National Library of Energy BETA

Sample records for of2 state mo

  1. Equation of state of bcc-Mo by static volume compression to 410 GPa

    SciTech Connect (OSTI)

    Akahama, Yuichi; Hirao, Naohisa; Ohishi, Yasuo; Singh, Anil K.

    2014-12-14

    Unit cell volumes of Mo and Pt have been measured simultaneously to ≈400 GPa by x-ray powder diffraction using a diamond anvil cell and synchrotron radiation source. The body-centered cubic (bcc) phase of Mo was found to be stable up to 410 GPa. The equation of state (EOS) of bcc-Mo was determined on the basis of Pt pressure scale. A fit of Vinet EOS to the volume compression data gave K{sub 0} = 262.3(4.6) GPa, K{sub 0}′ = 4.55(16) with one atmosphere atomic volume V{sub 0} = 31.155(24) A{sup 3}. The EOS was in good agreement with the previous ultrasonic data within pressure difference of 2.5%–3.3% in the multimegabar range, though the EOS of Mo proposed from a shock compression experiment gave lower pressure by 7.2%–11.3% than the present EOS. The agreement would suggest that the Pt pressure scale provides an accurate pressure value in an ultra-high pressure range.

  2. Surface confined quantum well state in MoS{sub 2}(0001) thin film (Journal

    Office of Scientific and Technical Information (OSTI)

    Article) | SciTech Connect Surface confined quantum well state in MoS{sub 2}(0001) thin film Citation Details In-Document Search Title: Surface confined quantum well state in MoS{sub 2}(0001) thin film Surface confined quantum well state (scQWS) is a QWS confined around the surface of a thin film whose electronic energy is smaller than the work function of the film. The scQWS is rather rare in most thin films. Here, we show the existence of scQWS in thin films of transition metal

  3. Theoretical study on strain induced variations in electronic properties of 2H-MoS{sub 2} bilayer sheets

    SciTech Connect (OSTI)

    Dong, Liang; Dongare, Avinash M.; Namburu, Raju R.; O'Regan, Terrance P.; Dubey, Madan

    2014-02-03

    The strain dependence of the electronic properties of bilayer sheets of 2H-MoS{sub 2} is studied using ab initio simulations based on density functional theory. An indirect band gap for bilayer MoS{sub 2} is observed for all variations of strain along the basal plane. Several transitions for the indirect band gap are observed for various strains for the bilayer structure. The variation of the band gap and the carrier effective masses for the holes and the electrons for the bilayer MoS{sub 2} structure under conditions of uniaxial strain, biaxial strain, as well as uniaxial stress is investigated.

  4. Observation of localized states in atomically thin MoS{sub 2} field effect transistor

    SciTech Connect (OSTI)

    Ghatak, Subhamoy; Pal, Atindra Nath; Ghosh, Arindam

    2013-12-04

    We present electrical transport and low frequency (1/f) noise measurements on mechanically exfoliated single, bi and trilayer MoS{sub 2}-based FET devices on Si/SiO{sub 2} substrate. We find that the electronic states in MoS{sub 2} are localized at low temperatures (T) and conduction happens through variable range hopping (VRH). A steep increase of 1/f noise with decreasing T, typical for localized regime was observed in all of our devices. From gate voltage dependence of noise, we find that the noise power is inversely proportional to square of the number density (? 1/n{sup 2}) for a wide range of T, indicating number density fluctuations to be the dominant source of 1/f noise in these MoS{sub 2} FETs.

  5. On the bonding nature of electron states for the Fe-Mo double perovskite

    SciTech Connect (OSTI)

    Carvajal, E.; Cruz-Irisson, M.; Oviedo-Roa, R.; Navarro, O.

    2014-05-15

    The electronic transport as well as the effect of an external magnetic field has been investigated on manganese-based materials, spinels and perovskites. Potential applications of double perovskites go from magnetic sensors to electrodes in solid-oxide fuel cells; besides the practical interests, it is known that small changes in composition modify radically the physical properties of double perovskites. We have studied the Sr{sub 2}FeMoO{sub 6} double perovskite compound (SFMO) using first-principles density functional theory. The calculations were done within the generalized gradient approximation (GGA) scheme with the Perdew-Burke-Ernzerhof (PBE) functional. We have made a detailed analysis of each electronic state and the charge density maps around the Fermi level. For the electronic properties of SFMO it was used a primitive cell, for which we found the characteristic half-metallic behavior density of states composed by e{sub g} and t{sub 2g} electrons from Fe and Mo atoms. Those peaks were tagged as bonding or antibonding around the Fermi level at both, valence and conduction bands.

  6. Observation of a new charged charmoniumlike state inB<mo stretchy='false'>mo>0<mo stretchy='false'>?mo>J<mo>/mo>?K<mo>-mo>?<mo>+>decays

    SciTech Connect (OSTI)

    Chilikin, K.; Mizuk, R.; Adachi, I.; Aihara, H.; Al Said, S.; Arinstein, K.; Asner, D.?M.; Aulchenko, V.; Aushev, T.; Ayad, R.; Aziz, T.; Bakich, A.?M.; Bansal, V.; Bondar, A.; Bonvicini, G.; Bozek, A.; Bra?ko, M.; Browder, T.?E.; ?ervenkov, D.; Chekelian, V.; Chen, A.; Cheon, B.?G.; Chistov, R.; Cho, K.; Chobanova, V.; Choi, S.-K.; Choi, Y.; Cinabro, D.; Danilov, M.; Doleal, Z.; Drsal, Z.; Drutskoy, A.; Dutta, K.; Eidelman, S.; Epifanov, D.; Farhat, H.; Fast, J.?E.; Ferber, T.; Frost, O.; Gaur, V.; Gabyshev, N.; Ganguly, S.; Garmash, A.; Gillard, R.; Goh, Y.?M.; Golob, B.; Grzymkowska, O.; Haba, J.; Hara, T.; Hayasaka, K.; Hayashii, H.; He, X.?H.; Hou, W.-S.; Huschle, M.; Hyun, H.?J.; Ishikawa, A.; Itoh, R.; Iwasaki, Y.; Jaegle, I.; Joo, K.?K.; Julius, T.; Kawasaki, T.; Kiesling, C.; Kim, D.?Y.; Kim, H.?J.; Kim, J.?H.; Kim, M.?J.; Kim, Y.?J.; Kinoshita, K.; Ko, B.?R.; Korpar, S.; Krian, P.; Krokovny, P.; Kuhr, T.; Kuzmin, A.; Kwon, Y.-J.; Lange, J.?S.; Li, Y.; Li Gioi, L.; Libby, J.; Liu, Y.; Liventsev, D.; Lukin, P.; Miyabayashi, K.; Miyata, H.; Mohanty, G.?B.; Moll, A.; Mori, T.; Mussa, R.; Nakano, E.; Nakao, M.; Nanut, T.; Natkaniec, Z.; Nedelkovska, E.; Nisar, N.?K.; Nishida, S.; Ogawa, S.; Okuno, S.; Olsen, S.?L.; Pakhlov, P.; Pakhlova, G.; Park, C.?W.; Park, H.; Pedlar, T.?K.; Petri?, M.; Piilonen, L.?E.; Ribel, E.; Ritter, M.; Rostomyan, A.; Sakai, Y.; Sandilya, S.; Santelj, L.; Sanuki, T.; Sato, Y.; Savinov, V.; Schneider, O.; Schnell, G.; Schwanda, C.; Seon, O.; Shebalin, V.; Shen, C.?P.; Shibata, T.-A.; Shiu, J.-G.; Shwartz, B.; Sibidanov, A.; Simon, F.; Sohn, Y.-S.; Sokolov, A.; Solovieva, E.; Stari?, M.; Steder, M.; Sumisawa, K.; Sumiyoshi, T.; Tamponi, U.; Tanida, K.; Tatishvili, G.; Teramoto, Y.; Thorne, F.; Trabelsi, K.; Uchida, M.; Uehara, S.; Uglov, T.; Unno, Y.; Uno, S.; Urquijo, P.; Van Hulse, C.; Vanhoefer, P.; Varner, G.; Vinokurova, A.; Wagner, M.?N.; Wang, C.?H.; Wang, M.-Z.; Wang, P.; Wang, X.?L.; Watanabe, Y.; Wehle, S.; Williams, K.?M.; Won, E.; Yamaoka, J.; Yashchenko, S.; Zhang, Z.?P.; Zhilich, V.; Zhulanov, V.; Zupanc, A.

    2014-12-16

    We present the results of an amplitude analysis of B0?J/?K-?+ decays. A new charged charmoniumlike state Zc(4200)+ decaying to J/??+ is observed with a significance of 6.2?. The mass and width of the Zc(4200)+ are 4196+31-29+17-13 MeV/c2 and 370+70-70+70-132 MeV, respectively; the preferred assignment of the quantum numbers is JP=1+. In addition, we find evidence for Zc(4430)+?J/??+. The analysis is based on a 711 fb-1 data sample collected by the Belle detector at the asymmetric-energy e+e- collider KEKB.

  7. Mo-99

    National Nuclear Security Administration (NNSA)

    its project for domestic production of molybdenum-99 (Mo-99) without highly enriched uranium (HEU).

    Mo-99 is the parent isotope of technetium-99m, which is the most widely...

  8. Mo-99

    National Nuclear Security Administration (NNSA)

    NorthStar Medical Radioisotopes to further develop its technology to produce Mo-99 via neutron capture, bringing the total NNSA support to this project to the maximum of 25...

  9. Origin State>> CA CA ID ID ID IL KY MD MO NM NM NY NY OH SC

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    MO NM NM NY NY OH SC TN TN TN, WA, CA TN TN TN TN Total Shipments by Route Lawrence Livermore National Laboratory General Atomics Batelle Energy Alliance Idaho National Laboratory Advanced Mixed Waste Treatment Project Argonne National Laboratory Paducah Gaseous Diffusion Plant Aberdeen Proving Grounds National Security Technologies Sandia National Laboratory Los Alamos National Laboratory Brookhaven National Laboratory CH2M Hill B&W West Valley, LLC Portsmouth Gaseous Diffusion Plant

  10. MO: ZL

    Office of Legacy Management (LM)

    II , --fsi2L /~YlO MO: ZL W./O -1 ;3UN 2 2 1984 DeLanr 6/W/f. NE-20 -24 Authorization for Remedial Action at the Seaway Industrial Park and Ashland 0 1 Co. (I) Sites at Tonawanda, 9 NY, and Mallinckrodt Chemical Co., St. Louis, MO Ba 1s J. LaGrone, Eianager Oak Ridge Operations Office 6/20/E We have determined that the subject sites are contaminated with residual NE-20 radioactive material as a result of the Manhattan Engineer District/Atomic ,/"/1. EnergyXommission operations at those

  11. Evaluation of 2.25Cr-1Mo Alloy for Containment of LiCl/KCl Eutectic during the Pyrometallurgical Processing of Used Nuclear Fuel

    SciTech Connect (OSTI)

    B.R. Westphal; S.X. Li; G.L. Fredrickson; D. Vaden; T.A. Johnson; J.C. Wass

    2011-03-01

    Recovery of uranium from the Mk-IV and Mk-V electrorefiner vessels containing a LiCl/KCl eutectic salt has been on-going for 14 and 12 years, respectively, during the pyrometallurgical processing of used nuclear fuel. Although austenitic stainless steels are typically utilized for LiCl/KCl salt systems, the presence of cadmium in the Mk-IV electrorefiner dictates an alternate material. A 2.25Cr-1Mo alloy (ASME SA-387) was chosen due to the absence of nickel in the alloy which has a considerable solubility in cadmium. Using the transition metal impurities (iron, chromium, nickel, molybdenum, and manganese) in the electrorefined uranium products, an algorithm was developed to derive values for the contribution of the transition metals from the various input sources. Weight loss and corrosion rate data for the Mk-V electrorefiner vessel were then generated based on the transition metal impurities in the uranium products. To date, the corrosion rate of the 2.25Cr-1Mo alloy in LiCl/KCl eutectic is outstanding assuming uniform (i.e. non-localized) conditions.

  12. Exciton-dominant electroluminescence from a diode of monolayer MoS{sub 2}

    SciTech Connect (OSTI)

    Ye, Yu; Ye, Ziliang; Gharghi, Majid; Zhu, Hanyu; Wang, Yuan; Zhao, Mervin; Yin, Xiaobo; Zhang, Xiang

    2014-05-12

    In two-dimensional monolayer MoS{sub 2}, excitons dominate the absorption and emission properties. However, the low electroluminescent efficiency and signal-to-noise ratio limit our understanding of the excitonic behavior of electroluminescence. Here, we study the microscopic origin of the electroluminescence from a diode of monolayer MoS{sub 2} fabricated on a heavily p-type doped silicon substrate. Direct and bound-exciton related recombination processes are identified from the electroluminescence. At a high electron-hole pair injection rate, Auger recombination of the exciton-exciton annihilation of the bound exciton emission is observed at room temperature. Moreover, the efficient electrical injection demonstrated here allows for the observation of a higher energy exciton peak of 2.255?eV in the monolayer MoS{sub 2} diode, attributed to the excited exciton state of a direct-exciton transition.

  13. Role of SrMoO{sub 4} in Sr{sub 2}MgMoO{sub 6} synthesis

    SciTech Connect (OSTI)

    Vasala, S.; Yamauchi, H.; Karppinen, M.

    2011-05-15

    Here we investigate the elemental and phase compositions during the solid-state synthesis of the promising SOFC-anode material, Sr{sub 2}MgMoO{sub 6}, and demonstrate that molybdenum does not notably evaporate under the normal synthesis conditions with temperatures up to 1200 {sup o}C due to the formation of SrMoO{sub 4} as an intermediate product at low temperatures, below 600 {sup o}C. However, partial decomposition of the Sr{sub 2}MgMoO{sub 6} phase becomes evident at the higher temperatures ({approx}1500 {sup o}C). The effect of SrMoO{sub 4} on the electrical conductivity of Sr{sub 2}MgMoO{sub 6} is evaluated by preparing a series of Sr{sub 2}MgMoO{sub 6} samples with different amounts of additional SrMoO{sub 4}. Under the reducing operation conditions of an SOFC anode the insulating SrMoO{sub 4} phase is apparently reduced to the highly conductive SrMoO{sub 3} phase. Percolation takes place with 20-30 wt% of SrMoO{sub 4} in a Sr{sub 2}MgMoO{sub 6} matrix, with a notable increase in electrical conductivity after reduction. Conductivity values of 14, 60 and 160 S/cm are determined at 800 {sup o}C in 5% H{sub 2}/Ar for the Sr{sub 2}MgMoO{sub 6} samples with 30, 40 and 50 wt% of added SrMoO{sub 4}, respectively. -- Graphical abstract: SrMoO{sub 4} is formed at low temperatures during the synthesis of Sr{sub 2}MgMoO{sub 6}, which prevents the volatilization of Mo from typical precursor mixtures of this promising SOFC anode material. SrMoO{sub 4} is insulating and it is often found as an impurity in Sr{sub 2}MgMoO{sub 6} samples. It is however readily reduced to highly conducting SrMoO{sub 3}. Composites of Sr{sub 2}MgMoO{sub 6} and SrMoO{sub 3} show increased electrical conductivities compared to pure Sr{sub 2}MgMoO{sub 6} under the reductive operation conditions of an SOFC anode. Display Omitted Highlights: {yields} Sr{sub 2}MgMoO{sub 6} is a promising SOFC anode material. {yields} During the Sr{sub 2}MgMoO{sub 6} synthesis SrMoO{sub 4} is formed at low temperatures. {yields} Formation of SrMoO{sub 4} effectively prevents volatilization of Mo at high temperatures. {yields} Insulating SrMoO{sub 4} reduces to highly conductive SrMoO{sub 3} under SOFC-anode conditions. {yields} Composites of Sr{sub 2}MgMoO{sub 6} and SrMoO{sub 3} show high electrical conductivities.

  14. Intermetallic phase formation and breakdown of Mo diffusion barriers in Ni-Mo-Cu and Ni-Mo-Monel 400 diffusion triads

    SciTech Connect (OSTI)

    Shueh, Y.

    1988-01-01

    The purpose of this research was to study the kinetics of compound formation and the interdiffusion behavior of a sacrificial type diffusion barrier in a model system. Ni-Mo diffusion couples were annealed in an inert atmosphere at 950-1050{degree}C for 5-300 hours. Ni-Mo-Cu and Ni-Mo-Monel 400 diffusion triads with varied thicknesses of Mo layers sandwiched by Ni and C or Monel 400 disks were annealed under the same conditions. Parabolic growth of the intermetallic phase, {beta}, was observed at 1000{degree}C and 1050{degree}C in the semi-infinite Ni-Mo diffusion couple an din the Ni-Mo-Cu diffusion triad when a finite thickness of the Mo layer remained. The {beta} phase exhibited more or less planar morphology except in the case of some extremely rugged interfaces which were associated with grain boundaries adjacent to these interfaces. Dissociation and recession of the compound layer in Ni-Mo-Cu diffusion triads initiated when the Mo layer was nearly consumed. The product phases of the dissociation reaction are consistent with those predicted from the Ni-Mo-Cu ternary phase diagram. Numerical methods based on a finite difference technique, and an analytical solution based on diffusion controlled parabolic growth and quasi-steady-state approximation in the {beta} phase region were used to analyze the results.

  15. Structure and electronic properties of Cu nanoclusters supported on Mo2C(001) and MoC(001) surfaces

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Posada-Pérez, Sergio; Viñes, Francesc; Rodríguez, José A.; Illas, Francesc

    2015-09-15

    In this study, the atomic structure and electronic properties of Cun nanoclusters (n = 4, 6, 7, and 10) supported on cubic nonpolar δ-MoC(001) and orthorhombic C- or Mo-terminated polar β-Mo2C(001) surfaces have been investigated by means of periodic density functional theory based calculations. The electronic properties have been analyzed by means of the density of states, Bader charges, and electron localization function plots. The Cu nanoparticles supported on β-Mo2C(001), either Mo- or C-terminated, tend to present a two-dimensional structure whereas a three-dimensional geometry is preferred when supported on δ-MoC(001), indicating that the Mo:C ratio and the surface polarity playmore » a key role determining the structure of supported clusters. Nevertheless, calculations also reveal important differences between the C- and Mo-terminated β-Mo2C(001) supports to the point that supported Cu particles exhibit different charge states, which opens a way to control the reactivity of these potential catalysts.« less

  16. Neutrino scattering off the stable even-even Mo isotopes

    SciTech Connect (OSTI)

    Balasi, K. G.; Kosmas, T. S.; Divari, P. C. [Theoretical Physics Section, University of Ioannina, GR 45110 Ioannina (Greece)

    2009-11-09

    Inelastic neutrino-nucleus reaction cross sections are studied focusing on the neutral current processes. Particularly, we investigate the angular and initial neutrino-energy dependence of the differential and integrated cross sections for low and intermediate energies of the incoming neutrino. The nuclear wave functions for the initial and final nuclear states are constructed in the context of the quasi-particle random phase approximation (QRPA) tested on the reproducibility of the low-lying energy spectrum. The results presented here refer to the isotopes Mo{sup 92}, Mo{sup 94}, Mo{sup 96}, Mo{sup 98} and Mo{sup 100}. These isotopes could play a significant role in supernova neutrino detection in addition to their use in double-beta and neutrinoless double-beta decay experiments (e.g. MOON, NEMO III)

  17. Effect of mechanical strain on electronic properties of bulk MoS{sub 2}

    SciTech Connect (OSTI)

    Kumar, Sandeep Kumar, Jagdish Sastri, O. S. K. S.

    2015-05-15

    Ab-initio density functional theory based calculations of electronic properties of bulk and monolayer Molybdenum di-Sulfide (MoS{sub 2}) have been performed using all electron Full Potential Linearised Augmentad Plane Wave (FPLAPW) method using Elk code. We have used Generalised Gradient Approximation (GGA) for exchange and correlation functionals and performed calculaitons of Lattice parameters, Density Of States (DOS) and Band Structure (BS). Band structure calculations revealed that bulk MoS{sub 2} has indirect band gap of 0.97 eV and mono-layer MoS{sub 2} has direct band gap which has increased to 1.71 eV. These are in better agreement with experimental values as compared with the other calculations using pseudo-potential code. The effect of mechanical strain on the electronic properties of bulk MoS{sub 2} has also been studied. For the different values of compressive strain (varying from 2% to 8% in steps of 2%) along the c-axis, the corresponding DOS and BS are obtained. We observed that the band gap decreases by about 15% for every 2% increase in strain along the c-axis.

  18. Quasiparticle description of (2+1)- flavor lattice QCD equation of state

    SciTech Connect (OSTI)

    Chandra, Vinod; Ravishankar, V.

    2011-10-01

    A quasiparticle model has been employed to describe the (2+1)-flavor lattice QCD equation of state with physical quark masses. The interaction part of the equation of state has been mapped to the effective fugacities of otherwise noninteracting quasigluons and quasiquarks. The mapping is found to be exact for the equation of state. The model leads to nontrivial dispersion relations for quasipartons. The dispersion relations, effective quasiparticle number densities, and trace anomaly have been investigated employing the model. A virial expansion for the equation of state has further been obtained to investigate the role of interactions in quark-gluon plasma. Finally, Debye screening in quark-gluon plasma has been studied employing the model.

  19. US WNC MO Site Consumption

    U.S. Energy Information Administration (EIA) Indexed Site

    WNC MO Site Consumption million Btu $0 $500 $1,000 $1,500 $2,000 $2,500 US WNC MO Expenditures dollars ALL ENERGY average per household (excl. transportation) 0 3,000 6,000 9,000 12,000 15,000 US WNC MO Site Consumption kilowatthours $0 $300 $600 $900 $1,200 $1,500 US WNC MO Expenditures dollars ELECTRICITY ONLY average per household * Missouri households consume an average of 100 million Btu per year, 12% more than the U.S. average. * Average household energy costs in Missouri are slightly less

  20. Tuning magnetism of monolayer MoS{sub 2} by doping vacancy and applying strain

    SciTech Connect (OSTI)

    Zheng, Huiling; Yang, Baishun; Han, Ruilin; Du, Xiaobo; Yan, Yu; Wang, Dingdi

    2014-03-31

    In view of important role of inducing and manipulating the magnetism in two-dimensional materials for the development of low-dimensional spintronic devices, the influences of strain on electronic structure and magnetic properties of commonly observed vacancies doped monolayer MoS{sub 2} are investigated using first-principles calculations. It is shown that unstrained V{sub S}, V{sub S2}, and V{sub MoS3} doped monolayer MoS{sub 2} systems are nonmagnetic, while the ground state of unstrained V{sub MoS6} doped system is magnetic and the magnetic moment is contributed mainly by six Mo atoms around V{sub MoS6}. In particular, tensile strain can induce magnetic moments in V{sub S}, V{sub S2}, and V{sub MoS3} doped monolayer MoS{sub 2} due to the breaking of Mo–Mo metallic bonds around the vacancies, while the magnetization induced by V{sub MoS6} can be effectively manipulated by equibiaxial strain due to the change of Mo–Mo metallic bonds around V{sub MoS6} under strains.

  1. Structure and electronic properties of Cu nanoclusters supported on Mo2C(001) and MoC(001) surfaces

    SciTech Connect (OSTI)

    Posada-Pérez, Sergio; Viñes, Francesc; Rodríguez, José A.; Illas, Francesc

    2015-09-15

    In this study, the atomic structure and electronic properties of Cun nanoclusters (n = 4, 6, 7, and 10) supported on cubic nonpolar δ-MoC(001) and orthorhombic C- or Mo-terminated polar β-Mo2C(001) surfaces have been investigated by means of periodic density functional theory based calculations. The electronic properties have been analyzed by means of the density of states, Bader charges, and electron localization function plots. The Cu nanoparticles supported on β-Mo2C(001), either Mo- or C-terminated, tend to present a two-dimensional structure whereas a three-dimensional geometry is preferred when supported on δ-MoC(001), indicating that the Mo:C ratio and the surface polarity play a key role determining the structure of supported clusters. Nevertheless, calculations also reveal important differences between the C- and Mo-terminated β-Mo2C(001) supports to the point that supported Cu particles exhibit different charge states, which opens a way to control the reactivity of these potential catalysts.

  2. d::;":,",:::,, ST. LOUIS.7. MO,

    Office of Legacy Management (LM)

    i ,' CKRODT CHEMICAL d::;":,",:::,, ST. LOUIS.7. MO, PiARCH 14, ,jq;ll MR. H. L. PRICE, ... I AL PERAT I ONS DF MALL- INCKRODT ' CHEMICAL b:ORKS WOULD LIKE TO MAKE.APPLlCATlON ...

  3. Optimization of the Processing of Mo Disks

    SciTech Connect (OSTI)

    Tkac, Peter; Rotsch, David A.; Stepinski, Dominique; Makarashvili, Vakhtang; Harvey, James; Vandegrift, George F.

    2016-01-01

    The objective of this work is to decrease the processing time for irradiated disks of enriched Mo for the production of 99Mo. Results are given for the dissolution of nonirradiated Mo disks, optimization of the process for large-scale dissolution of sintered disks, optimization of the removal of the main side products (Zr and Nb) from dissolved targets, and dissolution of irradiated Mo disks.

  4. SSL Demonstration: Street Lighting, Kansas City, MO

    SciTech Connect (OSTI)

    2013-08-01

    GATEWAY program report brief summarizing an SSL street lighting demonstration at nine separate installations in Kansas City, MO.

  5. DOE - Office of Legacy Management -- Washington University - MO 07

    Office of Legacy Management (LM)

    Washington University - MO 07 FUSRAP Considered Sites Site: WASHINGTON UNIVERSITY (MO.07 ) Eliminated from consideration under FUSRAP Designated Name: Not Designated Alternate Name: None Location: St. Louis , Missouri MO.07-1 Evaluation Year: 1987 MO.07-1 Site Operations: Activities were limited to programs involving relatively small quantities of radionuclides and chemicals in a controlled environment. MO.07-3 MO.07-1 Site Disposition: Eliminated - Potential for contamination remote MO.07-1

  6. Microstructure evolution of Li uptake/removal in MoO{sub 2}@C nanoparticles with high lithium storage performance

    SciTech Connect (OSTI)

    Liu, Yulong; Zhang, Hong; Ouyang, Pan; Chen, Wenhao [School of Materials Science and Engineering, Central South University, Changsha 410083 (China); Li, Zhicheng, E-mail: zhchli@mail.csu.edu.cn [School of Materials Science and Engineering, Central South University, Changsha 410083 (China); State Key Laboratory of Powder Metallurgy, Central South University, Changsha 410083 (China)

    2014-02-01

    Highlights: The carbon-coated MoO{sub 2} (MoO{sub 2}@C) ultra fine nanoparticles are synthesized by one-pot hydrothermal method. MoO{sub 2}@C nanoparticles have high specific capacity, excellent cycling performance and rate performance. Phase transformations for lithium ion uptake/removal are examined carefully by TEM. Phase transformations are highly reversible during the redox process. - Abstract: A facile one pot strategy of a hydrothermal methodology was applied to synthesize the carbon coated MoO{sub 2} (MoO{sub 2}@C) nanostructured particles, which are composed of ultra fine nanoparticles with homogeneous carbon coating about several nanometers. As an electrode in lithium ion batteries, the MoO{sub 2}@C shows a high specific capacity and reversible capacity (730 mA h g{sup ?1} after 60 cycles). Microstructure investigations, by using a high resolution transmission electron microscopy, of the MoO{sub 2}@C based electrodes employed at various states during the first discharge/charge cycle were conducted to elucidate the lithium ion uptake/removal mechanism and cycling behavior. In the lithium uptake process, the original MoO{sub 2} phase transfers into Li{sub 0.98}MoO{sub 2} through an addition type reaction, and then nanosized metallic Mo emerges as a result of a conversion reaction. In turn, Mo could be oxidized to the intermediate Li{sub 0.98}MoO{sub 2} before converting to hyperfine MoO{sub 2} phase on upcoming lithium removal process.

  7. Synthesis and characterization of model MgO supported catalyst with Pt-Mo interactions.

    SciTech Connect (OSTI)

    Alexeev, O.; Kawi, S.; Gates, B.C. [Univ. of California, Davis, CA (United States)] [Univ. of California, Davis, CA (United States); Shelef, M. [Ford Motor Co., Dearborn, MI (United States)] [Ford Motor Co., Dearborn, MI (United States)

    1996-01-04

    MgO supported platinum and platinum-molybdenum catalysts were prepared from organometallic precursors and charaterized structurally to determine how the nature of the bimetallic precursors and the treatment conditions affected the interaction between the two metals. Samples were prepared from [PtCl{sub 2}(PhCN){sub 2}], [PtCl{sub 2}(PhCN){sub 2}] + [Mo(CO){sub 6}], and [C@Pt[Mo(CO){sub 3}(C{sub 5}H{sub 5})]{sub 2}(PhCN){sub 2}] BC@ characterized by infrared and extended X-ray absorption fine structure (EXAFS) spectroscopies, tranmission electron microscopy, and chemisorption of H{sub 2}, CO, and O{sub 2}. The samples were treated in H{sub 2} at 400{degree}C prior to most of the characterizatons. Incorporation of Mo reduced the chemisorption of CO and of H{sub 2}. EXAFS spectra measured at the Pt L{sub III} edge and at the Mo K edge showed substantial Pt-Mo contributions with a Pt-Mo cordination number of about 2 and an average distance of 2.63 A for the sample prepared from [C@Pt[Mo(CO){sub 3}(C{sub 5}H{sub 5})]{sub 2}(PhCN){sub 2}] BC@. In constract, no significant Pt-Mo contribution was observed for the sample prepared from [PtCl{sub 2}(PhCN){sub 2}]+ [Mo(CO){sub 6}]. Electron micrographs and EXAFS results show that interaction between Pt and Mo ions in the former sample helped to maintain the platinum in a highly dispersed form, with supported platinum clusters being smaller than about 10 A. 53 refs., 9 figs., 9 tabs.

  8. Mo99 Production Plant Layout

    SciTech Connect (OSTI)

    Woloshun, Keith Albert; Dale, Gregory E.; Naranjo, Angela Carol

    2015-06-25

    The NorthStar Medical Technologies 99Mo production facility configuration is envisioned to be 8 accelerator pairs irradiating 7 100Mo targets (one spare accelerator pair undergoing maintenance while the other 7 pairs are irradiating targets). The required shielding in every direction for the accelerators is initially estimated to be 10 feet of concrete. With the accelerator pairs on one (ground) level and spaced with the required shielding between adjacent pairs, the only practical path for target insertion and removal while minimizing floor space is vertical. The current scheme then requires a target vertical lift of nominally 10 feet through a shield stack. It is envisioned that the lift will be directly into a hot cell where an activated target can be removed from its holder and a new target attached and lowered. The hot cell is on a rail system so that a single hot cell can service all active target locations, as well as deliver the ready targets to the separations lab. On this rail system, coupled to the hot cell, will be a helium recovery and clean-up system. All helium coolant equipment is located on the upper level near to the target removal point.

  9. DOE - Office of Legacy Management -- Spencer Chemical Co - MO...

    Office of Legacy Management (LM)

    MO 0-01 FUSRAP Considered Sites Site: SPENCER CHEMICAL CO. (MO.0-01) Eliminated from ... Also see Documents Related to SPENCER CHEMICAL CO. MO.0-01-1 - Spencer Chemical Company ...

  10. DOE - Office of Legacy Management -- St Louis Airport - MO 01

    Office of Legacy Management (LM)

    Operations: Stored uranium process residues containing uranium, radium, and thorium for the MED and AEC. MO.01-2 MO.01-3 MO.01-4 Eligibility Determination: Eligible ...

  11. Substrate interactions with suspended and supported monolayer MoS2: Angle-resolved photoemission spectroscopy

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Jin, Wencan; Yeh, Po -Chun; Zaki, Nader; Zhang, Datong; Liou, Jonathan T.; Dadap, Jerry I.; Barinov, Alexey; Yablonskikh, Mikhail; Sadowski, Jerzy T.; Sutter, Peter; et al

    2015-03-17

    We report the directly measured electronic structure of exfoliated monolayer molybdenum disulfide (MoS₂) using micrometer-scale angle-resolved photoemission spectroscopy. Measurements of both suspended and supported monolayer MoS₂ elucidate the effects of interaction with a substrate. Thus, a suggested relaxation of the in-plane lattice constant is found for both suspended and supported monolayer MoS₂ crystals. For suspended MoS₂, a careful investigation of the measured uppermost valence band gives an effective mass at Γ¯ and Κ¯ of 2.00m₀ and 0.43m₀, respectively. We also measure an increase in the band linewidth from the midpoint of Γ¯Κ¯ to the vicinity of Κ¯ and briefly discussmore » its possible origin.« less

  12. Missouri Department of National Resources Energy Center Mo DNR...

    Open Energy Info (EERE)

    Department of National Resources Energy Center Mo DNR Jump to: navigation, search Name: Missouri Department of National Resources Energy Center (Mo DNR) Place: Jefferson City,...

  13. DOE - Office of Legacy Management -- United Nuclear Corp - MO...

    Office of Legacy Management (LM)

    Nuclear Corp - MO 0-03 FUSRAP Considered Sites Site: UNITED NUCLEAR CORP. (MO.0-03) Eliminated from further consideration under FUSRAP Designated Name: Not Designated Alternate ...

  14. Demonstration of LED Street Lighting in Kansas City, MO (Technical...

    Office of Scientific and Technical Information (OSTI)

    Demonstration of LED Street Lighting in Kansas City, MO Citation Details In-Document Search Title: Demonstration of LED Street Lighting in Kansas City, MO Nine different ...

  15. Update to M&O Contractor Model Subcontract entitled "Standard...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    to M&O Contractor Model Subcontract entitled "Standard Research Subcontract (Educational Institution or Nonprofit Organization)" Update to M&O Contractor Model Subcontract entitled ...

  16. Tuning the electronic structure of monolayer graphene/ Mo S 2...

    Office of Scientific and Technical Information (OSTI)

    Tuning the electronic structure of monolayer graphene Mo S 2 van der Waals ... Title: Tuning the electronic structure of monolayer graphene Mo S 2 van der Waals ...

  17. DOE - Office of Legacy Management -- West Lake Landfill - MO...

    Office of Legacy Management (LM)

    Lake Landfill - MO 05 FUSRAP Considered Sites Site: West Lake Landfill (MO.05) Designated Name: Alternate Name: Location: Evaluation Year: Site Operations: Site Disposition:...

  18. Simultaneous measurement of forward-backward asymmetry and top polarization in dilepton final states from tt<mo stretchy='false'>¯mo> production at the Tevatron

    SciTech Connect (OSTI)

    Abazov, V. M.; Abbott, B.; Acharya, B. S.; Adams, M.; Adams, T.; Agnew, J. P.; Alexeev, G. D.; Alkhazov, G.; Alton, A.; Askew, A.; Atkins, S.; Augsten, K.; Avila, C.; Badaud, F.; Bagby, L.; Baldin, B.; Bandurin, D. V.; Banerjee, S.; Barberis, E.; Baringer, P.; Bartlett, J. F.; Bassler, U.; Bazterra, V.; Bean, A.; Begalli, M.; Bellantoni, L.; Beri, S. B.; Bernardi, G.; Bernhard, R.; Bertram, I.; Besançon, M.; Beuselinck, R.; Bhat, P. C.; Bhatia, S.; Bhatnagar, V.; Blazey, G.; Blessing, S.; Bloom, K.; Boehnlein, A.; Boline, D.; Boos, E. E.; Borissov, G.; Borysova, M.; Brandt, A.; Brandt, O.; Brock, R.; Bross, A.; Brown, D.; Bu, X. B.; Buehler, M.; Buescher, V.; Bunichev, V.; Burdin, S.; Buszello, C. P.; Camacho-Pérez, E.; Casey, B. C. K.; Castilla-Valdez, H.; Caughron, S.; Chakrabarti, S.; Chan, K. M.; Chandra, A.; Chapon, E.; Chen, G.; Cho, S. W.; Choi, S.; Choudhary, B.; Cihangir, S.; Claes, D.; Clutter, J.; Cooke, M.; Cooper, W. E.; Corcoran, M.; Couderc, F.; Cousinou, M. -C.; Cuth, J.; Cutts, D.; Das, A.; Davies, G.; de Jong, S. J.; De La Cruz-Burelo, E.; Déliot, F.; Demina, R.; Denisov, D.; Denisov, S. P.; Desai, S.; Deterre, C.; DeVaughan, K.; Diehl, H. T.; Diesburg, M.; Ding, P. F.; Dominguez, A.; Dubey, A.; Dudko, L. V.; Duperrin, A.; Dutt, S.; Eads, M.; Edmunds, D.; Ellison, J.; Elvira, V. D.; Enari, Y.; Evans, H.; Evdokimov, A.; Evdokimov, V. N.; Fauré, A.; Feng, L.; Ferbel, T.; Fiedler, F.; Filthaut, F.; Fisher, W.; Fisk, H. E.; Fortner, M.; Fox, H.; Fuess, S.; Garbincius, P. H.; Garcia-Bellido, A.; García-González, J. A.; Gavrilov, V.; Geng, W.; Gerber, C. E.; Gershtein, Y.; Ginther, G.; Gogota, O.; Golovanov, G.; Grannis, P. D.; Greder, S.; Greenlee, H.; Grenier, G.; Gris, Ph.; Grivaz, J. -F.; Grohsjean, A.; Grünendahl, S.; Grünewald, M. W.; Guillemin, T.; Gutierrez, G.; Gutierrez, P.; Haley, J.; Han, L.; Harder, K.; Harel, A.; Hauptman, J. M.; Hays, J.; Head, T.; Hebbeker, T.; Hedin, D.; Hegab, H.; Heinson, A. P.; Heintz, U.; Hensel, C.; Heredia-De La Cruz, I.; Herner, K.; Hesketh, G.; Hildreth, M. D.; Hirosky, R.; Hoang, T.; Hobbs, J. D.; Hoeneisen, B.; Hogan, J.; Hohlfeld, M.; Holzbauer, J. L.; Howley, I.; Hubacek, Z.; Hynek, V.; Iashvili, I.; Ilchenko, Y.; Illingworth, R.; Ito, A. S.; Jabeen, S.; Jaffré, M.; Jayasinghe, A.; Jeong, M. S.; Jesik, R.; Jiang, P.; Johns, K.; Johnson, E.; Johnson, M.; Jonckheere, A.; Jonsson, P.; Joshi, J.; Jung, A. W.; Juste, A.; Kajfasz, E.; Karmanov, D.; Katsanos, I.; Kaur, M.; Kehoe, R.; Kermiche, S.; Khalatyan, N.; Khanov, A.; Kharchilava, A.; Kharzheev, Y. N.; Kiselevich, I.; Kohli, J. M.; Kozelov, A. V.; Kraus, J.; Kumar, A.; Kupco, A.; Kurča, T.; Kuzmin, V. A.; Lammers, S.; Lebrun, P.; Lee, H. S.; Lee, S. W.; Lee, W. M.; Lei, X.; Lellouch, J.; Li, D.; Li, H.; Li, L.; Li, Q. Z.; Lim, J. K.; Lincoln, D.; Linnemann, J.; Lipaev, V. V.; Lipton, R.; Liu, H.; Liu, Y.; Lobodenko, A.; Lokajicek, M.; Lopes de Sa, R.; Luna-Garcia, R.; Lyon, A. L.; Maciel, A. K. A.; Madar, R.; Magaña-Villalba, R.; Malik, S.; Malyshev, V. L.; Mansour, J.; Martínez-Ortega, J.; McCarthy, R.; McGivern, C. L.; Meijer, M. M.; Melnitchouk, A.; Menezes, D.; Mercadante, P. G.; Merkin, M.; Meyer, A.; Meyer, J.; Miconi, F.; Mondal, N. K.; Mulhearn, M.; Nagy, E.; Narain, M.; Nayyar, R.; Neal, H. A.; Negret, J. P.; Neustroev, P.; Nguyen, H. T.; Nunnemann, T.; Orduna, J.; Osman, N.; Osta, J.; Pal, A.; Parashar, N.; Parihar, V.; Park, S. K.; Partridge, R.; Parua, N.; Patwa, A.; Penning, B.; Perfilov, M.; Peters, Y.; Petridis, K.; Petrillo, G.; Pétroff, P.; Pleier, M. -A.; Podstavkov, V. M.; Popov, A. V.; Prewitt, M.; Price, D.; Prokopenko, N.; Qian, J.; Quadt, A.; Quinn, B.; Ratoff, P. N.; Razumov, I.; Ripp-Baudot, I.; Rizatdinova, F.; Rominsky, M.; Ross, A.; Royon, C.; Rubinov, P.; Ruchti, R.; Sajot, G.; Sánchez-Hernández, A.; Sanders, M. P.; Santos, A. S.; Savage, G.; Savitskyi, M.; Sawyer, L.; Scanlon, T.; Schamberger, R. D.; Scheglov, Y.; Schellman, H.; Schott, M.; Schwanenberger, C.; Schwienhorst, R.; Sekaric, J.; Severini, H.; Shabalina, E.; Shary, V.; Shaw, S.; Shchukin, A. A.; Simak, V.; Skubic, P.; Slattery, P.; Smirnov, D.; Snow, G. R.; Snow, J.; Snyder, S.; Söldner-Rembold, S.; Sonnenschein, L.; Soustruznik, K.; Stark, J.; Stoyanova, D. A.; Strauss, M.; Suter, L.; Svoisky, P.; Titov, M.; Tokmenin, V. V.; Tsai, Y. -T.; Tsybychev, D.; Tuchming, B.; Tully, C.; Uvarov, L.; Uvarov, S.; Uzunyan, S.; Van Kooten, R.; van Leeuwen, W. M.; Varelas, N.; Varnes, E. W.; Vasilyev, I. A.; Verkheev, A. Y.; Vertogradov, L. S.; Verzocchi, M.; Vesterinen, M.; Vilanova, D.; Vokac, P.; Wahl, H. D.; Wang, M. H. L. S.; Warchol, J.; Watts, G.; Wayne, M.; Weichert, J.; Welty-Rieger, L.; Williams, M. R. J.; Wilson, G. W.; Wobisch, M.; Wood, D. R.; Wyatt, T. R.; Xie, Y.; Yamada, R.; Yang, S.; Yasuda, T.; Yatsunenko, Y. A.; Ye, W.; Ye, Z.; Yin, H.; Yip, K.; Youn, S. W.; Yu, J. M.; Zennamo, J.; Zhao, T. G.; Zhou, B.; Zhu, J.; Zielinski, M.; Zieminska, D.; Zivkovic, L.

    2015-09-01

    We present a simultaneous measurement of the forward-backward asymmetry and the top-quark polarization in tt¯ production in dilepton final states using 9.7 fb-1 of proton-antiproton collisions at √s=1.96 TeV with the D0 detector. To reconstruct the distributions of kinematic observables we employ a matrix element technique that calculates the likelihood of the possible tt¯ kinematic configurations. After accounting for the presence of background events and for calibration effects, we obtain a forward-backward asymmetry of Att¯=(15.0±6.4(stat)±4.9(syst))% and a top-quark polarization times spin analyzing power in the beam basis of κP=(7.2±10.5(stat)±4.2(syst))%, with a correlation of -56% between the measurements. If we constrain the forward-backward asymmetry to its expected standard model value, we obtain a measurement of the top polarization ofκP=(11.3±9.1(stat)±1.9(syst))%. If we constrain the top polarization to its expected standard model value, we measure a forward-backward asymmetry of Att¯=(17.5±5.6(stat)±3.1(syst))%. A combination with the D0 Att¯ measurement in the lepton+jets final state yields an asymmetry of Att¯=(11.8±2.5(stat)±1.3(syst))%. Within their respective uncertainties, all these results are consistent with the standard model expectations.

  19. MoS{sub 2} nanotube exfoliation as new synthesis pathway to molybdenum blue

    SciTech Connect (OSTI)

    Visic, B.; Gunde, M. Klanjsek; Kovac, J.; Iskra, I.; Jelenc, J.; Remskar, M.; Centre of Excellence Namaste, Jamova cesta 39, SI-1000 Ljubljana

    2013-02-15

    Graphical abstract: . Display Omitted Highlights: ? New synthesis approach to obtaining molybdenum blue via exfoliated MoS{sub 2} nanotubes. ? Material is prone to self assembly and is stable in high vacuum. ? Molecules are as small as 2 nm and their clusters are up to tens of nanometers. ? Change in absorption and oxidation states from the precursor MoS{sub 2}. -- Abstract: Molybdenum blue-type materials are usually obtained by partially reducing Mo{sup VI+} in acidic solutions, while in the presented method it is formed in ethanol solution of exfoliated MoS{sub 2} nanotubes, where the MoS{sub 2} flakes are the preferential location for their growth. Material was investigated by means of scanning electron and atomic force microscopy, showing the structure and self assembly, while also confirming that it is stable in high vacuum with molecules as small as 1.6 nm and the agglomerates of few tens of nanometres. The ultravioletvisible and photoelectron spectrometry show the change in absorption properties and oxidation states from MoS{sub 2} structure to molybdenum blue, while the presence of sulphur suggests that this is a new type of molybdenum blue material.

  20. Emergence of coherence in the charge-density wave state of 2H-NbSe2

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Chatterjee, U.; Zhao, J.; Iavarone, M.; Di Capua, R.; Castellan, J. P.; Karapetrov, G.; Malliakas, C. D.; Kanatzidis, M. G.; Claus, H.; Ruff, J. P. C.; et al

    2015-02-17

    A charge-density wave (CDW) state has a broken symmetry described by a complex order parameter with an amplitude and a phase. The conventional view, based on clean, weak-coupling systems, is that a finite amplitude and long-range phase coherence set in simultaneously at the CDW transition temperature Tcdw. Here we investigate, using photoemission, X-ray scattering and scanning tunnelling microscopy, the canonical CDW compound 2H-NbSe2 intercalated with Mn and Co, and show that the conventional view is untenable. We find that, either at high temperature or at large intercalation, CDW order becomes short-ranged with a well-defined amplitude, which has impacts on themoreelectronic dispersion, giving rise to an energy gap. The phase transition at Tcdw marks the onset of long-range order with global phase coherence, leading to sharp electronic excitations. Our observations emphasize the importance of phase fluctuations in strongly coupled CDW systems and provide insights into the significance of phase incoherence in pseudogap states.less

  1. Emergence of coherence in the charge-density wave state of 2H-NbSe2

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Chatterjee, U.; Zhao, J.; Iavarone, M.; Di Capua, R.; Castellan, J. P.; Karapetrov, G.; Malliakas, C. D.; Kanatzidis, M. G.; Claus, H.; Ruff, J. P. C.; et al

    2015-02-17

    A charge-density wave (CDW) state has a broken symmetry described by a complex order parameter with an amplitude and a phase. The conventional view, based on clean, weak-coupling systems, is that a finite amplitude and long-range phase coherence set in simultaneously at the CDW transition temperature Tcdw. Here we investigate, using photoemission, X-ray scattering and scanning tunnelling microscopy, the canonical CDW compound 2H-NbSe2 intercalated with Mn and Co, and show that the conventional view is untenable. We find that, either at high temperature or at large intercalation, CDW order becomes short-ranged with a well-defined amplitude, which has impacts on themore » electronic dispersion, giving rise to an energy gap. The phase transition at Tcdw marks the onset of long-range order with global phase coherence, leading to sharp electronic excitations. As a result, our observations emphasize the importance of phase fluctuations in strongly coupled CDW systems and provide insights into the significance of phase incoherence in ‘pseudogap’ states.« less

  2. Thermophysical Properties of U-10MO Alloy

    SciTech Connect (OSTI)

    A. M. Phillips; G. S. Mickum; D. E. Burkes

    2010-11-01

    This report provides an overview of thermophysical properties of unirradiated uranium alloyed with ten weight percent molybdenum (U 10Mo), with particular focus on those material properties needed for modeling of new fuels for HPRRs (High Performance Research Reactors). The report contains both historical data available in the literature on U-10Mo, as well as more recent results conducted by the Global Threat Reduction Initiative fuel development program. The main use of the report is intended as a standard U-10Mo alloy properties reference for reactor models and simulations.

  3. Mo Year Report Period: EIA ID NUMBER:

    U.S. Energy Information Administration (EIA) Indexed Site

    Mo Year Report Period: EIA ID NUMBER: http:www.eia.govsurveyformeia14instructions.pdf Mailing Address: Secure File Transfer option available at: (e.g., PO Box, RR) https:...

  4. Release on M&O Selection Final

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Federal Services LLC, of Bethesda, Maryland) has been awarded a 1.3 billion contract for management and operating (M&O) at DOE's Waste Isolation Pilot Plant (WIPP) in Carlsbad,...

  5. Investigations of 2? decay measured by low background HPGe spectrometer OBELIX

    SciTech Connect (OSTI)

    Rukhadze, Ekaterina [Institute of Experimental and Applied Physics, CTU in Prague, Horska 3a Collaboration: OBELIX Collaboration; SuperNEMO Collaboration

    2013-12-30

    A low background high sensitive HPGe spectrometer OBELIX was installed at the Modane Underground Laboratory (LSM, France, 4800 m w.e.). The detector was designed to measure a contamination of enriched isotopes and radio-impurities in construction materials, to investigate rare nuclear processes such as resonance neutrinoless double electron capture and two-neutrino double beta decay to excited states of daughter nuclei. Spectrometer sensitivity, contamination of NEMO-3 sources and results of 2?2?{sup ?} decay of {sup 100}Mo to the 0{sup +} (1130 keV) and 2{sup +} (540 keV) excited states as well as future plans for OBELIX detector are given.

  6. Elevated Temperature Tensile Tests on DU–10Mo Rolled Foils

    SciTech Connect (OSTI)

    Schulthess, Jason

    2014-09-01

    Tensile mechanical properties for uranium-10 wt.% molybdenum (U–10Mo) foils are required to support modeling and qualification of new monolithic fuel plate designs. It is expected that depleted uranium-10 wt% Mo (DU–10Mo) mechanical behavior is representative of the low enriched U–10Mo to be used in the actual fuel plates, therefore DU-10Mo was studied to simplify material processing, handling, and testing requirements. In this report, tensile testing of DU-10Mo fuel foils prepared using four different thermomechanical processing treatments were conducted to assess the impact of foil fabrication history on resultant tensile properties.

  7. Oxidation, Reduction, and Condensation of Alcohols over (MO3)3 (M=Mo, W) Nanoclusters

    SciTech Connect (OSTI)

    Fang, Zongtang; Li, Zhenjun; Kelley, Matthew S.; Kay, Bruce D.; Li, Shenggang; Hennigan, Jamie M.; Rousseau, Roger J.; Dohnalek, Zdenek; Dixon, David A.

    2014-10-02

    The reactions of deuterated methanol, ethanol, 1-propanol, 1-butanol, 2-propanol, 2-butanol and t-butanol over cyclic (MO3)3 (M = Mo, W) clusters were studied experimentally with temperature programmed desorption (TPD) and theoretically with coupled cluster CCSD(T) theory and density functional theory. The reactions of two alcohols per M3O9 cluster are required to provide agreement with experiment for D2O release, dehydrogenation and dehydration. The reaction begins with the elimination of water by proton transfers and forms an intermediate dialkoxy species which can undergo further reaction. Dehydration proceeds by a ? hydrogen transfer to a terminal M=O. Dehydrogenation takes place via an ? hydrogen transfer to an adjacent MoVI = O atom or a WVI metal center with redox involved for M = Mo and no redox for M = W. The two channels have comparable activation energies. H/D exchange to produce alcohols can take place after olefin is released or via the dialkoxy species depending on the alcohol and the cluster. The Lewis acidity of the metal center with WVI being larger than MoVI results in the increased reactivity of W3O9 over Mo3O9 for dehydrogenation and dehydration.

  8. MCNPX-CINDER'90 Simulation of Photonuclear Mo-99 Production Experiments

    SciTech Connect (OSTI)

    Kelsey, Charles T. IV [Los Alamos National Laboratory; Chemerizov, Sergey D. [Argonne National Laboratory; Dale, Gregory E. [Los Alamos National Laboratory; Harvey, James T. [NorthStar Medical Radioisotopes; Tkac, Peter [Argonne National Laboratory; Vandegrift, George R III [Argonne National Laboratory

    2011-01-01

    The MCNPX and CINDER'90 codes were used to support design of experiments investigating Mo-99 production with a 20-MeV electron beam. Bremsstrahlung photons produced by the electron beam interacting with the target drive the desired Mo-100({gamma},n)Mo-99 reaction, as well as many undesired reactions important to accurate prediction of radiation hazards. MCNPX is a radiation transport code and CINDER'90 is a transmutation code. They are routinely used together for accelerator activation calculations. Low energy neutron fluxes and production rates for nonneutron and high energy neutron induced reactions computed using MCNPX are inputs to CINDER'90. CINDER'90 presently has only a neutron reaction cross section library up to 25 MeV and normally the other reaction rates come from MCNPX physics models. For this work MCNPX photon flux tallies modified by energy response functions prepared from evaluated photonuclear cross section data were used to tally the reaction rates for CINDER'90 input. The cross section evaluations do not provide isomer to ground state yield ratios so a spin based approximation was used. Post irradiation dose rates were calculated using MCNPX with CINDER'90 produced decay photon spectra. The sensitivity of radionuclide activities and dose rates to beam parameters including energy, position, and profile, as well as underlying isomer assumptions, was investigated. Three experimental production targets were irradiated, two natural Mo and one Mo-100 enriched. Natural Mo foils upstream of the targets were used to analyze beam position and profile by exposing Gafchromic film to the foils after each irradiation. Activation and dose rate calculations were rerun after the experiments using measured beam parameters for comparison with measured Mo-99 activities and dose rates.

  9. DOE - Office of Legacy Management -- Rogers Iron Works Co - MO...

    Office of Legacy Management (LM)

    of Ohio Analytical Data Sheet 9908; August 2, 1956 MO.10-2 - MemorandumChecklist, Williams to File; Subject: Rogers Iron; June 1, 1990 MO.10-3 - DOE Memorandum; Williams to the...

  10. DOE - Office of Legacy Management -- Latty Avenue Site - MO 04

    Office of Legacy Management (LM)

    MO.04-1 - DOE Letter; Keller to Jarboe; Subject: Agreement for Use of Property at 9200 Latty Avenue, Hazelwood, Missouri; November 22, 1983 MO.04-10 - DOE Report (ORNLRASA-857); ...

  11. Accelerator Production Options for 99MO

    SciTech Connect (OSTI)

    Bertsche, Kirk; /SLAC

    2010-08-25

    Shortages of {sup 99}Mo, the most commonly used diagnostic medical isotope, have caused great concern and have prompted numerous suggestions for alternate production methods. A wide variety of accelerator-based approaches have been suggested. In this paper we survey and compare the various accelerator-based approaches.

  12. MOED_of_the_Italian_Republic.PDF | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    MOED_of_the_Italian_Republic.PDF MOED_of_the_Italian_Republic.PDF PDF icon MOED_of_the_Italian_Republic.PDF More Documents & Publications Scanned_Agreement.pdf International_Agreements_January_2001_December_2004.pdf Implementing Arrangement Between DOE and METI on R&D Cooperation on Clean Energy Technology - April 2015

  13. STATE OF MISSOURI DEPARTMENT OF NATURAL RESOURCES MISSOURI CLEAN WATER COMMISSION

    National Nuclear Security Administration (NNSA)

    STATE OF MISSOURI DEPARTMENT OF NATURAL RESOURCES MISSOURI CLEAN WATER COMMISSION MISSOURI STATE OPERATING PERMIT In compliance with the Missouri Clean Water Law, (Chapter 644 R.S. Mo. as amended, hereinafter, the Law), and the Federal Water Pollution Control Act (Public Law 92-500, 92 nd Congress) as amended, Permit No.: MO-0004863 Owner: United States Department of Energy (USDOE) Address: P.O. Box 410202, Kansas City, MO 64141-0202 Continuing Authority: United States Department of Energy

  14. United States Government

    Office of Legacy Management (LM)

    DOEF1325.8 P4 0 * 1 - 1 - Iq \ b- United States Government memorandum pJ .T\ \b Department of Energy DATE: OCT 9 1984 REPLY TO NE-20 All-N OF: .- Authorizations for Actions Under the Formerly Utilized Sites Remedial Action SUBJECT: Program (FUSRAP) at the St. Louis Airport Storage Site, St. Louis, MO. and the W. R. Grace Site at Curtis Bay, Md. To: J. LaGrone, Manager Oak Ridge Operations Office St. Louis Airport Storage Site, MO The House and Senate Reports for the Energy and Water Development

  15. Mo-99 | National Nuclear Security Administration

    National Nuclear Security Administration (NNSA)

    Mo-99 DOE/NNSA Successfully Establishes Uranium Lease and Takeback Program to Support Critical Medical Isotope Production In January 2016, the U.S. Department of Energy's National Nuclear Security Administration (DOE/NNSA) successfully established the Uranium Lease and Take-Back (ULTB) program, as directed in the American Medical Isotopes Production Act of 2012, to support the commercial production of the medical... NNSA's work aids in fight against cancer World Cancer Day encourages citizens

  16. Preparation and structural study from neutron diffraction data of Pr{sub 5}Mo{sub 3}O{sub 16}

    SciTech Connect (OSTI)

    Martinez-Lope, M.J.; Alonso, J.A.; Sheptyakov, D.; Pomjakushin, V.

    2010-12-15

    The title compound has been prepared as polycrystalline powder by thermal treatments of mixtures of Pr{sub 6}O{sub 11} and MoO{sub 2} in air. In the literature, an oxide with a composition Pr{sub 2}MoO{sub 6} has been formerly described to present interesting catalytic properties, but its true stoichiometry and crystal structure are reported here for the first time. It is cubic, isostructural with CdTm{sub 4}Mo{sub 3}O{sub 16} (space group Pn-3n, Z=8), with a=11.0897(1) A. The structure contains MoO{sub 4} tetrahedral units, with Mo-O distances of 1.788(2) A, fully long-range ordered with PrO{sub 8} polyhedra; in fact it can be considered as a superstructure of fluorite (M{sub 8}O{sub 16}), containing 32 MO{sub 2} fluorite formulae per unit cell, with a lattice parameter related to that of cubic fluorite (a{sub f}=5.5 A) as a{approx}2a{sub f}. A bond valence study indicates that Mo exhibits a mixed oxidation state between 5+ and 6+ (perhaps accounting for the excellent catalytic properties). One kind of Pr atoms is trivalent whereas the second presents a mixed Pr{sup 3+}-Pr{sup 4+} oxidation state. The similarity of the XRD pattern with that published for Ce{sub 2}MoO{sub 6} suggests that this compound also belongs to the same structural type, with an actual stoichiometry Ce{sub 5}Mo{sub 3}O{sub 16}. -- Graphical Abstract: Formerly formulated as Pr{sub 2}MoO{sub 6}, the title compound is a cubic superstructure of fluorite (a=11.0897(1) A, space group Pn-3n) due to the long-range ordering of PrO{sub 8} scalenohedra and MoO{sub 4} tetrahedral units, showing noticeable shifts of the oxygen positions in order to provide a tetrahedral coordination for Mo ions. A mixed valence Mo{sup 5+}-Mo{sup 6+} is identified, which could account for the excellent catalytic properties of this material. Display Omitted

  17. Electrical properties of a-C:Mo films produced by dual-cathode filtered cathodic arc plasma deposition

    SciTech Connect (OSTI)

    Sansongsiri, Sakon; Anders, Andre; Yodsombat, Banchob

    2008-01-20

    Molybdenum-containing amorphous carbon (a-C:Mo) thin films were prepared using a dual-cathode filtered cathodic arc plasma source with a molybdenum and a carbon (graphite) cathode. The Mo content in the films was controlled by varying the deposition pulse ratio of Mo and C. Film sheet resistance was measured in situ at process temperature, which was close to room temperature, as well as ex situ as a function of temperature (300-515 K) in ambient air. Film resistivity and electrical activation energy were derived for different Mo and C ratios and substrate bias. Film thickness was in the range 8-28 nm. Film resistivity varied from 3.55x10-4 Omega m to 2.27x10-6 Omega m when the Mo/C pulse ratio was increased from 0.05 to 0.4, with no substrate bias applied. With carbon-selective bias, the film resistivity was in the range of 4.59x10-2 and 4.05 Omega m at a Mo/C pulse ratio of 0.05. The electrical activation energy decreased from 3.80x10-2 to 3.36x10-4 eV when the Mo/C pulse ratio was increased in the absence of bias, and from 0.19 to 0.14 eV for carbon-selective bias conditions. The resistivity of the film shifts systematically with the amounts of Mo and upon application of substrate bias voltage. The intensity ratio of the Raman D-peak and G-peak (ID/IG) correlated with the pre-exponential factor (sigma 0) which included charge carrier density and density of states.

  18. Novel Processing of mo-si-b Intermetallics for improved efficiency of power systems

    SciTech Connect (OSTI)

    M.J. Kramer; O. Degirmen; A.J. Thom; M. Akinc

    2004-09-30

    Multiphase composite alloys based on the Mo-Si-B system are candidate materials for ultra-high temperature applications. In non load-bearing applications such as thermal barrier coatings or heat exchangers in fossil fuel burners, these materials may be ideally suited. Alloys based on the Mo{sub 5}Si{sub 3}B{sub x} phase (Tl phase) possess excellent oxidation resistance to at least 1600 C in synthetic air atmospheres. However, the ability of Tl-based alloys to resist aggressive combustion environments has not yet been determined. The present work seeks to investigate the resistance of these Mo-Si-B alloys to simulated combustion atmospheres. Material was pre-alloyed by combustion synthesis, and samples for testing were prepared by classic powder metallurgical processing techniques. Precursor material synthesized by self-heating-synthesis was sintered to densities exceeding 98% in an argon atmosphere at 1800 C. The approximate phase assemblage of the material was 57% Tl, 29% MoB, 14% MoSi{sub 2} (wt%). The alloy was oxidized from 1000-1100 C in flowing air containing water vapor at 18 Torr. At 1000 C the material achieved a steady state mass loss, and at 1100 C the material undergoes a steady state mass gain. The oxidation rate of these alloys in this temperature regime was accelerated by the presence of water vapor compared to oxidation in dry air. The results of microstructural analysis of the tested alloys will be discussed. Techniques and preliminary results for fabricating near-net-shaped parts will also be presented.

