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Note: This page contains sample records for the topic "nox carbon monoxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


1

Carbon Monoxide Safety Tips  

E-Print Network [OSTI]

Protect yourself and your family from the deadly effects of carbon monoxide--a colorless, odorless poisonous gas. This publication describes the warning signs of carbon monoxide exposure and includes a home safety checklist....

Shaw, Bryan W.; Garcia, Monica L.

1999-07-26T23:59:59.000Z

2

Carbon monoxide absorbing liquid  

SciTech Connect (OSTI)

The present disclosure is directed to a carbon monoxide absorbing liquid containing a cuprous ion, hydrochloric acid and titanum trichloride. Titanium trichloride is effective in increasing the carbon monoxide absorption quantity. Furthermore, titanium trichloride remarkably increases the oxygen resistance. Therefore, this absorbing liquid can be used continuously and for a long time.

Arikawa, Y.; Horigome, S.; Kanehori, K.; Katsumoto, M.

1981-07-07T23:59:59.000Z

3

SENSITIVE OPTOACOUSTIC DETECTION OF CARBON MONOXIDE BY RESONANCE ABSORPTION  

E-Print Network [OSTI]

Monoxide by Resonance Absorption Robert Gerlach and Nabil M.MONOXIDE BY RESONANCE ABSORPTION Robert Gerlach and Nabil M.the context of atmospheric absorption. The carbon monoxide

Gerlach, R.

2011-01-01T23:59:59.000Z

4

Why sequence carbon monoxide oxidizing thermophiles?  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

carbon monoxide oxidizing thermophiles? carbon monoxide oxidizing thermophiles? Many microbes that use carbon monoxide as an energy source are found in high temperature environments such as geothermal areas. Researchers think that these carboxydotrophs may be involved in reducing potentially toxic carbon monoxide hotspots by combine with water to form hydrogen, carbon dioxide and acetate, which are in turn used for thermophilic energy conservation and carbon sequestration mechanisms. The project focuses on sequencing two closely related microbes, one of which is Carboxydothermus hydrogenformans. A strain of C. hydrogenformans has been grown in hydrogen-enriched synthesis gas (syngas), which contains a mix of hydrogen and carbon monoxide. Researchers are interested in sequencing both microbial strains to track the genome's evolution and

5

Advanced Diesel Combustion with Low Hydrocarbon and Carbon Monoxide...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Combustion with Low Hydrocarbon and Carbon Monoxide Emissions Advanced Diesel Combustion with Low Hydrocarbon and Carbon Monoxide Emissions Poster presented at the 16th Directions...

6

Desorption of carbon monoxide from nickel using mercaptans  

SciTech Connect (OSTI)

An IR spectroscopic study on the displacement of carbon monoxide with 1-propyl, 2-propyl-, 1-butyl-, 2-butyl-, and tert.-butyl mercaptan from nickel foil and silica-supported nickel showed that at low carbon monoxide coverage on supported nickel, mercaptan adsorption initially converted bridged to linear carbon monoxide surface species. At higher mercaptan pressures, carbon monoxide desorbed into the gas phase. A small amount of carbon monoxide remained on the surface when the poisoned sample was evacuated, and additional carbon monoxide adsorbed when 5 mm Hg of carbon monoxide was added to the evacuated sample.

Neff, L.D.; Sturdivant, A.E.; Wallace, J.L.

1980-06-01T23:59:59.000Z

7

Enhanced carbon monoxide utilization in methanation process  

DOE Patents [OSTI]

Carbon monoxide - containing gas streams are passed over a catalyst to deposit a surface layer of active surface carbon thereon essentially without the formation of inactive coke. The active carbon is subsequently reacted with steam or hydrogen to form methane. Surprisingly, hydrogen and water vapor present in the feed gas do not adversely affect CO utilization significantly, and such hydrogen actually results in a significant increase in CO utilization.

Elek, Louis F. (Peekskill, NY); Frost, Albert C. (Congers, NY)

1984-01-01T23:59:59.000Z

8

Carbon Monoxide Concentration Trends in Urban Atmospheres  

Science Journals Connector (OSTI)

...BOVE, J.L., AIRBORNE LEAD AND CARBON MONOXIDE...various procedures that release transmitter has been...conclusion for trans-mitter release. He also provided evidence...suburban counties, a larger fraction of the gasoline is undoubtedly...in the huts (indoor fires are used for space heating...

Merril Eisenbud; Laurel R. Ehrlich

1972-04-14T23:59:59.000Z

9

Isotopic equilibration of carbon monoxide catalyzed by supported ruthenium  

SciTech Connect (OSTI)

Isotopic equilibration of carbon monoxide catalyzed by supported ruthenium was studied with oxygen-18 and carbon-13 labeled carbon monoxide in the presence and absence of hydrogen. The results showed that carbon monoxide was present on commercial alumina-supported ruthenium in a reactive undissociated form at 373/sup 0/K; that it adsorbed as a single carbonyl and in a geminal dicarbonyl form; and that hydrogen inhibited the exchange reaction by competitive adsorption and by stabilizing the carbonyl bond. The results elucidate the carbon monoxide methanation and Fischer-Tropsch reactions on this catalyst.

Bossi, A. (Cent. Ric. Novara); Zanderighi, L.; Carnisio, G.; Garbassi, F.; Giunchi, G.; Petrini, G.

1980-09-01T23:59:59.000Z

10

Advanced Diesel Combustion with Low Hydrocarbon and Carbon Monoxide...  

Broader source: Energy.gov (indexed) [DOE]

Combustion with Low Hydrocarbon and Carbon Monoxide Emissions Poster Location P-19 Gregory K. Lilik, Andr L. Boehman Department of Energy & Mineral Engineering EMS Energy...

11

Mechanistical studies on the formation of carbon dioxide in extraterrestrial carbon monoxide ice analog samples  

E-Print Network [OSTI]

be produced via radiolysis of carbon monoxide ices.5 Indeed, the effects of ionizing radiation on pure carbonMechanistical studies on the formation of carbon dioxide in extraterrestrial carbon monoxide ice901220f Binary ice mixtures of two carbon monoxide isotopomers, 13 C16 O and 12 C18 O, were subjected

Kaiser, Ralf I.

12

CO (Carbon Monoxide Mixing Ratio System) Handbook  

SciTech Connect (OSTI)

The main function of the CO instrument is to provide continuous accurate measurements of carbon monoxide mixing ratio at the ARM SGP Central Facility (CF) 60-meter tower (36.607 °N, 97.489 °W, 314 meters above sea level). The essential feature of the control and data acquisition system is to record signals from a Thermo Electron 48C and periodically calibrate out zero and span drifts in the instrument using the combination of a CO scrubber and two concentrations of span gas (100 and 300 ppb CO in air). The system was deployed on May 25, 2005.

Biraud, S

2011-02-23T23:59:59.000Z

13

Reducing NOx in Fired Heaters and Boilers  

E-Print Network [OSTI]

-6, 2000 Reducing NOx in Fired Heaters Air Pollution Control and Boilers Keeping the environment clean Presented by Ashutosh Garg Furnace Improvements Low cost solutions for fired heaters Trace compounds ? Nitric oxides ? Carbon monoxide ? Sulfur... it is essential to estimate accurately baseline NOx emissions. ? This will establish each units current compliance status. ? Emissions ? Current excess air level ? Carbon monoxide ? Combustibles ? NOx corrected to 3% 02 314 ESL-IE-00-04-46 Proceedings...

Garg, A.

14

The Catalysis of the Carbon Monoxide-Steam Reaction  

Science Journals Connector (OSTI)

...The Catalysis of the Carbon Monoxide-Steam Reaction F. J. Long K. W. Sykes The kinetics of the carbon monoxide-steam reaction occurring heterogeneously at...nearly unity, while that with respect to steam is correspondingly lowered; a slight...

1952-01-01T23:59:59.000Z

15

E-Print Network 3.0 - ambient carbon monoxide Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

FACT SHEET Carbon monoxide (CO), known as the Invisible Killer... , propane, oil, wood, coal, and gasoline. Exposure to carbon monoxide can cause flu-like symptoms and can... .)...

16

Carbon and carbon monoxide hydrogenation on nickel: support effects  

SciTech Connect (OSTI)

Hydrogenation of carbon, deposited on nickel catalysts by CO disproportionation, was investigated by temperature-programmed surface reaction (TPSR) for four oxide supports, alumina (Al/sub 2/O/sub 3/), silica (SiO/sub 2/), titanium oxide (TiO/sub 2/), and SiO/sub 2/.Al/sub 2/O/sub 3/. The rate of carbon monoxide hydrogenation was measured by temperature-programmed reaction (TPR) for comparison. The rate of carbon hydrogenation to methane was found to be independent of the support and an average activation energy of 42 kJ/mol was estimated. In contrast, the rate of carbon monoxide hydrogenation was very sensitive to the catalyst support. Nickel (Ni) supported on TiO/sub 2/ exhibited the highest specific activity, and two distinct sites for methanation were observed on Ni/TiO/sub 2/ and Ni/Al/sub 2/O/sub 3/. The lowest specific activities were observed for Ni/SiO/sub 2/ and Ni/SiO/sub 2/.Al/sub 2/O/sub 3/. For all catalysts, carbon hydrogenation occurred at a lower temperature than carbon monoxide hydrogenation. For both TPR and TPSR, small amounts of ethane were formed and at a lower temperature than methane. The amount of less-active, ..beta..-carbon observed in TPSR experiments was very small on all catalysts. These results indicate that at high coverages, carbon hydrogenation does not depend on the support, and thus it is not rate-determining for CO hydrogenation in excess hydrogen. The support is also shown to change the specific rate of carbon monoxide methanation; activity differences seen in steady-state experiments are not just due to differences in site densities. 5 figures, 5 tables.

Ozdogan, S.Z.; Gochis, P.D.; Falconer, J.L.

1983-10-01T23:59:59.000Z

17

Process for producing carbon monoxide and hydrogen from methanol  

SciTech Connect (OSTI)

A process is described for producing carbon monoxide and hydrogen which comprises contacting methanol vapor at a temperature of 200 degrees to 300 degrees C with an indirectly heated zinc containing catalyst to obtain an effluent gas in which the components of carbon monoxide and hydrogen constitute at least 90% by volume of said gas. At least a part of the impurities from said effluent gas are removed and said effluent gas is deparated into its carbon monoxide and hydrogen components by adsorption. The effluent gas can be separated into its carbon monoxide and hydrogen components by use of a plurality of adsorbers containing zeolite-type molecular sieve material where the zeolite is substantially permeable to hydrogen but sorbs carbon monoxide.

Jockel, H.; Marschner, F.; Moller, F.W.; Mortel, H.

1982-02-23T23:59:59.000Z

18

Carbon monoxide exposure of subjects with documented cardiac arrhythmias  

SciTech Connect (OSTI)

The impact of low-level carbon monoxide exposure on ventricular arrhythmia frequency in patients with ischemic heart disease has not been thoroughly studied. The issue is of concern because of the potential proarrhythmic effect of carbon monoxide in patients with ischemic heart disease. We studied 30 subjects with well-documented coronary artery disease who had an average of at least 30 ventricular ectopic beats per hour over a 20-hour monitoring interval. By using appropriate inclusion and exclusion criteria, subjects were selected and enrolled in a randomized double-blind study to determine the effects of carbon monoxide exposure on ventricular arrhythmia frequency at rest, during exercise, and during ambulatory activities. The carbon monoxide exposure was designed to result in 3% or 5% carboxyhemoglobin levels, as measured by gas chromatography. The carbon monoxide exposure protocol produced target levels in 60 minutes, and the levels were maintained for an additional 90 minutes to provide adequate time to assess the impact of carbon monoxide on the frequency of ventricular ectopic beats. The data on total and repetitive ventricular arrhythmias were analyzed for seven specific time intervals: (1) two hours before carbon monoxide exposure; (2) during the two-hour carbon monoxide or air exposure; (3) during a two-hour rest period; (4) during an exercise period; (5) during an exercise recovery period; (6) six hours after carbon monoxide or air exposure; and (7) approximately 10 hours after exposure, or the remaining recording interval on the Holter monitor. There was no increase in ventricular arrhythmia frequency after carbon monoxide exposure, regardless of the level of carboxyhemoglobin or the type of activity.

Chaitman, B.R.; Dahms, T.E.; Byers, S.; Carroll, L.W.; Younis, L.T.; Wiens, R.D. (St. Louis Univ. School of Medicine, MO (United States))

1992-09-01T23:59:59.000Z

19

Comparison of Three CarbonComparison of Three Carbon Monoxide Databases in ConnecticutMonoxide Databases in Connecticut  

E-Print Network [OSTI]

Comparison of Three CarbonComparison of Three Carbon Monoxide Databases in ConnecticutMonoxide Databases in Connecticut Brian Toal, MSPHBrian Toal, MSPH Patricia Miskell, MPHPatricia Miskell, MPH Connecticut Department of Public HealthConnecticut Department of Public Health Environmental & Occupational

20

Reduction of Carbon Monoxide. Past Research Summary  

DOE R&D Accomplishments [OSTI]

Research programs for the year on the preparation, characterization, and reactions of binuclear tantalum complexes are described. All evidence to date suggest the following of these dimeric molecules: (1) the dimer does not break into monomers under mild conditions; (2) intermolecular hydride exchange is not negligible, but it is slow; (3) intermolecular non-ionic halide exchange is fast; (4) the ends of the dimers can rotate partially with respect to one another. The binuclear tantalum hydride complexes were found to react with carbon monoxide to give a molecule which is the only example of reduction of CO by a transition metal hydride to give a complex containing a CHO ligand. Isonitrides also reacted in a similar manner with dimeric tantalum hydride. (ATT)

Schrock, R. R.

1982-00-00T23:59:59.000Z

Note: This page contains sample records for the topic "nox carbon monoxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Carbon monoxide sensor and method of use thereof  

DOE Patents [OSTI]

Carbon monoxide sensors suitable for use in hydrogen feed streams and methods of use thereof are disclosed. The sensors are palladium metal/insulator/semiconductor (Pd-MIS) sensors which may possess a gate metal layer having uniform, Type 1, or non-uniform, Type 2, film morphology. Type 1 sensors display an increased sensor response in the presence of carbon monoxide while Type 2 sensors display a decreased response to carbon monoxide. The methods and sensors disclosed herein are particularly suitable for use in proton exchange membrane fuel cells (PEMFCs).

McDaniel; Anthony H. (Livermore, CA), Medlin; J. Will (Boulder, CO), Bastasz; Robert J. (Livermore, CA)

2007-09-04T23:59:59.000Z

22

Nickel and iron EXAFS of carbon monoxide dehydrogenase from Clostridium thermoaceticum strain DSM  

Science Journals Connector (OSTI)

Nickel and iron EXAFS of carbon monoxide dehydrogenase from Clostridium thermoaceticum strain DSM ...

Neil R. Bastian; Gabriele. Diekert; Eric C. Niederhoffer; Boon Keng. Teo; Christopher T. Walsh; William H. Orme-Johnson

1988-08-01T23:59:59.000Z

23

Carbon monoxide-assisted growth of carbon nanotubes Y.H. Tang a,b  

E-Print Network [OSTI]

Carbon monoxide-assisted growth of carbon nanotubes Y.H. Tang a,b , Y.F. Zheng a , C.S. Lee a , N was used to synthesize carbon nanotubes (CNTs) in a hot-®lament chemical vapor deposition (HFCVD) system in the formation of multi-walled carbon nanotubes (MWNT)s. The CNTs synthesized from carbon monoxide validate

Zheng, Yufeng

24

Carbon Monoxide Poisoning Avoided Through Weatherization | Department of  

Broader source: Energy.gov (indexed) [DOE]

Carbon Monoxide Poisoning Avoided Through Weatherization Carbon Monoxide Poisoning Avoided Through Weatherization Carbon Monoxide Poisoning Avoided Through Weatherization October 5, 2010 - 10:56am Addthis Joshua DeLung What does this mean for me? Getting your heating pipes fixed can not only save you money, but also improve your health. "If we'd had a couple cold nights where I would've had to use my heat more than usual, it probably would've put me to sleep and left me there -- it was just too much carbon monoxide coming out in the house," says Mark Pickartz, of Van Buren, Ark. Pickartz's home was weatherized in February by his local community action agency, Crawford-Sebastian Community Development Council (C-SCDC). When energy auditors arrived to his house, they found that his home's heater was severely leaking the poisonous gas. C-SCDC, based in Fort Smith, Ark.,

25

Carbon Monoxide Toxicity after Lighting Coals at a Hookah Bar  

Science Journals Connector (OSTI)

Unintentional non-fire-related (UNFR) carbon monoxide (CO) poisonings continue to account for a significant health and economic burden in the United States. While most of these poisonings are related to faulty...

Ryan Misek; Christine Patte

2014-09-01T23:59:59.000Z

26

Carbon monoxide-silicon carbide interaction in HTGR fuel particles  

Science Journals Connector (OSTI)

The corrosion of the coating-layers of silicon carbide (SiC) by carbon monoxide (CO) was observed in irradiated Triso-coated uranium dioxide particles, used in high-temperature gas-cooled reactors, by optical ...

Kazuo Minato; Toru Ogawa; Satoru Kashimura; Kousaku Fukuda…

1991-05-01T23:59:59.000Z

27

Titanium dioxide based high temperature carbon monoxide selective sensor  

E-Print Network [OSTI]

Titanium dioxide based high temperature carbon monoxide selective sensor Nancy O. Savagea , Sheikh as a trap for the oxidation products of CO and CH4. Upon oxidation of CO on ALC, carbonate species were detected, whereas the reaction of CH4 produced negligible carbonate species. The insensitivity of the ALC

Dutta, Prabir K.

28

Determination of the atherogenic potential of inhaled carbon monoxide  

SciTech Connect (OSTI)

he effects of chronic exposure to moderate levels of carbon monoxide upon the augmentation of arteriosclerotic plaque development were investigated in a series of in vivo studies in the cockerel (young rooster). This animal model has been well characterized, especially regarding the role of environmental agents in exacerbating early stages of plaque development. Cockerels injected with subtumorigenic doses of carcinogens exhibit markedly accelerated development of aortic arteriosclerotic plaques. Inhalation of mainstream smoke from two packs of cigarettes (100 minutes/day for 16 weeks) causes small but statistically significant increases in plaque size. As is the case with many animal models of plaque development, raised fat-proliferative plaques also appear in these animals following cholesterol feeding. Carbon monoxide is a ubiquitous pollutant in urban environments, where it is derived largely from mobile sources and cigarette smoke. Exposure to chronically elevated carbon monoxide levels has been implicated in a number of health-related problems. Whether such exposure plays a role in the development of arteriosclerosis has not been determined conclusively. In the present study, three questions were posed: 1. Will inhaled carbon monoxide at levels of 50 to 200 parts per million (ppm)* (two hours/day for 16 weeks) be sufficient to augment arteriosclerotic plaque development in cockerels, in the absence of other plaque-promoting agents 2. Will the inhalation of 100 ppm carbon monoxide (two hours/day for 16 weeks), concomitant with the feeding of low levels (0.1%) of cholesterol, yield larger plaques than those obtained with either of these agents administered alone 3. Will inhalation of 100 ppm carbon monoxide (two hours/day for 11 or 22 weeks), by cockerels in whom plaques have already appeared, further augment plaque development Cockerels were exposed to carefully regulated levels of carbon monoxide in stainless-steel and Plexiglas dynamic exposure chambers.

Penn, A. (New York Univ. Medical Center, NY (United States))

1993-05-01T23:59:59.000Z

29

Carbon Monoxide, Ozone, Hydrocarbon Air Quality Standards, and Related  

Broader source: Energy.gov (indexed) [DOE]

Monoxide, Ozone, Hydrocarbon Air Quality Standards, and Monoxide, Ozone, Hydrocarbon Air Quality Standards, and Related Emission Requirements (Ohio) Carbon Monoxide, Ozone, Hydrocarbon Air Quality Standards, and Related Emission Requirements (Ohio) < Back Eligibility Agricultural Commercial Construction Fuel Distributor Industrial Institutional Investor-Owned Utility Local Government Municipal/Public Utility Rural Electric Cooperative State/Provincial Govt Transportation Tribal Government Utility Savings Category Buying & Making Electricity Program Info State Ohio Program Type Environmental Regulations Provider Ohio Environmental Protection Agency This chapter defining the roles of the Ohio Environmental Protection Agency gives specific detail on the regulation point-source air pollution for a variety of industries and pollutants.

30

Disproportionation of carbon monoxide on supported nickel catalysts  

SciTech Connect (OSTI)

The disproportionation of carbon monoxide was investigated mainly on a 5.5% Ni/Al/sub 2/O/sub 3/ catalyst by infrared spectroscopy and temperature-programmed desorption. The reaction was found to be of first order with respect to the surface concentration of CO below 200/sup 0/C, while at 450/sup 0/C the reaction proceeded as a second order reaction for the pressure of CO. Results obtained with predeposited carbon indicated that the disproportionation reaction requires an ensemble of several nickel atoms. In agreement with this result, the disproportionation did not take place readily on a 1.1% Ni/Al/sub 2/O/sub 3/ catalyst on which a high dispersion of the metal was indicated by both infrared spectroscopy and the chemisorption of hydrogen. In the temperature-programmed desorption (TPD) carbon monoxide desorbed in a single peak before 300/sup 0/C. Some of the carbon monoxide, however, underwent disproportionation during TPD and a carbon dioxide peak appeared at about 220/sup 0/C. Furthermore, carbon thus deposited on the surface was oxidized to carbon monoxide by oxygen supplied from the catalysts and gave a second peak of CO in TPD at temperatures higher than 300/sup 0/C. Possible sources of the oxygen were discussed.

Galuszka, J.; Chang, J.R.; Amenomiya, Y.

1981-03-01T23:59:59.000Z

31

E-Print Network 3.0 - acute carbon monoxide Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

28, 2007 Summary: OSHAReproToxin AcutelyHazardousWaste Carbon monoxide CalOSHAReproToxin Carbon Tetrachloride IARC-2BNTP Carbonic... toxins, biotoxins and acutely toxic...

32

Kinetic model of catalytic oxidation of carbon monoxide on nickel  

SciTech Connect (OSTI)

A mechanism is proposed for describing the previous disclosed multiplicity of equilibrium states in the oxidation of carbon monoxide on metallic nickel. In contrast to the known mechanism for oxidation of CO on platinum metals it includes a nonlinear stage of carbon monoxide adsorption and a linear stage of oxygen adsorption. A kinetic model has been obtained and stage velocity constants have been found, providing a basis for obtaining a quantitative agreement between the calculated and experimental relations between the reaction velocity and the reagent concentrations. Opinions are stated in relation to the causes for evolution of the CO oxidation reaction from platinum metals to nickel.

Pyatnitskii, Yu.I.; Ostapyuk, V.A.

1986-07-01T23:59:59.000Z

33

Terpolymerization of ethylene, sulfur dioxide and carbon monoxide  

DOE Patents [OSTI]

This invention relates to a high molecular weight terpolymer of ethylene, sulfur dioxide and carbon monoxide stable to 280.degree. C. and containing as little as 36 mol % ethylene and about 41-51 mol % sulfur dioxide; and to the method of producing said terpolymer by irradiation of a liquid and gaseous mixture of ethylene, sulfur dioxide and carbon monoxide by means of Co-60 gamma rays or an electron beam, at a temperature of about 10.degree.-50.degree. C., and at a pressure of about 140 to 680 atmospheres, to initiate polymerization.

Johnson, Richard (Shirley, NY); Steinberg, Meyer (Huntington Station, NY)

1981-01-01T23:59:59.000Z

34

Photobiogeochemical cycling of carbon monoxide in the southeastern Beaufort Sea in spring and autumn  

E-Print Network [OSTI]

Photobiogeochemical cycling of carbon monoxide in the southeastern Beaufort Sea in spring the distribution, photoproduction, microbial uptake, and air­sea exchange of carbon monoxide (CO), a key that in warmer seas. Carbon monoxide (CO) is the dominant sink for hydroxyl radicals in the troposphere, thus

Vincent, Warwick F.

35

Infrared spectra of carbon monoxide adsorbed on palladium black  

SciTech Connect (OSTI)

The authors investigate the heterogeneous adsorption of carbon monoxide and the concurrent catalytic and sorptive properties of palladium black from the standpoint of a comprehensive analysis of the infrared spectra of the reaction pathways and their various products as well as the pressure dependence of the line behavior at various wavelengths.

Vozdvizhenskii, V.F.; Levintova, T.D.; Sokol'skii, D.V.

1986-06-01T23:59:59.000Z

36

Catalytic activation of carbon monoxide on metal surfaces  

SciTech Connect (OSTI)

In discussing the important basic aspects of carbon monoxide chemistry, this review covers the adsorption and reaction of CO with H/sub 2/O and H/sub 2/ on reduced metal surfaces. Carbon monoxide adsorption of the Group VIII metals exhibits certain patterns. Typically, as coverages exceed one-half, compression occurs in the monolayer and the molecules lose registry with the surface metal atoms. Particular sites associated with rough surfaces facilitate CO dissociation to the surface carbon; these sites may have a significant effect on selectivity in the CO hydrogenation reaction. The support used and the metal crystallite size both affect the catalyst activity and product selectivity. Indications are strong that a better knowledge of metal-support interactions combined with a more complete understanding of the surface chemistry involved will lead to improved catalyst systems in the future.

Vannice, M.A.

1982-01-01T23:59:59.000Z

37

Catalyst for the methanation of carbon monoxide in sour gas  

DOE Patents [OSTI]

The invention involves the synergistic effect of the specific catalytic constituents on a specific series of carriers for the methanation of carbon monoxide in the presence of sulfur at relatively high temperatures and at low steam to gas ratios in the range of 0.2:1 or less. This effect was obtained with catalysts comprising the mixed sulfides and oxides of nickel and chromium supported on carriers comprising magnesium aluminate and magnesium silicate. Conversion of carbon monoxide to methane was in the range of from 40 to 80%. Tests of this combination of metal oxides and sulfides on other carriers and tests of other metal oxides and sulfides on the same carrier produced a much lower level of conversion.

Kustes, William A. (Louisville, KY); Hausberger, Arthur L. (Louisville, KY)

1985-01-01T23:59:59.000Z

38

INFRARED ABSORPTION SPECTROSCOPY OF CARBON MONOXIDE ON NICKEL FILMS: A LOW TEMPERATURE THERMAL DETECTION TECHNIQUE  

E-Print Network [OSTI]

A. B. Optical System Absorption Signal C. Small SignalNoise . Sensitivity of Absorption Spectroscopy EXPERIMENTSINFRARED ABSORPTION SPECTROSCOPY OF CARBON MONOXIDE ON

Bailey, Robert Brian

2011-01-01T23:59:59.000Z

39

Carbon Monoxide Oxidation by Bacteria Associated with the Roots of Freshwater Macrophytes  

Science Journals Connector (OSTI)

...consumption and production of atmospheric carbon monoxide by...the consumption of atmospheric carbon monoxide by...rapid oxidation of atmospheric CO to CO2 by soils...D. Influence of water table on carbon dioxide...rice fields and biogas generators: CH4, N2O, CO...

Jeremy J. Rich; G. M. King

1998-12-01T23:59:59.000Z

40

Population based exposure assessment methodology for carbon monoxide: Development of a Carbon Monoxide Passive Sampler and Occupational Dosimeter  

E-Print Network [OSTI]

Monoxide Poisoning from Propane- Fueled Forklifts." JournalMonoxide Poisoning from Propane- Fueled Fotklifts" Journalto the Indoor Use of Propane-Fueled Forklifts in Colorado

Apte, Michael G.

2010-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "nox carbon monoxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Removal of carbon monoxide. Physical adsorption on natural and synthetic zeolites  

SciTech Connect (OSTI)

The utilization of natural zeolite materials in the elimination of polluting gases is investigated. Carbon monoxide pollution is emphasized because its concentration may reach dangerous levels in places such as vehicle tunnels, underground parking lots, etc. The elimination of carbon monoxide is also of interest in some industrial processes relating to the production of pure gases.

Alfani, F.; Greco, G. Jr.; Iroio, G.

1982-07-01T23:59:59.000Z

42

Submitted to the Annals of Applied Statistics INTERPOLATING FIELDS OF CARBON MONOXIDE  

E-Print Network [OSTI]

and transport. CO AMS 2000 subject classifications: Carbon monoxide; satellite data; Bayesian hierarchi- cal models; interpolation; data assimilation 1 imsart-aoas ver. 2007/04/13 file: COpaper.tex date: March 24Submitted to the Annals of Applied Statistics INTERPOLATING FIELDS OF CARBON MONOXIDE DATA USING

Nychka, Douglas

43

Interaction of carbon monoxide with supported platinum catalysts  

SciTech Connect (OSTI)

The interaction of carbon monoxide with Pt/..gamma..-Al/sub 2/O/sub 3/ containing 0.5-5% Pt by weight has been investigated by means of thermal desorption and IR spectroscopy. It has been shown that CO is adsorbed in three different forms, corresponding to the desorption temperature intervals 25-250/sup 0/C (I), and 250-700/sup 0/C (II), and 550-850/sup 0/C (III). In the adsorption of CO in the first two forms, the metal takes part (absorption band at 2080 cm/sup -1/), and also the support (1800, 1260, 1390, 1470, 1550, and 1640 cm/sup -1/). The adsorption in form III probably takes place on oxidized platinum centers with the formation of strong surface carbonate structures. High temperatures tend to increase the adsorption of CO in forms II and III.

Savel'eva, G.A.; Galeev, T.K.; Popova, N.M.; Vozdvizhenskii, V.F.; Mishchenko, V.M.

1982-04-01T23:59:59.000Z

44

Indoor air pollutants from unvented kerosene heater emissions in mobile homes: studies on particles, semivolatile organics, carbon monoxide, and mutagenicity  

Science Journals Connector (OSTI)

Indoor air pollutants from unvented kerosene heater emissions in mobile homes: studies on particles, semivolatile organics, carbon monoxide, and mutagenicity ...

Judy L. Mumford; Ron W. Williams; Debra B. Walsh; Robert M. Burton; David J. Svendsgaard; Jane C. Chuang; Virginia S. Houk; Joellen Lewtas

1991-10-01T23:59:59.000Z

45

Some observations on the kinetics of the hydrogenation of carbon monoxide  

SciTech Connect (OSTI)

For the hydrogenation of CO a positive order of hydrogen and a slightly negative or a zero order in carbon monoxide are generally reported. The negative (or zero) order in carbon monoxide is often explained by assuming a strong adsorption of carbon monoxide on the same sites as used by the hydrogen. It is then assumed that the surface is ''almost totally'' covered by carbon monoxide. From experiments in which the surface products on an unsupported cobalt catalyst after the reaction were stripped off by a hydrogen treatment it was concluded that more than 95% of the surface (as determined from the adsorption of carbon monoxide at room temperature) was covered by carbon-containing species. This paper illustrates that ''zero order in carbon monoxide'' can be obtained with much lower coverage of carbon-containing species in equilibrium with gas-phase carbon monoxide than indicated above. Equations for reaction rates are presented, and data is calculated on the fraction of the catalyst surface covered by active carbon-containing species when the reaction is zero order in CO. The results suggest that only a small fraction of the catalyst surface is actively engaged in the hydrogenation of CO. This further suggests that the low turnover frequencies found for the Fischer-Tropsch synthesis could be caused by a small number of sites which are active in the rate-determining step. (MWF)

Rautavuoma, A.O.I.; van der Baan, H.S.

1981-10-01T23:59:59.000Z

46

Influence of the electrode material on carbon monoxide adsorption and electroreduction in aqueous solutions  

SciTech Connect (OSTI)

Carbon monoxide electroreduction was studied at rotating disk electrodes made of different materials (Cu, Au, Zn, Cd; amalgamated Cu; Al, Ga, In, glassy carbon, Sn, Pb, Mo, Fe, Ni, and certain binary systems). Positive partial currents which are evidence for a direct electroreduction of CO have been observed only at Zn, Ga, and Cd. The observation that CO is less susceptible to electroreduction than carbon dioxide is explained by the stronger chemisorption of carbon monoxide on the electrodes.

Osetrova, N.V.; Vasil'ev, Yu.B.

1987-12-01T23:59:59.000Z

47

Reduction of carbon monoxide emissions with regenerative thermal oxidizers  

SciTech Connect (OSTI)

Regenerative thermal oxidizers (RTOs) have been extensively used for the control of volatile organic compound (VOC) emissions from various sources. However, very little information is available on the ability of RTOs to control carbon monoxide (CO) emissions. This paper presents the results of extensive tests conducted on two RTOs to determine their VOC and CO control efficiencies. The inlet gas stream to the RTOs includes VOC and CO concentrations as high as 2,000 ppm and 3,600 ppm, respectfully. The testing demonstrated that both RTOs were capable of controlling greater than 98% of both inlet VOCs and CO. While the destruction efficiencies within the combustion chambers exceeded 99.9%, direct leakage past valves accounted for the lower control efficiencies. The tests indicated that the overall VOC and CO control efficiencies of the RTOs may be limited by valve leakage. The design and permitting of a RTO should include conservative control estimates which account for possible valve leakage.

Firmin, S.M.; Lipke, S.; Baturay, A.

1996-09-01T23:59:59.000Z

48

Crystallographic Snapshots of Cyanide- and Water-Bound C-Clusters from Bifunctional Carbon Monoxide Dehydrogenase/Acetyl-CoA Synthase  

E-Print Network [OSTI]

Nickel-containing carbon monoxide dehydrogenases (CODHs) reversibly catalyze the oxidation of carbon monoxide to carbon dioxide and are of vital importance in the global carbon cycle. The unusual catalytic CODH C-cluster ...

Kung, Yan

49

Role of Microorganisms in the Consumption and Production of Atmospheric Carbon Monoxide by Soil  

Science Journals Connector (OSTI)

...Winzer. 1932. Uber die Bildung von Essigsaure bei der biologischen Umsetzung von Kohlenoxyd und Kohlensaure mit Wasserstoff zu Methan. Biochem. Z. 245:2-12. 14. Fuchs, G., U. Schnitker, and R. K. Thauer. 1974. Carbon monoxide...

Ralf Conrad; Wolfgang Seiler

1980-09-01T23:59:59.000Z

50

Production of carbon monoxide-free hydrogen and helium from a high-purity source  

DOE Patents [OSTI]

The invention provides vacuum swing adsorption processes that produce an essentially carbon monoxide-free hydrogen or helium gas stream from, respectively, a high-purity (e.g., pipeline grade) hydrogen or helium gas stream using one or two adsorber beds. By using physical adsorbents with high heats of nitrogen adsorption, intermediate heats of carbon monoxide adsorption, and low heats of hydrogen and helium adsorption, and by using vacuum purging and high feed stream pressures (e.g., pressures of as high as around 1,000 bar), pipeline grade hydrogen or helium can purified to produce essentially carbon monoxide -free hydrogen and helium, or carbon monoxide, nitrogen, and methane-free hydrogen and helium.

Golden, Timothy Christopher (Allentown, PA); Farris, Thomas Stephen (Bethlehem, PA)

2008-11-18T23:59:59.000Z

51

Quantum cascade laser-based carbon monoxide detection on a second time scale from human breath  

Science Journals Connector (OSTI)

We present three different detection schemes for measuring carbon monoxide (CO) in direct absorption using a thermoelectrically cooled, distributed-feedback pulsed quantum cascade (qc) laser operating between 217...

B.W.M. Moeskops; H. Naus; S.M. Cristescu; F.J.M. Harren

2006-03-01T23:59:59.000Z

52

Continuous Measurement of Carbon Monoxide Improves Combustion Efficiency of CO Boilers  

E-Print Network [OSTI]

CONTINUOUS MEASUREMENT OF CARBON MONOXIDE IMPROVES COMBUSTION EFFICIENCY OF CO BOILERS Russell L. Branham ana James J. Prichard Ashland Oil Company Catlettsburg, KY ABSTRACT The paper describes the application of in-situ flue gas CO... measurement in the operation of CO Boilers and details the steps needed to optimize combustion efficiency. INTRODUCTION In the petroleum industry, the efficient operation of a fluid-cata1ytic-cracking unit, produces gases rich in carbon monoxide...

