National Library of Energy BETA

Sample records for ntu nephelometric turbidity

  1. Microsoft Word - 2902ntu.dot

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    902-NTU (10-2004) Supersedes (6-2000) issue SNL COMPUTER BANNER Banner for all SNL Computing SF 2902-NTU (10-2004) WARNING NOTICE TO USERS This is a Federal computer system and is...

  2. Microsoft Word - 2902ntu.dot

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    902-NTU (10-2004) Supersedes (6-2000) issue SNL COMPUTER BANNER Banner for all SNL Computing SF 2902-NTU (10-2004) WARNING NOTICE TO USERS This is a Federal computer system and is the property of the United States Government. It is for authorized use only. Users (authorized or unauthorized) have no explicit or implicit expectation of privacy. Any or all uses of this system and all files on this system may be intercepted, monitored, recorded, copied, audited, inspected, and disclosed to

  3. Digital optical phase conjugation of fluorescence in turbid tissue

    SciTech Connect (OSTI)

    Vellekoop, Ivo M.; Cui Meng; Yang Changhuei

    2012-08-20

    We demonstrate a method for phase conjugating fluorescence. Our method, called reference free digital optical phase conjugation, can conjugate extremely weak, incoherent optical signals. It was used to phase conjugate fluorescent light originating from a bead covered with 0.5 mm of light-scattering tissue. The phase conjugated beam refocuses onto the bead and causes a local increase of over two orders of magnitude in the light intensity. Potential applications are in imaging, optical trapping, and targeted photochemical activation inside turbid tissue.

  4. Critical analysis of atmospheric turbidity and precipitable water at five Canadian stations

    SciTech Connect (OSTI)

    Garrison, J.; Gueymard, C.

    1997-12-31

    Global and diffuse radiation and surface meteorological measurements at Edmonton, Montreal, Port Hardy, Toronto and Winnipeg for the years 1977--1984 are analyzed to yield estimates of atmospheric precipitable water and turbidity. Three methods of estimating the precipitable water and two methods of estimating the turbidity are used and compared. Measurements of pyranometer response as a function of zenith angle are used to correct the global radiation measurements. Turbidity is corrected for the effect of circumsolar radiation included in the direct radiation obtained from the global and diffuse radiation measurements. A comparison with earlier precipitable water and turbidity results is included.

  5. File:06MTFShortTermWaterQualityStandardForTurbidity318Authorization...

    Open Energy Info (EERE)

    MTFShortTermWaterQualityStandardForTurbidity318Authorization.pdf Jump to: navigation, search File File history File usage Metadata File:06MTFShortTermWaterQualityStandardForTurbidi...

  6. Optical imaging through turbid media with a degenerate four-wave mixing correlation time gate

    DOE Patents [OSTI]

    Sappey, Andrew D. (Golden, CO)

    1998-04-14

    Optical imaging through turbid media is demonstrated using a degenerate four-wave mixing correlation time gate. An apparatus and method for detecting ballistic and/or snake light while rejecting unwanted diffusive light for imaging structures within highly scattering media are described. Degenerate four-wave mixing (DFWM) of a doubled YAG laser in rhodamine 590 is used to provide an ultrafast correlation time gate to discriminate against light that has undergone multiple scattering and therefore has lost memory of the structures within the scattering medium. Images have been obtained of a test cross-hair pattern through highly turbid suspensions of whole milk in water that are opaque to the naked eye, which demonstrates the utility of DFWM for imaging through turbid media. Use of DFWM as an ultrafast time gate for the detection of ballistic and/or snake light in optical mammography is discussed.

  7. Quantitative broadband absorption and scattering spectroscopy in turbid media by combined frequency-domain and steady state methodologies

    DOE Patents [OSTI]

    Tromberg, Bruce J.; Berger, Andrew J.; Cerussi, Albert E.; Bevilacqua, Frederic; Jakubowski, Dorota

    2008-09-23

    A technique for measuring broadband near-infrared absorption spectra of turbid media that uses a combination of frequency-domain and steady-state reflectance methods. Most of the wavelength coverage is provided by a white-light steady-state measurement, whereas the frequency-domain data are acquired at a few selected wavelengths. Coefficients of absorption and reduced scattering derived from the frequency-domain data are used to calibrate the intensity of the steady-state measurements and to determine the reduced scattering coefficient at all wavelengths in the spectral window of interest. The absorption coefficient spectrum is determined by comparing the steady-state reflectance values with the predictions of diffusion theory, wavelength by wavelength. Absorption spectra of a turbid phantom and of human breast tissue in vivo, derived with the combined frequency-domain and steady-state technique, agree well with expected reference values.

  8. Annotated bibliography: Marine geologic hazards of the Hawaiian Islands with special focus on submarine slides and turbidity currents

    SciTech Connect (OSTI)

    Normark, W.R.; Herring, H.H.

    1993-10-01

    This annotated bibliography was compiled to highlight the submarine geology of the Hawaiian Islands and identify known and potential marine geologic hazards with special emphasis on turbidity currents, submarine slides and tsunamis. Some references are included that are not specific to Hawaii but are needed to understand the geologic processes that can affect the integrity of submarine cables and other man-made structures. Entries specific to the Hawaiian Island area are shown in bold type.

  9. Apparatus and method for qualitative and quantitative measurements of optical properties of turbid media using frequency-domain photon migration

    DOE Patents [OSTI]

    Tromberg, B.J.; Tsay, T.T.; Berns, M.W.; Svaasand, L.O.; Haskell, R.C.

    1995-06-13

    Optical measurements of turbid media, that is media characterized by multiple light scattering, is provided through an apparatus and method for exposing a sample to a modulated laser beam. The light beam is modulated at a fundamental frequency and at a plurality of integer harmonics thereof. Modulated light is returned from the sample and preferentially detected at cross frequencies at frequencies slightly higher than the fundamental frequency and at integer harmonics of the same. The received radiance at the beat or cross frequencies is compared against a reference signal to provide a measure of the phase lag of the radiance and modulation ratio relative to a reference beam. The phase and modulation amplitude are then provided as a frequency spectrum by an array processor to which a computer applies a complete curve fit in the case of highly scattering samples or a linear curve fit below a predetermined frequency in the case of highly absorptive samples. The curve fit in any case is determined by the absorption and scattering coefficients together with a concentration of the active substance in the sample. Therefore, the curve fitting to the frequency spectrum can be used both for qualitative and quantitative analysis of substances in the sample even though the sample is highly turbid. 14 figs.

  10. Apparatus and method for qualitative and quantitative measurements of optical properties of turbid media using frequency-domain photon migration

    DOE Patents [OSTI]

    Tromberg, Bruce J.; Tsay, Tsong T.; Berns, Michael W.; Svaasand, Lara O.; Haskell, Richard C.

    1995-01-01

    Optical measurements of turbid media, that is media characterized by multiple light scattering, is provided through an apparatus and method for exposing a sample to a modulated laser beam. The light beam is modulated at a fundamental frequency and at a plurality of integer harmonics thereof. Modulated light is returned from the sample and preferentially detected at cross frequencies at frequencies slightly higher than the fundamental frequency and at integer harmonics of the same. The received radiance at the beat or cross frequencies is compared against a reference signal to provide a measure of the phase lag of the radiance and modulation ratio relative to a reference beam. The phase and modulation amplitude are then provided as a frequency spectrum by an array processor to which a computer applies a complete curve fit in the case of highly scattering samples or a linear curve fit below a predetermined frequency in the case of highly absorptive samples. The curve fit in any case is determined by the absorption and scattering coefficients together with a concentration of the active substance in the sample. Therefore, the curve fitting to the frequency spectrum can be used both for qualitative and quantitative analysis of substances in the sample even though the sample is highly turbid.

  11. Hybrid radiosity-SP{sub 3} equation based bioluminescence tomography reconstruction for turbid medium with low- and non-scattering regions

    SciTech Connect (OSTI)

    Chen, Xueli E-mail: jimleung@mail.xidian.edu.cn; Zhang, Qitan; Yang, Defu; Liang, Jimin E-mail: jimleung@mail.xidian.edu.cn

    2014-01-14

    To provide an ideal solution for a specific problem of gastric cancer detection in which low-scattering regions simultaneously existed with both the non- and high-scattering regions, a novel hybrid radiosity-SP{sub 3} equation based reconstruction algorithm for bioluminescence tomography was proposed in this paper. In the algorithm, the third-order simplified spherical harmonics approximation (SP{sub 3}) was combined with the radiosity equation to describe the bioluminescent light propagation in tissues, which provided acceptable accuracy for the turbid medium with both low- and non-scattering regions. The performance of the algorithm was evaluated with digital mouse based simulations and a gastric cancer-bearing mouse based in situ experiment. Primary results demonstrated the feasibility and superiority of the proposed algorithm for the turbid medium with low- and non-scattering regions.

  12. Development of an Integrated Raman and Turbidity Fiber Optic Sensor for the In-Situ Analysis of High Level Nuclear Waste

    SciTech Connect (OSTI)

    Gasbarro, Christina; Bello, Job M.; Bryan, Samuel A.; Lines, Amanda M.; Levitskaia, Tatiana G.

    2013-02-24

    Stored nuclear waste must be retrieved from storage, treated, separated into low- and high-level waste streams, and finally put into a disposal form that effectively encapsulates the waste and isolates it from the environment for a long period of time. Before waste retrieval can be done, waste composition needs to be characterized so that proper safety precautions can be implemented during the retrieval process. In addition, there is a need for active monitoring of the dynamic chemistry of the waste during storage since the waste composition can become highly corrosive. This work describes the development of a novel, integrated fiber optic Raman and light scattering probe for in situ use in nuclear waste solutions. The dual Raman and turbidity sensor provides simultaneous chemical identification of nuclear waste as well as information concerning the suspended particles in the waste using a common laser excitation source.

  13. Development of an Integrated Raman and Turbidity Fiber Optic Sensor for the In-Situ Analysis of High Level Nuclear Waste - 13532

    SciTech Connect (OSTI)

    Gasbarro, Christina; Bello, Job [EIC Laboratories, Inc., 111 Downey St., Norwood, MA, 02062 (United States)] [EIC Laboratories, Inc., 111 Downey St., Norwood, MA, 02062 (United States); Bryan, Samuel; Lines, Amanda; Levitskaia, Tatiana [Pacific Northwest National Laboratory, PO Box 999, Richland, WA, 99352 (United States)] [Pacific Northwest National Laboratory, PO Box 999, Richland, WA, 99352 (United States)

    2013-07-01

    Stored nuclear waste must be retrieved from storage, treated, separated into low- and high-level waste streams, and finally put into a disposal form that effectively encapsulates the waste and isolates it from the environment for a long period of time. Before waste retrieval can be done, waste composition needs to be characterized so that proper safety precautions can be implemented during the retrieval process. In addition, there is a need for active monitoring of the dynamic chemistry of the waste during storage since the waste composition can become highly corrosive. This work describes the development of a novel, integrated fiber optic Raman and light scattering probe for in situ use in nuclear waste solutions. The dual Raman and turbidity sensor provides simultaneous chemical identification of nuclear waste as well as information concerning the suspended particles in the waste using a common laser excitation source. (authors)

  14. Microsoft Word - Appendix B Bedrock GW Samples.doc

    Office of Legacy Management (LM)

    Analytical Results for Bedrock Groundwater Samples, January 2000 through April 2011 This page intentionally left blank Bedrock Groundwaters -- Upgradient -- 92-06 a,b ____________________________________________ Analyte Unit 10/30/00 10/10/01 ____________________________________________ Field Measurements Alkalinity mg/L 189 182 Conductivity c μmhos/cm 560 560 DO c mg/L 1.4 -- ORP c mV -51 -46 pH c s.u. 7.24 7.52 Temperature c C 11.3 11.6 Turbidity c NTU 0.84 4.3 Common Ions Ca mg/L 72.8 69.3

  15. MHK ISDB/Sensors/Turbidity Sensor 4112 | Open Energy Information

    Open Energy Info (EERE)

    Velocity Planar Measurement (Current), 3D Velocity Volumetric Measurement (Current), Density (Ice), Direction (Ice), Speed (Ice), Thickness (Ice), Pressure (Tidal), Sea Surface...

  16. Speckle contrast diffuse correlation tomography of complex turbid medium flow

    SciTech Connect (OSTI)

    Huang, Chong; Irwin, Daniel; Lin, Yu; Shang, Yu; He, Lian; Kong, Weikai; Yu, Guoqiang; Luo, Jia

    2015-07-15

    Purpose: Developed herein is a three-dimensional (3D) flow contrast imaging system leveraging advancements in the extension of laser speckle contrast imaging theories to deep tissues along with our recently developed finite-element diffuse correlation tomography (DCT) reconstruction scheme. This technique, termed speckle contrast diffuse correlation tomography (scDCT), enables incorporation of complex optical property heterogeneities and sample boundaries. When combined with a reflectance-based design, this system facilitates a rapid segue into flow contrast imaging of larger, in vivo applications such as humans. Methods: A highly sensitive CCD camera was integrated into a reflectance-based optical system. Four long-coherence laser source positions were coupled to an optical switch for sequencing of tomographic data acquisition providing multiple projections through the sample. This system was investigated through incorporation of liquid and solid tissue-like phantoms exhibiting optical properties and flow characteristics typical of human tissues. Computer simulations were also performed for comparisons. A uniquely encountered smear correction algorithm was employed to correct point-source illumination contributions during image capture with the frame-transfer CCD and reflectance setup. Results: Measurements with scDCT on a homogeneous liquid phantom showed that speckle contrast-based deep flow indices were within 12% of those from standard DCT. Inclusion of a solid phantom submerged below the liquid phantom surface allowed for heterogeneity detection and validation. The heterogeneity was identified successfully by reconstructed 3D flow contrast tomography with scDCT. The heterogeneity center and dimensions and averaged relative flow (within 3%) and localization were in agreement with actuality and computer simulations, respectively. Conclusions: A custom cost-effective CCD-based reflectance 3D flow imaging system demonstrated rapid acquisition of dense boundary data and, with further studies, a high potential for translatability to real tissues with arbitrary boundaries. A requisite correction was also found for measurements in the fashion of scDCT to recover accurate speckle contrast of deep tissues.

  17. MHK ISDB/Sensors/Turbidity Sensor 4705 | Open Energy Information

    Open Energy Info (EERE)

    Velocity Planar Measurement (Current), 3D Velocity Volumetric Measurement (Current), Density (Ice), Direction (Ice), Speed (Ice), Thickness (Ice), Pressure (Tidal), Sea Surface...

  18. Alluvial Groundwater -- Upgradient -- 92-05&

    Office of Legacy Management (LM)

    09 This page intentionally left blank Alluvial Groundwater -- Upgradient -- 92-05 a,b ______________________________________________________________ Analyte Unit 10/30/00 04/11/01 07/20/01 10/10/01 ______________________________________________________________ Field Measurements Alkalinity mg/L -- 270 321 303 Conductivity c μmhos/cm 1520 1250 1366 1350 DO c mg/L -- 7.7 -- -- ORP c mV 84 71 -- 38 pH c s.u. 7.05 7.66 6.42 6.99 Temperature c C 9.4 7.7 9.7 10 Turbidity c NTU 42.6 4.05 60.3 70.5

  19. Appendix H biomonitoring data table H-1.xls

    Office of Legacy Management (LM)

    Baseline Surface Water, Sediment, and Benthic Macroinvertebrate Samples This page intentionally left blank Table H-1: Biomonitoring Sediment and Surface Water Data a Sediment Surface Location Date Sampled Se (mg/kg) Se (µg/L) Se b (µg/L) Alkalinity b (mg/L) Conductivity (µmhos/cm) ORP (mV) pH (s.u.) Temperature (C) Turbidity (NTU) 10/06/04 3.3 3.7 3 273 1481 -- 8.1 14.5 -- 10/06/04 -- 3.6 2.9 -- -- -- -- -- -- 04/05/05 1.3 2.9 2.2 170 810 -- 7.92 12.08 38.5 10/11/05 1.9 3 2.8 -- -- -- -- --

  20. Bedrock Groundwaters -- Upgradient -- 92-06a,b

    Office of Legacy Management (LM)

    09 This page intentionally left blank Bedrock Groundwaters -- Upgradient -- 92-06 a,b ____________________________________________ Analyte Unit 10/30/00 10/10/01 ____________________________________________ Field Measurements Alkalinity mg/L 189 182 Conductivity c μmhos/cm 560 560 DO c mg/L 1.4 -- ORP c mV -51 -46 pH c s.u. 7.24 7.52 Temperature c C 11.3 11.6 Turbidity c NTU 0.84 4.3 Common Ions Ca mg/L 72.8 69.3 Chloride mg/L 2.15 2.44 Fluoride μg/L 124 242 Hardness mg/L 225 214 K mg/L 1.98

  1. Microsoft Word - S02459_2006Annual GW Rpt.doc

    Office of Legacy Management (LM)

    Page 1 Alluvial Groundwater -- Upgradient -- 92-05 a,b ______________________________________________________________ Analyte Unit 10/30/00 04/11/01 07/20/01 10/10/01 ______________________________________________________________ Field Measurements Alkalinity mg/L -- 270 321 303 Conductivity b µmhos/cm 1520 1250 1366 1350 DO b mg/L -- 7.7 -- -- ORP b mV 84 71 -- 38 pH b s.u. 7.05 7.66 6.42 6.99 Temperature b C 9.4 7.7 9.7 10 Turbidity b NTU 42.6 4.05 60.3 70.5 Common Ions Ca mg/L 266 214 206

  2. Microsoft Word - S02459_2006Annual GW Rpt.doc

    Office of Legacy Management (LM)

    Page 1 Bedrock Groundwaters -- Upgradient -- 92-06 a,b ____________________________________________ Analyte Unit 10/30/00 10/10/01 ____________________________________________ Field Measurements Alkalinity mg/L 189 182 Conductivity b µmhos/cm 560 560 DO b mg/L 1.4 -- ORP b mV -51 -46 pH b s.u. 7.24 7.52 Temperature b C 11.3 11.6 Turbidity b NTU 0.84 4.3 Common Ions Ca mg/L 72.8 69.3 Chloride mg/L 2.15 2.44 Fluoride µg/L 124 242 Hardness mg/L 225 214 K mg/L 1.98 1.81 Mg mg/L 10.5 9.99 Na mg/L

