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1

IEP - Advanced NOx Emissions Control: NOx Reduction Technologies  

NLE Websites -- All DOE Office Websites (Extended Search)

NOx Reduction Technologies NOx reduction technologies can be grouped into two broad categories: combustion modifications and post-combustion processes. Some of the more important...

2

NETL: Advanced NOx Emissions Control: Control Technology - NOx Emissions  

NLE Websites -- All DOE Office Websites (Extended Search)

Emissions from Multi-Burners Emissions from Multi-Burners The University of Utah working with Reaction Engineering International and Brigham Young University is investigating a project that consists of integrated experimental, theoretical and computational modeling efforts. The primary objective is to evaluate NOx formation/destruction processes as they occur in multi-burner arrays, a geometry almost always utilized in utility practice. Most controlled experimental work examining NOx has been conducted on single burners. The range of potential intra-burner interactions are likely to provide added degrees of freedom for reducing NOx. The resultant findings may allow existing utilities to arrange fuel and air distribution to minimize NOx. In new applications, orientation of individual burners within an array may also be altered to reduce NOx. Comprehensive combustion codes will be modified to incorporate the latest submodels of nitrogen release and heterogeneous chemistry. Comparison of pilot scale experiments and simulations will be utilized to validate/develop theory.

3

NETL: Advanced NOx Emissions Control: Control Technology - Ultra Low-NOx  

NLE Websites -- All DOE Office Websites (Extended Search)

Ultra Low NOx Integrated System Ultra Low NOx Integrated System TFS 2000(tm) Low NOx Firing System Project Summary: ALSTOM Power Inc.'s Power Plant Laboratories, working in concert with ALSTOM Power's Performance Projects Group, has teamed with the U.S. Department of Energy's National Energy Technology Laboratory (DOE NETL) to conduct a comprehensive study to develop/evaluate low-cost, efficient NOx control technologies for retrofit to pulverized coal fired utility boilers. The objective of this project was to develop retrofit NOx control technology to achieve less than 0.15 lb/MMBtu NOx (for bituminous coals) and 0.10 lb/MMBtu NOx (for subbituminous coals) from existing pulverized coal fired utility boilers at a cost which is at least 25% less than SCR technology. Efficient control of NOx is seen as an important,

4

NETL: Advanced NOx Emissions Control: Control Technology - NOx Combustion  

NLE Websites -- All DOE Office Websites (Extended Search)

Control Options and Integration Control Options and Integration Reaction Engineering International (REI) is optimizing the performance of, and reduce the technical risks associated with the combined application of low-NOx firing systems (LNFS) and post combustion controls through modeling, bench-scale testing, and field verification. Teaming with REI are the University of Utah and Brown University. During this two-year effort, REI will assess real-time monitoring equipment to evaluate waterwall wastage, soot formation, and burner stoichiometry, demonstrate analysis techniques to improve LNFS in combination with reburning/SNCR, assess selective catalytic reduction catalyst life, and develop UBC/fly ash separation processes. The REI program will be applicable to coal-fired boilers currently in use in the United States, including corner-, wall-, turbo-, and cyclone-fired units. However, the primary target of the research will be cyclone boilers, which are high NOx producing units and represent about 20% of the U.S. generating capacity. The results will also be applicable to all U.S. coals. The research will be divided into four key components:

5

IEP - Advanced NOx Emissions Control: Control Technology  

NLE Websites -- All DOE Office Websites (Extended Search)

forms at high temperatures during fossil fuel combustion (see How NOx is Formed ). The primary sources of NOx emissions in the United States are motor vehicles, power plants,...

6

NETL: Advanced NOx Emissions Control: Control Technology - Model for NOx  

NLE Websites -- All DOE Office Websites (Extended Search)

Model for NOx Emissions in Biomass Cofiring Model for NOx Emissions in Biomass Cofiring Southern Research Institute is developing a validated tool or methodology to accurately and confidently design and optimize biomass-cofiring systems for full-scale utility boilers to produce the lowest NOX emissions and the least unburned carbon. The computer model will be validated through an extensive set of tests at the 6 MMBtu/hr pilot combustor in the Southern Company/Southern Research Institute Combustion Research Facility. Full-scale demonstration testing can be compared to the model for further validation. The project is designed to balance the development of a systematic and expansive database detailing the effects of cofiring parameters on NOx formation with the complementary modeling effort that will yield a capability to predict, and therefore optimize, NOx reductions by the selection of those parameters. The database of biomass cofiring results will be developed through an extensive set of pilot-scale tests at the Southern Company/Southern Research Institute Combustion Research Facility. The testing in this program will monitor NOx, LOI, and other emissions over a broad domain of biomass composition, coal quality, and cofiring injection configurations to quantify the dependence of NOx formation and LOI on these parameters. This database of cofiring cases will characterize an extensive suite of emissions and combustion properties for each of the fuel and injection configuration combinations tested.

7

Assessment of Alternative Post-Combustion NOx Controls Technologies  

Science Conference Proceedings (OSTI)

As emission control requirements continually become stricter, power producers need new, efficient, cost-effective approaches to reduce NOx and other atmospheric pollutants. This report focuses on alternative emerging and commercial post-combustion NOx controls applications other than the industry standard selective catalytic reduction (SCR) technology.

2008-12-01T23:59:59.000Z

8

NETL: Advanced NOx Emissions Control: Control Technology - ALTA for Cyclone  

NLE Websites -- All DOE Office Websites (Extended Search)

Full-Scale Demonstration of ALTA NOx Control for Cyclone-Fired Boilers Full-Scale Demonstration of ALTA NOx Control for Cyclone-Fired Boilers The primary goal of this project was to evaluate a technology called advanced layered technology application (ALTA) as a means to achieve NOx emissions below 0.15 lb/MMBtu in a cyclone boiler. Reaction Engineering International (REI) conducted field testing and combustion modeling to refine the process design, define the optimum technology parameters, and assess system performance. The ALTA NOx control technology combines deep staging from overfire air, rich reagent injection (RRI), and selective non-catalytic reduction (SNCR). Field testing was conducted during May-June 2005 at AmerenUE's Sioux Station Unit 1, a 500 MW cyclone boiler unit that typically burns an 80/20 blend of Powder River Basin subbituminous coal and Illinois No. 6 bituminous coal. Parametric testing was also conducted with 60/40 and 0/100 blends. The testing also evaluated process impacts on balance-of-plant issues such as the amount of unburned carbon in the ash, slag tapping, waterwall corrosion, ammonia slip, and heat distribution.

9

Advanced NOx Emissions Control: Control Technology - Second Generation  

NLE Websites -- All DOE Office Websites (Extended Search)

Second Generation Advanced Reburning Second Generation Advanced Reburning General Electric - Energy and Environmental Research Corporation (GE-EER) is carrying out a two Phase research program to develop novel Advanced Reburning (AR) concepts for high efficiency and low cost NOx control from coal-fired utility boilers. AR technologies are based on combination of basic reburning and N-agent/promoter injections. Phase I of the project was successfully completed and EER was selected to continue to develop AR technology during Phase II. Phase I demonstrated that AR technologies are able to provide effective NOx control for coal-fired combustors. Three technologies were originally envisioned for development: AR-Lean, AR-Rich, and Multiple Injection AR (MIAR). Along with these, three additional technologies were identified during the project: reburning plus promoted SNCR; AR-Lean plus promoted SNCR; and AR-Rich plus promoted SNCR. The promoters are sodium salts, in particular sodium carbonate. These AR technologies have different optimum reburn heat input levels and furnace temperature requirements. For full scale application, an optimum technology can be selected on a boiler-specific basis depending on furnace temperature profile and regions of injector access.

10

NETL: Advanced NOx Emissions Control: Control Technology - Mercury...  

NLE Websites -- All DOE Office Websites (Extended Search)

Mercury Speciation from NOx Control University of North Dakota Energy and Environmental Research Center (UNDEERC) is addressing the impact that selective catalytic reduction (SCR),...

11

NETL: Advanced NOx Emissions Control: Control Technology - Carbon...  

NLE Websites -- All DOE Office Websites (Extended Search)

product. The FFR concept solves this problem. The technology increases the efficiency of NOx reduction in coal reburning and decreases carbon-in ash. FFR can achieve the same...

12

NETL: Advanced NOx Emissions Control: Control Technology - ALTA...  

NLE Websites -- All DOE Office Websites (Extended Search)

of the burner design is to achieve homogeneity of the combustion products in the boiler. Not only does this create ideal conditions for combustion-related NOx control, it...

13

NETL: Advanced NOx Emissions Control: Control Technology - Methane de-NOx  

NLE Websites -- All DOE Office Websites (Extended Search)

METHANE de-NOx® METHANE de-NOx® The Gas Technology Institute (GTI) is teaming with the All-Russian Thermal Engineering Institute and DB Riley to develop a pulverized-coal (PC)-combustion system that is an extension of IGT's METHANE de-NOx® technology. The technology is composed of a novel PC burner design using natural gas fired coal preheating developed and demonstrated in Russia, LNBs with internal combustion staging, and additional natural gas injection with overfire air. The coal is preheated at elevated temperatures (up to 1500oF) in oxygen deficient conditions prior to combustion. Coal preheat releases fuel-bound nitrogen together with volatiles present in the coal. These conditions promote the conversion of fuel-bound nitrogen to molecular nitrogen rather than to NOx.

14

NETL: Advanced NOx Emissions Control  

NLE Websites -- All DOE Office Websites (Extended Search)

Home > Technologies > Coal & Power Systems > Innovations for Existing Plants > Advanced NOx Emissions Control Innovations for Existing Plants Advanced NOx Emissions Control Adv....

15

NETL: Advanced NOx Emissions Control: Control Technology - SCNR Field  

NLE Websites -- All DOE Office Websites (Extended Search)

SNCR Field Demonstration SNCR Field Demonstration American Electric Power (AEP), in conjunction with the U.S. Department of Energy, FuelTech, the Ohio Coal Development Office, and fourteen EPRI member utilities, performed a full-scale demonstration of a urea-based Selective Non-Catalytic Reduction (SNCR) system at Cardinal Unit 1. Cardinal Unit 1 is a 600MWe opposed-wall dry bottom pulverized coal-fired boiler that began service in 1967. This unit burns eastern bituminous high-sulfur coal, (3.72%S). This unit was retrofitted with low NOx burners (LNB's) during its scheduled fall 1998 outage and the SNCR system was installed concurrently. SNCR is a post-combustion NOx control process developed to reduce NOx emissions from fossil-fuel combustion systems. SNCR processes involve the injection of a chemical containing nitrogen into the combustion products, where the temperature is in the range of 1600°F - 2200°F (870°C - 1205°C). In this temperature range, the chemical reacts selectively with NOx in the presence of oxygen, forming primarily nitrogen and water. Although a number of chemicals have been investigated and implemented for SNCR NOx reduction, urea and ammonia have been most widely used for full-scale applications.

16

Advanced NOx Emissions Control: Control Technology - Second Generation  

NLE Websites -- All DOE Office Websites (Extended Search)

In Situ Device for Real-Time Catalyst Deactivation Measurements in Full-Scale SCR Systems In Situ Device for Real-Time Catalyst Deactivation Measurements in Full-Scale SCR Systems To support trends in the electric generating industry of moving from seasonal to year-round operation of Selective Catalytic Reduction (SCR) for control of NOx and mercury, as well as extending the time between generating unit outages, Fossil Energy Research Corporation (FERCo) is developing technology to determine SCR catalyst activity and remaining life without requiring an outage to obtain and analyze catalyst samples. FERCo intends to use SCR catalyst performance results measured with their in situ device at Alabama Power’s Plant Gorgas during the 2005 and 2006 ozone seasons, along with EPRI’s CatReactTM catalyst management software, to demonstrate the value of real-time activity measurements with respect to the optimization of catalyst replacement strategy. Southern Company and the Electric Power Research Institute are co-funding the project.

17

NETL: Advanced NOx Emissions Control: Control Technology - Dense...  

NLE Websites -- All DOE Office Websites (Extended Search)

air (ROFA(tm)) and ROTAMIX(tm) systems. Baseline NOx emission rates with the ROFA system ranged from 0.17 to 0.26 lbMMBtu. During DPRCS testing the micronized coal feed...

18

NETL: Advanced NOx Emissions Control: Control Technology - Optimized Fuel  

NLE Websites -- All DOE Office Websites (Extended Search)

Optimized Fuel Injector Design Optimized Fuel Injector Design This project includes fundamental research and engineering development of low NOx burners and reburning fuel injectors. The team of Reaction Engineering International (REI), the University of Utah, Brown University and DB Riley, Inc., will develop fundamental information on low NOx burners. The work has two phases. In the first phase, the University of Utah will examine two-phase mixing and near-field behavior of coal injectors using a 15-million Btu/hr bench-scale furnace, Brown University will examine char deactivation and effectiveness of reburning, and REI will develop a comprehensive burner model using the data produced by the University of Utah and Brown University. In the second phase, an optimized injector design will be tested at the 100-million Btu/hr Riley Coal Burner Test Facility. It is anticipated that this work will provide improved hardware designs and computer simulation models for reduced NOx emissions and minimized carbon loss.

19

Study of Lean NOx Technology for Diesel Emission Control  

DOE Green Energy (OSTI)

Diesel engines because of their reliability and efficiency are a popular mobile source. The diesel engine operates at higher compression ratios and with leaner fuel mixtures and produces lower carbon monoxide and hydrocarbon emissions. The oxygen-rich environment leads to higher nitrogen oxides in the form of NO. Catalysts selectively promoting the reduction of NOx by HCs in a lean environment have been termed lean NOx catalyst ''LNC''. The two groups that have shown most promise are, Copper exchanged zeolite Cu/ZSM5, and Platinum on alumina Pt/Al2O3.

Mital, R.

2000-08-20T23:59:59.000Z

20

PERFORMANCE OF NOx CONTROL TECHNOLOGIES ON THREE CALIFORNIA WASTE-TO-ENERGY  

E-Print Network (OSTI)

catalytic reduction (SNCR) technology. There is a sub stantial volume of literature available discussing NOx in the first three undergrate zones on the SERRF units. Preliminary indications were that some NOx reduction) to quantify the effect of FGR's contribution to NOx reduction during simultaneous FGRIThermal DeNOx use; (b

Columbia University

Note: This page contains sample records for the topic "nox control technologies" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Proceedings: 2000 NOx Controls Workshop  

Science Conference Proceedings (OSTI)

The 2000 EPRI workshop on nitrogen oxide (NOx) controls for utility boilers provided a medium for member utilities to augment their knowledge of recent operating experience and developments on NOx control technologies. The event focused on improving methods of compliance with emission regulations mandated by the Clean Air Act Amendments (CAAA) of 1990 without jeopardizing efficiency and plant performance.

2001-04-10T23:59:59.000Z

22

Rich Reagent Injection Technology for NOx Control in Cyclone-Fired Boilers  

Science Conference Proceedings (OSTI)

This report summarizes multiple demonstration projects that have led to commercial development of the Rich Reagent Injection (RRI) technology. RRI was developed by Reaction Engineering International (REI) with funding from EPRI and U.S. DOE National Energy Technology Laboratory (DOE-NETL). Prior to RRI, most NOx reduction efforts that focused on modifying combustion to reduce NOx formation in fossil-fuel-fired boilers and furnaces involved air or fuel staging. Even with significant levels of furnace stag...

2006-11-06T23:59:59.000Z

23

NETL: News Release - DOE-Funded Technology Slashes NOx, Costs...  

NLE Websites -- All DOE Office Websites (Extended Search)

November 7, 2005 DOE-Funded Technology Slashes NOx, Costs in Coal-Fired Cyclone Boiler Utility Reconsiders Plans to Install Standard NOx-control Technology After Successful Field...

24

Cyclone Boiler Field Testing of Advanced Layered NOx Control Technology in Sioux Unit 1  

SciTech Connect

A four week testing program was completed during this project to assess the ability of the combination of deep staging, Rich Reagent Injection (RRI), and Selective Non-Catalytic Reduction (SNCR) to reduce NOx emissions below 0.15 lb/MBtu in a cyclone fired boiler. The host site for the tests was AmerenUE's Sioux Unit 1, a 500 MW cyclone fired boiler located near St. Louis, MO. Reaction Engineering International (REI) led the project team including AmerenUE, FuelTech Inc., and the Electric Power Research Institute (EPRI). This layered approach to NOx reduction is termed the Advanced Layered Technology Approach (ALTA). Installed RRI and SNCR port locations were guided by computational fluid dynamics (CFD) based modeling conducted by REI. During the parametric testing, NOx emissions of 0.12 lb/MBtu were achieved consistently from overfire air (OFA)-only baseline NOx emissions of 0.25 lb/MBtu or less, when firing the typical 80/20 fuel blend of Powder River Basin (PRB) and Illinois No.6 coals. From OFA-only baseline levels of 0.20 lb/MBtu, NOx emissions of 0.12 lb/MBtu were also achieved, but at significantly reduced urea flow rates. Under the deeply staged conditions that were tested, RRI performance was observed to degrade as higher blends of Illinois No.6 were used. NOx emissions achieved with ALTA while firing a 60/40 blend were approximately 0.15 lb/MBtu. NOx emissions while firing 100% Illinois No.6 were approximately 0.165 lb/MBtu. Based on the performance results of these tests, economics analyses of the application of ALTA to a nominal 500 MW cyclone unit show that the levelized cost to achieve 0.15 lb/MBtu is well below 75% of the cost of a state of the art SCR.

Marc A. Cremer; Bradley R. Adams

2006-06-30T23:59:59.000Z

25

The Chemistry of the Thermal DeNOx Process: A Review of the Technology's Possible Application to control of NOx from Diesel Engines  

DOE Green Energy (OSTI)

This paper presents a review of the Thermal DeNOx process with respect to its application to control of NOx emissions from diesel engines. The chemistry of the process is discussed first in empirical and then theoretical terms. Based on this discussion the possibilities of applying the process to controlling NOx emissions from diesel engines is considered. Two options are examined, modifying the requirements of the chemistry of the Thermal DeNOx process to suit the conditions provided by diesel engines and modifying the engines to provide the conditions required by the process chemistry. While the former examination did not reveal any promising opportunities, the latter did. Turbocharged diesel engine systems in which the turbocharger is a net producer of power seem capable of providing the conditions necessary for NOx reduction via the Thermal DeNOx reaction.

Lyon, Richard

2001-08-05T23:59:59.000Z

26

Near-Zero NOx Technology  

E-Print Network (OSTI)

Miura Boiler is a world leader in boiler technology with manufacturing facilities in Japan, China, Korea, Taiwan and Brantford, Ontario. The company, which began operations in 1927, is committed to technologies that save fuel, reduce harmful emissions, and conserve natural resources. Recently the company announced the development of a technology that dramatically reduces the nitrogen oxide (NOx) concentration in the exhaust gas of gas-fired steam boilers to below 1ppm (at O2=0% equivalent) compared to over 30ppm of conventional US boilers. This near-zero NOx breakthrough will be available in North America by 2010 and represents yet another first in Miuras green technology achievements.

Utzinger, M.

2008-01-01T23:59:59.000Z

27

Impacts of NOx Controls on Mercury Controllability  

Science Conference Proceedings (OSTI)

Past tests have led researchers and air pollution regulators to hypothesize that nitrogen oxides (NOx) controls can enhance mercury capture by particulate collection devices and sulfur dioxide (SO2) scrubbers. This technology review presents results obtained to date from a comprehensive program designed to confirm, qualify, and quantify these hypotheses.

2002-03-13T23:59:59.000Z

28

IEP - Advanced NOx Emissions Control: Regulatory Drivers  

NLE Websites -- All DOE Office Websites (Extended Search)

IEP - Advanced NOx Emissions Control Regulatory Drivers Regulatory Drivers for Existing Coal-Fired Power Plants Regulatory and legislative requirements have predominantly driven the need to develop NOx control technologies for existing coal-fired power plants. The first driver was the Title IV acid rain program, established through the 1990 Clean Air Act Amendments (CAAA). This program included a two-phase strategy to reduce NOx emissions from coal-fired power plants – Phase I started January 1, 1996 and Phase II started January 1, 2000. The Title IV NOx program was implemented through unit-specific NOx emission rate limits ranging from 0.40 to 0.86 lb/MMBtu depending on the type of boiler/burner configuration and based on application of LNB technology.

29

Technology Innovations and Experience Curves for Nitrogen Oxides Control Technologies  

E-Print Network (OSTI)

Selective Catalytic Reduction (SCR) NOx Control; Prepared byNOx Removal Technologies. Volume 1. Selective Catalytic Reduction.

Yeh, Sonia; Rubin, Edward S.; Taylor, Margaret R.

2007-01-01T23:59:59.000Z

30

OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL  

SciTech Connect

Conventional wisdom says adding oxygen to a combustion system enhances product throughput, system efficiency, and, unless special care is taken, increases NOx emissions. This increase in NOx emissions is typically due to elevated flame temperatures associated with oxygen use leading to added thermal NOx formation. Innovative low flame temperature oxy-fuel burner designs have been developed and commercialized to minimize both thermal and fuel NOx formation for gas and oil fired industrial furnaces. To be effective these systems require close to 100% oxy-fuel combustion and the cost of oxygen is paid for by fuel savings and other benefits. For applications to coal-fired utility boilers at the current cost of oxygen, however, it is not economically feasible to use 100% oxygen for NOx control. In spite of this conventional wisdom, Praxair and its team members, in partnership with the US Department of Energy National Energy Technology Laboratory, have developed a novel way to use oxygen to reduce NOx emissions without resorting to complete oxy-fuel conversion. In this concept oxygen is added to the combustion process to enhance operation of a low NOx combustion system. Only a small fraction of combustion air is replaced with oxygen in the process. By selectively adding oxygen to a low NOx combustion system it is possible to reduce NOx emissions from nitrogen-containing fuels, including pulverized coal, while improving combustion characteristics such as unburned carbon. A combination of experimental work and modeling was used to define how well oxygen enhanced combustion could reduce NOx emissions. The results of this work suggest that small amounts of oxygen replacement can reduce the NOx emissions as compared to the air-alone system. NOx emissions significantly below 0.15 lbs/MMBtu were measured. Oxygen addition was also shown to reduce carbon in ash. Comparison of the costs of using oxygen for NOx control against competing technologies, such as SCR, show that this concept offers substantial savings over SCR and is an economically attractive alternative to purchasing NOx credits or installing other conventional technologies. In conjunction with the development of oxygen based low NOx technology, Praxair also worked on developing the economically enhancing oxygen transport membrane (OTM) technology which is ideally suited for integration with combustion systems to achieve further significant cost reductions and efficiency improvements. This OTM oxygen production technology is based on ceramic mixed conductor membranes that operate at high temperatures and can be operated in a pressure driven mode to separate oxygen with infinite selectivity and high flux. An OTM material was selected and characterized. OTM elements were successfully fabricated. A single tube OTM reactor was designed and assembled. Testing of dense OTM elements was conducted with promising oxygen flux results of 100% of target flux. However, based on current natural gas prices and stand-alone air separation processes, ceramic membranes do not offer an economic advantage for this application. Under a different DOE-NETL Cooperative Agreement, Praxair is continuing to develop oxygen transport membranes for the Advanced Boiler where the economics appear more attractive.

David R. Thompson; Lawrence E. Bool; Jack C. Chen

2004-04-01T23:59:59.000Z

31

Experience curves for power plant emission control technologies  

E-Print Network (OSTI)

Selective Catalytic Reduction (SCR) NOx Control, Prepared byReduction (SCR) Technology for the Control of Nitrogen Oxide (NOx)NOx removal technologies. Volume 1. Selective catalytic reduction.

Rubin, Edward S.; Yeh, Sonia; Hounshell, David A

2007-01-01T23:59:59.000Z

32

AMMONIA-FREE NOx CONTROL SYSTEM  

DOE Green Energy (OSTI)

This report describes a novel NOx control system that has the potential to drastically reduce cost, and enhance performance, operation and safety of power plant NOx control. The new system optimizes the burner and the furnace to achieve very low NOx levels and to provide an adequate amount of CO, and uses the CO for reducing NO both in-furnace and over a downstream AFSCR (ammonia-free selective catalytic reduction) reactor. The AF-SCR combines the advantages of the highly successful SCR technology for power plants and the TWC (three-way catalytic converter) widely used on automobiles. Like the SCR, it works in oxidizing environment of combustion flue gas and uses only base metal catalysts. Like the TWC, the AF-SCR removes NO and excess CO simultaneously without using any external reagent, such as ammonia. This new process has been studied in a development program jointed funded by the US Department of Energy and Foster Wheeler. The report outlines the experimental catalyst work performed on a bench-scale reactor, including test procedure, operating conditions, and results of various catalyst formulations. Several candidate catalysts, prepared with readily available transition metal oxides and common substrate materials, have shown over 80-90% removal for both NO and CO in oxidizing gas mixtures and at elevated temperatures. A detailed combustion study of a 400 MWe coal-fired boiler, applying computational fluid dynamics techniques to model boiler and burner design, has been carried out to investigate ways to optimize the combustion process for the lowest NOx formation and optimum CO/NO ratios. Results of this boiler and burner optimization work are reported. The paper further discusses catalyst scale-up considerations and the conceptual design of a 400 MWe size AF-SCR reactor, as well as economics analysis indicating large cost savings of the ammonia-free NOx control process over the current SCR technology.

Song Wu; Zhen Fan; Andrew H. Seltzer; Richard G. Herman

2006-06-01T23:59:59.000Z

33

NOx Sensor for Direct Injection Emission Control  

DOE Green Energy (OSTI)

The Electricore/Delphi team continues to leverage the electrochemical planar sensor technology that has produced stoichiometric planar and wide range oxygen sensors as the basis for development of a NOx sensor. Zirconia cell technology with an integrated heater will provide the foundation for the sensor structure. Proven materials and packaging technology will help to ensure a cost-effective approach to the manufacture of this sensor. The electronics technique and interface is considered to be an area where new strategies need to be employed to produce higher S/N ratios of the NOx signal with emphasis on signal stability over time for robustness and durability Both continuous mode and pulse mode control techniques are being evaluated. Packaging the electronics requires careful design and circuit partitioning so that only the necessary signal conditioning electronics are coupled directly in the wiring harness, while the remainder is situated within the ECM for durability and costs reasons. This task continues to be on hold due to the limitation that the definition of the interface electronics was unavailable until very late in the project. The sense element is based on the amperometric method utilizing integrated alumina and zirconia ceramics. Precious metal electrodes are used to form the integrated heater, the cell electrodes and leads. Inside the actual sense cell structure, it is first necessary to separate NOx from the remaining oxygen constituents of the exhaust, without reducing the NOx. Once separated, the NOx will be measured using a measurement cell. Development or test coupons have been used to facilitate material selection and refinement, cell, diffusion barrier, and chamber development. The sense element currently requires elaborate interconnections. To facilitate a robust durable connection, mechanical and metallurgical connections are under investigation. Materials and process refinements continue to play an important role in the development of the sensor.

Betteridge, William J

2006-02-28T23:59:59.000Z

34

ULTRA LOW NOx INTEGRATED SYSTEM FOR NOx EMISSION CONTROL FROM COAL-FIRED BOILERS  

Science Conference Proceedings (OSTI)

ALSTOM Power Inc.'s Power Plant Laboratories, working in concert with ALSTOM Power's Performance Projects Group, has teamed with the U.S. Department of Energy's National Energy Technology Laboratory (DOE NETL) to conduct a comprehensive study to develop/evaluate low-cost, efficient NOx control technologies for retrofit to pulverized coal fired utility boilers. The objective of this project was to develop retrofit NOx control technology to achieve less than 0.15 lb/MMBtu NOx (for bituminous coals) and 0.10 lb/MMBtu NOx (for subbituminous coals) from existing pulverized coal fired utility boilers at a cost which is at least 25% less than SCR technology. Efficient control of NOx is seen as an important, enabling step in keeping coal as a viable part of the national energy mix in this century, and beyond. Presently 57% of U.S. electrical generation is coal based, and the Energy Information Agency projects that coal will maintain a lead in U.S. power generation over all other fuel sources for decades (EIA 1998 Energy Forecast). Yet, coal-based power is being strongly challenged by society's ever-increasing desire for an improved environment and the resultant improvement in health and safety. The needs of the electric-utility industry are to improve environmental performance, while simultaneously improving overall plant economics. This means that emissions control technology is needed with very low capital and operating costs. This project has responded to the industry's need for low NOx emissions by evaluating ideas that can be adapted to present pulverized coal fired systems, be they conventional or low NOx firing systems. The TFS 2000{trademark} firing system has been the ALSTOM Power Inc. commercial offering producing the lowest NOx emission levels. In this project, the TFS 2000{trademark} firing system served as a basis for comparison to other low NOx systems evaluated and was the foundation upon which refinements were made to further improve NOx emissions and related combustion performance. Three coals were evaluated during the bench-scale and large pilot-scale testing tasks. The three coals ranged from a very reactive Powder River Basin coal (PRB) to a moderately reactive Midwestern bituminous coal (HVB) to a less reactive medium volatile Eastern bituminous coal (MVB). Bench-scale testing was comprised of standard ASTM properties evaluation, plus more detailed characterization of fuel properties through drop tube furnace testing and thermogravimetric analysis.

Galen H. Richards; Charles Q. Maney; Richard W. Borio; Robert D. Lewis

2002-12-30T23:59:59.000Z

35

NOx Control for Utility Boiler OTR Compliance  

Science Conference Proceedings (OSTI)

Under sponsorship of the Department of Energy's National Energy Technology Laboratory (NETL), the Babcock and Wilcox Company (B and W), and Fuel Tech teamed together to investigate an integrated solution for NO{sub x} control. The system is comprised of B and W's DRB-4Z{trademark} ultra low-NO{sub x} pulverized coal (PC) burner technology and Fuel Tech's NOxOUT{reg_sign}, a urea-based selective non-catalytic reduction (SNCR) technology. Development of the low-NO{sub x} burner technology has been a focus in B and W's combustion program. The DRB-4Z{trademark} burner is B and W's newest low-NO{sub x} burner capable of achieving very low NO{sub x}. The burner is designed to reduce NO{sub x} by controlled mixing of the fuel and air. Based on data from several 500 to 600 MWe boilers firing PRB coal, NOx emissions levels of 0.15 to 0.20 lb/ 106 Btu have been achieved from the DRB-4Z{trademark} burners in combination with overfire air ports. Although NOx emissions from the DRB-4Z{trademark} burner are nearing the Ozone Transport Rule (OTR) level of 0.15 lb NO{sub x}/106 Btu, the utility boiler owners can still benefit from the addition of an SNCR and/or SCR system in order to comply with the stringent NO{sub x} emission levels facing them. Large-scale testing is planned in B and W's 100-million Btu/hr Clean Environment Development Facility (CEDF) that simulates the conditions of large coal-fired utility boilers. The objective of the project is to achieve a NO{sub x} level below 0.15 lb/106 Btu (with ammonia slip of less than 5 ppm) in the CEDF using PRB coal and B and W's DRB-4Z{trademark} low-NO{sub x} pulverized coal (PC) burner in combination with dual zone overfire air ports and Fuel Tech's NO{sub x}OUT{reg_sign}. During this period B and W prepared and submitted the project management plan and hazardous substance plan to DOE. The negotiation of a subcontract for Fuel Tech has been started.

Hamid Farzan

2003-12-31T23:59:59.000Z

36

Ammonia-Free NOx Control System  

SciTech Connect

Research is being conducted under United States Department of Energy (DOE) Contract DEFC26-03NT41865 to develop a new technology to achieve very low levels of NOx emissions from pulverized coal fired boiler systems by employing a novel system level integration between the PC combustion process and the catalytic NOx reduction with CO present in the combustion flue gas. The combustor design and operating conditions will be optimized to achieve atypical flue gas conditions. This approach will not only suppress NOx generation during combustion but also further reduce NOx over a downstream catalytic reactor that does not require addition of an external reductant, such as ammonia. This report describes the work performed during the January 1 to March 31, 2004 time period.

S. Wu; Z. Fan; R. Herman

2004-03-31T23:59:59.000Z

37

Ammonia-Free NOx Control System  

SciTech Connect

Research is being conducted under United States Department of Energy (DOE) Contract DEFC26-03NT41865 to develop a new technology to achieve very low levels of NOx emissions from pulverized coal fired boiler systems by employing a novel system level integration between the PC combustion process and the catalytic NOx reduction with CO present in the combustion flue gas. The combustor design and operating conditions will be optimized to achieve atypical flue gas conditions. This approach will not only suppress NOx generation during combustion but also further reduce NOx over a downstream catalytic reactor that does not require addition of an external reductant, such as ammonia. This report describes the work performed during the April 1 to June 30, 2004 time period.

Zhen Fan; Song Wu; Richard G. Herman

2004-06-30T23:59:59.000Z

38

Aeroderivative Gas Turbines Can Meet Stringent NOx Control Requirements  

E-Print Network (OSTI)

Gas Turbines operating in the United States are required to meet federally mandated emission standards. This article will discuss how General Electric's LM industrial aeroderivative gas turbines are meeting NOx requirements as low as 25 parts per million using steam injection. The article will also describe the technical aspects of how water or steam injection can be used to supress NOx, what emission levels GE will guarantee and detail some recently obtained test results. The side benefits of water or steam injection for controlling NOx emissions will be discussed. Steam injection has a very favorable effect on engine performance raising both the power output and efficiency. As an example, full steam injection in the GE LM5000 gas turbine increases the power output from 34 MW to 52 MW while lowering the heat rate from 9,152 Btu/kWh to 7,684 Btu/kWh when fired on natural gas. Water injection increases power output at a slightly decreased thermal efficiency. When steam is injected, NOx can be controlled to 25 ppm (referenced to 15 percent O2) which is sufficient to comply with the most stringent requirements imposed in areas where water or steam injection is considered best available control technology (BACT). Selective Catalytic Reduction (SCR) systems are currently employed in areas with Lowest Achievable Emissions Requirements. SCRs have been proposed as BACT in several areas such as the Bay area of California and the state of New Jersey. These systems are expensive to install and operate, and this cost impact can cause many projects to become economically non-viable. Cost comparisons for NOx removal using an SCR in combination with the steam injection will demonstrate the large incremental cost incurred when NOx is controlled using an SCR. Lastly, a case will be made for not imposing SCR as BACT in that it would close the door on further research and development for better, cost-effective methods of NOx control.

Keller, S. C.; Studniarz, J. J.

1987-09-01T23:59:59.000Z

39

EPRI 2002 Workshop on Combustion-Based NOx Controls for Coal-Fired Boilers  

Science Conference Proceedings (OSTI)

The Workshop on Combustion-Based NOx Controls for Coal-Fired Boilers, formerly the Workshop on NOx Controls for Utility Boilers, was the sixth in a series sponsored by EPRI and offered attendees a comprehensive picture of recent developments and full-scale applications of control technologies for nitrogen oxides (NOx). The workshop took place on October 24-25, 2002, in Atlanta, Georgia.

2003-01-14T23:59:59.000Z

40

Retrofit NOx Control Guidelines for Gas- and Oil-Fired Boilers Version 2.0  

Science Conference Proceedings (OSTI)

This document reviews and summarizes NOx control technologies to help utility engineering and operating staff evaluate and select appropriate retrofit strategies for natural gas- and oil-fired boilers. In addition to general discussions of the various technologies, the document includes an accompanying database on diskette with detailed information on 239 NOx retrofits.

1997-08-19T23:59:59.000Z

Note: This page contains sample records for the topic "nox control technologies" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Multi-Pollutant Emissions Control: Pilot Plant Study of Technologies for Reducing Hg, SO3, NOx and CO2 Emissions  

SciTech Connect

A slipstream pilot plant was built and operated to investigate technology to adsorb mercury (Hg) onto the existing particulate (i.e., fly ash) by cooling flue gas to 200-240 F with a Ljungstrom-type air heater or with water spray. The mercury on the fly ash was then captured in an electrostatic precipitator (ESP). An alkaline material, magnesium hydroxide (Mg(OH){sub 2}), is injected into flue gas upstream of the air heater to control sulfur trioxide (SO{sub 3}), which prevents acid condensation and corrosion of the air heater and ductwork. The slipstream was taken from a bituminous coal-fired power plant. During this contract, Plant Design and Construction (Task 1), Start Up and Maintenance (Task 2), Baseline Testing (Task 3), Sorbent Testing (Task 4), Parametric Testing (Task 5), Humidification Tests (Task 6), Long-Term Testing (Task 7), and a Corrosion Study (Task 8) were completed. The Mercury Stability Study (Task 9), ESP Report (Task 11), Air Heater Report (Task 12) and Final Report (Task 14) were completed. These aspects of the project, as well as progress on Public Outreach (Task 15), are discussed in detail in this final report. Over 90% mercury removal was demonstrated by cooling the flue gas to 200-210 F at the ESP inlet; baseline conditions with 290 F flue gas gave about 26% removal. Mercury removal is sensitive to flue gas temperature and carbon content of fly ash. At 200-210 F, both elemental and oxidized mercury were effectively captured at the ESP. Mg(OH){sub 2} injection proved effective for removal of SO{sub 3} and eliminated rapid fouling of the air heater. The pilot ESP performed satisfactorily at low temperature conditions. Mercury volatility and leaching tests did not show any stability problems. No significant corrosion was detected at the air heater or on corrosion coupons at the ESP. The results justify larger-scale testing/demonstration of the technology. These conclusions are presented and discussed in two presentations given in July and September of 2005 and are included in Appendices E and F.

Michael L. Fenger; Richard A. Winschel

2005-08-31T23:59:59.000Z

42

Control of NOx by combustion process modifications  

E-Print Network (OSTI)

A theoretical and experimental study was carried out to determine lower bounds of NOx emission from staged combustion of a 0.7%N #6 fuel oil. Thermodynamic and chemical kinetic calculations have shown minimum NOx emissions ...

Ber?, J. M.

1981-01-01T23:59:59.000Z

43

NETL: News Release - DOE Selects Five NOx-Control Projects to Combat Acid  

NLE Websites -- All DOE Office Websites (Extended Search)

November 5, 2004 November 5, 2004 DOE Selects Five NOx-Control Projects to Combat Acid Rain and Smog Industry Partners to Focus on Reducing Emissions While Cutting Energy Costs PITTSBURGH, PA - Continuing efforts to cut acid rain and smog-producing nitrogen oxides (NOx) have prompted the U.S. Department of Energy to partner with industry experts to develop advanced NOx-control technologies. With the selection of five new NOx-control projects, the Energy Department continues as a leader in developing advanced technologies to achieve environmental compliance for the nation's fleet of coal-fired power plants. Although today's NOx-control workhorses, such as low-NOx burners and selective catalytic reduction (SCR), have been successfully deployed to address existing regulations, proposed regulations will require deeper cuts in NOx emissions, at a greater number of generating facilities. Many of the smaller affected plants will not be able to cost-effectively use today's technologies; these are the focus of the advanced technologies selected in this announcement.

44

NETL: Mercury Emissions Control Technologies - University of...  

NLE Websites -- All DOE Office Websites (Extended Search)

Using SCR and SNCR NOx Control Technologies Determination of the Speciated Mercury Inventory at Four Coal-Fired Boilers Using Continuous Hg Monitors Longer-Term Testing of...

45

NOx Control Options and Integration for US Coal Fired Boilers  

DOE Green Energy (OSTI)

This is the Final Report for DOE Cooperative Agreement No: DE-FC26-00NT40753. The goal of the project was to develop cost-effective analysis tools and techniques for demonstrating and evaluating low-NOx control strategies and their possible impact on boiler performance for boilers firing US coals. The Electric Power Research Institute (EPRI) provided co-funding for this program. This project included research on: (1) In furnace NOx control; (2) Impacts of combustion modifications on boiler operation; (3) Selective Catalytic Reduction (SCR) catalyst testing and (4) Ammonia adsorption/removal on fly ash. Important accomplishments were achieved in all aspects of the project. Rich Reagent Injection (RRI), an in-furnace NOx reduction strategy based on injecting urea or anhydrous ammonia into fuel rich regions in the lower furnace, was evaluated for cyclone-barrel and PC fired utility boilers. Field tests successfully demonstrated the ability of the RRI process to significantly reduce NOx emissions from a staged cyclone-fired furnace operating with overfire air. The field tests also verified the accuracy of the Computational Fluid Dynamic (CFD) modeling used to develop the RRI design and highlighted the importance of using CFD modeling to properly locate and configure the reagent injectors within the furnace. Low NOx firing conditions can adversely impact boiler operation due to increased waterwall wastage (corrosion) and increased soot production. A corrosion monitoring system that uses electrochemical noise (ECN) corrosion probes to monitor, on a real-time basis, high temperature corrosion events within the boiler was evaluated. Field tests were successfully conducted at two plants. The Ohio Coal Development Office provided financial assistance to perform the field tests. To investigate soot behavior, an advanced model to predict soot production and destruction was implemented into an existing reacting CFD modeling tool. Comparisons between experimental data collected in a pilot scale furnace and soot behavior predicted by the CFD model showed good agreement. Field and laboratory tests were performed for SCR catalysts used for coal and biomass co-firing applications. Fundamental laboratory studies were performed to better understand mechanisms involved with catalyst deactivation. Field tests with a slip stream reactor were used to create catalyst exposed to boiler flue gas for firing coal and for co-firing coal and biomass. The field data suggests the mechanisms leading to catalyst deactivation are, in order of importance, channel plugging, surface fouling, pore plugging and poisoning. Investigations were performed to better understand the mechanisms involved with catalyst regeneration through mechanical or chemical methods. A computer model was developed to predict NOx reduction across the catalyst in a SCR. Experiments were performed to investigate the fundamentals of ammonia/fly ash interactions with relevance to the operation of advanced NOx control technologies such as selective catalytic reduction. Measurements were performed for ammonia adsorption isotherms on commercial fly ash samples subjected to a variety of treatments and on the chemistry of dry and semi-dry ammonia removal processes. This work resulted in the first fundamental ammonia isotherms on carbon-containing fly ash samples. This work confirms industrial reports that aqueous solution chemistry takes place upon the introduction of even very small amounts of water, while the ash remains in a semi-dry state.

Mike Bockelie; Marc Cremer; Kevin Davis; Martin Denison; Adel Sarofim; Connie Senior; Hong-Shig Shim; Dave Swenson; Bob Hurt; Eric Suuberg; Eric Eddings; Kevin Whitty; Larry Baxter; Calvin Bartholomew; William Hecker

2006-06-30T23:59:59.000Z

46

Air Pollution Control Regulations: No. 41 - Nox Budget Trading Program  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

41 - Nox Budget Trading 41 - Nox Budget Trading Program (Rhode Island) Air Pollution Control Regulations: No. 41 - Nox Budget Trading Program (Rhode Island) < Back Eligibility Commercial Industrial Investor-Owned Utility Municipal/Public Utility Rural Electric Cooperative Utility Savings Category Alternative Fuel Vehicles Hydrogen & Fuel Cells Program Info State Rhode Island Program Type Environmental Regulations Provider Department of Environmental Management These regulations establish a budget trading program for nitrogen oxide emissions, setting NOx budget units for generators and an NOx Allowance Tracking System to account for emissions. These regulations apply to units that serve generators with a nameplate capacity greater than 15 MWe and sell any amount of electricity, as well as to units that have a maximum

47

Three-Dimensional Composite Nanostructures for Lean NOx Emission Control  

SciTech Connect

This final report to the Department of Energy (DOE) and National Energy Technology Laboratory (NETL) for DE-EE0000210 covers the period from October 1, 2009 to July 31, 2013. Under this project, DOE awarded UConn about $1,248,242 to conduct the research and development on a new class of 3D composite nanostructure based catalysts for lean NOx emission control. Much of the material presented here has already been submitted to DOE/NETL in quarterly technical reports. In this project, through a scalable solution process, we have successfully fabricated a new class of catalytic reactors, i.e., the composite nanostructure array (nano-array) based catalytic converters. These nanocatalysts, distinct from traditional powder washcoat based catalytic converters, directly integrate monolithic substrates together with nanostructures with well-defined size and shape during the scalable hydrothermal process. The new monolithic nanocatalysts are demonstrated to be able to save raw materials including Pt-group metals and support metal oxides by an order of magnitude, while perform well at various oxidation (e.g., CO oxidation and NO oxidation) and reduction reactions (H{sub 2} reduction of NOx) involved in the lean NOx emissions. The size, shape and arrangement of the composite nanostructures within the monolithic substrates are found to be the key in enabling the drastically reduced materials usage while maintaining the good catalytic reactivity in the enabled devices. The further understanding of the reaction kinetics associated with the unique mass transport and surface chemistry behind is needed for further optimizing the design and fabrication of good nanostructure array based catalytic converters. On the other hand, the high temperature stability, hydrothermal aging stability, as well as S-poisoning resistance have been investigated in this project on the nanocatalysts, which revealed promising results toward good chemical and mechanical robustness, as well as S-poisoning resistance. Further investigation is needed for unraveling the understanding, design and selection principles of this new class of nanostructure based monolithic catalysts.

Gao, Pu-Xian

2013-07-31T23:59:59.000Z

48

Nitrogen Oxides (NOx), Why and How They are Controlled  

NLE Websites -- All DOE Office Websites (Extended Search)

Air Quality EPA 456/F-99-006R Air Quality EPA 456/F-99-006R Environmental Protection Planning and Standards November 1999 Agency Research Triangle Park, NC 27711 Air EPA-456/F-99-006R November 1999 Nitrogen Oxides (NOx), Why and How They Are Controlled Prepared by Clean Air Technology Center (MD-12) Information Transfer and Program Integration Division Office of Air Quality Planning and Standards U.S. Environmental Protection Agency Research Triangle Park, North Carolina 27711 ii DISCLAIMER This report has been reviewed by the Information Transfer and Program Integration Division of the Office of Air Quality Planning and Standards, U.S. Environmental Protection Agency and approved for publication. Approval does not signify that the contents of this report reflect the views and policies of the U.S. Environmental Protection Agency. Mention of trade

49

NATURAL GAS REBURNING TECHNOLOGY FOR NOx REDUCTION FROM MSW COMBUSTION SYSTEMS  

E-Print Network (OSTI)

NATURAL GAS REBURNING TECHNOLOGY FOR NOx REDUCTION FROM MSW COMBUSTION SYSTEMS ABSTRACf CRAIG A series, injection of up to 15% (HHV basis) natural gas reduced NOx by 50-70% while maintain ing, Illinois DAVID G. LINZ Gas Research Institute Chicago, Illinois ducing NOx emISSIons from municipal solid

Columbia University

50

NOx Control Options and Integration for US Coal Fired Boilers  

DOE Green Energy (OSTI)

This is the fourteenth Quarterly Technical Report for DOE Cooperative Agreement No: DEFC26-00NT40753. The goal of the project is to develop cost effective analysis tools and techniques for demonstrating and evaluating low NOx control strategies and their possible impact on boiler performance for boilers firing US coals. The Electric Power Research Institute (EPRI) is providing co-funding for this program. Using the initial CFD baseline modeling of the Gavin Station and the plant corrosion maps, six boiler locations for the corrosion probes were identified and access ports have been installed. Preliminary corrosion data obtained appear consistent and believable. In situ, spectroscopic experiments at BYU reported in part last quarter were completed. New reactor tubes have been made for BYU's CCR that allow for testing smaller amounts of catalyst and thus increasing space velocity; monolith catalysts have been cut and a small reactor that can accommodate these pieces for testing is in its final stages of construction. A poisoning study on Ca-poisoned catalysts was begun this quarter. A possible site for a biomass co-firing test of the slipstream reactor was visited this quarter. The slipstream reactor at Rockport required repair and refurbishment, and will be re-started in the next quarter. This report describes the final results of an experimental project at Brown University on the fundamentals of ammonia / fly ash interactions with relevance to the operation of advanced NOx control technologies such as selective catalytic reduction. The Brown task focused on the measurement of ammonia adsorption isotherms on commercial fly ash samples subjected to a variety of treatments and on the chemistry of dry and semi-dry ammonia removal processes.

Mike Bockelie; Kevin Davis; Temi Linjewile; Connie Senior; Eric Eddings; Kevin Whitty; Larry Baxter; Calvin Bartholomew; William Hecker; Stan Harding; Robert Hurt

2003-12-31T23:59:59.000Z

51

Reduce NOx and Improve Energy Efficiency, Software Tools for Industry, Industrial Technologies Program (ITP) (Fact Sheet)  

SciTech Connect

This fact sheet describes how the Industrial Technologies Program NOx and Energy Assessment Tool (NxEAT) can help petroleum refining and chemical plants improve energy efficiency.

2008-12-01T23:59:59.000Z

52

NOx Control for Utility Boiler OTR Compliance  

SciTech Connect

Babcock & Wilcox Power Generation Group (B&W) and Fuel Tech, Inc. (Fuel Tech) teamed to evaluate an integrated solution for NO{sub x} control comprised of B&W's DRB-4Z{reg_sign} low-NO{sub x} pulverized coal (PC) burner technology and Fuel Tech's NO{sub x}OUT{reg_sign}, a selective non-catalytic reduction (SNCR) technology, capable of meeting a target emission limit of 0.15 lb NO{sub x}/10{sup 6} Btu. In a previous project sponsored by the U.S. Department of Energy (DOE), promising results were obtained with this technology from large-scale testing in B&W's 100-million Btu/hr Clean Environment Development Facility (CEDF) which simulates the conditions of large coal-fired utility boilers. Under the most challenging boiler temperatures at full load conditions, NO{sub x} emissions of 0.19 lb/10{sup 6} Btu were achieved firing Powder River Basin coal while controlling ammonia slip to less than 5 ppm. At a 40 million Btu/hr firing rate, NO{sub x} emissions were as low as 0.09 lb/10{sup 6} Btu. Improved performance with this system was proposed for this new program with injection at full load via a convective pass multiple nozzle lance (MNL) in front of the superheater tubes or in the convective tube bank. Convective pass lances represent the current state-of-the-art in SNCR and needed to be evaluated in order to assess the full potential of the combined technologies. The objective of the program was to achieve a NO{sub x} level below 0.15 lb/10{sup 6} Btu (with ammonia slip of less than 5 ppm) in the CEDF using PRB coal and B&W's DRB-4Z{reg_sign} low-NO{sub x} pulverized coal (PC) burner in combination with dual zone overfire air ports and Fuel Tech's NO{sub x}OUT{reg_sign} System. Commercial installations of B&W's low-NO{sub x} burner, in combination with overfire air ports using PRB coal, have demonstrated a NO{sub x} level of 0.15 to 0.2 lb/10{sup 6} Btu under staged combustion conditions. The proposed goal of the combustion system (no SNCR) for this project is a NO{sub x} level at 0.15 lb/10{sup 6} Btu. The NO{sub x} reduction goal for SNCR is 25% from the low-NO{sub x} combustion emission levels. Therefore, overall NO{sub x} emissions would approach a level of 0.11 lb/10{sup 6} Btu in commercial installation. The goals of the program were met. At 100% load, using the MNL for very low baseline NO{sub x} (0.094 to 0.162 lb/10{sup 6} Btu depending on burner stoichiometry), an approximately 25% NO{sub x} reduction was achieved (0.071 to 0.124 lb/10{sup 6} Btu) while maintaining NH{sub 3} slip less than 6.4 ppm. At 60% load, using MNL or only wall-injectors for very low baseline NO{sub x} levels, more than 30% NO{sub x} reduction was achieved. Although site specific economic evaluation is required for each unit, our economic evaluation of DRB-4Z{reg_sign} burner and SNCR for a 500 MW{sub e} plant firing PRB shows that the least cost strategy is low-NO{sub x} burner and OFA at a cost of $210 to $525 per ton of NO{sub x} removed. Installation of SNCR allows the utilities to sell more NO{sub x} credit and it becomes economical when NO{sub x} credit cost is more than $5,275 per ton of NO{sub x}.