Gilmour, W. A.; Pregler, D. N.; Branham, R. L.; Prichard, J. J.

1981-01-01T23:59:59.000Z

53

Reformer-pressure swing adsorption process for the production of carbon monoxide  

SciTech Connect (OSTI)

An improved process for the production of carbon monoxide by the steam reforming of hydrocarbons is described comprising: (a) catalytically reacting a fluid hydrocarbon feed stream with steam in a steam reformer; (b) passing the reformer effluent containing hydrogen, carbon monoxide and carbon dioxide from the steam reformer, without scrubbing to remove the carbon dioxide content thereof, to a pressure swing adsorption system having at least four adsorbent beds, each bed of which, on a cyclic basis, undergoes a processing sequence; (c) recycling the carbon dioxide-rich stream to the steam reformer for reaction with additional quantities of the hydrocarbon feed stream being passed to the stream reformer to form additional quantities of carbon monoxide and hydrogen, with product recovery being enhanced and the need for employing a carbon dioxide wash system being obviated.

Fuderer, A.

1988-02-23T23:59:59.000Z

54

Analysis of black carbon and carbon monoxide observed over the Indian Ocean: Implications for emissions and photochemistry  

E-Print Network [OSTI]

and known emission factors for black carbon (BC) from South Asia yields 0.7 Tg yrÃ?1 (upper limit of about 1 Global Change: Atmosphere (0315, 0325); KEYWORDS: Soot, black carbon, CO, emissions, India Citation of black carbon and carbon monoxide observed over the Indian Ocean: Implications for emissions

Dickerson, Russell R.

55

Coadsorption of hydrogen and ethylene, and carbon monoxide and ethylene on the Ru(001) surface  

SciTech Connect (OSTI)

A detailed investigation of the coadsorption of ethylene with both preadsorbed hydrogen and preadsorbed carbon monoxide on the Ru(001) surface is reported here. Both preadsorbed hydrogen and carbon monoxide reduce the saturation coverage of subsequently chemisorbed ethylene. The coadsorption of hydrogen with ethylene results in detectable hydrogenation of ethylene to ethane below 250 K, whereas no self-hydrogenation of ethylene to ethane is observed. High-resolution electron energy loss spectra show that ethylene coadsorbed with either hydrogen or carbon monoxide decomposes to ethylidyne (CCH/sub 3/) and acetylide (CCH), as it does on the clean surface. Carbon monoxide preadsorption enhances the stability of the ethylidyne such that it decomposes at approximately 420 K, rather than 355 K as on the initially clean Ru(001) surface. Preadsorbed carbon monoxide also reduces the ratio of ethylidyne to acetylide that is formed from ethylene, compared to the ratio observed from an equivalent coverage of ethylene on the clean surface; hydrogen preadsorption, on the other hand, increases this ratio.

Hills, M.M.; Parmeter, J.E.; Weinberg, W.H.

1986-11-12T23:59:59.000Z

56

Carbon monoxide annealed TiO2 nanotube array electrodes for efficient biosensor applications  

E-Print Network [OSTI]

Carbon monoxide annealed TiO2 nanotube array electrodes for efficient biosensor applications by anodic oxidation of titanium foil followed with O2 and CO annealing were employed as matrices consisted of Ti3+ defects with carbon-doping and exhibited well defined quasi-reversible cyclic voltammetric

Cao, Guozhong

57

An experimental investigation of the ignition properties of hydrogen and carbon monoxide  

E-Print Network [OSTI]

for syngas turbine applications S.M. Walton *, X. He, B.T. Zigler, M.S. Wooldridge Department of Mechanical of simulated syngas mixtures of hydrogen (H2), carbon monoxide (CO), oxygen (O2), nitrogen (N2), and carbon mechanism for H2 and CO. Ã? 2006 The Combustion Institute. Published by Elsevier Inc. All rights reserved

Wooldridge, Margaret S.

58

Factors Affecting the Efficiency of Carbon Monoxide Photoproduction in the St. Lawrence Estuarine System (Canada)  

Science Journals Connector (OSTI)

Factors Affecting the Efficiency of Carbon Monoxide Photoproduction in the St. Lawrence Estuarine System (Canada) ... The solar insolation-weighted mean apparent quantum yield of CO (?CO) decreased as much as fourfold with increasing salinity and showed a strong positive correlation with the dissolved organic carbon-specific absorption coefficient at 254 nm. ...

Yong Zhang; Huixiang Xie; Guohua Chen

2006-11-01T23:59:59.000Z

59

A population-based exposure assessment methodology for carbon monoxide: Development of a carbon monoxide passive sampler and occupational dosimeter  

SciTech Connect (OSTI)

Two devices, an occupational carbon monoxide (CO) dosimeter (LOCD), and an indoor air quality (IAQ) passive sampler were developed for use in population-based CO exposure assessment studies. CO exposure is a serious public health problem in the U.S., causing both morbidity and mortality (lifetime mortality risk approximately 10{sup -4}). Sparse data from population-based CO exposure assessments indicate that approximately 10% of the U.S. population is exposed to CO above the national ambient air quality standard. No CO exposure measurement technology is presently available for affordable population-based CO exposure assessment studies. The LOCD and IAQ Passive Sampler were tested in the laboratory and field. The palladium-molybdenum based CO sensor was designed into a compact diffusion tube sampler that can be worn. Time-weighted-average (TWA) CO exposure of the device is quantified by a simple spectrophotometric measurement. The LOCD and IAQ Passive Sampler were tested over an exposure range of 40 to 700 ppm-hours and 200 to 4200 ppm-hours, respectively. Both devices were capable of measuring precisely (relative standard deviation <20%), with low bias (<10%). The LOCD was screened for interferences by temperature, humidity, and organic and inorganic gases. Temperature effects were small in the range of 10{degrees}C to 30{degrees}C. Humidity effects were low between 20% and 90% RH. Ethylene (200 ppm) caused a positive interference and nitric oxide (50 ppm) caused a negative response without the presence of CO but not with CO.

Apte, M.G.

1997-09-01T23:59:59.000Z

60

Mechanism of methanol synthesis from carbon monoxide and hydrogen on copper catalysts  

SciTech Connect (OSTI)

The authors examine possible mechanisms of methanol synthesis from carbon monoxide and hydrogen on supported copper catalysts. Two broad categories of reaction mechanism can be identified: (a) Type I: Carbon monoxide, adsorbed on the copper surface, is hydrogenated by the addition of hydrogen atoms while the C-O bond remains intact. A second C-O bond is neither formed nor broken. (b) Type II: Carbon monoxide (or a partially hydrogenated intermediate, e.g., HCO) reacts with an oxygen atom on the catalyst surface to give an intermediate, typically a formate, which contains two C-O bonds. Subsequent reaction leads overall to methanol and the reformation of the surface oxygen atom. Both mechanisms are discussed.

Fakley, M.E.; Jennings, J.R.; Spencer, M.S. (ICI Chemicals and Polymers Ltd, Billingham, Cleveland (England))

1989-08-01T23:59:59.000Z

Note: This page contains sample records for the topic "nox carbon monoxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Process for producing methane from gas streams containing carbon monoxide and hydrogen  

DOE Patents [OSTI]

Carbon monoxide-containing gas streams are passed over a catalyst capable of catalyzing the disproportionation of carbon monoxide so as to deposit a surface layer of active surface carbon on the catalyst essentially without formation of inactive coke thereon. The surface layer is contacted with steam and is thus converted to methane and CO.sub.2, from which a relatively pure methane product may be obtained. While carbon monoxide-containing gas streams having hydrogen or water present therein can be used only the carbon monoxide available after reaction with said hydrogen or water is decomposed to form said active surface carbon. Although hydrogen or water will be converted, partially or completely, to methane that can be utilized in a combustion zone to generate heat for steam production or other energy recovery purposes, said hydrogen is selectively removed from a CO--H.sub.2 -containing feed stream by partial oxidation thereof prior to disproportionation of the CO content of said stream.

Frost, Albert C. (Congers, NY)

1980-01-01T23:59:59.000Z

62

Carbon monoxide oxidation on Rh(111): Velocity and angular distributions of the CO2 product  

E-Print Network [OSTI]

Carbon monoxide oxidation on Rh(111): Velocity and angular distributions of the CO2 product J. I and angular distributions of CO2 produced by CO oxidation on Rh 111 have been measured as a function a fundamental and a practical point of view. CO2 formation serves as a model recombina- tion reaction

Sibener, Steven

63

Observations of rotating jets of carbon monoxide in comet Hale-Bopp with the IRAM interferometer  

E-Print Network [OSTI]

Observations of rotating jets of carbon monoxide in comet Hale-Bopp with the IRAM interferometer;eres, France Abstract. CO was observed on March 11, 1997 in comet Hale-Bopp with the IRAM Plateau de for parent molecules. We have developed a 3-D model simulating rotating spiral jets of CO gas. We present

Demoulin, Pascal

64

Crystallization and mutational studies of carbon monoxide dehydrogenase from moorella thermoacetica  

E-Print Network [OSTI]

Carbon Monoxide Dehydrogenase (CODH), also known as Acetyl-CoA synthase (ACS), is one of seven known Ni containing enzymes. CODH/ACS is a bifunctional enzyme which oxidizes CO to CO2 reversibly and synthesizes acetyl-CoA. Recently, X-ray crystal...

Kim, Eun Jin

2004-09-30T23:59:59.000Z

65

Effect of redox potential, sulfide ions and a persulfide forming cysteine residue on carbon monoxide dehydrogenase  

E-Print Network [OSTI]

The Ni-Fe-S C-cluster of carbon monoxide dehydrogenases (CODH), which catalyzes the reversible oxidation of CO to CO2, can be stabilized in four redox states: Cox, Cred1, Cint, and Cred2. The best-supported mechanism of catalysis involves a one...

Feng, Jian

2005-08-29T23:59:59.000Z

66

Study of hydrogen and carbon monoxide adsorption on modified Zn/Cr catalysts by adsorption calorimetry  

SciTech Connect (OSTI)

Differential heat of adsorption (q) of hydrogen (a) and carbon monoxide (b) as a function of the adsorbed amount (a) on Zn/Cr catalysts at 463/sup 0/K; 1) unpromoted catalyst, 2) catalyst promoted with 2.5% of K/sub 2/O.

Yoshin, S.V.; Klyacho, A.L.; Kondrat'ev, L.T.; Leonov, V.E.; Skripchenko, G.B.; Sushchaya, L.E.

1986-08-01T23:59:59.000Z

67

Association of hydrogen metabolism with unitrophic or mixotrophic growth of Methanosarcina barkeri on carbon monoxide.  

Science Journals Connector (OSTI)

...by the simultaneous consumption of methanol and CO...by the simultaneous consumption of methanol and CO...conbustion of fossil fuels. Carbon monoxide is...involves the production and consumption of a carbonyl group...served as experi- mental vessels. Immediately after...

J M O'Brien; R H Wolkin; T T Moench; J B Morgan; J G Zeikus

1984-04-01T23:59:59.000Z

68

Electrochemical Removal of Carbon Monoxide in Reformate Hydrogen for Fueling Proton Exchange Membrane  

E-Print Network [OSTI]

Electrochemical Removal of Carbon Monoxide in Reformate Hydrogen for Fueling Proton Exchange Membrane Fuel Cells Sivagaminathan Balasubramanian, Charles E. Holland,* and John W. Weidner*,z Center in reformate hydrogen. In this design, the potential and gas flow are switched between the two filter cells so

Weidner, John W.

69

Molten metal reactor and method of forming hydrogen, carbon monoxide and carbon dioxide using the molten alkaline metal reactor  

DOE Patents [OSTI]

A molten metal reactor for converting a carbon material and steam into a gas comprising hydrogen, carbon monoxide, and carbon dioxide is disclosed. The reactor includes an interior crucible having a portion contained within an exterior crucible. The interior crucible includes an inlet and an outlet; the outlet leads to the exterior crucible and may comprise a diffuser. The exterior crucible may contain a molten alkaline metal compound. Contained between the exterior crucible and the interior crucible is at least one baffle.

Bingham, Dennis N.; Klingler, Kerry M.; Turner, Terry D.; Wilding, Bruce M.

2012-11-13T23:59:59.000Z

70

Carbon Monoxide Tolerant Electrocatalyst with Low Platinum Loading...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

particle. When used as an electrocatalyst for the oxidation of fuel at a fuel cell anode, this structure exhibits low platinum loading and elevated tolerance to carbon...

71

Impact of emissions, chemistry, and climate on atmospheric carbon monoxide : 100-year predictions from a global chemistry-climate model  

E-Print Network [OSTI]

The possible trends for atmospheric carbon monoxide in the next 100 yr have been illustrated using a coupled atmospheric chemistry and climate model driven by emissions predicted by a global economic development model. ...

Wang, Chien.; Prinn, Ronald G.

72

Relative and kinetic properties of carbon monoxide and carbon dioxide on a graphite surface  

SciTech Connect (OSTI)

Temperature-programmed desorption (TPD) results after chemisorption of carbon monoxide (CO) and carbon dioxide (CO/sub 2/) on polycrystalline graphite are presented. CO adsorbs onto graphite with a very low sticking coefficient. After CO chemisorption CO (mass 28 amu) desorbs in two temperature regions, between 400 and 700 K and between 1000 and 1300 K, and CO/sub 2/ (mass 44 amu) desorbs below 950 K. The intensity of the CO/sub 2/ signal is less than 1 order of magnitude lower than the CO intensity. After CO/sub 2/ adsorption the major desorption product is CO at high temperatures (1000 < T (K) < 1300), whereas a small amount of CO/sub 2/ desorbs around 450 K. The adsorption of C/sup 16/O/sub 2/ and C/sup 18/O/sub 2/ mixture leads to a nearly total oxygen scrambling of the CO/sub 2/ desorbed. A mechanism for CO and CO/sub 2/ interconversion on the graphite surface is presented in terms of surface oxide species, mainly lactones and semiquinones, and their relative stability. Assignments of the TPD features are proposed accordingly. Reaction studies on the CO/sub 2/ gasification of clean graphite and the CO disproportionation (Boudouard reaction) have been performed. A good agreement is found between the activation energies obtained and the desorption energies calculated from the analysis of the TPD results.

Marchon, B.; Tysoe, W.T.; Carrazza, J.; Heinemann, H.; Somorjai, G.A.

1988-10-06T23:59:59.000Z

73

Catalytic reactions on well-characterized vanadium oxide catalysts. 1. Oxidation of carbon monoxide  

SciTech Connect (OSTI)

The oxidation of carbon monoxide over unsupported and supported vanadium oxide catalysts was investigated from the standpoint of structure sensitivity. The activity of unsupported V/sub 2/O/sub 5/ markedly decreased the turnover frequency, while the reduction-oxidation treatment of the fused catalyst increased it. The turnover frequency of V/sub 2/O/sub 5//TiO/sub 2/ with low V/sub 2/O/sub 5/ content was much smaller than that of the V/sub 2/O/sub 5//TiO/sub 2/ with high V/sub 2/O/sub 5/ content or the unsupported V/sub 2/O/sub 5/. Such a retarding effect of the TiO/sub 2/ support on the activity of the oxidation of carbon monoxide is in contrast to the known promoting effect of TiO/sub 2/ for the oxidations of various hydrocarbons. From these results coupled with the characterization of the catalysts, it was concluded that the oxidation of carbon monoxide on vanadium oxide catalysts is a structure-sensitive reaction and that the activity of surface defects such as steps, kinks, and vacancies is much higher than that of the surface V=O species in the smooth (010) face of V/sub 2/O/sub 5/. 39 references, 9 figures, 2 tables.

Mori, K.; Miyamoto, A.; Murakami, Y.

1984-06-21T23:59:59.000Z

74

Gravimetric study of adsorbed intermediates in methanation of carbon monoxide  

SciTech Connect (OSTI)

The purpose of this study is to more fully elucidate the adsorbed intermediates and mechanism involved in catalytic methanation of CO on a typical nickel methanation catalyst. Rates of adsorption and desorption of surface species and of gasification of carbon were measured gravimetrically to determine their kinetics and possible roles in methanation. 19 refs.

Gardner, D.C.; Bartholomew, C.H.

1981-08-01T23:59:59.000Z

75

Mechanism of iron catalysis of carbon monoxide decomposition in refractories  

SciTech Connect (OSTI)

The authors discuss the catalytic effects of selected iron phases (metals, oxides, sulfides, and carbides) on the Boudouard reaction studied in an effort to more fully understand the disintegration of refractories when exposed to CO for long periods of time. It was found that active Fe atoms generated from the reduction of the iron oxides, especially {alpha}-Fe/sub 2/O/sub 3/, are the actual catalysts for the Boudouard reaction. The catalytic process confirmed by thermodynamic calculations, kinetic data, and X-ray diffraction data, consists of adsorption and decomposition of CO simultaneously forming carbides of iron. The chemisorption and subsequent decomposition of the iron carbides, rather than diffusion, constitute the rate-controlling process for carbon deposition.

Xu, M.W.P.; Brown, J.J. Jr. (Virginia Polytechnic Inst. and State Univ., Blacksburg, VA (USA). Dept. of Materials Engineering)

1989-01-01T23:59:59.000Z

76

Adsorption and desorption of hydrogen and carbon monoxide were studied on alumina-supported iridium catalysts  

SciTech Connect (OSTI)

The adsorption and desorption of hydrogen and carbon monoxide were studied on alumina-supported iridium catalysts which were examined by a scanning transmission electron microscope (STEM). The metal particle size and number of particles per area of catalyst increased with increasing metal loading. The particles were approx. 10 A. in diameter, cubo-octahedral shaped, and approx. 80-90% disperse. The STEM electron beam caused negligible damage to the samples. Hydrogen adsorption measurements showed that the hydrogen-iridium atom ratio was 1.2:1-1.3:1 and increased with decreasing metal loading. Temperature-programed desorption showed four types of adsorbed hydrogen desorbing at -90/sup 0/C (I), 15/sup 0/C (IV), 115/sup 0/C (II), and 245/sup 0/C (III). Types II and IV desorb from single atom sites and Types I and III from multiple atom sites. Type I is in rapid equilibrium with the gas phase. All desorption processes appear to be first order. Carbon monoxide adsorbed nondissociatively at 25/sup 0/C with approx. 0.7:1 CO/Ir atom ratio. It adsorbed primarily in linear forms at low coverage, but a bridged form appeared at high coverage.

Etherton, B.P.

1980-01-01T23:59:59.000Z

77

Ultraviolet photoelectron spectroscopic study of the interaction of potassium with carbon monoxide and benzene on the Pt(111) surface  

SciTech Connect (OSTI)

The interaction of potassium with carbon monoxide and benezene has been studied on the Pt(111) crystal surface by ultraviolet photoelectron spectroscopy (UPS). The adsorptive changes reported in previous studies for carbon monoxide and benzene when potassium is coadsorbed are correlated with the UPS results presented here and are explained with the aid of a molecular orbital analysis. The authors find that the valence molecular orbitals increase their binding energy slightly when the potassium is coadsorbed, implying a model in which the adsorbates sense the potassium-induced changes in dipole field at the surface. 36 references, 11 figures.

Kudo, M.; Garfunkel, E.L.; Somorjai, G.A.

1985-07-18T23:59:59.000Z

78

Observation of two-dimensional compositional ordering of a carbon monoxide and argon monolayer mixture physisorbed on graphite  

SciTech Connect (OSTI)

Commensurate monolayers of a mixture of 70% carbon monoxide and 30% argon on graphite are studied by neutron and low-energy-electron diffraction. A 2 x 2 superstructure due to 3:1 compositional ordering is observed below 25 K. The compositional ordering is most likely due to molecular-axis ordering of carbon monoxide molecules into a pinwheel pattern with argon atoms at the central sites of each pinwheel. Such a pinwheel structure has been predicted by Harris, Mouritsen, and Berlinsky for planar rotors with anisotropic interactions on a triangular lattice with vacancies.

You, H.; Fain, S.C. Jr.; Satija, S.; Passell, L.

1986-01-20T23:59:59.000Z

79

Impact of the Presence of Carbon Monoxide and Carbon Dioxide on Gas Oil Hydrotreatment: Investigation on Liquids from Biomass Cotreatment with Petroleum Cuts  

Science Journals Connector (OSTI)

Impact of the Presence of Carbon Monoxide and Carbon Dioxide on Gas Oil Hydrotreatment: Investigation on Liquids from Biomass Cotreatment with Petroleum Cuts ... A potential way of utilizing these bioliquids as fuels could be the direct hydrotreatment(6) or the cohydrotreatment with petroleum fractions,(7) such as atmospheric gas oils, to achieve the technical and environmental fuel standards, especially in terms of sulfur content. ...

Ana Pinheiro; Nathalie Dupassieux; Damien Hudebine; Christophe Geantet

2011-01-18T23:59:59.000Z

80

Design and Development of a Mid-Infrared Carbon Monoxide Sensor for a High-Pressure Combustor Rig  

E-Print Network [OSTI]

A sensor for carbon monoxide measurement has been developed using a mid-infrared quantum-cascade (QC) laser operating in the fundamental band (?v= 1) of CO near 4.5 ?m. The fundamental band was chosen due to its stronger absorption line...

Camou, Alejandro

2014-05-03T23:59:59.000Z

Note: This page contains sample records for the topic "nox carbon monoxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Chemisorption of carbon monoxide and nitrogen oxides on highly dispersed technetium  

SciTech Connect (OSTI)

The purpose of this work is to study, in infrared spectroscopy, the surface compounds formed on adsorption of carbon monoxide and nitrogen oxides on Tc/SiO/sub 2/. The samples were prepared by soaking Aerosil with aqueous solution of ammonium pertechnetate containing 10 wt.% of Tc. Reduction with hydrogen to the metal was carried out at 700-800/sup 0/C. Results indicated that chemisorption of CO on highly dispersed technetium gives rise to a single type of linear and several types of multicentered adsorption forms. Occurrence of bridge form of adsorbed CO was also suggested on the basis of the data on chemisorption stoichiometry. Formation of a structure characterizable by absorption at 1790 cm/sup -1/ may indicate, only after protracted analysis, that the surface of the technetium introduced gradually suffers significant rearrangement facilitating formation of this type of complexes.

Serebryakova, N.V.; Sokolova, N.P.; Spitsyn, V.S.

1982-08-01T23:59:59.000Z

82

Transformation of carbon monoxide dimer surface structures on yttrium oxide modified by silver  

SciTech Connect (OSTI)

It has been established that introducing ions of silver(II) in yttrium(III) oxide leads to the formation of a significant concentration of a paramagnetic dimer species (CO)/sub 2/-in the course of the adsorption of carbon monoxide, and that these dimers exhibit high thermal stability and reactivity. Reactions are proposed for the formation of the dimer species (CO)/sub 2//sup 2 -/ and (CO)/sub 2//sup -/ on the surface of the Ag/Y/sub 2/O/sub 3/ catalyst that involve the reduction of the anion vacancies and a change in the oxidation state of the silver ions. Modifying the yttrium oxide with ionic silver leads to a marked decrease in the strength of the oxidative ability of the surface of the catalyst for CO, while the nature of the active sites of the yttrium oxide, which adsorbs CO in three forms, remains unchanged.

Vydrin, S.N.; Bobolev, A.V.; Loginov, A.Yu.

1987-09-10T23:59:59.000Z

83

Infrared spectroscopic study of the adsorption of carbon monoxide on silica-supported copper oxide  

SciTech Connect (OSTI)

Adsorption of carbon monoxide at room temperature (0.1 to 50 Torr) on silica-supported copper oxide was studied by infrared spectroscopy. Catalysts were prepared by deposition-precipitation or impregnation. After calcination two types of adsorbed CO were identified showing absorption bands at 2136 +- 3 and 2204 +- 1 cm/sup -1/, which are ascribed to CO adsorbed on copper(II) oxide and on isolated copper(II) ions in the silica surface, respectively. Reduction and reoxidation removed the band at 2204 cm/sup -1/ with all samples and raised the intensity of the 2136-cm/sup -1/ band with the precipitated catalysts but not with the impregnation catalyst. Evidence is brought forward that the isolated copper ions are mobilized during reduction and generate new copper (oxide) surface. The change in background transmission of the samples could be used to obtain further information about the interaction of O/sub 2/ and CO with copper oxide.

De Jong, K.P.; Geus, J.W.; Joziasse, J.

1980-10-01T23:59:59.000Z

84

Modification of copper-chromium catalyst for steam conversion of carbon monoxide  

SciTech Connect (OSTI)

This paper presents the results of model tests that show that the copperchromium sample is superior in stability and activity to the industrial NTK-5 catalyst. Under unfavorable conditions with the use of industrial converted gas containing more than 20 vol.% of carbon monoxide, and with sulfur compounds, chlorine, and ammonia as impurities, after 3 months of continuous operation in the temperature range 190-260 degrees the catalyst lost less than 10% of inactivity (with respect to the degree of CO conversion), whereas the activity of the industrial NTK-4 catalyst fell by 15% under the same conditions. It is shown that a catalyst not inferior in properties to the industrial NTK-4 catalyst can be obtained by modifying the copper-chromium catalyst with aluminum compounds.

Khabibullin, R.R.; Torocheshnikov, N.S.

1986-08-01T23:59:59.000Z

85

Carbon monoxide adsorption/desorption processes over NaX zeolite and supported ruthenium catalyst  

SciTech Connect (OSTI)

The binding states of CO on NaX zeolite and RuNaX were investigated by thermal desorption spectroscopy. Desorption peaks centered at around 390, 430, 490, and 520 K were observed from NaX following room-temperature adsorption of CO. The activation energy values corresponding to these peaks were calculated to be 41.4, 45.7, 53.8, and 57.7 kJ mol{sup {minus}1}, respectively. These peaks were also observed in desorption profiles from RuNaX although their temperatures were higher by 10 to 20 K. In addition, the desorption spectra from RuNaX also comprise two high-temperature peaks at around 575 and 640 K. With both the RuNaX and the NaX samples the temperature and relative intensities of the desorption peaks depended on pretreatment conditions and on the lapsed time between CO exposure to the sample and the commencement of programmed heating. Mass spectral analysis revealed that the gas desorbed at 300-500 K consisted mainly of CO while at higher temperatures CO{sub 2} was the main component. The desorption peaks below 500 K are attributed to the release of carbon monoxide from structural and intragranular or intergranular zeolitic pores. Lewis sites on the zeolite surface are found to facilitate activation of CO, resulting in its transformation to CO{sub 2}. The initial adsorption of carbon monoxide in zeolite pores and subsequent diffusion to metal sites leading to its disproportionation/oxidation is found to play an important role in the CO adsorption/desorption process on RuNaX.

Kamble, V.S.; Gupta, N.M.; Iyer, R.M. (Bhabha Atomic Research Centre, Bombay (India))

1988-10-01T23:59:59.000Z

86

Solar Carbon Monoxide, Thermal Profiling, and the Abundances of C, O, and their Isotopes  

E-Print Network [OSTI]

A solar photospheric "thermal profiling" analysis is presented, exploiting the infrared rovibrational bands of carbon monoxide (CO) as observed with the McMath-Pierce Fourier transform spectrometer (FTS) at Kitt Peak, and from above the Earth's atmosphere by the Shuttle-borne ATMOS experiment. Visible continuum intensities and center-limb behavior constrained the temperature profile of the deep photosphere, while CO center-limb behavior defined the thermal structure at higher altitudes. The oxygen abundance was self consistently determined from weak CO absorptions. Our analysis was meant to complement recent studies based on 3-D convection models which, among other things, have revised the historical solar oxygen (and carbon) abundance downward by a factor of nearly two; although in fact our conclusions do not support such a revision. Based on various considerations, an oxygen abundance of 700+/-100 ppm (parts per million relative to hydrogen) is recommended; the large uncertainty reflects the model sensitivity of CO. New solar isotopic ratios also are reported for 13C, 17O, and 18O.

Thomas R. Ayres; Claude Plymate; Christoph U. Keller

2006-06-07T23:59:59.000Z

87

Kinetics of the Reduction of Wüstite by Hydrogen and Carbon Monoxide for the Chemical Looping Production of Hydrogen  

E-Print Network [OSTI]

produced could be stored, e.g. by geological sequestration, making the overall process “carbon-neutral”, or “carbon-negative” when biomass is used as fuel. In addition, the hydrogen produced during the oxidation of FexO and metallic Fe in steam can be kept... Kinetics of the reduction of wüstite by hydrogen and carbon monoxide for the chemical looping production of hydrogen Wen Liu a,n, Jin Yang Lim b, Marco A. Saucedo a, Allan N. Hayhurst b, Stuart A. Scott a, J.S. Dennis b a Department of Engineering...

Liu, Wen; Lim, Jin Yang; Saucedo, Marco A.; Hayhurst, Allan N.; Scott, Stuart A.; Dennis, J. S.

2014-08-13T23:59:59.000Z

88

Oxidation of carbon monoxide and hydrocarbons on platinum and palladium catalysts in the presence of sulfur dioxide  

SciTech Connect (OSTI)

The authors report on a study of the effect of sulfur dioxide on the activity of platinum and palladium catalysts with respect to oxidation of the principal toxic components in the exhaust gases of internal combustion engines: carbon monoxide and hydrocarbons (propylene (C/sub 3/H/sub 6/) and propane (C/sub 3/H/sub 8/)). The experiments were carried out in a flow system equipped with Beckman infrared analyzers to monitor the concentrations of CO and hydrocarbons and of sulfur dioxide. A series of thermal desorption experiments was carried out in a low-pressure flow system with mass spectrometric analysis of the gas phase. The results indicate that the low-temperature adsorption of sulfur dioxide on platinum (and also palladium) catalysts inhibits the oxidation of carbon monoxide and propylene. The poisoning effect of O/sub 2/ is due to blockage of the platinum centers for adsorption of the oxidizable compounds and oxygen.

Panchishnyi, V.I.; Bondareva, N.K.; Sklyarov, A.V.; Rozanov, V.V.; Chadina, G.P.

1988-11-10T23:59:59.000Z

89

Using the HP-41CV calculator as a data acquisition system for personal carbon monoxide exposure monitors  

SciTech Connect (OSTI)

The use of small, personal monitors as instruments for air pollution data acquisition, storage, and retrieval presents a new set of monitoring considerations. Portability, ruggedness, power supplies, and data capture are functions to be addressed in designing personal monitoring systems. The emphasis herein is on the data capture function. This paper describes experiences using the Hewlett-Packard HP-41CV system as a data management system interfaced with personal carbon monoxide monitors (General Electric Carbon Monoxide Detector, Model 15EC53CO3). In general, the HP-41CV proved to be reliable, adaptable, and easy to use. Problems with the monitor power source (battery failure) were more frequent than with the HP-41CV itself. Using the HP-41CV for the specific data collection requirements of the Washington Microenvironment Study is a focal point of this presentation.

Fitz-Simons, T.; Sauls, H.B.

1984-09-01T23:59:59.000Z

90

Total oxidation of carbon monoxide and methane over transition metal-fluorite oxide composite catalysts. I. Catalyst composition and activity  

SciTech Connect (OSTI)

A novel metal oxide composite catalyst for the total oxidation of carbon monoxide and methane was prepared by combining fluorite oxides with active transition metals. The fluorite oxides, such as ceria and zirconia, are oxygen-ion-conducting materials having catalytic properties usually at high temperatures. Active base metal catalysts, such as copper, were used as additives to promote the catalytic properties of these oxides. The contact of the two types of materials gave rise to a high active oxidation catalyst. At a space velocity of about 42,000 h{sup {minus}1}, complete carbon monoxide oxidation in air occurred at room temperature on the Au{sub 0.05}[Ce(La)]{sub 0.95}L{sub x} catalyst and at ca. 100{degrees}C on Cu-Ce-O composite catalysts. At the same space velocity, total oxidation of methane on the Cu-Ce-O catalyst doped with La{sub 2}O{sub 3} or SrO took place at ca. 550{degrees}C. The specific carbon monoxide oxidation activity of the Cu-Ce-O catalyst was several orders of magnitude higher than that of conventional copper-based catalysts and comparable or superior to platinum catalysts. This type of composite catalyst also showed excellent resistance to water vapor poisoning. The enhanced catalyst activity and stability resulted from strong interaction of the transition metal and fluorite oxide materials. 44 refs., 14 figs., 5 tabs.

Liu, W.; Flytzani-Stephanopoulos, F. [Tufts Univ., Medford, MA (United States)] [Tufts Univ., Medford, MA (United States)

1995-05-01T23:59:59.000Z

91

Pillared smectite modified with carbon and manganese as catalyst for SCR of NOx with NH3. Part I. General characterization and catalyst screening  

Science Journals Connector (OSTI)

Carbon- and manganese-modified zirconia-pillared smectites were prepared, characterized (XRD, BET and pore analysis, XPS) and tested in selective catalytic reduction of NOx with NH3. Both untreated and acidic pre...

Lucjan Chmielarz; Roman Dziembaj; Teresa Grzybek; Jerzy Klinik…

92

Adsorption of carbon monoxide on a smooth palladium electrode: an in-situ infrared spectroscopic study  

SciTech Connect (OSTI)

Adsorption of carbon monoxide on a smooth palladium electrode in 1 M HClO/sub 4/ saturated with CO was studied by two in-situ IR reflectance spectroscopic methods: EMIRS (electrochemically modulated infrared reflectance spectroscopy) and LPSIRS (linear potential sweep infrared reflectance spectroscopy). Two types of adsorbed CO, linear and bridged, were identified from the observed IR spectra, the latter being the predominant surface species. The C-O stretching frequency of the linear CO shifts to higher frequencies at more positive potentials with a slope of 48 cm/sup -1//V. The frequency of the bridged CO increases by 63 cm/sup -1/ between -0.5 and 0.9 V(NHE) and its integrated band intensity decreases continuously in the same potential region while the intensity of the linear CO is almost constant up to 0.1 V and then decreases gradually with increasing positive potential. The surface selection rule of the IR reflection absorption spectroscopy was tested for the present system by using the p- and s-polarized light. It was found that only p-polarized light gave the IR spectra of CO adsorbed on the palladium electrode thus proving the selection rule at the electrode/solution interface.

Kunimatsu, K.

1984-05-24T23:59:59.000Z

93

Cysteine 295 indirectly affects Ni coordination of carbon monoxide dehydrogenase-II C-cluster  

SciTech Connect (OSTI)

Highlights: •CODH-II harbors a unique [Ni-Fe-S] cluster. •We substituted the ligand residues of Cys{sup 295} and His{sup 261}. •Dramatic decreases in Ni content upon substitutions were observed. •All substitutions did not affect Fe-S clusters assembly. •CO oxidation activity was decreased by the substitutions. -- Abstract: A unique [Ni–Fe–S] cluster (C-cluster) constitutes the active center of Ni-containing carbon monoxide dehydrogenases (CODHs). His{sup 261}, which coordinates one of the Fe atoms with Cys{sup 295}, is suggested to be the only residue required for Ni coordination in the C-cluster. To evaluate the role of Cys{sup 295}, we constructed CODH-II variants. Ala substitution for the Cys{sup 295} substitution resulted in the decrease of Ni content and didn’t result in major change of Fe content. In addition, the substitution had no effect on the ability to assemble a full complement of [Fe–S] clusters. This strongly suggests Cys{sup 295} indirectly and His{sup 261} together affect Ni-coordination in the C-cluster.

