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Note: This page contains sample records for the topic "nox ods voc" from the National Library of EnergyBeta (NLEBeta).
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We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


1

Flexible CHP System with Low NOx, CO, and VOC Emissions - Presentation...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

CHP System with Low NOx, CO, and VOC Emissions - Presentation by the Gas Technology Institute (GTI), June 2011 Flexible CHP System with Low NOx, CO, and VOC Emissions -...

2

Flexible CHP System with Low NOx, CO and VOC Emissions | Department...  

Broader source: Energy.gov (indexed) [DOE]

Emissions Flexible CHP System with Low NOx, CO and VOC Emissions Introduction A combined heat and power (CHP) system can be a financially attractive energy option for many...

3

O3-NOx-VOC sensitivity and NOx-VOC indicators in Paris: Results from models and Atmospheric Pollution Over  

E-Print Network [OSTI]

from the Atmospheric Pollution Over the Paris Area campaign near Paris, with special attention Composition and Structure: Pollution--urban and regional (0305); 0365 Atmospheric Composition and Structure-VOC indicators in Paris: Results from models and Atmospheric Pollution Over the Paris Area (ESQUIF) measurements

Menut, Laurent

4

Flexible CHP System with Low NOx, CO, and VOC Emissions- Presentation by the Gas Technology Institute (GTI), June 2011  

Broader source: Energy.gov [DOE]

Presentation on Flexible CHP System with Low NOx, CO, and VOC Emissions, given by David Cygan of the Gas Technology Institute, at the U.S. DOE Industrial Distributed Energy Portfolio Review Meeting in Washington, D.C. on June 1-2, 2011.

5

Flexible CHP System with Low NOx, CO and VOC Emissions- Fact Sheet, 2014  

Broader source: Energy.gov [DOE]

Utilizing Supplemental Ultra-Low-NOx Burner Technology to Meet Emissions Standards and Improve System Efficiency

6

NOx Adsorber (Lean NOx Trap) Fundamentals (Agreement #10049 ...  

Broader source: Energy.gov (indexed) [DOE]

NOx Adsorber (Lean NOx Trap) Fundamentals (Agreement 10049 - PNNL Project 47120) NOx Adsorber (Lean NOx Trap) Fundamentals (Agreement 10049 - PNNL Project 47120) Presentation...

7

Microenvironmental Exposures to VOCs  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Microenvironmental Exposures to VOCs Microenvironmental Exposures to VOCs Speaker(s): Miranda Loh Date: February 1, 2006 - 12:00pm Location: 90-3122 The Boston Exposure Assessment in Microenvironments (BEAM) study was designed to examine the concentration distributions of VOCs in various microenvironments in and around Boston with the main objective of reducing the uncertainties in predicting exposure levels. A suite of VOC's with potential health effects including benzene, toluene, ethylbenzene, xylenes, several chlorinated compounds and aldehydes were collected in all microenvironments. Phase I. BEAM examined common non-residential microenvironments that have not been extensively studied, in particular, dining, shopping, and transportation microenvironments. Sampling using scripted activities in these microenvironments. For some compounds,

8

VOC Exposure Metrics  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

6 6 VOC Exposure Metrics ... and "Sick Building Syndrome" Figure1: The elevated odds ratios (above unity) in this figure suggest that exposures to VOCs from water-based points and solvents are associated with a variety of sick building symptions (* indicates the OR is significant at p < 0.05; ** for p < 0.01). The indoors is often regarded as safe haven from problems associated with outdoor air pollution, but a growing number of reports have suggested that exposures in indoor environments may lead to health problems. One area in which evidence has been accumulating is the relationship between working in office buildings (as opposed to industrial exposure conditions) and a variety of health effects, such as eye, nose, and throat irritation and

9

Low NOx combustion  

SciTech Connect (OSTI)

Combustion of hydrocarbon liquids and solids is achieved with less formation of NOx by feeding a small amount of oxygen into the fuel stream.

Kobayashi; Hisashi (Putnam Valley, NY), Bool, III; Lawrence E. (Aurora, NY)

2007-06-05T23:59:59.000Z

10

Low NOx combustion  

SciTech Connect (OSTI)

Combustion of hydrocarbon liquids and solids is achieved with less formation of NOx by feeding a small amount of oxygen into the fuel stream.

Kobayashi, Hisashi (Putnam Valley, NY); Bool, III, Lawrence E. (Aurora, NY)

2008-10-21T23:59:59.000Z

11

Thermal treatment for VOC control  

SciTech Connect (OSTI)

Catalytic and thermal oxidation are well-established technologies for controlling volatile organic compounds (VOCs). Oxidation destroys pollutants, rather than capturing them. Oxidation units can destroy nearly 100% of VOC and toxic emissions targeted by the Clean Air Act Amendments of 1990--some systems attain destruction efficiencies over 99.99%. To assist in the design of these systems, an engineer will often look a/t the heat of combustion of the gas stream, along with the type of pollutant, to best determine the correct type of oxidation device to use. The paper discusses catalytic and thermal oxidation, energy recovery, and equipment for these processes.

Cloud, R.A. [Huntington Environmental Systems, Schaumburg, IL (United States)

1998-07-01T23:59:59.000Z

12

4, 66916718, 2004 VOC emissions of  

E-Print Network [OSTI]

ACPD 4, 6691­6718, 2004 VOC emissions of Scots pine V. Tarvainen et al. Title Page Abstract Discussions Temperature and light dependence of the VOC emissions of Scots pine V. Tarvainen 1 , H. Hakola 1.tarvainen@fmi.fi) 6691 #12;ACPD 4, 6691­6718, 2004 VOC emissions of Scots pine V. Tarvainen et al. Title Page Abstract

Paris-Sud XI, Université de

13

NOx | OpenEI  

Open Energy Info (EERE)

NOx NOx Dataset Summary Description Emissions from energy use in buildings are usually estimated on an annual basis using annual average multipliers. Using annual numbers provides a reasonable estimation of emissions, but it provides no indication of the temporal nature of the emissions. Therefore, there is no way of understanding the impact on emissions from load shifting and peak shaving technologies such as thermal energy storage, on-site renewable energy, and demand control. Source NREL Date Released April 11th, 2011 (3 years ago) Date Updated April 11th, 2011 (3 years ago) Keywords buildings carbon dioxide emissions carbon footprinting CO2 commercial buildings electricity emission factors ERCOT hourly emission factors interconnect nitrogen oxides NOx SO2 sulfur dioxide emissions

14

NOx Reduction from Biodiesel Fuels  

Science Journals Connector (OSTI)

NOx Reduction from Biodiesel Fuels ... NOx emissions appear to be different for biodiesels from different feedstocks. ... For the suite of biodiesels prepared from nearly pure fatty acids, all biodiesel fuels produced higher NOx than certification diesel with the following exceptions:? methyl palmitate, methyl laurate, ethyl stearate, and the ethyl ester of hydrogenated soybean oil. ...

Sandun Fernando; Chris Hall; Saroj Jha

2005-11-19T23:59:59.000Z

15

Oxygen Diffusion (OD) Dramatically Improves Wear-Resistance of...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Oxygen Diffusion (OD) Dramatically Improves Wear-Resistance of Titanium Oxygen Diffusion (OD) Dramatically Improves Wear-Resistance of Titanium 2007 Diesel Engine-Efficiency &...

16

5, 90979126, 2005 VOC emissions from  

E-Print Network [OSTI]

ACPD 5, 9097­9126, 2005 VOC emissions from vegetation pyrolysis J. P. Greenberg et al. Title Page Discussions Volatile organic emissions from the distillation and pyrolysis of vegetation J. P. Greenberg, H is licensed under a Creative Commons License. 9097 #12;ACPD 5, 9097­9126, 2005 VOC emissions from vegetation

Paris-Sud XI, Université de

17

T2VOC user`s guide  

SciTech Connect (OSTI)

T2VOC is a numerical simulator for three-phase, three-component, non-isothermal flow of water, air, and a volatile organic compound (VOC) in multidimensional heterogeneous porous media. Developed at the Lawrence Berkeley Laboratory, T2VOC is an extension of the TOUGH2 general-purpose simulation program. This report is a self-contained guide to application of T2VOC to subsurface contamination problems involving nonaqueous phase liquids (NAPLs). It gives a technical description of the T2VOC code, including a discussion of the physical processes modeled, and the mathematical and numerical methods used. Detailed instructions for preparing input data are presented along with several illustrative sample problems.

Falta, R.W. [Clemson Univ., Clemson, SC (United States). Dept. of Earth Sciences; Pruess, K.; Finsterle, S. [Lawrence Berkeley Lab., CA (United States); Battistelli, A. [AQUATER S.p.A., San Lorenzo in Campo, (Italy)

1995-03-01T23:59:59.000Z

18

Measurement and Characterization of NOx Adsorber Regeneration...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Combustion with Lean-NOx Trap Yields Progress Toward Targets of Efficient NOx Control for Diesels Intra-catalyst Reductant Chemistry in Lean NOx Traps: A Study on Sulfur Effects...

19

NETL: Advanced NOx Emissions Control: Control Technology - NOx Emissions  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Emissions from Multi-Burners Emissions from Multi-Burners The University of Utah working with Reaction Engineering International and Brigham Young University is investigating a project that consists of integrated experimental, theoretical and computational modeling efforts. The primary objective is to evaluate NOx formation/destruction processes as they occur in multi-burner arrays, a geometry almost always utilized in utility practice. Most controlled experimental work examining NOx has been conducted on single burners. The range of potential intra-burner interactions are likely to provide added degrees of freedom for reducing NOx. The resultant findings may allow existing utilities to arrange fuel and air distribution to minimize NOx. In new applications, orientation of individual burners within an array may also be altered to reduce NOx. Comprehensive combustion codes will be modified to incorporate the latest submodels of nitrogen release and heterogeneous chemistry. Comparison of pilot scale experiments and simulations will be utilized to validate/develop theory.

20

Compact Potentiometric NOx Sensor | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Potentiometric NOx Sensor Compact Potentiometric NOx Sensor 2011 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation...

Note: This page contains sample records for the topic "nox ods voc" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

9, 11231155, 2009 Lightning NOx  

E-Print Network [OSTI]

of lightning intensities. By im-20 posing an updated lightning NO production value of 520 mol NO/Flash, weACPD 9, 1123­1155, 2009 Lightning NOx emissions over the USA investigated using TES L. Jourdain et to the corresponding final paper in ACP if available. Lightning NOx emissions over the USA investigated using TES, NLDN

22

NETL: Advanced NOx Emissions Control: Control Technology - Model for NOx  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Model for NOx Emissions in Biomass Cofiring Model for NOx Emissions in Biomass Cofiring Southern Research Institute is developing a validated tool or methodology to accurately and confidently design and optimize biomass-cofiring systems for full-scale utility boilers to produce the lowest NOX emissions and the least unburned carbon. The computer model will be validated through an extensive set of tests at the 6 MMBtu/hr pilot combustor in the Southern Company/Southern Research Institute Combustion Research Facility. Full-scale demonstration testing can be compared to the model for further validation. The project is designed to balance the development of a systematic and expansive database detailing the effects of cofiring parameters on NOx formation with the complementary modeling effort that will yield a capability to predict, and therefore optimize, NOx reductions by the selection of those parameters. The database of biomass cofiring results will be developed through an extensive set of pilot-scale tests at the Southern Company/Southern Research Institute Combustion Research Facility. The testing in this program will monitor NOx, LOI, and other emissions over a broad domain of biomass composition, coal quality, and cofiring injection configurations to quantify the dependence of NOx formation and LOI on these parameters. This database of cofiring cases will characterize an extensive suite of emissions and combustion properties for each of the fuel and injection configuration combinations tested.

23

Nox1 and Nox4 enzymes are persistently elevated in human hepatocytes producing infectious hepatitis C virus  

E-Print Network [OSTI]

location of NOX4 and NOX1 enzymes by cell fractionation. 6.13. Proposed role of hepatocyte NOX enzymes in HCV-inducedMERCED Nox1 and Nox4 enzymes are persistently elevated in

Reyes de Mochel, Nabora Soledad

2009-01-01T23:59:59.000Z

24

presentation ODS workshop dryepondt.pptx  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

and lifetime predictions and lifetime predictions of FeCrAl-ODS components S. Dryepondt, B. Pint , I. Wright Materials Science & Technology Division, ORNL November 17-18, 2010, ODS workshop La Jolla, CA 2 Managed by UT-Battelle for the U.S. Department of Energy Durability of ODS alloys -! Depends on the service conditions: temperature, stress, cycles... -! High temperature creep and oxidation are expected to be the main mode of degradation -! Existence of a stress threshold at a given temperature below which deformation is minimum -! For a mechanically sound component, oxidation will determine the components durability 3 Managed by UT-Battelle for the U.S. Department of Energy Durability depends on the time to break away oxidation Low mass change = growth and spallation of Al

25

VOC Destruction by Catalytic Combustion Microturbine  

SciTech Connect (OSTI)

This project concerned the application of a catalytic combustion system that has been married to a micro-turbine device. The catalytic combustion system decomposes the VOC's and transmits these gases to the gas turbine. The turbine has been altered to operate on very low-level BTU fuels equivalent to 1.5% methane in air. The performance of the micro-turbine for VOC elimination has some flexibility with respect to operating conditions, and the system is adaptable to multiple industrial applications. The VOC source that was been chosen for examination was the emissions from coal upgrading operations. The overall goal of the project was to examine the effectiveness of a catalytic combustion based system for elimination of VOCs while simultaneously producing electrical power for local consumption. Project specific objectives included assessment of the feasibility for using a Flex-Microturbine that generates power from natural gas while it consumes VOCs generated from site operations; development of an engineering plan for installation of the Flex-Microturbine system; operation of the micro-turbine through various changes in site and operation conditions; measurement of the VOC destruction quantitatively; and determination of the required improvements for further studies. The micro-turbine with the catalytic bed worked effectively to produce power on levels of fuel much lower than the original turbine design. The ability of the device to add or subtract supplemental fuel to augment the amount of VOC's in the inlet air flow made the device an effective replacement for a traditional flare. Concerns about particulates in the inlet flow and the presence of high sulfur concentrations with the VOC mixtures was identified as a drawback with the current catalytic design. A new microturbine design was developed based on this research that incorporates a thermal oxidizer in place of the catalytic bed for applications where particulates or contamination would limit the lifetime of the catalytic bed.

Tom Barton

2009-03-10T23:59:59.000Z

26

Transient Dynamometer Testing of a Single Leg NOx Adsorber Combined...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Transient Dynamometer Testing of a Single Leg NOx Adsorber Combined with a Fuel Processor for Enhanced NOx Control Transient Dynamometer Testing of a Single Leg NOx Adsorber...

27

Benchmark Reaction Mechanisms and Kinetics for Lean NOx Traps...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Benchmark Reaction Mechanisms and Kinetics for Lean NOx Traps Development of Chemical Kinetic Models for Lean NOx Traps Modeling the Regeneration Chemistry of Lean NOx Traps...

28

VOC transport in vented drums containing simulated waste sludge  

SciTech Connect (OSTI)

A model is developed to estimate the volatile organic compound (VOC) concentration in the headspace of the innermost layer of confinement in a lab-scale vented waste drum containing simulated waste sludge. The VOC transport model estimates the concentration using the measured VOC concentration beneath the drum lid and model parameters defined or estimated from process knowledge of drum contents and waste drum configuration. Model parameters include the VOC diffusion characteristic across the filter vent, VOC diffusivity in air, size of opening in the drum liner lid, the type and number of layers of polymer bags surrounding the waste, VOC permeability across the polymer, and the permeable surface area of the polymer bags. Comparison of model and experimental results indicates that the model can accurately estimate VOC concentration in the headspace of the innermost layer of confinement. The model may be useful in estimating the VOC concentration in actual waste drums.

Liekhus, K.J.; Gresham, G.L.; Rae, C.; Connolly, M.J.

1994-02-01T23:59:59.000Z

29

Control of NOx by combustion process modifications  

E-Print Network [OSTI]

A theoretical and experimental study was carried out to determine lower bounds of NOx emission from staged combustion of a 0.7%N #6 fuel oil. Thermodynamic and chemical kinetic calculations have shown minimum NOx emissions ...

Ber?, J. M.

1981-01-01T23:59:59.000Z

30

VOC reduction strategies for the aerospace industry  

SciTech Connect (OSTI)

The aerospace NESHAP, which was issued on September 1, 1995, requires reductions in Volatile Organic Compounds (VOCs) and organic Hazardous Air Pollutant (HAP) emissions associated with the application of primer and topcoat. The regulation affects any facility that is a major source of HAPs and produces, reworks, or repairs, in any amount any commercial, civil, or military aerospace vehicle. Options for reducing VOC and organic HAP emissions include use of low VOC/organic HAP containing coatings or implementation of air pollution control systems. Use of primers and topcoats that meet the regulatory limits for VOC and organic HAP content is clearly the lowest cost option of meeting requirements of the aerospace NESHAP. However, some facilities have been unsuccessful in identifying aerospace paints and primers that meet requirements of the NESHAP and also have acceptable performance properties. For those aerospace companies considering implementation of air pollution control systems, several strategies can help to reduce the anticipated capital and operating costs. Such strategies include: segregation of specialty coatings, non-aerospace coatings, and low-use coatings not affected by the aerospace NESHAP from regulated paints and primers; reduction of airflows in affected booths; recirculation of air; and combination of exhausts from one or more booth. Estimated capital and operating costs are also provided for the air pollution control systems best suited for aircraft painting and priming operations. These systems include regenerative thermal oxidizers and fluidized bed/rotary concentrators in conjunction with thermal oxidizers. Even after implementing strategies to reduce VOC and organic HAP pollution control system costs, economics will dictate use of compliant primers and topcoats for many aerospace companies. 6 refs.

Bauer, J.P. [Burns & McDonnell, Kansas City, MO (United States)

1996-12-31T23:59:59.000Z

31

Embedded Electronic Nose for VOC Mixture Analysis  

SciTech Connect (OSTI)

This paper details the work done towards a low cost, small size, portable embedded electronic nose (e-nose) and its application for analysis of different VOC mixtures. The sensor array is composed of commercially available metal oxide semiconductor sensors by Figaro. The embedded E-nose consists of an ADuC831 and has an RS 232 interface for Desktop PC for higher level data collection and NN training. The ESP tool with database facility and multilayer perceptron neural network (MLP NN) is employed to interface the embedded hardware and to process the electronic nose signals before being classified. The use of embedded e-nose for the quantification of VOCs in mixtures is investigated.

Botre, B.; Gharpure, D.; Shaligram, A. [Department of Electronic Science, University of Pune, Pune: 411007 (India)

2009-05-23T23:59:59.000Z

32

VOC compliance on the ball: Aluminum can manufacturer rolls to California VOC compliance  

SciTech Connect (OSTI)

Since entering the North American beverage can market in 1969, Ball Corp., has increased its market share at a pace more than double the growth of the market itself. In addition to holding numerous patented advancements in can-making technology, Ball prides itself as an environmentally responsible company. When Ball decided to increase production capacity in its Fairfield, California, plant, the challenge was to produce more cans, while still complying with the state`s stringent air emissions regulations. As with other aluminum can manufacturing facilities, Ball`s coating and curing operations generate volatile organic compounds (VOCs). Ball`s permit from the state of California allows only limited amounts of VOC discharges into the atmosphere. With proposed increases in production capacities, however, the Bay Area`s Air Quality Management District--a local US EPA authority--required Ball to incinerate far more VOCs than the existing recuperative abatement system could handle. According to California regulations, facilities that wish to increase VOC emissions must install some type of VOC-control system or provide technological offsets. This regulatory pressure led Ball to seek a solution that would not only comply with emissions regulations, but would not compromise the company`s production process. Ball engineers selected a regenerative thermal oxidizer (RTO) for the Fairfield, Calif., plant. Considering the success Ball has encountered in previous experiences with this type of oxidation unit, the company immediately selected an RTO instead of catalytic oxidizers or other types of pollution control equipment.

Gay, R. [Engelhard Corp., Iselin, NJ (United States)

1997-07-01T23:59:59.000Z

33

NETL: Advanced NOx Emissions Control: Control Technology - Ultra Low-NOx  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Ultra Low NOx Integrated System Ultra Low NOx Integrated System TFS 2000(tm) Low NOx Firing System Project Summary: ALSTOM Power Inc.'s Power Plant Laboratories, working in concert with ALSTOM Power's Performance Projects Group, has teamed with the U.S. Department of Energy's National Energy Technology Laboratory (DOE NETL) to conduct a comprehensive study to develop/evaluate low-cost, efficient NOx control technologies for retrofit to pulverized coal fired utility boilers. The objective of this project was to develop retrofit NOx control technology to achieve less than 0.15 lb/MMBtu NOx (for bituminous coals) and 0.10 lb/MMBtu NOx (for subbituminous coals) from existing pulverized coal fired utility boilers at a cost which is at least 25% less than SCR technology. Efficient control of NOx is seen as an important,

34

Reducing NOx in Fired Heaters and Boilers  

E-Print Network [OSTI]

-6, 2000 Reducing NOx in Fired Heaters Air Pollution Control and Boilers Keeping the environment clean Presented by Ashutosh Garg Furnace Improvements Low cost solutions for fired heaters Trace compounds ? Nitric oxides ? Carbon monoxide ? Sulfur... it is essential to estimate accurately baseline NOx emissions. ? This will establish each units current compliance status. ? Emissions ? Current excess air level ? Carbon monoxide ? Combustibles ? NOx corrected to 3% 02 314 ESL-IE-00-04-46 Proceedings...

Garg, A.

35

CLEERS Activities: Diesel Soot Filter Characterization & NOx...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Control Fundamentals CLEERS Activities: Diesel Soot Filter Characterization & NOx Control Fundamentals 2009 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit...

36

Fe Promoted NOx Storage Materials: Structural Properties and NOx Uptake  

Science Journals Connector (OSTI)

According to the European Union regulations (EURO VI),(2) by the end of 2014, diesel passenger cars will be subject to a 3-fold decrease in NOx emissions from 0.25 to 0.08 g km?1. ... Barium oxide crystallizes in the rock salt structure, and the first order Raman scattering is symmetry forbidden(32, 33) However, broad and weak bands within 350?500 cm?1 due to the lattice modes of the defective BaO domains can still be visible via Raman spectroscopy (see for instance, Figure 3 in the Supporting Information). ...

Emine Kayhan; Stanislava M. Andonova; Go?ksu S. S?entu?rk; Charles C. Chusuei; Emrah Ozensoy

2009-12-11T23:59:59.000Z

37

NETL: Advanced NOx Emissions Control: Control Technology - NOx Combustion  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Control Options and Integration Control Options and Integration Reaction Engineering International (REI) is optimizing the performance of, and reduce the technical risks associated with the combined application of low-NOx firing systems (LNFS) and post combustion controls through modeling, bench-scale testing, and field verification. Teaming with REI are the University of Utah and Brown University. During this two-year effort, REI will assess real-time monitoring equipment to evaluate waterwall wastage, soot formation, and burner stoichiometry, demonstrate analysis techniques to improve LNFS in combination with reburning/SNCR, assess selective catalytic reduction catalyst life, and develop UBC/fly ash separation processes. The REI program will be applicable to coal-fired boilers currently in use in the United States, including corner-, wall-, turbo-, and cyclone-fired units. However, the primary target of the research will be cyclone boilers, which are high NOx producing units and represent about 20% of the U.S. generating capacity. The results will also be applicable to all U.S. coals. The research will be divided into four key components:

38

Transmural Catalysis - High Efficiency Catalyst Systems for NOx...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Transmural Catalysis - High Efficiency Catalyst Systems for NOx Adsorbers and SCR Transmural Catalysis - High Efficiency Catalyst Systems for NOx Adsorbers and SCR Presentation...

39

SCR Technologies for NOx Reduction | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Technologies for NOx Reduction SCR Technologies for NOx Reduction 2005 Diesel Engine Emissions Reduction (DEER) Conference Presentations and Posters 2005deerhesser.pdf More...

40

An Improvement of Diesel PM and NOx Reduction System | Department...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

& Publications Development on simultaneous reduction system of NOx and PM from a diesel engine An Improvement of Diesel PM and NOx Reduction System New Diesel Emissions...

Note: This page contains sample records for the topic "nox ods voc" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Development on simultaneous reduction system of NOx and PM from...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

More Documents & Publications An Improvement of Diesel PM and NOx Reduction System An Improvement of Diesel PM and NOx Reduction System EPA Mobile Source Rule Update...

42

Passive Catalytic Approach to Low Temperature NOx Emission Abatement...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Catalytic Approach to Low Temperature NOx Emission Abatement Passive Catalytic Approach to Low Temperature NOx Emission Abatement Numerically evaluated and optimized proposed...

43

Three-Dimensional Composite Nanostructures for Lean NOx Emission...  

Broader source: Energy.gov (indexed) [DOE]

Three-Dimensional Composite Nanostructures for Lean NOx Emission Control Three-Dimensional Composite Nanostructures for Lean NOx Emission Control 2010 DOE Vehicle Technologies and...

44

Effect of Biodiesel Blends on NOx Emissions | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Biodiesel Blends on NOx Emissions Effect of Biodiesel Blends on NOx Emissions Poster presentation at the 2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER 2007)....

45

H2-Assisted NOx Traps: Test Cell Results Vehicle Installations...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

H2-Assisted NOx Traps: Test Cell Results Vehicle Installations H2-Assisted NOx Traps: Test Cell Results Vehicle Installations 2003 DEER Conference Presentation: ArvinMeritor...

46

Enhanced High and Low Temperature Performance of NOx Reduction...  

Broader source: Energy.gov (indexed) [DOE]

Enhanced High and Low Temperature Performance of NOx Reduction Materials Enhanced High and Low Temperature Performance of NOx Reduction Materials 2013 DOE Hydrogen and Fuel Cells...

47

Virtual Oxygen Sensor for Innovative NOx and PM Emission Control...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Virtual Oxygen Sensor for Innovative NOx and PM Emission Control Technologies Virtual Oxygen Sensor for Innovative NOx and PM Emission Control Technologies A virtual O2 sensor for...

48

Modeling the Regeneration Chemistry of Lean NOx Traps | Department...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

the Regeneration Chemistry of Lean NOx Traps Modeling the Regeneration Chemistry of Lean NOx Traps Presentation given at DEER 2006, August 20-24, 2006, Detroit, Michigan. Sponsored...

49

Electrochemical NOxSensor for Monitoring Diesel Emissions | Department...  

Broader source: Energy.gov (indexed) [DOE]

Diesel Emissions Electrochemical NOxSensor for Monitoring Diesel Emissions pm02glass.pdf More Documents & Publications Electrochemical NOx Sensor for Monitoring Diesel...

50

IEP - Advanced NOx Emissions Control: Regulatory Drivers  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

IEP - Advanced NOx Emissions Control Regulatory Drivers Regulatory Drivers for Existing Coal-Fired Power Plants Regulatory and legislative requirements have predominantly driven the need to develop NOx control technologies for existing coal-fired power plants. The first driver was the Title IV acid rain program, established through the 1990 Clean Air Act Amendments (CAAA). This program included a two-phase strategy to reduce NOx emissions from coal-fired power plants – Phase I started January 1, 1996 and Phase II started January 1, 2000. The Title IV NOx program was implemented through unit-specific NOx emission rate limits ranging from 0.40 to 0.86 lb/MMBtu depending on the type of boiler/burner configuration and based on application of LNB technology.

51

E-Print Network 3.0 - air voc flow Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Geosciences 28 ACCEPTED BY WATER ENVIRONMENT RESEARCH ODOR AND VOC REMOVAL FROM WASTEWATER TREATMENT PLANT Summary: of biofilters for sequential removal of H2S and VOCs from...

52

Ambient air VOC concentrations at WIPP  

SciTech Connect (OSTI)

The Waste Isolation Pilot Plant (WIPP), located near Carlsbad, New Mexico, is an underground facility designated as a potential repository for transuranic wastes. Approximately 60% of the wastes proposed to be emplaced at the WIPP are considered mixed wastes, which contain both radioactive and Resource Conservation and Recovery Act-regulated hazardous chemical components. As part of the Addendum to the WIPP No-Migration Variance Petition', the US Department of Energy presented a plan to monitor the release of volatile organic compounds (VOCs) from the WIPP unit boundary. This program should fulfill the monitoring requirements of 40CFR268.6 allowing the disposal of wastes prohibited from land disposal only after demonstration that, to a reasonable degree of certainty, there will be no migration of constituents from the disposal unit for as long as the wastes remain hazardous.

Wu, C.F.; Frank-Supka, L. (Westinghouse Waste Isolation Division, Carlsbad, NM (United States)); Zimmer, R.A. (Harding Lawson Associates, Denver, CO (United States))

1993-01-01T23:59:59.000Z

53

Low NOx combustion system for heavy oil  

SciTech Connect (OSTI)

As a result of the increasing demand for white oil as one of countermeasures for pollution control and as a fuel for motor vehicle, coupled with the increasing import of heavy crude oil, heavy oils such as asphalt and distillation residue have become surplus in Japan. It is difficult by the conventional low NOx technology to control the NOx emission from the industrial small and medium capacity boilers, which use heavy oil as their fuels. The authors have been developing and improving NOx control technologies for boilers such as low NOx burners, two-stage combustion methods and so on. They have developed a new combustion system for heavy oil, which generates less NOx and soot than conventional systems, by applying the knowledge, obtained in the course of their development of Coal Partial Combustor (CPC). The conventional low NOx combustion method for oil firing boilers has been developed based on decreasing the flame temperature and delaying the combustion reaction. In the system, however, the heavy oil shall be combusted in the intense reducing atmosphere at the high flame temperature between 1,500 C and 1,600 C, and then the combustions gas shall be cooled and oxidized by two-stage combustion air. With this system, NOx emission can be suppressed below 100ppm (converted as O{sub 2}=4%).

Kurata, Chikatoshi; Sasaki, Hideki

1999-07-01T23:59:59.000Z

54

Quantifying VOC emissions for the strategic petroleum reserve.  

SciTech Connect (OSTI)

A very important aspect of the Department of Energy's (DOE's) Strategic Petroleum Reserve (SPR) program is regulatory compliance. One of the regulatory compliance issues deals with limiting the amount of volatile organic compounds (VOCs) that are emitted into the atmosphere from brine wastes when they are discharged to brine holding ponds. The US Environmental Protection Agency (USEPA) has set limits on the amount of VOCs that can be discharged to the atmosphere. Several attempts have been made to quantify the VOC emissions associated with the brine ponds going back to the late 1970's. There are potential issues associated with each of these quantification efforts. Two efforts were made to quantify VOC emissions by analyzing VOC content of brine samples obtained from wells. Efforts to measure air concentrations were mentioned in historical reports but no data have been located to confirm these assertions. A modeling effort was also performed to quantify the VOC emissions. More recently in 2011- 2013, additional brine sampling has been performed to update the VOC emissions estimate. An analysis of the statistical confidence in these results is presented here. Arguably, there are uncertainties associated with each of these efforts. The analysis herein indicates that the upper confidence limit in VOC emissions based on recent brine sampling is very close to the 0.42 ton/MMB limit used historically on the project. Refining this estimate would require considerable investment in additional sampling, analysis, and monitoring. An analysis of the VOC emissions at each site suggests that additional discharges could be made and stay within current regulatory limits.

Knowlton, Robert G.; Lord, David L.

2013-06-01T23:59:59.000Z

55

Ammonia-Free NOx Control System  

SciTech Connect (OSTI)

Research is being conducted under United States Department of Energy (DOE) Contract DEFC26-03NT41865 to develop a new technology to achieve very low levels of NOx emissions from pulverized coal fired boiler systems by employing a novel system level integration between the PC combustion process and the catalytic NOx reduction with CO present in the combustion flue gas. The combustor design and operating conditions will be optimized to achieve atypical flue gas conditions. This approach will not only suppress NOx generation during combustion but also further reduce NOx over a downstream catalytic reactor that does not require addition of an external reductant, such as ammonia. This report describes the work performed during the January 1 to March 31, 2004 time period.

S. Wu; Z. Fan; R. Herman

2004-03-31T23:59:59.000Z

56

Ammonia-Free NOx Control System  

SciTech Connect (OSTI)

Research is being conducted under United States Department of Energy (DOE) Contract DEFC26-03NT41865 to develop a new technology to achieve very low levels of NOx emissions from pulverized coal fired boiler systems by employing a novel system level integration between the PC combustion process and the catalytic NOx reduction with CO present in the combustion flue gas. The combustor design and operating conditions will be optimized to achieve atypical flue gas conditions. This approach will not only suppress NOx generation during combustion but also further reduce NOx over a downstream catalytic reactor that does not require addition of an external reductant, such as ammonia. This report describes the work performed during the October 1 to December 31, 2003 time period.

S. Wu

2003-12-31T23:59:59.000Z

57

A Return Stroke NOx Production Model  

Science Journals Connector (OSTI)

A model is introduced for estimating the nitrogen oxides (NOx = NO + NO2) production from a lightning return stroke channel. A realistic Modified Transmission Line Model return stroke current is assumed to propagate vertically upward along a ...

William J. Koshak; Richard J. Solakiewicz; Harold S. Peterson

58

Electrochemical NOx Sensors for Monitoring Diesel Emissions  

Broader source: Energy.gov [DOE]

A unique electrochemical sensing strategy correlating the level of NOx with an impedance-based signal shows promise for sensitivity, stability, and accuracy while incorporating single-cell structures and simple electronics into low-cost designs

59

Regenerative thermal oxidation and alternative technologies for VOC control  

SciTech Connect (OSTI)

Thermal oxidation technologies have been used successfully to control VOC`s for many years but the recent 1990 Clean Air Act Amendments have spurred improvements in the established processes and development of economic alternatives. The combination of the regulatory maze and confusion in the selection of the best technology for a particular application has created a potential nightmare for those companies facing a need to reduce their VOC EMISSIONS. The relative advantages and disadvantages of regenerative, recuperative and catalytic oxidizers will be reviewed, with an emphasis on the economic justification for regenerative thermal oxidation (RTO). Control efficiencies of more than 99% have been demonstrated for RTO`s on a multitude of industrial process exhaust streams. Lowest evaluated cost over a fifteen to twenty year effective equipment life is a key selection criteria. This paper describes the underlying principles of thermal oxidation, and discusses the applicability of these and other emerging technologies for VOC control.

Biedell, E.L. [REECQ, Somerville, NJ (United States)

1995-12-31T23:59:59.000Z

60

OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL  

SciTech Connect (OSTI)

Conventional wisdom says adding oxygen to a combustion system enhances product throughput, system efficiency, and, unless special care is taken, increases NOx emissions. This increase in NOx emissions is typically due to elevated flame temperatures associated with oxygen use leading to added thermal NOx formation. Innovative low flame temperature oxy-fuel burner designs have been developed and commercialized to minimize both thermal and fuel NOx formation for gas and oil fired industrial furnaces. To be effective these systems require close to 100% oxy-fuel combustion and the cost of oxygen is paid for by fuel savings and other benefits. For applications to coal-fired utility boilers at the current cost of oxygen, however, it is not economically feasible to use 100% oxygen for NOx control. In spite of this conventional wisdom, Praxair and its team members, in partnership with the US Department of Energy National Energy Technology Laboratory, have developed a novel way to use oxygen to reduce NOx emissions without resorting to complete oxy-fuel conversion. In this concept oxygen is added to the combustion process to enhance operation of a low NOx combustion system. Only a small fraction of combustion air is replaced with oxygen in the process. By selectively adding oxygen to a low NOx combustion system it is possible to reduce NOx emissions from nitrogen-containing fuels, including pulverized coal, while improving combustion characteristics such as unburned carbon. A combination of experimental work and modeling was used to define how well oxygen enhanced combustion could reduce NOx emissions. The results of this work suggest that small amounts of oxygen replacement can reduce the NOx emissions as compared to the air-alone system. NOx emissions significantly below 0.15 lbs/MMBtu were measured. Oxygen addition was also shown to reduce carbon in ash. Comparison of the costs of using oxygen for NOx control against competing technologies, such as SCR, show that this concept offers substantial savings over SCR and is an economically attractive alternative to purchasing NOx credits or installing other conventional technologies. In conjunction with the development of oxygen based low NOx technology, Praxair also worked on developing the economically enhancing oxygen transport membrane (OTM) technology which is ideally suited for integration with combustion systems to achieve further significant cost reductions and efficiency improvements. This OTM oxygen production technology is based on ceramic mixed conductor membranes that operate at high temperatures and can be operated in a pressure driven mode to separate oxygen with infinite selectivity and high flux. An OTM material was selected and characterized. OTM elements were successfully fabricated. A single tube OTM reactor was designed and assembled. Testing of dense OTM elements was conducted with promising oxygen flux results of 100% of target flux. However, based on current natural gas prices and stand-alone air separation processes, ceramic membranes do not offer an economic advantage for this application. Under a different DOE-NETL Cooperative Agreement, Praxair is continuing to develop oxygen transport membranes for the Advanced Boiler where the economics appear more attractive.

David R. Thompson; Lawrence E. Bool; Jack C. Chen

2004-04-01T23:59:59.000Z

Note: This page contains sample records for the topic "nox ods voc" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

New CoO?SiO2-Sol Pillared Clays as Catalysts for NOx Conversion  

Science Journals Connector (OSTI)

For this purpose, codoped SiO2 sol PILC (CoSi?PILC) is prepared via an organic template route and the interlayer pillar structure is systematically investigated by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), X-ray absorption spectroscopy (XAS), and nitrogen adsorption isotherm measurement, along with a preliminary test on the de-NOx catalytic activity. ... The steady-state selective catalytic reduction of NO with CO over CoSi?PILC catalyst was carried out in an isothermal fixed-bed continuous flow quartz reactor (o.d. ... The elemental composition of CoSi?PILC was analyzed to estimate the pillar content of SiO2 and CoO. ...

Jin-Ho Choy; Hyun Jung; Yang-Su Han; Joo-Byoung Yoon; Yong-Gun Shul; Hyun-Jong Kim

2002-08-20T23:59:59.000Z

62

Microsoft PowerPoint - Webinar Austenitic ODS NEUP.pptx  

Broader source: Energy.gov (indexed) [DOE]

Austenitic ODS Austenitic ODS Strengthened Alloys for Very High Temperature Applications Yinbin Miao, Kun Mo, Guangming Zhang, Bai Cui, Wei-Ying Chen, Virginia McCreary, David Gross, Ian M. Robertson, James F. Stubbins Department of Nuclear, Plasma and Radiological Engineering University of Illinois at Urbana-Champaign Overview Orientation Relationship of Nanoparticles Particle-Dislocation Interaction Synchrotron Radiation Studies Challenges  Interest in high temperature metal-base alloys for very high temperature applications - primarily driven by heat exchange and energy conversion applications in VHTRs  Lead high temperature alloys are: Inconel 617 (Alloy 617) and Haynes 230 (Alloy 230) - based around Ni-20Cr (nichrome) - MA 754

63

Oil and Gas Recovery Data from the Riser Insertion Tub - ODS...  

Broader source: Energy.gov (indexed) [DOE]

ODS Oil and Gas Recovery Data from the Riser Insertion Tub - ODS Oil and Gas Recovery Data from the Riser Insertion Tube from May 17 until the Riser Insertion Tube was disconnected...

64

Ammonia Sensor for SCR NOX Reduction | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Sensor for SCR NOX Reduction Ammonia Sensor for SCR NOX Reduction Presentation given at the 2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER 2007). 13-16 August,...

65

Lean NOx Reduction with Dual Layer LNT/SCR Catalysts  

Broader source: Energy.gov [DOE]

Results show that a series of dual layer catalysts with a bottom layer of LNT catalyst and a top layer of SCR catalyst can carry out coupled ammonia generation and NOx reduction, achieving high NOx conversion with minimal ammonia slip

66

Enhanced Combustion Low NOx Pulverized Coal Burner  

SciTech Connect (OSTI)

For more than two decades, Alstom Power Inc. (Alstom) has developed a range of low cost, infurnace technologies for NOx emissions control for the domestic U.S. pulverized coal fired boiler market. This includes Alstom's internally developed TFS 2000{trademark} firing system, and various enhancements to it developed in concert with the U.S. Department of Energy. As of the date of this report, more than 270 units representing approximately 80,000 MWe of domestic coal fired capacity have been retrofit with Alstom low NOx technology. Best of class emissions range from 0.18 lb/MMBtu for bituminous coal to 0.10 lb/MMBtu for subbituminous coal, with typical levels at 0.24 lb/MMBtu and 0.13 lb/MMBtu, respectively. Despite these gains, NOx emissions limits in the U.S. continue to ratchet down for new and existing boiler equipment. On March 10, 2005, the Environmental Protection Agency (EPA) announced the Clean Air Interstate Rule (CAIR). CAIR requires 25 Eastern states to reduce NOx emissions from the power generation sector by 1.7 million tons in 2009 and 2.0 million tons by 2015. Low cost solutions to meet such regulations, and in particular those that can avoid the need for a costly selective catalytic reduction system (SCR), provide a strong incentive to continue to improve low NOx firing system technology to meet current and anticipated NOx control regulations. The overall objective of the work is to develop an enhanced combustion, low NOx pulverized coal burner, which, when integrated with Alstom's state-of-the-art, globally air staged low NOx firing systems will provide a means to achieve: Less than 0.15 lb/MMBtu NOx emissions when firing a high volatile Eastern or Western bituminous coal, Less than 0.10 lb/MMBtu NOx emissions when firing a subbituminous coal, NOx reduction costs at least 25% lower than the costs of an SCR, Validation of the NOx control technology developed through large (15 MWt) pilot scale demonstration, and Documentation required for economic evaluation and commercial application. During the project performance period, Alstom performed computational fluid dynamics (CFD) modeling and large pilot scale combustion testing in its Industrial Scale Burner Facility (ISBF) at its U.S. Power Plant Laboratories facility in Windsor, Connecticut in support of these objectives. The NOx reduction approach was to optimize near-field combustion to ensure that minimum NOx emissions are achieved with minimal impact on unburned carbon in ash, slagging and fouling, corrosion, and flame stability/turn-down. Several iterations of CFD and combustion testing on a Midwest coal led to an optimized design, which was extensively combustion tested on a range of coals. The data from these tests were then used to validate system costs and benefits versus SCR. Three coals were evaluated during the bench-scale and large pilot-scale testing tasks. The three coals ranged from a very reactive subbituminous coal to a moderately reactive Western bituminous coal to a much less reactive Midwest bituminous coal. Bench-scale testing was comprised of standard ASTM properties evaluation, plus more detailed characterization of fuel properties through drop tube furnace testing and thermogravimetric analysis. Bench-scale characterization of the three test coals showed that both NOx emissions and combustion performance are a strong function of coal properties. The more reactive coals evolved more of their fuel bound nitrogen in the substoichiometric main burner zone than less reactive coal, resulting in the potential for lower NOx emissions. From a combustion point of view, the more reactive coals also showed lower carbon in ash and CO values than the less reactive coal at any given main burner zone stoichiometry. According to bench-scale results, the subbituminous coal was found to be the most amenable to both low NOx, and acceptably low combustibles in the flue gas, in an air staged low NOx system. The Midwest bituminous coal, by contrast, was predicted to be the most challenging of the three coals, with the Western bituminous coal predicted to beh

David Towle; Richard Donais; Todd Hellewell; Robert Lewis; Robert Schrecengost

2007-06-30T23:59:59.000Z

67

NETL: Advanced NOx Emissions Control: Control Technology - Methane de-NOx  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

METHANE de-NOx® METHANE de-NOx® The Gas Technology Institute (GTI) is teaming with the All-Russian Thermal Engineering Institute and DB Riley to develop a pulverized-coal (PC)-combustion system that is an extension of IGT's METHANE de-NOx® technology. The technology is composed of a novel PC burner design using natural gas fired coal preheating developed and demonstrated in Russia, LNBs with internal combustion staging, and additional natural gas injection with overfire air. The coal is preheated at elevated temperatures (up to 1500oF) in oxygen deficient conditions prior to combustion. Coal preheat releases fuel-bound nitrogen together with volatiles present in the coal. These conditions promote the conversion of fuel-bound nitrogen to molecular nitrogen rather than to NOx.

68

Modeling VOC sorption of building materials and its impact on indoor air quality  

E-Print Network [OSTI]

Sorption of volatile organic compounds (VOCs) by building materials can have significant effect on the indoor VOC concentration levels and indoor air quality in buildings. The objective of this study was to investigate ...

Zhang, Jinsong, 1975-

2001-01-01T23:59:59.000Z

69

The Emissions of Major Aromatic Voc as Landfill Gas from Urban Landfill Sites in Korea  

Science Journals Connector (OSTI)

In this study, concentrations of major aromatic VOCs were determined from landfill gas (LFG) at a total of five...?1 (WJ in wintertime). The LFG flux values of aromatic VOC, when compared to the contribution of n...

Ki-Hyun Kim; Sung Ok Baek; Ye-Jin Choi

2006-07-01T23:59:59.000Z

70

VOC Emission Control with the Brayton Cycle Pilot Plant Operations  

E-Print Network [OSTI]

A mobile pilot plant capable of removing VOC emissions from exhaust air streams was cooperatively funded by SCE, EPRI, 3M, and NUCON. Valuable information about the process and the recovery operation has been gained by performing tests at a number...

Enneking, J. C.

71

ORIGINAL PAPER L. Voc adlo K. S. Knight G. D. Price I. G. Wood  

E-Print Network [OSTI]

ORIGINAL PAPER L. VocÏ adlo á K. S. Knight á G. D. Price á I. G. Wood Thermal expansion and crystal discussed by Wood et al. (1996), VocÏ adlo et al. (1999, 2000) and Mattheiss and Hamann (1993002690100202 L. VocÏ adlo (&) á G. D. Price á I. G. Wood Department of Geological Sciences, University College

Vocadlo, Lidunka

72

HELSINKI UNIVERSITY OF TECHNOLOGY ENE-47.153 VOCsVOCs,, PAHsPAHs, soot, tar, CO, soot, tar, CO  

E-Print Network [OSTI]

oxides in the presence of sunlight" (McConville, 1997) PAH polycyclic aromatic hydrocarbon tar or liquid fuel components during combustion THC,TOC totalhydrocarbon,totalorganiccarbon HAP (USA with heat recuperationThermal VOC incinerator with heat recuperation 150150EEEEF=66F=66EEEEC, 600C, 600EEEEF

Zevenhoven, Ron

73

Lower Freezing DEF For Higher NOx Reduction Attainment  

Broader source: Energy.gov [DOE]

NOx emissions data from bench-scale experiments and Class III truck operated using a low freezing point diesel exhaust fluid

74

Cummins/ORNL-FEERC CRADA: NOx Control & Measurement Technology...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

CumminsORNL-FEERC CRADA: NOx Control & Measurement Technology for Heavy-Duty Diesel Engines Vehicle Technologies Office Merit Review 2014: Cummins-ORNLFEERC Emissions CRADA:...

75

Unique Catalyst System for NOx Reduction in Diesel Exhaust |...  

Broader source: Energy.gov (indexed) [DOE]

More Documents & Publications Noxtechs PAC System Development and Demonstration Plasma Assisted Catalysis System for NOx Reduction Clean Diesel Engine Component Improvement...

76

Two Catalyst Formulations - One Solution for NOx After-treatment...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Two Catalyst Formulations - One Solution for NOx After-treatment Systems Low-temperature SCR combined with standard high-temperature SCR catalyst formulation in one system provides...

77

Measurement and Characterization of Lean NOx Adsorber Regeneration...  

Broader source: Energy.gov (indexed) [DOE]

for the Department of Energy Purpose of Work: Enable efficient lean engine market penetration by meeting emission regulations with aftertreatment * Research of Lean NOx...

78

Enhanced High and Low Temperature Performance of NOx Reduction...  

Broader source: Energy.gov (indexed) [DOE]

and Low Temperature Performance of NOx Reduction Materials 2013 DOE AMR Review This presentation does not contain any proprietary, confidential, or otherwise restricted...

79

NOx Adsorbers for Heavy Duty Truck Engines - Testing and Simulation...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Adsorbers for Heavy Duty Truck Engines - Testing and Simulation NOx Adsorbers for Heavy Duty Truck Engines - Testing and Simulation This report provides the results of an...

80

H2-Assisted NOx Traps: Test Cell Results Vehicle Installations  

Broader source: Energy.gov (indexed) [DOE]

Sam Crane August 28, 2003 H 2 -Assisted NOx Traps: Test Cell Results Vehicle Installations 2 Project Objectives * Determine Advantages of H 2 Assisted NO x Trap Regeneration *...

Note: This page contains sample records for the topic "nox ods voc" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Investigation of Aging Mechanisms in Lean NOx Traps | Department...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

"Mega" Merit Review 2008 on February 25, 2008 in Bethesda, Maryland. merit08johnson.pdf More Documents & Publications Investigation of Aging Mechanisms in Lean NOx Traps...

82

Fuel Processor Enabled NOx Adsorber Aftertreatment System for...  

Broader source: Energy.gov (indexed) [DOE]

for Diesel Engine Emissions Control R. Dalla Betta, D. Sheridan, J. Cizeron Catalytica Energy Systems Inc. Mountain View, California 2 Outline Why use a fuel processor for NOx...

83

Status of APBF-DEC NOx Adsorber/DPF Projects  

Broader source: Energy.gov (indexed) [DOE]

* Examine other fuel properties 6 OAK RIDGE NATIONAL LABORATORY U. S. DEPARTMENT OF ENERGY Each platform will determine effects of fuel properties on: * NOx and PM reduction...

84

Virtual Oxygen Sensor for Innovative NOx and PM Emission Control...  

Broader source: Energy.gov (indexed) [DOE]

2009 - Poster Session August 3 rd , Hyatt Regency Dearborn Hotel Virtual Oxygen Sensor Innovative NOx and PM Emission Control Technologies J. Seebode, E. Stlting,...

