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Sample records for nty syc amore

  1. U.S. Department of Energy and NTI Announce Key Nonproliferation...

    Energy Savers [EERE]

    HEU and Convert Reactor WASHINGTON, D.C. - The U.S. Department of Energy and the Nuclear Threat Initiative (NTI) today announced that they have reached an important...

  2. Context-dependent protein folding of a virulence peptide in the bacterial and host environments: structure of an SycH–YopH chaperone–effector complex

    SciTech Connect (OSTI)

    Vujanac, Milos; Stebbins, C. Erec, E-mail: stebbins@rockefeller.edu [The Rockefeller University, New York, NY 10065 (United States)

    2013-04-01

    The structure of a SycH–YopH chaperone–effector complex from Yersinia reveals the bacterial state of a protein that adopts different folds in the host and pathogen environments. Yersinia pestis injects numerous bacterial proteins into host cells through an organic nanomachine called the type 3 secretion system. One such substrate is the tyrosine phosphatase YopH, which requires an interaction with a cognate chaperone in order to be effectively injected. Here, the first crystal structure of a SycH–YopH complex is reported, determined to 1.9 Å resolution. The structure reveals the presence of (i) a nonglobular polypeptide in YopH, (ii) a so-called ?-motif in YopH and (iii) a conserved hydrophobic patch in SycH that recognizes the ?-motif. Biochemical studies establish that the ?-motif is critical to the stability of this complex. Finally, since previous work has shown that the N-terminal portion of YopH adopts a globular fold that is functional in the host cell, aspects of how this polypeptide adopts radically different folds in the host and in the bacterial environments are analysed.

  3. Sic et non en el Libro de buen amor 

    E-Print Network [OSTI]

    Hinton, Melvin

    1999-01-01

    point to the same signifies. This instability--shifting reality--is a refection of the everyday reality observed by the writers. An analysis of that reality should explain the simultaneous preaching of been amor and appealing presentation of loco amor...

  4. University of Maryland Baltimore County Policy on Amorous and Sexual Relationships

    E-Print Network [OSTI]

    Suri, Manil

    , no personal ties should be allowed to interfere with the academic integrity of the faculty-student relationship or with the professional integrity of the supervisor-employee relationship. In the particular case of amorous and sexual relationships, the potential for harm to that integrity exists not only

  5. La mujer y el amor en El mismo mar de todos los veranos, de Esther Tusquets 

    E-Print Network [OSTI]

    Reed, Linnette Fourquet

    1985-01-01

    Subject: Ncdern Languages LA NUJER Y EL AMOR EN EL NISMO NAR DE TODOS LOS VERANOSg DE ESTHER TUSQUEI'S A Thesis by Approved as to style and content by: Luis F. Costa (Chairman of the Committee) Joe S. Graham (Member) est r C. ' isti Jr. (~) Luis... with Tusquets, by almost all other con- temporary novelists in Spain. TABLE OF ~S CAPITULO I 1?IRCDUCCION. Pagina Datos biograficos La escritora espahola en la posguerra. . . La represion franquista. II LA NOVEIA FEMENINA ACTUAL EN ESPANA. . 2 3 10...

  6. “Como pella a las dueñas, tomelo quien podiere”: anacronismo y representación en las adaptaciones cinemáticas del Libro de buen amor dirigidas por Tomás Aznar y Jaime Bayarri

    E-Print Network [OSTI]

    Drayson, E. A.

    2015-01-01

    bastante del desnudo macho, con Juan Ruiz totalmente aunque discretamente desnudo al nadar en el río para refrescarse. Endrina casi se ahoga cuando queda atrapada por las algas del río, su guirnalda de flores flotando en el agua de una manera que evoca a... Ofelia. Juan Ruiz salta al agua con heroísmo y la salva del peligro, llevándola a la orilla donde consuman su amor. Poco después Endrina muere de una fiebre, y al poeta se le acusa injustamente de haber causado su muerte. Esta tragedia es el ultimo...

  7. AMoRE: Collaboration for searches for the neutrinoless double-beta decay of the isotope of {sup 100}Mo with the aid of {sup 40}Ca{sup 100}MoO{sub 4} as a cryogenic scintillation detector

    SciTech Connect (OSTI)

    Khanbekov, N. D., E-mail: xanbekov@gmail.com [Institute of Theoretical and Experimental Physics (Russian Federation)

    2013-09-15

    The AMoRE (Advanced Mo based Rare process Experiment) Collaboration is planning to employ {sup 40}Ca{sup 100}MoO{sub 4} single crystals as a cryogenic Scintillation detector for studying the neutrinoless double-beta decay of the isotope {sup 100}Mo. A simultaneous readout of phonon and scintillation signals is performed in order to suppress the intrinsic background. The planned sensitivity of the experiment that would employ 100 kg of {sup 40}Ca{sup 100}MoO{sub 4} over five years of data accumulation would be T{sub 1/2}{sup 0{nu}} = 3 Multiplication-Sign 10{sup 26} yr, which corresponds to values of the effective Majorana neutrino mass in the range of Left-Pointing-Angle-Bracket m{sub {nu}} Right-Pointing-Angle-Bracket {approx} 0.02-0.06 eV.

  8. U.S. Department of Energy and NTI Announce Key Nonproliferation Project

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LIST OF APPLICABLEStatutory AuthorityTrackCharterperformofDiscussionDesignerswith

  9. HealtH ServiceS We provide CoNFideNTiAL mediCAL CAre ANd

    E-Print Network [OSTI]

    of common health concerns. - Respiratory infections (e.g., cough, asthma attacks) - Injuries (e.g., sprains

  10. La realidad existencial y 'la realidad creada' en Pirandello y Salvador Novo

    E-Print Network [OSTI]

    Kuehne, Alyce de

    1968-10-01

    la palabra "Amor," cual proyectil disparado para combatir la amenaza atómica. Sempronio: . . . Repítasela [la palabra "Amor"] a los sabios esos que fabrican bombas y a los brazos que las arrojan. ¡Amor! Todos: Amor! . . . ¡Amor! ¡Amor! ¡Amor! (p... la palabra "Amor," cual proyectil disparado para combatir la amenaza atómica. Sempronio: . . . Repítasela [la palabra "Amor"] a los sabios esos que fabrican bombas y a los brazos que las arrojan. ¡Amor! Todos: Amor! . . . ¡Amor! ¡Amor! ¡Amor! (p...

  11. El amor en la poesia de Ernesto Cardenal 

    E-Print Network [OSTI]

    Lorenzo, Mary Cooley

    1995-01-01

    , God, oppression, the revolution and the cosmos. In this chapter the theme of unrequited love is emphasized as a symbol to show that Cardenal has not yet found his object of love. Another important symbol is renewal (or evolution) that represents...

  12. Automated classification of A/E/C web content R. Amor & K. Xu

    E-Print Network [OSTI]

    Amor, Robert

    purely on the search terms entered by the user. This means that the web pages which are found are often search en- gine. The premise behind this approach is that it is possible to accurately identify then a user searching for content in a particular area (e.g. by specifying a classification code

  13. How Can You Improve Overall Air Quality in Your Home?

    E-Print Network [OSTI]

    Liskiewicz, Maciej

    . · Allergicreactionscanincludearunnyorstuffynose, coughing,puffyeyes,itching,hives,orarash.Amore seriousreactioncouldbeanasthmaattackorswellingof

  14. State-of-the-Art of Social Media Analytics Research

    SciTech Connect (OSTI)

    Gastelum, Zoe N.; Whattam, Kevin M.

    2013-01-01

    Overview of current state-of-the-art of social media for NTI Working Group III: Societal Verification

  15. Why Do Zebras Have Stripes? New Study Offers Strong Evidence1 by Christine Dell'Amore of National Geographic2

    E-Print Network [OSTI]

    South Bohemia, University of

    played all of these theories against each other in a statistical model--and the7 result was pretty much was then entered into a statistical model to find out which variable best explains striping. The results showed Communications.21 22 Not the Last Word?23 Brenda Larison, a biologist at the University of California, Los

  16. “Non ci sono risposte compagno Gramsci... non ancora alle tue domande.” Soggettività e differenza sessuale: un dialogo tra Adele Cambria e Antonio Gramsci

    E-Print Network [OSTI]

    Righi, Andrea

    2008-01-01

    della piena espansione vitale insomma dell'amore romanticoliberata." '' di relazione vitale femminista matura dicevamo

  17. Son decenas y estn por toda Amrica Latina. Tienen en comn su amor por la ciencia y una curiosidad del tamao

    E-Print Network [OSTI]

    Barbosa, Marcia C. B.

    entendimiento de cómo ocurren los terremotos y también cómo se repliegan las proteínas, un proceso clave en el

  18. High-Tech Energy "Oasis" to Bloom in the Desert?1 by Christine Dell'Amore for www.nationalgeographic.com2

    E-Print Network [OSTI]

    South Bohemia, University of

    technologies designed to bring green4 living to the desert. The planned research center is part of the Sahara to build in deserts around the globe. Experts are now examining arid sites in Australia, the U and seawater make fresh water for growing crops, solar energy would be collected to generate power, and algae

  19. Employment Discrimination Based on Sexual Orientation and Gender Identity in Florida

    E-Print Network [OSTI]

    Mallory, Christy; Sears, Brad

    2015-01-01

    also HB 239 – Prohibited Discrimination, Florida House ofBill); SB 348 – Prohibited Discrimination, Florida House ofO RIENTATION A NTI - DISCRIMINATION P OLICIES ON THE W AGES

  20. Employment Discrimination Based on Sexual Orientation and Gender Identity in Arkansas

    E-Print Network [OSTI]

    Mallory, Christy; Sears, Brad

    2015-01-01

    Pine Bluff, Non-Discrimination Policy, http://www.uapb.edu/O RIENTATION A NTI - DISCRIMINATION P OLICIES ON THE W AGESand Gender Identity Discrimination 1998-2008, 84 C HI . -K

  1. Employment Discrimination Based on Sexual Orientation and Gender Identity in Oklahoma

    E-Print Network [OSTI]

    Mallory, Christy; Sears, Brad

    2015-01-01

    tit. 25, § 1307 (the non-discrimination requirements also doO RIENTATION A NTI - DISCRIMINATION P OLICIES ON THE W AGESand Gender Identity Discrimination 1998-2008, 84 C HI . -K

  2. Employment Discrimination Based on Sexual Orientation and Gender Identity in Wyoming

    E-Print Network [OSTI]

    Mallory, Christy; Sears, Brad

    2015-01-01

    senate-defeats-gay-discrimination- bill/article_fe8fef74-uploads/Sears-Mallory-Discrimination-July- 20111.pdf. J AMIEO RIENTATION A NTI - DISCRIMINATION P OLICIES ON THE W AGES

  3. CROSS-REACTIVE PROPERTIES OF ANTISERA PREPARED IN RABBITS BY STIMULATIONS WITH TELEOST VITELLINS

    E-Print Network [OSTI]

    of more taxonomically advanced species than more primitive species is indicated by the results by blend- ing and centrifuging one part eggs with three 203 #12;TADLE I.-A nti.~crn used in this study 2

  4. The Price of Texas Farm and Ranch Lands 1920-1945. 

    E-Print Network [OSTI]

    Crockett, Samuel L.; Southern, John H. (John Hoyle); Motheral, Joe R. (Joe Rankin)

    1947-01-01

    Feld-crop cot~nties. combined by qnarters. 1934-45 Combined quarterly totals First Counties quarter Jeff Davis. . . . . . . 20 14 BULLETIN NO. 688. TEXAS AGRICULTURAL EXPERIMENT STATION becomes relatively static, when the stock is marketed. Range...

  5. Ecosofía, tecnología y ludismo: una perspectiva ecocrítica al estudio de La raza cósmica, Doña Bárbara, Cien años de soledad, El hablador y Mantra

    E-Print Network [OSTI]

    FLORES, WILLIAMS

    2010-01-01

    el tema de la contaminación ambiental que sufre la capitalanencefálicos y la contaminación ambiental producida por lasel amor, la contaminación ambiental y elementos culturales

  6. Integer Solutions to Cutting Stock Problems

    E-Print Network [OSTI]

    2010-10-04

    This work has been partially supported by the Spanish Ministry of Science and Innovation under grant. No. MTM2008 ? 04206. References. [1] H. Ben Amor and

  7. ANDY: A general, fault-tolerant tool for database searching oncomputer...

    Office of Scientific and Technical Information (OSTI)

    data and figures and amore detailed overview of thesoftware. Authors: Smith, Andrew ; Chandonia, John-Marc ; Brenner, Steven E. Publication Date: 2005-12-21 OSTI...

  8. Master of Business Administration Graduate Business Program

    E-Print Network [OSTI]

    Sridhar, Srinivas

    saw when I decided to join Northeastern in July 2012. Our business school model ­ with its focusMaster of Business Administration Online Graduate Business Program #12;Message from the Dean 1'Amore-McKim School of Business 17 #12;It is my honor and pleasure to welcome you to the D'Amore-McKim School

  9. PA Regional Nanotechnology Conference Collaborating in Today's Economy

    E-Print Network [OSTI]

    Gilchrist, James F.

    4/23/2009 Present PA Regional Nanotechnology Conference Collaborating in Today's Economy May 27 of green technologies and alternative energy. The PA Initiative for Nanotechnology (PIN), established organizations - Drexel University's DNI, the LNN of Lehigh University, and The Nanotechnology Institute (NTI

  10. The Phonetics and Phonology of San Martín Itunyoso Trique

    E-Print Network [OSTI]

    DiCanio, Christian T

    2008-01-01

    Additionally, the word ‘nopal cactus’ in Itunyoso Trique, [1 mã 3 bug N=5 ti 3 ni 32 nopal cactus N=50 ka 2 mi 32 car Nti 3 ni 32 nã 3 see.1sg nopal here ‘I see a nopal (cactus)

  11. Khesbn no. 79-80 - April 1975 - Journal

    E-Print Network [OSTI]

    Admin, LAYCC

    1975-01-01

    p>teaag pD ngDpX-Tyi n»Ti VgB 1D PX g"T,/ /Pgr tpgT pa px /fopgnìyaovlg; px oy ya^yv ps : VgB f Iìx oiya^w sn^T » y^x

  12. Surgically Implanted JSATS Micro-Acoustic Transmitters Effects on Juvenile Chinook Salmon and Steelhead Tag Expulsion and Survival, 2010

    SciTech Connect (OSTI)

    Woodley, Christa M.; Carpenter, Scott M.; Carter, Kathleen M.; Wagner, Katie A.; Royer, Ida M.; Knox, Kasey M.; Kim, Jin A.; Gay, Marybeth E.; Weiland, Mark A.; Brown, Richard S.

    2011-09-16

    The purpose of this study was to evaluate survival model assumptions associated with a concurrent study - Acoustic Telemetry Evaluation of Dam Passage Survival and Associated Metrics at John Day, The Dalles, and Bonneville Dams, 2010 by Thomas Carlson and others in 2010 - in which the Juvenile Salmonid Acoustic Telemetry System (JSATS) was used to estimate the survival of yearling and subyearling Chinook salmon (Oncorhynchus tshawytscha) and steelhead (O. mykiss) migrating through the Federal Columbia River Power System (FCRPS). The micro-acoustic transmitter used in these studies is the smallest acoustic transmitter model to date (12 mm long x 5 mm wide x 4 mm high, and weighing 0.43 g in air). This study and the 2010 study by Carlson and others were conducted by researchers from the Pacific Northwest National Laboratory and the University of Washington for the U.S. Army Corps of Engineers, Portland District, to meet requirements set forth by the 2008 FCRPS Biological Opinion. In 2010, we compared survival, tag burden, and tag expulsion in five spring groups of yearling Chinook salmon (YCH) and steelhead (STH) and five summer groups of subyearling Chinook salmon (SYC) to evaluate survival model assumptions described in the concurrent study. Each tagging group consisted of approximately 120 fish/species, which were collected and implanted on a weekly basis, yielding approximately 600 fish total/species. YCH and STH were collected and implanted from late April to late May (5 weeks) and SYC were collected and implanted from mid-June to mid-July (5 weeks) at the John Day Dam Smolt Monitoring Facility. The fish were collected once a week, separated by species, and assigned to one of three treatment groups: (1) Control (no surgical treatment), (2) Sham (surgical implantation of only a passive integrated transponder [PIT] tag), and (3) Tagged (surgical implantation of JSATS micro-acoustic transmitter [AT] and PIT tags). The test fish were held for 30 days in indoor circular tanks at the Bonneville Dam Juvenile Monitoring Facility. Overall mortality ranged weekly from 45 to 72% for YCH, 55 to 83% for STH, and 56 to 84% for SYC. The high background mortality in all groups and species made it difficult to discern tag effects. However, for YCH, STH, and SYC, the Tagged treatment groups had the highest overall mean mortality - 62%, 79%, and 76%, respectively. Fungal infections were found on 35% of all fish. Mean tag burden for the Tagged treatment group was relatively low for YCH (1.7%) and moderate for SYC (4.2%), while STH had a very low mean tag burden (0.7%). Tag burden was significantly higher in the Tagged treatment group for all species when compared to the Sham treatment group because of the presence of two tags. Surgeon performance did not contribute to the difference in mortality between the Sham and Tagged treatment groups. Tag expulsion from fish that survived to the end of the 30-day experiment was low but occurred in all species, with only two PIT tags and one AT lost, one tag per species. The high background mortality in this experiment was not limited to a treatment, temperature, or month. The decreased number of surviving fish influenced our experimental results and thus analyses. For future research, we recommend that a more natural exposure to monitor tag effects and other factors, such as swimming ability and predator avoidance, be considered to determine the effects of AT- and PIT- implantation on fishes.

