants from the plume on the other side of the plume. The fluid enables the volatile contaminants to be volatilized and carried therewith through the ground to the extracting well. Injecting and extracting wells are preferably horizontal wells positioned below the plume in the saturated zone and above the plume in the vadose zone, respectively. The fluid may be air or other gas or a gas and liquid mixture depending on the type of contaminant to be removed and may be preheated to facilitate volatilization. Treatment of the volatilized contamination may be by filtration, incineration, atmospheric dispersion or the like. 3 figs.

  11. In-situ remediation system and method for contaminated groundwater

    DOE Patents [OSTI]

    Corey, John C. (Aiken, SC); Looney, Brian B. (Aiken, SC); Kaback, Dawn S. (Aiken, SC)

    1989-01-01T23:59:59.000Z

    A system for removing volatile contaminants from a subsurface plume of contamination comprising two sets of wells, a well for injecting a fluid into a saturated zone on one side of the plume and an extracting well for collecting the fluid together with volatilized contaminants from the plume on the other side of the plume. The fluid enables the volatile contaminants to be volatilized and carried therewith through the ground to the extracting well. Injecting and extracting wells are preferably horizontal wells positioned below the plume in the saturated zone and above the plume in the vadose zone, respectively. The fluid may be air or other gas or a gas and liquid mixture depending on the type of contaminant to be removed and may be preheated to facilitate volatilization. Treatment of the volatilized contamination may be by filtration, incineration, atmospheric dispersion or the like.

  12. Total effective dose equivalent associated with fixed uranium surface contamination

    SciTech Connect (OSTI)

    Bogard, J.S.; Hamm, R.N.; Ashley, J.C.; Turner, J.E.; England, C.A.; Swenson, D.E.; Brown, K.S.

    1997-04-01T23:59:59.000Z

    This report provides the technical basis for establishing a uranium fixed-contamination action level, a fixed uranium surface contamination level exceeding the total radioactivity values of Appendix D of Title 10, Code of Federal Regulations, part 835 (10CFR835), but below which the monitoring, posting, and control requirements for Radiological Areas are not required for the area of the contamination. An area of fixed uranium contamination between 1,000 dpm/100 cm{sup 2} and that level corresponding to an annual total effective dose equivalent (TEDE) of 100 mrem requires only routine monitoring, posting to alert personnel of the contamination, and administrative control. The more extensive requirements for monitoring, posting, and control designated by 10CFR835 for Radiological Areas do not have to be applied for these intermediate fixed-contamination levels.

  13. System for the removal of contaminant soil-gas vapors

    DOE Patents [OSTI]

    Weidner, Jerry R. (Iona, ID); Downs, Wayne C. (Sugar City, ID); Kaser, Timothy G. (Ammon, ID); Hall, H. James (Idaho Falls, ID)

    1997-01-01T23:59:59.000Z

    A system extracts contaminated vapors from soil or other subsurface regions by using changes in barometric pressure to operate sensitive check valves that control air entry and removal from wells in the ground. The system creates an efficient subterranean flow of air through a contaminated soil plume and causes final extraction of the contaminants from the soil to ambient air above ground without any external energy sources.

  14. Detection of contamination of municipal water distribution systems

    DOE Patents [OSTI]

    Cooper, John F. (Oakland, CA)

    2012-01-17T23:59:59.000Z

    A system for the detection of contaminates of a fluid in a conduit. The conduit is part of a fluid distribution system. A chemical or biological sensor array is connected to the conduit. The sensor array produces an acoustic signal burst in the fluid upon detection of contaminates in the fluid. A supervisory control system connected to the fluid and operatively connected to the fluid distribution system signals the fluid distribution system upon detection of contaminates in the fluid.

  15. System for the removal of contaminant soil-gas vapors

    DOE Patents [OSTI]

    Weidner, J.R.; Downs, W.C.; Kaser, T.G.; Hall, H.J.

    1997-12-16T23:59:59.000Z

    A system extracts contaminated vapors from soil or other subsurface regions by using changes in barometric pressure to operate sensitive check valves that control air entry and removal from wells in the ground. The system creates an efficient subterranean flow of air through a contaminated soil plume and causes final extraction of the contaminants from the soil to ambient air above ground without any external energy sources. 4 figs.

  16. Air Resources: Prevention and Control of Air Contamination and...

    Broader source: Energy.gov (indexed) [DOE]

    limits and permitting and operational requirements for facilities that may contribute to air emissions. General air quality standards and standards for specific contaminants are...

  17. Method and apparatus for destroying organic contaminants in aqueous liquids

    DOE Patents [OSTI]

    Donaldson, Terrence L. (Lenior City, TN); Wilson, James H. (Oak Ridge, TN)

    1993-01-01T23:59:59.000Z

    A method and apparatus for destroying organic contaminants, such as trichloroethylene, in aqueous liquids, such as groundwater, utilizing steam stripping integrated with biodegradation. The contaminated aqueous liquid is fed into a steam stripper causing the volatilization of essentially all of the organic contaminants and a portion of the aqueous liquid. The majority of the aqueous liquid is discharged from the steam stripper. The volatilized vapors are then condensed to the liquid phase and introduced into a bioreactor. The bioreactor contains methanotrophic microorganisms which convert the organic contaminants into mainly carbon dioxide. The effluent from the bioreactor is then recycled back to the steam stripper for further processing.

  18. Method and apparatus for destroying organic contaminants in aqueous liquids

    DOE Patents [OSTI]

    Donaldson, T.L.; Wilson, J.H.

    1993-09-21T23:59:59.000Z

    A method and apparatus for destroying organic contaminants, such as trichloroethylene, in aqueous liquids, such as groundwater, utilizing steam stripping integrated with biodegradation. The contaminated aqueous liquid is fed into a steam stripper causing the volatilization of essentially all of the organic contaminants and a portion of the aqueous liquid. The majority of the aqueous liquid is discharged from the steam stripper. The volatilized vapors are then condensed to the liquid phase and introduced into a bioreactor. The bioreactor contains methanotrophic microorganisms which convert the organic contaminants into mainly carbon dioxide. The effluent from the bioreactor is then recycled back to the steam stripper for further processing. 2 figures.

  19. adriatic seafood contamination: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of steel faying unknown authors 2007-01-01 95 Factors influencing biological treatment of MTBE contaminated ground water University of California eScholarship Repository Summary:...

  20. Remediation of Mercury and Industrial Contaminants Applied Field...

    Energy Savers [EERE]

    established to protect water resources by addressing the challenge of preventing contamination. The initiative at Oak Ridge is a collaborative effort that leverages DOE...

  1. 01-07-1999 - Contamination Spread Outside of Radiation Control...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    9 - Contamination Spread Outside of Radiation Control Areas by Fruit Flies Document Number: NA Effective Date: 011999 File (public): 01-07-1999red...