85

Three-Dimensional Composite Nanostructures for Lean NOx Emission...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Emission Control Catalysts Three-Dimensional Composite Nanostructures for Lean NOx Emission Control Ultra-efficient, Robust and Well-defined Nano-Array based Monolithic Catalysts...

86

Three-Dimensional Composite Nanostructures for Lean NOx Emission...  

Broader source: Energy.gov (indexed) [DOE]

Nanowire Lean NOx Emission Control Catalysts Ultra-efficient, Robust and Well-defined Nano-Array based Monolithic Catalysts Three-Dimensional Composite Nanostructures for Lean...

87

Passive Catalytic Approach to Low Temperature NOx Emission Abatement  

Broader source: Energy.gov [DOE]

Numerically evaluated and optimized proposed state-of-the-art passive catalytic technology designed to reduce NOx released during vehicle cold start portion of the FTP-75 cycle

88

Rapid Aging Protocols for Diesel Aftertreatment Devices: NOx...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Aftertreatment (Agreement 13415) Thermal Deactivation Mechanisms of Fully-Formed Lean NOx Trap Catalysts Aged by LeanRich Cycling Impacts of Biodiesel on Emission Control Devices...

89

Transient Dynamometer Testing of a Single-Leg NOX Adsorber Combined...  

Broader source: Energy.gov (indexed) [DOE]

Transient Dynamometer Testing of a Single-Leg NOX Adsorber Combined with a Fuel Processor for Enhanced NOx Control Transient Dynamometer Testing of a Single-Leg NOX Adsorber...

90

Fuel Consumption and NOx Trade-offs on a Port-Fuel-Injected SI...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Consumption and NOx Trade-offs on a Port-Fuel-Injected SI Gasoline Engine Equipped with a Lean-NOx Trap Fuel Consumption and NOx Trade-offs on a Port-Fuel-Injected SI Gasoline...

91

Low-NOx Gas Turbine Injectors Utilizing Hydrogen-Rich Opportunity...  

Broader source: Energy.gov (indexed) [DOE]

NOx Gas Turbine Injectors Utilizing Hydrogen-Rich Opportunity Fuels - Fact Sheet, 2011 Low-NOx Gas Turbine Injectors Utilizing Hydrogen-Rich Opportunity Fuels - Fact Sheet, 2011...

92

Ultra-Low NOx Advanced Vortex Combustor  

SciTech Connect (OSTI)

An ultra lean-premixed Advanced Vortex Combustor (AVC) has been developed and tested. The natural gas fueled AVC was tested at the U.S. Department of Energys National Energy Technology Laboratory (USDOE NETL) test facility in Morgantown (WV). All testing was performed at elevated pressures and inlet temperatures and at lean fuel-air ratios representative of industrial gas turbines. The improved AVC design exhibited simultaneous NOx/CO/UHC emissions of 4/4/0 ppmv (all emissions are at 15% O2 dry). The design also achieved less than 3 ppmv NOx with combustion efficiencies in excess of 99.5%. The design demonstrated tremendous acoustic dynamic stability over a wide range of operating conditions which potentially makes this approach significantly more attractive than other lean premixed combustion approaches. In addition, a pressure drop of 1.75% was measured which is significantly lower than conventional gas turbine combustors. Potentially, this lower pressure drop characteristic of the AVC concept translates into overall gas turbine cycle efficiency improvements of up to one full percentage point. The relatively high velocities and low pressure drops achievable with this technology make the AVC approach an attractive alternative for syngas fuel applications.

Edmonds, R.G. (Ramgen Power Systems, Inc., Bellevue, WA); Steele, R.C. (Ramgen Power Systems, Inc., Bellevue, WA); Williams, J.T. (Ramgen Power Systems, Inc., Bellevue, WA); Straub, D.L.; Casleton, K.H.; Bining, Avtar (California Energy Commission, Sacramento, CA)

2006-05-01T23:59:59.000Z

93

ULTRA-LOW NOX ADVANCED VORTEX COMBUSTOR  

SciTech Connect (OSTI)

An ultra lean-premixed Advanced Vortex Combustor (AVC) has been developed and tested. The natural gas fueled AVC was tested at the U.S. Department of Energys National Energy Technology Laboratory (USDOE NETL) test facility in Morgantown (WV). All testing was performed at elevated pressures and inlet temperatures and at lean fuel-air ratios representative of industrial gas turbines. The improved AVC design exhibited simultaneous NOx/CO/UHC emissions of 4/4/0 ppmv (all emissions are at 15% O2 dry). The design also achieved less than 3 ppmv NOx with combustion efficiencies in excess of 99.5%. The design demonstrated tremendous acoustic dynamic stability over a wide range of operating conditions which potentially makes this approach significantly more attractive than other lean premixed combustion approaches. In addition, a pressure drop of 1.75% was measured which is significantly lower than conventional gas turbine combustors. Potentially, this lower pressure drop characteristic of the AVC concept translates into overall gas turbine cycle efficiency improvements of up to one full percentage point. The relatively high velocities and low pressure drops achievable with this technology make the AVC approach an attractive alternative for syngas fuel applications.

Ryan G. Edmonds; Robert C. Steele; Joseph T. Williams; Douglas L. Straub; Kent H. Casleton; Avtar Bining

2006-05-01T23:59:59.000Z

94

OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL  

SciTech Connect (OSTI)

This quarterly technical progress report will summarize work accomplished for the Program through the twelfth quarter, January-March 2003, in the following task areas: Task 1--Oxygen Enhanced Combustion, Task 2--Oxygen Transport Membranes, Task 3--Economic Evaluation and Task 4--Program Management. The program is proceeding in accordance with the objectives for the third year. Pilot scale experiments conducted at the University of Utah explored both the effectiveness of oxygen addition and the best way to add oxygen with a scaled version of Riley Power's newest low NOx burner design. CFD modeling was done to compare the REI's modeling results for James River Unit 3 with the NOx and LOI results obtained during the demonstration program at that facility. Investigation of an alternative method of fabrication of PSO1d elements was conducted. OTM process development work has concluded with the completion of a long-term test of a PSO1d element Economic evaluation has confirmed the advantage of oxygen-enhanced combustion. Proposals have been submitted for two additional beta test sites. Commercial proposals have been submitted. Economic analysis of a beta site test performance was conducted.

David R. Thompson; Lawrence E. Bool; Jack C. Chen

2003-04-01T23:59:59.000Z

95

OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL  

SciTech Connect (OSTI)

This quarterly technical progress report will summarize work accomplished for the Program in the seventh quarter October-December 2001 in the following task areas: Task 1 - Oxygen Enhanced Combustion, Task 2 - Oxygen Transport Membranes, Task 3 - Economic Evaluation and Task 4 - Program Management. Computational fluid dynamic (CFD) modeling of oxygen injection strategies was performed during the quarter resulting in data that suggest the oxygen injection reduces NOx emissions while reducing LOI. Pilot-scale testing activities concluded at the University of Utah this quarter. Testing demonstrated that some experimental conditions can lead to NOx emissions well below the 0.15 lb/MMBtu limit. Evaluation of alternative OTM materials with improved mechanical properties continued this quarter. Powder procedure optimization continued and sintering trial began on an element with a new design. Several OTM elements were tested in Praxair's single tube high-pressure test facility under various conditions. A modified PSO1d element demonstrated stable oxygen product purity of >98% and oxygen flux of 68% of target. Updated test results and projected economic performance have been reviewed with the Utility Industrial Advisors. The economic comparison remains very favorable for O{sub 2} enhanced combustion. Discussions regarding possible Beta sites have been held with three other utilities in addition to the industrial advisors. Proposals will be prepared after the completion of full scale burner testing. Beta test cost estimating work has been initiated.

David R. Thompson; Lawrence E. Bool; Jack C. Chen

2002-01-01T23:59:59.000Z

96

NETL: Emissions Characterization - Adv. Low-NOx Burner Emissions  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Advanced Low-NOx Burner Emissions Characterization Advanced Low-NOx Burner Emissions Characterization The goal of this work is to develop a comprehensive, high-quality database characterizing PM2.5 emissions from utility plants firing high sulfur coals. The specific objectives are to: 1) develop and test an ultra low-NOx pulverized coal burner for plug-in retrofit applications without boiler wall tube modifications, 2) assess the impact of low-NOx PC burner operation on NOx and PM2.5 emissions, and 3) provide high-quality data to ensure that future PM2.5 regulations are based on good scientific information. The work will be performed in the Clean Environment Development Facility (CEDF), a 100 million Btu/hr near-full-scale facility located at the Alliance Research Center. Related Papers and Publications:

97

Air Pollution Control Regulations: No. 41 - Nox Budget Trading Program  

Broader source: Energy.gov (indexed) [DOE]

41 - Nox Budget Trading 41 - Nox Budget Trading Program (Rhode Island) Air Pollution Control Regulations: No. 41 - Nox Budget Trading Program (Rhode Island) < Back Eligibility Commercial Industrial Investor-Owned Utility Municipal/Public Utility Rural Electric Cooperative Utility Savings Category Alternative Fuel Vehicles Hydrogen & Fuel Cells Program Info State Rhode Island Program Type Environmental Regulations Provider Department of Environmental Management These regulations establish a budget trading program for nitrogen oxide emissions, setting NOx budget units for generators and an NOx Allowance Tracking System to account for emissions. These regulations apply to units that serve generators with a nameplate capacity greater than 15 MWe and sell any amount of electricity, as well as to units that have a maximum

98

ODS_Workshop101118_eldasher2Full.pptx  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Chamber-Blanket Design for LIFE Chamber-Blanket Design for LIFE Presenter: Bassem El-Dasher Jeff Latkowski Joseph Farmer Pete Fitsos November 18, 2010 ODS 2010 Materials Workshop The LIFE chamber design must satisfy a number of requirements 2 Capture and transmit thermal power to balance of plant (handle 0.5-1.5 MW/m 2 ) Produce tritium to replace that burned in previous targets (Tritium breeding ratio ≥ 1.08) Enable successful propagation of target and laser beams (Propagation efficiency ≥ 95%) Operate at high temperature for high thermal efficiency (T wall ≥ 600°C for η th ≥ 40%) Fabricate from an available material (commercially available & weldable) Remove residual material left behind by previous shot (material-dependent requirement) Collect and process target

99

Implementation of VOC source reduction practices in a manufactured house and in school classrooms  

SciTech Connect (OSTI)

Detailed studies of a new manufactured house and four new industrialized relocatable school classrooms were conducted to determine the emission sources of formaldehyde and other VOCs and to identify and implement source reduction practices. Procedures were developed to generate VOC emission factors that allowed reasonably accurate predictions of indoor air VOC concentrations. Based on the identified sources of formaldehyde and other aldehydes, practices were developed to reduce the concentrations of these compounds in new house construction. An alternate ceiling panel reduced formaldehyde concentrations in the classrooms. Overall, the classrooms had relatively low VOC concentrations.

Hodgson, A.T.; Apte, M.G.; Shendell, D.G.; Beal, D.; McIlvaine, J.E.R.

2002-01-01T23:59:59.000Z

100

Measurement of VOC reactivities using a photochemical flow reactor  

SciTech Connect (OSTI)

A commercial ambient air monitoring instrument, the Airtrak 2000, has been modified for use as a photochemical flow reactor and used to measure the absolute and incremental reactivity of 18 single test VOCs and the incremental reactivity of six multicomponent VOC mixtures. A flow technique is a useful supplement to traditional static chamber experiments. The static chamber technique involves periodic sampling of an irradiated mixture in a photochemical chamber. Under these conditions, the irradiated mixture is always in transition. Using a flow system, a steady-state condition is established within the flow reactor that is representative, in this case, of the early stages of the smog forming process in the atmosphere. The measurement technique also allows changes in the background chamber reactivity to be monitored and taken into account. The incremental reactivity of 13 of the 18 test compounds measured is compared with previously reported results from a static chamber experiment, and the two data sets are generally in good agreement. The additivity of reactivity was tested by measuring the incremental reactivity of six multicomponent mixtures, the components being compounds measured individually in this study. The measured reactivity of a mixture was compared to that calculated from the sum of the measured reactivity of the mixture`s individual components. The results show that reactivity is additive for the concentration range studied.

Hurley, M.D.; Chang, T.Y.; Japar, S.M.; Wallington, T.J. [Ford Motor Co., Dearborn, MI (United States). Ford Research Lab.] [Ford Motor Co., Dearborn, MI (United States). Ford Research Lab.

1998-07-01T23:59:59.000Z

Note: This page contains sample records for the topic "nox ods voc" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

In situ treatment of VOCs by recirculation technologies  

SciTech Connect (OSTI)

The project described herein was conducted by Oak Ridge National Laboratory (ORNL) to identify processes and technologies developed in Germany that appeared to have near-term potential for enhancing the cleanup of volatile organic compound (VOC) contaminated soil and groundwater at DOE sites. Members of the ORNL research team identified and evaluated selected German technologies developed at or in association with the University of Karlsruhe (UoK) for in situ treatment of VOC contaminated soils and groundwater. Project activities included contacts with researchers within three departments of the UoK (i.e., Applied Geology, Hydromechanics, and Soil and Foundation Engineering) during fall 1991 and subsequent visits to UoK and private industry collaborators during February 1992. Subsequent analyses consisted of engineering computations, groundwater flow modeling, and treatment process modeling. As a result of these project efforts, two processes were identified as having near-term potential for DOE: (1) the vacuum vaporizer well/groundwater recirculation well and (2) the porous pipe/horizontal well. This document was prepared to summarize the methods and results of the assessment activities completed during the initial year of the project. The project is still ongoing, so not all facets of the effort are completely described in this document. Recommendations for laboratory and field experiments are provided.

Siegrist, R.L.; Webb, O.F.; Ally, M.R.; Sanford, W.E. [Oak Ridge National Lab., TN (US); Kearl, P.M.; Zutman, J.L. [Oak Ridge National Lab., Grand Junction, CO (US)

1993-06-01T23:59:59.000Z

102

OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL  

SciTech Connect (OSTI)

This quarterly technical progress report will summarize work accomplished for the Program through the fourth quarter January-March 2001 in the following task areas: Task 1 - Oxygen Enhanced Combustion, Task 2 - Oxygen Transport Membranes and Task 4 - Program Management. This report will also recap the results of the past year. The program is proceeding in accordance with the objectives for the first year. OTM material characterization was completed. 100% of commercial target flux was demonstrated with OTM disks. The design and assembly of Praxair's single tube high-pressure test facility was completed. The production of oxygen with a purity of better than 99.5% was demonstrated. Coal combustion testing was conducted at the University of Arizona. Modest oxygen enhancement resulted in NOx emissions reduction. The injector for oxygen enhanced coal based reburning was conducted at Praxair. Combustion modeling with Keystone boiler was completed. Pilot-scale combustion test furnace simulations continued this quarter.

David R. Thompson; Lawrence E. Bool; Jack C. Chen

2001-04-01T23:59:59.000Z

103

OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL  

SciTech Connect (OSTI)

This quarterly technical progress report will summarize work accomplished for the Program through the thirteenth quarter, April-June 2003, in the following task areas: Task 1--Oxygen Enhanced Combustion, Task 3--Economic Evaluation and Task 4--Program Management. The program is proceeding in accordance with project objectives. REI's model was modified to evaluate mixing issues in the upper furnace of a staged unit. Analysis of the results, and their potential application to this unit is ongoing. Economic evaluation continues to confirm the advantage of oxygen-enhanced combustion. A contract for a commercial demonstration has been signed with the Northeast Generation Services Company to supply oxygen and license the oxygen enhanced low NOx combustor technology for use at the 147-megawatt coal fired Mt. Tom Station in Holyoke, MA. Commercial proposals have been submitted. Economic analysis of a beta site test performance was conducted.

David R. Thompson; Lawrence E. Bool; Jack C. Chen

2003-08-01T23:59:59.000Z

104

Ion-mobility Spectrometry Based NOx Sensor - Nuclear Engineering Division  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

NPNS > Sensors and NPNS > Sensors and Instrumentation and NDE > Energy System Application > DOE Office of Transportation Technologies > Ion-mobility Spectrometry Based NOx Sensor Capabilities Sensors and Instrumentation and Nondestructive Evaluation Overview Energy System Applications Overview DOE Office of Fossil Energy DOE Office of Transportation Technologies Ion-mobility Spectrometry Based NOx Sensor DOE Office of Power Technology Work for Others Safety-Related Applications Homeland Security Applications Biomedical Applications Millimiter Wave Group Papers Other NPNS Capabilities Work with Argonne Contact us For Employees Site Map Help Join us on Facebook Follow us on Twitter NE on Flickr Sensors and Instrumentation and Nondestructive Evaluation Ion-mobility Spectrometry Based NOx Sensor

105

ACCEPTED BY WATER ENVIRONMENT RESEARCH ODOR AND VOC REMOVAL FROM WASTEWATER TREATMENT PLANT  

E-Print Network [OSTI]

of their high rates of chemical consumption. Additionally, chemical scrubbers are ineffective for the removalACCEPTED BY WATER ENVIRONMENT RESEARCH _______ ODOR AND VOC REMOVAL FROM WASTEWATER TREATMENT PLANT of biofilters for sequential removal of H2S and VOCs from wastewater treatment plant waste air. The biofilter

106

CSTB / CTBA Wood Preservation -Cannes 2001 MEASUREMENT OF VOC EMISSIONS FROM CURATIVE TREATED WOOD  

E-Print Network [OSTI]

CSTB / CTBA Wood Preservation - Cannes 2001 1 MEASUREMENT OF VOC EMISSIONS FROM CURATIVE TREATED WOOD : A NEW EMISSION TEST CHAMBER METHOD François MAUPETIT1 , Olivier RAMALHO1 and Christophe YRIEIX2 wood, emission test chamber, VOCs Introduction A poor indoor air quality (IAQ) is now recognized

Paris-Sud XI, Université de

107

A Critical Review on Studies of Volatile Organic Compound (VOC) Sorption by  

E-Print Network [OSTI]

A Critical Review on Studies of Volatile Organic Compound (VOC) Sorption by Building Materials (RP the pros and cons of existing sorption models, as well as experimental methods. In addition, it summarizes existing sorption data in order to understand the phenomenon of VOC sorption on building materials better

Chen, Qingyan "Yan"

108

Oxidation State Optimization for Maximum Efficiency of NOx Adsorber...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Directions in Engine-Efficiency and Emissions Research (DEER) Conference in Detroit, MI, September 27-30, 2010. deer10li.pdf More Documents & Publications Lean NOx Trap...

109

Functionality of Commercial NOx Storage-Reduction Catalysts and...  

Broader source: Energy.gov (indexed) [DOE]

N.A. Ottinger, J.A. Pihl, T.J. Toops, C. Finney, M. Lance, C. Stuart Daw, "Types, Spatial Distribution, Stability, and Performance Impact of Sulfur on a Lean NOx Trap...

110

Reducing NOx emissions using the humid air motor concept  

Science Journals Connector (OSTI)

The use of water to prevent NOx...formation during the combustion process is well known. The H.A.M. system (Humid Air Motor) is an original and promising solution compared ... . This system involves evaporating l...

Emmanuel Riom; Lars-Ola Larsson; Ulf Hagstrm

2002-05-01T23:59:59.000Z

111

Enhanced High Temperature Performance of NOx Storage/Reduction...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

and Peer Evaluation Meeting, June 7-11, 2010 -- Washington D.C. ace026peden2010o.pdf More Documents & Publications Mechanisms of Sulfur Poisoning of NOx Adsorber (LNT) Materials...

112

Lean Gasoline Engine Reductant Chemistry During Lean NOx Trap Regeneration  

SciTech Connect (OSTI)

Lean NOx Trap (LNT) catalysts can effectively reduce NOx from lean engine exhaust. Significant research for LNTs in diesel engine applications has been performed and has led to commercialization of the technology. For lean gasoline engine applications, advanced direct injection engines have led to a renewed interest in the potential for lean gasoline vehicles and, thereby, a renewed demand for lean NOx control. To understand the gasoline-based reductant chemistry during regeneration, a BMW lean gasoline vehicle has been studied on a chassis dynamometer. Exhaust samples were collected and analyzed for key reductant species such as H2, CO, NH3, and hydrocarbons during transient drive cycles. The relation of the reductant species to LNT performance will be discussed. Furthermore, the challenges of NOx storage in the lean gasoline application are reviewed.

Choi, Jae-Soon [ORNL] [ORNL; Prikhodko, Vitaly Y [ORNL] [ORNL; Partridge Jr, William P [ORNL] [ORNL; Parks, II, James E [ORNL; Norman, Kevin M [ORNL] [ORNL; Huff, Shean P [ORNL] [ORNL; Chambon, Paul H [ORNL] [ORNL; Thomas, John F [ORNL] [ORNL

2010-01-01T23:59:59.000Z

113

Application of Electron Beams for the Treatment of VOC Streams  

Science Journals Connector (OSTI)

Department of Material Development, Japan Atomic Energy Research Institute, 1233 Watanuki, Takasaki, Gunma 370-1292, Japan, and Advanced Research Institute for Science and Engineering, Waseda University, 3-4-1 Okubo, Shinjuku-ku, Tokyo 169-8555, Japan ... However, VOC emissions to the atmosphere accounted for more than 80% of the total emission of 898?308 t/year to the environment in 2001, according to reports from the industrial corporations handling pollutants listed in the PRTR registry and the estimation of pollutant emissions from nonregistered corporations, mobile sources, and households.2 Figure 1 shows the emission amounts of the 10 highest-ranked substances reported by the PRTR in 2001. ...

Koichi Hirota; Hiroki Sakai; Masakazu Washio; Takuji Kojima

2004-01-22T23:59:59.000Z

114

ACCU Core Sampling/Storage Device for VOC Analysis  

SciTech Connect (OSTI)

The Accu Core sampler system consists of alternating cylindrical clear acrylic sections and one-inch cylindrical stainless steel sections arranged in clear shrink wrap. The set of alternating acrylic and stainless steel sections in the shrink wrap are designed to fit in a Geoprobe dual-tube penetrometer for collection of continuous soil cores. The clear acrylic sections can have 1/2-inch access holes for easy soil headspace screening without violating the integrity of the adjacent stainless steel sections. The Accu Core sampler system can be used to store a soil sample collected in the stainless steel section by capping the ends of the section so it becomes a sample storage container. The sampler system can also be used to collect a subsurface soil sample in one of the sections that can be directly extruded from the section into a container for storage during shipment to the laboratory. In addition, the soil in a sampler section can be quickly sub-sampled using a coring tool and extruded into a storage container so the integrity of the soil is not disrupted and the potential for VOC loss during sub-sampling is greatly reduced. A field validation study was conducted to evaluate the performance of the Accu Core sampler to store VOC soil samples during transportation to the laboratory for analysis and to compare the performance of the Accu Core with current sampling and storage techniques, all of which require sub-sampling when the soil sample is brought to the surface. During some of the validation testing, the acrylic sections having access holes for headspace screening were included in the Accu Core sampler configuration and soil in these sections was screened to show the usefulness of the sample screening capability provided by the Accu Core system. This report presents the results of the field validation study as well as recommendations for the Accu Core sampler system.

Susan S. Sorini; John F. Schabron; Mark M. Sanderson

2007-04-30T23:59:59.000Z

115

Reducing fishing vessel fuel consumption and NOX emissions  

Science Journals Connector (OSTI)

There is a growing concern with the impact of marine operations on the environment. This requires reducing fuel consumption and vessel pollution during operation. On-board computers and satellite communications will enable the operator to reduce fuel consumption and NOX emissions during vessel operations. This paper presents the results of a study on this problem and how such an on-board system could be implemented to reduce fuel consumption and engine NOX emissions.

Robert Latorre

2001-01-01T23:59:59.000Z

116

Group effects on fuel NOx emissisons from coal  

E-Print Network [OSTI]

GROUP EFFECTS ON FUEL NOX EMISSIONS FROM COAL A Thesis by ANAND ANAKKARA VADAKKATH Submitted to the Office of Graduate Studies of Texas ARM University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE August... 1991 Major Subject: Mechanical Engineering GROUP EFFECTS ON FUEL NOX EMISSIONS FROM COAL A Thesis by ANAND ANAKKARA VADAKKATH Approved ss to style and content by: K. Annamalai (Chair of Committee) Cr, R. Laster (Member) J. Wagne (Member...

Vadakkath, Anand Anakkara

2012-06-07T23:59:59.000Z

117

Friction Stir Welding of ODS Steels … Steps toward a Commercial Process  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Friction Stir Welding of ODS Friction Stir Welding of ODS Steels - Steps toward a Commercial Process 1 Glenn Grant Scott Weil Pacific Northwest National Laboratory Presented at the Workshop: Fe-Based ODS Alloys: Role and Future Applications University of California San Diego La Jolla, CA Nov 17 th - 18 th 2010 Barriers: * Traditionally produced by powder metallurgy methods that tend to be costly - Commercial viability requires new processing and manufacturing technology * Unfavorable anisotropic properties can result if processed improperly for the application * Cannot be welded by melt/solidification processes ODS Alloys: Incorporate a dispersion of nanoscale oxide particles (such as Y 2 O 3 ) in the ferritic matrix to mitigate grain boundary movement and allow greatly improved creep and high temperature strength while maintaining good

118

Microsoft PowerPoint - PNNL-Prior ODS work 1.pptx  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

MA957 at PNNL for Fast MA957 at PNNL for Fast Reactor Application: Prior Work (to 2000) Presented by Curt Lavender K. S. Weil and G. J. Grant "Fe- Based ODS Alloys: Role and Future Applications" November 17-18, 2010 University of California, San Diego La Jolla, California Outline * Discussion of work performed prior 2000 * ODS MA957 for Liquid Metal Reactor Cladding tubes * Supplier development - to develop multiple sources for tubing * Security of supply for reactor operations * Characterization of ODS MA 957 * Production validation * NDE - not discussed * End closure joining - EM pulse joining was qualified - not discussed * Where ODS may be headed * What may be done to speed qualification Motivation/Objective * Motivation: US DOE sponsored work to develop improved fuel cladding materials for liquid fast metal

119

Effect of outside air ventilation rate on VOC concentrations and emissions  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Effect of outside air ventilation rate on VOC concentrations and emissions Effect of outside air ventilation rate on VOC concentrations and emissions in a call center Title Effect of outside air ventilation rate on VOC concentrations and emissions in a call center Publication Type Conference Proceedings Year of Publication 2002 Authors Hodgson, Alfred T., David Faulkner, Douglas P. Sullivan, Dennis L. DiBartolomeo, Marion L. Russell, and William J. Fisk Conference Name Proceedings of the Indoor Air 2002 Conference, Monterey, CA Volume 2 Pagination 168-173 Publisher Indoor Air 2002, Santa Cruz, CA Abstract A study of the relationship between outside air ventilation rate and concentrations of VOCs generated indoors was conducted in a call center. Ventilation rates were manipulated in the building's four air handling units (AHUs). Concentrations of VOCs in the AHU returns were measured on 7 days during a 13- week period. Indoor minus outdoor concentrations and emission factors were calculated. The emission factor data was subjected to principal component analysis to identify groups of co-varying compounds based on source type. One vector represented emissions of solvents from cleaning products. Another vector identified occupant sources. Direct relationships between ventilation rate and concentrations were not observed for most of the abundant VOCs. This result emphasizes the importance of source control measures for limiting VOC concentrations in buildings

120

OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL  

SciTech Connect (OSTI)

This quarterly technical progress report will summarize work accomplished for the Program through the ninth quarter April-June 2002 in the following task areas: Task 1--Oxygen Enhanced Combustion, Task 2--Oxygen Transport Membranes, Task 3--Economic Evaluation and Task 4--Program Management. The program is proceeding in accordance with the objectives for the third year. Full-scale testing using the Industrial Boiler Simulation Facility (ISBF) at Alstom Power was completed. The pilot scale experiments to evaluate the effect of air preheat and transport air stoichiometric ratio (SR) on NOx emissions were conducted at the University of Utah. Combustion modeling activities continued with full-scale combustion test furnace simulations. An OTM element was tested in Praxair's single tube high-pressure test facility and two thermal cycles were completed. PSO1d elements of new dimension were tested resulting in a lower flux than previous PSO1d elements of different dimensions, however, no element deformation was observed. Economic evaluation has confirmed the advantage of oxygen-enhanced combustion. Two potential host beta sites have been identified and proposals submitted.

David R. Thompson; Lawrence E. Bool; Jack C. Chen

2002-08-01T23:59:59.000Z

Note: This page contains sample records for the topic "nox ods voc" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL  

SciTech Connect (OSTI)

This quarterly technical progress report will summarize work accomplished for the Program through the fourth quarter January-March 2002 in the following task areas: Task 1--Oxygen Enhanced Combustion, Task 2--Oxygen Transport Membranes, Task 3--Economic Evaluation and Task 4--Program Management. This report will also recap the results of the past year. The program is proceeding in accordance with the objectives for the second year. The first round of pilot scale testing with 3 bituminous coals was completed at the University of Utah. Full-scale testing equipment is in place and experiments are underway. Coal combustion lab-scale testing was completed at the University of Arizona. Modest oxygen enhancement resulted in NOx emissions reduction. Combustion modeling activities continued with pilot-scale combustion test furnace simulations. 75% of target oxygen flux was demonstrated with small PSO1 tube in Praxair's single tube high-pressure test facility. The production of oxygen with a purity of better than 99.999% was demonstrated. Economic evaluation has confirmed the advantage of oxygen-enhanced combustion. Two potential host sites have been identified.

David R. Thompson; Lawrence E. Bool; Jack C. Chen

2002-04-01T23:59:59.000Z

122

Continuation of Studies on Development of ODS Heat Exchanger Tubing  

SciTech Connect (OSTI)

The Department of Energy (DOE), National Energy Technology Center (NETL), has initiated a strategic plan for the development of advanced technologies needed to design and build fossil fuel plants with very high efficiency and environmental performance. These plants, referred to as 'Vision 21' and FutureGen programs by DOE, will produce electricity, chemicals, fuels, or a combination of these products, and possibly secondary products such as steam/heat for industrial use. MA956 is a prime candidate material being considered for a high temperature heat exchanger in the 'Vision 21' and FutureGen programs. This material is an oxide dispersion strengthened (ODS) alloy; however, there are some gaps in the data required to commit to the use of these alloys in a full-size plant. To fill the technology gaps for commercial production and use of the material for 'Advanced Power Generation Systems' this project has performed development activity to significant increase in circumferential strength of MA956 as compared to currently available material, investigated bonding technologies for bonding tube-to-tube joints through joining development, and performed tensile, creep and fire-side corrosion tests to validate the use and fabrication processes of MA956 to heat exchanger tubing applications. Development activities within this projected has demonstrated increased circumferential strength of MA956 tubes through flow form processing. Of the six fabrication technologies for bonding tube-to-tube joints, inertia friction welding (IFW) and flash butt welding (FBW) were identified as processes for joining MA956 tubes. Tensile, creep, and fire-side corrosion test data were generated for both base metal and weld joints. The data can be used for design of future systems employing MA956. Based upon the positive development activities, two test probes were designed and fabricated for field exposure testing at 1204 C ({approx}2200 F) flue gas. The probes contained tube portions with FBW and IFW welded MA956. Field testing of the probes and remaining heat exchanger design activity will be performed by Oak Ridge National Laboratory under DOE Contract DE-AC05-00OR22725.

Lawrence Brown; David Workman; Bimal Kad; Gaylord Smith; Archie Robertson; Ian Wright

2008-04-15T23:59:59.000Z

123

VOCs and formaldehyde emissions from cleaning products and air Ccilia Solal1,*  

E-Print Network [OSTI]

VOCs and formaldehyde emissions from cleaning products and air fresheners Cécilia Solal1: air fresheners, glass cleaners, furniture polishes, toilet products, carpet and floor cleaning Formaldehyde, Volatile organic compounds, Household products, Exposure INTRODUCTION Most indoor air pollutants

Paris-Sud XI, Université de

124

Vehicular emission of volatile organic compounds (VOCs) from a tunnel study in Hong Kong  

E-Print Network [OSTI]

ethene toluene n-butane propane i-pentane i-butane propeneethene, toluene, n-butane, propane and i-pentane. These fiveVOCs emitted. The high propane and n-butane emissions were

2009-01-01T23:59:59.000Z

125

Energy Efficient Indoor VOC Air Cleaning with Activated Carbon Fiber (ACF) Filters  

E-Print Network [OSTI]

The existing particle filters in HVAC systems of buildingscandidates for use as VOC filters in HVAC systems. Recentcost of an ACF filter bed in an HVAC system is the energy

Sidheswaran, Meera

2012-01-01T23:59:59.000Z

126

NETL: Advanced NOx Emissions Control: Control Technology - SCNR Field  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

SNCR Field Demonstration SNCR Field Demonstration American Electric Power (AEP), in conjunction with the U.S. Department of Energy, FuelTech, the Ohio Coal Development Office, and fourteen EPRI member utilities, performed a full-scale demonstration of a urea-based Selective Non-Catalytic Reduction (SNCR) system at Cardinal Unit 1. Cardinal Unit 1 is a 600MWe opposed-wall dry bottom pulverized coal-fired boiler that began service in 1967. This unit burns eastern bituminous high-sulfur coal, (3.72%S). This unit was retrofitted with low NOx burners (LNB's) during its scheduled fall 1998 outage and the SNCR system was installed concurrently. SNCR is a post-combustion NOx control process developed to reduce NOx emissions from fossil-fuel combustion systems. SNCR processes involve the injection of a chemical containing nitrogen into the combustion products, where the temperature is in the range of 1600°F - 2200°F (870°C - 1205°C). In this temperature range, the chemical reacts selectively with NOx in the presence of oxygen, forming primarily nitrogen and water. Although a number of chemicals have been investigated and implemented for SNCR NOx reduction, urea and ammonia have been most widely used for full-scale applications.

127

Southern California Edison's (SCE) Research Program for Industrial Volatile Organic Compound (VOC) Emissions Control  

E-Print Network [OSTI]

. Applied Utility Systems Rosemead, California Tarrytown, New York Santa Ana, California ABSTRACT SCE has developed and implemented a research program for customer retention through VOC emission control. Following characterization of problematic..., California RON CASCONE Senior Consultant Chem Systems, Inc. Tarrytown, New York JIM REESE Applied Utility Santa Ana, California ABSTRACT SCE has developed and implemented a research program for customer retention through VOC emission control. Following...

Sung, R. D.; Cascone, R.; Reese, J.

128

HRTEM Study of the Role of Nanoparticles in ODS Ferritic Steel  

SciTech Connect (OSTI)

Structures of nanoparticles and their role in dual-ion irradiated Fe-16Cr-4.5Al-0.3Ti-2W-0.37Y{sub 2}O{sub 3} (K3) ODS ferritic steel produced by mechanical alloying (MA) were studied using high-resolution transmission electron microscopy (HRTEM) techniques. The observation of Y{sub 4}Al{sub 2}O{sub 9} complex-oxide nanoparticles in the ODS steel imply that decomposition of Y{sub 2}O{sub 3} in association with internal oxidation of Al occurred during mechanical alloying. HRTEM observations of crystalline and partially crystalline nanoparticles larger than {approx}2 nm and amorphous cluster-domains smaller than {approx}2 nm provide an insight into the formation mechanism of nanoparticles/clusters in MA/ODS steels, which we believe involves solid-state amorphization and re-crystallization. The role of nanoparticles/clusters in suppressing radiation-induced swelling is revealed through TEM examinations of cavity distributions in (Fe + He) dual-ion irradiated K3-ODS steel. HRTEM observations of helium-filled cavities (helium bubbles) preferably trapped at nanoparticle/clusters in dual-ion irradiated K3-ODS are presented.

Hsiung, L; Tumey, S; Fluss, M; Serruys, Y; Willaime, F

2011-08-30T23:59:59.000Z

129

NETL: Advanced NOx Emissions Control: Control Technology - Optimized Fuel  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Optimized Fuel Injector Design Optimized Fuel Injector Design This project includes fundamental research and engineering development of low NOx burners and reburning fuel injectors. The team of Reaction Engineering International (REI), the University of Utah, Brown University and DB Riley, Inc., will develop fundamental information on low NOx burners. The work has two phases. In the first phase, the University of Utah will examine two-phase mixing and near-field behavior of coal injectors using a 15-million Btu/hr bench-scale furnace, Brown University will examine char deactivation and effectiveness of reburning, and REI will develop a comprehensive burner model using the data produced by the University of Utah and Brown University. In the second phase, an optimized injector design will be tested at the 100-million Btu/hr Riley Coal Burner Test Facility. It is anticipated that this work will provide improved hardware designs and computer simulation models for reduced NOx emissions and minimized carbon loss.

130

SCReaming for Low NOx - SCR for the Light Duty Market | Department...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

SCReaming for Low NOx - SCR for the Light Duty Market SCReaming for Low NOx - SCR for the Light Duty Market Presentation given at DEER 2006, August 20-24, 2006, Detroit, Michigan....

131

Engine and Reactor Evaluations of HC-SCR for Diesel NOx Reduction...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Engine and Reactor Evaluations of HC-SCR for Diesel NOx Reduction Engine and Reactor Evaluations of HC-SCR for Diesel NOx Reduction Focus is the heavy duty, US dynamometer...

132

Safe and compact ammonia storage/delivery systems for SCR-DeNOX...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Safe and compact ammonia storagedelivery systems for SCR-DeNOX in automotive units Safe and compact ammonia storagedelivery systems for SCR-DeNOX in automotive units Presentation...

133

Development of a Stand-Alone Urea-SCR System for NOx Reduction...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Stand-Alone Urea-SCR System for NOx Reduction in Marine Diesel Engines Development of a Stand-Alone Urea-SCR System for NOx Reduction in Marine Diesel Engines Stand-alone urea SCR...

134

Fuel-Borne Reductants for NOx Aftertreatment: Preliminary EtOH...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Reductants for NOx Aftertreatment: Preliminary EtOH SCR Study Fuel-Borne Reductants for NOx Aftertreatment: Preliminary EtOH SCR Study 2003 DEER Conference Presentation: Oak Ridge...

135

Initial Results of the DeNOx SCR System by Urea Injection in...  

Broader source: Energy.gov (indexed) [DOE]

Initial Results of the DeNOx SCR System by Urea Injection in the Euro 5 Bus Initial Results of the DeNOx SCR System by Urea Injection in the Euro 5 Bus 2005 Diesel Engine Emissions...

136

The Effects of Hydrocarbons on NOx Reduction over Fe-based SCR Catalyst  

Broader source: Energy.gov [DOE]

Study of effects of hydrocarbons on ammonia storage and NOx reduction over a commercial Fe-zeolite SCR catalyst to understand catalyst behaviors at low temperatures and improve NOx reduction performance and reduce system cost

137

Industry-Utility Collaborative Efforts to Address Environmental Concerns- Dispatching for Localized NOx Reduction  

E-Print Network [OSTI]

these objectives. The approach involves dispatching NOx-producing equipment (e.g., boilers and gas turbines) to achieve minimum NOx production during ozone alert periods and purchasing supplemental power under a special tariff to replace any loss in self...

Hamilton, D. E.; Helmick, R. W.; Lambert, W. J.

138

Intra-catalyst Reductant Chemistry in Lean NOx Traps: A Study...  

Broader source: Energy.gov (indexed) [DOE]

Intra-catalyst Reductant Chemistry in Lean NOx Traps: A Study on Sulfur Effects Intra-catalyst Reductant Chemistry in Lean NOx Traps: A Study on Sulfur Effects Presentation given...

139

NOx formation by steam injection using detailed chemical kinetics  

Science Journals Connector (OSTI)

In order to improve thermal efficiency of gas turbine system and better control NOx emission, the injection of steam into a gas turbine combustor has been employed. This study has used both chemical equilibrium calculations and the counterflow diffusion flame calculations of methane-air flame aiming at the elucidation of the NOx reduction mechanism due to the steam injection. The influence of the equivalence ratios, the amount of steam and method of injection, the influence of the temperature of the preheated air and fuel has been also investigated. In this study, the GRI-Mech was employed for modelling the chemical reactions.

H. Yamashita; D. Zhao; S.N. Danov; T. Furuhata; N. Arai

2001-01-01T23:59:59.000Z

140

Aeroderivative Gas Turbines Can Meet Stringent NOx Control Requirements  

E-Print Network [OSTI]

for controlling NOx emissions will be discussed. Steam injection has a very favorable effect on engine performance raising both the power output and efficiency. As an example, full steam injection in the GE LM5000 gas turbine :tncreases the power output from... methods for reducing the NOx levels of the LM2500 and LM5000 engines. These engines are aircraft-derivative turbine engines, which are used in a variety of industrial applications. Efforts have been concentrated on the use of water or steam injection...

Keller, S. C.; Studniarz, J. J.

Note: This page contains sample records for the topic "nox ods voc" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Optimization of High Temperature Hoop Creep Response in ODS-Fe3Al Tubes  

SciTech Connect (OSTI)

Oxide dispersion strengthened (ODS) Fe3Al alloys are currently being developed for heat-exchanger tubes for eventual use at operating temperatures of up to 1100 C in the power generation industry. The development challenges include (a) efforts to produce thin walled ODS-Fe3Al tubes, employing powder extrusion methodologies, with (b) adequate increased strength for service at operating temperatures to (c) mitigate creep failures by enhancing the as-processed grain size. A detailed and comprehensive research and development methodology is prescribed to produce ODS-Fe3Al thin walled tubes. Current single step extrusion consolidation methodologies typically yield 8ft. lengths of 1-3/8 inch diameter, 1/8 inch wall thickness ODS-Fe3Al tubes. The process parameters for such consolidation methodologies have been prescribed and evaluated as being routinely reproducible. Recrystallization treatments at 1200 C produce elongated grains (with their long axis parallel to the extrusion axis), typically 200-2000 {micro}m in diameter, and several millimeters long. The dispersion distribution is unaltered on a micro scale by recrystallization, but the high aspect ratio grain shape typically obtained limits grain spacing and consequently the hoop creep response. Improving hoop creep in ODS-alloys requires an understanding and manipulating the factors that control grain alignment and recrystallization behavior. Current efforts are focused on examining the processing dependent longitudinal vs. transverse creep anisotropy, and exploring post-extrusion methods to improve hoop creep response in ODS-Fe3Al alloy tubes. In this report we examine the mechanisms of hoop creep failure and describe our efforts to improve creep performance via variations in thermal-mechanical treatments.

Kad, B.K.; Heatherington, J.H.; McKamey, C.; Wright, I.; Sikka, V.; Judkins, R.

2003-04-22T23:59:59.000Z

142

Initial Development in Joining of ODS Alloys Using Friction Stir Welding  

SciTech Connect (OSTI)

Solid-state welding of oxide-dispersion-strengthened (ODS) alloy MA956 sheets using friction stir welding (FSW) was investigated. Butt weld was successfully produced. The weld and base metals were characterized using optical microscopy, scanning electronic microscopy, transmission electronic microscopy, and energy dispersion x-ray spectrum. Microhardness mapping was also conducted over the weld region. Analyses indicate that the distribution of the strengthening oxides was preserved in the weld. Decrease in microhardness of the weld was observed but was insignificant. The preliminary results seem to confirm the envisioned feasibility of FSW application to ODS alloy joining. For application to Gen IV nuclear reactor heat exchanger, further investigation is suggested.

Ren, Weiju [ORNL; Feng, Zhili [ORNL

2007-08-01T23:59:59.000Z

143

The Chemistry of the Thermal DeNOx Process: A Review of the Technology's Possible Application to control of NOx from Diesel Engines  

SciTech Connect (OSTI)

This paper presents a review of the Thermal DeNOx process with respect to its application to control of NOx emissions from diesel engines. The chemistry of the process is discussed first in empirical and then theoretical terms. Based on this discussion the possibilities of applying the process to controlling NOx emissions from diesel engines is considered. Two options are examined, modifying the requirements of the chemistry of the Thermal DeNOx process to suit the conditions provided by diesel engines and modifying the engines to provide the conditions required by the process chemistry. While the former examination did not reveal any promising opportunities, the latter did. Turbocharged diesel engine systems in which the turbocharger is a net producer of power seem capable of providing the conditions necessary for NOx reduction via the Thermal DeNOx reaction.

Lyon, Richard

2001-08-05T23:59:59.000Z

144

NETL: Advanced NOx Emissions Control: Control Technology - ALTA for Cyclone  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Full-Scale Demonstration of ALTA NOx Control for Cyclone-Fired Boilers Full-Scale Demonstration of ALTA NOx Control for Cyclone-Fired Boilers The primary goal of this project was to evaluate a technology called advanced layered technology application (ALTA) as a means to achieve NOx emissions below 0.15 lb/MMBtu in a cyclone boiler. Reaction Engineering International (REI) conducted field testing and combustion modeling to refine the process design, define the optimum technology parameters, and assess system performance. The ALTA NOx control technology combines deep staging from overfire air, rich reagent injection (RRI), and selective non-catalytic reduction (SNCR). Field testing was conducted during May-June 2005 at AmerenUE's Sioux Station Unit 1, a 500 MW cyclone boiler unit that typically burns an 80/20 blend of Powder River Basin subbituminous coal and Illinois No. 6 bituminous coal. Parametric testing was also conducted with 60/40 and 0/100 blends. The testing also evaluated process impacts on balance-of-plant issues such as the amount of unburned carbon in the ash, slag tapping, waterwall corrosion, ammonia slip, and heat distribution.

145

Lean NOx Reduction with Dual Layer LNT/SCR Catalysts  

Broader source: Energy.gov (indexed) [DOE]

Roles of ceria in LNT SCR: I ncreases NOx storage & NO conversion at low tem perature P rom otes W GS reaction Conditions: Lean: 500 ppm NO, 5% O 2 ; 60s Rich: 2.5% H 2 ; 5s X H2...

146

Oxidation behavior of ferriticmartensitic and ODS steels in supercritical water Jeremy Bischoff  

E-Print Network [OSTI]

, Arthur T. Motta Department of Mechanical and Nuclear Engineering, Pennsylvania State University, 227 The Supercritical Water Reactor is one of the six Generation IV nuclear power plant designs and was envisioned dispersion of yttrium­titanium-rich oxide nano- particles inside their matrix. The ODS alloys were developed

Motta, Arthur T.

147

Characterization and In-Situ Ion-Irradiation of MA957 ODS Steel Djamel Kaoumi1  

E-Print Network [OSTI]

, Mark Kirk2 1 Department of Mechanical and Nuclear Engineering, Pennsylvania State University, 18 Reber Laboratory, Argonne, IL 060493, USA INTRODUCTION Oxide dispersion strengthened (ODS) Ferritic for GEN-IV nuclear reactors. They are expected to achieve high creep strength and be resistant

Motta, Arthur T.

148

NMED COMMENTS ITEM 3 REVISE VOLATILE ORGANIC COMPOUND (VOC) TARGET ANALYTE LIST  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

3 3 NMED COMMENTS ITEM 3 REVISE VOLATILE ORGANIC COMPOUND (VOC) TARGET ANALYTE LIST OTHER CHANGES TO VOC MONITORING PROGRAM Page 1 of 21 VOC 3·1: PMR Section 3, Topic 1, Table 1 Recalculated Waste Matrix Code Group Weighting Factors based on the 2004 Compliance Recertification Contact Handled (CH) Transuranic (TRU) Waste Inventory (m 3 ) The new weighting factors appear to be based on CH TRU waste only and do not include remote handled (RH) TRU waste. There was no discussion in the PMR addressing possible differences in Waste Matrix Code Group (WMCG) for RH TRU that could potentially impact the weighting factors. Please provide data characterizing the differences in emissions between the two types of waste, in support of the assertion that modeling data from CH TRU waste adequately

149

Arid sites stakeholder participation in evaluating innovative technologies: VOC-Arid Site Integrated Demonstration  

SciTech Connect (OSTI)

Developing and deploying innovative environmental cleanup technologies is an important goal for the U.S. Department of Energy (DOE), which faces challenging remediation problems at contaminated sites throughout the United States. Achieving meaningful, constructive stakeholder involvement in cleanup programs, with the aim of ultimate acceptance of remediation decisions, is critical to meeting those challenges. DOE`s Office of Technology Development sponsors research and demonstration of new technologies, including, in the past, the Volatile Organic Compounds Arid Site Integrated Demonstration (VOC-Arid ID), hosted at the Hanford Site in Washington State. The purpose of the VOC-Arid ID has been to develop and demonstrate new technologies for remediating carbon tetrachloride and other VOC contamination in soils and ground water. In October 1994 the VOC-Arid ID became a part of the Contaminant Plume Containment and Remediation Focus Area (Plume Focus Area). The VOC Arid ID`s purpose of involving stakeholders in evaluating innovative technologies will now be carried on in the Plume Focus Area in cooperation with Site Technology Coordination Groups and Site Specific Advisory Boards. DOE`s goal is to demonstrate promising technologies once and deploy those that are successful across the DOE complex. Achieving that goal requires that the technologies be acceptable to the groups and individuals with a stake in DOE facility cleanup. Such stakeholders include groups and individuals with an interest in cleanup, including regulatory agencies, Native American tribes, environmental and civic interest groups, public officials, environmental technology users, and private citizens. This report documents the results of the stakeholder involvement program, which is an integral part of the VOC-Arid ID.

Peterson, T.S.; McCabe, G.H.; Brockbank, B.R. [and others

1995-05-01T23:59:59.000Z

150

Mechanisms for formation of organic and inorganic by-products and their control in nonthermal plasma chemical processing of VOCs  

Science Journals Connector (OSTI)

This paper presents the major by-products derived from Nonthermal Plasma (NTP) chemical processing of different types of Volatile Organic Compounds (VOCs), mechanisms for their formation, effects of reactor types and additives such as water and gaseous oxygen on by-product distribution, and safe operations of NTP reactors for the removal of VOCs.

