Sample records for nox particulate matter

  1. SURFACE OXIDATION OF DIESEL PARTICULATE MATTER IN PRESENCE OF O3 +NOX: NEW TD/GC/MS ANALYSIS METHOD

    E-Print Network [OSTI]

    Holmén, Britt A.

    SURFACE OXIDATION OF DIESEL PARTICULATE MATTER IN PRESENCE OF O3 +NOX: NEW TD/GC/MS ANALYSIS METHOD+08 2.6e+08 2.8e+08 3e+08 Time--> Abundance TIC: 0914S4.D INTRODUCTION Diesel exhaust is one into the atmosphere diesel particles can be transformed through physical and chemical processes resulting

  2. Particulate matter dynamics

    E-Print Network [OSTI]

    Cionco, Rodolfo G; Caligaris, Marta G

    2012-01-01T23:59:59.000Z

    A substantial fraction of the particulate matter released into the atmosphere by industrial or natural processes corresponds to particles whose aerodynamic diameters are greater than 50 mm. It has been shown that, for these particles, the classical description of Gaussian plume diffusion processes, is inadequate to describe the transport and deposition. In this paper we present new results concerning the dispersion of coarse particulate matter. The simulations are done with our own code that uses the Bulirsch Stoer numerical integrator to calculate threedimensional trajectories of particles released into the environment under very general conditions. Turbulent processes are simulated by the Langevin equation and weather conditions are modeled after stable (Monin-Obukhov length L> 0) and unstable conditions (L <0). We present several case studies based on Monte Carlo simulations and discusses the effect of weather on the final deposition of these particles.

  3. Particulate Matter Aerosols

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOnItemResearch > TheNuclear Astrophysics OneOutreach EffortsSearchParticulate Matter

  4. Apparatus for particulate matter analysis

    DOE Patents [OSTI]

    Gundel, Lara A.; Apte, Michael G.; Hansen, Anthony D.; Black, Douglas R.

    2007-01-30T23:59:59.000Z

    The apparatus described herein is a miniaturized system for particle exposure assessment (MSPEA) for the quantitative measurement and qualitative identification of particulate content in gases. The present invention utilizes a quartz crystal microbalance (QCM) or other mass-sensitive temperature compensated acoustic wave resonator for mass measurement. Detectors and probes and light sources are used in combination for the qualitative determination of particulate matter.

  5. Particulate Matter Standards (Ohio)

    Broader source: Energy.gov [DOE]

    This chapter of the law establishes that the Ohio Environmental Protection Agency sets the standards for particulate emissions from a variety of sources, including facilities that generate power. ...

  6. Effects of Advanced Combustion Technologies on Particulate Matter...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Advanced Combustion Technologies on Particulate Matter Emissions Characteristics Effects of Advanced Combustion Technologies on Particulate Matter Emissions Characteristics...

  7. UTILIZING WATER EMULSIFICATION TO REDUCE NOX AND PARTICULATE EMISSIONS ASSOCIATED WITH BIODIESEL

    SciTech Connect (OSTI)

    Kass, Michael D [ORNL; Lewis Sr, Samuel Arthur [ORNL; Lee, Doh-Won [ORNL; Huff, Shean P [ORNL; Storey, John Morse [ORNL; Swartz, Matthew M [ORNL; Wagner, Robert M [ORNL

    2009-01-01T23:59:59.000Z

    A key barrier limiting extended utilization of biodiesel is higher NOx emissions compared to petrodiesel fuels. The reason for this effect is unclear, but various researchers have attributed this phenomena to the higher liquid bulk modulus associated with biodiesel and the additional heat released during the breaking of C-C double bonds in the methyl ester groups. In this study water was incorporated into neat biodiesel (B100) as an emulsion in an attempt to lower NOx and particulate matter (PM) emissions. A biodiesel emulsion containing 10wt% water was formulated and evaluated against an ultra-low sulfur petroleum diesel (ULSD) and neat biodiesel (B100) in a light-duty diesel engine operated at 1500RPM and at loads of 68Nm (50ft-lbs) and 102Nm (75ft-lbs). The influence of exhaust gas recirculation (EGR) was also examined. The incorporation of water was found to significantly lower the NOx emissions of B100, while maintaining fuel efficiency when operating at 0 and 27% EGR. The soot fraction of the particulates (as determined using an opacity meter) was much lower for the B100 and B100-water emulsion compared ULSD. In contrast, total PM mass (for the three fuel types) was unchanged for the 0% EGR condition but was significantly lower for the B100 and B100-emulsion during the 27% EGR condition compared to the ULSD fuel. Analysis of the emissions and heat release data indicate that water enhances air-fuel premixing to maintain fuel economy and lower soot formation. The exhaust chemistry of the biodiesel base fuels (B100 and water-emulsified B100) was found to be unique in that they contained measurable levels of methyl alkenoates, which were not found for the ULSD. These compounds were formed by the partial cracking of the methyl ester groups during combustion.

  8. Advanced particulate matter control apparatus and methods

    DOE Patents [OSTI]

    Miller, Stanley J. (Grand Forks, ND); Zhuang, Ye (Grand Forks, ND); Almlie, Jay C. (East Grand Forks, MN)

    2012-01-10T23:59:59.000Z

    Apparatus and methods for collection and removal of particulate matter, including fine particulate matter, from a gas stream, comprising a unique combination of high collection efficiency and ultralow pressure drop across the filter. The apparatus and method utilize simultaneous electrostatic precipitation and membrane filtration of a particular pore size, wherein electrostatic collection and filtration occur on the same surface.

  9. Desorption of hexachlorobiphenyl from selected particulate matter

    E-Print Network [OSTI]

    Rorschach, Reagan Cartwright

    1989-01-01T23:59:59.000Z

    DESORPTION OF HEXACHLOROBIPHENYL FROM SELECTED PARTICULATE MATTER A Thesis by REAGAN CARTWRIGHT RORS CHACH Submitted to the Office of Graduate Studies of Texas ARM University in partial fulfillment of the requirements for the degree... of MASTER OF SCIENCE December 1989 Major Subject: Civil Engineering DESORPTION OF HEXACHLOROBIPHENYL FROM SELECTED PARTICULATE MATTER A Thesis by REAGAN C. RORSCHACH Approved as to style and content by: Robin L. Autenrieth (Chair of Committee...

  10. Fuel-Neutral Studies of Particulate Matter Transport Emissions...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Technologies Program Annual Merit Review and Peer Evaluation ace056stewart2011o.pdf More Documents & Publications Fuel-Neutral Studies of Particulate Matter Transport Emissions...

  11. air particulate matter: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    WetLabs, personal communication. There is variability in composition of particulate matter through the water column, so different correlations of PMbb or POCbb may exist in...

  12. airborne particulate matter: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    WetLabs, personal communication. There is variability in composition of particulate matter through the water column, so different correlations of PMbb or POCbb may exist in...

  13. ambient particulate matter: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    WetLabs, personal communication. There is variability in composition of particulate matter through the water column, so different correlations of PMbb or POCbb may exist in...

  14. Non-thermal plasma based technologies for the after-treatment of automotive exhaust particulates and marine diesel exhaust NOx

    SciTech Connect (OSTI)

    McAdams, R; Beech, P; Gillespie, R; Guy, C; Jones,S; Liddell, T; Morgan, R; Shawcross, J; Weeks, D; Hughes, D; Oesterle, J; Eberspdcher,

    2003-08-24T23:59:59.000Z

    The trend in environmental legislation is such that primary engine modifications will not be sufficient to meet all future emissions requirements and exhaust aftertreatment technologies will need to be employed. One potential solution that is well placed to meet those requirements is non-thermal plasma technology. This paper will describe our work with some of our partners in the development of a plasma based diesel particulate filter (DPF) and plasma assisted catalytic reduction (PACR) for NOx removal. This paper describes the development of non-thermal plasma technology for the aftertreatment of particulates from a passenger car engine and NOx from a marine diesel exhaust application.

  15. Concentrations and Size Distributions of Particulate Matter Emissions...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Matter Emissions from Catalyzed Trap-Equipped Heavy-duty Diesel Vehicles Operating on Ultra-low Sulfur EC-D Fuel Concentrations and Size Distributions of Particulate Matter...

  16. On-Board Engine Exhaust Particulate Matter Sensor for HCCI and...

    Energy Savers [EERE]

    On-Board Engine Exhaust Particulate Matter Sensor for HCCI and Conventional Diesel Engines On-Board Engine Exhaust Particulate Matter Sensor for HCCI and Conventional Diesel...

  17. Microscopy investigations of ash and particulate matter accumulation in diesel particulate filter surface pores

    E-Print Network [OSTI]

    Beauboeuf, Daniel P

    2010-01-01T23:59:59.000Z

    There has been increased focus on the environmental impact of automobile emissions in recent years. These environmental concerns have resulted in the creation of more stringent particulate matter emissions regulations in ...

  18. Implications of Low Particulate Matter Emissions on System Fuel Efficiency for High Efficiency Clean Combustion

    SciTech Connect (OSTI)

    Parks, II, James E [ORNL; Prikhodko, Vitaly Y [ORNL] [ORNL

    2009-01-01T23:59:59.000Z

    Advanced diesel combustion regimes such as High Efficiency Clean Combustion (HECC) offer the benefits of reduced engine out NOX and particulate matter (PM) emissions. Lower PM emissions during advanced combustion reduce the demand on diesel particulate filters (DPFs) and can, thereby, reduce the fuel penalty associated with DPF regeneration. In this study, a SiC DPF was loaded and regenerated on a 1.7-liter 4-cylinder diesel engine operated in conventional and advanced combustion modes at different speed and load conditions. A diesel oxidation catalyst (DOC) and a lean NOX trap (LNT) were also installed in the exhaust stream. Five steady-state speed and load conditions were weighted to estimate Federal Test Procedure (FTP) fuel efficiency. The DPF was loaded using lean-rich cycling with frequencies that resulted in similar levels of NOX emissions downstream of the LNT. The pressure drop across the DPF was measured at a standard point (1500 rpm, 5.0 bar) before and after loading, and a P rise rate was determined for comparison between conventional and advanced combustion modes. Higher PM emissions in conventional combustion resulted in a higher rate of backpressure rise across the DPF at all of the load points leading to more frequent DPF regenerations and higher fuel penalty. The fuel penalty during conventional combustion was 4.2% compared with 3.1% for a mixture of conventional and advanced modes.

  19. Simultaneous Removal of Particulates and NOx Using Catalyst Impregnated Fibrous Ceramic Filters

    SciTech Connect (OSTI)

    Choi, J.I.; Mun, S.H.; Kim, S.T.; Hong, M.S.; Lee, J.C.

    2002-09-19T23:59:59.000Z

    The research is focused on the development and commercialization of high efficiency, cost effective air pollution control system, which can replace in part air pollution control devices currently in use. In many industrial processes, hot exhaust gases are cooled down to recover heat and to remove air pollutants in exhaust gases. Conventional air pollution control devices such as bag filters, E.P. and adsorption towers withstand operating temperatures up to 300 C. Also, reheating is sometimes necessary to meet temperature windows for S.C.R. Since Oxidation reactions of acid gases such as SO{sub 2}, and HCl with lime are enhanced at high temperatures, catalyst impregnated ceramic filters can be candidate for efficient and cost effective air pollution control devices. As shown on Fig. 1., catalytic ceramic filters remove particulates on exterior surface of filters and acid gases are oxidized to salts reacting with limes injected in upstream ducts. Oxidation reactions are enhanced in the cake formed on exterior of filters. Finally, injected reducing gas such as NH{sub 3} react with NOx to form N{sub 2} and H{sub 2}O interior of filters in particulate-free environment. Operation and maintenance technology is similar to conventional bag filters except that systems are exposed to relatively high temperatures ranging 300-500 C.

  20. REVIEW OF DIESEL PARTICULATE MATTER SAMPLING METHODS Supplemental Report # 1

    E-Print Network [OSTI]

    Minnesota, University of

    REVIEW OF DIESEL PARTICULATE MATTER SAMPLING METHODS Supplemental Report # 1 DIESEL EXHAUST.D. and Megan Arnold University of Minnesota Department of Mechanical Engineering Center for Diesel Research....................................................................................... 3 Diesel aerosol size instrumentation............................................................ 4

  1. REVIEW OF DIESEL PARTICULATE MATTER SAMPLING METHODS Supplemental Report # 2

    E-Print Network [OSTI]

    Minnesota, University of

    REVIEW OF DIESEL PARTICULATE MATTER SAMPLING METHODS Supplemental Report # 2 AEROSOL DYMAMICS Arnold University of Minnesota Department of Mechanical Engineering Center for Diesel Research................................................................................................. 3 Diesel aerosol composition and structure................................................... 3

  2. Modeling of Particulate Matter Emissions from Agricultural Operations

    E-Print Network [OSTI]

    Bairy, Jnana 1988-

    2013-01-02T23:59:59.000Z

    State Air Pollution Regulation Agencies (SAPRAs) issue and enforce permits that limit particulate matter emissions from all sources including layer and broiler facilities, cattle feedyards, dairies, cotton gins, and grain elevators...

  3. ORIGINAL ARTICLE Fine Particulate Matter and Mortality

    E-Print Network [OSTI]

    Dominici, Francesca

    landmark cohort studies for estimating the chronic effects of fine particulate air pollution (PM2 that the Medicare files can be used to construct on-going cohorts for tracking the risk of air pollution over time- tory diseases, and also with increased mortality.1­6 Chronic effects of air pollution potentially

  4. An Overview of Particulate Matter and its Cost-efficient Evaluation

    E-Print Network [OSTI]

    Zhang, F.; Zhang, G.; Zhang, Q.

    2006-01-01T23:59:59.000Z

    Ambient particulate matter (PM) is a complex mixture of sizes and types of particles. Exposure to airborne particulate matter adversely affects human health. In this paper, sources of particles are summarized, and epidemiological and toxicological...

  5. Inductively heated particulate matter filter regeneration control system

    DOE Patents [OSTI]

    Gonze, Eugene V; Paratore Jr., Michael J; Kirby, Kevin W; Phelps, Amanda; Gregoire, Daniel J

    2012-10-23T23:59:59.000Z

    A system includes a particulate matter (PM) filter with an upstream end for receiving exhaust gas, a downstream end and zones. The system also includes a heating element. A control module selectively activates the heating element to inductively heat one of the zones.

  6. REVIEW OF DIESEL PARTICULATE MATTER SAMPLING FINAL REPORT

    E-Print Network [OSTI]

    Minnesota, University of

    REVIEW OF DIESEL PARTICULATE MATTER SAMPLING METHODS FINAL REPORT Prepared by David B. Kittelson of Mechanical Engineering Center for Diesel Research Minneapolis, MN January 14, 1999 #12;01/14/99 Page 2 TABLE ................................................................................................................5 DIESEL ENGINE TECHNOLOGY AND EMISSION REGULATIONS .............................7 PHYSICAL

  7. Biodiesel Fuel Property Effects on Particulate Matter Reactivity

    SciTech Connect (OSTI)

    Williams, A.; Black, S.; McCormick, R. L.

    2010-06-01T23:59:59.000Z

    Controlling diesel particulate emissions to meet the 2007 U.S. standard requires the use of a diesel particulate filter (DPF). The reactivity of soot, or the carbon fraction of particulate matter, in the DPF and the kinetics of soot oxidation are important in achieving better control of aftertreatment devices. Studies showed that biodiesel in the fuel can increase soot reactivity. This study therefore investigated which biodiesel fuel properties impact reactivity. Three fuel properties of interest included fuel oxygen content and functionality, fuel aromatic content, and the presence of alkali metals. To determine fuel effects on soot reactivity, the performance of a catalyzed DPF was measured with different test fuels through engine testing and thermo-gravimetric analysis. Results showed no dependence on the aromatic content or the presence of alkali metals in the fuel. The presence and form of fuel oxygen was the dominant contributor to faster DPF regeneration times and soot reactivity.

  8. Speciation of Sb in airborne particulate matter, vehicle brake linings, and brake pad wear residues

    E-Print Network [OSTI]

    Short, Daniel

    Speciation of Sb in airborne particulate matter, vehicle brake linings, and brake pad wear residues: XAS XANES EXAFS Antimony Particulate matter Brake linings a b s t r a c t Insights into the speciation of Sb in samples of brake linings, brake pad wear residues, road dust, and atmospheric particulate

  9. The Relationships of Particulate Matter and Particulate Organic Carbon with Hypoxic Conditions Along the Texas-Louisiana Shelf

    E-Print Network [OSTI]

    Zuck, Nicole A

    2014-08-06T23:59:59.000Z

    an onboard surface-water flow-through system, CTD casts, and by an undulating towed vehicle. Total particulate matter and particulate organic carbon samples were obtained from Niskin bottles on CTD casts. Samples were also taken to measure dissolved oxygen...

  10. Wireless zoned particulate matter filter regeneration control system

    DOE Patents [OSTI]

    Gonze, Eugene V [Pinckney, MI; Kirby, Kevin W [Calabasas Hills, CA; Phelps, Amanda [Malibu, CA

    2011-10-04T23:59:59.000Z

    An assembly includes a particulate matter (PM) filter that comprises an upstream end for receiving exhaust gas, a downstream end and multiple zones. An absorbing layer absorbs microwave energy in one of N frequency ranges and is arranged with the upstream end. N is an integer. A frequency selective filter has M frequency selective segments and receives microwave energy in the N frequency ranges. M is an integer. One of the M frequency selective segments permits passage of the microwave energy in one of the N frequency ranges and does not permit passage of microwave energy in the other of the N frequency ranges.

  11. Ash reduction system using electrically heated particulate matter filter

    DOE Patents [OSTI]

    Gonze, Eugene V [Pinckney, MI; Paratore, Jr., Michael J; He, Yongsheng [Sterling Heights, MI

    2011-08-16T23:59:59.000Z

    A control system for reducing ash comprises a temperature estimator module that estimates a temperature of an electrically heated particulate matter (PM) filter. A temperature and position estimator module estimates a position and temperature of an oxidation wave within the electrically heated PM filter. An ash reduction control module adjusts at least one of exhaust flow, fuel and oxygen levels in the electrically heated PM filter to adjust a position of the oxidation wave within the electrically heated PM filter based on the oxidation wave temperature and position.

  12. Low exhaust temperature electrically heated particulate matter filter system

    DOE Patents [OSTI]

    Gonze, Eugene V. (Pinckney, MI); Paratore, Jr., Michael J. (Howell, MI); Bhatia, Garima (Bangalore, IN)

    2012-02-14T23:59:59.000Z

    A system includes a particulate matter (PM) filter, a sensor, a heating element, and a control module. The PM filter includes with an upstream end that receives exhaust gas, a downstream end and multiple zones. The sensor detects a temperature of the exhaust gas. The control module controls current to the heating element to convection heat one of the zones and initiate a regeneration process. The control module selectively increases current to the heating element relative to a reference regeneration current level when the temperature is less than a predetermined temperature.

  13. Apparatus for removal of particulate matter from gas streams

    DOE Patents [OSTI]

    Smith, Peyton L. (Baton Rouge, LA); Morse, John C. (Baton Rouge, LA)

    2000-01-01T23:59:59.000Z

    An apparatus for the removal of particulate matter from the gaseous product stream of an entrained flow coal gasifier which apparatus includes an initial screen, an intermediate screen which is aligned with the direction of flow of the gaseous product stream and a final screen transversely disposed to the flow of gaseous product and which apparatus is capable of withstanding at least a pressure differential of about 10 psi (68.95 kPa) or greater at the temperatures of the gaseous product stream.

  14. Elevated exhaust temperature, zoned, electrically-heated particulate matter filter

    DOE Patents [OSTI]

    Gonze, Eugene V [Pinckney, MI; Bhatia, Garima [Bangalore, IN

    2012-04-17T23:59:59.000Z

    A system includes an electrical heater and a particulate matter (PM) filter that is arranged one of adjacent to and in contact with the electrical heater. A control module selectively increases an exhaust gas temperature of an engine to a first temperature and that initiates regeneration of the PM filter using the electrical heater while the exhaust gas temperature is above the first temperature. The first temperature is greater than a maximum exhaust gas temperature at the PM filter during non-regeneration operation and is less than an oxidation temperature of the PM.

  15. An evaluation of European air pollution regulations for particulate matter monitored from a

    E-Print Network [OSTI]

    Sahu, Sujit K

    An evaluation of European air pollution regulations for particulate matter monitored from, stationarity. Abstract Statistical methods are needed for evaluating many aspects of air pollution regu particulate matter (PM) is an important air pollutant for which regu- lations have been issued recently

  16. An Optical Backscatter Sensor for Particulate Matter Measurement

    SciTech Connect (OSTI)

    Parks, II, James E [ORNL; Prikhodko, Vitaly Y [ORNL; Partridge Jr, William P [ORNL

    2009-01-01T23:59:59.000Z

    Diesel engines are prone to emit particulate matter (PM) emissions under certain operation conditions. In-cylinder production of PM from diesel combustion control can occur under a wide variety of operating conditions, and in some cases, operation of a multi-cylinder engine can further complicate PM emissions due to variations in air or fuel charge due to manifold mixing effects. In this study, a probe for detecting PM in diesel exhaust was evaluated on a light-duty diesel engine. The probe is based on an optical backscattering effect. Due to the optical nature of the probe, PM sensing can occur at high rates. The feasibility of the probe for examining PM emissions in the exhaust manifold will be discussed.

  17. An optimization study on the control of NOx and particulate emissions from diesel engines

    SciTech Connect (OSTI)

    Larsen, C.; Oey, F.; Levendis, Y.A. [Northeastern Univ., Boston, MA (United States)

    1996-09-01T23:59:59.000Z

    This is an optimization study on the use of filtered exhaust gas recirculation (EGR) to reduce the NO emissions of diesel engines. Control of the particulate emissions and provisions for filtered EGR were achieved by an Aerodynamically Regenerated Trap (ART) with collection efficiencies in the order of 99%. The amount of EGR was regulated to provide for substantial NO reduction, without unacceptably decreasing the thermal efficiency of the engine or increasing the CO emissions. EGR regulation was accomplished by monitoring the injection pump setting which was correlated to the fuel flow rate, the speed of the engine, the amount of EGR flow, and the ambient air temperature. Through these parameters, the mixture strength expressed as the equivalence ratio {phi} was calculated and related to the power output of the engine. Thus, a map of engine performance parameters was generated and related to measured NO and CO emissions. A series of road tests showed that EGR most effectively reduces NO emissions at high {phi}`s (by a factor of two at 20% EGR) which, however, is accompanied by an increase in CO emissions by a factor of two, and a penalty in fuel economy by 8%. Benefits and losses can be optimized by automatically varying the level of EGR, using feedback from the aforementioned engine parameters. An algorithm was developed to govern the electrically controlled EGR valve and tests showed that the NO levels decreased by 30%, while the CO increased by 30%, showing no penalty in fuel economy. The resulting specific NO and CO emissions were well within the current US EPA standards.

  18. Interactions between diatom aggregates, minerals, particulate organic carbon, and dissolved organic matter: Further

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Interactions between diatom aggregates, minerals, particulate organic carbon, and dissolved organic October 2008. [1] Correlations of particulate organic carbon (POC) and mineral fluxes into sediment traps in the deep sea have previously suggested that interactions between organic matter and minerals play a key

  19. The Role of Particulate Matter in the Development of Hypoxia on the Texas-Louisiana Shelf

    E-Print Network [OSTI]

    Cochran, Emma Mary

    2013-07-31T23:59:59.000Z

    particle composition and processes that dominate those areas – river-dominated water, highly productive surface waters, and clear, nutrient-poor low-productivity surface waters. The distribution and bulk composition of particulate matter in the northern...

  20. Air dispersion modeling of particulate matter from ground-level area sources 

    E-Print Network [OSTI]

    Meister, Michael Todd

    2000-01-01T23:59:59.000Z

    State Air Pollution Regulatory Agencies (SAPRAs) often use dispersion modeling to predict downwind concentrations of particulate matter (PM) from a facility. As such, a facility may be granted or denied an operating permit ...

  1. On-Board Engine Exhaust Particulate Matter Sensor for HCCI and Conventional Diesel Engines

    SciTech Connect (OSTI)

    Hall, Matt; Matthews, Ron

    2011-09-30T23:59:59.000Z

    The goal of the research was to refine and complete development of an on-board particulate matter (PM) sensor for diesel, DISI, and HCCI engines, bringing it to a point where it could be commercialized and marketed.

  2. New Chemical Aerosol Characterization Methods- Examples Using Agricultural and Urban Airborne Particulate Matter

    E-Print Network [OSTI]

    Zhou, Lijun

    2010-10-12T23:59:59.000Z

    This study explored different chemical characterization methods of agricultural and urban airborne particulate matter. Three different field campaigns are discussed. For the agricultural aerosols, measurement of the chemical composition of size...

  3. Development and Demonstration of an Electronic Particulate Matter...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Aftertreatment and Low Pressure Loop EGR Applied to an Off-Highway Engine Advanced Radio Frequency-Based Sensors for Monitoring Diesel Particulate Filter Loading and...

  4. Emission factors for ammonia and particulate matter from broiler Houses

    E-Print Network [OSTI]

    Redwine, Jarah Suzanne

    2001-01-01T23:59:59.000Z

    Total suspended particulate (TSP) concentrations, ammonia (NH?) concentrations, and ventilation rates were measured in four commercial, tunnel ventilated broiler houses in June through December of 2000 in Brazos County, Texas. Particle size...

  5. Removal of residual particulate matter from filter media

    DOE Patents [OSTI]

    Almlie, Jay C; Miller, Stanley J

    2014-11-11T23:59:59.000Z

    A method for removing residual filter cakes that remain adhered to a filter after typical particulate removal methodologies have been employed, such as pulse-jet filter element cleaning, for all cleanable filters used for air pollution control, dust control, or powder control.

  6. Evaluation of the TEOM method for the measurement of particulate matter for Texas cattle feedlots

    E-Print Network [OSTI]

    Skloss, Stewart James

    2009-05-15T23:59:59.000Z

    and Patashnick (R&P) Series1400a monitors. The R&P Series 1400a monitor uses the TEOM method to measure particulate matter (PM) concentrations and was approved by EPA in 1990 as an automated equivalent method PM10 sampler. Since its approval, many state air...

  7. FTIR Analysis of Particulate Matter Collected on Teflon Filters in Columbus, OH A Senior Honors Thesis

    E-Print Network [OSTI]

    in the undergraduate colleges of The Ohio State University by Patrick Veres The Ohio State University June 2005 Project of particulate matter (PM) to which humans are exposed to provides information important to the understanding of our chemical environment and associated health risks. In this research, experimental methods have been

  8. Estimating particulate matter health impact related to the combustion of different fossil fuels

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Estimating particulate matter health impact related to the combustion of different fossil fuels generated a web map service that allows to access information on fuel dependent health effects due a simulation. Combined with a dedicated emission inventory PM2.5 maps specified by fuel type were generated

  9. DDT RESIDUES IN SEAWATER AND PARTICULATE MATTER IN THE CALIFORNIA CURRENT SYSTEM

    E-Print Network [OSTI]

    DDT RESIDUES IN SEAWATER AND PARTICULATE MATTER IN THE CALIFORNIA CURRENT SYSTEM JAMES L. COX in the California current system were analyzed for DDT residues. DDT residue concentrations in whole seawater are discussed in relation to mechanisms of land-sea DDT residue transfer. DDT residue concentrations

  10. Modeling water column structure and suspended particulate matter on the Middle Atlantic continental shelf

    E-Print Network [OSTI]

    Chang, Grace C.

    that contributed to the evolution of observed thermal structure and resuspension of particulate matter during resuspension processes. It is concluded that wave-current bottom shear stress was clearly the most important process for sediment resuspension during and following both hurricanes. Discrepancies between modeled

  11. Statistical Issues in the Study of Air Pollution Involving Airborne Particulate Matter

    E-Print Network [OSTI]

    Washington at Seattle, University of

    of the Workshop was to initiate a statistical research program relevant to setting air quality standardsStatistical Issues in the Study of Air Pollution Involving Airborne Particulate Matter Lawrence H. Cox NRCSET e c h n i c a l R e p o r t S e r i e s NRCSE-TRS No. 041 January 10, 2000 The NRCSEwas

  12. Contrasting Surface Ozone and Particulate Matter measurements with meteorological conditions in South Florida and its possible impacts on the number of Asthma cases: Five years of correlations.

    E-Print Network [OSTI]

    Miami, University of

    Contrasting Surface Ozone and Particulate Matter measurements with meteorological conditions, wind speed and direction), and air quality indicators (ozone O3 and particulate matter PM2.5) are presented in this study. Surface Ozone and Particulate Matter have been both important triggers of asthma

  13. Study of particulate matter formation and evolution in near-field aircraft plumes using a one-dimensional microphysical model

    E-Print Network [OSTI]

    Zhang, Jianye, S.M. Massachusetts Institute of Technology

    2007-01-01T23:59:59.000Z

    Environmental concerns have led to a growing effort to investigate and characterize the particulate matter (PM) emissions from aircraft engines. This thesis presents a one-dimensional microphysics and chemical kinetics ...

  14. Development of a size-fractionating stack sampler for collection of particulate matter

    E-Print Network [OSTI]

    1983-01-01T23:59:59.000Z

    information for the design of a cleaning system. The six major pollutants established by the U. S. Environmental Protection Agency (EPA) are carbon monoxide, nitrogen dioxide, sulfur oxides, hydrocarbons, photochemical oxidants, and particulate matter... descr1bed. In 1971 Monsanto Enviro-Chem Systems, Inc. ( 18) developed a novel cyclone preseparator with an inverted discharge tube for use w1th in- ertial impactors. In 1973, Ancel (19) developed a cyclone preseparator for inert1al impactors...

  15. Development of a Low-Cost Particulate Matter Monitor

    SciTech Connect (OSTI)

    White, Richard M.; Apte, Michael G.; Gundel, Lara A.; Black, Justin

    2008-08-01T23:59:59.000Z

    We describe a small, inexpensive portable monitor for airborne particulates, composed of the following elements: a. A simple size-selective inlet (vertical elutriator) that permits only particles below a pre-set diameter to pass and enter the measurement section; b. A measurement section in which passing particles are deposited thermophoretically on a micro-fabricated resonant piezoelectric mass sensor; c. An optical characterization module co-located with the mass sensor module that directs infrared and ultraviolet beams through the deposit. The emergent optical beams are detected by a photodiode. The optical absorption of the deposit can be measured in order to characterize the deposit, and determine how much is due to diesel exhaust and/or environmental tobacco smoke; and d. A small pump that moves air through the device, which may also be operated in a passive mode. The component modules were designed by the project team, and fabricated at UCB andLBNL. Testing and validation were performed in a room-sized environmental chamber at LBNL in to which was added either environmental tobacco smoke (ETS, produced by a cigarette smoking machine) or diesel exhaust (from a conventional diesel engine). Two pilot field tests in a dwelling compared the monitor with existing aerosol instruments during exposure to infiltrated ambient air to which cigarette smoke, diesel exhaust, wood smoke and cooking fumes were added. The limit of detection (LOD) derived from statistical analysis of field data is 18 mu g m-3, at the 99percent confidence level. The monitor weighs less than 120 g and has a volume of roughly 250 cm3. Power consumption is approximately 100 milliwatts. During this study, the optical component of the device was not fully implemented and has been left for future efforts. Suggested improvements in the current prototype include use of integrated thermal correction, reconfiguration of the resonator for increased particle collection area, increased thermophoretic collection efficiency using an increased temperature gradient, and shielding the resonator electronics from deposition of ultrafine particles.

  16. Measurements of particulate matter concentrations at a landfill site (Crete, Greece)

    SciTech Connect (OSTI)

    Chalvatzaki, E.; Kopanakis, I. [Department of Environmental Engineering, Technical University of Crete, Chania 73100, Crete (Greece); Kontaksakis, M. [Municipal Company of Solid Waste Management, Chania 73100, Crete (Greece); Glytsos, T.; Kalogerakis, N. [Department of Environmental Engineering, Technical University of Crete, Chania 73100, Crete (Greece); Lazaridis, M., E-mail: lazaridi@mred.tuc.g [Department of Environmental Engineering, Technical University of Crete, Chania 73100, Crete (Greece)

    2010-11-15T23:59:59.000Z

    Large amounts of solid waste are disposed in landfills and the potential of particulate matter (PM) emissions into the atmosphere is significant. Particulate matter emissions in landfills are the result of resuspension from the disposed waste and other activities such as mechanical recycling and composting, waste unloading and sorting, the process of coating residues and waste transport by trucks. Measurements of ambient levels of inhalable particulate matter (PM{sub 10}) were performed in a landfill site located at Chania (Crete, Greece). Elevated PM{sub 10} concentrations were measured in the landfill site during several landfill operations. It was observed that the meteorological conditions (mainly wind velocity and temperature) influence considerably the PM{sub 10} concentrations. Comparison between the PM{sub 10} concentrations at the landfill and at a PM{sub 10} background site indicates the influence of the landfill activities on local concentrations at the landfill. No correlation was observed between the measurements at the landfill and the background sites. Finally, specific preventing measures are proposed to control the PM concentrations in landfills.

  17. Simulating the Impact of Premixed Charge Compression Ignition on Light-Duty Diesel Fuel Economy and Emissions of Particulates and NOx

    SciTech Connect (OSTI)

    Gao, Zhiming [ORNL; Daw, C Stuart [ORNL; Wagner, Robert M [ORNL; Edwards, Kevin Dean [ORNL; Smith, David E [ORNL

    2013-01-01T23:59:59.000Z

    We utilize the Powertrain Systems Analysis Toolkit (PSAT) combined with transient engine and aftertreatment component models implemented in Matlab/Simulink to simulate the effect of premixed charge compression ignition (PCCI) on the fuel economy and emissions of light-duty diesel-powered conventional and hybrid electric vehicles (HEVs). Our simulated engine is capable of both conventional diesel combustion (CDC) and premixed charge compression ignition (PCCI) over real transient driving cycles. Our simulated aftertreatment train consists of a diesel oxidation catalyst (DOC), lean NOx trap (LNT), and catalyzed diesel particulate filter (DPF). The results demonstrate that, in the simulated conventional vehicle, PCCI can significantly reduce fuel consumption and emissions by reducing the need for LNT and DPF regeneration. However, the opportunity for PCCI operation in the simulated HEV is limited because the engine typically experiences higher loads and multiple stop-start transients that are outside the allowable PCCI operating range. Thus developing ways of extending the PCCI operating range combined with improved control strategies for engine and emissions control management will be especially important for realizing the potential benefits of PCCI in HEVs.

  18. Exposure to airborne metals and particulate matter and risk for youth adjudicated for criminal activity

    SciTech Connect (OSTI)

    Haynes, Erin N., E-mail: Erin.Haynes@uc.edu [College of Medicine, Department of Environmental Health, University of Cincinnati, Cincinnati, OH 45267 (United States); Chen, Aimin, E-mail: Aimin.Chen@uc.edu [College of Medicine, Department of Environmental Health, University of Cincinnati, Cincinnati, OH 45267 (United States)] [College of Medicine, Department of Environmental Health, University of Cincinnati, Cincinnati, OH 45267 (United States); Ryan, Patrick, E-mail: Patrick.Ryan@uc.edu [College of Medicine, Department of Environmental Health, University of Cincinnati, Cincinnati, OH 45267 (United States)] [College of Medicine, Department of Environmental Health, University of Cincinnati, Cincinnati, OH 45267 (United States); Succop, Paul, E-mail: Paul.Succop@uc.edu [College of Medicine, Department of Environmental Health, University of Cincinnati, Cincinnati, OH 45267 (United States)] [College of Medicine, Department of Environmental Health, University of Cincinnati, Cincinnati, OH 45267 (United States); Wright, John, E-mail: John.Wright@uc.edu [College of Education, Criminal Justice, and Human Services, University of Cincinnati, Cincinnati, OH 45221 (United States)] [College of Education, Criminal Justice, and Human Services, University of Cincinnati, Cincinnati, OH 45221 (United States); Dietrich, Kim N., E-mail: Kim.Dietrich@uc.edu [College of Medicine, Department of Environmental Health, University of Cincinnati, Cincinnati, OH 45267 (United States)

    2011-11-15T23:59:59.000Z

    Antisocial behavior is a product of multiple interacting sociohereditary variables, yet there is increasing evidence that metal exposure, particularly, manganese and lead, play a role in its epigenesis. Other metals, such as arsenic, cadmium, chromium, and mercury, and exposure to traffic-related air pollution, such as fine particulate matter ({<=}2.5 {mu}m) have been associated with neurological deficits, yet largely unexplored with respect to their relationship with delinquent behavior. The purpose of this study is to evaluate the ecological relationship between county-wide reported airborne emissions of air metals, particulate matter, and youth adjudicated for criminal activity. Metal exposure data were collected from the Environmental Protection Agency AirData. Population statistics were obtained from the United States Census 2000 and adjudication data was obtained from the Courts of Common Pleases from each Ohio County. Simple correlations were calculated with the percentage of adjudications, all covariates, and estimated metal air emissions. Separate negative binomial regression models for each pollutant were used to provide an estimated risk ratio of pollutant emissions on the risk of adjudication for all Ohio counties adjusting for urban-rural residence, percentage of African Americans, median family income, percentage of family below poverty, percentage of high school graduation in 25 years and older populations, and population density. Metal emissions and PM in 1999 were all correlated with adjudication rate (2003-2005 average). Metal emissions were associated with slightly higher risk of adjudication, with about 3-4% increased risk per natural log unit of metal emission except chromium. The associations achieved statistical significance for manganese and mercury. The particulate matter {<=}2.5 and {<=}10 {mu}m emissions had a higher risk estimate, with 12% and 19% increase per natural log unit emission, respectively, and also achieved statistical significance. In summary, airborne exposure to manganese, mercury, and particulate matter are associated with increased risk of adjudication. Causality cannot be proven in observational studies such as this one, but the association warrants further examination in other research studies. Comprehensive epidemiologic investigations of metal exposure in pediatric populations should include social health outcomes, including measures of delinquent or criminal activity. Furthermore, the influence of metals on the neurotoxic pathway leading to delinquent activity should be further explored. - Highlights: Black-Right-Pointing-Pointer We evaluate the relationship between air pollutants and adjudication. Black-Right-Pointing-Pointer Manganese, mercury, and particulate matter are associated with risk of adjudication. Black-Right-Pointing-Pointer Further research of metal exposure should include social health outcomes.

  19. Characterization of particulate matter deposited in diesel particulate filters: Visual and analytical approach in macro-, micro- and nano-scales

    SciTech Connect (OSTI)

    Liati, Anthi; Dimopoulos Eggenschwiler, Panayotis [EMPA, Swiss Federal Laboratories for Materials Testing and Research, Laboratory for I.C. Engines, Duebendorf (Switzerland)

    2010-09-15T23:59:59.000Z

    Multi-scale analytical investigations of particulate matter (soot and ash) of two loaded diesel particulate filters (DPF) from (a) a truck (DPF1) and (b) a passenger car (DPF2) reveal the following: in DPF1 (without fuel-borne additives), soot aggregates form an approximately 130-270 {mu}m thick, homogeneous porous cake with pronounced orientation. Soot aggregates consist of 15-30 nm large individual particles exhibiting relatively mature internal nanostructures, however, far from being graphite. Ash aggregates largely accumulate at the outlet part of DPF1, while minor amounts are deposited directly on the channel walls all along the filter length. They consist of crystalline phases with individual particles of sizes down to the nanoscale range. Chemically, the ash consists mainly of Mg, S, Ca, Zn and P, elements encountered in lubricating oil additives. In the passenger car DPF2 (with fuel-borne additives), soot aggregates form an approximately 200-500 {mu}m thick, inhomogeneous porous cake consisting of several superposed layers corresponding to different soot generations. The largest part of the soot cake is composed of unburned, oriented soot aggregates left behind despite repeated regenerations, while a small part constitutes a loose layer with randomly oriented aggregates, which was deposited last and has not seen any regeneration. Fe-oxide particles of micro- to nano-scale sizes, originating from the fuel-borne additive, are often dispersed within the part of the soot cake composed of the unburned soot leftovers. The individual soot nanoparticles in DPF2 are approximately 15-40 nm large and generally less mature than in the truck DPF1. The presence of soot leftovers in DPF2 indicates that the addition of fuel-borne material does not fully compensate for the temperatures needed for complete soot removal. Ash in DPF2 is filling up more than half of the filter volume (at the downstream part) and is dominated by Fe-oxide aggregates, due to the Fe-based fuel-borne additive, but otherwise its chemical composition reflects compounds of lubricating oil additives. (author)

  20. Characterization of ambient particulate matter in the Paso del Norte region

    SciTech Connect (OSTI)

    Li, W.W.; Currey, R.M.; Valenzuela, V.H.; Meuzelaar, H.L.C.; Sheya, S.A.; Anderson, J.R.; Banerjee, S.; Griffin, J.B.

    1999-07-01T23:59:59.000Z

    Air pollution in the Paso del Norte region, where West Texas abuts the southern boundary of New Mexico and the northern boundary of Chihuahua, Mexico is a common concern to the residents on both sides of the border. Parts of the region fail to meet the US and Mexican Ambient Air Quality Standards for particulate matter, ozone, and carbon monoxide. The regional air pollution problem is complicated due to arid climate, complex terrain topography, frequently occurring temperature inversions, extensive unpaved urban areas, an aging and poorly maintained vehicle fleet, and a number of other uncontrolled anthropogenic emission sources. The issue is further complicated by concerns arising from recent scientific evidence of the health effects associated with exposures to fine particulate matter. A study designed to address particulate matter (PM) air pollution problems in the region is currently undertaken by researchers from member universities of the Southwest Center for Environmental Research and Policy and several governmental agencies. The study attempts to (1) characterize the fine fraction of PM; (2) identify and characterize the major regional emission sources; (3) apportion the fine fraction of PM to the source emissions; and (4) establish a regional technological information clearinghouse. The short-term goal of this research is to initiate a research program to characterize, identify, and quantify the sources and nature of the PM in the region. The long-term goal of this study is to establish regional research capabilities to continue air quality monitoring, evaluation, modeling, and control after the implementation of the study. A scoping study to collect regional PM was conducted in December 1998.

  1. Assessment of Contribution of Contemporary Carbon Sources to Size-Fractionated Particulate Matter and Time-Resolved Bulk Particulate Matter Using the Measurement of Radiocarbon

    SciTech Connect (OSTI)

    Hwang, H M; Young, T M; Buchholz, B A

    2009-04-16T23:59:59.000Z

    This study was motivated by a desire to improve understanding of the sources contributing to the carbon that is an important component of airborne particulate matter (PM). The ultimate goal of this project was to lay a ground work for future tools that might be easily implemented with archived or routinely collected samples. A key feature of this study was application of radiocarbon measurement that can be interpreted to indicate the relative contributions from fossil and non-fossil carbon sources of atmospheric PM. Size-resolved PM and time-resolved PM{sub 10} collected from a site in Sacramento, CA in November 2007 (Phase I) and March 2008 (Phase II) were analyzed for radiocarbon and source markers such as levoglucosan, cholesterol, and elemental carbon. Radiocarbon data indicates that the contributions of non-fossil carbon sources were much greater than that from fossil carbon sources in all samples. Radiocarbon and source marker measurements confirm that a greater contribution of non-fossil carbon sources in Phase I samples was highly likely due to residential wood combustion. The present study proves that measurement of radiocarbon and source markers can be readily applied to archived or routinely collected samples for better characterization of PM sources. More accurate source apportionment will support ARB in developing more efficient control strategies.

  2. Fluxes, dynamics and chemistry of suspended particulate matter in a southeast Alaskan fjord

    SciTech Connect (OSTI)

    Hong, G.H.

    1986-01-01T23:59:59.000Z

    The weighted mean fluxes over the June 1982-October 1983 were 290, 519, 812, 1124 g m/sup -2/ yr/sup -1/, respectively, determined using sediment traps deployed at 40, 120, 300 and 375 m depth in the 380 m water column. The long-term sedimentation rate was estimated at average 589 g m/sup -2/ yr/sup -1/ from sediment /sup 210/Pb profiles. Substantial SPM input to mid-depths (below 100 m) from the side arms was noted. Thus, the flux measured at 120 m depth was designated as the primary flux of the SPM to the basin. The sediment focusing resulting from the V shaped basin does not appear to be important. Using particulate Al as a tracer, resuspension rate was estimated at some 30-80% of the vertical flux below 280 m depth. Based on the SPM dynamics, the non-conservative behavior of particulate biogenic matter, Mn and Fe was investigated using a primary-resuspended-altered flux model.

  3. Apportionment of ambient primary and secondary fine particulate matter during a 2001 summer intensive study at the CMU Supersite and NETL Pittsburgh Site

    SciTech Connect (OSTI)

    Delbert J. Eatough; Nolan F. Mangelson; Richard R. Anderson (and others) [Brigham Young University, Provo, UT (United States). Department of Chemistry and Biochemistry

    2007-10-15T23:59:59.000Z

    Gaseous and particulate pollutant concentrations associated with five samples per day collected during a July 2001 summer intensive study at the Pittsburgh Carnegie Mellon University (CMU) Supersite were used to apportion fine particulate matter (PM2.5) into primary and secondary contributions using PMF2. Input to the PMF2 analysis included the concentrations of PM2.5 nonvolatile and semivolatile organic material, elemental carbon (EC), ammonium sulfate, trace element components, gas-phase organic material, and NOx, NO{sub 2}, and O{sub 3} concentrations. A total of 10 factors were identified. These factors are associated with emissions from various sources and facilities including crustal material, gasoline combustion, diesel combustion, and three nearby sources high in trace metals. In addition, four secondary sources were identified, three of which were associated with secondary products of local emissions and were dominated by organic material and one of which was dominated by secondary ammonium sulfate transported to the CMU site from the west and southwest. The three largest contributors to PM2.5 were secondary transported material (dominated by ammonium sulfate) from the west and southwest from sources including coal-fired power plants, coke processing plants and steel mills, (49%), secondary material formed during midday photochemical processes (24%), and gasoline combustion emissions (11%). The other seven sources accounted for the remaining 16% of the PM2.5. Results obtained at the CMU site were comparable to results previously reported at the National Energy Technology Laboratory (NETL), located approximately 18 km south of downtown Pittsburgh. The major contributor at both sites was material transported from the west and southwest. Some difference in nearby sources could be attributed to meteorology as evaluated by HYSPLIT model back-trajectory calculations. 27 refs., 16 figs., 1 tab.

  4. SIZE DISTRIBUTION AND RATE OF PRODUCTION OF AIRBORNE PARTICULATE MATTER GENERATED DURING METAL CUTTING

    SciTech Connect (OSTI)

    M.A. Ebadian, Ph.D.; S.K. Dua, Ph.D., C.H.P.; Hillol Guha, Ph.D.

    2001-01-01T23:59:59.000Z

    During deactivation and decommissioning activities, thermal cutting tools, such as plasma torch, laser, and gasoline torch, are used to cut metals. These activities generate fumes, smoke and particulates. These airborne species of matter, called aerosols, may be inhaled if suitable respiratory protection is not used. Inhalation of the airborne metallic aerosols has been reported to cause ill health effects, such as acute respiratory syndrome and chromosome damage in lymphocytes. In the nuclear industry, metals may be contaminated with radioactive materials. Cutting these metals, as in size reduction of gloveboxes and tanks, produces high concentrations of airborne transuranic particles. Particles of the respirable size range (size < 10 {micro}m) deposit in various compartments of the respiratory tract, the fraction and the site in the respiratory tract depending on the size of the particles. The dose delivered to the respiratory tract depends on the size distribution of the airborne particulates (aerosols) and their concentration and radioactivity/toxicity. The concentration of airborne particulate matter in an environment is dependent upon the rate of their production and the ventilation rate. Thus, measuring aerosol size distribution and generation rate is important for (1) the assessment of inhalation exposures of workers, (2) the selection of respiratory protection equipment, and (3) the design of appropriate filtration systems. Size distribution of the aerosols generated during cutting of different metals by plasma torch was measured. Cutting rates of different metals, rate of generation of respirable mass, as well as the fraction of the released kerf that become respirable were determined. This report presents results of these studies. Measurements of the particles generated during cutting of metal plates with a plasma arc torch revealed the presence of particles with mass median aerodynamic diameters of particles close to 0.2 {micro}m, arising from condensation of vaporized material and subsequent rapid formation of aggregates. Particles of larger size, resulting from ejection of melted material or fragments from the cutting zone, were also observed. This study presents data regarding the metal cutting rate, particle size distribution, and their generation rate, while using different cutting tools and metals. The study shows that respirable particles constitute only a small fraction of the released kerf.