  3. Microsoft Word - S02459_2006Annual GW Rpt.doc

    Office of Legacy Management (LM)

    Baseline Surface Water and Sediment This page intentionally left blank Biomonitoring Data a Sediment Surface Location Date Sampled Se (mg/kg) Se (µg/L) Se b (µg/L) Alkalinity b (mg/L) Conductivity (µmhos/cm) pH (s.u.) Temperature (C) Turbidity (NTU) 10/06/04 3.3 3.7 3 273 1481 8.1 14.5 -- 10/06/04 -- 3.6 2.9 -- -- -- -- -- 04/05/05 1.3 2.9 2.2 170 810 7.92 12.08 38.5 10/11/05 1.9 3 2.8 -- -- -- -- -- 04/19/06 0.56 3.6EJ -- -- -- -- -- -- 10/06/04 3 1.6 1.2 292 1500 7.72 13.3 53.5 04/05/05

  4. Microsoft Word - S03623_2007AnnRep_091007.doc

    Office of Legacy Management (LM)

    Alluvial Groundwater -- Upgradient -- 92-05 a,b ______________________________________________________________ Analyte Unit 10/30/00 04/11/01 07/20/01 10/10/01 ______________________________________________________________ Field Measurements Alkalinity mg/L -- 270 321 303 Conductivity c μmhos/cm 1520 1250 1366 1350 DO c mg/L -- 7.7 -- -- ORP c mV 84 71 -- 38 pH c s.u. 7.05 7.66 6.42 6.99 Temperature c C 9.4 7.7 9.7 10 Turbidity c NTU 42.6 4.05 60.3 70.5 Common Ions Ca mg/L 266 214 206 207

  5. Microsoft Word - S03623_2007AnnRep_091007.doc

    Office of Legacy Management (LM)

    Bedrock Groundwaters -- Upgradient -- 92-06 a,b ____________________________________________ Analyte Unit 10/30/00 10/10/01 ____________________________________________ Field Measurements Alkalinity mg/L 189 182 Conductivity c μmhos/cm 560 560 DO c mg/L 1.4 -- ORP c mV -51 -46 pH c s.u. 7.24 7.52 Temperature c C 11.3 11.6 Turbidity c NTU 0.84 4.3 Common Ions Ca mg/L 72.8 69.3 Chloride mg/L 2.15 2.44 Fluoride μg/L 124 242 Hardness mg/L 225 214 K mg/L 1.98 1.81 Mg mg/L 10.5 9.99 Na mg/L 32.1

  6. Microsoft Word - S03623_2007AnnRep_091007.doc

    Office of Legacy Management (LM)

    I Analytical Results for Post-ROD Biomonitoring Baseline Surface Water and Sediment This page intentionally left blank Biomonitoring Data a Sediment Surface Water Surface Location Date Sampled Se (mg/kg) Se (µg/L) Se b (µg/L) Alkalinity b (mg/L) Conductivity (µmhos/cm) pH (s.u.) Temperature (C) Turbidity (NTU) 10/06/04 3.3 3.7 3 273 1481 8.1 14.5 -- 10/06/04 -- 3.6 2.9 -- -- -- -- -- 04/05/05 1.3 2.9 2.2 170 810 7.92 12.08 38.5 10/11/05 1.9 3 2.8 -- -- -- -- -- 04/19/06 0.56 3.6EJ -- -- -- --

  7. Microsoft Word - S06596_GW.doc

    Office of Legacy Management (LM)

    10 This page intentionally left blank Alluvial Groundwater -- Upgradient -- 92-05 a,b ______________________________________________________________ Analyte Unit 10/30/00 04/11/01 07/20/01 10/10/01 ______________________________________________________________ Field Measurements Alkalinity mg/L -- 270 321 303 Conductivity c μmhos/cm 1520 1250 1366 1350 DO c mg/L -- 7.7 -- -- ORP c mV 84 71 -- 38 pH c s.u. 7.05 7.66 6.42 6.99 Temperature c C 9.4 7.7 9.7 10 Turbidity c NTU 42.6 4.05 60.3 70.5

  8. Microsoft Word - S06596_GW.doc

    Office of Legacy Management (LM)

    10 This page intentionally left blank Bedrock Groundwaters -- Upgradient -- 92-06 a,b ____________________________________________ Analyte Unit 10/30/00 10/10/01 ____________________________________________ Field Measurements Alkalinity mg/L 189 182 Conductivity c μmhos/cm 560 560 DO c mg/L 1.4 -- ORP c mV -51 -46 pH c s.u. 7.24 7.52 Temperature c C 11.3 11.6 Turbidity c NTU 0.84 4.3 Common Ions Ca mg/L 72.8 69.3 Chloride mg/L 2.15 2.44 Fluoride μg/L 124 242 Hardness mg/L 225 214 K mg/L 1.98

  9. Integration of remote sensing and geographic information systems for Great Lakes water quality monitoring

    SciTech Connect (OSTI)

    Lathrop, R.G. Jr.

    1988-01-01

    The utility of three operational satellite remote sensing systems, namely, the Landsat Thematic Mapper (TM), the SPOT High Resolution Visible (HRV) sensors and the NOAA Advanced Very High Resolution Radiometer (AVHRR), were evaluated as a means of estimating water quality and surface temperature. Empirical calibration through linear regression techniques was used to relate near-simultaneously acquired satellite radiance/reflectance data and water quality observations obtained in Green Bay and the nearshore waters of Lake Michigan. Four dates of TM and one date each of SPOT and AVHRR imagery/surface reference data were acquired and analyzed. Highly significant relationships were identified between the TM and SPOT data and secchi disk depth, nephelometric turbidity, chlorophyll a, total suspended solids (TSS), absorbance, and surface temperature (TM only). The AVHRR data were not analyzed independently but were used for comparison with the TM data. Calibrated water quality image maps were input to a PC-based raster GIS package, EPPL7. Pattern interpretation and spatial analysis techniques were used to document the circulation dynamics and model mixing processes in Green Bay. A GIS facilitates the retrieval, query and spatial analysis of mapped information and provides the framework for an integrated operational monitoring system for the Great Lakes.

  10. Particle size analysis in a turbid media with a single-fiber, optical probe while using a visible spectrometer

    DOE Patents [OSTI]

    Canpolat, Murat; Mourant, Judith R.

    2003-12-09

    Apparatus and method for measuring scatterer size in a dense media with only a single fiber for both light delivery and collection are disclosed. White light is used as a source and oscillations of the detected light intensities are measured as a function of wavelength. The maximum and minimum of the oscillations can be used to determine scatterer size for monodisperse distributions of spheres when the refractive indices are known. In addition several properties of the probe relevant to tissue diagnosis are disclosed including the effects of absorption, a broad distribution of scatterers, and the depth probed.

  11. Sustainable Management of Flowback Water during Hydraulic Fracturing of Marcellus Shale for Natural Gas Production

    SciTech Connect (OSTI)

    Vidic, Radisav

    2015-01-24

    This study evaluated the feasibility of using abandoned mine drainage (AMD) as make- up water for the reuse of produced water for hydraulic fracturing. There is an abundance of AMD sources near permitted gas wells as documented in this study that can not only serve as makeup water and reduce the demand on high quality water resources but can also as a source of chemicals to treat produced water prior to reuse. The assessment of AMD availability for this purpose based on proximity and relevant regulations was accompanied by bench- and pilot-scale studies to determine optimal treatment to achieve desired water quality for use in hydraulic fracturing. Sulfate ions that are often present in AMD at elevated levels will react with Ba? and Sr? in produced water to form insoluble sulfate compounds. Both membrane microfiltration and gravity separation were evaluated for the removal of solids formed as a result of mixing these two impaired waters. Laboratory studies revealed that neither AMD nor barite formed in solution had significant impact on membrane filtration but that some produced waters contained submicron particles that can cause severe fouling of microfiltration membrane. Coagulation/flocculation was found to be an effective process for the removal of suspended solids and both bench- and pilot-scale studies revealed that optimal process conditions can consistently achieve the turbidity of the finished water below 5 NTU. Adjusting the blending ratio of AMD and produced water can achieve the desired effluent sulfate concentration that can be accurately predicted by chemical thermodynamics. Co-treatment of produced water and AMD will result in elevated levels of naturally occurring radioactive materials (NORM) in the solid waste generated in this process due to radium co-precipitation with barium sulfate. Laboratory studies revealed that the mobility of barite that may form in the subsurface due to the presence of sulfate in the fracturing fluid can be controlled by the addition of appropriate antiscalants.

  12. MHK ISDB/Instruments/SmartGuard | Open Energy Information

    Open Energy Info (EERE)

    4319: MIRA Visibility Sensor 3544: Oxygen Sensor 3835: Relative Humidity Sensor 3445: Solar Radiation Sensor 2770: Tide Sensor 5217: Turbidity Sensor 4112: Turbidity Sensor...

  13. TESTING OF A ROTARY MICROFILTER TO SUPPORT HANFORD APPLICATIONS

    SciTech Connect (OSTI)

    Poirier, M; David Herman, D; David Stefanko, D; Samuel Fink, S

    2008-06-26

    Savannah River National Laboratory (SRNL) researchers are investigating and developing a rotary microfilter for solid-liquid separation applications at the Savannah River Site (SRS). Because of the success of that work, the Hanford Site is evaluating the use of the rotary microfilter for its Supplemental Pretreatment process. The authors performed rotary filter testing with a full-scale, 25-disk unit with 0.5 {micro} filter media manufactured by Pall Corporation using a Hanford AN-105 simulant at solids loadings of 0.06, 0.29, and 1.29 wt%. The conclusions from this testing are: (1) The filter flux at 0.06 wt% solids reached a near constant value at an average of 0.26 gpm/ft{sup 2} (6.25 gpm total). (2) The filter flux at 0.29 wt% solids reached a near constant value at an average of 0.17 gpm/ft{sup 2} (4 gpm total). (3) The filter flux at 1.29 wt% solids reached a near constant value at an average of 0.10 gpm/ft{sup 2} (2.4 gpm total). (4) Because of differences in solids loadings, a direct comparison between crossflow filter flux and rotary filter flux is not possible. The data show the rotary filter produces a higher flux than the crossflow filter, but the improvement is not as large as seen in previous testing. (5) Filtrate turbidity measured < 4 NTU in all samples collected. (6) During production, the filter should be rinsed with filtrate or dilute caustic and drained prior to an extended shutdown to prevent the formation of a layer of settled solids on top of the filter disks. (7) Inspection of the seal faces after {approx} 140 hours of operation showed an expected amount of initial wear, no passing of process fluid through the seal faces, and very little change in the air channeling grooves on the stationary face. (8) Some polishing was observed at the bottom of the shaft bushing. The authors recommend improving the shaft bushing by holding it in place with a locking ring and incorporated grooves to provide additional cooling. (9) The authors recommend that CH2MHill Hanford test other pore size media to determine the optimum pore size for Hanford waste.

  14. ,"Liquefied U.S. Natural Gas Re-Exports to Turkey (Million Cubic Feet)"

    U.S. Energy Information Administration (EIA) Indexed Site

    Monthly","12/2015" ,"Release Date:","2/29/2016" ,"Next Release Date:","3/31/2016" ,"Excel File Name:","ngm_epg0_ere_nus-ntu_mmcfm.xls" ,"Available from Web Page:","http://tonto.eia.gov/dnav/ng/hist/ngm_epg0_ere_nus-ntu_mmcfm.htm" ,"Source:","Energy Information Administration" ,"For Help, Contact:","infoctr@eia.doe.gov" ,,"(202)

  15. ,"Liquefied U.S. Natural Gas Re-Exports to Turkey (Million Cubic Feet)"

    U.S. Energy Information Administration (EIA) Indexed Site

    Annual",2015 ,"Release Date:","2/29/2016" ,"Next Release Date:","3/31/2016" ,"Excel File Name:","ngm_epg0_ere_nus-ntu_mmcfa.xls" ,"Available from Web Page:","http://tonto.eia.gov/dnav/ng/hist/ngm_epg0_ere_nus-ntu_mmcfa.htm" ,"Source:","Energy Information Administration" ,"For Help, Contact:","infoctr@eia.doe.gov" ,,"(202) 586-8800",,,"2/26/2016 2:50:46

  16. Workbook Contents

    U.S. Energy Information Administration (EIA) Indexed Site

    Monthly","12/2015" ,"Release Date:","2/29/2016" ,"Next Release Date:","3/31/2016" ,"Excel File Name:","ngm_epg0_ere_nus-ntu_dmcfm.xls" ,"Available from Web Page:","http://tonto.eia.gov/dnav/ng/hist/ngm_epg0_ere_nus-ntu_dmcfm.htm" ,"Source:","Energy Information Administration" ,"For Help, Contact:","infoctr@eia.doe.gov" ,,"(202)

  17. Workbook Contents

    U.S. Energy Information Administration (EIA) Indexed Site

    Annual",2015 ,"Release Date:","2/29/2016" ,"Next Release Date:","3/31/2016" ,"Excel File Name:","ngm_epg0_ere_nus-ntu_dmcfa.xls" ,"Available from Web Page:","http://tonto.eia.gov/dnav/ng/hist/ngm_epg0_ere_nus-ntu_dmcfa.htm" ,"Source:","Energy Information Administration" ,"For Help, Contact:","infoctr@eia.doe.gov" ,,"(202) 586-8800",,,"2/26/2016 2:50:46

  18. Cross-flow versus counter-current flow packed-bed scrubbers: a mathematical analysis

    SciTech Connect (OSTI)

    Fthenakis, V.M.

    1996-02-01

    Little is known about the mass transfer properties of packing media exposed to a crossflow of gas and liquid, whereas there is abundant information related to counter-current scrubbers. This paper presents a theoretical analysis of mass transfer and hydrodynamics in cross- flow packed bed scrubbers and compares those with information available for counter current towers, so that the first can be evaluated and/or designed based on data derived for the second. Mathematical models of mass transfer in cross-flow and counter- current packed bed scrubbers are presented. From those, one can predict the removal effectiveness of a crossflow scrubber from the number of transfer units (NTU) calculated for a similar counterflow operation; alternatively, when the removal effectiveness in counterflow is known, one can predict the corresponding NTU in crossflow.

  19. Tae-Hyun Bae | Center for Gas SeparationsRelevant to Clean Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Technologies | Blandine Jerome Tae-Hyun Bae Previous Next List Bae Tae-Hyun Bae Previously: Postdoctoral Fellow, Department of Chemistry, University of California, Berkeley Presently: Assistant Professor, Nanyang Technological University, Singapore Email: thbae [at] ntu.edu.sg EFRC research: Carbon dioxide capture using metal organic framework membranes, both thin continuous films and mixed matrix membranes EFRC publications: Sumida, Kenji; Rogow, David L; Mason, Jarad A; McDonald, Thomas M;

  20. Microsoft Word - L15 01-22 Uranium Tranfers

    Office of Environmental Management (EM)

    To: Office of Nuclear Energy Department of Energy 1000 Independence Ave., SW Washington, DC 20585 From: Nan Swift Federal Affairs Manager National Taxpayers Union 108 N. Alfred Street Alexandria, VA 22314 Subject: Request for Information: Excess Uranium Management: Effects of DOE Transfers of Excess Uranium on Domestic Uranium Mining, Conversion, and Enrichment Industries To whom it may concern: On behalf of the members of the National Taxpayers Union (NTU), I write to express our concerns

  1. DE-FE0010141 | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    pressure, salinity, turbidity, bottom currents, and seafloor microseismicity) to ... The U.S. Bureau of Ocean Energy Management has used available industry data to identify ...

  2. Engineering faculty forum. Final report, June 1, 1993--May 31, 1994

    SciTech Connect (OSTI)

    Baldwin, L.V.

    1994-11-01

    The goal of the project was to develop and broadcast monthly one-hour teleconferences to support the professional development of engineering faculty. The {open_quotes}Engineering Faculty Forum{close_quotes} was available nationwide over the NTU Satellite Network and was also available from a C-Band Satellite. There was no cost to participate in the live teleconferences for the two year period. The programs were developed in response to a questionnaire sent to engineering faculty members across the United States. Copies of the flyers and a print out of each course participation form has been included as a part of this report.

  3. Building and Calibration of a FAST Model of the SWAY Prototype Floating Wind Turbine: Preprint

    SciTech Connect (OSTI)

    Koh, J. H.; Robertson, A.; Jonkman, J.; Driscoll, F.; Ng, E. Y. K.

    2013-09-01

    Present efforts to verify and validate aero-hydro-servo-elastic numerical simulation tools that predict the dynamic response of a floating offshore wind turbine are primarily limited to code-to-code comparisons or code-to-data comparisons using data from wind-wave basin tests. In partnership with SWAY AS, the National Renewable Energy Laboratory (NREL) installed scientific wind, wave, and motion measurement equipment on the 1/6.5th-scale prototype SWAY floating wind system to collect data to validate a FAST model of the SWAY design in an open-water condition. Nanyang Technological University (NTU), through a collaboration with NREL, assisted in this validation.

  4. Theoretical and experimental investigation of heat pipe solar collector

    SciTech Connect (OSTI)

    Azad, E.

    2008-09-15

    Heat pipe solar collector was designed and constructed at IROST and its performance was measured on an outdoor test facility. The thermal behavior of a gravity assisted heat pipe solar collector was investigated theoretically and experimentally. A theoretical model based on effectiveness-NTU method was developed for evaluating the thermal efficiency of the collector, the inlet, outlet water temperatures and heat pipe temperature. Optimum value of evaporator length to condenser length ratio is also determined. The modelling predictions were validated using experimental data and it shows that there is a good concurrence between measured and predicted results. (author)

  5. Comparison summary (key metrics and multiples)

    Energy Savers [EERE]

    ... Early Concern Over Slope Instability 10 (from McIver,1982) Cause Turbidity Currents Act as ... Documented Gas Release from the Seafloor 38 Sea surface Seafloor 100m ocean shear? 800m ...