  13. Being Blue in Hawai‘i: Politics, Affect, and the Last Queen of Hawai‘i

    E-Print Network [OSTI]

    Harvey, Bruce

    2011-01-01

    Being Blue in Hawai‘i: Politics, Affect, and the Last Queenmore primarily violated. To be blue in Hawai‘i is to be in amore subtle nuances of being blue in Hawai‘i. Yet also in

  14. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    components of the eigenstates turn out to be very strong and described by the Random Matrix Theory. Clearly, if this happens in a quantum computer, it may lead to amore...

  15. A Preliminary Structural Model for the Blue Mountain Geothermal...

    Open Energy Info (EERE)

    thewest flanks of Blue Mountain and the Eugene Mountains, and amore local WNW-striking, SW-dipping normal-dextral fault onthe southwest side of Blue Mountain. The WNW-striking...

  16. The Crafting of the National Low-Emission Vehicle Program: a Private Contract Theory of Public Rulemaking

    E-Print Network [OSTI]

    Fern, Danielle F.

    1997-01-01

    enforcing its own motor vehicle emission standards. 2 5 Sec-standards for motor vehicle emissions; 90 section 301(a)more stringent motor vehicle emissions standards until the

  17. Obituary: Omar Grasso, una pasión teatral

    E-Print Network [OSTI]

    Bogado, Ví ctor

    2002-04-01

    verdades absolutas, de segregación de razas, de elecciones afectivas.... Épocas sin diálogos, sin oídos, cargadas de odio, de resentimiento y del morboso amor a la muerte.... Cada mujer, cada hombre deberá tener la energía, la lucidez y la alegría de un... verdades absolutas, de segregación de razas, de elecciones afectivas.... Épocas sin diálogos, sin oídos, cargadas de odio, de resentimiento y del morboso amor a la muerte.... Cada mujer, cada hombre deberá tener la energía, la lucidez y la alegría de un...

  18. Thermal Performance and Reliability Characterization of Bonded Interface Materials (BIMs): Preprint

    SciTech Connect (OSTI)

    DeVoto, D.; Paret, P.; Mihalic, M.; Narumanchi, S.; Bar-Cohen, A.; Matin, K.

    2014-08-01

    Thermal interface materials are an important enabler for low thermal resistance and reliable electronics packaging for a wide array of applications. There is a trend towards bonded interface materials (BIMs) because of their potential for low thermal resistivity (< 1 mm2K/W). However, BIMs induce thermomechanical stresses in the package and can be prone to failures and integrity risks. Deteriorated interfaces can result in high thermal resistance in the package and degradation and/or failure of the electronics. DARPA's Thermal Management Technologies program has addressed this challenge, supporting the development of mechanically-compliant, low resistivity nano-thermal interface (NTI) materials. In this work, we describe the testing procedure and report the results of NREL's thermal performance and reliability characterization of an initial sample of four different NTI-BIMs.

  19. Grain Sorghum Date-of-Planting and Spacing Experiments. 

    E-Print Network [OSTI]

    Karper, R. E. (Robert Earl); Quinby, J. R.; Jones, D. L.; Dickson, R. E.

    1931-01-01

    tation ii' loc?at 'rl in th astern part of Hardeman Co11nty, fi\\t? and n -hnlf mil e.~ ' < u h\\\\? ~t of hilli oth, about midway IH ?I.wc ?Pn t h" ]{pd an

  20. José González Dávila: Réquiem por un amigo que inicia su leyenda

    E-Print Network [OSTI]

    Mijares, Enrique

    2000-10-01

    ; revisó y puso al corriente nuevas versiones de las liminales Noche de bandidos y Los gatos; concluyó Son amores y Quién baila mambo; y un buen día, tal vez fatigado de luchar contra la corriente, se retiró del mundanal ruido dejando inconclusas en el...; revisó y puso al corriente nuevas versiones de las liminales Noche de bandidos y Los gatos; concluyó Son amores y Quién baila mambo; y un buen día, tal vez fatigado de luchar contra la corriente, se retiró del mundanal ruido dejando inconclusas en el...

  1. The Flourishing of Hispanic Theatre in the Southwest, 1920-30's

    E-Print Network [OSTI]

    Kanellos, Nicolá s

    1982-10-01

    de los extras, Su excelencia el amor, México quiere paz (apropósito cómico-lírico), La maldita guerra (zarzuela), El Gran Visir, Loco amor, El proceso de Los Angeles, Las luces de Los Angeles, Los Angeles en pijama and Revista de radio 1934.... But his full-length dramas, Los emigrados and El sacrificio again dealt with the epic of Mexicans in California, the latter play with a 34 LATIN AMERICAN THEATRE REVIEW setting in 1846. Other dramas by Navarro are Cuando entraron los Dorados, Alma...

  2. Intensity modulated radiotherapy and 3D conformal radiotherapy for whole breast irradiation: a comparative dosimetric study and introduction of a novel qualitative index for plan evaluation, the normal tissue index

    SciTech Connect (OSTI)

    Yim, Jackie; Suttie, Clare; Bromley, Regina; Morgia, Marita; Lamoury, Gillian

    2015-09-15

    We report on a retrospective dosimetric study, comparing 3D conformal radiotherapy (3DCRT) and hybrid intensity modulated radiotherapy (hIMRT). We evaluated plans based on their planning target volume coverage, dose homogeneity, dose to organs at risk (OARs) and exposure of normal tissue to radiation. The Homogeneity Index (HI) was used to assess the dose homogeneity in the target region, and we describe a new index, the normal tissue index (NTI), to assess the dose in the normal tissue inside the tangent treatment portal. Plans were generated for 25 early-stage breast cancer patients, using a hIMRT technique. These were compared with the 3DCRT plans of the treatment previously received by the patients. Plan quality was evaluated using the HI, NTI and dose to OARs. The hIMRT technique was significantly more homogenous than the 3DCRT technique, while maintaining target coverage. The hIMRT technique was also superior at minimising the amount of tissue receiving D{sub 105%} and above (P < 0.0001). The ipsilateral lung and contralateral breast maximum were significantly lower in the hIMRT plans (P < 0.05 and P < 0.005), but the 3DCRT technique achieved a lower mean heart dose in left-sided breast cancer patients (P < 0.05). Hybrid intensity modulated radiotherapy plans achieved improved dose homogeneity compared to the 3DCRT plans and superior outcome with regard to dose to normal tissues. We propose that the addition of both HI and NTI in evaluating the quality of intensity modulated radiotherapy (IMRT) breast plans provides clinically relevant comparators which more accurately reflect the new paradigm of treatment goals and outcomes in the era of breast IMRT.

  3. An improved shell of revolution element utilizing cubic displacement functions 

    E-Print Network [OSTI]

    Mebane, Paul Mitchell

    1970-01-01

    GZ Gt /12 ideni';y matrix; monent of inertia harmonic number number of P harmonics = stiffness matrix for an element constant factor ", or each harmonic stiffness matrix for an l. ment in shell coordinates meridional length of shell el ment... cannot be achi eved. 7 Fxclusion of a constant strain state may he due to the dis- placement function not being "complete". A compl te function may be thought of as an nt!i order polynomial . Functio, v!hich in- cludes all terms of the ord r n...

  4. Profits and Losses from On-farm Drying and Storage of Rice in Texas. 

    E-Print Network [OSTI]

    Sorenson, J.W. Jr.; Hildreth, R.J.

    1957-01-01

    of the average benefits from drying and storage, $2.17 per barrel, with the total cost of the most common type unit, a build- ing with an installed auger of 79 cents per barrel, indicates a profit of $1.38 per barrel from 1, ownership of the on-farm unit. A... over 3 years if average h~ni fits were obtained each year and all the I)~nti11, above cash cost were used to pay principal an:, interest on the loan. I A study of the operation of 29 on-farm dr!in. and storage units during the 1954-55 stora...

  5. YUNMO WANG | The Dragon's Curse?: Examining the Relationship between China's Participation in United Nations Peacekeeping Operations and its Economic Ties in Africa, 2000-2013

    E-Print Network [OSTI]

    McConnell, Terry

    and Human Migration at the U.S. ­ Mexico Border THOMAS J. TREE | Nuclear Proliferation Realities: IranVeReigNty iN the age of gloBalizatioN: the paRadox BetWeeN the moVemeNt of capital aNd humaN migRatioN at the u.S. ­ mexico BoRdeR thomaS J. tRee | NucleaR pRolifeRatioN RealitieS: iRaN, egypt, aNd Saudi aRaBia michael S

  6. Center for Nanophase Materials Sciences (CNMS) - Nanomaterials Theory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 OutreachProductswsicloudwsiclouddenDVA N C E D BGene Network Shaping of InherentInstitute (NTI): Computational

  7. Center for Nanophase Materials Sciences (CNMS) - Nanoscale Measurements of

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 OutreachProductswsicloudwsiclouddenDVA N C E D BGene Network Shaping of InherentInstitute (NTI):

  8. Center for Nanophase Materials Sciences (CNMS) - News

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 OutreachProductswsicloudwsiclouddenDVA N C E D BGene Network Shaping of InherentInstitute (NTI):

  9. Center for Nanophase Materials Sciences (CNMS) - News

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 OutreachProductswsicloudwsiclouddenDVA N C E D BGene Network Shaping of InherentInstitute (NTI):CNMS News Enhanced

  10. Center for Nanophase Materials Sciences (CNMS) - ORNL develops lignin-based

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 OutreachProductswsicloudwsiclouddenDVA N C E D BGene Network Shaping of InherentInstitute (NTI):CNMS News

  11. Center for Nanophase Materials Sciences (CNMS) - STM for Oxide Surfaces,

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 OutreachProductswsicloudwsiclouddenDVA N C E D BGene Network Shaping of InherentInstitute (NTI):CNMS NewsMolecular

  12. Center for Nanophase Materials Sciences (CNMS) - Selective deuteration

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 OutreachProductswsicloudwsiclouddenDVA N C E D BGene Network Shaping of InherentInstitute (NTI):CNMS

  13. Center for Nanophase Materials Sciences (CNMS) - Soft Condensed Matter

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 OutreachProductswsicloudwsiclouddenDVA N C E D BGene Network Shaping of InherentInstitute (NTI):CNMSDesign

  14. Center for Nanophase Materials Sciences (CNMS) - Soft matter synthesis

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 OutreachProductswsicloudwsiclouddenDVA N C E D BGene Network Shaping of InherentInstitute (NTI):CNMSDesignSoft

  15. 1.TIF

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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  16. 1.TIF

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home RoomPreservationBio-InspiredAtmosphericdevicesPPO Retirees with Medicare PlanCONTRACT^^'*1 ^^Nti ^

  17. 1.TIF

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home RoomPreservationBio-InspiredAtmosphericdevicesPPO Retirees with Medicare PlanCONTRACT^^'*1 ^^Nti

  18. WR279,396, a Third Generation Aminoglycoside Ointment for the Treatment of Leishmania major

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    . , Pierre A. Buffet2. , Gloria Morizot2 , Nathalie Ben Massoud1 , Amor Za^atour1 , Nissaf Ben Alaya1 , Nabil: Ben Salah A, Buffet PA, Morizot G, Ben Massoud N, Za^atour A, et al. (2009) WR279,396, a Third reports were submitted to the FDA. Competing Interests: Patent-Actual: As a member of the US Army, MG

  19. Lasing in Amorphous Nanophotonic Structures Hui Cao and Heeso Noh

    E-Print Network [OSTI]

    Cao, Hui

    structures--three-dimensional (3D) continu- ous random networks with diamond-like tetrahedral-bonding between the transition from PhCs to amor- phous optical materials, e.g., how does the density of optical states (DOS) evolve as the structural properties of the material change from ordered to amorphous? Is there a critical

  20. 1120 IEEE TRANSACTIONS ON ELECTRON DEVICES, VOL. 53, NO. 5, MAY 2006 Theory of Interface-Trap-Induced NBTI Degradation

    E-Print Network [OSTI]

    Alam, Muhammad A.

    mechanisms that generate traps at the Si-channel/gate-oxide interface of MOSFETs during transistor operation. The semiconductor/oxide interface is a rough surface where the highly ordered crystalline channel and the amor lead to poor device performance; therefore, the transistors are annealed in hydrogen ambient during

  1. The MERLin Modelling Environment for Regular Languages

    E-Print Network [OSTI]

    van Zijl, Lynette

    packages available, such as AMORE [1], the FireEngine [19], Fadela [16] and Grail [15]. We chose to design the MERLin system around Grail for various reasons, the most important being its eÆcient memory usage and its, and an integral part of the design of the system is therefore the ability for parallel processing. We ported Grail

  2. Biogeosciences, 11, 44774491, 2014 www.biogeosciences.net/11/4477/2014/

    E-Print Network [OSTI]

    carbon (SOC) pool size vari- ation), while energy limited microbial activity in the amor- phous horizon- perature alleviated the energy constraint of microbial activity most notably in amorphous soils, whereas-4477-2014 © Author(s) 2014. CC Attribution 3.0 License. The implications of microbial and substrate limitation

  3. Franoise Berthoud1, Laurent Lefevre2, Marianne Parry3 -EcoInfo 1CNRS-LPMMC, Grenoble francoise.berthoud@grenoble.cnrs.fr

    E-Print Network [OSTI]

    Lefèvre, Laurent

    par usager Bonnes pratiques ans; 2; 2% 5 à 7 ans ; 55; 54% > 7 ans; 44; 44% ans; 10; 12% 5 à 7 cédé gratuitement : Un ordinateur de plus de 4 ans équipé (unité centrale, écran, clavier, souris et ans et totalement amor s, et sous certaines condi ons, de moins de cinq ans, pour les matériels dont l

  4. Optical Properties of Crystalline-Amorphous Core-Shell Silicon Nanowires

    E-Print Network [OSTI]

    Anantaram, M. P.

    higher absorption between wave- lengths of 400 and 800 nm compared to thin film amor- phous silicon.12 absorption of down to less than 2% at long wavelengths ( > 780 nm). These results indicate that our nanowires and creat- ing a p-n junction in high efficiency heterojunctions a-Si/ crystalline silicon solar cells.13

  5. Tesis Doctoral Sobre grafos intersecci on de arcos y

    E-Print Network [OSTI]

    Lin, Min Chih

    Tesis Doctoral Sobre grafos intersecci#19;on de arcos y cuerdas en un c#19;#16;rculo Guillermo A;#16;, que sigue viva dentro de mi coraz#19;on A Clau, mi gran amor, tambi#19;en responsable de esta tesis tesis. A Marisa, Jo~ao y Claudia, por su cuidadosa lectura del trabajo y sus valiosas sugerencias que

  6. Spherical deformation of compliant substrates with semiconductor device islands

    E-Print Network [OSTI]

    Suo, Zhigang

    is a function of the island structure, size, and substrate material properties. Although the substrate semiconductor device materials, such as amor- phous silicon and silicon nitride, are brittle and crack easily and thinning the substrate cannot be used to reduce the strain. Because inorganic semiconductor materials

  7. A simultaneous near-field and far-field viewer and its application in biomedical imaging

    E-Print Network [OSTI]

    Greenaway, Alan

    A simultaneous near-field and far-field viewer and its application in biomedical imaging R. Amor1 Institute of Pharmacy and Biomedical Sciences, University of Strathclyde, 161 Cathedral Street, Glasgow G4 0 Kingdom #12;Biomedical imaging at the Centre for Biophotonics · Confocal/widefield fluorescence microscopy

  8. About Raising Children (Spanish) 

    E-Print Network [OSTI]

    Warren, Judith L.

    2002-01-04

    significa establecer y adherirse a nor- mas de comportamiento. Despu?s del amor, los padres subrayan la importancia de dar direcci?n clara y hacer que los ni?os cumplan con las normas de conducta. Disciplina es una preparaci?n esencial para adaptarse al...