  5. EVALUATION OF THE EMISSION, TRANSPORT, AND DEPOSITION OF MERCURY, FINE PARTICULATE MATTER, AND ARSENIC FROM COAL-BASED POWER PLANTS IN THE OHIO RIVER VALLEY REGION

    SciTech Connect (OSTI)

    Kevin Crist

    2004-10-02T23:59:59.000Z

    Ohio University, in collaboration with CONSOL Energy, Advanced Technology Systems, Inc (ATS) and Atmospheric and Environmental Research, Inc. (AER) as subcontractors, is evaluating the impact of emissions from coal-fired power plants in the Ohio River Valley region as they relate to the transport and deposition of mercury, arsenic, and associated fine particulate matter. This evaluation will involve two interrelated areas of effort: ambient air monitoring and regional-scale modeling analysis. The scope of work for the ambient air monitoring will include the deployment of a surface air monitoring (SAM) station in southeastern Ohio. The SAM station will contain sampling equipment to collect and measure mercury (including speciated forms of mercury and wet and dry deposited mercury), arsenic, particulate matter (PM) mass, PM composition, and gaseous criteria pollutants (CO, NOx, SO{sub 2}, O{sub 3}, etc.). Laboratory analysis of time-integrated samples will be used to obtain chemical speciation of ambient PM composition and mercury in precipitation. Near-real-time measurements will be used to measure the ambient concentrations of PM mass and all gaseous species including Hg{sup 0} and RGM. Approximately of 18 months of field data will be collected at the SAM site to validate the proposed regional model simulations for episodic and seasonal model runs. The ambient air quality data will also provide mercury, arsenic, and fine particulate matter data that can be used by Ohio Valley industries to assess performance on multi-pollutant control systems. The scope of work for the modeling analysis will include (1) development of updated inventories of mercury and arsenic emissions from coal plants and other important sources in the modeled domain; (2) adapting an existing 3-D atmospheric chemical transport model to incorporate recent advancements in the understanding of mercury transformations in the atmosphere; (3) analyses of the flux of Hg{sup 0}, RGM, arsenic, and fine particulate matter in the different sectors of the study region to identify key transport mechanisms; (4) comparison of cross correlations between species from the model results to observations in order to evaluate characteristics of specific air masses associated with long-range transport from a specified source region; and (5) evaluation of the sensitivity of these correlations to emissions from regions along the transport path. This will be accomplished by multiple model runs with emissions simulations switched on and off from the various source regions. To the greatest extent possible, model results will also be compared to field data collected at other air monitoring sites in the Ohio Valley region, operated independently of this project. These sites may include (1) the DOE National Energy Technologies Laboratory's monitoring site at its suburban Pittsburgh, PA facility; (2) sites in Pittsburgh (Lawrenceville) PA and Holbrook, PA operated by ATS; (3) sites in Steubenville, OH and Pittsburgh, PA operated by U.S. EPA and/or its contractors; and (4) sites operated by State or local air regulatory agencies. Field verification of model results and predictions will provide critical information for the development of cost effective air pollution control strategies by the coal-fired power plants in the Ohio River Valley region.

  6. EVALUATION OF THE EMISSION, TRANSPORT, AND DEPOSITION OF MERCURY, FINE PARTICULATE MATTER, AND ARSENIC FROM COAL-BASED POWER PLANTS IN THE OHIO RIVER VALLEY REGION

    SciTech Connect (OSTI)

    Kevin Crist

    2004-04-02T23:59:59.000Z

    Ohio University, in collaboration with CONSOL Energy, Advanced Technology Systems, Inc. (ATS) and Atmospheric and Environmental Research, Inc. (AER) as subcontractors, is evaluating the impact of emissions from coal-fired power plants in the Ohio River Valley region as they relate to the transport and deposition of mercury, arsenic, and associated fine particulate matter. This evaluation will involve two interrelated areas of effort: ambient air monitoring and regional-scale modeling analysis. The scope of work for the ambient air monitoring will include the deployment of a surface air monitoring (SAM) station in southeastern Ohio. The SAM station will contain sampling equipment to collect and measure mercury (including speciated forms of mercury and wet and dry deposited mercury), arsenic, particulate matter (PM) mass, PM composition, and gaseous criteria pollutants (CO, NOx, SO{sub 2}, O{sub 3}, etc.). Laboratory analysis of time-integrated samples will be used to obtain chemical speciation of ambient PM composition and mercury in precipitation. Near-real-time measurements will be used to measure the ambient concentrations of PM mass and all gaseous species including Hg{sup 0} and RGM. Approximately 18 months of field data will be collected at the SAM site to validate the proposed regional model simulations for episodic and seasonal model runs. The ambient air quality data will also provide mercury, arsenic, and fine particulate matter data that can be used by Ohio Valley industries to assess performance on multi-pollutant control systems. The scope of work for the modeling analysis will include (1) development of updated inventories of mercury and arsenic emissions from coal-fired power plants and other important sources in the modeled domain; (2) adapting an existing 3-D atmospheric chemical transport model to incorporate recent advancements in the understanding of mercury transformations in the atmosphere; (3) analyses of the flux of Hg{sup 0}, RGM, arsenic, and fine particulate matter in the different sectors of the study region to identify key transport mechanisms; (4) comparison of cross correlations between species from the model results to observations in order to evaluate characteristics of specific air masses associated with long-range transport from a specified source region; and (5) evaluation of the sensitivity of these correlations to emissions from regions along the transport path. This will be accomplished by multiple model runs with emissions simulations switched on and off from the various source regions. To the greatest extent possible, model results will also be compared to field data collected at other air monitoring sites in the Ohio Valley Region, operated independently of this project. These sites may include (1) the DOE National Energy Technology Laboratory's monitoring site at its suburban Pittsburgh, PA facility; (2) sites in Pittsburgh (Lawrenceville) PA and Holbrook, PA operated by ATS; (3) sites in Steubenville, OH and Pittsburgh, PA operated by U.S. EPA and/or its contractors; and (4) sites operated by State or local air regulatory agencies. Field verification of model results and predictions will provide critical information for the development of cost effective air pollution control strategies by the coal-fired power plants in the Ohio River Valley region.

  7. Evaluation of the Emission, Transport, and Deposition of Mercury, Fine Particulate Matter, and Arsenic from Coal-Based Power Plants in the Ohio River Valley Region

    SciTech Connect (OSTI)

    Kevin Crist

    2005-10-02T23:59:59.000Z

    Ohio University, in collaboration with CONSOL Energy, Advanced Technology Systems, Inc (ATS) and Atmospheric and Environmental Research, Inc. (AER) as subcontractors, is evaluating the impact of emissions from coal-fired power plants in the Ohio River Valley region as they relate to the transport and deposition of mercury, arsenic, and associated fine particulate matter. This evaluation will involve two interrelated areas of effort: ambient air monitoring and regional-scale modeling analysis. The scope of work for the ambient air monitoring will include the deployment of a surface air monitoring (SAM) station in southeastern Ohio. The SAM station will contain sampling equipment to collect and measure mercury (including speciated forms of mercury and wet and dry deposited mercury), arsenic, particulate matter (PM) mass, PM composition, and gaseous criteria pollutants (CO, NOx, SO{sub 2}, O{sub 3}, etc.). Laboratory analysis of time-integrated samples will be used to obtain chemical speciation of ambient PM composition and mercury in precipitation. Near-real-time measurements will be used to measure the ambient concentrations of PM mass and all gaseous species including Hg{sup 0} and RGM. Approximately of 18 months of field data will be collected at the SAM site to validate the proposed regional model simulations for episodic and seasonal model runs. The ambient air quality data will also provide mercury, arsenic, and fine particulate matter data that can be used by Ohio Valley industries to assess performance on multi-pollutant control systems. The scope of work for the modeling analysis will include (1) development of updated inventories of mercury and arsenic emissions from coal plants and other important sources in the modeled domain; (2) adapting an existing 3-D atmospheric chemical transport model to incorporate recent advancements in the understanding of mercury transformations in the atmosphere; (3) analyses of the flux of Hg0, RGM, arsenic, and fine particulate matter in the different sectors of the study region to identify key transport mechanisms; (4) comparison of cross correlations between species from the model results to observations in order to evaluate characteristics of specific air masses associated with long-range transport from a specified source region; and (5) evaluation of the sensitivity of these correlations to emissions from regions along the transport path. This will be accomplished by multiple model runs with emissions simulations switched on and off from the various source regions. To the greatest extent possible, model results will also be compared to field data collected at other air monitoring sites in the Ohio Valley region, operated independently of this project. These sites may include (1) the DOE National Energy Technologies Laboratory's monitoring site at its suburban Pittsburgh, PA facility; (2) sites in Pittsburgh (Lawrenceville) PA and Holbrook, PA operated by ATS; (3) sites in Steubenville, OH and Pittsburgh, PA operated by U.S. EPA and/or its contractors; and (4) sites operated by State or local air regulatory agencies. Field verification of model results and predictions will provide critical information for the development of cost effective air pollution control strategies by the coal-fired power plants in the Ohio River Valley region.

  8. Evaluation of the Emission, Transport, and Deposition of Mercury and Fine Particulate Matter from Coal-Based Power Plants in the Ohio River Valley Region

    SciTech Connect (OSTI)

    Kevin Crist

    2008-12-31T23:59:59.000Z

    As stated in the proposal: Ohio University, in collaboration with CONSOL Energy, Advanced Technology Systems, Inc (ATS) and Atmospheric and Environmental Research, Inc. (AER) as subcontractors, evaluated the impact of emissions from coal-fired power plants in the Ohio River Valley region as they relate to the transport and deposition of mercury and associated fine particulate matter. This evaluation involved two interrelated areas of effort: ambient air monitoring and regional-scale modeling analysis. The scope of work for the ambient air monitoring included the deployment of a surface air monitoring (SAM) station in southeastern Ohio. The SAM station contains sampling equipment to collect and measure mercury (including speciated forms of mercury and wet and dry deposited mercury), particulate matter (PM) mass, PM composition, and gaseous criteria pollutants (CO, NOx, SO2, O3, etc.). Laboratory analyses of time-integrated samples were used to obtain chemical speciation of ambient PM composition and mercury in precipitation. Nearreal- time measurements were used to measure the ambient concentrations of PM mass and all gaseous species including Hg0 and RGM. Approximately 30 months of field data were collected at the SAM site to validate the proposed regional model simulations for episodic and seasonal model runs. The ambient air quality data provides mercury, and fine particulate matter data that can be used by Ohio Valley industries to assess performance on multi-pollutant control systems. The scope of work for the modeling analysis includes (1) development of updated inventories of mercury emissions from coal plants and other important sources in the modeled domain; (2) adapting an existing 3-D atmospheric chemical transport model to incorporate recent advancements in the understanding of mercury transformations in the atmosphere; (3) analyses of the flux of Hg0, RGM, and fine particulate matter in the different sectors of the study region to identify key transport mechanisms; (4) comparison of cross correlations between species from the model results to observations in order to evaluate characteristics of specific air masses associated with long-range transport from a specified source region; and (5) evaluation of the sensitivity of these correlations to emissions from regions along the transport path. This is accomplished by multiple model runs with emissions simulations switched on and off from the various source regions. To the greatest extent possible, model results were compared to field data collected at other air monitoring sites in the Ohio Valley region, operated independently of this project. These sites may include (1) the DOE National Energy Technologies Laboratory’s monitoring site at its suburban Pittsburgh, PA facility; (2) sites in Pittsburgh (Lawrenceville) PA and Holbrook, PA operated by ATS; (3) sites in Steubenville, OH and Pittsburgh, PA operated by the USEPA and/or its contractors; and (4) sites operated by State or local air regulatory agencies. Field verification of model results and predictions provides critical information for the development of cost effective air pollution control strategies by the coal-fired power plants in the Ohio River Valley region.

  9. Hydrocarbon-enhanced particulate filter regeneration via microwave ignition

    DOE Patents [OSTI]

    Gonze, Eugene V. (Pinckney, MI); Brown, David B. (Brighton, MI)

    2010-02-02T23:59:59.000Z

    A regeneration method for a particulate filter includes estimating a quantity of particulate matter trapped within the particulate filter, comparing the quantity of particulate matter to a predetermined quantity, heating at least a portion of the particulate filter to a combustion temperature of the particulate matter, and introducing hydrocarbon fuel to the particulate filter. The hydrocarbon fuel facilitates combustion of the particulate matter to regenerate the particulate filter.

  10. Evaluating point and process fugitive emission sources of particulate matter from feed mills associated with cattle feed yards

    E-Print Network [OSTI]

    Demny, Michael Alan

    1997-01-01T23:59:59.000Z

    . Emission factors for feed mills (Shannon et al. , 1974) Table 2. 1988 AP-42 emission factors for feed mills Table 3. Intemn AP-42 emission actors for grain elevators 12 Table 4. Proposed emission factors for feed mills 14 Table 5. Source sampling... grain handling gtcilities. Prior to this legislation, the validity of the particulate matter emission gtctors for animal feed mills was not questioned. The emission factors for grain handling facilities in the 1988 AP-42 were established in order...

  11. Novel Collection and Toxicological Analysis Techniques for IC Engine Exhaust Particulate Matter

    SciTech Connect (OSTI)

    Michael Keane; Xiao-Chun Shi; Tong-man Ong

    2008-09-30T23:59:59.000Z

    The project staff partnered with Costas Sioutas from the University of Southern California to apply the VACES (Versatile Aerosol Concentration Enhancement System) to a diesel engine test facility at West Virginia University Department of Mechanical Engineering and later the NIOSH Lake Lynn Mine facility. The VACES system was able to allow diesel exhaust particulate matter (DPM) to grow to sufficient particle size to be efficiently collected with the SKC Biosampler impinger device, directly into a suspension of simulated pulmonary surfactant. At the WVU-MAE facility, the concentration of the aerosol was too high to allow efficient use of the VACES concentration enhancement, although aerosol collection was successful. Collection at the LLL was excellent with the diluted exhaust stream. In excess of 50 samples were collected at the LLL facility, along with matching filter samples, at multiple engine speed and load conditions. Replicate samples were combined and concentration increased using a centrifugal concentrator. Bioassays were negative for all tested samples, but this is believed to be due to insufficient concentration in the final assay suspensions.

  12. Exposure assessment of particulate matter air pollution before, during, and after the 2003 Southern California wildfires

    E-Print Network [OSTI]

    Wu, J; Winer, A M; Delfino, R J

    2006-01-01T23:59:59.000Z

    Ostra, B. , 1997. Air pollution and emergency room visitsJ. , 1994. Indoor air pollution and asthma: Results from aof unmeasured particulate air pollution data for an

  13. Characterization of Fine Particulate Matter (PM) and Secondary PM Precursor Gases in the Mexico City Metropolitan Area

    SciTech Connect (OSTI)

    Luisa T. Molina, Rainer Volkamer, Benjamin de Foy, Wenfang Lei, Miguel Zavala, Erik Velasco; Mario J. Molina

    2008-10-31T23:59:59.000Z

    This project was one of three collaborating grants funded by DOE/ASP to characterize the fine particulate matter (PM) and secondary PM precursors in the Mexico City Metropolitan Area (MCMA) during the MILAGRO Campaign. The overall effort of MCMA-2006, one of the four components, focused on i) examination of the primary emissions of fine particles and precursor gases leading to photochemical production of atmospheric oxidants and secondary aerosol particles; ii) measurement and analysis of secondary oxidants and secondary fine PM production, with particular emphasis on secondary organic aerosol (SOA), and iii) evaluation of the photochemical and meteorological processes characteristic of the Mexico City Basin. The collaborative teams pursued the goals through three main tasks: i) analyses of fine PM and secondary PM precursor gaseous species data taken during the MCMA-2002/2003 campaigns and preparation of publications; ii) planning of the MILAGRO Campaign and deployment of the instrument around the MCMA; and iii) analysis of MCMA-2006 data and publication preparation. The measurement phase of the MILAGRO Campaign was successfully completed in March 2006 with excellent participation from the international scientific community and outstanding cooperation from the Mexican government agencies and institutions. The project reported here was led by the Massachusetts Institute of Technology/Molina Center for Energy and the Environment (MIT/MCE2) team and coordinated with DOE/ASP-funded collaborators at Aerodyne Research Inc., University of Colorado at Boulder and Montana State University. Currently 24 papers documenting the findings from this project have been published. The results from the project have improved significantly our understanding of the meteorological and photochemical processes contributing to the formation of ozone, secondary aerosols and other pollutants. Key findings from the MCMA-2003 include a vastly improved speciated emissions inventory from on-road vehicles: the MCMA motor vehicles produce abundant amounts of primary PM, elemental carbon, particle-bound polycyclic aromatic hydrocarbons, carbon monoxide and a wide range of air toxics; the feasibility of using eddy covariance techniques to measure fluxes of volatile organic compounds in an urban core and a valuable tool for validating local emissions inventory; a much better understanding of the sources and atmospheric loadings of volatile organic compounds; the first spectroscopic detection of glyoxal in the atmosphere; a unique analysis of the high fraction of ambient formaldehyde from primary emission sources; characterization of ozone formation and its sensitivity to VOCs and NOx; a much more extensive knowledge of the composition, size distribution and atmospheric mass loadings of both primary and secondary fine PM, including the fact that the rate of MCMA SOA production greatly exceeded that predicted by current atmospheric models; evaluations of significant errors that can arise from standard air quality monitors for O3 and NO2; and the implementation of an innovative Markov Chain Monte Carlo method for inorganic aerosol modeling as a powerful tool to analyze aerosol data and predict gas phase concentrations where these are unavailable. During the MILAGRO Campaign the collaborative team utilized a combination of central fixed sites and a mobile laboratory deployed throughout the MCMA to representative urban and boundary sites to measure trace gases and fine particles. Analysis of the extensive 2006 data sets has confirmed the key findings from MCMA-2002/2003; additionally MCMA-2006 provided more detailed gas and aerosol chemistry and wider regional scale coverage. Key results include an updated 2006 emissions inventory; extension of the flux system to measure fluxes of fine particles; better understanding of the sources and apportionment of aerosols, including contribution from biomass burning and industrial sources; a comprehensive evaluation of metal containing particles in a complex urban environment; identification of a close correlation between

  14. SOURCE SIGNATURES OF FINE PARTICULATE MATTER FROM PETROLEUM REFINING AND FUEL USE

    SciTech Connect (OSTI)

    Gerald P. Huffman; Frank E. Huggins; Naresh Shah; Artur Braun; Yuanzhi Chen; J. David Robertson; Joseph Kyger; Adel F. Sarofim; Ronald J. Pugmire; Henk L.C. Meuzelaar; JoAnn Lighty

    2003-07-31T23:59:59.000Z

    The molecular structure and microstructure of a suite of fine particulate matter (PM) samples produced by the combustion of residual fuel oil and diesel fuel were investigated by an array of analytical techniques. Some of the more important results are summarized below. Diesel PM (DPM): A small diesel engine test facility was used to generate a suite of diesel PM samples from different fuels under engine load and idle conditions. C XANES, {sup 13}C NMR, XRD, and TGA were in accord that the samples produced under engine load conditions contained more graphitic material than those produced under idle conditions, which contained a larger amount of unburned diesel fuel and lubricating oil. The difference was enhanced by the addition of 5% of oxygenated compounds to the reference fuel. Scanning transmission x-ray micro-spectroscopy (STXM) was able to distinguish particulate regions rich in C=C bonds from regions rich in C-H bonds with a resolution of {approx}50 nm. The former are representative of more graphitic regions and the latter of regions rich in unburned fuel and oil. The dominant microstructure observed by SEM and TEM consisted of complex chain-like structures of PM globules {approx}20-100 nm in mean diameter, with a high fractal dimension. High resolution TEM revealed that the graphitic part of the diesel soot consisted of onion-like structures made up of graphene layers. Typically 3-10 graphene layers make up the ''onion rings'', with the layer spacing decreasing as the number of layers increases. ROFA PM: Residual oil fly ash (ROFA) PM has been analyzed by a new approach that combines XAFS spectroscopy with selective leaching procedures. ROFA PM{sub 2.5} and PM{sub 2.5+} produced in combustion facilities at the U.S. EPA National Risk Management Research Laboratory (NRML) were analyzed by XAFS before and after leaching with water, acid (1N HCl), and pentane. Both water and acid leaching removed most of the metal sulfates, which were the dominant phase present for most metals (V, Ni, Zn, etc.). This allowed conclusive identification in the leaching residue of important secondary sulfide and oxide phases, including Ni sulfide, a toxic and carcinogenic phase observed in the leached PM{sub 2.5+} samples. Other significant secondary phases identified included V{sub 2}O{sub 4}, V sulfide, and NiFe{sub 2}O{sub 4}.

  15. 7, 1569315721, 2007 Particulate PAH

    E-Print Network [OSTI]

    Boyer, Edmond

    dioxide, particulate PAHs are most strongly correlated with NOx. Mexico City's PAH-to-black carbon mass and particu- late properties at six locations throughout the city. The measurements were intended to5 support of sources and15 ages of particles are present. Among carbon monoxide, nitrogen oxides (NOx), and carbon

  16. Diesel Particulate Filter Technology for Low-Temperature and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Filter Technology for Low-Temperature and Low-NOxPM Applications Diesel Particulate Filter Technology for Low-Temperature and Low-NOxPM Applications 2004 DEER Conference...

  17. Cashew nut roasting: Chemical characterization of particulate matter and genotocixity analysis

    SciTech Connect (OSTI)

    Oliveira Galvão, Marcos Felipe de [Programa de Pós-Graduação em Bioquímica, Universidade Federal do Rio Grande do Norte, Natal, RN (Brazil); Melo Cabral, Thiago de; André, Paulo Afonso de [Departamento de Patologia, Universidade de São Paulo, São Paulo, SP (Brazil); Fátima Andrade, Maria de; Miranda, Regina Maura de [Departamento de Ciências Atmosféricas, Universidade de São Paulo, São Paulo, SP (Brazil); Saldiva, Paulo Hilário Nascimento [Departamento de Patologia, Universidade de São Paulo, São Paulo, SP (Brazil); Castro Vasconcellos, Pérola de [Instituto de Química, Universidade de São Paulo, São Paulo, SP (Brazil); Batistuzzo de Medeiros, Silvia Regina, E-mail: sbatistu@cb.ufrn.br [Departamento de Biologia Celular e Genética, CB – UFRN, Centro de Biociências, Universidade Federal do Rio Grande do Norte, Campus Universitário, Lagoa Nova, 59072-970, Natal, RN (Brazil)

    2014-05-01T23:59:59.000Z

    Background: Particulate matter (PM) is potentially harmful to health and related to genotoxic events, an increase in the number of hospitalizations and mortality from respiratory and cardiovascular diseases. The present study conducted the first characterization of elemental composition and polycyclic aromatic hydrocarbon (PAH) analysis of PM, as well as the biomonitoring of genotoxic activity associated to artisanal cashew nut roasting, an important economic and social activity worldwide. Methods: The levels of PM{sub 2.5} and black carbon were also measured by gravimetric analysis and light reflectance. The elemental composition was determined using X-ray fluorescence spectrometry and PAH analysis was carried out by gas chromatography–mass spectrometry. Genotoxic activity was measured by the Tradescantia pallida micronucleus bioassay (Trad-MCN). Other biomarkers of DNA damage, such as nucleoplasmic bridges and nuclear fragments, were also quantified. Results: The mean amount of PM{sub 2.5} accumulated in the filters (January 2124.2 µg/m{sup 3}; May 1022.2 µg/m{sup 3}; September 1291.9 µg/m{sup 3}), black carbon (January 363.6 µg/m{sup 3}; May 70 µg/m{sup 3}; September 69.4 µg/m{sup 3}) and concentrations of Al, Si, P, S, Cl, K, Ca, Ti, Cr, Mn, Fe, Ni, Cu, Zn, Se, Br and Pb were significantly higher than the non-exposed area. Biomass burning tracers K, Cl, and S were the major inorganic compounds found. Benzo[k]fluoranthene, indene[1,2,3-c,d]pyrene, benzo[ghi]perylene, phenanthrene and benzo[b]fluoranthene were the most abundant PAHs. Mean benzo[a]pyrene-equivalent carcinogenic power values showed a significant cancer risk. The Trad-MCN bioassay revealed an increase in micronucleus frequency, 2–7 times higher than the negative control and significantly higher in all the months analyzed, possibly related to the mutagenic PAHs found. Conclusions: This study demonstrated that artisanal cashew nut roasting is a serious occupational problem, with harmful effects on workers' health. Those involved in this activity are exposed to higher PM{sub 2.5} concentrations and to 12 PAHs considered potentially mutagenic and/or carcinogenic. The Trad-MCN with T. pallida was sensitive and efficient in evaluating the genotoxicity of the components and other nuclear alterations may be used as effective biomarkers of DNA damage. - Highlights: • The cashew nut roasting generated high concentrations of particulate matter fine. • The biomass burning tracers K, Cl, S were the major inorganic compounds found. • It was identified 12 PAHs considered to be potentially mutagenic and/or carcinogenic. • The genotoxic potential of this activity was confirmed by the Trad MCN assay. • This activity is a serious occupational problem with harmful effects to health workers.

  18. Feasibility of high volume sampling for determination of total suspended particulate matter and trace metals

    SciTech Connect (OSTI)

    van der Meulen, A.; Hofschreuder, P.; van de Vate, J.F.; Oeseburg, F.

    1984-02-01T23:59:59.000Z

    The feasibility of the high volume sampling method (HVS) in extended control networks for the routine determination of total suspended particulate matter and trace metals, particularly traffic lead, has been explored. The HVS coarse particle sampling effectiveness obtained in wind tunnel studies is assumed to be indicative of the effectiveness under typical ambient meteorological conditions. For TSP, available data indicate the mass of the coarse fraction above 5 ..mu..m to range between about 10% and 90% of the total mass. Subsequently, when sampling TSP the total mass can be underestimated by up to appoximately 30%; the corresponding standard deviation is as high as approximately 15%. Differences in coarse particle sampling characteristics can result in systematic inter-HVS deviations up to 20% of the total mass. Traffic lead consists of a direct automotive tailpipe component (by and large below 30 ..mu..m) and a vehicular resuspended one (some 100-300 ..mu..m). Near the road the total (i.e., direct + resuspended) mass of traffic lead collected ranges from 70% to 120% of the direct automotive emissions; the corresponding TSP standard deviation can be as high as 15% owing to the contribution of resuspended lead. Away from the road (>50m) the resuspended component is depleted substantially due to deposition. Subsequently, the mass collected ranges between 70% and 110% of the direct lead; the standard deviation can be as high as 10%. The evaluation of the applicability of HVS under extreme wind speed situations is beyond the scope of this work. Under such conditions the coarse particle sampling effectiveness could be affected considerably. Hence under extreme situations the applicability of HVS should be left to the discretion of the user. 33 references.

  19. 2008-01-1748 An Analysis of Methods for Measuring Particulate Matter Mass

    E-Print Network [OSTI]

    Wu, Mingshen

    . The particulate organics are typically considered to be derived from diesel fuel and lubrication oil [1]. Typical PM mass speciation reveals a roughly even distribution between the organic and inorganic

  20. Exposure assessment of particulate matter air pollution before, during, and after the 2003 Southern California wildfires

    E-Print Network [OSTI]

    Wu, J; Winer, A M; Delfino, R J

    2006-01-01T23:59:59.000Z

    particulate air pollution data for an epidemiological studyOstra, B. , 1997. Air pollution and emergency room visitsJ. , 1994. Indoor air pollution and asthma: Results from a

  1. How does pulmonary exposure to particulate matter predispose the heart to increased injury after myocardial infarction? 

    E-Print Network [OSTI]

    Robertson, Sarah

    2013-07-06T23:59:59.000Z

    One of the most prevalent pollutants in urban cities is diesel exhaust particulate (DEP). Air pollution has been linked with increased risk of recurrent myocardial infarction (MI) and MI related death (Brook, 2008). This ...

  2. Source Signatures of Fine Particulate Matter from Petroleum Refining and Fuel Use

    SciTech Connect (OSTI)

    Gerald P. Huffman; Frank E. Huggins; Naresh Shah; Robert Huggins

    1999-12-31T23:59:59.000Z

    Combustion experiments were carried out on four different residual fuel oils in a 732 kW boiler. Particulate matter (PM) emission samples were separated aerodynamically by a cyclone into fractions that were nominally less than and greater than 2.5 microns in diameter. However, examination of several of the samples by computer-controlled scanning electron microscopy (CCSEM) revealed that part of the <2.5 micron fraction (PM{sub 2.5}) in fact consists of carbonaceous cenospheres and vesicular particles that range up to 10 microns in diameter. X-ray absorption fine structure (XAFS) spectroscopy data were obtained at the S, V, Ni, Fe, Cu, Zn, and As Kedges, and at the Pb L-edge. Deconvolution of the x-ray absorption near edge structure (XANES) region of the S spectra established that the dominant molecular forms of S present were sulfate (26-84% of total S) and thiophene (13-39% of total S). Sulfate was greater in the PM{sub 2.5} samples than in the >2.5 micron samples (PM{sub 2.5+}). Inorganic sulfides and elemental sulfur were present in lower percentages. The Ni XANES spectra from all of the samples agree fairly well with that of NiSO4, while most of the V spectra closely resemble that of vanadyl sulfate (VO{center_dot}SO{sub 4}{center_dot}xH{sub 2}O). The other metals investigated (Fe, Cu, Zn, and Pb) were also present predominantly as sulfates. Arsenic is present as an arsenate (As{sup +5}). X-ray diffraction patterns of the PM{sub 2.5} fraction exhibit sharp lines due to sulfate compounds (Zn, V, Ni, Ca, etc.) superimposed on broad peaks due to amorphous carbons. All of the samples contain a significant organic component, with the LOI ranging from 64 to 87 % for the PM{sub 2.5} fraction and from 88 to 97% for the PM{sub 2.5+} fraction. {sup 13}C nuclear magnetic resonance (NMR) analysis indicates that the carbon is predominantly condensed in graphitic structures. Aliphatic structure was detected in only one of seven samples examined.

  3. Method for contamination control and barrier apparatus with filter for containing waste materials that include dangerous particulate matter

    DOE Patents [OSTI]

    Pinson, P.A.

    1998-02-24T23:59:59.000Z

    A container for hazardous waste materials that includes air or other gas carrying dangerous particulate matter has incorporated barrier material, preferably in the form of a flexible sheet, and one or more filters for the dangerous particulate matter sealably attached to such barrier material. The filter is preferably a HEPA type filter and is preferably chemically bonded to the barrier materials. The filter or filters are preferably flexibly bonded to the barrier material marginally and peripherally of the filter or marginally and peripherally of air or other gas outlet openings in the barrier material, which may be a plastic bag. The filter may be provided with a backing panel of barrier material having an opening or openings for the passage of air or other gas into the filter or filters. Such backing panel is bonded marginally and peripherally thereof to the barrier material or to both it and the filter or filters. A coupling or couplings for deflating and inflating the container may be incorporated. Confining a hazardous waste material in such a container, rapidly deflating the container and disposing of the container, constitutes one aspect of the method of the invention. The chemical bonding procedure for producing the container constitutes another aspect of the method of the invention. 3 figs.

  4. Method for contamination control and barrier apparatus with filter for containing waste materials that include dangerous particulate matter

    DOE Patents [OSTI]

    Pinson, Paul A. (Idaho Falls, ID)

    1998-01-01T23:59:59.000Z

    A container for hazardous waste materials that includes air or other gas carrying dangerous particulate matter has incorporated in barrier material, preferably in the form of a flexible sheet, one or more filters for the dangerous particulate matter sealably attached to such barrier material. The filter is preferably a HEPA type filter and is preferably chemically bonded to the barrier materials. The filter or filters are preferably flexibly bonded to the barrier material marginally and peripherally of the filter or marginally and peripherally of air or other gas outlet openings in the barrier material, which may be a plastic bag. The filter may be provided with a backing panel of barrier material having an opening or openings for the passage of air or other gas into the filter or filters. Such backing panel is bonded marginally and peripherally thereof to the barrier material or to both it and the filter or filters. A coupling or couplings for deflating and inflating the container may be incorporated. Confining a hazardous waste material in such a container, rapidly deflating the container and disposing of the container, constitutes one aspect of the method of the invention. The chemical bonding procedure for producing the container constitutes another aspect of the method of the invention.

  5. Fine particulate matter source apportionment for the chemical speciation trends network site at Birmingham, Alabama, using positive matrix factorization

    SciTech Connect (OSTI)

    Baumann, K.; Jayanty, R.K.; Flanagan, J.B. [Research Triangle Institute International, NC (United States). Research Triangle Park

    2008-01-15T23:59:59.000Z

    The Positive Matrix Factorization (PMF) receptor model version 1.1 was used with data from the fine particulate matter (PM2.5) Chemical Speciation Trends Network (STN) to estimate source contributions to ambient PM2.5 in a highly industrialized urban setting in the southeastern United States. Model results consistently resolved 10 factors that are interpreted as two secondary, five industrial, one motor vehicle, one road dust, and one biomass burning sources. It was found that most PMF factors did not cleanly represent single source types and instead are 'contaminated' by other sources. Secondary particulate matter formed by atmospheric processes, such as sulfate and secondary OC, contribute the majority of ambient PM2.5 and exhibit strong seasonality 37 {+-} 10% winter vs. 55 {+-} 16% summer average. Motor vehicle emissions constitute the biggest primary PM2.5 mass contribution. In summary, this study demonstrates the utility of the EC tracer method to effectively blank-correct the OC concentrations in the STN dataset. In addition, examination of the effect of input uncertainty estimates on model results indicates that the estimated uncertainties currently being provided with the STN data may be somewhat lower than the levels needed for optimum modeling results. An appendix , available to members on the website www.awma lists stationary sources of PM2.5 within 10 km of the NHBM site and PM2.5 emissions greater than 1 ton per year. 71 refs., 7 figs., 9 tabs.

  6. Feasibility of the detection of trace elements in particulate...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of trace elements in particulate matter using online High-Resolution Aerosol Mass Spectrometry. Feasibility of the detection of trace elements in particulate matter using online...

  7. PARTICULATE CHARACTERIZATION AND ULTRA LOW-NOx BURNER FOR THE CONTROL OF NO{sub x} AND PM{sub 2.5} FOR COAL FIRED BOILERS

    SciTech Connect (OSTI)

    Ralph Bailey; Hamid Sarv; Jim Warchol; Debi Yurchison

    2001-09-30T23:59:59.000Z

    In response to the serious challenge facing coal-fired electric utilities with regards to curbing their NO{sub x} and fine particulate emissions, Babcock and Wilcox and McDermott Technology, Inc. conducted a project entitled, ''Particulate Characterization and Ultra Low-NO{sub x} Burner for the Control of NO{sub x} and PM{sub 2.5} for Coal Fired Boilers.'' The project included pilot-scale demonstration and characterization of technologies for removal of NO{sub x} and primary PM{sub 2.5} emissions. Burner development and PM{sub 2.5} characterization efforts were based on utilizing innovative concepts in combination with sound scientific and fundamental engineering principles and a state-of-the-art test facility. Approximately 1540 metric tonnes (1700 tons) of high-volatile Ohio bituminous coal were fired. Particulate sampling for PM{sub 2.5} emissions characterization was conducted in conjunction with burner testing. Based on modeling recommendations, a prototype ultra low-NO{sub x} burner was fabricated and tested at 100 million Btu/hr in the Babcock and Wilcox Clean Environment Development Facility. Firing the unstaged burner with a high-volatile bituminous Pittsburgh 8 coal at 100 million Btu/hr and 17% excess air achieved a NO{sub x} goal of 0.20 lb NO{sub 2}/million Btu with a fly ash loss on ignition (LOI) of 3.19% and burner pressure drop of 4.7 in H{sub 2}O for staged combustion. With the burner stoichiometry set at 0.88 and the overall combustion stoichiometry at 1.17, average NO{sub x} and LOI values were 0.14 lb NO{sub 2}/million Btu and 4.64% respectively. The burner was also tested with a high-volatile Mahoning 7 coal. Based on the results of this work, commercial demonstration is being pursued. Size classified fly ash samples representative of commercial low-NO{sub x} and ultra low-NO{sub x} combustion of Pittsburgh 8 coal were collected at the inlet and outlet of an ESP. The mass of size classified fly ash at the ESP outlet was sufficient to evaluate the particle size distribution, but was of insufficient size to permit reliable chemical analysis. The size classified fly ash from the inlet of the ESP was used for detailed chemical analyses. Chemical analyses of the fly ash samples from the ESP outlet using a high volume sampler were performed for comparison to the size classified results at the inlet. For all test conditions the particulate removal efficiency of the ESP exceeded 99.3% and emissions were less than the NSPS limits of {approx}48 mg/dscm. With constant combustion conditions, the removal efficiency of the ESP increased as the ESP voltage and Specific Collection Area (SCA) increased. The associated decrease in particle emissions occurred in size fractions both larger and smaller than 2.5 microns. For constant ESP voltage and SCA, the removal efficiency for the ultra low-NO{sub x} combustion ash (99.4-99.6%) was only slightly less than for the low-NO{sub x} combustion ash (99.7%). The decrease in removal efficiency was accompanied by a decrease in ESP current. The emission of PM{sub 2.5} from the ESP did not change significantly as a result of the change in combustion conditions. Most of the increase in emissions was in the size fraction greater than 2.5 microns, indicating particle re-entrainment. These results may be specific to the coal tested in this program. In general, the concentration of inorganic elements and trace species in the fly ash at the ESP inlet was dependent on the particle size fraction. The smallest particles tended to have higher concentrations of inorganic elements/trace species than larger particles. The concentration of most elements by particle size range was independent of combustion condition and the concentration of soluble ions in the fly ash showed little change with combustion condition when evaluated on a carbon free basis.

  8. Apportionment of ambient primary and secondary fine particulate matter at the Pittsburgh National Energy Laboratory particulate matter characterization site using positive matrix factorization and a potential source contributions function analysis

    SciTech Connect (OSTI)

    Donald V. Martello; Natalie J. Pekney; Richard R. Anderson (and others) [U.S. Department of Energy, Pittsburgh, PA (United States). National Energy Technology Laboratory

    2008-03-15T23:59:59.000Z

    Fine particulate matter (PM2.5) concentrations associated with 202 24-hr samples collected at the National Energy Technology Laboratory particulate matter characterization site in south Pittsburgh from October 1999 through September 2001 were used to apportion PM2.5 into primary and secondary contributions using Positive Matrix Factorization (PMF2). Input included the concentrations of PM2.5 mass determined with a Federal Reference Method (FRM) sampler, semi-volatile PM2.5 organic material, elemental carbon (EC), and trace element components of PM2.5. A total of 11 factors were identified. The results of potential source contributions function analysis using PMF2 factors and HYSPLIT-calculated back-trajectories were used to identify those factors associated with specific meteorological transport conditions. The 11 factors were identified as being associated with emissions from various specific regions and facilities including crustal material, gasoline combustion, diesel combustion, and three nearby sources high in trace metals. Three sources associated with transport from coal-fired power plants to the southeast, a combination of point sources to the northwest, and a steel mill and associated sources to the west were identified. In addition, two secondary-material-dominated sources were identified, one was associated with secondary products of local emissions and one was dominated by secondary ammonium sulfate transported to the NETL site from the west and southwest. Of these 11 factors, the four largest contributors to PM2.5 were the secondary transported material, local secondary material, diesel combustion emissions, and gasoline combustion emissions. 26 refs., 10 figs., 1 tab.

  9. Exposure to Particulate Matter and Ozone of Outdoor Origin in Singapore

    E-Print Network [OSTI]

    Gall, Elliott T; Chen, Ailu; Chang, Victor; Nazaroff, William W

    2015-01-01T23:59:59.000Z

    ulate matter (PM) or ozone, at concentration increments of ~SL, Samet JM, Dominici F. Ozone and short-term mortality inthe penetration of ambient ozone into residential buildings.

  10. Technical comments on EPA`s proposed revisions to the National Ambient Air Quality Standard for particulate matter

    SciTech Connect (OSTI)

    Lipfert, F.W.

    1997-03-01T23:59:59.000Z

    The US Environmental Protection Agency (EPA) has proposed new ambient air quality standards specifically for fine particulate matter, regulating concentrations of particles with median aerodynamic diameters less than 2.5 {mu}m (PM{sub 2.5}). Two new standards have been proposed: a maximum 24-hr concentration that is intended to protect against acute health effects, and an annual concentration limit that is intended to protect against longer-term health effects. EPA has also proposed a slight relaxation of the 24-hr standard for inhalable particles (PM{sub 10}), by allowing additional exceedances each year. Fine particles are currently being indirectly controlled by means of regulations for PM{sub 10} and TSP, under the Clean Air Act of 1970 and subsequent amendments. Although routine monitoring of PM{sub 2.5} is rare and data are sparse, the available data indicate that ambient concentrations have been declining at about 6% per year under existing regulations.

  11. Cardiopulmonary Toxicity Induced by Ambient Particulate Matter (BI City Concentrated Ambient Particle Study)

    SciTech Connect (OSTI)

    Annette Rohr; James Wagner Masako Morishita; Gerald Keeler; Jack Harkema

    2010-06-30T23:59:59.000Z

    Alterations in heart rate variability (HRV) have been reported in rodents exposed to concentrated ambient particles (CAPs) from different regions of the United States. The goal of this study was to compare alterations in cardiac function induced by CAPs in two distinct regional atmospheres. AirCARE 1, a mobile laboratory with an EPA/Harvard fine particle (particulate matter <2.5 {micro}m; PM{sub 2.5}) concentrator was located in urban Detroit, MI, where the PM mixture is heavily influenced by motor vehicles, and in Steubenville, OH, where PM is derived primarily from long-range transport and transformation of power plant emissions, as well as from local industrial operations. Each city was studied during both winter and summer months, for a total of four sampling periods. Spontaneously hypertensive rats instrumented for electrocardiogram (ECG) telemetry were exposed to CAPs 8 h/day for 13 consecutive days during each sampling period. Heart rate (HR), and indices of HRV (standard deviation of the average normal-to-normal intervals [SDNN]; square root of the mean squared difference of successive normal-to-normal intervals [rMSSD]), were calculated for 30-minute intervals during exposures. A large suite of PM components, including nitrate, sulfate, elemental and organic carbon, and trace elements, were monitored in CAPs and ambient air. In addition, a unique sampler, the Semi-Continuous Elements in Air Sampler (SEAS) was employed to obtain every-30-minute measurements of trace elements. Positive matrix factorization (PMF) methods were applied to estimate source contributions to PM{sub 2.5}. Mixed modeling techniques were employed to determine associations between pollutants/CAPs components and HR and HRV metrics. Mean CAPs concentrations in Detroit were 518 and 357 {micro}g/m{sup 3} (summer and winter, respectively) and 487 and 252 {micro}g/m{sup 3} in Steubenville. In Detroit, significant reductions in SDNN were observed in the summer in association with cement/lime, iron/steel, and gasoline/diesel factors, while associations with the sludge incineration factor and components were less consistent. In winter, increases in HR were associated with a refinery factor and its components. CAPs-associated HR decreases in winter were linked to sludge incineration, cement/lime, and coal/secondary factors and the majority of their associated components. Specific relationships for increased rMSSD in winter were difficult to determine due to lack of consistency between factors and associated constituents. In Steubenville, we observed significant changes in HR (both increases and decreases), SDNN, and rMSSD in the summer, but not in the winter. We examined associations between individual source factors/PM components and HRV metrics segregated by predominant wind direction (NE or SW). Changes in HR (both increases and decreases) were linked with metal processing, waste incineration, and iron/steel factors along with most of their associated elemental constituents. Reductions in SDNN were associated with metal processing, waste incineration, and mobile source factors and the majority of elements loading onto these factors. There were no consistent associations between changes in rMSSD and source factors/components. Despite the large number of coal-fired power plants in the region, and therefore the large contribution of secondary sulfate to overall PM mass, we did not observe any associations with the coal/secondary factor or with the majority of its associated components. There were several inconsistencies in our results which make definitive conclusions difficult. For example, we observed opposing signs of effect estimates with some components depending on season, and with others depending on wind direction. In addition, our extensive dataset clearly would be subject to issues of multiple comparisons, and the 'true' significant results are unknown. Overall, however, our results suggest that acute changes in cardiac function were most strongly associated with local industrial sources. Results for coal-fired power plant-derived PM were

  12. Kinetic Model Development for the Combustion of Particulate Matter from Conventional and Soy Methyl Ester Diesel Fuels

    SciTech Connect (OSTI)

    Strzelec, Andrea [ORNL

    2009-12-01T23:59:59.000Z

    The primary objective of this research has been to investigate how the oxidation characteristics of diesel particulate matter (PM) are affected by blending soy-based biodiesel fuel with conventional ultra low sulfur diesel (ULSD) fuel. PM produced in a light duty engine from different biodiesel-conventional fuel blends was subjected to a range of physical and chemical measurements in order to better understand the mechanisms by which fuel-related changes to oxidation reactivity are brought about. These observations were then incorporated into a kinetic model to predict PM oxidation. Nanostructure of the fixed carbon was investigated by HR-TEM and showed that particulates from biodiesel had a more open structure than particulates generated from conventional diesel fuel, which was confirmed by BET surface area measurements. Surface area evolution with extent of oxidation reaction was measured for PM from ULSD and biodiesel. Biodiesel particulate has a significantly larger surface area for the first 40% of conversion, at which point the samples become quite similar. Oxidation characteristics of nascent PM and the fixed carbon portion were measured by temperature programmed oxidation (TPO) and it was noted that increased biodiesel blending lowered the light-off temperature as well as the temperature where the peak rate of oxidation occurred. A shift in the oxidation profiles of all fuels was seen when the mobile carbon fraction was removed, leaving only the fixed carbon, however the trend in temperature advantage of the biofuel blending remained. The mobile carbon fraction was measured by temperature programmed desorption found to generally increase with increasing biodiesel blend level. The relative change in the light-off temperatures for the nascent and fixed carbon samples was found to be related to the fraction of mobile carbon. Effective Arrhenius parameters for fixed carbon oxidation were directly measured with isothermal, differential oxidation experiments. Normalizing the reaction rate to the total carbon surface area available for reaction allowed for the definition of a single reaction rate with constant activation energy (112.5 {+-} 5.8 kJ/mol) for the oxidation of PM, independent of its fuel source. A kinetic model incorporating the surface area dependence of fixed carbon oxidation rate and the impact of the mobile carbon fraction was constructed and validated against experimental data.

  13. Total Particulate Matter Air Sampling Data (TEOM) from Los Alamos National Laboratory

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    LANL measures the total particulate mass concentration in the air on a routine basis as well as during incidents that may affect ambient air. The collected data is added to the Air Quality Index (AQI). AQI is an index for reporting daily air quality. It tells you how clean or polluted your air is, and what associated health effects might be a concern for you. The AQI focuses on health effects you may experience within a few hours or days after breathing polluted air. EPA calculates the AQI for five major air pollutants regulated by the Clean Air Act.

  14. Active DPF for Off-Road Particulate Matter (PM) Control | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't Your Destiny: The Future of1 AAccelerated aging of1.1Energy DPF for Off-Road Particulate

  15. Contribution of vehicle emissions to ambient carbonaceous particulate matter: A review and synthesis of the available data in the South Coast Air Basin. Final report

    SciTech Connect (OSTI)

    Cass, G.R.

    1997-02-01T23:59:59.000Z

    Table of Contents: Executive Summary; Introduction; Ambient Carbonaceous Particulate Matter in the South Coast Air Basin; Measurements of Emissions from In-Use Motor Vehicles in the South Coast Air Basin; Integration of Emissions Measurements into Comprehensive Emissions Inventories; Relating Emissions fom Motor Vehicles to Particulate Air Quality; Synthesis: The Combined Effect of All Vehicle-Related Source Contributions Acting Together; Trends in More Recent Years; Opportunities for Further Research; References; Appendix A: Detailed Mass Emissions Rates for Organic Compounds from Motor Vehicle Exhaust; and Appendix B: Organic Compounds Emitted from Tire Dust, Paved Road Dust, and Brake Lining Wear Dust.

  16. Apportionment of ambient primary and secondary fine particulate matter at the Pittsburgh National Energy Laboratory particulate matter characterization site using positive matrix factorization and a potential source contributions function analysis

    SciTech Connect (OSTI)

    Martello, D.V.; Pekney, N.J.; Anderson, R.R.; Davidson, C.I. (Carnegie Mellon U., Pittsburgh, PA); Hopke, P.K. (Clarkson University, Potsdam, NY); Kim, E. (Clarkson University, Potsdam, NY); Christensen, W.F. (Brigham Young Univ., Provo, UT); Mangelson, N.F. (Brigham Young Univ., Provo, UT); Eatough, D.J. (Brigham Young Univ., Provo, UT)

    2008-03-01T23:59:59.000Z

    Fine particulate matter (PM2.5) concentrations associated with 202 24-hr samples collected at the National Energy Technology Laboratory (NETL) particulate matter (PM) characterization site in south Pittsburgh from October 1999 through September 2001 were used to apportion PM2.5 into primary and secondary contributions using Positive Matrix Factorization (PMF2). Input included the concentrations of PM2.5 mass determined with a Federal Reference Method (FRM) sampler, semi-volatile PM2.5 organic material, elemental carbon (EC), and trace element components of PM2.5. A total of 11 factors were identified. The results of potential source contributions function (PSCF) analysis using PMF2 factors and HYSPLIT-calculated back-trajectories were used to identify those factors associated with specific meteorological transport conditions. The 11 factors were identified as being associated with emissions from various specific regions and facilities including crustal material, gasoline combustion, diesel combustion, and three nearby sources high in trace metals. Three sources associated with transport from coal-fired power plants to the southeast, a combination of point sources to the northwest, and a steel mill and associated sources to the west were identified. In addition, two secondary-material-dominated sources were identified, one was associated with secondary products of local emissions and one was dominated by secondary ammonium sulfate transported to the NETL site from the west and southwest. Of these 11 factors, the four largest contributors to PM2.5 were the secondary transported material (dominated by ammonium sulfate) (47%), local secondary material (19%), diesel combustion emissions (10%), and gasoline combustion emissions (8%). The other seven factors accounted for the remaining 16% of the PM2.5 mass. The findings are consistent with the major source of PM2.5 in the Pittsburgh area being dominated by ammonium sulfate from distant transport and so decoupled from local activity emitting organic pollutants in the metropolitan area. In contrast, the major local secondary sources are dominated by organic material.

  17. Apportionment of ambient primary and secondary fine particulate matter at the Pittsburgh National Energy Laboratory particulate matter characterization site using positive matrix factorization and a potential source contributions function analysis

    SciTech Connect (OSTI)

    Martello, DV [Martello, Donald V.; Pekney, NJ [Pekney, Natalie J.; Anderson, RR [Anderson, Richard; R,; Davidson, CI [Davidson, Cliff I.; Hopke, PK [Hopke, Philip K.; Kim, E [Kim, Eugene; Christensen, WF; (Christensen, William F.); Mangelson, NF [Mangelson, Nolan F.; Eatough, DJ [Eatough, Delbert J.