Inoue, Takahiro; Takao, Kyosuke; Yoshida, Takashi [Division of Applied Biosciences, Graduate School of Agriculture, Kyoto University, Kyoto 606-8502 (Japan)] [Division of Applied Biosciences, Graduate School of Agriculture, Kyoto University, Kyoto 606-8502 (Japan); Wada, Kei [Organization for Promotion of Tenure Track, University of Miyazaki, Miyazaki 889-1692 (Japan)] [Organization for Promotion of Tenure Track, University of Miyazaki, Miyazaki 889-1692 (Japan); Daifuku, Takashi; Yoneda, Yasuko [Division of Applied Biosciences, Graduate School of Agriculture, Kyoto University, Kyoto 606-8502 (Japan)] [Division of Applied Biosciences, Graduate School of Agriculture, Kyoto University, Kyoto 606-8502 (Japan); Fukuyama, Keiichi [Department of Biological Sciences, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043 (Japan)] [Department of Biological Sciences, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043 (Japan); Sako, Yoshihiko, E-mail: sako@kais.kyoto-u.ac.jp [Division of Applied Biosciences, Graduate School of Agriculture, Kyoto University, Kyoto 606-8502 (Japan)] [Division of Applied Biosciences, Graduate School of Agriculture, Kyoto University, Kyoto 606-8502 (Japan)

2013-11-08T23:59:59.000Z

94

Carbon monoxide in the solar atmosphere I. Numerical method and two-dimensional models  

E-Print Network [OSTI]

The radiation hydrodynamic code CO5BOLD has been supplemented with the time-dependent treatment of chemical reaction networks. Advection of particle densities due to the hydrodynamic flow field is also included. The radiative transfer is treated frequency-independently, i.e. grey, so far. The upgraded code has been applied to two-dimensional simulations of carbon monoxide (CO) in the non-magnetic solar photosphere and low chromosphere. For this purpose a reaction network has been constructed, taking into account the reactions which are most important for the formation and dissociation of CO under the physical conditions of the solar atmosphere. The network has been strongly reduced to 27 reactions, involving the chemical species H, H2, C, O, CO, CH, OH, and a representative metal. The resulting CO number density is highest in the cool regions of the reversed granulation pattern at mid-photospheric heights and decreases strongly above. There, the CO abundance stays close to a value of 8.3 on the usual logarithmic abundance scale with [H]=12 but is reduced in hot shock waves which are a ubiquitous phenomenon of the model atmosphere. For comparison, the corresponding equilibrium densities have been calculated, based on the reaction network but also under assumption of instantaneous chemical equilibrium by applying the Rybicki & Hummer (RH) code by Uitenbroek (2001). Owing to the short chemical timescales, the assumption holds for a large fraction of the atmosphere, in particular the photosphere. In contrast, the CO number density deviates strongly from the corresponding equilibrium value in the vicinity of chromospheric shock waves. Simulations with altered reaction network clearly show that the formation channel via hydroxide (OH) is the most important one under the conditions of the solar atmosphere.

S. Wedemeyer-Boehm; I. Kamp; J. Bruls; B. Freytag

2005-03-23T23:59:59.000Z

95

Novel Carbon Monoxide Sensor for PEM Fuel Cell Systems C.T. Holt, A.-M. Azad, S.L. Swartz, W.J. Dawson, and P.K. Dutta  

E-Print Network [OSTI]

Novel Carbon Monoxide Sensor for PEM Fuel Cell Systems C.T. Holt, A.-M. Azad, S.L. Swartz, W The importance of carbon monoxide sensors for automotive PEM fuel cell systems is illustrated by a schematic will protect the PEM fuel cell stack; detection of CO is extremely important because too much CO will poison

Azad, Abdul-Majeed

96

Interaction of copper oxides with reaction medium in heterogeneous catalytic oxidation of carbon monoxide by molecular oxygen. IV. IR spectroscopic study of carbon monoxide interaction with copper oxide surface  

SciTech Connect (OSTI)

An IR spectroscopic study has been made of the interaction of CO with CuO prepared in different ways, and the interaction of O/sub 2/ with carbon monoxide preadsorbed on CuO. A number of Cu/sup +/CO surface complexes have been detected (2114-2148 cm/sup -1/) with a heat of adsorption about 79.5-180 kJ/mole. From an analysis of the nature of these complexes, we have evaluated the processes taking place on the CuO surface when it interacts with CO and have compared the properties of massive CuO with those of CuO on oxide supports. The data are interpreted on the assumption that extended defects - dislocations - exist and play an important role, determining to a considerable degree the properties of the massive CuO in the reaction of CO oxidation.

Lokhov, Y.A.; Popovskii, V.V.; Sadykov, V.A.; Tikhov, S.F.

1985-08-01T23:59:59.000Z

97

J. Phys. Chem. 1994, 98, 11213-11219 11213 Vibrational Dynamics of Carbon Monoxide at the Active Site of Myoglobin: Picosecond  

E-Print Network [OSTI]

J. Phys. Chem. 1994, 98, 11213-11219 11213 Vibrational Dynamics of Carbon Monoxide at the Active Physics Laboratory, Stanford University, Stanford, Califomia 94305 Received: April 27, 1994: In Final Form at Urbana-Champaign. Deparlment of Chemistry, Sfanford University. Hansen ExperimentaJ Physics Laboratory

Fayer, Michael D.

98

Process for the production of hydrogen and carbonyl sulfide from hydrogen sulfide and carbon monoxide using a metal boride, nitride, carbide and/or silicide catalyst  

SciTech Connect (OSTI)

Hydrogen and carbonyl sulfide are produced by a process comprising contacting gaseous hydrogen sulfide with gaseous carbon monoxide in the presence of a metal boride, carbide, nitride and/or silicide catalyst, such as titanium carbide, vanadium boride, manganese nitride or molybdenum silicide.

McGuiggan, M.F.; Kuch, P.L.

1984-05-08T23:59:59.000Z

99

Resilience of gas-phase anharmonicity in the vibrational response of adsorbed carbon monoxide and breakdown under electrical conditions  

E-Print Network [OSTI]

In surface catalysis, the adsorption of carbon monoxide on transition-metal electrodes represents the prototype of strong chemisorption. Notwithstanding significant changes in the molecular orbitals of adsorbed CO, spectroscopic experiments highlight a close correlation between the adsorbate stretching frequency and equilibrium bond length for a wide range of adsorption geometries and substrate compositions. In this work, we study the origins of this correlation, commonly known as Badger's rule, by deconvoluting and examining contributions from the adsorption environment to the intramolecular potential using first-principles calculations. Noting that intramolecular anharmonicity is preserved upon CO chemisorption, we show that Badger's rule for adsorbed CO can be expressed solely in terms of the tabulated Herzberg spectroscopic constants of isolated CO. Moreover, although it had been previously established using finite-cluster models that Badger's rule is not affected by electrical conditions, we find here th...

Dabo, Ismaila

2012-01-01T23:59:59.000Z

100

Adsorbate effects on a mixed-valence compound: Carbon monoxide chemisorption on CeIr/sub 2/  

SciTech Connect (OSTI)

We have studied the effects of stoichiometry change and CO chemisorption on the surface electronic structure of the mixed-valence compound CeIr/sub 2/. We show that the surface iridium to cerium ratio can be varied by changing sample temperature while sputtering. Carbon monoxide is found to adsorb 80% molecularly on the surface and cause a mild surface oxidation which induces a shift of electron density into available cerium f orbitals. Peaks due to the 4sigma, 1..pi.., and 5sigma CO molecular orbitals appear at different binding energies than those due to molecular CO on the pure iridium surface. This binding-energy shift as well as the high percentage of molecular CO on the surface (CO adsorption on pure cerium is completely dissociative) points toward a surface which has lost much of the elemental character of its two constituents upon compound formation.

Lindquist, J.M.; Hemminger, J.C.; Lawrence, J.

1987-10-15T23:59:59.000Z

Note: This page contains sample records for the topic "nox carbon monoxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Auger electron spectroscopy, electron loss spectroscopy and low energy electron diffraction of oxygen and carbon monoxide adsorption of Pd films  

SciTech Connect (OSTI)

The adsorption of oxygen and carbon monoxide at room temperature on polycrystalline and (111) monocrystalline thin films of Pd vapor deposited on mice was investigated by AES, ELS, and LEED. The results show that adsorbate coverage depends strongly on surface microstructure, composition, and topography. Polycrystalline or Cl contaminated surfaces adsorb large amounts of the gases, while flat, monocrystalline surfaces will adsorb almost none. These results are quite different from those observed earlier using sputter etched and annealed bulk single cyrstals where adsorbate superlattices formed after rather low gaseous exposures. In the present work no superlattices were observed after exposures ranging up to several thousand langmuirs. The contradictory results obtained in the two cases are attributed to probable differences in surface microtopography and microstructure.

Vook, R.W.; De Cooman, B.C.; Vankar, V.D.

1983-01-01T23:59:59.000Z

102

Remarkable catalytic activity of cobalt tetraphenylporphyrin modified on a titania for the oxidation of carbon monoxide below room temperature  

SciTech Connect (OSTI)

CoTPP on TiO/sub 2/-120s modified at 250 /sup 0/C under vacuum catalytically oxidized carbon monoxide rapidly with oxygen even at -79/sup 0/C. Its catalytic activity was incomparably higher than that of commercial Hopcalite. Comparison of its catalytic performance with those of the same catalyst or different TiO/sub 2/ supporting catalyst both evacuated at 200 /sup 0/C revealed unique features of the present catalyst in terms of its oxygen adsorption, the poisoning of adsorbed oxygen, and the insolubility of the complex in benzene. Both significant structural modification of the complex and its strong interaction with properly dehydrated TiO/sub 2/-120s brought about by evacuation at 250 /sup 0/C may induce such extraordinary activity. 14 references, 4 figures, 5 tables.

Mochida, I.; Iwai, Y.; Kamo, T.; Fujitsu, H.

1985-12-05T23:59:59.000Z

103

Adsorbate effects on a mixed-valence compound: carbon monoxide chemisorption on CeIr/sub 2/  

SciTech Connect (OSTI)

The authors studied the effects of stoichiometry change and CO chemisorption on the surface electronic structure of the mixed-valence compound CeIr/sub 2/. It is shown that the surface iridium to cerium ratio can be varied by changing sample temperature while sputtering. Carbon monoxide is found to adsorb 80% molecularly on the surface and cause a mild surface oxidation which induces a shift of electron density into available cerium f orbitals. Peaks due to the 4 sigma, 1 pi, and 5 sigma CO molecular orbitals appear at different binding energies than those due to molecular CO on the pure iridium surface. This binding-energy shift as well as the high percentage of molecular CO on the surface (CO adsorption on pure cerium is completely dissociative) points toward a surface which has lost much of the elemental character of its two constituents upon compound formation.

Lindquist, J.M.; Hemminger, J.C.

1987-10-15T23:59:59.000Z

104

DEVELOPMENT OF A VALIDATED MODEL FOR USE IN MINIMIZING NOx EMISSIONS AND MAXIMIZING CARBON UTILIZATION WHEN COFIRING BIOMASS WITH COAL  

SciTech Connect (OSTI)

This is the first Quarterly Technical Report for DOE Cooperative Agreement No. DE-FC26-00NT40895. A statement of the project objectives is included in the Introduction of this report. The project goals and detailed plans were presented in two project kickoff meetings; one at NETL in Pittsburgh and one in Birmingham, AL at Southern Research Institute. Progress has been made in developing a modeling approach to synthesize the reaction time and temperature distributions that will be produced by computational fluid dynamic models of the pilot-scale combustion furnace and the char burnout and chemical reaction kinetics that will predict NOx emissions and unburned carbon levels in the furnace exhaust. Preparations are under way for the initial pilot-scale combustion experiments.

Larry G. Felix; P. Vann Bush; Stephen Niksa

2001-01-24T23:59:59.000Z

105

E-Print Network 3.0 - accidental carbon monoxide Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Health Collection: Biology and Medicine 33 Assessing and Modeling Exposure to Indoor Air Pollution among Rural Women in Guatemala Summary: pollution exposures to carbon...

106

E-Print Network 3.0 - accelerates carbon monoxide Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Health Collection: Biology and Medicine 31 Assessing and Modeling Exposure to Indoor Air Pollution among Rural Women in Guatemala Summary: pollution exposures to carbon...

107

NOx | OpenEI  

Open Energy Info (EERE)

NOx NOx Dataset Summary Description Emissions from energy use in buildings are usually estimated on an annual basis using annual average multipliers. Using annual numbers provides a reasonable estimation of emissions, but it provides no indication of the temporal nature of the emissions. Therefore, there is no way of understanding the impact on emissions from load shifting and peak shaving technologies such as thermal energy storage, on-site renewable energy, and demand control. Source NREL Date Released April 11th, 2011 (3 years ago) Date Updated April 11th, 2011 (3 years ago) Keywords buildings carbon dioxide emissions carbon footprinting CO2 commercial buildings electricity emission factors ERCOT hourly emission factors interconnect nitrogen oxides NOx SO2 sulfur dioxide emissions

108

States of cobalt and iron in catalysts supported in TiO{sub 2} from data of diffuse reflectance IR spectra of adsorbed carbon monoxide  

SciTech Connect (OSTI)

The variations in the oxidation states of cobalt and iron atoms in pure and mixed Co- and Fe-containing catalysts supported on TiO{sub 2} as a function of the conditions in which the catalysts were prepared and preliminarily treated were studied by analysis of the IR spectra of carbon monoxide adsorbed on these catalysts. A mutual influence of the components was discovered; iron was found to promote reduction of cobalt.

Davydov, A.A. [G.K. Boreskov Inst. of Catalysis, Novosibirsk (Russian Federation); Coville, N. [Univ. of the Wiswatersrand Wits, Johannesburg (South Africa)

1995-10-01T23:59:59.000Z

109

Relation between surface adsorption states and emf in a solid electrolyte concentration cell during carbon monoxide oxidation on platinum studied by local current measurement  

SciTech Connect (OSTI)

The importance of measuring adsorption during surface catalysis has been emphasized often. This is true for the oxidation of carbon monoxide on a platinum surface. Surface adsorption states during the reaction under steady states can be learned from electromotive force (emf) measurement with appropriate assumptions. Two mechanisms for emf generation have been proposed, one is that only oxygen activity generates emf, the other is that both oxygen and CO adsorption generates emf.

Okamoto, H.; Kawamura, G.; Kudo, T.

1984-04-01T23:59:59.000Z

110

Effect of the type of carrier on the properties of cobalt catalysts in the synthesis of aliphatic hydrocarbons from carbon monoxide and hydrogen  

SciTech Connect (OSTI)

The properties of catalysts used in the synthesis of hydrocarbons from CO and H/sub 2/ are determined to a significant degree by the carriers used in their preparation. This paper deals with a study of the effect of the type of carrier on the properties of cobalt-based catalysts in the synthesis of aliphatic hydrocarbons from CO and H/sub 2/. Co catalysts that are active in the synthesis of hydrocarbons from CO and H/sub 2/ are those on which the adsorption of H/sub 2/ exceeds 3.10/sup -2/ mmole/g Co and the adsorptin of carbon monoxide exceeds 7.10/sup -2/ mmole/g Co. Carbon monoxide and hydrogen are adsorbed on active catalysts in weakly bound forms. A mechanism is proposed for the formatin of an active center and the adsorption of carbon monoxide on Co-catalysts which includes the appearance of a partial positive charge on the cobalt atom.

Lapidus, A.L.; Jem, H.C.; Krylova, A.Y.

1983-04-10T23:59:59.000Z

111

Kinetics and mechanisms of interactions of nitrogen and carbon monoxide with liquid niobium  

SciTech Connect (OSTI)

The kinetics and mechanisms of interactions of N{sub 2} and CO with liquid niobium were investigated in the temperature range of 2,700 to 3,000 K in samples levitated in N{sub 2}/Ar and CO/Ar streams. The nitrogen absorption and desorption processes were found to be second-order with respect to nitrogen concentration, indicating that the rate controlling step is either the adsorption of nitrogen molecules on the liquid surface or dissociation of absorbed nitrogen molecules into adsorbed atoms. The carbon and oxygen dissolution in liquid niobium from CO gas is an exothermic process and the solubilities of carbon and oxygen (C{sub Ce}, C{sub Oe} in at%) are related to the temperature and the partial pressure of CO. The reaction CO {yields} (C) + (O) along with the evaporation of niobium oxide takes place during C and O dissolution, whereas C and O desorption occurs via CO evolution only.

Park, H.G.

1990-01-01T23:59:59.000Z

112

Catalysts for the production of hydrocarbons from carbon monoxide and water  

DOE Patents [OSTI]

A method of converting low H.sub.2 /CO ratio syngas to carbonaceous products comprising reacting the syngas with water or steam at 200.degree. to 350.degree. C. in the presence of a metal catalyst supported on zinc oxide. Hydrocarbons are produced with a catalyst selected from cobalt, nickel or ruthenium and alcohols are produced with a catalyst selected from palladium, platinium, ruthenium or copper on the zinc oxide support. The ratio of the reactants are such that for alcohols and saturated hydrocarbons: (2n+1).gtoreq.x.gtoreq.O and for olefinic hydrocarbons: 2n.gtoreq.x.gtoreq.O where n is the number of carbon atoms in the product and x is the molar amount of water in the reaction mixture.

Sapienza, Richard S. (Shoreham, NY); Slegeir, William A. (Hampton Bays, NY); Goldberg, Robert I. (Selden, NY)

1987-01-01T23:59:59.000Z

113

Catalysts for the production of hydrocarbons from carbon monoxide and water  

DOE Patents [OSTI]

A method of converting low H/sub 2//CO ratio syngas to carbonaceous products comprising reacting the syngas with water or steam at 200 to 350/sup 0/C in the presence of a metal catalyst supported on zinc oxide. Hydrocarbons are produced with a catalyst selected from cobalt, nickel or ruthenium and alcohols are produced with a catalyst selected from palladium, platinum, ruthenium or copper on the zinc oxide support. The ratio of the reactants are such that for alcohols and saturated hydrocarbons: (2n + 1) greater than or equal to x greater than or equal to O and for olefinic hydrocarbons: 2n greater than or equal to x greater than or equal to O where n is the number of carbon atoms in the product and x is the molar amount of water in the reaction mixture.

Sapienza, R.S.; Slegeir, W.A.; Goldberg, R.I.

1985-11-06T23:59:59.000Z

114

Carbon monoxide line emission as a CMB foreground: tomography of the star-forming universe with different spectral resolutions  

E-Print Network [OSTI]

The rotational lines of carbon monoxide and the fine structure lines of CII and of the most abundant metals, emitted during the epoch of enhanced star formation in the universe, are redshifted in the frequency channels where the present-day and future CMB experiments are sensitive. We estimate the contribution to the CMB angular power spectrum by the emission in such lines in merging star-forming galaxies. We used the Lacey-Cole approach to characterize the distribution of the merging halos, together with a parametrization for the star formation rate in each of them. Using observational data from a sample of local, low-redshift, and high-redshift objects, we calibrated the luminosity in each line as a function of the star formation rate. We show that the correlation term arising from CO line emission is a significant source of foreground for CMB in a broad range of frequencies (in particular in the 20-60 GHz band) and for 1000

Mattia Righi; Carlos Hernandez-Monteagudo; Rashid Sunyaev

2008-07-24T23:59:59.000Z

115

Photochemical generation of carbon monoxide and hydrogen by reduction of carbon dioxide and water under visible light irradiation  

Science Journals Connector (OSTI)

...energy conversion with consumption of a pollutant, CO2...energy conversion with consumption of a pollutant, CO...energy conversion with consumption of a pollutant, CO2...energy by producing fuels (hydrogen, carbon...M) in the reaction vessel; the gas contained...

Jean-Marie Lehn; Raymond Ziessel

1982-01-01T23:59:59.000Z

116

Infrared spectroscopic studies of carbon monoxide adsorbed on a series of silica-supported copper catalysts in different oxidation states  

SciTech Connect (OSTI)

Infrared spectroscopy has been used to study the adsorption of carbon monoxide (358-493 K, 0.1-20 kPa) on four copper-on-silica (2-10 wt% Cu) catalysts prepared by the ion-exchange technique. The measurements are made for each sample in three different states: unreduced (predominantly Cu{sup 2+}), and reduced (Cu{sup 0}), and partially reoxidized in nitrous oxide (Cu{sup +}). On unreduced samples, a major absorption band between 2127 and 2132 cm{sup {minus}1} due to CO adsorbed on small CuO particles and a weak band at 2199 cm{sup {minus}1} due to CO on isolated Cu{sup 2+} ions incorporated in the silica surface have been identified. The former adsorption obeys a Langmuir isotherm with a heat of adsorption of 29 kJ/mol independent of CuO particle size and surface coverage. After catalyst reduction, the major absorption band lies between 2090 and 2113 cm{sup {minus}1} and arises from CO linearly bound to very small (1- to 5-nm) copper metal clusters. The observed frequency shifts indicate the presence of steps and terraces similar to low index Cu planes in very small particles (1- to 2-nm), and the presence of similar higher index Cu planes on larger clusters (2- to 5-nm). The absorption is described by a Freundlich isotherm with the heat of CO adsorption decreasing with coverage from 50 to 22 kJ/mol on bigger particles but more constant (27 to 22 kJ/mol) on small particles. A surface copper/CO atomic ratio increasing from 5 to 12 is established at equilibrium saturation between 358 and 493 K using extinction coefficients determined in this study. In the reduced catalysts, a weakly adsorbed ({Delta}H{sub a} = {minus}20 kJ/mol) species assigned to CO bound to isolated Cu{sup +} ions is also found and absorbs at 2175 cm{sup {minus}1}. The frequency of this band does not vary with catalyst loading and is not affected by reoxidation of the catalyst in nitrous oxide.

Kohler, M.A.; Wainwright, M.S.; Trimm, D.L.; Cant, N.W. (Macquarie Univ., New South Wales (Australia) Univ. of South Wales (Australia))

1989-05-01T23:59:59.000Z

117

NETL: Advanced NOx Emissions Control: Control Technology - Model for NOx  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Model for NOx Emissions in Biomass Cofiring Model for NOx Emissions in Biomass Cofiring Southern Research Institute is developing a validated tool or methodology to accurately and confidently design and optimize biomass-cofiring systems for full-scale utility boilers to produce the lowest NOX emissions and the least unburned carbon. The computer model will be validated through an extensive set of tests at the 6 MMBtu/hr pilot combustor in the Southern Company/Southern Research Institute Combustion Research Facility. Full-scale demonstration testing can be compared to the model for further validation. The project is designed to balance the development of a systematic and expansive database detailing the effects of cofiring parameters on NOx formation with the complementary modeling effort that will yield a capability to predict, and therefore optimize, NOx reductions by the selection of those parameters. The database of biomass cofiring results will be developed through an extensive set of pilot-scale tests at the Southern Company/Southern Research Institute Combustion Research Facility. The testing in this program will monitor NOx, LOI, and other emissions over a broad domain of biomass composition, coal quality, and cofiring injection configurations to quantify the dependence of NOx formation and LOI on these parameters. This database of cofiring cases will characterize an extensive suite of emissions and combustion properties for each of the fuel and injection configuration combinations tested.

118

NOx Adsorber (Lean NOx Trap) Fundamentals (Agreement #10049 ...  

Broader source: Energy.gov (indexed) [DOE]

NOx Adsorber (Lean NOx Trap) Fundamentals (Agreement 10049 - PNNL Project 47120) NOx Adsorber (Lean NOx Trap) Fundamentals (Agreement 10049 - PNNL Project 47120) Presentation...

119

Infrared spectra of carbon monoxide adsorbed on SiO sub 2 -supported lanthanide-Ni bimetallic catalysts and their catalytic properties  

SciTech Connect (OSTI)

Recently the surface properties of the lanthanide (rare earth) - transition metal intermetallics and lanthanide metal overlayers have attracted a growing interest from the point of view of technical applications in catalyst and hydrogen storage. However, despite the intrinsic interest and considerable potential of these novel materials, very little detailed work has been carried out with a view to unveiling the specific properties upon interactions of lanthanides with transition metals. It has been shown that Eu and Yb metals dissolve in liquid ammonia to yield homogeneous solutions containing the ammoniated electrons. When the transition metal powders are added to this solution, the metal powders react with the dissolved lanthanide metals in liquid ammonia to form novel bimetallic catalysts. Such a system can be used as a catalyst probe for studying the catalytic actions induced by interactions between the lanthanide and transition metals. The present investigation was extended to include a SiO{sub 2}-supported bimetallic systems obtained when Eu or Yb dissolved in liquid ammonia reacts with silica-supported Ni. Using Fourier transform (FT)-IR studies of adsorbed carbon monoxide the authors provided information about the way the surface components were disposed in this bimetallic system. Adsorbed carbon monoxide was used as a molecular probe for the nature of bimetallic surface since the IR spectra of adsorbed probe molecules directly reflected variations in the surface.

Imamura, Hayao; Sugimoto, Hiromi; Sakata, Yoshihisa; Tsuchiya, Susumu (Yamaguchi Univ., Ube (Japan))

1992-07-01T23:59:59.000Z

120

Increased combustion rate of chlorobenzene on Pt/?-Al2O3 in binary mixtures with hydrocarbons and with carbon monoxide  

Science Journals Connector (OSTI)

The catalytic combustion of chlorobenzene on a 2 wt.% Pt/?-Al2O3 catalyst in binary mixtures with various hydrocarbons (toluene, benzene, cyclohexane, cyclohexene, 1,4-cyclohexadiene, 2-butene, and ethene) and with carbon monoxide has been explored. For all binary mixtures used the (excess of) added hydrocarbon increased the rate of conversion of chlorobenzene. With 2-butene, T50% and T100% for chlorobenzene were reduced by 100 and 200°C, respectively. Toluene and ethene were almost equally efficient as 2-butene. Co-feeding benzene or carbon monoxide resulted in a much smaller decrease of the T50%. The additional heat and water production in hydrocarbon combustion may contribute to some extent to the observed rate acceleration, but removal of Cl from the surface due to the hydrocarbon appears to be the major factor. The co-feeding of hydrocarbons invariably reduced the output of polychlorinated benzenes, which are formed as byproducts in the combustion of chlorobenzene on Pt/?-Al2O3. Again, especially toluene, ethene, and 2-butene were very efficient. Benzene — as well as cyclohexane, cyclohexene, and 1,4-cyclohexadiene, which were converted in situ into benzene — was much less effective, due to chlorination of the aromatic nucleus. In chlorobenzene–CO mixtures the levels of polychlorinated benzenes were almost as high as with chlorobenzene per se. Removal of Cl from the surface (mainly in the form of HCl) by (non-aromatic) hydrocarbons is responsible for reducing the formation of byproducts.

R.W. van den Brink; R. Louw; P. Mulder

2000-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "nox carbon monoxide" from the National Library of EnergyBeta (NLEBeta).
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We encourage you to perform a real-time search of NLEBeta
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121

Final Technical Report "Catalytic Hydrogenation of Carbon Monoxide and Olefin Oxidation" Grant number : DE-FG02-86ER13615  

SciTech Connect (OSTI)

Title: Catalytic Hydrogenation of Carbon Monoxide and Olefin Oxidation Grant No. DE-FG02-86ER13615 PI: Wayland, B. B. (wayland@sas.upenn.edu) Abstract Development of new mechanistic strategies and catalyst materials for activation of CO, H2, CH4, C2H4, O2, and related substrates relevant to the conversion of carbon monoxide, alkanes, and alkenes to organic oxygenates are central objectives encompassed by this program. Design and synthesis of metal complexes that manifest reactivity patterns associated with potential pathways for the hydrogenation of carbon monoxide through metallo-formyl (M-CHO), dimetal ketone (M-C(O)-M), and dimetal dionyl (M-C(O)-C(O)-M) species is one major focus. Hydrocarbon oxidation using molecular oxygen is a central goal for methane activation and functionalization as well as regioselective oxidation of olefins. Discovery of new reactivity patterns and control of selectivity are pursued through designing new metal complexes and adjusting reaction conditions. Variation of reaction media promotes distinct reaction pathways that control both reaction rates and selectivities. Dimetalloradical diporphyrin complexes preorganize transition states for substrate reactions that involve two metal centers and manifest large rate increases over mono-metalloradical reactions of hydrogen, methane, and other small molecule substrates. Another broad goal and recurring theme of this program is to contribute to the thermodynamic database for a wide scope of organo-metal transformations in a range of reaction media. One of the most complete descriptions of equilibrium thermodynamics for organometallic reactions in water and methanol is emerging from the study of rhodium porphyrin substrate reactions in aqueous and alcoholic media. Water soluble group nine metalloporphyrins manifest remarkably versatile substrate reactivity in aqueous and alcoholic media which includes producing rhodium formyl (Rh-CHO) and hydroxy methyl (Rh-CH2OH) species. Exploratory directions for this program include expending new strategies for anti-Markovnikov addition of water, alcohols, and amines with olefins, developing catalytic reactions of CO to give formamides and formic esters, and evaluating the potential for coupling reactions of CO to produce organic building blocks.

Wayland, B.B.

2009-08-31T23:59:59.000Z

122

Quantum-chemical investigation of the interaction of nitrogen and carbon monoxide molecules with the Lewis acid sites of aluminium oxide  

SciTech Connect (OSTI)

Within the framework of the cluster approximation, using covalent and ionic models of Lewis acid sites of aluminumoxide, their electronic structure, as well as that of complexes of nitrogen and carbon monoxide molecules with them, was calculated. It was shown that the Lewis acid sites, representing a truncated tetrahedron, exhibit stronger electron-acceptor properties than the corresponding sites in the form of a truncated octahedron. For both molecules, the linear form of adsorption is energetically more profitable than the T-shaped form. The results obtained by the nonempirical SCF MO LCAO method in the STO-3GF basis and by semiempirical methods in CNDO/2 and INDO approximatations, are qualitatively the same.

Senchenya, I.N.; Chuvylkin, N.D.; Kazanskii, V.B.

1986-11-01T23:59:59.000Z

123

Studies on the sulfur poisoning of Ru-RuO{sub x}/TiO{sub 2} catalyst for the adsorption and methanation of carbon monoxide  

SciTech Connect (OSTI)

The effects of sulfur poisoning on the chemisorption and on the methanation of carbon monoxide over Ru/TiO{sub 2} catalyst were investigated by FTIR spectroscopy and volumetric gas adsorption measurements. The CS{sub 2} molecules are {eta}` bonded to Ru sites through one of the sulfur atoms and decompose to the constituent elements on thermal activation. Each S atom may deactivate 3 to 10 metal sites even at low coverages, the effect being more pronounced on the chemisorption of hydrogen. The deposited sulfur (and possibly carbon also) sterically hinders the formation of certain multicarbonyl and monocarbonyl species (vCO in 2055-2140 cm{sup -1} region), which otherwise transform to methane via surface methylene groups in the presence of chemisorbed hydrogen and are found to play an important role in the low-temperature methanation activity of the studied catalyst. The Ru-CO species giving rise to lower frequency vibrational bands are affected to a lesser extent. The presence of sulfur also results in the development of some new CO binding states which are weak and are identified with the CO and S coadsorbed at Ru sites of different oxidation states or of varying crystallographic nature. The CO adsorbed in these states is not reactive to hydrogen. 45 refs., 9 figs., 1 tab.

Kamble, V.S.; Londhe, V.P.; Gupta, N.M. [Bhambha Atomic Research centre, Bombay (India)] [and others] [Bhambha Atomic Research centre, Bombay (India); and others

1996-02-01T23:59:59.000Z

124

FTIR study of carbon monoxide oxidation and scrambling at room temperature over copper supported on ZnO and TiO{sub 2} No. 1  

SciTech Connect (OSTI)

An FTIR and quadrupole mass spectroscopic study of CO adsorption and oxidation with {sup 16}O{sub 2} and {sup 18}O{sub 2} on copper supported on ZnO and TiO{sub 2} is presented. The experimental results indicate that CO is adsorbed on the metallic particles dispersed on both oxides on two kinds of sites, on the normal terrace sites and on sites at the borderline of the particles. Moreover, on titania, a band at 2126 cm{sup -1}, assigned to CO adsorbed on isolated Cu atoms and/or on two-dimensional small clusters, is detected. A frequency shift of the bands of CO adsorbed on the metallic particles observed in the CO-O{sub 2} coadsorption experiments and the occurrence of a scrambling reaction between CO and {sup 18}O{sub 2} reveal that on all these samples, there are metallic sites which are able to adsorb at the same time oxygen atoms and carbon monoxide. Carbon dioxide and carbonate-like species are formed: the asymmetric stretching frequencies of CO{sub 2} and the quadrupole mass spectroscopic analysis reveal that with {sup 18}O{sub 2}, different isotopic molecular CO{sub 2}`s are formed, while the carbonate-like species have the same frequencies of those produced in {sup 16}O{sub 2}. Moreover, these species are completely lacking in the absence of oxygen in the gas phase. The experimental results indicate the there are, on these samples, two independent pathways for the CO oxidation, a direct oxidation of CO at the surface of the metallic particles and an induced oxidation with the surface lattice oxygen species of the supports. 46 refs., 8 figs.

Baccuzzi, F.; Chiorino, A. [Universita di Torino (Italy)] [Universita di Torino (Italy)

1996-02-29T23:59:59.000Z

125

Extending surface-enhanced Raman spectroscopy to transition-metal surfaces: carbon monoxide adsorption and electrooxidation on platinum- and palladium-coated gold electrodes  

SciTech Connect (OSTI)

Thin (ca. one to three monolayers) films of platinum and palladium electrodeposited on electrochemically roughened gold are observed to yield surface-enhanced Raman (SER) spectra for adsorbed carbon monoxide. The major vibrational band(s) on these surfaces are diagnosed from their frequencies as arising from C-O stretching vibrations, nu/sub CO/ bound to the transition-metal overlayers rather than to residual gold sites. The observed SFR nu/sub CO/ frequencies are closely similar to (within ca. 10 cm/sup -1/ of) those obtained for these systems from potential-difference infrared (PDIR) spectra. The major SERS and PDIR nu/sub CO/ features for the platinum and palladium surfaces appear at 2060-2090 and 1965-1985 cm/sup -1/, respectively, consistent with the presence of terminal and bridging CO on these two electrodes. The infrared as well as electrochemical properties of these systems are closely similar to those for the corresponding polycrystalline bulk electrodes. A difference between the SER- and IR-active adsorbed CO, however, is that the former undergoes electrooxidation on both surfaces at 0.2-0.3 V higher overpotentials than the latter form. Examination of the potential-dependent SERS bands for metal oxide vibrations, nu/sub PtO/, on the platinum surface shows that the electrooxidation potential for the SERS-active adsorbed CO coincides with that for the appearance of the nu/sub PtO/ band. Some broader implications to the utilization of SERS for examining transition-metal surfaces are pointed out.

Leung, L.W.H.; Weaver, M.J.

1987-08-19T23:59:59.000Z

126

Chemisorption and catalysis by metal clusters. II. Chemisorption of carbon monoxide and of oxygen by supported osmium clusters derived from Os/sub 3/(CO)/sub 12/ and from Os/sub 6/(CO)/sub 18/  

SciTech Connect (OSTI)

Carbon monoxide and oxygen have been chemisorbed at 293 K on the high-nuclearity carbonyl-protected clusters (the various species A) obtained by heating in vacuo to 523 K Os/sub 3/(CO)/sub 12/ or Os/sub 6/(CO)/sub 18/ impregnated on silica, alumina, or titania. The adsorption isotherms have a conventional appearance, but most are composed of a primary and a secondary region. Material adsorbed in the secondary region is removed by evacuation at room temperature whereas that adsorbed in the primary region is removed by evacuation at elevated temperatures. For species A/alumina and the species A/titania the primary region is complete and the secondary region commences when the pressure over the adsorbent is 0.2 Torr. Species A/silica gave no secondary region in oxygen adsorption. Adsorption and subsequent temperature-programmed desorption of (/sup 18/O)CO occurred without any dilution by (/sup 16/O)CO, indicating that ligand-(/sup 16/O)CO and adsorbed-(/sup 18/O)CO do not exchange even at elevated temperatures. The two species A/aluminas catalyzed oxygen isotope exchange at 293 K. From the experimental evidence it is deduced that carbon monoxide and oxygen each adsorbs molecularly in both the primary and the secondary regions. In the primary region carbon monoxide adsorption occurs at osmium sites on the cluster framework, whereas in the secondary region it occurs at ligand-carbon bonded to osmium. For oxygen, adsorption in the primary region is again at osmium sites on the cluster framework but that in the secondary region is at osmium sites of the cluster framework suitably modified as a result of the support-cluster interaction.

Hunt, D.J.; Jackson, S.D.; Moyes, R.B.; Wells, P.B.; Whyman, R.

1984-04-01T23:59:59.000Z

127

Low NOx combustion  

SciTech Connect (OSTI)

Combustion of hydrocarbon liquids and solids is achieved with less formation of NOx by feeding a small amount of oxygen into the fuel stream.