  9. Electric field gating with ionic liquids Rajiv Misra, Mitchell McCarthy, and Arthur F. Hebarda

    E-Print Network [OSTI]

    Hebard, Arthur F.

    of 104 for thin conducting InOx films. The areal capacitances and field effect mobilities noticeably dielectrics and show that a significant field-gate effect on thin films of amor- phous composite InOx can material is a non- porous continuous thin metal film such as low carrier density InOx,10 then excess charge

  10. Polymer Characterization and Optimization of Conditions for the Enhanced Bioproduction

    E-Print Network [OSTI]

    Daugulis, Andrew J.

    ARTICLE Polymer Characterization and Optimization of Conditions for the Enhanced Bioproduction. pastoris, prompting the development of a selection strategy for identifying sequestering polymers for use by amor- phous polymers is via absorption, not adsorption. Finally, we have adopted a common strategy used

  11. Matematicas II. Grupo B Grado en Optica y Optometria. Curso 2013/2014

    E-Print Network [OSTI]

    Hurtado, Ana

    ´idea del espacio. Tema 3. C´alculo diferencial e integral de funciones de varias variables. Tema 4. Curvas y campos vectoriales diferenciables. Tema 5. Estad´istica descriptiva en una variable. Tema 6://grados.ugr.es/optica/pages/infoacademica/guiasdocentes/matematicasii_201314 Bibliograf´ia 1. R. Amor, C. Aguilar y A. Morales, Estad´istica Descriptiva y C´alculo de

  12. Outfits - Company C - 21 

    E-Print Network [OSTI]

    Unknown

    2006-01-01

    , ' C44UL'Zl;, G '. :iii 'Z. (X. -' G. ' ! Z. i C. c';(. I I' "N '. I (: c'LANG /. 'I'hesis , Iubmitted tc the 'r'. d(" te chcol c. (he (c r1cultursl ond coh:. nic: I Collcre of fox. s 1n ~erti~l fut. ill;. , ent o. too reouire-, , ents I...'or the dec-ree of . (. "GI' ' d. i hD! I ISZ (I'I( (( . . ". )or su(, 1eot: cec n nti. r by , , ussoll i ~: c(nc. r /. . ;-rc. =c' ", ', -. . -. '. 'le ~ ecc '. c+ '-v ce . '. c bettor unde; st. indin- cf . . 'oi:ired clans i . 11 1? ~ oined 1!ic o...

  13. El teatro cubano para jóvenes: La apariencia y el mensaje

    E-Print Network [OSTI]

    Pozin, Mikhail

    1995-04-01

    comunista. Partiendo de este concepto, los autores de Tema para Verónica y Proyecto de amor no ven nada malo en mostrar a la gente urbana que trabaja en el campo ayudando a los campesinos. En Cuba se practica el uso del trabajo voluntario en gran escala... limitaciones, el espectador puede reconocer cierto realismo, verdadero en la representación de los protagonistas y de la vida diaria. Es notable en las obras la presencia de un compromiso ideológico. Pero dada la crisis de la economía cubana se advierte...

  14. René Marqués 1919-1979

    E-Print Network [OSTI]

    Gautier, Luis A.

    1979-04-01

    60 LATIN AMERICAN THEATRE REVIEW Rene Marqués 1919-1979 El dramaturgo puertorriqueño Rene Marqués murió el pasado mes de marzo en San Juan, Puerto Rico. Tenía cincuenta y nueve años de edad. Rene Marqués fué conocido principalmente por su teatro... representados en Europa y Estados Unidos. El tema central en la obra de Rene Marqués es su preocupación por el destino político de su país, así como el amor por la tierra, la cultura, y las tradiciones puertorriqueñas, que deben ser conservadas y preservadas...

  15. Latin American Theatre Review, Volume 33, Number 1: Book Reviews

    E-Print Network [OSTI]

    1999-10-01

    , por otro director del Cinema Novo, Nelson Pereira dos Santos, en 1962. Finalmente el traductor nos asegura, con cierta pequeña duda, que los otros doce dramas de su padre serán pronto publicados en inglés. Excelente trabajo de amor y dedicación el... be an outline for a playwriting course. In the second section, Schmidhuber describes his discovery of a new play by Sor Juana, La segunda Celestina. This section would be of particular interest to those who study Sor Juana and those who contemplate going...

  16. Gesture of defiance: an analysis of Edna St. Vincent Millay's A Few Figs From Thistles 

    E-Print Network [OSTI]

    Mackin, Janet Marie

    1967-01-01

    ranging in length from two lines to two pages, followed by four sonnets expressing the poet's unconventional ideas about love. A second edition, containing the same materials as the first, was printed in 11arch, 1921, "to supply the demand which SThe... was a woman who laughed at tradition and lived carelessly for the moment. That a woman should take love so light-heartedly was a novelty in 192G; and that sho should thirst for amorous adventure like a man was scandalous. As Harold Lewis Cook points...

  17. Festival Report: Festival Internacional de Teatro de La Paz (FITAZ)

    E-Print Network [OSTI]

    Muñ oz, Willy O.

    1999-10-01

    , hechos que humanizan a la personaje. El Grupo Galiano 108 de Cuba participó con La virgen triste, basada en los amores y sufrimientos de Juana Barrero, una de las figuras más excepcionales de las letras y artes cubanas del siglo XIX. El espectáculo... movimiento escénico basado en la danza y el salto son las técnicas utilizadas para dramatizar el sueño de una anciana de la comunidad, narración que culpa al karai, el hombre blanco, como el causante de la pérdida de una cultura ancestral. El Elenco del...

  18. Sadhana della divinita solitaria Yamantaka-Vajrabhairava - Traduzione e glossario della version cinese di Nenghai (Parte 2)

    E-Print Network [OSTI]

    Bianchi, Ester

    2006-01-01

    susseguono profondi sentimenti di amore e simpatia nei confronti delle cose del mondo, e che il dharmadhåtu è immutabile”. 15 “(La divinità) presenta trentaquattro mani e braccia, suddivise in diciassette braccia sulla destra e diciassette sulla sinistra. Le... . cit., p. 87, nota 74). 50 L’alabarda arpionata è descritta spesso nei testi come un vajra a punta unica (tib. rdo rje rtse gcig pa): “the single pointed vajra is the destroyer of failings (do?a T nyes pa) of body, speech and mind” (Vajrasiddha, citato...

  19. Colombia: Periplo Teatro

    E-Print Network [OSTI]

    King, Robert E.

    1996-04-01

    Universidad Libre de Cúcuta con Mi novia tiene dos novios de Alfonso Paso; la Escuela de Teatro de la Universidad de Antioquia con Penas sin importancia de Griselda Gámbaro; el grupo Yage de la Universidad de Pamplona con Diatriba de amor contra un hombre... mayoría de los participantes, pues todo esto sucedió, al mismo tiempo, en cinco lugares: el Teatro Zulima y el Auditorio de la UFPS en Cúcuta y en las vecinas pequeñas ciudades de Ocafía y Pamplona, y además en la ciudad venezolana de San Cristóbal, en...

  20. Trends in modeling Biomedical Complex Systems

    E-Print Network [OSTI]

    2009-10-15

    or if they are consequences of amore far-reaching metabolic derangement. A number of mar- kers of systemic inflammation, including C-reactive protein, are often increased, as are fibrinogen, interleukin 6 (IL-6), Tumor necrosis factor-alpha (TNFa) and others. Some have... cardiomyocytes by global mRNA amplification as well as quantification of mRNA levels in a panel of housekeeping and heart- specific genes increase in the old age compared to the young one [6]. The understanding of the aging process raises the question...

  1. Swift's beautiful nymphs: an attack on the pastoral female image 

    E-Print Network [OSTI]

    McClain, Richard Daniel

    1974-01-01

    . HYPOCRISY AKD SNIFT' S 'iiODERi~! LADY' THE PASTORAL Far'IAL IMAGE LAID TO REST BIBLIOGRAPHY VITA 4g 56 61 64 CHAPTER I S'iiIFT S SCATOLOGY AND ITS CRITICISli Jonathan Swift expressed his views concerning his own poetry in a letter to a friend... even amor. ' zcder. . cri ics Bona i e Bz tb in Dean "-wift char:es that hi ooetry lo cks poet'cal imagination and that "", o one can be a oet, with limitation such a Bwift pos essed. " vL he co"mentary in her book is general ard only a few poezs...

  2. Photoelectrochemical and photocatalytic properties of N + S co-doped TiO2 nanotube array films under visible light irradiation

    E-Print Network [OSTI]

    Yan, Guotian; Houa, Jian; Yang, Jianjun; 10.1016/j.matchemphys.2011.04.063

    2011-01-01

    In this paper, we report on the co-doping nitrogen and sulfur has been achieved in the TiO2 nanotube array films by treatment with thiourea and calcination under vacuum at 500 {\\deg}C for 3 h. The samples were characterized by scanning electron microscopy, X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and ultraviolet-visible diffuse reflectance spectroscopy. XPS spectra revealed that N might coexist in the forms of NTiO and NOTi, S was incorporated into the lattice of TiO2 through substituting oxygen atoms in the N + S co-doped TiO2 nanotube array films. XRD patterns indicated that improved crystallinity was obtained for N + S co-doped TiO2 nanotube arrays as compared to that of undoped TiO2 nanotube arrays. In photoelectrochemical measurements, the photocurrent of N + S co-doped TiO2 nanotube array films was greatly enhanced compared to that of undoped samples under visible light irradiation. And the photocatalytic activities of the samples were evaluated on the removal of methylene blue un...

  3. Fragile structural transition in Mo3Sb7

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yan, Jiaqiang -Q.; McGuire, Michael A; May, Andrew F; Parker, David S.; Mandrus, D. G.; Sales, Brian C.

    2015-08-10

    Mo3Sb7 single crystals lightly doped with Cr, Ru, or Te are studied in order to explore the interplay between superconductivity, magnetism, and the cubic-tetragonal structural transition. The structural transition at 53 K is extremely sensitive to Ru or Te substitution which introduces additional electrons, but robust against Cr substitution. We observed no sign of a structural transition in superconducting Mo2.91Ru0.09Sb7 and Mo3Sb6.975Te0.025. In contrast, 3 at.% Cr doping only slightly suppresses the structural transition to 48 K while leaving no trace of superconductivity above 1.8 K. Analysis of magnetic properties suggests that the interdimer interaction in Mo3Sb7 is near amore »critical value and essential for the structural transition. Futhermore, all dopants suppress the superconductivity of Mo3Sb7. The tetragonal structure is not necessary for superconductivity.« less

  4. Communication: Kinetics of scavenging of small, nucleating clusters: First nucleation theorem and sum rules

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Malila, Jussi; McGraw, Robert; Laaksonen, Ari; Lehtinen, Kari E. J.

    2015-01-07

    Despite recent advances in monitoring nucleation from a vapor at close-to-molecular resolution, the identity of the critical cluster, forming the bottleneck for the nucleation process, remains elusive. During past twenty years, the first nucleation theorem has been often used to extract the size of the critical cluster from nucleation rate measurements. However, derivations of the first nucleation theorem invoke certain questionable assumptions that may fail, e.g., in the case of atmospheric new particle formation, including absence of subcritical cluster losses and heterogeneous nucleation on pre-existing nanoparticles. Here we extend the kinetic derivation of the first nucleation theorem to give amore »general framework to include such processes, yielding sum rules connecting the size dependent particle formation and loss rates to the corresponding loss-free nucleation rate and the apparent critical size from a naïve application of the first nucleation theorem that neglects them.« less

  5. Single spin asymmetries of inclusive hadrons produced in electron scattering from a transversely polarized 3 He target

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Allada, K.; Zhao, Y. X.; Aniol, K.; Annand, J. R. M.; Averett, T.; Benmokhtar, F.; Bertozzi, W.; Bradshaw, P. C.; Bosted, P.; Camsonne, A.; et al

    2014-04-07

    We report the first measurement of target single-spin asymmetries (AN) in the inclusive hadron production reaction, e + 3He??h+X, using a transversely polarized 3 He target. This experiment was conducted at Jefferson Lab in Hall A using a 5.9-GeV electron beam. Three types of hadrons (?±, K± and proton) were detected in the transverse hadron momentum range 0.54 T F for pions was -0.29 FF+ and K+. Amore »negative asymmetry is observed for ?–. The magnitudes of the asymmetries follow |A? –|? +|K +|. The K– and proton asymmetries are consistent with zero within the experimental uncertainties. The ?+ and ?– asymmetries measured for the 3He target and extracted for neutrons are opposite in sign with a small increase observed as a function of pT.« less

  6. Technique for fabrication of ultrathin foils in cylindrical geometry for liner-plasma implosion experiments with sub-megaampere currents

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yager-Elorriaga, D. A.; Steiner, A. M.; Patel, S. G.; Jordan, N. M.; Lau, Y. Y.; Gilgenbach, R. M.

    2015-11-19

    In this study, we describe a technique for fabricating ultrathin foils in cylindrical geometry for liner-plasma implosion experiments using sub-MA currents. Liners are formed by wrapping a 400 nm, rectangular strip of aluminum foil around a dumbbell-shaped support structure with a non-conducting center rod, so that the liner dimensions are 1 cm in height, 6.55 mm in diameter, and 400 nm in thickness. The liner-plasmas are imploded by discharging ~600 kA with ~200 ns rise time using a 1 MA linear transformer driver, and the resulting implosions are imaged four times per shot using laser-shadowgraphy at 532 nm. As amore »result, this technique enables the study of plasma implosion physics, including the magneto Rayleigh-Taylor, sausage, and kink instabilities on initially solid, imploding metallic liners with university-scale pulsed power machines.« less

  7. Following the dynamics of matter with femtosecond precision using the X-ray streaking method

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    David, C.; Karvinen, P.; Sikorski, M.; Song, S.; Vartiainen, I.; Milne, C. J.; Mozzanica, A.; Kayser, Y.; Diaz, A.; Mohacsi, I.; et al

    2015-01-06

    X-ray Free Electron Lasers (FELs) can produce extremely intense and very short pulses, down to below 10 femtoseconds (fs). Among the key applications are ultrafast time-resolved studies of dynamics of matter by observing responses to fast excitation pulses in a pump-probe manner. Detectors with sufficient time resolution for observing these processes are not available. Therefore, such experiments typically measure a sample's full dynamics by repeating multiple pump-probe cycles at different delay times. This conventional method assumes that the sample returns to an identical or very similar state after each cycle. Here we describe a novel approach that can provide amore »time trace of responses following a single excitation pulse, jitter-free, with fs timing precision. We demonstrate, in an X-ray diffraction experiment, how it can be applied to the investigation of ultrafast irreversible processes.« less

  8. Next-to-leading order QCD predictions for top-quark pair production with up to two jets merged with a parton shower

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Höche, Stefan; Krauss, Frank; Maierhöfer, Philipp; Pozzorini, Stefano; Schönherr, Marek; Siegert, Frank

    2015-09-01

    We present differential cross sections for the production of top-quark pairs in conjunction with up to two jets, computed at next-to-leading order in perturbative QCD and consistently merged with a parton shower in the Sherpa+OpenLoops framework. Top quark decays including spin correlation effects are taken into account at leading order accuracy. The calculation yields a unified description of top-pair plus multi-jet production, and detailed results are presented for various key observables at the Large Hadron Collider. A large improvement with respect to the multi-jet merging approach at leading order is found for the total transverse energy spectrum, which plays amore »prominent role in searches for physics beyond the Standard Model.« less

  9. Resonant spin tunneling in randomly oriented nanospheres of Mn?? acetate

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lendinez, S.; Billinge, S. J. L.; Zarzuela, R.; Tejada, J.; Terban, M. W.; Espin, J.; Imaz, I.; Maspoch, D.; Chudnovsky, E. M.

    2015-01-06

    We report measurements and theoretical analysis of resonant spin tunneling in randomly oriented nanospheres of a molecular magnet. Amorphous nanospheres of Mn?? acetate have been fabricated and characterized by chemical, infrared, TEM, X-ray, and magnetic methods. Magnetic measurements have revealed sharp tunneling peaks in the field derivative of the magnetization that occur at the typical resonant field values for the Mn?? acetate crystal in the field parallel to the easy axis.Theoretical analysis is provided that explains these observations. We argue that resonant spin tunneling in a molecular magnet can be established in a powder sample, without the need for amore »single crystal and without aligning the easy magnetization axes of the molecules. This is confirmed by re-analyzing the old data on a powdered sample of non-oriented micron-size crystals of Mn?? acetate. Our findings can greatly simplify the selection of candidates for quantum spin tunneling among newly synthesized molecular magnets.« less

  10. Revisiting benzene cluster cations for the chemical ionization of dimethyl sulfide and select volatile organic compounds

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kim, M. J.; Zoerb, M. C.; Campbell, N. R.; Zimmermann, K. J.; Blomquist, B. W.; Huebert, B. J.; Bertram, T. H.