    2008-03-01T23:59:59.000Z

    Fine particulate matter (PM2.5) concentrations associated with 202 24-hr amples collected at the National Energy Technology Laboratory (NETL) particulate matter (PM) characterization site in south Pittsburgh from October 1999 through September 2001 were used to apportion PM2.5 into primary and secondary contributions using Positive Matrix Factorization (PMF2). Input included the concentrations of PM2.5 mass determined with a Federal Reference Method (FRM) sampler, semi-volatile PM2.5, organic material, elemental carbon (EC), and trace element components of PM2.5. A total of 11 factors were identified. The results of potential source contributions function (PSCF) analysis using PMF2 factors and HYSPLIT-calculated back-trajectories were used to identify those factors associated with specific meteorological transport conditions. The 11 factors were identified as being associated with emissions from various specific regions and facilities including crustal material, gasoline combustion, diesel combustion, and three nearby sources high in trace metals. Three sources associated with transport from coal-fired power plants to the southeast, a combination of point sources to the northwest, and a steel mill and associated sources to the west were identified. In addition, two secondary-material-dominated sources were identified, one was associated with secondary products of local emissions and one was dominated by secondary ammonium sulfate transported to the NETL site from the west and southwest. Of these 11 factors, the four largest contributors to PM2.5, were the secondary transported material (dominated by ammonium sulfate) (47%), local secondary material (19%), diesel combustion emissions (10%), and gasoline combustion emissions (8%). The other seven factors accounted for the remaining 16% of the PM2.5 mass. The findings are consistent with the major source of PM2.5 in the Pittsburgh area being dominated by ammonium sulfate from distant transport and so decoupled from local activity emitting organic pollutants in the metropolitan area. In contrast, the major local secondary sources are dominated by organic material.

  18. Apportionment of Ambient Primary and Secondary Fine Particulate Matter at the Pittsburgh National Energy Laboratory Particulate Matter Characterization Site Using Positive Matrix Factorization and a Potential Source Contributions Function Analysis

    SciTech Connect (OSTI)

    Martello, Donald [National Energy Technology Lab. (NETL), Pittsburgh, PA, (United States); Pekney, Natalie [National Energy Technology Lab. (NETL), Pittsburgh, PA, (United States); Anderson, Richard [National Energy Technology Lab. (NETL), Pittsburgh, PA, (United States); Davidson, Cliff [Department of Civil and Environmental Engineering, Carnegie Mellon University, Pittsburgh, PA; Hopke, Philip [Clarkson Univ., Potsdam, NY (United States). Center for Air Resources Engineering and Science, and Dept. of Chemical Engineering; Kim, Eugene [Clarkson Univ., Potsdam, NY (United States). Center for Air Resources Engineering and Science, and Dept. of Chemical Engineering; Christensen, William [Brigham Young Univ., Provo, UT (United States). Dept. of Statistics; Mangelson, Nolan [Brigham Young Univ., Provo, UT (United States). Dept. of Chemistry and Biochemistry; Eatough, Delbert [Brigham Young Univ., Provo, UT (United States). Dept. of Chemistry and Biochemistry

    2008-03-01T23:59:59.000Z

    Fine particulate matter (PM2.5) concentrations associated with 202 24-hr samples collected at the National Energy Technology Laboratory (NETL) particulate matter (PM) characterization site in south Pittsburgh from October 1999 through September 2001 were used to apportion PM2.5 into primary and secondary contributions using Positive Matrix Factorization (PMF2). Input included the concentrations of PM2.5 mass determined with a Federal Reference Method (FRM) sampler, semi-volatile PM2.5, organic material, elemental carbon (EC), and trace element components of PM2.5. A total of 11 factors were identified. The results of potential source contributions function (PSCF) analysis using PMF2 factors and HYSPLIT-calculated back-trajectories were used to identify those factors associated with specific meteorological transport conditions. The 11 factors were identified as being associated with emissions from various specific regions and facilities including crustal material, gasoline combustion, diesel combustion, and three nearby sources high in trace metals. Three sources associated with transport from coal-fired power plants to the southeast, a combination of point sources to the northwest, and a steel mill and associated sources to the west were identified. In addition, two secondary-material-dominated sources were identified, one was associated with secondary products of local emissions and one was dominated by secondary ammonium sulfate transported to the NETL site from the west and southwest. Of these 11 factors, the four largest contributors to PM2.5, were the secondary transported material (dominated by ammonium sulfate) (47%), local secondary material (19%), diesel combustion emissions (10%), and gasoline combustion emissions (8%). The other seven factors accounted for the remaining 16% of the PM2.5 mass. The findings are consistent with the major source of PM2.5 in the Pittsburgh area being dominated by ammonium sulfate from distant transport and so decoupled from local activity emitting organic pollutants in the metropolitan area. In contrast, the major local secondary sources are dominated by organic material.

  19. Alpha B-crystallin prevents the arrhythmogenic effects of particulate matter isolated from ambient air by attenuating oxidative stress

    SciTech Connect (OSTI)

    Park, Hyelim [The Division of Cardiology, Yonsei University College of Medicine, Seoul (Korea, Republic of) [The Division of Cardiology, Yonsei University College of Medicine, Seoul (Korea, Republic of); Brain Korea 21 Project for Medical Science, Yonsei University, Seoul (Korea, Republic of); Park, Sanghoon; Jeon, Hyunju [The Division of Cardiology, Yonsei University College of Medicine, Seoul (Korea, Republic of)] [The Division of Cardiology, Yonsei University College of Medicine, Seoul (Korea, Republic of); Song, Byeong-Wook [The Division of Cardiology, Yonsei University College of Medicine, Seoul (Korea, Republic of) [The Division of Cardiology, Yonsei University College of Medicine, Seoul (Korea, Republic of); Brain Korea 21 Project for Medical Science, Yonsei University, Seoul (Korea, Republic of); Kim, Jin-Bae [Division of Cardiology, Kyung Hee University College of Medicine, Seoul (Korea, Republic of)] [Division of Cardiology, Kyung Hee University College of Medicine, Seoul (Korea, Republic of); Kim, Chang-Soo [The Department of Preventive Medicine, Yonsei University College of Medicine, Seoul (Korea, Republic of)] [The Department of Preventive Medicine, Yonsei University College of Medicine, Seoul (Korea, Republic of); Pak, Hui-Nam [The Division of Cardiology, Yonsei University College of Medicine, Seoul (Korea, Republic of)] [The Division of Cardiology, Yonsei University College of Medicine, Seoul (Korea, Republic of); Hwang, Ki-Chul [The Division of Cardiology, Yonsei University College of Medicine, Seoul (Korea, Republic of) [The Division of Cardiology, Yonsei University College of Medicine, Seoul (Korea, Republic of); Brain Korea 21 Project for Medical Science, Yonsei University, Seoul (Korea, Republic of); Lee, Moon-Hyoung [The Division of Cardiology, Yonsei University College of Medicine, Seoul (Korea, Republic of)] [The Division of Cardiology, Yonsei University College of Medicine, Seoul (Korea, Republic of); Chung, Ji Hyung, E-mail: jhchung@yuhs.ac [The Division of Cardiology, Yonsei University College of Medicine, Seoul (Korea, Republic of); Joung, Boyoung, E-mail: cby6908@yuhs.ac [The Division of Cardiology, Yonsei University College of Medicine, Seoul (Korea, Republic of) [The Division of Cardiology, Yonsei University College of Medicine, Seoul (Korea, Republic of); Brain Korea 21 Project for Medical Science, Yonsei University, Seoul (Korea, Republic of)

    2013-01-15T23:59:59.000Z

    Ca{sup 2+}/calmodulin-dependent protein kinase II (CaMKII) is activated by particulate matter (PM) isolated from ambient air and linked to prolonged repolarization and cardiac arrhythmia. We evaluated whether alpha B-crystallin (CryAB), a heat shock protein, could prevent the arrhythmogenic effects of PM by preventing CaMKII activation. CryAB was delivered into cardiac cells using a TAT-protein transduction domain (TAT-CryAB). ECGs were measured before and after tracheal exposure of diesel exhaust particles (DEP) and each intervention in adult Sprague–Dawley rats. After endotracheal exposure of DEP (200 ?g/mL for 30 minutes, n = 11), QT intervals were prolonged from 115 ± 14 ms to 144 ± 20 ms (p = 0.03), and premature ventricular contractions were observed more frequently (0% vs. 44%) than control (n = 5) and TAT-Cry (n = 5). However, DEP-induced arrhythmia was not observed in TAT-CryAB (1 mg/kg) pretreated rats (n = 5). In optical mapping of Langendorff-perfused rat heats, compared with baseline, DEP infusion of 12.5 ?g/mL (n = 12) increased apicobasal action potential duration (APD) differences from 2 ± 6 ms to 36 ± 15 ms (p < 0.001), APD restitution slope from 0.26 ± 0.07 to 1.19 ± 0.11 (p < 0.001) and ventricular tachycardia (VT) from 0% to 75% (p < 0.001). DEP infusion easily induced spatially discordant alternans. However, the effects of DEP were prevented by TAT-CryAB (1 mg/kg, n = 9). In rat myocytes, while DEP increased reactive oxygen species (ROS) generation and phosphated CaMKII, TAT-CryAB prevented these effects. In conclusion, CryAB, a small heat shock protein, might prevent the arrhythmogenic effects of PM by attenuating ROS generation and CaMKII activation. -- Highlights: ? Particulate matter (PM) increases arrhythmia. ? PM induced arrhythmias are related with oxidative stress and CaMKII activation. ? Alpha B-crystallin (CryAB) could attenuate the arrhythmogenic effect of PM. ? CryAB decreases oxidative stress and CaMKII activation induced by ambient PM.

  20. Diesel Emission Control -- Sulfur Effects (DECSE) Program; Phase I Interim Date Report No. 3: Diesel Fuel Sulfur Effects on Particulate Matter Emissions

    SciTech Connect (OSTI)

    DOE; ORNL; NREL; EMA; MECA

    1999-11-15T23:59:59.000Z

    The Diesel Emission Control-Sulfur Effects (DECSE) is a joint government/industry program to determine the impact of diesel fuel sulfur levels on emission control systems whose use could lower emissions of nitrogen oxides (NO{sub x}) and particulate matter (PM) from on-highway trucks in the 2002--2004 model years. Phase 1 of the program was developed with the following objectives in mind: (1) evaluate the effects of varying the level of sulfur content in the fuel on the emission reduction performance of four emission control technologies; and (2) measure and compare the effects of up to 250 hours of aging on selected devices for multiple levels of fuel sulfur content. This interim report covers the effects of diesel fuel sulfur level on particulate matter emissions for four technologies.

  1. Evaluation of the modified Anderson sampler for determining particle size distributions and respirable concentrations of particulate matter present in the working environment of cottonseed oil mills

    E-Print Network [OSTI]

    Matlock, Stanley Wayne

    1976-01-01T23:59:59.000Z

    EVALUATION OF THE MODIFIED ANDERSON SAMPLER FOR DETERMINING PARTICLE SIZE DISTRIBUTIONS AND RESPIRABLE CONCENTRATIONS OF PARTICULATE MATTER PRESENT IN THE WORKING ENVIRONMENT OF COTTONSEED OIL MILLS A Thesis by STANLEY WAYNE MATLOCK Submitted... to the Graduate College of Texas A&M University in partial fulfillment of the requirement for the degree of MASTER OF SCIENCE August 1976 Major Subject: Agricultural Engineering FVALUATION OF THE MODIFIED ANDERSON SAMPLER FOR DETERMINING PARTICLE SIZE...

  2. Electrically heated particulate filter restart strategy

    DOE Patents [OSTI]

    Gonze, Eugene V [Pinckney, MI; Ament, Frank [Troy, MI

    2011-07-12T23:59:59.000Z

    A control system that controls regeneration of a particulate filter is provided. The system generally includes a propagation module that estimates a propagation status of combustion of particulate matter in the particulate filter. A regeneration module controls current to the particulate filter to re-initiate regeneration based on the propagation status.

  3. NOx Adsorber (Lean NOx Trap) Fundamentals (Agreement #10049 ...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    (Lean NOx Trap) Fundamentals (Agreement 10049 - PNNL Project 47120) NOx Adsorber (Lean NOx Trap) Fundamentals (Agreement 10049 - PNNL Project 47120) Presentation from the U.S....

  4. Impacts of Mid-level Biofuel Content in Gasoline on SIDI Engine-Out and Tailpipe Particulate Matter Emissions: Preprint

    SciTech Connect (OSTI)

    He, X.; Ireland, J. C.; Zigler, B. T.; Ratcliff, M. A.; Knoll, K. E.; Alleman, T. L.; Tester, J. T.

    2011-02-01T23:59:59.000Z

    The influences of ethanol and iso-butanol blended with gasoline on engine-out and post Three-Way Catalyst (TWC) particle size distribution and number concentration were studied using a GM 2.0L turbocharged Spark Ignition Direct Injection (SIDI) engine. The engine was operated using the production ECU with a dynamometer controlling the engine speed and the accelerator pedal position controlling the engine load. A TSI Fast Mobility Particle Sizer (FMPS) spectrometer was used to measure the particle size distribution in the range from 5.6 to 560 nm with a sampling rate of 1 Hz. US federal certification gasoline (E0), two ethanol-blended fuels (E10 and E20), and 11.7% iso-butanol blended fuel (BU12) were tested. Measurements were conducted at ten selected steady-state engine operation conditions. Bi-modal particle size distributions were observed for all operating conditions with peak values at particle sizes of 10 nm and 70 nm. Idle and low speed / low load conditions emitted higher total particle numbers than other operating conditions. At idle, the engine-out Particulate Matter (PM) emissions were dominated by nucleation mode particles, and the production TWC reduced these nucleation mode particles by more than 50%, while leaving the accumulation mode particle distribution unchanged. At engine load higher than 6 bar NMEP, accumulation mode particles dominated the engine-out particle emissions and the TWC had little effect. Compared to the baseline gasoline (E0), E10 does not significantly change PM emissions, while E20 and BU12 both reduce PM emissions under the conditions studied. Iso-butanol was observed to impact PM emissions more than ethanol, with up to 50% reductions at some conditions. In this paper, the issues related to PM measurement using FMPS are also discussed. While some uncertainties are due to engine variation, the FMPS must be operated under careful maintenance procedures in order to achieve repeatable measurement results.

  5. Characterization of Fine Particulate Matter (PM) and Secondary PM Precursor Gases in Mexico City

    SciTech Connect (OSTI)

    Dr. Charles E. Kolb

    2008-03-31T23:59:59.000Z

    This project was one of three collaborating grants designed to understand the atmospheric chemistry and aerosol particle microphysics impacting air quality in the Mexico City Metropolitan Area (MCMA) and its urban plume. The overall effort, titled MCMA- 2006, focused on: 1) the primary emissions of fine particles and precursor gases leading to photochemical production of atmospheric oxidants and secondary aerosol particles and 2) the measurement and analysis of secondary oxidants and secondary fine particular matter (PM) production, with particular emphasis on secondary organic aerosol (SOA). MCAM-2006 pursued it goals through three main activities: 1) performance and publication of detailed analyses of extensive MCMA trace gas and fine PM measurements made by the collaborating groups and others during earlier MCMA field campaigns in 2002 and 2003; 2) deployment and utilization of extensive real-time trace gas and fine PM instrumentation at urban and downwind MCMA sites in support of the MAX-Mex/MILAGRO field measurements in March, 2006; and, 3) analyses of the 2006 MCMA data sets leading to further publications that are based on new data as well as insights from analysis and publication of the 2002/2003 field data. Thirteen archival publications were coauthored with other MCMA-2003 participants. Documented findings included a significantly improved speciated emissions inventory from on-road vehicles, a greatly enhanced understanding of the sources and atmospheric loadings of volatile organic compounds, a unique analysis of the high fraction of ambient formaldehyde from primary emission sources, a much more extensive knowledge of the composition, size distributions and atmospheric mass loadings of both primary and secondary fine PM, including the fact that the rate of MCMA SOA production greatly exceeded that predicted by current atmospheric models, and evaluations of significant errors that can arise from standard air quality monitors for ozone and nitrogen dioxide. Deployment of the Aerodyne mobile laboratory, equipped with instruments from five collaborating laboratories, at the T0 urban supersite, four downwind sites and the Tula industrial area yielded unique trace gas and fine PM data sets during the March 2006 MAXMex/MILAGRO campaign. In addition, on-road measurements as the mobile laboratory moved between sites provided extensive data on 2006 MCMA fleet averaged vehicle emissions. Analyses of 2006 data sets have yielded the identification of a close correlation between the rate of production of SOA and “Odd Oxygen” (O3 + NO2) and primary organic PM with CO in the MCMA urban plume, a more sophisticated understanding of the interplay between nitrogen oxide speciation and ozone production, the identification of significant vehicular emission sources of HCN and CH3CN (usually associated with biomass burning), characterization of the aging of primary carbonaceous PM, and updated 2006 MCMA fleet on-road trace gas and fine PM emissions. Results from analyses of 2002/2003 and 2006 emissions and ambient measurements have conveyed to Mexican air quality managers who are using these data to devise and assess air quality management strategies. All data sets and published analyses are available to DOE/ASP researchers evaluating the impact of urban emissions on regional climate.

  6. Electrically heated particulate filter propagation support methods and systems

    DOE Patents [OSTI]

    Gonze, Eugene V [Pinckney, MI; Ament, Frank [Troy, MI

    2011-06-07T23:59:59.000Z

    A control system that controls regeneration of a particulate filter is provided. The system generally includes a regeneration module that controls current to the particulate filter to initiate combustion of particulate matter in the particulate filter. A propagation module estimates a propagation status of the combustion of the particulate matter based on a combustion temperature. A temperature adjustment module controls the combustion temperature by selectively increasing a temperature of exhaust that passes through the particulate filter.

  7. Diesel Emission Control -- Sulfur Effects (DECSE) Program; Phase I Interim Data Report No. 4: Diesel Particulate Filters -- Final Report

    SciTech Connect (OSTI)

    DOE; ORNL; NREL; EMA; MECA

    2000-01-15T23:59:59.000Z

    The Diesel Emission Control-Sulfur Effects (DECSE) is a joint government/industry program to determine the impact of diesel fuel sulfur levels on emission control systems whose use could lower emissions of nitrogen oxides (NOx) and particulate matter (PM) from on-highway trucks in the 2002--2004 model years. Phase 1 of the program was developed with the following objectives in mind: (1) evaluate the effects of varying the level of sulfur content in the fuel on the emission reduction performance of four emission control technologies; and (2) measure and compare the effects of up to 250 hours of aging on selected devices for multiple levels of fuel sulfur content. This is the fourth and final report for the DPF test program and covers the effect of diesel sulfur level on: a catalyzed diesel particulate filter (CDPF), and a continuously regenerating diesel particulate filter (CR-DPF).

  8. Leadership in Low NOx/ Lochinvar Corporation 

    E-Print Network [OSTI]

    Sheko, D.; Boston, S.; Moore, J.

    2002-01-01T23:59:59.000Z

    Jlutant. The following several paragraphs will look closer at each of the criteria pollutants associated with gas combustion. Two of the criteria pollutants outlined by the EPA, ozone and particulate matter, are of concern in at least some portions of Texas.... These national ambient air quality standards established national levels for acceptable concentrations of six specific pol1utants related to outdoor air quality. These six pollutants are ground level ozone (Smog), particulate matter, lead, nitrogen dioxide...

  9. Low NOx combustion

    DOE Patents [OSTI]

    Kobayashi, Hisashi (Putnam Valley, NY); Bool, III, Lawrence E. (Aurora, NY)

    2008-10-21T23:59:59.000Z

    Combustion of hydrocarbon liquids and solids is achieved with less formation of NOx by feeding a small amount of oxygen into the fuel stream.

  10. Low NOx combustion

    SciTech Connect (OSTI)

    Kobayashi; Hisashi (Putnam Valley, NY), Bool, III; Lawrence E. (Aurora, NY)

    2007-06-05T23:59:59.000Z

    Combustion of hydrocarbon liquids and solids is achieved with less formation of NOx by feeding a small amount of oxygen into the fuel stream.

  11. NOx Sensor Development

    Broader source: Energy.gov (indexed) [DOE]

    and advanced testing facilities. - EmiSense LLC: licensed LLNL NOx technology and CRADA partners for continued development. Relevance - If 33% of U.S. drivers switched to...

  12. EVALUATION OF THE EMISSION, TRANSPORT, AND DEPOSITION OF MERCURY, FINE PARTICULATE MATTER, AND ARSENIC FROM COAL-BASED POWER PLANTS IN THE OHIO RIVER VALLEY REGION

    SciTech Connect (OSTI)

    Kevin Crist

    2005-04-02T23:59:59.000Z

    Ohio University, in collaboration with CONSOL Energy, Advanced Technology Systems, Inc (ATS) and Atmospheric and Environmental Research, Inc. (AER) as subcontractors, is evaluating the impact of emissions from coal-fired power plants in the Ohio River Valley region as they relate to the transport and deposition of mercury, arsenic, and associated fine particulate matter. This evaluation will involve two interrelated areas of effort: ambient air monitoring and regional-scale modeling analysis. The scope of work for the ambient air monitoring will include the deployment of a surface air monitoring (SAM) station in southeastern Ohio. The SAM station will contain sampling equipment to collect and measure mercury (including speciated forms of mercury and wet and dry deposited mercury), arsenic, particulate matter (PM) mass, PM composition, and gaseous criteria pollutants (CO, NO{sub x}, SO{sub 2}, O{sub 3}, etc.). Laboratory analysis of time-integrated samples will be used to obtain chemical speciation of ambient PM composition and mercury in precipitation. Near-real-time measurements will be used to measure the ambient concentrations of PM mass and all gaseous species including Hg{sup 0} and RGM. Approximately of 18 months of field data will be collected at the SAM site to validate the proposed regional model simulations for episodic and seasonal model runs. The ambient air quality data will also provide mercury, arsenic, and fine particulate matter data that can be used by Ohio Valley industries to assess performance on multi-pollutant control systems. The scope of work for the modeling analysis will include (1) development of updated inventories of mercury and arsenic emissions from coal plants and other important sources in the modeled domain; (2) adapting an existing 3-D atmospheric chemical transport model to incorporate recent advancements in the understanding of mercury transformations in the atmosphere; (3) analyses of the flux of Hg{sup 0}, RGM, arsenic, and fine particulate matter in the different sectors of the study region to identify key transport mechanisms; (4) comparison of cross correlations between species from the model results to observations in order to evaluate characteristics of specific air masses associated with long-range transport from a specified source region; and (5) evaluation of the sensitivity of these correlations to emissions from regions along the transport path. This will be accomplished by multiple model runs with emissions simulations switched on and off from the various source regions. To the greatest extent possible, model results will also be compared to field data collected at other air monitoring sites in the Ohio Valley region, operated independently of this project. These sites may include (1) the DOE National Energy Technologies Laboratory's monitoring site at its suburban Pittsburgh, PA facility; (2) sites in Pittsburgh (Lawrenceville) PA and Holbrook, PA operated by ATS; (3) sites in Steubenville, OH and Pittsburgh, PA operated by U.S. EPA and/or its contractors; and (4) sites operated by State or local air regulatory agencies. Field verification of model results and predictions will provide critical information for the development of cost effective air pollution control strategies by the coal-fired power plants in the Ohio River Valley region.

  13. EVALUATION OF THE EMISSION, TRANSPORT, AND DEPOSITION OF MERCURY, FINE PARTICULATE MATTER, AND ARSENIC FROM COAL-BASED POWER PLANTS IN THE OHIO RIVER VALLEY REGION

    SciTech Connect (OSTI)

    Kevin Crist

    2003-10-02T23:59:59.000Z

    Ohio University, in collaboration with CONSOL Energy, Advanced Technology Systems, Inc (ATS) and Atmospheric and Environmental Research, Inc. (AER) as subcontractors, is evaluating the impact of emissions from coal-fired power plants in the Ohio River Valley region as they relate to the transport and deposition of mercury, arsenic, and associated fine particulate matter. This evaluation will involve two interrelated areas of effort: ambient air monitoring and regional-scale modeling analysis. The scope of work for the ambient air monitoring will include the deployment of a surface air monitoring (SAM) station in southeastern Ohio. The SAM station will contain sampling equipment to collect and measure mercury (including speciated forms of mercury and wet and dry deposited mercury), arsenic, particulate matter (PM) mass, PM composition, and gaseous criteria pollutants (CO, NO{sub x}, SO{sub 2}, O{sub 3}, etc.). Laboratory analysis of time-integrated samples will be used to obtain chemical speciation of ambient PM composition and mercury in precipitation. Near-real-time measurements will be used to measure the ambient concentrations of PM mass and all gaseous species including Hg{sup 0} and RGM. Approximately of 18 months of field data will be collected at the SAM site to validate the proposed regional model simulations for episodic and seasonal model runs. The ambient air quality data will also provide mercury, arsenic, and fine particulate matter data that can be used by Ohio Valley industries to assess performance on multi-pollutant control systems. The scope of work for the modeling analysis will include (1) development of updated inventories of mercury and arsenic emissions from coal plants and other important sources in the modeled domain; (2) adapting an existing 3-D atmospheric chemical transport model to incorporate recent advancements in the understanding of mercury transformations in the atmosphere; (3) analyses of the flux of Hg{sup 0}, RGM, arsenic, and fine particulate matter in the different sectors of the study region to identify key transport mechanisms; (4) comparison of cross correlations between species from the model results to observations in order to evaluate characteristics of specific air masses associated with long-range transport from a specified source region; and (5) evaluation of the sensitivity of these correlations to emissions from regions along the transport path. This will be accomplished by multiple model runs with emissions simulations switched on and off from the various source regions. To the greatest extent possible, model results will also be compared to field data collected at other air monitoring sites in the Ohio Valley Region, operated independently of this project. These sites may include (1) the DOE National Energy Technologies Laboratory's monitoring site at its suburban Pittsburgh, PA facility; (2) sites in Pittsburgh (Lawrenceville) PA and Holbrook, PA operated by ATS; (3) sites in Steubenville, OH and Pittsburgh, PA operated by U.S. EPA and/or its contractors; and (4) sites operated by State or local air regulatory agencies. Field verification of model results and predictions will provide critical information for the development of cost effective air pollution control strategies by the coal-fired power plants in the Ohio River Valley Region.

  14. Evaluation of the Emission, Transport, and Deposition of Mercury, Fine Particulate Matter, and Arsenic from Coal-Based Power Plants in the Ohio River Valley Region

    SciTech Connect (OSTI)

    Kevin Crist

    2006-04-02T23:59:59.000Z

    As stated in the proposal: Ohio University, in collaboration with CONSOL Energy, Advanced Technology Systems, Inc (ATS) and Atmospheric and Environmental Research, Inc. (AER) as subcontractors, is evaluating the impact of emissions from coal-fired power plants in the Ohio River Valley region as they relate to the transport and deposition of mercury, arsenic, and associated fine particulate matter. This evaluation will involve two interrelated areas of effort: ambient air monitoring and regional-scale modeling analysis. The scope of work for the ambient air monitoring will include the deployment of a surface air monitoring (SAM) station in southeastern Ohio. The SAM station will contain sampling equipment to collect and measure mercury (including speciated forms of mercury and wet and dry deposited mercury), arsenic, particulate matter (PM) mass, PM composition, and gaseous criteria pollutants (CO, NO{sub x}, SO{sub 2}, O{sub 3}, etc.). Laboratory analysis of time-integrated samples will be used to obtain chemical speciation of ambient PM composition and mercury in precipitation. Near-real-time measurements will be used to measure the ambient concentrations of PM mass and all gaseous species including Hg0 and RGM. Approximately 18 months of field data will be collected at the SAM site to validate the proposed regional model simulations for episodic and seasonal model runs. The ambient air quality data will also provide mercury, arsenic, and fine particulate matter data that can be used by Ohio Valley industries to assess performance on multi-pollutant control systems. The scope of work for the modeling analysis will include (1) development of updated inventories of mercury and arsenic emissions from coal plants and other important sources in the modeled domain; (2) adapting an existing 3-D atmospheric chemical transport model to incorporate recent advancements in the understanding of mercury transformations in the atmosphere; (3) analyses of the flux of Hg{sup 0}, RGM, arsenic, and fine particulate matter in the different sectors of the study region to identify key transport mechanisms; (4) comparison of cross correlations between species from the model results to observations in order to evaluate characteristics of specific air masses associated with long-range transport from a specified source region; and (5) evaluation of the sensitivity of these correlations to emissions from regions along the transport path. This will be accomplished by multiple model runs with emissions simulations switched on and off from the various source regions. To the greatest extent possible, model results will also be compared to field data collected at other air monitoring sites in the Ohio Valley region, operated independently of this project. These sites may include (1) the DOE National Energy Technologies Laboratory's monitoring site at its suburban Pittsburgh, PA facility; (2) sites in Pittsburgh (Lawrenceville) PA and Holbrook, PA operated by ATS; (3) sites in Steubenville, OH and Pittsburgh, PA operated by the USEPA and/or its contractors; and (4) sites operated by State or local air regulatory agencies. Field verification of model results and predictions will provide critical information for the development of cost effective air pollution control strategies by the coal-fired power plants in the Ohio River Valley region.

  15. NOx Adsorber (Lean NOx Trap) Fundamentals (Agreement #10049 ...

    Broader source: Energy.gov (indexed) [DOE]

    technology operation. - Chemical mechanisms of NOx adsorption, desorption, and reduction for inclusion in CLEERS models - emphasis this year: effect of CO 2 and H 2 O on NOx...

  16. Trace metal composition of particulate matter of the Danube River and Turkish rivers draining into the Black Sea

    E-Print Network [OSTI]

    Murray, James W.

    into the Black Sea Ouz Yiiterhan a,, James W. Murray b,1 a Institute of Marine Sciences, Middle East Technical several rivers entering the Black Sea as part of a broader study of the composition of suspended matter and sediments in the Black Sea. Suspended matter and surface sediment samples were collected from the Danube

  17. Microwave regenerated particulate trap

    SciTech Connect (OSTI)

    McDonald, A.C. Jr.; Yonushonis, T.M. [Cummins Engine Co., Inc., Columbus, IN (United States); Haberkamp, W.C.; Mako, F.; Len, L.K,; Silberglitt, R.; Ahmed, I. [FM Technologies, Inc., Fairfax, VA (United States)

    1997-12-31T23:59:59.000Z

    It has been demonstrated that a fibrous particulate filter can extract particulate matter from the diesel exhaust. However, additional engineering efforts remains to achieve the design target of 90%. It has also be shown that with minor modifications magnetrons produced for home ovens can endure a simulated diesel operating environment. Much work remains to develop a robust product ready to complete extensive engine testing and evaluation. These efforts include: (1) additional environmental testing of magnetrons; (2) vibration testing of the filter in the housing; (3) evaluating alternative methods/designs to seal the center bore; and (4) determining the optimum coating thickness that provides sufficient structural integrity while maintaining rapid heating rates.

  18. Particulate Matter Emissions from a Direct Injection Spark Ignition Engine under Cold Fast Idle Conditions for Ethanol-Gasoline Blends

    E-Print Network [OSTI]

    Dimou, Iason

    The engine out particular matter number (PN) distributions at engine coolant temperature (ECT) of 0° C to 40° C for ethanol/ gasoline blends (E0 to E85) have been measured for a direct-injection spark ignition engine under ...

  19. ambient particulate matterpm10: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    , E 12;ACPD 7, 15693-15721, 2007 Particulate PAH spatial variability and aging in Mexico City D. A Boyer, Edmond 7 Different Genes Interact with Particulate Matter and...

  20. CLEERS Activities: Diesel Soot Filter Characterization & NOx...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Activities: Diesel Soot Filter Characterization & NOx Control Fundamentals CLEERS Activities: Diesel Soot Filter Characterization & NOx Control Fundamentals 2009 DOE Hydrogen...

  1. Air Pollution Control Regulations: No. 13 - Particulate Emissions...

    Broader source: Energy.gov (indexed) [DOE]

    Environmental Regulations Provider Department of Environmental Management The purpose of this regulation is to limit emissions of particulate matter from fossil fuel fired and...

  2. active fine particulates: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Sciences and Ecology Websites Summary: Effects of Sampling Conditions on the Size Distribution of Fine Particulate Matter Emitted from complex because the dilution...

  3. airborne fine particulate: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Sciences and Ecology Websites Summary: Effects of Sampling Conditions on the Size Distribution of Fine Particulate Matter Emitted from complex because the dilution...

  4. ambient fine particulate: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Sciences and Ecology Websites Summary: Effects of Sampling Conditions on the Size Distribution of Fine Particulate Matter Emitted from complex because the dilution...

  5. Reactive based NOx sensor

    E-Print Network [OSTI]

    Vassiliou, Christophoros Christou

    2006-01-01T23:59:59.000Z

    Diesel engines exhibit better fuel economy and emit fewer greenhouse gases than gasoline engines. Modern diesel technology has virtually eliminated carbon monoxide and particulate emissions. Sulfur oxide emissions have ...

  6. Diesel lube oils; Fourth dimension of diesel particulate control

    SciTech Connect (OSTI)

    Springer, K.J. (Southwest Research Institute, San Antonio, TX (US))

    1989-07-01T23:59:59.000Z

    Particulate emission control, for the HD diesel engine, has previously been considered a three-dimensional problem involving: combustion of the fuel by the engine, fuel modification, and exhaust aftertreatment. The lube oil contribution may be considered a fourth dimension of the problem. Historically, the heavy-duty engine manufacturer has met emission standards for smoke (1968 to present), CO, HC, and NOx (1974 to present) and particulates (1988 to present) through changes in engine design. This paper used the allocation method to estimate the reduction in lube oil consumption needed to meet 1991 and 1994 U.S. particulate emission standards. This analysis places the contribution of lube oil as a source of exhaust particulates into prospective with the contributions from fuel sulfur and fuel combustion. An emissions control strategy to meet future regulations is offered in which reductions from fuel modification, combustion improvement, reduced lube oil consumption, and exhaust particulate trap-catalysts are all involved.

  7. Airborne Particulate Threat Assessment

    SciTech Connect (OSTI)

    Patrick Treado; Oksana Klueva; Jeffrey Beckstead

    2008-12-31T23:59:59.000Z

    Aerosol threat detection requires the ability to discern between threat agents and ambient background particulate matter (PM) encountered in the environment. To date, Raman imaging technology has been demonstrated as an effective strategy for the assessment of threat agents in the presence of specific, complex backgrounds. Expanding our understanding of the composition of ambient particulate matter background will improve the overall performance of Raman Chemical Imaging (RCI) detection strategies for the autonomous detection of airborne chemical and biological hazards. Improving RCI detection performance is strategic due to its potential to become a widely exploited detection approach by several U.S. government agencies. To improve the understanding of the ambient PM background with subsequent improvement in Raman threat detection capability, ChemImage undertook the Airborne Particulate Threat Assessment (APTA) Project in 2005-2008 through a collaborative effort with the National Energy Technology Laboratory (NETL), under cooperative agreement number DE-FC26-05NT42594. During Phase 1 of the program, a novel PM classification based on molecular composition was developed based on a comprehensive review of the scientific literature. In addition, testing protocols were developed for ambient PM characterization. A signature database was developed based on a variety of microanalytical techniques, including scanning electron microscopy, FT-IR microspectroscopy, optical microscopy, fluorescence and Raman chemical imaging techniques. An automated particle integrated collector and detector (APICD) prototype was developed for automated collection, deposition and detection of biothreat agents in background PM. During Phase 2 of the program, ChemImage continued to refine the understanding of ambient background composition. Additionally, ChemImage enhanced the APICD to provide improved autonomy, sensitivity and specificity. Deliverables included a Final Report detailing our findings and APICD Gen II subsystems for automated collection, deposition and detection of ambient particulate matter. Key findings from the APTA Program include: Ambient biological PM taxonomy; Demonstration of key subsystems needed for autonomous bioaerosol detection; System design; Efficient electrostatic collection; Automated bioagent recognition; Raman analysis performance validating Td<9 sec; Efficient collection surface regeneration; and Development of a quantitative bioaerosol defection model. The objective of the APTA program was to advance the state of our knowledge of ambient background PM composition. Operation of an automated aerosol detection system was enhanced by a more accurate assessment of background variability, especially for sensitive and specific sensing strategies like Raman detection that are background-limited in performance. Based on this improved knowledge of background, the overall threat detection performance of Raman sensors was improved.

  8. NOx Abatement Research and Development

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Work * Identify factors limiting NOx conversion during low temperature operation with CO and hydrocarbon (HC) reductants - Goal is to improve the effectiveness and efficiency of...

  9. Measurement and Characterization of NOx Adsorber Regeneration...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    NOx Adsorber Regeneration and Desulfation Measurement and Characterization of NOx Adsorber Regeneration and Desulfation 2003 DEER Conference Presentation: Oak Ridge National...

  10. Proceedings: 2000 NOx Controls Workshop

    SciTech Connect (OSTI)

    None

    2001-04-01T23:59:59.000Z

    The 2000 EPRI workshop on nitrogen oxide (NOx) controls for utility boilers provided a medium for member utilities to augment their knowledge of recent operating experience and developments on NOx control technologies. The event focused on improving methods of compliance with emission regulations mandated by the Clean Air Act Amendments (CAAA) of 1990 without jeopardizing efficiency and plant performance.

  11. Interpreting Remote Sensing NOx Measurements

    E-Print Network [OSTI]

    Denver, University of

    Interpreting Remote Sensing NOx Measurements Robert Slott, Consultant, Donald Stedman and Saj tailpipe emissions (HC, CO, NOx) are changing with time hUse remote sensing hMeasurements in at least 4 of the year at each location hUniform QC/QA and data reporting Paper # 2001-01-3640 #12;Remote Sensing

  12. The effect of lubricant derived ash on the catalytic activity of diesel particulate filters

    E-Print Network [OSTI]

    Murray, Timothy Quinn

    2014-01-01T23:59:59.000Z

    A diesel particulate filter (DPF) is an aftertreatment device used to remove hazardous particulate matter (PM) from diesel engine exhaust. Modem emission restrictions have limited the acceptable amount of PM output by ...

  13. Catalyzed Diesel Particulate Filter Performance in a Light-Duty Vehicle

    SciTech Connect (OSTI)

    Sluder, C.S.

    2001-04-23T23:59:59.000Z

    Light-duty chassis dynamometer driving cycle tests were conducted on a Mercedes A170 diesel vehicle with various sulfur-level fuels and exhaust emission control systems. Triplicate runs of a modified light-duty federal test procedure (FTP), US06 cycle, and SCO3 cycle were conducted with each exhaust configuration and fuel. Ultra-low sulfur (3-ppm) diesel fuel was doped to 30- and 150-ppm sulfur so that all other fuel properties remained the same. The fuels used in these experiments met the specifications of the fuels from the DECSE (Diesel Emission Control Sulfur Effects) program. Although the Mercedes A170 vehicle is not available in the US, its emissions in the as tested condition fell within the U.S. Tier 1 full useful life standards with the OEM catalysts installed. Tests with the OEM catalysts removed showed that the OEM catalysts reduced PM emissions from the engine-out condition by 30-40% but had negligible effects on NOx emissions. Fuel sulfur level had very little effect on th e OEM catalyst performance. A prototype catalyzed diesel particulate filter (CDPF) mounted in an underfloor configuration reduced particulate matter emissions by more than 90% compared to the factory emissions control system. The results show that the CDPF did not promote any significant amounts of SO{sub 2}-to-sulfate conversion during these light-duty drive cycles.

  14. A new aerosol collector for quasi on-line analysis of particulate organic matter: the Aerosol Collection Module (ACM) and first applications with a GC/MS-FID

    E-Print Network [OSTI]

    Hohaus, T.

    In many environments organic matter significantly contributes to the composition of atmospheric aerosol particles influencing its properties. Detailed chemical characterization of ambient aerosols is critical in order to ...

  15. Measurement and Characterization of Lean NOx Adsorber Regeneration...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Lean NOx Adsorber Regeneration and Desulfation and Controlling NOx from Multi-mode Measurement and Characterization of Lean NOx Adsorber Regeneration and Desulfation and...

  16. Shielded regeneration heating element for a particulate filter

    DOE Patents [OSTI]

    Gonze, Eugene V [Pinckney, MI; Ament, Frank [Troy, MI

    2011-01-04T23:59:59.000Z

    An exhaust system includes a particulate filter (PF) that is disposed downstream from an engine. The PF filters particulates within an exhaust from the engine. A heating element heats particulate matter in the PF. A catalyst substrate or a flow converter is disposed upstream from said heating element. The catalyst substrate oxidizes the exhaust prior to reception by the heating element. The flow converter converts turbulent exhaust flow to laminar exhaust flow prior to reception by the heating element.

  17. Plant-Wide NOx Reduction Strategies

    E-Print Network [OSTI]

    Baukal, C.; Waibel, D.; Webster, T.

    2006-01-01T23:59:59.000Z

    and the public's awareness increased, industry began looking for new strategies to curb NOx emissions. The strategies for reducing NOx are discussed next. Table 1 shows a summary of common NOx control technologies [1]. Table 1 NOx reduction technologies... for NOx Control, in Industrial Combustion Technologies, ed. by M.A. Lukasiewicz, American Society of Metals, Warren, PA, pp. 345-350, 1986. 7. A. Garg, Trimming NOx, Chem Eng., Vol. 99, No. 11, pp. 122-124, 1992. 8. C.E. Baukal, Industrial Combustion...

  18. CEC-500-2010-FS-017 Volatility of Ultrafine Particulate

    E-Print Network [OSTI]

    Gas Vehicles TRANSPORTATION ENERGY RESEARCH PIER Transportation Research www. Limited research has been done to characterize compressed natural gas mass emissions and practically-volatile and semi-volatile fractions of ultrafine particulate matter emissions from compressed natural gas vehicles

  19. air particulate exposure: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    25 Next Page Last Page Topic Index 1 Research Commuters Exposure to Particulate Matter Air Pollution Is Affected by Mode of Transport, Fuel Type, and Route CiteSeer Summary: Ba...

  20. 2008-01-0333 Detailed Effects of a Diesel Particulate Filter on the Reduction

    E-Print Network [OSTI]

    Wu, Mingshen

    2008-01-0333 Detailed Effects of a Diesel Particulate Filter on the Reduction of Chemical Species of Wisconsin-Madison Copyright © 2008 SAE International ABSTRACT Diesel particulate filters are designed to reduce the mass emissions of diesel particulate matter and have been proven to be effective

  1. Control of NOx by combustion process modifications

    E-Print Network [OSTI]

    Ber?, J. M.

    1981-01-01T23:59:59.000Z

    A theoretical and experimental study was carried out to determine lower bounds of NOx emission from staged combustion of a 0.7%N #6 fuel oil. Thermodynamic and chemical kinetic calculations have shown minimum NOx emissions ...

  2. NOx adsorber and method of regenerating same

    DOE Patents [OSTI]

    Endicott, Dennis L. (Peoria, IL); Verkiel, Maarten (Metamora, IL); Driscoll, James J. (Dunlap, IL)

    2007-01-30T23:59:59.000Z

    New technologies, such as NOx adsorber catalytic converters, are being used to meet increasingly stringent regulations on undesirable emissions, including NOx emissions. NOx adsorbers must be periodically regenerated, which requires an increased fuel consumption. The present disclosure includes a method of regenerating a NOx adsorber within a NOx adsorber catalytic converter. At least one sensor positioned downstream from the NOx adsorber senses, in the downstream exhaust, at least one of NOx, nitrous oxide and ammonia concentrations a plurality of times during a regeneration phase. The sensor is in communication with an electronic control module that includes a regeneration monitoring algorithm operable to end the regeneration phase when a time rate of change of the at least one of NOx, nitrous oxide and ammonia concentrations is after an expected plateau region begins.

  3. COMPARATIVE EVALUATION OF AMBIENT FINE PARTICULATE MATTER (PM2.5) DATA OBTAINED FROM URBAN AND RURAL MONITORING SITES ALONG THE UPPER OHIO RIVER VALLEY

    SciTech Connect (OSTI)

    Robinson P. Khosah; John P. Shimshock

    2004-03-02T23:59:59.000Z

    Advanced Technology Systems, Inc. (ATS), with Desert Research Institute (DRI) and Ohio University as subcontractors, was contracted by the NETL in September 1998 to manage the Upper Ohio River Valley Project (UORVP), with a goal of characterizing the ambient fine particulate in this region, including examination of urban/rural variations, correlations between PM{sub 2.5} and gaseous pollutants, and influences of artifacts on PM{sub 2.5} measurements in this region. Two urban and two rural monitoring sites were included in the UORVP. The four sites selected were all part of existing local and/or state air quality programs. One urban site was located in the Lawrenceville section of Pittsburgh, Pennsylvania at an air quality monitoring station operated by the Allegheny County Health Department. A second urban site was collocated at a West Virginia Division of Environmental Protection (WVDEP) monitoring station at the airport in Morgantown, West Virginia. One rural site was collocated with the Pennsylvania Department of Environmental Protection (PADEP) at a former NARSTO-Northeast site near Holbrook, Greene County, Pennsylvania. The other rural site was collocated at a site operated by the Ohio Environmental Protection Agency (OHEPA) and managed by the Ohio State Forestry Division in Gifford State Forest near Athens, Ohio. Previous Semi-Annual Technical Progress Reports presented the following: (1) the median mass and composition of PM{sub 2.5} are similar for both Lawrenceville and Holbrook, suggesting that the sites are impacted more by the regional than by local effects; (2) there was no significant differences in the particulate trending and levels observed at both sites within seasons; (3) sulfate levels predominate at both sites and (4) PM{sub 2.5} and PM{sub 10} mass concentration levels are consistently higher in summer than in winter, with intermediate levels being observed in the fall and spring. Analyses of data conducted during the period from April 1, 2003 through September 30, 2003 are presented in this Semi-Annual Technical Progress Report. Report Revision No. 1 includes the additions or removals of text presented in the previous version of this report.

  4. COMPARATIVE EVALUATION OF AMBIENT FINE PARTICULATE MATTER (PM2.5)DATA OBTAINED FROM URBAN AND RURAL MONITORING SITES ALONG THE UPPER OHIO RIVER VALLEY

    SciTech Connect (OSTI)

    Robinson P. Khosah; John P. Shimshock

    2003-04-30T23:59:59.000Z

    Advanced Technology Systems, Inc. (ATS), with Desert Research Institute (DRI) and Ohio University as subcontractors, was contracted by the NETL in September 1998 to manage the Upper Ohio River Valley Project (UORVP), with a goal of characterizing the ambient fine particulate in this region, including examination of urban/rural variations, correlations between PM{sub 2.5} and gaseous pollutants, and influences of artifacts on PM{sub 2.5} measurements in this region. Two urban and two rural monitoring sites were included in the UORVP. The four sites selected were all part of existing local and/or state air quality programs. One urban site was located in the Lawrenceville section of Pittsburgh, Pennsylvania at an air quality monitoring station operated by the Allegheny County Health Department. A second urban site was collocated at a West Virginia Division of Environmental Protection (WVDEP) monitoring station at the airport in Morgantown, West Virginia. One rural site was collocated with the Pennsylvania Department of Environmental Protection (PADEP) at a former NARSTO-Northeast site near Holbrook, Greene County, Pennsylvania. The other rural site was collocated at a site operated by the Ohio Environmental Protection Agency (OHEPA) and managed by the Ohio State Forestry Division in Gifford State Forest near Athens, Ohio. Analysis of data collected to date show that: (1) the median mass and composition of PM{sub 2.5} are similar for both Lawrenceville and Holbrook, suggesting that the sites are impacted more by the regional than by local effects; (2) there was no significant differences in the particulate trending and levels observed at both sites within seasons; (3) sulfate levels predominate at both sites, and (4) PM{sub 2.5} and PM{sub 10} mass concentration levels are consistently higher in summer than in winter, with intermediate levels being observed in the fall and spring. Data analysis focusing on relating the aerometric measurements to local and regional scale emissions of sources of primary and secondary fine particles using receptor-based air quality models will follow.

  5. Modeling The NOx Emissions In A Low NOx Burner While Fired With Pulverized Coal And Dairy Biomass Blends

    E-Print Network [OSTI]

    Uggini, Hari

    2012-07-16T23:59:59.000Z

    Hydrogen Cyanide HHV Higher Heating Value LNB Low NOx Burner PRB Powder River Basin TAMU Texas A&M University CABEL Coal And Biomass Energy Laboratory ER Equivalence Ratio VM Volatile Matter FC Fixed Carbon OFA Over Fired Air (tertiary air... ......................................... 33 5.1 Numerical model algorithm ..................................................................... 47 5.2 Pure PRB NO vs. overall ER ................................................................... 49 5.3 Oxygen concentration along...

  6. Non-thermal Aftertreatment of Particulates

    SciTech Connect (OSTI)

    Thomas, S.E.

