Sample records for octane gasoline alkylation

  1. An Experimental Investigation of Low Octane Gasoline in Diesel...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Low Octane Gasoline in Diesel Engines An Experimental Investigation of Low Octane Gasoline in Diesel Engines Presentation given at the 16th Directions in Engine-Efficiency and...

  2. High-Octane Fuel from Refinery Exhaust Gas: Upgrading Refinery Off-Gas to High-Octane Alkylate

    SciTech Connect (OSTI)

    None

    2009-12-01T23:59:59.000Z

    Broad Funding Opportunity Announcement Project: Exelus is developing a method to convert olefins from oil refinery exhaust gas into alkylate, a clean-burning, high-octane component of gasoline. Traditionally, olefins must be separated from exhaust before they can be converted into another source of useful fuel. Exelus’ process uses catalysts that convert the olefin to alkylate without first separating it from the exhaust. The ability to turn up to 50% of exhaust directly into gasoline blends could result in an additional 46 million gallons of gasoline in the U.S. each year.

  3. Method for determining the octane rating of gasoline samples by observing corresponding acoustic resonances therein

    DOE Patents [OSTI]

    Sinha, D.N.; Anthony, B.W.

    1997-02-25T23:59:59.000Z

    A method is described for determining the octane rating of gasoline samples by observing corresponding acoustic resonances therein. A direct correlation between the octane rating of gasoline and the frequency of corresponding acoustic resonances therein has been experimentally observed. Therefore, the octane rating of a gasoline sample can be directly determined through speed of sound measurements instead of by the cumbersome process of quantifying the knocking quality of the gasoline. Various receptacle geometries and construction materials may be employed. Moreover, it is anticipated that the measurements can be performed on flowing samples in pipes, thereby rendering the present method useful in refineries and distilleries. 3 figs.

  4. Method for determining the octane rating of gasoline samples by observing corresponding acoustic resonances therein

    DOE Patents [OSTI]

    Sinha, Dipen N. (Los Alamos, NM); Anthony, Brian W. (Clearfield, PA)

    1997-01-01T23:59:59.000Z

    A method for determining the octane rating of gasoline samples by observing corresponding acoustic resonances therein. A direct correlation between the octane rating of gasoline and the frequency of corresponding acoustic resonances therein has been experimentally observed. Therefore, the octane rating of a gasoline sample can be directly determined through speed of sound measurements instead of by the cumbersome process of quantifying the knocking quality of the gasoline. Various receptacle geometries and construction materials may be employed. Moreover, it is anticipated that the measurements can be performed on flowing samples in pipes, thereby rendering the present method useful in refineries and distilleries.

  5. The chemical origin of octane sensitivity in gasoline fuels containing nitroalkanes

    SciTech Connect (OSTI)

    Cracknell, R.F.; McAllister, L.J.; Norton, M.; Walmsley, H.L. [Shell Global Solutions, Shell Technology Centre Thornton, P.O. Box 1, Chester CH1 3SH (United Kingdom); Andrae, J.C.G. [Shell Global Solutions, Shell Technology Centre Thornton, P.O. Box 1, Chester CH1 3SH (United Kingdom); Dept. of Chemical Engineering and Technology, Royal Institute of Technology (KTH), SE-100 44 Stockholm (Sweden)

    2009-05-15T23:59:59.000Z

    Experimental octane measurements are presented for a standard gasoline to which has been added various quantities of nitromethane, nitroethane and 1-nitropropane. The addition of nitroalkanes was found to suppress the Motor Octane Number to a much greater extent than the Research Octane Number. In other words addition of nitroalkanes increases the octane sensitivity of gasoline. Density Functional Theory was used to model the equilibrium thermodynamics and the barrier heights for reactions leading to the break-up of nitroethane. These results were used to develop a chemical kinetic scheme for nitroalkanes combined with a surrogate gasoline (for which a mechanism has been developed previously). Finally the chemical kinetic simulations were combined with a quasi-dimensional engine model in order to predict autoignition in octane rating tests. Our results suggest that the chemical origin of octane sensitivity in gasoline/nitroalkane blends cannot be fully explained on the conventional basis of the extent to which NTC behaviour is absent. Instead we have shown that the contribution of the two pathways leading to autoignition in gasoline containing nitroalkanes becomes much more significant under the more severe conditions of the Motor Octane method than the Research Octane method. (author)

  6. An experimental investigation of low octane gasoline in diesel engines.

    SciTech Connect (OSTI)

    Ciatti, S. A.; Subramanian, S. (Energy Systems)

    2011-09-01T23:59:59.000Z

    Conventional combustion techniques struggle to meet the current emissions norms. In particular, oxides of nitrogen (NO{sub x}) and particulate matter (PM) emissions have limited the utilization of diesel fuel in compression ignition engines. Advance combustion concepts have proved the potential to combine fuel efficiency and improved emission performance. Low-temperature combustion (LTC) offers reduced NO{sub x} and PM emissions with comparable modern diesel engine efficiencies. The ability of premixed, low-temperature compression ignition to deliver low PM and NO{sub x} emissions is dependent on achieving optimal combustion phasing. Diesel operated LTC is limited by early knocking combustion, whereas conventional gasoline operated LTC is limited by misfiring. So the concept of using an unconventional fuel with the properties in between those two boundary fuels has been experimented in this paper. Low-octane (84 RON) gasoline has shown comparable diesel efficiencies with the lowest NO{sub x} emissions at reasonable high power densities (NO{sub x} emission was 1 g/kW h at 12 bar BMEP and 2750 rpm).

  7. Exploring the use of a higher octane gasoline for the U.S. light-duty vehicle fleet

    E-Print Network [OSTI]

    Chow, Eric W

    2013-01-01T23:59:59.000Z

    This thesis explores the possible benefits that can be achieved if U.S. oil companies produced and offered a grade of higher-octane gasoline to the consumer market. The octane number of a fuel represents how resistant the ...

  8. An Experimental Investigation of Low Octane Gasoline in Diesel...

    Broader source: Energy.gov (indexed) [DOE]

    Mixture Preparation Chemical Properties Pressure & Temperature (air preheating, Turbo charging, EGR & compression ratio) Octane rating, cetane rating (Fuels & Additives)...

  9. Proton NMR analysis of octane number for motor gasoline: Part V

    SciTech Connect (OSTI)

    Ichikawa, M.; Nonaka, N.; Amano, H.; Takada, I.; Ishimori, S. [Suzuki Motor Corp., Hamamatsu (Japan); Andoh, H.; Kumamoto, K. [Showa Shell Sikiyu Tokyo (Japan)

    1992-10-01T23:59:59.000Z

    A method to predict the octane number of automobile gasoline containing methyl tert-butyl ether (MTBE) by proton magnetic resonance (PMR) spectrometry was studied. Samples of gasoline whose octane numbers had been identified according to the ASTM standards (commercially available premium gasoline to which MTBE was added at rates of 7 vol % and 14 vol %) were used in this investigation of the effect of MTBE on the octane number. The findings were utilized to introduce a term regarding MTBE into the previously reported linear regression equation for estimating the octane number from the PMR spectrum, and the appropriateness of the linear regression equation was assessed. As a result the MTBE contents in the sample were determined with satisfactory accuracy by using a standard addition method, and a linear regression equation reflecting the effect of MTBE was obtained. These achievements are reported. 11 refs., 3 figs., 5 tabs.

  10. energy savings by the use of mtbe to replace alkylate in automotive gasolines

    SciTech Connect (OSTI)

    Englin, B.A.; Emel'yanov, V.E.; Terent'ev, G.A.; Vinogradov, A.M.

    1986-07-01T23:59:59.000Z

    This paper presents data on the differences in energy consumption in the production of leaded and unleaded AI-93 gasolines with various blend components. The authors investigate as high-octane components certain products that are more effective in use and less energy-consuming in production in comparison with alkylate. In particular, methyl tert-butyl ether (MTBE) is discussed; it is not poisonous, it has a high heat of combustion, and it does not attack materials of construction. The addition of 11% MTBE to gasoline lowers the cold start temperature of engines by 10-12 degrees. Moreover, no adjustment of the carburetor is required for the changeover to gasoline with 11% MTBE.

  11. A near infrared regression model for octane measurements in gasolines which contain MTBE

    SciTech Connect (OSTI)

    Maggard, S.M. (Ashland Petroleum Co., KY (USA))

    1990-01-01T23:59:59.000Z

    Near infrared (NIR) spectroscopy has emerged as a superior technique for the on-line determination of octane during the blending of gasoline. This results from the numerous advantages that NIR spectroscopy has over conventional on-line instrumentation. Methyl t-butyl ether (MTBE) is currently the oxygenated blending component of choice. MTBE is advantageous because it has a high blending octane, a low Reid vapor pressure, is relatively cheap, and does not form peroxides (1). The goal of this project was to develop a NIR regression model that could be used to predict pump octanes regardless of whether they contained MTBE.

  12. Raman Scattering Sensor for Control of the Acid Alkylation Process in Gasoline Production

    SciTech Connect (OSTI)

    Uibel, Rory, H.; Smith, Lee M.; Benner, Robert, E.

    2006-04-19T23:59:59.000Z

    Gasoline refineries utilize a process called acid alkylation to increase the octane rating of blended gasoline, and this is the single most expensive process in the refinery. For process efficiency and safety reasons, the sulfuric acid can only be used while it is in the concentration range of 98 to 86 %. The conventional technique to monitor the acid concentration is time consuming and is typically conducted only a few times per day. This results in running higher acid concentrations than they would like to ensure that the process proceeds uninterrupted. Maintaining an excessively high acid concentration costs the refineries millions of dollars each year. Using SBIR funding, Process Instruments Inc. has developed an inline sensor for real time monitoring of acid concentrations in gasoline refinery alkylation units. Real time data was then collected over time from the instrument and its responses were matched up with the laboratory analysis. A model was then developed to correlate the laboratory acid values to the Raman signal that is transmitted back to the instrument from the process stream. The instrument was then used to demonstrate that it could create real-time predictions of the acid concentrations. The results from this test showed that the instrument could accurately predict the acid concentrations to within ~0.15% acid strength, and this level of prediction proved to be similar or better then the laboratory analysis. By utilizing a sensor for process monitoring the most economic acid concentrations can be maintained. A single smaller refinery (50,000 barrels/day) estimates that they should save over $120,000/year, with larger refineries saving considerably more.

  13. A complex chemical kinetic mechanism for the oxidation of gasoline surrogate fuels: n heptane, iso octane and toluene - Mechanism development and validation

    E-Print Network [OSTI]

    Da Cruz, A Pires; Anderlohr, Jörg; Bounaceur, Roda; Battin-Leclerc, Frédérique

    2009-01-01T23:59:59.000Z

    The development and validation against experimental results of a new gasoline surrogate complex kinetic mechanism is presented in this paper. The surrogate fuel is a ternary mixture of n heptane, iso octane and toluene. The full three components mechanism is based on existing n heptane/iso octane (gasoline PRF) and toluene mechanisms which were modified and coupled for the purpose of this work. Mechanism results are compared against available experimental data from the literature. Simulations with the PRF plus toluene mechanism show that its behavior is in agreement with experimental results for most of the tested settings. These include a wide variety of thermodynamic conditions and fuel proportions in experimental configurations such as HCCI engine experiments, rapid compression machines, a shock tube and a jet stirred reactor.

  14. Premium Gasoline Overbuying in the U.S.: Consumer-Based Choice Analysis

    E-Print Network [OSTI]

    Setiawan, Winardi; Sperling, Daniel

    1993-01-01T23:59:59.000Z

    1990), Economics gasoline pool octane of growth, U.S.sensitive to modest is gasoline price shifts. Theprimary1991b), Effect of gasoline octane quality on vehicle

  15. Premium Gasoline Overbuying in the U.S.: Consumer-Based Choice Analysis

    E-Print Network [OSTI]

    Setiawan, Winardi; Sperling, Daniel

    2001-01-01T23:59:59.000Z

    1990), Economics gasoline pool octane of growth, U.S.sensitive to modest is gasoline price shifts. Theprimary1991b), Effect of gasoline octane quality on vehicle

  16. Add MTBE unit ahead of alkylation

    SciTech Connect (OSTI)

    Masters, K.R.; Prohaska, E.A.

    1988-08-01T23:59:59.000Z

    Approximately three years ago, the people at Diamond Shamrock's Sunray, Texas, refinery recognized a growing demand for high octane super premium unleaded gasoline in their regional marketing area. It was apparent that they would need to change their processing scheme to meet this growing demand. After investigating several options, they decided to install an MTBE (methyl tert-butyl ether) unit upstream of their existing sulfuric acid (H/sub 2/SO/sub 4/) aklylation unit. The new unit would process olefin feed before it entered the alkylation unit. The MTBE unit was expected to improve Diamond Shamrock's gasoline pool in two ways. First, the MTBE would be an additional high octane blending stock for the gasoline pool. Second, the MTBE unit would improve the quality of the olefin stream going to the alkylation unit. Diamond Shamrock brought their MTBE unit onstream in December, 1985. The results of the combined operation exceeded expectations, producing alkylate in excess of 98 RON (Research octane number) and MTBE of 118 RON. These components significantly upgraded the refinery's capability to produce a super premium unleaded gasoline.

  17. Gasoline marketing

    SciTech Connect (OSTI)

    Metzenbaum, H.M.

    1991-02-01T23:59:59.000Z

    Consumers have the option of purchasing several different grades of unleaded gasoline regular, mid-grade, and premium which are classified according to an octane rating. Because of concern that consumers may be needlessly buying higher priced premium unleaded gasoline for their automobiles when regular unleaded gasoline would meet their needs, this paper determines whether consumers were buying premium gasoline that they may not need, whether the higher retail price of premium gasoline includes a price mark-up added between the refinery and the retail pump which is greater than that included in the retail price for regular gasoline, and possible reasons for the price differences between premium and regular gasoline.

  18. Pool octanes via oxygenates

    SciTech Connect (OSTI)

    Prezelj, M.

    1987-09-01T23:59:59.000Z

    Increasingly stringent antipollution regulations placed on automobile exhaust gases with consequent reduction or complete lead ban from motor gasoline result in octane shortage at many manufacturing sites. Attractive solutions to this problem, especially in conjunction with abundant methanol supplies, are the hydration and etherification of olefins contained in light product streams from cracking unit or produced by field gas dehydrogenation. A comparison is made between oxygenates octane-volume pool contributions and established refinery technologies. Process reviews for bulk manufacture of fuel-grade isopropanol (IPA), secondary butanol (SBA), tertiary butanol (TBA), methyl tertiary butyl ether (MTBE) and tertiary amyl methyl ether (TAME) are presented together with the characteristic investment and operating data. The implantation of these processes into a typical FCCU refinery complex with the resulting octane-pool improvement possibilities is descried.

  19. Estimate octane numbers using an enhanced method

    SciTech Connect (OSTI)

    Twu, C.H.; Coon, J.E. [Simulation Sciences Inc., Brea, CA (United States)

    1997-03-01T23:59:59.000Z

    An improved model, based on the Twu-Coon method, is not only internally consistent, but also retains the same level of accuracy as the previous model in predicting octanes of gasoline blends. The enhanced model applies the same binary interaction parameters to components in each gasoline cut and their blends. Thus, the enhanced model can blend gasoline cuts in any order, in any combination or from any splitting of gasoline cuts and still yield the identical value of octane number for blending the same number of gasoline cuts. Setting binary interaction parameters to zero for identical gasoline cuts during the blending process is not required. The new model changes the old model`s methodology so that the same binary interaction parameters can be applied between components inside a gasoline cut as are applied to the same components between gasoline cuts. The enhanced model is more consistent in methodology than the original model, but it has equal accuracy for predicting octane numbers of gasoline blends, and it has the same number of binary interaction parameters. The paper discusses background, enhancement of the Twu-Coon interaction model, and three examples: blend of 2 identical gasoline cuts, blend of 3 gasoline cuts, and blend of the same 3 gasoline cuts in a different order.

  20. Process for reforming naphthene and paraffin-containing hydrocarbons in the naphtha boiling range and isomerizing C sub 5 -C sub 6 normal paraffin feedstock to produce a high octane gasoline

    SciTech Connect (OSTI)

    Dalson, M.H.

    1990-05-08T23:59:59.000Z

    This patent describes a process for reforming a naphthenic and paraffin-containing hydrocarbon feedstock to produce a reformate product having an increased octane rating by contacting the feedstock with a reforming catalyst in the presence of hydrogen at reforming conditions in a reforming zone, the reforming zone including a naphtha dehydrogenation zone and a paraffin dehydrocyclization zone wherein heated, pressurized hydrogen is added to the effluent stream from the naphtha dehydrogenation zone prior to charging the effluent stream to the paraffin dehydrocyclization zone to produce a first product stream comprising a gasoline range reformate product having an RON octane rating of at least about 90 and hydrogen wherein the reformate product is separated from the hydrogen in a reformate separation zone. It comprises: charging at least a portion of the heated, pressurized hydrogen with a C{sub 5}-C{sub 6} n-paraffin feedstock to an isomerization zone containing an isomerization catalyst at isomerization conditions to produce a second product stream containing an isomerized C{sub 5}-C{sub 6} product and passing the second product stream to the reformate separation zone and recovering at least a major portion of the isomerized C{sub 5}-C{sub 6} product with the reformate product.

  1. Predict octane numbers using a generalized interaction method

    SciTech Connect (OSTI)

    Twu, C.H.; Coon, J.E. [Simulation Sciences, Inc., Brea, CA (United States)

    1996-02-01T23:59:59.000Z

    An interaction-based correlation using a new approach can be used to predict research and motor octane numbers of gasoline blends. An ultimately detailed analysis of the gasoline cut is not necessary. This correlation can describe blending behavior over the entire composition range of gasoline cuts. The component-oriented interaction approach is general and will accurately predict, without performing additional blending studies, blending behavior for new gasoline cuts. The proposed correlation fits the data quite closely for blends of many gasoline cuts. The regression gives realistic values for binary interaction parameters between components. A unique set of binary interaction parameters was found for the equation for predicting octane number of any gasoline blend. The binary interaction parameters between components contained in gasoline cuts have been converted to binary interaction parameters between gasoline cuts through a general equation to simplify the calculations. Because of the proposed method`s accuracy, optimum allocation of components among gasoline grades can be obtained and predicted values can be used for quality control of the octane number of marketed gasolines.

  2. Ethers help gasoline quality

    SciTech Connect (OSTI)

    Chang, E.J.; Leiby, S.M. (SRI International, Menlo Park, CA (US))

    1992-02-01T23:59:59.000Z

    In this article three scenarios to evaluate the effect of etherification on gasoline production and quality are reviewed: Base case FCC/C{sub 4} alkylation complex - FCC unit operation for maximum gasoline yield, MTBE unit added to base case FCC unit operation and MTBE unit added to maximum olefins FCC unit operation. Details of the FCC, MTBE and C{sub 4} alkylation operations used in this article are reviewed, followed by a discussion of overall results.

  3. NATCOR -Xpress case study Margaret Oil produces three products: gasoline, jet fuel, and heating oil. The average

    E-Print Network [OSTI]

    Hall, Julian

    NATCOR - Xpress case study Margaret Oil produces three products: gasoline, jet fuel, and heating oil. The average octane levels must be at least 8.5 for gasoline, 7 for jet fuel, and 4.5 for heating to produce gasoline or jet fuel. Distilled oil can be used to produce all three products. The octane level

  4. Review of market for octane enhancers: Final report

    SciTech Connect (OSTI)

    J. E. Sinor Consultants, Inc.

    2000-06-20T23:59:59.000Z

    Crude oil is easily separated into its principal products by simple distillation. However, neither the amounts nor the quality of these natural products matches demand. Today, octane requirements must be achieved by changing the chemical composition of the straight-run gasoline fraction.

  5. Ethers have good gasoline-blending attributes

    SciTech Connect (OSTI)

    Unzelman, G.H.

    1989-04-10T23:59:59.000Z

    Because of their compatibility with hydrocarbon gasoline-blending components, their high octane blending values, and their low volatility blending values, ethers will grow in use as gasoline blending components. This article discusses the properties of ethers as blending components, and environmental questions.

  6. MTBE growth limited despite lead phasedown in gasoline

    SciTech Connect (OSTI)

    Storck, W.

    1985-07-15T23:59:59.000Z

    This month's legislated reduction of the allowable amount of lead additives in gasoline will increase demand strongly for methyl-tert-butyl ether (MTBE) as an octane enhancer, but the economics of the refinery business and the likelihood of rapidly increasing high-octane gasoline imports probably will limit the size of the business in coming years. MTBE will be used to fill the octane gap now, but economics and imports of gasoline later on could hold down demand. The limited growth in sales of MTBE is discussed.

  7. RELATIONS BETWEEN THE DETECTION OF METHYL TERT-BUTYL ETHER (MTBE) IN SURFACE AND GROUND WATER AND ITS CONTENT IN GASOLINE

    E-Print Network [OSTI]

    AND ITS CONTENT IN GASOLINE By Michael J. Moran, Mike J. Halde, Rick M. Clawges and John S. Zogorski U in the United States as an octane enhancer and oxygenate in gasoline. Octane enhancement began in the late 1970's with the phase-out of tetraethyl lead from gasoline. The use of oxygenates was expanded

  8. Novel anisole mixture and gasoline containing the same

    DOE Patents [OSTI]

    Singerman, Gary M. (Monroeville, PA)

    1982-01-26T23:59:59.000Z

    A novel anisole mixture containing anisole and a mixture of alkyl anisoles and liquid hydrocarbon fuels containing said novel anisole mixture in an amount sufficient to increase the octane number of said liquid fuel composition.

  9. NATCOR -Xpress case study (advanced) Margaret Oil produces three products: gasoline, jet fuel, and heating oil. The average

    E-Print Network [OSTI]

    Hall, Julian

    NATCOR - Xpress case study (advanced) Margaret Oil produces three products: gasoline, jet fuel, and heating oil. The average octane levels must be at least 8.5 for gasoline, 7 for jet fuel, and 4. Distilled naphtha can be used only to produce gasoline or jet fuel. Distilled oil can be used to produce

  10. Interaction blending equations enhance reformulated gasoline profitability

    SciTech Connect (OSTI)

    Snee, R.D. (Joiner Associates, Madison, WI (United States)); Morris, W.E.; Smith, W.E.

    1994-01-17T23:59:59.000Z

    The interaction approach to gasoline blending gives refiners an accurate, simple means of re-evaluating blending equations and increasing profitability. With reformulated gasoline specifications drawing near, a detailed description of this approach, in the context of reformulated gasoline is in order. Simple mathematics compute blending values from interaction equations and interaction coefficients between mixtures. A timely example of such interactions is: blending a mixture of catalytically cracked gasoline plus light straight run (LSR) from one tank with alkylate plus reformate from another. This paper discusses blending equations, using interactions, mixture interactions, other blending problems, and obtaining equations.

  11. MTBE, Oxygenates, and Motor Gasoline (Released in the STEO October 1999)

    Reports and Publications (EIA)

    1999-01-01T23:59:59.000Z

    The blending of methyl tertiary butyl ether (MTBE) into motor gasoline has increased dramatically since it was first produced 20 years ago. MTBE usage grew in the early 1980's in response to octane demand resulting initially from the phaseout of lead from gasoline and later from rising demand for premium gasoline. The oxygenated gasoline program stimulated an increase in MTBE production between 1990 and 1994. MTBE demand increased from 83,000 in 1990 to 161,000 barrels per day in 1994. The reformulated gasoline (RFG) program provided a further boost to oxygenate blending. The MTBE contained in motor gasoline increased to 269,000 barrels per day by 1997.

  12. Combustion behavior of gasoline and gasoline/ethanol blends in a modern direct-injection 4-cylinder engine.

    SciTech Connect (OSTI)

    Wallner, T.; Miers, S. A. (Energy Systems)

    2008-04-01T23:59:59.000Z

    Early in 2007 President Bush announced in his State of the Union Address a plan to off-set 20% of gasoline with alternative fuels in the next ten years. Ethanol, due to its excellent fuel properties for example, high octane number, renewable character, etc., appears to be a favorable alternative fuel from an engine perspective. Replacing gasoline with ethanol without any additional measures results in unacceptable disadvantages mainly in terms of vehicle range.

  13. An Experimental Investigation of Low Octane Gasoline in Diesel Engines |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-Up fromDepartment ofEnergy Natural Gas:Austin,An Evaluation of

  14. Electric car Gasoline car

    E-Print Network [OSTI]

    ENAC/ Electric car (Renault) Gasoline car (competitors) Gasoline car (Renault) Market shares of an electric vehicle? Electric car (Renault) Gasoline car (competitors) Gasoline car (Renault) Market shares preference survey with choice situation contexts involving gasoline cars (Renault and competitors

  15. Motor gasolines, winter 1981-1982

    SciTech Connect (OSTI)

    Shelton, E M

    1982-07-01T23:59:59.000Z

    Analytical data for 905 samples of motor gasoline, were collected from service stations throughout the country and were analyzed in the laboratories of various refiners, motor manufacturers, and chemical companies. The data were submitted to the Bartlesville Energy Technology Center for study, necessary calculations, and compilation under a cooperative agreement between the Bartlesville Energy Technology Center (BETC) and the American Petroleum Institute (API). The samples represent the products of 30 companies, large and small, which manufacture and supply gasoline. These data are tabulated by groups according to brands (unlabeled) and grades for 17 marketing districts into which the country is divided. A map included in this report, shows marketing areas, districts and sampling locations. The report also includes charts indicating the trends of selected properties of motor fuels since winter 1959-1960 survey for the leaded gasolines, and since winter 1979-1980 survey for the unleaded gasolines. Sixteen octane distribution percent charts for areas 1, 2, 3, and 4 for unleaded antiknock index (R+M)/2 below 90.0, unleaded antiknock index (R+M)/2 90.0 and above, leaded antiknock index (R+M)/2 below 93.0, and leaded antiknock index (R+M)/2 93.0 and above grades of gasoline are presented in this report. The antiknock (octane) index (R+M)/2 averages of gasoline sold in this country were 87.4 for unleaded below 90.0, 91.7 for unleaded 90.0 and above, and 88.9 for leaded below 93.0. Only one sample was reported as 93.0 for leaded gasolines with an antiknock index (R+M)/2 93.0 and above.

  16. The Performance of Gasoline Fuels and Surrogates in Gasoline...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    The Performance of Gasoline Fuels and Surrogates in Gasoline HCCI Combustion The Performance of Gasoline Fuels and Surrogates in Gasoline HCCI Combustion Almost 2 dozen gasoline...

  17. The Impact of Low Octane Hydrocarbon Blending Streams on Ethanol Engine Optimization

    SciTech Connect (OSTI)

    Szybist, James P [ORNL] [ORNL; West, Brian H [ORNL] [ORNL

    2013-01-01T23:59:59.000Z

    Ethanol is a very attractive fuel from an end-use perspective because it has a high chemical octane number and a high latent heat of vaporization. When an engine is optimized to take advantage of these fuel properties, both efficiency and power can be increased through higher compression ratio, direct fuel injection, higher levels of boost, and a reduced need for enrichment to mitigate knock or protect the engine and aftertreatment system from overheating. The ASTM D5798 specification for high level ethanol blends, commonly called E85, underwent a major revision in 2011. The minimum ethanol content was revised downward from 68 vol% to 51 vol%, which combined with the use of low octane blending streams such as natural gasoline introduces the possibility of a lower octane E85 fuel. While this fuel is suitable for current ethanol tolerant flex fuel vehicles, this study experimentally examines whether engines can still be aggressively optimized for the resultant fuel from the revised ASTM D5798 specification. The performance of six ethanol fuel blends, ranging from 51-85% ethanol, is compared to a premium-grade certification gasoline (UTG-96) in a single-cylinder direct-injection (DI) engine with a compression ratio of 12.9:1 at knock-prone engine conditions. UTG-96 (RON = 96.1), light straight run gasoline (RON = 63.6), and n-heptane (RON = 0) are used as the hydrocarbon blending streams for the ethanol-containing fuels in an effort to establish a broad range of knock resistance for high ethanol fuels. Results show that nearly all ethanol-containing fuels are more resistant to engine knock than UTG-96 (the only exception being the ethanol blend with 49% n-heptane). This knock resistance allows ethanol blends made with 33 and 49% light straight run gasoline, and 33% n-heptane to be operated at significantly more advanced combustion phasing for higher efficiency, as well as at higher engine loads. While experimental results show that the octane number of the hydrocarbon blend stock does impact engine performance, there remains a significant opportunity for engine optimization when considering even the lowest octane fuels that are in compliance with the current revision of ASTM D5798 compared to premium-grade gasoline.

  18. High Octane Fuels Can Make Better Use of Renewable Transportation...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High Octane Fuels Can Make Better Use of Renewable Transportation Fuels High Octane Fuels Can Make Better Use of Renewable Transportation Fuels Breakout Session 1C-Fostering...

  19. Mapping surrogate gasoline compositions into RON/MON space

    SciTech Connect (OSTI)

    Morgan, Neal; Kraft, Markus [Department of Chemical Engineering, University of Cambridge, Cambridge CB2 3RA (United Kingdom); Smallbone, Andrew; Bhave, Amit [Reaction Engineering Solutions Ltd., 61 Canterbury Street, Cambridge CB4 3QG (United Kingdom); Cracknell, Roger; Kalghatgi, Gautam [Shell Global Solutions, Shell Technology Centre Thornton, P.O. Box 1, Chester CH1 3SH (United Kingdom)

    2010-06-15T23:59:59.000Z

    In this paper, new experimentally determined octane numbers (RON and MON) of blends of a tri-component surrogate consisting of toluene, n-heptane, i-octane (called toluene reference fuel TRF) arranged in an augmented simplex design are used to derive a simple response surface model for the octane number of any arbitrary TRF mixture. The model is second-order in its complexity and is shown to be more accurate to the standard ''linear-by-volume'' (LbV) model which is often used when no other information is available. Such observations are due to the existence of both synergistic and antagonistic blending of the octane numbers between the three components. In particular, antagonistic blending of toluene and iso-octane leads to a maximum in sensitivity that lies on the toluene/iso-octane line. The model equations are inverted so as to map from RON/MON space back into composition space. Enabling one to use two simple formulae to determine, for a given fuel with known RON and MON, the volume fractions of toluene, n-heptane and iso-octane to be blended in order to emulate that fuel. HCCI engine simulations using gasoline with a RON of 98.5 and a MON of 88 were simulated using a TRF fuel, blended according to the derived equations to match the RON and MON. The simulations matched the experimentally obtained pressure profiles well, especially when compared to simulations using only PRF fuels which matched the RON or MON. This suggested that the mapping is accurate and that to emulate a refinery gasoline, it is necessary to match not only the RON but also the MON of the fuel. (author)

  20. The MTBE solution: Octanes, technology, and refinery profitability

    SciTech Connect (OSTI)

    Lander, E.P.; Hubbard, J.N.; Smith, L.A.

    1983-03-01T23:59:59.000Z

    This paper has been developed to provide refiners with business decision insight regarding the production of methyl tertiary butyl ether (MTBE) from refinery - (FCC) produced isobutylene. The driving forces making MTBE an attractive investment are examined with regard to the increasing demand for higher octane unleaded gasolines. The decision to proceed with MTBE production depends on the profitability of such an investment and the refiner's ability to meet market demands using available processing equipment, refinery produced streams and external feedstocks. The factors affecting this decision are analyzed in this paper and include: industry ability to meet rising octane demand; profit potential realized by diverting isobutylene to MTBE; availability of technology for producing MTBE; and investment and operating costs required to produce MTBE. Chemical Research and Licensing and NEOCHEM have developed a simple, low cost process to produce MTBE, reducing the excessive equipment and high operating costs that were associated with conventional MTBE designs. The economics and process benefits of installing a CRandL/NEOCHEM MTBE process are examined within the framework of a generalized medium-sized refinery configuration.

  1. CRC fuel rating program: road octane performance of oxygenates in 1982 model cars

    SciTech Connect (OSTI)

    Not Available

    1985-07-01T23:59:59.000Z

    Because of the widespread interest in the use of alcohols and ethers as gasoline blending components, this program was conducted to evaluate the effects of several oxygenates on gasoline octane performance and to evaluate the effects of car design features such as engine and transmission type. Five oxygenates were evaluated at two nominal concentrations, 5 and 10 volume%, at both regular- and premium-grade octane levels: methanol (MeOH), ethanol (ETOH), isopropanol (IPA), tertiary butanol (TBA), and methyl tertiary butyl ether (MTBE). A blend of 5% MeOH and 5 percent TBA was also tested at both octane levels. Twenty-eight unleaded fuels, including four hydrocarbon fuels, two hydrocarbon fuels plus toluene, and twenty-two oxygenated fuels, were rated in duplicate in thirty-eight cars using the Modified Uniontown Technique (CRC Designation F-28-75 described in Appendix C), plus some additional instructions. All testing was done on chassis dynamometers. Ratings were obtained at full throttle with all thirty-eight cars, and at the most critical part-throttle condition (occurring with manifold vacuum of 4 in. Hg (13.5 kPa) or greater above the full-throttle vacuum) with nine cars.

  2. Net Taxable Gasoline Gallons (Including Aviation Gasoline)

    E-Print Network [OSTI]

    Net Taxable Gasoline Gallons (Including Aviation Gasoline) Period 2000 2001 (2) 2002 2003 2004 "gross" to "net" , was deemed impractical. (5) This report replaces the Gross Taxable Gasoline Gallons (Including Aviation Gasoline) report which will not be produced after December 2002. (6) The November 2007

  3. ON-LINE OPTIMIZATION, ENERGY ANALYSIS AND ENVIRONMENTAL IMPACT ASSESSMENT OF SULFURIC ACID CATALYZED ALKYLATION

    E-Print Network [OSTI]

    Pike, Ralph W.

    pool, increased amounts of gasoline per volume of crude oil and high heats of combustion. The overall in sulfuric acid consumption potentially could be obtained. 1. Introduction Alkylation process is one

  4. Ashland's new process could boost gasoline yield

    SciTech Connect (OSTI)

    Atkins, O.E.

    1980-04-07T23:59:59.000Z

    According to O. E. Atkins (Ashland Oil Co.), Ashland's new fluid catalytic cracking process will convert heavy residual oil to (% by vol) 11% fuel gas, 4.8% LNG, 75.7% gasoline (if all the produced olefins are converted to gasoline), 9% distillates, and 8.1% heavy fuel oil. Ashland is building a $70 million, 40,000 bbl/day unit at its 215,000 bbl/day Catlettsburg, Ky., refinery which will increase the present 90,000 bbl/day gasoline yield by 25,000 bbl/day for the same amount of feedstock. The increased gasoline yield (no-lead octane rating of 94) is expected to increase the net margin on a barrel of feed from $8 up to $12, at the present prices of $11.50/bbl of residual oil and $40/bbl of gasoline. Ashland has not disclosed detailed information on the new process, which: can accommodate atmospheric residua that are high in sulfur and metals; is a high temperature, low (about 1 atm) pressure process; does not use hydrogen; uses a proprietary new crystalline silica-alumina microspherical (zeolite) catalyst which, via a proprietary passivating technique, will demetalize crude oil fractions of vanadium and nickel. Residuum cracking processes developed by other companies are briefly discussed.

  5. Ethanol Demand in United States Gasoline Production

    SciTech Connect (OSTI)

    Hadder, G.R.

    1998-11-24T23:59:59.000Z

    The Oak Ridge National Laboratory (OWL) Refinery Yield Model (RYM) has been used to estimate the demand for ethanol in U.S. gasoline production in year 2010. Study cases examine ethanol demand with variations in world oil price, cost of competing oxygenate, ethanol value, and gasoline specifications. For combined-regions outside California summer ethanol demand is dominated by conventional gasoline (CG) because the premised share of reformulated gasoline (RFG) production is relatively low and because CG offers greater flexibility for blending high vapor pressure components like ethanol. Vapor pressure advantages disappear for winter CG, but total ethanol used in winter RFG remains low because of the low RFG production share. In California, relatively less ethanol is used in CG because the RFG production share is very high. During the winter in California, there is a significant increase in use of ethanol in RFG, as ethanol displaces lower-vapor-pressure ethers. Estimated U.S. ethanol demand is a function of the refiner value of ethanol. For example, ethanol demand for reference conditions in year 2010 is 2 billion gallons per year (BGY) at a refiner value of $1.00 per gallon (1996 dollars), and 9 BGY at a refiner value of $0.60 per gallon. Ethanol demand could be increased with higher oil prices, or by changes in gasoline specifications for oxygen content, sulfur content, emissions of volatile organic compounds (VOCS), and octane numbers.

  6. Gasoline vapor recovery

    SciTech Connect (OSTI)

    Lievens, G.; Tiberi, T.P.

