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Note: This page contains sample records for the topic "nox sulfur dioxide" from the National Library of EnergyBeta (NLEBeta).
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they are not comprehensive nor are they the most current set.
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1

Sulfur Dioxide Regulations (Ohio)  

Energy.gov (U.S. Department of Energy (DOE))

This chapter of the law establishes that the Ohio Environmental Protection Agency provides sulfur dioxide emission limits for every county, as well as regulations for the emission, monitoring and...

2

Copper mercaptides as sulfur dioxide indicators  

DOE Patents (OSTI)

Organophosphine copper(I) mercaptide complexes are useful as convenient and semiquantitative visual sulfur dioxide gas indicators. The air-stable complexes form 1:1 adducts in the presence of low concentrations of sulfur dioxide gas, with an associated color change from nearly colorless to yellow-orange. The mercaptides are made by mixing stoichiometric amounts of the appropriate copper(I) mercaptide and phosphine in an inert organic solvent.

Eller, Phillip G. (Los Alamos, NM); Kubas, Gregory J. (Los Alamos, NM)

1979-01-01T23:59:59.000Z

3

Mechanisms of Sulfur Poisoning of NOx Adsorber Materials  

Science Conference Proceedings (OSTI)

This annual report will review progress of the initial 4 months of a three-year effort between Cummins Engine Company and Pacific Northwest National Laboratory to understand and improve the performance and sulfur tolerance of the materials used in the NOx adsorber after-treatment technology in order to meet both performance and reliability standards required for diesel engines. The goal of this project is to enable NOx after-treatment technologies that will meet both EPA 2007 emission standards and customer cost, reliability and durability requirements. The project will consist of three phases. First, the efforts will focus on understanding the current limitation of capture, regeneration and durability of existing NOx adsorber materials, especially with respect to their sulfur tolerance. With this developing understanding, efforts will also be focused on the optimization of the NOx absorber chemical and material properties to increase performance and durability over many regeneration cycles. We anticipate that improved materials will be tested and evaluated, in partnership with Cummins, on diesel vehicle engines over expected operating conditions.

Kim, Do Heui; Chin, Ya-Huei; Muntean, George G.; Peden, Charles HF; Stork, Kevin; Broering, L. C.; Stafford, R. J.; Stang, J. H.; Chen, H.-Y.; Cooper, B.; Hess, H.; Lafyatis, D.

2004-10-01T23:59:59.000Z

4

On the Ratio of Sulfur Dioxide to Nitrogen Oxides as an Indicator of Air Pollution Sources  

Science Conference Proceedings (OSTI)

The ratio of sulfur dioxide to nitrogen oxides (RSN = SO2/NOx) is one indicator of air pollution sources. The role of this ratio in source attribution is illustrated here for the Ashdod area, located in the southern coastal plain of Israel. The ...

Ronit Nirel; Uri Dayan

2001-07-01T23:59:59.000Z

5

A design strategy applied to sulfur resistant lean NOx̳ automotive catalysts  

E-Print Network (OSTI)

Catalyst poisoning due to sulfur compounds derived from fuel sulfur presents a major challenge, intractable thus far, to development of many advanced technologies for automotive catalysts such as the lean NOx, trap. Under ...

Tang, Hairong

2005-01-01T23:59:59.000Z

6

Diesel Fuel Sulfur Effects on the Performance of Lean NOx Catalysts  

DOE Green Energy (OSTI)

Evaluate the effects of diesel fuel sulfur on the performance of low temperature and high temperature Lean-NOx Catalysts. Evaluate the effects of up to 250 hours of aging on the performance of the Lean-NOx Catalysts with different fuel sulfur contents.

Ren, Shouxian

2000-08-20T23:59:59.000Z

7

sulfur dioxide emissions | OpenEI  

Open Energy Info (EERE)

sulfur dioxide emissions sulfur dioxide emissions Dataset Summary Description Emissions from energy use in buildings are usually estimated on an annual basis using annual average multipliers. Using annual numbers provides a reasonable estimation of emissions, but it provides no indication of the temporal nature of the emissions. Therefore, there is no way of understanding the impact on emissions from load shifting and peak shaving technologies such as thermal energy storage, on-site renewable energy, and demand control. Source NREL Date Released April 11th, 2011 (3 years ago) Date Updated April 11th, 2011 (3 years ago) Keywords buildings carbon dioxide emissions carbon footprinting CO2 commercial buildings electricity emission factors ERCOT hourly emission factors interconnect nitrogen oxides

8

Average prices for spot sulfur dioxide emissions allowances at ...  

U.S. Energy Information Administration (EIA)

The weighted average spot price for sulfur dioxide (SO 2) emissions allowances awarded to winning bidders at Environmental Protection Agency's (EPA) annual auction on ...

9

Mitigation of Sulfur Effects on a Lean NOx Trap Catalyst by Sorbate Reapplication  

DOE Green Energy (OSTI)

Lean NOx trap catalysis has demonstrated the ability to reduce NOx emissions from lean natural gas reciprocating engines by >90%. The technology operates in a cyclic fashion where NOx is trapped on the catalyst during lean operation and released and reduced to N2 under rich exhaust conditions; the rich cleansing operation of the cycle is referred to as "regeneration" since the catalyst is reactivated for more NOx trapping. Natural gas combusted over partial oxidation catalysts in the exhaust can be used to obtain the rich exhaust conditions necessary for catalyst regeneration. Thus, the lean NOx trap technology is well suited for lean natural gas engine applications. One potential limitation of the lean NOx trap technology is sulfur poisoning. Sulfur compounds directly bond to the NOx trapping sites of the catalyst and render them ineffective; over time, the sulfur poisoning leads to degradation in overall NOx reduction performance. In order to mitigate the effects of sulfur poisoning, a process has been developed to restore catalyst activity after sulfur poisoning has occurred. The process is an aqueous-based wash process that removes the poisoned sorbate component of the catalyst. A new sorbate component is reapplied after removal of the poisoned sorbate. The process is low cost and does not involve reapplication of precious metal components of the catalyst. Experiments were conducted to investigate the feasibility of the washing process on a lean 8.3-liter natural gas engine on a dynamometer platform. The catalyst was rapidly sulfur poisoned with bottled SO2 gas; then, the catalyst sorbate was washed and reapplied and performance was re-evaluated. Results show that the sorbate reapplication process is effective at restoring lost performance due to sulfur poisoning. Specific details relative to the implementation of the process for large stationary natural gas engines will be discussed.

Parks, II, James E [ORNL

2007-01-01T23:59:59.000Z

10

Historical Sulfur Dioxide Emissions 1850-2000: Methods and Results  

E-Print Network (OSTI)

PNNL-14537 Historical Sulfur Dioxide Emissions 1850-2000: Methods and Results S.J. Smith E;PNNL-14537 Historical Sulfur Dioxide Emissions 1850-2000: Methods and Results PNNL Research Report Joint Global Change Research Institute 8400 Baltimore Avenue College Park, Maryland 20740 #12;PNNL-14537

Hultman, Nathan E.

11

Method for Sequestering Carbon Dioxide and Sulfur Dioxide Utilizing a Plurality of Waste Streams  

NLE Websites -- All DOE Office Websites (Extended Search)

Sequestering Carbon Dioxide and Sulfur Dioxide Sequestering Carbon Dioxide and Sulfur Dioxide Utilizing a Plurality of Waste Streams Opportunity The Department of Energy's National Energy Technology Laboratory is seeking licensing partners interested in implementing United States Patent Number 7,922,792 entitled "Method for Sequestering Carbon Dioxide and Sulfur Dioxide Utilizing a Plurality of Waste Streams." Disclosed in this patent is the invention of a neutralization/sequestration method that concomitantly treats bauxite residues from aluminum production processes, as well as brine wastewater from oil and gas production processes. The method uses an integrated approach that coincidentally treats multiple industrial waste by-product streams. The end results include neutralizing caustic

12

THE EFFECT OF SULFUR ON METHANE PARTIAL OXIDATION AND REFORMING PROCESSES FOR LEAN NOX TRAP CATALYSIS  

Science Conference Proceedings (OSTI)

Lean NOx trap catalysis has demonstrated the ability to reduce NOx emissions from lean natural gas reciprocating engines by >90%. The technology operates in a cyclic fashion where NOx is trapped on the catalyst during lean operation and released and reduced to N2 under rich exhaust conditions; the rich cleansing operation of the cycle is referred to as "regeneration" since the catalyst is reactivated for more NOx trapping after NOx purge. Creating the rich exhaust conditions for regeneration can be accomplished by catalytic partial oxidation of methane in the exhaust system. Furthermore, catalytic reforming of partial oxidation exhaust can enable increased quantities of H2 which is an excellent reductant for lean NOx trap regeneration. It is critical to maintain clean and efficient partial oxidation and reforming processes to keep the lean NOx trap functioning properly and to reduce extra fuel consumption from the regeneration process. Although most exhaust constituents do not impede partial oxidation and reforming, some exhaust constituents may negatively affect the catalysts and result in loss of catalytic efficiency. Of particular concern are common catalyst poisons sulfur, zinc, and phosphorous. These poisons form in the exhaust through combustion of fuel and oil, and although they are present at low concentrations, they can accumulate to significant levels over the life of an engine system. In the work presented here, the effects of sulfur on the partial oxidation and reforming catalytic processes were studied to determine any durability limitations on the production of reductants for lean NOx trap catalyst regeneration.

Parks, II, James E [ORNL; Ponnusamy, Senthil [ORNL

2006-01-01T23:59:59.000Z

13

Terpolymerization of ethylene, sulfur dioxide and carbon monoxide  

DOE Patents (OSTI)

This invention relates to a high molecular weight terpolymer of ethylene, sulfur dioxide and carbon monoxide stable to 280.degree. C. and containing as little as 36 mol % ethylene and about 41-51 mol % sulfur dioxide; and to the method of producing said terpolymer by irradiation of a liquid and gaseous mixture of ethylene, sulfur dioxide and carbon monoxide by means of Co-60 gamma rays or an electron beam, at a temperature of about 10.degree.-50.degree. C., and at a pressure of about 140 to 680 atmospheres, to initiate polymerization.

Johnson, Richard (Shirley, NY); Steinberg, Meyer (Huntington Station, NY)

1981-01-01T23:59:59.000Z

14

Sulfur Management of NOx Adsorber Technology for Diesel Light-Duty Vehicle and Truck Applications  

DOE Green Energy (OSTI)

Sulfur poisoning from engine fuel and lube is one of the most recognizable degradation mechanisms of a NOx adsorber catalyst system for diesel emission reduction. Even with the availability of 15 ppm sulfur diesel fuel, NOx adsorber will be deactivated without an effective sulfur management. Two general pathways are currently being explored for sulfur management: (1) the use of a disposable SOx trap that can be replaced or rejuvenated offline periodically, and (2) the use of diesel fuel injection in the exhaust and high temperature de-sulfation approach to remove the sulfur poisons to recover the NOx trapping efficiency. The major concern of the de-sulfation process is the many prolonged high temperature rich cycles that catalyst will encounter during its useful life. It is shown that NOx adsorber catalyst suffers some loss of its trapping capacity upon high temperature lean-rich exposure. With the use of a disposable SOx trap to remove large portion of the sulfur poisons from the exhaust, the NOx adsorber catalyst can be protected and the numbers of de-sulfation events can be greatly reduced. Spectroscopic techniques, such as DRIFTS and Raman, have been used to monitor the underlying chemical reactions during NOx trapping/ regeneration and de-sulfation periods, and provide a fundamental understanding of NOx storage capacity and catalyst degradation mechanism using model catalysts. This paper examines the sulfur effect on two model NOx adsorber catalysts. The chemistry of SOx/base metal oxides and the sulfation product pathways and their corresponding spectroscopic data are discussed. SAE Paper SAE-2003-01-3245 {copyright} 2003 SAE International. This paper is published on this website with permission from SAE International. As a user of this website, you are permitted to view this paper on-line, download this pdf file and print one copy of this paper at no cost for your use only. The downloaded pdf file and printout of this SAE paper may not be copied, distributed or forwarded to others or for the use of others.

Fang, Howard L.; Wang, Jerry C.; Yu, Robert C. (Cummins, Inc.); Wan, C. Z. (Engelhard Corp.); Howden, Ken (U.S. Dept. of Energy)

2003-10-01T23:59:59.000Z

15

CATALYST EVALUATION FOR A SULFUR DIOXIDE-DEPOLARIZED ELECTROLYZER  

DOE Green Energy (OSTI)

Thermochemical processes are being developed to provide global-scale quantities of hydrogen. A variant on sulfur-based thermochemical cycles is the Hybrid Sulfur (HyS) Process which uses a sulfur dioxide depolarized electrolyzer (SDE) to produce the hydrogen. Testing examined the activity and stability of platinum and palladium as the electrocatalyst for the SDE in sulfuric acid solutions. Cyclic and linear sweep voltammetry revealed that platinum provided better catalytic activity with much lower potentials and higher currents than palladium. Testing also showed that the catalyst activity is strongly influenced by the concentration of the sulfuric acid electrolyte.

Hobbs, D; Hector Colon-Mercado, H

2007-01-31T23:59:59.000Z

16

Excellent Sulfur Resistance of Pt/BaO/CeO2 Lean NOx Trap Catalysts  

SciTech Connect

In this work, we investigated the NOx storage behavior of Pt-BaO/CeO2 catalysts, especially in the presence of SO2. High surface area CeO2 (~ 110 m2/g) with a rod like morphology was synthesized and used as a support. The Pt-BaO/CeO2 sample demonstrated slightly higher NOx conversion in the entire temperature range studied compared with Pt-BaO/?-Al2O3. More importantly, this ceria-based catalyst showed higher sulfur tolerance than the alumina-based one. The time of complete NOx uptake was maintained even after exposing the sample to ~3 g/L of SO2. The same sulfur exposure, on the other hand, eliminated the complete NOx uptake time on the alumina-based NOx storage catalysts. TEM images show no evidence of either Pt sintering or BaS phase formation during reductive de-sulfation up to 600°C on the ceria based catalyst, while the same process over the alumina-based catalyst resulted in both a significant increase in the average Pt cluster size and the agglomeration of a newly-formed BaS phase into large crystallites. XPS results revealed the presence of about 5 times more residual sulfur after reductive de-sulfation at 600°C on the alumina based catalysts in comparison with the ceria-based ones. All of these results strongly support that, besides their superior intrinsic NOx uptake properties, ceria based catalysts have a) much higher sulfur tolerance and b) excellent resistance against Pt sintering when they are compared to the widely used alumina based catalysts.

Kwak, Ja Hun; Kim, Do Heui; Szanyi, Janos; Peden, Charles HF

2008-10-21T23:59:59.000Z

17

Process for sequestering carbon dioxide and sulfur dioxide  

DOE Patents (OSTI)

A process for sequestering carbon dioxide, which includes reacting a silicate based material with an acid to form a suspension, and combining the suspension with carbon dioxide to create active carbonation of the silicate-based material, and thereafter producing a metal salt, silica and regenerating the acid in the liquid phase of the suspension.

Maroto-Valer, M. Mercedes (State College, PA); Zhang, Yinzhi (State College, PA); Kuchta, Matthew E. (State College, PA); Andresen, John M. (State College, PA); Fauth, Dan J. (Pittsburgh, PA)

2009-10-20T23:59:59.000Z

18

NOx | OpenEI  

Open Energy Info (EERE)

NOx NOx Dataset Summary Description Emissions from energy use in buildings are usually estimated on an annual basis using annual average multipliers. Using annual numbers provides a reasonable estimation of emissions, but it provides no indication of the temporal nature of the emissions. Therefore, there is no way of understanding the impact on emissions from load shifting and peak shaving technologies such as thermal energy storage, on-site renewable energy, and demand control. Source NREL Date Released April 11th, 2011 (3 years ago) Date Updated April 11th, 2011 (3 years ago) Keywords buildings carbon dioxide emissions carbon footprinting CO2 commercial buildings electricity emission factors ERCOT hourly emission factors interconnect nitrogen oxides NOx SO2 sulfur dioxide emissions

19

Impacts of NOx Controls on Mercury Controllability  

Science Conference Proceedings (OSTI)

Past tests have led researchers and air pollution regulators to hypothesize that nitrogen oxides (NOx) controls can enhance mercury capture by particulate collection devices and sulfur dioxide (SO2) scrubbers. This technology review presents results obtained to date from a comprehensive program designed to confirm, qualify, and quantify these hypotheses.

2002-03-13T23:59:59.000Z

20

Smart battery controller for lithium/sulfur dioxide batteries  

Science Conference Proceedings (OSTI)

Each year, the U.S. Army purchases millions of lithium sulfur dioxide batteries for use in portable electronics equipment. Because of their superior rate capability and service life over a wide variety of conditions, lithium batteries are the power source of choice for military equipment. There is no convenient method of determining the available energy remaining in partially used lithium batteries; hence, users do not take full advantage of all the available battery energy. Currently, users replace batteries before each mission, which leads to premature disposal, and results in the waste of millions of dollars in battery energy every year. Another problem of the lithium battery is that it is necessary to ensure complete discharge of the cells when the useful life of the battery has been expended, or when a hazardous condition exists; a hazardous condition may result in one or more of the cells venting. The Electronics Technology and Devices Laboratory has developed a working prototype of a smart battery controller (SBC) that addresses these problems.

Atwater, T.; Bard, A.; Testa, B.; Shader, W.

1992-08-01T23:59:59.000Z

Note: This page contains sample records for the topic "nox sulfur dioxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

SYNTHESIS OF SULFUR-BASED WATER TREATMENT AGENT FROM SULFUR DIOXIDE WASTE STREAMS  

Science Conference Proceedings (OSTI)

Absorption of sulfur dioxide from a simulated flue gas was investigated for the production of polymeric ferric sulfate (PFS), a highly effective coagulant useful in treatment of drinking water and wastewater. The reaction for PFS synthesis took place near atmospheric pressure and at temperatures of 30-80 C. SO{sub 2} removal efficiencies greater than 90% were achieved, with ferrous iron concentrations in the product less than 0.1%. A factorial analysis of the effect of temperature, oxidant dosage, SO{sub 2} concentration, and gas flow rate on SO{sub 2} removal efficiency was carried out, and statistical analyses are conducted. The solid PFS was also characterized with different methods. Characterization results have shown that PFS possesses both crystalline and non-crystalline structure. The kinetics of reactions among FeSO{sub 4} {center_dot} 7H{sub 2}O, NaHSO{sub 3} and NaClO{sub 3} was investigated. Characterizations of dry PFS synthesized from SO{sub 2} show the PFS possesses amorphous structure, which is desired for it to be a good coagulant in water and wastewater treatment. A series of lab-scale experiments were conducted to evaluate the performance of PFS synthesized from waste sulfur dioxide, ferrous sulfate and sodium chlorate. The performance assessments were based on the comparison of PFS and other conventional and new coagulants for the removal of turbidity and arsenic under different laboratory coagulant conditions. Pilot plant studies were conducted at Des Moines Water Works in Iowa and at the City of Savannah Industrial and Domestic (I&D) Water Treatment Plant in Port Wentworth, Georgia. PFS performances were compared with those of conventional coagulants. The tests in both water treatment plants have shown that PFS is, in general, comparable or better than other coagulants in removal of turbidity and organic substances. The corrosion behavior of polymeric ferric sulfate (PFS) prepared from SO{sub 2} and ferric chloride (FC) were compared. Results showed that both temperature and concentration of the coagulants substantially impact corrosion rates. The corrosion rates increased with the increase of temperature and concentration. The results from a scanning electron microscope (SEM) showed that chloride caused more serious pitting than sulfate anion on both aluminum and steel specimens. Although SEM confirmed the existence of pitting corrosion, the results of weight loss indicated that the uniform corrosion predominate the corrosion mechanism, and pitting corrosion played a less important role. The test proved that PFS was less corrosive than FC, which may lead to the large-scale application of PFS in waste treatment. The kinetics of the new desulfurization process has been studied. The study results provide the theoretical guidance for improving sulfur removal efficiency and controlling the quality of PFS.

Robert C. Brown; Maohong Fan; Adrienne Cooper

2004-11-01T23:59:59.000Z

22

Fast-regenerable sulfur dioxide absorbents for lean-burn diesel engine emission control  

SciTech Connect

It is known that sulfur oxides contribute significantly and deleteriously to the overall performance of lean-burn diesel engine aftertreatment systems, especially in the case of NOx traps. A Ag-based, fast regenerable SO2 absorbent has been developed and will be described. Over a temperature range of 300oC to 550oC, it absorbs almost all of the SO2 in the simulated exhaust gases during the lean cycles and can be fully regenerated by the short rich cycles at the same temperature. Its composition has been optimized as 1 wt% Pt-5wt%Ag-SiO2, and the preferred silica source for the supporting material has been identified as inert Cabosil fumed silica. The thermal instability of Ag2O under fuel-lean conditions at 230oC and above makes it possible to fast regenerate the sulfur-loaded absorbent during the following fuel-rich cycles. Pt catalyst helps reducing Ag2SO4 during rich cycles at low temperatures. And the chemically inert fumed SiO2 support gives the absorbent long term stability. This absorbent shows great potential to work under the same lean-rich cycling conditions as those imposed on the NOx traps, and thus, can protect the downstream particulate filter and the NOx trap from sulfur poisoning.

Li, Liyu; King, David L.

2010-01-23T23:59:59.000Z

23

Fast-regenerable sulfur dioxide adsorbents for diesel engine emission control  

Science Conference Proceedings (OSTI)

Disclosed herein are sorbents and devices for controlling sulfur oxides emissions as well as systems including such sorbents and devices. Also disclosed are methods for making and using the disclosed sorbents, devices and systems. In one embodiment the disclosed sorbents can be conveniently regenerated, such as under normal exhaust stream from a combustion engine, particularly a diesel engine. Accordingly, also disclosed are combustion vehicles equipped with sulfur dioxide emission control devices.

Li, Liyu [Richland, WA; King, David L [Richland, WA

2011-03-15T23:59:59.000Z

24

Improved efficiency in the sulfur dioxide-iodine hydrogen cycle through the use of magnesium oxide  

DOE Green Energy (OSTI)

The reaction of iodine with dry magnesium oxide and magnesium sulfite hexahydrate was studied experimentally as a possible means of improving the efficiency of the sulfur dioxide-iodine cycle. When no extra water was introduced, the maximum product yield was 67% obtained at 423 K. With excess water vapor, a nonporous plug was formed which prevented complete reaction. In the second case, maximum yield was 62% measured at 433 K showing that added water does not increase reaction products. This reaction gives an alternate route for producing hydrogen from water via the sulfur dioxide-iodine process.

Mason, C.F.V.; Bowman, M.G.

1981-01-01T23:59:59.000Z

25

Near-Zero Emissions Oxy-Combustion Flue Gas Purification Task 2: SOx/Nox/Hg Removal for High Sulfur Coal  

Science Conference Proceedings (OSTI)

The goal of this project is to develop a near-zero emissions flue gas purification technology for existing PC (pulverized coal) power plants that are retrofitted with oxy-combustion technology. The objective of Task 2 of this project was to evaluate an alternative method of SOx, NOx and Hg removal from flue gas produced by burning high sulfur coal in oxy-combustion power plants. The goal of the program was not only to investigate a new method of flue gas purification but also to produce useful acid byproduct streams as an alternative to using a traditional FGD and SCR for flue gas processing. During the project two main constraints were identified that limit the ability of the process to achieve project goals. 1) Due to boiler island corrosion issues >60% of the sulfur must be removed in the boiler island with the use of an FGD. 2) A suitable method could not be found to remove NOx from the concentrated sulfuric acid product, which limits sale-ability of the acid, as well as the NOx removal efficiency of the process. Given the complexity and safety issues inherent in the cycle it is concluded that the acid product would not be directly saleable and, in this case, other flue gas purification schemes are better suited for SOx/NOx/Hg control when burning high sulfur coal, e.g. this project's Task 3 process or a traditional FGD and SCR.

Nick Degenstein; Minish Shah; Doughlas Louie

2012-05-01T23:59:59.000Z

26

Remote Sensing of Ammonia and Sulfur Dioxide from On-Road Light  

E-Print Network (OSTI)

Remote Sensing of Ammonia and Sulfur Dioxide from On-Road Light Duty Vehicles D A N I E L A . B U R by dynamometer (16), remote sensing (17), and recently by a chase vehicle (18). Results from these studies vary

Denver, University of

27

Modified dry limestone process for control of sulfur dioxide emissions  

DOE Patents (OSTI)

A method and apparatus for removing sulfur oxides from flue gas comprise cooling and conditioning the hot flue gas to increase the degree of water vapor saturation prior to passage through a bed of substantially dry carbonate chips or lumps, e.g., crushed limestone. The reaction products form as a thick layer of sulfites and sulfates on the surface of the chips which is easily removed by agitation to restore the reactive surface of the chips.

Shale, Correll C. (Morgantown, WV); Cross, William G. (Morgantown, WV)

1976-08-24T23:59:59.000Z

28

NOx reduction by sulfur tolerant coronal-catalytic apparatus and method  

SciTech Connect

This invention presents an NO[sub x] environment effective reduction apparatus comprising a sulfur tolerant coronal-catalyst such as high dielectric coronal-catalysts like glass wool, ceramic-glass wool or zirconium glass wool and method of use. In one embodiment the invention comprises an NO[sub x] reduction apparatus of sulfur tolerant coronal-catalyst adapted and configured for hypercritical presentation to an NO[sub x] bearing gas stream at a minimum of at least about 75 watts/cubic meter.

Mathur, V.K.; Breault, R.W.; McLarnon, C.R.; Medros, F.G.

1993-08-31T23:59:59.000Z

29

Diesel Emission Control-- Sulfur Effects (DECSE) Program-- Phase II Summary Report: NOx Adsorber Catalysts  

DOE Green Energy (OSTI)

The investigations performed in this project demonstrated the ability to develop a NO{sub x} regeneration strategy including both an improved lean/rich modulation cycle and rich engine calibration, which resulted in a high NO{sub x} conversion efficiency over a range of operating temperatures. A high-temperature cycle was developed to desulfurize the NO{sub x} absorber catalyst. The effectiveness of the desulfurization process was demonstrated on catalysts aged using two different sulfur level fuels. The major findings of this project are as follows: (1) The improved lean/rich engine calibration achieved as a part of this test project resulted in NO{sub x} conversion efficiencies exceeding 90% over a catalyst inlet operating temperature window of 300 C-450 C. This performance level was achieved while staying within the 4% fuel economy penalty target defined for the regeneration calibration. (2) The desulfurization procedure developed showed that six catalysts, which had been exposed to fuel sulfur levels of 3-, 16-, and 30-ppm for as long as 250 hours, could be recovered to greater than 85% NO{sub x} conversion efficiency over a catalyst inlet operating temperature window of 300 C-450 C, after a single desulfurization event. This performance level was achieved while staying within the 4% fuel economy penalty target defined for the regeneration calibration. (3) The desulfurization procedure developed has the potential to meet in-service engine operating conditions and provide acceptable driveability conditions. (4) Although aging with 78-ppm sulfur fuel reduced NO{sub x} conversion efficiency more than aging with 3-ppm sulfur fuel as a result of sulfur contamination, the desulfurization events restored the conversion efficiency to nearly the same level of performance. However, repeatedly exposing the catalyst to the desulfurization procedure developed in this program caused a continued decline in the catalyst's desulfurized performance. Additional work will be necessary to identify the cause of this performance decline. (5) The rate of sulfur contamination during aging with 78-ppm sulfur fuel increased with repeated aging/desulfurization cycles (from 10% per ten hours to 18% per ten hours). This was not observed with the 3-ppm fuel, where the rate of decline during aging was fairly constant at approximately 2% per ten hours.

None

2000-10-01T23:59:59.000Z

30

Full Useful Life (120,000 miles) Exhaust Emission Performance of a NOx Adsorber and Diesel Particle Filter Equipped Passenger Car and Medium-duty Engine in Conjunction with Ultra Low Sulfur Fuel (Presentation)  

DOE Green Energy (OSTI)

Discusses the full useful life exhaust emission performance of a NOx (nitrogen oxides) adsorber and diesel particle filter equipped light-duty and medium-duty engine using ultra low sulfur diesel fuel.

Thornton, M.; Tatur, M.; Tomazic, D.; Weber, P.; Webb, C.

2005-08-25T23:59:59.000Z

31

Sulfur Poisoning and Regeneration of NOx Storage-Reduction Cu/K2Ti2O5 Qiang Wang,*,  

E-Print Network (OSTI)

aiming at NOx emission reduction are less effective in controlling the fate of char-N than volatile designated LNCFSTM level I, II and III, as shown in Figure 4.29, resulted in NOx reductions of 20% for levels and fuel quality and economic factors related to boiler age and size. An impression of what NOx reductions

Guo, John Zhanhu

32

Selective catalytic reduction of sulfur dioxide to elemental sulfur. Final report  

Science Conference Proceedings (OSTI)

This project has investigated new metal oxide catalysts for the single stage selective reduction of SO{sub 2} to elemental sulfur by a reductant, such as CO. Significant progress in catalyst development has been made during the course of the project. We have found that fluorite oxides, CeO{sub 2} and ZrO{sub 2}, and rare earth zirconates such as Gd{sub 2}Zr{sub 2}O{sub 7} are active and stable catalysts for reduction Of SO{sub 2} by CO. More than 95% sulfur yield was achieved at reaction temperatures about 450{degrees}C or higher with the feed gas of stoichiometric composition. Reaction of SO{sub 2} and CO over these catalysts demonstrated a strong correlation of catalytic activity with the catalyst oxygen mobility. Furthermore, the catalytic activity and resistance to H{sub 2}O and CO{sub 2} poisoning of these catalysts were significantly enhanced by adding small amounts of transition metals, such as Co, Ni, Co, etc. The resulting transition metal-fluorite oxide composite catalyst has superior activity and stability, and shows promise in long use for the development of a greatly simplified single-step sulfur recovery process to treat variable and dilute SO{sub 2} concentration gas streams. Among various active composite catalyst systems the Cu-CeO{sub 2} system has been extensively studied. XRD, XPS, and STEM analyses of the used Cu-CeO{sub 2} catalyst found that the fluorite crystal structure of ceria was stable at the present reaction conditions, small amounts of copper was dispersed and stabilized on the ceria matrix, and excess copper oxide particles formed copper sulfide crystals of little contribution to catalytic activity. A working catalyst consisted of partially sulfated cerium oxide surface and partially sulfided copper clusters. The overall reaction kinetics were approximately represented by a first order equation.

Liu, W.; Flytzani-Stephanopoulos, M.; Sarofim, A.F.

1995-06-01T23:59:59.000Z

33

Near-Zero Emissions Oxy-Combustion Flue Gas Purification Task 3: SOx/NOx/Hg Removal for Low Sulfur Coal  

Science Conference Proceedings (OSTI)

The goal of this project was to develop a near-zero emissions flue gas purification technology for existing PC (pulverized coal) power plants that are retrofitted with oxycombustion technology. The objective of Task 3 of this project was to evaluate an alternative method of SOx, NOx and Hg removal from flue gas produced by burning low sulfur coal in oxy-combustion power plants. The goal of the program was to conduct an experimental investigation and to develop a novel process for simultaneously removal of SOx and NOx from power plants that would operate on low sulfur coal without the need for wet-FGD & SCRs. A novel purification process operating at high pressures and ambient temperatures was developed. Activated carbonâ??s catalytic and adsorbent capabilities are used to oxidize the sulfur and nitrous oxides to SO{sub 3} and NO{sub 2} species, which are adsorbed on the activated carbon and removed from the gas phase. Activated carbon is regenerated by water wash followed by drying. The development effort commenced with the screening of commercially available activated carbon materials for their capability to remove SO{sub 2}. A bench-unit operating in batch mode was constructed to conduct an experimental investigation of simultaneous SOx and NOx removal from a simulated oxyfuel flue gas mixture. Optimal operating conditions and the capacity of the activated carbon to remove the contaminants were identified. The process was able to achieve simultaneous SOx and NOx removal in a single step. The removal efficiencies were >99.9% for SOx and >98% for NOx. In the longevity tests performed on a batch unit, the retention capacity could be maintained at high level over 20 cycles. This process was able to effectively remove up to 4000 ppm SOx from the simulated feeds corresponding to oxyfuel flue gas from high sulfur coal plants. A dual bed continuous unit with five times the capacity of the batch unit was constructed to test continuous operation and longevity. Full-automation was implemented to enable continuous operation (24/7) with minimum operator supervision. Continuous run was carried out for 40 days. Very high SOx (>99.9%) and NOx (98%) removal efficiencies were also achieved in a continuous unit. However, the retention capacity of carbon beds for SOx and NOx was decreased from ~20 hours to ~10 hours over a 40 day period of operation, which was in contrast to the results obtained in a batch unit. These contradictory results indicate the need for optimization of adsorption-regeneration cycle to maintain long term activity of activated carbon material at a higher level and thus minimize the capital cost of the system. In summary, the activated carbon process exceeded performance targets for SOx and NOx removal efficiencies and it was found to be suitable for power plants burning both low and high sulfur coals. More efforts are needed to optimize the system performance.

Monica Zanfir; Rahul Solunke; Minish Shah

2012-06-01T23:59:59.000Z

34

EVALUATION OF PROTON-CONDUCTING MEMBRANES FOR USE IN A SULFUR-DIOXIDE DEPOLARIZED ELECTROLYZER  

DOE Green Energy (OSTI)

The chemical stability, sulfur dioxide transport, ionic conductivity, and electrolyzer performance have been measured for several commercially available and experimental proton exchange membranes (PEMs) for use in a sulfur dioxide depolarized electrolyzer (SDE). The SDE's function is to produce hydrogen by using the Hybrid Sulfur (HyS) Process, a sulfur based electrochemical/thermochemical hybrid cycle. Membrane stability was evaluated using a screening process where each candidate PEM was heated at 80 C in 60 wt. % H{sub 2}SO{sub 4} for 24 hours. Following acid exposure, chemical stability for each membrane was evaluated by FTIR using the ATR sampling technique. Membrane SO{sub 2} transport was evaluated using a two-chamber permeation cell. SO{sub 2} was introduced into one chamber whereupon SO{sub 2} transported across the membrane into the other chamber and oxidized to H{sub 2}SO{sub 4} at an anode positioned immediately adjacent to the membrane. The resulting current was used to determine the SO{sub 2} flux and SO{sub 2} transport. Additionally, membrane electrode assemblies (MEAs) were prepared from candidate membranes to evaluate ionic conductivity and selectivity (ionic conductivity vs. SO{sub 2} transport) which can serve as a tool for selecting membranes. MEAs were also performance tested in a HyS electrolyzer measuring current density versus a constant cell voltage (1V, 80 C in SO{sub 2} saturated 30 wt% H2SO{sub 4}). Finally, candidate membranes were evaluated considering all measured parameters including SO{sub 2} flux, SO{sub 2} transport, ionic conductivity, HyS electrolyzer performance, and membrane stability. Candidate membranes included both PFSA and non-PFSA polymers and polymer blends of which the non-PFSA polymers, BPVE-6F and PBI, showed the best selectivity.

Hobbs, D.; Elvington, M.; Colon-Mercado, H.

2009-11-11T23:59:59.000Z

35

Limestone treatment for sulfur dioxide removal. (Latest citations from the EI compendex*plus database). Published Search  

Science Conference Proceedings (OSTI)

The bibliography contains citations concerning the use of limestone for the control of sulfur dioxide emmisions in flue gases. The various designs for flue gas desulfurization are discussed, including dry fluidized beds and wet scrubbers. (Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)

NONE

1998-02-01T23:59:59.000Z

36

Greenhouse gas emissions trading in U.S. States: observations and lessons from the OTC NOx Budget Program  

Science Conference Proceedings (OSTI)

A number of U.S. states are considering market-based policies to reduce emissions of greenhouse gases (GHGs). The experience gained from emissions trading for sulfur dioxide and oxides of nitrogen (NOx) offers a useful body of information and data to draw on to design a GHG emissions trading system. This report examines NOx trading under the Ozone Transport Commission (OTC) NOx Budget Program, which resulted principally from the leadership, decisions, and actions by a group of states, ultimately becoming the first multilateral cap-and-trade system for emissions of air pollutants. 72 refs.

Andrew Aulisi; Alexander E. Farrell; Jonathan Pershing; Stacy VanDeveer [World Resources Institute, Washington, DC (United States). Sustainable Enterprise Program

2005-07-01T23:59:59.000Z

37

Smart battery controller for lithium/sulfur dioxide batteries. Technical report, Jan 89-Apr 91  

Science Conference Proceedings (OSTI)

Each year, the U.S. Army purchases millions of lithium sulfur dioxide batteries for use in portable electronics equipment. Because of their superior rate capability and service life over a wide variety of conditions, lithium batteries are the power source of choice for military equipment. There is no convenient method of determining the available energy remaining in partially used lithium batteries; hence, users do not take full advantage of all the available battery energy. Currently, users replace batteries before each mission, which leads to premature disposal, and results in the waste of millions of dollars in battery energy every year. Another problem of the lithium battery is that it is necessary to ensure complete discharge of the cells when the useful life of the battery has been expended, or when a hazardous condition exists; a hazardous condition may result in one or more of the cells venting. The Electronics Technology and Devices Laboratory has developed a working prototype of a smart battery controller (SBC) that addresses these problems.

Atwater, T.; Bard, A.; Testa, B.; Shader, W.

1992-08-01T23:59:59.000Z

38

Analysis of Strategies for Reducing Multiple Emissions from Electric Power Plants: Sulfur Dioxide, Nitrogen Oxides, Carbon Dioxide, and Mercury and a Renewable Portfolio Standard  

Gasoline and Diesel Fuel Update (EIA)

3 3 ERRATA Analysis of Strategies for Reducing Multiple Emissions from Electric Power Plants: Sulfur Dioxide, Nitrogen Oxides, Carbon Dioxide, and Mercury and a Renewable Portfolio Standard July 2001 Energy Information Administration Office of Integrated Analysis and Forecasting U.S. Department of Energy Washington, DC 20585 This Service Report was prepared by the Energy Information Administration, the independent statistical and analytical agency within the Department of Energy. The information contained herein should be attributed to the Contacts This report was prepared by the Office of Integrated Analysis and Forecasting, Energy Information Adminis- tration. General questions concerning the report may be directed to Mary J. Hutzler (202/586-2222, mhutzler @eia.doe.gov), Director of the Office of Integrated Analysis and Forecasting, Scott B. Sitzer (202/586-2308,

39

Control of Sulfur Dioxide Emissions from Pulverized Coal-Fired Boilers by Dry Removal with Lime and Limestone Sorbants  

E-Print Network (OSTI)

Over the past decade increasing concern over the potential environmental impact associated with the emissions of both gaseous and particulate pollutants has resulted in the promulgation of strict regulatory standards governing such emissions. In this regard, particular attention has been placed upon the control of sulfur dioxide (SO2) from major fuel burning installations. The provisions of the 1977 Amendments to the Clean Air Act which relate to the Prevention of Significant Deterioration (PSD) and the New Source Performance Standards (NSPS) have made consideration of this problem of significant additional importance in the context of increased coal utilization. There exist three general methods for the control of sulfur dioxide emissions from pulverized coal-fired boiler equipment. These are: (1) coal cleaning to remove pyritic sulfur, (2) conventional wet, nonregenerable scrubbing with alkaline slurry and solution processes, and (3) dry processes which involve direct introduction of lime or limestone into the firebox, or a spray dryer operated with nonregenerable alkaline sorbents coupled with a fabric filter collector. Equipment requirements, SO2 removal criteria, general economics, and potential applications of these latter two approaches within category (3) will be discussed.

Schwartz, M. H.

1979-01-01T23:59:59.000Z

40

Development of a Desulfurization Strategy for a NOx Adsorber Catalyst  

DOE Green Energy (OSTI)

Improve NOx regeneration calibration developed in DECSE Phase I project to understand full potential of NOx adsorber catalyst over a range of operating temperatures. Develop and demonstrate a desulfurization process to restore NOx conversion efficiency lost to sulfur contamination. Investigate effect of desulfurization process on long-term performance of the NOx adsorber catalyst.

Tomazic, Dean

2000-08-20T23:59:59.000Z

Note: This page contains sample records for the topic "nox sulfur dioxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

National Level Co-Control Study of the Targets for Energy Intensity and Sulfur Dioxide in China  

E-Print Network (OSTI)

Ozawa Meida. 2001. “Carbon Dioxide Emissions from the Globalpost-combustion capture of carbon dioxide. ” InternationalIPCC Special Report on Carbon Dioxide Capture and Storage:

Zhou, Nan

2013-01-01T23:59:59.000Z

42

Simulation of the nonequilibrium chemical decomposition of carbon dioxide in the presence of sulfur in a plasma  

Science Conference Proceedings (OSTI)

The authors carry out a model calculation of the kinetics of the decomposition of carbon dioxide in the presence of sulfur in a moderate-pressure nonequilibrium discharge. The process is stimulated by the vibrational excitation of CO/sub 2/. Kinetic curves and the time variation of the vibrational and translational temperatures are calculated. The dependence of the energy efficiency on the specific energy input has been obtained. The optimal energy input is 4 J/cm/sup 3/. The minimal energy comsumption per CO molecule is 2.7-3.5 eV. The results of the calculations are consistent with the experimental results in the case of a nonequilibrium UHF discharge. The mechanism of the process, which accounts for the results, particularly the higher efficiency of the process in comparison to the dissociation of pure CO/sub 2/, has been ascertained.

Zhivotov, V.K.; Levitskii, A.A.; Macheret, S.O.; Polak, L.S.

1986-05-01T23:59:59.000Z

43

UREA INFRASTRUCTURE FOR UREA SCR NOX REDUCTION  

DOE Green Energy (OSTI)

Urea SCR is currently the only proven NOX aftertreatment for diesel engines - high NOX reduction possible - some SCR catalyst systems are robust against fuel sulfur - durability has been demonstrated - many systems in the field - long history in other markets - Major limitations to acceptance - distribution of urea solution to end user - ensuring that urea solution is added to vehicle.

Bunting, Bruce G.

2000-08-20T23:59:59.000Z

44

Sulfur isotope fractionation during oxidation of sulfur dioxide: gas-phase oxidation by OH radicals and aqueous oxidation by H2O2, O3 and iron catalysis  

E-Print Network (OSTI)

The oxidation of SO[subscript 2] to sulfate is a key reaction in determining the role of sulfate in the environment through its effect on aerosol size distribution and composition. Sulfur isotope analysis has been used to ...

Harris, E.

45

National Level Co-Control Study of the Targets for Energy Intensity and Sulfur Dioxide in China  

E-Print Network (OSTI)

carbon dioxide emissions. The model uses generation dispatch algorithms, efficiency levels, and capacity factorsemissions factors for fuel and electricity. Table A-3.3.2 Energy Savings, Costs, and Carbon Dioxide

Zhou, Nan

2013-01-01T23:59:59.000Z

46

Notification to Mirant by the Commonwealth of Virginia of Serious Violations of the National Ambient Air Quality Standards for Sulfur Dioxide  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

9, 2005 9, 2005 Lisa D. Johnson, President Mirant Potomac River, LLC 8711 Westphalia Road Upper Marlboro, Maryland 20774 Dear Ms. Johnson: DEQ is in receipt of the results of Mirant's "downwash" modeling provided by Mirant to DEQ pursuant to the consent special order between the State Air Pollution Control Board and Mirant Potomac River, LLC. A cursory review of the modeling reveals that emissions from the Potomac River Generating Station result in, cause or substantially contribute to serious violations of the primary national ambient air quality standards or "NAAQS" for sulfur dioxide (SO 2 ), nitrogen dioxide (NO 2 ) and PM 10 . NAAQS are established by the U. S. Environmental Protection Agency at concentrations necessary to protect human health with an adequate margin of safety.

47

National Level Co-Control Study of the Targets for Energy Intensity and Sulfur Dioxide in China  

E-Print Network (OSTI)

and Price 2008). In addition, this scenario assumes that the share of biomassand Price 2008). Substitution of fossil fuels in cement kilns with low-sulfur biomass

Zhou, Nan

2013-01-01T23:59:59.000Z

48

Sulfuric acid-sulfur heat storage cycle  

DOE Patents (OSTI)

A method of storing heat is provided utilizing a chemical cycle which interconverts sulfuric acid and sulfur. The method can be used to levelize the energy obtained from intermittent heat sources, such as solar collectors. Dilute sulfuric acid is concentrated by evaporation of water, and the concentrated sulfuric acid is boiled and decomposed using intense heat from the heat source, forming sulfur dioxide and oxygen. The sulfur dioxide is reacted with water in a disproportionation reaction yielding dilute sulfuric acid, which is recycled, and elemental sulfur. The sulfur has substantial potential chemical energy and represents the storage of a significant portion of the energy obtained from the heat source. The sulfur is burned whenever required to release the stored energy. A particularly advantageous use of the heat storage method is in conjunction with a solar-powered facility which uses the Bunsen reaction in a water-splitting process. The energy storage method is used to levelize the availability of solar energy while some of the sulfur dioxide produced in the heat storage reactions is converted to sulfuric acid in the Bunsen reaction.

Norman, John H. (LaJolla, CA)

1983-12-20T23:59:59.000Z

49

SRD 134 Sulfur Dioxide  

Science Conference Proceedings (OSTI)

... MO, NIST Standard Reference Database 23: NIST Reference Fluid Thermodynamic and Transport Properties, Version 7.0 Beta, National Institute ...

2012-07-27T23:59:59.000Z

50

Lubricant oil consumption effects on diesel exhaust ash emissions using a sulfur dioxide trace technique and thermogravimetry  

E-Print Network (OSTI)

A detailed experimental study was conducted targeting lubricant consumption effects on ,diesel exhaust ash levels using a model year 2002 5.9L diesel engine, high and low Sulfur commercial lubricants, and clean diesel ...

Plumley, Michael J

2005-01-01T23:59:59.000Z

51

Effects of sulfation level on the desulfation behavior of pre-sulfated Pt BaO/Al2O3 lean NOx trap catalysts: a combined H2 Temperature-Programmed Reaction, in-situ sulfur K-edge X-ray Absorption Near-Edge Spectroscopy, X-ray Photoelectron Spectroscopy, and Time-Resolved X-ray Diffraction Study  

SciTech Connect

Desulfation by hydrogen of pre-sulfated Pt(2wt%) BaO(20wt%)/Al2O3 with various sulfur loading (S/Ba = 0.12, 0.31 and 0.62) were investigated by combining H2 temperature programmed reaction (TPRX), x-ray photoelectron spectroscopy (XPS), in-situ sulfur K-edge x-ray absorption near-edge spectroscopy (XANES), and synchrotron time-resolved x-ray diffraction (TR-XRD) techniques. We find that the amount of H2S desorbed during the desulfation in the H2 TPRX experiments is not proportional to the amount of initial sulfur loading. The results of both in-situ sulfur K-edge XANES and TR-XRD show that at low sulfur loadings, sulfates were transformed to a BaS phase and remained in the catalyst, rather than being removed as H2S. On the other hand, when the deposited sulfur level exceeded a certain threshold (at least S/Ba = 0.31) sulfates were reduced to form H2S, and the relative amount of the residual sulfide species in the catalyst was much less than at low sulfur loading. Unlike samples with high sulfur loading (e.g., S/Ba = 0.62), H2O did not promote the desulfation for the sample with S/Ba of 0.12, implying that the formed BaS species originating from the reduction of sulfates at low sulfur loading are more stable to hydrolysis. The results of this combined spectroscopy investigation provide clear evidence to show that sulfates at low sulfur loadings are less likely to be removed as H2S and have a greater tendency to be transformed to BaS on the material, leading to the conclusion that desulfation behavior of Pt BaO/Al2O3 lean NOx trap catalysts is markedly dependent on the sulfation levels.

Kim, Do Heui; Szanyi, Janos; Kwak, Ja Hun; Wang, Xianqin; Hanson, Jonathan C.; Engelhard, Mark H.; Peden, Charles HF

2009-04-03T23:59:59.000Z

52

Calcium looping process for high purity hydrogen production integrated with capture of carbon dioxide, sulfur and halides  

DOE Patents (OSTI)

A process for producing hydrogen comprising the steps of: (i) gasifying a fuel into a raw synthesis gas comprising CO, hydrogen, steam, sulfur and halide contaminants in the form of H.sub.2S, COS, and HX, wherein X is a halide; (ii) passing the raw synthesis gas through a water gas shift reactor (WGSR) into which CaO and steam are injected, the CaO reacting with the shifted gas to remove CO.sub.2, sulfur and halides in a solid-phase calcium-containing product comprising CaCO.sub.3, CaS and CaX.sub.2; (iii) separating the solid-phase calcium-containing product from an enriched gaseous hydrogen product; and (iv) regenerating the CaO by calcining the solid-phase calcium-containing product at a condition selected from the group consisting of: in the presence of steam, in the presence of CO.sub.2, in the presence of synthesis gas, in the presence of H.sub.2 and O.sub.2, under partial vacuum, and combinations thereof.

Ramkumar, Shwetha; Fan, Liang-Shih

2013-07-30T23:59:59.000Z

53

High Purity Hydrogen Production with In-Situ Carbon Dioxide and Sulfur Capture in a Single Stage Reactor  

DOE Green Energy (OSTI)

Enhancement in the production of high purity hydrogen (H{sub 2}) from fuel gas, obtained from coal gasification, is limited by thermodynamics of the water gas shift (WGS) reaction. However, this constraint can be overcome by conducting the WGS in the presence of a CO{sub 2}-acceptor. The continuous removal of CO{sub 2} from the reaction mixture helps to drive the equilibrium-limited WGS reaction forward. Since calcium oxide (CaO) exhibits high CO{sub 2} capture capacity as compared to other sorbents, it is an ideal candidate for such a technique. The Calcium Looping Process (CLP) developed at The Ohio State University (OSU) utilizes the above concept to enable high purity H{sub 2} production from synthesis gas (syngas) derived from coal gasification. The CLP integrates the WGS reaction with insitu CO{sub 2}, sulfur and halide removal at high temperatures while eliminating the need for a WGS catalyst, thus reducing the overall footprint of the hydrogen production process. The CLP comprises three reactors - the carbonator, where the thermodynamic constraint of the WGS reaction is overcome by the constant removal of CO{sub 2} product and high purity H{sub 2} is produced with contaminant removal; the calciner, where the calcium sorbent is regenerated and a sequestration-ready CO{sub 2} stream is produced; and the hydrator, where the calcined sorbent is reactivated to improve its recyclability. As a part of this project, the CLP was extensively investigated by performing experiments at lab-, bench- and subpilot-scale setups. A comprehensive techno-economic analysis was also conducted to determine the feasibility of the CLP at commercial scale. This report provides a detailed account of all the results obtained during the project period.

Nihar Phalak; Shwetha Ramkumar; Daniel Connell; Zhenchao Sun; Fu-Chen Yu; Niranjani Deshpande; Robert Statnick; Liang-Shih Fan

2011-07-31T23:59:59.000Z

54

NETL: Emissions Characterization - Adv. Low-NOx Burner Emissions  

NLE Websites -- All DOE Office Websites (Extended Search)

Advanced Low-NOx Burner Emissions Characterization Advanced Low-NOx Burner Emissions Characterization The goal of this work is to develop a comprehensive, high-quality database characterizing PM2.5 emissions from utility plants firing high sulfur coals. The specific objectives are to: 1) develop and test an ultra low-NOx pulverized coal burner for plug-in retrofit applications without boiler wall tube modifications, 2) assess the impact of low-NOx PC burner operation on NOx and PM2.5 emissions, and 3) provide high-quality data to ensure that future PM2.5 regulations are based on good scientific information. The work will be performed in the Clean Environment Development Facility (CEDF), a 100 million Btu/hr near-full-scale facility located at the Alliance Research Center. Related Papers and Publications:

55

Status of the Development and Assessment of Advanced NOx Catalysts  

Science Conference Proceedings (OSTI)

This is an interim report summarizing the status of EPRI's advanced nitrogen oxides (NOx) reduction catalyst development efforts in 2000. Concepts for that are more effective, lower cost, and may not have the problems associated with the standard vanadium pentoxide - titanium dioxide (V2O5-TiO2) NOx selective catalytic reduction (SCR) catalysts that have been assessed under this program. The primary efforts in 2000 included further development of an ultra-high efficiency (UHE) catalyst, determining wheth...