    2000-08-20T23:59:59.000Z

    Modern diesel passenger vehicles employing common rail, high speed direct injection engines are capable of matching the drivability of gasoline powered vehicles with the additional benefit of providing high torque at low engine speed [1]. The diesel engine also offers considerable fuel economy and CO2 emissions advantages. However, future emissions standards [2,3] present a significant challenge for the diesel engine, as its lean exhaust precludes the use of aftertreatment strategies employing 3- way catalytic converters, which operate under stoichiometric conditions. In recent years significant developments by diesel engine manufacturers have greatly reduced emissions of both particulates (PM) and oxides of nitrogen (NOx) [4,5]. However to achieve compliance with future legislative limits it has been suggested that an integrated approach involving a combination of engine modifications and aftertreatment technology [1] will be required. A relatively new approach to exhaust aftertreatment is the application of non-thermal plasma (NTP) or plasma catalyst hybrid systems. These have the potential for treatment of both NOx and PM emissions [6- 8]. The primary focus of recent plasma aftertreatment studies [9-12] has concentrated on the removal of NOx. It has been shown that by combining plasmas with catalysts it is possible to chemically reduce NOx. The most common approach is to use a 2- stage system relying upon the plasma oxidation of hydrocarbons to promote NO to NO2 conversion as a precursor to NO2 reduction over a catalyst. However, relatively little work has yet been published on the oxidation of PM by plasma [ 8,13]. Previous investigations [8] have reported that a suitably designed NTP reactor containing a packing material designed to filter and retain PM can effect the oxidation of PM in diesel exhausts at low temperatures. It has been suggested that the retained PM competes with hydrocarbons for O, and possibly OH, radicals. This is an important consideration in plasma - catalyst hybrid schemes for the removal of NOx employing an NO2 selective catalyst, as the oxidation of PM may deplete the key radicals necessary for NO to NO2 conversion. It was also suggested that where simultaneous NOx and PM removal are required, alternative catalyst formulations may be needed which may be selective to NO rather than NO2.

  7. Developing an accelerated aging system for gasoline particulate filters and an evaluation test for effects on engine performance

    E-Print Network [OSTI]

    Jorgensen, James E. (James Eastman)

    2014-01-01T23:59:59.000Z

    Stringent regulations worldwide will limit the level of particulate matter (PM) emitted from gasoline engines equipped with direct fuel injection. Gasoline particulate filters (GPFs) present one strategy for meeting PM ...

  8. Reducing NOx in Fired Heaters and Boilers 

    E-Print Network [OSTI]

    Garg, A.

    2000-01-01T23:59:59.000Z

    -6, 2000 Reducing NOx in Fired Heaters Air Pollution Control and Boilers Keeping the environment clean Presented by Ashutosh Garg Furnace Improvements Low cost solutions for fired heaters Trace compounds ? Nitric oxides ? Carbon monoxide ? Sulfur... million BTU ? These levels can be achieved by Ultra Low NOx burners or FGR in boilers. ? Primary products of combustion ? Carbon dioxide ? Water vapors ? Oxygen ? Nitrogen ? Trace compounds NOx emissions ? NOx or Oxides of Nitrogen have...

  9. The distribution of particulate matter in the Equatorial and Subtropical South Atlantic Ocean: evidence for sources, transport and sinks of particles

    E-Print Network [OSTI]

    Berglund, Bret Lawrence

    1989-01-01T23:59:59.000Z

    matter in the oceans (including Feely, 1975; Bishop et al. , 1977, 1978, 1980; Bishop and Biscaye, 1982; Gardner et al. , 1985a; Richardson, 1987). Generally, the component particles can be divided into three groupings based on their origin (adapted... from Tchernia (1980). nitrate and phosphate are published in the cruise reports [Oceanographic Data Facility (ODF), 1988a; b and c]. In the western basin of the study area, the water column can be divided into the following vertical sequences (from...

  10. Chemopreventive activity of compounds extracted from Casearia sylvestris (Salicaceae) Sw against DNA damage induced by particulate matter emitted by sugarcane burning near Araraquara, Brazil

    SciTech Connect (OSTI)

    Prieto, A.M. [UNESP — Univ. Estadual Paulista, College of Pharmaceutical Sciences, Department of Clinical Analysis, Rua Expedicionários do Brasil, 1621, Araraquara (Brazil)] [UNESP — Univ. Estadual Paulista, College of Pharmaceutical Sciences, Department of Clinical Analysis, Rua Expedicionários do Brasil, 1621, Araraquara (Brazil); Santos, A.G. [UNESP — Univ. Estadual Paulista, College of Pharmaceutical Sciences, Department of Natural Principles and Toxicology, Rodovia Araraquara-Jau, km 01, Araraquara (Brazil)] [UNESP — Univ. Estadual Paulista, College of Pharmaceutical Sciences, Department of Natural Principles and Toxicology, Rodovia Araraquara-Jau, km 01, Araraquara (Brazil); Csipak, A.R.; Caliri, C.M.; Silva, I.C. [UNESP — Univ. Estadual Paulista, College of Pharmaceutical Sciences, Department of Clinical Analysis, Rua Expedicionários do Brasil, 1621, Araraquara (Brazil)] [UNESP — Univ. Estadual Paulista, College of Pharmaceutical Sciences, Department of Clinical Analysis, Rua Expedicionários do Brasil, 1621, Araraquara (Brazil); Arbex, M.A. [UNIFESP — Federal University of São Paulo, Paulista College of Medicine, Department of Internal Medicine, Rua Pedro de Toledo, 720, São Paulo (Brazil)] [UNIFESP — Federal University of São Paulo, Paulista College of Medicine, Department of Internal Medicine, Rua Pedro de Toledo, 720, São Paulo (Brazil); Silva, F.S.; Marchi, M.R.R. [UNESP — Univ. Estadual Paulista, Chemistry Institute, Department of Analytical Chemistry, Rua Francisco Degni, S/N, Araraquara (Brazil)] [UNESP — Univ. Estadual Paulista, Chemistry Institute, Department of Analytical Chemistry, Rua Francisco Degni, S/N, Araraquara (Brazil); Cavalheiro, A.J.; Silva, D.H.S.; Bolzani, V.S. [UNESP — Univ. Estadual Paulista, Chemistry Institute, Department of Organic Chemistry, Rua Francisco Degni, S/N, Araraquara (Brazil)] [UNESP — Univ. Estadual Paulista, Chemistry Institute, Department of Organic Chemistry, Rua Francisco Degni, S/N, Araraquara (Brazil); Soares, C.P., E-mail: soarescp@hotmail.com [UNESP — Univ. Estadual Paulista, College of Pharmaceutical Sciences, Department of Clinical Analysis, Rua Expedicionários do Brasil, 1621, Araraquara (Brazil)

    2012-12-15T23:59:59.000Z

    Ethanolic extract of Casearia sylvestris is thought to be antimutagenic. In this study, we attempted to determine whether this extract and casearin X (a clerodane diterpene from C. sylvestris) are protective against the harmful effects of airborne pollutants from sugarcane burning. To that end, we used the Tradescantia micronucleus test in meiotic pollen cells of Tradescantia pallida, the micronucleus test in mouse bone marrow cells, and the comet assay in mouse blood cells. The mutagenic compound was total suspended particulate (TSP) from air. For the Tradescantia micronucleus test, T. pallida cuttings were treated with the extract at 0.13, 0.25, or 0.50 mg/ml. Subsequently, TSP was added at 0.3 mg/ml, and tetrads from the inflorescences were examined for micronuclei. For the micronucleus test in mouse bone marrow cells and the comet assay in mouse blood cells, Balb/c mice were treated for 15 days with the extract—3.9, 7.5, or 15.0 mg/kg body weight (BW)—or with casearin X—0.3, 0.25, or 1.2 mg/kg BW—after which they received TSP (3.75 mg/kg BW). In T. pallida and mouse bone marrow cells, the extract was antimutagenic at all concentrations tested. In mouse blood cells, the extract was antigenotoxic at all concentrations, whereas casearin X was not antimutagenic but was antigenotoxic at all concentrations. We conclude that C. sylvestris ethanolic extract and casearin X protect DNA from damage induced by airborne pollutants from sugarcane burning. -- Highlights: ? We assessed DNA protection of C. sylvestris ethanolic extract. ? We assessed DNA protection of casearin X. ? We used Tradescantia pallida micronucleus test as screening. ? We used comet assay and micronucleus test in mice. ? The compounds protected DNA against sugar cane burning pollutants.

  11. Particulate hot gas stream cleanup technical issues

    SciTech Connect (OSTI)

    Pontius, D.H.; Snyder, T.R.

    1999-09-30T23:59:59.000Z

    The analyses of hot gas stream cleanup particulate samples and descriptions of filter performance studied under this contract were designed to address problems with filter operation that have been linked to characteristics of the collected particulate matter. One objective of this work was to generate an interactive, computerized data bank of the key physical and chemical characteristics of ash and char collected from operating advanced particle filters and to relate these characteristics to the operation and performance of these filters. The interactive data bank summarizes analyses of over 160 ash and char samples from fifteen pressurized fluidized-bed combustion and gasification facilities utilizing high-temperature, high pressure barrier filters.

  12. Method for immobilizing particulate materials in a packed bed

    DOE Patents [OSTI]

    Even, Jr., William R. (Livermore, CA); Guthrie, Stephen E. (Livermore, CA); Raber, Thomas N. (Livermore, CA); Wally, Karl (Lafayette, CA); Whinnery, LeRoy L. (Livermore, CA); Zifer, Thomas (Manteca, CA)

    1999-01-01T23:59:59.000Z

    The present invention pertains generally to immobilizing particulate matter contained in a "packed" bed reactor so as to prevent powder migration, compaction, coalescence, or the like. More specifically, this invention relates to a technique for immobilizing particulate materials using a microporous foam-like polymer such that a) the particulate retains its essential chemical nature, b) the local movement of the particulate particles is not unduly restricted, c) bulk powder migration and is prevented, d) physical and chemical access to the particulate is unchanged over time, and e) very high particulate densities are achieved. The immobilized bed of the present invention comprises a vessel for holding particulate matter, inlet and an outlet ports or fittings, a loosely packed bed of particulate material contained within the vessel, and a three dimensional porous matrix for surrounding and confining the particles thereby fixing the movement of individual particle to a limited local position. The established matrix is composed of a series of cells or chambers comprising walls surrounding void space, each wall forming the wall of an adjacent cell; each wall containing many holes penetrating through the wall yielding an overall porous structure and allowing useful levels of gas transport.

  13. Airborne particulate discriminator

    DOE Patents [OSTI]

    Creek, Kathryn Louise (San Diego, CA); Castro, Alonso (Santa Fe, NM); Gray, Perry Clayton (Los Alamos, NM)

    2009-08-11T23:59:59.000Z

    A method and apparatus for rapid and accurate detection and discrimination of biological, radiological, and chemical particles in air. A suspect aerosol of the target particulates is treated with a taggant aerosol of ultrafine particulates. Coagulation of the taggant and target particles causes a change in fluorescent properties of the cloud, providing an indication of the presence of the target.

  14. Fuel Efficient Diesel Particulate Filter (DPF) Modeling and Development

    SciTech Connect (OSTI)

    Stewart, Mark L.; Gallant, Thomas R.; Kim, Do Heui; Maupin, Gary D.; Zelenyuk, Alla

    2010-08-01T23:59:59.000Z

    The project described in this report seeks to promote effective diesel particulate filter technology with minimum fuel penalty by enhancing fundamental understanding of filtration mechanisms through targeted experiments and computer simulations. The overall backpressure of a filtration system depends upon complex interactions of particulate matter and ash with the microscopic pores in filter media. Better characterization of these phenomena is essential for exhaust system optimization. The acicular mullite (ACM) diesel particulate filter substrate is under continuing development by Dow Automotive. ACM is made up of long mullite crystals which intersect to form filter wall framework and protrude from the wall surface into the DPF channels. ACM filters have been demonstrated to effectively remove diesel exhaust particles while maintaining relatively low backpressure. Modeling approaches developed for more conventional ceramic filter materials, such as silicon carbide and cordierite, have been difficult to apply to ACM because of properties arising from its unique microstructure. Penetration of soot into the high-porosity region of projecting crystal structures leads to a somewhat extended depth filtration mode, but with less dramatic increases in pressure drop than are normally observed during depth filtration in cordierite or silicon carbide filters. Another consequence is greater contact between the soot and solid surfaces, which may enhance the action of some catalyst coatings in filter regeneration. The projecting crystals appear to provide a two-fold benefit for maintaining low backpressures during filter loading: they help prevent soot from being forced into the throats of pores in the lower porosity region of the filter wall, and they also tend to support the forming filter cake, resulting in lower average cake density and higher permeability. Other simulations suggest that soot deposits may also tend to form at the tips of projecting crystals due to the axial velocity component of exhaust moving down the filter inlet channel. Soot mass collected in this way would have a smaller impact on backpressure than soot forced into the flow restrictions deeper in the porous wall structure. This project has focused on the development of computational, analytical, and experimental techniques that are generally applicable to a wide variety of exhaust aftertreatment technologies. By helping to develop improved fundamental understanding pore-scale phenomena affecting filtration, soot oxidation, and NOX abatement, this cooperative research and development agreement (CRADA) has also assisted Dow Automotive in continuing development and commercialization of the ACM filter substrate. Over the course of this research project, ACM filters were successfully deployed on the Audi R10 TDI racecar which won the 24 Hours of LeMans endurance race in 2006, 2007, and 2008; and the 12 Hours of Sebring endurance race in 2006 and 2007. It would not have been possible for the R10 to compete in these traditionally gasoline-dominated events without reliable and effective exhaust particulate filtration. These successes demonstrated not only the performance of automotive diesel engines, but the efficacy of DPF technology as it was being deployed around the world to meet new emissions standards on consumer vehicles. During the course of this CRADA project, Dow Automotive commercialized their ACM DPF technology under the AERIFYTM DPF brand.

  15. SOx-NOx-Rox Box{trademark} flue gas clean-up demonstration. Final report

    SciTech Connect (OSTI)

    NONE

    1995-09-01T23:59:59.000Z

    Babcock and Wilcox`s (B and W) SOx-NOx-Rox Box{trademark} process effectively removes SOx, NOx and particulate (Rox) from flue gas generated from coal-fired boilers in a single unit operation, a high temperature baghouse. The SNRB technology utilizes dry sorbent injection upstream of the baghouse for removal of SOx and ammonia injection upstream of a zeolitic selective catalytic reduction (SCR) catalyst incorporated in the baghouse to reduce NOx emissions. Because the SOx and NOx removal processes require operation at elevated gas temperatures (800--900 F) for high removal efficiency, high-temperature fabric filter bags are used in the baghouse. The SNRB technology evolved from the bench and laboratory pilot scale to be successfully demonstrated at the 5-MWe field scale. This report represents the completion of Milestone M14 as specified in the Work Plan. B and W tested the SNRB pollution control system at a 5-MWe demonstration facility at Ohio Edison`s R.E. Burger Plant located near Shadyside, Ohio. The design and operation were influenced by the results from laboratory pilot testing at B and W`s Alliance Research Center. The intent was to demonstrate the commercial feasibility of the SNRB process. The SNRB facility treated a 30,000 ACFM flue gas slipstream from Boiler No. 8. Operation of the facility began in May 1992 and was completed in May 1993. About 2,300 hours of high-temperature operation were achieved. The main emissions control performance goals of: greater than 70% SO{sub 2} removal using a calcium-based sorbent; greater than 90% NOx removal with minimal ammonia slip; and particulate emissions in compliance with the New Source Performance Standards (NSPS) of 0.03 lb/million Btu were exceeded simultaneously in the demonstration program when the facility was operated at optimal conditions. Testing also showed significant reductions in emissions of some hazardous air pollutants.

  16. NOx Reduction through Efficiency Gain

    E-Print Network [OSTI]

    Benz, R.; Thompson, R.; Staedter, M.

    2007-01-01T23:59:59.000Z

    Approach, Fifth Edition, McGraw-Hill, June 2005 Kuo, K. K., Principles of Combustion 2 nd Edition, Wiley, January 2005 Erickson, K. T., Plant-Wide Process Control, 1 st Edition, Wiley, April 2005 ESL-IE-07-05-42 Proceedings... putting financial stress on steam generation plants to adhere to environmental regulations we provide an incentive to do so. The simplicity and elegance of the CompuNOx system minimizes system changes. Control related changes consist...

  17. Particulate Air Pollution, Ambulatory Heart Rate Variability, and Cardiac Arrhythmia in Retirement Community Residents with Coronary Artery Disease

    E-Print Network [OSTI]

    Bartell, Scott M.; Longhurst, John; Tjoa, Thomas; Sioutas, Constantinos; Delfino, Ralph J.

    2013-01-01T23:59:59.000Z

    in association with air pollution and air temperature amongvariability with traffic and air pollution in patients withParticulate matter air pollution and cardiovascular disease:

  18. Particulate air pollution, ambulatory heart rate variability, and cardiac arrhythmia in retirement community residents with coronary artery disease.

    E-Print Network [OSTI]

    Bartell, Scott M; Longhurst, John; Tjoa, Thomas; Sioutas, Constantinos; Delfino, Ralph J

    2013-01-01T23:59:59.000Z

    in association with air pollution and air temperature amongvariability with traffic and air pollution in patients withParticulate matter air pollution and cardiovascular disease:

  19. Air Pollution Control Regulations: No. 13- Particulate Emissions from Fossil Fuel Fired Steam or Hot Water Generating Units (Rhode Island)

    Broader source: Energy.gov [DOE]

    The purpose of this regulation is to limit emissions of particulate matter from fossil fuel fired and wood-fired steam or hot water generating units.

  20. Advanced Hybrid Particulate Collector Project Management Plan

    SciTech Connect (OSTI)

    Miller, S.J.

    1995-11-01T23:59:59.000Z

    As the consumption of energy increases, its impact on ambient air quality has become a significant concern. Recent studies indicate that fine particles from coal combustion cause health problems as well as atmospheric visibility impairment. These problems are further compounded by the concentration of hazardous trace elements such as mercury, cadmium, selenium, and arsenic in fine particles. Therefore, a current need exists to develop superior, but economical, methods to control emissions of fine particles. Since most of the toxic metals present in coal will be in particulate form, a high level of fine- particle collection appears to be the best method of overall air toxics control. However, over 50% of mercury and a portion of selenium emissions are in vapor form and cannot be collected in particulate control devices. Therefore, this project will focus on developing technology not only to provide ultrahigh collection efficiency of particulate air toxic emissions, but also to capture vapor- phase trace metals such as mercury and selenium. Currently, the primary state-of-the-art technologies for particulate control are fabric filters (baghouses) and electrostatic precipitators (ESPs). However, they both have limitations that prevent them from achieving ultrahigh collection of fine particulate matter and vapor-phase trace metals. The objective of this project is to develop a highly reliable advanced hybrid particulate collector (AHPC) that can provide > 99.99 % particulate collection efficiency for all particle sizes between 0.01 and 50 14m, is applicable for use with all U.S. coals, and is cost-0443competitive with existing technologies. Phase I of the project is organized into three tasks: Task I - Project Management, Reporting, and Subcontract Consulting Task 2 - Modeling, Design, and Construction of 200-acfm AHPC Model Task 3 - Experimental Testing and Subcontract Consulting

  1. NOx reduction in gas turbine combustors

    E-Print Network [OSTI]

    Sung, Nak Won

    1976-01-01T23:59:59.000Z

    NOx REDUCTION IN GAS TURBINE COMBUSTORS A Thesis by Nak Won Sung Submitted to the Graduate College of Texas A&M University in partial fullfillment of the requirement for the degree of MASTER OF SCIENCE August 1976 Major Subject: Mechanical... Engineering NOx REDUCTION IN GAS TURBINE COMBUSTORS A Thesis by Nak Won Sung Approved as to style and content by: (Chairman of Committe (Head of Department) (Member) August 1976 "40308 (Member) 1 1. 1 ABSTRACT NOx Reduction in Gas Turbine...

  2. Plasma Assisted Catalysis System for NOx Reduction

    Broader source: Energy.gov (indexed) [DOE]

    2 NOXTECH NOXTECH PLASMA ASSISTED CATALYSIS SYSTEM FOR NOx REDUCTION BY NOXTECH With the Support & Cooperation of DOE Noxtech, Inc. *Delaware Corporation registered to do business...

  3. Detailed Characterization of Particulates Emitted by Pre-Commercial Single-Cylinder Gasoline Compression Ignition Engine

    SciTech Connect (OSTI)

    Zelenyuk, Alla; Reitz, Paul; Stewart, Mark L.; Imre, D.; Loeper, Paul; Adams, Cory; Andrie, Michael; Rothamer, David; Foster, David E.; Narayanaswamy, Kushal; Najt, Paul M.; Solomon, Arun S.

    2014-08-01T23:59:59.000Z

    Gasoline Compression Ignition (GCI) engines have the potential to achieve high fuel efficiency and to significantly reduce both NOx and particulate matter (PM) emissions by operating under dilute partially-premixed conditions. This low temperature combustion strategy is dependent upon direct-injection of gasoline during the compression stroke and potentially near top dead center (TDC). The timing and duration of the in-cylinder injections can be tailored based on speed and load to create optimized conditions that result in a stable combustion. We present the results of advanced aerosol analysis methods that have been used for detailed real-time characterization of PM emitted from a single-cylinder GCI engine operated at different speed, load, timing, and number and duration of near-TDC fuel injections. PM characterization included 28 measurements of size and composition of individual particles sampled directly from the exhaust and after mass and/or mobility classification. We use these data to calculate particle effective density, fractal dimension, dynamic shape factors in free-molecular and transition flow regimes, average diameter of primary spherules, number of spherules, and void fraction of soot agglomerates.

  4. Face crack reduction strategy for particulate filters

    DOE Patents [OSTI]

    Gonze, Eugene V [Pinckney, MI

    2012-01-31T23:59:59.000Z

    A system comprises a particulate matter (PM) filter that comprises an upstream end for receiving exhaust gas, a downstream end and at least one portion. A control module initiates combustion of PM in the PM filter using a heater and selectively adjusts oxygen levels of the exhaust gas to adjust a temperature of combustion adjacent to the at least one portion of the PM filter. A method comprises providing a particulate matter (PM) filter that comprises an upstream end for receiving exhaust gas, a downstream end and at least one portion; initiating combustion of PM in the PM filter using a heater; selectively adjusting oxygen levels of the exhaust gas to adjust a temperature of combustion adjacent to the at least one portion of the PM filter.

  5. Method of feeding particulate material to a fluidized bed

    DOE Patents [OSTI]

    Borio, Richard W. (Somers, CT); Goodstine, Stephen L. (Windsor, CT)

    1984-01-01T23:59:59.000Z

    A centrifugal spreader type feeder that supplies a mixture of particulate limestone and coal to the top of a fluidized bed reactor having a flow of air upward therethrough. Large particles of particulate matter are distributed over the upper surface of the bed to utilize the natural mixing within the bed, while fine particles are adapted to utilize an independent feeder that separates them from the large particles and injects them into the bed.

  6. Particulate contamination removal from wafers using plasmas and mechanical agitation

    DOE Patents [OSTI]

    Selwyn, Gary S. (Los Alamos, NM)

    1998-01-01T23:59:59.000Z

    Particulate contamination removal from wafers using plasmas and mechanical agitation. The present invention includes the use of plasmas with mechanical agitation for removing particulate matter from the surface of a wafer. The apparatus hereof comprises a mechanical activator, at least one conducting contact pin for transferring the vibration from the activator to the wafer, clamp fingers that maintain the wafer's position, and means for generating a plasma in the vicinity of the surface of the wafer, all parts of the cleaning apparatus except the mechanical activator and part of the contact pin being contained inside the processing chamber. By exposing a wafer to a plasma and providing motion thereto in a direction perpendicular to its surface, the bonding between the particulate matter and the surface may be overcome. Once free of the wafer surface, the particulates become charged by electrons from the plasma and are drawn into the plasma by attractive forces which keep them from redepositing. The introduction of a flowing gas through the plasma sweeps the particulates away from the wafer and out of the plasma. The entire surface is cleaned during one cleaning step. The use of an rf plasma to accomplish the particulate removal was found to remove more than 90% of the particulates.

  7. Particulate contamination removal from wafers using plasmas and mechanical agitation

    DOE Patents [OSTI]

    Selwyn, G.S.

    1998-12-15T23:59:59.000Z

    Particulate contamination removal from wafers is disclosed using plasmas and mechanical agitation. The present invention includes the use of plasmas with mechanical agitation for removing particulate matter from the surface of a wafer. The apparatus hereof comprises a mechanical activator, at least one conducting contact pin for transferring the vibration from the activator to the wafer, clamp fingers that maintain the wafer`s position, and means for generating a plasma in the vicinity of the surface of the wafer, all parts of the cleaning apparatus except the mechanical activator and part of the contact pin being contained inside the processing chamber. By exposing a wafer to a plasma and providing motion thereto in a direction perpendicular to its surface, the bonding between the particulate matter and the surface may be overcome. Once free of the wafer surface, the particulates become charged by electrons from the plasma and are drawn into the plasma by attractive forces which keep them from redepositing. The introduction of a flowing gas through the plasma sweeps the particulates away from the wafer and out of the plasma. The entire surface is cleaned during one cleaning step. The use of an rf plasma to accomplish the particulate removal was found to remove more than 90% of the particulates. 4 figs.

  8. Power Generating Stationary Engines Nox Control: A Closed Loop...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Generating Stationary Engines Nox Control: A Closed Loop Control Technology Power Generating Stationary Engines Nox Control: A Closed Loop Control Technology Poster presented at...

  9. Selective reduction of NOx in oxygen rich environments with plasma...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Catalysis for Heavy-Duty Diesel Emissions Control Heavy-Duty NOx Emissions Control: Reformer-Assisted vs. Plasma-Facilitated Lean NOx Catalysis Dynamometer Evaluation of...

  10. An Experimental Investigation of the Origin of Increased NOx...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    NOx Emissions When Fueling a Heavy-Duty Compression-Ignition Engine with Soy Biodiesel An Experimental Investigation of the Origin of Increased NOx Emissions When Fueling...

  11. Measurement and Characterization of Lean NOx Adsorber Regeneration...

    Broader source: Energy.gov (indexed) [DOE]

    parks.pdf More Documents & Publications Synergies of High-Efficiency Clean Combustion and Lean NOx Trap Catalysts Measurement and Characterization of Lean NOx Adsorber Regeneration...

  12. Deactivation mechanisms of NOx storage materials arising from...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    mechanisms of NOx storage materials arising from thermal aging and sulfur poisoning Deactivation mechanisms of NOx storage materials arising from thermal aging and sulfur poisoning...

  13. Retrofit Diesel Emissions Control System Providing 50% NOxControl...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Diesel Emissions Control System Providing 50% NOxControl Retrofit Diesel Emissions Control System Providing 50% NOxControl 2005 Diesel Engine Emissions Reduction (DEER) Conference...

  14. Three-Dimensional Composite Nanostructures for Lean NOx Emission...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Three-Dimensional Composite Nanostructures for Lean NOx Emission Control Monolithic Metal Oxide based Composite Nanowire Lean NOx Emission Control...

  15. Monolithic Metal Oxide based Composite Nanowire Lean NOx Emission...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Monolithic Metal Oxide based Composite Nanowire Lean NOx Emission Control Catalysts Monolithic Metal Oxide based Composite Nanowire Lean NOx Emission Control Catalysts Presents...

  16. Virtual Oxygen Sensor for Innovative NOx and PM Emission Control...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Virtual Oxygen Sensor for Innovative NOx and PM Emission Control Technologies Virtual Oxygen Sensor for Innovative NOx and PM Emission Control Technologies A virtual O2 sensor for...

  17. NOx Abatement Research and Development CRADA with Navistar Incorporate...

    Broader source: Energy.gov (indexed) [DOE]

    NOx Abatement Research and Development CRADA with Navistar Incorporated NOx Abatement Research and Development CRADA with Navistar Incorporated 2009 DOE Hydrogen Program and...

  18. Functionality of Commercial NOx Storage-Reduction Catalysts and...

    Broader source: Energy.gov (indexed) [DOE]

    Catalysis Research: Fundamental SulfationDesulfation Studies of Lean NOx Traps CumminsORNL-FEERC CRADA: NOx Control & Measurement Technology for Heavy-Duty Diesel Engines...

  19. 8, 49114947, 2008 NOx-induced ozone

    E-Print Network [OSTI]

    Boyer, Edmond

    ACPD 8, 4911­4947, 2008 NOx-induced ozone loss processes B. Vogel et al. Title Page Abstract Chemistry and Physics Discussions Model simulations of stratospheric ozone loss caused by enhanced on behalf of the European Geosciences Union. 4911 #12;ACPD 8, 4911­4947, 2008 NOx-induced ozone loss

  20. Minimize NOx using only combustion control

    SciTech Connect (OSTI)

    Penterson, C.A.; Hules, K.R. [Riley Power Inc. (United States)

    2005-10-01T23:59:59.000Z

    The retrofit of a 600 MW opposed wall-fired utility boiler with low-NOx, dual air zone burners and overfire air cut the Wyoming PRB coal burner's NOx output by nearly half. The key to the project's success from the design stage through final testing and boiler tuning was CFD modeling. 7 figs., 2 tabs.

  1. Radiant zone heated particulate filter

    DOE Patents [OSTI]

    Gonze, Eugene V [Pinckney, MI

    2011-12-27T23:59:59.000Z

    A system includes a particulate matter (PM) filter including an upstream end for receiving exhaust gas and a downstream end. A radiant zoned heater includes N zones, where N is an integer greater than one, wherein each of the N zones includes M sub-zones, where M is an integer greater than or equal to one. A control module selectively activates at least a selected one of the N zones to initiate regeneration in downstream portions of the PM filter from the one of the N zones, restricts exhaust gas flow in a portion of the PM filter that corresponds to the selected one of the N zones, and deactivates non-selected ones of the N zones.

  2. Advanced Fine Particulate Characterization Methods

    SciTech Connect (OSTI)

    Steven Benson; Lingbu Kong; Alexander Azenkeng; Jason Laumb; Robert Jensen; Edwin Olson; Jill MacKenzie; A.M. Rokanuzzaman

    2007-01-31T23:59:59.000Z

    The characterization and control of emissions from combustion sources are of significant importance in improving local and regional air quality. Such emissions include fine particulate matter, organic carbon compounds, and NO{sub x} and SO{sub 2} gases, along with mercury and other toxic metals. This project involved four activities including Further Development of Analytical Techniques for PM{sub 10} and PM{sub 2.5} Characterization and Source Apportionment and Management, Organic Carbonaceous Particulate and Metal Speciation for Source Apportionment Studies, Quantum Modeling, and High-Potassium Carbon Production with Biomass-Coal Blending. The key accomplishments included the development of improved automated methods to characterize the inorganic and organic components particulate matter. The methods involved the use of scanning electron microscopy and x-ray microanalysis for the inorganic fraction and a combination of extractive methods combined with near-edge x-ray absorption fine structure to characterize the organic fraction. These methods have direction application for source apportionment studies of PM because they provide detailed inorganic analysis along with total organic and elemental carbon (OC/EC) quantification. Quantum modeling using density functional theory (DFT) calculations was used to further elucidate a recently developed mechanistic model for mercury speciation in coal combustion systems and interactions on activated carbon. Reaction energies, enthalpies, free energies and binding energies of Hg species to the prototype molecules were derived from the data obtained in these calculations. Bimolecular rate constants for the various elementary steps in the mechanism have been estimated using the hard-sphere collision theory approximation, and the results seem to indicate that extremely fast kinetics could be involved in these surface reactions. Activated carbon was produced from a blend of lignite coal from the Center Mine in North Dakota and sunflower hulls for the biomass material to be carbonized. The ability to remove mercury from a bituminous coal's derived flue gas was low. Removals of only 15% were attained while injecting 6 lb/Macf of activated carbon upstream of an electrostatic precipitator. Poisoning of sites on the activated carbon by SO{sub 2} and SO{sub 3} contributed to the poor mercury capture performance.

  3. Particulate matter in the south Atlantic Ocean 

    E-Print Network [OSTI]

    Wood, Megan Maria

    1993-01-01T23:59:59.000Z

    -6 of the South Atlantic Venti- lation Experiment (SAVE) from December 1988 to April 1989, during the austral summer and autumn. Beam attenuation due to particles (c ) was determined P and found to be maximal at or near the surface, decreas- ing rapidly... and gravitational settling. During their transit, they are acted upon by chemical and biological processes such as dissolution, scaveng- ing, remineralization, aggregation, and disaggregation. PM is important because it is a carrier of chemical and biological...

  4. Particulate matter in the central subtropical Pacific

    E-Print Network [OSTI]

    Colgan, Annette Renee

    1995-01-01T23:59:59.000Z

    temperature and salinity data. Since WMs tend to flow along isopycnal lines, the depth of an individual WM varies with changes in longitude and latitude. These depth changes were noted in this data set and portions of WM were distinguished at different...

  5. Plant-Wide NOx Reduction Strategies 

    E-Print Network [OSTI]

    Baukal, C.; Waibel, D.; Webster, T.

    2006-01-01T23:59:59.000Z

    (adapted from ref. 1). Technology Approximate Reduction (%) Approximate Emissions (lb/MMBtu) Standard Burners Base Case 0.14 Low-NOx Burners (LNB) 60% 0.06 Ultra-Low-NOx- Burners (ULNB) 80 – 95% 0.007 – 0.03 Flue Gas Recirculation 55% 0..., and oxidizer switching. Fuel switching is simply replacing a more polluting fuel with a less polluting fuel. For example, fuel oils generally contain some organically-bound nitrogen that produces fuel NOx. Natural gas does not normally contain any...

  6. Electrically-Assisted Diesel Particulate Filter Regeneration...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Substrate Studies of an Electrically-Assisted Diesel Particulate Filter Electrically-Assisted Diesel Particulate Filter Regeneration...

  7. Task 3.15 -- Impacts of low-NOx combustion on fly ash and slagging. Semi-annual report, July 1--December 31, 1996

    SciTech Connect (OSTI)

    Zygarlicke, C.J.; McCollor, D.P.

    1997-08-01T23:59:59.000Z

    With the advent of the Clean Air Act Amendments of 1990, the coal-fired power industry began a more accelerated move toward using low-NOx burner (LNB) technologies to reduce NOx emissions. Most LNBs incorporate less oxygen with the coal initially, creating a cooler and somewhat substoichiometric initial combustion zone, with additional oxygen added further on in the combustion process to complete char combustion. Another method used to achieve lower NOx emissions is to fire the coal substoichiometrically and add additional air through overfire air ports. Both of these methods create certain impacts on fireside performance that are different from conventional high-excess-air firing arrangements. Some of the impacts that have been noticed by the utility industry are higher levels of unburned carbon in the fly ash and bottom ash, increased boiler tube corrosion, higher particulate loadings on control devices, and changes in slagging in the main furnace. Work on the fundamental mechanisms of entrained ash and ash deposit formation during low-NOx combustion has been sparse. This project by the Energy and Environmental Research Center (EERC) focuses on the issues of entrained ash formation and slagging for low-NOx combustion systems in general. Time-resolved combustion tests under conventional and low-NOx conditions have been conducted to note particle-size formation and slagging deposition. The results from this work are yielding an increased understanding of the mechanisms of ash formation during low-NOx combustion along with methods for enhancing heat transfer and fly ash collectability. Specific objectives of this research project include (1) determining whether initial char and ash generated under low-NOx conditions have greater tendencies for slagging than conventionally generated ash and (2) determining the differences, if any, between particle size and composition for entrained ash generated under low-NOx and conventional combustion conditions.

  8. Plasma-Activated Lean NOx Catalysis for Heavy-Duty Diesel Emissions...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2002deeraardahl.pdf More Documents & Publications Heavy-Duty NOx Emissions Control: Reformer-Assisted vs. Plasma-Facilitated Lean NOx Catalysis Selective reduction of NOx in...

  9. OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL

    SciTech Connect (OSTI)

    David R. Thompson; Lawrence E. Bool; Jack C. Chen

    2004-04-01T23:59:59.000Z

    Conventional wisdom says adding oxygen to a combustion system enhances product throughput, system efficiency, and, unless special care is taken, increases NOx emissions. This increase in NOx emissions is typically due to elevated flame temperatures associated with oxygen use leading to added thermal NOx formation. Innovative low flame temperature oxy-fuel burner designs have been developed and commercialized to minimize both thermal and fuel NOx formation for gas and oil fired industrial furnaces. To be effective these systems require close to 100% oxy-fuel combustion and the cost of oxygen is paid for by fuel savings and other benefits. For applications to coal-fired utility boilers at the current cost of oxygen, however, it is not economically feasible to use 100% oxygen for NOx control. In spite of this conventional wisdom, Praxair and its team members, in partnership with the US Department of Energy National Energy Technology Laboratory, have developed a novel way to use oxygen to reduce NOx emissions without resorting to complete oxy-fuel conversion. In this concept oxygen is added to the combustion process to enhance operation of a low NOx combustion system. Only a small fraction of combustion air is replaced with oxygen in the process. By selectively adding oxygen to a low NOx combustion system it is possible to reduce NOx emissions from nitrogen-containing fuels, including pulverized coal, while improving combustion characteristics such as unburned carbon. A combination of experimental work and modeling was used to define how well oxygen enhanced combustion could reduce NOx emissions. The results of this work suggest that small amounts of oxygen replacement can reduce the NOx emissions as compared to the air-alone system. NOx emissions significantly below 0.15 lbs/MMBtu were measured. Oxygen addition was also shown to reduce carbon in ash. Comparison of the costs of using oxygen for NOx control against competing technologies, such as SCR, show that this concept offers substantial savings over SCR and is an economically attractive alternative to purchasing NOx credits or installing other conventional technologies. In conjunction with the development of oxygen based low NOx technology, Praxair also worked on developing the economically enhancing oxygen transport membrane (OTM) technology which is ideally suited for integration with combustion systems to achieve further significant cost reductions and efficiency improvements. This OTM oxygen production technology is based on ceramic mixed conductor membranes that operate at high temperatures and can be operated in a pressure driven mode to separate oxygen with infinite selectivity and high flux. An OTM material was selected and characterized. OTM elements were successfully fabricated. A single tube OTM reactor was designed and assembled. Testing of dense OTM elements was conducted with promising oxygen flux results of 100% of target flux. However, based on current natural gas prices and stand-alone air separation processes, ceramic membranes do not offer an economic advantage for this application. Under a different DOE-NETL Cooperative Agreement, Praxair is continuing to develop oxygen transport membranes for the Advanced Boiler where the economics appear more attractive.

  10. Enhanced Combustion Low NOx Pulverized Coal Burner

    SciTech Connect (OSTI)

    Ray Chamberland; Aku Raino; David Towle

    2006-09-30T23:59:59.000Z

    For more than two decades, ALSTOM Power Inc. (ALSTOM) has developed a range of low cost, in-furnace technologies for NOx emissions control for the domestic U.S. pulverized coal fired boiler market. This includes ALSTOM's internally developed TFS 2000 firing system, and various enhancements to it developed in concert with the U.S. Department of Energy (DOE). As of 2004, more than 200 units representing approximately 75,000 MWe of domestic coal fired capacity have been retrofit with ALSTOM low NOx technology. Best of class emissions range from 0.18 lb/MMBtu for bituminous coals to 0.10 lb/MMBtu for subbituminous coals, with typical levels at 0.24 lb/MMBtu and 0.13 lb/MMBtu, respectively. Despite these gains, NOx emissions limits in the U.S. continue to ratchet down for new and existing (retrofit) boiler equipment. If enacted, proposed Clear Skies legislation will, by 2008, require an average, effective, domestic NOx emissions rate of 0.16 lb/MMBtu, which number will be reduced to 0.13 lb/MMBtu by 2018. Such levels represent a 60% and 67% reduction, respectively, from the effective 2000 level of 0.40 lb/MMBtu. Low cost solutions to meet such regulations, and in particular those that can avoid the need for a costly selective catalytic reduction system (SCR), provide a strong incentive to continue to improve low NOx firing system technology to meet current and anticipated NOx control regulations. In light of these needs, ALSTOM, in cooperation with the DOE, is developing an enhanced combustion, low NOx pulverized coal burner which, when integrated with ALSTOM's state-of-the-art, globally air staged low NOx firing systems, will provide a means to achieve less than 0.15 lb/MMBtu NOx at less than 3/4 the cost of an SCR with low to no impact on balance of plant issues when firing a high volatile bituminous coal. Such coals can be more economic to fire than subbituminous or Powder River Basin (PRB) coals, but are more problematic from a NOx control standpoint as existing firing system technologies do not provide a means to meet current or anticipated regulations absent the use of an SCR. The DOE/ALSTOM program performed large pilot scale combustion testing in ALSTOM's Industrial Scale Burner Facility (ISBF) at its U.S. Power Plant Laboratories facility in Windsor, Connecticut. During this work, the near-field combustion environment was optimized to maximize NOx reduction while minimizing the impact on unburned carbon in ash, slagging and fouling, corrosion, and flame stability/turn-down under globally reducing conditions. Initially, ALSTOM utilized computational fluid dynamic modeling to evaluate a series of burner and/or near field stoichiometry controls in order to screen promising design concepts in advance of the large pilot scale testing. The third and final test, to be executed, will utilize several variants of the best nozzle tip configuration and compare performance with 3 different coals. The fuels to be tested will cover a wide range of coals commonly fired at US utilities. The completion of this work will provide sufficient data to allow ALSTOM to design, construct, and demonstrate a commercial version of an enhanced combustion low NOx pulverized coal burner. A preliminary cost/performance analysis of the developed enhanced combustion low NOx burner applied to ALSTOM's state-of-the-art TFS 2000 firing system was performed to show that the burner enhancements is a cost effective means to reduce NOx.

  11. Regenerable particulate filter

    DOE Patents [OSTI]

    Stuecker, John N. (Albuquerque, NM); Cesarano, III, Joseph (Albuquerque, NM); Miller, James E. (Albuquerque, NM)

    2009-05-05T23:59:59.000Z

    A method of making a three-dimensional lattice structure, such as a filter used to remove particulates from a gas stream, where the physical lattice structure is designed utilizing software simulation from pre-defined mass transfer and flow characteristics and the designed lattice structure is fabricated using a free-form fabrication manufacturing technique, where the periodic lattice structure is comprised of individual geometric elements.

  12. ADVANCED HYBRID PARTICULATE COLLECTOR

    SciTech Connect (OSTI)

    Stanley J. Miller; Grant L. Schelkoph; Grant E. Dunham

    2000-12-01T23:59:59.000Z

    A new concept in particulate control, called an advanced hybrid particulate collector (AHPC), is being developed under funding from the US Department of Energy. The AHPC combines the best features of electrostatic precipitators (ESPs) and baghouses in an entirely novel manner. The AHPC concept combines fabric filtration and electrostatic precipitation in the same housing, providing major synergism between the two methods, both in the particulate collection step and in transfer of dust to the hopper. The AHPC provides ultrahigh collection efficiency, overcoming the problem of excessive fine-particle emissions with conventional ESPs, and solves the problem of reentrainment and recollection of dust in conventional baghouses. Phase I of the development effort consisted of design, construction, and testing of a 5.7-m{sup 3}/min (200-acfm) working AHPC model. Results from both 8-hour parametric tests and 100-hour proof-of-concept tests with two different coals demonstrated excellent operability and greater than 99.99% fine-particle collection efficiency.

  13. Electrically heated particulate filter with reduced stress

    DOE Patents [OSTI]

    Gonze, Eugene V.

    2013-03-05T23:59:59.000Z

    A system comprises a particulate matter (PM) filter comprising an inlet for receiving exhaust gas. A zoned heater is arranged in the inlet and comprises a resistive heater comprising N zones, where N is an integer greater than one. Each of the N zones comprises M sub-zones, where M is an integer greater than one. A control module selectively activates one of the N zones to initiate regeneration in downstream portions of the PM filter from the one of the N zones and deactivates others of the N zones.

  14. Heavy-Duty NOx Emissions Control: Reformer-Assisted vs. Plasma...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    NOx Emissions Control: Reformer-Assisted vs. Plasma-Facilitated Lean NOx Catalysis Heavy-Duty NOx Emissions Control: Reformer-Assisted vs. Plasma-Facilitated Lean NOx Catalysis...

  15. Effect of Thermal Aging on NO oxidation and NOx storage in a...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Thermal Aging on NO oxidation and NOx storage in a Fully-Formulated Lean NOx Trap Effect of Thermal Aging on NO oxidation and NOx storage in a Fully-Formulated Lean NOx Trap...

  16. Cummins/ORNL-FEERC CRADA: NOx Control & Measurement Technology...

    Energy Savers [EERE]

    CumminsORNL-FEERC CRADA: NOx Control & Measurement Technology for Heavy-Duty Diesel Engines CumminsORNL-FEERC CRADA: NOx Control & Measurement Technology for Heavy-Duty Diesel...

  17. Characterization of NOx Species in Dehydrated and Hydrated Na...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    NOx Species in Dehydrated and Hydrated Na- and Ba-Y, FAU Zeolites Formed in NO Adsorption. Characterization of NOx Species in Dehydrated and Hydrated Na- and Ba-Y, FAU Zeolites...

  18. Model NOx storage systems: Storage capacity and thermal aging...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Model NOx storage systems: Storage capacity and thermal aging of BaOtheta- Al2O3NiAl(100). Model NOx storage systems: Storage capacity and thermal aging of BaOtheta- Al2O3...

  19. Cutting NOx from Diesel Engines with Membrane-Generated Nitrogen...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Cutting NOx from Diesel Engines with Membrane-Generated Nitrogen-Enriched Air Cutting NOx from Diesel Engines with Membrane-Generated Nitrogen-Enriched Air 2005 Diesel Engine...

  20. Enhanced Combustion Low NOx Pulverized Coal Burner

    SciTech Connect (OSTI)

    David Towle; Richard Donais; Todd Hellewell; Robert Lewis; Robert Schrecengost

    2007-06-30T23:59:59.000Z

    For more than two decades, Alstom Power Inc. (Alstom) has developed a range of low cost, infurnace technologies for NOx emissions control for the domestic U.S. pulverized coal fired boiler market. This includes Alstom's internally developed TFS 2000{trademark} firing system, and various enhancements to it developed in concert with the U.S. Department of Energy. As of the date of this report, more than 270 units representing approximately 80,000 MWe of domestic coal fired capacity have been retrofit with Alstom low NOx technology. Best of class emissions range from 0.18 lb/MMBtu for bituminous coal to 0.10 lb/MMBtu for subbituminous coal, with typical levels at 0.24 lb/MMBtu and 0.13 lb/MMBtu, respectively. Despite these gains, NOx emissions limits in the U.S. continue to ratchet down for new and existing boiler equipment. On March 10, 2005, the Environmental Protection Agency (EPA) announced the Clean Air Interstate Rule (CAIR). CAIR requires 25 Eastern states to reduce NOx emissions from the power generation sector by 1.7 million tons in 2009 and 2.0 million tons by 2015. Low cost solutions to meet such regulations, and in particular those that can avoid the need for a costly selective catalytic reduction system (SCR), provide a strong incentive to continue to improve low NOx firing system technology to meet current and anticipated NOx control regulations. The overall objective of the work is to develop an enhanced combustion, low NOx pulverized coal burner, which, when integrated with Alstom's state-of-the-art, globally air staged low NOx firing systems will provide a means to achieve: Less than 0.15 lb/MMBtu NOx emissions when firing a high volatile Eastern or Western bituminous coal, Less than 0.10 lb/MMBtu NOx emissions when firing a subbituminous coal, NOx reduction costs at least 25% lower than the costs of an SCR, Validation of the NOx control technology developed through large (15 MWt) pilot scale demonstration, and Documentation required for economic evaluation and commercial application. During the project performance period, Alstom performed computational fluid dynamics (CFD) modeling and large pilot scale combustion testing in its Industrial Scale Burner Facility (ISBF) at its U.S. Power Plant Laboratories facility in Windsor, Connecticut in support of these objectives. The NOx reduction approach was to optimize near-field combustion to ensure that minimum NOx emissions are achieved with minimal impact on unburned carbon in ash, slagging and fouling, corrosion, and flame stability/turn-down. Several iterations of CFD and combustion testing on a Midwest coal led to an optimized design, which was extensively combustion tested on a range of coals. The data from these tests were then used to validate system costs and benefits versus SCR. Three coals were evaluated during the bench-scale and large pilot-scale testing tasks. The three coals ranged from a very reactive subbituminous coal to a moderately reactive Western bituminous coal to a much less reactive Midwest bituminous coal. Bench-scale testing was comprised of standard ASTM properties evaluation, plus more detailed characterization of fuel properties through drop tube furnace testing and thermogravimetric analysis. Bench-scale characterization of the three test coals showed that both NOx emissions and combustion performance are a strong function of coal properties. The more reactive coals evolved more of their fuel bound nitrogen in the substoichiometric main burner zone than less reactive coal, resulting in the potential for lower NOx emissions. From a combustion point of view, the more reactive coals also showed lower carbon in ash and CO values than the less reactive coal at any given main burner zone stoichiometry. According to bench-scale results, the subbituminous coal was found to be the most amenable to both low NOx, and acceptably low combustibles in the flue gas, in an air staged low NOx system. The Midwest bituminous coal, by contrast, was predicted to be the most challenging of the three coals, with the Western bituminous coal predicted to beh

  1. Modeling of NOx formation in circular laminar jet flames

    E-Print Network [OSTI]

    Siwatch, Vivek

    2007-04-25T23:59:59.000Z

    -premixed isolated circular laminar jet flame. The jet consists of the fuel rich inner region and the O2 rich outer region. The model estimates both thermal NOx and prompt NOx assuming single step kinetics for NOx formation and a thin flame model. Further the amount...

  2. Particle Number & Particulate Mass Emissions Measurements on...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Number & Particulate Mass Emissions Measurements on a 'Euro VI' Heavy-duty Engine using the PMP Methodologies Particle Number & Particulate Mass Emissions Measurements on a 'Euro...