    1993-06-22T23:59:59.000Z

    In a gasoline distribution network wherein gasoline is drawn from a gasoline storage tank and pumped into individual vehicles and wherein the gasoline storage tank is refilled periodically from a gasoline tanker truck, a method of recovering liquid gasoline from gasoline vapor that collects in the headspace of the gasoline storage tank as the liquid gasoline is drawn therefrom, said method comprising the steps of: (a) providing a source of inert gas; (b) introducing inert gas into the gasoline storage tank as liquid gasoline is drawn therefrom so that liquid gasoline drawn from the tank is displaced by inert gas and gasoline vapor mixes with the inert gas in the headspace of the tank; (c) collecting the inert gas/gasoline vapor mixture from the headspace of the gasoline storage tank as the tank is refilled from a gasoline tanker truck; (d) cooling the inert gas/gasoline vapor mixture to a temperature sufficient to condense the gasoline vapor in the mixture to liquid gasoline but not sufficient to liquify the inert gas in the mixture; (e) separating the condensed liquid gasoline from the inert gas; and delivering the condensed liquid gasoline to a remote location for subsequent use.

  7. Detailed kinetic models for the low-temperature auto ignition of gasoline surrogates

    E-Print Network [OSTI]

    Bounaceur, Roda; Fournet, René; Warth, Valérie; Battin-Leclerc, Frédérique

    2009-01-01T23:59:59.000Z

    In the context of the search for gasoline surrogates for kinetic modeling purpose, this paper describes a new model for the low-temperature auto-ignition of n-heptane/iso-octane/hexene/toluene blends for the different linear isomers of hexene. The model simulates satisfactory experimental results obtained in a rapid compression machine for temperatures ranging from 650 to 850 K in the case of binary and ternary mixtures including iso octane, 1-hexene and toluene. Predictive simulations have also been performed for the autoignition of n heptane/iso octane/hexene/toluene quaternary mixtures: the predicted reactivity is close to that of pure iso octane with a retarding effect when going from 1- to 3-alkene.

  8. Liquid-liquid equilibria for the ternary systems sulfolane + octane + benzene, sulfolane + octane + toluene and sulfolane + octane + p-xylene

    SciTech Connect (OSTI)

    Lee, S.; Kim, H. [Seoul National Univ. (Korea, Republic of). Dept. of Chemical Engineering

    1995-03-01T23:59:59.000Z

    Sulfolane is widely used as a solvent for the extraction of aromatic hydrocarbons. Ternary phase equilibrium data are essential for the proper understanding of the solvent extraction process. Liquid-liquid equilibrium data for the systems sulfolane + octane + benzene, sulfolane + octane + toluene and sulfolane + octane + p-xylene were determined at 298.15, 308.15, and 318.15 K. Tie line data were satisfactorily correlated by the Othmer and Tobias method. The experimental data were compared with the values calculated by the UNIQUAC and NRTL models. Good quantitative agreement was obtained with these models. However, the calculated values based on the NRTL model were found to be better than those based on the UNIQUAC model.

  9. ETBE as a gasoline blending component. The experience of Elf Aquitaine

    SciTech Connect (OSTI)

    Chatin, L.; Fombarlet, C.; Bernasconi, C.; Gauthier, A.; Schmelzle, P.

    1994-10-01T23:59:59.000Z

    This study, led by Elf Aquitaine for several years, shows the possibility to use ETBE instead of MTBE as a gasoline component and compares properties of these two ethers regarding different parameters like octanes, volatility, engine cleanliness, stability of the ethers themselves and of gasoline blends, lubricant compatibility and toxicological data. ETBE appears at least as good as MTBE and sometimes better, as ETBE is chemically more similar to hydrocarbons than MTBE and can be used advantageously as a gasoline oxygenated component. 9 refs., 4 figs., 8 tabs.

  10. With Mathematica Gasoline Inventory

    E-Print Network [OSTI]

    Reiter, Clifford A.

    Preprint 1 With Mathematica and J: Gasoline Inventory Simulation Cliff Reiter Computational for the number of gallons of gasoline sold by a station for a thousand weeks. The pattern involves demands with the delivery and storage of the gasoline and we desire not to run out of gasoline or exceed the station

  11. [98e]-Catalytic reforming of gasoline and diesel fuel

    SciTech Connect (OSTI)

    Pereira, C.; Wilkenhoener, R.; Ahmed, S.; Krumpelt, M.

    2000-02-29T23:59:59.000Z

    Argonne National Laboratory is developing a fuel processor for converting liquid hydrocarbon fuels to a hydrogen-rich product suitable for a polymer electrolyte fuel cell stack. The processor uses an autothermal reformer to convert the feed to a mixture of hydrogen, carbon dioxide, carbon monoxide and water with trace quantities of other components. The carbon monoxide in the product gas is then converted to carbon dioxide in water-gas shift and preferential oxidation reactors. Fuels that have been tested include standard and low-sulfur gasoline and diesel fuel, and Fischer-Tropsch fuels. Iso-octane and n-hexadecane were also examined as surrogates for gasoline and diesel, respectively. Complete conversion of gasoline was achieved at 750 C in a microreactor over a novel catalyst developed at Argonne. Diesel fuel was completely converted at 850 C over this same catalyst. Product streams contained greater than 60% hydrogen on a dry, nitrogen-free basis with iso-octane, gasoline, and n-hexadecane. For a diesel fuel, product streams contained >50% hydrogen on a dry, nitrogen-free basis. The catalyst activity did not significantly decrease over >16 hours operation with the diesel fuel feed. Coke formation was not observed. The carbon monoxide fraction of the product gas could be reduced to as low as 1% on a dry, nitrogen-free basis when the water-gas shift reactors were used in tandem with the reformer.

  12. Reformulating Competition? Gasoline Content Regulation and Wholesale Gasoline Prices

    E-Print Network [OSTI]

    Brown, Jennifer; Hastings, Justine; Mansur, Erin T.; Villas-Boas, Sofia B

    2007-01-01T23:59:59.000Z

    Regulation and Arbitrage in Wholesale Gasoline Markets,Content Regulation and Wholesale Gasoline Prices JenniferCONTENT REGULATION AND WHOLESALE GASOLINE PRICES by Jennifer

  13. Production of methyl tert-alkyl ethers

    SciTech Connect (OSTI)

    Trofimov, V.A.

    1995-01-01T23:59:59.000Z

    The transition to the use of unleaded gasolines has required the replacement of tetraethyl lead by oxygen-containing compounds such as methanol, ethanol, and ethers, which are termed {open_quotes}oxygenates{close_quotes} in the technical literature. These may be used in commercial gasolines in amounts of 10-15% by volume, equivalent to 2% oxygen by weight. When methyl tert-butyl ether (MTBE) is used, the oxygen content may amount to 2.7% by weight. This oxygenate gives a significant improvement of knock resistance of naphtha fractions, the greatest effects being observed for straight-run naphthas and reformer naphthas produced under normal conditions; the MTBE also improves the engine power and economy characteristics and lowers the carbon monoxide content in the exhaust by 15-30% and the hydrocarbon content by 7-8%. This paper describes methods for the production of MTBE and also methyl tert-alkyl ethers.

  14. Use TAME and heavier ethers to improve gasoline properties

    SciTech Connect (OSTI)

    Ignatius, J.; Jaervelin, H.; Lindqvist, P. (Neste Engineering, Porvoo (Finland))

    1995-02-01T23:59:59.000Z

    Producing oxygenates from all potential FCC tertiary olefins is one of the most economic methods for reducing olefins and Reid vapor pressure (Rvp) in motor gasoline. MTBE production based on FCC isobutylene has reached a very high level. But the amount of MTBE from a refinery sidestream MTBE unit is insufficient for producing reformulated gasoline (RFG) and additional oxygenates must be purchased. The next phase will see conversion of isoamylenes in FCC light gasoline to TAME. Very little attention has been given to the heavier tertiary olefins present in the FCC light gasoline like tert-hexenes and heptenes. This route allows higher levels of oxygenates production, thereby lowering Rvp and the proportion of olefins in the gasoline pool and maximizing the use of FCC olefins. By using all the components produced by an FCC efficiently, many gasoline problems can be solved. Isobutene is converted to MTBE, C[sub 3]/C[sub 4] olefins are converted to alkylate and C[sub 5] tertiary olefins can be converted to TAME. All of these are preferred components for gasoline quality. By producing more oxygenates like MTBE, TAME and heavier ethers, a refinery can be self-sufficient in blending reformulated gasoline and no oxygenates need to be purchased. The technology for producing TAME and other ethers is described.

  15. Gasoline Biodesulfurization Fact Sheet

    Broader source: Energy.gov [DOE]

    This petroleum industry fact sheet describes how biodesulfurization can yield lower sulfur gasoline at lower production costs.

  16. Gasoline surrogate modeling of gasoline ignition in a rapid compression machine and comparison to experiments

    SciTech Connect (OSTI)

    Mehl, M; Kukkadapu, G; Kumar, K; Sarathy, S M; Pitz, W J; Sung, S J

    2011-09-15T23:59:59.000Z

    The use of gasoline in homogeneous charge compression ignition engines (HCCI) and in duel fuel diesel - gasoline engines, has increased the need to understand its compression ignition processes under engine-like conditions. These processes need to be studied under well-controlled conditions in order to quantify low temperature heat release and to provide fundamental validation data for chemical kinetic models. With this in mind, an experimental campaign has been undertaken in a rapid compression machine (RCM) to measure the ignition of gasoline mixtures over a wide range of compression temperatures and for different compression pressures. By measuring the pressure history during ignition, information on the first stage ignition (when observed) and second stage ignition are captured along with information on the phasing of the heat release. Heat release processes during ignition are important because gasoline is known to exhibit low temperature heat release, intermediate temperature heat release and high temperature heat release. In an HCCI engine, the occurrence of low-temperature and intermediate-temperature heat release can be exploited to obtain higher load operation and has become a topic of much interest for engine researchers. Consequently, it is important to understand these processes under well-controlled conditions. A four-component gasoline surrogate model (including n-heptane, iso-octane, toluene, and 2-pentene) has been developed to simulate real gasolines. An appropriate surrogate mixture of the four components has been developed to simulate the specific gasoline used in the RCM experiments. This chemical kinetic surrogate model was then used to simulate the RCM experimental results for real gasoline. The experimental and modeling results covered ultra-lean to stoichiometric mixtures, compressed temperatures of 640-950 K, and compression pressures of 20 and 40 bar. The agreement between the experiments and model is encouraging in terms of first-stage (when observed) and second-stage ignition delay times and of heat release rate. The experimental and computational results are used to gain insight into low and intermediate temperature processes during gasoline ignition.

  17. The Impact of Low Octane Hydrocarbon Blending Streams on "E85...

    Broader source: Energy.gov (indexed) [DOE]

    The Impact of Low Octane Hydrocarbon Blending Streams on "E85" Engine Optimization The Impact of Low Octane Hydrocarbon Blending Streams on "E85" Engine Optimization...

  18. Reformulating Competition? Gasoline Content Regulation and Wholesale Gasoline Prices

    E-Print Network [OSTI]

    Brown, Jennifer; Hastings, Justine; Mansur, Erin T.; Villas-Boas, Sofia B

    2007-01-01T23:59:59.000Z

    and Heterogeneity in U.S. Gasoline Prices, working paper,and J. M . Perloff, 2002. Gasoline Price Differences: Taxes,Gardner, K.W. , 2004. U.S. Gasoline Requirements, ExxonMobil

  19. Chemistry Impacts in Gasoline HCCI

    SciTech Connect (OSTI)

    Szybist, James P [ORNL; Bunting, Bruce G [ORNL

    2006-09-01T23:59:59.000Z

    The use of homogeneous charge compression ignition (HCCI) combustion in internal combustion engines is of interest because it has the potential to produce low oxides of nitrogen (NOx) and particulate matter (PM) emissions while providing diesel-like efficiency. In HCCI combustion, a premixed charge of fuel and air auto-ignites at multiple points in the cylinder near top dead center (TDC), resulting in rapid combustion with very little flame propagation. In order to prevent excessive knocking during HCCI combustion, it must take place in a dilute environment, resulting from either operating fuel lean or providing high levels of either internal or external exhaust gas recirculation (EGR). Operating the engine in a dilute environment can substantially reduce the pumping losses, thus providing the main efficiency advantage compared to spark-ignition (SI) engines. Low NOx and PM emissions have been reported by virtually all researchers for operation under HCCI conditions. The precise emissions can vary depending on how well mixed the intake charge is, the fuel used, and the phasing of the HCCI combustion event; but it is common for there to be no measurable PM emissions and NOx emissions <10 ppm. Much of the early HCCI work was done on 2-stroke engines, and in these studies the CO and hydrocarbon emissions were reported to decrease [1]. However, in modern 4-stroke engines, the CO and hydrocarbon emissions from HCCI usually represent a marked increase compared with conventional SI combustion. This literature review does not report on HCCI emissions because the trends mentioned above are well established in the literature. The main focus of this literature review is the auto-ignition performance of gasoline-type fuels. It follows that this discussion relies heavily on the extensive information available about gasoline auto-ignition from studying knock in SI engines. Section 2 discusses hydrocarbon auto-ignition, the octane number scale, the chemistry behind it, its shortcomings, and its relevance to HCCI. Section 3 discusses the effects of fuel volatility on fuel and air mixing and the consequences it has on HCCI. The effects of alcohol fuels on HCCI performance, and specifically the effects that they have on the operable speed/load range, are reviewed in Section 4. Finally, conclusions are drawn in Section 5.

  20. Three-stage autoignition of gasoline in an HCCI engine: An experimental and chemical kinetic modeling investigation

    SciTech Connect (OSTI)

    Machrafi, Hatim; Cavadias, Simeon [UPMC Universite Paris 06, LGPPTS, Ecole Nationale Superieure de Chimie de Paris (France); UPMC Universite Paris 06, Institut Jean Le Rond D'Alembert (France)

    2008-12-15T23:59:59.000Z

    The alternative HCCI combustion mode presents a possible means for decreasing the pollution with respect to conventional gasoline or diesel engines, while maintaining the efficiency of a diesel engine or even increasing it. This paper investigates the possibility of using gasoline in an HCCI engine and analyzes the autoignition of gasoline in such an engine. The compression ratio that has been used is 13.5, keeping the inlet temperature at 70 C, varying the equivalence ratio from 0.3 to 0.54, and the EGR (represented by N{sub 2}) ratio from 0 to 37 vol%. For comparison, a PRF95 and a surrogate containing 11 vol% n-heptane, 59 vol% iso-octane, and 30 vol% toluene are used. A previously validated kinetic surrogate mechanism is used to analyze the experiments and to yield possible explanations to kinetic phenomena. From this work, it seems quite possible to use the high octane-rated gasoline for autoignition purposes, even under lean inlet conditions. Furthermore, it appeared that gasoline and its surrogate, unlike PRF95, show a three-stage autoignition. Since the PRF95 does not contain toluene, it is suggested by the kinetic mechanism that the benzyl radical, issued from toluene, causes this so-defined ''obstructed preignition'' and delaying thereby the final ignition for gasoline and its surrogate. The results of the kinetic mechanism supporting this explanation are shown in this paper. (author)

  1. Process for conversion of lignin to reformulated, partially oxygenated gasoline

    DOE Patents [OSTI]

    Shabtai, Joseph S. (Salt Lake City, UT); Zmierczak, Wlodzimierz W. (Salt Lake City, UT); Chornet, Esteban (Golden, CO)

    2001-01-09T23:59:59.000Z

    A high-yield process for converting lignin into reformulated, partially oxygenated gasoline compositions of high quality is provided. The process is a two-stage catalytic reaction process that produces a reformulated, partially oxygenated gasoline product with a controlled amount of aromatics. In the first stage of the process, a lignin feed material is subjected to a base-catalyzed depolymerization reaction, followed by a selective hydrocracking reaction which utilizes a superacid catalyst to produce a high oxygen-content depolymerized lignin product mainly composed of alkylated phenols, alkylated alkoxyphenols, and alkylbenzenes. In the second stage of the process, the depolymerized lignin product is subjected to an exhaustive etherification reaction, optionally followed by a partial ring hydrogenation reaction, to produce a reformulated, partially oxygenated/etherified gasoline product, which includes a mixture of substituted phenyl/methyl ethers, cycloalkyl methyl ethers, C.sub.7 -C.sub.10 alkylbenzenes, C.sub.6 -C.sub.10 branched and multibranched paraffins, and alkylated and polyalkylated cycloalkanes.

  2. Analysis of leaded and unleaded gasoline pricing. Final report

    SciTech Connect (OSTI)

    Not Available

    1985-03-15T23:59:59.000Z

    This report summarizes the evaluation of the cost price relation between the two fuels. The original scope of work identified three separate categories of effort: Gather and organize available data on the wholesale and retail prices of gasoline at a national level for the past 5 years. Using the data collected in Subtask 1, develop models of pricing practices that aid in explaining retail markups and price differentials for different types and grades of gasoline at different retail outlets in the current gasoline market. Using the data from Subtask 1 and the analysis framework from Subtask 2, analyze the likely range of future retail markups and price differentials for different grades of leaded and unleaded gasoline. The report is organized in a format that is different than suggested by the subtasks outlined above. The first section provides a characterization of the problem - data available to quantify cost and price of the fuels as well as issues that directly affect this relationship. The second section provides a discussion of issues likely to affect this relation in the future. The third section postulates a model that can be used to quantify the relation between fuels, octane levels, costs and prices.

  3. Utilization of Renewable Oxygenates as Gasoline Blending Components

    SciTech Connect (OSTI)

    Yanowitz, J.; Christensen, E.; McCormick, R. L.

    2011-08-01T23:59:59.000Z

    This report reviews the use of higher alcohols and several cellulose-derived oxygenates as blend components in gasoline. Material compatibility issues are expected to be less severe for neat higher alcohols than for fuel-grade ethanol. Very little data exist on how blending higher alcohols or other oxygenates with gasoline affects ASTM Standard D4814 properties. Under the Clean Air Act, fuels used in the United States must be 'substantially similar' to fuels used in certification of cars for emission compliance. Waivers for the addition of higher alcohols at concentrations up to 3.7 wt% oxygen have been granted. Limited emission testing on pre-Tier 1 vehicles and research engines suggests that higher alcohols will reduce emissions of CO and organics, while NOx emissions will stay the same or increase. Most oxygenates can be used as octane improvers for standard gasoline stocks. The properties of 2-methyltetrahydrofuran, dimethylfuran, 2-methylfuran, methyl pentanoate and ethyl pentanoate suggest that they may function well as low-concentration blends with gasoline in standard vehicles and in higher concentrations in flex fuel vehicles.

  4. Experimental Investigation of Spark-Ignited Combustion with High-Octane Biofuels and EGR. 2. Fuel and EGR Effects on Knock-Limited Load and Speed

    SciTech Connect (OSTI)

    Splitter, Derek A [ORNL] [ORNL; Szybist, James P [ORNL] [ORNL

    2013-01-01T23:59:59.000Z

    The present study experimentally investigates spark-ignited combustion with 87 AKI E0 gasoline in its neat form and in midlevel alcohol gasoline blends with 24% vol/vol isobutanol gasoline (IB24) and 30% vol/vol ethanol gasoline (E30). A single-cylinder research engine is used with an 11.85:1 compression ratio, hydraulically actuated valves, laboratory intake air, and was capable of external exhaust gas recirculation (EGR). Experiments were conducted with all fuels to full-load conditions with = 1, using both 0% and 15% external-cooled EGR. Higher octane number biofuel blends exhibited increased stoichiometric torque capability at this compression ratio, where the unique properties of ethanol enabled a doubling of the stoichiometric torque capability with E30 as compared to that of 87AKI, up to 20 bar IMEPg (indicating mean effective pressure gross) at = 1. The results demonstrate that for all fuels, EGR is a key enabler for increasing engine efficiency but is less useful for knock mitigation with E30 than for 87AKI gasoline or IB24. Under knocking conditions, 15% EGR is found to offer 1 CA of CA50 timing advance with E30, whereas up to 5 CA of CA50 advance is possible with knock-limited 87AKI gasoline. Compared to 87AKI, both E30 and IB24 are found to have reduced adiabatic flame temperature and shorter combustion durations, which reduce knocking propensity beyond that indicated by the octane number. However, E30+0% EGR is found to exhibit the better antiknock properties than either 87AKI+15% EGR or IB24+15% EGR, expanding the knock limited operating range and engine stoichiometric torque capability at high compression ratio. Furthermore, the fuel sensitivity (S) of E30 was attributed to reduced speed sensitivity of E30, expanding the low-speed stoichiometric torque capability at high compression ratio. The results illustrate that intermediate alcohol gasoline blends exhibit exceptional antiknock properties and performance beyond that indicated by the octane number tests, particularly E30.

  5. State Gasoline Taxes

    E-Print Network [OSTI]

    Learned, Edmund Philip

    1925-03-15T23:59:59.000Z

    BULLETIN OF THE UNIVERSITY OF KANSAS HUMANISTIC STUDIES Vol. III March 15, 192S No. 4 State Gasoline Taxes BY KDMUNI) IV LKAENKI), A. B., A, M. Instructor in Economics and Commerce The Unlvmity of Kansas PUBLISHED BY THE UNIVERSITY l... vast sums of money, Oregon was the first state to adopt a tax on gasoline to provide revenue for building and maintaining roads. Since this adoption in 1919, many states have passed laws provid ing for gasoline taxes until now forty-four states...

  6. Ethanol Demand in United States Production of Oxygenate-limited Gasoline

    SciTech Connect (OSTI)

    Hadder, G.R.

    2000-08-16T23:59:59.000Z

    Ethanol competes with methyl tertiary butyl ether (MTBE) to satisfy oxygen, octane, and volume requirements of certain gasolines. However, MTBE has water quality problems that may create significant market opportunities for ethanol. Oak Ridge National Laboratory (ORNL) has used its Refinery Yield Model to estimate ethanol demand in gasolines with restricted use of MTBE. Reduction of the use of MTBE would increase the costs of gasoline production and possibly reduce the gasoline output of U.S. refineries. The potential gasoline supply problems of an MTBE ban could be mitigated by allowing a modest 3 vol percent MTBE in all gasoline. In the U.S. East and Gulf Coast gasoline producing regions, the 3 vol percent MTBE option results in costs that are 40 percent less than an MTBE ban. In the U.S. Midwest gasoline producing region, with already high use of ethanol, an MTBE ban has minimal effect on ethanol demand unless gasoline producers in other regions bid away the local supply of ethanol. The ethanol/MTBE issue gained momentum in March 2000 when the Clinton Administration announced that it would ask Congress to amend the Clean Air Act to provide the authority to significantly reduce or eliminate the use of MTBE; to ensure that air quality gains are not diminished as MTBE use is reduced; and to replace the existing oxygenate requirement in the Clean Air Act with a renewable fuel standard for all gasoline. Premises for the ORNL study are consistent with the Administration announcement, and the ethanol demand curve estimates of this study can be used to evaluate the impact of the Administration principles and related policy initiatives.

  7. The relation of octane number, compression ratio, and exhaust temperature in the gasoline engine

    E-Print Network [OSTI]

    Jentsch, Donald George

    1951-01-01T23:59:59.000Z

    on the engine consisted of a battery, two induction coils, distributor, spark indicator and spark plug. One induction coil was connected to the spark indicator on which could be read the amount of spark advance or retardation, while the other was connected... into the spark plug circuit. Fuel was supplied to the engine by gravity flow through flexible and copper tubing, a ceramic filter, and a simple float type carburetor from a gallon tank mounted on platform scales, The scales were graduated in hundredths...

  8. Fewer Steps to Higher Octane Gasoline in Petroleum Refining | U.S. DOE

    Office of Science (SC) Website

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear SecurityTensile Strain Switched5 IndustrialIsadore Perlman,Bios High EnergyEliane SJuly 2007Fermi

  9. A Dozen Reasons for Raising Gasoline Taxes

    E-Print Network [OSTI]

    Wachs, Martin

    2003-01-01T23:59:59.000Z

    States have the right gasoline tax? University of Californiajuly). A primer on gasoline prices. http://www.eia.gov/pub/Reasons for Raising Gasoline Taxes Martin Wachs RESEARCH

  10. Incidence of Federal and State Gasoline Taxes

    E-Print Network [OSTI]

    Chouinard, Hayley; Perloff, Jeffrey M.

    2003-01-01T23:59:59.000Z

    State Specific * Share of Gasoline State Specific * (Share of Gasoline) 2 StateSpecific * (Share of Gasoline) 3 State Specific * (Share of

  11. Market Power in California's Gasoline Market

    E-Print Network [OSTI]

    Borenstein, Severin; Bushnell, James; Lewis, Matthew

    2004-01-01T23:59:59.000Z

    Price Study Kayser, Hilke A. , 2000. Gasoline Demand andCar Choice: Estimating Gasoline Demand Using HouseholdIN GASOLINE MARKETS.

  12. Intermediate Alcohol-Gasoline Blends, Fuels for Enabling Increased Engine Efficiency and Powertrain Possibilities

    SciTech Connect (OSTI)

    Splitter, Derek A [ORNL] [ORNL; Szybist, James P [ORNL] [ORNL

    2014-01-01T23:59:59.000Z

    The present study experimentally investigates spark-ignited combustion with 87 AKI E0 gasoline in its neat form and in mid-level alcohol-gasoline blends with 24% vol./vol. iso-butanol-gasoline (IB24) and 30% vol./vol. ethanol-gasoline (E30). A single-cylinder research engine is used with a low and high compression ratio of 9.2:1 and 11.85:1 respectively. The engine is equipped with hydraulically actuated valves, laboratory intake air, and is capable of external exhaust gas recirculation (EGR). All fuels are operated to full-load conditions with =1, using both 0% and 15% external cooled EGR. The results demonstrate that higher octane number bio-fuels better utilize higher compression ratios with high stoichiometric torque capability. Specifically, the unique properties of ethanol enabled a doubling of the stoichiometric torque capability with the 11.85:1 compression ratio using E30 as compared to 87 AKI, up to 20 bar IMEPg at =1 (with 15% EGR, 18.5 bar with 0% EGR). EGR was shown to provide thermodynamic advantages with all fuels. The results demonstrate that E30 may further the downsizing and downspeeding of engines by achieving increased low speed torque, even with high compression ratios. The results suggest that at mid-level alcohol-gasoline blends, engine and vehicle optimization can offset the reduced fuel energy content of alcohol-gasoline blends, and likely reduce vehicle fuel consumption and tailpipe CO2 emissions.

  13. Is the gasoline tax regressive?

    E-Print Network [OSTI]

    Poterba, James M.

    1990-01-01T23:59:59.000Z

    Claims of the regressivity of gasoline taxes typically rely on annual surveys of consumer income and expenditures which show that gasoline expenditures are a larger fraction of income for very low income households than ...

  14. Gasoline price data systems

    SciTech Connect (OSTI)

    Not Available

    1980-05-01T23:59:59.000Z

    Timely observation on prices of gasoline at the wholesale and retail level by geographical area can serve several purposes: (1) to facilitate the monitoring of compliance with controls on distributor margins; (2) to indicate changes in the competitive structure of the distribution system; (3) to measure the incidence of changes in crude oil and refiner costs on retail prices by grade of gasoline, by type of retail outlet, and by geographic area; (4) to identify anomalies in the retail pricing structure that may create incentives for misfueling; and (5) to provide detailed time series data for use in evaluating conservation response to price changes. In order to provide the needed data for these purposes, the following detail on gasoline prices and characteristics of the sampling procedure appear to be appropriate: (1) monthly sample observations on wholesale and retail prices by gasoline grade and type of wholesale or retail dealer, together with volume weights; (2) sample size sufficient to provide detail by state and large cities; (3) responses to be tabulated and reports provided within 30 days after date of observation; and (4) a quick response sampling procedure that can provide weekly data, at least at the national level, when needed in time of rapidly changing prices. Price detail by state is suggested due to its significance for administrative purposes and since gasoline consumption data are estimated by state from other sources. Price detail for large cities are suggested in view of their relevancy as problem areas for vehicle emissions, reflecting one of the analytical uses of the data. In this report, current reporting systems and data on gasoline prices are reviewed and evaluated in terms of the needs outlined above. Recommendations are made for ways to fill the gaps in existing data systems to meet these needs.

  15. Experimental Investigation of Spark-Ignited Combustion with High-Octane Biofuels and EGR. 1. Engine Load Range and Downsize Downspeed Opportunity

    SciTech Connect (OSTI)

    Splitter, Derek A [ORNL] [ORNL; Szybist, James P [ORNL] [ORNL

    2013-01-01T23:59:59.000Z

    The present study experimentally investigates spark-ignited combustion with 87 AKI E0 gasoline in its neat form and in midlevel alcohol gasoline blends with 24% vol/vol isobutanol gasoline (IB24) and 30% vol/vol ethanol gasoline (E30). A single-cylinder research engine was used with an 11.85:1 compression ratio, hydraulically actuated valves, laboratory intake air, and was capable of external exhaust gas recirculation (EGR). Experiments were conducted with all fuels to full-load conditions with = 1, using both 0% and 15% external cooled EGR. Higher octane number biofuel blends exhibited increased stoichiometric torque capability at this compression ratio, where the unique properties of ethanol enabled a doubling of the stoichiometric torque capability with E30 as compared to 87 AKI, up to 20 bar IMEPg (indicated mean effective pressure gross) at = 1. EGR provided thermodynamic advantages and was a key enabler for increasing engine efficiency for all fuel types. However, with E30, EGR was less useful for knock mitigation than gasoline or IB24. Torque densities with E30 with 15% EGR at = 1 operation were similar or better than a modern EURO IV calibration turbo-diesel engine. The results of the present study suggest that it could be possible to implement a 40% downsize + downspeed configuration (1.2 L engine) into a representative midsize sedan. For example, for a midsize sedan at a 65 miles/h cruise, an estimated fuel consumption of 43.9 miles per gallon (MPG) (engine out 102 g-CO2/km) could be achieved with similar reserve power to a 2.0 L engine with 87AKI (38.6 MPG, engine out 135 g-CO2/km). Data suggest that, with midlevel alcohol gasoline blends, engine and vehicle optimization can offset the reduced fuel energy content of alcohol gasoline blends and likely reduce vehicle fuel consumption and tailpipe CO2 emissions.

  16. A Vehicle Manufacturer’s Perspective on Higher-Octane Fuels

    Broader source: Energy.gov [DOE]

    Breakout Session 1C—Fostering Technology Adoption I: Building the Market for Renewables with High Octane Fuels A Vehicle Manufacturer’s Perspective on Higher-Octane Fuels Tom Leone, Technical Expert, Powertrain Evaluation and Analysis, Ford Motor Company

  17. Gasoline Jet Fuels

    E-Print Network [OSTI]

    Kemner, Ken

    C4n= Diesel Gasoline Jet Fuels C O C5: Xylose C6 Fermentation of sugars Biofuel "Nanobowls" are inorganic catalysts that could provide the selectivity for converting sugars to fuels IACT Proposes Synthetic, Inorganic Catalysts to Produce Biofuels Current Process

  18. Method of making alkyl esters

    DOE Patents [OSTI]

    Elliott, Brian (Wheat Ridge, CO)

    2010-09-14T23:59:59.000Z

    Methods of making alkyl esters are described herein. The methods are capable of using raw, unprocessed, low-cost feedstocks and waste grease. Generally, the method involves converting a glyceride source to a fatty acid composition and esterifying the fatty acid composition to make alkyl esters. In an embodiment, a method of making alkyl esters comprises providing a glyceride source. The method further comprises converting the glyceride source to a fatty acid composition comprising free fatty acids and less than about 1% glyceride by mass. Moreover, the method comprises esterifying the fatty acid composition in the presence of a solid acid catalyst at a temperature ranging firm about 70.degree. C. to about 120.degree. C. to produce alkyl esters, such that at least 85% of the free fatty acids are converted to alkyl esters. The method also incorporates the use of packed bed reactors for glyceride conversion and/or fatty acid esterification to make alkyl esters.

  19. Chemical kinetic modeling of component mixtures relevant to gasoline

    SciTech Connect (OSTI)

    Mehl, M; Curran, H J; Pitz, W J; Dooley, S; Westbrook, C K

    2008-05-29T23:59:59.000Z

    Detailed kinetic models of pyrolysis and combustion of hydrocarbon fuels are nowadays widely used in the design of internal combustion engines and these models are effectively applied to help meet the increasingly stringent environmental and energetic standards. In previous studies by the combustion community, such models not only contributed to the understanding of pure component combustion, but also provided a deeper insight into the combustion behavior of complex mixtures. One of the major challenges in this field is now the definition and the development of appropriate surrogate models able to mimic the actual features of real fuels. Real fuels are complex mixtures of thousands of hydrocarbon compounds including linear and branched paraffins, naphthenes, olefins and aromatics. Their behavior can be effectively reproduced by simpler fuel surrogates containing a limited number of components. Aside the most commonly used surrogates containing iso-octane and n-heptane only, the so called Primary Reference Fuels (PRF), new mixtures have recently been suggested to extend the reference components in surrogate mixtures to also include alkenes and aromatics. It is generally agreed that, including representative species for all the main classes of hydrocarbons which can be found in real fuels, it is possible to reproduce very effectively in a wide range of operating conditions not just the auto-ignition propensity of gasoline or Diesel fuels, but also their physical properties and their combustion residuals [1]. In this work, the combustion behavior of several components relevant to gasoline surrogate formulation is computationally examined. The attention is focused on the autoignition of iso-octane, hexene and their mixtures. Some important issues relevant to the experimental and modeling investigation of such fuels are discussed with the help of rapid compression machine data and calculations. Following the model validation, the behavior of mixtures is discussed on the basis of computational results.

  20. Essays on Automotive Lending, Gasoline Prices, & Automotive Demand

    E-Print Network [OSTI]

    Schulz-Mahlendorf, Wilko Ziggy

    2013-01-01T23:59:59.000Z

    Gasoline PriceResponse to Chang- ing Gasoline Prices,” unpublishedShort-Run Price Elasticity of Gasoline Demand. ,” The Energy

  1. Motor gasoline assessment, Spring 1997

    SciTech Connect (OSTI)

    NONE

    1997-07-01T23:59:59.000Z

    The springs of 1996 and 1997 provide an excellent example of contrasting gasoline market dynamics. In spring 1996, tightening crude oil markets pushed up gasoline prices sharply, adding to the normal seasonal gasoline price increases; however, in spring 1997, crude oil markets loosened and crude oil prices fell, bringing gasoline prices down. This pattern was followed throughout the country except in California. As a result of its unique reformulated gasoline, California prices began to vary significantly from the rest of the country in 1996 and continued to exhibit distinct variations in 1997. In addition to the price contrasts between 1996 and 1997, changes occurred in the way in which gasoline markets were supplied. Low stocks, high refinery utilizations, and high imports persisted through 1996 into summer 1997, but these factors seem to have had little impact on gasoline price spreads relative to average spread.

  2. Asymmetric Alkyl?Alkyl Cross-Couplings of Unactivated Secondary Alkyl Electrophiles: Stereoconvergent Suzuki Reactions of Racemic Acylated Halohydrins

    E-Print Network [OSTI]

    Owston, Nathan A.

    A method for asymmetric alkyl?alkyl Suzuki reactions of unactivated secondary alkyl electrophiles, specifically, cross-couplings of racemic acylated halohydrins with alkylborane reagents, has been developed. A range of ...

  3. Novel Characterization of GDI Engine Exhaust for Gasoline and Mid-Level Gasoline-Alcohol Blends

    SciTech Connect (OSTI)

    Storey, John Morse [ORNL] [ORNL; Lewis Sr, Samuel Arthur [ORNL] [ORNL; Szybist, James P [ORNL] [ORNL; Thomas, John F [ORNL] [ORNL; Barone, Teresa L [ORNL] [ORNL; Eibl, Mary A [ORNL] [ORNL; Nafziger, Eric J [ORNL] [ORNL; Kaul, Brian C [ORNL] [ORNL

    2014-01-01T23:59:59.000Z

    Gasoline direct injection (GDI) engines can offer improved fuel economy and higher performance over their port fuel-injected (PFI) counterparts, and are now appearing in increasingly more U.S. and European vehicles. Small displacement, turbocharged GDI engines are replacing large displacement engines, particularly in light-duty trucks and sport utility vehicles, in order for manufacturers to meet more stringent fuel economy standards. GDI engines typically emit the most particulate matter (PM) during periods of rich operation such as start-up and acceleration, and emissions of air toxics are also more likely during this condition. A 2.0 L GDI engine was operated at lambda of 0.91 at typical loads for acceleration (2600 rpm, 8 bar BMEP) on three different fuels; an 87 anti-knock index (AKI) gasoline (E0), 30% ethanol blended with the 87 AKI fuel (E30), and 48% isobutanol blended with the 87 AKI fuel. E30 was chosen to maximize octane enhancement while minimizing ethanol-blend level and iBu48 was chosen to match the same fuel oxygen level as E30. Particle size and number, organic carbon and elemental carbon (OC/EC), soot HC speciation, and aldehydes and ketones were all analyzed during the experiment. A new method for soot HC speciation is introduced using a direct, thermal desorption/pyrolysis inlet for the gas chromatograph (GC). Results showed high levels of aromatic compounds were present in the PM, including downstream of the catalyst, and the aldehydes were dominated by the alcohol blending.

  4. EIS-0039: Motor Gasoline Deregulation and the Gasoline Tilt

    Broader source: Energy.gov [DOE]

    The Economic Regulatory Administration developed this EIS to evaluate the environmental impacts, including social and economic impacts, that may result from either of two proposed regulatory changes: (1) the exemption of motor gasoline from the Department of Energy's Mandatory Petroleum Price and Allocation Regulations, and (2) the adoption of the gasoline tilt, a proposed regulation that would allow refiners to recover an additional amount of their total increased costs on gasoline.