  2. Predicting Nickel Precipitate Formation in Contaminated Soils. (3717)

    E-Print Network [OSTI]

    Sparks, Donald L.

    Predicting Nickel Precipitate Formation in Contaminated Soils. (3717) Authors: E. Peltier* - Univ controlling precipitate formation is still needed. In this study, we have combined experimental data on nickel

  3. RESRAD Computer Code- Evaluation of Radioactively Contaminated Sites

    Broader source: Energy.gov [DOE]

    The evaluation of sites with radioactive contamination was a problem until the RESidual RADioactivity (RESRAD) Computer Code was first released in 1989.

  4. assessing aquifer contamination: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... In Situ Oil; Rock Springs 54 ASSESSING THE HUMAN HEALTH RISKS AND ENVIRONMENTAL IMPACTS OF CCA-CONTAMINATED MULCH. Open Access Theses and Dissertations Summary: ??To...

  5. actinide contaminants potential: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Asit 150 There are many locations throughout the world where sub-surface contamination impacts the natural environment, with Geosciences Websites Summary: There are many locations...

  6. Controls on arsenic mobility in contaminated wetland and riverbed streams

    E-Print Network [OSTI]

    Keon, Nicole E. (Nicole Elise), 1974-

    2002-01-01T23:59:59.000Z

    Arsenic mobility and transport in the environment are strongly influenced by associations with solid phases. This dissertation investigates the mechanisms affecting arsenic retention in contaminated wetland and riverbed ...

  7. Comments on cathode contaminants and the LBNL test stand

    E-Print Network [OSTI]

    Bieniosek, F.; Baca, D.; Greenway, W.; Leitner, M.; Kwan, J.W.

    2006-01-01T23:59:59.000Z

    LBNL-61978 Comments oncathode contaminants and the LBNL test stand F. Bieniosek,the process of operating the LBNL DARHT cathode test stand.

  8. Feed gas contaminant removal in ion transport membrane systems

    DOE Patents [OSTI]

    Underwood, Richard Paul (Allentown, PA); Makitka, III, Alexander (Hatfield, PA); Carolan, Michael Francis (Allentown, PA)

    2012-04-03T23:59:59.000Z

    An oxygen ion transport membrane process wherein a heated oxygen-containing gas having one or more contaminants is contacted with a reactive solid material to remove the one or more contaminants. The reactive solid material is provided as a deposit on a support. The one or more contaminant compounds in the heated oxygen-containing gas react with the reactive solid material. The contaminant-depleted oxygen-containing gas is contacted with a membrane, and oxygen is transported through the membrane to provide transported oxygen.

  9. area contamination site: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and Radium-226 are the predominant radioactive contaminents on Formerly Utilized Sites Remedial Action Plan (FUSRAP) sites. ** The half-life of a radioactive element is the time...

  10. alpha contaminated wastes: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    identify the primary mode (inhalationingestion or surface contact) of contamination to small mammals. Three composite samples of at least five animals per sample were collected at...

  11. The Simulation of Nuclear Contaminant Transport in Fractally ...

    E-Print Network [OSTI]

    The presentation will begin with a derivation of a model of nuclear contaminant transport in naturally-fractured porous media. Then, a Locally-Conservative ...

  12. Maternal Contributions to the Development of Contamination Sensitivity

    E-Print Network [OSTI]

    Beebe, Heidi

    2012-01-01T23:59:59.000Z

    of contamination and decontamination. Mothers made very fewcrawling C on sandwich Decontamination Water still and cleanThe story involving decontamination (boiling water during a

  13. aureus contaminated meat: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    spurred the implementation of numerous bans (more) Mahmood, Maryam 2012-01-01 367 Controls on arsenic mobility in contaminated wetland and riverbed streams MIT - DSpace...

  14. Investigation of the November 8, 2011, Plutonium Contamination...

    Energy Savers [EERE]

    November 8, 2011, Plutonium Contamination in the Zero Power Physics Reactor Facility, at the Idaho National Laboratory Investigation of the November 8, 2011, Plutonium...

  15. Mercury-Contaminated Hydraulic Mining Debris in San Francisco Bay

    E-Print Network [OSTI]

    Bouse, Robin M; Fuller, Christopher C; Luoma, Sam; Hornberger, Michelle I; Jaffe, Bruce E; Smith, Richard E

    2010-01-01T23:59:59.000Z

    Contaminated Hydraulic Mining Debris in San Francisco BayAbstract The hydraulic gold-mining process used during thecreated by hydraulic gold mining in the Sierra Nevada,

  16. alluvial groundwater contamination: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    aquifer of Israel, such as marine-derived saline groundwater Kasher, Roni 11 Contaminant Transport in Groundwater for Environmental Performance Assessment University of California...

  17. alpha contaminated soils: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Silverman; Angela M. Porretta 1988-01-01 6 BIOCYCLE JUNE 2002 41 ETAL contaminated soils Environmental Management and Restoration Websites Summary: pro- ject in Jasper County,...

  18. arsenic contaminated aquifer: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    areas. A number of studies have looked at the variation in nitrate Toran, Laura 13 Assessing Plants for Phytoremediation of Arsenic-Contaminated Soils Environmental Management...

  19. Author's personal copy Physica D 239 (2010) 18551866

    E-Print Network [OSTI]

    McLaughlin, Richard M.

    2010-01-01T23:59:59.000Z

    through the introduction of brine solutions. The success of such techniques relies on the accurate prediction of the location of the brine during the remediation stages as well as eventual brine recovery, such as those occurring during remediation of contaminated soils using brine solutions and during the geological

  20. Method of removing arsenic and other anionic contaminants from contaminated water using enhanced coagulation

    DOE Patents [OSTI]

    Teter, David M.; Brady, Patrick V.; Krumhansl, James L.; Khandaker, Nadim R.

    2006-11-21T23:59:59.000Z

    An improved water decontamination process comprising contacting water containing anionic contaminants with an enhanced coagulant to form an enhanced floc, which more efficiently binds anionic species (e.g., arsenate, arsenite, chromate, fluoride, selenate, and borate, and combinations thereof) predominantly through the formation of surface complexes. The enhanced coagulant comprises a trivalent metal cation coagulant (e.g., ferric chloride or aluminum sulfate) mixed with a divalent metal cation modifier (e.g., copper sulfate or zinc sulfate).

  1. Remediation of arsenic-contaminated soils and groundwaters

    DOE Patents [OSTI]

    Peters, R.W.; Frank, J.R.; Feng, X.

    1998-06-23T23:59:59.000Z

    An in situ method is described for extraction of arsenic contaminants from a soil medium and remediation of the medium including contacting the medium with an extractant solution, directing the solution within and through the medium, and collecting the solution and contaminants. The method can also be used for arsenate and/or arsenite removal. 8 figs.