    2015-10-01

    Benzene cluster cations were revisited as a sensitive and selective reagent ion for the chemical ionization of dimethyl sulfide (DMS) and a select group of volatile organic compounds (VOCs). Laboratory characterization was performed using both a new set of compounds (i.e. DMS, ?-caryophyllene) as well as previously studied VOCs (i.e., isoprene, ?-pinene). Using a field deployable chemical ionization time-of-flight mass spectrometer (CI-ToFMS), benzene cluster cations demonstrated high sensitivity (> 1 ncps ppt?1) to DMS, isoprene, and ?-pinene standards. Parallel measurements conducted using a chemical-ionization quadrupole mass spectrometer, with a weaker electric field, demonstrated that ion-molecule reactions likely proceed through amore »combination of ligand-switching and direct charge transfer mechanisms. Laboratory tests suggest that benzene cluster cations may be suitable for the selective ionization of sesquiterpenes, where minimal fragmentation (R2=0.80) over a wide range of sampling conditions.« less

  11. Single-shot hyperspectral coherent Raman planar imaging in the range 0–4200 cm?¹

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Bohlin, Alexis; Kliewer, Christopher J.

    2014-10-20

    We propose a technique for ultrabroadband planar coherent Raman spectroscopy that enables wideband chemically selective mapping of molecular partition functions in the gas-phase within a single-laser-shot. A spectral region spanning 0–4200 cm?¹ is excited simultaneously, in principle allowing for coherent planar imaging of most all fundamental Raman-active modes. This unique instantaneous and spatially correlated assessment enables multiplexed studies of transient dynamical systems in a two-dimensional (2D) field. Here, we demonstrate single-laser-shot high temperature diagnostics of H?, with spatially resolved 2D measurement of transitions of both the pure-rotational H? S-branch and the vibrational H? Q-branch, analyzing the temperature contour of amore »reacting fuel-species as it evolves at a flame-front.« less

  12. Measurement of ?(1S+2S+3S) production in p+p and Au+Au collisions at ?sNN=200 GeV

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Adare, A.

    2015-02-24

    Measurements of bottomonium production in heavy ion and p+p collisions at the Relativistic Heavy Ion Collider (RHIC) are presented. The inclusive yield of the three ? states, ?(1S + 2S + 3S), was measured in the PHENIX experiment via electron-positron decay pairs at midrapidity for Au+Au and p+p collisions at ?sNN = 200 GeV. The ?(1S + 2S + 3S) ? e?e? differential cross section at midrapidity was found to be Beed?/dy = 108 ± 38 (stat) ± 15 (syst) ± 11 (luminosity) pb in p+p collisions. The nuclear modification factor in the 30% most central Au+Au collisions indicates amore »suppression of the total ? state yield relative to the extrapolation from p+p collision data. The suppression is consistent with measurements at higher energies by the CMS experiment at the Large Hadron Collider.« less

  13. Theory of melting at high pressures: Amending density functional theory with quantum Monte Carlo

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Shulenburger, L.; Desjarlais, M. P.; Mattsson, T. R.

    2014-10-01

    We present an improved first-principles description of melting under pressure based on thermodynamic integration comparing Density Functional Theory (DFT) and quantum Monte Carlo (QMC) treatments of the system. The method is applied to address the longstanding discrepancy between density functional theory (DFT) calculations and diamond anvil cell (DAC) experiments on the melting curve of xenon, a noble gas solid where van der Waals binding is challenging for traditional DFT methods. The calculations show excellent agreement with data below 20 GPa and that the high-pressure melt curve is well described by a Lindemann behavior up to at least 80 GPa, amore »finding in stark contrast to DAC data.« less

  14. Four-flavour leading-order hadronic contribution to the muon anomalous magnetic moment

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Burger, Florian; Feng, Xu; Hotzel, Grit; Jansen, Karl; Univ. of Cyprus, Nicosia; Petschlies, Marcus; Renner, Dru B.

    2014-02-24

    We present a four-flavour lattice calculation of the leading-order hadronic vacuum polarisation contribution to the anomalous magnetic moment of the muon, a?hvp, arising from quark-connected Feynman graphs. It is based on ensembles featuring Nf=2+1+1 dynamical twisted mass fermions generated by the European Twisted Mass Collaboration (ETMC). Several light quark masses are used in order to yield a controlled extrapolation to the physical pion mass. We employ three lattice spacings to examine lattice artefacts and several different volumes to check for finite-size effects. Including the complete first two generations of quarks allows for a direct comparison with phenomenological determinations of amore »?hvp. The final result involving an estimate of the systematic uncertainty a?hvp=6.74 (21)(18) 10-8 shows a good overall agreement with these computations.« less

  15. Single Spin Asymmetries of Inclusive Hadrons Produced in Electron Scattering from a Transversely Polarized 3He Target

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Allada, Kalyan; Zhao, Yongxiang; Aniol, Konrad; Annand, John; Averett, Todd; Benmokhtar, Fatiha; Bertozzi, William; Bradshaw, Peter; Bosted, Peter; Camsonne, Alexandre; et al

    2014-04-01

    We report the first measurement of target single-spin asymmetries (AN) in the inclusive hadron production reaction, e + 3He??h+X, using a transversely polarized 3 He target. The experiment was conducted at Jefferson Lab in Hall A using a 5.9-GeV electron beam. Three types of hadrons (?±, K± and proton) were detected in the transverse hadron momentum range 0.54 T F for pions was -0.29 FF+ and K+. Amore »negative asymmetry is observed for ?–. The magnitudes of the asymmetries follow |A? –|? +|K +|. The K– and proton asymmetries are consistent with zero within the experimental uncertainties. The ?+ and ?– asymmetries measured for the 3He target and extracted for neutrons are opposite in sign with a small increase observed as a function of pT.« less

  16. Measurement of the production cross section ratio ?(?b2(1P)) / ?(?b1(1P)) in pp collisions at ?s = 8 TeV

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Khachatryan, Vardan

    2015-04-09

    A measurement of the production cross section ratio ?(?b2(1P)) / ?(?b1(1P)) is presented. The ?b1 (1P) and ?b2(1P) bottomonium states, promptly produced in pp collisions at ?s=8 TeV , are detected by the CMS experiment at the CERN LHC through their radiative decays ?b1,2(1P) ? ?(1S) + ? . The emitted photons are measured through their conversion to e?e? pairs, whose reconstruction allows the two states to be resolved. The ?(1S) is measured through its decay to two muons. An event sample corresponding to an integrated luminosity of 20.7 fb?¹ is used to measure the cross section ratio in amore »phase-space region defined by the photon pseudorapidity, |??| ?| T? ?b branching fractions.« less

  17. Demonstration of simultaneous experiments using thin crystal multiplexing at the Linac Coherent Light Source

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Feng, Y.; Alonso-Mori, R.; Barends, T. R. M.; Blank, V. D.; Botha, S.; Chollet, M.; Damiani, D. S.; Doak, R. B.; Glownia, J. M.; Koglin, J. M.; et al

    2015-04-10

    Multiplexing of the Linac Coherent Light Source beam was demonstrated for hard X-rays by spectral division using a near-perfect diamond thin-crystal monochromator operating in the Bragg geometry. The wavefront and coherence properties of both the reflected and transmitted beams were well preserved, thus allowing simultaneous measurements at two separate instruments. In this report, the structure determination of a prototypical protein was performed using serial femtosecond crystallography simultaneously with a femtosecond time-resolved XANES studies of photoexcited spin transition dynamics in an iron spin-crossover system. The results of both experiments using the multiplexed beams are similar to those obtained separately, using amore »dedicated beam, with no significant differences in quality.« less

  18. Stripe-like nanoscale structural phase separation in superconducting BaPb1-xBixO3

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Giraldo-Gallo, P.; Zhang, Y.; Parra, C.; Manoharan, H. C.; Beasley, M. R.; Geballe, T. H.; Kramer, M. J.; Fisher, I. R.

    2015-09-16

    The phase diagram of BaPb1-xBixO3 exhibits a superconducting “dome” in the proximity of a charge density wave phase. For the superconducting compositions, the material coexists as two structural polymorphs. Here we show, via high resolution transmission electron microscopy, that the structural dimorphism is accommodated in the form of partially disordered nanoscale stripes. Identification of the morphology of the nanoscale structural phase separation enables determination of the associated length scales, which we compare to the Ginzburg-Landau coherence length. Thus, we find that the maximum Tc occurs when the superconducting coherence length matches the width of the partially disordered stripes, implying amore »connection between the structural phase separation and the shape of the superconducting dome.« less

  19. Electric and Magnetic Response in Dielectric Dark States for Low Loss Subwavelength Optical Meta Atoms

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Jain, Aditya; Moitra, Parikshit; Koschny, Thomas; Valentine, Jason; Soukoulis, Costas M.

    2015-07-14

    Artificially created surfaces or metasurfaces, composed of appropriately shaped subwavelength structures, namely, meta-atoms, control light at subwavelength scales. Historically, metasurfaces have used radiating metallic resonators as subwavelength inclusions. However, while resonant optical metasurfaces made from metal have been sufficiently subwavelength in the propagation direction, they are too lossy for many applications. Metasurfaces made out of radiating dielectric resonators have been proposed to solve the loss problem, but are marginally subwavelength at optical frequencies. We designed subwavelength resonators made out of nonradiating dielectrics. The resonators are decorated with appropriately placed scatterers, resulting in a meta-atom with an engineered electromagnetic response. Amore »metasurface that yields an electric response is fabricated, experimentally characterized, and a method to obtain a magnetic response at optical frequencies is theoretically demonstrated. This design methodology paves the way for metasurfaces that are simultaneously subwavelength and low loss.« less

  20. Multireference configuration interaction calculations of the first six ionization potentials of the uranium atom

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Bross, David H.; Parmar, Payal; Peterson, Kirk A.

    2015-11-12

    The first 6 ionization potentials (IPs) of the uranium atom have been calculated using multireference configuration interaction (MRCI+Q) with extrapolations to the complete basis set (CBS) limit using new all-electron correlation consistent basis sets. The latter were carried out with the third-order Douglas-Kroll-Hess Hamiltonian. Correlation down through the 5s5p5d electrons have been taken into account, as well as contributions to the IPs due to the Lamb shift. Spin-orbit coupling contributions calculated at the 4-component Kramers restricted configuration interaction level, as well as the Gaunt term computed at the Dirac-Hartree-Fock level, were added to the best scalar relativistic results. As amore »result, the final ionization potentials are expected to be accurate to at least 5 kcal/mol (0.2 eV), and thus more reliable than the current experimental values of IP3 through IP6.« less

  1. Chirality-selected phase behaviour in ionic polypeptide complexes

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Perry, Sarah L.; Leon, Lorraine; Hoffmann, Kyle Q.; Kade, Matthew J.; Priftis, Dimitrios; Black, Katie A.; Wong, Derek; Klein, Ryan A.; Pierce, III, Charles F.; Margossian, Khatcher O.; et al

    2015-01-14

    In this study, polyelectrolyte complexes present new opportunities for self-assembled soft matter. Factors determining whether the phase of the complex is solid or liquid remain unclear. Ionic polypeptides enable examination of the effects of stereochemistry on complex formation. Here we demonstrate that chirality determines the state of polyelectrolyte complexes, formed from mixing dilute solutions of oppositely charged polypeptides, via a combination of electrostatic and hydrogen-bonding interactions. Fluid complexes occur when at least one of the polypeptides in the mixture is racemic, which disrupts backbone hydrogen-bonding networks. Pairs of purely chiral polypeptides, of any sense, form compact, fibrillar solids with amore »?-sheet structure. Analogous behaviour occurs in micelles formed from polypeptide block copolymers with polyethylene oxide, where assembly into aggregates with either solid or fluid cores, and eventually into ordered phases at high concentrations, is possible. Chirality is an exploitable tool for manipulating material properties in polyelectrolyte complexation.« less

  2. Magnetic domain tuning and the emergence of bubble domains in the bilayer manganite La2–2xSr1+2xMn2O7(x=0.32)

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Jeong, Juyoung; Yang, Ilkyu; Yang, Jinho; Ayala-Valenzuela, Oscar E.; Wulferding, Dirk; Zhou, J. -S.; Goodenough, John B.; de Lozanne, Alex; Mitchell, J. F.; Leon, Neliza; et al

    2015-08-17

    We report a magnetic force microscopy study of the magnetic domain evolution in the layered manganite La2-2xSr1+2xMn2O7 (with x=0.32). This strongly correlated electron compound is known to exhibit a wide range of magnetic phases, including a recently uncovered biskyrmion phase. We observe a continuous transition from dendritic to stripelike domains, followed by the formation of magnetic bubbles due to a field- and temperature-dependent competition between in-plane and out-of-plane spin alignments. The magnetic bubble phase appears at comparable field and temperature ranges as the biskyrmion phase, suggesting a close relation between both phases. Based on our real-space images we construct amore »temperature-field phase diagram for this composition.« less

  3. Resonant excitation of coupled Rayleigh waves in a short and narrow fluid channel clad between two identical metal plates

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    García-Chocano, Victor M.; López-Rios, Tomás; Krokhin, Arkadii; Sanchez-Dehesa, Jose

    2011-12-23

    Transmission of ultrasonic waves through a slit between two water immersed brass plates is studied for sub-wavelength plate thicknesses and slit apertures. Extraordinary high absorption is observed at discrete frequencies corresponding to resonant excitation of Rayleigh waves on the both sides of the channel. The coupling of the Rayleigh waves occurs through the fluid and the corresponding contribution to the dispersion has been theoretically derived and also experimentally confirmed. Symmetric and anti-symmetric modes are predicted but only the symmetric mode resonances have been observed. It follows from the dispersion equation that the coupled Rayleigh waves cannot be excited in amore »channel with apertures less than the critical one. The calculated critical aperture is in a good agreement with the measured acoustic spectra. These findings could be applied to design a broadband absorptive metamaterial.« less

  4. Using Ecosystem Experiments to Improve Vegetation Models

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Medlyn, Belinda; Zaehle, S; DeKauwe, Martin G.; Walker, Anthony P.; Dietze, Michael; Hanson, Paul J.; Hickler, Thomas; Jain, Atul; Luo, Yiqi; Parton, William; et al

    2015-05-21

    Ecosystem responses to rising CO2 concentrations are a major source of uncertainty in climate change projections. Data from ecosystem-scale Free-Air CO2 Enrichment (FACE) experiments provide a unique opportunity to reduce this uncertainty. The recent FACE Model–Data Synthesis project aimed to use the information gathered in two forest FACE experiments to assess and improve land ecosystem models. A new 'assumption-centred' model intercomparison approach was used, in which participating models were evaluated against experimental data based on the ways in which they represent key ecological processes. Identifying and evaluating the main assumptions caused differences among models, and the assumption-centered approach produced amore »clear roadmap for reducing model uncertainty. We explain this approach and summarize the resulting research agenda. We encourage the application of this approach in other model intercomparison projects to fundamentally improve predictive understanding of the Earth system.« less

  5. Single to Multiquasiparticle Excitations in the Itinerant Helical Magnet CeRhIn5

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Stock, C.; Rodriguez-Rivera, J. A.; Schmalzl, K.; Rodriguez, E. E.; Stunault, A.; Petrovic, C.

    2015-06-19

    Neutron scattering is used to measure the quantum spin fluctuations in CeRhIn5 - the parent material of the eXIn5 superconducting series. Out-of-plane spin fluctuations are gapped and localized in momentum, similar to the spin excitons in CeCoIn5. The in-plane fluctuations consist of sharp spin-wave excitations parameterized by a nearest neighbor exchange JRKKY =0.88 ± 0.05 meV that crossover to a temporally and spatially broad multiparticle spectrum with energies of ~ 2 × JRKKY . This continuum represents composite fluctuations that illustrate the breakdown of single magnons originating from the delicate energy balance between localized 4f and itinerant behavior in amore »heavy metal. The experiment therefore shows how quasiparticle behavior is changed by the close proximity of quantum criticality.« less

  6. Characterization and use of the spent beam for serial operation of LCLS

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Boutet, Sébastien; Foucar, Lutz; Barends, Thomas R. M.; Botha, Sabine; Doak, R. Bruce; Koglin, Jason E.; Messerschmidt, Marc; Nass, Karol; Schlichting, Ilme; Seibert, M. Marvin; et al

    2015-04-11

    X-ray free-electron laser sources such as the Linac Coherent Light Source offer very exciting possibilities for unique research. However, beam time at such facilities is very limited and in high demand. This has led to significant efforts towards beam multiplexing of various forms. One such effort involves re-using the so-called spent beam that passes through the hole in an area detector after a weak interaction with a primary sample. This beam can be refocused into a secondary interaction region and used for a second, independent experiment operating in series. The beam profile of this refocused beam was characterized for amore »particular experimental geometry at the Coherent X-ray Imaging instrument at LCLS. A demonstration of this multiplexing capability was performed with two simultaneous serial femtosecond crystallography experiments, both yielding interpretable data of sufficient quality to produce electron density maps.« less

  7. Forward Compton scattering with weak neutral current: Constraints from sum rules

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Gorchtein, Mikhail; Zhang, Xilin

    2015-07-01

    We generalize forward real Compton amplitude to the case of the interference of the electromagnetic and weak neutral current, formulate a low-energy theorem, relate the new amplitudes to the interference structure functions and obtain a new set of sum rules. We address a possible new sum rule that relates the product of the axial charge and magnetic moment of the nucleon to the 0th moment of the structure function g?(?0). For the dispersive ? ?-box correction to the proton's weak charge, the application of the GDH sum rule allows us to reduce the uncertainty due to resonance contributions by amore »factor of two. The finite energy sum rule helps addressing the uncertainty in that calculation due to possible duality violations.« less

  8. Gutzwiller charge phase diagram of cuprates, including electron–phonon coupling effects

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Markiewicz, R. S.; Seibold, G.; Lorenzana, J.; Bansil, A.