Shigeru Futamura; Masami Sugasawa

2008-01-01T23:59:59.000Z

151

Effects of Environmental Conditions on the Sorption of VOCs on Building Materials-Part II: Model Evaluation (RP-1097)  

E-Print Network [OSTI]

1 Effects of Environmental Conditions on the Sorption of VOCs on Building Materials-Part II: Model, Ph.D. Member ASHRAE 1 ABSTRACT: Sorption data obtained by using small environmental chambers under to evaluate the linear Langmuir model and the diffusion model for VOC sorption by different building materials

Chen, Qingyan "Yan"

152

LOW NOx EMISSIONS IN A FUEL FLEXIBLE GAS TURBINE  

SciTech Connect (OSTI)

In alignment with Vision 21 goals, a study is presented here on the technical and economic potential for developing a gas turbine combustor that is capable of generating less that 2 ppm NOx emissions, firing on either coal synthesis gas or natural gas, and being implemented on new and existing systems. The proposed solution involves controlling the quantity of H2 contained in the fuel. The presence of H2 leads to increased flame stability such that the combustor can be operated at lower temperatures and produce less thermal NOx. Coal gas composition would be modified using a water gas shift converter, and natural gas units would implement a catalytic partial oxidation (CPOX) reactor to convert part of the natural gas feed to a syngas before fed back into the combustor. While both systems demonstrated technical merit, the economics involved in implementing such a system are marginal at best. Therefore, Praxair has decided not to pursue the technology any further at this time.

Raymond Drnevich; James Meagher; Vasilis Papavassiliou; Troy Raybold; Peter Stuttaford; Leonard Switzer; Lee Rosen

2004-08-01T23:59:59.000Z

153

Diesel Aftertreatment Modeling:? A Systems Approach to NOx Control  

Science Journals Connector (OSTI)

Diesel Aftertreatment Modeling:? A Systems Approach to NOx Control ... Despite these challenges, the proposed system was able to make several advances:? (1) meeting the T2B5 CO, HC, and PM standards; (2) quantifying the ability to meet T2B5 NOx levels with a more durable DOC and a rapid warm-up strategy to heat the exhaust, especially during the initial cold-start portion of the Federal Test Procedure (FTP) drive cycle. ... The remainder of this work is organized as follows:? The formulation, calibration, and validation of the DOC and SCR models are presented in section 2. The DOC and SCR models are combined for an analysis of the AT system as a whole in section 3. The final section of the article summarizes the results and offers some general conclusions. ...

Santhoji R. Katare; Joseph E. Patterson; Paul M. Laing

2007-03-16T23:59:59.000Z

154

Photoconductive Decay Lifetime and Suns-Voc Diagnostics of Efficient Heterojunction Solar Cells: Preprint  

SciTech Connect (OSTI)

We report results of minority carrier lifetime measurements for double-sided p-type Si heterojunction devices and compare Suns-Voc results to Light I-V measurements on 1 cm2 solar cell devices measured on an AM1.5 calibrated XT-10 solar simulator.

Page, M. R.; Iwaniczko, E.; Xu, Y.; Roybal L.; Bauer, R.; Yan, H.-C.; Wang, Q.; Meier, D. L.

2008-05-01T23:59:59.000Z

155

Carbide-Derived Carbons for Adsorptive Removal of VOCs from Air Streams  

E-Print Network [OSTI]

Carbide-Derived Carbons for Adsorptive Removal of VOCs from Air Streams References 1. USEPA Literature Results Carbide-Derived Carbons Motivation Future Research · The effect of pore size and pore size decreasing removal cost is an advancement for the industry and the environment. Carbide-derived carbons (CDCs

Das, Suman

156

Determination of VOC emissions from French wood products Christophe YRIEIX *, Franois MAUPETIT **, Olivier RAMALHO **  

E-Print Network [OSTI]

building products. Introduction Today, it is well known that building products may influence indoor air1/10 Determination of VOC emissions from French wood products Christophe YRIEIX *, François air quality (IAQ), it appears necessary to have analytical protocol for the measurement and health

Paris-Sud XI, Université de

157

MEASUREMENT OF VOC EMISSIONS FROM WOOD REMEDIAL TREATMENT: CHAMBER TESTS AND FIELD EXPERIMENTS  

E-Print Network [OSTI]

products on indoor air quality. The emissions of two wood remedial treatment products (water in real conditions during a roof renovation work in an old building. A petroleum-based solvent product of volatile organic compound (VOC) emissions from building products. Simple models can be applied to emission

Paris-Sud XI, Université de

158

Energy Recovery Efficiency and Cost Analysis of VOC Thermal Oxidation Pollution Control Technology  

Science Journals Connector (OSTI)

Respective cost models were derived for recuperative thermal oxidizer (TO) and regenerative thermal oxidizer (RTO). ... In a thermal oxidation process, VOC-laden air is thermally treated (oxidized/decomposed) at temperatures about 730?850 C. ... Choi and Yi(4) worked on the simulation and optimization of regenerative thermal oxidizers. ...

Aruna S. K. Warahena; Yew Khoy Chuah

2009-06-24T23:59:59.000Z

159

Adsorption of VOCs from the Gas Phase to Different Minerals and a Mineral Mixture  

Science Journals Connector (OSTI)

Adsorption of VOCs from the Gas Phase to Different Minerals and a Mineral Mixture ... Here adsorption to three well-defined minerals (hematite, corundum, and lime) was studied by a chromatographic method. ... (39)?Suzuki, S.; Green, P. G.; Bumgarner, R. E.; Dasgupta, S.; Goddard, W. A.; Blake, G. A. Science 1992, 257, 942?945. ...

Kai-Uwe Goss; Steven J. Eisenreich

1996-06-26T23:59:59.000Z

160

Energy efficient indoor VOC air cleaning with activated carbon fiber (ACF) filters Meera A. Sidheswaran a  

E-Print Network [OSTI]

carbon fiber (ACF) filters for air cleaning in HVAC systems. The parallel aims for the air cleaningEnergy efficient indoor VOC air cleaning with activated carbon fiber (ACF) filters Meera A. Velocities through the ACF media were typical of those in normal particle filter systems (w0.5 m s?1

Note: This page contains sample records for the topic "nox ods voc" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Photocatalytic Degradation of VOC's by TOTO's Hydrotect (TiO2 Impregnated) Surfaces  

E-Print Network [OSTI]

, naturally occurs in wood and volcanic gases. Decaying organic matter can also produce methanol. Paint. This report describes the photocatalytic degradation of formaldehyde and methanol, two common VOC's, by TiO2 and methanol tests (Land et al., 2008). A standardized aqueous solution of formaldehyde and methanol was used

Bergin, Mike

162

Transmission electron microscopy of oxide dispersion strengthened (ODS) molybdenum: effects of irradiation on material microstructure  

SciTech Connect (OSTI)

Oxide dispersion strengthened (ODS) molybdenum has been characterized using transmission electron microscopy (TEM) to determine the effects of irradiation on material microstructure. This work describes the results-to-date from TEM characterization of unirradiated and irradiated ODS molybdenum. The general microstructure of the unirradiated material consists of fine molybdenum grains (< 5 {micro}m average grain size) with numerous low angle boundaries and isolated dislocation networks. 'Ribbon'-like lanthanum oxides are aligned along the working direction of the product form and are frequently associated with grain boundaries, serving to inhibit grain boundary and dislocation movement. In addition to the 'ribbons', discrete lanthanum oxide particles have also been detected. After irradiation, the material is characterized by the presence of nonuniformly distributed large ({approx} 20 to 100 nm in diameter), multi-faceted voids, while the molybdenum grain size and oxide morphology appear to be unaffected by irradiation.

Baranwal, R. and Burke, M.G.

2003-03-03T23:59:59.000Z

163

NOx Control Options and Integration for US Coal Fired Boilers  

SciTech Connect (OSTI)

This is the Final Report for DOE Cooperative Agreement No: DE-FC26-00NT40753. The goal of the project was to develop cost-effective analysis tools and techniques for demonstrating and evaluating low-NOx control strategies and their possible impact on boiler performance for boilers firing US coals. The Electric Power Research Institute (EPRI) provided co-funding for this program. This project included research on: (1) In furnace NOx control; (2) Impacts of combustion modifications on boiler operation; (3) Selective Catalytic Reduction (SCR) catalyst testing and (4) Ammonia adsorption/removal on fly ash. Important accomplishments were achieved in all aspects of the project. Rich Reagent Injection (RRI), an in-furnace NOx reduction strategy based on injecting urea or anhydrous ammonia into fuel rich regions in the lower furnace, was evaluated for cyclone-barrel and PC fired utility boilers. Field tests successfully demonstrated the ability of the RRI process to significantly reduce NOx emissions from a staged cyclone-fired furnace operating with overfire air. The field tests also verified the accuracy of the Computational Fluid Dynamic (CFD) modeling used to develop the RRI design and highlighted the importance of using CFD modeling to properly locate and configure the reagent injectors within the furnace. Low NOx firing conditions can adversely impact boiler operation due to increased waterwall wastage (corrosion) and increased soot production. A corrosion monitoring system that uses electrochemical noise (ECN) corrosion probes to monitor, on a real-time basis, high temperature corrosion events within the boiler was evaluated. Field tests were successfully conducted at two plants. The Ohio Coal Development Office provided financial assistance to perform the field tests. To investigate soot behavior, an advanced model to predict soot production and destruction was implemented into an existing reacting CFD modeling tool. Comparisons between experimental data collected in a pilot scale furnace and soot behavior predicted by the CFD model showed good agreement. Field and laboratory tests were performed for SCR catalysts used for coal and biomass co-firing applications. Fundamental laboratory studies were performed to better understand mechanisms involved with catalyst deactivation. Field tests with a slip stream reactor were used to create catalyst exposed to boiler flue gas for firing coal and for co-firing coal and biomass. The field data suggests the mechanisms leading to catalyst deactivation are, in order of importance, channel plugging, surface fouling, pore plugging and poisoning. Investigations were performed to better understand the mechanisms involved with catalyst regeneration through mechanical or chemical methods. A computer model was developed to predict NOx reduction across the catalyst in a SCR. Experiments were performed to investigate the fundamentals of ammonia/fly ash interactions with relevance to the operation of advanced NOx control technologies such as selective catalytic reduction. Measurements were performed for ammonia adsorption isotherms on commercial fly ash samples subjected to a variety of treatments and on the chemistry of dry and semi-dry ammonia removal processes. This work resulted in the first fundamental ammonia isotherms on carbon-containing fly ash samples. This work confirms industrial reports that aqueous solution chemistry takes place upon the introduction of even very small amounts of water, while the ash remains in a semi-dry state.

Mike Bockelie; Marc Cremer; Kevin Davis; Martin Denison; Adel Sarofim; Connie Senior; Hong-Shig Shim; Dave Swenson; Bob Hurt; Eric Suuberg; Eric Eddings; Kevin Whitty; Larry Baxter; Calvin Bartholomew; William Hecker

2006-06-30T23:59:59.000Z

164

Assessment of subsurface VOCs using a chemical microsensor array. Final report  

SciTech Connect (OSTI)

This report describes the results of laboratory investigations of several performance parameters relevant to surface-acoustic-wave (SAW) chemical sensor arrays for the measurement of volatile organic compounds (VOCs) in contaminated soil and groundwater. The small size, low cost, sensitivity and selectivity of such instruments promise improvements in the quality and quantity of data used to guide site assessment and restoration efforts. In this investigation, calibrations were performed for 15 different coated SAW sensors. Each sensor was exposed to six VOCs selected to represent three chemical classes of contaminants that are commonly found at waste sites (i.e., aliphatic, aromatic and chlorinated hydrocarbons). A new pattern recognition method was developed for determining which coated sensors would maximize the selectivity and accuracy of quantitation for a given set of vapor contaminants. Using this method, an optimal subwet of four coated sensors was selected for testing in a prototype microsensor instrument. Additional laboratory experiments were performed with this optimized array to assess the limits of detection and linear response ranges for the representative vapors, as well as the additivity of responses to vapors in binary mixtures, temperature and humidity effects, aging effects, and other performance parameters related to the application of this technology to soil and groundwater VOC monitoring. Results demonstrate that SAW microsensor arrays can identify and quantify specific VOCs at concentrations in the {mu}g/L to mg/L range when present alone or in simple (e.g., binary) mixtures. SAW sensor technology offers a potentially effective alternative to existing field instrumentation for headspace analysis, soil vapor monitoring, and vacuum extraction process monitoring of VOCs in subsurface media.

Batterman, S.A.; Zellers, E.T. [Michigan Univ., Ann Arbor, MI (United States). School of Public Health

1993-06-01T23:59:59.000Z

165

A Fast Start-up On-Board Fuel Reformer for NOx Adsorber Regeneration...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Fuel Processor for Rapid and Efficient Regeneration of Single Leg NOx Adsorber Systems Hydrogen generation from plasmatron reformers and use for diesel exhaust aftertreatment...

166

High-Throughput Program for the Discovery of NOx Reduction Catalysts...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

2004deerblint.pdf More Documents & Publications WA02042GENERALMOTORSPOWERTRAINDIVWaiverofDomestic.pdf Heavy-Duty NOx Emissions Control: Reformer-Assisted vs....

167

Boosted HCCI for High Power without Engine Knock, and with Ultra-Low NOX Emissions  

Broader source: Energy.gov [DOE]

Advanced engines using HCCI or HCCI-like combustion can provide both high efficiencies and very low emissions of NOX and PM

168

Synergies of High-Efficiency Clean Combustion and Lean NOx Trap...  

Broader source: Energy.gov (indexed) [DOE]

Combustion and Lean NOx Trap Catalysts investigation of potential synergies of low emission advanced combustion techniques and advanced lean exhaust catalytic aftertreatment....

169

E-Print Network 3.0 - aluminosilicates nox reduction Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

RELATIONSHIP BETWEEN Summary: Non-Catalytic Reduction SNCR NOx control throughout the United States and Canada. They correspond... explain why mass balances are not an appro...

170

Reduce NOx and Improve Energy Efficiency, Software Tools for Industry, Industrial Technologies Program (ITP) (Fact Sheet)  

SciTech Connect (OSTI)

This fact sheet describes how the Industrial Technologies Program NOx and Energy Assessment Tool (NxEAT) can help petroleum refining and chemical plants improve energy efficiency.

Not Available

2008-12-01T23:59:59.000Z

171

Deactivation mechanisms of NOx storage materials arising from thermal aging and sulfur poisoning  

Broader source: Energy.gov [DOE]

Presents the reliationship between Pt particle size and NOx storage performance over model catalysts. Novel reaction protocol designed to decouple effects of thermal deactivation and incomplete desulfation.

172

16 - Ultra-low nitrogen oxides (NOx) emissions combustion in gas turbine systems  

Science Journals Connector (OSTI)

Abstract: The historical development of gas turbine low \\{NOx\\} combustion from the pioneering NASA work in the early 1970s to the present generation of ultra-low \\{NOx\\} industrial gas turbine combustors is reviewed. The principles of operation of single digit ultra-low \\{NOx\\} gas turbine combustion for industrial applications are outlined. The review shows the potential has been demonstrated by several investigators using different flame stabilizers for \\{NOx\\} to be reduced to 1ppm at 1700K, 2ppm at 1800K and 34ppm at 1900K with no influence of operating pressure and with a practical operating flame stability margin. Under these conditions it is shown that no thermal \\{NOx\\} should occur and all the \\{NOx\\} is formed by the prompt \\{NOx\\} mechanisms. The elimination of thermal \\{NOx\\} makes the \\{NOx\\} emissions independent of residence time or reference velocity and independent of pressure. Also there is no influence of air inlet temperature for the same flame temperature. Where legislation requires emissions to be as low as can be achieved, emissions below 4ppm in production engines are current technology and this review shows the potential to get even lower than this in the future.

G.E. Andrews

2013-01-01T23:59:59.000Z

173

The mechanisms and relative importance of abiotic and biological processes for VOC loss from sludge amended soils  

SciTech Connect (OSTI)

The presence of volatile organic compounds (VOCs) in sewage sludge has been a cause of increasing concern due to the possible risk to human health and the environment when sludge is applied to agricultural soils. Sludge application to agricultural land in the UK is expected to increase as a result of restrictions on alternative disposal routes and also increasingly stringent wastewater treatment requirements. Few studies have examined the fate and behavior of VOCs in sewage sludge amended soils and those reported have used spiked sludge rather than investigating the behavior of VOCs resident in the sludge itself. This study was designed to evaluate the behavior of aromatic VOCs (namely toluene, xylene and ethyl benzene) in unspiked sewage sludge amended soils and assess the relative importance and mechanisms of abiotic and biological loss processes. This was undertaken by adding sewage sludge to sterilized and unsterilized soil in closed and open systems. Results indicated that abiotic loss processes, primarily volatilization, were most important for the removal of VOCs. Initial rate of VOC loss was similar in all systems. After 65 days a residual VOC soil concentration remained which was apparently dependent on the conditions within the system.

Wilson, S.C.; Jones, K.C. [Lancaster Univ. (United Kingdom). Inst. of Environmental and Biological Sciences

1994-12-31T23:59:59.000Z

174

METHANE de-NOX FOR UTILITY PC BOILERS  

SciTech Connect (OSTI)

The project seeks to develop and validate a new pulverized coal combustion system to reduce utility PC boiler NOx emissions to 0.15 lb per million Btu or less without post-combustion flue gas cleaning. Work during previous reporting periods completed the design, installation, shakedown and initial PRB coal testing of a 3-million Btu/h pilot system at BBP's Pilot-Scale Combustion Facility (PSCF) in Worcester, MA. Based on these results, modifications to the gas-fired preheat combustor and PC burner were defined, along with a modified testing plan and schedule. A revised subcontract was executed with BBP to reflect changes in the pilot testing program. Modeling activities were continued to develop and verify revised design approaches for both the Preheat gas combustor and PC burner. Reactivation of the pilot test system was then begun with BBP personnel. During the previous reporting period, reactivation of the pilot test system was completed with the modified Preheat gas combustor. Following shakedown of the modified gas combustor alone, a series of successful tests of the new combustor with PRB coal using the original PC burner were completed. NOx at the furnace exit was reduced significantly with the modified gas combustor, to as low as 150 ppm with only 36 ppm CO (both corrected to 3% O2). Concurrent with testing, GTI and BBP collaborated on development of two modified designs for the PC burner optimized to fire preheated char and pyrolysis products from the Preheat gas combustor. During the current reporting period, one of the two modified PC burner designs was fabricated and installed in the pilot test facility. Testing of the modified pilot system (modified gas combustor and modified PC burner) during the quarter included 38 tests with PRB coal. NOx reduction was significantly improved to levels as low as 60-100 ppmv with CO in the range of 35-112 ppmv without any furnace air staging.

Joseph Rabovitser; Bruce Bryan; Serguei Nester; Stan Wohadlo

2002-01-31T23:59:59.000Z

175

NOx CONTROL OPTIONS AND INTEGRATION FOR US COAL FIRED BOILERS  

SciTech Connect (OSTI)

This is the fifth Quarterly Technical Report for DOE Cooperative Agreement No: DE-FC26-00NT40753. The goal of the project is to develop cost effective analysis tools and techniques for demonstrating and evaluating low NOx control strategies and their possible impact on boiler performance for firing US coals. The Electric Power Research Institute (EPRI) is providing cofunding for this program. This program contains multiple tasks and good progress is being made on all fronts. Field tests for NOx reduction in a cyclone fired utility boiler due to using Rich Reagent Injection (RRI) have been started. CFD modeling studies have been started to evaluate the use of RRI for NOx reduction in a corner fired utility boiler using pulverized coal. Field tests of a corrosion monitor to measure waterwall wastage in a utility boiler have been completed. Computational studies to evaluate a soot model within a boiler simulation program are continuing. Research to evaluate SCR catalyst performance has started. A literature survey was completed. Experiments have been outlined and two flow reactor systems have been designed and are under construction. Commercial catalyst vendors have been contacted about supplying catalyst samples. Several sets of new experiments have been performed to investigate ammonia removal processes and mechanisms for fly ash. Work has focused on a promising class of processes in which ammonia is destroyed by strong oxidizing agents at ambient temperature during semi-dry processing (the use of moisture amounts less than 5 wt-%). Both ozone and an ozone/peroxide combination have been used to treat both basic and acidic ammonia-laden ashes.

Mike Bockelie; Marc Cremer; Kevin Davis; Connie Senior; Bob Hurt; Eric Eddings; Larry Baxter

2001-10-10T23:59:59.000Z

176

SOx/NOx sorbent and process of use  

DOE Patents [OSTI]

An alumina sorbent capable of adsorbing NOx and SOx from waste gases and being regenerated by heating above 600 C. is made by incorporating an alumina stabilizing agent into the sorbent. A preferred method is to add the stabilizer when the alumina is precipitated. The precipitated powder is formed subsequently into a slurry, milled and dripped to form the stabilizing spheroidal alumina particles. These particles are impregnated with an alkali metal or alkaline earth metal to form the stabilized sorbent. Alumina stabilizers include one or more of silica, lanthana, other rare earths, titania, zirconia and alkaline earths.

Ziebarth, M.S.; Hager, M.J.; Beeckman, J.W.; Plecha, S.

1993-01-19T23:59:59.000Z

177

Global impact of fossil fuel combustion on atmospheric NOx Larry W. Horowitz  

E-Print Network [OSTI]

potential than emissions in the United States to perturb the global oxidizing power of the atmosphere. #12% of NOx concentrations in the lower and middle troposphere throughout the extratropical northern of the ocean. Sources in the United States are found to contribute about half of the fossil fuel NOx over

Jacob, Daniel J.

178

On the NOx production by laboratory electrical discharges and lightning Vernon Cooraya,, Mahbubur Rahman a  

E-Print Network [OSTI]

in estimating the global production of NOx by lightning flashes, including field measurements carried out during influence extrapolation of laboratory data to lightning flashes. Second, an estimation of the NOx yield per lightning flash is made by treating the lightning flash as a composite event consisting of several discharge

Florida, University of

179

Measurements of NOX produced by rocket-triggered lightning M. Rahman,1  

E-Print Network [OSTI]

lightning flashes were triggered using the rocket- and-wire technique at the International Center atmosphere. [3] A direct measurement of the NOX generated by a natural lightning flash is impractical because generated by lightning flashes. Due to a large number of uncertainties involved, the estimates of global NOX

Florida, University of

180

A Novel Technology for the Reduction of NOx on Char by Microwaves  

E-Print Network [OSTI]

of these applications. The technology is directed at NOx reduction but may also address other pollutants like SO2. The technology employees char, a heat treated and devolitilized form of coal, to adsorb NOx from the flue (or waste) gas. Adsorption of greater than 99...

Buenger, C.; Peterson, E.

Note: This page contains sample records for the topic "nox ods voc" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Improvement of lightning NOx in the TM5 global chemistry transport model  

E-Print Network [OSTI]

, a key greenhouse gas, and for the formation of the hydroxyl28 radical, which removes methane, also a key greenhouse gas. Estimates of the global lightning NOx production vary29 by an order of magnitude interpreting the lighting NOx contribu-36 tion from satellite and aircraft observations of NO2 in comparison

Haak, Hein

182

Development of a Stand-Alone Urea-SCR System for NOx Reduction in Marine Diesel Engines  

Broader source: Energy.gov [DOE]

Stand-alone urea SCR system was developed for marine diesel engines and showed a 50-percent reduction in NOx.

183

Development of Compact Gaseous Sensors with Internal Reference for Monitoring O2 and NOx in Combustion Environments  

Broader source: Energy.gov [DOE]

Compact sensors have been developed to allow for real-time monitoring of O2 and NOx during combustion.

184

Advanced NOx Emissions Control: Control Technology - Second Generation  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Second Generation Advanced Reburning Second Generation Advanced Reburning General Electric - Energy and Environmental Research Corporation (GE-EER) is carrying out a two Phase research program to develop novel Advanced Reburning (AR) concepts for high efficiency and low cost NOx control from coal-fired utility boilers. AR technologies are based on combination of basic reburning and N-agent/promoter injections. Phase I of the project was successfully completed and EER was selected to continue to develop AR technology during Phase II. Phase I demonstrated that AR technologies are able to provide effective NOx control for coal-fired combustors. Three technologies were originally envisioned for development: AR-Lean, AR-Rich, and Multiple Injection AR (MIAR). Along with these, three additional technologies were identified during the project: reburning plus promoted SNCR; AR-Lean plus promoted SNCR; and AR-Rich plus promoted SNCR. The promoters are sodium salts, in particular sodium carbonate. These AR technologies have different optimum reburn heat input levels and furnace temperature requirements. For full scale application, an optimum technology can be selected on a boiler-specific basis depending on furnace temperature profile and regions of injector access.

185

2004 Conference on Reburning for NOX Control Reburning on Trial  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

2004 Conf. on Reburning for NOx Control Reburning on Trial 2004 Conf. on Reburning for NOx Control Reburning on Trial May 18, 2004 Table of Contents Disclaimer Papers and Presentations Reburning Overview Commercial Reburning Experience Biomass Reburning Other Applications of Reburning Posters Disclaimer This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government or any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. Reference herein to any specific commercial product, process, or service by trade name, trademark, manufacturer, or otherwise does not necessarily constitute or imply its endorsement, recommendation, or favoring by the United States Government or any agency thereof. The views and opinions of authors expressed herein do not necessarily state or reflect those of the United States Government or any agency thereof.

186

NETL: PPII - Integration of Low-NOx Burners with an Optimization Plan for  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Integration of Low-NOx Burners with an Optimization Plan for Boiler Combustion Integration of Low-NOx Burners with an Optimization Plan for Boiler Combustion - Project Brief [PDF-72KB] Sunflower Electric Power Corp., Garden City, Finney County, KS PROJECT FACT SHEET Achieving New Source Performance Standards (NSPS) Through Integration of Low-NOx Burners with an Optimization Plan for Boiler Combustion [PDF-260KB] (Oct 2008) PROGRAM PUBLICATIONS Final Report Achieving NSPS Emission Standards Through Integration of Low NOx Burners with an Optimization Plan for Boiler Combustion [PDF-3.4MB] (June 2006) CCT Reports: Project Performance Summaries, Post-Project Assessments, & Topical Reports Achieving New Source Performance Standards (NSPS) Emission Standards through Integration of Low-NOx Burners with an Optimization Plan for Boiler Combustion: A DOE Assessment [PDF-1.4MB] (Nov 2006)

187

EA-1472: Commercial Demonstration fo the Low Nox Burner/Separated Over-Fire  

Broader source: Energy.gov (indexed) [DOE]

472: Commercial Demonstration fo the Low Nox Burner/Separated 472: Commercial Demonstration fo the Low Nox Burner/Separated Over-Fire Air (LNB/SOFA) Integration System Emission Reduction Technology, Holcolm Station, Sunflower Electric Power Corporation Finnety County, Kansas EA-1472: Commercial Demonstration fo the Low Nox Burner/Separated Over-Fire Air (LNB/SOFA) Integration System Emission Reduction Technology, Holcolm Station, Sunflower Electric Power Corporation Finnety County, Kansas SUMMARY The DOE has prepared an Environmental Assessment (EA), to analyze the potential impacts of the commercial application of the Low-NOx Burner/Separated Over-Fire Air (LNB/SOFA) integration system to achieve nitrogen oxide (NOx) emissions reduction at Sunflower's Holcomb Unit No. 1 (Holcomb Station), located near Garden City, in Finney County, Kansas.

188

Treatability test of a stacked-tray air stripper for VOC in water  

SciTech Connect (OSTI)

A common strategy for hydraulic containment and mass removal at VOC contaminated sites is `pump and treat (P&T)`. In P&T operations, contaminated ground water is pumped from wells, treated above ground, and discharged. Many P&T remediation systems at VOC sites rely on air stripping technology because VOCs are easily transferred to the vapor phase. In stacked-tray air strippers, contaminated water is aerated while it flows down through a series of trays. System operations at LLNL are strictly regulated by the California and federal Environmental Protection Agencies (Cal/EPA and EPA), the Bay Area Air Quality Management District (BAAQMD), the California Regional Water Quality Control Board (RWQCB) and the Department of Toxic Substances Control (DTSC). These agencies set discharge limits, require performance monitoring, and assess penalties for non-compliance. National laboratories are also subject to scrutiny by the public and other government agencies. This extensive oversight makes it necessary to accurately predict field treatment performance at new extraction locations to ensure compliance with all requirements prior to facility activation. This paper presents treatability test results for a stacked- tray air stripper conducted at LLNL and compares them to the vendor`s modeling software results.

Pico, T., LLNL

1998-04-01T23:59:59.000Z

189

Regenerative thermal oxidizers for VOC and NO{sub x} -- efficiency and cost  

SciTech Connect (OSTI)

Regenerative fume incinerators or thermal oxidizers have a combustion chamber at about 1,600 F. Heat recovery is provided by switching regenerator beds filled with ceramic. Volatile organic compounds, VOC`s, are about 99% removed along with a thermal efficiency of 90 to 95%. Improvements are discussed which reduce fuel costs, reduce investment cost and give better VOC removal. A method of preventing NO{sub x} formation is presented as well as a possible method for removing NO{sub x} from incoming feed gas. Regenerative fume incinerators or regenerative thermal oxidizers have 3 possible improvements. (1) Add the required fuel to the incoming gas to nearly eliminate NO{sub x} generation while improving thermal efficiency. (2) Remove NO{sub x} from the incoming gas by a new modification of the Exxon Thermal DeNO{sub x} process. (3) Use a new 4-way valve for 1 or 2-bed regenerators to cut investment and improve destruction efficiency.

Houston, R. [Houston Consulting, Hendersonville, NC (United States)

1995-12-31T23:59:59.000Z

190

VOC/HAP control systems for the shipbuilding and aerospace industries  

SciTech Connect (OSTI)

Compliant coating systems, i.e., those which meet limits on pounds of volatile organic compound (VOC)/hazardous air pollutant (HAP) per gallon, on a solids applied basis, are routinely used to meet emission regulations in the shipbuilding and aerospace industries. However, there are occasions when solvent based systems must be used. Total capture and high destruction of the solvents in those systems is necessary in order to meet the required emission limit, e.g., a reasonably available control technology (RACT) limit of 3.5lbs of VOC/gallon. Water based marine coatings and certain aerospace finish coats do not provide sufficient longevity or meet other customer specifications in these instances. Furthermore, because of best available control technology (BACT) determinations or facility limits for operation in serious, severe, and extreme nonattainment areas, it is necessary to reduce annual emissions to levels which are below the levels required by the coating standards. The paper discusses those operations for controlling emissions from large-scale solvent based painting and coating systems in those instances when a high degree of overall control is required. Permanent total enclosures (stationary and portable), concentrators, regenerative thermal oxidizers, and other air pollution control systems are evaluated, both for technical applicability and economic feasibility. Several case studies are presented which illustrate techniques for capturing painting emissions, options for air handling in the workplace, and methods for destroying exhaust stream VOC concentrations of less than 40 ppm.

Lukey, M.E.; Toothman, D.A.

1999-07-01T23:59:59.000Z

191

The Change in the hardness of LCAC. TZM, and ODS molybdenum in the post-irradiated and annealed conditions  

SciTech Connect (OSTI)

Hardness measurements were performed on wrought Low Carbon Arc Cast (LCAC), TZM, and Oxide Dispersion Strengthened (ODS) molybdenum in the post-irradiated and post-irradiated + annealed condition to determine the recovery kinetics. Irradiations performed in the High Flux Isotope Reactor (HFIR) at nominally 300 C and 600 C to neutron fluence levels that range from 10.5 to 246 x 10{sup 24} n/m{sup 2} (E > 0.1 MeV) resulted in relatively large increases in hardness (77-109%), while small increases in hardness (<18%) were observed for irradiations at 870-1100 C. The hardness recovery for ODS and LCAC irradiated at 300 C and 600 C were shown to be complete at 980 C and {approx} 1100-1250 C, respectively. Isothermal annealing at 700 C was used to determine the activation energy for recovery of LCAC and ODS (3.70-4.88 eV {+-} 0.28-0.77 eV), which is comparable to values reported in the literature for molybdenum vacancy self-diffusion. This suggests that recovery of LCAC and ODS is controlled by the solid-state diffusion of vacancies in the bulk, and that the finer grain size and particle size ODS does not affect this mechanism. TZM exhibited slower recovery kinetics, which can be explained by the solute atoms (titanium and zirconium) inhibiting vacancy diffusion.

Cockeram, Brian V [Bechtel-Bettis, Inc.; Smith, Richard W [Bechtel-Bettis, Inc.; Byun, Thak Sang [ORNL; Snead, Lance Lewis [ORNL

2009-01-01T23:59:59.000Z

192

Acquisition LetteJ'S (AL) that remain in effect are identified below. All odJer  

Broader source: Energy.gov (indexed) [DOE]

LetteJ'S (AL) that remain in effect are identified below. All odJer previously issued ALs have been LetteJ'S (AL) that remain in effect are identified below. All odJer previously issued ALs have been supersedcd by a formal rule-making. incorporated into other guidance, and/or canceled. ~ ~,COUISITION LETTERS REMAINING IN EFFECT NUMBER 93-4 94-19 95-06 95-14 96-09 98-04 98-11 99.{)4 99-06 2000-02 2000-05 2000-08 2000-09 2000-10R 2000-12 200 1-03 ~ SUBJECT !!AIE 04/07/93 12/09/94 06!2819~ 11/17/9~ Displaced Workers Benefits Program Basic Labor Policies Fringe Benefits Personal Property Letter System Subcontracts under the New Independent States - Industrial Partnering Program Full and Open Competition - Management and Operating Contracts Diversity Plans Waiver of Synopsis Requirements Consortium Buying 09/16/96 03/11/98 09/18/98 06/23/99 08/27/99 DOE Authorized Subcontract for Use by DOE Management and

193

HRTEM Study of Oxide Nanoparticles in K3-ODS Ferritic Steel Developed for Radiation Tolerance  

SciTech Connect (OSTI)

Crystal and interfacial structures of oxide nanoparticles and radiation damage in 16Cr-4.5Al-0.3Ti-2W-0.37 Y{sub 2}O{sub 3} ODS ferritic steel have been examined using high-resolution transmission electron microscopy (HRTEM) techniques. Oxide nanoparticles with a complex-oxide core and an amorphous shell were frequently observed. The crystal structure of complex-oxide core is identified to be mainly monoclinic Y{sub 4}Al{sub 2}O{sub 9} (YAM) oxide compound. Orientation relationships between the oxide and the matrix are found to be dependent on the particle size. Large particles (> 20 nm) tend to be incoherent and have a spherical shape, whereas small particles (< 10 nm) tend to be coherent or semi-coherent and have a faceted interface. The observations of partially amorphous nanoparticles and multiple crystalline domains formed within a nanoparticle lead us to propose a three-stage mechanism to rationalize the formation of oxide nanoparticles containing core/shell structures in as-fabricated ODS steels. Effects of nanoparticle size and density on cavity formation induced by (Fe{sup 8+} + He{sup +}) dual-beam irradiation are briefly addressed.

Hsiung, L; Fluss, M; Tumey, S; Kuntz, J; El-Dasher, B; Wall, M; Choi, W; Kimura, A; Willaime, F; Serruys, Y

2009-11-02T23:59:59.000Z

194

Cross-Roll Flow Forming of ODS Alloy Heat Exchanger Tubes for Hoop Creep Enhancement  

SciTech Connect (OSTI)

Mechanically alloyed oxide dispersion strengthened (ODS) Fe-Cr-Al alloy thin walled tubes and sheets, produced via powder processing and consolidation methodologies, are promising materials for eventual use at temperatures up to 1200 C in the power generation industry, far above the temperature capabilities of conventional alloys. Target end-uses range from gas turbine combustor liners to high aspect ratio (L/D) heat exchanger tubes. Grain boundary creep processes at service temperatures, particularly those acting in the hoop direction, are the dominant failure mechanisms for such components. The processed microstructure of ODS alloys consists of high aspect ratio grains aligned parallel to the tube axis, a result of dominant axial metal flow which aligns the dispersoid particles and other impurities in the longitudinal direction. The dispersion distribution is unaltered on a micro scale by recrystallization thermal treatments, but the high aspect ratio grain shape typically obtained limits transverse grain spacing and consequently the hoop creep response. Improving hoop creep in ODS-alloy components will require understanding and manipulating the factors that control the recrystallization behavior, and represents a critical materials design and development challenge that must be overcome in order to fully exploit the potential of ODS alloys. The objectives of this program are to (1) increase creep-strength at temperature in ODS-alloy tube and liner components by 100% via, (2) preferential cross-roll flow forming and grain/particle fibering in the critical hoop direction. The research program outlined here is iterative in nature and is intended to systematically (1) examine and identify post-extrusion forming methodologies to create hoop strengthened tubes, which will be (2) evaluated at ''in-service'' loads at service temperatures and environments. This research program is being conducted in collaboration with the DOE's Oak Ridge National Laboratory and the vested industrial partner Special Metals Corporation. In this ninth quarter of performance, program activities are continued for Tasks 2, 3 and 4 and are reported herein. Two sets of MA956 tube material samples rotary crossrolled at rolling angles of {beta} = 2{sup o} and 8{sup o} are processed in Task 3 and available for mechanical property testing in the remainder of this project. These samples are at various stages of creep testing and evaluation in Task 4. The creep rigs are being upgraded to handle long term testing at 1000 C and above. Reduced test times at accelerated temperatures will allow for additional testes to be conducted resulting in overall robust creep data statistics. The creep performance enhancement in cross-rolled MA956 material samples versus the base creep property is elucidated. Additional creep enhancements are derived when flow formed tubes are flattened at 900 C and recrystallized. The Larsen-Miller parameter for the improvised thermo-mechanical processing now approaches 52. At least 2-3 orders of magnitude of improvement in creep rates/day are demonstrated for the cross-rolled samples versus the base reference tests.

Bimal K. Kad

2006-04-10T23:59:59.000Z

195

NETL: News Release - DOE Selects Five NOx-Control Projects to Combat Acid  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

November 5, 2004 November 5, 2004 DOE Selects Five NOx-Control Projects to Combat Acid Rain and Smog Industry Partners to Focus on Reducing Emissions While Cutting Energy Costs PITTSBURGH, PA - Continuing efforts to cut acid rain and smog-producing nitrogen oxides (NOx) have prompted the U.S. Department of Energy to partner with industry experts to develop advanced NOx-control technologies. With the selection of five new NOx-control projects, the Energy Department continues as a leader in developing advanced technologies to achieve environmental compliance for the nation's fleet of coal-fired power plants. Although today's NOx-control workhorses, such as low-NOx burners and selective catalytic reduction (SCR), have been successfully deployed to address existing regulations, proposed regulations will require deeper cuts in NOx emissions, at a greater number of generating facilities. Many of the smaller affected plants will not be able to cost-effectively use today's technologies; these are the focus of the advanced technologies selected in this announcement.

196

Low NOx burner retrofits and enhancements for a 518 MW oil and gas fired boiler  

SciTech Connect (OSTI)

Low NOx oil/gas burners originally supplied to Jacksonville Electric Authority, Northside No. 3 .500 MW unit, were based on a duplex air register design with lobed spray oil atomizers providing additional fuel staging. Although the burners could meet the targeted NOx levels of 0.3 and 0.2 lbs/10{sup 6} BTU on oil and gas respectively. There was insufficient margin on these NOx levels to enable continuous low NOx operation to be achieved. Further burner development was undertaken based on improved aerodynamic control within the burner design to give an approximate 25% improvement in NOx emission reduction thus providing an adequate operating margin. This `RoBTAS` (Round Burner with Tilted Air Supply) burner design based on techniques developed successfully for front wall coal firing applications achieved the required NOx reductions in full scale firing demonstrations on both heavy fuel oil and natural gas firing. The paper describes the development work and the subsequent application of the `RoBTAS` burners to the Northside No. 3 boiler. The burner will also be test fired on Orimulsion fuel and thus the comparison between heavy fuel oil firing and Orimulsion firing under ultra low NOx conditions will be made.

King, J.J. [Jacksonville Electric Authority, FL (United States); Allen, J.W.; Beal, P.R. [International Combustion Ltd., Derby (United Kingdom). Rolls-Royce Industrial Power Group

1995-12-31T23:59:59.000Z

197

Fe-Cr-Mo based ODS alloys via spark plasma sintering: A combinational characterization study by TEM and APT  

SciTech Connect (OSTI)

Nanoscale oxides play an important role in oxide dispersion strengthened (ODS) alloys for improved high temperature creep resistance and enhanced radiation damage tolerance. In this study, transmission electron microscopy (TEM) and atom probe tomography (APT) were combined to investigate two novel Fe-16Cr-3Mo (wt.%) based ODS alloys. Spark plasma sintering (SPS) was used to consolidate the ODS alloys from powders that were milled with 0.5 wt.% Y2O3 powder only or with Y2O3 powder and 1 wt.% Ti. TEM characterization revealed that both alloys have a bimodal structure of nanometer-size (~ 100 500 nm) and micron-size grains with nanostructured oxide precipitates formed along and close to grain boundaries with diameters ranging from five to tens of nanometers. APT provides further quantitative analyses of the oxide precipitates, and also reveals Mo segregation at grain boundaries next to oxide precipitates. The alloys with and without Ti are compared based on their microstructures.

Y. Q. Wu; K. N. Allahar; J. Burns; B. Jacques; I Charit; D. P. Butt; J. I. Cole

2013-08-01T23:59:59.000Z

198

Nitrogen Oxides (NOx), Why and How They are Controlled  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Air Quality EPA 456/F-99-006R Air Quality EPA 456/F-99-006R Environmental Protection Planning and Standards November 1999 Agency Research Triangle Park, NC 27711 Air EPA-456/F-99-006R November 1999 Nitrogen Oxides (NOx), Why and How They Are Controlled Prepared by Clean Air Technology Center (MD-12) Information Transfer and Program Integration Division Office of Air Quality Planning and Standards U.S. Environmental Protection Agency Research Triangle Park, North Carolina 27711 ii DISCLAIMER This report has been reviewed by the Information Transfer and Program Integration Division of the Office of Air Quality Planning and Standards, U.S. Environmental Protection Agency and approved for publication. Approval does not signify that the contents of this report reflect the views and policies of the U.S. Environmental Protection Agency. Mention of trade

199

Low NOx nozzle tip for a pulverized solid fuel furnace  

DOE Patents [OSTI]

A nozzle tip [100] for a pulverized solid fuel pipe nozzle [200] of a pulverized solid fuel-fired furnace includes: a primary air shroud [120] having an inlet [102] and an outlet [104], wherein the inlet [102] receives a fuel flow [230]; and a flow splitter [180] disposed within the primary air shroud [120], wherein the flow splitter disperses particles in the fuel flow [230] to the outlet [104] to provide a fuel flow jet which reduces NOx in the pulverized solid fuel-fired furnace. In alternative embodiments, the flow splitter [180] may be wedge shaped and extend partially or entirely across the outlet [104]. In another alternative embodiment, flow splitter [180] may be moved forward toward the inlet [102] to create a recessed design.

Donais, Richard E; Hellewell, Todd D; Lewis, Robert D; Richards, Galen H; Towle, David P

2014-04-22T23:59:59.000Z

200

METHANE de-NOX FOR UTILITY PC BOILERS  

SciTech Connect (OSTI)

The project seeks to develop and validate a new pulverized coal combustion system to reduce utility PC boiler NOx emissions to 0.15 lb/million Btu or less without post-combustion flue gas cleaning. Work during previous reporting periods completed the design, installation, shakedown and initial PRB coal testing of a 3-million Btu/h pilot system at BBP's Pilot-Scale Combustion Facility (PSCF) in Worcester, MA. Based on these results, modifications to the gas-fired preheat combustor and PC burner were defined, along with a modified testing plan and schedule. During the current reporting period, BBP's subcontract was modified to reflect changes in the pilot testing program, and the modifications to the gas-fired preheat combustor were completed. The Computational Fluid Dynamics (CFD) modeling approach was defined for the combined PC burner and 3-million Btu/h pilot system. Modeling of the modified gas-fired preheat combustor was also started.

Joseph Rabovitser; Bruce Bryan; Serguei Nester; Stan Wohadlo

2002-04-29T23:59:59.000Z

Note: This page contains sample records for the topic "nox ods voc" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

METHANE DE-NOX FOR UTILITY PC BOILERS  

SciTech Connect (OSTI)

The primary focus for the project continues to be on developing a PC PREHEAT system design suitable for use with caking coals and readying the 100 MMBtu/h CBTF for testing with noncaking PRB coal. During the current quarter, twenty-two pilot tests were conducted with Central Appalachian (CA) caking coal. The objective for these tests was to achieve continuous operation of the pilot system at its design coal feed rate of 156 lb/h, without plugging or agglomeration in the combustor. One combustor air distribution method tested achieved continuous operation at 110 lb/hr, and inspection of the combustor afterward indicated that this method has potential to solve the caking problem. The NOx results from the pilot caking coal runs indicate that even greater NOx reduction is possible with CA coal than with the PRB coal tested, to levels near 100 ppmv or lower at 4-6% exit oxygen. It was therefore decided to conduct additional pilot tests of the air distribution method to determine how to incorporate this into a workable CA combustor design. Based on current weather and manpower restrictions at the site, this pilot testing is expected to be started in February. The design for the 100 MMBtu/h unit for PRB testing in the CBTF was completed and fabrication and installation started during the quarter. While significant progress has been made in the installation of the unit, weather and combustor fabrication delays are expected to move the start of large-scale testing with PRB coal into February, which will push the project completion date beyond the current 3/30/04 end date. GTI is in the process of developing a revised project schedule and estimated cost to complete.

Bruce Bryan; Joseph Rabovitser; Serguei Nester; Stan Wohadlo

2004-02-06T23:59:59.000Z

202

METHANE de-NOX for Utility PC Boilers  

SciTech Connect (OSTI)

The primary focus for the project during the quarter was shakedown testing of the large-scale coal preheater prototype in the CBTF with non-caking PRB coal. Additional pilot-scale tests were conducted in the PSCF in support of developing a preheating system design suitable for use with caking coals. Thirty-two additional pilot tests were conducted during the quarter with caking coal. These tests further evaluated the use of the air-bleed and indirect air-cooled liner designs to reduce or eliminate combustor plugging with caking coal. The air-bleed configurations tested used air injection holes perpendicular to the liner's longitudinal axis with the number, size and air flow though the air-bleed holes varied to determine the effect on combustor plugging. The indirect cooling configurations tested included a stainless steel liner with spiral fins in the annular space between the liner and the combustor wall, and a silicon carbide liner without fins. Continuous pilot operation was maintained for up to 30 minutes at a coal feed rate of 50 lb/h with the air-bleed liner. The best result achieved was for the stainless steel indirect air-cooled liner with 20 minutes of continuous operation at 126 lb/h of coal followed by an additional 20 minutes at 150 lb/h. The NOx results from these continue to indicate that even greater NOx reduction is possible with caking coal than with the PRB coal tested. The installation of the large-scale prototype coal preheater for PRB testing in the CBTF was completed and shakedown testing with natural gas and PRB coal started during the quarter. Stable operation of the coal system, combustor and burner were achieved at coal feed rates up to 6000 lb/h (50 MMBtu/h).

Bruce Bryan; Joseph Rabovitser Serguei Nester; Stan Wohadlo

2004-06-30T23:59:59.000Z

203

Influencing factors on NOX emission level during grate conversion of three pelletized energy crops  

Science Journals Connector (OSTI)

Abstract NOX emission behavior of three different pelletized energy crops, a herbaceous one, Brassica carinata, a short rotation coppice, Populus sp., and a blend of them, was assessed during fixed grate conversion. Measurements of NOX emissions were done at combustion conditions that yielded both thermal efficiency and CO emissions according to the European norm (EN 303-5:2012), and results compared to limits established by the Austrian deviations. Based on the experimental data, NOX results fulfilled the Austrian restrictions except during combustion of brassica, which exhibited the highest Fuel-N content. The Fuel-NOX was identified as the main formation mechanism. An opposite relation was determined between the specific NOX emissions and the Fuel-N conversion ratio obtained between the N-rich and the N-lean fuels tested here. The influence of the air supply (amount and distribution) on the NOX formation was also noticeable. In general, a higher proportion of air increased the specific NOX emissions and the Fuel-N conversion ratio. Possibilities to control the NOX emissions level by air staging were rather limited, particularly, during combustion of brassica and the blend because of their peculiarities as ash-rich fuels with high slag formation risk. For attaining an appropriate conversion of these fuels, primary air requirements substantially increased. Due to limitations found during the energy crops conversion, efforts to minimize the level of NOX emissions identified here for the troublesome fuels tested should be mainly focused on attaining both a properly designed air supply system and the grate temperature control as well as on conditioning the Fuel-N content, for instance, by blending.

Maryori Daz-Ramrez; Fernando Sebastin; Javier Royo; Adeline Rezeau

2014-01-01T23:59:59.000Z

204

Exergy analysis of combustion characteristics and NOx emissions of a dual-fuel engine  

Science Journals Connector (OSTI)

The combustion characteristics and NOx emissions of compression ignition engines working on a dual fuel mode are investigated numerically and their exergetic efficiencies are determined. The model has been validated with available experimental results. The simulation results show that dual fuel engine combustion and trend of NOx emissions are well predicted by the present model. Parametric study showed improvements in engine performance and an increase in NOx emissions with decreased advanced injection timing of the pilot fuel as well as with increased intake temperature and pilot fuel quantity. The maximum values for energy and exergy are found to be comparable.