  3. ULTRA LOW NOx INTEGRATED SYSTEM FOR NOx EMISSION CONTROL FROM COAL-FIRED BOILERS

    SciTech Connect (OSTI)

    Galen H. Richards; Charles Q. Maney; Richard W. Borio; Robert D. Lewis

    2002-12-30T23:59:59.000Z

    ALSTOM Power Inc.'s Power Plant Laboratories, working in concert with ALSTOM Power's Performance Projects Group, has teamed with the U.S. Department of Energy's National Energy Technology Laboratory (DOE NETL) to conduct a comprehensive study to develop/evaluate low-cost, efficient NOx control technologies for retrofit to pulverized coal fired utility boilers. The objective of this project was to develop retrofit NOx control technology to achieve less than 0.15 lb/MMBtu NOx (for bituminous coals) and 0.10 lb/MMBtu NOx (for subbituminous coals) from existing pulverized coal fired utility boilers at a cost which is at least 25% less than SCR technology. Efficient control of NOx is seen as an important, enabling step in keeping coal as a viable part of the national energy mix in this century, and beyond. Presently 57% of U.S. electrical generation is coal based, and the Energy Information Agency projects that coal will maintain a lead in U.S. power generation over all other fuel sources for decades (EIA 1998 Energy Forecast). Yet, coal-based power is being strongly challenged by society's ever-increasing desire for an improved environment and the resultant improvement in health and safety. The needs of the electric-utility industry are to improve environmental performance, while simultaneously improving overall plant economics. This means that emissions control technology is needed with very low capital and operating costs. This project has responded to the industry's need for low NOx emissions by evaluating ideas that can be adapted to present pulverized coal fired systems, be they conventional or low NOx firing systems. The TFS 2000{trademark} firing system has been the ALSTOM Power Inc. commercial offering producing the lowest NOx emission levels. In this project, the TFS 2000{trademark} firing system served as a basis for comparison to other low NOx systems evaluated and was the foundation upon which refinements were made to further improve NOx emissions and related combustion performance. Three coals were evaluated during the bench-scale and large pilot-scale testing tasks. The three coals ranged from a very reactive Powder River Basin coal (PRB) to a moderately reactive Midwestern bituminous coal (HVB) to a less reactive medium volatile Eastern bituminous coal (MVB). Bench-scale testing was comprised of standard ASTM properties evaluation, plus more detailed characterization of fuel properties through drop tube furnace testing and thermogravimetric analysis.

  4. Diesel Particulate Filter Technology for Low-Temperature and Low-NOx/PM

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't Your Destiny:Revised Finding of No53197E T A * SEnergy studiesEnergyApplications |

  5. Electrical diesel particulate filter (DPF) regeneration

    DOE Patents [OSTI]

    Gonze, Eugene V; Ament, Frank

    2013-12-31T23:59:59.000Z

    An exhaust system that processes exhaust generated by an engine includes a diesel particulate filter (DPF) that is disposed downstream of the engine and that filters particulates from the exhaust. An electrical heater is disposed upstream of the DPF and selectively heats the exhaust to initiate combustion of the particulates within the exhaust as it passes therethrough. Heat generated by combustion of the particulates induces combustion of particulates within the DPF.

  6. Microwave mode shifting antenna system for regenerating particulate filters

    DOE Patents [OSTI]

    Gonze, Eugene V [Pinckney, MI; Kirby, Kevin W [Calabasas Hills, CA; Phelps, Amanda [Malibu, CA; Gregoire, Daniel J [Thousand Oaks, CA

    2011-04-26T23:59:59.000Z

    A regeneration system comprises a particulate matter (PM) filter including a microwave energy absorbing surface, and an antenna system comprising N antennas and an antenna driver module that sequentially drives the antenna system in a plurality of transverse modes of the antenna system to heat selected portions of the microwave absorbing surface to regenerate the PM filter, where N is an integer greater than one. The transverse modes may include transverse electric (TE) and/or transverse magnetic (TM) modes.

  7. New Houston NOx Rules: Implications and Solutions

    E-Print Network [OSTI]

    Cascone, R.

    Capex $MM NOx Reduction Tons/yr Net Cost NPV10 $MM Case 1 4 50 3.6 a. Defer 1 year 4.2 loss due to delay 0.6 b. Defer 2 years 5.4 loss due to delay 1.7 c. Defer 3 years 8.5 loss due to delay 4.8 Case 2 35 750 31.8 a. Defer 1 year 42...

  8. NOx sensor development | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn'tOrigin of Contamination in Many Devils Wash, Shiprock,Departmentsensor development NOx sensor

  9. A Low-Cost Continuous Emissions Monitoring System for Mobile...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Active DPF for Off-Road Particulate Matter (PM) Control Power Generating Stationary Engines Nox Control: A Closed Loop Control Technology...

  10. Sandia National Laboratories: Carbon Management

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (SO2), nitrous oxides (NOx), mercury, and fine particulate matter. Carbon dioxide (CO2) is always a byproduct of combustion. ... Geomechanics Laboratory On April 7, 2011,...

  11. Agricultural Bio-Fueled Generation of Electricity and Development of Durable and Efficent NOx Reduction

    SciTech Connect (OSTI)

    Boyd, Rodney

    2007-08-08T23:59:59.000Z

    The objective of this project was to define the scope and cost of a technology research and development program that will demonstrate the feasibility of using an off-the-shelf, unmodified, large bore diesel powered generator in a grid-connected application, utilizing various blends of BioDiesel as fuel. Furthermore, the objective of project was to develop an emissions control device that uses a catalytic process and BioDiesel (without the presence of Ammonia or Urea)to reduce NOx and other pollutants present in a reciprocating engine exhaust stream with the goal of redefining the highest emission reduction efficiencies possible for a diesel reciprocating generator. Process: Caterpillar Power Generation adapted an off-the-shelf Diesel Generator to run on BioDiesel and various Petroleum Diesel/BioDiesel blends. EmeraChem developed and installed an exhaust gas cleanup system to reduce NOx, SOx, volatile organics, and particulates. The system design and function was optimized for emissions reduction with results in the 90-95% range;

  12. Overlap zoned electrically heated particulate filter

    DOE Patents [OSTI]

    Gonze, Eugene V [Pinckney, MI; Chapman, Mark R [Brighton, MI

    2011-07-19T23:59:59.000Z

    A system includes a particulate matter (PM) filter that includes an upstream end for receiving exhaust gas and a downstream end. A zoned heater is arranged spaced from the upstream end and comprises N zones, where N is an integer greater than one, wherein each of the N zones comprises M sub-zones, where M is an integer greater than or equal to one, and wherein the N zones and the M sub-zones are arranged in P layers, where P is an integer greater than one. A control module selectively activates at least a selected one of the N zones to initiate regeneration in downstream portions of the PM filter from the one of the N zones and deactivates non-selected ones of the N zones.

  13. Development of Advanced Diesel Particulate Filtration (DPF) Systems...

    Broader source: Energy.gov (indexed) [DOE]

    Particulate Filtration (DPF) Systems Development of Advanced Diesel Particulate Filtration (DPF) Systems (ANLCorningCaterpillar CRADA) Development of Advanced Particulate Filters...

  14. Diesel Particulate Filters: Market Introducution in Europe

    Broader source: Energy.gov (indexed) [DOE]

    km) PM (gkm) EURO 4 Vehicle NOx and PM Emissions EURO 3 EURO 4 DPF equipped Vehicles * Combustion chamber * Fuel injection system * EGR control DPF Passenger cars DEER...

  15. American Institute of Aeronautics and Astronautics A Modular State-Vector based Modeling Architecture for

    E-Print Network [OSTI]

    de Weck, Olivier L.

    . de Weck Massachusetts Institute of Technology, Cambridge, MA, 02139 Diesel emission regulations HCReg = Hydrocarbon (HC) emissions regulation limit COReg = Carbon Monoxide (CO) emissions regulation limit NOxRegs = Oxides of Nitrogen (NOx) emissions regulation limit PMReg = Particulate Matter (PM

  16. Three-Dimensional Composite Nanostructures for Lean NOx Emission...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Emission Control Catalysts Three-Dimensional Composite Nanostructures for Lean NOx Emission Control Ultra-efficient, Robust and Well-defined Nano-Array based Monolithic Catalysts...

  17. Three-Dimensional Composite Nanostructures for Lean NOx Emission...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Documents & Publications Monolithic Metal Oxide based Composite Nanowire Lean NOx Emission Control Catalysts Ultra-efficient, Robust and Well-defined Nano-Array based Monolithic...

  18. NOx Adsorbers for Heavy Duty Truck Engines - Testing and Simulation...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Adsorbers for Heavy Duty Truck Engines - Testing and Simulation NOx Adsorbers for Heavy Duty Truck Engines - Testing and Simulation This report provides the results of an...

  19. Cummins/ORNL-FEERC CRADA: NOx Control & Measurement Technology...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CumminsORNL-FEERC CRADA: NOx Control & Measurement Technology for Heavy-Duty Diesel Engines Vehicle Technologies Office Merit Review 2014: Cummins-ORNLFEERC Emissions CRADA:...

  20. Novel Application of Air Separation Membranes Reduces NOx Emissions...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    permeation of gases using an air separation membrane. Can be retrofitted to existing engines Significantly reduces NOx emissions (as much as 70%) with just a 2% nitrogen...

  1. H2-Assisted NOx Traps: Test Cell Results Vehicle Installations

    Broader source: Energy.gov (indexed) [DOE]

    Sam Crane August 28, 2003 H 2 -Assisted NOx Traps: Test Cell Results Vehicle Installations 2 Project Objectives * Determine Advantages of H 2 Assisted NO x Trap Regeneration *...

  2. Durability Evaluation of an Integrated Diesel NOx Adsorber A...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Desulfurization Fuel Filter Development of NOx Adsorber System for Dodge Ram 2007 Heavy duty Pickup Truck Update on Diesel Exhaust Emission Control Technology and Regulations...

  3. Enhanced High and Low Temperature Performance of NOx Reduction...

    Energy Savers [EERE]

    High and Low Temperature Performance of NOx Reduction Materials 2013 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer...

  4. Effect of reductive treatments on Pt behavior and NOx storage...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    represent a promising approach to meet increasingly stringent NOx emission regulations on diesel and other lean-burn engines. Pt material properties, including dispersion and...

  5. Enhanced High Temperature Performance of NOx Storage/Reduction...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Program Annual Merit Review and Peer Evaluation ace026peden2011o.pdf More Documents & Publications Enhanced High Temperature Performance of NOx StorageReduction (NSR) Materials...

  6. Enhanced High Temperature Performance of NOx Storage/Reduction...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Meeting ace026peden2012o.pdf More Documents & Publications Enhanced High Temperature Performance of NOx StorageReduction (NSR) Materials Enhanced High and Low...

  7. Dynamometer Evaluation of Plasma-Catalyst for Diesel NOx Reduction

    Broader source: Energy.gov (indexed) [DOE]

    Dynamometer Evaluation of Plasma- Catalyst for Diesel NOx Reduction February 20, 2003 CRADA Protected Document and Data 2 Introduction * Engine dynamometer evaluation of...

  8. Cummins/ORNL-FEERC CRADA: NOx Control & Measurement Technology...

    Broader source: Energy.gov (indexed) [DOE]

    Vehicle Technologies Office Merit Review 2014: Cummins-ORNLFEERC Emissions CRADA: NOx Control & Measurement Technology for Heavy-Duty Diesel Engines CumminsORNL-FEERC...

  9. Spatiotemporal Distribution of NOx Storage: a Factor Controlling...

    Broader source: Energy.gov (indexed) [DOE]

    LNT & SCR CLEERS Coordination & Joint Development of Benchmark Kinetics for LNT & SCR CumminsORNL-FEERC CRADA: NOx Control & Measurement Technology for Heavy-Duty Diesel Engines...

  10. Dynamometer Evaluation of Plasma-Catalyst for Diesel NOx Reduction...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Plasma-Catalyst for Diesel NOx Reduction 2003 DEER Conference Presentation: Ford Motor Company 2003deerhoard.pdf More Documents & Publications Plasma Assisted Catalysis...

  11. Development on simultaneous reduction system of NOx and PM from...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    system of NOx and PM from a diesel engine 2003 DEER Converence Presentation: Toyota Motor Corporation 2003deerwatanabe.pdf More Documents & Publications An Improvement of...

  12. aluminosilicates nox reduction: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the CompuNOx system focus on a controls approach to minimize emissions without exposing steam generation plants to an unbearable financial burden. With minimal system changes we...

  13. Lean NOx Reduction with Dual Layer LNT/SCR Catalysts

    Broader source: Energy.gov (indexed) [DOE]

    emerging 2 NSRSCR Technology Goal: Reduce PGM & minimize fuel penalty in meeting NOx emission targets (adapted from Gandhi et al., US Patent, 2007) 3 Fundamental Issues for Dual...

  14. Fuel Consumption and NOx Trade-offs on a Port-Fuel-Injected SI...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Consumption and NOx Trade-offs on a Port-Fuel-Injected SI Gasoline Engine Equipped with a Lean-NOx Trap Fuel Consumption and NOx Trade-offs on a Port-Fuel-Injected SI Gasoline...

  15. Combining Low-Temperature Combustion with Lean-NOx Trap Yields...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Low-Temperature Combustion with Lean-NOx Trap Yields Progress Toward Targets of Efficient NOx Control for Diesels Combining Low-Temperature Combustion with Lean-NOx Trap Yields...

  16. NOx Uptake Mechanism on Pt/BaO/Al2O3 Catalysts. | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Al2O3 Catalysts. NOx Uptake Mechanism on PtBaOAl2O3 Catalysts. Abstract: The NOx adsorption mechanism on PtBaOAl2O3 catalysts was investigated by performing NOx storage...

  17. Air Pollution Control Regulations: No. 41- Nox Budget Trading Program (Rhode Island)

    Broader source: Energy.gov [DOE]

    These regulations establish a budget trading program for nitrogen oxide emissions, setting NOx budget units for generators and an NOx Allowance Tracking System to account for emissions. These...

  18. Synergies of High-Efficiency Clean Combustion and Lean NOx Trap...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Synergies of High-Efficiency Clean Combustion and Lean NOx Trap Catalysts Synergies of High-Efficiency Clean Combustion and Lean NOx Trap Catalysts investigation of potential...

  19. Leadership in Low NOx/ Lochinvar Corporation

    E-Print Network [OSTI]

    Sheko, D.; Boston, S.; Moore, J.

    , Texas Nashville, Tennessee On April 19, 2000, the Texas Natural Resource Conservation Commission adopted statewide NOx emission limits for all natural gas-fired water heaters, boilers and process heaters with input rates of 2 million Btu/hr or less... for the purposes of generating efficient boilers, and process heaters having a BTU rating of up and environmentally friendly hot water production. to 2,000,000 BTU/hour within the state of Texas. Some readers of this paper may already be aware It's not everyday...

  20. Durability of NOx Absorbers | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't Your Destiny:Revised Finding of No53197E TDrew Bittner About Us DrewDualLight-Duty2of NOx

  1. NOx reduction by electron beam-produced nitrogen atom injection

    DOE Patents [OSTI]

    Penetrante, Bernardino M. (San Ramon, CA)

    2002-01-01T23:59:59.000Z

    Deactivated atomic nitrogen generated by an electron beam from a gas stream containing more than 99% N.sub.2 is injected at low temperatures into an engine exhaust to reduce NOx emissions. High NOx reduction efficiency is achieved with compact electron beam devices without use of a catalyst.

  2. Passive Catalytic Approach to Low Temperature NOx Emission Abatement

    Broader source: Energy.gov (indexed) [DOE]

    ISF 2.8 during FTP-75 are too high for current state of the art NOx AT to meet T2B2 emission levels * Reduction in engine out NOx emissions from 2 gmi to 0.4 gmi allows for...

  3. Preserving Diesel Exhaust Ultrafine (Nano-) Particulate Structure...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Preserving Diesel Exhaust Ultrafine (Nano-) Particulate Structure in Genotoxicity Studies to Support Engineering Development of Emission Controls Preserving Diesel Exhaust...

  4. OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL

    SciTech Connect (OSTI)

    David R. Thompson; Lawrence E. Bool; Jack C. Chen

    2003-04-01T23:59:59.000Z

    This quarterly technical progress report will summarize work accomplished for the Program through the twelfth quarter, January-March 2003, in the following task areas: Task 1--Oxygen Enhanced Combustion, Task 2--Oxygen Transport Membranes, Task 3--Economic Evaluation and Task 4--Program Management. The program is proceeding in accordance with the objectives for the third year. Pilot scale experiments conducted at the University of Utah explored both the effectiveness of oxygen addition and the best way to add oxygen with a scaled version of Riley Power's newest low NOx burner design. CFD modeling was done to compare the REI's modeling results for James River Unit 3 with the NOx and LOI results obtained during the demonstration program at that facility. Investigation of an alternative method of fabrication of PSO1d elements was conducted. OTM process development work has concluded with the completion of a long-term test of a PSO1d element Economic evaluation has confirmed the advantage of oxygen-enhanced combustion. Proposals have been submitted for two additional beta test sites. Commercial proposals have been submitted. Economic analysis of a beta site test performance was conducted.

  5. Ultra-Low NOx Advanced Vortex Combustor

    SciTech Connect (OSTI)

    Edmonds, R.G. (Ramgen Power Systems, Inc., Bellevue, WA); Steele, R.C. (Ramgen Power Systems, Inc., Bellevue, WA); Williams, J.T. (Ramgen Power Systems, Inc., Bellevue, WA); Straub, D.L.; Casleton, K.H.; Bining, Avtar (California Energy Commission, Sacramento, CA)

    2006-05-01T23:59:59.000Z

    An ultra lean-premixed Advanced Vortex Combustor (AVC) has been developed and tested. The natural gas fueled AVC was tested at the U.S. Department of Energy’s National Energy Technology Laboratory (USDOE NETL) test facility in Morgantown (WV). All testing was performed at elevated pressures and inlet temperatures and at lean fuel-air ratios representative of industrial gas turbines. The improved AVC design exhibited simultaneous NOx/CO/UHC emissions of 4/4/0 ppmv (all emissions are at 15% O2 dry). The design also achieved less than 3 ppmv NOx with combustion efficiencies in excess of 99.5%. The design demonstrated tremendous acoustic dynamic stability over a wide range of operating conditions which potentially makes this approach significantly more attractive than other lean premixed combustion approaches. In addition, a pressure drop of 1.75% was measured which is significantly lower than conventional gas turbine combustors. Potentially, this lower pressure drop characteristic of the AVC concept translates into overall gas turbine cycle efficiency improvements of up to one full percentage point. The relatively high velocities and low pressure drops achievable with this technology make the AVC approach an attractive alternative for syngas fuel applications.

  6. ULTRA-LOW NOX ADVANCED VORTEX COMBUSTOR

    SciTech Connect (OSTI)

    Ryan G. Edmonds; Robert C. Steele; Joseph T. Williams; Douglas L. Straub; Kent H. Casleton; Avtar Bining

    2006-05-01T23:59:59.000Z

    An ultra lean-premixed Advanced Vortex Combustor (AVC) has been developed and tested. The natural gas fueled AVC was tested at the U.S. Department of Energy’s National Energy Technology Laboratory (USDOE NETL) test facility in Morgantown (WV). All testing was performed at elevated pressures and inlet temperatures and at lean fuel-air ratios representative of industrial gas turbines. The improved AVC design exhibited simultaneous NOx/CO/UHC emissions of 4/4/0 ppmv (all emissions are at 15% O2 dry). The design also achieved less than 3 ppmv NOx with combustion efficiencies in excess of 99.5%. The design demonstrated tremendous acoustic dynamic stability over a wide range of operating conditions which potentially makes this approach significantly more attractive than other lean premixed combustion approaches. In addition, a pressure drop of 1.75% was measured which is significantly lower than conventional gas turbine combustors. Potentially, this lower pressure drop characteristic of the AVC concept translates into overall gas turbine cycle efficiency improvements of up to one full percentage point. The relatively high velocities and low pressure drops achievable with this technology make the AVC approach an attractive alternative for syngas fuel applications.

  7. Catalytic fabric filtration for simultaneous NO{sub x} and particulate control. Final report

    SciTech Connect (OSTI)

    Weber, G.F.; Dunham, G.E.; Laudal, D.L.; Ness, S.R.; Schelkoph, G.L.

    1994-08-01T23:59:59.000Z

    The overall objective of the project proposed was to evaluate the catalyst-coated fabric filter concept for effective control of NO{sub 2} and particulate emissions simultaneously. General goals included demonstrating high removal efficiency of NO{sub x} and particulate matter, acceptable bag and catalyst life, and that process economics show a significant cost savings in comparison to a commercial SCR process and conventional particulate control. Specific goals included the following: reduce NO{sub x} emissions to 60 ppM or less; demonstrate particulate removal efficiency of >99.5%; demonstrate a bag/catalyst life of >1 year; Control ammonia slip to <25 ppM; show that catalytic fabric filtration can achieve a 50% cost savings over conventional fabric filtration and SCR control technology; determine compatibility with S0{sub 2} removal systems; and show that the concept results in a nonhazardous waste product.

  8. COST-EFFECTIVE CONTROL OF NOx WITH INTEGRATED ULTRA LOW-NOx BURNERS AND SNCR

    SciTech Connect (OSTI)

    Hamid Farzan

    2001-07-01T23:59:59.000Z

    Coal-fired electric utilities are facing a serious challenge with regards to curbing their NO{sub x} emissions. At issue are the NO{sub x} contributions to the acid rain, ground level ozone, and particulate matter formation. Substantial NO{sub x} control requirements could be imposed under the proposed Ozone Transport Rule, National Ambient Air Quality Standards, and New Source Performance Standards. McDermott Technology, Inc. (MTI), Babcock and Wilcox (B and W), and Fuel Tech are teaming to provide an integrated solution for NO{sub x} control. The system will be comprised of an ultra low-NO{sub x} pulverized coal (PC) burner technology plus a urea-based, selective non-catalytic reduction (SNCR) system. This system will be capable of meeting a target emission limit of 0.15 lb NO{sub x}/10{sup 6} Btu and target ammonia (NH3) slip level targeted below 5 ppmV for commercial units. Our approach combines the best available combustion and post-combustion NO{sub x} control technologies. More specifically, B and W's DRB-4Z TM ultra low-NO{sub x} PC burner technology will be combined with Fuel Tech's NO{sub x}OUT (SNCR) and NO{sub x}OUT Cascade (SNCR/SCR hybrid) systems and jointly evaluated and optimized in a state-of-the-art test facility at MTI. Although the NO{sub x}OUT Cascade (SNCR/SCR hybrid) system will not be tested directly in this program, its potential application for situations that require greater NO{sub x} reductions will be inferred from other measurements (i.e., SNCR NO{sub x} removal efficiency plus projected NO{sub x} reduction by the catalyst based on controlled ammonia slip). Our analysis shows that the integrated ultra low-NO{sub x} burner and SNCR system has the lowest cost when the burner emissions are 0.25 lb NO{sub x}/10{sup 6} Btu or less. At burner NO{sub x} emission level of 0.20 lb NO{sub x}/10{sup 6} Btu, the levelized cost per ton of NO{sub x} removed is 52% lower than the SCR cost.

  9. NOx Control for Utility Boiler OTR Compliance

    SciTech Connect (OSTI)

    Hamid Farzan

    2003-12-31T23:59:59.000Z

    Under sponsorship of the Department of Energy's National Energy Technology Laboratory (NETL), the Babcock and Wilcox Company (B and W), and Fuel Tech teamed together to investigate an integrated solution for NO{sub x} control. The system is comprised of B and W's DRB-4Z{trademark} ultra low-NO{sub x} pulverized coal (PC) burner technology and Fuel Tech's NOxOUT{reg_sign}, a urea-based selective non-catalytic reduction (SNCR) technology. Development of the low-NO{sub x} burner technology has been a focus in B and W's combustion program. The DRB-4Z{trademark} burner is B and W's newest low-NO{sub x} burner capable of achieving very low NO{sub x}. The burner is designed to reduce NO{sub x} by controlled mixing of the fuel and air. Based on data from several 500 to 600 MWe boilers firing PRB coal, NOx emissions levels of 0.15 to 0.20 lb/ 106 Btu have been achieved from the DRB-4Z{trademark} burners in combination with overfire air ports. Although NOx emissions from the DRB-4Z{trademark} burner are nearing the Ozone Transport Rule (OTR) level of 0.15 lb NO{sub x}/106 Btu, the utility boiler owners can still benefit from the addition of an SNCR and/or SCR system in order to comply with the stringent NO{sub x} emission levels facing them. Large-scale testing is planned in B and W's 100-million Btu/hr Clean Environment Development Facility (CEDF) that simulates the conditions of large coal-fired utility boilers. The objective of the project is to achieve a NO{sub x} level below 0.15 lb/106 Btu (with ammonia slip of less than 5 ppm) in the CEDF using PRB coal and B and W's DRB-4Z{trademark} low-NO{sub x} pulverized coal (PC) burner in combination with dual zone overfire air ports and Fuel Tech's NO{sub x}OUT{reg_sign}. During this period B and W prepared and submitted the project management plan and hazardous substance plan to DOE. The negotiation of a subcontract for Fuel Tech has been started.

  10. Quantification of Variability and Uncertainty in Hourly NOx Emissions from Coal-Fired Power Plants

    E-Print Network [OSTI]

    Frey, H. Christopher

    to quantify variability and uncertainty for NOx emissions from coal-fired power plants. Data for hourly NOx Uncertainty, Variability, Emission Factors, Coal-Fired Power Plants, NOx emissions, Regression Models for different source categories, NOx emissions from coal-fired power plants are analyzed in this #12;2 paper

  11. OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL

    SciTech Connect (OSTI)

    David R. Thompson; Lawrence E. Bool; Jack C. Chen

    2003-08-01T23:59:59.000Z

    This quarterly technical progress report will summarize work accomplished for the Program through the thirteenth quarter, April-June 2003, in the following task areas: Task 1--Oxygen Enhanced Combustion, Task 3--Economic Evaluation and Task 4--Program Management. The program is proceeding in accordance with project objectives. REI's model was modified to evaluate mixing issues in the upper furnace of a staged unit. Analysis of the results, and their potential application to this unit is ongoing. Economic evaluation continues to confirm the advantage of oxygen-enhanced combustion. A contract for a commercial demonstration has been signed with the Northeast Generation Services Company to supply oxygen and license the oxygen enhanced low NOx combustor technology for use at the 147-megawatt coal fired Mt. Tom Station in Holyoke, MA. Commercial proposals have been submitted. Economic analysis of a beta site test performance was conducted.

  12. OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL

    SciTech Connect (OSTI)

    David R. Thompson; Lawrence E. Bool; Jack C. Chen

    2001-04-01T23:59:59.000Z

    This quarterly technical progress report will summarize work accomplished for the Program through the fourth quarter January-March 2001 in the following task areas: Task 1 - Oxygen Enhanced Combustion, Task 2 - Oxygen Transport Membranes and Task 4 - Program Management. This report will also recap the results of the past year. The program is proceeding in accordance with the objectives for the first year. OTM material characterization was completed. 100% of commercial target flux was demonstrated with OTM disks. The design and assembly of Praxair's single tube high-pressure test facility was completed. The production of oxygen with a purity of better than 99.5% was demonstrated. Coal combustion testing was conducted at the University of Arizona. Modest oxygen enhancement resulted in NOx emissions reduction. The injector for oxygen enhanced coal based reburning was conducted at Praxair. Combustion modeling with Keystone boiler was completed. Pilot-scale combustion test furnace simulations continued this quarter.

  13. Electrically heated particulate filter with zoned exhaust flow control

    DOE Patents [OSTI]

    Gonze, Eugene V [Pinckney, MI

    2012-06-26T23:59:59.000Z

    A system includes a particulate matter (PM) filter that includes X zones. An electrical heater includes Y heater segments that are associated with respective ones of the X zones. The electrical heater is arranged upstream from and proximate with the PM filter. A valve assembly includes Z sections that are associated with respective ones of the X zones. A control module adjusts flow through each of the Z sections during regeneration of the PM filter via control of the valve assembly. X, Y and Z are integers.

  14. Zoned electrical heater arranged in spaced relationship from particulate filter

    DOE Patents [OSTI]

    Gonze, Eugene V [Pinckney, MI

    2011-11-15T23:59:59.000Z

    A system comprises a particulate matter (PM) filter that comprises an upstream end for receiving exhaust gas and a downstream end. A zoned heater is arranged spaced from the upstream end and comprises N zones, where N is an integer greater than one, wherein each of the N zones comprises M sub-zones, where M is an integer greater than one. A control module selectively activates at least a selected one of the N zones to initiate regeneration in downstream portions of the PM filter from the one of the N zones and deactivates non-selected ones of the N zones.

  15. Nitrogen Isotopes as Indicators of NOx Source Contributions to

    E-Print Network [OSTI]

    Elliott, Emily M.

    of NOx are dominated by fossilfuelcombustion(63%)frombothstationary(e.g.,power plant electricity andassociatedatmosphericdepositionofnitrate(NO3 - )pose threats to global ecosystems and human health (2, 3). Contemporary global emissions

  16. Lean NOx Trap Regeneration Selectivity Towards N2O -- Similarities...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Regeneration Selectivity Towards N2O -- Similarities and Differences Between H2, CO and C3H6 Reductants Lean NOx Trap Regeneration Selectivity Towards N2O -- Similarities and...

  17. Retrofit Diesel Emissions Control System Providing 50% NOxControl

    Broader source: Energy.gov (indexed) [DOE]

    Retrofit Diesel Emissions Control System Providing 50% NOx Control D. Yee, B. Adair, A. Boleda, B. Berry, T. Caron, J. Cizeron, T. Kinney, K. Lundberg and R. Dalla Betta Catalytica...

  18. Aeroderivative Gas Turbines Can Meet Stringent NOx Control Requirements

    E-Print Network [OSTI]

    Keller, S. C.; Studniarz, J. J.

    AERODERIVATIVE GAS TURBINES CAN MEET STRINGENT NOx CONTROL REQUIREMENTS S. C. Keller, Manager Cogeneration Sales & Market Development General Electric Company Marine & Industrial Engines Cincinnati, Ohio ABSTRACT Gas Turbines operating... in the United States are required to meet federally mandated emission standards. This article will discuss how General Electric's 1M industrial aeroderivative gas turbines are meeting NOx requirements as low as 25 parts per ~tllion usi-ng steam injection...

  19. Modeling The NOx Emissions In A Low NOx Burner While Fired With Pulverized Coal And Dairy Biomass Blends 

    E-Print Network [OSTI]

    Uggini, Hari

    2012-07-16T23:59:59.000Z

    by themselves already require cleanup technology; newer regulations will require development of new and economical technologies. Using a blend of traditional fuels & biomass is a promising technology to reduce NOX emissions. Experiments conducted previously...

  20. Fluid&ParticulateSystems 424514/2010

    E-Print Network [OSTI]

    Zevenhoven, Ron

    ... 3000 kg/m³ gas = 1.2 kg/m³ at 20°C, 1 bar (air) N L L H b c 2 Eff d d d p p ( ) 1 1 50 2 d W&ParticulateSystems 424514/2010 Fluid&ParticulateSystems ÅA424514/2014 Separation efficiency )( 27.0 gaspin cgas 50pc w&ParticulateSystems ÅA424514/2014 A "standard" cyclone (Lapple) Lb Lc De Dd W H D S High Conventional High efficiency

  1. Fluid&ParticulateSystems 424514/2010

    E-Print Network [OSTI]

    Zevenhoven, Ron

    fluidr L wDdrag v½bL Lv dxbFF 331 0 . Picture: BMH99 PTG #12;Fluid&ParticulateSystems 424514/2010 Fluid/2010 Fluid&ParticulateSystems ÅA424514/2014 Basic concept wFAw A F VpVpP losscs cs loss losspumppump carlosscar wFP 212121 ,0, ppwwzz F w wFP #12;Fluid&ParticulateSystems 424514/2010 Fluid

  2. Diesel particulate filter with zoned resistive heater

    DOE Patents [OSTI]

    Gonze, Eugene V [Pinckney, MI

    2011-03-08T23:59:59.000Z

    A diesel particulate filter assembly comprises a diesel particulate filter (DPF) and a heater assembly. The DPF filters a particulate from exhaust produced by an engine. The heater assembly has a first metallic layer that is applied to the DPF, a resistive layer that is applied to the first metallic layer, and a second metallic layer that is applied to the resistive layer. The second metallic layer is etched to form a plurality of zones.

  3. Zone heated diesel particulate filter electrical connection

    DOE Patents [OSTI]

    Gonze, Eugene V. (Pinckney, MI); Paratore, Jr., Michael J. (Howell, MI)

    2010-03-30T23:59:59.000Z

    An electrical connection system for a particulate filter is provided. The system includes: a particulate filter (PF) disposed within an outer shell wherein the PF is segmented into a plurality of heating zones; an outer mat disposed between the particulate filter and the outer shell; an electrical connector coupled to the outer shell of the PF; and a plurality of printed circuit connections that extend along the outer surface of the PF from the electrical connector to the plurality of heating zones.

  4. Electrically heated particulate filter using catalyst striping

    DOE Patents [OSTI]

    Gonze, Eugene V; Paratore, Jr., Michael J; Ament, Frank

    2013-07-16T23:59:59.000Z

    An exhaust system that processes exhaust generated by an engine is provided. The system generally includes a particulate filter (PF) that filters particulates from the exhaust wherein an upstream end of the PF receives exhaust from the engine. A grid of electrically resistive material is applied to an exterior upstream surface of the PF and selectively heats exhaust passing through the grid to initiate combustion of particulates within the PF. A catalyst coating is applied to the PF that increases a temperature of the combustion of the particulates within the PF.

  5. Electrically heated particulate filter embedded heater design

    DOE Patents [OSTI]

    Gonze, Eugene V.; Chapman, Mark R.

    2014-07-01T23:59:59.000Z

    An exhaust system that processes exhaust generated by an engine is provided. The system generally includes a particulate filter (PF) that filters particulates from the exhaust wherein an upstream end of the PF receives exhaust from the engine and wherein an upstream surface of the particulate filter includes machined grooves. A grid of electrically resistive material is inserted into the machined grooves of the exterior upstream surface of the PF and selectively heats exhaust passing through the grid to initiate combustion of particulates within the PF.

  6. Diesel Particulate Filtration (DPF) Technology: Success stories...

    Broader source: Energy.gov (indexed) [DOE]

    Diesel Particulate Filtration (DPF) Technology: Success stories at the High Temperature Materials Laboratory (HTML) User Program Dr. Amit Shyam, ORNL Sponsored by U.S. Department...

  7. Particulate residue separators for harvesting devices

    SciTech Connect (OSTI)

    Hoskinson, Reed L.; Kenney, Kevin L.; Wright, Christopher T.; Hess, John R.

    2010-06-29T23:59:59.000Z

    A particulate residue separator and a method for separating a particulate residue stream may include a plenum borne by a harvesting device, and have a first, intake end and a second, exhaust end; first and second particulate residue air streams which are formed by the harvesting device and which travel, at least in part, along the plenum and in a direction of the second, exhaust end; and a baffle assembly which is located in partially occluding relation relative to the plenum, and which substantially separates the first and second particulate residue air streams.

  8. Electrically-Assisted Diesel Particulate Filter Regeneration...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Evaluation pm041lance2011p.pdf More Documents & Publications Electrically-Assisted Diesel Particulate Filter Regeneration Substrate Studies of an Electrically-Assisted Diesel...

  9. Diesel Particulate Filtration (DPF) Technology: Success stories...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Success stories at the High Temperature Materials Laboratory (HTML) User Program Diesel Particulate Filtration (DPF) Technology: Success stories at the High Temperature...

  10. Trapping efficiency depending on particulate size

    SciTech Connect (OSTI)

    Mayer, A.; Czerwinski, J.; Scheidegger, P.

    1996-09-01T23:59:59.000Z

    There is growing concern about the risk potential of Diesel particulates. This prompted two Swiss R and D projects focused on the capabilities of different soot trap concepts for filtering finest particulates. Eight different filter media, some in numerous variants, were tested on four different Diesel engines. All traps attained their gravimetric target. However, there are noticeable performance differences for finest particulates at or smaller than 50 nm. Fiber deep filters seem to be noticeably better than other filter types. If the carcinogens are mainly the finest particulates, then this criterion may become important in future trap evaluation.

  11. Methods of separating particulate residue streams

    DOE Patents [OSTI]

    Hoskinson, Reed L. (Rigby, ID); Kenney, Kevin L. (Idaho Falls, ID); Wright, Christopher T. (Idaho Falls, ID); Hess, J. Richard (Idaho Falls, ID)

    2011-04-05T23:59:59.000Z

    A particulate residue separator and a method for separating a particulate residue stream may include an air plenum borne by a harvesting device, and have a first, intake end and a second, exhaust end; first and second particulate residue air streams that are formed by the harvesting device and that travel, at least in part, along the air plenum and in a direction of the second, exhaust end; and a baffle assembly that is located in partially occluding relation relative to the air plenum and that substantially separates the first and second particulate residue air streams.

  12. Advanced Particulate Filter Technologies for Direct Injection...

    Broader source: Energy.gov (indexed) [DOE]

    Public * Continuing efforts for further CO 2 and PN reduction create a challenging environment for vehicles equipped with DI gasoline engines * Gasoline particulate filters...

  13. Alternatives to Diesel Fuel in California - Fuel Cycle Energy and Emission Effects of Possible Replacements Due to the TAC Diesel Particulate Decision

    SciTech Connect (OSTI)

    Christopher L. Saraicks; Donald M. Rote; Frank Stodolsky; James J. Eberhardt

    2000-05-01T23:59:59.000Z

    Limitations on petroleum-based diesel fuel in California could occur pursuant to the 1998 declaration by California's Air Resources Board (CARB) that the particulate matter component of diesel exhaust is a carcinogen, therefore a toxic air contaminant (TAC) subject to the state's Proposition 65. It is the declared intention of CARB not to ban or restrict diesel fuel, per se, at this time. Assuming no total ban, Argonne National Laboratory (ANL) explored two feasible ''mid-course'' strategies, each of which results in some degree of (conventional) diesel displacement. In the first case, with substantial displacement of compression ignition by spark ignition engines, diesel fuel is assumed admissible for ignition assistance as a pilot fuel in natural gas (NG)-powered heavy-duty vehicles. Gasoline demand in California increases by 32.2 million liters (8.5 million gallons) per day overall, about 21 percent above projected 2010 baseline demand. Natural gas demand increases by 13.6 million diesel liter (3.6 million gallon) equivalents per day, about 7 percent above projected (total) consumption level. In the second case, ressionignition engines utilize substitutes for petroleum-based diesel having similar ignition and performance properties. For each case we estimated localized air emission plus generalized greenhouse gas and energy changes. Fuel replacement by di-methyl ether yields the greatest overall reduction in NOx emissions, though all scenarios bring about PM10 reductions relative to the 2010 baseline, with greatest reductions from the first case described above and the least from fuel replacement by Fischer-Tropsch synthetic diesel. Economic implications of vehicle and engine replacement were not formally evaluated.

  14. Combustor for fine particulate coal

    DOE Patents [OSTI]

    Carlson, L.W.

    1988-11-08T23:59:59.000Z

    A particulate coal combustor with two combustion chambers is provided. The first combustion chamber is toroidal; air and fuel are injected, mixed, circulated and partially combusted. The air to fuel ratio is controlled to avoid production of soot or nitrogen oxides. The mixture is then moved to a second combustion chamber by injection of additional air where combustion is completed and ash removed. Temperature in the second chamber is controlled by cooling and gas mixing. The clean stream of hot gas is then delivered to a prime mover. 4 figs.

  15. Combustor for fine particulate coal

    DOE Patents [OSTI]

    Carlson, L.W.

    1988-01-26T23:59:59.000Z

    A particulate coal combustor with two combustion chambers is provided. The first combustion chamber is toroidal; air and fuel are injected, mixed, circulated and partially combusted. The air to fuel ratio is controlled to avoid production of soot or nitrogen oxides. The mixture is then moved to a second combustion chamber by injection of additional air where combustion is completed and ash removed. Temperature in the second chamber is controlled by cooling and gas mixing. The clean stream of hot gas is then delivered to a prime mover. 4 figs.

  16. Edinburgh Research Explorer Pulmonary diesel particulate increases susceptibility to

    E-Print Network [OSTI]

    Millar, Andrew J.

    Edinburgh Research Explorer Pulmonary diesel particulate increases susceptibility to myocardial, MR & Gray, GA 2014, 'Pulmonary diesel particulate increases susceptibility to myocardial ischemia. Pulmonary diesel particulate increases susceptibility to myocardial ischemia/reperfusion injury via

  17. Spatial and temporal distributions of particulate matter and particulate organic carbon, Northeast Gulf of Mexico

    E-Print Network [OSTI]

    Bernal, Christina Estefana

    2001-01-01T23:59:59.000Z

    ) that becomes trapped in the rings upon separation, and they are an important part of the heat and salt budget of the Gulf basin. Most anticyclones tend to move westward and eventually dissipate along the Gulf* s western boundary, Convective mixing transforms... as well as a significant portion of the Canadian interior. The Mississippi River plume's input of new nutrients has been identified as a potentially important factor in the high level of primary production found in the northern Gulf of Mexico (Lohrenz...

  18. Fluid&ParticulateSystems 424514/2010

    E-Print Network [OSTI]

    Zevenhoven, Ron

    .zevenhoven@abo.fi 2Fluid&ParticulateSystems 424514/2010 Fluid&ParticulateSystems ÅA424514/2014 2.1 Flow tube sections / Turku Finland RoNz 3 Fluid Flow in Tube Systems loss 2 2 1 pump 2 2 1 ppwzgppwzg outoutoutoutininininloss,311 ' 3 ppzgp 2loss,322 ' 3 ppzgp 210 VVV For a fully developed turbulent flow (horizontal

  19. Fluid&ParticulateSystems 424514/2010

    E-Print Network [OSTI]

    Zevenhoven, Ron

    cake solids mass/m2, w 3. Ruth equation using dw = (1-)solid dx fluidL p Ku solidK )1( 1 resistance, , with cake porosity : velocity, u layer thickness, L pressure drop, p dynamic viscosity, fluid Finland februari 2014 Unit w: kg/m2 Fluid&ParticulateSystems 424514/2010 Fluid&ParticulateSystems ÅA424514

  20. Non-Destructive Neutron Imaging to Analyze Particulate Filters...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Neutron Imaging to Analyze Particulate Filters Non-Destructive Neutron Imaging to Analyze Particulate Filters Non-destructive, non-invasive imaging is being employed in the...

  1. Local Soot Loading Distribution in Cordierite Diesel Particulate...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Local Soot Loading Distribution in Cordierite Diesel Particulate Filters by Dynamic Neutron Radiography Local Soot Loading Distribution in Cordierite Diesel Particulate Filters by...

  2. Emissions and Durability of Underground Mining Diesel Particulate...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Durability of Underground Mining Diesel Particulate Filter Applications Emissions and Durability of Underground Mining Diesel Particulate Filter Applications Presentation given at...

  3. Detailed Assessment of Particulate Characteristics from Low-Temperatur...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Assessment of Particulate Characteristics from Low-Temperature Combustion Engines Detailed Assessment of Particulate Characteristics from Low-Temperature Combustion Engines 2012...

  4. Durability of Diesel Engine Particulate Filters (Agreement ID...

    Broader source: Energy.gov (indexed) [DOE]

    Durability of Diesel Engine Particulate Filters (Agreement ID:10461) Durability of Diesel Engine Particulate Filters (Agreement ID:10461) 2013 DOE Hydrogen and Fuel Cells Program...

  5. Measuring PM Distribution in a Catalyzed Particulate Filter using...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    in a Catalyzed Particulate Filter using a Terahertz Wave Scanner Terahertz scanning system produced 3-dimensional image of local PM density in catatalyzed particulate...

  6. Value Analysis of Alternative Diesel Particulate Filter (DPF...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Value Analysis of Alternative Diesel Particulate Filter (DPF) Substrates for Future Diesel Aftertreatment Systems Value Analysis of Alternative Diesel Particulate Filter (DPF)...

  7. Durability of Diesel Particulate Filters - Bench Studies on Cordierite...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Particulate Filters - Bench Studies on Cordierite Filters Durability of Diesel Particulate Filters - Bench Studies on Cordierite Filters Presentation given at DEER 2006, August...

  8. Radio Frequency Diesel Particulate Filter Sensor Reduces Fuel...

    Office of Environmental Management (EM)

    Radio Frequency Diesel Particulate Filter Sensor Reduces Fuel Consumption, Wins R&D 100 Award Radio Frequency Diesel Particulate Filter Sensor Reduces Fuel Consumption, Wins R&D...

  9. New Cordierite Diesel Particulate Filters for Catalyzed and Non...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Cordierite Diesel Particulate Filters for Catalyzed and Non-Catalyzed Applications New Cordierite Diesel Particulate Filters for Catalyzed and Non-Catalyzed Applications 2003 DEER...

  10. CARB Verification of Catalyzed Diesel Particulate Filters for...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CARB Verification of Catalyzed Diesel Particulate Filters for Emergency Generator Sets CARB Verification of Catalyzed Diesel Particulate Filters for Emergency Generator Sets 2005...

  11. Ultra-Lite Diesel Particulate Filter Cartridge for Reduced Regeneratio...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Lite Diesel Particulate Filter Cartridge for Reduced Regeneration Time and Fuel Consumption Ultra-Lite Diesel Particulate Filter Cartridge for Reduced Regeneration Time and Fuel...

  12. Versatile Diesel Particulate Filter Cartridge Any Size, Any Shape...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Versatile Diesel Particulate Filter Cartridge Any Size, Any Shape Versatile Diesel Particulate Filter Cartridge Any Size, Any Shape Presentation given at DEER 2006, August 20-24,...

  13. Development of Acicular Mullite Materials for Diesel Particulate...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    for Multifunctional Diesel Particulate Filters Future Trends for DPFSCR On-Filter (SCRF) fundamental Modeling and Experimental Studies of Acicular Mullite Diesel Particulate...

  14. Development of Advanced Diesel Particulate Filtration (DPF) Systems...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Filters Development of Advanced Diesel Particulate Filtration (DPF) Systems Development of Advanced Diesel Particulate Filtration (DPF) Systems (ANLCorningCaterpillar CRADA)...

  15. Development of Advanced Diesel Particulate Filtration (DPF) Systems...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Advanced Diesel Particulate Filtration (DPF) Systems (ANLCorningCaterpillar CRADA) Development of Advanced Diesel Particulate Filtration (DPF) Systems Development of...

  16. Characterization of Particulate Emissions from GDI Engine Combustion...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Particulate Emissions from GDI Engine Combustion with Alcohol-blended Fuels Characterization of Particulate Emissions from GDI Engine Combustion with Alcohol-blended Fuels Analysis...

  17. Requirements-Driven Diesel Catalyzed Particulate Trap Design...

    Broader source: Energy.gov (indexed) [DOE]

    Requirements-Driven Diesel Catalyzed Particulate Trap Design and Optimization Requirements-Driven Diesel Catalyzed Particulate Trap Design and Optimization 2005 Diesel Engine...

  18. Single Wall Diesel Particulate Filter (DPF) Filtration Efficiency...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Single Wall Diesel Particulate Filter (DPF) Filtration Efficiency Studies Using Laboratory Generated Particles. Single Wall Diesel Particulate Filter (DPF) Filtration Efficiency...

  19. Assessing Exposures to Particulate Matter and Manganese in Welding Fumes

    E-Print Network [OSTI]

    LIU, SA

    2010-01-01T23:59:59.000Z

    Ventilation                 Natural                 Mechanical                 Local on Cancer LEV: local-exhaust ventilation LOD: limit of42% lower with local exhaust ventilation, was higher among

  20. Fuel-Neutral Studies of Particulate Matter Transport Emissions

    Broader source: Energy.gov (indexed) [DOE]

    varied with operating conditions 10 SIDI ULSD Root Form factor Type Root Form factor Fractal Dimension ULSD 0.62 2.39 SIDI 0.29 1.86 Technical Accomplishments Engine Parameter...

  1. Fuel-Neutral Studies of Particulate Matter Transport Emissions

    Broader source: Energy.gov (indexed) [DOE]

    II 7 Shape (dynamic shape factor, asphericity, asymmetry) Hygroscopicity Fractal dimension High detection efficiency - 50% @ d85nm, 100% @ d125 nm High...

  2. Fuel-Neutral Studies of Particulate Matter Transport Emissions

    Broader source: Energy.gov [DOE]

    2013 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting

  3. Fuel-Neutral Studies of Particulate Matter Transport Emissions

    Broader source: Energy.gov (indexed) [DOE]

    Narrow size distribution for HL runs along with large mobility sizes suggests fractal shape Broader distribution for LL runs along with smaller mobility sizes suggests...

  4. Abatement of Air Pollution: Control of Particulate Matter and...

    Broader source: Energy.gov (indexed) [DOE]

    Savings Category Fuel Cells Photovoltaics Program Info State Connecticut Program Type Environmental Regulations Provider Department of Energy and Environmental Protection These...

  5. Development of a Low-Cost Particulate Matter Monitor

    E-Print Network [OSTI]

    White, Richard M.

    2010-01-01T23:59:59.000Z

    and air mover ii. Thermophoretic deposition module iii.Figure 6. Microfabricated thermophoretic heaters and theirand characteristics of thermophoretic deposition Figure 6.

  6. Fuel-Neutral Studies of Particulate Matter Transport Emissions...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting ace056stewart2012o.pdf More Documents & Publications...