  6. prs_vs_cgc.eps

    Office of Scientific and Technical Information (OSTI)

    ... Lett. 94, 0823002 (2005). 15 S.-Y. Jeon and G. D. Moore, Phys. Rev. C71, 034901 (2005); S. Turbide, C. Gale, S.-Y. Jeon and G. D. Moore, Phys. Rev. C72, 014906 (2005). 16 J. ...

  7. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... Schenke, Bjoern (5) Turbide, Simon (5) Heinz, Ulrich (4) Majumder, Abhijit (4) Paquet, Jean-Franois (4) Moore, Guy D. (3) Young, Clint (3) Bass, Steffen A. (2) Bourque, Alex (2) ...

  8. F-Area Acid/Caustic Basin groundwater monitoring report: Second quarter 1992

    SciTech Connect (OSTI)

    Thompson, C.Y.

    1992-09-01

    During second quarter 1992, samples from the six FAC monitoring wells at the F-Area Acid/Caustic Basin were analyzed for herbicides, indicator parameters, major ions, pesticides, radionuclides, turbidity, volatile organic compounds, and other constituents. Monitoring results that exceeded the US Environmental Protection Agency's Primary Drinking Water Standards (PDWS) or the Savannah River Site flagging criteria or turbidity standards during the quarter are the focus of this report.

  9. F-Area Acid/Caustic Basin groundwater monitoring report: Second quarter 1992

    SciTech Connect (OSTI)

    Thompson, C.Y.

    1992-09-01

    During second quarter 1992, samples from the six FAC monitoring wells at the F-Area Acid/Caustic Basin were analyzed for herbicides, indicator parameters, major ions, pesticides, radionuclides, turbidity, volatile organic compounds, and other constituents. Monitoring results that exceeded the US Environmental Protection Agency`s Primary Drinking Water Standards (PDWS) or the Savannah River Site flagging criteria or turbidity standards during the quarter are the focus of this report.

  10. Distillation efficiencies of an industrial-scale i-butane/n-butane fractionator

    SciTech Connect (OSTI)

    Klemola, K.T.; Ilme, J.K.

    1996-12-01

    Rarely published industrial-scale distillation efficiency data are presented. The Murphree tray efficiencies are determined from the i-butane/n-butane fractionator performance data. Point efficiencies, numbers of overall vapor phase transfer units, numbers of vapor and liquid phase transfer units, and liquid phase resistances of mass transfer are backcalculated from the Murphree tray efficiencies. Various efficiency prediction and scale-up methods have been tested against experimental results. A new model for the prediction of the numbers of vapor and liquid phase transfer units has been developed. The model can be applied to hydrocarbon systems at high pressure. The influence of the mass-transfer coefficients, the interfacial area, and the vapor and liquid residence times on mass transfer has been analyzed separately, and as a result the NTU correlations for vapor and liquid phases are obtained. The constants of the model can be obtained by fitting the model to experimental efficiency data from a similar system.

  11. Estimation of Stirling engine regenerator on the analogy of laminar oscillating flow in a circular pipe

    SciTech Connect (OSTI)

    Cho, K.S.; Lee, D.Y.; Ro, S.T.

    1995-12-31

    To design effective Stirling or other similar regenerative cycle machines, it is important to understand the heat transfer mechanism in the heat exchangers, especially in essential parts such as a regenerator. Most of the solutions for engineering were modelled under the assumption of an unidirectional steady flow; that is, during the first half of the regenerative cycle it flows in one direction with constant mass flow rate and during the second half of the cycle it flows in the other direction with the same mass flow rate. But its usefulness is limited by the available heat transfer data. Therefore, indirect experimental methods have been carried out for finding the Nusselt number. The basic idea of this method is to utilize two simple mathematical relations regarding regenerator effectiveness: one is expressed as a function of fluid inlet and outlet temperatures at both ends of the regenerator, and the other is expressed in the NTU (Number of Transfer Unit) number which is a function of mass flow rate, heat capacity and Nusselt number. Therefore, if one measures transient temperatures of the working fluid at both ends of the regenerator, it is possible to get the Nusselt number, and with these one can estimate effectiveness of the regenerator. However, the expression between regenerator effectiveness and NTU number is, in principle, applicable only to a classical counterflow heat exchanger composed of two unidirectional steady flows. The effect of oscillating flow characteristics, such as oscillation length and oscillation frequency, on the effectiveness of the regenerator has been neglected so far. By modelling a heat exchanger system (heater, cooler and regenerator) simply as an straight tube with specified boundary conditions, this paper analyzes the effect of oscillation length and frequency on the performance of the regenerator, and reviews the classical regenerator estimation method.

  12. Gated frequency-resolved optical imaging with an optical parametric amplifier

    DOE Patents [OSTI]

    Cameron, S.M.; Bliss, D.E.; Kimmel, M.W.; Neal, D.R.

    1999-08-10

    A system for detecting objects in a turbid media utilizes an optical parametric amplifier as an amplifying gate for received light from the media. An optical gating pulse from a second parametric amplifier permits the system to respond to and amplify only ballistic photons from the object in the media. 13 figs.

  13. Gated frequency-resolved optical imaging with an optical parametric amplifier

    DOE Patents [OSTI]

    Cameron, Stewart M.; Bliss, David E.; Kimmel, Mark W.; Neal, Daniel R.

    1999-01-01

    A system for detecting objects in a turbid media utilizes an optical parametric amplifier as an amplifying gate for received light from the media. An optical gating pulse from a second parametric amplifier permits the system to respond to and amplify only ballistic photons from the object in the media.

  14. Influence of the atmosphere on remotely sensed reflection from vegetation surfaces

    SciTech Connect (OSTI)

    Simmer, C.; Gerstl, S.A.W.

    1985-01-01

    Multiple scattering of solar radiation in a vegetation canopy is modelled equivalent to absorbing and scattering in a turbid medium with direction-dependent cross sections. Perturbations of plant reflection patterns due to atmospheric effects are computed at different altitudes and compared to the angular reflection characteristics caused by Lambertian surfaces of varying albedoes.

  15. Field experiments on an intelligent towed vehicle ``Flying Fish``

    SciTech Connect (OSTI)

    Koterayama, W.; Yamaguchi, S.; Nakamura, M.

    1995-12-31

    A depth, pitch and roll controllable towed vehicle, ``Flying Fish`` is being developed to measure the ocean current, temperature, salinity, dissolved oxygen, pH, turbidity, chlorophyll and total inorganic hydrocarbon. The first field experiments on its performance were carried out in the Japan sea last summer. The motion data of the ``Flying Fish`` are compared with those of numerical simulations.

  16. Modeling the performance of small capacity lithium bromide-water absorption chiller operated by solar energy

    SciTech Connect (OSTI)

    Saman, N.F.; Sa`id, W.A.D.K.

    1996-12-31

    An analysis of the performance of a solar operated small capacity (two-ton) Lithium Bromide-Water (LiBr-H{sub 2}O) absorption system is conducted. The analysis is based on the first law of thermodynamics with lithium bromide as the absorbent and water as the refrigerant. The effect of various parameters affecting the machine coefficient of performance under various operating conditions is reported. Coefficient of performance of up to 0.8 can be obtained using flat plate solar collectors with generator temperatures in the range of 80--95 C (176--203 F). Liquid heat exchangers with effectiveness based on an NTU of the order of one would be a good design choice. The chiller can save approximately 3,456 kWh/yr per a two-ton unit, and it will reduce emissions by 19 lb of NO{sub x}, 5,870 lb of CO{sub 2}, and 16 lb of SO{sub x} per year per machine.

  17. Process and system for treating waste water

    DOE Patents [OSTI]

    Olesen, Douglas E.; Shuckrow, Alan J.

    1978-01-01

    A process of treating raw or primary waste water using a powdered, activated carbon/aerated biological treatment system is disclosed. Effluent turbidities less than 2 JTU (Jackson turbidity units), zero TOC (total organic carbon) and in the range of 10 mg/l COD (chemical oxygen demand) can be obtained. An influent stream of raw or primary waste water is contacted with an acidified, powdered, activated carbon/alum mixture. Lime is then added to the slurry to raise the pH to about 7.0. A polyelectrolyte flocculant is added to the slurry followed by a flocculation period -- then sedimentation and filtration. The separated solids (sludge) are aerated in a stabilization sludge basin and a portion thereof recycled to an aerated contact basin for mixing with the influent waste water stream prior to or after contact of the influent stream with the powdered, activated carbon/alum mixture.

  18. Environmental applications of the particle analysis system

    SciTech Connect (OSTI)

    Moritz, E.J.; Hoffman, C.R.

    1993-09-28

    This study demonstrates the applicability of particle counting technology for analysis of various water treatment systems at the Rocky Flats Plant. The Particle Analysis System described in this study determined the water quality of samples from environmental remediation, stormwater treatment, and drinking water treatment operations. Samples were measured in either discrete or on-line mode. This data showed filtration efficiencies, particle counts, particle size distributions, and real-time treatment system performance. Particle counting proved more sensitive than the turbidimetric measurement technique commonly used by the water treatment industry. Particle counting is a two-dimensional measurement of counts and sizes, whereas turbidity is a one-dimensional measurement of water clarity. Samples showing identical turbidities could be distinguished easily with the Particle Analysis System. The Particle Analysis System proved to be an efficient and reliable water quality measurement tool, and it is applicable to a variety of water treatment systems at the Rocky Flats Plant.

  19. TESTING OF THE SPINTEK ROTARY MICROFILTER USING ACTUAL HANFORD WASTE SAMPLES

    SciTech Connect (OSTI)

    HUBER HJ

    2010-04-13

    The SpinTek rotary microfilter was tested on actual Hanford tank waste. The samples were a composite of archived Tank 241-AN-105 material and a sample representing single-shell tanks (SST). Simulants of the two samples have been used in non-rad test runs at the 222-S laboratory and at Savannah River National Laboratory (SRNL). The results of these studies are compared in this report. Two different nominal pore sizes for the sintered steel rotating disk filter were chosen: 0.5 and 0.1 {micro}m. The results suggest that the 0.5-{micro}m disk is preferable for Hanford tank waste for the following reasons: (1) The filtrate clarity is within the same range (<<4 ntu for both disks); (2) The filtrate flux is in general higher for the 0.5-{micro}m disk; and (3) The 0.1-{micro}m disk showed a higher likelihood of fouling. The filtrate flux of the actual tank samples is generally in the range of 20-30% compared to the equivalent non-rad tests. The AN-105 slurries performed at about twice the filtrate flux of the SST slurries. The reason for this difference has not been identified. Particle size distributions in both cases are very similar; comparison of the chemical composition is not conclusive. The sole hint towards what material was stuck in the filter pore holes came from the analysis of the dried flakes from the surface of the fouled 0.1-{micro}m disk. A cleaning approach developed by SRNL personnel to deal with fouled disks has been found adaptable when using actual Hanford samples. The use of 1 M nitric acid improved the filtrate flux by approximately two times; using the same simulants as in the non-rad test runs showed that the filtrate flux was restored to 1/2 of its original amount.

  20. Trace fossils of Marnoso-Arenacea Formation (Miocene), northern Italy: preliminary data

    SciTech Connect (OSTI)

    McBride, E.F.; Picard, M.D.

    1988-02-01

    Many horizons in the Marnoso-arenacea Formation contain rare to abundant trace fossils at numerous localities. Slope, fan, and basin-plain deposits have trace fossils dominated by the Nereites ichnofacies but include taxa from the Zoophycos ichnofacies plus Ohphiomorpha and Thalassinoides. Slope deposits contain Chondrites, Cosmorhaphe, Desmograpton, Helminthoida, Neonereites, Paleodictyon, Pelecypodichnus, Planolites, Punctorhaphe, and Scolicia; fan-channel deposits contain Chondrites and Planolites; fan-lobe deposits contain Chondrites, Ophiomorpha, Thalassinoides, Scolicia, and Zoophycos; and basin-plain deposits contain Chondrites, Helminthoida, Planolites, and Zoophycos. The distribution of hypichnial taxa may be in part the result of selective preservation (i.e., dependent on the depth of erosion by turbidity currents).

  1. Interim survey report, Wailua River hydropower, Kauai, Hawaii

    SciTech Connect (OSTI)

    Not Available

    1982-09-01

    Installation of hydroelectric facilities on the South Fork Wailua River three and five miles upstream of Wailua Falls on the Island of Kauai, Hawaii is proposed. The hydroelectric facilities would provide an additional source of energy for the island, effectively utilizing available waters. Addition of hydropower to the island's power system, which is primarily reliant on fuel and diesel oils, would diversify the system's base. Hydropower diversion would reduce flows downstream of the structures, affecting fishery, recreational, and aesthetic resources. Construction activities would disturb approximately 2.7 acres of cropland and create temporary turbidity downstream of the sites.

  2. Automated titration method for use on blended asphalts

    DOE Patents [OSTI]

    Pauli, Adam T. (Cheyenne, WY); Robertson, Raymond E. (Laramie, WY); Branthaver, Jan F. (Chatham, IL); Schabron, John F. (Laramie, WY)

    2012-08-07

    A system for determining parameters and compatibility of a substance such as an asphalt or other petroleum substance uses titration to highly accurately determine one or more flocculation occurrences and is especially applicable to the determination or use of Heithaus parameters and optimal mixing of various asphalt stocks. In a preferred embodiment, automated titration in an oxygen gas exclusive system and further using spectrophotometric analysis (2-8) of solution turbidity is presented. A reversible titration technique enabling in-situ titration measurement of various solution concentrations is also presented.

  3. Solar spectral measurements and modeling

    SciTech Connect (OSTI)

    Bird, R.E.; Hulstrom, R.L.

    1981-01-01

    A newly developed spectroradiometer for routine measurement of the solar spectra is described. This instrument measures the solar spectrum between 300 and 2500 nm in less than 2.5 min, with 0.7-nm resolution in the visible and 10-nm resolution in the infrared. Many examples of global, direct, and diffuse spectra are illustrated for Bedford, Mass. and Golden, Colo. The effects of air mass, turbidity, and sun tracking on the spectrum are presented, and radiative transfer modeling capabilities and comparisons between models and between models and experiment are discussed.

  4. Opportunities for Open Automated Demand Response in Wastewater Treatment Facilities in California - Phase II Report. San Luis Rey Wastewater Treatment Plant Case Study

    SciTech Connect (OSTI)

    Thompson, Lisa; Lekov, Alex; McKane, Aimee; Piette, Mary Ann

    2010-08-20

    This case study enhances the understanding of open automated demand response opportunities in municipal wastewater treatment facilities. The report summarizes the findings of a 100 day submetering project at the San Luis Rey Wastewater Treatment Plant, a municipal wastewater treatment facility in Oceanside, California. The report reveals that key energy-intensive equipment such as pumps and centrifuges can be targeted for large load reductions. Demand response tests on the effluent pumps resulted a 300 kW load reduction and tests on centrifuges resulted in a 40 kW load reduction. Although tests on the facility?s blowers resulted in peak period load reductions of 78 kW sharp, short-lived increases in the turbidity of the wastewater effluent were experienced within 24 hours of the test. The results of these tests, which were conducted on blowers without variable speed drive capability, would not be acceptable and warrant further study. This study finds that wastewater treatment facilities have significant open automated demand response potential. However, limiting factors to implementing demand response are the reaction of effluent turbidity to reduced aeration load, along with the cogeneration capabilities of municipal facilities, including existing power purchase agreements and utility receptiveness to purchasing electricity from cogeneration facilities.

  5. SLUDGE PARTICLE SEPAPATION EFFICIENCIES DURING SETTLER TANK RETRIEVAL INTO SCS-CON-230

    SciTech Connect (OSTI)

    DEARING JI; EPSTEIN M; PLYS MG

    2009-07-16

    The purpose of this document is to release, into the Hanford Document Control System, FA1/0991, Sludge Particle Separation Efficiencies for the Rectangular SCS-CON-230 Container, by M. Epstein and M. G. Plys, Fauske & Associates, LLC, June 2009. The Sludge Treatment Project (STP) will retrieve sludge from the 105-K West Integrated Water Treatment System (IWTS) Settler Tanks and transfer it to container SCS-CON-230 using the Settler Tank Retrieval System (STRS). The sludge will enter the container through two distributors. The container will have a filtration system that is designed to minimize the overflow of sludge fines from the container to the basin. FAI/09-91 was performed to quantify the effect of the STRS on sludge distribution inside of and overflow out of SCS-CON-230. Selected results of the analysis and a system description are discussed. The principal result of the analysis is that the STRS filtration system reduces the overflow of sludge from SCS-CON-230 to the basin by roughly a factor of 10. Some turbidity can be expected in the center bay where the container is located. The exact amount of overflow and subsequent turbidity is dependent on the density of the sludge (which will vary with location in the Settler Tanks) and the thermal gradient between the SCS-CON-230 and the basin. Attachment A presents the full analytical results. These results are applicable specifically to SCS-CON-230 and the STRS filtration system's expected operating duty cycles.

  6. H-Area Acid/Caustic Basin groundwater monitoring report. First quarter 1995

    SciTech Connect (OSTI)

    1995-06-01

    During first quarter 1995, samples collected from the four HAC monitoring wells at the H-Area Acid/Caustic Basin were analyzed for selected heavy metals, herbicides/pesticides, indicator parameters, major ions, radionuclide indicators, and other constituents. Monitoring results that exceeded the final Primary Drinking Water Standards (PDWS) or the Savannah River Site (SRS) flagging criteria or turbidity standard during third quarter are the focus of this report. Tritium exceeded the final PDWS in all four HAC wells during first quarter 1995. Carbon tetrachloride exceeded the final PDWS in well HAC 4. Aluminum exceeded its Flag 2 criterion in all four HAC wells. Iron was elevated in wells HAC 2 and 3. Total organic halogens was elevated in well HAC 3. The HAC 3 sample also exceeded the SRS turbidity standard. Groundwater flow direction in the water table beneath the H-Area Acid/Caustic Basin was to the northwest during first quarter 1995. This data is consistent with previous quarters, when the flow direction has been to the northwest or the north- northwest.

  7. Radionuclide tracers for the fate of metals in the Savannah estuary: River-ocean exchange processes

    SciTech Connect (OSTI)

    Olsen, C.R.; Thein, M.; Larsen, I.L.; Byrd, J.T.; Windom, H.L.