  5. Gasoline Ultra Fuel Efficient Vehicle

    Broader source: Energy.gov (indexed) [DOE]

    Principal Investigator 13MY11 2011 DOE Vehicle Technologies Review Gasoline Ultra Fuel Efficient Vehicle ACE064 "This presentation does not contain any proprietary,...

  6. Variable-Rate State Gasoline Taxes

    E-Print Network [OSTI]

    Ang-Olson, Jeffrey; Wachs, Martin; Taylor, Brian D.

    1999-01-01T23:59:59.000Z

    1986, the average retail gasoline price dropped from $1.17Figure 4 Average US Retail Gasoline Price (excluding taxes)of the average retail price of gasoline, with a 4.0 cent per

  7. Variable-Rate State Gasoline Taxes

    E-Print Network [OSTI]

    Ang-Olson, Jeffrey; Wachs, Martin; Taylor, Brian D.

    1999-01-01T23:59:59.000Z

    Recent Changes in State Gasoline Taxation: An Analysis ofMarch The excise tax on gasoline in New York is 8.0 centsis also a sales tax on gasoline which recently stood at 7.8

  8. Variable-Rate State Gasoline Taxes

    E-Print Network [OSTI]

    Ang-Olson, Jeffrey; Wachs, Martin; Taylor, Brian D.

    2000-01-01T23:59:59.000Z

    J Bradshaw, "SLate ’F~es’ Gasoline Tax So ~t Wdl Rise," TheVarlable-Rate State Gasoline Taxers Jeffrey Ang-Olson MartinVariable-Rate State Gasoline Taxes Jeffrey Ang-Olson

  9. Variable-Rate State Gasoline Taxes

    E-Print Network [OSTI]

    Ang-Olson, Jeffrey; Wachs, Martin; Taylor, Brian D.

    2000-01-01T23:59:59.000Z

    1986, the average retail gasoline price dropped from $I 17of the average retail price of gasoline, with a 4 oe per

  10. Relationship between MTBE-blended gasoline properties and warm-up driveability

    SciTech Connect (OSTI)

    Suzawa, Takumi; Yamaguchi, Kazunori; Kashiwabara, Kimito [Mitsubishi Motors Corp., Tokyo (Japan); Fujisawa, Norihiro; Matsubara, Michiro

    1995-12-31T23:59:59.000Z

    The relationship between MBE-blended gasoline properties and warm-up driveability is investigated by focusing on the transient combustion air-fuel ratio that strongly relates to the combustion state of the engine. As a result, although warm-up driveability of MTBE-free gasoline has a high correlation with 50% distillation temperature (T50) and a high correlation with 100 C distillation volume (E100), the correlation is found to be low when blended with MTBE. Various formulas that improve correlation with peak excess air ratio ({lambda}) by correcting T50 and E100 for the amount of MTBE blended are examined. The formula for which the highest determination coefficient is obtained is proposed as a new driveability index (DI) that can also be applied to MTBE-blended gasoline. In addition, the effect on driveability by gasoline base materials using this new DI also is investigated. The results indicate that the new DI worsen when heavy reformate containing large amounts of aromatics or MTBE, an oxygen-containing compound, is used for the octane improver, leaving the balance of the volatility out of consideration.

  11. The Impact of Low Octane Hydrocarbon Blending Streams on "E85...

    Broader source: Energy.gov (indexed) [DOE]

    IMPACT OF LOW OCTANE HYDROCARBON BLENDING STREAMS ON "E85" ENGINE OPTIMIZATION Jim Szybist and Brian West Oak Ridge National Laboratory October 19, 2012 Acknowledgement This...

  12. Oligomerize for better gasoline

    SciTech Connect (OSTI)

    Nierlich, F. (Huls AG, Marl (DE))

    1992-02-01T23:59:59.000Z

    This paper reports on normal butene containing isobutene-depleted C{sub 4} hydrocarbons like raffinate II which are oligomerized using the Octol process in the liquid phase on a heterogeneous catalyst system to yield mainly C{sub 8} and C{sub 12} olefins. Raffinate II, the spent C{sub 4} fraction of an MTBE unit, is an ideal feedstock for further n-butene processing because of its high olefin concentration ranging between 70% and 80%. By modifications of MTBE technology, implementation of selective hydrogenation for removal of residual butadiene and superfractionating raffinate II, polymer grade 1-butene can be produced. Until the mid-70s raffinate I, the team cracker C{sub 4} cut after butadiene extraction, was mainly burned or blended into gasoline. Now nearly all raffinate I is or will be consumed for the purpose of converting isobutylene to MTBE.

  13. Gasoline price spikes and regional gasoline context regulations : a structural approach

    E-Print Network [OSTI]

    Muehlegger, Erich J.

    2004-01-01T23:59:59.000Z

    Since 1999, gasoline prices in California, Illinois and Wisconsin have spiked occasionally well above gasoline prices in nearby states. In May and June 2000, for example, gasoline prices in Chicago rose twenty eight cents ...

  14. Comparing air quality impacts of hydrogen and gasoline

    E-Print Network [OSTI]

    Sperling, Dan; Wang, Guihua; Ogden, Joan M.

    2008-01-01T23:59:59.000Z

    from among existing gasoline station locations in Sacra-VOC emitted at gasoline service stations, because these arethe gasoline terminal storage and refueling stations, it is

  15. Edgeworth Price Cycles: Evidence from the Toronto Retail Gasoline Market

    E-Print Network [OSTI]

    Noel, Michael

    2004-01-01T23:59:59.000Z

    Johnson. “Gas Wars: Retail Gasoline Price Fluctua- tions”,Canadian cities, retail gasoline prices are very volatileset of twelve-hourly retail gasoline prices for 22 service

  16. Retail Policies and Competition in the Gasoline Industry

    E-Print Network [OSTI]

    Borenstein, Severin; Bushnell, Jim

    2005-01-01T23:59:59.000Z

    wholesale gasoline prices and retail prices. It includes theTable 4 - Gasoline Price Components Year Retail Price TaxesSupply Lower Retail Gasoline Prices? ” Contemporary Economic

  17. Essays on Automotive Lending, Gasoline Prices, & Automotive Demand

    E-Print Network [OSTI]

    Schulz-Mahlendorf, Wilko Ziggy

    2013-01-01T23:59:59.000Z

    National average retail gasoline prices peaked at over $so that average retail gasoline prices can be employed. Myrapid run-up in retail gasoline prices in recent history.

  18. Revisiting the Income Effect: Gasoline Prices and Grocery Purchases

    E-Print Network [OSTI]

    Gicheva, Dora; Hastings, Justine; Villas-Boas, Sofia B

    2008-01-01T23:59:59.000Z

    Sold On Sale and Retail Gasoline Prices Log % Purchased Onhigher gasoline prices into retail prices, by investigatingexcluding California average retail gasoline price for all

  19. Demand and Price Uncertainty: Rational Habits in International Gasoline Demand

    E-Print Network [OSTI]

    Scott, K. Rebecca

    2013-01-01T23:59:59.000Z

    Sterner. 1991. Analysing gasoline demand elasticities: A2011. Measuring global gasoline and diesel price and incomeMutairi. 1995. Demand for gasoline in Kuwait: An empirical

  20. Comparing air quality impacts of hydrogen and gasoline

    E-Print Network [OSTI]

    Sperling, Dan; Wang, Guihua; Ogden, Joan M.

    2008-01-01T23:59:59.000Z

    of hydrogen, methanol and gasoline as fuels for fuel cellto petroleum pathways with gasoline and diesel vehicles.simplicity, we use the term ‘‘gasoline pathway” to refer to

  1. Effects of Vehicle Image in Gasoline-Hybrid Electric Vehicles

    E-Print Network [OSTI]

    Heffner, Reid R.; Kurani, Kenneth S; Turrentine, Tom

    2005-01-01T23:59:59.000Z

    of Vehicle Image in Gasoline-Hybrid Electric Vehicles Reidof Vehicle Image in Gasoline-Hybrid Electric Vehicles Reidhigh demand for gasoline-hybrid electric vehicles (HEVs)?

  2. Carbonyl Emissions from Gasoline and Diesel Motor Vehicles

    E-Print Network [OSTI]

    Jakober, Chris A.

    2008-01-01T23:59:59.000Z

    fraction of light-duty gasoline vehicle particulate matterQuinone emissions from gasoline and diesel motor vehicles.32 organic compounds from gasoline- powered motor vehicles.

  3. Revisiting the Income Effect: Gasoline Prices and Grocery Purchases

    E-Print Network [OSTI]

    Gicheva, Dora; Hastings, Justine; Villas-Boas, Sofia B

    2008-01-01T23:59:59.000Z

    University. Espey, M. , 1998. "Gasoline Demand Revisited: AnRun Price Elasticity of Gasoline Demand,” working paper.Elasticities of Demand for Gasoline in Canada and the United

  4. Edgeworth Price Cycles: Evidence from the Toronto Retail Gasoline Market

    E-Print Network [OSTI]

    Noel, Michael

    2004-01-01T23:59:59.000Z

    Robbery, An Analysis of the Gasoline Crisis”, Bloomington:Dynamic Pricing in Retail gasoline Markets”, RAND Journal ofR. Gilbert. “Do Gasoline Markets Respond Asymmetrically to

  5. Vapor-liquid equilibria and excess enthalpies for octane + N-methylacetamide, cyclooctane + N-methylacetamide, and octane + acetic acid anhydride at 125 C

    SciTech Connect (OSTI)

    Haan, A.B. de [DSM-Research, Geleen (Netherlands); Heine, A.; Fischer, K.; Gmehling, J. [Univ. Oldenburg (Germany)

    1995-11-01T23:59:59.000Z

    Isothermal P-x data and excess enthalpies have been measured at approximately 125 C for the binary mixtures of octane + N-methylacetamide, cyclooctane + N-methylacetamide, and octane + acetic anhydride. For each binary system linear temperature dependent interaction parameters were fitted to experimental data using the NRTL model. Activity coefficients at infinite dilution were derived from the P-x data at low concentrations using a flexible Legendre polynomial.

  6. Vehicle Technologies Office Merit Review 2014: Advanced Gasoline...

    Broader source: Energy.gov (indexed) [DOE]

    Advanced Gasoline Turbocharged Direct Injection (GTDI) Engine Development Vehicle Technologies Office Merit Review 2014: Advanced Gasoline Turbocharged Direct Injection (GTDI)...

  7. Incidence of Federal and State Gasoline Taxes

    E-Print Network [OSTI]

    Chouinard, Hayley; Perloff, Jeffrey M.

    2003-01-01T23:59:59.000Z

    valorem taxes to the retail gasoline price. These ad valoremwholesale and retail, unleaded gasoline price equations. Wegasoline, Journal of Economic Issues 9, 409-414. Table 1: Retail and Wholesale Reduced-Form Price

  8. Household gasoline demand in the United States

    E-Print Network [OSTI]

    Schmalensee, Richard

    1995-01-01T23:59:59.000Z

    Continuing rapid growth in U.S. gasoline consumption threatens to exacerbate environmental and congestion problems. We use flexible semiparametric and nonparametric methods to guide analysis of household gasoline consumption, ...

  9. Motor Gasoline Outlook and State MTBE Bans

    Reports and Publications (EIA)

    2003-01-01T23:59:59.000Z

    The U.S. is beginning the summer 2003 driving season with lower gasoline inventories and higher prices than last year. Recovery from this tight gasoline market could be made more difficult by impending state bans on the blending of methyl tertiary butyl ether (MTBE) into gasoline that are scheduled to begin later this year.

  10. Methods of making alkyl esters

    DOE Patents [OSTI]

    Elliott, Brian (Wheat Ridge, CO)

    2010-08-03T23:59:59.000Z

    A method comprising contacting an alcohol, a feed comprising one or more glycerides and equal to or greater than 2 wt % of one or more free fatty acids, and a solid acid catalyst, a nanostructured polymer catalyst, or a sulfated zirconia catalyst in one or more reactors, and recovering from the one or more reactors an effluent comprising equal to or greater than about 75 wt % alkyl ester and equal to or less than about 5 wt % glyceride.

  11. Autoignition of gasoline surrogates mixtures at intermediate temperatures and high pressures

    SciTech Connect (OSTI)

    Fikri, M.; Herzler, J.; Starke, R.; Schulz, C.; Roth, P. [IVG, Universitaet Duisburg-Essen, D-47048 Duisburg (Germany); Kalghatgi, G.T. [Shell Global Solutions U.K., P.O. Box 1, Chester CH1 3SH (United Kingdom)

    2008-01-15T23:59:59.000Z

    Ignition times were determined in high-pressure shock-tube experiments for various stoichiometric mixtures of two multicomponent model fuels in air for the validation of ignition delay simulations based on chemical kinetic models. The fuel blends were n-heptane (18%)/isooctane (62%)/ethanol (20%) by liquid volume (14.5%/44.5%/41% by mole fraction) and n-heptane (20%)/toluene (45%)/isooctane (25%)/diisobutylene (10%) by liquid volume (17.5%/55%/19.5%/8.0% by mole fraction). These fuels have octane numbers comparable to a standard European gasoline of 95 RON and 85 MON. The experimental conditions cover temperatures from 690 to 1200 K and pressures at 10, 30, and 50 bar. The obtained ignition time data are scaled with respect to pressure and compared to previous results reported in the literature. (author)

  12. Clearing the Air? The Effects of Gasoline Content Regulation on Air Quality

    E-Print Network [OSTI]

    Auffhammer, Maximilian; Kellogg, Ryan

    2009-01-01T23:59:59.000Z

    Reformulating Competition? Gasoline Content Regulationand Wholesale Gasoline Prices,” Journal of Environmentaland Heterogeneity in U.S. Gasoline Prices,” Journal of

  13. High octane ethers from synthesis gas-derived alcohols

    SciTech Connect (OSTI)

    Klier, K.; Herman, R.G.; Feeley, O.C.; Johansson, M.A.

    1992-07-01T23:59:59.000Z

    The objective of the proposed research is to synthesize high octane ethers, primarily methyl isobutyl ether (MIBE) and methyl tertiary butyl ether (MTBE), directly from H[sub 2]/CO/CO[sub 2] coal-derived synthesis gas via alcohol mixtures that are rich in methanol and 2-methyl-l-propanol (isobutanol). The overall scheme involves gasification of coal, purification and shifting of the synthesis gas, higher alcohol synthesis, and direct synthesis of ethers. The last stage of the synthesis involves direct coupling of synthesis gas-derived methanol and isobutanol that has been demonstrated by us to occur over superacid catalysts to yield methyl isobutyl ether (MIBE) at moderate pressures and a mixture of methanol and isobutene at low pressures. MIBE is an isomer of MTBE and a process is proposed whereby MTBE from the two alcohols is maximized and MIBE is minimized. This will be achieved by the proper choice of reaction conditions, i.e. intermediate pressures, and of inorganic acid catalysts that are stable at temperatures higher than 200[degree]C, at which the carbonium ion reaction coupling of the two alcohols to MTBE is more effective than the oxonium ion or ester reaction coupling to MIBE. Both organic and inorganic catalysts will be investigated, and the better catalysts of these classes will be subjected to long term performance studies. The long term performance studies of the combined process will extend to 1000 hr and detailed analytical data for all products will be provided.

  14. Alkylate

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines AboutDecemberSteam Coal Import CostsLiquidsYear JanYear Jan Feb Mar

  15. Essays on gasoline price spikes, environmental regulation of gasoline content, and incentives for refinery operation

    E-Print Network [OSTI]

    Muehlegger, Erich J

    2005-01-01T23:59:59.000Z

    Since 1999, regional retail and wholesale gasoline markets in the United States have experienced significant price volatility, both intertemporally and across geographic markets. In particular, gasoline prices in California, ...

  16. YOUNG STARS NEAR EARTH: THE OCTANS-NEAR ASSOCIATION AND CASTOR MOVING GROUP

    SciTech Connect (OSTI)

    Zuckerman, B.; Vican, Laura [Department of Physics and Astronomy, University of California, Los Angeles, CA 90095 (United States); Song, Inseok [Department of Physics and Astronomy, University of Georgia, Athens, GA 30602-2451 (United States); Schneider, Adam, E-mail: ben@astro.ucla.edu, E-mail: lvican@ucla.edu, E-mail: song@uga.edu, E-mail: Adam.Schneider@Utoledo.edu [Department of Physics and Astronomy, University of Toledo, Toledo, OH 43606 (United States)

    2013-11-20T23:59:59.000Z

    All cataloged stellar moving groups and associations with ages ?100 Myr and within 100 pc of Earth have Galactic space motions (UVW) situated in a 'good box' with dimensions ?20 km s{sup –1} on a side. Torres et al. defined the Octans Association as a group of 15 stars with age '20 Myr?' and located ?140 pc from Earth, but with average V space velocity –3.6 km s{sup –1} that is well outside of the good box. We present a list of 14 Hipparcos star systems within 100 pc of Earth that we call {sup O}ctans-Near{sup ;} these systems have UVW similar to those of the much more distant Octans Association. The Octans-Near stars have apparent ages between about 30 and 100 Myr and their relationship to the Octans Association stars is unclear. Six additional star systems have UVW similar to those of Octans-Near stars and likely ages ?200 Myr. These six systems include the late-type binary star EQ Peg—6.2 pc from Earth with likely age ?100 Myr and thus likely to be the nearest known pre-main sequence star system. The UVW of stars in a previously proposed ?200 Myr old Castor moving group are not too dissimilar from the UVW of Octans-Near stars. However, stars in the Castor group—if it exists at all—are mostly substantially older than 200 Myr and thus generally can readily be distinguished from the much younger Octans-Near stars.

  17. Emissions Control for Lean Gasoline Engines

    Broader source: Energy.gov (indexed) [DOE]

    to achieve cost-effective compliance * minimize precious metal content while maximizing fuel economy * Relevance: - U.S. passenger car fleet is dominated by gasoline-fueled...

  18. Emissions Control for Lean Gasoline Engines

    Broader source: Energy.gov (indexed) [DOE]

    SCR Urea TankInjector Cost Customer Acceptance Not in Project Scope Specific Key Issues: Cost, Durability, Fuel Penalty, Operating Temp., etc... Lean Gasoline SI Direct Injection...

  19. Advanced Gasoline Turbocharged Direct Injection (GTDI) Engine...

    Broader source: Energy.gov (indexed) [DOE]

    in Gasoline Turbocharged Direct Injection (GTDI) engine technology in the near term as a cost effective, high volume, fuel economy solution, marketed globally as EcoBoost...

  20. Emissions Control for Lean Gasoline Engines

    Broader source: Energy.gov (indexed) [DOE]

    SCR Urea TankInjector Cost Customer Acceptance Not in Project Scope Specific Key Issues: Cost, Durability, Fuel Penalty, Operating Temp.,+... Lean Gasoline SI Direct Injection...

  1. Detailed Chemical Kinetic Modeling of Surrogate Fuels for Gasoline and Application to an HCCI Engine

    SciTech Connect (OSTI)

    Naik, C V; Pitz, W J; Sj?berg, M; Dec, J E; Orme, J; Curran, H J; Simmie, J M; Westbrook, C K

    2005-01-07T23:59:59.000Z

    Gasoline consists of many different classes of hydrocarbons, such as paraffins, olefins, aromatics, and cycloalkanes. In this study, a surrogate gasoline reaction mechanism is developed, and it has one representative fuel constituent from each of these classes. These selected constituents are iso-octane, n-heptane, 1-pentene, toluene, and methyl-cyclohexane. The mechanism was developed in a step-wise fashion, adding submechanisms to treat each fuel component. Reactions important for low temperature oxidation (<1000K) and cross-reactions among different fuels are incorporated into the mechanism. The mechanism consists of 1214 species and 5401 reactions. A single-zone engine model is used to evaluate how well the mechanism captures autoignition behavior for conditions corresponding to homogeneous charge compression ignition (HCCI) engine operation. Experimental data are available for both how the combustion phasing changes with fueling at a constant intake temperature, and also how the intake temperature has to be changed with pressure in order to maintain combustion phasing for a fixed equivalence ratio. Three different surrogate fuel mixtures are used for the modeling. Predictions are in reasonably good agreement with the engine data. In addition, the heat release rate is calculated and compared to the data from experiments. The model predicts less low-temperature heat release than that measured. It is found that the low temperature heat-release rate depends strongly on engine speed, reactions of RO{sub 2}+HO{sub 2}, fuel composition, and pressure boost.

  2. Automobile Prices, Gasoline Prices, and Consumer Demand for Fuel Economy

    E-Print Network [OSTI]

    Sadoulet, Elisabeth

    Automobile Prices, Gasoline Prices, and Consumer Demand for Fuel Economy Ashley Langer University evidence that automobile manufacturers set vehicle prices as if consumers respond to gasoline prices. We consumer preferences for fuel efficiency. Keywords: automobile prices, gasoline prices, environmental

  3. Demand and Price Volatility: Rational Habits in International Gasoline Demand

    E-Print Network [OSTI]

    Scott, K. Rebecca

    2011-01-01T23:59:59.000Z

    H. , and James M. Gri¢ n. 1983. Gasoline demand in the OECDof dynamic demand for gasoline. Journal of Econometrics 77(An empirical analysis of gasoline demand in Denmark using

  4. Retail Policies and Competition in the Gasoline Industry

    E-Print Network [OSTI]

    Borenstein, Severin; Bushnell, Jim

    2005-01-01T23:59:59.000Z

    Total Volume Table 4 - Gasoline Price Components Year RetailEvidence from Retail Gasoline Markets." Journal of Law,and Competition in the Gasoline Industry I. II. III. IV. V.

  5. Alkylation of organic aromatic compounds

    DOE Patents [OSTI]

    Smith, Jr., Lawrence A. (Bellaire, TX); Arganbright, Robert P. (Seabrook, TX); Hearn, Dennis (Houston, TX)

    1993-01-01T23:59:59.000Z

    Aromatic compounds are alkylated in a combination reactor/distillation column comprising a vessel suitable for operating between 70.degree. C. and 500.degree. C. and from 0.5 to 20 atmospheres pressure; an inert distillation packing in the lower one-third of said vessel; solid acidic catalytic material such as zeolites or an acidic cation exchange resin supported in the middle one-third of said vessel; and inert distillation packing in the upper one-third of said vessel. A benzene inlet is located near the upper end of the vessel; an olefin inlet is juxtaposed with said solid acidic catalytic material; a bottoms outlet is positioned near the bottom of said vessel for removing said cumene and ethyl benzene; and an overhead outlet is placed at the top of said vessel for removing any unreacted benzene and olefin.

  6. Alkylation of organic aromatic compounds

    DOE Patents [OSTI]

    Smith, L.A. Jr.; Arganbright, R.P.; Hearn, D.

    1993-01-05T23:59:59.000Z

    Aromatic compounds are alkylated in a combination reactor/distillation column comprising a vessel suitable for operating between 70 C and 500 C and from 0.5 to 20 atmospheres pressure; an inert distillation packing in the lower one-third of said vessel; solid acidic catalytic material such as zeolites or an acidic cation exchange resin supported in the middle one-third of said vessel; and inert distillation packing in the upper one-third of said vessel. A benzene inlet is located near the upper end of the vessel; an olefin inlet is juxtaposed with said solid acidic catalytic material; a bottoms outlet is positioned near the bottom of said vessel for removing said cumene and ethyl benzene; and an overhead outlet is placed at the top of said vessel for removing any unreacted benzene and olefin.

  7. Gasoline and Diesel Fuel Update

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelinesProved Reserves (BillionTotal Consumption1,2372009From PeruSampling MethodologyGasoline

  8. Reformulated Gasoline Foreign Refinery Rules

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines AboutDecember 2005 (Thousand9,0,InformationU.S.Feet)1,576 1,608Reformulated Gasoline

  9. Gasoline prices decrease (Short version)

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"Click worksheet9,1,50022,3,,,,6,1,,781 2,328 2,683DieselValues shown for(long24, 2014GasolineShort

  10. Gasoline prices decrease (long version)

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"Click worksheet9,1,50022,3,,,,6,1,,781 2,328 2,683DieselValues shown for(long24,5, 2014 Gasoline prices

  11. Gasoline prices decrease (long version)

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"Click worksheet9,1,50022,3,,,,6,1,,781 2,328 2,683DieselValues shown for(long24,5, 2014 Gasoline

  12. Gasoline prices decrease (short version)

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"Click worksheet9,1,50022,3,,,,6,1,,781 2,328 2,683DieselValues shown for(long24,5, 2014Gasoline prices

  13. Gasoline prices decrease (short version)

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"Click worksheet9,1,50022,3,,,,6,1,,781 2,328 2,683DieselValues shown for(long24,5, 2014Gasoline

  14. Design Case Summary: Production of Gasoline and Diesel from Biomass...

    Energy Savers [EERE]

    Design Case Summary: Production of Gasoline and Diesel from Biomass via Fast Pyrolysis, Hydrotreating, and Hydrocracking Design Case Summary: Production of Gasoline and Diesel from...

  15. Production of Gasoline and Diesel from Biomass via Fast Pyrolysis...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Production of Gasoline and Diesel from Biomass via Fast Pyrolysis, Hydrotreating and Hydrocracking: A Design Case Production of Gasoline and Diesel from Biomass via Fast Pyrolysis,...

  16. High Efficiency Clean Combustion Engine Designs for Gasoline...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Efficiency Clean Combustion Engine Designs for Gasoline and Diesel Engines High Efficiency Clean Combustion Engine Designs for Gasoline and Diesel Engines 2009 DOE Hydrogen Program...

  17. Reductant Chemistry during LNT Regeneration for a Lean Gasoline...

    Broader source: Energy.gov (indexed) [DOE]

    Reductant Chemistry during LNT Regeneration for a Lean Gasoline Engine Reductant Chemistry during LNT Regeneration for a Lean Gasoline Engine Poster presented at the 16th...

  18. Impact of Ethanol Blending on U.S. Gasoline Prices

    SciTech Connect (OSTI)

    Not Available

    2008-11-01T23:59:59.000Z

    This study assesses the impact of ethanol blending on gasoline prices in the US today and the potential impact of ethanol on gasoline prices at higher blending concentrations.

  19. Load Expansion with Diesel/Gasoline RCCI for Improved Engine...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    with DieselGasoline RCCI for Improved Engine Efficiency and Emissions Load Expansion with DieselGasoline RCCI for Improved Engine Efficiency and Emissions This poster will...

  20. Characterization of Pre-Commercial Gasoline Engine Particulates...

    Broader source: Energy.gov (indexed) [DOE]

    Pre-Commercial Gasoline Engine Particulates Through Advanced Aerosol Methods Characterization of Pre-Commercial Gasoline Engine Particulates Through Advanced Aerosol Methods...

  1. Advantages of Oxygenates Fuels over Gasoline in Direct Injection...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Advantages of Oxygenates Fuels over Gasoline in Direct Injection Spark Ignition Engines Advantages of Oxygenates Fuels over Gasoline in Direct Injection Spark Ignition Engines...

  2. Diesel and Gasoline Engine Emissions: Characterization of Atmosphere...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Gasoline Engine Emissions: Characterization of Atmosphere Composition and Health Responses to Inhaled Emissions Diesel and Gasoline Engine Emissions: Characterization of...

  3. In Vitro Genotoxicity of Gasoline and Diesel Engine Vehicle Exhaust...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Gasoline and Diesel Engine Vehicle Exhaust Particulate and Semi-Volatile Organic Compound Materials In Vitro Genotoxicity of Gasoline and Diesel Engine Vehicle Exhaust Particulate...

  4. 3-Cylinder Turbocharged Gasoline Direct Injection: A High Value...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Cylinder Turbocharged Gasoline Direct Injection: A High Value Solution for Euro VI Emissions 3-Cylinder Turbocharged Gasoline Direct Injection: A High Value Solution for Euro VI...

  5. Volatility of Gasoline and Diesel Fuel Blends for Supercritical...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Gasoline and Diesel Fuel Blends for Supercritical Fuel Injection Volatility of Gasoline and Diesel Fuel Blends for Supercritical Fuel Injection Supercritical dieseline could be...

  6. alkyl-tert alkyl ethers: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    TREAT METHYL- TERT-BUTYL ETHER CONTAMINATED CiteSeer Summary: Methyl-tert-butyl ether (MTBE) is a commonly used gasoline additive. Leaking underground storage tank systems,...

  7. Topology of cyclo-octane energy landscape Shawn Martin,1,a

    E-Print Network [OSTI]

    Coutsias, Evangelos

    . While this is a very mild assumption, we have discovered an example of an energy landscape whichTopology of cyclo-octane energy landscape Shawn Martin,1,a Aidan Thompson,2 Evangelos A. Coutsias,3 2010 Understanding energy landscapes is a major challenge in chemistry and biology. Although a wide

  8. E-Print Network 3.0 - alkyl halide transfer Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    alkyl halide, resulting... of the nucleophilic substitution and reduction reactions of iPr-LAB with alkyl halides. Ab initio and density... of alkyl halide by hydride. ......

  9. Gasoline price volatility and the elasticity of demand for gasoline1 C.-Y. Cynthia Lina

    E-Print Network [OSTI]

    Lin, C.-Y. Cynthia

    externalities including local air pollution, global climate change, accidents, congestion, and dependence at reducing demand for gasoline or reducing pollution from automobiles. The latter could be addressed

  10. Insights into Spring 2008 Gasoline Prices

    Reports and Publications (EIA)

    2008-01-01T23:59:59.000Z

    Gasoline prices rose rapidly in spring 2007 due a variety of factors, including refinery outages and lower than expected imports. This report explores those factors and looks at the implications for 2008.

  11. Edgeworth price cycles in retail gasoline markets

    E-Print Network [OSTI]

    Noel, Michael David, 1971-

    2002-01-01T23:59:59.000Z

    In this dissertation, I present three essays that are motivated by the interesting and dynamic price-setting behavior of firms in Canadian retail gasoline markets. In the first essay, I examine behavior at the market level ...

  12. Vertical Integration in Gasoline Supply: An Empirical Test of Raising Rivals' Costs

    E-Print Network [OSTI]

    Gilbert, Richard; Hastings, Justine

    2001-01-01T23:59:59.000Z

    erentials in wholesale and retail gasoline prices, sometimesand control retail gasoline prices, while still permittingnopolize retail gasoline markets and raise prices. Several

  13. The Speed of Gasoline Price Response in Markets With and Without Edgeworth Cycles

    E-Print Network [OSTI]

    Lewis, Matt; Noel, Michael

    2009-01-01T23:59:59.000Z

    3, 2009 Abstract Retail gasoline prices are known to respondspeed with which retail gasoline prices respond to wholesaleDeltas, George, “Retail Gasoline Price Dynamics and Local

  14. The Implications of a Gasoline Price Floor for the California Budget and Greenhouse Gas Emissions

    E-Print Network [OSTI]

    Borenstein, Severin

    2008-01-01T23:59:59.000Z

    result in a target retail gasoline price of about $3.00 perAdministration, retail gasoline prices in Californiaprice, the expected retail gasoline price and consumption

  15. Gasoline Price Differences: Taxes, Pollution Regulations, Mergers, Market Power, and Market Conditions

    E-Print Network [OSTI]

    Chouinard, Hayley; Perloff, Jeffrey M.

    2002-01-01T23:59:59.000Z

    of Information and Retail Gasoline Price Behavior: Anform wholesale and retail gasoline price equations usingfor some of the retail gasoline price dispersion within a

  16. Asymmetric Price Adjustment and Consumer Search: An Examination of the Retail Gasoline Market

    E-Print Network [OSTI]

    Lewis, Matt

    2003-01-01T23:59:59.000Z

    The Behavior of Retail Gasoline Prices: Symmetric or Not? ”Adjustment of U.K. Retail Gasoline Prices to Cost Changes. ”documented that retail gasoline prices respond more quickly

  17. Asymmetric Price Adjustment and Consumer Search: An Examination of the Retail Gasoline Industry

    E-Print Network [OSTI]

    Lewis, Matt

    2003-01-01T23:59:59.000Z

    Adjustment of U.K. Retail Gasoline Prices to Cost Changes. ”The Behavior of Retail Gasoline Prices: Symmetric or Not? ”documented that retail gasoline prices respond more quickly

  18. Electric and Gasoline Vehicle Lifecycle Cost and Energy-Use Model

    E-Print Network [OSTI]

    Delucchi, Mark; Burke, Andy; Lipman, Timothy; Miller, Marshall

    2000-01-01T23:59:59.000Z

    the gasoline-equivalent fuel retail price, excluding exciseprice is the full retail price of gasoline, including allon the retail cost and break-even gasoline price, because

  19. Edgeworth Price Cycles, Cost-based Pricing and Sticky Pricing in Retail Gasoline Markets

    E-Print Network [OSTI]

    Noel, Michael

    2004-01-01T23:59:59.000Z

    Johnson. “Gas Wars: Retail Gasoline Price Fluctua- tions”,were collected on retail gasoline prices, wholesale (rack)ancillary information. Retail gasoline prices, RET AIL mt ,

  20. Asymmetric Price Adjustment and Consumer Search: An Examination of the Retail Gasoline Market

    E-Print Network [OSTI]

    Lewis, Matt

    2004-01-01T23:59:59.000Z

    George. (2004) “Retail Gasoline Price Dynamics and Localof Information and Retail Gasoline Price Behavior: Andocumented that retail gasoline prices respond more quickly

  1. Do Gasoline Prices Resond Asymmetrically to Cost Shocks? The Confounding Effect of Edgeworth Cycles

    E-Print Network [OSTI]

    Noel, Michael

    2007-01-01T23:59:59.000Z

    Atkinson, B . (2006) "Retail Gasoline Price Cycles: Evidenceof Adjustment of U K Retail Gasoline Prices to Cost Changes"1993) "Gas Wars: Retail Gasoline Price Fluctuations", of and

  2. The Speed of Gasoline Price Response in Markets With and Without Edgeworth Cycles

    E-Print Network [OSTI]

    Lewis, Matt; Noel, Michael

    2009-01-01T23:59:59.000Z

    An Examination of the Retail Gasoline Market,” July 2005.OH. , “Temporary Wholesale Gasoline Price Spikes have Long-from the Toronto Retail Gasoline Market,” Journal of

  3. Clearing the Air: The Clean Air Act, GATT and the WTO's Reformulated Gasoline Decision

    E-Print Network [OSTI]

    McCrory, Martin A.; Richards, Eric L.

    1998-01-01T23:59:59.000Z

    Reformulated and Conventional Gasoline, 5 MwIN. J. GLOBALReformulated and Conventional Gasoline, 35 I.L.M. 274, 277 (regulations governing gasoline formulation to ensure that

  4. Impact of California Reformulated Gasoline on Motor Vehicle Emissions. 2. Volatile Organic Compound Speciation and Reactivity

    E-Print Network [OSTI]

    Kirchstetter, Thomas; Singer, Brett; Harley, Robert

    1999-01-01T23:59:59.000Z

    California Reformulated Gasoline On Motor Vehicle EmissionsCalifornia Reformulated Gasoline on Motor Vehicle EmmissionsBerkeley Environ. ScLTechnoL gasoline Impact California of

  5. Evidence of a Shift in the Short-Run Price Elasticity of Gasoline Demand

    E-Print Network [OSTI]

    Hughes, Jonathan; Knittel, Christopher R; Sperling, Dan

    2007-01-01T23:59:59.000Z

    An Empirical-Analysis of Gasoline Demand in Denmark UsingT. (1991). "Analyzing Gasoline Demand Elasticities: AConsumer Adjustment to a Gasoline Tax." The Review of

  6. Impact of California Reformulated Gasoline On Motor Vehicle Emissions. 1. Mass Emission Rates

    E-Print Network [OSTI]

    Kirchstetter, Thomas W.; Singer, Brett C.; Harley, Robert A.

    1999-01-01T23:59:59.000Z

    California reformulated gasoline on motor vehicle emissions.Impact of California Reformulated Gasoline OIl Motor Vehicleprogress, increased vehicle Gasoline Motor on Vehicle travel

  7. Do Gasoline Prices Resond Asymmetrically to Cost Shocks? The Confounding Effect of Edgeworth Cycles

    E-Print Network [OSTI]

    Noel, Michael

    2007-01-01T23:59:59.000Z

    Atkinson, B . (2006) "Retail Gasoline Price Cycles: EvidenceEvidence on Asymmetric Gasoline Price Re­ and Statistics "of Adjustment of U K Retail Gasoline Prices to Cost Changes"

  8. Development of a Fischer-Tropsch Gasoline Process for the Steam Hydrogasification Technology

    E-Print Network [OSTI]

    Li, Yang

    2013-01-01T23:59:59.000Z

    M. ,   et   al. ,   Gasoline  conversion:  reactivity  al. ,   Methanol   to   gasoline   over   zeolite   H-­?of a Fischer-Tropsch Gasoline Process for the Steam

  9. Demand for gasoline is more price-inelastic than commonly thought

    E-Print Network [OSTI]

    Havranek, Tomas; Irsova, Zuzana; Janda, Karel

    2011-01-01T23:59:59.000Z

    of Transportation and Gasoline Demand. ” Bell Journal ofA Semiparametric Analysis of Gasoline Demand in the Uniteda dynamic demand function for gasoline with di?erent schemes

  10. Lifecycle Analysis of Air Quality Impacts of Hydrogen and Gasoline Transportation Fuel Pathways

    E-Print Network [OSTI]

    Wang, Guihua

    2008-01-01T23:59:59.000Z

    of hydrogen, methanol and gasoline as fuels for fuel cellon Environmental Quality (TCEQ). Gasoline Vapor Recovery (Quality Impacts of Hydrogen and Gasoline Transportation Fuel

  11. The Implications of a Gasoline Price Floor for the California Budget and Greenhouse Gas Emissions

    E-Print Network [OSTI]

    Borenstein, Severin

    2008-01-01T23:59:59.000Z

    May 2004. Espey, M. “Gasoline Demand Revisited: AnRun Price Elasticity of Gasoline Demand,” Energy Journal,114. Poterba, J. “Is the Gasoline Tax Regressive? ,” in D.