  2. The fate of toxic pollutants in contaminated sediments

    SciTech Connect (OSTI)

    Yong, R.N. [McGill Univ., Montreal, Quebec (Canada)

    1995-12-31T23:59:59.000Z

    Sediments function as sinks for various kinds of contaminants (pollutants and nonpollutants) discharged into the receiving waters. Toxic pollutants in the sediments constitute a significant concern inasmuch as they can infect the waters above the sediment if they are released from the sediments. Hence the persistence and fate of these toxic pollutants need to be determined. At least tow sets of interests can be identified in the contamination of sediments as a whole: (1) assessment of the storage capacity (for contaminants) of the sediments, and the potential for mobilization or release of contaminants into the aqueous environment, particularly into the overlying water, and (2) development of a strategy for removal of the contaminants from the sediments that would be most appropriate (i.e., compatible with the manner in which the contaminants are retained in the sediment) and cost-effective. Both sets of interests require a knowledge of the distribution of the contaminants, i.e., characterization of the contaminants contained in the sediment, and the manner in which these are held within the sediment, i.e., bonded to the various sediment solid fractions (constituents). 56 refs., 11 figs., 3 tabs.

  3. IN SITU REMEDIATION OF CONTAMINATED SEDIMENTS - ACTIVE CAPPING TECHNOLOGY

    SciTech Connect (OSTI)

    Knox, A.; Roberts, J.; Paller, M.; Reible, D.

    2010-09-02T23:59:59.000Z

    Active capping is a relatively new approach for treating contaminated sediments. It involves applying chemically reactive amendments to the sediment surface. The main role of active caps is to stabilize contaminants in contaminated sediments, lower the bioavailable pool of contaminants, and reduce the release of contaminants to the water column. Metals are common contaminants in many marine and fresh water environments as a result of industrial and military activities. The mobile, soluble forms of metals are generally considered toxic. Induced chemical precipitation of these metals can shift toxic metals from the aqueous phase to a solid, precipitated phase which is often less bioavailable. This approach can be achieved through application of sequestering agents such as rock phosphates, organoclays, zeolites, clay minerals, and biopolymers (e.g., chitosan) in active capping technology. Active capping holds great potential for a more permanent solution that avoids residual risks resulting from contaminant migration through the cap or breaching of the cap. In addition to identifying superior active capping agents, research is needed to optimize application techniques, application rates, and amendment combinations that maximize sequestration of contaminants. A selected set of active capping treatment technologies has been demonstrated at a few sites, including a field demonstration at the Savannah River Site, Aiken, SC. This demonstration has provided useful information on the effects of sequestering agents on metal immobilization, bioavailability, toxicity, and resistance to mechanical disturbance.

  4. SIMULATION OF REMEDIATION ALTERNATIVES FOR A 137Cs CONTAMINATED SOIL.

    E-Print Network [OSTI]

    Politècnica de Catalunya, Universitat

    SIMULATION OF REMEDIATION ALTERNATIVES FOR A 137Cs CONTAMINATED SOIL. THE NUMERICAL MODELING analyze remediation alternatives for a soil contaminated with 137Cs, which sorbs strongly onto the clayey. The mobile portion of the soil (macropores) retains little water and cesium. The natural attenuation option

  5. Boron isotope application for tracing sources of contamination in groundwater.

    E-Print Network [OSTI]

    Kasher, Roni

    Boron isotope application for tracing sources of contamination in groundwater. Abstract: Boron isotope composition and concentration of sewage effluent and pristine and contaminated groundwater from sodium perborate as a bleaching agent in detergents, leads to an enrichment of boron in wastewaters

  6. Modeling Contaminant Exposure in a Single-Family House

    E-Print Network [OSTI]

    Chen, Qingyan "Yan"

    occupational exposure to household contaminants in a single-family house under different ventilation, heating the performance of two heating systems, two cooling systems and three ventilation systems in summer and winter, Contaminant exposure, Stratification, Ventilation system performance Abstract This study simulated

  7. Microbial Janitors: Enabling natural microbes to clean up uranium contamination

    E-Print Network [OSTI]

    of Energy's Environmental Remediation Sciences Program. Q: How can uranium be removed or neutralized so in the contaminated subsurface and engineering the subsurface environment to stimulate nitrate removal and uraniumMicrobial Janitors: Enabling natural microbes to clean up uranium contamination Oak Ridge

  8. Contaminant Concentrations in Fish SacramentoSan Joaquin Delta

    E-Print Network [OSTI]

    of Fish and Game) arranged for age determination of largemouth bass. Henry Lee (U.S. EPA) reviewed a draftContaminant Concentrations in Fish from the Sacramento­San Joaquin Delta and Lower San Joaquin ......................................................................................... 45 Contaminant Concentrations in Fish from the Sacramento­San Joaquin Delta and Lower San Joaquin

  9. SURVEY OF CONTAMINANTS IN FRASER RIVER SUSPENDED SEDIMENT AND WATER

    E-Print Network [OSTI]

    weight PAHs, chlorophenols, chloroguaiacols, and pesticides were primarily found in the water phase. #12SURVEY OF CONTAMINANTS IN FRASER RIVER SUSPENDED SEDIMENT AND WATER UPSTREAM AND DOWNSTREAM and inorganic contaminants were measured in time-integrated samples of suspended sediment and water

  10. Remediation of arsenic-contaminated soils and groundwaters

    DOE Patents [OSTI]

    Peters, Robert W. (Naperville, IL); Frank, James R. (Glen Ellyn, IL); Feng, Xiandong (West Richland, WA)

    1998-01-01T23:59:59.000Z

    An in situ method for extraction of arsenic contaminants from a soil medium and remediation of the medium including contacting the medium with an extractant solution, directing the solution within and through the medium, and collecting the solution and contaminants. The method can also be used for arsenate and/or arsenite removal.

  11. Method for treatment of soils contaminated with organic pollutants

    DOE Patents [OSTI]

    Wickramanayake, Godage B. (Cranbury, NJ)

    1993-01-01T23:59:59.000Z

    A method for treating soil contaminated by organic compounds wherein an ozone containing gas is treated with acid to increase the stability of the ozone in the soil environment and the treated ozone applied to the contaminated soil to decompose the organic compounds. The soil may be treated in situ or may be removed for treatment and refilled.

