National Library of Energy BETA

Sample records for oad abo dit

  1. ABO Wind Espana SA | Open Energy Information

    Open Energy Info (EERE)

    ABO Wind Espana SA Place: Valencia, Spain Zip: 46002 Sector: Wind energy Product: Spanish branch of project developer ABO Wind AG. Coordinates: 39.468791, -0.376913 Show...

  2. ABO Wind AG | Open Energy Information

    Open Energy Info (EERE)

    AG Jump to: navigation, search Name: ABO Wind AG Place: Hessen, Germany Zip: 65193 Sector: Bioenergy, Wind energy Product: German developer of wind and bioenergy generation assets....

  3. ABO Wind Biogas Sachsen Anhalt GmbH Co KG | Open Energy Information

    Open Energy Info (EERE)

    Biogas Sachsen Anhalt GmbH Co KG Jump to: navigation, search Name: ABO Wind Biogas Sachsen-Anhalt GmbH & Co. KG Place: Wiesbaden, Saxony-Anhalt, Germany Zip: 65193 Product: Company...

  4. Origin of the Diverse Behavior of Oxygen Vacancies in ABO3 Perovskites: A Symmetry Based Analysis

    SciTech Connect (OSTI)

    Yin, W. J.; Wei, S. H.; Al-Jassim, M. M.; Yan, Y. F.

    2012-05-15

    Using band symmetry analysis and density functional theory calculations, we reveal the origin of why oxygen vacancy (V{sub O}) energy levels are shallow in some ABO{sub 3} perovskites, such as SrTiO{sub 3}, but are deep in some others, such as LaAlO{sub 3}. We show that this diverse behavior can be explained by the symmetry of the perovskite structure and the location (A or B site) of the metal atoms with low d orbital energies, such as Ti and La atoms. When the conduction band minimum (CBM) is an antibonding {Gamma}12 state, which is usually associated with the metal atom with low d orbital energies at the A site (e.g., LaAlO{sub 3}), then the V{sub O} energy levels are deep inside the gap. Otherwise, if the CBM is the nonbonding {Gamma}25{prime} state, which is usually associated with metal atoms with low d orbital energies at the B site (e.g., SrTiO{sub 3}), then the V{sub O} energy levels are shallow and often above the CBM. The V{sub O} energy level is also deep for some uncommon ABO{sub 3} perovskite materials that possess a low s orbital, or large-size cations, and an antibonding {Gamma}{sub 1} state CBM, such as ZnTiO{sub 3}. Our results, therefore, provide guidelines for designing ABO{sub 3} perovskite materials with desired functional behaviors.

  5. Lead-free and lead-based ABO3 perovskite relaxors with mixed-valence A-site

    Office of Scientific and Technical Information (OSTI)

    and B-site disorder: A comparative neutron scattering structural study of (Na1/2Bi1/2)TiO3 and Pb(Mg1/3Nb2/3)O3 (Journal Article) | SciTech Connect Lead-free and lead-based ABO3 perovskite relaxors with mixed-valence A-site and B-site disorder: A comparative neutron scattering structural study of (Na1/2Bi1/2)TiO3 and Pb(Mg1/3Nb2/3)O3 Citation Details In-Document Search Title: Lead-free and lead-based ABO3 perovskite relaxors with mixed-valence A-site and B-site disorder: A comparative

  6. Slide 1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    images interarrival time aspect ratio partial images complete images rej 1000 tics X2.5cm Standard OAD-2DC arms Modified OAD-2DC arms Standard OAD-2DC arms...

  7. Lead-free and lead-based ABO3 perovskite relaxors with mixed...

    Office of Scientific and Technical Information (OSTI)

    We find that doping NBT with 5.6% BaTiO3, a composition close to the morphotropic phase boundary with enhanced piezoelectric properties, increases the room temperature correlation ...

  8. PDSF User Meeting 03-04-14.pptx

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Outages * None Other Topics from PDSF Staff * New login nodes are online - Accessed v ia l oad b alancer a t pdsf.nersc.gov * Individual a ccess i s a vailable v ia p dsf6, p...

  9. California Maritime Academy: Technical Design Report

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... Figure 7 --- Blade l oading for on revolution 12 With this in mind, a FEA analysis was performed modeling the blade as an idealized cantilever beam experiencing 321 g's, which ...

  10. p-Type transparent conducting oxides and methods for preparation

    DOE Patents [OSTI]

    Shahriari, Dean Y.; Barnabe, Antoine; Mason, Thomas O.; Poeppelmeier, Kenneth R.

    2005-12-27

    A facile, low temperature and low pressure method for the preparation of a wide range of phase pure ABO.sub.2 compositions.

  11. p-Type transparent conducting oxides and methods for preparation

    DOE Patents [OSTI]

    Shahriari, Dean Y.; Barnabe, Antoine; Mason, Thomas O.; Poeppelmeier, Kenneth R.

    2011-05-31

    A facile, low temperature and low pressure method for the preparation of a wide range of phase pure ABO.sub.2 compositions.

  12. A

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    48 55 22 41 52 28 50 02 63 66 64 74 00 62 58 59 11 P a j a r i t o R o a d Los Alamos Airport Di am o nd D r iv e W e st J e m e z R oad 00 Technical Areas TA-00 TA-02 TA-03 TA-05...