  12. Vertical Integration in Gasoline Supply: An Empirical Test of Raising Rivals' Costs

    E-Print Network [OSTI]

    Gilbert, Richard; Hastings, Justine

    2001-01-01T23:59:59.000Z

    Vertical Integration in Gasoline Supply: An Empirical Testfor the reÞning and distribution of gasoline and the whole-sale price of unbranded gasoline sold to independent

  13. Gasoline Price Differences: Taxes, Pollution Regulations, Mergers, Market Power, and Market Conditions

    E-Print Network [OSTI]

    Chouinard, Hayley; Perloff, Jeffrey M.

    2002-01-01T23:59:59.000Z

    1 2. A Reduced-Form Gasoline PriceThe Case of Retail Gasoline Markets,” The Journal of Law andof Organizational Form in Gasoline Retailing and the Costs

  14. Vertical Integration in Gasoline Supply: An Empirical Test of Raising Rivals' Costs

    E-Print Network [OSTI]

    Gilbert, Richard; Hastings, Justine

    2001-01-01T23:59:59.000Z

    Vertical Integration in Gasoline Supply: An Empirical Testoligopoly, market power, gasoline Abstract: This paperand distribution of gasoline and the wholesale price of

  15. Edgeworth Price Cycles, Cost-based Pricing and Sticky Pricing in Retail Gasoline Markets

    E-Print Network [OSTI]

    Noel, Michael

    2004-01-01T23:59:59.000Z

    Robbery, An Analysis of the Gasoline Crisis”, Bloomington:Dynamic Pricing in Retail gasoline Markets”, RAND Journal ofR. Gilbert. “Do Gasoline Markets Respond Asymmetrically to

  16. Asymmetric Price Adjustment and Consumer Search: An Examination of the Retail Gasoline Market

    E-Print Network [OSTI]

    Lewis, Matt

    2004-01-01T23:59:59.000Z

    and R. Gilbert (1997) “Do Gasoline Prices Respond Asymmet-George. (2004) “Retail Gasoline Price Dynamics and LocalAsymmetries in Local Gasoline Markets” Energy Economics

  17. Inductive Effect of Alkyl Chains on Alcohol Dehydration at Bridge...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Inductive Effect of Alkyl Chains on Alcohol Dehydration at Bridge-Bonded Oxygen Vacancies of TiO2(110). Inductive Effect of Alkyl Chains on Alcohol Dehydration at Bridge-Bonded...

  18. Enhancement of alkylation catalysts for improved supercritical fluid regeneration

    DOE Patents [OSTI]

    Ginosar, Daniel M. (Idaho Falls, ID); Petkovic, Lucia M. (Idaho Falls, ID)

    2010-12-28T23:59:59.000Z

    A method of modifying an alkylation catalyst to reduce the formation of condensed hydrocarbon species thereon. The method comprises providing an alkylation catalyst comprising a plurality of active sites. The plurality of active sites on the alkylation catalyst may include a plurality of weakly acidic active sites, intermediate acidity active sites, and strongly acidic active sites. A base is adsorbed to a portion of the plurality of active sites, such as the strongly acidic active sites, selectively poisoning the strongly acidic active sites. A method of modifying the alkylation catalyst by providing an alkylation catalyst comprising a pore size distribution that sterically constrains formation of the condensed hydrocarbon species on the alkylation catalyst or by synthesizing the alkylation catalyst to comprise a decreased number of strongly acidic active sites is also disclosed, as is a method of improving a regeneration efficiency of the alkylation catalyst.

  19. A study of the physics and chemistry of knock in modern SI engines and their relationship to the octane tests

    E-Print Network [OSTI]

    Mittal, Vikram

    2009-01-01T23:59:59.000Z

    Avoiding knock is the major design constraint for spark ignition engines because of the unacceptable noise and engine damage associated with it. Hence, the Research and Motor Octane Number (RON and MON) tests were established ...

  20. The potential for low petroleum gasoline

    SciTech Connect (OSTI)

    Hadder, G.R.; Webb, G.M.; Clauson, M.

    1996-06-01T23:59:59.000Z

    The Energy Policy Act requires the Secretary of Energy to determine the feasibility of producing sufficient replacement fuels to replace at least 30 percent of the projected consumption of motor fuels by light duty vehicles in the year 2010. The Act also requires the Secretary to determine the greenhouse gas implications of the use of replacement fuels. A replacement fuel is a non-petroleum portion of gasoline, including certain alcohols, ethers, and other components. The Oak Ridge National Laboratory Refinery Yield Model has been used to study the cost and refinery impacts for production of {open_quotes}low petroleum{close_quotes} gasolines, which contain replacement fuels. The analysis suggests that high oxygenation is the key to meeting the replacement fuel target, and a major contributor to cost increase is investment in processes to produce and etherify light olefins. High oxygenation can also increase the costs of control of vapor pressure, distillation properties, and pollutant emissions of gasolines. Year-round low petroleum gasoline with near-30 percent non-petroleum components might be produced with cost increases of 23 to 37 cents per gallon of gasoline, and with greenhouse gas emissions changes between a 3 percent increase and a 16 percent decrease. Crude oil reduction, with decreased dependence on foreign sources, is a major objective of the low petroleum gasoline program. For year-round gasoline with near-30 percent non-petroleum components, crude oil use is reduced by 10 to 12 percent, at a cost $48 to $89 per barrel. Depending upon resolution of uncertainties about extrapolation of the Environmental Protection Agency Complex Model for pollutant emissions, availability of raw materials and other issues, costs could be lower or higher.

  1. Catalytic, Enantioselective Alkylations of N,O-Acetals

    E-Print Network [OSTI]

    Lectka, Thomas

    , 10998-10999. (2) Hoveyda et al. have developed a Ni-catalyzed alkylation reaction of allylic acetalsCatalytic, Enantioselective Alkylations of N,O-Acetals Dana Ferraris, Travis Dudding, Brandon Young alkylation reactions of acetals have attained a prominent position in organic synthesis.1 Methods employing

  2. Catalytic Synthesis of n-Alkyl Arenes through Alkyl Group Cross-Metathesis

    E-Print Network [OSTI]

    Dobereiner, Graham E.

    n-Alkyl arenes were prepared in a one-pot tandem dehydrogenation/olefin metathesis/hydrogenation sequence directly from alkanes and ethylbenzene. Excellent selectivity was observed when (tBuPCP)IrH[subscript 2] was paired ...

  3. The Use of Fuel Chemistry and Property Variations to Evaluate the Robustness of Variable Compression Ratio as a Control Method for Gasoline HCCI

    SciTech Connect (OSTI)

    Szybist, James P [ORNL; Bunting, Bruce G [ORNL

    2007-01-01T23:59:59.000Z

    On a gasoline engine platform, homogeneous charge compression ignition (HCCI) holds the promise of improved fuel economy and greatly reduced engine-out NOx emissions, without an increase in particulate matter emissions. In this investigation, a variable compression ratio (CR) engine equipped with a throttle and intake air heating was used to test the robustness of these control parameters to accommodate a series of fuels blended from reference gasoline, straight run refinery naptha, and ethanol. Higher compression ratios allowed for operation with higher octane fuels, but operation could not be achieved with the reference gasoline, even at the highest compression ratio. Compression ratio and intake heat could be used separately or together to modulate combustion. A lambda of 2 provided optimum fuel efficiency, even though some throttling was necessary to achieve this condition. Ethanol did not appear to assist combustion, although only two ethanol-containing fuels were evaluated. The increased pumping work from throttling was minimal compared to the efficiency increases that were the result of lower unburned hydrocarbon (HC) and carbon monoxide (CO) emissions. Low temperature heat release was present for all the fuels, but could be suppressed with a higher intake air temperature. Results will be used to design future fuels and combustion studies with this research platform.

  4. Gasoline from Wood via Integrated Gasification, Synthesis, and Methanol-to-Gasoline Technologies

    SciTech Connect (OSTI)

    Phillips, S. D.; Tarud, J. K.; Biddy, M. J.; Dutta, A.

    2011-01-01T23:59:59.000Z

    This report documents the National Renewable Energy Laboratory's (NREL's) assessment of the feasibility of making gasoline via the methanol-to-gasoline route using syngas from a 2,000 dry metric tonne/day (2,205 U.S. ton/day) biomass-fed facility. A new technoeconomic model was developed in Aspen Plus for this study, based on the model developed for NREL's thermochemical ethanol design report (Phillips et al. 2007). The necessary process changes were incorporated into a biomass-to-gasoline model using a methanol synthesis operation followed by conversion, upgrading, and finishing to gasoline. Using a methodology similar to that used in previous NREL design reports and a feedstock cost of $50.70/dry ton ($55.89/dry metric tonne), the estimated plant gate price is $16.60/MMBtu ($15.73/GJ) (U.S. $2007) for gasoline and liquefied petroleum gas (LPG) produced from biomass via gasification of wood, methanol synthesis, and the methanol-to-gasoline process. The corresponding unit prices for gasoline and LPG are $1.95/gallon ($0.52/liter) and $1.53/gallon ($0.40/liter) with yields of 55.1 and 9.3 gallons per U.S. ton of dry biomass (229.9 and 38.8 liters per metric tonne of dry biomass), respectively.

  5. Demand and Price Uncertainty: Rational Habits in International Gasoline Demand

    E-Print Network [OSTI]

    Scott, K. Rebecca

    2013-01-01T23:59:59.000Z

    global gasoline and diesel price and income elasticities.shift in the short-run price elasticity of gasoline demand.Habits and Uncertain Relative Prices: Simulating Petrol Con-

  6. Demand and Price Volatility: Rational Habits in International Gasoline Demand

    E-Print Network [OSTI]

    Scott, K. Rebecca

    2011-01-01T23:59:59.000Z

    shift in the short-run price elasticity of gasoline demand.A meta-analysis of the price elasticity of gasoline demand.2007. Consumer demand un- der price uncertainty: Empirical

  7. Revisiting the Income Effect: Gasoline Prices and Grocery Purchases

    E-Print Network [OSTI]

    Gicheva, Dora; Hastings, Justine; Villas-Boas, Sofia B

    2008-01-01T23:59:59.000Z

    Gasoline and Crude Oil Prices, 2000-2006 Figure I:Weekly Gasoline and Crude Oil Prices for 2001- 2006 Crudeargue that increases in oil prices may lead to recessions

  8. Fact #835: August 25, Average Historical Annual Gasoline Pump...

    Energy Savers [EERE]

    5: August 25, Average Historical Annual Gasoline Pump Price, 1929-2013 Fact 835: August 25, Average Historical Annual Gasoline Pump Price, 1929-2013 When adjusted for inflation,...

  9. Fact #835: August 25, Average Annual Gasoline Pump Price, 1929...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    5: August 25, Average Annual Gasoline Pump Price, 1929-2013 Fact 835: August 25, Average Annual Gasoline Pump Price, 1929-2013 When adjusted for inflation, the average annual...

  10. Combustion and Emissions Performance of Dual-Fuel Gasoline and...

    Broader source: Energy.gov (indexed) [DOE]

    Combustion and Emissions Performance of Dual-Fuel Gasoline and Diesel HECC on a Multi-Cylinder Light Duty Diesel Engine Combustion and Emissions Performance of Dual-Fuel Gasoline...

  11. Fact #835: August 25, 2014 Average Annual Gasoline Pump Price...

    Broader source: Energy.gov (indexed) [DOE]

    5: August 25, 2014 Average Annual Gasoline Pump Price, 1929-2013 - Dataset Fact 835: August 25, 2014 Average Annual Gasoline Pump Price, 1929-2013 - Dataset Excel file with...

  12. Why Do Motor Gasoline Prices Vary Regionally? California Case Study

    Reports and Publications (EIA)

    1998-01-01T23:59:59.000Z

    Analysis of the difference between the retail gasoline prices in California and the average U.S. retail prices.

  13. National Survey of E85 and Gasoline Prices

    SciTech Connect (OSTI)

    Bergeron, P.

    2008-10-01T23:59:59.000Z

    Study compares the prices of E85 and regular gasoline nationally and regionally over time for one year.

  14. NAFTA and gasoline: Canada, U. S. , Mexico

    SciTech Connect (OSTI)

    Not Available

    1993-03-31T23:59:59.000Z

    The North American Free Trade Agreement has become a hotly debated topic all over the world, but especially in the countries involved: Mexico, United States, and Canada. Comments made by high ranking officials imply there are differences to reconcile before the agreement is passed. Toward seeing these countries in trio, this issue compares gasoline markets and some energy perspectives. The purpose of this article is to contribute to understanding of the three countries through their petroleum industry structure. Gasoline consumption and retail delivery infrastructure are compared and contrasted to illustrate the differences among the NAFTA countries.

  15. Gasoline prices continue to increase (short version)

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"Click worksheet9,1,50022,3,,,,6,1,,781 2,328 2,683DieselValues shown for(long24, 2014 GasolineGasoline

  16. Pollutant Emissions from Gasoline Combustion. 1. Dependence on Fuel

    E-Print Network [OSTI]

    Utah, University of

    Pollutant Emissions from Gasoline Combustion. 1. Dependence on Fuel Structural Functionalities H O fractions of gasoline fuels, the Utah Surrogate Mechanisms is extended to include submecha- nisms of gasoline surrogate compounds using a set of mechanism generation techniques. The mechanism yields very good

  17. Author's personal copy Gasoline prices and traffic safety in Mississippi

    E-Print Network [OSTI]

    Levinson, David M.

    Author's personal copy Gasoline prices and traffic safety in Mississippi Guangqing Chi a, , Arthur November 2010 Keywords: Gasoline prices Traffic crashes Traffic safety Age Gender Race Problem: Limited literature suggests that gasoline prices have substantial effects on reducing fatal crashes. However

  18. What Do Consumers Believe About Future Gasoline Soren T. Anderson

    E-Print Network [OSTI]

    Silver, Whendee

    What Do Consumers Believe About Future Gasoline Prices? Soren T. Anderson Michigan State University of consumers about their expectations of future gasoline prices. Overall, we find that consumer beliefs follow a random walk, which we deem a reasonable forecast of gasoline prices, but we find a deviation from

  19. Vertical Relationships and Competition in Retail Gasoline Markets

    E-Print Network [OSTI]

    California at Berkeley. University of

    PWP-075 Vertical Relationships and Competition in Retail Gasoline Markets: Empirical Evidence from in Retail Gasoline Markets Empirical Evidence from Contract Changes in Southern California Justine S, if any, of the differences in retail gasoline prices between markets is attributable to differences

  20. ISSN 1745-9648 Gasoline Prices Jump Up on Mondays

    E-Print Network [OSTI]

    Feigon, Brooke

    ISSN 1745-9648 Gasoline Prices Jump Up on Mondays: an Outcome of Aggressive Competition? by Ã?ystein Research Council is gratefully acknowledged. #12;Gasoline prices jump up on Mondays: An outcome, 2008 Abstract This paper examines Norwegian gasoline pump prices using daily station

  1. Empirical Regularities of Asymmetric Pricing in the Gasoline Industry

    E-Print Network [OSTI]

    Niebur, Ernst

    Empirical Regularities of Asymmetric Pricing in the Gasoline Industry Marc Remer August 2, 2010 pricing in the retail gasoline industry, and also documents empirical regularities in the market. I find of asymmetric price movements in the retail gasoline industry. Yet, there is no general agreement as to whether

  2. LAMINAR BURNING VELOCITY OF GASOLINES WITH ADDITION OF ETHANOL

    E-Print Network [OSTI]

    Boyer, Edmond

    1 LAMINAR BURNING VELOCITY OF GASOLINES WITH ADDITION OF ETHANOL P. Dirrenberger1 , P.A. Glaude*1 (2014) 162-169" DOI : 10.1016/j.fuel.2013.07.015 #12;2 LAMINAR BURNING VELOCITY OF GASOLINES, Sweden Abstract The adiabatic laminar burning velocities of a commercial gasoline and of a model fuel (n

  3. HCCI experiments with gasoline surrogate fuels modeled by a semidetailed chemical kinetic model

    SciTech Connect (OSTI)

    Andrae, J.C.G. [Dept. of Chemical Engineering and Technology, Royal Institute of Technology (KTH), SE-100 44 Stockholm (Sweden); Head, R.A. [Shell Technology Centre Thornton, P.O. Box 1, Chester CH1 3SH (United Kingdom)

    2009-04-15T23:59:59.000Z

    Experiments in a homogeneous charge compression ignition (HCCI) engine have been conducted with four gasoline surrogate fuel blends. The pure components in the surrogate fuels consisted of n-heptane, isooctane, toluene, ethanol and diisobutylene and fuel sensitivities (RON-MON) in the fuel blends ranged from two to nine. The operating conditions for the engine were p{sub in}=0.1 and 0.2 MPa, T{sub in}=80 and 250 C, {phi}=0.25 in air and engine speed 1200 rpm. A semidetailed chemical kinetic model (142 species and 672 reactions) for gasoline surrogate fuels, validated against ignition data from experiments conducted in shock tubes for gasoline surrogate fuel blends at 1.0{<=} p{<=}5.0MPa, 700{<=} T{<=}1200 K and {phi}=1.0, was successfully used to qualitatively predict the HCCI experiments using a single zone modeling approach. The fuel blends that had higher fuel sensitivity were more resistant to autoignition for low intake temperature and high intake pressure and less resistant to autoignition for high intake temperature and low intake pressure. A sensitivity analysis shows that at high intake temperature the chemistry of the fuels ethanol, toluene and diisobutylene helps to advance ignition. This is consistent with the trend that fuels with the least Negative Temperature Coefficient (NTC) behavior show the highest octane sensitivity, and become less resistant to autoignition at high intake temperatures. For high intake pressure the sensitivity analysis shows that fuels in the fuel blend with no NTC behavior consume OH radicals and acts as a radical scavenger for the fuels with NTC behavior. This is consistent with the observed trend of an increase in RON and fuel sensitivity. With data from shock tube experiments in the literature and HCCI modeling in this work, a correlation between the reciprocal pressure exponent on the ignition delay to the fuel sensitivity and volume percentage of single-stage ignition fuel in the fuel blend was found. Higher fuel sensitivity and single-stage fuel content generally gives a lower value of the pressure exponent. This helps to explain the results obtained while boosting the intake pressure in the HCCI engine. (author)

  4. IDENTIFYING THE USAGE PATTERNS OF METHYL TERT-BUTYL ETHER (MTBE) AND OTHER OXYGENATES IN GASOLINE USING GASOLINE

    E-Print Network [OSTI]

    IDENTIFYING THE USAGE PATTERNS OF METHYL TERT-BUTYL ETHER (MTBE) AND OTHER OXYGENATES IN GASOLINE USING GASOLINE SURVEYS By Michael J. Moran, Rick M. Clawges, and John S. Zogorski U.S. Geological Survey 1608 Mt. View Rapid City, SD 57702 Methyl tert-butyl ether (MTBE) is commonly added to gasoline

  5. Price changes in the gasoline market: Are Midwestern gasoline prices downward sticky?

    SciTech Connect (OSTI)

    NONE

    1999-03-01T23:59:59.000Z

    This report examines a recurring question about gasoline markets: why, especially in times of high price volatility, do retail gasoline prices seem to rise quickly but fall back more slowly? Do gasoline prices actually rise faster than they fall, or does this just appear to be the case because people tend to pay more attention to prices when they`re rising? This question is more complex than it might appear to be initially, and it has been addressed by numerous analysts in government, academia and industry. The question is very important, because perceived problems with retail gasoline pricing have been used in arguments for government regulation of prices. The phenomenon of prices at different market levels tending to move differently relative to each other depending on direction is known as price asymmetry. This report summarizes the previous work on gasoline price asymmetry and provides a method for testing for asymmetry in a wide variety of situations. The major finding of this paper is that there is some amount of asymmetry and pattern asymmetry, especially at the retail level, in the Midwestern states that are the focus of the analysis. Nevertheless, both the amount asymmetry and pattern asymmetry are relatively small. In addition, much of the pattern asymmetry detected in this and previous studies could be a statistical artifact caused by the time lags between price changes at different points in the gasoline distribution system. In other words, retail gasoline prices do sometimes rise faster than they fall, but this is largely a lagged market response to an upward shock in the underlying wholesale gasoline or crude oil prices, followed by a return toward the previous baseline. After consistent time lags are factored out, most apparent asymmetry disappears.

  6. Reformulated gasoline: Costs and refinery impacts

    SciTech Connect (OSTI)

    Hadder, G.R.

    1994-02-01T23:59:59.000Z

    Studies of reformulated gasoline (RFG) costs and refinery impacts have been performed with the Oak Ridge National Laboratory Refinery Yield Model (ORNL-RYM), a linear program which has been updated to blend gasolines to satisfy emissions constraints defined by preliminary complex emissions models. Policy makers may use the reformulation cost knee (the point at which costs start to rise sharply for incremental emissions control) to set emissions reduction targets, giving due consideration to the differences between model representations and actual refining operations. ORNL-RYM estimates that the reformulation cost knee for the US East Coast (PADD I) is about 15.2 cents per gallon with a 30 percent reduction of volatile organic compounds (VOCs). The estimated cost knee for the US Gulf Coast (PADD III) is about 5.5 cents per gallon with a VOC reduction of 35 percent. Reid vapor pressure (RVP) reduction is the dominant VOC reduction mechanism. Even with anti-dumping constraints, conventional gasoline appears to be an important sink which permits RFG to be blended with lower aromatics and sulfur contents in PADD III. In addition to the potentially large sensitivity of RFG production to different emissions models, RFG production is sensitive to the non-exhaust VOC share assumption for a particular VOC model. ORNL-RYM has also been used to estimate the sensitivity of RFG production to the cost of capital; to the RVP requirements for conventional gasoline; and to the percentage of RFG produced in a refining region.

  7. A shock tube study of iso-octane ignition at elevated pressures: The influence of diluent gases

    SciTech Connect (OSTI)

    Shen, Hsi-Ping S.; Vanderover, Jeremy; Oehlschlaeger, Matthew A. [Department of Mechanical, Aerospace, and Nuclear Engineering, Rensselaer Polytechnic Institute, 110 Eighth Street, JEC 2049, Troy, NY 12180 (United States)

    2008-12-15T23:59:59.000Z

    The ignition of iso-octane/air and iso-octane/O{sub 2}/Ar ({proportional_to}20% O{sub 2}) mixtures was studied in a shock tube at temperatures of 868-1300 K, pressures of 7-58 atm, and equivalence ratios {phi}=1.0, 0.5, and 0.25. Ignition times were determined using endwall OH* emission and sidewall piezoelectric pressure measurements. Measured iso-octane/air ignition times agreed well with the previously published results. Mixtures with argon as the diluent exhibited ignition times 20% shorter, for most conditions, than those with nitrogen as the diluent (iso-octane/air mixtures). The difference in measured ignition times for mixtures containing argon and nitrogen as the diluent gas can be attributed to the differing heat capacities of the two diluent species and the level of induction period heat release prior to ignition. Kinetic model predictions of ignition time from three mechanisms are compared to the experimental data. The mechanisms overpredict the ignition times but accurately capture the influence of diluent gas on iso-octane ignition time, indicating that the mechanisms predict an appropriate amount of induction period heat release. (author)

  8. A Simple, Accurate Model for Alkyl Adsorption on Late Transition...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    on Late Transition Metals. A Simple, Accurate Model for Alkyl Adsorption on Late Transition Metals. Abstract: A simple model that predicts the adsorption energy of an...

  9. Detailed Kinetic Modeling of Gasoline Surrogate Mixtures

    SciTech Connect (OSTI)

    Mehl, M; Curran, H J; Pitz, W J; Westbrook, C K

    2009-03-09T23:59:59.000Z

    Real fuels are complex mixtures of thousands of hydrocarbon compounds including linear and branched paraffins, naphthenes, olefins and aromatics. It is generally agreed that their behavior can be effectively reproduced by simpler fuel surrogates containing a limited number of components. In this work, a recently revised version of the kinetic model by the authors is used to analyze the combustion behavior of several components relevant to gasoline surrogate formulation. Particular attention is devoted to linear and branched saturated hydrocarbons (PRF mixtures), olefins (1-hexene) and aromatics (toluene). Model predictions for pure components, binary mixtures and multi-component gasoline surrogates are compared with recent experimental information collected in rapid compression machine, shock tube and jet stirred reactors covering a wide range of conditions pertinent to internal combustion engines. Simulation results are discussed focusing attention on the mixing effects of the fuel components.

  10. Vertical Relationships and Competition in Retail Gasoline Markets: An Empirical Evidence from Contract Changes in Southern California

    E-Print Network [OSTI]

    Hastings, Justine

    2000-01-01T23:59:59.000Z

    The Behavior of Retail Gasoline Prices: Symmetric or Not? ”vertical contracts and retail gasoline prices. The thirdthe differences in retail gasoline prices between markets is

  11. New Vehicle Choice, Fuel Economy and Vehicle Incentives: An Analysis of Hybrid Tax Credits and the Gasoline Tax

    E-Print Network [OSTI]

    Martin, Elliott William

    2009-01-01T23:59:59.000Z

    Run Price Elasticity of Gasoline Demand', The Energy Journal2007) The Link Between Gasoline Prices and Vehicle Sales:Tax Credits and the Gasoline Tax Elliot William Martin

  12. Applications of contaminant fate and bioaccumulation models in assessing ecological risks of chemicals: A case study for gasoline hydrocarbons

    E-Print Network [OSTI]

    MacLeod, Matthew; McKone, Thomas E.; Foster, Karen L.; Maddalena, Randy L.; Parkerton, Thomas F.; Mackay, Don

    2004-01-01T23:59:59.000Z

    the composition of the gasoline inventory, and can beand exposure assessment for gasoline; Trent University:of Chemicals: A Case Study for Gasoline Hydrocarbons Matthew

  13. Turn of the century refueling: A review of innovations in early gasoline refueling methods and analogies for hydrogen

    E-Print Network [OSTI]

    Melaina, Marc W

    2007-01-01T23:59:59.000Z

    NJ. Koenig, R. , 1984. Gasoline alley: service stations area parametric analysis of US gasoline station networks. Inof innovations in early gasoline refueling methods and

  14. New Vehicle Choices, Fuel Economy and Vehicle Incentives: An Analysis of Hybrid Tax Credits and Gasoline Tax

    E-Print Network [OSTI]

    Martin, Elliot William

    2009-01-01T23:59:59.000Z

    Run Price Elasticity of Gasoline Demand', The Energy Journal2007) The Link Between Gasoline Prices and Vehicle Sales:Tax Credits and the Gasoline Tax Elliot William Martin

  15. The Extraction of Gasoline from Natural Gas

    E-Print Network [OSTI]

    Schroeder, J. P.

    1914-05-15T23:59:59.000Z

    for the quantitative estimation of the condensable gasoline consti- tuents of so-called rtwetn natural gas» Three general lines of experimentation suggested themselves after a preliminary study of the problem. These were the separation of a liqui- fied sample... fractionation of a mixture of natural gases are, however, not available in the ordinary laboratory, so this method altho successful and accurate is hardly practical. Even after the fractionation of the gas has ^lebeau and Damiens in Chen. Abstr. 7, 1356...

  16. European Lean Gasoline Direct Injection Vehicle Benchmark

    SciTech Connect (OSTI)

    Chambon, Paul H [ORNL] [ORNL; Huff, Shean P [ORNL] [ORNL; Edwards, Kevin Dean [ORNL] [ORNL; Norman, Kevin M [ORNL] [ORNL; Prikhodko, Vitaly Y [ORNL] [ORNL; Thomas, John F [ORNL] [ORNL

    2011-01-01T23:59:59.000Z

    Lean Gasoline Direct Injection (LGDI) combustion is a promising technical path for achieving significant improvements in fuel efficiency while meeting future emissions requirements. Though Stoichiometric Gasoline Direct Injection (SGDI) technology is commercially available in a few vehicles on the American market, LGDI vehicles are not, but can be found in Europe. Oak Ridge National Laboratory (ORNL) obtained a European BMW 1-series fitted with a 2.0l LGDI engine. The vehicle was instrumented and commissioned on a chassis dynamometer. The engine and after-treatment performance and emissions were characterized over US drive cycles (Federal Test Procedure (FTP), the Highway Fuel Economy Test (HFET), and US06 Supplemental Federal Test Procedure (US06)) and steady state mappings. The vehicle micro hybrid features (engine stop-start and intelligent alternator) were benchmarked as well during the course of that study. The data was analyzed to quantify the benefits and drawbacks of the lean gasoline direct injection and micro hybrid technologies from a fuel economy and emissions perspectives with respect to the US market. Additionally that data will be formatted to develop, substantiate, and exercise vehicle simulations with conventional and advanced powertrains.

  17. E-Print Network 3.0 - alkylated silicon111 surfaces Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    13 N-Alkyl-polyethylenimine 2 kDastabilized superparamagnetic iron oxide nanoparticles for MRI cell tracking Summary: N-Alkyl-polyethylenimine 2 kDa-stabilized...

  18. E-Print Network 3.0 - alkyl chain bis-quaternary Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    by alkyl and alkylthiol chains, while in the archipelago model2 aromatic and naphthenic moieties... , the aromatic rings were linked or bridged through alkyl and...

  19. Carbonyl Emissions from Gasoline and Diesel Motor Vehicles

    E-Print Network [OSTI]

    Jakober, Chris A.

    2008-01-01T23:59:59.000Z

    emissions from gasoline and diesel motor vehicles. Environ.of four dilutions of diesel engine exhaust for a subchronicautomobiles and heavy-duty diesel trucks. Environ. Sci.

  20. Table 44. Refiner Motor Gasoline Volumes by Formulation, Sales...

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    250 Energy Information AdministrationPetroleum Marketing Annual 1999 Table 44. Refiner Motor Gasoline Volumes by Formulation, Sales Type, PAD District, and State (Thousand Gallons...

  1. Table 32. Conventional Motor Gasoline Prices by Grade, Sales...

    Gasoline and Diesel Fuel Update (EIA)

    Information AdministrationPetroleum Marketing Annual 1998 Table 32. Conventional Motor Gasoline Prices by Grade, Sales Type, PAD District, and State (Cents per Gallon...

  2. Table 44. Refiner Motor Gasoline Volumes by Formulation, Sales...

    Gasoline and Diesel Fuel Update (EIA)

    - - - - W W - - - - - - See footnotes at end of table. 44. Refiner Motor Gasoline Volumes by Formulation, Sales Type, PAD District, and State 292 Energy...

  3. Table 43. Refiner Motor Gasoline Volumes by Grade, Sales Type...

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    220 Energy Information AdministrationPetroleum Marketing Annual 1998 Table 43. Refiner Motor Gasoline Volumes by Grade, Sales Type, PAD District, and State (Thousand Gallons per...

  4. Table 34. Reformulated Motor Gasoline Prices by Grade, Sales...

    Gasoline and Diesel Fuel Update (EIA)

    Information AdministrationPetroleum Marketing Annual 1998 Table 34. Reformulated Motor Gasoline Prices by Grade, Sales Type, PAD District, and Selected States (Cents per...

  5. Table 48. Prime Supplier Sales Volumes of Motor Gasoline by...

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    Petroleum Marketing Annual 1995 Table 48. Prime Supplier Sales Volumes of Motor Gasoline by Grade, Formulation, PAD District, and State (Thousand Gallons per Day) -...

  6. Table 34. Reformulated Motor Gasoline Prices by Grade, Sales...

    Gasoline and Diesel Fuel Update (EIA)

    Information Administration Petroleum Marketing Annual 1995 Table 34. Reformulated Motor Gasoline Prices by Grade, Sales Type, PAD District, and State (Cents per Gallon...

  7. Table 43. Refiner Motor Gasoline Volumes by Grade, Sales Type...

    Gasoline and Diesel Fuel Update (EIA)

    220 Energy Information AdministrationPetroleum Marketing Annual 1999 Table 43. Refiner Motor Gasoline Volumes by Grade, Sales Type, PAD District, and State (Thousand Gallons per...

  8. Table 35. Refiner Motor Gasoline Prices by Grade, Sales Type...

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    Energy Information Administration Petroleum Marketing Annual 1995 Table 35. Refiner Motor Gasoline Prices by Grade, Sales Type, PAD District, and State (Cents per Gallon...

  9. Table 35. Refiner Motor Gasoline Prices by Grade, Sales Type...

    Gasoline and Diesel Fuel Update (EIA)

    134 Energy Information AdministrationPetroleum Marketing Annual 1998 Table 35. Refiner Motor Gasoline Prices by Grade, Sales Type, PAD District, and State (Cents per Gallon...

  10. Table 48. Prime Supplier Sales Volumes of Motor Gasoline by...

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    Petroleum Marketing Annual 1998 Table 48. Prime Supplier Sales Volumes of Motor Gasoline by Grade, Formulation, PAD District, and State (Thousand Gallons per Day) -...

  11. Table 32. Conventional Motor Gasoline Prices by Grade, Sales...

    Gasoline and Diesel Fuel Update (EIA)

    - - - - W W - - - - - - See footnotes at end of table. 32. Conventional Motor Gasoline Prices by Grade, Sales Type, PAD District, and State 86 Energy Information...

  12. Table 32. Conventional Motor Gasoline Prices by Grade, Sales...

    U.S. Energy Information Administration (EIA) Indexed Site

    Information Administration Petroleum Marketing Annual 1995 Table 32. Conventional Motor Gasoline Prices by Grade, Sales Type, PAD District, and State (Cents per Gallon...

  13. Table 48. Prime Supplier Sales Volumes of Motor Gasoline by...

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    Petroleum Marketing Annual 1999 Table 48. Prime Supplier Sales Volumes of Motor Gasoline by Grade, Formulation, PAD District, and State (Thousand Gallons per Day) -...

  14. Table 32. Conventional Motor Gasoline Prices by Grade, Sales...

    U.S. Energy Information Administration (EIA) Indexed Site

    - - - - 64.7 64.7 - - - - - - See footnotes at end of table. 32. Conventional Motor Gasoline Prices by Grade, Sales Type, PAD District, and State 86 Energy Information...

  15. Table 33. Oxygenated Motor Gasoline Prices by Grade, Sales Type...

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    - - - - - - - - - - - - See footnotes at end of table. 33. Oxygenated Motor Gasoline Prices by Grade, Sales Type, PAD District, and State 116 Energy Information...

  16. Table 43. Refiner Motor Gasoline Volumes by Grade, Sales Type...

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    Energy Information Administration Petroleum Marketing Annual 1995 Table 43. Refiner Motor Gasoline Volumes by Grade, Sales Type, PAD District, and State (Thousand Gallons per...

  17. Table 33. Oxygenated Motor Gasoline Prices by Grade, Sales Type...

    Gasoline and Diesel Fuel Update (EIA)

    Information Administration Petroleum Marketing Annual 1995 Table 33. Oxygenated Motor Gasoline Prices by Grade, Sales Type, PAD District, and State (Cents per Gallon...

  18. Table 44. Refiner Motor Gasoline Volumes by Formulation, Sales...

    U.S. Energy Information Administration (EIA) Indexed Site

    250 Energy Information AdministrationPetroleum Marketing Annual 1998 Table 44. Refiner Motor Gasoline Volumes by Formulation, Sales Type, PAD District, and State (Thousand Gallons...

  19. Table 34. Reformulated Motor Gasoline Prices by Grade, Sales...

    Gasoline and Diesel Fuel Update (EIA)

    Information AdministrationPetroleum Marketing Annual 1999 Table 34. Reformulated Motor Gasoline Prices by Grade, Sales Type, PAD District, and Selected States (Cents per...

  20. Table 44. Refiner Motor Gasoline Volumes by Formulation, Sales...

    Gasoline and Diesel Fuel Update (EIA)

    Energy Information Administration Petroleum Marketing Annual 1995 Table 44. Refiner Motor Gasoline Volumes by Formulation, Sales Type, PAD District, and State (Thousand Gallons...

  1. Table 35. Refiner Motor Gasoline Prices by Grade, Sales Type...

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    134 Energy Information AdministrationPetroleum Marketing Annual 1999 Table 35. Refiner Motor Gasoline Prices by Grade, Sales Type, PAD District, and State (Cents per Gallon...

  2. Lean Gasoline System Development for Fuel Efficient Small Car...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Vehicle Technologies Program Annual Merit Review and Peer Evaluation ace063smith2011o.pdf More Documents & Publications Lean Gasoline System Development for Fuel...

  3. Reductant Chemistry during LNT Regeneration for a Lean Gasoline...

    Broader source: Energy.gov (indexed) [DOE]

    Oak Ridge National Laboratory VW Scholar at the University of Tennessee Reductant Chemistry during LNT Regeneration for a Lean Gasoline Engine Poster P-09 2010 DEER Directions...