Mohamed H. Morsy; Abdelrahman El-Leathy; Arif Hepbasli

2012-01-01T23:59:59.000Z

205

Dual cure low-VOC coating process. Final technical report, Phase 3  

SciTech Connect (OSTI)

US EPA is implementing increasingly stringent environmental regulations on the emissions of volatile organic compounds (VOCs), which amount to about 7 {times} 10{sup 9} lb/year, largely from paints and other coating systems in industry. Objective of this project is to develop Dual Cure Photocatalyst coating technology for aerospace topcoats (urethane/acrylate), aerospace primers (epoxy/acrylate), and solventless tape backings. Some problems (moisture etc.) were encountered in the primer area. Cost, economic, and energy analyses were conducted. The dual cure technology has already been commercialized in 3M`s flexible diamond resin products. Tabs.

Kinzer, K.E.

1993-12-01T23:59:59.000Z

206

Definition: Reduced Sox, Nox, And Pm-2.5 Emissions | Open Energy  

Open Energy Info (EERE)

Sox, Nox, And Pm-2.5 Emissions Sox, Nox, And Pm-2.5 Emissions Jump to: navigation, search Dictionary.png Reduced Sox, Nox, And Pm-2.5 Emissions Functions that provide this benefit can lead to avoided vehicle miles, decrease the amount of central generation needed to their serve load (through reduced electricity consumption, reduced electricity losses, more optimal generation dispatch), and or reduce peak generation. These impacts translate into a reduction in pollutant emissions produced by fossil-based electricity generators and vehicles.[1] Related Terms electricity generation, reduced electricity losses, smart grid References ↑ SmartGrid.gov 'Description of Benefits' An in LikeLike UnlikeLike You like this.Sign Up to see what your friends like. line Glossary Definition Retrieved from "http://en.openei.org/w/index.php?title=Definition:Reduced_Sox,_Nox,_And_Pm-2.5_Emissions&oldid=502508

207

Demonstration of a Low-NOx Heavy-Duty Natural Gas Engine  

SciTech Connect (OSTI)

Results of a Next Generation Natural Gas Vehicle engine research project: A Caterpillar C-12 natural gas engine with Clean Air Power Dual-Fuel technology and exhaust gas recirculation demonstrated low NOx and PM emissions.

Not Available

2004-02-01T23:59:59.000Z

208

NH3 generation over commercial Three-Way Catalysts and Lean-NOx...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

formulations and operation for the in-situ generation of NH3, storage on a downstream SCR catalyst, and utilized to reduce the remaining NOx deer12toops.pdf More Documents &...

209

NOx Emissions of Alternative Diesel Fuels:? A Comparative Analysis of Biodiesel and FT Diesel  

Science Journals Connector (OSTI)

This study explores the diesel injection and combustion processes in an effort to better understand the differences in NOx emissions between biodiesel, Fischer?Tropsch (FT) diesel, and their blends with a conventional diesel fuel. Emissions studies were ...

James P. Szybist; Stephen R. Kirby; Andr L. Boehman

2005-05-14T23:59:59.000Z

210

Sulphur Removal Characteristics from a Commercial NOx Storage/Reduction Catalyst.  

E-Print Network [OSTI]

??The ability to effectively remove sulphur from sulphur-poisoned NOx storage/reduction (NSR) catalysts, while minimizing associated fuel penalties and thermal degradation, is important for commercial application (more)

Kisinger, Darren

2009-01-01T23:59:59.000Z

211

A design strategy applied to sulfur resistant lean NOx̳ automotive catalysts  

E-Print Network [OSTI]

Catalyst poisoning due to sulfur compounds derived from fuel sulfur presents a major challenge, intractable thus far, to development of many advanced technologies for automotive catalysts such as the lean NOx, trap. Under ...

Tang, Hairong

2005-01-01T23:59:59.000Z

212

Monolithic Metal Oxide based Composite Nanowire Lean NOx Emission Control Catalysts  

Broader source: Energy.gov [DOE]

Presents latest progress in the development of a new type of lean NOx trapping catalyst based on heterogenous composite nanowires, which could potentially be used in gasoline and diesel engines.

213

Time and location differentiated NOX control in competitive electricity markets using cap-and-trade mechanisms  

E-Print Network [OSTI]

Due to variations in weather and atmospheric chemistry, the timing and location of nitrogen oxide (NOX) reductions determine their effectiveness in reducing ground-level ozone, which adversely impacts human health. Electric ...

Martin, Katherine C.

2007-01-01T23:59:59.000Z

214

An experimental study on combustion processes and nox emission characteristics of the air-staged burner  

Science Journals Connector (OSTI)

The combustion processes and emission characteristics in air-staged burner...5H5N) is used to investigate the fuel NOX emission characteristics. Experiments are carried out for a wide range of operating condition...

Kook-Young Ahn; Han-Seok Kim; Eun-Seong Cho; Jin-Hyuk Ahn

1999-06-01T23:59:59.000Z

215

Combining Low-Temperature Combustion with Lean-NOx Trap Yields...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

and Posters 2005deerhuff.pdf More Documents & Publications Intra-catalyst Reductant Chemistry in Lean NOx Traps: A Study on Sulfur Effects Reductant Utilization in a LNT + SCR...

216

Intra-catalyst Reductant Chemistry in Lean NOx Traps: A Study...  

Broader source: Energy.gov (indexed) [DOE]

Intra-catalyst Reductant Chemistry in Lean NOx Traps: A Study on Sulfur Effects Jim Parks (parksjeii@ornl.gov), Matt Swartz, Shean Huff, Brian West Oak Ridge National Laboratory...

217

Assessment of a new fabrication route for Fe-9Cr-1W ODS cladding tubes L. Toualbi1  

E-Print Network [OSTI]

are developed as future cladding materials for Generation IV Sodium-Cooled Fast Reactors. ODS alloys nuclear reactors. These materials have to fulfill specific requirements such as limited deformations , R. Logé10 , Y. de Carlan11 1 Nuclear Materials Department, CEA Saclay, 91191 Gif-sur-Yvette, France

Boyer, Edmond

218

Corrosion property of 9Cr-ODS steel in nitric acid solution for spent nuclear fuel reprocessing  

SciTech Connect (OSTI)

Corrosion tests of oxide dispersion strengthened with 9% Cr (9Cr-ODS) steel, which is one of the desirable materials for cladding tube of sodium-cooled fast reactors, in pure nitric acid solution, spent FBR fuel solution, and its simulated solution were performed to understand the corrosion behavior in a spent nuclear fuel reprocessing. In this study, the 9Cr-ODS steel with lower effective chromium content was evaluated to understand the corrosion behavior conservatively. As results, the tube-type specimens of the 9Cr-ODS steels suffered severe weight loss owing to active dissolution at the beginning of the immersion test in pure nitric acid solution in the range from 1 to 3.5 M. In contrast, the weight loss was decreased and they showed a stable corrosion in the higher nitric acid concentration, the dissolved FBR fuel solution, and its simulated solution by passivation. The corrosion rates of the 9Cr-ODS steel in the dissolved FBR fuel solution and its simulated solution were 1-2 mm/y and showed good agreement with each other. The passivation was caused by the shift of corrosion potential to noble side owing to increase in nitric acid concentration or oxidative ions in the dissolved FBR fuel solution and the simulated spent fuel solution. (authors)

Takeuchi, M.; Koizumi, T. [Japan Atomic Energy Agency, Tokai-mura, Naka-gun, Ibaraki 319-1195 (Japan); Inoue, M.; Koyama, S.I. [Japan Atomic Energy Agency, Oarai-machi, Higashi-ibaraki-gun, Ibaraki 311-1393 (Japan)

2013-07-01T23:59:59.000Z

219

Measuring the Fracture Toughness of TZM and ODS Molybdenum Alloys Using Standard and Sub-Sized Bend Specimens  

SciTech Connect (OSTI)

Oxide Dispersion Strengthened (ODS) and TZM molybdenum have excellent creep resistance and strength at high temperatures in inert atmospheres. Fracture toughness and tensile testing was performed at temperatures between -150 degrees C and 450 degrees C to characterize 6.35 mm thick plate material of ODS and TZM molybdenum. A transition from low fracture toughness values (5.8 to 29.6 MPa square root m) to values greater than 30 MPa square root m is observed for TZM molybdenum in the longitudinal orientation at 100 degrees C and in the transverse orientation at 150 degrees C. These results are consistent with data reported in literature for molybdenum. A transition to low fracture toughness values (less than 30 MPa square root m) was not observed for longitudinal ODS molybdenum at temperatures greater than or equal to -150 degrees C, while a transition to low fracture toughness values (12.6 to 25.4 MPa square root m) was observed for the transverse orientation at room-temperature. The fi ne spacing of La-oxide precipitates that are present in ODS molybdenum result in a transition temperature that is significantly lower than any molybdenum alloy reported to date, with upper bound fracture toughness values that bound the literature data. A comparison of fracture toughness values obtained using a 1T, 0.5T, and 0.25T Charpy shows that a 0.5T Charpy could be used as a sub-sized specimen geometry.

Cockeram, B. V.

2002-12-01T23:59:59.000Z

220

Summer Research Opportunities -2014 Heather Anderson OD, PhD My research interests include objective measurements of  

E-Print Network [OSTI]

Summer Research Opportunities - 2014 Heather Anderson OD, PhD � My research interests include objective measurements of accommodation in children and factors limiting visual quality in individuals, PhD � My research centers on understanding the visual impact of the optical aberrations of the normal

Glasser, Adrian

Note: This page contains sample records for the topic "nox ods voc" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

METHANE de-NOX for Utility PC Boilers  

SciTech Connect (OSTI)

During the current quarter, pilot-scale testing with the modified air nozzle version of the PC burner was completed with PRB coal at the Riley Power Inc. (RPI) test facility. A total of 8 different burner configurations were tested utilizing various burner air nozzle arrangements in place of the burner air channels. It was found that with the arrangements tested, a stable flame could not be maintained at coal feed rates above 100 lb/h. While it is felt that the air nozzle approach can ultimately be used effectively, in the interest of holding to the current project schedule it was decided to proceed with the balance of the project using the air channel design. The pilot-scale PC burner was therefore restored to the air-channel configuration and benchmark testing with PRB coal to confirmed previous operating results. A series of tests was then conducted with PRB and West Virginia caking coal to evaluate modifications to the gas combustor configuration and operation for improved performance with caking coal. Continuous operation was achieved with caking coal up to 50 lb/h vs. the full load target of 150 lb/h. Impingement and deposition of partially devolatilized coal occurred at various points within the combustor when the caking coal feed was increased above 50 lb/h. The 100 MMBtu/h commercial-scale prototype design was continued with coal burner design input from both RPI and VTI. Based on typical burner installation layout considerations, it was decided that the preheat combustor should be oriented horizontally on the axial centerline of the coal burner. Accordingly, the pilot gas combustor was changed to this orientation so that the pilot results with caking coal will be directly applicable to the preferred 100 MMBtu design. Testing with caking coal in the horizontal pilot combustor achieved feed rates up to 126 lb/h, although some deposition and LOI issues remain. Several promising approaches to further improve operation with caking coal were identified. NOx results with caking coal are promising, with NOx as low as 150 ppmv at exit oxygen levels of 4% and higher. The 100 MMBtu/h commercial-scale prototype design is nearing completion. Design of the caking coal version of the unit continues with additional pilot testing in support of this design expected. GTI and RPI are expediting the fabrication of the 100 MMBtu/h PRB unit in order to start testing in early- to mid-December. Inspection and repair of the 100 MMBtu/h Coal Burner Test Facility (CBTF) is nearing completion. As of mid-September, this activity was 95% complete.

Bruce Bryan; Joseph Rabovitser; Serguei Nester; Stan Wohadlo

2003-09-30T23:59:59.000Z

222

Advanced furnace air staging and burner modifications for ultra-low NOx firing systems  

SciTech Connect (OSTI)

Overfire air is an effective means to reduce NOx emissions from coal fired furnaces. The current range of overfire air usage on wall-fired boilers in the US is in the range of 10 to 20%. In most cases this is enough to achieve current Title IV NOx reduction requirements. Future applications are likely to go beyond 20% Overfire Air to reduce NOx further for lower investment and operating costs of SCR retrofits. Summer ozone reduction requires NOx emissions of 0.15 lb/MBtu. Currently, industry is exploring the conditions under which this goal is attainable. The paper discussed the approach to achieve ultra-low NOx emissions by using advanced furnace air staging. It describes the unique approach of redesigning the burner to maintain low NOx burner performance when the overfire air system is added or increased in capacity. The impact on furnace corrosion and unburned carbon losses are presented. A case study is used to show the effects of overfire air both on emissions and unburned carbon.

McCarthy, K.; Laux, S.; Grusha, J.

1999-07-01T23:59:59.000Z

223

VOC recovery using microwave regeneration of adsorbents: Pilot-column studies  

SciTech Connect (OSTI)

A pilot-scale column was constructed to evaluate the technical feasibility of microwave (MW) heating as a means of regenerating adsorbents for recovery of volatile organic compounds (VOCs). The 6 inch diameter moving-bed column, which has a throughput capacity of 200 lb/hr of adsorbent, is representative of a full-scale component of a small-capacity recovery system or a single element of a large-capacity system. Regeneration experiments were conducted to study the effects of key process variables, including adsorbent and stripping gas feed rates, initial adsorbent coverage and microwave power input, on column performance. Two adsorbents with contrasting dielectric loss characteristics were studied, Dowex Optipore L502 (low dielectric loss styrene-based) and Rohm and Haas Ambersorb 600 (moderate dielectric loss carbonaceous). Adsorbates included polar and nonpolar compounds: isopropyl alcohol (iPA), methyl ethyl ketone (MEK) and toluene. Solvent recovery rates of 20--30 lbs/hr were achieved. The results of the pilot-column experiments demonstrate that axial temperature and desorption profiles are dependent on the dielectric characteristics of the adsorbent/sorbate pair, and that final regeneration coverage can be correlated with a dimensionless stripping gas ratio and final adsorbent temperature. Implications for design of microwave-regenerated VOC recovery systems are discussed.

Salinas, M.J.; Price, D.W.; Schmidt, P.S.

1999-07-01T23:59:59.000Z

224

The Perkin-Elmer ATD-400 system for monitoring of ambient VOC ozone precursors  

SciTech Connect (OSTI)

The systems described were used in the Texas Natural Resource Conservation Commission (TNRCC) Coastal Oxidant Assessment for Southeast Texas (COAST) program. Continuous VOC monitoring programs were implemented in June through November of this year in Houston. This Perkin-Elmer developed monitoring system included a dual capillary column chromatographic application in an 8700 GC with a modified ATD-400 sampling system. The resulting separations are monitored and quantified using Turbochrom (ver. 3.2) chromatographic data handling software. The key element to this system is the thermal desorption device which is capable of concentrating VOCs from ambient air then desorbing them directly to the gas chromatograph on a continuous cycle.The ATD-400, unlike other similar devices, contains an activated carbon trap which is electrically cooled during collection via Peltier technology. This eliminates the need for cryogenic liquids or compressed air (vortex) for sample collection and makes unattended field operation more feasible than previous systems. The entire system is integrated to provide a completely automatic sample collection cycle, gas chromatographic analysis and data collection, reduction and report generation. Reliability and repeatability data suggest that the system is robust. Good correlation between systems and quality audits confirms data from the manufacturer. Modifications which are being implemented to the chromatographic system, system sites, and operator behavior to enhance the system performance will also be presented.

Radenheimer, P. [Consolidated Sciences Corp., Pasadena, TX (United States); Gibich, J. [Texas Natural Resource Conservation Commission, Austin, TX (United States); Ogle, L. [Radian Corp., Austin, TX (United States)

1994-12-31T23:59:59.000Z

225

Advanced NOx Emissions Control: Control Technology - Second Generation  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

In Situ Device for Real-Time Catalyst Deactivation Measurements in Full-Scale SCR Systems In Situ Device for Real-Time Catalyst Deactivation Measurements in Full-Scale SCR Systems To support trends in the electric generating industry of moving from seasonal to year-round operation of Selective Catalytic Reduction (SCR) for control of NOx and mercury, as well as extending the time between generating unit outages, Fossil Energy Research Corporation (FERCo) is developing technology to determine SCR catalyst activity and remaining life without requiring an outage to obtain and analyze catalyst samples. FERCo intends to use SCR catalyst performance results measured with their in situ device at Alabama Power’s Plant Gorgas during the 2005 and 2006 ozone seasons, along with EPRI’s CatReactTM catalyst management software, to demonstrate the value of real-time activity measurements with respect to the optimization of catalyst replacement strategy. Southern Company and the Electric Power Research Institute are co-funding the project.

226

Release of Ammonium and Mercury from NOx Controlled Fly Ash  

SciTech Connect (OSTI)

One of the goals of the Department of Energy is to increase the reuse of coal utilization byproducts (CUB) to 50% by 2010. This will require both developing new markets and maintaining traditional ones such as the use of fly ash in concrete. However, the addition of pollution control devices can introduce side-effects that affect the marketability of the CUB. Such can be the case when NOx control is achieved using selective catalytic or non-catalytic reduction (SCR or SNCR). Depending on site-specific details, the ammonia slip can cause elevated levels of NH3 in the fly ash. Disposal of ammoniated fly ash can present environmental concerns related to the amount of ammonia that might be released, the amount of water that might become contaminated, and the extent to which metals might be mobilized by the presence of the ammonia. Ammonia retained in fly ash appears to be present as either an ammonium salt or as a chemisorbed species. Mercury in the leachates correlated to neither the amount of leachable ammonium nor to the total amount of Hg in the ash. The strongest correlation was between the decreases in the amount of Hg leached with increased LOI.

Schroeder, K.T.; Cardone, C.R.; Kim, A.G

2007-07-01T23:59:59.000Z

227

Utilization of computational fluid dynamics technique in low NOx burner/furnace retrofits  

SciTech Connect (OSTI)

A computational fluid dynamics (CFD) technique has been utilized to provide design guidance for retrofitting low NOx combustion systems and incorporating associated furnace modifications into existing utility boilers. The CFD program utilized is FW-FIRES (Fossil fuel, Water-walled Furnace Integrated Reaction and Emission Simulation) which simulates furnace combustion, heat transfer and pollutant formation based on fundamental principals of mass, momentum and energy conservations. The program models the gas flow field as a three-dimensional turbulent reacting continuum and the particle flow as a series of discrete particle trajectories through the gas continuum. Chemical reaction, heat transfer, and pollutant formation mechanisms are incorporated in the program. FW-FIRES furnace simulation of low NOx combustion system retrofits has been performed for various furnace configurations including front wall-fired, front and real wall-fired, and tangentially-fired furnaces, to determine the effects of burner/furnace modifications on the NOx emission, furnace exit gas temperature, furnace heat absorption, unburned carbon, and furnace wall corrosion. For front wall-fired, and front and real wall-fired furnaces, the NOx emission requirement is met by the use of Foster Wheeler lox NOx burners and overfire air (OFA) staging. Studies of burner and OFA quantify and spacing are conducted to limit NOx emission and unburned carbon to acceptable levels. A major concern in once-through supercritical units with OFA is furnace wall corrosion which is caused by high furnace wall metal temperature and corrosive hydrogen sulfide (H{sub 2}S) created in a reducing atmosphere from part of coal sulfur. The FW-FIRES code is used to minimize this corrosion potential by selecting the proper location and quantity of boundary air. A simulation of tangentially-fired unit, which has been retrofitted with low NOx burners, is used to study the effect of the burner tilt on the furnace exit gas temperature. This paper details the basis and results of several CFD analyses conducted for potential retrofit programs.

Cho, S.M.; Seltzer, A.H.; Ma, J.; Steitz, T.H.; Grusha, J.; Cole, R.W.

1999-07-01T23:59:59.000Z

228

Understanding the Distributed Intra-Catalyst Impact of Sulfation on Water Gas Shift in a Lean NOx Trap Catalyst  

Broader source: Energy.gov [DOE]

The Lean NOx Trap catalyst is an aftertreatment technology for abatement of nitrogen-oxide emissions from lean-burn vehicle engines.

229

Pilot-Scale Aftertreatment Using Nonthermal Plasma Reduction of Adsorbed NOx in Marine Diesel-Engine Exhaust Gas  

Science Journals Connector (OSTI)

Regulations governing marine diesel engine NOx emissions have recently become more stringent. As it is difficult to fulfill these requirements by combustion improvements alone, effective aftertreatment technologi...

Takuya Kuwahara; Keiichiro Yoshida

2014-01-01T23:59:59.000Z

230

The effect of impurities on the doping and VOC of CdTe/CdS thin film solar cells  

Science Journals Connector (OSTI)

The effect of introducing impurities in CdTe, namely antimony (Sb) and oxygen (O), on the net carrier concentration in CdS/CdTe solar cells and on their open-circuit voltage (VOC) has been investigated. Oxygen was introduced in the CdTe films during the deposition of this layer by the close-spaced sublimation process. The total pressure was held constant at 1330Pa (N2 and O2). The amount of oxygen was varied by varying its partial pressure. Antimony was introduced into CdTe using a post-deposition diffusion process. Following the deposition of CdTe a thin film (a few nm) of Sb was deposited onto the CdTe surface and subsequently heat-treated to cause in-diffusion of Sb. The temperature and time during the diffusion process were varied in the range of 300525C and 20160min respectively. In both instances it was possible to vary (increase) the doping concentration in CdTe. The increase in doping was accompanied by an increase in VOC. However, in all instances the doping in CdTe reached a maximum value, beyond which further increases were not possible leading to saturation in VOC. The highest VOC measured was similar to state-of-the-art values in the range of 800830mV, and the highest doping concentration measured was in the 1016cm?3 range.

H. Zhao; Alvi Farah; D. Morel; C.S. Ferekides

2009-01-01T23:59:59.000Z

231

VOC identification and inter-comparison from laboratory biomass burning using PTR-MS and PIT-MS  

Science Journals Connector (OSTI)

Volatile organic compounds (VOCs) emitted from fires of biomass commonly found in the southeast and southwest U.S. were investigated with PTR-MS and PIT-MS, which are capable of fast measurements of a large number of VOCs. Both instruments were calibrated with gas standards and mass dependent calibration curves are determined. The sensitivity of the PIT-MS linearly increases with mass, because the ion trap mass spectrometer used in PIT-MS is more efficient for higher masses, whereas the quadrupole in PTR-MS is most efficient around 70amu. The identification of \\{VOCs\\} in the complicated mix of the fire emissions was done by gas chromatographic pre separation and inter-comparison with other instrumentation: GCMS, FTIR, and NI-PT-CIMS. With these state of the art identification methods only 5075% of the mass detectable by PTR-MS or PIT-MS could be identified. The amount of identified material was dependent on the type of fuel used and the phase of the burns, more can be identified in the flaming stage of the fire. Compounds with masses above 100amu contributed the largest fraction of the unidentified mass. Emission ratios with CO for all identified and unidentified compounds were determined. Small oxygenated \\{VOCs\\} had the highest emission ratios of the observed compounds.

C. Warneke; J.M. Roberts; P. Veres; J. Gilman; W.C. Kuster; I. Burling; R. Yokelson; J.A. de Gouw

2011-01-01T23:59:59.000Z

232

METHANE de-NOX for Utility PC Boilers  

SciTech Connect (OSTI)

The overall project objective is the development and validation of an innovative combustion system, based on a novel coal preheating concept prior to combustion, that can reduce NO{sub x} emissions to 0.15 lb/million Btu or less on utility pulverized coal (PC) boilers. This NO{sub x} reduction should be achieved without loss of boiler efficiency or operating stability, and at more than 25% lower levelized cost than state-of-the-art SCR technology. A further objective is to ready technology for full-scale commercial deployment to meet the market demand for NO{sub x} reduction technologies. Over half of the electric power generated in the U.S. is produced by coal combustion, and more than 80% of these units utilize PC combustion technology. Conventional measures for NOx reduction in PC combustion processes rely on combustion and post-combustion modifications. A variety of combustion-based NO{sub x} reduction technologies are in use today, including low-NO{sub x} burners (LNBs), flue gas recirculation (FGR), air staging, and natural gas or other fuel reburning. Selective non-catalytic reduction (SNCR) and selective catalytic reduction (SCR) are post-combustion techniques. NO{sub x} reduction effectiveness from these technologies ranges from 30 to 60% and up to 90-93% for SCR. Typically, older wall-fired PC burner units produce NO{sub x} emissions in the range of 0.8-1.6 lb/million Btu. Low-NO{sub x} burner systems, using combinations of fuel staging within the burner and air staging by introduction of overfire air in the boiler, can reduce NO{sub x} emissions by 50-60%. This approach alone is not sufficient to meet the desired 0.15 lb/million Btu NO{sub x} standard with a range of coals and boiler loads. Furthermore, the heavy reliance on overfire air can lead to increased slagging and corrosion in furnaces, particularly with higher-sulfur coals, when LNBs are operated at sub-stoichiometric conditions to reduce fuel-derived NOx in the flame. Therefore, it is desirable to minimize the need for overfire air by maximizing NO{sub x} reduction in the burner. The proposed combustion concept aims to greatly reduce NO{sub x} emissions by incorporating a novel modification to conventional or low-NO{sub x} PC burners using gas-fired coal preheating to destroy NO{sub x} precursors and prevent NO{sub x} formation. A concentrated PC stream enters the burner, where flue gas from natural gas combustion is used to heat the PC up to about 1500 F prior to coal combustion. Secondary fuel consumption for preheating is estimated to be 3 to 5% of the boiler heat input. This thermal pretreatment releases coal volatiles, including fuel-bound nitrogen compounds into oxygen-deficient atmosphere, which converts the coal-derived nitrogen compounds to molecular N{sub 2} rather than NO. Design, installation, shakedown, and testing on Powder River Basin (PRB) coal at a 3-million Btu/h pilot system at RPI's (Riley Power, Inc.) pilot-scale combustion facility (PSCF) in Worcester, MA demonstrated that the PC PREHEAT process has a significant effect on final O{sub x} formation in the coal burner. Modifications to both the pilot system gas-fired combustor and the PC burner led to NO{sub x} reduction with PRB coal to levels below 0.15 lb/million Btu with CO in the range of 35-112 ppmv without any furnace air staging.

Bruce Bryan; Serguei Nester; Joseph Rabovitser; Stan Wohadlo

2005-09-30T23:59:59.000Z

233

NOx Control Options and Integration for US Coal Fired Boilers  

SciTech Connect (OSTI)

This is the sixteenth Quarterly Technical Report for DOE Cooperative Agreement No: DEFC26-00NT40753. The goal of the project is to develop cost effective analysis tools and techniques for demonstrating and evaluating low NOx control strategies and their possible impact on boiler performance for boilers firing US coals. The Electric Power Research Institute (EPRI) is providing co-funding for this program. During an unplanned outage, damage occurred to the electrochemical noise corrosion probes installed at the AEP Gavin plant; testing is expected to resume in August. The KEMCOP corrosion coupons were not affected by the unplanned outage; the coupons were removed and sent for analysis. BYU conducted a series of tests before the ISSR lab was relocated. Ammonia adsorption experiments provided clear evidence of the types of acidic sites present on catalyst surfaces. Data collected this quarter indicate that surface sulfation decreases Lewis acid site concentrations for all catalysts thus far studied, confirming that catalytic activity under commercial coal-based SCR conditions occurs primarily on Br{o}nsted acid sites and would be susceptible to basic impurities such as alkali and alkaline earth oxides, chlorides, and sulfates. SCR activity tests based on MS analysis showed that increasing sulfation generally increases NO reduction activity for both 0% and 1% vanadia catalysts. During this quarter, the slipstream reactor at Rockport operated for 720 hours on flue gas. Catalyst exposure time reached 4500 hours since installation. The reactor is out of service at the Rockport plant and plans are being made to move it to the Gadsden Plant. At Gadsden, modifications have begun in preparation for installation of the slipstream reactor next quarter.

Mike Bockelie; Kevin Davis; Temi Linjewile; Connie Senior; Eric Eddings; Kevin Whitty; Larry Baxter; Calvin Bartholomew; William Hecker; Stan Harding

2004-06-30T23:59:59.000Z

234

Turbulent Flame Speeds and NOx Kinetics of HHC Fuels with Contaminants and High Dilution Levels  

SciTech Connect (OSTI)

This final report documents the technical results of the 3-year project entitled, Turbulent Flame Speeds and NOx Kinetics of HHC Fuels with Contaminants and High Dilution Levels, funded under the NETL of DOE. The research was conducted under six main tasks: 1) program management and planning; 2) turbulent flame speed measurements of syngas mixtures; 3) laminar flame speed measurements with diluents; 4) NOx mechanism validation experiments; 5) fundamental NOx kinetics; and 6) the effect of impurities on NOx kinetics. Experiments were performed using primary constant-volume vessels for laminar and turbulent flame speeds and shock tubes for ignition delay times and species concentrations. In addition to the existing shock- tube and flame speed facilities, a new capability in measuring turbulent flame speeds was developed under this grant. Other highlights include an improved NOx kinetics mechanism; a database on syngas blends for real fuel mixtures with and without impurities; an improved hydrogen sulfide mechanism; an improved ammonia kintics mechanism; laminar flame speed data at high pressures with water addition; and the development of an inexpensive absorption spectroscopy diagnostic for shock-tube measurements of OH time histories. The Project Results for this work can be divided into 13 major sections, which form the basis of this report. These 13 topics are divided into the five areas: 1) laminar flame speeds; 2) Nitrogen Oxide and Ammonia chemical kinetics; 3) syngas impurities chemical kinetics; 4) turbulent flame speeds; and 5) OH absorption measurements for chemical kinetics.

Peterson, Eric; Krejci, Michael; Mathieu, Olivier; Vissotski, Andrew; Ravi, Sankat; Plichta, Drew; Sikes, Travis; Levacque, Anthony; Camou, Alejandro; Aul, Christopher

2013-09-30T23:59:59.000Z

235

Coal characterisation for \\{NOx\\} prediction in air-staged combustion of pulverised coals  

Science Journals Connector (OSTI)

A series of world-traded coal samples has been tested using the Imperial College high temperature wire mesh apparatus (HTWM) in order to assess the relationship between high temperature (1600C) char nitrogen content and \\{NOx\\} formation in Hemweg Power Station (in the Netherlands) using deep furnace air staging. A linear relationship between high temperature char nitrogen and \\{NOx\\} formation has been confirmed. These results suggest that high temperature char N content is the main factor limiting \\{NOx\\} emissions with deep air-staged combustion. Char N and (hence apparently deep air-staged NOx) can be predicted with an accuracy of approximately 20% for most coals from the coal proximate and ultimate analysisbut this might not be sufficient for stations operating close to their emission limits. Measuring high temperature char N directly reduces the likely uncertainty in deep air-staged \\{NOx\\} emissions for coals (and most blends) to approximately 10%. Its use should be considered on a routine basis for coal selection on plants employing this technology.

C.K. Man; J.R. Gibbins; J.G. Witkamp; J. Zhang

2005-01-01T23:59:59.000Z

236

NOIJLVaiSINIWaV NOIlVlAldOdNI AOU3N3 Z661  

Gasoline and Diesel Fuel Update (EIA)

61- 61- NOIJLVaiSINIWaV NOIlVlAldOdNI AOU3N3 Z661 This publication and other Energy Information Administration (EIA) publications may be purchased from the Superintendent of Documents, U.S. Government Printing Office. AH telephone orders should be directed to: U.S. Government Printing Office McPherson Square Bookstore 1510 H Street, N.W. Washington, DC 20005 (202)653-2050 FAX (202)376-5055 9 a.m. to 5 p.m., eastern time, M-F All mail orders should be directed to: Superintendent of Documents U.S. Government Printing Office Washington, DC 20402 (202)783-3238 FAX (202)512-2233 8 a.m. to 5 p.m., eastern time, M-F U.S. Government Printing Office c/o Mellon Bank P.O. Box 371954 Pittsburgh, PA 15250-7954 Complimentary subscriptions and single issues are available to certain groups of subscribers, such

237

NOIlVUlSININdV NOIlVWdOdNI AOd3N3 ACTO3NH  

Gasoline and Diesel Fuel Update (EIA)

NOIlVUlSININdV NOIlVWdOdNI AOd3N3 NOIlVUlSININdV NOIlVWdOdNI AOd3N3 ACTO3NH 0661 This publication may be purchased from the Superintendent of Documents, U.S. Government Printing Office. Purchasing in formation for this or other Energy Information Administration (EIA) publications may be obtained from the Government Printing Office or ElA's National Energy Information Center. Questions on energy statistics should be directed to the Center by mail, telephone, or telecommunications device for the hearing impaired. Addresses, telephone numbers, and hours are as follows: National Energy Information Center Energy Information Administration Forrestal Building, Room 1F-048 Washington, DC 20585 (202) 586-8800 Telecommunications Device for the Hearing Impaired Only: (202) 586-1181 8 a.m. - 5 p.m., eastern time, M-F

238

The 16OH/18OH and OD/OH isotope ratios in comet C/2002 T7 (LINEAR)  

E-Print Network [OSTI]

The 16OH/18OH and OD/OH isotope ratios are measured in the Oort-Cloud comet C/2002 T7 (LINEAR) through ground-based observations of the OH ultraviolet bands at 3063 A (0,0) and 3121 A (1,1) secured with the Very Large Telescope (VLT) feeding the Ultraviolet-Visual Echelle Spectrograph (UVES). From the 16OH/18OH ratio, we find 16O/18O = 425 +/- 55, equal within the uncertainties to the terrestrial value and to the ratio measured in other comets, although marginally smaller. We also estimate OD/OH from which we derive D/H = 2.5 +/- 0.7 10-4 in water. This value is compatible with the water D/H ratios evaluated in other comets and marginally higher than the terrestrial value.

D. Hutsemekers; J. Manfroid; E. Jehin; J. -M. Zucconi; C. Arpigny

2008-09-25T23:59:59.000Z

239

Closed-loop control of a SCR system using a NOx sensor cross-sensitive to NH3  

E-Print Network [OSTI]

Closed-loop control of a SCR system using a NOx sensor cross-sensitive to NH3 A.Bonfils , Y. Creff for an automotive selective catalytic reduction (SCR) system, for which the feedback is based on a NOx sensor the variety of en- countered technologies, selective catalytic reduction (SCR) is one of the most appealing

240

Exhaust gas fuel reforming of Diesel fuel by non-thermal arc discharge for NOx trap regeneration  

E-Print Network [OSTI]

1 Exhaust gas fuel reforming of Diesel fuel by non- thermal arc discharge for NOx trap regeneration to the reforming of Diesel fuel with Diesel engine exhaust gas using a non-thermal plasma torch for NOx trap Diesel fuel reforming with hal-00617141,version1-17May2013 Author manuscript, published in "Energy

Boyer, Edmond

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241

Nitrogen Isotopic Composition of Coal-Fired Power Plant NOx: Influence of Emission Controls and Implications for Global Emission  

E-Print Network [OSTI]

Nitrogen Isotopic Composition of Coal-Fired Power Plant NOx: Influence of Emission Controls and Implications for Global Emission Inventories J. David Felix,*, Emily M. Elliott, and Stephanie L. Shaw contributions, prior documentation of 15 N of various NOx emission sources is exceedingly limited

Elliott, Emily M.

242

NOx Control Options and Integration for US Coal Fired Boilers  

SciTech Connect (OSTI)

This is the fifteenth Quarterly Technical Report for DOE Cooperative Agreement No: DE-FC26-00NT40753. The goal of the project is to develop cost effective analysis tools and techniques for demonstrating and evaluating low NOx control strategies and their possible impact on boiler performance for boilers firing US coals. The Electric Power Research Institute (EPRI) is providing co-funding for this program. At AEP's Gavin Plant, data from the corrosion probes showed that corrosion rate increased as boiler load was increased. During an outage at the plant, the drop in boiler load, sensor temperature and corrosion rate could all be seen clearly. Restarting the boiler saw a resumption of corrosion activity. This behavior is consistent with previous observations made at a 600MWe utility boiler. More data are currently being examined for magnitudes of corrosion rates and changes in boiler operating conditions. Considerable progress was made this quarter in BYU's laboratory study of catalyst deactivation. Surface sulfation appears to partially suppress NO adsorption when the catalyst is not exposed to NH3; NH3 displaces surface-adsorbed NO on SCR catalysts and surface sulfation increases the amount of adsorbed NH3, as confirmed by both spectroscopy and TPD experiments. However, there is no indication of changes in catalyst activity despite changes in the amount of adsorbed NH3. A monolith test reactor (MTR), completed this quarter, provided the first comparative data for one of the fresh and field-exposed monolith SCR catalysts yet developed in this project. Measurements of activity on one of the field-exposed commercial monolith catalysts do not show significant changes in catalyst activity (within experimental error) as compared to the fresh catalyst. The exposed surface of the sample contains large amounts of Ca and Na, neither of which is present in the fresh sample, even after removal of visibly obvious fouling deposits. However, these fouling compounds do not deactivate the catalyst to the extent that these same poisons do in the deliberately wet-impregnated laboratory-prepared samples (1%V{sub 2}O{sub 5}-9%WO{sub 3}/TiO{sub 2}). At least in this case, the fouling deposits generated by field exposure present little if any chemical deactivation or barrier to mass transfer. During this quarter, the slipstream reactor at Rockport operated for 1000 hours on flue gas. Periodic NO{sub x} reduction measurements were made, showing some decrease in activity relative to fresh catalyst samples. Plans are being made to take the reactor out of service at the Rockport plant and move it to Plant Gadsden. At Gadsden, inlet and outlet ports were installed on Unit 1 for the slipstream reactor during an outage.

Mike Bockelie; Kevin Davis; Temi Linjewile; Connie Senior; Eric Eddings; Kevin Whitty; Larry Baxter; Calvin Bartholomew; William Hecker; Stan Harding

2004-03-31T23:59:59.000Z

243

Influence of Atmospheric Pressure and Water Table Fluctuations on Gas Phase Flow and Transport of Volatile Organic Compounds (VOCs) in Unsaturated Zones  

E-Print Network [OSTI]

in previous studies. This dissertation systematically investigates their influence on the gas phase flow and transport of VOCs in soil and ground water remediation processes using analytically and numerically mathematical modeling. New semi...

You, Kehua

2013-04-19T23:59:59.000Z

244

Influence of combustion parameters on NOx production in an industrial boiler  

E-Print Network [OSTI]

Influence of combustion parameters on NOx production in an industrial boiler M.A. Habib a,*, M pollution using a model furnace of an industrial boiler utilizing fuel gas. The importance of this problem is mainly due to its relation to the pollutants produced by large boiler furnaces used widely in thermal

Aldajani, Mansour A.

245

REAL-WORLD EFFICACY OF HEAVY DUTY DIESEL TRUCK NOX AND PM EMISSIONS CONTROLS  

E-Print Network [OSTI]

are International. b DOC = Diesel Oxidation Catalyst; DPF = Diesel Particulate Filter; EGR = Exhaust GasREAL-WORLD EFFICACY OF HEAVY DUTY DIESEL TRUCK NOX AND PM EMISSIONS CONTROLS Gurdas Sandhu H 26-28, 2012 #12;2 Objectives 1. Quantify inter-run variability in exhaust emission rates 2. Assess

Frey, H. Christopher

246

Consequences of propene and propane on plasma remediation of NOx Rajesh Doraia)  

E-Print Network [OSTI]

. INTRODUCTION Plasma remediation of exhaust from internal combustion engines, and diesel engines in particular of achieving high E/N electric field/ gas number density are promising in this regard.11 Actual diesel exhaust discharge DBD reactors are being investigated for plasma remediation of NOx from the exhaust of internal

Kushner, Mark

247

tive emissions from EVs (e.g., power plant NOx) and GPVs (tailpipe and  

E-Print Network [OSTI]

a few sluggish electric vehicles would cause enough traffic slowing that the gasoline- powered fleet Analy- sis article on battery-powered vehicles (Sept. 1996, p. 402A) serves as a useful remindertive emissions from EVs (e.g., power plant NOx) and GPVs (tailpipe and associated NO.,. emissions

Denver, University of

248

Observation of NOx enhancement and ozone depletion in the Northern and Southern  

E-Print Network [OSTI]

Clarmann, G. P. Stiller, M. Ho¨pfner, S. Kellmann, and H. Fischer Institut fu¨r Meteorologie und Clarmann, G. P. Stiller, M. Ho¨pfner, S. Kellmann, H. Fischer, and C. H. Jackman (2005), Observation of NOx

Jackman, Charles H.

249

Atmospheric Environment 38 (2004) 27792787 First detection of nitrogen from NOx in tree rings: a 15  

E-Print Network [OSTI]

abies; Air pollution; Dendroecology; Nitrogen deposition; Stable isotopes; Nitrogen dioxide 1Atmospheric Environment 38 (2004) 2779­2787 First detection of nitrogen from NOx in tree rings 2004; accepted 27 February 2004 Abstract Nitrogen isotope analysis (d15 N) of tree rings is potentially

250

Transport of NOx in East Asia identified by satellite and in situ measurements  

E-Print Network [OSTI]

Research Laboratory, Boulder, Colorado, USA, 3 Cooperative Institute for Research in Environmental Sciences, University of Colorado Boulder, Boulder, Colorado, USA, 4 School of Earth and Environmental Sciences, Seoul burning, and natural phenomena like lightning, wildfires, and soil microbial activity. NOx play

Park, Rokjin

251

NOx reduction with the use of feedlot biomass as a reburn fuel  

E-Print Network [OSTI]

. Additional air called overfire air (about 20 % of total air) is injected in order to complete combustion. Typically reburn fuel is natural gas (NG). From previous research at TAMU, it was found that firing feedlot biomass (FB) as reburn fuel lowers the NOx...

Goughnour, Paul Gordon

2009-05-15T23:59:59.000Z

252

Treatment of \\{VOCs\\} with molecular sieve catalysts in regenerative catalytic oxidizer  

Science Journals Connector (OSTI)

This work prepares molecular sieve catalysts with various metal species and various metal weight loadings by impregnation, and then screens them in a catalytic combustion system. The current study further investigates the molecular sieve catalyst in an RCO system after it performed well in combustion efficiency. This work tests its performances in terms of CO2 yield, pressure drop, the difference between temperatures of the inlet and outlet gases (Td), and thermal recovery efficiency (TRE), with various operational conditions. Experimental results demonstrate that the 10wt% Cu/(MS) catalyst was the most active because it has the greatest combustion efficiency to treat volatile organic compounds (VOCs) than Co/(MS) catalysts and Mn/(MS) catalysts. The 10wt% Cu/(MS) catalyst used in an RCO system reaches over 95% CO2 yields under the heating zone temperature (Tset)=400C, gas velocity (Ug)=0.37m/s, isopropyl alcohol (IPA) concentration=200400ppm conditions. Moreover, the RCO system performed well in economic efficiency with the RCO with in terms of TRE, Td and pressure drop. The TRE ranged from 90.4% to 94.6% and Td ranged from 14.0 to 34.2C under various conditions at Tset=300450C. Finally, the results of the stability test demonstrated that the catalyst was very stable at various Ug values and various Tset values.

Shih-Wei Huang; Jie-Chung Lou; Yung-Chang Lin

2010-01-01T23:59:59.000Z

253

Latest developments and application of DB Riley's low NOx CCV{reg{underscore}sign} burner technology  

SciTech Connect (OSTI)

Recent developments in DB Riley (DBR) low NOx burner technology and the application of this technology in coal fired utility boilers are discussed. Since the promulgation of the Clean Air Act Amendment in 1990, DBR has sold nearly 1,500 Controlled Combustion Venturi (CCV{reg{underscore}sign}) burners on pulverized coal fired utility boilers reducing NOx emissions 50--70% from uncontrolled levels. This technology has been retrofitted on boiler designs ranging in size and type from 50 MW front wall fired boilers to 1,300 MW opposed fired cell type boilers. In DBR's latest version of the CCV{reg{underscore}sign} burner, a second controlled flow air zone was added to enhance NOx control capability. Other developments included improved burner air flow measurement accuracy and several mechanical design upgrades such as new coal spreader designs for 3 year wear life. Test results of the CCV{reg{underscore}sign} dual air zone burner in DBR's 100 million Btu/hr (29 MW) coal burner test facility are presented. In the test program, coals from four utility boiler sites were fired to provide a range of coal properties. A baseline high volatile bituminous coal was also fired to provide a comparison with 1992 test data for the CCV{reg{underscore}sign} single register burner. The tests results showed that the second air zone enhanced NOx reduction capability by an additional 20% over the single register design. Computational fluid dynamic (DFD) modeling results of the CCV{reg{underscore}sign} dual air zone burner are also presented showing near field mixing patterns conducive to low NOx firing. DBR was recently awarded Phase IV of the Low Emission Boiler System (LEBS) program by the US Department of Energy to build a proof of concept facility representing the next major advancement in pulverized coal burning technology. A key part of winning that award were test results of the CCV{reg{underscore}sign} dual air zone burner with advanced air staging and coal reburning in a 100 million Btu/hr (20 MW) U-fired slagging combustor test facility. These results showed NOx emissions of less than 0.2 lb/million Btu (0.086 g/MJ) while converting the coal ash into an inert, non-leachable solid. This results is an 80% reduction in NOx emissions from currently operating U-fired slagging boilers.

Penterson, C.; Ake, T.

1998-07-01T23:59:59.000Z

254

Post-Irradiation Fracture Toughness of Unalloyed Molybdenum, ODS molybdenum, and TZM molybdenum following irradiation at 244C to 507C  

SciTech Connect (OSTI)

Commercially available unalloyed molybdenum (Low Carbon Arc Cast (LCAC)), Oxide Dispersion Strengthened (ODS) molybdenum, and TZM molybdenum were neutron irradiated at temperatures of nominally 244 C, 407 C, and 509 C to neutron fluences between 1.0 to 4.6x1025 n/m2 (E>0.1 MeV). Post-irradiation fracture toughness testing was performed. All alloys exhibited a Ductile to Brittle Transition Temperature that was defined to occur at 30 4 MPa-m1/2. The highest post-irradiated fracture toughness values (26-107 MPa-m1/2) and lowest DBTT (100-150 C) was observed for ODS molybdenum in the L-T orientation. The finer grain size for ODS molybdenum results in fine laminates that improve the ductile laminate toughening. The results for ODS molybdenum are anisotropic with lower post-irradiated toughness values (20-30 MPa-m1/2) and higher DBTT (450-600 C) in the T-L orientation. The results for T-L ODS molybdenum are consistent or slightly better than those for LCAC molybdenum (21-71 MPa-m1/2 and 450-800 C DBTT). The fracture toughness values measured for LCAC and T-L ODS molybdenum at temperatures below the DBTT were determined to be 8-18 MPa-m1/2. Lower non-irradiated fracture toughness values were measured for TZM molybdenum that are attributed to the large carbide precipitates serving as preferential fracture initiation sites. The role of microstructure and grain size on post-irradiated fracture toughness was evaluated by comparing the results for LCAC molybdenum and ODS molybdenum.

Cockeram, Brian V [Bechtel-Bettis, Inc.; Byun, Thak Sang [ORNL; Leonard, Keith J [ORNL; Snead, Lance Lewis [ORNL

2013-01-01T23:59:59.000Z

255

Chemistry of NOx on TiO2 surfaces studied by ambient pressure XPS:  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Chemistry of NOx on TiO2 surfaces studied by ambient pressure XPS: Chemistry of NOx on TiO2 surfaces studied by ambient pressure XPS: products, effect of UV irradiation, water and coadsorbed K+ Title Chemistry of NOx on TiO2 surfaces studied by ambient pressure XPS: products, effect of UV irradiation, water and coadsorbed K+ Publication Type Journal Article Year of Publication 2013 Authors Rosseler, Olivier, Mohamad Sleiman, Nahuel V. Montesinos, Andrey Shavorskiy, Valerie Keller, Nicolas Keller, Marta I. Litter, Hendrik Bluhm, Miquel Salmeron, and Hugo Destaillats Journal J. Phys. Chem. Lett. Volume 4 Start Page 536 Issue 3 Pagination 536-541 Date Published 01/2013 Abstract Self-cleaning surfaces containing TiO2 nanoparticles have been postulated to efficiently remove NOx from the atmosphere. However, UV irradiation of NOx adsorbed on TiO2 also was shown to form harmful gas-phase byproducts such as HONO and N2O that may limit their depolluting potential. Ambient pressure XPS was used to study surface and gas-phase species formed during adsorption of NO2 on TiO2 and subsequent UV irradiation at λ = 365 nm. It is shown here that NO3-, adsorbed on TiO2 as a byproduct of NO2 disproportionation, was quantitatively converted to surface NO2 and other reduced nitrogenated species under UV irradiation in the absence of moisture. When water vapor was present, a faster NO3- conversion occurred, leading to a net loss of surface-bound nitrogenated species. Strongly adsorbed NO3- in the vicinity of coadsorbed K+ cations was stable under UV light, leading to an efficient capture of nitrogenated compounds.

256

SOx-NOx-Rox Box{trademark} flue gas clean-up demonstration. Final report  

SciTech Connect (OSTI)

Babcock and Wilcox`s (B and W) SOx-NOx-Rox Box{trademark} process effectively removes SOx, NOx and particulate (Rox) from flue gas generated from coal-fired boilers in a single unit operation, a high temperature baghouse. The SNRB technology utilizes dry sorbent injection upstream of the baghouse for removal of SOx and ammonia injection upstream of a zeolitic selective catalytic reduction (SCR) catalyst incorporated in the baghouse to reduce NOx emissions. Because the SOx and NOx removal processes require operation at elevated gas temperatures (800--900 F) for high removal efficiency, high-temperature fabric filter bags are used in the baghouse. The SNRB technology evolved from the bench and laboratory pilot scale to be successfully demonstrated at the 5-MWe field scale. This report represents the completion of Milestone M14 as specified in the Work Plan. B and W tested the SNRB pollution control system at a 5-MWe demonstration facility at Ohio Edison`s R.E. Burger Plant located near Shadyside, Ohio. The design and operation were influenced by the results from laboratory pilot testing at B and W`s Alliance Research Center. The intent was to demonstrate the commercial feasibility of the SNRB process. The SNRB facility treated a 30,000 ACFM flue gas slipstream from Boiler No. 8. Operation of the facility began in May 1992 and was completed in May 1993. About 2,300 hours of high-temperature operation were achieved. The main emissions control performance goals of: greater than 70% SO{sub 2} removal using a calcium-based sorbent; greater than 90% NOx removal with minimal ammonia slip; and particulate emissions in compliance with the New Source Performance Standards (NSPS) of 0.03 lb/million Btu were exceeded simultaneously in the demonstration program when the facility was operated at optimal conditions. Testing also showed significant reductions in emissions of some hazardous air pollutants.