  13. NERSC-ScienceHighlightsJuly2013.ppt

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    d ioxide e missions i n California b y 2 1 m illion m etric t ons a nnually - t he s ame a s t aking s ome 4 m illion c ars o ff California r oads e very y ear. --- 8 --- h+p:...

  14. Microsoft PowerPoint - 2012 3rd Qtr Package.ppt [Compatibility...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Commission uses zero-based budgeting for j stif ing the R&D b dget abo e a p esc ibed le el and Reliabilit Cente ed Maintenance justifying the R&D budget above a...

  15. WIPP Update 5_27_14

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 7, 2 014 Waste C ontrol S pecialists c ontinues p recautionary m easures Waste C ontrol S pecialists ( WCS) i n A ndrews, T exas, c ontinues i mplementing p recautionary m easures this w eek t o ensure t he s afety o f t he p ublic, e nvironment a nd w orkers. W CS i s l oading standard w aste boxes from t he s uspect w aste s tream o riginating f rom t he L os A lamos N ational L aboratory (LANL) i nto modular c oncrete c asks. Prior t o l oading, t hermal r eadings a re t aken o f e ach

  16. Michael Stewart! NERSC User Services

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Stewart! NERSC User Services Compilers on NERSC Systems --- 1 --- September 10, 2013 Compilers on NERSC Systems Crays ( Hopper a nd E dison) PrgEnv m odules p rovide l inks t o M PI a nd m ath l ibrary l ibraries a nd includes. Invoke c ompilers w ith w rapper c ommands a nd t he l oaded PrgEnv m odule will i nvoke t he p roper c ompiler: ?n ( Fortran), c c ( C c ompiler), a nd C C ( C+ +). Available c ompiler m odules: pgi ( only o n H opper), i ntel, c ray, a nd g nu (gcc). Default PrgEnv m

  17. I'

    Office of Legacy Management (LM)

    Fou4 ,...-, ,/' / / I' ,/* ,I ,/' 4 ft ,,/- ,/ ./ "' /, 3: :GSD : mh Sylvania Electric Products, Inc. Cantiague Z.oad, P.O. Uox 75 iiicksvill~, I.cng Island. :!.a~ York <; 1. 5,756 lbs. of Fernsld rojeot slugs. 2. 10,000 lbs. rujeoted powder metallurgy slugs. 3. 5,3!;5 lbs. uranium scrap and sludge*. *Th'Ls material, we unc?srstanct, h4S alreedy been shi$ped and this cmfims nuthor.jeatioiito do 80.. %rthar,~in ncxord with the conver&ntion with bir. IStz ws are cancelling your order

  18. Accelerators AND Beams

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... (5) SImulAtIon of DetectIon of A hIggS BoSon In An exPerIment At cern'S lArge hADron collIDer. creDItS toP to Bottom: BrookhAven'S nAtIonAl Synchrotron lIght Source; ...

  19. Texas-Louisiana- Mississippi Salt Basin Greater Green River Basin

    Gasoline and Diesel Fuel Update (EIA)

    Texas-Louisiana- Mississippi Salt Basin Greater Green River Basin W. Gulf Coast Basin Appalachian Basin Wind River Basin Eastern Shelf NW Shelf Abo Sussex-Shannon Muddy J Mesaverde- Lance-Lewis Medina/Clinton-Tuscarora Bradford-Venango-Elk Berea-Murrysville Piceance Basin Bossier Williston Basin Ft Worth Basin Davis Bighorn Basin Judith River- Eagle Permian Basin Anadarko Basin Denver Basin San Juan Basin North-Central Montana Area Uinta Basin Austin Chalk Codell-Niobrara Penn-Perm Carbonate

  20. Diffusion in confinement: kinetic simulations of self- and collective

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    diffusion behavior of adsorbed gases | Center for Gas SeparationsRelevant to Clean Energy Technologies | Blandine Jerome confinement: kinetic simulations of self- and collective diffusion behavior of adsorbed gases Previous Next List M. K. F. Abouelnasr and B. Smit, PCCP 14 (33), 11600 (2012) DOI: 10.1039/C2CP41147D abo121 Abstract The self- and collective-diffusion behaviors of adsorbed methane, helium, and isobutane in zeolite frameworks LTA, MFI, AFI, and SAS were examined at various

  1. U.S. DEPARTMENT OF ENERGY BIOMASS PROGRAM

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    DEPARTMENT OF ENERGY BIOMASS PROGRAM Biomass Program ABO Algae Biomass Summit September 25, 2012 Valerie Reed, PhD Acting Program Manager 2 | Biomass Program eere.energy.gov Biomass Program Priorities Promote the use of diverse, domestic, and sustainable energy resources Establish an advanced bioindustry and stimulate economic growth Reduce carbon emissions from energy production and consumption Dramatically reduce dependence on foreign oil The Biomass Program supports the following national

  2. Towards 3D mapping of BO? octahedron rotations at perovskite heterointerfaces, unit cell by unit cell

    SciTech Connect (OSTI)

    He, Qian; Ishikawa, Ryo; Lupini, Andrew R.; Qiao, Liang; Moon, Eun Ju; Ovchinnikov, Oleg S.; May, Steven J.; Biegalski, Michael D.; Borisevich, Albina Y.