2000-11-27T23:59:59.000Z

56

Low NOx combustion  

DOE Patents (OSTI)

Combustion of hydrocarbon liquids and solids is achieved with less formation of NOx by feeding a small amount of oxygen into the fuel stream.

Kobayashi, Hisashi (Putnam Valley, NY); Bool, III, Lawrence E. (Aurora, NY)

2008-10-21T23:59:59.000Z

57

Low NOx combustion  

DOE Patents (OSTI)

Combustion of hydrocarbon liquids and solids is achieved with less formation of NOx by feeding a small amount of oxygen into the fuel stream.

Kobayashi; Hisashi (Putnam Valley, NY), Bool, III; Lawrence E. (Aurora, NY)

2007-06-05T23:59:59.000Z

58

Sulfur oxide adsorbents and emissions control  

DOE Patents (OSTI)

High capacity sulfur oxide absorbents utilizing manganese-based octahedral molecular sieve (Mn--OMS) materials are disclosed. An emissions reduction system for a combustion exhaust includes a scrubber 24 containing these high capacity sulfur oxide absorbents located upstream from a NOX filter 26 or particulate trap.

Li, Liyu (Richland, WA); King, David L. (Richland, WA)

2006-12-26T23:59:59.000Z

59

IEP - Advanced NOx Emissions Control: NOx Reduction Technologies  

NLE Websites -- All DOE Office Websites (Extended Search)

NOx Reduction Technologies NOx reduction technologies can be grouped into two broad categories: combustion modifications and post-combustion processes. Some of the more important...

60

NETL: Advanced NOx Emissions Control  

NLE Websites -- All DOE Office Websites (Extended Search)

Home > Technologies > Coal & Power Systems > Innovations for Existing Plants > Advanced NOx Emissions Control Innovations for Existing Plants Advanced NOx Emissions Control Adv....

Note: This page contains sample records for the topic "nox sulfur dioxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Effects of Fuel's Distribution on NOx Emissions in Iron Ore Sintering  

Science Conference Proceedings (OSTI)

The law of NOx emission in the sintering process indicates that the NOx mainly emits ... Effects of Reducer and Slag Concentrations in the Iron-carbon Nuggets ... Factors Affecting the Mixing Characteristics of Molten Steel in the RH Refining Process ... Simulation Calculation on Calciotherimic Reduction of Titanium Dioxide.

62

Elemental sulfur recovery process  

DOE Patents (OSTI)

An improved catalytic reduction process for the direct recovery of elemental sulfur from various SO[sub 2]-containing industrial gas streams. The catalytic process provides combined high activity and selectivity for the reduction of SO[sub 2] to elemental sulfur product with carbon monoxide or other reducing gases. The reaction of sulfur dioxide and reducing gas takes place over certain catalyst formulations based on cerium oxide. The process is a single-stage, catalytic sulfur recovery process in conjunction with regenerators, such as those used in dry, regenerative flue gas desulfurization or other processes, involving direct reduction of the SO[sub 2] in the regenerator off gas stream to elemental sulfur in the presence of a catalyst. 4 figures.

Flytzani-Stephanopoulos, M.; Zhicheng Hu.

1993-09-07T23:59:59.000Z

63

Method of detecting sulfur dioxide  

DOE Patents (OSTI)

(CH.sub.3).sub.3 SiNSO is produced by the reaction of ((CH.sub.3).sub.3 Si).sub.2 NH with SO.sub.2. Also produced in the reaction are ((CH.sub.3).sub.3 Si).sub.2 O and a new solid compound [NH.sub.4 ][(CH.sub.3).sub.3 SiOSO.sub.2 ]. Both (CH.sub.3).sub.3 SiNSO and [NH.sub.4 ][(CH.sub.3).sub.3 SiOSO.sub.2 ] have fluorescent properties. The reaction of the subject invention is used in a method of measuring the concentration of SO.sub.2 pollutants in gases. By the method, a sample of gas is bubbled through a solution of ((CH.sub.3).sub.3 Si).sub.2 NH, whereby any SO.sub.2 present in the gas will react to produce the two fluorescent products. The measured fluorescence of these products can then be used to calculate the concentration of SO.sub.2 in the original gas sample. The solid product [NH.sub.4][(CH.sub.3).sub.3 SiOSO.sub.2 ] may be used as a standard in solid state NMR spectroscopy.

Spicer, Leonard D. (Salt Lake City, UT); Bennett, Dennis W. (Clemson, SC); Davis, Jon F. (Salt Lake City, UT)

1985-01-01T23:59:59.000Z

64

Separation of sulfur isotopes  

DOE Patents (OSTI)

Sulfur isotopes are continuously separated and enriched using a closed loop reflux system wherein sulfur dioxide (SO.sub.2) is reacted with sodium hydroxide (NaOH) or the like to form sodium hydrogen sulfite (NaHSO.sub.3). Heavier sulfur isotopes are preferentially attracted to the NaHSO.sub.3, and subsequently reacted with sulfuric acid (H.sub.2 SO.sub.4) forming sodium hydrogen sulfate (NaHSO.sub.4) and SO.sub.2 gas which contains increased concentrations of the heavier sulfur isotopes. This heavy isotope enriched SO.sub.2 gas is subsequently separated and the NaHSO.sub.4 is reacted with NaOH to form sodium sulfate (Na.sub.2 SO.sub.4) which is subsequently decomposed in an electrodialysis unit to form the NaOH and H.sub.2 SO.sub.4 components which are used in the aforesaid reactions thereby effecting sulfur isotope separation and enrichment without objectionable loss of feed materials.

DeWitt, Robert (Centerville, OH); Jepson, Bernhart E. (Dayton, OH); Schwind, Roger A. (Centerville, OH)

1976-06-22T23:59:59.000Z

65

Reactive based NOx sensor  

E-Print Network (OSTI)

Diesel engines exhibit better fuel economy and emit fewer greenhouse gases than gasoline engines. Modern diesel technology has virtually eliminated carbon monoxide and particulate emissions. Sulfur oxide emissions have ...

Vassiliou, Christophoros Christou

2006-01-01T23:59:59.000Z

66

NETL: Advanced NOx Emissions Control: Control Technology - SCNR Field  

NLE Websites -- All DOE Office Websites (Extended Search)

SNCR Field Demonstration SNCR Field Demonstration American Electric Power (AEP), in conjunction with the U.S. Department of Energy, FuelTech, the Ohio Coal Development Office, and fourteen EPRI member utilities, performed a full-scale demonstration of a urea-based Selective Non-Catalytic Reduction (SNCR) system at Cardinal Unit 1. Cardinal Unit 1 is a 600MWe opposed-wall dry bottom pulverized coal-fired boiler that began service in 1967. This unit burns eastern bituminous high-sulfur coal, (3.72%S). This unit was retrofitted with low NOx burners (LNB's) during its scheduled fall 1998 outage and the SNCR system was installed concurrently. SNCR is a post-combustion NOx control process developed to reduce NOx emissions from fossil-fuel combustion systems. SNCR processes involve the injection of a chemical containing nitrogen into the combustion products, where the temperature is in the range of 1600°F - 2200°F (870°C - 1205°C). In this temperature range, the chemical reacts selectively with NOx in the presence of oxygen, forming primarily nitrogen and water. Although a number of chemicals have been investigated and implemented for SNCR NOx reduction, urea and ammonia have been most widely used for full-scale applications.

67

Lean NOx catalysis for gasoline fueled European cars  

SciTech Connect

There is increasing interest in operating gasoline fueled passenger cars lean of the stoichiometric air/fuel (A/F) ratio to improve fuel economy. These types of engines will operate at lean A/F ratios while cruising at partial load, and return to stoichiometric or even rich conditions when more power is required. The challenge for the engine and catalyst manufacturer is to develop a system which will combine the high activity rates of a state-of-the-art three-way catalyst (TWC) with the ability to reduce nitrogen oxides (NOx) in the presence of excess oxygen. The objective is to achieve the future legislative limits (EURO III/IV) in the European Union. Recent developments in automotive pollution control catalysis show that the use of NOx adsorption materials is a suitable way to reduce NOx emissions of gasoline-fueled lean-burn engines. However, the primary task for the implementation of this technology in the European market will be to improve the catalyst`s high-temperature stability and to decrease its susceptibility to sulfur poisoning. Outlined here are results of a recent R and D program to achieve NOx reduction under lean-burn gasoline engine conditions. Model gas test results as well as engine bench data are used for discussion of the parameters which control NOx adsorption efficiency under various conditions.

NONE

1997-02-01T23:59:59.000Z

68

Method for removing sulfur oxide from waste gases and recovering elemental sulfur  

DOE Patents (OSTI)

A continuous catalytic fused salt extraction process is described for removing sulfur oxides from gaseous streams. The gaseous stream is contacted with a molten potassium sulfate salt mixture having a dissolved catalyst to oxidize sulfur dioxide to sulfur trioxide and molten potassium normal sulfate to solvate the sulfur trioxide to remove the sulfur trioxide from the gaseous stream. A portion of the sulfur trioxide loaded salt mixture is then dissociated to produce sulfur trioxide gas and thereby regenerate potassium normal sulfate. The evolved sulfur trioxide is reacted with hydrogen sulfide as in a Claus reactor to produce elemental sulfur. The process may be advantageously used to clean waste stack gas from industrial plants, such as copper smelters, where a supply of hydrogen sulfide is readily available.

Moore, Raymond H. (Richland, WA)

1977-01-01T23:59:59.000Z

69

NETL: Advanced NOx Emissions Control: Control Technology - NOx Emissions  

NLE Websites -- All DOE Office Websites (Extended Search)

Emissions from Multi-Burners Emissions from Multi-Burners The University of Utah working with Reaction Engineering International and Brigham Young University is investigating a project that consists of integrated experimental, theoretical and computational modeling efforts. The primary objective is to evaluate NOx formation/destruction processes as they occur in multi-burner arrays, a geometry almost always utilized in utility practice. Most controlled experimental work examining NOx has been conducted on single burners. The range of potential intra-burner interactions are likely to provide added degrees of freedom for reducing NOx. The resultant findings may allow existing utilities to arrange fuel and air distribution to minimize NOx. In new applications, orientation of individual burners within an array may also be altered to reduce NOx. Comprehensive combustion codes will be modified to incorporate the latest submodels of nitrogen release and heterogeneous chemistry. Comparison of pilot scale experiments and simulations will be utilized to validate/develop theory.

70

Interpreting Remote Sensing NOx Measurements  

E-Print Network (OSTI)

Interpreting Remote Sensing NOx Measurements Robert Slott, Consultant, Donald Stedman and Saj tailpipe emissions (HC, CO, NOx) are changing with time hUse remote sensing hMeasurements in at least 4 of the year at each location hUniform QC/QA and data reporting Paper # 2001-01-3640 #12;Remote Sensing

Denver, University of

71

Proceedings: 2000 NOx Controls Workshop  

Science Conference Proceedings (OSTI)

The 2000 EPRI workshop on nitrogen oxide (NOx) controls for utility boilers provided a medium for member utilities to augment their knowledge of recent operating experience and developments on NOx control technologies. The event focused on improving methods of compliance with emission regulations mandated by the Clean Air Act Amendments (CAAA) of 1990 without jeopardizing efficiency and plant performance.

2001-04-10T23:59:59.000Z

72

IEP - Advanced NOx Emissions Control: Control Technology  

NLE Websites -- All DOE Office Websites (Extended Search)

forms at high temperatures during fossil fuel combustion (see How NOx is Formed ). The primary sources of NOx emissions in the United States are motor vehicles, power plants,...

73

Diesel Emissions Control- Sulfur Effects (DECSE): Summary of PM Results and Data  

DOE Green Energy (OSTI)

Determine the impact of fuel sulfur levels on emission control systems that could be implemented to lower emissions of NOx and PM from on-highway trucks in the 2002-2004 time frame.

Gorse, Jr. Robert A.

2000-08-20T23:59:59.000Z

74

Diesel Fuel Sulfur Effects on the Performance of Diesel Oxidation Catalysts  

DOE Green Energy (OSTI)

Research focus: - Impact of sulfur on: Catalyst performance; Short term catalyst durability. This presentation summarizes results from fresh catalyst performance evaluations - WVU contracted to conduct DOC and Lean NOx catalyst testing for DECSE DECSE program. (experimental details discussed previously)

Whitacre, Shawn D.

2000-08-20T23:59:59.000Z

75

NETL: Advanced NOx Emissions Control: Control Technology - Model for NOx  

NLE Websites -- All DOE Office Websites (Extended Search)

Model for NOx Emissions in Biomass Cofiring Model for NOx Emissions in Biomass Cofiring Southern Research Institute is developing a validated tool or methodology to accurately and confidently design and optimize biomass-cofiring systems for full-scale utility boilers to produce the lowest NOX emissions and the least unburned carbon. The computer model will be validated through an extensive set of tests at the 6 MMBtu/hr pilot combustor in the Southern Company/Southern Research Institute Combustion Research Facility. Full-scale demonstration testing can be compared to the model for further validation. The project is designed to balance the development of a systematic and expansive database detailing the effects of cofiring parameters on NOx formation with the complementary modeling effort that will yield a capability to predict, and therefore optimize, NOx reductions by the selection of those parameters. The database of biomass cofiring results will be developed through an extensive set of pilot-scale tests at the Southern Company/Southern Research Institute Combustion Research Facility. The testing in this program will monitor NOx, LOI, and other emissions over a broad domain of biomass composition, coal quality, and cofiring injection configurations to quantify the dependence of NOx formation and LOI on these parameters. This database of cofiring cases will characterize an extensive suite of emissions and combustion properties for each of the fuel and injection configuration combinations tested.

76

A Novel Technology for the Reduction of NOx on Char by Microwaves  

E-Print Network (OSTI)

The emphasis on reduction of NOx as a precursor to street level ozone has increased the need for technologies capable of reducing NOx (>95%) to very low levels in major metropolitan areas from a wide variety of sources. Technology offerings available today may not always be appropriate for every desired application in the utility and industrial sectors. This paper will discuss a new technology under development that has promise to address many of the specialized needs of some of these applications. The technology is directed at NOx reduction but may also address other pollutants like SO2. The technology employees char, a heat treated and devolitilized form of coal, to adsorb NOx from the flue (or waste) gas. Adsorption of greater than 99% has been demonstrated on a lab scale and appears very feasible for scale-up. Microwave energy properly applied to the char loaded with NOx converts the NOx via carbon reduction to nitrogen and carbon dioxide. The role of microwave energy in the efficient destruction of the NOx selectively to nitrogen and CO2 differentiates this technology from other technologies that may generate significant byproducts like CO or N2O. The basic principles of the technology, applications where it is appropriate, and a comparison to other NOx technologies are included in the paper as well as the developmental status and plans.

Buenger, C.; Peterson, E.

1994-04-01T23:59:59.000Z

77

Why Sequence Sulfur-Oxidizing Bacteria?  

NLE Websites -- All DOE Office Websites (Extended Search)

Sulfur-Oxidizing Bacteria? Sulfur-Oxidizing Bacteria? Several environmental problems, such as acid rain, biocorrosion, etc., are caused by sulfur compounds, such as sulfur dioxide (SO2) and hydrogen sulfide (H2S). A sustainable process to remove these sulfur compounds is the production of elemental sulfur from H2S-containing gas streams by the use of sulfide-oxidizing bacteria. In this process, H2S is absorbed into the alkaline solution in the scrubber unit, followed by the biological oxidation of H2S to elemental sulfur and the recycling of water. With this two-step process, a variety of gas streams (i.e., natural gas, synthesis gas, biogas, and refinery gas) can be treated. For the treatment of sulfate-containing waste streams, an extra step has to be introduced: the transformation of sulfate into H2S by sulfate-reducing bacteria. In

78

Proposed use of antimonyl sulfate in a sulfuric-acid cycle  

DOE Green Energy (OSTI)

A proposed use of antimonyl sulfate in a sulfuric acid thermochemical hydrogen cycle is outlined. The principal advantage would be the separate evolution of sulfur dioxide and oxygen in high temperature steps.

Jones, W.M.

1982-01-01T23:59:59.000Z

79

Experimental work related to two bismuth sulfate cycles and their possible improvement. Outline of a possible antimonyl sulfate cycle with separate evolution of sulfur dioxide and oxygen  

DOE Green Energy (OSTI)

Two bismuth sulfate cycles are made possible by the stepwise decomposition of the sulfate-oxysulfate system. Omitting statement of the steps for decomposition of SO/sub 3/ and the electrochemical formation of H/sub 2/ and H/sub 2/SO/sub 4/ from SO/sub 2/ and H/sub 2/O, the key reactions are: Cycle I - Bi/sub 2/(SO/sub 4/)/sub 3/ = Bi/sub 2/O/sub 2/ /sub 3/(SO/sub 4/)/sub 0/ /sub 7/ + 2.3 SO/sub 3/; Bi/sub 2/O/sub 2/ /sub 3/(SO/sub 4/)/sub 0/ /sub 7/ + 2.3 H/sub 2/SO/sub 4/ = Bi/sub 2/(SO/sub 4/)/sub 3/ + 2.3 H/sub 2/O; Cycle II - Bi/sub 2/O(SO/sub 4/)/sub 2/ = Bi/sub 2/O/sub 2/ /sub 3/(SO/sub 4/)/sub 0/ /sub 7/ + 1.3 SO/sub 3/; Bi/sub 2/O/sub 2/ /sub 3/(SO/sub 4/)/sub 0/ /sub 7/ + 1.3 H/sub 2/SO/sub 4/ = Bi/sub 2/O(SO/sub 4/)/sub 2/ + 1.3 H/sub 2/O. Cycle I proceeds through the intermediate oxysulfates Bi/sub 2/O(SO/sub 4/)/sub 2/ and Bi/sub 2/O/sub 2/SO/sub 4/ and Cycle II through Bi/sub 2/O/sub 2/SO/sub 4/. Cycle I has the advantage of generating 2.3 moles of H/sub 2/ per mole of Bi/sub 2/O/sub 3/, compared with 1.3 for Cycle II. Published work on the Bi/sub 2/O/sub 3/-SO/sub 3/-H/sub 2/O system shows that Bi/sub 2/(SO/sub 4/)/sub 3/ is the stable solid in contact with H/sub 2/SO/sub 4/ solutions above 52.7 wt%, so that acid of at least this strength would have to be used in Cycle I. Concentrations between about 3 wt% and 52.7 wt% could be used for Cycle II. The efficiency for electrochemical formation of H/sub 2/SO/sub 4/ and H/sub 2/ seems at present to be a maximum at around 30 wt% H/sub 2/SO/sub 4/. Some thermodynamic data obtained for the decomposition reactions are presented. A possible improvement in these cycles is also discussed which may provide a solution to a problem of sorption of H/sub 2/SO/sub 4/ solution by the solids and might allow use of a more dilute acid than in Cycle I above. A brief discussion on the possible simplification of the SO/sub 3/-SO/sub 2/-O/sub 2/ separation problem with a sulfuric acid-antimonyl sulfate hybrid cycle is presented. The principal reactions are: (1) Sb/sub 2/O/sub 2/SO/sub 4/ = Sb/sub 2/O/sub 4/ + SO/sub 2/ at 900 K; (2) Sb/sub 2/O/sub 4/ = Sb/sub 2/O/sub 3/ + 1/2 O/sub 2/ at 1300 K; (3) Sb/sub 2/O/sub 3/ + H/sub 2/SO/sub 4/ = Sb/sub 2/O/sub 2/SO/sub 4/ + H/sub 2/O.

Jones, W.M.

1981-01-01T23:59:59.000Z

80

Enhanced High Temperature Performance of NOx Reduction Catalyst Materials  

Science Conference Proceedings (OSTI)

Two primary NOx after-treatment technologies have been recognized as the most promising approaches for meeting stringent NOx emission standards for diesel vehicles within the Environmental Protection Agency’s (EPA’s) 2007/2010 mandated limits, NOx Storage Reduction (NSR) and NH3 selective catalytic reduction (SCR); both are, in fact being commercialized for this application. However, in looking forward to 2015 and beyond with expected more stringent regulations, the continued viability of the NSR technology for controlling NOx emissions from lean-burn engines such as diesels will require at least two specific, significant and inter-related improvements. First, it is important to reduce system costs by, for example, minimizing the precious metal content while maintaining, even improving, performance and long-term stability. A second critical need for future NSR systems, as well as for NH3 SCR, will be significantly improved higher and lower temperature performance and stability. Furthermore, these critically needed improvements will contribute significantly to minimizing the impacts to fuel economy of incorporating these after-treatment technologies on lean-burn vehicles. To meet these objectives will require, at a minimum an improved scientific understanding of the following things: i) the various roles for the precious and coinage metals used in these catalysts; ii) the mechanisms for these various roles; iii) the effects of high temperatures on the active metal performance in their various roles; iv) mechanisms for higher temperature NOx storage performance for modified and/or alternative storage materials; v) the interactions between the precious metals and the storage materials in both optimum NOx storage performance and long term stability; vi) the sulfur adsorption and regeneration mechanisms for NOx reduction materials; vii) materials degradation mechanisms in CHA-based NH3 SCR catalysts. The objective of this CRADA project between PNNL and Cummins, Inc. is to develop a fundamental understanding of the above-listed issues. Model catalysts that are based on literature formulations are the focus of the work being carried out at PNNL. In addition, the performance and stability of more realistic high temperature NSR catalysts, supplied by JM, are being studied in order to provide baseline data for the model catalysts that are, again, based on formulations described in the open literature. For this short summary, we will primarily highlight representative results from our recent studies of the stability of candidate high temperature NSR materials.

Gao, Feng; Kim, Do Heui; Luo, Jinyong; Muntean, George G.; Peden, Charles HF; Howden, Ken; Currier, Neal; Kamasamudram, Krishna; Kumar, Ashok; Li, Junhui; Stafford, Randy; Yezerets, Aleksey; Castagnola, Mario; Chen, Hai Ying; Hess, Howard ..

2012-12-31T23:59:59.000Z

Note: This page contains sample records for the topic "nox sulfur dioxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

USE OF A DIESEL FUEL PROCESSOR FOR RAPID AND EFFICIENT REGENERATION OF SINGLE LEG NOX ADSORBER SYSTEMS  

DOE Green Energy (OSTI)

Lean NOx adsorber systems are one of the primary candidate technologies for the control of NOx from diesel engines to meet the 2007-2010 US emissions regulations, which require a 90% reduction of NOx from the 2004 regulations. Several of the technical challenges facing this technology are regeneration at low exhaust temperatures and the efficient use of diesel fuel to minimize fuel penalty. A diesel processor system has been developed and tested in a single leg NOx adsorber configuration on a diesel engine test stand. During NOx adsorber regeneration, this fuel processor system performs reduces the exhaust O2 level to zero and efficiently processes the diesel fuel to H2 and CO. Combined with a Nox adsorber catalyst, this system has demonstrated NOx reduction above 90%, regeneration of the NOx adsorber H2/CO pulses as short as 1 second and fuel penalties in the 3 to 4% range at 50% load. This fuel processor system can also be used to provide the desulfation cycle required with sulfur containing fuels as well as providing thermal management for PM filter regeneration.

Betta, R; Cizeron, J; Sheridan, D; Davis, T

2003-08-24T23:59:59.000Z

82

Near-Zero NOx Technology  

E-Print Network (OSTI)

Miura Boiler is a world leader in boiler technology with manufacturing facilities in Japan, China, Korea, Taiwan and Brantford, Ontario. The company, which began operations in 1927, is committed to technologies that save fuel, reduce harmful emissions, and conserve natural resources. Recently the company announced the development of a technology that dramatically reduces the nitrogen oxide (NOx) concentration in the exhaust gas of gas-fired steam boilers to below 1ppm (at O2=0% equivalent) compared to over 30ppm of conventional US boilers. This “near-zero NOx” breakthrough will be available in North America by 2010 and represents yet another first in Miura’s “green technology” achievements.

Utzinger, M.

2008-01-01T23:59:59.000Z

83

NOx Reduction through Efficiency Gain  

E-Print Network (OSTI)

Benz Air Engineering and the CompuNOx system focus on a controls approach to minimize emissions without exposing steam generation plants to an unbearable financial burden. With minimal system changes we use thorough system analysis in conjunction with a novel control design to deliver a comprehensive boiler controls retrofit that provides reductions in emissions as well as substantial cost savings. Combining mechanical engineering expertise with substantial experience in control engineering in over 200 retrofits this system achieves astonishing results with short payback time, making CompuNOx a feasible solution for emission mandates and cost savings.

Benz, R.; Thompson, R.; Staedter, M.

2007-01-01T23:59:59.000Z

84

Control of NOx by combustion process modifications  

E-Print Network (OSTI)

A theoretical and experimental study was carried out to determine lower bounds of NOx emission from staged combustion of a 0.7%N #6 fuel oil. Thermodynamic and chemical kinetic calculations have shown minimum NOx emissions ...

Ber?, J. M.

1981-01-01T23:59:59.000Z

85

NOx Compliance Using the NOxOUT SNCR Process in the 1200 TPD Montgomery County  

E-Print Network (OSTI)

or RDF. NOx reduction by use of catalytic reduction and ammonia injection are clearly impractical research in this area, so that we can understand the principles of NOx reduction sufficiently to fill our·lined in cinerator by Hiraoka [2] reveals a reduction from 150 ppm NOx to below 100 ppm NOx (at 12% O2) by using

Columbia University

86

Some theoretical results concerning O3-NOx-VOC chemistry and NOx-VOC indicators  

E-Print Network (OSTI)

of modi®ed aircraft NOx emissions, a signi- ®cant reduction of the aircraft-induced NOx and ozone emissions are given in Fig. 6 for the reference year 1990. The reduction of the NOx perturbation is largest-day and future impact of NOx emissions 1073 #12;In July, a maximum reduction between 10 and 20 pptv is found

Sillman, Sanford

87

4, 62396281, 2004 lightning-NOx on  

E-Print Network (OSTI)

accurate model responses under the 25% VOC or NOx emission reduction scenarios but inaccurate results under the 75% NOx emission reduction scenario. OSAT predicts accurate model responses under the 25% VOC emission reduction scenario, but inaccurate responses under the 25% and 75% NOx emission reduction

Paris-Sud XI, Université de

88

Membrane Characterization for a Sulfur- Dioxide Depolarized ...  

with hot H 2SO 4 solution SO 2 transport under non-polarized conditions Ionic conductivity ... 2 transport characterization cell SO 2 Transport ...

89

OpenEI - sulfur dioxide emissions  

Open Energy Info (EERE)

http:en.openei.orgdatasetstaxonomyterm4600 en Hourly Energy Emission Factors for Electricity Generation in the United States http:en.openei.orgdatasetsnode488...

90

SOOT-CATALYZED OXIDATION OF SULFUR DIOXIDE  

E-Print Network (OSTI)

produced by combustion of propane saturated with benzeneparticles produced by a propane flame. investigators foundand carbon(ls) regions of propane soot particles produced by

Chang, S.G.

2010-01-01T23:59:59.000Z

91

Economic comparison of hydrogen production using sulfuric acid electrolysis and sulfur cycle water decomposition. Final report  

SciTech Connect

An evaluation of the relative economics of hydrogen production using two advanced techniques was performed. The hydrogen production systems considered were the Westinghouse Sulfur Cycle Water Decomposition System and a water electrolysis system employing a sulfuric acid electrolyte. The former is a hybrid system in which hydrogen is produced in an electrolyzer which uses sulfur dioxide to depolarize the anode. The electrolyte is sulfuric acid. Development and demonstration efforts have shown that extremely low cell voltages can be achieved. The second system uses a similar sulfuric acid electrolyte technology in water electrolysis cells. The comparative technoeconomics of hydrogen produced by the hybrid Sulfur Cycle and by water electrolysis using a sulfuric acid electrolyte were determined by assessing the performance and economics of 380 million SCFD plants, each energized by a very high temperature nuclear reactor (VHTR). The evaluation concluded that the overall efficiencies of hydrogen production, for operating parameters that appear reasonable for both systems, are approximately 41% for the sulfuric acid electrolysis and 47% for the hybrid Sulfur Cycle. The economic evaluation of hydrogen production, based on a 1976 cost basis and assuming a developed technology for both hydrogen production systems and the VHTRs, indicated that the hybrid Sulfur Cycle could generate hydrogen for a total cost approximately 6 to 7% less than the cost from the sulfuric acid electrolysis plant.

Farbman, G.H.; Krasicki, B.R.; Hardman, C.C.; Lin, S.S.; Parker, G.H.

1978-06-01T23:59:59.000Z

92

Catalyst for elemental sulfur recovery process  

DOE Patents (OSTI)

A catalytic reduction process is described for the direct recovery of elemental sulfur from various SO[sub 2]-containing industrial gas streams. The catalytic process provides high activity and selectivity, as well as stability in the reaction atmosphere, for the reduction of SO[sub 2] to elemental sulfur product with carbon monoxide or other reducing gases. The reaction of sulfur dioxide and reducing gas takes place over a metal oxide composite catalyst having one of the following empirical formulas: [(FO[sub 2])[sub 1[minus]n](RO)[sub n

Flytzani-Stephanopoulos, M.; Liu, W.

1995-01-24T23:59:59.000Z

93

Selective NOx Recirculation for Stationary Lean-Burn Natural Gas Engines  

SciTech Connect

Nitric oxide (NO) and nitrogen dioxide (NO2) generated by internal combustion (IC) engines are implicated in adverse environmental and health effects. Even though lean-burn natural gas engines have traditionally emitted lower oxides of nitrogen (NOx) emissions compared to their diesel counterparts, natural gas engines are being further challenged to reduce NOx emissions to 0.1 g/bhp-hr. The Selective NOx Recirculation (SNR) approach for NOx reduction involves cooling the engine exhaust gas and then adsorbing the NOx from the exhaust stream, followed by the periodic desorption of NOx. By sending the desorbed NOx back into the intake and through the engine, a percentage of the NOx can be decomposed during the combustion process. SNR technology has the support of the Department of Energy (DOE), under the Advanced Reciprocating Engine Systems (ARES) program to reduce NOx emissions to under 0.1 g/bhp-hr from stationary natural gas engines by 2010. The NO decomposition phenomenon was studied using two Cummins L10G natural gas fueled spark-ignited (SI) engines in three experimental campaigns. It was observed that the air/fuel ratio ({lambda}), injected NO quantity, added exhaust gas recirculation (EGR) percentage, and engine operating points affected NOx decomposition rates within the engine. Chemical kinetic model predictions using the software package CHEMKIN were performed to relate the experimental data with established rate and equilibrium models. The model was used to predict NO decomposition during lean-burn, stoichiometric burn, and slightly rich-burn cases with added EGR. NOx decomposition rates were estimated from the model to be from 35 to 42% for the lean-burn cases and from 50 to 70% for the rich-burn cases. The modeling results provided an insight as to how to maximize NOx decomposition rates for the experimental engine. Results from this experiment along with chemical kinetic modeling solutions prompted the investigation of rich-burn operating conditions, with added EGR to prevent preignition. It was observed that the relative air/fuel ratio, injected NO quantity, added EGR fraction, and engine operating points affected the NO decomposition rates. While operating under these modified conditions, the highest NO decomposition rate of 92% was observed. In-cylinder pressure data gathered during the experiments showed minimum deviation from peak pressure as a result of NO injections into the engine. A NOx adsorption system, from Sorbent Technologies, Inc., was integrated with the Cummins engine, comprised a NOx adsorbent chamber, heat exchanger, demister, and a hot air blower. Data were gathered to show the possibility of NOx adsorption from the engine exhaust, and desorption of NOx from the sorbent material. In order to quantify the NOx adsorption/desorption characteristics of the sorbent material, a benchtop adsorption system was constructed. The temperature of this apparatus was controlled while data were gathered on the characteristics of the sorbent material for development of a system model. A simplified linear driving force model was developed to predict NOx adsorption into the sorbent material as cooled exhaust passed over fresh sorbent material. A mass heat transfer analysis was conducted to analyze the possibility of using hot exhaust gas for the desorption process. It was found in the adsorption studies, and through literature review, that NO adsorption was poor when the carrier gas was nitrogen, but that NO in the presence of oxygen was adsorbed at levels exceeding 1% by mass of the sorbent. From the three experimental campaigns, chemical kinetic modeling analysis, and the scaled benchtop NOx adsorption system, an overall SNR system model was developed. An economic analysis was completed, and showed that the system was impractical in cost for small engines, but that economies of scale favored the technology.

Nigel N. Clark

2006-12-31T23:59:59.000Z

94

Integrated boiler, superheater, and decomposer for sulfuric acid decomposition  

DOE Patents (OSTI)

A method and apparatus, constructed of ceramics and other corrosion resistant materials, for decomposing sulfuric acid into sulfur dioxide, oxygen and water using an integrated boiler, superheater, and decomposer unit comprising a bayonet-type, dual-tube, counter-flow heat exchanger with a catalytic insert and a central baffle to increase recuperation efficiency.

Moore, Robert (Edgewood, NM); Pickard, Paul S. (Albuquerque, NM); Parma, Jr., Edward J. (Albuquerque, NM); Vernon, Milton E. (Albuquerque, NM); Gelbard, Fred (Albuquerque, NM); Lenard, Roger X. (Edgewood, NM)

2010-01-12T23:59:59.000Z

95

Performance and cost models for the direct sulfur recovery process. Task 1 Topical report, Volume 3  

SciTech Connect

The purpose of this project is to develop performance and cost models of the Direct Sulfur Recovery Process (DSRP). The DSRP is an emerging technology for sulfur recovery from advanced power generation technologies such as Integrated Gasification Combined Cycle (IGCC) systems. In IGCC systems, sulfur present in the coal is captured by gas cleanup technologies to avoid creating emissions of sulfur dioxide to the atmosphere. The sulfur that is separated from the coal gas stream must be collected. Leading options for dealing with the sulfur include byproduct recovery as either sulfur or sulfuric acid. Sulfur is a preferred byproduct, because it is easier to handle and therefore does not depend as strongly upon the location of potential customers as is the case for sulfuric acid. This report describes the need for new sulfur recovery technologies.

Frey, H.C. [North Carolina State Univ., Raleigh, NC (United States); Williams, R.B. [Carneigie Mellon Univ., Pittsburgh, PA (United States)

1995-09-01T23:59:59.000Z

96

RECENT ADVANCES IN THE DEVELOPMENT OF THE HYBRID SULFUR PROCESS FOR HYDROGEN PRODUCTION  

DOE Green Energy (OSTI)

Thermochemical processes are being developed to provide global-scale quantities of hydrogen. A variant on sulfur-based thermochemical cycles is the Hybrid Sulfur (HyS) Process, which uses a sulfur dioxide depolarized electrolyzer (SDE) to produce the hydrogen. In the HyS Process, sulfur dioxide is oxidized in the presence of water at the electrolyzer anode to produce sulfuric acid and protons. The protons are transported through a cation-exchange membrane electrolyte to the cathode and are reduced to form hydrogen. In the second stage of the process, the sulfuric acid by-product from the electrolyzer is thermally decomposed at high temperature to produce sulfur dioxide and oxygen. The two gases are separated and the sulfur dioxide recycled to the electrolyzer for oxidation. The Savannah River National Laboratory (SRNL) has been exploring a fuel-cell design concept for the SDE using an anolyte feed comprised of concentrated sulfuric acid saturated with sulfur dioxide. The advantages of this design concept include high electrochemical efficiency and small footprint compared to a parallel-plate electrolyzer design. This paper will provide a summary of recent advances in the development of the SDE for the HyS process.

Hobbs, D.

2010-07-22T23:59:59.000Z

97

NETL: Advanced NOx Emissions Control: Control Technology - Ultra Low-NOx  

NLE Websites -- All DOE Office Websites (Extended Search)

Ultra Low NOx Integrated System Ultra Low NOx Integrated System TFS 2000(tm) Low NOx Firing System Project Summary: ALSTOM Power Inc.'s Power Plant Laboratories, working in concert with ALSTOM Power's Performance Projects Group, has teamed with the U.S. Department of Energy's National Energy Technology Laboratory (DOE NETL) to conduct a comprehensive study to develop/evaluate low-cost, efficient NOx control technologies for retrofit to pulverized coal fired utility boilers. The objective of this project was to develop retrofit NOx control technology to achieve less than 0.15 lb/MMBtu NOx (for bituminous coals) and 0.10 lb/MMBtu NOx (for subbituminous coals) from existing pulverized coal fired utility boilers at a cost which is at least 25% less than SCR technology. Efficient control of NOx is seen as an important,

98

Effects of Sulfation Level on the Desulfation Behavior of Presulfated Pt-BaO/Al2O3 Lean NOx Trap Catalysts: A Combined H2 Temperature-Programmed Reaction, in Situ Sulfur K-Edge X-ray Absorption Near-Edge Spectroscopy, X-ray Photoelectron Spectroscopy, and Time-Resolved X-ray Diffraction Study  

SciTech Connect

Desulfation by hydrogen of presulfated Pt (2 wt %)-BaO(20 wt %)/Al{sub 2}O{sub 3} with various sulfur loading (S/Ba = 0.12, 0.31, and 0.62) were investigated by combining H{sub 2} temperature programmed reaction (TPRX), X-ray photoelectron spectroscopy (XPS), in situ sulfur K-edge X-ray absorption near-edge spectroscopy (XANES), and synchrotron time-resolved X-ray diffraction (TR-XRD) techniques. We find that the amount of H{sub 2}S desorbed during the desulfation in the H{sub 2} TPRX experiments is not proportional to the amount of initial sulfur loading. The results of both in situ sulfur K-edge XANES and TR-XRD show that at low sulfur loadings, sulfates were transformed to a BaS phase and remained in the catalyst rather than being removed as H{sub 2}S. On the other hand, when the deposited sulfur level exceeded a certain threshold (at least S/Ba = 0.31) sulfates were reduced to form H{sub 2}S, and the relative amount of the residual sulfide species in the catalyst was much less than at low sulfur loading. Unlike samples with high sulfur loading (e.g., S/Ba = 0.62), H{sub 2}O did not promote the desulfation for the sample with S/Ba of 0.12, implying that the formed BaS species originating from the reduction of sulfates at low sulfur loading are more stable to hydrolysis. The results of this combined spectroscopy investigation provide clear evidence to show that sulfates at low sulfur loadings are less likely to be removed as H{sub 2}S and have a greater tendency to be transformed to BaS on the material, leading to the conclusion that desulfation behavior of Pt-BaO/Al{sub 2}O{sub 3} lean NO{sub x} trap catalysts is markedly dependent on the sulfation levels.

Kim, D.H.; Hanson, J.; Szanyi, J.; Kwak, J.H.; Wang, X.; Hanson, J.C.; Engelhard, M.; and Peden, C.H.F.

2009-04-30T23:59:59.000Z

99

THERMAL DeNOx: A COMMERCIAL SELECTIVE NONCATALYTIC NOx REDUCTION PROCESS FOR  

E-Print Network (OSTI)

THERMAL DeNOx: A COMMERCIAL SELECTIVE NONCATALYTIC NOx REDUCTION PROCESS FOR WASTE when high NOx reduction is required. To illustrate the cost effectiveness, investment and operating in cinerators. INTRODUCTION THERMAL DeNO", a selective noncatalytic NO" reduction process, was invented just

Columbia University

100

NETL: Advanced NOx Emissions Control: Control Technology - NOx Combustion  

NLE Websites -- All DOE Office Websites (Extended Search)

Control Options and Integration Control Options and Integration Reaction Engineering International (REI) is optimizing the performance of, and reduce the technical risks associated with the combined application of low-NOx firing systems (LNFS) and post combustion controls through modeling, bench-scale testing, and field verification. Teaming with REI are the University of Utah and Brown University. During this two-year effort, REI will assess real-time monitoring equipment to evaluate waterwall wastage, soot formation, and burner stoichiometry, demonstrate analysis techniques to improve LNFS in combination with reburning/SNCR, assess selective catalytic reduction catalyst life, and develop UBC/fly ash separation processes. The REI program will be applicable to coal-fired boilers currently in use in the United States, including corner-, wall-, turbo-, and cyclone-fired units. However, the primary target of the research will be cyclone boilers, which are high NOx producing units and represent about 20% of the U.S. generating capacity. The results will also be applicable to all U.S. coals. The research will be divided into four key components:

Note: This page contains sample records for the topic "nox sulfur dioxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
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101

Low NOx Advanced Vortex Combustor  

SciTech Connect

A lean-premixed advanced vortex combustor (AVC) has been developed and tested. The natural gas fueled AVC was tested at the U.S. Department of Energy’s National Energy Technology Laboratory in Morgantown, WV. All testing was performed at elevated pressures and inlet temperatures and at lean fuel-air ratios representative of industrial gas turbines. The improved AVC design exhibited simultaneous NOx /CO/unburned hydrocarbon (UHC) emissions of 4/4/0 ppmv (all emissions corrected to 15% O2 dry). The design also achieved less than 3 ppmv NOx with combustion efficiencies in excess of 99.5%. The design demonstrated marked acoustic dynamic stability over a wide range of operating conditions, which potentially makes this approach significantly more attractive than other lean-premixed combustion approaches. In addition, the measured 1.75% pressure drop is significantly lower than conventional gas turbine combustors, which could translate into an overall gas turbine cycle efficiency improvement. The relatively high velocities and low pressure drop achievable with this technology make the AVC approach an attractive alternative for syngas fuel applications.

Edmonds, R.G. (Ramgen Power Systems, Inc., Bellevue, WA); Williams, J.T. (Ramgen Power Systems, Inc., Bellevue, WA); Steele, R.C. (EPRI); Straub, D.L.; Casleton, K.H.; Bining, Avtar (California Energy Commission, Sacramento, CA)

2008-05-01T23:59:59.000Z

102

IEP - Advanced NOx Emissions Control: Regulatory Drivers  

NLE Websites -- All DOE Office Websites (Extended Search)

IEP - Advanced NOx Emissions Control Regulatory Drivers Regulatory Drivers for Existing Coal-Fired Power Plants Regulatory and legislative requirements have predominantly driven the need to develop NOx control technologies for existing coal-fired power plants. The first driver was the Title IV acid rain program, established through the 1990 Clean Air Act Amendments (CAAA). This program included a two-phase strategy to reduce NOx emissions from coal-fired power plants – Phase I started January 1, 1996 and Phase II started January 1, 2000. The Title IV NOx program was implemented through unit-specific NOx emission rate limits ranging from 0.40 to 0.86 lb/MMBtu depending on the type of boiler/burner configuration and based on application of LNB technology.

103

Lean NOx Trap Catalysis for Lean Natural Gas Engine Applications  

DOE Green Energy (OSTI)

Distributed energy is an approach for meeting energy needs that has several advantages. Distributed energy improves energy security during natural disasters or terrorist actions, improves transmission grid reliability by reducing grid load, and enhances power quality through voltage support and reactive power. In addition, distributed energy can be efficient since transmission losses are minimized. One prime mover for distributed energy is the natural gas reciprocating engine generator set. Natural gas reciprocating engines are flexible and scalable solutions for many distributed energy needs. The engines can be run continuously or occasionally as peak demand requires, and their operation and maintenance is straightforward. Furthermore, system efficiencies can be maximized when natural gas reciprocating engines are combined with thermal energy recovery for cooling, heating, and power applications. Expansion of natural gas reciprocating engines for distributed energy is dependent on several factors, but two prominent factors are efficiency and emissions. Efficiencies must be high enough to enable low operating costs, and emissions must be low enough to permit significant operation hours, especially in non-attainment areas where emissions are stringently regulated. To address these issues the U.S. Department of Energy and the California Energy Commission launched research and development programs called Advanced Reciprocating Engine Systems (ARES) and Advanced Reciprocating Internal Combustion Engines (ARICE), respectively. Fuel efficiency and low emissions are two primary goals of these programs. The work presented here was funded by the ARES program and, thus, addresses the ARES 2010 goals of 50% thermal efficiency (fuel efficiency) and <0.1 g/bhp-hr emissions of oxides of nitrogen (NOx). A summary of the goals for the ARES program is given in Table 1-1. ARICE 2007 goals are 45% thermal efficiency and <0.015 g/bhp-hr NOx. Several approaches for improving the efficiency and emissions of natural gas reciprocating engines are being pursued. Approaches include: stoichiometric engine operation with exhaust gas recirculation and three-way catalysis, advanced combustion modes such as homogeneous charge compression ignition, and extension of the lean combustion limit with advanced ignition concepts and/or hydrogen mixing. The research presented here addresses the technical approach of combining efficient lean spark-ignited natural gas combustion with low emissions obtained from a lean NOx trap catalyst aftertreatment system. This approach can be applied to current lean engine technology or advanced lean engines that may result from related efforts in lean limit extension. Furthermore, the lean NOx trap technology has synergy with hydrogen-assisted lean limit extension since hydrogen is produced from natural gas during the lean NOx trap catalyst system process. The approach is also applicable to other lean engines such as diesel engines, natural gas turbines, and lean gasoline engines; other research activities have focused on those applications. Some commercialization of the technology has occurred for automotive applications (both diesel and lean gasoline engine vehicles) and natural gas turbines for stationary power. The research here specifically addresses barriers to commercialization of the technology for large lean natural gas reciprocating engines for stationary power. The report presented here is a comprehensive collection of research conducted by Oak Ridge National Laboratory (ORNL) on lean NOx trap catalysis for lean natural gas reciprocating engines. The research was performed in the Department of Energy's ARES program from 2003 to 2007 and covers several aspects of the technology. All studies were conducted at ORNL on a Cummins C8.3G+ natural gas engine chosen based on industry input to simulate large lean natural gas engines. Specific technical areas addressed by the research include: NOx reduction efficiency, partial oxidation and reforming chemistry, and the effects of sulfur poisons on the partial oxidation

Parks, II, James E [ORNL; Storey, John Morse [ORNL; Theiss, Timothy J [ORNL; Ponnusamy, Senthil [ORNL; Ferguson, Harley Douglas [ORNL; Williams, Aaron M [ORNL; Tassitano, James B [ORNL

2007-09-01T23:59:59.000Z

104

A Fundamental Consideration on NOx Adsorber Technology for DI Diesel Application  

DOE Green Energy (OSTI)

Diesel engines are far more efficient than gasoline engines of comparable size, and emit less greenhouse gases that have been implicated in global warming. In 2000, the US EPA proposed very stringent emissions standards to be introduced in 2007 along with low sulfur (< 15 ppm) diesel fuel. The California Air Resource Board (CARB) has also established the principle that future diesel fueled vehicles should meet the same low emissions standards as gasoline fueled vehicles and the EPA followed suit with its Tier II emissions regulation. Achieving such low emissions cannot be done through engine development and fuel reformulation alone, and requires application of NOx and particulate matter (PM) aftertreatment control devices. There is a widespread consensus that NOx adsorbers and particulate filter are required in order for diesel engines to meet the 2007 emissions regulations for NOx and PM. In this paper, the key exhaust characteristics from an advanced diesel engine are reviewed. Development of the NOx adsorber technology is discussed. Spectroscopic techniques are applied to understand the underlying chemical reactions over the catalyst surface during NOx trapping and regeneration periods. In-situ surface probes are useful in providing not only thermodynamic and kinetics information required for model development but also a fundamental understanding of storage capacity and degradation mechanisms. The distribution of various nitration/sulfation species is related to surface basicity. Surface displacement reactions of carbonates also play roles in affecting the trapping capability of NOx adsorbers. When ultralow-S fuel is used as a reductant during the regeneration, sulfur induced performance degradation is still observed in an aged catalyst. Other possible sources related to catalyst deactivation include incomplete reduction of surface nitration, coke formation derived from incomplete hydrocarbon burning, and lubricant formulations. Sulfur management and the direction of future work for the successful implementation of such integrated engine and aftertreatment technology are discussed. SAE Paper SAE-2002-01-2889 {copyright} 2002 SAE International. This paper is published on this website with permission from SAE International. As a user of this website, you are permitted to view this paper on-line, download this pdf file and print one copy of this paper at no cost for your use only. The downloaded pdf file and printout of this SAE paper may not be copied, distributed or forwarded to others or for the use of others.

Fang, Howard L.; Huang, Shyan C.; Yu, Robert C. (Cummins, Inc.); Wan, C. Z. (Engelhard Corp.); Howden, Ken (U.S. Dept. of Energy)

2002-10-01T23:59:59.000Z

105

COMPONENT DEVELOPMENT NEEDS FOR THE HYBRID SULFUR ELECTROLYZER  

DOE Green Energy (OSTI)

Fiscal year 2008 studies in electrolyzer component development have focused on the characterization of membrane electrode assemblies (MEA) after performance tests in the single cell electrolyzer, evaluation of electrocatalysts and membranes using a small scale electrolyzer and evaluating the contribution of individual cell components to the overall electrochemical performance. Scanning electron microscopic (SEM) studies of samples taken from MEAs testing in the SRNL single cell electrolyzer test station indicates a sulfur-rich layer forms between the cathode catalyst layer and the membrane. Based on a review of operating conditions for each of the MEAs evaluated, we conclude that the formation of the layer results from the reduction of sulfur dioxide as it passes through the MEA and reaches the catalyst layer at the cathode-membrane interface. Formation of the sulfur rich layer results in partial delamination of the cathode catalyst layer leading to diminished performance. Furthermore we believe that operating the electrolyzer at elevated pressure significantly increases the rate of formation due to increased adsorption of hydrogen on the internal catalyst surface. Thus, identification of a membrane that exhibits much lower transport of sulfur dioxide is needed to reduce the quantity of sulfur dioxide that reaches the cathode catalyst and is reduced to produce the sulfur-rich layer. Three candidate membranes are currently being evaluated that have shown promise from preliminary studies, (1) modified Nafion{reg_sign}, (2) polybenzimidazole (PBI), and (3) sulfonated Diels Alder polyphenylene (SDAPP). Testing examined the activity for the sulfur dioxide oxidation of platinum (Pt) and platinum-alloy catalysts in 30 wt% sulfuric acid solution. Linear sweep voltammetry showed an increase in activity when catalysts in which Pt is alloyed with non-noble transition metals such as cobalt and chromium. However when Pt is alloyed with noble metals, such as iridium or ruthenium, the kinetic activity decreases. We recommend further testing to determine if these binary alloys will provide the increased reaction kinetic needed to meet the targets. We also plan to test the performance of these catalyst materials for both proton and sulfur dioxide reduction. The latter may provide another parameter by which we can control the reduction of sulfur dioxide upon transport to the cathode catalyst surface. A small scale electrolyzer (2 cm{sup 2}) has been fabricated and successfully installed as an additional tool to evaluate the effect of different operating conditions on electrolyzer and MEA performance. Currently this electrolyzer is limited to testing at temperatures up to 80 C and at atmospheric pressure. Selected electrochemical performance data from the single cell sulfur dioxide depolarized electrolyzer were analyzed with the aid of an empirical equation which takes into account the overpotential of each of the components. By using the empirical equation, the performance data was broken down into its components and a comparison of the potential losses was made. The results indicated that for the testing conditions of 80 C and 30 wt% sulfuric acid, the major overpotential contribution ({approx}70 % of all losses) arise from the slow reaction rate of oxidation of sulfur dioxide. The results indicate that in order to meet the target of hydrogen production at 0.5 A/cm{sup 2} at 0.6 V and 50 wt% sulfuric acid, identification of a better catalyst for sulfur dioxide oxidation will provide the largest gain in electrolyzer performance.