  12. ORIGINAL PAPER Bioremediation of oily sludge-contaminated soil

    E-Print Network [OSTI]

    Ma, Lena

    ORIGINAL PAPER Bioremediation of oily sludge-contaminated soil by stimulating indigenous microbes contaminants. On the other hand, biological treatment (bioremediation) appears to be among the most promising in the complete destruction of hazardous compounds into innocuous products (Bal- ba et al. 1998). For this reason

  13. Decontamination of Mutually Contaminated Models Gilles Blanchard Clayton Scott

    E-Print Network [OSTI]

    Kaski, Samuel

    Decontamination of Mutually Contaminated Models Gilles Blanchard Clayton Scott Universit¨at Potsdam distributions are nonseparable and po- tentially quite complex. We develop a pro- cedure for decontamination technique for "decontamination" of the contaminated models. In particular, we show that under the sufficient

  14. Degradation of organic and inorganic contaminants by zero valent iron

    E-Print Network [OSTI]

    Malla, Deepak Babu

    1997-01-01T23:59:59.000Z

    and in combination. All three target contaminants were effectively reduced by both iron (Feo) and palladized iron (Pd/Fe'). However, the rate of reduction by Pd/Fe' was found to be much faster than that by Feo. The reduction of all the contaminants in mixed waste...

  15. Capture zone design for a contaminated shallow unconfined aquifer

    E-Print Network [OSTI]

    Cann, Eric Roy

    1997-01-01T23:59:59.000Z

    from the early 1950's to 1987. The extent of the ground water contamination has impacted City of Austin properties, private residential areas, and is migrating towards the Colorado River to the South. A capture zone is proposed to stop the contaminants...

  16. Low contaminant formic acid fuel for direct liquid fuel cell

    DOE Patents [OSTI]

    Masel, Richard I. (Champaign, IL); Zhu, Yimin (Urbana, IL); Kahn, Zakia (Palatine, IL); Man, Malcolm (Vancouver, CA)

    2009-11-17T23:59:59.000Z

    A low contaminant formic acid fuel is especially suited toward use in a direct organic liquid fuel cell. A fuel of the invention provides high power output that is maintained for a substantial time and the fuel is substantially non-flammable. Specific contaminants and contaminant levels have been identified as being deleterious to the performance of a formic acid fuel in a fuel cell, and embodiments of the invention provide low contaminant fuels that have improved performance compared to known commercial bulk grade and commercial purified grade formic acid fuels. Preferred embodiment fuels (and fuel cells containing such fuels) including low levels of a combination of key contaminants, including acetic acid, methyl formate, and methanol.

  17. In vitro gastrointestinal mimetic protocol for measuring bioavailable contaminants

    DOE Patents [OSTI]

    Holman, Hoi-Ying N. (Berkeley, CA)

    2000-01-01T23:59:59.000Z

    The present invention relates to measurements of contaminants in the soil and other organic or environmental materials, using a biologically relevant chemical analysis that will measure the amount of contaminants in a given sample that may be expected to be absorbed by a human being ingesting the contaminated soil. According to the present invention, environmental samples to be tested are added to a pre-prepared physiological composition of bile salts and lipids. They are thoroughly mixed and then the resulting mixture is separated e.g. by centrifugation. The supernatant is then analyzed for the presence of contaminants and these concentrations are compared to the level of contaminants in the untreated samples. It is important that the bile salts and lipids be thoroughly pre-mixed to form micelles.

  18. Method for detecting organic contaminants in water supplies

    DOE Patents [OSTI]

    Dooley, K.J.; Barrie, S.L.; Buttner, W.J.

    1999-08-24T23:59:59.000Z

    A system is described for detecting organic contaminants in water supplies. A sampling unit is employed which includes a housing having at least one opening therein and a tubular member positioned within the housing having a central passageway surrounded by a side wall. The side wall is made of a composition designed to absorb the contaminants. In use, the sampling unit is immersed in a water supply. The water supply contacts the tubular member through the opening in the housing, with any contaminants being absorbed into the side wall of the tubular member. A carrier gas is then passed through the central passageway of the tubular member. The contaminants will diffuse out of the side wall and into the central passageway where they will subsequently combine with the carrier gas, thereby yielding a gaseous product. The gaseous product is then analyzed to determine the amount and type of contaminants therein. 5 figs.

  19. Method for detecting organic contaminants in water supplies

    DOE Patents [OSTI]

    Dooley, Kirk J. (Shelley, ID); Barrie, Scott L. (Idaho Falls, ID); Buttner, William J. (White Bear Lake, MN)

    1999-01-01T23:59:59.000Z

    A system for detecting organic contaminants in water supplies. A sampling unit is employed which includes a housing having at least one opening therein and a tubular member positioned within the housing having a central passageway surrounded by a side wall. The side wall is made of a composition designed to absorb the contaminants. In use, the sampling unit is immersed in a water supply. The water supply contacts the tubular member through the opening in the housing, with any contaminants being absorbed into the side wall of the tubular member. A carrier gas is then passed through the central passageway of the tubular member. The contaminants will diffuse out of the side wall and into the central passageway where they will subsequently combine with the carrier gas, thereby yielding a gaseous product. The gaseous product is then analyzed to determine the amount and type of contaminants therein.

  20. Methods for removing contaminant matter from a porous material

    DOE Patents [OSTI]

    Fox, Robert V. (Idaho Falls, ID) [Idaho Falls, ID; Avci, Recep (Bozeman, MT) [Bozeman, MT; Groenewold, Gary S. (Idaho Falls, ID) [Idaho Falls, ID

    2010-11-16T23:59:59.000Z

    Methods of removing contaminant matter from porous materials include applying a polymer material to a contaminated surface, irradiating the contaminated surface to cause redistribution of contaminant matter, and removing at least a portion of the polymer material from the surface. Systems for decontaminating a contaminated structure comprising porous material include a radiation device configured to emit electromagnetic radiation toward a surface of a structure, and at least one spray device configured to apply a capture material onto the surface of the structure. Polymer materials that can be used in such methods and systems include polyphosphazine-based polymer materials having polyphosphazine backbone segments and side chain groups that include selected functional groups. The selected functional groups may include iminos, oximes, carboxylates, sulfonates, .beta.-diketones, phosphine sulfides, phosphates, phosphites, phosphonates, phosphinates, phosphine oxides, monothio phosphinic acids, and dithio phosphinic acids.