    2015-07-15

    The rich functionalities in the ABO? perovskite oxides originate at least partly from the ability of the corner-connected BO? octahedral network to host a large variety of cations through distortions and rotations. Characterizing these rotations, which significantly affect both fundamental aspects of materials behavior and possible applications, remains a major challenge. In this work, we have developed a unique method of investigating BO? rotation patterns in complex oxides ABO? with unit cell resolution at heterointerfaces, where novel properties often emerge. Our method involves column shape analysis in annular bright field - scanning transmission electron microscope images of the ABO? heterointerfaces taken in specific orientations. The rotating phase of BO? octahedra can be identified for all three spatial dimensions without the need of case-by-case simulation. In several common rotation systems, it is now possible to quantitatively measure all three rotation angles. With this method, we examined interfaces between perovskites with distinct tilt systems as well as interfaces between tilted and untilted perovskites, identifying an unusual coupling behavior at the CaTiO?/LSAT interface. We believe this unique method will significantly improve our knowledge of the complex oxide heterointerfaces.

  3. A

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Unleashing the Power of Next---Genera5on Many---Core Processors Richard A . G erber ( NERSC) Chris G o6brath ( Rogue W ave S o<ware) Chris J . N ewburn ( Intel) Thomas S teinke ( ZIB) Frankfurt, J uly 1 5 th 2 015 IXPUG W ORKSHOP The R oad t o A pplica/on P erformance o n I ntel X eon P hi Thursday, J uly 1 6, 2 015 09:00 a m --- 0 1:00 p m Room: K ilobyte, F rankfurt M arrio6 H otel www.ixpug.org 7/15/15 www.ixpug.org 2 Agenda IXPUG BoF 12:15 Welcome a nd I ntroduc/on ( Thomas S teinke, Z

  4. PDSF User Meeting 05-06-14.pptx

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    4 Lisa Gerhardt Utilization --- 2 --- Past Outages * 4/22/14: M endel r ack 1 2 u pgrade * 4/23/14 ( 11 a m - 1 2 p m): R olling r eboot o f l ogin nodes * 5/1/14 ( 24 h ours): M endel r ack 1 p ower Planned Outages * May 1 3 ( 8:00 a m - 5 :00 p m): F ull o utage. J obs w ill begin d raining a t 5 :00 p m t he d ay b efore Other Topics from PDSF Staff * Please u se p dsf.nersc.gov t o a ccess P DSF - Goes t hrough l oad b alancer - Old l ogin n odes a re u sed f or s ystem t es8ng a nd c an b e

  5. Microsoft Word - Port of Call Dates.docx

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Horizon S pirit P ort o f C all D ates The f ollowing d ates a re t entative p ort c alls b ased u pon t he n ormal t ransit a nd d ock times. P lease b e a ware t hat s ignificant c hanges c an o ccur d ue t o m echanical difficulties either w ith t he v essel o r p ort e quipment, l abor d isputes o r g eneral d ock traffic l oading a nd u nloading i ssues. The t ypical i n p ort t imes f or L os A ngeles a re a rrival o n a T hursday m orning a round 8 a m l ocal t ime a nd d eparts o n S

  6. TEAMING AS A SMALL BUSINESS Brent L. Clark, Vice President Performance Results Corporation

    Energy Savers [EERE]

    TEAMING AS A SMALL BUSINESS Brent L. Clark, Vice President Performance Results Corporation 2 WHO IS PERFORMANCE RESULTS CORPORATION? * Incorporated i n A pril 2 000 * SBA C er4fied S mall, W oman---Owned C orpora4on * Kathy C linton O wner a nd P resident * Located a t 6 C anyon R oad, M organtown, W V * Employs o ver 2 30 p ersonnel l ocated a cross 1 6 ci4es a nd 1 3 s tates * 2010 r evenue w as $ 25M, p rojected t o e xceed $30M i n 2 011 * Primary c lients a re t he D OE, D OJ, C DC, a nd A

  7. Transaction-Based Operation of Resource Constrained Systems

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Transac'on---Based O pera'on o f Resource C onstrained S ystems - T ROPEC T ransac.ve E nergy M icrogrid C ontroller - Vol$ron T echnical M ee/ng July 24, 2015 Rich B rown, B ruce N ordman, S tephen C zarnecki, M ike Spears, A nna L iao, M ichael V on H ippel, M ary A nn P ie$e Lawrence B erkeley N a/onal L aboratory Funded b y D OE/EERE, D oD/TROPEC 1 Objec'ves * Integrate r epresenta/ve c on/ngency---base l oad a nd g enera/on a ssets i nto transac/onal n etwork * Demonstrate o pera/on o f m

  8. Synthesis of N-formyl-3,4-di-t-butoxycarbonyloxy-6(trimethylstannyl)-L-phenylalanine ethyl ester and its regioselective radiofluorodestannylation to 6-[{sup 18}F]fluoro-1-dopa

    DOE Patents [OSTI]

    Satyamurthy, N.; Barrio, J.R.; Bishop, A.J.; Namavari, M.; Bida, G.T.

    1996-04-23

    A process is revealed for forming a 6-fluoro derivative of compounds in the L-Dopa family comprising the steps of protecting the groups attached to the benzene ring in the compound followed by serially reacting the protected compound with (a) iodine and silver trifluoroacetic acid; (b) Bb{sub 3}; (c) dit-butyldicarbonate; (d) hexamethyltin; (e) a fluoro compound; (f) hydrobromic acid; and (g) raising the pH to {<=}7. 1 fig.