Hobbs, D; Hector Colon-Mercado, H; Mark Elvington, M

2008-05-30T23:59:59.000Z

106

A Review of DOE/NETL’s Advanced NOx Control Technology R&D Program for Coal-Fired Power Plants. National Energy Technology Laboratory  

E-Print Network (OSTI)

The environmental performance of the United States ’ fleet of coal-fired boilers has steadily improved since passage of the 1990 Clean Air Act Amendments (CAAA). Missions of sulfur dioxide (SO

Bruce W. Lani; Thomas J. Feeley; James Murphy; Lindsay Green

2005-01-01T23:59:59.000Z

107

METHOD TO PREVENT SULFUR ACCUMULATION INSIDE MEMBRANE ELECTRODE ASSEMBLY  

DOE Green Energy (OSTI)

HyS is conceptually the simplest of the thermochemical cycles and involves only sulfur chemistry. In the HyS Cycle hydrogen gas (H{sub 2}) is produced at the cathode of the electrochemical cell (or electrolyzer). Sulfur dioxide (SO{sub 2}) is oxidized at the anode to form sulfuric acid (H{sub 2}SO{sub 4}) and protons (H{sup +}) as illustrated below. A separate high temperature reaction decomposes the sulfuric acid to water and sulfur dioxide which are recycled to the electrolyzers, and oxygen which is separated out as a secondary product. The electrolyzer includes a membrane that will allow hydrogen ions to pass through but block the flow of hydrogen gas. The membrane is also intended to prevent other chemical species from migrating between electrodes and undergoing undesired reactions that could poison the cathode or reduce overall process efficiency. In conventional water electrolysis, water is oxidized at the anode to produce protons and oxygen. The standard cell potential for conventional water electrolysis is 1.23 volts at 25 C. However, commercial electrolyzers typically require higher voltages ranging from 1.8 V to 2.6 V [Kirk-Othmer, 1991]. The oxidation of sulfur dioxide instead of water in the HyS electrolyzer occurs at a much lower potential. For example, the standard cell potential for sulfur dioxide oxidation at 25 C in 50 wt % sulfuric acid is 0.29 V [Westinghouse, 1980]. Since power consumption by the electrolyzers is equal to voltage times current, and current is proportional to hydrogen production, a large reduction in voltage results in a large reduction in electrical power cost per unit of hydrogen generated.

Steimke, J.; Steeper, T.; Herman, D.; Colon-Mercado, H.; Elvington, M.

2009-06-22T23:59:59.000Z

108

Influence of Ceria on the NOx Storage/Reduction Behavior of Lean NOx Trap Catalysts  

E-Print Network (OSTI)

ACPD 8, 4911­4947, 2008 NOx-induced ozone loss processes B. Vogel et al. Title Page Abstract mesospheric NOx during Arctic Winter 2003/2004 B. Vogel 1 , P. Konopka 1 , J.-U. Groo� 1 , R. M¨uller 1 , B on behalf of the European Geosciences Union. 4911 #12;ACPD 8, 4911­4947, 2008 NOx-induced ozone loss

Pennycook, Steve

109

Ammonia-Free NOx Control System  

SciTech Connect

Research is being conducted under United States Department of Energy (DOE) Contract DEFC26-03NT41865 to develop a new technology to achieve very low levels of NOx emissions from pulverized coal fired boiler systems by employing a novel system level integration between the PC combustion process and the catalytic NOx reduction with CO present in the combustion flue gas. The combustor design and operating conditions will be optimized to achieve atypical flue gas conditions. This approach will not only suppress NOx generation during combustion but also further reduce NOx over a downstream catalytic reactor that does not require addition of an external reductant, such as ammonia. This report describes the work performed during the January 1 to March 31, 2004 time period.

S. Wu; Z. Fan; R. Herman

2004-03-31T23:59:59.000Z

110

Ammonia-Free NOx Control System  

SciTech Connect

Research is being conducted under United States Department of Energy (DOE) Contract DEFC26-03NT41865 to develop a new technology to achieve very low levels of NOx emissions from pulverized coal fired boiler systems by employing a novel system level integration between the PC combustion process and the catalytic NOx reduction with CO present in the combustion flue gas. The combustor design and operating conditions will be optimized to achieve atypical flue gas conditions. This approach will not only suppress NOx generation during combustion but also further reduce NOx over a downstream catalytic reactor that does not require addition of an external reductant, such as ammonia. This report describes the work performed during the April 1 to June 30, 2004 time period.

Zhen Fan; Song Wu; Richard G. Herman

2004-06-30T23:59:59.000Z

111

DIESEL REFORMERS FOR LEAN NOX TRAP REGENERATION AND OTHER ON-BOARD HYDROGEN APPLICATIONS  

DOE Green Energy (OSTI)

Many solutions to meeting the 2007 and 2010 diesel emissions requirements have been suggested. On board production of hydrogen for in-cylinder combustion and exhaust after-treatment provide promising opportunities for meeting those requirements. Other benefits may include using syngas to rapidly heat up exhaust after-treatment catalysts during engine startup. HydrogenSource's development of a catalytic partial oxidation reformer for generating hydrogen from ultra-low sulfur diesel fuel is presented. The system can operate on engine exhaust and diesel fuel with no water tank. Test data for hydrogen regeneration of a lean NOx trap is presented showing 90% NOx conversion at temperatures as low as 150 degrees C and 99% conversion at 300 degrees C. Finally, additional efforts required to fully understand the benefits and commercial challenges of this technology are discussed.

Mauss, M; Wnuck, W

2003-08-24T23:59:59.000Z

112

In-Situ Combustion NOx Analyzer Sensor  

Science Conference Proceedings (OSTI)

This report contains a review of the different technologies currently available for measuring nitrogen oxide (NOx) in the flue gas stream including chemiluminescence, photometric, Fourier transform infrared (FTIR) and electrochemical cells. Reviews of how NOx is produced, the detrimental effects, and Environmental Protection Agency (EPA) Code of Federal Regulations (CFR) Title 40 test protocols are also included. A survey to gather information and to evaluate the most promising available technologies for...

2005-12-21T23:59:59.000Z

113

Advancements in low NOx tangential firing systems  

Science Conference Proceedings (OSTI)

The most cost effective method of reducing nitrogen oxide emissions when burning fossil fuels, such as coal, is through in-furnace NOx reduction processes. ABB Combustion Engineering, Inc. (ABB CE), through its ABB Power Plant Laboratories has been involved in the development of such low NOx pulverized coal firing systems for many years. This development effort is most recently demonstrated through ABB CE`s involvement with the U.S. Department of Energy`s (DOE) {open_quotes}Engineering Development of Advanced Coal Fired Low-Emission Boiler Systems{close_quotes} (LEBS) project. The goal of the DOE LEBS project is to use {open_quotes}near term{close_quotes} technologies to produce a commercially viable, low emissions boiler. This paper addresses one of the key technologies within this project, the NOx control subsystem. The foundation for the work undertaken at ABB CE is the TFS 2000{trademark} firing system, which is currently offered on a commercial basis. This system encompasses sub-stoichiometric combustion in the main firing zone for reduced NOx formation. Potential enhancements to this firing system focus on optimizing the introduction of the air and fuel within the primary windbox to provide additional horizontal and vertical staging. As is the case with all in-furnace NOx control processes, it is necessary to operate the system in a manner which does not decrease NOx at the expense of reduced combustion efficiency.

Hein, R. von; Maney, C.; Borio, R. [and others

1996-12-31T23:59:59.000Z

114

OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL  

SciTech Connect

Conventional wisdom says adding oxygen to a combustion system enhances product throughput, system efficiency, and, unless special care is taken, increases NOx emissions. This increase in NOx emissions is typically due to elevated flame temperatures associated with oxygen use leading to added thermal NOx formation. Innovative low flame temperature oxy-fuel burner designs have been developed and commercialized to minimize both thermal and fuel NOx formation for gas and oil fired industrial furnaces. To be effective these systems require close to 100% oxy-fuel combustion and the cost of oxygen is paid for by fuel savings and other benefits. For applications to coal-fired utility boilers at the current cost of oxygen, however, it is not economically feasible to use 100% oxygen for NOx control. In spite of this conventional wisdom, Praxair and its team members, in partnership with the US Department of Energy National Energy Technology Laboratory, have developed a novel way to use oxygen to reduce NOx emissions without resorting to complete oxy-fuel conversion. In this concept oxygen is added to the combustion process to enhance operation of a low NOx combustion system. Only a small fraction of combustion air is replaced with oxygen in the process. By selectively adding oxygen to a low NOx combustion system it is possible to reduce NOx emissions from nitrogen-containing fuels, including pulverized coal, while improving combustion characteristics such as unburned carbon. A combination of experimental work and modeling was used to define how well oxygen enhanced combustion could reduce NOx emissions. The results of this work suggest that small amounts of oxygen replacement can reduce the NOx emissions as compared to the air-alone system. NOx emissions significantly below 0.15 lbs/MMBtu were measured. Oxygen addition was also shown to reduce carbon in ash. Comparison of the costs of using oxygen for NOx control against competing technologies, such as SCR, show that this concept offers substantial savings over SCR and is an economically attractive alternative to purchasing NOx credits or installing other conventional technologies. In conjunction with the development of oxygen based low NOx technology, Praxair also worked on developing the economically enhancing oxygen transport membrane (OTM) technology which is ideally suited for integration with combustion systems to achieve further significant cost reductions and efficiency improvements. This OTM oxygen production technology is based on ceramic mixed conductor membranes that operate at high temperatures and can be operated in a pressure driven mode to separate oxygen with infinite selectivity and high flux. An OTM material was selected and characterized. OTM elements were successfully fabricated. A single tube OTM reactor was designed and assembled. Testing of dense OTM elements was conducted with promising oxygen flux results of 100% of target flux. However, based on current natural gas prices and stand-alone air separation processes, ceramic membranes do not offer an economic advantage for this application. Under a different DOE-NETL Cooperative Agreement, Praxair is continuing to develop oxygen transport membranes for the Advanced Boiler where the economics appear more attractive.

David R. Thompson; Lawrence E. Bool; Jack C. Chen

2004-04-01T23:59:59.000Z

115

Process and apparatus for generating elemental sulfur and re-usable metal oxide from spent metal sulfide sorbents  

DOE Patents (OSTI)

A process and apparatus for generating elemental sulfur and re-usable metal oxide from spent metal-sulfur compound. Spent metal-sulfur compound is regenerated to re-usable metal oxide by moving a bed of spent metal-sulfur compound progressively through a single regeneration vessel having a first and second regeneration stage and a third cooling and purging stage. The regeneration is carried out and elemental sulfur is generated in the first stage by introducing a first gas of sulfur dioxide which contains oxygen at a concentration less than the stoichiometric amount required for complete oxidation of the spent metal-sulfur compound. A second gas containing sulfur dioxide and excess oxygen at a concentration sufficient for complete oxidation of the partially spent metal-sulfur compound, is introduced into the second regeneration stage. Gaseous sulfur formed in the first regeneration stage is removed prior to introducing the second gas into the second regeneration stage. An oxygen-containing gas is introduced into the third cooling and purging stage. Except for the gaseous sulfur removed from the first stage, the combined gases derived from the regeneration stages which are generally rich in sulfur dioxide and lean in oxygen, are removed from the regenerator as an off-gas and recycled as the first and second gas into the regenerator. Oxygen concentration is controlled by adding air, oxygen-enriched air or pure oxygen to the recycled off-gas.

Ayala, Raul E. (Clifton Park, NY); Gal, Eli (Lititz, PA)

1995-01-01T23:59:59.000Z

116

Lean NOx Trap Catalysis for Lean Natural Gas Engine Applications  

Science Conference Proceedings (OSTI)

Distributed energy is an approach for meeting energy needs that has several advantages. Distributed energy improves energy security during natural disasters or terrorist actions, improves transmission grid reliability by reducing grid load, and enhances power quality through voltage support and reactive power. In addition, distributed energy can be efficient since transmission losses are minimized. One prime mover for distributed energy is the natural gas reciprocating engine generator set. Natural gas reciprocating engines are flexible and scalable solutions for many distributed energy needs. The engines can be run continuously or occasionally as peak demand requires, and their operation and maintenance is straightforward. Furthermore, system efficiencies can be maximized when natural gas reciprocating engines are combined with thermal energy recovery for cooling, heating, and power applications. Expansion of natural gas reciprocating engines for distributed energy is dependent on several factors, but two prominent factors are efficiency and emissions. Efficiencies must be high enough to enable low operating costs, and emissions must be low enough to permit significant operation hours, especially in non-attainment areas where emissions are stringently regulated. To address these issues the U.S. Department of Energy and the California Energy Commission launched research and development programs called Advanced Reciprocating Engine Systems (ARES) and Advanced Reciprocating Internal Combustion Engines (ARICE), respectively. Fuel efficiency and low emissions are two primary goals of these programs. The work presented here was funded by the ARES program and, thus, addresses the ARES 2010 goals of 50% thermal efficiency (fuel efficiency) and engines are being pursued. Approaches include: stoichiometric engine operation with exhaust gas recirculation and three-way catalysis, advanced combustion modes such as homogeneous charge compression ignition, and extension of the lean combustion limit with advanced ignition concepts and/or hydrogen mixing. The research presented here addresses the technical approach of combining efficient lean spark-ignited natural gas combustion with low emissions obtained from a lean NOx trap catalyst aftertreatment system. This approach can be applied to current lean engine technology or advanced lean engines that may result from related efforts in lean limit extension. Furthermore, the lean NOx trap technology has synergy with hydrogen-assisted lean limit extension since hydrogen is produced from natural gas during the lean NOx trap catalyst system process. The approach is also applicable to other lean engines such as diesel engines, natural gas turbines, and lean gasoline engines; other research activities have focused on those applications. Some commercialization of the technology has occurred for automotive applications (both diesel and lean gasoline engine vehicles) and natural gas turbines for stationary power. The research here specifically addresses barriers to commercialization of the technology for large lean natural gas reciprocating engines for stationary power. The report presented here is a comprehensive collection of research conducted by Oak Ridge National Laboratory (ORNL) on lean NOx trap catalysis for lean natural gas reciprocating engines. The research was performed in the Department of Energy's ARES program from 2003 to 2007 and covers several aspects of the technology. All studies were conducted at ORNL on a Cummins C8.3G+ natural gas engine chosen based on industry input to simulate large lean natural gas engines. Specific technical areas addressed by the research include: NOx reduction efficiency, partial oxidation and reforming chemistry, and the effects of sulfur poisons on the partial oxidation

Parks, II, James E [ORNL; Storey, John Morse [ORNL; Theiss, Timothy J [ORNL; Ponnusamy, Senthil [ORNL; Ferguson, Harley Douglas [ORNL; Williams, Aaron M [ORNL; Tassitano, James B [ORNL

2007-09-01T23:59:59.000Z

117

Diesel Emission Control -- Sulfur Effects (DECSE) Program; Phase I Interim Data Report No. 2: NO{sub x} Adsorber Catalysts  

DOE Green Energy (OSTI)

The Diesel Emission Control-Sulfur Effects (DECSE) is a joint government/industry program to determine the impact of diesel fuel sulfur levels on emission control systems whose use could lower emissions of nitrogen oxides (NOx) and particulate matter (PM) from on-highway trucks in the 2002--2004 model years. Phase 1 of the program was developed with the following objectives in mind: (1) evaluate the effects of varying the level of sulfur content in the fuel on the emission reduction performance of four emission control technologies; and (2) measure and compare the effects of up to 250 hours of aging on selected devices for multiple levels of fuel sulfur content. This interim report discusses the results of the DECSE test program that demonstrates the potential of NOx adsorber catalyst technology across the range of diesel engine operation with a fuel economy penalty less than 4%.

DOE; ORNL; NREL; EMA; MECA

1999-10-15T23:59:59.000Z

118

Sulfur tolerant anode materials  

DOE Green Energy (OSTI)

The goal of this program is the development of a molten carbonate fuel cell (MCFC) anode which is more tolerant of sulfur contaminants in the fuel than the current state-of-the-art nickel-based anode structures. This program addresses two different but related aspects of the sulfur contamination problem. The primary aspect is concerned with the development of a sulfur tolerant electrocatalyst for the fuel oxidation reaction. A secondary issue is the development of a sulfur tolerant water-gas-shift reaction catalyst and an investigation of potential steam reforming catalysts which also have some sulfur tolerant capabilities. These two aspects are being addressed as two separate tasks.

Not Available

1988-05-01T23:59:59.000Z

119

NETL: News Release - DOE-Funded Technology Slashes NOx, Costs...  

NLE Websites -- All DOE Office Websites (Extended Search)

November 7, 2005 DOE-Funded Technology Slashes NOx, Costs in Coal-Fired Cyclone Boiler Utility Reconsiders Plans to Install Standard NOx-control Technology After Successful Field...

120

OBSERVATION-BASED METHODS (OBMS) FOR ANALYZING URBAN/REGIONAL OZONE PRODUCTION AND OZONE-NOx-VOC SENSITIVITY.  

E-Print Network (OSTI)

and reduction ofFormation and reduction of NOxNOx during burner combustionduring burner combustion ·· LowLow NOxNOx gas treatment forFlue gas treatment for NOxNOx reduction: SCR, SNCR, otherreduction: SCR, SNCR, other OF TECHNOLOGY ENE-47.153 Selective catalyticSelective catalytic reduction (SCR) ofreduction (SCR) of NOxNOx /1

Sillman, Sanford

Note: This page contains sample records for the topic "nox sulfur dioxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Evaluation of Gas Reburning & Low NOx Burners on a Wall Fired Boiler Performance and Economics Report Gas Reburning-Low NOx Burner System Cherokee Station Unit 3 Public Service Company of Colorado  

Science Conference Proceedings (OSTI)

Under the U.S. Department of Energy's Clean Coal Technology Program (Round 3), a project was completed to demonstrate control of boiler NOX emissions and to a lesser degree, due to coal replacement, SO2 emissions. The project involved combining Gas Reburning with Low NOX Burners (GR-LNB) on a coal-fired electric utility boiler to determine if high levels of NOX reduction (70%) could be achieved. Sponsors of the project included the U.S. Department of Energy, the Gas Research Institute, Public Service Company of Colorado, Colorado Interstate Gas, Electric Power Research Institute, and the Energy and Environmental Research Corporation. The GR-LNB demonstration was performed on Public Service Company of Colorado's (PSCO) Cherokee Unit #3, located in Denver, Colorado. This unit is a 172 MW~ wall-fired boiler that uses Colorado Bituminous, low-sulfur coal. It had a baseline NOX emission level of 0.73 lb/106 Btu using conventional burners. Low NOX burners are designed to yield lower NOX emissions than conventional burners. However, the NOX control achieved with this technique is limited to 30-50%. Also, with LNBs, CO emissions can increase to above acceptable standards. Gas Reburning (GR) is designed to reduce NOX in the flue gas by staged fuel combustion. This technology involves the introduction of natural gas into the hot furnace flue gas stream. When combined, GR and LNBs minimize NOX emissions and maintain acceptable levels of CO emissions. A comprehensive test program was completed, operating over a wide range of boiler conditions. Over 4,000 hours of operation were achieved, providing substantial data. Measurements were taken to quantify reductions in NOX emissions, the impact on boiler equipment and operability and factors influencing costs. The GR-LNB technology achieved good NOX emission reductions and the goals of the project were achieved. Although the performance of the low NOX burners (supplied by others) was less than expected, a NOX reduction of 65% was achieved at an average gas heat input of 18Y0. The performance goal of 70% reduction was met on many test runs, but at a higher reburn gas heat input. S02 emissions, based on coal replacement, were reduced by 18Y0. The performance goal of 70% reduction was met on many test runs, but at a higher reburn gas heat input. S02 emissions, based on coal replacement, were reduced by 18Y0. Toward the end of the program, a Second Generation gas injection system was installed. Higher injector gas pressures were used that eliminated the need for flue gas recirculation as used in the first generation design. The Second Generation GR resulted in similar NOX reduction performance as that for the First Generation. With an improvement in the LNB performance in combination with the new gas injection system , the reburn gas could be reduced to 12.5% of the total boiler heat input to achieve al 64?40 reduction in NO, emissions. In addition, the OFA injectors were modified to provide for better mixing to lower CO emissions.

None

1998-07-01T23:59:59.000Z

122

Steam effect on NOx reduction over lean NOx trap Pt–BaO/Al2O3 ...  

Science Conference Proceedings (OSTI)

Compared to dry atmosphere, steam promoted NOx reduction; however, under ... stored NOx over Pt–BaO/Al2O3 suggest that steam causes NH3 formation over ...

123

Novel Application of Air Separation Membranes Reduces Engine NOx Emissions  

Nitrogen oxide (NOx) emissions pose risks to human health, and so they need to be reduced. One very effective tool for reducing engine in-cylinder temperature and, hence NOx emissions (NOx is a strong function of temperature), is Exhaust Gas ...

124

(plexiglass) covers (negligible transmittance at 290320 nm). NOx emission decreased  

E-Print Network (OSTI)

that the controlling NOx formation and reduction reactions are insensi- tive to coal rank. This observation has been as the initial NOx level in- creases suggests that the char/NO reduction step(s) is more temperature sensitive concentrations cannot be reduced to levels ap- proaching 0 ppm without the use of downstream NOx reduction

125

Radiative forcing from aircraft NOx emissions: mechanisms and seasonal dependence  

E-Print Network (OSTI)

), a Babcock Power Inc. company, has developed a new, innovative, high-efficiency NOX reduction technology into a single unit and provides the maximum NOX reduction and heat recovery practical. The paper will describe emissions. A new system for the reduction of NOX emissions to levels hereby unheard of for US WTE boilers

Stevenson, David

126

NETL: Advanced NOx Emissions Control: Control Technology - Methane de-NOx  

NLE Websites -- All DOE Office Websites (Extended Search)

METHANE de-NOx® METHANE de-NOx® The Gas Technology Institute (GTI) is teaming with the All-Russian Thermal Engineering Institute and DB Riley to develop a pulverized-coal (PC)-combustion system that is an extension of IGT's METHANE de-NOx® technology. The technology is composed of a novel PC burner design using natural gas fired coal preheating developed and demonstrated in Russia, LNBs with internal combustion staging, and additional natural gas injection with overfire air. The coal is preheated at elevated temperatures (up to 1500oF) in oxygen deficient conditions prior to combustion. Coal preheat releases fuel-bound nitrogen together with volatiles present in the coal. These conditions promote the conversion of fuel-bound nitrogen to molecular nitrogen rather than to NOx.

127

Carbon Dioxide (CO2)  

NLE Websites -- All DOE Office Websites (Extended Search)

Carbon Dioxide (CO2) Carbon Dioxide (CO2) Gateway Pages to Carbon Dioxide Data Modern records and ice core records back 2000 years 800,000 year records from ice cores Other...

128

NOx Sensor for Direct Injection Emission Control  

DOE Green Energy (OSTI)

The Electricore/Delphi team continues to leverage the electrochemical planar sensor technology that has produced stoichiometric planar and wide range oxygen sensors as the basis for development of a NOx sensor. Zirconia cell technology with an integrated heater will provide the foundation for the sensor structure. Proven materials and packaging technology will help to ensure a cost-effective approach to the manufacture of this sensor. The electronics technique and interface is considered to be an area where new strategies need to be employed to produce higher S/N ratios of the NOx signal with emphasis on signal stability over time for robustness and durability Both continuous mode and pulse mode control techniques are being evaluated. Packaging the electronics requires careful design and circuit partitioning so that only the necessary signal conditioning electronics are coupled directly in the wiring harness, while the remainder is situated within the ECM for durability and costs reasons. This task continues to be on hold due to the limitation that the definition of the interface electronics was unavailable until very late in the project. The sense element is based on the amperometric method utilizing integrated alumina and zirconia ceramics. Precious metal electrodes are used to form the integrated heater, the cell electrodes and leads. Inside the actual sense cell structure, it is first necessary to separate NOx from the remaining oxygen constituents of the exhaust, without reducing the NOx. Once separated, the NOx will be measured using a measurement cell. Development or test coupons have been used to facilitate material selection and refinement, cell, diffusion barrier, and chamber development. The sense element currently requires elaborate interconnections. To facilitate a robust durable connection, mechanical and metallurgical connections are under investigation. Materials and process refinements continue to play an important role in the development of the sensor.

Betteridge, William J

2006-02-28T23:59:59.000Z

129

AMMONIA-FREE NOx CONTROL SYSTEM  

DOE Green Energy (OSTI)

This report describes a novel NOx control system that has the potential to drastically reduce cost, and enhance performance, operation and safety of power plant NOx control. The new system optimizes the burner and the furnace to achieve very low NOx levels and to provide an adequate amount of CO, and uses the CO for reducing NO both in-furnace and over a downstream AFSCR (ammonia-free selective catalytic reduction) reactor. The AF-SCR combines the advantages of the highly successful SCR technology for power plants and the TWC (three-way catalytic converter) widely used on automobiles. Like the SCR, it works in oxidizing environment of combustion flue gas and uses only base metal catalysts. Like the TWC, the AF-SCR removes NO and excess CO simultaneously without using any external reagent, such as ammonia. This new process has been studied in a development program jointed funded by the US Department of Energy and Foster Wheeler. The report outlines the experimental catalyst work performed on a bench-scale reactor, including test procedure, operating conditions, and results of various catalyst formulations. Several candidate catalysts, prepared with readily available transition metal oxides and common substrate materials, have shown over 80-90% removal for both NO and CO in oxidizing gas mixtures and at elevated temperatures. A detailed combustion study of a 400 MWe coal-fired boiler, applying computational fluid dynamics techniques to model boiler and burner design, has been carried out to investigate ways to optimize the combustion process for the lowest NOx formation and optimum CO/NO ratios. Results of this boiler and burner optimization work are reported. The paper further discusses catalyst scale-up considerations and the conceptual design of a 400 MWe size AF-SCR reactor, as well as economics analysis indicating large cost savings of the ammonia-free NOx control process over the current SCR technology.

Song Wu; Zhen Fan; Andrew H. Seltzer; Richard G. Herman

2006-06-01T23:59:59.000Z

130

Carbon Dioxide: Threat or Opportunity?  

E-Print Network (OSTI)

Over the past century, fossil fuel consumption has added carbon dioxide to the atmosphere at rapidly increasing rates. The prospect of further acceleration of this rate by turning from petroleum to coal has alarmed climatologists because of possible catastrophic long term effects on world climate. An alternative to discharging carbon dioxide into the atmosphere is to find new uses. One possible use is in 'Biofactories'. Biofactories may be achieved by exploiting two new developing technologies: Solar (Photosynthesis) energy, and genetic engineering. Some exciting new developments in genetic engineering will be touched on together with established bio-engineering-aquaculture, hydroponics, yeast, pharmaceutical production, fermentation, single cell protein, etc. A 'bio-factory' will be described, with a feed stream of carbon dioxide, water, nutrients containing sulfur, nitrogen, phosphorus and trace elements, and living culture interacting with light under controlled conditions to yield food and raw materials. Candidate products will be suggested and a few of the problems anticipated. Engineering and logistic requirements will be outlined and the economic impact assessed.

McKinney, A. R.

1982-01-01T23:59:59.000Z

131

ULTRA LOW NOx INTEGRATED SYSTEM FOR NOx EMISSION CONTROL FROM COAL-FIRED BOILERS  

Science Conference Proceedings (OSTI)

ALSTOM Power Inc.'s Power Plant Laboratories, working in concert with ALSTOM Power's Performance Projects Group, has teamed with the U.S. Department of Energy's National Energy Technology Laboratory (DOE NETL) to conduct a comprehensive study to develop/evaluate low-cost, efficient NOx control technologies for retrofit to pulverized coal fired utility boilers. The objective of this project was to develop retrofit NOx control technology to achieve less than 0.15 lb/MMBtu NOx (for bituminous coals) and 0.10 lb/MMBtu NOx (for subbituminous coals) from existing pulverized coal fired utility boilers at a cost which is at least 25% less than SCR technology. Efficient control of NOx is seen as an important, enabling step in keeping coal as a viable part of the national energy mix in this century, and beyond. Presently 57% of U.S. electrical generation is coal based, and the Energy Information Agency projects that coal will maintain a lead in U.S. power generation over all other fuel sources for decades (EIA 1998 Energy Forecast). Yet, coal-based power is being strongly challenged by society's ever-increasing desire for an improved environment and the resultant improvement in health and safety. The needs of the electric-utility industry are to improve environmental performance, while simultaneously improving overall plant economics. This means that emissions control technology is needed with very low capital and operating costs. This project has responded to the industry's need for low NOx emissions by evaluating ideas that can be adapted to present pulverized coal fired systems, be they conventional or low NOx firing systems. The TFS 2000{trademark} firing system has been the ALSTOM Power Inc. commercial offering producing the lowest NOx emission levels. In this project, the TFS 2000{trademark} firing system served as a basis for comparison to other low NOx systems evaluated and was the foundation upon which refinements were made to further improve NOx emissions and related combustion performance. Three coals were evaluated during the bench-scale and large pilot-scale testing tasks. The three coals ranged from a very reactive Powder River Basin coal (PRB) to a moderately reactive Midwestern bituminous coal (HVB) to a less reactive medium volatile Eastern bituminous coal (MVB). Bench-scale testing was comprised of standard ASTM properties evaluation, plus more detailed characterization of fuel properties through drop tube furnace testing and thermogravimetric analysis.

Galen H. Richards; Charles Q. Maney; Richard W. Borio; Robert D. Lewis

2002-12-30T23:59:59.000Z

132

Ultra-Low Sulfur Diesel  

NLE Websites -- All DOE Office Websites (Extended Search)

Ultra-Low Sulfur Diesel ULSD LSD Off-Road Ultra-Low Sulfur Highway Diesel Fuel (15 ppm Sulfur Maximum). Required for use in all model year 2007 and later highway diesel vehicles...

133

Investigation Of Synergistic NOx Reduction From Cofiring And Air Staged Combustion Of Coal And Low Ash Dairy Biomass In A 30 Kilowatt Low NOx Furnace  

E-Print Network (OSTI)

Alternate, cost effective disposal methods must be developed for reducing phosphorous and nitrogen loading from land application of animal waste. Cofiring coal with animal waste, termed dairy biomass (DB), is the proposed thermo-chemical method to address this concern. DB is evaluated as a cofired fuel with Wyoming Powder River Basin (PRB) sub-bituminous coal in a small-scale 29 kW_(t) low NO_(x) burner (LNB) facility. Fuel properties, of PRB and DB revealed the following: a higher heating value of 29590 kJ/kg for dry ash free (DAF) coal and 21450 kJ/kg for DAF DB. A new method called Respiratory Quotient (RQ), defined as ratio of carbon dioxide moles to oxygen moles consumed in combustion, used widely in biology, was recently introduced to engineering literature to rank global warming potential (GWP) of fuels. A higher RQ means higher CO_(2) emission and higher GWP. PRB had an RQ of 0.90 and DB had an RQ of 0.92. For comparison purposes, methane has an RQ of 0.50. For unknown fuel composition, gas analyses can be adapted to estimate RQ values. The LNB was modified and cofiring experiments were performed at various equivalence ratios (phi) with pure coal and blends of PRB-DB. Standard emissions from solid fuel combustion were measured; then NO_(x) on a heat basis (g/GJ), fuel burnt fraction, and fuel nitrogen conversion percentage were estimated. The gas analyses yielded burnt fraction ranging from 89% to 100% and confirmed an RQ of 0.90 to 0.94, which is almost the same as the RQ based on fuel composition. At the 0.90 equivalence ratio, unstaged pure coal produced 653 ppm (377 g/GJ) of NOx. At the same equivalence ratio, a 90-10 PRB:LADB blended fuel produced 687 ppm (397 g/GJ) of NO_(x). By staging 20% of the total combustion air as tertiary air (which raised the equivalence ratio of the main burner to 1.12), NO_(x) was reduced to 545 ppm (304 g/GJ) for the 90-10 blended fuel. Analysis of variance showed that variances were statistically significant because of real differences between the independent variables (equivalence ratio, percent LADB in the fuel, and staging intensity).

Lawrence, Benjamin Daniel

2013-08-01T23:59:59.000Z

134

CLOSEOUT REPORT FOR HYBRID SULFUR PRESSURIZED BUTTON CELL TEST FACILITY  

DOE Green Energy (OSTI)

This document is the Close-Out Report for design and partial fabrication of the Pressurized Button Cell Test Facility at Savannah River National Laboratory (SRNL). This facility was planned to help develop the sulfur dioxide depolarized electrolyzer (SDE) that is a key component of the Hybrid Sulfur Cycle for generating hydrogen. The purpose of this report is to provide as much information as possible in case the decision is made to resume research. This report satisfies DOE Milestone M3GSR10VH030107.0. The HyS Cycle is a hybrid thermochemical cycle that may be used in conjunction with advanced nuclear reactors or centralized solar receivers to produce hydrogen by watersplitting. The HyS Cycle utilizes the high temperature (>800 C) thermal decomposition of sulfuric acid to produce oxygen and regenerate sulfur dioxide. The unique aspect of HyS is the generation of hydrogen in a water electrolyzer that is operated under conditions where dissolved sulfur dioxide depolarizes the anodic reaction, resulting in substantial voltage reduction. Low cell voltage is essential for both high thermodynamic efficiency and low hydrogen cost. Sulfur dioxide is oxidized at the anode, producing sulfuric acid that is sent to the high temperature acid decomposition portion of the cycle. Sulfur dioxide from the decomposer is cycled back to electrolyzers. The electrolyzer cell uses the membrane electrode assembly (MEA) concept. Anode and cathode are formed by spraying a catalyst, typically platinized carbon, on both sides of a Proton Exchange Membrane (PEM). SRNL has been testing SDEs for several years including an atmospheric pressure Button Cell electrolyzer (2 cm{sup 2} active area) and an elevated temperature/pressure Single Cell electrolyzer (54.8 cm{sup 2} active area). SRNL tested 37 MEAs in the Single Cell electrolyzer facility from June 2005 until June 2009, when funding was discontinued. An important result of the final months of testing was the development of a method that prevents the formation of a sulfur layer previously observed in MEAs used in the Hybrid Sulfur Cycle electrolyzer. This result is very important because the sulfur layer increased cell voltage and eventually destroyed the MEA that is the heart of the cell. Steimke and Steeper [2005, 2006, 2007, 2008] reported on testing in the Single Cell Electrolyzer test facility in several periodic reports. Steimke et. al [2010] issued a final facility close-out report summarizing all the testing in the Single Cell Electrolyzer test facility. During early tests, significant deterioration of the membrane occurred in 10 hours or less; the latest tests ran for at least 200 hours with no sign of deterioration. Ironically, the success with the Single Cell electrolyzer meant that it became dedicated to long runs and not available for quick membrane evaluations. Early in this research period, the ambient pressure Button Cell Electrolyzer test facility was constructed to quickly evaluate membrane materials. Its small size allowed testing of newly developed membranes that typically were not available in sizes large enough to test in the Single Cell electrolyzer. The most promising membranes were tested in the Single Cell Electrolyzer as soon as sufficient large membranes could be obtained. However, since the concentration of SO{sub 2} gas in sulfuric acid decreases rapidly with increasing temperature, the ambient pressure Button Cell was no longer able to achieve the operating conditions needed to evaluate the newer improved high temperature membranes. Significantly higher pressure operation was required to force SO{sub 2} into the sulfuric acid to obtain meaningful concentrations at increased temperatures. A high pressure (200 psig), high temperature (120 C) Button Cell was designed and partially fabricated just before funding was discontinued in June 2009. SRNL completed the majority of the design of the test facility, including preparation of a process and instrument drawing (P&ID) and preliminary designs for the major components. SRNL intended to complete the designs and procu

Steeper, T.

2010-09-15T23:59:59.000Z

135

Sulfur tolerance of selective partial oxidation of NO to NO2 in a plasma  

DOE Green Energy (OSTI)

Several catalytic aftertreatment technologies rely on the conversion of NO to NO2 to achieve efficient reduction of NOx and particulates in diesel exhaust. These technologies include the use of selective catalytic reduction of NOx with hydrocarbons, NOx adsorption, and continuously regenerated particulate trapping. These technologies require low sulfur fuel because the catalyst component that is active in converting NO to NO2 is also active in converting SO2 to SO3 . The SO3 leads t o increase in particulates and/or poison active sites on the catalyst. A non-thermal plasma can be used for the selective partial oxidation of NO to NO2 in the gas-phase under diesel engine exhaust conditions. This paper discusses how a non-thermal plasma can efficiently oxidize NO to NO2 without oxidizing SO2 to SO3 .

Penetrante, B; Brusasco, R M; Merritt, B T; Vogtlin, G E

1999-08-24T23:59:59.000Z

136

Bacterial Sulfur Storage Globules  

NLE Websites -- All DOE Office Websites (Extended Search)

by I. J. Pickering and G. N. George by I. J. Pickering and G. N. George Sulfur is essential for all life, but it plays a particularly central role in the metabolism of many anaerobic microorganisms. Prominent among these are the sulfide-oxidizing bacteria that oxidize sulfide (S2-) to sulfate (SO42-). Many of these organisms can store elemental sulfur (S0) in "globules" for use when food is in short supply (Fig. 1). The chemical nature of the sulfur in these globules has been an enigma since they were first described as far back as 1887 (1); all known forms (or allotropes) of elemental sulfur are solid at room temperature, but globule sulfur has been described as "liquid", and it apparently has a low density – 1.3 compared to 2.1 for the common yellow allotrope a-sulfur. Various exotic forms of sulfur have been proposed to explain these properties, including micelles (small bubble-like structures) formed from long-chain polythionates, but all of these deductions have been based upon indirect evidence (for example the density was estimated by flotation of intact cells), and many questions remained.

137

NOx Reduction with Natural Gas for Lean Large-Bore Engine Applications Using Lean NOx Trap Aftertreatment  

SciTech Connect

Large-bore natural gas engines are used for distributed energy and gas compression since natural gas fuel offers a convenient and reliable fuel source via the natural gas pipeline and distribution infrastructure. Lean engines enable better fuel efficiency and lower operating costs; however, NOx emissions from lean engines are difficult to control. Technologies that reduce NOx in lean exhaust are desired to enable broader use of efficient lean engines. Lean NOx trap catalysts have demonstrated greater than 90% NOx reduction in lean exhaust from engines operating with gasoline, diesel, and natural gas fuels. In addition to the clean nature of the technology, lean NOx traps reduce NOx with the fuel source of the engine thereby eliminating the requirement for storage and handling of secondary fuels or reducing agents. A study of lean NOx trap catalysts for lean natural gas engines is presented here. Testing was performed on a Cummins C8.3G (CG-280) engine on a motor dynamometer. Lean NOx trap catalysts were tested for NOx reduction performance under various engine operating conditions, and the utilization of natural gas as the reductant fuel source was characterized. Engine test results show that temperature greatly affects the catalytic processes involved, specifically methane oxidation and NOx storage on the lean NOx trap. Additional studies on a bench flow reactor demonstrate the effect of precious metal loading (a primary cost factor) on lean NOx trap performance at different temperatures. Results and issues related to the potential of the lean NOx trap technology for large-bore engine applications will be discussed.

Parks, JE

2005-02-11T23:59:59.000Z

138

OVERVIEW: TROPOSPHERIC OZONE, SMOG AND OZONE-NOx-VOC SENSITIVITY. Dr. Sanford Sillman  

E-Print Network (OSTI)

. MERMCI and the Waste System Authority of Montgomery County (WSA) evaluated the different NOx reduction-Catalytic Reduction (SNCR) system. The NOxOUT® process is a post combustion NOx reduction method that reduces NOx. Such modifications have been successfully employed to achieve 25-70% reduction in NOx from fossil-fueled combusters

Sillman, Sanford

139

Diesel Emission Control -- Sulfur Effects (DECSE) Program; Phase I Interim Data Report No. 4: Diesel Particulate Filters -- Final Report  

DOE Green Energy (OSTI)

The Diesel Emission Control-Sulfur Effects (DECSE) is a joint government/industry program to determine the impact of diesel fuel sulfur levels on emission control systems whose use could lower emissions of nitrogen oxides (NOx) and particulate matter (PM) from on-highway trucks in the 2002--2004 model years. Phase 1 of the program was developed with the following objectives in mind: (1) evaluate the effects of varying the level of sulfur content in the fuel on the emission reduction performance of four emission control technologies; and (2) measure and compare the effects of up to 250 hours of aging on selected devices for multiple levels of fuel sulfur content. This is the fourth and final report for the DPF test program and covers the effect of diesel sulfur level on: a catalyzed diesel particulate filter (CDPF), and a continuously regenerating diesel particulate filter (CR-DPF).

DOE; ORNL; NREL; EMA; MECA

2000-01-15T23:59:59.000Z

140

Operational Flexibility Guidelines for Gas Turbine Low NOx Combustion Systems  

Science Conference Proceedings (OSTI)

Gas turbine low-NOx combustion systems can differ in hardware from manufacturer to manufacturer, but the principle is the same. Low-NOx combustors reduce peak flame temperatures by mixing fuel and air before combustion and by keeping the fuel-to-air ratio as low (lean) as possible, while still maintaining combustion stability over the broadest possible operating range. Low-NOx combustion systems are inherently more complex than diffusion combustion systems, a fact that impacts operational flexibility, re...

2011-12-14T23:59:59.000Z

Note: This page contains sample records for the topic "nox sulfur dioxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

CARBON SEQUESTRATION IN ALASKA'S BOREAL FOREST: PLANNING FOR RESILIENCE IN A CHANGING LANDSCAPE  

E-Print Network (OSTI)

results in emissions of sulfur dioxide (SO2), nitrogen oxides (NOx), particulates, mercury, and other in emissions of sulfur dioxide (SO2), nitrogen oxides (NOx), particulates, and mercury Figure 11: Gasification pressure than is found in post-combustion flue gases (Rosenberg et al., 2005). This pre- combustion

Ruess, Roger W.

142

NETL: Advanced NOx Emissions Control: Control Technology - Mercury...  

NLE Websites -- All DOE Office Websites (Extended Search)

Mercury Speciation from NOx Control University of North Dakota Energy and Environmental Research Center (UNDEERC) is addressing the impact that selective catalytic reduction (SCR),...

143

Development of the Hybrid Sulfur Thermochemical Cycle  

DOE Green Energy (OSTI)

The production of hydrogen via the thermochemical splitting of water is being considered as a primary means for utilizing the heat from advanced nuclear reactors to provide fuel for a hydrogen economy. The Hybrid Sulfur (HyS) Process is one of the baseline candidates identified by the U.S. Department of Energy [1] for this purpose. The HyS Process is a two-step hybrid thermochemical cycle that only involves sulfur, oxygen and hydrogen compounds. Recent work has resulted in an improved process design with a calculated overall thermal efficiency (nuclear heat to hydrogen, higher heating value basis) approaching 50%. Economic analyses indicate that a nuclear hydrogen plant employing the HyS Process in conjunction with an advanced gas-cooled nuclear reactor system can produce hydrogen at competitive prices. Experimental work has begun on the sulfur dioxide depolarized electrolyzer, the major developmental component in the cycle. Proof-of-concept tests have established proton-exchange-membrane cells (a state-of-the-art technology) as a viable approach for conducting this reaction. This is expected to lead to more efficient and economical cell designs than were previously available. Considerable development and scale-up issues remain to be resolved, but the development of a viable commercial-scale HyS Process should be feasible in time to meet the commercialization schedule for Generation IV gas-cooled nuclear reactors.

Summers, William A.; Steimke, John L

2005-09-23T23:59:59.000Z

144

Using ISC & GIS to predict sulfur deposition from coal-fired power plants  

E-Print Network (OSTI)

The goal of this research project was to determine if atmospheric sources have the potential of contributing significantly to the sulfur content of grazed forage. Sulfur deposition resulting from sulfur dioxide emissions from coal- fired power plants was predicted utilizing the Industrial Source Complex Long-Term (ISCLT2) Model for the areas ofa interest in East Texas. GRASS, a geographical information system (GIS), was used to pull together all predicted values from ISCLT2 and present them in the form of predicted sulfur deposition maps with different ranges of deposition. Two field trips to NE Texas were taken to obtain data on soil and forage sulfur content. GRASS was used extensively in the planning process before each trip and the global positioning system was also used extensively during the trip to locate sampling sites and to obtain the geographical location of each site. The methodology developed predicts that 11 to 21 kg sulfur/ha per year can be deposited as far as 100 to 160 km from the source. Data from both field trips do not show a statistical significant relation between predicted sulfur deposition and either soil or forage sulfur content. However, the data do show that there is a trend of increasing soil and forage sulfur content as predicted sulfur deposition increases.

Lopez, Jose Ignacio

1993-01-01T23:59:59.000Z

145

Aminoguanidine inhibits aortic hydrogen peroxide production, VSMC NOX activity and hypercontractility in diabetic mice  

E-Print Network (OSTI)

likely via a reduction in NOX-linked hypercontractility.signif- icant reduction in VSMC NOX activity remains to beNOX-derived O 2•- in diabetic VSMC might underlie AG reduction

Oak, Jeong-Ho; Youn, Ji-Youn; Cai, Hua

2009-01-01T23:59:59.000Z

146

Power plant emissions of sulfur dioxide and nitrogen oxides ...  

U.S. Energy Information Administration (EIA)

Have a question, comment, or suggestion for a future article? Send your feedback to todayinenergy@eia.gov

147

Abatement of Air Pollution: Control of Sulfur Dioxide Emissions...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

serve a generator with a nameplate capacity of 15 MW or more, or fossil-fuel fired boilers or indirect heat exchangers with a maximum input heat capacity of 250 MMBtuhr or...

148

Power plant emissions of sulfur dioxide and nitrogen oxides ...  

U.S. Energy Information Administration (EIA)

Nuclear & Uranium. Uranium fuel ... acid rain program in the eastern half of the United States. ... and settlements under the Clean Air Act's New Source Review ...

149

Power plant emissions of sulfur dioxide and nitrogen oxides ...  

U.S. Energy Information Administration (EIA)

State Energy Data System ... the program provided an economic incentive for coal-fired power plants to reduce emissions by installing pollution contro ...

150

Mercury removal from coal by leaching with sulfur-dioxide.  

E-Print Network (OSTI)

??Mercury from coal-fired utilities has been identified as one of the most hazardous air pollutants and the greatest potential public health concern. Furthermore, it has… (more)

Chateker, Poornima.

2010-01-01T23:59:59.000Z

151

Preservation of chopped sweet sorghum using sulfur dioxide  

Science Conference Proceedings (OSTI)

Sweet sorghum (Sorghum bicolor (L.) Moench) is an attractive feedstock for fermentation but its sugars degrade quickly after harvest. The effects of SO/sub 2/ dosage and temperature on the storability of chopped Rio sweet sorghum was studied. Four SO/sub 2/ dosage levels (0, 0.5, 1.5 and 3.0% w.b.) and five storage temperatures (-16, 2, 12, 22 and 32/sup 0/C) were investigated. The samples were stored in constant temperature incubators for three months. Fermentable sugars, sample pH and initial and final SO/sub 2/ levels were determined. All three non-zero levels of SO/sub 2/ adequately preserved the chopped sweet sorghum with no significant decrease in the total fermentable sugars.

Eckhoff, S.R.; Bender, D.A.; Okos, M.R.; Peart, R.M.

1983-12-01T23:59:59.000Z

152

Carbon Dioxide Compression  

Science Conference Proceedings (OSTI)

Page 1. © C opyright 2009 Carbon Dioxide Compression DOE – EPRI – NIST ... Greenhouse gas sequestration Page 5. 5 © C opyright 2009 ...

2013-04-22T23:59:59.000Z

153

APBF-DEC NOx Adsorber/DPF Project: Light-Duty Passenger Car Platform  

DOE Green Energy (OSTI)

A 1.9L turbo direct injection (TDI) diesel engine was modified to achieve the upcoming Tier 2 Bin 5 emission standard in combination with a NOx adsorber catalyst (NAC) and a diesel particulate filter (DPF). The primary objective for developing this test bed is to investigating the effects of different fuel sulfur contents on the performance of an advanced emission control system (ECS) in a light-duty application. During the development process, the engine-out emissions were minimized by applying a state-of-the-art combustion system in combination with cooled exhaust gas recirculation (EGR). The subsequent calibration effort resulted in emission levels requiring 80-90 percent nitrogen-oxide (NOx) and particulate matter (PM) conversion rates by the corresponding ECS. The strategy development included ean/rich modulation for NAC regeneration, as well as, the desulfurization of the NAC and the regeneration of the DPF. Two slightly different ECS were investigated and calibrated. The initial vehicle results in an Audi A4 station wagon over the federal test procedure (FTP), US 06, and the highway fuel economy test (HFET) cycle indicate the potential of these configuration to meet the future Tier 2 emission standard.

Tomazic, D; Tatur, M; Thornton, M

2003-08-24T23:59:59.000Z

154

Assessment of Alternative Post-Combustion NOx Controls Technologies  

Science Conference Proceedings (OSTI)

As emission control requirements continually become stricter, power producers need new, efficient, cost-effective approaches to reduce NOx and other atmospheric pollutants. This report focuses on alternative emerging and commercial post-combustion NOx controls applications other than the industry standard selective catalytic reduction (SCR) technology.

2008-12-01T23:59:59.000Z

155

NOx reduction by electron beam-produced nitrogen atom injection  

DOE Patents (OSTI)

Deactivated atomic nitrogen generated by an electron beam from a gas stream containing more than 99% N.sub.2 is injected at low temperatures into an engine exhaust to reduce NOx emissions. High NOx reduction efficiency is achieved with compact electron beam devices without use of a catalyst.

Penetrante, Bernardino M. (San Ramon, CA)

2002-01-01T23:59:59.000Z

156

Trifluoromethyl Sulfur Pentafluoride (SF5CF3) and Sulfur Hexafluoride...  

NLE Websites -- All DOE Office Websites (Extended Search)

Sulfur Pentafluoride (SF5CF3) and Sulfur Hexafluoride (SF6) from Dome Concordia graphics Graphics data Data Investigators W. T. Sturges,1 T. J. Wallington,2 M. D. Hurley,2 K....

157

Air Pollution Control Regulations: No. 41 - Nox Budget Trading Program  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

41 - Nox Budget Trading 41 - Nox Budget Trading Program (Rhode Island) Air Pollution Control Regulations: No. 41 - Nox Budget Trading Program (Rhode Island) < Back Eligibility Commercial Industrial Investor-Owned Utility Municipal/Public Utility Rural Electric Cooperative Utility Savings Category Alternative Fuel Vehicles Hydrogen & Fuel Cells Program Info State Rhode Island Program Type Environmental Regulations Provider Department of Environmental Management These regulations establish a budget trading program for nitrogen oxide emissions, setting NOx budget units for generators and an NOx Allowance Tracking System to account for emissions. These regulations apply to units that serve generators with a nameplate capacity greater than 15 MWe and sell any amount of electricity, as well as to units that have a maximum

158

Sodium sulfur battery seal  

DOE Patents (OSTI)

This disclosure is directed to an improvement in a sodium sulfur battery construction in which a seal between various battery compartments is made by a structure in which a soft metal seal member is held in a sealing position by holding structure. A pressure applying structure is used to apply pressure on the soft metal seal member when it is being held in sealing relationship to a surface of a container member of the sodium sulfur battery by the holding structure. The improvement comprises including a thin, well-adhered, soft metal layer on the surface of the container member of the sodium sulfur battery to which the soft metal seal member is to be bonded.