NONE

1995-09-01T23:59:59.000Z

257

Combustion and \\{NOx\\} emissions of biomass-derived syngas under various gasification conditions utilizing oxygen-enriched-air and steam  

Science Journals Connector (OSTI)

The purpose of this study is to investigate the \\{NOx\\} emissions from combustion of syngas derived from gasification of three different biomass feedstock (i.e., pine, mapleoak mixture, and seed corn) at different oxygen-enriched-air and steam conditions. Three different oxygen-enriched-air and steam conditions were tested for each feedstock, thus resulting in nine different sets of syngas. The biomass-derived syngas was burned in an industrial burner that was integrated into the gasification system. The gasifier and burner are rated at 800kW and 879kW thermal, respectively. For each set of biomass-derived syngas, \\{NOx\\} emissions were measured at different burner operating conditions including various heat rates and equivalence ratios using emission analyzers with chemiluminescence technology. All the combustion test conditions are in the lean mixture ranges in order to avoid the peak temperature limitation of both the burner and combustion chamber. Results show that \\{NOx\\} emissions using syngas obtained from woody feedstock decrease almost linearly as the combustion mixture becomes leaner and the heat rate decreases. When compared to natural gas, syngas from both woody feedstock generates higher \\{NOx\\} emissions even when the heat rates are comparable, indicating that fuel \\{NOx\\} formation is highly important in biomass-derived syngas combustion. In contrast to syngas from woody feedstock, syngas from seed corn results in peak \\{NOx\\} emissions before \\{NOx\\} decreases with leaner conditions. The trend is observed for all fuel flow rates and all oxygen-enriched-air and steam conditions of seed corn-derived syngas. Among the three feedstock, seed corn has the highest nitrogen content which yields the highest ammonia concentration in syngas, which, in turn, results in the highest \\{NOx\\} emissions for all test conditions. Overall, the \\{NOx\\} emissions from seed corn-derived syngas combustion are approximately in the range of 450900ppm higher compared to those from wood-derived syngas combustion.

Cuong Van Huynh; Song-Charng Kong

2013-01-01T23:59:59.000Z

258

On the Promoting Effect of Water during NOx Removal over Single-Site Copper in Hydrophobic Silica APD-Aerogels  

Science Journals Connector (OSTI)

Reversibility of the Cu2+/Cu+ redox pair was confirmed in the Cu-aerogel during and after wet redox cycling. ... (1) Popular solutions to selective catalytic reduction of NOx include the use of exhaust hydrocarbon residuals (SCR-HC-deNOx) or ammonia added to the exhaust (SCR-NH3-deNOx) as the reductant; the former technology being suitable for light duty passenger vehicles, whereas the latter is applied to medium or heavy duty vehicles. ... During vehicle use, the converter is exposed to heat, which causes the metal particles to agglomerate and grow, and their overall surface area to decrease. ...

Tina Kristiansen; Karina Mathisen

2014-01-10T23:59:59.000Z

259

Global Emissions of Terpenoid VOCs from Terrestrial Vegetation in the Last Millennium  

SciTech Connect (OSTI)

We investigated the millennial variability of global BVOC emissions by using two independent numerical models: The Model of Emissions of Gases and Aerosols from Nature (MEGAN), for isoprene, monoterpene and sesquiterpene and Lund-Potsdam-Jena General Ecosystem Simulator (LPJ8 GUESS), for isoprene and monoterpenes. We found the millennial trends of global isoprene emissions to be mostly affected by land cover and atmospheric carbon dioxide changes, whereas monoterpene and sesquiterpene emission were dominated by temperature change. Isoprene emissions declined substantially in regions with large and rapid land cover change. In addition, isoprene emission sensitivity to drought proved to have signicant short term global effects. By the end of the past millennium MEGAN isoprene emissions were 634 TgC yr-1 (13% and 19% less than during during 1750-1850 and 1000- 15 1200, respectively) and LPJ-GUESS emissions were 323 TgC yr-1 (15% and 20% less than during 1750-1850 and 1000-1200, respectively). Monoterpene emissions were 89 TgC yr-1 (10% and 6% higher than during 1750-1850 and 1000-1200, respectively) in MEGAN, and 24 TgC yr-1 (2% higher and 5% 19 20 less than during 1750-1850 and 1000-1200, respectively) in LPJ-GUESS. MEGAN sesquiterpene emissions were 36 TgC yr-1 (10% and 4% higher than during1750-1850 and 1000-1200, respectively). Although both models capture similar We investigated the millennial variability of global BVOC emissions by using two independent numerical models: The Model of Emissions of Gases and Aerosols from Nature (MEGAN), for isoprene, monoterpene and sesquiterpene and Lund-Potsdam-Jena General Ecosystem Simulator (LPJ8GUESS), for isoprene and monoterpenes. We found the millennial trends ofglobal isoprene emissions to be mostly a*ected by land cover and atmospheric carbon dioxide changes, whereas monoterpene and sesquiterpene emission were dominated by temperature change. Isoprene emissions declined substantially in regions with large and rapid land cover change. In addition, isoprene emission sensitivity to drought proved to have signifcant short term global effects. By the end of the past millennium MEGAN isoprene emissions were 634 TgC yr-1 (13% and 19% less than during during 1750-1850 and 1000- 1200, respectively) and LPJ-GUESS emissions were 323 TgC yr-1 (15% and 16 17 20% less than during 1750-1850 and 1000-1200, respectively). Monoterpene emissions were 89 TgC yr-1 (10% and 6% higher than during 1750-1850 and 18 1000-1200, respectively) in MEGAN, and 24 TgC yr-1 (2% higher and 5% less than during 1750-1850 and 1000-1200, respectively) in LPJ-GUESS. MEGAN sesquiterpene emissions were 36 TgC yr-1 (10% and 4% higher than during1750-1850 and 1000-1200, respectively). Although both models capture similar emission trends, the magnitude of the emissions are different. This highlights the importance of building better constraints on VOC emissions from terrestrial vegetation.emission trends, the magnitude of the emissions are different. This highlights the importance of building better constraints on VOC emissions from terrestrial vegetation.

Acosta Navarro, J. C.; Smolander, S.; Struthers, H.; Zorita, E.; Ekman, A. M.; Kaplan, J. O.; Guenther, Alex B.; Arneth, A.; Riipinen, I.

2014-06-16T23:59:59.000Z

260

A Fundamental Consideration on NOx Adsorber Technology for DI Diesel Application  

SciTech Connect (OSTI)

Diesel engines are far more efficient than gasoline engines of comparable size, and emit less greenhouse gases that have been implicated in global warming. In 2000, the US EPA proposed very stringent emissions standards to be introduced in 2007 along with low sulfur (< 15 ppm) diesel fuel. The California Air Resource Board (CARB) has also established the principle that future diesel fueled vehicles should meet the same low emissions standards as gasoline fueled vehicles and the EPA followed suit with its Tier II emissions regulation. Achieving such low emissions cannot be done through engine development and fuel reformulation alone, and requires application of NOx and particulate matter (PM) aftertreatment control devices. There is a widespread consensus that NOx adsorbers and particulate filter are required in order for diesel engines to meet the 2007 emissions regulations for NOx and PM. In this paper, the key exhaust characteristics from an advanced diesel engine are reviewed. Development of the NOx adsorber technology is discussed. Spectroscopic techniques are applied to understand the underlying chemical reactions over the catalyst surface during NOx trapping and regeneration periods. In-situ surface probes are useful in providing not only thermodynamic and kinetics information required for model development but also a fundamental understanding of storage capacity and degradation mechanisms. The distribution of various nitration/sulfation species is related to surface basicity. Surface displacement reactions of carbonates also play roles in affecting the trapping capability of NOx adsorbers. When ultralow-S fuel is used as a reductant during the regeneration, sulfur induced performance degradation is still observed in an aged catalyst. Other possible sources related to catalyst deactivation include incomplete reduction of surface nitration, coke formation derived from incomplete hydrocarbon burning, and lubricant formulations. Sulfur management and the direction of future work for the successful implementation of such integrated engine and aftertreatment technology are discussed. SAE Paper SAE-2002-01-2889 {copyright} 2002 SAE International. This paper is published on this website with permission from SAE International. As a user of this website, you are permitted to view this paper on-line, download this pdf file and print one copy of this paper at no cost for your use only. The downloaded pdf file and printout of this SAE paper may not be copied, distributed or forwarded to others or for the use of others.

Fang, Howard L.; Huang, Shyan C.; Yu, Robert C. (Cummins, Inc.); Wan, C. Z. (Engelhard Corp.); Howden, Ken (U.S. Dept. of Energy)

2002-10-01T23:59:59.000Z

Note: This page contains sample records for the topic "nox ods voc" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

HYDROGEN GENERATION FROM PLASMATRON REFORMERS: A PROMISING TECHNOLOGY FOR NOX ADSORBER REGENERATION AND OTHER AUTOMOTIVE APPLICATIONS  

SciTech Connect (OSTI)

Plasmatron reformers are being developed at MIT and ArvinMeritor [1]. In these reformers a special low power electrical discharge is used to promote partial oxidation conversion of hydrocarbon fuels into hydrogen and CO. The partial oxidation reaction of this very fuel rich mixture is difficult to initiate. The plasmatron provides continuous enhanced volume initiation. To minimize electrode erosion and electrical power requirements, a low current, high voltage discharge with wide area electrodes is used. The reformers operate at or slightly above atmospheric pressure. Plasmatron reformers provide the advantages of rapid startup and transient response; efficient conversion of the fuel to hydrogen rich gas; compact size; relaxation or elimination of reformer catalyst requirements; and capability to process difficult to reform fuels, such as diesel and bio-oils. These advantages facilitate use of onboard hydrogen-generation technology for diesel exhaust after-treatment. Plasma-enhanced reformer technology can provide substantial conversion even without the use of a catalyst. Recent progress includes a substantial decrease in electrical power consumption (to about 200 W), increased flow rate (above 1 g/s of diesel fuel corresponding to approximately 40 kW of chemical energy), soot suppression and improvements in other operational features.. Plasmatron reformer technology has been evaluated for regeneration of NOx adsorber after-treatment systems. At ArvinMeritor tests were performed on a dual-leg NOx adsorber system using a Cummins 8.3L diesel engine both in a test cell and on a vehicle. A NOx adsorber system was tested using the plasmatron reformer as a regenerator and without the reformer i.e., with straight diesel fuel based regeneration as the baseline case. The plasmatron reformer was shown to improve NOx regeneration significantly compared to the baseline diesel case. The net result of these initial tests was a significant decrease in fuel penalty, roughly 50% at moderate adsorber temperatures. This fuel penalty improvement is accompanied by a dramatic drop in slipped hydrocarbon emissions, which decreased by 90% or more. Significant advantages are demonstrated across a wide range of engine conditions and temperatures. The study also indicated the potential to regenerate NOx adsorbers at low temperatures where diesel fuel based regeneration is not effective, such as those typical of idle conditions. Two vehicles, a bus and a light duty truck, have been equipped for plasmatron reformer NOx adsorber regeneration tests.

Bromberg, L.; Crane, S; Rabinovich, A.; Kong, Y; Cohn, D; Heywood, J; Alexeev, N.; Samokhin, A.

2003-08-24T23:59:59.000Z

262

Helical order and multiferroicity in the S=12 quasi-kagome system KCu3As2O7(OD)3  

Science Journals Connector (OSTI)

Several Cu2+ hydroxide minerals have been recently identified as candidate realizations of the S=1/2 kagome Heisenberg model. In this context, we have studied the distorted system KCu3As2O7(OD)3 using neutron scattering and bulk measurements. Although the distortion favors magnetic order over a spin liquid ground state, refinement of the magnetic diffraction pattern below TN1=7.05(5) K yields a complex helical structure with k=(0.77,0,0.11). This structure, as well as the spin excitation spectrum, are well described by a classical Heisenberg model with ferromagnetic nearest neighbor couplings. Multiferroicity is observed below TN1, with an unusual crossover between improper and pseudoproper behavior occurring at TN2=5.5 K. The polarization at T=2 K is P=1.5?Cm?2. The properties of KCu3As2O7(OD)3 highlight the variety of physics which arise from the interplay of spin and orbital degrees of freedom in Cu2+ kagome systems.

G. J. Nilsen; Y. Okamoto; H. Ishikawa; V. Simonet; C. V. Colin; A. Cano; L. C. Chapon; T. Hansen; H. Mutka; Z. Hiroi

2014-04-28T23:59:59.000Z

263

Irradiation hardening in unalloyed and ODS molybdenum during low dose neutron irradiation at 300 and 600?C  

SciTech Connect (OSTI)

Unalloyed molybdenum and oxide dispersion strengthened (ODS) molybdenum were irradiated at 300 C and 600 C in HFIR to neutron fluences of 0.2, 2.1, and 24.3 x 10{sup 24} n/m{sup 2} (E > 0.1 MeV). The size and number density of voids and loops as well as the measured irradiation hardening and electrical resistivity were found to increase sub-linearly with fluence. This supports the idea that the formation of the extended defects that produce irradiation hardening in molybdenum is the result of a nucleation and growth process rather than the formation of sessile defects directly from the displacement damage cascades. This conclusion is further supported by molecular dynamics (MD) simulations of cascade damage. The unalloyed molybdenum had a low impurity interstitial content with less irradiation hardening and lower change in electrical resistivity than is observed for ODS Mo. This result suggests that high-purity can result in slightly improved resistance to irradiation embrittlement in molybdenum at low fluences.

Snead, Lance Lewis [ORNL; Byun, Thak Sang [ORNL; Leonard, Keith J [ORNL; Smith, Richard W [Bechtel-Bettis, Inc.; Cockeram, Brian V [Bechtel-Bettis, Inc.

2008-01-01T23:59:59.000Z

264

An Analysis of the health impacts from PM and NOx emissions resulting from train operations in the Alameda Corridor, CA  

E-Print Network [OSTI]

2009). Estimating PM and NOx Train Emissions in the AlamedaAuthority. Number of Trains Running on the Alameda Corridor.x emissions resulting from train operations in the Alameda

Sangkapichai, Mana; Saphores, Jean-Daniel M; Ogunseitan, Oladele; Ritchie, Stephen G.; You, Soyoung Iris; Lee, Gunwoo

2010-01-01T23:59:59.000Z

265

Heavy-duty diesel vehicle Nox? aftertreatment in 2010 : the infrastructure and compliance challenges of urea-SCR  

E-Print Network [OSTI]

Increasingly stringent heavy-duty vehicle emission regulations are prompting the use of PM and NOx aftertreatment systems in the US, the EU and Japan. In the US, the EPA Highway Diesel Rule, which will be fully implemented ...

Bodek, Kristian M

2008-01-01T23:59:59.000Z

266

Cold-Start Emissions Control in Hybrid Vehicles Equipped with a Passive Adsorber for Hydrocarbons and NOx  

Broader source: Energy.gov [DOE]

Reports results from study of potential for using chemisorbing materials to temporally trap HC and NOx emissions during cold-start of HEVs and PHEVs over transient driving cycles

267

NOx Emissions Reductions from Implementation of the 2000 IECC/IRC Conservation Code to Residential Construction in Texas  

E-Print Network [OSTI]

.1000 0.1500 0.2000 0.2500 0.3000 0.3500 0.4000 0.0000 0.0500 0.1000 0.1500 0.2000 0.2500 0.3000 0.3500 0.4000 To ns - NOx/day (average) Tons - NOX/day (p eak) Apx 2x difference 1:1 2...

Haberl, J. S.; Im, P.; Culp, C.; Yazdani, B.; Fitzpatrick, T.

2004-01-01T23:59:59.000Z

268

Application of Taguchi's orthogonal array in reducing the NOx emission of a stationary diesel engine  

Science Journals Connector (OSTI)

The main objective of this investigation is to reduce the NOx emission of a stationary diesel engine with less sacrifice on smoke intensity and brake thermal efficiency (BTE). Fuel injection timing, percentage of EGR and fuel injection pressure are chosen as factors influencing the objective. Three levels were chosen in each factor and design of experiments method was employed to design the experiments. Taguchi's L9 orthogonal array was used to conduct the engine tests with different levels of the chosen factors. Test results were analysed by analysis of variance (ANOVA) method and ANOVA table was formed for each response variable. From the ANOVA table the most influencing factor and also the significance of each factor affecting the NOx emission, smoke intensity and BTE was found out. Response graph was drawn for each response variable to determine the optimum combination of the factor levels. This optimum combination was confirmed experimentally. [Received: November 14, 2010; Accepted: March 17, 2011

S. Saravanan; G. Nagarajan; R. Ramanujam; S. Sampath

2011-01-01T23:59:59.000Z

269

NOIIVUISINII/UQV NOIlVIAIdOdNI AOH3N3 SNOLL33fOHcI AlHHXHVnO  

Gasoline and Diesel Fuel Update (EIA)

NOIIVUISINII/UQV NOIlVIAIdOdNI AOH3N3 NOIIVUISINII/UQV NOIlVIAIdOdNI AOH3N3 SNOLL33fOHcI AlHHXHVnO xoonno AOHHNH T €661 This publication and other Energy Information Administration (EIA) publications may be purchased from the Superintendent of Documents, U.S. Government Printing Office. All telephone orders should be directed to: U.S. Government Printing Office Superintendent of Documents McPherson Square Bookstore U.S. Government Printing Office 1510 H Street, N.W. Washington, DC 20402

270

A decoupled approach for NOxN2O 3-D CFD modeling in CFB plants  

Science Journals Connector (OSTI)

Abstract In this study, a 3D CFD model for the formation of \\{NOx\\} and N2O in a lignite fired 1.2MWth CFB pilot plant is developed. The decoupled approach (decoupled from combustion simulation) is tested for the minimization of computational cost. As combustion simulation is prerequired, this was achieved through a simplified 3-D CFD combustion model. The developed model is then applied to the pilot-scale 1.2MWth CFB plant and validated against experimental data. As concerns the NOxN2O model, an extensive literature review is also carried out for the incorporation of the appropriate reactions network and respective reaction rates expressions. Results show that homogenous reactions are favoured on the lower section of the bed, due to the abundance of fuel devolatilization products. On the other hand, on the upper section, heterogeneous reactions govern nitric oxide formation/reduction. It is found that for the lignite examined in this work, HCN is released in negligible amounts during char combustion. The proposed and validated CFD model for \\{NOx\\} and N2O, is capable of examining the effect of different operational parameters and coal properties on the overall nitric oxides emissions from a CFB combustor, with low computational cost and without the additional expenses for pilot-scale experiments.

A. Nikolopoulos; I. Malgarinos; N. Nikolopoulos; P. Grammelis; S. Karrelas; E. Kakaras

2014-01-01T23:59:59.000Z

271

Ammonia Generation over TWC for Passive SCR NOX Control for Lean Gasoline Engines  

SciTech Connect (OSTI)

A commercial three-way catalyst (TWC) was evaluated for ammonia (NH3) generation on a 2.0-liter BMW lean burn gasoline direct injection engine as a component in a passive ammonia selective catalytic reduction (SCR) system. The passive NH3 SCR system is a potential low cost approach for controlling nitrogen oxides (NOX) emissions from lean burn gasoline engines. In this system, NH3 is generated over a close-coupled TWC during periodic slightly rich engine operation and subsequently stored on an underfloor SCR catalyst. Upon switching to lean, NOX passes through the TWC and is reduced by the stored NH3 on the SCR catalyst. NH3 generation was evaluated at different air-fuel equivalence ratios at multiple engine speed and load conditions. Near complete conversion of NOX to NH3 was achieved at =0.96 for nearly all conditions studied. At the =0.96 condition, HC emissions were relatively minimal, but CO emissions were significant. Operation at AFRs richer than =0.96 did not provide more NH3 yield and led to higher HC and CO emissions. Results of the reductant conversion and consumption processes were used to calculate a representative fuel consumption of the engine operating with an ideal passive SCR system. The results show a 1-7% fuel economy benefit at various steady-state engine speed and load points relative to a stoichiometric engine operation.

Prikhodko, Vitaly Y [ORNL] [ORNL; Parks, II, James E [ORNL; Pihl, Josh A [ORNL] [ORNL; Toops, Todd J [ORNL] [ORNL

2014-01-01T23:59:59.000Z

272

Modeling Species Inhibition of NO oxidation in Urea-SCR Catalysts for Diesel Engine NOx Control  

SciTech Connect (OSTI)

Urea-selective catalytic reduction (SCR) catalysts are regarded as the leading NOx aftertreatment technology to meet the 2010 NOx emission standards for on-highway vehicles running on heavy-duty diesel engines. However, issues such as low NOx conversion at low temperature conditions still exist due to various factors, including incomplete urea thermolysis, inhibition of SCR reactions by hydrocarbons and H2O. We have observed a noticeable reduction in the standard SCR reaction efficiency at low temperature with increasing water content. We observed a similar effect when hydrocarbons are present in the stream. This effect is absent under fast SCR conditions where NO ~ NO2 in the feed gas. As a first step in understanding the effects of such inhibition on SCR reaction steps, kinetic models that predict the inhibition behavior of H2O and hydrocarbons on NO oxidation are presented in the paper. A one-dimensional SCR model was developed based on conservation of species equations and was coded as a C-language S-function and implemented in Matlab/Simulink environment. NO oxidation and NO2 dissociation kinetics were defined as a function of the respective adsorbates storage in the SCR catalyst. The corresponding kinetic models were then validated on temperature ramp tests that showed good match with the test data.

Devarakonda, Maruthi N.; Tonkyn, Russell G.; Tran, Diana N.; Lee, Jong H.; Herling, Darrell R.

2010-09-15T23:59:59.000Z

273

Modeling Species Inhibition of NO Oxidation in Urea-SCR Catalysts for Diesel Engine NOx Control  

SciTech Connect (OSTI)

Urea-selective catalytic reduction (SCR) catalysts are regarded as the leading NOx aftertreatment technology to meet the 2010 NOx emission standards for on-highway vehicles running on heavy-duty diesel engines. However, issues such as low NOx conversion at low temperature conditions still exist due to various factors, including incomplete urea thermolysis, inhibition of SCR reactions by hydrocarbons and H2O. We have observed a noticeable reduction in the standard SCR reaction efficiency at low temperature with increasing water content. We observed a similar effect when hydrocarbons are present in the stream. This effect is absent under fast SCR conditions where NO ~ NO2 in the feed gas. As a first step in understanding the effects of such inhibition on SCR reaction steps, kinetic models that predict the inhibition behavior of H2O and hydrocarbons on NO oxidation are presented in the paper. A one-dimensional SCR model was developed based on conservation of species equations and was coded as a C-language S-function and implemented in Matlab/Simulink environment. NO oxidation and NO2 dissociation kinetics were defined as a function of the respective adsorbates storage in the Fe-zeolite SCR catalyst. The corresponding kinetic models were then validated on temperature ramp tests that showed good match with the test data. Such inhibition models will improve the accuracy of model based control design for integrated DPF-SCR aftertreatment systems.

Devarakonda, Maruthi N.; Tonkyn, Russell G.; Tran, Diana N.; Lee, Jong H.; Herling, Darrell R.

2011-04-20T23:59:59.000Z

274

BPA BUYER LISTING August 2013 For the "NIH Purchase Card List", visit http://www.nih.gov/icd/od/foia/ and scroll to "Frequently Requested Records"  

E-Print Network [OSTI]

BPA BUYER LISTING August 2013 For the "NIH Purchase Card List", visit http://www.nih.gov/icd/od/foia/ and scroll to "Frequently Requested Records" Name BPA Call Approval Threshold FSS BPA Call Approval Threshold ENNIS, COLLEEN E 500000 25000 NCI #12;BPA BUYER LISTING August 2013 For the "NIH Purchase Card List

Rau, Don C.

275

\\{NOx\\} emission characteristics of fluidized bed combustion in atmospheres rich in oxygen and water vapor for high-nitrogen fuel  

Science Journals Connector (OSTI)

Abstract The present study examines the influence of water vapor in combustion atmosphere on \\{NOx\\} emission from oxygen-enriched combustion of air-dried distilled spirit lees and its char in a laboratory fluidized bed of 760mm high and 68mm in inner diameter. Steam was added into the fluidizing gas to vary the vapor content in the combustion atmosphere. At a combustion temperature of 950C and a steam-to-fuel mass ratio (S/F) of 0.5, the presence of water vapor reduced the \\{NOx\\} concentration in the flue gas for low O2 contents (?30vol.%) in the combustion agent but increased the \\{NOx\\} emission for high O2 contents (?40vol.%). The possible causes were clarified for this shift from suppression to promotion of fuel-N conversion into \\{NOx\\} with raising O2 concentration in the combustion agent. Varying temperature from 850C to 1150C resulted in a peak conversion of fuel-N to \\{NOx\\} in the temperature range of 9501050C for all the tested O2 concentrations. Increasing the O2 concentration tended to lower the critical temperature corresponding to such a peak fuel-N conversion. Testing results also suggested that the presence of excessive water vapor in the combustion atmosphere would inhibit the release of fuel-N in the devolatilization stage and promote the formation of some reducing gases. In addition to the anticipated diluting effect, the steam addition also shortened the reaction time for homogeneous and heterogeneous \\{NOx\\} reduction by the reducing gases and char. It is postulated that the formation of OH radicals at high O2 content and high temperature could cause the observed increase in the \\{NOx\\} emission.

Chuanqiang Zhu; Shuyuan Liu; Huan Liu; Juan Yang; Xiaoxing Liu; Guangwen Xu

2015-01-01T23:59:59.000Z

276

Development of a control-oriented model to optimise fuel consumption and NOX emissions in a DI Diesel engine  

Science Journals Connector (OSTI)

Abstract This paper describes a predictive NOX and consumption model, which is oriented to control and optimisation of DI Diesel engines. The model applies the Response Surface Methodology following a two-step process: firstly, the relationship between engine inputs (intake charge conditions and injection settings) and some combustion parameters (peak pressure, indicated mean effective pressure and burn angles) is determined; secondly, engine outputs (NOX and consumption) are predicted from the combustion parameters using NOX and mechanical losses models. Splitting the model into two parts allows using either experimental or modelled combustion parameters, thus enhancing the model flexibility. If experimental in-cylinder pressure is used to obtain combustion parameters, the mean error of predicted NOX and consumption are 2% and 6% respectively, with a calculation time of 5.5ms. Using modelled parameters reduces the calculation time to 1.5ms, with a penalty in the accuracy. The model performs well in a multi-objective optimisation, reducing NOX and consumption in different amounts depending on the objective of the optimisation.

S. Molina; C. Guardiola; J. Martn; D. Garca-Sarmiento

2014-01-01T23:59:59.000Z

277

Correcting injection pressure maladjustments to reduce NOX emissions by marine diesel engines  

Science Journals Connector (OSTI)

Emissions from the exhausts of marine diesel engines comprises several different gases including NOX. These are currently regulated at the international level under Regulation 13 of ANNEX VI of MARPOL 73/78, but this regulation only applies to new engines and is based on bench tests, for only a single engine designated the parent engine. Here, the need to take measurements from across their whole range and once in operation on board a vessel is examined. This would not only improve assessment of new equipment against the current regulation, but would also detect defects in the functioning of the engine.

C. Vanesa Durn Grados; Zigor Uriondo; Manuel Clemente; Francisco J. Jimnez Espadafor; Juan Moreno Gutirrez

2009-01-01T23:59:59.000Z

278

Methyl tert-butyl ether (MTBE) is a volatile organic com-pound (VOC) derived from natural gas that is added to gas-  

E-Print Network [OSTI]

Methyl tert-butyl ether (MTBE) is a volatile organic com- pound (VOC) derived from natural gas Water in Urban and Agricultural Areas made from methanol, which is derived primarily from natural gas that is added to gas- oline either seasonally or year round in many parts of the United States to increase

279

Recovery of manganese oxides from spent alkaline and zinccarbon batteries. An application as catalysts for VOCs elimination  

SciTech Connect (OSTI)

Highlights: Manganese oxides were synthesized using spent batteries as raw materials. Spent alkaline and zinccarbon size AA batteries were used. A biohydrometallurgical process was employed to bio-lixiviate batteries. Manganese oxides were active in the oxidation of VOCs (ethanol and heptane). - Abstract: Manganese, in the form of oxide, was recovered from spent alkaline and zinccarbon batteries employing a biohydrometallurgy process, using a pilot plant consisting in: an air-lift bioreactor (containing an acid-reducing medium produced by an Acidithiobacillus thiooxidans bacteria immobilized on elemental sulfur); a leaching reactor (were battery powder is mixed with the acid-reducing medium) and a recovery reactor. Two different manganese oxides were recovered from the leachate liquor: one of them by electrolysis (EMO) and the other by a chemical precipitation with KMnO{sub 4} solution (CMO). The non-leached solid residue was also studied (RMO). The solids were compared with a MnO{sub x} synthesized in our laboratory. The characterization by XRD, FTIR and XPS reveal the presence of Mn{sub 2}O{sub 3} in the EMO and the CMO samples, together with some Mn{sup 4+} cations. In the solid not extracted by acidic leaching (RMO) the main phase detected was Mn{sub 3}O{sub 4}. The catalytic performance of the oxides was studied in the complete oxidation of ethanol and heptane. Complete conversion of ethanol occurs at 200 C, while heptane requires more than 400 C. The CMO has the highest oxide selectivity to CO{sub 2}. The results show that manganese oxides obtained using spent alkaline and zinccarbon batteries as raw materials, have an interesting performance as catalysts for elimination of VOCs.

Gallegos, Mara V., E-mail: plapimu@yahoo.com.ar [Pla.Pi.Mu-Planta Piloto Multipropsito, (CICPBA-UNLP) Cno. Centenario y 505, M.B. Gonnet, Buenos Aires (Argentina); Falco, Lorena R., E-mail: mlfalco@quimica.unlp.edu.ar [Pla.Pi.Mu-Planta Piloto Multipropsito, (CICPBA-UNLP) Cno. Centenario y 505, M.B. Gonnet, Buenos Aires (Argentina); Peluso, Miguel A., E-mail: apelu@quimica.unlp.edu.ar [Centro de Investigacin y Desarrollo en Ciencias Aplicadas, Dr. J. Ronco CINDECA (CONICET CCT La Plata), 47 N257, La Plata, Buenos Aires (Argentina); Sambeth, Jorge E., E-mail: sambeth@quimica.unlp.edu.ar [Centro de Investigacin y Desarrollo en Ciencias Aplicadas, Dr. J. Ronco CINDECA (CONICET CCT La Plata), 47 N257, La Plata, Buenos Aires (Argentina); Thomas, Horacio J. [Pla.Pi.Mu-Planta Piloto Multipropsito, (CICPBA-UNLP) Cno. Centenario y 505, M.B. Gonnet, Buenos Aires (Argentina)

2013-06-15T23:59:59.000Z

280

Method for control of NOx emission from combustors using fuel dilution  

DOE Patents [OSTI]

A method of controlling NOx emission from combustors. The method involves the controlled addition of a diluent such as nitrogen or water vapor, to a base fuel to reduce the flame temperature, thereby reducing NOx production. At the same time, a gas capable of enhancing flame stability and improving low temperature combustion characteristics, such as hydrogen, is added to the fuel mixture. The base fuel can be natural gas for use in industrial and power generation gas turbines and other burners. However, the method described herein is equally applicable to other common fuels such as coal gas, biomass-derived fuels and other common hydrocarbon fuels. The unique combustion characteristics associated with the use of hydrogen, particularly faster flame speed, higher reaction rates, and increased resistance to fluid-mechanical strain, alter the burner combustion characteristics sufficiently to allow operation at the desired lower temperature conditions resulting from diluent addition, without the onset of unstable combustion that can arise at lower combustor operating temperatures.

Schefer, Robert W. (Alamo, CA); Keller, Jay O (Oakland, CA)

2007-01-16T23:59:59.000Z

Note: This page contains sample records for the topic "nox ods voc" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

N-nitrosamine and N-nitramine Formation from NOx Reactions with Amines during Amine-Based CO2  

E-Print Network [OSTI]

Capture for Post-combustion Carbon Sequestration Background! Generation of electricity and heat from power- combustion carbon sequestration, the capture and underground storage of CO2 from the exhaust gases of power formation from NOx reactions with amines during amine-based carbon dioxide capture for postcombustion carbon

Mitch, William A.

282

Nox reduction with CO over supported Pd catalysts under simulated post Euro-IV diesel exhaust conditions  

Science Journals Connector (OSTI)

The catalytic reduction of NOx with CO over Pd/Al2O3 and Pd/TiO2/Al2O3 under simulated post Euro-IV diesel exhaust conditions was studied. The catalytic activities obtained...2 loadings and total amounts of reduc...

Yinghua Li; Dae-Won Lee; Young-Chul Ko

2008-12-01T23:59:59.000Z

283

Implications of Near-Term Coal Power Plant Retirement for SO2 and NOX and Life Cycle GHG Emissions  

Science Journals Connector (OSTI)

Implications of Near-Term Coal Power Plant Retirement for SO2 and NOX and Life Cycle GHG Emissions ... Life cycle GHG emissions were found to decrease by less than 4% in almost all scenarios modeled. ... Resulting changes in fuel use, life cycle greenhouse gas (GHG) emissions, and emissions of sulfur and nitrogen oxides are estimated. ...

Aranya Venkatesh; Paulina Jaramillo; W. Michael Griffin; H. Scott Matthews

2012-08-13T23:59:59.000Z

284

Implications of near-term coal power plant retirement for SO2 and NOX, and life cycle GHG emissions  

E-Print Network [OSTI]

prices of electricity production Plant type Unit Price Nuclear ($/MWh) 16.51 Wind ($/MWh) 201 Hydro Top SO2 100 430 95 440 100 430 Top NOX 105 350 100 380 105 345 Small, inefficient 125 410 125 405 125) Manitoba Hydro Manitoba Hydro Undertaking # 57 http://www.pub.gov.mb.ca/exhibits/mh-83.pdf. (5) Sotkiewicz

Jaramillo, Paulina

285

Global partitioning of NOx sources using satellite observations: Relative roles of fossil fuel combustion, biomass burning and  

E-Print Network [OSTI]

combustion, biomass burning and soil emissions Lyatt Jaegle´ ,a Linda Steinberger,a Randall V. Martinbc anthropogenic emissions, mostly resulting from fossil fuel combustion and biomass burning, are superimposed-CHEM chemical transport model. Top-down NOx sources are partitioned among fuel combustion (fossil fuel

Lyatt Jaeglé

286

Field Demonstration of 0.2 Grams Per Horsepower-Hour (g/bhp-hr) Oxides of Nitrogen (NOx) Natural  

E-Print Network [OSTI]

: · Reducing health and environmental impacts from air pollution, and greenhouse gas emissions related pollution and greenhouse gas emissions beyond applicable standards, and that benefit natural gas ratepayers of nitrogen (NOx) emission standard of 0.20 g/bhp-hr for heavy duty engines to reduce levels of this critical

287

\\{NOx\\} reduction from a large bore natural gas engine via reformed natural gas prechamber fueling optimization  

Science Journals Connector (OSTI)

Lean combustion is a standard approach used to reduce \\{NOx\\} emissions in large bore (3556cm) stationary natural gas engines. However, at lean operating points, combustion instabilities and misfires give rise to high total hydrocarbon (THC) and carbon monoxide (CO) emissions. To counteract this effect, precombustion chamber (PCC) technology is employed to allow engine operation at an overall lean equivalence ratio while mitigating the rise of THC and CO caused by combustion instability and misfires. A PCC is a small chamber, typically 12% of the clearance volume. A separate fuel line supplies gaseous fuel to the PCC and a standard spark plug ignites the slightly rich mixture (equivalence ratio 1.11.2) in the PCC. The ignited PCC mixture enters the main combustion chamber as a high energy flame jet, igniting the lean mixture in the main chamber. Typically, natural gas fuels both the main chamber and the PCC. In the current research, a mixture of reformed natural gas (syngas) and natural gas fuels the PCC. Syngas is a broad term that refers to a synthetic gaseous fuel. In this case, syngas specifically denotes a mixture of hydrogen, carbon monoxide, nitrogen, and methane generated in a natural gas reformer. Syngas has a faster flame speed and a wider equivalence ratio range of operation than methane. Fueling the PCC with Syngas reduces combustion instabilities and misfires. This extends the overall engine lean limit, enabling further \\{NOx\\} reductions. Research results presented are aimed at quantifying the benefits of syngas PCC fueling. A model is developed to calculate the equivalence ratio in the PCC for different mixtures and flowrates of fuel. An electronic injection valve is used to supply the PCC with syngas. The delivery pressure, injection timing, and flow rate are varied to optimize PCC equivalence ratio. The experimental results show that supplying the PCC with 100% syngas improves combustion stability by 21% compared to natural gas PCC fueling. A comparison at equivalent combustion stability operating points between 100% syngas and natural gas shows an 87% reduction in \\{NOx\\} emissions for 100% syngas PCC fueling compared to natural gas PCC fueling.

Mathew D. Ruter; Daniel B. Olsen; Mark V. Scotto; Mark A. Perna

2012-01-01T23:59:59.000Z

288

Effect of B20 and Low Aromatic Diesel on Transit Bus NOx Emissions Over Driving Cycles with a Range of Kinetic Intensity  

SciTech Connect (OSTI)

Oxides of nitrogen (NOx) emissions for transit buses for up to five different fuels and three standard transit duty cycles were compared to establish whether there is a real-world biodiesel NOx increase for transit bus duty cycles and engine calibrations. Six buses representing the majority of the current national transit fleet and including hybrid and selective catalyst reduction systems were tested on a heavy-duty chassis dynamometer with certification diesel, certification B20 blend, low aromatic (California Air Resources Board) diesel, low aromatic B20 blend, and B100 fuels over the Manhattan, Orange County and UDDS test cycles. Engine emissions certification level had the dominant effect on NOx; kinetic intensity was the secondary driving factor. The biodiesel effect on NOx emissions was not statistically significant for most buses and duty cycles for blends with certification diesel, except for a 2008 model year bus. CARB fuel had many more instances of a statistically significant effect of reducing NOx. SCR systems proved effective at reducing NOx to near the detection limit on all duty cycles and fuels, including B100. While offering a fuel economy benefit, a hybrid system significantly increased NOx emissions over a same year bus with a conventional drivetrain and the same engine.

Lammert, M. P.; McCormick, R. L.; Sindler, P.; Williams, A.

2012-10-01T23:59:59.000Z

289

NOx, SO{sub 3} in the spotlight at NETL's 2006 Environmental Controls conference  

SciTech Connect (OSTI)

As emissions caps drop, technological solutions must become increasingly effective and efficient. Researchers, equipment vendors, and plant operators are exploring alternatives to SCR and SNCR, with a view to reducing the overall costs of NOx reduction. They have also achieved 95% to 99% removal of SO{sub 3}, with no visible plume opacity. These topics were discussed at ECC 2006. The first conference session focussed on selective catalytic reduction (SCR) and selective non-catalytic reduction (SNCR) control of nitrogen oxide emissions; the second session addressed the related issue of reducing stack emissions and flue gas concentrations of sulfur trioxide. The article summarises many papers presented. Summaries and/or full versions of all the papers mentioned, and others, are posted at www.netl.doe.gov/publications/proceedings/06/ecc/index.html. 2 figs.

Mann, A.N.; Makovsky, L.E.; Sarkus, T.A. [Technology and Management Services Inc. (United States)

2007-02-15T23:59:59.000Z

290

Method for reducing NOx during combustion of coal in a burner  

DOE Patents [OSTI]

An organically complexed nanocatalyst composition is applied to or mixed with coal prior to or upon introducing the coal into a coal burner in order to catalyze the removal of coal nitrogen from the coal and its conversion into nitrogen gas prior to combustion of the coal. This process leads to reduced NOx production during coal combustion. The nanocatalyst compositions include a nanoparticle catalyst that is made using a dispersing agent that can bond with the catalyst atoms. The dispersing agent forms stable, dispersed, nano-sized catalyst particles. The catalyst composition can be formed as a stable suspension to facilitate storage, transportation and application of the catalyst nanoparticles to a coal material. The catalyst composition can be applied before or after pulverizing the coal material or it may be injected directly into the coal burner together with pulverized coal.

Zhou, Bing (Cranbury, NJ); Parasher, Sukesh (Lawrenceville, NJ); Hare, Jeffrey J. (Provo, UT); Harding, N. Stanley (North Salt Lake, UT); Black, Stephanie E. (Sandy, UT); Johnson, Kenneth R. (Highland, UT)

2008-04-15T23:59:59.000Z

291

Exhaust Gas Fuel Reforming of Diesel Fuel by Nonthermal Arc Discharge for NOx Trap Regeneration Application  

Science Journals Connector (OSTI)

Exhaust Gas Fuel Reforming of Diesel Fuel by Nonthermal Arc Discharge for NOx Trap Regeneration Application ... It has been demonstrated that low current arc discharges are highly nonhomogenous. ... In the second case, which corresponds to the most favorable one, assuming (i) a 100 kW car engine thermal power (i.e., 40 kW mechanical power), (ii) that the plasma will treat only a small fraction of the exhaust gas (typically 3.5%), (iii) that the plasma will operate under a cycling operating mode, and (iv) an 80% efficiency for the onboard production of electricity from the car engine, one can estimate that the electric power needed to run the plasma will be around 2.2% of the engine power only during 12 s every 11 km (6.8 miles), that is, 12 s every 6 min assuming a 110 kmh?1 (68 mph) average car velocity. ...

Alexandre Lebouvier; Franc?ois Fresnet; Fre?de?ric Fabry; Vale?rie Boch; Vandad Rohani; Franc?ois Cauneau; Laurent Fulcheri

2011-02-03T23:59:59.000Z

292

Work plan for support to Upper East Fork Poplar Creek east end VOC plumes well installation project at the Oak Ridge Y-12 Plant, Oak Ridge, Tennessee  

SciTech Connect (OSTI)

Under the Resource Conservation and Recovery Act of 1976 guidelines and requirements from the Tennessee Department of Environment and Conservation (TDEC), the Y-12 Plant initiated investigation and monitoring of various sites within its boundaries in the mid-1980s. The entire Oak Ridge Reservation (ORR) was placed on the National Priorities List of the Comprehensive Environmental Response, Compensation, and Liability Act of 1980 (CERCLA) sites in November 1989. Following CERCLA guidelines, sites within the ORR require a remedial investigation (RI) to define the nature and extent of contamination, evaluate the risks to public health and the environment, and determine the goals for a feasibility study (FS) or an engineering evaluation/cost analysis (EE/CA) of potential remedial actions. Data from monitoring wells at the east end of the Y-12 Plant have identified an area of groundwater contamination dominated by the volatile organic compound (VOC) carbon tetrachloride; other VOCs include chloroform, tetrachloroethene, and trichloroethene.

NONE

1998-03-01T23:59:59.000Z

293

Global data set of biogenic VOC emissions calculated by the MEGAN model over the last 30 years  

SciTech Connect (OSTI)

The Model of Emissions of Gases and Aerosols from Nature (MEGANv2.1) together with the Modern-Era Retrospective Analysis for Research and Applications (MERRA) meteorological fields were used to create a global emission dataset of biogenic VOCs available on a monthly basis for the time period of 1980 - 2010. This dataset is called MEGAN-MACC. The model estimated mean annual total BVOC emission of 760 Tg(C) yr1 consisting of isoprene (70%), monoterpenes (11%), methanol (6%), acetone (3%), sesquiterpenes (2.5%) and other BVOC species each contributing less than 2 %. Several sensitivity model runs were performed to study the impact of different model input and model settings on isoprene estimates and resulted in differences of * 17% of the reference isoprene total. A greater impact was observed for sensitivity run applying parameterization of soil moisture deficit that led to a 50% reduction of isoprene emissions on a global scale, most significantly in specific regions of Africa, South America and Australia. MEGAN-MACC estimates are comparable to results of previous studies. More detailed comparison with other isoprene in ventories indicated significant spatial and temporal differences between the datasets especially for Australia, Southeast Asia and South America. MEGAN-MACC estimates of isoprene and*-pinene showed a reasonable agreement with surface flux measurements in the Amazon andthe model was able to capture the seasonal variation of emissions in this region.

Sindelarova, K.; Granier, Claire; Bouarar, I.; Guenther, Alex B.; Tilmes, S.; Stavrakou, T.; Muller, J. F.; Kuhn, U.; Stefani, P.; Knorr, W.

2014-09-09T23:59:59.000Z

294

Air filters from HVAC systems as possible source of volatile organic compounds (VOC) laboratory and field assays  

Science Journals Connector (OSTI)

The emission of volatile organic compounds (VOC) from air filters of HVAC systems was to be evaluated. In a first study carbonyl compounds (14 aldehydes and two ketones) were measured by reacting them with 2,4-dinitrophenylhydrazine (DNPH). Analysis was done by HPLC and UV detection. In laboratory experiments pieces of used and unused HVAC filters were incubated in test chambers. Filters to be investigated were taken from a filter bank of a large HVAC system in the centre of Berlin. First results show that among those compounds formaldehyde and acetone were found in higher concentrations in the test chambers filled with used filters in comparison to those with unused filters. Parallel field measurements were carried out at the prefilter and main filter banks of the two HVAC systems. Here measurements were carried out simultaneously before and after the filters to investigate whether those aldehydes or ketones arise from the filter material on site. Formaldehyde and acetone significantly increased in concentration after the filters of one HVAC system. In parallel experiments microorganisms were proved to be able to survive on air filters. Therefore, a possible source of formaldehyde and acetone might be microbes.

Hans Schleibinger; Henning Rden

1999-01-01T23:59:59.000Z

295

Shifting primary energy source and NOx emission location with plug-in hybrid vehicles  

Science Journals Connector (OSTI)

Plug-in hybrid vehicles (PHEVs) present an interesting technological opportunity for using non-fossil primary energy in light duty passenger vehicles, with the associated potential for reducing air pollutant and greenhouse gas emissions, to the extent that the electric power grid is fed by non-fossil sources. This perspective, accompanying the article by Thompson et al (2011) in this issue, will touch on two other studies that are directly related: the Argonne study (Elgowainy et al 2010) and a PhD thesis from Utrecht (van Vliet 2010). Thompson et al (2011) have examined air quality effects in a case where the grid is predominantly fossil fed. They estimate a reduction of 7.42 tons/day of NOx from motor vehicles as a result of substituting electric VMTs for 20% of the light duty gasoline vehicle miles traveled. To estimate the impact of this reduction on air quality they also consider the increases in NOx emissions due to the increased load on electricity generating units. The NOx emission increases are estimated as 4.0, 5.5 and 6.3 tons for the Convenience, Battery and Night charging scenarios respectively. The net reductions are thus in the 1.13.4 tons/day range. The air quality modelling results presented show that the air quality impact from a ground-level ozone perspective is favorable overall, and while the effect is stronger in some localities, the difference between the three scenarios is small. This is quite significant and suggests that localization of the NOx emissions to point sources has a more pronounced effect than the absolute reductions achieved. Furthermore it demonstrates that localization of NOx emissions to electricity generating units by using PHEVs in vehicle traffic has beneficial effects for air quality not only by minimizing direct human exposure to motor vehicle emissions, but also due to reduced exposure to secondary pollutants (i.e. ozone). In an electric power grid with a smaller share of fossil fired generating units, the beneficial effects would be more pronounced. In such a case, it would also be possible to realize reductions in greenhouse gas emissions. The significance of the electric power generation mix for plug-in hybrid vehicles and battery electric vehicles is a key aspect of Argonne National Laboratories' well-to-wheel study which focuses on petroleum use and greenhouse gas emissions (Elgowainy et al 2010). The study evaluates possible reductions in petroleum use and GHG emissions in the electric power systems in four major regions of the United States as well as the US average generation mix, using Argonne's GREET life-cycle analysis model. Two PHEV designs are investigated through a Powertrain System Analysis Toolkit (PSAT) model: the power-split configuration (e.g. the current Toyota Prius model with Hymotion conversion), and a future series configuration where the engine powers a generator, which charges a battery that is used by the electric motor to propel the vehicle. Since the petroleum share is small in the electricity generation mix for most regions in the United States, it is possible to achieve significant reductions in petroleum use by PHEVs. However, GHG reduction is another story. In one of the cases in the study, PHEVs in the charge depleting mode and recharging from a mix with a large share of coal generation (e.g., Illinois marginal mix) produce GHG emissions comparable to those of baseline gasoline internal combustion engine vehicles (with a range from ?15% to +10%) but significantly higher than those of gasoline hybrid electric vehicles (with a range from +20% to +60%). In what is called the unconstrained charging scenario where investments in new generation capacity with high efficiency and low carbon intensity are envisaged, it becomes possible to achieve significant reductions in both petroleum use and GHG emissions. In a PhD dissertation at Utrecht University, van Vliet (2010) presents a comprehensive analysis of alternatives to gasoline and diesel by looking at various fuel and vehicle technologies. Three chapters are of particular interest from the

Deniz Karman

2011-01-01T23:59:59.000Z

296

An Experimental Investigation of the Origin of Increased NOx Emissions When Fueling a Heavy-Duty Compression-Ignition Engine with Soy Biodiesel  

Broader source: Energy.gov [DOE]

Optical engine experiments suggest that near stoichiometric charge-gas mixtures in the standing premixed autoignition zone near flame lift-off length explains biodiesel NOx increase under all conditions

297

Pillared smectite modified with carbon and manganese as catalyst for SCR of NOx with NH3. Part I. General characterization and catalyst screening  

Science Journals Connector (OSTI)

Carbon- and manganese-modified zirconia-pillared smectites were prepared, characterized (XRD, BET and pore analysis, XPS) and tested in selective catalytic reduction of NOx with NH3. Both untreated and acidic pre...