    2015-02-01

    Besides significant electronic correlations, high-temperature superconductors also show a strong coupling of electrons to a number of lattice modes. Combined with the experimental detection of electronic inhomogeneities and ordering phenomena in many high-Tc compounds, these features raise the question as to what extent phonons are involved in the associated instabilities. Here we address this problem based on the Hubbard model including a coupling to phonons in order to capture several salient features of the phase diagram of hole-doped cuprates. Charge degrees of freedom, which are suppressed by the large Hubbard U near half-filling, are found to become active at amore »fairly low doping level. We find that possible charge order is mainly driven by Fermi surface nesting, with competition between a near-(?, ?) order at low doping and antinodal nesting at higher doping, very similar to the momentum structure of magnetic fluctuations. The resulting nesting vectors are generally consistent with photoemission and tunneling observations, evidence for charge density wave order in YBa?Cu?O7-? including Kohn anomalies, and suggestions of competition between one- and two-q-vector nesting.« less

  9. Evaluation of partial coherence correction in X-ray ptychography

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Burdet, Nicolas; Shi, Xiaowen; Parks, Daniel; Clark, Jesse N.; Huang, Xiaojing; Kevan, Stephen D.; Robinson, Ian K.

    2015-02-23

    Coherent X-ray Diffraction Imaging (CDI) and X-ray ptychography both heavily rely on the high degree of spatial coherence of the X-ray illumination for sufficient experimental data quality for reconstruction convergence. Nevertheless, the majority of the available synchrotron undulator sources have a limited degree of partial coherence, leading to reduced data quality and a lower speckle contrast in the coherent diffraction patterns. It is still an open question whether experimentalists should compromise the coherence properties of an X-ray source in exchange for a higher flux density at a sample, especially when some materials of scientific interest are relatively weak scatterers. Amore »previous study has suggested that in CDI, the best strategy for the study of strong phase objects is to maintain a high degree of coherence of the illuminating X-rays because of the broadening of solution space resulting from the strong phase structures. In this article, we demonstrate the first systematic analysis of the effectiveness of partial coherence correction in ptychography as a function of the coherence properties, degree of complexity of illumination (degree of phase diversity of the probe) and sample phase complexity. We have also performed analysis of how well ptychographic algorithms refine X-ray probe and complex coherence functions when those variables are unknown at the start of reconstructions, for noise-free simulated data, in the case of both real-valued and highly-complex objects.« less

  10. Top quark mass measurement using the template method at CDF

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Aaltonen, T

    2011-06-03

    We present a measurement of the top quark mass in the lepton+jets and dilepton channels of t$\\bar{t}$ decays using the template method. The data sample corresponds to an integrated luminosity of 5.6 fb-1 of p$\\bar{p}$ collisions at Tevatron with ?s = 1.96 TeV, collected with the CDF II detector. The measurement is performed by constructing templates of three kinematic variables in the lepton+jets and two kinematic variables in the dilepton channel. The variables are two reconstructed top quark masses from different jets-to-quarks combinations and the invariant mass of two jets from the W decay in the lepton+jets channel, and amore »reconstructed top quark mass and mT2, a variable related to the transverse mass in events with two missing particles, in the dilepton channel. The simultaneous fit of the templates from signal and background events in the lepton+jets and dilepton channels to the data yields a measured top quark mass of Mtop = 172.1±1.1 (stat)±0.9 (syst) GeV/c2.« less

  11. FlaF is a ?-sandwich protein that anchors the archaellum in the archaeal cell envelope by binding the S-layer protein

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Banerjee, Ankan; Tsai, Chi -Lin; Chaudhury, Paushali; Tripp, Patrick; Arvai, Andrew  S.; Ishida, Justin  P.; Tainer, John  A.; Albers, Sonja -Verena

    2015-05-01

    Archaea employ the archaellum, a type IV pilus-like nanomachine, for swimming motility. In the crenarchaeon Sulfolobus acidocaldarius, the archaellum consists of seven proteins: FlaB/X/G/F/H/I/J. FlaF is conserved and essential for archaellum assembly but no FlaF structures exist. Here, we truncated the FlaF N terminus and solved 1.5-Å and 1.65-Å resolution crystal structures of this monotopic membrane protein. Structures revealed an N-terminal ?-helix and an eight-strand ?-sandwich, immunoglobulin-like fold with striking similarity to S-layer proteins. Crystal structures, X-ray scattering, and mutational analyses suggest dimer assembly is needed for in vivo function. The sole cell envelope component of S. acidocaldarius is amore »paracrystalline S-layer, and FlaF specifically bound to S-layer protein, suggesting that its interaction domain is located in the pseudoperiplasm with its N-terminal helix in the membrane. From these data, FlaF may act as the previously unknown archaellum stator protein that anchors the rotating archaellum to the archaeal cell envelope.« less

  12. Theory of nitrogen doping of carbon nanoribbons: Edge effects

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Jiang, Jie; Turnbull, Joseph; Lu, Wenchang; Oak Ridge National Lab.; Boguslawski, Piotr; Univ. of Warsaw; Bernholc, J.; Oak Ridge National Lab.

    2012-01-01

    Nitrogen doping of a carbon nanoribbon is profoundly affected by its one-dimensional character, symmetry, and interaction with edge states. Using state-of-the-art ab initio calculations, including hybrid exact-exchange density functional theory, we find that, for N-doped zigzag ribbons, the electronic properties are strongly dependent upon sublattice effects due to the non-equivalence of the two sublattices. For armchair ribbons, N-doping effects are different depending upon the ribbon family: for families 2 and 0, the N-induced levels are in the conduction band, while for family 1 the N levels are in the gap. In zigzag nanoribbons, nitrogen close to the edge is amore »deep center, while in armchair nanoribbons its behavior is close to an effective-mass-like donor with the ionization energy dependent on the value of the band gap. In chiral nanoribbons, we find strong dependence of the impurity level and formation energy upon the edge position of the dopant, while such site-specificity is not manifested in the magnitude of the magnetization.« less

  13. Plant salt stress status is transmitted systemically via propagating calcium waves

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Stephan, Aaron B.; Schroeder, Julian I.

    2014-04-29

    The existence and relevance of rapid long distance signaling in plants is evident to any observer of the nastic movements of the Venus flytrap (Dionaea muscipula) or the sensitive plant (Mimosa pudica). However, all plants require the transmission of sensory information from the site of perception to other tissues to adjust their physiological states according to their environment. It is becoming increasingly apparent that rapid long-distance signals exist throughout the plant kingdom and may be responsible for initiating a multitude of physiological responses: electrical “action potentials” have been shown to convey wounding and saltstress information from leaf-to-leaf (1, 2); amore »“hydraulic signal” transmitted by the direction of water movement within the xylem can mediate long-distance signaling of water stress experienced by the roots to the leaves in Arabidopsis (3); and reactive oxygen species (ROS) have been shown to propagate across a plant and carry stimulus-specific information to a variety of stresses (4). In PNAS, Choi et al. (5) use elegant approaches and present advances demonstrating that calcium can function as a long-distance signaling messenger, propagating in waves from roots and carrying salt-stress signals to induce expression of salt tolerance genes in leaves.« less

  14. A unified parameterization of clouds and turbulence using CLUBB and subcolumns in the Community Atmosphere Model

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Thayer-Calder, K.; Gettelman, A.; Craig, C.; Goldhaber, S.; Bogenschutz, P. A.; Chen, C.-C.; Morrison, H.; Höft, J.; Raut, E.; Griffin, B. M.; et al

    2015-06-30

    Most global climate models parameterize separate cloud types using separate parameterizations. This approach has several disadvantages, including obscure interactions between parameterizations and inaccurate triggering of cumulus parameterizations. Alternatively, a unified cloud parameterization uses one equation set to represent all cloud types. Such cloud types include stratiform liquid and ice cloud, shallow convective cloud, and deep convective cloud. Vital to the success of a unified parameterization is a general interface between clouds and microphysics. One such interface involves drawing Monte Carlo samples of subgrid variability of temperature, water vapor, cloud liquid, and cloud ice, and feeding the sample points into amore »microphysics scheme. This study evaluates a unified cloud parameterization and a Monte Carlo microphysics interface that has been implemented in the Community Atmosphere Model (CAM) version 5.3. Results describing the mean climate and tropical variability from global simulations are presented. The new model shows a degradation in precipitation skill but improvements in short-wave cloud forcing, liquid water path, long-wave cloud forcing, precipitable water, and tropical wave simulation. Also presented are estimations of computational expense and investigation of sensitivity to number of subcolumns.« less

  15. Quantitative infrared absorption cross-sections of isoprene for atmospheric measurements

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Brauer, C. S.; Blake, T. A.; Guenther, A. B.; Sams, R. L.; Johnson, T. J.

    2014-04-25

    Isoprene (C5H8, 2-methyl-1,3-butadiene) is a volatile organic compound (VOC) that is one of the primary contributors to annual global VOC emissions. Produced by vegetation as well as anthropogenic sources, the OH- and O3-initiated oxidations of isoprene are a major source of atmospheric oxygenated organics. Few quantitative infrared studies have been reported for isoprene, however, limiting the ability to quantify isoprene emissions via stand-off infrared or in situ detection. We thus report absorption coefficients and integrated band intensities for isoprene in the 600–6500 cm?1 region. The pressure-broadened (1 atmosphere N2) spectra were recorded at 278, 298 and 323 K in amore »19.94 cm path length cell at 0.112 cm?1 resolution, using a Bruker 66v FTIR. Composite spectra are derived from a minimum of seven isoprene sample pressures at each temperature and the number densities are normalized to 296 K and 1 atmosphere.« less

  16. Airborne aerosol in situ measurements during TCAP: A closure study of total scattering

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kassianov, Evgueni; Sedlacek, Arthur; Berg, Larry K.; Pekour, Mikhail; Barnard, James; Chand, Duli; Flynn, Connor; Ovchinnikov, Mikhail; Schmid, Beat; Shilling, John; et al

    2015-07-31

    We present a framework for calculating the total scattering of both non-absorbing and absorbing aerosol at ambient conditions from aircraft data. Our framework is developed emphasizing the explicit use of chemical composition data for estimating the complex refractive index (RI) of particles, and thus obtaining improved ambient size spectra derived from Optical Particle Counter (OPC) measurements. The feasibility of our framework for improved calculations of total scattering is demonstrated using three types of data collected by the U.S. Department of Energy’s (DOE) aircraft during the Two-Column Aerosol Project (TCAP). Namely, these data types are: (1) size distributions measured by amore »suite of OPC’s; (2) chemical composition data measured by an Aerosol Mass Spectrometer and a Single Particle Soot Photometer; and (3) the dry total scattering coefficient measured by a integrating nephelometer and scattering enhancement factor measured with a humidification system. We demonstrate that good agreement (~10%) between the observed and calculated scattering can be obtained under ambient conditions (RH « less

  17. Azasugar inhibitors as pharmacological chaperones for Krabbe disease

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Hill, Chris H.; Viuff, Agnete H.; Spratley, Samantha J.; Salamone, Stéphane; Christensen, Stig H.; Read, Randy J.; Moriarty, Nigel W.; Jensen, Henrik H.; Deane, Janet E.

    2015-03-23

    Krabbe disease is a devastating neurodegenerative disorder characterized by rapid demyelination of nerve fibers. This disease is caused by defects in the lysosomal enzyme ?-galactocerebrosidase (GALC), which hydrolyzes the terminal galactose from glycosphingolipids. These lipids are essential components of eukaryotic cell membranes: substrates of GALC include galactocerebroside, the primary lipid component of myelin, and psychosine, a cytotoxic metabolite. Mutations of GALC that cause misfolding of the protein may be responsive to pharmacological chaperone therapy (PCT), whereby small molecules are used to stabilize these mutant proteins, thus correcting trafficking defects and increasing residual catabolic activity in cells. Here we describe amore »new approach for the synthesis of galacto-configured azasugars and the characterization of their interaction with GALC using biophysical, biochemical and crystallographic methods. We identify that the global stabilization of GALC conferred by azasugar derivatives, measured by fluorescence-based thermal shift assays, is directly related to their binding affinity, measured by enzyme inhibition. X-ray crystal structures of these molecules bound in the GALC active site reveal which residues participate in stabilizing interactions, show how potency is achieved and illustrate the penalties of aza/iminosugar ring distortion. The structure–activity relationships described here identify the key physical properties required of pharmacological chaperones for Krabbe disease and highlight the potential of azasugars as stabilizing agents for future enzyme replacement therapies. This work lays the foundation for new drug-based treatments of Krabbe disease.« less

  18. Redox probing study of the potential dependence of charge transport through Li2O2

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Knudsen, Kristian B.; Luntz, Alan C.; Jensen, Søren H.; Vegge, Tejs; Hjelm, Johan

    2015-11-20

    In the field of energy storage devices the pursuit for cheap, high energy density, reliable secondary batteries is at the top of the agenda. The Li–O2 battery is one of the possible technologies that, in theory, should be able to close the gap, which exists between the present state-of-the-art Li-ion technologies and the demand placed on batteries by technologies such as electrical vehicles. Here we present a redox probing study of the charge transfer across the main deposition product lithium peroxide, Li2O2, in the Li–O2 battery using outer-sphere redox shuttles. The change in heterogeneous electron transfer exchange rate as amore »function of the potential and the Li2O2 layer thickness (~depth-of-discharge) was determined using electrochemical impedance spectroscopy. In addition, the attenuation of the electron transfer exchange rate with film thickness is dependent on the probing potential, providing evidence that hole transport is the dominant process for charge transfer through Li2O2 and showing that the origin of the sudden death observed upon discharge is due to charge transport limitations.« less

  19. A 6 kV arbitrary waveform generator for the Tevatron Electron Lens

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Pfeffer, H.; Saewert, G.