  9. Synthesis of N-formyl-3,4-di-t-butoxycarbonyloxy-6-(trimethylstannyl)-L-phenylalanine ethyl ester and its regioselective radiofluorodestannylation to 6- .sup.18 F!fluoro-1-dopa

    DOE Patents [OSTI]

    Satyamurthy, Nagichettiar; Barrio, Jorge R.; Bishop, Allyson J.; Namavari, Mohammad; Bida, Gerald T.

    1996-01-01

    A process for forming a 6-fluoro derivative of compounds in the L-Dopa family comprising the steps of protecting the groups attached to the benzene ring in the compound followed by serially reacting the protected compound with (a) iodine and silver trifluoroacetic acid; (b) Bb.sub.3 ; (c) dit-butyldicarbonate; (d) hexamethyltin; (e) a fluoro compound; (f) hydrobromic acid; and (g) raising the pH to .ltoreq.7.

  10. Protective coatings for metal alloys and methods incorporating the same

    DOE Patents [OSTI]

    Seabaugh, Matthew M.; Ibanez, Sergio; Swartz, Scott L.

    2015-06-09

    An electrochemical device having one or more solid oxide fuel cells (SOFCs), each of the SOFCs including a cathode, an anode, and an electrolyte layer positioned between the cathode and anode; and at least one additional component comprising a metallic substrate having an electronically conductive, chromium-free perovskite coating deposited directly thereon. The perovskite coating has the formula ABO.sub.3, wherein A is a lanthanide element or Y, and B is a mixture of two or more transition elements, with the A site undoped by any alkaline earth element, and the perovskite coating exhibits limited or no ionic transport of oxygen.

  11. Structural Basis of Wnt Signaling Inhibition by Dickkopf Binding to LRP5/6

    Office of Scientific and Technical Information (OSTI)

    (Journal Article) | SciTech Connect Basis of Wnt Signaling Inhibition by Dickkopf Binding to LRP5/6 Citation Details In-Document Search Title: Structural Basis of Wnt Signaling Inhibition by Dickkopf Binding to LRP5/6 Authors: Ahn, Victoria E. ; Chu, Matthew Ling-Hon ; Choi, Hee-Jung ; Tran, Denise ; Abo, Arie ; Weis, William I. Publication Date: 2011-11-01 OSTI Identifier: 1198118 Type: Published Article Journal Name: Developmental Cell Additional Journal Information: Journal Volume: 21;

  12. STEM-ing the Tide | Department of Energy

    Energy Savers [EERE]

    STEM-ing the Tide STEM-ing the Tide September 29, 2010 - 4:29pm Addthis Ali Zaidi Special Assistant to the Secretary of Energy Yesterday, the MacArthur Foundation rolled out its latest class of "geniuses" - 23 Americans who stand out because of their creativity and enterprise. Each recipient of the honor (and the $500,000 prize) has made an extraordinary contribution. One of those recipients is Amir Abo-Shaeer, an engineer in the aerospace and telecommunications industries who decided

  13. R I

    Office of Legacy Management (LM)

    . [b, R I c ~ ~ & F, INC. L A ~ & L E ' , - F~ZVICES \ : " ' May 11,2004 Pamela S. French Stoller-Navarro 7710 West Cheyenne Avenue Las Vegas, NV 89129 Re: Tatum Salt Dome site Lamas County, Mississippi Dear Pamela, Enclosed you will fmd the original title opinion that we have prepared for the abo referenced property owned by the United States of America. I have also enclose supporting documents for the ownership interests as reflected in the title opinion. Thank you for allowing

  14. FY

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    FY 2008 FOIA - Request Log Closed/ No. Dated Date HQ ~~- l Date Rec'd or Dir. Finalized 001 02/01/08 03/11/08 Transfer ':'11 correspondence: m~mora~da, documents, reports, recor~s, statement~, ~~dits, IV' IA AI Ir"I:9 r._.-._ I." Vvl I 11VU "UII' n\,,( lists of names, applications, diskettes, ietters, calendars or diary logs, facsimile logs, call sheets, tape recordings, video. movie recordings, notes, chars, photographs, electronic mail and other documents sand things that refer

  15. Ferroelectric capacitor with reduced imprint

    DOE Patents [OSTI]

    Evans, Jr., Joseph T. (13609 Verbena Pl., NE., Albuquerque, NM 87112); Warren, William L. (7716 Wm. Moyers Ave., NE., Albuquerque, NM 87122); Tuttle, Bruce A. (12808 Lillian Pl., NE., Albuquerque, NM 87122); Dimos, Duane B. (6105 Innsbrook Ct., NE., Albuquerque, NM 87111); Pike, Gordon E. (1609 Cedar Ridge, NE., Albuquerque, NM 87112)

    1997-01-01

    An improved ferroelectric capacitor exhibiting reduced imprint effects in comparison to prior art capacitors. A capacitor according to the present invention includes top and bottom electrodes and a ferroelectric layer sandwiched between the top and bottom electrodes, the ferroelectric layer comprising a perovskite structure of the chemical composition ABO.sub.3 wherein the B-site comprises first and second elements and a dopant element that has an oxidation state greater than +4. The concentration of the dopant is sufficient to reduce shifts in the coercive voltage of the capacitor with time. In the preferred embodiment of the present invention, the ferroelectric element comprises Pb in the A-site, and the first and second elements are Zr and Ti, respectively. The preferred dopant is chosen from the group consisting of Niobium, Tantalum, and Tungsten. In the preferred embodiment of the present invention, the dopant occupies between 1 and 8% of the B-sites.