Kobayashi; Hisashi (Putnam Valley, NY), Bool, III; Lawrence E. (Aurora, NY)

2007-06-05T23:59:59.000Z

128

Low NOx combustion  

SciTech Connect (OSTI)

Combustion of hydrocarbon liquids and solids is achieved with less formation of NOx by feeding a small amount of oxygen into the fuel stream.

Kobayashi, Hisashi (Putnam Valley, NY); Bool, III, Lawrence E. (Aurora, NY)

2008-10-21T23:59:59.000Z

129

Studies of the coadsorption of deuterium and carbon monoxide with silver on rhodium and the adsorption of 2,4,6-trinitrotoluene on clean and carbon covered platinum  

SciTech Connect (OSTI)

Ag adsorbed on Rh(100) is presented as a model of the corresponding bimetallic catalyst. Ag overlayer growth follows the Frank-Van der Merwe growth mechanism at 300 K and the Stranski-Krastanov growth mechanism at 640 K. Ag(3d) binding energies are found to track the vacuum level rather than the Fermi level. The results of D/sub 2/ and CO adsorption studies on Ag/Rh(100) show that adsorbed Ag does not significantly alter the properties of adjacent D/sub 2/ or CO adsorption sites on the Rh(100) surface. The desorption and decomposition of 2,4,6-trinitrotoluene (TNT) on clean and carbon covered Pt(111) is also reported. No evidence for TNT decomposition on the carbon covered surface is found. Molecular TNT desorption kinetics at low coverage are first order, yielding an activation energy of 16.7 +/- 1 Kcal/mol and a preexponential factor of 2.3 x 10/sup 11/ (x e/sup - + 0.5/) sec/sup -1/. TNT adsorbed on the clean Pt(111) surface at submonolayer coverages undergoes almost complete decomposition during heating. The major decomposition products are H/sub 2/O, NO, CO/sub 2/, CO, HCN, and a carbon residue left on the surface. TNT adsorbed in the second and higher monolayers desorbs molecularly. The significance of these results in understanding the performance of a commercial explosive vapor preconcentrator is discussed.

Peebles, H.C.

1983-01-01T23:59:59.000Z

130

\\{NOx\\} reduction from a large bore natural gas engine via reformed natural gas prechamber fueling optimization  

Science Journals Connector (OSTI)

Lean combustion is a standard approach used to reduce \\{NOx\\} emissions in large bore (35–56 cm) stationary natural gas engines. However, at lean operating points, combustion instabilities and misfires give rise to high total hydrocarbon (THC) and carbon monoxide (CO) emissions. To counteract this effect, precombustion chamber (PCC) technology is employed to allow engine operation at an overall lean equivalence ratio while mitigating the rise of THC and CO caused by combustion instability and misfires. A PCC is a small chamber, typically 1–2% of the clearance volume. A separate fuel line supplies gaseous fuel to the PCC and a standard spark plug ignites the slightly rich mixture (equivalence ratio 1.1–1.2) in the PCC. The ignited PCC mixture enters the main combustion chamber as a high energy flame jet, igniting the lean mixture in the main chamber. Typically, natural gas fuels both the main chamber and the PCC. In the current research, a mixture of reformed natural gas (syngas) and natural gas fuels the PCC. Syngas is a broad term that refers to a synthetic gaseous fuel. In this case, syngas specifically denotes a mixture of hydrogen, carbon monoxide, nitrogen, and methane generated in a natural gas reformer. Syngas has a faster flame speed and a wider equivalence ratio range of operation than methane. Fueling the PCC with Syngas reduces combustion instabilities and misfires. This extends the overall engine lean limit, enabling further \\{NOx\\} reductions. Research results presented are aimed at quantifying the benefits of syngas PCC fueling. A model is developed to calculate the equivalence ratio in the PCC for different mixtures and flowrates of fuel. An electronic injection valve is used to supply the PCC with syngas. The delivery pressure, injection timing, and flow rate are varied to optimize PCC equivalence ratio. The experimental results show that supplying the PCC with 100% syngas improves combustion stability by 21% compared to natural gas PCC fueling. A comparison at equivalent combustion stability operating points between 100% syngas and natural gas shows an 87% reduction in \\{NOx\\} emissions for 100% syngas PCC fueling compared to natural gas PCC fueling.

Mathew D. Ruter; Daniel B. Olsen; Mark V. Scotto; Mark A. Perna

2012-01-01T23:59:59.000Z

131

OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL  

SciTech Connect (OSTI)

Conventional wisdom says adding oxygen to a combustion system enhances product throughput, system efficiency, and, unless special care is taken, increases NOx emissions. This increase in NOx emissions is typically due to elevated flame temperatures associated with oxygen use leading to added thermal NOx formation. Innovative low flame temperature oxy-fuel burner designs have been developed and commercialized to minimize both thermal and fuel NOx formation for gas and oil fired industrial furnaces. To be effective these systems require close to 100% oxy-fuel combustion and the cost of oxygen is paid for by fuel savings and other benefits. For applications to coal-fired utility boilers at the current cost of oxygen, however, it is not economically feasible to use 100% oxygen for NOx control. In spite of this conventional wisdom, Praxair and its team members, in partnership with the US Department of Energy National Energy Technology Laboratory, have developed a novel way to use oxygen to reduce NOx emissions without resorting to complete oxy-fuel conversion. In this concept oxygen is added to the combustion process to enhance operation of a low NOx combustion system. Only a small fraction of combustion air is replaced with oxygen in the process. By selectively adding oxygen to a low NOx combustion system it is possible to reduce NOx emissions from nitrogen-containing fuels, including pulverized coal, while improving combustion characteristics such as unburned carbon. A combination of experimental work and modeling was used to define how well oxygen enhanced combustion could reduce NOx emissions. The results of this work suggest that small amounts of oxygen replacement can reduce the NOx emissions as compared to the air-alone system. NOx emissions significantly below 0.15 lbs/MMBtu were measured. Oxygen addition was also shown to reduce carbon in ash. Comparison of the costs of using oxygen for NOx control against competing technologies, such as SCR, show that this concept offers substantial savings over SCR and is an economically attractive alternative to purchasing NOx credits or installing other conventional technologies. In conjunction with the development of oxygen based low NOx technology, Praxair also worked on developing the economically enhancing oxygen transport membrane (OTM) technology which is ideally suited for integration with combustion systems to achieve further significant cost reductions and efficiency improvements. This OTM oxygen production technology is based on ceramic mixed conductor membranes that operate at high temperatures and can be operated in a pressure driven mode to separate oxygen with infinite selectivity and high flux. An OTM material was selected and characterized. OTM elements were successfully fabricated. A single tube OTM reactor was designed and assembled. Testing of dense OTM elements was conducted with promising oxygen flux results of 100% of target flux. However, based on current natural gas prices and stand-alone air separation processes, ceramic membranes do not offer an economic advantage for this application. Under a different DOE-NETL Cooperative Agreement, Praxair is continuing to develop oxygen transport membranes for the Advanced Boiler where the economics appear more attractive.

David R. Thompson; Lawrence E. Bool; Jack C. Chen

2004-04-01T23:59:59.000Z

132

FTIR study of hydrogen and carbon monoxide adsorption on Pt/TiO{sub 2}, Pt/ZrO{sub 2}, and Pt/Al{sub 2}O{sub 3}  

SciTech Connect (OSTI)

The Pt/TiO{sub 2}, Pt/ZrO{sub 2}, and Pt/Al{sub 2}O{sub 3} catalysts submitted to low-temperature reduction (LTR,200 C) and high-temperature reduction (HTR, 500 C) and exposed to hydrogen and carbon monoxide at room temperature were studied by infrared spectroscopy. There is a strong loss of transmission in the entire infrared spectra on Pt/TiO{sub 2} after its exposure to hydrogen, which is related to the reducibility of the support. A typical SMSI behavior (strong metal-support interaction), such as the decrease in carbon monoxide adsorption capacity, was detected on Pt/TiO{sub 2} and Pt/ZrO{sub 2} after exposure to hydrogen, even for the catalysts submitted to LTR treatment. Also a carbonyl band shift to lower wavenumber was observed on LTR-treated Pt/TiO{sub 2}, Pt/ZrO{sub 2}, and Pt/Al{sub 2}O{sub 3} after exposure to hydrogen. The authors interpreted this SMSI behavior as an electronic rather than morphological effect, which was induced by the presence of hydrogen spillover.

Benvenutti, E.V.; Franken, L.; Moro, C.C.; Davanzo, C.U.

1999-11-09T23:59:59.000Z

133

Visible-Light Photoredox Catalysis: Selective Reduction of Carbon Dioxide to Carbon Monoxide by a Nickel N-Heterocyclic Carbene-Isoquinoline Complex  

SciTech Connect (OSTI)

The solar-driven reduction of carbon dioxide to value-added chemical fuels is a longstanding challenge in the fields of catalysis, energy science, and green chemistry. In order to develop effective CO2 fixation, several key considerations must be balanced, including (1) catalyst selectivity for promoting CO2 reduction over competing hydrogen generation from proton reduction, (2) visible-light harvesting that matches the solar spectrum, and (3) the use of cheap and earth-abundant catalytic components. In this report, we present the synthesis and characterization of a new family of earth-abundant nickel complexes supported by N-heterocyclic carbene amine ligands that exhibit high selectivity and activity for the electrocatalytic and photocatalytic conversion of CO2 to CO. Systematic changes in the carbene and amine donors of the ligand have been surveyed, and [Ni(Prbimiq1)]2+ (1c, where Prbimiq1 = bis(3-(imidazolyl)isoquinolinyl)propane) emerges as a catalyst for electrochemical reduction of CO2 with the lowest cathodic onset potential (Ecat = 1.2 V vs SCE). Using this earth-abundant catalyst with Ir(ppy)3 (where ppy = 2-phenylpyridine) and an electron donor, we have developed a visible-light photoredox system for the catalytic conversion of CO2 to CO that proceeds with high selectivity and activity and achieves turnover numbers and turnover frequencies reaching 98,000 and 3.9 s1, respectively. Further studies reveal that the overall efficiency of this solar-to-fuel cycle may be limited by the formation of the active Ni catalyst and/or the chemical reduction of CO2 to CO at the reduced nickel center and provide a starting point for improved photoredox systems for sustainable carbon-neutral energy conversion.

Thoi, VanSara; Kornienko, Nick; Margarit, C; Yang, Peidong; Chang, Christopher

2013-06-07T23:59:59.000Z

134

The structure of adsorbed sulfur and carbon on molybdenum and rhenium single crystal surfaces, and their influence on carbon monoxide and hydrocarbon chemisorption  

SciTech Connect (OSTI)

An ultra-high vacuum (10/sup -10/ Torr) study was performed on the chemisorption and structures of S and C adsorbates on Mo(100), Re(0001), and Re(1010) single crystal surfaces. Both S and C adsorb strongly on Mo(100), Re(0001), and Re(1010), with adsorption energies >70 kcal/mol for coverages less than saturation. S was proposed to adsorb in the highest symmetry sites on all surfaces except for theta/sub s/ > 0.75 on Mo(100), where studies suggest two different adsorption sites. C adsorbs in a ''carbidic'' or active phase on Mo(100), where it is also proposed to adsorb in the highest symmetry sites. However, C adsorbs in a ''graphitic'' or inactive phase on Re(0001) and Re(1010). CO chemisorption on the S and C overlayers was found to be blocked (except for C on Mo(100)), with S blocking adsorption more efficiently than C. Changes in adsorption energy were determined to be caused by local crowding of CO molecules by S or C, rather than a long-range electronic interaction. Unsaturated hydrocarbons decomposed completely on Mo(100), Re(0001), and Re(1010). Similar to the results for CO chemisorption, strong adsorption of unsaturated hydrocarbons (leading to decomposition) was blocked by pre-adsorbed S, allowing only physisorption to occur (adsorption energies < 11 kcal/mol). The effect of pre-adsorbed ''graphitic'' C on Re(0001) and Re(1010) on unsaturated hydrocarbon chemisorption was the same; strong adsorption (leading to decomposition) was blocked allowing only physisorption. However, Mo(100) with pre-adsorbed ''carbidic'' carbon blocks only decomposition while allowing strong reversible molecular chemisorption (12 to 23 kcal/mol). Differences in inhibition efficiency of S and C are proposed to be caused by differences in bond distances of the adsorbates to the surface. Greater distance from the metal surface causes more interaction with neighboring metal atoms. These differences also suggest explanations for catalytic hydrodesulfurization of thiophene.

Kelly, D.G.

1987-08-01T23:59:59.000Z

135

Synthesis and reactivity of sterically congested metallacyclobutenes and metal-mediated carbon-sulfur bond activation  

E-Print Network [OSTI]

methods for this conversion typically involve the production of byproducts like carbon monoxide and hydrogen

Vélez, Carmen L.

2011-01-01T23:59:59.000Z

136

Exhaust-catalyst development for methanol-fueled vehicles. II. Synergism between palladium and silver in methanol and carbon monoxide oxidation over an alumina-supported palladium-silver catalyst  

SciTech Connect (OSTI)

Methanol and carbon monoxide oxidation were examined over 0.01 Pd, 5% Ag, and 0.01% Pd/5% Ag catalysts - all supported on ..gamma..-alumina. The bimetallic catalyst showed greater CO and CH/sub 3/OH oxidation activity than either of the single-component catalysts; moreover, the Pd and Ag interacted synergistically in the bimetallic catalyst to produce greater CO and CH/sub 3/OH oxidation rates and lower yields of methanol partial oxidation products than expected from a mixture of the single-component catalysts. Temperature-programmed oxidation experiments and reactivity experiments involving changes in O/sub 2/ partial pressure both provided evidence that the Pd-Ag synergism results from Pd promoting the rate of O/sub 2/ adsorption and reaction with CO and CH/sub 3/OH on Ag. The data also indicate that virtually all of the Pd in the bimetallic catalyst is present in Pd-Ag crystallites.

McCabe, R.W.; Mitchell, P.J.

1987-02-01T23:59:59.000Z

137

NOx Reduction from Biodiesel Fuels  

Science Journals Connector (OSTI)

NOx Reduction from Biodiesel Fuels ... NOx emissions appear to be different for biodiesels from different feedstocks. ... For the suite of biodiesels prepared from nearly pure fatty acids, all biodiesel fuels produced higher NOx than certification diesel with the following exceptions:? methyl palmitate, methyl laurate, ethyl stearate, and the ethyl ester of hydrogenated soybean oil. ...

Sandun Fernando; Chris Hall; Saroj Jha

2005-11-19T23:59:59.000Z

138

Enhanced Combustion Low NOx Pulverized Coal Burner  

SciTech Connect (OSTI)

For more than two decades, Alstom Power Inc. (Alstom) has developed a range of low cost, infurnace technologies for NOx emissions control for the domestic U.S. pulverized coal fired boiler market. This includes Alstom's internally developed TFS 2000{trademark} firing system, and various enhancements to it developed in concert with the U.S. Department of Energy. As of the date of this report, more than 270 units representing approximately 80,000 MWe of domestic coal fired capacity have been retrofit with Alstom low NOx technology. Best of class emissions range from 0.18 lb/MMBtu for bituminous coal to 0.10 lb/MMBtu for subbituminous coal, with typical levels at 0.24 lb/MMBtu and 0.13 lb/MMBtu, respectively. Despite these gains, NOx emissions limits in the U.S. continue to ratchet down for new and existing boiler equipment. On March 10, 2005, the Environmental Protection Agency (EPA) announced the Clean Air Interstate Rule (CAIR). CAIR requires 25 Eastern states to reduce NOx emissions from the power generation sector by 1.7 million tons in 2009 and 2.0 million tons by 2015. Low cost solutions to meet such regulations, and in particular those that can avoid the need for a costly selective catalytic reduction system (SCR), provide a strong incentive to continue to improve low NOx firing system technology to meet current and anticipated NOx control regulations. The overall objective of the work is to develop an enhanced combustion, low NOx pulverized coal burner, which, when integrated with Alstom's state-of-the-art, globally air staged low NOx firing systems will provide a means to achieve: Less than 0.15 lb/MMBtu NOx emissions when firing a high volatile Eastern or Western bituminous coal, Less than 0.10 lb/MMBtu NOx emissions when firing a subbituminous coal, NOx reduction costs at least 25% lower than the costs of an SCR, Validation of the NOx control technology developed through large (15 MWt) pilot scale demonstration, and Documentation required for economic evaluation and commercial application. During the project performance period, Alstom performed computational fluid dynamics (CFD) modeling and large pilot scale combustion testing in its Industrial Scale Burner Facility (ISBF) at its U.S. Power Plant Laboratories facility in Windsor, Connecticut in support of these objectives. The NOx reduction approach was to optimize near-field combustion to ensure that minimum NOx emissions are achieved with minimal impact on unburned carbon in ash, slagging and fouling, corrosion, and flame stability/turn-down. Several iterations of CFD and combustion testing on a Midwest coal led to an optimized design, which was extensively combustion tested on a range of coals. The data from these tests were then used to validate system costs and benefits versus SCR. Three coals were evaluated during the bench-scale and large pilot-scale testing tasks. The three coals ranged from a very reactive subbituminous coal to a moderately reactive Western bituminous coal to a much less reactive Midwest bituminous coal. Bench-scale testing was comprised of standard ASTM properties evaluation, plus more detailed characterization of fuel properties through drop tube furnace testing and thermogravimetric analysis. Bench-scale characterization of the three test coals showed that both NOx emissions and combustion performance are a strong function of coal properties. The more reactive coals evolved more of their fuel bound nitrogen in the substoichiometric main burner zone than less reactive coal, resulting in the potential for lower NOx emissions. From a combustion point of view, the more reactive coals also showed lower carbon in ash and CO values than the less reactive coal at any given main burner zone stoichiometry. According to bench-scale results, the subbituminous coal was found to be the most amenable to both low NOx, and acceptably low combustibles in the flue gas, in an air staged low NOx system. The Midwest bituminous coal, by contrast, was predicted to be the most challenging of the three coals, with the Western bituminous coal predicted to beh

David Towle; Richard Donais; Todd Hellewell; Robert Lewis; Robert Schrecengost

2007-06-30T23:59:59.000Z

139

Sulfur tolerant molten carbonate fuel cell anode and process  

DOE Patents [OSTI]

Molten carbonate fuel cell anodes incorporating a sulfur tolerant carbon monoxide to hydrogen water-gas-shift catalyst provide in situ conversion of carbon monoxide to hydrogen for improved fuel cell operation using fuel gas mixtures of over about 10 volume percent carbon monoxide and up to about 10 ppm hydrogen sulfide.

Remick, Robert J. (Naperville, IL)

1990-01-01T23:59:59.000Z

140

A DFT Study of Interaction of Carbon Monoxide with Carbonaceous Materials Juan F. Espinal, Alejandro Montoya, Fanor Mondragon,*, and Thanh N. Truong*,  

E-Print Network [OSTI]

is an important process in the gasification of carbon materials such as char, coke, soot, as well as in the growth it is a clean and efficient alternative to the use of coal instead of combustion. The gasification process

Truong, Thanh N.

Note: This page contains sample records for the topic "nox carbon monoxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Measurement and Characterization of NOx Adsorber Regeneration...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Combustion with Lean-NOx Trap Yields Progress Toward Targets of Efficient NOx Control for Diesels Intra-catalyst Reductant Chemistry in Lean NOx Traps: A Study on Sulfur Effects...

142

Use of carbon monoxide and third-derivative EPR spectra to probe the coordination of surface V/sup 4 +/ ions on reduced V/sub 2/O/sub 5//SiO/sub 2/ catalysts  

SciTech Connect (OSTI)

The coordination properties of surface V/sup 4 +/ ions of reduced V/sub 2/O/sub 5/ supported on silica have been studied by EPR using the adsorption of various probe molecules. The spectrum resolution, greatly enhanced with the third-derivative presentation, indicates an orthorhombic symmetry for the V/sup 4 +/ ions after CO adsorption (g/sub 1/ approx. g/sub 2/ = 1.985, g/sub 3/ = 1.931, A/sub 1/ approx. A/sub 2/ 71.4 G, A/sub 3/ = 191.4 G). The use of /sup 13/C-enriched carbon monoxide allows us to observe that the V/sup 4 +/ surface ions can coordinate two CO molecules from the gas phase to form, together with four lattice oxide ions, a distorted octahedron with one pronounced vanadyl character bond. The /sup 13/C superhyperfine coupling constant is found to be about 7 G. The influence of the adsorbed molecules (CO, H/sub 2/O, C/sub 2/H/sub 4/) on the properties of the V/sup 4 +/ ions at the surface is further discussed. 33 references, 4 figures, 1 table.

Che, M.; Canosa, B.; Gonzalez-Elipe, A.R.

1986-02-13T23:59:59.000Z

143

NETL: Advanced NOx Emissions Control: Control Technology - NOx Emissions  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Emissions from Multi-Burners Emissions from Multi-Burners The University of Utah working with Reaction Engineering International and Brigham Young University is investigating a project that consists of integrated experimental, theoretical and computational modeling efforts. The primary objective is to evaluate NOx formation/destruction processes as they occur in multi-burner arrays, a geometry almost always utilized in utility practice. Most controlled experimental work examining NOx has been conducted on single burners. The range of potential intra-burner interactions are likely to provide added degrees of freedom for reducing NOx. The resultant findings may allow existing utilities to arrange fuel and air distribution to minimize NOx. In new applications, orientation of individual burners within an array may also be altered to reduce NOx. Comprehensive combustion codes will be modified to incorporate the latest submodels of nitrogen release and heterogeneous chemistry. Comparison of pilot scale experiments and simulations will be utilized to validate/develop theory.

144

Compact Potentiometric NOx Sensor | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Potentiometric NOx Sensor Compact Potentiometric NOx Sensor 2011 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation...

145

9, 11231155, 2009 Lightning NOx  

E-Print Network [OSTI]

of lightning intensities. By im-20 posing an updated lightning NO production value of 520 mol NO/Flash, weACPD 9, 1123­1155, 2009 Lightning NOx emissions over the USA investigated using TES L. Jourdain et to the corresponding final paper in ACP if available. Lightning NOx emissions over the USA investigated using TES, NLDN

146

Controlling NOx to Obtain Offsets or Meet Compliance  

E-Print Network [OSTI]

monitored and regu lated a number of pollutants: lead, carbon monoxide, oxides of sulfur, oxides of nitrogen, ozone and PM-lO. The Clean Air Act Amendments increased the focus on these pollutants, mandating the reductions to specified limits. Title I...

Mincy, J. E.

147

Interaction of carbon monoxide with oxygen in the adsorbed layer on Pd, Ce, Pd-Ce catalysts supported on /gamma/-Al/sub 2/O/sub 3/  

SciTech Connect (OSTI)

The adsorption of CO and the interaction of CO/sub ads/ with O/sub 2/ on Pd, Ce, and Pd-Ce//gamma/-Al/sub 2/O/sub 3/ (0.5 wt. % Pd, 2.0 wt. % Ce) has been studied using the methods of IR spectroscopy and differential scanning calorimetry. The identity of the adsorbed CO complexes, the temperature ranges over which they desorb, and their reactivity with O/sub 2/ have been established. The interaction of bridging and carbonate - carboxylate CO complexes and carbon (disproportionation and dissociation products) with O/sub 2/ on Pd and Pd-Ce catalysts is preceded by the coadsorption of oxygen and the evolution of heat. During the oxidation of CO, autooscillation, heat evolution, and the concentration of oxygen in the flow are observed.

Savel'eva, G.A.; Sass, A.S.; Speranskaya, G.V.; Tenchev, K.K.; Petrov, L.A.; Vozdvizhenskii, V.F.; Galeev, T.K.; Popova, N.M.

1989-01-01T23:59:59.000Z

148

Nox1 and Nox4 enzymes are persistently elevated in human hepatocytes producing infectious hepatitis C virus  

E-Print Network [OSTI]

location of NOX4 and NOX1 enzymes by cell fractionation. 6.13. Proposed role of hepatocyte NOX enzymes in HCV-inducedMERCED Nox1 and Nox4 enzymes are persistently elevated in

Reyes de Mochel, Nabora Soledad

2009-01-01T23:59:59.000Z

149

Conversion of carbon monoxide on membrane catalysts of palladium alloys. I. Reaction between CO and H/sub 2/ on binary palladium alloys with ruthenium and nickel  

SciTech Connect (OSTI)

The formation of saturated and unsaturated C/sub 1/ and C/sub 2/ hydrocarbons, carbon dioxide and water is observed during reaction CO and H/sub 2/ on binary palladium alloys with 10 wt. % of Ru and 5.5 wt. % Ni at atmospheric pressure and 523-683 K. The introduction of hydrogen into the reaction zone by different methods, bu diffusion through a membrane catalyst or in a mixture with CO, influences the activity and selectivity of the catalysts investigated.

Gur'yanova, O.S.; Serov, Yu.M.; Gyl'yanova, S.G.; Gryaznov, V.M.

1989-01-01T23:59:59.000Z

150

NETL: Advanced NOx Emissions Control: Control Technology - Optimized Fuel  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Optimized Fuel Injector Design Optimized Fuel Injector Design This project includes fundamental research and engineering development of low NOx burners and reburning fuel injectors. The team of Reaction Engineering International (REI), the University of Utah, Brown University and DB Riley, Inc., will develop fundamental information on low NOx burners. The work has two phases. In the first phase, the University of Utah will examine two-phase mixing and near-field behavior of coal injectors using a 15-million Btu/hr bench-scale furnace, Brown University will examine char deactivation and effectiveness of reburning, and REI will develop a comprehensive burner model using the data produced by the University of Utah and Brown University. In the second phase, an optimized injector design will be tested at the 100-million Btu/hr Riley Coal Burner Test Facility. It is anticipated that this work will provide improved hardware designs and computer simulation models for reduced NOx emissions and minimized carbon loss.

151

Transient Dynamometer Testing of a Single Leg NOx Adsorber Combined...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Transient Dynamometer Testing of a Single Leg NOx Adsorber Combined with a Fuel Processor for Enhanced NOx Control Transient Dynamometer Testing of a Single Leg NOx Adsorber...

152

Benchmark Reaction Mechanisms and Kinetics for Lean NOx Traps...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Benchmark Reaction Mechanisms and Kinetics for Lean NOx Traps Development of Chemical Kinetic Models for Lean NOx Traps Modeling the Regeneration Chemistry of Lean NOx Traps...

153

Control of NOx by combustion process modifications  

E-Print Network [OSTI]

A theoretical and experimental study was carried out to determine lower bounds of NOx emission from staged combustion of a 0.7%N #6 fuel oil. Thermodynamic and chemical kinetic calculations have shown minimum NOx emissions ...

Ber?, J. M.

1981-01-01T23:59:59.000Z

154

N-nitrosamine and N-nitramine Formation from NOx Reactions with Amines during Amine-Based CO2  

E-Print Network [OSTI]

Capture for Post-combustion Carbon Sequestration Background! Generation of electricity and heat from power- combustion carbon sequestration, the capture and underground storage of CO2 from the exhaust gases of power formation from NOx reactions with amines during amine-based carbon dioxide capture for postcombustion carbon

Mitch, William A.

155

NETL: Advanced NOx Emissions Control: Control Technology - ALTA for Cyclone  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Full-Scale Demonstration of ALTA NOx Control for Cyclone-Fired Boilers Full-Scale Demonstration of ALTA NOx Control for Cyclone-Fired Boilers The primary goal of this project was to evaluate a technology called advanced layered technology application (ALTA) as a means to achieve NOx emissions below 0.15 lb/MMBtu in a cyclone boiler. Reaction Engineering International (REI) conducted field testing and combustion modeling to refine the process design, define the optimum technology parameters, and assess system performance. The ALTA NOx control technology combines deep staging from overfire air, rich reagent injection (RRI), and selective non-catalytic reduction (SNCR). Field testing was conducted during May-June 2005 at AmerenUE's Sioux Station Unit 1, a 500 MW cyclone boiler unit that typically burns an 80/20 blend of Powder River Basin subbituminous coal and Illinois No. 6 bituminous coal. Parametric testing was also conducted with 60/40 and 0/100 blends. The testing also evaluated process impacts on balance-of-plant issues such as the amount of unburned carbon in the ash, slag tapping, waterwall corrosion, ammonia slip, and heat distribution.

156

Identifying and counting point defects in carbon nanotubes  

E-Print Network [OSTI]

of single-walled carbon nanotubes. J. Phys. Chem. B 103,single-walled carbon nanotubes on patterned silicon wafers.of single-walled carbon nanotubes from carbon monoxide.

Fan, Y W; Goldsmith, B R; Collins, Philip G

2005-01-01T23:59:59.000Z

157

Identifying and Counting Point Defects in Carbon Nanotubes  

E-Print Network [OSTI]

single-walled carbon nanotubes on patterned silicon wafers.of single-walled carbon nanotubes from carbon monoxide.single-walled carbon nanotubes. Science 306, 1362–1364 (

Collins, Philip G

2005-01-01T23:59:59.000Z

158

Advanced furnace air staging and burner modifications for ultra-low NOx firing systems  

SciTech Connect (OSTI)

Overfire air is an effective means to reduce NOx emissions from coal fired furnaces. The current range of overfire air usage on wall-fired boilers in the US is in the range of 10 to 20%. In most cases this is enough to achieve current Title IV NOx reduction requirements. Future applications are likely to go beyond 20% Overfire Air to reduce NOx further for lower investment and operating costs of SCR retrofits. Summer ozone reduction requires NOx emissions of 0.15 lb/MBtu. Currently, industry is exploring the conditions under which this goal is attainable. The paper discussed the approach to achieve ultra-low NOx emissions by using advanced furnace air staging. It describes the unique approach of redesigning the burner to maintain low NOx burner performance when the overfire air system is added or increased in capacity. The impact on furnace corrosion and unburned carbon losses are presented. A case study is used to show the effects of overfire air both on emissions and unburned carbon.

McCarthy, K.; Laux, S.; Grusha, J.

1999-07-01T23:59:59.000Z

159

NETL: Advanced NOx Emissions Control: Control Technology - Ultra Low-NOx  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Ultra Low NOx Integrated System Ultra Low NOx Integrated System TFS 2000(tm) Low NOx Firing System Project Summary: ALSTOM Power Inc.'s Power Plant Laboratories, working in concert with ALSTOM Power's Performance Projects Group, has teamed with the U.S. Department of Energy's National Energy Technology Laboratory (DOE NETL) to conduct a comprehensive study to develop/evaluate low-cost, efficient NOx control technologies for retrofit to pulverized coal fired utility boilers. The objective of this project was to develop retrofit NOx control technology to achieve less than 0.15 lb/MMBtu NOx (for bituminous coals) and 0.10 lb/MMBtu NOx (for subbituminous coals) from existing pulverized coal fired utility boilers at a cost which is at least 25% less than SCR technology. Efficient control of NOx is seen as an important,

160

CLEERS Activities: Diesel Soot Filter Characterization & NOx...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Control Fundamentals CLEERS Activities: Diesel Soot Filter Characterization & NOx Control Fundamentals 2009 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit...

Note: This page contains sample records for the topic "nox carbon monoxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Method of removing nitrogen monoxide from a nitrogen monoxide-containing gas using a water-soluble iron ion-dithiocarbamate, xanthate or thioxanthate  

DOE Patents [OSTI]

A method of removing nitrogen monoxide from a nitrogen monoxide-containing gas, which method comprises: (a) contacting a nitrogen oxide-containing gas with an aqueous solution of water soluble organic compound-iron ion chelate of the formula: ##STR1## wherein the water-soluble organic compound is selected from compounds of the formula: ##STR2## wherein: R is selected from hydrogen or an organic moiety having at least one polar functional group; Z is selected from oxygen, sulfur, or --N--A wherein N is nitrogen and A is hydrogen or lower alkyl having from one to four carbon atoms; and M is selected from hydrogen, sodium or potassium; and n is 1 or 2, in a contacting zone for a time and at a temperature effective to reduce the nitrogen monoxide. These mixtures are useful to provide an unexpensive method of removing NO from gases, thus reducing atmospheric pollution from flue gases.

Liu, David K. (San Pablo, CA); Chang, Shih-Ger (El Cerrito, CA)

1989-01-01T23:59:59.000Z

162

Fe Promoted NOx Storage Materials: Structural Properties and NOx Uptake  

Science Journals Connector (OSTI)

According to the European Union regulations (EURO VI),(2) by the end of 2014, diesel passenger cars will be subject to a 3-fold decrease in NOx emissions from 0.25 to 0.08 g km?1. ... Barium oxide crystallizes in the rock salt structure, and the first order Raman scattering is symmetry forbidden(32, 33) However, broad and weak bands within 350?500 cm?1 due to the lattice modes of the defective BaO domains can still be visible via Raman spectroscopy (see for instance, Figure 3 in the Supporting Information). ...

Emine Kayhan; Stanislava M. Andonova; Go?ksu S. S?entu?rk; Charles C. Chusuei; Emrah Ozensoy

2009-12-11T23:59:59.000Z

163

NETL: Advanced NOx Emissions Control: Control Technology - NOx Combustion  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Control Options and Integration Control Options and Integration Reaction Engineering International (REI) is optimizing the performance of, and reduce the technical risks associated with the combined application of low-NOx firing systems (LNFS) and post combustion controls through modeling, bench-scale testing, and field verification. Teaming with REI are the University of Utah and Brown University. During this two-year effort, REI will assess real-time monitoring equipment to evaluate waterwall wastage, soot formation, and burner stoichiometry, demonstrate analysis techniques to improve LNFS in combination with reburning/SNCR, assess selective catalytic reduction catalyst life, and develop UBC/fly ash separation processes. The REI program will be applicable to coal-fired boilers currently in use in the United States, including corner-, wall-, turbo-, and cyclone-fired units. However, the primary target of the research will be cyclone boilers, which are high NOx producing units and represent about 20% of the U.S. generating capacity. The results will also be applicable to all U.S. coals. The research will be divided into four key components:

164

Transmural Catalysis - High Efficiency Catalyst Systems for NOx...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Transmural Catalysis - High Efficiency Catalyst Systems for NOx Adsorbers and SCR Transmural Catalysis - High Efficiency Catalyst Systems for NOx Adsorbers and SCR Presentation...

165

SCR Technologies for NOx Reduction | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Technologies for NOx Reduction SCR Technologies for NOx Reduction 2005 Diesel Engine Emissions Reduction (DEER) Conference Presentations and Posters 2005deerhesser.pdf More...

166

An Improvement of Diesel PM and NOx Reduction System | Department...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

& Publications Development on simultaneous reduction system of NOx and PM from a diesel engine An Improvement of Diesel PM and NOx Reduction System New Diesel Emissions...

167

Development on simultaneous reduction system of NOx and PM from...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

More Documents & Publications An Improvement of Diesel PM and NOx Reduction System An Improvement of Diesel PM and NOx Reduction System EPA Mobile Source Rule Update...

168

Passive Catalytic Approach to Low Temperature NOx Emission Abatement...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Catalytic Approach to Low Temperature NOx Emission Abatement Passive Catalytic Approach to Low Temperature NOx Emission Abatement Numerically evaluated and optimized proposed...

169

Three-Dimensional Composite Nanostructures for Lean NOx Emission...  

Broader source: Energy.gov (indexed) [DOE]

Three-Dimensional Composite Nanostructures for Lean NOx Emission Control Three-Dimensional Composite Nanostructures for Lean NOx Emission Control 2010 DOE Vehicle Technologies and...

170

Effect of Biodiesel Blends on NOx Emissions | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Biodiesel Blends on NOx Emissions Effect of Biodiesel Blends on NOx Emissions Poster presentation at the 2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER 2007)....

171

H2-Assisted NOx Traps: Test Cell Results Vehicle Installations...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

H2-Assisted NOx Traps: Test Cell Results Vehicle Installations H2-Assisted NOx Traps: Test Cell Results Vehicle Installations 2003 DEER Conference Presentation: ArvinMeritor...

172

Enhanced High and Low Temperature Performance of NOx Reduction...  

Broader source: Energy.gov (indexed) [DOE]

Enhanced High and Low Temperature Performance of NOx Reduction Materials Enhanced High and Low Temperature Performance of NOx Reduction Materials 2013 DOE Hydrogen and Fuel Cells...