  19. Ferromagnetic superexchange in insulating Cr2MoO6 by controlling orbital hybridization

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhu, M.; Do, D.; Dela Cruz, Clarina R.; Dun, Zhiling; Cheng, J. -G.; Goto, H.; Uwatoko, Yoshiya; Zou, T.; Zhou, Haidon D.; Mahanti, Subhendra D.; et al

    2015-09-11

    We report the magnetic and electronic structures of the newly synthesized inverse-trirutile compound Cr2MoO6. Despite the same crystal symmetry and similar bond-lengths and bond-angles to Cr2TeO6, Cr2MoO6 possesses a magnetic structure of the Cr2MoO6 type, different from that seen in Cr2TeO6. Ab-initio electronic structure calculations show that the sign and strength of the Cr-O-Cr exchange coupling is strongly influenced by the hybridization between Mo 4d and O 2p orbitals. This result further substantiates our recently proposed mechanism for tuning the exchange interaction between two magnetic atoms by modifying the electronic states of the non-magnetic atoms in the exchange path throughmore » orbital hybridization. This approach is fundamentally different from the conventional methods of controlling the exchange interaction by either carrier injection or through structural distortions.« less

  20. Chemical isolation of .sup.82 Sr from proton-irradiated Mo targets

    DOE Patents [OSTI]

    Grant, Patrick M.; Kahn, Milton; O'Brien, Jr., Harold A.

    1976-01-01

    Spallation reactions are induced in Mo targets with 200-800 MeV protons to produce microcurie to millicurie amounts of a variety of radionuclides. A six-step radiochemical procedure, incorporating precipitation, solvent extractions, and ion exchange techniques, has been developed for the separation and purification of Sr radioactivities from other spallation products and the bulk target material. Radiostrontium can be quantitatively recovered in a sufficiently decontaminated state for use in biomedical generator development.

  1. NNSA Awards Mo-99 Cooperative Agreement to General Atomics | National

    National Nuclear Security Administration (NNSA)

    Nuclear Security Administration Library / Press Releases NNSA Awards Mo-99 Cooperative Agreement to General Atomics September 30, 2015 WASHINGTON, DC - Today, the Department of Energy's National Nuclear Security Administration (DOE/NNSA) announced that it will award a cooperative agreement to General Atomics (GA) to support its project for domestic production of molybdenum-99 (Mo-99) without highly enriched uranium (HEU). Mo-99 is the parent isotope of technetium-99m, which is the most

  2. MoRu/Be multilayers for extreme ultraviolet applications

    DOE Patents [OSTI]

    Bajt, Sasa C.; Wall, Mark A.

    2001-01-01

    High reflectance, low intrinsic roughness and low stress multilayer systems for extreme ultraviolet (EUV) lithography comprise amorphous layers MoRu and crystalline Be layers. Reflectance greater than 70% has been demonstrated for MoRu/Be multilayers with 50 bilayer pairs. Optical throughput of MoRu/Be multilayers can be 30-40% higher than that of Mo/Be multilayer coatings. The throughput can be improved using a diffusion barrier to make sharper interfaces. A capping layer on the top surface of the multilayer improves the long-term reflectance and EUV radiation stability of the multilayer by forming a very thin native oxide that is water resistant.

  3. DOE - Office of Legacy Management -- Petrolite Corp - MO 08

    Office of Legacy Management (LM)

    Materials Handled: Yes Primary Radioactive Materials Handled: Uranium Flouride & Thorium Oxide MO.08-2 Radiological Survey(s): None Indicated Site Status: Eliminated from ...

  4. Microsoft Word - chapter FeCrMo_ver2.doc

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Low-Alloy Ferritic Steels Fe-Cr-Mo Tempered December 8, 2005 ... strength level, material processing, and heat treatment 1. ... yield strength, hydrogen gas pressure, and temperature. ...

  5. Demonstration of LED Street Lighting in Kansas City, MO Kinzey...

    Office of Scientific and Technical Information (OSTI)

    Street Lighting in Kansas City, MO Kinzey, Bruce R.; Royer, Michael P.; Hadjian, M.; Kauffman, Rick LED streetlighting; field illuminance measurement LED streetlighting; field...

  6. Predicting sigma formation in mo-bearing stainless steels. (Conference...

    Office of Scientific and Technical Information (OSTI)

    Title: Predicting sigma formation in mo-bearing stainless steels. No abstract prepared. Authors: Perricone, Matthew ; Dupont, John Neuman ; Anderson, T. D. 1 ; Robino, Charles ...

  7. Fragile structural transition in Mo3Sb7

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yan, Jiaqiang -Q.; McGuire, Michael A; May, Andrew F; Parker, David S.; Mandrus, D. G.; Sales, Brian C.

    2015-01-01

    Mo3Sb7 single crystals lightly doped with Cr, Ru, or Te are studied in order to explore the interplay between superconductivity, magnetism, and the cubic-tetragonal structural transition. The structural transition at 53 K is extremely sensitive to Ru or Te substitution which introduces additional electrons, but robust against Cr substitution. We observed no sign of a structural transition in superconducting Mo2.91Ru0.09Sb7 and Mo3Sb6.975Te0.025. In contrast, 3 at.% Cr doping only slightly suppresses the structural transition to 48 K while leaving no trace of superconductivity above 1.8 K. Analysis of magnetic properties suggests that the interdimer interaction in Mo3Sb7 is near amore » critical value and essential for the structural transition. Futhermore, all dopants suppress the superconductivity of Mo3Sb7. The tetragonal structure is not necessary for superconductivity.« less

  8. Rotationally Commensurate Growth of MoS[subscript 2] on Epitaxial...

    Office of Scientific and Technical Information (OSTI)

    Rotationally Commensurate Growth of MoSsubscript 2 on Epitaxial Graphene Citation Details In-Document Search Title: Rotationally Commensurate Growth of MoSsubscript 2 on ...

  9. Mo-O bond doping and related-defect assisted enhancement of photoluminescence in monolayer MoS{sub 2}

    SciTech Connect (OSTI)

    Wei, Xiaoxu; Yu, Zhihao; Cheng, Ying; Yu, Linwei; Wang, Junzhuan Wang, Xinran; Shi, Yi; Hu, Fengrui; Wang, Xiaoyong; Xiao, Min

    2014-12-15

    In this work, we report a strong photoluminescence (PL) enhancement of monolayer MoS{sub 2} under different treatments. We find that by simple ambient annealing treatment in the range of 200?C to 400?C, the PL emission can be greatly enhanced by a factor up to two orders of magnitude. This enhancement can be attributed to two factors: first, the formation of Mo-O bonds during ambient exposure introduces an effective p-doping in the MoS{sub 2} layer; second, localized electrons formed around Mo-O bonds related defective sites where the electrons can be effectively localized with higher binding energy resulting in efficient radiative excitons recombination. Time resolved PL decay measurement showed that longer lifetime of the treated sample consistent with the higher quantum efficiency in PL. These results give more insights to understand the luminescence properties of the MoS{sub 2}.

  10. A novel three dimensional semimetallic MoS{sub 2}

    SciTech Connect (OSTI)

    Tang, Zhen-Kun; Zhang, Hui; Liu, Li-Min; Liu, Hao; Lau, Woon-Ming

    2014-05-28

    Transition metal dichalcogenides (TMDs) have many potential applications, while the performances of TMDs are generally limited by the less surface active sites and the poor electron transport efficiency. Here, a novel three-dimensional (3D) structure of molybdenum disulfide (MoS{sub 2}) with larger surface area was proposed based on first-principle calculations. 3D layered MoS{sub 2} structure contains the basal surface and joint zone between the different nanoribbons, which is thermodynamically stable at room temperature, as confirmed by first principles molecular dynamics calculations. Compared the two-dimensional layered structures, the 3D MoS{sub 2} not only owns the large surface areas but also can effectively avoid the aggregation. Interestingly, although the basal surface remains the property of the intrinsic semiconductor as the bulk MoS{sub 2}, the joint zone of 3D MoS{sub 2} exhibits semimetallic, which is derived from degenerate 3d orbitals of the Mo atoms. The high stability, large surface area, and high conductivity make 3D MoS{sub 2} have great potentials as high performance catalyst.

  11. Polystyrene/MoS{sub 2}@oleylamine nanocomposites

    SciTech Connect (OSTI)

    Altavilla, Claudia; Ciambelli, Paolo; Fedi, Filippo; Sorrentino, Andrea; Iannace, Salvatore

    2014-05-15

    The effects of adding different concentrations of MoS{sub 2}@oleylamine nano particles on the thermal and mechanical properties of polystyrene (PS) nanocomposites have been investigated. X-ray diffraction and optical microscopy were used to characterize the morphology of the resulting nanocomposites. The thermal stability of the nanocomposites has been characterized by thermogravimetric analysis. It has been found that the MoS{sub 2}@oleylamine nanoparticles have a good compatibility with the PS matrix forming homogeneous dispersion even at high concentrations. The PS/MoS{sub 2}@oleylamine nanocomposites showed enhanced thermal stability in comparison with neat polystyrene.

  12. Slow Mo Guys and Cold Spray | GE Global Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Slow Mo Guys and Cold Spray Click to email this to a friend (Opens in new window) Share on Facebook (Opens in new window) Click to share (Opens in new window) Click to share on LinkedIn (Opens in new window) Click to share on Tumblr (Opens in new window) Slow Mo Guys and Cold Spray ) The Slow Mo Guys came to GE Global Research in Niskayuna to film our researchers demonstrate a process called "cold spray", in which metal powders are sprayed at high velocities to build a part or add

  13. Diffusion Barrier Selection from Refractory Metals (Zr, Mo and Nb) via Interdiffusion Investigation for U-Mo RERTR Fuel Alloy

    SciTech Connect (OSTI)

    K. Huang; C. Kammerer; D. D. Keiser, Jr.; Y. H. Sohn

    2014-04-01

    U-Mo alloys are being developed as low enrichment monolithic fuel under the Reduced Enrichment for Research and Test Reactor (RERTR) Program. Diffusional interactions between the U-Mo fuel alloy and Al-alloy cladding within the monolithic fuel plate construct necessitate incorporation of a barrier layer. Fundamentally, a diffusion barrier candidate must have good thermal conductivity, high melting point, minimal metallurgical interaction, and good irradiation performance. Refractory metals, Zr, Mo, and Nb are considered based on their physical properties, and the diffusion behavior must be carefully examined first with U-Mo fuel alloy. Solid-to-solid U-10wt.%Mo vs. Mo, Zr, or Nb diffusion couples were assembled and annealed at 600, 700, 800, 900 and 1000 degrees C for various times. The interdiffusion microstructures and chemical composition were examined via scanning electron microscopy and electron probe microanalysis, respectively. For all three systems, the growth rate of interdiffusion zone were calculated at 1000, 900 and 800 degrees C under the assumption of parabolic growth, and calculated for lower temperature of 700, 600 and 500 degrees C according to Arrhenius relationship. The growth rate was determined to be about 10 3 times slower for Zr, 10 5 times slower for Mo and 10 6 times slower for Nb, than the growth rates reported for the interaction between the U-Mo fuel alloy and pure Al or Al-Si cladding alloys. Zr, however was selected as the barrier metal due to a concern for thermo- mechanical behavior of UMo/Nb interface observed from diffusion couples, and for ductile-to-brittle transition of Mo near room temperature.

  14. Imaging findings and pharmacokinetics of 111-indium ZME-018 monoclonal antibody (MoAb) in malignant melanoma

    SciTech Connect (OSTI)

    Murray, J.L.; Rosenblum, M.; Lamki, L.; Haynie, T.P.; Glenn, H.; Jahns, M.; Plager, C.; Hersh, E.M.; Unger, M.; Carlo, D.L.

    1985-05-01

    13 patients with metastatic melanoma were studied using 5 mCi of In-111 labeled MoAb ZME-018 which reacts with GP 240 melanoma-associated antigen. The MoAb was infused over 2 h at doses of 2.5 mg (5 pts), 5 mg (5 pts), and 10 mg (3 pts). Total body tomograms and planar spot views with region of interest analysis were performed at 4, 24 and 72 hours post infusion. No adverse side effects were noted. There was rapid distribution to spleen, bone, bone marrow, liver, and testes. Tumor sites could be visualized as early as 24 hours but were more easily seen at 72 hours when the background activity was less. 20 of 46 (43%) previously documented metastases were identified. More sites imaged with increasing concentrations of MoAB, I.E., 25% at 2.5 mg; 67% at 5 mg; 70% at 10 mg. Tumor localization occurred in a significant number of patients especially at MoAb doses above 2.5 mg. In two instances, uptake of 111-In occurred in previously undiagnosed sites. The pharmacokinetics of MoAb were analyzed at each dose level. At the 5 mg dose, the terminal phase half-life for 111-In in plasma was 24.5 +- 2.7 hours. The apparent volume of distribution (Vd) was 4.03 +- 5iota similar to the plasma value, and the calculated clearance rate for 111-In label was 0.0259 + 0.002 ml/kg/min. Mean urinary excretion of 111-In label was 8.7 +- 0.6% of the administered dose over 48 hours after administration. The calculated pharmacokinetic parameters were independent of antibody dose. ZME 018 was cleared more rapidly from plasma, compared to previous studies with P97 antimelanoma MoAb.

  15. M.O. Wascko, LSU NuInt05...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    O. Wascko, LSU NuInt05 26 September, 2005 MiniBooNE CC + CCQE Ratio M.O. Wascko, LSU J.R. Monroe, Columbia CC interactions Quasi-Elastic (CCQE) Inclusive Single +...

  16. 9 Cr-- 1 Mo steel material for high temperature application

    DOE Patents [OSTI]

    Jablonski, Paul D; Alman, David; Dogan, Omer; Holcomb, Gordon; Cowen, Christopher

    2012-11-27

    One or more embodiments relates to a high-temperature, titanium alloyed, 9 Cr-1 Mo steel exhibiting improved creep strength and oxidation resistance at service temperatures up to 650.degree. C. The 9 Cr-1 Mo steel has a tempered martensite microstructure and is comprised of both large (0.5-3 .mu.m) primary titanium carbides and small (5-50 nm) secondary titanium carbides in a ratio of. from about 1:1.5 to about 1.5:1. The 9 Cr-1 Mo steel may be fabricated using exemplary austenizing, rapid cooling, and tempering steps without subsequent hot working requirements. The 9 Cr-1 Mo steel exhibits improvements in total mass gain, yield strength, and time-to-rupture over ASTM P91 and ASTM P92 at the temperature and time conditions examined.

  17. Structural Insights into FeMo Cofactor Biosynthesis

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    a catalytic component and a specific reductase, which, in the standard system, are referred to as the MoFe protein and the Fe protein. At the active site of the...

  18. CO2ReMoVe | Open Energy Information

    Open Energy Info (EERE)

    of industrial, research and service organizations with experience in CO2 geological storage. References: CO2ReMoVe1 This article is a stub. You can help OpenEI by expanding...

  19. Co-Mo Electric Cooperative- Energy Efficiency Rebate Program

    Broader source: Energy.gov [DOE]

    Co-Mo Electric Cooperative provides rebates to its residential and commercial members who install air source, dual fuel, and/or geothermal heat pumps, and certain energy efficient appliances. Heat...

  20. Support effects on hydrotreating activity of NiMo catalysts

    SciTech Connect (OSTI)

    Dominguez-Crespo, M.A. Arce-Estrada, E.M.; Torres-Huerta, A.M.

    2007-10-15

    The effect of the gamma alumina particle size on the catalytic activity of NiMoS{sub x} catalysts prepared by precipitation method of aluminum acetate at pH = 10 was studied. The structural characterization of the supports was measured by using XRD, pyridine FTIR-TPD and nitrogen physisorption. NiMo catalysts were characterized during the preparation steps (annealing and sulfidation) using transmission electron microscopy (TEM). Hydrogen TPR studies of the NiMo catalysts were also carried out in order to correlate their hydrogenating properties and their catalytic functionality. Catalytic tests were carried out in a pilot plant at 613, 633 and 653 K temperatures. The results showed that the rate constants of hydrodesulfurization (HDS), hydrodenitrogenation (HDN) and hydrodearomatizing (HDA) at 613-653 K decreased in the following order: A > B > C corresponding to the increase of NiMoS particle size associated to these catalysts.

  1. Ethanol Conversion on Cyclic (MO3)3 (M = Mo, W) Clusters

    SciTech Connect (OSTI)

    Li, Zhenjun; Fang, Zongtang; Kelley, Matthew S.; Kay, Bruce D.; Rousseau, Roger J.; Dohnalek, Zdenek; Dixon, David A.

    2014-03-06

    Oxides of molybdenum and tungsten are an important class of catalytic materials with applications ranging from isomerization of alkanes and alkenes, partial oxidation of alcohols, selective reduction of nitric oxide and metathesis of alkeness.[1-10] While many studies have focused on the structure - function relationships, the nature of high catalytic activity is still being extensively investigated. There is a general agreement that the activity of supported MOx (M = W, Mo) catalysts is correlated with the presence of acidic sites, where the catalytic activity is strongly affected by the type of oxide support, delocalization of electron density, structures of tungsten oxide domains and presence of protons

  2. Microstructures in rapidly solidified Ni-Mo alloys

    SciTech Connect (OSTI)

    Jayaraman, N.; Tewari, S.N.; Hemker, K.J.; Glasgow, T.K.

    1985-01-01

    Ni-Mo alloys of compositions ranging from pure Ni to Ni-40 at % Mo were rapidly solidified by chill block melt spinning in vacuum and were examined by optical metallography, x-ray diffraction and transmission electron microscopy. Rapid solidification resulted in an extension of molybdenum solubility in nickel from 28 to 37.5 at %. A number of different phases and microstructures were seen at different depths (solidification conditions) from the quenched surface of the melt spun ribbons.

  3. Order and disorder in the local and long-range structure of the spin-glass pyrochlore, Tb{sub 2}Mo{sub 2}O{sub 7}

    SciTech Connect (OSTI)

    Jiang, Yu; Huq, Ashfia; Booth, Corwin H.; Ehlers, Georg; Greedan, John E.; Gardner, Jason S.

    2011-02-11

    To understand the origin of the spin-glass state in molybdate pyrochlores, the structure of Tb{sub 2}Mo{sub 2}O{sub 7} is investigated using two techniques: the long-range lattice structure was measured using neutron powder diffraction (NPD), and local structure information was obtained from the extended x-ray absorption fine structure (EXAFS) technique. While the long-range structure appears generally well ordered, enhanced mean-squared site displacements on the O(1) site and the lack of temperature dependence of the strongly anisotropic displacement parameters for both the Mo and O(1) sites indicate some disorder exists. Likewise, the local structure measurements indicate some Mo-Mo and Tb-O(1) nearest-neighbor disorder exists, similar to that found in the related spin-glass pyrochlore, Y{sub 2}Mo{sub 2}O{sub 7}. Although the freezing temperature in Tb{sub 2}Mo{sub 2}O{sub 7}, 25 K, is slightly higher than in Y{sub 2}Mo{sub 2}O{sub 7}, 22 K, the degree of local pair distance disorder is actually less in Tb{sub 2}Mo{sub 2}O{sub 7}. This apparent contradiction is considered in light of the interactions involved in the freezing process.

  4. Ferromagnetic superexchange in insulating Cr2MoO6 by controlling orbital hybridization

    SciTech Connect (OSTI)

    Zhu, M.; Do, D.; Dela Cruz, Clarina R.; Dun, Zhiling; Cheng, J. -G.; Goto, H.; Uwatoko, Yoshiya; Zou, T.; Zhou, Haidon D.; Mahanti, Subhendra D.; Ke, Xianglin

    2015-09-11

    We report the magnetic and electronic structures of the newly synthesized inverse-trirutile compound Cr2MoO6. Despite the same crystal symmetry and similar bond-lengths and bond-angles to Cr2TeO6, Cr2MoO6 possesses a magnetic structure of the Cr2MoO6 type, different from that seen in Cr2TeO6. Ab-initio electronic structure calculations show that the sign and strength of the Cr-O-Cr exchange coupling is strongly influenced by the hybridization between Mo 4d and O 2p orbitals. This result further substantiates our recently proposed mechanism for tuning the exchange interaction between two magnetic atoms by modifying the electronic states of the non-magnetic atoms in the exchange path through orbital hybridization. This approach is fundamentally different from the conventional methods of controlling the exchange interaction by either carrier injection or through structural distortions.

  5. Thermomechanical process optimization of U-10wt% Mo Part 2: The effect of homogenization on the mechanical properties and microstructure

    SciTech Connect (OSTI)

    Joshi, Vineet V.; Nyberg, Eric A.; Lavender, Curt A.; Paxton, Dean M.; Burkes, Douglas E.

    2015-07-09

    Low-enriched uranium alloyed with 10 wt% molybdenum (U-10Mo) is currently being investigated as an alternative fuel for the highly enriched uranium used in several of the United States high performance research reactors. Development of the methods to fabricate the U-10Mo fuel plates is currently underway and requires fundamental understanding of the mechanical properties at the expected processing temperatures. In the first part of this series, it was determined that the as-cast U-10Mo had a dendritic microstructure with chemical inhomogeneity and underwent eutectoid transformation during hot compression testing. In the present (second) part of the work, the as-cast samples were heat treated at several temperatures and times to homogenize the Mo content. Like the previous as-cast material, the homogenized materials were then tested under compression between 500 and 800C. The as-cast samples and those treated at 800C for 24 hours had grain sizes of 25-30 ?m, whereas those treated at 1000C for 16 hours had grain sizes around 250 ?m before testing. Upon compression testing, it was determined that the heat treatment had effects on the mechanical properties and the precipitation of the lamellar phase at sub-eutectoid temperatures.

  6. Coated U(Mo) Fuel: As-Fabricated Microstructures

    SciTech Connect (OSTI)

    Emmanuel Perez; Dennis D. Keiser, Jr.; Ann Leenaers; Sven Van den Berghe; Tom Wiencek

    2014-04-01

    As part of the development of low-enriched uranium fuels, fuel plates have recently been tested in the BR-2 reactor as part of the SELENIUM experiment. These fuel plates contained fuel particles with either Si or ZrN thin film coating (up to 1 µm thickness) around the U-7Mo fuel particles. In order to best understand irradiation performance, it is important to determine the starting microstructure that can be observed in as-fabricated fuel plates. To this end, detailed microstructural characterization was performed on ZrN and Si-coated U-7Mo powder in samples taken from AA6061-clad fuel plates fabricated at 500°C. Of interest was the condition of the thin film coatings after fabrication at a relatively high temperature. Both scanning electron microscopy and transmission electron microscopy were employed. The ZrN thin film coating was observed to consist of columns comprised of very fine ZrN grains. Relatively large amounts of porosity could be found in some areas of the thin film, along with an enrichment of oxygen around each of the the ZrN columns. In the case of the pure Si thin film coating sample, a (U,Mo,Al,Si) interaction layer was observed around the U-7Mo particles. Apparently, the Si reacted with the U-7Mo and Al matrix during fuel plate fabrication at 500°C to form this layer. The microstructure of the formed layer is very similar to those that form in U-7Mo versus Al-Si alloy diffusion couples annealed at higher temperatures and as-fabricated U-7Mo dispersion fuel plates with Al-Si alloy matrix fabricated at 500°C.

  7. Ligand Bridging-Angle-Driven Assembly of Molecular Architectures Based on Quadruply Bonded Mo-Mo Dimers

    SciTech Connect (OSTI)

    Li, Jian-Rong; Yakovenko, Andrey A; Lu, Weigang; Timmons, Daren J; Zhuang, Wenjuan; Yuan, Daqiang; Zhou, Hong-Cai

    2010-12-15

    A systematic exploration of the assembly of Mo?(O?C-)?-based metalorganic molecular architectures structurally controlled by the bridging angles of rigid organic linkers has been performed. Twelve bridging dicarboxylate ligands were designed to be of different sizes with bridging angles of 0, 60, 90, and 120 while incorporating a variety of nonbridging functional groups, and these ligands were used as linkers. These dicarboxylate linkers assemble with quadruply bonded MoMo clusters acting as nodes to give 13 molecular architectures, termed metalorganic polygons/polyhedra with metal cluster node arrangements of a linear shape, triangle, octahedron, and cuboctahedron/anti-cuboctahedron. The syntheses of these complexes have been optimized and their structures determined by single-crystal X-ray diffraction. The results have shown that the shape and size of the resulting molecular architecture can be controlled by tuning the bridging angle and size of the linker, respectively. Functionalization of the linker can adjust the solubility of the ensuing molecular assembly but has little or no effect on the geometry of the product. Preliminary gas adsorption, spectroscopic, and electrochemical properties of selected members were also studied. The present work is trying to enrich metal-containing supramolecular chemistry through the inclusion of well-characterized quadruply bonded MoMo units into the structures, which can widen the prospect of additional electronic functionality, thereby leading to novel properties.

  8. The high pressure structure and equation of state of 2,6-diamino-3,5-dinitropyrazine-1-oxide (LLM-105) up to 20 GPa: X-ray diffraction measurements and first principles molecular dynamics simulations

    SciTech Connect (OSTI)

    Stavou, Elissaios; Manaa, M. Riad; Zaug, Joseph M.; Kuo, I-Feng W.; Pagoria, Philip F.; Crowhurst, Jonathan C.; Armstrong, Michael R.; Kalkan, Bora

    2015-10-14

    Recent theoretical studies of 2,6-diamino-3,5-dinitropyrazine-1-oxide (C4H4N6O5 Lawrence Livermore Molecule No. 105, LLM-105) report unreacted high pressure equations of state that include several structural phase transitions, between 8 and 50 GPa, while one published experimental study reports equation of state (EOS) data up to a pressure of 6 GPa with no observed transition. Here we report the results of a synchrotron-based X-ray diffraction study and also ambient temperature isobaric-isothermal atomistic molecular dynamics simulations of LLM-105 up to 20 GPa. We find that the ambient pressure phase remains stable up to 20 GPa; there is no indication of a pressure induced phase transition. We do find a prominent decrease in b-axis compressibility starting at approximately 13 GPa and attribute the stiffening to a critical length where inter-sheet distance becomes similar to the intermolecular distance within individual sheets. The ambient temperature isothermal equation of state was determined through refinements of measured X-ray diffraction patterns. The pressure-volume data were fit using various EOS models to yield bulk moduli with corresponding pressure derivatives. As a result, we find very good agreement between the experimental and theoretically derived EOS.

  9. The high pressure structure and equation of state of 2,6-diamino-3,5-dinitropyrazine-1-oxide (LLM-105) up to 20 GPa: X-ray diffraction measurements and first principles molecular dynamics simulations

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Stavou, Elissaios; Manaa, M. Riad; Zaug, Joseph M.; Kuo, I-Feng W.; Pagoria, Philip F.; Crowhurst, Jonathan C.; Armstrong, Michael R.; Kalkan, Bora

    2015-10-14

    Recent theoretical studies of 2,6-diamino-3,5-dinitropyrazine-1-oxide (C4H4N6O5 Lawrence Livermore Molecule No. 105, LLM-105) report unreacted high pressure equations of state that include several structural phase transitions, between 8 and 50 GPa, while one published experimental study reports equation of state (EOS) data up to a pressure of 6 GPa with no observed transition. Here we report the results of a synchrotron-based X-ray diffraction study and also ambient temperature isobaric-isothermal atomistic molecular dynamics simulations of LLM-105 up to 20 GPa. We find that the ambient pressure phase remains stable up to 20 GPa; there is no indication of a pressure induced phasemore » transition. We do find a prominent decrease in b-axis compressibility starting at approximately 13 GPa and attribute the stiffening to a critical length where inter-sheet distance becomes similar to the intermolecular distance within individual sheets. The ambient temperature isothermal equation of state was determined through refinements of measured X-ray diffraction patterns. The pressure-volume data were fit using various EOS models to yield bulk moduli with corresponding pressure derivatives. As a result, we find very good agreement between the experimental and theoretically derived EOS.« less

  10. A novel Bi-based phosphomolybdate photocatalyst K{sub 2}Bi(PO{sub 4})(MoO{sub 4}): Crystal structure, electronic structure and photocatalytic activity

    SciTech Connect (OSTI)

    Huang, Hongwei; Chen, Gong; Wang, Shuobo; Kang, Lei; Lin, Zheshuai; Zhang, Yihe

    2014-03-01

    Graphical abstract: - Highlights: A new type of phosphomolybdate K{sub 2}Bi(PO{sub 4})(MoO{sub 4}) photocatalyst was successfully synthesized. The products synthesized at 600 C were mainly composed of nano-cubes. The indirect band gap of K{sub 2}Bi(PO{sub 4})(MoO{sub 4}) has been determined to be 2.93 eV. K{sub 2}Bi(PO{sub 4})(MoO{sub 4}) synthesized at 600 C exhibits the highest photocatalytic activity. The electronic structure was calculated by density functional calculations. - Abstract: A novel phosphomolybdate photocatalyst K{sub 2}Bi(PO{sub 4})(MoO{sub 4}) has been successfully developed via a solid-state reaction. The products were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), high-resolution transmission electron microscopy (HRTEM), diffuse reflectance spectrum (DRS) and photoluminescence (PL) spectra. The photocatalytic activities of the samples prepared at different temperature were determined by the photooxidative decomposition of methylene blue (MB) in aqueous solution. The results revealed that K{sub 2}Bi(PO{sub 4})(MoO{sub 4}) can be used as an effective photocatalyst under UVvis irradiation and the nanocubes obtained at 600 C exhibits the highest photocatalytic activity. The photodegradation of MB by K{sub 2}Bi(PO{sub 4})(MoO{sub 4}) nanocrystals followed the first-order kinetics. Theoretical calculations on electronic structure confirmed the indirect optical transitions property in the absorption edge region of K{sub 2}Bi(PO{sub 4})(MoO{sub 4}), and the orbital constitutions of CB and VB were also analyzed.

  11. U-Mo Plate Blister Anneal Interim Report

    SciTech Connect (OSTI)

    Francine J. Rice; Daniel M. Wachs; Adam B. Robinson; Dennis D. Keiser Jr.; Jan-Fong Jue; Danielle M. Perez; Ross Finlay

    2010-10-01

    Blister thresholds in fuel elements have been a longstanding performance parameter for fuel elements of all types. This behavior has yet to be fully defined for the RERTR U-Mo fuel types. Blister anneal studies that began in 2007 have been expanded to include plates from more recent RERTR experiments. Preliminary data presented in this report encompasses the early generations of the U-Mo fuel systems and the most recent but still developing fuel system. Included is an overview of relevant dispersion fuel systems for the purposes of comparison.

  12. Comparative study of water reactivity with Mo{sub 2}O{sub y}{sup ?} and W{sub 2}O{sub y}{sup ?} clusters: A combined experimental and theoretical investigation

    SciTech Connect (OSTI)

    Ray, Manisha; Waller, Sarah E.; Saha, Arjun; Raghavachari, Krishnan; Jarrold, Caroline Chick

    2014-09-14

    A computational investigation of the Mo{sub 2}O{sub y}{sup ?} + H{sub 2}O (y = 4, 5) reactions as well as a photoelectron spectroscopic probe of the deuterated Mo{sub 2}O{sub 6}D{sub 2}{sup ?} product have been carried out to understand a puzzling question from a previous study: Why is the rate constant determined for the Mo{sub 2}O{sub 5}{sup ?} + H{sub 2}O/D{sub 2}O reaction, the terminal reaction in the sequential oxidation of Mo{sub 2}O{sub y}{sup ?} by water, higher than the W{sub 2}O{sub 5}{sup ?} + H{sub 2}O/D{sub 2}O reaction? This disparity was intriguing because W{sub 3}O{sub y}{sup ?} clusters were found to be more reactive toward water than their Mo{sub 3}O{sub y}{sup ?} analogs. A comparison of molecular structures reveals that the lowest energy structure of Mo{sub 2}O{sub 5}{sup ?} provides a less hindered water addition site than the W{sub 2}O{sub 5}{sup ?} ground state structure. Several modes of water addition to the most stable molecular and electronic structures of Mo{sub 2}O{sub 4}{sup ?} and Mo{sub 2}O{sub 5}{sup ?} were explored computationally. The various modes are discussed and compared with previous computational studies on W{sub 2}O{sub y}{sup ?} + H{sub 2}O reactions. Calculated free energy reaction profiles show lower barriers for the initial Mo{sub 2}O{sub y}{sup ?} + H{sub 2}O addition, consistent with the higher observed rate constant. The terminal Mo{sub 2}O{sub y}{sup ?} sequential oxidation product predicted computationally was verified by the anion photoelectron spectrum of Mo{sub 2}O{sub 6}D{sub 2}{sup ?}. Based on the computational results, this anion is a trapped dihydroxide intermediate in the Mo{sub 2}O{sub 5}{sup ?} + H{sub 2}O/D{sub 2}O ? Mo{sub 2}O{sub 6}{sup ?} + H{sub 2}/D{sub 2} reaction.

  13. H-point exciton transitions in bulk MoS{sub 2}

    SciTech Connect (OSTI)

    Saigal, Nihit; Ghosh, Sandip

    2015-05-04

    Reflectance and photoreflectance spectrum of bulk MoS{sub 2} around its direct bandgap energy have been measured at 12?K. Apart from spectral features due to the A and B ground state exciton transitions at the K-point of the Brillouin zone, one observes additional features at nearby energies. Through lineshape analysis the character of two prominent additional features are shown to be quite different from that of A and B. By comparing with reported electronic band structure calculations, these two additional features are identified as ground state exciton transitions at the H-point of the Brillouin zone involving two spin-orbit split valance bands. The excitonic energy gap at the H-point is 1.965?eV with a valance bands splitting of 185?meV. While at the K-point, the corresponding values are 1.920?eV and 205?meV, respectively.

  14. Policy Flash 2013-71 AL 2013-11 NON M&O CONTRACTOR BUSINESS SYSTEMS...

    Energy Savers [EERE]

    Policy Flash 2013-71 AL 2013-11 NON M&O CONTRACTOR BUSINESS SYSTEMS CLAUSES FOR SECTION H Policy Flash 2013-71 AL 2013-11 NON M&O CONTRACTOR BUSINESS SYSTEMS CLAUSES FOR SECTION H...

  15. Corrosion report for the U-Mo fuel concept

    SciTech Connect (OSTI)

    Henager, Jr., Charles H.; Bennett, Wendy D.; Doherty, Ann L.; Fuller, E. S.; Hardy, John S.; Omberg, Ronald P.

    2014-08-28

    The Fuel Cycle Research and Development (FCRD) program of the Office of Nuclear Energy (NE) has implemented a program to develop a Uranium-Molybdenum (U-Mo) metal fuel for Light Water Reactors (LWR)s. Uranium-Molybdenum fuel has the potential to provide superior performance based on its thermo-physical properties, which includes high thermal conductivity for less stored heat energy. With sufficient development, it may be able to provide the Light Water industry with a melt-resistant accident tolerant fuel with improved safety response. However, the corrosion of this fuel in reactor water environments needs to be further explored and optimized by additional alloying. The Pacific Northwest National Laboratory has been tasked with performing ex-reactor corrosion testing to characterize the performance of U-Mo fuel. This report documents the results of the effort to characterize and develop the U-Mo metal fuel concept for LWRs with regard to corrosion testing. The results of a simple screening test in buffered water at 30°C using surface alloyed U-10Mo is documented and discussed. The screening test was used to guide the selection of several potential alloy improvements that were found and are recommended for further testing in autoclaves to simulate PWR water conditions more closely.

  16. Mo{sub 6}Se{sub 8}-cluster-based superconducting compounds Cs{sub 2}Mo{sub 12}Se{sub 14} and Rb{sub 4}Mo{sub 18}Se{sub 20}: Evidence for a strongly correlated and anisotropic electron system

    SciTech Connect (OSTI)

    Brusetti, R.; Laborde, O.; Sulpice, A.; Calemczuk, R.; Potel, M.; Gougeon, P.

    1995-08-01

    We studied the normal and superconducting states of the title compounds by measuring the conductivity and magnetization of single crystals and powder samples. From the upper and lower critical fields we deduced the characteristic lengths and thermodynamical fields. These results are borne out by our specific-heat measurements. We recognize in these compounds many features of the Chevrel-phase superconductors, including very small coherence lengths and strong-coupling-like effects. However, we show that the electron system is much more anisotropic and still less delocalized in these materials where the Mo{sub 6}Se{sub 8} clusters have condensed in Mo{sub 6{ital n}}Se{sub 6{ital n}+2} finite chains. This condensation is accompanied by an enhancement of the magnetic response whereas the lengthening of the chains leads to a counteracting reduction of the density of carriers. This indicates that superconductivity is built upon highly correlated molecular states. Reviewing the available data on the other Chevrel-cluster-based superconductors confirms this picture and suggests that the small coherence lengths reflect the local character of the electron pairing. This comparison also shows that forming finite chains of Mo{sub 6}Se{sub 8} clusters makes the electron correlations more repulsive and pushes the electron system near the borderline between superconductivity and magnetism. In this respect these compounds could provide valuable complementary information on issues which are at the center of the research upon high-{ital Y}{sub {ital c}} superconductivity.

  17. Defects Engineered Monolayer MoS2 for Improved Hydrogen Evolution Reaction

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ye, Gonglan; Gong, Yongji; Lin, Junhao; Li, Bo; He, Yongmin; Pantelides, Sokrates T.; Zhou, Wu; Vajtai, Robert; Ajayan, Pulickel M.

    2016-01-13

    MoS2 is a promising, low-cost material for electrochemical hydrogen production due to its high activity and stability during the reaction. Our work represents an easy method to increase the hydrogen production in electrochemical reaction of MoS2 via defect engineering, and helps to understand the catalytic properties of MoS2.

  18. Consent to Subcontracts on Management and Operating (M&O) Contracts

    Broader source: Energy.gov [DOE]

    This is to provide notice that an Acquisition Letter (AL) will be issued addressing the establishment of subcontract review thresholds on M&O contracts. Currently, DEAR 970.4401-1 and 970.4401-2 require Heads of the Contracting Activities (HCAs) to establish thresholds, by subcontract type and dollar level, for the review and approval of proposed subcontracting actions by each M&O contractor under their cognizance. The AL will seek to improve Consent to Subcontract efficiency and to ensure we apply our resources to those subcontract actions that truly pose the most risk. The AL will state that the HCA should determine appropriate tiers for subcontract review thresholds, as a result of a risk assessment. This tiered approach may result in different thresholds being established for different sites as well as different thresholds at a given site, taking into consideration the best interests of DOE and the following factors: approval status of the contractor's purchasing system results of Independent Peer Review Program for Contractors' Purchasing Systems (e.g., PERT results) results of Contractor Balanced Scorecard Self-assessment size, experience, ability, reliability, and organization of the contractor's purchasing function internal controls, procedures, and organizational stature of the contractor's purchasing function subcontract type (fixed price vs. cost reimbursement) degree of competition value nature of the work/complexity whether the subcontract needs special surveillance

  19. Partial substitution of Mo{sup 6+} by S{sup 6+} in the fast oxide ion conductor La{sub 2}Mo{sub 2}O{sub 9}: Synthesis, structure and sulfur depletion

    SciTech Connect (OSTI)

    Mhadhbi, Noureddine; Corbel, Gwenaeel; Lacorre, Philippe; Bulou, Alain

    2012-06-15

    Powder-solid state reaction route using La{sub 2}(SO{sub 4}){sub 3} as sulfur source was used to prepare compositions of the solid solution La{sub 2}Mo{sub 2-y}S{sub y}O{sub 9}. Single phases were only obtained in the substitution range extending up to y=0.8 (40 mol% S) at the annealing temperature of 850 Degree-Sign C with regard to the limit of stability of the lanthanum sulphate reactant. Within the synthesis conditions, a stabilization of the high temperature {beta}-form is observed from and above y=0.1 (5 mol% S). Temperature-controlled X-ray diffraction and thermogravimetric analyses have shown that La{sub 2}Mo{sub 2-y}S{sub y}O{sub 9} raw powders undergo thermal decompositions in two steps. Heating above 900 Degree-Sign C, a sulfur depletion to the benefit of molybdenum in La{sub 2}Mo{sub 2-y}S{sub y}O{sub 9} raw powders leads to the formation of La{sub 2}SO{sub 6}. At higher temperature, the exsolved La{sub 2}SO{sub 6} phase then decomposes into La{sub 2}O{sub 3}, which in turn reacts with the sulfur-depleted La{sub 2}Mo{sub 2}O{sub 9} phase to form La{sub 2}MoO{sub 6}. The present study also reveals that depending on the substitution rate y, the sulfur depletion can be induced by ball-milling of raw powders. Along the La{sub 2}Mo{sub 2-y}S{sub y}O{sub 9} series, the isovalent substitution of molybdenum by sulfur tends to restrict in magnitude, or even to suppress above 400 Degree-Sign C, the distortive thermal expansion of the cubic {beta}-type structure, thus strongly decreasing the conductance at high temperature. - Graphical abstract: La{sub 2}O{sub 3}-MoO{sub 3}-'SO{sub 3}' ternary phase diagram showing the exsolution path at low temperature (white arrows) and the total decomposition path at high temperature (black arrows) of {beta}-La{sub 2}Mo{sub 2-y}S{sub y}O{sub 9} raw powders. Highlights: Black-Right-Pointing-Pointer Isovalent substitution of molybdenum by sulfur in La{sub 2}Mo{sub 2}O{sub 9} up to 40 mol%. Black-Right-Pointing-Pointer Stabilization of the {beta}-form for a sulfur content greater than or equal to 5 mol%. Black-Right-Pointing-Pointer Decomposition by sulfur exsolution induced by thermal treatment or ball-milling. Black-Right-Pointing-Pointer Reduction or even cancellation of the distortive thermal expansion above 400 Degree-Sign C. Black-Right-Pointing-Pointer Decrease of conductance at high T involved by the low thermal expansion above 400 Degree-Sign C.

  20. Thermal transport properties of metal/MoS{sub 2} interfaces from first principles

    SciTech Connect (OSTI)

    Mao, Rui; Kong, Byoung Don; Kim, Ki Wook, E-mail: kwk@ncsu.edu [Department of Electrical and Computer Engineering, North Carolina State University, Raleigh, North Carolina 27695-7911 (United States)

    2014-07-21

    Thermal transport properties at the metal/MoS{sub 2} interfaces are analyzed by using an atomistic phonon transport model based on the Landauer formalism and first-principles calculations. The considered structures include chemisorbed Sc(0001)/MoS{sub 2} and Ru(0001)/MoS{sub 2}, physisorbed Au(111)/MoS{sub 2}, as well as Pd(111)/MoS{sub 2} with intermediate characteristics. Calculated results illustrate a distinctive dependence of thermal transfer on the details of interfacial microstructures. More specifically, the chemisorbed case with a stronger bonding exhibits a generally smaller interfacial thermal resistance than the physisorbed. Comparison between metal/MoS{sub 2} and metal/graphene systems suggests that metal/MoS{sub 2} is significantly more resistive. Further examination of lattice dynamics identifies the presence of multiple distinct atomic planes and bonding patterns at the interface as the key origins of the observed large thermal resistance.

  1. Development of uranium metal targets for {sup 99}Mo production

    SciTech Connect (OSTI)

    Wiencek, T.C.; Hofman, G.L.

    1993-10-01

    A substantial amount of high enriched uranium (HEU) is used for the production of medical-grade {sup 99}Mo. Promising methods of producing irradiation targets are being developed and may lead to the reduction or elimination of this HEU use. To substitute low enriched uranium (LEU) for HEU in the production of {sup 99}Mo, the target material may be changed to uranium metal foil. Methods of fabrication are being developed to simplify assembly and disassembly of the targets. Removal of the uranium foil after irradiation without dissolution of the cladding is a primary goal in order to reduce the amount of liquid radioactive waste material produced in the process. Proof-of-concept targets have been fabricated. Destructive testing indicates that acceptable contact between the uranium foil and the cladding can be achieved. Thermal annealing tests, which simulate the cladding/uranium diffusion conditions during irradiation, are underway. Plans are being made to irradiate test targets.

  2. Undercooled and rapidly quenched Ni-Mo alloys

    SciTech Connect (OSTI)

    Tewari, S.N.; Glasgow, T.K.

    1986-01-01

    Hypoeutectic, eutectic, and hypereutectic nickel-molybdenum alloys were rapidly solidified by both bulk undercooling and melt spinning techniques. Alloys were undercooled in both electromagnetic levitation and differential thermal analysis equipment. The rate of recalescence depended upon the degree of initial undercooling and the nature (faceted or nonfaceted) of the primary nucleating phase. Alloy melts were observed to undercool more in the presence of primary Beta (NiMo intermetallic) phase than in gamma (fcc solid solution) phase. Melt spinning resulted in an extension of molybdenum solid solubility in gamma nickel, from 28 to 37.5 at % Mo. Although the microstructures observed by undercooling and melt spinning were similar the microsegregation pattern across the gamma dendries was different. The range of microstructures evolved was analyzed in terms of the nature of the primary phase to nucleate, its subsequent dendritic growth, coarsening and fragmentation, and final solidification of interfenderitic liquid.

  3. Insulator to correlated metal transition in V_1-xMo_xO_2

    SciTech Connect (OSTI)

    Klimczuk, Tomasz; Ronning, Filip; Holman, Katherine; Mcqueen, Tyrel M; Williams, Anthony J; Stephens, P W; Zandbergen, Henny W; Xu, Q; Cava, Robert J

    2009-01-01

    The change from metallic to insulating states is one of the most dramatic transitions that solids undergo on cooling or chemical doping. Many materials display this transition, but only a handful have the right combination of crystal structure and physical properties to serve as model systems. VO{sub 2} is one of those materials. Using Mo as a chemical dopant in VO{sub 2}, we find unanticipated phenomenology for both the electronic and structural characteristics of the resulting insulator to metal transition. The results support a complex, previously proposed scenario involving the coexistence of both electron repulsion and electron pairing for yielding an insulator in VO{sub 2}, but not simply; many issues are raised about local versus itinerant behavior and structure-property correlations in this most iconic ofdoped correlated electron systems.

  4. IRRADIATION PERFORMANCE OF U-Mo MONOLITHIC FUEL

    SciTech Connect (OSTI)

    M.K. Meyer; J. Gan; J.-F. Jue; D.D. Keiser; E. Perez; A. Robinson; D.M. Wachs; N. Woolstenhulme; G.L. Hofman; Y.-S. Kim

    2014-04-01

    High-performance research reactors require fuel that operates at high specific power to high fission density, but at relatively low temperatures. Research reactor fuels are designed for efficient heat rejection, and are composed of assemblies of thin-plates clad in aluminum alloy. The development of low-enriched fuels to replace high-enriched fuels for these reactors requires a substantially increased uranium density in the fuel to offset the decrease in enrichment. Very few fuel phases have been identified that have the required combination of very-high uranium density and stable fuel behavior at high burnup. UMo alloys represent the best known tradeoff in these properties. Testing of aluminum matrix U-Mo aluminum matrix dispersion fuel revealed a pattern of breakaway swelling behavior at intermediate burnup, related to the formation of a molybdenum stabilized high aluminum intermetallic phase that forms during irradiation. In the case of monolithic fuel, this issue was addressed by eliminating, as much as possible, the interfacial area between U-Mo and aluminum. Based on scoping irradiation test data, a fuel plate system composed of solid U-10Mo fuel meat, a zirconium diffusion barrier, and Al6061 cladding was selected for development. Developmental testing of this fuel system indicates that it meets core criteria for fuel qualification, including stable and predictable swelling behavior, mechanical integrity to high burnup, and geometric stability. In addition, the fuel exhibits robust behavior during power-cooling mismatch events under irradiation at high power.

  5. Single Phase Melt Processed Powellite (Ba,Ca) MoO{sub 4} For The Immobilization Of Mo-Rich Nuclear Waste

    SciTech Connect (OSTI)

    Brinkman, Kyle; Marra, James; Fox, Kevin; Reppert, Jason; Crum, Jarrod; Tang, Ming

    2012-09-17

    Crystalline and glass composite materials are currently being investigated for the immobilization of combined High Level Waste (HLW) streams resulting from potential commercial fuel reprocessing scenarios. Several of these potential waste streams contain elevated levels of transition metal elements such as molybdenum (Mo). Molybdenum has limited solubility in typical silicate glasses used for nuclear waste immobilization. Under certain chemical and controlled cooling conditions, a powellite (Ba,Ca)MoO{sub 4} crystalline structure can be formed by reaction with alkaline earth elements. In this study, single phase BaMoO{sub 4} and CaMoO{sub 4} were formed from carbonate and oxide precursors demonstrating the viability of Mo incorporation into glass, crystalline or glass composite materials by a melt and crystallization process. X-ray diffraction, photoluminescence, and Raman spectroscopy indicated a long range ordered crystalline structure. In-situ electron irradiation studies indicated that both CaMoO{sub 4} and BaMoO{sub 4} powellite phases exhibit radiation stability up to 1000 years at anticipated doses with a crystalline to amorphous transition observed after 1 X 10{sup 13} Gy. Aqueous durability determined from product consistency tests (PCT) showed low normalized release rates for Ba, Ca, and Mo (<0.05 g/m{sup 2}).

  6. secretary of state | National Nuclear Security Administration

    National Nuclear Security Administration (NNSA)

    state

  7. Bonding between graphene and MoS{sub 2} monolayers without and with Li

    Office of Scientific and Technical Information (OSTI)

    intercalation (Journal Article) | SciTech Connect Journal Article: Bonding between graphene and MoS{sub 2} monolayers without and with Li intercalation Citation Details In-Document Search Title: Bonding between graphene and MoS{sub 2} monolayers without and with Li intercalation We performed density functional theory (DFT) calculations for a bi-layered heterostructure combining a graphene layer with a MoS{sub 2} layer with and without intercalated Li atoms. Our calculations demonstrate the

  8. Characterization of modified 9 Cr-1 Mo steel extruded pipe

    SciTech Connect (OSTI)

    Sikka, V.K.; Hart, M.D.

    1985-04-01

    The fabrication of hot-extruded pipe of modified 9 Cr-1 Mo steel at Cameron Iron Works is described. The report also deals with the tempering response; tensile, Charpy impact, and creep properties; and microstructure of the hot-extruded pipe. The tensile properties of the pipe are compared with the average and average -1.65 standard error of estimate curves for various product forms of several commercial heats of this alloy. The creep-rupture properties are compared with the average curve for various product forms of the commercial heats.

  9. Recovery of Mo/Si multilayer coated optical substrates

    DOE Patents [OSTI]

    Baker, S.L.; Vernon, S.P.; Stearns, D.G.

    1997-12-16

    Mo/Si multilayers are removed from superpolished ZERODUR and fused silica substrates with a dry etching process that, under suitable processing conditions, produces negligible change in either the substrate surface figure or surface roughness. The two step dry etching process removes SiO{sub 2} overlayer with a fluroine-containing gas and then moves molybdenum and silicon multilayers with a chlorine-containing gas. Full recovery of the initial normal incidence extreme ultra-violet (EUV) reflectance response has been demonstrated on reprocessed substrates. 5 figs.

  10. Recovery of Mo/Si multilayer coated optical substrates

    DOE Patents [OSTI]

    Baker, Sherry L.; Vernon, Stephen P.; Stearns, Daniel G.

    1997-12-16

    Mo/Si multilayers are removed from superpolished ZERODUR and fused silica substrates with a dry etching process that, under suitable processing conditions, produces negligible change in either the substrate surface figure or surface roughness. The two step dry etching process removes SiO.sub.2 overlayer with a fluroine-containing gas and then moves molybdenum and silicon multilayers with a chlorine-containing gas. Full recovery of the initial normal incidence extreme ultra-violet (EUV) reflectance response has been demonstrated on reprocessed substrates.

  11. Greenfield Alternative Study LEU-Mo Fuel Fabrication Facility

    SciTech Connect (OSTI)

    Washington Division of URS

    2008-07-01

    This report provides the initial “first look” of the design of the Greenfield Alternative of the Fuel Fabrication Capability (FFC); a facility to be built at a Greenfield DOE National Laboratory site. The FFC is designed to fabricate LEU-Mo monolithic fuel for the 5 US High Performance Research Reactors (HPRRs). This report provides a pre-conceptual design of the site, facility, process and equipment systems of the FFC; along with a preliminary hazards evaluation, risk assessment as well as the ROM cost and schedule estimate.

  12. NUMERICAL SIMULATION FOR MECHANICAL BEHAVIOR OF U10MO MONOLITHIC MINIPLATES FOR RESEARCH AND TEST REACTORS

    SciTech Connect (OSTI)

    Hakan Ozaltun & Herman Shen

    2011-11-01

    This article presents assessment of the mechanical behavior of U-10wt% Mo (U10Mo) alloy based monolithic fuel plates subject to irradiation. Monolithic, plate-type fuel is a new fuel form being developed for research and test reactors to achieve higher uranium densities within the reactor core to allow the use of low-enriched uranium fuel in high-performance reactors. Identification of the stress/strain characteristics is important for understanding the in-reactor performance of these plate-type fuels. For this work, three distinct cases were considered: (1) fabrication induced residual stresses (2) thermal cycling of fabricated plates; and finally (3) transient mechanical behavior under actual operating conditions. Because the temperatures approach the melting temperature of the cladding during the fabrication and thermal cycling, high temperature material properties were incorporated to improve the accuracy. Once residual stress fields due to fabrication process were identified, solution was used as initial state for the subsequent simulations. For thermal cycling simulation, elasto-plastic material model with thermal creep was constructed and residual stresses caused by the fabrication process were included. For in-service simulation, coupled fluid-thermal-structural interaction was considered. First, temperature field on the plates was calculated and this field was used to compute the thermal stresses. For time dependent mechanical behavior, thermal creep of cladding, volumetric swelling and fission induced creep of the fuel foil were considered. The analysis showed that the stresses evolve very rapidly in the reactor. While swelling of the foil increases the stress of the foil, irradiation induced creep causes stress relaxation.

  13. Synthesis of molybdenum disulfide (MoS{sub 2}) for lithium ion battery applications

    SciTech Connect (OSTI)

    Feng Chuanqi; Ma Jun; Li Hua; Zeng Rong; Guo Zaiping; Liu Huakun

    2009-09-15

    This paper reports the use of a rheological phase reaction method for preparing MoS{sub 2} nanoflakes. The characterization by powder X-ray diffraction indicated that MoS{sub 2} had been formed. High resolution electron microscopy observation revealed that the as-prepared MoS{sub 2} nanoflakes had started to curve and partly form MoS{sub 2} nanotubes. The lithium intercalation/de-intercalation behavior of as-prepared MoS{sub 2} nanoflake electrode was also investigated. It was found that the MoS{sub 2} nanoflake electrode exhibited higher specific capacity, with very high cycling stability, compared to MoS{sub 2} nanoparticle electrode. The possible reasons for the high electrochemical performance of the nanoflakes electrodes are also discussed. The outstanding electrochemical properties of MoS{sub 2} nanoflakes obtained by this method make it possible for MoS{sub 2} to be used as a promising anode material.

  14. Solution-based thermodynamic modeling of the Ni-Al-Mo system using

    Office of Scientific and Technical Information (OSTI)

    first-principles calculations (Journal Article) | SciTech Connect Solution-based thermodynamic modeling of the Ni-Al-Mo system using first-principles calculations Citation Details In-Document Search Title: Solution-based thermodynamic modeling of the Ni-Al-Mo system using first-principles calculations A solution-based thermodynamic description of the ternary Ni-Al-Mo system is developed here, incorporating first-principles calculations and reported modeling of the binary Ni-Al, Ni-Mo and

  15. Improving Accident Tolerance of Nuclear Fuel with Coated Mo-alloy...

    Office of Scientific and Technical Information (OSTI)

    Improving Accident Tolerance of Nuclear Fuel with Coated Mo-alloy Cladding Citation Details In-Document Search Title: Improving Accident Tolerance of Nuclear Fuel with Coated ...

  16. Experimental activities supporting commercial U.S. accelerator production of 99-Mo

    SciTech Connect (OSTI)

    Dale, Gregory E [Los Alamos National Laboratory; Chemerisov, Sergey D [ANL; Vandegrift, George F [ANL

    2010-01-01

    {sup 99m}Tc, the daughter product of {sup 99}Mo, is the most commonly used radioisotope for nuclear medicine in the U.S. Experiments are being performed at Los Alamos National Laboratory and Argonne National Laboratory to demonstrate production of {sup 99}Mo using accelerators. The {sup 100}Mo({gamma},n){sup 99}Mo reaction in an enriched {sup 100}Mo target is currently under investigation. Three scaled low-power production experiments using a 20-MeV electron linac at Argonne have been performed to date. Two of these experiments used natural Mo targets and produced a total of 613 {mu}C of {sup 99}Mo. The third experiment used an enriched {sup 100}Mo target and produced 10.5 mCi of {sup 99}Mo. Following irradiation the targets were dissolved and the low specific activity solution was processed through an ARSII generator from NorthStar Medical Radioisotopes. Yields of {sup 99m}Tc >95% have been observed.

  17. Conceptual design of a new homogeneous reactor for medical radioisotope Mo-99/Tc-99m production

    SciTech Connect (OSTI)

    Liem, Peng Hong [Nippon Advanced Information Service (NAIS Co., Inc.) Scientific Computational Division, 416 Muramatsu, Tokaimura, Ibaraki (Japan); Tran, Hoai Nam [Chalmers University of Technology, Dept. of Applied Physics, Div. of Nuclear Engineering, SE-412 96 Gothenburg (Sweden); Sembiring, Tagor Malem [National Nuclear Energy Agency (BATAN), Center for Reactor Technology and Nuclear Safety, Kawasan Puspiptek, Serpong, Tangerang Selatan, Banten (Indonesia); Arbie, Bakri [PT MOTAB Technology, Kedoya Elok Plaza Blok DA 12, Jl. Panjang, Kebun Jeruk, Jakarta Barat (Indonesia)

    2014-09-30

    To partly solve the global and regional shortages of Mo-99 supply, a conceptual design of a nitrate-fuel-solution based homogeneous reactor dedicated for Mo-99/Tc-99m medical radioisotope production is proposed. The modified LEU Cintichem process for Mo-99 extraction which has been licensed and demonstrated commercially for decades by BATAN is taken into account as a key design consideration. The design characteristics and main parameters are identified and the advantageous aspects are shown by comparing with the BATAN's existing Mo-99 supply chain which uses a heterogeneous reactor (RSG GAS multipurpose reactor)

  18. Microsoft Word - chapter FeNiCrMo_ver4.doc

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Low-Alloy Ferritic Steels Fe-Ni-Cr-Mo Tempered December 8, ... strength level, material processing, and heat treatment 1. ... steel composition, hydrogen gas pressure, and temperature. ...

  19. Domestic production of medical isotope Mo-99 moves a step closer

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    partners, including Morgridge Institute for Research-SHINE Medical Technologies (MIR-SHINE), which proposes to use a particle accelerator to produce Mo-99 from a mildly...

  20. Acquisition Guide Chapter 7.3:Acquisition Planning in the M&O Environment

    Broader source: Energy.gov [DOE]

    Acquisition Letter 2013-03, Acquisition Planning Considerations for M&O Contracts, has been moved to the Acquisition Guide as chapter (7.3).

  1. Mechanically Activated Combustion Synthesis of MoSi2-Based Composites

    SciTech Connect (OSTI)

    Shafirovich, Evgeny

    2015-09-30

    The thermal efficiency of gas-turbine power plants could be dramatically increased by the development of new structural materials based on molybdenum silicides and borosilicides, which can operate at temperatures higher than 1300 °C with no need for cooling. A major challenge, however, is to simultaneously achieve high oxidation resistance and acceptable mechanical properties at high temperatures. One approach is based on the fabrication of MoSi2-Mo5Si3 composites that combine high oxidation resistance of MoSi2 and good mechanical properties of Mo5Si3. Another approach involves the addition of boron to Mo-rich silicides for improving their oxidation resistance through the formation of a borosilicate surface layer. In particular, materials based on Mo5SiB2 phase are promising materials that offer favorable combinations of high temperature mechanical properties and oxidation resistance. However, the synthesis of Mo-Si-B multi-phase alloys is difficult because of their extremely high melting temperatures. Mechanical alloying has been considered as a promising method, but it requires long milling times, leading to large energy consumption and contamination of the product by grinding media. In the reported work, MoSi2-Mo5Si3 composites and several materials based on Mo5SiB2 phase have been obtained by mechanically activated self-propagating high-temperature synthesis (MASHS). Short-term milling of Mo/Si mixture in a planetary mill has enabled a self-sustained propagation of the combustion front over the mixture pellet, leading to the formation of MoSi2-T1 composites. Combustion of Mo/Si/B mixtures for the formation of T2 phase becomes possible if the composition is designed for the addition of more exothermic reactions leading to the formation of MoB, TiC, or TiB2. Upon ignition, Mo/Si/B and Mo/Si/B/Ti mixtures exhibited spin combustion, but the products were porous, contained undesired secondary phases, and had low oxidation resistance. It has been shown that use of SHS compaction (quasi-isostatic pressing after combustion) significantly improves oxidation resistance of the obtained MoSi2-Mo5Si3 composites. The “chemical oven” technique has been successfully employed to fabricate low-porous Mo5SiB2–TiC, Mo5SiB2–TiB2, and Mo–Mo5SiB2–Mo3Si materials. Among them, Mo5SiB2–TiB2 material possesses good mechanical properties and simultaneously exhibits excellent oxidation resistance at temperatures up to 1500 °C.

  2. Momentum distributions for H2<mo>(mo>e<mo>,mo>e<mo>'p)>

    SciTech Connect (OSTI)

    Ford, William P.; Jeschonnek, Sabine; Van Orden, J. W.