Lucjan Chmielarz; Roman Dziembaj; Teresa Grzybek; Jerzy Klinik

298

In-situ Fracture Studies and Modeling of the Toughening Mechanism Present in Wrought LCAC, TZM, and ODS Molybdenum Flat Products  

SciTech Connect (OSTI)

In-situ testing, ultrasonic C-scans, and metallography were used to show that a crack-divider delamination form of thin-sheet toughening occurs in wrought Low Carbon Arc Cast (LCAC) unalloyed molybdenum, Oxide Dispersion Strengthened (ODS) molybdenum, and TZM molybdenum at temperatures {ge} the Ductile to Brittle Transition Temperature (DBTT). Cracking along boundaries relieves mechanical constraint to free ligaments that may plastically stretch to produce toughening. Anisotropy in fracture toughness with lower values in the short-transverse direction is shown to produce the crack divider delaminations at the crack tip in the LT and TL orientations. The delamination zone increases with increasing stress-intensity to sizes significantly larger than the plastic zone, which leads to large increases in fracture toughness by the thin sheet toughening mechanism. Fracture in ODS Mo-alloys proceeds mainly along grain boundaries to produce small ligaments that exhibit ductility for both LT and TL orientations resulting in a lower DBTT and higher toughness values at lower temperatures than observed in LCAC and TZM. A combination of grain boundary fracture and cleavage is prevalent in LCAC molybdenum and TZM. The predominance for microcracking along grain boundaries to leave fine, ductile ligaments in ODS molybdenum can be attributed to a fine-grained microstructure with {approx} 1-2 {micro}m thickness of sheet-like grains. The presence of mixed grain boundary fracture and cleavage in LCAC and TZM can be attributed to a microstructure with a larger thickness of sheet-like grains (4-15 {micro}m).

Cockerman, B. V. and Chan, K. S.

2007-07-01T23:59:59.000Z

299

Development of a dry low-NOx gas turbine combustor for a natural-gas fueled 2MW co-generation system  

SciTech Connect (OSTI)

A dry low-NOx gas turbine combustor has been developed for natural-gas fueled co-generation systems in the power range of 1--4MW. The combustor. called the Double Swirler Combustor, uses the lean premixed combustion to reduce NOx emission. The combustor is characterized by two staged lean premixed combustion with two coaxial annular burners and a simple fuel control system without the complex variable geometry. Substantially low NOx level has been achieved to meet the strict NOx regulation to co-generation systems in Japan. High combustion efficiency has been obtained for a wide operating range. In 1994, Tokyo Gas and Ishikawajima-Harima Heavy Industries initiated a collaborative program to develop a natural-gas fueled low NOx gas turbine engine for new 2MW class co-generation system, named IM270. The Double Swirler Combustor, originally developed by Tokyo Gas, was introduced into the natural gas fueled version of the IM270. Engine test of the first production unit was successfully conducted to confirm substantially low NOx level of less than 15 ppm (O{sub 2} = 16%) with the output power of more than 2MW. Test for the durability and the reliability of the system is being conducted at Tokyo Gas Negishi LNG Terminal in Kanagawa, Japan and successful results have been so far obtained.

Mori, Masaaki; Sato, Hiroshi

1998-07-01T23:59:59.000Z

300

Experimental investigation of the thermal and diluent effects of EGR components on combustion and \\{NOx\\} emissions of a turbocharged natural gas SI engine  

Science Journals Connector (OSTI)

Abstract Exhaust gas recirculation (EGR) is one of effective measures used in natural gas (NG) engines to reduce nitrogen oxides (NOx) emissions. Each component of EGR gases can exert different effects on NG combustion and \\{NOx\\} formation rates, such as thermal effect, diluent effect, and chemical effect. In this study, the thermal and diluent effects of the main components of EGR gases, including carbon dioxide (CO2) and nitrogen (N2), were experimentally investigated. The experiments were arranged based on an electronically controlled heavy-duty natural gas spark-ignition (SI) engine with multi-point injection and 6-cylinder. In order to define the diluent effect of EGR components, argon (Ar) was introduced to the test, for its low and unchangeable specific heat capacity under different temperatures. The results showed that the contribution of the diluent effect on \\{NOx\\} reductions was 5060% and 4153% for N2 and CO2 respectively, and the relevant contribution of the thermal effect was 4050% and 4759% respectively. CO2 had greater effects on NG combustion and \\{NOx\\} formation rates than N2 at the same dilution ratio. Increasing Ar improved the thermal efficiency due to the higher specific heat ratio provided. Meanwhile, \\{NOx\\} emissions were found to be decreased with increasing DR as a result of the diluent effect of Ar on combustion and \\{NOx\\} formations.

Weifeng Li; Zhongchang Liu; Zhongshu Wang; Yun Xu

2014-01-01T23:59:59.000Z

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301

Evaluation of the Impacts of Biodiesel and Second Generation Biofuels on NOx Emissions for CARB Diesel Fuels  

Science Journals Connector (OSTI)

McCormick, R. L.; Graboski, M. S.; Alleman, T. L.; Herring, A. M.; Tyson, K. S.Impact of Biodiesel Source Material and Chemical Structure on Emissions of Criteria Pollutants from a Heavy-Duty Engine Environ. ... McCormick, Robert L.; Graboski, Michael S.; Alleman, Teresa L.; Herring, Andrew M.; Tyson, K. Shaine ... McCormick, R.; Alvarez, J.; Graboski, M.; Tyson, K.Fuel Additive and Blending Approaches to Reducing NOx Emissions from Biodiesel SAE Tech. ...

Maryam Hajbabaei; Kent C. Johnson; Robert A. Okamoto; Alexander Mitchell; Marcie Pullman; Thomas D. Durbin

2012-07-12T23:59:59.000Z

302

NOx, FINE PARTICLE AND TOXIC METAL EMISSIONS FROM THE COMBUSTION OF SEWAGE SLUDGE/COAL MIXTURES: A SYSTEMATIC ASSESSMENT  

SciTech Connect (OSTI)

This research project focuses on pollutants from the combustion of mixtures of dried municipal sewage sludge (MSS) and coal. The objective is to determine the relationship between (1) fraction sludge in the sludge/coal mixture, and (2) combustion conditions on (a) NOx concentrations in the exhaust, (b) the size segregated fine and ultra-fine particle composition in the exhaust, and (c) the partitioning of toxic metals between vapor and condenses phases, within the process. The proposed study will be conducted in concert with an existing ongoing research on toxic metal partitioning mechanisms for very well characterized pulverized coals alone. Both high NOx and low NOx combustion conditions will be investigated (unstaged and staged combustion). Tradeoffs between CO{sub 2} control, NO{sub x} control, and inorganic fine particle and toxic metal emissions will be determined. Previous research results have demonstrated that the inhalation of coal/MSS ash particles cause an increase in lung permeability than coal ash particles alone. Elemental analysis of the coal/MSS ash particles showed that Zn was more abundant in these ash particles than the ash particles of coal ash alone.

Jost O.L. Wendt

2003-01-31T23:59:59.000Z

303

NOx diesel exhaust treatment using a pulsed corona discharge: the pulse repetition rate effect  

Science Journals Connector (OSTI)

The pulsed corona offers real promise for degradation of pollutants in gas and water streams. This paper presents a study of NOx removal from diesel exhaust. Special emphasis is laid on the investigation of the dependence of the NO removal rate and efficiency on the pulse repetition rate (PRR). A nanosecond solid state power supply (45?kV, 60?ns, up to 1?kHz) was used for driving the corona reactor. A Mitsubishi 10?kW 3-cylinder diesel-generator engine with a total volume of 1300?cm3 was used as a source of exhaust gas. At an NO removal rate of 35% the NO removal efficiency was 53?g?kW?1h?1 for PRR = 500?Hz and the initial NO concentration was 375?ppm. A semi-empirical expression for the corona reactor removal efficiency related both to PRR and to the residence time is presented. The removal efficiency decreases with increasing PRR at constant flow rate or constant residence time. This expression demonstrates reasonable agreement between the calculation results and the experimental data.

Y Yankelevich; M Wolf; R Baksht; A Pokryvailo; J Vinogradov; B Rivin; E Sher

2007-01-01T23:59:59.000Z

304

Low NOx Burner Design and Analysis for Conceptual Design of Oxygen-Based PC Boiler  

SciTech Connect (OSTI)

The objective of the low NOx burner design and analysis task of the Conceptual Design of Oxygen-Based PC Boiler study is to optimize the burner design to ensure stable ignition, to provide safe operation, and to minimize pollutant formation. The burners were designed and analyzed using the Fluent computer program. Four burner designs were developed: (1) with no over-fire gas (OFG) and 65% flue gas recycle, (2) with 20% OFG and 65% flue gas recycle, (3) with no OFG and 56% flue gas recycle and (4) with 20% OFG and 56% flue gas recycle. A 3-D Fluent simulation was made of a single wall-fired burner and horizontal portion of the furnace from the wall to the center. Without primary gas swirl, coal burnout was relatively small, due to the low oxygen content of the primary gas stream. Consequently, the burners were modified to include primary gas swirl to bring the coal particles in contact with the secondary gas. An optimal primary gas swirl was chosen to achieve sufficient burnout.

Andrew Seltzer

2005-05-01T23:59:59.000Z

305

Development of Irradiation hardening of Unalloyed and ODS molybdenum during neurtron irradiation to low doses at 300C and 600C  

SciTech Connect (OSTI)

Unalloyed molybdenum and Oxide Dispersion Strengthened (ODS) molybdenum were irradiated at 300 C and 600 C in the high flux isotope reactor (HFIR) to neutron fluences of 0.2, 2.1, and 24.3 x 10{sup 24} n/m{sup 2} (E > 0.1 MeV), producing damage levels of 0.01, 0.1 and 1.3 Mo-dpa. Hardness measurements, electrical resistivity measurements, tensile testing, and Transmission Electron Microscopy (TEM) were used to assess the defect structure. Irradiation hardening was evident even at a damage level of 0.01 dpa resulting in a significant increase in yield stress, decrease in ductility, and elevation of the Ductile-to-Brittle Transition Temperature (DBTT). The observed size and number density of voids and loops as well as the measured irradiation hardening and electrical resistivity were found to increase sub-linearly with fluence over the range of exposure investigated. This supports the idea that the formation of the extended defects that produce irradiation hardening in molybdenum are the result of a nucleation and growth process rather than the formation of sessile defects directly from the displacement damage cascades. The formation of sessile defect clusters in the displacement cascade would be expected to result in a linear fluence dependence for the number density of defects followed by saturation at fluences less than 1-dpa. This conclusion is supported by Molecular Dynamics (MD) simulations of cascade damage which do not reveal large clusters forming directly as a result of the short-term collapse of the cascade. The finer grain size for the unalloyed Mo and ODS Mo compared to Low Carbon Arc Cast molybdenum results in slightly less irradiation hardening and slightly lower DBTT values. The unalloyed molybdenum used in this work had a low impurity interstitial content that correlates with a slightly lower void size and void number density, less irradiation hardening and lower change in electrical resistivity in this fluence range than is observed for ODS Mo. Although the differences are relatively subtle, this result does suggest that high purity can result in slightly improved resistance to irradiation embrittlement in molybdenum at low fluences.

B. V. Cockeran, R. W. Smith, L.L. Snead

2007-11-21T23:59:59.000Z

306

Calculation of NOx Emission Reduction from Implementation of the 2000 IECC/IRC Conservation Code in Texas  

E-Print Network [OSTI]

building prototypes, which will be constructed to be representative of the new building construction in Texas. 12 The NAHB characteristics divided the state into east (E), and west (W) divisions: window-to-wall area E=15.28%, W=20.6%, glazing U.... Division (East and West Texas): From NAHB survey data. 17. AFUE (%),SEER and Water Heater Efficiency for 1999 standard and IECC 2000 house are 80%, 11 and 76%, respectively. Table 1: 2002 NOx emissions reductions from implementation of the 2000 IECC...

Turner, W. D.; Yazdani, B.; Im, P.; Verdict, M.; Bryant, J.; Fitzpatrick, T.; Haberl, J. S.; Culp, C.

2003-01-01T23:59:59.000Z

307

Intergrated Nox Emissions Reductions from Energy Efficiency and Renewable Energy (EE/RE) Programs across State Agencies in Texas  

E-Print Network [OSTI]

1 Calculation of Integrated NOx Emissions Reductions from Energy Efficiency and Renewable Energy (EE/RE) Programs across State Agencies in Texas Juan-Carlos Baltazar, Ph.D., P.E.,Jeff S. Haberl, Ph.D., P.E., and Bahman Yazdani, P... on Environmental Quality (TCEQ) from the state-wide energy efficiency and renewable energy programs. These programs include: the impact of code-complaint construction, the Texas Public Utility Commission (PUC), the energy efficiency programs managed by the Texas...

Baltazar, J.C.; Haberl, J.; Yazdani, B.

2014-01-01T23:59:59.000Z

308

Impact of the Driving Cycle on the NOx and Particulate Matter Exhaust Emissions of Diesel Passenger Cars  

Science Journals Connector (OSTI)

Impact of the Driving Cycle on the NOx and Particulate Matter Exhaust Emissions of Diesel Passenger Cars ... The driving cycles used are the New European Driving Cycle (NEDC), the 11 and 15 modes Japanese cycles, and three U.S. driving cycles: Federal Test Procedure (FTP-75), US06, and Highway. ... In general, we can state that a reduction in compression ratio in combination with an advanced boosting system and a fast response of the EGR system with advanced EGR cooling leads to a reduction of the emission level. ...

Efthimios Zervas; George Bikas

2008-02-19T23:59:59.000Z

309

Development of a Low NOx Medium sized Industrial Gas Turbine Operating on Hydrogen-Rich Renewable and Opportunity Fuels  

SciTech Connect (OSTI)

This report presents the accomplishments at the completion of the DOE sponsored project (Contract # DE-FC26-09NT05873) undertaken by Solar Turbines Incorporated. The objective of this 54-month project was to develop a low NOx combustion system for a medium sized industrial gas turbine engine operating on Hydrogen-rich renewable and opportunity Fuels. The work in this project was focused on development of a combustion system sized for 15MW Titan 130 gas turbine engine based on design analysis and rig test results. Although detailed engine evaluation of the complete system is required prior to commercial application, those tasks were beyond the scope of this DOE sponsored project. The project tasks were organized in three stages, Stages 2 through 4. In Stage 2 of this project, Solar Turbines Incorporated characterized the low emission capability of current Titan 130 SoLoNOx fuel injector while operating on a matrix of fuel blends with varying Hydrogen concentration. The mapping in this phase was performed on a fuel injector designed for natural gas operation. Favorable test results were obtained in this phase on emissions and operability. However, the resulting fuel supply pressure needed to operate the engine with the lower Wobbe Index opportunity fuels would require additional gas compression, resulting in parasitic load and reduced thermal efficiency. In Stage 3, Solar characterized the pressure loss in the fuel injector and developed modifications to the fuel injection system through detailed network analysis. In this modification, only the fuel delivery flowpath was modified and the air-side of the injector and the premixing passages were not altered. The modified injector was fabricated and tested and verified to produce similar operability and emissions as the Stage 2 results. In parallel, Solar also fabricated a dual fuel capable injector with the same air-side flowpath to improve commercialization potential. This injector was also test verified to produce 15-ppm NOx capability on high Hydrogen fuels. In Stage 4, Solar fabricated a complete set of injectors and a combustor liner to test the system capability in a full-scale atmospheric rig. Extensive high-pressure single injector rig test results show that 15-ppm NOx guarantee is achievable from 50% to 100% Load with fuel blends containing up to 65% Hydrogen. Because of safety limitations in Solar Test Facility, the atmospheric rig tests were limited to methane-based fuel blends. Further work to validate the durability and installed engine capability would require long-term engine field test.

Srinivasan, Ram

2013-07-31T23:59:59.000Z

310

Corrosion Behavior of AISI 316L Stainless Steel and ODS FeAl Aluminide in Eutectic Li2CO3K2CO3 Molten Carbonates under Flowing CO2O2 Gas Mixtures  

Science Journals Connector (OSTI)

A kinetics study on AISI 316L stainless steel and ODS(Oxide-Dispersion-Strenghtened) FeAl iron aluminide was conducted concerningits corrosion behavior in moltenLi2CO3-K2CO3 eutectic at 650C in flowingCO2-O2 gas...

S. Frangini

2000-02-01T23:59:59.000Z

311

Understanding the Synergistic Catalytic Effect between La2O3 and CaO for the CH4 Lean De-NOx Reaction:? Kinetic and Mechanistic Studies  

Science Journals Connector (OSTI)

Department of Chemistry, Heterogeneous Catalysis Laboratory, University of Cyprus, P.O. ... 3-5 Methane is of particular interest as a reductant hydrocarbon species because of the large availability of natural gas, the use of the latter at gas-fired power plants (main stationary NOx polluting source), and the potential to be considered as an alternative to NH3 reductant used in industrial practice (NH3?SCR technology), which faces various problems. ... However, the likelihood for the presence of inactive but exchangeable NOx species with gaseous 15NO cannot be excluded. ...

T. Anastasiadou; L. A. Loukatzikou; C. N. Costa; A. M. Efstathiou

2005-06-28T23:59:59.000Z

312

Analysis of different control strategies for the simultaneous reduction of CO2 and NOx emissions of a diesel hybrid passenger car  

Science Journals Connector (OSTI)

Different control strategies for a diesel parallel hybrid passenger car were evaluated through numerical simulations. Two different control strategies were analysed: the first focused on fuel consumption minimisation, the second on NOx emissions cuts. Each of these goals was addressed through two different methodologies, the first based on a group of heuristic laws, the second focused on the instantaneous minimisation of a cost function that takes into account both the fuel and battery energies. A first assessment of the potential of a diesel hybrid passenger car as far as fuel consumption and NOx emissions reductions are concerned was obtained.

Federico Millo; Carlo V. Ferraro; Luciano Rolando

2012-01-01T23:59:59.000Z

313

Transportation and Stationary Power Integration Workshop: A California...  

Broader source: Energy.gov (indexed) [DOE]

October 27th 3 of 18 Mike Tollstrup Horizontal lines indicate 2007 CARB DG Standards * Combined cycle turbine placed for reference only. CO Standard NOx Standard VOC Standard...

314

JV Task 117 - Impact of Lignite Properties on Powerspan's NOx Oxidation System  

SciTech Connect (OSTI)

Powerspan's multipollutant control process called electrocatalytic oxidation (ECO) technology is designed to simultaneously remove SO{sub 2}, NO{sub x}, PM{sub 2.5}, acid gases (such as hydrogen fluoride [HF], hydrochloric acid [HCl], and sulfur trioxide [SO{sub 3}]), Hg, and other metals from the flue gas of coal-fired power plants. The core of this technology is a dielectric barrier discharge reactor composed of cylindrical quartz electrodes residing in metal tubes. Electrical discharge through the flue gas, passing between the electrode and the tube, produces reactive O and OH radicals. The O and OH radicals react with flue gas components to oxidize NO to NO{sub 2} and HNO{sub 3} and a small portion of the SO{sub 2} to SO{sub 3} and H{sub 2}SO{sub 4}. The oxidized compounds are subsequently removed in a downstream scrubber and wet electrostatic precipitator. A challenging characteristic of selected North Dakota lignites is their high sodium content. During high-sodium lignite combustion and gas cooling, the sodium vaporizes and condenses to produce sodium- and sulfur-rich aerosols. Based on past work, it was hypothesized that the sodium aerosols would deposit on and react with the silica electrodes and react with the silica electrodes, resulting in the formation of sodium silicate. The deposit and reacted surface layer would then electrically alter the electrode, thus impacting its dielectric properties and NO{sub x} conversion capability. The purpose of this project was to determine the impact of lignite-derived flue gas containing sodium aerosols on Powerspan's dielectric barrier discharge (DBD) reactor with specific focus on the interaction with the quartz electrodes. Partners in the project were Minnkota Power Cooperative; Basin Electric Power Cooperative; Montana Dakota Utilities Co.; Minnesota Power; the North Dakota Industrial Commission, the Lignite Energy Council, and the Lignite Research Council; the Energy & Environmental Research Center (EERC); and the U.S. Department of Energy. An electrocatalytic oxidation (ECO) reactor slipstream system was designed by Powerspan and the EERC. The slipstream system was installed by the EERC at Minnkota Power Cooperative's Milton R. Young Station Unit 1 downstream of the electrostatic precipitator where the flue gas temperature ranged from 300 to 350 F. The system was commissioned on July 3, 2007, operated for 107 days, and then winterized upon completion of the testing campaign. Operational performance of the system was monitored, and data were archived for postprocessing. A pair of electrodes were extracted and replaced on a biweekly basis. Each pair of electrodes was shipped to Powerspan to determine NO conversion efficiency in Powerspan's laboratory reactor. Tested electrodes were then shipped to the EERC for scanning electron microscopy (SEM) and x-ray microanalysis. Measurement of NO{sub x} conversion online in operating the slipstream system was not possible because the nitric and sulfuric acid production by the DBD reactor results in conditioning corrosion challenges in the sample extraction system and NO measurement technologies. The operational observations, performance results, and lab testing showed that the system was adversely affected by accumulation of the aerosol materials on the electrode. NO{sub x} conversion by ash-covered electrodes was significantly reduced; however, with electrodes that were rinsed with water, the NOx conversion efficiency recovered to nearly that of a new electrode. In addition, the visual appearance of the electrode after washing did not show evidence of a cloudy reacted surface but appeared similar to an unexposed electrode. Examination of the electrodes using SEM x-ray microanalysis showed significant elemental sodium, sulfur, calcium, potassium, and silica in the ash coating the electrodes. There was no evidence of the reaction of the sodium with the silica electrodes to produce sodium silicate layers. All SEM images showed a clearly marked boundary between the ash and the silica. Sodium and sulfur are the main culprits in the

Scott Tolbert; Steven Benson

2008-02-29T23:59:59.000Z

315

Near-Zero Emissions Oxy-Combustion Flue Gas Purification Task 2: SOx/Nox/Hg Removal for High Sulfur Coal  

SciTech Connect (OSTI)

The goal of this project is to develop a near-zero emissions flue gas purification technology for existing PC (pulverized coal) power plants that are retrofitted with oxy-combustion technology. The objective of Task 2 of this project was to evaluate an alternative method of SOx, NOx and Hg removal from flue gas produced by burning high sulfur coal in oxy-combustion power plants. The goal of the program was not only to investigate a new method of flue gas purification but also to produce useful acid byproduct streams as an alternative to using a traditional FGD and SCR for flue gas processing. During the project two main constraints were identified that limit the ability of the process to achieve project goals. 1) Due to boiler island corrosion issues >60% of the sulfur must be removed in the boiler island with the use of an FGD. 2) A suitable method could not be found to remove NOx from the concentrated sulfuric acid product, which limits sale-ability of the acid, as well as the NOx removal efficiency of the process. Given the complexity and safety issues inherent in the cycle it is concluded that the acid product would not be directly saleable and, in this case, other flue gas purification schemes are better suited for SOx/NOx/Hg control when burning high sulfur coal, e.g. this project's Task 3 process or a traditional FGD and SCR.

Nick Degenstein; Minish Shah; Doughlas Louie

2012-05-01T23:59:59.000Z

316

Effects of diesel-water emulsion combustion on diesel engine NOx emissions. Final report, 1 January 1998--1 May 1999  

SciTech Connect (OSTI)

This study examines the effects of combusting a mixture of diesel fuel, water, and surfactant on the nitrogen oxides (NOx) emissions from a compression ignition diesel engine. Extensive previous research in the literature has attributed the observed reduction of nitrogen oxide emissions to a suppression of flame temperature due to quenching effects from the water, thereby reducing thermal NOx formation. The report highlights the relevant theory, operation, and design parameters of diesel internal combustion engines. Experimental procedures conducted using a Detroit Diesel 4-cylinder diesel engine are discussed. Results from testing diesel fuel with varying ratios of water balanced with a surfactant to stabilize the emulsion are presented and discussed. The data shows significant NOx emission reduction with up to 45 percent water, by volume, in the fuel. These results are correlated with thermodynamic first law and equilibrium combustion products analyses to estimate the adiabatic flame temperature of the standard fuel and fuel-water emulsion cases. Results indicate that thermal NOx is indeed reduced by quenching and flame temperature suppression, confirming reports in the literature. Recommendations are given for further studies, including improving the fuel-water emulsion and considerations for long-term testing.

Canfield, A.C.

1999-05-01T23:59:59.000Z

317

Microsoft Word - 41892_Praxair_Low NOx_Factsheet_Rev 0a_01-09-04.doc  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

FACT SHEET FACT SHEET Revision 0a Jan. 9, 2004 Page 1 of 4 I. PROJECT DESCRIPTION A. Objective: The objective of this project is to design a gas turbine combustor system for new and existing turbines with a combination of air flow management control and fuel composition control to achieve 2 ppm NOx emissions. Since most Integrated Gasification Combined-Cycle (IGCC) systems consider the use of natural gas as an alternative fuel and there is a large infrastructure of existing natural gas based turbines, it is imperative that the combustor design be amenable to operating on both coal derived fuel gas and natural gas. The specific objectives of each phase of this program are: Phase I: Develop conceptual design of turbine combustor with air flow control and fuel

318

DEVELOPMENT OF A VALIDATED MODEL FOR USE IN MINIMIZING NOx EMISSIONS AND MAXIMIZING CARBON UTILIZATION WHEN COFIRING BIOMASS WITH COAL  

SciTech Connect (OSTI)

This is the first Quarterly Technical Report for DOE Cooperative Agreement No. DE-FC26-00NT40895. A statement of the project objectives is included in the Introduction of this report. The project goals and detailed plans were presented in two project kickoff meetings; one at NETL in Pittsburgh and one in Birmingham, AL at Southern Research Institute. Progress has been made in developing a modeling approach to synthesize the reaction time and temperature distributions that will be produced by computational fluid dynamic models of the pilot-scale combustion furnace and the char burnout and chemical reaction kinetics that will predict NOx emissions and unburned carbon levels in the furnace exhaust. Preparations are under way for the initial pilot-scale combustion experiments.

Larry G. Felix; P. Vann Bush; Stephen Niksa

2001-01-24T23:59:59.000Z

319

A method to extend flamelet manifolds for prediction of NOx and long time scale species with tabulated chemistry  

Science Journals Connector (OSTI)

Numerical simulation is currently used to help design low NOx devices for aircraft engines. In order to improve the prediction of pollutant species, combustion models based on tabulated chemistry have been commonly used in recent years. However, the short time scales of usual flamelet manifolds can lead to errors concerning the NO prediction in post flame area, as shown in this paper. Thus, a new method is proposed to extend the manifold in order to describe the evolution of species with a long characteristic time. This method is tested in the framework of 0D-1D computations. The use of the extended manifold is shown to be necessary to correctly predict the evolution of NO concentration in burnt gases. As an example, the extended and classical manifolds were compared in the framework of 2D simulations of an industrial-like combustor, showing an evident difference on the NO levels predicted in the outlet section.

Aymeric Boucher; Nicolas Bertier; Francis Dupoirieux

2014-01-01T23:59:59.000Z

320

Mass Balance of Gaseous and Particulate Products from ?-Pinene/O3/Air in the Absence of Light and ?-Pinene/NOx/Air in the Presence of Natural Sunlight  

Science Journals Connector (OSTI)

The gas and particle phase products from the reaction of ?-pinene with the atmospheric oxidants O3 and OH radicals in the presence of NOx were investigated using both gas chromatography-mass spectrometry (GC-MS) ...

M. Jaoui; R. M. Kamens

2003-06-01T23:59:59.000Z

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321

180 MW demonstration of advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NOx) emissions from coal-fired boilers. Technical progress report, First quarter 1991  

SciTech Connect (OSTI)

This project is being conducted at Gulf Power Company`s Plant Lansing Smith Unit 2 (LS-2) located near Panama City, Florida. The primary objective of this demonstration is to determine the long-term effects of commercially available tangentially-fired low NOx combustion technologies on NOx emissions and boiler performance. The stepwise approach that is being used to evaluate the NOx control technologies requires three plant outages to successively install the test instrumentation and the different levels of the low NOx concentric firing system (LNCFS). Following each outage, a series of four groups of tests are performed. These are (1) diagnostic, (2) performance, (3) long-term, and (4) verification. These tests are used to quantify the NOx reductions of each technology and evaluate the effects of those reductions on other combustion parameters such as particulate characteristics and boiler efficiency. This quarterly update provides a description of the flow modeling study. This modeling effort centers on evaluating the in-furnace flow and mixing phenomena for the various low NOx firing systems being demonstrated at LS-2. Testing on the 1/12 scale model of the LS-2 boiler and the 1/6 scale model of the overfire air ductwork was completed. The test matrix included an analysis of the overfire air ductwork and three different boiler configurations. This report also contains results from the Phase 1 baseline tests. Data from the diagnostic, performance, and verification tests are presented. In addition, NOx emissions data and unit load profiles collected during long-term testing are reported. At the full load condition, the baseline NOx emission level at LS-2 is 0.62 lb/mBtu.

Not Available

1991-12-31T23:59:59.000Z

322

Near-Zero Emissions Oxy-Combustion Flue Gas Purification Task 3: SOx/NOx/Hg Removal for Low Sulfur Coal  

SciTech Connect (OSTI)

The goal of this project was to develop a near-zero emissions flue gas purification technology for existing PC (pulverized coal) power plants that are retrofitted with oxycombustion technology. The objective of Task 3 of this project was to evaluate an alternative method of SOx, NOx and Hg removal from flue gas produced by burning low sulfur coal in oxy-combustion power plants. The goal of the program was to conduct an experimental investigation and to develop a novel process for simultaneously removal of SOx and NOx from power plants that would operate on low sulfur coal without the need for wet-FGD & SCRs. A novel purification process operating at high pressures and ambient temperatures was developed. Activated carbon??s catalytic and adsorbent capabilities are used to oxidize the sulfur and nitrous oxides to SO{sub 3} and NO{sub 2} species, which are adsorbed on the activated carbon and removed from the gas phase. Activated carbon is regenerated by water wash followed by drying. The development effort commenced with the screening of commercially available activated carbon materials for their capability to remove SO{sub 2}. A bench-unit operating in batch mode was constructed to conduct an experimental investigation of simultaneous SOx and NOx removal from a simulated oxyfuel flue gas mixture. Optimal operating conditions and the capacity of the activated carbon to remove the contaminants were identified. The process was able to achieve simultaneous SOx and NOx removal in a single step. The removal efficiencies were >99.9% for SOx and >98% for NOx. In the longevity tests performed on a batch unit, the retention capacity could be maintained at high level over 20 cycles. This process was able to effectively remove up to 4000 ppm SOx from the simulated feeds corresponding to oxyfuel flue gas from high sulfur coal plants. A dual bed continuous unit with five times the capacity of the batch unit was constructed to test continuous operation and longevity. Full-automation was implemented to enable continuous operation (24/7) with minimum operator supervision. Continuous run was carried out for 40 days. Very high SOx (>99.9%) and NOx (98%) removal efficiencies were also achieved in a continuous unit. However, the retention capacity of carbon beds for SOx and NOx was decreased from ~20 hours to ~10 hours over a 40 day period of operation, which was in contrast to the results obtained in a batch unit. These contradictory results indicate the need for optimization of adsorption-regeneration cycle to maintain long term activity of activated carbon material at a higher level and thus minimize the capital cost of the system. In summary, the activated carbon process exceeded performance targets for SOx and NOx removal efficiencies and it was found to be suitable for power plants burning both low and high sulfur coals. More efforts are needed to optimize the system performance.

Monica Zanfir; Rahul Solunke; Minish Shah

2012-06-01T23:59:59.000Z

323

180 MW demonstration of advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NOx) emissions from coal-fired boilers. Technical progress report, Third quarter 1992  

SciTech Connect (OSTI)

The project is being conducted at Gulf Power Company`s Plant Lansing Smith Unit 2 located near Panama City, Florida. The primary objective of this demonstration is to determine the long-term effects of commercially available tangentially-fired low NOx combustion technologies on NOx emissions and boiler performance. A target of achieving 50% NOx reduction using combustion modifications has been established for the project. The stepwise approach that is being used to evaluate the NOx control technologies requires three plant outages to successively install the test instrumentation and the different levels of the low NOx concentric firing system (LNCFS). Following each outage, a series of four groups of tests are performed. These are (1) diagnostic, (2) performance, (3) long-term, and (4) verification. These tests are used to quantify the NOx reductions of each technology and evaluate the effects of those reductions on other combustion parameters such as particulate characteristics and boiler efficiency. This technical progress report presents the LNCFS Level 1 long-term data collected during this quarter. In addition, a comparison of all the long-term emissions data that have been collected to date is included.

Not Available

1992-12-31T23:59:59.000Z

324

Combustion characteristics and NOx emissions of two kinds of swirl burners in a 300-MWe wall-fired pulverized-coal utility boiler  

SciTech Connect (OSTI)

Measurements were performed in a 300-MWe wall-fired pulverized-coal utility boiler. Enhanced ignition-dual register (EI-DR) burners and centrally fuel rich (CFR) swirl coal combustion burners were installed in the bottom row of the furnace during experiments. Local mean concentrations of O{sub 2}, CO, CO{sub 2} and NOx gas species, gas temperatures, and char burnout were determined in the region of the two types of burners. For centrally fuel rich swirl coal combustion burners, local mean CO concentrations, gas temperatures and the temperature gradient are higher and mean concentrations of O{sub 2} and NOx along the jet flow direction in the burner region are lower than for the enhanced ignition-dual register burners. Moreover, the mean O{sub 2} concentration is higher and the gas temperature and mean CO concentration are lower in the side wall region. For centrally fuel rich swirl coal combustion burners in the bottom row, the combustion efficiency of the boiler increases from 96.73% to 97.09%, and NOx emission decreases from 411.5 to 355 ppm at 6% O{sub 2} compared to enhanced ignition-dual register burners and the boiler operates stably at 110 MWe without auxiliary fuel oil.

Li, Z.Q.; Jing, J.P.; Chen, Z.C.; Ren, F.; Xu, B.; Wei, H.D.; Ge, Z.H. [Harbin Institute for Technology, Harbin (China). School for Energy Science & Engineering

2008-07-01T23:59:59.000Z

325

Visualization research on high efficiency and low NOx combustion technology with multiple air?staged and large angle counter flow of fuel?rich jet  

Science Journals Connector (OSTI)

In this paper a new technique for tangentially fired pulverized coal boiler high efficiency and low NOx combustion technology with multiple air?staged and large angle counter flow of fuel?rich jet (ACCT for short) is proposed. Based on traditional air staged and rich?lean combustion technique a NOx reduction area is introduced through air injection between primary combustion zone and secondary combustion zone. To verify the characters of this technique experiment with a new developed visualization method image processing on smog tracing with fractal dimension is carried out on a cold model of 300 MW furnace designed with this technique. The result shows compared to injection without counter flow the center lines of counter flow injection go deeper into the chamber and form a smaller tangential circle which means the rotating momentum of entire vortex is feebler and the exit gyration is weaker. It also shows that with counter flow the fractal dimensions of boundary between primary jet and front fire side air is bigger which means more intense turbulence and better mix. As a conclusion with fractal dimension image processing on smog tracing method can be a quantificational convenient and effective visualization way without disturbing the flow field and its also acknowledged that ACCT has the following superiorities: high burn out rate low NOx emission stable burning slagging preventing and temp?bias reducing.

Y. Y. Li; Y. Li; Z. C. Lin; W. D. Fan; M. C. Zhang

2010-01-01T23:59:59.000Z

326

Influence of operating conditions and coal properties on \\{NOx\\} and N2O emissions in pressurized fluidized bed combustion of subbituminous coals  

Science Journals Connector (OSTI)

This experimental study is aimed at finding effects of operating conditions in PFBC on nitrogen oxide emissions for subbituminous coals differing in ash content/composition, combustion/gasification reactivities and in particle size distribution. The experiments have been done on a smaller laboratory apparatus with ID=8 cm. The effects of operating pressure (0.11 MPa), temperature of the fluidized bed (800900 C), freeboard temperature and oxygen concentration (310vol.%) on the nitrogen oxides emissions are relatively complex, coupled with temperature of burning coal particles. The coal ash content/composition (esp. CaO and Fe2O3) and fly ash freeboard concentration play an important role in formation/destruction chemistry of both NO and N2O. The \\{NOx\\} emissions decrease with increasing operating pressure at the same volumetric oxygen concentration and temperature. Temperature, volatile content, reactivities of coals and ash composition are the most important factors for N2O emissions. The N2O emissions are either almost constant or can exhibit a maximum at increasing operating pressure. Influence of increasing oxygen concentration on \\{NOx\\} and N2O emissions is more pronounced at lower operating pressures, esp. for the less reactive, medium ash coal. The particle size distribution of the coal (influence of coal dust) can cause characteristic changes in \\{NOx\\} and N2O emissions in PFBC, esp. at lower combustion temperatures (800840 C). The emission changes are dependent on ash properties/composition.

Karel Svoboda; Michael Poho?el

2004-01-01T23:59:59.000Z

327

Validation of a zero-dimensional model for prediction of \\{NOx\\} and engine performance for electronically controlled marine two-stroke diesel engines  

Science Journals Connector (OSTI)

The aim of this paper is to derive a methodology suitable for energy system analysis for predicting the performance and \\{NOx\\} emissions of marine low speed diesel engines. The paper describes a zero-dimensional model, evaluating the engine performance by means of an energy balance and a two zone combustion model using ideal gas law equations over a complete crank cycle. The combustion process is divided into intervals, and the product composition and flame temperature are calculated in each interval. The \\{NOx\\} emissions are predicted using the extended Zeldovich mechanism. The model is validated using experimental data from two MAN B&W engines; one case being data subject to engine parameter changes corresponding to simulating an electronically controlled engine; the second case providing data covering almost all model input and output parameters. The first case of validation suggests that the model can predict specific fuel oil consumption and \\{NOx\\} emissions within the 95% confidence intervals given by the experimental measurements. The second validation confirms the capability of the model to match measured engine output parameters based on measured engine input parameters with a maximum 5% deviation.

Fabio Scappin; Sigurur H. Stefansson; Fredrik Haglind; Anders Andreasen; Ulrik Larsen

2012-01-01T23:59:59.000Z

328

kazimierzak ODS workshop 111710.ppt  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

EU
ODS
material
Vendor
Perspec6ve,
Past,
 EU
ODS
material
Vendor
Perspec6ve,
Past,
 Present
and
Future.
 Bohumil
Kazimierzak
 Dour
Metal
Sro.
 viacesty@viacesty.sk Why
a
New
Dour
Metal
ODS
Supplier?
 - 
Because
the
former
Dour
Metal
Belgium
had
 demonstrated
the
ability
to
produce
large
quan66es
of

 high
performance

ODS
materials
 - 
Because
compe6tors
i.e.
Special
Metals
and
Plansee
 have
stopped
ODS
produc6on
but
part
of
the
ODS
market
 is
s6ll
there
 - Rising
interest
in
ODS
materials
for
energy
applica6ons
 (fossil,
fissile,
fusion)
especially
in
the
form
of
tubing

 - Because
Dour
Metal
is
convinced
that
it
may
build
a
new


329

Emission reduction of NOx and CO by optimization of the automatic control system in a coal-fired stoker boiler  

SciTech Connect (OSTI)

To date research on NO, and CO emission reduction in stoker-fired boilers has been devoted to combustion modification to the overfire air, diverting air to a selected set of burners, using modified low-NOx, burners, using flue gas recirculation or flue gas treatment with specially controlled catalyst and additives. This study introduces a concept that focuses on the dynamics of the boiler and the automatic control system. The objective of this study was to reduce the NO and CO emissions by restructuring the automatic control system and then tuning the control system with parameters that have been optimized with emission reduction as the objective. Dynamic data were obtained from a step-input test of either the underfire air or the overfire air. These data were used to model the boiler with a transfer function describing the emissions. The analyzer dynamic response was included in the overall model. The control parameters were determined from this overall emissions transfer function by mathematical optimization. These control parameters constituted the initial values in the automatic control system used for the final tests in the boiler. Additional adjustments to reduce the emissions were carried out during boiler operation. A low controller gain and a fast reset time were found to be the most suitable setting for the control system. The NO emissions controlled by the overfire air and CO emissions controlled by the underfire air produced the best results.

Schnelle, K.B.; Laungphairojana, A.; Debelak, K.A. [Vanderbilt University, Nashville, TN (United States). Dept. of Chemical Engineering

2006-07-15T23:59:59.000Z

330

Latest developments and application of DB Riley`s low NOx CCV{reg_sign} burner technology  

SciTech Connect (OSTI)

Recent developments in DB Riley (DBR) low NO{sub x} burner technology and the application of this technology in coal fired utility boilers are discussed. Since the promulgation of the Clean Air Act Amendment in 1990, DBR has sold nearly 1500 Controlled Combustion Venturi (CCV{reg_sign}) burners on pulverized coal fired utility boilers reducing NOx emissions 50 - 70% from uncontrolled levels. This technology has been retrofitted on boiler designs ranging in size and type from 50 MW front wall fired boilers to 1300 MW opposed fired cell type boilers. In DBR`s latest version of the CCV{reg_sign} burner, a second controlled flow air zone was added to enhance NO{sub x} control capability. Other developments included improved burner air flow measurement accuracy and several mechanical design upgrades such as new coal spreader designs for 3 year wear life. Test results of the CCV{reg_sign} dual air zone burner in DBR`s 100 million Btu/hr (29 MW) coal burner test facility are presented. In the test program, coals from four utility boiler sites were fired to provide a range of coal properties. A baseline high volatile bituminous coal was also fired to provide a comparison with 1992 test data for the CCV{reg_sign} single register burner. The test results showed that the second air zone enhanced NO{sub x} reduction capability by an additional 20% over the single register design. Computational fluid dynamic (CFD) modeling results of the CCV{reg_sign} dual air zone burner are also presented showing near field mixing patterns conducive to low NO{sub x} firing.

Penterson, C.; Ake, T. [DB Riley, Inc., Worcester, MA (United States)

1998-04-01T23:59:59.000Z

331

High pressure conversion of \\{NOx\\} and Hg and their capture as aqueous condensates in a laboratory piston-compressor simulating oxy-fuel CO2 compression  

Science Journals Connector (OSTI)

Abstract Oxy-fuel technology for CO2 capture has largely focused on combustion characteristics as a driver towards demonstration. Impurity removal studies typically centre on the how current environmental control units (FGD, SCR, activated carbon beds) operate in oxy-fuel firing. However, it is expected that some removal of \\{NOx\\} and \\{SOx\\} may occur during compression of flue gas through the lead chamber process. Some commercial systems link the capture of mercury to the formation of acid condensates (as a soluble mercury salt). Mercury in compressed flue gas represents a potential corrosion risk in the processing of CO2 from oxy-fuel combustion processes. Gas phase elemental mercury (Hg0) is difficult to remove from the flue gas and the level of cleaning required to prevent corrosion of cryogenic brazed aluminium heat exchangers is uncertain. This work has investigated the behaviour of gaseous Hg0 in pressurised oxy-fuel systems in terms of the potential capture in acidic condensates, interaction with \\{NOx\\} gases and liquid stability on de-pressurisation. The work was undertaken on an adapted laboratory scale three stage axial-piston compressor with gas and liquid sampling at pressures up to 30bar. The main finding was that gaseous Hg0 reacts readily with NO2 formed from NO oxidation at high pressure. This reaction occurred without the presence of water, either water vapour or liquid water, contrary to speculation in the literature. Without NO2, no capture of Hg0 was observed in the compression system. Overall, the capture of mercury during compression occurred as a consequence of high pressure, longer residence time and concentration of NO2. Capture rates of 100% Hg and 7583% \\{NOx\\} were measured from the compressor exit at 30barg.

Rohan Stanger; Timothy Ting; Terry Wall

2014-01-01T23:59:59.000Z

332

Ambient Temperature Hydrocarbon Selective Catalytic Reduction of NOx Using Atmospheric Pressure Nonthermal Plasma Activation of a Ag/Al2O3 Catalyst  

Science Journals Connector (OSTI)

Ambient Temperature Hydrocarbon Selective Catalytic Reduction of NOx Using Atmospheric Pressure Nonthermal Plasma Activation of a Ag/Al2O3 Catalyst ... This low temperature activity provides the basis for applying nonthermal plasmas to activate emission control catalysts during cold start conditions, which remains an important issue for mobile and stationary applications. ... (14, 15) Therefore, the combination of heterogeneous catalysis with plasmas has attracted interest due to the combined possible advantages of having a fast and low-temperature reaction from atmospheric nonthermal plasma and high product selectivity from heterogeneous catalysis. ...

Cristina E. Stere; Wameedh Adress; Robbie Burch; Sarayute Chansai; Alexandre Goguet; William G. Graham; Fabio De Rosa; Vincenzo Palma; Christopher Hardacre

2014-01-10T23:59:59.000Z

333

DOE/EA-1472: Finding of No Significant Impact for the Commercial Demonstration of the Low NOx Burner/Separated Over-Fire Air Integration System Emission Reduction Technology (03/11/03)  

Broader source: Energy.gov (indexed) [DOE]

IMPACT IMPACT COMMERCIAL DEMONSRATION OF THE LOW NOx BURNER/SEPARATED OVER- FIRE AIR (LNB/SOFA) INTEGRATON SYSTEM EMISSION REDUCTION TECHNOLOGY HOLCOMB STATION SUNFLOWER ELECTRIC POWER CORPORATION FINNEY COUNTY, KANSAS AGENCY: U.S. Department of Energy (DOE) ACTION: Finding of No Significant Impact (FONSI) SUMMARY: The DOE has prepared an Environmental Assessment (EA), to analyze the potential impacts of the commercial application of the Low-NOx Burner/Separated Over-Fire Air (LNB/SOFA) integration system to achieve nitrogen oxide (NOx) emissions reduction at Sunflower's Holcomb Unit No. 1 (Holcomb Station), located near Garden City, in Finney County, Kansas. The Holcomb Station would be modified in three distinct phases to demonstrate the synergistic effect of layering NO,

334

Oxyfuel CO2 compression: The gas phase reaction of elemental mercury and \\{NOx\\} at high pressure and absorption into nitric acid  

Science Journals Connector (OSTI)

Abstract Oxyfuel combustion is a technology which combusts coal in oxygen and recycled flue gas, producing a carbon dioxide rich flue gas for sequestration. Oxyfuel flue gas contains trace amounts of elemental mercury, which may corrode brazed aluminium heat exchangers used in the carbon dioxide purification system. International gas vendors have tested the use of the compression system to remove other flue gas impurities such as NOx; however, the reaction mechanism of mercury and its reaction products with \\{NOx\\} and nitric acid formed with condensed water vapour are unclear. This study used lab scale experiments to study the absorption of gaseous elemental mercury into nitric acid and the gas phase reaction between mercury and nitrogen dioxide formed from oxidised NO at pressures up to 25bar. It was observed that mercury has limited absorption into nitric acid and may partially desorb out of solution after depressurisation. On the other hand, mercury reacted readily with nitrogen dioxide (formed from nitric oxide oxidation at high pressure) in the gas phase. These gas phase reactions from the oxidation of nitric oxide to nitrogen dioxide to the subsequent oxidation of elemental mercury by nitrogen dioxide were predicted using existing global kinetic equations. The limited absorption of gaseous elemental mercury in nitric acid and significant oxidation of gaseous elemental mercury by nitrogen dioxide suggests that the primary removal step for elemental mercury is through the gas phase reaction. Oxyfuel compression circuits should therefore allow sufficient residence time for this gas phase reaction to occur.

Timothy Ting; Rohan Stanger; Terry Wall

2014-01-01T23:59:59.000Z

335

Biomarker Response to Galactic Cosmic Ray-Induced NOx and the Methane Greenhouse Effect in the Atmosphere of an Earthlike Planet Orbiting an M-Dwarf Star  

E-Print Network [OSTI]

Planets orbiting in the habitable zone (HZ) of M-Dwarf stars are subject to high levels of galactic cosmic rays (GCRs) which produce nitrogen oxides in earthlike atmospheres. We investigate to what extent this NOx may modify biomarker compounds such as ozone (O3) and nitrous oxide (N2O), as well as related compounds such as water (H2O) (essential for life) and methane (CH4) (which has both abiotic and biotic sources) . Our model results suggest that such signals are robust, changing in the M-star world atmospheric column by up to 20% due to the GCR NOx effects compared to an M-star run without GCR effects and can therefore survive at least the effects of galactic cosmic rays. We have not however investigated stellar cosmic rays here. CH4 levels are about 10 times higher than on the Earth related to a lowering in hydroxyl (OH) in response to changes in UV. The increase is less than reported in previous studies. This difference arose partly because we used different biogenic input. For example, we employed 23% ...

Grenfell, J L; Patzer, B; Rauer, H; Segura, A; Stadelmann, A; Stracke, B; Titz, R; Von Paris, P; Grenfell, John Lee; Griessmeier, Jean-Mathias; Patzer, Beate; Rauer, Heike; Segura, Antigona; Stadelmann, Anja; Stracke, Barbara; Titz, Ruth; Paris, Philip von

2007-01-01T23:59:59.000Z

336

NOx Sensor Development  

Broader source: Energy.gov [DOE]

2011 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation

337

NOx Sensor Development  

Broader source: Energy.gov (indexed) [DOE]

zirconia (PSZ) for better mechanical properties * (bottom) Dense LSM (Strontium-doped lanthanum manganite oxide) with yttria fully- stabilized zirconia (YSZ) for...