Mikkor, Mati (Ann Arbor, MI)

1981-01-01T23:59:59.000Z

159

Low quality natural gas sulfur removal/recovery  

Science Conference Proceedings (OSTI)

The project comprises a Base Program and an Optional Program. The Base Program, which included NEPA reporting, process design and an experimental research plan for the optional program, was completed August 31, 1993 with submission of the Task 2 Final Report. The Optional Program, Task 3, began in July 1994. The project goal is to further develop and demonstrate two of the component technologies of the CFZ-CNG Process: (1) pilot-scale triple-point crystallization of carbon dioxide, producing commercially pure carbon dioxide from contaminated carbon dioxide at the rate of 25 ton/day, and (2) bench-scale modified high pressure Claus technology, recovering elemental sulfur from hydrogen sulfide at the rate of 200 lb/day.

Siwajek, L.A. [Acrion Technologies, Inc., Cleveland, OH (United States); Kuehn, L. [Bovar Corp., Houston, TX (United States). Western Research

1995-06-01T23:59:59.000Z

160

Simultaneous removal of nitrogen oxides and sulfur oxides from combustion gases  

DOE Patents (OSTI)

A process for the simultaneous removal of sulfur oxides and nitrogen oxides from power plant stack gases comprising contacting the stack gases with a supported iron oxide catalyst/absorbent in the presence of sufficient reducing agent selected from the group consisting of carbon monoxide, hydrogen, and mixtures thereof, to provide a net reducing atmosphere in the SO.sub.x /NO.sub.x removal zone. The sulfur oxides are removed by absorption substantially as iron sulfide, and nitrogen oxides are removed by catalytic reduction to nitrogen and ammonia. The spent iron oxide catalyst/absorbent is regenerated by oxidation and is recycled to the contacting zone. Sulfur dioxide is also produced during regeneration and can be utilized in the production of sulfuric acid and/or sulfur.

Clay, David T. (Longview, WA); Lynn, Scott (Walnut Creek, CA)

1976-10-19T23:59:59.000Z

Note: This page contains sample records for the topic "nox sulfur dioxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
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161

ELECTRON IRRADIATION OF CARBON DISULFIDE-OXYGEN ICES: TOWARD THE FORMATION OF SULFUR-BEARING MOLECULES IN INTERSTELLAR ICES  

Science Conference Proceedings (OSTI)

The formation of sulfur-bearing molecules in interstellar ices was investigated during the irradiation of carbon disulfide (CS{sub 2})-oxygen (O{sub 2}) ices with energetic electrons at 12 K. The irradiation-induced chemical processing of these ices was monitored online and in situ via Fourier transform infrared spectroscopy to probe the newly formed products quantitatively. The sulfur-bearing molecules produced during the irradiation were sulfur dioxide (SO{sub 2}), sulfur trioxide (SO{sub 3}), and carbonyl sulfide (OCS). Formations of carbon dioxide (CO{sub 2}), carbon monoxide (CO), and ozone (O{sub 3}) were observed as well. To fit the temporal evolution of the newly formed products and to elucidate the underlying reaction pathways, kinetic reaction schemes were developed and numerical sets of rate constants were derived. Our studies suggest that carbon disulfide (CS{sub 2}) can be easily transformed to carbonyl sulfide (OCS) via reactions with suprathermal atomic oxygen (O), which can be released from oxygen-containing precursors such as water (H{sub 2}O), carbon dioxide (CO{sub 2}), and/or methanol (CH{sub 3}OH) upon interaction with ionizing radiation. This investigation corroborates that carbonyl sulfide (OCS) and sulfur dioxide (SO{sub 2}) are the dominant sulfur-bearing molecules in interstellar ices.

Maity, Surajit; Kaiser, Ralf I. [Department of Chemistry, University of Hawai'i at Manoa, Honolulu, HI 96822 (United States)

2013-08-20T23:59:59.000Z

162

NOx Control for Utility Boiler OTR Compliance  

Science Conference Proceedings (OSTI)

Under sponsorship of the Department of Energy's National Energy Technology Laboratory (NETL), the Babcock and Wilcox Company (B and W), and Fuel Tech teamed together to investigate an integrated solution for NO{sub x} control. The system is comprised of B and W's DRB-4Z{trademark} ultra low-NO{sub x} pulverized coal (PC) burner technology and Fuel Tech's NOxOUT{reg_sign}, a urea-based selective non-catalytic reduction (SNCR) technology. Development of the low-NO{sub x} burner technology has been a focus in B and W's combustion program. The DRB-4Z{trademark} burner is B and W's newest low-NO{sub x} burner capable of achieving very low NO{sub x}. The burner is designed to reduce NO{sub x} by controlled mixing of the fuel and air. Based on data from several 500 to 600 MWe boilers firing PRB coal, NOx emissions levels of 0.15 to 0.20 lb/ 106 Btu have been achieved from the DRB-4Z{trademark} burners in combination with overfire air ports. Although NOx emissions from the DRB-4Z{trademark} burner are nearing the Ozone Transport Rule (OTR) level of 0.15 lb NO{sub x}/106 Btu, the utility boiler owners can still benefit from the addition of an SNCR and/or SCR system in order to comply with the stringent NO{sub x} emission levels facing them. Large-scale testing is planned in B and W's 100-million Btu/hr Clean Environment Development Facility (CEDF) that simulates the conditions of large coal-fired utility boilers. The objective of the project is to achieve a NO{sub x} level below 0.15 lb/106 Btu (with ammonia slip of less than 5 ppm) in the CEDF using PRB coal and B and W's DRB-4Z{trademark} low-NO{sub x} pulverized coal (PC) burner in combination with dual zone overfire air ports and Fuel Tech's NO{sub x}OUT{reg_sign}. During this period B and W prepared and submitted the project management plan and hazardous substance plan to DOE. The negotiation of a subcontract for Fuel Tech has been started.

Hamid Farzan

2003-12-31T23:59:59.000Z

163

Flue Gas Purification Utilizing SOx/NOx Reactions During Compressin of CO2 Derived from Oxyfuel Combustion  

NLE Websites -- All DOE Office Websites (Extended Search)

Flue Gas Purification Flue Gas Purification Utilizing SO X /NO X Reactions During Compression of CO 2 Derived from Oxyfuel Combustion Background Oxy-combustion in a pulverized coal-fired power station produces a raw carbon dioxide (CO 2 ) product containing contaminants such as water vapor, oxygen, nitrogen, and argon from impurities in the oxygen used and any air leakage into the system. Acid gases are also produced as combustion products, such as sulfur oxides (SO

164

Sodium sulfur battery seal  

SciTech Connect

This invention is directed to a seal for a sodium sulfur battery in which a flexible diaphragm sealing elements respectively engage opposite sides of a ceramic component of the battery which separates an anode compartment from a cathode compartment of the battery.

Topouzian, Armenag (Birmingham, MI)

1980-01-01T23:59:59.000Z

165

SULFUR POLYMER ENCAPSULATION.  

SciTech Connect

Sulfur polymer cement (SPC) is a thermoplastic polymer consisting of 95 wt% elemental sulfur and 5 wt% organic modifiers to enhance long-term durability. SPC was originally developed by the U.S. Bureau of Mines as an alternative to hydraulic cement for construction applications. Previous attempts to use elemental sulfur as a construction material in the chemical industry failed due to premature degradation. These failures were caused by the internal stresses that result from changes in crystalline structure upon cooling of the material. By reacting elemental sulfur with organic polymers, the Bureau of Mines developed a product that successfully suppresses the solid phase transition and significantly improves the stability of the product. SPC, originally named modified sulfur cement, is produced from readily available, inexpensive waste sulfur derived from desulfurization of both flue gases and petroleum. The commercial production of SPC is licensed in the United States by Martin Resources (Odessa, Texas) and is marketed under the trade name Chement 2000. It is sold in granular form and is relatively inexpensive ({approx}$0.10 to 0.12/lb). Application of SPC for the treatment of radioactive, hazardous, and mixed wastes was initially developed and patented by Brookhaven National Laboratory (BNL) in the mid-1980s (Kalb and Colombo, 1985; Colombo et al., 1997). The process was subsequently investigated by the Commission of the European Communities (Van Dalen and Rijpkema, 1989), Idaho National Engineering Laboratory (Darnell, 1991), and Oak Ridge National Laboratory (Mattus and Mattus, 1994). SPC has been used primarily in microencapsulation applications but can also be used for macroencapsulation of waste. SPC microencapsulation has been demonstrated to be an effective treatment for a wide variety of wastes, including incinerator hearth and fly ash; aqueous concentrates such as sulfates, borates, and chlorides; blowdown solutions; soils; and sludges. It is not recommended for treatment of wastes containing high concentrations of nitrates because of potentially dangerous reactions between sulfur, nitrate, and trace quantities of organics. Recently, the process has been adapted for the treatment of liquid elemental mercury and mercury contaminated soil and debris.

KALB, P.

2001-08-22T23:59:59.000Z

166

METHANE de-NOX for Utility PC Boilers  

SciTech Connect

The overall project objective is the development and validation of an innovative combustion system, based on a novel coal preheating concept prior to combustion, that can reduce NO{sub x} emissions to 0.15 lb/million Btu or less on utility pulverized coal (PC) boilers. This NO{sub x} reduction should be achieved without loss of boiler efficiency or operating stability, and at more than 25% lower levelized cost than state-of-the-art SCR technology. A further objective is to ready technology for full-scale commercial deployment to meet the market demand for NO{sub x} reduction technologies. Over half of the electric power generated in the U.S. is produced by coal combustion, and more than 80% of these units utilize PC combustion technology. Conventional measures for NOx reduction in PC combustion processes rely on combustion and post-combustion modifications. A variety of combustion-based NO{sub x} reduction technologies are in use today, including low-NO{sub x} burners (LNBs), flue gas recirculation (FGR), air staging, and natural gas or other fuel reburning. Selective non-catalytic reduction (SNCR) and selective catalytic reduction (SCR) are post-combustion techniques. NO{sub x} reduction effectiveness from these technologies ranges from 30 to 60% and up to 90-93% for SCR. Typically, older wall-fired PC burner units produce NO{sub x} emissions in the range of 0.8-1.6 lb/million Btu. Low-NO{sub x} burner systems, using combinations of fuel staging within the burner and air staging by introduction of overfire air in the boiler, can reduce NO{sub x} emissions by 50-60%. This approach alone is not sufficient to meet the desired 0.15 lb/million Btu NO{sub x} standard with a range of coals and boiler loads. Furthermore, the heavy reliance on overfire air can lead to increased slagging and corrosion in furnaces, particularly with higher-sulfur coals, when LNBs are operated at sub-stoichiometric conditions to reduce fuel-derived NOx in the flame. Therefore, it is desirable to minimize the need for overfire air by maximizing NO{sub x} reduction in the burner. The proposed combustion concept aims to greatly reduce NO{sub x} emissions by incorporating a novel modification to conventional or low-NO{sub x} PC burners using gas-fired coal preheating to destroy NO{sub x} precursors and prevent NO{sub x} formation. A concentrated PC stream enters the burner, where flue gas from natural gas combustion is used to heat the PC up to about 1500 F prior to coal combustion. Secondary fuel consumption for preheating is estimated to be 3 to 5% of the boiler heat input. This thermal pretreatment releases coal volatiles, including fuel-bound nitrogen compounds into oxygen-deficient atmosphere, which converts the coal-derived nitrogen compounds to molecular N{sub 2} rather than NO. Design, installation, shakedown, and testing on Powder River Basin (PRB) coal at a 3-million Btu/h pilot system at RPI's (Riley Power, Inc.) pilot-scale combustion facility (PSCF) in Worcester, MA demonstrated that the PC PREHEAT process has a significant effect on final O{sub x} formation in the coal burner. Modifications to both the pilot system gas-fired combustor and the PC burner led to NO{sub x} reduction with PRB coal to levels below 0.15 lb/million Btu with CO in the range of 35-112 ppmv without any furnace air staging.

Bruce Bryan; Serguei Nester; Joseph Rabovitser; Stan Wohadlo

2005-09-30T23:59:59.000Z

167

HYBRID SULFUR ELECTROLYZER DEVELOPMENT FY09 SECOND QUARTER REPORT  

DOE Green Energy (OSTI)

The primary objective of the DOE-NE Nuclear Hydrogen Initiative (NHI) is to develop the nuclear hydrogen production technologies necessary to produce hydrogen at a cost competitive with other alternative transportation fuels. The focus of the NHI is on thermochemical cycles and high temperature electrolysis that can be powered by heat from high temperature gas reactors. The Savannah River National Laboratory (SRNL) has been tasked with the primary responsibility to perform research and development in order to characterize, evaluate and develop the Hybrid Sulfur (HyS) thermochemical process. This report documents work during the first quarter of Fiscal Year 2009, for the period between January 1, 2009 and March 31, 2009. The HyS Process is a two-step hybrid thermochemical cycle that is part of the 'Sulfur Family' of cycles. As a sulfur cycle, it uses high temperature thermal decomposition of sulfuric acid to produce oxygen and to regenerate the sulfur dioxide reactant. The second step of the process uses a sulfur dioxide depolarized electrolyzer (SDE) to split water and produce hydrogen by electrochemically reacting sulfur dioxide with H{sub 2}O. The SDE produces sulfuric acid, which is then sent to the acid decomposer to complete the cycle. The DOE NHI program is developing the acid decomposer at Sandia National Laboratory for application to both the HyS Process and the Sulfur Iodine Cycle. The SDE is being developed at SRNL. During FY05 and FY06, SRNL designed and conducted proof-of-concept testing for a SDE using a low temperature, PEM fuel cell-type design concept. The advantages of this design concept include high electrochemical efficiency, small footprint and potential for low capital cost, characteristics that are crucial for successful implementation on a commercial scale. During FY07, SRNL extended the range of testing of the SDE to higher temperature and pressure, conducted a 100-hour longevity test with a 60-cm{sup 2} single cell electrolyzer, and designed and built a larger, multi-cell stack electrolyzer. During FY08, SRNL continued SDE development, including development and successful testing of a three-cell electrolyzer stack with a rated capacity of 100 liters per hour. The HyS program for FY09 program will address improving SDE performance by focusing on preventing or minimizing sulfur deposition inside the cell caused by SO{sub 2} crossover, reduction of cell voltage for improved efficiency, an extension of cell operating lifetime. During FY09 a baseline technology development program is being conducted to address each of these issues. Button-cell (2-cm{sup 2}) and single cell (60-cm{sup 2}) SDEs will be fabricated and tested. A pressurized button-cell test facility will be designed and constructed to facilitate addition testing. The single cell test facility will be upgraded for unattended operation, and later for operation at higher temperature and pressure. Work will continue on development of the Gas Diffusion Electrode (GDE), or Gap Cell, as an alternative electrolyzer design approach that is being developed under subcontract with industry partner Giner Electrochemical Systems. If successful, it could provide an alternative means of preventing sulfur crossover through the proton exchange membrane, as well as the possibility for higher current density operation based on more rapid mass transfer in a gas-phase anode. Promising cell components will be assembled into membrane electrode assemblies (MEAs) and tested in the single cell test facility. Upon modification for unattended operation, test will be conducted for 200 hours or more. Both the button-cell and modified single cell facility will be utilized to demonstrate electrolyzer operation without sulfur build-up limitations, which is a Level 1 Milestone.

Herman, D; David Hobbs, D; Hector Colon-Mercado, H; Timothy Steeper, T; John Steimke, J; Mark Elvington, M

2009-04-15T23:59:59.000Z

168

Process for removal of sulfur compounds from fuel gases  

DOE Patents (OSTI)

Fuel gases such as those produced in the gasification of coal are stripped of sulfur compounds and particulate matter by contact with molten metal salt. The fuel gas and salt are intimately mixed by passage through a venturi or other constriction in which the fuel gas entrains the molten salt as dispersed droplets to a gas-liquid separator. The separated molten salt is divided into a major and a minor flow portion with the minor flow portion passing on to a regenerator in which it is contacted with steam and carbon dioxide as strip gas to remove sulfur compounds. The strip gas is further processed to recover sulfur. The depleted, minor flow portion of salt is passed again into contact with the fuel gas for further sulfur removal from the gas. The sulfur depleted, fuel gas then flows through a solid absorbent for removal of salt droplets. The minor flow portion of the molten salt is then recombined with the major flow portion for feed to the venturi.

Moore, Raymond H. (Richland, WA); Stegen, Gary E. (Richland, WA)

1978-01-01T23:59:59.000Z

169

Why sequence Alkaliphilic sulfur oxidizing bacteria for sulfur pollution  

NLE Websites -- All DOE Office Websites (Extended Search)

Alkaliphilic sulfur oxidizing Alkaliphilic sulfur oxidizing bacteria for sulfur pollution remediation? Burning sulfur-containing fuels, such as coal, oil, and natural gas, contributes significantly to global environmental problems, such as air pollution and acid rain, besides contributing to the loss of the ozone layer. One method of managing sulfur compounds released as byproducts from industrial processes is to scrub them out using chemical treatments and activated charcoal beds. A lower-cost solution relies on incorporating alkaliphic sulfur-oxidizing bacteria into biofilters to convert the volatile and toxic compounds into insoluble sulfur for easier removal. Discovered in the last decade, these bacteria have been found to thrive in habitats that span the full pH range. The bacteria could have applications

170

Ion-mobility Spectrometry Based NOx Sensor - Nuclear Engineering Division  

NLE Websites -- All DOE Office Websites (Extended Search)

NPNS > Sensors and NPNS > Sensors and Instrumentation and NDE > Energy System Application > DOE Office of Transportation Technologies > Ion-mobility Spectrometry Based NOx Sensor Capabilities Sensors and Instrumentation and Nondestructive Evaluation Overview Energy System Applications Overview DOE Office of Fossil Energy DOE Office of Transportation Technologies Ion-mobility Spectrometry Based NOx Sensor DOE Office of Power Technology Work for Others Safety-Related Applications Homeland Security Applications Biomedical Applications Millimiter Wave Group Papers Other NPNS Capabilities Work with Argonne Contact us For Employees Site Map Help Join us on Facebook Follow us on Twitter NE on Flickr Sensors and Instrumentation and Nondestructive Evaluation Ion-mobility Spectrometry Based NOx Sensor

171

Modeling of NOx formation in circular laminar jet flames  

E-Print Network (OSTI)

Emissions of oxides of nitrogen (NOx) from combustion devices is a topic of tremendous current importance. The bulk of the review of NOx emissions has been in the field of turbulent jet flames. However laminar jet flames have provided much insight into the relative importance of NOx reaction pathways in non premixed combustion for various flame conditions. The existing models include detailed chemistry kinetics for various species involved in the flame. These detailed models involve very complex integration of hundreds of chemical reactions of various species and their intermediates. Hence such models are highly time consuming and also normally involve heavy computational costs. This work proposes a numerical model to compute the total production of NOx in a non-premixed isolated circular laminar jet flame. The jet consists of the fuel rich inner region and the O2 rich outer region. The model estimates both thermal NOx and prompt NOx assuming single step kinetics for NOx formation and a thin flame model. Further the amount of air entrainment by jet depends upon the Sc number of fuel. The higher the Sc number, the higher is the air entrained which lowers the flame temperature and hence NOx formation. With increasing Sc number, flame volume increases which leads to an increase in the NOx formation. The effect of the Sc number variation on the net production of NOx and flame structure is also investigated. The effect of equilibrium chemistry for CO2 CO + 1/2 O2 and H2O H2 +1/2 O2 on total NOx emission is studied. Also the effect of both CO2 and H2O equilibrium is considered simultaneously and the net x NO formation for propane is 45 ppm. The split between pre-flame and post-flame regions is also investigated. For Propane, 96% of NO emissions occur in the pre-flame region and about 4% in the post-flame region. The model predictions are compared with experimental values of NOx missions reported elsewhere.

Siwatch, Vivek

2005-12-01T23:59:59.000Z

172

Quantification of Variability and Uncertainty in Hourly NOx Emissions from Coal-Fired Power Plants  

E-Print Network (OSTI)

1 Quantification of Variability and Uncertainty in Hourly NOx Emissions from Coal-Fired Power to quantify variability and uncertainty for NOx emissions from coal-fired power plants. Data for hourly NOx Uncertainty, Variability, Emission Factors, Coal-Fired Power Plants, NOx emissions, Regression Models

Frey, H. Christopher

173

PERFORMANCE OF NOx CONTROL TECHNOLOGIES ON THREE CALIFORNIA WASTE-TO-ENERGY  

E-Print Network (OSTI)

catalytic reduction (SNCR) technology. There is a sub stantial volume of literature available discussing NOx in the first three undergrate zones on the SERRF units. Preliminary indications were that some NOx reduction) to quantify the effect of FGR's contribution to NOx reduction during simultaneous FGRIThermal DeNOx use; (b

Columbia University

174

Use of Simulation To Optimize NOx Abatement by Absorption and Selective Catalytic Reduction  

E-Print Network (OSTI)

Use of Simulation To Optimize NOx Abatement by Absorption and Selective Catalytic Reduction Andrew the effect of the ammonia feed ratio on the NOx reduction efficiency for the SCR model. Optimal NOx removal NOx in an inert gas slows its absorption in the absorber and its reduction in the SCR because

Liu, Y. A.

175

Ultra-low Sulfur Reduction Emission Control Device/Development of an On-board Fuel Sulfur Trap  

DOE Green Energy (OSTI)

Honeywell has completed working on a multiyear program to develop and demonstrate proof-of-concept for an 'on-vehicle' desulfurization fuel filter for both light duty and heavy-duty diesel engines. Integration of the filter into the vehicle fuel system will reduce the adverse effects sulfur has on post combustion emission control devices such as NOx adsorbers. The NOx adsorber may be required to meet the proposed new EPA Tier II and '2007-Rule' emission standards. The proposed filter concept is based on Honeywell's reactive filtration technology and experience in liquids handling and conditioning. A regeneration and recycling plan for the spent filters was also examined. We have chosen to develop and demonstrate this technology based on criteria set forth for a heavy duty CIDI engine system because it represents a more challenging set of conditions of service intervals and overall fuel usage over light duty systems. In the second phase of the program a light duty diesel engine test was also demonstrated. Further, technology developed under this proposal would also have application for the use of liquid based fuels for fuel cell power generation. The program consisted of four phases. Phase I focused on developing a concept design and analysis and resolution of technical barriers concerning removal of sulfur-containing species in low sulfur fuels. In Phase II concentrated on prototype filter design and preparation followed by qualification testing of this component in a fuel line application. Phase III studied life cycle and regeneration options for the spent filter. Phase IV focused on efficacy and benefits in the desulfation steps of a NOx adsorber on both a heavy and light duty engine. The project team included a number of partners, with Honeywell International as the prime contractor. The partners include an emission control technology developer (Honeywell International), a fuel technology developer (Marathon Ashland Petroleum), a catalyst technology developer (Johnson Matthey), a CIDI engine manufacturer (Navistar Inc. (formerly International Truck & Engine Corporation) and Mack Trucks Inc.), and filter recycler (American Wastes Industries).

Rohrbach, Ron; Barron, Ann

2008-07-31T23:59:59.000Z

176

NETL: Advanced NOx Emissions Control: Control Technology - ALTA...  

NLE Websites -- All DOE Office Websites (Extended Search)

of the burner design is to achieve homogeneity of the combustion products in the boiler. Not only does this create ideal conditions for combustion-related NOx control, it...

177

NETL: Advanced NOx Emissions Control: Control Technology - Carbon...  

NLE Websites -- All DOE Office Websites (Extended Search)

product. The FFR concept solves this problem. The technology increases the efficiency of NOx reduction in coal reburning and decreases carbon-in ash. FFR can achieve the same...

178

NETL: Advanced NOx Emissions Control: Control Technology - Dense...  

NLE Websites -- All DOE Office Websites (Extended Search)

air (ROFA(tm)) and ROTAMIX(tm) systems. Baseline NOx emission rates with the ROFA system ranged from 0.17 to 0.26 lbMMBtu. During DPRCS testing the micronized coal feed...

179

Lean Gasoline Engine Reductant Chemistry During Lean NOx Trap Regeneration  

Science Conference Proceedings (OSTI)

Lean NOx Trap (LNT) catalysts can effectively reduce NOx from lean engine exhaust. Significant research for LNTs in diesel engine applications has been performed and has led to commercialization of the technology. For lean gasoline engine applications, advanced direct injection engines have led to a renewed interest in the potential for lean gasoline vehicles and, thereby, a renewed demand for lean NOx control. To understand the gasoline-based reductant chemistry during regeneration, a BMW lean gasoline vehicle has been studied on a chassis dynamometer. Exhaust samples were collected and analyzed for key reductant species such as H2, CO, NH3, and hydrocarbons during transient drive cycles. The relation of the reductant species to LNT performance will be discussed. Furthermore, the challenges of NOx storage in the lean gasoline application are reviewed.

Choi, Jae-Soon [ORNL; Prikhodko, Vitaly Y [ORNL; Partridge Jr, William P [ORNL; Parks, II, James E [ORNL; Norman, Kevin M [ORNL; Huff, Shean P [ORNL; Chambon, Paul H [ORNL; Thomas, John F [ORNL

2010-01-01T23:59:59.000Z

180

Economics of pollution trading for SO{sub 2} and NOx  

Science Conference Proceedings (OSTI)

For years economists have urged policymakers to use market-based approaches such as cap-and-trade programs or emission taxes to control pollution. The sulphur dioxide (SO{sub 2}) allowance market created by Title IV of the 1990 US Clean Air Act Amendments represents the first real test of the wisdom of economists' advice. Subsequent urban and regional applications of NOx emission allowance trading took shape in the 1990s in the United States, culminating in a second large experiment in emission trading in the eastern United States that began in 2003. This paper provides an overview of the economic rationale for emission trading and a description of the major US programs for SO{sub 2} and nitrogen oxides. These programs are evaluated along measures of performance including cost savings, environmental integrity, and incentives for technological innovation. The authors offer lessons for the design of future programs including, most importantly, those reducing carbon dioxide. 128 refs., 1 fig., 1 tab.

Dallas Burtraw; David A. Evans; Alan Krupnick; Karen Palmer; Russell Toth

2005-03-15T23:59:59.000Z

Note: This page contains sample records for the topic "nox sulfur dioxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

NOx reduction aftertreatment system using nitrogen nonthermal plasma desorption  

Science Conference Proceedings (OSTI)

In the flue emission from an internal combustion system using diffusing combustion such as coal or oil fuel boiler, incinerator, or diesel engine, around 10% oxygen is usually included. It is difficult to reduce the NOx in the emission completely using catalysts or plasma alone because part of the NO is oxidized under an O{sub 2}-rich environment. In order to overcome these difficulties, we propose a new aftertreatment system of NOx included in the exhaust gas of the combustion system using nonthermal plasma (NTP) desorption and reduction. In this system, exchangeable adsorbent columns are equipped. As an initial step to realize such kind of aftertreatment system, the basic characteristics of the N{sub 2} NTP desorption and NOx reduction were examined experimentally using a pulse corona NTP reactor. After several adsorption/desorption processes, the amount of NOx adsorbed becomes equal to that of the NOx desorbed, that is, all the NO, was desorbed in a single desorption process. It is confirmed that the NOx complete reduction using N{sub 2} NTP desorption is possible not only for a simulated exhaust gas but for a real diesel engine gas. The effective specific energy density can be decreased down to 22 Wh/m{sup 3}.

Okubo, M.; Inoue, M.; Kuroki, T.; Yamamoto, T. [University of Osaka Prefecture, Osaka (Japan). Dept. of Mechanical Engineering

2005-08-01T23:59:59.000Z

182

Assessing historical global sulfur emission patterns for the period 1850--1990  

Science Conference Proceedings (OSTI)

Anthropogenic sulfur dioxide emissions from energy-producing and metal production activities have become an important factor in better understanding the relationship between humans and the environment. Concerns about (1) acid rain effects on the environment and (2) anthropogenic aerosols affecting possible global change have prompted interest in the transformation and fate of sulfur in the environment. One step in assessing the importance of sulfur emissions is the development of a reliable regional emission inventory of sulfur as a function of time. The objective of this research effort was to create a homogeneous database for historical sulfur emission estimates for the world. The time from 1850--1990 was selected to include the period of industrialization form the time the main production of fuels and minerals began until the most recent year for which complete production data exist. This research effort attempts to correct some of the deficiencies associated with previous global sulfur emission estimates by (1) identifying those production activities that resulted in sulfur emissions by country and (2) calculating historical emission trends by country across years. An important component of this study was the comparison of the sulfur emission results with those of previous studies.

Lefohn, A.S. [A.S.L. and Associates, Helena, MT (United States); Husar, J.D.; Husar, R.B. [Washington Univ., St. Louis, MO (United States). Center for Air Pollution Impact and Trend Analysis; Brimblecombe, P. [Univ. of East Anglia, Norwich (United Kingdom)

1996-07-19T23:59:59.000Z

183

Method for dissolving plutonium dioxide  

DOE Patents (OSTI)

A method for dissolving plutonium dioxide comprises adding silver ions to a nitric acid-hydrofluoric acid solution to significantly speed up dissolution of difficultly soluble plutonium dioxide.

Tallent, Othar K. (Oak Ridge, TN)

1976-01-01T23:59:59.000Z

184

It's Elemental - The Element Sulfur  

NLE Websites -- All DOE Office Websites (Extended Search)

Phosphorus Phosphorus Previous Element (Phosphorus) The Periodic Table of Elements Next Element (Chlorine) Chlorine The Element Sulfur [Click for Isotope Data] 16 S Sulfur 32.065 Atomic Number: 16 Atomic Weight: 32.065 Melting Point: 388.36 K (115.21°C or 239.38°F) Boiling Point: 717.75 K (444.60°C or 832.28°F) Density: 2.067 grams per cubic centimeter Phase at Room Temperature: Solid Element Classification: Non-metal Period Number: 3 Group Number: 16 Group Name: Chalcogen What's in a name? From the Sanskrit word sulvere and the Latin word sulphurium. Say what? Sulfur is pronounced as SUL-fer. History and Uses: Sulfur, the tenth most abundant element in the universe, has been known since ancient times. Sometime around 1777, Antoine Lavoisier convinced the rest of the scientific community that sulfur was an element. Sulfur is a

185

Why sequence purple sulfur bacteria?  

NLE Websites -- All DOE Office Websites (Extended Search)

purple sulfur bacteria? purple sulfur bacteria? The process by which plants and some bacteria can convert light energy to sugar, or photosynthesis, is crucial to global food webs, and complicated. Very little is known about the photosynthetic bacteria in the purple sulfur bacteria group, which may represent one of the most primitive photosynthetic organisms and are capable of carbon fixation and sequestration in both light and dark conditions with the help of sulfur compounds. Purple sulfur bacteria are autotrophic and can synthesize organic compounds from inorganic sources. Researchers hope to learn more by sequencing nine type strains of purple sulfur bacteria that are found in freshwater, brackish and marine systems. The information would lead to a better understanding of the process of photosynthesis as well as the global

186

Better Batteries from Waste Sulfur  

Science Conference Proceedings (OSTI)

Apr 28, 2013 ... Although there are some industrial uses for sulfur, the amount generated from refining fossil fuels far outstrips the current need for the element.

187

Aeroderivative Gas Turbines Can Meet Stringent NOx Control Requirements  

E-Print Network (OSTI)

Gas Turbines operating in the United States are required to meet federally mandated emission standards. This article will discuss how General Electric's LM industrial aeroderivative gas turbines are meeting NOx requirements as low as 25 parts per million using steam injection. The article will also describe the technical aspects of how water or steam injection can be used to supress NOx, what emission levels GE will guarantee and detail some recently obtained test results. The side benefits of water or steam injection for controlling NOx emissions will be discussed. Steam injection has a very favorable effect on engine performance raising both the power output and efficiency. As an example, full steam injection in the GE LM5000 gas turbine increases the power output from 34 MW to 52 MW while lowering the heat rate from 9,152 Btu/kWh to 7,684 Btu/kWh when fired on natural gas. Water injection increases power output at a slightly decreased thermal efficiency. When steam is injected, NOx can be controlled to 25 ppm (referenced to 15 percent O2) which is sufficient to comply with the most stringent requirements imposed in areas where water or steam injection is considered best available control technology (BACT). Selective Catalytic Reduction (SCR) systems are currently employed in areas with Lowest Achievable Emissions Requirements. SCRs have been proposed as BACT in several areas such as the Bay area of California and the state of New Jersey. These systems are expensive to install and operate, and this cost impact can cause many projects to become economically non-viable. Cost comparisons for NOx removal using an SCR in combination with the steam injection will demonstrate the large incremental cost incurred when NOx is controlled using an SCR. Lastly, a case will be made for not imposing SCR as BACT in that it would close the door on further research and development for better, cost-effective methods of NOx control.

Keller, S. C.; Studniarz, J. J.

1987-09-01T23:59:59.000Z

188

Spray-dryer scrubbers for high-sulfur coal combustion  

Science Conference Proceedings (OSTI)

Spray-dryer scrubbers for sulfur-dioxide removal from flue gases have been a developing technology for several years. Because spray-dryer scrubbers offer several potential advantages over wet scrubbing, they are attractive to the utility industry. Some of these advantages are: 1) a simpler waste-disposal problem, 2) higher energy efficiency, 3) lower water comsumption, 4) lower capital cost, 5) lower operating costs, 6) less exotic materials of construction, 7) simpler operation, and 8) ability to consume some plant waste water in the spray dryer. The paper provides a broad survey of the state of the art as it might be useful to electric utilitites using high-sulfur coal.

Henry, J.M.; Robards, R.F.; Wells, W.L.

1982-11-01T23:59:59.000Z

189

The Hybrid Sulfur Cycle for Nuclear Hydrogen Production  

DOE Green Energy (OSTI)

Two Sulfur-based cycles--the Sulfur-Iodine (SI) and the Hybrid Sulfur (HyS)--have emerged as the leading thermochemical water-splitting processes for producing hydrogen utilizing the heat from advanced nuclear reactors. Numerous international efforts have been underway for several years to develop the SI Cycle, but development of the HyS Cycle has lagged. The purpose of this paper is to discuss the background, current status, recent development results, and the future potential for this thermochemical process. Savannah River National Laboratory (SRNL) has been supported by the U.S. Department of Energy Office of Nuclear Energy, Science, and Technology since 2004 to evaluate and to conduct research and development for the HyS Cycle. Process design studies and flowsheet optimization have shown that an overall plant efficiency (based on nuclear heat converted to hydrogen product, higher heating value basis) of over 50% is possible with this cycle. Economic studies indicate that a nuclear hydrogen plant based on this process can be economically competitive, assuming that the key component, the sulfur dioxide-depolarized electrolyzer, can be successfully developed. SRNL has recently demonstrated the use of a proton-exchange-membrane electrochemical cell to perform this function, thus holding promise for economical and efficient hydrogen production.

Summers, William A.; Gorensek, Maximilian B.; Buckner, Melvin R.

2005-09-08T23:59:59.000Z

190

Process for removing sulfur from sulfur-containing gases  

DOE Patents (OSTI)

The present disclosure relates to improved processes for treating hot sulfur-containing flue gas to remove sulfur therefrom. Processes in accorda The government may own certain rights in the present invention pursuant to EPA Cooperative Agreement CR 81-1531.

Rochelle, Gary T. (Austin, TX); Jozewicz, Wojciech (Chapel Hill, NC)

1989-01-01T23:59:59.000Z

191

Volume efficient sodium sulfur battery  

SciTech Connect

In accordance with the teachings of this specification, a sodium sulfur battery is formed as follows. A plurality of box shaped sulfur electrodes are provided, the outer surfaces of which are defined by an electrolyte material. Each of the electrodes have length and width dimensions substantially greater than the thicknesses thereof as well as upwardly facing surface and a downwardly facing surface. An electrode structure is contained in each of the sulfur electrodes. A holding structure is provided for holding the plurality of sulfur electrodes in a stacked condition with the upwardly facing surface of one sulfur electrode in facing relationship to the downwardly facing surface of another sulfur electrode thereabove. A small thickness dimension separates each of the stacked electrodes thereby defining between each pair of sulfur electrodes a volume which receives the sodium reactant. A reservoir is provided for containing sodium. A manifold structure interconnects the volumes between the sulfur electrodes and the reservoir. A metering structure controls the flow of sodium between the reservoir and the manifold structure.

Mikkor, Mati (Ann Arbor, MI)

1980-01-01T23:59:59.000Z

192

Chemical Consequences of Heme Distortion and the Role of Heme Distortion in Signal Transduction of H-NOX Proteins  

E-Print Network (OSTI)

T. tengcongensis (Tt H-NOX), the reduction potential wasdesign of Tt H-NOX to broaden the reduction potential rangewith Tt H-NOX show that the reduction potential is

Olea, Jr., Charles

2010-01-01T23:59:59.000Z

193

CYCLIC CARBON DIOXIDE STIMULATION  

NLE Websites -- All DOE Office Websites (Extended Search)

CARBON DIOXIDE STIMULATION ("Huff-and-Puff') (A well-stimulation method) Cyclic CO 2 stimulation is a single-well operation that is developing as a method of rapidly producing oil....

194

SRD 134 Carbon Dioxide  

Science Conference Proceedings (OSTI)

> Return to SRD 134, Index of Semiconductor Process Gases. CARBON DIOXIDE. MW [1]. 44.010. NBP [1]. 194.75 K. TP [1]. 216.59 K. CO 2. Pc [1]. ...

2012-07-27T23:59:59.000Z

195

Why Sequence Bacteria That Reduce Sulfur Compounds?  

NLE Websites -- All DOE Office Websites (Extended Search)

Bacteria That Reduce Sulfur Compounds? Combustion of sulfur-containing fuels, such as coal, oil, and natural gas, contributes significantly to global environmental problems, such...

196

Electrochemical NOx Sensor for Monitoring Diesel Emissions  

Science Conference Proceedings (OSTI)

Increasingly stringent emissions regulations will require the development of advanced gas sensors for a variety of applications. For example, compact, inexpensive sensors are needed for detection of regulated pollutants, including hydrocarbons (HCs), CO, and NO{sub x}, in automotive exhaust. Of particular importance will be a sensor for NO{sub x} to ensure the proper operation of the catalyst system in the next generation of diesel (CIDI) automobiles. Because many emerging applications, particularly monitoring of automotive exhaust, involve operation in harsh, high-temperature environments, robust ceramic-oxide-based electrochemical sensors are a promising technology. Sensors using yttria-stabilized zirconia (YSZ) as an oxygen-ion-conducting electrolyte have been widely reported for both amperometric and potentiometric modes of operation. These include the well-known exhaust gas oxygen (EGO) sensor. More recently, ac impedance-based (i.e., impedance-metric) sensing techniques using YSZ have been reported for sensing water vapor, hydrocarbons, CO, and NO{sub x}. Typically small-amplitude alternating signal is applied, and the sensor response is measured at a specified frequency. Most impedance-metric techniques have used the modulus (or magnitude) at low frequencies ( 600 C, and thermodynamic calculations predict {approx}90% NO, balance NO{sub 2}. Since automotive exhaust sensors will probably be required to operate at temperatures > 600 C, NO is the dominant component in thermodynamic equilibrium and the target NOx species. Also, the use of upstream catalysts could further promote the conversion of NO{sub x} species to NO. Therefore, the focus of current work is to investigate the response to NO. Nevertheless, minimizing the sensitivity to a variety of competing species is important in order to obtain the accuracy necessary for achieving the emission limits. Mitigating the effect of interfering gases (e.g., O{sub 2}, water vapor, HCs, etc.) is an area of current study. For impedance metric NO{sub x} sensors, our previous work has demonstrated that the cross-sensitivity to O{sub 2} may be accounted for by comparing measurements at multiple frequencies. Other strategies for compensation are also being explored, including calibration using data from existing sensors located nearby. Our current work has made significant advances in terms of developing prototype sensors more suitable for commercialization. Also, dynamometer testing has provided real-world sensor performance data that will be useful in approaching potential suppliers to whom we can transfer the technology for commercialization. The advances are a direct result of understanding the sensing mechanisms responsible for impedance-based NO{sub x} sensing and the effect of materials choice and sensor design/geometry.

Woo, L Y; Glass, R S

2008-11-14T23:59:59.000Z

197

NETL: Advanced NOx Emissions Control: Control Technology - Optimized Fuel  

NLE Websites -- All DOE Office Websites (Extended Search)

Optimized Fuel Injector Design Optimized Fuel Injector Design This project includes fundamental research and engineering development of low NOx burners and reburning fuel injectors. The team of Reaction Engineering International (REI), the University of Utah, Brown University and DB Riley, Inc., will develop fundamental information on low NOx burners. The work has two phases. In the first phase, the University of Utah will examine two-phase mixing and near-field behavior of coal injectors using a 15-million Btu/hr bench-scale furnace, Brown University will examine char deactivation and effectiveness of reburning, and REI will develop a comprehensive burner model using the data produced by the University of Utah and Brown University. In the second phase, an optimized injector design will be tested at the 100-million Btu/hr Riley Coal Burner Test Facility. It is anticipated that this work will provide improved hardware designs and computer simulation models for reduced NOx emissions and minimized carbon loss.

198

Study of Lean NOx Technology for Diesel Emission Control  

DOE Green Energy (OSTI)

Diesel engines because of their reliability and efficiency are a popular mobile source. The diesel engine operates at higher compression ratios and with leaner fuel mixtures and produces lower carbon monoxide and hydrocarbon emissions. The oxygen-rich environment leads to higher nitrogen oxides in the form of NO. Catalysts selectively promoting the reduction of NOx by HCs in a lean environment have been termed lean NOx catalyst ''LNC''. The two groups that have shown most promise are, Copper exchanged zeolite Cu/ZSM5, and Platinum on alumina Pt/Al2O3.

Mital, R.

2000-08-20T23:59:59.000Z

199

NOx Solutions for Biodiesel: Final Report; Report 6 in a Series of 6  

DOE Green Energy (OSTI)

A number of studies have shown substantial particulate matter (PM) reductions for biodiesel, but also a significant increase in nitrogen oxides (NOx) emissions. This study examines a number of approaches for NOx reduction from biodiesel.

McCormick, R. L.; Alvarez, J. R.; Graboski, M. S.

2003-02-01T23:59:59.000Z

200

BEHAVIOR OF METALLIC INCLUSIONS IN URANIUM DIOXIDE  

E-Print Network (OSTI)

Metallic Inclusions in Uranium Dioxide", LBL-11117 (1980).in Hypostoichiornetric Uranium Dioxide 11 , LBL-11095 (OF METALLIC INCLUSIONS IN URANIUM DIOXIDE Rosa L. Yang and

Yang, Rosa L.

2013-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "nox sulfur dioxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Sulfur condensation in Claus catalyst  

SciTech Connect

The heterogeneous reactions in which catalyst deactivation by pore plugging occur are listed and include: coke formation in petroleum processing, especially hydrocracking and hydrodesulfurization catalysts; steam reforming and methnation catalysts; ammonia synthesis catalyst; and automobile exhause catalysts. The authors explain how the Claus process converts hydrogen sulfide produced by petroleum desulfurization units and gas treatment processes into elemental sulfur and water. More than 15 million tons of sulfur are recovered annually by this process. Commercial Claus plants appear to operate at thermodynamic equilibrium. Depending on the H2S content of the feed and the number of reactors, total H2S conversion to elemental sulfur can exceed 95%.

Schoffs, G.R.

1985-02-01T23:59:59.000Z

202

Influence of combustion parameters on NOx production in an industrial boiler  

E-Print Network (OSTI)

Influence of combustion parameters on NOx production in an industrial boiler M.A. Habib a,*, M; accepted 14 April 2007 Available online 24 June 2007 Abstract NOx formation during the combustion process occurs mainly through the oxidation of nitrogen in the combustion air (thermal NOx) and through oxidation

Aldajani, Mansour A.

203

EVALUATION OF OBSERVATION-BASED METHODS FOR ANALYZING OZONE PRODUCTION AND OZONE-NOX-VOC SENSITIVITY  

E-Print Network (OSTI)

summertime For example: Reduce NOx emissions More reduction of NOy deposition Less reduction of NOy export Less reduction of NOy burden The non-linearity indicates that anthropogenic NOx emission reductions/3 of BL O3 production change exists as change of direct O3 export to the FT 23% reduction of surface NOx

Sillman, Sanford

204

Applied Catalysis B: Environmental 37 (2002) 2735 NOx reduction by urea under lean conditions over  

E-Print Network (OSTI)

Applied Catalysis B: Environmental 37 (2002) 27­35 NOx reduction by urea under lean conditions over using a single step sol­gel process (designated as 2% Pt-SG) and tested its activity for NOx reduction and hydrothermally stable in the range of 150­500 C in the reduction of NOx by hy- drocarbons or oxygenated

Gulari, Erdogan

205

A Cost-Effectiveness Analysis of Alternative Ozone Control Strategies: Flexible Nitrogen Oxide (NOx) Abatement  

E-Print Network (OSTI)

hydrolysis of N2O5, and ultimately leads to the computed reduction in NOx levels. 4. Effects of the different in the source magnitude of LtNOx can lead to a substantial10 reduction in the computed lifetimes of these trace. This increase of O3 at higher altitudes is responsible for the reduction of surface NOx levels simulated at high

206

Hydrogen peroxide-producing NADH oxidase (nox-1) from Lactococcus lactis  

E-Print Network (OSTI)

to either water in a four-electron reduction (nox-2 enzymes) or to hydrogen peroxide in a two-electron reduction (nox-1 enzymes).3 Recently, we published the characterization of a novel water- forming NADH the reduction of oxygen to hydrogen peroxide with the help of NADH oxidase (nox-1) from Lactococ- cus lactis (L

Bommarius, Andreas

207

Measurements of NOX produced by rocket-triggered lightning M. Rahman,1  

E-Print Network (OSTI)

with reductions in NOx and VOC emissions are presented and analyzed in this study. Finally, a combination per- formed with the validated model. The first involves a reduction in NOx emissions of 50 emission reduction scenarios at 17:00 LT. (A) 50% NOx reduction emission scenario, (B) 50% VOC reduction

Slatton, Clint

208

NATURAL GAS REBURNING TECHNOLOGY FOR NOx REDUCTION FROM MSW COMBUSTION SYSTEMS  

E-Print Network (OSTI)

NATURAL GAS REBURNING TECHNOLOGY FOR NOx REDUCTION FROM MSW COMBUSTION SYSTEMS ABSTRACf CRAIG A series, injection of up to 15% (HHV basis) natural gas reduced NOx by 50-70% while maintain ing, Illinois DAVID G. LINZ Gas Research Institute Chicago, Illinois ducing NOx emISSIons from municipal solid

Columbia University

209

Microbial removal of nitrogen oxides from flue gas: The BioDeNOx-process  

E-Print Network (OSTI)

W) facilities. NOx levels below 60 ppm (7% O2) have been reliably achieved, which is a reduction of 70% below combustion controls to maximize NOx reduction and minimize ammonia slip. A simplified version of the process forward in the reduction of NOx emissions from EfW facilities. INTRODUCTION Emissions from U.S. Energy

Dekker, Cees

210

Assessment of NOx Reduction Potential from Combustion Modifications at Illinois Power -- Baldwin Unit 1  

Science Conference Proceedings (OSTI)

Cyclone boilers have recently become regulated with respect to NOx emissions due to the adoption of Title IV -- Group 2 NOx emission limits for cyclones of 0.86 lb/MBtu. This project explored the NOx reduction potential of cyclone biasing on a bituminous coal-fired cyclone boiler.

1998-06-24T23:59:59.000Z

211

Electrochemical NOx Sensor for Monitoring Diesel Emissions  

SciTech Connect

Increasingly stringent emissions regulations will require the development of advanced gas sensors for a variety of applications. For example, compact, inexpensive sensors are needed for detection of regulated pollutants, including hydrocarbons (HCs), CO, and NO{sub x}, in automotive exhaust. Of particular importance will be a sensor for NO{sub x} to ensure the proper operation of the catalyst system in the next generation of diesel (CIDI) automobiles. Because many emerging applications, particularly monitoring of automotive exhaust, involve operation in harsh, high-temperature environments, robust ceramic-oxide-based electrochemical sensors are a promising technology. Sensors using yttria-stabilized zirconia (YSZ) as an oxygen-ion-conducting electrolyte have been widely reported for both amperometric and potentiometric modes of operation. These include the well-known exhaust gas oxygen (EGO) sensor. More recently, ac impedance-based (i.e., impedance-metric) sensing techniques using YSZ have been reported for sensing water vapor, hydrocarbons, CO, and NO{sub x}. Typically small-amplitude alternating signal is applied, and the sensor response is measured at a specified frequency. Most impedance-metric techniques have used the modulus (or magnitude) at low frequencies (< 1 Hz) as the sensing signal and attribute the measured response to interfacial phenomena. Work by our group has also investigated using phase angle as the sensing signal at somewhat higher frequencies (10 Hz). The higher frequency measurements would potentially allow for reduced sampling times during sensor operation. Another potential advantage of impedance-metric NO{sub x} sensing is the similarity in response to NO and NO{sub 2} (i.e., total-NO{sub x} sensing). Potentiometric NO{sub x} sensors typically show higher sensitivity to NO2 than NO, and responses that are opposite in sign. However, NO is more stable than NO{sub 2} at temperatures > 600 C, and thermodynamic calculations predict {approx}90% NO, balance NO{sub 2}. Since automotive exhaust sensors will probably be required to operate at temperatures > 600 C, NO is the dominant component in thermodynamic equilibrium and the target NOx species. Also, the use of upstream catalysts could further promote the conversion of NO{sub x} species to NO. Therefore, the focus of current work is to investigate the response to NO. Nevertheless, minimizing the sensitivity to a variety of competing species is important in order to obtain the accuracy necessary for achieving the emission limits. Mitigating the effect of interfering gases (e.g., O{sub 2}, water vapor, HCs, etc.) is an area of current study. For impedance metric NO{sub x} sensors, our previous work has demonstrated that the cross-sensitivity to O{sub 2} may be accounted for by comparing measurements at multiple frequencies. Other strategies for compensation are also being explored, including calibration using data from existing sensors located nearby. Our current work has made significant advances in terms of developing prototype sensors more suitable for commercialization. Also, dynamometer testing has provided real-world sensor performance data that will be useful in approaching potential suppliers to whom we can transfer the technology for commercialization. The advances are a direct result of understanding the sensing mechanisms responsible for impedance-based NO{sub x} sensing and the effect of materials choice and sensor design/geometry.