  16. Static ferroelectric memory transistor having improved data retention

    DOE Patents [OSTI]

    Evans, Jr., Joseph T. (13609 Verbena Pl., N.E., Albuquerque, NM 87112); Warren, William L. (7716 Wm. Moyers Ave., NE., Albuquerque, NM 87112); Tuttle, Bruce A. (12808 Lillian Pl., NE., Albuquerque, NM 87112)

    1996-01-01

    An improved ferroelectric FET structure in which the ferroelectric layer is doped to reduce retention loss. A ferroelectric FET according to the present invention includes a semiconductor layer having first and second contacts thereon, the first and second contacts being separated from one another. The ferroelectric FET also includes a bottom electrode and a ferroelectric layer which is sandwiched between the semiconductor layer and the bottom electrode. The ferroelectric layer is constructed from a perovskite structure of the chemical composition ABO.sub.3 wherein the B site comprises first and second elements and a dopant element that has an oxidation state greater than +4 in sufficient concentration to impede shifts in the resistance measured between the first and second contacts with time. The ferroelectric FET structure preferably comprises Pb in the A-site. The first and second elements are preferably Zr and Ti, respectively. The preferred B-site dopants are Niobium, Tantalum, and Tungsten at concentrations between 1% and 8%.

  17. Strain Accommodation By Facile WO6 Octahedral Distortion and Tilting During WO3 Heteroepitaxy on SrTiO3(001)

    SciTech Connect (OSTI)

    Du, Yingge; Gu, Meng; Varga, Tamas; Wang, Chong M.; Bowden, Mark E.; Chambers, Scott A.

    2014-08-27

    In this paper, we show that compared to other BO6 octahedra in ABO3 structured perovskite oxides, the WO6 octahedra in tungsten trioxide (WO3) can withstand a much larger degree of distortion and tilting to accommodate interfacial strain, which in turn strongly impact the nucleation, structure, and defect formation during the epitaxial growth of WO3 on SrTiO3(001). A meta-stable tetragonal phase can be stabilized by epitaxy and a thickness dependent phase transition (tetragonal to monoclinic) is observed. In contrast to misfit dislocations to accommodate the interfacial stain, the facial WO6 octahedral distortion and tilting give rise to three types of planar defects that affect more than 15 monolayers from the interface. These atomically resolved, unusual interfacial defects may significantly alter the electronic, electrochromic, and mechanical properties of the epitaxial films.

  18. Structure and ferroelectricity of nonstoichiometric (Na{sub 0.5}Bi{sub 0.5})TiO{sub 3}

    SciTech Connect (OSTI)

    Carter, Jared; Aksel, Elena; Iamsasri, Thanakorn; Forrester, Jennifer S.; Jones, Jacob L.; Chen, Jun

    2014-03-17

    Stoichiometric (Na{sub 0.5}Bi{sub 0.5})TiO{sub 3} (NBT) adopts the ABO{sub 3} perovskite structure with the A-site equally occupied by Na{sup +} and Bi{sup 3+} ions. However, non-stoichiometric compositions can be synthesized intentionally or unintentionally. To determine the effect of A-site nonstoichiometry on the crystal structure and ferroelectricity of NBT, the composition of (Na{sub 0.5?x}Bi{sub 0.5+x})TiO{sub 3+x} was varied using x?=??0.01, ?0.005, 0, 0.005, and 0.01. High resolution synchrotron x-ray diffraction and Rietveld refinement revealed that a shift in either direction from x = 0 results in a decrease in the spontaneous ferroelastic strain. Ferroelectric hysteresis and piezoelectric coefficients were found to be optimum in the stoichiometric composition.

  19. B

    Office of Legacy Management (LM)

    ;;;. plf. t& -b ,,::";:,I. , P- ^' ' I- $ : / 7 ! I T,f , - . -.. .._...__ _ ___. ___ yL." j";;e,.i.--ey- g-- .._ ___...._ fi' B res ~...: j w CWies, Series-, __.__ CtASlfKATION MAi%- TO: NOT ClAsUFlED huCsuso u 1944 -1, ,- ,ciiT 7 t-ff hi .A a To: c. I?. Daniel8 T-7 In m3: <&dit y n&u-d\mre CorIpeqly Aftax ounmroation xlth Dr. Stona, it %Z3S d85Li0d t!lUt WX!TJdQtO tar;~inul phyolaul sx~?~inations x-ill not be IIeOasaWX'y On la:tirldtiti who had wrked less tha E

  20. Effect of cation ordering on oxygen vacancy diffusion pathways in double perovskites

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Uberuaga, Blas Pedro; Pilania, Ghanshyam

    2015-07-08

    Perovskite structured oxides (ABO3) are attractive for a number of technological applications, including as superionics because of the high oxygen conductivities they exhibit. Double perovskites (AA’BB’O6) provide even more flexibility for tailoring properties. Using accelerated molecular dynamics, we examine the role of cation ordering on oxygen vacancy mobility in one model double perovskite SrLaTiAlO6. We find that the mobility of the vacancy is very sensitive to the cation ordering, with a migration energy that varies from 0.6 to 2.7 eV. In the extreme cases, the mobility is both higher and lower than either of the two end member single perovskites.more » Further, the nature of oxygen vacancy diffusion, whether one-dimensional, two-dimensional, or three-dimensional, also varies with cation ordering. We correlate the dependence of oxygen mobility on cation structure to the distribution of Ti4+ cations, which provide unfavorable environments for the positively charged oxygen vacancy. The results demonstrate the potential of using tailored double perovskite structures to precisely control the behavior of oxygen vacancies in these materials.« less