    2014-12-29

    [Background] A primary goal of deuteron electrodisintegration is the possibility of extracting the deuteron momentum distribution. This extraction is inherently fraught with difficulty, as the momentum distribution is not an observable and the extraction relies on theoretical models dependent on other models as input. [Purpose] We present a new method for extracting the momentum distribution which takes into account a wide variety of model inputs thus providing a theoretical uncertainty due to the various model constituents. [Method] The calculations presented here are using a Bethe-Salpeter like formalism with a wide variety of bound state wave functions, form factors, and final state interactions. We present a method to extract the momentum distributions from experimental cross sections, which takes into account the theoretical uncertainty from the various model constituents entering the calculation. [Results] In order to test the extraction pseudo-data was generated, and the extracted "experimental'' distribution, which has theoretical uncertainty from the various model inputs, was compared with the theoretical distribution used to generate the pseudo-data. [Conclusions] In the examples we compared the original distribution was typically within the error band of the extracted distribution. The input wave functions do contain some outliers which are discussed in the text, but at least this process can provide an upper bound on the deuteron momentum distribution. Due to the reliance on the theoretical calculation to obtain this quantity any extraction method should account for the theoretical error inherent in these calculations due to model inputs.

  3. Characterization of U-Mo Foils for AFIP-7

    SciTech Connect (OSTI)

    Edwards, Danny J.; Ermi, Ruby M.; Schemer-Kohrn, Alan L.; Overman, Nicole R.; Henager, Charles H.; Burkes, Douglas; Senor, David J.

    2012-11-07

    Twelve AFIP in-process foil samples, fabricated by either Y-12 or LANL, were shipped from LANL to PNNL for potential characterization using optical and scanning electron microscopy techniques. Of these twelve, nine different conditions were examined to one degree or another using both techniques. For this report a complete description of the results are provided for one archive foil from each source of material, and one unirradiated piece of a foil of each source that was irradiated in the Advanced Test Reactor. Additional data from two other LANL conditions are summarized in very brief form in an appendix. The characterization revealed that all four characterized conditions contained a cold worked microstructure to different degrees. The Y-12 foils exhibited a higher degree of cold working compared to the LANL foils, as evidenced by the highly elongated and obscure U-Mo grain structure present in each foil. The longitudinal orientations for both of the Y-12 foils possesses a highly laminar appearance with such a distorted grain structure that it was very difficult to even offer a range of grain sizes. The U-Mo grain structure of the LANL foils, by comparison, consisted of a more easily discernible grain structure with a mix of equiaxed and elongated grains. Both materials have an inhomogenous grain structure in that all of the characterized foils possess abnormally coarse grains.

  4. New Generation of MoSx Based Solid Lubricant Coatings: Recent Developments and Applications

    SciTech Connect (OSTI)

    Haider, Julfikar; Hashmi, M. S. J.

    2011-01-17

    In recent times, there is a growing interest in applying Molybdenum disulphide (MoS{sub x}) solid lubricant coatings on components to improve the tribological performance (i.e. lower friction coefficient and wear rate). The tribological performance of MoS{sub x} coating is strongly dependent on coating properties and tribological environment. MoS{sub x} coatings are highly successful in certain applications such as in space/vacuum technology, but its effectiveness is questioned in other terrestrial applications such as in cutting tool industry due to its lower hardness and poor oxidation resistance leading to shorter life. In order to circumvent this drawback, the paper identifies that current research is being concentrated on developing MoS{sub x} based coatings using three different approaches: (1) Metal or compound addition in MoS{sub x} coating (2)MoS{sub x} layer on hard coating and (3)MoS{sub x} addition in hard coating matrix. Although the primary objective is same in all three cases, the third approach is considered to be more effective in improving the tribological properties of the coating. Finally, the potential applications of MoS{sub x} based coatings in different industrial sectors have been briefly outlined.

  5. Photo-oxidation method using MoS2 nanocluster materials

    DOE Patents [OSTI]

    Wilcoxon, Jess P.

    2001-01-01

    A method of photo-oxidizing a hydrocarbon compound is provided by dispersing MoS.sub.2 nanoclusters in a solvent containing a hydrocarbon compound contaminant to form a stable solution mixture and irradiating the mixture to photo-oxide the hydrocarbon compound. Hydrocarbon compounds of interest include aromatic hydrocarbon and chlorinated hydrocarbons. MoS.sub.2 nanoclusters with an average diameter less than approximately 10 nanometers are shown to be effective in decomposing potentially toxic aromatic and chlorinated hydrocarbons, such as phenol, pentachlorophenol, chlorinated biphenols, and chloroform, into relatively non-toxic compounds. The irradiation can occur by exposing the MoS.sub.2 nanoclusters and hydrocarbon compound mixture with visible light. The MoS.sub.2 nanoclusters can be introduced to the toxic hydrocarbons as either a MoS.sub.2 solution or deposited on a support material.

  6. Surface Structures of Cubo-octahedral Pt-Mo Catalyst Nanoparticles from Monte Carlo Simulations

    SciTech Connect (OSTI)

    Wang, Guofeng; Van Hove, M.A.; Ross, P.N.; Baskes, M.I.

    2005-03-31

    The surface structures of cubo-octahedral Pt-Mo nanoparticles have been investigated using the Monte Carlo method and modified embedded atom method potentials that we developed for Pt-Mo alloys. The cubo-octahedral Pt-Mo nanoparticles are constructed with disordered fcc configurations, with sizes from 2.5 to 5.0 nm, and with Pt concentrations from 60 to 90 at. percent. The equilibrium Pt-Mo nanoparticle configurations were generated through Monte Carlo simulations allowing both atomic displacements and element exchanges at 600 K. We predict that the Pt atoms weakly segregate to the surfaces of such nanoparticles. The Pt concentrations in the surface are calculated to be 5 to 14 at. percent higher than the Pt concentrations of the nanoparticles. Moreover, the Pt atoms preferentially segregate to the facet sites of the surface, while the Pt and Mo atoms tend to alternate along the edges and vertices of these nanoparticles. We found that decreasing the size or increasing the Pt concentration leads to higher Pt concentrations but fewer Pt-Mo pairs in the Pt-Mo nanoparticle surfaces.

  7. Origin State Destination State

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    State 2001 2002 2003 2004 2005 2006 2007 2008 2009 2001-2009 2008-2009 Alabama Alabama W W W W W W W W W W W Alabama Georgia W W W W W W W W W W W Alabama Illinois - - - - - W W...

  8. Electronic and magnetic properties of armchair MoS{sub 2} nanoribbons under both external strain and electric field, studied by first principles calculations

    SciTech Connect (OSTI)

    Hu, Ting; Dong, Jinming; Zhou, Jian; Kawazoe, Yoshiyuki

    2014-08-14

    The electronic and magnetic properties of armchair edge MoS{sub 2} nanoribbons (MoS{sub 2}-ANRs) underboth the external strain and transverse electric field (E{sub t}) have been systematically investigated by using the first-principles calculations. It is found that: (1) If no electric field is applied, an interesting structural phase transition would appear under a large tensile strain, leading to a new phase MoS{sub 2}-A'NR, and inducing a big jump peak of the band gap in the transition region. But, the band gap response to compressive strains is much different from that to tensile strain, showing no the structural phase transition. (2) Under the small tensile strains (<10%), the combined E{sub t} and tensile strain give rise to a positive superposition (resonant) effect on the band gap reduction at low E{sub t} (<3 V/nm), and oppositely a negative superposition (antiresonant) one at high E{sub t} (>4 V/nm). On the other hand, the external compressive strains have always presented the resonant effect on the band gap reduction, induced by the electric field. (3) After the structural phase transition, an external large tensile strain could greatly reduce the critical field E{sub tc} causing the band gap closure, and make the system become a ferromagnetic (FM) metal at a relative low E{sub t} (e.g., <4 V/nm), which is very helpful for its promising applications in nano-mechanical spintronics devices. (4) At high E{sub t} (>10 V/nm), the magnetic moments of both the MoS{sub 2}-ANR and MoS{sub 2}-A'NR in their FM states could be enhanced greatly by a tensile strain. Our numerical results of effectively tuning physical properties of MoS{sub 2}-ANRs by combined external strain and electric field may open their new potential applications in nanoelectronics and spintronics.

  9. Microstructural characterization of a thin film ZrN diffusion barrier in an As-fabricated U7Mo/Al matrix dispersion fuel plate

    SciTech Connect (OSTI)

    Keiser, Dennis D.; Perez, Emmanuel; Wiencek, Tom; Leenaers, Ann; Van den Berghe, Sven

    2015-03-01

    The United States High Performance Research Reactor Fuel Development program is developing low enriched uranium fuels for application in research and test reactors. One concept utilizes U7 wt.% Mo (U7Mo) fuel particles dispersed in Al matrix, where the fuel particles are coated with a 1 ?m-thick ZrN coating. The ZrN serves as a diffusion barrier to eliminate a deleterious reaction that can occur between U7Mo and Al when a dispersion fuel is irradiated under aggressive reactor conditions. To investigate the final microstructure of a physically-vapor-deposited ZrN coating in a dispersion fuel plate after it was fabricated using a rolling process, characterization samples were taken from a fuel plate that was fabricated at 500 C using ZrN-coated U7Mo particles, Al matrix and AA6061 cladding. Scanning electron and transmission electron microscopy analysis were performed. Data from these analyses will be used to support future microstructural examinations of irradiated fuel plates, in terms of understanding the effects of irradiation on the ZrN microstructure, and to determine the role of diffusion barrier microstructure in eliminating fuel/matrix interactions during irradiation. The as-fabricated coating was determined to be cubic-ZrN (cF8) phase. It exhibited a columnar microstructure comprised of nanometer-sized grains and a region of relatively high porosity, mainly near the Al matrix. Small impurity-containing phases were observed at the U7Mo/ZrN interface, and no interaction zone was observed at the ZrN/Al interface. The bonding between the U7Mo and ZrN appeared to be mechanical in nature. A relatively high level of oxygen was observed in the ZrN coating, extending from the Al matrix in the ZrN coating in decreasing concentration. The above microstructural characteristics are discussed in terms of what may be most optimal for a diffusion barrier in a dispersion fuel plate application.

  10. Search for neutrinoless double-beta decay of Mo 100 with the NEMO-3 detector

    SciTech Connect (OSTI)

    John D. Baker; A. J. Caffrey

    2014-06-01

    We report the results of a search for the neutrinoless double- decay (0? ) of Mo 100 , using the NEMO-3 detector to reconstruct the full topology of the final state events. With an exposure of 34.7??kgy , no evidence for the 0? signal has been found, yielding a limit for the light Majorana neutrino mass mechanism of T 1/2 (0?)>1.110 24 years (90% C.L.) once both statistical and systematic uncertainties are taken into account. Depending on the nuclear matrix elements this corresponds to an upper limit on the Majorana effective neutrino mass of ?m ? ?<0.30.9??eV (90% C.L.). Constraints on other lepton number violating mechanisms of 0? decays are also given. Searching for high-energy double electron events in all suitable sources of the detector, no event in the energy region [3.210] MeV is observed for an exposure of 47??kgy .

  11. Spectroscopic signatures of AA' and AB stacking of chemical vapor deposited bilayer MoS2

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Xia, Ming; Li, Bo; Yin, Kuibo; Capellini, Giovanni; Niu, Gang; Gong, Yongji; Zhou, Wu; Ajayan, Pulickel M.; Xie, Ya -Hong

    2015-11-04

    We discuss prominent resonance Raman and photoluminescence spectroscopic differences between AA'and AB stacked bilayer molybdenum disulfide (MoS2) grown by chemical vapor deposition are reported. Bilayer MoS2 islands consisting of the two stacking orders were obtained under identical growth conditions. Also, resonance Raman and photoluminescence spectra of AA' and AB stacked bilayer MoS2 were obtained on Au nanopyramid surfaces under strong plasmon resonance. Both resonance Raman and photoluminescence spectra show distinct features indicating clear differences in interlayer interaction between these two phases. The implication of these findings on device applications based on spin and valley degrees of freedom.

  12. New Insights Into a Functioning Mg-ion Cathode-Chevrel Phase Mo6S8 -

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Joint Center for Energy Storage Research April 24, 2014, Research Highlights New Insights Into a Functioning Mg-ion Cathode-Chevrel Phase Mo6S8 An isosurface of the charge density difference between pristine Mo6S8 and the inclusion of a single Mg2+ intercalant (and accompanying 2 electrons). Colors: Yellow (cyan) indicates an increase (decrease) in electron density, the Mg atom is shown in orange, S yellow, Mo purple. Scientific Achievement First-principles analysis of the screening of Mg2+

  13. Development of an Immobilisation Technology for Radioactive Waste Solution from Mo-99 Production

    SciTech Connect (OSTI)

    Sizgek, G.D.; Sizgek, E.

    2006-07-01

    Australian Nuclear Science and Technology Organisation (ANSTO) developed a method to immobilize the Intermediate Level Liquid Waste (ILLW) arising from its Mo-99 production process. The immobilisation process involves impregnation of waste solution into ceramic precursor powders, drying, calcining and consolidation (Hot Isostatic Pressing, HIP) to produce final ceramic waste form. Ceramic precursor powder is produced by spray drying of a sol-gel based colloidal dispersion. These free-flowing, microspherical, 20-80 microns, precursors have porosity of 40-50%. An in-house custom designed and manufactured microwave-heated and mechanically fluidized mixer-drier was used for impregnation of the precursor powder with the simulated waste (Depleted Uranyl Nitrate Hexahydrate, DUNH, and inactive Cs, Sr nitrates as fission products) and drying. During impregnation an evaporation rate of 1 l/h water per kW microwave energy in steady state was achieved by matching the feed rate of DUNH to produce equivalent of 35% UO{sub 2} loading. It was demonstrated that the tuned microwave energy can be delivered to the mixer-drier during the entire impregnation process within very low reflection values. The samples of the waste loaded free-flowing powder were subsequently calcined at 750 deg. C under reducing atmosphere for thermal denitration and mineral phase nucleation. Calcined powders were filled into cans. After evacuation and sealing, the cans were isostatically pressed at 1260 deg. C. The consolidated ceramic waste form produced from the DUNH run has been assessed by durability and material characterization tests. Successful confirmation of each processing step at pilot and/or plant scale, has led to the design and construction of the overall process at full scale (equivalent of processing 8 kg U per batch) in a simulated hot-cell mock-up plant. The constructed plant mainly consists of a Microwave-heated Mechanical Fluidized Bed (MWMFB) mixer-drier a fluidized bed calciner, an off gas unit, material transfer/holding and can filling units. Performance of the overall process by integrating each of the processing steps and material transfer operations are currently being tested with inactive simulants from the point of remote operated plant design perspective. Definitive design of a hot-cell production system has been initiated in parallel to the mock-up plant tests. This paper describes the results of both full-scale DUNH impregnation run and inactive mock-up plant tests in developing unique Mo-99 waste immobilisation technology. (authors)

  14. Microstructural evolution during solution treatment of Co-Cr-Mo-C biocompatible alloys

    SciTech Connect (OSTI)

    Giacchi, J.V.; Fornaro, O.; Palacio, H.

    2012-06-15

    Three different Co-Cr-Mo-C alloys conforming to ASTM F75 standard were poured in an industrial environment and subjected to a conventional solution treatment at 1225 Degree-Sign C for several time intervals. The microstructural changes and transformations were studied in each case in order to evaluate the way in which treatment time influences the secondary phase fraction and clarify the microstructural changes that could occur. To assess how treatment time affects microstructure, optical microscopy and image analyzer software, scanning electron microscopy and energy dispersion spectrometry analysis were employed. The main phases detected in the as-cast state were: {sigma}-phase, M{sub 6}C, and M{sub 23}C{sub 6} carbides. The latter presented two different morphologies, blocky type and lamellar type. Despite being considered the most detrimental feature to mechanical properties, {sigma}-phase and lamellar carbides dissolution took place in the early stages of solution treatment. M{sub 23}C{sub 6} carbides featured two different behaviors. In the alloy obtained by melting an appropriate quantity of alloyed commercial materials, a decrease in size, spheroidization and transformation into M{sub 6}C carbides were simultaneously observed. In the commercial ASTM F75 alloy, in turn, despite being the same phase, only a marked decrease in precipitates size was noticed. These different behaviors could be ascribed to the initial presence of other phases in the alloy obtained from alloyed materials, such as {sigma}-phase and 'pearlitic' carbides, or to the initial precipitate size which was much larger in the first than in the commercial ASTM F75 alloy studied. M{sub 6}C carbides dissolved directly in the matrix as they could not be detected in samples solution-treated for 15 min. - Highlights: Black-Right-Pointing-Pointer Three different Co-Cr-Mo alloys were poured under an industrial environment. Black-Right-Pointing-Pointer Transformation of existing phases followed during conventional solution treatment. Black-Right-Pointing-Pointer In as-cast/treated samples, phases were identified by color metallography, SEM and EDS. Black-Right-Pointing-Pointer M{sub 23}C{sub 6} {yields} M{sub 6}C transformation was corroborated by SEM and EDS analysis. Black-Right-Pointing-Pointer Carbide spheroidization was also detected prior a noticeably carbide size decreasing.

  15. Electrochemical Testing of Ni-Cr-Mo-Gd Alloys

    SciTech Connect (OSTI)

    T. E. Lister; R. E. Mizia; H. Tian

    2005-10-01

    The waste package site recommendation design specified a boron-containing stainless steel, Neutronit 976/978, for fabrication of the internal baskets that will be used as a corrosion-resistant neutron-absorbing material. Recent corrosion test results gave higher-than-expected corrosion rates for this material. The material callout for these components has been changed to a Ni-Cr-Mo-Gd alloy (ASTM-B 932-04, UNS N06464) that is being developed at the Idaho National Laboratory. This report discusses the results of initial corrosion testing of this material in simulated in-package environments that could contact the fuel baskets after breach of the waste package outer barrier. The corrosion test matrix was executed using the potentiodynamic and potentiostatic electrochemical test techniques. The alloy performance shows low rates of general corrosion after initial removal of a gadolinium-rich second phase that intersects the surface. The high halide-containing test solutions exhibited greater tendencies toward initiation of crevice corrosion.

  16. Thermo-physical Properties of DU-10 wt.% Mo Alloys

    SciTech Connect (OSTI)

    Douglas E. Burkes; Cynthia A. Papesch; Andrew P. Maddison; Thomas Hartmann; Francine J. Rice

    2010-08-01

    Low-enriched uranium alloyed with 10 wt% molybdenum is under consideration by the Global Threat Reduction Initiative reactor convert program as a very high density fuel to enable the conversion of high-performance research reactors away from highly-enriched uranium fuels. As with any fuel development program, the thermophysical properties of the fuel as a function of temperature are extremely important and must be well characterized in order to effectively model and predict fuel behavior under normal and off-normal irradiation conditions. For the alloy system under investigation, there is a lack of thermophysical property data, and in most cases, the data is relatively inconsistent and lacks sufficient explanation. Available literature on this alloy system comes mainly from studies done during the 1960s and 1970s, and often does not include sufficient information on fabrication history or conditions to draw conclusions for the current application. The current paper has investigated specific heat capacity, coefficient of linear thermal expansion, density, and thermal diffusivity that were then used to calculate alloy thermal conductivity as a function of temperature. The data obtained from this investigation was compared to available literature on similar U-Mo alloys, and in most cases are in good agreement.

  17. Monolayers of MoS{sub 2} as an oxidation protective nanocoating material

    SciTech Connect (OSTI)

    Sen, H. Sener; Sahin, H.; Peeters, F. M.; Durgun, E.

    2014-08-28

    First-principle calculations are employed to investigate the interaction of oxygen with ideal and defective MoS{sub 2} monolayers. Our calculations show that while oxygen atoms are strongly bound on top of sulfur atoms, the oxygen molecule only weakly interacts with the surface. The penetration of oxygen atoms and molecules through a defect-free MoS{sub 2} monolayer is prevented by a very high diffusion barrier indicating that MoS{sub 2} can serve as a protective layer for oxidation. The analysis is extended to WS{sub 2} and similar coating characteristics are obtained. Our calculations indicate that ideal and continuous MoS{sub 2} and WS{sub 2} monolayers can improve the oxidation and corrosion-resistance of the covered surface and can be considered as an efficient nanocoating material.

  18. Microscopic origin of low frequency noise in MoS{sub 2} field-effect transistors

    SciTech Connect (OSTI)

    Ghatak, Subhamoy; Jain, Manish; Ghosh, Arindam; Mukherjee, Sumanta; Sarma, D. D.

    2014-09-01

    We report measurement of low frequency 1/f noise in molybdenum di-sulphide (MoS{sub 2}) field-effect transistors in multiple device configurations including MoS{sub 2} on silicon dioxide as well as MoS{sub 2}-hexagonal boron nitride (hBN) heterostructures. All as-fabricated devices show similar magnitude of noise with number fluctuation as the dominant mechanism at high temperatures and density, although the calculated density of traps is two orders of magnitude higher than that at the SiO{sub 2} interface. Measurements on the heterostructure devices with vacuum annealing and dual gated configuration reveals that along with the channel, metal-MoS{sub 2} contacts also play a significant role in determining noise magnitude in these devices.

  19. File:USDA-CE-Production-GIFmaps-MO.pdf | Open Energy Information

    Open Energy Info (EERE)

    MO.pdf Jump to: navigation, search File File history File usage Missouri Ethanol Plant Locations Size of this preview: 776 600 pixels. Full resolution (1,650 1,275 pixels,...

  20. Structure and Electronic Properties of MoVO type Mixed-metal...

    Office of Scientific and Technical Information (OSTI)

    and Theory Citation Details In-Document Search Title: Structure and Electronic Properties of MoVO type Mixed-metal Oxides a Combined View by Experiment and Theory Authors: ...

  1. NNSA Works to Establish a Reliable Supply of Mo-99 Produced Without...

    National Nuclear Security Administration (NNSA)

    DOENNSA's objective is to accelerate the establishment of a reliable, commercial Mo-99 supply network that avoids a single point of failure and does not use proliferation-sensitiv...

  2. Giant and tunable valley degeneracy splitting in MoTe 2 (Journal...

    Office of Scientific and Technical Information (OSTI)

    This content will become publicly available on September 7, 2016 Title: Giant and tunable valley degeneracy splitting in MoTe 2 Authors: Qi, Jingshan ; Li, Xiao ; Niu, Qian ; Feng, ...

  3. A pseudo binary y-Gd solidification diagram for Ni-Cr-Mo-Gd alloys...

    Office of Scientific and Technical Information (OSTI)

    Title: A pseudo binary y-Gd solidification diagram for Ni-Cr-Mo-Gd alloys. No abstract prepared. Authors: Dupont, John Neuman 1 ; Minicozzi, Michael J. 1 ; Robino, Charles ...

  4. AB INITIO Modeling of Thermomechanical Properties of Mo-Based Alloys for Fossil Energy Conversion

    SciTech Connect (OSTI)

    Ching, Wai-Yim

    2013-12-31

    In this final scientific/technical report covering the period of 3.5 years started on July 1, 2011, we report the accomplishments on the study of thermo-mechanical properties of Mo-based intermetallic compounds under NETL support. These include computational method development, physical properties investigation of Mo-based compounds and alloys. The main focus is on the mechanical and thermo mechanical properties at high temperature since these are the most crucial properties for their potential applications. In particular, recent development of applying ab initio molecular dynamic (AIMD) simulations to the T1 (Mo{sub 5}Si{sub 3}) and T2 (Mo{sub 5}SiB{sub 2}) phases are highlighted for alloy design in further improving their properties.

  5. Population Pulsation Resonances of Excitons in Monolayer MoSe 2 with Sub- 1 μ eV Linewidths

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Schaibley, John R.; Karin, Todd; Yu, Hongyi; Ross, Jason S.; Rivera, Pasqual; Jones, Aaron M.; Scott, Marie E.; Yan, Jiaqiang; Mandrus, D. G.; Yao, Wang; et al

    2015-04-01

    Monolayer transition metal dichalcogenides, a new class of atomically thin semiconductors, possess optically coupled 2D valley excitons. The nature of exciton relaxation in these systems is currently poorly understood. Here, we investigate exciton relaxation in monolayer MoSe₂ using polarization-resolved coherent nonlinear optical spectroscopy with high spectral resolution. We report strikingly narrow population pulsation resonances with two different characteristic linewidths of 1 and <0.2 μeV at low temperature. These linewidths are more than 3 orders of magnitude narrower than the photoluminescence and absorption linewidth, and indicate that a component of the exciton relaxation dynamics occurs on time scales longer than 1more » ns. The ultranarrow resonance (<0.2 μeV) emerges with increasing excitation intensity, and implies the existence of a long-lived state whose lifetime exceeds 6 ns.« less

  6. Improving Accident Tolerance of Nuclear Fuel with Coated Mo-alloy Cladding

    Office of Scientific and Technical Information (OSTI)

    (Journal Article) | SciTech Connect Improving Accident Tolerance of Nuclear Fuel with Coated Mo-alloy Cladding Citation Details In-Document Search Title: Improving Accident Tolerance of Nuclear Fuel with Coated Mo-alloy Cladding Authors: Cheng, Bo ; Kim, Young-Jin ; Chou, Peter Publication Date: 2016-02-01 OSTI Identifier: 1253199 Type: Published Article Journal Name: Nuclear Engineering and Technology Additional Journal Information: Journal Volume: 48; Journal Issue: 1; Related Information:

  7. Li Intercalation in MoS 2 : In Situ Observation of Its Dynamics and Tuning

    Office of Scientific and Technical Information (OSTI)

    Optical and Electrical Properties (Journal Article) | SciTech Connect Li Intercalation in MoS 2 : In Situ Observation of Its Dynamics and Tuning Optical and Electrical Properties Citation Details In-Document Search Title: Li Intercalation in MoS 2 : In Situ Observation of Its Dynamics and Tuning Optical and Electrical Properties Authors: Xiong, Feng ; Wang, Haotian ; Liu, Xiaoge ; Sun, Jie ; Brongersma, Mark ; Pop, Eric ; Cui, Yi Publication Date: 2015-10-14 OSTI Identifier: 1244610 DOE

  8. Climate Action Champions: Mid-America Regional Council, KS and MO |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Mid-America Regional Council, KS and MO Climate Action Champions: Mid-America Regional Council, KS and MO The Mid-America Regional Council (MARC) is a nonprofit association of city and county governments and the metropolitan planning organization for the bistate Kansas City region. They provide a forum for the region to work together to advance social, economic and environmental progress. MARC received the Climate Action Champion designation in consortium with the City

  9. Valence and metal/silicate partitioning of Mo: Implications for conditions

    Office of Scientific and Technical Information (OSTI)

    of Earth accretion and core formation (Journal Article) | SciTech Connect Valence and metal/silicate partitioning of Mo: Implications for conditions of Earth accretion and core formation Citation Details In-Document Search Title: Valence and metal/silicate partitioning of Mo: Implications for conditions of Earth accretion and core formation Authors: Righter, K. ; Danielson, L. R. ; Pando, K. M. ; Shofner, G. A. ; Sutton, S. R. ; Newville, M. ; Lee, C. -T. [1] ; UC) [2] ; Rice) [2] + Show

  10. Dynamic Structural Response and Deformations of Monolayer MoS 2 Visualized

    Office of Scientific and Technical Information (OSTI)

    by Femtosecond Electron Diffraction (Journal Article) | SciTech Connect SciTech Connect Search Results Journal Article: Dynamic Structural Response and Deformations of Monolayer MoS 2 Visualized by Femtosecond Electron Diffraction Citation Details In-Document Search Title: Dynamic Structural Response and Deformations of Monolayer MoS 2 Visualized by Femtosecond Electron Diffraction Authors: Mannebach, Ehren M. ; Li, Renkai ; Duerloo, Karel-Alexander ; Nyby, Clara ; Zalden, Peter ; Vecchione,

  11. U-EXTRACTION--IMPROVEMENTS IN ELIMINATION OF Mo BY USE OF FERRIC ION

    DOE Patents [OSTI]

    Clark, H.M.; Duffey, D.

    1958-06-10

    An improved solvent extraction process is described whereby U may be extracted by a water immiscible organic solvent from an aqueous solution of uranyl nitrate. It has been found that Mo in the presence of phosphate ions appears to form a complex with the phosphate which extracts along with the U. This extraction of Mo may be suppressed by providing ferric ion in the solution prior to the extraction step. The ferric ion is preferably provided in the form of ferric nitrate.

  12. Rotationally Commensurate Growth of MoS[subscript 2] on Epitaxial Graphene

    Office of Scientific and Technical Information (OSTI)

    (Journal Article) | SciTech Connect Rotationally Commensurate Growth of MoS[subscript 2] on Epitaxial Graphene Citation Details In-Document Search Title: Rotationally Commensurate Growth of MoS[subscript 2] on Epitaxial Graphene Authors: Liu, Xiaolong ; Balla, Itamar ; Bergeron, Hadallia ; Campbell, Gavin P. ; Bedzyk, Michael J. ; Hersam, Mark C. [1] + Show Author Affiliations NWU Publication Date: 2016-03-04 OSTI Identifier: 1240188 Resource Type: Journal Article Resource Relation: Journal

  13. High reflectance and low stress Mo2C/Be multilayers

    DOE Patents [OSTI]

    Bajt, Sasa; Barbee, Jr., Troy W.

    2001-01-01

    A material for extreme ultraviolet (EUV) multilayers that will reflect at about 11.3 nm, have a high reflectance, low stress, and high thermal and radiation stability. The material consists of alternating layers of Mo.sub.2 C and Be deposited by DC magnetron sputtering on a substrate, such as silicon. In one example a Mo.sub.2 C/Be multilayer gave 65.2% reflectance at 11.25 nm measured at 5 degrees off normal incidence angle, and consisted of 70 bilayers with a deposition period of 5.78 nm, and was deposited at 0.83 mTorr argon (Ar) sputtering pressure, with the first and last layers being Be. The stress of the multilayer is tensile and only +88 MPa, compared to +330 MPa of a Mo/Be multilayers of the same thickness. The Mo.sub.2 C/Be multilayer was capped with carbon which produced an increase in reflectivity of about 7% over a similar multilayer with no carbon capping material, thus raising the reflectivity from 58.3% to over 65%. The multilayers were formed using either Mo.sub.2 C or Be as the first and last layers, and initial testing has shown the formation of beryllium carbide at the interfaces between the layers which both stabilizes and has a smoothing effect, and appear to be smoother than the interfaces in Mo/Be multilayers.

  14. Thermal stability of intermetallic phases in Fe-rich Fe-Cr-Ni-Mo alloys

    SciTech Connect (OSTI)

    Yang, Ying; Tan, Lizhen; Busby, Jeremy T.

    2015-06-12

    Understanding the stability of precipitate phases in the Fe-rich Fe-Cr-Ni-Mo alloys is critical to the alloy design and application of Mo-containing Austenitic steels. Coupled with thermodynamic modeling, stability of the chi and Laves phases in two Fe-Cr-Ni-Mo alloys were investigated at 1000, 850 and 700 °C for different annealing time. The morphologies, compositions and crystal structures of the matrix and precipitate phases were carefully examined by Scanning Electron Microscopy, Electron Probe Microanalysis, X-ray diffraction and Transmission Electron Microscopy. The two key findings resulted from this work. One is that the chi phase is stable at high temperature and transformed into the Laves phase at low temperature. The other is that both the chi and Laves phases have large solubilites of Cr, Mo and Ni, among which the Mo solubility has a major role on the relative stability of the precipitate phases. The developed thermodynamic models were then applied to evaluating the Mo effect on the stability of precipitate phases in AISI 316 and NF709 alloys.

  15. Stability of precipitate phases in Fe-rich Fe-Cr-Ni-Mo alloys

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yang, Ying; Tan, Lizhen; Busby, Jeremy T

    2015-01-01

    Understanding the stability of precipitate phases in the Fe-rich Fe-Cr-Ni-Mo alloys is critical to the alloy design and application of Mo-containing Austenitic steels. Coupled with thermodynamic modeling, stability of the and phases in two Fe-Cr-Ni-Mo alloys were investigated at 1000, 850 and 700 C for different annealing time. The morphologies, compositions and crystal structures of the matrix and precipitate phases were carefully examined by Scanning Electron Microscopy, Electron Probe Microanalysis, X-ray diffraction and Transmission Electron Microscopy. Two key findings resulted from this work. One is that the phase is stable at high temperature and transformed into the phase at lowmoretemperature. The other is that both the and phases have large solubilites of Cr, Mo and Ni, among which the Mo solubility has a major role on the relative stability of the precipitate phases. The developed thermodynamic models were then applied to evaluating the Mo effect on the stability of precipitate phases in AISI 316 and NF709 alloys.less

  16. Thermal stability of intermetallic phases in Fe-rich Fe-Cr-Ni-Mo alloys

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yang, Ying; Tan, Lizhen; Busby, Jeremy T.

    2015-06-12

    Understanding the stability of precipitate phases in the Fe-rich Fe-Cr-Ni-Mo alloys is critical to the alloy design and application of Mo-containing Austenitic steels. Coupled with thermodynamic modeling, stability of the chi and Laves phases in two Fe-Cr-Ni-Mo alloys were investigated at 1000, 850 and 700 °C for different annealing time. The morphologies, compositions and crystal structures of the matrix and precipitate phases were carefully examined by Scanning Electron Microscopy, Electron Probe Microanalysis, X-ray diffraction and Transmission Electron Microscopy. The two key findings resulted from this work. One is that the chi phase is stable at high temperature and transformed intomore » the Laves phase at low temperature. The other is that both the chi and Laves phases have large solubilites of Cr, Mo and Ni, among which the Mo solubility has a major role on the relative stability of the precipitate phases. The developed thermodynamic models were then applied to evaluating the Mo effect on the stability of precipitate phases in AISI 316 and NF709 alloys.« less

  17. Effects of thermal treatment on the co-rolled U-Mo fuel foils

    SciTech Connect (OSTI)

    Dennis D. Keiser, Jr.; Tammy L. Trowbridge; Cynthia R. Breckenridge; Brady L. Mackowiak; Glenn A. Moore; Barry H. Rabin; Mitchell K. Meyer

    2014-11-01

    A monolithic fuel type is being developed to convert US high performance research and test reactors such as Advanced Test Reactor (ATR) at Idaho National Laboratory from highly enriched uranium (HEU) to low-enriched uranium (LEU). The interaction between the cladding and the U-Mo fuel meat during fuel fabrication and irradiation is known to have negative impacts on fuel performance, such as mechanical integrity and dimensional stability. In order to eliminate/minimize the direct interaction between cladding and fuel meat, a thin zirconium diffusion barrier was introduced between the cladding and U-Mo fuel meat through a co-rolling process. A complex interface between the zirconium and U-Mo was developed during the co-rolling process. A predictable interface between zirconium and U-Mo is critical to achieve good fuel performance since the interfaces can be the weakest link in the monolithic fuel system. A post co-rolling annealing treatment is expected to create a well-controlled interface between zirconium and U-Mo. A systematic study utilizing post co-rolling annealing treatment has been carried out. Based on microscopy results, the impacts of the annealing treatment on the interface between zirconium and U-Mo will be presented and an optima annealing treatment schedule will be suggested. The effects of the annealing treatment on the fuel performance will also be discussed.

  18. Construction of the Barut–Girardello quasi coherent states for the Morse potential

    SciTech Connect (OSTI)

    Popov, Dušan; Dong, Shi-Hai; Pop, Nicolina; Sajfert, Vjekoslav; Şimon, Simona

    2013-12-15

    The Morse oscillator (MO) potential occupies a privileged place among the anharmonic oscillator potentials due to its applications in quantum mechanics to diatomic or polyatomic molecules, spectroscopy and so on. For this potential some kinds of coherent states (especially of the Klauder–Perelomov and Gazeau–Klauder kinds) have been constructed previously. In this paper we construct the coherent states of the Barut–Girardello kind (BG-CSs) for the MO potential, which have received less attention in the scientific literature. We obtain these CSs and demonstrate that they fulfil all conditions required by the coherent state. The Mandel parameter for the pure BG-CSs and Husimi’s and P-quasi distribution functions (for the mixed-thermal states) are also presented. Finally, we show that all obtained results for the BG-CSs of MO tend, in the harmonic limit, to the corresponding results for the coherent states of the one dimensional harmonic oscillator (CSs for the HO-1D). -- Highlights: •Construct the coherent states of the Barut–Girardello kind (BG-CSs) for the MO potential. •They fulfil all the conditions needed to a coherent state. •Present the Mandel parameter and Husimi’s and P-quasi distribution functions. •All results tend to those for the one dimensional harmonic oscillator in its harmonic limit.

  19. Using Qualified Energy Conservation Bonds (QECBs) to Fund a Residential Energy Efficiency Loan Program: Case Study on Saint Louis County, MO

    SciTech Connect (OSTI)

    Zimring, Mark

    2011-06-23

    Qualified Energy Conservation Bonds (QECBs) are federally-subsidized debt instruments that enable state, tribal, and local government issuers to borrow money to fund a range of qualified energy conservation projects. QECBs offer issuers very attractive borrowing rates and long terms, and can fund low-interest energy efficiency loans for home and commercial property owners. Saint Louis County, MO recently issued over $10 million of QECBs to finance the Saint Louis County SAVES residential energy efficiency loan program. The county's experience negotiating QECB regulations and restrictions can inform future issuers.

  20. Doping against the native propensity of MoS₂: Degenerate hole doping by cation substitution

    SciTech Connect (OSTI)

    Suh, Joonki; Park, Tae-Eon; Lin, Der-Yuh; Fu, Deyi; Park, Joonsuk; Jung, Hee Joon; Chen, Yabin; Ko, Changhyun; Jang, Chaun; Sun, Yinghui; Sinclair, Robert; Chang, Joonyeon; Tongay, Sefaattin; Wu, Junqiao

    2014-12-10

    Layered transition metal dichalcogenides (TMDs) draw much attention as the key semiconducting material for two-dimensional electrical, optoelectronic, and spintronic devices. For most of these applications, both n- and p-type materials are needed to form junctions and support bipolar carrier conduction. However, typically only one type of doping is stable for a particular TMD. For example, molybdenum disulfide (MoS₂) is natively an n-type presumably due to omnipresent electron-donating sulfur vacancies, and stable/controllable p-type doping has not been achieved. The lack of p-type doping hampers the development of charge-splitting p–n junctions of MoS₂, as well as limits carrier conduction to spin-degenerate conduction bands instead of the more interesting, spin-polarized valence bands. Traditionally, extrinsic p-type doping in TMDs has been approached with surface adsorption or intercalation of electron-accepting molecules. However, practically stable doping requires substitution of host atoms with dopants where the doping is secured by covalent bonding. In this work, we demonstrate stable p-type conduction in MoS₂ by substitutional niobium (Nb) doping, leading to a degenerate hole density of ~3 × 10¹⁹ cm⁻³. Structural and X-ray techniques reveal that the Nb atoms are indeed substitutionally incorporated into MoS₂ by replacing the Mo cations in the host lattice. van der Waals p–n homojunctions based on vertically stacked MoS₂ layers are fabricated, which enable gate-tunable current rectification. A wide range of microelectronic, optoelectronic, and spintronic devices can be envisioned from the demonstrated substitutional bipolar doping of MoS₂. From the miscibility of dopants with the host, it is also expected that the synthesis technique demonstrated here can be generally extended to other TMDs for doping against their native unipolar propensity.

  1. Propane ammoxidation over the Mo-V-Te-Nb-O M1 phase: Reactivity of surface cations in hydrogen abstraction steps

    SciTech Connect (OSTI)

    Muthukumar, Kaliappan; Yu, Junjun; Xu, Ye; Guliants, Vadim V.

    2011-01-01

    Density functional theory calculations (GGA-PBE) have been performed to investigate the adsorption of C3 (propane, isopropyl, propene, and allyl) and H species on the proposed active center present in the surface ab planes of the bulk Mo-V-Te-Nb-O M1 phase in order to better understand the roles of the different surface cations in propane ammoxidation. Modified cluster models were employed to isolate the closely spaced V=O and Te=O from each other and to vary the oxidation state of the V cation. While propane and propene adsorb with nearly zero adsorption energy, the isopropyl and allyl radicals bind strongly to V=O and Te=O with adsorption energies, {Delta}E, being {le} -1.75 eV, but appreciably more weakly on other sites, such as Mo=O, bridging oxygen (Mo-O-V and Mo-O-Mo), and empty metal apical sites ({Delta}E > -1 eV). Atomic H binds more strongly to Te = O ({Delta}E {le} -3 eV) than to all the other sites, including V = O ({Delta}E = -2.59 eV). The reduction of surface oxo groups by dissociated H and their removal as water are thermodynamically favorable except when both H atoms are bonded to the same Te=O. Consistent with the strong binding of H, Te=O is markedly more active at abstracting the methylene H from propane (E{sub a} {le} 1.01 eV) than V = O (E{sub a} = 1.70 eV on V{sup 5+} = O and 2.13 eV on V{sup 4+} = O). The higher-than-observed activity and the loose binding of Te = O moieties to the mixed metal oxide lattice of M1 raise the question of whether active Te = O groups are in fact present in the surface ab planes of the M1 phase under propane ammoxidation conditions.

  2. In Situ Time-Resolved Characterization of Ni-MoO2 Catalysts for the Water-Gas Shift Reaction

    SciTech Connect (OSTI)

    Wen,W.; Calderon, J.; Brito, J.; Marinkovic, N.; Hanson, J.; Rodriquez, J.

    2008-01-01

    Active catalysts for the water-gas shift (WGS, CO + H2O ? H2 + CO2) reaction were synthesized from nickel molybdates ({beta}-NiMoO4 and nH2O{center_dot}NiMoO4) as precursors, and their structural transformations were monitored using in situ time-resolved X-ray diffraction and X-ray absorption near-edge spectroscopy. In general, the nickel molybdates were not stable and underwent partial reduction in the presence of CO or CO/H2O mixtures at high temperatures. The interaction of {beta}-NiMoO4 with the WGS reactants at 500 C led to the formation of a mixture of Ni (24 nm particle size) and MoO2 (10 nm particle size). These Ni-MoO2 systems displayed good catalytic activity at 350, 400, and 500 C. At 350 and 400 C, catalytic tests revealed that the Ni-MoO2 system was much more active than isolated Ni (some activity) or isolated MoO2 (negligible activity). Thus, cooperative interactions between the admetal and oxide support were probably responsible for the high WGS activity of Ni-MoO2. In a second synthetic approach, the NiMoO4 hydrate was reduced to a mixture of metallic Ni, NiO, and amorphous molybdenum oxide by direct reaction with H2 gas at 350 C. In the first pass of the water-gas shift reaction, MoO2 appeared gradually at 500 C with a concurrent increase of the catalytic activity. For these catalysts, the particle size of Ni (4 nm) was much smaller than that of the MoO2 (13 nm). These systems were found to be much more active WGS catalysts than Cu-MoO2, which in turn is superior to commercial low-temperature Cu-ZnO catalysts.

  3. Hopping conduction in p-type MoS{sub 2} near the critical regime of the

    Office of Scientific and Technical Information (OSTI)

    metal-insulator transition (Journal Article) | SciTech Connect Hopping conduction in p-type MoS{sub 2} near the critical regime of the metal-insulator transition Citation Details In-Document Search Title: Hopping conduction in p-type MoS{sub 2} near the critical regime of the metal-insulator transition We report on temperature-dependent charge and magneto transport of chemically doped MoS{sub 2}, p-type molybdenum disulfide degenerately doped with niobium (MoS{sub 2}:Nb). The temperature

  4. Method for the production of {sup 99m}Tc compositions from {sup 99}Mo-containing materials

    DOE Patents [OSTI]

    Bennett, R.G.; Christian, J.D.; Grover, S.B.; Petti, D.A.; Terry, W.K.; Yoon, W.Y.

    1998-09-01

    An improved method is described for producing {sup 99m}Tc compositions from {sup 99}Mo compounds. {sup 100}Mo metal or {sup 100}MoO{sub 3} is irradiated with photons in a particle (electron) accelerator to ultimately produce {sup 99}MoO{sub 3}. This composition is then heated in a reaction chamber to form a pool of molten {sup 99}MoO{sub 3} with an optimum depth of 0.5--5 mm. A gaseous mixture thereafter evolves from the molten {sup 99}MoO{sub 3} which contains vaporized {sup 99}MoO{sub 3}, vaporized {sup 99m}TcO{sub 3}, and vaporized {sup 99m}TcO{sub 2}. This mixture is then combined with an oxidizing gas (O{sub 2(g)}) to generate a gaseous stream containing vaporized {sup 99m}Tc{sub 2}O{sub 7} and vaporized {sup 99}MoO{sub 3}. Next, the gaseous stream is cooled in a primary condensation stage in the reaction chamber to remove vaporized {sup 99}MoO{sub 3}. Cooling is undertaken at a specially-controlled rate to achieve maximum separation efficiency. The gaseous stream is then cooled in a sequential secondary condensation stage to convert vaporized {sup 99m}Tc{sub 2}O{sub 7} into a condensed {sup 99m}Tc-containing reaction product which is collected. 1 fig.

  5. Method for the production of .sup.99m Tc compositions from .sup.99 Mo-containing materials

    DOE Patents [OSTI]

    Bennett, Ralph G.; Christian, Jerry D.; Grover, S. Blaine; Petti, David A.; Terry, William K.; Yoon, Woo Y.

    1998-01-01

    An improved method for producing .sup.99m Tc compositions from .sup.99 Mo compounds. .sup.100 Mo metal or .sup.100 MoO.sub.3 is irradiated with photons in a particle (electron) accelerator to ultimately produce .sup.99 MoO.sub.3. This composition is then heated in a reaction chamber to form a pool of molten .sup.99 MoO.sub.3 with an optimum depth of 0.5-5 mm. A gaseous mixture thereafter evolves from the molten .sup.99 MoO.sub.3 which contains vaporized .sup.99 MoO.sub.3, vaporized .sup.99m TcO.sub.3, and vaporized .sup.99m TcO.sub.2. This mixture is then combined with an oxidizing gas (O.sub.2(g)) to generate a gaseous stream containing vaporized .sup.99m Tc.sub.2 O.sub.7 and vaporized .sup.99 MoO.sub.3. Next, the gaseous stream is cooled in a primary condensation stage in the reaction chamber to remove vaporized .sup.99 MoO.sub.3. Cooling is undertaken at a specially-controlled rate to achieve maximum separation efficiency. The gaseous stream is then cooled in a sequential secondary condensation stage to convert vaporized .sup.99m Tc.sub.2 O.sub.7 into a condensed .sup.99m Tc-containing reaction product which is collected.

  6. TEM Characterization of High Burn-up Microstructure of U-7Mo Alloy

    SciTech Connect (OSTI)

    Jian Gan; Brandon Miller; Dennis Keiser; Adam Robinson; James Madden; Pavel Medvedev; Daniel Wachs

    2014-04-01

    As an essential part of global nuclear non-proliferation effort, the RERTR program is developing low enriched U-Mo fuels (< 20% U-235) for use in research and test reactors that currently employ highly enriched uranium fuels. One type of fuel being developed is a dispersion fuel plate comprised of U-7Mo particles dispersed in Al alloy matrix. Recent TEM characterizations of the ATR irradiated U-7Mo dispersion fuel plates include the samples with a local fission densities of 4.5, 5.2, 5.6 and 6.3 E+21 fissions/cm3 and irradiation temperatures of 101-136?C. The development of the irradiated microstructure of the U-7Mo fuel particles consists of fission gas bubble superlattice, large gas bubbles, solid fission product precipitates and their association to the large gas bubbles, grain subdivision to tens or hundreds of nanometer size, collapse of bubble superlattice, and amorphisation. This presentation will describe the observed microstructures specifically focusing on the U-7Mo fuel particles. The impact of the observed microstructure on the fuel performance and the comparison of the relevant features with that of the high burn-up UO2 fuels will be discussed.

  7. FeAl and Mo-Si-B Intermetallic Coatings Prepared by Thermal Spraying

    SciTech Connect (OSTI)

    Totemeier, T.C.; Wright, R.N.; Swank, W.D.

    2003-04-22

    FeAl and Mo-Si-B intermetallic coatings for elevated temperature environmental resistance were prepared using high-velocity oxy-fuel (HVOF) and air plasma spray (APS) techniques. For both coating types, the effect of coating parameters (spray particle velocity and temperature) on the microstructure and physical properties of the coatings was assessed. Fe-24Al (wt.%) coatings were prepared using HVOF thermal spraying at spray particle velocities varying from 540 m/s to 700 m/s. Mo-13.4Si-2.6B coatings were prepared using APS at particle velocities of 180 and 350 m/s. Residual stresses in the HVOF FeAl coatings were compressive, while stresses in the APS Mo-Si-B coatings were tensile. In both cases, residual stresses became more compressive with increasing spray particle velocity due to increased peening imparted by the spray particles. The hardness and elastic moduli of FeAl coatings also increased with increasing particle velocity, again due to an increased peening effect. For Mo-Si-B coatings, plasma spraying at 180 m/s resulted in significant oxidation of the spray particles and conversion of the T1 phase into amorphous silica and {alpha}-Mo. The T1 phase was retained after spraying at 350 m/s.

  8. Surface oxidation energetics and kinetics on MoS{sub 2} monolayer

    SciTech Connect (OSTI)

    KC, Santosh; Longo, Roberto C.; Wallace, Robert M.; Cho, Kyeongjae

    2015-04-07

    In this work, surface oxidation of monolayer MoS{sub 2} (one of the representative semiconductors in transition-metal dichalcogenides) has been investigated using density functional theory method. Oxygen interaction with MoS{sub 2} shows that, thermodynamically, the surface tends to be oxidized. However, the dissociative absorption of molecular oxygen on the MoS{sub 2} surface is kinetically limited due to the large energy barrier at low temperature. This finding elucidates the air stability of MoS{sub 2} surface in the atmosphere. Furthermore, the presence of defects significantly alters the surface stability and adsorption mechanisms. The electronic properties of the oxidized surface have been examined as a function of oxygen adsorption and coverage as well as substitutional impurities. Our results on energetics and kinetics of oxygen interaction with the MoS{sub 2} monolayer are useful for the understanding of surface oxidation, air stability, and electronic properties of transition-metal dichalcogenides at the atomic scale.

  9. Fragile structural transition in Mo3Sb7

    SciTech Connect (OSTI)

    Yan, Jiaqiang -Q.; McGuire, Michael A; May, Andrew F; Parker, David S.; Mandrus, D. G.; Sales, Brian C.

    2015-08-10

    Mo3Sb7 single crystals lightly doped with Cr, Ru, or Te are studied in order to explore the interplay between superconductivity, magnetism, and the cubic-tetragonal structural transition. The structural transition at 53 K is extremely sensitive to Ru or Te substitution which introduces additional electrons, but robust against Cr substitution. We observed no sign of a structural transition in superconducting Mo2.91Ru0.09Sb7 and Mo3Sb6.975Te0.025. In contrast, 3 at.% Cr doping only slightly suppresses the structural transition to 48 K while leaving no trace of superconductivity above 1.8 K. Analysis of magnetic properties suggests that the interdimer interaction in Mo3Sb7 is near a critical value and essential for the structural transition. Futhermore, all dopants suppress the superconductivity of Mo3Sb7. The tetragonal structure is not necessary for superconductivity.

  10. Elementary Steps of Syngas Reactions on Mo2C(001): Adsorption Thermochemistry and Bond Dissociation

    SciTech Connect (OSTI)

    Medford, Andrew

    2012-02-16

    Density functional theory (DFT) and ab initio thermodynamics are applied in order to investigate the most stable surface and subsurface terminations of Mo{sub 2}C(001) as a function of chemical potential and in the presence of syngas. The Mo-terminated (001) surface is then used as a model surface to evaluate the thermochemistry and energetic barriers for key elementary steps in syngas reactions. Adsorption energy scaling relations and Broensted-Evans-Polanyi relationships are established and used to place Mo{sub 2}C into the context of transition metal surfaces. The results indicate that the surface termination is a complex function of reaction conditions and kinetics. It is predicted that the surface will be covered by either C{sub 2}H{sub 2} or O depending on conditions. Comparisons to transition metals indicate that the Mo-terminated Mo{sub 2}C(001) surface exhibits carbon reactivity similar to transition metals such as Ru and Ir, but is significantly more reactive towards oxygen.

  11. Neutron Diffraction Measurement of Residual Stresses, Dislocation Density and Texture in Zr-bonded U-10Mo ''Mini'' Fuel Foils and Plates

    SciTech Connect (OSTI)

    Brown, Donald W.; Okuniewski, M. A.; Sisneros, Thomas A.; Clausen, Bjorn; Moore, G. A.; Balogh, L

    2014-08-07

    Aluminum clad monolithic uranium 10 weight percent molybdenum (U-10Mo) fuel plates are being considered for conversion of several research and test nuclear reactors from high-enriched to low-enriched uranium fuel due to the inherently high density of fissile material. Comprehensive neutron diffraction measurements of the evolution of the textures, residual phase stresses, and dislocation densities in the individual phases of the mini-foils throughout several processing steps and following hot-isostatic pressing to the Al cladding, have been completed. Recovery and recrystallization of the bare U-10Mo fuel foil, as indicated by the dislocation density and texture, are observed depending on the state of the material prior to annealing and the duration and temperature of the annealing process. In general, the HIP procedure significantly reduces the dislocation density, but the final state of the clad plate, both texture and dislocation density, depends strongly on the final processing step of the fuel foil. In contrast, the residual stresses in the clad fuel plate do not depend strongly on the final processing step of the bare foil prior to HIP bonding. Rather, the residual stresses are dominated by the thermal expansion mismatch of the constituent materials of the fuel plate.

  12. Thermal stability of fission gas bubble superlattice in irradiated U10Mo fuel

    SciTech Connect (OSTI)

    Gan, J.; Keiser, D. D.; Miller, B. D.; Robinson, A. B.; Wachs, D. M.; Meyer, M. K.

    2015-09-01

    To investigate the thermal stability of the fission gas bubble superlattice, a key microstructural feature in both irradiated U-7Mo dispersion and U-10Mo monolithic fuel plates, a FIB-TEM sample of the irradiated U-10Mo fuel with a local fission density of 3.51021 fissions/cm3 was used for an in-situ heating TEM experiment. The temperature of the heating holder was raised at a ramp rate of approximately 10 C/min up to ~700 C, kept at that temperature for about 34 min, continued to 850 C with a reduced rate of 5 C/min. The result shows a high thermal stability of the fission gas bubble superlattice. The implication of this observation on the fuel microstructural evolution and performance under irradiation is discussed.

  13. Highly conducting SrMoO{sub 3} thin films for microwave applications

    SciTech Connect (OSTI)

    Radetinac, Aldin Mani, Arzhang; Ziegler, Jrgen; Alff, Lambert; Komissinskiy, Philipp; Melnyk, Sergiy; Nikfalazar, Mohammad; Zheng, Yuliang; Jakoby, Rolf

    2014-09-15

    We have measured the microwave resistance of highly conducting perovskite oxide SrMoO{sub 3} thin film coplanar waveguides. The epitaxial SrMoO{sub 3} thin films were grown by pulsed laser deposition and showed low mosaicity and smooth surfaces with a root mean square roughness below 0.3?nm. Layer-by-layer growth could be achieved for film thicknesses up to 400?nm as monitored by reflection high-energy electron diffraction and confirmed by X-ray diffraction. We obtained a constant microwave resistivity of 29???cm between 0.1 and 20?GHz by refining the frequency dependence of the transmission coefficients. Our result shows that SrMoO{sub 3} is a viable candidate as a highly conducting electrode material for all-oxide microwave electronic devices.

  14. Controlling the metal to semiconductor transition of MoS2 and WS2 in solution

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Chou, Stanley Shihyao; Yi-Kai Huang; Kim, Jaemyung; Kaehr, Bryan James; Foley, Brian M.; Lu, Ping; Conner Dykstra; Hopkins, Patrick E.; Brinker, C. Jeffrey; Jiaxing Huang; et al

    2015-01-22

    Lithiation-exfoliation produces single to few-layered MoS2 and WS2 sheets dispersible in water. However, the process transforms them from the pristine semiconducting 2H phase to a distorted metallic phase. Recovery of the semiconducting properties typically involves heating of the chemically exfoliated sheets at elevated temperatures. Therefore, it has been largely limited to sheets deposited on solid substrates. We report the dispersion of chemically exfoliated MoS2 sheets in high boiling point organic solvents enabled by surface functionalization and the controllable recovery of their semiconducting properties directly in solution. Ultimately, this process connects the scalability of chemical exfoliation with the simplicity of solutionmore » processing, enabling a facile method for tuning the metal to semiconductor transitions of MoS2 and WS2 within a liquid medium.« less

  15. Electronic and magnetic properties of Mo doped graphene; full potential approach

    SciTech Connect (OSTI)

    Thakur, Jyoti Kashyap, Manish K.; Singh, Mukhtiyar; Saini, Hardev S.

    2015-05-15

    The electronic and magnetic properties of Pristine and Mo doped Graphene have been calculated using WIEN2k implementation of full potential linearized augmented plane wave (FPLAPW) method based on Density Functional Theory (DFT). The exchange and correlation (XC) effects were taken into account by generalized gradient approximation (GGA). The calculated results show that Mo doping creates magnetism in Graphene by shifting the energy levels at E{sub F} and opens up a channel for Graphene to be used in real nanoscale device applications. The unpaired d-electrons of Mo atom are responsible for induced magnetism in Graphene. Magnetic ordering created in Graphene in this way makes it suitable for recording media, magnetic sensors, magnetic inks and spintronic devices.

  16. Thermal aging modeling and validation on the Mo containing Fe-Cr-Ni alloys

    SciTech Connect (OSTI)

    Yang, Ying; Tan, Lizhen; Busby, Jeremy T.

    2015-04-01

    Thermodynamics of intermetallic phases in Fe-rich Fe-Cr-Ni-Mo alloys is critical knowledge to understand thermal aging effect on the phase stability of Mo-containing austenitic steels, which subsequently facilitates alloy design/improvement and degradation mitigation of these materials for reactor applications. Among the intermetallic phases, Chi (χ), Laves, and Sigma (σ) are often of concern because of their tendency to cause embrittlement of the materials. The focus of this study is thermal stability of the Chi and Laves phases as they were less studied compared to the Sigma phase. Coupled with thermodynamic modeling, thermal stability of intermetallic phases in Mo containing Fe-Cr-Ni alloys was investigated at 1000, 850 and 700 C for different annealing times. The morphologies, compositions and crystal structures of the precipitates of the intermetallic phases were carefully examined by scanning electron microscopy, electron probe microanalysis, X-ray diffraction, and transmission electron microscopy. Three key findings resulted from this study. First, the Chi phase is stable at high temperature, and with decreasing temperature it transforms into the Laves phase that is stable at low temperature. Secondly, Cr, Mo, Ni are soluble in both the Chi and Laves phases, with the solubility of Mo playing a major role in the relative stability of the intermetallic phases. Thirdly, in situ transformation from Chi phase to Laves phase was directly observed, which increased the local strain field, generated dislocations in the intermetallic phases, and altered the precipitate phase orientation relationship with the austenitic matrix. The thermodynamic models that were developed and validated were then applied to evaluating the effect of Mo on the thermal stability of intermetallic phases in type 316 and NF709 stainless steels.

  17. Two-step growth of two-dimensional WSe2/MoSe2 heterostructures

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Gong, Yongji; Lei, Sidong; Lou, Jun; Liu, Zheng; Vajtai, Robert; Zhou, Wu; Ajayan, Pullikel M.

    2015-08-03

    Two dimensional (2D) materials have attracted great attention due to their unique properties and atomic thickness. Although various 2D materials have been successfully synthesized with different optical and electrical properties, a strategy for fabricating 2D heterostructures must be developed in order to construct more complicated devices for practical applications. Here we demonstrate for the first time a two-step chemical vapor deposition (CVD) method for growing transition-metal dichalcogenide (TMD) heterostructures, where MoSe2 was synthesized first and followed by an epitaxial growth of WSe2 on the edge and on the top surface of MoSe2. Compared to previously reported one-step growth methods, thismore » two-step growth has the capability of spatial and size control of each 2D component, leading to much larger (up to 169 μm) heterostructure size, and cross-contamination can be effectively minimized. Furthermore, this two-step growth produces well-defined 2H and 3R stacking in the WSe2/MoSe2 bilayer regions and much sharper in-plane interfaces than the previously reported MoSe2/WSe2 heterojunctions obtained from one-step growth methods. The resultant heterostructures with WSe2/MoSe2 bilayer and the exposed MoSe2 monolayer display rectification characteristics of a p-n junction, as revealed by optoelectronic tests, and an internal quantum efficiency of 91% when functioning as a photodetector. As a result, a photovoltaic effect without any external gates was observed, showing incident photon to converted electron (IPCE) efficiencies of approximately 0.12%, providing application potential in electronics and energy harvesting.« less

  18. SEM and TEM Characterization of As-Fabricated U-7Mo Disperson Fuel Plates

    SciTech Connect (OSTI)

    D. D. Keiser, Jr.; B. Yao; E. Perez; Y. H. Sohn

    2009-11-01

    The starting microstructure of a dispersion fuel plate can have a dramatic impact on the overall performance of the plate during irradiation. To improve the understanding of the as-fabricated microstructures of dispersion fuel plates, SEM and TEM analysis have been performed on RERTR-9A archive fuel plates, which went through an additional hot isostatic procsssing (HIP) step during fabrication. The fuel plates had depleted U-7Mo fuel particles dispersed in either Al-2Si or 4043 Al alloy matrix. For the characterized samples, it was observed that a large fraction of the ?-phase U-7Mo alloy particles had decomposed during fabrication, and in areas near the fuel/matrix interface where the transformation products were present significant fuel/matrix interaction had occurred. Relatively thin Si-rich interaction layers were also observed around the U-7Mo particles. In the thick interaction layers, (U)(Al,Si)3 and U6Mo4Al43 were identified, and in the thin interaction layers U(Al,Si)3, U3Si3Al2, U3Si5, and USi1.88-type phases were observed. The U3Si3Al2 phase contained some Mo. Based on the results of this work, exposure of dispersion fuel plates to relatively high temperatures during fabrication impacts the overall microstructure, particularly the nature of the interaction layers around the fuel particles. The time and temperature of fabrication should be carefully controlled in order to produce the most uniform Si-rich layers around the U-7Mo particles.