    1989-01-01

    Plutonium-238 from the US Department of Energy's Savannah River Plant labels riverborne particles, providing a unique opportunity for examining the fate of metals in estuaries and for tracing river-ocean exchange processes. Results indicate that plutonium and lead-210 are enriched on estuarine particles and that inputs of plutonium from oceanic sources greatly exceed inputs from riverborne or drainage-basin sources as far upstream as the landward limit of seawater penetration. We suggest that these radionuclides (and other chemically reactive metals) are being scavenged from oceanic water by sorption onto particles in turbid estuarine and coastal areas. Since estuaries, bays, mangroves, and intertidal areas serve as effective traps for fine particles and associated trace substances, these results have important implications concerning the disposal of chemically reactive substances in oceanic waters. 13 refs., 1 fig., 1 tab.

  8. Birefringence imaging in biological tissue using polarization sensitive optical coherent tomography

    DOE Patents [OSTI]

    De Boer, Johannes F. (Irvine, CA); Milner, Thomas E. (Austin, TX); Nelson, J. Stuart (Laguna Niguel, CA)

    2001-01-01

    Employing a low coherence Michelson interferometer, two dimensional images of optical birefringence in turbid samples as a function of depth are measured. Polarization sensitive detection of the signal formed by interference of backscattered light from the sample and a mirror or reference plane in the reference arm which defines a reference optical path length, give the optical phase delay between light propagating along the fast and slow axes of the birefringence sample. Images showing the change in birefringence in response to irradiation of the sample are produced as an example of the detection apparatus and methodology. The technique allow rapid, noncontact investigation of tissue or sample diagnostic imaging for various medical or materials procedures.

  9. Atmospheric transmittance model for photosynthetically active radiation

    SciTech Connect (OSTI)

    Paulescu, Marius; Stefu, Nicoleta; Gravila, Paul; Paulescu, Eugenia; Boata, Remus; Pacurar, Angel; Mares, Oana; Pop, Nicolina; Calinoiu, Delia

    2013-11-13

    A parametric model of the atmospheric transmittance in the PAR band is presented. The model can be straightforwardly applied for calculating the beam, diffuse and global components of the PAR solar irradiance. The required inputs are: air pressure, ozone, water vapor and nitrogen dioxide column content, ngstrm's turbidity coefficient and single scattering albedo. Comparison with other models and ground measured data shows a reasonable level of accuracy for this model, making it suitable for practical applications. From the computational point of view the calculus is condensed into simple algebra which is a noticeable advantage. For users interested in speed-intensive computation of the effective PAR solar irradiance, a PC program based on the parametric equations along with a user guide are available online at http://solar.physics.uvt.ro/srms.

  10. Range gated imaging experiments using gated intensifiers

    SciTech Connect (OSTI)

    McDonald, T.E. Jr.; Yates, G.J.; Cverna, F.H.; Gallegos, R.A.; Jaramillo, S.A.; Numkena, D.M.; Payton, J.; Pena-Abeyta, C.R.

    1999-03-01

    A variety of range gated imaging experiments using high-speed gated/shuttered proximity focused microchannel plate image intensifiers (MCPII) are reported. Range gated imaging experiments were conducted in water for detection of submerged mines in controlled turbidity tank test and in sea water for the Naval Coastal Sea Command/US Marine Corps. Field experiments have been conducted consisting of kilometer range imaging of resolution targets and military vehicles in atmosphere at Eglin Air Force Base for the US Air Force, and similar imaging experiments, but in smoke environment, at Redstone Arsenal for the US Army Aviation and Missile Command (AMCOM). Wavelength of the illuminating laser was 532 nm with pulse width ranging from 6 to 12 ns and comparable gate widths. These tests have shown depth resolution in the tens of centimeters range from time phasing reflected LADAR images with MCPII shutter opening.

  11. Turbidimetric determination of the total glucozinolate content of rape

    SciTech Connect (OSTI)

    Kononova, R.V.; Chaika, I.K.; Levitskii, A.P.; Lucashenok, E.V.

    1986-03-01

    The objective of the investigation was to develop a procedure for the determination of the total GZ (glucozinolate--non-nurishing substances found in rapeseed) content from the content of sulfate ion SO/sup 2 -4/which is formed in the fermentative hydrolysis of GZ, based on the degree of turbidity formed by the addition of a barium chloride solution in the presence of the surfactant Tween-80 (poly(20)ethoxysorbitan monooleate.). The supernatant liquid is used to determine the SO/sup 2 -4 -/ion before and after fermentative hydrolysis. The GZ content of the analyzed sample of rapeseed raw material was calculated from an equation. Data show that the precision, reliability, and reproducibility of the results obtained by the proposed method are satisfactory. The procedure can be sued for serial analysis in selection establishments as well as feed production plants.

  12. Compatibility of manufacturing process fluids with R-134a and polyolester lubricant. Final report

    SciTech Connect (OSTI)

    Cavestri, R.C.; Schooley, D.L.

    1996-07-01

    This report includes a broad list of processing fluids that are known to be used to manufacture air conditioning and refrigeration products. Sixty-four process fluids from this list were selected for compatibility studies with R-134a and ICI EMKARATE RL32H (32 ISO) polyolester lubricant. Solutions or suspensions of the process fluid residues in polyolester lubricant were heated for 14 days at 175{degrees}C (347{degrees}F) in evacuated sealed glass tubes containing only valve steel coupons. Miscibility tests were performed at 90 wt.% R-134a, 10 wt.% polyolester lubricant with process fluid residue contaminate and were scanned in 10{degrees}C (18{degrees}F) increments over a temperature range of ambient to -40{degrees}C (-40{degrees}F). Any sign of turbidity, haze formation or oil separation was considered the immiscibility point.

  13. An evaluation of the effect of volcanic eruption on the solar radiation at Australian and Canadian stations

    SciTech Connect (OSTI)

    Yatko, B.R.; Garrison, J.D.

    1996-11-01

    Peak (most probable) and average values of {angstrom}`s turbidity coefficient {beta} and peak (most probable) and average values of the diffuse index k{sub d} are obtained from the solar radiation data from 21 stations in Australia and 5 stations in Canada. These data exhibit clear increases in their values when the volcanic aerosols in the stratosphere increase following volcanic eruptions of sufficient magnitude. The effect of the eruptions of Fuego (1974), El Chichon (1982) and Pinatubo (1991) are seen most clearly in the data. The effect of lesser eruptions is also seen. The store of volcanic aerosols in the stratosphere shifts with the season so that scattering by volcanic aerosols in the spring half of the year is stronger than in the fall.

  14. Low-frequency elastic waves alter pore-scale colloid mobilization

    SciTech Connect (OSTI)

    Beckham, Richard Edward; Abdel-fattah, Amr I; Roberts, Peter M; Ibrahim, Reem; Tarimala, Sownitri

    2009-01-01

    Naturally occurring seismic events and artificially generated low-frequency elastic waves have been observed to alter the production rates of oil and water wells, sometimes increasing and sometimes decreasing production, and to influence the turbidity of water wells. TEe decreases in production are of particular concern - especially when artificially generated elastic waves are applied as a method for enhanced oil recovery. The exact conditions that result in a decrease in production remain unknown. While the underlying environment is certainly complex, the observed increase in water well turbidity after seismic events suggests the existence of a mechanism that can affect both the subsurface flow paths and mobilization of in-situ colloidal particles. This paper explores the macroscopic and microscopic effects of elastic wave stimulations on the release of colloidal particles and investigates the microscopic mechanism of particle release during stimulation. Experiments on a column packed with 1-mm borosilicate beads loaded with polystyrene microspheres demonstrate that low-frequency elastic wave stimulations enhance the mobilization of captured microspheres. Increasing the intensity of the stimulations increases the number of microspheres released and can also result in cyclical variations in effluent microsphere concentration during and after stimulations. Under a prolonged period of stimulation, the cyclical effluent variations coincided with fluctuations in the column pressure data. This behavior can be attributed to flow pathways fouling and/or rearrangements of the beads in the column. Optical microscopy observations of the beads during low frequency oscillations reveal that the individual beads rotate, thereby rubbing against each other and scraping off portions of the adsorbed microspheres. These results support the theory that mechanical interactions between soil grains are important mechanisms in flow path alteration and the mobilization of naturally occurring colloidal particles during elastic wave stimulation. These results also point to both continuous and discrete, en masse releases of colloidal particles.

  15. (Energy related studies utilizing microline thermochronology)

    SciTech Connect (OSTI)

    Not Available

    1991-01-01

    In our first year of the current funding cycle, we have investigated three interrelated aspects of K-feldspar thermochronology; (1) the Ar diffusion properties and microstructures of K-feldspars, (2) the thermal evolution of the Valles Caldera and (3) the continued development of microanalysis. Results of TEM and light microscopy on heated and unheated samples of MH-10 K-feldspar reveal three classes of substructure are present: (1) cross hatched extinction is common and there is almost no albite/pericline twinning, only tweed microstructure; (2) 5--10 vol. % of this K-feldspar are turbid zones with complex twin and tweed structures at the sub-micron scale and numerous dislocation and strain features; (3) about 20% of the K-feldspar is comprised of 0.01 {times} 0.2-1{mu}m albite exsolution lamellae. The network of fractured/turbid zones divides the sample into blocks of approximately 50 {mu}m and the separation between albite exsolution lamellae produce K-feldspar domains of the order 0.1 {mu}m. Independent crushing and diffusion experiments suggest the scale of the largest domain is order ten's of micron whereas the smallest domain size is inferred to be {approximately}0.1 {mu}m. Many, and perhaps most, alkali feldspars contain diffusion domains with activation energies that may vary by as much as 8 kcal/mol. An extraordinary consequence of even relatively small variations in activation energy between domains is that the shape of an age spectrum can change dramatically by varying the laboratory heating schedule. We have performed {sup 40}Ar/{sup 39}Ar age spectrum experiments on K-feldspar separated from Proterozoic quartz monzonite taken from a depth of 1.76 km down the VC-2B drill hole, Valles Caldera, north-central New Mexcio.

  16. [Energy related studies utilizing microline thermochronology]. Progress report, 1990--1991

    SciTech Connect (OSTI)

    Not Available

    1991-12-31

    In our first year of the current funding cycle, we have investigated three interrelated aspects of K-feldspar thermochronology; (1) the Ar diffusion properties and microstructures of K-feldspars, (2) the thermal evolution of the Valles Caldera and (3) the continued development of microanalysis. Results of TEM and light microscopy on heated and unheated samples of MH-10 K-feldspar reveal three classes of substructure are present: (1) cross hatched extinction is common and there is almost no albite/pericline twinning, only tweed microstructure; (2) 5--10 vol. % of this K-feldspar are turbid zones with complex twin and tweed structures at the sub-micron scale and numerous dislocation and strain features; (3) about 20% of the K-feldspar is comprised of 0.01 {times} 0.2-1{mu}m albite exsolution lamellae. The network of fractured/turbid zones divides the sample into blocks of approximately 50 {mu}m and the separation between albite exsolution lamellae produce K-feldspar domains of the order 0.1 {mu}m. Independent crushing and diffusion experiments suggest the scale of the largest domain is order ten`s of micron whereas the smallest domain size is inferred to be {approximately}0.1 {mu}m. Many, and perhaps most, alkali feldspars contain diffusion domains with activation energies that may vary by as much as 8 kcal/mol. An extraordinary consequence of even relatively small variations in activation energy between domains is that the shape of an age spectrum can change dramatically by varying the laboratory heating schedule. We have performed {sup 40}Ar/{sup 39}Ar age spectrum experiments on K-feldspar separated from Proterozoic quartz monzonite taken from a depth of 1.76 km down the VC-2B drill hole, Valles Caldera, north-central New Mexcio.

  17. Mobilization of colloidal particles by low-frequency dynamic stress stimulation

    SciTech Connect (OSTI)

    Beckham, Richard Edward; Amr, Abdel - Fattah I; Peter, Roberts M; Reem, Ibrahim; Tarimala, Sowmitri

    2009-01-01

    Naturally occurring seismic events and artificially generated low-frequency (1 to 500 Hertz) elastic waves have been observed to alter the production rates of oil and water wells, sometimes increasing and sometimes decreasing production, and to influence the turbidity of surface and well water. The decreases in production are of particular concern - especially when artificially generated elastic waves are applied as a method for enhanced oil recovery. The exact conditions that result in a decrease in production remain unknown. While the underlying environment is certainly complex, the observed increase in water well turbidity after natural seismic events suggests the existence of a mechanism that can affect both the subsurface flow paths and mobilization of in-situ colloidal particles. This paper explores the macroscopic and microscopic effects of low-frequency dynamic stress stimulations on the release of colloidal particles from an analog core representing an infinitesimal section along the propagation paths of an elastic wave. Experiments on a column packed with 1-mm borosilicate beads and loaded with polystyrene microspheres demonstrate that axial mechanical stress oscillations enhance the mobilization of captured microspheres. Increasing the amplitude of the oscillations increases the number of microspheres released and can also result in cyclical spikes in effluent microsphere concentration during stimulation. Under a prolonged period of stimulation, the cyclical effluent spikes coincided with fluctuations in the column pressure data, and continue at a diminished level after stimulation. This behavior can be attributed to rearrangements of the beads in the column, resulting in possible changes to the void space and/or tortuosity of the packing. Optical microscopy observations of the beads during low frequency oscillations reveal that individual beads rotate, thereby rubbing against each other and scraping away portions of the adsorbed microspheres. These results support the theory that mechanical interactions between porous matrix grains are important mechanisms in flow path alteration and the mobilization of naturally occurring colloidal particles during elastic wave stimulation. These results also point to both continuous and discrete, en masse releases of colloidal particles, perhaps due to circulation cells within the packing material.

  18. TANK 21 AND TANK 24 BLEND AND FEED STUDY: BLENDING TIMES, SETTLING TIMES, AND TRANSFERS

    SciTech Connect (OSTI)

    Lee, S.; Leishear, R.; Poirier, M.

    2012-05-31

    The Salt Disposition Integration (SDI) portfolio of projects provides the infrastructure within existing Liquid Waste facilities to support the startup and long term operation of the Salt Waste Processing Facility (SWPF). Within SDI, the Blend and Feed Project will equip existing waste tanks in the Tank Farms to serve as Blend Tanks where salt solutions of up to 1.2 million gallons will be blended in 1.3 million gallon tanks and qualified for use as feedstock for SWPF. In particular, Tanks 21 and 24 are planned to be used for blending and transferring to the SDI feed tank. These tanks were evaluated here to determine blending times, to determine a range of settling times for disturbed sludge, and to determine that the SWPF Waste Acceptance Criteria that less than 1200 mg/liter of solids will be entrained in salt solutions during transfers from the Tank 21 and Tank 24 will be met. Overall conclusions for Tank 21 and Tank 24 operations include: (1) Experimental correction factors were applied to CFD (computational fluid dynamics) models to establish blending times between approximately two and five hours. As shown in Phase 2 research, blending times may be as much as ten times greater, or more, if lighter fluids are added to heavier fluids (i.e., water added to salt solution). As the densities of two salt solutions converge this effect may be minimized, but additional confirmatory research was not performed. (2) At the current sludge levels and the presently planned operating heights of the transfer pumps, solids entrainment will be less than 1200 mg/liter, assuming a conservative, slow settling sludge simulant. (3) Based on theoretical calculations, particles in the density range of 2.5 to 5.0 g/mL must be greater than 2-4 {micro}m in diameter to ensure they settle adequately in 30-60 days to meet the SWPF feed criterion (<1200 mg/l). (4) Experimental tests with sludge batch 6 simulant and field turbidity data from a recent Tank 21 mixing evolution suggest the solid particles have higher density and/or larger size than indicated by previous analysis of SRS sludge and sludge simulants. (5) Tank 21 waste characterization, laboratory settling tests, and additional field turbidity measurements during mixing evolutions are recommended to better understand potential risk for extended (> 60 days) settling times in Tank 21.

  19. ROTARY FILTER FINES TESTING FOR SMALL COLUMN ION EXCHANGE

    SciTech Connect (OSTI)

    Herman, D.

    2011-08-03

    SRNL was requested to quantify the amount of 'fines passage' through the 0.5 micron membranes currently used for the rotary microfilter (RMF). Testing was also completed to determine if there is any additional benefit to utilizing a 0.1 micron filter to reduce the amount of fines that could pass through the filter. Quantifying of the amount of fines that passed through the two sets of membranes that were tested was accomplished by analyzing the filtrate by Inductively Coupled Plasma Atomic Emission Spectrometry (ICP-AES) for titanium. Even with preparations to isolate the titanium, all samples returned results of less than the instrument's detection limit of 0.184 mg/L. Test results show that the 0.5 micron filters produced a significantly higher flux while showing a negligible difference in filtrate clarity measured by turbidity. The first targeted deployment of the RMF is with the Small Column Ion Exchange (SCIX) at the Savannah River Site (SRS). SCIX uses crystalline silicotitanate (CST) to sorb cesium to decontaminate a clarified salt solution. The passage of fine particles through the filter membranes in sufficient quantities has the potential to impact the downstream facilities. To determine the amount of fines passage, a contract was established with SpinTek Filtration to operate a 3-disk pilot scale unit with prototypic filter disk and various feeds and two different filter disk membranes. SpinTek evaluated a set of the baseline 0.5 micron filter disks as well as a set of 0.1 micron filter disks to determine the amount of fine particles that would pass the membrane and to determine the flux each set produced. The membrane on both disk sets is manufactured by the Pall Corporation (PMM 050). Each set of disks was run with three feed combinations: prototypically ground CST, CST plus monosodium titanate (MST), and CST, MST, plus Sludge Batch 6 (SB6) simulant. Throughout the testing, samples of the filtrate were collected, measured for turbidity, and sent back to SRNL for analysis to quantify the amount of fines that passed through the membrane. It should be noted that even though ground CST was tested, it will be transferred to the Defense Waste Processing Facility (DWPF) feed tank and is not expected to require filtration.

  20. Environmental resources of selected areas of Hawaii: Geological hazards

    SciTech Connect (OSTI)

    Staub, W.P.; Reed, R.M.