  4. Geographic Area Month Aviation Gasoline Kerosene-Type Jet Fuel

    Gasoline and Diesel Fuel Update (EIA)

    State (Cents per Gallon Excluding Taxes) - Continued Geographic Area Month Aviation Gasoline Kerosene-Type Jet Fuel Kerosene Sales to End Users Sales for Resale Sales to End...

  5. Characterization of Pre-Commercial Gasoline Engine ParticulatesThrough...

    Broader source: Energy.gov (indexed) [DOE]

    Pre-commercial Gasoline Engine Particulates Through Advanced Aerosol Methods Alla Zelenyuk, Paul Reitz, Mark Stewart Pacific Northwest National Laboratory Paul Loeper, Cory Adam,...

  6. Petroleum Products Table 31. Motor Gasoline Prices by Grade...

    Gasoline and Diesel Fuel Update (EIA)

    by Grade, Sales Type, PAD District, and State 56 Energy Information Administration Petroleum Marketing Annual 1996 Table 31. Motor Gasoline Prices by Grade, Sales Type, PAD...

  7. Energy Department Announces First Regional Gasoline Reserve to...

    Office of Environmental Management (EM)

    Ernest Moniz today announced the creation of the first federal regional refined petroleum product reserve containing gasoline. Based on the Energy Department's lessons...

  8. Petroleum Products Table 43. Refiner Motor Gasoline Volumes...

    Gasoline and Diesel Fuel Update (EIA)

    by Grade, Sales Type, PAD District, and State 262 Energy Information Administration Petroleum Marketing Annual 1996 Table 43. Refiner Motor Gasoline Volumes by Grade, Sales Type,...

  9. Petroleum Products Table 43. Refiner Motor Gasoline Volumes...

    Gasoline and Diesel Fuel Update (EIA)

    by Grade, Sales Type, PAD District, and State 262 Energy Information Administration Petroleum Marketing Annual 1997 Table 43. Refiner Motor Gasoline Volumes by Grade, Sales Type,...

  10. Clearing the Air? The Effects of Gasoline Content Regulation on Air Quality

    E-Print Network [OSTI]

    Auffhammer, Maximilian; Kellogg, Ryan

    2009-01-01T23:59:59.000Z

    15 for retail gasoline stations and May 1 – September 15 forof one if retail gasoline stations in county c are requiredseason for retail gasoline distribution stations is June 1 -

  11. Do Gasoline Prices Resond Asymmetrically to Cost Shocks? The Confounding Effect of Edgeworth Cycles

    E-Print Network [OSTI]

    Noel, Michael

    2007-01-01T23:59:59.000Z

    t as determined by gasoline stations is unlikely to beshows a map of all gasoline stations i n central and easterni n Figure 5: Toronto Gasoline Stations Canadian cents per

  12. Evidence of a Shift in the Short-Run Price Elasticity of Gasoline Demand

    E-Print Network [OSTI]

    Hughes, Jonathan; Knittel, Christopher R; Sperling, Dan

    2007-01-01T23:59:59.000Z

    Consumption and Real Retail Gasoline Price for January 19742006. FIGURE 2 Real Retail Gasoline Price for Two Periodsjt is the real retail price of gasoline in month j and year

  13. Asymmetric Price Adjustment and Consumer Search: An Examination of the Retail Gasoline Industry

    E-Print Network [OSTI]

    Lewis, Matt

    2003-01-01T23:59:59.000Z

    Adjustment of U.K. Retail Gasoline Prices to Cost Changes. ”C. and R. Gilbert (1997) “Do Gasoline Prices Respond Asym-Asymmetries in Local Gasoline Markets” Energy Economics

  14. Electric and Gasoline Vehicle Lifecycle Cost and Energy-Use Model

    E-Print Network [OSTI]

    Delucchi, Mark; Burke, Andy; Lipman, Timothy; Miller, Marshall

    2000-01-01T23:59:59.000Z

    147 Lifecycle cost (break-even gasoline price): base-casegrease. 37B part: Fuel Gasoline, for the conventional ICEVs.BTU-from-battery to mi/BTU-gasoline. C OST SUMMARY (F ORD T

  15. Asymmetric Price Adjustment and Consumer Search: An Examination of the Retail Gasoline Market

    E-Print Network [OSTI]

    Lewis, Matt

    2003-01-01T23:59:59.000Z

    Adjustment of U.K. Retail Gasoline Prices to Cost Changes. ”C. and R. Gilbert (1997) “Do Gasoline Prices Respond Asym-Asymmetries in Local Gasoline Markets” Energy Economics

  16. Elucidating secondary organic aerosol from diesel and gasoline vehicles through detailed characterization of

    E-Print Network [OSTI]

    Silver, Whendee

    Elucidating secondary organic aerosol from diesel and gasoline vehicles through detailed 19, 2012 (received for review July 22, 2012) Emissions from gasoline and diesel vehicles composition, mass distribu- tion, and organic aerosol formation potential of emissions from gasoline

  17. Factors Affecting Indoor Air Concentrations of Volatile Organic Compounds at a Site of Subsurface Gasoline Contamination

    E-Print Network [OSTI]

    Fischer, M.L.

    2011-01-01T23:59:59.000Z

    AT A SITE OF SUBSURFACE GASOLINE CONTAMINATION Marc L.A T A SITE OF SUBSURFACE GASOLINE CONTAMINATION Marc L.a site contaminated with gasoline. Although the high V O C

  18. Impacts of Oxygenated Gasoline Use on California Light-Duty Vehicle Emissions

    E-Print Network [OSTI]

    Kirchstetter, Thomas W.; Singer, Brett C.; Harley, Robert A.

    1996-01-01T23:59:59.000Z

    Addition of oxTgenates gasoline will not reduce ozone to (3)I. Y. remote sensing 1994 gasoline samples ranged from 0.7weight reported for liquid gasoline with an RVP Assoc. 1990,

  19. Determination of a peak benzene exposure to consumers at typical self-service gasoline stations

    E-Print Network [OSTI]

    Carapezza, Ted

    2012-06-07T23:59:59.000Z

    . LITERATURE REVIEW Gasoline is a complex mixture of various volatile hydrocarbons blended with several additives depend1ng on the grade of gasoline desired. The goal in blending gasoline 1s to meet two criteria: l) improve antiknock performance, and 2.... This was due to differences in blending. Those identified hydrocarbons amounted to 98 percent, by weight, of the liquid gasoline sample. Benzene in Liquid Gasoline In 1928, Askey , reported that gasolines in West California 2 might contain as much as 17...

  20. Gasoline prices continue to fall (long version)

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"Click worksheet9,1,50022,3,,,,6,1,,781 2,328 2,683DieselValues shown for(long version) ThelongGasoline

  1. Gasoline prices continue to increase (long version)

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"Click worksheet9,1,50022,3,,,,6,1,,781 2,328 2,683DieselValues shown for(long24, 2014 Gasoline prices

  2. Gasoline prices continue to increase (short version)

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"Click worksheet9,1,50022,3,,,,6,1,,781 2,328 2,683DieselValues shown for(long24, 2014 Gasoline

  3. Gasoline prices continue to increase (short version)

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"Click worksheet9,1,50022,3,,,,6,1,,781 2,328 2,683DieselValues shown for(long24, 2014Gasoline prices

  4. Gasoline prices continue to increase (short version)

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"Click worksheet9,1,50022,3,,,,6,1,,781 2,328 2,683DieselValues shown for(long24, 2014Gasoline prices4,

  5. Gasoline prices continue to increase (short version)

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"Click worksheet9,1,50022,3,,,,6,1,,781 2,328 2,683DieselValues shown for(long24, 2014Gasoline prices4,1,

  6. Gasoline prices continue to rise (Short version)

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"Click worksheet9,1,50022,3,,,,6,1,,781 2,328 2,683DieselValues shown for(long24, 2014Gasoline prices4,1,

  7. Gasoline prices continue to rise (long version)

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"Click worksheet9,1,50022,3,,,,6,1,,781 2,328 2,683DieselValues shown for(long24, 2014Gasoline

  8. Gasoline prices inch down (long version)

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"Click worksheet9,1,50022,3,,,,6,1,,781 2,328 2,683DieselValues shownshort version) The U.S.shortGasoline

  9. Lifecycle Analysis of Air Quality Impacts of Hydrogen and Gasoline Transportation Fuel Pathways

    E-Print Network [OSTI]

    Wang, Guihua

    2008-01-01T23:59:59.000Z

    Includes gasoline, diesel, and electric. The following fourIncludes gasoline, diesel, and electric. In this study, weemissions from diesel-truck delivery and electric generation

  10. Fact #858 February 2, 2015 Retail Gasoline Prices in 2014 Experienced...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    8 February 2, 2015 Retail Gasoline Prices in 2014 Experienced the Largest Decline since 2008 Fact 858 February 2, 2015 Retail Gasoline Prices in 2014 Experienced the Largest...

  11. A Comparison of Two Gasoline and Two Diesel Cars with Varying...

    Broader source: Energy.gov (indexed) [DOE]

    A Comparison of Two Gasoline and Two Diesel Cars with Varying Emission Control Technologies A Comparison of Two Gasoline and Two Diesel Cars with Varying Emission Control...

  12. SwRI's HEDGE Technology for High Efficiency, Low Emissions Gasoline...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    SwRI's HEDGE Technology for High Efficiency, Low Emissions Gasoline Engines SwRI's HEDGE Technology for High Efficiency, Low Emissions Gasoline Engines Presentation given at the...

  13. Ethanol Production and Gasoline Prices: A Spurious Correlation

    E-Print Network [OSTI]

    Rothman, Daniel

    Ethanol Production and Gasoline Prices: A Spurious Correlation Christopher R. Knittel and Aaron Smith July 12, 2012 Abstract Ethanol made from corn comprises 10% of US gasoline, up from 3% in 2003-level blend mandates, and supported by direct subsidies such as the Volumetric Ethanol Excise Tax Credit. Some

  14. Lean Gasoline Engine Reductant Chemistry During Lean NOx Trap Regeneration

    SciTech Connect (OSTI)

    Choi, Jae-Soon [ORNL] [ORNL; Prikhodko, Vitaly Y [ORNL] [ORNL; Partridge Jr, William P [ORNL] [ORNL; Parks, II, James E [ORNL; Norman, Kevin M [ORNL] [ORNL; Huff, Shean P [ORNL] [ORNL; Chambon, Paul H [ORNL] [ORNL; Thomas, John F [ORNL] [ORNL

    2010-01-01T23:59:59.000Z

    Lean NOx Trap (LNT) catalysts can effectively reduce NOx from lean engine exhaust. Significant research for LNTs in diesel engine applications has been performed and has led to commercialization of the technology. For lean gasoline engine applications, advanced direct injection engines have led to a renewed interest in the potential for lean gasoline vehicles and, thereby, a renewed demand for lean NOx control. To understand the gasoline-based reductant chemistry during regeneration, a BMW lean gasoline vehicle has been studied on a chassis dynamometer. Exhaust samples were collected and analyzed for key reductant species such as H2, CO, NH3, and hydrocarbons during transient drive cycles. The relation of the reductant species to LNT performance will be discussed. Furthermore, the challenges of NOx storage in the lean gasoline application are reviewed.

  15. Assessment of Summer 1997 motor gasoline price increase

    SciTech Connect (OSTI)

    NONE

    1998-05-01T23:59:59.000Z

    Gasoline markets in 1996 and 1997 provided several spectacular examples of petroleum market dynamics. The first occurred in spring 1996, when tight markets, following a long winter of high demand, resulted in rising crude oil prices just when gasoline prices exhibit their normal spring rise ahead of the summer driving season. Rising crude oil prices again pushed gasoline prices up at the end of 1996, but a warm winter and growing supplies weakened world crude oil markets, pushing down crude oil and gasoline prices during spring 1997. The 1996 and 1997 spring markets provided good examples of how crude oil prices can move gasoline prices both up and down, regardless of the state of the gasoline market in the United States. Both of these spring events were covered in prior Energy Information Administration (EIA) reports. As the summer of 1997 was coming to a close, consumers experienced yet another surge in gasoline prices. Unlike the previous increase in spring 1996, crude oil was not a factor. The late summer 1997 price increase was brought about by the supply/demand fundamentals in the gasoline markets, rather than the crude oil markets. The nature of the summer 1997 gasoline price increase raised questions regarding production and imports. Given very strong demand in July and August, the seemingly limited supply response required examination. In addition, the price increase that occurred on the West Coast during late summer exhibited behavior different than the increase east of the Rocky Mountains. Thus, the Petroleum Administration for Defense District (PADD) 5 region needed additional analysis (Appendix A). This report is a study of this late summer gasoline market and some of the important issues surrounding that event.

  16. Use of a thermodynamic cycle simulation to determine the difference between a propane-fuelled engine and an iso-octane-fuelled engine

    E-Print Network [OSTI]

    Pathak, Dushyant

    2006-04-12T23:59:59.000Z

    the engine cycle simulation to determine the difference between a propane-fuelled and an iso-octane-fuelled engine for the same operating conditions and engine specifications. A comprehensive parametric investigation was conducted to examine the effects...

  17. Adsorption of alkyl amides: monolayer structures and mixing behaviour

    E-Print Network [OSTI]

    Bhinde, Tej

    2011-02-08T23:59:59.000Z

    friction in polymer films, particularly in polyethylene and polypropylene. Pure polymers can often be very ‘sticky’ (e.g. as seen in plastic bags). To prevent this tack, alkyl amides, particularly unsaturated amides such as erucamide, are added...

  18. GASOLINE VEHICLE EXHAUST PARTICLE SAMPLING STUDY

    SciTech Connect (OSTI)

    Kittelson, D; Watts, W; Johnson, J; Zarling, D Schauer,J Kasper, K; Baltensperger, U; Burtscher, H

    2003-08-24T23:59:59.000Z

    The University of Minnesota collaborated with the Paul Scherrer Institute, the University of Wisconsin (UWI) and Ricardo, Inc to physically and chemically characterize the exhaust plume from recruited gasoline spark ignition (SI) vehicles. The project objectives were: (1) Measure representative particle size distributions from a set of on-road SI vehicles and compare these data to similar data collected on a small subset of light-duty gasoline vehicles tested on a chassis dynamometer with a dilution tunnel using the Unified Drive Cycle, at both room temperature (cold start) and 0 C (cold-cold start). (2) Compare data collected from SI vehicles to similar data collected from Diesel engines during the Coordinating Research Council E-43 project. (3) Characterize on-road aerosol during mixed midweek traffic and Sunday midday periods and determine fleet-specific emission rates. (4) Characterize bulk- and size-segregated chemical composition of the particulate matter (PM) emitted in the exhaust from the gasoline vehicles. Particle number concentrations and size distributions are strongly influenced by dilution and sampling conditions. Laboratory methods were evaluated to dilute SI exhaust in a way that would produce size distributions that were similar to those measured during laboratory experiments. Size fractionated samples were collected for chemical analysis using a nano-microorifice uniform deposit impactor (nano-MOUDI). In addition, bulk samples were collected and analyzed. A mixture of low, mid and high mileage vehicles were recruited for testing during the study. Under steady highway cruise conditions a significant particle signature above background was not measured, but during hard accelerations number size distributions for the test fleet were similar to modern heavy-duty Diesel vehicles. Number emissions were much higher at high speed and during cold-cold starts. Fuel specific number emissions range from 1012 to 3 x 1016 particles/kg fuel. A simple relationship between number and mass emissions was not observed. Data were collected on-road to compare weekday with weekend air quality around the Twin Cities area. This portion of the study resulted in the development of a method to apportion the Diesel and SI contribution to on-road aerosol.

  19. Final Technical Report [Development of Catalytic Alkylation and Fluoroalkylation Methods

    SciTech Connect (OSTI)

    Vicic, David A.

    2014-05-01T23:59:59.000Z

    In the early stages of this DOE-funded research project, we sought to prepare and study a well-defined nickel-alkyl complex containing tridentate nitrogen donor ligands. We found that reaction of (TMEDA)NiMe2 (1) with terpyridine ligand cleanly led to the formation of (terpyridyl)NiMe (2), which we also determined to be an active alkylation catalyst. The thermal stability of 2 was unlike that seen for any of the active pybox ligands, and enabled a number of key studies on alkyl transfer reactions to be performed, providing new insights into the mechanism of nickel-mediated alkyl-alkyl cross-coupling reactions. In addition to the mechanistic studies, we showed that the terpyridyl nickel compounds can catalytically cross-couple alkyl iodides in yields up to 98% and bromides in yields up to 46 %. The yields for the bromides can be increased up to 67 % when the new palladium catalyst [(tpy’)Pd-Ph]I is used. The best route to the targeted [(tpy)NiBr] (1) was found to involve the comproportionation reaction of [(dme)NiBr{sub 2}] and [Ni(COD){sub 2}] in the presence of two equivalents of terpyridine. This reaction was driven to high yields of product formation (72 % isolated) by the precipitation of 1 from THF solvent.

  20. An experimental and modeling study of iso-octane ignition delay times under homogeneous charge compression ignition conditions

    SciTech Connect (OSTI)

    He, X.; Donovan, M.T.; Zigler, B.T.; Palmer, T.R.; Walton, S.M.; Wooldridge, M.S.; Atreya, A. [Department of Mechanical Engineering, University of Michigan, 2350 Hayward Street, Ann Arbor, MI 48109-2125 (United States)

    2005-08-01T23:59:59.000Z

    Autoignition of iso-octane was examined using a rapid compression facility (RCF) with iso-octane, oxygen, nitrogen, and argon mixtures. The effects of typical homogeneous charge compression ignition (HCCI) conditions on the iso-octane ignition characteristics were studied. Experimental results for ignition delay times, t{sub ign}, were obtained from pressure time-histories. The experiments were conducted over a range of equivalence ratios (f=0.25-1.0), pressures (P=5.12-23 atm), temperatures (T=943-1027 K), and oxygen mole fractions ({chi}{sub O{sub 2}}=9-21%), and with the addition of trace amounts of combustion product gases (CO{sub 2} and H{sub 2}O). It was found that the ignition delay times were well represented by the expression t{sub ign}=1.3x10{sup -4}P{sup -1.05}f{sup -0.77}{chi}{sub O{sub 2}}{sup -1.41}exp(33,700/R{sub (c} {sub al/mol/K)}T), where P is pressure (atm), T is temperature (K), f is the equivalence ratio (based on iso-octane to O{sub 2} molar ratios), {chi}{sub O{sub 2}} is the oxygen mole percent (%), and t{sub ign} is the ignition delay time (ms). Carbon dioxide was found to have no chemical effect on t{sub ign}. Water was found to systematically decrease t{sub ign} by a small amount (less than 14% for the range of conditions studied). The maximum uncertainty in the measured t{sub ign} is +/-12% with an average uncertainty of +/-6%. The performance of several proposed chemical reaction mechanisms (including detailed, reduced, and skeletal mechanisms) was evaluated in the context of the current experimental results.

  1. Vapor-liquid equilibria of ethanol with 2,2,4-trimethylpentane or octane at 101. 3 kPa

    SciTech Connect (OSTI)

    Hiaki, Toshihiko; Takahashi, Kenji; Tsuji, Tomoya; Hongo, Masaru (Nihon Univ., Chiba (Japan). Dept. of Industrial Chemistry); Kojima, Kazuo (Nihon Univ., Tokyo (Japan). Dept. of Industrial Chemistry)

    1994-10-01T23:59:59.000Z

    Vapor-liquid equilibria (VLE) are required for engineering use such as in the design and operation of separation processes. Isobaric vapor-liquid equilibria were measured for ethanol with 2,2,4-trimethylpentane or octane at 101.3 kPa in an equilibrium still with circulation of both the vapor and liquid phases. The results were correlated with the Wilson and nonrandom two-liquid (NRTL) equations.

  2. Modeling intraurban price competition: an example of gasoline pricing

    SciTech Connect (OSTI)

    Haining, R.

    1983-11-01T23:59:59.000Z

    Three interacting market models are considered as models for intraurban retail price variation for a single homogenous good, price-posted gasoline. Modifications include spatial markets instead of interacting economic sectors and supply functions independent of price levels in other markets. The final section discusses the results of fitting one of the models to gasoline data for the city of Sheffield during a period of intensifying price competition in the first quarter of 1982. It is concluded, with respect to gasoline price modeling, both independent and interacting market models exist but at different intraurban scales. 15 references, 1 figure, 1 table.

  3. Gasoline: An adaptable implementation of TreeSPH

    E-Print Network [OSTI]

    Wadsley, J; Quinn, T; Wadsley, James; Stadel, Joachim; Quinn, Thomas

    2003-01-01T23:59:59.000Z

    The key algorithms and features of the Gasoline code for parallel hydrodynamics with self-gravity are described. Gasoline is an extension of the efficient Pkdgrav parallel N-body code using smoothed particle hydrodynamics. Accuracy measurements, performance analysis and tests of the code are presented. Recent successful Gasoline applications are summarized. These cover a diverse set of areas in astrophysics including galaxy clusters, galaxy formation and gas-giant planets. Future directions for gasdynamical simulations in astrophysics and code development strategies for tackling cutting edge problems are discussed.

  4. Gasoline: An adaptable implementation of TreeSPH

    E-Print Network [OSTI]

    James Wadsley; Joachim Stadel; Thomas Quinn

    2003-03-24T23:59:59.000Z

    The key algorithms and features of the Gasoline code for parallel hydrodynamics with self-gravity are described. Gasoline is an extension of the efficient Pkdgrav parallel N-body code using smoothed particle hydrodynamics. Accuracy measurements, performance analysis and tests of the code are presented. Recent successful Gasoline applications are summarized. These cover a diverse set of areas in astrophysics including galaxy clusters, galaxy formation and gas-giant planets. Future directions for gasdynamical simulations in astrophysics and code development strategies for tackling cutting edge problems are discussed.

  5. FT-IR spectroscopy of nitric acid in TBP/octane solution.

    SciTech Connect (OSTI)

    Ferraro, J. R.; Borkowski, M.; Chiarizia, R.; McAlister, D. R.; Chemistry; Loyola Univ. Chicago

    2001-01-01T23:59:59.000Z

    Infrared studies for the HNO{sub 3}/0.73 M TBP n-octane system are reported. Two extracted species, TBP {center_dot} HNO{sub 3} and TBP {center_dot} 2HNO{sub 3}, were identified in the organic phase. The concentration of the individual species was determined by the analysis of the vibrational band at {approx}1650 cm{sup -1}. The band at 1648 cm{sup -1} was assigned to the monosolvate TBP {center_dot} HNO{sub 3} and the band at 1672 cm{sup -1} to the hemisolvate TBP {center_dot} 2HNO{sub 3}. The infrared spectra revealed that with respect to the P{double_bond}O bond, as well to each other, the HNO{sub 3} molecules in the hemisolvate are spectrally non-equivalent. The predominant structure of TBP {center_dot} 2HNO{sub 3} involves the chain HNO{sub 3} dimer. Some ionic NO{sub 3}{sup -} and hydronium ions were identified in this system but only during formation of the monosolvate. The analyses performed in this system can serve for the characterization of HNO{sub 3} in related systems in the presence of metal species.

  6. A Computer Generated Reduced Iso-Octane Chemical Kinetic Mechanism Applied to Simulation of HCCI Combustion

    SciTech Connect (OSTI)

    Aceves, S M; Martinez-Frias, J; Flowers, D; Smith, J R; Dibble, R; Chen, J Y

    2002-08-12T23:59:59.000Z

    This paper shows how a computer can systematically remove non-essential chemical reactions from a large chemical kinetic mechanism. The computer removes the reactions based upon a single solution using a detailed mechanism. The resulting reduced chemical mechanism produces similar numerical predictions significantly faster than predictions that use the detailed mechanism. Specifically, a reduced chemical kinetics mechanism for iso-octane has been derived from a detailed mechanism by eliminating unimportant reaction steps and species. The reduced mechanism has been developed for the specific purpose of fast and accurate prediction of ignition timing in an HCCI engine. The reduced mechanism contains 199 species and 383 reactions, while the detailed mechanism contains 859 species and 3606 reactions. Both mechanisms have been used in numerical simulation of HCCI combustion. The simulations show that the reduced mechanism predicts pressure traces and heat release with good accuracy, similar to the accuracy obtained with the detailed mechanism. As may be expected, emissions of hydrocarbon and carbon monoxide are not as well predicted with the reduced mechanism as with the detailed mechanism, since the reduced mechanism was targeted for predicting HCCI ignition and not HC and CO emissions. Considering that the reduced mechanism requires about 25 times less computational time than the detailed mechanism (2 hours vs. 2 days), the ability to automatically generate a problem specific reduced mechanism is an important new tool for combustion research in general.

  7. Detailed Chemical Kinetic Modeling of Iso-octane SI-HCCI Transition

    SciTech Connect (OSTI)

    Havstad, Mark A [Lawrence Livermore National Laboratory (LLNL); Aceves, Salvador M [Lawrence Livermore National Laboratory (LLNL); McNenly, Matthew J [Lawrence Livermore National Laboratory (LLNL); Piggott, William T [Lawrence Livermore National Laboratory (LLNL); Edwards, Kevin Dean [ORNL; Wagner, Robert M [ORNL; Daw, C Stuart [ORNL; FINNEY, Charles E A [ORNL

    2010-01-01T23:59:59.000Z

    We describe a CHEMKIN-based multi-zone model that simulates the expected combustion variations in a single-cylinder engine fueled with iso-octane as the engine transitions from spark-ignited (SI) combustion to homogenous charge compression ignition (HCCI) combustion. The model includes a 63-species reaction mechanism and mass and energy balances for the cylinder and the exhaust flow. For this study we assumed that the SI-to-HCCI transition is implemented by means of increasing the internal exhaust gas recirculation (EGR) at constant engine speed. This transition scenario is consistent with that implemented in previously reported experimental measurements on an experimental engine equipped with variable valve actuation. We find that the model captures many of the important experimental trends, including stable SI combustion at low EGR (-0.10), a transition to highly unstable combustion at intermediate EGR, and finally stable HCCI combustion at very high EGR (-0.75). Remaining differences between the predicted and experimental instability patterns indicate that there is further room for model improvement.

  8. Lean Gasoline System Development for Fuel Efficient Small Car...

    Broader source: Energy.gov (indexed) [DOE]

    Small Car Lean Gasoline System Development for Fuel Efficient Small Car Vehicle Technologies Office Merit Review 2014: ATP-LD; Cummins Next Generation Tier 2 Bin 2 Diesel Engine...

  9. Table 43. Refiner Motor Gasoline Volumes by Grade, Sales Type...

    Gasoline and Diesel Fuel Update (EIA)

    150.0 2,026.7 W W 234.5 161.7 - 396.3 See footnotes at end of table. 43. Refiner Motor Gasoline Volumes by Grade, Sales Type, PAD District, and State 262 Energy Information...

  10. Table 48. Prime Supplier Sales Volumes of Motor Gasoline by...

    U.S. Energy Information Administration (EIA) Indexed Site

    - - 466.1 466.1 See footnotes at end of table. 48. Prime Supplier Sales Volumes of Motor Gasoline by Grade, Formulation, PAD District, and State 356 Energy Information...

  11. Table 43. Refiner Motor Gasoline Volumes by Grade, Sales Type...

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    253.2 2,222.4 W W 206.4 134.3 - 340.7 See footnotes at end of table. 43. Refiner Motor Gasoline Volumes by Grade, Sales Type, PAD District, and State 262 Energy Information...

  12. Table 48. Prime Supplier Sales Volumes of Motor Gasoline by...

    U.S. Energy Information Administration (EIA) Indexed Site

    - - 532.1 532.1 See footnotes at end of table. 48. Prime Supplier Sales Volumes of Motor Gasoline by Grade, Formulation, PAD District, and State 356 Energy Information...

  13. Determination of methyl tert. butyl ether (MTBE) in gasoline

    SciTech Connect (OSTI)

    Feldman, J.; Orchin, M. (Univ. of Cincinnati, OH (United States))

    1993-02-01T23:59:59.000Z

    A GLC-acid extraction method is described for the determination of MTBE in gasolines. The method consists of a programmed GLC analysis starting at about room temperature conducted before and after extraction with cold 85% phosphoric acid. This treatment results in the preferential solubility of ethers and other oxygenated compounds while minimizing the reaction of olefins and aromatics which may be present in the gasolines. Plotting various known concentrations of MTBE in gasolines against the concentrations determined in the same samples by the authors methodology results in a straight line relationship. The concentration of MTBE in any sample of gasoline may thus be determined using their GLC-extraction procedure and the calibration line. The analysis can accommodate a wide choice of standard GLC columns and programs. 2 refs., 1 fig., 1 tab.

  14. Enabling and Expanding HCCI in PFI Gasoline Engines with High...

    Broader source: Energy.gov (indexed) [DOE]

    Enabling and Expanding HCCI in PFI Gasoline Engines with High EGR and Spark Assist Robert M. Wagner, K. Dean Edwards, C. Stuart Daw, Johney B. Green Jr., Bruce G. Bunting Fuels,...

  15. Process for conversion of lignin to reformulated hydrocarbon gasoline

    DOE Patents [OSTI]

    Shabtai, Joseph S. (Salt Lake City, UT); Zmierczak, Wlodzimierz W. (Salt Lake City, UT); Chornet, Esteban (Golden, CO)

    1999-09-28T23:59:59.000Z

    A process for converting lignin into high-quality reformulated hydrocarbon gasoline compositions in high yields is disclosed. The process is a two-stage, catalytic reaction process that produces a reformulated hydrocarbon gasoline product with a controlled amount of aromatics. In the first stage, a lignin material is subjected to a base-catalyzed depolymerization reaction in the presence of a supercritical alcohol as a reaction medium, to thereby produce a depolymerized lignin product. In the second stage, the depolymerized lignin product is subjected to a sequential two-step hydroprocessing reaction to produce a reformulated hydrocarbon gasoline product. In the first hydroprocessing step, the depolymerized lignin is contacted with a hydrodeoxygenation catalyst to produce a hydrodeoxygenated intermediate product. In the second hydroprocessing step, the hydrodeoxygenated intermediate product is contacted with a hydrocracking/ring hydrogenation catalyst to produce the reformulated hydrocarbon gasoline product which includes various desirable naphthenic and paraffinic compounds.

  16. High compression ratio turbo gasoline engine operation using alcohol enhancement

    E-Print Network [OSTI]

    Lewis, Raymond (Raymond A.)

    2013-01-01T23:59:59.000Z

    Gasoline - ethanol blends were explored as a strategy to mitigate engine knock, a phenomena in spark ignition engine combustion when a portion of the end gas is compressed to the point of spontaneous auto-ignition. This ...

  17. Petroleum Products Table 31. Motor Gasoline Prices by Grade...

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    99.2 - 105.3 See footnotes at end of table. 56 Energy Information AdministrationPetroleum Marketing Annual 2000 Table 31. Motor Gasoline Prices by Grade, Sales Type, PAD...

  18. Petroleum Products Table 31. Motor Gasoline Prices by Grade...

    Gasoline and Diesel Fuel Update (EIA)

    66.6 - 72.3 See footnotes at end of table. 56 Energy Information Administration Petroleum Marketing Annual 1995 Table 31. Motor Gasoline Prices by Grade, Sales Type, PAD...

  19. Petroleum Products Table 43. Refiner Motor Gasoline Volumes...

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    133.6 - 276.4 See footnotes at end of table. 220 Energy Information AdministrationPetroleum Marketing Annual 2000 Table 43. Refiner Motor Gasoline Volumes by Grade, Sales Type,...

  20. Petroleum Products Table 43. Refiner Motor Gasoline Volumes...

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    201.3 - 453.3 See footnotes at end of table. 262 Energy Information Administration Petroleum Marketing Annual 1995 Table 43. Refiner Motor Gasoline Volumes by Grade, Sales Type,...

  1. Gasoline Prices, Fuel Economy, and the Energy Paradox

    E-Print Network [OSTI]

    Wozny, Nathan

    It is often asserted that consumers purchasing automobiles or other goods and services underweight the costs of gasoline or other "add-ons." We test this hypothesis in the US automobile market by examining the effects of ...

  2. Gasoline-like fuel effects on advanced combustion regimes

    Broader source: Energy.gov (indexed) [DOE]

    Gasoline-like fuel effects on advanced combustion regimes Project ID FT008 2011 U.S. DOE Hydrogen and Vehicle Technologies Program Annual Merit Review and Peer Evaluation May...

  3. Demand and Price Volatility: Rational Habits in International Gasoline Demand

    E-Print Network [OSTI]

    Scott, K. Rebecca

    2011-01-01T23:59:59.000Z

    analysis of the demand for oil in the Middle East. EnergyEstimates elasticity of demand for crude oil, not gasoline.World crude oil and natural gas: a demand and supply model.

  4. Demand and Price Uncertainty: Rational Habits in International Gasoline Demand

    E-Print Network [OSTI]

    Scott, K. Rebecca

    2013-01-01T23:59:59.000Z

    analysis of the demand for oil in the Middle East. EnergyEstimates elasticity of demand for crude oil, not gasoline.World crude oil and natural gas: a demand and supply model.

  5. Restructuring: The Changing Face of Motor Gasoline Marketing

    Reports and Publications (EIA)

    2001-01-01T23:59:59.000Z

    This report reviews the U.S. motor gasoline marketing industry during the period 1990 to 1999, focusing on changes that occurred during the period. The report incorporates financial and operating data from the Energy Information Administration's Financial Reporting System (FRS), motor gasoline outlet counts collected by the National Petroleum News from the states, and U.S. Census Bureau salary and employment data published in County Business Patterns.

  6. Gasoline Engine Economy as Affected by the Time of Ignition

    E-Print Network [OSTI]

    Hopkins, George Jay

    1907-01-01T23:59:59.000Z

    KU ScholarWorks | The University of Kansas Pre-1923 Dissertations and Theses Collection Gasoline Engine Economy as Affected by the Time of Ignition 1907 by George Jay Hopkins This work was digitized by the Scholarly Communications program staff... in the KU Libraries’ Center for Digital Scholarship. http://kuscholarworks.ku.edu Submitted to the University of Kansas in partial fulfillment of the requirements for the Degree of Bachelor of Science GASOLINE ENCUNE ECONOMY as Affected W the Time...

  7. Data reconciliation and optimal operation of a catalytic naphtha reformer

    E-Print Network [OSTI]

    Skogestad, Sigurd

    -mail:skoge@chemeng.ntnu.no) #12;Abstract The naphtha reforming process converts low-octane gasoline blending compo- nents to high process converts low-octane gasoline blending compo- nents to high-octane components for use in high-octane components for use in high-performance gasoline fuels. The reformer also has a important function

  8. What Do We Know About Ethanol and Alkylates as Pollutants?

    SciTech Connect (OSTI)

    Rich, D W; Marchetti, A A; Buscheck, T; Layton, D W

    2001-05-11T23:59:59.000Z

    Gov. Davis issued Executive Order D-5-99 in March 1999 calling for removal of methyl tertiary butyl ether (MTBE) from gasoline no later than December 31, 2002. The Executive Order required the California Air Board, State Water Resources Control Board (SWRCB) and Office of Environmental Health Hazard Assessment (OEHHA) to prepare an analysis of potential impacts and health risks that may be associated with the use of ethanol as a fuel oxygenate. The SWRCB contracted with the Lawrence Livermore National Laboratory (LLNL) to lead a team of researchers, including scientists from Clarkson University, University of Iowa, and University of California, Davis, in evaluating the potential ground and surface water impacts that may occur if ethanol is used to replace MTBE. These findings are reported in the document entitled Health and Environmental Assessment of the Use of Ethanol as a Fuel Oxygenate. This document has been peer reviewed and presented to the California Environmental Policy Council and may be viewed at: http://www-erd.llnl.gov/ethanol/. Ethanol used for fuels is made primarily from grains, but any feed stock containing sugar, starch, or cellulose can be fermented to ethanol. Ethanol contains 34.7% oxygen by weight. It is less dense than water, but infinitely soluble in water. Ethanol vapors are denser than air. One and a half gallons of ethanol have the same energy as one gallon of gasoline. Pure fuel ethanol, and gasoline with ethanol, conducts electricity, while gasoline without ethanol is an insulator. Corrosion and compatibility of materials is an issue with the storage of pure ethanol and gasoline with high percentages of ethanol, but these issues are less important if gasoline with less than 10% ethanol is used.

  9. New processes to recovery methanol and remove oxygenates from Valero MTBE unit

    SciTech Connect (OSTI)

    Hillen, P.; Clemmons, J.

    1987-01-01T23:59:59.000Z

    The refiner today has to evaluate every available option to increase octane in the gasoline pool to make up for the loss in octane created by lead phase down. Production of MTBE is one of the most attractive options. MTBE is produced by selectivity reacting isobutylene with methanol. Valero Refining's refinery at Corpus Christie, Texas (formerly Saber Refining) is one of the most modern refineries built in the last decade to upgrade resids. As part of the gasoline upgrading Valero had built a Butamer Unit to convert normal butane to isobutane upstream of their HF Alkylation Unit. In 1984 as an ongoing optimization of its operations, Valero Refining evaluated various processes to enable it to increase the octane output, and decided to build an MTBE unit. Valero selected the MTBE process licensed by Arco Technology, Inc. and contracted with Jacobs Engineering Group, Inc., Houston, Texas to provide detailed engineering and procurement services.