  19. Electrical and photovoltaic characteristics of MoS{sub 2}/Si p-n junctions

    SciTech Connect (OSTI)

    Hao, Lanzhong Liu, Yunjie Gao, Wei; Han, Zhide; Xue, Qingzhong; Zeng, Huizhong; Wu, Zhipeng; Zhu, Jun; Zhang, Wanli

    2015-03-21

    Bulk-like molybdenum disulfide (MoS{sub 2}) thin films were deposited on the surface of p-type Si substrates using dc magnetron sputtering technique and MoS{sub 2}/Si p-n junctions were formed. The vibrating modes of E{sup 1}{sub 2g} and A{sub 1g} were observed from the Raman spectrum of the MoS{sub 2} films. The current density versus voltage (J-V) characteristics of the junction were investigated. A typical J-V rectifying effect with a turn-on voltage of 0.2?V was shown. In different voltage range, the electrical transporting of the junction was dominated by diffusion current and recombination current, respectively. Under the light illumination of 15?mW?cm{sup ?2}, the p-n junction exhibited obvious photovoltaic characteristics with a short-circuit current density of 3.2?mA?cm{sup ?2} and open-circuit voltage of 0.14?V. The fill factor and energy conversion efficiency were 42.4% and 1.3%, respectively. According to the determination of the Fermi-energy level (?4.65?eV) and energy-band gap (?1.45?eV) of the MoS{sub 2} films by capacitance-voltage curve and ultraviolet-visible transmission spectra, the mechanisms of the electrical and photovoltaic characteristics were discussed in terms of the energy-band structure of the MoS{sub 2}/Si p-n junctions. The results hold the promise for the integration of MoS{sub 2} thin films with commercially available Si-based electronics in high-efficient photovoltaic devices.

  20. Topological degeneracy of non-Abelian states for dummies (Journal Article)

    Office of Scientific and Technical Information (OSTI)

    | SciTech Connect Topological degeneracy of non-Abelian states for dummies Citation Details In-Document Search Title: Topological degeneracy of non-Abelian states for dummies We present a physical construction of degenerate groundstates of the Moore-Read Pfaffian states, which exhibits non-Abelian statistics, on general Riemann surface with genus g. The construction is given by a generalization of the recent argument [M.O., T. Senthil, Phys. Rev. Lett. 96 (2006) 060601] which relates

  1. Syntheses, structure and rare earth metal photoluminescence of new and known isostructural A{sub 2}Mo{sub 4}Sb{sub 2}O{sub 18} (A=Ce, Pr, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu) compounds

    SciTech Connect (OSTI)

    Mohitkar, Shrikant A.; Kalpana, G.; Vidyasagar, K.

    2011-04-15

    Nine new A{sub 2}Mo{sub 4}Sb{sub 2}O{sub 18} (A=Ce, Pr, Eu, Tb, Ho, Er, Tm, Yb, Lu) compounds have been synthesized by solid-state reactions. They are isostructural with six reported analogues of yttrium and other lanthanides and the monoclinic unit cell parameters of all fifteen of them vary linearly with the size of A{sup 3+} ion. Single crystal X-ray structures of eight A{sub 2}Mo{sub 4}Sb{sub 2}O{sub 18} (A=Ce, Pr, Eu, Gd, Tb, Ho, Er, Tm) compounds have been determined. Neat A{sub 2}Mo{sub 4}Sb{sub 2}O{sub 18} (A=Pr, Sm, Eu, Tb, Dy, Ho, Er, Tm) compounds exhibit characteristic rare earth metal photoluminescence. -- Graphical abstract: Among the fifteen isostructural A{sub 2}Mo{sub 4}Sb{sub 2}O{sub 18} (A=rare earth metal) molybdoantimonites, eight (A=Pr, Sm, Eu, Tb, Dy, Ho, Er, Tm) compounds exhibit neat characteristic lanthanide photoluminescence in the 200-800 nm range at room temperature. Display Omitted Research highlights: {yields} Syntheses of nine new A{sub 2}Mo{sub 4}Sb{sub 2}O{sub 18} (A=Ce, Pr, Eu, Tb, Ho, Er, Tm, Yb, Lu) compounds. {yields} X-ray structures of eight A{sub 2}Mo{sub 4}Sb{sub 2}O{sub 18} (A=Ce, Pr, Eu, Gd, Tb, Ho, Er, Tm) compounds. {yields} Photoluminescence of neat A{sub 2}Mo{sub 4}Sb{sub 2}O{sub 18} (A=Pr, Sm, Eu, Tb, Dy, Ho, Er, Tm) compounds.

  2. Site-dependent free energy barrier for proton reduction on MoS2 edges

    Office of Scientific and Technical Information (OSTI)

    (Journal Article) | SciTech Connect Site-dependent free energy barrier for proton reduction on MoS2 edges Citation Details In-Document Search Title: Site-dependent free energy barrier for proton reduction on MoS2 edges Authors: Choi, W ; Wood, B C ; Schwegler, E ; Ogitsu, T Publication Date: 2013-05-30 OSTI Identifier: 1113397 Report Number(s): LLNL-JRNL-639087 DOE Contract Number: W-7405-ENG-48 Resource Type: Journal Article Resource Relation: Journal Name: Journal of Physical Chemistry C,

  3. Structure and Electronic Properties of MoVO type Mixed-metal Oxides ¿ a

    Office of Scientific and Technical Information (OSTI)

    Combined View by Experiment and Theory (Journal Article) | SciTech Connect Structure and Electronic Properties of MoVO type Mixed-metal Oxides ¿ a Combined View by Experiment and Theory Citation Details In-Document Search Title: Structure and Electronic Properties of MoVO type Mixed-metal Oxides ¿ a Combined View by Experiment and Theory Authors: Chiu, C ; Vogt, T ; Zhao, L ; Genest, A ; Rosch, N Publication Date: 2015-07-01 OSTI Identifier: 1229398 Report Number(s): BNL--111474-2015-JA

  4. Primary arm spacing in chill block melt spun Ni-Mo alloys

    SciTech Connect (OSTI)

    Tewari, S.N.; Glasgow, T.K.

    1986-01-01

    Chill block melt spun ribbons of Ni-Mo binary alloys containing 8.0 to 41.8 wt % Mo have been prepared under carefully controlled processing conditions. The growth velocity has been determined as a function of distance from the quench surface from the observed ribbon thickness dependence on the melt puddle residence time. Primary arm spacings measured at the midribbon thickness locations show a dependence on growth velocity and alloy composition which is expected from dendritic growth models for binary alloys directionally solidified in a positive temperature gradient.

  5. Neutrino-nucleus scattering of {sup 95,97}Mo and {sup 116}Cd

    SciTech Connect (OSTI)

    Ydrefors, E.; Almosly, W.; Suhonen, J.

    2013-12-30

    Accurate knowledge about the nuclear responses to supernova neutrinos for relevant nuclear targets is important both for neutrino detection and for astrophysical applications. In this paper we discuss the cross sections for the charged-current neutrino-nucleus scatterings off {sup 95,97}Mo and {sup 116}Cd. The microscopic quasiparticle-phonon model is adopted for the odd-even nuclei {sup 95,97}Mo. In the case of {sup 116}Cd we present cross sections both for the Bonn one-boson-exchange potential and self-consistent calculations based on modern Skyrme interactions.

  6. Thickness-dependent charge transport in few-layer MoS 2 field-effect

    Office of Scientific and Technical Information (OSTI)

    transistors (Journal Article) | SciTech Connect Thickness-dependent charge transport in few-layer MoS 2 field-effect transistors Citation Details In-Document Search This content will become publicly available on March 10, 2017 Title: Thickness-dependent charge transport in few-layer MoS 2 field-effect transistors Authors: Lin, Ming-Wei ; Kravchenko, Ivan I. ; Fowlkes, Jason ; Li, Xufan ; Puretzky, Alexander A. ; Rouleau, Christopher M. ; Geohegan, David B. ; Xiao, Kai Publication Date:

  7. Measurement of Double-Polarization Asymmetries in the Quasielastic He<mo stretchy='true'>?mo>3<mo stretchy='false'>(mo>e<mo stretchy='false'>?mo><mo>,mo>e<mo>'d stretchy='false'>)mo> Process

    SciTech Connect (OSTI)

    Mihovilovic, M.; Jin, G.; Long, E.; Zhang, Y. -W.; Allada, K.; Anderson, B.; Annand, J. R.M.; Averett, T.; Boeglin, W.; Bradshaw, P.; Camsonne, A.; Canan, M.; Cates, G. D.; Chen, C.; Chen, J. P.; Chudakov, E.; De Leo, R.; Deng, X.; Deltuva, A.; Deur, A.; Dutta, C.; El Fassi, L.; Flay, D.; Frullani, S.; Garibaldi, F.; Gao, H.; Gilad, S.; Gilman, R.; Glamazdin, O.; Golak, J.; Golge, S.; Gomez, J.; Hansen, O.; Higinbotham, D. W.; Holmstrom, T.; Huang, J.; Ibrahim, H.; de Jager, C. W.; Jensen, E.; Jiang, X.; Jones, M.; Kang, H.; Katich, J.; Khanal, H. P.; Kievsky, A.; King, P.; Korsch, W.; LeRose, J.; Lindgren, R.; Lu, H. -J.; Luo, W.; Marcucci, L. E.; Markowitz, P.; Meziane, M.; Michaels, R.; Moffit, B.; Monaghan, P.; Muangma, N.; Nanda, S.; Norum, B. E.; Pan, K.; Parno, D.; Piasetzky, E.; Posik, M.; Punjabi, V.; Puckett, A. J.R.; Qian, X.; Qiang, Y.; Qui, X.; Riordan, S.; Saha, A.; Sauer, P. U.; Sawatzky, B.; Schiavilla, R.; Schoenrock, B.; Shabestari, M.; Shahinyan, A.; Sirca, S.; Skibinski, R.; St John, J.; Subedi, R.; Sulkosky, V.; Tobias, W. A.; Tireman, W.; Urciuoli, G. M.; Viviani, M.; Wang, D.; Wang, K.; Wang, Y.; Watson, J.; Wojtsekhowski, B.; Witala, H.; Ye, Z.; Zhan, X.; Zhang, Y.; Zheng, X.; Zhao, B.; Zhu, L.

    2014-12-05

    We present a precise measurement of double-polarization asymmetries in the 3He(e,e'd) reaction. This particular process is a uniquely sensitive probe of hadron dynamics in 3He and the structure of the underlying electromagnetic currents. The measurements have been performed in and around quasi-elastic kinematics at Q2=0.25(GeV/c)2 for missing momenta up to 270MeV/c. The asymmetries are in fair agreement with the state-of-the-art calculations in terms of their functional dependencies on pm and omega, but are systematically offset. Beyond the region of the quasi-elastic peak, the discrepancies become even more pronounced. Thus, our measurements have been able to reveal deficiencies in the most sophisticated calculations of the three-body nuclear system, and indicate that further refinement in the treatment of their two- and/or three-body dynamics is required.

  8. Measurement of Double-Polarization Asymmetries in the Quasielastic He<mo stretchy='true'>→mo>3<mo stretchy='false'>(mo>e<mo stretchy='false'>→mo><mo>,mo>e<mo>'d stretchy='false'>)mo> Process

    SciTech Connect (OSTI)

    Mihovilovic, M.; Jin, G.; Long, E.; Zhang, Y. -W.; Allada, K.; Anderson, B.; Annand, J. R.M.; Averett, T.; Boeglin, W.; Bradshaw, P.; Camsonne, A.; Canan, M.; Cates, G. D.; Chen, C.; Chen, J. P.; Chudakov, E.; De Leo, R.; Deng, X.; Deltuva, A.; Deur, A.; Dutta, C.; El Fassi, L.; Flay, D.; Frullani, S.; Garibaldi, F.; Gao, H.; Gilad, S.; Gilman, R.; Glamazdin, O.; Golak, J.; Golge, S.; Gomez, J.; Hansen, O.; Higinbotham, D. W.; Holmstrom, T.; Huang, J.; Ibrahim, H.; de Jager, C. W.; Jensen, E.; Jiang, X.; Jones, M.; Kang, H.; Katich, J.; Khanal, H. P.; Kievsky, A.; King, P.; Korsch, W.; LeRose, J.; Lindgren, R.; Lu, H. -J.; Luo, W.; Marcucci, L. E.; Markowitz, P.; Meziane, M.; Michaels, R.; Moffit, B.; Monaghan, P.; Muangma, N.; Nanda, S.; Norum, B. E.; Pan, K.; Parno, D.; Piasetzky, E.; Posik, M.; Punjabi, V.; Puckett, A. J.R.; Qian, X.; Qiang, Y.; Qui, X.; Riordan, S.; Saha, A.; Sauer, P. U.; Sawatzky, B.; Schiavilla, R.; Schoenrock, B.; Shabestari, M.; Shahinyan, A.; Sirca, S.; Skibinski, R.; St John, J.; Subedi, R.; Sulkosky, V.; Tobias, W. A.; Tireman, W.; Urciuoli, G. M.; Viviani, M.; Wang, D.; Wang, K.; Wang, Y.; Watson, J.; Wojtsekhowski, B.; Witala, H.; Ye, Z.; Zhan, X.; Zhang, Y.; Zheng, X.; Zhao, B.; Zhu, L.

    2014-12-05

    We present a precise measurement of double-polarization asymmetries in the 3He(e,e'd) reaction. This particular process is a uniquely sensitive probe of hadron dynamics in 3He and the structure of the underlying electromagnetic currents. The measurements have been performed in and around quasi-elastic kinematics at Q2=0.25(GeV/c)2 for missing momenta up to 270MeV/c. The asymmetries are in fair agreement with the state-of-the-art calculations in terms of their functional dependencies on pm and omega, but are systematically offset. Beyond the region of the quasi-elastic peak, the discrepancies become even more pronounced. Thus, our measurements have been able to reveal deficiencies in the most sophisticated calculations of the three-body nuclear system, and indicate that further refinement in the treatment of their two- and/or three-body dynamics is required.

  9. Persistent photoconductivity in two-dimensional Mo1-xW xSe2–MoSe2 van der Waals heterojunctions

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Puretzky, Alexander A.; Basile, Leonardo; Idrobo, Juan Carlos; Rouleau, Christopher M.; Geohegan, David B.; Xiao, Kai; Li, Xufan; Lin, Ming -Wei; Wang, Kei

    2016-02-16

    Van der Waals (vdW) heterojunctions consisting of vertically-stacked individual or multiple layers of two-dimensional (2D) layered semiconductors, especially the transition metal dichalcogenides (TMDs), are fascinating new artificial solids just nanometers-thin that promise novel optoelectronic functionalities due to the sensitivity of their electronic and optical properties to strong quantum confinement and interfacial interactions. Here, monolayers of n-type MoSe2 and p-type Mo1-xW xSe2–MoSe2 are grown by vapor transport methods, then transferred and stamped to form artificial vdW heterostructures with different interlayer orientations. Atomic-resolution Z-contrast electron microscopy and electron diffraction are used to characterize both the individual monolayers and the atomic registry betweenmore » layers in the bilayer vdW heterostructures. These measurements are compared with photoluminescence and low-frequency Raman spectroscopy, which indicates strong interlayer coupling in heterostructures. Remarkably, the heterojunctions exhibit an unprecedented photoconductivity effect that persists at room temperature for several days. This persistent photoconductivity is shown to be tunable by applying a gate bias that equilibrates the charge distribution. Furthermore, these measurements indicate that such ultrathin vdW heterojunctions can function as rewritable optoelectronic switches or memory elements under time-dependent photo-illumination, an effect which appears promising for new monolayer TMDs-based optoelectronic devices applications.« less

  10. Two-leg SU<mo>(>2n<mo>)> spin ladder: A low-energy effective field theory approach

    SciTech Connect (OSTI)

    Lecheminant, P.; Tsvelik, A. M.

    2015-05-07

    We present a field-theory analysis of a model of two SU(2n)-invariant magnetic chains coupled by a generic interaction preserving time reversal and inversion symmetry. Contrary to the SU(2)-invariant case the zero-temperature phase diagram of such two-leg spin ladder does not contain topological phases. Thus, only generalized Valence Bond Solid phases are stabilized when n > 1 with different wave vectors and ground-state degeneracies. In particular, we find a phase which is made of a cluster of 2n spins put in an SU(2n) singlet state. For n = 3, this cluster phase is relevant to ?Yb ultracold atoms, with an emergent SU(6) symmetry, loaded in a double-well optical lattice.

  11. Single-layer MoS{sub 2} roughness and sliding friction quenching by interaction with atomically flat substrates

    SciTech Connect (OSTI)

    Quereda, J.; Castellanos-Gomez, A.; Agrat, N.; Rubio-Bollinger, G.

    2014-08-04

    We experimentally study the surface roughness and the lateral friction force in single-layer MoS{sub 2} crystals deposited on different substrates: SiO{sub 2}, mica, and hexagonal boron nitride (h-BN). Roughness and sliding friction measurements are performed by atomic force microscopy. We find a strong dependence of the MoS{sub 2} roughness on the underlying substrate material, being h-BN the substrate which better preserves the flatness of the MoS{sub 2} crystal. The lateral friction also lowers as the roughness decreases, and attains its lowest value for MoS{sub 2} flakes on h-BN substrates. However, it is still higher than for the surface of a bulk MoS{sub 2} crystal, which we attribute to the deformation of the flake due to competing tip-to-flake and flake-to-substrate interactions.

  12. High blue-near ultraviolet photodiode response of vertically stacked graphene-MoS{sub 2}-metal heterostructures

    SciTech Connect (OSTI)

    Wi, Sungjin; Chen, Mikai; Nam, Hongsuk; Liu, Amy C.; Meyhofer, Edgar; Liang, Xiaogan

    2014-06-09

    We present a study on the photodiode response of vertically stacked graphene/MoS{sub 2}/metal heterostructures in which MoS{sub 2} layers are doped with various plasma species. In comparison with undoped heterostructures, such doped ones exhibit significantly improved quantum efficiencies in both photovoltaic and photoconductive modes. This indicates that plasma-doping-induced built-in potentials play an important role in photocurrent generation. As compared to indium-tin-oxide/ MoS{sub 2}/metal structures, the presented graphene/MoS{sub 2}/metal heterostructures exhibit greatly enhanced quantum efficiencies in the blue-near ultraviolet region, which is attributed to the low density of recombination centers at graphene/MoS{sub 2} heterojunctions. This work advances the knowledge for making photo-response devices based on layered materials.

  13. United States

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    l 0 United States Office of Research and Environmental Protection Agency Development Washington, DC 20460 EPA 600/R-94/209 January 1993 Offsite Environment itoring Report adiation Monitoring Around United States Nuclear Test Areas, Calendar Year 1992 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY OFFICE OF RESEARCH AND DEVELOPMENT ENVIRONMENTAL MONITORING SYSTEMS LABORATORY-LAS VEGAS P.O. BOX 93478 LAS VEGAS, NEVADA 89193-3478 , 702/798-2100 April 20, 1995 Dear Reader: Since 1954, the U.S.

  14. United States

    Office of Legacy Management (LM)

    - I United States Department of Energy D lSCk Al M E R "This book was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe

  15. UNITED STATES

    Office of Legacy Management (LM)

    Stephen M. Shelton General Manager Gentlemen: Enclosed is Special Nuclear Material License ... STATES ATOMIC ENERGY COMMISSION SPECIAL NUCLEAR MATERIAL LlCENSE .- Pursuant to the ...

  16. MoS{sub 2} functionalization for ultra-thin atomic layer deposited dielectrics

    SciTech Connect (OSTI)

    Azcatl, Angelica; McDonnell, Stephen; Santosh, K.C.; Peng, Xin; Dong, Hong; Qin, Xiaoye; Addou, Rafik; Lu, Ning; Kim, Moon J.; Cho, Kyeongjae; Wallace, Robert M.; Mordi, Greg I.; Kim, Jiyoung

    2014-03-17

    The effect of room temperature ultraviolet-ozone (UV-O{sub 3}) exposure of MoS{sub 2} on the uniformity of subsequent atomic layer deposition of Al{sub 2}O{sub 3} is investigated. It is found that a UV-O{sub 3} pre-treatment removes adsorbed carbon contamination from the MoS{sub 2} surface and also functionalizes the MoS{sub 2} surface through the formation of a weak sulfur-oxygen bond without any evidence of molybdenum-sulfur bond disruption. This is supported by first principles density functional theory calculations which show that oxygen bonded to a surface sulfur atom while the sulfur is simultaneously back-bonded to three molybdenum atoms is a thermodynamically favorable configuration. The adsorbed oxygen increases the reactivity of MoS{sub 2} surface and provides nucleation sites for atomic layer deposition of Al{sub 2}O{sub 3}. The enhanced nucleation is found to be dependent on the thin film deposition temperature.

  17. Magnetic Force Microscopy Study of Zr2Co11 -Based Nanocrystalline Materials: Effect of Mo Addition

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yue, Lanping; Jin, Yunlong; Zhang, Wenyong; Sellmyer, David J.

    2015-01-01

    Tmore » he addition of Molybdenum was used to modify the nanostructure and enhance coercivity of rare-earth-free Zr2Co11-based nanocrystalline permanent magnets. he effect of Mo addition on magnetic domain structures of melt spun nanocrystalline Zr16Co84-xMox(x=0, 0.5, 1, 1.5, and 2.0) ribbons has been investigated. It was found that magnetic properties and local domain structures are strongly influenced by Mo doping. he coercivity of the samples increases with the increase in Mo content (x≤1.5). he maximum energy product(BH)maxincreases with increasingxfrom 0.5 MGOe forx=0to a maximum value of 4.2 MGOe forx=1.5. he smallest domain size with a relatively short magnetic correlation length of 128 nm and largest root-mean-square phase shiftΦrmsvalue of 0.66° are observed for thex=1.5. he optimal Mo addition promotes magnetic domain structure refinement and thus leads to a significant increase in coercivity and energy product in this sample.« less

  18. M&O Contract 2008-2013, Alliance for Sustainable Energy, LLC

    Broader source: Energy.gov [DOE]

    Contract No. DE-AC36-08GO28308 M&O Contract 2008-2013, between the Alliance for Sustainable Energy, LLC and the U.S. Department Of Energy. Part I, Section B, Supplies and Services and Price/Costs.

  19. EIS-0475: Disposition of the Bannister Federal Complex, Kansas City, MO

    Broader source: Energy.gov [DOE]

    NNSA/DOE announces its intent to prepare an EIS for the disposition of the Bannister Federal Complex, Kansas City, MO. NNSA previously decided in a separate NEPA review (EA-1592) to relocate its operations from the Bannister Federal Complex to a newly constructed industrial campus eight miles from the current location.

  20. On the combined gradient-stochastic plasticity model: Application to Mo-micropillar compression

    SciTech Connect (OSTI)

    Konstantinidis, A. A.; Zhang, X.; Aifantis, E. C.

    2015-02-17

    A formulation for addressing heterogeneous material deformation is proposed. It is based on the use of a stochasticity-enhanced gradient plasticity model implemented through a cellular automaton. The specific application is on Mo-micropillar compression, for which the irregularities of the strain bursts observed have been experimentally measured and theoretically interpreted through Tsallis' q-statistics.

  1. Electric contributions to magnetic force microscopy response from graphene and MoS{sub 2} nanosheets

    SciTech Connect (OSTI)

    Li, Lu Hua Chen, Ying

    2014-12-07

    Magnetic force microscopy (MFM) signals have recently been detected from whole pieces of mechanically exfoliated graphene and molybdenum disulfide (MoS{sub 2}) nanosheets, and magnetism of the two nanomaterials was claimed based on these observations. However, non-magnetic interactions or artefacts are commonly associated with MFM signals, which make the interpretation of MFM signals not straightforward. A systematic investigation has been done to examine possible sources of the MFM signals from graphene and MoS{sub 2} nanosheets and whether the MFM signals can be correlated with magnetism. It is found that the MFM signals have significant non-magnetic contributions due to capacitive and electrostatic interactions between the nanosheets and conductive cantilever tip, as demonstrated by electric force microscopy and scanning Kevin probe microscopy analyses. In addition, the MFM signals of graphene and MoS{sub 2} nanosheets are not responsive to reversed magnetic field of the magnetic cantilever tip. Therefore, the observed MFM response is mainly from electric artefacts and not compelling enough to correlate with magnetism of graphene and MoS{sub 2} nanosheets.

  2. Interaction Layer Characteristics in U-xMo Dispersion/Monolithic Fuels

    SciTech Connect (OSTI)

    D. L. Porter

    2010-11-01

    Published data concerning the interaction layer (IL) formed between U-xMo fuel alloy and aluminum (Al)-based matrix or cladding materials was reviewed, including the effects of silicon (Si) content in the matrix/cladding, molybdenum (Mo) content in the fuel, pre irradiation thermal treatments, irradiation, and test temperature. The review revealed that tests conducted in the laboratory produce results different from those conducted in an irradiation environment. However, the laboratory testing relates well to thermal treatments performed prior to irradiation and helps in understanding the effects that these pre irradiation treatments have on in reactor performance. A pre-formed, Si-enriched IL seems to be important in delaying the onset of rapid growth of fission gas bubbles at low irradaiiation temperatures. Several other conclusions can be drawn: 1. An IL with phases akin to UAl3 is desired for optimum fuel performance, but at low temperatures, and especially in an irradiation atmosphere, the desired (Al+Si)/(U+Mo) ratio of three is difficult to produce. When the fuel operating temperature is low, it is important to create a pre-irradiation IL, enriched in Si. This pre-formed IL is relatively stable, performs well in terms of swelling resistance, and prevents rapid IL growth during irradiation. 2. At higher operating temperatures (>150–170°C), IL formation in reactor may not be so dependent on pre-irradiation IL formation, especially at high burnup; a pre-fabricated IL seems to be less stable at high burnup and high operating temperature. Moreover, the (Al+SI)/(U+Mo) ratio of three occurs more often at higher temperature. For these two reasons, it is important at high operating temperature to also have a matrix with significant Si content to create an IL in reactor with the right characteristics. 3. Out-of-reactor testing seems to indicate that Si in the matrix material is required in some concentration (2%, 5%, ?) to provide for a thin, Si-enriched IL formed before irradiation of a fuel plate. It ensures that the IL contains beneficial phases, or prevents formation of some known to promote poor fuel performance. Significant progress has been made in determining the desired characteristics of the IL. 4. The use of a fuel with stable gamma phase appears to allow more predictable performance regarding both a beneficial pre-irradiation layer, and the fuel performance (low swelling) to high burnup. Destabilization of the gamma phase may create problems with IL breakaway growth. 5. A theory whereby prevention of the U6Mo4Al43 complex phase in interaction layers formed during fabrication may be a key to good irradiation performance. Si additions to the matrix allow for solubility of Mo in the desirable (U,Mo)(Al,Si)3 or perhaps (U,Mo)(Al,Si)4 phase, helping to prevent formation of the complex phase. Keeping alloy Mo content as low as possible may also help so long as decomposition does not occur in fabrication, forcing Mo into the interaction layer. This theory may explain a number of apparent anomalies observed in testing results. 6. More work is needed in order to prescribe the conditions to best produce a beneficial IL. Another necessity is a better understanding of any correlation between beneficial characteristics of the pre-fabricated IL and the irradiation conditions to which it will be subjected.

  3. Modeling of Interaction Layer Growth Between U-Mo Particles and an Al Matrix

    SciTech Connect (OSTI)

    Yeon Soo Kim; G. L. Hofman; Ho Jin Ryu; Jong Man Park; A. B. Robinson; D. M. Wachs

    2013-12-01

    Interaction layer growth between U-Mo alloy fuel particles and Al in a dispersion fuel is a concern due to the volume expansion and other unfavorable irradiation behavior of the interaction product. To reduce interaction layer (IL) growth, a small amount of Si is added to the Al. As a result, IL growth is affected by the Si content in the Al matrix. In order to predict IL growth during fabrication and irradiation, empirical models were developed. For IL growth prediction during fabrication and any follow-on heating process before irradiation, out-of-pile heating test data were used to develop kinetic correlations. Two out-of-pile correlations, one for the pure Al matrix and the other for the Al matrix with Si addition, respectively, were developed, which are Arrhenius equations that include temperature and time. For IL growth predictions during irradiation, the out-of-pile correlations were modified to include a fission-rate term to consider fission enhanced diffusion, and multiplication factors to incorporate the Si addition effect and the effect of the Mo content. The in-pile correlation is applicable for a pure Al matrix and an Al matrix with the Si content up to 8 wt%, for fuel temperatures up to 200 degrees C, and for Mo content in the range of 6 10wt%. In order to cover these ranges, in-pile data were included in modeling from various tests, such as the US RERTR-4, -5, -6, -7 and -9 tests and Koreas KOMO-4 test, that were designed to systematically examine the effects of the fission rate, temperature, Si content in Al matrix, and Mo content in U-Mo particles. A model converting the IL thickness to the IL volume fraction in the meat was also developed.

  4. In situ X-ray absorption spectroscopic investigation of the electrochemical conversion reactions of CuF{sub 2}-MoO{sub 3} nanocomposite

    SciTech Connect (OSTI)

    Mansour, A.N.; Badway, F.; Yoon, W.-S.; Chung, K.Y.; Amatucci, G.G.

    2010-12-15

    We have used X-ray absorption spectroscopy at the Cu K-edge to investigate the electrochemical conversion reaction of 20 nm size 85 wt% CuF{sub 2}-15 wt% MoO{sub 3} nanocomposite under in situ conditions. The nanocomposite was prepared by high energy milling. Upon discharge, the lithiation reaction with the nanocomposite resulted in the formation of nanophase metallic Cu, which is consistent with the conversion of CuF{sub 2} into Cu and LiF. Based on XANES and Fourier transforms of EXAFS spectra, we show that the discharge process proceeded via the formation of highly dispersed Cu particles. Based on the coordination number of the first shell of Cu, the average size of the Cu particles was estimated to be in the 1-3 nm range in the fully discharged state. -- Graphical Abstract: Comparison of Fourier transform of in situ Cu K-edge EXAFS spectra for a fully discharged CuF{sub 2{center_dot}}MoO{sub 3} nanocomposite in a nonaqueous Li cell with that of a Cu foil. Quantitative analysis of the Fourier transforms confirmed that the discharge mechanism for the nanocomposite proceeds via the reaction CuF{sub 2}+2Li{yields}Cu+2LiF. The discharge product of Cu is in the form of highly dispersed nanoparticles. Display Omitted

  5. Study of structure of the TiO{sub 2}MoO{sub 3} bilayer films by Raman spectroscopy

    SciTech Connect (OSTI)

    Santos, Elias de Barros; Sigoli, Fernando Aparecido; Mazali, Italo Odone

    2014-12-15

    Highlights: TiO{sub 2}MoO{sub 3} bilayer thin films were easily prepared by dip-coating technique. Ti and Mo metallo-organic compounds were used as source of its respective oxide. TiO{sub 2} in anatase phase and orthorhombic phase of ?-MoO{sub 3} were identified. The bilayer structure was investigated by Raman spectroscopy. - Abstract: In this work, TiO{sub 2}MoO{sub 3} films were easily prepared by dip-coating technique and metallo-organic decomposition process (MOD). Raman analyses indicate the formation of TiO{sub 2} in anatase phase and orthorhombic phase of ?-MoO{sub 3}. It was observed that the Raman bands intensities attributed to TiO{sub 2} and MoO{sub 3} oxides were dependent on the number of decompositiondeposition cycles (DDC). The different number of DDC generates films with different thicknesses and the Raman signal was sensitive to this variation. Raman analyses provided qualitative information about the bilayer structure of the bi-component TiO{sub 2}MoO{sub 3} films, which was confirmed by scanning electron microscopy. In this direction, the dip-coating technique and MOD process can be an efficient strategy to facile preparation of many samples to be used in applications.

  6. Microstructural Characterization of U-7Mo/Al-Si Alloy Matrix Dispersion Fuel Plates Fabricated at 500°C

    SciTech Connect (OSTI)

    Dennis D. Keiser, Jr.; Jan-Fong Jue; Bo Yao; Emmanuel Perez; Yongho Sohn; Curtis R. Clark

    2011-05-01

    The starting microstructure of a dispersion fuel plate will impact the overall performance of the plate during irradiation. To improve the understanding of the as-fabricated microstructures of U–Mo dispersion fuel plates, particularly the interaction layers that can form between the fuel particles and the matrix, scanning electron microscopy (SEM) and transmission electron microscopy (TEM) analyses have been performed on samples from depleted U–7Mo (U–7Mo) dispersion fuel plates with either Al–2 wt.% Si(Al–2Si) or AA4043 alloy matrix. It was observed that in the thick interaction layers, U(Al, Si)3 and U6Mo4Al43 were present, and in the thin interaction layers, (U, Mo) (Al, Si)3, U(Al, Si)4, U3Si3Al2, U3Si5, and possibly USi-type phases were observed. The U3Si3Al2 phase contained some Mo. Based on the results of this investigation, the time that a dispersion fuel plate is exposed to a relatively high temperature during fabrication will impact the nature of the interaction layers around the fuel particles. Uniformly thin, Si-rich layers will develop around the U–7Mo particles for shorter exposure times, and thicker, Si-depleted layers will develop for the longer exposure times.

  7. MoS{sub 2}@ZnO nano-heterojunctions with enhanced photocatalysis and field emission properties

    SciTech Connect (OSTI)

    Tan, Ying-Hua; Yu, Ke Li, Jin-Zhu; Fu, Hao; Zhu, Zi-Qiang

    2014-08-14

    The molybdenum disulfide (MoS{sub 2})@ZnO nano-heterojunctions were successfully fabricated through a facile three-step synthetic process: prefabrication of the ZnO nanoparticles, the synthesis of MoS{sub 2} nanoflowers, and the fabrication of MoS{sub 2}@ZnO heterojunctions, in which ZnO nanoparticles were uniformly self-assembled on the MoS{sub 2} nanoflowers by utilizing polyethyleneimine as a binding agent. The photocatalytic activities of the composite samples were evaluated by monitoring the photodegradation of methylene blue (MB). Compared with pure MoS{sub 2} nanoflowers, the composites show higher adsorption capability in dark and better photocatalytic efficiency due to the increased specific surface area and improved electron-hole pair separation. After irradiation for 100?min, the remaining MB in solution is about 7.3%. Moreover, the MoS{sub 2}@ZnO heterojunctions possess enhanced field emission properties with lower turn-on field of 3.08?V ?m{sup ?1}and lower threshold field of 6.9?V ?m{sup ?1} relative to pure MoS{sub 2} with turn-on field of 3.65?V ?m{sup ?1} and threshold field of 9.03?V ?m{sup ?1}.

  8. Evaluation of ferritic alloy Fe-2-1/4Cr-1Mo after neutron irradiation - microstructure development

    SciTech Connect (OSTI)

    Gelles, D.S.

    1984-05-01

    Microstructural examinations are reported for nine specimen conditions of 2-1/4Cr-1Mo steel which had been irradiated by fast neutrons over the temperature range 390 to 510/sup 0/C. Two heats of material were involved, each with a different preirradiation heat treatment, one irradiated to a peak fluence of 5.1 x 10/sup 22/ n/cm/sup 2/ (E > 0.1 MeV) or 24 dpa and the other to 2.4 x 10/sup 23/ n/cm/sup 2/ (E > 0.1 MeV) or 116 dpa. Void swelling is found following irradiation at 400/sup 0/C in both conditions and to 480/sup 0/C in the higher fluence conditions. Concurrently dislocation structure and precipitation formed. Peak void swelling, void density, dislocation density and precipitate number density developed at the lowest temperature, approx. 400/sup 0/C, whereas mean void size, and mean precipitate size increased with increasing irradiation temperature. The examination results are used to provide interpretation of in-reactor creep, density change and post irradiation tensile behavior.

  9. United States

    Broader source: Energy.gov (indexed) [DOE]

    ... of the Senate Energy and Natural Resources Committee when ... with section 1222's requirements, referred to in the ... States v. 14.02 Acres of Land More or Less in Fresno ...

  10. Electron-phonon coupling and thermal transport in the thermoelectric compound Mo3Sb7–xTex

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Bansal, Dipanshu; Li, Chen W.; Said, Ayman H.; Abernathy, Douglas L.; Yan, Jiaqiang; Delaire, Olivier A.

    2015-12-07

    Phonon properties of Mo3Sb7–xTex (x = 0, 1.5, 1.7), a potential high-temperature thermoelectric material, have been studied with inelastic neutron and x-ray scattering, and with first-principles simulations. The substitution of Te for Sb leads to pronounced changes in the electronic struc- ture, local bonding, phonon density of states (DOS), dispersions, and phonon lifetimes. Alloying with tellurium shifts the Fermi level upward, near the top of the valence band, resulting in a strong suppression of electron-phonon screening, and a large overall stiffening of interatomic force- constants. The suppression in electron-phonon coupling concomitantly increases group velocities and suppresses phonon scattering rates, surpassingmore » the effects of alloy-disorder scattering, and re- sulting in a surprising increased lattice thermal conductivity in the alloy. We also identify that the local bonding environment changes non-uniformly around different atoms, leading to variable perturbation strengths for different optical phonon branches. The respective roles of changes in phonon group velocities and phonon lifetimes on the lattice thermal conductivity are quantified. Lastly, our results highlight the importance of the electron-phonon coupling on phonon mean-free-paths in this compound, and also estimates the contributions from boundary scattering, umklapp scattering, and point-defect scattering.« less

  11. Hydrogenation-induced edge magnetization in armchair MoS{sub 2} nanoribbon and electric field effects

    SciTech Connect (OSTI)

    Ouyang, Fangping; Yang, Zhixiong; Wu, Nannan; Chen, Yu; Ni, Xiang; Xiong, Xiang

    2014-02-17

    We performed density functional theory study on the electronic and magnetic properties of armchair MoS{sub 2} nanoribbons (AMoS{sub 2}NR) with different edge hydrogenation. Although bare and fully passivated AMoS{sub 2}NRs are nonmagnetic semiconductors, it was found that hydrogenation in certain patterns can induce localized ferromagnetic edge state in AMoS{sub 2}NRs and make AMoS{sub 2}NRs become antiferromagnetic semiconductors or ferromagnetic semiconductors. Electric field effects on the bandgap and magnetic moment of AMoS{sub 2}NRs were investigated. Partial edge hydrogenation can change a small-sized AMoS{sub 2}NR from semiconductor to metal or semimetal under a moderate transverse electric field. Since the rate of edge hydrogenation can be controlled experimentally via the temperature, pressure and concentration of H{sub 2}, our results suggest edge hydrogenation is a useful method to engineer the band structure of AMoS{sub 2}NRs.

  12. Domestic production of medical isotope Mo-99 moves a step closer

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Domestic Uranium Production Report - Annual With Data for 2015 | Release Date: May 5, 2016 | Next Release Date: May 2017 | full report Previous domestic uranium production reports Year: 2014 2013 2012 2011 2010 2009 2008 2007 2006 2005 2004 Go Drilling Total uranium drilling was 1,518 holes covering 0.9 million feet, 13% fewer holes than in 2015. Expenditures for uranium drilling in the United States were $29 million in 2015, an increase of 2% compared with 2014. Figure 1. U.S. Uranium drilling

  13. Search for Long-Lived Particles ine<mo>+mo>e<mo>->Collisions

    SciTech Connect (OSTI)

    Lees, J. P.; Poireau, V.; Tisserand, V.; Grauges, E.; Palano, A.; Eigen, G.; Stugu, B.; Brown, D. N.; Kerth, L. T.; Kolomensky, Yu. G.; Lee, M. J.; Lynch, G.; Koch, H.; Schroeder, T.; Hearty, C.; Mattison, T. S.; McKenna, J. A.; So, R. Y.; Khan, A.; Blinov, V. E.; Buzykaev, A. R.; Druzhinin, V. P.; Golubev, V. B.; Kravchenko, E. A.; Onuchin, A. P.; Serednyakov, S. I.; Skovpen, Yu. I.; Solodov, E. P.; Todyshev, K. Yu.; Lankford, A. J.; Dey, B.; Gary, J. W.; Long, O.; Campagnari, C.; Franco Sevilla, M.; Hong, T. M.; Kovalskyi, D.; Richman, J. D.; West, C. A.; Eisner, A. M.; Lockman, W. S.; Panduro Vazquez, W.; Schumm, B. A.; Seiden, A.; Chao, D. S.; Cheng, C. H.; Echenard, B.; Flood, K. T.; Hitlin, D. G.; Miyashita, T. S.; Ongmongkolkul, P.; Porter, F. C.; Röhrken, M.; Andreassen, R.; Huard, Z.; Meadows, B. T.; Pushpawela, B. G.; Sokoloff, M. D.; Sun, L.; Bloom, P. C.; Ford, W. T.; Gaz, A.; Smith, J. G.; Wagner, S. R.; Ayad, R.; Toki, W. H.; Spaan, B.; Bernard, D.; Verderi, M.; Playfer, S.; Bettoni, D.; Bozzi, C.; Calabrese, R.; Cibinetto, G.; Fioravanti, E.; Garzia, I.; Luppi, E.; Piemontese, L.; Santoro, V.; Calcaterra, A.; de Sangro, R.; Finocchiaro, G.; Martellotti, S.; Patteri, P.; Peruzzi, I. M.; Piccolo, M.; Rama, M.; Zallo, A.; Contri, R.; Lo Vetere, M.; Monge, M. R.; Passaggio, S.; Patrignani, C.; Robutti, E.; Bhuyan, B.; Prasad, V.; Adametz, A.; Uwer, U.; Lacker, H. M.; Mallik, U.; Chen, C.; Cochran, J.; Prell, S.; Ahmed, H.; Gritsan, A. V.; Arnaud, N.; Davier, M.; Derkach, D.; Grosdidier, G.; Le Diberder, F.; Lutz, A. M.; Malaescu, B.; Roudeau, P.; Stocchi, A.; Wormser, G.; Lange, D. J.; Wright, D. M.; Coleman, J. P.; Fry, J. R.; Gabathuler, E.; Hutchcroft, D. E.; Payne, D. J.; Touramanis, C.; Bevan, A. J.; Di Lodovico, F.; Sacco, R.; Cowan, G.; Brown, D. N.; Davis, C. L.; Denig, A. G.; Fritsch, M.; Gradl, W.; Griessinger, K.; Hafner, A.; Schubert, K. R.; Barlow, R. J.; Lafferty, G. D.; Cenci, R.; Hamilton, B.; Jawahery, A.; Roberts, D. A.; Cowan, R.; Sciolla, G.; Cheaib, R.; Patel, P. M.; Robertson, S. H.; Neri, N.; Palombo, F.; Cremaldi, L.; Godang, R.; Sonnek, P.; Summers, D. J.; Simard, M.; Taras, P.; De Nardo, G.; Onorato, G.; Sciacca, C.; Martinelli, M.; Raven, G.; Jessop, C. P.; LoSecco, J. M.; Honscheid, K.; Kass, R.; Feltresi, E.; Margoni, M.; Morandin, M.; Posocco, M.; Rotondo, M.; Simi, G.; Simonetto, F.; Stroili, R.; Akar, S.; Ben-Haim, E.; Bomben, M.; Bonneaud, G. R.; Briand, H.; Calderini, G.; Chauveau, J.; Leruste, Ph.; Marchiori, G.; Ocariz, J.; Biasini, M.; Manoni, E.; Pacetti, S.; Rossi, A.; Angelini, C.; Batignani, G.; Bettarini, S.; Carpinelli, M.; Casarosa, G.; Cervelli, A.; Chrzaszcz, M.; Forti, F.; Giorgi, M. A.; Lusiani, A.; Oberhof, B.; Paoloni, E.; Perez, A.; Rizzo, G.; Walsh, J. J.; Lopes Pegna, D.; Olsen, J.; Smith, A. J. S.; Anulli, F.; Faccini, R.; Ferrarotto, F.; Ferroni, F.; Gaspero, M.; Li Gioi, L.; Pilloni, A.; Piredda, G.; Bünger, C.; Dittrich, S.; Grünberg, O.; Hess, M.; Leddig, T.; Voß, C.; Waldi, R.; Adye, T.; Olaiya, E. O.; Wilson, F. F.; Emery, S.; Vasseur, G.; Aston, D.; Bard, D. J.; Cartaro, C.; Convery, M. R.; Dorfan, J.; Dubois-Felsmann, G. P.; Dunwoodie, W.; Ebert, M.; Field, R. C.; Fulsom, B. G.; Graham, M. T.; Hast, C.; Innes, W. R.; Kim, P.; Leith, D. W. G. S.; Lindemann, D.; Luitz, S.; Luth, V.; Lynch, H. L.; MacFarlane, D. B.; Muller, D. R.; Neal, H.; Perl, M.; Pulliam, T.; Ratcliff, B. N.; Roodman, A.; Salnikov, A. A.; Schindler, R. H.; Snyder, A.; Su, D.; Sullivan, M. K.; Va’vra, J.; Wisniewski, W. J.; Wulsin, H. W.; Purohit, M. V.; White, R. M.; Wilson, J. R.; Randle-Conde, A.; Sekula, S. J.; Bellis, M.; Burchat, P. R.; Puccio, E. M. T.; Alam, M. S.; Ernst, J. A.; Gorodeisky, R.; Guttman, N.; Peimer, D. R.; Soffer, A.; Spanier, S. M.; Ritchie, J. L.; Schwitters, R. F.; Wray, B. C.; Izen, J. M.; Lou, X. C.; Bianchi, F.; De Mori, F.; Filippi, A.; Gamba, D.; Lanceri, L.; Vitale, L.; Martinez-Vidal, F.; Oyanguren, A.; Villanueva-Perez, P.; Albert, J.; Banerjee, Sw.; Beaulieu, A.; Bernlochner, F. U.; Choi, H. H. F.; King, G. J.; Kowalewski, R.; Lewczuk, M. J.; Lueck, T.; Nugent, I. M.; Roney, J. M.; Sobie, R. J.; Tasneem, N.; Gershon, T. J.; Harrison, P. F.; Latham, T. E.; Band, H. R.; Dasu, S.; Pan, Y.; Prepost, R.; Wu, S. L.

    2015-04-29

    We present a search for a neutral, long-lived particle L that is produced in e+e- collisions and decays at a significant distance from the e+e- interaction point into various flavor combinations of two oppositely charged tracks. The analysis uses an e+e- data sample with a luminosity of 489.1 fb-1 collected by the BABAR detector at the γ (4S), γ (3S), and γ (2S) resonances and just below the γ (4S). Fitting the two-track mass distribution in search of a signal peak, we do not observe a significant signal, and set 90% confidence level upper limits on the product of the L production cross section, branching fraction, and reconstruction efficiency for six possible two-body L decay modes as a function of the L mass. The efficiency is given for each final state as a function of the mass, lifetime, and transverse momentum of the candidate, allowing application of the upper limits to any production model. In addition, upper limits are provided on the branching fraction B(B→XsL), where Xs is a strange hadronic system.

  14. AMoRE: Collaboration for searches for the neutrinoless double-beta decay of the isotope of {sup 100}Mo with the aid of {sup 40}Ca{sup 100}MoO{sub 4} as a cryogenic scintillation detector

    SciTech Connect (OSTI)

    Khanbekov, N. D., E-mail: xanbekov@gmail.com [Institute of Theoretical and Experimental Physics (Russian Federation)

    2013-09-15

    The AMoRE (Advanced Mo based Rare process Experiment) Collaboration is planning to employ {sup 40}Ca{sup 100}MoO{sub 4} single crystals as a cryogenic Scintillation detector for studying the neutrinoless double-beta decay of the isotope {sup 100}Mo. A simultaneous readout of phonon and scintillation signals is performed in order to suppress the intrinsic background. The planned sensitivity of the experiment that would employ 100 kg of {sup 40}Ca{sup 100}MoO{sub 4} over five years of data accumulation would be T{sub 1/2}{sup 0{nu}} = 3 Multiplication-Sign 10{sup 26} yr, which corresponds to values of the effective Majorana neutrino mass in the range of Left-Pointing-Angle-Bracket m{sub {nu}} Right-Pointing-Angle-Bracket {approx} 0.02-0.06 eV.

  15. Determination of the direct double- β -decay Q value of Zr 96 and atomic masses of Zr 90 <mo>-> 92 <mo>,> 94 <mo>,> 96 and Mo 92 <mo>,> 94 <mo>-> 98 <mo>,> 100

    SciTech Connect (OSTI)

    Gulyuz, K.; Ariche, J.; Bollen, G.; Bustabad, S.; Eibach, M.; Izzo, C.; Novario, S. J.; Redshaw, M.; Ringle, R.; Sandler, R.; Schwarz, S.; Valverde, A. A.

    2015-05-06

    Experimental searches for neutrinoless double-β decay offer one of the best opportunities to look for physics beyond the standard model. Detecting this decay would confirm the Majorana nature of the neutrino, and a measurement of its half-life can be used to determine the absolute neutrino mass scale. Important to both tasks is an accurate knowledge of the Q value of the double-β decay. The LEBIT Penning trap mass spectrometer was used for the first direct experimental determination of the ⁹⁶Zr double-β decay Q value: Qββ=3355.85(15) keV. This value is nearly 7 keV larger than the 2012 Atomic Mass Evaluation [M. Wang et al., Chin. Phys. C 36, 1603 (2012)] value and one order of magnitude more precise. The 3-σ shift is primarily due to a more accurate measurement of the ⁹⁶Zr atomic mass: m(⁹⁶Zr)=95.90827735(17) u. Using the new Q value, the 2νββ-decay matrix element, |M|, is calculated. Improved determinations of the atomic masses of all other zirconium (90-92,94,96Zr) and molybdenum (92,94-98,100Mo) isotopes using both ¹²C₈ and ⁸⁷Rb as references are also reported.

  16. Microstructure evolution in solution treated Ti15Mo alloy processed by high pressure torsion

    SciTech Connect (OSTI)

    Jane?ek, Milo; ?ek, Jakub; Strsk, Josef; Vclavov, Kristna; Hruka, Petr; Polyakova, Veronika; Gatina, Svetlana; Semenova, Irina

    2014-12-15

    Microstructure evolution and mechanical properties of ultra-fine grained Ti15Mo alloy processed by high pressure torsion were investigated. High pressure torsion straining resulted in strong grain refinement as-observed by transmission electron microscopy. Microhardness and light microscopy showed two distinct regions (i) a central region with radial material flow and low microhardness (340 HV) and (ii) a peripheral region with rotational material flow and high microhardness (430 HV). Positron annihilation spectroscopy showed that the only detectable defects in the material are dislocations, whose density increases with the radial distance and the number of high pressure torsion revolutions. The local chemical environment around defects does not differ significantly from the average composition. - Highlights: Beta-Ti alloy Ti15Mo was processed by high pressure torsion (HPT). Lateral inhomogeneity of the microstructure and microhardness was found. Dislocations are the only lattice defects detectable by positron annihilation. Molybdenum is not preferentially segregated along dislocation cores.

  17. LANL Experience Rolling Zr-Clad LEU-10Mo Foils for AFIP-7

    SciTech Connect (OSTI)

    Hammon, Duncan L.; Clarke, Kester D.; Alexander, David J.; Kennedy, Patrick K.; Edwards, Randall L.; Duffield, Andrew N.; Dombrowski, David E.

    2015-05-29

    The cleaning, canning, rolling and final trimming of Low Enriched Uranium-10 wt. pct. Molybdenum (LEU-10Mo) foils for ATR (Advanced Test Reactor) fuel plates to be used in the AFIP-7 (ATR Full Size Plate In Center Flux Trap Position) experiments are summarized. Six Zr-clad foils were produced from two LEU-10Mo castings supplied to Los Alamos National Laboratory (LANL) by Y-12 National Security Complex. Details of cleaning and canning procedures are provided. Hot- and cold-rolling results are presented, including rolling schedules, images of foils in-process, metallography and local compositions of regions of interest, and details of final foil dimensions and process yield. This report was compiled from the slides for the presentation of the same name given by Duncan Hammon on May 12, 2011 at the AFIP-7 Lessons Learned meeting in Salt Lake City, UT, with Los Alamos National Laboratory document number LA-UR 11-02898.

  18. A multiscale method for the analysis of defect behavior in MO during electron irradiation

    SciTech Connect (OSTI)

    Rest, J.; Insepov, Z.; Ye, B.; Yun, D.

    2014-10-01

    In order to overcome a lack of experimental information on values for key materials properties and kinetic coefficients, a multiscale modeling approach is applied to defect behavior in irradiated Mo where key materials properties, such as point defect (vacancy and interstitial) migration enthalpies as well as kinetic factors such as dimer formation, defect recombination, and self interstitial–interstitial loop interaction coefficients, are obtained by molecular dynamics calculations and implemented into rate-theory simulations of defect behavior. The multiscale methodology is validated against interstitial loop growth data obtained from electron irradiation of pure Mo. It is shown that the observed linear behavior of the loop diameter vs. the square root of irradiation time is a direct consequence of the 1D migration of self-interstitial atoms.

  19. Production and Characterization of Atomized U-Mo Powder by the Rotating Electrode Process

    SciTech Connect (OSTI)

    C.R. Clark; B.R. Muntifering; J.F. Jue

    2007-09-01

    In order to produce feedstock fuel powder for irradiation testing, the Idaho National Laboratory has produced a rotating electrode type atomizer to fabricate uranium-molybdenum alloy fuel. Operating with the appropriate parameters, this laboratory-scale atomizer produces fuel in the desired size range for the RERTR dispersion experiments. Analysis of the powder shows a homogenous, rapidly solidified microstructure with fine equiaxed grains. This powder has been used to produce irradiation experiments to further test adjusted matrix U-Mo dispersion fuel.

  20. Co-Rolled U10Mo/Zirconium-Barrier-Layer Monolithic Fuel Foil Fabrication Process

    SciTech Connect (OSTI)

    G. A. Moore; M. C. Marshall

    2010-01-01

    Integral to the current UMo fuel foil processing scheme being developed at Idaho National Laboratory (INL) is the incorporation of a zirconium barrier layer for the purpose of controlling UMo-Al interdiffusion at the fuel-meat/cladding interface. A hot “co-rolling” process is employed to establish a ~25-µm-thick zirconium barrier layer on each face of the ~0.3-mm-thick U10Mo fuel foil.

  1. High strength Sn-Mo-Nb-Zr alloy tubes and method of making same

    DOE Patents [OSTI]

    Cheadle, Brian A.

    1977-01-01

    Tubes for use in nuclear reactors fabricated from a quaternary alloy comprising 2.5-4.0 wt% Sn, 0.5-1.5 wt% Mo, 0.5-1.5 wt% Nb, balance essentially Zr. The tubes are fabricated by a process of hot extrusion, heat treatment, cold working to size and age hardening, so as to produce a microstructure comprising elongated .alpha. grains with an acicular transformed .beta. grain boundary phase.

  2. Crystal structure of the spin-glass pyrochlore, Y/sub 2/Mo/sub 2/O/sub 7/

    SciTech Connect (OSTI)

    Reimers, J.N.; Greedan, J.E.; Sato, M.

    1988-02-01

    The crystal structure of the spin-glass material, Y/sub 2/Mo/sub 2/O/sub 7/, has been determined from powder neutron diffraction data using profile (Rietveld) methods. The data are consistent with the fully ordered cubic pyrochlore structure, a/sub 0/ = 10.230(1) A with Y in 16d, Mo in 16c, O in 48f(x = 0.3382(1), and O' in 8b of Fd3m. Attempts to refine models with O' disordered over the 32e sites or between the 8a and 8b sites resulted in convergence to the 8b positions. Derived Y-O and Mo-O distances are in excellent agreement with those found in isostructural materials giving indirect evidence for Y-Mo ordering over the cation sites.

  3. United States

    Office of Legacy Management (LM)

    onp5fGonal Ruord United States of America . I. .' - PROCEEDINGS AND DEBATES OF THE 9t?lh CONGRESS, FIRST SESSION United States Government Printing Office SUPERINTENDENT OF DOCUMENTS Wash!ogtm. 0.C 20402 OFFICIAL BUSINESS Penalty for pwate use. sco Congressmal Record (USPS 087-390) Postage and Fees Pad I.) s ~lJ"er"ment Prlntlng OffIce 375 SECOND CLASS NEWSPAPER -...~-- -~- -- --- H 45' 78 ' cCJ~GRESSIONAL RECORD - HOUSE June 28, 1983 H.J. Res. 213: Mr. BOLAND, Mr. WAXM.UG Mr. OBERSTAR.

  4. United States

    Office of Legacy Management (LM)

    onSres;eional atecord United States of America :- PROCEEDINGS AND DEBATES OF THE 981h CONGRESS, FIRST SESSION United States Government Printing Office SUPERINTENDENT OF DOCUMENTS Washwtn. D C 20402 OFFICIAL BUSINESS Penalty for plvate use. $300 Congressmnal Record (USPS 087-390) Postage and Fees Pad U S Government Prtnttng Offlce 375 SECOND CLASS NEWSPAPER H 45' 78 * C.QvGRESSIONAL RECORD - HOUSE .-. June 28, 1983 H.J. Res. 273: Mr. BOLAND. Mr. Whxrdhr?. Mr. OBERsThx. Mi. BEDELL, Mr. BONER of

  5. Exciton-dominated dielectric function of atomically thin MoS2 films

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yu, Yiling; Yu, Yifei; Cai, Yongqing; Li, Wei; Gurarslan, Alper; Peelaers, Hartwin; Aspnes, David E.; Van de Walle, Chris G.; Nguyen, Nhan V.; Zhang, Yong -Wei; et al

    2015-11-24

    We systematically measure the dielectric function of atomically thin MoS2 films with different layer numbers and demonstrate that excitonic effects play a dominant role in the dielectric function when the films are less than 5–7 layers thick. The dielectric function shows an anomalous dependence on the layer number. It decreases with the layer number increasing when the films are less than 5–7 layers thick but turns to increase with the layer number for thicker films. We show that this is because the excitonic effect is very strong in the thin MoS2 films and its contribution to the dielectric function maymore » dominate over the contribution of the band structure. We also extract the value of layer-dependent exciton binding energy and Bohr radius in the films by fitting the experimental results with an intuitive model. The dominance of excitonic effects is in stark contrast with what reported at conventional materials whose dielectric functions are usually dictated by band structures. Lastly, the knowledge of the dielectric function may enable capabilities to engineer the light-matter interactions of atomically thin MoS2 films for the development of novel photonic devices, such as metamaterials, waveguides, light absorbers, and light emitters.« less

  6. Supercondutivity at 9K in Mo5PB2 with evidence for multiple gaps

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    McGuire, Michael A.; Parker, David S.

    2016-02-09

    Superconductivity is observed with critical temperatures near 9 K in the tetragonal compound Mo5PB2. This material adopts the Cr5B3 structure type common to superconducting Nb5Si3–xBx, Mo5SiB2, and W5SiB2, which have critical temperatures of 5.8–7.8 K. We have synthesized polycrystalline samples of the compound, made measurements of electrical resistivity, magnetic susceptibility, and heat capacity, and performed first-principles electronic structure calculations. The highest Tc value (9.2 K) occurs in slightly phosphorus rich samples, with composition near Mo5P1.1B1.9, and the upper critical field Hc2 at T = 0 is estimated to be ≈17 kOe. Together, the measurements and band-structure calculations indicate intermediate couplingmore » (λ=1.0), phonon mediated superconductivity. Here, the temperature dependence of the heat capacity and upper critical field Hc2 below Tc suggest multiple superconducting gaps may be present.« less

  7. Study on Shielding Requirements for Radioactive Waste Transportation in a Mo-99 Production Plant - 13382

    SciTech Connect (OSTI)

    Melo Rego, Maria Eugenia de; Kazumi Sakata, Solange; Vicente, Roberto; Hiromoto, Goro [Nuclear and Energy Research Institute, IPEN-CNEN/SP (Brazil)] [Nuclear and Energy Research Institute, IPEN-CNEN/SP (Brazil)

    2013-07-01

    Brazil is currently planning to produce {sup 99}Mo from fission of low enriched uranium (LEU) targets. The planned end of irradiation activity of {sup 99}Mo is about 185 TBq (5 kCi) per week to meet the present domestic demand of {sup 99m}Tc generators. The radioactive wastes from the production plant will be transferred to a waste treatment facility at the same site. The total activity of the actinides, fission and activation products present in the wastes can be predicted based on the yields of fission and activation data for the irradiation conditions, such as composition and mass of uranium targets, irradiation time, neutron flux, production schedule, etc., which were in principle already established by the project management. The transportation of the wastes from the production plant to the treatment facility will be done by means of special shielded packages. An assessment of the shielding required for the packages has been done and the results are presented here, aiming at contributing to the design of the waste management facility for the {sup 99}Mo production plant. (authors)

  8. Exciton-dominated dielectric function of atomically thin MoS2 films

    SciTech Connect (OSTI)

    Yu, Yiling; Yu, Yifei; Cai, Yongqing; Li, Wei; Gurarslan, Alper; Peelaers, Hartwin; Aspnes, David E.; Van de Walle, Chris G.; Nguyen, Nhan V.; Zhang, Yong -Wei; Cao, Linyou

    2015-11-24

    We systematically measure the dielectric function of atomically thin MoS2 films with different layer numbers and demonstrate that excitonic effects play a dominant role in the dielectric function when the films are less than 5–7 layers thick. The dielectric function shows an anomalous dependence on the layer number. It decreases with the layer number increasing when the films are less than 5–7 layers thick but turns to increase with the layer number for thicker films. We show that this is because the excitonic effect is very strong in the thin MoS2 films and its contribution to the dielectric function may dominate over the contribution of the band structure. We also extract the value of layer-dependent exciton binding energy and Bohr radius in the films by fitting the experimental results with an intuitive model. The dominance of excitonic effects is in stark contrast with what reported at conventional materials whose dielectric functions are usually dictated by band structures. Lastly, the knowledge of the dielectric function may enable capabilities to engineer the light-matter interactions of atomically thin MoS2 films for the development of novel photonic devices, such as metamaterials, waveguides, light absorbers, and light emitters.