  1. Please cite this article in press as: Birkholzer, J.T., et al., Brine flow up a well caused by pressure perturbation from geologic carbon sequestration: Static and dynamic evaluations. Int. J. Greenhouse Gas Control (2011), doi:10.1016/j.ijggc.2011.01.003

    E-Print Network [OSTI]

    Zhou, Quanlin

    2011-01-01T23:59:59.000Z

    by pressure perturbation from geologic carbon sequestration: Static and dynamic evaluations. Int. J.elsevier.com/locate/ijggc Brine flow up a well caused by pressure perturbation from geologic carbon sequestration: Static carbon sequestration (GCS) has drawn increasing con- sideration as a promising method to mitigate

  2. Monitoring and Modeling Non-Point Source Contributions of Host-Specific Fecal Contamination in San Pablo Bay

    E-Print Network [OSTI]

    Wuertz, Stefan; Bombardelli, Fabian A; Sirikanchana, Kwanrawee; Wang, Dan

    2009-01-01T23:59:59.000Z

    Host-Specific Fecal Contamination in San Pablo Bay Principlelivestock sources of fecal contamination in Kenya with host-Huang. Abstract Fecal contamination from non-point sources

  3. Motivation Atmospheric Contamination Rejuvenation of a Cesium-Based Dispenser Photocathode

    E-Print Network [OSTI]

    Anlage, Steven

    Motivation Atmospheric Contamination Results Rejuvenation of a Cesium-Based Dispenser Photocathode in Response to Atmospheric Contamination Alexandra Day, Dr. Eric Montgomery, Dr. Kevin Jensen, Blake Riddick, Saara Khan, Scott Eustice Quantum Efficiency Key Conclusions Cs + contaminants higher work function

  4. Contamination of heavy metals in mangroves: A comparison between Cao Martn Pea and

    E-Print Network [OSTI]

    Gilbes, Fernando

    Contamination of heavy metals in mangroves: A comparison between Caño that contamination of heavy metals in mangroves decrease their chlorophyll levels and how heavy metals contamination has affected them. The images utilized

  5. Contamination des mollusques bivalves par des phycotoxines : interactions entre niveaux de toxicit et rponses physiologiques

    E-Print Network [OSTI]

    Boyer, Edmond

    1 Contamination des mollusques bivalves par des phycotoxines : interactions entre niveaux de principaux types de phycotoxines peuvent contaminer les mollusques bivalves : les toxines diarrhéiques (DSP nécessite de connaître au préalable les conditions initiales de contamination des mollusques ainsi que les

  6. Xenocryst assimilation and formation of peritectic crystals during magma contamination: An experimental study

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Xenocryst assimilation and formation of peritectic crystals during magma contamination Minéralogie, Switzerland c Dalhousie University, Department of Earth Sciences, Canada Abstract Contamination and peritectic crystals that form through incongruent melting or dissolution of the original contaminants

  7. A study of biological contaminants in rainwater collected from rooftops in Bryan and College Station Texas

    E-Print Network [OSTI]

    Vasudevan, Lakshmi Narasimhan

    2002-01-01T23:59:59.000Z

    This study was conducted to identify the presence of biological contaminants and the factors responsible for these contaminants in rainwater collected from rooftops of buildings in Bryan and College Station, Texas. Two main biological contaminants...

  8. Process for treating waste water having low concentrations of metallic contaminants

    DOE Patents [OSTI]

    Looney, Brian B; Millings, Margaret R; Nichols, Ralph L; Payne, William L

    2014-12-16T23:59:59.000Z

    A process for treating waste water having a low level of metallic contaminants by reducing the toxicity level of metallic contaminants to an acceptable level and subsequently discharging the treated waste water into the environment without removing the treated contaminants.

  9. A Plutonium-Contaminated Wound, 1985, USA

    SciTech Connect (OSTI)

    Doran M. Christensen, DO, REAC /TS Associate Director and Staff Physician Eugene H. Carbaugh, CHP, Staff Scientist, Internal Dosimetry Manager, Pacific Northwest National Laboratory, Richland, Washington

    2012-02-02T23:59:59.000Z

    A hand injury occurred at a U.S. facility in 1985 involving a pointed shaft (similar to a meat thermometer) that a worker was using to remove scrap solid plutonium from a plastic bottle. The worker punctured his right index finger on the palm side at the metacarpal-phalangeal joint. The wound was not through-and- through, although it was deep. The puncture wound resulted in deposition of ~48 kBq of alpha activity from the weapons-grade plutonium mixture with a nominal 12 to 1 Pu-alpha to {sup 241}Am-alpha ratio. This case clearly showed that DTPA was very effective for decorporation of plutonium and americium. The case is a model for management of wounds contaminated with transuranics: (1) a team approach for dealing with all of the issues surrounding the incident, including the psychological, (2) early surgical intervention for foreign-body removal, (3) wound irrigation with DTPA solution, and (4) early and prolonged DTPA administration based upon bioassay and in vivo dosimetry.

  10. Assessment of hot gas contaminant control

    SciTech Connect (OSTI)

    Rutkowski, M.D.; Klett, M.G.; Zaharchuk, R.

    1996-12-31T23:59:59.000Z

    The objective of this work is to gather data and information to assist DOE in responding to the NRC recommendation on hot gas cleanup by performing a comprehensive assessment of hot gas cleanup systems for advanced coal-based Integrated Gasification Combined Cycle (IGCC) and Pressurized Fluidized Bed Combustion (PFBC) including the status of development of the components of the hot gas cleanup systems, and the probable cost and performance impacts. The scope and time frame of information gathering is generally responsive to the boundaries set by the National Research council (NRC), but includes a broad range of interests and programs which cover hot gas cleanup through the year 2010. As the status of hot gas cleanup is continually changing, additional current data and information are being obtained for this effort from this 1996 METC Contractors` Review Meeting as well as from the 1996 Pittsburgh Coal Conference, and the University of Karlsruhe Symposium. The technical approach to completing this work consists of: (1) Determination of the status of hot gas cleanup technologies-- particulate collection systems, hot gas desulfurization systems, and trace contaminant removal systems; (2) Determination of hot gas cleanup systems cost and performance sensitivities. Analysis of conceptual IGCC and PFBC plant designs with hot gas cleanup have been performed. The impact of variations in hot gas cleanup technologies on cost and performance was evaluated using parametric analysis of the baseline plant designs and performance sensitivity.

  11. Remediating pesticide contaminated soils using solvent extraction

    SciTech Connect (OSTI)

    Sahle-Demessie, E.; Meckes, M.C.; Richardson, T.L. [National Management Research Lab., Cincinnati, OH (United States)

    1996-12-31T23:59:59.000Z

    Bench-scale solvent extraction studies were performed on soil samples obtained from a Superfund site contaminated with high levels of p,p{prime}-DDT, p,p{prime}-DDE and toxaphene. The effectiveness of the solvent extraction process was assessed using methanol and 2-propanol as solvents over a wide range of operating conditions. It was demonstrated that a six-stage methanol extraction using a solvent-to-soil ratio of 1.6 can decrease pesticide levels in the soil by more than 99% and reduce the volume of material requiring further treatment by 25 times or more. The high solubility of the pesticides in methanol resulted in rapid extraction rates, with the system reaching quasi-equilibrium state in 30 minutes. The extraction efficiency was influenced by the number of extraction stages, the solvent-to-soil ratio, and the soil moisture content. Various methods were investigated to regenerate and recycle the solvent. Evaporation and solvent stripping are low cost and reliable methods for removing high pesticide concentrations from the solvent. For low concentrations, GAC adsorption may be used. Precipitating and filtering pesticides by adding water to the methanol/pesticide solution was not successful when tested with soil extracts. 26 refs., 10 figs., 6 tabs.