  10. Alkyl phospholipid antihypertensive agents in method of lowering blood pressure

    DOE Patents [OSTI]

    Snyder, Fred L. (Oak Ridge, TN); Blank, Merle L. (Oak Ridge, TN); Muirhead, Ernest E. (Memphis, TN); Leach, deceased, Byron E. (late of Memphis, TN); Byers, Lawrence W. (Memphis, TN)

    1988-01-01T23:59:59.000Z

    The composition of this invention is 1-O-alkyl-2-acetoyl-sn-glycero-3-phosphocholine, having the ionic structural formula; ##STR1## wherein R is saturated alkyl having 9-21 carbon atoms, or salts or hydrates of the composition. Preferably R has 13-19 carbon atoms and most preferably R has 15 carbon atoms. The composition of this invention is useful for reducing hypertension in warm-blooded animals, including humans, when administered either orally or by injection or innoculation, e.g., intravenous injection. The composition can be prepared from naturally occurring lipids or synthetically from commercially available material.

  11. E-Print Network 3.0 - aliphatic alkyl quaternaries Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of this alkylation reaction can also be catalyzed by chiral titanate complexes2-4 (e.g., TAD- DOLs2 and chiral... with various substrates. This alkylation approach provides a...

  12. E-Print Network 3.0 - alkylated aromatics Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of this alkylation reaction can also be catalyzed by chiral titanate complexes2-4 (e.g., TAD- DOLs2 and chiral... with various substrates. This alkylation approach provides a...

  13. Alcohol Chemistry on Rutile TiO2(110): The Influence of Alkyl...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Alcohol Chemistry on Rutile TiO2(110): The Influence of Alkyl Substituents on Reactivity and Selectivity. Alcohol Chemistry on Rutile TiO2(110): The Influence of Alkyl Substituents...

  14. Size-Resolved Particle Number and Volume Emission Factors for On-Road Gasoline and Diesel Motor Vehicles

    E-Print Network [OSTI]

    Ban-Weiss, George A.

    2009-01-01T23:59:59.000Z

    matter from on-road gasoline and diesel vehicles.D.H. , Chase, R.E. , 1999b. Gasoline vehicle particle sizeFactors for On-Road Gasoline and Diesel Motor Vehicles

  15. Vertical Relationships and Competition in Retail Gasoline Markets: An Empirical Evidence from Contract Changes in Southern California

    E-Print Network [OSTI]

    Hastings, Justine

    2000-01-01T23:59:59.000Z

    Margaret E. “Vancouver's Gasoline-Price Wars: An EmpiricalEvidence from Retail Gasoline Markets” Journal of Law,The Case of Retail Gasoline Markets” Journal of Law and

  16. High-resolution NMR process analyzer for oxygenates in gasoline

    SciTech Connect (OSTI)

    Skloss, T.W.; Kim, A.J.; Haw, J.F. (Texas A M Univ., College Station, TX (United States))

    1994-02-15T23:59:59.000Z

    We report a high-resolution 42-MHz[sup 1]HFT-NMR instrument that is suitable for use as a process analyzer and demonstrate its use in the determination of methyl tert-butyl ether (MTBE) in a flowing stream of gasoline. This spectrometer is based on a 55-kg permanent magnet with essentially no fringe field. A spectral resolution of 3 Hz was typically obtained for spinning samples, and this performance was only slightly degraded with flowing samples. We report a procedure for magnet drift compensation using a software procedure rather than a field-frequency lock channel. This procedure allowed signal averaging without loss of resolution. Regulatory changes to be implemented in the near future have created a need for the development of methods for the determination of MTBE and other oxygenates in reformulated gasolines. Existing methods employing gas chromatography are not fast enough for process control of a gasoline blender and suffer from other limitations. This study demonstrates that process analysis NMR is well-suited to the determination of MTBE in a simulated gasoline blender. The detection limit of 0.5 vol % MTBE was obtained with a measurement time of 1 min. The absolute standard deviation of independent determinations was 0.17% when the MTBE concentration was 10%, a nominal value. Preliminary results also suggest that the method may be applicable to gasolines containing mixtures of oxygenate additives as well as the measurement of aromatic and olefinic hydrogens. 33 refs., 9 figs.

  17. Who is Exposed to Gas Prices? How Gasoline Prices Affect Automobile Manufacturers and Dealerships

    E-Print Network [OSTI]

    Rothman, Daniel

    Who is Exposed to Gas Prices? How Gasoline Prices Affect Automobile Manufacturers and Dealerships Prices Affect Automobile Manufacturers and Dealerships Abstract Many consumers are keenly aware, by contrast, we investigate how gasoline prices affect the automobile industry: manufacturers and dealerships

  18. Modeling and Analysis of Natural Gas and Gasoline In A High Compressio...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Analysis of Natural Gas and Gasoline In A High Compression Ratio High Efficiency ICRE Modeling and Analysis of Natural Gas and Gasoline In A High Compression Ratio High...

  19. Fact #584: August 17, 2009 The Price of Gasoline and Vehicle...

    Energy Savers [EERE]

    4: August 17, 2009 The Price of Gasoline and Vehicle Travel: How Do They Relate? Fact 584: August 17, 2009 The Price of Gasoline and Vehicle Travel: How Do They Relate? The price...

  20. Syngas Conversion to Gasoline-Range Hydrocarbons over Pd/ZnO...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Syngas Conversion to Gasoline-Range Hydrocarbons over PdZnOAl2O3 and ZSM-5 Composite Catalyst System. Syngas Conversion to Gasoline-Range Hydrocarbons over PdZnOAl2O3 and ZSM-5...

  1. Evidence of a Shift in the Short-Run Price Elasticity of Gasoline Demand

    E-Print Network [OSTI]

    Hughes, Jonathan; Knittel, Christopher R; Sperling, Dan

    2007-01-01T23:59:59.000Z

    demand shocks. Since gasoline demand and oil price areto gasoline demand shocks. In Venezuela, a strike by oildemand is likely correlated with the prices of other refinery outputs via the price of oil.

  2. New low-mass members of the Octans stellar association and an updated 30-40 Myr lithium age

    E-Print Network [OSTI]

    Murphy, Simon J

    2014-01-01T23:59:59.000Z

    The Octans association is one of several young stellar moving groups recently discovered in the Solar neighbourhood, and hence a valuable laboratory for studies of stellar, circumstellar disc and planetary evolution. However, a lack of low-mass members or any members with trigonometric parallaxes means the age, distance and space motion of the group are poorly constrained. To better determine its membership and age, we present the first spectroscopic survey for new K and M-type Octans members, resulting in the discovery of 29 UV-bright K5-M4 stars with kinematics, photometry and distances consistent with existing members. Nine new members possess strong Li I absorption, which allow us to estimate a lithium age of 30-40 Myr, similar to that of the Tucana-Horologium association and bracketed by the firm lithium depletion boundary ages of the Beta Pictoris (20 Myr) and Argus/IC 2391 (50 Myr) associations. Several stars also show hints in our medium-resolution spectra of fast rotation or spectroscopic binarity. M...

  3. Health studies indicate MTBE is safe gasoline additive

    SciTech Connect (OSTI)

    Anderson, E.V.

    1993-09-01T23:59:59.000Z

    Implementation of the oxygenated fuels program by EPA in 39 metropolitan areas, including Fairbanks and Anchorage, Alaska, in the winter of 1992, encountered some unexpected difficulties. Complaints of headaches, dizziness, nausea, and irritated eyes started in Fairbanks, jumped to Anchorage, and popped up in various locations in the lower 48 states. The suspected culprit behind these complaints was the main additive for oxygenation of gasoline is methyl tert-butyl ether (MTBE). A test program, hastily organized in response to these complaints, has indicated that MTBE is a safe gasoline additive. However, official certification of the safety of MTBE is still awaited.

  4. Puddle Dynamics and Air-to-Fuel Ratio Compensation for Gasoline-Ethanol Blends in

    E-Print Network [OSTI]

    Stefanopoulou, Anna

    1 Puddle Dynamics and Air-to-Fuel Ratio Compensation for Gasoline-Ethanol Blends in Flex flexible fuel vehicles (FFVs) can operate on a blend of gasoline and ethanol in any concentration of up for gasoline-ethanol blends is, thus, necessary for the purpose of air-to-fuel ratio control. In this paper, we

  5. Fuel Puddle Model and AFR Compensator for Gasoline-Ethanol Blends in Flex-Fuel Engines*

    E-Print Network [OSTI]

    Stefanopoulou, Anna

    Fuel Puddle Model and AFR Compensator for Gasoline-Ethanol Blends in Flex-Fuel Engines* Kyung vehicles (FFVs) can operate on a blend of gasoline and ethanol in any concentration of up to 85% ethanol for gasoline-ethanol blends is, thus, necessary for the purpose of air-to-fuel ratio control. In this paper, we

  6. Response to "Ethanol Production and Gasoline Prices: A Spurious Correlation" by Knittel and Smith

    E-Print Network [OSTI]

    Rothman, Daniel

    Response to "Ethanol Production and Gasoline Prices: A Spurious Correlation" by Knittel and Smith Beardshear Hall, (515) 294-7612." #12;1 Response to "Ethanol Production and Gasoline Prices: A Spurious and Aaron Smith attack the paper "The Impact of Ethanol Production on US and Regional Gasoline Markets

  7. Asymmetric and nonlinear pass-through of crude oil prices to gasoline and natural gas prices

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Asymmetric and nonlinear pass-through of crude oil prices to gasoline and natural gas prices Ahmed distributed lags (NARDL) mod- el to examine the pass-through of crude oil prices into gasoline and natural gas the possibility to quantify the respective responses of gasoline and natural gas prices to positive and negative

  8. ATOC/CHEM 5151 Problem 9 Combustion of Gasoline and Conservation of Mass

    E-Print Network [OSTI]

    Toohey, Darin W.

    ATOC/CHEM 5151 ­ Problem 9 Combustion of Gasoline and Conservation of Mass Answers will be posted Thursday, September 18, 2014 Gasoline is composed of a variety of hydrocarbons with 4 to 12 carbon atoms (e for the complete combustion of gasoline: _C8H18 + _O2 _CO2 + _H2O 1. Balance the equation (i.e., find

  9. The Origins of US Transportation Policy: Was There Ever Support for Gasoline Taxes?

    E-Print Network [OSTI]

    Rothman, Daniel

    The Origins of US Transportation Policy: Was There Ever Support for Gasoline Taxes? Christopher R consumption. Missing from these policies were taxes on either oil or gasoline, prompting a long economics press. In doing so, I pay particular attention to whether gasoline taxes were "on the table," as well

  10. Modeling of Air-Fuel Ratio Dynamics of Gasoline Combustion Engine with ARX Network

    E-Print Network [OSTI]

    Johansen, Tor Arne

    DS-06-1351 Modeling of Air-Fuel Ratio Dynamics of Gasoline Combustion Engine with ARX Network Tomás dynamics of gasoline engines during transient operation. With a collection of input-output data measured;Modeling of Air-Fuel Ratio Dynamics of Gasoline Combustion Engine with ARX Network I. INTRODUCTION

  11. CARS, GAS, AND POLLUTION POLICIES Distributional and Efficiency Impacts of Gasoline Taxes

    E-Print Network [OSTI]

    Boyer, Edmond

    CARS, GAS, AND POLLUTION POLICIES Distributional and Efficiency Impacts of Gasoline Taxes, reduc- ing automobile-related gasoline consumption has become a major U.S. public policy issue. Recently, many analysts have called for new or more stringent policies to discourage gasoline consumption

  12. The producer surplus associated with gasoline fuel use in the United States1

    E-Print Network [OSTI]

    Lin, C.-Y. Cynthia

    The producer surplus associated with gasoline fuel use in the United States1 Yongling Sun, Mark A. This paper estimates the producer surplus associated with changes in gasoline fuel use in the United States that affect oil use and oil imports to the US, and (2) comparing the actual average cost of gasoline

  13. Vertical Integration in Gasoline Supply: An Empirical Test of Raising Rivals' Costs

    E-Print Network [OSTI]

    California at Berkeley. University of

    PWP-084 Vertical Integration in Gasoline Supply: An Empirical Test of Raising Rivals' Costs Justine-5180 www.ucei.org #12;Vertical Integration in Gasoline Supply: An Empirical Test of Raising Rivals' Costs gasoline prices. The 1997 acquisition of Unocal's West Coast refining and marketing assets by Tosco

  14. Energy Policy 29 (2001) 11331143 Ethanol as a lead replacement: phasing out leaded gasoline in Africa

    E-Print Network [OSTI]

    Thomas, Valerie

    Energy Policy 29 (2001) 1133­1143 Ethanol as a lead replacement: phasing out leaded gasoline cost of lead additives and of gasoline, and the falling cost of ethanol and sugarcane, have created sugarcane is produced in Africa to replace all the lead used in African gasoline; this would require Africa

  15. Stranded Vehicles: How Gasoline Taxes Change the Value of Households' Vehicle Assets

    E-Print Network [OSTI]

    Rothman, Daniel

    Stranded Vehicles: How Gasoline Taxes Change the Value of Households' Vehicle Assets Meghan Busse pollution caused by the burning of fossil fuels. Argu- ments against energy taxes, and gasoline taxes more incidence of the tax. We study the effect of a gasoline tax using changes in vehicle values. We construct

  16. he increasing frequency of detection of the widely used gasoline additive methyl tert-

    E-Print Network [OSTI]

    T he increasing frequency of detection of the widely used gasoline additive methyl tert- butyl, the September 15, 1999, Report of the Blue Ribbon Panel on Oxygenates in Gasoline (1) states that between 5 with large releases (e.g., LUFTs). Unprecedented growth in use Use of MTBE as a gasoline additive began

  17. Multiscale Strategic Planning Model for the Design of Integrated Ethanol and Gasoline Supply Chain

    E-Print Network [OSTI]

    Grossmann, Ignacio E.

    1 Multiscale Strategic Planning Model for the Design of Integrated Ethanol and Gasoline Supply address the design and planning of an integrated ethanol and gasoline supply chain. We assume, distribution centers where blending takes place, and the retail gas stations where different blends of gasoline

  18. Atmospheric Environment 38 (2004) 14171423 Measurements of ion concentration in gasoline and diesel

    E-Print Network [OSTI]

    Yu, Fangqun

    Atmospheric Environment 38 (2004) 1417­1423 Measurements of ion concentration in gasoline of a gasoline engine (K-car) and a diesel engine (diesel generator). Under the experimental set-up reported all of the ions smaller than 3 nm in the gasoline engine exhaust, and is above 2.7 � 108 cm�3

  19. Carbonyl Emissions from Gasoline and Diesel Motor Vehicles Chris A. Jakober, 2

    E-Print Network [OSTI]

    1 Carbonyl Emissions from Gasoline and Diesel Motor Vehicles 1 Chris A0205CH11231. LBNL752E #12;Carbonyl Emissions from Gasoline and Diesel Motor Vehicles 1Chris A DATE * mjkleeman@ucdavis.edu, (530)-752-8386 ABSTRACT Carbonyls from gasoline powered light

  20. Gasoline accounts for about half the U.S. consumption of petroleum products, and its

    E-Print Network [OSTI]

    2 Gasoline accounts for about half the U.S. consumption of petroleum products, and its price is the most visible among these products. As such, changes in gasoline prices are always under public scrutiny. Many claim to observe an asymmetric relationship between gasoline and oil prices -- specifically

  1. Automakers' Short-Run Responses to Changing Gasoline Prices and the Implications for Energy Policy

    E-Print Network [OSTI]

    Edwards, Paul N.

    Automakers' Short-Run Responses to Changing Gasoline Prices and the Implications for Energy Policy as if consumers respond to gasoline prices. We estimate a selection-corrected regression equation and exploit operating costs between vehicles. Keywords: automobile prices, gasoline prices, environmental policy JEL

  2. The impact of gasoline price changes on traffic safety: a time geography explanation Guangqing Chi a,

    E-Print Network [OSTI]

    Levinson, David M.

    The impact of gasoline price changes on traffic safety: a time geography explanation Guangqing Chi, United States a r t i c l e i n f o Keywords: Time geography Gasoline prices Traffic safety Traffic crashes Fatal crashes Space­time path a b s t r a c t The impact of gasoline price changes on traffic

  3. Gasoline price effects on traffic safety in urban and rural areas: Evidence from Minnesota, 19982007

    E-Print Network [OSTI]

    Levinson, David M.

    Gasoline price effects on traffic safety in urban and rural areas: Evidence from Minnesota, 1998 February 2012 Received in revised form 3 May 2013 Accepted 24 May 2013 Keywords: Gasoline prices Traffic examines the role of gasoline prices in the occurrence of traffic crashes. However, no studies have

  4. forthcoming in Economic Letters Incidence of Federal and State Gasoline Taxes

    E-Print Network [OSTI]

    Perloff, Jeffrey M.

    forthcoming in Economic Letters Incidence of Federal and State Gasoline Taxes Hayley Chouinarda, Berkeley, and member of the Giannini Foundation. Abstract The federal specific gasoline tax falls equally incidence of state taxes is greater in states that use relatively little gasoline. Author Keywords: Taxes

  5. ESTIMATION OF EXHAUST MANIFOLD PRESSURE IN TURBOCHARGED GASOLINE ENGINES WITH VARIABLE VALVE TIMING

    E-Print Network [OSTI]

    Grizzle, Jessy W.

    ESTIMATION OF EXHAUST MANIFOLD PRESSURE IN TURBOCHARGED GASOLINE ENGINES WITH VARIABLE VALVE TIMING in turbocharged gasoline engines with variable valve timing requires knowledge of exhaust mani- fold pressure, Pe control systems for gasoline engines rely heavily on feedforward air-fuel ratio (A/F) control to meet

  6. Study of Brazilian Gasoline Quality Using Hydrogen Nuclear Magnetic Resonance (1H NMR) Spectroscopy and Chemometrics

    E-Print Network [OSTI]

    Ferreira, Márcia M. C.

    Study of Brazilian Gasoline Quality Using Hydrogen Nuclear Magnetic Resonance (1H NMR) Spectroscopy The identification of gasoline adulteration by organic solvents is not an easy task, because compounds that constitute the solvents are already in gasoline composition. In this work, the use of hydrogen nuclear

  7. An independent refiner`s approach to reformulated gasolines

    SciTech Connect (OSTI)

    Czeskleba, H.M. [Ashland Petroleum Co., KY (United States)

    1995-12-31T23:59:59.000Z

    Included in this paper are brief reviews of Ashland Petroleum Company`s renewable oxygenate (ethanol) usage, the latest CAA oxygenate supply and demand forecasts, oxygenated fuel and reformulated blending economics, some very brief comments on the EPA proposed renewable oxygenate standard (ROS), and Ashland`s approach to reformulated gasolines (RFG).

  8. Comparing Scales of Environmental Effects from Gasoline and Ethanol Production

    SciTech Connect (OSTI)

    Parish, Esther S [ORNL; Kline, Keith L [ORNL; Dale, Virginia H [ORNL; Efroymson, Rebecca Ann [ORNL; McBride, Allen [ORNL; Johnson, Timothy L [U.S. Environmental Protection Agency, Raleigh, North Carolina; Hilliard, Michael R [ORNL; Bielicki, Dr Jeffrey M [University of Minnesota

    2013-01-01T23:59:59.000Z

    Understanding the environmental effects of alternative fuel production is critical to characterizing the sustainability of energy resources to inform policy and regulatory decisions. The magnitudes of these environmental effects vary according to the intensity and scale of fuel production along each step of the supply chain. We compare the scales (i.e., spatial extent and temporal duration) of ethanol and gasoline production processes and environmental effects based on a literature review, and then synthesize the scale differences on space-time diagrams. Comprehensive assessment of any fuel-production system is a moving target, and our analysis shows that decisions regarding the selection of spatial and temporal boundaries of analysis have tremendous influences on the comparisons. Effects that strongly differentiate gasoline and ethanol supply chains in terms of scale are associated with when and where energy resources are formed and how they are extracted. Although both gasoline and ethanol production may result in negative environmental effects, this study indicates that ethanol production traced through a supply chain may impact less area and result in more easily reversed effects of a shorter duration than gasoline production.

  9. Table 34. Reformulated Motor Gasoline Prices by Grade, Sales...

    Gasoline and Diesel Fuel Update (EIA)

    61.5 70.8 92.7 90.7 81.5 72.8 - 78.0 See footnotes at end of table. 34. Reformulated Motor Gasoline Prices by Grade, Sales Type, PAD District, and State 146 Energy Information...

  10. Table 34. Reformulated Motor Gasoline Prices by Grade, Sales...

    Gasoline and Diesel Fuel Update (EIA)

    62.6 71.7 92.3 89.9 82.6 72.7 - 78.2 See footnotes at end of table. 34. Reformulated Motor Gasoline Prices by Grade, Sales Type, PAD District, and State 146 Energy Information...

  11. Table 35. Refiner Motor Gasoline Prices by Grade, Sales Type...

    U.S. Energy Information Administration (EIA) Indexed Site

    71.8 W 70.5 78.9 W 76.0 83.6 W 69.2 75.2 See footnotes at end of table. 35. Refiner Motor Gasoline Prices by Grade, Sales Type, PAD District and State 176 Energy Information...

  12. Table 35. Refiner Motor Gasoline Prices by Grade, Sales Type...

    Gasoline and Diesel Fuel Update (EIA)

    W 68.4 70.8 W W 78.6 W 85.7 81.8 W 69.3 73.8 See footnotes at end of table. 35. Refiner Motor Gasoline Prices by Grade, Sales Type, PAD District and State 176 Energy Information...

  13. Evaluating nonmetallic materials` compatibility with MTBE and MTBE + gasoline service

    SciTech Connect (OSTI)

    Hotaling, A.C.

    1995-12-31T23:59:59.000Z

    Methyl-tertiary-butyl-ether (MTBE) has become the leading oxygenate in use in the petroleum industry. Since its introduction several years ago there has been premature deterioration of nonmetallic materials in both neat MTBE and MTBE + gasoline. This degradation is costly in several ways: maintenance, replacement, environmental, and product-loss. Identifying nonmetallic materials compatible with MTBE and MTBE + gasoline is important to the petroleum industry -- all the way from the refinery to the retail sale. Exposure tests have been conducted with different types of nonmetallics in neat MTBE, neat MTBE vapor, and 5% MTBE + 95% gasoline. As in previously reported tests, Teflon{reg_sign} laminates were the top performers, experiencing very little change in any of the properties tested. An ester and ether-based urethane laminate also exhibited only small property changes. Most materials displayed significant deterioration of one or more of the measured properties, even in MTBE condensing vapor and the 5% MTBE + 95% gasoline. The specific effects on each material need to be individually evaluated to determine the effect on service life.

  14. Biomass to Gasoline and DIesel Using Integrated Hydropyrolysis and Hydroconversion

    SciTech Connect (OSTI)

    Marker, Terry; Roberts, Michael; Linck, Martin; Felix, Larry; Ortiz-Toral, Pedro; Wangerow, Jim; Tan, Eric; Gephart, John; Shonnard, David

    2013-01-02T23:59:59.000Z

    Cellulosic and woody biomass can be directly converted to hydrocarbon gasoline and diesel blending components through the use of integrated hydropyrolysis plus hydroconversion (IH2). The IH2 gasoline and diesel blending components are fully compatible with petroleum based gasoline and diesel, contain less than 1% oxygen and have less than 1 total acid number (TAN). The IH2 gasoline is high quality and very close to a drop in fuel. The DOE funding enabled rapid development of the IH2 technology from initial proof-of-principle experiments through continuous testing in a 50 kg/day pilot plant. As part of this project, engineering work on IH2 has also been completed to design a 1 ton/day demonstration unit and a commercial-scale 2000 ton/day IH2 unit. These studies show when using IH2 technology, biomass can be converted directly to transportation quality fuel blending components for the same capital cost required for pyrolysis alone, and a fraction of the cost of pyrolysis plus upgrading of pyrolysis oil. Technoeconomic work for IH2 and lifecycle analysis (LCA) work has also been completed as part of this DOE study and shows IH2 technology can convert biomass to gasoline and diesel blending components for less than $2.00/gallon with greater than 90% reduction in greenhouse gas emissions. As a result of the work completed in this DOE project, a joint development agreement was reached with CRI Catalyst Company to license the IH2 technology. Further larger-scale, continuous testing of IH2 will be required to fully demonstrate the technology, and funding for this is recommended. The IH2 biomass conversion technology would reduce U.S. dependence on foreign oil, reduce the price of transportation fuels, and significantly lower greenhouse gas (GHG) emissions. It is a breakthrough for the widespread conversion of biomass to transportation fuels.

  15. Fact #858 February 2, 2015 Retail Gasoline Prices in 2014 Experienced the Largest Decline since 2008 – Dataset

    Broader source: Energy.gov [DOE]

    Excel file with dataset for Retail Gasoline Prices in 2014 Experienced the Largest Decline since 2008

  16. Effects of fuel octane number and inlet air temperature on knock characteristics of a single cylinder engine

    SciTech Connect (OSTI)

    Haghgooie, M.

    1990-01-01T23:59:59.000Z

    A dual sample rate technique has been developed and applied to measuring in-cylinder pressure and its oscillations due to autoignition. The harmonics of in-cylinder oscillations were found in good agreement with those obtained from the solutions of wave equation in a cylindrical container. The time of knock relative to spark timing was almost independent of the knock intensity, fuel octane number, and inlet air temperature. The knock intensity was almost constant up to the spark advance when about 100% of the cycles were knocking, further spark advance resulted in higher knock intensity. The mass fraction of unburned fuel at the time of knock was about 10% and was independent of the frequency of the cycles knocking. These observations indicated that the phenomenon of knock is a single-site autoignition for intermittent knock and multi-site autoignition for severe knocking.

  17. Techno-economic Analysis for the Conversion of Lignocellulosic Biomass to Gasoline via the Methanol-to-Gasoline (MTG) Process

    SciTech Connect (OSTI)

    Jones, Susanne B.; Zhu, Yunhua

    2009-05-01T23:59:59.000Z

    Biomass is a renewable energy resource that can be converted into liquid fuel suitable for transportation applications. As a widely available biomass form, lignocellulosic biomass can have a major impact on domestic transportation fuel supplies and thus help meet the Energy Independence and Security Act renewable energy goals (U.S. Congress 2007). With gasification technology, biomass can be converted to gasoline via methanol synthesis and methanol-to-gasoline (MTG) technologies. Producing a gasoline product that is infrastructure ready has much potential. Although the MTG technology has been commercially demonstrated with natural gas conversion, combining MTG with biomass gasification has not been shown. Therefore, a techno-economic evaluation for a biomass MTG process based on currently available technology was developed to provide information about benefits and risks of this technology. The economic assumptions used in this report are consistent with previous U.S. Department of Energy Office of Biomass Programs techno-economic assessments. The feedstock is assumed to be wood chips at 2000 metric ton/day (dry basis). Two kinds of gasification technologies were evaluated: an indirectly-heated gasifier and a directly-heated oxygen-blown gasifier. The gasoline selling prices (2008 USD) excluding taxes were estimated to be $3.20/gallon and $3.68/gallon for indirectly-heated gasified and directly-heated. This suggests that a process based on existing technology is economic only when crude prices are above $100/bbl. However, improvements in syngas cleanup combined with consolidated gasoline synthesis can potentially reduce the capital cost. In addition, improved synthesis catalysts and reactor design may allow increased yield.

  18. E-Print Network 3.0 - alkyl radicals Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Collection: Chemistry 2 Radicals and Hydroxy Radical Reactions in Troposphere Summary: : Nitrogen dioxide, 17 valence electrons 7. NO 3 : Nitrate radical 8. R CH 2 1;: alkyl...

  19. E-Print Network 3.0 - alkyl hydroperoxide reductase Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Methyl Esters J. Biet, V. Warth, O. Herbinet* Summary: hydroperoxides methyl esters, acrolein and OH and methyl ester alkyl radicals from unsaturated hydroperoxide... for...

  20. E-Print Network 3.0 - alkylating agent consolidation Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Natural Product Leinamycin Summary: , the antitumor natural product leina- mycin (LM) (1, 2) is converted to a potent DNA-alkylating agent via... the sequence specificity...

  1. E-Print Network 3.0 - alkylating agents synthesis Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Natural Product Leinamycin Summary: , the antitumor natural product leina- mycin (LM) (1, 2) is converted to a potent DNA-alkylating agent via... the sequence specificity...

  2. E-Print Network 3.0 - alkylating agents Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Natural Product Leinamycin Summary: , the antitumor natural product leina- mycin (LM) (1, 2) is converted to a potent DNA-alkylating agent via... the sequence specificity...

  3. E-Print Network 3.0 - alkylating agents evaluacion Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Natural Product Leinamycin Summary: , the antitumor natural product leina- mycin (LM) (1, 2) is converted to a potent DNA-alkylating agent via... the sequence specificity...

  4. Chemical kinetic modeling of component mixtures relevant to gasoline

    SciTech Connect (OSTI)

    Mehl, M; Curran, H J; Pitz, W J; Westbrook, C K

    2009-02-13T23:59:59.000Z

    Real fuels are complex mixtures of thousands of hydrocarbon compounds including linear and branched paraffins, naphthenes, olefins and aromatics. It is generally agreed that their behavior can be effectively reproduced by simpler fuel surrogates containing a limited number of components. In this work, a recently revised version of the kinetic model by the authors is used to analyze the combustion behavior of several components relevant to gasoline surrogate formulation. Particular attention is devoted to linear and branched saturated hydrocarbons (PRF mixtures), olefins (1-hexene) and aromatics (toluene). Model predictions for pure components, binary mixtures and multi-component gasoline surrogates are compared with recent experimental information collected in rapid compression machine, shock tube and jet stirred reactors covering a wide range of conditions pertinent to internal combustion engines. Simulation results are discussed focusing attention on the mixing effects of the fuel components.

  5. Assessment of California reformulated gasoline impact on vehicle fuel economy

    SciTech Connect (OSTI)

    Aceves, S.; Glaser, R.; Richardson, J.

    1997-01-01T23:59:59.000Z

    Fuel economy data contained in the 1996 California Air Resources Board (CAROB) report with respect to the introduction of California Reformulated Gasoline (CaRFG) has been examined and reanalyzed by two additional statistical methodologies. Additional data has also been analyzed by these two statistical approaches. Within the assumptions of the analysis, point estimates for the reduction in fuel economy using CaRFG as compared to conventional, non-reformulated gasoline were 2-4 %, with a 95% upper confidence bound of 6 %. Substantial variations in fuel economy are routine and inevitable due to additional factors which affect mileage, even if there is no change in fuel reformulation. This additional analysis confirms the conclusion reached by CAROB with respect to the impact of CaRFG on fuel economy.

  6. Assessment of California reformulated gasoline impact on vehicle fuel economy

    SciTech Connect (OSTI)

    Aceves, S., LLNL

    1997-01-01T23:59:59.000Z

    Fuel economy data contained in the 1996 California Air Resources Board (CARB) report with respect to the introduction of California Reformulated Gasoline (CaRFG) has been examined and reanalyzed by two additional statistical methodologies. Additional data has also been analyzed by these two statistical approaches. Within the assumptions of the analysis, point estimates for the reduction in fuel economy using CaRFG as compared to conventional, non-reformulated gasoline were 2-4%, with a 95% upper confidence bound of 6%. Substantial variations in fuel economy are routine and inevitable due to additional factors which affect mileage, even if there is no change in fuel reformulation. This additional analysis confirms the conclusion reached by CARB with respect to the impact of CaRFG on fuel economy.

  7. Nickel-catalyzed Suzuki-Miyaura reactions of unactivated halides with alkyl boranes and planar-chiral borabenzene catalysts for Diels-Alder reactions

    E-Print Network [OSTI]

    Lu, Zhe

    2010-01-01T23:59:59.000Z

    Part I describes the expansion in scope of a nickel-catalyzed coupling reaction of unactivated alkyl bromides and alkyl boranes to include unactivated alkyl chlorides. The new method is adapted for use outside of a glove ...

  8. A new blending agent and its effects on methanol-gasoline fuels

    SciTech Connect (OSTI)

    Karaosmanoglu, F.; Isigiguer-Erguedenler, A.; Aksoy, H.A.

    2000-04-01T23:59:59.000Z

    The major difficulty encountered with the use of methanol-gasoline blends as SI engine fuel is their tendency to phase separation due to the hydrophilic properties of methanol. Phase separation can lead to some utilization problems. Using a blending agent for the methanol-gasoline system is the common approach taken towards solving the phase separation problem. In this study introduces fraction of molasses fuel oil as an effective new blending agent for methanol-gasoline fuel.

  9. The Speed of Gasoline Price Response in Markets With and Without Edgeworth Cycles

    E-Print Network [OSTI]

    Lewis, Matt; Noel, Michael

    2009-01-01T23:59:59.000Z

    Columbus, OH. , “Temporary Wholesale Gasoline Price Spikesrespond fairly slowly to wholesale price changes. This doesand asymmetrically to wholesale costs, with cost increases

  10. Table 7. U.S. Refiner Motor Gasoline Volumes by Grade and Sales...

    U.S. Energy Information Administration (EIA) Indexed Site

    Information Administration Petroleum Marketing Annual 1995 Table 7. U.S. Refiner Motor Gasoline Volumes by Grade and Sales Type (Million Gallons per Day) - Continued Year...

  11. Table 31. Motor Gasoline Prices by Grade, Sales Type, PAD District...

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    table. 56 Energy Information AdministrationPetroleum Marketing Annual 1998 Table 31. Motor Gasoline Prices by Grade, Sales Type, PAD District, and State (Cents per Gallon...

  12. Table A1. Refiner/Reseller Motor Gasoline Prices by Grade, PAD...

    U.S. Energy Information Administration (EIA) Indexed Site

    AdministrationPetroleum Marketing Annual 1999 401 Table A1. RefinerReseller Motor Gasoline Prices by Grade, PAD District and State, 1984-Present (Cents per Gallon...

  13. Table A1. Refiner/Reseller Motor Gasoline Prices by Grade, PAD...

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    Information Administration Petroleum Marketing Annual 1995 Table A1. RefinerReseller Motor Gasoline Prices by Grade, PAD District and State, 1984-Present (Cents per Gallon...

  14. Table 31. Motor Gasoline Prices by Grade, Sales Type, PAD District...

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    table. 56 Energy Information AdministrationPetroleum Marketing Annual 1999 Table 31. Motor Gasoline Prices by Grade, Sales Type, PAD District, and State (Cents per Gallon...

  15. Table 6. U.S. Refiner Motor Gasoline Prices by Grade and Sales...

    U.S. Energy Information Administration (EIA) Indexed Site

    Energy Information AdministrationPetroleum Marketing Annual 1999 Table 6. U.S. Refiner Motor Gasoline Prices by Grade and Sales Type (Cents per Gallon Excluding Taxes) - Continued...

  16. Table 31. Motor Gasoline Prices by Grade, Sales Type, PAD District...

    U.S. Energy Information Administration (EIA) Indexed Site

    table. 56 Energy Information Administration Petroleum Marketing Annual 1995 Table 31. Motor Gasoline Prices by Grade, Sales Type, PAD District, and State (Cents per Gallon...

  17. Table 10. U.S. Refiner Oxygenated Motor Gasoline Prices by...

    U.S. Energy Information Administration (EIA) Indexed Site

    AdministrationPetroleum Marketing Annual 1999 Table 10. U.S. Refiner Oxygenated Motor Gasoline Prices by Grade and Sales Type (Cents per Gallon Excluding Taxes) Year Month...

  18. Table 6. U.S. Refiner Motor Gasoline Prices by Grade and Sales...

    U.S. Energy Information Administration (EIA) Indexed Site

    Energy Information AdministrationPetroleum Marketing Annual 1998 Table 6. U.S. Refiner Motor Gasoline Prices by Grade and Sales Type (Cents per Gallon Excluding Taxes) - Continued...

  19. Table 7. U.S. Refiner Motor Gasoline Volumes by Grade and Sales...

    U.S. Energy Information Administration (EIA) Indexed Site

    Energy Information AdministrationPetroleum Marketing Annual 1998 Table 7. U.S. Refiner Motor Gasoline Volumes by Grade and Sales Type (Million Gallons per Day) - Continued Year...

  20. Table 6. U.S. Refiner Motor Gasoline Prices by Grade and Sales...

    U.S. Energy Information Administration (EIA) Indexed Site

    Information Administration Petroleum Marketing Annual 1995 Table 6. U.S. Refiner Motor Gasoline Prices by Grade and Sales Type (Cents per Gallon Excluding Taxes) - Continued...

  1. Vehicle Technologies Office Merit Review 2014: Advanced Gasoline Turbocharged Direct Injection (GTDI) Engine Development

    Broader source: Energy.gov [DOE]

    Presentation given by Ford Motor Companyh at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about advanced gasoline...

  2. Higher prices or gasoline lines loom if Iran-Iraq war lasts into spring

    SciTech Connect (OSTI)

    Madison, C.