Hamid Farzan; Jennifer L. Sivy

2005-07-30T23:59:59.000Z

53

A Novel Technology for the Reduction of NOx on Char by Microwaves  

E-Print Network (OSTI)

The emphasis on reduction of NOx as a precursor to street level ozone has increased the need for technologies capable of reducing NOx (>95%) to very low levels in major metropolitan areas from a wide variety of sources. Technology offerings available today may not always be appropriate for every desired application in the utility and industrial sectors. This paper will discuss a new technology under development that has promise to address many of the specialized needs of some of these applications. The technology is directed at NOx reduction but may also address other pollutants like SO2. The technology employees char, a heat treated and devolitilized form of coal, to adsorb NOx from the flue (or waste) gas. Adsorption of greater than 99% has been demonstrated on a lab scale and appears very feasible for scale-up. Microwave energy properly applied to the char loaded with NOx converts the NOx via carbon reduction to nitrogen and carbon dioxide. The role of microwave energy in the efficient destruction of the NOx selectively to nitrogen and CO2 differentiates this technology from other technologies that may generate significant byproducts like CO or N2O. The basic principles of the technology, applications where it is appropriate, and a comparison to other NOx technologies are included in the paper as well as the developmental status and plans.

Buenger, C.; Peterson, E.

1994-04-01T23:59:59.000Z

54

NOxControl revised.p65  

NLE Websites -- All DOE Office Websites (Extended Search)

technologies, GR and LNBs. GR complements LNB by allowing it to operate at low stoichiometric ra- tios, enabling low NO x emissions without exceeding ac- ceptable CO and UBC...

55

Demonstration of a NOx Control System for Stationary Diesel Engines  

Science Conference Proceedings (OSTI)

California has over 26,000 stationary diesel engines, mostly in emergency power and direct drive applications. In the past few years, various incentive programs in the state have resulted in the change-out of older, dirtier engines for newer, cleaner models or replacement with electric motors. Emissions reductions can be accomplished by equipping existing engines with controls for nitrogen oxides (NOx) and particulate matter (PM). The retrofit systems currently available, however, either are not cost com...

2005-06-30T23:59:59.000Z

56

Cyclone Boiler Reburn NOx Control Improvements via Cyclone Design Improvements and Advanced Air Staging  

E-Print Network (OSTI)

Eastman Kodak owns three Babcock & Wilcox coal fired cyclone boilers and one Combustion Engineering pulverized coal boiler located at Kodak Park in Rochester, New York. Duke Energy Generation Services (DEGS) operates and maintains the steam and electric generation equipment for Kodak and has primary responsibility for related capital project development and execution. The Kodak plant is capable of generating approximately 1,900,000 pounds of steam and 130 MWs of electrical power. To achieve the required level of NOx control, Kodak chose The Babcock & Wilcox (B&W) Company's, Natural Gas Reburn technology for the three cyclone boilers. The relatively low capital cost of the system and reasonable cost of natural gas in the mid 1990s made Natural Gas Reburn an economic fit for the RACT requirements of 0.60#s/Mmbtu NOx. The run up in natural gas prices since 2002 has increased the cost of NOx removed from ~ $2000/ton to ~$5000/ton based on fuel expense alone. In an effort to curtail the cost of control, Duke Energy Generations Services and Kodak implemented a series of projects that integrated Cyclone Design Improvements and Advancements in Air Staging along with ESP inlet flue modifications that resulted in decreasing the Natural Gas required for NOx control ~ 40% from baseline levels saving the plant several million dollars per year in fuel expense. Significant improvements in opacity and filterable PM were also realized by these changes.

Morabito, B.; Nee, B.; Goff, V.; Maringo, G.

2008-01-01T23:59:59.000Z

57

A Fundamental Consideration on NOx Adsorber Technology for DI Diesel Application  

DOE Green Energy (OSTI)

Diesel engines are far more efficient than gasoline engines of comparable size, and emit less greenhouse gases that have been implicated in global warming. In 2000, the US EPA proposed very stringent emissions standards to be introduced in 2007 along with low sulfur (< 15 ppm) diesel fuel. The California Air Resource Board (CARB) has also established the principle that future diesel fueled vehicles should meet the same low emissions standards as gasoline fueled vehicles and the EPA followed suit with its Tier II emissions regulation. Achieving such low emissions cannot be done through engine development and fuel reformulation alone, and requires application of NOx and particulate matter (PM) aftertreatment control devices. There is a widespread consensus that NOx adsorbers and particulate filter are required in order for diesel engines to meet the 2007 emissions regulations for NOx and PM. In this paper, the key exhaust characteristics from an advanced diesel engine are reviewed. Development of the NOx adsorber technology is discussed. Spectroscopic techniques are applied to understand the underlying chemical reactions over the catalyst surface during NOx trapping and regeneration periods. In-situ surface probes are useful in providing not only thermodynamic and kinetics information required for model development but also a fundamental understanding of storage capacity and degradation mechanisms. The distribution of various nitration/sulfation species is related to surface basicity. Surface displacement reactions of carbonates also play roles in affecting the trapping capability of NOx adsorbers. When ultralow-S fuel is used as a reductant during the regeneration, sulfur induced performance degradation is still observed in an aged catalyst. Other possible sources related to catalyst deactivation include incomplete reduction of surface nitration, coke formation derived from incomplete hydrocarbon burning, and lubricant formulations. Sulfur management and the direction of future work for the successful implementation of such integrated engine and aftertreatment technology are discussed. SAE Paper SAE-2002-01-2889 {copyright} 2002 SAE International. This paper is published on this website with permission from SAE International. As a user of this website, you are permitted to view this paper on-line, download this pdf file and print one copy of this paper at no cost for your use only. The downloaded pdf file and printout of this SAE paper may not be copied, distributed or forwarded to others or for the use of others.

Fang, Howard L.; Huang, Shyan C.; Yu, Robert C. (Cummins, Inc.); Wan, C. Z. (Engelhard Corp.); Howden, Ken (U.S. Dept. of Energy)

2002-10-01T23:59:59.000Z

58

NATURAL GAS REBURNING TECHNOLOGY FOR NOx REDUCTION FROM MSW COMBUSTION SYSTEMS  

E-Print Network (OSTI)

NATURAL GAS REBURNING TECHNOLOGY FOR NOx REDUCTION FROM MSW COMBUSTION SYSTEMS Discussion by CRAIG's increased turbulent mixing is on the CO profile and what the incremental NOx reduction experienced was from that this alone would contribute to a significant reduction in the NO", generated. The authors are careful

Columbia University

59

LBNL's Low-NOx Combustion Technologies for Heat and Power Generation  

NLE Websites -- All DOE Office Websites (Extended Search)

Us Department Contacts Media Contacts LBNL's Low-NOx Combustion Technologies for Heat and Power Generation Speaker(s): Robert Cheng Date: February 2, 1999 - 12:00pm Location: Bldg....

60

Active NOX Control of Cogen Gas Turbine Exhaust using a Nonlinear Feed Forward with Cascade Architecture  

E-Print Network (OSTI)

Active NOX Control of Cogen Gas Turbine Exhaust using a Nonlinear Feed Forward with Cascade control, cogeneration, gas turbine, model based control, feed forward, cascade ABSTRACT Presented is a model based strategy for controlling the NOX concentration of natural gas turbine emissions

Cooper, Doug

Note: This page contains sample records for the topic "nox control technologies" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Assessment of Impacts of NOx Reduction Technologies on Coal Ash Use: Volume 1: North American Perspective  

Science Conference Proceedings (OSTI)

This two-volume report provides documentation about physical and chemical effects combustion and post-combustion low-NOx technologies have on coal fly ash. U.S., European, and, to a lesser degree, Japanese experience is discussed. The report assesses the effect of low-NOx technologies on fly ash markets in a general manner. Options for beneficiating fly ash for specific markets also appear.

1997-01-04T23:59:59.000Z

62

2004 Conference on Reburning for NOX Control Reburning on Trial  

NLE Websites -- All DOE Office Websites (Extended Search)

2004 Conf. on Reburning for NOx Control Reburning on Trial 2004 Conf. on Reburning for NOx Control Reburning on Trial May 18, 2004 Table of Contents Disclaimer Papers and Presentations Reburning Overview Commercial Reburning Experience Biomass Reburning Other Applications of Reburning Posters Disclaimer This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government or any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. Reference herein to any specific commercial product, process, or service by trade name, trademark, manufacturer, or otherwise does not necessarily constitute or imply its endorsement, recommendation, or favoring by the United States Government or any agency thereof. The views and opinions of authors expressed herein do not necessarily state or reflect those of the United States Government or any agency thereof.

63

NOx CONTROL OPTIONS AND INTEGRATION FOR US COAL FIRED BOILERS  

SciTech Connect

This is the fifth Quarterly Technical Report for DOE Cooperative Agreement No: DE-FC26-00NT40753. The goal of the project is to develop cost effective analysis tools and techniques for demonstrating and evaluating low NOx control strategies and their possible impact on boiler performance for firing US coals. The Electric Power Research Institute (EPRI) is providing cofunding for this program. This program contains multiple tasks and good progress is being made on all fronts. Field tests for NOx reduction in a cyclone fired utility boiler due to using Rich Reagent Injection (RRI) have been started. CFD modeling studies have been started to evaluate the use of RRI for NOx reduction in a corner fired utility boiler using pulverized coal. Field tests of a corrosion monitor to measure waterwall wastage in a utility boiler have been completed. Computational studies to evaluate a soot model within a boiler simulation program are continuing. Research to evaluate SCR catalyst performance has started. A literature survey was completed. Experiments have been outlined and two flow reactor systems have been designed and are under construction. Commercial catalyst vendors have been contacted about supplying catalyst samples. Several sets of new experiments have been performed to investigate ammonia removal processes and mechanisms for fly ash. Work has focused on a promising class of processes in which ammonia is destroyed by strong oxidizing agents at ambient temperature during semi-dry processing (the use of moisture amounts less than 5 wt-%). Both ozone and an ozone/peroxide combination have been used to treat both basic and acidic ammonia-laden ashes.

Mike Bockelie; Marc Cremer; Kevin Davis; Connie Senior; Bob Hurt; Eric Eddings; Larry Baxter

2001-10-10T23:59:59.000Z

64

NETL: Clean Coal Technology Demonstration Program (CCTDP) - Round...  

NLE Websites -- All DOE Office Websites (Extended Search)

4 Environmental Control Technologies - NOx Control Technologies Micronized Coal Reburning Demonstration for NOx Control - Project Brief PDF-245KB New York State Electric & Gas...

65

NETL: Clean Coal Technology Demonstration Program (CCTDP) - Round...  

NLE Websites -- All DOE Office Websites (Extended Search)

Control Technologies - NOx Control Technologies Integrated Dry NOxSO2 Emissions Control System - Project Brief PDF-267KB Public Service Company of Colorado, Denver, CO...

66

NOx Control Options and Integration for US Coal Fired Boilers  

Science Conference Proceedings (OSTI)

This is the twelfth Quarterly Technical Report for DOE Cooperative Agreement No: DE-FC26-00NT40753. The goal of the project is to develop cost effective analysis tools and techniques for demonstrating and evaluating low NOx control strategies and their possible impact on boiler performance for boilers firing US coals. The Electric Power Research Institute (EPRI) is providing co-funding for this program. This program contains multiple tasks and good progress is being made on all fronts. During this quarter, a new effort was begun on the development of a corrosion management system for minimizing the impacts of low NOx combustion systems on waterwalls; a kickoff meeting was held at the host site, AEP's Gavin Plant, and work commenced on fabrication of the probes. FTIR experiments for SCR catalyst sulfation were finished at BYU and indicated no vanadium/vanadyl sulfate formation at reactor conditions. Improvements on the mass-spectrometer system at BYU have been made and work on the steady state reactor system shakedown neared completion. The slipstream reactor continued to operate at AEP's Rockport plant; at the end of the quarter, the catalysts had been exposed to flue gas for about 1000 hours. Some operational problems were addressed that enable the reactor to run without excessive downtime by the end of the quarter.

Mike Bockelie; Kevin Davis; Temi Linjewile; Connie Senior; Eric Eddings; Kevin Whitty; Larry Baxter; Calvin Bartholomew; William Hecker; Stan Harding

2003-06-30T23:59:59.000Z

67

An Assessment of Alternative NOx Monitoring Technologies for Coal-Fired Boiler Applications  

Science Conference Proceedings (OSTI)

This report reviews the applicability of alternate measurement technologies to measure NOx in coal-fired boiler applications using optical techniques in general, and tunable diode laser spectroscopy in particular. Increasingly stringent regulations of NOx emission limits on this class of boilers make accurate, reliable, cost effective measurement techniques of growing importance. Existing commercial instrumentation used for CEMS applications, do not entirely satisfy industry requirements and needs for pr...

2005-12-12T23:59:59.000Z

68

Urea for SCR-based NOx Control Systems and Potential Impacts to Ground Water Resources  

DOE Green Energy (OSTI)

One of the key challenges facing manufacturers of diesel engines for light- and heavy-duty vehicles is the development of technologies for controlling emissions of nitrogen oxides, In this regard, selective catalytic reduction (SCR) systems represent control technology that can potentially achieve the NOx removal efficiencies required to meet new U.S. EPA standards. SCR systems rely on a bleed stream of urea solution into exhaust gases prior to catalytic reduction. While urea's role in this emission control technology is beneficial, in that it supports reduced NOx emissions, it can also be an environmental threat to ground water quality. This would occur if it is accidentally released to soils because once in that environmental medium, urea is subsequently converted to nitrate--which is regulated under the U.S. EPA's primary drinking water standards. Unfortunately, nitrate contamination of ground waters is already a significant problem across the U.S. Historically, the primary sources of nitrate in ground waters have been septic tanks and fertilizer applications. The basic concern over nitrate contamination is the potential health effects associated with drinking water containing elevated levels of nitrate. Specifically, consumption of nitrate-contaminated water can cause a blood disorder in infants known as methemoglobinemia.

Layton, D.

2002-01-03T23:59:59.000Z

69

Additives for NOx emissions control from fixed sources. Final report, Aug 88-Feb 89  

SciTech Connect

This project tested several additives and catalysts as potential additive/catalyst combinations for a new NOx abatement process. The goal was to identify an effective, economical NOx emissions control process for application to post combustion, exhaust gas streams from jet engine test cells (JETC) and incinerators. The most useful results from this project are that: (1) an additive was identified that achieved gas-phase removal, with no catalyst, of NOx at temperatures as low as 350 deg C, and (2) good NOx removals can be achieved with additive: NOx ratios less than one. These results offer good possibilities for new low-temperature (350 to 500 deg C) gas phase NOx reduction processes of the selective noncatalytic reduction (SNR) type for both JETCs and incinerators.

Ham, D.O.; Moniz, G.; Gouveia, M.

1989-12-01T23:59:59.000Z

70

Modeling Species Inhibition of NO Oxidation in Urea-SCR Catalysts for Diesel Engine NOx Control  

DOE Green Energy (OSTI)

Urea-selective catalytic reduction (SCR) catalysts are regarded as the leading NOx aftertreatment technology to meet the 2010 NOx emission standards for on-highway vehicles running on heavy-duty diesel engines. However, issues such as low NOx conversion at low temperature conditions still exist due to various factors, including incomplete urea thermolysis, inhibition of SCR reactions by hydrocarbons and H2O. We have observed a noticeable reduction in the standard SCR reaction efficiency at low temperature with increasing water content. We observed a similar effect when hydrocarbons are present in the stream. This effect is absent under fast SCR conditions where NO ~ NO2 in the feed gas. As a first step in understanding the effects of such inhibition on SCR reaction steps, kinetic models that predict the inhibition behavior of H2O and hydrocarbons on NO oxidation are presented in the paper. A one-dimensional SCR model was developed based on conservation of species equations and was coded as a C-language S-function and implemented in Matlab/Simulink environment. NO oxidation and NO2 dissociation kinetics were defined as a function of the respective adsorbates storage in the Fe-zeolite SCR catalyst. The corresponding kinetic models were then validated on temperature ramp tests that showed good match with the test data. Such inhibition models will improve the accuracy of model based control design for integrated DPF-SCR aftertreatment systems.

Devarakonda, Maruthi N.; Tonkyn, Russell G.; Tran, Diana N.; Lee, Jong H.; Herling, Darrell R.

2011-04-20T23:59:59.000Z

71

Controlling diesel NOx & PM emissions using fuel components and enhanced aftertreatment techniques: developing the next generation emission control system.  

E-Print Network (OSTI)

??The following research thesis focuses on methods of controlling nitrogen oxides (NO(X)) and particulate matter (PM) emissions emitted from a low temperature diesel exhaust. This (more)

Gill, Simaranjit Singh

2012-01-01T23:59:59.000Z

72

COST-EFFECTIVE CONTROL OF NOx WITH INTEGRATED ULTRA LOW-NOx BURNERS AND SNCR  

SciTech Connect

Coal-fired electric utilities are facing a serious challenge with regards to curbing their NO{sub x} emissions. At issue are the NO{sub x} contributions to the acid rain, ground level ozone, and particulate matter formation. Substantial NO{sub x} control requirements could be imposed under the proposed Ozone Transport Rule, National Ambient Air Quality Standards, and New Source Performance Standards. McDermott Technology, Inc. (MTI), Babcock and Wilcox (B and W), and Fuel Tech are teaming to provide an integrated solution for NO{sub x} control. The system will be comprised of an ultra low-NO{sub x} pulverized coal (PC) burner technology plus a urea-based, selective non-catalytic reduction (SNCR) system. This system will be capable of meeting a target emission limit of 0.15 lb NO{sub x}/10{sup 6} Btu and target ammonia (NH3) slip level targeted below 5 ppmV for commercial units. Our approach combines the best available combustion and post-combustion NO{sub x} control technologies. More specifically, B and W's DRB-4Z TM ultra low-NO{sub x} PC burner technology will be combined with Fuel Tech's NO{sub x}OUT (SNCR) and NO{sub x}OUT Cascade (SNCR/SCR hybrid) systems and jointly evaluated and optimized in a state-of-the-art test facility at MTI. Although the NO{sub x}OUT Cascade (SNCR/SCR hybrid) system will not be tested directly in this program, its potential application for situations that require greater NO{sub x} reductions will be inferred from other measurements (i.e., SNCR NO{sub x} removal efficiency plus projected NO{sub x} reduction by the catalyst based on controlled ammonia slip). Our analysis shows that the integrated ultra low-NO{sub x} burner and SNCR system has the lowest cost when the burner emissions are 0.25 lb NO{sub x}/10{sup 6} Btu or less. At burner NO{sub x} emission level of 0.20 lb NO{sub x}/10{sup 6} Btu, the levelized cost per ton of NO{sub x} removed is 52% lower than the SCR cost.

Hamid Farzan

2001-07-01T23:59:59.000Z

73

Assessment of Impacts of Retrofit NOx Controls on Gas/Oil Boilers  

Science Conference Proceedings (OSTI)

In 1997, when EPRI issued the version 2 of its Retrofit NOx Control Guidelines for Gas- and Oil-Fired Boilers (EPRI report TR-108181), it was thought the most common NOx controls installed on gas and oil-fired boilers would include low NOx burners; selective catalytic reduction (SCR); and other vendor supplied, hardware-intensive approaches. In the years that followed, however, most of the gas and oil power generating fleet opted for less hardware intensive, more cost-effective approaches, with Induced F...

2007-02-07T23:59:59.000Z

74

The evolution of NOx control policy for coal-fired power plants in the United States  

Science Conference Proceedings (OSTI)

Emissions of nitrogen oxides (NOx) contribute to formation of particulate matter and ozone, and also to acidification of the environment. The electricity sector is responsible for about 20% of NOx emissions in the United States, and the sector has been the target of both prescriptive (command-and-control) and flexible (cap-and-trade) approaches to regulation. The paper summarises the major NOx control policies affecting this sector in the USA, and provides some perspectives as to their effectiveness. While both prescriptive and flexible approaches continue to play an important role, significant new proposals have wholly embraced a cap-and-trade approach. 20 refs., 7 figs., 2 tabs.

Dallas Burtraw; David A. Evans

2003-12-15T23:59:59.000Z

75

Retrofit NOx Controls for Coal-Fired Utility Boilers - 2000 Update  

Science Conference Proceedings (OSTI)

During the last four years (1996-2000), NOx control retrofits increased significantly in response to further tightening of NOx regulations. Approximately one hundred complete burner retrofits of wall- and T-fired boilers were implemented during this period, bringing the total burner retrofits to 357. Also, 32 burner component modification BCM) projects were implemented. Other control options included combustion optimization in more than two hundred boilers, thirteen reburns, five selective non-catalytic ...

2000-12-15T23:59:59.000Z

76

NOx Control Options and Integration for US Coal Fired Boilers  

SciTech Connect

This is the sixteenth Quarterly Technical Report for DOE Cooperative Agreement No: DEFC26-00NT40753. The goal of the project is to develop cost effective analysis tools and techniques for demonstrating and evaluating low NOx control strategies and their possible impact on boiler performance for boilers firing US coals. The Electric Power Research Institute (EPRI) is providing co-funding for this program. During an unplanned outage, damage occurred to the electrochemical noise corrosion probes installed at the AEP Gavin plant; testing is expected to resume in August. The KEMCOP corrosion coupons were not affected by the unplanned outage; the coupons were removed and sent for analysis. BYU conducted a series of tests before the ISSR lab was relocated. Ammonia adsorption experiments provided clear evidence of the types of acidic sites present on catalyst surfaces. Data collected this quarter indicate that surface sulfation decreases Lewis acid site concentrations for all catalysts thus far studied, confirming that catalytic activity under commercial coal-based SCR conditions occurs primarily on Br{o}nsted acid sites and would be susceptible to basic impurities such as alkali and alkaline earth oxides, chlorides, and sulfates. SCR activity tests based on MS analysis showed that increasing sulfation generally increases NO reduction activity for both 0% and 1% vanadia catalysts. During this quarter, the slipstream reactor at Rockport operated for 720 hours on flue gas. Catalyst exposure time reached 4500 hours since installation. The reactor is out of service at the Rockport plant and plans are being made to move it to the Gadsden Plant. At Gadsden, modifications have begun in preparation for installation of the slipstream reactor next quarter.

Mike Bockelie; Kevin Davis; Temi Linjewile; Connie Senior; Eric Eddings; Kevin Whitty; Larry Baxter; Calvin Bartholomew; William Hecker; Stan Harding

2004-06-30T23:59:59.000Z

77

COST-EFFECTIVE CONTROL OF NOX WITH INTEGRATED ULTRA LOW-NOX BURNERS AND SNCR  

Science Conference Proceedings (OSTI)

The objective of this project is to develop an environmentally acceptable and cost-effective NO{sub x} control system that can achieve less than 0.15 lb NO{sub x}/10{sup 6} Btu for a wide range of coal-burning commercial boilers. The system will be comprised of an ultra low-NO{sub x} PC burner technology plus a urea-based, selective non-catalytic reduction (SNCR) system. In addition to the above stated NO{sub x} limit of 0.15 lb NO{sub x}/10{sup 6} Btu, ammonia (NH{sub 3}) slip levels will be targeted below 5 ppmV for commercial units. Testing will be performed in the 100 million Btu/hr Clean Environment Development Facility (CEDF) in Alliance, Ohio. Finally, by amendment action, a limited mercury measurement campaign was conducted to determine if the partitioning and speciation of mercury in the flue gas from a Powder River Basin coal is affected by the addition of Chlorides to the combustion zone.

Hamid Farzan

2001-10-01T23:59:59.000Z

78

Cost analysis of NOx control alternatives for stationary gas turbines  

SciTech Connect

The use of stationary gas turbines for power generation has been growing rapidly with continuing trends predicted well into the future. Factors that are contributing to this growth include advances in turbine technology, operating and siting flexibility and low capital cost. Restructuring of the electric utility industry will provide new opportunities for on-site generation. In a competitive market, it maybe more cost effective to install small distributed generation units (like gas turbines) within the grid rather than constructing large power plants in remote locations with extensive transmission and distribution systems. For the customer, on-site generation will provide added reliability and leverage over the cost of purchased power One of the key issues that is addressed in virtually every gas turbine application is emissions, particularly NO{sub x} emissions. Decades of research and development have significantly reduced the NO{sub x} levels emitted from gas turbines from uncontrolled levels. Emission control technologies are continuing to evolve with older technologies being gradually phased-out while new technologies are being developed and commercialized. The objective of this study is to determine and compare the cost of NO{sub x} control technologies for three size ranges of stationary gas turbines: 5 MW, 25 MW and 150 MW. The purpose of the comparison is to evaluate the cost effectiveness and impact of each control technology as a function of turbine size. The NO{sub x} control technologies evaluated in this study include: Lean premix combustion, also known as dry low NO{sub x} (DLN) combustion; Catalytic combustion; Water/steam injection; Selective catalytic reduction (SCR)--low temperature, conventional, high temperature; and SCONO{sub x}{trademark}.

Bill Major

1999-11-05T23:59:59.000Z

79

Retrofit NOx Control Guidelines for Gas- and Oil-Fired Boilers  

Science Conference Proceedings (OSTI)

Ground-level ozone concentrations continue to exceed the federal health-based standard in many parts of the country, especially urban areas. This condition led Congress to include in the Clean Air Act Amendments of 1990 a requirement that states with nonattainment regions implement regulations to reduce NOx from all sources, including utility boilers. By providing a summary and analysis of all the available information on NOx control techniques for gas-and oil-fired boilers, this document can help utilit...

1994-01-01T23:59:59.000Z

80

Heavy-Duty Emissions Control: Plasma-Facilitated vs Reformer-Assisted Lean NOx Catalysis  

DOE Green Energy (OSTI)

Progress has been made in the control of combustion processes to limit the formation of environmentally harmful species, but lean burn vehicles, such as those powered by diesel engines used for the majority of commercial trucking and off-road applications, remain a major source of nitrogen oxides (NOx) and particulate matter (PM) emissions. Tighter control of the combustion process coupled with exhaust gas recirculation has brought emissions in line with 2004 targets worldwide. Additional modifications to the engine control system, somewhat limited NOx control, and PM filters will likely allow the 2007 limits to be met for the on-highway regulations for heavy-duty engines in the United States. Concern arises when the NOx emission limit of 0.2 g/bhphr set for the year 2010 is considered.

(1)Aardahl, C; (1)Rozmiarek, R; (1)Rappe, K; (1)Mendoza, D (2)Park, P

2003-08-24T23:59:59.000Z

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81

HYDROGEN GENERATION FROM PLASMATRON REFORMERS: A PROMISING TECHNOLOGY FOR NOX ADSORBER REGENERATION AND OTHER AUTOMOTIVE APPLICATIONS  

DOE Green Energy (OSTI)

Plasmatron reformers are being developed at MIT and ArvinMeritor [1]. In these reformers a special low power electrical discharge is used to promote partial oxidation conversion of hydrocarbon fuels into hydrogen and CO. The partial oxidation reaction of this very fuel rich mixture is difficult to initiate. The plasmatron provides continuous enhanced volume initiation. To minimize electrode erosion and electrical power requirements, a low current, high voltage discharge with wide area electrodes is used. The reformers operate at or slightly above atmospheric pressure. Plasmatron reformers provide the advantages of rapid startup and transient response; efficient conversion of the fuel to hydrogen rich gas; compact size; relaxation or elimination of reformer catalyst requirements; and capability to process difficult to reform fuels, such as diesel and bio-oils. These advantages facilitate use of onboard hydrogen-generation technology for diesel exhaust after-treatment. Plasma-enhanced reformer technology can provide substantial conversion even without the use of a catalyst. Recent progress includes a substantial decrease in electrical power consumption (to about 200 W), increased flow rate (above 1 g/s of diesel fuel corresponding to approximately 40 kW of chemical energy), soot suppression and improvements in other operational features.. Plasmatron reformer technology has been evaluated for regeneration of NOx adsorber after-treatment systems. At ArvinMeritor tests were performed on a dual-leg NOx adsorber system using a Cummins 8.3L diesel engine both in a test cell and on a vehicle. A NOx adsorber system was tested using the plasmatron reformer as a regenerator and without the reformer i.e., with straight diesel fuel based regeneration as the baseline case. The plasmatron reformer was shown to improve NOx regeneration significantly compared to the baseline diesel case. The net result of these initial tests was a significant decrease in fuel penalty, roughly 50% at moderate adsorber temperatures. This fuel penalty improvement is accompanied by a dramatic drop in slipped hydrocarbon emissions, which decreased by 90% or more. Significant advantages are demonstrated across a wide range of engine conditions and temperatures. The study also indicated the potential to regenerate NOx adsorbers at low temperatures where diesel fuel based regeneration is not effective, such as those typical of idle conditions. Two vehicles, a bus and a light duty truck, have been equipped for plasmatron reformer NOx adsorber regeneration tests.

Bromberg, L.; Crane, S; Rabinovich, A.; Kong, Y; Cohn, D; Heywood, J; Alexeev, N.; Samokhin, A.

2003-08-24T23:59:59.000Z

82

Pilot-Scale Demonstration of ALTA for NOx Control in Pulverized Coal-Fired Boilers  

SciTech Connect

This report describes computational fluid dynamics (CFD) modeling and pilot-scale testing conducted to demonstrate the ability of the Advanced Layered Technology Approach (ALTA) to reduce NO{sub x} emissions in a pulverized coal (PC) boiler. Testing specifically focused on characterizing NO{sub x} behavior with deep burner staging combined with Rich Reagent Injection (RRI). Tests were performed in a 4 MBtu/hr pilot-scale furnace at the University of Utah. Reaction Engineering International (REI) led the project team which included the University of Utah and Combustion Components Associates (CCA). Deep burner staging and RRI, combined with selective non-catalytic reduction (SNCR), make up the Advanced Layered Technology Approach (ALTA) for NO{sub x} reduction. The application of ALTA in a PC environment requires homogenization and rapid reaction of post-burner combustion gases and has not been successfully demonstrated in the past. Operation of the existing low-NO{sub x} burner and design and operation of an application specific ALTA burner was guided by CFD modeling conducted by REI. Parametric pilot-scale testing proved the chemistry of RRI in a PC environment with a NOx reduction of 79% at long residence times and high baseline NOx rate. At representative particle residence times, typical operation of the dual-register low-NO{sub x} burner provided an environment that was unsuitable for NO{sub x} reduction by RRI, showing no NOx reduction. With RRI, the ALTA burner was able to produce NO{sub x} emissions 20% lower than the low-NO{sub x} burner, 76 ppmv vs. 94 ppmv, at a burner stoichiometric ratio (BSR) of 0.7 and a normalized stoichiometric ratio (NSR) of 2.0. CFD modeling was used to investigate the application of RRI for NO{sub x} control on a 180 MW{sub e} wall-fired, PC boiler. A NO{sub x} reduction of 37% from baseline (normal operation) was predicted using ALTA burners with RRI to produce a NO{sub x} emission rate of 0.185 lb/MBtu at the horizontal nose of the boiler. When combined with SNCR, a NO{sub x} emission rate of 0.12-0.14 lb/MBtu can be expected when implementing a full ALTA system on this unit. Cost effectiveness of the full ALTA system was estimated at $2,152/ton NO{sub x} removed; this was less than 75% of the cost estimated for an SCR system on a unit of this size.

Andrew Fry; Devin Davis; Marc Cremer; Bradley Adams

2008-04-30T23:59:59.000Z

83

Three-Dimensional Composite Nanostructures for Lean NOx Emission Control  

DOE Green Energy (OSTI)

In this project, through a scalable solution process, we have successfully fabricated a new class of catalytic reactors, i.e., the composite nanostructure array (nano-array) based catalytic converters. These nanocatalysts, distinct from traditional powder washcoat based catalytic converters, directly integrate monolithic substrates together with nanostructures with well-defined size and shape during the scalable hydrothermal process. The new monolithic nanocatalysts are demonstrated to be able to save raw materials including Pt-group metals and support metal oxides by an order of magnitude, while perform well at various oxidation (e.g., CO oxidation and NO oxidation) and reduction reactions (H{sub 2} reduction of NOx) involved in the lean NOx emissions. The size, shape and arrangement of the composite nanostructures within the monolithic substrates are found to be the key in enabling the drastically reduced materials usage while maintaining the good catalytic reactivity in the enabled devices. The further understanding of the reaction kinetics associated with the unique mass transport and surface chemistry behind is needed for further optimizing the design and fabrication of good nanostructure array based catalytic converters. On the other hand, the high temperature stability, hydrothermal aging stability, as well as S-poisoning resistance have been investigated in this project on the nanocatalysts, which revealed promising results toward good chemical and mechanical robustness, as well as S-poisoning resistance. Further investigation is needed for unraveling the understanding, design and selection principles of this new class of nanostructure based monolithic catalysts.

Gao, Pu-Xian

2013-07-31T23:59:59.000Z

84

Second Generation Advanced Reburning for High Efficiency NOx Control  

SciTech Connect

This project is designed to develop a family of novel NO{sub x} control technologies, called Second Generation Advanced Reburning (SGAR) which has the potential to achieve 90+ NO{sub x} control in coal fired boilers at a significantly lower cost than Selective Catalytic Reduction. The ninth reporting period in Phase II (October 1-December 31, 1999) included preparation of the 10 x 10{sup 6} Btu/hr Tower Furnace for tests and setting the SGAR model to predict process performance under Tower Furnace conditions. Based on results of previous work, a paper has been prepared and submitted for the presentation at the 28 Symposium (International) on Combustion to be held at the University of Edinburgh, Scotland.

Vladimir M. Zamansky; Vitali V. Lissianski

1999-12-31T23:59:59.000Z

85

Proceedings: 1986 Joint Symposium on Dry SO2 and Simultaneous SO2/NOx Control Technologies, Volume 1: Sorbents, Process Research, an d Dispersion; Volume 2: Economics, Power Plant and Commercial Applications  

Science Conference Proceedings (OSTI)

Fundamental sorbent research, postfurnace injection, system impacts, and commercial applications were among the topics discussed at the second symposium on dry sorbent injection technologies. Injection of these sorbents offers an SO2 emissions control alternative that is potentially simpler and cheaper than conventional flue gas desulfurization systems.

1986-12-22T23:59:59.000Z

86

NOx | OpenEI  

Open Energy Info (EERE)

NOx NOx Dataset Summary Description Emissions from energy use in buildings are usually estimated on an annual basis using annual average multipliers. Using annual numbers provides a reasonable estimation of emissions, but it provides no indication of the temporal nature of the emissions. Therefore, there is no way of understanding the impact on emissions from load shifting and peak shaving technologies such as thermal energy storage, on-site renewable energy, and demand control. Source NREL Date Released April 11th, 2011 (3 years ago) Date Updated April 11th, 2011 (3 years ago) Keywords buildings carbon dioxide emissions carbon footprinting CO2 commercial buildings electricity emission factors ERCOT hourly emission factors interconnect nitrogen oxides NOx SO2 sulfur dioxide emissions

87

Evaluation of Oil-Fired Gas Turbine Selective Catalytic Reduction (SCR) NOx Control  

Science Conference Proceedings (OSTI)

Utilities are experiencing increasing regulatory pressure to equip oil-fired power generation units with selective catalytic reduction (SCR) control systems. This report addresses factors utilities may wish to evaluate when justifying an NOx reduction system other than SCR or ensuring successful implementation of an SCR system.

1990-12-17T23:59:59.000Z

88

Near-Zero NOx Combustion Technology for ATS Mercury 50 Gas Turbine  

SciTech Connect

A project to demonstrate a near-zero NOx, catalytic combustion technology for natural gas-fired, industrial gas turbines is described. In a cooperative effort between Solar Turbines Incorporated and Precision Combustion Incorporated (PCI), proof-of-concept rig testing of PCI's fuel-rich catalytic combustion technology has been completed successfully. The primary technical goal of the project was to demonstrate NOx and CO emissions below 5ppm and 10 ppm, respectively, (corrected to 15% O{sub 2}) at realistic gas turbine operating conditions. The program consisted of two tasks. In the first task, a single prototype RCL{trademark} (Rich Catalytic Lean Burn) module was demonstrated at Taurus 70 (7.5 Mw) operating conditions (1.6 MPa, 16 atm) in a test rig. For a Taurus 70 engine, eight to twelve RCL modules will be required, depending on the final system design. In the second task, four modules of a similar design were adapted to a Saturn engine (1 Mw) test rig (600 kPa, 6 atm) to demonstrate gas turbine light-off and operation with an RCL combustion system. This project was initially focused on combustion technology for the Mercury 50 engine. However, early in the program, the Taurus 70 replaced the Mercury. This substitution was motivated by the larger commercial market for an ultra-low NOx Taurus 70 in the near-term. Rig tests using a single prototype RCL module at Taurus 70 conditions achieved NOx emissions as low as 0.75 ppm. A combustor turndown of approximately 110C (200F) was achieved with NOx and CO emissions below 3 ppm and 10 ppm, respectively. Catalyst light-off occurred at an inlet temperature of 310C (590F). Once lit the module remained active at inlet air temperatures as low as 204C (400F). Combustor pressure oscillations were acceptably low during module testing. Single module rig tests were also conducted with the Taurus 70 module reconfigured with a central pilot fuel injector. Such a pilot will be required in a commercial RCL system for turbine light-off and transient operation. At and near simulated full load engine conditions, the pilot operated at low pilot fueling rates without degrading overall system emissions. In the second project task, a set of four Taurus 70 modules was tested in an existing Saturn engine rig. The combustion system allowed smooth engine startup and load variation. At steady state conditions (between 82% and 89.7% engine speed; 32% and 61% load), NOx and CO emissions were below 3ppm and 10ppm, respectively. Rig limitations unrelated to the RCL technology prevented low emissions operation outside of this speed range. Combustor pressure oscillations were low, below 0.25 % (peak-to-peak) of the mean combustor pressure.

Kenneth Smith

2004-12-31T23:59:59.000Z

89

Nitrogen Isotopic Composition of Coal-Fired Power Plant NOx: Influence of Emission Controls and Implications for Global Emission  

E-Print Network (OSTI)

Nitrogen Isotopic Composition of Coal-Fired Power Plant NOx: Influence of Emission Controls from coal-fired power plants in the U.S. at typical operating conditions with and without the presence this, a novel method for collection and isotopic analysis of coal-fired stack NOx emission samples

Elliott, Emily M.

90

Non-thermal plasma based technologies for the after-treatment of automotive exhaust particulates and marine diesel exhaust NOx  

DOE Green Energy (OSTI)

The trend in environmental legislation is such that primary engine modifications will not be sufficient to meet all future emissions requirements and exhaust aftertreatment technologies will need to be employed. One potential solution that is well placed to meet those requirements is non-thermal plasma technology. This paper will describe our work with some of our partners in the development of a plasma based diesel particulate filter (DPF) and plasma assisted catalytic reduction (PACR) for NOx removal. This paper describes the development of non-thermal plasma technology for the aftertreatment of particulates from a passenger car engine and NOx from a marine diesel exhaust application.

McAdams, R; Beech, P; Gillespie, R; Guy, C; Jones,S; Liddell, T; Morgan, R; Shawcross, J; Weeks, D; Hughes, D; Oesterle, J; Eberspdcher,

2003-08-24T23:59:59.000Z

91

Proceedings: EPRI/EPA 1995 Joint Symposium on Stationary Combustion NOx Control: Volume 1: Tuesday, May 16, 1995, Sessions 1, 2, 3; Volume 2: Wednesday, May 17, 1995, Sessions 4 and 5; Volume 3: Thursday, May 18, 1995, Sessions 6A, 6B, 7A, 7B; Volume ...  

Science Conference Proceedings (OSTI)

The 1995 Joint Symposium Combustion NOx Controls was held in Kansas City, Missouri, May 16-19, 1995. Jointly sponsored by EPRI and EPA, the symposium was the eighth in a biennial series devoted to the international exchange of information on recent technological and regulatory developments for stationary combustion NOx control. Topics covered included active full-scale retrofit demonstrations of low-NOx combustion systems in the United States and abroad; performance and economics results from pilot- and ...

2000-01-05T23:59:59.000Z

92

Catalyst Management Handbook for Coal-Fired Selective Catalytic Reduction NOx Control  

Science Conference Proceedings (OSTI)

This report provides guidelines for operators of coal-fired power plants equipped with selective catalytic reduction (SCR) NOx-control processes. These control processes define when to exchange or replace catalyst, while minimizing power-production cost impacts from SCR process equipment.BackgroundSelective catalytic reduction (SCR) is deployed on most major coal-fired generating units in the United States. Over 225 units, totaling 140 GW of ...

2012-12-14T23:59:59.000Z

93

Advanced NOx Emissions Control: Control Technology - SCR Catalyst Blinding  

NLE Websites -- All DOE Office Websites (Extended Search)

SCR Catalyst Blinding SCR Catalyst Blinding University of North Dakota Energy and Environmental Research Center (UND-EERC) is determining the potential of low-rank coal ash to cause blinding or masking of selective catalytic reduction (SCR) catalysts. A secondary goal will be to determine the degree of elemental mercury conversion across the catalysts. Specific objectives include (1) identify candidate coals and blends for testing under bench-scale conditions, (2) conduct bench-scale testing to screen coals and identify key conditions for full-scale testing, (3) design and construct an SCR slipstream test chamber for sampling at full-scale facilities, (4) conduct testing at full-scale testing, (5) identify SCR blinding mechanisms, rates, and cleaning methods as well as mercury conversion efficiencies, and (6) interpret data, prepare a report, and attend sponsor meetings to present information and recommendations.

94

NETL: Advanced NOx Emissions Control: Control Technology - O2...  

NLE Websites -- All DOE Office Websites (Extended Search)

of adding oxygen to the combustion process appears counter intuitive due to the higher flame temperatures typically associated with oxy-fuel firing. For example, when small...

95

NETL: Advanced NOx Emissions Control: Control Technology - Enhanced...  

NLE Websites -- All DOE Office Websites (Extended Search)

Pulverized Coal Burner" PDF-561KB Contacts: For further information on this project, contact the NETL Project Manager, Barbara Carney, or ALSTOM's Project Manager Galen Richards...

96

NETL: Advanced NOx Emissions Control: Control Technology - Ultra...  

NLE Websites -- All DOE Office Websites (Extended Search)

bituminous (Pennsylvania Middle Kittanning). No staging will be employed; a stoichiometric ratio range from 1.10 to 1.28 will be tested, with 17% excess air being the target...

97

NETL: Advanced NOx Emissions Control: Control Technology - LNB...  

NLE Websites -- All DOE Office Websites (Extended Search)

process, which includes three zones: main combustion, reburn, and burn-out. The stoichiometric ratio (SR) in the main combustion zone will be varied from 0.8 to 1.1. The reburn...

98

Development of METHANE de-NOX Reburn Process for Wood Waste and Biomass Fired Stoker Boilers - Final Report - METHANE de-NOX Reburn Technology Manual  

Science Conference Proceedings (OSTI)

The overall objective of this project was to demonstrate the effectiveness of the METHANE de-NOX (MdN) Reburn process in the Forest Products Industry (FPI) to provide more efficient use of wood and sludge waste (biosolids) combustion for both energy generation and emissions reduction (specifically from nitrogen oxides (NOx)) and to promote the transfer of the technology to the wide range of wood waste-fired stoker boilers populating the FPI. This document, MdN Reburn Commercial Technology Manual, was prepared to be a resource to promote technology transfer and commercialization activities of MdN in the industry and to assist potential users understand its application and installation requirements. The Manual includes a compilation of MdN commercial design data from four different stoker boiler designs that were baseline tested as part of the development effort. Design information in the Manual include boiler CFD model studies, process design protocols, engineering data sheets and commercial installation drawings. Each design package is unique and implemented in a manner to meet specific mill requirements.

J. Rabovitser; B. Bryan; S. Wohadlo; S. Nester; J. Vaught; M. Tartan (Gas Technology Institute) L. Szymanski; R. Glickert (ESA Environmental Solutions)

2007-12-31T23:59:59.000Z

99

NOx CONTROL OPTIONS AND INTEGRATION FOR US COAL FIRED BOILERS  

SciTech Connect

This is the tenth Quarterly Technical Report for DOE Cooperative Agreement No: DE-FC26-00NT40753. The goal of the project is to develop cost effective analysis tools and techniques for demonstrating and evaluating low NO{sub x} control strategies and their possible impact on boiler performance for firing US coals. The Electric Power Research Institute (EPRI) is providing cofunding for this program. This program contains multiple tasks and good progress is being made on all fronts. During this quarter, progress was made on the computational simulation of a full-scale boiler with the purpose of understanding the potential impacts of burner operating conditions on soot and NO{sub x} generation. Sulfation tests on both the titania support and vanadia/titania catalysts were completed using BYU's in situ spectroscopy reactor this quarter. These experiments focus on the extent to which vanadia and titania sulfate in an SO{sub 2}-laden, moist environment. Construction of the CCS reactor system is essentially complete and the control hardware and software are largely in place. A large batch of vanadia/titania catalyst in powder form has been prepared for use in poisoning tests. During this quarter, minor modifications were made to the multi-catalyst slipstream reactor and to the control system. The slipstream reactor was installed at AEP's Rockport plant at the end of November 2002. In this report, we describe the reactor system, particularly the control system, which was created by REI specifically for the reactor, as well as the installation at Rockport.

Mike Bockelie; Marc Cremer; Kevin Davis; Temi Linjewile; Connie Senior; Hong-Shig Shim; Bob Hurt; Eric Eddings; Larry Baxter

2003-01-30T23:59:59.000Z

100

Modeling Species Inhibition of NO oxidation in Urea-SCR Catalysts for Diesel Engine NOx Control  

DOE Green Energy (OSTI)

Urea-selective catalytic reduction (SCR) catalysts are regarded as the leading NOx aftertreatment technology to meet the 2010 NOx emission standards for on-highway vehicles running on heavy-duty diesel engines. However, issues such as low NOx conversion at low temperature conditions still exist due to various factors, including incomplete urea thermolysis, inhibition of SCR reactions by hydrocarbons and H2O. We have observed a noticeable reduction in the standard SCR reaction efficiency at low temperature with increasing water content. We observed a similar effect when hydrocarbons are present in the stream. This effect is absent under fast SCR conditions where NO ~ NO2 in the feed gas. As a first step in understanding the effects of such inhibition on SCR reaction steps, kinetic models that predict the inhibition behavior of H2O and hydrocarbons on NO oxidation are presented in the paper. A one-dimensional SCR model was developed based on conservation of species equations and was coded as a C-language S-function and implemented in Matlab/Simulink environment. NO oxidation and NO2 dissociation kinetics were defined as a function of the respective adsorbates storage in the SCR catalyst. The corresponding kinetic models were then validated on temperature ramp tests that showed good match with the test data.

Devarakonda, Maruthi N.; Tonkyn, Russell G.; Tran, Diana N.; Lee, Jong H.; Herling, Darrell R.

2010-09-15T23:59:59.000Z

Note: This page contains sample records for the topic "nox control technologies" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Cold-Start Emissions Control in Hybrid Vehicles Equipped with a Passive Hydrocarbon and NOx Adsorber  

SciTech Connect

We presents a study of the potential for using low-cost sorbent materials (i.e. Ag-Beta-zeolite and Fe-Mn-Zr transition metal oxides) to temporally trap hydrocarbons (HCs) and nitrogen oxides (NOx) emissions during cold-start periods in HEVs and PHEVs over transient driving cycles. The adsorption behavior of the candidate sorbent materials was characterized in our laboratory flow reactor experiments. The parameters were then used to develop a one-dimensional, transient device model which has been implemented in the Powertrain Systems Analysis Toolkit (PSAT) to simulate a passive HC and NOx absorber device. The results show that such an absorber can substantially reduce HC and NOx emissions by storing them when the 3-way catalyst is too cool to function and re-releasing them when the exhaust temperature rises. These improved emission controls do not involve any penalty in fuel consumption or require any change in engine operation. The cost of these sorbent materials is also much less than conventional 3-way catalysts.

Gao, Zhiming [ORNL; Kim, Miyoung [ORNL; Choi, Jae-Soon [ORNL; Daw, C Stuart [ORNL; Parks, II, James E [ORNL; Smith, David E [ORNL

2012-01-01T23:59:59.000Z

102

Innovative clean coal technology: 500 MW demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NOx) emissions from coal-fired boilers. Final report, Phases 1 - 3B  

SciTech Connect

This report presents the results of a U.S. Department of Energy (DOE) Innovative Clean Coal Technology (ICCT) project demonstrating advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NOx) emissions from coal-fired boilers. The project was conducted at Georgia Power Company`s Plant Hammond Unit 4 located near Rome, Georgia. The technologies demonstrated at this site include Foster Wheeler Energy Corporation`s advanced overfire air system and Controlled Flow/Split Flame low NOx burner. The primary objective of the demonstration at Hammond Unit 4 was to determine the long-term effects of commercially available wall-fired low NOx combustion technologies on NOx emissions and boiler performance. Short-term tests of each technology were also performed to provide engineering information about emissions and performance trends. A target of achieving fifty percent NOx reduction using combustion modifications was established for the project. Short-term and long-term baseline testing was conducted in an {open_quotes}as-found{close_quotes} condition from November 1989 through March 1990. Following retrofit of the AOFA system during a four-week outage in spring 1990, the AOFA configuration was tested from August 1990 through March 1991. The FWEC CF/SF low NOx burners were then installed during a seven-week outage starting on March 8, 1991 and continuing to May 5, 1991. Following optimization of the LNBs and ancillary combustion equipment by FWEC personnel, LNB testing commenced during July 1991 and continued until January 1992. Testing in the LNB+AOFA configuration was completed during August 1993. This report provides documentation on the design criteria used in the performance of this project as it pertains to the scope involved with the low NOx burners and advanced overfire systems.