338

NOx Sensor Development  

Broader source: Energy.gov (indexed) [DOE]

needed to meet emission targets and enable widespread use of diesel vehicles with better fuel economies: We are developing a novel sensor with the potential to meet OEM cost and...

339

Reduction of NOx emission on NiCrAl-Titanium Oxide coated direct injection diesel engine fuelled with radish (Raphanus sativus) biodiesel  

Science Journals Connector (OSTI)

The main aim of this study is the experimental investigation of single cylinder DI diesel engine with and without coating. Diesel and radish (Raphanus sativus) oil Methyl Ester are used as fuels and the results are compared to find the effect of biodiesel in a thermal barrier coating engine. For this purpose engine cylinder head valves and piston crown are coated with 100??m of nickel-chrome-aluminium bond coat and 450??m of TiO2 by the plasma spray method. Radish oil methyl ester is produced by the transesterification process method. From the experimental investigation slight increase in specific fuel consumption in thermal barrier coating engine is observed when compared with the uncoated engine whereas NOx HC Smoke and CO emissions decreased with coated engine for all test fuels used in the coated engine when compared with that of the uncoated engine.

V. Ravikumar; D. Senthilkumar

2013-01-01T23:59:59.000Z

340

NOx, SOx and CO2 Emissions Reduction from Continuous Commissioning (CC) Measures at the Rent-A-Car Facility in the Dallas-Fort Worth International Airport  

E-Print Network [OSTI]

, and CO2) reduction for year 1999 and the projected ones for 2007 and corresponding OSD periods are presented next. Potential Emissions Reductions for 1999 Potential Emissions Reductions for 2007 Emissions Annual (Tons/yr) OSD (Tons/day) Annual... (Tons/yr) OSD (Tons/day) NOX 3.710320 0.012782 1.64387 0.00554 SO2 N/A N/A 1.11594 0.00362 CO2 N/A N/A 1316.468 4.62669 The potential emissions reduction of SO2 and CO2 for the year 1999 was not evaluated because eGRID tables for that year were...

Baltazar-Cervantes, J. C.; Haberl, J. S.; Yazdani, B.

2006-10-27T23:59:59.000Z

Note: This page contains sample records for the topic "nox ods voc" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Biomarker Response to Galactic Cosmic Ray-Induced NOx and the Methane Greenhouse Effect in the Atmosphere of an Earthlike Planet Orbiting an M-Dwarf Star  

E-Print Network [OSTI]

Planets orbiting in the habitable zone (HZ) of M-Dwarf stars are subject to high levels of galactic cosmic rays (GCRs) which produce nitrogen oxides in earthlike atmospheres. We investigate to what extent this NOx may modify biomarker compounds such as ozone (O3) and nitrous oxide (N2O), as well as related compounds such as water (H2O) (essential for life) and methane (CH4) (which has both abiotic and biotic sources) . Our model results suggest that such signals are robust, changing in the M-star world atmospheric column by up to 20% due to the GCR NOx effects compared to an M-star run without GCR effects and can therefore survive at least the effects of galactic cosmic rays. We have not however investigated stellar cosmic rays here. CH4 levels are about 10 times higher than on the Earth related to a lowering in hydroxyl (OH) in response to changes in UV. The increase is less than reported in previous studies. This difference arose partly because we used different biogenic input. For example, we employed 23% lower CH4 fluxes compared to those studies. Unlike on the Earth, relatively modest changes in these fluxes can lead to larger changes in the concentrations of biomarker and related species on the M-star world. We calculate a CH4 greenhouse heating effect of up to 4K. O3 photochemistry in terms of the smog mechanism and the catalytic loss cycles on the M-star world differs considerably compared with the Earth.

John Lee Grenfell; Jean-Mathias Griessmeier; Beate Patzer; Heike Rauer; Antigona Segura; Anja Stadelmann; Barbara Stracke; Ruth Titz; Philip von Paris

2007-02-23T23:59:59.000Z

342

Structure of high pressure Ca(OD){sub 2} II from powder neutron diffraction: Relationship to the ZrO{sub 2} and EuI{sub 2} structures  

SciTech Connect (OSTI)

The {open_quotes}unquenchable{close_quotes} high pressure form of Ca(OD){sub 2} [Ca(OH){sub 2}II] has been synthesized at 9 GPa and 400{degrees}C and recovered to ambient pressure at cryogenic temperatures. The structure was determined from powder neutron diffraction data using the Rietveld technique. The symmetry is monoclinic P2{sub 1}/c with a = 5.3979(4) {angstrom}, b = 6.0931(4) {angstrom}, c = 5.9852(4) {angstrom}, {beta} = 103.581(6), Z = 4 at 1 atm and 11 K. R{sub wp} = 2.8%, R{sub p} = 1.9%, reduced {chi}{sup 2} = 6.6. for 117 variables. The calcium and oxygen substructure is intermediate between that in {alpha}-PbO{sub 2} and that in fluorite; it was previously described as isostructural with baddeleyite (ZrO{sub 2}), but it is more accurately described as isostructural with EuI{sub 2}. This structure is distinguished by the presence of a 3{sup 6} anion met parallel to (100). Only one of the two kinds of D atoms in the structure shows appreciable hydrogen bonding to O, with a second neighbor D...O distance of 1.91 {angstrom}, and an O-D...O angle of 153.2{degrees}; the other D atom has 3 second-neighbor oxygens near 2.6 {angstrom} away.

Leinenweber, K.; Partin, D.E.; Schuelke, U. [Arziona State Univ., Tempe, AZ (United States)] [and others] [Arziona State Univ., Tempe, AZ (United States); and others

1997-09-01T23:59:59.000Z

343

Air Pollution Control  

Science Journals Connector (OSTI)

Petroleum and chemical processes are responsible for many emissions both into the air. Most relevant emissions into the air are nitrous oxides (NOx), sulfur oxides ... compounds (VOC).The major cause of all air pollution

Alireza Bahadori

2014-01-01T23:59:59.000Z

344

Atmos. Chem. Phys., 14, 1097710988, 2014 www.atmos-chem-phys.net/14/10977/2014/  

E-Print Network [OSTI]

side. In addition, there are also about 1000 coal bed methane wells and conventional wells located in emissions of greenhouse gases (mostly methane), volatile organic compounds (VOCs) and nitrogen oxides (NOx

Pierce, Jeffrey

345

Simulating the Impact of Premixed Charge Compression Ignition on Light-Duty Diesel Fuel Economy and Emissions of Particulates and NOx  

SciTech Connect (OSTI)

We utilize the Powertrain Systems Analysis Toolkit (PSAT) combined with transient engine and aftertreatment component models implemented in Matlab/Simulink to simulate the effect of premixed charge compression ignition (PCCI) on the fuel economy and emissions of light-duty diesel-powered conventional and hybrid electric vehicles (HEVs). Our simulated engine is capable of both conventional diesel combustion (CDC) and premixed charge compression ignition (PCCI) over real transient driving cycles. Our simulated aftertreatment train consists of a diesel oxidation catalyst (DOC), lean NOx trap (LNT), and catalyzed diesel particulate filter (DPF). The results demonstrate that, in the simulated conventional vehicle, PCCI can significantly reduce fuel consumption and emissions by reducing the need for LNT and DPF regeneration. However, the opportunity for PCCI operation in the simulated HEV is limited because the engine typically experiences higher loads and multiple stop-start transients that are outside the allowable PCCI operating range. Thus developing ways of extending the PCCI operating range combined with improved control strategies for engine and emissions control management will be especially important for realizing the potential benefits of PCCI in HEVs.

Gao, Zhiming [ORNL; Daw, C Stuart [ORNL; Wagner, Robert M [ORNL; Edwards, Kevin Dean [ORNL; Smith, David E [ORNL

2013-01-01T23:59:59.000Z

346

WearAir: Expressive T-shirts for Air Quality Sensing Sunyoung Kim and Eric Paulos  

E-Print Network [OSTI]

are less proactively concerned with air quality. AIR POLLUTANT: VOLATILE ORGANIC COMPOUNDS Different types of air pollutants contribute to air quality in different locations: Ozone, CO, NOx and VOCs are major contributors to outdoor air pollution; and particulate matters, VOCs, carbon monoxide and lead are common air

Mankoff, Jennifer

347

Two-stroke scooters are a dominant source of air pollution in many cities  

E-Print Network [OSTI]

pollution despite relatively small numbers. Chemical analysis of the emissions shows that SOA is mainly produced via photo oxidation of aromatic VOCs, present in gasoline, from the exhaust. This shows that the known issue of incomplete fuel combustion during... producing higher CO, VOC and PM emissions (but lower NOX). Accordingly, the VOC emissions measured here, in particular aromatics as found in raw gasoline, are also on average 124 and 11times higher from idling and driving 2S scooters, respectively, compared...

Platt, S. M.; El Haddad, I.; Pieber, S. M.; Huang, R.-J.; Zardini, A. A.; Clairotte, M.; Suarez-Bertoa, R.; Barmet, P.; Pfaffenberger, L.; Wolf, R.; Slowik, J. G.; Fuller, S. J.; Kalberer, M.; Chirico, R.; Dommen, J.; Astorga, C.; Zimmermann, R.; Marchand, N.; Hellebust, S.; Temime-Roussel, B.; Baltensperger, U.; Prvt, A. S. H.

2014-05-13T23:59:59.000Z

348

Fabrication technology for ODS Alloy MA957  

SciTech Connect (OSTI)

A successful fabrication schedule has been developed at Carpenter Technology Corporation for the production of MA957 fuel and blanket cladding. Difficulties with gun drilling, plug drawing and recrystallization were overcome to produce a pilot lot of tubing. This report documents the fabrication efforts of two qualified vendors and the support studies performed at WHC to develop the fabrication-schedule.

ML Hamilton; DS Gelles; RJ Lobsinger; MM Paxton; WF Brown

2000-03-16T23:59:59.000Z

349

Table of Contents ODS Scholars 1  

E-Print Network [OSTI]

, and promoting social innovation. "Each of you will have the opportunity to make a difference in your own way

Chapman, Michael S.

350

GAS TURBINES AND BIODIESEL : A CLARIFICATION OF THE RELATIVE  

E-Print Network [OSTI]

1 GAS TURBINES AND BIODIESEL : A CLARIFICATION OF THE RELATIVE NOX INDICES OF FAME, GASOIL ("tallow"). A key factor for the use of biofuels in gas turbines is their Emissions Indices (NOx, CO, VOC to gas turbines is very scarce. Two recent, independent field tests carried out in Europe (RME

Paris-Sud XI, Université de

351

BaO/Al2O3/NiAl(110) Model NOx Storage Materials: the effect of BaO film thickness on the amorphous-to-crystalline Ba(NO3)2 phase transition  

SciTech Connect (OSTI)

The reaction of NO2 with BaO (0.15 2 ML and > 30 ML)/Al2O3(12 ML)/NiAl(110) model NOx storage materials was studied. A thick (~12 ML), ordered Al2O3 film was prepared as the support oxide on a NiAl(110) substrate in order to minimize the effect of the intermixing between the two oxide phases (BaO and Al2O3) on the NOx chemistry of BaO. The growth of a thick alumina film, prepared by atomic oxygen deposition onto NiAl(110), follows a layer-by-layer growth mode and the resulting film is much more stable when exposed to NO2 than the ultra-thin alumina films studied before. The interaction of NO2 with the model NOx storage systems at low coverages of BaO show fundamentally different behaviors from a thick BaO film, as nitrite species form at low exposures of NO2, followed by nitrate formation at high NO2 exposures. In contrast, on the thick BaO layer nitrite-nitrate ion pairs form at 300 K under UHV conditions (PNO2 ~ 1 ? 10-9 Torr). However, at elevated NO2 pressures (? 1 ? 10-5 Torr) the thick BaO film is gradually converted into amorphous Ba(NO3)2 at 300 K. Raising the temperature of the samples with ?BaO > 1 ML after NO2 exposure (in the absence of gas phase NO2) leads to the phase transformation of the amorphous Ba(NO3)2 layer into crystalline Ba(NO3)2 particles in the temperature range of 500 600 K. No phase transformation is observed in samples with ?BaO < 1 ML.

Yi, Cheol-Woo W.; Szanyi, Janos

2009-01-15T23:59:59.000Z

352

Recent VOC Control Test Data for a Reactive VOC Converter- Scrubber System for Non-Thermal Control of VOCs  

E-Print Network [OSTI]

of real estate. Non-thermal VOHAP (Volatile Organic Hazardous Air Pollutant) emission control devices require additional maintenance. They also require the replacement of costly consumables such as activated carbon or they use large amounts of energy...

McGinness, M.

353

Movement of VOCs through the vadose zone  

E-Print Network [OSTI]

were classified into steady-state and transient methods. In the first type, difFusion coefficients were determined under steady state conditions. The second type was categorized into open tube (OTM) and closed tube methods (CTM), both measuring dif...Fusion coeflicient in the transient state. In the OTM, one end of the difFusion chamber was open to the atmosphere or to a continuous source. The CTM had the soil medium open at the end chambers but the whole system was isolated from the atmosphere. CTM gave...

Patel, Pinakin K.

1989-01-01T23:59:59.000Z

354

Membrane applications to control VOC emissions  

SciTech Connect (OSTI)

A thin film composite membrane to separate and recover organic vapors is briefly described. The membrane is designed for end of pipe installation with a separation efficiency of greater than 90%. The main components of the membrane system are feed compressor, vacuum pump, and membrane modules. The paper focuses on operating characteristics of the membrane, and provides data on various ideal selectivities for organics; dependence of toluene/nitrogen selectivity and stage cut on flow velocity; and dependence of plant capacity, recovery rate, pressure ratio, stage cut, retentate concentration, and specific energy consumption on membrane area for gasoline vapor separation process conditions. 5 refs., 6 figs., 1 tab.

Ohlrogge, K.; Wind, J. [GKSS Research Center, Geesthacht (Germany)

1996-12-31T23:59:59.000Z

355

Brayton Cycle Heat Pump for VOC Control  

E-Print Network [OSTI]

of this technology is particularly suitable for recovery of CFCs, water miscible solvents, and halogenated hydrocarbons. The process can be directly or indirectly coupled to various adsorbent based solvent concentrators....

Kovach, J. L.

356

Pilot tests guide VOC control choice  

SciTech Connect (OSTI)

On-site pilot testing determines proper operating conditions for catalysts of pollution control equipment at optimum performance levels while demonstrating their ability to reduce emissions, odors and opacity from stack gases in manufacturing processes. Examples are provided ofr the catalytic control of emissions from coffee roasting, carbon fiber manufacturing, and can coating. Portable oxidizer units are employed in the pilot testing.

Van Benschoten, D.M. [Johnson Matthey Environmental Products, Wayne, PA (United States)

1993-10-01T23:59:59.000Z

357

8, 1182111851, 2008 VOCs during 2006  

E-Print Network [OSTI]

, Texas 77843, TX, USA 2 Molina Center for Energy and the Environment, La Jolla, California, CA, USA * now Northeast of downtown Mexico City as part of the Megacity Initiative ­ Local and Global Research the probability of significant industrial sources of the two compounds in the15 region. Wind fields during those

Boyer, Edmond

358

Atmospheric pressure gas plasma-induced colorectal cancer cell death is mediated by Nox2ASK1 apoptosis pathways and oxidative stress is mitigated by SrxNrf2 anti-oxidant system  

Science Journals Connector (OSTI)

Abstract Atmospheric pressure gas plasma (AGP) generates reactive oxygen species (ROS) that induce apoptosis in cultured cancer cells. The majority of cancer cells develop a ROS-scavenging anti-oxidant system regulated by Nrf2, which confers resistance to ROS-mediated cancer cell death. Generation of ROS is involved in the AGP-induced cancer cell death of several colorectal cancer cells (Caco2, HCT116 and SW480) by activation of ASK1-mediated apoptosis signaling pathway without affecting control cells (human colonic sub-epithelial myofibroblasts; CO18, human fetal lung fibroblast; MRC5 and fetal human colon; FHC). However, the identity of an oxidase participating in AGP-induced cancer cell death is unknown. Here, we report that AGP up-regulates the expression of Nox2 (NADPH oxidase) to produce ROS. RNA interference designed to target Nox2 effectively inhibits the AGP-induced ROS production and cancer cell death. In some cases both colorectal cancer HT29 and control cells showed resistance to AGP treatment. Compared to AGP-sensitive Caco2 cells, HT29 cells show a higher basal level of the anti-oxidant system transcriptional regulator Nrf2 and its target protein sulfiredoxin (Srx) which are involved in cellular redox homeostasis. Silencing of both Nrf2 and Srx sensitized HT29 cells, leads to ROS overproduction and decreased cell viability. This indicates that in HT29 cells, Nrf2/Srx axis is a protective factor against AGP-induced oxidative stress. The inhibition of Nrf2/Srx signaling should be considered as a central target in drug-resistant colorectal cancer treatments.

Musarat Ishaq; Margaret D.M. Evans; Kostya (Ken) Ostrikov

2014-01-01T23:59:59.000Z

359

Oxygen Diffusion (OD) Dramatically Improves Wear-Resistance of Titanium  

Broader source: Energy.gov [DOE]

2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER 2007). 13-16 August, 2007, Detroit, Michigan. Sponsored by the U.S. Department of Energy's (DOE) Office of FreedomCAR and Vehicle Technologies (OFCVT).

360

OD3P: On-Demand Page Paired PCM  

Science Journals Connector (OSTI)

With current memory scalability challenges, Phase Change Memory (PCM) is viewed as an attractive replacement to DRAM. The preliminary concern for PCM applicability is its limited write endurance that is highly affected by process variation in nanometer ... Keywords: Lifetime, Page Pairing

Marjan Asadinia, Mohammad Arjomand, Hamid Sarbazi-Azad

2014-06-01T23:59:59.000Z

Note: This page contains sample records for the topic "nox ods voc" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

NARSTO OZONE ASSESSMENT EXECUTIVE SUMMARY  

E-Print Network [OSTI]

. Atmospheric scientists examine O3 production and transport through measurements, analysis, and the application Canada, the United States, and Mexico. Although policy recommendations are not within the purview organic compounds (VOCs) and nitrogen oxides (NOx ) are exposed to sunlight. Since the emissions

362

A Midwest Regional Inventory of Heavy-Duty Diesel Vehicle Emissions  

E-Print Network [OSTI]

A Midwest Regional Inventory of Heavy-Duty Diesel Vehicle Emissions by Christopher D. Dresser OF WISCONSIN - MADISON Abstract A Midwest Regional Inventory of Heavy-Duty Diesel Vehicle Emissions Christopher Studies This study presents a "bottom-up" emissions inventory for NOx, PM2.5, SO2, CO, and VOCs from heavy

Wisconsin at Madison, University of

363

Impact of realistic hourly emissions profiles on air pollutants concentrations modelled with CHIMERE  

E-Print Network [OSTI]

Impact of realistic hourly emissions profiles on air pollutants concentrations modelled Keywords: Atmospheric composition European air quality Anthropogenic emissions a b s t r a c t Regional inputs data like anthropogenic surface emissions of NOx, VOCs and particulate matter. These emissions

Menut, Laurent

364

Air Quality Conformity G.C. Sciara  

E-Print Network [OSTI]

) · Nitrogen Dioxide (NO2) · Ozone (O3) ­ Volatile Organic Compounds (VOC) ­ Oxides of Nitrogen (NOX) · Oxides disease · Contributes to 80,000 premature deaths/year in CA #12;U.S. Sources of Oxides of Nitrogen EPA

Handy, Susan L.

365

Atmos. Chem. Phys., 11, 1136111386, 2011 www.atmos-chem-phys.net/11/11361/2011/  

E-Print Network [OSTI]

. Trainer2, A. Richter3, W. M. Angevine1,2, E. Atlas4, L. Bianco1,2, K. F. Boersma5,6, J. Brioude1,2, J. P) columns and airborne in-situ obser- vations of several trace gases including NOx and a num- ber of VOCs

Stoffelen, Ad

366

Aerosol optical and hygroscopic properties during TexAQS-GoMACCS 2006 and their impact on aerosol  

E-Print Network [OSTI]

by diesel-fueled mobile sources and from the numerous coal- fired industries and power generation stations August thru 11 September 2006) with a number of gas and aerosol instru- ments deployed to measure air and power plants, with emissions rich in reactive volatile organic compounds (VOCs) and NOX [Ryerson et al

367

Using Local and Regional Air Quality Modeling and Source Apportionment Tools to Evaluate Vehicles and Biogenic Emission Factors  

E-Print Network [OSTI]

and inventories of CO, NO_(x) and VOCs from on-road vehicles estimated by vehicle emission factor models and biogenic emissions of isoprene estimated by a popular biogenic emission model are evaluated using local and regional scale air quality modeling and source...

Kota, Sri H

2014-07-25T23:59:59.000Z

368

Air Quality Standards & ATOC/CHEM 5151  

E-Print Network [OSTI]

1 Lecture 22 Air Quality Standards & Control ATOC/CHEM 5151 #12;2 Primary Pollutants Things to reduce air pollution emissions ­ Latest version ­ 1990 (original, 1963) ­ What is an "air pollutant that are directly emitted Nitrogen Oxides (NOx) Hydrocarbons (VOCs) Carbon Monoxide (CO) #12;3 Secondary Pollutants

Toohey, Darin W.

369

NOxControl revised.p65  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

OCTOBER 2001 OCTOBER 2001 DOE/FE-0442 EVALUATION OF GAS REBURNING AND LOW-NO X BURNERS ON A WALL-FIRED BOILER ENERGY AND ENVIRONMENTAL RESEARCH CORPORATION Disclaimer This report was prepared using publicly available information, including the Final Technical Report and other reports prepared pursuant to a cooperative agreement partially funded by the U.S. Department of Energy. Neither the United States Government nor any agency, employee, contractor, or representative thereof, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe upon privately owned rights. Reference herein to any specific commercial

370

Microsoft Word - netl NOx paper 0398.doc  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Overview of NO Overview of NO x Control Technologies Demonstrated under the Department of Energy's Clean Coal Technology Program J.U. Watts U.S. Department of Energy, Federal Energy Technology Center P.O. Box 10940, Pittsburgh PA 15236 A.N. Mann and D.L. Russell, Sr. Burns and Roe Services Corporation P.O. Box 18288, Pittsburgh PA 15236 ABSTRACT The Clean Coal Technology (CCT) Demonstration Program, sponsored by the U. S. Department of Energy (DOE), is a government and industry co-funded technology development effort to demonstrate a new generation of innovative coal utilization processes. The CCT Program began in 1987 and will continue through the year 2000. The purpose of the Program is to remove the economic and environmental impediments associated with the development and demonstration of

371

Leadership in Low NOx/ Lochinvar Corporation  

E-Print Network [OSTI]

.lochinvar.com. What does clean air mean to you? Do you have children? Do your children have allergies or asthma? Perhaps you or someone you know struggles with emphysema? The fact is, pol1uted air has a big effect on our children, the elderly and even healthy... yield of agricultural crops; poor air quality can have a negative effect on those yields. In a recently displayed photograph of downtown Dallas, a fairly distinct view of Dallas's downtown skyline could be seen. The interesting thing about...

Sheko, D.; Boston, S.; Moore, J.

372

Measurement and Characterization of NOx Adsorber Regeneration...  

Broader source: Energy.gov (indexed) [DOE]

West, Bill Partridge, Sam Lewis, Dean Edwards, Katey Lenox, Jae-Soon Choi, Todd Toops Oak Ridge National Laboratory Fuels, Engines and Emissions Research Center feerc.ornl.gov...

373

Electrochemical NOx Sensor for Monitoring Diesel Emissions  

Broader source: Energy.gov (indexed) [DOE]

fuel economy - Completely compatible with biodiesel Estimate diesel light-vehicle penetration to increase from 3% (2007) to 14% by 2017 * Problem: Diesel technology is...

374

Further improvement of conventional diesel NOx aftertreatment...  

Broader source: Energy.gov (indexed) [DOE]

, Kolbeck Andreas, Korfer Thomas Wittka Thomas, Schnorbus Thorsten FEV GmbH Aachen, Germany 2011 DEER conference, Detroit, MI, USA by FEV - all rights reserved. Confidential...

375

Bringing the Low NOx Diesel Under Control  

Broader source: Energy.gov [DOE]

Presentation given at DEER 2006, August 20-24, 2006, Detroit, Michigan. Sponsored by the U.S. DOE's EERE FreedomCar and Fuel Partnership and 21st Century Truck Programs.

376

OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL  

SciTech Connect (OSTI)

This quarterly technical progress report will summarize work accomplished for the Program through the second quarter July--September 2000 in the following task areas: Task 1-Oxygen Enhanced Combustion, Task 2-Oxygen Transport Membranes and Task 4-Program Management. The program is proceeding in accordance with the objectives for the first year. OTM tube characterization is well underway, the design and assembly of the high pressure permeation test facility is complete and the facility will be in full operation during the next quarter. Combustion testing has been initiated at both the University of Arizona and Praxair. Testing at the University of Arizona has experienced some delays; steps have been take to get the test work back on schedule. Completion of the first phase of the testing is expected in next quarter. Combustion modeling has been started at both REI and Praxair, preliminary results are expected in the next quarter.

Lawrence E. Bool; Jack C. Chen; David R. Thompson

2000-10-01T23:59:59.000Z

377

OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL  

SciTech Connect (OSTI)

Increased environmental regulations will require utility boilers to reduce NO{sub x} emissions to less than 0.15lb/MMBtu in the near term. Conventional technologies such as Selective Catalytic Reduction (SCR) and Selective Non-Catalytic Reduction (SNCR) are unable to achieve these lowered emission levels without substantially higher costs and major operating problems. Oxygen enhanced combustion is a novel technology that allows utilities to meet the NO{sub x} emission requirements without the operational problems that occur with SCR and SNCR. Furthermore, oxygen enhanced combustion can achieve these NO{sub x} limits at costs lower than conventional technologies. The objective of this program is to demonstrate the use of oxygen enhanced combustion as a technical and economical method of meeting the EPA State Implementation Plan for NO{sub x} reduction to less than 0.15lb/MMBtu for a wide range of boilers and coal. The oxygen enhanced coal combustion program (Task 1) focused this quarter on the specific objective of exploration of the impact of oxygen enrichment on NO{sub x} formation utilizing small-scale combustors for parametric testing. Research efforts toward understanding any limitations to the applicability of the technology to different burners and fuels such as different types of coal are underway. The objective of the oxygen transport membrane (OTM) materials development program (Task 2.1) is to ascertain a suitable material composition that can be fabricated into dense tubes capable of producing the target oxygen flux under the operating conditions. This requires that the material have sufficient oxygen permeation resulting from high oxygen ion conductivity, high electronic conductivity and high oxygen surface exchange rate. The OTM element development program (Task 2.2) objective is to develop, fabricate and characterize OTM elements for laboratory and pilot reactors utilizing quality control parameters to ensure reproducibility and superior performance. A specific goal is to achieve a material that will sinter to desired density without compromising other variables such as reaction to binder systems or phase purity. Oxygen-enhanced combustion requires a facility which is capable of supplying high purity oxygen (>99.5%) at low costs. This goal can be achieved through the thermal integration of high temperature air separation with ceramic OTM. The objective of the OTM process development program (Task 2.3) is to demonstrate successfully the program objectives on a lab-scale single OTM tube reactor under process conditions comparable to those of an optimum large-scale oxygen facility. This quarterly technical progress report will summarize work accomplished for the Program through the first quarter April--June 2000 in the following task areas: Task 1 Oxygen Enhanced Coal Combustion; Task 2 Oxygen Transport Membranes; and Task 4 Program Management.

Lawrence E. Bool; Jack C. Chen; David R. Thompson

2000-07-01T23:59:59.000Z

378

OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL  

SciTech Connect (OSTI)

This quarterly technical progress report will summarize work accomplished for the Program through the eleventh quarter, October-December 2002, in the following task areas: Task 1 - Oxygen Enhanced Combustion, Task 2 - Oxygen Transport Membranes, Task 3 - Economic Evaluation and Task 4 - Program Management. The program is proceeding in accordance with the objectives for the third year. Pilot scale experiments conducted at the University of Utah were aimed at confirming the importance of oxygen injection strategy for different types of burners. CFD modeling at REI was used to better understand the potential for increased corrosion under oxygen enhanced combustion conditions. Data from a full-scale demonstration test in Springfield, MO were analyzed. OTM element development continued with preliminary investigation of an alternative method of fabrication of PSO1d elements. OTM process development continued with long-term testing of a PSO1d element. Economic evaluation has confirmed the advantage of oxygen-enhanced combustion. Proposals have been submitted for two additional beta test sites. A first commercial proposal has been submitted. Economic analysis of a beta site test performance was conducted.

David R. Thompson; Lawrence E. Bool; Jack C. Chen

2003-02-01T23:59:59.000Z

379

Further improvement of conventional diesel NOx aftertreatment...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

More Documents & Publications Future Directions in Engines and Fuels Diesel Passenger Car Technology for Low Emissions and CO2 Compliance A View from the Bridge...

380

New Houston NOx Rules: Implications and Solutions  

E-Print Network [OSTI]

include utility and boilers, boilers and furnaces in petrochemical plants, other chemical facilities, and petroleum refineries, IPPs and cogenerators, pipeline turbine compressors, and other stationary IC engines. The regulations will affect... such stationary sources as boilers (gas, coke, wood, oil, gas and biomass-fired), process heaters, stationary engines, industrial furnaces, lime kilns, metallurgical furnaces, FCCs, utility boilers, gas turbine IPPs and cogenerators, and process incinerators...

Cascone, R.

Note: This page contains sample records for the topic "nox ods voc" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Nox reduction system utilizing pulsed hydrocarbon injection  

DOE Patents [OSTI]

Hydrocarbon co-reductants, such as diesel fuel, are added by pulsed injection to internal combustion engine exhaust to reduce exhaust NO.sub.x to N.sub.2 in the presence of a catalyst. Exhaust NO.sub.x reduction of at least 50% in the emissions is achieved with the addition of less than 5% fuel as a source of the hydrocarbon co-reductants. By means of pulsing the hydrocarbon flow, the amount of pulsed hydrocarbon vapor (itself a pollutant) can be minimized relative to the amount of NO.sub.x species removed.

Brusasco, Raymond M. (Livermore, CA); Penetrante, Bernardino M. (San Ramon, CA); Vogtlin, George E. (Fremont, CA); Merritt, Bernard T. (Livermore, CA)

2001-01-01T23:59:59.000Z

382

Brookhaven National Laboratory - OU V VOC | Department of Energy  

Office of Environmental Management (EM)

monitored natural attenuation program. Remedy contained in ROD for OU V Area of concern (AOC) 4, 21, and 23. Cleanup goals have been achieved by MNA. Post cleanup monitoring has...

383

Upgrading the performance of groudwater VOC air strippers  

SciTech Connect (OSTI)

Rocketdynes Santa Susana Field Laboratory has been treating groundwater to remove chlorinated solvents since 1987. Six air stripping treatment installations, using vapor-phase carbon to control air emissions, have consistently met effluent quality standards over nine years of operation. In 1995, Rocketdyne embarked on an inspection and maintenance program to thoroughly check tower equipment and packing condition and to improve treatment efficiency using new packing technology now available. Baseline removal efficiency measurements were made on one large-capacity air stripper, which was then shut down for inspection. The original random packing was found to be fouled, and had settled too far below the level of the spray nozzle. The packing was removed, and replaced with a newer, high-efficiency packing. As a result, single-stage removal efficiency for trichloroethylene increased from 98.5% to > 99.60%. Aside from demonstrating the improvement attainable by upgrading the packing media, Rocketdyne`s maintenance program also highlighted the critical importance of proper liquid distribution. At one point, the refurbished air stripper was overpacked, resulting in concentration of the water spray near the center of the packed section. The liquid distribution was found to remain grossly nonuniform even after the water had trickled down over 8.2 meters of packing in a 91-cm diameter column. 4 refs., 1 fig., 5 tabs.

Nelson, A.D. [Rockwell International Corp., Canoga Park, CA (United States); Schmitt, R.J. [EnviroSolve Corp., Agoura Hills, CA (United States); Dickeson, D. [Lantec Products, Inc., Agoura Hills, CA (United States)

1997-12-31T23:59:59.000Z

384

Process Development for High Voc CdTe Solar Cells  

SciTech Connect (OSTI)

This is a cumulative and final report for Phases I, II and III of this NREL funded project (subcontract # XXL-5-44205-10). The main research activities of this project focused on the open-circuit voltage of the CdTe thin film solar cells. Although, thin film CdTe continues to be one of the leading materials for large-scale cost-effective production of photovoltaics, the efficiency of the CdTe solar cells have been stagnant for the last few years. This report describes and summarizes the results for this 3-year research project.

Ferekides, C. S.; Morel, D. L.

2011-05-01T23:59:59.000Z

385

Application of solar photocatalytic oxidation to VOC-containing airstreams  

SciTech Connect (OSTI)

Researchers from the National Renewable Energy Laboratory (NREL) recently conducted two pilot-scale field tests located at McClellan Air Force Base (AFB) in Sacramento, California and at the Fort Carson US Army Installation in Colorado Springs, Colorado. The objective of the tests was to determine the effectiveness of solar-powered photocatalytic oxidation (PCO) treatment units for destroying emissions of chlorinated organic compounds (trichloroethylene and dichloroethylenes) from an air stripper at ambient temperature and destroying paint solvent emissions (toluene and MEK) from a painting facility at higher temperatures. Their goals for field testing these solar-driven systems was to gather real-world treatability data and establish that the systems maintained performance during the duration of the testing. This paper reports the results of these field tests.

Magrini, K.A.; Watt, A.S.; Boyd, L.C.; Wolfrum, E.J.; Larson, S.A.; Roth, C.; Glatzmaier, G.C.

1999-07-01T23:59:59.000Z

386

A Novel New Approach to VOC and HAP Emission Control  

E-Print Network [OSTI]

of real estate. Non-thermal VOHAP (Volatile Organic Hazardous Air Pollutant) emission control devices require additional maintenance. They also require the replacement of costly consumables such as activated carbon or they use large amounts of energy...

McGinness, M.

387

Brookhaven National Laboratory - OU III VOC | Department of Energy  

Office of Environmental Management (EM)

Driver Cleanup Requirement CCI4 64 Yes 5 Chloroform 19 Yes 5 DCA 12 Yes 5 DCE 77 Yes 5 PCE 1000 Yes 5 TCS 87 Yes 5 freon 450 (ppm) 5 Fuel Present? No Metals Present? Yes Isotopes...

388

Brookhaven National Laboratory - OU I/IV VOC | Department of...  

Office of Environmental Management (EM)

and only post closure monitoring of several wells continues in this area. The Strontium 90 plume is several acres and concentrations still remain above cleanup goals. Basis...

389

Environmental Impact on Applied Technology- Global Warming CFCs & VOCs  

E-Print Network [OSTI]

Fuel Oil -3299 -3093 -2834 Coal -4545 -4338 -4079 Wood Waste -5232 -5025 -4766 Coping With Environmental Pressures The textile finishing industry, pulp and paper and thers rejecting large quantities of warm water are undegoing increased... Fuel Oil -3299 -3093 -2834 Coal -4545 -4338 -4079 Wood Waste -5232 -5025 -4766 Coping With Environmental Pressures The textile finishing industry, pulp and paper and thers rejecting large quantities of warm water are undegoing increased...

Gilbert, J. S.

390

Chapter 10 - Regenerative catalytic oxidizer technology for VOC control  

Science Journals Connector (OSTI)

Publisher Summary The regenerative catalytic oxidizer (RCO) technology has evolved significantly as an efficient method to control volatile organic compounds. The RCO technology favors using oxide catalysts because it allows for easy compensation of lower activity by an increase in the catalyst amount or temperature. Heat transfer and accumulation properties of ceramic packing material strongly influence RCO performance. The rate of heat transfer affects the temperature gradients along the bed length that, in turn, determine the volume of material required to preheat the gas to the temperature of catalytic or thermal oxidation. During the catalyst operation, it gradually becomes less active and must be eventually replaced. The factors affecting the catalyst lifetime include high temperature, catalytic poisons, and masking agents. Compounds of halogens and sulfur are the most common catalyst poisons. Temperature control, poison tolerant catalysts, and gas-flow pretreatment are used to reduce the impact of catalyst deactivation. This chapter also presents the behavior of an RCO when the catalyst deactivates, and proposes strategies ensuring the required performance during the entire catalyst lifetime.

V.O. Strots; G.A. Bunimovich; C.R. Roach; Yu.Sh. Matros

2000-01-01T23:59:59.000Z

391

NMED COMMENTS ITEM 3 REVISE VOLATILE ORGANIC COMPOUND (VOC) TARGET...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

to the target list or not, according to proposed language in Permit Attachment N. If a TIC is determined to contribute more than one percent of the risk, then it will be added to...

392

Brookhaven National Laboratory - OU VI VOC | Department of Energy  

Office of Environmental Management (EM)

Present? No Contaminant Concentration (ppb) Regulatory Driver Cleanup Requirement ethylene dibromide 2.3 Yes 0.05 Hydrogeology Conduit Flow? No Depth (feet): 100 Mulitple Units...

393

Brookhaven National Laboratory - OU I VOC | Department of Energy  

Office of Environmental Management (EM)

Migration Under Control? Yes Current Human Exposure Acceptable? Yes Confirmed by Lead Regulator? Yes Confirmed by Lead Regulator? Yes Regulatory Decision Document Status? Decision...

394

NOx Adsorber (Lean NOx Trap) Fundamentals (Agreement #10049- PNNL Project #47120)  

Broader source: Energy.gov [DOE]

Presentation from the U.S. DOE Office of Vehicle Technologies "Mega" Merit Review 2008 on February 25, 2008 in Bethesda, Maryland.

395

Establishing Policy Relevant Background (PRB) Ozone Concentrations in the United States  

Science Journals Connector (OSTI)

National Oceanic and Atmospheric Administration, Boulder, Colorado ... Processes that contribute to PRB ozone concentrations include photochemistry associated with natural emissions of volatile organic compounds (VOCs), nitrogen oxides (NOx), and carbon monoxide (CO) from sources such as biogenic emissions (not including agricultural activities), wildfires, lightning, the long-range transport of ozone and its precursors from outside of North America, and stratospheric-tropospheric exchange (STE) of ozone. ... Models generally find little ozone production in wildfire plumes for short aging times (days) because NOx emissions are low and conversion to peroxyacetylnitrate (PAN) is rapid. ...

Elena C. McDonald-Buller; David T Allen; Nancy Brown; Daniel J. Jacob; Daniel Jaffe; Charles E. Kolb; Allen S. Lefohn; Samuel Oltmans; David D. Parrish; Greg Yarwood; Lin Zhang

2011-10-10T23:59:59.000Z

396

Sensitivity Analysis of Ozone Formation and Transport for a Central  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Sensitivity Analysis of Ozone Formation and Transport for a Central Sensitivity Analysis of Ozone Formation and Transport for a Central California Air Pollution Episode Title Sensitivity Analysis of Ozone Formation and Transport for a Central California Air Pollution Episode Publication Type Journal Article Year of Publication 2008 Authors Jin, Ling, Shaheen R. Tonse, Daniel S. Cohan, Xianglei Mao, Robert A. Harley, and Nancy J. Brown Journal Environmental Science & Technology Volume 42 Start Page 3683 Issue 10 Pagination 3683-3689 Date Published 05/2008 Abstract We developed a first- and second-order sensitivity analysis approach with the decoupled direct method to examine spatial and temporal variations of ozone-limiting reagents and the importance of local vs upwind emission sources in the San Joaquin Valley of central California for a 5 day ozone episode (Jul 29th to Aug 3rd, 2000). Despite considerable spatial variations, nitrogen oxides (NOx) emission reductions are overall more effective than volatile organic compound (VOC) control for attaining the 8 h ozone standard in this region for this episode, in contrast to the VOC control that works better for attaining the prior 1 h ozone standard. Interbasin source contributions of NOx emissions are limited to the northern part of the SJV, while anthropogenic VOC (AVOC) emissions, especially those emitted at night, influence ozone formation in the SJV further downwind. Among model input parameters studied here, uncertainties in emissions of NOx and AVOC, and the rate coefficient of the OH + NO2 termination reaction, have the greatest effect on first-order ozone responses to changes in NOx emissions. Uncertainties in biogenic VOC emissions only have a modest effect because they are generally not collocated with anthropogenic sources in this region.

397

Regenerative catalytic oxidation  

SciTech Connect (OSTI)

Currently Regenerative Thermal Oxidizers (R.T.O.`s) are an accepted technology for the control of volatile organic compounds (VOC`s) and hazardous air pollutants (HAP`s). This control technology, when introduced, offered substantial reductions in operating costs, especially auxiliary fuel requirements when compared to existing control technologies such as recuperative thermal and recuperative catalytic oxidizers. While these savings still exist, there is a demand for control of new and/or hybrid technologies, one of which is Regenerative Catalytic Oxidizers (R.C.O.`s). This paper will explore the development of regenerative catalytic oxidation from the theoretical stage through pilot testing through a commercial installation. The operating cost of R.C.O.`s will be compared to R.T.O.`s to verify the savings that are achievable through the use of regenerative catalytic oxidation. In the development of this technology, which is a combination of two (2) existing technologies, R.T.O.`s and catalysis, a second hybrid technology was explored and pilot tested. This is a combination R.C.O. for VOC and HAP control and simultaneous SCR (Selective Catalytic Reduction) for NOx (Oxides of Nitrogen) control. Based on the pilot and full scale testing, both regenerative catalytic oxidizers and systems which combine R.C.O. with SCR for both VOC and NOx reduction are economically viable and are in fact commercially available. 6 figs., 2 tabs.

Gribbon, S.T. [Engelhard Process Emission Systems, South Lyon, MI (United States)

1996-12-31T23:59:59.000Z

398

Measurement of the rotational distribution for the OD product from the reaction ND3 D2O~ND4 OD under translationally thermal conditions  

E-Print Network [OSTI]

laser-induced fluorescence spectrum on the 1,1 band following excitation of the 1,0 band. Rotational by coupling resonance-enhanced multiphoton ion- ization REMPI to laser-induced fluorescence LIF in a bulb has

Zare, Richard N.

399

Advanced NOx Emissions Control: Control Technology - SCR Catalyst Blinding  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

SCR Catalyst Blinding SCR Catalyst Blinding University of North Dakota Energy and Environmental Research Center (UND-EERC) is determining the potential of low-rank coal ash to cause blinding or masking of selective catalytic reduction (SCR) catalysts. A secondary goal will be to determine the degree of elemental mercury conversion across the catalysts. Specific objectives include (1) identify candidate coals and blends for testing under bench-scale conditions, (2) conduct bench-scale testing to screen coals and identify key conditions for full-scale testing, (3) design and construct an SCR slipstream test chamber for sampling at full-scale facilities, (4) conduct testing at full-scale testing, (5) identify SCR blinding mechanisms, rates, and cleaning methods as well as mercury conversion efficiencies, and (6) interpret data, prepare a report, and attend sponsor meetings to present information and recommendations.

400

NETL: Emissions Characterization - Adv. Low-NOx Burner Emissions  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Characterization of Fine Particulate Emissions using Subcritical Water Characterization of Fine Particulate Emissions using Subcritical Water As part of a Cooperative Agreement with DOE-NETL, the University of North Dakota Energy and Environmental Research Center (EERC) is developing advanced sampling and analysis methodologies for particulate matter that can be used for source apportionment and to assist in health studies. These techniques will be used to determine sources of fine particulate matter in rural states such as North Dakota. One of the primary activities of this effort is the development of a procedure using subcritical water to fractionate organics in air particulates, and test the toxicity of the fractionated organics using various tests. In contrast to inorganic aerosols, which are often well characterized, only ca. 15%–50% of the organic carbonaceous (OC) particulate mass has been characterized. The characterized compounds are almost exclusively nonpolar. The limited knowledge on OC fractions is due to the use of organic solvents which are able to extract only nonpolar or slightly polar organics. Subcritical water has not previously been used to fractionate OC from air particulates, but should have the ability to extract a broad range of polar to low-polarity OC, as well as to provide extracts in a solvent (water) which is directly useful for biological tests. Earlier studies have shown that compounds of different polarities, such as phenols, PAHs, and alkanes, can be sequentially extracted from a petroleum waste sludge by increases in subcritical water temperature.

Note: This page contains sample records for the topic "nox ods voc" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

NOx CONTROL OPTIONS AND INTEGRATION FOR US COAL FIRED BOILERS  

SciTech Connect (OSTI)

This is the tenth Quarterly Technical Report for DOE Cooperative Agreement No: DE-FC26-00NT40753. The goal of the project is to develop cost effective analysis tools and techniques for demonstrating and evaluating low NO{sub x} control strategies and their possible impact on boiler performance for firing US coals. The Electric Power Research Institute (EPRI) is providing cofunding for this program. This program contains multiple tasks and good progress is being made on all fronts. During this quarter, progress was made on the computational simulation of a full-scale boiler with the purpose of understanding the potential impacts of burner operating conditions on soot and NO{sub x} generation. Sulfation tests on both the titania support and vanadia/titania catalysts were completed using BYU's in situ spectroscopy reactor this quarter. These experiments focus on the extent to which vanadia and titania sulfate in an SO{sub 2}-laden, moist environment. Construction of the CCS reactor system is essentially complete and the control hardware and software are largely in place. A large batch of vanadia/titania catalyst in powder form has been prepared for use in poisoning tests. During this quarter, minor modifications were made to the multi-catalyst slipstream reactor and to the control system. The slipstream reactor was installed at AEP's Rockport plant at the end of November 2002. In this report, we describe the reactor system, particularly the control system, which was created by REI specifically for the reactor, as well as the installation at Rockport.

Mike Bockelie; Marc Cremer; Kevin Davis; Temi Linjewile; Connie Senior; Hong-Shig Shim; Bob Hurt; Eric Eddings; Larry Baxter

2003-01-30T23:59:59.000Z

402

Computer simulation as a NOx reduction design tool  

SciTech Connect (OSTI)

Nalco Mobotec engineers were charged with reducing emissions on a utility boiler converted from burning oil to eastern bituminous coal using the company's Rotamix selective noncatalytic reduction (SNCR) system which injects urea into the furnace. A CFD simulation of the existing boiler was first conducted and then the furnace was simulated with the SNCR system added and the design was optimised. Operating and capital costs were minimised by optimal placement of 50 injector ports. 6 figs., 2 tabs.

Liu, G.; Higgins, B.S. [Nalco Mobotec (United States)

2008-10-15T23:59:59.000Z

403

METHANE de-NOX FOR UTILITY PC BOILERS  

SciTech Connect (OSTI)

The overall project objective is the development and validation of an innovative combustion system, based on a novel coal preheating concept prior to combustion, that can reduce NO{sub x} emissions to 0.15 lb/million Btu or less on utility pulverized coal (PC) boilers. This NO{sub x} reduction should be achieved without loss of boiler efficiency or operating stability, and at more than 25% lower levelized cost than state-of-the-art SCR technology. A further objective is to make this technology ready for full-scale commercial deployment by 2002-2003 in order to meet an anticipated market demand for NO{sub x} reduction technologies resulting from the EPA's NO{sub x} SIP call.

Joseph Rabovitser

2000-07-05T23:59:59.000Z

404

NOx Control Options and Integration for US Coal Fired Boilers  

SciTech Connect (OSTI)

This is the twentieth Quarterly Technical Report for DOE Cooperative Agreement No: DEFC26-00NT40753. The goal of the project is to develop cost-effective analysis tools and techniques for demonstrating and evaluating low-NO{sub x} control strategies and their possible impact on boiler performance for boilers firing US coals. The Electric Power Research Institute (EPRI) is providing co-funding for this program. At the beginning of this quarter, the corrosion probes were removed from Gavin Station. Data analysis and preparation of the final report continued this quarter. This quarterly report includes further results from the BYU catalyst characterization lab and the in-situ FTIR lab, and includes the first results from tests run on samples cut from the commercial plate catalysts. The SCR slipstream reactor at Plant Gadsden was removed from the plant, where the total exposure time on flue gas was 350 hours. A computational framework for SCR deactivation was added to the SCR model.

Mike Bockelie; Kevin Davis; Martin Denison; Connie Senior; Hong-Shig Shim; Darren Shino; Dave Swenson; Larry Baxter; Calvin Bartholomew; William Hecker

2005-06-30T23:59:59.000Z

405

Selectlive Catalytic Reducution of NOx wilth Diesel-Based Fuels...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

of NO by Hydrocarbons Bifunctional Catalysts for the Selective Catalytic Reduction of NO by Hydrocarbons Progress on Acidic Zirconia Mixed Oxides for Efficient NH3-SCR Catalysis...

406

An Improvement of Diesel PM and NOx Reduction System | Department...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Presentation given at the 2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER 2007). 13-16 August, 2007, Detroit, Michigan. Sponsored by the U.S. Department of...

407

Micronized Coal Reburning Demonstration for NOx Control: A DOE Assessment  

SciTech Connect (OSTI)

The goal of the U.S. Department of Energy's (DOE) Clean Coal Technology (CCT) program is to furnish the energy marketplace with a number of advanced, more efficient, and environmentally responsible coal utilization technologies through demonstration projects. These projects seek to establish the commercial feasibility of the most promising advanced coal technologies that have developed beyond the proof-of-concept stage. This document serves as a DOE post-project assessment of a project selected in CCT Round IV, the Micronized Coal Reburning (MCR) Demonstration for NO{sub x} Control, as described in a report to Congress (U.S. Department of Energy 1999). The need to meet strict emissions requirements at a minimum cost prompted the Tennessee Valley Authority (TVA), in conjunction with Fuller Company, Energy and Environmental Research Corporation (EER), and Fluor Daniel, to submit the proposal for this project to be sited at TVA's Shawnee Fossil Plant. In July 1992, TVA entered into a cooperative agreement with DOE to conduct the study. However, because of operational and environmental compliance strategy changes, the Shawnee site became unavailable.