  9. Tribological properties of self-lubricating NiAl/Mo-based composites containing AgVO{sub 3} nanowires

    SciTech Connect (OSTI)

    Liu, Eryong; Gao, Yimin; Bai, Yaping; Yi, Gewen; Wang, Wenzhen; Zeng, Zhixiang; Jia, Junhong

    2014-11-15

    Silver vanadate (AgVO{sub 3}) nanowires were synthesized by hydrothermal method and self-lubricating NiAl/Mo-AgVO{sub 3} composites were fabricated by powder metallurgy technique. The composition and microstructure of NiAl/Mo-based composites were characterized and the tribological properties were investigated from room temperature to 900 C. The results showed that NiAl/Mo-based composites were consisted of nanocrystalline B2 ordered NiAl matrix, Al{sub 2}O{sub 3}, Mo{sub 2}C, metallic Ag and vanadium oxide phase. The appearance of metallic Ag and vanadium oxide phase can be attributed to the decomposition of AgVO{sub 3} during sintering. Wear testing results confirmed that NiAl/Mo-based composites have excellent tribological properties over a wide temperature range. For example, the friction coefficient and wear rate of NiAl/Mo-based composites containing AgVO{sub 3} were significantly lower than the composites containing only metallic Mo or AgVO{sub 3} lubricant when the temperature is above 300 C, which can be attributed to the synergistic lubricating action of metallic Mo and AgVO{sub 3} lubricants. Furthermore, Raman results indicated that the composition on the worn surface of NiAl-based composites was self-adjusted after wear testing at different temperatures. For example, Ag{sub 3}VO{sub 4} and Fe{sub 3}O{sub 4} lubricants were responsible for the improvement of tribological properties at 500 C, AgVO{sub 3}, Ag{sub 3}VO{sub 4} and molybdate for 700 C, and AgVO{sub 3} and molybdate for 900 C of NiAl-based composites with the addition of metallic Mo and AgVO{sub 3}. - Highlights: NiAl/Mo-AgVO{sub 3} nanocomposites were prepared by mechanical alloying and sintering. AgVO{sub 3} decomposed to metallic Ag and vanadium oxide during the sintering process. NiAl/Mo-AgVO{sub 3} exhibited superior tribological properties at a board temperature range. Phase composition on the worn surface was varied with temperatures. Self-adjusted action was responsible for the improvement of tribological properties.

  10. Two-dimensional GaSe/MoSe2 misfit bilayer heterojunctions by van der Waals epitaxy

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Li, Xufan; Lin, Ming-Wei; Lin, Junhao; Huang, Bing; Puretzky, Alexander A.; Ma, Cheng; Wang, Kai; Zhou, Wu; Pantelides, Sokrates T.; Chi, Miaofang; et al

    2016-04-01

    Two-dimensional (2D) heterostructures hold the promise for future atomically-thin electronics and optoelectronics due to their diverse functionalities. While heterostructures consisting of different transition metal dichacolgenide monolayers with well-matched lattices and novel physical properties have been successfully fabricated via van der Waals (vdW) or edge epitaxy, constructing heterostructures from monolayers of layered semiconductors with large lattice misfits still remains challenging. Here, we report the growth of monolayer GaSe/MoSe2 heterostructures with large lattice misfit by two-step chemical vapor deposition (CVD). Both vertically stacked and lateral heterostructures are demonstrated. The vertically stacked GaSe/MoSe2 heterostructures exhibit vdW epitaxy with well-aligned lattice orientation between themore » two layers, forming an incommensurate vdW heterostructure. However, the lateral heterostructures exhibit no lateral epitaxial alignment at the interface between GaSe and MoSe2 crystalline domains. Instead of a direct lateral connection at the boundary region where the same lattice orientation is observed between GaSe and MoSe2 monolayer domains in lateral GaSe/MoSe2 heterostructures, GaSe monolayers are found to overgrow MoSe2 during CVD, forming a stripe of vertically stacked vdW heterostructure at the crystal interface. Such vertically-stacked vdW GaSe/MoSe2 heterostructures are shown to form p-n junctions with effective transport and separation of photo-generated charge carriers between layers, resulting in a gate-tunable photovoltaic response. In conclusion, these GaSe/MoSe2 vdW heterostructures should have applications as gate-tunable field-effect transistors, photodetectors, and solar cells.« less

  11. Physicochemical properties of Dy/sup 3 +/ in single KY(MoO/sub 4/)/sub 2/

    Office of Scientific and Technical Information (OSTI)

    crystal (electron absorption, emission, IR, Raman, and magnetic data) (Journal Article) | SciTech Connect Physicochemical properties of Dy/sup 3 +/ in single KY(MoO/sub 4/)/sub 2/ crystal (electron absorption, emission, IR, Raman, and magnetic data) Citation Details In-Document Search Title: Physicochemical properties of Dy/sup 3 +/ in single KY(MoO/sub 4/)/sub 2/ crystal (electron absorption, emission, IR, Raman, and magnetic data) Electron absorption, luminescence, vibrational, and

  12. Superconducting and structural properties of {delta}-MoC{sub 0.681} cubic molybdenum carbide phase

    SciTech Connect (OSTI)

    Sathish, C.I. [Graduate School of Chemical Sciences and Engineering, Hokkaido University, Sapporo, Hokkaido 060-0810 (Japan) [Graduate School of Chemical Sciences and Engineering, Hokkaido University, Sapporo, Hokkaido 060-0810 (Japan); Superconducting Properties Unit, National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan); Guo, Yanfeng, E-mail: GUO.Yanfeng@nims.go.jp [Superconducting Properties Unit, National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan)] [Superconducting Properties Unit, National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan); Wang, Xia [Graduate School of Chemical Sciences and Engineering, Hokkaido University, Sapporo, Hokkaido 060-0810 (Japan) [Graduate School of Chemical Sciences and Engineering, Hokkaido University, Sapporo, Hokkaido 060-0810 (Japan); Superconducting Properties Unit, National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan); Tsujimoto, Yoshihiro [International Center for Materials Nanoarchitectonics (WPI-MANA), National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan)] [International Center for Materials Nanoarchitectonics (WPI-MANA), National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan); Li, Jun [Graduate School of Chemical Sciences and Engineering, Hokkaido University, Sapporo, Hokkaido 060-0810 (Japan) [Graduate School of Chemical Sciences and Engineering, Hokkaido University, Sapporo, Hokkaido 060-0810 (Japan); Superconducting Properties Unit, National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan); Zhang, Shoubao [International Center for Materials Nanoarchitectonics (WPI-MANA), National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan)] [International Center for Materials Nanoarchitectonics (WPI-MANA), National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan); Matsushita, Yoshitaka [Synchrotron X-ray Station at SPring-8, National Institute for Materials Science, 1-1-1 Kouto, Sayo-cho, Hyogo 679-5148 (Japan)] [Synchrotron X-ray Station at SPring-8, National Institute for Materials Science, 1-1-1 Kouto, Sayo-cho, Hyogo 679-5148 (Japan); Shi, Youguo; Tian, Huanfang; Yang, Huaixin; Li, Jianqi [Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190 (China)] [Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190 (China); Yamaura, Kazunari, E-mail: YAMAURA.Kazunari@nims.go.jp [Graduate School of Chemical Sciences and Engineering, Hokkaido University, Sapporo, Hokkaido 060-0810 (Japan) [Graduate School of Chemical Sciences and Engineering, Hokkaido University, Sapporo, Hokkaido 060-0810 (Japan); Superconducting Properties Unit, National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan)

    2012-12-15

    The superconducting and lattice properties of {delta}-MoC{sub 0.681} were studied by electromagnetic measurements, synchrotron X-ray diffraction, neutron diffraction, and electron diffraction. The superconducting properties (T{sub c}=12 K) of {delta}-MoC{sub 0.681} were well characterized by a weak coupling model. The carbon vacancies present in the host cubic structure were found to be robust, although the material was synthesized from stoichiometric carbon and Mo powder under a high-pressure of 6 GPa. A thermodynamically-stable structure with ordered vacancies did not account for the robust features of {delta}-MoC{sub 0.681} since the vacancies are unlikely to be ordered in long range in the host structure. A model based on inherent phonon instability theoretically predicted for a stoichiometric MoC phase might be responsible for the robust features of {delta}-MoC{sub 0.681}. - Graphical Abstract: The cubic molybdenum carbide shows an excellent superconductivity with robust carbon vacancies. Inherent phonon instability theoretically predicted for a stoichiometric MoC phase might be responsible for the vacancies rather than a thermodynamically-stable structure with vacancies ordering. Highlights: Black-Right-Pointing-Pointer The 12 K superconductivity is well characterized by a weakly coupling model. Black-Right-Pointing-Pointer Carbon vacancies are robust and disordered in the cubic host structure. Black-Right-Pointing-Pointer Inherent phonon instability might be responsible for the robust carbon vacancies in {delta}-MoC{sub 0.681}.

  13. Preparation of Al{sub 2}O{sub 3}/Mo nanocomposite powder via chemical route and spray drying

    SciTech Connect (OSTI)

    Lo, M.; Cheng, F.; Wei, W.J.

    1996-08-01

    A route to prepare nanometer-sized Mo particulates in Al{sub 2}O{sub 3} was attempted by a combination of solution reactions in molecular scale and forcing precipitation by a spray-drying technique. MoO{sub 3} was first dissolved in ammonia water and then added in the slurry with high purity, submicrometer Al{sub 2}O{sub 3} powder. Mixed suspension was spray-dried, and then the dried granules were reduced by hydrogen gas and further hot-pressing to a bulky composite at various temperatures. Dissolution of Mo oxide, adsorption reactions on alumina surface, and surface potential of alumina particles in homogeneous ammonia suspension were studied. Characterization of the granules, including compactability, flowing properties, surface morphology, grain growth of Mo and Al{sub 2}O{sub 3}, and mixing homogeneity, were examined. Homogeneity of the spray-dried granules was determined by the calculation of mixing index and the observation of the microstructure of sintered body. The existence of intergranular, intragranular, and nanosized Mo particulates within Al{sub 2}O{sub 3} grains was observed by transmission electron microscopy (TEM). All the evidences revealed that homogeneous composites with nanometer-sized Mo had been successfully prepared by this attempt with the proposed chemical route and following spray-drying process. {copyright}{ital 1996 Materials Research Society.}

  14. Low-frequency 1/f noise in MoS{sub 2} transistors: Relative contributions of the channel and contacts

    SciTech Connect (OSTI)

    Renteria, J.; Jiang, C.; Samnakay, R.; Rumyantsev, S. L.; Goli, P.; Balandin, A. A.; Shur, M. S.

    2014-04-14

    We report on the results of the low-frequency (1/f, where f is frequency) noise measurements in MoS{sub 2} field-effect transistors revealing the relative contributions of the MoS{sub 2} channel and Ti/Au contacts to the overall noise level. The investigation of the 1/f noise was performed for both as fabricated and aged transistors. It was established that the McWhorter model of the carrier number fluctuations describes well the 1/f noise in MoS{sub 2} transistors, in contrast to what is observed in graphene devices. The trap densities extracted from the 1/f noise data for MoS{sub 2} transistors, are 2??10{sup 19}?eV{sup ?1}cm{sup ?3} and 2.5??10{sup 20}?eV{sup ?1}cm{sup ?3} for the as fabricated and aged devices, respectively. It was found that the increase in the noise level of the aged MoS{sub 2} transistors is due to the channel rather than the contact degradation. The obtained results are important for the proposed electronic applications of MoS{sub 2} and other van der Waals materials.

  15. Kinetic study of hydrogen evolution reaction on Ni{sub 30} Mo{sub 70}, Co{sub 30}Mo{sub 70}, Co{sub 30}Ni{sub 70} and Co{sub 10}Ni{sub 20}Mo{sub 70} alloy electrodes

    SciTech Connect (OSTI)

    Dominguez-Crespo, M.A.; Plata-Torres, M.; Torres-Huerta, A.M.; Arce-Estrada, E.M. . E-mail: earce@ipn.mx; Hallen-Lopez, J.M.

    2005-07-15

    The hydrogen evolution reaction on nanocrystalline Ni{sub 30}Mo{sub 70}, Co{sub 30}Mo{sub 70}, Co{sub 30}Ni{sub 70}, and Co{sub 10}Ni{sub 20}Mo{sub 70}, metallic powders prepared by mechanical alloying was investigated with linear polarization and ac impedance methods, in 30 wt.% KOH aqueous solution at room temperature. The formation process and structural properties of these nanocrystalline materials were characterized by X-ray diffraction and transmission electron microscopy. Alloyed powders showed the presence of two phases: an fcc solid solution and intermetallic compounds of Ni, Co and Mo. Based on polarization and ac impedance measurements, an improved electrocatalytic activity for hydrogen evolution reaction was observed in mechanically alloyed Co{sub 30}Ni{sub 70} powders, which is slightly higher than milled metallic Ni powders.

  16. Characterization of few-layer 1T-MoSe{sub 2} and its superior performance in the visible-light induced hydrogen evolution reaction

    SciTech Connect (OSTI)

    Gupta, Uttam; Naidu, B. S.; Maitra, Urmimala; Rao, C. N. R.; Singh, Anjali; Shirodkar, Sharmila N.; Waghmare, Umesh V.

    2014-09-01

    Based on earlier results on the photocatalytic properties of MoS{sub 2}, the 1T form of MoSe{sub 2}, prepared by lithium intercalation and exfoliation of bulk MoSe{sub 2}, has been employed for the visible-light induced generation of hydrogen. 1T-MoSe{sub 2} is found to be superior to both 2H and 1T MoS{sub 2} as well as 2H-MoSe{sub 2} in producing hydrogen from water, the yield being in the 6075 mmol?h{sup ?1}?g{sup ?1} range with a turn over frequency of 1519 h{sup ?1}. First principles calculations reveal that 1T-MoSe{sub 2} has a lower work function than 2H-MoSe{sub 2} as well as 1T and 2H-MoS{sub 2}, making it easier to transfer an electron from 1T-MoSe{sub 2} for the production of H{sub 2}.

  17. A practical grinding-assisted dry synthesis of nanocrystalline NiMoO{sub 4} polymorphs for oxidative dehydrogenation of propane

    SciTech Connect (OSTI)

    Chen Miao; Wu Jialing; Liu Yongmei; Cao Yong; Guo Li; He Heyong; Fan Kangnian

    2011-12-15

    A practical two-stage reactive grinding-assisted pathway waste-free and cost-effective for the synthesis of NiMoO{sub 4} has been successfully developed. It was demonstrated that proper design in synthetic strategy for grinding plays a crucial role in determining the ultimate polymorph of NiMoO{sub 4}. Specifically, direct grinding (DG) of MoO{sub 3} and NiO rendered {alpha}-NiMoO{sub 4} after annealing, whereas sequential grinding (SG) of the two independently pre-ground oxides followed by annealing generated {beta}-NiMoO{sub 4} solid solution. Characterizations in terms of Raman and X-ray diffraction suggest the creation of {beta}-NiMoO{sub 4} precursor in the latter alternative is the key aspect for the formation of {beta}-NiMoO{sub 4}. The DG-derived {alpha}-NiMoO{sub 4} tested by oxidative dehydrogenation of propane exhibited superior activity in contrast to its analog synthesized via conventional coprecipitation. It is suggested that the favorable chemical composition facilely obtained via grinding in contrast to that by coprecipitation was essential for achieving a more selective production of propylene. - Graphical Abstract: Grinding-assisted synthesis of NiMoO{sub 4} offers higher and more reproducible activities in contrast to coprecipitation for oxidative dehydrogenation of propane, and both {alpha}- and {beta}-NiMoO{sub 4} can be synthesized. Highlights: Black-Right-Pointing-Pointer NiMoO{sub 4} was prepared through grinding-assisted pathway. Black-Right-Pointing-Pointer Direct/sequential grinding rendered {alpha}-, {beta}-NiMoO{sub 4}, respectively. Black-Right-Pointing-Pointer Grinding-derived {alpha}-NiMoO{sub 4} showed high and reproducible activity for oxidative dehydrogenation of propane.

  18. United States

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    States Department of Agriculture Forest Service Southern Research Station General Technical Report SRS-68 Bats of the Savannah River Site and Vicinity Michael A. Menzel, Jennifer M. Menzel, John C. Kilgo, W. Mark Ford, Timothy C. Carter, and John W. Edwards Authors: Michael A. Menzel, 1 Jennifer M. Menzel, 2 John C. Kilgo, 3 W. Mark Ford, 2 Timothy C. Carter, 4 and John W. Edwards 5 1 Graduate Research Assistant, Division of Forestry, Wildlife and Fisheries, West Virginia University, Morgantown,

  19. State Overview

    Energy Savers [EERE]

    PAGE | 1 Produced by Department of Energy (DOE), Office of Electricity Delivery & Energy Reliability (OE) State Overview Population: 0.63 million (<1% total U.S.) Housing Units: 0.32 million (<1% total U.S.) Business Establishments: 0.02 million (<1% total U.S.) Annual Energy Consumption Electric Power: 5.5 TWh (<1% total U.S.) Coal: 0 MSTN (0% total U.S.) Natural Gas: 392 Bcf (2% total U.S.) Motor Gasoline: 7,800 Mbarrels (<1% total U.S.) Distillate Fuel: 3,900 Mbarrels

  20. United States

    Energy Savers [EERE]

    Tenaslta Power Services Co. OE Docket No. EA-243-A Order Authorizing Electricity Exports to Canada Order No. EA-243-A March 1,2007 Tenaska Power Services Co. Order No. EA-243-A I. BACKGROUND Exports of elcctricity from the United States to a foreign country are regulated by the Department of Energy (DOE) pursuant to sections 30 I(b) and 402(f) of the Departrncnt of' Energy Organizatio~l Act (42 U, S.C. 7 15 1 (b), 7 1 72Cf)) and rcquirc authorization under section 202(e) of the Federal Power Act

  1. United States

    Energy Savers [EERE]

    BP Energy Company OE Docket No. EA- 3 14 Order Authorizing Electricity Exports to Mexico Order No. EA-3 14 February 22,2007 BP Energy Company Order No. EA-314 I. BACKGROUND Exports of electricity from the United States to a foreign country are regulated by the Department of Energy (DOE) pursuant to sections 301(b) and 402(Q of the Department of Energy Organization Act (42 U.S.C. 7 15 l(b), 7172(f)) and require authorization under section 202(e) of the Federal Power Act (FPA) (16 U.S.C.S24a(e)) .

  2. States Government

    Office of Legacy Management (LM)

    ,.' &I ,J?5.8 = , sr; i&L:E%, 7-e;, iB 1 L Unitbd ' States Government ma.morandum DATE: $I$! 24 ml1 Department of Energy y;;;z EM-421 .- Elimination of the Landis Machine Company site SVWECT: The File TO: I have reviewed the attached site summary and elimination recommendation for the Landis Machine Company site in Waynesboro, Pennsylvania. I have determined that there is little likelihood of radioactive contamination at this site. Based' on the above, the Landis Machine Company site is

  3. Surface structure determinations of ordered sulfur overlayers on Mo(100) and Re(0001) by low-energy electron diffraction intensity analysis

    SciTech Connect (OSTI)

    Jentz, D.W.

    1992-11-01

    A newly developed method for surface structure determination, tensor LEED, combined with automated search was used to analyze the structures. The ordered structures of S on Mo(100) which were studied formed a c(2 {times} 2), c(4 {times} 2), and p(2 {times} l) periodicities at coverages of 0.5, 0.75, 1.0 ML (monolayers, of one sulfur atom per one molybdenum atom) respectively. A MO{sub 2}S-like overlayer, which formed at coverages greater than 1.0 ML, is also discussed. Calculations for the c(2 {times} 2) structure gave a best fit geometry with S adsorbed in a four-fold symmetric hollow site and the second layer buckled by 0.09{Angstrom}. The S-Mo bond length is 2.45{Angstrom} and the Pendry R-factor is 0.21. Preliminary calculations for the c(4 {times} 2) structure did not yield an acceptable fit. The three models tried are discussed. Calculations for p(2 {times} l) data did not yield an acceptable geometry either. The types of models that were tried are discussed. Implications of this analysis are discussed along with results of a scanning tunneling microscopy (STM) investigation. The ordered structures on the RE(0001) surface studied have p(2 {times} 2) and (2{radical}3 {times} 2{radical}3)R30{degree} periodicities and occurred at S coverages of 0.25 and 0.5 ML respectively. Best fit structure for p(2 {times} 2) structure has S adsorbed in a three-fold hollow hcp site and exhibits a buckling of the first and second Re layers. The first layer is buckled by 0.05{Angstrom} and the second layer is buckled by 0.06{Angstrom}. Re-S bond length is 2.32{Angstrom} and Pendry R-factor is 0.21. Preliminary results of dynamical LEED investigation of (2{radical}3 {times} 2{radical}3)R30{degree} structure show reasonable agreement with a model with a 6-S atom basis.

  4. Martensitic transformation behaviors of rapidly solidified TiNiMo powders

    SciTech Connect (OSTI)

    Kim, Yeon-wook

    2012-10-15

    For the fabrication of bulk near-net-shape shape memory alloys and porous metallic biomaterials, consolidation of TiNiMo alloy powders is more useful than that of elemental powders of Ti, Ni and Mo. Ti{sub 50}Ni{sub 49.9}Mo{sub 0.1} shape memory alloy powders were prepared by gas atomization, and transformation temperatures and microstructures of those powders were investigated as a function of powder size. XRD analysis showed that the B2RB19 martensitic transformation occurred in powders smaller than 150 ?m. According to DSC analysis of the as-atomized powders, the B2R transformation temperature (T{sub R}) of the 2550 ?m powders was 18.4 C. The T{sub R} decreased with increasing powder size, however, the difference in T{sub R} between 2550 ?m powders and 100150 ?m powders is only 1 C. Evaluation of powder microstructures was based on SEM examination of the surface and the polished and etched powder cross sections and the typical images of the rapidly solidified powders showed cellular morphology. Porous cylindrical foams of 10 mm diameter and 1.5 mm length were fabricated by spark plasma sintering (SPS) at 800 C and 5 MPa. Finally these porous TiNi alloy samples are heat-treated for 1 h at 850 C, and then quenched in ice water. The bulk samples have 23% porosity and 4.6 g/cm{sup 3} density and their T{sub R} is 17.8 C.

  5. Corrosion and degradation of a polyurethane/Co-Ni-Cr-Mo pacemaker lead

    SciTech Connect (OSTI)

    Sung, P.; Fraker, A.C.

    1987-12-01

    An investigation to study changes in the metal surfaces and the polyurethane insulation of heart pacemaker leads under controlled in vitro conditions was conducted. A polyurethane (Pellethane 2363-80A)/Co-Ni-Cr-Mo (MP35N) wire lead was exposed in Hanks' physiological saline solution for 14 months and then analyzed using scanning electron microscopy, x-ray energy dispersive analysis, and small angle x-ray scattering. Results showed that some leakage of solution into the lead had occurred and changes were present on both the metal and the polyurethane surfaces.

  6. FULL SIZE U-10MO MONOLITHIC FUEL FOIL AND FUEL PLATE FABRICATION-TECHNOLOGY DEVELOPMENT

    SciTech Connect (OSTI)

    G. A. Moore; J-F Jue; B. H. Rabin; M. J. Nilles

    2010-03-01

    Full-size U10Mo foils are being developed for use in high density LEU monolithic fuel plates. The application of a zirconium barrier layer too the foil is applied using a hot co-rolling process. Aluminum clad fuel plates are fabricated using Hot Isostatic Pressing (HIP) or a Friction Bonding (FB) process. An overview is provided of ongoing technology development activities, including: the co-rolling process, foil shearing/slitting and polishing, cladding bonding processes, plate forming, plate-assembly swaging, and fuel plate characterization. Characterization techniques being employed include, Ultrasonic Testing (UT), radiography, and microscopy.

  7. Pairing correlations and thermodynamical quantities in {sup 96,97}Mo

    SciTech Connect (OSTI)

    Kargar, Z.

    2007-06-15

    The nuclear level densities of {sup 96,97}Mo are calculated in the framework of superconducting theory. The parameters of nuclear level density are so chosen that the saddle point conditions are satisfied and the best fit to the experimental data yields. Then, using these parameters the energy, the entropy and the spin cut-off factor are calculated as a function of temperature. The curves show structures, reflecting the phase transition from a correlated to an uncorrelated phase. The critical temperature for quenching of pairing correlations is found at T{sub c}{approx}0.7-0.9 MeV.

  8. Hydrofining of Athabasca derived heavy gas oil over Ni-W and Co-Mo catalysts

    SciTech Connect (OSTI)

    Mann, R.S.; Diaz-real, R.

    1987-01-01

    The hydrotreatment of heavy gas oil derived from Athabasca bitumen was studied in a trickle bed reactor over Ni-W and Co-Mo zeolite catalyst at 350-425/sup 0/C, 3.55 to 10.44 MPa, and LHSV of 1-4. The effects of temperature and liquid flow rates on the product were investigated. ASTM distillation, aniline point, viscosities and densities of the product oil were measured and correlated with various parameters. Activity of the catalysts for hydrodenitrogenation is compared.

  9. Room-temperature thermally induced relaxation effect in a two-dimensional cyano-bridged Cu-Mo bimetal assembly and thermodynamic analysis of the relaxation process

    SciTech Connect (OSTI)

    Umeta, Yoshikazu; Ozaki, Noriaki; Tokoro, Hiroko; Ohkoshi, Shin-ichi

    2013-04-15

    We observed a photo-switching effect in [Cu{sup II}(1,4,8,11-tetraazacyclodecane)]{sub 2}[Mo{sup IV}(CN){sub 8}]{center_dot}10H{sub 2}O by irradiation with 410-nm light around room temperature using infrared spectroscopy. This photo-switching is caused by the photo-induced charge transfer from Mo{sup IV} to Cu{sup II}. The photo-induced phase thermally relaxed to the initial phase with a half-life time of 2.7 Multiplication-Sign 10{sup 1}, 6.9 Multiplication-Sign 10{sup 1}, and 1.7 Multiplication-Sign 10{sup 2} s at 293, 283, and 273 K, respectively. The relaxation process was analyzed using Hauser's equation, k=k{sub 0}exp[-(E{sub a}+E{sub a}{sup *}{gamma}) /k{sub B}T], where k is the rate constant of relaxation, k{sub 0} is the frequency factor, E{sub a} is the activation energy, E{sub a}{sup *} is the additional activation energy due to the cooperativity, and {gamma} is the fraction of the photo-induced phase. k{sub 0}, E{sub a}, and E{sub a}{sup *} were evaluated as 1.28 Multiplication-Sign 10{sup 7}{+-} 2.6 s{sup -1}, 4002 {+-} 188 cm{sup -1}, and 546 {+-} 318 cm{sup -1}, respectively. The value of E{sub a} is much larger than that of the relaxation process for the typical light-induced spin crossover effect (E{sub a} Almost-Equal-To 1000 cm{sup -1}). Room-temperature photo-switching is an important issue in the field of optical functional materials. The present system is useful for the demonstration of high-temperature photo-switching material.

  10. In Situ Time-Resolved Characterization of Novel Cu-MoO2 Catalysts During the Water-Gas Shift Reaction

    SciTech Connect (OSTI)

    Wen ,W.; Liu, J.; White, M.; Marinkovic, N.; Hanson, J.; Rodriguez, J.

    2007-01-01

    A novel and active Cu-MoO{sub 2} catalyst was synthesized by partial reduction of a precursor CuMoO{sub 4} mixed-metal oxide with CO or H{sub 2} at 200-250 C. The phase transformations of Cu-MoO{sub 2} during H{sub 2} reduction and the water-gas shift reaction could be followed by In situ time resolved XRD techniques. During the reduction process the diffraction pattern of the CuMoO{sub 4} collapsed and the copper metal lines were observed on an amorphous material background that was assigned to molybdenum oxides. During the first pass of water-gas shift (WGS) reaction, diffraction lines for Cu{sub 6}Mo{sub 5}O{sub 18} and MoO{sub 2} appeared around 350 C and Cu{sub 6}Mo{sub 5}O{sub 18} was further transformed to Cu/MoO{sub 2} at higher temperature. During subsequent passes, significant WGS catalytic activity was observed with relatively stable plateaus in product formation around 350, 400 and 500 C. The interfacial interactions between Cu clusters and MoO{sub 2} increased the water-gas shift catalytic activities at 350 and 400 C.

  11. Extraordinary selectivity of CoMo{sub 3}S{sub 13} chalcogel for C{sub 2}H{sub 6} and CO{sub 2} adsorption.

    SciTech Connect (OSTI)

    Shafaei-Fallah, M.; Rothenberger, Z.; Katsoulidis, A. P.; He, J.; Malliakas, C. D.; Kanatzidis, M. G.

    2011-11-09

    The chalcogel CoMo{sub 3}S{sub 13} is obtained from the reaction of (NH{sub 4}){sub 2}[Mo{sub 3}S{sub 13}] with cobalt acetate in solution. The chalcogel has a BET surface area of 570 m{sup 2} g{sup -1}, and pair distribution function analysis (PDF) and infrared spectroscopy indicate that the [Mo{sub 3}S{sub 13}]{sup 2-} cluster is a building block in the porous network. The CoMo{sub 3}S{sub 13} chalcogel exhibits high selectivity for separating ethane and carbon dioxide from hydrogen and methane.

  12. Localized Corrosion of a Neutron Absorbing Ni-Cr-Mo-Gd Alloy

    SciTech Connect (OSTI)

    R.E. Mizia; T. E. Lister; P. J. Pinhero; T. L. Trowbridge

    2005-04-01

    The National Spent Nuclear Fuel Program, located at the Idaho National Laboratory (INL), has developed a new nickel-chromium-molybdenum-gadolinium structural alloy for storage and long-term disposal of spent nuclear fuel (SNF). The new alloy will be used for SNF storage container inserts for nuclear criticality control. Gadolinium has been chosen as the neutron absorption alloying element due to its high thermal neutron absorption cross section. This alloy must be resistant to localized corrosion when exposed to postulated Yucca Mountain in-package chemistries. The corrosion resistance properties of three experimental heats of this alloy are presented. The alloys performance are be compared to Alloy 22 and borated stainless steel. The results show that initially the new Ni-Cr-Mo-Gd alloy is less resistant to corrosion as compared to another Ni-Cr-Mo-Gd alloy (Alloy 22); but when the secondary phase that contains gadolinium (gadolinide) is dissolved, the alloy surface becomes passive. The focus of this work is to qualify these gadolinium containing materials for ASME code qualification and acceptance in the Yucca Mountain Repository.

  13. Experimental study of the electric dipole strength in the even Mo nuclei and its deformation dependence

    SciTech Connect (OSTI)

    Erhard, M.; Junghans, A. R.; Nair, C.; Schwengner, R.; Beyer, R.; Klug, J.; Kosev, K.; Wagner, A.; Grosse, E.

    2010-03-15

    Two methods based on bremsstrahlung were applied to the stable even Mo isotopes for the experimental determination of the photon strength function covering the high excitation energy range above 4 MeV with its increasing level density. Photon scattering was used up to the neutron separation energies S{sub n} and data up to the maximum of the isovector giant resonance (GDR) were obtained by photoactivation. After a proper correction for multistep processes the observed quasicontinuous spectra of scattered photons show a remarkably good match to the photon strengths derived from nuclear photoeffect data obtained previously by neutron detection and corrected in absolute scale by using the new activation results. The combined data form an excellent basis to derive a shape dependence of the E1 strength in the even Mo isotopes with increasing deviation from the N=50 neutron shell (i.e., with the impact of quadrupole deformation and triaxiality). The wide energy coverage of the data allows for a stringent assessment of the dipole sum rule and a test of a novel parametrization developed previously which is based on it. This parametrization for the electric dipole strength function in nuclei with A>80 deviates significantly from prescriptions generally used previously. In astrophysical network calculations it may help to quantify the role the p-process plays in cosmic nucleosynthesis. It also has impact on the accurate analysis of neutron capture data of importance for future nuclear energy systems and waste transmutation.

  14. Spin and valley transport in monolayers of MoS{sub 2}

    SciTech Connect (OSTI)

    Sun, J. F.; Cheng, F.

    2014-04-07

    We investigate theoretically quantum transport and Goos-Hnchen (GH) effect of electrons in a p-n-p junction on monolayers of MoS{sub 2}. We find that the transmission properties of spin-up (spin-down) electrons in K valley are the same with spin-down (spin-up) electrons in K? valley due to the time-reversal symmetry. The GH shifts for the transmitted K and K? beams in the n-p interface are in the opposite direction, and GH shifts for the spin-up and spin-down electron beams at the same valley have different values in the same direction due to the different group velocities. Therefore, the spin-up and spin-down electrons can be separated after passing a sufficiently long channel created by a p-n-p junction. These features provide us a new way to generate a fully spin- and valley-polarized current in monolayers of MoS{sub 2}.

  15. Electronic structure and conductivity of nanocomposite metal (Au,Ag,Cu,Mo)-containing amorphous carbon films

    SciTech Connect (OSTI)

    Endrino, Jose L.; Horwat, David; Gago, Raul; Andersson, Joakim; Liu, Y.S.; Guo, Jinghua; Anders, Andre

    2008-05-14

    In this work, we study the influence of the incorporation of different metals (Me = Au, Ag, Cu, Mo) on the electronic structure of amorphous carbon (a-C:Me) films. The films were produced at room temperature using a novel pulsed dual-cathode arc deposition technique. Compositional analysis was performed with secondary neutral mass spectroscopy whereas X-ray diffraction was used to identify the formation of metal nanoclusters in the carbon matrix. The metal content incorporated in the nanocomposite films induces a drastic increase in the conductivity, in parallel with a decrease in the band gap corrected from Urbach energy. The electronic structure as a function of the Me content has been monitored by x-ray absorption near edge structure (XANES) at the C K-edge. XANES showed that the C host matrix has a dominant graphitic character and that it is not affected significantly by the incorporation of metal impurities, except for the case of Mo, where the modifications in the lineshape spectra indicated the formation of a carbide phase. Subtle modifications of the spectral lineshape are discussed in terms of nanocomposite formation.

  16. Raman shifts in electron-irradiated monolayer MoS2

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Parkin, William M.; Balan, Adrian; Liang, Liangbo; Das, Paul Masih; Lamparski, Michael; Naylor, Carl H.; Rodríguez-Manzo, Julio A.; Johnson, A. T. Charlie; Meunier, Vincent; Drndic, Marija

    2016-03-21

    Here, we report how the presence of electron-beam-induced sulfur vacancies affects first-order Raman modes and correlate the effects with the evolution of the in situ transmission-electron microscopy (TEM) two-terminal conductivity of monolayer MoS2 under electron irradiation. We observe a redshift in the E Raman peak and a less pronounced blueshift in the A'1 peak with increasing electron dose. Using energy-dispersive X-ray spectroscopy (EDS), we show that irradiation causes partial removal of sulfur and correlate the dependence of the Raman peak shifts with S vacancy density (a few %), which is confirmed by first-principles density functional theory calculations. In situ devicemore » current measurements show exponential decrease in channel current upon irradiation. Our analysis demonstrates that the observed frequency shifts are intrinsic properties of the defective systems and that Raman spectroscopy can be used as a quantitative diagnostic tool to characterize MoS2-based transport channels.« less

  17. Spectroscopic signatures of AA' and AB stacking of chemical vapor deposited bilayer MoS2

    SciTech Connect (OSTI)

    Xia, Ming; Li, Bo; Yin, Kuibo; Capellini, Giovanni; Niu, Gang; Gong, Yongji; Zhou, Wu; Ajayan, Pulickel M.; Xie, Ya -Hong

    2015-11-04

    We discuss prominent resonance Raman and photoluminescence spectroscopic differences between AA'and AB stacked bilayer molybdenum disulfide (MoS2) grown by chemical vapor deposition are reported. Bilayer MoS2 islands consisting of the two stacking orders were obtained under identical growth conditions. Also, resonance Raman and photoluminescence spectra of AA' and AB stacked bilayer MoS2 were obtained on Au nanopyramid surfaces under strong plasmon resonance. Both resonance Raman and photoluminescence spectra show distinct features indicating clear differences in interlayer interaction between these two phases. The implication of these findings on device applications based on spin and valley degrees of freedom.

  18. State Total

    U.S. Energy Information Administration (EIA) Indexed Site

    State Total Percent of U.S. total Alabama 1,652 0.0 Alaska 152 0.0 Arizona 912,975 19.9 Arkansas 2,724 0.1 California 2,239,983 48.8 Colorado 49,903 1.1 Connecticut 33,627 0.7 Delaware 3,080 0.1 District of Columbia 1,746 0.0 Florida 22,061 0.5 Georgia 99,713 2.2 Guam 39 0.0 Hawaii 126,595 2.8 Idaho 1,423 0.0 Illinois 8,176 0.2 Indiana 12,912 0.3 Iowa 4,480 0.1 Kansas 523 0.0 Kentucky 2,356 0.1 Louisiana 27,704 0.6 Maine 993 0.0 Maryland 30,528 0.7 Massachusetts 143,539 3.1 Michigan 3,416 0.1

  19. Structural, magnetic, and superconducting properties of pulsed-laser-deposition-grown La1.85 Sr0.15 CuO4 / La2<mo>/>3 Ca1<mo>/>3 MnO3 superlattices on (001)-oriented LaSrAlO4 substrates

    SciTech Connect (OSTI)

    Das, S.; Sen, K.; Marozau, I.; Uribe-Laverde, M. A.; Biskup, N.; Varela, M.; Khaydukov, Y.; Soltwedel, O.; Keller, T.; Döbeli, M.; Schneider, C. W.; Bernhard, C.

    2014-03-12

    Epitaxial La1.85 Sr0.15 CuO4 / La2<mo>/>3 Ca1<mo>/>3 MnO3 (LSCO/LCMO) superlattices (SL) on (001)- oriented LaSrAlO4 substrates have been grown with pulsed laser deposition (PLD) technique. Their structural, magnetic and superconducting properties have been determined with in-situ reflection high energy electron diffraction (RHEED), x-ray diffraction, specular neutron reflectometry, scanning transmission electron microscopy (STEM), electric transport, and magnetization measurements. We find that despite the large mismatch between the in-plane lattice parameters of LSCO (a = 0.3779 nm) and LCMO (a = 0.387 nm) these superlattices can be grown epitaxially and with a high crystalline quality. While the first LSCO layer remains clamped to the LSAO substrate, a sizeable strain relaxation occurs already in the first LCMO layer. The following LSCO and LCMO layers adopt a nearly balanced state in which the tensile and compressive strain effects yield alternating in-plane lattice parameters with an almost constant average value. No major defects are observed in the LSCO layers, while a significant number of vertical antiphase boundaries are found in the LCMO layers. The LSCO layers remain superconducting with a relatively high superconducting onset temperature of Tconset ≈ 36 K. The macroscopic superconducting response is also evident in the magnetization data due to a weak diamagnetic signal below 10 K for H ∥ ab and a sizeable paramagnetic shift for H ∥ c that can be explained in terms of a vortex-pinning-induced flux compression. The LCMO layers maintain a strongly ferromagnetic state with a Curie temperature of TCurie ≈ 190 K and a large low-temperature saturation moment of about 3.5 (1) μB. These results suggest that the LSCO/LCMO superlattices can be used to study the interaction between the antagonistic ferromagnetic and superconducting orders and, in combination with previous studies on YBCO/LCMO superlattices, may allow one to identify the relevant mechanisms.

  20. Preparation and immunoreactivity of high specific activity indium-111-DTPA labeled monoclonal antibody (MoAb) using ultrapure indium-111

    SciTech Connect (OSTI)

    Zoghbi, S.S.; Neumann, R.D.; Gottschalk, A.

    1986-10-01

    The preparation of high-specific activity /sup 111/In-DTPA-MoAb without increasing the number of DTPA molecules per Ab was investigated. Instant thin layer chromatography was used to assay the relationship between labeling efficiencies and specific activities. With ultrapurified /sup 111/In, the specific activity of the radiolabeled MoAb approached the expected theoretic maximum of 100 muCi/microgram. The bioactivity of such high-specific activity preparation showed no degradation as measured by in vitro cell binding assay.

  1. MoO3 as combined hole injection layer and tapered spacer in combinatorial multicolor microcavity organic light emitting diodes

    SciTech Connect (OSTI)

    Liu, R.; Xu, Chun; Biswas, Rana; Shinar, Joseph; Shinar, Ruth

    2011-09-01

    Multicolor microcavity ({mu}C) organic light-emitting diode (OLED) arrays were fabricated simply by controlling the hole injection and spacer MoO{sub 3} layer thickness. The normal emission was tunable from {approx}490 to 640 nm and can be further expanded. A compact, integrated spectrometer with two-dimensional combinatorial arrays of {mu}C OLEDs was realized. The MoO{sub 3} yields more efficient and stable devices, revealing a new breakdown mechanism. The pixel current density reaches {approx}4 A/cm{sup 2} and a maximal normal brightness {approx}140 000 Cd/m{sup 2}, which improves photoluminescence-based sensing and absorption measurements.

  2. Comparison of Two Preparation Methods on Catalytic Activity and Selectivity of Ru-Mo/HZSM5 for Methane Dehydroaromatization

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Petkovic, Lucia M.; Ginosar, Daniel M.

    2014-01-01

    Catalytic performance of Mo/HZSM5 and Ru-Mo/HZSM5 catalysts prepared by vaporization-deposition of molybdenum trioxide and impregnation with ammonium heptamolybdate was analyzed in terms of catalyst activity and selectivity, nitrogen physisorption analyses, temperature-programmed oxidation of carbonaceous residues, and temperature-programmed reduction. Vaporization-deposition rendered the catalyst more selective to ethylene and coke than the catalyst prepared by impregnation. This result was assigned to lower interaction of molybdenum carbide with the zeolite acidic sites.

  3. Enhancing the photocurrent and photoluminescence of single crystal monolayer MoS{sub 2} with resonant plasmonic nanoshells

    SciTech Connect (OSTI)

    Sobhani, Ali [Department of Electrical and Computer Engineering, Rice University, Houston, Texas 77005 (United States); Lauchner, Adam [Department of Physics and Astronomy, Rice University, Houston, Texas 77005 (United States); Najmaei, Sina; Lou, Jun [Department of Materials Science and NanoEngineering, Rice University, Houston, Texas 77005 (United States); Ayala-Orozco, Ciceron; Wen, Fangfang [Department of Chemistry, Rice University, Houston, Texas 77005 (United States); Halas, Naomi J., E-mail: halas@rice.edu [Department of Electrical and Computer Engineering, Rice University, Houston, Texas 77005 (United States); Department of Physics and Astronomy, Rice University, Houston, Texas 77005 (United States)

    2014-01-20

    Monolayer molybdenum disulfide (MoS{sub 2}) produced by controlled vapor-phase synthesis is a commercially promising new two-dimensional material for optoelectronics because of its direct bandgap and broad absorption in the visible and ultraviolet regimes. By tuning plasmonic core-shell nanoparticles to the direct bandgap of monolayer MoS{sub 2} and depositing them sparsely (<1% coverage) onto the material's surface, we observe a threefold increase in photocurrent and a doubling of photoluminescence signal for both excitonic transitions, amplifying but not altering the intrinsic spectral response.

  4. Comprehensive amplitude analysis of γγ<mo stretchy='false'>→mo>π<mo>+mo>π<mo>-,>π0π0 and K<mo accent='true' stretchy='true'>¯mo>K below 1.5 GeV

    SciTech Connect (OSTI)

    Dai, Ling-Yun; Pennington, Michael R.

    2014-08-15

    In this paper we perform an amplitude analysis of essentially all published pion and kaon pair production data from two photon collisions below 1.5 GeV. This includes all the high statistics results from Belle, as well as older data from Mark II at SLAC, CELLO at DESY, Crystal Ball at SLAC. The purpose of this analysis is to provide as close to a model-independent determination of the γγ to meson pair amplitudes as possible. Having data with limited angular coverage, typically |cosθ| < 0.6-0.8, and no polarization information for reactions in which spin is an essential complication, the determination of the underlying amplitudes might appear an intractable problem. However, imposing the basic constraints required by analyticity, unitarity, and crossing-symmetry makes up for the experimentally missing information. Above 1.5 GeV multi-meson production channels become important and we have too little information to resolve the amplitudes. Nevertheless, below 1.5 GeV the two photon production of hadron pairs serves as a paradigm for the application of S-matrix techniques. Final state interactions among the meson pairs is critical to this analysis. To fix these, we include the latest ππ → ππ, K⁻K scattering amplitudes given by dispersive analyses, supplemented in the K⁻K threshold region by the recent precision Dalitz plot analysis from BaBar. With these hadronic amplitudes built into unitarity, we can constrain the overall description of γγ → ππ and K⁻K datasets, both integrated and differential cross-sections, including the high statistics charged and neutral pion data from Belle. A region of solutions is found for the γγ → ππ partial waves with both isospin 0 and 2. Since this analysis invokes coupled hadronic channels, even the relatively poor integrated cross-section data on γγ → K⁻K narrows the patch of solutions to essentially a single form. For this we present the complete partial wave amplitudes, show how well they fit all the available data, and give the two photon couplings of scalar and tensor resonances that appear.

  5. Management & Operating (M&O) Contracts | U.S. DOE Office of Science...

    Office of Science (SC) Website

    ... Iowa State University DE-AC02-07CH11358 1242006 12312016 8 years Award Term Earnedadditional 7 years Award Term Available 12312026 Iowa State University Argonne ...

  6. Toward epitaxially grown two-dimensional crystal hetero-structures: Single and double MoS{sub 2}/graphene hetero-structures by chemical vapor depositions

    SciTech Connect (OSTI)

    Lin, Meng-Yu [Graduate Institute of Electronics Engineering, National Taiwan University, Taipei, Taiwan (China); Research Center for Applied Sciences, Academia Sinica, Nankang, Taipei, Taiwan (China); Chang, Chung-En [Department of Photonics, National Chiao-Tung University, Hsinchu, Taiwan (China); Wang, Cheng-Hung [Institute of Display, National Chiao-Tung University, Hsinchu, Taiwan (China); Su, Chen-Fung; Chen, Chi [Research Center for Applied Sciences, Academia Sinica, Nankang, Taipei, Taiwan (China); Lee, Si-Chen [Graduate Institute of Electronics Engineering, National Taiwan University, Taipei, Taiwan (China); Lin, Shih-Yen, E-mail: shihyen@gate.sinica.edu.tw [Graduate Institute of Electronics Engineering, National Taiwan University, Taipei, Taiwan (China); Research Center for Applied Sciences, Academia Sinica, Nankang, Taipei, Taiwan (China); Department of Photonics, National Chiao-Tung University, Hsinchu, Taiwan (China)

    2014-08-18

    Uniform large-size MoS{sub 2}/graphene hetero-structures fabricated directly on sapphire substrates are demonstrated with layer-number controllability by chemical vapor deposition (CVD). The cross-sectional high-resolution transmission electron microscopy (HRTEM) images provide the direct evidences of layer numbers of MoS{sub 2}/graphene hetero-structures. Photo-excited electron induced Fermi level shift of the graphene channel are observed on the single MoS{sub 2}/graphene hetero-structure transistors. Furthermore, double hetero-structures of graphene/MoS{sub 2}/graphene are achieved by CVD fabrication of graphene layers on top of the MoS{sub 2}, as confirmed by the cross-sectional HRTEM. These results have paved the possibility of epitaxially grown multi-hetero-structures for practical applications.

  7. Heat treated 9 Cr-1 Mo steel material for high temperature application

    DOE Patents [OSTI]

    Jablonski, Paul D.; Alman, David; Dogan, Omer; Holcomb, Gordon; Cowen, Christopher

    2012-08-21

    The invention relates to a composition and heat treatment for a high-temperature, titanium alloyed, 9 Cr-1 Mo steel exhibiting improved creep strength and oxidation resistance at service temperatures up to 650.degree. C. The novel combination of composition and heat treatment produces a heat treated material containing both large primary titanium carbides and small secondary titanium carbides. The primary titanium carbides contribute to creep strength while the secondary titanium carbides act to maintain a higher level of chromium in the finished steel for increased oxidation resistance, and strengthen the steel by impeding the movement of dislocations through the crystal structure. The heat treated material provides improved performance at comparable cost to commonly used high-temperature steels such as ASTM P91 and ASTM P92, and requires heat treatment consisting solely of austenization, rapid cooling, tempering, and final cooling, avoiding the need for any hot-working in the austenite temperature range.

  8. Microstructural Characterization of Irradiated U-7Mo/Al-5Si Dispersion to High Fission Density

    SciTech Connect (OSTI)

    J. Gan; B. D. Miller; D. D. Keiser, Jr.; A. B. Robinson; J. W. Madden; P. G. Medvedev; D. M. Wachs

    2014-11-01

    The fuel development program for research and test reactors calls for improved knowledge on the effect of microstructure on fuel performance in reactors. This work summarizes the recent TEM microstructural characterization of an irradiated U-7Mo/Al-5Si dispersion fuel plate (R3R050) irradiated in the Advanced Test Reactor (ATR) at Idaho National Laboratory to 5.21021 fissions/cm3. While a large fraction of the fuel grains is decorated with large bubbles, there is no evidence showing interlinking of these large bubbles at the specified fission density. The attachment of solid fission product precipitates to the bubbles is likely the result of fission product diffusion into these bubbles. The process of fission gas bubble superlattice collapse appears through bubble coalescence. The results are compared with the previous TEM work of the dispersion fuels irradiated to lower fission density from the same fuel plate.

  9. Extreme ultraviolet spectra of highly ionized Ge, Kr and Mo emitted by imploding plasmas

    SciTech Connect (OSTI)

    Goldsmith, S.; Feldman, U.; Cohen, L.; Behring, W.E.

    1984-01-01

    Spectra of highly ionized Ge, Kr and Mo in the spectral region of 10 to 80A were excited in laser-produced plasmas. The plasma was obtained by focusing the energy of the 24 laser beams of the University of Rochester Omega system on 0.4 mm diameter microballoon targets. The laser pulse duration was in the range of 0.87 to 1.09 ns, with total energy in the range of 1.8 to 2.2 kJ. The observed spectral lines include n = 2-2 transitions in the oxygen and fluorine isoelectronic sequences and n = 3 to 4 transitions in the sodium, magnesium and aluminum isoelectronic sequences. The present observations are compared with previous experimental and theoretical studies.

  10. Intense femtosecond photoexcitation of bulk and monolayer MoS{sub 2}

    SciTech Connect (OSTI)

    Paradisanos, I.; Fotakis, C.; Kymakis, E.; Kioseoglou, G.; Stratakis, E.

    2014-07-28

    The effect of femtosecond laser irradiation on bulk and single-layer MoS{sub 2} on silicon oxide is studied. Optical, field emission scanning electron microscopy and Raman microscopy were used to quantify the damage. The intensity of A{sub 1g} and E{sub 2g}{sup 1} vibrational modes was recorded as a function of the number of irradiation pulses. The observed behavior was attributed to laser-induced bond breaking and subsequent atoms removal due to electronic excitations. The single-pulse optical damage threshold was determined for the monolayer and bulk under 800?nm and 1030?nm pulsed laser irradiation, and the role of two-photon versus one photon absorption effects is discussed.

  11. Thermodynamic modeling and experimental validation of the Fe-Al-Ni-Cr-Mo alloy system

    SciTech Connect (OSTI)

    Teng, Zhenke; Zhang, F; Miller, Michael K; Liu, Chain T; Huang, Shenyan; Chou, Y.T.; Tien, R; Chang, Y A; Liaw, Peter K

    2012-01-01

    NiAl-type precipitate-strengthened ferritic steels have been known as potential materials for the steam turbine applications. In this study, thermodynamic descriptions of the B2-NiAl type nano-scaled precipitates and body-centered-cubic (BCC) Fe matrix phase for four alloys based on the Fe-Al-Ni-Cr-Mo system were developed as a function of the alloy composition at the aging temperature. The calculated phase structure, composition, and volume fraction were validated by the experimental investigations using synchrotron X-ray diffraction and atom probe tomography. With the ability to accurately predict the key microstructural features related to the mechanical properties in a given alloy system, the established thermodynamic model in the current study may significantly accelerate the alloy design process of the NiAl-strengthened ferritic steels.

  12. High reflectance-low stress Mo-Si multilayer reflective coatings

    DOE Patents [OSTI]

    Montcalm, Claude; Mirkarimi, Paul B.

    2000-01-01

    A high reflectance-low stress Mo-Si multilayer reflective coating particularly useful for the extreme ultraviolet (EUV) wavelength region. While the multilayer reflective coating has particular application for EUV lithography, it has numerous other applications where high reflectance and low stress multilayer coatings are utilized. Multilayer coatings having high near-normal incidence reflectance (R.gtoreq.65%) and low residual stress (.ltoreq.100 MPa) have been produced using thermal and non-thermal approaches. The thermal approach involves heating the multilayer coating to a given temperature for a given time after deposition in order to induce structural changes in the multilayer coating that will have an overall "relaxation" effect without reducing the reflectance significantly.

  13. Process for fabricating high reflectance-low stress Mo--Si multilayer reflective coatings

    DOE Patents [OSTI]

    Montcalm, Claude; Mirkarimi, Paul B.

    2001-01-01

    A high reflectance-low stress Mo--Si multilayer reflective coating particularly useful for the extreme ultraviolet (EUV) wavelength region. While the multilayer reflective coating has particular application for EUV lithography, it has numerous other applications where high reflectance and low stress multilayer coatings are utilized. Multilayer coatings having high near-normal incidence reflectance (R.gtoreq.65%) and low residual stress (.ltoreq.100 MPa) have been produced using thermal and non-thermal approaches. The thermal approach involves heating the multilayer coating to a given temperature for a given time after deposition in order to induce structural changes in the multilayer coating that will have an overall "relaxation" effect without reducing the reflectance significantly.

  14. UPDATE ON FRICTION BONDING OF MONOLITHIC U-MO FUEL PLATES

    SciTech Connect (OSTI)

    D. E. Burkes; N. P. Hallinan; J. M. Wight; M. D. Chapple

    2007-09-01

    Friction Bonding (FB), formerly referred to as Friction Stir Welding, is an alternative plate fabrication technique to encapsulate monolithic U-Mo fuel foils inside 6061-T6 aluminum alloy cladding. Over the past year, significant progress has been made in the area of FB, including improvements in tool material, tool design, process parameters, cooling capability and capacity and modeling, all of which improve and enhance the quality of fabricated fuel plates, reproducibility of the fabrication process and bond quality of the fuel plates. Details of this progress and how it relates to the observed improvements and enhancements are discussed. In addition, details on how these improvements have been implemented into the last two RERTR mini-plate irradiation campaigns are also discussed.

  15. High-temperature behavior of dicesium molybdate Cs{sub 2}MoO{sub 4}: Implications for fast neutron reactors

    SciTech Connect (OSTI)

    Wallez, Gilles; Raison, Philippe E.; Smith, Anna L.; Clavier, Nicolas

    2014-07-01

    Dicesium molybdate (Cs{sub 2}MoO{sub 4})'s thermal expansion and crystal structure have been investigated herein by high temperature X ray diffraction in conjunction with Raman spectroscopy. This first crystal-chemical insight at high temperature is aimed at predicting the thermostructural and thermomechanical behavior of this oxide formed by the accumulation of Cs and Mo fission products at the periphery of nuclear fuel rods in sodium-cooled fast reactors. Within the temperature range of the fuel's rim, Cs{sub 2}MoO{sub 4} becomes hexagonal P6{sub 3}/mmc, with disordered MoO{sub 4} tetrahedra and 2D distribution of CsO bonds that makes thermal axial expansion both large (50??{sub l}?70 10{sup ?6} C{sup ?1}, 500800 C) and highly anisotropic (?{sub c}??{sub a}=6710{sup ?6} C{sup ?1}, hexagonal form). The difference with the fuel's expansion coefficient is of potential concern with respect to the cohesion of the Cs{sub 2}MoO{sub 4} surface film and the possible release of cesium radionuclides in accidental situations. - Graphical abstract: The weakness of the CsO bonds and the disordering of the MoO{sub 4} tetrahedra array in the high-temperature form are responsible for the huge thermal expansion of Cs{sub 2}MoO{sub 4} along the c-axis. - Highlights: Thermomechanical behavior of Cs{sub 2}MoO{sub 4} fission products compound is studied. High-temperature form of Cs{sub 2}MoO{sub 4} is characterized by XRD and Raman. Thermal expansion appears very high and anisotropic. Cohesion between Cs{sub 2}MoO{sub 4} and nuclear fuel seems questionable, and Cs release is expected.

  16. Role of Si on the Diffusional Interactions between U-Mo and Al-Si Alloys at 823 K (550 degrees C)

    SciTech Connect (OSTI)

    E. Perez; Y.H. Sohn; D.D. Keiser, Jr.

    2013-01-01

    U-Mo dispersions in Al-alloy matrix and monolithic fuels encased in Al-alloy are under development to fulfill the requirements for research and test reactors to use low-enriched molybdenum stabilized uranium alloys fuels. Significant interaction takes place between the U-Mo fuel and Al during manufacturing and in-reactor irradiation. The interactions products are Al-rich phases with physical and thermal characteristics that adversely affect fuel performance and lead to premature failure. Detailed analysis of the interdiffusion and microstructural development of this system was carried through diffusion couples consisting of U-7wt.%Mo, U-10wt.%Mo and U-12wt.%Mo in contact with pure Al, Al-2wt.%Si, and Al-5wt.%Si, annealed at 823K for 1, 5 and 20 hours. Scanning electron microscopy (SEM) and transmission electron microscopy (TEM) were employed for the analysis. Diffusion couples consisting of U-Mo vs. pure Al contained UAl3, UAl4, U6Mo4Al43, and UMo2Al20 phases. The addition of Si to the Al significantly reduced the thickness of the interdiffusion zone. The interdiffusion zones developed Al and Si enriched regions, whose locations and size depended on the Si and Mo concentrations in the terminal alloys. In the couples, the (U,Mo)(Al,Si)3 phase was observed throughout interdiffusion zone, and the U6Mo4Al43 and UMo2Al20 phases were observed only where the Si concentrations were low.

  17. Mesoporous carbon-containing MoS{sub 2} materials formed from the in situ decomposition of tetraalkylammonium thiomolybdates

    SciTech Connect (OSTI)

    Alonso, Gabriel; Berhault, Gilles; Paraguay, Francisco; Rivera, Eric; Fuentes, Sergio; Chianelli, Russell R

    2003-05-26

    Molybdenum disulfide with unique mesoporous structure was synthesized from tetraalkylammonium thiometallate precursors in situ decomposed in a batch reactor in the presence of dibenzothiophene (DBT). The precursors used in this study were tetraalkylammonium thiomolybdates with alkyl groups ranging from propyl to octyl. Molybdenum disulfide thus prepared presents high surface area (from 255 up to 329 m{sup 2}/g), high content of carbon (C/Mo=2.7-4.0) and type IV nitrogen adsorption-desorption isotherms when decomposed from tetrahexyl-, tetraheptyl- or tetraoctylammonium thiomolybdates. The as-formed materials are poorly crystallized with a very weak intensity of the (0 0 2) peak of the 2H-MoS{sub 2} structure. Such diffraction patterns are characteristic of exfoliated samples. Characterization by TEM shows a disordered layered structure with no long range order for the MoS{sub 2} catalysts. Therefore, the nature of the alkyl group in the precursor affects both the surface area and the pore size distribution of the final MoS{sub 2} catalysts with a progressive morphological modification up to a mesoporous organization.

  18. Prediction of U-Mo dispersion nuclear fuels with Al-Si alloy using artificial neural network

    SciTech Connect (OSTI)

    Susmikanti, Mike; Sulistyo, Jos

    2014-09-30

    Dispersion nuclear fuels, consisting of U-Mo particles dispersed in an Al-Si matrix, are being developed as fuel for research reactors. The equilibrium relationship for a mixture component can be expressed in the phase diagram. It is important to analyze whether a mixture component is in equilibrium phase or another phase. The purpose of this research it is needed to built the model of the phase diagram, so the mixture component is in the stable or melting condition. Artificial neural network (ANN) is a modeling tool for processes involving multivariable non-linear relationships. The objective of the present work is to develop code based on artificial neural network models of system equilibrium relationship of U-Mo in Al-Si matrix. This model can be used for prediction of type of resulting mixture, and whether the point is on the equilibrium phase or in another phase region. The equilibrium model data for prediction and modeling generated from experimentally data. The artificial neural network with resilient backpropagation method was chosen to predict the dispersion of nuclear fuels U-Mo in Al-Si matrix. This developed code was built with some function in MATLAB. For simulations using ANN, the Levenberg-Marquardt method was also used for optimization. The artificial neural network is able to predict the equilibrium phase or in the phase region. The develop code based on artificial neural network models was built, for analyze equilibrium relationship of U-Mo in Al-Si matrix.