NONE

1998-01-01T23:59:59.000Z

103

NETL: Clean Coal Technology Demonstration Program (CCTDP) - Round...  

NLE Websites -- All DOE Office Websites (Extended Search)

Control Technologies - Combined SO2 NOx Control Technologies Milliken Clean Coal Technology Demonstration Project - Project Brief PDF-342KB New York State Electric &...

104

A Cost-Effectiveness Analysis of Alternative Ozone Control Strategies: Flexible Nitrogen Oxide (NOx) Abatement  

E-Print Network (OSTI)

hydrolysis of N2O5, and ultimately leads to the computed reduction in NOx levels. 4. Effects of the different in the source magnitude of LtNOx can lead to a substantial10 reduction in the computed lifetimes of these trace. This increase of O3 at higher altitudes is responsible for the reduction of surface NOx levels simulated at high

105

NOx Reduction with Natural Gas for Lean Large-Bore Engine Applications Using Lean NOx Trap Aftertreatment  

SciTech Connect

Large-bore natural gas engines are used for distributed energy and gas compression since natural gas fuel offers a convenient and reliable fuel source via the natural gas pipeline and distribution infrastructure. Lean engines enable better fuel efficiency and lower operating costs; however, NOx emissions from lean engines are difficult to control. Technologies that reduce NOx in lean exhaust are desired to enable broader use of efficient lean engines. Lean NOx trap catalysts have demonstrated greater than 90% NOx reduction in lean exhaust from engines operating with gasoline, diesel, and natural gas fuels. In addition to the clean nature of the technology, lean NOx traps reduce NOx with the fuel source of the engine thereby eliminating the requirement for storage and handling of secondary fuels or reducing agents. A study of lean NOx trap catalysts for lean natural gas engines is presented here. Testing was performed on a Cummins C8.3G (CG-280) engine on a motor dynamometer. Lean NOx trap catalysts were tested for NOx reduction performance under various engine operating conditions, and the utilization of natural gas as the reductant fuel source was characterized. Engine test results show that temperature greatly affects the catalytic processes involved, specifically methane oxidation and NOx storage on the lean NOx trap. Additional studies on a bench flow reactor demonstrate the effect of precious metal loading (a primary cost factor) on lean NOx trap performance at different temperatures. Results and issues related to the potential of the lean NOx trap technology for large-bore engine applications will be discussed.

Parks, JE

2005-02-11T23:59:59.000Z

106

Method for control of NOx emission from combustors using fuel dilution  

SciTech Connect

A method of controlling NOx emission from combustors. The method involves the controlled addition of a diluent such as nitrogen or water vapor, to a base fuel to reduce the flame temperature, thereby reducing NOx production. At the same time, a gas capable of enhancing flame stability and improving low temperature combustion characteristics, such as hydrogen, is added to the fuel mixture. The base fuel can be natural gas for use in industrial and power generation gas turbines and other burners. However, the method described herein is equally applicable to other common fuels such as coal gas, biomass-derived fuels and other common hydrocarbon fuels. The unique combustion characteristics associated with the use of hydrogen, particularly faster flame speed, higher reaction rates, and increased resistance to fluid-mechanical strain, alter the burner combustion characteristics sufficiently to allow operation at the desired lower temperature conditions resulting from diluent addition, without the onset of unstable combustion that can arise at lower combustor operating temperatures.

Schefer, Robert W. (Alamo, CA); Keller, Jay O (Oakland, CA)

2007-01-16T23:59:59.000Z

107

Program on Technology Innovation: Field Evaluations of Entrained Flow NOx Catalyst Concept  

Science Conference Proceedings (OSTI)

EPRI has been actively evaluating and developing advanced catalyst concepts for NOx reduction that are more effective and have potential in achieving near zero emissions. The concept called NOMERCTM involves the entrained flow of pulverized SCR catalyst for NOx reduction combined with activated carbon injection for removing mercury from the flue gas stream at coal-fired utilities. The entrained flow removal process is a novel concept and has been proven to work in a previous proof of concept test. This r...

2006-03-27T23:59:59.000Z

108

Advancements in low NOx tangential firing systems  

Science Conference Proceedings (OSTI)

The most cost effective method of reducing nitrogen oxide emissions when burning fossil fuels, such as coal, is through in-furnace NOx reduction processes. ABB Combustion Engineering, Inc. (ABB CE), through its ABB Power Plant Laboratories has been involved in the development of such low NOx pulverized coal firing systems for many years. This development effort is most recently demonstrated through ABB CE`s involvement with the U.S. Department of Energy`s (DOE) {open_quotes}Engineering Development of Advanced Coal Fired Low-Emission Boiler Systems{close_quotes} (LEBS) project. The goal of the DOE LEBS project is to use {open_quotes}near term{close_quotes} technologies to produce a commercially viable, low emissions boiler. This paper addresses one of the key technologies within this project, the NOx control subsystem. The foundation for the work undertaken at ABB CE is the TFS 2000{trademark} firing system, which is currently offered on a commercial basis. This system encompasses sub-stoichiometric combustion in the main firing zone for reduced NOx formation. Potential enhancements to this firing system focus on optimizing the introduction of the air and fuel within the primary windbox to provide additional horizontal and vertical staging. As is the case with all in-furnace NOx control processes, it is necessary to operate the system in a manner which does not decrease NOx at the expense of reduced combustion efficiency.

Hein, R. von; Maney, C.; Borio, R. [and others

1996-12-31T23:59:59.000Z

109

Program on Technology Innovation: Effect of Hydrogen Addition on Part Load Operation of Dry, Low NOx Combustors  

Science Conference Proceedings (OSTI)

Emissions and operability of Dry, Low NOx gas turbines at part load can be an issue for operators. One potential remedy for this problem is the addition of hydrogen to natural gas supplies when operating at part load. This report examines the effect of hydrogen addition on part load emissions and operating envelope. Chemical Reactor Modeling is used to simulate the fluid mechanics of the gas turbine combustor, while allowing for accurate consideration of the chemical kinetics which control emission produ...

2006-09-11T23:59:59.000Z

110

Desulfurization Effects on a Light-Duty Diesel Vehicle NOx Adsorber Exhaust Emission Control System  

DOE Green Energy (OSTI)

Analyzes the effects on gaseous emissions, before and after desulfurization, on a light-duty diesel vehicle with a NOx adsorber catalyst.

Tatur, M.; Tomazic, D.; Tyrer, H.; Thornton, M.; Kubsh, J.

2006-05-01T23:59:59.000Z

111

Sulfur Management of NOx Adsorber Technology for Diesel Light-Duty Vehicle and Truck Applications  

DOE Green Energy (OSTI)

Sulfur poisoning from engine fuel and lube is one of the most recognizable degradation mechanisms of a NOx adsorber catalyst system for diesel emission reduction. Even with the availability of 15 ppm sulfur diesel fuel, NOx adsorber will be deactivated without an effective sulfur management. Two general pathways are currently being explored for sulfur management: (1) the use of a disposable SOx trap that can be replaced or rejuvenated offline periodically, and (2) the use of diesel fuel injection in the exhaust and high temperature de-sulfation approach to remove the sulfur poisons to recover the NOx trapping efficiency. The major concern of the de-sulfation process is the many prolonged high temperature rich cycles that catalyst will encounter during its useful life. It is shown that NOx adsorber catalyst suffers some loss of its trapping capacity upon high temperature lean-rich exposure. With the use of a disposable SOx trap to remove large portion of the sulfur poisons from the exhaust, the NOx adsorber catalyst can be protected and the numbers of de-sulfation events can be greatly reduced. Spectroscopic techniques, such as DRIFTS and Raman, have been used to monitor the underlying chemical reactions during NOx trapping/ regeneration and de-sulfation periods, and provide a fundamental understanding of NOx storage capacity and catalyst degradation mechanism using model catalysts. This paper examines the sulfur effect on two model NOx adsorber catalysts. The chemistry of SOx/base metal oxides and the sulfation product pathways and their corresponding spectroscopic data are discussed. SAE Paper SAE-2003-01-3245 {copyright} 2003 SAE International. This paper is published on this website with permission from SAE International. As a user of this website, you are permitted to view this paper on-line, download this pdf file and print one copy of this paper at no cost for your use only. The downloaded pdf file and printout of this SAE paper may not be copied, distributed or forwarded to others or for the use of others.

Fang, Howard L.; Wang, Jerry C.; Yu, Robert C. (Cummins, Inc.); Wan, C. Z. (Engelhard Corp.); Howden, Ken (U.S. Dept. of Energy)

2003-10-01T23:59:59.000Z

112

OBSERVATION-BASED METHODS (OBMS) FOR ANALYZING URBAN/REGIONAL OZONE PRODUCTION AND OZONE-NOx-VOC SENSITIVITY.  

E-Print Network (OSTI)

and reduction ofFormation and reduction of NOxNOx during burner combustionduring burner combustion ·· LowLow NOxNOx gas treatment forFlue gas treatment for NOxNOx reduction: SCR, SNCR, otherreduction: SCR, SNCR, other OF TECHNOLOGY ENE-47.153 Selective catalyticSelective catalytic reduction (SCR) ofreduction (SCR) of NOxNOx /1

Sillman, Sanford

113

Time and location differentiated NOX control in competitive electricity markets using cap-and-trade mechanisms  

E-Print Network (OSTI)

Due to variations in weather and atmospheric chemistry, the timing and location of nitrogen oxide (NOX) reductions determine their effectiveness in reducing ground-level ozone, which adversely impacts human health. Electric ...

Martin, Katherine C.

2007-01-01T23:59:59.000Z

114

Integrated Dry NOx/SO2 Emissions Control System, A DOE Assessment  

NLE Websites -- All DOE Office Websites (Extended Search)

0 Integrated Dry NO X SO 2 Emissions Control System A DOE Assessment October 2001 U.S. Department of Energy National Energy Technology Laboratory P.O. Box 880, 3610 Collins Ferry...

115

Feasibility of plasma aftertreatment for simultaneous control of NOx and particulates  

DOE Green Energy (OSTI)

Plasma reactors can be operated as a particulate trap or as a NOx converter. Particulate trapping in a plasma reactor can be accomplished by electrostatic precipitation. The soluble organic fraction of the trapped particulates can be utilized for the hydrocarbon-enhanced oxidation of NO to NO2 . The NO2 can then be used to non-thermally oxidize the carbon fraction of the particulates. The oxidation of the carbon fraction by NO2 can lead to reduction of NOx or backconversion of NO2 to NO. This paper examines the hydrocarbon and electrical energy density requirements in a plasma for maximum NOx conversion in both heavy-duty and light-duty diesel engine exhaust. The energy density required for complete oxidation of hydrocarbons is also examined and shown to be much greater than that required for maximum NOx conversion. The reaction of NO2 with carbon is shown to lead mainly to backconversion of NO2 to NO. These results suggest that the combination of the plasma with a catalyst will be required to reduce the NOx and oxidize the hydrocarbons. The plasma reactor can be operated occasionally in the arc mode to thermally oxidize the carbon fraction of the particulates.

Brusasco, R M; Merritt, B T; Penetrante, B; Pitz, W J; Vogtlin, G E

1999-08-24T23:59:59.000Z

116

NETL: News Release - Novel Pollution Control Technology Recognized  

NLE Websites -- All DOE Office Websites (Extended Search)

November 17, 2005 November 17, 2005 Novel Pollution Control Technology Recognized NETL-funded Technology Honored for Chemical Engineering Achievement PITTSBURGH, PA - Praxair Inc.'s Oxygen Enhanced Combustion (OEC) system for controlling emissions of nitrogen oxides (NOx) was recently recognized as one of five 2005 finalists for Chemical Engineering magazine's prestigious Kirkpatrick Award for Chemical Engineering Achievement. The system was developed under the National Energy Technology Laboratory's Innovations for Existing Plants program, which advances technologies to improve the environmental performance of America's existing coal-fired power plants. MORE INFO Read June 26, 2002 TechLine Chemical Engineering magazine, published by Chemical Week Associates, grants the Kirkpatrick Award biennially to honor the most outstanding

117

LBNLs Low-NOx Combustion Technologies for Heat and Power Generation  

NLE Websites -- All DOE Office Websites (Extended Search)

Swirl Injectors for Swirl Injectors for High Hydrogen Fuel Gas Turbines Robert K. Cheng Environmental Energy Technologies Division Lawrence Berkeley National Laboratory Berkeley, CA 94720 Research supported by NETL - Fossil Energy, US Dept. of Energy Presentation at UTSR Workshop - Oct. 20, 2010 Participants and Collaborators  LBNL - Environmental Energy Technology Div.  Robert Cheng, David Littlejohn, Peter Therkelsen, Ken Smith & Sy Ali  United Tech. Research Center - Pratt & Whitney Power Systems  Dustin Davis, Catalin Fotache & Richard Tuthill  Florida Turbine Technologies  Russell Jones & Joe Brostmeyer  LBNL - Computational Research Div.  John Bell & Marc Day  Siemens Energy Inc.  Scott Martin & Enrique Portillo Bilbao  University of Iowa

118

Lean Gasoline Engine Reductant Chemistry During Lean NOx Trap Regeneration  

Science Conference Proceedings (OSTI)

Lean NOx Trap (LNT) catalysts can effectively reduce NOx from lean engine exhaust. Significant research for LNTs in diesel engine applications has been performed and has led to commercialization of the technology. For lean gasoline engine applications, advanced direct injection engines have led to a renewed interest in the potential for lean gasoline vehicles and, thereby, a renewed demand for lean NOx control. To understand the gasoline-based reductant chemistry during regeneration, a BMW lean gasoline vehicle has been studied on a chassis dynamometer. Exhaust samples were collected and analyzed for key reductant species such as H2, CO, NH3, and hydrocarbons during transient drive cycles. The relation of the reductant species to LNT performance will be discussed. Furthermore, the challenges of NOx storage in the lean gasoline application are reviewed.

Choi, Jae-Soon [ORNL; Prikhodko, Vitaly Y [ORNL; Partridge Jr, William P [ORNL; Parks, II, James E [ORNL; Norman, Kevin M [ORNL; Huff, Shean P [ORNL; Chambon, Paul H [ORNL; Thomas, John F [ORNL

2010-01-01T23:59:59.000Z

119

Gas Turbine/Combined-Cycle Emissions Control Technology and Regulatory Issues Handbook-2010 Edition  

Science Conference Proceedings (OSTI)

This report provides information pertaining to emissions from combustion turbines. Topics covered include low-NOx burner design and information on add-on control systems, including equipment used in practice as well as emerging technologies. Select air quality regulations that apply to new and existing combustion turbines are discussed, including requirements regarding best available control technology (BACT) (which also may represent the lowest-achievable emission rate or LAER) requirement. United State...

2010-12-20T23:59:59.000Z

120

NETL: Clean Coal Technology Demonstration Program (CCTDP) - Round...  

NLE Websites -- All DOE Office Websites (Extended Search)

Catalytic Reduction Technology for the Control of NOx Emissions from High-Sulfur Coal-Fired Boilers - Project Brief PDF-247KB Southern Company Services, Pensacola, FL...

Note: This page contains sample records for the topic "nox control technologies" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

The Office of Fossil Energy's National Energy Technology Laboratory...  

NLE Websites -- All DOE Office Websites (Extended Search)

such as the President's Clear Skies Act. DOE-NETL NOx Control Program The Office of Fossil Energy's National Energy Technology Laboratory (NETL) is teaming with industry and...

122

Review of Combustion Modification Emerging Technologies  

Science Conference Proceedings (OSTI)

Combustion modification emerging technologies for coal-fired boilers represent new developments in NOx control through changes in the fuel/air mixing of the combustion process. Technologies examined in this report fall into the categories of low-NOX burners (LNB), overfire air (OFA), enriched combustion, and combustion diagnostics. The technology reviews are comprised of the following sections where sufficient information was available: background, NOX reduction principle, performance and experience base...

2008-02-26T23:59:59.000Z

123

Calibration and performance of a selective catalytic reduction (SCR) bench rig for NOx? emissions control  

E-Print Network (OSTI)

A laboratory test rig was designed and built to easily test SCR (Selective Catalytic Reduction) technology. Equipped with three 6 kW heaters, connections for liquid N2 and an assortment of test gases, and a connection with ...

Castro Galnares, Sebastin (Castro Galnares Wright Paz)

2008-01-01T23:59:59.000Z

124

Lean NOx catalysis for gasoline fueled European cars  

SciTech Connect

There is increasing interest in operating gasoline fueled passenger cars lean of the stoichiometric air/fuel (A/F) ratio to improve fuel economy. These types of engines will operate at lean A/F ratios while cruising at partial load, and return to stoichiometric or even rich conditions when more power is required. The challenge for the engine and catalyst manufacturer is to develop a system which will combine the high activity rates of a state-of-the-art three-way catalyst (TWC) with the ability to reduce nitrogen oxides (NOx) in the presence of excess oxygen. The objective is to achieve the future legislative limits (EURO III/IV) in the European Union. Recent developments in automotive pollution control catalysis show that the use of NOx adsorption materials is a suitable way to reduce NOx emissions of gasoline-fueled lean-burn engines. However, the primary task for the implementation of this technology in the European market will be to improve the catalyst`s high-temperature stability and to decrease its susceptibility to sulfur poisoning. Outlined here are results of a recent R and D program to achieve NOx reduction under lean-burn gasoline engine conditions. Model gas test results as well as engine bench data are used for discussion of the parameters which control NOx adsorption efficiency under various conditions.

NONE

1997-02-01T23:59:59.000Z

125

Mercury Control Technology Selection Guide  

Science Conference Proceedings (OSTI)

EPRI, the DOE National Energy Technology Laboratory, and various other organizations have undertaken extensive RD programs over the past decade to develop cost-effective methods for reducing mercury emissions from coal-burning power plants. The field tests sponsored by these organizations have produced a significant amount of pilot and full-scale mercury control data for a variety of technologies at power plant sites with different boiler types, firing different coals, and equipped with various air emiss...

2006-09-22T23:59:59.000Z

126

NOx Reduction through Efficiency Gain  

E-Print Network (OSTI)

Benz Air Engineering and the CompuNOx system focus on a controls approach to minimize emissions without exposing steam generation plants to an unbearable financial burden. With minimal system changes we use thorough system analysis in conjunction with a novel control design to deliver a comprehensive boiler controls retrofit that provides reductions in emissions as well as substantial cost savings. Combining mechanical engineering expertise with substantial experience in control engineering in over 200 retrofits this system achieves astonishing results with short payback time, making CompuNOx a feasible solution for emission mandates and cost savings.

Benz, R.; Thompson, R.; Staedter, M.

2007-01-01T23:59:59.000Z

127

RETROFIT OF A WTE FACILITY WITH SCR FOR NOx and PCDD/F CONTROL  

E-Print Network (OSTI)

flue gases. These studies have shown the relative ease of controlling oxidized mercury (specifically, Nashville, 1996 8. B. Hall, O . Lindqvist, and E. Ljungstrom, "Mercury Chemistry in Simulated Flue Gases municipal waste combustor (MWC), flue gas mercury is mainly found as HgCI2. They postulated thatHgCl2

Columbia University

128

USE OF A DIESEL FUEL PROCESSOR FOR RAPID AND EFFICIENT REGENERATION OF SINGLE LEG NOX ADSORBER SYSTEMS  

DOE Green Energy (OSTI)

Lean NOx adsorber systems are one of the primary candidate technologies for the control of NOx from diesel engines to meet the 2007-2010 US emissions regulations, which require a 90% reduction of NOx from the 2004 regulations. Several of the technical challenges facing this technology are regeneration at low exhaust temperatures and the efficient use of diesel fuel to minimize fuel penalty. A diesel processor system has been developed and tested in a single leg NOx adsorber configuration on a diesel engine test stand. During NOx adsorber regeneration, this fuel processor system performs reduces the exhaust O2 level to zero and efficiently processes the diesel fuel to H2 and CO. Combined with a Nox adsorber catalyst, this system has demonstrated NOx reduction above 90%, regeneration of the NOx adsorber H2/CO pulses as short as 1 second and fuel penalties in the 3 to 4% range at 50% load. This fuel processor system can also be used to provide the desulfation cycle required with sulfur containing fuels as well as providing thermal management for PM filter regeneration.

Betta, R; Cizeron, J; Sheridan, D; Davis, T

2003-08-24T23:59:59.000Z

129

Impacts of Low-NOX Combustion and Activated Carbon Injection on Particulate Control Device Performance  

Science Conference Proceedings (OSTI)

This report summarizes the results of a computational fluid dynamics (CFD) model study of the re-entrainment of carbon from the hoppers of a typical utility electrostatic precipitator (ESP). During earlier phases of this study, hopper re-entrainment was identified as the principle mechanism responsible for the low collection efficiency of carbon by ESPs. This statement was found to be true for both unburned carbon from the boiler and activated carbon injected for mercury control. The results indicate tha...

2008-03-31T23:59:59.000Z

130

Radiative forcing from aircraft NOx emissions: mechanisms and seasonal dependence  

E-Print Network (OSTI)

), a Babcock Power Inc. company, has developed a new, innovative, high-efficiency NOX reduction technology into a single unit and provides the maximum NOX reduction and heat recovery practical. The paper will describe emissions. A new system for the reduction of NOX emissions to levels hereby unheard of for US WTE boilers

Stevenson, David

131

Selective NOx Recirculation for Stationary Lean-Burn Natural Gas Engines  

SciTech Connect

Nitric oxide (NO) and nitrogen dioxide (NO2) generated by internal combustion (IC) engines are implicated in adverse environmental and health effects. Even though lean-burn natural gas engines have traditionally emitted lower oxides of nitrogen (NOx) emissions compared to their diesel counterparts, natural gas engines are being further challenged to reduce NOx emissions to 0.1 g/bhp-hr. The Selective NOx Recirculation (SNR) approach for NOx reduction involves cooling the engine exhaust gas and then adsorbing the NOx from the exhaust stream, followed by the periodic desorption of NOx. By sending the desorbed NOx back into the intake and through the engine, a percentage of the NOx can be decomposed during the combustion process. SNR technology has the support of the Department of Energy (DOE), under the Advanced Reciprocating Engine Systems (ARES) program to reduce NOx emissions to under 0.1 g/bhp-hr from stationary natural gas engines by 2010. The NO decomposition phenomenon was studied using two Cummins L10G natural gas fueled spark-ignited (SI) engines in three experimental campaigns. It was observed that the air/fuel ratio ({lambda}), injected NO quantity, added exhaust gas recirculation (EGR) percentage, and engine operating points affected NOx decomposition rates within the engine. Chemical kinetic model predictions using the software package CHEMKIN were performed to relate the experimental data with established rate and equilibrium models. The model was used to predict NO decomposition during lean-burn, stoichiometric burn, and slightly rich-burn cases with added EGR. NOx decomposition rates were estimated from the model to be from 35 to 42% for the lean-burn cases and from 50 to 70% for the rich-burn cases. The modeling results provided an insight as to how to maximize NOx decomposition rates for the experimental engine. Results from this experiment along with chemical kinetic modeling solutions prompted the investigation of rich-burn operating conditions, with added EGR to prevent preignition. It was observed that the relative air/fuel ratio, injected NO quantity, added EGR fraction, and engine operating points affected the NO decomposition rates. While operating under these modified conditions, the highest NO decomposition rate of 92% was observed. In-cylinder pressure data gathered during the experiments showed minimum deviation from peak pressure as a result of NO injections into the engine. A NOx adsorption system, from Sorbent Technologies, Inc., was integrated with the Cummins engine, comprised a NOx adsorbent chamber, heat exchanger, demister, and a hot air blower. Data were gathered to show the possibility of NOx adsorption from the engine exhaust, and desorption of NOx from the sorbent material. In order to quantify the NOx adsorption/desorption characteristics of the sorbent material, a benchtop adsorption system was constructed. The temperature of this apparatus was controlled while data were gathered on the characteristics of the sorbent material for development of a system model. A simplified linear driving force model was developed to predict NOx adsorption into the sorbent material as cooled exhaust passed over fresh sorbent material. A mass heat transfer analysis was conducted to analyze the possibility of using hot exhaust gas for the desorption process. It was found in the adsorption studies, and through literature review, that NO adsorption was poor when the carrier gas was nitrogen, but that NO in the presence of oxygen was adsorbed at levels exceeding 1% by mass of the sorbent. From the three experimental campaigns, chemical kinetic modeling analysis, and the scaled benchtop NOx adsorption system, an overall SNR system model was developed. An economic analysis was completed, and showed that the system was impractical in cost for small engines, but that economies of scale favored the technology.

Nigel N. Clark

2006-12-31T23:59:59.000Z

132

Building Technologies Office: Sensors and Controls Research  

NLE Websites -- All DOE Office Websites (Extended Search)

Sensors and Controls Sensors and Controls Research to someone by E-mail Share Building Technologies Office: Sensors and Controls Research on Facebook Tweet about Building Technologies Office: Sensors and Controls Research on Twitter Bookmark Building Technologies Office: Sensors and Controls Research on Google Bookmark Building Technologies Office: Sensors and Controls Research on Delicious Rank Building Technologies Office: Sensors and Controls Research on Digg Find More places to share Building Technologies Office: Sensors and Controls Research on AddThis.com... About Take Action to Save Energy Partner with DOE Activities Appliances Research Building Envelope Research Windows, Skylights, & Doors Research Space Heating & Cooling Research Water Heating Research Lighting Research

133

Advanced In-Furnace NOx Control for Wall and Cyclone-Fired Boilers  

SciTech Connect

A NO{sub x} minimization strategy for coal-burning wall-fired and cyclone boilers was developed that included deep air staging, innovative oxygen use, reburning, and advanced combustion control enhancements. Computational fluid dynamics modeling was applied to refine and select the best arrangements. Pilot-scale tests were conducted by firing an eastern high-volatile bituminous Pittsburgh No.8 coal at 5 million Btu/hr in a facility that was set up with two-level overfire air (OFA) ports. In the wall-fired mode, pulverized coal was burned in a geometrically scaled down version of the B and W DRB-4Z{reg_sign} low-NO{sub x} burner. At a fixed overall excess air level of 17%, NO{sub x} emissions with single-level OFA ports were around 0.32 lb/million Btu at 0.80 burner stoichiometry. Two-level OFA operation lowered the NO{sub x} levels to 0.25 lb/million Btu. Oxygen enrichment in the staged burner reduced the NO{sub x} values to 0.21 lb/million Btu. Oxygen enrichment plus reburning and 2-level OFA operation further curbed the NO{sub x} emissions to 0.19 lb/million Btu or by 41% from conventional air-staged operation with single-level OFA ports. In the cyclone firing arrangement, oxygen enrichment of the cyclone combustor enabled high-temperature and deeply staged operation while maintaining good slag tapping. Firing the Pittsburgh No.8 coal in the optimum arrangement generated 112 ppmv NO{sub x} (0.15 lb/million Btu) and 59 ppmv CO. The optimum emissions results represent 88% NO{sub x} reduction from the uncontrolled operation. Levelized costs for additional NO{sub x} removal by various in-furnace control methods in reference wall-fired or cyclone-fired units already equipped with single-level OFA ports were estimated and compared with figures for SCR systems achieving 0.1 lb NO{sub x}/10{sup 6} Btu. Two-level OFA ports could offer the most economical approach for moderate NO{sub x} control, especially for smaller units. O{sub 2} enrichment in combination with 2-level OFA was not cost effective for wall-firing. For cyclone units, NO{sub x} removal by two-level OFA plus O{sub 2} enrichment but without coal reburning was economically attractive.

Hamid Sarv

2009-02-28T23:59:59.000Z

134

In-Situ Combustion NOx Analyzer Sensor  

Science Conference Proceedings (OSTI)

This report contains a review of the different technologies currently available for measuring nitrogen oxide (NOx) in the flue gas stream including chemiluminescence, photometric, Fourier transform infrared (FTIR) and electrochemical cells. Reviews of how NOx is produced, the detrimental effects, and Environmental Protection Agency (EPA) Code of Federal Regulations (CFR) Title 40 test protocols are also included. A survey to gather information and to evaluate the most promising available technologies for...

2005-12-21T23:59:59.000Z

135

(plexiglass) covers (negligible transmittance at 290320 nm). NOx emission decreased  

E-Print Network (OSTI)

that the controlling NOx formation and reduction reactions are insensi- tive to coal rank. This observation has been as the initial NOx level in- creases suggests that the char/NO reduction step(s) is more temperature sensitive concentrations cannot be reduced to levels ap- proaching 0 ppm without the use of downstream NOx reduction

136

DOE/EA-1472: Finding of No Significant Impact for the Commercial Demonstration of the Low NOx Burner/Separated Over-Fire Air Integration System Emission Reduction Technology (03/11/03)  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

IMPACT IMPACT COMMERCIAL DEMONSRATION OF THE LOW NOx BURNER/SEPARATED OVER- FIRE AIR (LNB/SOFA) INTEGRATON SYSTEM EMISSION REDUCTION TECHNOLOGY HOLCOMB STATION SUNFLOWER ELECTRIC POWER CORPORATION FINNEY COUNTY, KANSAS AGENCY: U.S. Department of Energy (DOE) ACTION: Finding of No Significant Impact (FONSI) SUMMARY: The DOE has prepared an Environmental Assessment (EA), to analyze the potential impacts of the commercial application of the Low-NOx Burner/Separated Over-Fire Air (LNB/SOFA) integration system to achieve nitrogen oxide (NOx) emissions reduction at Sunflower's Holcomb Unit No. 1 (Holcomb Station), located near Garden City, in Finney County, Kansas. The Holcomb Station would be modified in three distinct phases to demonstrate the synergistic effect of layering NO,

137

NETL: Mercury Emissions Control Technologies - Demonstration...  

NLE Websites -- All DOE Office Websites (Extended Search)

Demonstration of Integrated Approach to Mercury Control This project will demonstrate a novel multi-pollutant control technology for coal-fired power plants that can reduce...

138

Enhanced High Temperature Performance of NOx Reduction Catalyst Materials  

Science Conference Proceedings (OSTI)

Two primary NOx after-treatment technologies have been recognized as the most promising approaches for meeting stringent NOx emission standards for diesel vehicles within the Environmental Protection Agencys (EPAs) 2007/2010 mandated limits, NOx Storage Reduction (NSR) and NH3 selective catalytic reduction (SCR); both are, in fact being commercialized for this application. However, in looking forward to 2015 and beyond with expected more stringent regulations, the continued viability of the NSR technology for controlling NOx emissions from lean-burn engines such as diesels will require at least two specific, significant and inter-related improvements. First, it is important to reduce system costs by, for example, minimizing the precious metal content while maintaining, even improving, performance and long-term stability. A second critical need for future NSR systems, as well as for NH3 SCR, will be significantly improved higher and lower temperature performance and stability. Furthermore, these critically needed improvements will contribute significantly to minimizing the impacts to fuel economy of incorporating these after-treatment technologies on lean-burn vehicles. To meet these objectives will require, at a minimum an improved scientific understanding of the following things: i) the various roles for the precious and coinage metals used in these catalysts; ii) the mechanisms for these various roles; iii) the effects of high temperatures on the active metal performance in their various roles; iv) mechanisms for higher temperature NOx storage performance for modified and/or alternative storage materials; v) the interactions between the precious metals and the storage materials in both optimum NOx storage performance and long term stability; vi) the sulfur adsorption and regeneration mechanisms for NOx reduction materials; vii) materials degradation mechanisms in CHA-based NH3 SCR catalysts. The objective of this CRADA project between PNNL and Cummins, Inc. is to develop a fundamental understanding of the above-listed issues. Model catalysts that are based on literature formulations are the focus of the work being carried out at PNNL. In addition, the performance and stability of more realistic high temperature NSR catalysts, supplied by JM, are being studied in order to provide baseline data for the model catalysts that are, again, based on formulations described in the open literature. For this short summary, we will primarily highlight representative results from our recent studies of the stability of candidate high temperature NSR materials.

Gao, Feng; Kim, Do Heui; Luo, Jinyong; Muntean, George G.; Peden, Charles HF; Howden, Ken; Currier, Neal; Kamasamudram, Krishna; Kumar, Ashok; Li, Junhui; Stafford, Randy; Yezerets, Aleksey; Castagnola, Mario; Chen, Hai Ying; Hess, Howard ..

2012-12-31T23:59:59.000Z

139

Multipollutant Emission Control Technology Options  

E-Print Network (OSTI)

The U. S. Environmental Protection Agency is charged by Congress with protecting the nation's land, air, and water resources. Under a mandate of national environmental laws, the agency strives to formulate and implement actions leading to a compatible balance between human activities and the ability of natural systems to support and nurture life. To meet this mandate, EPA's research program is providing data and technical support for solving environmental problems today and building a science knowledge base necessary to manage our ecological resources wisely, understand how pollutants affect our health, and prevent or reduce environmental risks in the future. The National Risk Management Research Laboratory is the agencys center for investigation of technological and management approaches for reducing risks from threats to human health and the environment. The focus of the laboratory's research program is on methods for the prevention and control of pollution to air, land, water, and subsurface resources, protection of water quality in public water systems; remediation of contaminated sites and groundwater; and prevention and control of indoor air pollution. The goal of this research effort is to catalyze development and implementation of innovative, cost-effective environmental technologies; develop scientific and engineering information needed by EPA to support regulatory and policy decisions; and provide technical support and information transfer to ensure effective implementation of environmental regulations and strategies. This publication has been produced as part of the laboratory's strategic long-term research plan. It is published and made available by EPA's Office of Research and Development to assist the user community and to link researchers with their clients.

For Coal-fired Power Plants Foreword; Sally Gutierrez Director

2005-01-01T23:59:59.000Z

140

SELECTIVE NOx RECIRCULATION FOR STATIONARY LEAN-BURN NATURAL GAS ENGINES  

DOE Green Energy (OSTI)

The research program conducted at the West Virginia University Engine and Emissions Research Laboratory (EERL) is working towards the verification and optimization of an approach to remove nitric oxides from the exhaust gas of lean burn natural gas engines. This project was sponsored by the US Department of Energy, National Energy Technology Laboratory (NETL) under contract number: DE-FC26-02NT41608. Selective NOx Recirculation (SNR) involves three main steps. First, NOx is adsorbed from the exhaust stream, followed by periodic desorption from the aftertreatment medium. Finally the desorbed NOx is passed back into the intake air stream and fed into the engine, where a percentage of the NOx is decomposed. This reporting period focuses on the NOx decomposition capability in the combustion process. Although researchers have demonstrated NOx reduction with SNR in other contexts, the proposed program is needed to further understand the process as it applies to lean burn natural gas engines. SNR is in support of the Department of Energy goal of enabling future use of environmentally acceptable reciprocating natural gas engines through NOx reduction under 0.1 g/bhp-hr. The study of decomposition of oxides of nitrogen (NOx) during combustion in the cylinder was conducted on a 1993 Cummins L10G 240 hp lean burn natural gas engine. The engine was operated at different air/fuel ratios, and at a speed of 800 rpm to mimic a larger bore engine. A full scale dilution tunnel and analyzers capable of measuring NOx, CO{sub 2}, CO, HC concentrations were used to characterize the exhaust gas. Commercially available nitric oxide (NO) was used to mimic the NOx stream from the desorption process through a mass flow controller and an injection nozzle. The same quantity of NOx was injected into the intake and exhaust line of the engine for 20 seconds at various steady state engine operating points. NOx decomposition rates were obtained by averaging the peak values at each set point minus the baseline and finding the ratio between the injected NO amounts. It was observed that the air/fuel ratio, injected NO quantity and engine operating points affected the NOx decomposition rates of the natural gas engine. A highest NOx decomposition rate of 27% was measured from this engine. A separate exploratory tests conducted with a gasoline engine with a low air/fuel ratio yielded results that suggested, that high NOx decomposition rates may be possible if a normally lean burn engine were operated at conditions closer to stoichiometric, with high exhaust gas recirculation (EGR) for a brief period of time during the NOx decomposition phase and with a wider range of air/fuel ratios. Chemical kinetic model predictions using CHEMKIN were performed to relate the experimental data with the established rate and equilibrium models. NOx decomposition rates from 35% to 42% were estimated using the CHEMKIN software. This provided insight on how to maximize NOx decomposition rates for a large bore engine. In the future, the modeling will be used to examine the effect of higher NO{sub 2}/NO ratios that are associated with lower speed and larger bore lean burn operation.

Nigel Clark; Gregory Thompson; Richard Atkinson; Chamila Tissera; Matt Swartz; Emre Tatli; Ramprabhu Vellaisamy

2005-01-01T23:59:59.000Z

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141

Intelligent Actuation Control Using Model-Free Adaptive Control Technology  

NLE Websites -- All DOE Office Websites (Extended Search)

Intelligent Actuation Control Using Intelligent Actuation Control Using Model-Free Adaptive Control Technology Background The Advanced Research Sensors and Controls Program is leading the effort to develop sensing and control technologies and methods to achieve seamlessly integrated and intelligent power systems. The program is led by the U.S. Department of Energy (DOE) Office of Fossil Energy National Energy Technology Laboratory (NETL) and is implemented

142

Low NOx combustion  

DOE Patents (OSTI)

Combustion of hydrocarbon liquids and solids is achieved with less formation of NOx by feeding a small amount of oxygen into the fuel stream.

Kobayashi, Hisashi (Putnam Valley, NY); Bool, III, Lawrence E. (Aurora, NY)

2008-10-21T23:59:59.000Z

143

Low NOx combustion  

DOE Patents (OSTI)

Combustion of hydrocarbon liquids and solids is achieved with less formation of NOx by feeding a small amount of oxygen into the fuel stream.

Kobayashi; Hisashi (Putnam Valley, NY), Bool, III; Lawrence E. (Aurora, NY)

2007-06-05T23:59:59.000Z

144

NETL: Clean Coal Technology Demonstration Program (CCTDP) - Round 2  

NLE Websites -- All DOE Office Websites (Extended Search)

NOx Control Technologies NOx Control Technologies 180-MWe Demonstration of Advanced Tangentially-Fired Combustion Techniques for the Reduction of NOx Emissions from Coal-Fired Boilers - Project Brief [PDF-280KB] Southern Company Services, Inc., Lynn Haven, FL PROGRAM PUBLICATIONS Final Reports 180-MWe Demonstration of Advanced Tangentially-Fired Combustion Techniques for the Reduction of Nitrogen Oxide (NOx) Emissions from Coal-Fired Boilers, Final Report and Key Project Findings [PDF-4.6MB] (Feb 1994) CCT Reports: Project Performance Summaries, Post-Project Assessments, & Topical Reports 180-MWe Demonstration of Advanced Tangentially Fired Combustion Techniques for the Reduction of NOx Emissions, Project Performance Summary [PDF-1.9MB] (June 1999) The Advanced Tangentially Fired Combustion Techniques for the Reduction of Nitrogen Oxides (NOx) Emissions From Coal-Fired Boilers Demonstration Project: A DOE Assessment [PDF-243KB] (Mar 2000)

145

Advanced Controls Technologies and Strategies Linking Energy...  

NLE Websites -- All DOE Office Websites (Extended Search)

Advanced Controls Technologies and Strategies Linking Energy Efficiency and Demand Response Speaker(s): Sila Kiliccote Date: October 6, 2005 - 12:00pm Location: Bldg. 90 Reliable...

146

Available Technologies Nano Structure Control and ...  

Available Technologies Nano Structure Control and Selectivity of Hydrogen Release from Hydrogen Storage Materials SuMMARy Researchers at PNNL have ...

147

LOW NOx EMISSIONS IN A FUEL FLEXIBLE GAS TURBINE  

SciTech Connect

In alignment with Vision 21 goals, a study is presented here on the technical and economic potential for developing a gas turbine combustor that is capable of generating less that 2 ppm NOx emissions, firing on either coal synthesis gas or natural gas, and being implemented on new and existing systems. The proposed solution involves controlling the quantity of H2 contained in the fuel. The presence of H2 leads to increased flame stability such that the combustor can be operated at lower temperatures and produce less thermal NOx. Coal gas composition would be modified using a water gas shift converter, and natural gas units would implement a catalytic partial oxidation (CPOX) reactor to convert part of the natural gas feed to a syngas before fed back into the combustor. While both systems demonstrated technical merit, the economics involved in implementing such a system are marginal at best. Therefore, Praxair has decided not to pursue the technology any further at this time.

Raymond Drnevich; James Meagher; Vasilis Papavassiliou; Troy Raybold; Peter Stuttaford; Leonard Switzer; Lee Rosen

2004-08-01T23:59:59.000Z

148

Electrothermal controlled-exposure technology  

E-Print Network (OSTI)

A technology is presented for exposing the contents of microfabricated cavities in a substrate. These contents are hermetically sealed until exposure is triggered by an electronic signal. The exposure mechanism uses ...

Maloney, John Mapes

2006-01-01T23:59:59.000Z

149

NETL: Clean Coal Technology Demonstration Program (CCTDP) - Round 2  

NLE Websites -- All DOE Office Websites (Extended Search)

NOx Control Technologies NOx Control Technologies Demonstration of Coal Reburning for Cyclone Boiler NOx Control - Project Brief [PDF-320KB] The Babcock & Wilcox Company, Cassville, WI Program Publications Final Reports Demonstration of Coal Reburning for Cyclone Boiler NOx Control, Final Project Report [PDF-14.4MB] (Feb 1994) Appendices 1 - 5 [PDF-2.6MB] (Feb 1994) Appendix 1: Small Boiler Simulator Description Appendix 2: Statement of Work by Task and Subtask Appendix 3: Evaluation of Reburning for NOx Control from Lignite-Fired Cyclone Boilers Appendix 4: Nelson Dewey In-Furnace gas Species and Temperature Measurements Appendix 5: Balance of Plant Details Appendix 6: Test Report - Nelson Dewey Cyclone Reburn Optimization and Performance Environmental Tests [PDF-6.2MB] (Feb 1994)

150

Discovery of New NOx Reduction Catalysts for CIDI Engines Using Combinatorial Techniques  

SciTech Connect

This project for the discovery of new lean reduction NOx catalysts was initiated on August 16th, 2002 and is now into its fourth year. Several materials have already been identified as NOx reduction catalysts for possible future application. NOx reduction catalysts are a critical need in the North American vehicle market since these catalysts are needed to enable both diesels and lean gasoline engines to meet the 2007-2010 emission standards. Hydrocarbon selective catalytic reduction (SCR) is a preferred technology since it requires no infrastructure changes (as may be expected for urea SCR) and most likely has the simplest engine control strategy of the three proposed NOx reduction approaches. The use of fast throughput techniques and informatics greatly enhances the possibility of discovering new NOx reduction catalysts. Using fast throughput techniques this project has already screened over 3000 new materials and evaluates hundreds of new materials a month. Evaluating such a high number of new materials puts this approach into a very different paradigm than previous discovery approaches for new NOx reduction catalysts. With so much data on materials it is necessary to use statistical techniques to identify the potential catalysts and these statistical techniques are needed to optimize compositions of the multi-component materials that are identified under the program as possible new lean NOx catalysts. Several new materials have conversions in excess of 80% at temperatures above 300 C. That is more than twice the activity of previous HC SCR materials. These materials are candidates for emission control on heavy-duty systems (i.e.; over 8500 pounds gross weight). Tests of one of the downselected materials on an engine dynamometer show NOx reductions greater than 80% under some conditions even though the net NOx reductions on the HWFET and the US06 cycles were relatively low. The program is scheduled to continue until the end of the 2006 calendar year. Work in the final year will focus on continued discovery and identity of candidate materials, and also on refining the engine operating strategies to increase NOx reduction over a full engine cycle.

Blint, Richard J

2005-08-15T23:59:59.000Z

151

NETL: Clean Coal Technology Demonstration Program (CCTDP) - Round 2  

NLE Websites -- All DOE Office Websites (Extended Search)

2 2 Environmental Control Technologies - NOx Control Technologies Demonstration of Selective Catalytic Reduction Technology for the Control of NOx Emissions from High-Sulfur Coal-Fired Boilers - Project Brief [PDF-247KB] Southern Company Services, Pensacola, FL PROGRAM PUBLICATIONS Final Reports Innovative Clean Coal Technologies (ICCT) Demonstration of Selective Catalytic Reduction (SCR) Technology for the Control of Nitrogen Oxide (NOx) Emissions from High-Sulfur Coal-Fired Boilers Volume 1, Final Report [PDF-29MB] (Oct 1996) Volume 2, Appendices A-N [PDF-20.2MB] (Oct 1996) Volume 3, Appendices O-T [PDF-17.9MB] (Oct 1996) CCT Reports: Project Performance Summaries, Post-Project Assessments, & Topical Reports Demonstration Of Selective Catalytic Reduction For The Control Of NOx Emissions From High-Sulfur Coal-Fired Boilers, Project Performance Summary [PDF-1.1MB] (Nov 2002)

152

Selective NOx Recirculation for Stationary Lean-Burn Natural Gas Engines  

Science Conference Proceedings (OSTI)

Selective NOx Recirculation (SNR) involves cooling the engine exhaust gas and then adsorbing the oxides of nitrogen (NOx) from the exhaust stream, followed by the periodic desorption of NOx. By returning the desorbed, concentrated NOx into the engine intake and through the combustion chamber, a percentage of the NOx is decomposed during the combustion process. An initial study of NOx decomposition during lean-burn combustion was concluded in 2004 using a 1993 Cummins L10G 240hp natural gas engine. It was observed that the air/fuel ratio, injected NO (nitric oxide) quantity and engine operating points affected NOx decomposition rates of the engine. Chemical kinetic modeling results were also used to determine optimum NOx decomposition operating points and were published in the 2004 annual report. A NOx decomposition rate of 27% was measured from this engine under lean-burn conditions while the software model predicted between 35-42% NOx decomposition for similar conditions. A later technology 1998 Cummins L10G 280hp natural gas engine was procured with the assistance of Cummins Inc. to replace the previous engine used for 2005 experimental research. The new engine was equipped with an electronic fuel management system with closed-loop control that provided a more stable air/fuel ratio control and improved the repeatability of the tests. The engine was instrumented with an in-cylinder pressure measurement system and electronic controls, and was adapted to operate over a range of air/fuel ratios. The engine was connected to a newly commissioned 300hp alternating current (AC) motoring dynamometer. The second experimental campaign was performed to acquire both stoichiometric and slightly rich (0.97 lambda ratio) burn NOx decomposition rates. Effects of engine load and speed on decomposition were quantified, but Exhaust Gas Recirculation (EGR) was not varied independently. Decomposition rates of up to 92% were demonstrated. Following recommendations at the 2004 ARES peer review meeting at Argonne National Laboratories, in-cylinder pressure was measured to calculate engine indicated mean effective pressure (IMEP) changes due to NOx injections and EGR variations, and to observe conditions in the cylinder. The third experimental campaign gathered NOx decomposition data at 800, 1200 and 1800 rpm. EGR was added via an external loop, with EGR ranging from zero to the point of misfire. The air/fuel ratio was set at both stoichiometric and slightly rich conditions, and NOx decomposition rates were calculated for each set of runs. Modifications were made to the engine exhaust manifold to record individual exhaust temperatures. The three experimental campaigns have provided the data needed for a comprehensive model of NOx decomposition during the combustion process, and data have confirmed that there was no significant impact of injected NO on in-cylinder pressure. The NOx adsorption system provided by Sorbent Technologies Corp. (Twinsburg, OH), comprised a NOx adsorber, heat exchanger and a demister. These components were connected to the engine, and data were gathered to show both the adsorption of NOx from the engine, and desorption of NOx from the carbon-based sorbent material back into the engine intake, using a heated air stream. In order to quantify the NOx adsorption/desorption characteristics of the sorbent material, a bench top adsorption system was constructed and instrumented with thermocouples and the system output was fed into a NOx analyzer. The temperature of this apparatus was controlled while gathering data on the characteristics of the sorbent material. These data were required for development of a system model. Preliminary data were gathered in 2005, and will continue in early 2006. To assess the economic benefits of the proposed SNR technology the WVU research team has been joined in the last quarter by Dr Richard Turton (WVU-Chemical Engineering), who is modeling, sizing and costing the major components. The tasks will address modeling and preliminary design of the heat exchanger, demister and NOx sorbent chamber s

Nigel Clark; Gregory Thompson; Richard Atkinson; Richard Turton; Chamila Tissera; Emre Tatli; Andy Zimmerman

2005-12-28T23:59:59.000Z

153

Available Technologies: Spatially Controlled Surface ...  

This spatial control of functionality is very difficult to achieve with non-grafting techniques currently in use such as direct copolymerization, ...