National Energy Technology Laboratory

2001-08-15T23:59:59.000Z

408

Development of Chemical Kinetic Models for Lean NOx Traps  

Broader source: Energy.gov [DOE]

2011 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation

409

Measurement and Characterization of Lean NOx Adsorber Regeneration...  

Broader source: Energy.gov (indexed) [DOE]

(Multimode): 250k * Barriers - Emissions regulations for advanced lean engine market penetration * Partners - Catalyst Suppliers * Manufacturers of Emissions Controls...

410

Cummins/ORNL-FEERC CRADA: NOx Control & Measurement Technology...  

Broader source: Energy.gov (indexed) [DOE]

of Energy Purpose of Work Assist Cummins in addressing barriers to transportation-market penetration of fuel-efficient diesel engines & by doing so generate useful knowledge and...

411

Low NOx firing technology of Mitsubishi Heavy Industries  

SciTech Connect (OSTI)

This paper presents super low NO{sub x} combustion technologies successfully developed by MHI (Mitsubishi Heavy Industries, Ltd.) and its use in practice. PM (Pollution Minimum) burners directly reduce NO{sub x} from the burners themselves and MACT (Mitsubishi Advanced Combustion Technology) system, an in-furnace NO{sub x} removal system, reduces NO{sub x} generated from the main burners within the boiler. These firing systems are applicable to coal, oil, gas and also to other exotic fuels like Orimulsion or CWM (Coal Water Mixture). MRS (Mitsubishi Rotary Separator) mills minimizes unburnt carbon with its reliable ultra-fine grinding of coal and hence contribute to low NO{sub x}. These technologies have been applied in various combinations to 227 boilers for both new installation and retrofit jobs. Large 1,000 MWe oil or gas fired boilers and 700 MWe coal fired boilers have been put into commercial use, and a 1,000 MWe coal fired boiler is under commissioning. The technologies have been applied to small sized boilers for industrial use as well. All the delivered systems have been working both domestic and overseas to the customers` satisfaction.

Kaneko, Shozo; Tokuda, Kimishiro; Sato, Susumu [Mitsubishi Heavy Industries, Yokohama (Japan)

1996-01-01T23:59:59.000Z

412

METHANE DE-NOX FOR UTILITY PC BOILERS  

SciTech Connect (OSTI)

The project seeks to develop and validate a new pulverized coal combustion system to reduce utility PC boiler NO{sub x} emissions to 0.15 lb/million Btu or less without post-combustion flue gas cleaning. Work during the quarter included completion of the equipment fabrication and installation efforts for the 3-million Btu/h pilot system at BBP's Pilot-Scale Combustion Facility (PSCF) in Worcester, MA. Selection and procurement of the first two test coals and preliminary selection of the final two test coals were completed. Shakedown and commissioning activities were finished and PC Preheat pilot scale tests commenced with PRB coal.

Joseph Rabovitser; Bruce Bryan; Serguei Nester; Stan Wohadlo

2002-01-31T23:59:59.000Z

413

Detection of Ammonia Slip Using NOx Sensor Signal Processing  

Broader source: Energy.gov [DOE]

Presentation given at the 16th Directions in Engine-Efficiency and Emissions Research (DEER) Conference in Detroit, MI, September 27-30, 2010.

414

Controlling Emissions of SOx and NOx from power plants  

E-Print Network [OSTI]

#12;Sulfur Removal Sulfur is removed from crude oil by the catalytic reaction: R-S + H2 H2S + R Until the mid 1970's the H2S was mixed back into the fuel gas. The problem with this is that the H2S is burned + CO2 This is a two step process including the scrubber and the effluent hold tank. CaSO4 (gypsum

Toohey, Darin W.

415

The development of Comprehensive Community NOx Emissions Reduction Toolkit (CCNERT)  

E-Print Network [OSTI]

?s Industry Code Description into the EIA?s Commercial Building Activity Description .................................................... 136 Table 5-21 Summary of the Total Number of Employees and Establishments (Businesses) .... 142... Table 5-22 Summary of Information Taken from the EIA?s 1999 CBECS................................ 143 Table 5-23 Commercial Sector Profile and Estimated Energy Use in College Station............... 145 Table 5-24 Summary of the Educational Service...

Sung, Yong Hoon

2004-11-15T23:59:59.000Z

416

METHANE de-NOX for Utility PC Boilers  

SciTech Connect (OSTI)

The overall project objective is the development and validation of an innovative coal combustion system, based on a novel coal preheating concept prior to combustion, that can reduce NO{sub x} emissions to 0.15 lb/million Btu or less on utility pulverized coal (PC) boilers without the need for post-combustion cleaning. Work during the quarter included initiation of the equipment fabrication effort for all pilot system components. Fabrication of the gas-fired combustor was started and completed by IGT during the quarter. The combustor was then installed in IGT's combustion laboratory for proof-of-performance testing prior to shipping to BBP for installation in the pilot-scale test system. A testing procedure and performance goals were developed for the combustor testing.

Joseph Rabovitser; Bruce Bryan; Stan Wohadlo

2001-03-31T23:59:59.000Z

417

METHANE de-NOX FOR UTILITY PC BOILERS  

SciTech Connect (OSTI)

The project seeks to develop and validate a new pulverized coal combustion system to reduce utility PC boiler NO{sub x} emissions to 0.15 lb per million Btu or less without post-combustion flue gas cleaning. Work during previous reporting periods completed the design, installation, shakedown and initial PRB coal testing of a 3-million Btu/h pilot system at BBP's Pilot-Scale Combustion Facility (PSCF) in Worcester, MA. Based on these results, modifications to the gas-fired preheat combustor and PC burner were defined, along with a modified testing plan and schedule. A revised subcontract was executed with BBP to reflect changes in the pilot testing program. Modeling activities were continued to develop and verify revised design approaches for both the Preheat gas combustor and PC burner. Reactivation of the pilot test system was then begun with BBP personnel. During the current reporting period, reactivation of the pilot test system was completed with the modified Preheat gas combustor. Following shakedown of the modified gas combustor alone, a series of successful tests of the new combustor with PRB coal using the original PC burner were completed. NO{sub x} at the furnace exit was reduced significantly with the modified gas combustor, to as low as 150 ppm with only 36 ppm CO (both corrected to 3% O{sub 2}). Concurrent with testing, GTI and BBP collaborated on development of two modified designs for the PC burner optimized to fire preheated char and pyrolysis products from the Preheat gas combustor.

Joseph Rabovitser; Bruce Bryan; Serguei Nester; Stan Wohadlo

2002-10-29T23:59:59.000Z

418

METHANE de-NOX FOR UTILITY PC BOILERS  

SciTech Connect (OSTI)

During the current quarter, pilot scale testing was continued with the modified combustor and modified channel burner using the new PRB coal delivered in late December. Testing included benchmark testing to determine whether the system performance was comparable to that with the previous batch of PRB coal, baseline testing to characterize performance of the PC Burner without coal preheating, and parametric testing to evaluate the effect of various preheat combustor and PC burner operating variables, including reduced gas usage in the preheat combustor. A second version of the PC burner in which the secondary air channels were closed and replaced with six air nozzles was then tested with PRB coal. Plans were developed with RPI for the next phase of testing at the 100 million Btu/h scale using RPI's Coal Burner Test Facility (CBTF). A cost estimate for preparation of the CBTF and preheat burner system design, installation and testing was then prepared by RPI.

Joseph Rabovitser; Bruce Bryan; Serguei Nester; Stan Wohadlo

2003-04-01T23:59:59.000Z

419

METHANE DE-NOX FOR UTILITY PC BOILERS  

SciTech Connect (OSTI)

During the current quarter, pilot-scale testing with the modified air nozzle version of the PC burner was completed with PRB coal at the Riley Power Inc. (RPI) test facility. A total of 8 different burner configurations were tested utilizing various burner air nozzle arrangements in place of the burner air channels. It was found that with the arrangements tested, a stable flame could not be maintained at coal feed rates above 100 lb/h. While it is felt that the air nozzle approach can ultimately be used effectively, in the interest of holding to the current project schedule it was decided to proceed with the balance of the project using the air channel design. The pilot-scale PC burner was therefore restored to the air-channel configuration and benchmark testing with PRB coal to confirmed previous operating results. A series of tests was then conducted with PRB and West Virginia caking coal to evaluate modifications to the gas combustor configuration and operation for improved performance with caking coal. Continuous operation was achieved with caking coal up to 50 lb/h vs. the full load target of 150 lb/h. Impingement and deposition of partially devolatilized coal occurred at various points within the combustor when the caking coal feed was increased above 50 lb/h. The 100 MMBtu/h commercial-scale prototype design was started with coal burner design input from both RPI and VTI. Based on typical burner installation layout considerations, it was that the preheat combustor should be oriented horizontally on the axial centerline of the coal burner. Accordingly, work was begun to relocate the pilot gas combustor to this orientation so that the pilot results with caking coal will be directly applicable to the preferred 100 MMBtu design. Inspection and repair of the 100 MMBtu/h Coal Burner Test Facility (CBTF) was initiated by RPI and as of 6/30, this activity was 70% complete.

Bruce Bryan; Joseph Rabovitser; Serguei Nester; Stan Wohadlo

2003-07-30T23:59:59.000Z

420

METHANE de-NOX for Utility PC Boilers  

SciTech Connect (OSTI)

The project seeks to develop and validate a new pulverized coal combustion system to reduce utility PC boiler NO{sub x} emissions to 0.15 lb/million Btu or less without post-combustion flue gas cleaning. Work during the quarter included continuation of the equipment fabrication effort for pilot system components. Successful proof-of-performance testing of the IGT-designed pilot-scale natural gas-fired coal preheat combustor was completed by IGT during the quarter. The combustor was then disassembled and shipped for installation in the pilot-scale test system in BBP's Coal Burner Test Facility (CBTF) in Worcester, MA. Delivery of the balance of the pilot system components from the fabricator began near the end of the quarter, with components being installed in the pilot test facility as they were received.

Joseph Rabovitser; Bruce Bryan; Serguei Nester; Stan Wohadlo

2001-06-30T23:59:59.000Z

Note: This page contains sample records for the topic "nox ods voc" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

CLEERS Activities: Diesel Soot Filter Characterization & NOx Control Fundamentals  

Broader source: Energy.gov [DOE]

2009 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C.

422

High-temperature lean NOx catalyst and catalyst reaction management  

Science Journals Connector (OSTI)

Mitsubishi Motors introduced a gasoline direct injection engine called the GDI engine into Europe in 1997. Since then, emissions regulations have become even more stringent.

Hiromitsu Ando

2001-07-01T23:59:59.000Z

423

Controlling NOx to Obtain Offsets or Meet Compliance  

E-Print Network [OSTI]

monitored and regu lated a number of pollutants: lead, carbon monoxide, oxides of sulfur, oxides of nitrogen, ozone and PM-lO. The Clean Air Act Amendments increased the focus on these pollutants, mandating the reductions to specified limits. Title I...

Mincy, J. E.

424

Cummins/ORNL-FEERC CRADA: NOx Control & Measurement Technology...  

Broader source: Energy.gov (indexed) [DOE]

- 2x independent gas switching feeds - LabView microreactor control & monitoring * MatLab analysis: - Steady state, transient & integrated analysis Flow Flow Capillaries Enter...

425

Impact of Sulfur Dioxide on Lean NOx Trap Catalysts | Department...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Diesel Engine Emissions Reduction (DEER) Conference Presentation: University of New Mexico 2004deerhammache.pdf More Documents & Publications CLEERS Aftertreatment Modeling...

426

Cummins/ORNL-FEERC CRADA: NOx Control & Measurement Technology...  

Broader source: Energy.gov (indexed) [DOE]

to multiplex for multiple point measurements - Simple and easy to implement In comparison to other techniques* * Purpose - rapid feedback to guide development *...

427

Mechanisms of Sulfur Poisoning of NOx Adsorber (LNT) Materials  

Broader source: Energy.gov [DOE]

2009 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C.

428

Oxidation State Optimization for Maximum Efficiency of NOx Adsorber Catalysts  

Broader source: Energy.gov [DOE]

Presentation given at the 16th Directions in Engine-Efficiency and Emissions Research (DEER) Conference in Detroit, MI, September 27-30, 2010.

429

Mechanisms of Sulfur Poisoning of NOx Adsorber (LNT) Materials  

Broader source: Energy.gov [DOE]

Presentation from the U.S. DOE Office of Vehicle Technologies "Mega" Merit Review 2008 on February 25, 2008 in Bethesda, Maryland.

430

Methane de-NOX for Utility PC Boilers  

SciTech Connect (OSTI)

Large-scale combustion tests with caking bituminous coal was on hold this quarter mainly due to Riley's Commercial Burner Test Facility (CBTF) not having adequate weatherproofing to support operation under freezing conditions. The CBTF was secured and decommissioned for the winter season. CBTF bituminous coal tests shall continue to remain on hold now as a result of project funding limitations, however. No further modifications at the CBTF are planned until needed support is obtained. Activities this quarter have concentrated on finding additional support for the project. Currently, GTI has been granted a no-cost time extension through September 2005 and efforts to secure more support will continue in hopes that large-scale preheat caking bituminous combustion tests will be carried out as planned.

Bruce Bryan; Joseph Rabovitser; Serguei Nester; Stan Wohadlo

2005-03-31T23:59:59.000Z

431

METHANE de-NOX for Utility PC Boilers  

SciTech Connect (OSTI)

Large-scale PRB testing during the current quarter was cut short due to the inability of the coal mill to meet the 85 MMBtu/h design firing rate. The project was therefore redirected toward design, installation and testing of the 85-million Btu/h preheater for bituminous coal. Based on extensive pilot-scale testing completed earlier in the project, 2-D modeling and preliminary design activities were started based on the use of staged, annular protective air films to control temperature and prevent deposition on the preheater walls. A total of 14 2-D modeling cases were completed for the modified preheater for bituminous coal. The preheater concept modeled was based on an expanding preheater chamber where the diameter of the chamber is increased in steps along its length and annular cooling/protective air is introduced at each step. A process flow diagram for the bituminous coal preheating system and a preliminary preheater design drawing were developed based on the modeling results. A project schedule to complete design, installation and testing of the 85 MMBtu/h bituminous coal preheating system before the end of December was also developed.

Bruce Bryan; Joseph Rabovitser; Serguei Nester; Stan Wohadlo

2004-09-30T23:59:59.000Z

432

METHANE de-NOX for Utility PC Boilers  

SciTech Connect (OSTI)

Large-scale combustion tests with caking bituminous coal has stopped. This stoppage has come about due to limitations in current funding available to continue large scale research and development activities at Riley's Commercial Burner Test Facility (CBTF) of the PC Preheat technology. The CBTF was secured and decommissioned in the previous quarter; work this quarter has focused on disposition of PC Preheat experimental equipment at the CBTF as well as methods for disposal of about 100 tons of residual PRB test coal in storage. GTI was granted a no-cost time extension through September 2005; a final report is due in December 2005.

Bruce Bryan; Joseph Rabovitser; Serguei Nester; Stan Wohadlo

2005-06-30T23:59:59.000Z

433

Three-Dimensional Composite Nanostructures for Lean NOx Emission Control  

Broader source: Energy.gov [DOE]

2011 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation

434

Radiative forcing from aircraft NOx emissions: Mechanisms and seasonal dependence  

E-Print Network [OSTI]

dependence. The long-term globally integrated annual mean net forcing calculated here is approximately zero, related to the annual cycle in photochemistry; the O3 radiative forcing calculations also have a seasonal, although earlier work suggests a small net positive forcing. The model design (e.g., upper tropospheric

435

Power Generating Stationary Engines Nox Control: A Closed Loop...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

A Low-Cost Continuous Emissions Monitoring System for Mobile and Stationary Engine SCRDPF ApplicationsData-Logger for Vehicle Data Acquisition Active DPF for Off-Road...

436

UTILIZATION OF LOW NOx COAL COMBUSTION BY-PRODUCTS  

SciTech Connect (OSTI)

Potomac Electric Power Company (PEPCo) Class F fly ash is the first material to be worked on in this project. A head sample was taken and a screen analysis performed. Each size fraction was evaluated for LOI content. Table 1 shows the distribution of the as-received material by size and LOI content. From the data, 80% of the as-received material is finer than 400 mesh and the LOI content goes from high at coarse fractions and decreases to a low at the finest size fraction. SEM chemical analysis identified the as-received fly ash to mainly consist of silica (46%), aluminum oxide (21%), and iron in various forms (16%). The high iron content presents an extreme case as compared to other fly ash samples we have evaluated previously. Its effect on product testing applications could identify physical and chemical limitations as product testing progresses. Because of the high iron content, it was realized that magnetic separation would be incorporated into the early part of the pilot plant flowsheet to remove magnetic iron and, hopefully, reduce the total iron content. More analytical data will be presented in the next reporting period.

A.M. HEIN; J.Y. HWANG; M.G. MCKIMPSON; R.C. GREENLUND; X. HUANG

1998-10-01T23:59:59.000Z

437

Development of Chemical Kinetic Models for Lean NOx Traps  

Broader source: Energy.gov [DOE]

2010 DOE Vehicle Technologies and Hydrogen Programs Annual Merit Review and Peer Evaluation Meeting, June 7-11, 2010 -- Washington D.C.

438

Investigation of Aging Mechanisms in Lean NOx Traps  

Broader source: Energy.gov [DOE]

2009 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C.

439

NOx Measurement Errors in Ammonia-Containing Exhaust  

Broader source: Energy.gov [DOE]

Presentation given at DEER 2006, August 20-24, 2006, Detroit, Michigan. Sponsored by the U.S. DOE's EERE FreedomCar and Fuel Partnership and 21st Century Truck Programs.

440

Pt-free, Perovskite-based Lean NOx Trap Catalysts  

Broader source: Energy.gov (indexed) [DOE]

Conference Pt-free, Perovskite-based Lean NO x Trap Catalysts Gongshin Qi, Chang H. Kim, and Wei Li GM Global Research & Development 2010 DEER Conference Overview LNT Chemistry...

Note: This page contains sample records for the topic "nox ods voc" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Cost analysis of NOx control alternatives for stationary gas turbines  

SciTech Connect (OSTI)

The use of stationary gas turbines for power generation has been growing rapidly with continuing trends predicted well into the future. Factors that are contributing to this growth include advances in turbine technology, operating and siting flexibility and low capital cost. Restructuring of the electric utility industry will provide new opportunities for on-site generation. In a competitive market, it maybe more cost effective to install small distributed generation units (like gas turbines) within the grid rather than constructing large power plants in remote locations with extensive transmission and distribution systems. For the customer, on-site generation will provide added reliability and leverage over the cost of purchased power One of the key issues that is addressed in virtually every gas turbine application is emissions, particularly NO{sub x} emissions. Decades of research and development have significantly reduced the NO{sub x} levels emitted from gas turbines from uncontrolled levels. Emission control technologies are continuing to evolve with older technologies being gradually phased-out while new technologies are being developed and commercialized. The objective of this study is to determine and compare the cost of NO{sub x} control technologies for three size ranges of stationary gas turbines: 5 MW, 25 MW and 150 MW. The purpose of the comparison is to evaluate the cost effectiveness and impact of each control technology as a function of turbine size. The NO{sub x} control technologies evaluated in this study include: Lean premix combustion, also known as dry low NO{sub x} (DLN) combustion; Catalytic combustion; Water/steam injection; Selective catalytic reduction (SCR)--low temperature, conventional, high temperature; and SCONO{sub x}{trademark}.

Bill Major

1999-11-05T23:59:59.000Z

442

Three-Dimensional Composite Nanostructures for Lean NOx Emission...  

Broader source: Energy.gov (indexed) [DOE]

DFT atomistic calculation. * Objectives (quarters 7-10, 0412011-3312012) - Optimization of synthesis of 3D nanoarray catalysts. - Metal loading and thermalmechanical...

443

Enhanced High Temperature Performance of NOx Storage/Reduction...  

Broader source: Energy.gov (indexed) [DOE]

Neal Currier, Junhui Li, Alex Yezerets Cummins Inc. Hai-Ying Chen, Howard Hess Johnson Matthey ACE026 2 Project Overview Timeline Budget Partners Barriers * Start - March...

444

Mechanisms of Sulfur Poisoning of NOx Adsorber (LNT) Materials  

Broader source: Energy.gov (indexed) [DOE]

Stafford, John Stang (retired), Alex Yezerets Cummins Inc. Hai-Ying Chen, Howard Hess Johnson Matthey Project ID: ace24peden 2 Project Overview Timeline Budget Partners Barriers...

445

Durability Evaluation of an Integrated Diesel NOx Adsorber A...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Diesel Engine Emissions Reduction (DEER) Conference Presentation: Cummins Inc. and Johnson-Matthey 2004deerli.pdf More Documents & Publications Desulfurization Fuel Filter...

446

Passive Catalytic Approach to Low Temperature NOx Emission Abatement  

Broader source: Energy.gov (indexed) [DOE]

Aleksey Yezerets, Michael Ruth Cummins Inc. Hai-Ying Chen, Howard Hess, Mojghan Naseri Johnson Matthey 10252011 US DoE DEER Conference 2011 * 40% Fuel Economy improvement over...

447

Enhanced High and Low Temperature Performance of NOx Reduction...  

Broader source: Energy.gov (indexed) [DOE]

Li, John Luo, Alex Yezerets Cummins Inc. Mario Castagnola, Hai-Ying Chen, Howard Hess Johnson Matthey ACE026 Vehicle Technologies Office 2 Project Overview Timeline Budget...

448

Enhanced High Temperature Performance of NOx Storage/Reduction...  

Broader source: Energy.gov (indexed) [DOE]

Neal Currier, Junhui Li, Alex Yezerets Cummins Inc. Hai-Ying Chen, Howard Hess Johnson Matthey Ace026 2 Project Overview Timeline Budget Partners Barriers * Start - July...

449

Mechanisms of Sulfur Poisoning of NOx Adsorber (LNT) Materials  

Broader source: Energy.gov (indexed) [DOE]

Stafford, Junhui Li, John Stang, Alex Yezerets Cummins Inc. Hai-Ying Chen, Howard Hess Johnson Matthey 2 The project is a CRADA between PNNL and Cummins Inc. It involves a...

450

Cummins/ORNL-FEERC CRADA: NOx Control & Measurement Technology...  

Broader source: Energy.gov (indexed) [DOE]

* Finish: September 2012 * % Complete: 17% Budget * Total project budget since 1998 - DOE share: 4,950k - Contractor share: 4,950k * Funding received in FY09 - 400k *...

451

Cummins/ORNL-FEERC CRADA: NOx Control & Measurement Technology...  

Broader source: Energy.gov (indexed) [DOE]

* Current end date: Sept. 2012 * 80% Complete Budget * 1:1 DOE:Cummins cost share * DOE Funding: - FY2010: 400k - FY2011: 450k - FY2012: 450k Barriers * Emissions controls...

452

Enhanced High Temperature Performance of NOx Storage/Reduction...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

2 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting ace026peden2012o.pdf More Documents & Publications...

453

Enhanced High Temperature Performance of NOx Storage/Reduction...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

1 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation ace026peden2011o.pdf More Documents & Publications Enhanced High...

454

Cummins/ORNL-FEERC CRADA: NOx Control & Measurement Technology...  

Broader source: Energy.gov (indexed) [DOE]

models 19 Technical Back-Up Slides 20 Managed by UT-Battelle for the Department of Energy * Step1: NO oxidation * Step2: SS NO x & NH 3 conversions, Parasitic NH 3...

455

Cummins/ORNL-FEERC CRADA: NOx Control & Measurement Technology...  

Broader source: Energy.gov (indexed) [DOE]

barriers 16 Technical Back-Up Slides 17 Managed by UT-Battelle for the Department of Energy * Step1: NO oxidation * Step2: SS NO x & NH 3 conversions, Parasitic NH 3...

456

Retrofit Diesel Emissions Control System Providing 50% NOxControl  

Broader source: Energy.gov (indexed) [DOE]

B. Berry, T. Caron, J. Cizeron, T. Kinney, K. Lundberg and R. Dalla Betta Catalytica Energy Systems, Inc. The preparation of this poster is based on work funded in part by the...

457

Expression of Genes Linked to NOx Detoxification in Aerobic Bacteria  

E-Print Network [OSTI]

operons referred to as the nif cluster. This suite of genesgenes not found in the nif clusters of K. pneumoniae (i.e.is high conservation among nif gene organization based on

Cua, Lynnie

2010-01-01T23:59:59.000Z

458

Spatiotemporal Distribution of NOx Storage: a Factor Controlling...  

Broader source: Energy.gov (indexed) [DOE]

Commercialized variants of LNTs DOC LNT DPF SCR LNT TWC Muffler Lean gasoline (TWC + LNT) Diesel (LNT+SCR) Diesel (LNT) 4 Managed by UT-Battelle for the U.S. Department of Energy...

459

Three-Dimensional Composite Nanostructures for Lean NOx Emission Control  

Broader source: Energy.gov [DOE]

2012 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting

460

Three-Dimensional Composite Nanostructures for Lean NOx Emission Control  

Broader source: Energy.gov [DOE]

2010 DOE Vehicle Technologies and Hydrogen Programs Annual Merit Review and Peer Evaluation Meeting, June 7-11, 2010 -- Washington D.C.

Note: This page contains sample records for the topic "nox ods voc" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

METHANE de-NOX for Utility PC Boilers  

SciTech Connect (OSTI)

Large-scale combustion tests with caking bituminous coal has stopped. This stoppage has come about due to limitations in current funding available to continue large scale research and development activities at Riley Power's Commercial Burner Test Facility (CBTF) of the PC Preheat technology. The CBTF was secured and decommissioned in the previous quarter; work this quarter work completed the securing the proper disposition of all PC Preheat experimental equipment at the PSCF and CBTF and completing negotiations with AES Westover (a power plant in Johnson City, New York) to accept 130 tons of residual PRB test coal in storage. The coal transport to Westover occurred at the end of August. GTI was granted a no-cost time extension through September 2005; immediate efforts are focused on completing a draft final report, which is due in October 31, 2005 and the final report in December.

Joseph Rabovitser; Serguei Nester; Stan Wohadlo

2005-09-30T23:59:59.000Z

462

Benchmark Reaction Mechanisms and Kinetics for Lean NOx Traps  

Broader source: Energy.gov [DOE]

2009 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C.

463

Enhanced High and Low Temperature Performance of NOx Reduction Materials  

Broader source: Energy.gov [DOE]

2013 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting

464

Three-Dimensional Composite Nanostructures for Lean NOx Emission...  

Broader source: Energy.gov (indexed) [DOE]

metal catalysts. 3 Objectives and Approaches Synthesis: To synthesize 3D composite nano(wiredendrite)arrays rooted on different substrates by solution and vapor phase...

465

METHANE de-NOX for Utility PC Boilers  

SciTech Connect (OSTI)

Preparations for conducting large-scale combustion tests with caking bituminous coal continued during the start of this quarter. Major project accomplishments related to bituminous coal testing included: a CFD preheat model and evaluation, an update of the process flow diagram and a detailed preheat burner mechanical design (suitable for construction) for firing bituminous coal. Installation and testing of the 85 MMBtu/h bituminous coal preheating system was planned to take place before the end of December. Based on the inability to conduct testing in Riley's Commercial Burner Test Facility (CBTF) during freezing weather, a schedule review indicated required site work for testing bituminous coal at the CBTF could not be completed before freezing weather set in at the site. Further bituminous preheat modification work was put on hold and efforts turned to securing the test facility over the winter season. Bituminous coal tests are therefore delayed; April-May 2005 is earliest estimate of when testing can resume. A request for a time extension was submitted to DOE to extend the project through September 2005 to allow time to secure additional funding and complete the bituminous coal testing. Removal of the PRB PC Preheater from the CBTF burner deck was completed. Decommissioning of the CBTF for the winter was also completed.

Bruce Bryan; Joseph Rabovitser; Serguei Nester; Stan Wohadlo

2004-12-31T23:59:59.000Z

466

Advanced tangential low NOx systems - development and results  

SciTech Connect (OSTI)

The development of low NO{sub x} combustion systems has identified the near burner flame conditions as critical in determining the eventual NO{sub x} emission levels. In this paper the development of this criterion, in respect of tangentially coal ({open_quote}T{close_quote}) fired power generation boilers, is discussed together with their commercial application. The potential ultra low NO{sub x} performance of these techniques requires a deeper understanding of coal characteristics in addition to the standard properties involving volatile release rates, the behaviour of particulate clouds and their burning velocities. Aerodynamic properties including fuel air mixing, velocity and particulate distribution are all of fundamental importance and can be studied by means of isothermal physical modelling and computational fluid dynamics (CFD). Amalgamation of these various aspects into burner and combustion system design can be considered as NO{sub x} control by flame management and can be applied to conventional systems as well as to the development of advanced low NO{sub x} burner technology. Low NO{sub x} equipment based on this technology is known as the EnviroNO{sub x}{trademark} system.

Allen, J.W.; Beal, P.R. [Rolls-Royce Industrial Power Group, Derby (United Kingdom)

1996-01-01T23:59:59.000Z

467

Measurement and Characterization of Lean NOx Adsorber Regeneration and Desulfation and Controlling NOx from Multi-mode Lean DI Engines  

Broader source: Energy.gov [DOE]

Presentation from the U.S. DOE Office of Vehicle Technologies "Mega" Merit Review 2008 on February 25, 2008 in Bethesda, Maryland.

468

Measurement and Characterization of Lean NOx Adsorber Regeneration and Desulfation and Controlling NOx from Multi-mode  

Broader source: Energy.gov [DOE]

2009 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C.

469

Transient Dynamometer Testing of a Single Leg NOx Adsorber Combined with a Fuel Processor for Enhanced NOx Control  

Broader source: Energy.gov [DOE]

Presentation given at DEER 2006, August 20-24, 2006, Detroit, Michigan. Sponsored by the U.S. DOE's EERE FreedomCar and Fuel Partnership and 21st Century Truck Programs.

470

Friction stir welding and processing of oxide dispersion strengthened (ODS) alloys  

DOE Patents [OSTI]

A method of welding including forming a filler material of a first oxide dispersoid metal, the first oxide dispersoid material having first strengthening particles that compensate for decreases in weld strength of friction stir welded oxide dispersoid metals; positioning the filler material between a first metal structure and a second metal structure each being comprised of at least a second oxide dispersoid metal; and friction welding the filler material, the first metal structure and the second metal structure to provide a weld.

Ren, Weiju

2014-11-11T23:59:59.000Z

471

Simultaneous calibration of a microscopic traffic simulation model and OD matrix  

E-Print Network [OSTI]

With the recent widespread deployment of intelligent transportation systems (ITS) in North America there is an abundance of data on traffic systems and thus an opportunity to use these data in the calibration of microscopic traffic simulation models...

Kim, Seung-Jun

2006-10-30T23:59:59.000Z

472

Innovative Powder Processing of Oxide Dispersion Strengthened ODS Ferritic Stainless Steels  

SciTech Connect (OSTI)

An innovative gas atomization reaction synthesis technique was employed as a viable method to dramatically lower the processing cost for precursor oxide dispersion forming ferritic stainless steel powders (i.e., Fe-Cr-(Hf,Ti)-Y). During this rapid solidification process the atomized powders were enveloped by a nano-metric Cr-enriched metastable oxide film. Elevated temperature heat treatment was used to dissociate this metastable oxide phase through oxygen exchange reactions with Y-(Hf,Ti) enriched intermetallic compound precipitates. These solid state reactions resulted in the formation of highly stable nano-metric mixed oxide dispersoids (i.e., Y-Ti-O or Y-Hf-O) throughout the alloy microstructure. Subsequent high temperature (1200 C) heat treatments were used to elucidate the thermal stability of each nano-metric oxide dispersoid phase. Transmission electron microscopy coupled with X-ray diffraction was used to evaluate phase evolution within the alloy microstructure.

Rieken, Joel; Anderson, Iver; Kramer, Matthew

2011-04-01T23:59:59.000Z

473

Non-thermal Plasma Processing for Dilute VOCs Decomposition Combined with the Catalyst  

Science Journals Connector (OSTI)

Atmospheric pressure non-thermal plasma process combined with the new catalyst for...2...) named as the carbon balance. For better carbon balance, SED of the electric discharge is more than 90 J/L which is pretty...

Tetsuji Oda; Hikaru Kuramochi; Ryo Ono

2009-01-01T23:59:59.000Z

474

Data validation and risk assessment -- some pitfalls when evaluating VOC measurements  

SciTech Connect (OSTI)

Data validation, as described in Environmental Protection Agency (EPA) protocols under the Contract Laboratory Program (CLP), yields false confidence in the data and drives up costs while providing little benefit (Korte and Brown 1992). Commonly, these data are then used to perform a risk assessment. Much of the published guidance for risk assessments in and arid soils is inadequate because it does not take into account vapor migration due to density-driven flow (Korte and others 1992). Investigations into both of these problems have been performed by personnel of Oak Ridge National Laboratory (ORNL) and are described in this presentation.

Korte, N.; Kearl, P.

1993-06-01T23:59:59.000Z

475

Vehicular emission of volatile organic compounds (VOCs) from a tunnel study in Hong Kong  

E-Print Network [OSTI]

Chemistry and Physics Vehicular emission of volatile organicY. , and Huang, Y. S. : Emission factors and characteristicslight-duty vehicle emissions, Environ. Sci. Technol. , 30,

2009-01-01T23:59:59.000Z

476

Non-Incineration Treatment to Reduce Benzene and VOC Emissions from Green Sand Molding Systems  

SciTech Connect (OSTI)

Final report describing laboratory, pilot scale and production scale evaluation of advanced oxidation systems for emissions and cost reduction in metal casting green sand systems.

Fred S. Cannon; Robert C. Voigt

2002-06-28T23:59:59.000Z

477

Polymer/Clay Nanocomposites as Barrier Materials Used for VOC Removal.  

E-Print Network [OSTI]

??The objective of this study was to determine if the method of incorporation of a silicate layered nanoclay into a polymer matrix can affect the (more)

Herrera-Alonso, Jose M

2009-01-01T23:59:59.000Z

478

Sorbent-Based Gas Phase Air Cleaning for VOCs in Commercial Buildings  

E-Print Network [OSTI]

Efficiency and Renewable Energy, Building TechnologiesEfficiency and Renewable Energy, Building Technologies

Fisk, William J.

2006-01-01T23:59:59.000Z

479

Energy Efficient Indoor VOC Air Cleaning with Activated Carbon Fiber (ACF) Filters  

E-Print Network [OSTI]

Efficiency and Renewable Energy, Building TechnologiesEfficiency and Renewable Energy, Building Technologies

Sidheswaran, Meera

2012-01-01T23:59:59.000Z

480

A Coupled Airflow and Source/Sink Model for Simulating Indoor VOC and Q. Chen2  

E-Print Network [OSTI]

Protection Agency (EPA) have identified indoor air pollution as one of the top environmental risks 1 Department of Civil, Architectural, and Environmental Engineering, University of Miami, Coral Building Technology Program, Massachusetts Institute of Technology, 77 Massachusetts Avenue, Cambridge, MA

Chen, Qingyan "Yan"

Note: This page contains sample records for the topic "nox ods voc" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

Numerical simulation of VOC Emissions from Dry Materials , J.S. Zhang2  

E-Print Network [OSTI]

, subfloors), and insulation materials (fiberglass, rigid foam) emit a variety of volatile organic compounds

Chen, Qingyan "Yan"

482

TRIF Water Sustainability Program Fellowship Report Destruction of Gas-Phase VOCs by a Coupled  

E-Print Network [OSTI]

. Advanced oxidation processes (AOPs) are also widely employed for the remediation of sediment for recovered gas treatment was installed at the site as an interim remediation scheme while the Remedial-test this innovative technology perhaps leading to considerable cost savings without sacrificing the broad

Fay, Noah

483

EVALUATION OF ENHANCED VOC REMOVAL WITH SOIL FRACTURING IN THE SRS UPLAND UNIT  

SciTech Connect (OSTI)

The Environmental Restoration Technology Section (ERTS) of the Savannah River National Laboratory (SRNL) conducted pilot scale testing to evaluate the effectiveness of using hydraulic fracturing as a means to improve soil vapor extraction (SVE) system performance. Laboratory and field research has shown that significant amounts of solvents can be entrapped in low permeability zones by capillary forces and removal by SVE can be severely limited due to low flow rates, mass transfer resistance of the hydrophobic compounds by trapped interparticle water, and diffusion resistance. Introducing sand-filled fractures into these tight zones improves the performance of SVE by (1) increasing the overall permeability of the formation and thereby increasing SVE flow rates, (2) shortening diffusion pathways, and (3) increasing air permeability by improving pore water removal. The synergistic effect of the fracture well completion methods, fracture and flow geometry, and pore water removal appears to increase the rate of solvent mass removal over that of increasing flow rate alone. A field test was conducted where a conventional well in the SRS Upland Unit was tested before and after hydraulic fracturing. ERTS teamed with Clemson University through the South Carolina University and Education Foundation (SCUREF) program utilizing their expertise in fracturing and fracture modeling. The goals of the fracturing pilot testing were to evaluate the following: (1) The effect of hydraulic fractures on the performance of a conventional well. This was the most reliable way to remove the effects of spatial variations in permeability and contaminant distribution on relative well performance. It also provided data on the option of improving the performance of existing wells using hydraulic fractures. (2) The relative performance of a conventional SVE well and isolated hydraulic fractures. This was the most reliable indicator of the performance of hydraulic fractures that could be created in a full-scale implementation. The SVE well, monitoring point arrays and four fracturing wells were installed and the well testing has been completed. Four fractures were successfully created the week of July 25, 2005. The fractures were created in an open area at the bottom of steel well casing by using a water jet to create a notch in the soil and then injecting a guar-sand slurry into the formation. The sand-filled fractures increase the effective air permeability of the subsurface formation diffusion path lengths for contaminant removal. The primary metrics for evaluation were an increase in SVE flow rates in the zone of contamination and an increase in the zone of influence. Sufficient testing has been performed to show that fracturing in the Upland Unit accelerates SVE solvent remediation and fracturing can increase flow rates in the Upland Unit by at least one order of magnitude.

Riha, B

2005-10-31T23:59:59.000Z

484

Experimental and numerical VOC concentration field analysis from flooring material in a ventilated room  

E-Print Network [OSTI]

in "7th International Conference, Healthy Buildings 2003, Singapore : Singapore (2003)" #12;Ventilation

Paris-Sud XI, Université de

485

Copyright (c) 2000 Water Environment Federation. All Rights Reserved. Odors and VOC Emissions 2000  

E-Print Network [OSTI]

. This paper documents burst releases of H2S recorded with a state-of-the-art field measurement system in two manure collection and storage pits under fully slatted floors. They were mechanically ventilated with pit was continuously pumped from three locations: pit fans, wall fans and pit headspaces. Hydrogen sulfide

Ni, Jiqin "Jee-Chin"

486

ARTIFACT FORMATION IN HIGH VOLUME SAMPLING OF VOC's AND SOLID ORGANIC COMPOUNDS.  

E-Print Network [OSTI]

when sampling polluted air. Purified air containing 180 ppbv ozone seems to destroy PAH according Atmospheriques, Boite 7059, UNIVERSITE PARIS 7, 2, place Jussieu, 75251 PARIS Cedex 05 ABSTRACT Pollutants from well äs solid (SOC's) organic compounds. High volume samplers are commonly used m air quality

Boyer, Edmond

487

Atmospheric Pollutant Removal by Non?Thermal Plasmas: Basic Data Needs for Understanding and Optimization of the Process  

Science Journals Connector (OSTI)

Since fifteen years an increasing interest has been devoted to removal of atmospheric pollutant by non?thermal plasmas achieved using e?beams or pulsed discharges for the nitrous oxides the so?called de?NOx process or for Volatils Organic Compounds the so?called de?VOC process. However the physical and chemical mechanisms involved are not easy to understand: molecules or gas mixtures are quite complex and the transient plasma created by the type of discharge often used dielectric barrier or corona ones is non homogeneous in space. In this paper is discussed some data needs for understanding of the NO?removal process and the destruction of some selected VOC molecules TCE and TCA by pulsed discharge plasmas. Some experimental studies performed to get insight into the discharge plasma kinetic involved in the pollutant removal are presented in particular about the hydroxyl radical OH which play an important role in this kinetic.

S. Pasquiers; M. Cormier; O. Motret

2002-01-01T23:59:59.000Z

488

Measurement of the atmospheric reactivity of emissions from gasoline and alternative-fueled vehicles: Assessment of available methodologies. Part 1. Indoor smog chamber study of reactivity. Final report for the first year, January 1-December 31, 1993  

SciTech Connect (OSTI)

A set of multiple indoor smog chambers were used to measure the increase in smog formation (smog = NO oxidation + O3 formation) from a series of individual test volatile organic compounds (VOC`s), as well as carbon monoxide (CO), when they were added to a standard urban mixture and irradiated for 10-12 hours with a solar simulator. The chambers and the mixtures were designed to simulate the Carter incremental reactivity concept that is being used in California. The test compounds covered a wide range of mechanistic uncertainties and predicted reactivities (reactivity is the increase in smog divided by the amount of test compound added). Also, the chambers were used to test the recently developed Integrated Empirical Rate (IER) Model which predicts that the smog formation of a mixture is constant and independent of NOx in the so-called light-limited regime.

Kelly, N.A.; Wang, P.; Japar, S.M.; Hurley, M.D.; Wallington, T.J.

1994-06-30T23:59:59.000Z

489

Nitrogen Oxide Emission Statements (Ohio) | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Nitrogen Oxide Emission Statements (Ohio) Nitrogen Oxide Emission Statements (Ohio) Nitrogen Oxide Emission Statements (Ohio) < Back Eligibility Agricultural Commercial Construction Fuel Distributor Industrial Investor-Owned Utility Municipal/Public Utility Rural Electric Cooperative Utility Program Info State Ohio Program Type Environmental Regulations Provider Ohio Environmental Protection Agency This chapter of the law establishes that the Ohio Environmental Protection Agency requires any facility that emits 25 tons or more of NOx and/or 25 tons or more of VOC during the calendar year and is located in a county designated as nonattainment for the National Ambient Air Quality Standards for ozone submit emission statements. Any facility that is located in a county described above is exempt from these requirements. If NOx

490

System and method for selective catalytic reduction of nitrogen oxides in combustion exhaust gases  

DOE Patents [OSTI]

A multi-stage selective catalytic reduction (SCR) unit (32) provides efficient reduction of NOx and other pollutants from about 50-550.degree. C. in a power plant (19). Hydrogen (24) and ammonia (29) are variably supplied to the SCR unit depending on temperature. An upstream portion (34) of the SCR unit catalyzes NOx+NH.sub.3 reactions above about 200.degree. C. A downstream portion (36) catalyzes NOx+H.sub.2 reactions below about 260.degree. C., and catalyzes oxidation of NH.sub.3, CO, and VOCs with oxygen in the exhaust above about 200.degree. C., efficiently removing NOx and other pollutants over a range of conditions with low slippage of NH.sub.3. An ammonia synthesis unit (28) may be connected to the SCR unit to provide NH.sub.3 as needed, avoiding transport and storage of ammonia or urea at the site. A carbonaceous gasification plant (18) on site may supply hydrogen and nitrogen to the ammonia synthesis unit, and hydrogen to the SCR unit.

Sobolevskiy, Anatoly; Rossin, Joseph A

2014-04-08T23:59:59.000Z

491

A novel Whole Air Sample Profiler (WASP) for the quantification of volatile organic compounds in the boundary layer  

SciTech Connect (OSTI)

The emission and fate of reactive VOCs is of inherent interest to those studying chemical biosphere-atmosphere interactions. In-canopy VOC observations are obtainable using tower-based samplers, but the lack of suitable sampling systems for the full boundary 5 layer has limited the data characterizing the vertical structure of such gases above the canopy height and still in the boundary layer. This is the important region where many reactive VOCs are oxidized or otherwise removed. Here we describe an airborne sampling system designed to collect a vertical profile of air into a 3/800 OD tube 150m in length. The inlet ram air pressure is used to flow sampled air through the 10 tube, which results in a varying flow rate based on aircraft speed and altitude. Since aircraft velocity decreases during ascent, it is necessary to account for the variable flow rate into the tube. This is accomplished using a reference gas that is pulsed into the air stream so that the precise altitude of the collected air can be reconstructed post-collection. The pulsed injections are also used to determine any significant effect 15 from diffusion/mixing within the sampling tube, either during collection or subsequent extraction for gas analysis. This system has been successfully deployed, and we show some measured vertical profiles of isoprene and its oxidation products methacrolein and methyl vinyl ketone from a mixed canopy near Columbia, Missouri.

Mak, J. E.; Su, L.; Guenther, Alex B.; Karl, Thomas G.

2013-10-16T23:59:59.000Z

492

Investigation Of Synergistic NOx Reduction From Cofiring And Air Staged Combustion Of Coal And Low Ash Dairy Biomass In A 30 Kilowatt Low NOx Furnace  

E-Print Network [OSTI]

Alternate, cost effective disposal methods must be developed for reducing phosphorous and nitrogen loading from land application of animal waste. Cofiring coal with animal waste, termed dairy biomass (DB), is the proposed thermo-chemical method...

Lawrence, Benjamin Daniel

2013-08-01T23:59:59.000Z

493

Fuel Consumption and NOx Trade-offs on a Port-Fuel-Injected SI Gasoline Engine Equipped with a Lean-NOx Trap  

Broader source: Energy.gov [DOE]

Lean-burn improves PFI fuel economy by ~3% relative to best stoichiometric VCT/EGR conditions, when used in combination with VCT & EGR.

494

Development of ADECS to Meet 2010 Emission Levels: Optimization of NOx, NH3 and Fuel Consumption Using High and Low Engine-Out NOx Calibrations  

Broader source: Energy.gov [DOE]

Development and validation of a simple strategy-based technique using four engine parameters to minimize emissions and fuel consumption

495

Ispitivanje ?inilaca od zna?aja za rast razli?itih sojeva Listeria monocytogenes u filetima hladno dimljene pastrmke.  

E-Print Network [OSTI]

??Veterinarska medicina - Higijena i tehnologija mesa / Veterinary medicine - Meat hygiene and Technology Osnovni princip pakovanja hrane je slede?i izbegavanje kontaminacije, odlaganje (more)

Kuzmanovi?, Jelena Z., 1979-

2015-01-01T23:59:59.000Z

496

TRANSMISSION ELECTRON MICROSCOPY ANALYSIS OF A PRESOLAR SPINEL GRAIN. T. J. Ze-, C. M. O'D. Alexander2  

E-Print Network [OSTI]

Federal Reserve Bank of Boston Fidelity Investments First Wind Forest Laboratories, Inc. General Electric Company General Mills Hasbro, Inc. Houghton Mifflin Harcourt IBM Global Services Johnson & Johnson Jones

Nittler, Larry R.

497

From horse-drawn railway to high-speed transportation system Od konspezn zeleznice k vysokorychlostnm dopravnm systm  

E-Print Network [OSTI]

composed for many centuries and isn´t prepared for the acute impact of automobile conveyance. It was the UT, mnozství více ci mén vhodn parkujících automobil, nízká cestovní rychlost mstské hromadné dopravy (MHD automobil na 2,1 obyvatele vrcholovou pozici v zebícku mst nejen ceských, ale v poslední dob jiz i

Paris-Sud XI, Université de

498

36 | VOL.9 NO.1 | JANUARY 2012 | nature methods special feature | MethOds tO wAtch  

E-Print Network [OSTI]

Methods for tackling the enormously complex glycoproteome are sorely needed. Technologies for profiling for profiling the enor- mously complex glycoproteome. Glycans, complex chains of sugars, are not just energy-storage proteins--but not in high throughput. Mass spectrometry, already a proven technology for proteomics

Cai, Long

499

Buildings Energy Data Book: 1.4 Environmental Data  

Buildings Energy Data Book [EERE]

0 0 2010 Emissions Summary Table for U.S. Buildings Energy Consumption (Thousand Short Tons) (1) Buildings Buildings Percent Wood/SiteFossil Electricity Total U.S. Total of U.S. Total SO2 (2) 54% NOx 17% CO 5% VOCs 2% PM-2.5 15% PM-10 7% Note(s): Source(s): 1) VOCs = volatile organic compounds; PM-10 = particulate matter less than 10 micrometers in aerodynamic diameter. PM-2.5 = particulate matter less than 2.5 micrometers in aerodynamic diameter. CO and VOCs site fossil emissions mostly from wood burning. 2) Emissions of SO2 are 28% lower for 2002 than 1994 estimates since Phase II of the 1990 Clean Air Act Amendments began in 2000. Buildings Energy Consumption related to SO2 emissions dropped 27% from 1994 to 2002. EIA, Annual Energy Outlook 2012 Early Release, Jan. 2012, Summary Reference Case Tables, Table A2, p. 3-5; and EPA, 1970-2010 National Emissions

500

Source Contributions to VOC's to Ozone Formation in Southeast Texas Using a Source-oriented Air Quality Model  

E-Print Network [OSTI]

AQS) from August 16, 2000 to September 7, 2000. Environmental Protection Agency (EPA)?s Community Scale Air Quality Model (CMAQ) version 4.6 was used as a host model to include a revised Statewide Air Pollution Research Center (SAPRC99) photochemical...

Krishnan, Anupama

2011-08-08T23:59:59.000Z