  7. Assessing Exposures to Particulate Matter and Manganese in Welding Fumes

    E-Print Network [OSTI]

    LIU, SA

    2010-01-01T23:59:59.000Z

    465.   Sapp ME.  A History of Welding: from Hepheastus to whistoryfolder/welding/index.html.   Saric M, Markicevic, be retrieved from American Welding Society publications. The

  8. Assessing Exposures to Particulate Matter and Manganese in Welding Fumes

    E-Print Network [OSTI]

    LIU, SA

    2010-01-01T23:59:59.000Z

    less hazardous compared to MIG welding, these areas as wellareas where high concentrations occurred; 3) although resistance welding is considered less hazardoushazardous welding operations such as resistance welding should also be effectively controlled. Those who work in areas

  9. Concentrations and Size Distributions of Particulate Matter Emissions...

    Broader source: Energy.gov (indexed) [DOE]

    ECD-1 CRT CNG1 CNG2 Carbonyl Compounds (Air Toxics) Formaldehyde Acetaldehyde Acetone Acrolein Propionaldehyde Croton Methyl ethyl Ketone (MEK) Methylacrolein Butanal Benzaldehyde...

  10. Assessing Exposures to Particulate Matter and Manganese in Welding Fumes

    E-Print Network [OSTI]

    LIU, SA

    2010-01-01T23:59:59.000Z

    titanium and zinc; non-metal constituents such as fluorides and silica; and gases such as carbon monoxide and carbon dioxide, nitrogen

  11. Occupational Medicine Implications of Engineered Nanoscale Particulate Matter

    E-Print Network [OSTI]

    Kelly, Richard J.

    2008-01-01T23:59:59.000Z

    Titanium Ytterbium Zirconium Animony Boron Carbon Cobalt Erbium Gallium Hafnium Iridium Lead Magnesium Neodymium Nitrogen

  12. acidic particulate matter: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    methods. The observed secondary OM in urban plumes may account and absorption of solar radiation, and indirectly by providing the condensation nuclei for cloud droplets 167...

  13. Occupational Medicine Implications of Engineered Nanoscale Particulate Matter

    E-Print Network [OSTI]

    Kelly, Richard J.

    2008-01-01T23:59:59.000Z

    Ed. ) American Industrial Hygiene Association: 2008.occupational medicine and industrial hygiene is hampered byThe vast majority of industrial hygiene exposure limits for

  14. Development of a Low-Cost Particulate Matter Monitor

    E-Print Network [OSTI]

    White, Richard M.

    2010-01-01T23:59:59.000Z

    air quality and improving industrial hygiene. The PM monitorquality and improving industrial hygiene. Compact particleinstruments for industrial hygiene applications. References

  15. Assessing Exposures to Particulate Matter and Manganese in Welding Fumes

    E-Print Network [OSTI]

    LIU, SA

    2010-01-01T23:59:59.000Z

    helmets.   American Industrial Hygiene Association Journal welding.   American Industrial Hygiene Association Journal electrodes.  American  Industrial Hygiene Association 

  16. Particulate Matter Sampling and Volatile Organic Compound Removal...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    being proposed to mitigate adverse human health and environmental impacts of internal combustion engines. With that in mind, it has been proposed that vehicular...

  17. Comments on the Criteria Document for Particulate Matter Air Pollution

    E-Print Network [OSTI]

    Washington at Seattle, University of

    and the American Statistical Association Section on Statistics and the Environment, written by Richard Smith individuals. The document, however, fails to take into account much of the recent statistical literature. For example, a special issue of Environmetrics (vol. 11, issue 6, 2000) on statistical analysis of PM data

  18. Analysis and Prediction of Particulate Matter in Graz

    E-Print Network [OSTI]

    Stadlober, Ernst

    15 · bronchitis · chronic cough 1.3 EU Directive The threshold value for the daily average in the EU

  19. Effects of Advanced Combustion Technologies on Particulate Matter...

    Broader source: Energy.gov (indexed) [DOE]

    Selective capture of semi-volatiles (C10-C18) GCMS speciation Engine: 4 cylinder 1.7L turbo DI Exhaust 6 Managed by UT-Battelle for the Department of Energy Pre-mixed Charge...

  20. atmospheric particulate matters: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    October 28, 1980. The purposes of this meeting were: to synthesize our knowledge of the Norton Sound Lease Area (Sale No. 57) in order to facilitate the preparation of BLM's...

  1. atmospheric particulate matter: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    October 28, 1980. The purposes of this meeting were: to synthesize our knowledge of the Norton Sound Lease Area (Sale No. 57) in order to facilitate the preparation of BLM's...

  2. Development of a Low-Cost Particulate Matter Monitor

    E-Print Network [OSTI]

    White, Richard M.

    2010-01-01T23:59:59.000Z

    response to fresh diesel exhaust Generation of dieselduring and after generation of ETS and diesel exhaust inof PM generation of cigarette smoke and diesel exhaust

  3. Occupational Medicine Implications of Engineered Nanoscale Particulate Matter

    E-Print Network [OSTI]

    Kelly, Richard J.

    2008-01-01T23:59:59.000Z

    New England Journal of Medicine 1993, 329, 7. S. v. Klot; A.34 of 42 Occupational Medicine Implications of Engineered35 of 42 Occupational Medicine Implications of Engineered

  4. Fuel-Neutral Studies of Particulate Matter Transport Emissions | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't YourTransport inEnergy0.pdfTechnologies ProgramOutfitted with SCR |Altering Exhaustof

  5. Fuel-Neutral Studies of Particulate Matter Transport Emissions | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't YourTransport inEnergy0.pdfTechnologies ProgramOutfitted with SCR |Altering Exhaustofof

  6. Investigation of Direct Injection Vehicle Particulate Matter Emissions |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't YourTransport(FactDepartment ofLetter Report: I11IG002 Investigation Letter2009Department of

  7. Particulate Matter Characteristics for Highly Dilute Stoichiometric GDI

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn'tOrigin of Contamination in235-1 Termoelectrica U.SPRESSHeavy-duty Engine using theEngine

  8. Concentrations and Size Distributions of Particulate Matter Emissions from

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't Your Destiny: Theof"Wave the WhiteNational|ofSeptember 3,Bringing youProgram AreasCatalyzed

  9. Development and Demonstration of an Electronic Particulate Matter Sensor

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't Your Destiny:Revised Finding of No53197E T A * S H I E LGeothermalEnergyProgram)for Both

  10. Effects of Advanced Combustion Technologies on Particulate Matter Emissions

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't Your Destiny:RevisedAdvisory Board ContributionsreductionRefineries | DepartmentStates:

  11. Accelerated Extraction of Diesel Particulate Matter SOF | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't Your Destiny: The Future of1 AAccelerated aging of roofing surfaces Hugo Destaillats,

  12. Optical Backscatter Probe for Sensing Particulate Matter - Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What's Possible for RenewableSpeeding accessSpeedingOctoberResearchOpen→and Technology,Optical

  13. Reduction of Transient Particulate Matter Spikes with Decision Tree Based

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn'tOrigin of ContaminationHubs+18, 2012Energy ReliabilityNewsEnergy VehicleofIndustry Does

  14. The Effects of Hydrocarbons on NOx Reduction over Fe-based SCR...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydrocarbons on NOx Reduction over Fe-based SCR Catalyst The Effects of Hydrocarbons on NOx Reduction over Fe-based SCR Catalyst Study of effects of hydrocarbons on ammonia storage...

  15. Climate impact of aviation NOx? emissions : radiative forcing, temperature, and temporal heterogeneity

    E-Print Network [OSTI]

    Wong, Lawrence Man Kit

    2014-01-01T23:59:59.000Z

    Aviation NOx emissions are byproducts of combustion in the presence of molecular nitrogen. In the upper troposphere, NOx emissions result in the formation of O? but also reduce the lifetime of CH4 , causing an indirect ...

  16. Safe and compact ammonia storage/delivery systems for SCR-DeNOX...

    Energy Savers [EERE]

    Safe and compact ammonia storagedelivery systems for SCR-DeNOX in automotive units Safe and compact ammonia storagedelivery systems for SCR-DeNOX in automotive units Presentation...

  17. Combining Biodiesel and EGR for Low-Temperature NOx and PM Reductions...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Biodiesel and EGR for Low-Temperature NOx and PM Reductions Combining Biodiesel and EGR for Low-Temperature NOx and PM Reductions Poster presentation at the 2007 Diesel...

  18. Development of a Stand-Alone Urea-SCR System for NOx Reduction...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    a Stand-Alone Urea-SCR System for NOx Reduction in Marine Diesel Engines Development of a Stand-Alone Urea-SCR System for NOx Reduction in Marine Diesel Engines Stand-alone urea...

  19. Effect of Engine-Out NOx Control Strategies on PM Size Distribution...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Engine-Out NOx Control Strategies on PM Size Distribution in Heavy-Duty Diesel Engines Developed for 2010 Effect of Engine-Out NOx Control Strategies on PM Size Distribution in...

  20. A Cost-Effectiveness Analysis of Alternative Ozone Control Strategies: Flexible Nitrogen Oxide (NOx) Abatement

    E-Print Network [OSTI]

    and Policy at the Massachusetts Institute of Technology June 2009 ©2009 Massachusetts Institute of Technology differentiated regulation for NOx emissions. Such a flexible NOx regulation policy, so-called "smart trading

  1. Industry-Utility Collaborative Efforts to Address Environmental Concerns- Dispatching for Localized NOx Reduction

    E-Print Network [OSTI]

    Hamilton, D. E.; Helmick, R. W.; Lambert, W. J.

    these objectives. The approach involves dispatching NOx-producing equipment (e.g., boilers and gas turbines) to achieve minimum NOx production during ozone alert periods and purchasing supplemental power under a special tariff to replace any loss in self...

  2. Thermal Durability of Cu-CHA NH3-SCR Catalysts for Diesel NOx...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Durability of Cu-CHA NH3-SCR Catalysts for Diesel NOx Reduction. Thermal Durability of Cu-CHA NH3-SCR Catalysts for Diesel NOx Reduction. Abstract: Multiple catalytic functions...

  3. Water-induced morphology changes in BaO/?-Al2O3 NOx storage...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    materials. Water-induced morphology changes in BaO?-Al2O3 NOx storage materials. Abstract: Exposure of NO2-saturated BaO?-Al2O3 NOx storage materials to H2O vapour...

  4. Sizes, graphitic structures and fractal geometry of light-duty diesel engine particulates.

    SciTech Connect (OSTI)

    Lee, K. O.; Zhu, J.; Ciatti, S.; Choi, M. Y.; Energy Systems; Drexel Univ.

    2003-01-01T23:59:59.000Z

    The particulate matter of a light-duty diesel engine was characterized in its morphology, sizes, internal microstructures, and fractal geometry. A thermophoretic sampling system was employed to collect particulates directly from the exhaust manifold of a 1.7-liter turbocharged common-rail direct-injection diesel engine. The particulate samples collected at various engine-operating conditions were then analyzed by using a high-resolution transmission electron microscope (TEM) and an image processing/data acquisition system. Results showed that mean primary particle diameters (dp), and radii of gyration (Rg), ranged from 19.4 nm to 32.5 nm and 77.4 nm to 134.1 nm, respectively, through the entire engine-operating conditions of 675 rpm (idling) to 4000 rpm and 0% to 100% loads. It was also revealed that the other important parameters sensitive to the particulate formation, such as exhaust-gas recirculation (EGR) rate, equivalence ratio, and temperature, affected particle sizes significantly. Bigger primary particles were measured at higher EGR rates, higher equivalence ratios (fuel-rich), and lower exhaust temperatures. Fractal dimensions (D{sup f}) were measured at a range of 1.5 - 1.7, which are smaller than those measured for heavy-duty direct-injection diesel engine particulates in our previous study. This finding implies that the light-duty diesel engine used in this study produces more stretched chain-like shape particles, while the heavy-duty diesel engine emits more spherical particles. The microstructures of diesel particulates were observed at high TEM magnifications and further analyzed by a Raman spectroscope. Raman spectra revealed an atomic structure of the particulates produced at high engine loads, which is similar to that of typical graphite.

  5. Reduction of NOx by plasma-assisted methods , F. Leipold1

    E-Print Network [OSTI]

    acid rain and ozone production when it is released into the air. Reduction of NOx in the exhaust gas

  6. Development of diesel particulate filter made of porous metal

    SciTech Connect (OSTI)

    Matsunuma, Kenji; Ihara, Tomohiko; Hanamoto, Yuichi; Nakajima, Shiro; Okamoto, Satoru

    1996-09-01T23:59:59.000Z

    Pollution is worsening in cities. The exhaust gas from vehicles is the main cause of air pollution in cities. The major drawback of the diesel engine is the Particulate Matter (PM) contained in the exhaust fumes which is also said to lead to cancer. For about 20 years many tests have been conducted in order to reduce PM in diesel exhaust gas. However the exhaust gas in present diesel engines contains a significant amount of PM. This is because there is no practical material for the Diesel Particulate Filter (DPF). Conventional ceramic materials have problems such as cracking and melting during regeneration and conventional metal materials lack adequate corrosion resistance for practical use. The authors present a new type of DPF made of metal porous matter (Celmet) which is designed with a thermal construction and simple control system in order to solve the problem of diesel exhaust gas. As metal porous matter has low pressure loss per unit filter area during filtering, two-cylinder filters have similar trapping performance to the honeycomb type filter such as pressure loss and trapping efficiency, In this paper, 2,800--3,400cc diesel engines were used. Then a cycle of collection and regeneration with an electric heater and 12V battery was performed under several conditions on the engine bench and trapping efficiency and pressure loss were measured. It was confirmed that this new type DPF has good practical use in automobiles. Tests on forklifts were also performed. In a simple control system, this DPF can be applied to practical use. It is trouble-free for 6 months. The total performance of DPF for vehicles such as forklifts and heavy duty vehicles and the possibilities for other practical uses was mainly discussed.

  7. Characteristics of Pt-K/MgAl2O4 lean NOx trap catalysts. | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Pt-KMgAl2O4 lean NOx trap catalysts. Characteristics of Pt-KMgAl2O4 lean NOx trap catalysts. Abstract: We report the various characteristics of Pt-KMgAl2O4 lean NOx trap (LNT)...

  8. Influence of combustion parameters on NOx production in an industrial boiler

    E-Print Network [OSTI]

    Aldajani, Mansour A.

    Influence of combustion parameters on NOx production in an industrial boiler M.A. Habib a,*, M; accepted 14 April 2007 Available online 24 June 2007 Abstract NOx formation during the combustion process occurs mainly through the oxidation of nitrogen in the combustion air (thermal NOx) and through oxidation

  9. Asian emissions of CO and NOx: Constraints from aircraft and Chinese station data

    E-Print Network [OSTI]

    Palmer, Paul

    Asian emissions of CO and NOx: Constraints from aircraft and Chinese station data Yuxuan X. Wang to constrain estimates of Asian emissions of CO and NOx. A priori emissions are based on a detailed bottom emissions of CO and NOx, respectively, distributed heterogeneously, with the largest adjustments required

  10. Electrically heated particulate filter enhanced ignition strategy

    SciTech Connect (OSTI)

    Gonze, Eugene V; Paratore, Jr., Michael J

    2012-10-23T23:59:59.000Z

    An exhaust system that processes exhaust generated by an engine is provided. The system generally includes a particulate filter (PF) that filters particulates from the exhaust wherein an upstream end of the PF receives exhaust from the engine. A grid of electrically resistive material is applied to an exterior upstream surface of the PF and selectively heats exhaust passing through the grid to initiate combustion of particulates within the PF. A catalyst coating applied to at least one of the PF and the grid. A control module estimates a temperature of the grid and controls the engine to produce a desired exhaust product to increase the temperature of the grid.

  11. Gaseous and particulate emissions from a DC arc melter

    SciTech Connect (OSTI)

    Overcamp, T.J.; Speer, M.P.; Griner, S.J.; Cash, D.M. [Clemson Univ., Anderson, SC (United States)

    1997-12-31T23:59:59.000Z

    This paper presents the results of the gaseous and particulate emissions from eight experimental tests of a DC arc melter to treat simulated Savannah River soils contaminated with metals, surrogates for radionuclides, and organic debris. The gaseous analyses reported on the concentrations of oxygen, hydrogen, carbon monoxide, carbon dioxide, hydrogen, methane, nitric oxide, and nitrogen dioxide. The carbon dioxide concentration was high for all runs. For the runs with an air purge, the carbon monoxide concentration ranged up to 10% in the runs with the debris and 2% in the runs without debris. Hydrogen ranged up to 5% by with debris and up to 1% without debris. The methane concentration ranged up to 7,000 ppm{sub v} for the runs with debris and 2,000 ppm for the runs without debris. With a nitrogen purge, oxygen concentrations were less than 1%. The carbon dioxide concentrations ranged from 3 to 15%. Much of this carbon dioxide was probably due the carbonates added to the feed material. The carbon monoxide concentration ranged up to 20% with the debris and 7% without debris. Hydrogen was above 6% in with debris and up to 6% without debris. The methane concentration ranged up to 10,000 ppm{sub v} with debris and 4,000 ppm{sub v} without debris. The particulate concentrations exiting ranged from 32 to 145 g/m{sup 3}. From the chemical analyses, the primary elements were silicon and calcium. The CHN analyses indicated that carbon, probably as carbonates, are an additional component in the particulate matter. The estimated emissions were at a level of 3% or less for cerium, up to 7% for nickel, and 11 to 30% for cesium.

  12. An improved visualization of diesel particulate filter/

    E-Print Network [OSTI]

    Boehm, Kevin (Kevin W.)

    2011-01-01T23:59:59.000Z

    The prevalence of diesel particulate filters (DPF) is increasing as emissions standards worldwide evolve to match current technologies. Since the first application of DPFs in the 1980's, PM trapping effectiveness has ...

  13. Durability of Diesel Engine Particulate Filters

    Broader source: Energy.gov (indexed) [DOE]

    Durability of Diesel Engine Particulate Filters Thomas Watkins, Amit Shyam, H.T. Lin, Edgar Lara-Curzio and Amit Pandey; ORNL Randall Stafford; Cummins Inc. Sponsored by U.S....

  14. Fluid&ParticulateSystems 424514/2010

    E-Print Network [OSTI]

    Zevenhoven, Ron

    size distribution (CSD) and quality #12;Fluid&ParticulateSystems 424514/2010 Fluid solution ­ Selective distribution of impurities between a liquid phase and a solid phase uniformity, purity

  15. NOx, SOx & CO{sub 2} mitigation using blended coals

    SciTech Connect (OSTI)

    Labbe, D.

    2009-11-15T23:59:59.000Z

    Estimates of potential CO{sub 2} reduction achievable through the use of a mixture of bituminous and subbituminous (PRB) coals, whilst attaining NOx and SOx compliance are presented. The optimization considerations to provide satisfactory furnace, boiler and unit performance with blended coal supplies to make such operation feasible are discussed. 6 refs., 7 figs., 1 tab.

  16. Electrochemical NOx Sensor for Monitoring Diesel Emissions

    SciTech Connect (OSTI)

    Woo, L Y; Glass, R S

    2008-11-14T23:59:59.000Z

    Increasingly stringent emissions regulations will require the development of advanced gas sensors for a variety of applications. For example, compact, inexpensive sensors are needed for detection of regulated pollutants, including hydrocarbons (HCs), CO, and NO{sub x}, in automotive exhaust. Of particular importance will be a sensor for NO{sub x} to ensure the proper operation of the catalyst system in the next generation of diesel (CIDI) automobiles. Because many emerging applications, particularly monitoring of automotive exhaust, involve operation in harsh, high-temperature environments, robust ceramic-oxide-based electrochemical sensors are a promising technology. Sensors using yttria-stabilized zirconia (YSZ) as an oxygen-ion-conducting electrolyte have been widely reported for both amperometric and potentiometric modes of operation. These include the well-known exhaust gas oxygen (EGO) sensor. More recently, ac impedance-based (i.e., impedance-metric) sensing techniques using YSZ have been reported for sensing water vapor, hydrocarbons, CO, and NO{sub x}. Typically small-amplitude alternating signal is applied, and the sensor response is measured at a specified frequency. Most impedance-metric techniques have used the modulus (or magnitude) at low frequencies (< 1 Hz) as the sensing signal and attribute the measured response to interfacial phenomena. Work by our group has also investigated using phase angle as the sensing signal at somewhat higher frequencies (10 Hz). The higher frequency measurements would potentially allow for reduced sampling times during sensor operation. Another potential advantage of impedance-metric NO{sub x} sensing is the similarity in response to NO and NO{sub 2} (i.e., total-NO{sub x} sensing). Potentiometric NO{sub x} sensors typically show higher sensitivity to NO2 than NO, and responses that are opposite in sign. However, NO is more stable than NO{sub 2} at temperatures > 600 C, and thermodynamic calculations predict {approx}90% NO, balance NO{sub 2}. Since automotive exhaust sensors will probably be required to operate at temperatures > 600 C, NO is the dominant component in thermodynamic equilibrium and the target NOx species. Also, the use of upstream catalysts could further promote the conversion of NO{sub x} species to NO. Therefore, the focus of current work is to investigate the response to NO. Nevertheless, minimizing the sensitivity to a variety of competing species is important in order to obtain the accuracy necessary for achieving the emission limits. Mitigating the effect of interfering gases (e.g., O{sub 2}, water vapor, HCs, etc.) is an area of current study. For impedance metric NO{sub x} sensors, our previous work has demonstrated that the cross-sensitivity to O{sub 2} may be accounted for by comparing measurements at multiple frequencies. Other strategies for compensation are also being explored, including calibration using data from existing sensors located nearby. Our current work has made significant advances in terms of developing prototype sensors more suitable for commercialization. Also, dynamometer testing has provided real-world sensor performance data that will be useful in approaching potential suppliers to whom we can transfer the technology for commercialization. The advances are a direct result of understanding the sensing mechanisms responsible for impedance-based NO{sub x} sensing and the effect of materials choice and sensor design/geometry.

  17. Lanthanides as particulate flow markers in ruminants

    E-Print Network [OSTI]

    Conner, Michael Cronan

    1977-01-01T23:59:59.000Z

    Suhj ect: Anindl I'lutri tion LANTHANIDES AS PARTICULATE FLOW NARVERS IN RUNINANTS A Thesis by MICUAEL CRONAN CONNER Approved as to style and content by: Yie, aber+ (Yieniber) August l977 ABSTPACT Lanthanides as Particulate Flow Markers... in Ruminants (Auoust 1977) Michael Cronan Conner, B. S. , California Polytechnic State University at San Luis Gbispo Chairman of Advisory Committee: Gr. Ii. C, Ellis The validity of lanthanides as par+iculate flow markers was evaluated by comparing...

  18. Alumina catalysts for reduction of NOx from methanol fueled diesel engine

    SciTech Connect (OSTI)

    Yamamoto, Toshiro; Noda, Akira; Sakamoto, Takashi; Sato, Yoshio [Ministry of Transport of Japan, Kumamoto (Japan)

    1996-09-01T23:59:59.000Z

    NOx selective reducing catalysts are expected to be used for lean-burn gasoline engines and diesel engines as an effective NOx reduction measure. The authors are interested in the combination of methanol, as a reducing agent, and alumina catalyst, and have considered the NOx reduction method using effectively much unburned methanol. In this report, in order to investigate the effect of NOx reduction by the alumina catalyst, the experiment was carried out by feeding the actual exhaust gas from the methanol engine into the alumina catalyst. As a result, it was confirmed that, without addition of any other reducing agents into the exhaust gas, the alumina catalyst has activity to reduce NOx.

  19. Catalytic Combustion for Ultra-Low NOx Hydrogen Turbines

    SciTech Connect (OSTI)

    Etemad, Shahrokh; Baird, Benjamin; Alavandi, Sandeep

    2011-06-30T23:59:59.000Z

    Precision Combustion, Inc., (PCI) in close collaboration with Solar Turbines, Incorporated, has developed and demonstrated a combustion system for hydrogen fueled turbines that reduces NOx to low single digit level while maintaining or improving current levels of efficiency and eliminating emissions of carbon dioxide. Full scale Rich Catalytic Hydrogen (RCH1) injector was developed and successfully tested at Solar Turbines, Incorporated high pressure test facility demonstrating low single digit NOx emissions for hydrogen fuel in the range of 2200F-2750F. This development work was based on initial subscale development for faster turnaround and reduced cost. Subscale testing provided promising results for 42% and 52% H2 with NOx emissions of less than 2 ppm with improved flame stability. In addition, catalytic reactor element testing for substrate oxidation, thermal cyclic injector testing to simulate start-stop operation in a gas turbine environment, and steady state 15 atm. operation testing were performed successfully. The testing demonstrated stable and robust catalytic element component life for gas turbine conditions. The benefit of the catalytic hydrogen combustor technology includes capability of delivering near-zero NOx without costly post-combustion controls and without requirement for added sulfur control. In addition, reduced acoustics increase gas turbine component life. These advantages advances Department of Energy (DOE’s) objectives for achievement of low single digit NOx emissions, improvement in efficiency vs. postcombustion controls, fuel flexibility, a significant net reduction in Integrated Gasification Combined Cycle (IGCC) system net capital and operating costs, and a route to commercialization across the power generation field from micro turbines to industrial and utility turbines.

  20. SOUTHERN FINE PARTICULATE MONITORING PROJECT

    SciTech Connect (OSTI)

    Unknown

    2002-04-01T23:59:59.000Z

    This quarterly report presents results and analysis of continuous onsite ambient fine particulate data at the North Birmingham sampling site during the January-March, 2002 study period. The continuous data include PM{sub 2.5} mass concentrations measured by TEOM, particle sulfate using the R&P 8400S monitor, particle size distributions measured by SMPS and APS monitors, and PM{sub 2.5} light scattering extinction coefficient as measured by nephelometer. Some instrumental issues were noted with the upgrade of the APS model 3320 are described in the report, as well as preliminary performance indications for the upgraded instrument. During the quarter preliminary data analysis and modeling studies were conducted to test the potential of the North Birmingham site data for source attribution analyses. Our initial assessment has continued to be optimistic in this regard due to the location of the site relative to several important classes of local and midrange emission sources. We anticipate that these analyses will provide good separations of the effects of major source classes and spatial source clusters, and will provide useful information relevant to PM{sub 2.5} implementation strategies.

  1. Integrated exhaust and electrically heated particulate filter regeneration systems

    DOE Patents [OSTI]

    Gonze, Eugene V.; Paratore, Jr., Michael J.

    2013-01-08T23:59:59.000Z

    A system includes a particulate matter (PM) filter that includes multiple zones. An electrical heater includes heater segments that are associated with respective ones of the zones. The electrical heater is arranged upstream from and proximate with the PM filter. A post-fuel injection system injects fuel into at least one of a cylinder of an engine and an exhaust system. A control module is configured to operate in a first mode that includes activating the electrical heater to heat exhaust of the engine. The control module is also configured to operate in a second mode that includes activating the post-injection system to heat the exhaust. The control module selectively operates in at least one of the first mode and the second mode.

  2. A new closing method for wall flow diesel particulate filters

    SciTech Connect (OSTI)

    Stobbe, P.; Petersen, H.G.; Sorenson, S.C.; Hoej, J.W.

    1996-09-01T23:59:59.000Z

    A new method has been developed to close the ends of a wall flow filter used for removing particulate matter from diesel engine exhaust. In this method, the ends of the honeycomb structure are capped by deforming and closing the ends of the channel walls between the extrusion and firing stages of production. The method increases the amount of filtration area per filter volume for a given cell geometry compared to the traditional plugging method, since the entire length of the honeycomb channels is used for filtration purposes. In addition, use of the capping method has a beneficial effect on the pressure loss characteristics of a filter with a given filtration area. These benefits are illustrated through experimental results.

  3. LOW NOx EMISSIONS IN A FUEL FLEXIBLE GAS TURBINE

    SciTech Connect (OSTI)

    Raymond Drnevich; James Meagher; Vasilis Papavassiliou; Troy Raybold; Peter Stuttaford; Leonard Switzer; Lee Rosen

    2004-08-01T23:59:59.000Z

    In alignment with Vision 21 goals, a study is presented here on the technical and economic potential for developing a gas turbine combustor that is capable of generating less that 2 ppm NOx emissions, firing on either coal synthesis gas or natural gas, and being implemented on new and existing systems. The proposed solution involves controlling the quantity of H2 contained in the fuel. The presence of H2 leads to increased flame stability such that the combustor can be operated at lower temperatures and produce less thermal NOx. Coal gas composition would be modified using a water gas shift converter, and natural gas units would implement a catalytic partial oxidation (CPOX) reactor to convert part of the natural gas feed to a syngas before fed back into the combustor. While both systems demonstrated technical merit, the economics involved in implementing such a system are marginal at best. Therefore, Praxair has decided not to pursue the technology any further at this time.

  4. Small, Inexpensive Combined NOx Sensor and O2 Sensor

    SciTech Connect (OSTI)

    W. N. Lawless; C. F. Clark, Jr.

    2008-09-08T23:59:59.000Z

    It has been successfully demonstrated in this program that a zirconia multilayer structure with rhodium-based porous electrodes performs well as an amperometric NOx sensor. The sensitivity of the sensor bodies operating at 650 to 700 C is large, with demonstrated current outputs of 14 mA at 500 ppm NOx from sensors with 30 layers. The sensor bodies are small (4.5 x 4.2 x 3.1 mm), rugged, and inexpensive. It is projected the sensor bodies will cost $5 - $10 in production. This program has built on another successful development program for an oxygen sensor based on the same principles and sponsored by DOE. This oxygen sensor is not sensitive to NOx. A significant technical hurdle has been identified and solved. It was found that the 100% Rh electrodes oxidize rapidly at the preferred operating temperatures of 650 - 700 C, and this oxidation is accompanied by a volume change which delaminates the sensors. The problem was solved by using alloys of Rh and Pt. It was found that a 10%/90% Rh/Pt alloy dropped the oxidation rate of the electrodes by orders of magnitude without degrading the NOx sensitivity of the sensors, allowing long-term stable operation at the preferred operating temperatures. Degradation in the sensor output caused by temperature cycling was identified as a change in resistance at the junction between the sensor body and the external leads attached to the sensor body. The degradation was eliminated by providing strong mechanical anchors for the wire and processing the junctions to obtain good electrical bonds. The NOx sensors also detect oxygen and therefore the fully-packaged sensor needs to be enclosed with an oxygen sensor in a small, heated zirconia chamber exposed to test gas through a diffusion plug which limits the flow of gas from the outside. Oxygen is pumped from the interior of the chamber to lower the oxygen content and the combination of measurements from the NOx and oxygen sensors yields the NOx content of the gas. Two types of electronic control units were designed and built. One control unit provides independent constant voltages to the NOx and oxygen sensors and reads the current from them (that is, detects the amount of test gas present). The second controller holds the fully-assembled sensor at the desired operating temperature and controllably pumps excess oxygen from the test chamber. While the development of the sensor body was a complete success, the development of the packaging was only partially successful. All of the basic principles were demonstrated, but the packaging was too complex to optimize the operation within the resources of the program. Thus, no fully-assembled sensors were sent to outside labs for testing of cross-sensitivities, response times, etc. Near the end of the program, Sensata Technologies of Attleboro, MA tested the sensor bodies and confirmed the CeramPhysics measurements as indicated in the following attached letter. Sensata was in the process of designing their own packaging for the sensor and performing cross-sensitivity tests when they stopped all sensor development work due to the automotive industry downturn. Recently Ceramatec Inc. of Salt Lake City has expressed an interest in testing the sensor, and other licensing opportunities are being pursued.

  5. Method for dispersing catalyst onto particulate material

    DOE Patents [OSTI]

    Utz, Bruce R. (Pittsburgh, PA); Cugini, Anthony V. (Pittsburgh, PA)

    1992-01-01T23:59:59.000Z

    A method for dispersing finely divided catalyst precursors onto the surface of coal or other particulate material includes the steps of forming a wet paste mixture of the particulate material and a liquid solution containing a dissolved transition metal salt, for instance a solution of ferric nitrate. The wet paste mixture is in a state of incipient wetness with all of this solution adsorbed onto the surfaces of the particulate material without the presence of free moisture. On adding a precipitating agent such as ammonia, a catalyst precursor such as hydrated iron oxide is deposited on the surfaces of the coal. The catalyst is activated by converting it to the sulfide form for the hydrogenation or direct liquefaction of the coal.

  6. Congressionally Directed Project for Passive NOx Removal Catalysts Research

    SciTech Connect (OSTI)

    Schneider, William

    2014-08-29T23:59:59.000Z

    The Recipient proposes to produce new scientific and technical knowledge and tools to enable the discovery and deployment of highly effective materials for the selective catalytic reduction (SCR) of nitrogen oxides (NOx) from lean combustion exhaust. A second goal is to demonstrate a closely coupled experimental and computational approach to heterogeneous catalysis research. These goals will be met through the completion of four primary technical objectives: First, an in-depth kinetic analysis will be performed on two prominent classes of NOx SCR catalysts, Fe- and Cu-exchanged beta and ZSM-5 zeolites, over a wide range of catalyst formulation and under identical, high conversion conditions as a function of gas phase composition. Second, the nanoscale structure and adsorption chemistry of these high temperature (HT) and low temperature (LT) catalysts will be determined using in situ and operando spectroscopy under the same reaction conditions. Third, first-principles molecular simulations will be used to model the metal-zeolite active sites, their adsorption chemistry, and key steps in catalytic function. Fourth, this information will be integrated into chemically detailed mechanistic and kinetic descriptions and models of the operation of these well- defined NOx SCR catalysts under practically relevant reaction conditions. The new knowledge and models that derive from this work will be published in the scientific literature.

  7. NOx CONTROL OPTIONS AND INTEGRATION FOR US COAL FIRED BOILERS

    SciTech Connect (OSTI)

    Michael J. Bockelie

    2000-10-31T23:59:59.000Z

    This report summarizes the research that has been performed by Reaction Engineering International (REI) during the last three months on demonstrating and evaluating low NOx control strategies and their possible impact on boiler performance for firing US coals. The focus of our efforts during the last six months have been on: (1) Field Tests for RRI at the Conectiv BL England Station Unit No.1, a 130 MW cyclone fired boiler; (2) Extending our Computational Fluid Dynamics (CFD) based NOx model to accommodate the chemistry for Rich Reagent Injection (RRI) in cyclone fired boilers; (3) Applying the NOx model to evaluate RRI systems integrated into a boiler with Over Fired Air (OFA) and Selective Non-Catalytic Reduction (SNCR); (4) Field Tests of the REI Corrosion Probe at the Conectiv BL England Station Unit No.1; (5) Commence engineering study of ammonia adsorption mechanisms for Fly Ash; (6) Presentation of current program accomplishments and plans for future work to DoE staff members at NETL-FE (Pittsburgh); and (7) Presentation of preliminary field test results for RRI to EPRI CNCIG.

  8. Method of dispersing particulate aerosol tracer

    DOE Patents [OSTI]

    O'Holleran, Thomas P. (Belleville, MI)

    1988-01-01T23:59:59.000Z

    A particulate aerosol tracer which comprises a particulate carrier of sheet silicate composition having a particle size up to one micron, and a cationic dopant chemically absorbed in solid solution in the carrier. The carrier is preferably selected from the group consisting of natural mineral clays such as bentonite, and the dopant is selected from the group consisting of rare earth elements and transition elements. The tracers are dispersed by forming an aqueous salt solution with the dopant present as cations, dispersing the carriers in the solution, and then atomizing the solution under heat sufficient to superheat the solution droplets at a level sufficient to prevent reagglomeration of the carrier particles.

  9. Modeling of Particulate Behavior in Pinhole Breaches

    SciTech Connect (OSTI)

    Casella, Andrew M.; Loyalka, Sudarshan K.; Hanson, Brady D.

    2014-04-01T23:59:59.000Z

    A model is presented for calculating depressurization time for and particulate release from used nuclear fuel dry storage containers that have developed a pinhole breach. Particular attention is given to particulate deposition and transmission within the breach pathway. The model is modular in nature and is developed in a way that allows for more advanced treatments of internal temperature, internal component geometry, or aerosol flow to be readily incorporated. The model can be treated as a basis for addressing concerns associated with monitoring and verification efforts during long-term dry cask storage

  10. Partial-Flow Diesel Particulate Filter of Sintered Metal Fiber...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Partial-Flow Diesel Particulate Filter of Sintered Metal Fiber Fleece Partial-Flow Diesel Particulate Filter of Sintered Metal Fiber Fleece Poster presented at the 16th Directions...

  11. Size-Dependent Filtration of Non-Loaded Particulate Traps

    E-Print Network [OSTI]

    White, Jessica

    2014-12-12T23:59:59.000Z

    This work investigates the filtration efficiency of uncoated, commercial Diesel Particulate Filter (DPF) substrates of three porosities (55.8%, 61.1%, 65.0%) for particulate sizes representative of Gasoline Direct Injection (GDI) exhaust, and also...

  12. Ultra Low NOx Catalytic Combustion for IGCC Power Plants

    SciTech Connect (OSTI)

    Shahrokh Etemad; Benjamin Baird; Sandeep Alavandi; William Pfefferle

    2008-03-31T23:59:59.000Z

    In order to meet DOE's goals of developing low-emissions coal-based power systems, PCI has further developed and adapted it's Rich-Catalytic Lean-burn (RCL{reg_sign}) catalytic reactor to a combustion system operating on syngas as a fuel. The technology offers ultra-low emissions without the cost of exhaust after-treatment, with high efficiency (avoidance of after-treatment losses and reduced diluent requirements), and with catalytically stabilized combustion which extends the lower Btu limit for syngas operation. Tests were performed in PCI's sub-scale high-pressure (10 atm) test rig, using a two-stage (catalytic then gas-phase) combustion process for syngas fuel. In this process, the first stage consists of a fuel-rich mixture reacting on a catalyst with final and excess combustion air used to cool the catalyst. The second stage is a gas-phase combustor, where the air used for cooling the catalyst mixes with the catalytic reactor effluent to provide for final gas-phase burnout and dilution to fuel-lean combustion products. During testing, operating with a simulated Tampa Electric's Polk Power Station syngas, the NOx emissions program goal of less than 0.03 lbs/MMBtu (6 ppm at 15% O{sub 2}) was met. NOx emissions were generally near 0.01 lbs/MMBtu (2 ppm at 15% O{sub 2}) (PCI's target) over a range on engine firing temperatures. In addition, low emissions were shown for alternative fuels including high hydrogen content refinery fuel gas and low BTU content Blast Furnace Gas (BFG). For the refinery fuel gas increased resistance to combustor flashback was achieved through preferential consumption of hydrogen in the catalytic bed. In the case of BFG, stable combustion for fuels as low as 88 BTU/ft{sup 3} was established and maintained without the need for using co-firing. This was achieved based on the upstream catalytic reaction delivering a hotter (and thus more reactive) product to the flame zone. The PCI catalytic reactor was also shown to be active in ammonia reduction in fuel allowing potential reductions in the burner NOx production. These reductions of NOx emissions and expanded alternative fuel capability make the rich catalytic combustor uniquely situated to provide reductions in capital costs through elimination of requirements for SCR, operating costs through reduction in need for NOx abating dilution, SCR operating costs, and need for co-firing fuels allowing use of lower value but more available fuels, and efficiency of an engine through reduction in dilution flows.

  13. NOx reduction through combustion optimization at PEPCO`s Potomac River Station

    SciTech Connect (OSTI)

    Cramer, D.S.; Williams, S.E.; Watkins, J.T. [Potomac Electric Power Company, Upper Marlboro, MD (United States)] [and others

    1995-06-01T23:59:59.000Z

    This paper describes the work done under EPRI Project RP 3383 at Potomac River Station to reduce NOx emissions by adjusting boiler controls. it details the method followed by PEPCO and Lehigh engineers to achieve a 35% reduction in average NOx emissions over a one-month extended test. Parameters that had the largest effect on NOx are discussed. A description of instruments installed to better monitor and control combustion is included.

  14. Lean NOx Trap Catalysis for Lean Natural Gas Engine Applications

    SciTech Connect (OSTI)

    Parks, II, James E [ORNL; Storey, John Morse [ORNL; Theiss, Timothy J [ORNL; Ponnusamy, Senthil [ORNL; Ferguson, Harley Douglas [ORNL; Williams, Aaron M [ORNL; Tassitano, James B [ORNL

    2007-09-01T23:59:59.000Z

    Distributed energy is an approach for meeting energy needs that has several advantages. Distributed energy improves energy security during natural disasters or terrorist actions, improves transmission grid reliability by reducing grid load, and enhances power quality through voltage support and reactive power. In addition, distributed energy can be efficient since transmission losses are minimized. One prime mover for distributed energy is the natural gas reciprocating engine generator set. Natural gas reciprocating engines are flexible and scalable solutions for many distributed energy needs. The engines can be run continuously or occasionally as peak demand requires, and their operation and maintenance is straightforward. Furthermore, system efficiencies can be maximized when natural gas reciprocating engines are combined with thermal energy recovery for cooling, heating, and power applications. Expansion of natural gas reciprocating engines for distributed energy is dependent on several factors, but two prominent factors are efficiency and emissions. Efficiencies must be high enough to enable low operating costs, and emissions must be low enough to permit significant operation hours, especially in non-attainment areas where emissions are stringently regulated. To address these issues the U.S. Department of Energy and the California Energy Commission launched research and development programs called Advanced Reciprocating Engine Systems (ARES) and Advanced Reciprocating Internal Combustion Engines (ARICE), respectively. Fuel efficiency and low emissions are two primary goals of these programs. The work presented here was funded by the ARES program and, thus, addresses the ARES 2010 goals of 50% thermal efficiency (fuel efficiency) and <0.1 g/bhp-hr emissions of oxides of nitrogen (NOx). A summary of the goals for the ARES program is given in Table 1-1. ARICE 2007 goals are 45% thermal efficiency and <0.015 g/bhp-hr NOx. Several approaches for improving the efficiency and emissions of natural gas reciprocating engines are being pursued. Approaches include: stoichiometric engine operation with exhaust gas recirculation and three-way catalysis, advanced combustion modes such as homogeneous charge compression ignition, and extension of the lean combustion limit with advanced ignition concepts and/or hydrogen mixing. The research presented here addresses the technical approach of combining efficient lean spark-ignited natural gas combustion with low emissions obtained from a lean NOx trap catalyst aftertreatment system. This approach can be applied to current lean engine technology or advanced lean engines that may result from related efforts in lean limit extension. Furthermore, the lean NOx trap technology has synergy with hydrogen-assisted lean limit extension since hydrogen is produced from natural gas during the lean NOx trap catalyst system process. The approach is also applicable to other lean engines such as diesel engines, natural gas turbines, and lean gasoline engines; other research activities have focused on those applications. Some commercialization of the technology has occurred for automotive applications (both diesel and lean gasoline engine vehicles) and natural gas turbines for stationary power. The research here specifically addresses barriers to commercialization of the technology for large lean natural gas reciprocating engines for stationary power. The report presented here is a comprehensive collection of research conducted by Oak Ridge National Laboratory (ORNL) on lean NOx trap catalysis for lean natural gas reciprocating engines. The research was performed in the Department of Energy's ARES program from 2003 to 2007 and covers several aspects of the technology. All studies were conducted at ORNL on a Cummins C8.3G+ natural gas engine chosen based on industry input to simulate large lean natural gas engines. Specific technical areas addressed by the research include: NOx reduction efficiency, partial oxidation and reforming chemistry, and the effects of sulfur poisons on the partial oxidation

  15. NOx Control Options and Integration for US Coal Fired Boilers

    SciTech Connect (OSTI)

    Mike Bockelie; Marc Cremer; Kevin Davis; Martin Denison; Adel Sarofim; Connie Senior; Hong-Shig Shim; Dave Swenson; Bob Hurt; Eric Suuberg; Eric Eddings; Kevin Whitty; Larry Baxter; Calvin Bartholomew; William Hecker

    2006-06-30T23:59:59.000Z

    This is the Final Report for DOE Cooperative Agreement No: DE-FC26-00NT40753. The goal of the project was to develop cost-effective analysis tools and techniques for demonstrating and evaluating low-NOx control strategies and their possible impact on boiler performance for boilers firing US coals. The Electric Power Research Institute (EPRI) provided co-funding for this program. This project included research on: (1) In furnace NOx control; (2) Impacts of combustion modifications on boiler operation; (3) Selective Catalytic Reduction (SCR) catalyst testing and (4) Ammonia adsorption/removal on fly ash. Important accomplishments were achieved in all aspects of the project. Rich Reagent Injection (RRI), an in-furnace NOx reduction strategy based on injecting urea or anhydrous ammonia into fuel rich regions in the lower furnace, was evaluated for cyclone-barrel and PC fired utility boilers. Field tests successfully demonstrated the ability of the RRI process to significantly reduce NOx emissions from a staged cyclone-fired furnace operating with overfire air. The field tests also verified the accuracy of the Computational Fluid Dynamic (CFD) modeling used to develop the RRI design and highlighted the importance of using CFD modeling to properly locate and configure the reagent injectors within the furnace. Low NOx firing conditions can adversely impact boiler operation due to increased waterwall wastage (corrosion) and increased soot production. A corrosion monitoring system that uses electrochemical noise (ECN) corrosion probes to monitor, on a real-time basis, high temperature corrosion events within the boiler was evaluated. Field tests were successfully conducted at two plants. The Ohio Coal Development Office provided financial assistance to perform the field tests. To investigate soot behavior, an advanced model to predict soot production and destruction was implemented into an existing reacting CFD modeling tool. Comparisons between experimental data collected in a pilot scale furnace and soot behavior predicted by the CFD model showed good agreement. Field and laboratory tests were performed for SCR catalysts used for coal and biomass co-firing applications. Fundamental laboratory studies were performed to better understand mechanisms involved with catalyst deactivation. Field tests with a slip stream reactor were used to create catalyst exposed to boiler flue gas for firing coal and for co-firing coal and biomass. The field data suggests the mechanisms leading to catalyst deactivation are, in order of importance, channel plugging, surface fouling, pore plugging and poisoning. Investigations were performed to better understand the mechanisms involved with catalyst regeneration through mechanical or chemical methods. A computer model was developed to predict NOx reduction across the catalyst in a SCR. Experiments were performed to investigate the fundamentals of ammonia/fly ash interactions with relevance to the operation of advanced NOx control technologies such as selective catalytic reduction. Measurements were performed for ammonia adsorption isotherms on commercial fly ash samples subjected to a variety of treatments and on the chemistry of dry and semi-dry ammonia removal processes. This work resulted in the first fundamental ammonia isotherms on carbon-containing fly ash samples. This work confirms industrial reports that aqueous solution chemistry takes place upon the introduction of even very small amounts of water, while the ash remains in a semi-dry state.

  16. Electrically heated particulate filter preparation methods and systems

    DOE Patents [OSTI]

    Gonze, Eugene V [Pinckney, MI

    2012-01-31T23:59:59.000Z

    A control system that controls regeneration of a particulate filter is provided. The system generally includes a fuel control module that controls injection of fuel into exhaust that passes through the particulate filter. A regeneration module controls current to the particulate filter to initiate regeneration after the fuel has been injected into the exhaust.

  17. Flexible CHP System with Low NOx, CO and VOC Emissions - Fact...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Sheet, 2014 Flexible CHP System with Low NOx, CO and VOC Emissions - Fact Sheet, 2014 The Gas Technology Institute, in collaboration with Cannon Boiler Works, Integrated CHP...

  18. Use of Simulation To Optimize NOx Abatement by Absorption and Selective Catalytic Reduction

    E-Print Network [OSTI]

    Liu, Y. A.

    portion of the tower and 2 spray-scrubber sections in the bottom. The NOx-laden fumes enter the bottom

  19. Reduction of NOx in Synthetic Diesel Exhaust via Two-Step Plasma...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Citation: Tonkyn RG, SE Barlow, and J Hoard.2003."Reduction of NOx in Synthetic Diesel Exhaust via Two-Step Plasma-Catalysis Treatment."Applied Catalysis. B,...

  20. Desulfurization Effects on a Light-Duty Diesel Vehicle NOx Adsorber Exhaust Emission Control System

    SciTech Connect (OSTI)

    Tatur, M.; Tomazic, D.; Tyrer, H.; Thornton, M.; Kubsh, J.

    2006-05-01T23:59:59.000Z

    Analyzes the effects on gaseous emissions, before and after desulfurization, on a light-duty diesel vehicle with a NOx adsorber catalyst.

  1. Plasma-Activated Lean NOx Catalysis for Heavy-Duty Diesel Emissions...

    Broader source: Energy.gov (indexed) [DOE]

    Lean NOx Catalysis l Chemistry l Reducing Agent Effects l Collaboration with LEP CRADA l Aging Studies Plasma Initiation - + Electron Avalanche e - e - e - e - e - e - e -...

  2. NH3 generation over commercial Three-Way Catalysts and Lean-NOx...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    & Publications Emissions Control for Lean Gasoline Engines Emissions Control for Lean Gasoline Engines Spatiotemporal Distribution of NOx Storage: a Factor Controlling NH3 and...

  3. A Fast Start-up On-Board Fuel Reformer for NOx Adsorber Regeneration...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fuel Processor for Rapid and Efficient Regeneration of Single Leg NOx Adsorber Systems Hydrogen generation from plasmatron reformers and use for diesel exhaust aftertreatment...

  4. Evaluating the origins and transformations of organic matter and dissolved inorganic nitrogen in two contrasting North Sea estuaries 

    E-Print Network [OSTI]

    Ahad, Jason Michael Elias

    In order to delineate the potential sources and to understand the main controls on the biogeochemical cycling of dissolved and particulate organic matter (DOM, POM) and dissolved inorganic nitrogen (DIN) during estuarine ...