154

ADVANCED BIOMASS REBURNING FOR HIGH EFFICIENCY NOx CONTROL AND BIOMASS REBURNING - MODELING/ENGINEERING STUDIES JOINT FINAL REPORT  

DOE Green Energy (OSTI)

This report presents results of studies under a Phase II SBIR program funded by the U. S. Department of Agriculture, and a closely coordinated project sponsored by the DOE National Energy Technology Laboratory (NETL, formerly FETC). The overall Phase II objective of the SBIR project is to experimentally optimize the biomass reburning technologies and conduct engineering design studies needed for process demonstration at full scale. The DOE project addresses supporting issues for the process design including modeling activities, economic studies of biomass handling, and experimental evaluation of slagging and fouling. The performance of biomass has been examined in a 300 kW (1 x 10{sup 6} Btu/hr) Boiler Simulator Facility under different experimental conditions. Fuels under investigation include furniture waste, willow wood and walnut shells. Tests showed that furniture pellets and walnut shells provided similar NO{sub x} control as that of natural gas in basic reburning at low heat inputs. Maximum NO{sub x} reduction achieved with walnut shell and furniture pellets was 65% and 58% respectively. Willow wood provided a maximum NO{sub x} reduction of 50% and was no better than natural gas at any condition tested. The efficiency of biomass increases when N-agent is injected into reburning and/or burnout zones, or along with OFA (Advanced Reburning). Co-injection of Na{sub 2}CO{sub 3} with N-agent further increases efficiency of NO{sub x} reduction. Maximum NO{sub x} reduction achieved with furniture pellets and willow wood in Advanced Reburning was 83% and 78% respectively. All combustion experiments of the Phase II project have been completed. All objectives of the experimental tasks were successfully met. The kinetic model of biomass reburning has been developed. Model agrees with experimental data for a wide range of initial conditions and thus correctly represents main features of the reburning process. Modeling suggests that the most important factors that provide high efficiency of biomass in reburning are low fuel-N content and high content of alkali metals in ash. These results indicate that the efficiency of biomass as a reburning fuel may be predicted based on its ultimate, proximate, and ash analyses. The results of experimental and kinetic modeling studies were utilized in applying a validated methodology for reburning system design to biomass reburning in a typical coal-fired boiler. Based on the trends in biomass reburning performance and the characteristics of the boiler under study, a preliminary process design for biomass reburning was developed. Physical flow models were applied to specific injection parameters and operating scenarios, to assess the mixing performance of reburning fuel and overfire air jets which is of paramount importance in achieving target NO{sub x} control performance. The two preliminary cases studied showed potential as candidate reburning designs, and demonstrated that similar mixing performance could be achieved in operation with different quantities of reburning fuel. Based upon this preliminary evaluation, EER has determined that reburning and advanced reburning technologies can be successfully applied using biomass. Pilot-scale studies on biomass reburning conducted by EER have indicated that biomass is an excellent reburning fuel. This generic design study provides a template approach for future demonstrations in specific installations.

Vladimir M. Zamansky; Mark S. Sheldon; Vitali V. Lissianski; Peter M. Maly; David K. Moyeda; Antonio Marquez; W. Randall Seeker

2000-10-01T23:59:59.000Z

155

Field Test of a Catalytic Combustion System for Non-Ammonia Control of Gas Turbine NOx Emissions  

DOE Green Energy (OSTI)

Under federal Award/Proposal Number DE-FG26-04NT42078, the California Energy Commission (CEC) will subgrant $100,000 to the City of Riverside, California, where the project will be located. In turn, the City of Riverside will subaward the federal funds to Alliance Power and/or Catalytica Energy Systems, Inc. (CESI). Alliance Power will coordinate administrative and management activities associated with this task to ensure compliance with CEC grant requirements. CESI will design and fabricate two Xonon{trademark} modules according to General Electric (GE) specification for operating conditions in the GE-10 gas turbine. CESI will ship the modules to the GE test facility for engine testing. CESI will provide test personnel as required to oversee the installation, testing and removal of the Xonon modules. GE will perform an engine test of the CESI-supplied Xonon modules on a GE-10 test engine in the fall of 2004. GE will record all test data as appropriate to evaluate the emissions and operating performance of the Xonon module. Following the test, GE will provide a letter report of the engine test findings. The letter report shall summarize the testing and provide an assessment of Xonon's ability to ultimately achieve less than 3 ppm NOx emissions on the GE-10. All expenses incurred by GE for this task will be paid by GE; no federal funds will be used. Following the reporting of findings, GE will make a decision whether or not to proceed with the Riverside retrofit project. GE will write a letter to CESI giving their decision. GE and CESI will report of engine test findings and the decision letter to the CEC Project Manager.

James F. Burns

2007-07-31T23:59:59.000Z

156

Field Test of a Catalytic Combustion System for Non-Ammonia Control of Gas Turbine NOx Emissions  

SciTech Connect

Under federal Award/Proposal Number DE-FG26-04NT42078, the California Energy Commission (CEC) will subgrant $100,000 to the City of Riverside, California, where the project will be located. In turn, the City of Riverside will subaward the federal funds to Alliance Power and/or Catalytica Energy Systems, Inc. (CESI). Alliance Power will coordinate administrative and management activities associated with this task to ensure compliance with CEC grant requirements. CESI will design and fabricate two Xonon{trademark} modules according to General Electric (GE) specification for operating conditions in the GE-10 gas turbine. CESI will ship the modules to the GE test facility for engine testing. CESI will provide test personnel as required to oversee the installation, testing and removal of the Xonon modules. GE will perform an engine test of the CESI-supplied Xonon modules on a GE-10 test engine in the fall of 2004. GE will record all test data as appropriate to evaluate the emissions and operating performance of the Xonon module. Following the test, GE will provide a letter report of the engine test findings. The letter report shall summarize the testing and provide an assessment of Xonon's ability to ultimately achieve less than 3 ppm NOx emissions on the GE-10. All expenses incurred by GE for this task will be paid by GE; no federal funds will be used. Following the reporting of findings, GE will make a decision whether or not to proceed with the Riverside retrofit project. GE will write a letter to CESI giving their decision. GE and CESI will report of engine test findings and the decision letter to the CEC Project Manager.

James F. Burns

2007-07-31T23:59:59.000Z

157

NETL: Mercury Emissions Control Technologies - University of...  

NLE Websites -- All DOE Office Websites (Extended Search)

control technologies at the pilot scale that show promise for application at plants burning Gulf Coast lignite, or a blend with subbituminous coal. Gulf Coast lignite is one of...

158

Program on Technology Innovation: Future Control Centers  

Science Conference Proceedings (OSTI)

This project reviews the functions and architectures of control centers: their past, present, and likely future. The evolving changes in power system operational needs require a distributed control center that is decentralized, integrated, flexible, and open. Present-day control centers are moving in that direction with varying degrees of success. Technologies employed in today's control centers enabling them to be distributed are briefly reviewed. With the rise of the Internet age, the trend in informat...

2005-08-31T23:59:59.000Z

159

Ion-mobility Spectrometry Based NOx Sensor - Nuclear Engineering Division  

NLE Websites -- All DOE Office Websites (Extended Search)

NPNS > Sensors and NPNS > Sensors and Instrumentation and NDE > Energy System Application > DOE Office of Transportation Technologies > Ion-mobility Spectrometry Based NOx Sensor Capabilities Sensors and Instrumentation and Nondestructive Evaluation Overview Energy System Applications Overview DOE Office of Fossil Energy DOE Office of Transportation Technologies Ion-mobility Spectrometry Based NOx Sensor DOE Office of Power Technology Work for Others Safety-Related Applications Homeland Security Applications Biomedical Applications Millimiter Wave Group Papers Other NPNS Capabilities Work with Argonne Contact us For Employees Site Map Help Join us on Facebook Follow us on Twitter NE on Flickr Sensors and Instrumentation and Nondestructive Evaluation Ion-mobility Spectrometry Based NOx Sensor

160

Development of a Cummins ISL Natural Gas Engine at 1.4g/bhp-hr NOx + NMHC Using PLUS Technology: Final Report  

DOE Green Energy (OSTI)

NREL subcontractor report describes Cummins Westport, Inc.'s development of an 8.9 L natural gas engine (320 hp, 1,000 ft-lb peak torque) with CARB emissions certification of 1.4 g/bhp-hr NOx + NMHC.

Kamel, M. M.

2005-07-01T23:59:59.000Z

Note: This page contains sample records for the topic "nox control technologies" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

A cost-effectiveness analysis of alternative ozone control strategies : flexible nitrogen oxide (NOx) abatement from power plants in the eastern United States  

E-Print Network (OSTI)

Ozone formation is a complex, non-linear process that depends on the atmospheric concentrations of its precursors, nitrogen oxide (NOx) and Volatile Organic Compounds (VOC), as well as on temperature and the available ...

Sun, Lin, S.M. Massachusetts Institute of Technology

2009-01-01T23:59:59.000Z

162

NETL: Clean Coal Technology Demonstration Program (CCTDP) - Round 3  

NLE Websites -- All DOE Office Websites (Extended Search)

Environmental Control Technologies - Combined SO2/NOx Control Technologies Environmental Control Technologies - Combined SO2/NOx Control Technologies Commercial Demonstration of the NOXSO SO2/NOx Removal Flue Gas Cleanup System - Project Brief [PDF-188KB] NOXSO Corporation - Alcoa Warrick Power Station, Hammond, IN Program Publications Final Reports Not Available Annual/Quarterly Technical Reports Commercial Demonstration of the NOXSO SO2/NOx Removal Flue Gas Cleanup System Quarterly Technical Progress Reports Report No. 16. December 1994 - February 1995 [PDF-2.3MB] Report No. 15. (Sept - November 1994 [PDF-2.0MB] Report No. 14. June - August 1994 [PDF-2.8MB] Report No. 13. March - May 1994 [PDF-2.4MB] Report No. 12. December 1993 - February 1994 [PDF-3.0MB] Report No. 11. (Sept - November 1993 [PDF-3.3MB] Report No. 10. June - August 1993 [PDF-3.8MB]

163

Low NOx Advanced Vortex Combustor  

SciTech Connect

A lean-premixed advanced vortex combustor (AVC) has been developed and tested. The natural gas fueled AVC was tested at the U.S. Department of Energys National Energy Technology Laboratory in Morgantown, WV. All testing was performed at elevated pressures and inlet temperatures and at lean fuel-air ratios representative of industrial gas turbines. The improved AVC design exhibited simultaneous NOx /CO/unburned hydrocarbon (UHC) emissions of 4/4/0 ppmv (all emissions corrected to 15% O2 dry). The design also achieved less than 3 ppmv NOx with combustion efficiencies in excess of 99.5%. The design demonstrated marked acoustic dynamic stability over a wide range of operating conditions, which potentially makes this approach significantly more attractive than other lean-premixed combustion approaches. In addition, the measured 1.75% pressure drop is significantly lower than conventional gas turbine combustors, which could translate into an overall gas turbine cycle efficiency improvement. The relatively high velocities and low pressure drop achievable with this technology make the AVC approach an attractive alternative for syngas fuel applications.

Edmonds, R.G. (Ramgen Power Systems, Inc., Bellevue, WA); Williams, J.T. (Ramgen Power Systems, Inc., Bellevue, WA); Steele, R.C. (EPRI); Straub, D.L.; Casleton, K.H.; Bining, Avtar (California Energy Commission, Sacramento, CA)

2008-05-01T23:59:59.000Z

164

Evaluation of Lighting and Lighting Control Technologies  

Science Conference Proceedings (OSTI)

Energy efficient lighting and lighting controls have been a means to significant energy savings for many facilities around the world. Advances in lighting sources often allow for the conservation of quality of light while providing more flexibility in the control of light. Additionally, advances in core technologies within the lighting marketplace regularly lead to the introduction of new lamps, fixtures and controls. With the rapid introduction of new products and designs, it is important to ...

2013-11-15T23:59:59.000Z

165

Vehicle Technologies Office: Thermal Control and System Integration  

NLE Websites -- All DOE Office Websites (Extended Search)

Thermal Control and System Integration to someone by E-mail Share Vehicle Technologies Office: Thermal Control and System Integration on Facebook Tweet about Vehicle Technologies...

166

Vehicle Technologies Office: Emission Control R&D  

NLE Websites -- All DOE Office Websites (Extended Search)

Control R&D The Vehicle Technologies Office (VTO) supports research and development of aftertreatment technologies to control advanced combustion engine exhaust emissions. All...

167

The nuclear materials control technology briefing book  

SciTech Connect

As national and international interests in nuclear arms control and non-proliferation of nuclear weapons, intensify, it becomes ever more important that contributors be aware of the technologies available for the measurement and control of the nuclear materials important to nuclear weapons development. This briefing book presents concise, nontechnical summaries of various special nuclear material (SNM) and tritium production monitoring technologies applicable to the control of nuclear materials and their production. Since the International Atomic Energy Agency (IAEA) operates a multinational, on-site-inspector-based safeguards program in support of the Treaty on the Non-Proliferation of Nuclear Weapons (NPT), many (but not all) of the technologies reported in this document are in routine use or under development for IAEA safeguards.

Hartwell, J.K.; Fernandez, S.J.

1992-03-01T23:59:59.000Z

168

Development of a Low NOx Burner System for Coal Fired Power Plants Using Coal and Biomass Blends  

E-Print Network (OSTI)

The low NOx burner (LNB) is the most cost effective technology used in coal-fired power plants to reduce NOx. Conventional (unstaged) burners use primary air for transporting particles and swirling secondary air to create recirculation of hot gases. LNB uses staged air (dividing total air into primary, secondary and tertiary air) to control fuel bound nitrogen from mixing early and oxidizing to NOx; it can also limit thermal NOx by reducing peak flame temperatures. Previous research at Texas A&M University (TAMU) demonstrated that cofiring coal with feedlot biomass (FB) in conventional burners produced lower or similar levels of NOx but increased CO. The present research deals with i) construction of a small scale 29.31 kW (100,000 BTU/hr) LNB facility, ii) evaluation of firing Wyoming (WYO) coal as the base case coal and cofiring WYO and dairy biomass (DB) blends, and iii) evaluating the effects of staging on NOx and CO. Ultimate and Proximate analysis revealed that WYO and low ash, partially composted, dairy biomass (LA-PC-DB-SepS) had the following heat values and empirical formulas: CH0.6992N0.0122O0.1822S0.00217 and CH_1.2554N_0.0470O_0.3965S_0.00457. The WYO contained 3.10 kg of Ash/GJ, 15.66 kg of VM/GJ, 0.36 kg of N/GJ, and 6.21 kg of O/GJ while LA-PC-DB-SepS contained 11.57 kg of Ash/GJ, 36.50 kg of VM/GJ, 1.50 kg of N/GJ, and 14.48 kg of O/GJ. The construction of a LNB nozzle capable of providing primary, swirled secondary and swirled tertiary air for staging was completed. The reactor provides a maximum residence time of 1.8 seconds under hot flow conditions. WYO and DB were blended on a mass basis for the following blends: 95:5, 90:10, 85:15, and 80:20. Results from firing pure WYO showed that air staging caused a slight decrease of NOx in lean regions (equivalence ratio, greater than or equal to 1.0) but an increase of CO in rich regions (=1.2). For unstaged combustion, cofiring resulted in most fuel blends showing similar NOx emissions to WYO. Staged cofiring resulted in a 12% NOx increase in rich regions while producing similar to slightly lower amounts of NOx in lean regions. One conclusion is that there exists a strong inverse relationship between NOx and CO emissions.

Gomez, Patsky O.

2009-05-01T23:59:59.000Z

169

Adaptive PI control of NOx? emissions in a Urea Selective Catalytic Reduction System using system identification models  

E-Print Network (OSTI)

The Urea SCR System has shown great potential for implementation on diesel vehicles wanting to meet the upcoming emission regulations by the EPA. The objective of this thesis is to develop an adaptive controller that is ...

Ong, Chun Yang

2009-01-01T23:59:59.000Z

170

Evaluation of Gas Reburning & Low NOx Burners on a Wall Fired Boiler Performance and Economics Report Gas Reburning-Low NOx Burner System Cherokee Station Unit 3 Public Service Company of Colorado  

Science Conference Proceedings (OSTI)

Under the U.S. Department of Energy's Clean Coal Technology Program (Round 3), a project was completed to demonstrate control of boiler NOX emissions and to a lesser degree, due to coal replacement, SO2 emissions. The project involved combining Gas Reburning with Low NOX Burners (GR-LNB) on a coal-fired electric utility boiler to determine if high levels of NOX reduction (70%) could be achieved. Sponsors of the project included the U.S. Department of Energy, the Gas Research Institute, Public Service Company of Colorado, Colorado Interstate Gas, Electric Power Research Institute, and the Energy and Environmental Research Corporation. The GR-LNB demonstration was performed on Public Service Company of Colorado's (PSCO) Cherokee Unit #3, located in Denver, Colorado. This unit is a 172 MW~ wall-fired boiler that uses Colorado Bituminous, low-sulfur coal. It had a baseline NOX emission level of 0.73 lb/106 Btu using conventional burners. Low NOX burners are designed to yield lower NOX emissions than conventional burners. However, the NOX control achieved with this technique is limited to 30-50%. Also, with LNBs, CO emissions can increase to above acceptable standards. Gas Reburning (GR) is designed to reduce NOX in the flue gas by staged fuel combustion. This technology involves the introduction of natural gas into the hot furnace flue gas stream. When combined, GR and LNBs minimize NOX emissions and maintain acceptable levels of CO emissions. A comprehensive test program was completed, operating over a wide range of boiler conditions. Over 4,000 hours of operation were achieved, providing substantial data. Measurements were taken to quantify reductions in NOX emissions, the impact on boiler equipment and operability and factors influencing costs. The GR-LNB technology achieved good NOX emission reductions and the goals of the project were achieved. Although the performance of the low NOX burners (supplied by others) was less than expected, a NOX reduction of 65% was achieved at an average gas heat input of 18Y0. The performance goal of 70% reduction was met on many test runs, but at a higher reburn gas heat input. S02 emissions, based on coal replacement, were reduced by 18Y0. The performance goal of 70% reduction was met on many test runs, but at a higher reburn gas heat input. S02 emissions, based on coal replacement, were reduced by 18Y0. Toward the end of the program, a Second Generation gas injection system was installed. Higher injector gas pressures were used that eliminated the need for flue gas recirculation as used in the first generation design. The Second Generation GR resulted in similar NOX reduction performance as that for the First Generation. With an improvement in the LNB performance in combination with the new gas injection system , the reburn gas could be reduced to 12.5% of the total boiler heat input to achieve al 64?40 reduction in NO, emissions. In addition, the OFA injectors were modified to provide for better mixing to lower CO emissions.

None

1998-07-01T23:59:59.000Z

171

Microbial removal of nitrogen oxides from flue gas: The BioDeNOx-process  

E-Print Network (OSTI)

W) facilities. NOx levels below 60 ppm (7% O2) have been reliably achieved, which is a reduction of 70% below combustion controls to maximize NOx reduction and minimize ammonia slip. A simplified version of the process forward in the reduction of NOx emissions from EfW facilities. INTRODUCTION Emissions from U.S. Energy

Dekker, Cees

172

DOE and Industry Showcase New Control Systems Security Technologies...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Electricity Advisory Committee Technology Development Transmission Planning Smart Grid Energy Delivery Systems Cybersecurity Control Systems Security News Archive Control...

173

TransForum v8n2 - DeNOX Catalyst License  

NLE Websites -- All DOE Office Websites (Extended Search)

Integrated Fuel Technologies Gets Worldwide License for Argonne-developed Diesel DeNOX Catalyst Argonne chemist Chris Marshall (front) displays a container of the catalyst while...

174

EA-1472: Commercial Demonstration fo the Low Nox Burner/Separated...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

472: Commercial Demonstration fo the Low Nox BurnerSeparated Over-Fire Air (LNBSOFA) Integration System Emission Reduction Technology, Holcolm Station, Sunflower Electric Power...

175

DEVELOPMENT AND DEMONSTRATION OF NOVEL LOW-NOx BURNERS IN THE STEEL INDUSTRY  

Science Conference Proceedings (OSTI)

Gas Technology Institute (GTI), together with Hamworthy Peabody Combustion Incorporated (formerly Peabody Engineering Corporation), the University of Utah, and Far West Electrochemical have developed and demonstrated an innovative combustion system suitable for natural gas and coke-oven gas firing within the steel industry. The combustion system is a simple, low-cost, energy-efficient burner that can reduce NOx by more than 75%. The U.S. steel industry needs to address NOx control at its steelmaking facilities. A significant part of NOx emissions comes from gas-fired boilers. In steel plants, byproduct gases blast furnace gas (BFG) and coke-oven gas (COG) are widely used together with natural gas to fire furnaces and boilers. In steel plants, natural gas can be fired together with BFG and COG, but, typically, the addition of natural gas raises NOx emissions, which can already be high because of residual fuel-bound nitrogen in COG. The Project Team has applied its expertise in low-NOx burners to lower NOx levels for these applications by combining advanced burner geometry and combustion staging with control strategies tailored to mixtures of natural gas and byproduct fuel gases. These methods reduce all varieties of NOx thermal NOx produced by high flame temperatures, prompt NOx produced by complex chain reactions involving radical hydrocarbon species and NOx from fuel-bound nitrogen compounds such as ammonia found in COG. The Project Team has expanded GTIs highly successful low-NOx forced internal recirculation (FIR) burner, previously developed for natural gas-fired boilers, into facilities that utilize BFG and COG. For natural gas firing, these burners have been shown to reduce NOx emissions from typical uncontrolled levels of 80-100 vppm to single-digit levels (9 vppm). This is done without the energy efficiency penalties incurred by alternative NOx control methods, such as external flue gas recirculation (FGR), water injection, and selective non-catalytic reduction. The FIR burner was previously demonstrated on firetube and watertube boilers, and these units are still operating at several industrial and commercial boiler sites in sizes ranging from 2.5 to 60 million Btu/h. This report covers the development of an innovative combustion system suitable for natural gas or coke-oven gas firing within the steel industry. The prototype FIR burner was evaluated on a 20 million Btu/h watertube boiler. Acceptable burner performance was obtained when firing natural gas and simulated coke-oven gas doped with ammonia. The laboratory data reveals a direct relationship between NOx formation and the ammonia concentration in the fuel. In addition, NOx formation increases as the primary stoichiometric ratio (PSR) increases. Representative ammonia concentrations, as documented in the steel industry, ranged from 200 to 500 vppm. When the laboratory burner/boiler was operated with 500 vppm ammonia in the fuel, NOx emissions ranged from 50 to 75 vppm. This, conservatively, is 75% less than state-of-the-art burner performance. When the burner is operated with 200 vppm ammonia in the fuel, the corresponding NOx emissions would range from 30 to 45 vppm, 84% less than present burner technology. During field evaluation on a 174 million Btu/h industrial prototype burner both natural gas and actual COG from on-site generation were tested. Despite the elevated hydrogen cyanide and ammonia content in the COG throughout the test program, the FIR burner showed an improvement over baseline emissions. At full load; 167 million Btu/h, NOx emissions were relatively low at 169 vppm. This represents a 30% reduction compared to baseline emissions not accounting for the higher hydrogen cyanide content in the COG. CO emissions remained below 20 vppm and were stable across the firing range. This represents a 68% reduction compared to baseline CO emissions. When firing natural gas, emissions were stable as firing rate increased over the range. At low fire; 45 million Btu/h, NOx emissions where 33 vppm and increased at full load; 144 million Btu

Cygan, David

2006-12-28T23:59:59.000Z

176

Plasma Catalysis for NOx Reduction from Light-Duty Diesel Vehicles  

SciTech Connect

The control of NOx (NO and NO2) emissions from so-called lean-burn vehicle engines remains a challenge. In this program, we have been developing a novel plasma/catalyst technology for the remediation of NOx under lean (excess oxygen) conditions, specifically for compression ignition direct injection (CIDI) diesel engines that have significant fuel economy benefits over conventional stoichiometric gasoline engines. Program efforts included: (1) improving the catalyst and plasma reactor efficiencies for NOx reduction; (2) studies to reveal important details of the reaction mechanism(s) that can then guide our catalyst and reactor development efforts; (3) evaluating the performance of prototype systems on real engine exhaust; and (4) studies of the effects of the plasma on particulate matter (PM) in real diesel engine exhaust. Figure 1 is a conceptual schematic of a plasma/catalyst device, which also shows our current best understanding of the role of the various components of the overall device for reducing NOx from the exhaust of a CIDI engine. When this program was initiated, it was not at all clear what the plasma was doing and, as such, what class of catalyst materials might be expected to produce good results. With the understanding of the role of the plasma (as depicted in Figure 1) obtained in this program, faujasite zeolite-based catalysts were developed and shown to produce high activity for NOx reduction of plasma-treated exhaust in a temperature range expected for light-duty diesel engines. These materials are the subject of a pending patent application, and were recognized with a prestigious R&D100 Award in 2002. In addition, PNNL staff were awarded a Federal Laboratory Consortium (FLC) Award in 2003 For Excellence in Technology Transfer. The program also received the DOEs 2001 CIDI Combustion and Emission Control Program Special Recognition Award and 2004 Advanced Combustion Engine R&D Special Recognition Award.

Barlow, Stephan E.; Kwak, Ja Hun; Peden, Charles HF; Szanyi, Janos; Tonkyn, Russell G.; Howden, Ken; Hoard, John W.; Cho, Byong; Schmieg, Steven J.; Brooks, David J.; Nunn, Steven; Davis, Patrick

2004-12-31T23:59:59.000Z

177

Building Technologies Office: Sensors and Controls Research  

NLE Websites -- All DOE Office Websites (Extended Search)

Sensors and Controls Research Sensors and Controls Research The Emerging Technologies team conducts research into technologies related to building sensors and controls. They work with building systems-such as a heating, ventilation, and air conditioning (HVAC) systems-to analyze energy use and help occupants manage energy costs. Building controls have the potential to reduce building energy consumption by monitoring variables and other inputs, and then automatically responding in a predetermined fashion. Research between the Department of Energy, industry, and laboratories focuses on: Sensors Photo of a ceiling-mounted fire sprinkler. Sensors are designed to help building owners and operators better manage their energy use through automation. Sensors measure predefined variables, such as the amount of natural light coming in through an office window, and then feed this data into a building's control system. The control can then respond by adjusting the various building systems. For example, sensors may note when a person leaves a room and let controls know to turn off the lights, or can ensure that faucets only release water if someone's hand is waved.

178

NETL: Control Technology: Advanced Hybrid Particulate Collector  

NLE Websites -- All DOE Office Websites (Extended Search)

Advanced Hybrid Particulate Collector Advanced Hybrid Particulate Collector Under DOE-NETL sponsorship, the University of North Dakota, Energy and Environmental Research Center (UND-EERC) has developed a new concept in particulate control, called an advanced hybrid particulate collector (AHPC). In addition to DOE and the EERC, the project team includes W.L. Gore & Associates, Inc., Allied Environmental Technologies, Inc., and the Otter Tail Power Company. The AHPC utilizes both electrostatic collection and filtration in a unique geometric configuration that achieves ultrahigh particle collection with much less collection area than conventional particulate control devices. The primary technologies for state-of-the-art particulate control are fabric filters (baghouses) and electrostatic precipitators (ESPs). A major limitation of ESPs is that the fractional penetration of 0.1- to 1.0-µm particles is typically at least an order of magnitude greater than for 10-µm particles, so a situation exists where the particles that are of greatest health concern are collected with the lowest efficiency. Fabric filters are currently considered to be the best available control technology for fine particles, but emissions are dependent on ash properties and typically increase if the air-to-cloth (A/C) ratio is increased. In addition, many fabrics cannot withstand the rigors of high-SO2 flue gases, which are typical for bituminous fuels. Fabric filters may also have problems with bag cleanability and high pressure drop, which has resulted in conservatively designed, large, costly baghouses.

179

Vehicle Technologies Office: Thermal Control and System Integration  

NLE Websites -- All DOE Office Websites (Extended Search)

Thermal Control and System Integration The thermal control and system integration activity focuses on issues such as the integration of motor and power control technologies and the...

180

2006 Mercury Control Technology Conference Proceedings  

NLE Websites -- All DOE Office Websites (Extended Search)

Mercury Control Technology Conference Mercury Control Technology Conference December 11-13, 2006 Table of Contents Disclaimer Papers and Presentations Introduction Sorbent Injection By-Product Characterization/Management Mercury Oxidation and Co-Removal with FGD Systems Other Mercury Control Technology Panel Discussions Posters New 2006 Phase III Mercury Field Testing Projects Sorbent Injection Pretreatment of Coal Oxidation of Mercury Environmental Studies on Mercury Mercury in CUBs Disclaimer This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government or any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. Reference herein to any specific commercial product, process, or service by trade name, trademark, manufacturer, or otherwise does not necessarily constitute or imply its endorsement, recommendation, or favoring by the United States Government or any agency thereof. The views and opinions of authors expressed herein do not necessarily state or reflect those of the United States Government or any agency thereof.

Note: This page contains sample records for the topic "nox control technologies" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

500 MW demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NOx) emissions from coal-fired boilers. Technical progress report, fourth quarter, 1994, October 1994--December 1994  

Science Conference Proceedings (OSTI)

This quarterly report discusses the technical progress of an innovative Clean Coal Technology (ICCT) demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NOx) emissions from coal-fired boilers. The project is being conducted at Georgia Power Company`s Plant Hammond Unit 4 located near Rome, Georgia. The primary goal of this project is the characterization of the low NOx combustion equipment through the collection and analysis of long-term emissions data. The project provides a stepwise evaluation of the following NOx reduction technologies: Advanced overfire air (AOFA), Low NOx burners (LNB), LNB with AOFA, and Advanced Digital Controls and Optimization Strategies. The project has completed the baseline, AOFA, LNB, and LNB+AOFA test segments, fulfilling all testing originally proposed to DOE. Analysis of the LNB long-term data collected show the full load NOx emission levels to be near 0.65 lb/MBtu. This NOx level represents a 48 percent reduction when compared to the baseline, full load value of 1.24 lb/MBtu. These reductions were sustainable over the long-term test period and were consistent over the entire load range. Full load, fly ash LOI values in the LNB configuration were near 8 percent compared to 5 percent for baseline. Results from the LNB+AOFA phase indicate that full load NOx emissions are approximately 0.40 lb/MBtu with a corresponding fly ash LOI value of near 8 percent. Although this NOx level represents a 67 percent reduction from baseline levels, a substantial portion of the incremental change in NOx emissions between the LNB and LNB+AOFA configurations was the result of operational changes and not the result of the AOFA system. Phase 4 of the project is now underway.

NONE

1995-09-01T23:59:59.000Z

182

Vehicle Technologies Office: Emission Control R&D  

NLE Websites -- All DOE Office Websites (Extended Search)

Emission Control R&D to Emission Control R&D to someone by E-mail Share Vehicle Technologies Office: Emission Control R&D on Facebook Tweet about Vehicle Technologies Office: Emission Control R&D on Twitter Bookmark Vehicle Technologies Office: Emission Control R&D on Google Bookmark Vehicle Technologies Office: Emission Control R&D on Delicious Rank Vehicle Technologies Office: Emission Control R&D on Digg Find More places to share Vehicle Technologies Office: Emission Control R&D on AddThis.com... Just the Basics Hybrid & Vehicle Systems Energy Storage Advanced Power Electronics & Electrical Machines Advanced Combustion Engines Combustion Engines Emission Control Waste Heat Recovery Fuels & Lubricants Materials Technologies Emission Control R&D

183

Experience curves for power plant emission control technologies  

E-Print Network (OSTI)

power plant emission control technologies Historical growthpower plant emission control technologies The environmental policy initiatives responsible for the substantial growthfired power plants. E.S. Rubin et al. Historical growth in

Rubin, Edward S.; Yeh, Sonia; Hounshell, David A

2007-01-01T23:59:59.000Z

184

FEMP Technology Brief: Boiler Combustion Control and Monitoring...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Boiler Combustion Control and Monitoring System FEMP Technology Brief: Boiler Combustion Control and Monitoring System October 7, 2013 - 9:12am Addthis This composite photo shows...

185

Fuel Cell Technologies Office: Controlled Hydrogen Fleet and...  

NLE Websites -- All DOE Office Websites (Extended Search)

Controlled Hydrogen Fleet and Infrastructure Demonstration and Validation Project Solicitation to someone by E-mail Share Fuel Cell Technologies Office: Controlled Hydrogen Fleet...

186

Interpreting Remote Sensing NOx Measurements  

E-Print Network (OSTI)

Interpreting Remote Sensing NOx Measurements Robert Slott, Consultant, Donald Stedman and Saj tailpipe emissions (HC, CO, NOx) are changing with time hUse remote sensing hMeasurements in at least 4 of the year at each location hUniform QC/QA and data reporting Paper # 2001-01-3640 #12;Remote Sensing

Denver, University of

187

NOx reduction with the use of feedlot biomass as a reburn fuel  

E-Print Network (OSTI)

Coal fired power plants produce NOx at unacceptable levels. In order to control these emissions without major modifications to the burners, additional fuel called reburn fuel is fired under rich conditions (10-30 % by heat) after the coal burners. Additional air called overfire air (about 20 % of total air) is injected in order to complete combustion. Typically reburn fuel is natural gas (NG). From previous research at TAMU, it was found that firing feedlot biomass (FB) as reburn fuel lowers the NOx emission at significant levels compared to NG. The present research was conducted to determine the optimum operating conditions for the reduction of NOx. Experiments were performed in a small scale 29.3 kW (100,000 BTU/hr) reactor using low ash partially composted FB (LA PC FB) with equivalence ratio ranging from 1 to 1.15. The results of these experiments show that NOx levels can be reduced by as much as 90% - 95 % when firing pure LA PC FB and results are almost independent of. The reburn fuel was injected with normal air and then vitiated air (12.5 % O2); further the angles of reburn injector were set normal to the main gas flow and at 45-degrees upward. For LA PC FB no significant changes were observed; but high ash PC FB revealed better reductions with 45-degrees injector and vitiated air. This new technology has the potential to reduce NOx emissions in coal fired boilers located near cattle feedlots and also relieves the cattle industry of the waste.

Goughnour, Paul Gordon

2006-08-01T23:59:59.000Z

188

Status and Performance of Best Available Control Technologies  

Science Conference Proceedings (OSTI)

This study is intended to provide a better understanding of the best available control technology (BACT) as required today in permits issued for new coal-fired power plants and to document the actual emissions performance of the emission control technologies on new units. The study focused on controls technologies, data reporting, initial test results, and permitting trends.

2005-03-28T23:59:59.000Z

189

NETL: Clean Coal Technology Demonstration Program (CCTDP) - Round 2  

NLE Websites -- All DOE Office Websites (Extended Search)

SOx-NOx-Rox Box(tm) Flue Gas Cleanup Demonstration Project - Project Brief [PDF-317KB] SOx-NOx-Rox Box(tm) Flue Gas Cleanup Demonstration Project - Project Brief [PDF-317KB] The Babcock & Wilcox Co., Dilles Bottom, OH PROGRAM PUBLICATIONS Final Reports SOx-NOx-Rox Box(tm) Flue Gas Cleanup Demonstration Final Report [PDF-27.5MB] (Sept 1995) CCT Reports: Project Performance Summaries, Post-Project Assessments, & Topical Reports SOx-NOx-Rox Box(tm) Flue Gas Cleanup Demonstration: A DOE Assessment [PDF-296KB] (Dec 2000) SOx-NOx-Rox Box(tm) Flue Gas Cleanup Demonstration Project, Project Performance Summary [PDF-1.4MB] (June 1999) Technologies for the Combined Control of Sulfur Dioxide and Nitrogen Oxides Emissions from Coal-Fired Boilers, Topical Report No. 13 [PDF-500KB] (May 1999) Design Reports 5 MWe SNRBT Demonstration Facility: Detailed Design Report [PDF-4.5MB] (Nov 1992)

190

Sulfur Poisoning and Regeneration of NOx Storage-Reduction Cu/K2Ti2O5 Qiang Wang,*,  

E-Print Network (OSTI)

aiming at NOx emission reduction are less effective in controlling the fate of char-N than volatile designated LNCFSTM level I, II and III, as shown in Figure 4.29, resulted in NOx reductions of 20% for levels and fuel quality and economic factors related to boiler age and size. An impression of what NOx reductions

Guo, John Zhanhu

191

Key Issues in the Design of NOx Emission Trading Programs to Reduce Ground-Level Ozone  

Science Conference Proceedings (OSTI)

As NOx control requirements grow more stringent and expensive, interest in emission trading as a means of controlling costs and increasing flexibility has risen. This report provides background information for and analysis of the design of emission trading programs for control of nitrogen oxides (NOx) from stationary sources, including fossil fuel electric generating plants.

1994-10-07T23:59:59.000Z

192

NETL: Mercury Emissions Control Technologies - Brominated Sorbents...  

NLE Websites -- All DOE Office Websites (Extended Search)

ESPs, and Fly Ash Use in Concrete Sorbent Technology will test two technologies for mercury removal from flue gas. Their concrete safe brominated sorbent will be tested at...

193

Program on Technology Innovation: Next Generation Monitoring, Assessment, and Control  

Science Conference Proceedings (OSTI)

Power system operation technologies such as computerized one-line diagram visualization, state estimation, contingency analysis, and distance relay were developed upwards of 50 years ago, However, technological advances in communication, computing, and algorithms have made it possible to reexamine methods for performing real-time monitoring, assessment, and control. This report describes the vision, infrastructure, and technology roadmap for future smart control centers.

2009-01-22T23:59:59.000Z

194

Integration of building envelope and services via control technologies  

Science Conference Proceedings (OSTI)

The last decade offered the foundation of several seminal concepts, which although natively composite and complex, amply demonstrate the potential of 21st century technology to affect important societal trends. Among notable candidates, the convergence ... Keywords: A/V ratio, EIB- KONNEX technology, bioclimatic architecture, bits, building envelope, building facades, bytes, communication protocols, control technologies, data telegram, integration, power line technology, services

Chris J. Koinakis; John K. Sakellaris

2009-07-01T23:59:59.000Z

195

Building Technologies Office: Open-Standard Wireless Controllers for Water  

NLE Websites -- All DOE Office Websites (Extended Search)

Open-Standard Wireless Open-Standard Wireless Controllers for Water Heaters Research Project to someone by E-mail Share Building Technologies Office: Open-Standard Wireless Controllers for Water Heaters Research Project on Facebook Tweet about Building Technologies Office: Open-Standard Wireless Controllers for Water Heaters Research Project on Twitter Bookmark Building Technologies Office: Open-Standard Wireless Controllers for Water Heaters Research Project on Google Bookmark Building Technologies Office: Open-Standard Wireless Controllers for Water Heaters Research Project on Delicious Rank Building Technologies Office: Open-Standard Wireless Controllers for Water Heaters Research Project on Digg Find More places to share Building Technologies Office: Open-Standard Wireless Controllers for Water Heaters Research Project on

196

FEMP Technology Brief: Boiler Combustion Control and Monitoring System |  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Boiler Combustion Control and Monitoring Boiler Combustion Control and Monitoring System FEMP Technology Brief: Boiler Combustion Control and Monitoring System October 7, 2013 - 9:12am Addthis This composite photo shows technicians observing operation at the monitoring station and making subsequent fine adjustments on combustion system controls Technical staff are making boiler adjustments with the control and monitoring system. Photo courtesy of the Department of Defense's Environmental Security Technology Certification Program. Technology Description A novel combustion control system, along with gas sensors, sets the opening of fuel and air inlets based on flue-gas concentrations. Continuous feedback from measurements of oxygen, carbon monoxide, and nitrogen oxide concentrations enable the control system

197

Coal Ash Carbon Removal Technologies  

Science Conference Proceedings (OSTI)

Market resistance to the use of ash containing elevated levels of carbon and/or ammonia has become a major concern for coal-fired facilities in recent years as a result of increased use of nitrogen oxide (NOx) reduction environmental control technologies. EPRI initiated this state of practice assessment to help power producers evaluate alternatives for ash beneficiation.

2001-11-01T23:59:59.000Z

198

Division of Environmental Control Technology program, 1977  

DOE Green Energy (OSTI)

Environmental engineering programs are reviewed for the following technologies; coal; petroleum and gas; oil shale; solar; geothermal and energy conservation; nuclear energy; and decontamination and decommissioning. Separate abstracts were prepared for each technology. (MHR)

None

1978-06-01T23:59:59.000Z

199

Technology Innovations and Experience Curves for Nitrogen Oxides Control Technologies  

E-Print Network (OSTI)

x Abatement and Control. IEA Coal Research: London, UnitedM. Air Pollution Control Costs for Coal-Fired PowerStations; IEA Coal Research: London, UK, 1995. 25. Arrow, K.

Yeh, Sonia; Rubin, Edward S.; Taylor, Margaret R.

2007-01-01T23:59:59.000Z

200

NETL: Mercury Emissions Control Technologies - Long-Term Demonstration...  

NLE Websites -- All DOE Office Websites (Extended Search)

Long-Term Demonstration of Sorbent Enhancement Additive Technology for Mercury Control In this project, The University of North Dakota Energy & Environmental Research Center...

Note: This page contains sample records for the topic "nox control technologies" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Technology Reviews | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Technology Reviews Technology Reviews Technology Reviews November 1, 2013 - 11:40am Addthis Selecting a distributed energy (DE) technology for a specific application depends on many factors. Considerations include the amount of power needed, the duty cycle, space constraints, thermal needs, emission regulations, fuel availability, utility prices, and interconnection issues. The following technology reviews include descriptions of a variety of DE and combined heat and power (CHP) technologies, providing (when available) such parameters as efficiency, size, and projected cost to install and maintain. Behavior of Capstone and Honeywell Microturbine Generators During Load Changes, 38 pp, Feb. 2004 Catalogue of CHP Technologies, Dec. 2012 Cost Analysis of Nitrogen Oxide (NOx) Control Alternatives for

202

Building Technologies Office: Advanced, Integrated Control for...  

NLE Websites -- All DOE Office Websites (Extended Search)

Buildings News Building Technologies Office Announces 3 Million to Advance Building Automation Software Solutions in Small to Medium-Sized Commercial Buildings March 29,...

203

Building Technologies Office: Sensors and Controls Characteristics...  

NLE Websites -- All DOE Office Websites (Extended Search)

Buildings News Building Technologies Office Announces 3 Million to Advance Building Automation Software Solutions in Small to Medium-Sized Commercial Buildings March 29,...

204

Available Technologies: Controlled Assembly of Nanocrystal ...  

See More Nano & Micro Technologies. Contact Us. Receive Customized Tech Alerts. Tech Transfer Site Map. Last updated: 09/17/2009.

205

Exhaust Speciation Studies for Aftertreatment Technology Development  

DOE Green Energy (OSTI)

Lean NOx reduction shown to be strongly affected by HC reductant composition. Possibility exists to tailor exhaust HC composition by manipulating HC post-injection process. Why is this relevant if lean NOx catalysis ''isn't going to work'' ? Lean NOx (esp. with post-injection of HC) offers unmatched ''passiveness'' NOx adsorber technology will require reductant - potentially introduced the same way

Graves, Ron

2000-08-20T23:59:59.000Z

206

EA-1472: Commercial Demonstration fo the Low Nox Burner/Separated Over-Fire  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

472: Commercial Demonstration fo the Low Nox Burner/Separated 472: Commercial Demonstration fo the Low Nox Burner/Separated Over-Fire Air (LNB/SOFA) Integration System Emission Reduction Technology, Holcolm Station, Sunflower Electric Power Corporation Finnety County, Kansas EA-1472: Commercial Demonstration fo the Low Nox Burner/Separated Over-Fire Air (LNB/SOFA) Integration System Emission Reduction Technology, Holcolm Station, Sunflower Electric Power Corporation Finnety County, Kansas SUMMARY The DOE has prepared an Environmental Assessment (EA), to analyze the potential impacts of the commercial application of the Low-NOx Burner/Separated Over-Fire Air (LNB/SOFA) integration system to achieve nitrogen oxide (NOx) emissions reduction at Sunflower's Holcomb Unit No. 1 (Holcomb Station), located near Garden City, in Finney County, Kansas.

207

NETL: Mercury Emissions Control Technologies - Development of Comprehensive  

NLE Websites -- All DOE Office Websites (Extended Search)

Full-Scale Testing of Mercury Control Via Sorbent Injection Full-Scale Testing of Mercury Control Via Sorbent Injection DOE has identified technologies (based on past DOE and other R&D organizations' mercury measurement and control achievements) that are expected to be important in developing possible strategies on mercury control for the coal-fired electric utility industry. To address critical questions related to cost and efficiency of these mercury control technologies, DOE has funded the first of a kind large-scale initiative aimed at testing and evaluating large-scale mercury control technologies for coal-based power systems. These tests will collect cost and performance data with parametric and long term field experiments at power plants with existing air pollution control devices (APCDs) utilized to control other pollutants as well as mercury in hopes of providing the cheapest control options for the utility industry in mid-term application (5 to 10 years).

208

Advanced Instrumentation, Information, and Control Systems Technologies Technical Program Plan  

SciTech Connect

Reliable instrumentation, information, and control (II&C) systems technologies are essential to ensuring safe and efficient operation of the U.S. light water reactor (LWR) fleet. These technologies affect every aspect of nuclear power plant (NPP) and balance-of-plant operations. In 1997, the National Research Council conducted a study concerning the challenges involved in modernization of digital instrumentation and control systems in NPPs. Their findings identified the need for new II&C technology integration.

Bruce Hallbert

2012-09-01T23:59:59.000Z

209

Available Technologies: Electronic Control of Friction on ...  

... motor vehicles, and tools. Existing methods of friction control involve permanently modifying surfaces by adding lubricant layers and hard ...

210

Available Technologies Grid Friendly Appliance Controller  

The Grid Friendly Appliance controller developed at PNNL senses grid conditions ... Smart Grid Devices potential industry Applications Computers ...

211

NOX REDUCTION FOR LEAN EXHAUST USING PLASMA ASSISTED CATALYSIS  

DOE Green Energy (OSTI)

Currently CARB estimates on road diesel vehicles contribute 50% of the NOX and 78% of the particulates being discharged from mobile sources. Diesel emissions obviously must be reduced if future air quality targets are to be met. A critical technological barrier exists because there are no commercial technologies available, which can reduce NOX from diesel (lean), exhaust containing 5-15% O2 concentration. One promising approach to reducing NOX and particulates from diesel exhaust is to use a combination of plasma with catalyst. Plasma can be generated thermally or non-thermally. Thermal plasma is formed by heating the system to an exceedingly high temperature (>2000 C). High temperature requirements for plasma makes thermal plasma inefficient and requires skillful thermal management and hence is considered impractical for mobile applications. Non-thermal plasma directs electrical energy into the creation of free electrons, which in turn react with gaseous species thus creating plasma. A combination of non-thermal plasma with catalysts can be referred to Plasma Assisted Catalysts or PAC. PAC technology has been demonstrated in stationary sources where non-thermal plasma catalysis is carried out in presence of NH3 as a reductant. In stationary applications NO is oxidized to HNO3 and then into ammonium nitrate where it is condensed and removed. This approach is impractical for mobile application because of the ammonia requirement and the ultimate mechanism by which NOX is removed. However, if a suitable catalyst can be found which can use onboard fuel as reductant then the technology holds a considerable promise. NOX REDUCTION FOR LEAN EXHAUST USING PLASMA ASSISTED CATALYSIS Ralph Slone, B. Bhatt and Victor Puchkarev NOXTECH INC. In addition to the development of an effective catalyst, a non-thermal plasma reactor needs be scaled and demonstrated along with a reliable and cost effective plasma power source and onboard HC source needs to be proven. Under the work sponsored by DOE and SCAQMD Noxtech is developing a cost effective and reliable PAC system for mobile applications. The goal of the program is to develop a suitable catalyst with the ability to remove high levels of NOx at reasonable space velocities. This new catalyst will then be used to scale the technology to treat exhaust from 80Hp engine and eventually to demonstrate the technology on 200 and 400 Hp engine applications. Using the 2004 EPA proposed regulation as a standard, it is clear in order for PAC system to be commercially viable it needs to remove NOX by 70% or better. It is further assumed from past experience that 30,000 HR-1 space velocities are necessary to ensure a good compact design.

Bhatt, B.

2000-08-20T23:59:59.000Z

212

Reactive based NOx sensor  

E-Print Network (OSTI)

Diesel engines exhibit better fuel economy and emit fewer greenhouse gases than gasoline engines. Modern diesel technology has virtually eliminated carbon monoxide and particulate emissions. Sulfur oxide emissions have ...

Vassiliou, Christophoros Christou

2006-01-01T23:59:59.000Z

213

NOx Adsorbers for Heavy Duty Truck Engines-Testing and Simulation  

DOE Green Energy (OSTI)

This feasibility study of NOx adsorbers in heavy-duty diesel engines examined three configurations (dual-leg, single-leg and single-leg-bypass) in an integrated experimental setup, composed of a Detroit Diesel Class-8 truck engine, a catalyzed diesel particulate filter and the NOx absorber system. The setup also employed a reductant injection concept, sensors and advanced control strategies.

Hakim, N; Hoelzer, J.; Liu, Y.

2002-08-25T23:59:59.000Z

214

Demonstration of a Low-NOx Heavy-Duty Natural Gas Engine  

DOE Green Energy (OSTI)

Results of a Next Generation Natural Gas Vehicle engine research project: A Caterpillar C-12 natural gas engine with Clean Air Power Dual-Fuel technology and exhaust gas recirculation demonstrated low NOx and PM emissions.

Not Available

2004-02-01T23:59:59.000Z

215

A design strategy applied to sulfur resistant lean NOx̳ automotive catalysts  

E-Print Network (OSTI)

Catalyst poisoning due to sulfur compounds derived from fuel sulfur presents a major challenge, intractable thus far, to development of many advanced technologies for automotive catalysts such as the lean NOx, trap. Under ...

Tang, Hairong

2005-01-01T23:59:59.000Z

216

Noise-control needs in the developing energy technologies  

DOE Green Energy (OSTI)

The noise characteristics of existing energy conversion technologies, e.g., from obtaining and processing fossil fuels to power plants operations, and of developing energy technologies (wind, geothermal sources, solar energy or fusion systems) are discussed in terms of the effects of noise on humans, animals, structures, and equipment and methods for noise control. Regulations for noise control are described. Recommendations are made for further research on noise control and noise effects. (LCL)

Keast, D.N.

1978-03-01T23:59:59.000Z

217

NOx Compliance Using the NOxOUT SNCR Process in the 1200 TPD Montgomery County  

E-Print Network (OSTI)

or RDF. NOx reduction by use of catalytic reduction and ammonia injection are clearly impractical research in this area, so that we can understand the principles of NOx reduction sufficiently to fill our·lined in cinerator by Hiraoka [2] reveals a reduction from 150 ppm NOx to below 100 ppm NOx (at 12% O2) by using

Columbia University

218

Some theoretical results concerning O3-NOx-VOC chemistry and NOx-VOC indicators  

E-Print Network (OSTI)

of modi®ed aircraft NOx emissions, a signi- ®cant reduction of the aircraft-induced NOx and ozone emissions are given in Fig. 6 for the reference year 1990. The reduction of the NOx perturbation is largest-day and future impact of NOx emissions 1073 #12;In July, a maximum reduction between 10 and 20 pptv is found

Sillman, Sanford

219

DOE and Industry Showcase New Control Systems Security Technologies at  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Technology Development » Energy Delivery Systems Technology Development » Energy Delivery Systems Cybersecurity » Control Systems Security News Archive » DOE and Industry Showcase New Control Systems Security Technologies at DistribuTECH DOE and Industry Showcase New Control Systems Security Technologies at DistribuTECH DistribuTECH Conference Tuesday-Thursday, March 23-25, 2010 Tampa Convention Center Booth #231 Tampa, FL Join the Department of Energy and its industry partners as they showcase six new products and technologies designed to secure the nation's energy infrastructure from cyber attack on Tuesday through Thursday, March 23-25. Visit Booth #231 at the DistribuTECH 2010 Conference & Exhibition in Tampa, FL, to see first-hand demonstrations of several newly commercialized control systems security products-each developed through a

220

Available Technologies: Ventilation Controller for Improved Indoor ...  