  1. Air electrode composition for solid oxide fuel cell

    DOE Patents [OSTI]

    Kuo, Lewis (Monroeville, PA); Ruka, Roswell J. (Pittsburgh, PA); Singhal, Subhash C. (Murrysville, PA)

    1999-01-01

    An air electrode composition for a solid oxide fuel cell is disclosed. The air electrode material is based on lanthanum manganite having a perovskite-like crystal structure ABO.sub.3. The A-site of the air electrode composition comprises a mixed lanthanide in combination with rare earth and alkaline earth dopants. The B-site of the composition comprises Mn in combination with dopants such as Mg, Al, Cr and Ni. The mixed lanthanide comprises La, Ce, Pr and, optionally, Nd. The rare earth A-site dopants preferably comprise La, Nd or a combination thereof, while the alkaline earth A-site dopant preferably comprises Ca. The use of a mixed lanthanide substantially reduces raw material costs in comparison with compositions made from high purity lanthanum starting materials. The amount of the A-site and B-site dopants is controlled in order to provide an air electrode composition having a coefficient of thermal expansion which closely matches that of the other components of the solid oxide fuel cell.

  2. Cation Intermixing And Electronic Deviations At The Insulating LaCrO3/SrTiO3(001) Interface

    SciTech Connect (OSTI)

    Colby, Robert J.; Qiao, Liang; Zhang, Hongliang; Shutthanandan, V.; Ciston, Jim; Kabius, Bernd C.; Chambers, Scott A.

    2013-10-29

    The interface between polar perovskite LaCrO3 (LCO) and non-polar SrTiO3(001) (STO), grown by molecular beam epitaxy, is examined using a combination of electron microscopy, spectroscopy, and Rutherford backscattering spectrometry. The LCO/STO(001) interface is insulating, a potential counter example for the claim that polar/nonpolar perovskite interfaces should be conductive by virtue of an electronic reconstruction to alleviate the polar discontinuity. The A-site cations of these ABO3 perovskites are found to diffuse across the interface to a greater extent than the B-site cations, based on high angle annular dark field scanning transmission electron microscopy (HAADF-STEM), energy dispersive x-ray spectroscopy (EDS) and electron energy loss spectroscopy (EELS). The B-site cation valences are shown to be partially reduced near the interface by analysis of EELS near-edge structures. The location and direction of these electronic modifications do not intuitively compensate the charge imbalance imposed by uneven cation inter-diffusion, and yet both the film and interface are insulating. These results highlight the importance of both the physical and electronic structure of such complex interfaces in determining their characteristics. Furthermore, the extent of inter-diffusion is shown to increase with increasing LCO film thickness, suggesting a potential mechanism behind the critical thickness for interfacial conductivity in other polar/non-polar oxide systems, and a fundamental limitation on the formation of abrupt interfaces in LCO/STO(001).

  3. OPTIMIZATION OF INFILL DRILLING IN NATURALLY-FRACTURED TIGHT-GAS RESERVOIRS

    SciTech Connect (OSTI)

    Lawrence W. Teufel; Her-Yuan Chen; Thomas W. Engler; Bruce Hart

    2004-05-01

    A major goal of industry and the U.S. Department of Energy (DOE) fossil energy program is to increase gas reserves in tight-gas reservoirs. Infill drilling and hydraulic fracture stimulation in these reservoirs are important reservoir management strategies to increase production and reserves. Phase II of this DOE/cooperative industry project focused on optimization of infill drilling and evaluation of hydraulic fracturing in naturally-fractured tight-gas reservoirs. The cooperative project involved multidisciplinary reservoir characterization and simulation studies to determine infill well potential in the Mesaverde and Dakota sandstone formations at selected areas in the San Juan Basin of northwestern New Mexico. This work used the methodology and approach developed in Phase I. Integrated reservoir description and hydraulic fracture treatment analyses were also conducted in the Pecos Slope Abo tight-gas reservoir in southeastern New Mexico and the Lewis Shale in the San Juan Basin. This study has demonstrated a methodology to (1) describe reservoir heterogeneities and natural fracture systems, (2) determine reservoir permeability and permeability anisotropy, (3) define the elliptical drainage area and recoverable gas for existing wells, (4) determine the optimal location and number of new in-fill wells to maximize economic recovery, (5) forecast the increase in total cumulative gas production from infill drilling, and (6) evaluate hydraulic fracture simulation treatments and their impact on well drainage area and infill well potential. Industry partners during the course of this five-year project included BP, Burlington Resources, ConocoPhillips, and Williams.

  4. NaIrO{sub 3}-A pentavalent post-perovskite

    SciTech Connect (OSTI)

    Bremholm, M.; Dutton, S.E.; Stephens, P.W.; Cava, R.J.