Woo, L Y; Glass, R S

2008-11-14T23:59:59.000Z

212

Waste Coal Fines Reburn for NOx and Mercury Emission Reduction  

SciTech Connect

Injection of coal-water slurries (CWS) made with both waste coal and bituminous coal was tested for enhanced reduction of NO{sub x} and Hg emissions at the AES Beaver Valley plant near Monaca, PA. Under this project, Breen Energy Solutions (BES) conducted field experiments on the these emission reduction technologies by mixing coal fines and/or pulverized coal, urea and water to form slurry, then injecting the slurry in the upper furnace region of a coal-fired boiler. The main focus of this project was use of waste coal fines as the carbon source; however, testing was also conducted using pulverized coal in conjunction with or instead of waste coal fines for conversion efficiency and economic comparisons. The host site for this research and development project was Unit No.2 at AES Beaver Valley cogeneration station. Unit No.2 is a 35 MW Babcock & Wilcox (B&W) front-wall fired boiler that burns eastern bituminous coal. It has low NO{sub x} burners, overfire air ports and a urea-based selective non-catalytic reduction (SNCR) system for NO{sub x} control. The back-end clean-up system includes a rotating mechanical ash particulate removal and electrostatic precipitator (ESP) and wet flue gas desulfurization (FGD) scrubber. Coal slurry injection was expected to help reduce NOx emissions in two ways: (1) Via fuel-lean reburning when the slurry is injected above the combustion zone. (2) Via enhanced SNCR reduction when urea is incorporated into the slurry. The mercury control process under research uses carbon/water slurry injection to produce reactive carbon in-situ in the upper furnace, promoting the oxidation of elemental mercury in flue gas from coal-fired power boilers. By controlling the water content of the slurry below the stoichiometric requirement for complete gasification, water activated carbon (WAC) can be generated in-situ in the upper furnace. As little as 1-2% coal/water slurry (heat input basis) can be injected and generate sufficient WAC for mercury capture. During July, August, and September 2007, BES designed, procured, installed, and tested the slurry injection system at Beaver Valley. Slurry production was performed by Penn State University using equipment that was moved from campus to the Beaver Valley site. Waste coal fines were procured from Headwaters Inc. and transported to the site in Super Sacks. In addition, bituminous coal was pulverized at Penn State and trucked to the site in 55-gallon drums. This system was operated for three weeks during August and September 2007. NO{sub x} emission data were obtained using the plant CEM system. Hg measurements were taken using EPA Method 30B (Sorbent Trap method) both downstream of the electrostatic precipitator and in the stack. Ohio Lumex Company was on site to provide rapid Hg analysis on the sorbent traps during the tests. Key results from these tests are: (1) Coal Fines reburn alone reduced NO{sub x} emissions by 0-10% with up to 4% heat input from the CWS. However, the NO{sub x} reduction was accompanied by higher CO emissions. The higher CO limited our ability to try higher reburn rates for further NO{sub x} reduction. (2) Coal Fines reburn with Urea (Carbon enhanced SNCR) decreased NO{sub x} emissions by an additional 30% compared to Urea injection only. (3) Coal slurry injection did not change Hg capture across the ESP at full load with an inlet temperature of 400-430 F. The Hg capture in the ESP averaged 40%, with or without slurry injection; low mercury particulate capture is normally expected across a higher temperature ESP because any oxidized mercury is thought to desorb from the particulate at ESP temperatures above 250 F. (4) Coal slurry injection with halogen salts added to the mixing tank increased the Hg capture in the ESP to 60%. This significant incremental mercury reduction is important to improved mercury capture with hot-side ESP operation and wherever hindrance from sulfur oxides limit mercury reduction, because the higher temperature is above sulfur oxide dew point interference.

Stephen Johnson; Chetan Chothani; Bernard Breen

2008-04-30T23:59:59.000Z

213

NETL: Advanced NOx Emissions Control: Control Technology - ALTA for Cyclone  

NLE Websites -- All DOE Office Websites (Extended Search)

Full-Scale Demonstration of ALTA NOx Control for Cyclone-Fired Boilers Full-Scale Demonstration of ALTA NOx Control for Cyclone-Fired Boilers The primary goal of this project was to evaluate a technology called advanced layered technology application (ALTA) as a means to achieve NOx emissions below 0.15 lb/MMBtu in a cyclone boiler. Reaction Engineering International (REI) conducted field testing and combustion modeling to refine the process design, define the optimum technology parameters, and assess system performance. The ALTA NOx control technology combines deep staging from overfire air, rich reagent injection (RRI), and selective non-catalytic reduction (SNCR). Field testing was conducted during May-June 2005 at AmerenUE's Sioux Station Unit 1, a 500 MW cyclone boiler unit that typically burns an 80/20 blend of Powder River Basin subbituminous coal and Illinois No. 6 bituminous coal. Parametric testing was also conducted with 60/40 and 0/100 blends. The testing also evaluated process impacts on balance-of-plant issues such as the amount of unburned carbon in the ash, slag tapping, waterwall corrosion, ammonia slip, and heat distribution.

214

NOx, SOx & CO{sub 2} mitigation using blended coals  

Science Conference Proceedings (OSTI)

Estimates of potential CO{sub 2} reduction achievable through the use of a mixture of bituminous and subbituminous (PRB) coals, whilst attaining NOx and SOx compliance are presented. The optimization considerations to provide satisfactory furnace, boiler and unit performance with blended coal supplies to make such operation feasible are discussed. 6 refs., 7 figs., 1 tab.

Labbe, D.

2009-11-15T23:59:59.000Z

215

The Chemistry of the Thermal DeNOx Process: A Review of the Technology's Possible Application to control of NOx from Diesel Engines  

DOE Green Energy (OSTI)

This paper presents a review of the Thermal DeNOx process with respect to its application to control of NOx emissions from diesel engines. The chemistry of the process is discussed first in empirical and then theoretical terms. Based on this discussion the possibilities of applying the process to controlling NOx emissions from diesel engines is considered. Two options are examined, modifying the requirements of the chemistry of the Thermal DeNOx process to suit the conditions provided by diesel engines and modifying the engines to provide the conditions required by the process chemistry. While the former examination did not reveal any promising opportunities, the latter did. Turbocharged diesel engine systems in which the turbocharger is a net producer of power seem capable of providing the conditions necessary for NOx reduction via the Thermal DeNOx reaction.

Lyon, Richard

2001-08-05T23:59:59.000Z

216

NOX REDUCTION FOR LEAN EXHAUST USING PLASMA ASSISTED CATALYSIS  

DOE Green Energy (OSTI)

Currently CARB estimates on road diesel vehicles contribute 50% of the NOX and 78% of the particulates being discharged from mobile sources. Diesel emissions obviously must be reduced if future air quality targets are to be met. A critical technological barrier exists because there are no commercial technologies available, which can reduce NOX from diesel (lean), exhaust containing 5-15% O2 concentration. One promising approach to reducing NOX and particulates from diesel exhaust is to use a combination of plasma with catalyst. Plasma can be generated thermally or non-thermally. Thermal plasma is formed by heating the system to an exceedingly high temperature (>2000 C). High temperature requirements for plasma makes thermal plasma inefficient and requires skillful thermal management and hence is considered impractical for mobile applications. Non-thermal plasma directs electrical energy into the creation of free electrons, which in turn react with gaseous species thus creating plasma. A combination of non-thermal plasma with catalysts can be referred to Plasma Assisted Catalysts or PAC. PAC technology has been demonstrated in stationary sources where non-thermal plasma catalysis is carried out in presence of NH3 as a reductant. In stationary applications NO is oxidized to HNO3 and then into ammonium nitrate where it is condensed and removed. This approach is impractical for mobile application because of the ammonia requirement and the ultimate mechanism by which NOX is removed. However, if a suitable catalyst can be found which can use onboard fuel as reductant then the technology holds a considerable promise. NOX REDUCTION FOR LEAN EXHAUST USING PLASMA ASSISTED CATALYSIS Ralph Slone, B. Bhatt and Victor Puchkarev NOXTECH INC. In addition to the development of an effective catalyst, a non-thermal plasma reactor needs be scaled and demonstrated along with a reliable and cost effective plasma power source and onboard HC source needs to be proven. Under the work sponsored by DOE and SCAQMD Noxtech is developing a cost effective and reliable PAC system for mobile applications. The goal of the program is to develop a suitable catalyst with the ability to remove high levels of NOx at reasonable space velocities. This new catalyst will then be used to scale the technology to treat exhaust from 80Hp engine and eventually to demonstrate the technology on 200 and 400 Hp engine applications. Using the 2004 EPA proposed regulation as a standard, it is clear in order for PAC system to be commercially viable it needs to remove NOX by 70% or better. It is further assumed from past experience that 30,000 HR-1 space velocities are necessary to ensure a good compact design.

Bhatt, B.

2000-08-20T23:59:59.000Z

217

Alkali metal/sulfur battery  

SciTech Connect

Alkali metal/sulfur batteries in which the electrolyte-separator is a relatively fragile membrane are improved by providing means for separating the molten sulfur/sulfide catholyte from contact with the membrane prior to cooling the cell to temperatures at which the catholyte will solidify. If the catholyte is permitted to solidify while in contact with the membrane, the latter may be damaged. The improvement permits such batteries to be prefilled with catholyte and shipped, at ordinary temperatures.

Anand, Joginder N. (Clayton, CA)

1978-01-01T23:59:59.000Z

218

Depleted Uranium (DU) Dioxide Fill  

NLE Websites -- All DOE Office Websites (Extended Search)

Fill Depleted Uranium (DU) Dioxide Fill DU dioxide in the form of sand may be used to fill the void spaces in the waste package after the package is loaded with SNF. This...

219

METHOD OF SINTERING URANIUM DIOXIDE  

DOE Green Energy (OSTI)

This patent relates to a method of sintering uranium dioxide. Uranium dioxide bodies are heated to above 1200 nif- C in hydrogen, sintered in steam, and then cooled in hydrogen. (AEC)

Henderson, C.M.; Stavrolakis, J.A.

1963-04-30T23:59:59.000Z

220

Available Technologies: Acceleration of Carbon Dioxide ...  

APPLICATIONS OF TECHNOLOGY: Carbon dioxide capture and sequestration; ADVANTAGES: Accelerated capture of carbon dioxide; Effective at extremely dilute (nanomolar ...

Note: This page contains sample records for the topic "nox sulfur dioxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Observations of the atmospheric sulfur cycle on SAGA 3  

SciTech Connect

During the Soviet/American Gases and Aerosols (SAGA) 3 program in February and March 1991 the authors measured a wide variety of sulfur compounds simultaneously in the equatorial Pacific marine boundary layer. They made measurements of atmospheric dimethyl sulfide (DMS), sulfur dioxide (SO{sub 2}), and size-resolved aerosol non-sea-salt sulfate (NSS), and methane sulfonate (MSA). Some of the observed ratios contradict commonly held views of the marine sulfur cycle: the large DMS/NSS ratio implies that NSS may not be the primary product of DMS oxidation under some conditions. The authors also found much more DMS than SO{sub 2}, which may suggest that SO{sub 2} is not always an intermediate in DMS oxidation. The small SO{sub 2}/NSS ratio also supports the idea that most NSS was not formed from SO{sub 2}. Although the measured ratios of MSA/NSS were similar to previous observations in this region, much of the MSA was contained on supermicron particles, in contrast to both the NSS and the earlier MSA observations at higher latitudes. This implies that MSA/NSS ratios in ice cores may not accurately reflect the MSA/NSS ratios in their source areas. 51 refs., 4 figs., 3 tabs.

Huebert, B.J.; Howell, S.; Laj, P. [Univ. of Rhode Island, Narragansett, RI (United States); Johnson, J.E.; Bates, T.S.; Quinn, P.K. [NOAA/Pacific Marine Environmental Lab., Seattle, WA (United States); Yegorov, V. [State Committee for Hydrometeorology, Moscow (Russian Federation); Clarke, A.D.; Porter, J.N. [Univ. of Hawaii, Honolulu, HI (United States)

1993-09-20T23:59:59.000Z

222

Hydrogen and Sulfur Production from Hydrogen Sulfide Wastes  

E-Print Network (OSTI)

A new hydrogen sulfide waste-treatment process that uses microwave plasma-chemical technology is currently under development in the Soviet Union and in the United States. Whereas the present waste treatment process only recovers sulfur at best, this novel process recovers both hydrogen and sulfur. The plasma process involves dissociating hydrogen sulfide in a "nonequilibrium" plasma in a microwave or radio-frequency reactor. After the dissociation process, sulfur is condensed and sold just as is currently done. The remaining gases are purified and separated into streams containing the product hydrogen, the hydrogen sulfide to be recycled to the plasma reactor, and the process purge containing carbon dioxide and water. This process has particular implications for petroleum refining industry, in which hydrogen is a widely used reagent and must be produced from increasingly scarce hydrocarbon resources. The modular nature of the new process may also offer economic advantages over small-scale waste treatment technologies widely used in the natural-gas industry. Laboratory-scale experiments with pure hydrogen sulfide indicate that conversions exceeding 90% are possible with appropriate reactor design and that the energy required to dissociate hydrogen sulfide is low enough for the plasma process to be economically competitive. In addition, the experiments show-that typical refinery acid-gas streams are compatible with the plasma process and that all by-products can be treated with existing technology.

Harkness, J.; Doctor, R. D.

1993-03-01T23:59:59.000Z

223

Hydrogen and sulfur production from hydrogen sulfide wastes  

DOE Green Energy (OSTI)

A new hydrogen sulfide waste-treatment process that uses microwave plasma-chemical technology is currently under development in the Soviet Union and in the United States. Whereas the present waste treatment process only recovers sulfur at best, this novel process recovers both hydrogen and sulfur. The plasma process involves dissociating hydrogen sulfide in a nonequilibrium'' plasma in a microwave or radio-frequency reactor. After the dissociation process, sulfur is condensed and sold just as is currently done. The remaining gases are purified and separated into streams containing the product hydrogen, the hydrogen sulfide to be recycled to the plasma reactor, and the process purge containing carbon dioxide and water. This process has particular implications for the petroleum refining industry, in which hydrogen is a widely used reagent and must be produced from increasingly scarce hydrocarbon resources. The modular nature of the new process may also offer economic advantages over small-scale waste treatment technologies widely used in the natural-gas industry. Laboratory-scale experiments with pure hydrogen sulfide indicate that conversions exceeding 90% are possible with appropriate reactor design and that the energy required to dissociate hydrogen sulfide is low enough for the plasma process to be economically competitive. In addition, the experiments show that typical refinery acid-gas streams are compatible with the plasma process and that all by-products can be treated with existing technology.

Harkness, J.B.L.; Doctor, R.D.

1993-01-01T23:59:59.000Z

224

Hydrogen and sulfur production from hydrogen sulfide wastes  

DOE Green Energy (OSTI)

A new hydrogen sulfide waste-treatment process that uses microwave plasma-chemical technology is currently under development in the Soviet Union and in the United States. Whereas the present waste treatment process only recovers sulfur at best, this novel process recovers both hydrogen and sulfur. The plasma process involves dissociating hydrogen sulfide in a ``nonequilibrium`` plasma in a microwave or radio-frequency reactor. After the dissociation process, sulfur is condensed and sold just as is currently done. The remaining gases are purified and separated into streams containing the product hydrogen, the hydrogen sulfide to be recycled to the plasma reactor, and the process purge containing carbon dioxide and water. This process has particular implications for the petroleum refining industry, in which hydrogen is a widely used reagent and must be produced from increasingly scarce hydrocarbon resources. The modular nature of the new process may also offer economic advantages over small-scale waste treatment technologies widely used in the natural-gas industry. Laboratory-scale experiments with pure hydrogen sulfide indicate that conversions exceeding 90% are possible with appropriate reactor design and that the energy required to dissociate hydrogen sulfide is low enough for the plasma process to be economically competitive. In addition, the experiments show that typical refinery acid-gas streams are compatible with the plasma process and that all by-products can be treated with existing technology.

Harkness, J.B.L.; Doctor, R.D.

1993-03-01T23:59:59.000Z

225

Modeling The NOx Emissions In A Low NOx Burner While Fired With Pulverized Coal And Dairy Biomass Blends  

E-Print Network (OSTI)

New regulations like the Clean Air Interstate Rule (CAIR) will pose greater challenges for Coal fired power plants with regards to pollution reduction. These new regulations plan to impose stricter limits on NOX reduction. The current regulations by themselves already require cleanup technology; newer regulations will require development of new and economical technologies. Using a blend of traditional fuels & biomass is a promising technology to reduce NOX emissions. Experiments conducted previously at the Coal and Biomass energy lab at Texas A&M reported that dairy biomass can be an effective Reburn fuel with NOX reduction of up to 95%; however little work has been done to model such a process with Feedlot Biomass as a blend with the main burner fuel. The present work concerns with development of a zero dimensional for a low NOx burner (LNB) model in order to predict NOX emissions while firing a blend of Coal and dairy biomass. Two models were developed. Model I assumes that the main burner fuel is completely oxidized to CO,CO2,H20 and fuel bound nitrogen is released as HCN, NH3, N2; these partially burnt product mixes with tertiary air, undergoes chemical reactions specified by kinetics and burns to complete combustion. Model II assumes that the main burner solid fuel along with primary and secondary air mixes gradually with recirculated gases, burn partially and the products from the main burner include partially burnt solid particles and fuel bound nitrogen partially converted to N2, HCN and NH3. These products mix gradually with tertiary air, undergo further oxidation-reduction reactions in order to complete the combustion. The results are based on model I. Results from the model were compared with experimental findings to validate it. Results from the model recommend the following conditions for optimal reduction of NOx: Equivalence Ratio should be above 0.95; mixing time should be below 100ms. Based on Model I, results indicate that increasing percentage of dairy biomass in the blend increases the NOx formation due to the assumption that fuel N compounds ( HCN, NH3) do not undergo oxidation in the main burner zone. Thus it is suggested that model II must be adopted in the future work.

Uggini, Hari

2012-05-01T23:59:59.000Z

226

Design and operation of the coke-oven gas sulfur removal facility at Geneva Steel  

Science Conference Proceedings (OSTI)

The coke-oven gas sulfur removal facility at Geneva Steel utilizes a combination of two technologies which had never been used together. These two technologies had proven effective separately and now in combination. However, it brought unique operational considerations which has never been considered previously. The front end of the facility is a Sulfiban process. This monoethanolamine (MEA) process effectively absorbs hydrogen sulfide and other acid gases from coke-oven gas. The final step in sulfur removal uses a Lo-Cat II. The Lo-Cat process absorbs and subsequently oxidizes H{sub 2}S to elemental sulfur. These two processes have been effective in reducing sulfur dioxide emissions from coke-oven gas by 95%. Since the end of the start-up and optimization phase, emission rate has stayed below the 104.5 lb/hr limit of equivalent SO{sub 2} (based on a 24-hr average). In Jan. 1995, the emission rate from the sulfur removal facility averaged 86.7 lb/hr with less than 20 lb/hr from the Econobator exhaust. The challenges yet to be met are decreasing the operating expenses of the sulfur removal facility, notably chemical costs, and minimizing the impact of the heating system on unit reliability.

Havili, M.U.; Fraser-Smyth, L.L.; Wood, B.W. [Geneva Steel, Provo, UT (United States)

1996-02-01T23:59:59.000Z

227

NOx versus VOC limitation of O3 production in the Po valley: Local and integrated view based  

E-Print Network (OSTI)

- 14 #12;emissions and for NOx and VOC emissions reduced by 35%. Before 1300 a NOx reduction is seen north of downtown Milan, the NOx and VOC reduction curves cross. Before this time, O3 is VOC- sensitive reduction) is greater than zero, a VOC emissions reduction is more effective than a NOx emissions reduction

228

Modeling NOx emissions from coal-fired utility boilers using support vector regression with ant colony optimization  

Science Conference Proceedings (OSTI)

Modeling NO"x emissions from coal fired utility boiler is critical to develop a predictive emissions monitoring system (PEMS) and to implement combustion optimization software package for low NO"x combustion. This paper presents an efficient NO"x emissions ... Keywords: Ant colony optimization, Artificial neural networks, Combustion modeling, NOx emissions modeling, Support vector regression

Hao Zhou; Jia Pei Zhao; Li Gang Zheng; Chun Lin Wang; Ke Fa Cen

2012-02-01T23:59:59.000Z

229

The carbon dioxide dilemma  

SciTech Connect

The effect of burning fossil fuels on the global climate is discussed. It may be that as we produce carbon dioxide by burning fossil fuels, we create a greenhouse effect which causes temperatures on earth to rise. Implications of changes in global temperatures are discussed.

Edelson, E.

1982-02-01T23:59:59.000Z

230

Carbon dioxide sensor  

SciTech Connect

The present invention generally relates to carbon dioxide (CO.sub.2) sensors. In one embodiment, the present invention relates to a carbon dioxide (CO.sub.2) sensor that incorporates lithium phosphate (Li.sub.3PO.sub.4) as an electrolyte and sensing electrode comprising a combination of lithium carbonate (Li.sub.2CO.sub.3) and barium carbonate (BaCO.sub.3). In another embodiment, the present invention relates to a carbon dioxide (CO.sub.2) sensor has a reduced sensitivity to humidity due to a sensing electrode with a layered structure of lithium carbonate and barium carbonate. In still another embodiment, the present invention relates to a method of producing carbon dioxide (CO.sub.2) sensors having lithium phosphate (Li.sub.3PO.sub.4) as an electrolyte and sensing electrode comprising a combination of lithium carbonate (Li.sub.2CO.sub.3) and barium carbonate (BaCO.sub.3).

Dutta, Prabir K. (Worthington, OH); Lee, Inhee (Columbus, OH); Akbar, Sheikh A. (Hilliard, OH)

2011-11-15T23:59:59.000Z

231

Cost-effective sulfur control strategies for the Great Plains gasification project  

SciTech Connect

The Great Plains gasification plant in Beulah, North Dakota, uses 14 Lurgi gasifiers to produce 152x10/sup 6/ scf/d (4.1x10/sup 6/ Nm/sup 3//d) of pipeline-quality gas from lignite. Since start-up in mid-1984, the plant has provided a serious challenge to the reliable operation of the Stretford sulfur recovery system. To address this challenge, over forty options for mitigating sulfur emissions were evaluated on an economic and technical basis, beginning at the emissions source (the stack) and working back through the plant. Although this study was directed toward providing a timely solution to the sulfur dioxide emissions problem, the status and opportunities for a number of emerging technologies were brought into focus. This evaluation is detailed here by the authors.

Doctor, R.D.; Wilzbach, K.E. (Argonne National Lab., IL (USA). Energy and Environmental Systems Div.)

1989-09-01T23:59:59.000Z

232

Development of Ni-based Sulfur Resistant Catalyst for Diesel Reforming  

DOE Green Energy (OSTI)

In order for diesel fuel to be used in a solid oxide fuel cell auxiliary power unit, the diesel fuel must be reformed into hydrogen, carbon monoxide and carbon dioxide. One of the major problems facing catalytic reforming is that the level of sulfur found in low sulfur diesel can poison most catalysts. This report shows that a proprietary low cost Ni-based reforming catalyst can be used to reform a 7 and 50 ppm sulfur containing diesel fuel for over 500 hours of operation. Coking, which appears to be route of catalyst deactivation due to metal stripping, can be controlled by catalyst modifications, introduction of turbulence, and/or by application of an electromagnetic field with a frequency from {approx}50 kHz to 13.56 MHz with field strength greater than about 100 V/cm and more preferably greater about 500 V/cm.

Gunther Dieckmann

2006-06-30T23:59:59.000Z

233

JV Task 117 - Impact of Lignite Properties on Powerspan's NOx Oxidation System  

Science Conference Proceedings (OSTI)

Powerspan's multipollutant control process called electrocatalytic oxidation (ECO) technology is designed to simultaneously remove SO{sub 2}, NO{sub x}, PM{sub 2.5}, acid gases (such as hydrogen fluoride [HF], hydrochloric acid [HCl], and sulfur trioxide [SO{sub 3}]), Hg, and other metals from the flue gas of coal-fired power plants. The core of this technology is a dielectric barrier discharge reactor composed of cylindrical quartz electrodes residing in metal tubes. Electrical discharge through the flue gas, passing between the electrode and the tube, produces reactive O and OH radicals. The O and OH radicals react with flue gas components to oxidize NO to NO{sub 2} and HNO{sub 3} and a small portion of the SO{sub 2} to SO{sub 3} and H{sub 2}SO{sub 4}. The oxidized compounds are subsequently removed in a downstream scrubber and wet electrostatic precipitator. A challenging characteristic of selected North Dakota lignites is their high sodium content. During high-sodium lignite combustion and gas cooling, the sodium vaporizes and condenses to produce sodium- and sulfur-rich aerosols. Based on past work, it was hypothesized that the sodium aerosols would deposit on and react with the silica electrodes and react with the silica electrodes, resulting in the formation of sodium silicate. The deposit and reacted surface layer would then electrically alter the electrode, thus impacting its dielectric properties and NO{sub x} conversion capability. The purpose of this project was to determine the impact of lignite-derived flue gas containing sodium aerosols on Powerspan's dielectric barrier discharge (DBD) reactor with specific focus on the interaction with the quartz electrodes. Partners in the project were Minnkota Power Cooperative; Basin Electric Power Cooperative; Montana Dakota Utilities Co.; Minnesota Power; the North Dakota Industrial Commission, the Lignite Energy Council, and the Lignite Research Council; the Energy & Environmental Research Center (EERC); and the U.S. Department of Energy. An electrocatalytic oxidation (ECO) reactor slipstream system was designed by Powerspan and the EERC. The slipstream system was installed by the EERC at Minnkota Power Cooperative's Milton R. Young Station Unit 1 downstream of the electrostatic precipitator where the flue gas temperature ranged from 300 to 350 F. The system was commissioned on July 3, 2007, operated for 107 days, and then winterized upon completion of the testing campaign. Operational performance of the system was monitored, and data were archived for postprocessing. A pair of electrodes were extracted and replaced on a biweekly basis. Each pair of electrodes was shipped to Powerspan to determine NO conversion efficiency in Powerspan's laboratory reactor. Tested electrodes were then shipped to the EERC for scanning electron microscopy (SEM) and x-ray microanalysis. Measurement of NO{sub x} conversion online in operating the slipstream system was not possible because the nitric and sulfuric acid production by the DBD reactor results in conditioning corrosion challenges in the sample extraction system and NO measurement technologies. The operational observations, performance results, and lab testing showed that the system was adversely affected by accumulation of the aerosol materials on the electrode. NO{sub x} conversion by ash-covered electrodes was significantly reduced; however, with electrodes that were rinsed with water, the NOx conversion efficiency recovered to nearly that of a new electrode. In addition, the visual appearance of the electrode after washing did not show evidence of a cloudy reacted surface but appeared similar to an unexposed electrode. Examination of the electrodes using SEM x-ray microanalysis showed significant elemental sodium, sulfur, calcium, potassium, and silica in the ash coating the electrodes. There was no evidence of the reaction of the sodium with the silica electrodes to produce sodium silicate layers. All SEM images showed a clearly marked boundary between the ash and the silica. Sodium and sulfur are the main culprits in the

Scott Tolbert; Steven Benson

2008-02-29T23:59:59.000Z

234

JV Task 117 - Impact of Lignite Properties on Powerspan's NOx Oxidation System  

SciTech Connect

Powerspan's multipollutant control process called electrocatalytic oxidation (ECO) technology is designed to simultaneously remove SO{sub 2}, NO{sub x}, PM{sub 2.5}, acid gases (such as hydrogen fluoride [HF], hydrochloric acid [HCl], and sulfur trioxide [SO{sub 3}]), Hg, and other metals from the flue gas of coal-fired power plants. The core of this technology is a dielectric barrier discharge reactor composed of cylindrical quartz electrodes residing in metal tubes. Electrical discharge through the flue gas, passing between the electrode and the tube, produces reactive O and OH radicals. The O and OH radicals react with flue gas components to oxidize NO to NO{sub 2} and HNO{sub 3} and a small portion of the SO{sub 2} to SO{sub 3} and H{sub 2}SO{sub 4}. The oxidized compounds are subsequently removed in a downstream scrubber and wet electrostatic precipitator. A challenging characteristic of selected North Dakota lignites is their high sodium content. During high-sodium lignite combustion and gas cooling, the sodium vaporizes and condenses to produce sodium- and sulfur-rich aerosols. Based on past work, it was hypothesized that the sodium aerosols would deposit on and react with the silica electrodes and react with the silica electrodes, resulting in the formation of sodium silicate. The deposit and reacted surface layer would then electrically alter the electrode, thus impacting its dielectric properties and NO{sub x} conversion capability. The purpose of this project was to determine the impact of lignite-derived flue gas containing sodium aerosols on Powerspan's dielectric barrier discharge (DBD) reactor with specific focus on the interaction with the quartz electrodes. Partners in the project were Minnkota Power Cooperative; Basin Electric Power Cooperative; Montana Dakota Utilities Co.; Minnesota Power; the North Dakota Industrial Commission, the Lignite Energy Council, and the Lignite Research Council; the Energy & Environmental Research Center (EERC); and the U.S. Department of Energy. An electrocatalytic oxidation (ECO) reactor slipstream system was designed by Powerspan and the EERC. The slipstream system was installed by the EERC at Minnkota Power Cooperative's Milton R. Young Station Unit 1 downstream of the electrostatic precipitator where the flue gas temperature ranged from 300 to 350 F. The system was commissioned on July 3, 2007, operated for 107 days, and then winterized upon completion of the testing campaign. Operational performance of the system was monitored, and data were archived for postprocessing. A pair of electrodes were extracted and replaced on a biweekly basis. Each pair of electrodes was shipped to Powerspan to determine NO conversion efficiency in Powerspan's laboratory reactor. Tested electrodes were then shipped to the EERC for scanning electron microscopy (SEM) and x-ray microanalysis. Measurement of NO{sub x} conversion online in operating the slipstream system was not possible because the nitric and sulfuric acid production by the DBD reactor results in conditioning corrosion challenges in the sample extraction system and NO measurement technologies. The operational observations, performance results, and lab testing showed that the system was adversely affected by accumulation of the aerosol materials on the electrode. NO{sub x} conversion by ash-covered electrodes was significantly reduced; however, with electrodes that were rinsed with water, the NOx conversion efficiency recovered to nearly that of a new electrode. In addition, the visual appearance of the electrode after washing did not show evidence of a cloudy reacted surface but appeared similar to an unexposed electrode. Examination of the electrodes using SEM x-ray microanalysis showed significant elemental sodium, sulfur, calcium, potassium, and silica in the ash coating the electrodes. There was no evidence of the reaction of the sodium with the silica electrodes to produce sodium silicate layers. All SEM images showed a clearly marked boundary between the ash and the silica. Sodium and sulfur are the main culprits in the

Scott Tolbert; Steven Benson

2008-02-29T23:59:59.000Z

235

NETL: Carbon Dioxide 101 FAQs  

NLE Websites -- All DOE Office Websites (Extended Search)

is carbon dioxide? is carbon dioxide? CO2 Dipole Carbon Dioxide Carbon dioxide (chemical name CO2) is a clear gas composed of one atom of carbon (C) and two atoms of oxygen (O). Carbon dioxide is one of many chemical forms of carbon on the Earth. It does not burn, and in standard temperature and pressure conditions it is stable, inert, and non-toxic. Carbon dioxide occurs naturally in small amounts (about 0.04%) in the Earth's atmosphere. The volume of CO2 in the atmosphere is equivalent to one individual in a crowd of 2,500. Carbon dioxide is produced naturally by processes deep within the Earth. This CO2 can be released at the surface by volcanoes or might be trapped in natural underground geologic CO2 deposits, similar to underground deposits of oil and natural gas. As a major greenhouse gas, CO2 helps create and

236

LOW NOx EMISSIONS IN A FUEL FLEXIBLE GAS TURBINE  

SciTech Connect

In alignment with Vision 21 goals, a study is presented here on the technical and economic potential for developing a gas turbine combustor that is capable of generating less that 2 ppm NOx emissions, firing on either coal synthesis gas or natural gas, and being implemented on new and existing systems. The proposed solution involves controlling the quantity of H2 contained in the fuel. The presence of H2 leads to increased flame stability such that the combustor can be operated at lower temperatures and produce less thermal NOx. Coal gas composition would be modified using a water gas shift converter, and natural gas units would implement a catalytic partial oxidation (CPOX) reactor to convert part of the natural gas feed to a syngas before fed back into the combustor. While both systems demonstrated technical merit, the economics involved in implementing such a system are marginal at best. Therefore, Praxair has decided not to pursue the technology any further at this time.

Raymond Drnevich; James Meagher; Vasilis Papavassiliou; Troy Raybold; Peter Stuttaford; Leonard Switzer; Lee Rosen

2004-08-01T23:59:59.000Z

237

DYNAMOMETER EVALUATION OF PLASMA-CATALYST FOR DIESEL NOX REDUCTION  

DOE Green Energy (OSTI)

A three-stage plasma-catalyst system was developed and tested on an engine dynamometer. Previous laboratory testing suggested high NOx efficiency could be obtained. With hexene reductant added to the exhaust, over 90% NOx reduction was observed. However, with diesel or Fischer-Tropsch reductant the catalyst efficiency rapidly dropped off. Heating the catalyst in air removed brown deposit from the surface and restored conversion efficiency. Following the engine tests, the used catalysts were evaluated. BET surface area decreased, and TPD revealed significant storage. This storage appears to be partly unburned diesel fuel that can be removed by heating to around 250-300 C, and partly hydrocarbons bonded to the surface that remain in place until 450-500 C. Laboratory testing with propene reductant demonstrated that the catalyst regains efficiency slowly even when operating temperature does not exceed 300 C. This suggests that control strategies may be able to regenerate the catalyst by occasional moderate heating.

Hoard, J; Schmieg, S; Brooks, D; Peden, C; Barlow, S; Tonkyn, R

2003-08-24T23:59:59.000Z

238

Measuring Sulphur Dioxide (SO2) Emissions in October, 2010 Catastrophic Eruption from Merapi Volcano in Java, Indonesia  

E-Print Network (OSTI)

Volcano in Java, Indonesia with Ozone Monitoring Instrument (OMI) José A. Morales-Collazo Geology This paper discusses sulfur dioxide (SO2) cloud emissions from Merapi Volcano in Java, Indonesia during, Indonesia. In October 26th , 2010, a catastrophic eruption was reported from Merapi causing nearly 386

Gilbes, Fernando

239

Carbon Dioxide Capture Technology for the Coal-Powered Electricity Industry: A Systematic Prioritization of Research Needs  

E-Print Network (OSTI)

Balbach, J. H. (1991). "Modeling the removal of sulfur dioxide and nitrogen oxides from flue gases using% by volume (Chang et al. 1992b). Such observation is important for combustors that operate with flue gases and ultraviolet radiation. The composition, tem- perature, and pressure of the treated gas streams simulate gases

240

Demonstration of a NOx Control System for Stationary Diesel Engines  

Science Conference Proceedings (OSTI)

California has over 26,000 stationary diesel engines, mostly in emergency power and direct drive applications. In the past few years, various incentive programs in the state have resulted in the change-out of older, dirtier engines for newer, cleaner models or replacement with electric motors. Emissions reductions can be accomplished by equipping existing engines with controls for nitrogen oxides (NOx) and particulate matter (PM). The retrofit systems currently available, however, either are not cost com...

2005-06-30T23:59:59.000Z

Note: This page contains sample records for the topic "nox sulfur dioxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Coal Blending for NOx Reductions and Performance Improvements  

Science Conference Proceedings (OSTI)

Following its formation and initial meeting in 1995, the Alabama Fuels Development Consortium (AFDC) identified its highest priority as mitigating the adverse effects of burning low-volatile Alabama coals. These adverse effects included increased NOx emissions and flame instability. A pilot-scale AFDC study in 1995 and larger-scale projects conducted in partnership with EPRI in 1996 (Shoal Creek/Mina Pribbenow Blend Firing Demonstration) and 1997 (Shoal Creek/Mina Pribbenow Blend Milling Demonstration) m...

2004-09-20T23:59:59.000Z

242

CARBON DIOXIDE FIXATION.  

DOE Green Energy (OSTI)

Solar carbon dioxide fixation offers the possibility of a renewable source of chemicals and fuels in the future. Its realization rests on future advances in the efficiency of solar energy collection and development of suitable catalysts for CO{sub 2} conversion. Recent achievements in the efficiency of solar energy conversion and in catalysis suggest that this approach holds a great deal of promise for contributing to future needs for fuels and chemicals.

FUJITA,E.

2000-01-12T23:59:59.000Z

243

Ultra-Low Sulfur Diesel Fuel | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Ultra-Low Sulfur Diesel Fuel Ultra-Low Sulfur Diesel Fuel August 20, 2013 - 8:53am Addthis Ultra-low sulfur diesel (ULSD) is diesel fuel with 15 parts per million or lower sulfur...

244

Energy Basics: Ultra-Low Sulfur Diesel Fuel  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Hydrogen Natural Gas Propane Ultra-Low Sulfur Diesel Vehicles Ultra-Low Sulfur Diesel Fuel Ultra-low sulfur diesel (ULSD) is diesel fuel with 15 parts per million or lower sulfur...

245

Ultra-Low Sulfur Diesel Fuel  

Energy.gov (U.S. Department of Energy (DOE))

Ultra-low sulfur diesel (ULSD) is diesel fuel with 15 parts per million or lower sulfur content. The U.S. Environmental Protection Agency requires 80% of the highway diesel fuel refined in or...

246

Continuous Emission Monitoring (CEM) System Application and Maintenance Guide  

Science Conference Proceedings (OSTI)

Large quantities of gases and particulate matter are emitted daily from industrial plants and fossil-fueled steam generating facilities. The gases include sulfur dioxide (SO2), the nitrogen oxides (NOx), and carbon dioxide (CO2). All of these gases affect the environment in some manner. Sulfur dioxide and the nitrogen oxides are precursors to acid rain. High levels of nitrogen oxides lead to the generation of photochemical smog, while carbon dioxide is implicated in climate change (global warming).

2003-12-31T23:59:59.000Z

247

Characteristics of Desulfation Behavior for Pre-Sulfated Pt-BaO/CeO2 Lean NOx Trap Catalysts: The Role of the CeO2 Support  

SciTech Connect

The desulfation of pre-sulfated Pt-BaO/CeO2 lean NOx trap catalysts was investigated by H2 TPRX (temperature programmed reaction), in-situ TR-XRD (time-resolved X-ray diffraction) and in-situ S K-edge XANES (X-ray absorption near edge spectroscopy) techniques. Compared with Pt-BaO/Al2O3 materials, the reductive treatment in H2 for a CeO2 supported sample up to 1073 K hardly removes any sulfur species. However, the results of in-situ TR-XRD measurements demonstrate that the quantity of a BaS phase formed on Pt-BaO/CeO2 is much smaller than that on Pt-BaO/Al2O3, implying that the formation of BaS crystallites, which occurs during the reduction from sulfate (SO42-) to sulfide (S2-), is significantly suppressed in the CeO2-supported catalyst. As the desulfation temperature increases under reducing conditions (in H2), the in-situ S XANES spectra show that, compared with alumina-supported samples, the reduction temperature for sulfates (S6+) decreases by about 150 K. Concomitantly, the formation of sulfur species with lower oxidation states (S2- - S4+) is enhanced. The step jump of S XANES spectra before and after desulfation are very similar, implying that the amount of sulfur-containing species removed during the reductive treatment is negligible, in agreement with the results of H2 TPRX. These results suggest that H2S produced by the reduction of BaSO4 is readily re-adsorbed on the ceria support to form ceria-sulfur complexes (e.g. CeS2). The high affinity of ceria for H2S, combined with the ease of reducibility of the ceria support gives rise to various oxidation states of sulfur after high temperature H2 treatments. Thus, the results of this study clearly show that the ceria support strongly affects the overall desulfation mechanism. The intrinsic role of the ceria support during desulfation, and its effect on the overall NOx storage processes are discussed on the basis of the characterization results obtained here.

Kim, Do Heui; Kwak, Ja Hun; Szanyi, Janos; Wang, Xianqin; Li, Guosheng; Hanson, Jonathan C.; Peden, Charles HF

2009-12-17T23:59:59.000Z

248

Characteristics of Desulfation Behavior for Presulfated Pt-BaO/CeO2 Lean NOx Trap Catalyst: The Role of the CeO2 Support  

SciTech Connect

The desulfation of presulfated Pt-BaO/CeO{sub 2} lean NOx trap catalyst was investigated by H{sub 2} TPRX (temperature programmed reaction), in situ TR-XRD (time-resolved X-ray diffraction), and in situ S K-edge XANES (X-ray absorption near edge spectroscopy) techniques. Compared with Pt-BaO/Al{sub 2}O{sub 3} materials, a reductive treatment in H{sub 2} for the CeO{sub 2}-supported sample up to 1073 K removes, at most, only a very small amount of sulfur species. However, the results of in situ TR-XRD measurements demonstrate that the quantity of a BaS phase formed on Pt-BaO/CeO{sub 2} is much smaller than that on Pt-BaO/Al{sub 2}O{sub 3}, implying that the formation of BaS crystallites, which occurs during the reduction from sulfate (SO{sub 4}{sup 2-}) to sulfide (S{sup 2-}), is significantly suppressed in the CeO{sub 2}-supported catalyst. As the desulfation temperature increases under reducing conditions (in H{sub 2}), in situ S XANES spectra show that, compared with alumina-supported samples, the reduction temperature for sulfates (S{sup 6+}) decreases by about 150 K. Concomitantly, the formation of sulfur species with lower oxidation states (S{sup 2}-S{sup 4+}) is enhanced. The absolute intensities of S XANES spectra before and after desulfation are very similar, implying that the amount of sulfur-containing species removed during the reductive treatment is negligible, in agreement with the results of H{sub 2} TPRX. These results suggest that H{sub 2}S produced by the reduction of BaSO{sub 4} is readily readsorbed on the ceria support to form ceria-sulfur complexes (e.g., Ce{sub 2}O{sub 2}S). The high affinity of ceria for H{sub 2}S, combined with the ease of reducibility of the ceria support material gives rise to various oxidation states of sulfur after high-temperature H{sub 2} treatments. Thus, the results of this study clearly show that the ceria support strongly affects the overall desulfation mechanism. The intrinsic role of the ceria support during desulfation and its effect on the overall NOx storage processes are discussed on the basis of the characterization results obtained here.

Kim, D.; Kwak, J; Szanyi, J; Wang, X; Li, G; Hanson, J; Peden, C

2009-01-01T23:59:59.000Z

249

Ultra Low NOx Catalytic Combustion for IGCC Power Plants  

DOE Green Energy (OSTI)

In order to meet DOE's goals of developing low-emissions coal-based power systems, PCI has further developed and adapted it's Rich-Catalytic Lean-burn (RCL{reg_sign}) catalytic reactor to a combustion system operating on syngas as a fuel. The technology offers ultra-low emissions without the cost of exhaust after-treatment, with high efficiency (avoidance of after-treatment losses and reduced diluent requirements), and with catalytically stabilized combustion which extends the lower Btu limit for syngas operation. Tests were performed in PCI's sub-scale high-pressure (10 atm) test rig, using a two-stage (catalytic then gas-phase) combustion process for syngas fuel. In this process, the first stage consists of a fuel-rich mixture reacting on a catalyst with final and excess combustion air used to cool the catalyst. The second stage is a gas-phase combustor, where the air used for cooling the catalyst mixes with the catalytic reactor effluent to provide for final gas-phase burnout and dilution to fuel-lean combustion products. During testing, operating with a simulated Tampa Electric's Polk Power Station syngas, the NOx emissions program goal of less than 0.03 lbs/MMBtu (6 ppm at 15% O{sub 2}) was met. NOx emissions were generally near 0.01 lbs/MMBtu (2 ppm at 15% O{sub 2}) (PCI's target) over a range on engine firing temperatures. In addition, low emissions were shown for alternative fuels including high hydrogen content refinery fuel gas and low BTU content Blast Furnace Gas (BFG). For the refinery fuel gas increased resistance to combustor flashback was achieved through preferential consumption of hydrogen in the catalytic bed. In the case of BFG, stable combustion for fuels as low as 88 BTU/ft{sup 3} was established and maintained without the need for using co-firing. This was achieved based on the upstream catalytic reaction delivering a hotter (and thus more reactive) product to the flame zone. The PCI catalytic reactor was also shown to be active in ammonia reduction in fuel allowing potential reductions in the burner NOx production. These reductions of NOx emissions and expanded alternative fuel capability make the rich catalytic combustor uniquely situated to provide reductions in capital costs through elimination of requirements for SCR, operating costs through reduction in need for NOx abating dilution, SCR operating costs, and need for co-firing fuels allowing use of lower value but more available fuels, and efficiency of an engine through reduction in dilution flows.

Shahrokh Etemad; Benjamin Baird; Sandeep Alavandi; William Pfefferle

2008-03-31T23:59:59.000Z

250

Abatement of Air Pollution: Control of Carbon Dioxide Emissions...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Carbon Dioxide EmissionsCarbon Dioxide Budget Trading Program (Connecticut) Abatement of Air Pollution: Control of Carbon Dioxide EmissionsCarbon Dioxide Budget Trading Program...

251

NOx Control Options and Integration for US Coal Fired Boilers  

DOE Green Energy (OSTI)

This is the Final Report for DOE Cooperative Agreement No: DE-FC26-00NT40753. The goal of the project was to develop cost-effective analysis tools and techniques for demonstrating and evaluating low-NOx control strategies and their possible impact on boiler performance for boilers firing US coals. The Electric Power Research Institute (EPRI) provided co-funding for this program. This project included research on: (1) In furnace NOx control; (2) Impacts of combustion modifications on boiler operation; (3) Selective Catalytic Reduction (SCR) catalyst testing and (4) Ammonia adsorption/removal on fly ash. Important accomplishments were achieved in all aspects of the project. Rich Reagent Injection (RRI), an in-furnace NOx reduction strategy based on injecting urea or anhydrous ammonia into fuel rich regions in the lower furnace, was evaluated for cyclone-barrel and PC fired utility boilers. Field tests successfully demonstrated the ability of the RRI process to significantly reduce NOx emissions from a staged cyclone-fired furnace operating with overfire air. The field tests also verified the accuracy of the Computational Fluid Dynamic (CFD) modeling used to develop the RRI design and highlighted the importance of using CFD modeling to properly locate and configure the reagent injectors within the furnace. Low NOx firing conditions can adversely impact boiler operation due to increased waterwall wastage (corrosion) and increased soot production. A corrosion monitoring system that uses electrochemical noise (ECN) corrosion probes to monitor, on a real-time basis, high temperature corrosion events within the boiler was evaluated. Field tests were successfully conducted at two plants. The Ohio Coal Development Office provided financial assistance to perform the field tests. To investigate soot behavior, an advanced model to predict soot production and destruction was implemented into an existing reacting CFD modeling tool. Comparisons between experimental data collected in a pilot scale furnace and soot behavior predicted by the CFD model showed good agreement. Field and laboratory tests were performed for SCR catalysts used for coal and biomass co-firing applications. Fundamental laboratory studies were performed to better understand mechanisms involved with catalyst deactivation. Field tests with a slip stream reactor were used to create catalyst exposed to boiler flue gas for firing coal and for co-firing coal and biomass. The field data suggests the mechanisms leading to catalyst deactivation are, in order of importance, channel plugging, surface fouling, pore plugging and poisoning. Investigations were performed to better understand the mechanisms involved with catalyst regeneration through mechanical or chemical methods. A computer model was developed to predict NOx reduction across the catalyst in a SCR. Experiments were performed to investigate the fundamentals of ammonia/fly ash interactions with relevance to the operation of advanced NOx control technologies such as selective catalytic reduction. Measurements were performed for ammonia adsorption isotherms on commercial fly ash samples subjected to a variety of treatments and on the chemistry of dry and semi-dry ammonia removal processes. This work resulted in the first fundamental ammonia isotherms on carbon-containing fly ash samples. This work confirms industrial reports that aqueous solution chemistry takes place upon the introduction of even very small amounts of water, while the ash remains in a semi-dry state.

Mike Bockelie; Marc Cremer; Kevin Davis; Martin Denison; Adel Sarofim; Connie Senior; Hong-Shig Shim; Dave Swenson; Bob Hurt; Eric Suuberg; Eric Eddings; Kevin Whitty; Larry Baxter; Calvin Bartholomew; William Hecker

2006-06-30T23:59:59.000Z

252

Additives for NOx emissions control from fixed sources. Final report, Aug 88-Feb 89  

SciTech Connect

This project tested several additives and catalysts as potential additive/catalyst combinations for a new NOx abatement process. The goal was to identify an effective, economical NOx emissions control process for application to post combustion, exhaust gas streams from jet engine test cells (JETC) and incinerators. The most useful results from this project are that: (1) an additive was identified that achieved gas-phase removal, with no catalyst, of NOx at temperatures as low as 350 deg C, and (2) good NOx removals can be achieved with additive: NOx ratios less than one. These results offer good possibilities for new low-temperature (350 to 500 deg C) gas phase NOx reduction processes of the selective noncatalytic reduction (SNR) type for both JETCs and incinerators.

Ham, D.O.; Moniz, G.; Gouveia, M.

1989-12-01T23:59:59.000Z

253

Two stage sorption of sulfur compounds  

DOE Patents (OSTI)

A two stage method for reducing the sulfur content of exhaust gases is disclosed. Alkali- or alkaline-earth-based sorbent is totally or partially vaporized 10 and introduced into a sulfur-containing gas stream. The activated sorbent can be introduced in the reaction zone or the exhaust gases of a combustor or a gasifier. High efficiencies of sulfur removal can be achieved.

Moore, W.E.

1991-12-31T23:59:59.000Z

254

Two stage sorption of sulfur compounds  

DOE Patents (OSTI)

A two stage method for reducing the sulfur content of exhaust gases is disclosed. Alkali- or alkaline-earth-based sorbent is totally or partially vaporized and introduced into a sulfur-containing gas stream. The activated sorbent can be introduced in the reaction zone or the exhaust gases of a combustor or a gasifier. High efficiencies of sulfur removal can be achieved.

Moore, William E. (Manassas, VA)

1992-01-01T23:59:59.000Z

255

Seal for sodium sulfur battery  

SciTech Connect

This invention is directed to a seal for a sodium sulfur battery in which the sealing is accomplished by a radial compression seal made on a ceramic component of the battery which separates an anode compartment from a cathode compartment of the battery.

Topouzian, Armenag (Birmingham, MI); Minck, Robert W. (Lathrup Village, MI); Williams, William J. (Northville, MI)

1980-01-01T23:59:59.000Z

256

EPRI 2002 Workshop on Combustion-Based NOx Controls for Coal-Fired Boilers  

Science Conference Proceedings (OSTI)

The Workshop on Combustion-Based NOx Controls for Coal-Fired Boilers, formerly the Workshop on NOx Controls for Utility Boilers, was the sixth in a series sponsored by EPRI and offered attendees a comprehensive picture of recent developments and full-scale applications of control technologies for nitrogen oxides (NOx). The workshop took place on October 24-25, 2002, in Atlanta, Georgia.

2003-01-14T23:59:59.000Z

257

TransForum v8n2 - DeNOX Catalyst License  

NLE Websites -- All DOE Office Websites (Extended Search)

Integrated Fuel Technologies Gets Worldwide License for Argonne-developed Diesel DeNOX Catalyst Argonne chemist Chris Marshall (front) displays a container of the catalyst while...

258

Desulfurization Effects on a Light-Duty Diesel Vehicle NOx Adsorber Exhaust Emission Control System  

DOE Green Energy (OSTI)

Analyzes the effects on gaseous emissions, before and after desulfurization, on a light-duty diesel vehicle with a NOx adsorber catalyst.

Tatur, M.; Tomazic, D.; Tyrer, H.; Thornton, M.; Kubsh, J.

2006-05-01T23:59:59.000Z

259

NETL: PPII - Integration of Low-NOx Burners with an Optimization...  

NLE Websites -- All DOE Office Websites (Extended Search)

Integration of Low-NOx Burners with an Optimization Plan for Boiler Combustion - Project Brief PDF-72KB Sunflower Electric Power Corp., Garden City, Finney County, KS PROJECT...

260

Impact of Lubricant Formulation on the Performance of NOx Adsorber Catalysts (Presentation)  

DOE Green Energy (OSTI)

Discusses the impact of lubricant formulation on the performance of oxides of nitrogen (NOx) Adsorber Catalysts, including background/motivation for study, experimental design, and results.

Whitacre, S. D.