Iain Walker and colleagues at Berkeley Lab have developed a dynamic control system for whole-house ventilation fans that provides maximal air quality while reducing ...

Note: This page contains sample records for the topic "nox control technologies" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Available Technologies: Controlling Metabolic Pathways Using ...  

Biofuels and biofuel precursors; Secondary metabolite ... the transcription factors are inserted at strategic spots to control target metabolic pathways of yeast ...

222

Grid Friendly Charger Controller - Available Technologies ...  

Daily battery charging is fully automatic with the Grid Friendly ... Reduced electricity costs for consumersthe Grid Friendly Charger Controller ...

223

NETL: Mercury Emissions Control Technologies - Modifications...  

NLE Websites -- All DOE Office Websites (Extended Search)

Mercury Control Jointly funded by DOE and the Electric Power Research Institute (EPRI), this project's purpose is to investigate novel approaches of capturing elemental and...

224

4, 62396281, 2004 lightning-NOx on  

E-Print Network (OSTI)

accurate model responses under the 25% VOC or NOx emission reduction scenarios but inaccurate results under the 75% NOx emission reduction scenario. OSAT predicts accurate model responses under the 25% VOC emission reduction scenario, but inaccurate responses under the 25% and 75% NOx emission reduction

Paris-Sud XI, Université de

225

LNG fire and vapor control system technologies  

SciTech Connect

This report provides a review of fire and vapor control practices used in the liquefied natural gas (LNG) industry. Specific objectives of this effort were to summarize the state-of-the-art of LNG fire and vapor control; define representative LNG facilities and their associated fire and vapor control systems; and develop an approach for a quantitative effectiveness evaluation of LNG fire and vapor control systems. In this report a brief summary of LNG physical properties is given. This is followed by a discussion of basic fire and vapor control design philosophy and detailed reviews of fire and vapor control practices. The operating characteristics and typical applications and application limitations of leak detectors, fire detectors, dikes, coatings, closed circuit television, communication systems, dry chemicals, water, high expansion foam, carbon dioxide and halogenated hydrocarbons are described. Summary descriptions of a representative LNG peakshaving facility and import terminal are included in this report together with typical fire and vapor control systems and their locations in these types of facilities. This state-of-the-art review identifies large differences in the application of fire and vapor control systems throughout the LNG industry.

Konzek, G.J.; Yasutake, K.M.; Franklin, A.L.

1982-06-01T23:59:59.000Z

226

Near-Zero Emissions Oxy-Combustion Flue Gas Purification Task 2: SOx/Nox/Hg Removal for High Sulfur Coal  

Science Conference Proceedings (OSTI)

The goal of this project is to develop a near-zero emissions flue gas purification technology for existing PC (pulverized coal) power plants that are retrofitted with oxy-combustion technology. The objective of Task 2 of this project was to evaluate an alternative method of SOx, NOx and Hg removal from flue gas produced by burning high sulfur coal in oxy-combustion power plants. The goal of the program was not only to investigate a new method of flue gas purification but also to produce useful acid byproduct streams as an alternative to using a traditional FGD and SCR for flue gas processing. During the project two main constraints were identified that limit the ability of the process to achieve project goals. 1) Due to boiler island corrosion issues >60% of the sulfur must be removed in the boiler island with the use of an FGD. 2) A suitable method could not be found to remove NOx from the concentrated sulfuric acid product, which limits sale-ability of the acid, as well as the NOx removal efficiency of the process. Given the complexity and safety issues inherent in the cycle it is concluded that the acid product would not be directly saleable and, in this case, other flue gas purification schemes are better suited for SOx/NOx/Hg control when burning high sulfur coal, e.g. this project's Task 3 process or a traditional FGD and SCR.

Nick Degenstein; Minish Shah; Doughlas Louie

2012-05-01T23:59:59.000Z

227

ENERGY UTILIZATION AND ENVIRONMENTAL CONTROL TECHNOLOGIES IN THE COAL-ELECTRIC CYCLE  

E-Print Network (OSTI)

simultaneous NOx-SO x reduction with coal derived reductfor Catalytic NO x and NOx-SO x Reduction Schemes on 800 MwRe6uctfon Process 2 NOx-SO x Reduction Sulfide Process 3 New

Ferrell, G.C.

2010-01-01T23:59:59.000Z

228

Technology Assessment Report: Duty Cycling Controllers Revisited  

SciTech Connect

This report covers an assessment of two brands of energy management controllers that are currently being offered that utilize the principle of duty cycling to purportedly save energy for unitary air conditioners and heat pumps, gas furnaces, and gas fired boilers. The results of an extensive review of past research on this subject as well as a review of vendor sponsored field testing of these controllers compares these newer controllers to those of the past. Included also is a discussion of how the duty cycling principle is prone to misinterpretation as to its potential to save energy.

Webster, Tom; Benenson, Peter

1998-05-01T23:59:59.000Z

229

Demonstration of Demand Control Ventilation Technology  

Science Conference Proceedings (OSTI)

Demand Control Ventilation (DCV) is one of the control strategies that can be used modulate the amount of ventilation air for space conditioning in commercial buildings. DCV modulates the amount of ventilation air introduced into the heating, ventilation and air conditioning (HVAC) system based on carbon dioxide levels sensed in the areas served. The carbon dioxide level is a proxy for the number of people within the space, from which the required quantity of ventilation air is determined. By using this ...

2011-12-30T23:59:59.000Z

230

Mechanisms of Sulfur Poisoning of NOx Adsorber Materials  

Science Conference Proceedings (OSTI)

This annual report will review progress of the initial 4 months of a three-year effort between Cummins Engine Company and Pacific Northwest National Laboratory to understand and improve the performance and sulfur tolerance of the materials used in the NOx adsorber after-treatment technology in order to meet both performance and reliability standards required for diesel engines. The goal of this project is to enable NOx after-treatment technologies that will meet both EPA 2007 emission standards and customer cost, reliability and durability requirements. The project will consist of three phases. First, the efforts will focus on understanding the current limitation of capture, regeneration and durability of existing NOx adsorber materials, especially with respect to their sulfur tolerance. With this developing understanding, efforts will also be focused on the optimization of the NOx absorber chemical and material properties to increase performance and durability over many regeneration cycles. We anticipate that improved materials will be tested and evaluated, in partnership with Cummins, on diesel vehicle engines over expected operating conditions.

Kim, Do Heui; Chin, Ya-Huei; Muntean, George G.; Peden, Charles HF; Stork, Kevin; Broering, L. C.; Stafford, R. J.; Stang, J. H.; Chen, H.-Y.; Cooper, B.; Hess, H.; Lafyatis, D.

2004-10-01T23:59:59.000Z

231

THE EFFECT OF SULFUR ON METHANE PARTIAL OXIDATION AND REFORMING PROCESSES FOR LEAN NOX TRAP CATALYSIS  

Science Conference Proceedings (OSTI)

Lean NOx trap catalysis has demonstrated the ability to reduce NOx emissions from lean natural gas reciprocating engines by >90%. The technology operates in a cyclic fashion where NOx is trapped on the catalyst during lean operation and released and reduced to N2 under rich exhaust conditions; the rich cleansing operation of the cycle is referred to as "regeneration" since the catalyst is reactivated for more NOx trapping after NOx purge. Creating the rich exhaust conditions for regeneration can be accomplished by catalytic partial oxidation of methane in the exhaust system. Furthermore, catalytic reforming of partial oxidation exhaust can enable increased quantities of H2 which is an excellent reductant for lean NOx trap regeneration. It is critical to maintain clean and efficient partial oxidation and reforming processes to keep the lean NOx trap functioning properly and to reduce extra fuel consumption from the regeneration process. Although most exhaust constituents do not impede partial oxidation and reforming, some exhaust constituents may negatively affect the catalysts and result in loss of catalytic efficiency. Of particular concern are common catalyst poisons sulfur, zinc, and phosphorous. These poisons form in the exhaust through combustion of fuel and oil, and although they are present at low concentrations, they can accumulate to significant levels over the life of an engine system. In the work presented here, the effects of sulfur on the partial oxidation and reforming catalytic processes were studied to determine any durability limitations on the production of reductants for lean NOx trap catalyst regeneration.

Parks, II, James E [ORNL; Ponnusamy, Senthil [ORNL

2006-01-01T23:59:59.000Z

232

Environmental control technology for atmospheric carbon dioxide  

Science Conference Proceedings (OSTI)

The impact of fossil fuel use in the United States on worldwide CO/sub 2/ emissions and the impact of increased coal utilization on CO/sub 2/ emission rates are assessed. The aspects of CO/sub 2/ control are discussed as well as the available CO/sub 2/ control points (CO/sub 2/ removal sites). Two control scenarios are evaluated, one based on the absorption of CO/sub 2/ contained in power plant flue gas by seawater; the other, based on absorption of CO/sub 2/ by MEA (Mono Ethanol Amine). Captured CO/sub 2/ is injected into the deep ocean in both cases. The analyses indicate that capture and disposal by seawater is energetically not feasible, whereas capture and disposal using MEA is a possibility. However, the economic penalities of CO/sub 2/ control are significant. The use of non-fossil energy sources, such as hydroelectric, nuclear or solar energy is considered as an alternative for limiting and controlling CO/sub 2/ emissions resulting from fossil energy usage.

Steinberg, M.; Albanese, A.S.

1980-01-01T23:59:59.000Z

233

NOx Sensor Development  

SciTech Connect

The objectives of this report are: (1) Develop an inexpensive, rapid-response, high-sensitivity and selective electrochemical sensor for oxides of nitrogen (NO{sub x}) for compression-ignition, direct-injection (CIDI) exhaust gas monitoring; (2) Explore and characterize novel, effective sensing methodologies based on impedance measurements; (3) Explore designs and manufacturing methods that could be compatible with mass fabrication; and (4) Collaborate with industry in order to (ultimately) transfer the technology to a supplier for commercialization.

Woo, L Y; Glass, R S

2009-10-27T23:59:59.000Z

234

NOVEL TECHNOLOGIES FOR GASEOUS CONTAMINANTS CONTROL  

Science Conference Proceedings (OSTI)

Overall objective of this project was to develop a technology platform for cleaning/conditioning the syngas from an integrated gasification combined cycle (IGCC) system at elevated temperatures (500-1,000 F) and gasifier pressures to meet the tolerance limits for contaminants, including H{sub 2}S, COS, NH{sub 3}, HCl, Hg, and As. This technology development effort involved progressive development and testing of sorbent/catalytic materials and associated processes through laboratory, bench, pilot, and demonstration testing phases, coupled with a comprehensive systems analysis at various stages of development. The development of the regenerable RTI-3 desulfurization sorbent - a highly attrition-resistant, supported ZnO-based material - was the key discovery in this project. RTI-3's high attrition resistance, coupled with its high reactivity, effectively allowed its application in a high-velocity transport reactor system. Production of the RTI-3 sorbent was successfully scaled up to an 8,000-lb batch by Sued-Chemie. In October 2005, RTI obtained U.S Patent 6,951,635 to protect the RTI-3 sorbent technology and won the 2004 R&D 100 Award for development of this material. The RTI-3 sorbent formed the basis for the development of the High-Temperature Desulfurization System (HTDS), a dual-loop transport reactor system for removing the reduced sulfur species from syngas. An 83-foot-tall, pilot HTDS unit was constructed and commissioned first at ChevronTexaco's gasification site and later at Eastman's gasification plant. At Eastman, the HTDS technology was successfully operated with coal-derived syngas for a total of 3,017 hrs over a 12-month period and consistently reduced the sulfur level to <10 ppmv. The sorbent attrition rate averaged {approx}31 lb/MM lb of circulation. To complement the HTDS technology, which extracts the sulfur from syngas as SO{sub 2}, RTI developed the Direct Sulfur Recovery Process (DSRP). The DSRP, operating at high pressure and high temperature, uses a small slipstream of syngas to catalytically reduce the SO{sub 2} produced in the warm syngas desulfurization process to elemental sulfur. To demonstrate this process at Eastman, RTI constructed and commissioned a skid-mounted pilot DSRP unit. During its 117-h operation, the DSRP system achieved 90% to 98% removal of the inlet sulfur. The DSRP catalyst proved very robust, demonstrating consistent reaction rates in multiple experiments over a 3-year period. Sorbent materials for removing trace NH{sub 3}, Hg, and As impurities from syngas at high temperature and high pressure were developed and tested with real syngas. A Li{sub 4}SiO{sub 4} sorbent for removal of CO{sub 2} from syngas at high temperature was also developed and tested. The Li{sub 4}SiO{sub 4} material demonstrates excellent CO{sub 2} removal, but its regeneration was found to be technically challenging. Additionally, reverse-selective polymer membrane materials were investigated for the bulk removal of CO{sub 2} and H{sub 2}S from syngas. These materials exhibited adequate separation at ambient conditions for these acid gases. Field testing of these membrane modules with real syngas demonstrated potential use for acid-gas separation from syngas. The HTDS/DSRP technologies are estimated to have a significant economic advantage over conventional gas cleanup technologies such as Selexol{trademark} and Rectisol. From a number of system studies, use of HTDS/DSRP is expected to give a 2-3 percentage point increase in the overall IGCC thermal efficiency and a significant reduction in capital cost. Thus, there is significant economic incentive for adaptation of these warm gas cleanup technologies due to significantly increased thermal efficiency and reduction in capital and operating costs. RTI and Eastman are currently in discussions with a number of companies to commercialize this technology.

B. S. Turk; R. P. Gupta; S. Gangwal; L. G. Toy; J. R. Albritton; G. Henningsen; P. Presler-Jur; J. Trembly

2008-04-03T23:59:59.000Z

235

Nexus of technologies : international safeguards, physical protection and arms control.  

Science Conference Proceedings (OSTI)

New technologies have been, and are continuing to be, developed for Safeguards, Arms Control, and Physical Protection. Application spaces and technical requirements are evolving - Overlaps are developing. Lessons learned from IAEA's extensive experience could benefit other communities. Technologies developed for other applications may benefit Safeguards - Inherent cost benefits and improvements in procurement security processes.

Jordan, Sabina Erteza; Blair, Dianna Sue; Smartt, Heidi Anne

2010-09-01T23:59:59.000Z

236

Multi-Pollutant Control Technology and Cost Sensitivity Analysis  

Science Conference Proceedings (OSTI)

Current emissions control systems used by the U.S. generating fleet typically reduce emission rates of only one pollutant. This requires installation in series of various combinations of emission control systems to remove multiple pollutants. Technologies for simultaneous removal of multiple pollutants are now moving toward commercialization. These integrated systems have the potential to require less capital investment and to offer lower operating costs than traditional technologies. This report investi...

2008-12-22T23:59:59.000Z

237

Export Control Regulations Michigan Technological University  

E-Print Network (OSTI)

Regulations (EAR) Department of Commerce, Bureau of Industry and Security (BIS) Commercial or dual-use items Control (OFAC) Department of Justice Department of Energy Nuclear Regulatory Commission Department of Homeland Security Boarder and Transportation Security U.S. Customs #12;15 CFR 730.5; 22 CFR 120.17 Export

238

NETL: Mercury Emissions Control Technologies - Advanced Utility  

NLE Websites -- All DOE Office Websites (Extended Search)

Advanced Utility Mercury-Sorbent Field Testing Program Advanced Utility Mercury-Sorbent Field Testing Program Sorbent Technologies Corporation, will test an advanced halgenated activated carbon to determine the mercury removal performance and relative costs of sorbent injection for advanced sorbent materials in large-scale field trials of a variety of combinations of coal-type and utility plant-configuration. These include one site (Detroit Edison's St. Clair Station) with a cold-side ESP using subbituminous coal, or blend of subbituminous and bituminous coal, and one site (Duke Energy's Buck Plant) with a hot-side ESP which burns a bituminous coal. Related Papers and Publications: Semi-Annual Technical Progress Report for the period April 1 - October 31, 2004 [PDF-2275KB] Semi-Annual Technical Progress Report for the period of October 2003 - March 2004 [PDF-1108KB]

239

Rotating preventers; Technology for better well control  

Science Conference Proceedings (OSTI)

This paper reports that recent changes in the oil and gas industry and ongoing developments in horizontal and underbalanced drilling necessitated development of a better rotating head. A new device called the rotating blowout preventer (RBOP) was developed by Seal-Tech. It is designed to replace the conventional rotating control head on top of BOP stacks and allows drilling operations to continue even on live (underbalanced) wells. Its low wear characteristics and high working pressure (1,500 psi) allow drilling rig crews to drill safely in slightly underbalanced conditions or handle severe well control problems during the time required to actuate other BOPs in the stack. Drilling with a RBOP allows wellbores to be completely closed in tat the drill floor rather than open as with conventional BOPs.

Tangedahl, M.J.; Stone, C.R. (Signa Engineering Corp. (United States))

1992-10-01T23:59:59.000Z

240

NETL: Mercury Emissions Control Technologies - Evaluation of Control  

NLE Websites -- All DOE Office Websites (Extended Search)

Evaluation of Control Strategies to Effectively Meet 70 - 90% Evaluation of Control Strategies to Effectively Meet 70 - 90% Mercury Reduction on an Eastern Bituminous Coal Cyclone Boiler with SCR The overall objective of this project is to assess the potential for significant mercury control, between 50 and 90% above baseline, by sorbent injection for the challenging technical process configuration at Public Service of New Hampshire Company Merrimack Station Unit No. 2. The primary emphasis of this project is to evaluate the performance of mercury sorbent injection, but the effect of co-benefits from SO3 mitigation on mercury control will also be explored. Also in this program the performance capabilities of mercury measurement techniques in challenging flue-gas environment will be assessed and the impact of activated carbon injection on fly ash disposal options will be investigated.

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241

NOVEL TECHNOLOGIES FOR GASEOUS CONTAMINANTS CONTROL  

Science Conference Proceedings (OSTI)

The overall objective of this project is to develop technologies for cleaning/conditioning the syngas from an integrated gasification combined cycle (IGCC) system to meet the tolerance limits for contaminants such as H{sub 2}S, COS, NH{sub 3}, HCN, HCl, and alkali for fuel cell and chemical production applications. RTI's approach is to develop a modular system that (1) removes reduced sulfur species to sub-ppm levels using a hybrid process consisting of a polymer membrane and a regenerable ZnO-coated monolith or a mixed metal oxide sorbent; (2) removes hydrogen chloride vapors to sub-ppm levels using an inexpensive, high-surface area material; and (3) removes NH{sub 3} with acidic adsorbents. RTI is working with MEDAL, Inc., and North Carolina State University (NCSU) to develop polymer membrane technology for bulk removal of H{sub 2}S from syngas. These membranes are being engineered to remove the acid gas components (H{sub 2}S, CO{sub 2}, NH{sub 3}, and H{sub 2}O) from syngas by focusing on the ''solubility selectivity'' of the novel polymer compositions. The desirable components of the syngas (H{sub 2} and CO) are maintained at high-pressure conditions as a non-permeate stream while the impurities are transported across the membrane to the low pressure side. RTI tested commercially available and novel materials from MEDAL using a high-temperature, high-pressure (HTHP) permeation apparatus. H{sub 2}S/H{sub 2} selectivities >30 were achieved, although there was a strong negative dependence with temperature. MEDAL believes that all the polymer compositions tested so far can be prepared as hollow fiber membrane modules using the existing manufacturing technology. For fuel cell and chemical applications, additional sulfur removal (beyond that achievable with the membranes) is required. To overcome limitations of conventional ZnO pellets, RTI is testing a monolith with a thin coating of high surface area zinc-oxide based materials. Alternatively, a regenerable sorbent developed by DOE/NETL (RVS-1) is being evaluated for this application. A multi-cycle test of 2-in. (5-cm) diameter monolith samples demonstrated that HCl vapors is being accomplished by low-cost materials that combine the known effectiveness of sodium carbonate as an active matrix used with enhanced surface area supports for greater reactivity and capacity at the required operating temperatures. RTI is working with SRI International on this task. Sorbents prepared using diatomaceous earth and sepiolite, impregnated with sodium carbonate achieved steady-state HCl level <100 ppb (target is 10 ppb). Research is continuing to optimize the impregnation and calcination procedures to provide an optimum pore size distribution and other properties. RTI and SRI International have established the feasibility of a process to selectively chemisorb NH3 from syngas on high surface area molecular sieve adsorbents at high temperatures by conducting a series of temperature-programmed reactions at 225 C (437 F). Significant levels of NH{sub 3} were adsorbed on highly acidic adsorbents; the adsorbed NH{sub 3} was subsequently recovered by heating the adsorbent and the regenerated adsorbent was reused. A comprehensive technical and economic evaluation of this modular gas cleaning process was conducted by Nexant to compare capital and operating cost with existing amine based processes. Nexant estimated a total installed cost of $42 million for the RTI process for a 500 MWe IGCC plant based on its current state of development. By comparison, Nexant estimated the installed cost for an equivalent sized plant based on the Rectisol process (which would achieve the same sulfur removal specification) to be $75 million. Thus the RTI process is economically competitive with a state-of-the-art process for syngas cleanup.

B.S. Turk; T. Merkel; A. Lopez-Ortiz; R.P. Gupta; J.W. Portzer; G.N. Krishnan; B.D. Freeman; G.K. Fleming

2001-09-30T23:59:59.000Z

242

NOVEL TECHNOLOGIES FOR GASEOUS CONTAMINANTS CONTROL  

SciTech Connect

The overall objective of this project is to develop technologies for cleaning/conditioning the syngas from an integrated gasification combined cycle (IGCC) system to meet the tolerance limits for contaminants such as H{sub 2}S, COS, NH{sub 3}, HCN, HCl, and alkali for fuel cell and chemical production applications. RTI's approach is to develop a modular system that (1) removes reduced sulfur species to sub-ppm levels using a hybrid process consisting of a polymer membrane and a regenerable ZnO-coated monolith or a mixed metal oxide sorbent; (2) removes hydrogen chloride vapors to sub-ppm levels using an inexpensive, high-surface area material; and (3) removes NH{sub 3} with acidic adsorbents. RTI is working with MEDAL, Inc., and North Carolina State University (NCSU) to develop polymer membrane technology for bulk removal of H{sub 2}S from syngas. These membranes are being engineered to remove the acid gas components (H{sub 2}S, CO{sub 2}, NH{sub 3}, and H{sub 2}O) from syngas by focusing on the ''solubility selectivity'' of the novel polymer compositions. The desirable components of the syngas (H{sub 2} and CO) are maintained at high-pressure conditions as a non-permeate stream while the impurities are transported across the membrane to the low pressure side. RTI tested commercially available and novel materials from MEDAL using a high-temperature, high-pressure (HTHP) permeation apparatus. H{sub 2}S/H{sub 2} selectivities >30 were achieved, although there was a strong negative dependence with temperature. MEDAL believes that all the polymer compositions tested so far can be prepared as hollow fiber membrane modules using the existing manufacturing technology. For fuel cell and chemical applications, additional sulfur removal (beyond that achievable with the membranes) is required. To overcome limitations of conventional ZnO pellets, RTI is testing a monolith with a thin coating of high surface area zinc-oxide based materials. Alternatively, a regenerable sorbent developed by DOE/NETL (RVS-1) is being evaluated for this application. A multi-cycle test of 2-in. (5-cm) diameter monolith samples demonstrated that <0.5 ppm sulfur can be achieved. Removal of HCl vapors is being accomplished by low-cost materials that combine the known effectiveness of sodium carbonate as an active matrix used with enhanced surface area supports for greater reactivity and capacity at the required operating temperatures. RTI is working with SRI International on this task. Sorbents prepared using diatomaceous earth and sepiolite, impregnated with sodium carbonate achieved steady-state HCl level <100 ppb (target is 10 ppb). Research is continuing to optimize the impregnation and calcination procedures to provide an optimum pore size distribution and other properties. RTI and SRI International have established the feasibility of a process to selectively chemisorb NH3 from syngas on high surface area molecular sieve adsorbents at high temperatures by conducting a series of temperature-programmed reactions at 225 C (437 F). Significant levels of NH{sub 3} were adsorbed on highly acidic adsorbents; the adsorbed NH{sub 3} was subsequently recovered by heating the adsorbent and the regenerated adsorbent was reused. A comprehensive technical and economic evaluation of this modular gas cleaning process was conducted by Nexant to compare capital and operating cost with existing amine based processes. Nexant estimated a total installed cost of $42 million for the RTI process for a 500 MWe IGCC plant based on its current state of development. By comparison, Nexant estimated the installed cost for an equivalent sized plant based on the Rectisol process (which would achieve the same sulfur removal specification) to be $75 million. Thus the RTI process is economically competitive with a state-of-the-art process for syngas cleanup.

B.S. Turk; T. Merkel; A. Lopez-Ortiz; R.P. Gupta; J.W. Portzer; G.N. Krishnan; B.D. Freeman; G.K. Fleming

2001-09-30T23:59:59.000Z

243

NOx Sensor Development  

SciTech Connect

NO{sub x} compounds, specifically NO and NO{sub 2}, are pollutants and potent greenhouse gases. Compact and inexpensive NO{sub x} sensors are necessary in the next generation of diesel (CIDI) automobiles to meet government emission requirements and enable the more rapid introduction of more efficient, higher fuel economy CIDI vehicles. Because the need for a NO{sub x} sensor is recent and the performance requirements are extremely challenging, most are still in the development phase. Currently, there is only one type of NO{sub x} sensor that is sold commercially, and it seems unlikely to meet more stringent future emission requirements. Automotive exhaust sensor development has focused on solid-state electrochemical technology, which has proven to be robust for in-situ operation in harsh, high-temperature environments (e.g., the oxygen stoichiometric sensor). Solid-state sensors typically rely on yttria-stabilized zirconia (YSZ) as the oxygen-ion conducting electrolyte and then target different types of metal or metal-oxide electrodes to optimize the response. Electrochemical sensors can be operated in different modes, including amperometric (a current is measured) and potentiometric (a voltage is measured), both of which employ direct current (dc) measurements. Amperometric operation is costly due to the electronics necessary to measure the small sensor signal (nanoampere current at ppm NO{sub x} levels), and cannot be easily improved to meet the future technical performance requirements. Potentiometric operation has not demonstrated enough promise in meeting long-term stability requirements, where the voltage signal drift is thought to be due to aging effects associated with electrically driven changes, both morphological and compositional, in the sensor. Our approach involves impedancemetric operation, which uses alternating current (ac) measurements at a specified frequency. The approach is described in detail in previous reports and several publications. Briefly, impedancemetric operation has shown the potential to overcome the drawbacks of other approaches, including higher sensitivity towards NO{sub x}, better long-term stability, potential for subtracting out background interferences, total NO{sub x} measurement, and lower cost materials and operation. Past LLNL research and development efforts have focused on characterizing different sensor materials and understanding complex sensing mechanisms. Continued effort has led to improved prototypes with better performance, including increased sensitivity (to less than 5 ppm) and long-term stability, with more appropriate designs for mass fabrication, including incorporation of an alumina substrate with an imbedded heater. Efforts in the last year to further improve sensor robustness have led to successful engine dynamometer testing with prototypes mounted directly in the engine manifold. Previous attempts had required exhaust gases to be routed into a separate furnace for testing due to mechanical failure of the sensor from engine vibrations. A more extensive cross-sensitivity study was also undertaken this last year to examine major noise factors including fluctuations in water, oxygen, and temperature. The quantitative data were then used to develop a strategy using numerical algorithms to improve sensor accuracy. The ultimate goal is the transfer of this technology to a supplier for commercialization. Due to the recent economic downturn, suppliers are demanding more comprehensive data and increased performance analysis before committing their resources to take the technology to market. Therefore, our NO{sub x} sensor work requires a level of technology development more thorough and extensive than ever before. The objectives are: (1) Develop an inexpensive, rapid-response, high-sensitivity and selective electrochemical sensor for oxides of nitrogen (NO{sub x}) for compression-ignition, direct-injection (CIDI) exhaust gas monitoring; (2) Explore and characterize novel, effective sensing methodologies based on impedance measurements and designs and manufacturing metho

Woo, L Y; Glass, R S

2010-11-01T23:59:59.000Z

244

Mercury Control Technologies for Electric Utilities Burning Lignite Coal  

NLE Websites -- All DOE Office Websites (Extended Search)

Mercury control technologies for Mercury control technologies for electric utilities Burning lignite coal Background In partnership with a number of key stakeholders, the U.S. Department of Energy's Office of Fossil Energy (DOE/FE), through its National Energy Technology Laboratory (NETL), has been carrying out a comprehensive research program since the mid-1990s focused on the development of advanced, cost-effective mercury (Hg) control technologies for coal-fired power plants. Mercury is a poisonous metal found in coal, which can be harmful and even toxic when absorbed from the environment and concentrated in animal tissues. Mercury is present as an unwanted by-product of combustion in power plant flue gases, and is found in varying percentages in three basic chemical forms(known as speciation): particulate-bound mercury, oxidized

245

NETL: Control Technology: ElectroCore Separator  

NLE Websites -- All DOE Office Websites (Extended Search)

ElectroCore Separator ElectroCore Separator LSR Technologies and its subcontractors designed and installed a 8,500 m3/hr (5,000 acfm) Advanced ElectroCore system and a dry sulfur scrubber to test it using an exhaust gas slipstream at Alabama Power Company's Gaston Steam Plant. Shakedown is scheduled for August 15, 2001. The exhaust gas will be from Unit #4 of a 270 MWe sub-critical, pulverized coal boiler burning a low-sulfur bituminous coal. The Advanced ElectroCore system will consist of a conventional upstream ESP, a dry SO2 scrubber, a particle precharger and an Advanced ElectroCore separator. Particle concentrations and size distributions will be measured at the ESP inlet, at the dry scrubber outlet and at the ElectroCore outlet. The concentration of 12 common HAPs will be measured at these locations as well. For purposes of project organization and monitoring, the work will be divided into nine (9) tasks described below.

246

Soft-Sensor Modeling on NOx Emission of Power Station Boilers Based on Least Squares Support Vector Machines  

Science Conference Proceedings (OSTI)

The online monitoring for NOx emission of coal-fired boilers in power plants is more difficult to achieve. The soft-sensor technology of artificial neural network (ANN) method that was commonly used has not strong generalization ability, but support ... Keywords: NOx emission, support vector machines, soft sensor, modeling, power station boilers

Feng Lei-hua; Gui Wei-hua; Yang Feng

2009-10-01T23:59:59.000Z

247

Modeling The NOx Emissions In A Low NOx Burner While Fired With Pulverized Coal And Dairy Biomass Blends  

E-Print Network (OSTI)

New regulations like the Clean Air Interstate Rule (CAIR) will pose greater challenges for Coal fired power plants with regards to pollution reduction. These new regulations plan to impose stricter limits on NOX reduction. The current regulations by themselves already require cleanup technology; newer regulations will require development of new and economical technologies. Using a blend of traditional fuels & biomass is a promising technology to reduce NOX emissions. Experiments conducted previously at the Coal and Biomass energy lab at Texas A&M reported that dairy biomass can be an effective Reburn fuel with NOX reduction of up to 95%; however little work has been done to model such a process with Feedlot Biomass as a blend with the main burner fuel. The present work concerns with development of a zero dimensional for a low NOx burner (LNB) model in order to predict NOX emissions while firing a blend of Coal and dairy biomass. Two models were developed. Model I assumes that the main burner fuel is completely oxidized to CO,CO2,H20 and fuel bound nitrogen is released as HCN, NH3, N2; these partially burnt product mixes with tertiary air, undergoes chemical reactions specified by kinetics and burns to complete combustion. Model II assumes that the main burner solid fuel along with primary and secondary air mixes gradually with recirculated gases, burn partially and the products from the main burner include partially burnt solid particles and fuel bound nitrogen partially converted to N2, HCN and NH3. These products mix gradually with tertiary air, undergo further oxidation-reduction reactions in order to complete the combustion. The results are based on model I. Results from the model were compared with experimental findings to validate it. Results from the model recommend the following conditions for optimal reduction of NOx: Equivalence Ratio should be above 0.95; mixing time should be below 100ms. Based on Model I, results indicate that increasing percentage of dairy biomass in the blend increases the NOx formation due to the assumption that fuel N compounds ( HCN, NH3) do not undergo oxidation in the main burner zone. Thus it is suggested that model II must be adopted in the future work.

Uggini, Hari

2012-05-01T23:59:59.000Z

248

NETL: Clean Coal Technology Demonstration Program (CCTDP) - Round 3  

NLE Websites -- All DOE Office Websites (Extended Search)

Evaluation of Gas Reburning and Low-NOx Burners on a Wall-Fired Boiler - Project Brief [PDF-252KB] Evaluation of Gas Reburning and Low-NOx Burners on a Wall-Fired Boiler - Project Brief [PDF-252KB] Energy and Environmental Research Corp., Denver, CO PROGRAM PUBLICATIONS Final Reports Evaluation of Gas Reburning and Low NOx Burners on a Wall-Fired Boiler: Performance and Economics Report, Gas Reburning-Low NOx Burner System, Cherokee Station Unit No. 3, Final Report [PDF-17.2MB] (July 1998) CCT Reports: Project Performance Summaries, Post-Project Assessments, & Topical Reports Evaluation of Gas Reburning and Low-NOx Burners on a Wall-Fired Boiler: A DOE Assessment [PDF-309KB] (Feb 2001) Reburning Technologies for the Control of Nitrogen Oxides Emissions from Coal-Fired Boilers, Topical Report No.14 [PDF-1.2MB] ((May 1999) Reduction of NOx and SO2 Using Gas Reburning, Sorbent Injection, and Integrated Technologies, Topical Report No. 3 [PDF-1MB] ((Sept 1993)

249

INL Control System Situational Awareness Technology Annual Report 2012  

Science Conference Proceedings (OSTI)

The overall goal of this project is to develop an interoperable set of tools to provide a comprehensive, consistent implementation of cyber security and overall situational awareness of control and sensor network implementations. The operation and interoperability of these tools will fill voids in current technological offerings and address issues that remain an impediment to the security of control systems. This report provides an FY 2012 update on the Sophia, Mesh Mapper, Intelligent Cyber Sensor, and Data Fusion projects with respect to the year-two tasks and annual reporting requirements of the INL Control System Situational Awareness Technology report (July 2010).

Gordon Rueff; Bryce Wheeler; Todd Vollmer; Tim McJunkin; Robert Erbes

2012-10-01T23:59:59.000Z

250

A Review of DOE/NETLs Advanced NOx Control Technology R&D Program for Coal-Fired Power Plants. National Energy Technology Laboratory  

E-Print Network (OSTI)

The environmental performance of the United States fleet of coal-fired boilers has steadily improved since passage of the 1990 Clean Air Act Amendments (CAAA). Missions of sulfur dioxide (SO

Bruce W. Lani; Thomas J. Feeley; James Murphy; Lindsay Green

2005-01-01T23:59:59.000Z

251

NETL: Mercury Emissions Control Technologies - Mercury Control For Plants  

NLE Websites -- All DOE Office Websites (Extended Search)

Mercury Control For Plants Firing Texas Lignite and Equipped with ESP-wet FGD Mercury Control For Plants Firing Texas Lignite and Equipped with ESP-wet FGD URS Group, Inc., in collaboration with EPRI, Apogee Scientific, AEP, Texas Genco, and TXU Power, ADA-ES, will evaluate sorbent injection for mercury control in an 85/15 blend Texas lignite/PRB derived flue gas, upstream of a cold-side ESP – wet FGD combination. Full-scale sorbent injection tests conducted with various sorbents and combinations of fuel and plant air pollution control devices (APCD) have provided a good understanding of variables that affect sorbent performance. However, many uncertainties exist regarding long-term performance and data gaps remain for specific plant configurations. For example, sorbent injection has not been demonstrated at full-scale for plants firing Texas lignite, which represent approximately 10% of the annual U.S. power plant mercury emissions. The low and variable chloride content of Texas lignite may pose a challenge to achieving high levels of mercury removal with sorbent injection. Furthermore, activated carbon injection may render the fly ash unsuitable for sale, posing an economic liability to Texas lignite utilities. Alternatives to standard activated carbon, such as non-carbon sorbents and alternate injection locations (Toxecon II), have not been fully explored. Toxecon II involves sorbent injection in the middle field(s) of an ESP, thus preserving the integrity of the fly ash in the first fields.

252

PARTICULATE CHARACTERIZATION AND ULTRA LOW-NOx BURNER FOR THE CONTROL OF NO{sub x} AND PM{sub 2.5} FOR COAL FIRED BOILERS  

SciTech Connect

In response to the serious challenge facing coal-fired electric utilities with regards to curbing their NO{sub x} and fine particulate emissions, Babcock and Wilcox and McDermott Technology, Inc. conducted a project entitled, ''Particulate Characterization and Ultra Low-NO{sub x} Burner for the Control of NO{sub x} and PM{sub 2.5} for Coal Fired Boilers.'' The project included pilot-scale demonstration and characterization of technologies for removal of NO{sub x} and primary PM{sub 2.5} emissions. Burner development and PM{sub 2.5} characterization efforts were based on utilizing innovative concepts in combination with sound scientific and fundamental engineering principles and a state-of-the-art test facility. Approximately 1540 metric tonnes (1700 tons) of high-volatile Ohio bituminous coal were fired. Particulate sampling for PM{sub 2.5} emissions characterization was conducted in conjunction with burner testing. Based on modeling recommendations, a prototype ultra low-NO{sub x} burner was fabricated and tested at 100 million Btu/hr in the Babcock and Wilcox Clean Environment Development Facility. Firing the unstaged burner with a high-volatile bituminous Pittsburgh 8 coal at 100 million Btu/hr and 17% excess air achieved a NO{sub x} goal of 0.20 lb NO{sub 2}/million Btu with a fly ash loss on ignition (LOI) of 3.19% and burner pressure drop of 4.7 in H{sub 2}O for staged combustion. With the burner stoichiometry set at 0.88 and the overall combustion stoichiometry at 1.17, average NO{sub x} and LOI values were 0.14 lb NO{sub 2}/million Btu and 4.64% respectively. The burner was also tested with a high-volatile Mahoning 7 coal. Based on the results of this work, commercial demonstration is being pursued. Size classified fly ash samples representative of commercial low-NO{sub x} and ultra low-NO{sub x} combustion of Pittsburgh 8 coal were collected at the inlet and outlet of an ESP. The mass of size classified fly ash at the ESP outlet was sufficient to evaluate the particle size distribution, but was of insufficient size to permit reliable chemical analysis. The size classified fly ash from the inlet of the ESP was used for detailed chemical analyses. Chemical analyses of the fly ash samples from the ESP outlet using a high volume sampler were performed for comparison to the size classified results at the inlet. For all test conditions the particulate removal efficiency of the ESP exceeded 99.3% and emissions were less than the NSPS limits of {approx}48 mg/dscm. With constant combustion conditions, the removal efficiency of the ESP increased as the ESP voltage and Specific Collection Area (SCA) increased. The associated decrease in particle emissions occurred in size fractions both larger and smaller than 2.5 microns. For constant ESP voltage and SCA, the removal efficiency for the ultra low-NO{sub x} combustion ash (99.4-99.6%) was only slightly less than for the low-NO{sub x} combustion ash (99.7%). The decrease in removal efficiency was accompanied by a decrease in ESP current. The emission of PM{sub 2.5} from the ESP did not change significantly as a result of the change in combustion conditions. Most of the increase in emissions was in the size fraction greater than 2.5 microns, indicating particle re-entrainment. These results may be specific to the coal tested in this program. In general, the concentration of inorganic elements and trace species in the fly ash at the ESP inlet was dependent on the particle size fraction. The smallest particles tended to have higher concentrations of inorganic elements/trace species than larger particles. The concentration of most elements by particle size range was independent of combustion condition and the concentration of soluble ions in the fly ash showed little change with combustion condition when evaluated on a carbon free basis.

Ralph Bailey; Hamid Sarv; Jim Warchol; Debi Yurchison

2001-09-30T23:59:59.000Z

253

Establishment of an Environmental Control Technology Laboratory with a Circulating Fluidized-Bed Combustion System  

DOE Green Energy (OSTI)

This report is to present the progress made on the project entitled ''Establishment of an Environmental Control Technology Laboratory (ECTL) with a Circulating Fluidized-Bed Combustion (CFBC) System'' during the period January 1, 2007 through March 31, 2007. The effort in this quarter has concentrated on installing the CFBC Facility and for conducting cold fluidization operations tests in the CFBC facility. The assembly of the ash recirculation pipe duct from the cyclones back to the bed area of the combustor, including the upper and lower loop seals was completed. The electric bed pre-heater was installed to heat the fluidizing air as it enters the wind box. The induced draft fan along with its machine base and power supply was received and installed. The flue gas duct from secondary cyclone outlet to induced draft fan inlet was received and installed, as well as the induced fan flue gas discharge duct. Pressure testing from the forced draft fan to the outlet of the induced fan was completed. In related research a pilot-scale halogen addition test was conducted in the empty slipstream reactor (without (Selective Catalytic Reduction) SCR catalyst loading) and the SCR slipstream reactor with two commercial SCR catalysts. The greatest benefits of conducting slipstream tests can be flexible control and isolation of specific factors. This facility is currently used in full-scale utility and will be combined into 0.6MW CFBC in the future. This work attempts to first investigate performance of the SCR catalyst in the flue gas atmosphere when burning Powder River Basin (PRB), including the impact of PRB coal flue gas composition on the reduction of nitrogen oxides (NOx) and the oxidation of elemental mercury (Hg(0)) under SCR conditions. Secondly, the impacts of hydrogen halogens (Hydrogen fluoride (HF), Hydrogen chloride (HCl), Hydrogen Bromide (HBr) and Hydrogen Iodine (HI)) on Hg(0) oxidation and their mechanisms can be explored.

Wei-Ping Pan; Yan Cao; John Smith

2007-03-31T23:59:59.000Z

254

Vehicle Technologies Office: Emission Control R&D  

NLE Websites -- All DOE Office Websites (Extended Search)

Emission Control R&D Emission Control R&D The Vehicle Technologies Office (VTO) supports research and development of aftertreatment technologies to control advanced combustion engine exhaust emissions. All engines that enter the vehicle market must comply with the Environmental Protection Agency's emissions regulations. Harmful pollutants in these emissions include: Carbon monoxide Nitrogen oxides Unburned hydrocarbons Volatile organic compounds (VOCs) Particulate matter The energy required for emission control often reduces vehicle fuel economy and increases vehicle cost. VTO's Emission Control R&D focuses on developing efficient, durable, low-cost emission control systems that complement new combustion strategies while minimizing efficiency losses. VTO often leverages the national laboratories' unique capabilities and facilities to conduct this research.

255

NETL: Mercury Emissions Control Technologies - Low-Cost Options for  

NLE Websites -- All DOE Office Websites (Extended Search)

Low-Cost Options for Moderate Levels of Mercury Control Low-Cost Options for Moderate Levels of Mercury Control ADA- Environmental Solutions will test two new technologies for mercury control. The TOXECON II(tm) technology injects activated carbon directly into the downstream collecting fields of an electrostatic precipitator. The benefit of this technology is that the majority of the fly ash is collected in the upstream collecting fields which results in only a small portion of carbon-contaminated ash. Additionally, the TOXECON II(tm) technology requires minimal capital investment as only minor retrofits to the electrostatic precipitator are needed. The second technology is injection of novel sorbents for mercury removal on units with hot-side electrostatic precipitators (ESPs). Mercury removal from hot-side electrostatic precipitators is difficult as their high operating temperature range keeps the mercury in the vapor phase and prevents the mercury from adsorbing onto sorbents. The TOXECON II(tm) technology will be tested at Entergy's Independence Station which burns PRB coal. The novel sorbents for hot-side ESPs technology will be tested at MidAmerican's Council Bluffs Energy Center and MidAmerican's Louisa Station, both of which burn PRB coal. Additional project partners include EPRI, MidAmerican, Entergy, Alliant, ATCO Power, DTE Energy, Oglethorpe Power, Norit Americas Inc., Xcel Energy, Southern Company, Arch Coal, and EPCOR.

256

NETL: Mercury Emissions Control Technologies - Testing of Mercury Control  

NLE Websites -- All DOE Office Websites (Extended Search)

Testing of Mercury Control with Calcium-Based Sorbents and Oxidizing Agents Testing of Mercury Control with Calcium-Based Sorbents and Oxidizing Agents Southern Research Institute, Birmingham, Alabama Subcontractor- ARCADIS Geraghty & Miller The overall goal of this project is to test the effectiveness of calcium-based sorbents and oxidizing agents for controlling mercury emissions from coal-fired power plant boilers. ARCADIS Geraghty & Miller, with EPA support, has developed calcium-based sorbents to remove SO2 and mercury simultaneously. The sorbents consist of hydrated lime (Ca(OH)2) and an added oxidant and a silica-modified calcium (CaSiO3) with an added oxidant. The mercury capacity in ug Hg/g sorbent for the two sorbents is 20 and 110-150, respectively, verses a mercury capacity for the current standard sorbent, activated carbon, of 70-100. The advantages of a lime based sorbent verses carbon is lower cost, simultaneous removal of sulfur, and allowance of ash to be utilized for a cement additive.

257

Technology for CO{sub 2} emission monitoring and control  

DOE Green Energy (OSTI)

The authors examined three specific areas relative to CO{sub 2} emissions and controls: (1) the effect of deregulation of the utility industry on emissions, (2) the role of advanced power systems in reducing emissions, and (3) developing CO{sub 2} mitigation technologies. In this work the Energy Technologies program office at Los Alamos attempted to initiate an integrated approach that includes a range of tasks involving both point and distributed CO{sub 2} control. The authors have examined evolving mitigation (separation and sequestration) technologies for CO{sub 2} disposal. The separation of hydrogen gas from high-temperature CO{sub 2}-containing streams is a critical component of carbon dioxide mitigation technology, and cost-effective point sequestration will require separation of CO{sub 2} from H{sub 2}. They investigated four types of separation techniques: two high-temperature membrane technologies, an intermediate-temperature membrane technology, and a separation technology based on the formation of CO{sub 2} hydrate compounds through reaction of CO{sub 2} with water at near freezing conditions. At Los Alamos, sequestration technologies are being developed along three principal areas: mineral sequestration of CO{sub 2}, the enhancement of natural sinks using biotechnology methods, and the conversion of CO{sub 2} to methanol using high-temperature photolysis.

Joyce, E.L. Jr.; Unkefer, P.J.; Pendergrass, J.H.; Parkinson, W.J.; Loose, V.W.; Brainard, J.R.

1998-12-31T23:59:59.000Z

258

NOx Reduction Study at New York Power Authority's Charles Poletti Station  

Science Conference Proceedings (OSTI)

This engineering study assessed the feasibility and economics of obtaining significant NOx reduction levels at New York Power Authoritys Charles Poletti Station through one or more of a variety of approaches. Specific NOx reduction technologies included in the assessment were: 30 Unit De-Rate Induced Flue Gas Recirculation (IFGR) IFGR +30 De-Rate Selective Non-Catalytic Reduction (SNCR) IFGR +SNCR IFGR +SNCR +30 De-Rate Selective Catalytic Reduction (SCR) A number of windbox re-powering options, ...

2006-08-01T23:59:59.000Z

259

NETL: Mercury Emissions Control Technologies - Multi-Pollutant Control  

NLE Websites -- All DOE Office Websites (Extended Search)

Multi-Pollutant Control Using Membrane-Based Up-Flow Wet Precipitation Multi-Pollutant Control Using Membrane-Based Up-Flow Wet Precipitation The primary objective of this work is to compare the performance of metallic collecting surfaces to the performance of membrane collecting surfaces in a wet electrostatic precipitator (ESP), in terms of their efficiency in removing fine particulates, acid aerosols, and mercury from an actual power plant flue gas stream. The relative durability and overall cost-effectiveness of the membrane collectors versus metallic collectors will also be evaluated. Due to the higher specific powers, superior corrosion resistance, and better wetting and cleaning qualities, the membrane-collecting surface is expected to perform better than the metallic surface. The second objective of the project will be to compare the overall fine particulate, acid aerosol, and mercury removal efficiency of the baseline flue gas treatment system on BMP Units 1 and 2 to the efficiencies obtained when the two wet ESP systems (metallic and membrane collectors) are added to the existing treatment system.

260

Integrated powertrain control to meet future CO2 and Euro-6 emissions targets for a diesel hybrid with SCR-deNOx system  

Science Conference Proceedings (OSTI)

A new concept is introduced to optimize the performance of the entire powertrain: Integrated Powertrain Control (IPC). In this concept, the synergy between engine, driveline and aftertreatment system is exploited by integrated energy and emission management. ...

Frank Willems; Darren Foster

2009-06-01T23:59:59.000Z

Note: This page contains sample records for the topic "nox control technologies" from the National Library of EnergyBeta (NLEBeta).
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261

Vehicle Technologies Office: Thermal Control and System Integration  

NLE Websites -- All DOE Office Websites (Extended Search)

Thermal Control and System Integration Thermal Control and System Integration The thermal control and system integration activity focuses on issues such as the integration of motor and power control technologies and the development of advanced thermal control technologies. Thermal control is a critical element to enable power density, cost, and reliability of Power Electronics and Electric Machines (PEEM). Current hybrid electric vehicle systems typically use a dedicated 65°C coolant loop to cool the electronics and electric machines. A primary research focus is to develop cooling technologies that will enable the use of coolant temperatures of up to 105°C. Enabling the higher-temperature coolant would reduce system cost by using a single loop to cool the PEEM, internal combustion engine or fuel cell. Several candidate cooling technologies are being investigated along with the potential to reduce material and component costs through the use of more aggressive cooling. Advanced component modeling, fabrication, and manufacturing techniques are also being investigated.

262

Detection Technologies, Arms control and nonproliferation technologies. Third/fourth quarters 1993  

SciTech Connect

This issue of Arms Control and Nonproliferation Technologies is another in a series of issues about specific means for detecting and identifying proliferation and other suspect activities outside the realm of arms control treaties. All the projects discussed are funded by the Office of Research and Development of the Department of Energy`s Office of Nonproliferation and National Security.

Staehle, G; Stull, S; Talaber, C; Moulthrop, P [eds.