  12. Biological Treatment of Petroleum in Radiologically Contaminated Soil

    SciTech Connect (OSTI)

    BERRY, CHRISTOPHER

    2005-11-14T23:59:59.000Z

    This chapter describes ex situ bioremediation of the petroleum portion of radiologically co-contaminated soils using microorganisms isolated from a waste site and innovative bioreactor technology. Microorganisms first isolated and screened in the laboratory for bioremediation of petroleum were eventually used to treat soils in a bioreactor. The bioreactor treated soils contaminated with over 20,000 mg/kg total petroleum hydrocarbon and reduced the levels to less than 100 mg/kg in 22 months. After treatment, the soils were permanently disposed as low-level radiological waste. The petroleum and radiologically contaminated soil (PRCS) bioreactor operated using bioventing to control the supply of oxygen (air) to the soil being treated. The system treated 3.67 tons of PCRS amended with weathered compost, ammonium nitrate, fertilizer, and water. In addition, a consortium of microbes (patent pending) isolated at the Savannah River National Laboratory from a petroleum-contaminated site was added to the PRCS system. During operation, degradation of petroleum waste was accounted for through monitoring of carbon dioxide levels in the system effluent. The project demonstrated that co-contaminated soils could be successfully treated through bioventing and bioaugmentation to remove petroleum contamination to levels below 100 mg/kg while protecting workers and the environment from radiological contamination.

  13. Innovative technology for contamination control in plasma processing

    SciTech Connect (OSTI)

    Selwyn, G.S.

    1994-10-01T23:59:59.000Z

    The causes and contributing factors to wafer contamination during plasma processing are discussed in the context of future technologies for controlling particle contamination by tool and process design and by the development of wafer dry cleaning technology. The importance of these developments is linked with the history of technological innovation and with the continuing evolution of the cleanroom from a highly developed facility for reducing ambient particle levels to an integrated, synergistic approach involving facilities and tooling for impeding the formation and transport of particles while also actively removing particles from sensitive surfaces. The methods, strategy and requirements for innovation in contamination control for plasma processing is discussed from a diachronic viewpoint.

  14. Measurement of Neutral Particle Contamination in the MICE Muon Beam

    E-Print Network [OSTI]

    Rob Roy Fletcher; Linda Coney; Gail Hanson

    2011-05-03T23:59:59.000Z

    The Muon Ionization Cooling Experiment (MICE) is being built at the ISIS proton synchrotron at Rutherford Appleton Laboratory (RAL) to measure ionization cooling of a muon beam. During recent data-taking, it was determined that there is a significant background contamination of neutral particles populating the MICE muon beam. This contamination creates unwanted triggers in MICE, thus reducing the percentage of useful data taken during running. This paper describes the analysis done with time-of-flight detectors, used to measure and identify the source of the contamination in both positive and negative muon beams.

  15. Bioavailability of sediment-bound contaminants to marine organisms

    SciTech Connect (OSTI)

    Brown, B. [Battelle/Marine Sciences Lab., Sequim, WA (United States); [Colby Coll., Waterville, ME (United States); Neff, J. [Battelle/Marine Sciences Lab., Sequim, WA (United States); [Battelle Ocean Sciences, Duxbury, MA (United States)

    1993-09-01T23:59:59.000Z

    The bioavailability of sediment-bound contaminants to marine organisms indicates that there exists a potential for transfer of these contaminants through marine food webs to commercial fisheries products consumed by humans. However, there has been relatively little effort to combine and synthesize data on chemical/biological interactions between benthic animals and seagrasses and the sediments in which they reside on the one hand, and on the chemistry of bioaccumulation on the other. This report provides a conceptual basis for an approach to bioavailability and biomagnification of sediment-bound contaminants that reviews biological and chemical approaches.

  16. Effect of Coal Gas Contaminants on Solid Oxide Fuel Cell Operation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Coal Gas Contaminants on Solid Oxide Fuel Cell Operation. Effect of Coal Gas Contaminants on Solid Oxide Fuel Cell Operation. Abstract: The operation of solid oxide fuel cells...

  17. Mitigation of the Impact of Pt Contamination on Cu-Zeolite SCR...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    the Impact of Pt Contamination on Cu-Zeolite SCR Catalyst Performance Mitigation of the Impact of Pt Contamination on Cu-Zeolite SCR Catalyst Performance Investigates operating...

  18. Procedures for sampling radium-contaminated soils

    SciTech Connect (OSTI)

    Fleischhauer, H.L.

    1985-10-01T23:59:59.000Z

    Two procedures for sampling the surface layer (0 to 15 centimeters) of radium-contaminated soil are recommended for use in remedial action projects. Both procedures adhere to the philosophy that soil samples should have constant geometry and constant volume in order to ensure uniformity. In the first procedure, a ''cookie cutter'' fashioned from pipe or steel plate, is driven to the desired depth by means of a slide hammer, and the sample extracted as a core or plug. The second procedure requires use of a template to outline the sampling area, from which the sample is obtained using a trowel or spoon. Sampling to the desired depth must then be performed incrementally. Selection of one procedure over the other is governed primarily by soil conditions, the cookie cutter being effective in nongravelly soils, and the template procedure appropriate for use in both gravelly and nongravelly soils. In any event, a minimum sample volume of 1000 cubic centimeters is recommended. The step-by-step procedures are accompanied by a description of the minimum requirements for sample documentation. Transport of the soil samples from the field is then addressed in a discussion of the federal regulations for shipping radioactive materials. Interpretation of those regulations, particularly in light of their application to remedial action soil-sampling programs, is provided in the form of guidance and suggested procedures. Due to the complex nature of the regulations, however, there is no guarantee that our interpretations of them are complete or entirely accurate. Preparation of soil samples for radium-226 analysis by means of gamma-ray spectroscopy is described.

  19. Nitrate contamination of domestic potable water supplies: a social problem

    SciTech Connect (OSTI)

    Holmes, T.; Jensen, E.L.; Conway, J.B.

    1985-01-01T23:59:59.000Z

    Nitrate contamination of potable water supplies is a recognized health hazard. Potentially, the contamination of private drinking water supplies could be a problem in the rural Palouse area of Idaho and Washington. Studies have shown that 12% of the rural population of Whitman County, Washington, may be drinking water containing nitrates in excess of the national standard. Yet there is no organized concern about this potential health hazard among local citizens. After reviewing the literature on nitrate contamination of ground water and discussing nitrate contamination of private potable water supplies in the Palouse, we use a social movement theory of social problems to explain why this situation has not been defined as a public health problem.