    2011-11-09

    This paper reports on a 6 kV modulator built and installed at Fermilab to drive the electron gun anode for the Tevatron Electron Lens (TEL). The TEL was built with the intention of shifting the individual (anti)proton bunch tunes to even out the tune spread among all 36 bunches with the desire of improving Tevatron integrated luminosity. This modulator is essentially a 6 kV arbitrary waveform generator that enables the TEL to define the electron beam intensity on a bunch-by-bunch basis. A voltage waveform is constructed having a 7 ?s duration that corresponds to the tune shift requirements of amore »12-bunch (anti)proton beam pulse train. This waveform is played out for any one or all three bunch trains in the Tevatron. The programmed waveform voltages transition to different levels at time intervals corresponding to the 395 ns bunch spacing. In addition, complex voltage waveforms can be played out at a sustained rate of 143 kHz over the full 6 kV output range. This paper describes the novel design of the inductive adder topology employing five transformers. It describes the design aspects that minimize switching losses for this multi-kilovolt, high repetition rate and high duty factor application.« less

  20. MEIC electron cooling program

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Derbenev, Yaroslav S.; Zhang, Yuhong

    2014-12-01

    Cooling of proton and ion beams is essential for achieving high luminosities (up to above 1034 cm-2s-1) for MEIC, a Medium energy Electron-Ion Collider envisioned at JLab [1] for advanced nuclear science research. In the present conceptual design, we utilize the conventional election cooling method and adopted a multi-staged cooling scheme for reduction of and maintaining low beam emittances [2,3,4]. Two electron cooling facilities are required to support the scheme: one is a low energy (up to 2 MeV) DC cooler installed in the MEIC ion pre-booster (with the proton kinetic energy up to 3 GeV); the other is amore »high electron energy (up to 55 MeV) cooler in the collider ring (with the proton kinetic energy from 25 to 100 GeV). The high energy cooler, which is based on the ERL technology and a circulator ring, utilizes a bunched electron beam to cool bunched proton or ion beams. To complete the MEIC cooling concept and a technical design of the ERL cooler as well as to develop supporting technologies, an R&D program has been initiated at Jefferson Lab and significant progresses have been made since then. In this study, we present a brief description of the cooler design and a summary of the progress in this cooling R&D.« less

  1. RACORO continental boundary layer cloud investigations. 3. Separation of parameterization biases in single-column model CAM5 simulations of shallow cumulus

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lin, Wuyin; Liu, Yangang; Vogelmann, Andrew M.; Fridlind, Ann; Endo, Satoshi; Song, Hua; Feng, Sha; Toto, Tami; Li, Zhijin; Zhang, Minghua

    2015-06-19

    Climatically important low-level clouds are commonly misrepresented in climate models. The FAst-physics System TEstbed and Research (FASTER) project has constructed case studies from the Atmospheric Radiation Measurement (ARM) Climate Research Facility's Southern Great Plain site during the RACORO aircraft campaign to facilitate research on model representation of boundary-layer clouds. This paper focuses on using the single-column Community Atmosphere Model version 5 (SCAM5) simulations of a multi-day continental shallow cumulus case to identify specific parameterization causes of low-cloud biases. Consistent model biases among the simulations driven by a set of alternative forcings suggest that uncertainty in the forcing plays only amore »relatively minor role. In-depth analysis reveals that the model's shallow cumulus convection scheme tends to significantly under-produce clouds during the times when shallow cumuli exist in the observations, while the deep convective and stratiform cloud schemes significantly over-produce low-level clouds throughout the day. The links between model biases and the underlying assumptions of the shallow cumulus scheme are further diagnosed with the aid of large-eddy simulations and aircraft measurements, and by suppressing the triggering of the deep convection scheme. It is found that the weak boundary layer turbulence simulated is directly responsible for the weak cumulus activity and the simulated boundary layer stratiform clouds. Increased vertical and temporal resolutions are shown to lead to stronger boundary layer turbulence and reduction of low-cloud biases.« less

  2. Time-Resolved Imaging of the Microbunching Instability and Energy Spread at the Linac Coherent Light Source

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ratner, D.; Behrens, C.; Deutsches Elektronen-Synchrotron DESY, Hamburg; Ding, Y.; Huang, Z.; Marinelli, A.; Maxwell, T.; Zhou, F.

    2015-03-01

    The microbunching instability (MBI) is a well known problem for high brightness electron beams and has been observed at accelerator facilities around the world. Free-electron lasers (FELs) are particularly susceptible to MBI, which can distort the longitudinal phase space and increase the beam’s slice energy spread (SES). Past studies of MBI at the Linac Coherent Light Source (LCLS) relied on optical transition radiation to infer the existence of microbunching. With the development of the x-band transverse deflecting cavity (XTCAV), we can for the first time directly image the longitudinal phase space at the end of the accelerator and complete amore »comprehensive study of MBI, revealing both detailed MBI behavior as well as insights into mitigation schemes. The fine time resolution of the XTCAV also provides the first LCLS measurements of the final SES, a critical parameter for many advanced FEL schemes. Detailed MBI and SES measurements can aid in understanding MBI mechanisms, benchmarking simulation codes, and designing future high- brightness accelerators.« less

  3. Tightly integrated single- and multi-crystal data collection strategy calculation and parallelized data processing in JBluIce beamline control system

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Pothineni, Sudhir Babu; Venugopalan, Nagarajan; Ogata, Craig M.; Hilgart, Mark C.; Stepanov, Sergey; Sanishvili, Ruslan; Becker, Michael; Winter, Graeme; Sauter, Nicholas K.; Smith, Janet L.; et al

    2014-11-18

    The calculation of single- and multi-crystal data collection strategies and a data processing pipeline have been tightly integrated into the macromolecular crystallographic data acquisition and beamline control software JBluIce. Both tasks employ wrapper scripts around existing crystallographic software. JBluIce executes scripts through a distributed resource management system to make efficient use of all available computing resources through parallel processing. The JBluIce single-crystal data collection strategy feature uses a choice of strategy programs to help users rank sample crystals and collect data. The strategy results can be conveniently exported to a data collection run. The JBluIce multi-crystal strategy feature calculates amore »collection strategy to optimize coverage of reciprocal space in cases where incomplete data are available from previous samples. The JBluIce data processing runs simultaneously with data collection using a choice of data reduction wrappers for integration and scaling of newly collected data, with an option for merging with pre-existing data. Data are processed separately if collected from multiple sites on a crystal or from multiple crystals, then scaled and merged. Results from all strategy and processing calculations are displayed in relevant tabs of JBluIce.« less

  4. Direct spectroscopic evidence for completely filled Cu 3d shell in BaCu?As? and ? – BaCu?Sb?

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wu, S. F.; Richard, P.; van Roekeghem, A.; Nie, S. M.; Miao, H.; Xu, N.; Qian, T.; Saparov, B.; Fang, Z.; Biermann, S.; et al

    2015-06-08

    We use angle-resolved photoemission spectroscopy to extract the band dispersion and the Fermi surface of BaCu?As? and ? - BaCu?Sb?. While the Cu 3d bands in both materials are located around 3.5 eV below the Fermi level, the low-energy photoemission intensity mainly comes from As 4p states, suggesting a completely filled Cu 3d shell. The splitting of the As 3d core levels and the lack of pronounced three-dimensionality in the measured band structure of BaCu?As? indicate a surface state likely induced by the cleavage of this material in the collapsed tetragonal phase, which is consistent with our observation of amore »Cu?¹ oxidation state. However, the observation of Cu states at similar energy in ? - BaCu?Sb? without the pnictide-pnictide interlayer bonding characteristic of the collapsed tetragonal phase suggests that the short interlayer distance in BaCu?As? follows from the stability of the Cu?¹ rather than the other way around. Our results confirm the prediction that BaCu?As? is an sp metal with weak electronic correlations.« less

  5. Phosphorylation and Methylation of Proteasomal Proteins of the HaloarcheonHaloferax volcanii

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Humbard, Matthew A.; Reuter, Christopher J.; Zuobi-Hasona, Kheir; Zhou, Guangyin; Maupin-Furlow, Julie A.

    2010-01-01

    Proteasomes are composed of 20S core particles (CPs) of?- and?-type subunits that associate with regulatory particle AAA ATPases such as the proteasome-activating nucleotidase (PAN) complexes of archaea. In this study, the roles and additional sites of post-translational modification of proteasomes were investigated using the archaeonHaloferax volcaniias a model. Indicative of phosphorylation, phosphatase-sensitive isoforms of?1and?2were detected by 2-DE immunoblot. To map these and other potential sites of post-translational modification, proteasomes were purified and analyzed by tandem mass spectrometry (MS/MS). Using this approach, several phosphosites were mapped including?1Thr147,?2 Thr13/Ser14 and PAN-A Ser340. Multiple methylation sites were also mapped to?1, thus, revealing amore »new type of proteasomal modification. Probing the biological role of?1and PAN-A phosphorylation by site-directed mutagenesis revealed dominant negative phenotypes for cell viability and/or pigmentation for?1variants including Thr147Ala, Thr158Ala and Ser58Ala. AnH. volcaniiRio1p Ser/Thr kinase homolog was purified and shown to catalyze autophosphorylation and phosphotransfer to?1. The?1variants in Thr and Ser residues that displayed dominant negative phenotypes were significantly reduced in their ability to accept phosphoryl groups from Rio1p, thus, providing an important link between cell physiology and proteasomal phosphorylation.« less

  6. Laser acceleration of protons using multi-ion plasma gaseous targets

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Liu, Tung -Chang; Shao, Xi; Liu, Chuan -Sheng; Eliasson, Bengt; Strathclyde Univ., Glasgow; Hill, III, W. T.; Wang, Jyhpyng; National Central Univ., Taoyuan; Chen, Shih -Hung

    2015-02-01

    We present a theoretical and numerical study of a novel acceleration scheme by applying a combination of laser radiation pressure and shielded Coulomb repulsion in laser acceleration of protons in multi-species gaseous targets. By using a circularly polarized CO? laser pulse with a wavelength of 10 ?m—much greater than that of a Ti: Sapphire laser—the critical density is significantly reduced, and a high-pressure gaseous target can be used to achieve an overdense plasma. This gives us a larger degree of freedom in selecting the target compounds or mixtures, as well as their density and thickness profiles. By impinging such amore »laser beam on a carbon–hydrogen target, the gaseous target is first compressed and accelerated by radiation pressure until the electron layer disrupts, after which the protons are further accelerated by the electron-shielded carbon ion layer. An 80 MeV quasi-monoenergetic proton beam can be generated using a half-sine shaped laser beam with a peak power of 70 TW and a pulse duration of 150 wave periods.« less

  7. Edge-terminated molybdenum disulfide with a 9.4-Å interlayer spacing for electrochemical hydrogen production

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Gao, Min -Rui; Chan, Maria K. Y.; Sun, Yugang

    2015-07-03

    In this study, layered molybdenum disulfide has demonstrated great promise as a low-cost alternative to platinum-based catalysts for electrochemical hydrogen production from water. Research effort on this material has focused mainly on synthesizing highly nanostructured molybdenum disulfide that allows the exposure of a large fraction of active edge sites. Here we report a promising microwave-assisted strategy for the synthesis of narrow molybdenum disulfide nanosheets with edge-terminated structure and a significantly expanded interlayer spacing, which exhibit striking kinetic metrics with onset potential of -103 mV, Tafel slope of 49 mV per decade and exchange current density of 9.62 × 10-3 mAmore »cm-2, performing among the best of current molybdenum disulfide catalysts. Besides benefits from the edge-terminated structure, the expanded interlayer distance with modified electronic structure is also responsible for the observed catalytic improvement, which suggests a potential way to design newly advanced molybdenum disulfide catalysts through modulating the interlayer distance.« less

  8. Measurement of the top-quark mass in the lepton+jets channel using a matrix element technique with the CDF II detector

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Aaltonen, T.

    2011-10-14

    A measurement of the top-quark mass is presented using Tevatron data from proton-antiproton collisions at center-of-mass energy ?s = 1.96 TeV collected with the CDF II detector. Events are selected from a sample of candidates for production of tt? pairs that decay into the lepton+jets channel. The top-quark mass is measured with an unbinned maximum likelihood method where the event probability density functions are calculated using signal and background matrix elements, as well as a set of parameterized jet-to-parton transfer functions. The likelihood function is maximized with respect to the top-quark mass, the signal fraction in the sample, and amore »correction to the jet energy scale (JES) calibration of the calorimeter jets. The simultaneous measurement of the JES correction ({Delta}{sub JES}) amounts to an additional in situ jet energy calibration based on the known mass of the hadronically decaying W boson. Using the data sample of 578 lepton+jets candidate events, corresponding to 3.2 fb-1 of integrated luminosity, the top-quark mass is measured to be mt = 172.4± 1.4 (stat + ?JES) ± 1.3 (syst) GeV/c2.« less

  9. Basic features of the pion valence-quark distribution function

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Chang, Lei; Mezrag, Cédric; Moutarde, Hervé; Roberts, Craig D.; Rodríguez-Quintero, Jose; Tandy, Peter C.

    2014-10-07

    The impulse-approximation expression used hitherto to define the pion's valence-quark distribution function is flawed because it omits contributions from the gluons which bind quarks into the pion. A corrected leading-order expression produces the model-independent result that quarks dressed via the rainbow–ladder truncation, or any practical analogue, carry all the pion's light-front momentum at a characteristic hadronic scale. Corrections to the leading contribution may be divided into two classes, responsible for shifting dressed-quark momentum into glue and sea-quarks. Working with available empirical information, we use an algebraic model to express the principal impact of both classes of corrections. This enables amore »realistic comparison with experiment that allows us to highlight the basic features of the pion's measurable valence-quark distribution, q?(x); namely, at a characteristic hadronic scale, q?(x)~(1-x)2 for x?0.85; and the valence-quarks carry approximately two-thirds of the pion's light-front momentum.« less

  10. In situ visualization of metallurgical reactions in nanoscale Cu/Sn diffusion couples

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yin, Qiyue; Stach, Eric A.; Gao, Fan; Zhou, Guangwen; Gu, Zhiyong

    2015-02-10

    The Cu–Sn metallurgical soldering reaction in two-segmented Cu–Sn nanowires is visualized by in-situ transmission electron microscopy. By varying the relative lengths of Cu and Sn segments, we show that the metallurgical reaction starts at ~ 200 ° with the formation of a Cu–Sn solid solution for the Sn/Cu length ratio smaller than 1:5 while the formation of Cu–Sn intermetallic compounds (IMCs) for larger Sn/Cu length ratios. Upon heating the nanowires up to ~ 500 °C, two phase transformation pathways occur, ?-Cu?Sn? ? ?-Cu?Sn ? ?-Cu??Sn?? for nanowires with a long Cu segment and ?-Cu?Sn? ? ?-Cu?Sn ? ?-Cu?Sn with amore »short Cu segment. The dynamic in situ TEM visualization of the evolution of Kirkendall voids demonstrates that Cu diffuses faster both in Sn and IMCs than that of Sn in Cu? and IMCs, which is the underlying cause of the dependence of the IMC formation and associated phase evolution on the relative lengths of the Cu and Sn segments.« less

  11. Development of nanosecond time-resolved infrared detection at the LEAF pulse radiolysis facility

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Grills, David C.; Farrington, Jaime A.; Layne, Bobby H.; Preses, Jack M.; Bernstein, Herbert J.; Wishart, James F.

    2015-04-27

    When coupled with transient absorption spectroscopy, pulse radiolysis, which utilizes high-energy electron pulses from an accelerator, is a powerful tool for investigating the kinetics and thermodynamics of a wide range of radiation-induced redox and electron transfer processes. The majority of these investigations detect transient species in the UV, visible, or near-IR spectral regions. Unfortunately, the often-broad and featureless absorption bands in these regions can make the definitive identification of intermediates difficult. Time-resolved vibrational spectroscopy would offer much improved structural characterization, but has received only limited application in pulse radiolysis. In this paper, we describe in detail the development of amore »unique nanosecond time-resolved infrared (TRIR) detection capability for condensed-phase pulse radiolysis on a new beam line at the LEAF facility of Brookhaven National Laboratory. The system makes use of a suite of high-power, continuous wave external-cavity quantum cascade lasers as the IR probe source, with coverage from 2330-1051 cm?¹. The response time of the TRIR detection setup is ~40 ns, with a typical sensitivity of ~100 µOD after 4-8 signal averages using a dual-beam probe/reference normalization detection scheme. As a result, this new detection method has enabled mechanistic investigations of a range of radiation-induced chemical processes, some of which are highlighted here.« less

  12. Unconventional transformation of spin Dirac phase across a topological quantum phase transition

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Xu, Su -Yang; Neupane, Madhab; Belopolski, Ilya; Liu, Chang; Alidoust, Nasser; Bian, Guang; Jia, Shuang; Landolt, Gabriel; Slomski, Batosz; Dil, J. Hugo; et al

    2015-04-17

    The topology of a topological material can be encoded in its surface states. These surface states can only be removed by a bulk topological quantum phase transition into a trivial phase. Here we use photoemission spectroscopy to image the formation of protected surface states in a topological insulator as we chemically tune the system through a topological transition. Surprisingly, we discover an exotic spin-momentum locked, gapped surface state in the trivial phase that shares many important properties with the actual topological surface state in anticipation of the change of topology. Using a spin-resolved measurement, we show that apart from amore »surface bandgap these states develop spin textures similar to the topological surface states well before the transition. Our results provide a general paradigm for understanding how surface states in topological phases arise from a quantum phase transition and are suggestive for the future realization of Weyl arcs, condensed matter supersymmetry and other fascinating phenomena in the vicinity of a quantum criticality.« less

  13. Heat capacity of the site-diluted spin dimer system Ba?(Mn1-xVx)?O?

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Samulon, E. C.; Shapiro, M. C.; Fisher, I. R.