2005-08-25T23:59:59.000Z

Note: This page contains sample records for the topic "nox sulfur dioxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Using hydroponic biomass to regulate NOx emissions in long range space travel  

E-Print Network (OSTI)

Using Hydroponic Biomass to Regulate NOx Emissions in Longprepared from hydroponic biomass prohibits high surface areapotato stalk are inedible biomass that can be continuously

2002-01-01T23:59:59.000Z

262

EA-1472: Commercial Demonstration fo the Low Nox Burner/Separated...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

472: Commercial Demonstration fo the Low Nox BurnerSeparated Over-Fire Air (LNBSOFA) Integration System Emission Reduction Technology, Holcolm Station, Sunflower Electric Power...

263

Reduce NOx and Improve Energy Efficiency, Software Tools for Industry, Industrial Technologies Program (ITP) (Fact Sheet)  

SciTech Connect

This fact sheet describes how the Industrial Technologies Program NOx and Energy Assessment Tool (NxEAT) can help petroleum refining and chemical plants improve energy efficiency.

2008-12-01T23:59:59.000Z

264

NETL: Carbon Dioxide 101 FAQs  

NLE Websites -- All DOE Office Websites (Extended Search)

the process through which carbon is cycled through the air, ground, plants, animals, and fossil fuels. People and animals inhale oxygen from the air and exhale carbon dioxide...

265

Sonochemical reduction of carbon dioxide.  

E-Print Network (OSTI)

??Emissions from the combustion of fossil fuels and cement production are responsible for approximately 75% of the increase of carbon dioxide (CO2) concentration in the… (more)

Koblov, Alexander

2011-01-01T23:59:59.000Z

266

Process for reducing sulfur in coal char  

DOE Patents (OSTI)

Coal is gasified in the presence of a small but effective amount of alkaline earth oxide, hydroxide or carbonate to yield a char fraction depleted in sulfur. Gases produced during the reaction are enriched in sulfur compounds and the alkaline earth compound remains in the char fraction as an alkaline earth oxide. The char is suitable for fuel use, as in a power plant, and during combustion of the char the alkaline earth oxide reacts with at least a portion of the sulfur oxides produced from the residual sulfur contained in the char to further lower the sulfur content of the combustion gases.

Gasior, Stanley J. (Pittsburgh, PA); Forney, Albert J. (Coraopolis, PA); Haynes, William P. (Pittsburgh, PA); Kenny, Richard F. (Venetia, PA)

1976-07-20T23:59:59.000Z

267

New Model to Predict Formation Damage due to Sulfur Deposition in Sour M.A. Mahmoud and A.A. Al-Majed, KFUPM, all SPE  

E-Print Network (OSTI)

. Kennedy, H. T. and Wieland, D. R. 1960. Equilibrium in the Methane/Carbon Dioxide/Hydrogen Sulfide (pressure and temperature). Accurate correlations were used to calculate the gas compressibility factor (Z-Awadhy et al. (1998) conducted a core flow experiment to study the sulfur deposition in carbonate oil

Al-Majed, Abdulaziz Abdullah

268

Lean NOx Trap Modeling in Vehicle Systems Simulations  

DOE Green Energy (OSTI)

A one-dimensional model for simulating lean NOx trap (LNT) performance is developed and validated using both steady state cycling data and transient data from FTP testing cycles. The model consists of the conservation equations for chemical species and energy in the bulk flow, energy of the solid walls, O2 storage and NOx storage (in the form of nitrites and nitrates). Nitrites and nitrates are formed by diffusion of NO and NO2, respectively, into sorbent particles (assumed to be hemi-spherical in shape) along with O2 and their formation rates are controlled by chemical kinetics as well as solid-phase diffusion rates of NOx species. The model also accounts for thermal aging and sulfation of LNTs. Empirical correlations are developed on the basis of published experimental data to capture these effects. These empirical correlations depend on total mileage for which the LNT has been in use, the mileage accumulated since the last desulfation event in addition to the freshly degreened catalyst characteristics. The model has been used in studies of vehicle systems (integration, performance etc.) including hybrid powertrain configurations. Since the engines in hybrid vehicles turn on and off multiple number of times during single drive cycles, the exhaust systems may encounter multiple cold start transients. Accurate modeling of catalyst warm-up and cooling is, therefore, very important to simulate LNT performance in such vehicles. For this purpose, the convective heat loss from the LNT to the ambient is modeled using a Nusselt number correlation that includes effects of both forced convection and natural convection (with later being important when vehicle is stationary). Using the model, the fuel penalty associated with operating LNTs on small diesel engine powered car during FTP drive cycles is estimated.

Gao, Zhiming [ORNL; Chakravarthy, Veerathu K [ORNL; Daw, C Stuart [ORNL; Conklin, Jim [ORNL

2010-09-01T23:59:59.000Z

269

Three-Dimensional Composite Nanostructures for Lean NOx Emission Control  

SciTech Connect

This final report to the Department of Energy (DOE) and National Energy Technology Laboratory (NETL) for DE-EE0000210 covers the period from October 1, 2009 to July 31, 2013. Under this project, DOE awarded UConn about $1,248,242 to conduct the research and development on a new class of 3D composite nanostructure based catalysts for lean NOx emission control. Much of the material presented here has already been submitted to DOE/NETL in quarterly technical reports. In this project, through a scalable solution process, we have successfully fabricated a new class of catalytic reactors, i.e., the composite nanostructure array (nano-array) based catalytic converters. These nanocatalysts, distinct from traditional powder washcoat based catalytic converters, directly integrate monolithic substrates together with nanostructures with well-defined size and shape during the scalable hydrothermal process. The new monolithic nanocatalysts are demonstrated to be able to save raw materials including Pt-group metals and support metal oxides by an order of magnitude, while perform well at various oxidation (e.g., CO oxidation and NO oxidation) and reduction reactions (H{sub 2} reduction of NOx) involved in the lean NOx emissions. The size, shape and arrangement of the composite nanostructures within the monolithic substrates are found to be the key in enabling the drastically reduced materials usage while maintaining the good catalytic reactivity in the enabled devices. The further understanding of the reaction kinetics associated with the unique mass transport and surface chemistry behind is needed for further optimizing the design and fabrication of good nanostructure array based catalytic converters. On the other hand, the high temperature stability, hydrothermal aging stability, as well as S-poisoning resistance have been investigated in this project on the nanocatalysts, which revealed promising results toward good chemical and mechanical robustness, as well as S-poisoning resistance. Further investigation is needed for unraveling the understanding, design and selection principles of this new class of nanostructure based monolithic catalysts.

Gao, Pu-Xian

2013-07-31T23:59:59.000Z

270

NOx CONTROL OPTIONS AND INTEGRATION FOR US COAL FIRED BOILERS  

SciTech Connect

This is the fifth Quarterly Technical Report for DOE Cooperative Agreement No: DE-FC26-00NT40753. The goal of the project is to develop cost effective analysis tools and techniques for demonstrating and evaluating low NOx control strategies and their possible impact on boiler performance for firing US coals. The Electric Power Research Institute (EPRI) is providing cofunding for this program. This program contains multiple tasks and good progress is being made on all fronts. Field tests for NOx reduction in a cyclone fired utility boiler due to using Rich Reagent Injection (RRI) have been started. CFD modeling studies have been started to evaluate the use of RRI for NOx reduction in a corner fired utility boiler using pulverized coal. Field tests of a corrosion monitor to measure waterwall wastage in a utility boiler have been completed. Computational studies to evaluate a soot model within a boiler simulation program are continuing. Research to evaluate SCR catalyst performance has started. A literature survey was completed. Experiments have been outlined and two flow reactor systems have been designed and are under construction. Commercial catalyst vendors have been contacted about supplying catalyst samples. Several sets of new experiments have been performed to investigate ammonia removal processes and mechanisms for fly ash. Work has focused on a promising class of processes in which ammonia is destroyed by strong oxidizing agents at ambient temperature during semi-dry processing (the use of moisture amounts less than 5 wt-%). Both ozone and an ozone/peroxide combination have been used to treat both basic and acidic ammonia-laden ashes.

Mike Bockelie; Marc Cremer; Kevin Davis; Connie Senior; Bob Hurt; Eric Eddings; Larry Baxter

2001-10-10T23:59:59.000Z

271

Summary of NOx Emissions Reduction from Biomass Cofiring  

DOE Green Energy (OSTI)

NOx emissions from commercial- and pilot-scale biomass/coal cofiring demonstrations are reduced as the percentage of energy supplied to the boiler by the biomass fuel is increased. This report attempts to provide a summary of the NO{sub x} emissions measured during recent biomass/coal cofiring demonstrations. These demonstrations were carried out at the commercial and pilot-scales. Commercial-scale tests were conducted in a variety of pulverized fuel boiler types including wall-fired, T-fired, and cyclone furnaces. Biomass input ranged up to 20% on a mass basis and 10% on an energy basis.

Dayton, D.

2002-05-01T23:59:59.000Z

272

SOx/NOx sorbent and process of use  

DOE Patents (OSTI)

An alumina sorbent capable of adsorbing NOx and SOx from waste gases and being regenerated by heating above 600 C. is made by incorporating an alumina stabilizing agent into the sorbent. A preferred method is to add the stabilizer when the alumina is precipitated. The precipitated powder is formed subsequently into a slurry, milled and dripped to form the stabilizing spheroidal alumina particles. These particles are impregnated with an alkali metal or alkaline earth metal to form the stabilized sorbent. Alumina stabilizers include one or more of silica, lanthana, other rare earths, titania, zirconia and alkaline earths.

Ziebarth, M.S.; Hager, M.J.; Beeckman, J.W.; Plecha, S.

1993-01-19T23:59:59.000Z

273

Carbon dioxide and climate  

SciTech Connect

Scientific and public interest in greenhouse gases, climate warming, and global change virtually exploded in 1988. The Department's focused research on atmospheric CO{sub 2} contributed sound and timely scientific information to the many questions produced by the groundswell of interest and concern. Research projects summarized in this document provided the data base that made timely responses possible, and the contributions from participating scientists are genuinely appreciated. In the past year, the core CO{sub 2} research has continued to improve the scientific knowledge needed to project future atmospheric CO{sub 2} concentrations, to estimate climate sensitivity, and to assess the responses of vegetation to rising concentrations of CO{sub 2} and to climate change. The Carbon Dioxide Research Program's goal is to develop sound scientific information for policy formulation and governmental action in response to changes of atmospheric CO{sub 2}. The Program Summary describes projects funded by the Carbon Dioxide Research Program during FY 1990 and gives a brief overview of objectives, organization, and accomplishments.

1990-10-01T23:59:59.000Z

274

Photocatalytic Conversion of Carbon Dioxide to Methanol.  

E-Print Network (OSTI)

??The photocatalytic conversion of carbon dioxide (CO2) to methanol was investigated. The procedure for the carbon dioxide conversion was carried out using a small scale… (more)

Okpo, Emmanuel

2009-01-01T23:59:59.000Z

275

Figure 37. Carbon dioxide emissions from electricity ...  

U.S. Energy Information Administration (EIA)

Sheet3 Sheet2 Sheet1 Figure 37. Carbon dioxide emissions from electricity generation in three cases, 2005-2040 (million metric tons carbon dioxide ...

276

China's Industrial Carbon Dioxide Emissions in Manufacturing...  

NLE Websites -- All DOE Office Websites (Extended Search)

China's Industrial Carbon Dioxide Emissions in Manufacturing Subsectors and in Selected Provinces Title China's Industrial Carbon Dioxide Emissions in Manufacturing Subsectors and...

277

Optimize carbon dioxide sequestration, enhance oil recovery  

NLE Websites -- All DOE Office Websites (Extended Search)

4 January Optimize carbon dioxide sequestration, enhance oil recovery Optimize carbon dioxide sequestration, enhance oil recovery The simulation provides an important...

278

Optimize carbon dioxide sequestration, enhance oil recovery  

NLE Websites -- All DOE Office Websites (Extended Search)

Optimize carbon dioxide sequestration, enhance oil recovery Optimize carbon dioxide sequestration, enhance oil recovery The simulation provides an important approach to estimate...

279

Advanced NOx Emissions Control: Control Technology - Second Generation  

NLE Websites -- All DOE Office Websites (Extended Search)

Second Generation Advanced Reburning Second Generation Advanced Reburning General Electric - Energy and Environmental Research Corporation (GE-EER) is carrying out a two Phase research program to develop novel Advanced Reburning (AR) concepts for high efficiency and low cost NOx control from coal-fired utility boilers. AR technologies are based on combination of basic reburning and N-agent/promoter injections. Phase I of the project was successfully completed and EER was selected to continue to develop AR technology during Phase II. Phase I demonstrated that AR technologies are able to provide effective NOx control for coal-fired combustors. Three technologies were originally envisioned for development: AR-Lean, AR-Rich, and Multiple Injection AR (MIAR). Along with these, three additional technologies were identified during the project: reburning plus promoted SNCR; AR-Lean plus promoted SNCR; and AR-Rich plus promoted SNCR. The promoters are sodium salts, in particular sodium carbonate. These AR technologies have different optimum reburn heat input levels and furnace temperature requirements. For full scale application, an optimum technology can be selected on a boiler-specific basis depending on furnace temperature profile and regions of injector access.

280

2004 Conference on Reburning for NOX Control Reburning on Trial  

NLE Websites -- All DOE Office Websites (Extended Search)

2004 Conf. on Reburning for NOx Control Reburning on Trial 2004 Conf. on Reburning for NOx Control Reburning on Trial May 18, 2004 Table of Contents Disclaimer Papers and Presentations Reburning Overview Commercial Reburning Experience Biomass Reburning Other Applications of Reburning Posters Disclaimer This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government or any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. Reference herein to any specific commercial product, process, or service by trade name, trademark, manufacturer, or otherwise does not necessarily constitute or imply its endorsement, recommendation, or favoring by the United States Government or any agency thereof. The views and opinions of authors expressed herein do not necessarily state or reflect those of the United States Government or any agency thereof.

Note: This page contains sample records for the topic "nox sulfur dioxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

NOx Control Options and Integration for US Coal Fired Boilers  

Science Conference Proceedings (OSTI)

This is the twelfth Quarterly Technical Report for DOE Cooperative Agreement No: DE-FC26-00NT40753. The goal of the project is to develop cost effective analysis tools and techniques for demonstrating and evaluating low NOx control strategies and their possible impact on boiler performance for boilers firing US coals. The Electric Power Research Institute (EPRI) is providing co-funding for this program. This program contains multiple tasks and good progress is being made on all fronts. During this quarter, a new effort was begun on the development of a corrosion management system for minimizing the impacts of low NOx combustion systems on waterwalls; a kickoff meeting was held at the host site, AEP's Gavin Plant, and work commenced on fabrication of the probes. FTIR experiments for SCR catalyst sulfation were finished at BYU and indicated no vanadium/vanadyl sulfate formation at reactor conditions. Improvements on the mass-spectrometer system at BYU have been made and work on the steady state reactor system shakedown neared completion. The slipstream reactor continued to operate at AEP's Rockport plant; at the end of the quarter, the catalysts had been exposed to flue gas for about 1000 hours. Some operational problems were addressed that enable the reactor to run without excessive downtime by the end of the quarter.

Mike Bockelie; Kevin Davis; Temi Linjewile; Connie Senior; Eric Eddings; Kevin Whitty; Larry Baxter; Calvin Bartholomew; William Hecker; Stan Harding

2003-06-30T23:59:59.000Z

282

ULTRA LOW NOx CATALYTIC COMBUSTION FOR IGCC POWER PLANTS  

Science Conference Proceedings (OSTI)

Tests were performed in PCI's sub-scale high-pressure (10 atm) test rig, using PCI's two-stage (catalytic / gas-phase) combustion process for syngas fuel. In this process, the first stage is a Rich-Catalytic Lean-burn (RCL{trademark}) catalytic reactor, wherein a fuel-rich mixture contacts the catalyst and reacts while final and excess combustion air cool the catalyst. The second stage is a gas-phase combustor, wherein the catalyst cooling air mixes with the catalytic reactor effluent to provide for final gas-phase burnout and dilution to fuel-lean combustion products. During the reporting period, PCI successfully achieved NOx = 0.011 lbs/MMBtu at 10 atm pressure (corresponding to 2.0 ppm NOx corrected to 15% O{sub 2} dry) with near-zero CO emissions, surpassing the project goal of baseload conditions corresponding to Tampa Electric's Polk Power Station operation on 100% syngas (no co-firing of natural gas).

Lance L. Smith

2004-03-01T23:59:59.000Z

283

Three-Dimensional Composite Nanostructures for Lean NOx Emission Control  

DOE Green Energy (OSTI)

In this project, through a scalable solution process, we have successfully fabricated a new class of catalytic reactors, i.e., the composite nanostructure array (nano-array) based catalytic converters. These nanocatalysts, distinct from traditional powder washcoat based catalytic converters, directly integrate monolithic substrates together with nanostructures with well-defined size and shape during the scalable hydrothermal process. The new monolithic nanocatalysts are demonstrated to be able to save raw materials including Pt-group metals and support metal oxides by an order of magnitude, while perform well at various oxidation (e.g., CO oxidation and NO oxidation) and reduction reactions (H{sub 2} reduction of NOx) involved in the lean NOx emissions. The size, shape and arrangement of the composite nanostructures within the monolithic substrates are found to be the key in enabling the drastically reduced materials usage while maintaining the good catalytic reactivity in the enabled devices. The further understanding of the reaction kinetics associated with the unique mass transport and surface chemistry behind is needed for further optimizing the design and fabrication of good nanostructure array based catalytic converters. On the other hand, the high temperature stability, hydrothermal aging stability, as well as S-poisoning resistance have been investigated in this project on the nanocatalysts, which revealed promising results toward good chemical and mechanical robustness, as well as S-poisoning resistance. Further investigation is needed for unraveling the understanding, design and selection principles of this new class of nanostructure based monolithic catalysts.

Gao, Pu-Xian

2013-07-31T23:59:59.000Z

284

Experimental Study of Non-thermal Plasma Injection System Converting NOx in Simulated Diesel Emissions  

Science Conference Proceedings (OSTI)

In order to study the removal effect of non-thermal plasma (NTP) after-treatment system on diesel engine harmful emissions, a dielectric barrier discharge (DBD) plasma reactor is designed, and the NOx removal effect is studied under the conditions of ... Keywords: Non-thermal Plasma(NTP), Dielectric Barrier Discharge(DBD, Diesel Engine, Nox

Jing Wang; Yixi Cai; Jun Wang; Dongli Ran

2010-11-01T23:59:59.000Z

285

Active NOX Control of Cogen Gas Turbine Exhaust using a Nonlinear Feed Forward with Cascade Architecture  

E-Print Network (OSTI)

Active NOX Control of Cogen Gas Turbine Exhaust using a Nonlinear Feed Forward with Cascade control, cogeneration, gas turbine, model based control, feed forward, cascade ABSTRACT Presented is a model based strategy for controlling the NOX concentration of natural gas turbine emissions

Cooper, Doug

286

NOx Adsorbers for Heavy Duty Truck Engines-Testing and Simulation  

DOE Green Energy (OSTI)

This feasibility study of NOx adsorbers in heavy-duty diesel engines examined three configurations (dual-leg, single-leg and single-leg-bypass) in an integrated experimental setup, composed of a Detroit Diesel Class-8 truck engine, a catalyzed diesel particulate filter and the NOx absorber system. The setup also employed a reductant injection concept, sensors and advanced control strategies.

Hakim, N; Hoelzer, J.; Liu, Y.

2002-08-25T23:59:59.000Z

287

Retrofit NOx Control Guidelines for Gas- and Oil-Fired Boilers Version 2.0  

Science Conference Proceedings (OSTI)

This document reviews and summarizes NOx control technologies to help utility engineering and operating staff evaluate and select appropriate retrofit strategies for natural gas- and oil-fired boilers. In addition to general discussions of the various technologies, the document includes an accompanying database on diskette with detailed information on 239 NOx retrofits.

1997-08-19T23:59:59.000Z

288

NATURAL GAS REBURNING TECHNOLOGY FOR NOx REDUCTION FROM MSW COMBUSTION SYSTEMS  

E-Print Network (OSTI)

NATURAL GAS REBURNING TECHNOLOGY FOR NOx REDUCTION FROM MSW COMBUSTION SYSTEMS Discussion by CRAIG's increased turbulent mixing is on the CO profile and what the incremental NOx reduction experienced was from that this alone would contribute to a significant reduction in the NO", generated. The authors are careful

Columbia University

289

Key Issues in the Design of NOx Emission Trading Programs to Reduce Ground-Level Ozone  

Science Conference Proceedings (OSTI)

As NOx control requirements grow more stringent and expensive, interest in emission trading as a means of controlling costs and increasing flexibility has risen. This report provides background information for and analysis of the design of emission trading programs for control of nitrogen oxides (NOx) from stationary sources, including fossil fuel electric generating plants.

1994-10-07T23:59:59.000Z

290

The Cost of Carbon Dioxide Capture and Storage in Geologic Formations  

NLE Websites -- All DOE Office Websites (Extended Search)

CosT of Carbon DioxiDe CapTure CosT of Carbon DioxiDe CapTure anD sTorage in geologiC formaTions The sequestration of carbon dioxide (CO 2 ) in geologic formations is a viable option for achieving deep reductions in greenhouse gas emissions without hindering economic prosperity. Due to the abundance of fossil fuels in the United States and around the globe as compared to other energy sources, there is strong interest in geologic sequestration, but cost is a key issue. The volume of CO 2 emitted from power plants and other energy systems is enormous compared to other emissions of concern. For example, a pulverized coal (PC) boiler operating on Illinois #6 coal (2.5 percent sulfur) may generate 0.03 pounds of sulfur dioxide per kilowatt hour (kWh) and emit CO 2 at a rate of 1.7 pounds per kWh.

291

NETL: PPII - Integration of Low-NOx Burners with an Optimization Plan for  

NLE Websites -- All DOE Office Websites (Extended Search)

Integration of Low-NOx Burners with an Optimization Plan for Boiler Combustion Integration of Low-NOx Burners with an Optimization Plan for Boiler Combustion - Project Brief [PDF-72KB] Sunflower Electric Power Corp., Garden City, Finney County, KS PROJECT FACT SHEET Achieving New Source Performance Standards (NSPS) Through Integration of Low-NOx Burners with an Optimization Plan for Boiler Combustion [PDF-260KB] (Oct 2008) PROGRAM PUBLICATIONS Final Report Achieving NSPS Emission Standards Through Integration of Low NOx Burners with an Optimization Plan for Boiler Combustion [PDF-3.4MB] (June 2006) CCT Reports: Project Performance Summaries, Post-Project Assessments, & Topical Reports Achieving New Source Performance Standards (NSPS) Emission Standards through Integration of Low-NOx Burners with an Optimization Plan for Boiler Combustion: A DOE Assessment [PDF-1.4MB] (Nov 2006)

292

EA-1472: Commercial Demonstration fo the Low Nox Burner/Separated Over-Fire  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

472: Commercial Demonstration fo the Low Nox Burner/Separated 472: Commercial Demonstration fo the Low Nox Burner/Separated Over-Fire Air (LNB/SOFA) Integration System Emission Reduction Technology, Holcolm Station, Sunflower Electric Power Corporation Finnety County, Kansas EA-1472: Commercial Demonstration fo the Low Nox Burner/Separated Over-Fire Air (LNB/SOFA) Integration System Emission Reduction Technology, Holcolm Station, Sunflower Electric Power Corporation Finnety County, Kansas SUMMARY The DOE has prepared an Environmental Assessment (EA), to analyze the potential impacts of the commercial application of the Low-NOx Burner/Separated Over-Fire Air (LNB/SOFA) integration system to achieve nitrogen oxide (NOx) emissions reduction at Sunflower's Holcomb Unit No. 1 (Holcomb Station), located near Garden City, in Finney County, Kansas.

293

Modeling of NOx Destruction Options for INEEL Sodium-Bearing Waste Vitrification  

SciTech Connect

Off-gas NOx concentrations in the range of 1-5 mol% are expected as a result of the proposed vitrification of sodium-bearing waste at the Idaho National Engineering and Environmental Laboratory. An existing kinetic model for staged combustion (originally developed for NOx abatement from the calcination process) was updated for application to vitrification offgas. In addition, two new kinetic models were developed to assess the feasibility of using selective non-catalytic reduction (SNCR) or high-temperature alone for NOx abatement. Each of the models was developed using the Chemkin code. Results indicate that SNCR is a viable option, reducing NOx levels to below 1000 ppmv. In addition, SNCR may be capable of simultaneously reducing CO emissions to below 100 ppmv. Results for using high-temperature alone were not as promising, indicating that a minimum NOx concentration of 3950 ppmv is achievable at 3344°F.

Wood, Richard Arthur

2001-09-01T23:59:59.000Z

294

FURNACE INJECTION OF ALKALINE SORBENTS FOR SULFURIC ACID REMOVAL  

Science Conference Proceedings (OSTI)

The objective of this project has been to demonstrate the use of alkaline reagents injected into the furnace of coal-fired boilers as a means of controlling sulfuric acid emissions. The project was co-funded by the U.S. DOE National Energy Technology Laboratory under Cooperative Agreement DE-FC26-99FT40718, along with EPRI, the American Electric Power Company (AEP), FirstEnergy Corporation, the Tennessee Valley Authority, and Carmeuse North America. Sulfuric acid controls are becoming of increased interest for coal-fired power generating units for a number of reasons. In particular, sulfuric acid can cause plant operation problems such as air heater plugging and fouling, back-end corrosion, and plume opacity. These issues will likely be exacerbated with the retrofit of selective catalytic reduction (SCR) for NOX control, as SCR catalysts are known to further oxidize a portion of the flue gas SO{sub 2} to SO{sub 3}. The project tested the effectiveness of furnace injection of four different magnesium-based or dolomitic alkaline sorbents on full-scale utility boilers. These reagents were tested during one- to two-week tests conducted on two FirstEnergy Bruce Mansfield Plant (BMP) units. One of the sorbents tested was a magnesium hydroxide slurry byproduct from a modified Thiosorbic{reg_sign} Lime wet flue gas desulfurization process. The other three sorbents are available commercially and include dolomite, pressure-hydrated dolomitic lime, and commercially available magnesium hydroxide. The dolomite reagent was injected as a dry powder through out-of-service burners. The other three reagents were injected as slurries through air-atomizing nozzles inserted through the front wall of the upper furnace. After completing the four one- to two-week tests, the most promising sorbents were selected for longer-term (approximately 25-day) full-scale tests on two different units. The longer-term tests were conducted to confirm sorbent effectiveness over extended operation on two different boilers, and to determine balance-of-plant impacts. The first long-term test was conducted on FirstEnergy's BMP Unit 3, and the second was conducted on AEP's Gavin Plant, Unit 1. The Gavin Plant test provided an opportunity to evaluate the effects of sorbent injected into the furnace on SO{sub 3} formed across an operating SCR reactor. A final task in the project was to compare projected costs for furnace injection of magnesium hydroxide slurries to estimated costs for other potential sulfuric acid control technologies. Estimates were developed for reagent and utility costs, and capital costs, for furnace injection of magnesium hydroxide slurries and seven other sulfuric acid control technologies. The estimates were based on retrofit application to a model coal-fired plant.

Gary M. Blythe

2004-01-01T23:59:59.000Z

295

Enhanced Elemental Mercury Removal from Coal-fired Flue Gas by Sulfur-chlorine Compounds  

E-Print Network (OSTI)

efficiency by sulfur and/or chlorine containing compounds atfired Flue Gas by Sulfur-chlorine Compounds Nai-Qiang Yanremoval. Two sulfur-chlorine compounds, sulfur dichloride (

Miller, Nai-Qiang Yan-Zan Qu Yao Chi Shao-Hua Qiao Ray Dod Shih-Ger Chang Charles

2008-01-01T23:59:59.000Z

296

World petroleum-derived sulfur production  

SciTech Connect

Research efforts in new uses for sulfur, among them those of the Sulfur Development Institute of Canada, have resulted in the development of several new product markets. Petroleum and natural gas derived sulfurs are finding use as asphalt extenders in road construction throughout North America and as concrete extenders and substitutes for Portland cement in the construction industries of Mexico and the Middle East. Their use in masonry blocks is now being commercialized. Canada is the world's largest producer of commercial sulfur; 80% of it is used as a processing chemical in the form of sulfuric acid. Saudi Arabia, recently having begun to commercialize its vast resources, is constructing plants for the extraction of sulfur from natural gas and plans to export between 6 and 7 x 10/sup 5/ tons annually, much of it for fertilizer manufacture to India, Tunisia, Italy, Pakistan, Greece, Morocco, and Thailand.

Cantrell, A.

1982-08-02T23:59:59.000Z

297

The Influence of Flue Gas Recirculation on the Formation of NOx in the Process of Coal Grate-Fired  

Science Conference Proceedings (OSTI)

With the improvement of environmental protection requirements, the problems of NOx emission from industrial boiler become more and more notable. To explore a real effective method of low NOx combustion, the article discusses the influence of flue gas ... Keywords: flue gas recirculation, grate-fired, temperature, Nox

Li Xu; Jianmin Gao; Guangbo Zhao; Laifu Zhao; Zhifeng Zhao; Shaohua Wu

2011-03-01T23:59:59.000Z

298

Topsoe`s Wet gas Sulfuric Acid (WSA) process: An alternative technology for recovering refinery sulfur  

SciTech Connect

The Topsoe Wet gas Sulfuric Acid (WSA) process is a catalytic process which produces concentrated sulfuric acid from refinery streams containing sulfur compounds such as H{sub 2}S (Claus plant feed), Claus plant tail gas, SO{sub 2} (FCC off-gas, power plants), and spent sulfuric acid (alkylation acid). The WSA process recovers up to 99.97% of the sulfur value in the stream as concentrated sulfuric acid (93--98.5 wt%). No solid waste products or waste water is produced and no chemicals are consumed in the process. The simple process layout provides low capital cost and attractive operating economy. Twenty four commercial WSA plants have been licensed. The WSA process is explained in detail and comparisons with alternative sulfur management technology are presented. Environmental regulations applying to SO{sub x} abatement and sulfuric acid production plants are explained in the context of WSA plant operation.

Ward, J.W. [Haldor Topsoe, Inc., Houston, TX (United States)

1995-09-01T23:59:59.000Z

299

HYDROCARBON AND SULFUR SENSORS FOR SOFC SYSTEMS  

DOE Green Energy (OSTI)

The following report summarizes work conducted during the Phase I program Hydrocarbon and Sulfur Sensors for SOFC Systems under contract No. DE-FC26-02NT41576. For the SOFC application, sensors are required to monitor hydrocarbons and sulfur in order to increase the operation life of SOFC components. This report discusses the development of two such sensors, one based on thick film approach for sulfur monitoring and the second galvanic based for hydrocarbon monitoring.

A.M. Azad; Chris Holt; Todd Lesousky; Scott Swartz

2003-11-01T23:59:59.000Z

300

It's Elemental - Isotopes of the Element Sulfur  

NLE Websites -- All DOE Office Websites (Extended Search)

Phosphorus Previous Element (Phosphorus) The Periodic Table of Elements Next Element (Chlorine) Chlorine Isotopes of the Element Sulfur Click for Main Data Most of the isotope...

Note: This page contains sample records for the topic "nox sulfur dioxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Improved sulfur removal processes evaluated for IGCC  

SciTech Connect

An inherent advantage of Integrated Coal Gasification Combined Cycle (IGCC) electric power generation is the ability to easily remove and recover sulfur. During the last several years, a number of new, improved sulfur removal and recovery processes have been commercialized. An assessment is given of alternative sulfur removal processes for IGCC based on the Texaco coal gasifier. The Selexol acid gas removal system, Claus sulfur recovery, and SCOT tail gas treating are currently used in Texaco-based IGCC. Other processes considered are: Purisol, Sulfinol-M, Selefning, 50% MDEA, Sulften, and LO-CAT. 2 tables.

1986-12-01T23:59:59.000Z

302

Retail Prices for Ultra Low Sulfur Diesel  

U.S. Energy Information Administration (EIA)

Beginning July 26, 2010 publication of Ultra Low Sulfur Diesel (ULSD) price became fully represented by the Diesel Average All Types price. As of December 1, ...

303

Natural Gas Processing Plant- Sulfur (New Mexico)  

Energy.gov (U.S. Department of Energy (DOE))

This regulation establishes sulfur emission standards for natural gas processing plants. Standards are stated for both existing and new plants. There are also rules for stack height requirements,...

304

THE EFFECT OF ANOLYTE PRODUCT ACID CONCENTRATION ON HYBRID SULFUR CYCLE PERFORMANCE  

DOE Green Energy (OSTI)

The Hybrid Sulfur (HyS) cycle (Fig. 1) is one of the simplest, all-fluids thermochemical cycles that has been devised for splitting water with a high-temperature nuclear or solar heat source. It was originally patented by Brecher and Wu in 1975 and extensively developed by Westinghouse in the late 1970s and early 1980s. As its name suggests, the only element used besides hydrogen and oxygen is sulfur, which is cycled between the +4 and +6 oxidation states. HyS comprises two steps. One is the thermochemical (>800 C) decomposition of sulfuric acid (H{sub 2}SO{sub 4}) to sulfur dioxide (SO{sub 2}), oxygen (O{sub 2}), and water. H{sub 2}SO{sub 4} = SO{sub 2} + 1/2 O{sub 2} + H{sub 2}O. The other is the SO{sub 2}-depolarized electrolysis of water to H{sub 2}SO{sub 4} and hydrogen (H{sub 2}), SO{sub 2} + 2 H{sub 2}O = H{sub 2}SO{sub 4} + H{sub 2}, E{sup o} = -0.156 V, explaining the 'hybrid' designation. These two steps taken together split water into H{sub 2} and O{sub 2} using heat and electricity. Researchers at the Savannah River National Laboratory (SRNL) and at the University of South Carolina (USC) have successfully demonstrated the use of proton exchange membrane (PEM) electrolyzers (Fig. 2) for the SO{sub 2}-depolarized electrolysis (sulfur oxidation) step, while Sandia National Laboratories (SNL) successfully demonstrated the high-temperature sulfuric acid decomposition (sulfur reduction) step using a bayonet-type reactor (Fig. 3). This latter work was performed as part of the Sulfur-Iodine (SI) cycle Integrated Laboratory Scale demonstration at General Atomics (GA). The combination of these two operations results in a simple process that will be more efficient and cost-effective for the massive production of hydrogen than alkaline electrolysis. Recent developments suggest that the use of PEMs other than Nafion will allow sulfuric acid to be produced at higher concentrations (>60 wt%), offering the possibility of net thermal efficiencies around 50% (HHV basis). The effect of operation at higher anolyte concentrations on the flowsheet, and on the net thermal efficiency for a nuclear-heated HyS process, is examined and quantified.

Gorensek, M.; Summers, W.

2010-03-24T23:59:59.000Z

305

Simultaneous Removal of NOx and Mercury in Low Temperature Selective Catalytic and Adsorptive Reactor  

SciTech Connect

The results of a 18-month investigation to advance the development of a novel Low Temperature Selective Catalytic and Adsorptive Reactor (LTSCAR), for the simultaneous removal of NO{sub x} and mercury (elemental and oxidized) from flue gases in a single unit operation located downstream of the particulate collectors, are reported. In the proposed LTSCAR, NO{sub x} removal is in a traditional SCR mode but at low temperature, and, uniquely, using carbon monoxide as a reductant. The concomitant capture of mercury in the unit is achieved through the incorporation of a novel chelating adsorbent. As conceptualized, the LTSCAR will be located downstream of the particulate collectors (flue gas temperature 140-160 C) and will be similar in structure to a conventional SCR. That is, it will have 3-4 beds that are loaded with catalyst and adsorbent allowing staged replacement of catalyst and adsorbent as required. Various Mn/TiO{sub 2} SCR catalysts were synthesized and evaluated for their ability to reduce NO at low temperature using CO as the reductant. It has been shown that with a suitably tailored catalyst more than 65% NO conversion with 100% N{sub 2} selectivity can be achieved, even at a high space velocity (SV) of 50,000 h-1 and in the presence of 2 v% H{sub 2}O. Three adsorbents for oxidized mercury were developed in this project with thermal stability in the required range. Based on detailed evaluations of their characteristics, the mercaptopropyltrimethoxysilane (MPTS) adsorbent was found to be most promising for the capture of oxidized mercury. This adsorbent has been shown to be thermally stable to 200 C. Fixed-bed evaluations in the targeted temperature range demonstrated effective removal of oxidized mercury from simulated flue gas at very high capacity ({approx}>58 mg Hg/g adsorbent). Extension of the capability of the adsorbent to elemental mercury capture was pursued with two independent approaches: incorporation of a novel nano-layer on the surface of the chelating mercury adsorbent to achieve in situ oxidation on the adsorbent, and the use of a separate titania-supported manganese oxide catalyst upstream of the oxidized mercury adsorbent. Both approaches met with some success. It was demonstrated that the concept of in situ oxidation on the adsorbent is viable, but the future challenge is to raise the operating capacity beyond the achieved limit of 2.7 mg Hg/g adsorbent. With regard to the manganese dioxide catalyst, elemental mercury was very efficiently oxidized in the absence of sulfur dioxide. Adequate resistance to sulfur dioxide must be incorporated for the approach to be feasible in flue gas. A preliminary benefits analysis of the technology suggests significant potential economic and environmental advantages.

Neville G. Pinto; Panagiotis G. Smirniotis

2006-03-31T23:59:59.000Z

306

Sonic Enhanced Ash Agglomeration and Sulfur Capture. Technical progress report, October 1992--December 1992  

SciTech Connect

A major concern with the utilization of coal in directly fired gas turbines is the control of particulate emissions and reduction of sulfur dioxide, and alkali vapor from combustion of coal, upstream of the gas turbine. Much research and development has been sponsored on methods for particulate emissions control and the direct injection of calcium-based sorbents to reduce SO{sub 2} emission levels. The results of this research and development indicate that both acoustic agglomeration of particulates and direct injection of sorbents have the potential to become a significant emissions control strategy. The Sonic Enhanced Ash Agglomeration and Sulfur Capture program focuses upon the application of an MTCI proprietary invention (Invention Disclosure filed) for simultaneously enhancing sulfur capture and particulate agglomeration of the combustor effluent. This application can be adapted as either a ``hot flue gas cleanup`` subsystem for the current concepts for combustor islands or as an alternative primary pulse combustor island in which slagging, sulfur capture, particulate agglomeration and control, and alkali gettering as well as NO{sub x} control processes become an integral part of the pulse combustion process.

Not Available

1992-12-31T23:59:59.000Z

307

Co-firing high sulfur coal with refuse derived fuels. Final report  

DOE Green Energy (OSTI)

This project was designed to evaluate the combustion performance of and emissions from a fluidized bed combustor during the combustion of mixtures of high sulfur and/or high chlorine coals and municipal solid waste (MSW). The project included four major tasks, which were as follows: (1) Selection, acquisition, and characterization of raw materials for fuels and the determination of combustion profiles of combination fuels using thermal analytical techniques; (2) Studies of the mechanisms for the formation of chlorinated organics during the combustion of MSW using a tube furnace; (3) Investigation of the effect of sulfur species on the formation of chlorinated organics; and (4) Examination of the combustion performance of combination fuels in a laboratory scale fluidized bed combustor. Several kinds of coals and the major combustible components of the MSW, including PVC, newspaper, and cellulose were tested in this project. Coals with a wide range of sulfur and chlorine contents were used. TGA/MS/FTIR analyses were performed on the raw materials and their blends. The possible mechanism for the formation of chlorinated organics during combustion was investigated by conducting a series of experiments in a tube furnace. The effect of sulfur dioxide on the formation of molecular chlorine during combustion processes was examined in this study.

Pan, W.P.; Riley, J.T.; Lloyd, W.G.

1997-11-30T23:59:59.000Z

308

Nitrogen Oxides (NOx), Why and How They are Controlled  

NLE Websites -- All DOE Office Websites (Extended Search)

Air Quality EPA 456/F-99-006R Air Quality EPA 456/F-99-006R Environmental Protection Planning and Standards November 1999 Agency Research Triangle Park, NC 27711 Air EPA-456/F-99-006R November 1999 Nitrogen Oxides (NOx), Why and How They Are Controlled Prepared by Clean Air Technology Center (MD-12) Information Transfer and Program Integration Division Office of Air Quality Planning and Standards U.S. Environmental Protection Agency Research Triangle Park, North Carolina 27711 ii DISCLAIMER This report has been reviewed by the Information Transfer and Program Integration Division of the Office of Air Quality Planning and Standards, U.S. Environmental Protection Agency and approved for publication. Approval does not signify that the contents of this report reflect the views and policies of the U.S. Environmental Protection Agency. Mention of trade

309

JV Task-Long-Kiln NOx Reduction Study  

Science Conference Proceedings (OSTI)

Field sampling was conducted by the Energy & Environmental Research Center at two Lafarge North America cement kiln locations in Canada. Emissions including SO{sub x}, NO{sub x}, and particulate were measured and reported at various locations throughout the kilns. At each site data were collected on two kilns during field sampling. However, only Kiln 1 at the Ravena site was utilized for modeling efforts. Experimental work was then conducted to estimate the effectiveness of various NO{sub x} control techniques on limiting both NO{sub x} and SO{sub x} emissions in cement kiln exhaust. Theory-based models were constructed to estimate both NO{sub x} and SO{sub x} emissions from cement kilns. These models were then applied to estimating the impact of various NO{sub x} control strategies on kiln exhaust emissions. The sulfur model constructed as part of this work was successful at predicting SO{sub 2} emissions and sulfur capture in the Alpena kiln. This model is designed to run as a postprocessing step that uses the output of a NO{sub x} model as input. With an accurate NO{sub x} model, the sulfur model may prove to be a valuable tool in estimating the impact of kiln modifications on sulfur emissions. The NO{sub x} model was also applied to model several operating scenarios on three of Lafarge's kilns: Alpena 20/21, Alpena 22/23, and Ravena 1. The predictions of the flue gas temperature at the kiln feed end, the kiln shell heat loss, the quality of clinker, and the excess O{sub 2} in the flue gas are consistent with the audit data. The developed simulation tool in this project has proven to be an effective way to investigate the NO{sub x} emissions, to optimize kiln performance, and to assess changes in operating condition on kiln performance.

Bruce Folkedahl; Joshua Strege; Darren Schmidt; Lingbu Kong

2008-07-01T23:59:59.000Z

310

Sulfur  

U.S. Energy Information Administration (EIA)

-No Data Reported; --= Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Notes: Hydrogen production ...

311

NOx Control Options and Integration for US Coal Fired Boilers  

DOE Green Energy (OSTI)

This is the fourteenth Quarterly Technical Report for DOE Cooperative Agreement No: DEFC26-00NT40753. The goal of the project is to develop cost effective analysis tools and techniques for demonstrating and evaluating low NOx control strategies and their possible impact on boiler performance for boilers firing US coals. The Electric Power Research Institute (EPRI) is providing co-funding for this program. Using the initial CFD baseline modeling of the Gavin Station and the plant corrosion maps, six boiler locations for the corrosion probes were identified and access ports have been installed. Preliminary corrosion data obtained appear consistent and believable. In situ, spectroscopic experiments at BYU reported in part last quarter were completed. New reactor tubes have been made for BYU's CCR that allow for testing smaller amounts of catalyst and thus increasing space velocity; monolith catalysts have been cut and a small reactor that can accommodate these pieces for testing is in its final stages of construction. A poisoning study on Ca-poisoned catalysts was begun this quarter. A possible site for a biomass co-firing test of the slipstream reactor was visited this quarter. The slipstream reactor at Rockport required repair and refurbishment, and will be re-started in the next quarter. This report describes the final results of an experimental project at Brown University on the fundamentals of ammonia / fly ash interactions with relevance to the operation of advanced NOx control technologies such as selective catalytic reduction. The Brown task focused on the measurement of ammonia adsorption isotherms on commercial fly ash samples subjected to a variety of treatments and on the chemistry of dry and semi-dry ammonia removal processes.

Mike Bockelie; Kevin Davis; Temi Linjewile; Connie Senior; Eric Eddings; Kevin Whitty; Larry Baxter; Calvin Bartholomew; William Hecker; Stan Harding; Robert Hurt

2003-12-31T23:59:59.000Z

312

SELECTIVE NOx RECIRCULATION FOR STATIONARY LEAN-BURN NATURAL GAS ENGINES  

DOE Green Energy (OSTI)

The research program conducted at the West Virginia University Engine and Emissions Research Laboratory (EERL) is working towards the verification and optimization of an approach to remove nitric oxides from the exhaust gas of lean burn natural gas engines. This project was sponsored by the US Department of Energy, National Energy Technology Laboratory (NETL) under contract number: DE-FC26-02NT41608. Selective NOx Recirculation (SNR) involves three main steps. First, NOx is adsorbed from the exhaust stream, followed by periodic desorption from the aftertreatment medium. Finally the desorbed NOx is passed back into the intake air stream and fed into the engine, where a percentage of the NOx is decomposed. This reporting period focuses on the NOx decomposition capability in the combustion process. Although researchers have demonstrated NOx reduction with SNR in other contexts, the proposed program is needed to further understand the process as it applies to lean burn natural gas engines. SNR is in support of the Department of Energy goal of enabling future use of environmentally acceptable reciprocating natural gas engines through NOx reduction under 0.1 g/bhp-hr. The study of decomposition of oxides of nitrogen (NOx) during combustion in the cylinder was conducted on a 1993 Cummins L10G 240 hp lean burn natural gas engine. The engine was operated at different air/fuel ratios, and at a speed of 800 rpm to mimic a larger bore engine. A full scale dilution tunnel and analyzers capable of measuring NOx, CO{sub 2}, CO, HC concentrations were used to characterize the exhaust gas. Commercially available nitric oxide (NO) was used to mimic the NOx stream from the desorption process through a mass flow controller and an injection nozzle. The same quantity of NOx was injected into the intake and exhaust line of the engine for 20 seconds at various steady state engine operating points. NOx decomposition rates were obtained by averaging the peak values at each set point minus the baseline and finding the ratio between the injected NO amounts. It was observed that the air/fuel ratio, injected NO quantity and engine operating points affected the NOx decomposition rates of the natural gas engine. A highest NOx decomposition rate of 27% was measured from this engine. A separate exploratory tests conducted with a gasoline engine with a low air/fuel ratio yielded results that suggested, that high NOx decomposition rates may be possible if a normally lean burn engine were operated at conditions closer to stoichiometric, with high exhaust gas recirculation (EGR) for a brief period of time during the NOx decomposition phase and with a wider range of air/fuel ratios. Chemical kinetic model predictions using CHEMKIN were performed to relate the experimental data with the established rate and equilibrium models. NOx decomposition rates from 35% to 42% were estimated using the CHEMKIN software. This provided insight on how to maximize NOx decomposition rates for a large bore engine. In the future, the modeling will be used to examine the effect of higher NO{sub 2}/NO ratios that are associated with lower speed and larger bore lean burn operation.

Nigel Clark; Gregory Thompson; Richard Atkinson; Chamila Tissera; Matt Swartz; Emre Tatli; Ramprabhu Vellaisamy

2005-01-01T23:59:59.000Z

313

decommissioning of carbon dioxide (CO  

NLE Websites -- All DOE Office Websites (Extended Search)

decommissioning of carbon dioxide (CO decommissioning of carbon dioxide (CO 2 ) storage wells. The manual builds on lessons learned through NETL research; the experiences of the Regional Carbon Sequestration Partnerships' (RCSPs) carbon capture, utilization, and storage (CCUS) field tests; and the acquired knowledge of industries that have been actively drilling wells for more than 100 years. In addition, the BPM provides an overview of the well-

314

METHOD OF MAKING PLUTONIUM DIOXIDE  

DOE Patents (OSTI)

A process is presented For converting both trivalent and tetravalent plutonium oxalate to substantially pure plutonium dioxide. The plutonium oxalate is carefully dried in the temperature range of 130 to300DEC by raising the temperature gnadually throughout this range. The temperature is then raised to 600 C in the period of about 0.3 of an hour and held at this level for about the same length of time to obtain the plutonium dioxide.

Garner, C.S.

1959-01-13T23:59:59.000Z

315

NETL: News Release - DOE Selects Five NOx-Control Projects to Combat Acid  

NLE Websites -- All DOE Office Websites (Extended Search)

November 5, 2004 November 5, 2004 DOE Selects Five NOx-Control Projects to Combat Acid Rain and Smog Industry Partners to Focus on Reducing Emissions While Cutting Energy Costs PITTSBURGH, PA - Continuing efforts to cut acid rain and smog-producing nitrogen oxides (NOx) have prompted the U.S. Department of Energy to partner with industry experts to develop advanced NOx-control technologies. With the selection of five new NOx-control projects, the Energy Department continues as a leader in developing advanced technologies to achieve environmental compliance for the nation's fleet of coal-fired power plants. Although today's NOx-control workhorses, such as low-NOx burners and selective catalytic reduction (SCR), have been successfully deployed to address existing regulations, proposed regulations will require deeper cuts in NOx emissions, at a greater number of generating facilities. Many of the smaller affected plants will not be able to cost-effectively use today's technologies; these are the focus of the advanced technologies selected in this announcement.

316

Effects of Coaxial Air on Nitrogen-Diluted Hydrogen Jet Diffusion Flame Length and NOx Emission  

DOE Green Energy (OSTI)

Turbulent nitrogen-diluted hydrogen jet diffusion flames with high velocity coaxial air flows are investigated for their NOx emission levels. This study is motivated by the DOE turbine program’s goal of achieving 2 ppm dry low NOx from turbine combustors running on nitrogen-diluted high-hydrogen fuels. In this study, effects of coaxial air velocity and momentum are varied while maintaining low overall equivalence ratios to eliminate the effects of recirculation of combustion products on flame lengths, flame temperatures, and resulting NOx emission levels. The nature of flame length and NOx emission scaling relationships are found to vary, depending on whether the combined fuel and coaxial air jet is fuel-rich or fuel-lean. In the absence of differential diffusion effects, flame lengths agree well with predicted trends, and NOx emissions levels are shown to decrease with increasing coaxial air velocity, as expected. Normalizing the NOx emission index with a flame residence time reveals some interesting trends, and indicates that a global flame strain based on the difference between the fuel and coaxial air velocities, as is traditionally used, is not a viable parameter for scaling the normalized NOx emissions of coaxial air jet diffusion flames.

Weiland, N.T.; Chen, R.-H.; Strakey, P.A.

2007-10-01T23:59:59.000Z

317

Global NOx Measurements in Turbulent Nitrogen-Diluted Hydrogen Jet Flames  

DOE Green Energy (OSTI)

Turbulent hydrogen diffusion flames diluted with nitrogen are currently being studied to assess their ability to achieve the DOE Turbine Program’s aggressive emissions goal of 2 ppm NOx in a hydrogen-fueled IGCC gas turbine combustor. Since the unstrained adiabatic flame temperatures of these diluted flames are not low enough to eliminate thermal NOx formation the focus of the current work is to study how the effects of flame residence time and global flame strain can be used to help achieve the stated NOx emissions goal. Dry NOx measurements are presented as a function of jet diameter nitrogen dilution and jet velocity for a turbulent hydrogen/nitrogen jet issuing from a thin-lipped tube in an atmospheric pressure combustor. The NOx emission indices from these experiments are normalized by the flame residence time to ascertain the effects of global flame strain and fuel Lewis Number on the NOx emissions. In addition dilute hydrogen diffusion flame experiments were performed in a high-pressure combustor at 2 4 and 8 atm. The NOx emission data from these experiments are discussed as well as the results from a Computational Fluid Dynamics modeling effort currently underway to help explain the experimental data.

Weiland, N.T.; Strakey, P.A.