1993-12-31T23:59:59.000Z

263

Advanced Controls Technologies and Strategies Linking Energy Efficiency and  

NLE Websites -- All DOE Office Websites (Extended Search)

Advanced Controls Technologies and Strategies Linking Energy Efficiency and Advanced Controls Technologies and Strategies Linking Energy Efficiency and Demand Response Speaker(s): Sila Kiliccote Date: October 6, 2005 - 12:00pm Location: Bldg. 90 Reliable supply of affordable electricity has been in the spotlight since the blackouts in California, the grid shutdown events in New England and the terrorist threats nationwide. While the array of generation technologies and transmission safety issues have been widely discussed, capacity requirements and demand side management issues have also been revisited. This presentation will concentrate on a preliminary framework to describe how advanced controls can support multiple modes of operations including both energy efficiency and demand response (DR). A general description of DR, its benefits, and nationwide status will be outlined.

264

NETL: Mercury Emissions Control Technologies - Full- Scale Testing of  

NLE Websites -- All DOE Office Websites (Extended Search)

Full-Scale Testing of Enhanced Mercury Control in Wet FGD Full-Scale Testing of Enhanced Mercury Control in Wet FGD The goal of this project is to commercialize methods for the control of mercury in coal-fired electric utility systems equipped with wet flue gas desulfurization (wet FGD). The two specific objectives of this project are 1) ninety percent (90%) total mercury removal and 2) costs below 1/4 to 1/2 of today's commercially available activated carbon mercury removal technologies. Babcock and Wilcox and McDermott Technology, Inc's (B&W/MTI's) will demonstrate their wet scrubbing mercury removal technology (which uses very small amounts of a liquid reagent to achieve increased mercury removal) at two locations burning high-sulfur Ohio bituminous coal: 1) Michigan South Central Power Agency's (MSCPA) 55 MWe Endicott Station located in Litchfield, Michigan and 2) Cinergy's 1300 MWe Zimmer Station located near Cincinnati, Ohio.

265

THERMAL DeNOx: A COMMERCIAL SELECTIVE NONCATALYTIC NOx REDUCTION PROCESS FOR  

E-Print Network (OSTI)

THERMAL DeNOx: A COMMERCIAL SELECTIVE NONCATALYTIC NOx REDUCTION PROCESS FOR WASTE when high NOx reduction is required. To illustrate the cost effectiveness, investment and operating in cinerators. INTRODUCTION THERMAL DeNO", a selective noncatalytic NO" reduction process, was invented just

Columbia University

266

Mitigation of Sulfur Effects on a Lean NOx Trap Catalyst by Sorbate Reapplication  

DOE Green Energy (OSTI)

Lean NOx trap catalysis has demonstrated the ability to reduce NOx emissions from lean natural gas reciprocating engines by >90%. The technology operates in a cyclic fashion where NOx is trapped on the catalyst during lean operation and released and reduced to N2 under rich exhaust conditions; the rich cleansing operation of the cycle is referred to as "regeneration" since the catalyst is reactivated for more NOx trapping. Natural gas combusted over partial oxidation catalysts in the exhaust can be used to obtain the rich exhaust conditions necessary for catalyst regeneration. Thus, the lean NOx trap technology is well suited for lean natural gas engine applications. One potential limitation of the lean NOx trap technology is sulfur poisoning. Sulfur compounds directly bond to the NOx trapping sites of the catalyst and render them ineffective; over time, the sulfur poisoning leads to degradation in overall NOx reduction performance. In order to mitigate the effects of sulfur poisoning, a process has been developed to restore catalyst activity after sulfur poisoning has occurred. The process is an aqueous-based wash process that removes the poisoned sorbate component of the catalyst. A new sorbate component is reapplied after removal of the poisoned sorbate. The process is low cost and does not involve reapplication of precious metal components of the catalyst. Experiments were conducted to investigate the feasibility of the washing process on a lean 8.3-liter natural gas engine on a dynamometer platform. The catalyst was rapidly sulfur poisoned with bottled SO2 gas; then, the catalyst sorbate was washed and reapplied and performance was re-evaluated. Results show that the sorbate reapplication process is effective at restoring lost performance due to sulfur poisoning. Specific details relative to the implementation of the process for large stationary natural gas engines will be discussed.

Parks, II, James E [ORNL

2007-01-01T23:59:59.000Z

267

Advanced Data Processing and Computing Technologies at Control Centers  

Science Conference Proceedings (OSTI)

Control center operation is becoming more complex as new and often-conflicting reliability, economics, and public policy issues emerge. To manage the complexity, control center operators need prompt, comprehensive information about their own systems and neighboring systems. Computer simulations analyze system data and what-if-scenarios to derive succinct information for operators to make more informed decisions. This report reviews the applicability of new technologies and some solution methods for addre...

2011-12-05T23:59:59.000Z

268

Simulator demonstration of the interphase power controller technology  

SciTech Connect

The paper reports on a simulator demonstration of the Interphase Power Controller (IPC) technology. The simulator models developed and the testing methodology are described. The main results confirm the basic attributes of the IPC (robust power flow control characteristic, fault current limitation and decoupling of the interconnected networks) and that the IPC can be built from conventional equipment. Random testing performed on the simulator proved to be useful in assessing the maximum stresses on the equipment.

Sybille, G.; Haj-Maharsi, Y. [Inst. de Recherche d`Hydro-Quebec, Varennes, Quebec (Canada)] [Inst. de Recherche d`Hydro-Quebec, Varennes, Quebec (Canada); Morin, G.; Beauregard, F.; Brochu, J.; Lemay, J.; Pelletier, P. [Centre d`Innovation sur le Transport d`Energie du Quebec, Varennes, Quebec (Canada)] [Centre d`Innovation sur le Transport d`Energie du Quebec, Varennes, Quebec (Canada)

1996-10-01T23:59:59.000Z

269

Adapting Wireless Technology to Lighting Control and Environmental Sensing  

SciTech Connect

The high cost of retrofitting buildings with advanced lighting control systems is a barrier to adoption of this energy-saving technology. Wireless technology, however, offers a solution to mounting installation costs since it requires no additional wiring to implement. To demonstrate the feasibility of such a system, a prototype wirelessly-controlled advanced lighting system was designed and built. The system includes the following components: a wirelessly-controllable analog circuit module (ACM), a wirelessly-controllable electronic dimmable ballast, a T8 3-lamp fixture, an environmental multi-sensor, a current transducer, and control software. The ACM, dimmable ballast, multi-sensor, and current transducer were all integrated with SmartMesh{trademark} wireless mesh networking nodes, called motes, enabling wireless communication, sensor monitoring, and actuator control. Each mote-enabled device has a reliable communication path to the SmartMesh Manager, a single board computer that controls network functions and connects the wireless network to a PC running lighting control software. The ACM is capable of locally driving one or more standard 0-10 Volt electronic dimmable ballasts through relay control and a 0-10 Volt controllable output. The mote-integrated electronic dimmable ballast is designed to drive a standard 3-lamp T8 light fixture. The environmental multi-sensor measures occupancy, light level and temperature. The current transducer is used to measure the power consumed by the fixture. Control software was developed to implement advanced lighting algorithms, including daylight ramping, occupancy control, and demand response. Engineering prototypes of each component were fabricated and tested in a bench-scale system. Based on standard industry practices, a cost analysis was conducted. It is estimated that the installation cost of a wireless advanced lighting control system for a retrofit application is at least 30% lower than a comparable wired system for a typical 16,000 square-foot office building, with a payback period of less than 3 years.

Dana Teasdale; Francis Rubinstein; Dave Watson; Steve Purdy

2005-10-01T23:59:59.000Z

270

Program on Technology Innovation: Network Management Technology Applied to Power Plant Instrumentation, Control, and Maintenance  

Science Conference Proceedings (OSTI)

Generic solutions developed for the information technology and telecommunications (IT-Telco) fields can benefit power plants willing to modernize instrumentation and control (I&C) equipment and maintenance tasks to take advantage of the expanded functionality of new technologies. This report investigates the applicability of generic network management products to help streamline power plant I&C and maintenance practices. Because of the competitive pressures of a large and expanding marketplace, such gene...

2005-07-25T23:59:59.000Z

271

Economic Evaluation of Particulate Control Technologies: Volume 1: New Units  

Science Conference Proceedings (OSTI)

Baghouses (reverse-gas, shake-deflate, and pulse-jet) and electrostatic precipitators are the principal options for controlling particulate emissions at coal-fired power plants. This report provides the latest cost information and cost models for determining the capital and O&M costs of the two technologies for various design conditions in new units.

1992-09-01T23:59:59.000Z

272

UREA INFRASTRUCTURE FOR UREA SCR NOX REDUCTION  

DOE Green Energy (OSTI)

Urea SCR is currently the only proven NOX aftertreatment for diesel engines - high NOX reduction possible - some SCR catalyst systems are robust against fuel sulfur - durability has been demonstrated - many systems in the field - long history in other markets - Major limitations to acceptance - distribution of urea solution to end user - ensuring that urea solution is added to vehicle.

Bunting, Bruce G.

2000-08-20T23:59:59.000Z

273

NETL: Conference Proceedings - 2007 Mercury Control Technology Conference  

NLE Websites -- All DOE Office Websites (Extended Search)

2007 Mercury Control Technology Conference 2007 Mercury Control Technology Conference December 11-13, 2007 Table of Contents Disclaimer Papers and Presentations Overview Sorbent Injection Panel Discussion #1: Sorbents for Mercury Control Mercury Oxidaton and Co-Removal with FGD Systems By-Product Characterization/Management Panel Discussion #2: Mercury Measurements / CEMS Other Mercury Control Technology Panel Discussion #3: Non-Sorbent Mercury Control Poster Presentations Disclaimer This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government or any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. Reference herein to any specific commercial product, process, or service by trade name, trademark, manufacturer, or otherwise does not necessarily constitute or imply its endorsement, recommendation, or favoring by the United States Government or any agency thereof. The views and opinions of authors expressed herein do not necessarily state or reflect those of the United States Government or any agency thereof.

274

Addendum to Guarantee Testing Results from the Greenidge Multi-Pollutant Control Project: Additiona NH3, NOx, and CO Testing Results  

SciTech Connect

On March 28-30 and May 1-4, 2007, CONSOL Energy Inc. Research & Development (CONSOL R&D) performed flue gas sampling at AES Greenidge to verify the performance of the multi-pollutant control system recently installed by Babcock Power Environmental Inc. (BPEI) on the 107-MW Unit 4 (Boiler 6). The multi-pollutant control system includes combustion modifications and a hybrid selective non-catalytic reduction (SNCR)/in-duct selective catalytic reduction (SCR) system to reduce NO{sub x} emissions, followed by a Turbosorp{reg_sign} circulating fluidized bed dry scrubber system and baghouse to reduce emissions of SO{sub 2}, SO{sub 3}, HCl, HF, and particulate matter. Mercury removal is provided via the co-benefits afforded by the in-duct SCR, dry scrubber, and baghouse and by injection of activated carbon upstream of the scrubber, as required. The testing in March and May demonstrated that the multi-pollutant control system attained its performance targets for NO{sub x} emissions, SO{sub 2} removal efficiency, acid gas (SO{sub 3}, HCl, and HF) removal efficiency, and mercury removal efficiency. However, the ammonia slip measured between the SCR outlet and air heater inlet was consistently greater than the guarantee of 2 ppmvd {at} 3% O{sub 2}. As a result, additional testing was performed on May 30-June 1 and on June 20-21, 2007, in conjunction with tuning of the hybrid NO{sub x} control system by BPEI, in an effort to achieve the performance target for ammonia slip. This additional testing occurred after the installation of a large particle ash (LPA) screen and removal system just above the SCR reactor and a fresh SCR catalyst layer in mid-May. This report describes the results of the additional tests. During the May 30-June 1 sampling period, CONSOL R&D and Clean Air Engineering (CAE) each measured flue gas ammonia concentrations at the air heater inlet, downstream of the in-duct SCR reactor. In addition, CONSOL R&D measured flue gas ammonia concentrations at the economizer outlet, upstream of the SCR reactor, and CAE measured flue gas NO{sub x} and CO concentrations at the sampling grids located at the inlet and outlet of the SCR reactor. During the June 20-21 sampling period, CONSOL R&D measured flue gas ammonia concentrations at the air heater inlet. All ammonia measurements were performed using a modified version of U.S. Environmental Protection Agency (EPA) Conditional Test Method (CTM) 027. The NO{sub x} and CO measurements were performed using U.S. EPA Methods 7E and 10, respectively.

Daniel P. Connell; James E. Locke

2008-03-01T23:59:59.000Z

275

Survey of LWR environmental control technology performance and cost  

Science Conference Proceedings (OSTI)

This study attempts to establish a ranking for species that are routinely released to the environment for a projected nuclear power growth scenario. Unlike comparisons made to existing standards, which are subject to frequent revision, the ranking of releases can be used to form a more logical basis for identifying the areas where further development of control technology could be required. This report describes projections of releases for several fuel cycle scenarios, identifies areas where alternative control technologies may be implemented, and discusses the available alternative control technologies. The release factors were used in a computer code system called ENFORM, which calculates the annual release of any species from any part of the LWR nuclear fuel cycle given a projection of installed nuclear generation capacity. This survey of fuel cycle releases was performed for three reprocessing scenarios (stowaway, reprocessing without recycle of Pu and reprocessing with full recycle of U and Pu) for a 100-year period beginning in 1977. The radioactivity releases were ranked on the basis of a relative ranking factor. The relative ranking factor is based on the 100-year summation of the 50-year population dose commitment from an annual release of radioactive effluents. The nonradioactive releases were ranked on the basis of dilution factor. The twenty highest ranking radioactive releases were identified and each of these was analyzed in terms of the basis for calculating the release and a description of the currently employed control method. Alternative control technology is then discussed, along with the available capital and operating cost figures for alternative control methods.

Heeb, C.M.; Aaberg, R.L.; Cole, B.M.; Engel, R.L.; Kennedy, W.E. Jr.; Lewallen, M.A.

1980-03-01T23:59:59.000Z

276

Agricultural Bio-Fueled Generation of Electricity and Development of Durable and Efficent NOx Reduction  

Science Conference Proceedings (OSTI)

The objective of this project was to define the scope and cost of a technology research and development program that will demonstrate the feasibility of using an off-the-shelf, unmodified, large bore diesel powered generator in a grid-connected application, utilizing various blends of BioDiesel as fuel. Furthermore, the objective of project was to develop an emissions control device that uses a catalytic process and BioDiesel (without the presence of Ammonia or Urea)to reduce NOx and other pollutants present in a reciprocating engine exhaust stream with the goal of redefining the highest emission reduction efficiencies possible for a diesel reciprocating generator. Process: Caterpillar Power Generation adapted an off-the-shelf Diesel Generator to run on BioDiesel and various Petroleum Diesel/BioDiesel blends. EmeraChem developed and installed an exhaust gas cleanup system to reduce NOx, SOx, volatile organics, and particulates. The system design and function was optimized for emissions reduction with results in the 90-95% range;

Boyd, Rodney

2007-08-08T23:59:59.000Z

277

NETL: Mercury Emissions Control Technologies - Demonstration of Mer-Cure  

NLE Websites -- All DOE Office Websites (Extended Search)

Demonstration of Mer-Cure Technology for Enhanced Mercury Control Demonstration of Mer-Cure Technology for Enhanced Mercury Control ALSTOM Power, Inc. – U.S. Power Plant Laboratories (ALSTOM-PPL) proposes herein a consortium-based program to demonstrate ALSTOM-PPL's Mer-Cure™ technology – a novel, sorbent-based (Mer-Clean™ ) mercury control technology in coal-fired boilers. The program objective is (i) to demonstrate at a full scale greater than 90% mercury capture based on baseline mercury level (ii) at a cost significantly less than 50% of the $60,000/lb of mercury removed. The proposed full-scale demonstration program is to perform two- to six-month test campaigns in three independent host sites with various boiler configurations over a two-year period. The demonstration program will include a two- to four-week short-term field test followed by two- to six-month long-term demonstration for each of the three selected sites.

278

Information-technology approach to quantum feedback control  

E-Print Network (OSTI)

Quantum control theory is profitably reexamined from the perspective of quantum information, two results on the role of quantum information technology in quantum feedback control are presented and two quantum feedback control schemes, teleportation-based distant quantum feedback control and quantum feedback control with quantum cloning, are proposed. In the first feedback scheme, the output from the quantum system to be controlled is fed back into the distant actuator via teleportation to alter the dynamics of system. The result theoretically shows that it can accomplish some tasks such as distant feedback quantum control that Markovian or Bayesian quantum feedback can't complete. In the second feedback strategy, the design of quantum feedback control algorithms is separated into a state recognition step, which gives "on-off" signal to the actuator through recognizing some copies from the cloning machine, and a feedback (control) step using another copies of cloning machine. A compromise between information acquisition and measurement disturbance is established, and this strategy can perform some quantum control tasks with coherent feedback.

Dao-Yi Dong; Chen-Bin Zhang; Zong-Hai Chen

2005-03-01T23:59:59.000Z

279

New and Underutilized Technology: Carbon Dioxide Demand Ventilation Control  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Carbon Dioxide Demand Ventilation Carbon Dioxide Demand Ventilation Control New and Underutilized Technology: Carbon Dioxide Demand Ventilation Control October 4, 2013 - 4:23pm Addthis The following information outlines key deployment considerations for carbon dioxide (CO2) demand ventilation control within the Federal sector. Benefits Demand ventilation control systems modulate ventilation levels based on current building occupancy, saving energy while still maintaining proper indoor air quality (IAQ). CO2 sensors are commonly used, but a multiple-parameter approach using total volatile organic compounds (TVOC), particulate matter (PM), formaldehyde, and relative humidity (RH) levels can also be used. CO2 sensors control the outside air damper to reduce the amount of outside air that needs to be conditioned and supplied to the building when

280

Procedure to Calculate NOx Reductions Using the Emissions & Generation Resource Integrated Database (E-Grid) Spreadsheet  

E-Print Network (OSTI)

In this report a detailed description of the procedure to calculate NOx reductions from energy savings due to the 2000 IECC code implementation in single family residences using the United States Environmental Protect Agency's (USEPA's) Emissions and Generation Resource Integrated Database (E-GRID) is presented. This procedure is proposed for calculating county-wide NOx reductions in pounds per MWh for Energy Efficiency and Renewable Energy projects (EE/RE) implemented in each Power Control Area (PCA) in the ERCOT region.

Haberl, J. S.; Im, P.; Culp, C.; Yazdani, B.; Fitzpatrick, T.; Verdict, M.; Turner, W. D.

2003-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "nox control technologies" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

DEVELOPMENT AND DEMONSTRATION OF AN ULTRA LOW NOx COMBUSTOR FOR GAS TURBINES  

SciTech Connect

Alzeta Corporation has developed surface-stabilized fuel injectors for use with lean premixed combustors which provide extended turndown and ultra-low NOX emission performance. These injectors use a patented technique to form interacting radiant and blue-flame zones immediately above a selectively-perforated porous metal surface. This allows stable operation at low reaction temperatures. This technology is being commercialized under the product name nanoSTAR. Initial tests demonstrated low NOX emissions but, were limited by flashback failure of the injectors. The weld seams required to form cylindrical injectors from flat sheet material were identified as the cause of the failures. The approach for this project was to first develop new fabrication methods to produce injectors without weld seams, verify similar emissions performance to the original flat sheet material and then develop products for microturbines and small gas turbines along parallel development paths. A 37 month project was completed to develop and test a surface stabilized combustion system for gas turbine applications. New fabrication techniques developed removed a technological barrier to the success of the product by elimination of conductive weld seams from the injector surface. The injectors demonstrated ultra low emissions in rig tests conducted under gas turbine operating conditions. The ability for injectors to share a common combustion chamber allowing for deployment in annular combustion liner was also demonstrated. Some further development is required to resolve integration issues related to specific engine constraints, but the nanoSTAR technology has clearly demonstrated its low emissions potential. The overall project conclusions can be summarized: (1) A wet-laid casting method successfully eliminated weld seams from the injector surface without degrading performance. (2) Gas turbine cycle analysis identified several injector designs and control schemes to start and load engines using nanoSTAR technology. A mechanically simple single zone injector can be used in Solar Turbine's Taurus 60 engine. (3) Rig testing of single monolithic injectors demonstrated sub 3 ppmv NOX and sub 10 ppmv CO and UHC emissions (all corrected to 15% O2) at Taurus 60 full-load pressure and combustion air inlet temperature. (4) Testing of two nanoSTAR injectors in Solar Turbine's sector rig demonstrated the ability for injectors to survive when fired in close proximity at Taurus 60 full load pressure and combustion air inlet temperature. (5) Sector rig tests demonstrated emissions performance and range of operability consistent with single injector rig tests. Alzeta has committed to the commercialization of nanoSTAR injectors and has sufficient production capability to conclude development and meet initial demand.

NEIL K. MCDOUGALD

2005-04-30T23:59:59.000Z

282

DEVELOPMENT AND DEMONSTRATION OF AN ULTRA LOW NOx COMBUSTOR FOR GAS TURBINES  

SciTech Connect

Alzeta Corporation has developed surface-stabilized fuel injectors for use with lean premixed combustors which provide extended turndown and ultra-low NOX emission performance. These injectors use a patented technique to form interacting radiant and blue-flame zones immediately above a selectively-perforated porous metal surface. This allows stable operation at low reaction temperatures. This technology is being commercialized under the product name nanoSTAR. Initial tests demonstrated low NOX emissions but, were limited by flashback failure of the injectors. The weld seams required to form cylindrical injectors from flat sheet material were identified as the cause of the failures. The approach for this project was to first develop new fabrication methods to produce injectors without weld seams, verify similar emissions performance to the original flat sheet material and then develop products for microturbines and small gas turbines along parallel development paths. A 37 month project was completed to develop and test a surface stabilized combustion system for gas turbine applications. New fabrication techniques developed removed a technological barrier to the success of the product by elimination of conductive weld seams from the injector surface. The injectors demonstrated ultra low emissions in rig tests conducted under gas turbine operating conditions. The ability for injectors to share a common combustion chamber allowing for deployment in annular combustion liner was also demonstrated. Some further development is required to resolve integration issues related to specific engine constraints, but the nanoSTAR technology has clearly demonstrated its low emissions potential. The overall project conclusions can be summarized: (1) A wet-laid casting method successfully eliminated weld seams from the injector surface without degrading performance. (2) Gas turbine cycle analysis identified several injector designs and control schemes to start and load engines using nanoSTAR technology. A mechanically simple single zone injector can be used in Solar Turbine's Taurus 60 engine. (3) Rig testing of single monolithic injectors demonstrated sub 3 ppmv NOX and sub 10 ppmv CO and UHC emissions (all corrected to 15% O2) at Taurus 60 full-load pressure and combustion air inlet temperature. (4) Testing of two nanoSTAR injectors in Solar Turbine's sector rig demonstrated the ability for injectors to survive when fired in close proximity at Taurus 60 full load pressure and combustion air inlet temperature. (5) Sector rig tests demonstrated emissions performance and range of operability consistent with single injector rig tests. Alzeta has committed to the commercialization of nanoSTAR injectors and has sufficient production capability to conclude development and meet initial demand.

NEIL K. MCDOUGALD

2005-04-30T23:59:59.000Z

283

Adapting Wireless Technology to Lighting Control and Environmental Sensing  

SciTech Connect

Although advanced lighting control systems offer significant energy savings, the high cost of retrofitting buildings with advanced lighting control systems is a barrier to adoption of this energy-saving technology. Wireless technology, however, offers a solution to mounting installation costs since it requires no additional wiring to implement. To demonstrate the feasibility of such a system, a prototype wirelessly-controlled advanced lighting system was designed and built. The system includes the following components: a wirelessly-controllable analog circuit module (ACM), a wirelessly-controllable electronic dimmable ballast, a T8 3-lamp fixture, an environmental multi-sensor, a current transducer, and control software. The ACM, dimmable ballast, multi-sensor, and current transducer were all integrated with SmartMesh{trademark} wireless mesh networking nodes, called motes, enabling wireless communication, sensor monitoring, and actuator control. Each mote-enabled device has a reliable communication path to the SmartMesh Manager, a single board computer that controls network functions and connects the wireless network to a PC running lighting control software. The ACM is capable of locally driving one or more standard 0-10 Volt electronic dimmable ballasts through relay control and a 0-10 Volt controllable output, in addition to 0-24 Volt and 0-10 Volt inputs. The mote-integrated electronic dimmable ballast is designed to drive a standard 3-lamp T8 light fixture. The environmental multisensor measures occupancy, light level and temperature. The current transducer is used to measure the power consumed by the fixture. Control software was developed to implement advanced lighting algorithms, including open and closed-loop daylight ramping, occupancy control, and demand response. Engineering prototypes of each component were fabricated and tested in a bench-scale system. Based on standard industry practices, a cost analysis was conducted. It is estimated that the installation cost of a wireless advanced lighting control system for a retrofit application is at least 20% lower than a comparable wired system for a typical 16,000 square-foot office building, with a payback period of less than 3 years. At 30% market penetration saturation, a cumulative 695 Billion kWh of energy could be saved through 2025, a cost savings of $52 Billion.

Dana Teasdale; Francis Rubinstein; David S. Watson; Steve Purdy

2006-04-30T23:59:59.000Z

284

NETL: Mercury Emissions Control Technologies - Evaluation of Mercury  

NLE Websites -- All DOE Office Websites (Extended Search)

Control Technology Evaluation of Mercury Emissions from Coal-Fired Facilities w/ SCR and FGD Systems Control Technology Evaluation of Mercury Emissions from Coal-Fired Facilities w/ SCR and FGD Systems CONSOL is evaluating the mercury removal co-benefits achieved by SCR-FGD combi nations. Specific issues that will be addressed include the effects of SCR, catalyst degradation, and load changes on mercury oxidation and capture. This objective will be achieved by measuring mercury removal achieved by SCR-FGD combinations at ten plants with such equipment configurations. These plants include five with wet limestone, three wet lime, and two with dry scrubbing. Material balance will be conducted. Related Papers and Publications: Final Report - April 2006 [PDF-377KB] Topical Report # 11 - January 2006 [PDF-19MB] Topical Report # 9 - January 2006 [PDF-6MB]

285

Lean NOx Trap Catalysis for Lean Natural Gas Engine Applications  

DOE Green Energy (OSTI)

Distributed energy is an approach for meeting energy needs that has several advantages. Distributed energy improves energy security during natural disasters or terrorist actions, improves transmission grid reliability by reducing grid load, and enhances power quality through voltage support and reactive power. In addition, distributed energy can be efficient since transmission losses are minimized. One prime mover for distributed energy is the natural gas reciprocating engine generator set. Natural gas reciprocating engines are flexible and scalable solutions for many distributed energy needs. The engines can be run continuously or occasionally as peak demand requires, and their operation and maintenance is straightforward. Furthermore, system efficiencies can be maximized when natural gas reciprocating engines are combined with thermal energy recovery for cooling, heating, and power applications. Expansion of natural gas reciprocating engines for distributed energy is dependent on several factors, but two prominent factors are efficiency and emissions. Efficiencies must be high enough to enable low operating costs, and emissions must be low enough to permit significant operation hours, especially in non-attainment areas where emissions are stringently regulated. To address these issues the U.S. Department of Energy and the California Energy Commission launched research and development programs called Advanced Reciprocating Engine Systems (ARES) and Advanced Reciprocating Internal Combustion Engines (ARICE), respectively. Fuel efficiency and low emissions are two primary goals of these programs. The work presented here was funded by the ARES program and, thus, addresses the ARES 2010 goals of 50% thermal efficiency (fuel efficiency) and <0.1 g/bhp-hr emissions of oxides of nitrogen (NOx). A summary of the goals for the ARES program is given in Table 1-1. ARICE 2007 goals are 45% thermal efficiency and <0.015 g/bhp-hr NOx. Several approaches for improving the efficiency and emissions of natural gas reciprocating engines are being pursued. Approaches include: stoichiometric engine operation with exhaust gas recirculation and three-way catalysis, advanced combustion modes such as homogeneous charge compression ignition, and extension of the lean combustion limit with advanced ignition concepts and/or hydrogen mixing. The research presented here addresses the technical approach of combining efficient lean spark-ignited natural gas combustion with low emissions obtained from a lean NOx trap catalyst aftertreatment system. This approach can be applied to current lean engine technology or advanced lean engines that may result from related efforts in lean limit extension. Furthermore, the lean NOx trap technology has synergy with hydrogen-assisted lean limit extension since hydrogen is produced from natural gas during the lean NOx trap catalyst system process. The approach is also applicable to other lean engines such as diesel engines, natural gas turbines, and lean gasoline engines; other research activities have focused on those applications. Some commercialization of the technology has occurred for automotive applications (both diesel and lean gasoline engine vehicles) and natural gas turbines for stationary power. The research here specifically addresses barriers to commercialization of the technology for large lean natural gas reciprocating engines for stationary power. The report presented here is a comprehensive collection of research conducted by Oak Ridge National Laboratory (ORNL) on lean NOx trap catalysis for lean natural gas reciprocating engines. The research was performed in the Department of Energy's ARES program from 2003 to 2007 and covers several aspects of the technology. All studies were conducted at ORNL on a Cummins C8.3G+ natural gas engine chosen based on industry input to simulate large lean natural gas engines. Specific technical areas addressed by the research include: NOx reduction efficiency, partial oxidation and reforming chemistry, and the effects of sulfur poisons on the partial oxidation

Parks, II, James E [ORNL; Storey, John Morse [ORNL; Theiss, Timothy J [ORNL; Ponnusamy, Senthil [ORNL; Ferguson, Harley Douglas [ORNL; Williams, Aaron M [ORNL; Tassitano, James B [ORNL

2007-09-01T23:59:59.000Z

286

NETL: Mercury Emissions Control Technologies - Preliminary Field Evaluation  

NLE Websites -- All DOE Office Websites (Extended Search)

Preliminary Field Evaluation of Mercury Control Using Combustion Modifications Preliminary Field Evaluation of Mercury Control Using Combustion Modifications General Electric – Energy and Environmental Research Corporation is developing a new technology that reduces the cost of mercury removal from flue gas by combining it with carbon reduction in a burnout system and simultaneously controlling nitrogen oxides emissions. Data on mercury removal at Western Kentucky Electric’s Green Station will be obtained and used to assess options to improve the efficiency of mercury removal. These options will be further investigated in pilot-scale testing on a 300 kW combustor. Related Papers and Publications: Preliminary Field Evaluation of Hg Control Using Combustion Modifications [PDF-732KB] - Presented at the 2004 Electric Utilities Environmental Conference, Tucson, AZ - January 19-22, 2004.

287

Power generation systems for NOx reduction. CRADA final report for CRADA Number Y-1292-0111  

SciTech Connect

The Cooperative Research and Development Agreement (CRADA) No. Y1292-0111, between Allison Gas Turbine Division of General Motors Corporation and Lockheed Martin Energy Systems, under contract to the US Department of Energy, is entitled ``Power Generation Systems for NOx Reduction``. The objective of this effort was to design, develop, and demonstrate an integrated turbine genset suitable for high efficiency power generation requirements. The result of this effort would have been prototype generator hardware including controllers for testing and evaluation by Allison Gas Turbine Division. The generator would have been coupled to a suitably sized and configured gas turbine engine, which would operate on a laboratory load bank. This effort leads to extensive knowledge and design capability in the most efficient and high power density generator design for mobile power generation and potentially to commercialization of these advanced technologies.

Adams, D.J. [Lockheed Martin Energy Research Corp., Oak Ridge, TN (United States); Berenyi, S.G. [General Motors Corp., Indianapolis, IN (United States). Allison Gas Turbine Div.

1996-04-30T23:59:59.000Z

288

NETL: Mercury Emissions Control Technologies - Amended Silicates for  

NLE Websites -- All DOE Office Websites (Extended Search)

Amended Silicates for Mercury Control Amended Silicates for Mercury Control The project is designed to implement a comprehensive demonstration of the use of Amended Silicates for mercury control on a commercial-scale generating unit. Miami Fort Unit 6 burns eastern bituminous coal, has a nominal output of 175 MW, and a flue gas volumetric flow of 535,000 actual cubic feet per minute (acfm) at full load. The demonstration includes a baseline phase with no injection of mercury control sorbents, injection of carbon to develop a mercury-control technology baseline for sorbent performance comparison, and the injection of Amended Silicates at several rates. All sorbent will be injected upstream of the existing electro-static precipitators (ESPs) on the host unit, providing a nominal 1-second contact time before the gas flow enters an ESP. Mercury measurements will be made upstream of the sorbent injection and downstream of the first ESP to characterize the performance of the sorbent technologies. In addition, samples of coal and fly ash will be collected and analyzed to provide data for a mercury mass balance for the unit. The mercury measurements will be made with continuous emissions monitors as well as with Ontario-Hydro wet-chemistry sampling. Samples of fly ash plus sorbent from demonstration cases which include Amended Silicate sorbent injection will be collected from ESP hoppers for use in concrete testing to confirm the suitability of the material as a portland cement replacement.

289

DYNAMOMETER EVALUATION OF PLASMA-CATALYST FOR DIESEL NOX REDUCTION  

DOE Green Energy (OSTI)

A three-stage plasma-catalyst system was developed and tested on an engine dynamometer. Previous laboratory testing suggested high NOx efficiency could be obtained. With hexene reductant added to the exhaust, over 90% NOx reduction was observed. However, with diesel or Fischer-Tropsch reductant the catalyst efficiency rapidly dropped off. Heating the catalyst in air removed brown deposit from the surface and restored conversion efficiency. Following the engine tests, the used catalysts were evaluated. BET surface area decreased, and TPD revealed significant storage. This storage appears to be partly unburned diesel fuel that can be removed by heating to around 250-300 C, and partly hydrocarbons bonded to the surface that remain in place until 450-500 C. Laboratory testing with propene reductant demonstrated that the catalyst regains efficiency slowly even when operating temperature does not exceed 300 C. This suggests that control strategies may be able to regenerate the catalyst by occasional moderate heating.

Hoard, J; Schmieg, S; Brooks, D; Peden, C; Barlow, S; Tonkyn, R

2003-08-24T23:59:59.000Z

290

Expanding Robust HCCI Operation with Advanced Valve and Fuel Control Technologies Pub ID 38707 Title Expanding Robust HCCI Operation with Advanced Valve and Fuel Control Technologies Status Distributed Communication Type ORNL report ORNL Review? Scientific communication that requires ORNL review Information Category Protected CRADA Information ORNL Report Classification Final Expanding Robust HCCI Operation with Advanced Valve and Fuel Control Technologies  

SciTech Connect

Delphi Automotive Systems and ORNL established this CRADA to advance the commercialization potential of the homogeneous charge compression ignition (HCCI) advanced combustion strategy for gasoline engine platforms. HCCI combustion has been shown by others to produce high diesel-like efficiency on a gasoline engine platform while simultaneously producing low NOX and particulate matter emissions. However, the commercialization barriers that face HCCI combustion are significant, with requirements for a more active engine control system, likely with next-cycle closed-loop feedback control, and with advanced valve train technologies to enable negative valve overlap conditions. In the partnership between Delphi and ORNL, each organization brought a unique and complementary set of skills to the project. Delphi has made a number of breakthroughs with production-intent valve train technologies and controls in recent years to make a part time production-intent HCCI engine plausible. ORNL has extensive knowledge and expertise with HCCI combustion, and also has a versatile research engine with hydraulic valve actuation (HVA) that is useful for guiding production of a cam-based HCCI system. Partnering these knowledge bases and capabilities was essential towards making progress to better understand HCCI combustion and the commercialization barriers that it faces. ORNL and Delphi maintained strong collaboration throughout the project. Meetings were held regularly, with additional reports, presentations, and meetings as necessary to maintain progress. Delphi provided guidance to ORNL regarding operational strategies to investigate on their single-cylinder research engine with HVA and data from their experimental multi-cylinder engine for modeling. ORNL provided single-cylinder engine data and modeling results.

Szybist, J.P.; Confer, K. (Delphi Automotive Systems)

2012-09-11T23:59:59.000Z

291

Development of a Desulfurization Strategy for a NOx Adsorber Catalyst  

DOE Green Energy (OSTI)

Improve NOx regeneration calibration developed in DECSE Phase I project to understand full potential of NOx adsorber catalyst over a range of operating temperatures. Develop and demonstrate a desulfurization process to restore NOx conversion efficiency lost to sulfur contamination. Investigate effect of desulfurization process on long-term performance of the NOx adsorber catalyst.

Tomazic, Dean

2000-08-20T23:59:59.000Z

292

NOxControl revised.p65  

NLE Websites -- All DOE Office Websites (Extended Search)

OCTOBER 2001 OCTOBER 2001 DOE/FE-0442 EVALUATION OF GAS REBURNING AND LOW-NO X BURNERS ON A WALL-FIRED BOILER ENERGY AND ENVIRONMENTAL RESEARCH CORPORATION Disclaimer This report was prepared using publicly available information, including the Final Technical Report and other reports prepared pursuant to a cooperative agreement partially funded by the U.S. Department of Energy. Neither the United States Government nor any agency, employee, contractor, or representative thereof, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe upon privately owned rights. Reference herein to any specific commercial

293

Influence of Ceria on the NOx Storage/Reduction Behavior of Lean NOx Trap Catalysts  

E-Print Network (OSTI)

ACPD 8, 4911­4947, 2008 NOx-induced ozone loss processes B. Vogel et al. Title Page Abstract mesospheric NOx during Arctic Winter 2003/2004 B. Vogel 1 , P. Konopka 1 , J.-U. Groo? 1 , R. M¨uller 1 , B on behalf of the European Geosciences Union. 4911 #12;ACPD 8, 4911­4947, 2008 NOx-induced ozone loss

Pennycook, Steve

294

Instrumentation and Control Technologies for Refueling the AHTR  

Science Conference Proceedings (OSTI)

The process and mechanisms for refueling the Advanced High-Temperature Reactor (AHTR) are currently undergoing preconceptual design. The instrumentation and controls (I&C) required for the fuel transfer are simultaneously under design as part of this process. Overall, the AHTR's refueling system will consist of a fully automated, optically guided mechanical transfer system with operator intervention only required for exception handling. The refueling system design remains too immature to enable selection of particular instrumentation components. This paper provides an overview of the refueling process for the AHTR, the I&C requirements for the refueling, the current I&C design and technology status, and the envisioned process for developing and validating the required technology.

Holcomb, David Eugene [ORNL; Varma, Venugopal Koikal [ORNL

2012-01-01T23:59:59.000Z

295

NETL: Mercury Emissions Control Technologies - Long-Term Carbon Injection  

NLE Websites -- All DOE Office Websites (Extended Search)

Long-Term Carbon Injection Field Test for > 90% Long-Term Carbon Injection Field Test for > 90% Mercury Removal for a PRB Unit with a Spray Drier and Fabric Filter The intent of DOE's Phase I and II field tests was to work with industry to evaluate the most promising mercury control technologies at full-scale in a variety of configurations. Although longer-term tests were conducted, the test period was not sufficient to answer many fundamental questions about long-term consistency of mercury removal and reliability of the system when integrated with plant processes. As the technologies move towards commercial implementation, it is critical to accurately define the mercury removal performance and costs so that power companies and policy makers can make informed decisions. Therefore, the overall objective of this Phase III project is to determine the mercury removal performance, long-term emissions variability, and associated O&M costs of activated carbon injection for >90% mercury control over a 10 to 12 month period on a unit that represents the combination of coal and emission control equipment that will be used for many new and existing power plants.

296

Analysis of the environmental control technology for oil shale development  

SciTech Connect

The environmental control technology proposed in the various oil shale projects which are under development are examined. The technologies for control of air pollution, water pollution, and for the disposal, stabilization, and vegetation of the processed shale were thoroughly investigated. Although some difficulties may be encountered in any of these undertakings, it seems clear that the air and water pollution problems can be solved to meet any applicable standard. There are no published national standards against which to judge the stabilization and vegetation of the processed shale. However, based on the goal of producing an environmentally and aesthetically acceptable finished processed shale pile, it seems probable that this can be accomplished. It is concluded that the environmental control technology is available to meet all current legal requirements. This was not the case before Colorado changed their applicable Air Pollution regulations in August of 1977; the previous ones for the oil shale region were sufficiently stringent to have caused a problem for the current stage of oil shale development. Similarly, the federal air-quality, non-deterioration regulations could be interpreted in the future in ways which would be difficult for the oil shale industry to comply with. The Utah water-quality, non-deterioration regulations could also be a problem. Thus, the only specific regulations which may be a problem are the non-deterioration parts of air and water quality regulations. The unresolved areas of environmental concern with oil shale processing are mostly for the problems not covered by existing environmental law, e.g., trace metals, polynuclear organics, ground water-quality changes, etc. These may be problems, but no evidence is yet available that these problems will prevent the successful commercialization of oil shale production.

de Nevers, N.; Eckhoff, D.; Swanson, S.; Glenne, B.; Wagner, F.

1978-02-01T23:59:59.000Z

297

NETL: Clean Coal Technology Demonstration Program (CCTDP) - Round 2  

NLE Websites -- All DOE Office Websites (Extended Search)

Combined SO2 / NOx Control Technologies Combined SO2 / NOx Control Technologies SNOX(tm) Flue Gas Cleaning Demonstration Project - Project Brief [PDF-359KB] ABB Environmental Systems, Niles, OH PROGRAM PUBLICATIONS Final Reports Final Report Volume II: Project Performance and Economics [PDF-10.2MB] (July 1996) CCT Reports: Project Performance Summaries, Post-Project Assessments, & Topical Reports ABB Environmental Systems SNOX(tm) Flue Gas Cleaning Demonstration Project, Project Performance Summary [PDF-450KB] (June 1999) SNOX(tm) Flue Gas Cleaning Demonstration Project: A DOE Assessment [PDF-185KB] (June 2000) Technologies for the Combined Control of Sulfur Dioxide and Nitrogen Oxides Emissions from Coal-Fired Boilers, Topical Report No. 13 [PDF-500KB] (May 1999) Design Reports Final Report Volume I: Public Design [PDF-3.9MB] (July 1996)

298

Ultra Low NOx Catalytic Combustion for IGCC Power Plants  

DOE Green Energy (OSTI)

In order to meet DOE's goals of developing low-emissions coal-based power systems, PCI has further developed and adapted it's Rich-Catalytic Lean-burn (RCL{reg_sign}) catalytic reactor to a combustion system operating on syngas as a fuel. The technology offers ultra-low emissions without the cost of exhaust after-treatment, with high efficiency (avoidance of after-treatment losses and reduced diluent requirements), and with catalytically stabilized combustion which extends the lower Btu limit for syngas operation. Tests were performed in PCI's sub-scale high-pressure (10 atm) test rig, using a two-stage (catalytic then gas-phase) combustion process for syngas fuel. In this process, the first stage consists of a fuel-rich mixture reacting on a catalyst with final and excess combustion air used to cool the catalyst. The second stage is a gas-phase combustor, where the air used for cooling the catalyst mixes with the catalytic reactor effluent to provide for final gas-phase burnout and dilution to fuel-lean combustion products. During testing, operating with a simulated Tampa Electric's Polk Power Station syngas, the NOx emissions program goal of less than 0.03 lbs/MMBtu (6 ppm at 15% O{sub 2}) was met. NOx emissions were generally near 0.01 lbs/MMBtu (2 ppm at 15% O{sub 2}) (PCI's target) over a range on engine firing temperatures. In addition, low emissions were shown for alternative fuels including high hydrogen content refinery fuel gas and low BTU content Blast Furnace Gas (BFG). For the refinery fuel gas increased resistance to combustor flashback was achieved through preferential consumption of hydrogen in the catalytic bed. In the case of BFG, stable combustion for fuels as low as 88 BTU/ft{sup 3} was established and maintained without the need for using co-firing. This was achieved based on the upstream catalytic reaction delivering a hotter (and thus more reactive) product to the flame zone. The PCI catalytic reactor was also shown to be active in ammonia reduction in fuel allowing potential reductions in the burner NOx production. These reductions of NOx emissions and expanded alternative fuel capability make the rich catalytic combustor uniquely situated to provide reductions in capital costs through elimination of requirements for SCR, operating costs through reduction in need for NOx abating dilution, SCR operating costs, and need for co-firing fuels allowing use of lower value but more available fuels, and efficiency of an engine through reduction in dilution flows.

Shahrokh Etemad; Benjamin Baird; Sandeep Alavandi; William Pfefferle

2008-03-31T23:59:59.000Z

299

Measurement of air toxic emissions from a coal-fired boiler equipped with a tangentially-fired low NOx combustion system  

Science Conference Proceedings (OSTI)

This paper presents the results of measurements of chemical emissions from a coal-burning, tangentially-fired, utility boiler equipped with a hot-side electrostatic precipitator and a low NOx firing system. The tests were conducted in response to Title III of the 1990 Amendments to the Clean Air Act which lists 189 chemicals to be evaluated as {open_quotes}Air Toxics.{close_quotes} The project was jointly funded by the Electric Power Research Institute and the US Department of Energy under an existing Innovative Clean Coal Technology Cooperative Agreement managed by Southern Company Services. Field chemical emissions monitoring was conducted in two phases: a baseline {open_quotes}pre-low NOx burner{close_quotes} condition in September 1991 and in the LNCFS Level III low NOx firing condition in January 1992. In addition to stack emissions measurements of both organic and inorganic chemicals, plant material balance evaluations were performed to determine the efficiency of the hot-side ESP at controlling emissions of air toxics and to determine the fate of the target chemicals in various plant process streams.

Dismukes, E.B. [Southern Research Inst., Birmingham, AL (United States); Clarkson, R.J.; Hardman, R.R. [Southern Company Services, Birmingham, AL (United States); Elia, G.G. [Pittsburgh Energy Technology Center, PA (United States)

1993-11-01T23:59:59.000Z

300

The Office of Fossil Energy's National Energy Technology Laboratory \(NETL\) is teaming with industry and acadamia through ...  

NLE Websites -- All DOE Office Websites (Extended Search)

Energy-National Energy Technology Laboratory's NOx Energy-National Energy Technology Laboratory's NOx Control Program for Coal-Fired Power Plants Bruce W. Lani and Thomas J. Feeley, III U.S. Department of Energy National Energy Technology Laboratory P.O. Box 10940 Pittsburgh, PA 15236-0940 (412) 386-5819 Fax: (412) 386-5917 Email: lani@netl.doe.gov ABSTRACT The environmental performance of the United States' fleet of coal-fired boilers has steadily improved over the last three decades in response to concerns on the potential impact of emissions on the environment. Emissions of sulfur dioxide (SO 2 ), nitrogen oxide (NOx), particulate matter (PM) have been significantly reduced during this period while coal use has almost doubled. However, further restrictions on emissions from power plants have been proposed in response to issues such as mercury, acid rain,

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We encourage you to perform a real-time search of NLEBeta
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301

Control technology appendices for pollution control technical manuals. Final report, June 1982-February 1983  

SciTech Connect

The document is one of six technical handbooks prepared by EPA to help government officials granting permits to build synfuels facilities, synfuels process developers, and other interested parties. They provide technical data on waste streams from synfuels facilities and technologies capable of controlling them. Process technologies covered in the manuals include coal gasification, coal liquefaction by direct and idirect processing, and the extraction of oil from shale. The manuals offer no regulatory guidance, allowing the industry flexibility in deciding how best to comply with environmental regulations.

1983-04-01T23:59:59.000Z

302

Catalysts for Lean Engine Emission Control - Emissions & Emission Controls  

NLE Websites -- All DOE Office Websites (Extended Search)

Catalysts for Lean Engine Emission Control Catalysts for Lean Engine Emission Control Catalysts for controlling NOx from lean engines are studied in great detail at FEERC. Lean NOx Traps (LNTs) and Selective Catalytic Reduction (SCR) are two catalyst technologies of interest. Catalysts are studied from the nanoscale to full scale. On the nanoscale, catalyst powders are analyzed with chemisorptions techniques to determine the active metal surface area where catalysis occurs. Diffuse Reflectance Infrared Fourier Transform (DRIFT) spectroscopy is used to observe the chemical reactions occurring on the catalyst surface during catalyst operation. Both powder and coated catalyst samples are analyzed on bench flow reactors in controlled simulated exhaust environments to better characterize the chemical

303

W. E. Mott, Director, Division of Environmental Control Technology, HQ  

Office of Legacy Management (LM)

Eyergy Eyergy pak t??pEOperatlons dak Ridge, Tennessee 37830 December 12, 1977 W. E. Mott, Director, Division of Environmental Control Technology, HQ Germantown, M.S. E-201 REPORT OF FINDINGS: ALLIED CHEMICAL CORPORATION SITES AT NORTH CLAYMONT, DELAWARE; MARCUS HOOK, PENNSYLVANIA, AND BALTIMORE, MARYLAND The following information summarizes our findings and conclusions relative to the reassessment of the subject sites. Information supplied from files of the former Atomic Energy Commission, Division of Raw Materials, indicates the company was engaged during the 1950's in research and development and pilot scale operations on uranium recovery at North Claymont, Delaware, and possibly at other Allied Chemical sites at Marcus Hook, Pa., and Baltimore, Md. under

304

Synergies of PCCI-Type Combustion and Lean NOx Trap Catalysis for Diesel Engines  

Science Conference Proceedings (OSTI)

It is widely recognized that future NOx and PM emission targets for diesel engines cannot be met solely via advanced combustion over the full engine drive cycle. Therefore some combination of advanced combustion methodology with an aftertreatment technology will be required. In this study, NOx reduction, fuel efficiency, and regeneration performance of lean NOx trap (LNT) were evaluated for four operating conditions. The combustion approaches included baseline engine operation with and without EGR, two exhaust enrichment methods (post injection and delayed injection), and one advanced combustion mode to enable high efficiency clean combustion (HECC). A 1.7 liter 4-cylinder diesel engine was operated under five conditions, which represent key interest points for light-duty diesel operation. At the low load setting the exhaust temperature was too low to enable LNT regeneration and oxidation; however, HECC (low NOx) was achievable. HECC was also reached under more moderate loads and the exhaust temperatures were high enough to enable even further NOx reductions by the LNT. At high loads HECC becomes difficult but the LNT performance improves and acceptable regeneration can be met with enrichment methodologies.