    2011-03-15

    Sodium iridium (V) oxide, NaIrO{sub 3,} was synthesized by a high pressure solid state method and recovered to ambient conditions. It is found to be isostructural with CaIrO{sub 3}, the much-studied structural analog of the high-pressure post-perovskite phase of MgSiO{sub 3}. Among the oxide post-perovskites, NaIrO{sub 3} is the first example with a pentavalent cation. The structure consists of layers of corner- and edge-sharing IrO{sub 6} octahedra separated by layers of NaO{sub 8} bicapped trigonal prisms. NaIrO{sub 3} shows no magnetic ordering and resistivity measurements show non-metallic behavior. The crystal structure, electrical and magnetic properties are discussed and compared to known post-perovskites and pentavalent perovskite metal oxides. -- Graphical abstract: Sodium iridium(V) oxide, NaIrO{sub 3}, synthesized by a high pressure solid state method and recovered to ambient conditions is found to crystallize as the post-perovskite structure and is the first example of a pentavalent ABO{sub 3} post-perovskite. Research highlights: {yields} NaIrO{sub 3} post-perovskite stabilized by pressure. {yields} First example of a pentavalent oxide post-perovskite. {yields} Non-metallic and non-magnetic behavior of NaIrO{sub 3}.

  5. Air electrode composition for solid oxide fuel cell

    DOE Patents [OSTI]

    Kuo, L.; Ruka, R.J.; Singhal, S.C.

    1999-08-03

    An air electrode composition for a solid oxide fuel cell is disclosed. The air electrode material is based on lanthanum manganite having a perovskite-like crystal structure ABO{sub 3}. The A-site of the air electrode composition comprises a mixed lanthanide in combination with rare earth and alkaline earth dopants. The B-site of the composition comprises Mn in combination with dopants such as Mg, Al, Cr and Ni. The mixed lanthanide comprises La, Ce, Pr and, optionally, Nd. The rare earth A-site dopants preferably comprise La, Nd or a combination thereof, while the alkaline earth A-site dopant preferably comprises Ca. The use of a mixed lanthanide substantially reduces raw material costs in comparison with compositions made from high purity lanthanum starting materials. The amount of the A-site and B-site dopants is controlled in order to provide an air electrode composition having a coefficient of thermal expansion which closely matches that of the other components of the solid oxide fuel cell. 3 figs.

  6. Lanthanum manganite-based air electrode for solid oxide fuel cells

    DOE Patents [OSTI]

    Ruka, Roswell J.; Kuo, Lewis; Li, Baozhen

    1999-01-01

    An air electrode material for a solid oxide fuel cell is disclosed. The electrode material is based on lanthanum manganite having a perovskite-like crystal structure ABO.sub.3. The A-site of the air electrode material preferably comprises La, Ca, Ce and at least one lanthanide selected from Sm, Gd, Dy, Er, Y and Nd. The B-site of the electrode material comprises Mn with substantially no dopants. The ratio of A:B is preferably slightly above 1. A preferred air electrode composition is of the formula La.sub.w Ca.sub.x Ln.sub.y Ce.sub.z MnO.sub.3, wherein Ln comprises at least one lanthanide selected from Sm, Gd, Dy, Er, Y and Nd, w is from about 0.55 to about 0.56, x is from about 0.255 to about 0.265, y is from about 0.175 to about 0.185, and z is from about 0.005 to about 0.02. The air electrode material possesses advantageous chemical and electrical properties as well as favorable thermal expansion and thermal cycle shrinkage characteristics.

  7. Lanthanum manganite-based air electrode for solid oxide fuel cells

    DOE Patents [OSTI]

    Ruka, R.J.; Kuo, L.; Li, B.

    1999-06-29

    An air electrode material for a solid oxide fuel cell is disclosed. The electrode material is based on lanthanum manganite having a perovskite-like crystal structure ABO[sub 3]. The A-site of the air electrode material preferably comprises La, Ca, Ce and at least one lanthanide selected from Sm, Gd, Dy, Er, Y and Nd. The B-site of the electrode material comprises Mn with substantially no dopants. The ratio of A:B is preferably slightly above 1. A preferred air electrode composition is of the formula La[sub w]Ca[sub x]Ln[sub y]Ce[sub z]MnO[sub 3], wherein Ln comprises at least one lanthanide selected from Sm, Gd, Dy, Er, Y and Nd, w is from about 0.55 to about 0.56, x is from about 0.255 to about 0.265, y is from about 0.175 to about 0.185, and z is from about 0.005 to about 0.02. The air electrode material possesses advantageous chemical and electrical properties as well as favorable thermal expansion and thermal cycle shrinkage characteristics. 10 figs.

  8. Le LHC, un tunnel cosmique

    ScienceCinema (OSTI)

    None

    2011-10-06

    Et si la lumière au bout du tunnel du LHC était cosmique ? En d?autres termes, qu?est-ce que le LHC peut nous apporter dans la connaissance de l?Univers ? Car la montée en énergie des accélérateurs de particules nous permet de mieux appréhender l?univers primordial, chaud et dense. Mais dans quel sens dit-on que le LHC reproduit des conditions proches du Big bang ? Quelles informations nous apporte-t-il sur le contenu de l?Univers ? La matière noire est-elle détectable au LHC ? L?énergie noire ? Pourquoi l?antimatière accumulée au CERN est-elle si rare dans l?Univers ? Et si le CERN a bâti sa réputation sur l?exploration des forces faibles et fortes qui opèrent au sein des atomes et de leurs noyaux, est-ce que le LHC peut nous apporter des informations sur la force gravitationnelle qui gouverne l?évolution cosmique ? Depuis une trentaine d?années, notre compréhension de l?univers dans ses plus grandes dimensions et l?appréhension de son comportement aux plus petites distances sont intimement liées : en quoi le LHC va-t-il tester expérimentalement cette vision unifiée ? Tout public, entrée libre / Réservations au +41 (0)22 767 76 76