  5. Rare earth element components in atmospheric particulates in the Bayan Obo mine region

    SciTech Connect (OSTI)

    Wang, Lingqing, E-mail: wanglq@igsnrr.ac.cn; Liang, Tao, E-mail: liangt@igsnrr.ac.cn; Zhang, Qian; Li, Kexin

    2014-05-01T23:59:59.000Z

    The Bayan Obo mine, located in Inner Mongolia, China, is the largest light rare earth body ever found in the world. The research for rare earth elements (REEs) enrichment in atmospheric particulates caused by mining and ore processing is fairly limited so far. In this paper, atmospheric particulates including total suspended particulate (TSP) matter and particles with an equivalent aerodynamic diameter less than 10 ?m (PM{sub 10}) were collected around the Bayan Obo mine region, in August 2012 and March 2013, to analyze the levels and distributions of REEs in particles. The total concentrations of REEs for TSP were 149.8 and 239.6 ng/m{sup 3}, and those for PM{sub 10} were 42.8 and 68.9 ng/m{sup 3}, in August 2012 and March 2013, respectively. Enrichment factor was calculated for all 14 REEs in the TSP and PM{sub 10} and the results indicated that REEs enrichment in atmosphere particulates was caused by anthropogenic sources and influenced by the strong wind in springtime. The spatial distribution of REEs in TSP showed a strong gradient concentration in the prevailing wind direction. REE chondrite normalized patterns of TSP and PM{sub 10} were similar and the normalized curves inclined to the right side, showing the conspicuous fractionation between the light REEs and heavy REE, which supported by the chondrite normalized concentration ratios calculated for selected elements (La{sub N}/Yb{sub N}, La{sub N}/Sm{sub N}, Gd{sub N}/Yb{sub N}). - Highlights: • TSP and PM{sub 10} samples were collected to analyze the levels and distributions of REE. • Enrichment factors indicated that REE enrichment was caused by anthropogenic sources. • The distribution of REEs showed a strong gradient in the prevailing wind direction. • Obvious fractionation between LREEs and HREEs is observed in atmospheric particulates.

  6. A study of the regeneration process in diesel particulate traps using a copper fuel additive

    SciTech Connect (OSTI)

    Tan, J.C.; Opris, C.N.; Baumgard, K.J.; Johnson, J.H. [Michigan Technological Univ., Houghton, MI (United States)

    1996-09-01T23:59:59.000Z

    The goals of this research are to understand the regeneration process in ceramic (Cordierite) monolith traps using a copper fuel additive and to investigate the various conditions that lead to trap regeneration failure. The copper additive lowers the trap regeneration temperature from approximately 500 C to 375 C and decreases the time necessary for regeneration. Because of these characteristics, it is important to understand the effect of the additive on regeneration when excessive particulate matter accumulation occurs in the trap. The effects of particulate mass loading on regeneration temperatures and regeneration time were studied for both the controlled (engine operated at full load rated speed) and uncontrolled conditions. The trap peak temperatures were higher for the uncontrolled than the controlled regeneration. The higher peak trap temperatures were predominantly controlled by the effect of the exhaust flow rates on the energy transfer processes. The total regeneration time was faster for the controlled regeneration compared to the uncontrolled regeneration. All traps passed the controlled regeneration tests having maximum temperatures less than 900 C. During the uncontrolled regeneration tests, trap failure occurred at 135 and 139 g particulate matter loadings. The maximum temperatures were in excess of 1,150 C. The pressure drop across the trap was modeled using the one dimensional Darcy`s law which accounted for the pressure drop due to the ceramic wall and the particulate layer. The experimental results for the substrate correlate well with the empirical substrate pressure drop models available in the literature. The models also enable an estimate to be made regarding trap mass loading. These data along with the laboratory data have indicated that mass loadings greater than 110 g followed by high temperature operation and subsequent engine idling can result in trap failures during regeneration.

  7. Particulate Matter: What is it and Why does it Matter to Agriculture? 

    E-Print Network [OSTI]

    Mukhtar, Saqib; McGee, Russell

    2009-04-16T23:59:59.000Z

    for PM and other pollutants. As the EPA and state regulatory agencies refine their regulations, it is important to recognize that not all PM is the same. Most of the PM in urban environments is fine, while most agricultural PM is larger than...

  8. Particulate Matter: What is it and Why does it Matter to Agriculture?

    E-Print Network [OSTI]

    Mukhtar, Saqib; McGee, Russell

    2009-04-16T23:59:59.000Z

    for PM and other pollutants. As the EPA and state regulatory agencies refine their regulations, it is important to recognize that not all PM is the same. Most of the PM in urban environments is fine, while most agricultural PM is larger than...

  9. NOx CONTROL OPTIONS AND INTEGRATION FOR US COAL FIRED BOILERS

    SciTech Connect (OSTI)

    Mike Bockelie; Marc Cremer; Kevin Davis; Connie Senior; Bob Hurt; Eric Eddings; Larry Baxter

    2001-10-10T23:59:59.000Z

    This is the fifth Quarterly Technical Report for DOE Cooperative Agreement No: DE-FC26-00NT40753. The goal of the project is to develop cost effective analysis tools and techniques for demonstrating and evaluating low NOx control strategies and their possible impact on boiler performance for firing US coals. The Electric Power Research Institute (EPRI) is providing cofunding for this program. This program contains multiple tasks and good progress is being made on all fronts. Field tests for NOx reduction in a cyclone fired utility boiler due to using Rich Reagent Injection (RRI) have been started. CFD modeling studies have been started to evaluate the use of RRI for NOx reduction in a corner fired utility boiler using pulverized coal. Field tests of a corrosion monitor to measure waterwall wastage in a utility boiler have been completed. Computational studies to evaluate a soot model within a boiler simulation program are continuing. Research to evaluate SCR catalyst performance has started. A literature survey was completed. Experiments have been outlined and two flow reactor systems have been designed and are under construction. Commercial catalyst vendors have been contacted about supplying catalyst samples. Several sets of new experiments have been performed to investigate ammonia removal processes and mechanisms for fly ash. Work has focused on a promising class of processes in which ammonia is destroyed by strong oxidizing agents at ambient temperature during semi-dry processing (the use of moisture amounts less than 5 wt-%). Both ozone and an ozone/peroxide combination have been used to treat both basic and acidic ammonia-laden ashes.

  10. METHANE de-NOX FOR UTILITY PC BOILERS

    SciTech Connect (OSTI)

    Joseph Rabovitser; Bruce Bryan; Serguei Nester; Stan Wohadlo

    2002-01-31T23:59:59.000Z

    The project seeks to develop and validate a new pulverized coal combustion system to reduce utility PC boiler NOx emissions to 0.15 lb per million Btu or less without post-combustion flue gas cleaning. Work during previous reporting periods completed the design, installation, shakedown and initial PRB coal testing of a 3-million Btu/h pilot system at BBP's Pilot-Scale Combustion Facility (PSCF) in Worcester, MA. Based on these results, modifications to the gas-fired preheat combustor and PC burner were defined, along with a modified testing plan and schedule. A revised subcontract was executed with BBP to reflect changes in the pilot testing program. Modeling activities were continued to develop and verify revised design approaches for both the Preheat gas combustor and PC burner. Reactivation of the pilot test system was then begun with BBP personnel. During the previous reporting period, reactivation of the pilot test system was completed with the modified Preheat gas combustor. Following shakedown of the modified gas combustor alone, a series of successful tests of the new combustor with PRB coal using the original PC burner were completed. NOx at the furnace exit was reduced significantly with the modified gas combustor, to as low as 150 ppm with only 36 ppm CO (both corrected to 3% O2). Concurrent with testing, GTI and BBP collaborated on development of two modified designs for the PC burner optimized to fire preheated char and pyrolysis products from the Preheat gas combustor. During the current reporting period, one of the two modified PC burner designs was fabricated and installed in the pilot test facility. Testing of the modified pilot system (modified gas combustor and modified PC burner) during the quarter included 38 tests with PRB coal. NOx reduction was significantly improved to levels as low as 60-100 ppmv with CO in the range of 35-112 ppmv without any furnace air staging.

  11. Three-Dimensional Composite Nanostructures for Lean NOx Emission Control

    SciTech Connect (OSTI)

    Gao, Pu-Xian

    2013-07-31T23:59:59.000Z

    This final report to the Department of Energy (DOE) and National Energy Technology Laboratory (NETL) for DE-EE0000210 covers the period from October 1, 2009 to July 31, 2013. Under this project, DOE awarded UConn about $1,248,242 to conduct the research and development on a new class of 3D composite nanostructure based catalysts for lean NOx emission control. Much of the material presented here has already been submitted to DOE/NETL in quarterly technical reports. In this project, through a scalable solution process, we have successfully fabricated a new class of catalytic reactors, i.e., the composite nanostructure array (nano-array) based catalytic converters. These nanocatalysts, distinct from traditional powder washcoat based catalytic converters, directly integrate monolithic substrates together with nanostructures with well-defined size and shape during the scalable hydrothermal process. The new monolithic nanocatalysts are demonstrated to be able to save raw materials including Pt-group metals and support metal oxides by an order of magnitude, while perform well at various oxidation (e.g., CO oxidation and NO oxidation) and reduction reactions (H{sub 2} reduction of NOx) involved in the lean NOx emissions. The size, shape and arrangement of the composite nanostructures within the monolithic substrates are found to be the key in enabling the drastically reduced materials usage while maintaining the good catalytic reactivity in the enabled devices. The further understanding of the reaction kinetics associated with the unique mass transport and surface chemistry behind is needed for further optimizing the design and fabrication of good nanostructure array based catalytic converters. On the other hand, the high temperature stability, hydrothermal aging stability, as well as S-poisoning resistance have been investigated in this project on the nanocatalysts, which revealed promising results toward good chemical and mechanical robustness, as well as S-poisoning resistance. Further investigation is needed for unraveling the understanding, design and selection principles of this new class of nanostructure based monolithic catalysts.

  12. SOx/NOx sorbent and process of use

    DOE Patents [OSTI]

    Ziebarth, M.S.; Hager, M.J.; Beeckman, J.W.; Plecha, S.

    1993-01-19T23:59:59.000Z

    An alumina sorbent capable of adsorbing NOx and SOx from waste gases and being regenerated by heating above 600 C. is made by incorporating an alumina stabilizing agent into the sorbent. A preferred method is to add the stabilizer when the alumina is precipitated. The precipitated powder is formed subsequently into a slurry, milled and dripped to form the stabilizing spheroidal alumina particles. These particles are impregnated with an alkali metal or alkaline earth metal to form the stabilized sorbent. Alumina stabilizers include one or more of silica, lanthana, other rare earths, titania, zirconia and alkaline earths.

  13. SOX/NOX sorbent and process of use

    DOE Patents [OSTI]

    Ziebarth, M.S.; Hager, M.J.; Beeckman, J.W.; Plecha, S.

    1995-05-09T23:59:59.000Z

    An alumina sorbent capable of adsorbing NOx and SOx from waste gases and being regenerated by heating above 600 C is made by incorporating an alumina stabilizing agent into the sorbent. A preferred method is to add the stabilizer when the alumina is precipitated. The precipitated powder is formed subsequently into a slurry, milled and dripped to form the stabilized spheroidal alumina particles. These particles are impregnated with an alkali metal or alkaline earth metal to form the stabilized sorbent. Alumina stabilizers include one or more of silica, lanthana, other rare earths, titania, zirconia and alkaline earths. 3 figs.

  14. Group effects on fuel NOx emissisons from coal

    E-Print Network [OSTI]

    Vadakkath, Anand Anakkara

    1991-01-01T23:59:59.000Z

    . 18 N to NO Conversion vs G Number via Volatiles . 55 56 19 N to NO Conversion vs G Number by Burn-out. . . 20 N to NO Conversion vs G Number by All Methods . 57 21 N to NO Conversion vs G number for Two Coal Diameters 60 Figure Page 22 N... Ratio of GC Rate to ISOC Rate versus G Number (Annamalai) 17 8 Group Combustion Model for a. Spherical Coal Cloud 20 9 Flow-chart for the Program 32 10 Experimental Set-up . 11 Water Cooled Collection System . 40 12 Connections for NOx Analyzer . 42...

  15. Lean NOx Catalysis Research and Development | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't YourTransport(FactDepartment ofLetter Report:40PMDepartment ofs o u t h e a s t e rtheNOx

  16. Experimental and numerical analysis of isothermal turbulent flows in interacting low NOx burners in coal-fired furnaces 

    E-Print Network [OSTI]

    Cvoro, Valentina

    Coal firing power stations represent the second largest source of global NOx emissions. The current practice of predicting likely exit NOx levels from multi-burner furnaces on the basis of single burner test rig data has been proven inadequate...

  17. A Novel Technology for the Reduction of NOx on Char by Microwaves 

    E-Print Network [OSTI]

    Buenger, C.; Peterson, E.

    1994-01-01T23:59:59.000Z

    of these applications. The technology is directed at NOx reduction but may also address other pollutants like SO2. The technology employees char, a heat treated and devolitilized form of coal, to adsorb NOx from the flue (or waste) gas. Adsorption of greater than 99...

  18. Promotional Effects of H2O Treatment on NOx Storage over Fresh...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Aged Pt-BaOAl2O3 Lean NOx Trap Catalysts . Abstract: A simple liquid water treatment applied to fresh and thermally aged Pt(2wt%)-BaO(20wt%)Al2O3 lean NOx trap catalysts at...

  19. Low Carbon Footprint and Ultra Low NOx Boilers through Efficiency Gain 

    E-Print Network [OSTI]

    Benz, R,; Staedter, M.

    2008-01-01T23:59:59.000Z

    Low Carbon Footprint and Ultra Low NOx Boilers through Efficiency Gain Robert Benz Marcel Staedter... Industrial Energy Technology Conference, New Orleans, LA, May 6-9, 2008. M. Staedter, R. Benz / Low Carbon, Ultra Low NOx through Efficiency Gain where y denotes the mole fraction of excess...

  20. The effect of hydrogen addition on flammability limit and NOx emission in ultra-lean counterflow

    E-Print Network [OSTI]

    Gülder, �mer L.

    . They indicated that the addition of hydrogen to natural gas or methane resulted in an increase in NOx for most increases, and then decreases with the increase in the fraction of hydrogen. Overall, hydrogen enrichment rights reserved. Keywords: Hydrogen enrichment; NOx; Extinction limit; Ultra-lean premixed flame. 1

  1. APBF-DEC Light-duty NOx Adsorber/DPF Project

    Broader source: Energy.gov (indexed) [DOE]

    Light - Duty NOx AdsorberDPF Project Vehicle Tests - FTP 75 (Conducted at EPA NVFEL in Ann Arbor) NOx (gmi) 0.00 0.01 0.02 0.03 0.04 0.05 0.06 0.07 Test No. 1 2 3 4 5 PM (mgmi)...

  2. Intra-catalyst Reductant Chemistry in Lean NOx Traps: A Study...

    Broader source: Energy.gov (indexed) [DOE]

    Engine DOC LNT Engine Out Bench (SS1) UEGO1 UEGO2 UEGO3 SS2 NOx Sensor 1 NOx Sensor 2 Turbo 14 LNT 12 LNT 34 LNT FTIR GCMS bag (dilute) Air Bench 2 SpaciMS Tailpipe Bench...

  3. Examination of the Effects of Sea Salt Aerosols on Southeast Texas Ozone and Secondary Organic Aerosol 

    E-Print Network [OSTI]

    Benoit, Mark David

    2013-02-06T23:59:59.000Z

    study these interactions. This is important because the EPA has considered tightening the standards for both ozone and particulate matter. Industries would then need to reduce emissions or move farther from current sources of Cl or NOx pollution....

  4. Apparatus for measuring surface particulate contamination

    DOE Patents [OSTI]

    Woodmansee, Donald E. (Simpsonville, SC)

    2002-01-01T23:59:59.000Z

    An apparatus for measuring surface particulate contamination includes a tool for collecting a contamination sample from a target surface, a mask having an opening of known area formed therein for defining the target surface, and a flexible connector connecting the tool to the mask. The tool includes a body portion having a large diameter section defining a surface and a small diameter section extending from the large diameter section. A particulate collector is removably mounted on the surface of the large diameter section for collecting the contaminants. The tool further includes a spindle extending from the small diameter section and a spool slidingly mounted on the spindle. A spring is disposed between the small diameter section and the spool for biasing the spool away from the small diameter section. An indicator is provided on the spindle so as to be revealed when the spool is pressed downward to compress the spring.

  5. Acute changes in pulse pressure in relation to constituents of particulate air pollution in elderly persons

    SciTech Connect (OSTI)

    Jacobs, Lotte [Occupational and Environmental Medicine, Unit of Lung Toxicology, K.U.Leuven, Leuven (Belgium)] [Occupational and Environmental Medicine, Unit of Lung Toxicology, K.U.Leuven, Leuven (Belgium); Buczynska, Anna [Departement of Chemistry, UA, Wilrijk (Belgium)] [Departement of Chemistry, UA, Wilrijk (Belgium); Walgraeve, Christophe [Research group EnVOC, Department of Sustainable Organic Chemistry and Technology, UGent, Gent (Belgium)] [Research group EnVOC, Department of Sustainable Organic Chemistry and Technology, UGent, Gent (Belgium); Delcloo, Andy [Royal Meteorological Institute, Brussels (Belgium)] [Royal Meteorological Institute, Brussels (Belgium); Potgieter-Vermaak, Sanja [Departement of Chemistry, UA, Wilrijk (Belgium) [Departement of Chemistry, UA, Wilrijk (Belgium); Molecular Science Institute, School of Chemistry, University of Witwatersrand, Johannesburg (South Africa); Division of Chemistry and Environmental Science, Manchester Metropolitan University, Manchester (United Kingdom); Van Grieken, Rene [Departement of Chemistry, UA, Wilrijk (Belgium)] [Departement of Chemistry, UA, Wilrijk (Belgium); Demeestere, Kristof; Dewulf, Jo; Van Langenhove, Herman [Research group EnVOC, Department of Sustainable Organic Chemistry and Technology, UGent, Gent (Belgium)] [Research group EnVOC, Department of Sustainable Organic Chemistry and Technology, UGent, Gent (Belgium); De Backer, Hugo [Royal Meteorological Institute, Brussels (Belgium)] [Royal Meteorological Institute, Brussels (Belgium); Nemery, Benoit, E-mail: ben.nemery@med.kuleuven.be [Occupational and Environmental Medicine, Unit of Lung Toxicology, K.U.Leuven, Leuven (Belgium)] [Occupational and Environmental Medicine, Unit of Lung Toxicology, K.U.Leuven, Leuven (Belgium); Nawrot, Tim S. [Occupational and Environmental Medicine, Unit of Lung Toxicology, K.U.Leuven, Leuven (Belgium) [Occupational and Environmental Medicine, Unit of Lung Toxicology, K.U.Leuven, Leuven (Belgium); Centre for Environmental Sciences, Hasselt University, Diepenbeek (Belgium)

    2012-08-15T23:59:59.000Z

    An increased pulse pressure (difference between systolic and diastolic blood pressure) suggests aortic stiffening. The objective of this study was to examine the acute effects of both particulate matter (PM) mass and composition on blood pressure, among elderly persons. We carried out a panel study in persons living in elderly homes in Antwerp, Belgium. We recruited 88 non-smoking persons, 70% women with a mean age of 83 years (standard deviation: 5.2). Blood pressure was measured and a blood sample was collected on two time points, which were chosen so that there was an exposure contrast in ambient PM exposure. The elemental content of the collected indoor and outdoor PM{sub 2.5} (particulate matter with an aerodynamic diameter <2.5 {mu}m) mass concentration was measured. Oxygenated polycyclic aromatic hydrocarbons (oxy-PAHs) on outdoor PM{sub 10} (particulate matter with an aerodynamic diameter <10 {mu}m) were measured. Each interquartile range increase of 20.8 {mu}g/m Superscript-Three in 24-h mean outdoor PM{sub 2.5} was associated with an increase in pulse pressure of 4.0 mmHg (95% confidence interval: 1.8-6.2), in persons taking antihypertensive medication (n=57), but not in persons not using antihypertensive medication (n=31) (p for interaction: 0.02). Vanadium, iron and nickel contents of PM{sub 2.5} were significantly associated with systolic blood pressure and pulse pressure, among persons on antihypertensive medication. Similar results were found for indoor concentrations. Of the oxy-PAHs, chrysene-5,6-dione and benzo[a]pyrene-3,6-dione were significantly associated with increases in systolic blood pressure and pulse pressure. In elderly, pulse pressure was positively associated with acute increases in outdoor and indoor air pollution, among persons taking antihypertensive medication. These results might form a mechanistic pathway linking air pollution as a trigger of cardiovascular events.

  6. Generator powered electrically heated diesel particulate filter

    DOE Patents [OSTI]

    Gonze, Eugene V; Paratore, Jr., Michael J

    2014-03-18T23:59:59.000Z

    A control circuit for a vehicle powertrain includes a switch that selectivity interrupts current flow between a first terminal and a second terminal. A first power source provides power to the first terminal and a second power source provides power to the second terminal and to a heater of a heated diesel particulate filter (DPF). The switch is opened during a DPF regeneration cycle to prevent the first power source from being loaded by the heater while the heater is energized.

  7. NOx EMISSIONS PRODUCED WITH COMBUSTION OF POWDER RIVER BASIN COAL IN A UTILITY BOILER

    SciTech Connect (OSTI)

    John S. Nordin; Norman W. Merriam

    1997-04-01T23:59:59.000Z

    The objective of this report is to estimate the NOx emissions produced when Powder River Basin (PRB) coal is combusted in a utility boiler. The Clean Air Act regulations specify NOx limits of 0.45 lb/mm Btu (Phase I) and 0.40 lb/mm Btu (Phase II) for tangentially fired boilers, and 0.50 lb/mm 13tu (Phase II) and 0.46 lb/mm Btu (Phase II) for dry-bottom wall-fired boilers. The Clean Air Act regulations also specify other limits for other boiler types. Compliance for Phase I has been in effect since January 1, 1996. Compliance for Phase II goes into effect on January 1, 2000. Emission limits are expressed as equivalent NO{sub 2} even though NO (and sometimes N{sub 2}O) is the NOx species emitted during combustion. Regulatory agencies usually set even lower NOx emission limits in ozone nonattainment areas. In preparing this report, Western Research Institute (WRI) used published test results from utilities burning various coals, including PRB coal, using state-of-the art control technology for minimizing NOx emissions. Many utilities can meet Clean Air Act NOx emission limits using a combination of tight combustion control and low-NOx burners and by keeping furnaces clean (i.e., no slag buildup). In meeting these limits, some utilities also report problems such as increased carbon in their fly ash and excessive furnace tube corrosion. This report discusses utility experience. The theory of NOx emission formation during coal combustion as related to coal structure and how the coal is combusted is also discussed. From this understanding, projections are made for NOx emissions when processed PRB coal is combusted in a test similar to that done with other coals. As will be shown, there are a lot of conditions for achieving low NOx emissions, such as tight combustion control and frequent waterlancing of the furnace to avoid buildup of deposits.

  8. Effect of Biodiesel Blends on NOx Emissions | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't Your Destiny:RevisedAdvisory Board Contributionsreduction systemParticulate Filters |Biodiesel

  9. Selective NOx Recirculation for Stationary Lean-Burn Natural Gas Engines

    SciTech Connect (OSTI)

    Nigel N. Clark

    2006-12-31T23:59:59.000Z

    Nitric oxide (NO) and nitrogen dioxide (NO2) generated by internal combustion (IC) engines are implicated in adverse environmental and health effects. Even though lean-burn natural gas engines have traditionally emitted lower oxides of nitrogen (NOx) emissions compared to their diesel counterparts, natural gas engines are being further challenged to reduce NOx emissions to 0.1 g/bhp-hr. The Selective NOx Recirculation (SNR) approach for NOx reduction involves cooling the engine exhaust gas and then adsorbing the NOx from the exhaust stream, followed by the periodic desorption of NOx. By sending the desorbed NOx back into the intake and through the engine, a percentage of the NOx can be decomposed during the combustion process. SNR technology has the support of the Department of Energy (DOE), under the Advanced Reciprocating Engine Systems (ARES) program to reduce NOx emissions to under 0.1 g/bhp-hr from stationary natural gas engines by 2010. The NO decomposition phenomenon was studied using two Cummins L10G natural gas fueled spark-ignited (SI) engines in three experimental campaigns. It was observed that the air/fuel ratio ({lambda}), injected NO quantity, added exhaust gas recirculation (EGR) percentage, and engine operating points affected NOx decomposition rates within the engine. Chemical kinetic model predictions using the software package CHEMKIN were performed to relate the experimental data with established rate and equilibrium models. The model was used to predict NO decomposition during lean-burn, stoichiometric burn, and slightly rich-burn cases with added EGR. NOx decomposition rates were estimated from the model to be from 35 to 42% for the lean-burn cases and from 50 to 70% for the rich-burn cases. The modeling results provided an insight as to how to maximize NOx decomposition rates for the experimental engine. Results from this experiment along with chemical kinetic modeling solutions prompted the investigation of rich-burn operating conditions, with added EGR to prevent preignition. It was observed that the relative air/fuel ratio, injected NO quantity, added EGR fraction, and engine operating points affected the NO decomposition rates. While operating under these modified conditions, the highest NO decomposition rate of 92% was observed. In-cylinder pressure data gathered during the experiments showed minimum deviation from peak pressure as a result of NO injections into the engine. A NOx adsorption system, from Sorbent Technologies, Inc., was integrated with the Cummins engine, comprised a NOx adsorbent chamber, heat exchanger, demister, and a hot air blower. Data were gathered to show the possibility of NOx adsorption from the engine exhaust, and desorption of NOx from the sorbent material. In order to quantify the NOx adsorption/desorption characteristics of the sorbent material, a benchtop adsorption system was constructed. The temperature of this apparatus was controlled while data were gathered on the characteristics of the sorbent material for development of a system model. A simplified linear driving force model was developed to predict NOx adsorption into the sorbent material as cooled exhaust passed over fresh sorbent material. A mass heat transfer analysis was conducted to analyze the possibility of using hot exhaust gas for the desorption process. It was found in the adsorption studies, and through literature review, that NO adsorption was poor when the carrier gas was nitrogen, but that NO in the presence of oxygen was adsorbed at levels exceeding 1% by mass of the sorbent. From the three experimental campaigns, chemical kinetic modeling analysis, and the scaled benchtop NOx adsorption system, an overall SNR system model was developed. An economic analysis was completed, and showed that the system was impractical in cost for small engines, but that economies of scale favored the technology.

  10. MERCURY CONTROL WITH ADVANCED HYBRID PARTICULATE COLLECTOR

    SciTech Connect (OSTI)

    Ye Zhuang; Stanley J. Miller

    2005-05-01T23:59:59.000Z

    This project was awarded under U.S. Department of Energy (DOE) National Energy Technology Laboratory (NETL) Program Solicitation DE-PS26-00NT40769 and specifically addressed Technical Topical Area 4-Testing Novel and Less Mature Control Technologies on Actual Flue Gas at the Pilot Scale. The project team included the Energy & Environmental Research Center (EERC) as the main contractor; W.L. Gore & Associates, Inc., as a technical and financial partner; and the Big Stone Power Plant operated by Otter Tail Power Company, host for the field-testing portion of the research. Since 1995, DOE has supported development of a new concept in particulate control called the advanced hybrid particulate collector (AHPC). The AHPC has been licensed to W.L. Gore & Associates, Inc., and has been marketed as the Advanced Hybrid{trademark} filter by Gore. The Advanced Hybrid{trademark} filter combines the best features of electrostatic precipitators (ESPs) and baghouses in a unique configuration, providing major synergism between the two collection methods, both in the particulate collection step and in the transfer of dust to the hopper. The Advanced Hybrid{trademark} filter provides ultrahigh collection efficiency, overcoming the problem of excessive fine-particle emissions with conventional ESPs, and it solves the problem of reentrainment and re-collection of dust in conventional baghouses. The Advanced Hybrid{trademark} filter also appears to have unique advantages for mercury control over baghouses or ESPs as an excellent gas--solid contactor. The objective of the project was to demonstrate 90% total mercury control in the Advanced Hybrid{trademark} filter at a lower cost than current mercury control estimates. The approach included bench-scale batch tests, larger-scale pilot testing with real flue gas on a coal-fired combustion system, and field demonstration at the 2.5-MW (9000-acfm) scale at a utility power plant to prove scale-up and demonstrate longer-term mercury control. An additional task was included in this project to evaluate mercury oxidation upstream of a dry scrubber by using mercury oxidants. This project demonstrated at the pilot-scale level a technology that provides a cost-effective technique to control mercury and, at the same time, greatly enhances fine particulate collection efficiency. The technology can be used to retrofit systems currently employing inefficient ESP technology as well as for new construction, thereby providing a solution for improved fine particulate control combined with effective mercury control for a large segment of the U.S. utility industry as well as other industries.

  11. Metal/metal oxide doped oxide catalysts having high deNOx selectivity for lean NOx exhaust aftertreatment systems

    DOE Patents [OSTI]

    Park, Paul W.

    2004-03-16T23:59:59.000Z

    A lean NOx catalyst and method of preparing the same is disclosed. The lean NOx catalyst includes a ceramic substrate, an oxide support material, preferably .gamma.-alumina, deposited on the substrate and a metal promoter or dopant introduced into the oxide support material. The metal promoters or dopants are selected from the group consisting of indium, gallium, tin, silver, germanium, gold, nickel, cobalt, copper, iron, manganese, molybdenum, chromium, cerium, vanadium, oxides thereof, and combinations thereof. The .gamma.-alumina preferably has a pore volume of from about 0.5 to about 2.0 cc/g; a surface area of between about 80 to 350 m.sup.2 /g; an average pore size diameter of between about 3 to 30 nm; and an impurity level of less than or equal to 0.2 weight percent. In a preferred embodiment the .gamma.-alumina is prepared by a sol-gel method, with the metal doping of the .gamma.-alumina preferably accomplished using an incipient wetness impregnation technique.

  12. Atmospheric particulate emissions from dry abrasive blasting using coal slag

    SciTech Connect (OSTI)

    Bhaskar Kura; Kalpalatha Kambham; Sivaramakrishnan Sangameswaran; Sandhya Potana [University of New Orleans, New Orleans, LA (United States). Department of Civil and Environmental Engineering

    2006-08-15T23:59:59.000Z

    Coal slag is one of the widely used abrasives in dry abrasive blasting. Atmospheric emissions from this process include particulate matter (PM) and heavy metals, such as chromium, lead, manganese, nickel. Quantities and characteristics of PM emissions depend on abrasive characteristics and process parameters. Emission factors are key inputs to estimate emissions. Experiments were conducted to study the effect of blast pressure, abrasive feed rate, and initial surface contamination on total PM (TPM) emission factors for coal slag. Rusted and painted mild steel surfaces were used as base plates. Blasting was carried out in an enclosed chamber, and PM was collected from an exhaust duct using U.S. Environment Protection Agency source sampling methods for stationary sources. Results showed that there is significant effect of blast pressure, feed rate, and surface contamination on TPM emissions. Mathematical equations were developed to estimate emission factors in terms of mass of emissions per unit mass of abrasive used, as well as mass of emissions per unit of surface area cleaned. These equations will help industries in estimating PM emissions based on blast pressure and abrasive feed rate. In addition, emissions can be reduced by choosing optimum operating conditions. 40 refs., 5 figs., 2 tabs.

  13. Method of forming particulate materials for thin-film solar cells

    DOE Patents [OSTI]

    Eberspacher, Chris; Pauls, Karen Lea

    2004-11-23T23:59:59.000Z

    A method for preparing particulate materials useful in fabricating thin-film solar cells is disclosed. Particulate materials is prepared by the method include for example materials comprising copper and indium and/or gallium in the form of single-phase, mixed-metal oxide particulates; multi-phase, mixed-metal particulates comprising a metal oxide; and multinary metal particulates.

  14. Diesel particulate filter regeneration via resistive surface heating

    DOE Patents [OSTI]

    Gonze, Eugene V; Ament, Frank

    2013-10-08T23:59:59.000Z

    An exhaust system that processes exhaust generated by an engine is provided. The system includes: a particulate filter (PF) that filters particulates from the exhaust wherein an upstream end of the PF receives exhaust from the engine; and a grid of electrically resistive material that is applied to an exterior upstream surface of the PF and that selectively heats exhaust passing through the grid to initiate combustion of particulates within the PF.

  15. The integration of low NOx control technologies at the Southern Energy, Inc. Birchwood Power Facility

    SciTech Connect (OSTI)

    Lauber, J.A. [Southern Energy, Inc. (United States); Cohen, M.B.; Donais, R.E. [ABB Combustion Engineering, Inc. (United States)

    1997-12-31T23:59:59.000Z

    The Southern Energy, Inc. (SEI) Birchwood Power Facility, a cogeneration unit, represents the first application worldwide of the TFS 2000{trademark} firing system and selective catalytic reduction (SCR). The installation of these state-of-the-art NOx control technologies was necessary to meet strict Commonwealth of Virginia environmental regulations requiring a 0.10 lbs/10{sup 6} Btu (0.043 g/MJ) NOx emission rate based upon a 30-day rolling average. The plant successfully completed all performance and emission testing on September 24, 1996. Commercial operation began November 14, 1996. Stack NOx emission rates are consistently maintained below 0.10 lbs/10{sup 6} Btu. The paper describes the integration of both in-furnace and post-combustion NOx control technologies into the overall boiler design. Operational data depicting boiler outlet NOx, stack NOx and loss on ignition (LOI) are presented across the design load range from 32% to 100% boiler output. The description, arrangement, design parameters and operation of the NOx control equipment are discussed. Novel design features include a split economizer, an air heater suitable for ammonia applications, Dynamic{trademark} classifiers, and a multi-zone secondary air flow control system utilized for the TFS 2000{trademark} firing system.

  16. PARAMETRIC STUDY OF SUBMICRON PARTICULATES FROM PULVERIZED COAL COMBUSTION

    E-Print Network [OSTI]

    Pennucci, J.

    2014-01-01T23:59:59.000Z

    Chemistry of Coal during Combustion and the Emissions fromParticulates Generated by Combustion of Pulverized Coal,Particles from Coal Combustion, presented at the Eighteenth

  17. air particulate samples: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2. Measurements of fine quantitative information on fine airborne particulate-size and chemically resolved mass concentration from composition, urban, organic, mass...

  18. Electrically heated particulate filter regeneration using hydrocarbon adsorbents

    DOE Patents [OSTI]

    Gonze, Eugene V [Pinckney, MI

    2011-02-01T23:59:59.000Z

    An exhaust system that processes exhaust generated by an engine is provided. The system generally includes a particulate filter (PF) that filters particulates from the exhaust wherein an upstream end of the PF receives exhaust from the engine. A grid of electrically resistive material selectively heats exhaust passing through the upstream end to initiate combustion of particulates within the PF. A hydrocarbon adsorbent coating applied to the PF releases hydrocarbons into the exhaust to increase a temperature of the combustion of the particulates within the PF.

  19. Particulate Produced from Advanced Combustion Operation in a...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Produced from Advanced Combustion Operation in a Compression Ignition Engine Particulate Produced from Advanced Combustion Operation in a Compression Ignition Engine Determine...

  20. Development of Advanced Diesel Particulate Filtration (DPF) Systems...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    (ANLCorningCaterpillar CRADA) Development of Advanced Diesel Particulate Filtration (DPF) Systems (ANLCorningCaterpillar CRADA) ace22lee.pdf More Documents & Publications...

  1. Diesel Particulate Oxidation Model: Combined Effects of Fixed...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Oxidation Model: Combined Effects of Fixed & Volatile Carbon Diesel Particulate Oxidation Model: Combined Effects of Fixed & Volatile Carbon Poster presented at the 16th Directions...

  2. Improvement and Simplification of Diesel Particulate Filter System...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Improvement and Simplification of Diesel Particulate Filter System using a Ceria-Based Fuel-Borne Catalyst in Serial Applications Improvement and Simplification of Diesel...

  3. Development of Advanced Diesel Particulate Filtration (DPF) Systems

    Broader source: Energy.gov (indexed) [DOE]

    heat release in DPF regeneration. - Derive equations for the oxidation rate of diesel particulates - Measure the amount of heat release from the oxidation Characterize...

  4. Diesel Particulate Filter: A Success for Faurecia Exhaust Systems

    Broader source: Energy.gov (indexed) [DOE]

    DIESEL PARTICULATE FILTER: A SUCCESS FOR FAURECIA EXHAUST SYSTEMS Robert Parmann, Emmanuel Jean, Eric Quemere Faurecia Exhaust Systems DPF with Fuel Borne Catalyst DPF Experience...

  5. airborne particulate threat: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    particulate pollution in Beijing. Overall, coal burning and the traffic exhausts, plus mineral aerosol and it could provide the basic information in controlling the air-borne...

  6. airborne fungi particulate: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    particulate pollution in Beijing. Overall, coal burning and the traffic exhausts, plus mineral aerosol and it could provide the basic information in controlling the air-borne...

  7. airborne particulates european: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    particulate pollution in Beijing. Overall, coal burning and the traffic exhausts, plus mineral aerosol and it could provide the basic information in controlling the air-borne...

  8. Characterization of Pre-Commercial Gasoline Engine Particulates...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    analysis methods were used to examine particulates from single cylinder test engines running on gasoline and ethanol blends. deer12zelenyuk.pdf More Documents & Publications...

  9. Development of Advanced Diesel Particulate Filtration (DPF) Systems

    Broader source: Energy.gov (indexed) [DOE]

    Filtration (DPF) Systems Particulate Filtration (DPF) Systems (ANLCorningCaterpillar CRADA) February 26, 2008 DOE Merit Review PI: Kyeong Lee (Postdoc: Joe Song) Transportation...

  10. Requirements-Driven Diesel Catalyzed Particulate Trap Design...

    Broader source: Energy.gov (indexed) [DOE]

    Requirements Driven Diesel Catalyzed Particulate Trap (DCPT) Design and Optimization Tom Harris, Donna McConnell and Danan Dou Delphi Catalyst Tulsa, Oklahoma 2 Euro 45 Light Duty...

  11. Effect of Biodiesel Blends on Diesel Particulate Filter Performance

    SciTech Connect (OSTI)

    Williams, A.; McCormick, R. L.; Hayes, R. R.; Ireland, J.; Fang, H. L.

    2006-11-01T23:59:59.000Z

    Presents results of tests of ultra-low sulfur diesel blended with soy-biodiesel at 5 percent using a Cummins ISB engine with a diesel particulate filter.

  12. Partitioning of Volatile Organics in Diesel Particulate and Exhaust...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    in Diesel Particulate and Exhaust Evaluation of how sampling details affect the measurement of volatile organic compounds in diesel exhaust deer08strzelec.pdf More Documents...

  13. Final Report: Particulate Emissions Testing, Unit 1, Potomac...

    Broader source: Energy.gov (indexed) [DOE]

    were completed while Unit 1 was operating at 90% of full load (84MW) or greater. Final Report: Particulate Emissions Testing, Unit 1, Potomac River Generating Station, Alexandria,...

  14. Particulate Produced from Advanced Combustion Operation in a...

    Broader source: Energy.gov (indexed) [DOE]

    Produced From Advanced Combustion Operation in a Compression Ignition Engine P-1 Particulate Produced From Advanced Combustion Operation in a Compression Ignition Engine P-1...

  15. Low NOx nozzle tip for a pulverized solid fuel furnace

    DOE Patents [OSTI]

    Donais, Richard E; Hellewell, Todd D; Lewis, Robert D; Richards, Galen H; Towle, David P

    2014-04-22T23:59:59.000Z

    A nozzle tip [100] for a pulverized solid fuel pipe nozzle [200] of a pulverized solid fuel-fired furnace includes: a primary air shroud [120] having an inlet [102] and an outlet [104], wherein the inlet [102] receives a fuel flow [230]; and a flow splitter [180] disposed within the primary air shroud [120], wherein the flow splitter disperses particles in the fuel flow [230] to the outlet [104] to provide a fuel flow jet which reduces NOx in the pulverized solid fuel-fired furnace. In alternative embodiments, the flow splitter [180] may be wedge shaped and extend partially or entirely across the outlet [104]. In another alternative embodiment, flow splitter [180] may be moved forward toward the inlet [102] to create a recessed design.

  16. NOx Control Options and Integration for US Coal Fired Boilers

    SciTech Connect (OSTI)

    Mike Bockelie; Kevin Davis; Temi Linjewile; Connie Senior; Eric Eddings; Kevin Whitty; Larry Baxter; Calvin Bartholomew; William Hecker; Stan Harding; Robert Hurt

    2003-12-31T23:59:59.000Z

    This is the fourteenth Quarterly Technical Report for DOE Cooperative Agreement No: DEFC26-00NT40753. The goal of the project is to develop cost effective analysis tools and techniques for demonstrating and evaluating low NOx control strategies and their possible impact on boiler performance for boilers firing US coals. The Electric Power Research Institute (EPRI) is providing co-funding for this program. Using the initial CFD baseline modeling of the Gavin Station and the plant corrosion maps, six boiler locations for the corrosion probes were identified and access ports have been installed. Preliminary corrosion data obtained appear consistent and believable. In situ, spectroscopic experiments at BYU reported in part last quarter were completed. New reactor tubes have been made for BYU's CCR that allow for testing smaller amounts of catalyst and thus increasing space velocity; monolith catalysts have been cut and a small reactor that can accommodate these pieces for testing is in its final stages of construction. A poisoning study on Ca-poisoned catalysts was begun this quarter. A possible site for a biomass co-firing test of the slipstream reactor was visited this quarter. The slipstream reactor at Rockport required repair and refurbishment, and will be re-started in the next quarter. This report describes the final results of an experimental project at Brown University on the fundamentals of ammonia / fly ash interactions with relevance to the operation of advanced NOx control technologies such as selective catalytic reduction. The Brown task focused on the measurement of ammonia adsorption isotherms on commercial fly ash samples subjected to a variety of treatments and on the chemistry of dry and semi-dry ammonia removal processes.

  17. METHANE de-NOX for Utility PC Boilers

    SciTech Connect (OSTI)

    Bruce Bryan; Joseph Rabovitser Serguei Nester; Stan Wohadlo

    2004-06-30T23:59:59.000Z

    The primary focus for the project during the quarter was shakedown testing of the large-scale coal preheater prototype in the CBTF with non-caking PRB coal. Additional pilot-scale tests were conducted in the PSCF in support of developing a preheating system design suitable for use with caking coals. Thirty-two additional pilot tests were conducted during the quarter with caking coal. These tests further evaluated the use of the air-bleed and indirect air-cooled liner designs to reduce or eliminate combustor plugging with caking coal. The air-bleed configurations tested used air injection holes perpendicular to the liner's longitudinal axis with the number, size and air flow though the air-bleed holes varied to determine the effect on combustor plugging. The indirect cooling configurations tested included a stainless steel liner with spiral fins in the annular space between the liner and the combustor wall, and a silicon carbide liner without fins. Continuous pilot operation was maintained for up to 30 minutes at a coal feed rate of 50 lb/h with the air-bleed liner. The best result achieved was for the stainless steel indirect air-cooled liner with 20 minutes of continuous operation at 126 lb/h of coal followed by an additional 20 minutes at 150 lb/h. The NOx results from these continue to indicate that even greater NOx reduction is possible with caking coal than with the PRB coal tested. The installation of the large-scale prototype coal preheater for PRB testing in the CBTF was completed and shakedown testing with natural gas and PRB coal started during the quarter. Stable operation of the coal system, combustor and burner were achieved at coal feed rates up to 6000 lb/h (50 MMBtu/h).

  18. METHANE DE-NOX FOR UTILITY PC BOILERS

    SciTech Connect (OSTI)

    Bruce Bryan; Joseph Rabovitser; Serguei Nester; Stan Wohadlo

    2004-02-06T23:59:59.000Z

    The primary focus for the project continues to be on developing a PC PREHEAT system design suitable for use with caking coals and readying the 100 MMBtu/h CBTF for testing with noncaking PRB coal. During the current quarter, twenty-two pilot tests were conducted with Central Appalachian (CA) caking coal. The objective for these tests was to achieve continuous operation of the pilot system at its design coal feed rate of 156 lb/h, without plugging or agglomeration in the combustor. One combustor air distribution method tested achieved continuous operation at 110 lb/hr, and inspection of the combustor afterward indicated that this method has potential to solve the caking problem. The NOx results from the pilot caking coal runs indicate that even greater NOx reduction is possible with CA coal than with the PRB coal tested, to levels near 100 ppmv or lower at 4-6% exit oxygen. It was therefore decided to conduct additional pilot tests of the air distribution method to determine how to incorporate this into a workable CA combustor design. Based on current weather and manpower restrictions at the site, this pilot testing is expected to be started in February. The design for the 100 MMBtu/h unit for PRB testing in the CBTF was completed and fabrication and installation started during the quarter. While significant progress has been made in the installation of the unit, weather and combustor fabrication delays are expected to move the start of large-scale testing with PRB coal into February, which will push the project completion date beyond the current 3/30/04 end date. GTI is in the process of developing a revised project schedule and estimated cost to complete.

  19. Procedure to Calculate NOx Reductions Using the Emissions & Generation Resource Integrated Database (E-Grid) Spreadsheet

    E-Print Network [OSTI]

    Haberl, J. S.; Im, P.; Culp, C.; Yazdani, B.; Fitzpatrick, T.; Verdict, M.; Turner, W. D.

    2003-01-01T23:59:59.000Z

    and Renewable Energy projects (EE/RE) implemented in each Power Control Area (PCA) in the ERCOT region E-GRID is a comprehensive database of environmental attributes of electric power systems. E-GRID is based on available plant-specific data for all U... in Figure 9 that three counties (i.e., Ward, McLennan, and Mitchell) rise significantly in NOx reductions during peak days when compared to annual NOx reductions (Figure 5). Table 1. EPA's EGRID table: County-wide NOx Reductions in pounds per MWh for EE/RE...

  20. Neutron Imaging of Diesel Particulate Filters

    SciTech Connect (OSTI)

    Strzelec, Andrea [ORNL; Bilheux, Hassina Z [ORNL; FINNEY, Charles E A [ORNL; Daw, C Stuart [ORNL; Foster, Prof. Dave [University of Wisconsin; Rutland, Prof. Christopher J. [University of Wisconsin; Schillinger, Burkhard [FRM-II, Technische Universitaet Munchen; Schulz, Michael [FRM-II, Technische Universitaet Munchen

    2009-01-01T23:59:59.000Z

    This article presents nondestructive neutron computed tomography (nCT) measurements of Diesel Particulate Filters (DPFs) as a method to measure ash and soot loading in the filters. Uncatalyzed and unwashcoated 200cpsi cordierite DPFs exposed to 100% biodiesel (B100) exhaust and conventional ultra low sulfur 2007 certification diesel (ULSD) exhaust at one speed-load point (1500rpm, 2.6bar BMEP) are compared to a brand new (never exposed) filter. Precise structural information about the substrate as well as an attempt to quantify soot and ash loading in the channel of the DPF illustrates the potential strength of the neutron imaging technique.

  1. Ceramic Particulate Filters | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't Your Destiny: Theof EnergyAdministration-Desertof Energy PresentationCeramic Particulate

  2. Trends in Particulate Nanostructure | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn'tOriginEducationVideoStrategic|IndustrialCenter GetsEnergySpecification: RevisionParticulate

  3. Modeling and interpreting the observed effects of ash on diesel particulate filter performance and regeneration

    E-Print Network [OSTI]

    Wang, Yujun, Ph. D. Massachusetts Institute of Technology

    2014-01-01T23:59:59.000Z

    Diesel particulate filters (DPF) are devices that physically capture diesel particulates to prevent their release to the atmosphere. Diesel particulate filters have seen widespread use in on- and off-road applications as ...

  4. Dark Matters

    ScienceCinema (OSTI)

    Joseph Silk

    2010-01-08T23:59:59.000Z

    One of the greatest mysteries in the cosmos is that it is mostly dark.  Astronomers and particle physicists today are seeking to unravel the nature of this mysterious, but pervasive dark matter which has profoundly influenced the formation of structure in the universe.  I will describe the complex interplay between galaxy formation and dark matter detectability and review recent attempts to measure particle dark matter by direct and indirect means.

  5. Climate Co-benefits of Tighter SO2 and NOx Regulations in China

    E-Print Network [OSTI]

    Nam, Kyung-Min

    2012-10-01T23:59:59.000Z

    Air pollution has been recognized as a significant problem in China. In its Twelfth Five Year Plan (FYP), China proposes to reduce SO2 and NOx emissions significantly, and here we investigate the cost of achieving those ...

  6. A design strategy applied to sulfur resistant lean NOx̳ automotive catalysts

    E-Print Network [OSTI]

    Tang, Hairong

    2005-01-01T23:59:59.000Z

    Catalyst poisoning due to sulfur compounds derived from fuel sulfur presents a major challenge, intractable thus far, to development of many advanced technologies for automotive catalysts such as the lean NOx, trap. Under ...

  7. APBF-DEC NOx Adsorber/DPF Project: SUV/Pick-Up Platform

    Broader source: Energy.gov (indexed) [DOE]

    Status Principal Investigators: Cynthia Webb Phillip Weber DEER August 25, 2003 APBF-DEC NOx AdsorberDPF Project: SUVPick-Up Platform Program Goals Objectives Light-Duty SUV ...

  8. Excellent Sulfur Resistance of Pt/BaO/CeO2 Lean NOx Trap Catalysts...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and CHF Peden.2008."Excellent Sulfur Resistance of PtBaOCeO2 Lean NOx Trap Catalysts."Applied Catalysis. B, Environmental 84(3-4):545-551. doi:10.1016j.apcatb.2008.05.009...

  9. Diesel NOx-PM Reduction with Fuel Economy Increase by IMET-OBC...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Increase by IMET-OBC-DPF + Hydrated-EGR System for Retrofit of In-Use Trucks Diesel NOx-PM Reduction with Fuel Economy Increase by IMET-OBC-DPF + Hydrated-EGR System...