    2011-08-01

    Heat-capacity and susceptibility measurements have been performed on the diluted spin dimer compound Ba?(Mn1-xVx)?O?. The parent compound Ba?Mn?O? is a spin dimer system based on pairs of antiferromagnetically coupled S=1, 3d² Mn?? ions such that the zero-field ground state is a product of singlets. Substitution of nonmagnetic S=0, 3d? V?? ions leads to an interacting network of unpaired Mn moments, the low-temperature properties of which are explored in the limit of small concentrations 0?x?0.05. The zero-field heat capacity of this diluted system reveals a progressive removal of magnetic entropy over an extended range of temperatures, with no evidence for amore »phase transition. The concentration dependence does not conform to expectations for a spin-glass state. Rather, the data suggest a low-temperature random singlet phase, reflecting the hierarchy of exchange energies found in this system.« less

  14. Optimizing Monitoring Designs under Alternative Objectives

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Gastelum, Jason A.; USA, Richland Washington; Porter, Ellen A.; USA, Richland Washington

    2014-12-31

    This paper describes an approach to identify monitoring designs that optimize detection of CO2 leakage from a carbon capture and sequestration (CCS) reservoir and compares the results generated under two alternative objective functions. The first objective function minimizes the expected time to first detection of CO2 leakage, the second more conservative objective function minimizes the maximum time to leakage detection across the set of realizations. The approach applies a simulated annealing algorithm that searches the solution space by iteratively mutating the incumbent monitoring design. The approach takes into account uncertainty by evaluating the performance of potential monitoring designs across amore »set of simulated leakage realizations. The approach relies on a flexible two-tiered signature to infer that CO2 leakage has occurred. This research is part of the National Risk Assessment Partnership, a U.S. Department of Energy (DOE) project tasked with conducting risk and uncertainty analysis in the areas of reservoir performance, natural leakage pathways, wellbore integrity, groundwater protection, monitoring, and systems level modeling.« less

  15. Physically motivated global alignment method for electron tomography

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Sanders, Toby; Prange, Micah; Akatay, Cem; Binev, Peter

    2015-04-08

    Electron tomography is widely used for nanoscale determination of 3-D structures in many areas of science. Determining the 3-D structure of a sample from electron tomography involves three major steps: acquisition of sequence of 2-D projection images of the sample with the electron microscope, alignment of the images to a common coordinate system, and 3-D reconstruction and segmentation of the sample from the aligned image data. The resolution of the 3-D reconstruction is directly influenced by the accuracy of the alignment, and therefore, it is crucial to have a robust and dependable alignment method. In this paper, we develop amore »new alignment method which avoids the use of markers and instead traces the computed paths of many identifiable ‘local’ center-of-mass points as the sample is rotated. Compared with traditional correlation schemes, the alignment method presented here is resistant to cumulative error observed from correlation techniques, has very rigorous mathematical justification, and is very robust since many points and paths are used, all of which inevitably improves the quality of the reconstruction and confidence in the scientific results.« less

  16. Effects of Intercritical Annealing Temperature on Mechanical Properties of Fe-7.9Mn-0.14Si-0.05Al-0.07C Steel

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhao, Xianming; Shen, Yongfeng; Qiu, Lina; Liu, Yandong; Sun, Xin; Zuo, Liang

    2014-12-09

    A medium Mn steel has been designed to achieve an excellent combination of strength and ductility based on the TRIP (Transformation Induced Plasticity) concept for automotive applications. Following six passes of hot rolling at 850 °C, the Fe-7.9Mn-0.14Si-0.05Al-0.07C (wt.%) steel was warm-rolled at 630 °C for seven passes and subsequently air cooled to room temperature. The sample was subsequently intercritically annealed at various temperatures for 30 min to promote the reverse transformation of martensite into austenite. The obtained results show that the highest volume fraction of austenite is 39% for the sample annealed at 600 °C. This specimen exhibits amore »yield stress of 910 MPa and a high ultimate tensile stress of 1600 MPa, with an elongation-to-failure of 0.29 at a strain rate of 1 × 10?³/s. The enhanced work-hardening ability of the investigated steel is closely related to martensitic transformation and the interaction of dislocations. Especially, the alternate arrangement of acicular ferrite (soft phase) and ultrafine austenite lamellae (50–200 nm, strong and ductile phase) is the key factor contributing to the excellent combination of strength and ductility. On the other hand, the as-warm-rolled sample also exhibits the excellent combination of strength and ductility, with elongation-to-failure much higher than those annealed at temperatures above 630 °C.« less

  17. Towards reversible basic linear algebra subprograms: A performance study

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Perumalla, Kalyan S.; Yoginath, Srikanth B.

    2014-12-06

    Problems such as fault tolerance and scalable synchronization can be efficiently solved using reversibility of applications. Making applications reversible by relying on computation rather than on memory is ideal for large scale parallel computing, especially for the next generation of supercomputers in which memory is expensive in terms of latency, energy, and price. In this direction, a case study is presented here in reversing a computational core, namely, Basic Linear Algebra Subprograms, which is widely used in scientific applications. A new Reversible BLAS (RBLAS) library interface has been designed, and a prototype has been implemented with two modes: (1) amore »memory-mode in which reversibility is obtained by checkpointing to memory in forward and restoring from memory in reverse, and (2) a computational-mode in which nothing is saved in the forward, but restoration is done entirely via inverse computation in reverse. The article is focused on detailed performance benchmarking to evaluate the runtime dynamics and performance effects, comparing reversible computation with checkpointing on both traditional CPU platforms and recent GPU accelerator platforms. For BLAS Level-1 subprograms, data indicates over an order of magnitude better speed of reversible computation compared to checkpointing. For BLAS Level-2 and Level-3, a more complex tradeoff is observed between reversible computation and checkpointing, depending on computational and memory complexities of the subprograms.« less

  18. Resonant spin tunneling in randomly oriented nanospheres of Mn12 acetate

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lendínez, S.; Zarzuela, R.; Tejada, J.; Terban, M. W.; Billinge, S. J. L.; Espin, J.; Imaz, I.; Maspoch, D.; Chudnovsky, E. M.

    2015-01-06

    We report measurements and theoretical analysis of resonant spin tunneling in randomly oriented nanospheres of a molecular magnet. Amorphous nanospheres of Mn?? acetate have been fabricated and characterized by chemical, infrared, TEM, X-ray, and magnetic methods. Magnetic measurements have revealed sharp tunneling peaks in the field derivative of the magnetization that occur at the typical resonant field values for the Mn?? acetate crystal in the field parallel to the easy axis.Theoretical analysis is provided that explains these observations. We argue that resonant spin tunneling in a molecular magnet can be established in a powder sample, without the need for amore »single crystal and without aligning the easy magnetization axes of the molecules. This is confirmed by re-analyzing the old data on a powdered sample of non-oriented micron-size crystals of Mn?? acetate. In conclusion, our findings can greatly simplify the selection of candidates for quantum spin tunneling among newly synthesized molecular magnets.« less

  19. Structures of Escherichia coli DNA adenine methyltransferase (Dam) in complex with a non-GATC sequence: Potential implications for methylation-independent transcriptional repression

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Horton, John R.; Zhang, Xing; Blumenthal, Robert M.; Cheng, Xiaodong

    2015-04-06

    DNA adenine methyltransferase (Dam) is widespread and conserved among the ?-proteobacteria. Methylation of the Ade in GATC sequences regulates diverse bacterial cell functions, including gene expression, mismatch repair and chromosome replication. Dam also controls virulence in many pathogenic Gram-negative bacteria. An unexplained and perplexing observation about Escherichia coli Dam (EcoDam) is that there is no obvious relationship between the genes that are transcriptionally responsive to Dam and the promoter-proximal presence of GATC sequences. Here, we demonstrate that EcoDam interacts with a 5-base pair non-cognate sequence distinct from GATC. The crystal structure of a non-cognate complex allowed us to identify amore »DNA binding element, GTYTA/TARAC (where Y = C/T and R = A/G). This element immediately flanks GATC sites in some Dam-regulated promoters, including the Pap operon which specifies pyelonephritis-associated pili. In addition, Dam interacts with near-cognate GATC sequences (i.e. 3/4-site ATC and GAT). All together, these results imply that Dam, in addition to being responsible for GATC methylation, could also function as a methylation-independent transcriptional repressor.« less

  20. Low-loss electron energy loss spectroscopy: An atomic-resolution complement to optical spectroscopies and application to graphene

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kapetanakis, Myron; Zhou, Wu; Oxley, Mark P.; Lee, Jaekwang; Prange, Micah P.; Pennycook, Stephen J.; Idrobo Tapia, Juan Carlos; Pantelides, Sokrates T.

    2015-09-25

    Photon-based spectroscopies have played a central role in exploring the electronic properties of crystalline solids and thin films. They are a powerful tool for probing the electronic properties of nanostructures, but they are limited by lack of spatial resolution. On the other hand, electron-based spectroscopies, e.g., electron energy loss spectroscopy (EELS), are now capable of subangstrom spatial resolution. Core-loss EELS, a spatially resolved analog of x-ray absorption, has been used extensively in the study of inhomogeneous complex systems. In this paper, we demonstrate that low-loss EELS in an aberration-corrected scanning transmission electron microscope, which probes low-energy excitations, combined with amore »theoretical framework for simulating and analyzing the spectra, is a powerful tool to probe low-energy electron excitations with atomic-scale resolution. The theoretical component of the method combines density functional theory–based calculations of the excitations with dynamical scattering theory for the electron beam. We apply the method to monolayer graphene in order to demonstrate that atomic-scale contrast is inherent in low-loss EELS even in a perfectly periodic structure. The method is a complement to optical spectroscopy as it probes transitions entailing momentum transfer. The theoretical analysis identifies the spatial and orbital origins of excitations, holding the promise of ultimately becoming a powerful probe of the structure and electronic properties of individual point and extended defects in both crystals and inhomogeneous complex nanostructures. The method can be extended to probe magnetic and vibrational properties with atomic resolution.« less

  1. Dual-spacecraft reconstruction of a three-dimensional magnetic flux rope at the Earth's magnetopause

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Hasegawa, H.; Sonnerup, B. U. Ö.; Eriksson, S.; Nakamura, T. K. M.; Kawano, H.

    2015-02-03

    We present the first results of a data analysis method, developed by Sonnerup and Hasegawa (2011), for reconstructing three-dimensional (3-D), magnetohydrostatic structures from data taken as two closely spaced satellites traverse the structures. The method is applied to a magnetic flux transfer event (FTE), which was encountered on 27 June 2007 by at least three (TH-C, TH-D, and TH-E) of the five THEMIS probes near the subsolar magnetopause. The FTE was sandwiched between two oppositely directed reconnection jets under a southward interplanetary magnetic field condition, consistent with its generation by multiple X-line reconnection. The recovered 3-D field indicates that amore »magnetic flux rope with a diameter of ~ 3000 km was embedded in the magnetopause. The FTE flux rope had a significant 3-D structure, because the 3-D field reconstructed from the data from TH-C and TH-D (separated by ~ 390 km) better predicts magnetic field variations actually measured along the TH-E path than does the 2-D Grad–Shafranov reconstruction using the data from TH-C (which was closer to TH-E than TH-D and was at ~ 1250 km from TH-E). Such a 3-D nature suggests that the field lines reconnected at the two X-lines on both sides of the flux rope are entangled in a complicated way through their interaction with each other. The generation process of the observed 3-D flux rope is discussed on the basis of the reconstruction results and the pitch-angle distribution of electrons observed in and around the FTE.« less

  2. The activity of CouR, a MarR family transcriptional regulator, is modulated through a novel molecular mechanism

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Otani, Hiroshi; Stogios, Peter J.; Xu, Xiaohui; Nocek, Boguslaw; Li, Shu -Nan; Savchenko, Alexei; Eltis, Lindsay D.

    2015-09-22

    CouR, a MarR-type transcriptional repressor, regulates the cou genes, encoding p-hydroxycinnamate catabolism in the soil bacterium Rhodococcus jostii RHA1. The CouR dimer bound two molecules of the catabolite p-coumaroyl–CoA (Kd = 11 ± 1 ?M). The presence of p-coumaroyl–CoA, but neither p-coumarate nor CoASH, abrogated CouR's binding to its operator DNA in vitro. The crystal structures of ligand-free CouR and its p-coumaroyl–CoA-bound form showed no significant conformational differences, in contrast to other MarR regulators. The CouR–p-coumaroyl–CoA structure revealed two ligand molecules bound to the CouR dimer with their phenolic moieties occupying equivalent hydrophobic pockets in each protomer and their CoAmore »moieties adopting non-equivalent positions to mask the regulator's predicted DNA-binding surface. More specifically, the CoA phosphates formed salt bridges with predicted DNA-binding residues Arg36 and Arg38, changing the overall charge of the DNA-binding surface. The substitution of either arginine with alanine completely abrogated the ability of CouR to bind DNA. By contrast, the R36A/R38A double variant retained a relatively high affinity for p-coumaroyl–CoA (Kd = 89 ± 6 ?M). Altogether, our data point to a novel mechanism of action in which the ligand abrogates the repressor's ability to bind DNA by steric occlusion of key DNA-binding residues and charge repulsion of the DNA backbone.« less

  3. Stripe order in superconducting La2-xBaxCuO? (0.095?x?0.155)

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Hücker, M.; v. Zimmermann, M.; Gu, G. D.; Xu, Z. J.; Wen, J. S.; Xu, Guangyong; Kang, H. J.; Zheludev, A.; Tranquada, J. M.

    2011-03-01

    The correlations between stripe order, superconductivity, and crystal structure in La2-xBaxCuO? single crystals have been studied by means of x-ray and neutron diffraction as well as static magnetization measurements. The derived phase diagram shows that charge stripe order (CO) coexists with bulk superconductivity in a broad range of doping around x=1/8, although the CO order parameter and correlation length fall off quickly for x?1/8. Except for x=0.155, the onset of CO always coincides with the transition between the orthorhombic and the tetragonal or less orthorhombic low-temperature structures. The CO transition evolves from a sharp drop at low x to amore »more gradual transition at higher x, eventually falling below the structural phase boundary for optimum doping. With respect to the interlayer CO correlations, we find no qualitative change of the stripe stacking order as a function of doping, and in-plane and out-of-plane correlations disappear simultaneously at the transition. Similarly to the CO, the spin stripe order (SO) is also most pronounced at x=1/8. Truly static SO sets in below the CO and coincides with the first appearance of in-plane superconducting correlations at temperatures significantly above the bulk transition to superconductivity (SC). Indications that bulk SC causes a reduction of the spin or charge stripe order could not be identified. We argue that CO is the dominant order that is compatible with SC pairing but competes with SC phase coherence. Comparing our results with data from the literature, we find good agreement if all results are plotted as a function of x' instead of the nominal x, where x' represents an estimate of the actual Ba content, extracted from the doping dependence of the structural transition between the orthorhombic phase and the tetragonal high-temperature phase.« less

  4. Determination of the optical properties of La2-xBaxCuO? for several dopings, including the anomalous x=1/8 phase

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Homes, C. C.; Hücker, M.; Li, Q.; Xu, Z. J.; Wen, J. S.; Gu, G. D.; Tranquada, J. M.

    2012-04-11

    The optical properties of single crystals of the high-temperature superconductor La2-xBaxCuO? have been measured over a wide frequency and temperature range for light polarized in the a-b planes and along the c axis. Three different Ba concentrations have been examined, x=0.095 with a critical temperature Tc=32 K, x=0.125 where the superconductivity is dramatically weakened with Tc?2.4 K, and x=0.145 with Tc?24 K. The in-plane behavior of the optical conductivity for these materials at high temperature is described by a Drude-like response with a scattering rate that decreases with temperature. Below Tc in the x=0.095 and 0.145 materials there is amore »clear signature of the formation of a superconducting state in the optical properties allowing the superfluid density (?s0) and the penetration depth to be determined. In the anomalous 1/8 phase, some spectral weight shifts from lower to higher frequency (?300 cm?¹) on cooling below the spin-ordering temperature Tso?42 K, associated with the onset of spin-stripe order; we discuss alternative interpretations in terms of a conventional density-wave gap versus the response to pair-density-wave superconductivity. The two dopings for which a superconducting response is observed both fall on the universal scaling line ?s0/8?4.4?dcTc, which is consistent with the observation of strong dissipation within the a-b planes. The optical properties for light polarized along the c axis reveal an insulating character dominated by lattice vibrations, superimposed on a weak electronic background. No Josephson plasma edge is observed in the low-frequency reflectance along the c axis for x=1/8; however, sharp plasma edges are observed for x=0.095 and 0.145 below Tc.« less

  5. Understanding oxygen adsorption on 9.375 at. % Ga-stabilized ?-Pu (111) surface: A DFT study

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Hernandez, Sarah C.; Wilkerson, Marianne P.; Huda, Muhammad N.