173

Virtual Oxygen Sensor for Innovative NOx and PM Emission Control...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Virtual Oxygen Sensor for Innovative NOx and PM Emission Control Technologies Virtual Oxygen Sensor for Innovative NOx and PM Emission Control Technologies A virtual O2 sensor for...

174

Modeling the Regeneration Chemistry of Lean NOx Traps | Department...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

the Regeneration Chemistry of Lean NOx Traps Modeling the Regeneration Chemistry of Lean NOx Traps Presentation given at DEER 2006, August 20-24, 2006, Detroit, Michigan. Sponsored...

175

Electrochemical NOxSensor for Monitoring Diesel Emissions | Department...  

Broader source: Energy.gov (indexed) [DOE]

Diesel Emissions Electrochemical NOxSensor for Monitoring Diesel Emissions pm02glass.pdf More Documents & Publications Electrochemical NOx Sensor for Monitoring Diesel...

176

IEP - Advanced NOx Emissions Control: Regulatory Drivers  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

IEP - Advanced NOx Emissions Control Regulatory Drivers Regulatory Drivers for Existing Coal-Fired Power Plants Regulatory and legislative requirements have predominantly driven the need to develop NOx control technologies for existing coal-fired power plants. The first driver was the Title IV acid rain program, established through the 1990 Clean Air Act Amendments (CAAA). This program included a two-phase strategy to reduce NOx emissions from coal-fired power plants – Phase I started January 1, 1996 and Phase II started January 1, 2000. The Title IV NOx program was implemented through unit-specific NOx emission rate limits ranging from 0.40 to 0.86 lb/MMBtu depending on the type of boiler/burner configuration and based on application of LNB technology.

177

Utilization of computational fluid dynamics technique in low NOx burner/furnace retrofits  

SciTech Connect (OSTI)

A computational fluid dynamics (CFD) technique has been utilized to provide design guidance for retrofitting low NOx combustion systems and incorporating associated furnace modifications into existing utility boilers. The CFD program utilized is FW-FIRES (Fossil fuel, Water-walled Furnace Integrated Reaction and Emission Simulation) which simulates furnace combustion, heat transfer and pollutant formation based on fundamental principals of mass, momentum and energy conservations. The program models the gas flow field as a three-dimensional turbulent reacting continuum and the particle flow as a series of discrete particle trajectories through the gas continuum. Chemical reaction, heat transfer, and pollutant formation mechanisms are incorporated in the program. FW-FIRES furnace simulation of low NOx combustion system retrofits has been performed for various furnace configurations including front wall-fired, front and real wall-fired, and tangentially-fired furnaces, to determine the effects of burner/furnace modifications on the NOx emission, furnace exit gas temperature, furnace heat absorption, unburned carbon, and furnace wall corrosion. For front wall-fired, and front and real wall-fired furnaces, the NOx emission requirement is met by the use of Foster Wheeler lox NOx burners and overfire air (OFA) staging. Studies of burner and OFA quantify and spacing are conducted to limit NOx emission and unburned carbon to acceptable levels. A major concern in once-through supercritical units with OFA is furnace wall corrosion which is caused by high furnace wall metal temperature and corrosive hydrogen sulfide (H{sub 2}S) created in a reducing atmosphere from part of coal sulfur. The FW-FIRES code is used to minimize this corrosion potential by selecting the proper location and quantity of boundary air. A simulation of tangentially-fired unit, which has been retrofitted with low NOx burners, is used to study the effect of the burner tilt on the furnace exit gas temperature. This paper details the basis and results of several CFD analyses conducted for potential retrofit programs.

Cho, S.M.; Seltzer, A.H.; Ma, J.; Steitz, T.H.; Grusha, J.; Cole, R.W.

1999-07-01T23:59:59.000Z

178

Low NOx combustion system for heavy oil  

SciTech Connect (OSTI)

As a result of the increasing demand for white oil as one of countermeasures for pollution control and as a fuel for motor vehicle, coupled with the increasing import of heavy crude oil, heavy oils such as asphalt and distillation residue have become surplus in Japan. It is difficult by the conventional low NOx technology to control the NOx emission from the industrial small and medium capacity boilers, which use heavy oil as their fuels. The authors have been developing and improving NOx control technologies for boilers such as low NOx burners, two-stage combustion methods and so on. They have developed a new combustion system for heavy oil, which generates less NOx and soot than conventional systems, by applying the knowledge, obtained in the course of their development of Coal Partial Combustor (CPC). The conventional low NOx combustion method for oil firing boilers has been developed based on decreasing the flame temperature and delaying the combustion reaction. In the system, however, the heavy oil shall be combusted in the intense reducing atmosphere at the high flame temperature between 1,500 C and 1,600 C, and then the combustions gas shall be cooled and oxidized by two-stage combustion air. With this system, NOx emission can be suppressed below 100ppm (converted as O{sub 2}=4%).

Kurata, Chikatoshi; Sasaki, Hideki

1999-07-01T23:59:59.000Z

179

Ammonia-Free NOx Control System  

SciTech Connect (OSTI)

Research is being conducted under United States Department of Energy (DOE) Contract DEFC26-03NT41865 to develop a new technology to achieve very low levels of NOx emissions from pulverized coal fired boiler systems by employing a novel system level integration between the PC combustion process and the catalytic NOx reduction with CO present in the combustion flue gas. The combustor design and operating conditions will be optimized to achieve atypical flue gas conditions. This approach will not only suppress NOx generation during combustion but also further reduce NOx over a downstream catalytic reactor that does not require addition of an external reductant, such as ammonia. This report describes the work performed during the January 1 to March 31, 2004 time period.

S. Wu; Z. Fan; R. Herman

2004-03-31T23:59:59.000Z

180

Ammonia-Free NOx Control System  

SciTech Connect (OSTI)

Research is being conducted under United States Department of Energy (DOE) Contract DEFC26-03NT41865 to develop a new technology to achieve very low levels of NOx emissions from pulverized coal fired boiler systems by employing a novel system level integration between the PC combustion process and the catalytic NOx reduction with CO present in the combustion flue gas. The combustor design and operating conditions will be optimized to achieve atypical flue gas conditions. This approach will not only suppress NOx generation during combustion but also further reduce NOx over a downstream catalytic reactor that does not require addition of an external reductant, such as ammonia. This report describes the work performed during the October 1 to December 31, 2003 time period.

S. Wu

2003-12-31T23:59:59.000Z

Note: This page contains sample records for the topic "nox carbon monoxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

A Return Stroke NOx Production Model  

Science Journals Connector (OSTI)

A model is introduced for estimating the nitrogen oxides (NOx = NO + NO2) production from a lightning return stroke channel. A realistic Modified Transmission Line Model return stroke current is assumed to propagate vertically upward along a ...

William J. Koshak; Richard J. Solakiewicz; Harold S. Peterson

182

Electrochemical NOx Sensors for Monitoring Diesel Emissions  

Broader source: Energy.gov [DOE]

A unique electrochemical sensing strategy correlating the level of NOx with an impedance-based signal shows promise for sensitivity, stability, and accuracy while incorporating single-cell structures and simple electronics into low-cost designs

183

NOx Control Options and Integration for US Coal Fired Boilers  

SciTech Connect (OSTI)

This is the Final Report for DOE Cooperative Agreement No: DE-FC26-00NT40753. The goal of the project was to develop cost-effective analysis tools and techniques for demonstrating and evaluating low-NOx control strategies and their possible impact on boiler performance for boilers firing US coals. The Electric Power Research Institute (EPRI) provided co-funding for this program. This project included research on: (1) In furnace NOx control; (2) Impacts of combustion modifications on boiler operation; (3) Selective Catalytic Reduction (SCR) catalyst testing and (4) Ammonia adsorption/removal on fly ash. Important accomplishments were achieved in all aspects of the project. Rich Reagent Injection (RRI), an in-furnace NOx reduction strategy based on injecting urea or anhydrous ammonia into fuel rich regions in the lower furnace, was evaluated for cyclone-barrel and PC fired utility boilers. Field tests successfully demonstrated the ability of the RRI process to significantly reduce NOx emissions from a staged cyclone-fired furnace operating with overfire air. The field tests also verified the accuracy of the Computational Fluid Dynamic (CFD) modeling used to develop the RRI design and highlighted the importance of using CFD modeling to properly locate and configure the reagent injectors within the furnace. Low NOx firing conditions can adversely impact boiler operation due to increased waterwall wastage (corrosion) and increased soot production. A corrosion monitoring system that uses electrochemical noise (ECN) corrosion probes to monitor, on a real-time basis, high temperature corrosion events within the boiler was evaluated. Field tests were successfully conducted at two plants. The Ohio Coal Development Office provided financial assistance to perform the field tests. To investigate soot behavior, an advanced model to predict soot production and destruction was implemented into an existing reacting CFD modeling tool. Comparisons between experimental data collected in a pilot scale furnace and soot behavior predicted by the CFD model showed good agreement. Field and laboratory tests were performed for SCR catalysts used for coal and biomass co-firing applications. Fundamental laboratory studies were performed to better understand mechanisms involved with catalyst deactivation. Field tests with a slip stream reactor were used to create catalyst exposed to boiler flue gas for firing coal and for co-firing coal and biomass. The field data suggests the mechanisms leading to catalyst deactivation are, in order of importance, channel plugging, surface fouling, pore plugging and poisoning. Investigations were performed to better understand the mechanisms involved with catalyst regeneration through mechanical or chemical methods. A computer model was developed to predict NOx reduction across the catalyst in a SCR. Experiments were performed to investigate the fundamentals of ammonia/fly ash interactions with relevance to the operation of advanced NOx control technologies such as selective catalytic reduction. Measurements were performed for ammonia adsorption isotherms on commercial fly ash samples subjected to a variety of treatments and on the chemistry of dry and semi-dry ammonia removal processes. This work resulted in the first fundamental ammonia isotherms on carbon-containing fly ash samples. This work confirms industrial reports that aqueous solution chemistry takes place upon the introduction of even very small amounts of water, while the ash remains in a semi-dry state.

Mike Bockelie; Marc Cremer; Kevin Davis; Martin Denison; Adel Sarofim; Connie Senior; Hong-Shig Shim; Dave Swenson; Bob Hurt; Eric Suuberg; Eric Eddings; Kevin Whitty; Larry Baxter; Calvin Bartholomew; William Hecker

2006-06-30T23:59:59.000Z

184

E-Print Network 3.0 - americium carbonates Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

air pollutants are defined in the Clean Air Act and include ozone, particulate matter, carbon monoxide... .g., americium-241, cesium- 137, plutonium-238, plutonium-239, uranium-...

185

Advanced NOx Emissions Control: Control Technology - Second Generation  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Second Generation Advanced Reburning Second Generation Advanced Reburning General Electric - Energy and Environmental Research Corporation (GE-EER) is carrying out a two Phase research program to develop novel Advanced Reburning (AR) concepts for high efficiency and low cost NOx control from coal-fired utility boilers. AR technologies are based on combination of basic reburning and N-agent/promoter injections. Phase I of the project was successfully completed and EER was selected to continue to develop AR technology during Phase II. Phase I demonstrated that AR technologies are able to provide effective NOx control for coal-fired combustors. Three technologies were originally envisioned for development: AR-Lean, AR-Rich, and Multiple Injection AR (MIAR). Along with these, three additional technologies were identified during the project: reburning plus promoted SNCR; AR-Lean plus promoted SNCR; and AR-Rich plus promoted SNCR. The promoters are sodium salts, in particular sodium carbonate. These AR technologies have different optimum reburn heat input levels and furnace temperature requirements. For full scale application, an optimum technology can be selected on a boiler-specific basis depending on furnace temperature profile and regions of injector access.

186

Ammonia Sensor for SCR NOX Reduction | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Sensor for SCR NOX Reduction Ammonia Sensor for SCR NOX Reduction Presentation given at the 2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER 2007). 13-16 August,...

187

Lean NOx Reduction with Dual Layer LNT/SCR Catalysts  

Broader source: Energy.gov [DOE]

Results show that a series of dual layer catalysts with a bottom layer of LNT catalyst and a top layer of SCR catalyst can carry out coupled ammonia generation and NOx reduction, achieving high NOx conversion with minimal ammonia slip

188

NETL: Advanced NOx Emissions Control: Control Technology - Methane de-NOx  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

METHANE de-NOx® METHANE de-NOx® The Gas Technology Institute (GTI) is teaming with the All-Russian Thermal Engineering Institute and DB Riley to develop a pulverized-coal (PC)-combustion system that is an extension of IGT's METHANE de-NOx® technology. The technology is composed of a novel PC burner design using natural gas fired coal preheating developed and demonstrated in Russia, LNBs with internal combustion staging, and additional natural gas injection with overfire air. The coal is preheated at elevated temperatures (up to 1500oF) in oxygen deficient conditions prior to combustion. Coal preheat releases fuel-bound nitrogen together with volatiles present in the coal. These conditions promote the conversion of fuel-bound nitrogen to molecular nitrogen rather than to NOx.

189

A New Approach to Carbon Gasification  

Science Journals Connector (OSTI)

... carbon monoxide plus hydrogen respectively, under the usual conditions of temperature and pressure applying in gasification practice, the rates of reaction measured by the number of gm. moles of product ...

J. D. BLACKWOOD; F. K. McTAGGART

1959-08-08T23:59:59.000Z

190

Plasmachemical Synthesis of Carbon Suboxide  

E-Print Network [OSTI]

A nonthermal carbon monoxide plasma is known to produce a solid deposition which is thought to be a polymer of carbon suboxide (C3O2); however there are very few investigations of this deposition in the literature. This thesis contains an analysis...

Geiger, Robert

2012-12-11T23:59:59.000Z

191

Lower Freezing DEF For Higher NOx Reduction Attainment  

Broader source: Energy.gov [DOE]

NOx emissions data from bench-scale experiments and Class III truck operated using a low freezing point diesel exhaust fluid

192

Cummins/ORNL-FEERC CRADA: NOx Control & Measurement Technology...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

CumminsORNL-FEERC CRADA: NOx Control & Measurement Technology for Heavy-Duty Diesel Engines Vehicle Technologies Office Merit Review 2014: Cummins-ORNLFEERC Emissions CRADA:...

193

Unique Catalyst System for NOx Reduction in Diesel Exhaust |...  

Broader source: Energy.gov (indexed) [DOE]

More Documents & Publications Noxtechs PAC System Development and Demonstration Plasma Assisted Catalysis System for NOx Reduction Clean Diesel Engine Component Improvement...

194

Two Catalyst Formulations - One Solution for NOx After-treatment...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Two Catalyst Formulations - One Solution for NOx After-treatment Systems Low-temperature SCR combined with standard high-temperature SCR catalyst formulation in one system provides...

195

Measurement and Characterization of Lean NOx Adsorber Regeneration...  

Broader source: Energy.gov (indexed) [DOE]

for the Department of Energy Purpose of Work: Enable efficient lean engine market penetration by meeting emission regulations with aftertreatment * Research of Lean NOx...

196

Enhanced High and Low Temperature Performance of NOx Reduction...  

Broader source: Energy.gov (indexed) [DOE]

and Low Temperature Performance of NOx Reduction Materials 2013 DOE AMR Review This presentation does not contain any proprietary, confidential, or otherwise restricted...

197

NOx Adsorbers for Heavy Duty Truck Engines - Testing and Simulation...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Adsorbers for Heavy Duty Truck Engines - Testing and Simulation NOx Adsorbers for Heavy Duty Truck Engines - Testing and Simulation This report provides the results of an...

198

H2-Assisted NOx Traps: Test Cell Results Vehicle Installations  

Broader source: Energy.gov (indexed) [DOE]

Sam Crane August 28, 2003 H 2 -Assisted NOx Traps: Test Cell Results Vehicle Installations 2 Project Objectives * Determine Advantages of H 2 Assisted NO x Trap Regeneration *...

199

Investigation of Aging Mechanisms in Lean NOx Traps | Department...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

"Mega" Merit Review 2008 on February 25, 2008 in Bethesda, Maryland. merit08johnson.pdf More Documents & Publications Investigation of Aging Mechanisms in Lean NOx Traps...

200

Fuel Processor Enabled NOx Adsorber Aftertreatment System for...  

Broader source: Energy.gov (indexed) [DOE]

for Diesel Engine Emissions Control R. Dalla Betta, D. Sheridan, J. Cizeron Catalytica Energy Systems Inc. Mountain View, California 2 Outline Why use a fuel processor for NOx...

Note: This page contains sample records for the topic "nox carbon monoxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Status of APBF-DEC NOx Adsorber/DPF Projects  

Broader source: Energy.gov (indexed) [DOE]

* Examine other fuel properties 6 OAK RIDGE NATIONAL LABORATORY U. S. DEPARTMENT OF ENERGY Each platform will determine effects of fuel properties on: * NOx and PM reduction...

202

Virtual Oxygen Sensor for Innovative NOx and PM Emission Control...  

Broader source: Energy.gov (indexed) [DOE]

2009 - Poster Session August 3 rd , Hyatt Regency Dearborn Hotel Virtual Oxygen Sensor Innovative NOx and PM Emission Control Technologies J. Seebode, E. Stlting,...

203

Three-Dimensional Composite Nanostructures for Lean NOx Emission...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Emission Control Catalysts Three-Dimensional Composite Nanostructures for Lean NOx Emission Control Ultra-efficient, Robust and Well-defined Nano-Array based Monolithic Catalysts...

204

Three-Dimensional Composite Nanostructures for Lean NOx Emission...  

Broader source: Energy.gov (indexed) [DOE]

Nanowire Lean NOx Emission Control Catalysts Ultra-efficient, Robust and Well-defined Nano-Array based Monolithic Catalysts Three-Dimensional Composite Nanostructures for Lean...

205

Passive Catalytic Approach to Low Temperature NOx Emission Abatement  

Broader source: Energy.gov [DOE]

Numerically evaluated and optimized proposed state-of-the-art passive catalytic technology designed to reduce NOx released during vehicle cold start portion of the FTP-75 cycle

206

Rapid Aging Protocols for Diesel Aftertreatment Devices: NOx...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Aftertreatment (Agreement 13415) Thermal Deactivation Mechanisms of Fully-Formed Lean NOx Trap Catalysts Aged by LeanRich Cycling Impacts of Biodiesel on Emission Control Devices...

207

Transient Dynamometer Testing of a Single-Leg NOX Adsorber Combined...  

Broader source: Energy.gov (indexed) [DOE]

Transient Dynamometer Testing of a Single-Leg NOX Adsorber Combined with a Fuel Processor for Enhanced NOx Control Transient Dynamometer Testing of a Single-Leg NOX Adsorber...

208

Fuel Consumption and NOx Trade-offs on a Port-Fuel-Injected SI...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Consumption and NOx Trade-offs on a Port-Fuel-Injected SI Gasoline Engine Equipped with a Lean-NOx Trap Fuel Consumption and NOx Trade-offs on a Port-Fuel-Injected SI Gasoline...

209

Detection of Carbon Monoxide within the Magellanic Bridge  

E-Print Network [OSTI]

The Mopra 22m and SEST 15m telescopes have been used to detect and partially map a region of 12CO(1-0) line emission within the Magellanic Bridge, a region lying between the Large and Small Magellanic Clouds. The emission appears to be embedded in a cloud of neutral hydrogen, and is in the vicinity of an IRAS source. The CO emission region is found to have a 60um/100um flux density ratio typical for 12CO(1-0) detections within the SMC, although it has a significantly lower 12CO brightness and velocity width. These suggest that the observed region is of a low metallicity, supporting earlier findings that the Magellanic Bridge is not as evolved as the SMC and Magellanic Stream, which are themselves of a lower metallicity than the Galaxy. Our observations, along with empirical models based on SMC observations, indicate that the radius of the detected CO region has an upper limit of ~16 pc. This detection is, to our knowledge, the first detection of CO emission from the Magellanic Bridge and is the only direct evidence of star formation through molecular cloud collapse in this region.

E. Muller; L. Staveley-Smith; W. Zealey

2002-09-25T23:59:59.000Z

210

Studies of carbon monoxide diffusion in an urban area  

E-Print Network [OSTI]

3 40 ( )-, 7) 50 I I ) 'I ' 0 (. ' i . l') 4! !, , /' / 600 700 TRAFFTC/15 N!. Ii Fig. 14. Carl~co moaoxicle come. atrat ion v, traffic for Sampler 2 fro' t 12 15PN7 00PYCI/To ? 'JU)v 20' 1969(r'057) 29 if] 8!. & vcti jr. ';"; /I 7... correlation co"fficient 0. 47% 16. 6% 2. 44% 0. 13% Table 10 sboms 95/ confislence limits for average values for the three days. T1-e...

Thomas, John Charles

2012-06-07T23:59:59.000Z

211

Oxidation of Carbon Monoxide in Cell Extracts of Pseudomonas carboxydovorans  

Science Journals Connector (OSTI)

...Winzer. 1932. Uber die Bildung von Essigsaure bei der biologischen Umsetzung von Kohlenoxyd und Kohlensaure mit Wasserstoff zu Methan. Biochem. Z. 245:2-12. 9. Fuchs, G., G. Andress, and R. K. Thauer. 1975. CO- oxidation by anaerobic...

Ortwin Meyer; Hans G. Schlegel

1979-02-01T23:59:59.000Z

212

Advanced Diesel Combustion with Low Hydrocarbon and Carbon Monoxide Emissions  

Broader source: Energy.gov [DOE]

Poster presented at the 16th Directions in Engine-Efficiency and Emissions Research (DEER) Conference in Detroit, MI, September 27-30, 2010.

213

ILENR/RE-AQ-ON-ROAD CARBON MONOXIDE AND HYDROCARBON  

E-Print Network [OSTI]

. McVey, and Stuart P. Beaton Prepared for: Illinois Department of Energy and Natural Resources Office A. Witter Director State of Illinois Illinois Department of Energy and Natural Resources #12;NOTE This report has been reviewed by the Illinois Department of Energy and Natural Resources (ENR) and approved

Denver, University of

214

Computer simulation of the dispersion of carbon monoxide from roadways  

E-Print Network [OSTI]

and that the transport of material in the x-direction is due mainly to the mean wind, one can reduce equation (1) to BB B BV B BB u ? = ? (K ? ) + ? (K ? ) Bx By y By Bz z Bz (4) with the following boundary conditions, 1) I ~ 0 as x -+ 2) V~ asx-+0 (5) 3... are illustrated in Figures 5 and 6. Using equations (24) and (25) with n = 1 and equation (21), the concentration equations (19) and (20) become Q 1 v 21 r&(x, y, z, h) 2rra a u exp P- ? (~) J L2 ~ z z-h) 1 z+h)2 a az 'z (28) t(x, z, h) = exp /2rr a u z...

Maldonado, Cesar

1976-01-01T23:59:59.000Z

215

Decomposition and Polymerization of Solid Carbon Monoxide under Pressure  

Science Journals Connector (OSTI)

By performing constant-pressure deformable-cell ab initio molecular dynamics simulations we have studied the pressure-induced chemical instability of CO above 5 GPa. The simulation shows that, contrary to previous speculations, polymerization proceeds without CO bond dissociation. The resulting polymer consists of a disordered network of small polycarbonyl (CO)n chains connecting fivefold C4O cycles. The computed vibrational spectra and electronic gap agree very well with (and shed light on) very recent experimental data.

Stéphane Bernard; Guido L. Chiarotti; Sandro Scandolo; Erio Tosatti

1998-09-07T23:59:59.000Z

216

Experimental investigation of the thermal and diluent effects of EGR components on combustion and \\{NOx\\} emissions of a turbocharged natural gas SI engine  

Science Journals Connector (OSTI)

Abstract Exhaust gas recirculation (EGR) is one of effective measures used in natural gas (NG) engines to reduce nitrogen oxides (NOx) emissions. Each component of EGR gases can exert different effects on NG combustion and \\{NOx\\} formation rates, such as thermal effect, diluent effect, and chemical effect. In this study, the thermal and diluent effects of the main components of EGR gases, including carbon dioxide (CO2) and nitrogen (N2), were experimentally investigated. The experiments were arranged based on an electronically controlled heavy-duty natural gas spark-ignition (SI) engine with multi-point injection and 6-cylinder. In order to define the diluent effect of EGR components, argon (Ar) was introduced to the test, for its low and unchangeable specific heat capacity under different temperatures. The results showed that the contribution of the diluent effect on \\{NOx\\} reductions was 50–60% and 41–53% for N2 and CO2 respectively, and the relevant contribution of the thermal effect was 40–50% and 47–59% respectively. CO2 had greater effects on NG combustion and \\{NOx\\} formation rates than N2 at the same dilution ratio. Increasing Ar improved the thermal efficiency due to the higher specific heat ratio provided. Meanwhile, \\{NOx\\} emissions were found to be decreased with increasing DR as a result of the diluent effect of Ar on combustion and \\{NOx\\} formations.

Weifeng Li; Zhongchang Liu; Zhongshu Wang; Yun Xu

2014-01-01T23:59:59.000Z

217

Flexible CHP System with Low NOx, CO, and VOC Emissions - Presentation...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

CHP System with Low NOx, CO, and VOC Emissions - Presentation by the Gas Technology Institute (GTI), June 2011 Flexible CHP System with Low NOx, CO, and VOC Emissions -...

218

Low-NOx Gas Turbine Injectors Utilizing Hydrogen-Rich Opportunity...  

Broader source: Energy.gov (indexed) [DOE]

NOx Gas Turbine Injectors Utilizing Hydrogen-Rich Opportunity Fuels - Fact Sheet, 2011 Low-NOx Gas Turbine Injectors Utilizing Hydrogen-Rich Opportunity Fuels - Fact Sheet, 2011...

219

A Fundamental Consideration on NOx Adsorber Technology for DI Diesel Application  

SciTech Connect (OSTI)

Diesel engines are far more efficient than gasoline engines of comparable size, and emit less greenhouse gases that have been implicated in global warming. In 2000, the US EPA proposed very stringent emissions standards to be introduced in 2007 along with low sulfur (< 15 ppm) diesel fuel. The California Air Resource Board (CARB) has also established the principle that future diesel fueled vehicles should meet the same low emissions standards as gasoline fueled vehicles and the EPA followed suit with its Tier II emissions regulation. Achieving such low emissions cannot be done through engine development and fuel reformulation alone, and requires application of NOx and particulate matter (PM) aftertreatment control devices. There is a widespread consensus that NOx adsorbers and particulate filter are required in order for diesel engines to meet the 2007 emissions regulations for NOx and PM. In this paper, the key exhaust characteristics from an advanced diesel engine are reviewed. Development of the NOx adsorber technology is discussed. Spectroscopic techniques are applied to understand the underlying chemical reactions over the catalyst surface during NOx trapping and regeneration periods. In-situ surface probes are useful in providing not only thermodynamic and kinetics information required for model development but also a fundamental understanding of storage capacity and degradation mechanisms. The distribution of various nitration/sulfation species is related to surface basicity. Surface displacement reactions of carbonates also play roles in affecting the trapping capability of NOx adsorbers. When ultralow-S fuel is used as a reductant during the regeneration, sulfur induced performance degradation is still observed in an aged catalyst. Other possible sources related to catalyst deactivation include incomplete reduction of surface nitration, coke formation derived from incomplete hydrocarbon burning, and lubricant formulations. Sulfur management and the direction of future work for the successful implementation of such integrated engine and aftertreatment technology are discussed. SAE Paper SAE-2002-01-2889 {copyright} 2002 SAE International. This paper is published on this website with permission from SAE International. As a user of this website, you are permitted to view this paper on-line, download this pdf file and print one copy of this paper at no cost for your use only. The downloaded pdf file and printout of this SAE paper may not be copied, distributed or forwarded to others or for the use of others.

Fang, Howard L.; Huang, Shyan C.; Yu, Robert C. (Cummins, Inc.); Wan, C. Z. (Engelhard Corp.); Howden, Ken (U.S. Dept. of Energy)

2002-10-01T23:59:59.000Z

220

Metal catalyzed copolymerization processes involving carbon oxides as substrates  

E-Print Network [OSTI]

backbone and electron donating tert-butyl groups in the phenolate rings. This catalyst was used to investigate the effect of altering the nature of the cocatalyst and its concentration. The coupling of carbon monoxide and aziridines has been shown...

Phelps, Andrea Lee

2005-11-01T23:59:59.000Z

Note: This page contains sample records for the topic "nox carbon monoxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Population based exposure assessment methodology for carbon monoxide: Development of a Carbon Monoxide Passive Sampler and Occupational Dosimeter  

E-Print Network [OSTI]

monitoring for nitrogen dioxide exposure: methodologyB.G. , Jr. (1983) Nitrogen dioxide inside and outside 137Personal Sampler for Nitrogen Dioxide. American Industrial

Apte, Michael G.

2010-01-01T23:59:59.000Z

222

Ultra-Low NOx Advanced Vortex Combustor  

SciTech Connect (OSTI)

An ultra lean-premixed Advanced Vortex Combustor (AVC) has been developed and tested. The natural gas fueled AVC was tested at the U.S. Department of Energy’s National Energy Technology Laboratory (USDOE NETL) test facility in Morgantown (WV). All testing was performed at elevated pressures and inlet temperatures and at lean fuel-air ratios representative of industrial gas turbines. The improved AVC design exhibited simultaneous NOx/CO/UHC emissions of 4/4/0 ppmv (all emissions are at 15% O2 dry). The design also achieved less than 3 ppmv NOx with combustion efficiencies in excess of 99.5%. The design demonstrated tremendous acoustic dynamic stability over a wide range of operating conditions which potentially makes this approach significantly more attractive than other lean premixed combustion approaches. In addition, a pressure drop of 1.75% was measured which is significantly lower than conventional gas turbine combustors. Potentially, this lower pressure drop characteristic of the AVC concept translates into overall gas turbine cycle efficiency improvements of up to one full percentage point. The relatively high velocities and low pressure drops achievable with this technology make the AVC approach an attractive alternative for syngas fuel applications.

Edmonds, R.G. (Ramgen Power Systems, Inc., Bellevue, WA); Steele, R.C. (Ramgen Power Systems, Inc., Bellevue, WA); Williams, J.T. (Ramgen Power Systems, Inc., Bellevue, WA); Straub, D.L.; Casleton, K.H.; Bining, Avtar (California Energy Commission, Sacramento, CA)

2006-05-01T23:59:59.000Z

223

ULTRA-LOW NOX ADVANCED VORTEX COMBUSTOR  

SciTech Connect (OSTI)

An ultra lean-premixed Advanced Vortex Combustor (AVC) has been developed and tested. The natural gas fueled AVC was tested at the U.S. Department of Energy’s National Energy Technology Laboratory (USDOE NETL) test facility in Morgantown (WV). All testing was performed at elevated pressures and inlet temperatures and at lean fuel-air ratios representative of industrial gas turbines. The improved AVC design exhibited simultaneous NOx/CO/UHC emissions of 4/4/0 ppmv (all emissions are at 15% O2 dry). The design also achieved less than 3 ppmv NOx with combustion efficiencies in excess of 99.5%. The design demonstrated tremendous acoustic dynamic stability over a wide range of operating conditions which potentially makes this approach significantly more attractive than other lean premixed combustion approaches. In addition, a pressure drop of 1.75% was measured which is significantly lower than conventional gas turbine combustors. Potentially, this lower pressure drop characteristic of the AVC concept translates into overall gas turbine cycle efficiency improvements of up to one full percentage point. The relatively high velocities and low pressure drops achievable with this technology make the AVC approach an attractive alternative for syngas fuel applications.

Ryan G. Edmonds; Robert C. Steele; Joseph T. Williams; Douglas L. Straub; Kent H. Casleton; Avtar Bining

2006-05-01T23:59:59.000Z

224

OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL  

SciTech Connect (OSTI)

This quarterly technical progress report will summarize work accomplished for the Program through the twelfth quarter, January-March 2003, in the following task areas: Task 1--Oxygen Enhanced Combustion, Task 2--Oxygen Transport Membranes, Task 3--Economic Evaluation and Task 4--Program Management. The program is proceeding in accordance with the objectives for the third year. Pilot scale experiments conducted at the University of Utah explored both the effectiveness of oxygen addition and the best way to add oxygen with a scaled version of Riley Power's newest low NOx burner design. CFD modeling was done to compare the REI's modeling results for James River Unit 3 with the NOx and LOI results obtained during the demonstration program at that facility. Investigation of an alternative method of fabrication of PSO1d elements was conducted. OTM process development work has concluded with the completion of a long-term test of a PSO1d element Economic evaluation has confirmed the advantage of oxygen-enhanced combustion. Proposals have been submitted for two additional beta test sites. Commercial proposals have been submitted. Economic analysis of a beta site test performance was conducted.

David R. Thompson; Lawrence E. Bool; Jack C. Chen

2003-04-01T23:59:59.000Z

225

OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL  

SciTech Connect (OSTI)

This quarterly technical progress report will summarize work accomplished for the Program in the seventh quarter October-December 2001 in the following task areas: Task 1 - Oxygen Enhanced Combustion, Task 2 - Oxygen Transport Membranes, Task 3 - Economic Evaluation and Task 4 - Program Management. Computational fluid dynamic (CFD) modeling of oxygen injection strategies was performed during the quarter resulting in data that suggest the oxygen injection reduces NOx emissions while reducing LOI. Pilot-scale testing activities concluded at the University of Utah this quarter. Testing demonstrated that some experimental conditions can lead to NOx emissions well below the 0.15 lb/MMBtu limit. Evaluation of alternative OTM materials with improved mechanical properties continued this quarter. Powder procedure optimization continued and sintering trial began on an element with a new design. Several OTM elements were tested in Praxair's single tube high-pressure test facility under various conditions. A modified PSO1d element demonstrated stable oxygen product purity of >98% and oxygen flux of 68% of target. Updated test results and projected economic performance have been reviewed with the Utility Industrial Advisors. The economic comparison remains very favorable for O{sub 2} enhanced combustion. Discussions regarding possible Beta sites have been held with three other utilities in addition to the industrial advisors. Proposals will be prepared after the completion of full scale burner testing. Beta test cost estimating work has been initiated.

David R. Thompson; Lawrence E. Bool; Jack C. Chen

2002-01-01T23:59:59.000Z

226

NETL: Emissions Characterization - Adv. Low-NOx Burner Emissions  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Advanced Low-NOx Burner Emissions Characterization Advanced Low-NOx Burner Emissions Characterization The goal of this work is to develop a comprehensive, high-quality database characterizing PM2.5 emissions from utility plants firing high sulfur coals. The specific objectives are to: 1) develop and test an ultra low-NOx pulverized coal burner for plug-in retrofit applications without boiler wall tube modifications, 2) assess the impact of low-NOx PC burner operation on NOx and PM2.5 emissions, and 3) provide high-quality data to ensure that future PM2.5 regulations are based on good scientific information. The work will be performed in the Clean Environment Development Facility (CEDF), a 100 million Btu/hr near-full-scale facility located at the Alliance Research Center. Related Papers and Publications:

227

Air Pollution Control Regulations: No. 41 - Nox Budget Trading Program  

Broader source: Energy.gov (indexed) [DOE]

41 - Nox Budget Trading 41 - Nox Budget Trading Program (Rhode Island) Air Pollution Control Regulations: No. 41 - Nox Budget Trading Program (Rhode Island) < Back Eligibility Commercial Industrial Investor-Owned Utility Municipal/Public Utility Rural Electric Cooperative Utility Savings Category Alternative Fuel Vehicles Hydrogen & Fuel Cells Program Info State Rhode Island Program Type Environmental Regulations Provider Department of Environmental Management These regulations establish a budget trading program for nitrogen oxide emissions, setting NOx budget units for generators and an NOx Allowance Tracking System to account for emissions. These regulations apply to units that serve generators with a nameplate capacity greater than 15 MWe and sell any amount of electricity, as well as to units that have a maximum

228

Carbon dioxide recovery from an integrated coal gasifier, combined cycle plant using membrane separation and a CO2 gas turbine  

Science Journals Connector (OSTI)

A scheme is described for electricity production based on coal gasification with recovery of carbon dioxide. In this scheme, coal is gasified into a coal gas, consisting mainly of hydrogen and carbon monoxide. A ...