Parks, II, James E [ORNL; Prikhodko, Vitaly Y [ORNL; Kass, Michael D [ORNL; Huff, Shean P [ORNL

2008-01-01T23:59:59.000Z

305

SELECTIVE CATALYTIC REDUCTION OF DIESEL ENGINE NOX EMISSIONS USING ETHANOL AS A REDUCTANT  

DOE Green Energy (OSTI)

NOx emissions from a heavy-duty diesel engine were reduced by more than 90% and 80% utilizing a full-scale ethanol-SCR system for space velocities of 21000/h and 57000/h respectively. These results were achieved for catalyst temperatures between 360 and 400 C and for C1:NOx ratios of 4-6. The SCR process appears to rapidly convert ethanol to acetaldehyde, which subsequently slipped past the catalyst at appreciable levels at a space velocity of 57000/h. Ammonia and N2O were produced during conversion; the concentrations of each were higher for the low space velocity condition. However, the concentration of N2O did not exceed 10 ppm. In contrast to other catalyst technologies, NOx reduction appeared to be enhanced by initial catalyst aging, with the presumed mechanism being sulfate accumulation within the catalyst. A concept for utilizing ethanol (distilled from an E-diesel fuel) as the SCR reductant was demonstrated.

(1)Kass, M; Thomas, J; Lewis, S; Storey, J; Domingo, N; Graves, R (2) Panov, A

2003-08-24T23:59:59.000Z

306

Lean NOx Trap Catalysis for Lean Natural Gas Engine Applications  

Science Conference Proceedings (OSTI)

Distributed energy is an approach for meeting energy needs that has several advantages. Distributed energy improves energy security during natural disasters or terrorist actions, improves transmission grid reliability by reducing grid load, and enhances power quality through voltage support and reactive power. In addition, distributed energy can be efficient since transmission losses are minimized. One prime mover for distributed energy is the natural gas reciprocating engine generator set. Natural gas reciprocating engines are flexible and scalable solutions for many distributed energy needs. The engines can be run continuously or occasionally as peak demand requires, and their operation and maintenance is straightforward. Furthermore, system efficiencies can be maximized when natural gas reciprocating engines are combined with thermal energy recovery for cooling, heating, and power applications. Expansion of natural gas reciprocating engines for distributed energy is dependent on several factors, but two prominent factors are efficiency and emissions. Efficiencies must be high enough to enable low operating costs, and emissions must be low enough to permit significant operation hours, especially in non-attainment areas where emissions are stringently regulated. To address these issues the U.S. Department of Energy and the California Energy Commission launched research and development programs called Advanced Reciprocating Engine Systems (ARES) and Advanced Reciprocating Internal Combustion Engines (ARICE), respectively. Fuel efficiency and low emissions are two primary goals of these programs. The work presented here was funded by the ARES program and, thus, addresses the ARES 2010 goals of 50% thermal efficiency (fuel efficiency) and engines are being pursued. Approaches include: stoichiometric engine operation with exhaust gas recirculation and three-way catalysis, advanced combustion modes such as homogeneous charge compression ignition, and extension of the lean combustion limit with advanced ignition concepts and/or hydrogen mixing. The research presented here addresses the technical approach of combining efficient lean spark-ignited natural gas combustion with low emissions obtained from a lean NOx trap catalyst aftertreatment system. This approach can be applied to current lean engine technology or advanced lean engines that may result from related efforts in lean limit extension. Furthermore, the lean NOx trap technology has synergy with hydrogen-assisted lean limit extension since hydrogen is produced from natural gas during the lean NOx trap catalyst system process. The approach is also applicable to other lean engines such as diesel engines, natural gas turbines, and lean gasoline engines; other research activities have focused on those applications. Some commercialization of the technology has occurred for automotive applications (both diesel and lean gasoline engine vehicles) and natural gas turbines for stationary power. The research here specifically addresses barriers to commercialization of the technology for large lean natural gas reciprocating engines for stationary power. The report presented here is a comprehensive collection of research conducted by Oak Ridge National Laboratory (ORNL) on lean NOx trap catalysis for lean natural gas reciprocating engines. The research was performed in the Department of Energy's ARES program from 2003 to 2007 and covers several aspects of the technology. All studies were conducted at ORNL on a Cummins C8.3G+ natural gas engine chosen based on industry input to simulate large lean natural gas engines. Specific technical areas addressed by the research include: NOx reduction efficiency, partial oxidation and reforming chemistry, and the effects of sulfur poisons on the partial oxidation

Parks, II, James E [ORNL; Storey, John Morse [ORNL; Theiss, Timothy J [ORNL; Ponnusamy, Senthil [ORNL; Ferguson, Harley Douglas [ORNL; Williams, Aaron M [ORNL; Tassitano, James B [ORNL

2007-09-01T23:59:59.000Z

307

Next Generation Natural Gas Vehicle Program Phase I: Clean Air Partners 0.5 g/hp-h NOx Engine Concept; Final Report  

DOE Green Energy (OSTI)

Subcontractor report details work done by Clean Air Partners to develop 0.5 g/hp-h NOx natural gas engine exhaust gas recirculation (EGR) technology for the Next Generation Natural Gas Vehicle Program.

Wong, H. C.

2003-07-01T23:59:59.000Z

308

Electrochemical NOx Sensor for Monitoring Diesel Emissions  

Science Conference Proceedings (OSTI)

Increasingly stringent emissions regulations will require the development of advanced gas sensors for a variety of applications. For example, compact, inexpensive sensors are needed for detection of regulated pollutants, including hydrocarbons (HCs), CO, and NO{sub x}, in automotive exhaust. Of particular importance will be a sensor for NO{sub x} to ensure the proper operation of the catalyst system in the next generation of diesel (CIDI) automobiles. Because many emerging applications, particularly monitoring of automotive exhaust, involve operation in harsh, high-temperature environments, robust ceramic-oxide-based electrochemical sensors are a promising technology. Sensors using yttria-stabilized zirconia (YSZ) as an oxygen-ion-conducting electrolyte have been widely reported for both amperometric and potentiometric modes of operation. These include the well-known exhaust gas oxygen (EGO) sensor. More recently, ac impedance-based (i.e., impedance-metric) sensing techniques using YSZ have been reported for sensing water vapor, hydrocarbons, CO, and NO{sub x}. Typically small-amplitude alternating signal is applied, and the sensor response is measured at a specified frequency. Most impedance-metric techniques have used the modulus (or magnitude) at low frequencies ( 600 C, and thermodynamic calculations predict {approx}90% NO, balance NO{sub 2}. Since automotive exhaust sensors will probably be required to operate at temperatures > 600 C, NO is the dominant component in thermodynamic equilibrium and the target NOx species. Also, the use of upstream catalysts could further promote the conversion of NO{sub x} species to NO. Therefore, the focus of current work is to investigate the response to NO. Nevertheless, minimizing the sensitivity to a variety of competing species is important in order to obtain the accuracy necessary for achieving the emission limits. Mitigating the effect of interfering gases (e.g., O{sub 2}, water vapor, HCs, etc.) is an area of current study. For impedance metric NO{sub x} sensors, our previous work has demonstrated that the cross-sensitivity to O{sub 2} may be accounted for by comparing measurements at multiple frequencies. Other strategies for compensation are also being explored, including calibration using data from existing sensors located nearby. Our current work has made significant advances in terms of developing prototype sensors more suitable for commercialization. Also, dynamometer testing has provided real-world sensor performance data that will be useful in approaching potential suppliers to whom we can transfer the technology for commercialization. The advances are a direct result of understanding the sensing mechanisms responsible for impedance-based NO{sub x} sensing and the effect of materials choice and sensor design/geometry.

Woo, L Y; Glass, R S

2008-11-14T23:59:59.000Z

309

Novel Application of Air Separation Membranes Reduces Engine NOx Emissions  

Nitrogen oxide (NOx) emissions pose risks to human health, and so they need to be reduced. One very effective tool for reducing engine in-cylinder temperature and, hence NOx emissions (NOx is a strong function of temperature), is Exhaust Gas ...

310

Steam effect on NOx reduction over lean NOx trap PtBaO/Al2O3 ...  

Science Conference Proceedings (OSTI)

Compared to dry atmosphere, steam promoted NOx reduction; however, under ... stored NOx over PtBaO/Al2O3 suggest that steam causes NH3 formation over...

311

Microsoft Word - netl NOx paper 0398.doc  

NLE Websites -- All DOE Office Websites (Extended Search)

Overview of NO Overview of NO x Control Technologies Demonstrated under the Department of Energy's Clean Coal Technology Program J.U. Watts U.S. Department of Energy, Federal Energy Technology Center P.O. Box 10940, Pittsburgh PA 15236 A.N. Mann and D.L. Russell, Sr. Burns and Roe Services Corporation P.O. Box 18288, Pittsburgh PA 15236 ABSTRACT The Clean Coal Technology (CCT) Demonstration Program, sponsored by the U. S. Department of Energy (DOE), is a government and industry co-funded technology development effort to demonstrate a new generation of innovative coal utilization processes. The CCT Program began in 1987 and will continue through the year 2000. The purpose of the Program is to remove the economic and environmental impediments associated with the development and demonstration of

312

Proceedings of the Combustion Institute, Volume 29, 2002/pp. 11151121 LABORATORY INVESTIGATION OF AN ULTRALOW NOx PREMIXED  

E-Print Network (OSTI)

by the Office of Industrial Technology of the U.S. Department of Energy for year 2020, a new approach was supported by the U.S. Department of Energy, Office of Industrial Technology, and the California Institute INVESTIGATION OF AN ULTRALOW NOx PREMIXED COMBUSTION CONCEPT FOR INDUSTRIAL BOILERS DAVID LITTLEJOHN,1 ADRIAN J

Knowles, David William

313

Lean NOx Trap Modeling in Vehicle Systems Simulations  

DOE Green Energy (OSTI)

A one-dimensional model for simulating lean NOx trap (LNT) performance is developed and validated using both steady state cycling data and transient data from FTP testing cycles. The model consists of the conservation equations for chemical species and energy in the bulk flow, energy of the solid walls, O2 storage and NOx storage (in the form of nitrites and nitrates). Nitrites and nitrates are formed by diffusion of NO and NO2, respectively, into sorbent particles (assumed to be hemi-spherical in shape) along with O2 and their formation rates are controlled by chemical kinetics as well as solid-phase diffusion rates of NOx species. The model also accounts for thermal aging and sulfation of LNTs. Empirical correlations are developed on the basis of published experimental data to capture these effects. These empirical correlations depend on total mileage for which the LNT has been in use, the mileage accumulated since the last desulfation event in addition to the freshly degreened catalyst characteristics. The model has been used in studies of vehicle systems (integration, performance etc.) including hybrid powertrain configurations. Since the engines in hybrid vehicles turn on and off multiple number of times during single drive cycles, the exhaust systems may encounter multiple cold start transients. Accurate modeling of catalyst warm-up and cooling is, therefore, very important to simulate LNT performance in such vehicles. For this purpose, the convective heat loss from the LNT to the ambient is modeled using a Nusselt number correlation that includes effects of both forced convection and natural convection (with later being important when vehicle is stationary). Using the model, the fuel penalty associated with operating LNTs on small diesel engine powered car during FTP drive cycles is estimated.

Gao, Zhiming [ORNL; Chakravarthy, Veerathu K [ORNL; Daw, C Stuart [ORNL; Conklin, Jim [ORNL

2010-09-01T23:59:59.000Z

314

Systems engineering identification and control of mixed waste technology development  

SciTech Connect

The Department of Energy (DOE) established the Mixed Waste Characterization, Treatment, and Disposal Focus Area (MWFA) to develop technologies required to meet the Department`s commitments for treatment of mixed low-level and transuranic wastes. Waste treatment includes all necessary steps from generation through disposal. Systems engineering was employed to reduce programmatic risk, that is, risk of failure to meet technical commitments within cost and schedule. Customer needs (technology deficiencies) are identified from Site Treatment Plans, Consent Orders, ten year plans, Site Technical Coordinating Groups, Stakeholders, and Site Visits. The Technical Baseline, a prioritized list of technology deficiencies, forms the basis for determining which technology development activities will be supported by the MWFA. Technology Development Requirements Documents are prepared for each technology selected for development. After technologies have been successfully developed and demonstrated, they are documented in a Technology Performance Report. The Technology Performance Reports are available to any of the customers or potential users of the technology, thus closing the loop between problem identification and product development. This systematic approach to technology development and its effectiveness after 3 years is discussed in this paper.

Beitel, G.A.

1997-08-01T23:59:59.000Z

315

Assessment of Thermal Control Technologies for Cooling Electric Vehicle Power Electronics  

DOE Green Energy (OSTI)

NREL is assessing thermal control technologies to improve the thermal performance of power electronics devices for electric vehicles, while reducing the cost, weight, and volume of the system.

Kelly, K.; Abraham, T.; Bennion, K.; Bharathan, D.; Narumanchi, S.; O'Keefe, M.

2008-01-01T23:59:59.000Z

316

High-Efficiency, High-Capacity, Low-NOx Aluminum Melting Using Oxygen-Enhanced Combustion  

SciTech Connect

This report describes the development and application of a novel oxygen enhanced combustion system with an integrated vacuum swing adsorption (VSA) oxygen supply providing efficient, low NOx melting in secondary aluminum furnaces. The mainstay of the combustion system is a novel air-oxy-natural gas burner that achieves high productivity and energy efficiency with low NOx emissions through advanced mixing concepts and the use of separate high- and low-purity oxidizer streams. The technology was installed on a reverberatory, secondary aluminum melting plant at the Wabash Aluminum Alloy's Syracuse, N.Y. plant, where it is currently in operation. Field testing gave evidence that the new burner technology meets the stringent NOx emissions target of 0.323 lb NO2/ton aluminum, thus complying with regulations promulgated by Southern California's South Coast Air Quality Management District (SCAQMD). Test results also indicated that the burner technology exceeded fuel efficiency and melting capacity goals. Economic modeling showed that the novel air-oxy-fuel (ADF) combustion technology provides a substantial increase in furnace profitability relative to air-fuel operation. Model results also suggest favorable economics for the air-oxy-fuel technology relative to a full oxy-fuel conversion of the furnace.

D'Agostini, M.D.

2000-06-02T23:59:59.000Z

317

NETL: Mercury Emissions Control Technologies - Non-Thermal Plasma...  

NLE Websites -- All DOE Office Websites (Extended Search)

Non-Thermal Plasma Based Removal of Mercury Project Summary Powerspan Corp. will pilot test a multi-pollutant technology that converts mercury into mercuric oxide, nitrogen oxide...

318

Air Cooling Technology for Power Electronics Thermal Control (Presentation)  

DOE Green Energy (OSTI)

Assessing potential for air cooling in power electronics is a critical factor in power electronics equipment. NREL aims to assess effective air cooling techniques for power electronics technologies.

Bharathan, D.

2007-11-14T23:59:59.000Z

319

De-NOx Evaluation of Graphene Oxides Supported Vanadium Oxides  

Science Conference Proceedings (OSTI)

About this Abstract. Meeting, Materials Science & Technology 2013. Symposium, Controlled Synthesis, Processing, and Applications of Structural and Functional...

320

Development of nondestructive characterization technologies for process control of ceramics  

DOE Green Energy (OSTI)

Ceramic matrix composites using either continuous ceramic fibers or ceramic whiskers have been shown to have significantly higher fracture toughness than monolithic ceramics. High fracture toughness is necessary for ceramic applications in many advanced heat engines. Nondestructive characterization methods to measure different properties therefore are important for both types of materials. Mass production methods such as slip casting and injection molding, for composites or monolithics, require high reliability; thus, the development of nondestructive characterization methods for process control can have a high payoff. A method of producing continuous-fiber composites is by chemical vapor infiltration (CVI). In this technology, production and process development requires knowledge of the as-infiltrated density distribution and the orientation of the fibers after infiltration. We have demonstrated on injection-molded Si{sub 3}N{sub 4} with 10--15 wt.% binder that by appropriate use of high-gradient-field nuclear magnetic resonance (NMR) imaging and microfocus 3-D X-ray computed tomography (CT), the distribution of polymeric binders can be mapped to with {plus minus}0.5 wt.%. In the case of SiC/SiC CVI continuous-fiber composites made with 0,+, {minus}30 degree cloth layups, we have shown that density variations attributed to process conditions can be detected and that fiber orientations can be determined to better than {plus minus}2 degrees by 3-D X-ray microfocus CT data, together with advanced image processing. All data were acquired on NMR and X-ray CT machines designed and built at Argonne National Laboratory. 15 refs., 7 figs., 5 tabs.

Ellingson, W.A.; Gopalsami, N.; Dieckman, S.L. (Argonne National Lab., IL (United States)); Luethi, T. (EMPA, Duebendorf (Switzerland))

1991-07-01T23:59:59.000Z

Note: This page contains sample records for the topic "nox control technologies" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Control Technology - Multi-Pollutant Control Using Membrane-Based Up-Flow  

NLE Websites -- All DOE Office Websites (Extended Search)

Control Control Control Technologies - Multi-Pollutant Control Using Membrane-Based Up-Flow Wet Precipitation Up-Flow Wet Precipitation The primary objective of this work is to compare the performance of metallic collecting surfaces to the performance of membrane collecting surfaces in a wet electrostatic precipitator (ESP), in terms of their efficiency in removing fine particulates, acid aerosols, and mercury from an actual power plant flue gas stream. The relative durability and overall cost-effectiveness of the membrane collectors versus metallic collectors will also be evaluated. Due to the higher specific powers, superior corrosion resistance, and better wetting and cleaning qualities, the membrane-collecting surface is expected to perform better than the metallic surface. The second objective of the project will be to compare the overall fine particulate, acid aerosol, and mercury removal efficiency of the baseline flue gas treatment system on BMP Units 1 and 2 to the efficiencies obtained when the two wet ESP systems (metallic and membrane collectors) are added to the existing treatment system.

322

NETL: Mercury Emissions Control Technologies - Full-scale Testing...  

NLE Websites -- All DOE Office Websites (Extended Search)

electrostatic precipitator for particulate control, and a wet FGD system for SO2 control. The FGD system has three modules, two of which are normally operated....

323

AIR POLLUTION CONTROL TECHNOLOGY DEVELOPMENT WASTE-AS-FUEL PROCESSES  

E-Print Network (OSTI)

stream char acterization for co-firing RDF and coal as perti nent to the progress of the study to date TECHNOLOGIES There are three primary thermal waste-as-fuel technologies described below: (1) co-firing of an RDF suit able for co-firing. In most instances there is little or no preprocessing associated

Columbia University

324

IEEE TRANSACTION ON CONTROL SYSTEM TECHNOLOGY, VOL. XX, NO. Y, MONTH 2003 1 Control of Natural Gas Catalytic Partial  

E-Print Network (OSTI)

IEEE TRANSACTION ON CONTROL SYSTEM TECHNOLOGY, VOL. XX, NO. Y, MONTH 2003 1 Control of Natural Gas that reforms natural gas to hydrogen-rich mixture to feed the anode field of fuel cell stack is considered partial oxidation of the methane in the natural gas. We present a model-based control analysis and design

Peng, Huei

325

Electrochemical NOx Sensor for Monitoring Diesel Emissions  

SciTech Connect

Increasingly stringent emissions regulations will require the development of advanced gas sensors for a variety of applications. For example, compact, inexpensive sensors are needed for detection of regulated pollutants, including hydrocarbons (HCs), CO, and NO{sub x}, in automotive exhaust. Of particular importance will be a sensor for NO{sub x} to ensure the proper operation of the catalyst system in the next generation of diesel (CIDI) automobiles. Because many emerging applications, particularly monitoring of automotive exhaust, involve operation in harsh, high-temperature environments, robust ceramic-oxide-based electrochemical sensors are a promising technology. Sensors using yttria-stabilized zirconia (YSZ) as an oxygen-ion-conducting electrolyte have been widely reported for both amperometric and potentiometric modes of operation. These include the well-known exhaust gas oxygen (EGO) sensor. More recently, ac impedance-based (i.e., impedance-metric) sensing techniques using YSZ have been reported for sensing water vapor, hydrocarbons, CO, and NO{sub x}. Typically small-amplitude alternating signal is applied, and the sensor response is measured at a specified frequency. Most impedance-metric techniques have used the modulus (or magnitude) at low frequencies (< 1 Hz) as the sensing signal and attribute the measured response to interfacial phenomena. Work by our group has also investigated using phase angle as the sensing signal at somewhat higher frequencies (10 Hz). The higher frequency measurements would potentially allow for reduced sampling times during sensor operation. Another potential advantage of impedance-metric NO{sub x} sensing is the similarity in response to NO and NO{sub 2} (i.e., total-NO{sub x} sensing). Potentiometric NO{sub x} sensors typically show higher sensitivity to NO2 than NO, and responses that are opposite in sign. However, NO is more stable than NO{sub 2} at temperatures > 600 C, and thermodynamic calculations predict {approx}90% NO, balance NO{sub 2}. Since automotive exhaust sensors will probably be required to operate at temperatures > 600 C, NO is the dominant component in thermodynamic equilibrium and the target NOx species. Also, the use of upstream catalysts could further promote the conversion of NO{sub x} species to NO. Therefore, the focus of current work is to investigate the response to NO. Nevertheless, minimizing the sensitivity to a variety of competing species is important in order to obtain the accuracy necessary for achieving the emission limits. Mitigating the effect of interfering gases (e.g., O{sub 2}, water vapor, HCs, etc.) is an area of current study. For impedance metric NO{sub x} sensors, our previous work has demonstrated that the cross-sensitivity to O{sub 2} may be accounted for by comparing measurements at multiple frequencies. Other strategies for compensation are also being explored, including calibration using data from existing sensors located nearby. Our current work has made significant advances in terms of developing prototype sensors more suitable for commercialization. Also, dynamometer testing has provided real-world sensor performance data that will be useful in approaching potential suppliers to whom we can transfer the technology for commercialization. The advances are a direct result of understanding the sensing mechanisms responsible for impedance-based NO{sub x} sensing and the effect of materials choice and sensor design/geometry.

Woo, L Y; Glass, R S

2008-11-14T23:59:59.000Z

326

NETL: Control Technology: Furnace Injection of Alkaline Sorbents  

NLE Websites -- All DOE Office Websites (Extended Search)

Energy Technology Laboratory, under Cooperative Agreement DE-FC26-99FT40718, along with EPRI, the American Electric Power Company (AEP), FirstEnergy Corp., the Tennessee Valley...

327

Control technology for radioactive emissions to the atmosphere at US Department of Energy facilities  

SciTech Connect

The purpose of this report is to provide information to the US Environmental Protection agency (EPA) on existing technology for the control of radionuclide emissions into the air from US Department of Energy (DOE) facilities, and to provide EPA with information on possible additional control technologies that could be used to further reduce these emissions. Included in this report are generic discussions of emission control technologies for particulates, iodine, rare gases, and tritium. Also included are specific discussions of existing emission control technologies at 25 DOE facilities. Potential additional emission control technologies are discussed for 14 of these facilities. The facilities discussed were selected by EPA on the basis of preliminary radiation pathway analyses. 170 references, 131 figures, 104 tables.

Moore, E.B.

1984-10-01T23:59:59.000Z

328

Application of the interphase power controller technology for transmission line power flow control  

SciTech Connect

This paper presents an application of the IPC technology for controlling power flows while maintaining the natural synchronizing capacity of transmission lines. The benefits for transmission systems are a substantial increase in steady-state transmission capability, lower losses and voltage support. An example based on the 500 kV Mead-Phoenix Project demonstrates the effectiveness of the IPC solution: the addition of a 370 Mvar capacitor in parallel with the two 500 kV phase-shifting transformers increases their maximum capability from 1,300 to 1,910 MW. The concepts presented are the results of the first phase of work leading to the development of an IPC using power electronics.

Brochu, J.; Beauregard, F.; Lemay, J.; Morin, G.; Pelletier, P. [Center d`Innovation sur le Transport d`Energie du Quebec, Varennes, Quebec (Canada)] [Center d`Innovation sur le Transport d`Energie du Quebec, Varennes, Quebec (Canada); Thallam, R.S. [Salt River Project, Phoenix, AZ (United States)] [Salt River Project, Phoenix, AZ (United States)

1997-04-01T23:59:59.000Z

329

DENSE PHASE REBURN COMBUSTION SYSTEM (DPRCS) DEMONSTRATION ON A 154 MWE TANGENTIAL FURNACE: ADDITIONAL AREA OF INTEREST-TO DEVELOP AND DEMONSTRATE AN IN-FURNACE MULTI-POLLUTANT REDUCTION TECHNOLOGY TO REDUCE NOx, SO2 & Hg  

Science Conference Proceedings (OSTI)

Semi-dense phase pneumatic delivery and injection of calcium and sodium sorbents, and microfine powdered coal, at various sidewall elevations of an online operating coal-fired power plant, was investigated for the express purpose of developing an in-furnace, economic multi-pollutant reduction methodology for NO{sub x}, SO{sub 2} & Hg. The 154 MWe tangentially-fired furnace that was selected for a full-scale demonstration, was recently retrofitted for NO{sub x} reduction with a high velocity rotating-opposed over-fire air system. The ROFA system, a Mobotec USA technology, has a proven track record of breaking up laminar flow along furnace walls, thereby enhancing the mix of all constituents of combustion. The knowledge gained from injecting sorbents and micronized coal into well mixed combustion gases with significant improvement in particulate retention time, should serve well the goals of an in-furnace multi-pollutant reduction technology; that of reducing back-end cleanup costs on a wide variety of pollutants, on a cost per ton basis, by first accomplishing significant in-furnace reductions of all pollutants.

Allen C. Wiley; Steven Castagnero; Geoff Green; Kevin Davis; David White

2004-03-01T23:59:59.000Z

330

OVERVIEW: TROPOSPHERIC OZONE, SMOG AND OZONE-NOx-VOC SENSITIVITY. Dr. Sanford Sillman  

E-Print Network (OSTI)

. MERMCI and the Waste System Authority of Montgomery County (WSA) evaluated the different NOx reduction-Catalytic Reduction (SNCR) system. The NOxOUT® process is a post combustion NOx reduction method that reduces NOx. Such modifications have been successfully employed to achieve 25-70% reduction in NOx from fossil-fueled combusters

Sillman, Sanford

331

Operational Flexibility Guidelines for Gas Turbine Low NOx Combustion Systems  

Science Conference Proceedings (OSTI)

Gas turbine low-NOx combustion systems can differ in hardware from manufacturer to manufacturer, but the principle is the same. Low-NOx combustors reduce peak flame temperatures by mixing fuel and air before combustion and by keeping the fuel-to-air ratio as low (lean) as possible, while still maintaining combustion stability over the broadest possible operating range. Low-NOx combustion systems are inherently more complex than diffusion combustion systems, a fact that impacts operational flexibility, re...

2011-12-14T23:59:59.000Z

332

INL Control System Situational Awareness Technology Final Report 2013  

SciTech Connect

The Situational Awareness project is a comprehensive undertaking of Idaho National Laboratory (INL) in an effort to produce technologies capable of defending the countrys energy sector infrastructure from cyber attack. INL has addressed this challenge through research and development of an interoperable suite of tools that safeguard critical energy sector infrastructure. The technologies in this project include the Sophia Tool, Mesh Mapper (MM) Tool, Intelligent Cyber Sensor (ICS) Tool, and Data Fusion Tool (DFT). Each is designed to function effectively on its own, or they can be integrated in a variety of customized configurations based on the end users risk profile and security needs.

Gordon Rueff; Bryce Wheeler; Todd Vollmer; Tim McJunkin

2013-01-01T23:59:59.000Z

333

NETL: Clean Coal Technology Demonstration Program (CCTDP) - Round 4  

NLE Websites -- All DOE Office Websites (Extended Search)

4 4 Environmental Control Technologies - Combined SO2 /NOx Control Technologies Milliken Clean Coal Technology Demonstration Project - Project Brief [PDF-342KB] New York State Electric & Gas Corporation, Lansing, NY PROGRAM PUBLICATIONS Final Reports Milliken Clean Coal Technology Demonstration Project, Project Performance and Economics Report, Final Report (Apr 1999) Volume 1 [PDF-12.4MB] Volume 2 [PDF-15.7MB] CCT Reports: Project Performance Summaries, Post-Project Assessments, & Topical Reports Milliken Clean Coal Technology Demonstration Project, Project Performance Summary [PDF-1.4MB] (Nov 2002) Milliken Clean Coal Demonstration Project: A DOE Assessment [PDF-1.1MB] (Aug 2001) Advanced Technologies for the Control of Sulfur Dioxide Emissions from Coal-Fired Boilers, Topical Report No.12 [PDF-1.28MB] (June 1999)

334

NETL: Control Technology - Field Testing of a Wet FGD Additive...  

NLE Websites -- All DOE Office Websites (Extended Search)

Enhanced Mercury Control URS Corporation will demonstrate the use of an additive in wet lime or limestone flue gas desulfurization (FGD) systems to prevent oxidized mercury that...

335

NETL: Mercury Emissions Control Technologies - Long-term Operation...  

NLE Websites -- All DOE Office Websites (Extended Search)

Papers and Publications: Long-Term Evaluation of Activated Carbon Injection for Mercury Control Upstream of a COHPAC Fabric Filter PDF-298KB presented at Air Quality IV...

336

NETL: Mercury Emissions Control Technologies - Pilot Plant Study...  

NLE Websites -- All DOE Office Websites (Extended Search)

well. The facility will be composed of an air preheater, an electrostatic precipitator (ESP) to collect fine particulates, and an alkaline-sorbent injection system to control...

337

Fuel Nozzle Flow Testing Guideline for Gas Turbine Low-NOx Combustion Systems  

Science Conference Proceedings (OSTI)

The evolution of dry low-NOx (DLN) gas turbine combustion systems capable of achieving single-digit emission levels requires precise control of the fuel/air ratio within each combustor. The primary means of maintaining the required fuel/air ratio control is through flow testing designed to ensure even distribution of fuel to both individual fuel nozzles and combustion chambers around the gas turbine. This report provides fuel nozzle flow testing guidelines for advanced gas turbine ...

2012-12-31T23:59:59.000Z

338

IEEE TRANSACTIONS ON CONTROL SYSTEMS TECHNOLOGY, VOL. 15, NO. 3, MARCH 2007 403 Special Issue on Control  

E-Print Network (OSTI)

, traction control, and active safety systems that have the potential to decrease the number and severity powerplants (such as fuel cells), to issues in transmission, driveline, and integrated pow- ertrain control researched alternative powerplant technology for automotive vehicles, which holds promise for positive

Brennan, Sean

339

Economics of pollution trading for SO{sub 2} and NOx  

Science Conference Proceedings (OSTI)

For years economists have urged policymakers to use market-based approaches such as cap-and-trade programs or emission taxes to control pollution. The sulphur dioxide (SO{sub 2}) allowance market created by Title IV of the 1990 US Clean Air Act Amendments represents the first real test of the wisdom of economists' advice. Subsequent urban and regional applications of NOx emission allowance trading took shape in the 1990s in the United States, culminating in a second large experiment in emission trading in the eastern United States that began in 2003. This paper provides an overview of the economic rationale for emission trading and a description of the major US programs for SO{sub 2} and nitrogen oxides. These programs are evaluated along measures of performance including cost savings, environmental integrity, and incentives for technological innovation. The authors offer lessons for the design of future programs including, most importantly, those reducing carbon dioxide. 128 refs., 1 fig., 1 tab.

Dallas Burtraw; David A. Evans; Alan Krupnick; Karen Palmer; Russell Toth

2005-03-15T23:59:59.000Z

340

NETL: Mercury Emissions Control Technologies - Evaluation of Sorbent  

NLE Websites -- All DOE Office Websites (Extended Search)

Evaluation of Sorbent Injection for Mercury Control Evaluation of Sorbent Injection for Mercury Control ADA Environmental Solutions will evaluate injection of activated carbon and other sorbents to remove mercury for a variety of coal and air pollution control equipment configurations. The scope of work is for 36 months and intended to gather operating data that will document actual performance levels and accurate cost information to assess the costs of controlling mercury from coal fired utilities. Testing will be conducted at four different host sites that represent a significant percentage of unit configurations. The subsequent cost analyses will include capital costs, by-product utilization issues, sorbent usage, any necessary enhancements, such as SO3 control or flue gas conditioning, balance of plant, manpower requirements and waste issues. The host sites are Sunflower Electric's Holcomb Station, Ontario Power Generation's Nanticoke Station, AmerenUE's Meramec Station and American Electric Power's (AEP) Conesville Station.

Note: This page contains sample records for the topic "nox control technologies" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Assessment of Emission Control Technologies for Distributed Resource Options  

Science Conference Proceedings (OSTI)

Distributed resources (DR) are projected to be an expanding part of the power generation mix in the future as the market shifts from a strong reliance on large, central power plants to greater use of smaller, more dispersed power generation sources located closer to load centers. This report assesses the current environmental regulatory situation for DR technologies and describes a range of combustion and post-combustion strategies to address environmental requirements. Such information will benefit ener...

1999-12-23T23:59:59.000Z

342

Development and Demonstration of Mercury Control by Dry Technologies  

Science Conference Proceedings (OSTI)

The Environmental Protection Agency (EPA) will regulate mercury emissions from coal-fired boilers under Title III of the Clean Air Act Amendments of 1990, with compliance slated for December 2007. It is thus very important for power producers to determine the amount of mercury emissions from their power plants, options for reducing mercury emissions, the cost-effectiveness of various removal technologies, and the potential impact on power plant operation and other air pollutant emissions.

2003-02-17T23:59:59.000Z

343

Experience curves for power plant emission control technologies  

E-Print Network (OSTI)

1/2, 2004 Experience curves for power plant emission controlcoal-fired electric power plants. In particular, we focus on2004) Experience curves for power plant emission control

Rubin, Edward S.; Yeh, Sonia; Hounshell, David A; Taylor, Margaret R

2007-01-01T23:59:59.000Z

344

Aminoguanidine inhibits aortic hydrogen peroxide production, VSMC NOX activity and hypercontractility in diabetic mice  

E-Print Network (OSTI)

likely via a reduction in NOX-linked hypercontractility.signif- icant reduction in VSMC NOX activity remains to beNOX-derived O 2- in diabetic VSMC might underlie AG reduction

Oak, Jeong-Ho; Youn, Ji-Youn; Cai, Hua

2009-01-01T23:59:59.000Z

345

Environmental-control-technology activities of the Department of Energy in FY 1979  

SciTech Connect

This report provides an annual identification and summarization of environmental control RD and D activities and associated funding conducted by DOE in conjunction with developing environmentally acceptable energy technologies. Environmental control technology is an integral part of the DOE energy technology R, D, and D effort. As the third in a series of annual reports on environmental control R, D, and D activities within DOE, this report may serve as a basis for evaluating program trends. The report presents background material that contributes to the capability to evaluate and assess the environmental control accomplishments, issues, gaps, and overlaps associated with energy development within DOE, in conjunction with other agencies, and in the private sector. A measure of the change in emphasis in the environmental control technology activities within DOE is also presented, indicating shifts, if any, in funding levels for each of the energy technologies. Total DOE FY 1979 budget outlay allocated to environmental control activities was $421,533,000, or 5.0% of the total FY 1979 DOE budget. This report summarizes the inputs received from the energy technology areas. These inputs were submitted in accordance with a description of environmental control related activities, which are those activities directed at research, development, and demonstration of processes, procedures, systems, subsystems, and strategies that directly or indirectly eliminate, minimize, or mitigate environmental impacts. 25 references, 10 figures, 40 tables.

1980-06-01T23:59:59.000Z

346

NETL: Mercury Emissions Control Technologies - University of North Dakota,  

NLE Websites -- All DOE Office Websites (Extended Search)

Table Of Contents for Field Testing Enhancing Carbon Reactivity in Mercury Control in Lignite-Fired Systems Mercury Oxidation Upstream of an ESP and Wet FGD Enhancing Carbon Reactivity in Mercury Control in Lignite-Fired Systems The scope of the project consists of attempting to control mercury at four different power plants using two novel concepts. The first concept is using furnace additives that will enhance the sorbent effectiveness for mercury capture. The other concept involves using novel treated carbons to significantly increase sorbent reactivity and resultant capture of Hg. The furnace additives will be tested at Leland Olds Station and Antelope Valley Station while the novel sorbents will be tested at Stanton Station Units 1 &10. Related Papers and Publications:

347

NETL: Mercury Emissions Control Technologies - Field Demonstration of  

NLE Websites -- All DOE Office Websites (Extended Search)

Field Demonstration of Enhanced Sorbent Injection for Mercury Control Field Demonstration of Enhanced Sorbent Injection for Mercury Control ALSTOM will test their proprietary activated carbon-based sorbent which promotes oxidation and capture of mercury via preparation with chemical additives. ALSTOM proposes to test the sorbents at three utilities burning different coals, PacificCorp’s Dave Johnston (PRB), Basin Electric’s Leland Olds (North Dakota Lignite) and Reliant Energy’s Portland Unit (bituminous). Other project partners include Energy and Environmental Research Center, North Dakota Industrial Commission and Minnkota Power who will be a non-host utility participant. Upon completion of this two year project, ALSTOM will demonstrate the capability of controlling mercury emissions from units equipped with electrostatic precipitators, a configuration representing approximately 75% of the existing units.

348

Establishment of an Environmental Control Technology Laboratory with a Circulating Fluidized-Bed Combustion System  

NLE Websites -- All DOE Office Websites (Extended Search)

EstablishmEnt EstablishmEnt of an EnvironmEntal Control tEChnology laboratory with a CirCulating fluidizEd-bEd Combustion systEm Description In response to President Bush's Clear Skies Initiative in 2002-a legislative proposal to control the emissions of nitrogen oxides (NO x ), sulfur dioxide (SO 2 ), and mercury (Hg) from power plants-the National Energy Technology Laboratory (NETL) organized a Combustion Technology University Alliance and hosted a Solid Fuel Combustion Technology Alliance Workshop. The workshop identified four high- priority research needs for controlling emissions from fossil-fueled power plants: multipollutant control, improved sorbents and catalysts, mercury monitoring and capture, and an improved understanding of the underlying combustion chemistry.

349

Trends Affecting Building Control System Development: Trends in Energy Management Technology  

E-Print Network (OSTI)

technologies on energy management systems and products. Therelative to energy management systems design, specification,and Control System Energy Management System F E D E R A L E

Collins, Ted; Parker, Steven A.; Webster, Tom

2002-01-01T23:59:59.000Z

350

Fiscal interactions and the costs of controlling pollution from electricity  

Science Conference Proceedings (OSTI)

I quantify the costs of controlling SO{sub 2}, carbon, and NOx emissions from power generation, accounting for interactions between environmental policies and the broader fiscal system. I distinguish a dirty technology (coal) that satisfies baseload demand and a clean technology (gas) that is used at peak period, and I distinguish sectors with and without regulated prices. Estimated emissions control costs are substantially lower than in previous models of fiscal interactions that assume a single, constant-returns technology and competitive pricing. The results are reasonably robust to alternative scenarios, such as full price deregulation, and market power in the deregulated sector.

Parry, I.W.H.

2005-01-01T23:59:59.000Z

351

Coal-fueled diesel technology development Emissions Control  

DOE Green Energy (OSTI)

GEESI Emissions Control program activity ranged from control concept testing of 10 CFM slipstream from a CWS fuel single cylinder research diesel engine to the design, installation, and operation of a full-size Emissions Control system for a full-size CWS fuel diesel engine designed for locomotive operation.Early 10 CFM slipstream testing program activity was performed to determine Emissions Characteristics and to evaluate Emissions Control concepts such a Barrier filtration, Granular bed filtration, and Cyclone particulate collection for reduction of particulate and gaseous emissions. Use of sorbent injection into the engine exhaust gas upstream of the barrier filter or use of sorbent media in the granular bed filter were found to provide reduction of exhaust gas SO{sub 2} and NO{sub x} in addition to collection of ash particulate. Emergence of the use of barrier filtration as a most practical Emissions Control concept disclosed a need to improve cleanability of the filter media in order to avoid reduction of turbocharger performance by excessive barrier filter pressure drop. The next progression of program activity, after the slipstream feasibility state, was 500 CFM cold flow testing of control system concepts. The successful completion of 500 CFM cold flow testing of the Envelope Filter led to a subsequent progression to a similar configuration Envelope Filter designed to operate at 500 CFM hot gas flow from the CWS fuel research diesel engine in the GETS engine test laboratory. This Envelope Filter included the design aspect proven by cold flow testing as well as optimization of the selection of the installed filter media.

Van Kleunen, W.; Kaldor, S.; Gal, E.; Mengel, M.; Arnold, M.

1994-01-01T23:59:59.000Z

352

Control System Development for an Advanced-Technology Medium-Duty Hybrid Electric Truck  

E-Print Network (OSTI)

03TB-45 Control System Development for an Advanced-Technology Medium-Duty Hybrid Electric Truck and vehicle test results for a medium-duty hybrid electric truck are reported in this paper. The design the benchmark vehicle. INTRODUCTION Hybrid powertrain is among the most visible transportation technology

Grizzle, Jessy W.

353

NOx reduction by electron beam-produced nitrogen atom injection  

DOE Patents (OSTI)

Deactivated atomic nitrogen generated by an electron beam from a gas stream containing more than 99% N.sub.2 is injected at low temperatures into an engine exhaust to reduce NOx emissions. High NOx reduction efficiency is achieved with compact electron beam devices without use of a catalyst.

Penetrante, Bernardino M. (San Ramon, CA)

2002-01-01T23:59:59.000Z

354

NETL: Clean Coal Technology Demonstration Program (CCTDP) - Round 3  

NLE Websites -- All DOE Office Websites (Extended Search)

Full-Scale Demonstration of Low-NOx Cell Burner Retrofit - Project Brief [PDF-294KB] Full-Scale Demonstration of Low-NOx Cell Burner Retrofit - Project Brief [PDF-294KB] The Babcock & Wilcox Company, Aberdeen, OH PROGRAM PUBLICATIONS Final Reports Full-Scale Demonstration of Low-NOx Cell Burner Retrofit, Final Report [PDF-3.6MB] (July 1994) CCT Reports: Project Performance Summaries, Post-Project Assessments, & Topical Reports Full-Scale Demonstration of Low-NOx Cell Burner Retrofit, Project Performance Summary [PDF-1.18MB] (June 1999) Full-Scale Demonstration of Low-NOx Cell Burner Retrofit: A DOE Assessment [PDF-1.1MB] (Nov 2000) Reducing Emissions of Nitrogen Oxides via Low-NOx Burner Technologies, Topical Report No. 5 [PDF-825KB] (Sept 1996) Design Reports Full-Scale Demonstration of Low-NOx Cell Burner Retrofit, Public Design Report [PDF-2.68MB] (Aug 1991)

355

Ammonia scrubbing technology for CO2 capture  

NLE Websites -- All DOE Office Websites (Extended Search)

Low-Cost CCS Technologies Low-Cost CCS Technologies at Coal-Fired Power Plant in China Dr. Zhao Bo Prof. Chen Changhe Assoc. Prof. WANG Shujuan The Research Group of Emission Control and New Energy Department of Thermal Engineering, Tsinghua University May 30, 2008 Group Members Academician, Prof. XU Xuchang Prof. CHEN Changhe Assoc. Prof. LI Yan Assoc. Prof. ZHUO Yuqun Assoc. Prof. TONG Huiling Assoc. Prof. WANG Shujuan Lecturer ZHAO Bo Research Interests * Emission Control - The formation mechanisms and removal technologies of all the major pollutants from coal combustion, including SO 2 , NOx, and trace elements (Hg, As, Se, etc.); - Sustainable utilization of emission control byproduct; * New Energy - Utilization of solar and geothermal energy; - Hydrogen energy infrastructure development;

356

DIESEL REFORMERS FOR LEAN NOX TRAP REGENERATION AND OTHER ON-BOARD HYDROGEN APPLICATIONS  

DOE Green Energy (OSTI)

Many solutions to meeting the 2007 and 2010 diesel emissions requirements have been suggested. On board production of hydrogen for in-cylinder combustion and exhaust after-treatment provide promising opportunities for meeting those requirements. Other benefits may include using syngas to rapidly heat up exhaust after-treatment catalysts during engine startup. HydrogenSource's development of a catalytic partial oxidation reformer for generating hydrogen from ultra-low sulfur diesel fuel is presented. The system can operate on engine exhaust and diesel fuel with no water tank. Test data for hydrogen regeneration of a lean NOx trap is presented showing 90% NOx conversion at temperatures as low as 150 degrees C and 99% conversion at 300 degrees C. Finally, additional efforts required to fully understand the benefits and commercial challenges of this technology are discussed.

Mauss, M; Wnuck, W

2003-08-24T23:59:59.000Z

357

NETL: Emissions Characterization - Adv. Low-NOx Burner Emissions  

NLE Websites -- All DOE Office Websites (Extended Search)

Advanced Low-NOx Burner Emissions Characterization Advanced Low-NOx Burner Emissions Characterization The goal of this work is to develop a comprehensive, high-quality database characterizing PM2.5 emissions from utility plants firing high sulfur coals. The specific objectives are to: 1) develop and test an ultra low-NOx pulverized coal burner for plug-in retrofit applications without boiler wall tube modifications, 2) assess the impact of low-NOx PC burner operation on NOx and PM2.5 emissions, and 3) provide high-quality data to ensure that future PM2.5 regulations are based on good scientific information. The work will be performed in the Clean Environment Development Facility (CEDF), a 100 million Btu/hr near-full-scale facility located at the Alliance Research Center. Related Papers and Publications:

358

Mercury Emissions Control Technologies (released in AEO2006)  

Reports and Publications (EIA)

The AEO2006 reference case assumes that States will comply with the requirements of the EPAs new CAMR regulation. CAMR is a two-phase program, with a Phase I cap of 38 tons of mercury emitted from all U.S. power plants in 2010 and a Phase II cap of 15 tons in 2018. Mercury emissions in the electricity generation sector in 2003 are estimated at around 50 tons. Generators have a variety of options to meet the mercury limits, such as: switching to coal with a lower mercury content, relying on flue gas desulfurization or selective catalytic reduction equipment to reduce mercury emissions, or installing conventional activated carbon injection (ACI) technology.

Information Center

2006-03-20T23:59:59.000Z

359

Brine pH Modification Scale Control Technology. 2. A Review.pdf | Open  

Open Energy Info (EERE)

Brine pH Modification Scale Control Technology. 2. A Review.pdf Brine pH Modification Scale Control Technology. 2. A Review.pdf Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: Brine pH Modification Scale Control Technology. 2. A Review.pdf Abstract A variety of processes has been deployed at geothermalfields to inhibit or control siliceous scale deposition. It has beenknown for decades that the kinetics of silicic acid polymerizationis retarded when the pH of an aqueous solution is decreased.Therefore, a potential method for controlling siliceous scalingfrom geothermal brine is treatment with acid. Early attempts tocontrol siliceous scaling in geothermal brine-handling equipmentby retarding polymerization led to the belief that the pHhad to be reduced to < 4. Acidifying brine was discourageddue to corrosion concerns.

360

Assessment of geothermal development in the Imperial Valley of California. Volume 2. Environmental control technology  

DOE Green Energy (OSTI)

Environmental control technologies are essential elements to be included in the overall design of Imperial Valley geothermal power systems. Environmental controls applicable to abatement of hydrogen sulfide emissions, cooling tower drift, noise, liquid and solid wastes, and induced subsidence and seismicity are assessed here. For optimum abatement of H{sub 2}S under a variety of plant operating conditions, removal of H{sub 2}S upstream of the steam turbine is recommended. The environmental impact of cooling tower drift will be closely tied to the quality of cooling water supplies. Conventional noise abatement procedures can be applied and no special research and development are needed. Injection technology constitutes the primary and most essential environmental control and liquid waste disposal technology for Imperial Velley geothermal operations. Subsurface injection of fluids is the primary control for managing induced subsidence. Careful maintenance of injection pressure is expected to control induced seismicity. (MHR)

Morris, W.; Hill, J. (eds.)

1980-07-01T23:59:59.000Z

Note: This page contains sample records for the topic "nox control technologies" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Environment, health, socioeconomics and environmental control technology. Executive summary  

DOE Green Energy (OSTI)

This report summarizes the important findings of a two-volume report that deals with the potential impacts and environmental controls associated with the operation of geothermal power plants in California's Imperial Valley. The valley contains nearly a third of the nation's total energy potential for identified hot-water resources. Possible impacts of developing those resources include violation of air quality standards if emissions of hydrogen sulfide are not abated, negative ecological effects resulting from increased in the salinity of the Salton Sea, and damage to irrigation systems caused by land subsidence induced by the extraction of geothermal fluids. Other minor impacts concern occupational health and safety, socioeconomics, and hazardous wastes. Analyses of environmental impacts and the control measures for minimizing negative impacts are based primarily on a projected production of 3000 MW of electrical power by the year 2010.

Layton, D.W.

1980-10-01T23:59:59.000Z

362

Coal-fueled diesel emissions control technology development  

DOE Green Energy (OSTI)

The objective of this project is to develop an emissions control system for a GE locomotive powered by a Coal Water Slurry (CWS) fuel diesel engine. The development effort is directed toward reducing particulate matter, SO{sub 2} and NO{sub x} emissions from the engine exhaust gas at 700--800F and 1-2 psig. The commercial system should be economically attractive while subject to limited space constraints. After testing various alternatives, a system composed of a barrier filter with sorbent injection ups was selected for controlling particulates, SO{sub 2} and NO{sub x} emissions. In bench scale and 500 acfm slip s tests, removal efficiencies greater than 90% for SO{sub 2} and 85% for NO{sub x} were achieved. Particulate emissions from the barrier filter are within NSPS limits.

Cook, C.; Gal, E.; Mengel, M.; Van Kleunen, W.

1993-03-01T23:59:59.000Z

363

Coal-fueled diesel emissions control technology development  

DOE Green Energy (OSTI)

The objective of this project is to develop an emissions control system for a GE locomotive powered by a Coal Water Slurry (CWS) fuel diesel engine. The development effort is directed toward reducing particulate matter, SO[sub 2] and NO[sub x] emissions from the engine exhaust gas at 700--800F and 1-2 psig. The commercial system should be economically attractive while subject to limited space constraints. After testing various alternatives, a system composed of a barrier filter with sorbent injection ups was selected for controlling particulates, SO[sub 2] and NO[sub x] emissions. In bench scale and 500 acfm slip s tests, removal efficiencies greater than 90% for SO[sub 2] and 85% for NO[sub x] were achieved. Particulate emissions from the barrier filter are within NSPS limits.

Cook, C.; Gal, E.; Mengel, M.; Van Kleunen, W.