2007-03-01T23:59:59.000Z

318

Energy Basics: Ultra-Low Sulfur Diesel Fuel  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

EERE: Energy Basics Ultra-Low Sulfur Diesel Fuel Ultra-low sulfur diesel (ULSD) is diesel fuel with 15 parts per million or lower sulfur content. The U.S. Environmental Protection...

319

Low Quality Natural Gas Sulfur Removal and Recovery CNG Claus Sulfur Recovery Process  

Science Conference Proceedings (OSTI)

Increased use of natural gas (methane) in the domestic energy market will force the development of large non-producing gas reserves now considered to be low quality. Large reserves of low quality natural gas (LQNG) contaminated with hydrogen sulfide (H{sub 2}S), carbon dioxide (CO{sub 2}) and nitrogen (N) are available but not suitable for treatment using current conventional gas treating methods due to economic and environmental constraints. A group of three technologies have been integrated to allow for processing of these LQNG reserves; the Controlled Freeze Zone (CFZ) process for hydrocarbon / acid gas separation; the Triple Point Crystallizer (TPC) process for H{sub 2}S / C0{sub 2} separation and the CNG Claus process for recovery of elemental sulfur from H{sub 2}S. The combined CFZ/TPC/CNG Claus group of processes is one program aimed at developing an alternative gas treating technology which is both economically and environmentally suitable for developing these low quality natural gas reserves. The CFZ/TPC/CNG Claus process is capable of treating low quality natural gas containing >10% C0{sub 2} and measurable levels of H{sub 2}S and N{sub 2} to pipeline specifications. The integrated CFZ / CNG Claus Process or the stand-alone CNG Claus Process has a number of attractive features for treating LQNG. The processes are capable of treating raw gas with a variety of trace contaminant components. The processes can also accommodate large changes in raw gas composition and flow rates. The combined processes are capable of achieving virtually undetectable levels of H{sub 2}S and significantly less than 2% CO in the product methane. The separation processes operate at pressure and deliver a high pressure (ca. 100 psia) acid gas (H{sub 2}S) stream for processing in the CNG Claus unit. This allows for substantial reductions in plant vessel size as compared to conventional Claus / Tail gas treating technologies. A close integration of the components of the CNG Claus process also allow for use of the methane/H{sub 2}S separation unit as a Claus tail gas treating unit by recycling the CNG Claus tail gas stream. This allows for virtually 100 percent sulfur recovery efficiency (virtually zero SO{sub 2} emissions) by recycling the sulfur laden tail gas to extinction. The use of the tail gas recycle scheme also deemphasizes the conventional requirement in Claus units to have high unit conversion efficiency and thereby make the operation much less affected by process upsets and feed gas composition changes. The development of these technologies has been ongoing for many years and both the CFZ and the TPC processes have been demonstrated at large pilot plant scales. On the other hand, prior to this project, the CNG Claus process had not been proven at any scale. Therefore, the primary objective of this portion of the program was to design, build and operate a pilot scale CNG Claus unit and demonstrate the required fundamental reaction chemistry and also demonstrate the viability of a reasonably sized working unit.

Klint, V.W.; Dale, P.R.; Stephenson, C.

1997-10-01T23:59:59.000Z

320

Assessment of Impacts of Retrofit NOx Controls on Gas/Oil Boilers  

Science Conference Proceedings (OSTI)

In 1997, when EPRI issued the version 2 of its Retrofit NOx Control Guidelines for Gas- and Oil-Fired Boilers (EPRI report TR-108181), it was thought the most common NOx controls installed on gas and oil-fired boilers would include low NOx burners; selective catalytic reduction (SCR); and other vendor supplied, hardware-intensive approaches. In the years that followed, however, most of the gas and oil power generating fleet opted for less hardware intensive, more cost-effective approaches, with Induced F...

2007-02-07T23:59:59.000Z

Note: This page contains sample records for the topic "nox sulfur dioxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Development of METHANE de-NOX reburning process. Quarterly report, October 1 - December 31, 1999  

DOE Green Energy (OSTI)

The use of biomass and wood waste solids and sludges as fuel is often hampered by their low heating values and the presence of bound nitrogen that result in inefficient combustion and high NOx emission. Cofiring supplemental fuel through auxiliary burners helps with improving the combustion effectiveness and NOx reduction, but the benefits are limited to the fractional heat input of the auxiliary fuel. Demonstration tests have shown over 60% reduction in NOx, CO and VOC emissions, and a 2% increase in boiler thermal efficiency using only 8 to 13% natural gas.

NONE

1999-12-31T23:59:59.000Z

322

Impacts of Low-NOx Regulations on Chillers: Commercial Cooling Update, Issue 15, September 1996  

Science Conference Proceedings (OSTI)

The 1990 Clean Air Act Amendments and local air quality rules are affecting the cost and operation of all chillers. This document takes a close look at the cost and source energy use impacts of NOx regulations on chillers and provides a summary of findings. Four chiller types are examined: electric centrifugal, direct- fired absorber, engine driven with a lean-burn engine and engine driven by nonselective catalytic reduction. A table is provided that compares energy use, NOx, and first costs of low-NOx c...

1996-10-30T23:59:59.000Z

323

The evolution of NOx control policy for coal-fired power plants in the United States  

Science Conference Proceedings (OSTI)

Emissions of nitrogen oxides (NOx) contribute to formation of particulate matter and ozone, and also to acidification of the environment. The electricity sector is responsible for about 20% of NOx emissions in the United States, and the sector has been the target of both prescriptive (command-and-control) and flexible (cap-and-trade) approaches to regulation. The paper summarises the major NOx control policies affecting this sector in the USA, and provides some perspectives as to their effectiveness. While both prescriptive and flexible approaches continue to play an important role, significant new proposals have wholly embraced a cap-and-trade approach. 20 refs., 7 figs., 2 tabs.

Dallas Burtraw; David A. Evans

2003-12-15T23:59:59.000Z

324

Sulfur-Iodine thermochemical cycle for hydrogen production.  

E-Print Network (OSTI)

??The aim of the thesis was to study the Sulfur-Iodine thermochemical cycle for hydrogen production. There were three reactions in this cycle: Bunsen reaction, sulfuric… (more)

Dan, Huang

2009-01-01T23:59:59.000Z

325

Method of removal of sulfur from coal and petroleum products  

DOE Patents (OSTI)

A method for the removal of sulfur from sulfur-bearing materials such as coal and petroleum products using organophosphine and organophosphite compounds is provided.

Verkade, John G. (Ames, IA); Mohan, Thyagarajan (Ames, IA); Angelici, Robert J. (Ames, IA)

1995-01-01T23:59:59.000Z

326

Lithium/Sulfur Batteries Based on Doped Mesoporous Carbon ...  

A sulfur/carbon composite material was prepared by heat treatment of doped mesoporous carbon and elemental sulfur at a temperature inside a stainless steel vessel ...

327

Calculating the probability of injected carbon dioxide plumes encountering faults  

E-Print Network (OSTI)

Change Special Report on Carbon Dioxide Capture and Storage,Probability of Injected Carbon Dioxide Plumes Encounteringthe probability of injected carbon dioxide encountering and

Jordan, P.D.

2013-01-01T23:59:59.000Z

328

The Greenness of Cities: Carbon Dioxide Emissions and Urban Development  

E-Print Network (OSTI)

carbon dioxide emissions index, we use conversion factors.conversion factor of pounds of carbon dioxide emitted perappropriate factors to arrive at carbon dioxide emissions.

Glaeser, Edward L.; Kahn, Matthew E.

2008-01-01T23:59:59.000Z

329

The Greenness of Cities: Carbon Dioxide Emissions and Urban Development  

E-Print Network (OSTI)

carbon dioxide emissions index, we use conversion factors.into carbon dioxide emissions, we continue to use a factorappropriate factors to arrive at carbon dioxide emissions.

Glaeser, Edward L.; Kahn, Matthew E.

2008-01-01T23:59:59.000Z

330

Definition: Reduced Sox, Nox, And Pm-2.5 Emissions | Open Energy  

Open Energy Info (EERE)

Sox, Nox, And Pm-2.5 Emissions Sox, Nox, And Pm-2.5 Emissions Jump to: navigation, search Dictionary.png Reduced Sox, Nox, And Pm-2.5 Emissions Functions that provide this benefit can lead to avoided vehicle miles, decrease the amount of central generation needed to their serve load (through reduced electricity consumption, reduced electricity losses, more optimal generation dispatch), and or reduce peak generation. These impacts translate into a reduction in pollutant emissions produced by fossil-based electricity generators and vehicles.[1] Related Terms electricity generation, reduced electricity losses, smart grid References ↑ SmartGrid.gov 'Description of Benefits' An in LikeLike UnlikeLike You like this.Sign Up to see what your friends like. line Glossary Definition Retrieved from "http://en.openei.org/w/index.php?title=Definition:Reduced_Sox,_Nox,_And_Pm-2.5_Emissions&oldid=502508

331

Modelling of catalytic aftertreatment of NOx emissions using hydrocarbon as a reductant.  

E-Print Network (OSTI)

??Hydrocarbon selective catalytic reduction (HC-SCR) is emerging as one of the most practical methods for the removal of nitrogen oxides (NOx) from light-duty-diesel engine exhaust… (more)

Sawatmongkhon, Boonlue

2012-01-01T23:59:59.000Z

332

LBNL's Low-NOx Combustion Technologies for Heat and Power Generation  

NLE Websites -- All DOE Office Websites (Extended Search)

Us Department Contacts Media Contacts LBNL's Low-NOx Combustion Technologies for Heat and Power Generation Speaker(s): Robert Cheng Date: February 2, 1999 - 12:00pm Location: Bldg....

333

Demonstration of a Low-NOx Heavy-Duty Natural Gas Engine  

DOE Green Energy (OSTI)

Results of a Next Generation Natural Gas Vehicle engine research project: A Caterpillar C-12 natural gas engine with Clean Air Power Dual-Fuel technology and exhaust gas recirculation demonstrated low NOx and PM emissions.

Not Available

2004-02-01T23:59:59.000Z

334

Microsoft Word - 41892_Praxair_Low NOx_Factsheet_Rev 0a_01-09...  

NLE Websites -- All DOE Office Websites (Extended Search)

Low NOx Emissions in a Fuel Flexible Gas Turbine FACT SHEET Revision 0a Jan. 9, 2004 Page 1 of 4 I. PROJECT DESCRIPTION A. Objective: The objective of this project is to design a...

335

Time and location differentiated NOX control in competitive electricity markets using cap-and-trade mechanisms  

E-Print Network (OSTI)

Due to variations in weather and atmospheric chemistry, the timing and location of nitrogen oxide (NOX) reductions determine their effectiveness in reducing ground-level ozone, which adversely impacts human health. Electric ...

Martin, Katherine C.

2007-01-01T23:59:59.000Z

336

Climate Co-benefits of Tighter SO2 and NOx Regulations in China  

E-Print Network (OSTI)

Air pollution has been recognized as a significant problem in China. In its Twelfth Five Year Plan (FYP), China proposes to reduce SO2 and NOx emissions significantly, and here we investigate the cost of achieving those ...

Nam, Kyung-Min

2012-10-01T23:59:59.000Z

337

Program on Technology Innovation: Field Evaluations of Entrained Flow NOx Catalyst Concept  

Science Conference Proceedings (OSTI)

EPRI has been actively evaluating and developing advanced catalyst concepts for NOx reduction that are more effective and have potential in achieving near zero emissions. The concept called NOMERCTM involves the entrained flow of pulverized SCR catalyst for NOx reduction combined with activated carbon injection for removing mercury from the flue gas stream at coal-fired utilities. The entrained flow removal process is a novel concept and has been proven to work in a previous proof of concept test. This r...

2006-03-27T23:59:59.000Z

338

An Assessment of Alternative NOx Monitoring Technologies for Coal-Fired Boiler Applications  

Science Conference Proceedings (OSTI)

This report reviews the applicability of alternate measurement technologies to measure NOx in coal-fired boiler applications using optical techniques in general, and tunable diode laser spectroscopy in particular. Increasingly stringent regulations of NOx emission limits on this class of boilers make accurate, reliable, cost effective measurement techniques of growing importance. Existing commercial instrumentation used for CEMS applications, do not entirely satisfy industry requirements and needs for pr...

2005-12-12T23:59:59.000Z

339

Assessment of Impacts of NOx Reduction Technologies on Coal Ash Use: Volume 1: North American Perspective  

Science Conference Proceedings (OSTI)

This two-volume report provides documentation about physical and chemical effects combustion and post-combustion low-NOx technologies have on coal fly ash. U.S., European, and, to a lesser degree, Japanese experience is discussed. The report assesses the effect of low-NOx technologies on fly ash markets in a general manner. Options for beneficiating fly ash for specific markets also appear.

1997-01-04T23:59:59.000Z

340

Retrofit NOx Controls for Coal-Fired Utility Boilers - 2000 Update  

Science Conference Proceedings (OSTI)

During the last four years (1996-2000), NOx control retrofits increased significantly in response to further tightening of NOx regulations. Approximately one hundred complete burner retrofits of wall- and T-fired boilers were implemented during this period, bringing the total burner retrofits to 357. Also, 32 burner component modification BCM) projects were implemented. Other control options included combustion optimization in more than two hundred boilers, thirteen reburns, five selective non-catalytic ...

2000-12-15T23:59:59.000Z

Note: This page contains sample records for the topic "nox sulfur dioxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

NOx Reduction Study at New York Power Authority's Charles Poletti Station  

Science Conference Proceedings (OSTI)

This engineering study assessed the feasibility and economics of obtaining significant NOx reduction levels at New York Power Authoritys Charles Poletti Station through one or more of a variety of approaches. Specific NOx reduction technologies included in the assessment were: 30 Unit De-Rate Induced Flue Gas Recirculation (IFGR) IFGR +30 De-Rate Selective Non-Catalytic Reduction (SNCR) IFGR +SNCR IFGR +SNCR +30 De-Rate Selective Catalytic Reduction (SCR) A number of windbox re-powering options, ...

2006-08-01T23:59:59.000Z

342

Retrofit NOx Control Guidelines for Gas- and Oil-Fired Boilers  

Science Conference Proceedings (OSTI)

Ground-level ozone concentrations continue to exceed the federal health-based standard in many parts of the country, especially urban areas. This condition led Congress to include in the Clean Air Act Amendments of 1990 a requirement that states with nonattainment regions implement regulations to reduce NOx from all sources, including utility boilers. By providing a summary and analysis of all the available information on NOx control techniques for gas-and oil-fired boilers, this document can help utilit...

1994-01-01T23:59:59.000Z

343

Procedure to Calculate NOx Reductions Using the Emissions & Generation Resource Integrated Database (E-Grid) Spreadsheet  

E-Print Network (OSTI)

In this report a detailed description of the procedure to calculate NOx reductions from energy savings due to the 2000 IECC code implementation in single family residences using the United States Environmental Protect Agency's (USEPA's) Emissions and Generation Resource Integrated Database (E-GRID) is presented. This procedure is proposed for calculating county-wide NOx reductions in pounds per MWh for Energy Efficiency and Renewable Energy projects (EE/RE) implemented in each Power Control Area (PCA) in the ERCOT region.

Haberl, J. S.; Im, P.; Culp, C.; Yazdani, B.; Fitzpatrick, T.; Verdict, M.; Turner, W. D.

2003-01-01T23:59:59.000Z

344

Rich Reagent Injection Technology for NOx Control in Cyclone-Fired Boilers  

Science Conference Proceedings (OSTI)

This report summarizes multiple demonstration projects that have led to commercial development of the Rich Reagent Injection (RRI) technology. RRI was developed by Reaction Engineering International (REI) with funding from EPRI and U.S. DOE National Energy Technology Laboratory (DOE-NETL). Prior to RRI, most NOx reduction efforts that focused on modifying combustion to reduce NOx formation in fossil-fuel-fired boilers and furnaces involved air or fuel staging. Even with significant levels of furnace stag...

2006-11-06T23:59:59.000Z

345

The Ozone Weekend Effect in California: Evidence Supporting NOx Emission Reductions  

E-Print Network (OSTI)

Ozone is typically higher on weekends (WE) than on weekdays (WD) at many of California’s air-monitoring stations. Sometimes called the “ozone WE effect, ” this phenomenon occurs despite substantially lower estimates of WE emissions for the major ozone precursors – volatile organic compounds (VOC) and oxides of nitrogen (NOx). Compared to WD emissions, WE emissions of NOx decrease more (proportionally) than do the WE emissions of VOC. Because the WE increases in ozone coincide with the relatively large WE reductions in NOx, some conclude that regulations that would reduce NOx emissions on all days would undermine ozone attainment efforts by causing ozone to decrease more slowly (or even to increase). At this time, public discussion of the ozone WE effect has mostly reflected the viewpoint that NOx emission reductions would not help reduce ambient ozone levels. A large body of published research from this perspective has accumulated over the last 10 to 20 years. Nevertheless, the presently available scientific evidence can also lead to the conclusion that NOx emission reductions may be needed to maintain or even to expedite progress toward attainment

Lawrence C. Larsen

2003-01-01T23:59:59.000Z

346

Reaction products of chlorine dioxide  

E-Print Network (OSTI)

Concern over the presence of trihalomethanes and other chlorinated by-products in chlorinedisinfected drinking water has led to extensive investigations of treatment options for controlling these by-products. Among these treatment options is the use of an alternative disinfectant such as chlorine dioxide. Although chlorine dioxide does not react to produce trihalomethanes, considerable evidence does exist that chlorine dioxide, like chlorine, will produce other organic by-products. The literature describes chlorinated and nonchlorinated derivatives including acids, epoxides, quinones, aldehydes, disulfides, and sulfonic acids that are products of reactions carried out under conditions that are vastly different from those experienced during drinking water treatment. Evidence is beginning to emerge, however, that some by-products in these categories may be produced. Certain specific volatile aldehydes and halogenated derivatives as determined by the total organic halogen parameter are among those by-products that have been measured.

Alan A. Stevens

1982-01-01T23:59:59.000Z

347

Weyburn Carbon Dioxide Sequestration Project  

NLE Websites -- All DOE Office Websites (Extended Search)

Weyburn Carbon DioxiDe SequeStration Weyburn Carbon DioxiDe SequeStration ProjeCt Background Since September 2000, carbon dioxide (CO 2 ) has been transported from the Dakota Gasification Plant in North Dakota through a 320-km pipeline and injected into the Weyburn oilfield in Saskatchewan, Canada. The CO 2 has given the Weyburn field, discovered 50 years ago, a new life: 155 million gross barrels of incremental oil are slated to be recovered by 2035 and the field is projected to be able to store 30 million tonnes of CO 2 over 30 years. CO 2 injection began in October of 2005 at the adjacent Midale oilfield, and an additional 45-60 million barrels of oil are expected to be recovered during 30 years of continued operation. A significant monitoring project associated with the Weyburn and Midale commercial

348

Advanced NOx Emissions Control: Control Technology - Second Generation  

NLE Websites -- All DOE Office Websites (Extended Search)

In Situ Device for Real-Time Catalyst Deactivation Measurements in Full-Scale SCR Systems In Situ Device for Real-Time Catalyst Deactivation Measurements in Full-Scale SCR Systems To support trends in the electric generating industry of moving from seasonal to year-round operation of Selective Catalytic Reduction (SCR) for control of NOx and mercury, as well as extending the time between generating unit outages, Fossil Energy Research Corporation (FERCo) is developing technology to determine SCR catalyst activity and remaining life without requiring an outage to obtain and analyze catalyst samples. FERCo intends to use SCR catalyst performance results measured with their in situ device at Alabama PowerÂ’s Plant Gorgas during the 2005 and 2006 ozone seasons, along with EPRIÂ’s CatReactTM catalyst management software, to demonstrate the value of real-time activity measurements with respect to the optimization of catalyst replacement strategy. Southern Company and the Electric Power Research Institute are co-funding the project.

349

Fundamental Study of Low NOx Combustion Fly Ash Utilization  

SciTech Connect

This study is principally concerned with characterizing the organic part of coal combustion fly ashes. High carbon fly ashes are becoming more common as by-products of low-NOx combustion technology, and there is need to learn more about this fraction of the fly ash. The project team consists of two universities, Brown and Princeton, and an electrical utility, New England Power. A sample suite of over forty fly ashes has been gathered from utilities across the United States, and includes ashes from a coals ranging in rank from bituminous to lignite. The characterizations of these ashes include standard tests (LOI, Foam Index), as well as more detailed characterizations of their surface areas, porosity, extractability and adsorption behavior. The ultimate goal is, by better characterizing the material, to enable broadening the range of applications for coal fly ash re-use beyond the current main market as a pozzolanic agent for concretes. The potential for high carbon-content fly ashes to substitute for activated carbons is receiving particular attention. The work performed to date has already revealed how very different the surfaces of different ashes produced by the same utility can be, with respect to polarity of the residual carbon. This can help explain the large variations in acceptability of these ashes as concrete additives.

E. M. Suubert; I. Kuloats; K. Smith; N. Sabanegh; R.H. Hurt; W. D. Lilly; Y. M. Gao

1997-05-01T23:59:59.000Z

350

SEPARATING PROTOACTINIUM WITH MANGANESE DIOXIDE  

DOE Patents (OSTI)

The preparation of U/sup 235/ and an improved method for isolating Pa/ sup 233/ from foreign products present in neutronirradiated thorium is described. The method comprises forming a solution of neutron-irradiated thorium together with a manganous salt, then adding potassium permanganate to precipitate the manganese as manganese dioxide whereby protoactinium is carried down with the nnanganese dioxide dissolving the precipitate, adding a soluble zirconium salt, and adding phosphate ion to precipitate zirconium phosphate whereby protoactinium is then carried down with the zirconium phosphate to effect a further concentration.

Seaborg, G.T.; Gofman, J.W.; Stoughton, R.W.

1958-04-22T23:59:59.000Z

351

Erbium diffusion in silicon dioxide  

SciTech Connect

Erbium diffusion in silicon dioxide layers prepared by magnetron sputtering, chemical vapor deposition, and thermal growth has been investigated by secondary ion mass spectrometry, and diffusion coefficients have been extracted from simulations based on Fick's second law of diffusion. Erbium diffusion in magnetron sputtered silicon dioxide from buried erbium distributions has in particular been studied, and in this case a simple Arrhenius law can describe the diffusivity with an activation energy of 5.3{+-}0.1 eV. Within a factor of two, the erbium diffusion coefficients at a given temperature are identical for all investigated matrices.

Lu Yingwei; Julsgaard, B.; Petersen, M. Christian [Department of Physics and Astronomy, Aarhus University, DK-8000 Aarhus C (Denmark); Jensen, R. V. Skougaard [Department of Physics and Nanotechnology, Aalborg University, DK-9220 Aalborg O (Denmark); Pedersen, T. Garm; Pedersen, K. [Department of Physics and Nanotechnology, Aalborg University, DK-9220 Aalborg O (Denmark); Interdisciplinary Nanoscience Center-iNANO, DK-8000 Aarhus C (Denmark); Larsen, A. Nylandsted [Department of Physics and Astronomy, Aarhus University, DK-8000 Aarhus C (Denmark); Interdisciplinary Nanoscience Center-iNANO, DK-8000 Aarhus C (Denmark)

2010-10-04T23:59:59.000Z

352

Sulfur-graphene oxide material for lithium-sulfur battery cathodes  

NLE Websites -- All DOE Office Websites (Extended Search)

Sulfur-graphene oxide material for lithium-sulfur battery cathodes Sulfur-graphene oxide material for lithium-sulfur battery cathodes Theoretical specific energy and theoretical energy density Scanning electron micrograph of the GO-S nanocomposite June 2013 Searching for a safer, less expensive alternative to today's lithium-ion batteries, scientists have turned to lithium-sulfur as a possible chemistry for next-generation batteries. Li/S batteries have several times the energy storage capacity of the best currently available rechargeable Li-ion battery, and sulfur is inexpensive and nontoxic. Current batteries using this chemistry, however, suffer from extremely short cycle life-they don't last through many charge-discharge cycles before they fail. A research team led by Elton Cairns and Yuegang Zhang has developed a new

353

OXYGEN DIFFUSION IN HYPOSTOICHIOMETRIC URANIUM DIOXIDE  

E-Print Network (OSTI)

IN HYPOSTOICHIOMETRIC URANIUM DIOXIDE Kee Chul Kim Ph.D.727-366; Figure 1. Oxygen-uranium phase-equilibrium _ystem [18]. uranium dioxide powders and 18 0 enriched carbon

Kim, Kee Chul

2010-01-01T23:59:59.000Z

354

Carbon Dioxide Information Analysis Center (CDIAC)  

NLE Websites -- All DOE Office Websites (Extended Search)

Emissions Carbon Dioxide Fossil-Fuel CO2 Emissions Carbon Dioxide Emissions from Fossil-Fuel Consumption and Cement Manufacture, (2011) Kyoto-Related Fossil-Fuel CO2 Emission...

355

Appalachian No. 1 Refinery District Sulfur Content (Weighted ...  

U.S. Energy Information Administration (EIA)

Appalachian No. 1 Refinery District Sulfur Content (Weighted Average) of Crude Oil Input to Refineries (Percent)

356

Flame Inhibition by Ferrocene, Carbon Dioxide, and ...  

Science Conference Proceedings (OSTI)

Flame Inhibition by Ferrocene, Carbon Dioxide, and Trifluoromethane Blends: Synergistic ... a straight sided schlieren image which is captured by a ...

2012-10-23T23:59:59.000Z

357

Discovery of New NOx Reduction Catalysts for CIDI Engines Using Combinatorial Techniques  

SciTech Connect

This project for the discovery of new lean reduction NOx catalysts was initiated on August 16th, 2002 and is now into its fourth year. Several materials have already been identified as NOx reduction catalysts for possible future application. NOx reduction catalysts are a critical need in the North American vehicle market since these catalysts are needed to enable both diesels and lean gasoline engines to meet the 2007-2010 emission standards. Hydrocarbon selective catalytic reduction (SCR) is a preferred technology since it requires no infrastructure changes (as may be expected for urea SCR) and most likely has the simplest engine control strategy of the three proposed NOx reduction approaches. The use of fast throughput techniques and informatics greatly enhances the possibility of discovering new NOx reduction catalysts. Using fast throughput techniques this project has already screened over 3000 new materials and evaluates hundreds of new materials a month. Evaluating such a high number of new materials puts this approach into a very different paradigm than previous discovery approaches for new NOx reduction catalysts. With so much data on materials it is necessary to use statistical techniques to identify the potential catalysts and these statistical techniques are needed to optimize compositions of the multi-component materials that are identified under the program as possible new lean NOx catalysts. Several new materials have conversions in excess of 80% at temperatures above 300 C. That is more than twice the activity of previous HC SCR materials. These materials are candidates for emission control on heavy-duty systems (i.e.; over 8500 pounds gross weight). Tests of one of the downselected materials on an engine dynamometer show NOx reductions greater than 80% under some conditions even though the net NOx reductions on the HWFET and the US06 cycles were relatively low. The program is scheduled to continue until the end of the 2006 calendar year. Work in the final year will focus on continued discovery and identity of candidate materials, and also on refining the engine operating strategies to increase NOx reduction over a full engine cycle.

Blint, Richard J

2005-08-15T23:59:59.000Z

358

Sulfur Resistant Electrodes for Zirconia Oxygen Sensors ...  

Prototype - A zirconia O2 sensor with a Tb-YSZ electrode was tested in a high sulfur coal fired power plant side by side with a normal zirconia O2 ...

359

Process for removing sulfur from coal  

DOE Patents (OSTI)

A process is disclosed for the removal of divalent organic and inorganic sulfur compounds from coal and other carbonaceous material. A slurry of pulverized carbonaceous material is contacted with an electrophilic oxidant which selectively oxidizes the divalent organic and inorganic compounds to trivalent and tetravalent compounds. The carbonaceous material is then contacted with a molten caustic which dissolves the oxidized sulfur compounds away from the hydrocarbon matrix.

Aida, T.; Squires, T.G.; Venier, C.G.

1983-08-11T23:59:59.000Z

360

Selective NOx Recirculation for Stationary Lean-Burn Natural Gas Engines  

Science Conference Proceedings (OSTI)

Selective NOx Recirculation (SNR) involves cooling the engine exhaust gas and then adsorbing the oxides of nitrogen (NOx) from the exhaust stream, followed by the periodic desorption of NOx. By returning the desorbed, concentrated NOx into the engine intake and through the combustion chamber, a percentage of the NOx is decomposed during the combustion process. An initial study of NOx decomposition during lean-burn combustion was concluded in 2004 using a 1993 Cummins L10G 240hp natural gas engine. It was observed that the air/fuel ratio, injected NO (nitric oxide) quantity and engine operating points affected NOx decomposition rates of the engine. Chemical kinetic modeling results were also used to determine optimum NOx decomposition operating points and were published in the 2004 annual report. A NOx decomposition rate of 27% was measured from this engine under lean-burn conditions while the software model predicted between 35-42% NOx decomposition for similar conditions. A later technology 1998 Cummins L10G 280hp natural gas engine was procured with the assistance of Cummins Inc. to replace the previous engine used for 2005 experimental research. The new engine was equipped with an electronic fuel management system with closed-loop control that provided a more stable air/fuel ratio control and improved the repeatability of the tests. The engine was instrumented with an in-cylinder pressure measurement system and electronic controls, and was adapted to operate over a range of air/fuel ratios. The engine was connected to a newly commissioned 300hp alternating current (AC) motoring dynamometer. The second experimental campaign was performed to acquire both stoichiometric and slightly rich (0.97 lambda ratio) burn NOx decomposition rates. Effects of engine load and speed on decomposition were quantified, but Exhaust Gas Recirculation (EGR) was not varied independently. Decomposition rates of up to 92% were demonstrated. Following recommendations at the 2004 ARES peer review meeting at Argonne National Laboratories, in-cylinder pressure was measured to calculate engine indicated mean effective pressure (IMEP) changes due to NOx injections and EGR variations, and to observe conditions in the cylinder. The third experimental campaign gathered NOx decomposition data at 800, 1200 and 1800 rpm. EGR was added via an external loop, with EGR ranging from zero to the point of misfire. The air/fuel ratio was set at both stoichiometric and slightly rich conditions, and NOx decomposition rates were calculated for each set of runs. Modifications were made to the engine exhaust manifold to record individual exhaust temperatures. The three experimental campaigns have provided the data needed for a comprehensive model of NOx decomposition during the combustion process, and data have confirmed that there was no significant impact of injected NO on in-cylinder pressure. The NOx adsorption system provided by Sorbent Technologies Corp. (Twinsburg, OH), comprised a NOx adsorber, heat exchanger and a demister. These components were connected to the engine, and data were gathered to show both the adsorption of NOx from the engine, and desorption of NOx from the carbon-based sorbent material back into the engine intake, using a heated air stream. In order to quantify the NOx adsorption/desorption characteristics of the sorbent material, a bench top adsorption system was constructed and instrumented with thermocouples and the system output was fed into a NOx analyzer. The temperature of this apparatus was controlled while gathering data on the characteristics of the sorbent material. These data were required for development of a system model. Preliminary data were gathered in 2005, and will continue in early 2006. To assess the economic benefits of the proposed SNR technology the WVU research team has been joined in the last quarter by Dr Richard Turton (WVU-Chemical Engineering), who is modeling, sizing and costing the major components. The tasks will address modeling and preliminary design of the heat exchanger, demister and NOx sorbent chamber s

Nigel Clark; Gregory Thompson; Richard Atkinson; Richard Turton; Chamila Tissera; Emre Tatli; Andy Zimmerman

2005-12-28T23:59:59.000Z

Note: This page contains sample records for the topic "nox sulfur dioxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Method for dissolving plutonium dioxide  

DOE Patents (OSTI)

The fluoride-catalyzed, non-oxidative dissolution of plutonium dioxide in HNO.sub.3 is significantly enhanced in rate by oxidizing dissolved plutonium ions. It is believed that the oxidation of dissolved plutonium releases fluoride ions from a soluble plutonium-fluoride complex for further catalytic action.

Tallent, Othar K. (Oak Ridge, TN)

1978-01-01T23:59:59.000Z

362

Low-quality natural gas sulfur removal/recovery: Task 2. Topical report, September 30, 1992--August 29, 1993  

Science Conference Proceedings (OSTI)

The primary purpose of this Task 2 Report is to present conceptual designs developed to treat a large portion of proven domestic natural gas reserves which are low quality. The conceptual designs separate hydrogen sulfide and large amounts of carbon dioxide (>20%) from methane, convert hydrogen sulfide to elemental sulfur, produce a substantial portion of the carbon dioxide as EOR or food grade CO{sub 2}, and vent residual CO{sub 2} virtually free of contaminating sulfur containing compounds. A secondary purpose of this Task 2 Report is to review existing gas treatment technology and identify existing commercial technologies currently used to treat large volumes of low quality natural gas with high acid content. Section II of this report defines low quality gas and describes the motivation for seeking technology to develop low quality gas reserves. The target low quality gas to be treated with the proposed technology is identified, and barriers to the production of this gas are reviewed. Section III provides a description of the Controlled Freeze Zone (CFG)-CNG technologies, their features, and perceived advantages. The three conceptual process designs prepared under Task 2 are presented in Section IV along with the design basis and process economics. Section V presents an overview of existing gas treatment technologies, organized into acid gas removal technology and sulfur recovery technology.

Cook, W.J.; Neyman, M.; Brown, W. [Acrion Technologies, Inc., Cleveland, OH (United States); Klint, B.W.; Kuehn, L.; O`Connell, J.; Paskall, H.; Dale, P. [Bovar, Inc., Calgary, Alberta (Canada)

1993-08-01T23:59:59.000Z

363

KINETICS OF DIRECT OXIDATION OF H2S IN COAL GAS TO ELEMENTAL SULFUR  

DOE Green Energy (OSTI)

The direct oxidation of H{sub 2}S to elemental sulfur in the presence of SO{sub 2} is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. This direct oxidation process has the potential to produce a super clean coal gas more economically than both conventional amine-based processes and the hot-gas desulfurization using regenerable metal oxide sorbents followed by Direct Sulfur Recovery Process. The objective of this research is to support the near- and long-term process development efforts to commercialize this direct oxidation technology. The objectives of this research are to measure kinetics of direct oxidation of H{sub 2}S to elemental sulfur in the presence of a simulated coal gas mixture containing SO{sub 2}, H{sub 2}, and moisture, using 160-{micro}m C-500-04 alumina catalyst particles and a micro bubble reactor, and to develop kinetic rate equations and model the direct oxidation process to assist in the design of large-scale plants. This heterogeneous catalytic reaction has gaseous reactants such as H{sub 2}S and SO{sub 2}. However, this heterogeneous catalytic reaction has heterogeneous products such as liquid elemental sulfur and steam. To achieve the above-mentioned objectives, experiments on conversion of hydrogen sulfide into liquid elemental sulfur were carried out for the space time range of 1-6 milliseconds at 125-155 C to evaluate effects of reaction temperature, moisture concentration, reaction pressure on conversion of hydrogen sulfide into liquid elemental sulfur. Simulated coal gas mixtures consist of 70 v% hydrogen, 2,500-7,500-ppmv hydrogen sulfide, 1,250-3,750 ppmv sulfur dioxide, and 0-15 vol% moisture, and nitrogen as remainder. Volumetric feed rates of a simulated coal gas mixture to a micro bubble reactor are 100 cm{sup 3}/min at room temperature and atmospheric pressure. The temperature of the reactor is controlled in an oven at 125-155 C. The pressure of the reactor is maintained at 40-170 psia.

K.C. Kwon

2004-01-01T23:59:59.000Z

364

KINETICS OF DIRECT OXIDATION OF H2S IN COAL GAS TO ELEMENTAL SULFUR  

DOE Green Energy (OSTI)

The direct oxidation of H{sub 2}S to elemental sulfur in the presence of SO{sub 2} is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. This direct oxidation process has the potential to produce a super clean coal gas more economically than both conventional amine-based processes and the hot-gas desulfurization using regenerable metal oxide sorbents followed by Direct Sulfur Recovery Process. The objective of this research is to support the near- and long-term process development efforts to commercialize this direct oxidation technology. The objectives of this research are to measure kinetics of direct oxidation of H{sub 2}S to elemental sulfur in the presence of a simulated coal gas mixture containing SO{sub 2}, H{sub 2}, and moisture, using 160-{micro}m C-500-04 alumina catalyst particles and a micro bubble reactor, and to develop kinetic rate equations and model the direct oxidation process to assist in the design of large-scale plants. This heterogeneous catalytic reaction has gaseous reactants such as H{sub 2}S and SO{sub 2}. However, this heterogeneous catalytic reaction has heterogeneous products such as liquid elemental sulfur and steam. To achieve the above-mentioned objectives, experiments on conversion of hydrogen sulfide into liquid elemental sulfur were carried out for the space time range of 0.059-0.87 seconds at 125-155 C to evaluate effects of reaction temperature, H{sub 2}S concentration, reaction pressure, and catalyst loading on conversion of hydrogen sulfide into liquid elemental sulfur. Simulated coal gas mixtures consist of 62-78 v% hydrogen, 3,000-7,000-ppmv hydrogen sulfide, 1,500-3,500 ppmv sulfur dioxide, and 10 vol % moisture, and nitrogen as remainder. Volumetric feed rates of a simulated coal gas mixture to a micro bubble reactor are 50 cm{sup 3}/min at room temperature and atmospheric pressure. The temperature of the reactor is controlled in an oven at 125-155 C. The pressure of the reactor is maintained at 40-170 psia. The molar ratio of H{sub 2}S to SO{sub 2} in the bubble reactor is maintained at 2 for all the reaction experiment runs.

K.C. Kwon

2005-01-01T23:59:59.000Z

365

Cyclone Boiler Field Testing of Advanced Layered NOx Control Technology in Sioux Unit 1  

SciTech Connect

A four week testing program was completed during this project to assess the ability of the combination of deep staging, Rich Reagent Injection (RRI), and Selective Non-Catalytic Reduction (SNCR) to reduce NOx emissions below 0.15 lb/MBtu in a cyclone fired boiler. The host site for the tests was AmerenUE's Sioux Unit 1, a 500 MW cyclone fired boiler located near St. Louis, MO. Reaction Engineering International (REI) led the project team including AmerenUE, FuelTech Inc., and the Electric Power Research Institute (EPRI). This layered approach to NOx reduction is termed the Advanced Layered Technology Approach (ALTA). Installed RRI and SNCR port locations were guided by computational fluid dynamics (CFD) based modeling conducted by REI. During the parametric testing, NOx emissions of 0.12 lb/MBtu were achieved consistently from overfire air (OFA)-only baseline NOx emissions of 0.25 lb/MBtu or less, when firing the typical 80/20 fuel blend of Powder River Basin (PRB) and Illinois No.6 coals. From OFA-only baseline levels of 0.20 lb/MBtu, NOx emissions of 0.12 lb/MBtu were also achieved, but at significantly reduced urea flow rates. Under the deeply staged conditions that were tested, RRI performance was observed to degrade as higher blends of Illinois No.6 were used. NOx emissions achieved with ALTA while firing a 60/40 blend were approximately 0.15 lb/MBtu. NOx emissions while firing 100% Illinois No.6 were approximately 0.165 lb/MBtu. Based on the performance results of these tests, economics analyses of the application of ALTA to a nominal 500 MW cyclone unit show that the levelized cost to achieve 0.15 lb/MBtu is well below 75% of the cost of a state of the art SCR.

Marc A. Cremer; Bradley R. Adams

2006-06-30T23:59:59.000Z

366

Reducing Emissions of Sulfur Dioxide, Nitrogen Oxides, and Mercury from Electric Power Plants  

Reports and Publications (EIA)

This analysis responds to a request from Senators Bob Smith, George Voinovich, and Sam Brownback to examine the costs of specific multi-emission reduction strategies

J. Alan Beamon

2001-10-01T23:59:59.000Z

367

Modeling the Dry Deposition Velocity of Sulfur Dioxide and Sulfate in Asia  

Science Conference Proceedings (OSTI)

The dry deposition model was created to estimate SO2 and sulfate dry deposition velocities over nine land use types in Asia. The study domain is 20°S–50°N, 39°–154°E. Monthly averaged 1° × 1° dry deposition velocities are estimated for four ...

Yiwen Xu; Gregory R. Carmichael

1998-10-01T23:59:59.000Z

368

Regenerable process for the selective removal of sulfur dioxide from effluent gases  

SciTech Connect

A regenerable process is claimed for scrubbing SO/sub 2/ from effluent gases using an aqueous alkanolamine and the corresponding sulfite as the solvent, such amine having a boiling point below about 250/sup 0/ C. At one atmosphere pressure and wherein the alkanolamine solutions containing heat stable salts (Hss) is regenerated by alkali addition, crystallization and vacuum distillation of the amine.

Atwood, G.R.; Kosseim, A.J.; Sokolik, J.E.

1983-06-21T23:59:59.000Z

369

Study of Trona (Sodium Sesquicarbonate) Reactivity with Sulfur Dioxide in a Simulated Flue Gas.  

E-Print Network (OSTI)

??Dry injection of sodium-based sorbents has gained a lot of attention in the last few years. With Dry injection, it is possible to achieve almost… (more)

Srinivasn, Rangesh

2004-01-01T23:59:59.000Z

370

Effects of the reaction cavity on metastable optical excitation in ruthenium-sulfur dioxide complexes  

SciTech Connect

We report photoexcited-state crystal structures for two new members of the [Ru(SO{sub 2})(NH{sub 3}){sub 4}X]Y family: 1:X=H{sub 2}O, Y=({+-})-camphorsulfonate{sub 2}; 2:X=isonicotinamide, Y=tosylate{sub 2}. The excited states are metastable at 100 K, with a photoconversion fraction of 11.1(7)% achieved in 1, and 22.1(10)% and 26.9(10)% at the two distinct sites in 2. We further show using solid-state density-functional-theory calculations that the excited-state geometries achieved are strongly influenced by the local crystal environment. This result is relevant to attempts to rationally design related photoexcitation systems for optical data-storage applications.

Phillips, Anthony E.; D'Almeida, Thierry; Low, Kian Sing [Department of Physics, Cavendish Laboratory, University of Cambridge, J J Thomson Avenue, Cambridge CB3 0HE (United Kingdom); Cole, Jacqueline M. [Department of Physics, Cavendish Laboratory, University of Cambridge, J J Thomson Avenue, Cambridge CB3 0HE (United Kingdom); Department of Chemistry, University of New Brunswick, P.O. Box 4400, Fredericton, New Brunswick, E3B5A3 (Canada); Department of Physics, University of New Brunswick, P.O. Box 4400, Fredericton, New Brunswick, E3B5A3 (Canada)

2010-10-15T23:59:59.000Z

371

FISCAL YEAR 2006 REPORT ON ELECTROLYZER COMPONENT DEVELOPMENT FOR THE HYBRID SULFUR PROJECT  

DOE Green Energy (OSTI)

Thermochemical processes are being developed to provide global-scale quantities of hydrogen. A variant on sulfur-based thermochemical cycles is the Hybrid Sulfur (HyS) Process which uses a sulfur dioxide depolarized electrolyzer (SDE) to produce the hydrogen. In FY05, testing at the Savannah River National Laboratory (SRNL) explored a low temperature fuel cell design concept for the SDE. The advantages of this design concept include high electrochemical efficiency and small volumetric footprint that is crucial for successful implementation on a commercial scale. A key component of the SDE is the ion conductive membrane through which protons produced at anode migrate to the cathode and react to produce hydrogen. An ideal membrane for the SDE should have both low ionic resistivity and low sulfur dioxide transport. These features allow the electrolyzer to perform at high currents with low potentials, along with preventing contamination of both the hydrogen output and poisoning of the catalysts involved. Another key component is the electrocatalyst material used for the anode and cathode. Good electrocatalysts should be chemically stable and low overpotential for the desired electrochemical reactions. This report summarizes results from activities to evaluate different membrane and electrocatalyst materials for the SDE. Several different types of commercially-available membranes were analyzed for ionic resistance and sulfur dioxide transport including perfluorinated sulfonic acid, sulfonated poly-etherketone-ketone, and poly-benzimidazole membranes. Of these membrane types, the poly-benzimidazole (PBI) membrane, Celtec-L, exhibited the best combination of characteristics for use in an SDE. Testing examined the activity and stability of platinum and palladium as electrocatalyst for the SDE in sulfuric acid solutions. Cyclic and linear sweep voltammetry revealed that platinum provided better catalytic activity with much lower potentials and higher currents than palladium. Testing also showed that the catalyst activity is strongly influenced by concentration of the sulfuric acid. Various cell configurations were examined with respect to the deposition of electrocatalyst and use of conductive carbon materials such as carbon cloth and carbon paper. Findings from these evaluations and the results of the membrane and electrocatalyst testing, we prepared three different membrane electrode assemblies (MEA) for electrolyzer testing. The first MEA consisted of a Nafion{reg_sign} membrane with platinum electrocatalyst deposited on carbon cloths, which were heat pressed onto the membrane, an assembly identical to those used in proton exchange membrane fuel cells. The second MEA also used a Nafion membrane with the electrocatalysts deposited directly onto the membrane. The third MEA proved similar to the second but utilized a PBI membrane in place of the Nafion{reg_sign} membrane. Tailor of the membrane and catalysts properties for the SDE system was concluded as a required step for the technology to move forward. It was also recommended the evaluation of the tested and new developed materials at conditions closer to the SDE operating conditions and for longer period of time.

Colon-Mercado, H; David Hobbs, D; Daryl Coleman, D; Amy Ekechukwu, A

2006-08-03T23:59:59.000Z

372

Low-quality natural gas sulfur removal/recovery  

Science Conference Proceedings (OSTI)

Low quality natural gas processing with the integrated CFZ/CNG Claus process is feasible for low quality natural gas containing 10% or more of CO{sub 2}, and any amount of H{sub 2}S. The CNG Claus process requires a minimum CO{sub 2} partial pressure in the feed gas of about 100 psia (15% CO{sub 2} for a 700 psia feed gas) and also can handle any amount of H{sub 2}S. The process is well suited for handling a variety of trace contaminants usually associated with low quality natural gas and Claus sulfur recovery. The integrated process can produce high pressure carbon dioxide at purities required by end use markets, including food grade CO{sub 2}. The ability to economically co-produce high pressure CO{sub 2} as a commodity with significant revenue potential frees process economic viability from total reliance on pipeline gas, and extends the range of process applicability to low quality gases with relatively low methane content. Gases with high acid gas content and high CO{sub 2} to H{sub 2}S ratios can be economically processed by the CFZ/CNG Claus and CNG Claus processes. The large energy requirements for regeneration make chemical solvent processing prohibitive. The cost of Selexol physical solvent processing of the LaBarge gas is significantly greater than the CNG/CNG Claus and CNG Claus processes.

Damon, D.A. [CNG Research Co., Pittsburgh, PA (United States); Siwajek, L.A. [Acrion Technologies, Inc., Cleveland, OH (United States); Klint, B.W. [BOVAR Inc., AB (Canada). Western Research

1993-12-31T23:59:59.000Z

373

NOx Control Options and Integration for US Coal Fired Boilers  

SciTech Connect

This is the sixteenth Quarterly Technical Report for DOE Cooperative Agreement No: DEFC26-00NT40753. The goal of the project is to develop cost effective analysis tools and techniques for demonstrating and evaluating low NOx control strategies and their possible impact on boiler performance for boilers firing US coals. The Electric Power Research Institute (EPRI) is providing co-funding for this program. During an unplanned outage, damage occurred to the electrochemical noise corrosion probes installed at the AEP Gavin plant; testing is expected to resume in August. The KEMCOP corrosion coupons were not affected by the unplanned outage; the coupons were removed and sent for analysis. BYU conducted a series of tests before the ISSR lab was relocated. Ammonia adsorption experiments provided clear evidence of the types of acidic sites present on catalyst surfaces. Data collected this quarter indicate that surface sulfation decreases Lewis acid site concentrations for all catalysts thus far studied, confirming that catalytic activity under commercial coal-based SCR conditions occurs primarily on Br{o}nsted acid sites and would be susceptible to basic impurities such as alkali and alkaline earth oxides, chlorides, and sulfates. SCR activity tests based on MS analysis showed that increasing sulfation generally increases NO reduction activity for both 0% and 1% vanadia catalysts. During this quarter, the slipstream reactor at Rockport operated for 720 hours on flue gas. Catalyst exposure time reached 4500 hours since installation. The reactor is out of service at the Rockport plant and plans are being made to move it to the Gadsden Plant. At Gadsden, modifications have begun in preparation for installation of the slipstream reactor next quarter.

Mike Bockelie; Kevin Davis; Temi Linjewile; Connie Senior; Eric Eddings; Kevin Whitty; Larry Baxter; Calvin Bartholomew; William Hecker; Stan Harding

2004-06-30T23:59:59.000Z

374

Controlling diesel NOx & PM emissions using fuel components and enhanced aftertreatment techniques: developing the next generation emission control system.  

E-Print Network (OSTI)

??The following research thesis focuses on methods of controlling nitrogen oxides (NO(X)) and particulate matter (PM) emissions emitted from a low temperature diesel exhaust. This… (more)

Gill, Simaranjit Singh

2012-01-01T23:59:59.000Z

375

Carbon dioxide for enhanced oil recovery  

SciTech Connect

The current status and outlook for carbon dioxide in the immediate future has been examined by Kenneth M. Stern of Chem Systems Inc. Stern. Most of the tonnage carbon dioxide being used for EOR comes from natural gas wells. Major projects are now in progress to develop natural carbon dioxide sources and to transport the gas via pipeline to the injection region. These projects and the maximum permissible cost of carbon dioxide at current petroleum prices are discussed. Potential sources include exhaust gases from power plants, natural gas processing plants, chemical plants, and natural carbon dioxide wells.

Not Available

1986-04-28T23:59:59.000Z

376

Kinetics and mechanism of the reduction of sulphur dioxide in non-aqueous media  

Science Conference Proceedings (OSTI)

The electroreduction of sulfur dioxide has been studied using three solvents and six supporting electrolytes. Electrochemical and spectroscopic measurements indicate that several follow-on reactions occur after the initial electron transfer step. The results are interpreted in terms of equilibria between SO/sub 2/, SO/sub 2//sup -/, S/sub 2/O/sub 4//sup -/ and S/sub 2/O/sub 4//sup 2-/. It has been found that both the solvent and supporting electrolyte have a strong influence on the distribution of products. These results indicate that ion-pairing plays an important role in determining the course of the reduction process. 11 refs.

Gardner, C.L.; Fouchard, D.T.; Laman, F.C.; Fawcett, W.R.

1980-01-01T23:59:59.000Z

377

Parallel, high-resolution carbon and sulfur isotope records of the evolving Paleozoic marine sulfur reservoir  

E-Print Network (OSTI)

. Carbonate rocks record the inorganic carbon isotope composition of the oceanic reservoir through geologicalParallel, high-resolution carbon and sulfur isotope records of the evolving Paleozoic marine sulfur, University of California-Riverside, Riverside California 92521-0423, USA b Department of Geological Sciences

Saltzman, Matthew R.

378

Synergies of PCCI-Type Combustion and Lean NOx Trap Catalysis for Diesel Engines  

Science Conference Proceedings (OSTI)

It is widely recognized that future NOx and PM emission targets for diesel engines cannot be met solely via advanced combustion over the full engine drive cycle. Therefore some combination of advanced combustion methodology with an aftertreatment technology will be required. In this study, NOx reduction, fuel efficiency, and regeneration performance of lean NOx trap (LNT) were evaluated for four operating conditions. The combustion approaches included baseline engine operation with and without EGR, two exhaust enrichment methods (post injection and delayed injection), and one advanced combustion mode to enable high efficiency clean combustion (HECC). A 1.7 liter 4-cylinder diesel engine was operated under five conditions, which represent key interest points for light-duty diesel operation. At the low load setting the exhaust temperature was too low to enable LNT regeneration and oxidation; however, HECC (low NOx) was achievable. HECC was also reached under more moderate loads and the exhaust temperatures were high enough to enable even further NOx reductions by the LNT. At high loads HECC becomes difficult but the LNT performance improves and acceptable regeneration can be met with enrichment methodologies.