  10. Consequences of propene and propane on plasma remediation of NOx Rajesh Doraia)

    E-Print Network [OSTI]

    Kushner, Mark

    Consequences of propene and propane on plasma remediation of NOx Rajesh Doraia) Department exhausts with hydrocarbons propane (C3H8) and propene (C3H6) has been investigated. In general

  11. Time and location differentiated NOX control in competitive electricity markets using cap-and-trade mechanisms

    E-Print Network [OSTI]

    Martin, Katherine C.

    2007-01-01T23:59:59.000Z

    Due to variations in weather and atmospheric chemistry, the timing and location of nitrogen oxide (NOX) reductions determine their effectiveness in reducing ground-level ozone, which adversely impacts human health. Electric ...

  12. Demonstration of a Low-NOx Heavy-Duty Natural Gas Engine

    SciTech Connect (OSTI)

    Not Available

    2004-02-01T23:59:59.000Z

    Results of a Next Generation Natural Gas Vehicle engine research project: A Caterpillar C-12 natural gas engine with Clean Air Power Dual-Fuel technology and exhaust gas recirculation demonstrated low NOx and PM emissions.

  13. Engine and Reactor Evaluations of HC-SCR for Diesel NOx Reduction

    Broader source: Energy.gov (indexed) [DOE]

    and Reactor Evaluations of HC-SCR for Diesel NOx Reduction Richard Blint, Michael B. Viola and Steven J. Schmieg General Motors R&D Center Warren, MI 48090-9055 DEER 2009 Tuesday,...

  14. Two-Stage Plasma-Catalysis for Diesel NOx Emission Control. ...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    producing nitrogen. Citation: Hoard J, and RG Tonkyn.2003."Two-Stage Plasma-Catalysis for Diesel NOx Emission Control."Journal of Advanced Oxidation Technologies 6(2):158-165....

  15. Non-thermal plasma-assisted NOx reduction over Na-Y zeolites...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    investigated in the non-thermal plasma assisted NOx reduction reaction using a simulated diesel engine exhaust gas mixture. The acid sites were formed by NH4+ ion exchange and...

  16. Water-induced morphology changes in BaO/?-Al2O3 NOx storage...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    materials: an FTIR, TPD, and time-resolved synchrotron XRD Water-induced morphology changes in BaO?-Al2O3 NOx storage materials: an FTIR, TPD, and time-resolved synchrotron...

  17. Calculation of NOx Emissions Reductions From Energy Efficient Residential Building Construction in Texas

    E-Print Network [OSTI]

    Haberl, J. S.; Culp, C.; Gilman, D.; Yazdani, B.; Fitzpatrick, T.; Muns, S.

    2006-05-23T23:59:59.000Z

    . These areas face severe sanctions if attainment is not reached by 2007. This paper provides an overview of the procedures that have been developed and used to calculate the electricity savings and NOx reductions from code-compliant residential construction...

  18. Reduction of NOx Emissions in Alamo Area Council of Government Projects

    E-Print Network [OSTI]

    Haberl, J. S.; Zhu, Y.; Im, P.

    2004-01-01T23:59:59.000Z

    This reports summarizes the electricity, natural gas and NOx emissions reductions from retrofit measures reported as part of the AACOG emissions reduction effort. The electricity and natural gas savings were collected by the Brooks Energy...

  19. Particulate optical scattering coefficients along an Atlantic Meridional Transect

    E-Print Network [OSTI]

    Boss, Emmanuel S.

    Particulate optical scattering coefficients along an Atlantic Meridional Transect G. Dall'Olmo,1, E, USA gdal@pml.ac.uk Abstract: The particulate optical backscattering coefficient (bbp) is a fundamental optical property that allows monitoring of marine suspended particles both in situ and from space

  20. Process for off-gas particulate removal and apparatus therefor

    DOE Patents [OSTI]

    Carl, D.E.

    1997-10-21T23:59:59.000Z

    In the event of a breach in the off-gas line of a melter operation requiring closure of the line, a secondary vessel vent line is provided with a particulate collector utilizing atomization for removal of large particulates from the off-gas. The collector receives the gas containing particulates and directs a portion of the gas through outer and inner annular channels. The collector further receives a fluid, such as water, which is directed through the outer channel together with a second portion of the particulate-laden gas. The outer and inner channels have respective ring-like termination apertures concentrically disposed adjacent one another on the outer edge of the downstream side of the particulate collector. Each of the outer and inner channels curves outwardly away from the collector`s centerline in proceeding toward the downstream side of the collector. Gas flow in the outer channel maintains the fluid on the channel`s wall in the form of a ``wavy film,`` while the gas stream from the inner channel shears the fluid film as it exits the outer channel in reducing the fluid to small droplets. Droplets formed by the collector capture particulates in the gas stream by one of three mechanisms: impaction, interception or Brownian diffusion in removing the particulates. The particulate-laden droplets are removed from the fluid stream by a vessel vent condenser or mist eliminator. 4 figs.

  1. Process for off-gas particulate removal and apparatus therefor

    DOE Patents [OSTI]

    Carl, Daniel E. (Orchard Park, NY)

    1997-01-01T23:59:59.000Z

    In the event of a breach in the off-gas line of a melter operation requiring closure of the line, a secondary vessel vent line is provided with a particulate collector utilizing atomization for removal of large particulates from the off-gas. The collector receives the gas containing particulates and directs a portion of the gas through outer and inner annular channels. The collector further receives a fluid, such as water, which is directed through the outer channel together with a second portion of the particulate-laden gas. The outer and inner channels have respective ring-like termination apertures concentrically disposed adjacent one another on the outer edge of the downstream side of the particulate collector. Each of the outer and inner channels curves outwardly away from the collector's centerline in proceeding toward the downstream side of the collector. Gasflow in the outer channel maintains the fluid on the channel's wall in the form of a "wavy film," while the gas stream from the inner channel shears the fluid film as it exits the outer channel in reducing the fluid to small droplets. Droplets formed by the collector capture particulates in the gas stream by one of three mechanisms: impaction, interception or Brownian diffusion in removing the particulates. The particulate-laden droplets are removed from the fluid stream by a vessel vent condenser or mist eliminator.

  2. NOx reduction with the use of feedlot biomass as a reburn fuel

    E-Print Network [OSTI]

    Goughnour, Paul Gordon

    2009-05-15T23:59:59.000Z

    ash because the residence time for char burnout is reduced. [16] 9 Another relatively new NOx reduction technique, that only recently became feasible, uses oxygen and re-circulated exhaust gas as the oxidizer in the combustion zone. Enough exhaust... gas is re-circulated to achieve a near 20% oxygen level prior to combustion. This concentration of oxygen is required to maintain the temperature at an acceptable level. This type of combustion scheme has been reported to reduce NOx levels by 75...

  3. Analysis of characteristic of microwave regeneration for diesel particulate filter

    SciTech Connect (OSTI)

    Ning Zhi; Zhang Guanglong; Lu Yong; Liu Junmin; Gao Xiyan; Liang Iunhui; Chen Jiahua [Dalian Univ. of Technology (China)

    1995-12-31T23:59:59.000Z

    The mathematical model for the microwave regeneration of diesel particulate filter is proposed according to the characteristic of microwave regeneration process. The model is used to calculate the temperature field, distribution of particulate and density field of oxygen in the filter during the process of regeneration with typical ceramic foam particulate filter data. The parametric study demonstrates how some of the main parameters, such as microwave attenuation constant of the filter, filter particulate loading, the power and distribution of microwave energy and so on, affect the efficiency of regeneration, the maximum filter temperature and regeneration duration. The results show that it is possible to regenerate the diesel particulate filters in certain conditions by using microwave energy. This paper can give one a whole understanding to several main factors that have effects on the process of microwave regeneration and provide a theoretical basis for the optimal design of the microwave regeneration system.

  4. METHANE de-NOX for Utility PC Boilers

    SciTech Connect (OSTI)

    Bruce Bryan; Joseph Rabovitser; Serguei Nester; Stan Wohadlo

    2003-09-30T23:59:59.000Z

    During the current quarter, pilot-scale testing with the modified air nozzle version of the PC burner was completed with PRB coal at the Riley Power Inc. (RPI) test facility. A total of 8 different burner configurations were tested utilizing various burner air nozzle arrangements in place of the burner air channels. It was found that with the arrangements tested, a stable flame could not be maintained at coal feed rates above 100 lb/h. While it is felt that the air nozzle approach can ultimately be used effectively, in the interest of holding to the current project schedule it was decided to proceed with the balance of the project using the air channel design. The pilot-scale PC burner was therefore restored to the air-channel configuration and benchmark testing with PRB coal to confirmed previous operating results. A series of tests was then conducted with PRB and West Virginia caking coal to evaluate modifications to the gas combustor configuration and operation for improved performance with caking coal. Continuous operation was achieved with caking coal up to 50 lb/h vs. the full load target of 150 lb/h. Impingement and deposition of partially devolatilized coal occurred at various points within the combustor when the caking coal feed was increased above 50 lb/h. The 100 MMBtu/h commercial-scale prototype design was continued with coal burner design input from both RPI and VTI. Based on typical burner installation layout considerations, it was decided that the preheat combustor should be oriented horizontally on the axial centerline of the coal burner. Accordingly, the pilot gas combustor was changed to this orientation so that the pilot results with caking coal will be directly applicable to the preferred 100 MMBtu design. Testing with caking coal in the horizontal pilot combustor achieved feed rates up to 126 lb/h, although some deposition and LOI issues remain. Several promising approaches to further improve operation with caking coal were identified. NOx results with caking coal are promising, with NOx as low as 150 ppmv at exit oxygen levels of 4% and higher. The 100 MMBtu/h commercial-scale prototype design is nearing completion. Design of the caking coal version of the unit continues with additional pilot testing in support of this design expected. GTI and RPI are expediting the fabrication of the 100 MMBtu/h PRB unit in order to start testing in early- to mid-December. Inspection and repair of the 100 MMBtu/h Coal Burner Test Facility (CBTF) is nearing completion. As of mid-September, this activity was 95% complete.

  5. Laser induced thermophoresis and particulate deposition efficiency

    SciTech Connect (OSTI)

    Cipolla, J.; Morse, T.F.; Wang, C.Y.

    1983-07-01T23:59:59.000Z

    The interaction of laser radiation and an absorbing aerosol in a tube flow has been considered. The aerosol is produced by external heating of reactants as in the MCVD (Modified Chemical Vapor Deposition) process to produce submicron size particles in the manufacture of optical fiber preforms. These are subsequently deposited by thermophoretic forces on the inner wall of the tube as they are convected by a Poiseuille velocity profile. Axial laser radiation in the tube interacts with the absorbing particles, and the laser heating of the gas induces additional thermophoretic forces that markedly increase the efficiency of particulate deposition. A particle concentration dependent absorption coefficient that appears in the energy equation couples the energy equation to the equation of particle conservation, so that a non-linear set of coupled partial integrodifferential equations must be solved. Numerical solutions for aerosol particle trajectories, and thus deposition efficiencies, have been obtained. It is shown that laser enhanced thermophoresis markedly improves the deposition efficiency.

  6. Exhaust-gas recirculation for retrofit NOx control on natural gas engines. Topical report, January-April 1988

    SciTech Connect (OSTI)

    Urban, C.M.

    1989-01-01T23:59:59.000Z

    Data on exhaust-gas recirculation obtained from Tenneco Gas Transportation Company were reviewed and analyzed, and a basic EGR system design and cost estimate were developed. EGR can provide practical NOx reductions of up to 50% in 2-cycle natural gas engines. The amount of NO reduction achievable is dependent on the initial baseline NOx emissions of the engine. On the basis of NOx reduction per unit of costs, EGR was found to be more cost effective than selective catalytic reduction. EGR is considered to provide a practical retrofit NOx control method in applications where the level of NOx control achievable with EGR meet regulatory requirements. One specific application is emissions offset to enable installation of additional engine horsepower. Also, EGR could become the primary NOx control method for any regulation in which costs are a major consideration.

  7. NOx Control Options and Integration for US Coal Fired Boilers

    SciTech Connect (OSTI)

    Mike Bockelie; Kevin Davis; Connie Senior Darren Shino; Dave Swenson; Larry Baxter; Calvin Bartholomew; William Hecker; Stan Harding

    2004-09-30T23:59:59.000Z

    This is the seventeenth Quarterly Technical Report for DOE Cooperative Agreement No: DEFC26-00NT40753. The goal of the project is to develop cost effective analysis tools and techniques for demonstrating and evaluating low NOx control strategies and their possible impact on boiler performance for boilers firing US coals. The Electric Power Research Institute (EPRI) is providing co-funding for this program. The SCR slipstream reactor was assembled and installed at Plant Gadsden this quarter. Safety equipment for ammonia had not been installed at the end of the quarter, but will be installed at the beginning of next quarter. The reactor will be started up next quarter. Four ECN corrosion probes were reinstalled at Gavin and collected corrosion data for approximately one month. Two additional probes were installed and removed after about 30 hours for future profilometry analysis. Preliminary analysis of the ECN probes, the KEMA coupons and the CFD modeling results all agree with the ultrasonic tube test measurements gathered by AEP personnel.

  8. NOx Control Options and Integration for US Coal Fired Boilers

    SciTech Connect (OSTI)

    Mike Bockelie; Kevin Davis; Connie Senior; Darren Shino; Dave Swenson; Larry Baxter; Calvin Bartholomew; William Hecker; Stan Harding

    2004-12-31T23:59:59.000Z

    This is the eighteenth Quarterly Technical Report for DOE Cooperative Agreement No: DEFC26-00NT40753. The goal of the project is to develop cost effective analysis tools and techniques for demonstrating and evaluating low NOx control strategies and their possible impact on boiler performance for boilers firing US coals. The Electric Power Research Institute (EPRI) is providing co-funding for this program. Safety equipment for ammonia for the SCR slipstream reactor at Plant Gadsden was installed. The slipstream reactor was started and operated for about 1400 hours during the last performance period. Laboratory analysis of exposed catalyst and investigations of the sulfation of fresh catalyst continued at BYU. Thicker end-caps for the ECN probes were designed and fabricated to prevent the warpage and failure that occurred at Gavin with the previous design. A refurbished ECN probe was successfully tested at the University of Utah combustion laboratory. Improvements were implemented to the software that controls the flow of cooling air to the ECN probes.

  9. Release of Ammonium and Mercury from NOx Controlled Fly Ash

    SciTech Connect (OSTI)

    Schroeder, K.T.; Cardone, C.R.; Kim, A.G

    2007-07-01T23:59:59.000Z

    One of the goals of the Department of Energy is to increase the reuse of coal utilization byproducts (CUB) to 50% by 2010. This will require both developing new markets and maintaining traditional ones such as the use of fly ash in concrete. However, the addition of pollution control devices can introduce side-effects that affect the marketability of the CUB. Such can be the case when NOx control is achieved using selective catalytic or non-catalytic reduction (SCR or SNCR). Depending on site-specific details, the ammonia slip can cause elevated levels of NH3 in the fly ash. Disposal of ammoniated fly ash can present environmental concerns related to the amount of ammonia that might be released, the amount of water that might become contaminated, and the extent to which metals might be mobilized by the presence of the ammonia. Ammonia retained in fly ash appears to be present as either an ammonium salt or as a chemisorbed species. Mercury in the leachates correlated to neither the amount of leachable ammonium nor to the total amount of Hg in the ash. The strongest correlation was between the decreases in the amount of Hg leached with increased LOI.

  10. Method of preparing doped oxide catalysts for lean NOx exhaust

    DOE Patents [OSTI]

    Park, Paul W.

    2004-03-09T23:59:59.000Z

    The lean NOx catalyst includes a substrate, an oxide support material, preferably .gamma.-alumina deposited on the substrate and a metal or metal oxide promoter or dopant introduced into the oxide support material. The metal promoters or dopants are selected from the group consisting of indium, gallium, tin, silver, germanium, gold, nickel, cobalt, copper, iron, manganese, molybdenum, chromium cerium, and vanadium, and oxides thereof, and any combinations thereof. The .gamma.-alumina preferably has a pore volume of from about 0.5 to about 2.0 cc/g; a surface area of between 80 and 350 m.sup.2 /g; an average pore size diameter of between about 3 to 30 nm; and an impurity level of less than or equal to about 0.2 weight percent. In a preferred embodiment the .gamma.-alumina is prepared by a sol-gel method, with the metal doping of the .gamma.-alumina preferably accomplished using an incipient wetness impregnation technique.

  11. Background information for RACT determination of NOx emissions from Maryland power plants. Part 1. Boilers. Technical report

    SciTech Connect (OSTI)

    Borkowicz, R.J.

    1993-10-01T23:59:59.000Z

    The purpose of the report is to provide an evaluation of potential NOx control technologies for utility boilers in the State of Maryland. The boilers discussed are owned and operated by Baltimore Gas Electric Company (BG E), Potomac Electric Power Company (PEPCO), Delmarva Power and Light (DP L), and Allegheny Power. The paper focuses on available technologies, costs, achievable NOx reductions, unique characteristics of specific units, and strategies for achieving low NOx emissions.

  12. Selective NOx Recirculation for Stationary Lean-Burn Natural Gas Engines

    SciTech Connect (OSTI)

    Nigel Clark; Gregory Thompson; Richard Atkinson; Richard Turton; Chamila Tissera; Emre Tatli; Andy Zimmerman

    2005-12-28T23:59:59.000Z

    Selective NOx Recirculation (SNR) involves cooling the engine exhaust gas and then adsorbing the oxides of nitrogen (NOx) from the exhaust stream, followed by the periodic desorption of NOx. By returning the desorbed, concentrated NOx into the engine intake and through the combustion chamber, a percentage of the NOx is decomposed during the combustion process. An initial study of NOx decomposition during lean-burn combustion was concluded in 2004 using a 1993 Cummins L10G 240hp natural gas engine. It was observed that the air/fuel ratio, injected NO (nitric oxide) quantity and engine operating points affected NOx decomposition rates of the engine. Chemical kinetic modeling results were also used to determine optimum NOx decomposition operating points and were published in the 2004 annual report. A NOx decomposition rate of 27% was measured from this engine under lean-burn conditions while the software model predicted between 35-42% NOx decomposition for similar conditions. A later technology 1998 Cummins L10G 280hp natural gas engine was procured with the assistance of Cummins Inc. to replace the previous engine used for 2005 experimental research. The new engine was equipped with an electronic fuel management system with closed-loop control that provided a more stable air/fuel ratio control and improved the repeatability of the tests. The engine was instrumented with an in-cylinder pressure measurement system and electronic controls, and was adapted to operate over a range of air/fuel ratios. The engine was connected to a newly commissioned 300hp alternating current (AC) motoring dynamometer. The second experimental campaign was performed to acquire both stoichiometric and slightly rich (0.97 lambda ratio) burn NOx decomposition rates. Effects of engine load and speed on decomposition were quantified, but Exhaust Gas Recirculation (EGR) was not varied independently. Decomposition rates of up to 92% were demonstrated. Following recommendations at the 2004 ARES peer review meeting at Argonne National Laboratories, in-cylinder pressure was measured to calculate engine indicated mean effective pressure (IMEP) changes due to NOx injections and EGR variations, and to observe conditions in the cylinder. The third experimental campaign gathered NOx decomposition data at 800, 1200 and 1800 rpm. EGR was added via an external loop, with EGR ranging from zero to the point of misfire. The air/fuel ratio was set at both stoichiometric and slightly rich conditions, and NOx decomposition rates were calculated for each set of runs. Modifications were made to the engine exhaust manifold to record individual exhaust temperatures. The three experimental campaigns have provided the data needed for a comprehensive model of NOx decomposition during the combustion process, and data have confirmed that there was no significant impact of injected NO on in-cylinder pressure. The NOx adsorption system provided by Sorbent Technologies Corp. (Twinsburg, OH), comprised a NOx adsorber, heat exchanger and a demister. These components were connected to the engine, and data were gathered to show both the adsorption of NOx from the engine, and desorption of NOx from the carbon-based sorbent material back into the engine intake, using a heated air stream. In order to quantify the NOx adsorption/desorption characteristics of the sorbent material, a bench top adsorption system was constructed and instrumented with thermocouples and the system output was fed into a NOx analyzer. The temperature of this apparatus was controlled while gathering data on the characteristics of the sorbent material. These data were required for development of a system model. Preliminary data were gathered in 2005, and will continue in early 2006. To assess the economic benefits of the proposed SNR technology the WVU research team has been joined in the last quarter by Dr Richard Turton (WVU-Chemical Engineering), who is modeling, sizing and costing the major components. The tasks will address modeling and preliminary design of the heat exchanger, demister and NOx sorbent chamber s

  13. Investigation Of Synergistic NOx Reduction From Cofiring And Air Staged Combustion Of Coal And Low Ash Dairy Biomass In A 30 Kilowatt Low NOx Furnace

    E-Print Network [OSTI]

    Lawrence, Benjamin Daniel

    2013-08-01T23:59:59.000Z

    to address this concern. DB is evaluated as a cofired fuel with Wyoming Powder River Basin (PRB) sub-bituminous coal in a small-scale 29 kW_(t) low NO_(x) burner (LNB) facility. Fuel properties, of PRB and DB revealed the following: a higher heating value...

  14. METHANE de-NOX for Utility PC Boilers

    SciTech Connect (OSTI)

    Bruce Bryan; Serguei Nester; Joseph Rabovitser; Stan Wohadlo

    2005-09-30T23:59:59.000Z

    The overall project objective is the development and validation of an innovative combustion system, based on a novel coal preheating concept prior to combustion, that can reduce NO{sub x} emissions to 0.15 lb/million Btu or less on utility pulverized coal (PC) boilers. This NO{sub x} reduction should be achieved without loss of boiler efficiency or operating stability, and at more than 25% lower levelized cost than state-of-the-art SCR technology. A further objective is to ready technology for full-scale commercial deployment to meet the market demand for NO{sub x} reduction technologies. Over half of the electric power generated in the U.S. is produced by coal combustion, and more than 80% of these units utilize PC combustion technology. Conventional measures for NOx reduction in PC combustion processes rely on combustion and post-combustion modifications. A variety of combustion-based NO{sub x} reduction technologies are in use today, including low-NO{sub x} burners (LNBs), flue gas recirculation (FGR), air staging, and natural gas or other fuel reburning. Selective non-catalytic reduction (SNCR) and selective catalytic reduction (SCR) are post-combustion techniques. NO{sub x} reduction effectiveness from these technologies ranges from 30 to 60% and up to 90-93% for SCR. Typically, older wall-fired PC burner units produce NO{sub x} emissions in the range of 0.8-1.6 lb/million Btu. Low-NO{sub x} burner systems, using combinations of fuel staging within the burner and air staging by introduction of overfire air in the boiler, can reduce NO{sub x} emissions by 50-60%. This approach alone is not sufficient to meet the desired 0.15 lb/million Btu NO{sub x} standard with a range of coals and boiler loads. Furthermore, the heavy reliance on overfire air can lead to increased slagging and corrosion in furnaces, particularly with higher-sulfur coals, when LNBs are operated at sub-stoichiometric conditions to reduce fuel-derived NOx in the flame. Therefore, it is desirable to minimize the need for overfire air by maximizing NO{sub x} reduction in the burner. The proposed combustion concept aims to greatly reduce NO{sub x} emissions by incorporating a novel modification to conventional or low-NO{sub x} PC burners using gas-fired coal preheating to destroy NO{sub x} precursors and prevent NO{sub x} formation. A concentrated PC stream enters the burner, where flue gas from natural gas combustion is used to heat the PC up to about 1500 F prior to coal combustion. Secondary fuel consumption for preheating is estimated to be 3 to 5% of the boiler heat input. This thermal pretreatment releases coal volatiles, including fuel-bound nitrogen compounds into oxygen-deficient atmosphere, which converts the coal-derived nitrogen compounds to molecular N{sub 2} rather than NO. Design, installation, shakedown, and testing on Powder River Basin (PRB) coal at a 3-million Btu/h pilot system at RPI's (Riley Power, Inc.) pilot-scale combustion facility (PSCF) in Worcester, MA demonstrated that the PC PREHEAT process has a significant effect on final O{sub x} formation in the coal burner. Modifications to both the pilot system gas-fired combustor and the PC burner led to NO{sub x} reduction with PRB coal to levels below 0.15 lb/million Btu with CO in the range of 35-112 ppmv without any furnace air staging.

  15. Two-stage Catalytic Reduction of NOx with Hydrocarbons

    SciTech Connect (OSTI)

    Umit S. Ozkan; Erik M. Holmgreen; Matthew M. Yung; Jonathan Halter; Joel Hiltner

    2005-12-21T23:59:59.000Z

    A two-stage system for the catalytic reduction of NO from lean-burn natural gas reciprocating engine exhaust is investigated. Each of the two stages uses a distinct catalyst. The first stage is oxidation of NO to NO{sub 2} and the second stage is reduction of NO{sub 2} to N{sub 2} with a hydrocarbon. The central idea is that since NO{sub 2} is a more easily reduced species than NO, it should be better able to compete with oxygen for the combustion reaction of hydrocarbon, which is a challenge in lean conditions. Early work focused on demonstrating that the N{sub 2} yield obtained when NO{sub 2} was reduced was greater than when NO was reduced. NO{sub 2} reduction catalysts were designed and silver supported on alumina (Ag/Al{sub 2}O{sub 3}) was found to be quite active, able to achieve 95% N{sub 2} yield in 10% O{sub 2} using propane as the reducing agent. The design of a catalyst for NO oxidation was also investigated, and a Co/TiO{sub 2} catalyst prepared by sol-gel was shown to have high activity for the reaction, able to reach equilibrium conversion of 80% at 300 C at GHSV of 50,000h{sup -1}. After it was shown that NO{sub 2} could be more easily reduced to N{sub 2} than NO, the focus shifted on developing a catalyst that could use methane as the reducing agent. The Ag/Al{sub 2}O{sub 3} catalyst was tested and found to be inactive for NOx reduction with methane. Through iterative catalyst design, a palladium-based catalyst on a sulfated-zirconia support (Pd/SZ) was synthesized and shown to be able to selectively reduce NO{sub 2} in lean conditions using methane. Development of catalysts for the oxidation reaction also continued and higher activity, as well as stability in 10% water, was observed on a Co/ZrO{sub 2} catalyst, which reached equilibrium conversion of 94% at 250 C at the same GHSV. The Co/ZrO{sub 2} catalyst was also found to be extremely active for oxidation of CO, ethane, and propane, which could potential eliminate the need for any separate oxidation catalyst. At every stage, catalyst synthesis was guided by the insights gained through detailed characterization of the catalysts using many surface and bulk analysis techniques such as X-ray diffraction, X-ray photoelectron spectroscopy, Temperature-programmed Reduction, Temperature programmed Desorption, and Diffuse Reflectance InfraRed Fourier Transform Spectroscopy as well as steady state reaction experiments. Once active catalysts for each stage had been developed, a physical mixture of the two catalysts was tested for the reduction of NO with methane in lean conditions. These experiments using a mixture of the catalysts produced N2 yields as high as 90%. In the presence of 10% water, the catalyst mixture produced 75% N{sub 2} yield, without any optimization. The dual catalyst system developed has the potential to be implemented in lean-burn natural gas engines for reducing NOx in lean exhaust as well as eliminating CO and unburned hydrocarbons without any fuel penalty or any system modifications. If funding continues, future work will focus on improving the hydrothermal stability of the system to bring the technology closer to application.

  16. Regenerative process and system for the simultaneous removal of particulates and the oxides of sulfur and nitrogen from a gas stream

    DOE Patents [OSTI]

    Cohen, M.R.; Gal, E.

    1993-04-13T23:59:59.000Z

    A process and system are described for simultaneously removing from a gaseous mixture, sulfur oxides by means of a solid sulfur oxide acceptor on a porous carrier, nitrogen oxides by means of ammonia gas and particulate matter by means of filtration and for the regeneration of loaded solid sulfur oxide acceptor. Finely-divided solid sulfur oxide acceptor is entrained in a gaseous mixture to deplete sulfur oxides from the gaseous mixture, the finely-divided solid sulfur oxide acceptor being dispersed on a porous carrier material having a particle size up to about 200 microns. In the process, the gaseous mixture is optionally pre-filtered to remove particulate matter and thereafter finely-divided solid sulfur oxide acceptor is injected into the gaseous mixture.

  17. NOx CONTROL OPTIONS AND INTEGRATION FOR US COAL FIRED BOILERS

    SciTech Connect (OSTI)

    Mike Bockelie; Marc Cremer; Kevin Davis; Connie Senior; Bob Hurt; Eric Suuberg; Eric Eddings; Larry Baxter

    2002-01-31T23:59:59.000Z

    This is the sixth Quarterly Technical Report for DOE Cooperative Agreement No: DE-FC26-00NT40753. The goal of the project is to develop cost effective analysis tools and techniques for demonstrating and evaluating low NOx control strategies and their possible impact on boiler performance for firing US coals. The Electric Power Research Institute (EPRI) is providing co-funding for this program. This program contains multiple tasks and good progress is being made on all fronts. Preliminary results from laboratory and field tests of a corrosion probe to predict waterwall wastage indicate good agreement between the electrochemical noise corrosion rates predicted by the probe and corrosion rates measured by a surface profilometer. Four commercial manufacturers agreed to provide catalyst samples to the program. BYU has prepared two V/Ti oxide catalysts (custom, powder form) containing commercially relevant concentrations of V oxide and one containing a W oxide promoter. Two pieces of experimental apparatus being built at BYU to carry out laboratory-scale investigations of SCR catalyst deactivation are nearly completed. A decision was made to carry out the testing at full-scale power plants using a slipstream of gas instead of at the University of Utah pilot-scale coal combustor as originally planned. Design of the multi-catalyst slipstream reactor was completed during this quarter. One utility has expressed interest in hosting a long-term test at one of their plants that co-fire wood with coal. Tests to study ammonia adsorption onto fly ash have clearly established that the only routes that can play a role in binding significant amounts of ammonia to the ash surface, under practical ammonia slip conditions, are those that must involve co-adsorbates.

  18. Turbulent Flame Speeds and NOx Kinetics of HHC Fuels with Contaminants and High Dilution Levels

    SciTech Connect (OSTI)

    Peterson, Eric; Krejci, Michael; Mathieu, Olivier; Vissotski, Andrew; Ravi, Sankat; Plichta, Drew; Sikes, Travis; Levacque, Anthony; Camou, Alejandro; Aul, Christopher

    2013-09-30T23:59:59.000Z

    This final report documents the technical results of the 3-year project entitled, “Turbulent Flame Speeds and NOx Kinetics of HHC Fuels with Contaminants and High Dilution Levels,” funded under the NETL of DOE. The research was conducted under six main tasks: 1) program management and planning; 2) turbulent flame speed measurements of syngas mixtures; 3) laminar flame speed measurements with diluents; 4) NOx mechanism validation experiments; 5) fundamental NOx kinetics; and 6) the effect of impurities on NOx kinetics. Experiments were performed using primary constant-volume vessels for laminar and turbulent flame speeds and shock tubes for ignition delay times and species concentrations. In addition to the existing shock- tube and flame speed facilities, a new capability in measuring turbulent flame speeds was developed under this grant. Other highlights include an improved NOx kinetics mechanism; a database on syngas blends for real fuel mixtures with and without impurities; an improved hydrogen sulfide mechanism; an improved ammonia kintics mechanism; laminar flame speed data at high pressures with water addition; and the development of an inexpensive absorption spectroscopy diagnostic for shock-tube measurements of OH time histories. The Project Results for this work can be divided into 13 major sections, which form the basis of this report. These 13 topics are divided into the five areas: 1) laminar flame speeds; 2) Nitrogen Oxide and Ammonia chemical kinetics; 3) syngas impurities chemical kinetics; 4) turbulent flame speeds; and 5) OH absorption measurements for chemical kinetics.

  19. aerosol bound particulates: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Data) cloud drop size distributions and (iv) TWP-ICE (Darwin, Australia) rain drop size distributions. A. M. Selvam 2010-05-08 26 7, 1569315721, 2007 Particulate PAH Computer...

  20. Ultrasonic wave propagation in random and periodic particulate composites 

    E-Print Network [OSTI]

    Henderson, Benjamin Kyle

    1996-01-01T23:59:59.000Z

    Current theoretical models are insufficient to predict the dynamic behavior of particulate composites under ultrasonic loading. To facilitate the creation of more accurate models, ultrasonic tests have been performed to expand the database...

  1. Durability of Diesel Engine Particulate Filters CRADA No. ORNL...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Filters CRADA No. ORNL-04-0692 with Cummins Inc. Durability of Diesel Engine Particulate Filters CRADA No. ORNL-04-0692 with Cummins Inc. Presentation from the U.S. DOE Office of...

  2. Mechanical Properties of Particulate Reinforced Aluminium Alloy Matrix Composite

    SciTech Connect (OSTI)

    Sayuti, M. [Faculty of Engineering, Malikussaleh University of Lhokseumawe, 24300 Aceh (Indonesia); Department of Mechanical and Manufacturing Engineering, Faculty of Engineering, Universiti Putra Malaysia, 43400 Serdang, Selangor (Malaysia); Sulaiman, S.; Baharudin, B. T. H. T.; Arifin, M. K. A. [Department of Mechanical and Manufacturing Engineering, Faculty of Engineering, Universiti Putra Malaysia, 43400 Serdang, Selangor (Malaysia); Suraya, S.; Vijayaram, T. R.

    2011-01-17T23:59:59.000Z

    This paper discusses the mechanical properties of Titanium Carbide (TiC) particulate reinforced aluminium-silicon alloy matrix composite. TiC particulate reinforced LM6 alloy matrix composites were fabricated by carbon dioxide sand molding process with different particulate weight fraction. Tensile strength, hardness and microstructure studies were conducted to determine the maximum load, tensile strength, modulus of elasticity and fracture surface analysis have been performed to characterize the morphological aspects of the test samples after tensile testing. Hardness values are measured for the TiC reinforced LM6 alloy composites and it has been found that it gradually increases with increased addition of the reinforcement phase. The tensile strength of the composites increased with the increase percentage of TiC particulate.

  3. Automated particulate sampler field test model operations guide

    SciTech Connect (OSTI)

    Bowyer, S.M.; Miley, H.S.

    1996-10-01T23:59:59.000Z

    The Automated Particulate Sampler Field Test Model Operations Guide is a collection of documents which provides a complete picture of the Automated Particulate Sampler (APS) and the Field Test in which it was evaluated. The Pacific Northwest National Laboratory (PNNL) Automated Particulate Sampler was developed for the purpose of radionuclide particulate monitoring for use under the Comprehensive Test Ban Treaty (CTBT). Its design was directed by anticipated requirements of small size, low power consumption, low noise level, fully automatic operation, and most predominantly the sensitivity requirements of the Conference on Disarmament Working Paper 224 (CDWP224). This guide is intended to serve as both a reference document for the APS and to provide detailed instructions on how to operate the sampler. This document provides a complete description of the APS Field Test Model and all the activity related to its evaluation and progression.

  4. air particulate analysis: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Meta-analysis for Assessment of Relationships between Asthma Rates and Particulate Air Pollution Math Preprints (arXiv) Summary: Multi-dimensional meta-analysis (MDMA) is an...

  5. Diesel particulate filter (DPF) regeneration by electrical heating of resistive coatings

    DOE Patents [OSTI]

    Williamson, Weldon S. (Malibu, CA); Gonze, Eugene V. (Pinckney, MI)

    2008-12-30T23:59:59.000Z

    An exhaust system that processes exhaust generated by an engine includes a diesel particulate filter (DPF) that is disposed downstream of the engine and that filters particulates from the exhaust. An electrical heater is integrally formed in an upstream end of the DPF and selectively heats the exhaust to initiate combustion of the particulates within the exhaust as it passes therethrough. Heat generated by combustion of the particulates induces combustion of particulates within the DPF.

  6. Ultrasonic wave propagation in random and periodic particulate composites

    E-Print Network [OSTI]

    Henderson, Benjamin Kyle

    1996-01-01T23:59:59.000Z

    ULTRASONIC WAVE PROPAGATION IN RANDOM AND PERIODIC PARTICULATE COMPOSITES A Thesis by BENJAMIN KYLE HENDERSON Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfilltnent of the requirements for the degree... of MASTER OF SCIENCE May 1996 Major Subject: Aerospace Engineering ULTRASONIC WAVE PROPAGATION IN RANDOM AND PERIODIC PARTICULATE COMPOSITES A Thesis by BENJAMIN KYLE HENDERSON Submitted to Texas ASM University in partial fulfillment...

  7. Zone heated inlet ignited diesel particulate filter regeneration

    DOE Patents [OSTI]

    Gonze, Eugene V [Pinckney, MI; Ament, Frank [Troy, MI

    2012-06-26T23:59:59.000Z

    An exhaust system that processes exhaust generated by an engine is provided. The system includes: a particulate filter (PF) that is disposed downstream of the engine and that filters particulates from the exhaust; and a grid that includes electrically resistive material that is segmented by non-conductive material into a plurality of zones and wherein the grid is applied to an exterior upstream surface of the PF.

  8. Atmospheric particulates in a semi-rural environment

    E-Print Network [OSTI]

    Klein, Thomas Kelly

    1974-01-01T23:59:59.000Z

    and sampling results used in Figures 11 through 17 Comparison of the resultant monthly mean concentrations of airborne particulates over College Station with the mean concentrations detected by non-urban stations of the National Air Sampling Network 64... of variance table for the dependent variable C4 100 LIST OF FIGURES Figure Title Page Size distributions of airborne particulates over continents (After Junge, 1963) Nomenclature and importance of natural aerosols (After Junge, 1963) 10 The location...

  9. A particulate non-specific alkaline phosphatase in Saccharomyces cerevisiae

    E-Print Network [OSTI]

    Mitchell, James Kent

    1980-01-01T23:59:59.000Z

    utant Strain DO4-AP2 24 24 24 30 31 36 39 41 43 43 43 46 46 51 51 TABLE OF CONTENTS (Continued) Isoelectric Focussing Page 53 IV. Discussion and Conclusions 56 V. References 65 VI, Vita 68 LIST OF TABLES Tables Page 1.... Fluorescent Readings of 4-methylumbelliferone 25 2. Fluorescent Readings of a-naphthol 25 3. Substrate Specificity of Particulate Alkaline Phosohatase 40 Intracellular Localization of Particulate Alkaline Phos- phatase 45 5. Specific Activity of a...

  10. The distribution of particulate aluminum in the Gulf of Mexico

    E-Print Network [OSTI]

    Feely, Richard Alan

    1971-01-01T23:59:59.000Z

    THE DISTRIBUTION OF PARTICULATE ALUMINUM IN THE GULF OF MEXICO A Thesis RICHARD ALAN FEELY Submitted to the Graduate College of Texas A&M University in partial fulfillment of the reguirement for the degree of MASTER OF SCIENCE May, 1971... Major Subject: Oceanography THE DISTRIBUTION OF PARTICULATE ALUMINUM IN THE GULF OF MEXICO A Thesis by RICHARD ALAN FEELY Approved as to style a d content by: hairma of Committee Head Department (Member) Member) May, 1971 ABSTRACT...

  11. Fine particulate chemical composition and light extinction at Meadview, AZ

    SciTech Connect (OSTI)

    Delbert J. Eatough; Wenxuan Cui; Jeffery Hull; Robert J. Farber [Brigham Young University, Provo, UT (United States). Department of Chemistry and Biochemistry

    2006-12-15T23:59:59.000Z

    The concentration of fine particulate nitrate, sulfate, and carbonaceous material was measured for 12-hr daynight samples using diffusion denuder samplers during the Project Measurement of Haze and Visibility Effects (MOHAVE) July to August 1992 Summer Intensive study at Meadview, AZ, just west of Grand Canyon National Park. Organic material was measured by several techniques. Only the diffusion denuder method measured the semivolatile organic material. Fine particulate sulfate and nitrate (using denuder technology) determined by various groups agreed. Based on the various collocated measurements obtained during the Project MOHAVE study, the precision of the major fine particulate species was {+-} 0.6 {mu}g/m{sup 3} organic material, {+-} 0.3 {mu}g/m{sup 3} ammonium sulfate, and {+-} 0.07 {mu}g/m{sup 3} ammonium nitrate. Fine particulate organic material was the principal particulate contributor to light extinction during the study period, with fine particulate sulfate as the second most important contributor. Particle light extinction was dominated by sulfate and organic material during periods of lowest light extinction. Combination of the extinction data and chemical mass balance analysis of sulfur oxides sources in the region indicate that the major anthropogenic contributors to light extinction were from the Los Angeles, CA, and Las Vegas, NV, urban areas. Mohave Power Project associated secondary sulfate was a negligible contributor to light extinction. 49 refs., 12 figs., 7 tabs.

  12. Loading and Regeneration Analysis of a Diesel Particulate Filter with a Radio Frequency-Based Sensor

    SciTech Connect (OSTI)

    Sappok, Alex [Filter Sensing Technologies] [Filter Sensing Technologies; Prikhodko, Vitaly Y [ORNL] [ORNL; Parks, II, James E [ORNL

    2010-01-01T23:59:59.000Z

    Accurate knowledge of diesel particulate filter (DPF) loading is critical for robust and efficient operation of the combined engine-exhaust aftertreatment system. Furthermore, upcoming on-board diagnostics regulations require on-board technologies to evaluate the status of the DPF. This work describes the application of radio frequency (RF) based sensing techniques to accurately measure DPF soot levels and the spatial distribution of the accumulated material. A 1.9L GM turbo diesel engine and a DPF with an RF-sensor were studied. Direct comparisons between the RF measurement and conventional pressure-based methods were made. Further analysis of the particulate matter loading rates was obtained with a mass-based soot emission measurement instrument (TEOM). Comparison with pressure drop measurements show the RF technique is unaffected by exhaust flow variations and exhibits a high degree of sensitivity to DPF soot loading and good dynamic response. Additional computational and experimental work further illustrates the spatial resolution of the RF measurements. Based on the experimental results, the RF technique shows significant promise for improving DPF control enabling optimization of the combined engine-aftertreatment system for improved fuel economy and extended DPF service life.

  13. Nitrogen Isotopic Composition of Coal-Fired Power Plant NOx: Influence of Emission Controls and Implications for Global Emission

    E-Print Network [OSTI]

    Elliott, Emily M.

    Nitrogen Isotopic Composition of Coal-Fired Power Plant NOx: Influence of Emission Controls from coal-fired power plants in the U.S. at typical operating conditions with and without the presence this, a novel method for collection and isotopic analysis of coal-fired stack NOx emission samples

  14. Exhaust gas fuel reforming of Diesel fuel by non-thermal arc discharge for NOx trap regeneration

    E-Print Network [OSTI]

    Boyer, Edmond

    1 Exhaust gas fuel reforming of Diesel fuel by non- thermal arc discharge for NOx trap regeneration to the reforming of Diesel fuel with Diesel engine exhaust gas using a non-thermal plasma torch for NOx trap Diesel fuel reforming with hal-00617141,version1-17May2013 Author manuscript, published in "Energy

  15. Sulfur Poisoning and Regeneration of NOx Storage-Reduction Cu/K2Ti2O5 Qiang Wang,*,

    E-Print Network [OSTI]

    Guo, John Zhanhu

    a maximum value of 15 ppm sulfur content in diesel fuel, and this ultra-low-sulfur fuel is expectedSulfur Poisoning and Regeneration of NOx Storage-Reduction Cu/K2Ti2O5 Catalyst Qiang Wang,*, Jiahua of sulfur has not been investigated. In this article, the sulfur poisoning of the NOx storage

  16. Variable power distribution for zoned regeneration of an electrically heated particulate filter

    DOE Patents [OSTI]

    Bhatia, Garima [Bangalore, IN; Gonze, Eugene V [Pinckney, MI

    2012-04-03T23:59:59.000Z

    A system includes a particulate matter (PM) filter with multiple zones, an electric heater and a control module. The electrical heater includes heater segments, which each correspond with a respective one of the zones. The electrical heater is arranged upstream from and is proximate with the PM filter. The control module selectively applies a first energy level to a first one of the zones via a first one of the heater segments to initiate regeneration in the first zone. The control module also selectively applies a second energy level that is less than the first energy level to a second one of the zones via a second one of the heater segments to initiate regeneration in the second zone.

  17. Chemical compositions responsible for inflammation and tissue damage in the mouse lung by coarse and fine particulate samples from contrasting air pollution in Europe

    SciTech Connect (OSTI)

    Happo, M.S.; Hirvonen, M.R.; Halinen, A.I.; Jalava, P.I.; Pennanen, A.S.; Sillanpaa, M.; Hillamo, R.; Salonen, R.O. [National Public Health Institute, Kuopio (Finland). Dept. of Environmental Health

    2008-07-01T23:59:59.000Z

    Inflammation is regarded as an important mechanism in mortality and morbidity associated with exposures of cardiorespiratory patients to urban air particulate matter. We investigated the association of the chemical composition and sources of urban air fine (PM2.5-0.2) and coarse (PM10-2.5) particulate samples with the inflammatory activity in the mouse lung. The particulate samples were collected during selected seasons in six European cities using a high-volume cascade impactor. Healthy C57BL/6J mice were intratracheally instilled with a single dose (10 mg/kg) of the particulate samples. At 4, 12, and 24 h after the exposure, the lungs were lavaged and the bronchoalveolar lavage fluid (BALF) was assayed for indicators of inflammation and tissue damage: cell number, total protein, and cytokines (tumor necrosis factor (TNF)-alpha, interleukin (IL)-6, and KC). Dicarboxylic acids and transition metals, especially Ni and V, in PM2.5-0.2 correlated positively and some secondary inorganic ions (NO{sub 3}{sup -}, NH{sub 4}{sup +}) negatively with the inflammatory activity. Total organic matter and SO{sub 4}{sup 2-} had no consistent correlations. In addition, the soil-derived constituents (Ca{sup 2+}, Al, Fe, Si) showed positive correlations with the PM2.5-0.2-induced inflammatory activity, but their role in PM10 (2.5) remained obscure, possibly due to largely undefined biogenic material. Markers of poor biomass and coal combustion, i.e., monosaccharide anhydrides and As, were associated with elevated PAH contents in PM2.5 (0.2) and a consistent immunosuppressive effect. Overall, our results support epidemiological findings that the local sources of incomplete combustion and resuspended road dust are important in urban air particulate pollution-related health effects.

  18. Microwave-Regenerated Diesel Exhaust Particulate Filter

    SciTech Connect (OSTI)

    Nixdorf, Richard D. (Industrial Ceramic Solution, LLC); Green, Johney Boyd; Story, John M.; Wagner, Robert M. (Oak Ridge National Laboratory)

    2001-03-05T23:59:59.000Z

    Development of a microwave-regenerated particulate filter system has evolved from bench scale work to actual diesel engine experimentation. The filter system was initially evaluated on a stationary mounted 1.2-L diesel engine and was able to remove a significant amount of carbon particles from the exhaust. The ability of the microwave energy to regenerate or clean the filter was also demonstrated on this engine under idle conditions. Based on the 1.2-L experiments, improvements to the filter design and materials were implemented and the system was re-evaluated on a vehicle equipped with a 7.3-L diesel engine. The 7.3-L engine was selected to achieve heavy filter loading in a relatively short period of time. The purpose of these experiments was to evaluate filter-loading capacity, power requirements for regeneration, and filter regeneration efficiency. A more detailed evaluation of the filter was performed on a stationary mounted 1.9-L diesel engine. The effect of exhaust flow rate, loading, transients, and regeneration on filter efficiency was evaluated with this setup. In addition, gaseous exhaust emissions were investigated with and without an oxidation catalyst on the filter cartridge during loading and regeneration. (SAE Paper SAE-2001-01-0903 © 2001 SAE International. This paper is published on this website with permission from SAE International. As a user of this website, you are permitted to view this paper on-line, download this pdf file and print one copy of this paper at no cost for your use only. The downloaded pdf file and printout of this SAE paper may not be copied, distributed or forwarded to others or for the use of others.)

  19. JV Task-Long-Kiln NOx Reduction Study

    SciTech Connect (OSTI)

    Bruce Folkedahl; Joshua Strege; Darren Schmidt; Lingbu Kong

    2008-07-01T23:59:59.000Z

    Field sampling was conducted by the Energy & Environmental Research Center at two Lafarge North America cement kiln locations in Canada. Emissions including SO{sub x}, NO{sub x}, and particulate were measured and reported at various locations throughout the kilns. At each site data were collected on two kilns during field sampling. However, only Kiln 1 at the Ravena site was utilized for modeling efforts. Experimental work was then conducted to estimate the effectiveness of various NO{sub x} control techniques on limiting both NO{sub x} and SO{sub x} emissions in cement kiln exhaust. Theory-based models were constructed to estimate both NO{sub x} and SO{sub x} emissions from cement kilns. These models were then applied to estimating the impact of various NO{sub x} control strategies on kiln exhaust emissions. The sulfur model constructed as part of this work was successful at predicting SO{sub 2} emissions and sulfur capture in the Alpena kiln. This model is designed to run as a postprocessing step that uses the output of a NO{sub x} model as input. With an accurate NO{sub x} model, the sulfur model may prove to be a valuable tool in estimating the impact of kiln modifications on sulfur emissions. The NO{sub x} model was also applied to model several operating scenarios on three of Lafarge's kilns: Alpena 20/21, Alpena 22/23, and Ravena 1. The predictions of the flue gas temperature at the kiln feed end, the kiln shell heat loss, the quality of clinker, and the excess O{sub 2} in the flue gas are consistent with the audit data. The developed simulation tool in this project has proven to be an effective way to investigate the NO{sub x} emissions, to optimize kiln performance, and to assess changes in operating condition on kiln performance.

  20. Matter Field, Dark Matter and Dark Energy

    E-Print Network [OSTI]

    Masayasu Tsuge

    2009-03-24T23:59:59.000Z

    A model concerning particle theory and cosmology is proposed. Matter field, dark matter and dark energy are created by an energy flow from space to primordial matter fields at the phase transition in the early universe.