  20. Detection of contaminants using a MEMS FAIMS sensor

    E-Print Network [OSTI]

    Carr, Kristin (Kristin Malia)

    2005-01-01T23:59:59.000Z

    Detecting the presence of contaminants in water is a critical mission, but thorough testing often requires extensive time at a remote facility. A MEMS implementation of a FAIMS (High-Field Asymmetric-Waveform Ion Mobility ...

  1. Solidification/stabilization of simulated uranium and nickel contaminated sludges 

    E-Print Network [OSTI]

    Ramabhadran, Sanjay

    1996-01-01T23:59:59.000Z

    Research missions in nuclear energy conducted by the U.S. Department of Energy facilities have generated large volumes of mixed wastes with hazardous and radioactive components. Uranium and nickel are the primary contaminants of concern...

  2. Transuranic contaminated waste form characterization and data base

    SciTech Connect (OSTI)

    Kniazewycz, B.G.; McArthur, W.C.

    1980-07-01T23:59:59.000Z

    This volume contains 5 appendices. Title listing are: technologies for recovery of transuranics; nondestructive assay of TRU contaminated wastes; miscellaneous waste characteristics; acceptance criteria for TRU waste; and TRU waste treatment technologies.

  3. Contaminant modeling. Environmental effects of dredging. Technical note

    SciTech Connect (OSTI)

    Bird, S.L.; Dortch, M.

    1988-03-01T23:59:59.000Z

    This note provides initial information on contaminant models that are potentially applicable to situations where the presence of toxic materials in sediments complicates Corps of Engineers (CE) dredging activities.

  4. Rapid and Robust Detection Methods for Poison and Microbial Contamination

    E-Print Network [OSTI]

    Lu, Peter J.

    Real-time on-site monitoring of analytes is currently in high demand for food contamination, water, medicines, and ingestible household products that were never tested appropriately. Here we introduce chemical methods for ...

  5. Orthogonal Analytical Approaches to Detect Potential Contaminants in Heparin

    E-Print Network [OSTI]

    Shriver, Zachary

    Heparin is a widely used anticoagulant and antithrombotic agent. Recently, a contaminant, oversulfated chondroitin sulfate (OSCS), was discovered within heparin preparations. The presence of OSCS within heparin likely led ...

  6. alpha contaminated material: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    In this paper a long-term systematic study about gas purifiers, gas contaminants and detector performance is discussed. The study aims at measuring the lifetime of purifiers with...

  7. Sustainable treatment of hydrocarbon-contaminated industrial land 

    E-Print Network [OSTI]

    Cunningham, Colin John

    2012-06-25T23:59:59.000Z

    Land contamination by petroleum hydrocarbons is a widespread and global environmental pollution issue from recovery and refining of crude oil and the ubiquitous use of hydrocarbons in industrial processes and applications. ...

  8. Biodegradation of petroleum hydrocarbons in contaminated aqueous and sediment environments

    E-Print Network [OSTI]

    Mills, Marc Allyn

    1994-01-01T23:59:59.000Z

    Six bioremediation methods were tested in laboratory microcosms using field soil and water samples from within the fire-wall area of a petroleum storage tank. This soil had been intermittently contaminated with Bunker C fuel oil and other petroleum...

  9. USE OF APATITE FOR CHEMICAL STABILIZATION OF SUBSURFACE CONTAMINANTS

    SciTech Connect (OSTI)

    Dr. William D. Bostick

    2003-05-01T23:59:59.000Z

    Groundwater at many Federal and civilian industrial sites is often contaminated with toxic metals at levels that present a potential concern to regulatory agencies. The U.S. Department of Energy (DOE) has some unique problems associated with radionuclides (primarily uranium), but metal contaminants most likely drive risk-based cleanup decisions, from the perspective of human health, in groundwater at DOE and U.S. Environmental Protection Agency (EPA) Superfund Sites include lead (Pb), arsenic (As), cadmium (Cd), chromium (Cr), mercury (Hg), zinc (Zn), selenium (Se), antimony (Sb), copper (Cu) and nickel (Ni). Thus, the regulatory ''drivers'' for toxic metals in contaminated soils/groundwaters are very comparable for Federal and civilian industrial sites, and most sites have more than one metal above regulatory action limits. Thus improving the performance of remedial technologies for metal-contaminated groundwater will have ''dual use'' (Federal and civilian) benefit.

  10. Radon induced surface contaminations in low background experiments

    SciTech Connect (OSTI)

    Pattavina, L. [INFN - Laboratori Nazionali del Gran Sasso, I-67010 Assergi (AQ) (Italy)] [INFN - Laboratori Nazionali del Gran Sasso, I-67010 Assergi (AQ) (Italy)

    2013-08-08T23:59:59.000Z

    In neutrinoless double-beta decay and dark matter searches, one of the main issues is to increase the experimental sensitivity through careful material selection and production, minimizing the background contributions. In order to achieve the required, extremely low, counting rates, very stringent requirements must be fulfilled in terms of bulk material radiopurity. As the experimental sensitivity increases, the bulk impurities in the detector components decrease, and surface contaminations start to play an increasingly significant role In fully active detectors, like cryogenic particle detectors, surface contaminations are a critical issue (as shown by the CUORICINO experiment). {sup 222}Rn is by far the most intense source of airborne radioactivity, and if a radio-pure material is exposed to environment where the Radon concentration is not minimized, {sup 210}Pb and {sup 210}Po contaminations can occur. The mechanisms and the dynamics of Radon-induced surface contaminations are reviewed, and specific solutions to prevent and to reject the induced background are presented.

  11. Mechanisms of metal release from contaminated coastal sediments

    E-Print Network [OSTI]

    Kalnejais, Linda H

    2005-01-01T23:59:59.000Z

    The fate of trace metals in contaminated coastal sediments is poorly understood, yet critical for effective coastal management. The aim of this thesis is to investigate and quantify the mechanisms leading to the release ...

  12. Catalytic destruction of groundwater contaminants in reactive extraction wells

    DOE Patents [OSTI]

    McNab, Jr., Walt W. (Concord, CA); Reinhard, Martin (Stanford, CA)

    2002-01-01T23:59:59.000Z

    A system for remediating groundwater contaminated with halogenated solvents, certain metals and other inorganic species based on catalytic reduction reactions within reactive well bores. The groundwater treatment uses dissolved hydrogen as a reducing agent in the presence of a metal catalyst, such a palladium, to reduce halogenated solvents (as well as other substituted organic compounds) to harmless species (e.g., ethane or methane) and immobilize certain metals to low valence states. The reactive wells function by removing water from a contaminated water-bearing zone, treating contaminants with a well bore using catalytic reduction, and then reinjecting the treated effluent into an adjacent water-bearing zone. This system offers the advantages of a compact design with a minimal surface footprint (surface facilities) and the destruction of a broad suite of contaminants without generating secondary waste streams.