  9. DEVELOPMENT OF IMPROVED ANAEROBIC GROWTH OF BACILLUS MOJAVENSIS STRAIN JF-2 FOR THE PURPOSE OF IMPROVED ANAEROBIC BIOSURFACTANT PRODUCTION FOR ENHANCED OIL RECOVERY

    SciTech Connect (OSTI)

    M.J. McInerney; M. Folmsbee; D. Nagle

    2004-05-31

    Our work focuses on the use of microorganisms to recover petroleum hydrocarbons that remain entrapped after current recovery technologies reach their economic limit. Capillary forces between the hydrocarbon and aqueous phases are largely responsible for trapping the hydrocarbons in the pores of the rock and large reductions in the interfacial tension between the hydrocarbon and aqueous phases are needed for hydrocarbon mobilization (1-3, 10, 11). Microorganisms produce a variety of biosurfactants (4), several of which generate the ultra low interfacial tensions needed for hydrocarbon mobilization (4, 5, 8). In particular, the lipopeptide biosurfactant produced by Bacillus mojavensis strain JF-2 reduces the interfacial tension between hydrocarbon and aqueous phases to very low levels (<0.016 mN/m) (8) (9). B. mojavensis JF-2 grows under the environmental conditions found in many oil reservoirs, i. e., anaerobic, NaCl concentrations up to 80 g l{sup -1}, and temperatures up to 45 C (6, 7), making it ideally suited for in situ applications. However, anaerobic growth of B. mojavensis JF-2 was inconsistent and difficult to replicate, which limited its use for in situ applications. Our initial studies revealed that enzymatic digests, such as Proteose Peptone, were required for anaerobic growth of Bacillus mojavensis JF-2. Subsequent purification of the growth-enhancing factor in Proteose Peptone resulted in the identification of the growth-enhancing factor as DNA or deoxyribonucleosides. The addition of salmon sperm DNA, herring sperm DNA, E. coli DNA or synthetic DNA (single or double stranded) to Medium E all supported anaerobic growth of JF-2. Further, we found that JF-2 required all four deoxyribonucleosides (deoxyadeonosine, deoxyguanosine, deoxycytidine and thymidine) for growth under strict anaerobic conditions. The requirement for the deoxyribonucleosides did not occur under aerobic growth conditions. DNA was not used as a sole energy source; sucrose was required for anaerobic growth and biosurfactant production in DNA-supplemented Medium E. In addition to DNA or deoxyribonucleosides, nitrate, amino acids and vitamins were all required for anaerobic growth of JF-2. Bacillus mojavensisT (ABO21191), Bacillus mojavensis, strain ROB2 also required DNA or deoxyribonucleosides for anaerobic growth. The improved anaerobic growth of Bacillus mojavensis JF-2 was a prerequisite for studies that will lead to improved anaerobic biosurfactant production.

  10. Predation, Competition, and Abiotic Disturbance: Population Dynamics of Small Mammals

    SciTech Connect (OSTI)

    Yunger, John A.; /Northern Illinois U. /Northern Illinois U.

    1996-01-01

    Predation and food availability have been implicated in annual non-cyclic fluctuations of vertebrate prey at mid-latitudes. The timing and magnitude of these factors are unclear due to a lack of large-scale field experiments, little attention to interactions, and a failure to closely link vertebrate predators with their prey. From October 1992 to January 1996, small mammal populations were censused on eight 0.6 ha plots at monthly intervals in a 32-ha prairie restoration at Fermi National Accelerator Laboratory, Illinois. Terrestrial vertebrate predators were excluded after July 1993 from four of the eight plots and canid diets monitored. Both terrestrial and avian vertebrate predators were excluded in March 1994. During 1993 small mammal densities (i.e., Microtus Pennsylvanicus, Peromyscus leucopus, and P. maniculatus) were relatively high. Following peak densities in late summer, Microtus numbers wer 2-3x greater on exclusion plots relative to controls due to preferential selection of Microtus by canids, as reflected in dits. Following an ice-storm and crash in small mammal numbers (particularly Microtus), vertebrate predator exclusion had no detectable effect on P. leucopus numbers, probably due to an abundance of alternative prey (i.e., Sylvilagus floridanus). Meadow vole numbers began to increase in Fall 1995, and a numerical effect of predator exclusion, similar to that in 1993, was observed. Predator exclusion had no detectable effect on the movements and spatial patterns of Microtus during 1993. There was a significant decrease in home range and a significant increase in home range overlap for P. leucopus on the predator exclusion plots. The change in spatial behavior may be due to interspecific competition with Microtus resulting from increased densities on exclusion plots. Thus, predators had an indirect effect on P. leucopus spatial patterns mediated through M. Pennsylvanicus. The role of food limitation was studied using natural and manipulative experiments. Unusually high acorn production in Fall 1994 resulted in increased P. leucopus numbers at one Fermilab site due to immigration since survivorship or reproduction were unaffected. A food supplementation experiment during October 1994-March 1995 induced a strong increase in P. leucopus numbers, due again to immigration, although reproduction also was advanced by two months.