    1995-03-01

    This report has been prepared to make available and archive the background scientific data and related information collected on geologic hazards during the preparation of the environmental impact statement (EIS) for Phases 3 and 4 of the Hawaii Geothermal Project (HGP) as defined by the state of Hawaii in its April 1989 proposal to Congress. The US Department of Energy (DOE) published a notice withdrawing its Notice of Intent to prepare the HGP-EIS. Since the state of Hawaii is no longer pursuing or planning to pursue the HGP, DOE considers the project to be terminated. This report presents a review of current information on geologic hazards in the Hawaiian Islands. Interrelationships among these hazards are discussed. Probabilities of occurrence of given geologic hazards are provided in various regions where sufficient geologic or historical data are available. Most of the information contained herein is compiled from recent US Geological Survey (USGS) publications and USGS open-file reports related to this project. This report describes the natural geologic hazards present in the area and does not represent an assessment of environmental impacts. Geologic hazards originate both onshore and offshore. Onshore geologic hazards such as volcanic eruptions, earthquakes, surface rupture, landslides, uplift and subsidence occur mainly on the southern third of the island of Hawaii (hereinafter referred to as Hawaii). Offshore geologic hazards are more widely distributed throughout the Hawaiian Islands. Examples of offshore geologic hazards are submarine landslides, turbidity currents, and seismic sea waves (tsunamis).

  1. Application of advanced reservoir characterization, simulation, and production optimization strategies to maximize recovery in slope and basin clastic reservoirs, west Texas (Delaware Basin). Annual progress report, March 31, 1995--March 31, 1996

    SciTech Connect (OSTI)

    Dutton, S.P.; Hovorka, S.D.; Cole, A.G.

    1996-08-01

    The objective of this Class III project is to demonstrate that detailed reservoir characterization of clastic reservoirs in basinal sandstones of the Delaware Mountain Group in the Delaware Basin of West Texas and New Mexico is a cost-effective way to recover more of the original oil in place by strategic infill-well placement and geologically based field development. Reservoirs in the Delaware Mountain Group have low producibility (average recovery <14 percent of the original oil in place) because of a high degree of vertical and lateral heterogeneity caused by depositional processes and post-depositional diagenetic modification. Detailed correlations of the Ramsey sandstone reservoirs in Geraldine Ford field suggest that lateral sandstone continuity is less than interpreted by previous studies. The degree of lateral heterogeneity in the reservoir sandstones suggests that they were deposited by eolian-derived turbidites. According to the eolian-derived turbidite model, sand dunes migrated across the exposed shelf to the shelf break during sea-level lowstands and provided well sorted sand for turbidity currents or grain flows into the deep basin.

  2. Surfactant/detergent titration analysis method and apparatus for machine working fluids, surfactant-containing wastewater and the like

    DOE Patents [OSTI]

    Smith, D.D.; Hiller, J.M.

    1998-02-24

    The present invention is an improved method and related apparatus for quantitatively analyzing machine working fluids and other aqueous compositions such as wastewater which contain various mixtures of cationic, neutral, and/or anionic surfactants, soluble soaps, and the like. The method utilizes a single-phase, non-aqueous, reactive titration composition containing water insoluble bismuth nitrate dissolved in glycerol for the titration reactant. The chemical reaction of the bismuth ion and glycerol with the surfactant in the test solutions results in formation of micelles, changes in micelle size, and the formation of insoluble bismuth soaps. These soaps are quantified by physical and chemical changes in the aqueous test solution. Both classical potentiometric analysis and turbidity measurements have been used as sensing techniques to determine the quantity of surfactant present in test solutions. This method is amenable to the analysis of various types of new, in-use, dirty or decomposed surfactants and detergents. It is a quick and efficient method utilizing a single-phase reaction without needing a separate extraction from the aqueous solution. It is adaptable to automated control with simple and reliable sensing methods. The method is applicable to a variety of compositions with concentrations from about 1% to about 10% weight. It is also applicable to the analysis of waste water containing surfactants with appropriate pre-treatments for concentration. 1 fig.

  3. Characterization of highly scattering media by measurement of diffusely backscattered polarized light

    DOE Patents [OSTI]

    Hielscher, Andreas H. (Brooklyn, NY); Mourant, Judith R. (Los Alamos, NM); Bigio, Irving J. (Los Alamos, NM)

    2000-01-01

    An apparatus and method for recording spatially dependent intensity patterns of polarized light that is diffusely backscattered from highly scattering media are described. These intensity patterns can be used to differentiate different turbid media, such as polystyrene-sphere and biological-cell suspensions. Polarized light from a He-Ne laser (.lambda.=543 nm) is focused onto the surface of the scattering medium, and a surface area of approximately 4.times.4 cm centered on the light input point is imaged through polarization analysis optics onto a CCD camera. A variety of intensity patterns may be observed by varying the polarization state of the incident laser light and changing the analyzer configuration to detect different polarization components of the backscattered light. Experimental results for polystyrene-sphere and Intralipid suspensions demonstrate that the radial and azimuthal variations of the observed pattern depend on the concentration, size, and anisotropy factor, g, of the particles constituting the scattering medium. Measurements performed on biological cell suspensions show that intensity patterns can be used to differentiate between suspensions of cancerous and non-cancerous cells. Introduction of the Mueller-matrix for diffusely backscattered light, permits the selection of a subset of measurements which comprehensively describes the optical properties of backscattering media.

  4. Sedimentological, mineralogical and geochemical definition of oil-shale facies in the lower Parachute Creek Member of Green River Formation, Colorado

    SciTech Connect (OSTI)

    Cole, R.D.

    1984-04-01

    Sedimentological, mineralogical and geochemical studies of two drill cores penetrating the lower Saline zone of the Parachute Creek Member (middle L-4 oil-shale zone through upper R-2 zone) of the Green River Formation in north-central Piceance Creek basin, Colorado, indicate the presence of two distinct oil-shale facies. The most abundant facies has laminated stratification and frequently occurs in the L-4, L-3 and L-2 oil-shale zones. The second, and subordinate facies, has ''streaked and blebby'' stratification and is most abundant in the R-4, R-3 and R-2 zones. Laminated oil shale originated by slow, regular sedimentation during meromictic phases of ancient Lake Uinta, whereas streaked and blebby oil shale was deposited by episodic, non-channelized turbidity currents. Laminated oil shale has higher contents of nahcolite, dawsonite, quartz, K-feldspar and calcite, but less dolomite/ankerite and albite than streaked and blebby oil shale. Ca-Mg-Fe carbonate minerals in laminated oil shale have more variable compositions than those in streaked and blebby shales. Streaked and blebby oil shale has more kerogen and a greater diversity of kerogen particles than laminated oil shale. Such variations may produce different pyrolysis reactions when each shale type is retorted.

  5. CFPL installs products pipeline with directional drilling

    SciTech Connect (OSTI)

    1996-01-01

    Central Florida Pipeline Company (CFPL), a subsidiary of GATX Terminals Corp., Tampa, FL, has used directional drilling under seven water bodies in Hillsborough, Polk and Osceola Counties in constructing its new pipeline from Tampa to Orlando. Primary reason for using directional drilling is to protect the environment by minimizing water turbidity while the 16-inch diameter, 109-mile refined petroleum products pipeline is being installed. Total cost of the project is pegged at $68.5 million. Directional drilling enabled the pipe to be placed about 20 feet below the bottom of: The Alafia River in Riverview with 999 feet drilled; Port Sutton Channel near the Port of Tampa with 2,756 feet drilled; Reedy Creek Swamp at the intersection of Interstate 4 and Highway 192 which had 1,111 feet drilled; Wetland {number_sign}70 southwest of Lake Wales with 1,575 feet drilled; Peace River south of Bartow had 2,470 feet drilled; Bonnet Creek west of Kissimmee had 693 feet drilled. Shingle Creek near the borders of Osceola and Orange Counties with 1,700 feet drilled. This paper reviews the design plans for construction and the emergency response plans should a rupture occur in the line.

  6. Modeling and forecasting the distribution of Vibrio vulnificus in Chesapeake Bay

    SciTech Connect (OSTI)

    Jacobs, John M.; Rhodes, M.; Brown, C. W.; Hood, Raleigh R.; Leight, A.; Long, Wen; Wood, R.

    2014-11-01

    The aim is to construct statistical models to predict the presence, abundance and potential virulence of Vibrio vulnificus in surface waters. A variety of statistical techniques were used in concert to identify water quality parameters associated with V. vulnificus presence, abundance and virulence markers in the interest of developing strong predictive models for use in regional oceanographic modeling systems. A suite of models are provided to represent the best model fit and alternatives using environmental variables that allow them to be put to immediate use in current ecological forecasting efforts. Conclusions: Environmental parameters such as temperature, salinity and turbidity are capable of accurately predicting abundance and distribution of V. vulnificus in Chesapeake Bay. Forcing these empirical models with output from ocean modeling systems allows for spatially explicit forecasts for up to 48 h in the future. This study uses one of the largest data sets compiled to model Vibrio in an estuary, enhances our understanding of environmental correlates with abundance, distribution and presence of potentially virulent strains and offers a method to forecast these pathogens that may be replicated in other regions.

  7. Analysis of clear hour solar irradiation for seven Canadian stations

    SciTech Connect (OSTI)

    Garrison, J.; Sahami, K.

    1995-12-31

    Hourly global and diffuse irradiation and corresponding surface meteorological data have been analyzed for the seven Canadian stations at Edmonton, Goose Bay, Montreal, Port Hardy, Resolute, Toronto, and Winnipeg. The variation of the most probable clear hour values of clearness index k{sub t}, diffuse index k{sub d}, direct beam index k{sub b}, and Angstrom turbidity coefficient {beta} with solar elevation, atmospheric precipitable water, and snow depth are obtained. Values of these quantities are presented which are consistent with the attenuation and scattering of solar radiation by the atmosphere which is expected. The most probable values of {beta} tend to be lower than the average values of {beta} recently reported by Gueymard. The data indicate a drift in the calibration of the instruments used for measurements of the irradiation data for the stations at Goose Bay and Resolute. The data for the other five stations indicate that the instrument calibration is maintained over the years of the data. 4 refs., 8 figs., 5 tabs.

  8. Surfactant/detergent titration analysis method and apparatus for machine working fluids, surfactant-containing wastewater and the like

    DOE Patents [OSTI]

    Smith, Douglas D. (Knoxville, TN); Hiller, John M. (Oak Ridge, TN)

    1998-01-01

    The present invention is an improved method and related apparatus for quantitatively analyzing machine working fluids and other aqueous compositions such as wastewater which contain various mixtures of cationic, neutral, and/or anionic surfactants, soluble soaps, and the like. The method utilizes a single-phase, non-aqueous, reactive titration composition containing water insoluble bismuth nitrate dissolved in glycerol for the titration reactant. The chemical reaction of the bismuth ion and glycerol with the surfactant in the test solutions results in formation of micelles, changes in micelle size, and the formation of insoluble bismuth soaps. These soaps are quantified by physical and chemical changes in the aqueous test solution. Both classical potentiometric analysis and turbidity measurements have been used as sensing techniques to determine the quantity of surfactant present in test solutions. This method is amenable to the analysis of various types of new, in-use, dirty or decomposed surfactants and detergents. It is a quick and efficient method utilizing a single-phase reaction without needing a separate extraction from the aqueous solution. It is adaptable to automated control with simple and reliable sensing methods. The method is applicable to a variety of compositions with concentrations from about 1% to about 10% weight. It is also applicable to the analysis of waste water containing surfactants with appropriate pre-treatments for concentration.

  9. Operation and performance of the Supercritical Fluids Reactor (SFR)

    SciTech Connect (OSTI)

    Hanush, R.G.; Rice, S.F.; Hunter, T.B.; Aiken, J.D.

    1995-11-01

    The Supercritical Fluids Reactor (SFR) at Sandia National Laboratories, CA has been developed to examine and solve engineering, process, and fundamental chemistry issues regarding the development of supercritical water oxidation (SCWO). This report details the experimental apparatus, procedures, analytical methods used in these experiments, and performance characteristics of the reactor. The apparatus consists of pressurization, feed, preheat, reactor, cool down, and separation subsystems with ancillary control and data acquisition hardware and software. Its operating range is from 375 - 650{degrees} at 3250 - 6300 psi with resident times from 0.09 to 250 seconds. Procedures required for experimental operations are described. They include maintenance procedures conducted between experiments, optical alignment for acquisition of spectroscopic data, setup of the experiment, reactor start up, experimental operations, and shutdown of apparatus. Analytical methods used are Total Organic Carbon analysis, Gas Chromatography, ion probes, pH probes, turbidity measurements and in situ Raman spectroscopy. Experiments conducted that verify the accuracy of measurement and sampling methods are described.

  10. Water quality evaluation and geochemical assessment of iron, manganese, and arsenic in a landfill site

    SciTech Connect (OSTI)

    Pisigan, R.A. Jr.

    1995-12-31

    Several monitoring wells at a landfill site were sampled for water quality parameters to determine the nature of groundwater contamination. The landfill, located beneath a limestone and dolomitic bedrock, has been used for about 20 years for trash and garbage disposal. The monitoring parameters include major cations and anions, as well as iron, manganese, arsenic, and other parameters measured in the field to characterize the subsurface conditions. Groundwater samples collected near the landfill and downgradient locations had higher levels of iron, manganese, arsenic, alkalinity, hardness than those samples from an upgradient well. The downgradient and on-site samples were also more acidic and turbid, The dissolved oxygen data tend to suggest reducing conditions in the leachate environment. The elevated groundwater concentrations of the three metals, especially iron, were most probably caused by the acidity generated by carbon dioxide and organic acids released from microbial degradation of organic compounds dumped into the landfill. The acidic pH led to the dissolution of iron, manganese, and arsenic bearing mineral phases. The buffering reactions of limestone and dolomite to neutralize the acidic degradation products increased the hardness cations, Ca{sup +2} and Mg{sup +2}. Inorganic speciation modeling indicates that iron, manganese, and arsenic predominantly exist as Fe {sup +2}, Mn{sup +2}, and H{sub 3}AsO{sub 3}. The possible presence of organic complexes of iron was discussed, but could be modeled due to lack of appropriate equilibrium constant data.

  11. Manipulating subsurface colloids to enhance cleanups of DOE waste sites. 1997 annual progress report

    SciTech Connect (OSTI)

    Gschwend, P.M.

    1997-01-01

    'This research is aimed at (a) developing improved understandings of the processes involved in holding colloids immobile in subsurface media, and (b) exploring the prospects for mobilizing such colloids to enhance cleanups. These colloids are important because they are the many contaminants of concern. chief sorbent media for The following briefly describes the efforts manuscript (currently submitted to Environmental also appended. in the last year. A draft Science and Technology) is Mechanisms Controlling Colloid Releases (Swartz) Using aquifer materials from a Southeastern Coastal Plain site, the authors have explored the mechanisms which control the releases of attached colloids into the groundwater flow. First, the authors have completed electron microscopy observations regarding the intimate particle:particle juxtapositions in the solids (Swartz et al. Geochim. Cosmochim. Acta 61, 707, 1997.) Next, by flushing these aquifer sands with various aqueous solutions, the authors have found that the bulk of the attached colloids appear to be (a) bound to one another via intermediary amorphous iron oxyhydroxides, and (b) attracted to the other colloids by juxtapositions of oppositely charged phases (manuscript submitted to Environ. Sci. Technol. and attached.) The authors suspect that this combination of inter-colloid interactions may be especially important in geologically young deposits where diagenetic processes have not produced highly crystalline solids yet. As a result of these observations and laboratory manipulations, the authors believe the authors understand the steps necessary to initiate colloid mobilization at such a groundwater site. First, one must apply solution constituents which are suited to dissolving a limited portion of the amorphous iron oxyhydroxides. The authors have accomplished this using 0.5 mM ascorbic acid (i.e., vitamin C.) Next, one must reverse the surface charges of either the negatively charged alumino-silicate clays or the adjacent positively charged iron oxyhydroxides. The authors have used 0.5 \\265m phosphate solutions (pH 5.2) to drive the iron oxyhydroxides to a net negative surface charge. By working at only millimolar levels, the resulting total solution ionic strength is still low enough to permit the corresponding expanded double layers to push the now like-charge colloids apart. In the laboratory, this results in a sustained presence of about 2 mg colloids per liter of flushing solution for at least many tens of pore volumes. In the author''s continuing efforts, he has returned to the field site, where the aquifer solids were initially collected, and tested the possibility of using such ascorbic acid-phosphate solutions to mobilize colloids in the ground. Efforts have proven successful as measured by the presence of turbidity in suitably altered flushing solutions (and the absence of turbidity in control tests). The author is now completing measurements of the ancillary parameters necessary to interpret the field tests.'

  12. Duck Valley Reservoirs Fish Stocking and Operation and Maintenance, 2006-2007 Annual Progress Report.

    SciTech Connect (OSTI)

    Sellman, Jake; Dykstra, Tim

    2009-05-11

    The Duck Valley Reservoirs Fish Stocking and Operations and Maintenance (DV Fisheries) project is an ongoing resident fish program that serves to partially mitigate the loss of anadromous fish that resulted from downstream construction of the hydropower system. The project's goals are to enhance subsistence fishing and educational opportunities for Tribal members of the Shoshone-Paiute Tribes and provide resident fishing opportunities for non-Tribal members. In addition to stocking rainbow trout (Oncorhynchus mykiss) in Mountain View, Lake Billy Shaw, and Sheep Creek Reservoirs, the program is also designed to maintain healthy aquatic conditions for fish growth and survival, to provide superior facilities with wilderness qualities to attract non-Tribal angler use, and to offer clear, consistent communication with the Tribal community about this project as well as outreach and education within the region and the local community. Tasks for this performance period are divided into operations and maintenance plus monitoring and evaluation. Operation and maintenance of the three reservoirs include fences, roads, dams and all reservoir structures, feeder canals, water troughs and stock ponds, educational signs, vehicles and equipment, and outhouses. Monitoring and evaluation activities included creel, gillnet, wildlife, and bird surveys, water quality and reservoir structures monitoring, native vegetation planting, photo point documentation, control of encroaching exotic vegetation, and community outreach and education. The three reservoirs are monitored in terms of water quality and fishery success. Sheep Creek Reservoir was very unproductive this year as a fishery. Fish morphometric and water quality data indicate that the turbidity is severely impacting trout survival. Lake Billy Shaw was very productive as a fishery and received good ratings from anglers. Mountain View was also productive and anglers reported a high number of quality sized fish. Water quality (specifically dissolved oxygen and temperature) is the main limiting factor in our fisheries.