  19. Irradiation Performance of U-Mo Alloy Based ‘Monolithic’ Plate-Type Fuel – Design Selection

    SciTech Connect (OSTI)

    A. B. Robinson; G. S. Chang; D. D. Keiser, Jr.; D. M. Wachs; D. L. Porter

    2009-08-01

    A down-selection process has been applied to the U-Mo fuel alloy based monolithic plate fuel design, supported by irradiation testing of small fuel plates containing various design parameters. The irradiation testing provided data on fuel performance issues such as swelling, fuel-cladding interaction (interdiffusion), blister formation at elevated temperatures, and fuel/cladding bond quality and effectiveness. U-10Mo (wt%) was selected as the fuel alloy of choice, accepting a somewhat lower uranium density for the benefits of phase stability. U-7Mo could be used, with a barrier, where the trade-off for uranium density is critical to nuclear performance. A zirconium foil barrier between fuel and cladding was chosen to provide a predictable, well-bonded, fuel-cladding interface, allowing little or no fuel-cladding interaction. The fuel plate testing conducted to inform this selection was based on the use of U-10Mo foils fabricated by hot co-rolling with a Zr foil. The foils were subsequently bonded to Al-6061 cladding by hot isostatic pressing or friction stir bonding.

  20. Modification of polymer velvet cathode via metallic Mo coating for enhancement of high-current electron emission performances

    SciTech Connect (OSTI)

    Xiong, Ying; Wang, Bing; Yi, Yong; Xia, Liansheng; Zhang, Huang

    2013-09-15

    The effect of surface Mo coating on the high-current electron emission performances for polymer velvet cathode has been investigated in a diode with A-K gap of 11.5 cm by the combination of time-resolved electrical diagnostic and temporal pressure variation. Compared with uncoated polymer velvet cathode under the single-pulsed emission mode, the Mo-coated one shows lower outgassing levels (?0.40 Pa L), slower cathode plasma expansion velocity (?2.30 cm/?s), and higher emission stability as evidences by the change in cathode current, temporal pressure variation, and diode perveance. Moreover, after Mo coating, the emission consistency of the polymer velvet cathode between two adjacent pulses is significantly improved in double-pulsed emission mode with ?500 ns interval between two pulses, which further confirms the effectiveness of Mo coating for enhancement of electron emission performance of polymer velvet cathodes. These results should be of interest to the high-repetitive high-power microwave systems with cold cathodes.

  1. Concept Feasibility Report for Using Co-Extrusion to Bond Metals to Complex Shapes of U-10Mo

    SciTech Connect (OSTI)

    Lavender, Curt A.; Paxton, Dean M.; Smith, Mark T.; Soulami, Ayoub; Joshi, Vineet V.; Burkes, Douglas

    2013-12-30

    In support of the Convert Program of the U.S. Department of Energys National Nuclear Security Administration (DOE/NNSA) Global Threat Reduction Initiative (GTRI), Pacific Northwest National Laboratory (PNNL) has been investigating manufacturing processes for the uranium-10% molybdenum (U-10Mo) alloy plate fuel for the U.S. high-performance research reactors (USHPRR). This report documents the results of PNNLs efforts to develop the extrusion process for this concept. The approach to the development of a co-extruded complex-shaped fuel has been described and an extrusion of DU-10Mo was made. The initial findings suggest that given the extrusion forces required for processing U-10Mo, the co-extrusion process can meet the production demands of the USHPRR fuel and may be a viable production method. The development activity is in the early stages and has just begun to identify technical challenges to address details such as dimensional tolerances and shape control. New extrusion dies and roll groove profiles have been developed and will be assessed by extrusion and rolling of U-10Mo during the next fiscal year. Progress on the development and demonstration of the co-extrusion process for flat and shaped fuel is reported in this document

  2. Development and validation of capabilities to measure thermal properties of layered monolithic U-Mo alloy plate-type fuel

    SciTech Connect (OSTI)

    Burkes, Douglas; Casella, Andrew M.; Buck, Edgar C.; Casella, Amanda J.; Edwards, Matthew K.; MacFarlan, Paul J.; Pool, Karl N.; Smith, Frances N.; Steen, Franciska H.

    2014-07-19

    The uranium-molybdenum (U-Mo) alloy in a monolithic form has been proposed as one fuel design capable of converting some of the worlds highest power research reactors from the use of high enriched uranium (HEU) to low enriched uranium (LEU). One aspect of the fuel development and qualification process is to demonstrate appropriate understanding of thermal conductivity behavior of the fuel system as a function of temperature and expected irradiation conditions. The purpose of this paper is to verify and validate the functionality of equipment methods installed in hot cells for eventual measurements on irradiated uranium-molybdenum (U-Mo) monolithic fuel specimens, procedures to operate the equipment, and models to extract the desired thermal properties. The results presented here demonstrate the adequacy of the equipment, procedures and models that have been developed for this purpose based on measurements conducted on surrogate depleted uranium-molybdenum (DU-Mo) alloy samples containing a zirconium diffusion barrier and clad in aluminum alloy 6061 (AA6061). The results are in excellent agreement with thermal property data reported in the literature for similar U-Mo alloys as a function of temperature.

  3. The photocatalysis of Bi{sub 2}MoO{sub 6} under the irradiation of blue LED

    SciTech Connect (OSTI)

    Sun, Yuanyuan; Wang, Wenzhong Zhang, Ling; Sun, Songmei

    2013-10-15

    Graphical abstract: - Highlights: • ·OH trap and hole sink were involved to investigate the active radicals. • Holes play a more important role in the degradation of RhB. • The ·OH were related to the decomposition of phenol. • The ·O{sub 2}-played a leading role in the photodegradation of phenol. • Blue LED is competitive and promising alternative for the future application. - Abstract: Bi{sub 2}MoO{sub 6} has been reported as a promising photocatalyst in wastewater treatment. The active radicals generated over the Bi{sub 2}MoO{sub 6} during the photocatalytic process were thought to be hydroxyl radical (·OH) but have not been proved. Herein, Bi{sub 2}MoO{sub 6} with nanoplate like morphology was synthesized and its photocatalytic performances in the degradation of rhodamine B (RhB) and phenol as colored and colorless model pollutants respectively were evaluated under the irradiation of blue light emitting diode (LED). The tert-butyl alcohol (TBA) as a ·OH trap and ethylene diamine tetraacetic acid (EDTA) as a hole sink were involved to investigate the main active groups that are generated on Bi{sub 2}MoO{sub 6} and function during the photodegradation of RhB and phenol. In addition, it is a competitive and promising alternative plan to use blue LED as light source for the future practical application in environmental remediation.

  4. Four-point Bend Testing of Irradiated Monolithic U-10Mo Fuel

    SciTech Connect (OSTI)

    Rabin, B. H.; Lloyd, W. R.; Schulthess, J. L.; Wright, J. K.; Lind, R. P.; Scott, L.; Wachs, K. M.

    2015-03-01

    This paper presents results of recently completed studies aimed at characterizing the mechanical properties of irradiated U-10Mo fuel in support of monolithic base fuel qualification. Mechanical properties were evaluated in four-point bending. Specimens were taken from fuel plates irradiated in the RERTR-12 and AFIP-6 Mk. II irradiation campaigns, and tests were conducted in the Hot Fuel Examination Facility (HFEF) at Idaho National Laboratory (INL). The monolithic fuel plates consist of a U-10Mo fuel meat covered with a Zr diffusion barrier layer fabricated by co-rolling, clad in 6061 Al using a hot isostatic press (HIP) bonding process. Specimens exhibited nominal (fresh) fuel meat thickness ranging from 0.25 mm to 0.64 mm, and fuel plate average burnup ranged from approximately 0.4 x 1021 fissions/cm3 to 6.0 x 1021 fissions/cm3. After sectioning the fuel plates, the 6061 Al cladding was removed by dissolution in concentrated NaOH. Pre- and post-dissolution dimensional inspections were conducted on test specimens to facilitate accurate analysis of bend test results. Four-point bend testing was conducted on the HFEF Remote Load Frame at a crosshead speed of 0.1 mm/min using custom-designed test fixtures and calibrated load cells. All specimens exhibited substantially linear elastic behavior and failed in a brittle manner. The influence of burnup on the observed slope of the stress-strain curve and the calculated fracture strength is discussed.

  5. Microstructural characterization of as-cast biocompatible Co-Cr-Mo alloys

    SciTech Connect (OSTI)

    Giacchi, J.V.; Morando, C.N.; Fornaro, O.; Palacio, H.A.

    2011-01-15

    The microstructure of a cobalt-base alloy (Co-Cr-Mo) obtained by the investment casting process was studied. This alloy complies with the ASTM F75 standard and is widely used in the manufacturing of orthopedic implants because of its high strength, good corrosion resistance and excellent biocompatibility properties. This work focuses on the resulting microstructures arising from samples poured under industrial environment conditions, of three different Co-Cr-Mo alloys. For this purpose, we used: 1) an alloy built up from commercial purity constituents, 2) a remelted alloy and 3) a certified alloy for comparison. The characterization of the samples was achieved by using optical microscopy (OM) with a colorant etchant to identify the present phases and scanning electron microscopy (SE-SEM) and energy dispersion spectrometry (EDS) techniques for a better identification. In general the as-cast microstructure is a Co-fcc dendritic matrix with the presence of a secondary phase, such as the M{sub 23}C{sub 6} carbides precipitated at grain boundaries and interdendritic zones. These precipitates are the main strengthening mechanism in this type of alloys. Other minority phases were also reported and their presence could be linked to the cooling rate and the manufacturing process variables and environment. - Research Highlights: {yields}The solidification microstructure of an ASTM-F75 type alloy were studied. {yields}The alloys were poured under an industrial environment. {yields}Carbides and sigma phase identified by color metallography and scanning microscopy (SEM and EDS). {yields}Two carbide morphologies were detected 'blocky type' and 'pearlite type'. {yields}Minority phases were also detected.

  6. Development of an energy-use estimation methodology for the revised Navy Manual MO-303

    SciTech Connect (OSTI)

    Richman, E.E.; Keller, J.M.; Wood, A.G.; Dittmer, A.L.

    1995-01-01

    The U.S. Navy commissioned Pacific Northwest Laboratory (PNL) to revise and/or update the Navy Utilities Targets Manual, NAVFAC MO-303 (U.S. Navy 1972b). The purpose of the project was to produce a current, applicable, and easy-to-use version of the manual for use by energy and facility engineers and staff at all Navy Public Works Centers (PWCs), Public Works Departments (PWDs), Engineering Field Divisions (EFDs), and other related organizations. The revision of the MO-303 manual involved developing a methodology for estimating energy consumption in buildings and ships. This methodology can account for, and equitably allocate, energy consumption within Navy installations. The analyses used to develop this methodology included developing end-use intensities (EUIs) from a vast collection of Navy base metering and billing data. A statistical analysis of the metering data, weather data, and building energy-use characteristics was used to develop appropriate EUI values for use at all Navy bases. A complete Navy base energy reconciliation process was also created for use in allocating all known energy consumption. Initial attempts to use total Navy base consumption values did not produce usable results. A parallel effort using individual building consumption data provided an estimating method that incorporated weather effects. This method produced a set of building EUI values and weather adjustments for use in estimating building energy use. A method of reconciling total site energy consumption was developed based on a {open_quotes}zero-sum{close_quotes} principle. This method provides a way to account for all energy use and apportion part or all of it to buildings and other energy uses when actual consumption is not known. The entire text of the manual was also revised to present a more easily read understood and usable document.

  7. Method for generating a crystalline {sup 99}MoO{sub 3} product and the isolation {sup 99m}Tc compositions therefrom

    DOE Patents [OSTI]

    Bennett, R.G.; Christian, J.D.; Kirkham, R.J.; Tranter, T.J.

    1998-09-01

    An improved method is described for producing {sup 99m}Tc compositions. {sup 100}Mo metal is irradiated with photons in a particle (electron) accelerator to produce {sup 99}Mo metal which is dissolved in a solvent. A solvated {sup 99}Mo product is then dried to generate a supply of {sup 99}MoO{sub 3} crystals. The crystals are thereafter heated at a temperature which will sublimate the crystals and form a gaseous mixture containing vaporized {sup 99m}TcO{sub 3} and vaporized {sup 99m}TcO{sub 2} but will not cause the production of vaporized {sup 99}MoO{sub 3}. The mixture is then combined with an oxidizing gas to generate a gaseous stream containing vaporized {sup 99m}Tc{sub 2}O{sub 7}. Next, the gaseous stream is cooled to a temperature sufficient to convert the vaporized {sup 99m}Tc{sub 2}O{sub 7} into a condensed {sup 99m}Tc-containing product. The product has high purity levels resulting from the use of reduced temperature conditions and ultrafine crystalline {sup 99}MoO{sub 3} starting materials with segregated {sup 99m}Tc compositions therein which avoid the production of vaporized {sup 99}MoO{sub 3} contaminants. 1 fig.

  8. Method for generating a crystalline .sup.99 MoO.sub.3 product and the isolation .sup.99m Tc compositions therefrom

    DOE Patents [OSTI]

    Bennett, Ralph G.; Christian, Jerry D.; Kirkham, Robert J.; Tranter, Troy J.

    1998-01-01

    An improved method for producing .sup.99m Tc compositions. .sup.100 Mo metal is irradiated with photons in a particle (electron) accelerator to produce .sup.99 Mo metal which is dissolved in a solvent. A solvated .sup.99 Mo product is then dried to generate a supply of .sup.99 MoO.sub.3 crystals. The crystals are thereafter heated at a temperature which will sublimate the crystals and form a gaseous mixture containing vaporized .sup.99m TcO.sub.3 and vaporized .sup.99m TcO.sub.2 but will not cause the production of vaporized .sup.99 MoO.sub.3. The mixture is then combined with an oxidizing gas to generate a gaseous stream containing vaporized .sup.99m Tc.sub.2 O.sub.7. Next, the gaseous stream is cooled to a temperature sufficient to convert the vaporized .sup.99m Tc.sub.2 O.sub.7 into a condensed .sup.99m Tc-containing product. The product has high purity levels resulting from the use of reduced temperature conditions and ultrafine crystalline .sup.99 MoO.sub.3 starting materials with segregated .sup.99m Tc compositions therein which avoid the production of vaporized .sup.99 MoO.sub.3 contaminants.

  9. Synthesis and mechanical properties of CrMoC{sub x}N{sub 1-x} coatings deposited by a hybrid coating system

    SciTech Connect (OSTI)

    Yun, Ji Hwan; Heo, Su Jeong; Kim, Kwang Ryul; Kim, Kwang Ho

    2008-01-15

    Quaternary CrMoC{sub x}N{sub 1-x} coatings were deposited on steel substrates (AISI D2) and Si wafers by a hybrid coating system combining an arc-ion plating technique and a dc reactive magnetron sputtering technique using Cr and Mo targets in an Ar/N{sub 2}/CH{sub 4} gaseous mixture. The carbon content of CrMoC{sub x}N{sub 1-x} coatings was linearly increased with increasing CH{sub 4}/(CH{sub 4}+N{sub 2}) gas flow rate ratio. The maximum hardness of 44 GPa was obtained from the CrMoC{sub x}N{sub 1-x} coatings containing a carbon content of x=0.33 with a residual stress of -4.4 GPa. The average friction coefficient of Cr-Mo-N coatings was 0.42, and it is decreased to 0.31 after applying CrMoC{sub x}N{sub 1-x} coatings. This result was caused by the formation of a carbon-rich transfer layer that acted as a solid lubricant to reduce contact between the coating surface and steel ball. The microstructure of the coatings was investigated by x-ray diffraction, scanning electron microscopy, and x-ray photoelectron spectroscopy. In this work, the microstructure and mechanical properties of the CrMoC{sub x}N{sub 1-x} coatings were systematically investigated with the instrumental analyses.

  10. State Energy Program awards $5 million to states for State Energy...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    State Energy Program awards 5 million to states for State Energy Planning and Innovative Energy Practices State Energy Program awards 5 million to states for State Energy...

  11. Facile deposition of Ag{sub 3}PO{sub 4} on graphene-like MoS{sub 2} nanosheets for highly efficient photocatalysis

    SciTech Connect (OSTI)

    Wang, Peifu; Shi, Penghui; Hong, Yuanchen; Zhou, Xuejun; Yao, Weifeng

    2015-02-15

    Graphical abstract: The photocatalytic performance of Ag{sub 3}PO{sub 4} was highly improved by the in situ deposition of Ag{sub 3}PO{sub 4} particles on graphene-like MoS{sub 2} nanosheets. - Highlights: A novel composite photocatalyst was synthesized by depositing Ag{sub 3}PO{sub 4} on the graphene-like MoS{sub 2} nanosheets. Ag{sub 3}PO{sub 4}/MoS{sub 2} photocatalyst exhibited a high photocatalytic activity for RhB degradation. Graphene-like MoS{sub 2} nanosheets. MoS{sub 2} nanosheets play an important role in photocatalytic activity by serving as an effective acceptor of the photogenerated carriers. - Abstract: A facile method for the in situ deposition of Ag{sub 3}PO{sub 4} on graphene-like MoS{sub 2} nanosheets was developed to improve the photocatalytic performance of Ag{sub 3}PO{sub 4} catalysts. The heterostructure of Ag{sub 3}PO{sub 4}/MoS{sub 2} composites was characterized by using X-ray diffraction spectra (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and X-ray photoelectron spectroscopy (XPS). The prepared Ag{sub 3}PO{sub 4}/MoS{sub 2} photocatalyst exhibited a much higher photocatalytic activity than that of Ag{sub 3}PO{sub 4} for the degradation of Rhodamine B (RhB) under visible light irradiation (>400 nm). The improved photocatalytic activity of Ag{sub 3}PO{sub 4}/MoS{sub 2} is attributed to the efficient separation of photogenerated electronhole pairs in the composite. This result provides a new perspective on the design of high-performance photocatalysts which is promising for energy applications.

  12. Long-lived nanosecond spin relaxation and spin coherence of electrons in monolayer MoS2 and WS2

    SciTech Connect (OSTI)

    Yang, Luyi; Sinitsyn, Nikolai A.; Chen, Weibing; Yuan, Jiangtan; Zhang, Jing; Lou, Jun; Crooker, Scott  A.

    2015-08-03

    The recently discovered monolayer transition metal dichalcogenides (TMDCs) provide a fertile playground to explore new coupled spin–valley physics. Although robust spin and valley degrees of freedom are inferred from polarized photoluminescence (PL) experiments PL timescales are necessarily constrained by short-lived (3–100 ps) electron–hole recombination9, 10. Direct probes of spin/valley polarization dynamics of resident carriers in electron (or hole)-doped TMDCs, which may persist long after recombination ceases, are at an early stage. Here we directly measure the coupled spin–valley dynamics in electron-doped MoS2 and WS2 monolayers using optical Kerr spectroscopy, and reveal very long electron spin lifetimes, exceeding 3 ns at 5 K (2-3 orders of magnitude longer than typical exciton recombination times). In contrast with conventional III–V or II–VI semiconductors, spin relaxation accelerates rapidly in small transverse magnetic fields. Supported by a model of coupled spin–valley dynamics, these results indicate a novel mechanism of itinerant electron spin dephasing in the rapidly fluctuating internal spin–orbit field in TMDCs, driven by fast inter-valley scattering. Additionally, a long-lived spin coherence is observed at lower energies, commensurate with localized states. These studies provide insight into the physics underpinning spin and valley dynamics of resident electrons in atomically thin TMDCs.

  13. Electron-phonon coupling and thermal transport in the thermoelectric compound Mo3Sb7–xTex

    SciTech Connect (OSTI)

    Bansal, Dipanshu; Li, Chen W.; Said, Ayman H.; Abernathy, Douglas L.; Yan, Jiaqiang; Delaire, Olivier A.

    2015-12-07

    Phonon properties of Mo3Sb7–xTex (x = 0, 1.5, 1.7), a potential high-temperature thermoelectric material, have been studied with inelastic neutron and x-ray scattering, and with first-principles simulations. The substitution of Te for Sb leads to pronounced changes in the electronic struc- ture, local bonding, phonon density of states (DOS), dispersions, and phonon lifetimes. Alloying with tellurium shifts the Fermi level upward, near the top of the valence band, resulting in a strong suppression of electron-phonon screening, and a large overall stiffening of interatomic force- constants. The suppression in electron-phonon coupling concomitantly increases group velocities and suppresses phonon scattering rates, surpassing the effects of alloy-disorder scattering, and re- sulting in a surprising increased lattice thermal conductivity in the alloy. We also identify that the local bonding environment changes non-uniformly around different atoms, leading to variable perturbation strengths for different optical phonon branches. The respective roles of changes in phonon group velocities and phonon lifetimes on the lattice thermal conductivity are quantified. Lastly, our results highlight the importance of the electron-phonon coupling on phonon mean-free-paths in this compound, and also estimates the contributions from boundary scattering, umklapp scattering, and point-defect scattering.

  14. Long-lived nanosecond spin relaxation and spin coherence of electrons in monolayer MoS2 and WS2

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yang, Luyi; Sinitsyn, Nikolai A.; Chen, Weibing; Yuan, Jiangtan; Zhang, Jing; Lou, Jun; Crooker, Scott  A.

    2015-08-03

    The recently discovered monolayer transition metal dichalcogenides (TMDCs) provide a fertile playground to explore new coupled spin–valley physics. Although robust spin and valley degrees of freedom are inferred from polarized photoluminescence (PL) experiments PL timescales are necessarily constrained by short-lived (3–100 ps) electron–hole recombination9, 10. Direct probes of spin/valley polarization dynamics of resident carriers in electron (or hole)-doped TMDCs, which may persist long after recombination ceases, are at an early stage. Here we directly measure the coupled spin–valley dynamics in electron-doped MoS2 and WS2 monolayers using optical Kerr spectroscopy, and reveal very long electron spin lifetimes, exceeding 3 ns atmore » 5 K (2-3 orders of magnitude longer than typical exciton recombination times). In contrast with conventional III–V or II–VI semiconductors, spin relaxation accelerates rapidly in small transverse magnetic fields. Supported by a model of coupled spin–valley dynamics, these results indicate a novel mechanism of itinerant electron spin dephasing in the rapidly fluctuating internal spin–orbit field in TMDCs, driven by fast inter-valley scattering. Additionally, a long-lived spin coherence is observed at lower energies, commensurate with localized states. These studies provide insight into the physics underpinning spin and valley dynamics of resident electrons in atomically thin TMDCs.« less

  15. Topological degeneracy of non-Abelian states for dummies

    SciTech Connect (OSTI)

    Oshikawa, Masaki . E-mail: oshikawa@issp.u-tokyo.ac.jp; Kim, Yong Baek; Shtengel, Kirill; Nayak, Chetan; Tewari, Sumanta

    2007-06-15

    We present a physical construction of degenerate groundstates of the Moore-Read Pfaffian states, which exhibits non-Abelian statistics, on general Riemann surface with genus g. The construction is given by a generalization of the recent argument [M.O., T. Senthil, Phys. Rev. Lett. 96 (2006) 060601] which relates fractionalization and topological order. The nontrivial groundstate degeneracy obtained by Read and Green [Phys. Rev. B 61 (2000) 10267] based on differential geometry is reproduced exactly. Some restrictions on the statistics, due to the fractional charge of the quasiparticle are also discussed. Furthermore, the groundstate degeneracy of the p + ip superconductor in two dimensions, which is closely related to the Pfaffian states, is discussed with a similar construction.

  16. Results of U-xMo (x=7, 10, 12 wt.%) Alloy versus Al-6061 Cladding Diffusion Couple Experiments Performed at 500, 550 and 600 Degrees C

    SciTech Connect (OSTI)

    Emmanuel Perez; Dennis D. Keiser, Jr.; Yongho Sohn

    2013-04-01

    The Reduced Enrichment for Research and Test Reactors (RERTR) program has been developing low enrichment fuel systems encased in Al 6061 for use in research and test reactors. U–Mo alloys in contact with Al and Al alloys can undergo diffusional interactions that can result in the development of interdiffusion zones with complex fine-grained microstructures composed of multiple phases. A monolithic fuel currently being developed by the RERTR program has local regions where the U–Mo fuel plate is in contact with the Al 6061 cladding and, as a result, the program finds information about interdiffusion zone development at high temperatures of interest. In this study, the microstructural development of diffusion couples consisting of U-7wt.%Mo, U-10wt.%Mo, and U-12wt.%Mo vs. Al 6061 (or 6061 aluminum) cladding, annealed at 500, 550, 600 degrees C for 1, 5, 20, 24, or 132 hours, was analyzed by backscatter electron microscopy and x-ray energy dispersive spectroscopy on a scanning electron microscope. Concentration profiles were determined by standardized wavelength dispersive spectroscopy and standardless x-ray energy dispersive spectroscopy. The results of this work shows that the presence of surface layers at the U–Mo/Al 6061 interface can dramatically impact the overall interdiffusion behavior in terms of rate of interaction and uniformity of the developed interdiffusion zones. It further reveals that relatively uniform interaction layers with higher Si concentrations can develop in U–Mo/Al 6061 couples annealed at shorter times and that longer times at temperature result in the development of more non-uniform interaction layers with more areas that are enriched in Al. At longer annealing times and relatively high temperatures, U–Mo/Al 6061 couples can exhibit more interaction compared to U–Mo/pure Al couples. The minor alloying constituents in Al 6061 cladding can result in the development of many complex phases in the interaction layer of U–Mo/Al–6061 cladding couples, and some phases in the interdiffusion zones of U–Mo/Al–6061 cladding couples are likely similar to those observed for U–Mo/pure Al couples.

  17. Cobalt-doped Bi{sub 26}Mo{sub 10}O{sub 69}: Crystal structure and conductivity

    SciTech Connect (OSTI)

    Mikhailovskaya, Z.A.; Buyanova, E.S.; Petrova, S.A.; Morozova, M.V.; Zhukovskiy, V.M.; Zakharov, R.G.; Tarakina, N.V.; Berger, I.F.

    2013-08-15

    A series of cobalt-doped bismuth molybdates were synthesized and investigated using X-ray powder diffraction, transmission electron microscopy and impedance spectroscopy. The ranges of solid solution were determined. Two new compounds, Bi{sub 1?x}Co{sub x}[Bi{sub 12}O{sub 14}]Mo{sub 5}O{sub 34.5?} (x=0.2) and Bi[Bi{sub 12}O{sub 14}]Mo{sub 5?y}Co{sub y}O{sub 34.5?} (y=0.2), which crystallise in monoclinic unit cells have been examined in detail by diffraction methods. Impedance spectroscopy measurements show that the studied materials are good ionic conductors with conductivity values about 510{sup ?3} Scm{sup ?1} at 973 K and 1.710{sup ?4} Scm{sup ?1} at 623 K, which are similar to conductivity values of yttrium substituted zirconia and (YSZ) gadolinium doped ceria (CGO). - Graphical abstract: Measured and calculated diffraction spectra for Bi{sub 12.8}Co{sub 0.2}Mo{sub 5}O{sub 34?} and projection of the Bi{sub 12.8}Co{sub 0.2}Mo{sub 5}O{sub 34?} crystal structure onto the ac plane. Highlights: The limit of the Bi{sub 1?x}Co{sub x}[Bi{sub 12}O{sub 14}]Mo{sub 5}O{sub 34.5?} homogeneity range is equal to x=0.2. The limit of the Bi[Bi{sub 12}O{sub 14}]Mo{sub 5?y}Co{sub y}O{sub 34.5?} homogeneity range is equal to y=0.2. Solid solutions have monoclinic symmetry. No phase transition is observed. The conductivity at 700 for y=0.2 solid solutions is equal to ?lg ?, Scm{sup ?1}=2.23. The conductivity at 350 for y=0.2 solid solutions is equal to ?lg ?, Scm{sup ?1}=3.74.

  18. Update to M&O Contractor Model Subcontract entitled "Standard Research Subcontract (Educational Institution or Nonprofit Organization)"

    Broader source: Energy.gov [DOE]

    The purpose of this Policy Flash is to disseminate an update to the Management and Operating (M&O) Contractor Standard Research Subcontract (Educational Institution or Nonprofit Organization) Model. The original Model was championed by the Integrated Contractor Purchasing Team and included representatives from other federally funded research facilities and DOE/NNSA. The attached update represents a similar stakeholder's collaboration. DOE/NNSA encourages M&O contractors to use this model subcontractor for unclassified research and development work not related to nuclear, chemical, biological, or radiological weapons of mass destruction or the production of special nuclear material. If the proposed subcontract is for other than standard research and development work (e.g., work performed on a DOE/NNSA site, a programmatic requirement for open source software distribution, etc.), the articles and clauses in the model should be tailored to address those specific requirements.

  19. Mass Measurements of Very Neutron-Deficient Mo and Tc Isotopes and Their Impact on rp Process Nucleosynthesis

    SciTech Connect (OSTI)

    Haettner, E.; Plass, W. R.; Scheidenberger, C.; Ackermann, D.; Block, M.; Eliseev, S.; Herfurth, F.; Hessberger, F. P.; Hofmann, S.; Kluge, H.-J.; Audi, G.; Blaum, K.; Ketter, J.; Fleckenstein, T.; Ketelaer, J.; Marx, G.; Schweikhard, L.; Mazzocco, M.; Novikov, Yu. N.; Vorobjev, G.

    2011-03-25

    The masses of ten proton-rich nuclides, including the N=Z+1 nuclides {sup 85}Mo and {sup 87}Tc, were measured with the Penning trap mass spectrometer SHIPTRAP. Compared to the Atomic Mass Evaluation 2003 a systematic shift of the mass surface by up to 1.6 MeV is observed causing significant abundance changes of the ashes of astrophysical x-ray bursts. Surprisingly low {alpha} separation energies for neutron-deficient Mo and Tc are found, making the formation of a ZrNb cycle in the rp process possible. Such a cycle would impose an upper temperature limit for the synthesis of elements beyond Nb in the rp process.

  20. Calculation of Design Parameters for an Equilibrium LEU Core in the NBSR using a U7Mo Dispersion Fuel

    SciTech Connect (OSTI)

    Hanson A. L.; Diamond D.

    2014-06-30

    A plan is being developed for the conversion of the NIST research reactor (NBSR) from high-enriched uranium (HEU) fuel to low-enriched uranium (LEU) fuel. The LEU fuel may be a monolithic foil (LEUm) of U10Mo (10% molybdenum by weight in an alloy with uranium) or a dispersion of U7Mo in aluminum (LEUd). A previous report provided neutronic calculations for the LEUm fuel and this report presents the neutronics parameters for the LEUd fuel. The neutronics parameters for the LEUd fuel are compared to those previously obtained for the present HEU fuel and the proposed LEUm fuel. The results show no significant differences between the LEUm and the LEUd other than the LEUd fuel requires slightly less uranium than the LEUm fuel due to less molybdenum being present. The calculations include kinetics parameters, reactivity coefficients, reactivity worths of control elements and abnormal configurations, and power distributions under normal operation and with misloaded fuel elements.

  1. SEM in situ MiniCantilever Beam Bending of U-10Mo/Zr/Al Fuel Elements

    SciTech Connect (OSTI)

    Mook, William; Baldwin, Jon K.; Martinez, Ricardo M.; Mara, Nathan A.

    2014-06-16

    In this work, the fracture behavior of Al/Zr and Zr/dU-10Mo interfaces was measured via the minicantilever bend technique. The energy dissipation rates were found to be approximately 3.7-5 mj/mm2 and 5.9 mj/mm2 for each interface, respectively. It was found that in order to test the Zr/U-10Mo interface, location of the hinge of the cantilever was a key parameter. While this test could be adapted to hot cell use through careful alignment fixturing and measurement of crack lengths with an optical microscope (as opposed to SEM, which was used here out of convenience), machining of the cantilevers via MiniMill in such a way as to locate the interfaces at the cantilever hinge, as well as proper placement of a femtosecond laser notch will continue to be key challenges in a hot cell environment.

  2. Coupled spin and valley physics in monolayer MoS2 and group-VI dichalcogenides

    SciTech Connect (OSTI)

    Xiao, Di; Liu, G. B.; Feng, wanxiang; Xu, Xiaodong; Yao, Wang

    2012-01-01

    We show that inversion symmetry breaking together with spin-orbit coupling leads to coupled spin and valley physics in monolayer MoS2 and group-VI dichalcogenides, making possible controls of spin and valley in these 2D materials. The spin-valley coupling at the valence band edges suppresses spin and valley relaxation, as flip of each index alone is forbidden by the 0.1 eV valley contrasting spin splitting. Valley Hall and spin Hall effects coexist in both electron-doped and hole-doped systems. Optical interband transitions have frequency-dependent polarization selection rules which allow selective photoexcitation of carriers with various combination of valley and spin indices. Photo-induced spin Hall and valley Hall effects can generate long lived spin and valley accumulations on sample boundaries. The physics discussed here provides a route towards the integration of valleytronics and spintronics in multi-valley materials with strong spin-orbit coupling and inversion symmetry breaking.

  3. Wettability of brazing alloys on molybdenum and TZM (Mo-Ti-Zr alloy)

    SciTech Connect (OSTI)

    McDonald, M.M.; Keller, D.L.; Heiple, C.R.; Hofmann, W.E.

    1988-01-01

    Vacuum brazing studies have been performed on molybdenum and TZM (0.5Ti-0.08Zr-Mo). Wettability tests have been conducted for nineteen braze metal filler alloys on molybdenum and thirty-two braze metal filler alloys on TZM over a wide range of temperatures. A wetting index, which is a function of contact angle and braze alloy contact area, was determined for each filler alloy at each brazing temperature. The nature and extent of interaction between the brazing alloys and the base metals was analyzed by conventional metallography, scanning-electron microscopy, and electron microprobe analysis. A comparison is made between the behavior of filler alloys on molybdenum and TZM -- filler alloys consistently exhibited less wettability on TZM than on molybdenum. The lower wettability of TZM is believed to be due to a small amount of titanium in the surface oxide on TZM. Cracking was observed in the base metal under some of the high temperature braze deposits. The cracking is shown to arise from liquid metal embrittlement from nickel in the high temperature braze alloys. 7 refs., 11 figs., 2 tabs.

  4. Separation of interlayer resistance in multilayer MoS{sub 2} field-effect transistors

    SciTech Connect (OSTI)

    Na, Junhong; Jeong Kim, Yun; Kim, Gyu-Tae; Shin, Minju; Joo, Min-Kyu; Huh, Junghwan; Jong Choi, Hyung; Hyung Shim, Joon

    2014-06-09

    We extracted the interlayer resistance between two layers in multilayer molybdenum disulfide (MoS{sub 2}) field-effect transistors by confirming that contact resistances (R{sub contact}) measured using the four-probe measurements were similar, within ∼30%, to source/drain series resistances (R{sub sd}) measured using the two-probe measurements. R{sub contact} values obtained from gated four-probe measurements exhibited gate voltage dependency. In the two-probe measurements, the Y-function method was applied to obtain the R{sub sd} values. By comparing those two R{sub contact} (∼9.5 kΩ) and R{sub sd} (∼12.3 kΩ) values in strong accumulation regime, we found the rationality that those two values had nearly the same properties, i.e., the Schottky barrier resistances and interlayer resistances. The R{sub sd} values of devices with two-probe source/drain electrodes exhibited thickness dependency due to interlayer resistance changes. The interlayer resistance between two layers was also obtained as ∼2.0 Ω mm.

  5. Measurement of fission gas release from irradiated UMo monolithic fuel samples

    SciTech Connect (OSTI)

    Burkes, Douglas E.; Casella, Amanda J.; Casella, Andrew M.; Luscher, Walter G.; Rice, Francine J.; Pool, Karl N.

    2015-06-01

    The uraniummolybdenum (U-Mo) alloy in a monolithic form has been proposed as one fuel design capable of converting some of the worlds highest power research reactors from the use of high enriched uranium (HEU) to low enriched uranium (LEU). One aspect of the fuel development and qualification process is to demonstrate appropriate understanding of the extent of fission product release from the fuel under anticipated service environments. An apparatus capable of heating post-irradiated small-scale samples cut from larger fuel segments according to specified thermal profiles under a controlled atmosphere has been installed into a hot cell. Results show that optimized experimental parameters to investigate fission product release from small samples have been established. Initial measurements conducted on aluminum alloy clad uraniummolybdenum monolithic fuel samples reveal three clear fission gas release events over the temperature range of 30-1000 C. The mechanisms responsible for these events are discussed, and the results have been compared with available information in the literature.

  6. Modeling the Influence of Interaction Layer Formation on Thermal Conductivity of UMo Dispersion Fuel

    SciTech Connect (OSTI)

    Burkes, Douglas; Casella, Andrew M.; Huber, Tanja K.

    2015-01-01

    The Global Threat Reduction Initiative Program continues to develop existing and new plate- and rod-type research and test reactor fuels with maximum attainable uranium loadings capable of potentially converting a number of the worlds remaining high-enriched uranium fueled reactors to low-enriched uranium fuel. Currently, the program is focused on assisting with the development and qualification of an even higher density fuel type consisting of a uranium-molybdenum (U-Mo) alloy dispersed in an aluminum matrix. Thermal conductivity is an important consideration in determining the operational temperature of the fuel plate and can be influenced by interaction layer formation between the fuel and matrix, porosity that forms during fabrication of the fuel plates, and upon the concentration of the dispersed phase within the matrix. This paper develops and validates a simple model to study the influence of interaction layer formation and conductivity, fuel particle size, and volume fraction of fuel dispersed in the matrix on the effective conductivity of the composite. The model shows excellent agreement with results previously presented in the literature. In particular, the thermal conductivity of the interaction layer does not appear to be important in determining the overall conductivity of the composite, while formation of the interaction layer and subsequent consumption of the matrix reveals a rather significant effect. The effective thermal conductivity of the composite can be influenced by the fuel particle distribution by minimizing interaction layer formation and preserving the higher thermal conductivity matrix.

  7. Measurement of Fission Gas Release from Irradiated U-Mo Monolithic Fuel Samples

    SciTech Connect (OSTI)

    Burkes, Douglas; Casella, Amanda J.; Casella, Andrew M.; Luscher, Walter G.; Rice, Francine; Pool, Karl N.

    2015-06-01

    The uranium-molybdenum (U-Mo) alloy in a monolithic form has been proposed as one fuel design capable of converting some of the world’s highest power research reactors from the use of high enriched uranium (HEU) to low enriched uranium (LEU). One aspect of the fuel development and qualification process is to demonstrate appropriate understanding of the extent of fission product release from the fuel under anticipated service environments. An apparatus capable of annealing post-irradiated small-scale samples cut from larger fuel segments according to specified thermal profiles under a controlled atmosphere has been installed into a hot cell. Results show that optimized experimental parameters to investigate fission product release from small samples have been established. Initial measurements conducted on aluminum alloy clad uranium-molybdenum monolithic fuel samples reveal three clear fission gas release events over the temperature range of 30-1050 C. The mechanisms responsible for these events are discussed, and the results have been compared with available information in literature.

  8. Effects of the foil flatness on irradiation performance of U10Mo monolithic mini-plates

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ozaltun, Hakan; Medvedev, Pavel G.; Rabin, Barry H.

    2015-09-03

    Monolithic plate-type fuels comprise of a high density, low enrichment, U10Mo fuel foil encapsulated in a cladding material. This concept generates several fabrication challenges such as flatness, centering or thickness variation. There are concerns, if these parameters have implications on overall performance. To investigate these inquiries, the effects of the foil flatness were studied. For this, a representative plate was simulated for an ideal case. The simulations were repeated for additional cases with various foil curvatures to evaluate the effects on the irradiation performance. The results revealed that the stresses and strains induced by fabrication process are not affected bymore » the flatness of the foil. Furthermore, fabrication stresses in the foil are relieved relatively fast in the reactor. The effects of the foil flatness on peak irradiation stressstrains are minimal. There is a slight increase in temperature for the case with maximum curvature. The major impact is on the displacement characteristics. Furthermore, while the case with a flat foil produces a symmetrical swelling, if the foil is curved, more swelling occurs on the thin-cladding side and the plate bows during irradiation.« less

  9. Cs-doped Mo as surface converter for H{sup −}/D{sup −} generation in negative ion sources: First steps and proof of principle

    SciTech Connect (OSTI)

    Schiesko, L. Hopf, C.; Höschen, T.; Meisl, G.; Encke, O.; Franzen, P.; Heinemann, B.; Hopf, C.; Fantz, U.; Cartry, G.; Achkasov, K.

    2015-04-08

    In a proof-of-principle study, molybdenum samples were implanted with a very small dose of Cs in order to test the properties of the compound as a surface converter for negative hydrogen ion production. First results on the properties of Cs doped Mo compounds show a reduction of the work function and a stable H{sup −} yield up to four hours in low density hydrogen plasma. The implanted Cs atoms were stable in the Mo lattice over one year for samples stored in vacuum and not exposed to the plasma. The surface H{sup −} generation mechanisms were identified and a comparison of the negative ion yield with pure Mo showed that the Cs doped Mo sample’s yield was much larger.

  10. The Influence of Casting Conditions on the Microstructure of As-Cast U-10Mo Alloys: Characterization of the Casting Process Baseline

    SciTech Connect (OSTI)

    Nyberg, Eric A.; Joshi, Vineet V.; Lavender, Curt A.; Paxton, Dean M.; Burkes, Douglas

    2013-12-13

    Sections of eight plate castings of uranium alloyed with 10 wt% molybdenum (U-10Mo) were sent from Y-12 to the Pacific Northwest National Laboratory (PNNL) for microstructural characterization. This report summarizes the results from this study.

  11. Optimal electron irradiation as a tool for functionalization of MoS{sub 2}: Theoretical and experimental investigation

    SciTech Connect (OSTI)

    Karmakar, Debjani Padma, N.; Ghosh, M.; Kaur, M.; Chandrasekhar Rao, T. V.; Halder, Rumu; Abraham, Geogy; Vaibhav, K.; Bhattacharya, D.

    2015-04-07

    We demonstrate the utility of electron irradiation as a tool to enhance device functionality of graphene-analogous MoS{sub 2}. With the help of first-principles based calculations, vacancy-induced changes of various electronic properties are shown to be a combined result of crystal-field modification and spin-orbital coupling. A comparative theoretical study of various possible vacancy configurations both in bulk and monolayer MoS{sub 2} and related changes in their respective band-structures help us to explain plausible irradiation induced effects. Experimentally, various structural forms of MoS{sub 2} in bulk, few layered flakes, and nanocrystals are observed to exhibit important modification of their magnetic, transport, and vibrational properties, following low doses of electron irradiation. While irradiated single crystals and nanocrystals show an enhanced magnetization, transport properties of few-layered devices show a significant increase in their conductivity, which can be very useful for fabrication of electronic devices. Our theoretical calculations reveal that this increase in n-type conductivity and magnetization can be correlated with the presence of sulfur and molybdenum vacancies.

  12. Reconfigurable p-n junction diodes and the photovoltaic effect in exfoliated MoS{sub 2} films

    SciTech Connect (OSTI)

    Sutar, Surajit; Agnihotri, Pratik; Comfort, Everett; Ung Lee, Ji; Taniguchi, T.; Watanabe, K.

    2014-03-24

    Realizing basic semiconductor devices such as p-n junctions are necessary for developing thin-film and optoelectronic technologies in emerging planar materials such as MoS{sub 2}. In this work, electrostatic doping by buried gates is used to study the electronic and optoelectronic properties of p-n junctions in exfoliated MoS{sub 2} flakes. Creating a controllable doping gradient across the device leads to the observation of the photovoltaic effect in monolayer and bilayer MoS{sub 2} flakes. For thicker flakes, strong ambipolar conduction enables realization of fully reconfigurable p-n junction diodes with rectifying current-voltage characteristics, and diode ideality factors as low as 1.6. The spectral response of the photovoltaic effect shows signatures of the predicted band gap transitions. For the first excitonic transition, a shift of >4{sub kB}T is observed between monolayer and bulk devices, indicating a thickness-dependence of the excitonic coulomb interaction.

  13. Growth kinetics and microstructural evolution during hot isostatic pressing of U-10 wt.% Mo monolithic fuel plate in AA6061 cladding with Zr diffusion barrier

    SciTech Connect (OSTI)

    Y. Park; J. Yoo; K. Huang; D. D. Keiser, Jr.; J. F. Jue; B. Rabin; G. Moore; Y. H. Sohn

    2014-04-01

    Phase constituents and microstructure changes in RERTR fuel plate assemblies as functions of temperature and duration of hot-isostatic pressing (HIP) during fabrication were examined. The HIP process was carried out as functions of temperature (520, 540, 560 and 580 °C for 90 min) and time (45–345 min at 560 °C) to bond 6061 Al-alloy to the Zr diffusion barrier that had been co-rolled with U-10 wt.% Mo (U10Mo) fuel monolith prior to the HIP process. Scanning and transmission electron microscopies were employed to examine the phase constituents, microstructure and layer thickness of interaction products from interdiffusion. At the interface between the U10Mo and Zr, following the co-rolling, the UZr2 phase was observed to develop adjacent to Zr, and the a-U phase was found between the UZr2 and U10Mo, while the Mo2Zr was found as precipitates mostly within the a-U phase. The phase constituents and thickness of the interaction layer at the U10Mo-Zr interface remained unchanged regardless of HIP processing variation. Observable growth due to HIP was only observed for the (Al,Si)3Zr phase found at the Zr/AA6061 interface, however, with a large activation energy of 457 ± 28 kJ/mole. Thus, HIP can be carried to improve the adhesion quality of fuel plate without concern for the excessive growth of the interaction layer, particularly at the U10Mo-Zr interface with the a-U, Mo2Zr, and UZr2 phases.

  14. Radiation Stability of Mo2Zr Phase as an Interaction Product in U-10M0/Zr/Al 6061 Monolithic Fuel Plate

    SciTech Connect (OSTI)

    Jian Gan; Brandon D. Miller; Dennis D. Keiser; Daniel M. Wachs; W. Sprowes; Y. H. Sohn; M. Kirk

    2015-04-01

    Abstract Monolithic U-10Mo alloy fuel plates with Al-6061 cladding are being developed for use in research and test reactors as low enrichment fuel (< 20% U-235 enrichment). These fuel plates contain a Zr diffusion barrier between the U-10Mo fuel and Al-6061 cladding that suppresses the interaction between the two that is known to be problematic under irradiation. However, the Zr also interacts with the U-10Mo and Al-6061 cladding during fuel fabrication to produce a variety of interaction phases. The results from recent post-irradiation-examination (PIE) of the irradiated monolithic fuel plates suggested that the microstructural development of the U-10Mo/Zr interaction phases under irradiation may have an impact on fuel performance. The Mo2Zr phase has been identified as a major interaction product at the interface of U-10Mo and Zr. TEM in-situ irradiation with 500 keV Kr ions at 200 ?C temperature to 2?1016 ions/cm2 was carried out to investigate its radiation stability. The Mo2Zr undergoes a radiation-induced structural change, from a large cubic (cF24, a0 = 0.7588 nm) to a small bcc cubic (cI2, a0 = 0.3185 nm), along with an estimated 11.3% volume contraction without changing its composition. The Mo2Zr phase demonstrated exceptional radiation tolerance with the development of dislocation showing no evidence of bubble formation. The irradiation to the same ion dose with the reduced ion energy at 250 keV reveals a high concentration of small bubbles (< 2 nm) as a result of increased Kr ion retention in the sample. .

  15. By Coal Origin State

    U.S. Energy Information Administration (EIA) Indexed Site

    Table OS-1. Domestic coal distribution, by origin State, 1st Quarter 2010 Origin: Alabama (thousand short tons) Coal Destination State...

  16. By Coal Origin State

    U.S. Energy Information Administration (EIA) Indexed Site

    Table OS-1. Domestic coal distribution, by origin State, 4th Quarter 2011 Origin: Alabama (thousand short tons) Coal Destination State...

  17. By Coal Destination State

    U.S. Energy Information Administration (EIA) Indexed Site

    Table DS-1. Domestic coal distribution, by destination State, 3rd Quarter 2011 Destination: Alabama (thousand short tons) Coal Origin State...

  18. By Coal Origin State

    U.S. Energy Information Administration (EIA) Indexed Site

    Table OS-1. Domestic coal distribution, by origin State, 3rd Quarter 2011 Origin: Alabama (thousand short tons) Coal Destination State...

  19. By Coal Destination State

    U.S. Energy Information Administration (EIA) Indexed Site

    Table DS-1. Domestic coal distribution, by destination State, 4th Quarter 2011 Destination: Alabama (thousand short tons) Coal Origin State...

  20. By Coal Destination State

    U.S. Energy Information Administration (EIA) Indexed Site

    Table DS-1. Domestic coal distribution, by destination State, 3rd Quarter 2010 Destination: Alabama (thousand short tons) Coal Origin State...

  1. By Coal Origin State

    U.S. Energy Information Administration (EIA) Indexed Site

    Table OS-1. Domestic coal distribution, by origin State, 4th Quarter 2010 Origin: Alabama (thousand short tons) Coal Destination State...

  2. By Coal Origin State

    U.S. Energy Information Administration (EIA) Indexed Site

    Table OS-1. Domestic coal distribution, by origin State, 2nd Quarter 2011 Origin: Alabama (thousand short tons) Coal Destination State...

  3. By Coal Origin State

    U.S. Energy Information Administration (EIA) Indexed Site

    Table OS-1. Domestic coal distribution, by origin State, 3rd Quarter 2010 Origin: Alabama (thousand short tons) Coal Destination State...

  4. By Coal Destination State

    U.S. Energy Information Administration (EIA) Indexed Site

    Table DS-1. Domestic coal distribution, by destination State, 4th Quarter 2010 Destination: Alabama (thousand short tons) Coal Origin State...

  5. By Coal Origin State

    U.S. Energy Information Administration (EIA) Indexed Site

    Table OS-1. Domestic coal distribution, by origin State, 1st Quarter 2011 Origin: Alabama (thousand short tons) Coal Destination State...

  6. By Coal Destination State

    U.S. Energy Information Administration (EIA) Indexed Site

    Table DS-1. Domestic coal distribution, by destination State, 1st Quarter 2011 Destination: Alabama (thousand short tons) Coal Origin State...

  7. By Coal Origin State

    U.S. Energy Information Administration (EIA) Indexed Site

    Table OS-1. Domestic coal distribution, by origin State, 2nd Quarter 2010 Origin: Alabama (thousand short tons) Coal Destination State...

  8. By Coal Destination State

    U.S. Energy Information Administration (EIA) Indexed Site

    Table DS-1. Domestic coal distribution, by destination State, 1st Quarter 2010 Destination: Alabama (thousand short tons) Coal Origin State...

  9. By Coal Destination State

    U.S. Energy Information Administration (EIA) Indexed Site

    Table DS-1. Domestic coal distribution, by destination State, 2nd Quarter 2010 Destination: Alabama (thousand short tons) Coal Origin State...

  10. By Coal Destination State

    U.S. Energy Information Administration (EIA) Indexed Site

    Table DS-1. Domestic coal distribution, by destination State, 2nd Quarter 2011 Destination: Alabama (thousand short tons) Coal Origin State...

  11. EIA - State Electricity Profiles

    U.S. Energy Information Administration (EIA) Indexed Site

    United States Electricity Profile 2014 Table 1. 2014 Summary statistics (United States) Item Value Primary energy source Coal Net summer capacity (megawatts) 1,068,422 Electric ...

  12. STATE OF WASHINGTON August

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    STATE OF WASHINGTON August 29, 2012 The Honorable Stephen Chu, Secretary United States Department of Energy 1000 Independence Avenue Washington, DC 20585 Dear Secretary Chu: As you...

  13. Solid State Lighting Reliability

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Key Partners: Auburn University Cree SAS Institute PPG Industries State of North Carolina ... Consortium Auburn University SAS Institute Cree Lighting PPG Industries State of North ...

  14. Synthesis, characterization and evaluation of the photocatalytic performance of Ag-CdMoO{sub 4} solar light driven plasmonic photocatalyst

    SciTech Connect (OSTI)

    Adhikari, Rajesh; Malla, Shova; Gyawali, Gobinda; Sekino, Tohru; Lee, Soo Wohn

    2013-09-01

    Graphical abstract: - Highlights: Ag-CdMoO{sub 4} solar light driven photocatalyst was successfully synthesized. Photocatalyst exhibited strong absorption in the visible region. Photocatalytic activity was significantly enhanced. Enhanced activity was caused by the SPR effect induced by Ag nanoparticles. - Abstract: Ag-CdMoO{sub 4} plasmonic photocatalyst was synthesized in ethanol/water mixture by photo assisted co-precipitation method at room temperature. As synthesized powders were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), UVVis diffuse reflectance spectroscopy (DRS), X-ray photoelectron spectroscopy (XPS) and BrunauerEmmettTeller (BET) surface area analyzer. Photocatalytic activity was evaluated by performing the degradation experiment over methylene blue (MB) and indigo carmine (IC) as model dyes under simulated solar light irradiation. The results revealed that the Ag-CdMoO{sub 4} showed the higher photocatalytic performance as compared to CdMoO{sub 4} nanoparticles. Dispersion of Ag nanoparticles over the surface of CdMoO{sub 4} nanoparticles causes the surface plasmon resonance (SPR) and enhances the broad absorption in the entire visible region of the solar spectrum. Hence, dispersion of Ag nanoparticles over CdMoO{sub 4} nanoparticles could be the better alternative to enhance the absorption of visible light by scheelite crystal family for effective photocatalysis.

  15. A low-temperature extraction-solvothermal route to the fabrication of micro-sized MoS{sub 2} spheres modified by Cyanex 301

    SciTech Connect (OSTI)

    Shi Huaqiang; Fu Xun . E-mail: fuxun4483@163.com; Zhou Xiaodong; Wang Debao; Hu Zhengshui

    2006-06-15

    Mono-dispersed molybdenum disulfide micro-spheres with the diameter of 1-3 {mu}m have been successfully synthesized via extraction-solvothermal method at 150 deg. C. The extractant Cyanex 301 (di-(2,4,4-trimethylpentyl) dithiophosphinic acid) acted as phase transferring agent, reductant, sulfur source and morphology-controlling agent in the whole procedure. The obtained MoS{sub 2} micro-spheres were characterized by XRD, EDS, SEM, TEM, HRTEM, IR, UV-Vis and TG, respectively. The influences of reaction conditions were discussed while a mechanism was proposed to explain the formation of the micro-spheres. Moreover, the tribological properties of liquid paraffin (LP) containing Cyanex 301-modified MoS{sub 2} micro-spheres were also evaluated on a four-ball machine, showing that the obtained MoS{sub 2} product was an excellent oil additive in LP and such lubricant had good anti-wear and friction-reducing properties. - Graphical abstract: Mono-dispersed MoS{sub 2} micro-spheres with the diameter of 1-3 {mu}m were synthesized in gasoline via extraction-solvothermal method at 150 deg. C. The MoS{sub 2} product could be well dispersed into organic solvents again and the tribological properties of liquid paraffin (LP) containing MoS{sub 2} micro-spheres were improved.

  16. Bonding between graphene and MoS{sub 2} monolayers without and...

    Office of Scientific and Technical Information (OSTI)

    Laboratory, Los Alamos, New Mexico 87545 3 + Show Author Affiliations Theoretical Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States) Center ...

  17. Site-dependent free energy barrier for proton reduction on MoS2...

    Office of Scientific and Technical Information (OSTI)

    Research Org: Lawrence Livermore National Laboratory (LLNL), Livermore, CA Sponsoring Org: USDOE Country of Publication: United States Language: English Subject: 14 SOLAR ENERGY

  18. Removal of Radioactive Nuclides from Mo-99 Acidic Liquid Waste - 13027

    SciTech Connect (OSTI)

    Hsiao, Hsien-Ming; Pen, Ben-Li

    2013-07-01

    About 200 liters highly radioactive acidic liquid waste originating from Mo-99 production was stored at INER (Institute of Nuclear Energy Research). A study regarding the treatment of the radioactive acidic liquid waste was conducted to solve storage-related issues and allow discharge of the waste while avoiding environmental pollution. Before discharging the liquid waste, the acidity, NO{sub 3}{sup -} and Hg ions in high concentrations, and radionuclides must comply with environmental regulations. Therefore, the treatment plan was to neutralize the acidic liquid waste, remove key radionuclides to reduce the dose rate, and then remove the nitrate and mercury ions. Bench tests revealed that NaOH is the preferred solution to neutralize the high acidic waste solution and the pH of solution must be adjusted to 9?11 prior to the removal of nuclides. Significant precipitation was produced when the pH of solution reached 9. NaNO{sub 3} was the major content in the precipitate and part of NaNO{sub 3} was too fine to be completely collected by filter paper with a pore size of approximately 3 ?m. The residual fine particles remaining in solution therefore blocked the adsorption column during operation. Two kinds of adsorbents were employed for Cs-137 and a third for Sr-90 removal to minimize cost. For personnel radiation protection, significant lead shielding was required at a number of points in the process. The final process design and treatment facilities successfully treated the waste solutions and allowed for environmentally compliant discharge. (authors)

  19. Technical assumption for Mo-99 production in the MARIA reactor. Feasibility study

    SciTech Connect (OSTI)

    Jaroszewicz, J.; Pytel, K.; Dabkowski, L.; Krzysztoszek, G. [Institute of Atomic Energy, 05-400 Otwock-Swierk (Poland)

    2008-07-15

    The main objective of U-235 irradiation is to obtain the Tc-99m isotope which is widely used in the domain of medical diagnostics. The decisive factor determining its availability, despite its short life time, is a reaction of radioactive decay of Mo-99 into Tc- 99m. One of the possible sources of molybdenum can be achieved in course of the U-235 fission reaction. The paper presents activities and the calculations results obtained upon the feasibility study on irradiation of U-235 targets for production of molybdenum in the MARIA reactor. The activities including technical assumption were focused on performing calculation for modelling of the target and irradiation device as well as adequate equipment and tools for processing in reactor. It has been assumed that the basic component of fuel charge is an aluminium cladded plate with dimensions of 40x230x1.45 containing 4.7 g U-235. The presumed mode of the heat removal generated in the fuel charge of the reactor primary cooling circuit influences the construction of installation to be used for irradiation and the technological instrumentation. The outer channel construction for irradiation has to be identical as the standard fuel channel construction of the MARIA reactor. It enables to use the existing slab and reactor mounting sockets for the fastening of the molybdenum channel as well as the cooling water delivery system. The measurement of water temperature cooling a fuel charge and control of water flow rate in the channel can also be carried out be means of the standard instrumentation of the reactor. (author)

  20. Laser welding and post weld treatment of modified 9Cr-1MoVNb steel.

    SciTech Connect (OSTI)

    Xu, Z.

    2012-04-03

    Laser welding and post weld laser treatment of modified 9Cr-1MoVNb steels (Grade P91) were performed in this preliminary study to investigate the feasibility of using laser welding process as a potential alternative to arc welding methods for solving the Type IV cracking problem in P91 steel welds. The mechanical and metallurgical testing of the pulsed Nd:YAG laser-welded samples shows the following conclusions: (1) both bead-on-plate and circumferential butt welds made by a pulsed Nd:YAG laser show good welds that are free of microcracks and porosity. The narrow heat affected zone has a homogeneous grain structure without conventional soft hardness zone where the Type IV cracking occurs in conventional arc welds. (2) The laser weld tests also show that the same laser welder has the potential to be used as a multi-function tool for weld surface remelting, glazing or post weld tempering to reduce the weld surface defects and to increase the cracking resistance and toughness of the welds. (3) The Vicker hardness of laser welds in the weld and heat affected zone was 420-500 HV with peak hardness in the HAZ compared to 240 HV of base metal. Post weld laser treatment was able to slightly reduce the peak hardness and smooth the hardness profile, but failed to bring the hardness down to below 300 HV due to insufficient time at temperature and too fast cooling rate after the time. Though optimal hardness of weld made by laser is to be determined for best weld strength, methods to achieve the post weld laser treatment temperature, time at the temperature and slow cooling rate need to be developed. (4) Mechanical testing of the laser weld and post weld laser treated samples need to be performed to evaluate the effects of laser post treatments such as surface remelting, glazing, re-hardening, or tempering on the strength of the welds.

  1. Application of U10Mo Fuel for Space Fission Power Applications - White Paper

    SciTech Connect (OSTI)

    James Werner

    2014-07-01

    A novel reactor design has been proposed for space applications to provide hundreds of watts to one or two kilowatts of electrical power. The reactor concept proposed uses the alloy U10Mo (uranium with 10 weight percent molybdenum) as the fuel. This fuel was selected for its high uranium density, high thermal conductivity, and excellent neutronic characteristics for this application. The core is surrounded by a BeO reflector. Heat is carried from the reactor by liquid metal heat pipes. A shadow shield of LiH tungsten is also utilized to reduce the neutron and gamma radiation dose to the rest of the spacecraft. This design represents a best effort at minimizing the complexity of the fission system and reducing the mass of the system. The compact nature of the block UMo core and BeO radial reflector allows the reactor diameter to be as small as practical while still meeting the neutronic and thermal power demands. This directly results in a reduced shield mass since the reactor diameter dictates the footprint of the radiation shield. The use of heat pipes offers a straightforward primary heat transport approach using proven liquid-metal heat pipe technology. Further, the elimination of a liquid core coolant system heat transport components, both at the reactor side and radiator side, contributes to reducing the total part-count and lowering system mass. The proposed reactor is using a fuel that is being developed by DOE, but there are significant differences in the fuels enrichment, operating conditions and the physical shape of the fuel itself. This paper attempts to highlight some of the basic consideration and needs that would be expected to be met in developing this fuel and qualifying it for use.

  2. Nano-Scale Fission Product Phases in an Irradiated U-7Mo Alloy Nuclear Fuel

    SciTech Connect (OSTI)

    Dennis Keiser, Jr.; Brandon Miller; James Madden; Jan-Fong Jue; Jian Gan

    2014-09-01

    Irradiated nuclear fuel is a very difficult material to characterize. Due to the large radiation fields associated with these materials, they are hard to handle and typically have to be contained in large hot cells. Even the equipment used for performing characterization is housed in hot cells or shielded glove boxes. The result is not only a limitation in the techniques that can be employed for characterization, but also a limitation in the size of features that can be resolved The most standard characterization techniques include light optical metallography (WM), scanning electron microscopy (SEM), and electron probe microanalysis (EPMA). These techniques are applied to samples that are typically prepared using grinding and polishing approaches that will always generate some mechanical damage on the sample surface. As a result, when performing SEM analysis, for example, the analysis is limited by the quality of the sample surface that can be prepared. However, a new approach for characterizing irradiated nuclear fuel has recently been developed at the Idaho National Laboratory (INL) in Idaho Falls, Idaho. It allows for a dramatic improvement in the quality of characterization that can be performed when using an instrument like an SEM. This new approach uses a dual-beam scanning microscope, where one of the beams isa focused ion beam (FIB), which can be used to generate specimens of irradiated fuel (-10m x 10m) for microstructural characterization, and the other beam is the electron beam of an SEM. One significant benefit of this approach is that the specimen surface being characterized has received much less damage (and smearing) than is caused by the more traditional approaches, which enables the imaging of nanometer sized microstructural features in the SEM. The process details are for an irradiated low-enriched uranium (LEU) U-Mo alloy fuel Another type of irradiated fuel that has been characterized using this technique is a mixed oxide fuel.