    2015-08-30

    Plutonium (Pu) metal reacts rapidly in the presence of oxygen (O), resulting in an oxide layer that will eventually have an olive green rust appearance over time. Recent experimental work suggested that the incorporation of gallium (Ga) as an alloying impurity to stabilize the highly symmetric high temperature ?-phase lattice may also provide resistance against corrosion/oxidation of plutonium. In this paper, we modeled a 9.375 at. % Ga stabilized ?-Pu (111) surface and investigated adsorption of atomic O using all-electron density functional theory. Key findings revealed that the O bonded strongly to a Pu-rich threefold hollow fcc site with amore »chemisorption energy of –5.06 eV. Migration of the O atom to a Pu-rich environment was also highly sensitive to the surface chemistry of the Pu–Ga surface; when the initial on-surface O adsorption site included a bond to a nearest neighboring Ga atom, the O atom relaxed to a Ga deficient environment, thus affirming the O preference for Pu. Only one calculated final on-surface O adsorption site included a Ga-O bond, but this chemisorption energy was energetically unfavorable. Chemisorption energies for interstitial adsorption sites that included a Pu or Pu-Ga environment suggested that over-coordination of the O atom was energetically unfavorable as well. Electronic structure properties of the on-surface sites, illustrated by the partial density of states, implied that the Ga 4p states indirectly but strongly influenced the Pu 6d states strongly to hybridize with the O 2p states, while also weakly influenced the Pu 5f states to hybridize with the O 2p states, even though Ga was not participating in bonding with O.« less

  6. Neutron spectroscopic study of crystalline electric field excitations in stoichiometric and lightly stuffed Yb2Ti2O7

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Gaudet, J.; Maharaj, D. D.; Sala, G.; Kermarrec, E.; Ross, K. A.; Dabkowska, H. A.; Kolesnikov, A. I.; Granroth, G. E.; Gaulin, B. D.

    2015-10-27

    Time-of-flight neutron spectroscopy has been used to determine the crystalline electric field (CEF) Hamiltonian, eigenvalues and eigenvectors appropriate to the J=7/2 Yb3+ ion in the candidate quantum spin ice pyrochlore magnet Yb2Ti2O7. The precise ground state (GS) of this exotic, geometrically frustrated magnet is known to be sensitive to weak disorder associated with the growth of single crystals from the melt. Such materials display weak “stuffing,” wherein a small proportion, ? 2%, of the nonmagnetic Ti4+ sites are occupied by excess Yb3+. We have carried out neutron spectroscopic measurements on a stoichiometric powder sample of Yb2Ti2O7, as well as amore »crushed single crystal with weak stuffing and an approximate composition of Yb2+xTi2–xO7+y with x = 0.046. All samples display three CEF transitions out of the GS, and the GS doublet itself is identified as primarily composed of mJ = ±1/2, as expected. However, stuffing at low temperatures in Yb2+xTi2–xO7+y induces a similar finite CEF lifetime as is induced in stoichiometric Yb2Ti2O7 by elevated temperature. In conclusion, an extended strain field exists about each local “stuffed” site, which produces a distribution of random CEF environments in the lightly stuffed Yb2+xTi2–xO7+y, in addition to producing a small fraction of Yb ions in defective environments with grossly different CEF eigenvalues and eigenvectors.« less

  7. Observations of the scale-dependent turbulence and evaluation of the flux–gradient relationship for sensible heat for a closed Douglas-fir canopy in very weak wind conditions

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Vickers, D.; Thomas, C. K.

    2014-09-16

    Observations of the scale-dependent turbulent fluxes, variances, and the bulk transfer parameterization for sensible heat above, within, and beneath a tall closed Douglas-fir canopy in very weak winds are examined. The daytime sub-canopy vertical velocity spectra exhibit a double-peak structure with peaks at timescales of 0.8 s and 51.2 s. A double-peak structure is also observed in the daytime sub-canopy heat flux co-spectra. The daytime momentum flux co-spectra in the upper bole space and in the sub-canopy are characterized by a relatively large cross-wind component, likely due to the extremely light and variable winds, such that the definition of amore »mean wind direction, and subsequent partitioning of the momentum flux into along- and cross-wind components, has little physical meaning. Positive values of both momentum flux components in the sub-canopy contribute to upward transfer of momentum, consistent with the observed sub-canopy secondary wind speed maximum. For the smallest resolved scales in the canopy at nighttime, we find increasing vertical velocity variance with decreasing timescale, consistent with very small eddies possibly generated by wake shedding from the canopy elements that transport momentum, but not heat. Unusually large values of the velocity aspect ratio within the canopy were observed, consistent with enhanced suppression of the horizontal wind components compared to the vertical by the very dense canopy. The flux–gradient approach for sensible heat flux is found to be valid for the sub-canopy and above-canopy layers when considered separately in spite of the very small fluxes on the order of a few W m?2 in the sub-canopy. However, single-source approaches that ignore the canopy fail because they make the heat flux appear to be counter-gradient when in fact it is aligned with the local temperature gradient in both the sub-canopy and above-canopy layers. While sub-canopy Stanton numbers agreed well with values typically reported in the literature, our estimates for the above-canopy Stanton number were much larger, which likely leads to underestimated modeled sensible heat fluxes above dark warm closed canopies.« less

  8. Novel mechanism for scavenging of hypochlorite involving a periplasmic methionine-rich peptide and methionine sulfoxide reductase

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Melnyk, Ryan A.; Youngblut, Matthew D.; Clark, Iain C.; Carlson, Hans K.; Wetmore, Kelly M.; Price, Morgan N.; Lavarone, Anthony T.; Deutschbauer, Adam M.; Arkin, Adam P.; Coates, John D.

    2015-05-12

    Reactive chlorine species (RCS) defense mechanisms are important for bacterial fitness in diverse environments. In addition to the anthropogenic use of RCS in the form of bleach, these compounds are also produced naturally through photochemical reactions of natural organic matter and in vivo by the mammalian immune system in response to invading microorganisms. To gain insight into bacterial RCS defense mechanisms, we investigated Azospira suillum strain PS, which produces periplasmic RCS as an intermediate of perchlorate respiration. Our studies identified an RCS response involving an RCS stress-sensing sigma/anti-sigma factor system (SigF/NrsF), a soluble hypochlorite-scavenging methionine-rich periplasmic protein (MrpX), and amore »putative periplasmic methionine sulfoxide reductase (YedY1). We investigated the underlying mechanism by phenotypic characterization of appropriate gene deletions, chemogenomic profiling of barcoded transposon pools, transcriptome sequencing, and biochemical assessment of methionine oxidation. Our results demonstrated that SigF was specifically activated by RCS and initiated the transcription of a small regulon centering around yedY1 and mrpX. A yedY1 paralog (yedY2) was found to have a similar fitness to yedY1 despite not being regulated by SigF. Markerless deletions of yedY2 confirmed its synergy with the SigF regulon. MrpX was strongly induced and rapidly oxidized by RCS, especially hypochlorite. Our results suggest a mechanism involving hypochlorite scavenging by sacrificial oxidation of the MrpX in the periplasm. Reduced MrpX is regenerated by the YedY methionine sulfoxide reductase activity. The phylogenomic distribution of this system revealed conservation in several Proteobacteria of clinical importance, including uropathogenic Escherichia coli and Brucella spp., implying a putative role in immune response evasion in vivo. In addition, bacteria are often stressed in the environment by reactive chlorine species (RCS) of either anthropogenic or natural origin, but little is known of the defense mechanisms they have evolved. Using a microorganism that generates RCS internally as part of its respiratory process allowed us to uncover a novel defense mechanism based on RCS scavenging by reductive reaction with a sacrificial methionine-rich peptide and redox recycling through a methionine sulfoxide reductase. This system is conserved in a broad diversity of organisms, including some of clinical importance, invoking a possible important role in innate immune system evasion.« less

  9. Molecular transformations of phenolic SOA during photochemical aging in the aqueous phase: competition among oligomerization, functionalization, and fragmentation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yu, L.; Smith, J.; Laskin, A.; George, K. M.; Anastasio, C.; Laskin, J.; Dillner, A. M.; Zhang, Q.

    2015-10-30

    Organic aerosol is formed and transformed in atmospheric aqueous phases (e.g., cloud and fog droplets and deliquesced airborne particles containing small amounts of water) through a multitude of chemical reactions. Understanding these reactions is important for a predictive understanding of atmospheric aging of aerosols and their impacts on climate, air quality, and human health. In this study, we investigate the chemical evolution of aqueous secondary organic aerosol (aqSOA) formed during reactions of phenolic compounds with two oxidants – the triplet excited state of an aromatic carbonyl (3C*) and hydroxyl radical (•OH). Changes in the molecular composition of aqSOA as amore »function of aging time are characterized using an offline nanospray desorption electrospray ionization mass spectrometer (nano-DESI MS) whereas the real-time evolution of SOA mass, elemental ratios, and average carbon oxidation state (OSC) are monitored using an online aerosol mass spectrometer (AMS). Our results indicate that oligomerization is an important aqueous reaction pathway for phenols, especially during the initial stage of photooxidation equivalent to ? 2 h irradiation under midday, winter solstice sunlight in northern California. At later reaction times functionalization (i.e., adding polar oxygenated functional groups to the molecule) and fragmentation (i.e., breaking of covalent bonds) become more important processes, forming a large variety of functionalized aromatic and open-ring products with higher OSC values. Fragmentation reactions eventually dominate the photochemical evolution of phenolic aqSOA, forming a large number of highly oxygenated open-ring molecules with carbon numbers (nC) below 6. The average nC of phenolic aqSOA decreases while average OSC increases over the course of photochemical aging. In addition, the saturation vapor pressures C*) of dozens of the most abundant phenolic aqSOA molecules are estimated. A wide range of C* values is observed, varying from -20 ?g m-3 for functionalized phenolic oligomers to > 10 ?g m-3 for small open-ring species. The detection of abundant extremely low volatile organic compounds (ELVOC) indicates that aqueous reactions of phenolic compounds are likely an important source of ELVOC in the atmosphere.« less

  10. Structural, thermal, magnetic, and electronic transport properties of the LaNi?(Ge1-xPx)? system

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Goetsch, R. J.; Anand, V. K.; Pandey, Abhishek; Johnston, D. C.

    2012-02-29

    Polycrystalline samples of LaNi?(Ge1-xPx)? (x=0,0.25,0.50,0.75,1) were synthesized and their properties investigated by x-ray diffraction (XRD) measurements at room temperature and by heat capacity Cp, magnetic susceptibility ?, and electrical resistivity ? measurements versus temperature T from 1.8 to 350 K. Rietveld refinements of powder XRD patterns confirm that these compounds crystallize in the body-centered-tetragonal ThCr?Si?-type structure (space group I4/mmm) with composition-dependent lattice parameters that slightly deviate from Vegard's law. The ?(T) measurements showed a positive temperature coefficient for all samples from 1.8 to 300 K, indicating that all compositions in this system are metallic. The low-T Cp measurements yield amore »rather large Sommerfeld electronic specific heat coefficient ?=12.4(2) mJ/mol K² for x=0, reflecting a large density of states at the Fermi energy that is comparable with the largest values found for the AFe?As? class of materials with the same crystal structure. The ? decreases approximately linearly with x to 7.4(1) mJ/mol K² for x=1. The ? measurements show nearly temperature-independent paramagnetic behavior across the entire range of compositions except for LaNi?Ge?, where a broad peak is observed at ?300 K from ?(T) measurements up to 1000 K that may arise from short-range antiferromagnetic correlations in a quasi-two-dimensional magnetic system. High-accuracy Padé approximants representing the Debye lattice heat capacity and Bloch-Grüneisen electron-phonon resistivity functions versus T are presented and are used to analyze our experimental Cp(T) and ?(T) data, respectively, for 1.8K?T?300 K. The T dependences of ? for all samples are well-described over this T range by the Bloch-Grüneisen model, although the observed ?(300 K) values are larger than calculated from this model. A significant T dependence of the Debye temperature determined from the Cp(T) data was observed for each composition. No clear evidence for bulk superconductivity or any other long-range phase transition was found for any of the LaNi?(Ge1-xPx)? compositions studied.« less

  11. Impact of induced seismic events on seal integrity, Texas Gulf Coast

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Nicot, Jean-Philippe; Meckel, Timothy A.; Carr, David A.; Oldenburg, Curtis M.

    2014-12-31

    Recent publications have suggested that large-scale CO2 injection could trigger earthquakes and that even small- to moderate-sized earthquakes may threaten the seal integrity of the injection zone, and potentially damage buildings and other surface structures. In this study, we compared seal thickness to estimated fault displacement due to a single hypothetical seismic event in a selected area of the Texas Gulf Coast comprising an offshore strip of state waters along two Texas counties. To evaluate the slip generated by a single seismic event, we compiled well log information on shale/sand sequences and seismic information on fault geometric characteristics of amore »section of Lower Miocene age. The section is thousands of feet thick and is overlain and underlain by marine shales (Amph. B and Anahuac, respectively) that are relatively easy to correlate between wells. The Amph. B. shale is the secondary and ultimate seal for all injection intervals in the Lower Miocene. Given its thickness, no realistic seismic event or small series of seismic events will offset it significantly. However, this may not be true of smaller local primary seals. An analysis of geophysical logs of a total of 71 wells yielded a total of 2,871 sand / shale binary intervals. An analysis of the dedicated 3D seismic survey counted 723 fault traces at five roughly horizontal horizons within the Lower Miocene Fault displacement estimated using the product of the fault length times an uncertain multiplier coefficient assumed to follow a triangular distribution with a 10-3 to 10-5 range and a mode of 8 × 10-5. We then compared estimated single-event fault displacements to seal thicknesses by means of a Monte-Carlo analysis. Only 1.8% of thickness/displacement pairs display a displacement greater than 20% of the seal thickness. Only 0.26% of the pairs result in a displacement of half the seal thickness and only 0.05% of thickness/displacement pairs result in a clear seal rupture. The next step was to compare the magnitude of the event generated by such a displacement to documented magnitudes of “large” earthquakes generated by waterflooding and fluid disposal. Based on this analysis, we conclude that seismicity that may arise from CO2 injection appears not to be a serious complication for CO2 storage integrity, at least in the Gulf Coast area.« less

  12. Utilizing rare earth elements as tracers in high TDS reservoir brines in CCS applications

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    McLing, Travis; Smith, William; Smith, Robert

    2014-12-31

    In this paper we report the result of research associated with the testing of a procedures necessary for utilizing natural occurring trace elements, specifically the Rare Earth Elements (REE) as geochemical tracers in Carbon Capture and Storage (CCS) applications. Trace elements, particularly REE may be well suited to serve as in situ tracers for monitoring geochemical conditions and the migration of CO?-charged waters within CCS storage systems. We have been conducting studies to determine the efficacy of using REE as a tracer and characterization tool in the laboratory, at a CCS analogue site in Soda Springs, Idaho, and at amore »proposed CCS reservoir at the Rock Springs Uplift, Wyoming. Results from field and laboratory studies have been encouraging and show that REE may be an effective tracer in CCS systems and overlying aquifers. In recent years, a series of studies using REE as a natural groundwater tracer have been conducted successfully at various locations around the globe. Additionally, REE and other trace elements have been successfully used as in situ tracers to describe the evolution of deep sedimentary Basins. Our goal has been to establish naturally occurring REE as a useful monitoring measuring and verification (MMV) tool in CCS research because formation brine chemistry will be particularly sensitive to changes in local equilibrium caused by the addition of large volumes of CO?. Because brine within CCS target formations will have been in chemical equilibrium with the host rocks for millions of years, the addition of large volumes of CO? will cause reactions in the formation that will drive changes to the brine chemistry due to the pH change caused by the formation of carbonic acid. This CO? driven change in formation fluid chemistry will have a major impact on water rock reaction equilibrium in the formation, which will impart a change in the REE fingerprint of the brine that can measured and be used to monitor in situ reservoir conditions. Our research has shown that the REE signature imparted to the formation fluid by the introduction of CO? to the formation, can be measured and tracked as part of an MMV program. Additionally, this REE fingerprint may serve as an ideal tracer for fluid migration, both within the CCS target formation, and should formation fluids migrate into overlying aquifers. However application of REE and other trace elements to CCS system is complicated by the high salt content of the brines contained within the target formations. In the United States by regulation, in order for a geologic reservoir to be considered suitable for carbon storage, it must contain formation brine with total dissolved solids (TDS) > 10,000 ppm, and in most cases formation brines have TDS well in excess of that threshold. The high salinity of these brines creates analytical problems for elemental analysis, including element interference with trace metals in Inductively Coupled Plasma Mass Spectroscopy (ICP-MS) (i.e. element mass overlap due to oxide or plasma phenomenon). Additionally, instruments like the ICP-MS that are sensitive enough to measure trace elements down to the parts per trillion level are quickly oversaturated when water TDS exceeds much more than 1,000 ppm. Normally this problem is dealt with through dilution of the sample, bringing the water chemistry into the instruments working range. However, dilution is not an option when analyzing these formation brines for trace metals, because trace elements, specifically the REE, which occur in aqueous solutions at the parts per trillion levels. Any dilution of the sample would make REE detection impossible. Therefore, the ability to use trace metals as in situ natural tracers in high TDS brines environments requires the development of methods for pre-concentrating trace elements, while reducing the salinity and associated elemental interference such that the brines can be routinely analyzed by standard ICP-MS methods. As part of the Big Sky Carbon Sequestration Project the INL-CAES has developed a rapid, easy to use proces