    1981-01-17T23:59:59.000Z

    Policies for dealing with the gasoline shortage caused by the Iran-Iraq war are predicted. Options for allocations of existing supplies are discussed. (PSB)

  3. A Detailed Chemical Kinetic Reaction Mechanism for n-Alkane Hydrocarbons From n-Octane to n-Hexadecane

    SciTech Connect (OSTI)

    Westbrook, C K; Pitz, W J; Herbinet, O; Curran, H J; Silke, E J

    2008-02-08T23:59:59.000Z

    Detailed chemical kinetic reaction mechanisms have been developed to describe the pyrolysis and oxidation of nine n-alkanes larger than n-heptane, including n-octane (n-C{sub 8}H{sub 18}), n-nonane (n-C{sub 9}H{sub 20}), n-decane (n-C{sub 10}H{sub 22}), n-undecane (n-C{sub 11}H{sub 24}), n-dodecane (n-C{sub 12}H{sub 26}), n-tridecane (n-C{sub 13}H{sub 28}), n-tetradecane (n-C{sub 14}H{sub 30}), n-pentadecane (n-C{sub 15}H{sub 32}), and n-hexadecane (n-C{sub 16}H{sub 34}). These mechanisms include both high temperature and low temperature reaction pathways. The mechanisms are based on our previous mechanisms for the primary reference fuels n-heptane and iso-octane, using the reaction class mechanism construction first developed for n-heptane. Individual reaction class rules are as simple as possible in order to focus on the parallelism between all of the n-alkane fuels included in the mechanisms, and these mechanisms will be refined further in the future to incorporate greater levels of accuracy and predictive capability. These mechanisms are validated through extensive comparisons between computed and experimental data from a wide variety of different sources. In addition, numerical experiments are carried out to examine features of n-alkane combustion in which the detailed mechanisms can be used to compare reactivities of different n-alkane fuels. The mechanisms for all of these n-alkanes are presented as a single detailed mechanism, which can be edited to produce efficient mechanisms for any of the n-alkanes included, and the entire mechanism, with supporting thermochemical and transport data, together with an explanatory glossary explaining notations and structural details, will be available for download from our web page.

  4. Data reconciliation and optimal operation of a catalytic naphtha reformer

    E-Print Network [OSTI]

    Skogestad, Sigurd

    -mail:skoge@chemeng.ntnu.no) #12;Abstract The naphtha reforming process converts low-octane gasoline blending compo- nents to high cases. #12;1 Introduction The naphtha reforming process converts low-octane gasoline blending compo-octane components for use in high-performance gasoline fuels. The reformer also has an important function

  5. This article was published in an Elsevier journal. The attached copy is furnished to the author for non-commercial research and

    E-Print Network [OSTI]

    Skogestad, Sigurd

    reforming process converts low-octane gasoline blending components to high-octane components for use in high. Introduction The naphtha reforming process converts low-octane gasoline blending components to high-per- formance gasoline fuels. The reformer also has an important function as the producer of hydrogen

  6. Assembly of carbon nanotubes and alkylated fullerenes: nanocarbon hybrid towards photovoltaic applications

    E-Print Network [OSTI]

    Nabben, Reinhard

    Assembly of carbon nanotubes and alkylated fullerenes: nanocarbon hybrid towards photovoltaic and a fullerene (C60) derivative with long alkyl chains was constructed as a donor­acceptor pair for photovoltaics as attractive candidates for the development of light- energy harvesting and photovoltaic materials because

  7. for the alkylation reaction. We (23) and others (24) observed similar carbon isotope effects in

    E-Print Network [OSTI]

    Jacob, Daniel J.

    - ination proceeds to yield the alkylation product and a cationic Ru-hydroxo complex 23. Notably, Ru for the regeneration of the Ru-alkenyl species 22. Extensive hydrogen- deuterium exchange between indene and 2 the catalytic conditions. Our catalytic alkylation method exhibits a broad substrate scope, as well as a high

  8. Highly ecient kinetic resolution of 2-cyclohexenyl acetate in Pd-catalyzed allylic alkylation

    E-Print Network [OSTI]

    Zhang, Xumu

    Highly ecient kinetic resolution of 2-cyclohexenyl acetate in Pd-catalyzed allylic alkylation James resolution of 2-cyclohexenyl acetate was observed during alkylation. In addition, the reactivity and enantioselectivity showed a strong dependence on the acetate salt with the BSA/MOAc (M=alkali metal) base system

  9. A Practical and Highly Stereoselective Umpolung Alternative to the Alkylation of Chiral Enolates

    E-Print Network [OSTI]

    Spino, Claude

    , acetates, carbonates, and epoxides.9,10 Thus, in principle, the displacement reaction of a chiral allyl reactive electrophiles such as methyl, ethyl, and some primary alkyl iodides and benzyl or allyl halides. s-silyl ketene acetals, and s-alkyl electrophiles are poor electrophiles with this method.7,8 In this paper, we

  10. High octane ethers from synthesis gas-derived alcohols. Quarterly technical progress report, April--June 1992

    SciTech Connect (OSTI)

    Klier, K.; Herman, R.G.; Feeley, O.C.; Johansson, M.A.

    1992-07-01T23:59:59.000Z

    The objective of the proposed research is to synthesize high octane ethers, primarily methyl isobutyl ether (MIBE) and methyl tertiary butyl ether (MTBE), directly from H{sub 2}/CO/CO{sub 2} coal-derived synthesis gas via alcohol mixtures that are rich in methanol and 2-methyl-l-propanol (isobutanol). The overall scheme involves gasification of coal, purification and shifting of the synthesis gas, higher alcohol synthesis, and direct synthesis of ethers. The last stage of the synthesis involves direct coupling of synthesis gas-derived methanol and isobutanol that has been demonstrated by us to occur over superacid catalysts to yield methyl isobutyl ether (MIBE) at moderate pressures and a mixture of methanol and isobutene at low pressures. MIBE is an isomer of MTBE and a process is proposed whereby MTBE from the two alcohols is maximized and MIBE is minimized. This will be achieved by the proper choice of reaction conditions, i.e. intermediate pressures, and of inorganic acid catalysts that are stable at temperatures higher than 200{degree}C, at which the carbonium ion reaction coupling of the two alcohols to MTBE is more effective than the oxonium ion or ester reaction coupling to MIBE. Both organic and inorganic catalysts will be investigated, and the better catalysts of these classes will be subjected to long term performance studies. The long term performance studies of the combined process will extend to 1000 hr and detailed analytical data for all products will be provided.

  11. U.S. Gasoline Price Continues to Increase (Short version)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered energy consumption by sector Transportation EnergyGlossary API gravity:Gasoline

  12. U.S. gasoline price continues to increase (short version)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered energy consumption by sector Transportationdiesel fueldieselU.S.3, 2015 U.S.gasoline

  13. U.S. gasoline price continues to increase (short version)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered energy consumption by sector Transportationdiesel fueldieselU.S.3, 2015gasoline

  14. U.S. gasoline prices decreased (long version)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered energy consumption by sectorlong version) The U.S. averagelong, 2013 U.S. gasoline

  15. U.S. gasoline prices show little movement (long version)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered energy consumption by sectorlong version) The U.S.1, 2014 U.S. gasoline prices

  16. U.S. gasoline prices show little movement (long version)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered energy consumption by sectorlong version) The U.S.1, 2014 U.S. gasoline pricesAugust

  17. U.S. gasoline prices unchanged (short version)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered energy consumption by sectorlong version) The U.S.1, 2014 U.S. gasoline

  18. U.S. gasoline prices unchanged (short version)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered energy consumption by sectorlong version) The U.S.1, 2014 U.S.gasoline prices

  19. Developing an accelerated aging system for gasoline particulate filters and an evaluation test for effects on engine performance

    E-Print Network [OSTI]

    Jorgensen, James E. (James Eastman)

    2014-01-01T23:59:59.000Z

    Stringent regulations worldwide will limit the level of particulate matter (PM) emitted from gasoline engines equipped with direct fuel injection. Gasoline particulate filters (GPFs) present one strategy for meeting PM ...

  20. Supplement for "Secondary organic aerosol1 formation from idling gasoline passenger vehicle2

    E-Print Network [OSTI]

    Meskhidze, Nicholas

    Supplement for "Secondary organic aerosol1 formation from idling gasoline passenger vehicle2.O. Box 503, FIN-00101 Helsinki, Finland}14 [5]{Department of Chemistry, Atmospheric Science, University experiment show a total concentration of light aromatics of less than 1 ppb.6 Vehicles7 In total six gasoline

  1. Indirect conversion of coal to methanol and gasoline: product price vs product slate

    SciTech Connect (OSTI)

    Wham, R.M.; McCracken, D.J.; Forrester, R.C. III

    1980-01-01T23:59:59.000Z

    The Oak Ridge National Laboratory (ORNL) conducts process analysis and engineering evaluation studies for the Department of Energy to provide, on a consistent basis, technical and economic assessments of processes and systems for coal conversion and utilization. Such assessments permit better understanding of the relative technical and economic potential of these processes. The objective of the work described here was to provide an assessment of the technical feasibility, economic competitiveness, and environmental acceptability of selected indirect coal liquefaction processes on a uniform, consistent, and impartial basis. Particular emphasis is placed on production of methanol as a principal product or methanol production for conversion to gasoline. Potential uses for the methanol are combustion in peaking-type turbines or blending with gasoline to yield motor fuel. Conversion of methanol to gasoline is accomplished through the use of the Mobil methanol-to-gasoline (MTG) process. Under the guidance of ORNL, Fluor Engineers and Constructors, Houston Division, prepared four conceptual process designs for indirect conversion of a Western subbituminous coal to either methanol or gasoline. The conceptual designs are based on the use of consistent technology for the core of the plant (gasification through methanol synthesis) with additional processing as necessary for production of different liquid products of interest. The bases for the conceptual designs are given. The case designations are: methanol production for turbine-grade fuel; methanol production for gasoline blending; gasoline production with coproduction of SNG; and gasoline production maximized.

  2. Fact #834: August 18, 2014 About Two-Thirds of Transportation Energy Use is Gasoline for Light Vehicles – Dataset

    Broader source: Energy.gov [DOE]

    Excel file with dataset for Fact #834: About Two-Thirds of Transportation Energy Use is Gasoline for Light Vehicles

  3. Quantitative in-cylinder NO-LIF imaging in a realistic gasoline engine with spray-guided direct injection

    E-Print Network [OSTI]

    Lee, Tonghun

    Quantitative in-cylinder NO-LIF imaging in a realistic gasoline engine with spray-guided direct of engines with gasoline direct injection. Exhaust gas aftertreatment requires storage catalysts fractions in a gasoline engine with spray-guided direct injection using laser-induced fluorescence (LIF

  4. Math 115 Excel Group Project 3 Worksheet Price Elasticity of Demand: U.S. Demand for Gasoline

    E-Print Network [OSTI]

    Newberger, Florence

    Math 115 Excel Group Project 3 Worksheet Price Elasticity of Demand: U.S. Demand for Gasoline 1 for Gasoline 2 4. Consider the two price-demand graphs below. The labels give the x-value. Which graph for Gasoline 3 6. Jewelry This quote is from the article "Americans Snap Up Gold Jewelry as Metal's Price Sinks

  5. Farm Fuel Safety Accidents in the handling, use and storage of gasoline, gasohol, diesel fuel, LP-gas and

    E-Print Network [OSTI]

    112 Farm Fuel Safety Accidents in the handling, use and storage of gasoline, gasohol, diesel fuel and by keeping fuel storage facilities in top condition. Flammable Liquids and Gases Gasoline, diesel fuel, LP flammability and safety precautions. Do not keep gasoline inside the home or transport it in the trunks

  6. Practical Observers for Unmeasured States in Turbocharged Gasoline Julia H. Buckland, Jim Freudenberg, J. W. Grizzle and Mrdjan Jankovic

    E-Print Network [OSTI]

    Grizzle, Jessy W.

    Practical Observers for Unmeasured States in Turbocharged Gasoline Engines Julia H. Buckland, Jim Freudenberg, J. W. Grizzle and Mrdjan Jankovic Abstract--Turbocharged gasoline engines are becoming more with a significant reduction in calibration complexity. I. INTRODUCTION Turbocharged gasoline engines are becoming

  7. Combustion Phasing Model for Control of a Gasoline-Ethanol Fueled SI Engine with Variable Valve Timing

    E-Print Network [OSTI]

    Combustion Phasing Model for Control of a Gasoline-Ethanol Fueled SI Engine with Variable Valve engine efficiency. Fuel-flexible engines permit the increased use of ethanol-gasoline blends. Ethanol points across the engine operating range for four blends of gasoline and ethanol. I. INTRODUCTION Fuel

  8. The Reaction Engineering of Green Gasoline Prof. de Lasa's CREC group at the University of Western Ontario has been

    E-Print Network [OSTI]

    Sinnamon, Gordon J.

    The Reaction Engineering of Green Gasoline Prof. de Lasa's CREC group at the University of Western Ontario has been leading efforts to establish the reaction engineering of "green gasoline". The main goal in gasoline. Benzene is a well- known cancerogenic and has to be minimized or avoided if at all possible

  9. alkyl tert-butyl ether: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    by Fusarium solani CiteSeer Summary: Fusarium solani degraded methyl tert-butyl ether (MTBE) and other oxygenated compounds from gasoline including tert-butyl alcohol (TBA). The...

  10. E-Print Network 3.0 - alkylations added insight Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Natural Product Leinamycin Summary: . In a typical alkylation reaction, a solution of LM (2 L of a 0.5 mM solution in acetonitrile) was added... to achieve efficient reaction....

  11. Intramolecular Heck couplings of unactivated alkyl electrophiles : synthetic and mechanistic studies

    E-Print Network [OSTI]

    Firmansjah, Luke

    2007-01-01T23:59:59.000Z

    A method for the palladium-catalyzed intramolecular Heck coupling of unactivated alkyl bromides and chlorides is described. The optimal catalyst system was composed of Pd2(MeO-dba)3 as the metal source and N-heterocyclic ...

  12. Palladium-catalyzed allylic alkylation via decarboxylative and retro-Claisen C-C cleavage methods

    E-Print Network [OSTI]

    Grenning, Alexander James

    2012-05-31T23:59:59.000Z

    Presented herein is the development of new methods for Pd-catalyzed allylic alkylation with a central focus on reactions that generate molecular complexity rapidly with little waste byproduct. With this simply stated, yet ...

  13. A Mild, Palladium-Catalyzed Method for the Dehydrohalogenation of Alkyl Bromides: Synthetic and Mechanistic Studies

    E-Print Network [OSTI]

    Bissember, Alex C.

    We have exploited a typically undesired elementary step in cross-coupling reactions, ?-hydride elimination, to accomplish palladium-catalyzed dehydrohalogenations of alkyl bromides to form terminal olefins. We have applied ...

  14. E-Print Network 3.0 - asymmetric intramolecular alkylation Sample...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of this alkylation reaction can also be catalyzed by chiral titanate complexes2-4 (e.g., TAD- DOLs2 and chiral... ,2-bis(3,5-dichloro-2-hydroxyben- zenesulfonamido)cyclohexane) for...

  15. Gasoline Ultra Efficient Fuel Vehicle with Advanced Low Temperature Combustion

    SciTech Connect (OSTI)

    Confer, Keith

    2014-09-30T23:59:59.000Z

    The objective of this program was to develop, implement and demonstrate fuel consumption reduction technologies which are focused on reduction of friction and parasitic losses and on the improvement of thermal efficiency from in-cylinder combustion. The program was executed in two phases. The conclusion of each phase was marked by an on-vehicle technology demonstration. Phase I concentrated on short term goals to achieve technologies to reduce friction and parasitic losses. The duration of Phase I was approximately two years and the target fuel economy improvement over the baseline was 20% for the Phase I demonstration. Phase II was focused on the development and demonstration of a breakthrough low temperature combustion process called Gasoline Direct- Injection Compression Ignition (GDCI). The duration of Phase II was approximately four years and the targeted fuel economy improvement was 35% over the baseline for the Phase II demonstration vehicle. The targeted tailpipe emissions for this demonstration were Tier 2 Bin 2 emissions standards.

  16. Gasoline Biodesulfurization DE-FC07-97ID13570 FINAL REPORT

    SciTech Connect (OSTI)

    Pienkos, Philip T.

    2002-01-15T23:59:59.000Z

    Nine strains were identified to grow with gasoline as sole sulfur source. Two different genes were cloned from Gordonia terrae KGB1 and tested for the ability to support gasoline BDS. The first of these, fmoA, was cloned by screening a KGB1 gene library for the ability to convert indole to indigo (a sulfur-regulated capability in KGB1). The fmoA gene was overexpressed in a gasoline tolerant strain of Pseudomonas putida PpG1 and the recombinant strain was shown to convert thiophene to a dimer of thiophene sulfoxide at rates nearly two orders of magnitude higher than KGB1 could catalyze the reaction. Despite this high activity the recombinant PpG1 was unable to demonstrate any activity against gasoline either in shake flask or in bench-scale gasoline BDS bioreactor. A second gene (toeA) was cloned from KGB1 and shown to support growth of Rhodococcus erythropolis JB55 on gasoline. The toeA gene was also identified in another gasoline strain T. wratislaviensis EMT4, and was identified as a homolog of dszA from R. erythropolis IGTS8. Expression of this gene in JB55 supported conversion of DBTO2 (the natural substrate for DszA) to HPBS, but activity against gasoline was low and BDS results were inconsistent. It appeared that activity was directed against C2- and C3-thiophenes. Efforts to increase gene expression by plasmid manipulation, by addition of flavin reductase genes, or by expression in PpG1 were unsuccessful. The DszC protein (DBT monooxygenase) from IGTS8 has very little activity against the sulfur compounds in gasoline, but a mutant enzyme with a substitution of phenylalanine for valine at position 261 was shown to have an altered substrate range. This alteration resulted in increased activity against gasoline, with activity towards mainly C3- and C4-thiophenes and benzothiophene. A mutant library of dszB was constructed by RACHITT (W. C. Coco et al., DNA shuffling method for generating highly recombined genes and evolved enzymes. 2001. Nature Biotech. 19:354-359) method of in vitro recombination. Methods for analysis were developed and a preliminary analysis of the library was performed. A preliminary gasoline process design was constructed and process economics were determined based upon assumptions made from experimental results. The projected cost of gasoline BDS was determined to be competitive with current competing technologies.

  17. Areas Participating in the Oxygenated Gasoline Program (Released in the STEO July 1999)

    Reports and Publications (EIA)

    1999-01-01T23:59:59.000Z

    Section 211(m) of the Clean Air Act (42 U.S.C. 7401-7671q) requires that gasoline containing at least 2.7% oxygen by weight is to be used in the wintertime in those areas of the county that exceed the carbon monoxide National Ambient Air Quality Standards (NAAQS). The winter oxygenated gasoline program applies to all gasoline sold in the larger of the Consolidated Metropolitan Statistical Area (CMSA) or Metropolitan Statistical Area (MSA) in which the nonattainment area is located.

  18. Electrophilic Metal Alkyl Chemistry in New Ligand Environments

    SciTech Connect (OSTI)

    Jordan, Richard F. [University of Chicago] University of Chicago

    2013-06-30T23:59:59.000Z

    The goals of this project were to design new electrophilic metal alkyl complexes and to exploit these systems in fundamental studies of olefin polymerization and other important and new catalytic reactions. A key target reaction is insertion copolymerization of olefins and polar CH2=CHX vinyl monomers such as vinyl halides and vinyl ethers. During the period covered by this report we (i) investigated the properties of ortho-alkoxy-arylphosphine ligands in Ni-based olefin polymerization catalysts, (ii) studied the synthesis of double-end-capped polyethylene using group 4 metal catalysts that contain tris-pyrazolylborate ligands, (iii) explored the ethylene insertion reactivity of group 4 metal tris-pyrazolyl-borate complexes, (iv) showed that (?-diimine)PdMe{sup +} species undergo multiple insertion of silyl vinyl ethers, (v) synthesized and explored the reactivity of base-free Ni benzyl complexes that contain ortho-phosphino-arene sulfonate ligands, (vi) established the mechanism of the reaction of vinyl chloride with (?-diimine)PdMe{sup +} catalysts, (vii) explored the role of cationic polymerization and insertion chemistry in the reactions of vinyl ethers with (?-diimine)PdMe{sup +} species, (viii) discovered a new class of self-assembled tetranuclear Pd catalysts that produce high molecular weight linear polyethylene and copolymerize ethylene and vinyl fluoride, and (ix) developed model systems that enabled investigation of cis-trans isomerization of {phosphine-sulfonate}Pd(II) complexes.

  19. A Detailed Chemical Kinetic Reaction Mechanism for n-Alkane Hydrocarbons from n-Octane to n-Hexadecane

    SciTech Connect (OSTI)

    Westbrook, C K; Pitz, W J; Herbinet, O; Silke, E J; Curran, H J

    2007-09-25T23:59:59.000Z

    Detailed chemical kinetic reaction mechanisms have been developed to describe the pyrolysis and oxidation of the n-alkanes, including n-octane (n-C{sub 8}H{sub 18}), n-nonane (n-C{sub 9}H{sub 20}), n-decane (n-C{sub 10}H{sub 22}), n-undecane (n-C{sub 11}H{sub 24}), n-dodecane (n-C{sub 12}H{sub 26}), n-tridecane (n-C{sub 13}H{sub 28}), n-tetradecane (n-C{sub 14}H{sub 30}), n-pentadecane (n-C{sub 15}H{sub 32}), and n-hexadecane (n-C{sub 16}H{sub 34}). These mechanisms include both high temperature and low temperature reaction pathways. The mechanisms are based on previous mechanisms for n-heptane, using the same reaction class mechanism construction developed initially for n-heptane. Individual reaction class rules are as simple as possible in order to focus on the parallelism between all of the n-alkane fuels included in the mechanisms, and there is an intent to develop these mechanisms further in the future to incorporate greater levels of accuracy and predictive capability. Several of these areas for improvement are identified and explained in detail. These mechanisms are validated through comparisons between computed and experimental data from as many different sources as possible. In addition, numerical experiments are carried out to examine features of n-alkane combustion in which the detailed mechanisms can be used to compare processes in all of the n-alkane fuels. The mechanisms for all of these n-alkanes are presented as a single detailed mechanism, which can be edited to produce efficient mechanisms for any of the n-alkanes included, and the entire mechanism, with supporting thermochemical and transport data, together with an explanatory glossary explaining notations and structural details, will be available on our web page when the paper is accepted for publication.

  20. Beyond a Billion: Clean Cities Coaliations Have Displaced More Than a Billion Gallons of Gasoline

    SciTech Connect (OSTI)

    Not Available

    2005-10-01T23:59:59.000Z

    In 2004, DOE's Clean Cities achieved a milestone - displacing the equivalent of more than 1 billion gallons of gasoline since 1994. This fact sheet describes how Clean Cities achieved this goal.

  1. Table 9. U.S. Refiner Conventional Motor Gasoline Volumes by...

    U.S. Energy Information Administration (EIA) Indexed Site

    5.7 5.9 4.4 12.9 NA 17.3 See footnotes at end of table. 9. U.S. Refiner Conventional Motor Gasoline Volumes by Grade and Sales Type 18 Energy Information Administration ...

  2. Table 10. U.S. Refiner Oxygenated Motor Gasoline Prices by...

    U.S. Energy Information Administration (EIA) Indexed Site

    98.0 98.0 86.6 75.0 - 80.1 See footnotes at end of table. 10. U.S. Refiner Oxygenated Motor Gasoline Prices by Grade and Sales Type 20 Energy Information Administration ...

  3. Table 13. U.S. Refiner Reformulated Motor Gasoline Volumes by...

    U.S. Energy Information Administration (EIA) Indexed Site

    3.3 3.4 7.9 3.3 W 11.3 See footnotes at end of table. 13. U.S. Refiner Reformulated Motor Gasoline Volumes by Grade and Sales Type 26 Energy Information Administration ...

  4. Table 12. U.S. Refiner Reformulated Motor Gasoline Prices by...

    U.S. Energy Information Administration (EIA) Indexed Site

    92.4 92.1 83.7 74.1 W 80.9 See footnotes at end of table. 12. U.S. Refiner Reformulated Motor Gasoline Prices by Grade and Sales Type 24 Energy Information Administration ...

  5. Table 8. U.S. Refiner Conventional Motor Gasoline Prices by...

    U.S. Energy Information Administration (EIA) Indexed Site

    87.4 86.9 78.3 68.5 W 70.8 See footnotes at end of table. 8. U.S. Refiner Conventional Motor Gasoline Prices by Grade and Sales Type 16 Energy Information Administration ...

  6. Table 12. U.S. Refiner Reformulated Motor Gasoline Prices by...

    U.S. Energy Information Administration (EIA) Indexed Site

    92.8 92.5 84.0 72.5 W 80.7 See footnotes at end of table. 12. U.S. Refiner Reformulated Motor Gasoline Prices by Grade and Sales Type 24 Energy Information Administration ...

  7. Table 8. U.S. Refiner Conventional Motor Gasoline Prices by...

    U.S. Energy Information Administration (EIA) Indexed Site

    88.4 87.8 80.1 70.0 NA 72.6 See footnotes at end of table. 8. U.S. Refiner Conventional Motor Gasoline Prices by Grade and Sales Type 16 Energy Information Administration ...

  8. Table 10. U.S. Refiner Oxygenated Motor Gasoline Prices by...

    U.S. Energy Information Administration (EIA) Indexed Site

    94.0 93.9 83.2 73.8 - 79.3 See footnotes at end of table. 10. U.S. Refiner Oxygenated Motor Gasoline Prices by Grade and Sales Type 20 Energy Information Administration ...

  9. Table 13. U.S. Refiner Reformulated Motor Gasoline Volumes by...

    U.S. Energy Information Administration (EIA) Indexed Site

    3.6 3.7 7.9 3.1 W 11.0 See footnotes at end of table. 13. U.S. Refiner Reformulated Motor Gasoline Volumes by Grade and Sales Type 26 Energy Information Administration ...

  10. Table 9. U.S. Refiner Conventional Motor Gasoline Volumes by...

    U.S. Energy Information Administration (EIA) Indexed Site

    5.7 5.9 3.9 12.7 W 16.6 See footnotes at end of table. 9. U.S. Refiner Conventional Motor Gasoline Volumes by Grade and Sales Type 18 Energy Information Administration ...

  11. Market behavior under partial price controls: the case of the retail gasoline market

    SciTech Connect (OSTI)

    Camm, F.

    1983-03-01T23:59:59.000Z

    The use of firm-specific controls on the price of gasoline during 1979 and 1980, at both the wholesale and the retail level, dramatically affected the retail market for gasoline. The most visible effect was a diversity of monetary prices across service stations within particular retail market areas. Price could no longer play its usual role in clearing the retail market for gasoline. Queues and other changes in quality of service at stations arose to maintain the balance of market demand and supply. This report examines the behavior of an otherwise competitive market in the presence of such regulation-induced nonprice phenomena. In such a market, consumers consider both monetary prices and costs imposed by queues in deciding where to buy gasoline and how much to buy. Using a price-theoretic model of behavior, this paper predicts how various changes in effective price regulation affect consumers. 14 references, 7 figures, 2 tables.

  12. Knock limits in spark ignited direct injected engines using gasoline/ethanol blends

    E-Print Network [OSTI]

    Kasseris, Emmanuel P

    2011-01-01T23:59:59.000Z

    Direct Fuel Injection (DI) extends engine knock limits compared to Port Fuel Injection (PFI) by utilizing the in-cylinder charge cooling effect due to fuel evaporation. The use of gasoline/ethanol blends in DI is therefore ...

  13. Vehicle Technologies Office Merit Review 2014: Gasoline-Like Fuel Effects on Advanced Combustion Regimes

    Broader source: Energy.gov [DOE]

    Presentation given by Oak Ridge National Laboratory at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about gasoline-like...

  14. Long Beach Transit: Two-Year Evaluation of Gasoline-Electric Hybrid Transit Buses

    SciTech Connect (OSTI)

    Lammert, M.

    2008-06-01T23:59:59.000Z

    This report focuses on a gasoline-electric hybrid transit bus propulsion system. The propulsion system is an alternative to standard diesel buses and allows for reductions in emissions (usually focused on reductions of particulate matter and oxides of nitrogen) and petroleum use. Gasoline propulsion is an alternative to diesel fuel and hybrid propulsion allows for increased fuel economy, which ultimately results in reduced petroleum use.

  15. Lean Gasoline System Development for Fuel Efficient Small Cars

    SciTech Connect (OSTI)

    None

    2013-08-30T23:59:59.000Z

    The General Motors and DOE cooperative agreement program DE-EE0003379 is completed. The program has integrated and demonstrated a lean-stratified gasoline engine, a lean aftertreatment system, a 12V Stop/Start system and an Active Thermal Management system along with the necessary controls that significantly improves fuel efficiency for small cars. The fuel economy objective of an increase of 25% over a 2010 Chevrolet Malibu and the emission objective of EPA T2B2 compliance have been accomplished. A brief review of the program, summarized from the narrative is: The program accelerates development and synergistic integration of four cost competitive technologies to improve fuel economy of a light-duty vehicle by at least 25% while meeting Tier 2 Bin 2 emissions standards. These technologies can be broadly implemented across the U.S. light-duty vehicle product line between 2015 and 2025 and are compatible with future and renewable biofuels. The technologies in this program are: lean combustion, innovative passive selective catalyst reduction lean aftertreatment, 12V stop/start and active thermal management. The technologies will be calibrated in a 2010 Chevrolet Malibu mid-size sedan for final fuel economy demonstration.

  16. Gasoline from coal in the state of Illinois: feasibility study. Volume I. Design. [KBW gasification process, ICI low-pressure methanol process and Mobil M-gasoline process

    SciTech Connect (OSTI)

    Not Available

    1980-01-01T23:59:59.000Z

    Volume 1 describes the proposed plant: KBW gasification process, ICI low-pressure methanol process and Mobil M-gasoline process, and also with ancillary processes, such as oxygen plant, shift process, RECTISOL purification process, sulfur recovery equipment and pollution control equipment. Numerous engineering diagrams are included. (LTN)

  17. Size-Resolved Particle Number and Volume Emission Factors for On-Road Gasoline and Diesel Motor Vehicles

    E-Print Network [OSTI]

    Ban-Weiss, George A.

    2009-01-01T23:59:59.000Z

    losses when sampling diesel aerosol: A quality assurancefrom on-road gasoline and diesel vehicles. AtmosphericSource apportionment of diesel and spark ignition exhaust

  18. Simulating the daily gasoline price-setting behaviour of gas stations in Cincinnati by agent-based modeling.

    E-Print Network [OSTI]

    Zhou, Li

    2009-01-01T23:59:59.000Z

    ??In the retail gasoline market, gas stations as independent entities set gas prices according to a number of factors related to global and local economic… (more)

  19. Effect of Polyethylene Glycol, Alkyl, and Oligonucleotide Spacers on the Binding, Secondary Structure, and Self-Assembly of Fractalkine

    E-Print Network [OSTI]

    Kokkoli, Efie

    Effect of Polyethylene Glycol, Alkyl, and Oligonucleotide Spacers on the Binding, Secondary-amphiphiles with no spacer (NoSPR), polyethylene glycol (PEG4, PEG8, PEG24), alkyl (C12 and C24), or oligonucleotide (T10 a polyethylene glycol (PEG) or an oligo-T (thymine) spacer is added to the aptamer, especially when attaching

  20. COMBUSTION AND FLAME 24, 27-34 (1975) 27 Flame Emission Studies of Ozone with Metal Alkyls

    E-Print Network [OSTI]

    Zare, Richard N.

    COMBUSTION AND FLAME 24, 27-34 (1975) 27 Flame Emission Studies of Ozone with Metal Alkyls: Zn (CH3 of combustion. Premixed [2, 3] anddiffusion [4] flames of metal alkyl compounds have been carried out to deter- tageous to study the combustion of polyatomic molecules under single-collision conditions, i

  1. Vapor-liquid equilibria of binary and ternary mixtures of cyclohexane, 3-methyl-2-butanone, and octane at 101.3 kPa

    SciTech Connect (OSTI)

    Chen, C.C.; Tang, M.; Chen, Y.P. [National Taiwan Univ., Taipei (Taiwan, Province of China). Dept. of Chemical Engineering] [National Taiwan Univ., Taipei (Taiwan, Province of China). Dept. of Chemical Engineering

    1996-05-01T23:59:59.000Z

    Vapor-liquid equilibria were measured at 101.3 kPa for the three binary and one ternary mixtures of cyclohexane, 3-methyl-2-butanone, and octane. The isobaric T-x-y data were reported, including an azeotropic point for the binary mixture cyclohexane + 3-methyl-2-butanone. The virial equation of state truncated after the second coefficient was used to calculate the vapor-phase fugacity coefficients. The Tsonopoulos correlation equation was applied to determine the second virial coefficients. Various activity coefficient models of the Wilson, the NRTL, and the UNIQUAC equations were used to correlate the binary experimental vapor-liquid equilibrium results. Optimally-fitted binary parameters of the activity coefficient models were obtained and those parameters of the NRTL model were employed to predict the ternary vapor-liquid equilibria. Satisfactory results were presented for the correlation and prediction of the vapor-liquid equilibrium data on binary and ternary mixtures.

  2. Life Cycle Assessment of Gasoline and Diesel Produced via Fast Pyrolysis and Hydroprocessing

    SciTech Connect (OSTI)

    Hsu, D. D.

    2011-03-01T23:59:59.000Z

    In this work, a life cycle assessment (LCA) estimating greenhouse gas (GHG) emissions and net energy value (NEV) of the production of gasoline and diesel from forest residues via fast pyrolysis and hydroprocessing, from production of the feedstock to end use of the fuel in a vehicle, is performed. The fast pyrolysis and hydrotreating and hydrocracking processes are based on a Pacific Northwest National Laboratory (PNNL) design report. The LCA results show GHG emissions of 0.142 kg CO2-equiv. per km traveled and NEV of 1.00 MJ per km traveled for a process using grid electricity. Monte Carlo uncertainty analysis shows a range of results, with all values better than those of conventional gasoline in 2005. Results for GHG emissions and NEV of gasoline and diesel from pyrolysis are also reported on a per MJ fuel basis for comparison with ethanol produced via gasification. Although pyrolysis-derived gasoline and diesel have lower GHG emissions and higher NEV than conventional gasoline does in 2005, they underperform ethanol produced via gasification from the same feedstock. GHG emissions for pyrolysis could be lowered further if electricity and hydrogen are produced from biomass instead of from fossil sources.

  3. Alkylation of Phenol: A Mechanistic View Qisheng Ma, Deb Chakraborty, Francesco Faglioni, Rick P. Muller, and

    E-Print Network [OSTI]

    Goddard III, William A.

    imparts improved perfor- mance properties to the class of metallic detergents used in lubricating oils as additives in gasoline, lubricants, and as hosts of consumer products. For instance, the p-alkylphenol isomer industries as drilling oil additives, antioxidants, and polymer stabilizers.1 Both homogeneous

  4. Gas/particle partitioning of total alkyl nitrates observed with TD-LIF in Bakersfield

    E-Print Network [OSTI]

    Cohen, Ronald C.

    total AN (gas + aerosol) and ANaer show that on average 21% of ANs are in the condensed phaseGas/particle partitioning of total alkyl nitrates observed with TD-LIF in Bakersfield A. W. Rollins samples. These measurements show that ANs are a ubiquitous component of the OA with the ­ONO2 subunit

  5. Electronic desorption of alkyl monolayers from silicon by very highly charged ions

    E-Print Network [OSTI]

    -assembled alkyl monolayers SAM on Si 111 .13 AFM images of SAMs after exposure to Xe41 and Au63 show craters ions, like Xe41 and Th73 . Atomic force microscope images show craters from single ion impacts be used to modify surfaces at very low impact energies. Impact energies are limited by the image charge

  6. Serendipitous alkylation of a Plk1 ligand uncovers a new binding channel

    E-Print Network [OSTI]

    Lim, Dan

    We obtained unanticipated synthetic byproducts from alkylation of the ?[superscript 1] nitrogen (N3) of the histidine imidazole ring of the polo-like kinase-1 (Plk1) polo-box domain (PBD)-binding peptide PLHSpT. For the ...

  7. Oligonucleoside alkyl or arylphosphonate derivatives capable of crosslinking with or cleaving nucleic acids

    DOE Patents [OSTI]

    Miller, P.S.; Ts'o, P.O.P.

    1999-06-15T23:59:59.000Z

    A composition for inactivating a target nucleic acid which comprises an oligonucleoside alkyl or arylphosphonate analogue which is complementary to the sequence of the target nucleic acid is provided. It includes a functional group which reacts with the target nucleic acid to render the target nucleic acid inactive or nonfunctional. 16 figs.

  8. Molecular simulation study of nanoscale friction for alkyl monolayers on Si,,111...

    E-Print Network [OSTI]

    Zhang, Luzheng

    . To calculate friction in MD simulations, two Si 111 surfaces coated with the alkyl monolayers were slid against is critical to the design of coatings for microelectromechanical systems. © 2002 American Institute of Physics, such as membranes, gears, motors, pumps and valves.1­3 The integration of miniaturized mechanical components

  9. Oligonucleoside alkyl or arylphosphonate derivatives capable of crosslinking with or cleaving nucleic acids

    DOE Patents [OSTI]

    Miller, Paul S. (Baltimore, MD); Ts'o, Paul O.P. (Lutherville, MD)

    1999-06-15T23:59:59.000Z

    A composition for inactivating a target nucleic acid which comprises an oligonucleoside alkyl or arylphosphonate analogue which is complementary to the sequence of the target nucleic acid and includes a functional group which reacts with the target nucleic acid to render the target nucleic acid inactive or nonfunctional.