  3. Conformal growth of Mo/Si multilayers on grating substrates using collimated ion beam sputtering

    SciTech Connect (OSTI)

    Gawlitza, Peter; Cambie, Rossana; Dhuey, Scott; Gullikson, Eric; Warwick, Tony; Braun, Stefan; Yashchuk, Valeriy; Padmore, Howard

    2012-01-23

    Deposition of multilayers on saw-tooth substrates is a key step in the fabrication of multilayer blazed gratings (MBG) for extreme ultraviolet and soft x-rays. Growth of the multilayers can be perturbed by shadowing effects caused by the highly corrugated surface of the substrates, which results in distortion of the multilayer stack structure and degradation of performance of MBGs. To minimize the shadowing effects we used an ionbeam sputtering machine with a highly collimated atomic flux to deposit Mo/Si multilayers on saw-tooth substrates. The sputtering conditions were optimized by finding a balance between smoothening and roughening processes in order to minimize degradation of the groove profile in the course of deposition and at the same time to keep the interfaces of a multilayer stack smooth enough for high efficiency. An optimal value of energy of 200 eV for sputtering Kr{sup +} ions was found by deposition of test multilayers on flat substrates at a range of ion energies. Two saw-tooth substrates were deposited at energies of 200 eV and 700 eV for the sputtering ions. It was found that reduction of the ion energy improved the blazing performance of the MBG and resulted in a 40% gain in the diffraction efficiency due to better replication of the groove profile by the multilayer. As a result of the optimization performed, an absolute diffraction efficiency of 28.8% was achieved for the 2nd blaze order of the MBG with a groove density of 7350 lines/mm at a wavelength of 13.5 nm. Details of the growth behavior of the multilayers on flat and saw-tooth substrates are discussed in terms of the Linear Continuous Model of film growth.

  4. State Energy Risk Assessment Initiative - State Energy Risk Profiles...

    Energy Savers [EERE]

    Mission Energy Infrastructure Modeling and Analysis State Energy Risk Assessment Initiative - State Energy Risk Profiles State Energy Risk Assessment Initiative - State...

  5. State Energy Program Helps States Plan and Implement Energy Efficiency...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Helps States Plan and Implement Energy Efficiency State Energy Program Helps States Plan and Implement Energy Efficiency The U.S. Department of Energy (DOE) State Energy Program ...

  6. Ga-67 vs In-111-DTPA-anti-p97 monoclonal antibody (MoAb) for scintigraphic detection of metastatic melanoma

    SciTech Connect (OSTI)

    Neumann, R.D.; Kirkwood, J.M.; Zoghbi, S.S.; Ernstoff, M.S.; Cornelius, E.A.; Hoffer, P.B.; Gottschalk, A.

    1985-05-01

    The authors have initiated a prospective comparative evaluation of tomographic (Pho/Con) Ga-67 (10 mCi) scintigraphy versus computerized gamma camera radioimmunoscintigraphy using anti-p97 murine MoAb (5 mCi In-111-DTPA conjugated to 1 mg MoAb + 19 mgs ''cold'' MoAb) for detection of metastatic melanoma. To date 9 patients have had both a Ga-67 scan and an anti-p97 MoAb study within a 1 month interval. The 9 patients had 45 known sites of disease greater than 1 cm minimum diameter, located in skin, soft tissue, and/or viscea. In-111-anti-p97 scans were done 72 hrs after i.v. administration of the radiolabeled MoAb mixed together with the ''cold'' carrier MoAb. Ga-67 scans were done 48-72 hrs after injection. MoAb scans detected 30/45 known sites (sensitivity=67%) while the Ga-67 scans found 29/45 of these known sites (sensitivity=64%). Heterogeneity of metastases was evident with the detection of partly overlapping subsets of metastases by the two techniques, i.e. some mets were localized with both techniques while other mets were detected by only one of the two methods. Combined detection with both techniques improved sensitivity from 64-67% to 91%. These preliminary data suggest: 1) comparable sensitivities for Ga-67 and In-111-DTPA anti-p97 scans, 2) heterogeneity of metastases with regard to the localization of these two agents, and 3) improved sensitivity by combining both techniques.

  7. The effect of strontium non-stoichiometry on the physical properties of double perovskite Sr{sub 2}FeMoO{sub 6}

    SciTech Connect (OSTI)

    Harnagea, L. Berthet, P.

    2015-02-15

    We present a detailed study on the effect of strontium non-stoichiometry on the properties of double perovskite Sr{sub 2}FeMoO{sub 6} (SFMO). A citrate route has been used to prepare high quality polycrystalline samples with (2−x)Sr:Fe:Mo (x=0, 0.02, 0.04) and (2+x)Sr:Fe:Mo (x=0.02, 0.04, 0.10) cationic ratios. The strontium deficient samples exhibit a significant decrease in their values of saturation magnetization (Ms), Curie temperature (Tc) and magnetoresistance (MR) compared to the stoichiometric SFMO. On the other hand, the samples prepared with an excess of strontium, respectively those with x=0.02 and 0.04, show remarkably superior magneto–transport characteristics, despite of their increased level of Fe/Mo disorder and somewhat diminished magnetic properties compared to the stoichiometric SFMO. We also show that these samples exhibit superior MR values under low magnetic field and persisting up to temperatures as high as 400 K. - Graphical abstract: Evolution of the magnetization versus temperature under an applied magnetic field of 1000 Oe (left panel) and magnetoresistance versus applied magnetic field at 300 K (right panel) for strontium off-stoichiometric Sr{sub 2}FeMoO{sub 6} samples. - Highlights: • Strontium nonstoichiometric samples of Sr{sub 2}FeMoO{sub 6} are prepared by a citrate route. • The nonstoichiometric samples exhibit an increased Fe/Mo disorder in the structure. • We observed important changes in their magnetic and magnetoresistive properties. • Improved magnetoresistive properties for samples prepared with strontium excess.

  8. Fuel Cells in the States

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    in the Fuel Cells in the States States State and Regional State and Regional Initiatives ... Jennifer Gangi Jennifer Gangi Program Director Program Director Fuel Cells 2000 Fuel Cells ...

  9. Strain, interdiffusion, and microstructural evolution under ion irradiation in Ni(111)/Mo(110) multilayers: Interdependence with elastic properties

    SciTech Connect (OSTI)

    Martin, F.; Jaouen, C.; Pacaud, J.; Abadias, G.; Djemia, Ph.; Ganot, F.

    2005-01-15

    The interdependence between the microstructure of sputter-deposited Ni(111)/Mo(110) superlattices and their elastic behavior is investigated as a function of the bilayer period ({lambda}). Brillouin light scattering measurements show that a drastic softening of the effective shear modulus occurs with decreasing {lambda}, until {lambda}=2 nm where it reaches -62%. Ion irradiation is here used to trigger stress relaxation and to induce, in a controlled way, interdiffusion and structural changes allowing us thus to investigate their influence on the elastic anomaly. At a very low irradiation dose (0.1 displacements per atom), the relief of the lattice expansion and associated compressive stresses does not induce any change of the elastic response, which indicates that the elastic behavior of the as-grown multilayers is not correlated with the presence of elastic strains. Furthermore, a detailed x-ray diffraction analysis shows that the unstrained lattice parameter of Mo layers exhibit a linear dependence with the interface density, while the Ni unstrained lattice parameter remains nearly unchanged in the same {lambda} range. This effect can be attributed to an interfacial mixing of a constant Ni amount ({approx}1.5 monolayers) into the Mo layers, as a consequence of a dynamic segregation of Ni atoms during growth. Thus, the formation of interfacial metastable and supersaturated solid solutions, structurally and mechanically unstable, appears as the origin of the huge elastic softening observed in this system. At high ion fluences, when the mixing process becomes dominant, the present study also provides experimental data on phase transformation in 'driven' alloys, by addressing the issue of the stability of out-of-equilibrium structures under irradiation.

  10. Progress and status of the IAEA coordinated research project: production of Mo-99 using LEU fission or neutron activation

    SciTech Connect (OSTI)

    Goldman, Ira N.; Adelfang, Pablo E-mail: P.Adelfang@iaea.org; Ramamoorthy, Natesan

    2008-07-15

    Since late 2004, the IAEA has developed and implemented a Coordinated Research Project (CRP) to assist countries interested in initiating indigenous, small-scale production of Mo-99 to meet local nuclear medicine requirements. The objective of the CRP is to provide interested countries with access to non-proprietary technologies and methods to produce Mo-99 using LEU foil or LEU mini-plate targets, or for the utilization of n,gamma neutron activation, e.g. through the use of gel generators. The project has made further progress since the RERTR 2006 meeting, with a Technical Workshop on Operational Aspects of Mo99 Production held 28-30 November 2006 in Vienna and the Second Research Coordination Meeting held in Bucharest, Romania 16-20 April 2007. The paper describes activities carried out as noted above, and as well as the provision of LEU foils to a number of participants, and the progress by a number of groups in preparing for LEU target assembly and disassembly, irradiation, chemical processing, and waste management. The participants' progress in particular on thermal hydraulics computations required for using LEU targets is notable, as also the progress in gel generator plant operations in India and Kazakhstan. Poland has joined as a new research agreement holder and an application by Egypt to be a contract holder is undergoing internal review in the IAEA and is expected to be approved. The IAEA has also participated in several open meetings of the U.S. National Academy of Sciences Study on Producing Medical Radioisotopes without HEU, which will also be discussed in the paper. (author)

  11. Effects of Irradiation on the Microstructure of U-7Mo Dispersion Fuel with Al-2Si Matrix

    SciTech Connect (OSTI)

    Dennis D. Keiser, Jr.; Jan-Fong Jue; Adam B. Robinson; Pavel Medvedev; Jian Gan; Brandon D. Miller; Daniel M. Wachs; Glenn A. Moore; Curtis R. Clark; Mitchell K. Meyer; M. Ross Finlay

    2012-06-01

    The Reduced Enrichment for Research and Test Reactor program is developing low-enriched uranium U-Mo dispersion fuels for application in research and test reactors around the world. As part of this development, fuel plates have been irradiated in the Advanced Test Reactor and then characterized using optical metallography (OM) and scanning electron microscopy (SEM) to determine the as-irradiated microstructure. To demonstrate the irradiation performance of U-7Mo dispersion fuel plates with 2 wt% Si added to the matrix, fuel plates were tested to medium burnups at intermediate fission rates as part of the RERTR-6 experiment. Further testing was performed to higher fission rates as part of the RERTR-7A experiment, and very aggressive testing (high temperature, high fission density, high fission rate) was performed in the RERTR-9A, RERTR-9B and AFIP-1 experiments. As-irradiated microstructures were compared to those observed after fabrication to determine the effects of irradiation on the microstructure. Based on comparison of the microstructural characterization results for each irradiated sample, some general conclusions can be drawn about how the microstructure evolves during irradiation: there is growth of the fuel/matrix interaction layer (FMI), which was present in the samples to some degree after fabrication, during irradiation; Si diffuses from the FMI layer to deeper depths in the U-7Mo particles as the irradiation conditions are made more aggressive; lowering of the Si content in the FMI layer results in an increase in the size of the fission gas bubbles; as the FMI layer grows during irradiation more Si diffuses from the matrix to the FMI layer/matrix interface, and interlinking of fission gas bubbles in the fuel plate microstructure that may indicate breakaway swelling is not observed.

  12. Prediction and Monitoring Systems of Creep-Fracture Behavior of 9Cr-1Mo Steels for Teactor Pressure Vessels

    SciTech Connect (OSTI)

    Potirniche, Gabriel; Barlow, Fred D.; Charit, Indrajit; Rink, Karl

    2013-11-26

    A recent workshop on next-generation nuclear plant (NGNP) topics underscored the need for research studies on the creep fracture behavior of two materials under consideration for reactor pressure vessel (RPV) applications: 9Cr-1Mo and SA-5XX steels. This research project will provide a fundamental understanding of creep fracture behavior of modified 9Cr-1Mo steel welds for through modeling and experimentation and will recommend a design for an RPV structural health monitoring system. Following are the specific objectives of this research project: • Characterize metallurgical degradation in welded modified 9Cr-1Mo steel resulting from aging processes and creep service conditions. • Perform creep tests and characterize the mechanisms of creep fracture process. • Quantify how the microstructure degradation controls the creep strength of welded steel specimens. • Perform finite element (FE) simulations using polycrystal plasticity to understand how grain texture affects the creep fracture properties of welds. • Develop a microstructure-based creep fracture model to estimate RPVs service life . • Manufacture small, prototypic, cylindrical pressure vessels, subject them to degradation by aging, and measure their leak rates. • Simulate damage evolution in creep specimens by FE analyses. • Develop a model that correlates gas leak rates from welded pressure vessels with the amount of microstructural damage. • Perform large-scale FE simulations with a realistic microstructure to evaluate RPV performance at elevated temperatures and creep strength. • Develop a fracture model for the structural integrity of RPVs subjected to creep loads. • Develop a plan for a non-destructive structural health monitoring technique and damage detection device for RPVs.

  13. Atomic layer deposition grown MO{sub x} thin films for solar water splitting: Prospects and challenges

    SciTech Connect (OSTI)

    Singh, Trilok; Lehnen, Thomas; Leuning, Tessa; Mathur, Sanjay

    2015-01-15

    The magnitude of energy challenge not only calls for efficient devices but also for abundant, inexpensive, and stable photoactive materials that can enable efficient light harvesting, charge separation and collection, as well as chemical transformations. Photoelectrochemical systems based on semiconductor materials have the possibility to transform solar energy directly into chemical energy the so-called “solar hydrogen.” The current challenge lies in the harvesting of a larger fraction of electromagnetic spectrum by enhancing the absorbance of electrode materials. In this context, atomically precise thin films of metal oxide semiconductors and their multilayered junctions are promising candidates to integrate high surface areas with well-defined electrode–substrate interface. Given its self-limited growth mechanism, the atomic layer deposition (ALD) technique offers a wide range of capabilities to deposit and modify materials at the nanoscale. In addition, it opens new frontiers for developing precursor chemistry that is inevitable to design new processes. Herein, the authors review the properties and potential of metal oxide thin films deposited by ALD for their application in photoelectrochemical water splitting application. The first part of the review covers the basics of ALD processes followed by a brief discussion on the electrochemistry of water splitting reaction. The second part focuses on different MO{sub x} films deposited by atomic layer deposition for water splitting applications; in this section, The authors discuss the most explored MO{sub x} semiconductors, namely, Fe{sub 2}O{sub 3}, TiO{sub 2}, WO{sub 3}, and ZnO, as active materials and refer to their application as protective coatings, conductive scaffolds, or in heterojunctions. The third part deals with the current challenges and future prospects of ALD processed MO{sub x} thin films for water splitting reactions.

  14. Crystal structural study of ternary molybdate LiRbBi{sub 2}(MoO{sub 4}){sub 4}

    SciTech Connect (OSTI)

    Klevtsova, R.F.; Glinskaya, L.A.; Alekseev, V.I.

    1994-03-01

    Single crystals of the title compound have been synthesized and its crystal structure has been determined. The compound crystallizes in the monoclinic system, space group C2/c, Z = 2 (a = 5.3056, b = 12.976, c = 19.578 {angstrom}, {beta} = 92.583{degrees}, R = 0.029). A distinctive feature of the structure is lacy layers of eight-vertex Bi polyhedra and Mo tetrahedra connected to them via common vertices. The adjacent layers are linked together by ten-vertex Rb polyhedra and Li octahedra.

  15. Deformation and fracture behavior of Ni-Mo-Al (. gamma. /. gamma. -. cap alpha. ) in-situ composite

    SciTech Connect (OSTI)

    Siramamurthy, A.M.; Tewari, S.N.

    1984-10-01

    Tensile properties for directionally solidified (DS) eutectic alloy of a nominal composition Ni-33 Mo-5.7 Al (weight percent) have been investigated at room and elevated temperatures. The microstructure-mechanical property relationship has been studied for the as-DS and heat-treated conditions. Changes in yield strength, work hardening behavior, and fracture morphology are explained in terms of microstructural changes due to heat treatment. The yield drops are attributed to microdebonding due to segregation of impurities at the fiber-matrix interface and partly to strain aging.

  16. Basin Destination State

    Gasoline and Diesel Fuel Update (EIA)

    4. Estimated rail transportation rates for coal, basin to state, EIA data Basin Destination State 2008 2009 2010 2008-2010 2009-2010 Northern Appalachian Basin Delaware 26.24 - W...

  17. Basin Destination State

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    3. Estimated rail transportation rates for coal, basin to state, EIA data Basin Destination State 2008 2009 2010 2008-2010 2009-2010 Northern Appalachian Basin Delaware 28.49 - W...

  18. State Energy Strategic Plans

    Broader source: Energy.gov [DOE]

    Most state energy offices across the country are required to have current and long-term strategic energy management plans in place. These strategic plans help to ensure that state agencies are...

  19. FY 2005 State Table

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Office of Management, Budget and Evaluation/CFO February 2004 State Tables State Tables Preliminary Preliminary Department of Energy Department of Energy FY 2005 Congressional Budget FY 2005 Congressional Budget Request Request Office of Management, Budget and Evaluation/CFO February 2004 State Tables State Tables Printed with soy ink on recycled paper Preliminary Preliminary The numbers depicted in this document represent the gross level of DOE budget authority for the years displayed. The

  20. AASG STATE GDR

    Energy Science and Technology Software Center (OSTI)

    003198MLTPL00 AASG State Geothermal Data Repository for the National Geothermal Data System. http://repository.stategeothermaldata.org/repository/

  1. AASG State Geological Survey

    Broader source: Energy.gov [DOE]

    presentation at the April 2013 peer review meeting held in Denver, Colorado.Contributions to the NGDSAASG State Geological Survey

  2. States & Emerging Energy Technologies

    Broader source: Energy.gov [DOE]

    This presentation, given through the DOE's Technical Assitance Program (TAP), provides information on States & Emerging Energy Technologies.

  3. Discrete Li-occupation versus pseudo-continuous Na-occupation and their relationship with structural change behaviors in Fe₂(MoO₄)₃

    SciTech Connect (OSTI)

    Yue, Ji-Li; Zhou, Yong-Ning; Shi, Si-Qi; Shadike, Zulipiya; Huang, Xuan-Qi; Luo, Jun; Yang, Zhen-Zhong; Li, Hong; Gu, Lin; Yang, Xiao-Qing; Fu, Zheng-Wen

    2015-03-06

    The key factors governing the single-phase or multi-phase structural change behaviors during the intercalation/deintercalation of guest ions have not been well studied and understood yet. Through systematic studies of orthorhombic Fe₂(MoO₄)₃ electrode, two distinct guest ion occupation paths, namely discrete one for Li and pseudo-continuous one for Na, as well as their relationship with single-phase and two-phase modes for Na⁺ and Li⁺, respectively during the intercalation/deintercalation process have been demonstrated. For the first time, the direct atomic-scale observation of biphasic domains (discrete occupation) in partially lithiated Fe₂(MoO₄)₃ and the one by one Na occupation (pseudo-continuous occupation) at 8d sites in partially sodiated Fe₂(MoO₄)₃ are obtained during the discharge processes of Li/Fe₂(MoO₄)₃ and Na/Fe₂(MoO₄)₃ cells respectively. Our combined experimental and theoretical studies bring the new insights for the research and development of intercalation compounds as electrode materials for secondary batteries.

  4. Synthesis of novel MoS{sub 2}/g-C{sub 3}N{sub 4} heterojunction photocatalysts with enhanced hydrogen evolution activity

    SciTech Connect (OSTI)

    Tian, Yuming; Ge, Lei; Wang, Kaiyue; Chai, Yuesheng

    2014-01-15

    Novel MoS{sub 2}/g-C{sub 3}N{sub 4} heterojunction photocatalysts were synthesized via a simple impregnation and heating methods. The products were characterized by X-ray diffraction, transmission electron microscopy and UVvis diffuse reflectance spectra. The photocatalytic activities of MoS{sub 2}/g-C{sub 3}N{sub 4} samples were evaluated based on the hydrogen evolution experiments under visible light irradiation (? > 400 nm). The UVvis diffuse reflectance spectra revealed that the MoS{sub 2}/g-C{sub 3}N{sub 4} photocatalysts had strong absorption in the visible light region. The photocatalytic results indicated that the highest H{sub 2} evolution rate of 23.10 ?molh{sup ?1} was achieved on the 0.5 wt.% MoS{sub 2}g-C{sub 3}N{sub 4} sample, which was enhanced by 11.3 times compared to pure g-C{sub 3}N{sub 4}. This study may provide an approach to the development of novel heterojunction photocatalysts for hydrogen production under visible light irradiation. - Highlights: MoS{sub 2}/g-C{sub 3}N{sub 4} photocatalyst is obtained by simple impregnation and heating methods. and determined by XRD, TEM, UV-vis diffuse reflectance spectra. the photocatalysts had strong absorption in the visible light region. the highest H2 evolution rate was achieved on the 0.5wt% samples.

  5. Discrete Li-occupation versus pseudo-continuous Na-occupation and their relationship with structural change behaviors in Fe?(MoO?)?

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yue, Ji -Li; Zhou, Yong -Ning; Shi, Si -Qi; Shadike, Zulipiya; Huang, Xuan -Qi; Luo, Jun; Yang, Zhen -Zhong; Li, Hong; Gu, Lin; Yang, Xiao -Qing; et al

    2015-03-06

    The key factors governing the single-phase or multi-phase structural change behaviors during the intercalation/deintercalation of guest ions have not been well studied and understood yet. Through systematic studies of orthorhombic Fe?(MoO?)? electrode, two distinct guest ion occupation paths, namely discrete one for Li and pseudo-continuous one for Na, as well as their relationship with single-phase and two-phase modes for Na? and Li?, respectively during the intercalation/deintercalation process have been demonstrated. For the first time, the direct atomic-scale observation of biphasic domains (discrete occupation) in partially lithiated Fe?(MoO?)? and the one by one Na occupation (pseudo-continuous occupation) at 8d sites inmorepartially sodiated Fe?(MoO?)? are obtained during the discharge processes of Li/Fe?(MoO?)? and Na/Fe?(MoO?)? cells respectively. Our combined experimental and theoretical studies bring the new insights for the research and development of intercalation compounds as electrode materials for secondary batteries.less

  6. The Influence of Neutron Irradiation in FFTF on the Microstructural and Microchemical Development of Mo-41Re at 470-730ºC

    SciTech Connect (OSTI)

    Edwards, Danny J.; Garner, Francis A.; Gelles, David S.

    2008-04-30

    Specimens of Mo-41 wt% Re irradiated in the Fast Flux Test Facility (FFTF) experience significant and non-monotonic changes in density that arise first from radiation-induced segregation, leading to non-equilibrium phase separation, and second by progressive transmutation of Re to Os. As a consequence the density of Mo-41Re initially decreases and then increases thereafter. Beginning as a single-phase solid solution of Re and Mo, irradiation of Mo-41 wt% Re over a range of temperatures (470-730ºC) to 28-96 dpa produces a high density of thin platelets of a hexagonal close-packed phase identified as a solid solution of Re, Os and possibly a small amount of Mo. These hcp precipitates are thought to form in the alloy matrix as a consequence of strong radiation-induced segregation to Frank loops. Grain boundaries also segregate Re to form the hcp phase, but the precipitates are much bigger and more equiaxed in shape. Although not formed at lower dose, continued irradiation at 730º C leads to the co-formation of late-forming Chi–phase, an equilibrium phase that then competes with the preexisting hcp phase for rhenium.

  7. Discrete Li-occupation versus pseudo-continuous Na-occupation and their relationship with structural change behaviors in Fe₂(MoO₄)₃

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yue, Ji-Li; Zhou, Yong-Ning; Shi, Si-Qi; Shadike, Zulipiya; Huang, Xuan-Qi; Luo, Jun; Yang, Zhen-Zhong; Li, Hong; Gu, Lin; Yang, Xiao-Qing; et al

    2015-03-06

    The key factors governing the single-phase or multi-phase structural change behaviors during the intercalation/deintercalation of guest ions have not been well studied and understood yet. Through systematic studies of orthorhombic Fe₂(MoO₄)₃ electrode, two distinct guest ion occupation paths, namely discrete one for Li and pseudo-continuous one for Na, as well as their relationship with single-phase and two-phase modes for Na⁺ and Li⁺, respectively during the intercalation/deintercalation process have been demonstrated. For the first time, the direct atomic-scale observation of biphasic domains (discrete occupation) in partially lithiated Fe₂(MoO₄)₃ and the one by one Na occupation (pseudo-continuous occupation) at 8d sites inmore » partially sodiated Fe₂(MoO₄)₃ are obtained during the discharge processes of Li/Fe₂(MoO₄)₃ and Na/Fe₂(MoO₄)₃ cells respectively. Our combined experimental and theoretical studies bring the new insights for the research and development of intercalation compounds as electrode materials for secondary batteries.« less

  8. Solid-state dosimeters: A new approach for mammography measurements

    SciTech Connect (OSTI)

    Brateman, Libby F.; Heintz, Philip H.

    2015-02-15

    Purpose: To compare responses of modern commercially available solid-state dosimeters (SStDs) used in mammography medical physics surveys for two major vendors of current digital mammography units. To compare differences in dose estimates among SStD responses with ionization chamber (IC) measurements for several target/filter (TF) combinations and report their characteristics. To review scientific bases for measurements of quantities required for mammography for traditional measurement procedures and SStDs. Methods: SStDs designed for use with modern digital mammography units were acquired for evaluation from four manufacturers. Each instrument was evaluated under similar conditions with the available mammography beams provided by two modern full-field digital mammography units in clinical use: a GE Healthcare Senographe Essential (Essential) and a Hologic Selenia Dimensions 5000 (Dimensions), with TFs of Mo/Mo, Mo/Rh; and Rh/Rh and W/Rh, W/Ag, and W/Al, respectively. Measurements were compared among the instruments for the TFs over their respective clinical ranges of peak tube potentials for kVp and half-value layer (HVL) measurements. Comparisons for air kerma (AK) and their associated relative calculated average glandular doses (AGDs), i.e., using fixed mAs, were evaluated over the limited range of 2830 kVp. Measurements were compared with reference IC measurements for AK, reference HVLs and calculated AGD, for two compression paddle heights for AK, to evaluate scatter effects from compression paddles. SStDs may require different positioning from current mammography measurement protocols. Results: Measurements of kVp were accurate in general for the SStDs (within ?1.2 and +1.1 kVp) for all instruments over a wide range of set kVps and TFs and most accurate for Mo/Mo and W/Rh. Discrepancies between measurements and reference values were greater for HVL and AK. Measured HVL values differed from reference values by ?6.5% to +3.5% depending on the SStD and TF. AK measurements over limited (2830) kVps ranged from ?6% to +7% for SStDs, compared with IC reference values. Relative AGDs for each SStD using its associated measurements of kVp, HVL and AK underestimated AGD in nearly all cases, compared with reference IC values, with discrepancies of

  9. PLASMA SPRAYED FUNCTIONALLY GRADED AND LAYERED MoSi2-A1203 COMPOSITES FOR HIGH TEMPERATURE SENSOR SHEATH APPLICATION

    SciTech Connect (OSTI)

    R. VAIDYA; ET AL

    2001-01-01

    Protective sensor sheaths are required in the glass industry for sensors that are used to measure various properties of the melt. Molten glass presents an extremely corrosive elevated temperature environment, in which only a few types of materials can survive. Molybdenum disilicide (MoSi{sub 2}) has been shown to possess excellent corrosion resistance in molten glass, and is thus a candidate material for advanced sensor sheath applications. Plasma spray-forming techniques were developed to fabricate molybdenum dilicide-alumina (Al{sub 2}O{sub 3}) laminate and functionally graded composite tubes with mechanical properties suitable for sensor sheath applications. These functionally graded materials (FGMs) were achieved by manipulating the powder hoppers and plasma torch translation via in-house created computer software. Molybdenum disilicide and alumina are thermodynamically stable elevated temperature materials with closely matching thermal expansion coefficients. Proper tailoring of the microstructure of these MoSi{sub 2}-Al{sub 2}O{sub 3} composites can result in improved strength, toughness, and thermal shock resistance. This study focuses on the mechanical performance of these composite microstructures.

  10. Comparison of Crevice Corrosion of Fe-Based Amorphous Metal and Crystalline Ni-Cr-Mo Alloy

    SciTech Connect (OSTI)

    Shan, X; Ha, H; Payer, J H

    2008-07-24

    The crevice corrosion behaviors of an Fe-based bulk metallic glass alloy (SAM1651) and a Ni-Cr-Mo crystalline alloy (C-22) were studied in 4M NaCl at 100 C with cyclic potentiodynamic polarization and constant potential tests. The corrosion damage morphologies, corrosion products and the compositions of corroded surfaces of these two alloys were studied with optical 3D reconstruction, Scanning Electron Microscopy (SEM), Energy Dispersive Spectroscopy (EDS) and Auger Electron Spectroscopy (AES). It was found that the Fe-based bulk metallic glass (amorphous alloy) SAM1651 had a more positive breakdown potential and repassivation potential than crystalline alloy C-22 in cyclic potentiodynamic polarization tests and required a more positive oxidizing potential to initiate crevice corrosion in constant potential test. Once crevice corrosion initiated, the corrosion propagation of C-22 was more localized near the crevice border compared to SAM1651, and SAM1651 repassivated more readily than C-22. The EDS results indicated that the corrosion products of both alloys contained high amount of O and were enriched in Mo and Cr. The AES results indicated that a Cr-rich oxide passive film was formed on the surfaces of both alloys, and both alloys were corroded congruently.

  11. Production of monoclonal antibody (MoAB) CS-1 against platelet glycoprotein IIb-IIIa (GP IIb-IIIa)

    SciTech Connect (OSTI)

    Ramsamooj, P.; Morris, M.; Doellgast, G.; Hantgan, R.

    1987-05-01

    Platelet aggregation is mediated by the binding of fibrinogen (FGN) to the platelet GP IIb-IIIa complex. Receptor complex was purified from a solubilized platelet membrane fraction followed by lentil-lectin affinity chromatography and gel filtration. SDS-PAGE showed the product to be the complex, GP IIb-IIIa; light scattering intensity measurements indicated a Ca/sup 2 +/-dependent complex of the appropriate MW. Purified complex was then used to raise antibodies in Balb-c mice by standard hybridoma technology; positive cells were found by ELISA enabling the detection of antibody concentrations as low as 3 ng/ml. The MoABs were purified from both culture supernatant and ascites fluid by ion exchange and protein-A affinity chromatography. Western blotting determined that CS-1 is specific for nonreduced GP IIIa but not reduced GP IIIa or any form of GP IIb. CS-1 inhibited binding of radiolabeled FGN to ADP-stimulated platelets by 40-50% over a concentration range of 5-70 ..mu..g/ml. Flow cytometric analysis confirmed that CS-1 recognized a protein on the surface of both resting and stimulated platelets. The determined specificity of CS-1 and its limited ability to inhibit FGN binding to platelets make this MoAB useful for analysis of the structural and functional relationships between fibrin(ogen) and GP IIb-IIIa.

  12. Electrolysis of uranium nitride containing fission product elements (Mo, Pd, Nd) in a molten LiCl-KCl eutectic

    SciTech Connect (OSTI)

    Satoh, Takumi; Iwai, Takashi; Arai, Yasuo

    2007-07-01

    The electrolysis of burnup-simulated uranium nitride, UN, containing representative solid fission product elements (Mo, Pd, Nd) was investigated in the molten LiCl-KCl eutectic salt with 0.54 wt% UCl{sub 3} from the view point of application of pyrochemical reprocessing to nitride fuel cycle. It was found from cyclic voltammetry and anodic polarization curve measurement that anodic dissolution of UN began at about -0.75 V vs. Ag/AgCl reference electrode in all samples. After the electrolysis at the constant anodic potential of -0.65 {approx} -0.60 V vs. Ag/AgCl, most of UN was dissolved into LiCl- KCl as UCl{sub 3} at the anode, and U was recovered in the liquid Cd cathode in all samples. Further, Nd was dissolved into LiCl-KCl as NdCl{sub 3}, while Mo and Pd were not dissolved but remained at the anode. (authors)

  13. Efficient Interlayer Relaxation and Transition of Excitons in Epitaxial and Non-epitaxial MoS2/WS2 Heterostructures

    SciTech Connect (OSTI)

    Yu, Yifei; Hu, Shi; Su, Liqin; Huang, Lujun; Liu, Yi; Jin, Zhenghe; Puretzky, Alexander A; Geohegan, David B; Kim, Ki Wook; Zhang, Yong; Cao, Linyou

    2014-01-01

    Semiconductor heterostructurs provide a powerful platform for the engineering of excitons. Here we report on the excitonic properties of two-dimensional (2D) heterostructures that consist of monolayer MoS2 and WS2 stacked epitaxially or non-epitaxially in the vertical direction. We find similarly efficient interlayer relaxation and transition of excitons in both the epitaxial and non-epitaxial heterostructures. This is manifested by a two orders of magnitude decrease in the photoluminescence and an extra absorption peak at low energy region of both heterostructures. The MoS2/WS2 heterostructures show weak interlayer coupling and essentially act as an atomic-scale heterojunction with the intrinsic band structures of the two monolayers largely preserved. They are particularly promising for the applications that request efficient dissociation of excitons and strong light absorption, including photovoltaics, solar fuels, photodetectors, and optical modulators. Our results also indicate that 2D heterostructures promise to provide capabilities to engineer excitons from the atomic level without concerns of interfacial imperfection.

  14. Density functional theory study of chemical sensing on surfaces of single-layer MoS{sub 2} and graphene

    SciTech Connect (OSTI)

    Mehmood, F.; Pachter, R.

    2014-04-28

    In this work, density functional theory (DFT) calculations have been used to investigate chemical sensing on surfaces of single-layer MoS{sub 2} and graphene, considering the adsorption of the chemical compounds triethylamine, acetone, tetrahydrofuran, methanol, 2,4,6-trinitrotoluene, o-nitrotoluene, o-dichlorobenzene, and 1,5-dicholoropentane. Physisorption of the adsorbates on free-standing surfaces was analyzed in detail for optimized material structures, considering various possible adsorption sites. Similar adsorption characteristics for the two surface types were demonstrated, where inclusion of a correction to the DFT functional for London dispersion was shown to be important to capture interactions at the interface of molecular adsorbate and surface. Charge transfer analyses for adsorbed free-standing surfaces generally demonstrated very small effects. However, charge transfer upon inclusion of the underlying SiO{sub 2} substrate rationalized experimental observations for some of the adsorbates considered. A larger intrinsic response for the electron-donor triethylamine adsorbed on MoS{sub 2} as compared to graphene was demonstrated, which may assist in devising chemical sensors for improved sensitivity.

  15. Update On The Development, Testing, And Manufacture Of High Density LEU-Foil Targets For The Production Of Mo-99

    SciTech Connect (OSTI)

    Creasy, John T

    2015-05-12

    This project has the objective to reduce and/or eliminate the use of HEU in commerce. Steps in the process include developing a target testing methodology that is bounding for all Mo-99 target irradiators, establishing a maximum target LEU-foil mass, developing a LEU-foil target qualification document, developing a bounding target failure analysis methodology (failure in reactor containment), optimizing safety vs. economics (goal is to manufacture a safe, but relatively inexpensive target to offset the inherent economic disadvantage of using LEU in place of HEU), and developing target material specifications and manufacturing QC test criteria. The slide presentation is organized under the following topics: Objective, Process Overview, Background, Team Structure, Key Achievements, Experiment and Activity Descriptions, and Conclusions. The High Density Target project has demonstrated: approx. 50 targets irradiated through domestic and international partners; proof of concept for two front end processing methods; fabrication of uranium foils for target manufacture; quality control procedures and steps for manufacture; multiple target assembly techniques; multiple target disassembly devices; welding of targets; thermal, hydraulic, and mechanical modeling; robust target assembly parametric studies; and target qualification analysis for insertion into very high flux environment. The High Density Target project has tested and proven several technologies that will benefit current and future Mo-99 producers.

  16. Electrical characteristics of multilayer MoS{sub 2} transistors at real operating temperatures with different ambient conditions

    SciTech Connect (OSTI)

    Kwon, Hyuk-Jun; Grigoropoulos, Costas P.; Jang, Jaewon Subramanian, Vivek; Kim, Sunkook

    2014-10-13

    Atomically thin, two-dimensional (2D) materials with bandgaps have attracted increasing research interest due to their promising electronic properties. Here, we investigate carrier transport and the impact of the operating ambient conditions on back-gated multilayer MoS{sub 2} field-effect transistors with a thickness of ?50?nm at their realistic working temperatures and under different ambient conditions (in air and in a vacuum of ?10{sup ?5}?Torr). Increases in temperature cause increases in I{sub min} (likely due to thermionic emission at defects), and result in decreased I{sub on} at high V{sub G} (likely due to increased phonon scattering). Thus, the I{sub on}/I{sub min} ratio decreases as the temperature increases. Moreover, the ambient effects with working temperatures on field effect mobilities were investigated. The adsorbed oxygen and water created more defect sites or impurities in the MoS{sub 2} channel, which can lead another scattering of the carriers. In air, the adsorbed molecules and phonon scattering caused a reduction of the field effect mobility, significantly. These channel mobility drop-off rates in air and in a vacuum reached 0.12?cm{sup 2}/V s K and 0.07?cm{sup 2}/V s K, respectively; the rate of degradation is steeper in air than in a vacuum due to enhanced phonon mode by the adsorbed oxygen and water molecules.

  17. Efficient Interlayer Relaxation and Transition of Excitons in Epitaxial and Non-epitaxial MoS2/WS2 Heterostructures

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yu, Yifei; Hu, Shi; Su, Liqin; Huang, Lujun; Liu, Yi; Jin, Zhenghe; Puretzky, Alexander A; Geohegan, David B; Kim, Ki Wook; Zhang, Yong; et al

    2014-01-01

    Semiconductor heterostructurs provide a powerful platform for the engineering of excitons. Here we report on the excitonic properties of two-dimensional (2D) heterostructures that consist of monolayer MoS2 and WS2 stacked epitaxially or non-epitaxially in the vertical direction. We find similarly efficient interlayer relaxation and transition of excitons in both the epitaxial and non-epitaxial heterostructures. This is manifested by a two orders of magnitude decrease in the photoluminescence and an extra absorption peak at low energy region of both heterostructures. The MoS2/WS2 heterostructures show weak interlayer coupling and essentially act as an atomic-scale heterojunction with the intrinsic band structures of themore » two monolayers largely preserved. They are particularly promising for the applications that request efficient dissociation of excitons and strong light absorption, including photovoltaics, solar fuels, photodetectors, and optical modulators. Our results also indicate that 2D heterostructures promise to provide capabilities to engineer excitons from the atomic level without concerns of interfacial imperfection.« less

  18. Thermal expansion of Cr{sub 2x}Fe{sub 2-2x}Mo{sub 3}O{sub 12}, Al{sub 2x}Fe{sub 2-2x}Mo{sub 3}O{sub 12} and Al{sub 2x}Cr{sub 2-2x}Mo{sub 3}O{sub 12} solid solutions

    SciTech Connect (OSTI)

    Ari, M.; Jardim, P.M.; Marinkovic, B.A. Rizzo, F.; Ferreira, F.F.

    2008-06-15

    The transition temperature from monoclinic to orthorhombic and the thermal expansion of the orthorhombic phase were investigated for three systems of the family A{sub 2}M{sub 3}O{sub 12}: Cr{sub 2x}Fe{sub 2-2x}Mo{sub 3}O{sub 12}, Al{sub 2x}Fe{sub 2-2x}Mo{sub 3}O{sub 12} and Al{sub 2x}Cr{sub 2-2x}Mo{sub 3}O{sub 12}. It was possible to obtain a single-phase solid solution in all studied samples (x=0, 0.1, 0.3, 0.5, 0.7, 0.9 and 1). A linear relationship between the transition temperature and the fraction of A{sup 3+} cations (x) was observed for each system. In all orthorhombic solid solutions studied here the observed thermal expansion was anisotropic. These anisotropic thermal expansion properties of crystallographic axes a, b and c result in a low positive or near-zero overall linear coefficient of thermal expansion ({alpha}{sub l}={alpha}{sub V}/3). The relationship between the size of A{sup 3+} cations in A{sub 2}M{sub 3}O{sub 12} and the coefficient of thermal expansion is discussed. Near-zero thermal expansion of Cr{sub 2}Mo{sub 3}O{sub 12} is explained by the behavior of Cr-O and Mo-O bond distances, Cr-Mo non-bond distances and Cr-O-Mo bond angles with increasing temperature, estimated by Rietveld analysis of synchrotron X-ray powder diffraction data. - Graphical abstract: In this figure, all published overall linear coefficients of thermal expansion for orthorhombic A{sub 2}M{sub 3}O{sub 12} family obtained through diffraction methods as a function of A{sup 3+} cation radii size, together with dilatometric results, are plotted. Our results indicate that Cr{sub 2}Mo{sub 3}O{sub 12} does not exactly follow the established relationship.

  19. Demonstration of femtosecond laser ablation inductively coupled plasma mass spectrometry for uranium isotopic measurements in U-10Mo nuclear fuel foils

    SciTech Connect (OSTI)

    Havrilla, George Joseph; Gonzalez, Jhanis

    2015-06-10

    The use of femtosecond laser ablation inductively coupled plasma mass spectrometry was used to demonstrate the feasibility of measuring the isotopic ratio of uranium directly in U-10Mo fuel foils. The measurements were done on both the flat surface and cross sections of bare and Zr clad U-10Mo fuel foil samples. The results for the depleted uranium content measurements were less than 10% of the accepted U235/238 ratio of 0.0020. Sampling was demonstrated for line scans and elemental mapping over large areas. In addition to the U isotopic ratio measurement, the Zr thickness could be measured as well as trace elemental composition if required. A number of interesting features were observed during the feasibility measurements which could provide the basis for further investigation using this methodology. The results demonstrate the feasibility of using fs-LA-ICP-MS for measuring the U isotopic ratio in U-10Mo fuel foils.

  20. State Technologies Advancement Collaborative

    SciTech Connect (OSTI)

    David S. Terry

    2012-01-30

    The U. S. Department of Energy (DOE), National Association of State Energy Officials (NASEO), and Association of State Energy Research and Technology Transfer Institutions (ASERTTI) signed an intergovernmental agreement on November 14, 2002, that allowed states and territories and the Federal Government to better collaborate on energy research, development, demonstration and deployment (RDD&D) projects. The agreement established the State Technologies Advancement Collaborative (STAC) which allowed the states and DOE to move RDD&D forward using an innovative competitive project selection and funding process. A cooperative agreement between DOE and NASEO served as the contracting instrument for this innovative federal-state partnership obligating funds from DOE's Office of Energy Efficiency and Renewable Energy and Office of Fossil Energy to plan, fund, and implement RDD&D projects that were consistent with the common priorities of the states and DOE. DOE's Golden Field Office provided Federal oversight and guidance for the STAC cooperative agreement. The STAC program was built on the foundation of prior Federal-State efforts to collaborate on and engage in joint planning for RDD&D. Although STAC builds on existing, successful programs, it is important to note that it was not intended to replace other successful joint DOE/State initiatives such as the State Energy Program or EERE Special Projects. Overall the STAC process was used to fund, through three competitive solicitations, 35 successful multi-state research, development, deployment, and demonstration projects with an overall average non-federal cost share of 43%. Twenty-two states were awarded at least one prime contract, and organizations in all 50 states and some territories were involved as subcontractors in at least one STAC project. Projects were funded in seven program areas: (1) Building Technologies, (2) Industrial Technologies, (3) Transportation Technologies, (4) Distributed Energy Resources, (5) Hydrogen Technology Learning Centers, (6) Fossil Energy, and (7) Rebuild America.

  1. State and Local Code Implementation: State Energy Officials ...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    State and Local Code Implementation: State Energy Officials - 2014 BTO Peer Review Presenter: Chris Wagner, National Association of State Energy Officials View the Presentation PDF ...

  2. Nevada State Air Regulations and State Implementation Plan Webpage...

    Open Energy Info (EERE)

    in Nevada and its state implementation plan. Author State of Nevada Division of Environmental Protection Published State of Nevada, Date Not Provided DOI Not Provided...

  3. Solid-State Lighting

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... HomeSolid-State Lighting Permalink ECIS-Veeco: Research Driving Down the Costs of Efficient LED Lighting Energy, Energy Efficiency, Materials Science, Partnership, Research & ...

  4. United States Government

    Office of Legacy Management (LM)

    OR Ohio State Uuiversity, Columbus, OH (*) Stauffer Tenescal Co., Richmond, CA Tocco Induction Heating Division, Cleveland, OH Utica Drop Forge & Tool Co., Utica, NY Tltaniua...

  5. State Energy Strategic Planning

    Broader source: Energy.gov [DOE]

    U.S. Department of Energy (DOE) Technical Assistance Program (TAP) presentation at a TAP webinar held on April 3, 2013 and dealing with state energy strategic planning.

  6. By Coal Destination State

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    California (thousand short tons) Coal Origin State Transportation Mode Electric Power Sector Coke Plants Industrial Plants (excluding Coke) Commercial & Institutional Total...

  7. Appalachian State | Open Energy Information

    Open Energy Info (EERE)

    Appalachian State Jump to: navigation, search Name Appalachian State Facility Appalachian State Sector Wind energy Facility Type Small Scale Wind Facility Status In Service...

  8. Energy Standards for State Agencies

    Broader source: Energy.gov [DOE]

    State departments and agencies are encouraged to employ the latest energy-conservation practices in the design, construction, renovation, operation and maintenance of state facilities. All state ...

  9. Solid State Division

    SciTech Connect (OSTI)

    Green, P.H.; Watson, D.M.

    1989-08-01

    This report contains brief discussions on work done in the Solid State Division of Oak Ridge National Laboratory. The topics covered are: Theoretical Solid State Physics; Neutron scattering; Physical properties of materials; The synthesis and characterization of materials; Ion beam and laser processing; and Structure of solids and surfaces. (LSP)

  10. State Fact Sheets

    Broader source: Energy.gov [DOE]

    The U.S. Department of Energy provides joint funding to university, national laboratory, and industrial partners at the state level to research, develop, and demonstrate sustainable bio-based fuels and products. Learn how these states are expanding promising bioenergy research into commercial production.

  11. Grid State Estimation Tool

    Energy Science and Technology Software Center (OSTI)

    2014-10-09

    This software code is designed to track generator state variables in real time using the Ensemble Kalman Filter method with the aid of PMU measurements. This code can also be used to calibrate dynamic model parameters by augmenting parameters in the state variable vector.

  12. Reaction-bonding preparation of Si{sub 3}N{sub 4}/MoSi{sub 2} and Si{sub 3}N{sub 4}/WSi{sub 2} composites from elemental powders

    SciTech Connect (OSTI)

    Zhang, B.R.; Marino, F.

    1997-01-01

    Si{sub 3}N{sub 4}/MoSi{sub 2} and Si{sub 3}N{sub 4}/WSi{sub 2} composites were prepared by reaction-bonding processes using as starting materials powder mixtures of Si-Mo and Si-W, respectively. A presintering step in an Ar-base atmosphere was used before nitriding for the formation of MoSi{sub 2} and WSi{sub 2}; the nitridation in a N{sub 2}-base atmosphere was followed after presintering with the total stepwise cycle of 1,350 C {times} 20 h + 1,400 C {times} 20 h + 1,450 C {times} 2 h. The final phases obtained in the two different composites were Si{sub 3}N{sub 4} and MoSi{sub 2} or WSi{sub 2}; no free elemental Si and Mo or W were detected by X-ray diffraction.

  13. State of the States 2009: Renewable Energy Development and the...

    Open Energy Info (EERE)

    manual, Lessons learnedbest practices Website: www.nrel.govapplyingtechnologiesstatelocalactivitieswebinar2009 State of the States 2009: Renewable Energy Development and...

  14. State of the States: Fuel Cells in America 2012

    Broader source: Energy.gov [DOE]

    This report from Fuel Cells 2000 describes the state of fuel cell technologies across the United States.

  15. Formation of BaSi{sub 2} heterojunction solar cells using transparent MoO{sub x} hole transport layers

    SciTech Connect (OSTI)

    Du, W.; Takabe, R.; Baba, M.; Takeuchi, H.; Toko, K.; Hara, K. O.; Usami, N.; Suemasu, T.

    2015-03-23

    Heterojunction solar cells that consist of 15?nm thick molybdenum trioxide (MoO{sub x}, x?

  16. Microstructure investigation of 13Cr-2Mo ODS steel components obtained by high voltage electric discharge compaction technique

    SciTech Connect (OSTI)

    Bogachev, Igor; Yudin, Artem; Grigoryev, Evgeniy; Chernov, Ivan; Staltsov, Maxim; Khasanov, Oleg; Olevsky, Eugene

    2015-11-02

    Refractory oxide dispersion strengthened 13Cr-2Mo steel powder was successfully consolidated to near theoretical density using high voltage electric discharge compaction. Cylindrical samples with relative density from 90% to 97% and dimensions of 10 mm in diameter and 10–15 mm in height were obtained. Consolidation conditions such as pressure and voltage were varied in some ranges to determine the optimal compaction regime. Three different concentrations of yttria were used to identify its effect on the properties of the samples. It is shown that the utilized ultra-rapid consolidation process in combination with high transmitted energy allows obtaining high density compacts, retaining the initial structure with minimal grain growth. The experimental results indicate some heterogeneity of the structure which may occur in the external layers of the tested samples due to various thermal and electromagnetic in-processing effects. As a result, the choice of the optimal parameters of the consolidation enables obtaining samples of acceptable quality.

  17. Irradiation behavior of the interaction product of U-Mo fuel particle dispersion in an Al matrix.

    SciTech Connect (OSTI)

    Kim, Y.S.; Hofman, G. (Nuclear Engineering Division)

    2012-06-01

    Irradiation performance of U-Mo fuel particles dispersed in Al matrix is stable in terms of fuel swelling and is suitable for the conversion of research and test reactors from highly enriched uranium (HEU) to low enriched uranium (LEU). However, tests of the fuel at high temperatures and high burnups revealed obstacles caused by the interaction layers forming between the fuel particle and matrix. In some cases, fission gas filled pores grow and interconnect in the interdiffusion layer resulting in fuel plate failure. Postirradiation observations are made to examine the behavior of the interdiffusion layers. The interdiffusion layers show a fluid-like behavior characteristic of amorphous materials. In the amorphous interdiffusion layers, fission gas diffusivity is high and the material viscosity is low so that the fission gas pores readily form and grow. Based on the observations, a pore formation mechanism is proposed and potential remedies to suppress the pore growth are also introduced.

  18. Scanning Electron Microscopy Analysis of Fuel/Matrix Interaction Layers in Highly-Irradiated UMo Dispersion Fuel Plates with Al and AlSi Alloy Matrices

    SciTech Connect (OSTI)

    Dennis D. Keiser, Jr.; Jan-Fong Jue; Brandon D. Miller; Jian Gan; Adam B. Robinson; Pavel Medvedev; James Madden; Dan Wachs; Mitch Meyer

    2014-04-01

    In order to investigate how the microstructure of fuel/matrix-interaction (FMI) layers change during irradiation, different U7Mo dispersion fuel plates have been irradiated to high fission density and then characterized using scanning electron microscopy (SEM). Specifially, samples from irradiated U7Mo dispersion fuel elements with pure Al, Al2Si and AA4043 (~4.5 wt.%Si) matrices were SEM characterized using polished samples and samples that were prepared with a focused ion beam (FIB). Features not observable for the polished samples could be captured in SEM images taken of the FIB samples. For the Al matrix sample, a relatively large FMI layer develops, with enrichment of Xe at the FMI layer/Al matrix interface and evidence of debonding. Overall, a significant penetration of Si from the FMI layer into the U7Mo fuel was observed for samples with Si in the Al matrix, which resulted in a change of the size (larger) and shape (round) of the fission-gas bubbles. Additionally, solid-fission-product phases were observed to nucleate and grow within these bubbles. These changes in the localized regions of the microstructure of the U7Mo may contribute to changes observed in the macroscopic swelling of fuel plates with AlSi matrices.

  19. Effects of the solvent on the structure, morphology and photocatalytic properties of Bi{sub 2}MoO{sub 6} in the solvothermal process

    SciTech Connect (OSTI)

    Bi, Jinhong; Che, Jiangang; Wu, Ling; Liu, Minghua

    2013-06-01

    Graphical abstract: Various nanostructure Bi{sub 2}MoO{sub 6} photocatalysts have been prepared by a solvothermal process via simply altering the used solvent. It is revealed that the type of solvents has a strong influence on the morphology of Bi{sub 2}MoO{sub 6}. This could be understood in terms of the reaction media effect on the crystal growth. The photocatalytic experiments for the decomposition of RhB demonstrate that the samples prepared by different solvents show different photocatalytic activity. The highest photocatalytic activity is obtained by the sample with glycol as solvent. Highlights: ? The used solvent in the synthesis can affect the morphology and size of Bi{sub 2}MoO{sub 6}. ? Different solvent in the reaction leads to different surface area and pore size. ? The highest photocatalytic activity is obtained by the sample prepared in glycol. ? The high activity is mainly due to the large surface area and small particle size. - Abstract: Visible-light-driven photocatalyst Bi{sub 2}MoO{sub 6} was prepared by a solvothermal process with different kinds of solvent including water, isopropanol and ethylene glycol. The obtained samples were characterized by X-ray diffraction technique, N{sub 2}-sorption, UVvis diffuse reflectance spectra, transmission electron microscopy and Fourier transform infrared spectroscopy. The results revealed that the type of solvent has a strong influence on the morphologies and physico-chemical properties of Bi{sub 2}MoO{sub 6}. Meanwhile, the formation mechanism of Bi{sub 2}MoO{sub 6} with various morphologies was discussed. The photocatalytic activities of Bi{sub 2}MoO{sub 6} photocatalysts were evaluated by the decomposition of rhodamine B (RhB) under visible light irradiation (? > 420 nm). It was found that the sample prepared with glycol as solvent showed the best performance in the photodegradation of RhB under visible light irradiation. This could be ascribed to the large surface area, unique morphology and small particle size.

  20. Multichannel 0<mo stretchy='false'>?mo>2 and 1<mo stretchy='false'>?mo>2 transition amplitudes for arbitrary spin particles in a finite volume

    SciTech Connect (OSTI)

    Hansen, Maxwell; Briceno, Raul

    2015-10-01

    We present a model-independent, non-perturbative relation between finite-volume matrix elements and infinite-volume $\\textbf{0}\\rightarrow\\textbf{2}$ and $\\textbf{1}\\rightarrow\\textbf{2}$ transition amplitudes. Our result accommodates theories in which the final two-particle state is coupled to any number of other two-body channels, with all angular momentum states included. The derivation uses generic, fully relativistic field theory, and is exact up to exponentially suppressed corrections in the lightest particle mass times the box size. This work distinguishes itself from previous studies by accommodating particles with any intrinsic spin. To illustrate the utility of our general result, we discuss how it can be implemented for studies of $N+\\mathcal{J}~\\rightarrow~(N\\pi,N\\eta,N\\eta',\\Sigma K,\\Lambda K)$ transitions, where $\\mathcal{J}$ is a generic external current. The reduction of rotational symmetry, due to the cubic finite volume, manifests in this example through the mixing of S- and P-waves when the system has nonzero total momentum.

  1. Multipartite secure state distribution

    SciTech Connect (OSTI)

    Duer, W.; Briegel, H.-J.; Calsamiglia, J.

    2005-04-01

    We introduce the distribution of a secret multipartite entangled state in a real-world scenario as a quantum primitive. We show that in the presence of noisy quantum channels (and noisy control operations), any state chosen from the set of two-colorable graph states (Calderbank-Shor-Steane codewords) can be created with high fidelity while it remains unknown to all parties. This is accomplished by either blind multipartite entanglement purification, which we introduce in this paper, or by multipartite entanglement purification of enlarged states, which offers advantages over an alternative scheme based on standard channel purification and teleportation. The parties are thus provided with a secret resource of their choice for distributed secure applications.

  2. By Coal Destination State

    U.S. Energy Information Administration (EIA) Indexed Site

    Destination State ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ U.S. Energy Information Administration | Quarterly Coal Distribution Report 1st Quarter 2012 U.S. Energy Information Administration | Quarterly Coal Distribution Report 1st Quarter 2012 Alabama _____________________________________________________________________________________________________________________________________ Table DS-1. Domestic coal

  3. By Coal Origin State

    U.S. Energy Information Administration (EIA) Indexed Site

    Origin State ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ U.S. Energy Information Administration | Quarterly Coal Distribution Report 1st Quarter 2012 U.S. Energy Information Administration | Quarterly Coal Distribution Report 1st Quarter 2012 Alabama ___________________________________________________________________________________________________________________________________ Table OS-1. Domestic coal

  4. State Biomass Contacts

    Broader source: Energy.gov [DOE]

    Most state governments have designated contacts for biomass conversion programs. The following contacts used by the Bioenergy Technologies Office may also be good contacts for you to find out about...

  5. United States Government

    Office of Environmental Management (EM)

    States Government Department of Energy memorandum Carlsbad Field Office Carlsbad, New Mexico 88221 DATE: REPLY TO ATTN OF: SUBJECT: JAN 1 7 2014 CBFO:OESH:GTB:MN:14-1404:UFC...

  6. Distribution System State Estimation

    Office of Scientific and Technical Information (OSTI)

    This Notice shall be affixed to any reproductions of these data in whole or in part. Executive Summary State estimation is a key enabler for any number of "smart grid" applications ...

  7. State Nuclear Profiles 2010

    Gasoline and Diesel Fuel Update (EIA)

    Primary energy source Summer capacity (mw) Share of State total (percent) Net generation ... Station Unit 1, Unit 2 2,330 19,200 20.0 Exelon Nuclear Byron Generating Station Unit 1, ...

  8. State Nuclear Profiles 2010

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Primary energy source Summer capacity (mw) Share of State total (percent) Net generation ... Limerick Unit 1, Unit 2 2,264 18,926 24.3 Exelon Nuclear PPL Susquehanna Unit 1, Unit 2 ...

  9. State Nuclear Profiles 2010

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Share of State total (percent) Net generation (thousand mwh) New Jersey nuclear power plants, summer capacity and net generation, 2010 Oyster Creek Unit 1 615 4,601 14.0 Exelon ...

  10. NetState

    Energy Science and Technology Software Center (OSTI)

    2005-09-01

    NetState is a distributed network monitoring system. It uses passive sensors to develop status information on a target network. Two major features provided by NetState are version and port tracking. Version tracking maintains information about software and operating systems versions. Port tracking identifies information about active TOP and UDP ports. Multiple NetState sniffers can be deployed, one at each entry point of the target network. The sniffers monitor network traffic, then send the information tomore » the NetState server. The information is stored in centralized database which can then be accessed via standard SQL database queries or this web-based GUI, for further analysis and display.« less

  11. United States Government

    Office of Legacy Management (LM)

    81278 United States Government Department of Energy memorandum - ?71 S.EP 23 F; i: 54 DATE: SEP 1 8 1991 REPLY TO ATTNOF: EM-421 (P. Blom, 3-8148) SUBJECT: Approved Categorical...

  12. FY 2006 State Table

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    State Tables Preliminary Department of Energy FY 2006 Congressional Budget Request Office of Management, Budget and Evaluation/CFO February 2005 State Tables Preliminary Printed with soy ink on recycled paper The numbers depicted in this document represent the gross level of DOE budget authority for the years displayed. The figures include both the discretionary and mandatory funding in the budget. They do not consider revenues/receipts, uses of prior year balances, deferrals, rescissions, or

  13. FY 2007 State Table

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    state tables preliminary Department of Energy FY 2007 Congressional Budget Request February 2006 Printed with soy ink on recycled paper Office of Chief Financial Officer state tables preliminary The numbers depicted in this document represent the gross level of DOE budget authority for the years displayed. The figures include both the discretionary and mandatory funding in the budget. They do not consider revenues/receipts, uses of prior year balances, deferrals, rescissions, or other

  14. FY 2008 State Table

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    State Table Preliminary Department of Energy FY 2008 Congressional Budget Request February 2007 Office of Chief Financial Officer State Table Preliminary Printed with soy ink on recycled paper The numbers depicted in this document represent the gross level of DOE budget authority for the years displayed. The figures include both the discretionary and mandatory funding in the budget. They do not consider revenues/receipts, uses of prior year balances, deferrals, rescissions, or other adjustments

  15. FY 2009 State Table

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    State Tables Preliminary February 2008 Office of Chief Financial Officer Department of Energy FY 2009 Congressional Budget Request State Tables Preliminary The numbers depicted in this document represent the gross level of DOE budget authority for the years displayed. The figures include both the discretionary and mandatory funding in the budget. They do not consider revenues/receipts, use of prior year balances, deferrals, rescissions, or other adjustments appropriated as offsets to the DOE

  16. FY 2010 State Table

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    State Tables Preliminary May 2009 Office of Chief Financial Officer FY 2010 Congressional Budget Request State Tables Preliminary The numbers depicted in this document represent the gross level of DOE budget authority for the years displayed. The figures include both the discretionary and mandatory funding in the budget. They do not consider revenues/receipts, use of prior year balances, deferrals, rescissions, or other adjustments appropriated as offsets to the DOE appropriations by the

  17. FY 2011 State Table

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    State Tables Department of Energy FY 2011 Congressional Budget Request DOE/CF-0054 March 2010 Office of Chief Financial Officer State Tables Printed with soy ink on recycled paper The numbers depicted in this document represent the gross level of DOE budget authority for the years displayed. The figures include both the discretionary and mandatory funding in the budget. They do not consider revenues/receipts, use of prior year balances, deferrals, rescissions, or other adjustments appropriated

  18. FY 2012 State Table

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    6 Department of Energy FY 2012 Congressional Budget Request State Tables P li i Preliminary February 2012 Office of Chief Financial Officer DOE/CF-0066 Department of Energy FY 2012 Congressional Budget Request State Tables P li i Preliminary The numbers depicted in this document represent the gross level of DOE budget authority for the years displayed. The figures include both the discretionary and mandatory funding in the budget. They displayed. The figures include both the discretionary and

  19. FY 2013 State Table

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    9 Department of Energy FY 2013 Congressional Budget Request State Tables P li i Preliminary February 2012 Office of Chief Financial Officer DOE/CF-0079 Department of Energy FY 2013 Congressional Budget Request State Tables P li i Preliminary The numbers depicted in this document represent the gross level of DOE budget authority for the years displayed. The figures include both the discretionary and mandatory funding in the budget. They displayed. The figures include both the discretionary and

  20. Solid state switch

    DOE Patents [OSTI]

    Merritt, Bernard T.; Dreifuerst, Gary R.