  13. arsenic contaminated soils: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    x-ray fluorescence and x-contaminating metal cations (Cu, Zn, & Cr) in the solid phase speciation of arsenic. Elemental maps from SXRF of this study show that As...

  14. Application of integrated constructed wetlands for contaminant treatment and diffusion 

    E-Print Network [OSTI]

    Dong, Yu

    2013-07-01T23:59:59.000Z

    The sediment accumulation is an important characteristic in the ageing process of integrated constructed wetlands (ICW). Retained nutrient and other contaminants in wetland sediments have the potential to be remobilized ...

  15. Contaminant Boundary at the Faultless Underground Nuclear Test

    SciTech Connect (OSTI)

    Greg Pohll; Karl Pohlmann; Jeff Daniels; Ahmed Hassan; Jenny Chapman

    2003-04-01T23:59:59.000Z

    The U.S. Department of Energy (DOE) and the Nevada Division of Environmental Protection (NDEP) have reached agreement on a corrective action strategy applicable to address the extent and potential impact of radionuclide contamination of groundwater at underground nuclear test locations. This strategy is described in detail in the Federal Facility Agreement and Consent Order (FFACO, 2000). As part of the corrective action strategy, the nuclear detonations that occurred underground were identified as geographically distinct corrective action units (CAUs). The strategic objective for each CAU is to estimate over a 1,000-yr time period, with uncertainty quantified, the three-dimensional extent of groundwater contamination that would be considered unsafe for domestic and municipal use. Two types of boundaries (contaminant and compliance) are discussed in the FFACO that will map the three-dimensional extent of radionuclide contamination. The contaminant boundary will identify the region wi th 95 percent certainty that contaminants do not exist above a threshold value. It will be prepared by the DOE and presented to NDEP. The compliance boundary will be produced as a result of negotiation between the DOE and NDEP, and can be coincident with, or differ from, the contaminant boundary. Two different thresholds are considered for the contaminant boundary. One is based on the enforceable National Primary Drinking Water Regulations for radionuclides, which were developed as a requirement of the Safe Drinking Water Act. The other is a risk-based threshold considering applicable lifetime excess cancer-risk-based criteria The contaminant boundary for the Faultless underground nuclear test at the Central Nevada Test Area (CNTA) is calculated using a newly developed groundwater flow and radionuclide transport model that incorporates aspects of both the original three-dimensional model (Pohlmann et al., 1999) and the two-dimensional model developed for the Faultless data decision analysis (DDA) (Pohll and Mihevc, 2000). This new model includes the uncertainty in the three-dimensional spatial distribution of lithology and hydraulic conductivity from the 1999 model as well as the uncertainty in the other flow and transport parameters from the 2000 DDA model. Additionally, the new model focuses on a much smaller region than was included in the earlier models, that is, the subsurface within the UC-1 land withdrawal area where the 1999 model predicted radionuclide transport will occur over the next 1,000 years. The purpose of this unclassified document is to present the modifications to the CNTA groundwater flow and transport model, to present the methodology used to calculate contaminant boundaries, and to present the Safe Drinking Water Act and risk-derived contaminant boundaries for the Faultless underground nuclear test CAU.

  16. Temporal trends of contaminants recorded in sediments of Puget Sound

    SciTech Connect (OSTI)

    Crecelius, E.A.; Curl, H.C. Jr.

    1988-03-01T23:59:59.000Z

    This paper discusses the temporal trends of contamination that can be inferred from the chemical composition of age-dated sediment cores from central Puget Sound. The fine-grain sediment (less than 10% sand) of the deep region (>150m) of central Puget Sound, which accumulates relatively undisturbed sediment at a rate of approximately 1 cm per year, provides a useful record of the history of contamination. 21 refs., 4 figs.

  17. System to control contamination during retrieval of buried TRU waste

    DOE Patents [OSTI]

    Menkhaus, Daniel E. (Idaho Falls, ID); Loomis, Guy G. (Idaho Falls, ID); Mullen, Carlan K. (Idaho Falls, ID); Scott, Donald W. (Idaho Falls, ID); Feldman, Edgar M. (Idaho Falls, ID); Meyer, Leroy C. (Idaho Falls, ID)

    1993-01-01T23:59:59.000Z

    A system to control contamination during the retrieval of hazardous waste comprising an outer containment building, an inner containment building, within the outer containment building, an electrostatic radioactive particle recovery unit connected to and in communication with the inner and outer containment buildings, and a contaminate suppression system including a moisture control subsystem, and a rapid monitoring system having the ability to monitor conditions in the inner and outer containment buildings.

  18. A unified theory on electro-kinetic extraction of contaminants

    E-Print Network [OSTI]

    Datla, Subbaraju

    1994-01-01T23:59:59.000Z

    of contaminants from fine-grained soils. Here, the experimental and the theoretical studies conducted to date are reviewed briefly 2. 3. 1. Experimental Studies The technique of electro-kinetic extraction of salts from alkaline soils was investigated by Puri...A VNIFIED THEORY ON ELECTRO-KINETIC EXTRACTION OF CONTAMINANTS A Thesis by SUBBARAJU DATLA Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE...

  19. The recognition of toxic contaminants in sea water by bioassay

    E-Print Network [OSTI]

    Duke, Thomas Wade

    1960-01-01T23:59:59.000Z

    THE RECOGNITION OF TOXIC CONTAMINANTS IN SEA WATER BY BIOASSAY A Thesis By THOMAS WADE DUKE Submitted to the Graduate School of the Agricultural and Mechanical College of Texas in partial fulfillment of the requirements for the degree... of MASTER OF SCIENCE January 1960 Major Subject: Biological Oceanography THE RECOGNITION OF TOXIC CONTAMINANTS IN SEA li'ATER BY BIOASSAY A Thesis THOMAS O'ADE DUKE Approved as to style and content by: ( airman o emmy ee wi, ( ea of Depar me...

  20. The recognition of toxic contaminants in sea water by bioassay 

    E-Print Network [OSTI]

    Duke, Thomas Wade

    1960-01-01T23:59:59.000Z

    THE RECOGNITION OF TOXIC CONTAMINANTS IN SEA WATER BY BIOASSAY A Thesis By THOMAS WADE DUKE Submitted to the Graduate School of the Agricultural and Mechanical College of Texas in partial fulfillment of the requirements for the degree... of MASTER OF SCIENCE January 1960 Major Subject: Biological Oceanography THE RECOGNITION OF TOXIC CONTAMINANTS IN SEA li'ATER BY BIOASSAY A Thesis THOMAS O'ADE DUKE Approved as to style and content by: ( airman o emmy ee wi, ( ea of Depar me...