Chris Hendriks

1994-01-01T23:59:59.000Z

229

OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL  

SciTech Connect (OSTI)

This quarterly technical progress report will summarize work accomplished for the Program through the fourth quarter January-March 2001 in the following task areas: Task 1 - Oxygen Enhanced Combustion, Task 2 - Oxygen Transport Membranes and Task 4 - Program Management. This report will also recap the results of the past year. The program is proceeding in accordance with the objectives for the first year. OTM material characterization was completed. 100% of commercial target flux was demonstrated with OTM disks. The design and assembly of Praxair's single tube high-pressure test facility was completed. The production of oxygen with a purity of better than 99.5% was demonstrated. Coal combustion testing was conducted at the University of Arizona. Modest oxygen enhancement resulted in NOx emissions reduction. The injector for oxygen enhanced coal based reburning was conducted at Praxair. Combustion modeling with Keystone boiler was completed. Pilot-scale combustion test furnace simulations continued this quarter.

David R. Thompson; Lawrence E. Bool; Jack C. Chen

2001-04-01T23:59:59.000Z

230

OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL  

SciTech Connect (OSTI)

This quarterly technical progress report will summarize work accomplished for the Program through the thirteenth quarter, April-June 2003, in the following task areas: Task 1--Oxygen Enhanced Combustion, Task 3--Economic Evaluation and Task 4--Program Management. The program is proceeding in accordance with project objectives. REI's model was modified to evaluate mixing issues in the upper furnace of a staged unit. Analysis of the results, and their potential application to this unit is ongoing. Economic evaluation continues to confirm the advantage of oxygen-enhanced combustion. A contract for a commercial demonstration has been signed with the Northeast Generation Services Company to supply oxygen and license the oxygen enhanced low NOx combustor technology for use at the 147-megawatt coal fired Mt. Tom Station in Holyoke, MA. Commercial proposals have been submitted. Economic analysis of a beta site test performance was conducted.

David R. Thompson; Lawrence E. Bool; Jack C. Chen

2003-08-01T23:59:59.000Z

231

Flexible CHP System with Low NOx, CO and VOC Emissions- Fact Sheet, 2014  

Broader source: Energy.gov [DOE]

Utilizing Supplemental Ultra-Low-NOx Burner Technology to Meet Emissions Standards and Improve System Efficiency

232

Smog Check II Evaluation California Inspection and  

E-Print Network [OSTI]

National Ambient Air Quality Standards NO Nitrogen Oxide NO2 Nitrogen Dioxide NOx Nitrogen Oxides RAP Assistance Program CHP California Highway Patrol CO Carbon Monoxide CO2 Carbon Dioxide DMV California

Denver, University of

233

Ion-mobility Spectrometry Based NOx Sensor - Nuclear Engineering Division  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

NPNS > Sensors and NPNS > Sensors and Instrumentation and NDE > Energy System Application > DOE Office of Transportation Technologies > Ion-mobility Spectrometry Based NOx Sensor Capabilities Sensors and Instrumentation and Nondestructive Evaluation Overview Energy System Applications Overview DOE Office of Fossil Energy DOE Office of Transportation Technologies Ion-mobility Spectrometry Based NOx Sensor DOE Office of Power Technology Work for Others Safety-Related Applications Homeland Security Applications Biomedical Applications Millimiter Wave Group Papers Other NPNS Capabilities Work with Argonne Contact us For Employees Site Map Help Join us on Facebook Follow us on Twitter NE on Flickr Sensors and Instrumentation and Nondestructive Evaluation Ion-mobility Spectrometry Based NOx Sensor

234

Oxidation State Optimization for Maximum Efficiency of NOx Adsorber...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Directions in Engine-Efficiency and Emissions Research (DEER) Conference in Detroit, MI, September 27-30, 2010. deer10li.pdf More Documents & Publications Lean NOx Trap...

235

Functionality of Commercial NOx Storage-Reduction Catalysts and...  

Broader source: Energy.gov (indexed) [DOE]

N.A. Ottinger, J.A. Pihl, T.J. Toops, C. Finney, M. Lance, C. Stuart Daw, "Types, Spatial Distribution, Stability, and Performance Impact of Sulfur on a Lean NOx Trap...

236

Reducing NOx emissions using the humid air motor concept  

Science Journals Connector (OSTI)

The use of water to prevent NOx...formation during the combustion process is well known. The H.A.M. system (Humid Air Motor) is an original and promising solution compared ... . This system involves evaporating l...

Emmanuel Riom; Lars-Ola Larsson; Ulf Hagström

2002-05-01T23:59:59.000Z

237

Enhanced High Temperature Performance of NOx Storage/Reduction...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

and Peer Evaluation Meeting, June 7-11, 2010 -- Washington D.C. ace026peden2010o.pdf More Documents & Publications Mechanisms of Sulfur Poisoning of NOx Adsorber (LNT) Materials...

238

Lean Gasoline Engine Reductant Chemistry During Lean NOx Trap Regeneration  

SciTech Connect (OSTI)

Lean NOx Trap (LNT) catalysts can effectively reduce NOx from lean engine exhaust. Significant research for LNTs in diesel engine applications has been performed and has led to commercialization of the technology. For lean gasoline engine applications, advanced direct injection engines have led to a renewed interest in the potential for lean gasoline vehicles and, thereby, a renewed demand for lean NOx control. To understand the gasoline-based reductant chemistry during regeneration, a BMW lean gasoline vehicle has been studied on a chassis dynamometer. Exhaust samples were collected and analyzed for key reductant species such as H2, CO, NH3, and hydrocarbons during transient drive cycles. The relation of the reductant species to LNT performance will be discussed. Furthermore, the challenges of NOx storage in the lean gasoline application are reviewed.

Choi, Jae-Soon [ORNL] [ORNL; Prikhodko, Vitaly Y [ORNL] [ORNL; Partridge Jr, William P [ORNL] [ORNL; Parks, II, James E [ORNL; Norman, Kevin M [ORNL] [ORNL; Huff, Shean P [ORNL] [ORNL; Chambon, Paul H [ORNL] [ORNL; Thomas, John F [ORNL] [ORNL

2010-01-01T23:59:59.000Z

239

Reducing fishing vessel fuel consumption and NOX emissions  

Science Journals Connector (OSTI)

There is a growing concern with the impact of marine operations on the environment. This requires reducing fuel consumption and vessel pollution during operation. On-board computers and satellite communications will enable the operator to reduce fuel consumption and NOX emissions during vessel operations. This paper presents the results of a study on this problem and how such an on-board system could be implemented to reduce fuel consumption and engine NOX emissions.

Robert Latorre

2001-01-01T23:59:59.000Z

240

Group effects on fuel NOx emissisons from coal  

E-Print Network [OSTI]

GROUP EFFECTS ON FUEL NOX EMISSIONS FROM COAL A Thesis by ANAND ANAKKARA VADAKKATH Submitted to the Office of Graduate Studies of Texas ARM University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE August... 1991 Major Subject: Mechanical Engineering GROUP EFFECTS ON FUEL NOX EMISSIONS FROM COAL A Thesis by ANAND ANAKKARA VADAKKATH Approved ss to style and content by: K. Annamalai (Chair of Committee) Cr, R. Laster (Member) J. Wagne (Member...

Vadakkath, Anand Anakkara

2012-06-07T23:59:59.000Z

Note: This page contains sample records for the topic "nox carbon monoxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL  

SciTech Connect (OSTI)

This quarterly technical progress report will summarize work accomplished for the Program through the ninth quarter April-June 2002 in the following task areas: Task 1--Oxygen Enhanced Combustion, Task 2--Oxygen Transport Membranes, Task 3--Economic Evaluation and Task 4--Program Management. The program is proceeding in accordance with the objectives for the third year. Full-scale testing using the Industrial Boiler Simulation Facility (ISBF) at Alstom Power was completed. The pilot scale experiments to evaluate the effect of air preheat and transport air stoichiometric ratio (SR) on NOx emissions were conducted at the University of Utah. Combustion modeling activities continued with full-scale combustion test furnace simulations. An OTM element was tested in Praxair's single tube high-pressure test facility and two thermal cycles were completed. PSO1d elements of new dimension were tested resulting in a lower flux than previous PSO1d elements of different dimensions, however, no element deformation was observed. Economic evaluation has confirmed the advantage of oxygen-enhanced combustion. Two potential host beta sites have been identified and proposals submitted.

David R. Thompson; Lawrence E. Bool; Jack C. Chen

2002-08-01T23:59:59.000Z

242

OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL  

SciTech Connect (OSTI)

This quarterly technical progress report will summarize work accomplished for the Program through the fourth quarter January-March 2002 in the following task areas: Task 1--Oxygen Enhanced Combustion, Task 2--Oxygen Transport Membranes, Task 3--Economic Evaluation and Task 4--Program Management. This report will also recap the results of the past year. The program is proceeding in accordance with the objectives for the second year. The first round of pilot scale testing with 3 bituminous coals was completed at the University of Utah. Full-scale testing equipment is in place and experiments are underway. Coal combustion lab-scale testing was completed at the University of Arizona. Modest oxygen enhancement resulted in NOx emissions reduction. Combustion modeling activities continued with pilot-scale combustion test furnace simulations. 75% of target oxygen flux was demonstrated with small PSO1 tube in Praxair's single tube high-pressure test facility. The production of oxygen with a purity of better than 99.999% was demonstrated. Economic evaluation has confirmed the advantage of oxygen-enhanced combustion. Two potential host sites have been identified.

David R. Thompson; Lawrence E. Bool; Jack C. Chen

2002-04-01T23:59:59.000Z

243

NETL: Advanced NOx Emissions Control: Control Technology - SCNR Field  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

SNCR Field Demonstration SNCR Field Demonstration American Electric Power (AEP), in conjunction with the U.S. Department of Energy, FuelTech, the Ohio Coal Development Office, and fourteen EPRI member utilities, performed a full-scale demonstration of a urea-based Selective Non-Catalytic Reduction (SNCR) system at Cardinal Unit 1. Cardinal Unit 1 is a 600MWe opposed-wall dry bottom pulverized coal-fired boiler that began service in 1967. This unit burns eastern bituminous high-sulfur coal, (3.72%S). This unit was retrofitted with low NOx burners (LNB's) during its scheduled fall 1998 outage and the SNCR system was installed concurrently. SNCR is a post-combustion NOx control process developed to reduce NOx emissions from fossil-fuel combustion systems. SNCR processes involve the injection of a chemical containing nitrogen into the combustion products, where the temperature is in the range of 1600°F - 2200°F (870°C - 1205°C). In this temperature range, the chemical reacts selectively with NOx in the presence of oxygen, forming primarily nitrogen and water. Although a number of chemicals have been investigated and implemented for SNCR NOx reduction, urea and ammonia have been most widely used for full-scale applications.

244

Strain-induced band-gap engineering of graphene monoxide and its effect on graphene  

Science Journals Connector (OSTI)

Using first-principles calculations we demonstrate the feasibility of band-gap engineering in two-dimensional crystalline graphene monoxide (GMO), a recently reported graphene-based material with a 1:1 carbon/oxygen ratio. The band gap of GMO, which can be switched between direct and indirect, is tunable over a large range (0–1.35 eV) for accessible strains. Electron and hole transport occurs predominantly along the zigzag and armchair directions (armchair for both) when GMO is a direct- (indirect-) gap semiconductor. A band gap of ?0.5 eV is also induced in graphene at the K? points for GMO/graphene hybrid systems.

H. H. Pu; S. H. Rhim; C. J. Hirschmugl; M. Gajdardziska-Josifovska; M. Weinert; J. H. Chen

2013-02-13T23:59:59.000Z

245

SCReaming for Low NOx - SCR for the Light Duty Market | Department...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

SCReaming for Low NOx - SCR for the Light Duty Market SCReaming for Low NOx - SCR for the Light Duty Market Presentation given at DEER 2006, August 20-24, 2006, Detroit, Michigan....

246

Engine and Reactor Evaluations of HC-SCR for Diesel NOx Reduction...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Engine and Reactor Evaluations of HC-SCR for Diesel NOx Reduction Engine and Reactor Evaluations of HC-SCR for Diesel NOx Reduction Focus is the heavy duty, US dynamometer...

247

Safe and compact ammonia storage/delivery systems for SCR-DeNOX...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Safe and compact ammonia storagedelivery systems for SCR-DeNOX in automotive units Safe and compact ammonia storagedelivery systems for SCR-DeNOX in automotive units Presentation...

248

Development of a Stand-Alone Urea-SCR System for NOx Reduction...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Stand-Alone Urea-SCR System for NOx Reduction in Marine Diesel Engines Development of a Stand-Alone Urea-SCR System for NOx Reduction in Marine Diesel Engines Stand-alone urea SCR...

249

Fuel-Borne Reductants for NOx Aftertreatment: Preliminary EtOH...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Reductants for NOx Aftertreatment: Preliminary EtOH SCR Study Fuel-Borne Reductants for NOx Aftertreatment: Preliminary EtOH SCR Study 2003 DEER Conference Presentation: Oak Ridge...

250

Initial Results of the DeNOx SCR System by Urea Injection in...  

Broader source: Energy.gov (indexed) [DOE]

Initial Results of the DeNOx SCR System by Urea Injection in the Euro 5 Bus Initial Results of the DeNOx SCR System by Urea Injection in the Euro 5 Bus 2005 Diesel Engine Emissions...

251

The Effects of Hydrocarbons on NOx Reduction over Fe-based SCR Catalyst  

Broader source: Energy.gov [DOE]

Study of effects of hydrocarbons on ammonia storage and NOx reduction over a commercial Fe-zeolite SCR catalyst to understand catalyst behaviors at low temperatures and improve NOx reduction performance and reduce system cost

252

Industry-Utility Collaborative Efforts to Address Environmental Concerns- Dispatching for Localized NOx Reduction  

E-Print Network [OSTI]

these objectives. The approach involves dispatching NOx-producing equipment (e.g., boilers and gas turbines) to achieve minimum NOx production during ozone alert periods and purchasing supplemental power under a special tariff to replace any loss in self...

Hamilton, D. E.; Helmick, R. W.; Lambert, W. J.

253

Intra-catalyst Reductant Chemistry in Lean NOx Traps: A Study...  

Broader source: Energy.gov (indexed) [DOE]

Intra-catalyst Reductant Chemistry in Lean NOx Traps: A Study on Sulfur Effects Intra-catalyst Reductant Chemistry in Lean NOx Traps: A Study on Sulfur Effects Presentation given...

254

Detection of iodine monoxide in the tropical free troposphere  

E-Print Network [OSTI]

19, 2012) Atmospheric iodine monoxide (IO) is a radical that catalytically destroys heat trapping in the remote tropical marine boundary layer (MBL) (2­4). IO further affects the oxidative capacity iodine species over the remote ocean remain poorly understood (11, 14) but are currently thought

255

NOx formation by steam injection using detailed chemical kinetics  

Science Journals Connector (OSTI)

In order to improve thermal efficiency of gas turbine system and better control NOx emission, the injection of steam into a gas turbine combustor has been employed. This study has used both chemical equilibrium calculations and the counterflow diffusion flame calculations of methane-air flame aiming at the elucidation of the NOx reduction mechanism due to the steam injection. The influence of the equivalence ratios, the amount of steam and method of injection, the influence of the temperature of the preheated air and fuel has been also investigated. In this study, the GRI-Mech was employed for modelling the chemical reactions.

H. Yamashita; D. Zhao; S.N. Danov; T. Furuhata; N. Arai

2001-01-01T23:59:59.000Z

256

Aeroderivative Gas Turbines Can Meet Stringent NOx Control Requirements  

E-Print Network [OSTI]

for controlling NOx emissions will be discussed. Steam injection has a very favorable effect on engine performance raising both the power output and efficiency. As an example, full steam injection in the GE LM5000 gas turbine :tncreases the power output from... methods for reducing the NOx levels of the LM2500 and LM5000 engines. These engines are aircraft-derivative turbine engines, which are used in a variety of industrial applications. Efforts have been concentrated on the use of water or steam injection...

Keller, S. C.; Studniarz, J. J.

257

Cobalt carbonyl catalyzed olefin hydroformylation in supercritical carbon dioxide  

DOE Patents [OSTI]

A method of olefin hydroformylation is provided wherein an olefin reacts with a carbonyl catalyst and with reaction gases such as hydrogen and carbon monoxide in the presence of a supercritical reaction solvent, such as carbon dioxide. The invention provides higher yields of n-isomer product without the gas-liquid mixing rate limitation seen in conventional Oxo processes using liquid media.

Rathke, J.W.; Klingler, R.J.

1993-03-30T23:59:59.000Z

258

The Chemistry of the Thermal DeNOx Process: A Review of the Technology's Possible Application to control of NOx from Diesel Engines  

SciTech Connect (OSTI)

This paper presents a review of the Thermal DeNOx process with respect to its application to control of NOx emissions from diesel engines. The chemistry of the process is discussed first in empirical and then theoretical terms. Based on this discussion the possibilities of applying the process to controlling NOx emissions from diesel engines is considered. Two options are examined, modifying the requirements of the chemistry of the Thermal DeNOx process to suit the conditions provided by diesel engines and modifying the engines to provide the conditions required by the process chemistry. While the former examination did not reveal any promising opportunities, the latter did. Turbocharged diesel engine systems in which the turbocharger is a net producer of power seem capable of providing the conditions necessary for NOx reduction via the Thermal DeNOx reaction.

Lyon, Richard

2001-08-05T23:59:59.000Z

259

Lean NOx Reduction with Dual Layer LNT/SCR Catalysts  

Broader source: Energy.gov (indexed) [DOE]

Roles of ceria in LNT SCR: I ncreases NOx storage & NO conversion at low tem perature P rom otes W GS reaction Conditions: Lean: 500 ppm NO, 5% O 2 ; 60s Rich: 2.5% H 2 ; 5s X H2...

260

Near-Zero Emissions Oxy-Combustion Flue Gas Purification Task 3: SOx/NOx/Hg Removal for Low Sulfur Coal  

SciTech Connect (OSTI)

The goal of this project was to develop a near-zero emissions flue gas purification technology for existing PC (pulverized coal) power plants that are retrofitted with oxycombustion technology. The objective of Task 3 of this project was to evaluate an alternative method of SOx, NOx and Hg removal from flue gas produced by burning low sulfur coal in oxy-combustion power plants. The goal of the program was to conduct an experimental investigation and to develop a novel process for simultaneously removal of SOx and NOx from power plants that would operate on low sulfur coal without the need for wet-FGD & SCRs. A novel purification process operating at high pressures and ambient temperatures was developed. Activated carbonâ??s catalytic and adsorbent capabilities are used to oxidize the sulfur and nitrous oxides to SO{sub 3} and NO{sub 2} species, which are adsorbed on the activated carbon and removed from the gas phase. Activated carbon is regenerated by water wash followed by drying. The development effort commenced with the screening of commercially available activated carbon materials for their capability to remove SO{sub 2}. A bench-unit operating in batch mode was constructed to conduct an experimental investigation of simultaneous SOx and NOx removal from a simulated oxyfuel flue gas mixture. Optimal operating conditions and the capacity of the activated carbon to remove the contaminants were identified. The process was able to achieve simultaneous SOx and NOx removal in a single step. The removal efficiencies were >99.9% for SOx and >98% for NOx. In the longevity tests performed on a batch unit, the retention capacity could be maintained at high level over 20 cycles. This process was able to effectively remove up to 4000 ppm SOx from the simulated feeds corresponding to oxyfuel flue gas from high sulfur coal plants. A dual bed continuous unit with five times the capacity of the batch unit was constructed to test continuous operation and longevity. Full-automation was implemented to enable continuous operation (24/7) with minimum operator supervision. Continuous run was carried out for 40 days. Very high SOx (>99.9%) and NOx (98%) removal efficiencies were also achieved in a continuous unit. However, the retention capacity of carbon beds for SOx and NOx was decreased from ~20 hours to ~10 hours over a 40 day period of operation, which was in contrast to the results obtained in a batch unit. These contradictory results indicate the need for optimization of adsorption-regeneration cycle to maintain long term activity of activated carbon material at a higher level and thus minimize the capital cost of the system. In summary, the activated carbon process exceeded performance targets for SOx and NOx removal efficiencies and it was found to be suitable for power plants burning both low and high sulfur coals. More efforts are needed to optimize the system performance.

Monica Zanfir; Rahul Solunke; Minish Shah

2012-06-01T23:59:59.000Z

Note: This page contains sample records for the topic "nox carbon monoxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Carbon dioxide capture process with regenerable sorbents  

DOE Patents [OSTI]

A process to remove carbon dioxide from a gas stream using a cross-flow, or a moving-bed reactor. In the reactor the gas contacts an active material that is an alkali-metal compound, such as an alkali-metal carbonate, alkali-metal oxide, or alkali-metal hydroxide; or in the alternative, an alkaline-earth metal compound, such as an alkaline-earth metal carbonate, alkaline-earth metal oxide, or alkaline-earth metal hydroxide. The active material can be used by itself or supported on a substrate of carbon, alumina, silica, titania or aluminosilicate. When the active material is an alkali-metal compound, the carbon-dioxide reacts with the metal compound to generate bicarbonate. When the active material is an alkaline-earth metal, the carbon dioxide reacts with the metal compound to generate carbonate. Spent sorbent containing the bicarbonate or carbonate is moved to a second reactor where it is heated or treated with a reducing agent such as, natural gas, methane, carbon monoxide hydrogen, or a synthesis gas comprising of a combination of carbon monoxide and hydrogen. The heat or reducing agent releases carbon dioxide gas and regenerates the active material for use as the sorbent material in the first reactor. New sorbent may be added to the regenerated sorbent prior to subsequent passes in the carbon dioxide removal reactor.

Pennline, Henry W. (Bethel Park, PA); Hoffman, James S. (Library, PA)

2002-05-14T23:59:59.000Z

262

The ebullition of hydrogen, carbon monoxide, methane, carbon dioxide and total gaseous mercury  

E-Print Network [OSTI]

of gaseous species depends of their solubility in the water. Since CH4 is relatively insoluble, ebullition-product of the respiration and is highly soluble in the water, leading ofte h- 1 . Measurements of H2, CO, CH4 and CO2 trapped gas concentrations and fluxes were used

O'Driscoll, Nelson

263

Electrocatalytic reduction of carbon dioxide to carbon monoxide by rhenium and manganese polypyridyl catalysts  

E-Print Network [OSTI]

are on the decline of the peak oil production curve, and thedue to the impending peak in oil production and the threatoil production curves for those countries that have passed peak

Smieja, Jonathan Mark

2012-01-01T23:59:59.000Z

264

Electrocatalytic reduction of carbon dioxide to carbon monoxide by rhenium and manganese polypyridyl catalysts  

E-Print Network [OSTI]

graph displays not only the shift in energy from wood to fossil fuels but also shows that total energy usagegraph displays not only the shift in energy from wood to fossil fuels, but also shows that total energy usage

Smieja, Jonathan Mark

2012-01-01T23:59:59.000Z

265

Electrocatalytic reduction of carbon dioxide to carbon monoxide by rhenium and manganese polypyridyl catalysts  

E-Print Network [OSTI]

compressed air and hydrogen production are all frequently discussed as viable options for future energy storage.

Smieja, Jonathan Mark

2012-01-01T23:59:59.000Z

266

Carbon monoxide and carbon dioxide concentrations in Santiago de Chile associated with traffic emissions  

Science Journals Connector (OSTI)

CO/CO2 ratios have been measured in different locations of Santiago de Chile city. Measurements were carried out in a tunnel (prevailing emissions from cars with catalytic converter) and close to heavy traffic st...

María A. Rubio; Irene Fuenzalida…

2010-03-01T23:59:59.000Z

267

Short-term effects of air pollution: a panel study of blood markers in patients with chronic pulmonary disease  

E-Print Network [OSTI]

monoxide [NO], nitrogen dioxide [NO 2 ], carbon monoxide [monoxide (NO), nitrogen dioxide (NO 2 ), carbon monoxide (dioxide; NO 2 , nitrogen dioxide; CO, carbon monoxide; NO,

2009-01-01T23:59:59.000Z

268

A New Solar Carbon Capture Process: Solar Thermal Electrochemical Photo (STEP) Carbon Capture  

Science Journals Connector (OSTI)

A New Solar Carbon Capture Process: Solar Thermal Electrochemical Photo (STEP) Carbon Capture ... CO2 can be captured from 34% to over 50% solar energy efficiency (depending on the level of solar heat inclusion), as solid carbon and stored, or used as carbon monoxide to be available for a feedstock to synthesize (with STEP generated hydrogen) solar diesel fuel, synthetic jet fuel, or chemical production. ... STEP Iron, a Chemistry of Iron Formation without CO2 Emission: Molten Carbonate Solubility and Electrochemistry of Iron Ore Impurities ...

Stuart Licht; Baohui Wang; Susanta Ghosh; Hina Ayub; Dianlu Jiang; Jason Ganley

2010-07-14T23:59:59.000Z

269

LOW NOx EMISSIONS IN A FUEL FLEXIBLE GAS TURBINE  

SciTech Connect (OSTI)

In alignment with Vision 21 goals, a study is presented here on the technical and economic potential for developing a gas turbine combustor that is capable of generating less that 2 ppm NOx emissions, firing on either coal synthesis gas or natural gas, and being implemented on new and existing systems. The proposed solution involves controlling the quantity of H2 contained in the fuel. The presence of H2 leads to increased flame stability such that the combustor can be operated at lower temperatures and produce less thermal NOx. Coal gas composition would be modified using a water gas shift converter, and natural gas units would implement a catalytic partial oxidation (CPOX) reactor to convert part of the natural gas feed to a syngas before fed back into the combustor. While both systems demonstrated technical merit, the economics involved in implementing such a system are marginal at best. Therefore, Praxair has decided not to pursue the technology any further at this time.

Raymond Drnevich; James Meagher; Vasilis Papavassiliou; Troy Raybold; Peter Stuttaford; Leonard Switzer; Lee Rosen

2004-08-01T23:59:59.000Z

270

Diesel Aftertreatment Modeling:? A Systems Approach to NOx Control  

Science Journals Connector (OSTI)

Diesel Aftertreatment Modeling:? A Systems Approach to NOx Control ... Despite these challenges, the proposed system was able to make several advances:? (1) meeting the T2B5 CO, HC, and PM standards; (2) quantifying the ability to meet T2B5 NOx levels with a more durable DOC and a rapid warm-up strategy to heat the exhaust, especially during the initial cold-start portion of the Federal Test Procedure (FTP) drive cycle. ... The remainder of this work is organized as follows:? The formulation, calibration, and validation of the DOC and SCR models are presented in section 2. The DOC and SCR models are combined for an analysis of the AT system as a whole in section 3. The final section of the article summarizes the results and offers some general conclusions. ...

Santhoji R. Katare; Joseph E. Patterson; Paul M. Laing

2007-03-16T23:59:59.000Z

271

Carbon capture by sorption-enhanced water-gas shift reaction process using hydrotalcite-based material  

SciTech Connect (OSTI)

A novel route for precombustion decarbonization is the sorption-enhanced water-gas shift (SEWGS) process. In this process carbon dioxide is removed from a synthesis gas at elevated temperature by adsorption. Simultaneously, carbon monoxide is converted to carbon dioxide by the water-gas shift reaction. The periodic adsorption and desorption of carbon dioxide is induced by a pressure swing cycle, and the cyclic capacity can be amplified by purging with steam. From previous studies is it known that for SEWGS applications, hydrotalcite-based materials are particularly attractive as sorbent, and commercial high-temperature shift catalysts can be used for the conversion of carbon monoxide. Tablets of a potassium promoted hydrotalcite-based material are characterized in both breakthrough and cyclic experiments in a 2 m tall fixed-bed reactor. When exposed to a mixture of carbon dioxide, steam, and nitrogen at 400{sup o}C, the material shows a breakthrough capacity of 1.4 mmol/g. In subsequent experiments the material was mixed with tablets of promoted iron-chromium shift catalyst and exposed to a mixture of carbon dioxide, carbon monoxide, steam, hydrogen, and nitrogen. It is demonstrated that carbon monoxide conversion can be enhanced to 100% in the presence of a carbon dioxide sorbent. At breakthrough, carbon monoxide and carbon dioxide simultaneously appear at the end of the bed. During more than 300 cycles of adsorption/reaction and desorption, the capture rate, and carbon monoxide conversion are confirmed to be stable. Two different cycle types are investigated: one cycle with a CO{sub 2} rinse step and one cycle with a steam rinse step. The performance of both SEWGS cycles are discussed.

van Selow, E.R.; Cobden, P.D.; Verbraeken, P.A.; Hufton, J.R.; van den Brink, R.W. [Energy research Center of the Netherlands, Petten (Netherlands)

2009-05-15T23:59:59.000Z

272

A Fast Start-up On-Board Fuel Reformer for NOx Adsorber Regeneration...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Fuel Processor for Rapid and Efficient Regeneration of Single Leg NOx Adsorber Systems Hydrogen generation from plasmatron reformers and use for diesel exhaust aftertreatment...

273

High-Throughput Program for the Discovery of NOx Reduction Catalysts...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

2004deerblint.pdf More Documents & Publications WA02042GENERALMOTORSPOWERTRAINDIVWaiverofDomestic.pdf Heavy-Duty NOx Emissions Control: Reformer-Assisted vs....

274

Boosted HCCI for High Power without Engine Knock, and with Ultra-Low NOX Emissions  

Broader source: Energy.gov [DOE]

Advanced engines using HCCI or HCCI-like combustion can provide both high efficiencies and very low emissions of NOX and PM

275

Synergies of High-Efficiency Clean Combustion and Lean NOx Trap...  

Broader source: Energy.gov (indexed) [DOE]

Combustion and Lean NOx Trap Catalysts investigation of potential synergies of low emission advanced combustion techniques and advanced lean exhaust catalytic aftertreatment....

276

E-Print Network 3.0 - aluminosilicates nox reduction Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

RELATIONSHIP BETWEEN Summary: Non-Catalytic Reduction SNCR NOx control throughout the United States and Canada. They correspond... explain why mass balances are not an appro...

277

Flexible CHP System with Low NOx, CO and VOC Emissions | Department...  

Broader source: Energy.gov (indexed) [DOE]

Emissions Flexible CHP System with Low NOx, CO and VOC Emissions Introduction A combined heat and power (CHP) system can be a financially attractive energy option for many...

278

Reduce NOx and Improve Energy Efficiency, Software Tools for Industry, Industrial Technologies Program (ITP) (Fact Sheet)  

SciTech Connect (OSTI)

This fact sheet describes how the Industrial Technologies Program NOx and Energy Assessment Tool (NxEAT) can help petroleum refining and chemical plants improve energy efficiency.

Not Available

2008-12-01T23:59:59.000Z

279

Deactivation mechanisms of NOx storage materials arising from thermal aging and sulfur poisoning  

Broader source: Energy.gov [DOE]

Presents the reliationship between Pt particle size and NOx storage performance over model catalysts. Novel reaction protocol designed to decouple effects of thermal deactivation and incomplete desulfation.

280

16 - Ultra-low nitrogen oxides (NOx) emissions combustion in gas turbine systems  

Science Journals Connector (OSTI)

Abstract: The historical development of gas turbine low \\{NOx\\} combustion from the pioneering NASA work in the early 1970s to the present generation of ultra-low \\{NOx\\} industrial gas turbine combustors is reviewed. The principles of operation of single digit ultra-low \\{NOx\\} gas turbine combustion for industrial applications are outlined. The review shows the potential has been demonstrated by several investigators using different flame stabilizers for \\{NOx\\} to be reduced to 1 ppm at 1700 K, 2 ppm at 1800 K and 3–4 ppm at 1900 K with no influence of operating pressure and with a practical operating flame stability margin. Under these conditions it is shown that no thermal \\{NOx\\} should occur and all the \\{NOx\\} is formed by the prompt \\{NOx\\} mechanisms. The elimination of thermal \\{NOx\\} makes the \\{NOx\\} emissions independent of residence time or reference velocity and independent of pressure. Also there is no influence of air inlet temperature for the same flame temperature. Where legislation requires emissions to be as low as can be achieved, emissions below 4 ppm in production engines are current technology and this review shows the potential to get even lower than this in the future.

G.E. Andrews

2013-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "nox carbon monoxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

METHANE de-NOX FOR UTILITY PC BOILERS  

SciTech Connect (OSTI)

The project seeks to develop and validate a new pulverized coal combustion system to reduce utility PC boiler NOx emissions to 0.15 lb per million Btu or less without post-combustion flue gas cleaning. Work during previous reporting periods completed the design, installation, shakedown and initial PRB coal testing of a 3-million Btu/h pilot system at BBP's Pilot-Scale Combustion Facility (PSCF) in Worcester, MA. Based on these results, modifications to the gas-fired preheat combustor and PC burner were defined, along with a modified testing plan and schedule. A revised subcontract was executed with BBP to reflect changes in the pilot testing program. Modeling activities were continued to develop and verify revised design approaches for both the Preheat gas combustor and PC burner. Reactivation of the pilot test system was then begun with BBP personnel. During the previous reporting period, reactivation of the pilot test system was completed with the modified Preheat gas combustor. Following shakedown of the modified gas combustor alone, a series of successful tests of the new combustor with PRB coal using the original PC burner were completed. NOx at the furnace exit was reduced significantly with the modified gas combustor, to as low as 150 ppm with only 36 ppm CO (both corrected to 3% O2). Concurrent with testing, GTI and BBP collaborated on development of two modified designs for the PC burner optimized to fire preheated char and pyrolysis products from the Preheat gas combustor. During the current reporting period, one of the two modified PC burner designs was fabricated and installed in the pilot test facility. Testing of the modified pilot system (modified gas combustor and modified PC burner) during the quarter included 38 tests with PRB coal. NOx reduction was significantly improved to levels as low as 60-100 ppmv with CO in the range of 35-112 ppmv without any furnace air staging.

Joseph Rabovitser; Bruce Bryan; Serguei Nester; Stan Wohadlo

2002-01-31T23:59:59.000Z

282

NOx CONTROL OPTIONS AND INTEGRATION FOR US COAL FIRED BOILERS  

SciTech Connect (OSTI)

This is the fifth Quarterly Technical Report for DOE Cooperative Agreement No: DE-FC26-00NT40753. The goal of the project is to develop cost effective analysis tools and techniques for demonstrating and evaluating low NOx control strategies and their possible impact on boiler performance for firing US coals. The Electric Power Research Institute (EPRI) is providing cofunding for this program. This program contains multiple tasks and good progress is being made on all fronts. Field tests for NOx reduction in a cyclone fired utility boiler due to using Rich Reagent Injection (RRI) have been started. CFD modeling studies have been started to evaluate the use of RRI for NOx reduction in a corner fired utility boiler using pulverized coal. Field tests of a corrosion monitor to measure waterwall wastage in a utility boiler have been completed. Computational studies to evaluate a soot model within a boiler simulation program are continuing. Research to evaluate SCR catalyst performance has started. A literature survey was completed. Experiments have been outlined and two flow reactor systems have been designed and are under construction. Commercial catalyst vendors have been contacted about supplying catalyst samples. Several sets of new experiments have been performed to investigate ammonia removal processes and mechanisms for fly ash. Work has focused on a promising class of processes in which ammonia is destroyed by strong oxidizing agents at ambient temperature during semi-dry processing (the use of moisture amounts less than 5 wt-%). Both ozone and an ozone/peroxide combination have been used to treat both basic and acidic ammonia-laden ashes.

Mike Bockelie; Marc Cremer; Kevin Davis; Connie Senior; Bob Hurt; Eric Eddings; Larry Baxter

2001-10-10T23:59:59.000Z

283

SOx/NOx sorbent and process of use  

DOE Patents [OSTI]

An alumina sorbent capable of adsorbing NOx and SOx from waste gases and being regenerated by heating above 600 C. is made by incorporating an alumina stabilizing agent into the sorbent. A preferred method is to add the stabilizer when the alumina is precipitated. The precipitated powder is formed subsequently into a slurry, milled and dripped to form the stabilizing spheroidal alumina particles. These particles are impregnated with an alkali metal or alkaline earth metal to form the stabilized sorbent. Alumina stabilizers include one or more of silica, lanthana, other rare earths, titania, zirconia and alkaline earths.

Ziebarth, M.S.; Hager, M.J.; Beeckman, J.W.; Plecha, S.