  13. Duck Valley Reservoirs Fish Stocking and Operation and Maintenance, 2005-2006 Annual Progress Report.

    SciTech Connect (OSTI)

    Sellman, Jake; Dykstra, Tim

    2009-05-11

    The Duck Valley Reservoirs Fish Stocking and Operations and Maintenance (DV Fisheries) project is an ongoing resident fish program designed to enhance both subsistence fishing, educational opportunities for Tribal members of the Shoshone-Paiute Tribes, and recreational fishing facilities for non-Tribal members. In addition to stocking rainbow trout (Oncorhynchus mykiss) in Mountain View, Lake Billy Shaw, and Sheep Creek Reservoirs, the program also intends to afford and maintain healthy aquatic conditions for fish growth and survival, to provide superior facilities with wilderness qualities to attract non-Tribal angler use, and to offer clear, consistent communication with the Tribal community about this project as well as outreach and education within the region and the local community. Tasks for this performance period are divided into operations and maintenance plus monitoring and evaluation. Operation and maintenance of the three reservoirs include fences, roads, dams and all reservoir structures, feeder canals, water troughs and stock ponds, educational signs, vehicles and equipment, and outhouses. Monitoring and evaluation activities included creel, gillnet, wildlife, and bird surveys, water quality and reservoir structures monitoring, native vegetation planting, photo point documentation, control of encroaching exotic vegetation, and community outreach and education. The three reservoirs are monitored in terms of water quality and fishery success. Sheep Creek Reservoir was the least productive as a result of high turbidity levels and constraining water quality parameters. Lake Billy Shaw trout were in poorer condition than in previous years potentially as a result of water quality or other factors. Mountain View Reservoir trout exhibit the best health of the three reservoirs and was the only reservoir to receive constant flows of water.

  14. Environmental Resources of Selected Areas of Hawaii: Geological Hazards (DRAFT)

    SciTech Connect (OSTI)

    Staub, W.P.

    1994-06-01

    This report has been prepared to make available and archive the background scientific data and related information collected on geologic hazards during the preparation of the environmental impact statement (EIS) for Phases 3 and 4 of the Hawaii Geothermal Project (HGP) as defined by the state of Hawaii in its April 1989 proposal to Congress. The U.S. Department of Energy (DOE) published a notice in the Federal Register on May 17, 1994 (Fed Regis. 5925638) withdrawing its Notice of Intent (Fed Regis. 575433) of February 14, 1992, to prepare the HGP-EIS. Since the state of Hawaii is no longer pursuing or planning to pursue the HGP, DOE considers the project to be terminated This report presents a review of current information on geologic hazards in the Hawaiian Islands. Interrelationships among these hazards are discussed. Probabilities of occurrence of given geologic hazards are provided in various regions where sufficient geologic or historical data are available. Most of the information contained herein is compiled from recent U.S. Geological Survey (USGS) publications and open-file reports. This report describes the natural geologic hazards present in the area and does not represent an assessment of environmental impacts. Geologic hazards originate both onshore and offshore. Onshore geologic hazards such as volcanic eruptions, earthquakes, surface rupture, landslides, uplift, and subsidence occur mainly on the southern third of the island of Hawaii (hereinafter referred to as Hawaii). Offshore geologic hazards are more widely distributed throughout the Hawaiian Islands. Examples of offshore geologic hazards are submarine landslides, turbidity currents, and seismic sea waves (tsunamis). First, overviews of volcanic and earthquake activity, and details of offshore geologic hazards is provided for the Hawaiian Islands. Then, a more detailed discussion of onshore geologic hazards is presented with special emphasis on the southern third of Hawaii and the east rift zone of Kilauea.

  15. Particle Restabilization in Silica/PEG/Ethanol Suspensions: How Strongly do Polymers Need To Adsorb To Stabilize Against Aggregation?

    SciTech Connect (OSTI)

    Kim, So Youn; Zukoski, Charles F.

    2014-09-24

    We study the effects of increasing the concentration of a low molecular weight polyethylene glycol on the stability of 44 nm diameter silica nanoparticles suspended in ethanol. Polymer concentration, c{sub p}, is increased from zero to that characterizing the polymer melt. Particle stability is accessed through measurement of the particle second-virial coefficient, B{sub -2}, performed by light scattering and ultrasmall angle X-ray scattering (USAXS). The results show that at low polymer concentration, c{sub p} < 3 wt %, B{sub -2} values are positive, indicating repulsive interactions between particles. B{sub -2} decreases at intermediate concentrations (3 wt % < c{sub p} < 50 wt %), and particles aggregates are formed. At high concentrations (50 wt % < c{sub p}) B{sub -2} increases and stabilizes at a value expected for hard spheres with a diameter near 44 nm, indicating the particles are thermodynamically stable. At intermediate polymer concentrations, rates of aggregation are determined by measuring time-dependent changes in the suspension turbidity, revealing that aggregation is slowed by the necessity of the particles diffusing over a repulsive barrier in the pair potential. The magnitude of the barrier passes through a minimum at c{sub p} {approx} 12 wt % where it has a value of {approx}12kT. These results are understood in terms of a reduction of electrostatic repulsion and van der Waals attractions with increasing c{sub p}. Depletion attractions are found to play a minor role in particle stability. A model is presented suggesting displacement of weakly adsorbed polymer leads to slow aggregation at intermediate concentration, and we conclude that a general model of depletion restabilization may involve increased strength of polymer adsorption with increasing polymer concentration.

  16. Opportunities for Automated Demand Response in California Wastewater Treatment Facilities

    SciTech Connect (OSTI)

    Aghajanzadeh, Arian; Wray, Craig; McKane, Aimee

    2015-08-30

    Previous research over a period of six years has identified wastewater treatment facilities as good candidates for demand response (DR), automated demand response (Auto-­DR), and Energy Efficiency (EE) measures. This report summarizes that work, including the characteristics of wastewater treatment facilities, the nature of the wastewater stream, energy used and demand, as well as details of the wastewater treatment process. It also discusses control systems and automated demand response opportunities. Furthermore, this report summarizes the DR potential of three wastewater treatment facilities. In particular, Lawrence Berkeley National Laboratory (LBNL) has collected data at these facilities from control systems, submetered process equipment, utility electricity demand records, and governmental weather stations. The collected data were then used to generate a summary of wastewater power demand, factors affecting that demand, and demand response capabilities. These case studies show that facilities that have implemented energy efficiency measures and that have centralized control systems are well suited to shed or shift electrical loads in response to financial incentives, utility bill savings, and/or opportunities to enhance reliability of service. In summary, municipal wastewater treatment energy demand in California is large, and energy-­intensive equipment offers significant potential for automated demand response. In particular, large load reductions were achieved by targeting effluent pumps and centrifuges. One of the limiting factors to implementing demand response is the reaction of effluent turbidity to reduced aeration at an earlier stage of the process. Another limiting factor is that cogeneration capabilities of municipal facilities, including existing power purchase agreements and utility receptiveness to purchasing electricity from cogeneration facilities, limit a facility’s potential to participate in other DR activities.

  17. Quantification of Libby Reservoir Levels Needed to Maintain or Enhance Reservoir Fisheries, 1985 Annual Report.

    SciTech Connect (OSTI)

    Chisholm, Ian

    1985-01-01

    The goal was to quantify seasonal water levels needed to maintain or enhance the reservoir fishery in Libby. This report summarizes data collected from July 1984 through July 1985, and, where appropriate, presents data collected since 1983. The Canada, Rexford, and Tenmile areas of the reservoir are differentially affected by drawdown. Relative changes in water volume and surface area are greatest in the Canada area and smallest in the Tenmile area. Reservoir morphology and hydraulics probably play a major role in fish distribution through their influence on water temperature. Greatest areas of habitat with optimum water temperature for Salmo spp. and kokanee occurred during the spring and fall months. Dissolved oxygen, pH and conductivity levels were not limiting during any sampling period. Habitat enhancement work was largely unsuccessful. Littoral zone vegetation plantings did not survive well, primarily the result of extreme water level fluctuations. Relative abundances of fish species varied seasonally within and between the three areas. Water temperature is thought to be the major influence in fish distribution patterns. Other factors, such as food availability and turbidity, may mitigate its influence. Sampling since 1975 illustrates a continued increase in kokanee numbers and a dramatic decline in redside shiners. Salmo spp., bull trout, and burbot abundances are relatively low while peamouth and coarsescale sucker numbers remain high. A thermal dynamics model and a trophic level components model will be used to quantify the impact of reservoir operation on the reservoir habitat, primary production, secondary production and fish populations. Particulate carbon will be used to track energy flow through trophic levels. A growth-driven population dynamics simulation model that will estimate the impacts of reservoir operation on fish population dynamics is also being considered.

  18. Enrichment of Microbial Electrolysis Cell Biocathodes from Sediment Microbial Fuel Cell Bioanodes

    SciTech Connect (OSTI)

    Pisciotta, JM; Zaybak, Z; Call, DF; Nam, JY; Logan, BE

    2012-07-18

    Electron-accepting (electrotrophic) biocathodes were produced by first enriching graphite fiber brush electrodes as the anodes in sediment-type microbial fuel cells (sMFCs) using two different marine sediments and then electrically inverting the anodes to function as cathodes in two-chamber bioelectrochemical systems (BESs). Electron consumption occurred at set potentials of -439 mV and -539 mV (versus the potential of a standard hydrogen electrode) but not at -339 mV in minimal media lacking organic sources of energy. Results at these different potentials were consistent with separate linear sweep voltammetry (LSV) scans that indicated enhanced activity (current consumption) below only ca. -400 mV. MFC bioanodes not originally acclimated at a set potential produced electron-accepting (electrotrophic) biocathodes, but bioanodes operated at a set potential (+11 mV) did not. CO, was removed from cathode headspace, indicating that the electrotrophic biocathodes were autotrophic. Hydrogen gas generation, followed by loss of hydrogen gas and methane production in one sample, suggested hydrogenotrophic methanogenesis. There was abundant microbial growth in the biocathode chamber, as evidenced by an increase in turbidity and the presence of microorganisms on the cathode surface. Clone library analysis of 16S rRNA genes indicated prominent sequences most similar to those of Eubacterium limosum (Butyribacterium methylotrophicum), Desulfovibrio sp. A2, Rhodococcus opacus, and Gemmata obscuriglobus. Transfer of the suspension to sterile cathodes made of graphite plates, carbon rods, or carbon brushes in new BESs resulted in enhanced current after 4 days, demonstrating growth by these microbial communities on a variety of cathode substrates. This report provides a simple and effective method for enriching autotrophic electrotrophs by the use of sMFCs without the need for set potentials, followed by the use of potentials more negative than -400 mV.

  19. Lower granite GIS data description and collection guidelines

    SciTech Connect (OSTI)

    Gordon, J.L.; Evans, B.J.; Perry, E.M.

    1995-12-01

    The Lower Granite Geographic Information System (GIS) was developed jointly by the US Army Corps of Engineers (USCOE) Walla Walla District and the Pacific Northwest Laboratory (PNL). The goal of the project is to use GIS technology to analyze impacts of the drawdown mitigation option on the physical and biological environment of the Lower Granite Reservoir. The drawdown mitigation option is based on the hypothesis that faster juvenile salmon travel to the ocean would result in higher juvenile survival and greater smolt-to-adult return ratios; to accomplish this, reservoir elevations would be lowered to increase channel velocities. Altering the elevation of the reservoirs on the Snake River is expected to have a variety of impacts to the Physical environment including changes to water velocity, temperature, dissolved gases, and turbidity. The GIS was developed to evaluate these changes and the resulting impacts on the anadromous and resident fish of the Snake River, as well as other aquatic organisms and terrestrial wildlife residing in the adjacent riparian areas. The Lower Granite GIS was developed using commercial hardware and software and is supported by a commercial relational database. Much of the initial system development involved collecting and incorporating data describing the river channel characteristics, hydrologic properties, and aquatic ecology. Potentially meaningful data for the Lower Granite GIS were identified and an extensive data search was performed. Data were obtained from scientists who are analyzing the habitats, limnology, and hydrology of the Snake River. The next six sections of this document describe the bathymetry, fish abundance, substrate, sediment chemistry, and channel hydrology data.

  20. Umatilla River Basin Anadromous Fish Habitat Enhancement Project: 1990 Annual Report.

    SciTech Connect (OSTI)

    Scheeler, Carl A.

    1991-01-01

    The Umatilla habitat improvement program is funded under the Northwest Power Planning Council`s Columbia River Basin Fish and Wildlife Program measure 704 (d) (1) 34.02, and targets the improvement of water quality and the restoration of riparian areas, spawning and rearing habitat of steelhead, spring and fall chinook and coho salmon. The Confederated Tribes of the Umatilla Indian Reservation are responsible for enhancing stream reaches within the Reservation boundaries as guided by an implementation plan developed cooperatively with the Oregon Department of Fish and Wildlife and the USDA Forest Service, Umatilla National Forest. Treatment areas included the lower 4 miles of Meacham Creek, the lower {1/4} mile of Boston Canyon Creek, and the Umatilla River between RM 78.5 and 80. The upper {1/2} of the Meacham Creek project area including Boston Canyon Creek, which were initially enhanced during 1989, were reentered for maintenance and continued enhancements. Approximately 2400 cu. yds. of boulders and 1000 cu. yds. of riprap was used in the construction of in-stream, stream bank and flood plain structures and in the anchoring of large organic debris (LOD) placements. In-stream structures were designed to increase instream cover and channel stability and develop of a defined thalweg to focus low summer flows. Flood plain structures were designed to reduce sediment inputs and facilitate deposition on flood plains. Riparian recovery was enhanced through the planting of over 1000 willow cuttings and 400 lbs. of grass seed mix and through the exclusion of livestock from the riparian corridor with 4.5 miles of high tensile smooth wire fence. Photo documentation and elevational transects were used to monitor changes in channel morphology and riparian recovery at permanent standardized points throughout the projects. Water quality (temperature and turbidity) data was collected at locations within the project area and in tributaries programmed for future enhancements.

  1. Application of turbidite facies of the Stevens Oil Zone for reservoir management, Elk Hills Field, California

    SciTech Connect (OSTI)

    Reid, S.A.; Thompson, T.W.; McJannet, G.S.

    1996-12-31

    A detailed depositional model for the uppermost sand reservoirs of the Stevens Oil Zone, Elk Hills Field, California, contains three facies: turbidite channel-fill sand bodies, overbank Sandstone and mudstone, and pelagic and hemipelagic siliceous shale. Sand bodies are the primary producing facies and consist of layered, graded sandstone with good permeability. The presence of incipient anticlines with subsea relief in the late Miocene resulted in deposition of lenticular and sinuous sand Was within structurally created channels. Relief of these structural channels was low when the earliest sand bodies were deposited, leading to a wide channel complex bounded by broad overbank deposits of moderate to low permeability. As deposition proceeded, increased structural relief constrained the channels, resulting in narrower sand body width and relatively abrupt channel terminations against very low permeability siliceous shale. With post-Miocene uplift and differential compaction, stratigraphic mounding of sand bodies helped create structural domes such as the 24Z reservoir. Stratigraphic traps including the 26R reservoir were also created. Such traps vary in seal quality from very effective to leaky, depending on the lateral transition from sand bodies to siliceous shale. Application of the Elk Hills turbidity model (1) provides a framework for monitoring production performance in the 24Z and Northwest Stevens waterflood projects; and for tracking gas migration into and out of the 26R reservoir, (2) helps b identify undeveloped locations in the 26R reservoir ideally suited for horizontal wells, (3) has led to the identification of two new production trends in the 29R area, and (4) makes possible the development of exploration plays in western Elk Hills.

  2. Application of turbidite facies of the Stevens Oil Zone for reservoir management, Elk Hills Field, California

    SciTech Connect (OSTI)

    Reid, S.A.; Thompson, T.W. ); McJannet, G.S. )

    1996-01-01

    A detailed depositional model for the uppermost sand reservoirs of the Stevens Oil Zone, Elk Hills Field, California, contains three facies: turbidite channel-fill sand bodies, overbank Sandstone and mudstone, and pelagic and hemipelagic siliceous shale. Sand bodies are the primary producing facies and consist of layered, graded sandstone with good permeability. The presence of incipient anticlines with subsea relief in the late Miocene resulted in deposition of lenticular and sinuous sand Was within structurally created channels. Relief of these structural channels was low when the earliest sand bodies were deposited, leading to a wide channel complex bounded by broad overbank deposits of moderate to low permeability. As deposition proceeded, increased structural relief constrained the channels, resulting in narrower sand body width and relatively abrupt channel terminations against very low permeability siliceous shale. With post-Miocene uplift and differential compaction, stratigraphic mounding of sand bodies helped create structural domes such as the 24Z reservoir. Stratigraphic traps including the 26R reservoir were also created. Such traps vary in seal quality from very effective to leaky, depending on the lateral transition from sand bodies to siliceous shale. Application of the Elk Hills turbidity model (1) provides a framework for monitoring production performance in the 24Z and Northwest Stevens waterflood projects; and for tracking gas migration into and out of the 26R reservoir, (2) helps b identify undeveloped locations in the 26R reservoir ideally suited for horizontal wells, (3) has led to the identification of two new production trends in the 29R area, and (4) makes possible the development of exploration plays in western Elk Hills.