  10. Method of upgrading oils containing hydroxyaromatic hydrocarbon compounds to highly aromatic gasoline

    DOE Patents [OSTI]

    Baker, E.G.; Elliott, D.C.

    1993-01-19T23:59:59.000Z

    The present invention is a multi-stepped method of converting an oil which is produced by various biomass and coal conversion processes and contains primarily single and multiple ring hydroxyaromatic hydrocarbon compounds to highly aromatic gasoline. The single and multiple ring hydroxyaromatic hydrocarbon compounds in a raw oil material are first deoxygenated to produce a deoxygenated oil material containing single and multiple ring aromatic compounds. Then, water is removed from the deoxygenated oil material. The next step is distillation to remove the single ring aromatic compounds as gasoline. In the third step, the multiple ring aromatics remaining in the deoxygenated oil material are cracked in the presence of hydrogen to produce a cracked oil material containing single ring aromatic compounds. Finally, the cracked oil material is then distilled to remove the single ring aromatics as gasoline.

  11. Reformulated Gasoline Foreign Refinery Rules (Released in the STEO January 1998)

    Reports and Publications (EIA)

    1998-01-01T23:59:59.000Z

    On August 27, 1997, the Environmental Protection Agency (EPA) promulgated revised the rules that allow foreign refiners to establish and use individual baselines, but it would not be mandatory (the optional use of an individual refinery baseline is not available to domestic refiners.) If a foreign refiner did not establish and use an individual baseline, the gasoline they export to the United States would be regulated through the importer, and subject to the importer's baseline (most likely the statutory baseline). Specific regulatory provisions are implemented to ensure that the option to use an individual baseline would not lead to adverse environmental impacts. This involves monitoring the average quality of imported gasoline, and if a specified benchmark is exceeded, remedial action would be taken by adjusting the requirements applicable to imported gasoline.

  12. Method of upgrading oils containing hydroxyaromatic hydrocarbon compounds to highly aromatic gasoline

    DOE Patents [OSTI]

    Baker, Eddie G. (Richland, WA); Elliott, Douglas C. (Richland, WA)

    1993-01-01T23:59:59.000Z

    The present invention is a multi-stepped method of converting an oil which is produced by various biomass and coal conversion processes and contains primarily single and multiple ring hydroxyaromatic hydrocarbon compounds to highly aromatic gasoline. The single and multiple ring hydroxyaromatic hydrocarbon compounds in a raw oil material are first deoxygenated to produce a deoxygenated oil material containing single and multiple ring aromatic compounds. Then, water is removed from the deoxygenated oil material. The next step is distillation to remove the single ring aromatic compouns as gasoline. In the third step, the multiple ring aromatics remaining in the deoxygenated oil material are cracked in the presence of hydrogen to produce a cracked oil material containing single ring aromatic compounds. Finally, the cracked oil material is then distilled to remove the single ring aromatics as gasoline.

  13. Estimate the fraction of the total transported energy (in the form of gasoline) in the Trans-Alaska Pipeline that is consumed in pumping.

    E-Print Network [OSTI]

    Nimmo, Francis

    Estimate the fraction of the total transported energy (in the form of gasoline) in the Trans m). So we can toss this out. Now estimate the energy content of gasoline: Many of you tried figuring

  14. Hybrid combustion-premixed gasoline homogeneous charge ignited by injected diesel fuel-4-stroke cycle engines

    SciTech Connect (OSTI)

    Yonetani, H.; Okanishi, N.; Fukutani, I.; Watanabe, E.

    1989-01-01T23:59:59.000Z

    This paper describes the formation and testing of two hybrid combustion engines, wherein a premixed gasoline homogeneous charge was ignited by a small amount of injected diesel fuel under high compression ratio, by modifying open chamber and prechamber 4-stroke cycle diesel engines. It was found that the premixed gasoline was effective not only for decreasing the fuel consumption but also for reducing the smoke density both in the heavy and over-load regions. The effect of introducing a small amount N/sub 2/ gas for suppressing the diesel knock in the heavy load region also was examined.

  15. Increasing Gas Prices: Good Economics, but Bad Public Relations Rising gasoline prices captured the attention of the press and politicians in recent months,

    E-Print Network [OSTI]

    Ahmad, Sajjad

    Increasing Gas Prices: Good Economics, but Bad Public Relations Rising gasoline prices captured interest during our current gasoline shortage. That is, a higher price rations the product to the best use the supply of gasoline become relatively scarcer? First, the growth of the Chinese and Indian economies

  16. Supporting Information1 Condensational Uptake of Semivolatile Organic Compounds in Gasoline3

    E-Print Network [OSTI]

    Meskhidze, Nicholas

    Supporting Information1 2 Condensational Uptake of Semivolatile Organic Compounds in Gasoline31A 0H3 Canada (now at Department of Chemistry,13 University of Christchurch, Canterbury 8041, New Zealand)14 15 For submission to Atmospheric Chemistry and Physics16 17 Revised Version: May 31, 201118 19

  17. Proper Oil Sampling Intervals and Sample Collection Techniques Gasoline/Diesel/Natural Gas Engines

    E-Print Network [OSTI]

    Proper Oil Sampling Intervals and Sample Collection Techniques Gasoline/Diesel/Natural Gas Engines: · Oil samples can be collected during oil changes. Follow manufacturers recommendations on frequency (hours, mileage, etc) of oil changes. · Capture a sample from the draining oil while the oil is still hot

  18. Climate change and health costs of air emissions from biofuels and gasoline

    E-Print Network [OSTI]

    Weiblen, George D

    Climate change and health costs of air emissions from biofuels and gasoline Jason Hilla,b,1 on the source of land used to produce biomass for biofuels, on the magnitude of any indirect land use that may result, and on other as yet unmeasured environmental impacts of biofuels. fine particulate matter ethanol

  19. In Oklahoma and other parts of the Midwest, gasoline prices have been

    E-Print Network [OSTI]

    Balasundaram, Balabhaskar "Baski"

    's biomass for biofuels can improve profitability for farmers, enhance local economies, attract capital for the production of drop-in biofuels including propanol, butanol and hexanol. These higher alcohols can be converted with chemical catalysts to produce renewable gasoline, diesel and jet fuels. "We are advancing

  20. Introduction The use of ethanol as a gasoline additive is likely to

    E-Print Network [OSTI]

    Alvarez, Pedro J.

    Introduction The use of ethanol as a gasoline additive is likely to increase in the near future will also lead to additional ethanol use. There- fore, it is important to understand how ethanol affects that the presence of ethanol could have undesirable effects on the biodegradation of BTEX (i.e., benzene, toluene

  1. Using Gasoline, Diesel, and Compressed Natural Gas (CNG) Vehicles, Characterize the Significance of Lube

    E-Print Network [OSTI]

    Using Gasoline, Diesel, and Compressed Natural Gas (CNG) Vehicles, Characterize the Significance from natural gas vehicles will help in the development of PM mitigation technologies. This in turn emissions beyond applicable standards, and that benefit natural gas ratepayers (Public Resources Code 25620

  2. Table 7. U.S. Refiner Motor Gasoline Volumes by Grade and Sales...

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    35.2 213.6 9.5 9.8 12.9 16.6 NA 29.5 See footnotes at end of table. 7. U.S. Refiner Motor Gasoline Volumes by Grade and Sales Type 14 Energy Information Administration ...

  3. Table A1. Refiner/Reseller Motor Gasoline Prices by Grade, PAD...

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    71.6 92.3 78.2 101.8 83.6 87.5 74.7 See footnotes at end of table. A1. RefinerReseller Motor Gasoline Prices by Grade, PAD District, and State, 1984-Present 452 Energy Information...

  4. Table 6. U.S. Refiner Motor Gasoline Prices by Grade and Sales...

    U.S. Energy Information Administration (EIA) Indexed Site

    62.2 68.5 90.1 89.6 82.4 70.9 NA 75.9 See footnotes at end of table. 6. U.S. Refiner Motor Gasoline Prices by Grade and Sales Type 12 Energy Information Administration ...

  5. Table 11. U.S. Refiner Oxygenated Motor Gasoline Volumes by...

    U.S. Energy Information Administration (EIA) Indexed Site

    - 4.9 0.4 0.4 0.3 0.4 - 0.7 See footnotes at end of table. 11. U.S. Refiner Oxygenated Motor Gasoline Volumes by Grade and Sales Type 22 Energy Information Administration ...

  6. Table 6. U.S. Refiner Motor Gasoline Prices by Grade and Sales...

    U.S. Energy Information Administration (EIA) Indexed Site

    61.5 67.3 89.8 89.5 82.2 69.4 71.1 74.9 See footnotes at end of table. 6. U.S. Refiner Motor Gasoline Prices by Grade and Sales Type 12 Energy Information Administration ...

  7. Table 31. Motor Gasoline Prices by Grade, Sales Type, PAD District...

    Gasoline and Diesel Fuel Update (EIA)

    82.4 77.1 68.9 62.6 71.6 92.3 89.9 82.6 72.7 - 78.2 See footnotes at end of table. 31. Motor Gasoline Prices by Grade, Sales Type, PAD District, and State 56 Energy Information...

  8. Table 31. Motor Gasoline Prices by Grade, Sales Type, PAD District...

    Gasoline and Diesel Fuel Update (EIA)

    82.5 75.1 68.6 62.0 70.7 92.7 90.7 81.5 72.8 - 78.0 See footnotes at end of table. 31. Motor Gasoline Prices by Grade, Sales Type, PAD District, and State 56 Energy Information...

  9. Table 7. U.S. Refiner Motor Gasoline Volumes by Grade and Sales...

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    33.9 215.8 9.7 10.0 12.1 16.3 0.0 28.4 See footnotes at end of table. 7. U.S. Refiner Motor Gasoline Volumes by Grade and Sales Type 14 Energy Information Administration ...

  10. Table 11. U.S. Refiner Oxygenated Motor Gasoline Volumes by...

    U.S. Energy Information Administration (EIA) Indexed Site

    W 5.6 0.5 0.5 0.5 0.4 - 0.9 See footnotes at end of table. 11. U.S. Refiner Oxygenated Motor Gasoline Volumes by Grade and Sales Type 22 Energy Information Administration ...

  11. CLEARING THE AIR? THE EFFECTS OF GASOLINE CONTENT REGULATION ON AIR QUALITY

    E-Print Network [OSTI]

    Edwards, Paul N.

    )--are pollutants produced in part through human activity. Ozone control programs have targeted a wide array of VOCCLEARING THE AIR? THE EFFECTS OF GASOLINE CONTENT REGULATION ON AIR QUALITY Maximilian Auffhammer regulations on ground- level ozone pollution. These regulations are costly and have been shown to fragment

  12. Effect of Intake Air Filter Condition on Light-Duty Gasoline Vehicles

    SciTech Connect (OSTI)

    Thomas, John F [ORNL] [ORNL; Huff, Shean P [ORNL] [ORNL; West, Brian H [ORNL] [ORNL; Norman, Kevin M [ORNL] [ORNL

    2012-01-01T23:59:59.000Z

    Proper maintenance can help vehicles perform as designed, positively affecting fuel economy, emissions, and the overall drivability. This effort investigates the effect of one maintenance factor, intake air filter replacement, with primary focus on vehicle fuel economy, but also examining emissions and performance. Older studies, dealing with carbureted gasoline vehicles, have indicated that replacing a clogged or dirty air filter can improve vehicle fuel economy and conversely that a dirty air filter can be significantly detrimental to fuel economy. The effect of clogged air filters on the fuel economy, acceleration and emissions of five gasoline fueled vehicles is examined. Four of these were modern vehicles, featuring closed-loop control and ranging in model year from 2003 to 2007. Three vehicles were powered by naturally aspirated, port fuel injection (PFI) engines of differing size and cylinder configuration: an inline 4, a V6 and a V8. A turbocharged inline 4-cylinder gasoline direct injection (GDI) engine powered vehicle was the fourth modern gasoline vehicle tested. A vintage 1972 vehicle equipped with a carburetor (open-loop control) was also examined. Results reveal insignificant fuel economy and emissions sensitivity of modern vehicles to air filter condition, but measureable effects on the 1972 vehicle. All vehicles experienced a measured acceleration performance penalty with clogged intake air filters.

  13. FedEx Express Gasoline Hybrid Electric Delivery Truck Evaluation: 12-Month Report

    SciTech Connect (OSTI)

    Barnitt, R.

    2011-01-01T23:59:59.000Z

    This report summarizes the data obtained in a 12-month comparison of three gasoline hybrid electric delivery vehicles with three comparable diesel vehicles. The data show that there was no statistical difference between operating cost per mile of the two groups of vehicles. As expected, tailpipe emissions were considerably lower across all drive cycles for the gHEV than for the diesel vehicle.

  14. Societyof Petroleum Engineers Cleaning Up Spilled Gasoline With Steam: Compo~itional Simulations

    E-Print Network [OSTI]

    Patzek, Tadeusz W.

    Societyof Petroleum Engineers SPE 25257 Cleaning Up Spilled Gasoline With Steam: Compo Copyright 1993, Society of Petroleum Engineers, Inc. This paper was prepared for presentation at the 121h reviewed by the Society of Petroleum Engineers and are sUbject to correctlo~ by the author(s). The

  15. Spin Crossover in a Series of Iron(II) Complexes of 2-(2-Alkyl-2H-tetrazol-5-yl)-1,10-phenanthroline: Effects of Alkyl Side

    E-Print Network [OSTI]

    Gao, Song

    Spin Crossover in a Series of Iron(II) Complexes of 2-(2-Alkyl-2H-tetrazol-5-yl)-1Versity, Beijing 100871, China Received October 27, 2006 2-(2H-Tetrazol-5-yl)-1,10-phenanthroline (HL0 ), its alkyl) at the 2H position of the tetrazole ring, and their iron(II) complexes (a for [Fe(L0 )2], na for [Fe(Ln)2

  16. Selective catalytic reduction of nitric oxide with ethanol/gasoline blends over a silver/alumina catalyst

    SciTech Connect (OSTI)

    Pihl, Josh A [ORNL] [ORNL; Toops, Todd J [ORNL] [ORNL; Fisher, Galen [University of Michigan] [University of Michigan; West, Brian H [ORNL] [ORNL

    2014-01-01T23:59:59.000Z

    Lean gasoline engines running on ethanol/gasoline blends and equipped with a silver/alumina catalyst for selective catalytic reduction (SCR) of NO by ethanol provide a pathway to reduced petroleum consumption through both increased biofuel utilization and improved engine efficiency relative to the current stoichiometric gasoline engines that dominate the U.S. light duty vehicle fleet. A pre-commercial silver/alumina catalyst demonstrated high NOx conversions over a moderate temperature window with both neat ethanol and ethanol/gasoline blends containing at least 50% ethanol. Selectivity to NH3 increases with HC dosing and ethanol content in gasoline blends, but appears to saturate at around 45%. NO2 and acetaldehyde behave like intermediates in the ethanol SCR of NO. NH3 SCR of NOx does not appear to play a major role in the ethanol SCR reaction mechanism. Ethanol is responsible for the low temperature SCR activity observed with the ethanol/gasoline blends. The gasoline HCs do not deactivate the catalyst ethanol SCR activity, but they also do not appear to be significantly activated by the presence of ethanol.

  17. Remediation of a fractured clay soil contaminated with gasoline containing MTBE

    SciTech Connect (OSTI)

    Johnson, R.L.; Grady, D.E. [Oregon Graduate Institute, Portland, OR (United States); Walden, T. [BP Oil Europe, Brussels (Belgium)

    1997-12-31T23:59:59.000Z

    Gasoline and other light non-aqueous phase liquids (LNAPLs) released into fractured clay soils initially move by advection of the LNAPL through the fractures. Once advective movement of the LNAPL ceases, dissolution of the gasoline components into the pore water and diffusion into the intact blocks of clay becomes an important transport process. The aqueous-phase flux of each compound in the mixture depends in large part upon its aqueous solubility. For example, a low-solubility compound like isooctane remains primarily in the fracture in the LNAPL. A high-solubility compound, like methyl-tert-butyl ether (MTBE), dissolves readily and may move almost entirely into the clay matrix. The distribution of compounds between the matrix and the fractures will have an important impact on the rate at which the gasoline contaminated soil can be remediated. In this context, the presence of soluble additives like MTBE can significantly impact the risk and remediation time for the, soil. Beginning in 1993 a field study to examine the applicability of air flushing for remediation of low-permeability soils was sponsored by API. The study focused on a variety of soil vapor extraction (SVE) and in situ air sparging (IAS) approaches for mass removal and risk reduction. The source of gasoline contamination in this study was a release of 50 liters of a mixture containing 14 gasoline hydrocarbons ranging from pentane to naphthalene, and including MTBE. The mixture was released into the shallow subsurface and allowed to redistribute for 10 months prior to air flushing startup. Numerical modeling indicated that essentially all of the MTBE should have dissolved into the matrix. In contrast, essentially all of the isooctane should have remained in the LNAPL in the fractures.

  18. Solid catalyzed isoparaffin alkylation at supercritical fluid and near-supercritical fluid conditions

    DOE Patents [OSTI]

    Ginosar, Daniel M. (Idaho Falls, ID); Fox, Robert V. (Idaho Falls, ID); Kong, Peter C. (Idaho Falls, ID)

    2000-01-01T23:59:59.000Z

    This invention relates to an improved method for the alkylation reaction of isoparaffins with olefins over solid catalysts including contacting a mixture of an isoparaffin, an olefin and a phase-modifying material with a solid acid catalyst member under alkylation conversion conditions at either supercritical fluid, or near-supercritical fluid conditions, at a temperature and a pressure relative to the critical temperature(T.sub.c) and the critical pressure(P.sub.c) of the reaction mixture. The phase-modifying phase-modifying material is employed to promote the reaction's achievement of either a supercritical fluid state or a near-supercritical state while simultaneously allowing for decreased reaction temperature and longer catalyst life.

  19. Alkylation of mixed olefins with isobutane in a stratco chemical reactor

    SciTech Connect (OSTI)

    Vichailak, M. [ABB Lummus Global Inc., Houston, TX (United States); Hopper, J.R.; Yaws, C.L. [Lamar Univ., Beaumont, TX (United States); Pike, R.W. [Louisiana State Univ., Baton Rouge, LA (United States)

    1996-12-31T23:59:59.000Z

    The 17 reaction model for the sulfuric acid alkylation of isobutane with propylene as proposed by Langley and Pike has been used to simulate the effluent refrigeration reactor. The simulation conditions selected to minimize the formation of light and heavy by-product were determined to be: Temperature: 9 - 10 {degrees}C,- Isobutane/Olefin Ratio: 8 - 10; % Volume of Acid: 50 %. The reactor effluent composition from the simulation program has been used to compare with several sets of published data with reasonable agreement. This model has been extrapolated to simulate the alkylation of isobutane with butylenes and amylenes. The model will be optimized with commercial data. 9 refs., 6 figs., 1 tab.

  20. HCCI in a Variable Compression Ratio Engine: Effects of Engine...

    Broader source: Energy.gov (indexed) [DOE]

    Fuels Practical Full Time HCCI Operation Will Require Specific HCCI Fuel Low Octane gasoline Experimental Variables Experimental Variables Engine Variables Intake Manifold...

  1. Sunco Oil manufactures three types of gasoline (gas 1, gas 2 and gas 3). Each type is produced by blending three types of crude oil (crude 1, crude 2 and crude 3). The sales price per barrel of gasoline and the purchase price per

    E-Print Network [OSTI]

    Phillips, David

    Sunco Oil manufactures three types of gasoline (gas 1, gas 2 and gas 3). Each type is produced by blending three types of crude oil (crude 1, crude 2 and crude 3). The sales price per barrel of gasoline and the purchase price per barrel of crude oil are given in following table: Gasoline Sale Price per barrel Gas 1

  2. Organic gas emissions from a stoichiometric direct injection spark ignition engine operating on ethanol/gasoline blends

    E-Print Network [OSTI]

    Kar, Kenneth

    The organic gas emissions from a stoichiometric direct injection spark ignition engine operating on ethanol/gasoline blends have been assessed under warmed-up and cold idle conditions. The speciated emissions show that the ...

  3. The role of content regulation on pricing and market power in regional retail and wholesale gasoline markets

    E-Print Network [OSTI]

    Muehlegger, Erich J.

    2002-01-01T23:59:59.000Z

    Since 1999, regional retail and wholesale gasoline markets in the United States have experienced significant price volatility, both intertemporally and across geographic markets. This paper focuses on one potential explanation ...

  4. Speciated Engine-Out Organic Gas Emissions from a PFI-SI Engine Operating on Ethanol/Gasoline Mixtures

    E-Print Network [OSTI]

    Kar, Kenneth

    Engine-out HC emissions from a PFI spark ignition engine were measured using a gas chromatograph and a flame ionization detector (FID). Two port fuel injectors were used respectively for ethanol and gasoline so that the ...

  5. Particulate Matter Emissions from a Direct Injection Spark Ignition Engine under Cold Fast Idle Conditions for Ethanol-Gasoline Blends

    E-Print Network [OSTI]

    Dimou, Iason

    The engine out particular matter number (PN) distributions at engine coolant temperature (ECT) of 0° C to 40° C for ethanol/ gasoline blends (E0 to E85) have been measured for a direct-injection spark ignition engine under ...

  6. Experimental and Modeling Study of the Flammability of Fuel Tank Headspace Vapors from Ethanol/Gasoline Fuels; Phase 3: Effects of Winter Gasoline Volatility and Ethanol Content on Blend Flammability; Flammability Limits of Denatured Ethanol

    SciTech Connect (OSTI)

    Gardiner, D. P.; Bardon, M. F.; Clark, W.

    2011-07-01T23:59:59.000Z

    This study assessed differences in headspace flammability for summertime gasolines and new high-ethanol content fuel blends. The results apply to vehicle fuel tanks and underground storage tanks. Ambient temperature and fuel formulation effects on headspace vapor flammability of ethanol/gasoline blends were evaluated. Depending on the degree of tank filling, fuel type, and ambient temperature, fuel vapors in a tank can be flammable or non-flammable. Pure gasoline vapors in tanks generally are too rich to be flammable unless ambient temperatures are extremely low. High percentages of ethanol blended with gasoline can be less volatile than pure gasoline and can produce flammable headspace vapors at common ambient temperatures. The study supports refinements of fuel ethanol volatility specifications and shows potential consequences of using noncompliant fuels. E85 is flammable at low temperatures; denatured ethanol is flammable at warmer temperatures. If both are stored at the same location, one or both of the tanks' headspace vapors will be flammable over a wide range of ambient temperatures. This is relevant to allowing consumers to splash -blend ethanol and gasoline at fueling stations. Fuels compliant with ASTM volatility specifications are relatively safe, but the E85 samples tested indicate that some ethanol fuels may produce flammable vapors.

  7. Effect of alkyl glycerophosphate on the activation of peroxisome proliferator-activated receptor gamma and glucose uptake in C2C12 cells

    SciTech Connect (OSTI)

    Tsukahara, Tamotsu, E-mail: ttamotsu@shinshu-u.ac.jp [Department of Integrative Physiology and Bio-System Control, Shinshu University School of Medicine, 3-1-1 Asahi, Matsumoto, Nagano 390-8621 (Japan)] [Department of Integrative Physiology and Bio-System Control, Shinshu University School of Medicine, 3-1-1 Asahi, Matsumoto, Nagano 390-8621 (Japan); Haniu, Hisao [Department of Orthopedic Surgery, Shinshu University School of Medicine, 3-1-1 Asahi, Matsumoto, Nagano 390-8621 (Japan)] [Department of Orthopedic Surgery, Shinshu University School of Medicine, 3-1-1 Asahi, Matsumoto, Nagano 390-8621 (Japan); Matsuda, Yoshikazu [Clinical Pharmacology Educational Center, Nihon Pharmaceutical University, Ina-machi, Saitama 362-0806 (Japan)] [Clinical Pharmacology Educational Center, Nihon Pharmaceutical University, Ina-machi, Saitama 362-0806 (Japan)

    2013-04-12T23:59:59.000Z

    Highlights: •Alkyl-LPA specifically interacts with PPAR?. •Alkyl-LPA treatments induces lipid accumulation in C2C12 cells. •Alkyl-LPA enhanced glucose uptake in C2C12 cells. •Alkyl-LPA-treated C2C12 cells express increased amounts of GLUT4 mRNA. •Alkyl-LPA is a novel therapeutic agent that can be used for the treatment of obesity and diabetes. -- Abstract: Studies on the effects of lipids on skeletal muscle cells rarely examine the effects of lysophospholipids. Through our recent studies, we identified select forms of phospholipids, such as alkyl-LPA, as ligands for the intracellular receptor peroxisome proliferator-activated receptor gamma (PPAR?). PPAR? is a nuclear hormone receptor implicated in many human diseases, including diabetes and obesity. We previously showed that alkyl-LPA is a specific agonist of PPAR?. However, the mechanism by which the alkyl-LPA–PPAR? axis affects skeletal muscle cells is poorly defined. Our objective in the present study was to determine whether alkyl-LPA and PPAR? activation promotes glucose uptake in skeletal muscle cells. Our findings indicate that PPAR?1 mRNA is more abundant than PPAR?2 mRNA in C2C12 cells. We showed that alkyl-LPA (3 ?M) significantly activated PPAR? and increased intracellular glucose levels in skeletal muscle cells. We also showed that incubation of C2C12 cells with alkyl-LPA led to lipid accumulation in the cells. These findings suggest that alkyl-LPA activates PPAR? and stimulates glucose uptake in the absence of insulin in C2C12 cells. This may contribute to the plasma glucose-lowering effect in the treatment of insulin resistance.

  8. Kinetic Modeling of Gasoline Surrogate Components and Mixtures under Engine Conditions

    SciTech Connect (OSTI)

    Mehl, M; Pitz, W J; Westbrook, C K; Curran, H J

    2010-01-11T23:59:59.000Z

    Real fuels are complex mixtures of thousands of hydrocarbon compounds including linear and branched paraffins, naphthenes, olefins and aromatics. It is generally agreed that their behavior can be effectively reproduced by simpler fuel surrogates containing a limited number of components. In this work, an improved version of the kinetic model by the authors is used to analyze the combustion behavior of several components relevant to gasoline surrogate formulation. Particular attention is devoted to linear and branched saturated hydrocarbons (PRF mixtures), olefins (1-hexene) and aromatics (toluene). Model predictions for pure components, binary mixtures and multicomponent gasoline surrogates are compared with recent experimental information collected in rapid compression machine, shock tube and jet stirred reactors covering a wide range of conditions pertinent to internal combustion engines (3-50 atm, 650-1200K, stoichiometric fuel/air mixtures). Simulation results are discussed focusing attention on the mixing effects of the fuel components.

  9. Dispensing Equipment Testing with Mid-Level Ethanol/Gasoline Test Fluid: Summary Report

    SciTech Connect (OSTI)

    Boyce, K.; Chapin, J. T.

    2010-11-01T23:59:59.000Z

    The National Renewable Energy Laboratory's (NREL) Nonpetroleum-Based Fuel Task addresses the hurdles to commercialization of biomass-derived fuels and fuel blends. One such hurdle is the unknown compatibility of new fuels with current infrastructure, such as the equipment used at service stations to dispense fuel into automobiles. The U.S. Department of Energy's (DOE) Vehicle Technology Program and the Biomass Program have engaged in a joint project to evaluate the potential for blending ethanol into gasoline at levels higher than nominal 10 volume percent. This project was established to help DOE and NREL better understand any potentially adverse impacts caused by a lack of knowledge about the compatibility of the dispensing equipment with ethanol blends higher than what the equipment was designed to dispense. This report provides data about the impact of introducing a gasoline with a higher volumetric ethanol content into service station dispensing equipment from a safety and a performance perspective.

  10. Draft regulatory analysis: notice of proposed rulemaking motor gasoline allocation revisions

    SciTech Connect (OSTI)

    None

    1980-06-01T23:59:59.000Z

    The Draft Regulatory Analysis is prepared for those proposed regulations which either may have a major impact on the general economy, individual industries, or geographic regions and levels of government, or may be significant in that they affect important DOE policy concerns and are the object of public interest. The problems and proposed solutions for the Notice of Proposed Rulemaking and Public Hearings on the Motor Gasoline Allocation Program are examined. The ERA's mandate for this program is set out in the Emergency Petroleum Allocation Act of 1973. Under this Act, the President is empowered to enforce, at his discretion, price and allocation controls on petroleum and petroleum products, including gasoline, through September 30, 1981. The Act sets the following allocation goals: protect public health; maintain public services and agricultural operations; foster competition in the petroleum industry; distribute petroleum among industry sectors and US regions equitably; and minimize economic disruption and unnecessary interference wth market mechanisms.

  11. Two US markets, or one? How the MTBE-gasoline relationship is evolving

    SciTech Connect (OSTI)

    NONE

    1996-01-26T23:59:59.000Z

    This issue of Energy Detente features the price sensitivity of Methyl Tertiary Butyl Ether. Data is presented for US wholesale gasoline prices vs. MTBE for the 20-month period beginning in June 1994 and ending in January 1996, and the data is discussed. Also contained in this issue is the refining netback data and the fuel price/tax data for the period ending January 5, 1996.

  12. Technoeconomic Comparison of Biofuels: Ethanol, Methanol, and Gasoline from Gasification of Woody Residues (Presentation)

    SciTech Connect (OSTI)

    Tarud, J.; Phillips, S.

    2011-08-01T23:59:59.000Z

    This presentation provides a technoeconomic comparison of three biofuels - ethanol, methanol, and gasoline - produced by gasification of woody biomass residues. The presentation includes a brief discussion of the three fuels evaluated; discussion of equivalent feedstock and front end processes; discussion of back end processes for each fuel; process comparisons of efficiencies, yields, and water usage; and economic assumptions and results, including a plant gate price (PGP) for each fuel.

  13. U.S. gasoline price decrease for first time in seven weeks (short version)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered energy consumption by sector Transportationdiesel fueldieselU.S.3,gasoline

  14. ,"U.S. Sales for Resale, Total Refiner Motor Gasoline Sales Volumes"

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia:FAQ < RAPID Jump to:SeadovCooperativeA2.Reformulated, Average Refiner Gasoline Prices"Sales Volumes

  15. ,"U.S. Sales to End Users, Total Refiner Motor Gasoline Sales Volumes"

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia:FAQ < RAPID Jump to:SeadovCooperativeA2.Reformulated, Average Refiner Gasoline Prices"SalesSales

  16. ,"Finished Motor Gasoline Refinery, Bulk Terminal, and Natural Gas Plant Stocks"

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia:FAQ <Information Administration (EIA) 103. Relative2. Occupancy ofAviation Gasoline Sales to

  17. The Energy Information Administration`s assessment of reformulated gasoline: An update

    SciTech Connect (OSTI)

    Not Available

    1994-12-01T23:59:59.000Z

    This report (Part II) concludes a two part study of The Energy Information Administration`s (EIA) assessment of Reformulated Gasoline (RFG). The data contained herein updates EIA`s previous findings and analyses on reformulated gasoline as it affects the petroleum industry. The major findings of Part II have not changed considerably from Part I: Supplies of RFG are adequate to meet demand, but a tight supply-demand balance exists, leaving the RFG system with little ability to absorb unexpected supply or delivery system disruption. In December 1994, the estimated demand for RFG was 2.6 million barrels per day, with the production capability just meeting this demand. The study concludes that current prices for RFG are consistent with the costs underlying the product, and the difference in RFG and conventional gasoline indicates confidence in supply. The study also follows the impact of recent events such as: postponement of the Renewable Oxygenate Standard, the decision to require importers to use the U.S. average baseline for limiting emissions, the disruption of the Colonial Pipeline in Texas, and Pennsylvania`s request to opt-out of the RFG program.

  18. Role of alkyl alcohol on viscosity of silica-based chemical gels for decontamination of highly radioactive nuclear facilities

    SciTech Connect (OSTI)

    Choi, B. S.; Yoon, S. B.; Jung, C. H.; Lee, K. W.; Moon, J. K. [Div. of Decontamination and Decommissioning Technology Development, Korea Atomic Energy Research Inst., Daedeok-daero 989-111, Yuseong-gu, Daejeon, 305-353 (Korea, Republic of)

    2012-07-01T23:59:59.000Z

    Silica-based chemical gel for the decontamination of nuclear facilities was prepared by using fumed silica as a viscosifier, a 0.5 M Ce (IV) solution dissolved in concentrated nitric acid as a chemical decontamination agent, and tripropylene glycol butyl ether (TPGBE) as a co-viscosifier. A new effective strategy for the preparation of the chemical gel was investigated by introducing the alkyl alcohols as organic solvents to effectively dissolve the co-viscosifier. The mixture solution of the co-viscosifier and alkyl alcohols was more effective in the control of viscosity than that of the co-viscosifier only in gel. Here, the alkyl alcohols played a key role as an effective dissolution solvent for the co-viscosifier in the preparation of the chemical gel, resulting in a reducing of the amount of the co-viscosifier and gel time compared with that of the chemical gel prepared without the alkyl alcohols. It was considered that the alkyl alcohols contributed to the effective dissolution of the co-viscosifier as well as the homogeneous mixing in the formation of the gel, while the co-viscosifier in an aqueous media of the chemical decontamination agent solution showed a lower solubility. The decontamination efficiency of the chemical gels prepared in this work using a multi-channel analyzer (MCA) showed a high decontamination efficiency of over ca. 94% and ca. 92% for Co-60 and Cs-137 contaminated on surface of the stainless steel 304, respectively. (authors)

  19. Exhaust particle characterization for lean and stoichiometric DI vehicles operating on ethanol-gasoline blends

    SciTech Connect (OSTI)

    Storey, John Morse [ORNL] [ORNL; Barone, Teresa L [ORNL] [ORNL; Thomas, John F [ORNL] [ORNL; Huff, Shean P [ORNL] [ORNL

    2012-01-01T23:59:59.000Z

    Gasoline direct injection (GDI) engines can offer better fuel economy and higher performance over their port fuel-injected (PFI) counterparts, and are now appearing in increasingly more U.S. and European vehicles. Small displacement, turbocharged GDI engines are replacing large displacement engines, particularly in light-duty trucks and sport utility vehicles, in order for manufacturers to meet the U.S. fuel economy standards for 2016. Furthermore, lean-burn GDI engines can offer even higher fuel economy than stoichiometric GDI engines and have overcome challenges associated with cost-effective aftertreatment for NOx control. Along with changes in gasoline engine technology, fuel composition may increase in ethanol content beyond the current 10% due to the recent EPA waiver allowing 15% ethanol. In addition, the Renewable Fuels Standard passed as part of the 2007 Energy Independence and Security Act (EISA) mandates the use of biofuels in upcoming years. GDI engines are of environmental concern due to their high particulate matter (PM) emissions relative to port-fuel injected (PFI) gasoline vehicles; widespread market penetration of GDI vehicles may result in additional PM from mobile sources at a time when the diesel contribution is declining. In this study, we characterized particulate emissions from a European certified lean-burn GDI vehicle operating on ethanol-gasoline blends. Particle mass and particle number concentration emissions were measured for the Federal Test Procedure urban driving cycle (FTP 75) and the more aggressive US06 driving cycle. Particle number-size distributions and organic to elemental carbon ratios (OC/EC) were measured for 30 MPH and 80 MPH steady-state operation. In addition, particle number concentration was measured during wide open throttle accelerations (WOTs) and gradual accelerations representative of the FTP 75. Fuels included certification gasoline and 10% (E10) and 20% (E20) ethanol blends from the same supplier. The particle mass emissions were approximately 3 and 7 mg/mile for the FTP75 and US06, respectively, with lower emissions for the ethanol blends. The data are compared to a previous study on a U.S.-legal stoichiometric GDI vehicle operating on the same ethanol blends. The lean-burn GDI vehicle emitted a higher number of particles, but had an overall smaller average size. Particle number per mile decreased with increasing ethanol content for the transient tests. For the 30 and 80 mph tests, particle number concentration decreased with increasing ethanol content, although the shape of the particle size distribution remained the same. Engine-out OC/EC ratios were highest for the stoichiometric GDI vehicle with E20, but tailpipe OC/EC ratios were similar for all vehicles.

  20. Removal patterns of some alkyl phenyl ketones in a heterogeneous bacterial system

    E-Print Network [OSTI]

    Salitros, James Joseph

    1969-01-01T23:59:59.000Z

    never lrave been wri t ten, I can only say thank you. TABLE OF CONTENTS pacCe ABSTRACT ACKNONLEDGEMENTS iLIST OF TABLES LIST OF FIGURES SECTION I Introduction and Literature Review SECTION II Apparatus and Materials Reactor Gas Chromatograph... 2 3 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 3 0 Gas Gas Gas Gas Gas Gas Gas Gas Gas hyl Alkyl Gas Gas Gas Gas Chemical Nomenclature Inorganic i'Jutrients Test A. Reactor Conditions Test A...