    1994-01-01

    A solid state switch, with reverse conducting thyristors, is designed to operate at 20 kV hold-off voltage, 1500 A peak, 1.0 .mu.s pulsewidth, and 4500 pps, to replace thyratrons. The solid state switch is more reliable, more economical, and more easily repaired. The switch includes a stack of circuit card assemblies, a magnetic assist and a trigger chassis. Each circuit card assembly contains a reverse conducting thyristor, a resistor capacitor network, and triggering circuitry.

  1. State of the Lab!

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (Conference) | SciTech Connect State of the Art for Autonomous Detection Systems using Genomic Sequencing Citation Details In-Document Search Title: State of the Art for Autonomous Detection Systems using Genomic Sequencing Authors: Detter, John C. [1] + Show Author Affiliations Los Alamos National Laboratory Publication Date: 2013-07-09 OSTI Identifier: 1087610 Report Number(s): LA-UR-13-25114 DOE Contract Number: AC52-06NA25396 Resource Type: Conference Resource Relation: Conference: DHS

  2. State Energy Finance Programs

    Office of Environmental Management (EM)

    Startup America Policy Challenge: Clean Energy Startup America Policy Challenge: Clean Energy December 15, 2011 - 12:05pm Addthis The Startup America Policy Challenge wants your ideas on how we can accelerate innovation in clean energy and position the United States to lead in this critical sector. | Photo Courtesy of JBEI. The Startup America Policy Challenge wants your ideas on how we can accelerate innovation in clean energy and position the United States to lead in this critical sector. |

  3. Modelling of arc jet plasma flow in transitional regime by Navier Stokes and state-to-state coupling

    SciTech Connect (OSTI)

    Alexandrova, T.; Izrar, B.; Lino da Silva, M.; Dudeck, M.

    2005-05-16

    The combination of 2D Navier-Stokes and state-to-state approaches has been used to describe the air plasma flow in an arc-jet. The gas dynamic parameters were calculated in Navier-Stokes approximation in a steady state description without chemical reaction and vibrational exchanges. And then, the set of equations of vibrational level densities and atomic species densities was locally solved. Experimental validations have been performed.

  4. Radiative return capabilities of a high-energy, high-luminositye<mo>+mo>e<mo>->collider

    SciTech Connect (OSTI)

    Karliner, Marek; Low, Matthew; Rosner, Jonathan L.; Wang, Lian-Tao

    2015-08-14

    An electron-positron collider operating at a center-of-mass energy ECM can collect events at all lower energies through initial-state radiation (ISR or radiative return). We explore the capabilities for radiative return studies by a proposed high-luminosity collider at ECM = 250 or 90 GeV, to fill in gaps left by lower-energy colliders such as PEP, PETRA, TRISTAN, and LEP. These capabilities are compared with those of the lower-energy e+e- colliders as well as hadron colliders such as the Tevatron and the CERN Large Hadron Collider (LHC). Some examples of accessible questions in dark photon searches and heavy flavor spectroscopy are given.

  5. Negative Ion Photoelectron Spectroscopy Confirms the Prediction that D-3h Carbontrioxide (CO3) Has a Singlet Ground State

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Hrovat, David; Hou, Gao-Lei; Chen, Bo; Wang, Xue B.; Borden, Weston

    2015-11-13

    The CO3 radical anion (CO3•–) has been formed by electrospraying carbonate dianion (CO32–) into the gas phase. The negative ion photoelectron (NIPE) spectrum of CO3•– shows that, unlike trimethylenemethane [C(CH2)3], carbontrioxide (CO3) has a singlet ground state. From the NIPE spectrum, the electron affinity of CO3 was determined to be EA = 4.06 ± 0.03 eV, and the singlet-triplet energy difference was found to be ΔEST = - 17.8 ± 0.9 kcal/mol. B3LYP, CCSD(T), and CASPT2 calculations all find that the two lowest triplet states of CO3 are very close in energy, a prediction that is confirmed by the relativemore » intensities of the bands in the NIPE spectrum of CO3•–. The 560 cm-1 vibrational progression, seen in the low energy region of the triplet band, enables the identification of the lowest, Jahn-Teller-distorted, triplet state as 3A1, in which both unpaired electrons reside in σ MOs, rather than 3A2, in which one unpaired electron occupies the b2 σ MO, and the other occupies the b1 π MO.« less

  6. EIA - State Nuclear Profiles

    U.S. Energy Information Administration (EIA) Indexed Site

    Vermont profile Vermont total electric power industry, summer capacity and net generation, by energy source, 2010 Primary energy source Summer capacity (mw) Share of State total (percent) Net generation (thousand mwh) Share of State total (percent) Nuclear 620 55.0 4,782 72.2 Hydro and Pumped Storage 324 28.7 1,347 20.3 Natural Gas - - 4 0.1 Other Renewable1 84 7.5 482 7.3 Petroleum 100 8.9 5 0.1 Total 1,128 100.0 6,620 100.0 1Municipal Solid Waste net generation is allocated according to the

  7. Solid state switch

    DOE Patents [OSTI]

    Merritt, B.T.; Dreifuerst, G.R.

    1994-07-19

    A solid state switch, with reverse conducting thyristors, is designed to operate at 20 kV hold-off voltage, 1,500 A peak, 1.0 [mu]s pulsewidth, and 4,500 pps, to replace thyratrons. The solid state switch is more reliable, more economical, and more easily repaired. The switch includes a stack of circuit card assemblies, a magnetic assist and a trigger chassis. Each circuit card assembly contains a reverse conducting thyristor, a resistor capacitor network, and triggering circuitry. 6 figs.

  8. United States Government

    Office of Legacy Management (LM)

    f&E F 1325.8 J ;rgy!w, United States Government m e m o randum 7-L 0 cI - 2, Department of Energy I~27 DATE: !-jEC -2 3 1293 REPLY TO ATTN OF: EM-421 (W. A. W illiams, 903-8149) SUBJECT: Elimination of the Sites from the Formerly Utilized Sites Remedial Action Program TO: The F ile I have reviewed the attached site summaries and elimination recommendations for the following sites: f' l M itts & Merrel Co., Saginaw, M ichigan l North Carolina State University, Raleigh, North Carolina l

  9. EIA - State Nuclear Profiles

    Gasoline and Diesel Fuel Update (EIA)

    Vermont profile Vermont total electric power industry, summer capacity and net generation, by energy source, 2010 Primary energy source Summer capacity (mw) Share of State total (percent) Net generation (thousand mwh) Share of State total (percent) Nuclear 620 55.0 4,782 72.2 Hydro and Pumped Storage 324 28.7 1,347 20.3 Natural Gas - - 4 0.1 Other Renewable1 84 7.5 482 7.3 Petroleum 100 8.9 5 0.1 Total 1,128 100.0 6,620 100.0 1Municipal Solid Waste net generation is allocated according to the

  10. EIA - State Electricity Profiles

    Gasoline and Diesel Fuel Update (EIA)

    United States Electricity Profile 2014 Table 1. 2014 Summary statistics (United States) Item Value Primary energy source Coal Net summer capacity (megawatts) 1,068,422 Electric utilities 616,632 IPP & CHP 451,791 Net generation (megawatthours) 4,093,606,005 Electric utilities 2,382,473,495 IPP & CHP 1,711,132,510 Emissions Sulfur Dioxide (short tons) 3,842,005 Nitrogen Oxide (short tons) 2,400,375 Carbon Dioxide (thousand metric tons) 2,160,342 Sulfur Dioxide (lbs/MWh) 1.9 Nitrogen Oxide

  11. MO-B-16A-01: Memorial to Donald D. Tolbert - Memorial Lecture

    SciTech Connect (OSTI)

    Morin, R

    2014-06-15

    The Medical Physics community lost one of its prominent leaders in April, 2013 with the passing of Donald D. Tolbert, PhD. He received his Doctorate at the University of Kansas followed by post Doctoral training at Florida State University and the University of Wisconsin. He was Chief of Radiation Therapy Medical Physics at the University of Wisconsin Hospital for 7 years before relocating to Honolulu Hawaii, where he founded the consulting group Mid-Pacific Medical Physics. Don was a leader in both the AAPM and the ACR, chairing the Professional Council and the Commission on Medical Physics. He was active on the AAPM Board of Directors and a member of the ACR Board of Chancellors. Dr. Tolbert's approach to the difficult problems of the times was admired and respected by colleagues in Medical Physics, Radiation Oncology, and Diagnostic Radiology. He always rose above the heated political rhetoric and led the discussion to higher ground. His wisdom was continually sought to solve complicated problems. Following retirement, he returned to homes in Kansas and Colorado, devoting his time to writing about coping with diabetes and providing support for Seniors in Beloit Kansas. Don is survived by his wife, Mattie, his 3 children and 5 grandchildren. He will be greatly missed.

  12. Blister Threshold Based Thermal Limits for the U-Mo Monolithic Fuel System

    SciTech Connect (OSTI)

    D. M. Wachs; I. Glagolenko; F. J. Rice; A. B. Robinson; B. H. Rabin; M. K. Meyer

    2012-10-01

    Fuel failure is most commonly induced in research and test reactor fuel elements by exposure to an under-cooled or over-power condition that results in the fuel temperature exceeding a critical threshold above which blisters form on the plate. These conditions can be triggered by normal operational transients (i.e. temperature overshoots that may occur during reactor startup or power shifts) or mild upset events (e.g., pump coastdown, small blockages, mis-loading of fuel elements into higher-than-planned power positions, etc.). The rise in temperature has a number of general impacts on the state of a fuel plate that include, for example, stress relaxation in the cladding (due to differential thermal expansion), softening of the cladding, increased mobility of fission gases, and increased fission-gas pressure in pores, all of which can encourage the formation of blisters on the fuel-plate surface. These blisters consist of raised regions on the surface of fuel plates that occur when the cladding plastically deforms in response to fission-gas pressure in large pores in the fuel meat and/or mechanical buckling of the cladding over damaged regions in the fuel meat. The blister temperature threshold decreases with irradiation because the mechanical properties of the fuel plate degrade while under irradiation (due to irradiation damage and fission-product accumulation) and because the fission-gas inventory progressively increases (and, thus, so does the gas pressure in pores).

  13. State Energy Program Helps States Plan and Implement Energy Efficiency |

    Energy Savers [EERE]

    Department of Energy Helps States Plan and Implement Energy Efficiency State Energy Program Helps States Plan and Implement Energy Efficiency The U.S. Department of Energy (DOE) State Energy Program (SEP) provides grants and technical assistance to states and U.S. territories to promote energy conservation and reduce the growth of energy demand in ways that are consistent with national energy goals. PDF icon 48100_weather_sep_fsr3.pdf More Documents & Publications State Energy Program

  14. NREL: State and Local Governments - State Solar Technical Assistance

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    What suite of solar PV policies and finance or incentive programs could be implemented in your state to maximize economic development opportunities? If your state agency implements ...

  15. State Energy Risk Assessment Initiative - State and Regional...

    Broader source: Energy.gov (indexed) [DOE]

    OE is leading a State Energy Risk Assessment Initiative to help States better understand risks to their energy infrastructure so they can be better prepared to make informed...

  16. State Clean Energy Policies Analysis (SCEPA): State Policy and...

    Open Energy Info (EERE)

    Analysis (SCEPA): State Policy and the Pursuit of Renewable Energy Manufacturing Jump to: navigation, search Tool Summary LAUNCH TOOL Name: State Clean Energy Policies Analysis...

  17. State of the States: Fuel Cells in America

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CELLS 2000 STATE OF THE STATES: FUEL CELLS IN AMERICA June 2011 Foreword by Connecticut ... Jennifer Gangi and Elizabeth Delmont of Fuel Cells 2000, an activity of Breakthrough ...

  18. EVALUATION OF U10MO FUEL PLATE IRRADIATION BEHAVIOR VIA NUMERICAL AND EXPERIMENTAL BENCHMARKING

    SciTech Connect (OSTI)

    Samuel J. Miller; Hakan Ozaltun

    2012-11-01

    This article analyzes dimensional changes due to irradiation of monolithic plate-type nuclear fuel and compares results with finite element analysis of the plates during fabrication and irradiation. Monolithic fuel plates tested in the Advanced Test Reactor (ATR) at Idaho National Lab (INL) are being used to benchmark proposed fuel performance for several high power research reactors. Post-irradiation metallographic images of plates sectioned at the midpoint were analyzed to determine dimensional changes of the fuel and the cladding response. A constitutive model of the fabrication process and irradiation behavior of the tested plates was developed using the general purpose commercial finite element analysis package, Abaqus. Using calculated burn-up profiles of irradiated plates to model the power distribution and including irradiation behaviors such as swelling and irradiation enhanced creep, model simulations allow analysis of plate parameters that are either impossible or infeasible in an experimental setting. The development and progression of fabrication induced stress concentrations at the plate edges was of primary interest, as these locations have a unique stress profile during irradiation. Additionally, comparison between 2D and 3D models was performed to optimize analysis methodology. In particular, the ability of 2D and 3D models account for out of plane stresses which result in 3-dimensional creep behavior that is a product of these components. Results show that assumptions made in 2D models for the out-of-plane stresses and strains cannot capture the 3-dimensional physics accurately and thus 2D approximations are not computationally accurate. Stress-strain fields are dependent on plate geometry and irradiation conditions, thus, if stress based criteria is used to predict plate behavior (as opposed to material impurities, fine micro-structural defects, or sharp power gradients), unique 3D finite element formulation for each plate is required.

  19. Bluegrass State Getting Greener

    Broader source: Energy.gov [DOE]

    To help reduce Kentucky’s energy appetite, the state set a goal of 25-percent energy reduction by 2025 and is using Recovery Act funding from the U.S. Department of Energy to improve the energy-efficiency of its buildings.

  20. Variational transition state theory

    SciTech Connect (OSTI)

    Truhlar, D.G.

    1993-12-01

    This research program involves the development of variational transition state theory (VTST) and semiclassical tunneling methods for the calculation of gas-phase reaction rates and selected applications. The applications are selected for their fundamental interest and/or their relevance to combustion.

  1. UNITED STATES GOVERNMENT

    Office of Legacy Management (LM)

    Menxmmhmz 9 1 UNITED STATES GOVERNMENT i TO : ThcFFles . mx.f I A. B. Piccct, +3lation section : DATE: .@.eti 16, 1949 SUBJECT: VISIT To HAVY OFfDHAlfCE DEPOT, EARIZ, B.J. FmmlTo...

  2. Recovery Act State Summaries | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Recovery Act State Summaries Recovery Act State Summaries Alabama Recovery Act State Memo Alaska Recovery Act State Memo American Samoa Recovery Act State Memo Arizona Recovery Act ...

  3. STEM HAADF Image Simulation of the Orthorhombic M1 Phase in the Mo-V-Nb-Te-O Propane Oxidation Catalyst

    SciTech Connect (OSTI)

    D Blom; X Li; S Mitra; T Vogt; D Buttrey

    2011-12-31

    A full frozen phonon multislice simulation of high angle annular dark field scanning transmission electron microscopy (HAADF STEM) images from the M1 phase of the Mo-V-Nb-Te-O propane oxidation catalyst has been performed by using the latest structural model obtained using the Rietveld method. Simulated contrast results are compared with experimental HAADF images. Good agreement is observed at ring sites, however significant thickness dependence is noticed at the linking sites. The remaining discrepancies between the model based on Rietveld refinement and image simulations indicate that the sampling of a small volume element in HAADF STEM and averaging elemental contributions of a disordered site in a crystal slab by using the virtual crystal approximation might be problematic, especially if there is preferential Mo/V ordering near the (001) surface.

  4. State authorization manual. Volume 1

    SciTech Connect (OSTI)

    Brugler-Jones, S.

    1990-10-01

    The State Authorization Manual (SAM) (Vol. I) provides guidance for States applying for program revisions to their authorized RCRA State program. The SAM is an updated version of the 1988 State Consolidated RCRA Authorization Manual (SCRAM). It focuses on program revision applications rather than initial applications since most States have received initial authorization for the RCRA program. The SCRAM should continue to be used to assist States not yet authorized under the RCRA program.

  5. Better Catalysts through Microscopy: Nanometer Scale M1/M2 Intergrown Heterostructure in Mo-V-M Complex Oxides

    SciTech Connect (OSTI)

    He, Qian; Woo, Jungwon; Belianinov, Alex; Guliants, Vadim V.; Borisevich, Albina Y

    2015-01-01

    In recent decades, catalysis research has transformed from the predominantly empirical field to one where it is possible to control the catalytic properties via characterization and modification of the atomic-scale active centers. Many phenomena in catalysis, such as synergistic effect, however, transcend the atomic scale and also require the knowledge and control of the mesoscale structure of the specimen to harness. In this paper, we use our discovery of atomic-scale epitaxial interfaces in molybdenum vanadium based complex oxide catalysts systems (i.e., MoVMO, M = Ta, Te, Sb, Nb, etc.) to achieve control of the mesoscale structure of this complex mixture of very different active phases. We can now achieve true epitaxial intergrowth between the catalytically critical M1 and M2 phases in the system that are hypothesized to have synergistic interactions, and demonstrate that the resulting catalyst has improved selectivity in the initial studies. Finally, we highlight the crucial role atomic scale characterization and mesoscale structure control play in uncovering the complex underpinnings of the synergistic effect in catalysis.

  6. Better Catalysts through Microscopy: Nanometer Scale M1/M2 Intergrown Heterostructure in Mo-V-M Complex Oxides

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    He, Qian; Woo, Jungwon; Belianinov, Alex; Guliants, Vadim V.; Borisevich, Albina Y

    2015-01-01

    In recent decades, catalysis research has transformed from the predominantly empirical field to one where it is possible to control the catalytic properties via characterization and modification of the atomic-scale active centers. Many phenomena in catalysis, such as synergistic effect, however, transcend the atomic scale and also require the knowledge and control of the mesoscale structure of the specimen to harness. In this paper, we use our discovery of atomic-scale epitaxial interfaces in molybdenum vanadium based complex oxide catalysts systems (i.e., MoVMO, M = Ta, Te, Sb, Nb, etc.) to achieve control of the mesoscale structure of this complex mixturemore » of very different active phases. We can now achieve true epitaxial intergrowth between the catalytically critical M1 and M2 phases in the system that are hypothesized to have synergistic interactions, and demonstrate that the resulting catalyst has improved selectivity in the initial studies. Finally, we highlight the crucial role atomic scale characterization and mesoscale structure control play in uncovering the complex underpinnings of the synergistic effect in catalysis.« less

  7. Exciton diamagnetic shifts and valley Zeeman effects in monolayer WS2 and MoS2 to 65 Tesla

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Stier, Andreas V.; McCreary, Kathleen M.; Jonker, Berend T.; Kono, Junichiro; Crooker, Scott A.

    2016-02-09

    In bulk and quantum-confined semiconductors, magneto-optical studies have historically played an essential role in determining the fundamental parameters of excitons (size, binding energy, spin, dimensionality and so on). Here we report low-temperature polarized reflection spectroscopy of atomically thin WS2 and MoS2 in high magnetic fields to 65 T. Both the A and B excitons exhibit similar Zeeman splittings of approximately –230 μeV T–1 (g-factor ≃–4), thereby quantifying the valley Zeeman effect in monolayer transition-metal disulphides. Crucially, these large fields also allow observation of the small quadratic diamagnetic shifts of both A and B excitons in monolayer WS2, from which radiimore » of ~1.53 and ~1.16 nm are calculated. Further, when analysed within a model of non-local dielectric screening, these diamagnetic shifts also constrain estimates of the A and B exciton binding energies (410 and 470 meV, respectively, using a reduced A exciton mass of 0.16 times the free electron mass). Lastly, these results highlight the utility of high magnetic fields for understanding new two-dimensional materials.« less

  8. Microstructural Characterization of Burnable Absorber Materials Being Evaluated for Application in LEU U-Mo Fuel Plates

    SciTech Connect (OSTI)

    J. F. Jue; B. Miller; B. Yao; E. Perez; Y. H. Sohn

    2011-03-01

    The starting microstructure of a fuel plate will impact how it performs during irradiation. As a result, microstructural characterization has been performed on as-fabricated monolithic fuel plates to determine the changes in fuel plate microstructure that may result from changes in fabrication parameters. Particular focus has been given to the fuel plate U-10Mo/Zr and Zr/AA6061 cladding interfaces, since the integrity of these interfaces will play a big role in determining the overall performance of the fuel plate during irradiation. In addition, burnable absorber materials for potential incorporation into monolithic fuel plates have been characterized to identify their as-fabricated microstructures. This information will be important when trying to understand the PIE data from fuel plates with burnable absorbers that are irradiated in future irradiation experiments. This paper will focus on the microstructures observed using optical metallography, X-ray diffraction, and scanning and transmission electron microscopy for monolithic fuel plates exposed to different fabrication parameters and for as-fabricated burnable absorber materials.

  9. Temperature-dependent phase-specific deformation mechanisms in a directionally solidified NiAl-Cr(Mo) lamellar composite

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yu, Dunji; An, Ke; Chen, Xu; Bei, Hongbin

    2015-10-09

    Phase-specific thermal expansion and mechanical deformation behaviors of a directionally solidified NiAl–Cr(Mo) lamellar in situ composite were investigated by using real-time in situ neutron diffraction during compression at elevated temperatures up to 800 °C. Tensile and compressive thermal residual stresses were found to exist in the NiAl phase and Crss (solid solution) phase, respectively. Then, based on the evolution of lattice spacings and phase stresses, the phase-specific deformation behavior was analyzed qualitatively and quantitatively. Moreover, estimates of phase stresses were derived by Hooke's law on the basis of a simple method for the determination of stress-free lattice spacing in inmore » situ composites. During compressive loading, the NiAl phase yields earlier than the Crss phase. The Crss phase carries much higher stress than the NiAl phase, and displays consistent strain hardening at all temperatures. The NiAl phase exhibits strain hardening at relatively low temperatures and softening at high temperatures. During unloading, the NiAl phase yields in tension whereas the Crss phase unloads elastically. Additionally, post-test microstructural observations show phase-through cracks at room temperature, micro cracks along phase interfaces at 600 °C and intact lamellae kinks at 800 °C, which is due to the increasing deformability of both phases as temperature rises.« less

  10. Twisted MoSe2 bilayers with variable local stacking and interlayer coupling revealed by low-frequency Raman spectroscopy

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Puretzky, Alexander A.; Liang, Liangbo; Li, Xufan; Xiao, Kai; Sumpter, Bobby G.; Meunier, Vincent; Geohegan, David B.

    2016-01-14

    Unique twisted bilayers of MoSe2 with multiple stacking orientations and interlayer couplings in the narrow range of twist angles, 60 ± 3°, are revealed by low-frequency Raman spectroscopy and theoretical analysis. The slight deviation from 60 allows the concomitant presence of patches featuring all three high-symmetry stacking configurations (2H or AA', AB', A'B) in one unique bilayer system. In this case, the periodic arrangement of the patches and their size strongly depend on the twist angle. Ab initio modeling predicts significant changes in frequencies and intensities of low-frequency modes versus stacking and twist angle. Experimentally, the variable stacking and couplingmore » across the interface is revealed by the appearance of two breathing modes corresponding to the mixture of the high-symmetry stacking configurations and unaligned regions of monolayers. Only one breathing mode is observed outside the narrow range of twist angles. This indicates a stacking transition to unaligned monolayers with mismatched atom registry without the in-plane restoring force required to generate a shear mode. As a result, the variable interlayer coupling and spacing in transition metal dichalcogenide bilayers revealed in this study may provide a new platform for optoelectronic applications of these materials.« less

  11. Microstructure investigation of 13Cr-2Mo ODS steel components obtained by high voltage electric discharge compaction technique

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Bogachev, Igor; Yudin, Artem; Grigoryev, Evgeniy; Chernov, Ivan; Staltsov, Maxim; Khasanov, Oleg; Olevsky, Eugene

    2015-11-02

    Refractory oxide dispersion strengthened 13Cr-2Mo steel powder was successfully consolidated to near theoretical density using high voltage electric discharge compaction. Cylindrical samples with relative density from 90% to 97% and dimensions of 10 mm in diameter and 10–15 mm in height were obtained. Consolidation conditions such as pressure and voltage were varied in some ranges to determine the optimal compaction regime. Three different concentrations of yttria were used to identify its effect on the properties of the samples. It is shown that the utilized ultra-rapid consolidation process in combination with high transmitted energy allows obtaining high density compacts, retaining themore » initial structure with minimal grain growth. The experimental results indicate some heterogeneity of the structure which may occur in the external layers of the tested samples due to various thermal and electromagnetic in-processing effects. As a result, the choice of the optimal parameters of the consolidation enables obtaining samples of acceptable quality.« less

  12. CASL - North Carolina State University

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    North Carolina State University Raleigh, NC NC State University has a proven record of working with industry and government to advance research in support of solving nuclear...

  13. Resources for State Energy Officials

    SciTech Connect (OSTI)

    SEE Action

    2012-06-01

    Provides a summary of State and Local Energy Efficiency Action Network (SEE Action) information resources available to state energy officials, organized by topic.

  14. Fermilab Today | Kansas State University

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Kansas State University Feb. 27, 2013 NAME: Kansas State University HOME TOWN: Manhattan, Kan. MASCOT: Willie the Wildcat COLORS: Royal purple COLLABORATING AT FERMILAB SINCE: 1993...

  15. Fermilab Today | Wayne State University

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Wayne State University May 29, 2013 NAME: Wayne State University HOME TOWN: Detroit, Mich. COLORS: Green and gold COLLABORATING AT FERMILAB SINCE: 1995 WORLDWIDE PARTICLE PHYSICS...

  16. Templates for Approval to Continue Sponsorship as a Federally Funded Research Development Center (FFRDC) and Authorization for a Management and Operating (M&O) Type of Contract

    Broader source: Energy.gov [DOE]

    The purpose of this Flash is to provide you copies of the subject templates. These templates were developed to standardize the format for approving sponsorship as a FFRDC and authorization to enter into an M&O type of contract. Two versions of each template were developed. One version covers non-competitive extensions and the other covers competitions. Word versions of the four templates will be available in the STRIPES Library.

  17. Self-powdering and nonlinear optical domain structures in ferroelastic beta'-Gd{sub 2}(MoO{sub 4}){sub 3} crystals formed in glass

    SciTech Connect (OSTI)

    Tsukada, Y.; Honma, T.; Komatsu, T.

    2009-08-15

    Ferroelastic beta'-Gd{sub 2}(MoO{sub 4}){sub 3}, (GMO), crystals are formed through the crystallization of 21.25Gd{sub 2}O{sub 3}-63.75MoO{sub 3}-15B{sub 2}O{sub 3} glass (mol%), and two scientific curious phenomena are observed. (1) GMO crystals formed in the crystallization break into small pieces with a triangular prism or pyramid shape having a length of 50-500 {mu}m spontaneously during the crystallizations in the inside of an electric furnace, not during the cooling in air after the crystallization. This phenomenon is called 'self-powdering phenomenon during crystallization' in this paper. (2) Each self-powdered GMO crystal grain shows a periodic domain structure with different refractive indices, and a spatially periodic second harmonic generation (SHG) depending on the domain structure is observed. It is proposed from polarized micro-Raman scattering spectra and the azimuthal dependence of second harmonic intensities that GMO crystals are oriented in each crystal grain and the orientation of (MoO{sub 4}){sup 2-} tetrahedra in GMO crystals changes periodically due to spontaneous strains in ferroelastic GMO crystals. - Graphical abstract: This figure shows the polarized optical photograph at room temperature for a particle (piece) obtained by a heat treatment of the glass at 590 deg. C for 2 h in an electric furnace in air. This particle was obtained through the self-powdering behavior in the crystallization of glass. The periodic domain structure is observed. Ferroelastic beta'-Gd{sub 2}(MoO{sub 4}){sub 3} crystals are formed in the particle, and second harmonic generations are detected, depending on the domain structure.

  18. Mechanism and Substrate Recognition of 2-Hydroxyethylphosphonate

    Office of Scientific and Technical Information (OSTI)

    Dioxygenase (Journal Article) | SciTech Connect SciTech Connect Search Results Journal Article: Mechanism and Substrate Recognition of 2-Hydroxyethylphosphonate Dioxygenase Citation Details In-Document Search Title: Mechanism and Substrate Recognition of 2-Hydroxyethylphosphonate Dioxygenase HEPD belongs to the superfamily of 2-His-1-carboxylate non-heme iron-dependent dioxygenases. It converts 2-hydroxyethylphosphonate (2-HEP) to hydroxymethylphosphonate (HMP) and formate. Previously

  19. Policy Flash 2013-40 Acquisition Guide Chapter 43.3 Maintaining Alignment of Project Management with Contract Management of Non-Management and Operating (M&O) Cost Reimburstment Contracts

    Broader source: Energy.gov [DOE]

    Attached is Policy Flash 2013-40 Acquisition Guide Chapter 43.3 Maintaining Alignment of Project Management with Contract Management of Non-Management and Operating (M&O) Cost Reimbursement...

  20. Low-field magnetoresistance up to 400 K in double perovskite Sr{sub 2}FeMoO{sub 6} synthesized by a citrate route

    SciTech Connect (OSTI)

    Harnagea, L.; Jurca, B.; Berthet, P.

    2014-03-15

    A wet-chemistry technique, namely the citrate route, has been used to prepare high-quality polycrystalline samples of double perovskite Sr{sub 2}FeMoO{sub 6}. We report on the evolution of magnetic and magnetoresistive properties of the synthesized samples as a function of three parameters (i) the pH of the starting solution, (ii) the decomposition temperature of the citrate precursors and (iii) the sintering conditions. The low-field magnetoresistance (LFMR) value of our best samples is as high as 5% at room temperature for an applied magnetic field of 1 kOe. Additionally, the distinguishing feature of these samples is the persistence of LFMR, with a reasonably large value, up to 400 K which is a crucial parameter for any practical application. Our study indicates that the enhancement of LFMR observed is due to a good compromise between the grain size distribution and their magnetic polarization. -- Graphical abstract: The microstructure (left panel) and corresponding low-field magnetoresistance of one of the Sr{sub 2}FeMoO{sub 6} samples synthesized in the course of this work. Highlights: Samples of Sr{sub 2}FeMoO{sub 6} are prepared using a citrate route under varying conditions. Magnetoresistive properties are improved and optimized. Low-field magnetoresitence values as large as 5% at 300 K/1 kOe are reported. Persistence of low-field magnetoresistance up to 400 K.

  1. Adsorption of propane, isopropyl, and hydrogen on cluster models of the M1 phase of Mo-V-Te-Nb-O mixed metal oxide catalyst

    SciTech Connect (OSTI)

    Govindasamy, Agalya; Muthukumar, Kaliappan; Yu, Junjun; Xu, Ye; Guliants, Vadim V.

    2010-01-01

    The Mo-V-Te-Nb-O mixed metal oxide catalyst possessing the M1 phase structure is uniquely capable of directly converting propane into acrylonitrile. However, the mechanism of this complex eight-electron transformation, which includes a series of oxidative H-abstraction and N-insertion steps, remains poorly understood. We have conducted a density functional theory study of cluster models of the proposed active and selective site for propane ammoxidation, including the adsorption of propane, isopropyl (CH{sub 3}CHCH{sub 3}), and H which are involved in the first step of this transformation, that is, the methylene C-H bond scission in propane, on these active site models. Among the surface oxygen species, the telluryl oxo (Te=O) is found to be the most nucleophilic. Whereas the adsorption of propane is weak regardless of the MO{sub x} species involved, isopropyl and H adsorption exhibits strong preference in the order of Te=O > V=O > bridging oxygens > empty Mo apical site, suggesting the importance of TeO{sub x} species for H abstraction. The adsorption energies of isopropyl and H and consequently the reaction energy of the initial dehydrogenation of propane are strongly dependent on the number of ab planes included in the cluster, which points to the need to employ multilayer cluster models to correctly capture the energetics of surface chemistry on this mixed metal oxide catalyst.

  2. A study of nitrogenation of a NdFe{sub 12-x}Mo{sub x} compound by in situ neutron powder diffraction.

    SciTech Connect (OSTI)

    Ding, Y.; Lin, J.; Loong, C.-K.; Short, S. M.

    1997-11-18

    The effects on the crystal lattice of a NdFe{sub 12{minus}x}Mo{sub x}(x {approx_equal} 1.7) compound which contained {approximately}12 vol% of bcc-Fe were studied by neutron powder diffraction during controlled nitrogenation over the 25-600 C temperature range. The sample inside the furnace was connected to a closed volume of ultra-pure nitrogen gas while neutron data were collected over regular time intervals during sequential heating. Substantial nitrogen absorption occurred between 500 to 600 C. During the nitrogenation process the NdFe{sub 12{minus}x}Mo{sub x}N{sub y} lattice expanded while the bcc-Fe lattice contracted. An increasing decomposition of the compound into bcc-Fe at 600 C was observed. The average size of the NdFe{sub 12{minus}x}Mo{sub x}N{sub y} crystalline grains decreased starting at {approximately}300 C, reaching a minimum at {approximately}500 C and then increased markedly at higher temperatures. The development of lattice strains, on the other hand, showed an opposite trend, i.e., a maximum at 500 C. A correlation of structural modification of the crystalline phases and the nitrogenation process is discussed.

  3. Nanoscale Phase Separation In Epitaxial Cr-Mo and Cr-V Alloy Thin Films Studied Using Atom Probe Tomography: Comparison Of Experiments And Simulation

    SciTech Connect (OSTI)

    Devaraj, Arun; Kaspar, Tiffany C.; Ramanan, Sathvik; Walvekar, Sarita K.; Bowden, Mark E.; Shutthanandan, V.; Kurtz, Richard J.

    2014-11-21

    Tailored metal alloy thin film-oxide interfaces generated using molecular beam epitaxial (MBE) deposition of alloy thin films on a single crystalline oxide substrate can be used for detailed studies of irradiation damage response on the interface structure. However presence of nanoscale phase separation in the MBE grown alloy thin films can impact the metal-oxide interface structure. Due to nanoscale domain size of such phase separation it is very challenging to characterize by conventional techniques. Therefor laser assisted atom probe tomography (APT) was utilized to study the phase separation in epitaxial Cr0.61Mo0.39, Cr0.77Mo0.23, and Cr0.32V0.68 alloy thin films grown by MBE on MgO(001) single crystal substrates. Statistical analysis, namely frequency distribution analysis and Pearson coefficient analysis of experimental data was compared with similar analyses conducted on simulated APT datasets with known extent of phase separation. Thus the presence of phase separation in Cr-Mo films, even when phase separation was not clearly observed by x-ray diffraction, and the absence of phase separation in the Cr-V film were thus confirmed.

  4. Nanoscale phase separation in epitaxial Cr-Mo and Cr-V alloy thin films studied using atom probe tomography: Comparison of experiments and simulation

    SciTech Connect (OSTI)

    Devaraj, A.; Ramanan, S.; Walvekar, S.; Bowden, M. E.; Shutthanandan, V.; Kaspar, T. C.; Kurtz, R. J.

    2014-11-21

    Tailored metal alloy thin film-oxide interfaces generated using molecular beam epitaxy (MBE) deposition of alloy thin films on a single crystalline oxide substrate can be used for detailed studies of irradiation damage response on the interface structure. However, the presence of nanoscale phase separation in the MBE grown alloy thin films can impact the metal-oxide interface structure. Due to nanoscale domain size of such phase separation, it is very challenging to characterize by conventional techniques. Therefore, laser assisted atom probe tomography (APT) was utilized to study the phase separation in epitaxial Cr{sub 0.61}Mo{sub 0.39}, Cr{sub 0.77}Mo{sub 0.23}, and Cr{sub 0.32}V{sub 0.68} alloy thin films grown by MBE on MgO(001) single crystal substrates. Statistical analysis, namely frequency distribution analysis and Pearson coefficient analysis of experimental data was compared with similar analyses conducted on simulated APT datasets with known extent of phase separation. Thus, the presence of phase separation in Cr-Mo films, even when phase separation was not clearly observed by x-ray diffraction, and the absence of phase separation in the Cr-V film were confirmed.

  5. Qualified Energy Conservation Bond State-by-State Summary Tables

    Broader source: Energy.gov [DOE]

    Provides a list of qualified energy conservation bond state summary tables. Author: Energy Programs Consortium

  6. EIA - State Nuclear Profiles

    U.S. Energy Information Administration (EIA) Indexed Site

    Alabama Nuclear Profile 2010 Alabama profile Alabama total electric power industry, summer capacity and net generation, by energy source, 2010 Primary energy source Summer capacity (mw) Share of State total (percent) Net generation (thousand mwh) Share of State total (percent) Nuclear 5,043 15.6 37,941 24.9 Coal 11,441 35.3 63,050 41.4 Hydro and Pumped Storage 3,272 10.1 8,704 5.7 Natural Gas 11,936 36.8 39,235 25.8 Other1 100 0.3 643 0.4 Other Renewable1 583 1.8 2,377 1.6 Petroleum 43 0.1 200

  7. EIA - State Nuclear Profiles

    U.S. Energy Information Administration (EIA) Indexed Site

    Arizona Nuclear Profile 2010 Arizona profile Arizona total electric power industry, summer capacity and net generation, by energy source, 2010 Primary energy source Summer capacity (mw) Share of State total (percent) Net generation (thousand mwh) Share of State total (percent) Nuclear 1,937 14.9 31,200 27.9 Coal 6,233 23.6 43,644 39.1 Hydro and Pumped Storage 2,937 11.1 6,831 6.1 Natural Gas 13,012 49.3 29,676 26.6 Other 1 - - 15 * Other Renewable1 181 0.7 319 0.3 Petroleum 93 0.4 66 0.1 Total

  8. EIA - State Nuclear Profiles

    U.S. Energy Information Administration (EIA) Indexed Site

    Arkansas Nuclear Profile 2010 Arkansas profile Arkansas total electric power industry, summer capacity and net generation, by energy source, 2010 Primary energy source Summer capacity (mw) Share of State total (percent) Net generation (thousand mwh) Share of State ttal (percent) Nuclear 1,835 11.5 15,023 24.6 Coal 4,535 28.4 28,152 46.2 Hydro and Pumped Storage 1,369 8.6 3,658 6.0 Natural Gas 7,894 49.4 12,469 20.4 Other 1 - - 28 * Other Renewable1 326 2.0 1,624 2.7 Petroleum 22 0.1 45 0.1 Total

  9. EIA - State Nuclear Profiles

    U.S. Energy Information Administration (EIA) Indexed Site

    California Nuclear Profile 2010 California profile California total electric power industry, summer capacity and net generation, by energy source, 2010 Primary energy source Summer capacity (mw) Share of State total (percent) Net generation (thousand mwh) Share of State total (percent) Nuclear 4,390 6.5 32,201 15.8 Coal 374 0.6 2,100 1.0 Hydro and Pumped Storage 13,954 20.7 33,260 16.3 Natural Gas 41,370 61.4 107,522 52.7 Other 1 220 0.3 2,534 1.2 Other Renewable1 6,319 9.4 25,450 12.5 Petroleum

  10. EIA - State Nuclear Profiles

    U.S. Energy Information Administration (EIA) Indexed Site

    Connecticut Nuclear Profile 2010 Connecticut profile Connecticut total electric power industry, summer capacity and net generation, by energy source, 2010 Primary energy source Summer capacity (mw) Share of State total (percent) Net generation (thousand mwh) Share of State total (percent) Nuclear 2,103 25.4 16,750 50.2 Coal 564 6.8 2,604 7.8 Hydro and Pumped Storage 151 1.8 400 1.2 Natural Gas 2,292 27.7 11,716 35.1 Other 1 27 0.3 730 2.2 Other Renewable1 159 1.9 740 2.2 Petroleum 2,989 36.1 409

  11. EIA - State Nuclear Profiles

    U.S. Energy Information Administration (EIA) Indexed Site

    Florida Nuclear Profile 2010 Florida profile Florida total electric power industry, summer capacity and net generation, by energy source, 2010 Primary Energy Source Summer capacity (mw) Share of State total (percent) Net generation (thousand mwh) Share of State total (percent) Nuclear 3,924 6.6 23,936 10.4 Coal 9,975 16.9 59,897 26.1 Hydro and Pumped Storage 55 0.1 177 0.1 Natural Gas 31,563 53.4 128,634 56.1 Other1 544 0.9 2,842 1.2 Other Renewable1 1,053 1.8 4,487 2.0 Petroleum 12,033 20.3

  12. EIA - State Nuclear Profiles

    U.S. Energy Information Administration (EIA) Indexed Site

    Georgia Nuclear Profile 2010 Georgia profile Georgia total electric power industry, summer capacity and net generation, by energy source, 2010 Primary energy source Summer capacity (mw) Share of State total (percent) Net generation (thousand mwh) Share of State total (percent) Nuclear 4,061 11.1 33,512 24.6 Coal 13,230 36.1 73,298 54.0 Hydro and Pumped Storage 3,851 10.5 3,044 2.7 Natural Gas 12,668 34.6 23,884 15.9 Other 1 - - 18 * Other Renewable1 637 1.7 3,181 2.2 Petroleum 2,189 6.0 641 0.5

  13. EIA - State Nuclear Profiles

    U.S. Energy Information Administration (EIA) Indexed Site

    Illinois Nuclear Profile 2010 Illinois profile Illinois total electric power industry, summer capacity and net generation, by energy source, 2010 Primary energy source Summer capacity (mw) Share of State total (percent) Net generation (thousand mwh) Share of State total (percent) Nuclear 11,441 25.9 96,190 47.8 Coal 15,551 35.2 93,611 46.5 Hydro and Pumped Storage 34 0.1 119 0.1 Natural Gas 13,771 31.2 5,724 2.8 Other 1 145 0.3 461 0.2 Other Renewable1 2,078 4.7 5,138 2.6 Petroleum 1,106 2.5 110

  14. EIA - State Nuclear Profiles

    U.S. Energy Information Administration (EIA) Indexed Site

    Iowa Nuclear Profile 2010 Iowa profile Iowa total electric power industry, summer capacity and net generation, by energy source, 2010 Primary energy source Summer capacity (mw) Share of State total (percent) Net generation (thousand mwh) Share of State total (percent) Nuclear 601 4.1 4,451 7.7 Coal 6,956 47.7 41,283 71.8 Hydro and Pumped Storage 144 1.0 948 1.6 Natural Gas 2,299 15.8 1,312 2.3 Other Renewable1 3,584 24.6 9,360 16.3 Petroleum 1,007 6.9 154 .0.3 Total 14,592 100.0 57,509 100

  15. EIA - State Nuclear Profiles

    U.S. Energy Information Administration (EIA) Indexed Site

    Kansas Nuclear Profile 2010 Kansas profile Kansas total electric power industry, summer capacity and net generation, by energy source, 2010 Primary energy source Summer capacity (mw) Share of State total (percent) Net generation (thousand mwh) Share of State total (percent) Nuclear 1,160 9.2 9,556 19.9 Coal 5,179 41.3 32,505 67.8 Hydro and Pumped Storage 3 * 13 * Natural Gas 4,573 36.5 2,287 4.8 Other Renewable1 1,079 8.6 3,459 7.2 Petroleum 550 4.4 103 0.2 Total 12,543 100.0 47,924 100

  16. EIA - State Nuclear Profiles

    U.S. Energy Information Administration (EIA) Indexed Site

    Louisiana Nuclear Profile 2010 Louisiana profile Louisiana total electric power industry, summer capacity and net generation, by energy source, 2010 Primary energy source Summer capacity (nw) Share of State total (percent) Net generation (thousand nwh) Share of State total (percent) Nuclear 2,142 8.0 18,639 18.1 Coal 3,417 12.8 23,924 23.3 Hydro and Pumped Storage 192 0.7 1,109 1.1 Natural Gas 19,574 73.2 51,344 49.9 Other 1 213 0.8 2,120 2.1 Other Renewable1 325 1.2 2,468 2.4 Petroleum 881 3.3

  17. EIA - State Nuclear Profiles

    U.S. Energy Information Administration (EIA) Indexed Site

    Maryland Nuclear Profile 2010 Maryland profile Maryland total electric power industry, summer capacity and net generation, by energy source, 2010 Primary energy source Summer capacity (mw) Share of State total (percent) Net generation (thousand mwh) Share of State total (Percent) Nuclear 1,705 13.6 13,994 32.1 Coal 4,886 39.0 23,668 54.3 Hydro and Pumped Storage 590 4.7 1,667 3.8 Natural Gas 2,041 16.3 2,897 6.6 Other 1 152 1.2 485 1.1 Other Renewable1 209 1.7 574 1.3 Petroleum 2,933 23.4 322

  18. EIA - State Nuclear Profiles

    U.S. Energy Information Administration (EIA) Indexed Site

    Massachusetts Nuclear Profile 2010 Massachusetts profile Massachusetts total electric power industry, summer capacity and net generation, by energy source, 2010 Primary energy source Summer capacity (mw) Share of State total (percent) Net generation (thousand mwh) Share of State total (percent) Nuclear 685 5.0 5,918 13.8 Coal 1,669 12.2 8,306 19.4 Hydro and Pumped Storage 1,942 14.2 659 1.5 Natural Gas 6,063 44.3 25,582 59.8 Other 1 3 * 771 1.8 Other Renewable1 304 2.2 1,274 3.0 Petroleum 3,031

  19. EIA - State Nuclear Profiles

    U.S. Energy Information Administration (EIA) Indexed Site

    Michigan Nuclear Profile 2010 Michigan profile Michigan total electric power industry, summer capacity and net generation, by energy source, 2010 Primary energy source Summer capacity (mw) Share of State total (percent) Net generation (thousand mwh) Share of State total (percent) Nuclear 3,947 13.2 29,625 26.6 Coal 11,531 38.7 65,604 58.8 Hydro and Pumped Storage 2,109 7.1 228 0.2 Natural Gas 11,033 37.0 12,249 11.0 Other 1 - - 631 0.6 Other Renewable1 571 1.9 2,832 2.5 Petroleum 640 2.1 382 0.3

  20. EIA - State Nuclear Profiles

    U.S. Energy Information Administration (EIA) Indexed Site

    Minnesota Nuclear Profile 2010 Minnesota profile Minnesota total electric power industry, summer capacity and net generation, by energy source, 2010 Primary energy source Summer capacity (mw) Share of State total (percent) Net generation (thousand mwh) Share of State total (percent) Nuclear 1,549 10.8 13,478 25.1 Coal 4,789 32.5 28,083 52.3 Hydro and Pumped Storage 193 1.3 840 1.6 Natural Gas 4,936 33.5 4,341 8.1 Other 1 13 0.1 258 0.5 Other Renewable1 2,395 16.3 6,640 12.4 Petroleum 795 5.4 31

  1. EIA - State Nuclear Profiles

    U.S. Energy Information Administration (EIA) Indexed Site

    Mississippi Nuclear Profile 2010 Mississippi profile Mississippi total electric power industry, summer capacity and net generation, by energy source, 2010 Primary energy source Summer capacity (mw) Share of State total (percent) Net generation (thousand mwh) Share of State total (percent) Nuclear 1,251 8.0 9,643 17.7 Coal 2,526 16.1 13,629 25.0 Natural Gas 11,640 74.2 29,619 54.4 Other 1 4 * 10 * Other Renewable1 235 1.5 1,504 2.8 Petroleum 35 0.2 18 0.1 Total 15,691 100.0 54,487 100.0

  2. EIA - State Nuclear Profiles

    U.S. Energy Information Administration (EIA) Indexed Site

    Missouri Nuclear Profile 2010 Missouri profile Missouri total electric power industry, summer capacity and net generation, by energy source, 2010 Primary energy source Summer capacity (mw) Share of State total (percent) Net generation (thousand mwh) Share of State total (percent) Nuclear 1,190 5.5 8,996 9.7 Coal 12,070 55.5 75,047 81.3 Hydro and Pumped Storage 1,221 5.6 2,427 2.6 Natural Gas 5,579 25.7 4,690 5.1 Other 1 - - 39 * Other Renewable1 466 2.1 988 1.1 Petroleum 1,212 5.6 126 0.1 Total

  3. EIA - State Nuclear Profiles

    U.S. Energy Information Administration (EIA) Indexed Site

    Nebraska Nuclear Profile 2010 Nebraska profile Nebraska total electric power industry, summer capacity and net generation, by energy source, 2010 Primary energy source Summer capacity (mw) Share of State total (percent) Net generation (thousand mwh) Share of State total (percent) Nuclear 1,245 15.8 11,054 30.2 Coal 3,932 50.0 23,368 63.8 Hydro and Pumped Storage 278 3.5 1,314 3.6 Natural Gas 1,864 23.5 375 1.0 Other Renewable1 165 2.1 493 1.3 Petroleum 387 4.9 31 0.1 Total 7,857 100.0 36,630

  4. EIA - State Nuclear Profiles

    U.S. Energy Information Administration (EIA) Indexed Site

    Hampshire Nuclear Profile 2010 New Hampshire profile New Hampshire total electric power industry, summer capacity and net generation, by energy source, 2010 Primary energy source Summer capacity (mw) Share of State total (percent) Net generation (thousand mwh) Share of State total (percent) Nuclear 1,247 29.8 10,910 49.2 Coal 546 13.1 3,083 13.9 Hydro and Pumped Storage 489 11.7 1,478 6.7 Natural Gas 1,215 29.1 5,365 24.2 Other 1 - - 57 0.3 Other Renewable1 182 4.4 1,232 5.6 Petroleum 501 12.0

  5. EIA - State Nuclear Profiles

    U.S. Energy Information Administration (EIA) Indexed Site

    Jersey Nuclear Profile 2010 New Jersey profile New Jersey total electric power industry, summer capacity and net generation, by energy source, 2010 Primary energy source Summer capacity (mw) Share of State total (percent) Net generation (thousand mwh) Share of State total (percent) Nuclear 4,108 22.3 32,771 49.9 Coal 2,036 11.1 6,418 9.8 Hydro and Pumped Storage 404 2.2 -176 -0.3 Natural Gas 10,244 55.6 24,902 37.9 Other 1 56 0.3 682 1.0 Other Renewable1 226 1.2 850 1.3 Petroleum 1,351 7.3 235

  6. EIA - State Nuclear Profiles

    U.S. Energy Information Administration (EIA) Indexed Site

    York Nuclear Profile 2010 New York profile New York total electric power industry, summer capacity and net generation, by energy source, 2010 Primary energy source Summer capacity (mw) Share of State total (percent) Net generation (thousand mwh) Share of State total (percent) Nuclear 5,271 13.4 41,870 30.6 Coal 2,781 7.1 13,583 9.9 Hydro and Pumped Storage 5,714 14.5 24,942 18.2 Natural Gas 17,407 44.2 48,916 35.7 Other 1 45 0.1 832 0.6 Other Renewable1 1,719 4.4 4,815 3.5 Petroleum 6,421 16.3

  7. EIA - State Nuclear Profiles

    U.S. Energy Information Administration (EIA) Indexed Site

    North Carolina Nuclear Profile 2010 North Carolina profile North Carolina total electric power industry, summer capacity and net generation, by energy source, 2010 Primary energy source Summer capacity (mw) Share of State total (percent) Net generation (thousand mwh) Share of State total (percent) Nuclear 4,958 17.9 40,740 31.7 Coal 12,766 46.1 71,951 55.9 Hydro and Pumped Storage 2,042 7.4 4,757 3.7 Natural Gas 6,742 24.4 8,447 6.6 Other 1 50 0.2 407 0.3 Other Renewable1 543 2.0 2,083 1.6

  8. EIA - State Nuclear Profiles

    U.S. Energy Information Administration (EIA) Indexed Site

    Ohio Nuclear Profile 2010 Ohio profile Ohio total electric power industry, summer capacity and net generation, by energy source, 2010 Primary energy source Summer capacity (mw) Share of State total (percent) Net generation (thousand mwh) Share of State total (percent) Nuclear 2,134 6.5 15,805 11.0 Coal 21,360 64.6 117,828 82.1 Hydro and Pumped Storage 101 0.3 429 0.3 Natural Gas 8,203 24.8 7,128 5.0 Other 1 123 0.4 266 0.2 Other Renewable1 130 0.4 700 0.5 Petroleum 1,019 3.1 1,442 1.0 Total

  9. EIA - State Nuclear Profiles

    U.S. Energy Information Administration (EIA) Indexed Site

    Pennsylvania Nuclear Profile 2010 Pennsylvania profile Pennsylvania total electric power industry, summer capacity and net generation, by energy source, 2010 Primary energy source Summer capacity (mw) Share of State total (percent) Net generation (thousand mwh) Share of State total (percent) Nuclear 9,540 20.9 77,828 33.9 Coal 18,481 40.6 110,369 48.0 Hydro and Pumped Storage 2,268 5.0 1,624 0.7 Natural Gas 9,415 20.7 33,718 14.7 Other 1 100 0.2 1,396 0.6 Other Renewable1 1,237 2.7 4,245 1.8

  10. EIA - State Nuclear Profiles

    U.S. Energy Information Administration (EIA) Indexed Site

    South Carolina profile South Carolina total electric power industry, summer capacity and net generation, by energy source, 2010 Primary energy source Summer capacity (mw) Share of State total (percent) Net generation (thousand mwh) Share of State total (percent) Nuclear 6,486 27.0 51,988 49.9 Coal 7,230 30.1 37,671 36.2 Hydro and Pumped Storage 4,006 16.7 1,442 1.4 Natural Gas 5,308 22.1 10,927 10.5 Other 1 - - 61 0.1 Other Renewable1 284 1.2 1,873 1.8 Petroleum 670 2.8 191 0.2 Total 23,982

  11. EIA - State Nuclear Profiles

    U.S. Energy Information Administration (EIA) Indexed Site

    Tennessee profile Tennessee total electric power industry, summer capacity and net generation, by energy source, 2010 Primary energy source Summer capacity (mw) Share of State total (percent) Net generation (thousand mwh) Share of State total (percent) Nuclear 3,401 15.9 27,739 33.7 Coal 8,805 41.1 43,670 53.0 Hydro and Pumped Storage 4,277 20.0 7,416 9.0 Natural Gas 4,655 21.7 2,302 2.8 Other 1 - - 16 * Other Renewable1 222 1.0 988 1.2 Petroleum 58 0.3 217 0.3 Total 21,417 100.0 82,349 100.0

  12. EIA - State Nuclear Profiles

    U.S. Energy Information Administration (EIA) Indexed Site

    Texas profile Texas total electric power industry, summer capacity and net generation, by energy source, 2010 Primary energy source Summer capacity (mw) Share of State total (percent) Net generation (thousand mwh) Share of State total (percent) Nuclear 4,966 4.6 41,335 10.0 Coal 22,335 20.6 150,173 36.5 Hydro and Pumped Storage 689 0.6 1,262 0.3 Natural Gas 69,291 64.0 186,882 45.4 Other 1 477 0.4 3,630 0.9 Other Renewable1 10,295 9.5 27,705 6.7 Petroleum 204 0.2 708 0.2 Total 108,258 100.0

  13. EIA - State Nuclear Profiles

    U.S. Energy Information Administration (EIA) Indexed Site

    Virginia profile Virginia total electric power industry, summer capacity and net generation, by energy source, 2010 Primary energy source Summer capacity (mw) Share of State total (percent) Net generation (thousand mwh) Share of State total (percent) Nuclear 3,501 14.5 26,572 36.4 Coal 5,868 24.3 25,459 34.9 Hydro and Pumped Storage 4,107 17.0 10 * Natural Gas 7,581 31.4 16,999 23.3 Other 1 - - 414 0.6 Other Renewable1 621 2.6 2,220 3.0 Petroleum 2,432 10.1 1,293 1.8 Total 24,109 100.0 72,966

  14. EIA - State Nuclear Profiles

    U.S. Energy Information Administration (EIA) Indexed Site

    Washington profile Washington total electric power industry, summer capacity and net generation, by energy source, 2010 Primary energy source Summer capacity (mw) Share of State total (percent) Net generation (thousand mwh) Share of State total (percent) Nuclear 1,097 3.6 9,241 8.9 Coal 1,340 4.4 8,527 8.2 Hydro and Pumped Storage 21,495 70.5 68,342 66.0 Natural Gas 3,828 12.6 10,359 10.0 Other 1 - - 354 0.3 Other Renewable1 2,703 8.9 6,617 6.4 Petroleum 15 * 32 * Total 30,478 100.0 103,473

  15. EIA - State Nuclear Profiles

    U.S. Energy Information Administration (EIA) Indexed Site

    Wisconsin profile Wisconsin total electric power industry, summer capacity and net generation, by energy source, 2010 Primary energy source Summer capacity (mw) Share of State total (percent) Net generation (thousand mwh) Share of State total (percent) Nuclear 1,584 8.9 13,281 20.7 Coal 8,063 45.2 40,169 62.5 Hydro and Pumped Storage 492 2.8 2,112 3.3 Natural Gas 6,110 34.3 5,497 8.5 Other 1 21 0.1 63 0.1 Other Renewable1 775 4.3 2,474 3.8 Petroleum 790 4.4 718 1.1 Total 17,836 100.0 64,314

  16. EIA - State Nuclear Profiles

    Gasoline and Diesel Fuel Update (EIA)

    Massachusetts Nuclear Profile 2010 Massachusetts profile Massachusetts total electric power industry, summer capacity and net generation, by energy source, 2010 Primary energy source Summer capacity (mw) Share of State total (percent) Net generation (thousand mwh) Share of State total (percent) Nuclear 685 5.0 5,918 13.8 Coal 1,669 12.2 8,306 19.4 Hydro and Pumped Storage 1,942 14.2 659 1.5 Natural Gas 6,063 44.3 25,582 59.8 Other 1 3 * 771 1.8 Other Renewable1 304 2.2 1,274 3.0 Petroleum 3,031

  17. EIA - State Nuclear Profiles

    Gasoline and Diesel Fuel Update (EIA)

    Michigan Nuclear Profile 2010 Michigan profile Michigan total electric power industry, summer capacity and net generation, by energy source, 2010 Primary energy source Summer capacity (mw) Share of State total (percent) Net generation (thousand mwh) Share of State total (percent) Nuclear 3,947 13.2 29,625 26.6 Coal 11,531 38.7 65,604 58.8 Hydro and Pumped Storage 2,109 7.1 228 0.2 Natural Gas 11,033 37.0 12,249 11.0 Other 1 - - 631 0.6 Other Renewable1 571 1.9 2,832 2.5 Petroleum 640 2.1 382 0.3

  18. EIA - State Nuclear Profiles

    Gasoline and Diesel Fuel Update (EIA)

    Mississippi Nuclear Profile 2010 Mississippi profile Mississippi total electric power industry, summer capacity and net generation, by energy source, 2010 Primary energy source Summer capacity (mw) Share of State total (percent) Net generation (thousand mwh) Share of State total (percent) Nuclear 1,251 8.0 9,643 17.7 Coal 2,526 16.1 13,629 25.0 Natural Gas 11,640 74.2 29,619 54.4 Other 1 4 * 10 * Other Renewable1 235 1.5 1,504 2.8 Petroleum 35 0.2 18 0.1 Total 15,691 100.0 54,487 100.0

  19. EIA - State Nuclear Profiles

    Gasoline and Diesel Fuel Update (EIA)

    Missouri Nuclear Profile 2010 Missouri profile Missouri total electric power industry, summer capacity and net generation, by energy source, 2010 Primary energy source Summer capacity (mw) Share of State total (percent) Net generation (thousand mwh) Share of State total (percent) Nuclear 1,190 5.5 8,996 9.7 Coal 12,070 55.5 75,047 81.3 Hydro and Pumped Storage 1,221 5.6 2,427 2.6 Natural Gas 5,579 25.7 4,690 5.1 Other 1 - - 39 * Other Renewable1 466 2.1 988 1.1 Petroleum 1,212 5.6 126 0.1 Total

  20. EIA - State Nuclear Profiles

    Gasoline and Diesel Fuel Update (EIA)

    Nebraska Nuclear Profile 2010 Nebraska profile Nebraska total electric power industry, summer capacity and net generation, by energy source, 2010 Primary energy source Summer capacity (mw) Share of State total (percent) Net generation (thousand mwh) Share of State total (percent) Nuclear 1,245 15.8 11,054 30.2 Coal 3,932 50.0 23,368 63.8 Hydro and Pumped Storage 278 3.5 1,314 3.6 Natural Gas 1,864 23.5 375 1.0 Other Renewable1 165 2.1 493 1.3 Petroleum 387 4.9 31 0.1 Total 7,857 100.0 36,630