  3. Duck Valley Reservoirs Fish Stocking and O&M, Annual Progress Report 2007-2008.

    SciTech Connect (OSTI)

    Sellman, Jake; Perugini, Carol

    2009-02-20

    The Duck Valley Reservoirs Fish Stocking and Operations and Maintenance Project (DV Fisheries) is an ongoing resident fish program that serves to partially mitigate the loss of anadromous fish that resulted from downstream construction of the federal hydropower system. The project's goals are to enhance subsistence fishing and educational opportunities for Tribal members of the Shoshone-Paiute Tribes and provide fishing opportunities for non-Tribal members. In addition to stocking rainbow trout (Oncorhynchus mykiss) in Mountain View (MVR), Lake Billy Shaw (LBS), and Sheep Creek Reservoirs (SCR), the program is also designed to: maintain healthy aquatic conditions for fish growth and survival, provide superior facilities with wilderness qualities to attract non-Tribal angler use, and offer clear, consistent communication with the Tribal community about this project as well as outreach and education within the region and the local community. Tasks for this performance period fall into three categories: operations and maintenance, monitoring and evaluation, and public outreach. Operation and maintenance of the three reservoirs include maintaining fences, roads, dams and all reservoir structures, feeder canals, water troughs, stock ponds, educational signs, vehicles, equipment, and restroom facilities. Monitoring and evaluation activities include creel, gillnet, wildlife, and bird surveys, water quality and reservoir structures monitoring, native vegetation planting, photo point documentation, and control of encroaching exotic vegetation. Public outreach activities include providing environmental education to school children, providing fishing reports to local newspapers and vendors, updating the website, hosting community environmental events, and fielding numerous phone calls from anglers. The reservoir monitoring program focuses on water quality and fishery success. Sheep Creek Reservoir and Lake Billy Shaw had less than productive trout growth due to water quality issues including dissolved oxygen and/or turbidity. Regardless, angler fishing experience was the highest at Lake Billy Shaw. Trout in Mountain View Reservoir were in the best condition of the three reservoirs and anglers reported very good fishing there. Water quality (specifically dissolved oxygen and temperature) remain the main limiting factors in the fisheries, particularly in late August to early September.

  4. A real two-phase submarine debris flow and tsunami

    SciTech Connect (OSTI)

    Pudasaini, Shiva P.; Miller, Stephen A.

    2012-09-26

    The general two-phase debris flow model proposed by Pudasaini is employed to study subaerial and submarine debris flows, and the tsunami generated by the debris impact at lakes and oceans. The model, which includes three fundamentally new and dominant physical aspects such as enhanced viscous stress, virtual mass, and generalized drag (in addition to buoyancy), constitutes the most generalized two-phase flow model to date. The advantage of this two-phase debris flow model over classical single-phase, or quasi-two-phase models, is that the initial mass can be divided into several parts by appropriately considering the solid volume fraction. These parts include a dry (landslide or rock slide), a fluid (water or muddy water; e.g., dams, rivers), and a general debris mixture material as needed in real flow simulations. This innovative formulation provides an opportunity, within a single framework, to simultaneously simulate the sliding debris (or landslide), the water lake or ocean, the debris impact at the lake or ocean, the tsunami generation and propagation, the mixing and separation between the solid and fluid phases, and the sediment transport and deposition process in the bathymetric surface. Applications of this model include (a) sediment transport on hill slopes, river streams, hydraulic channels (e.g., hydropower dams and plants); lakes, fjords, coastal lines, and aquatic ecology; and (b) submarine debris impact and the rupture of fiber optic, submarine cables and pipelines along the ocean floor, and damage to offshore drilling platforms. Numerical simulations reveal that the dynamics of debris impact induced tsunamis in mountain lakes or oceans are fundamentally different than the tsunami generated by pure rock avalanches and landslides. The analysis includes the generation, amplification and propagation of super tsunami waves and run-ups along coastlines, debris slide and deposition at the bottom floor, and debris shock waves. It is observed that the submarine debris speed can be faster than the tsunami speed. This information can be useful for early warning strategies in the coastal regions. These findings substantially increase our understanding of complex multi-phase systems and multi-physics and flows, and allows for the proper modeling of landslide and debris induced tsunami, the dynamics of turbidity currents and sediment transport, and the associated applications to hazard mitigation, geomorphology and sedimentology.

  5. BACKPRESSURE TESTING OF ROTARY MICROFILTER DISKS

    SciTech Connect (OSTI)

    Fowley, M.; Herman, D.

    2011-04-14

    The Savannah River National Laboratory (SRNL), under the Department of Energy (DOE) Office of Environmental Management (EM), is modifying and testing the SpinTek{trademark} rotary microfilter (RMF) for radioactive filtration service in the Department of Energy (DOE) complex. The RMF has been shown to improve filtration throughput when compared to other conventional methods such as cross-flow filtration. A concern with the RMF was that backpressure, or reverse flow through the disk, would damage the filter membranes. Reverse flow might happen as a result of an inadvertent valve alignment during flushing. Testing was completed in the Engineering Development Laboratory (EDL) located in SRNL to study the physical effects of backpressure as well as to determine the maximum allowable back-pressure for RMF disks. The RMF disks tested at the EDL were manufactured by SpinTek{trademark} Filtration and used a Pall Corporation PMM050 filter membrane (0.5 micron nominal pore size) made from 316L stainless steel. Early versions of the RMF disks were made from synthetic materials that were incompatible with caustic solutions and radioactive service as well as being susceptible to delaminating when subjected to backpressure. Figure 1-1 shows the essential components of the RMF; 3 rotating disks and 3 stationary turbulence promoters (or shear elements) are shown. Figure 1-2 show the assembly view of a 25 disk RMF proposed for use at the Savannah River Site (SRS) and at the Hanford Facility. The purpose of the testing discussed in this report was to determine the allowable backpressure for RMF disks as well as study the physical effects of backpressure on RMF disks made with the Pall PMM050 membrane. This was accomplished by pressurizing the disks in the reverse flow direction (backpressure) until the test limit was reached or until membrane failure occurred. Backpressure was applied to the disks with air while submerged in deionized (DI) water. This method provided a visual representation of membrane integrity via bubble flow patterns. Membrane failure was defined as the inability to filter effectively at the nominal filter pore size. Effective filtration was determined by turbidity measurements of filtrate that was produced by applying forward-pressure to the disks while submerged in a representative simulant. The representative simulant was Tank 8F simulated sludge produced for SRNL by Optima Chemical. Two disks were tested. Disk 1 was tested primarily to determine approximate levels of backpressure where membrane failure occurred. These levels were then used to define the strategy for testing the Disk 2; a strategy that would better define and quantify the mode of failure.

  6. Measuring water velocity using DIDSON and image cross-correlation techniques

    SciTech Connect (OSTI)

    Deng, Zhiqun; Mueller, Robert P.; Richmond, Marshall C.

    2009-08-01

    To design or operate hydroelectric facilities for maximum power generation and minimum ecological impact, it is critical to understand the biological responses of fish to different flow structures. However, information is still lacking on the relationship between fish behavior and flow structures despite many years of research. Existing field characterization approaches conduct fish behavior studies and flow measurements separately and coupled later using statistical analysis. These types of studies, however, lack a way to determine the specific hydraulic conditions or the specific causes of the biological response. The Dual-Frequency Identification Sonar (DIDSON) has been in wide use for fish behavior studies since 1999. The DIDSON can detect acoustic targets at long ranges in dark or turbid dark water. PIV is a state-of-the-art, non-intrusive, whole-flow-field technique, providing instantaneous velocity vector measurements in a whole plane using image cross-correlating techniques. There has been considerable research in the development of image processing techniques associated with PIV. This existing body of knowledge is applicable and can be used to process the images taken by the DIDSON. This study was conducted in a water flume which is 9 m long, 1.2 m wide, and 1.2 m deep when filled with water. A lab jet flow was setup as the benchmark flow to calibrate DIDSON images. The jet nozzle was 6.35 cm in diameter and core jet velocity was 1.52 m/s. Different particles were used to seed the flow. The flow was characterized based on the results using Laser Doppler Velocimetry (LDV). A DIDSON was mounted about 5 meters away from the jet nozzle. Consecutive DIDSON images with known time delay were divided into small interrogation spots after background was subtracted. Across-correlation was then performed to estimate the velocity vector for each interrogation spot. The estimated average velocity in the core zone was comparable to that obtained using a LDV. This proof-of-principle project demonstrated the feasibility of extracting water flow velocity information from underwater DIDSON images using image cross-correlation techniques.

  7. Assessment of heavy metals in seawater and fish tissues at Pulau Indah, Selangor, Malaysia

    SciTech Connect (OSTI)

    Md Yunus, Sabarina Hamzah, Zaini; Wood, Ab. Khalik; Ahmad

    2015-04-29

    This study focuses on the levels of heavy metals in seawater and selected fish tissue at Pulau Indah, Selangor, Malaysia. Pulau Indah primarily contains Westport (Malaysia’s major port), and a host of full scales factories. Therefore, it is important to monitor the levels of pollution in this water body and the aquatic organisms in the long term effects, due to the human activities in this area. Water samples in this study were taken from 8 locations along the coastal area. The water samples were collected using water sampler and sampling locations were determined using a Global Positioning system (GPS). Similarly, in situ water quality parameters including temperature, dissolve oxygen (DO), salinity, total suspended solid (TSS), pH and turbidity were measured by using portable multi probes meter. Then, the samples were acidified until pH 2 and filtered. Fish samples were purchased from local fisherman along the Pulau Indah coastal area and samples were digested using concentrated nitric acid in wet digestion method. The levels of selected heavy metals in four species of fish and seawater from Pulau Indah coastal area were determined using Inductive Coupled Plasma Mass Spectrometer (ICPMS) after dilution to the samples. In general, the quality of water at Pulau Indah is lower than Malaysia Marine Water Quality Standard except for few locations were higher than the maximum permissible levels. The concentration of heavy metals which are lead (Pb), copper (Cu), zinc (Zn) and uranium (U) in water samples are in the range of 0.36-5.43 µg/L, 75.20-621.58 µg/L, 11.92-30.52 µg/L, and 4.00-4.65 µg/L respectively. While the results of the four selected fish showed the following order of abundance Zn> U> Cu> Pb. Transfer factor (TF) of heavy metals in fish tissue of selected fish species from the water was discussed. However, the observed metal concentration in the sample tissue did not exceed the allowable limit of Malaysian Food Act (1983) and Regulation (1985). Therefore, it is safe for human consumption. Moreover, the pollution levels of these heavy metals were also compared with other studies. This present study can also be used to evaluate the safety dose uptake level of marine biota as well as to monitor environmental health.

  8. Imaging Reservoir Quality: Seismic Signatures of Geologic Processes

    SciTech Connect (OSTI)

    Department of Geophysics

    2008-06-30

    Lithofacies successions from diverse depositional environments show distinctive patterns in various rock-physics planes (velocity-porosity, velocity-density and porosity-clay). Four clear examples of decameter-scale lithofacies sequences are documented in this study: (1) Micocene fluvial deposits show an inverted-V pattern indicative of dispersed fabric, (2) a fining-upward sequence of mud-rich deep deposits shows a linear trend associated with laminated sand-clay mixtures, (3) sand-rich deposits show a pattern resulting from the scarcity of mixed lithofacies, and (4) a coarsening-upward sequence shows evidence of both dispersed and horizontally laminated mixed lithofacies, with predominating dispersed mixtures generated by bioturbation. It was observed that carbonate-cemented sandstones are extremely heterogeneous in the project deep-water study area. Those from the base of incisions are usually associated with lower shaliness, lower porosity and higher P-impedance, while from the top of flooding surfaces exhibit higher shaliness, higher porosity and lower P-impedance. One rock physics model that captures the observed impedance-porosity trend is the 'stiff-sand model'. For this model, the high-porosity end-member is unconsolidated sand whose initial porosity is a function of sorting and shaliness, while the low-porosity end-member is solid mineral. These two end points are joined with a Hashin-Shtrikman equation. A systematic variation of quartz:clay ratio from proximal to distal locations was observed in the study area even within a single facies. The quartz:clay ratio changes from [0.5:0.5] to [1:0] along the direction of flow, based on the trends of P-impedance vs. porosity as predicted by the rock model for uncemented sands. The results are in agreement with spill-and-fill sequence stratigraphic model in mini-basin setting. In addition, porosity at the distal location ({approx}25 % to 35%) is higher than the porosity at the proximal location ({approx}20 % to 23%). This trend is explained by a sequence stratigraphic model which predicts progressive increase in sorting by turbidity current along the flow, as well as, quantified by a rock model that heuristically accounts for sorting. The results can be applied to improve quantitative predication of sediment parameters from seismic impedance, away from well locations.

  9. Hopewell Beneficial CO2 Capture for Production of Fuels, Fertilizer and Energy

    SciTech Connect (OSTI)

    UOP; Honeywell Resins & Chemicals; Honeywell Process Solutions; Aquaflow Bionomics Ltd

    2010-09-30

    For Phase 1 of this project, the Hopewell team developed a detailed design for the Small Scale Pilot-Scale Algal CO2 Sequestration System. This pilot consisted of six (6) x 135 gallon cultivation tanks including systems for CO2 delivery and control, algal cultivation, and algal harvesting. A feed tank supplied Hopewell wastewater to the tanks and a receiver tank collected the effluent from the algal cultivation system. The effect of environmental parameters and nutrient loading on CO2 uptake and sequestration into biomass were determined. Additionally the cost of capturing CO2 from an industrial stack emission at both pilot and full-scale was determined. The engineering estimate evaluated Amine Guard technology for capture of pure CO2 and direct stack gas capture and compression. The study concluded that Amine Guard technology has lower lifecycle cost at commercial scale, although the cost of direct stack gas capture is lower at the pilot scale. Experiments conducted under high concentrations of dissolved CO2 did not demonstrate enhanced algae growth rate. This result suggests that the dissolved CO2 concentration at neutral pH was already above the limiting value. Even though dissolved CO2 did not show a positive effect on biomass growth, controlling its value at a constant set-point during daylight hours can be beneficial in an algae cultivation stage with high algae biomass concentration to maximize the rate of CO2 uptake. The limited enhancement of algal growth by CO2 addition to Hopewell wastewater was due at least in part to the high endogenous CO2 evolution from bacterial degradation of dissolved organic carbon present at high levels in the wastewater. It was found that the high level of bacterial activity was somewhat inhibitory to algal growth in the Hopewell wastewater. The project demonstrated that the Honeywell automation and control system, in combination with the accuracy of the online pH, dissolved O2, dissolved CO2, turbidity, Chlorophyll A and conductivity sensors is suitable for process control of algae cultivation in an open pond systems. This project concluded that the Hopewell wastewater is very suitable for algal cultivation but the potential for significant CO2 sequestration from the plant stack gas emissions was minimal due to the high endogenous CO2 generation in the wastewater from the organic wastewater content. Algae cultivation was found to be promising, however, for nitrogen remediation in the Hopewell wastewater.

  10. Extended Sleeve Products Allow Control and Monitoring of Process Fluid Flows Inside Shielding, Behind Walls and Beneath Floors - 13041

    SciTech Connect (OSTI)

    Abbott, Mark W.

    2013-07-01

    Throughout power generation, delivery and waste remediation, the ability to control process streams in difficult or impossible locations becomes increasingly necessary as the complexity of processes increases. Example applications include radioactive environments, inside concrete installations, buried in dirt, or inside a shielded or insulated pipe. In these situations, it is necessary to implement innovative solutions to tackle such issues as valve maintenance, valve control from remote locations, equipment cleaning in hazardous environments, and flow stream analysis. The Extended Sleeve family of products provides a scalable solution to tackle some of the most challenging applications in hazardous environments which require flow stream control and monitoring. The Extended Sleeve family of products is defined in three groups: Extended Sleeve (ESV), Extended Bonnet (EBV) and Instrument Enclosure (IE). Each of the products provides a variation on the same requirements: to provide access to the internals of a valve, or to monitor the fluid passing through the pipeline through shielding around the process pipe. The shielding can be as simple as a grout filled pipe covering a process pipe or as complex as a concrete deck protecting a room in which the valves and pipes pass through at varying elevations. Extended Sleeves are available between roughly 30 inches and 18 feet of distance between the pipeline centerline and the top of the surface to which it mounts. The Extended Sleeve provides features such as 1.5 inches of adjustment between the pipeline and deck location, internal flush capabilities, automatic alignment of the internal components during assembly and integrated actuator mounting pads. The Extended Bonnet is a shorter fixed height version of the Extended Sleeve which has a removable deck flange to facilitate installation through walls, and is delivered fully assembled. The Instrument Enclosure utilizes many of the same components as an Extended Sleeve, yet allows the installation of process monitoring instruments, such as a turbidity meter to be placed in the flow stream. The basis of the design is a valve body, which, rather than having a directly mounted bonnet has lengths of concentric pipe added, which move the bonnet away from the valve body. The pipe is conceptually similar to an oil field well, with the various strings of casing, and tubing installed. Each concentric pipe provides a required function, such as the outermost pipes, the valve sleeve and penetration sleeve, which provide structural support to the deck flange. For plug valve based designs, the next inner pipe provides compression on the environmental seals at the top of the body to bonnet joint, followed by the innermost pipe which provides rotation of the plug, in the same manner as an extended stem. Ball valve ESVs have an additional pipe to provide compressive loading on the stem packing. Due to the availability of standard pipe grades and weights, the product can be configured to fit a wide array of valve sizes, and application lengths, with current designs as short as seven inches and as tall as 18 feet. Central to the design is the requirement for no special tools or downhole tools to remove parts or configure the product. Off the shelf wrenches, sockets or other hand tools are all that is required. Compared to other products historically available, this design offers a lightweight option, which, while not as rigidly stiff, can deflect compliantly under extreme seismic loading, rather than break. Application conditions vary widely, as the base product is 316 and 304 stainless steel, but utilizes 17-4PH, and other allows as needed based on the temperature range and mechanical requirements. Existing designs are installed in applications as hot as 1400 deg. F, at low pressure, and separately in highly radioactive environments. The selection of plug versus ball valve, metal versus soft seats, and the material of the seals and seats is all dependent on the application requirements. The design of the Extended Sleeve family of products provid

  11. Geoscience Perspectives in Carbon Sequestration - Educational Training and Research Through Classroom, Field, and Laboratory Investigations

    SciTech Connect (OSTI)