1993-01-19T23:59:59.000Z

284

Global impact of fossil fuel combustion on atmospheric NOx Larry W. Horowitz  

E-Print Network [OSTI]

potential than emissions in the United States to perturb the global oxidizing power of the atmosphere. #12% of NOx concentrations in the lower and middle troposphere throughout the extratropical northern of the ocean. Sources in the United States are found to contribute about half of the fossil fuel NOx over

Jacob, Daniel J.

285

On the NOx production by laboratory electrical discharges and lightning Vernon Cooraya,, Mahbubur Rahman a  

E-Print Network [OSTI]

in estimating the global production of NOx by lightning flashes, including field measurements carried out during influence extrapolation of laboratory data to lightning flashes. Second, an estimation of the NOx yield per lightning flash is made by treating the lightning flash as a composite event consisting of several discharge

Florida, University of

286

Measurements of NOX produced by rocket-triggered lightning M. Rahman,1  

E-Print Network [OSTI]

lightning flashes were triggered using the rocket- and-wire technique at the International Center atmosphere. [3] A direct measurement of the NOX generated by a natural lightning flash is impractical because generated by lightning flashes. Due to a large number of uncertainties involved, the estimates of global NOX

Florida, University of

287

A Novel Technology for the Reduction of NOx on Char by Microwaves  

E-Print Network [OSTI]

of these applications. The technology is directed at NOx reduction but may also address other pollutants like SO2. The technology employees char, a heat treated and devolitilized form of coal, to adsorb NOx from the flue (or waste) gas. Adsorption of greater than 99...

Buenger, C.; Peterson, E.

288

Improvement of lightning NOx in the TM5 global chemistry transport model  

E-Print Network [OSTI]

, a key greenhouse gas, and for the formation of the hydroxyl28 radical, which removes methane, also a key greenhouse gas. Estimates of the global lightning NOx production vary29 by an order of magnitude interpreting the lighting NOx contribu-36 tion from satellite and aircraft observations of NO2 in comparison

Haak, Hein

289

Development of a Stand-Alone Urea-SCR System for NOx Reduction in Marine Diesel Engines  

Broader source: Energy.gov [DOE]

Stand-alone urea SCR system was developed for marine diesel engines and showed a 50-percent reduction in NOx.

290

Development of Compact Gaseous Sensors with Internal Reference for Monitoring O2 and NOx in Combustion Environments  

Broader source: Energy.gov [DOE]

Compact sensors have been developed to allow for real-time monitoring of O2 and NOx during combustion.

291

2004 Conference on Reburning for NOX Control Reburning on Trial  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

2004 Conf. on Reburning for NOx Control Reburning on Trial 2004 Conf. on Reburning for NOx Control Reburning on Trial May 18, 2004 Table of Contents Disclaimer Papers and Presentations Reburning Overview Commercial Reburning Experience Biomass Reburning Other Applications of Reburning Posters Disclaimer This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government or any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. Reference herein to any specific commercial product, process, or service by trade name, trademark, manufacturer, or otherwise does not necessarily constitute or imply its endorsement, recommendation, or favoring by the United States Government or any agency thereof. The views and opinions of authors expressed herein do not necessarily state or reflect those of the United States Government or any agency thereof.

292

Mechanistical studies on the formation and destruction of carbon monoxide (CO), carbon dioxide (CO2), and carbon trioxide (CO3)  

E-Print Network [OSTI]

) in extraterrestrial, low temperature ices. Reactants and products were analyzed on line and in situ via absorption with a 1/r2 dependence, r being the distance from the sun, and thus becomes less important when the outer% H+ , 2% He2+ , and few heavier nuclei; the energy distribution maximum peaks at around 10 MeV where

Kaiser, Ralf I.

293

NETL: PPII - Integration of Low-NOx Burners with an Optimization Plan for  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Integration of Low-NOx Burners with an Optimization Plan for Boiler Combustion Integration of Low-NOx Burners with an Optimization Plan for Boiler Combustion - Project Brief [PDF-72KB] Sunflower Electric Power Corp., Garden City, Finney County, KS PROJECT FACT SHEET Achieving New Source Performance Standards (NSPS) Through Integration of Low-NOx Burners with an Optimization Plan for Boiler Combustion [PDF-260KB] (Oct 2008) PROGRAM PUBLICATIONS Final Report Achieving NSPS Emission Standards Through Integration of Low NOx Burners with an Optimization Plan for Boiler Combustion [PDF-3.4MB] (June 2006) CCT Reports: Project Performance Summaries, Post-Project Assessments, & Topical Reports Achieving New Source Performance Standards (NSPS) Emission Standards through Integration of Low-NOx Burners with an Optimization Plan for Boiler Combustion: A DOE Assessment [PDF-1.4MB] (Nov 2006)

294

EA-1472: Commercial Demonstration fo the Low Nox Burner/Separated Over-Fire  

Broader source: Energy.gov (indexed) [DOE]

472: Commercial Demonstration fo the Low Nox Burner/Separated 472: Commercial Demonstration fo the Low Nox Burner/Separated Over-Fire Air (LNB/SOFA) Integration System Emission Reduction Technology, Holcolm Station, Sunflower Electric Power Corporation Finnety County, Kansas EA-1472: Commercial Demonstration fo the Low Nox Burner/Separated Over-Fire Air (LNB/SOFA) Integration System Emission Reduction Technology, Holcolm Station, Sunflower Electric Power Corporation Finnety County, Kansas SUMMARY The DOE has prepared an Environmental Assessment (EA), to analyze the potential impacts of the commercial application of the Low-NOx Burner/Separated Over-Fire Air (LNB/SOFA) integration system to achieve nitrogen oxide (NOx) emissions reduction at Sunflower's Holcomb Unit No. 1 (Holcomb Station), located near Garden City, in Finney County, Kansas.

295

NETL: News Release - DOE Selects Five NOx-Control Projects to Combat Acid  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

November 5, 2004 November 5, 2004 DOE Selects Five NOx-Control Projects to Combat Acid Rain and Smog Industry Partners to Focus on Reducing Emissions While Cutting Energy Costs PITTSBURGH, PA - Continuing efforts to cut acid rain and smog-producing nitrogen oxides (NOx) have prompted the U.S. Department of Energy to partner with industry experts to develop advanced NOx-control technologies. With the selection of five new NOx-control projects, the Energy Department continues as a leader in developing advanced technologies to achieve environmental compliance for the nation's fleet of coal-fired power plants. Although today's NOx-control workhorses, such as low-NOx burners and selective catalytic reduction (SCR), have been successfully deployed to address existing regulations, proposed regulations will require deeper cuts in NOx emissions, at a greater number of generating facilities. Many of the smaller affected plants will not be able to cost-effectively use today's technologies; these are the focus of the advanced technologies selected in this announcement.

296

Low NOx burner retrofits and enhancements for a 518 MW oil and gas fired boiler  

SciTech Connect (OSTI)

Low NOx oil/gas burners originally supplied to Jacksonville Electric Authority, Northside No. 3 .500 MW unit, were based on a duplex air register design with lobed spray oil atomizers providing additional fuel staging. Although the burners could meet the targeted NOx levels of 0.3 and 0.2 lbs/10{sup 6} BTU on oil and gas respectively. There was insufficient margin on these NOx levels to enable continuous low NOx operation to be achieved. Further burner development was undertaken based on improved aerodynamic control within the burner design to give an approximate 25% improvement in NOx emission reduction thus providing an adequate operating margin. This `RoBTAS` (Round Burner with Tilted Air Supply) burner design based on techniques developed successfully for front wall coal firing applications achieved the required NOx reductions in full scale firing demonstrations on both heavy fuel oil and natural gas firing. The paper describes the development work and the subsequent application of the `RoBTAS` burners to the Northside No. 3 boiler. The burner will also be test fired on Orimulsion fuel and thus the comparison between heavy fuel oil firing and Orimulsion firing under ultra low NOx conditions will be made.

King, J.J. [Jacksonville Electric Authority, FL (United States); Allen, J.W.; Beal, P.R. [International Combustion Ltd., Derby (United Kingdom). Rolls-Royce Industrial Power Group

1995-12-31T23:59:59.000Z

297

Nitrogen Oxides (NOx), Why and How They are Controlled  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Air Quality EPA 456/F-99-006R Air Quality EPA 456/F-99-006R Environmental Protection Planning and Standards November 1999 Agency Research Triangle Park, NC 27711 Air EPA-456/F-99-006R November 1999 Nitrogen Oxides (NOx), Why and How They Are Controlled Prepared by Clean Air Technology Center (MD-12) Information Transfer and Program Integration Division Office of Air Quality Planning and Standards U.S. Environmental Protection Agency Research Triangle Park, North Carolina 27711 ii DISCLAIMER This report has been reviewed by the Information Transfer and Program Integration Division of the Office of Air Quality Planning and Standards, U.S. Environmental Protection Agency and approved for publication. Approval does not signify that the contents of this report reflect the views and policies of the U.S. Environmental Protection Agency. Mention of trade

298

Low NOx nozzle tip for a pulverized solid fuel furnace  

DOE Patents [OSTI]

A nozzle tip [100] for a pulverized solid fuel pipe nozzle [200] of a pulverized solid fuel-fired furnace includes: a primary air shroud [120] having an inlet [102] and an outlet [104], wherein the inlet [102] receives a fuel flow [230]; and a flow splitter [180] disposed within the primary air shroud [120], wherein the flow splitter disperses particles in the fuel flow [230] to the outlet [104] to provide a fuel flow jet which reduces NOx in the pulverized solid fuel-fired furnace. In alternative embodiments, the flow splitter [180] may be wedge shaped and extend partially or entirely across the outlet [104]. In another alternative embodiment, flow splitter [180] may be moved forward toward the inlet [102] to create a recessed design.

Donais, Richard E; Hellewell, Todd D; Lewis, Robert D; Richards, Galen H; Towle, David P

2014-04-22T23:59:59.000Z

299

METHANE de-NOX FOR UTILITY PC BOILERS  

SciTech Connect (OSTI)

The project seeks to develop and validate a new pulverized coal combustion system to reduce utility PC boiler NOx emissions to 0.15 lb/million Btu or less without post-combustion flue gas cleaning. Work during previous reporting periods completed the design, installation, shakedown and initial PRB coal testing of a 3-million Btu/h pilot system at BBP's Pilot-Scale Combustion Facility (PSCF) in Worcester, MA. Based on these results, modifications to the gas-fired preheat combustor and PC burner were defined, along with a modified testing plan and schedule. During the current reporting period, BBP's subcontract was modified to reflect changes in the pilot testing program, and the modifications to the gas-fired preheat combustor were completed. The Computational Fluid Dynamics (CFD) modeling approach was defined for the combined PC burner and 3-million Btu/h pilot system. Modeling of the modified gas-fired preheat combustor was also started.

Joseph Rabovitser; Bruce Bryan; Serguei Nester; Stan Wohadlo

2002-04-29T23:59:59.000Z

300

METHANE DE-NOX FOR UTILITY PC BOILERS  

SciTech Connect (OSTI)

The primary focus for the project continues to be on developing a PC PREHEAT system design suitable for use with caking coals and readying the 100 MMBtu/h CBTF for testing with noncaking PRB coal. During the current quarter, twenty-two pilot tests were conducted with Central Appalachian (CA) caking coal. The objective for these tests was to achieve continuous operation of the pilot system at its design coal feed rate of 156 lb/h, without plugging or agglomeration in the combustor. One combustor air distribution method tested achieved continuous operation at 110 lb/hr, and inspection of the combustor afterward indicated that this method has potential to solve the caking problem. The NOx results from the pilot caking coal runs indicate that even greater NOx reduction is possible with CA coal than with the PRB coal tested, to levels near 100 ppmv or lower at 4-6% exit oxygen. It was therefore decided to conduct additional pilot tests of the air distribution method to determine how to incorporate this into a workable CA combustor design. Based on current weather and manpower restrictions at the site, this pilot testing is expected to be started in February. The design for the 100 MMBtu/h unit for PRB testing in the CBTF was completed and fabrication and installation started during the quarter. While significant progress has been made in the installation of the unit, weather and combustor fabrication delays are expected to move the start of large-scale testing with PRB coal into February, which will push the project completion date beyond the current 3/30/04 end date. GTI is in the process of developing a revised project schedule and estimated cost to complete.

Bruce Bryan; Joseph Rabovitser; Serguei Nester; Stan Wohadlo

2004-02-06T23:59:59.000Z

Note: This page contains sample records for the topic "nox carbon monoxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

METHANE de-NOX for Utility PC Boilers  

SciTech Connect (OSTI)

The primary focus for the project during the quarter was shakedown testing of the large-scale coal preheater prototype in the CBTF with non-caking PRB coal. Additional pilot-scale tests were conducted in the PSCF in support of developing a preheating system design suitable for use with caking coals. Thirty-two additional pilot tests were conducted during the quarter with caking coal. These tests further evaluated the use of the air-bleed and indirect air-cooled liner designs to reduce or eliminate combustor plugging with caking coal. The air-bleed configurations tested used air injection holes perpendicular to the liner's longitudinal axis with the number, size and air flow though the air-bleed holes varied to determine the effect on combustor plugging. The indirect cooling configurations tested included a stainless steel liner with spiral fins in the annular space between the liner and the combustor wall, and a silicon carbide liner without fins. Continuous pilot operation was maintained for up to 30 minutes at a coal feed rate of 50 lb/h with the air-bleed liner. The best result achieved was for the stainless steel indirect air-cooled liner with 20 minutes of continuous operation at 126 lb/h of coal followed by an additional 20 minutes at 150 lb/h. The NOx results from these continue to indicate that even greater NOx reduction is possible with caking coal than with the PRB coal tested. The installation of the large-scale prototype coal preheater for PRB testing in the CBTF was completed and shakedown testing with natural gas and PRB coal started during the quarter. Stable operation of the coal system, combustor and burner were achieved at coal feed rates up to 6000 lb/h (50 MMBtu/h).

Bruce Bryan; Joseph Rabovitser Serguei Nester; Stan Wohadlo

2004-06-30T23:59:59.000Z

302

Influencing factors on NOX emission level during grate conversion of three pelletized energy crops  

Science Journals Connector (OSTI)

Abstract NOX emission behavior of three different pelletized energy crops, a herbaceous one, Brassica carinata, a short rotation coppice, Populus sp., and a blend of them, was assessed during fixed grate conversion. Measurements of NOX emissions were done at combustion conditions that yielded both thermal efficiency and CO emissions according to the European norm (EN 303-5:2012), and results compared to limits established by the Austrian deviations. Based on the experimental data, NOX results fulfilled the Austrian restrictions except during combustion of brassica, which exhibited the highest Fuel-N content. The Fuel-NOX was identified as the main formation mechanism. An opposite relation was determined between the specific NOX emissions and the Fuel-N conversion ratio obtained between the N-rich and the N-lean fuels tested here. The influence of the air supply (amount and distribution) on the NOX formation was also noticeable. In general, a higher proportion of air increased the specific NOX emissions and the Fuel-N conversion ratio. Possibilities to control the NOX emissions level by air staging were rather limited, particularly, during combustion of brassica and the blend because of their peculiarities as ash-rich fuels with high slag formation risk. For attaining an appropriate conversion of these fuels, primary air requirements substantially increased. Due to limitations found during the energy crops conversion, efforts to minimize the level of NOX emissions identified here for the troublesome fuels tested should be mainly focused on attaining both a properly designed air supply system and the grate temperature control as well as on conditioning the Fuel-N content, for instance, by blending.

Maryori Díaz-Ramírez; Fernando Sebastián; Javier Royo; Adeline Rezeau

2014-01-01T23:59:59.000Z

303

Shifting primary energy source and NOx emission location with plug-in hybrid vehicles  

Science Journals Connector (OSTI)

Plug-in hybrid vehicles (PHEVs) present an interesting technological opportunity for using non-fossil primary energy in light duty passenger vehicles, with the associated potential for reducing air pollutant and greenhouse gas emissions, to the extent that the electric power grid is fed by non-fossil sources. This perspective, accompanying the article by Thompson et al (2011) in this issue, will touch on two other studies that are directly related: the Argonne study (Elgowainy et al 2010) and a PhD thesis from Utrecht (van Vliet 2010). Thompson et al (2011) have examined air quality effects in a case where the grid is predominantly fossil fed. They estimate a reduction of 7.42 tons/day of NOx from motor vehicles as a result of substituting electric VMTs for 20% of the light duty gasoline vehicle miles traveled. To estimate the impact of this reduction on air quality they also consider the increases in NOx emissions due to the increased load on electricity generating units. The NOx emission increases are estimated as 4.0, 5.5 and 6.3 tons for the Convenience, Battery and Night charging scenarios respectively. The net reductions are thus in the 1.1–3.4 tons/day range. The air quality modelling results presented show that the air quality impact from a ground-level ozone perspective is favorable overall, and while the effect is stronger in some localities, the difference between the three scenarios is small. This is quite significant and suggests that localization of the NOx emissions to point sources has a more pronounced effect than the absolute reductions achieved. Furthermore it demonstrates that localization of NOx emissions to electricity generating units by using PHEVs in vehicle traffic has beneficial effects for air quality not only by minimizing direct human exposure to motor vehicle emissions, but also due to reduced exposure to secondary pollutants (i.e. ozone). In an electric power grid with a smaller share of fossil fired generating units, the beneficial effects would be more pronounced. In such a case, it would also be possible to realize reductions in greenhouse gas emissions. The significance of the electric power generation mix for plug-in hybrid vehicles and battery electric vehicles is a key aspect of Argonne National Laboratories' well-to-wheel study which focuses on petroleum use and greenhouse gas emissions (Elgowainy et al 2010). The study evaluates possible reductions in petroleum use and GHG emissions in the electric power systems in four major regions of the United States as well as the US average generation mix, using Argonne's GREET life-cycle analysis model. Two PHEV designs are investigated through a Powertrain System Analysis Toolkit (PSAT) model: the power-split configuration (e.g. the current Toyota Prius model with Hymotion conversion), and a future series configuration where the engine powers a generator, which charges a battery that is used by the electric motor to propel the vehicle. Since the petroleum share is small in the electricity generation mix for most regions in the United States, it is possible to achieve significant reductions in petroleum use by PHEVs. However, GHG reduction is another story. In one of the cases in the study, PHEVs in the charge depleting mode and recharging from a mix with a large share of coal generation (e.g., Illinois marginal mix) produce GHG emissions comparable to those of baseline gasoline internal combustion engine vehicles (with a range from ?15% to +10%) but significantly higher than those of gasoline hybrid electric vehicles (with a range from +20% to +60%). In what is called the unconstrained charging scenario where investments in new generation capacity with high efficiency and low carbon intensity are envisaged, it becomes possible to achieve significant reductions in both petroleum use and GHG emissions. In a PhD dissertation at Utrecht University, van Vliet (2010) presents a comprehensive analysis of alternatives to gasoline and diesel by looking at various fuel and vehicle technologies. Three chapters are of particular interest from the

Deniz Karman

2011-01-01T23:59:59.000Z

304

Exergy analysis of combustion characteristics and NOx emissions of a dual-fuel engine  

Science Journals Connector (OSTI)

The combustion characteristics and NOx emissions of compression ignition engines working on a dual fuel mode are investigated numerically and their exergetic efficiencies are determined. The model has been validated with available experimental results. The simulation results show that dual fuel engine combustion and trend of NOx emissions are well predicted by the present model. Parametric study showed improvements in engine performance and an increase in NOx emissions with decreased advanced injection timing of the pilot fuel as well as with increased intake temperature and pilot fuel quantity. The maximum values for energy and exergy are found to be comparable.

Mohamed H. Morsy; Abdelrahman El-Leathy; Arif Hepbasli

2012-01-01T23:59:59.000Z

305

Catalysis of hydrocarbon synthesis from CO and H{sub 2} on carbon membranes  

SciTech Connect (OSTI)

This paper describes the preparation of carbon membrane supports from polyacrylonitrile. The membranes were utilized for the preparation of cobalt catalysts. The catalysts were prepared by impregnating the membranes with a cobalt nitrate solution followed by drying on a water bath. The cobalt was sometimes introduced directly into the molding solution before the activation stage. The cobalt catalysts were utilized in the methanation of carbon monoxide. The products were dependent on the conditions utilized to obtain the carbon supports.

Lapidus, A.l.; Krylova, A.Yu.; Strupov, A.N.; Linkov, V.M.; Sanderson, R.D. [Rossiiskaya Akademiya, Nauk (Russian Federation)

1994-12-31T23:59:59.000Z

306

Definition: Reduced Sox, Nox, And Pm-2.5 Emissions | Open Energy  

Open Energy Info (EERE)

Sox, Nox, And Pm-2.5 Emissions Sox, Nox, And Pm-2.5 Emissions Jump to: navigation, search Dictionary.png Reduced Sox, Nox, And Pm-2.5 Emissions Functions that provide this benefit can lead to avoided vehicle miles, decrease the amount of central generation needed to their serve load (through reduced electricity consumption, reduced electricity losses, more optimal generation dispatch), and or reduce peak generation. These impacts translate into a reduction in pollutant emissions produced by fossil-based electricity generators and vehicles.[1] Related Terms electricity generation, reduced electricity losses, smart grid References ↑ SmartGrid.gov 'Description of Benefits' An in LikeLike UnlikeLike You like this.Sign Up to see what your friends like. line Glossary Definition Retrieved from "http://en.openei.org/w/index.php?title=Definition:Reduced_Sox,_Nox,_And_Pm-2.5_Emissions&oldid=502508

307

Demonstration of a Low-NOx Heavy-Duty Natural Gas Engine  

SciTech Connect (OSTI)

Results of a Next Generation Natural Gas Vehicle engine research project: A Caterpillar C-12 natural gas engine with Clean Air Power Dual-Fuel technology and exhaust gas recirculation demonstrated low NOx and PM emissions.

Not Available

2004-02-01T23:59:59.000Z

308

NH3 generation over commercial Three-Way Catalysts and Lean-NOx...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

formulations and operation for the in-situ generation of NH3, storage on a downstream SCR catalyst, and utilized to reduce the remaining NOx deer12toops.pdf More Documents &...

309

NOx Emissions of Alternative Diesel Fuels:? A Comparative Analysis of Biodiesel and FT Diesel  

Science Journals Connector (OSTI)

This study explores the diesel injection and combustion processes in an effort to better understand the differences in NOx emissions between biodiesel, Fischer?Tropsch (FT) diesel, and their blends with a conventional diesel fuel. Emissions studies were ...

James P. Szybist; Stephen R. Kirby; André L. Boehman

2005-05-14T23:59:59.000Z

310

Sulphur Removal Characteristics from a Commercial NOx Storage/Reduction Catalyst.  

E-Print Network [OSTI]

??The ability to effectively remove sulphur from sulphur-poisoned NOx storage/reduction (NSR) catalysts, while minimizing associated fuel penalties and thermal degradation, is important for commercial application… (more)

Kisinger, Darren

2009-01-01T23:59:59.000Z

311

A design strategy applied to sulfur resistant lean NOx̳ automotive catalysts  

E-Print Network [OSTI]

Catalyst poisoning due to sulfur compounds derived from fuel sulfur presents a major challenge, intractable thus far, to development of many advanced technologies for automotive catalysts such as the lean NOx, trap. Under ...

Tang, Hairong

2005-01-01T23:59:59.000Z

312

Monolithic Metal Oxide based Composite Nanowire Lean NOx Emission Control Catalysts  

Broader source: Energy.gov [DOE]

Presents latest progress in the development of a new type of lean NOx trapping catalyst based on heterogenous composite nanowires, which could potentially be used in gasoline and diesel engines.

313

Time and location differentiated NOX control in competitive electricity markets using cap-and-trade mechanisms  

E-Print Network [OSTI]

Due to variations in weather and atmospheric chemistry, the timing and location of nitrogen oxide (NOX) reductions determine their effectiveness in reducing ground-level ozone, which adversely impacts human health. Electric ...

Martin, Katherine C.

2007-01-01T23:59:59.000Z

314

An experimental study on combustion processes and nox emission characteristics of the air-staged burner  

Science Journals Connector (OSTI)

The combustion processes and emission characteristics in air-staged burner...5H5N) is used to investigate the fuel NOX emission characteristics. Experiments are carried out for a wide range of operating condition...

Kook-Young Ahn; Han-Seok Kim; Eun-Seong Cho; Jin-Hyuk Ahn…

1999-06-01T23:59:59.000Z

315

Combining Low-Temperature Combustion with Lean-NOx Trap Yields...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

and Posters 2005deerhuff.pdf More Documents & Publications Intra-catalyst Reductant Chemistry in Lean NOx Traps: A Study on Sulfur Effects Reductant Utilization in a LNT + SCR...

316

Intra-catalyst Reductant Chemistry in Lean NOx Traps: A Study...  

Broader source: Energy.gov (indexed) [DOE]

Intra-catalyst Reductant Chemistry in Lean NOx Traps: A Study on Sulfur Effects Jim Parks (parksjeii@ornl.gov), Matt Swartz, Shean Huff, Brian West Oak Ridge National Laboratory...

317

Oxyfuel CO2 compression: The gas phase reaction of elemental mercury and \\{NOx\\} at high pressure and absorption into nitric acid  

Science Journals Connector (OSTI)

Abstract Oxyfuel combustion is a technology which combusts coal in oxygen and recycled flue gas, producing a carbon dioxide rich flue gas for sequestration. Oxyfuel flue gas contains trace amounts of elemental mercury, which may corrode brazed aluminium heat exchangers used in the carbon dioxide purification system. International gas vendors have tested the use of the compression system to remove other flue gas impurities such as NOx; however, the reaction mechanism of mercury and its reaction products with \\{NOx\\} and nitric acid formed with condensed water vapour are unclear. This study used lab scale experiments to study the absorption of gaseous elemental mercury into nitric acid and the gas phase reaction between mercury and nitrogen dioxide formed from oxidised NO at pressures up to 25 bar. It was observed that mercury has limited absorption into nitric acid and may partially desorb out of solution after depressurisation. On the other hand, mercury reacted readily with nitrogen dioxide (formed from nitric oxide oxidation at high pressure) in the gas phase. These gas phase reactions from the oxidation of nitric oxide to nitrogen dioxide to the subsequent oxidation of elemental mercury by nitrogen dioxide were predicted using existing global kinetic equations. The limited absorption of gaseous elemental mercury in nitric acid and significant oxidation of gaseous elemental mercury by nitrogen dioxide suggests that the primary removal step for elemental mercury is through the gas phase reaction. Oxyfuel compression circuits should therefore allow sufficient residence time for this gas phase reaction to occur.

Timothy Ting; Rohan Stanger; Terry Wall

2014-01-01T23:59:59.000Z

318

METHANE de-NOX for Utility PC Boilers  

SciTech Connect (OSTI)

During the current quarter, pilot-scale testing with the modified air nozzle version of the PC burner was completed with PRB coal at the Riley Power Inc. (RPI) test facility. A total of 8 different burner configurations were tested utilizing various burner air nozzle arrangements in place of the burner air channels. It was found that with the arrangements tested, a stable flame could not be maintained at coal feed rates above 100 lb/h. While it is felt that the air nozzle approach can ultimately be used effectively, in the interest of holding to the current project schedule it was decided to proceed with the balance of the project using the air channel design. The pilot-scale PC burner was therefore restored to the air-channel configuration and benchmark testing with PRB coal to confirmed previous operating results. A series of tests was then conducted with PRB and West Virginia caking coal to evaluate modifications to the gas combustor configuration and operation for improved performance with caking coal. Continuous operation was achieved with caking coal up to 50 lb/h vs. the full load target of 150 lb/h. Impingement and deposition of partially devolatilized coal occurred at various points within the combustor when the caking coal feed was increased above 50 lb/h. The 100 MMBtu/h commercial-scale prototype design was continued with coal burner design input from both RPI and VTI. Based on typical burner installation layout considerations, it was decided that the preheat combustor should be oriented horizontally on the axial centerline of the coal burner. Accordingly, the pilot gas combustor was changed to this orientation so that the pilot results with caking coal will be directly applicable to the preferred 100 MMBtu design. Testing with caking coal in the horizontal pilot combustor achieved feed rates up to 126 lb/h, although some deposition and LOI issues remain. Several promising approaches to further improve operation with caking coal were identified. NOx results with caking coal are promising, with NOx as low as 150 ppmv at exit oxygen levels of 4% and higher. The 100 MMBtu/h commercial-scale prototype design is nearing completion. Design of the caking coal version of the unit continues with additional pilot testing in support of this design expected. GTI and RPI are expediting the fabrication of the 100 MMBtu/h PRB unit in order to start testing in early- to mid-December. Inspection and repair of the 100 MMBtu/h Coal Burner Test Facility (CBTF) is nearing completion. As of mid-September, this activity was 95% complete.

Bruce Bryan; Joseph Rabovitser; Serguei Nester; Stan Wohadlo

2003-09-30T23:59:59.000Z

319

Advanced NOx Emissions Control: Control Technology - Second Generation  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

In Situ Device for Real-Time Catalyst Deactivation Measurements in Full-Scale SCR Systems In Situ Device for Real-Time Catalyst Deactivation Measurements in Full-Scale SCR Systems To support trends in the electric generating industry of moving from seasonal to year-round operation of Selective Catalytic Reduction (SCR) for control of NOx and mercury, as well as extending the time between generating unit outages, Fossil Energy Research Corporation (FERCo) is developing technology to determine SCR catalyst activity and remaining life without requiring an outage to obtain and analyze catalyst samples. FERCo intends to use SCR catalyst performance results measured with their in situ device at Alabama PowerÂ’s Plant Gorgas during the 2005 and 2006 ozone seasons, along with EPRIÂ’s CatReactTM catalyst management software, to demonstrate the value of real-time activity measurements with respect to the optimization of catalyst replacement strategy. Southern Company and the Electric Power Research Institute are co-funding the project.

320

Release of Ammonium and Mercury from NOx Controlled Fly Ash  

SciTech Connect (OSTI)

One of the goals of the Department of Energy is to increase the reuse of coal utilization byproducts (CUB) to 50% by 2010. This will require both developing new markets and maintaining traditional ones such as the use of fly ash in concrete. However, the addition of pollution control devices can introduce side-effects that affect the marketability of the CUB. Such can be the case when NOx control is achieved using selective catalytic or non-catalytic reduction (SCR or SNCR). Depending on site-specific details, the ammonia slip can cause elevated levels of NH3 in the fly ash. Disposal of ammoniated fly ash can present environmental concerns related to the amount of ammonia that might be released, the amount of water that might become contaminated, and the extent to which metals might be mobilized by the presence of the ammonia. Ammonia retained in fly ash appears to be present as either an ammonium salt or as a chemisorbed species. Mercury in the leachates correlated to neither the amount of leachable ammonium nor to the total amount of Hg in the ash. The strongest correlation was between the decreases in the amount of Hg leached with increased LOI.

Schroeder, K.T.; Cardone, C.R.; Kim, A.G

2007-07-01T23:59:59.000Z

Note: This page contains sample records for the topic "nox carbon monoxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Carbon Dioxide Hydrate Process for Gas Separation from a Shifted Synthesis Gas Stream  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Sequestration and Sequestration and Gasification Technologies Carbon DioxiDe HyDrate ProCess for Gas seParation from a sHifteD syntHesis Gas stream Background One approach to de-carbonizing coal is to gasify it to form fuel gas consisting predominately of carbon monoxide and hydrogen. This fuel gas is sent to a shift conversion reactor where carbon monoxide reacts with steam to produce carbon dioxide (CO 2 ) and hydrogen. After scrubbing the CO 2 from the fuel, a stream of almost pure hydrogen stream remains, which can be burned in a gas turbine or used to power a fuel cell with essentially zero emissions. However, for this approach to be practical, it will require an economical means of separating CO 2 from mixed gas streams. Since viable options for sequestration or reuse of CO

322

Adsorption and methanation of carbon dioxide on a nickel/silica catalyst  

SciTech Connect (OSTI)

Temperature-programed desorption and reaction studies showed that increasing amounts of CO/sub 2/ adsorbed on silica-supported 6.9% nickel with increasing temperature to a maximum adsorption at approx. 443/sup 0/K, i.e., that the adsorption was activated; that CO/sub 2/ desorbed partly as CO/sub 2/ with the peak at 543/sup 0/K, and partly as CO with several peaks; that in the presence of hydrogen, nearly all adsorbed CO/sub 2/ desorbed as methane, and a small amount as CO; and that the methane desorption peaks from adsorbed CO and CO/sub 2/ both occurred at 473/sup 0/K. These results suggested that carbon dioxide adsorbed dissociatively as a carbon monoxide and an oxygen species. An observed absence of higher hydrocarbons in the methanation products of carbon dioxide was attributed to a high hydrogen/carbon monoxide surface ratio caused by the activated carbon dioxide adsorption.

Falconer, J.L.; Zagli, A.E.

1980-04-01T23:59:59.000Z

323

Titanium monoxide spectroscopy following laser-induced optical breakdown  

SciTech Connect (OSTI)

This work investigates Titanium Monoxide (TiO) in ablation-plasma by employing laser-induced breakdown spectroscopy (LIBS) with 1 to 10 TW/cm{sup 2} irradiance, pulsed, 13 nanosecond, Q-switched Nd:YAG laser radiation at the fundamental wavelength of 1064 nm. The analysis of TiO is based on our first accurate determination of transition line strengths for selected TiO A-X, B-X, and E-X transitions, particularly TiO A-X {gamma} and B-X {gamma} Prime bands. Electric dipole line strengths for the A{sup 3}{Phi}-X{sup 3}{delta} and B{sup 3}{Pi}-X{sup 3}{delta} bands of TiO are computed. The molecular TiO spectra are observed subsequent to laser-induced breakdown (LIB). We discuss analysis of diatomic molecular spectra that may occur simultaneously with spectra originating from atomic species. Gated detection is applied to investigate the development in time of the emission spectra following LIB. Collected emission spectra allow one to infer micro-plasma parameters such as temperature and electron density. Insight into the state of the micro-plasma is gained by comparing measurements with predictions of atomic and molecular spectra. Nonlinear fitting of recorded and computed diatomic spectra provides the basis for molecular diagnostics, while atomic species may overlap and are simultaneously identified. Molecular diagnostic approaches similar to TiO have been performed for diatomic molecules such as AlO, C{sub 2}, CN, CH, N{sub 2}, NH, NO and OH.

Parigger, Christian G.; Woods, Alexander C.; Keszler, Anna; Nemes, Laszlo; Hornkohl, James O. [The University of Tennessee/UT Space Institute, Center for Laser Applications, 411 B.H. Goethert Parkway, Tullahoma, TN 37388-9700 (United States); Chemical Research Center of the Hungarian Academy of Sciences, Institute of Materials and Environmental Chemistry, Pusztaszeri ut 59-67, H-1025 Budapest (Hungary); Chemical Research Center of the Hungarian Academy of Sciences, Laser Spectroscopy Laboratory, Pusztaszeri ut 59-67, H-1025 Budapest (Hungary); Hornkohl Consulting, Tullahoma, TN 37388 (United States)

2012-07-30T23:59:59.000Z

324

Synthesis of higher alcohols from carbon monoxide and hydrogen in a slurry reactor  

SciTech Connect (OSTI)

Higher, i.e. C{sub 2{sup +}}, alcohols are desired as gasoline additives, feedstocks for producing ethers and as alternative fuels for automobiles. In all cases, the backbone branching of an alcohol improves octane rating, which is essential for good engine performance. These types of branched, higher alcohols are the desired products for a process converting synthesis gas, a CO and H{sub 2} mixture, often generated from coal gasification. Based on this premise, promoted ZnCr oxide catalysts appear to be as one of the best avenues for further investigation. Once this investigation is complete, a natural extension is to replace the Cr in the ZnCr oxide catalyst with Mo and W, both in the same elemental triad with Cr. Mo has already been shown as an active HAS catalyst, both on a SiO{sub 2} support and in the MoS{sub 2} form. The three catalyst combinations, ZnMo, ZnW, and MnCr oxides will be tested in the stirred autoclave system. However, if none of the three indicate any comparable activity and/or selectivity toward higher alcohols as compared with other HAS catalysts, then an investigation of the effects of Cs promotion on the ZnCr oxide methanol catalysts will be executed.