1993-01-01T23:59:59.000Z

364

NETL: Mercury Emissions Control Technologies - Sorbent Injection for Small  

NLE Websites -- All DOE Office Websites (Extended Search)

Sorbent Injection for Small ESP Mercury Control in Low Sulfur Eastern Bituminous Coal Flue Gas Sorbent Injection for Small ESP Mercury Control in Low Sulfur Eastern Bituminous Coal Flue Gas URS Group and their test team will evaluate sorbent injection for mercury control on sites with low-SCA ESPs, burning low sulfur Eastern bituminous coals. Full-scale tests will be performed at Plant Yates Units 1 and 2 to evaluate sorbent injection performance across a cold-side ESP/wet FGD and a cold-side ESP with a dual NH3/SO3 flue gas conditioning system, respectively. Short-term parametric tests on Units 1 and 2 will provide data on the effect of sorbent injection rate on mercury removal and ash/FGD byproduct composition. Tests on Unit 2 will also evaluate the effect of dual-flue gas conditioning on sorbent injection performance. Results from a one-month injection test on Unit 1 will provide insight to the long-term performance and variability of this process as well as any effects on plant operations. The goals of the long-term testing are to obtain sufficient operational data on removal efficiency over time, effects on the ESP and balance of plant equipment, and on injection equipment operation to prove process viability.

365

Energy utilization and environmental control technologies in the coal-electric cycle  

SciTech Connect

This report presents an overview and assessment of the currently commercial and possible future technologies in the United States that are a part of the coal-electric cycle. From coal production to residual emissions control at the power plant stack, this report includes a brief history, current status and future assessment of each technology. It also includes a discussion, helpful for policy making decisions, of the process operation, environmental emission characteristics, market constraints and detailed cost estimates for each of these technologies, with primary emphasis on coal preparation, coal-electric generation and emissions control systems.

Ferrell, G.C.

1977-10-01T23:59:59.000Z

366

Systems and Controls Analysis and Testing; Harvesting More Wind Energy with Advanced Controls Technology (Fact Sheet)  

DOE Green Energy (OSTI)

This fact sheet outlines the systems and controls analysis and testing that takes place at the NWTC on the Controls Advanced Research Turbines.

Not Available

2010-01-01T23:59:59.000Z

367

Real-time Combustion Control and Diagnostics Sensor-Pressure Oscillation Monitor  

NLE Websites -- All DOE Office Websites (Extended Search)

Combustion Control and Diagnostics Combustion Control and Diagnostics Sensor-Pressure Oscillation Monitor Opportunity The Department of Energy's National Energy Technology Laboratory (NETL) is seeking licensing partners interested in implementing its patented "Real-Time Combustion Control and Diagnostics Sensor-Pressure Oscillation Monitor" technology. Disclosed is NETL's sensor system and process for monitoring and controlling the amplitude and/or frequencies of dynamic pressure oscillations in combustion systems during active combustion processes. The combustion control and diagnostics sensor (CCADS) is designed for gas turbine combustors that are operated near the fuel-lean flame extinction limit to minimize production of the atmospheric pollutant NOx. CCADS eliminates the problems of flashback,

368

Assessment of basic research needs for greenhouse gas control technologies  

SciTech Connect

This paper is an outgrowth of an effort undertaken by the Department of Energy's Office of Energy Research to assess the fundamental research needs to support a national program in carbon management. Five topics were identified as areas where carbon management strategies and technologies might be developed: (1) capture of carbon dioxide, decarbonization strategies, and carbon dioxide disposal and utilization; (2) hydrogen development and fuel cells; (3) enhancement of the natural carbon cycle; (4) biomass production and utilization; and (5) improvement of the efficiency of energy production, conversion, and utilization. Within each of these general areas, experts came together to identify targets of opportunity for fundamental research likely to lead to the development of mid- to long-term solutions for stabilizing or decreasing carbon dioxide and other greenhouse gases in the atmosphere. Basic research to support the options outlined above are far reaching-from understanding natural global processes such as the ocean and terrestrial carbon cycles to development of new materials and concepts for chemical separation. Examples of fundamental research needs are described in this paper.

Benson, S.M.; Chandler, W.; Edmonds, J.; Houghton, J.; Levine, M.; Bates, L.; Chum, H.; Dooley, J.; Grether, D.; Logan, J.; Wiltsee, G.; Wright, L.

1998-09-01T23:59:59.000Z

369

Advanced Instrumentation, Information, and Control System Technologies: Nondestructive Examination Technologies - FY11 Report  

SciTech Connect

Licensees of commercial nuclear power plants in the US are expected to submit license renewal applications for the period of operation of 60 to 80 years which has also been referred to as long term operation (LTO). The greatest challenges to LTO are associated with degradation of passive components as active components are routinely maintained and repaired or placed through maintenance programs. Some passive component degradation concerns include stress corrosion cracking (SCC) of metal components, radiation induced embrittlement of the reactor pressure vessel (RPV), degradation of buried piping, degradation of concrete containment structures, and degradation of cables. Proactive management of passive component aging employs three important elements including online monitoring of degradation, early detection of degradation at precursor stages, and application of prognostics for the prediction of remaining useful life (RUL). This document assesses several nondestructive examination (NDE) measurement technologies for integration into proactive aging management programs. The assessment is performed by discussing the three elements of proactive aging management identified above, considering the current state of the industry with respect to adopting these key elements, and analyzing measurement technologies for monitoring large cracks in metal components, monitoring early degradation at precursor stages, monitoring the degradation of concrete containment structures, and monitoring the degradation of cables. Specific and general needs have been identified through this assessment. General needs identified include the need for environmentally rugged sensors are needed that can operate reliably in an operating reactor environment, the need to identify parameters from precursor monitoring technologies that are unambiguously correlated with the level of pre-macro defect damage, and a methodology for identifying regions where precursor damage is most likely to initiate.

Meyer, Ryan M.; Coble, Jamie B.; Ramuhalli, Pradeep; Bond, Leonard J.

2011-08-30T23:59:59.000Z

370

Control of attendance applied in higher education through mobile NFC technologies  

Science Conference Proceedings (OSTI)

This paper presents an improved attendance control system, required for continuous evaluation which has become compulsory following the Bologna Process. It provides a solution based on NFC technology and is based on a real project developed and pilot ... Keywords: Check-in, Class attendance, EHEA, NFC, Presence control, QR codes, Roll call, Tap & Go

Marcos J. LPez FernNdez; Jorge GuzN FernNdez; Sergio ROs Aguilar; Blanca Salazar Selvi; RubN GonzLez Crespo

2013-09-01T23:59:59.000Z

371

NREL's National Wind Technology Center provides the world's only dedicated turbine controls testing platforms.  

E-Print Network (OSTI)

NREL's National Wind Technology Center provides the world's only dedicated turbine controls testing platforms. Today's utility-scale wind turbine structures are more complex and their compo- nents more of algorithms to control the dynamic systems of wind turbines must account for multiple complex, nonlinear

372

FEMP/NTDP Technology Focus Chiller Controls-related Energy Saving Opportunities  

E-Print Network (OSTI)

are designed and operated, and in the diversity of chiller products that are available to support innovativeFEMP/NTDP Technology Focus Chiller Controls-related Energy Saving Opportunities in Federal in recent years has been on optimization of set point and staging controls, improvements in chiller design

373

Study of storage yard PRIC key technologies based on modern measurement and control  

Science Conference Proceedings (OSTI)

Pattern recognition and intelligent control (PRIC) based on modern measure and control is developing with the important challenge that machine how to percept external environment information. At the same time, storage yard automation guarantee the efficiency ... Keywords: PRIC technology, embedded system, fuzzy theory, image matching, storage yard

Changan Ji; Xiubin Zhang; Junhao Ying; Yi Wang; Guohui Zeng

2006-04-01T23:59:59.000Z

374

JV Task 126 - Mercury Control Technologies for Electric Utilities Burning Bituminous Coal  

SciTech Connect

The EERC developed an applied research consortium project to test cost-effective mercury (Hg) control technologies for utilities burning bituminous coals. The project goal was to test innovative Hg control technologies that have the potential to reduce Hg emissions from bituminous coal-fired power plants by {ge}90% at costs of one-half to three-quarters of current estimates for activated carbon injection (ACI). Hg control technology evaluations were performed using the EERC's combustion test facility (CTF). The CTF was fired on pulverized bituminous coals at 550,000 Btu/hr (580 MJ/hr). The CTF was configured with the following air pollution control devices (APCDs): selective catalytic reduction (SCR) unit, electrostatic precipitator (ESP), and wet flue gas desulfurization system (WFDS). The Hg control technologies investigated as part of this project included ACI (three Norit Americas, Inc., and eleven Envergex sorbents), elemental mercury (Hg{sup 0}) oxidation catalysts (i.e., the noble metals in Hitachi Zosen, Cormetech, and Hitachi SCR catalysts), sorbent enhancement additives (SEAs) (a proprietary EERC additive, trona, and limestone), and blending with a Powder River Basin (PRB) subbituminous coal. These Hg control technologies were evaluated separately, and many were also tested in combination.

Jason Laumb; John Kay; Michael Jones; Brandon Pavlish; Nicholas Lentz; Donald McCollor; Kevin Galbreath

2009-03-29T23:59:59.000Z

375

NETL: Mercury Emissions Control Technologies - Bench Scale Kinetics of  

NLE Websites -- All DOE Office Websites (Extended Search)

Bench Scale Kinetics of Mercury Reactions in FGD Liquors Bench Scale Kinetics of Mercury Reactions in FGD Liquors When research into the measurement and control of Hg emissions from coal-fired power plants began in earnest in the early 1990s, it was observed that oxidized mercury can be scrubbed at high efficiency in wet FGD systems, while elemental mercury can not. In many cases, elemental mercury concentrations were observed to increase slightly across wet FGD systems, but this was typically regarded as within the variability of the measurement methods. However, later measurements have shown substantial re-emissions from some FGD systems. The goal of this project is to develop a fundamental understanding of the aqueous chemistry of mercury (Hg) absorbed by wet flue gas desulfurization (FGD) scrubbing liquors. Specifically, the project will determine the chemical reactions that oxidized mercury undergoes once absorbed, the byproducts of those reactions, and reaction kinetics.

376

Arms Control and Nonproliferation Technologies Second Quarter 1993I................................................................................................................................................................  

E-Print Network (OSTI)

Observers from the Department of Energy and the Defense Nuclear Agency watch as a tag/seal is applied to a uranium hexafluoride cylinder during the demonstration held at Portsmouth Gaseous Diffusion Plant. In June 1993, the Department of Energy conducted a demonstration of the ability to tag and seal potential nuclear material containers appropriate for the U.S.-Russian conversion of highly enriched uranium (HEU) to lowenrichment uranium (LEU). Begun in the Office of Arms Control and Nonproliferation, the task was carried out after DOE's reorganization by the Qffice of Research and Development. Tags and seals that were previously developed at the DOE national laboratories and under the sponsorship of the Defense Nuclear Agency were demonstrated on three possible containers: the Department of Transportation Specification 6M HEU container, the AT-400R HEU container, and the Type 30B uranium hexafluoride cylinder.

Thepurposeof Armscontroland

1993-01-01T23:59:59.000Z

377

Hydrogen-control systems for severe LWR accident conditions - a state-of-technology report  

Science Conference Proceedings (OSTI)

This report reviews the current state of technology regarding hydrogen safety issues in light water reactor plants. Topics considered in this report relate to control systems and include combustion prevention, controlled combustion, minimization of combustion effects, combination of control concepts, and post-accident disposal. A companion report addresses hydrogen generation, distribution, and combustion. The objectives of the study were to identify the key safety issues related to hydrogen produced under severe accident conditions, to describe the state of technology for each issue, and to point out ongoing programs aimed at resolving the open issues.

Hilliard, R.K.; Postma, A.K.; Jeppson, D.W.

1983-03-01T23:59:59.000Z

378

Using Semantic Web Technologies to Develop Intrinsically Resilient Energy Control Systems  

SciTech Connect

To preserve critical energy control functions while under attack, it is necessary to perform comprehensive analysis on root causes and impacts of cyber intrusions without sacrificing the availability of energy delivery. We propose to design an intrinsically resilient energy control system where we extensively utilize Semantic Web technologies, which play critical roles in knowledge representation and acquisition. While our ultimate goal is to ensure availability/resiliency of energy delivery functions and the capability to assess root causes and impacts of cyber intrusions, the focus of this paper is to demonstrate a proof of concept of how Semantic Web technologies can significantly contribute to resilient energy control systems.

Sheldon, Frederick T [ORNL; Huang, Jingshan [ORNL; Fetzer, Daniel T [ORNL; Morris, Thomas H [ORNL; Jonathan, Kirsch [Siemens Corporate Research; Goose, Stuart [Siemens Corporate Research; Wei, Dong [Siemens Corporate Research; Dang, Jiangbo [Siemens Corporate Research; Manz, David [Pacific Northwest National Laboratory (PNNL)

2012-01-01T23:59:59.000Z

379

Review of Literature on Terminal Box Control, Occupancy Sensing Technology and Multi-zone Demand Control Ventilation (DCV)  

Science Conference Proceedings (OSTI)

This report presents an overall review of the standard requirement, the terminal box control, occupancy sensing technology and DCV. There is system-specific guidance for single-zone systems, but DCV application guidance for multi-zone variable air volume (VAV) systems is not available. No real-world implementation case studies have been found using the CO2-based DCV. The review results also show that the constant minimum air flow set point causes excessive fan power consumption and potential simultaneous heating and cooling. Occupancy-based control (OBC) is needed for the terminal box in order to achieve deep energy savings. Key to OBC is a technology for sensing the actual occupancy of the zone served in real time. Several technologies show promise, but none currently fully meets the need with adequate accuracy and sufficiently low cost.

Liu, Guopeng; Dasu, Aravind R.; Zhang, Jian

2012-03-01T23:59:59.000Z

380

Program on Technology Innovation: Combustion Exhaust Gas Monitoring with Laser Absorption Sensors  

Science Conference Proceedings (OSTI)

In current plant practice, the operator of a coal-fired boiler must typically rely on a limited number of point measurements of exhaust-gas oxygen and nitric oxides (NOX) to support combustion and selective catalytic reduction (SCR) control efforts with the goal of meeting emissions reduction mandates. As a possible alternative, tunable diode laser technology offers the potential for enabling a much richer set of measurements to be obtained using in situ, species-specific laser absorption sensors. This t...

2012-07-11T23:59:59.000Z

Note: This page contains sample records for the topic "nox control technologies" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Available Technologies: Ultra-low Emission Natural Draft ...  

Low air emissions, particularly NOx, without post-combustion emissions controls ; Enables refineries to continuing using natural gas or refinery gas ...

382

NETL: Clean Coal Technology Demonstration Program (CCTDP) - Round...  

NLE Websites -- All DOE Office Websites (Extended Search)

Coal Reburning for Cyclone Boiler NOx Control - Project Brief PDF-320KB The Babcock & Wilcox Company, Cassville, WI Program Publications Final Reports Demonstration of Coal...

383

Technologies Applications  

E-Print Network (OSTI)

. MERMCI and the Waste System Authority of Montgomery County (WSA) evaluated the different NOx reduction-Catalytic Reduction (SNCR) system. The NOxOUT® process is a post combustion NOx reduction method that reduces NOx. Such modifications have been successfully employed to achieve 25-70% reduction in NOx from fossil-fueled combusters

384

NETL: Mercury Emissions Control Technologies - On-Site Production of  

NLE Websites -- All DOE Office Websites (Extended Search)

On-Site Production of Mercury Sorbent with Low Concrete Impact On-Site Production of Mercury Sorbent with Low Concrete Impact The detrimental health effects of mercury are well documented. Furthermore, it has been reported that U.S. coal-fired plants emit approximately 48 tons of mercury a year. To remedy this, the U.S. Environmental Protection Agency (EPA) released the Clean Air Mercury Rule (CAMR) on March 15, 2005. A promising method to achieve the mandated mercury reductions is activated carbon injection (ACI). While promising, the current cost of ACI for mercury capture is expensive, and ACI adversely impacts the use of the by-product fly-ash for concrete. Published prices for activated carbon are generally 0.5-1 $/lb and capital costs estimates are 2-55 $/KW. Because of the high costs of ACI, Praxair started feasibility studies on an alternative process to reduce the cost of mercury capture. The proposed process is composed of three steps. First, a hot oxidant mixture is created by using a proprietary Praxair burner. Next, the hot oxidant is allowed to react with pulverized coal and additives. The resulting sorbent product is separated from the resulting syngas. In a commercial installation, the resulting sorbent product would be injected between the air-preheater and the particulate control device.

385

METHANE de-NOX for Utility PC Boilers  

SciTech Connect

The overall project objective is the development and validation of an innovative combustion system, based on a novel coal preheating concept prior to combustion, that can reduce NO{sub x} emissions to 0.15 lb/million Btu or less on utility pulverized coal (PC) boilers. This NO{sub x} reduction should be achieved without loss of boiler efficiency or operating stability, and at more than 25% lower levelized cost than state-of-the-art SCR technology. A further objective is to ready technology for full-scale commercial deployment to meet the market demand for NO{sub x} reduction technologies. Over half of the electric power generated in the U.S. is produced by coal combustion, and more than 80% of these units utilize PC combustion technology. Conventional measures for NOx reduction in PC combustion processes rely on combustion and post-combustion modifications. A variety of combustion-based NO{sub x} reduction technologies are in use today, including low-NO{sub x} burners (LNBs), flue gas recirculation (FGR), air staging, and natural gas or other fuel reburning. Selective non-catalytic reduction (SNCR) and selective catalytic reduction (SCR) are post-combustion techniques. NO{sub x} reduction effectiveness from these technologies ranges from 30 to 60% and up to 90-93% for SCR. Typically, older wall-fired PC burner units produce NO{sub x} emissions in the range of 0.8-1.6 lb/million Btu. Low-NO{sub x} burner systems, using combinations of fuel staging within the burner and air staging by introduction of overfire air in the boiler, can reduce NO{sub x} emissions by 50-60%. This approach alone is not sufficient to meet the desired 0.15 lb/million Btu NO{sub x} standard with a range of coals and boiler loads. Furthermore, the heavy reliance on overfire air can lead to increased slagging and corrosion in furnaces, particularly with higher-sulfur coals, when LNBs are operated at sub-stoichiometric conditions to reduce fuel-derived NOx in the flame. Therefore, it is desirable to minimize the need for overfire air by maximizing NO{sub x} reduction in the burner. The proposed combustion concept aims to greatly reduce NO{sub x} emissions by incorporating a novel modification to conventional or low-NO{sub x} PC burners using gas-fired coal preheating to destroy NO{sub x} precursors and prevent NO{sub x} formation. A concentrated PC stream enters the burner, where flue gas from natural gas combustion is used to heat the PC up to about 1500 F prior to coal combustion. Secondary fuel consumption for preheating is estimated to be 3 to 5% of the boiler heat input. This thermal pretreatment releases coal volatiles, including fuel-bound nitrogen compounds into oxygen-deficient atmosphere, which converts the coal-derived nitrogen compounds to molecular N{sub 2} rather than NO. Design, installation, shakedown, and testing on Powder River Basin (PRB) coal at a 3-million Btu/h pilot system at RPI's (Riley Power, Inc.) pilot-scale combustion facility (PSCF) in Worcester, MA demonstrated that the PC PREHEAT process has a significant effect on final O{sub x} formation in the coal burner. Modifications to both the pilot system gas-fired combustor and the PC burner led to NO{sub x} reduction with PRB coal to levels below 0.15 lb/million Btu with CO in the range of 35-112 ppmv without any furnace air staging.

Bruce Bryan; Serguei Nester; Joseph Rabovitser; Stan Wohadlo

2005-09-30T23:59:59.000Z

386

Modeling of NOx formation in circular laminar jet flames  

E-Print Network (OSTI)

Emissions of oxides of nitrogen (NOx) from combustion devices is a topic of tremendous current importance. The bulk of the review of NOx emissions has been in the field of turbulent jet flames. However laminar jet flames have provided much insight into the relative importance of NOx reaction pathways in non premixed combustion for various flame conditions. The existing models include detailed chemistry kinetics for various species involved in the flame. These detailed models involve very complex integration of hundreds of chemical reactions of various species and their intermediates. Hence such models are highly time consuming and also normally involve heavy computational costs. This work proposes a numerical model to compute the total production of NOx in a non-premixed isolated circular laminar jet flame. The jet consists of the fuel rich inner region and the O2 rich outer region. The model estimates both thermal NOx and prompt NOx assuming single step kinetics for NOx formation and a thin flame model. Further the amount of air entrainment by jet depends upon the Sc number of fuel. The higher the Sc number, the higher is the air entrained which lowers the flame temperature and hence NOx formation. With increasing Sc number, flame volume increases which leads to an increase in the NOx formation. The effect of the Sc number variation on the net production of NOx and flame structure is also investigated. The effect of equilibrium chemistry for CO2 CO + 1/2 O2 and H2O H2 +1/2 O2 on total NOx emission is studied. Also the effect of both CO2 and H2O equilibrium is considered simultaneously and the net x NO formation for propane is 45 ppm. The split between pre-flame and post-flame regions is also investigated. For Propane, 96% of NO emissions occur in the pre-flame region and about 4% in the post-flame region. The model predictions are compared with experimental values of NOx missions reported elsewhere.

Siwatch, Vivek

2005-12-01T23:59:59.000Z

387

Advanced Control Technology Update: Multi-Loop Tuning and Model Predictive Control  

Science Conference Proceedings (OSTI)

This technical update provides information on two projects in the advanced control area. The first project is a study of control system tuning methods for multiple interacting proportional-integral-derivative PID control loops. The traditional method for tuning such systems, common on power plant boiler control systems, is to tune each loop in a specified sequence. An alternative method, in which all loops are tuned simultaneously, is being developed in this study and will be compared to the traditional ...

2008-03-30T23:59:59.000Z

388

Quantification of Variability and Uncertainty in Hourly NOx Emissions from Coal-Fired Power Plants  

E-Print Network (OSTI)

1 Quantification of Variability and Uncertainty in Hourly NOx Emissions from Coal-Fired Power to quantify variability and uncertainty for NOx emissions from coal-fired power plants. Data for hourly NOx Uncertainty, Variability, Emission Factors, Coal-Fired Power Plants, NOx emissions, Regression Models

Frey, H. Christopher

389

Use of Simulation To Optimize NOx Abatement by Absorption and Selective Catalytic Reduction  

E-Print Network (OSTI)

Use of Simulation To Optimize NOx Abatement by Absorption and Selective Catalytic Reduction Andrew the effect of the ammonia feed ratio on the NOx reduction efficiency for the SCR model. Optimal NOx removal NOx in an inert gas slows its absorption in the absorber and its reduction in the SCR because

Liu, Y. A.

390

Fundamental Study of Low NOx Combustion Fly Ash Utilization  

SciTech Connect

This study is principally concerned with characterizing the organic part of coal combustion fly ashes. High carbon fly ashes are becoming more common as by-products of low-NOx combustion technology, and there is need to learn more about this fraction of the fly ash. The project team consists of two universities, Brown and Princeton, and an electrical utility, New England Power. A sample suite of over forty fly ashes has been gathered from utilities across the United States, and includes ashes from a coals ranging in rank from bituminous to lignite. The characterizations of these ashes include standard tests (LOI, Foam Index), as well as more detailed characterizations of their surface areas, porosity, extractability and adsorption behavior. The ultimate goal is, by better characterizing the material, to enable broadening the range of applications for coal fly ash re-use beyond the current main market as a pozzolanic agent for concretes. The potential for high carbon-content fly ashes to substitute for activated carbons is receiving particular attention. The work performed to date has already revealed how very different the surfaces of different ashes produced by the same utility can be, with respect to polarity of the residual carbon. This can help explain the large variations in acceptability of these ashes as concrete additives.

E. M. Suubert; I. Kuloats; K. Smith; N. Sabanegh; R.H. Hurt; W. D. Lilly; Y. M. Gao

1997-05-01T23:59:59.000Z

391

APPLICATIONS THE DIESEL DeNOx  

E-Print Network (OSTI)

"footprint." LINKS TO ONLINE INFORMATION http://www.anl.gov/techtransfer/ Available_Technologies/ Material

Kemner, Ken

392

Argonne Transportation Technology News Archive  

NLE Websites -- All DOE Office Websites (Extended Search)

EGR to control NOx reaction kinetics and those from a new SunDiesel fuel derived from wood chips (made by the Choren Company in Germany using a process similar to...

393

THE DEVELOPMENT AND ON-ROAD PERFORMANCE AND DURABILITY OF THE FOUR-WAY EMISSION CONTROL SCRT{trademark} SYSTEM  

DOE Green Energy (OSTI)

legislation worldwide necessitates the development of pollution control systems capable of enabling engines to meet the incoming legislative requirements. It is clear that to maximize the benefit to the environment, as well as to meet the very stringent future standards (especially the US 2010 limits), systems capable of high simultaneous conversions of all four major pollutants, carbon monoxide (CO), hydrocarbons (HC), oxides of nitrogen (NOx) and Particulate Matter (PM), are required. Very high conversions of CO, HC and PM are achieved using catalyst-based Diesel Particulate Filter (DPF) systems, such as the Continuously Regenerating Technology, CRT{reg_sign}, system. High NOx conversions can be obtained using Selective Catalytic Reduction (SCR) systems, in which ammonia (generated from urea) is used to selectively reduce the NOx. This paper summarizes the key steps in the development of the four-way SCRT system, which comprises the CRT system followed by an SCR system. Engine bench results obtained during the development of this system are presented and discussed. However, the key to real-world emissions benefit is the actual on-road performance of such systems. It is well established that the CRT system provides very high and durable conversions of CO, HC and PM, so the focus of this current work was to demonstrate the NOx conversion capability and durability of the SCRT system. The SCRT unit was installed on a long-haul truck powered by a 15 litre Cummins engine. On-road NOx emissions performance was measured using NOx sensors located upstream and downstream of the SCRT unit. Over an 850 km evaluation route, the average on-road NOx conversion obtained was up to 82%, even when the urea injection quantity was set to give a maximum NOx conversion of around 85%. The durability of the system has also been assessed. Over the course of 150,000 km, no reduction in the NOx conversion efficiency of the system was observed. The results presented in this paper demonstrate that the SCRT system provides very high on-road NOx conversion, and that the system has excellent durability within real-world applications.

Cooper, BJ; McDonald, AC; Walker, AP; Sanchez, M

2003-08-24T23:59:59.000Z

394

Homeostatic control: economic integration of solar technologies into electric power operations and planning  

DOE Green Energy (OSTI)

The economic and technical interfaces between the electrical utility and the distributed, nondispatchable electric generation systems are only minimally understood at the present time. The economic issues associated with the interface of new energy technologies and the electric utility grid are discussed. Then the concept of Homeostatic Control is introduced and the use of such an economic concept applied to the introduction of nondispatchable technologies into the existing utility system is discussed. The transition and potential impact of a Homoeostatic Control system working with the existing electric utility system is discussed.

Tabors, R.D.

1981-07-01T23:59:59.000Z

395

Status of the Development and Assessment of Advanced NOx Catalysts  

Science Conference Proceedings (OSTI)

This is an interim report summarizing the status of EPRI's advanced nitrogen oxides (NOx) reduction catalyst development efforts in 2000. Concepts for that are more effective, lower cost, and may not have the problems associated with the standard vanadium pentoxide - titanium dioxide (V2O5-TiO2) NOx selective catalytic reduction (SCR) catalysts that have been assessed under this program. The primary efforts in 2000 included further development of an ultra-high efficiency (UHE) catalyst, determining wheth...

2000-11-27T23:59:59.000Z

396

Integrated Emissions Control - Process Review: Multi-Pollutant Control Technology Descriptions and Performance  

Science Conference Proceedings (OSTI)

A few air pollution control suppliers are developing processes that may reduce several pollutants simultaneously in a configuration that is lower in cost than the total cost of using existing devices for each pollutant. It would benefit the industry if an independent organization that is technically knowledgeable about all the components of such multi-pollutant controls evaluated the opportunities these processes offer.

2002-03-13T23:59:59.000Z

397

DOE/NETL's Mercury Control Technology R&D Program Review  

NLE Websites -- All DOE Office Websites (Extended Search)

DOE/NETL's Mercury Control Technology R&D Program Review DOE/NETL's Mercury Control Technology R&D Program Review July 14-15, 2004 Table of Contents Disclaimer Papers and Presentations Program Review Overview Sorbent Injection Research Panel Discussion: Sorbent Injection for Hg Control Mercury Control Technology R&D I Poster Session Mercury Control Technology R&D II By-Product Characterization Disclaimer This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government or any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. Reference herein to any specific commercial product, process, or service by trade name, trademark, manufacturer, or otherwise does not necessarily constitute or imply its endorsement, recommendation, or favoring by the United States Government or any agency thereof. The views and opinions of authors expressed herein do not necessarily state or reflect those of the United States Government or any agency thereof.

398

Geothermal and geopressure blowout control. Phase I. Study of existing technology. Phase II. Program plan for geothermal and geopressure blowout control  

DOE Green Energy (OSTI)

Four papers on existing technology and program planning for blowout control in geothermal and geopressured systems are included. Separate abstracts were prepared for each. (MHR)

Rehm, W.A.; Goins, W.C. Jr.

1978-11-01T23:59:59.000Z

399

NOx reduction aftertreatment system using nitrogen nonthermal plasma desorption  

Science Conference Proceedings (OSTI)

In the flue emission from an internal combustion system using diffusing combustion such as coal or oil fuel boiler, incinerator, or diesel engine, around 10% oxygen is usually included. It is difficult to reduce the NOx in the emission completely using catalysts or plasma alone because part of the NO is oxidized under an O{sub 2}-rich environment. In order to overcome these difficulties, we propose a new aftertreatment system of NOx included in the exhaust gas of the combustion system using nonthermal plasma (NTP) desorption and reduction. In this system, exchangeable adsorbent columns are equipped. As an initial step to realize such kind of aftertreatment system, the basic characteristics of the N{sub 2} NTP desorption and NOx reduction were examined experimentally using a pulse corona NTP reactor. After several adsorption/desorption processes, the amount of NOx adsorbed becomes equal to that of the NOx desorbed, that is, all the NO, was desorbed in a single desorption process. It is confirmed that the NOx complete reduction using N{sub 2} NTP desorption is possible not only for a simulated exhaust gas but for a real diesel engine gas. The effective specific energy density can be decreased down to 22 Wh/m{sup 3}.

Okubo, M.; Inoue, M.; Kuroki, T.; Yamamoto, T. [University of Osaka Prefecture, Osaka (Japan). Dept. of Mechanical Engineering

2005-08-01T23:59:59.000Z

400

DOE/NETL's Mercury Emissions Control Technology R&D Program  

NLE Websites -- All DOE Office Websites (Extended Search)

Mercury Emissions Control Mercury Emissions Control Technology R&D Program LRC and Lignite Industry Meeting August 27-28, 2002 Bismarck, ND Thomas J. Feeley, III, Product Manager Innovations for Existing Plants LigniteResearch_TJF,082702 Presentation Outline * About NETL * IEP Program * Hg Background * Hg and lignite coals * Hg Control R&D LigniteResearch_TJF,082702 About NETL LigniteResearch_TJF,082702 * One of DOE's 17 national labs * Government owned / operated * Sites in: - Pennsylvania - West Virginia - Oklahoma - Alaska * More than 1,100 federal and support contractor employees National Energy Technology Laboratory LigniteResearch_TJF,082702 Electric Power Using Coal Clean Liquid Fuels Natural Gas Coal Production Environmental Control V21 Next Generation Carbon Sequestration Exploration & Production Refining &

Note: This page contains sample records for the topic "nox control technologies" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Sequential high temperature reduction, low temperature hydrolysis for the regeneration of sulfated NOx trap catalysts  

SciTech Connect

We describe a new method that minimizes irreversible Pt sintering during the desulfation of sulfated Pt/BaO/Al2O3 lean NOx trap (LNT) catalysts. While it is known that the addition of H2O to H2 promotes desulfation, we find that the significant and irreversible Pt sintering arising from the presence of water is unavoidable. Control of precious metal sintering is considered to be one of the critical issues in the development of durable LNT catalysts. The new method described here is a sequential desulfation process: the first step is to reduce the sulfates with hydrogen only at higher temperatures to form BaS, followed by a treatment of the thus reduced sample with water at low to moderate temperatures to convert BaS to BaO and H2S. The data showed that Pt sintering was significantly inhibited due to the absence of H2O during the desulfation at high temperatures, and also demonstrates the similar NOx uptake with the desulfated sample cooperatively with H2 and H2O. Therefore, the sequential desulfation process may find applications in realistic systems to inhibit the irreversible sintering of the Pt in the lean NOx trap catalyst, leading to a longer catalyst life.

Kim, Do Heui; Kwak, Ja Hun; Wang, Xianqin; Szanyi, Janos; Peden, Charles HF

2008-07-15T23:59:59.000Z

402

Energy-efficient air pollution controls for fossil-fueled plants: Technology assessment  

SciTech Connect

The 1990 Clean Air Act Amendments require most fossil-fuel fired power plants to reduce sulfur dioxide, nitrogen oxides, and particulate emissions. While emission-control equipment is available to help most of New York State`s 91 utility units in 31 power plants comply with the new regulations, technologies currently available consume energy, increase carbon dioxide emissions, reduce operating efficiency, and may produce large amounts of solid and/or semisolid byproducts that use additional energy for processing and disposal. This report discribes several pollution-control technologies that are more energy efficient compared to traditional technologies for controlling sulfur dioxide, nitrogen oxide, and particulates, that may have application in New York State. These technologies are either in commercial use, under development, or in the demonstration phase; This report also presents operating characteristics for these technologies and discusses solutions to dispose of pollution-control system byproducts. Estimated energy consumption for emission-control systems relative to a plant`s gross generating capacity is 3 to 5 for reducing up to 90% sulfur dioxide emissions from coal-fired plants. 0.5 to 2.5% for reducing nitrogen oxide emissions by up to 80% from all fossil-fuel fired plants; and 0.5 to 1.5 % for controlling particulate emissions from oil- and coal-fired plants. While fuel switching and/or cofiring with natural gas are options to reduce emissions, these techniques are not considered in this report; the discussion is limited to fossil-fueled steam-generating plants.

Sayer, J.H.

1995-06-01T23:59:59.000Z

403

Waste Coal Fines Reburn for NOx and Mercury Emission Reduction  

SciTech Connect

Injection of coal-water slurries (CWS) made with both waste coal and bituminous coal was tested for enhanced reduction of NO{sub x} and Hg emissions at the AES Beaver Valley plant near Monaca, PA. Under this project, Breen Energy Solutions (BES) conducted field experiments on the these emission reduction technologies by mixing coal fines and/or pulverized coal, urea and water to form slurry, then injecting the slurry in the upper furnace region of a coal-fired boiler. The main focus of this project was use of waste coal fines as the carbon source; however, testing was also conducted using pulverized coal in conjunction with or instead of waste coal fines for conversion efficiency and economic comparisons. The host site for this research and development project was Unit No.2 at AES Beaver Valley cogeneration station. Unit No.2 is a 35 MW Babcock & Wilcox (B&W) front-wall fired boiler that burns eastern bituminous coal. It has low NO{sub x} burners, overfire air ports and a urea-based selective non-catalytic reduction (SNCR) system for NO{sub x} control. The back-end clean-up system includes a rotating mechanical ash particulate removal and electrostatic precipitator (ESP) and wet flue gas desulfurization (FGD) scrubber. Coal slurry injection was expected to help reduce NOx emissions in two ways: (1) Via fuel-lean reburning when the slurry is injected above the combustion zone. (2) Via enhanced SNCR reduction when urea is incorporated into the slurry. The mercury control process under research uses carbon/water slurry injection to produce reactive carbon in-situ in the upper furnace, promoting the oxidation of elemental mercury in flue gas from coal-fired power boilers. By controlling the water content of the slurry below the stoichiometric requirement for complete gasification, water activated carbon (WAC) can be generated in-situ in the upper furnace. As little as 1-2% coal/water slurry (heat input basis) can be injected and generate sufficient WAC for mercury capture. During July, August, and September 2007, BES designed, procured, installed, and tested the slurry injection system at Beaver Valley. Slurry production was performed by Penn State University using equipment that was moved from campus to the Beaver Valley site. Waste coal fines were procured from Headwaters Inc. and transported to the site in Super Sacks. In addition, bituminous coal was pulverized at Penn State and trucked to the site in 55-gallon drums. This system was operated for three weeks during August and September 2007. NO{sub x} emission data were obtained using the plant CEM system. Hg measurements were taken using EPA Method 30B (Sorbent Trap method) both downstream of the electrostatic precipitator and in the stack. Ohio Lumex Company was on site to provide rapid Hg analysis on the sorbent traps during the tests. Key results from these tests are: (1) Coal Fines reburn alone reduced NO{sub x} emissions by 0-10% with up to 4% heat input from the CWS. However, the NO{sub x} reduction was accompanied by higher CO emissions. The higher CO limited our ability to try higher reburn rates for further NO{sub x} reduction. (2) Coal Fines reburn with Urea (Carbon enhanced SNCR) decreased NO{sub x} emissions by an additional 30% compared to Urea injection only. (3) Coal slurry injection did not change Hg capture across the ESP at full load with an inlet temperature of 400-430 F. The Hg capture in the ESP averaged 40%, with or without slurry injection; low mercury particulate capture is normally expected across a higher temperature ESP because any oxidized mercury is thought to desorb from the particulate at ESP temperatures above 250 F. (4) Coal slurry injection with halogen salts added to the mixing tank increased the Hg capture in the ESP to 60%. This significant incremental mercury reduction is important to improved mercury capture with hot-side ESP operation and wherever hindrance from sulfur oxides limit mercury reduction, because the higher temperature is above sulfur oxide dew point interference.

Stephen Johnson; Chetan Chothani; Bernard Breen

2008-04-30T23:59:59.000Z

404

Editorial and Introduction of the Special Issue for the Ninth International Conference on Greenhouse Gas Control Technologies in the International Journal of Greenhouse Gas Control  

Science Conference Proceedings (OSTI)

Short one page editorial to introduce the +30 peer reviewed papers contained within the Special Issue for the Ninth International Conference on Greenhouse Gas Control Technologies in the International Journal of Greenhouse Gas Control

Dooley, James J.; Benson, Sally M.; Karimjee, Anhar; Rubin, Edward S.

2010-03-01T23:59:59.000Z

405

NREL's National Wind Technology Center provides the world's only dedicated turbine controls testing platforms.  

E-Print Network (OSTI)

NREL's National Wind Technology Center provides the world's only dedicated turbine controls testing platforms. Today's utility-scale wind turbine structures are more complex and their compo- nents more turbine designers is to capture the maximum amount of energy, with minimal structural loading, for minimal

406

Scoping Study: Surface Mount Technology and Applications in Power Electronics and Control Systems  

Science Conference Proceedings (OSTI)

The electronics packaging industry has not seen a revolution of the magnitude of surface mount technology (SMT) since the development of the printed wiring board. This study examines the rapid shift toward SMT and provides an overview of SMT applications for power electronics and controls equipment manufacturers.

1996-10-06T23:59:59.000Z

407

Diesel Emission Control -- Sulfur Effects (DECSE) Program; Phase I Interim Data Report No. 2: NO{sub x} Adsorber Catalysts  

DOE Green Energy (OSTI)

The Diesel Emission Control-Sulfur Effects (DECSE) is a joint government/industry program to determine the impact of diesel fuel sulfur levels on emission control systems whose use could lower emissions of nitrogen oxides (NOx) and particulate matter (PM) from on-highway trucks in the 2002--2004 model years. Phase 1 of the program was developed with the following objectives in mind: (1) evaluate the effects of varying the level of sulfur content in the fuel on the emission reduction performance of four emission control technologies; and (2) measure and compare the effects of up to 250 hours of aging on selected devices for multiple levels of fuel sulfur content. This interim report discusses the results of the DECSE test program that demonstrates the potential of NOx adsorber catalyst technology across the range of diesel engine operation with a fuel economy penalty less than 4%.

DOE; ORNL; NREL; EMA; MECA

1999-10-15T23:59:59.000Z

408

Technologies  

Technologies Materials. Aggregate Spray for Air Particulate; Actuators Made From Nanoporous Materials; Ceramic Filters; Energy Absorbing Material; Diode Arrays for ...

409

Technologies  

Technologies Energy. Advanced Carbon Aerogels for Energy Applications; Distributed Automated Demand Response; Electrostatic Generator/Motor; Modular Electromechanical ...

410

Technologies  

Technologies Energy, Utilities, & Power Systems. Advanced Carbon Aerogels for Energy Applications; Distributed Automated Demand Response; Electrostatic Generator/Motor

411

Technologies  

Technologies Research Tools. Cell-Free Assembly of NanoLipoprotein Particles; Chemical Prism; Lawrence Livermore Microbial Detection Array (LLMDA) ...

412

Technologies  

Science & Technology. Weapons & Complex Integration. News Center. News Center. Around the Lab. Contacts. For Reporters. Livermore Lab Report. ...

413

Environmental control technology activities of the Department of Energy in FY 1978  

DOE Green Energy (OSTI)

This second in a series of annual reports on environmental control technology activities within DOE serves as a basis for evaluating program progress. The total DOE FY 1978 funding allocation related to environmenta control activities was $294 million, which corresponds to 3.3% of the total FY 1978 budget. Funding allocations for environmental control activities in the budget show fossil and nuclear energy technologies accounting for 90% of the total (26 and 64%, respectively). The majority of the fossil-energy-related activities were related to the coal program. Waste management activities demanded the majority of the nuclear energy funds. Conservation and geothermal made up 4 and 3%, respectively, of the total. The remaining portion of the total consisted of solar (2%), basic energy sciences (1%), and magnetic fusion energy (less than 1%). (MCW)

Not Available

1979-03-01T23:59:59.000Z

414

Instrumentation, Controls, and Human-Machine Interface Technology Development Roadmap in Support of Grid Appropriate Reactors  

Science Conference Proceedings (OSTI)

Grid Appropriate Reactors (GARs) are a component of the U.S. Department of Energy s (DOE s) Global Nuclear Energy Partnership (GNEP) program. GARs have smaller output power (Instrumentation, Controls, and Human-Machine Interface (ICHMI) technology development roadmap emphasizing the specific characteristics of GARs [1]. This roadmapping effort builds upon and focuses the recently developed, more general nuclear energy ICHMI technology development roadmap [2]. The combination of the smaller plant size, smaller grids, and deployment in locations without extensive prior nuclear power experience presents particular infrastructure, regulation, design, operational, and safeguards challenges for effective GAR deployment. ICHMI technologies are central to efficient GAR operation and as such are a dimension of each of these challenges. Further, while the particular ICHMI technologies to be developed would be useful at larger power plants, they are not high-priority development items at the larger plants. For example, grid transient resilience would be a useful feature for any reactor/grid combination and indeed would have limited some recent blackout events. However, most large reactors have limited passive cooling features. Large plants with active safety response features will likely preserve trip preferential grid transient response. This contrasts sharply with GARs featuring passive shutdown cooling, which can safely support grid stability during large grid transients. ICHMI technologies ranging from alternative control algorithms to simplified human-interface system designs are key to enabling GARs to respond properly and thereby stabilize the grid during transients.

Holcomb, David Eugene [ORNL; Upadhyaya, Belle R. [University of Tennessee, Knoxville (UTK); Kisner, Roger A [ORNL; O'Hara, John [Brookhaven National Laboratory (BNL); Quinn, Edward L. [Longenecker & Associates; Miller, Don W. [Ohio State University

2009-01-01T23:59:59.000Z

415

NETL: Oil & Natural Gas Technologies Reference Shelf - Presentation  

NLE Websites -- All DOE Office Websites (Extended Search)

Mapping Study to Characterize NSCR Performance on a Natural Gas-Fueled Engine Mapping Study to Characterize NSCR Performance on a Natural Gas-Fueled Engine Mapping Study to Characterize NSCR Performance on a Natural Gas-Fueled Engine Authors: Mohamed Toema (speaker), Sarah Nuss-Warren, and Kirby S. Chapman, Kansas State University National Gas Machinery Laboratory; James McCarthy and Thomas McGrath, Innovative Environmental Solutions Inc. Venue: ASME Internal Combustion Engine Division 2009 Spring Technical Conference, May 3–6, Milwaukee, WI. http://www.asmeconferences.org/ICES09/index.cfm [external site]. Abstract: The researchers are conducting a project to characterize pollutant emissions performance of field gas-fired four-stroke cycle rich burn engines equipped with non-selective catalytic reduction (NSCR) technology. Engine emissions and operating parameters are being monitored on three engines over an extended period. In addition, a mapping study was conducted on one engine. The NSCR was operated at various controlled air-to-fuel (AF) ratios while emission measurements were conducted and engine operating parameters monitored. NOx, CO, and oxygen were measured using both EPA reference method technology and the portable analyzer used in the long-term study. In the mapping study, ammonia, formaldehyde, CO, NOx, and speciated hydrocarbon emissions were recorded in real-time using an extractive FTIR system. This paper focuses on the engine mapping phase. The mapping tests demonstrated a trade-off between NOx emissions and CO, ammonia, and hydrocarbon emissions. Richer engine operation (lower AF) decreases NOx emissions at the expense of higher CO, ammonia, and hydrocarbons. Leaner operation has the opposite effect. The results to date of the semi-continuous monitoring are presented in a separate paper.

416

Super Duty Diesel Truck with NOx Aftertreatment  

Energy.gov (U.S. Department of Energy (DOE))

A profile of a Ford-Energy Department program to develop a three-stage aftertreatment technology, which cleans the vehicle exhaust emissions.

417

U.S. Department of Energy Instrumentation and Controls Technology Research for Advanced Small Modular Reactors  

Science Conference Proceedings (OSTI)

Instrumentation, controls, and human-machine interfaces (ICHMI) are essential enabling technologies that strongly influence nuclear power plant performance and operational costs. The U.S. Department of Energy (DOE) has recognized that ICHMI research, development, and demonstration (RD&D) is needed to resolve the technical challenges that may compromise the effective and efficient utilization of modern ICHMI technology and consequently inhibit realization of the benefits offered by expanded utilization of nuclear power. Consequently, key DOE programs have substantial ICHMI RD&D elements to their respective research portfolio. This article describes current ICHMI research to support the development of advanced small modular reactors.

Wood, Richard Thomas [ORNL

2012-01-01T23:59:59.000Z

418

Communication to the 10th International Conference on Greenhouse Gas Control Technologies (GHGT 10), Amsterdam, September 19-23, 2010.  

E-Print Network (OSTI)

Communication to the 10th International Conference on Greenhouse Gas Control Technologies (GHGT 10 on Greenhouse Gas Control Technologies GHGT-10, Amsterdam : Pays-Bas (2010)" #12;2. Historical context Total. The captured gas is compressed and transported for about 30km reusing an existing natural gas pipeline. The gas

Paris-Sud XI, Université de

419

Chemical Consequences of Heme Distortion and the Role of Heme Distortion in Signal Transduction of H-NOX Proteins  

E-Print Network (OSTI)

T. tengcongensis (Tt H-NOX), the reduction potential wasdesign of Tt H-NOX to broaden the reduction potential rangewith Tt H-NOX show that the reduction potential is

Olea, Jr., Charles

2010-01-01T23:59:59.000Z

420

Establishment of an Environmental Control Technology Laboratory with a Circulating Fluidized-Bed Combustion System  

DOE Green Energy (OSTI)

On February 14, 2002, President Bush announced the Clear Skies Initiative, a legislative proposal to control the emissions of nitrogen oxides (NO{sub x}), sulfur dioxide (SO{sub 2}), and mercury from power plants. In response to this initiative, the National Energy Technology Laboratory organized a Combustion Technology University Alliance and hosted a Solid Fuel Combustion Technology Alliance Workshop. The workshop identified multi-pollutant control; improved sorbents and catalysts; mercury monitoring and capture; and improved understanding of the underlying reaction chemistry occurring during combustion as the most pressing research needs related to controlling environmental emissions from fossil-fueled power plants. The Environmental Control Technology Laboratory will help meet these challenges and offer solutions for problems associated with emissions from fossil-fueled power plants. The goal of this project was to develop the capability and technology database needed to support municipal, regional, and national electric power generating facilities to improve the efficiency of operation and solve operational and environmental problems. In order to effectively provide the scientific data and the methodologies required to address these issues, the project included the following aspects: (1) Establishing an Environmental Control Technology Laboratory using a laboratory-scale, simulated fluidized-bed combustion (FBC) system; (2) Designing, constructing, and operating a bench-scale (0.6 MW{sub th}), circulating fluidized-bed combustion (CFBC) system as the main component of the Environmental Control Technology Laboratory; (3) Developing a combustion technology for co-firing municipal solid waste (MSW), agricultural waste, and refuse-derived fuel (RDF) with high sulfur coals; (4) Developing a control strategy for gaseous emissions, including NO{sub x}, SO{sub 2}, organic compounds, and heavy metals; and (5) Developing new mercury capturing sorbents and new particulate filtration technologies. Major tasks during this period of the funded project's timeframe included: (1) Conducting pretests on a laboratory-scale simulated FBC system; (2) Completing detailed design of the bench-scale CFBC system; (3) Contracting potential bidders to fabricate of the component parts of CFBC system; (4) Assembling CFBC parts and integrating system; (5) Resolving problems identified during pretests; (6) Testing with available Powder River Basin (PRB) coal and co-firing of PRB coal with first wood pallet and then chicken wastes; and (7) Tuning of CFBC load. Following construction system and start-up of this 0.6 MW CFBC system, a variety of combustion tests using a wide range of fuels (high-sulfur coals, low-rank coals, MSW, agricultural waste, and RDF) under varying conditions were performed to analyze and monitor air pollutant emissions. Data for atmospheric pollutants and the methodologies required to reduce pollutant emissions were provided. Integration with a selective catalytic reduction (SCR) slipstream unit did mimic the effect of flue gas composition, including trace metals, on the performance of the SCR catalyst to be investigated. In addition, the following activities were also conducted: (1) Developed advanced mercury oxidant and adsorption additives; (2) Performed laboratory-scale tests on oxygen-fuel combustion and chemical looping combustion; and (3) Conducted statistical analysis of mercury emissions in a full-scale CFBC system.

Wei-Ping Pan; Yan Cao; John Smith

2008-05-31T23:59:59.000Z