    Wronkiewicz, David; Paul, Varum; Abousif, Alsedik; Ryback, Kyle

    2013-09-30

    The most effective mechanism to limit CO{sub 2} release from underground Geologic Carbon Sequestration (GCS) sites over multi-century time scales will be to convert the CO{sub 2} into solid carbonate minerals. This report describes the results from four independent research investigations on carbonate mineralization: 1) Colloidal calcite particles forming in Maramec Spring, Missouri, provide a natural analog to evaluate reactions that may occur in a leaking GCS site. The calcite crystals form as a result of physiochemical changes that occur as the spring water rises from a depth of more than 190'?. The resultant pressure decrease induces a loss of CO{sub 2} from the water, rise in pH, lowering of the solubility of Ca{sup 2+} and CO{sub 3}{sup 2-}, and calcite precipitation. Equilibrium modelling of the spring water resulted in a calculated undersaturated state with respect to calcite. The discontinuity between the observed occurrence of calcite and the model result predicting undersaturated conditions can be explained if bicarbonate ions (HCO{sub 3}{sup -}) are directly involved in precipitation process rather than just carbonate ions (CO{sub 3}{sup 2-}). 2) Sedimentary rocks in the Oronto Group of the Midcontinent Rift (MCR) system contain an abundance of labile Ca-, Mg-, and Fe-silicate minerals that will neutralize carbonic acid and provide alkaline earth ions for carbonate mineralization. One of the challenges in using MCR rocks for GCS results from their low porosity and permeability. Oronto Group samples were reacted with both CO{sub 2}-saturated deionized water at 90C, and a mildly acidic leachant solution in flow-through core-flooding reactor vessels at room temperature. Resulting leachate solutions often exceeded the saturation limit for calcite. Carbonate crystals were also detected in as little as six days of reaction with Oronto Group rocks at 90oC, as well as experiments with forsterite-olivine and augite, both being common minerals this sequence. The Oronto Group samples have poor reservoir rock characteristics, none ever exceeded a permeability value of 2.0 mD even after extensive dissolution of calcite cement during the experiments. The overlying Bayfield Group Jacobsville Formation sandstones averaged 13.4 4.3% porosity and a single sample tested by core-flooding revealed a permeability of ~340 mD. The high porosity-permeability characteristics of these sandstones will allow them to be used for GCS as a continuous aquifer unit with the overlying Mt. Simon Formation. 3) Anaerobic sulfate reducing bacteria (SRB) can enhance the conversion rate of CO{sub 2} into solid minerals and thereby improve long-term storage. SRB accelerated carbonate mineralization reactions between pCO{sub 2} values of 0.0059 and 14.7 psi. Hydrogen, lactate and formate served as suitable electron donors for SRB metabolism. The use of a {sup 13}CO{sub 2} spiked gas source also produced carbonate minerals with ~53% of the carbon being derived from the gas phase. The sulfate reducing activity of the microbial community was limited, however, at 20 psi pCO{sub 2} and carbonate mineralization did not occur. Inhibition of bacterial metabolism may have resulted from the acidic conditions or CO{sub 2} toxicity. 4) Microbialite communities forming in the high turbidity and hypersaline water of Storrs Lake, San Salvador Island, The Bahamas, were investigated for their distribution, mineralogy and microbial diversity. Molecular analysis of the organic mats on the microbialites indicate only a trace amount of cyanobacteria, while anaerobic and photosynthetic non-sulfur bacteria of the phyla Chloroflexi and purple sulfur bacteria of class Gammaproteobacteria were abundant.

  12. CROSSFLOW FILTRATION: EM-31, WP-2.3.6

    SciTech Connect (OSTI)

    Duignan, M.; Nash, C.; Poirier, M.

    2011-02-01

    In the interest of accelerating waste treatment processing, the DOE has funded studies to better understand filtration with the goal of improving filter fluxes in existing crossflow equipment. The Savannah River National Laboratory (SRNL) performed some of those studies, with a focus on start-up techniques, filter cake development, the application of filter aids (cake forming solid precoats), and body feeds (flux enhancing polymers). This paper discusses the progress of those filter studies. Crossflow filtration is a key process step in many operating and planned waste treatment facilities to separate undissolved solids from supernate solutions. This separation technology generally has the advantage of self-cleaning through the action of wall shear stress created by the flow of waste slurry through the filter tubes. However, the ability of filter wall self-cleaning depends on the slurry being filtered. Many of the alkaline radioactive wastes are extremely challenging to filtration, e.g., those containing compounds of aluminum and iron, which have particles whose size and morphology reduce permeability. Unfortunately, low filter flux can be a bottleneck in waste processing facilities such as the Savannah River Integrated Salt Disposition Process and the Hanford Waste Treatment Plant. Any improvement to the filtration rate would lead directly to increased throughput of the entire process. To date increased rates are generally realized by either increasing the crossflow filter feed flow rate, limited by pump capacity, or by increasing filter surface area, limited by space and increasing the required pump load. SRNL set up both dead-end and crossflow filter tests to better understand filter performance based on filter media structure, flow conditions, filter cleaning, and several different types of filter aids and body feeds. Using non-radioactive simulated wastes, both chemically and physically similar to the actual radioactive wastes, the authors performed several tests to evaluate methods to improve filter performance. With the proper use of filter flow conditions and filter enhancers, filter flow rates can be increased over rates currently realized today. Experiments that use non-radioactive simulants for actual waste always carry the inherent risk of not eliciting prototypic results; however, they will assist in focusing the scope needed to minimize radioactive testing and thus maximize safety. To that end this investigation has determined: (1) Waste simulant SB6 was found to be more challenging to filtration than a SRS Tank 8F simulant; (2) Higher solids concentration presents a greater challenge to filtration; (3) Filter cake is something that should be properly developed in initial filter operation; (4) Backpulsing is not necessary to maintain a good filter flux with salt wastes; (5) Scouring a filter without cleaning will lead to improved filter performance; (6) The presence of a filter cake can improve the solids separation by an order of magnitude as determined by turbidity; (7) A well developed cake with periodic scouring may allow a good filter flux to be maintained for long periods of time; and (8) Filtrate flux decline is reversible when the concentration of the filtering slurry drops and the filter is scoured.

  13. Post-Closure RCRA Groundwater Monitoring Plan for the 216-S-10 Pond and Ditch

    SciTech Connect (OSTI)

    Barnett, D BRENT.; Williams, Bruce A.; Chou, Charissa J.; Hartman, Mary J.

    2006-03-17

    The purpose of this plan is to provide a post-closure groundwater monitoring program for the 216-S-10 Pond and Ditch (S-10) treatment, storage, and/or disposal (TSD) unit. The plan incorporates the sum of knowledge about the potential for groundwater contamination to originate from the S-10, including groundwater monitoring results, hydrogeology, and operational history. The S-10 has not received liquid waste since October 1991. The closure of S-10 has been coordinated with the 200-CS-1 source operable unit in accordance with the Tri-Party Agreement interim milestones M-20-39 and M-15-39C. The S-10 is closely situated among other waste sites of very similar operational histories. The proximity of the S-10 to the other facilities (216-S-17 pond, 216-S-11 Pond, 216-S-5,6 cribs, 216-S-16 ditch and pond, and 216-U-9 ditch) indicate that at least some observed groundwater contamination beneath and downgradient of S-10 could have originated from waste sites other than S-10. Hence, it may not be feasible to strictly discriminate between the contributions of each waste site to groundwater contamination beneath the S-10. A post-closure groundwater monitoring network is proposed that will include the drilling of three new wells to replace wells that have gone dry. When completed, the revised network will meet the intent for groundwater monitoring network under WAC 173-303-645, and enable an improved understanding of groundwater contamination at the S-10. Site-specific sampling constituents are based on the dangerous waste constituents of concern relating to RCRA TSD unit operations (TSD unit constituents) identified in the Part A Permit Application. Thus, a constituent is selected for monitoring if it is: A dangerous waste constituent identified in the Part A Permit Application, or A mobile decomposition product (i.e., nitrate from nitrite) of a Part A constituent, or A reliable indicator of the site-specific contaminants (i.e., specific conductance). Using these criteria, the following constituent list and sampling schedule is proposed: Constituent; Sampling Frequency Site-Specific Parameters; Hexavalent chromium (a); Semiannual Chloride; Semiannual Fluoride; Semiannual Nitrate; Semiannual Nitrite; Semiannual Specific conductance (field)(a); Semiannual Ancillary Parameters; Anions; Annual Alkalinity Annual Metals, (in addition to chromium); Annual pH (field) Semiannual Temperature (field); Semiannual Turbidity (field) Semiannual (a). These constituents will be subject to statistical tests after background is established. It will be necessary to install new monitoring wells and accumulate background data on the groundwater from those wells before statistical comparisons can be made. Until then, the constituents listed above will be evaluated by tracking and trending concentrations in all wells and comparing these results with the corresponding DWS or Hanford Site background concentration for each constituent. If a comparison value (background or DWS) for a constituent is exceeded, DOE will notify Ecology per WAC 173-303-645 (9) (g) requirements (within seven days or a time agreed to between DOE and Ecology).

  14. Kootenai River Nutrient Dosing System and N-P Consumption: Year 2008.

    SciTech Connect (OSTI)

    Holderman, Charles

    2009-02-19

    In early 2006 we designed and built low energy consumption, pump-operated system, for dosing of the liquid nutrient in the summer 2006 season. This operated successfully, and the system was used again during the 2007 and 2008 seasons for dosing. During the early winter period, 2008, laboratory tests were made of the liquid nutrient pump system, and it was noted that small amounts of air were being entrained on the suction side of the pump, during conditions when the inlet pressure was low. It was believed that this was the cause of diurnal fluctuations in the flow supplied, characteristic of the 2007 year flow data. Replacement of '0' rings on the inlet side of the pumps was the solution to this problem, and when tested in the field during the summer season, the flow supplied was found to be stable. A decision was made by the IKERT committee at the meeting of 20th to 21st May 2008 (held in Coeur d'Alene, Idaho) to use an injection flow rate of liquid fertilizer (polyammonium phosphate 10-34-0) to achieve a target phosphorus concentration of 3.0 {micro}g/L, after complete mixing in the river. This target concentration was the same as that used in 2006 and 2007. The proposed starting date was as early as possible in June 2008. Plans were made to measure the dosing flow in three ways. Two of the three methods of flow measurement (1 and 2 below) are inter-dependent. These were: (1) Direct measurement of flow rate by diverting dosing flow into a 1000 mL volume standard flask. The flow rate was computed by dividing the flask volume by the time required to fill the flask. This was done a few times only during the summer period. (2) Adjusting the flow rate reading of the Gamma dosing pump using the 'calibration' function to achieve agreement with the flow rate computed by method 1 above. (3) Direct measurement by electrical signal from conductive fluid passing through a magnetic field (Seametrics meter, as used in previous years). Values were recorded every 4 minutes by a data-logger. This instrument has been shown to be reliable, and in agreement with method 1 to within the expected uncertainty (within 2%). Liquid nutrients were delivered to the site in late May, and system testing was done the same day. High concentrations of suspended sediment in the water column, as indicated by shallow Secchi depth readings, were present in the river in the last part of May, into June. A plan was made to delay the start up of nutrient addition to a date later than 1st June, because the aquatic productivity was almost certainly to be compromised by insufficient light availability. Daily monitoring of Secchi depths was done, showing declining turbidity in early June. A decision was made to start the system on 15th June, by which time conditions were good.

  15. Temporal Characterization of Hydrates System Dynamics beneath Seafloor Mounds. Integrating Time-Lapse Electrical Resistivity Methods and In Situ Observations of Multiple Oceanographic Parameters

    SciTech Connect (OSTI)

    Lutken, Carol; Macelloni, Leonardo; D'Emidio, Marco; Dunbar, John; Higley, Paul

    2015-01-31

    This study was designed to investigate temporal variations in hydrate system dynamics by measuring changes in volumes of hydrate beneath hydrate-bearing mounds on the continental slope of the northern Gulf of Mexico, the landward extreme of hydrate occurrence in this region. Direct Current Resistivity (DCR) measurements were made contemporaneously with measurements of oceanographic parameters at Woolsey Mound, a carbonate-hydrate complex on the mid-continental slope, where formation and dissociation of hydrates are most vulnerable to variations in oceanographic parameters affected by climate change, and where changes in hydrate stability can readily translate to loss of seafloor stability, impacts to benthic ecosystems, and venting of greenhouse gases to the water-column, and eventually, the atmosphere. We focused our study on hydrate within seafloor mounds because the structurally-focused methane flux at these sites likely causes hydrate formation and dissociation processes to occur at higher rates than at sites where the methane flux is less concentrated and we wanted to maximize our chances of witnessing association/dissociation of hydrates. We selected a particularly well-studied hydrate-bearing seafloor mound near the landward extent of the hydrate stability zone, Woolsey Mound (MC118). This mid-slope site has been studied extensively and the project was able to leverage considerable resources from the teams research experience at MC118. The site exhibits seafloor features associated with gas expulsion, hydrates have been documented at the seafloor, and changes in the outcropping hydrates have been documented, photographically, to have occurred over a period of months. We conducted observatory-based, in situ measurements to 1) characterize, geophysically, the sub-bottom distribution of hydrate and its temporal variability, and 2) contemporaneously record relevant environmental parameters (temperature, pressure, salinity, turbidity, bottom currents) to detect short-term changes within the hydrates system, identify relationships/impacts of local oceanographic parameters on the hydrates system, and improve our understanding of how seafloor instability is affected by hydrates-driven changes. A 2009 DCR survey of MC118 demonstrated that we could image resistivity anomalies to a depth of 75m below the seafloor in water depths of 1km. We reconfigured this system to operate autonomously on the seafloor in a pre-programmed mode, for periods of months. We designed and built a novel seafloor lander and deployment capability that would allow us to investigate the seafloor at potential deployment sites and deploy instruments only when conditions met our criteria. This lander held the DCR system, controlling computers, and battery power supply, as well as instruments to record oceanographic parameters. During the first of two cruises to the study site, we conducted resistivity surveying, selected a monitoring site, and deployed the instrumented lander and DCR, centered on what appeared to be the most active locations within the site, programmed to collect a DCR profile, weekly. After a 4.5-month residence on the seafloor, the team recovered all equipment. Unfortunately, several equipment failures occurred prior to recovery of the instrument packages. Prior to the failures, however, two resistivity profiles were collected together with oceanographic data. Results show, unequivocally, that significant changes can occur in both hydrate volume and distribution during time periods as brief as one week. Occurrences appear to be controlled by both deep and near-surface structure. Results have been integrated with seismic data from the area and show correspondence in space of hydrate and structures, including faults and gas chimneys.

  16. Assessment of Salmonids and Their Habitat Conditions in the Walla Walla River Basin within Washington, Annual Report 2002-2003.

    SciTech Connect (OSTI)

    Mendel, Glen; Trump, Jeremy; Gembala, Mike

    2003-09-01

    This study began in 1998 to assess salmonid distribution, relative abundance, genetics, and the condition of salmonid habitats in the Walla Walla River basin. Stream flows in the Walla Walla Basin continue to show a general trend that begins with a sharp decline in discharge in late June, followed by low summer flows and then an increase in discharge in fall and winter. Manual stream flow measurements at Pepper bridge showed an increase in 2002 of 110-185% from July-September, over flows from 2001. This increase is apparently associated with a 2000 settlement agreement between the U.S. Fish and Wildlife Service (USFWS) and the irrigation districts to leave minimum flows in the river. Stream temperatures in the Walla Walla basin were similar to those in 2001. Upper montane tributaries maintained maximum summer temperatures below 65 F, while sites in mid and lower Touchet and Walla Walla rivers frequently had daily maximum temperatures well above 68 F (high enough to inhibit migration in adult and juvenile salmonids, and to sharply reduce survival of their embryos and fry). These high temperatures are possibly the most critical physiological barrier to salmonids in the Walla Walla basin, but other factors (available water, turbidity or sediment deposition, cover, lack of pools, etc.) also play a part in salmonid survival, migration, and breeding success. The increased flows in the Walla Walla, due to the 2000 settlement agreement, have not shown consistent improvements to stream temperatures. Rainbow/steelhead (Oncorhynchus mykiss) trout represent the most common salmonid in the basin. Densities of Rainbow/steelhead in the Walla Walla River from the Washington/Oregon stateline to Mojonnier Rd. dropped slightly from 2001, but are still considerably higher than before the 2000 settlement agreement. Other salmonids including; bull trout (Salvelinus confluentus), chinook salmon (Oncorhynchus tshawytscha), mountain whitefish (Prosopium williamsoni), and brown trout (Salmo trutta) had low densities, and limited distribution throughout the basin. A large return of adult spring chinook to the Touchet River drainage in 2001 produced higher densities of juvenile chinook in 2002 than have been seen in recent years, especially in the Wolf Fork. The adult return in 2002 was substantially less than what was seen in 2001. Due to poor water conditions and trouble getting personnel hired, spawning surveys were limited in 2002. Surveyors found only one redd in four Walla Walla River tributaries (Cottonwood Ck., East Little Walla Walla, West Little Walla Walla, and Mill Ck.), and 59 redds in Touchet River tributaries (10 in the North Fork Touchet, 30 in the South Fork Touchet, and 19 in the Wolf Fork). Bull trout spawning surveys in the upper Touchet River tributaries found a total of 125 redds and 150 live fish (92 redds and 75 fish in the Wolf Fork, 2 redds and 1 fish in the Burnt Fork, 0 redds and 1 fish in the South Fork Touchet, 29 redds and 71 fish in the North Fork Touchet, and 2 redds and 2 fish in Lewis Ck.). A preliminary steelhead genetics analysis was completed as part of this project. Results indicate differences between naturally produced steelhead and those produced in the hatchery. There were also apparent genetic differences among the naturally produced fish from different areas of the basin. Detailed results are reported in Bumgarner et al. 2003. Recommendations for assessment activities in 2003 included: (1) continue to monitor the Walla Walla River (focusing from the stateline to McDonald Rd.), the Mill Ck system, and the Little Walla Walla System. (2) reevaluate Whiskey Ck. for abundance and distribution of salmonids, and Lewis Ck. for bull trout density and distribution. (3) select or develop a habitat survey protocol and begin to conduct habitat inventory and assessment surveys. (4) summarize bull trout data for Mill Ck, South Fork Touchet, and Lewis Ck. (5) begin to evaluate temperature and flow data to assess if the habitat conditions exist for spring chinook in the Touchet River.