Parks, II, James E [ORNL; Prikhodko, Vitaly Y [ORNL; Kass, Michael D [ORNL; Huff, Shean P [ORNL

2008-01-01T23:59:59.000Z

379

Feasibility of plasma aftertreatment for simultaneous control of NOx and particulates  

DOE Green Energy (OSTI)

Plasma reactors can be operated as a particulate trap or as a NOx converter. Particulate trapping in a plasma reactor can be accomplished by electrostatic precipitation. The soluble organic fraction of the trapped particulates can be utilized for the hydrocarbon-enhanced oxidation of NO to NO2 . The NO2 can then be used to non-thermally oxidize the carbon fraction of the particulates. The oxidation of the carbon fraction by NO2 can lead to reduction of NOx or backconversion of NO2 to NO. This paper examines the hydrocarbon and electrical energy density requirements in a plasma for maximum NOx conversion in both heavy-duty and light-duty diesel engine exhaust. The energy density required for complete oxidation of hydrocarbons is also examined and shown to be much greater than that required for maximum NOx conversion. The reaction of NO2 with carbon is shown to lead mainly to backconversion of NO2 to NO. These results suggest that the combination of the plasma with a catalyst will be required to reduce the NOx and oxidize the hydrocarbons. The plasma reactor can be operated occasionally in the arc mode to thermally oxidize the carbon fraction of the particulates.

Brusasco, R M; Merritt, B T; Penetrante, B; Pitz, W J; Vogtlin, G E

1999-08-24T23:59:59.000Z

380

DEVELOPMENT AND DEMONSTRATION OF NOVEL LOW-NOx BURNERS IN THE STEEL INDUSTRY  

Science Conference Proceedings (OSTI)

Gas Technology Institute (GTI), together with Hamworthy Peabody Combustion Incorporated (formerly Peabody Engineering Corporation), the University of Utah, and Far West Electrochemical have developed and demonstrated an innovative combustion system suitable for natural gas and coke-oven gas firing within the steel industry. The combustion system is a simple, low-cost, energy-efficient burner that can reduce NOx by more than 75%. The U.S. steel industry needs to address NOx control at its steelmaking facilities. A significant part of NOx emissions comes from gas-fired boilers. In steel plants, byproduct gases – blast furnace gas (BFG) and coke-oven gas (COG) – are widely used together with natural gas to fire furnaces and boilers. In steel plants, natural gas can be fired together with BFG and COG, but, typically, the addition of natural gas raises NOx emissions, which can already be high because of residual fuel-bound nitrogen in COG. The Project Team has applied its expertise in low-NOx burners to lower NOx levels for these applications by combining advanced burner geometry and combustion staging with control strategies tailored to mixtures of natural gas and byproduct fuel gases. These methods reduce all varieties of NOx – thermal NOx produced by high flame temperatures, prompt NOx produced by complex chain reactions involving radical hydrocarbon species and NOx from fuel-bound nitrogen compounds such as ammonia found in COG. The Project Team has expanded GTI’s highly successful low-NOx forced internal recirculation (FIR) burner, previously developed for natural gas-fired boilers, into facilities that utilize BFG and COG. For natural gas firing, these burners have been shown to reduce NOx emissions from typical uncontrolled levels of 80-100 vppm to single-digit levels (9 vppm). This is done without the energy efficiency penalties incurred by alternative NOx control methods, such as external flue gas recirculation (FGR), water injection, and selective non-catalytic reduction. The FIR burner was previously demonstrated on firetube and watertube boilers, and these units are still operating at several industrial and commercial boiler sites in sizes ranging from 2.5 to 60 million Btu/h. This report covers the development of an innovative combustion system suitable for natural gas or coke-oven gas firing within the steel industry. The prototype FIR burner was evaluated on a 20 million Btu/h watertube boiler. Acceptable burner performance was obtained when firing natural gas and simulated coke-oven gas doped with ammonia. The laboratory data reveals a direct relationship between NOx formation and the ammonia concentration in the fuel. In addition, NOx formation increases as the primary stoichiometric ratio (PSR) increases. Representative ammonia concentrations, as documented in the steel industry, ranged from 200 to 500 vppm. When the laboratory burner/boiler was operated with 500 vppm ammonia in the fuel, NOx emissions ranged from 50 to 75 vppm. This, conservatively, is 75% less than state-of-the-art burner performance. When the burner is operated with 200 vppm ammonia in the fuel, the corresponding NOx emissions would range from 30 to 45 vppm, 84% less than present burner technology. During field evaluation on a 174 million Btu/h industrial prototype burner both natural gas and actual COG from on-site generation were tested. Despite the elevated hydrogen cyanide and ammonia content in the COG throughout the test program, the FIR burner showed an improvement over baseline emissions. At full load; 167 million Btu/h, NOx emissions were relatively low at 169 vppm. This represents a 30% reduction compared to baseline emissions not accounting for the higher hydrogen cyanide content in the COG. CO emissions remained below 20 vppm and were stable across the firing range. This represents a 68% reduction compared to baseline CO emissions. When firing natural gas, emissions were stable as firing rate increased over the range. At low fire; 45 million Btu/h, NOx emissions where 33 vppm and increased at full load; 144 million Btu

Cygan, David

2006-12-28T23:59:59.000Z

Note: This page contains sample records for the topic "nox sulfur dioxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Reductive Sequestration of Carbon Dioxide  

NLE Websites -- All DOE Office Websites (Extended Search)

Reductive Sequestration of Carbon Dioxide Reductive Sequestration of Carbon Dioxide T. Mill (ted.mill@sri.com; 650-859-3605) SRI, PS273 333 Ravenswood Menlo Park, CA 94025 D. Ross (dsross3@yahoo.com; 650-327-3842) U.S. Geological Survey, Bldg 15 MS 999 345 Middlefield Rd. Menlo Park, CA 94025 Introduction The United States currently meets 80% of its energy needs by burning fossil fuels to form CO 2 . The combustion-based production of CO 2 has evolved into a major environmental challenge that extends beyond national borders and the issue has become as politically charged as it is technologically demanding. Whereas CO 2 levels in the atmosphere had remained stable over the 10,000 years preceeding the industrial revolution, that event initiated rapid growth in CO 2 levels over the past 150 years (Stevens, 2000). The resulting accelerating accumulation of

382

IEP - Carbon Dioxide: Regulatory Drivers  

NLE Websites -- All DOE Office Websites (Extended Search)

IEP - Carbon Dioxide (CO2) Regulatory Drivers In July 7, 2009 testimony before the U.S. Senate Committee on Environment and Public Works, Secretary of Energy Steven Chu made the following statements:1 "...Overwhelming scientific evidence shows that carbon dioxide from human activity has increased the atmospheric level of CO2 by roughly 40 percent, a level one- third higher than any time in the last 800,000 years. There is also a consensus that CO2 and other greenhouse gas emissions have caused our planet to change. Already, we have seen the loss of about half of the summer arctic polar ice cap since the 1950s, a dramatically accelerating rise in sea level, and the loss of over two thousand cubic miles of glacial ice, not on geological time scales but over a mere hundred years.

383

Capturing Carbon Dioxide From Air  

NLE Websites -- All DOE Office Websites (Extended Search)

Capturing Carbon Dioxide From Air Capturing Carbon Dioxide From Air Klaus S. Lackner (kl2010@columbia.edu; 212-854-0304) Columbia University 500 West 120th Street New York, NY 10027 Patrick Grimes (pgrimes@worldnet.att.net; 908-232-1134) Grimes Associates Scotch Plains, NJ 07076 Hans-J. Ziock (ziock@lanl.gov; 505-667-7265) Los Alamos National Laboratory P.O.Box 1663 Los Alamos, NM 87544 Abstract The goal of carbon sequestration is to take CO 2 that would otherwise accumulate in the atmosphere and put it in safe and permanent storage. Most proposed methods would capture CO 2 from concentrated sources like power plants. Indeed, on-site capture is the most sensible approach for large sources and initially offers the most cost-effective avenue to sequestration. For distributed, mobile sources like cars, on-board capture at affordable cost would not be

384

Carbon Dioxide Compression and Transportation  

Science Conference Proceedings (OSTI)

This report summarizes the state of the art regarding carbon dioxide CO2 compression and transportation in the United States and Canada. The primary focus of the report was on CO2 compression because it is a significant cost and energy penalty in carbon capture and storage CCS. The secondary focus of the report was to document the state of the art of CO2 pipeline transportation in the United States and Canada.

2008-12-23T23:59:59.000Z

385

Removal of NOx or its conversion into harmless gases by charcoals and composites of metal oxides  

SciTech Connect

In recent years, much attention has been devoted to environmental problems such as acid rain, photochemical smog and water pollution. In particular, NOx emissions from factories, auto mobiles, etc. in urban areas have become worse. To solve these problems on environmental pollution on a global scale, the use of activated charcoal to reduce air pollutants is increasing. However, the capability of wood-based charcoal materials is not yet fully known. The removal of NOx or its conversion into harmless gases such as N{sub 2} should be described. In this study, the adsorption of NO over wood charcoal or metal oxide-dispersed wood charcoal was investigated. In particular, carbonized wood powder of Sugi (Cryptomeria japonica D. Don) was used to study the effectivity of using these materials in adsorbing NOx. Since wood charcoal is chemically stable, metal oxide with the ability of photocatalysis was dispersed into wood charcoal to improve its adsorption and capability to use the light energy effectively.

Ishihara, Shigehisa; Furutsuka, Takeshi [Kyoto Univ. (Japan)

1996-12-31T23:59:59.000Z

386

Heavy-Duty Emissions Control: Plasma-Facilitated vs Reformer-Assisted Lean NOx Catalysis  

DOE Green Energy (OSTI)

Progress has been made in the control of combustion processes to limit the formation of environmentally harmful species, but lean burn vehicles, such as those powered by diesel engines used for the majority of commercial trucking and off-road applications, remain a major source of nitrogen oxides (NOx) and particulate matter (PM) emissions. Tighter control of the combustion process coupled with exhaust gas recirculation has brought emissions in line with 2004 targets worldwide. Additional modifications to the engine control system, somewhat limited NOx control, and PM filters will likely allow the 2007 limits to be met for the on-highway regulations for heavy-duty engines in the United States. Concern arises when the NOx emission limit of 0.2 g/bhphr set for the year 2010 is considered.

(1)Aardahl, C; (1)Rozmiarek, R; (1)Rappe, K; (1)Mendoza, D (2)Park, P

2003-08-24T23:59:59.000Z

387

SELECTIVE CATALYTIC REDUCTION OF DIESEL ENGINE NOX EMISSIONS USING ETHANOL AS A REDUCTANT  

DOE Green Energy (OSTI)

NOx emissions from a heavy-duty diesel engine were reduced by more than 90% and 80% utilizing a full-scale ethanol-SCR system for space velocities of 21000/h and 57000/h respectively. These results were achieved for catalyst temperatures between 360 and 400 C and for C1:NOx ratios of 4-6. The SCR process appears to rapidly convert ethanol to acetaldehyde, which subsequently slipped past the catalyst at appreciable levels at a space velocity of 57000/h. Ammonia and N2O were produced during conversion; the concentrations of each were higher for the low space velocity condition. However, the concentration of N2O did not exceed 10 ppm. In contrast to other catalyst technologies, NOx reduction appeared to be enhanced by initial catalyst aging, with the presumed mechanism being sulfate accumulation within the catalyst. A concept for utilizing ethanol (distilled from an E-diesel fuel) as the SCR reductant was demonstrated.

(1)Kass, M; Thomas, J; Lewis, S; Storey, J; Domingo, N; Graves, R (2) Panov, A

2003-08-24T23:59:59.000Z

388

Plasma-chemical conversion of hydrogen sulfide into hydrogen and sulfur  

DOE Green Energy (OSTI)

A waste-treatment process that recovers both hydrogen and sulfur from hydrogen-sulfide-contaminated industrial wastes is being developed to replace the Claus technology, which recovers only sulfur. The proposed process is based on research reported in the Soviet technical literature and uses microwave (or radio-frequency) energy to initiate plasma-chemical reactions that dissociate hydrogen sulfide into elemental hydrogen and sulfur. In the plasma-chemical process, the gaseous stream would be purified and separated into streams containing the product hydrogen, hydrogen sulfide for recycle to the plasma reactor, and the process purge containing carbon dioxide and water. Since unconverted hydrogen sulfide is recycled to the plasma reactor, the plasma-chemical process has the potential for sulfur recoveries in excess of 99% without the additional tail-gas clean-up processes associated with the Claus technology. Laboratory experiments with pure hydrogen sulfide have confirmed that conversions of over 90% per pass are possible. Experiments with impurities typical of petroleum refinery and natural gas production acid gases have demonstrated that these impurities are compatible with the plasma dissociation process and do not appear to create new waste-treatment problems. Other experiments show that the cyclonic-flow pattern hypothesized by the Russian theoretical analysis of the plasma-chemical process can substantially decrease energy requirements for hydrogen sulfide dissociation while increasing conversion. This process has several advantages over the current Claus-plus-tail-gas-cleanup technology. The primary advantage is the potential for recovering hydrogen more cheaply than the direct production of hydrogen. The difference could amount to an energy savings of 40 {times} 10{sup 15} to 70 {times} 10{sup 15} J/yr in the refining industry, for an annual savings of $500 million to $1,000 million.

Harkness, J.B.L.; Doctor, R.D.; Daniels, E.J.

1993-09-01T23:59:59.000Z

389

NOx Reduction Assessment for Tangentially Fired Boilers Burning Powder River Basin Coal  

Science Conference Proceedings (OSTI)

The objective of this project was to assess the feasibility of and the most cost-effective approaches for reducing nitrous oxide (NOx) emissions for tangentially fired boilers burning Powder River Basin (PRB) coal in order to achieve average NOx emission rates of 0.15 lb/mmBtu (110 ppm), or lower. This is typically achievable by a deep level of combustion air staging, which may be possible if operational issues experienced during low combustion air operation (for example, slagging) can be mitigated. Acc...

2010-01-20T23:59:59.000Z

390

Nitrogen Isotopic Composition of Coal-Fired Power Plant NOx: Influence of Emission Controls and Implications for Global Emission  

E-Print Network (OSTI)

Nitrogen Isotopic Composition of Coal-Fired Power Plant NOx: Influence of Emission Controls from coal-fired power plants in the U.S. at typical operating conditions with and without the presence this, a novel method for collection and isotopic analysis of coal-fired stack NOx emission samples

Elliott, Emily M.

391

Soft-Sensor Modeling on NOx Emission of Power Station Boilers Based on Least Squares Support Vector Machines  

Science Conference Proceedings (OSTI)

The online monitoring for NOx emission of coal-fired boilers in power plants is more difficult to achieve. The soft-sensor technology of artificial neural network (ANN) method that was commonly used has not strong generalization ability, but support ... Keywords: NOx emission, support vector machines, soft sensor, modeling, power station boilers

Feng Lei-hua; Gui Wei-hua; Yang Feng

2009-10-01T23:59:59.000Z

392

Sulfur isotopic evidence for controls on sulfur incorporation in peat and coal  

Science Conference Proceedings (OSTI)

Pyritic sulfur isotope [delta][sup 34]S values were used as a measure of two principal controls on sulfur incorporation in peat and coal: the availability of sulfate, and the activity of sulfate-reducing bacteria in the peat-forming mire. Relatively low [delta][sup 34]S values indicated an open system with a relatively abundant supply of sulfate that exceeded the rate of sulfate reduction to sulfide, whereas relatively high [delta][sup 34]S values indicated a closed system with a more limited supply of sulfate. For example, in the high-sulfur (>3% S), Holocene deposits of Mud Lake, Florida, pyritic sulfur [delta][sup 34]S values decreasing sharply across the transition from peat to the overlying lacustrine sapropel, which corresponds to an increased supply of sulfate from the lake waters. Likewise, syngenetic pyrite in the high-sulfur Minto coal bed (Pictou Group, Westphalian C) in New Brunswick, Canada, show up to 10% negative shifts in [delta][sup 34]S in attrital layers containing detrital quartz and illite, consistent with an increased supply of sulfate from streams entering the peat-forming mire. In contrast, positive pyritic sulfur [delta][sup 34]S values in high-sulfur, channel-fill coal beds (lower Breathitt Formation, Middle Pennsylvanian) in eastern Kentucky indicate that a steady supply of sulfate was exhausted by very active microbial sulfate reduction in the channel-fill peat.

Spiker, E.C.; Bates, A.L. (Geological Survey, Reston, VA (United States))

1993-08-01T23:59:59.000Z

393

Method of making a sodium sulfur battery  

SciTech Connect

A method of making a portion of a sodium sulfur battery is disclosed. The battery portion made is a portion of the container which defines the volume for the cathodic reactant materials which are sulfur and sodium polysulfide materials. The container portion is defined by an outer metal casing with a graphite liner contained therein, the graphite liner having a coating on its internal diameter for sealing off the porosity thereof. The steel outer container and graphite pipe are united by a method which insures that at the operating temperature of the battery, relatively low electrical resistance exists between the two materials because they are in intimate contact with one another.

Elkins, Perry E. (Santa Ana, CA)

1981-01-01T23:59:59.000Z

394

Carbon dioxide and climate: a bibliography  

SciTech Connect

This bibliography with abstracts presents 394 citations retrieved from the Energy Data Base of the Department of Energy Technical Information Center, Oak Ridge, Tennessee. The citations cover all aspects of the climatic effects of carbon dioxide emissions to the atmosphere. These include carbon cycling, temperature effects, carbon dioxide control technologies, paleoclimatology, carbon dioxide sources and sinks, mathematical models, energy policies, greenhouse effect, and the role of the oceans and terrestrial forests.

Ringe, A.C. (ed.)

1980-10-01T23:59:59.000Z

395

Multiple-sulfur isotope effects during photolysis of carbonyl sulfide  

E-Print Network (OSTI)

Laboratory experiments were carried out to determine sulfur isotope effects during ultraviolet photolysis of carbonyl sulfide (OCS) to carbon monoxide (CO) and elemental sulfur (S[superscript 0]). The OCS gas at 3.7 to 501 ...

Lin, Ying

396

Microwave assisted sulfur infusion technique and the corresponding ...  

Science Conference Proceedings (OSTI)

Abstract Scope, Li-S battery is quite attractive due to the usage of elemental sulfur as cathode. The theoretical capacity of sulfur cathode is 1672 mAh/g, which

397

ADVANCED BYPRODUCT RECOVERY: DIRECT CATALYTIC REDUCTION OF SO2 TO ELEMENTAL SULFUR  

SciTech Connect

Arthur D. Little, Inc., together with its commercialization partner, Engelhard Corporation, and its university partner Tufts, investigated a single-step process for direct, catalytic reduction of sulfur dioxide from regenerable flue gas desulfurization processes to the more valuable elemental sulfur by-product. This development built on recently demonstrated SO{sub 2}-reduction catalyst performance at Tufts University on a DOE-sponsored program and is, in principle, applicable to processing of regenerator off-gases from all regenerable SO{sub 2}-control processes. In this program, laboratory-scale catalyst optimization work at Tufts was combined with supported catalyst formulation work at Engelhard, bench-scale supported catalyst testing at Arthur D. Little and market assessments, also by Arthur D. Little. Objectives included identification and performance evaluation of a catalyst which is robust and flexible with regard to choice of reducing gas. The catalyst formulation was improved significantly over the course of this work owing to the identification of a number of underlying phenomena that tended to reduce catalyst selectivity. The most promising catalysts discovered in the bench-scale tests at Tufts were transformed into monolith-supported catalysts at Engelhard. These catalyst samples were tested at larger scale at Arthur D. Little, where the laboratory-scale results were confirmed, namely that the catalysts do effectively reduce sulfur dioxide to elemental sulfur when operated under appropriate levels of conversion and in conditions that do not contain too much water or hydrogen. Ways to overcome those limitations were suggested by the laboratory results. Nonetheless, at the end of Phase I, the catalysts did not exhibit the very stringent levels of activity or selectivity that would have permitted ready scale-up to pilot or commercial operation. Therefore, we chose not to pursue Phase II of this work which would have included further bench-scale testing, scale-up, pilot-scale (0.5 MW{sub e}) testing at conditions representative of various regenerable SO{sub 2}-control systems, preparation of a commercial process design, and development of a utility-scale demonstration plan.

Robert S. Weber

1999-05-01T23:59:59.000Z

398

Improved performance of NOx reduction by H2 and CO over a Pd/Al2O3 catalyst at low temperatures under lean-burn conditions  

E-Print Network (OSTI)

Improved performance of NOx reduction by H2 and CO over a Pd/Al2O3 catalyst at low temperatures 4 June 2004; accepted 6 June 2004 Available online 28 July 2004 Abstract Selective reduction of NOx of lean-burn vehicle exhaust. Macleod and Lambert [9] found that Pd/Al2O3 promotes lean NOx reduction

Gulari, Erdogan

399

TABLE OF CONTENTS Carbon Dioxide Reduction Metallurgy  

Science Conference Proceedings (OSTI)

Chemical Utilization of Sequestered Carbon Dioxide as a. Booster of Hydrogen ... CO2 Capture and Sequestration – Implications for the Metals. Industry.

400

Atmospheric carbon dioxide and the greenhouse effect  

SciTech Connect

This document contains a non-technical review of the problems associated with atmospheric carbon dioxide and the resulting greenhouse effect. (TEM)

Firestine, M.W. (ed.)

1989-05-01T23:59:59.000Z

Note: This page contains sample records for the topic "nox sulfur dioxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Carbon Ion Pump for Carbon Dioxide Removal  

coal fired power plants; oil or gas fired power plants; cement production; bio-fuel combustion; Separation of carbon dioxide from other combustion ...

402

Carbon Dioxide Transportation and Sequestration Act (Illinois...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

process for the issuance of a certificate of authority by an owner or operator of a pipeline designed, constructed, and operated to transport and to sequester carbon dioxide...

403

Scientists Crack Materials Mystery of Vanadium Dioxide  

Science Conference Proceedings (OSTI)

Dec 1, 2010 ... Using a condensed physics theory to explain the observed phase behaviors of vanadium dioxide, ORNL scientists have discovered that the ...

404

EIA - Greenhouse Gas Emissions - Carbon Dioxide Emissions  

U.S. Energy Information Administration (EIA)

Nonfuel uses of fossil fuels (for purposes other than their energy value) create carbon dioxide emissions and also sequester carbon in nonfuel products, ...

405

Carbon Dioxide Information Analysis Center (CDIAC)  

NLE Websites -- All DOE Office Websites (Extended Search)

available free of charge - include estimates of carbon dioxide emissions from fossil-fuel consumption and land-use changes; records of atmospheric concentrations of carbon...

406

HYBRID SULFUR ELECTROLYZER DEVELOPMENT, NHI WORK PACKAGE N-SR07TC0301, FY07 FIRST QUARTER REPORT  

DOE Green Energy (OSTI)

The proof of concept of SO2 electrolysis for the hybrid sulfur (HyS) process is the second priority research target of the DOE Nuclear Hydrogen Initiative's thermochemical program for FY07. The proof of concept of the liquid-phase option must be demonstrated at the single cell level for an extended run times (>100 hours). The rate of development of HyS will depend on the identification of a promising membrane or an alternative means for controlling sulfur formation. Once successful long-duration operation has been demonstrated, SRNL will develop a multi-cell stack that can be connected to the H2SO4 decomposer being developed by SNL for the S-I ILS for a Hybrid Sulfur Integrated Laboratory-Scale Experiment during FY 2008. During the first quarter of FY07, SRNL continued the component development and membrane development activities with the goal of identifying and characterizing improved electrodes, electrocatalysts, membranes and MEA configurations which could then be tested at larger scale in the SDE test facility. A modified glass cell was fabricated to allow measurements of sulfur dioxide (SO2) transport across membrane samples at elevated temperatures (up to 70 C). This testing also includes evaluating SO2 transport in different sulfuric acid concentrations (30-70 wt%). A new potentiostat/frequency analyzer was installed for determining ionic conductivity of membranes. This instrument enhances our capabilities to characterize membrane, electrocatalyst and MEA properties and performance. Continuing work from FY06, evaluations were preformed on various commercial and experimental membranes and electrocatalyst materials for the SDE. Several different types of commercially-available membranes were analyzed for sulfur dioxide transport as a function of acid strength including perfluorinated sulfonic acid (PFSA), sulfonated polyetherketone-ketone, and poly-benzimidazole (PBI) membranes. Experimental membranes from the sulfonated diels-alder polyphenylenes (SDAPP) and modified Nafion{reg_sign} 117 were evaluated for SO{sub 2} transport as well. These membranes exhibited reduced transport coefficient for SO{sub 2} transport without the loss in ionic conductivity.

Summers, W

2006-12-20T23:59:59.000Z

407

DEVELOPMENT OF A VALIDATED MODEL FOR USE IN MINIMIZING NOx EMISSIONS AND MAXIMIZING CARBON UTILIZATION WHEN CO-FIRING BIOMASS WITH COAL  

DOE Green Energy (OSTI)

This is the eighth Quarterly Technical Report for DOE Cooperative Agreement No. DE-FC26-00NT40895. A statement of the project objectives is included in the Introduction of this report. The final biomass co-firing test burn was conducted during this quarter. In this test (Test 14), up to 20% by weight dry switchgrass was comilled with Jim Walters No.7 mine coal and injected through the single-register burner. Jim Walters No.7 coal is a low-volatility, low-sulfur ({approx}0.7% S) Eastern bituminous coal. The results of this test are presented in this quarterly report. Progress has continued to be made in implementing a modeling approach to combine reaction times and temperature distributions from computational fluid dynamic models of the pilot-scale combustion furnace with char burnout and chemical reaction kinetics to predict NO{sub x} emissions and unburned carbon levels in the furnace exhaust. The REI Configurable Fireside Simulator (CFS) is now in regular use. Presently, the CFS is being used to generate CFD calculations for completed tests with Powder River Basin coal and low-volatility (Jim Walters No.7 Mine) coal. Niksa Energy Associates will use the results of these CFD simulations to complete their validation of the NOx/LOI predictive model. Work has started on the project final report.

Larry G. Felix; P. Vann Bush

2002-10-26T23:59:59.000Z

408

Reducing Sulfur Hexafluoride Use at LANSCE  

NLE Websites -- All DOE Office Websites (Extended Search)

U N C L A S S I F I E D U N C L A S S I F I E D Reducing Sulfur Hexafluoride Use at LANSCE Hank Alvestad presents to the Fugitive Emissions Working Group September 8, 2011...

409

Sulfuric acid thermoelectrochemical system and method  

DOE Patents (OSTI)

A thermoelectrochemical system in which an electrical current is generated between a cathode immersed in a concentrated sulfuric acid solution and an anode immersed in an aqueous buffer solution of sodium bisulfate and sodium sulfate. Reactants consumed at the electrodes during the electrochemical reaction are thermochemically regenerated and recycled to the electrodes to provide continuous operation of the system.

Ludwig, Frank A. (Rancho Palos Verdes, CA)

1989-01-01T23:59:59.000Z

410

Process for removing sulfur from sulfur-containing gases: high calcium fly-ash  

DOE Patents (OSTI)

The present disclosure relates to improved processes for treating hot sulfur-containing flue gas to remove sulfur therefrom. Processes in accordance with the present invention include preparing an aqueous slurry composed of a calcium alkali source and a source of reactive silica and/or alumina, heating the slurry to above-ambient temperatures for a period of time in order to facilitate the formation of sulfur-absorbing calcium silicates or aluminates, and treating the gas with the heat-treated slurry components. Examples disclosed herein demonstrate the utility of these processes in achieving improved sulfur-absorbing capabilities. Additionally, disclosure is provided which illustrates preferred configurations for employing the present processes both as a dry sorbent injection and for use in conjunction with a spray dryer and/or bagfilter. Retrofit application to existing systems is also addressed.

Rochelle, Gary T. (Austin, TX); Chang, John C. S. (Cary, NC)

1991-01-01T23:59:59.000Z

411

Formation of N2O and NO2 Across Conventional DeNOx SCR Catalysts  

Science Conference Proceedings (OSTI)

This project investigated the formation of N2O and NO2 across conventional DeNOx selective catalytic reduction (SCR) catalysts. N2O is a particularly strong greenhouse gas, and both N2O and NO2 may adversely impact downstream processes. Additional data related to their formation or reduction across SCR catalysts is desirable.

2009-12-15T23:59:59.000Z

412

A Numerical Investigation into the Anomalous Slight NOx Increase when Burning Biodiesel: A New (Old) Theory  

DOE Green Energy (OSTI)

Biodiesel is a notable alternative to petroleum derived diesel fuel because it comes from natural domestic sources and thus reduces dependence on diminishing petroleum fuel from foreign sources, it likely lowers lifecycle greenhouse gas emissions, and it lowers an engine's emission of most pollutants as compared to petroleum derived diesel. However, the use of biodiesel often slightly increases a diesel engine's emission of smog forming nitrogen oxides (NO{sub x}) relative to petroleum diesel. In this paper, previously proposed theories for this slight NOx increase are reviewed, including theories based on biodiesel's cetane number, which leads to differing amounts of charge preheating, and theories based on the fuel's bulk modulus, which affects injection timing. This paper proposes an additional theory for the slight NO{sub x} increase of biodiesel. Biodiesel typically contains more double bonded molecules than petroleum derived diesel. These double bonded molecules have a slightly higher adiabatic flame temperature, which leads to the increase in NOx production for biodiesel. Our theory was verified using numerical simulations to show a NOx increase, due to the double bonded molecules, that is consistent with observation. Further, the details of these numerical simulations show that NOx is predominantly due to the Zeldovich mechanism.

Ban-Weiss, G A; Chen, J Y; Buchholz, B A; Dibble, R W

2007-01-30T23:59:59.000Z

413

A Numerical Investigation into the Anomalous Slight NOx Increase when Burning Biodiesel: A New (Old) Theory  

SciTech Connect

Biodiesel is a notable alternative to petroleum derived diesel fuel because it comes from natural domestic sources and thus reduces dependence on diminishing petroleum fuel from foreign sources, it likely lowers lifecycle greenhouse gas emissions, and it lowers an engine's emission of most pollutants as compared to petroleum derived diesel. However, the use of biodiesel often slightly increases a diesel engine's emission of smog forming nitrogen oxides (NO{sub x}) relative to petroleum diesel. In this paper, previously proposed theories for this slight NOx increase are reviewed, including theories based on biodiesel's cetane number, which leads to differing amounts of charge preheating, and theories based on the fuel's bulk modulus, which affects injection timing. This paper proposes an additional theory for the slight NO{sub x} increase of biodiesel. Biodiesel typically contains more double bonded molecules than petroleum derived diesel. These double bonded molecules have a slightly higher adiabatic flame temperature, which leads to the increase in NOx production for biodiesel. Our theory was verified using numerical simulations to show a NOx increase, due to the double bonded molecules, that is consistent with observation. Further, the details of these numerical simulations show that NOx is predominantly due to the Zeldovich mechanism.

Ban-Weiss, G A; Chen, J Y; Buchholz, B A; Dibble, R W

2007-01-30T23:59:59.000Z

414

Agricultural Bio-Fueled Generation of Electricity and Development of Durable and Efficent NOx Reduction  

DOE Green Energy (OSTI)

Caterpillar Power Generation adapted an off-the-shelf Diesel Generator to run on BioDiesel and various Petroleum Diesel/BioDiesel blends. EmeraChem developed and installed an exhaust gas cleanup system to reduce NOx, SOx, volatile organics, and particulates. The system design and function was optimized for emissions reduction with results in the 90-95% range;

Boyd, Rodney

2007-08-08T23:59:59.000Z

415

Experiment Study on Adsorption Characteristics of SO2, NOx by Biomass Chars  

Science Conference Proceedings (OSTI)

Different kinds of biomass chars of the wheat straws, rice straw, cotton straw collected at Nanjing, China, were pyrolysed in a fixed bed reactor at different temperatures and heating rates. The specific area and pore structure, micromorphology of different ... Keywords: Biomass char, Pyrolysis, Adsorption efficiency, SO2, NOx

Fei Lu; Ping Lu

2010-12-01T23:59:59.000Z

416

Cyclone Boiler Reburn NOx Control Improvements via Cyclone Design Improvements and Advanced Air Staging  

E-Print Network (OSTI)

Eastman Kodak owns three Babcock & Wilcox coal fired cyclone boilers and one Combustion Engineering pulverized coal boiler located at Kodak Park in Rochester, New York. Duke Energy Generation Services (DEGS) operates and maintains the steam and electric generation equipment for Kodak and has primary responsibility for related capital project development and execution. The Kodak plant is capable of generating approximately 1,900,000 pounds of steam and 130 MW’s of electrical power. To achieve the required level of NOx control, Kodak chose The Babcock & Wilcox (B&W) Company's, Natural Gas Reburn technology for the three cyclone boilers. The relatively low capital cost of the system and reasonable cost of natural gas in the mid 1990’s made Natural Gas Reburn an economic fit for the RACT requirements of 0.60#’s/Mmbtu NOx. The run up in natural gas prices since 2002 has increased the cost of NOx removed from ~ $2000/ton to ~$5000/ton based on fuel expense alone. In an effort to curtail the cost of control, Duke Energy Generations Services and Kodak implemented a series of projects that integrated Cyclone Design Improvements and Advancements in Air Staging along with ESP inlet flue modifications that resulted in decreasing the Natural Gas required for NOx control ~ 40% from baseline levels saving the plant several million dollars per year in fuel expense. Significant improvements in opacity and filterable PM were also realized by these changes.

Morabito, B.; Nee, B.; Goff, V.; Maringo, G.

2008-01-01T23:59:59.000Z

417

Evaluation of Oil-Fired Gas Turbine Selective Catalytic Reduction (SCR) NOx Control  

Science Conference Proceedings (OSTI)

Utilities are experiencing increasing regulatory pressure to equip oil-fired power generation units with selective catalytic reduction (SCR) control systems. This report addresses factors utilities may wish to evaluate when justifying an NOx reduction system other than SCR or ensuring successful implementation of an SCR system.

1990-12-17T23:59:59.000Z

418

State of Knowledge Assessment for Waterwall Wastage with Low NOx Burners  

Science Conference Proceedings (OSTI)

Many utilities have experienced high corrosion rates of waterwall tubing in coal-fired steam plants following retrofit of low NOx systems with separated over-fire air (SOFA) ports. This report provides information on the currently applied materials solutions and their costs.

1997-09-11T23:59:59.000Z

419

Chemistry of NOx on TiO2 surfaces studied by ambient pressure XPS:  

NLE Websites -- All DOE Office Websites (Extended Search)

Chemistry of NOx on TiO2 surfaces studied by ambient pressure XPS: Chemistry of NOx on TiO2 surfaces studied by ambient pressure XPS: products, effect of UV irradiation, water and coadsorbed K+ Title Chemistry of NOx on TiO2 surfaces studied by ambient pressure XPS: products, effect of UV irradiation, water and coadsorbed K+ Publication Type Journal Article Year of Publication 2013 Authors Rosseler, Olivier, Mohamad Sleiman, Nahuel V. Montesinos, Andrey Shavorskiy, Valerie Keller, Nicolas Keller, Marta I. Litter, Hendrik Bluhm, Miquel Salmeron, and Hugo Destaillats Journal J. Phys. Chem. Lett. Volume 4 Start Page 536 Issue 3 Pagination 536-541 Date Published 01/2013 Abstract Self-cleaning surfaces containing TiO2 nanoparticles have been postulated to efficiently remove NOx from the atmosphere. However, UV irradiation of NOx adsorbed on TiO2 also was shown to form harmful gas-phase byproducts such as HONO and N2O that may limit their depolluting potential. Ambient pressure XPS was used to study surface and gas-phase species formed during adsorption of NO2 on TiO2 and subsequent UV irradiation at λ = 365 nm. It is shown here that NO3-, adsorbed on TiO2 as a byproduct of NO2 disproportionation, was quantitatively converted to surface NO2 and other reduced nitrogenated species under UV irradiation in the absence of moisture. When water vapor was present, a faster NO3- conversion occurred, leading to a net loss of surface-bound nitrogenated species. Strongly adsorbed NO3- in the vicinity of coadsorbed K+ cations was stable under UV light, leading to an efficient capture of nitrogenated compounds.

420

Plasma Catalysis for NOx Reduction from Light-Duty Diesel Vehicles  

SciTech Connect

The control of NOx (NO and NO2) emissions from so-called ‘lean-burn’ vehicle engines remains a challenge. In this program, we have been developing a novel plasma/catalyst technology for the remediation of NOx under lean (excess oxygen) conditions, specifically for compression ignition direct injection (CIDI) diesel engines that have significant fuel economy benefits over conventional stoichiometric gasoline engines. Program efforts included: (1) improving the catalyst and plasma reactor efficiencies for NOx reduction; (2) studies to reveal important details of the reaction mechanism(s) that can then guide our catalyst and reactor development efforts; (3) evaluating the performance of prototype systems on real engine exhaust; and (4) studies of the effects of the plasma on particulate matter (PM) in real diesel engine exhaust. Figure 1 is a conceptual schematic of a plasma/catalyst device, which also shows our current best understanding of the role of the various components of the overall device for reducing NOx from the exhaust of a CIDI engine. When this program was initiated, it was not at all clear what the plasma was doing and, as such, what class of catalyst materials might be expected to produce good results. With the understanding of the role of the plasma (as depicted in Figure 1) obtained in this program, faujasite zeolite-based catalysts were developed and shown to produce high activity for NOx reduction of plasma-treated exhaust in a temperature range expected for light-duty diesel engines. These materials are the subject of a pending patent application, and were recognized with a prestigious R&D100 Award in 2002. In addition, PNNL staff were awarded a Federal Laboratory Consortium (FLC) Award in 2003 “For Excellence in Technology Transfer”. The program also received the DOE’s 2001 CIDI Combustion and Emission Control Program Special Recognition Award and 2004 Advanced Combustion Engine R&D Special Recognition Award.

Barlow, Stephan E.; Kwak, Ja Hun; Peden, Charles HF; Szanyi, Janos; Tonkyn, Russell G.; Howden, Ken; Hoard, John W.; Cho, Byong; Schmieg, Steven J.; Brooks, David J.; Nunn, Steven; Davis, Patrick

2004-12-31T23:59:59.000Z

Note: This page contains sample records for the topic "nox sulfur dioxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

NOx reduction with the use of feedlot biomass as a reburn fuel  

E-Print Network (OSTI)

Coal fired power plants produce NOx at unacceptable levels. In order to control these emissions without major modifications to the burners, additional fuel called reburn fuel is fired under rich conditions (10-30 % by heat) after the coal burners. Additional air called overfire air (about 20 % of total air) is injected in order to complete combustion. Typically reburn fuel is natural gas (NG). From previous research at TAMU, it was found that firing feedlot biomass (FB) as reburn fuel lowers the NOx emission at significant levels compared to NG. The present research was conducted to determine the optimum operating conditions for the reduction of NOx. Experiments were performed in a small scale 29.3 kW (100,000 BTU/hr) reactor using low ash partially composted FB (LA PC FB) with equivalence ratio ranging from 1 to 1.15. The results of these experiments show that NOx levels can be reduced by as much as 90% - 95 % when firing pure LA PC FB and results are almost independent of. The reburn fuel was injected with normal air and then vitiated air (12.5 % O2); further the angles of reburn injector were set normal to the main gas flow and at 45-degrees upward. For LA PC FB no significant changes were observed; but high ash PC FB revealed better reductions with 45-degrees injector and vitiated air. This new technology has the potential to reduce NOx emissions in coal fired boilers located near cattle feedlots and also relieves the cattle industry of the waste.

Goughnour, Paul Gordon

2006-08-01T23:59:59.000Z

422

Low-Quality Natural Gas Sulfur Removal/Recovery System  

SciTech Connect

Natural gas provides more than one-fifth of all the primary energy used in the United States. Much raw gas is `subquality`, that is, it exceeds the pipeline specifications for nitrogen, carbon dioxide, and/or hydrogen sulfide content, and much of this low-quality natural gas cannot be produced economically with present processing technology. Against this background, a number of industry-wide trends are affecting the natural gas industry. Despite the current low price of natural gas, long-term demand is expected to outstrip supply, requiring new gas fields to be developed. Several important consequences will result. First, gas fields not being used because of low-quality products will have to be tapped. In the future, the proportion of the gas supply that must be treated to remove impurities prior to delivery to the pipeline will increase substantially. The extent of treatment required to bring the gas up to specification will also increase. Gas Research Institute studies have shown that a substantial capital investment in facilities is likely to occur over the next decade. The estimated overall investment for all gas processing facilities up to the year 2000 alone is approximates $1.2 Billion, of which acid gas removal and sulfur recovery are a significant part in terms of invested capital. This large market size and the known shortcomings of conventional processing techniques will encourage development and commercialization of newer technologies such as membrane processes. Second, much of today`s gas production is from large, readily accessible fields. As new reserves are exploited, more gas will be produced from smaller fields in remote or offshore locations. The result is an increasing need for technology able to treat small-scale gas streams.

Lokhandwala, K.A.; Ringer, M.; Wijams, H.; Baker, R.W.

1997-10-01T23:59:59.000Z

423

Development of NOx Sensors for Heavy Vehicle Applications  

SciTech Connect

The primary gaseous pollutants (excluding CO{sub 2}) produced by combustion of low-sulfur diesel fuel oxides of nitrogen (NO{sub x}), carbon monoxide (CO), and hydrocarbons (C{sub y}H{sub z}). The last two of these can be readily ameliorated by an oxidation catalyst in the O{sub 2}-rich environment of diesel exhaust but NO{sub x} can not.[1] For this reason NO{sub x} remediation strategies such as selective catalytic reduction (SCR) [2, 3] and the lean NO{sub x} trap (LNT) [4, 5] are being actively pursued. The ideal implementation of these strategies would employ NO{sub x} sensors to control reagent injection in the case of SCR and trap regeneration in the case of LNT. Two different NO{sub x} sensors for this application are at or near commercialization: An amperometric NO{sub x} sensor developed by NGK [6] and a 'mixed potential' NO{sub x} sensor developed by Riken [7]. The NGK sensor works by passing the sampled exhaust through a series of two chambers. In the first chamber O{sub 2} is pumped from the exhaust and in the second, NO{sub x} is decomposed electrochemically and the current from this decomposition is measured in order to determine [NO{sub x}]. Since the NO{sub x} concentrations can be small, on the 10's of ppm levels, the currents produced by decomposing the NO{sub x} can be small and difficult to measure accurately. The Riken sensor functions by passing the exhaust over a 'conversion electrode' that converts the NO{sub x} to NO{sub 2}. This NO{sub 2} is then sensed by a mixed potential sensing element.[8-10] Researchers at Ford evaluated the NGK sensor and observed the above shortcoming (poor for low [NO{sub x}]) as well as others [11] (e.g., asymmetric response to NO vs. NO{sub 2}) and were unable to obtain samples of the Riken sensor. Therefore a CRADA was initiated between Ford an ORNL to investigate the development of NO{sub x} sensors for diesel exhaust applications.

Armstrong, T.R.; West, D. L.; Montgomery, F.C.

2006-11-06T23:59:59.000Z

424

Carbon dioxide storage professor Martin Blunt  

E-Print Network (OSTI)

Carbon dioxide storage professor Martin Blunt executive summary Carbon Capture and Storage (CCS) referS to the Set of technologies developed to capture carbon dioxide (Co2) gas from the exhausts raises new issues of liability and risk. the focus of this briefing paper is on the storage of carbon

425

ORNL DAAC, Effects of Increased Carbon Dioxide, Dec. 11, 2002  

NLE Websites -- All DOE Office Websites (Extended Search)

Increased Carbon Dioxide on Vegetation The ORNL DAAC announces the release of a data set entitled "Effects of Elevated Carbon Dioxide on Litter Chemistry and Decomposition." The...

426

Geologic Carbon Dioxide Storage Field Projects Supported by DOE...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Geologic Carbon Dioxide Storage Field Projects Supported by DOE's Sequestration Program Geologic Carbon Dioxide Storage Field Projects Supported by DOE's Sequestration Program...

427

Recovery Act: Re-utilization of Industrial Carbon Dioxide for...  

NLE Websites -- All DOE Office Websites (Extended Search)

Re-utilization of Industrial Carbon Dioxide for Algae Production Using a Phase Change Material Background Worldwide carbon dioxide (CO 2 ) emissions from human activity have...

428

EA-1336: Ocean Sequestration of Carbon Dioxide Field Experiment...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

6: Ocean Sequestration of Carbon Dioxide Field Experiment, Pittsburgh, Pennsylvania EA-1336: Ocean Sequestration of Carbon Dioxide Field Experiment, Pittsburgh, Pennsylvania...

429

Haverford Researchers Create Carbon Dioxide-Separating Polymer  

NLE Websites -- All DOE Office Websites (Extended Search)

Haverford College Researchers Create Carbon Dioxide-Separating Polymer Haverford College Researchers Create Carbon Dioxide-Separating Polymer August 1, 2012 | Tags: Basic Energy...

430

Cost and Performance of Carbon Dioxide Capture from Power Generation...  

Open Energy Info (EERE)

on Facebook icon Twitter icon Cost and Performance of Carbon Dioxide Capture from Power Generation Jump to: navigation, search Name Cost and Performance of Carbon Dioxide...

431

Changes related to "Cost and Performance of Carbon Dioxide Capture...  

Open Energy Info (EERE)

icon Changes related to "Cost and Performance of Carbon Dioxide Capture from Power Generation" Cost and Performance of Carbon Dioxide Capture from Power Generation...

432

Why do carbon dioxide emissions weigh more than the ...  

U.S. Energy Information Administration (EIA)

Why do carbon dioxide emissions weigh more than the original fuel? Carbon dioxide emissions weigh more than the original fuel because during complete ...

433

Nano-Enabled Titanium Dioxide Ultraviolet Protective Layers for...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Nano-Enabled Titanium Dioxide Ultraviolet Protective Layers for Cool-Color Roofing Research Project Nano-Enabled Titanium Dioxide Ultraviolet Protective Layers for Cool-Color...

434

THE HIGH TEMPERATURE BEHAVIOR OF METALLIC INCLUSIONS IN URANIUM DIOXIDE.  

E-Print Network (OSTI)

Products in Irradiated Uranium Dioxide," UKAEA Report AERE-OF METALLIC INCLUSIONS IN URANIUM DIOXIDE Rosa Lu Yang (Chemical State of Irradiated Uranium- Plutonium Oxide Fuel

Yang, Rosa Lu.

2010-01-01T23:59:59.000Z

435

Improving the Carbon Dioxide Emission Estimates from the Combustion...  

NLE Websites -- All DOE Office Websites (Extended Search)

Improving the Carbon Dioxide Emission Estimates from the Combustion of Fossil Fuels in California and Spatial Disaggregated Estimate of Energy-related Carbon Dioxide for California...

436

Improving the Carbon Dioxide Emission Estimates from the Combustion...  

NLE Websites -- All DOE Office Websites (Extended Search)

the Carbon Dioxide Emission Estimates from the Combustion of Fossil Fuels in California Title Improving the Carbon Dioxide Emission Estimates from the Combustion of Fossil Fuels in...

437

Emerging Energy-efficiency and Carbon Dioxide Emissions-reduction...  

NLE Websites -- All DOE Office Websites (Extended Search)

Energy-efficiency and Carbon Dioxide Emissions-reduction Technologies for the Iron and Steel Industry Title Emerging Energy-efficiency and Carbon Dioxide Emissions-reduction...

438

Carbon Dioxide Capture/Sequestration Tax Deduction (Kansas) ...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Carbon Dioxide CaptureSequestration Tax Deduction (Kansas) Carbon Dioxide CaptureSequestration Tax Deduction (Kansas) Eligibility Commercial Industrial Utility Program...

439

Carbon dioxide disposal in solid form  

SciTech Connect

Coal reserves can provide for the world`s energy needs for centuries. However, coal`s long term use may be severely curtailed if the emission of carbon dioxide into the atmosphere is not eliminated. We present a safe and permanent method of carbon dioxide disposal that is based on combining carbon dioxide chemically with abundant raw materials to form stable carbonate minerals. We discuss the availability of raw materials and potential process designs. We consider our initial rough cost estimate of about 3{cents}/kWh encouraging. The availability of a carbon dioxide fixation technology would serve as insurance in case global warming, or the perception of global warming, causes severe restrictions on carbon dioxide emissions. If the increased energy demand of a growing world population is to be satisfied from coal, the implementation of such a technology would quite likely be unavoidable.

Lackner, K.S.; Butt, D.P.; Sharp, D.H. [Los Alamos National Lab., NM (United States); Wendt, C.H. [Auxon Corp., (United States)

1995-12-31T23:59:59.000Z

440

carbon dioxide emissions | OpenEI  

Open Energy Info (EERE)

dioxide emissions dioxide emissions Dataset Summary Description Total annual carbon dioxide emissions by country, 2005 to 2009 (million metric tons). Compiled by Energy Information Administration (EIA). Source EIA Date Released Unknown Date Updated Unknown Keywords carbon dioxide emissions EIA world Data text/csv icon total_carbon_dioxide_emissions_from_the_consumption_of_energy_2005_2009million_metric_tons.csv (csv, 12.3 KiB) Quality Metrics Level of Review Peer Reviewed Comment Temporal and Spatial Coverage Frequency Time Period 2005 - 2009 License License Other or unspecified, see optional comment below Comment Rate this dataset Usefulness of the metadata Average vote Your vote Usefulness of the dataset Average vote Your vote Ease of access Average vote Your vote Overall rating

Note: This page contains sample records for the topic "nox sulfur dioxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

EIA - Greenhouse Gas Emissions - Carbon Dioxide Emissions  

Gasoline and Diesel Fuel Update (EIA)

2. Carbon Dioxide Emissions 2. Carbon Dioxide Emissions 2.1. Total carbon dioxide emissions Annual U.S. carbon dioxide emissions fell by 419 million metric tons in 2009 (7.1 percent), to 5,447 million metric tons (Figure 9 and Table 6). The annual decrease-the largest over the 19-year period beginning with the 1990 baseline-puts 2009 emissions 608 million metric tons below the 2005 level, which is the Obama Administration's benchmark year for its goal of reducing U.S. emissions by 17 percent by 2020. The key factors contributing to the decrease in carbon dioxide emissions in 2009 included an economy in recession with a decrease in gross domestic product of 2.6 percent, a decrease in the energy intensity of the economy of 2.2 percent, and a decrease in the carbon intensity of energy supply of

442

Energy Savings and NOx Emissions Reduction Potential from the 2012 Federal Legislation to Phase Out Incandescent Lamps in Texas  

E-Print Network (OSTI)

This report provides detailed information about the potential savings from the 2012 Federal Legislation to phase out incandescent lamps and the NOx emissions reduction from the replacement of incandescent bulbs with Compact Fluorescent Lamps (CFL). In Texas, this analysis includes the savings estimates from both the annual and Ozone Season Day (OSD) NOx reductions. The NOx emissions reduction in this analysis are calculated using estimated emissions factors for 2007 from the US Environmental Protection Agency (US EPA) eGRID database, which had been specially prepared for this purpose.

Liu, Zi; Baltazar, Juan Carlos; Haberl, Jeff; Soman, Rohit

2010-03-01T23:59:59.000Z

443