McCutchen, M.S.

1992-08-28T23:59:59.000Z

325

A Novel Carbon Monoxide-Releasing Molecule Fully Protects Mice from Severe Malaria  

Science Journals Connector (OSTI)

...exudate, and elevated VEGF levels in plasma, followed by death between days 7 and...b) Levels of VEGF protein in the plasma of P. berghei ANKA-infected DBA-2...adequate cautions. Published ahead of print 12 December 2011 Supplemental material...

Ana C. Pena; Nuno Penacho; Liliana Mancio-Silva; Rita Neres; João D. Seixas; Afonso C. Fernandes; Carlos C. Romão; Maria M. Mota; Gonçalo J. L. Bernardes; Ana Pamplona

2011-12-12T23:59:59.000Z

326

A Novel Carbon Monoxide-Releasing Molecule Fully Protects Mice from Severe Malaria  

Science Journals Connector (OSTI)

...temperature under a nitrogen atmosphere. The solution was concentrated...C O) cm deltaH (400 MHz, D2O) 2.23 (3H...an inductively coupled plasma-atomic emission spectrometer...growth factor (VEGF) in plasma samples was determined...elevated VEGF levels in plasma, followed by death between...

Ana C. Pena; Nuno Penacho; Liliana Mancio-Silva; Rita Neres; João D. Seixas; Afonso C. Fernandes; Carlos C. Romão; Maria M. Mota; Gonçalo J. L. Bernardes; Ana Pamplona

2011-12-12T23:59:59.000Z

327

Measuring the Kinetics of the Reduction of Iron Oxide with Carbon Monoxide in a Fluidized Bed  

Science Journals Connector (OSTI)

Combusting a solid fuel in the presence of a metal oxide rather than air, chemical looping combustion, generates CO2suitable for sequestration and the reduced metal. For the case of iron, the reduced oxide can be...

C. D. Bohnt; J. P. Cleeton; C. M. Miiller…

2010-01-01T23:59:59.000Z

328

Detection of carbon monoxide (CO) as a furnace byproduct using a rotating mask spectrometer.  

SciTech Connect (OSTI)

Sandia National Laboratories, in partnership with the Consumer Product Safety Commission (CPSC), has developed an optical-based sensor for the detection of CO in appliances such as residential furnaces. The device is correlation radiometer based on detection of the difference signal between the transmission spectrum of the sample multiplied by two alternating synthetic spectra (called Eigen spectra). These Eigen spectra are derived from a priori knowledge of the interferents present in the exhaust stream. They may be determined empirically for simple spectra, or using a singular value decomposition algorithm for more complex spectra. Data is presented on the details of the design of the instrument and Eigen spectra along with results from detection of CO in background N{sub 2}, and CO in N{sub 2} with large quantities of interferent CO{sub 2}. Results indicate that using the Eigen spectra technique, CO can be measured at levels well below acceptable limits in the presence of strongly interfering species. In addition, a conceptual design is presented for reducing the complexity and cost of the instrument to a level compatible with consumer products.

Sinclair, Michael B.; Flemming, Jeb Hunter; Blair, Raymond (Honeywell Federal Manufacturing & Technologies, Albuqueruque, NM); Pfeifer, Kent Bryant

2006-02-01T23:59:59.000Z

329

Test results of a ceramic-based carbon monoxide sensor in the automotive exhaust manifold  

SciTech Connect (OSTI)

A prototype CO sensor based on the anatase phase of TiO{sub 2} was fabricated and tested in a Ford V6 engine. Fuel combustion was programmed to be near stoichiometric conditions, and emissions were monitored with an FT-IR analytical instrument. The sensor, positioned near the oxygen sensor in the exhaust manifold, was successfully tested for 50 cycles of revving and idling, and was observed to respond quickly and reproducibly. The sensor response was correlated to the CO concentration at specific engine temperatures and was found to vary systematically with increasing concentrations. The results are promising and the sensor shows potentials to monitor the efficiency of the catalytic converter.

Azad, A.M.; Younkman, L.B.; Akbar, S.A. [Ohio State Univ., Columbus, OH (United States)

1996-12-31T23:59:59.000Z

330

Sensing mechanism of a carbon monoxide sensor based on anatase titania  

SciTech Connect (OSTI)

This paper reports results on a TiO{sub 2} (anatase)-based CO sensor and proposes a possible surface-controlled sensing mechanism. The complex plane analysis of the ac electrical data provides quantitative evidence supporting the mechanism. The grain-boundary capacitance and conductance, extracted from the impedance plane, were observed to increase with the CO concentration. This effect is attributed to a change in the depletion region thickness and barrier height at the TiO{sub 2} intergranular contact. The analysis of the electrical data combined with x-ray diffraction and x-ray photoelectron spectroscopy observations support the proposed sensing mechanism involving CO adsorption and ionization on the titania surface, and not an oxidation-reduction type reaction as observed in most oxide-based sensors.

Akbar, S.A.; Younkman, L.B. [Ohio State Univ., Columbus, OH (United States). Dept. of Materials Science and Engineering

1997-05-01T23:59:59.000Z

331

Adsorption effects during temperature-programmed desorption of carbon monoxide from supported platinum  

SciTech Connect (OSTI)

To investigate the effects of CO adsorption, we develop a mathematical model and use it to compute desorption spectra for the TPD of CO from Pt dispersed over a porous support into (a) an inert carrier gas and (b) a vacuum. Over the realistic parameter range considered, our model predicts that adsorption effects, caused by high concentrations of gaseous CO in the system, are always an important feature, broadening the desorption peaks and shifting them to higher temperatures. Indeed, we find that adsorption competes with desorption to the extent that adsorption equilibrium is always approached closely within the porous supported Pt samples. For desorption into a carrier gas, the adsorption effects result from limitations to the flow of CO from the sample cell, whereas for desorption into a vacuum, the adsorption effects result from limitations to the diffusion of CO from the porous sample. Our results suggest that significant adsorption effects will also be present during the TPD of CO from other Group VIII precious metals dispersed over porous supports. 4 figures, 2 tables.

Herz, R.K.; Kiela, J.B.; Marin, S.P.

1982-01-01T23:59:59.000Z

332

Some general laws of the hydrogenation of carbon monoxide on metals  

SciTech Connect (OSTI)

The catalytic properties of supported transition metals in the hydrogenation of CO to hydrocarbons have been studied. A kinetic model interpreting the unusual dependence of the activation energy on temperature is proposed. It is shown that the catalytic activity (r) decreases and the selectivity with respect to methane (SCH/sub 4/) increases with an increase in the heat of adsorption of CO.

Golodets, G.I.; Pavlenko, N.V.; Tripol'skii, A.I.

1988-01-01T23:59:59.000Z

333

Kinetic study of the reaction between nitric oxide and carbon monoxide catalyzed by clean polycrystalline platinum  

SciTech Connect (OSTI)

The kinetics of the platinum catalyzed reaction between NO and CO has been studied under conditions chosen to approximate those observed during operation of catalysts in automotive exhaust gas treatment applications. The catalysts were polycrystalline platinum foils and wires. The reaction was studied over a range of reactant partial pressures of 10 V Torr to 1 Torr and catalyst temperatures of 500 to 1500K. The steady-state kinetics results could not be fit by a simple Langmuir-Hinshelwood kinetic model over all experimental conditions studied. The kinetics at high coverage were most consistent with Langmuir-Hinshelwood kinetics assuming a bimolecular reaction between NO and CO as the rate-limiting step. At high temperature, the Langmuir-Hinshelwood assumption of fast adsorption-desorption equilibrium relative to the surface reaction rate was no longer appropriate and the mechanism of adsorption of NO had to be considered explicitly.

Klein, R.L.

1984-01-01T23:59:59.000Z

334

Dissociation and oxidation of carbon monoxide over Rh/Al sub 2 O sub 3 catalysts  

SciTech Connect (OSTI)

The activity of Rh/Al{sub 2}O{sub 3} catalysts for CO oxidation was investigated by transient isotopic pulse experiments using packed-bed reactor. This transient experimental scheme revealed significant CO dissociation activity during CO oxidation over Rh/Al{sub 2}O{sub 3} catalysts. Results indicate that the oxidation of CO proceeds via dissociative oxidation by its own oxygen as well as via direct oxidation by gas-phase oxygen on well-dispersed Rh/Al{sub 2}O{sub 3} catalysts. The rate of CO dissociation is on the same order of magnitude as the rate of CO oxidation; under steady-state conditions at 300{degree}C, the rate of CO dissociation is approximately half that of direct oxidation. Differences in CO dissociation activity between single-crystal Rh surfaces and well-dispersed supported Rh particles are explained in terms of the molecular bonding and adsorption characteristics on these two different surfaces. The importance of CO dissociation kinetics in the overall CO oxidation activity of Rh/Al{sub 2}O{sub 3} catalysts is further discussed in view of the reaction lightoff behavior.

Cho, Byong K.; Stock, C.J. (General Motors Research Labs., Warren, MI (USA))

1989-05-01T23:59:59.000Z

335

Adsorption of carbon monoxide on ZSM-5 zeolites. Infrared spectroscopic study and quantum-chemical calculations  

SciTech Connect (OSTI)

Low temperature adsorption of CO was studied on H-ZSM-5 zeolites modified by dehydroxylation, ionic exchange with Al/sup 3 +/, and impregnation with Al/sub 2/O/sub 3/ and on Na-ZSM-5 and CaH-ZSM-5 zeolites. It was found that interaction of CO with framework OH groups results in the formation of a hydrogen-bonded CO complex whose OH bond frequency is decreased by 310-320 cm/sup -1/ compared with that of free hydroxyls. For the less acidic framework hydroxyls in large cavities of H/sub 70/Na/sub 30/-Y zeolite the observed shift is 275 cm/sup -1/. With ZSM-5 zeolites, at least six types of electron-accepting sites are observed originating from nonframework Al species (band of CO in the interaction complex: 2132, 2222, 2202, 2195, and 2198 cm/sup -1/) and the Al/sub 2/O/sub 3/ microcrystalline phase (CO band at 2153 cm/sup -1/). The CO bond orders calculated by the CNDO/2 method for the CO interaction complexes with models of surface sites increase in the following order: > O-CO < > OH-CO approx. ..-->.. Al-CO approx. = Na-CO < alumina-CO approx. = Ca-CO < ..-->.. Si-CO < Al(cationic)-CO. A correlation between the calculated bond orders of CO and the observed vibrational frequencies of CO-forming interaction complexes is drawn.

Kustov, L.M.; Kazansky, V.B.; Beran, S.; Kubelkova, L.; Jiru, P.

1987-09-24T23:59:59.000Z

336

Sulfur adsorption on nickel(100) and its effect on carbon monoxide, nitric oxide, and deuterium chemisorption  

SciTech Connect (OSTI)

The adsorption of CO, NO, and D/sub 2/ was studied on clean and sulfided Ni(100) near 100K using Auger electron spectroscopy, thermal desorption spectroscopy, X-ray and ultraviolet photoelectron spectroscopies, and work function change measurements. The evidence suggests that sulfur's effects are predominantly steric in nature. Weak, short-range (approx.4 angstrom) electrostatic effects are also present, due to charge transfer of about 0.04 of an electron from nickel to sulfur. The blocking effect of S on the adsorption of each gas at various temperatures is discussed.

Hardegree, E.L.

1985-01-01T23:59:59.000Z

337

Free-radical reactions in glow and explosion of carbon monoxide-oxygen mixtures  

SciTech Connect (OSTI)

Examination of published compilations of rate coefficients of free-radical reactions yields reactions that are associated with chain branching in mixtures of CO and O/sub 2/ and small quantities of hydrogen or water vapor. The complete mechanism included diffusion of HO/sub 2/ radicals to the vessel wall and their adsorption and reaction at the surface. This mechanism is applied to the data of E.J. Buckler and R.G.W. Norrish on the branched-chain explosion of CO-O/sub 2/ mixtures containing H/sub 2/ in the order of 1 mm Hg. Substantial agreement is found between theory and experiment. Further, the mechanism is applied to experiments of Bond, Gray, and Griffiths with an H/sub 2/ content of 0.01-0.05 mm Hg. By specifying details of the adsorption and surface reaction of HO/sub 2/ on the basis of Langmuir's adsorption the phenomenon of flow is explained and the regions of slow reaction, glow, and explosion are described in accord with the experimental data. It is confirmed that the reaction between CO and O/sub 2/ requires the presence of a hydrogenous compound such as H/sub 2/, H/sub 2/O, CH/sub 4/, etc., and that ''dry'' homogenous reaction is not possible except at very high temperatures.

Von Elbe, G.; Lewis, B.

1986-02-01T23:59:59.000Z

338

Homologation and functionalization of carbon monoxide by a recyclable uranium complex  

Science Journals Connector (OSTI)

...C-5b (R = Ph) were confirmed by CHN combustion analyses, FTIR spectroscopy, and the...SiOCCOSiPh 3 , and 4 to estimate the heats of formation ({delta}H for ) for...resource from which to produce industrial hydrocarbon feedstocks as alternatives to crude oil...

Benedict M. Gardner; John C. Stewart; Adrienne L. Davis; Jonathan McMaster; William Lewis; Alexander J. Blake; Stephen T. Liddle

2012-01-01T23:59:59.000Z

339

Impacts of 2006 Indonesian fires and dynamics on tropical upper tropospheric carbon monoxide and ozone  

E-Print Network [OSTI]

reproduce seasonal mean lightning flash rates to match theobser- vations of lightning flashes from the Optical

2011-01-01T23:59:59.000Z

340

Hydrocarbons from carbon monoxide hydrogen-steam mixtures, unusual product distributions and mechanistic implications  

SciTech Connect (OSTI)

Over recent years, considerable interest has developed in hydrocarbon synthesis via direct processing of H/sub 2/-lean synthesis gases which are produced by the ''second generation'' of thermally efficient coal gasifiers. To directly process gases with a H/sub 2//CO ratio less than 0.5, requires that water be mixed with the reactor feed gas so that additional H/sub 2/ is generated in-situ via the water-gas-shift (WGS) reaction. This obviously requires the use of catalysts which are active for both the synthesis and WGS reactions. The fact that most Group VIII metals are active for both reactions is well demonstrated by the development of the Kolbel-Engelhardt (KE) synthesis in which all the H/sub 2/ is formed in-situ. The authors previously examined the effect of H/sub 2//CO/H/sub 2/2O feed ratios on CO conversion rates (4); the present report concerns its effect upon hydrocarbon product distributions. In the experiments described, as the H/sub 2//CO ratio was reduced from 2.0 (Typical Fischer-Tropsch (FT) conditions), sufficient H/sub 2/O was added to compensate for the H/sub 2/ deficiency based on the assumption that all added H/sub 2/O was converted to H/sub 2/ via the WGS reaction.

Chaffee, A.L.; Ekstrom; Lapszewica, J.; Loeh, H.

1986-03-01T23:59:59.000Z

Note: This page contains sample records for the topic "nox carbon monoxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Multimodel simulations of carbon monoxide: Comparison with observations and projected near-future changes  

E-Print Network [OSTI]

development of a gridded climatology for tropospheric ozone,et al. , 2000] O 3 climatology based on satellite and sondeO 3 nudged toward climatology above 380 K zonal mean O 3

2006-01-01T23:59:59.000Z

342

Nitric oxide and carbon monoxide in cigarette smoke in the development of cardiorespiratory disease in smokers  

E-Print Network [OSTI]

(Rep 1983). This could be due to indoor air pollution but respiratory disease in childhood may affect later respiratory function ( Burrows, Knudson and Lebvitz 1977). Similarly the decline in bronchitis mortality i n the U.K . in re c ent years which... anteceded the decline in cigarette cons umption might, in addition, suggest an effect of outdoor pollution Air Acts". The marked internat ional differences in mortality and the high figures for the British I sles...

Borland, Colin David Ross

1988-10-18T23:59:59.000Z

343

TEXIN2: a model for predicting carbon monoxide concentrations near intersections  

E-Print Network [OSTI]

of the Journal of the Air Pollution Control Association emitted along straight roadways, where traffic is wel 1-def ined and flows uniformly at constant speeds. This scenario is extremely inap- propriate for intersections. A simple conversion from straight... are presented in Chapter V. CHAPTER II LITERATURE REVIEW The task of modeling pollutant concentrations near intersections has traditionally been approached by first enlisting an emissions model to estimate a composite emission rate for vehicular traffic...

Korpics, J. J

1985-01-01T23:59:59.000Z

344

REFORMULATION OF COAL-DERIVED TRANSPORTATION FUELS: SELECTIVE OXIDATION OF CARBON MONOXIDE ON METAL FOAM CATALYSTS  

SciTech Connect (OSTI)

Hydrocarbon fuels must be reformed in a series of steps to provide hydrogen for use in proton exchange membrane fuel cells (PEMFCs). Preferential oxidation (PROX) is one method to reduce the CO concentration to less than 10 ppm in the presence of {approx}40% H{sub 2}, CO{sub 2}, and steam. This will prevent CO poisoning of the PEMFC anode. Structured supports, such as ceramic monoliths, can be used for the PROX reaction. Alternatively, metal foams offer a number of advantages over the traditional ceramic monolith.

Paul Chin; Xiaolei Sun; George W. Roberts; Amornmart Sirijarhuphan; Sourabh Pansare; James G. Goodwin Jr; Richard W. Rice; James J. Spivey

2005-06-01T23:59:59.000Z

345

Influence of solid fuel on the carbon-monoxide and nitrogen-oxide emissions on sintering  

SciTech Connect (OSTI)

Laboratory and industrial research now underway at the sintering plant of AO Mittal Steel Temirtau is focusing on the preparation of fuel of optimal granulometric composition, the replacement of coke fines, and the adaptation of fuel-input technology so as to reduce fuel consumption and toxic emissions without loss of sinter quality.

M.F. Vitushchenko; N.L. Tatarkin; A.I. Kuznetsov; A.E. Vilkov [AO Mittal Steel Temirtau, Temirtau (Kazakhstan)

2007-07-01T23:59:59.000Z

346

Electroreduction of carbon monoxide to liquid fuel on oxide-derived nanocrystalline copper  

Science Journals Connector (OSTI)

... were used without further purification. Electrolyte solutions were prepared with deionized water (Ricca Chemical, ASTM Type I). Preparation of oxide-derived Cu 1

Christina W. Li; Jim Ciston; Matthew W. Kanan

2014-04-09T23:59:59.000Z

347

Isotope effect in the formation of carbon monoxide by radiative association  

Science Journals Connector (OSTI)

......levels of the final electronic state. 3 COMPUTATIONAL...parameters needed for calculation of according to...through reaction (2) does not vary much at...1sigma+ transition does not go above 2...curve of the A 1pi electronic state leads to the...M. Mathematical Handbook for Scientists and......

Sergey V. Antipov; Magnus Gustafsson; Gunnar Nyman

2013-01-01T23:59:59.000Z

348

Carbon Monoxide Dehydrogenases and Acetyl-CoA Synthases: Light at the End of the Tunnel?  

SciTech Connect (OSTI)

OAK-B135 Metalloenzymes seem to ''come of age'' when their structures are known at atomic resolution, spectroscopic and catalytic properties are basically understood, and genetic expression systems are available. Such foundations allow detailed mechanistic and spectroscopic properties to be probed and correlated to structure. The objective of this article is to summarize what is known about the title group of enzymes, and show that, to a large degree, they have come of age.

Paul A. Lindahl

2002-02-19T23:59:59.000Z

349

Oxygen isotope fractionation in the vacuum ultraviolet photodissociation of carbon monoxide: Wavelength, pressure and temperature dependency.  

E-Print Network [OSTI]

Oxygen isotope fractionation in the vacuum ultravioletmeasurement of the associated oxygen isotopic composition ofwavelength dependency of the oxygen isotopic composition in

Chakraborty, Subrata

2013-01-01T23:59:59.000Z

350

Carbon Monoxide Pollution Promotes Cardiac Remodeling and Ventricular Arrhythmia in Healthy Rats  

E-Print Network [OSTI]

worldwide by outdoor air pollution caused by vehicles and industrial emissions (http://www.who.int; http:// www.infoforhealth.org). Notably, air pollution increases the risk of mortality from cardiovascular investigating the effects of urban air pollution in humans are mainly restricted to epide- miological studies

Boyer, Edmond

351

REFORMULATION OF COAL-DERIVED TRANSPORTATION FUELS: SELECTIVE OXIDATION OF CARBON MONOXIDE ON METAL FOAM CATALYSTS  

SciTech Connect (OSTI)

Uses for structured catalytic supports, such as ceramic straight-channel monoliths and ceramic foams, have been established for a long time. One of the most prominent examples is the washcoated ceramic monolith as a three-way catalytic converter for gasoline-powered automobiles. A distinct alternative to the ceramic monolith is the metal foam, with potential use in fuel cell-powered automobiles. The metal foams are characterized by their pores per inch (ppi) and density ({rho}). In previous research, using 5 wt% platinum (Pt) and 0.5 wt% iron (Fe) catalysts, washcoated metal foams, 5.08 cm in length and 2.54 cm in diameter, of both varying and similar ppi and {rho} were tested for their activity (X{sub CO}) and selectivity (S{sub CO}) on a CO preferential oxidation (PROX) reaction in the presence of a H{sub 2}-rich gas stream. The variances in these metal foams' activity and selectivity were much larger than expected. Other structured supports with 5 wt% Pt, 0-1 wt% Fe weight loading were also examined. A theory for this phenomenon states that even though these structured supports have a similar nominal catalyst weight loading, only a certain percentage of the Pt/Fe catalyst is exposed on the surface as an active site for CO adsorption. We will use two techniques, pulse chemisorption and temperature programmed desorption (TPD), to characterize our structured supports. Active metal count, metal dispersion, and other calculations will help clarify the causes for the activity and selectivity variations between the supports. Results on ceramic monoliths show that a higher Fe loading yields a lower dispersion, potentially because of Fe inhibition of the Pt surface for CO adsorption. This theory is used to explain the reason for activity and selectivity differences for varying ppi and {rho} metal foams; less active and selective metal foams have a lower Fe loading, which justifies their higher metal dispersion. Data on the CO desorption temperature and average metal crystallite size for TPD are also collected.

Paul Chin; George W. Roberts; James J. Spivey

2003-12-31T23:59:59.000Z

352

INFRARED ABSORPTION SPECTROSCOPY OF CARBON MONOXIDE ON NICKEL FILMS: A LOW TEMPERATURE THERMAL DETECTION TECHNIQUE  

E-Print Network [OSTI]

excess noise from the thermometer element and the digitizingXBL 78/2-6334 Fig. 14. Noise spectra of sample thermometer.noise spectrum of the thermometer signal for two different

Bailey, Robert Brian

2011-01-01T23:59:59.000Z

353

Understanding the Distributed Intra-Catalyst Impact of Sulfation on Water Gas Shift in a Lean NOx Trap Catalyst  

Broader source: Energy.gov [DOE]

The Lean NOx Trap catalyst is an aftertreatment technology for abatement of nitrogen-oxide emissions from lean-burn vehicle engines.

354

Pilot-Scale Aftertreatment Using Nonthermal Plasma Reduction of Adsorbed NOx in Marine Diesel-Engine Exhaust Gas  

Science Journals Connector (OSTI)

Regulations governing marine diesel engine NOx emissions have recently become more stringent. As it is difficult to fulfill these requirements by combustion improvements alone, effective aftertreatment technologi...

Takuya Kuwahara; Keiichiro Yoshida…

2014-01-01T23:59:59.000Z

355

High pressure conversion of \\{NOx\\} and Hg and their capture as aqueous condensates in a laboratory piston-compressor simulating oxy-fuel CO2 compression  

Science Journals Connector (OSTI)

Abstract Oxy-fuel technology for CO2 capture has largely focused on combustion characteristics as a driver towards demonstration. Impurity removal studies typically centre on the how current environmental control units (FGD, SCR, activated carbon beds) operate in oxy-fuel firing. However, it is expected that some removal of \\{NOx\\} and \\{SOx\\} may occur during compression of flue gas through the lead chamber process. Some commercial systems link the capture of mercury to the formation of acid condensates (as a soluble mercury salt). Mercury in compressed flue gas represents a potential corrosion risk in the processing of CO2 from oxy-fuel combustion processes. Gas phase elemental mercury (Hg0) is difficult to remove from the flue gas and the level of cleaning required to prevent corrosion of cryogenic brazed aluminium heat exchangers is uncertain. This work has investigated the behaviour of gaseous Hg0 in pressurised oxy-fuel systems in terms of the potential capture in acidic condensates, interaction with \\{NOx\\} gases and liquid stability on de-pressurisation. The work was undertaken on an adapted laboratory scale three stage axial-piston compressor with gas and liquid sampling at pressures up to 30 bar. The main finding was that gaseous Hg0 reacts readily with NO2 formed from NO oxidation at high pressure. This reaction occurred without the presence of water, either water vapour or liquid water, contrary to speculation in the literature. Without NO2, no capture of Hg0 was observed in the compression system. Overall, the capture of mercury during compression occurred as a consequence of high pressure, longer residence time and concentration of NO2. Capture rates of 100% Hg and 75–83% \\{NOx\\} were measured from the compressor exit at 30 bar g.

Rohan Stanger; Timothy Ting; Terry Wall

2014-01-01T23:59:59.000Z

356

METHANE de-NOX for Utility PC Boilers  

SciTech Connect (OSTI)

The overall project objective is the development and validation of an innovative combustion system, based on a novel coal preheating concept prior to combustion, that can reduce NO{sub x} emissions to 0.15 lb/million Btu or less on utility pulverized coal (PC) boilers. This NO{sub x} reduction should be achieved without loss of boiler efficiency or operating stability, and at more than 25% lower levelized cost than state-of-the-art SCR technology. A further objective is to ready technology for full-scale commercial deployment to meet the market demand for NO{sub x} reduction technologies. Over half of the electric power generated in the U.S. is produced by coal combustion, and more than 80% of these units utilize PC combustion technology. Conventional measures for NOx reduction in PC combustion processes rely on combustion and post-combustion modifications. A variety of combustion-based NO{sub x} reduction technologies are in use today, including low-NO{sub x} burners (LNBs), flue gas recirculation (FGR), air staging, and natural gas or other fuel reburning. Selective non-catalytic reduction (SNCR) and selective catalytic reduction (SCR) are post-combustion techniques. NO{sub x} reduction effectiveness from these technologies ranges from 30 to 60% and up to 90-93% for SCR. Typically, older wall-fired PC burner units produce NO{sub x} emissions in the range of 0.8-1.6 lb/million Btu. Low-NO{sub x} burner systems, using combinations of fuel staging within the burner and air staging by introduction of overfire air in the boiler, can reduce NO{sub x} emissions by 50-60%. This approach alone is not sufficient to meet the desired 0.15 lb/million Btu NO{sub x} standard with a range of coals and boiler loads. Furthermore, the heavy reliance on overfire air can lead to increased slagging and corrosion in furnaces, particularly with higher-sulfur coals, when LNBs are operated at sub-stoichiometric conditions to reduce fuel-derived NOx in the flame. Therefore, it is desirable to minimize the need for overfire air by maximizing NO{sub x} reduction in the burner. The proposed combustion concept aims to greatly reduce NO{sub x} emissions by incorporating a novel modification to conventional or low-NO{sub x} PC burners using gas-fired coal preheating to destroy NO{sub x} precursors and prevent NO{sub x} formation. A concentrated PC stream enters the burner, where flue gas from natural gas combustion is used to heat the PC up to about 1500 F prior to coal combustion. Secondary fuel consumption for preheating is estimated to be 3 to 5% of the boiler heat input. This thermal pretreatment releases coal volatiles, including fuel-bound nitrogen compounds into oxygen-deficient atmosphere, which converts the coal-derived nitrogen compounds to molecular N{sub 2} rather than NO. Design, installation, shakedown, and testing on Powder River Basin (PRB) coal at a 3-million Btu/h pilot system at RPI's (Riley Power, Inc.) pilot-scale combustion facility (PSCF) in Worcester, MA demonstrated that the PC PREHEAT process has a significant effect on final O{sub x} formation in the coal burner. Modifications to both the pilot system gas-fired combustor and the PC burner led to NO{sub x} reduction with PRB coal to levels below 0.15 lb/million Btu with CO in the range of 35-112 ppmv without any furnace air staging.

Bruce Bryan; Serguei Nester; Joseph Rabovitser; Stan Wohadlo

2005-09-30T23:59:59.000Z

357

NOx Control Options and Integration for US Coal Fired Boilers  

SciTech Connect (OSTI)

This is the sixteenth Quarterly Technical Report for DOE Cooperative Agreement No: DEFC26-00NT40753. The goal of the project is to develop cost effective analysis tools and techniques for demonstrating and evaluating low NOx control strategies and their possible impact on boiler performance for boilers firing US coals. The Electric Power Research Institute (EPRI) is providing co-funding for this program. During an unplanned outage, damage occurred to the electrochemical noise corrosion probes installed at the AEP Gavin plant; testing is expected to resume in August. The KEMCOP corrosion coupons were not affected by the unplanned outage; the coupons were removed and sent for analysis. BYU conducted a series of tests before the ISSR lab was relocated. Ammonia adsorption experiments provided clear evidence of the types of acidic sites present on catalyst surfaces. Data collected this quarter indicate that surface sulfation decreases Lewis acid site concentrations for all catalysts thus far studied, confirming that catalytic activity under commercial coal-based SCR conditions occurs primarily on Br{o}nsted acid sites and would be susceptible to basic impurities such as alkali and alkaline earth oxides, chlorides, and sulfates. SCR activity tests based on MS analysis showed that increasing sulfation generally increases NO reduction activity for both 0% and 1% vanadia catalysts. During this quarter, the slipstream reactor at Rockport operated for 720 hours on flue gas. Catalyst exposure time reached 4500 hours since installation. The reactor is out of service at the Rockport plant and plans are being made to move it to the Gadsden Plant. At Gadsden, modifications have begun in preparation for installation of the slipstream reactor next quarter.

Mike Bockelie; Kevin Davis; Temi Linjewile; Connie Senior; Eric Eddings; Kevin Whitty; Larry Baxter; Calvin Bartholomew; William Hecker; Stan Harding

2004-06-30T23:59:59.000Z

358

Reaction of titanium polonides with carbon dioxide  

SciTech Connect (OSTI)

It has been ascertained that heating titanium and tantalum in carbon dioxide to temperatures of 500 or 800/sup 0/C alters the composition of the gas phase, causing the advent of carbon monoxide and lowering the oxygen content. Investigation of the thermal stability of titanium polonides in a carbon dioxide medium has shown that titanium mono- and hemipolonides are decomposed at temperatures below 350/sup 0/C. The temperature dependence of the vapor pressure of polonium produced in the decomposition of these polonides in a carbon dioxide medium have been determined by a radiotensimetric method. The enthalpy of the process, calculated from this relationship, is close to the enthalpy of vaporization of elementary polonium in vacuo.

Abakumov, A.S.; Malyshev, M.L.; Reznikova, N.F.

1987-05-01T23:59:59.000Z

359

Flow reactor experiments on the selective non-catalytic removal of nitrogen oxides  

E-Print Network [OSTI]

?CO, and H, O are initially present in exhaust stream [57]. .. . . . 42 Fig. 21 Fig. 22 Reaction path diagram for RAPRENOx process [63]. .. . Reduction of nitric oxide as a function of temperature, concentration of oxygen, carbon monoxide, and water... the influence of carbon monoxide [89]. . . . . . . . . 58 Fig. 28 Effect of residence time on the NOxOUT process as a function of temperature, NO(initial)=125ppm, 0-ratio of 4 [90]. .. . . . . . . . . . . . . . . 60 Fig. 29 Ammonia slip as a function...

Gentemann, Alexander M.G.

2001-01-01T23:59:59.000Z

360

Turbulent Flame Speeds and NOx Kinetics of HHC Fuels with Contaminants and High Dilution Levels  

SciTech Connect (OSTI)

This final report documents the technical results of the 3-year project entitled, “Turbulent Flame Speeds and NOx Kinetics of HHC Fuels with Contaminants and High Dilution Levels,” funded under the NETL of DOE. The research was conducted under six main tasks: 1) program management and planning; 2) turbulent flame speed measurements of syngas mixtures; 3) laminar flame speed measurements with diluents; 4) NOx mechanism validation experiments; 5) fundamental NOx kinetics; and 6) the effect of impurities on NOx kinetics. Experiments were performed using primary constant-volume vessels for laminar and turbulent flame speeds and shock tubes for ignition delay times and species concentrations. In addition to the existing shock- tube and flame speed facilities, a new capability in measuring turbulent flame speeds was developed under this grant. Other highlights include an improved NOx kinetics mechanism; a database on syngas blends for real fuel mixtures with and without impurities; an improved hydrogen sulfide mechanism; an improved ammonia kintics mechanism; laminar flame speed data at high pressures with water addition; and the development of an inexpensive absorption spectroscopy diagnostic for shock-tube measurements of OH time histories. The Project Results for this work can be divided into 13 major sections, which form the basis of this report. These 13 topics are divided into the five areas: 1) laminar flame speeds; 2) Nitrogen Oxide and Ammonia chemical kinetics; 3) syngas impurities chemical kinetics; 4) turbulent flame speeds; and 5) OH absorption measurements for chemical kinetics.

Peterson, Eric; Krejci, Michael; Mathieu, Olivier; Vissotski, Andrew; Ravi, Sankat; Plichta, Drew; Sikes, Travis; Levacque, Anthony; Camou, Alejandro; Aul, Christopher

2013-09-30T23:59:59.000Z

Note: This page contains sample records for the topic "nox carbon monoxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Coal characterisation for \\{NOx\\} prediction in air-staged combustion of pulverised coals  

Science Journals Connector (OSTI)

A series of world-traded coal samples has been tested using the Imperial College high temperature wire mesh apparatus (HTWM) in order to assess the relationship between high temperature (1600°C) char nitrogen content and \\{NOx\\} formation in Hemweg Power Station (in the Netherlands) using deep furnace air staging. A linear relationship between high temperature char nitrogen and \\{NOx\\} formation has been confirmed. These results suggest that high temperature char N content is the main factor limiting \\{NOx\\} emissions with deep air-staged combustion. Char N and (hence apparently deep air-staged NOx) can be predicted with an accuracy of approximately ±20% for most coals from the coal proximate and ultimate analysis—but this might not be sufficient for stations operating close to their emission limits. Measuring high temperature char N directly reduces the likely uncertainty in deep air-staged \\{NOx\\} emissions for coals (and most blends) to approximately ±10%. Its use should be considered on a routine basis for coal selection on plants employing this technology.

C.K. Man; J.R. Gibbins; J.G. Witkamp; J. Zhang

2005-01-01T23:59:59.000Z

362

carbon footprinting | OpenEI  

Open Energy Info (EERE)

footprinting footprinting Dataset Summary Description Emissions from energy use in buildings are usually estimated on an annual basis using annual average multipliers. Using annual numbers provides a reasonable estimation of emissions, but it provides no indication of the temporal nature of the emissions. Therefore, there is no way of understanding the impact on emissions from load shifting and peak shaving technologies such as thermal energy storage, on-site renewable energy, and demand control. Source NREL Date Released April 11th, 2011 (3 years ago) Date Updated April 11th, 2011 (3 years ago) Keywords buildings carbon dioxide emissions carbon footprinting CO2 commercial buildings electricity emission factors ERCOT hourly emission factors interconnect nitrogen oxides NOx

363

Estimation of Carbon Monoxide and Carbon Dioxide at Sub-ppm Level Concentrations in Ammonia Synthesis Gas  

Science Journals Connector (OSTI)

......can be handled per analysis. The ammonia synthesis...conditioning of I2O5 reactors or to marginal flow...20%. Thus, the reliability of the method depends...practice for the analysis of trace impurities...estimated from a single analysis the method of converting...to CO2 using I2O5 reactor (11) after its......

K. Annaji Rao; K.K. Pushpa; Hari Mohan; R.M. Iyer

1978-07-01T23:59:59.000Z

364

Effect of potassium carbonate on char gasification by carbon dioxide  

SciTech Connect (OSTI)

A differential packed-bed reactor has been employed to study the gasification of 7.5 wt% K/sub 2/CO/sub 3/-catalyzed Saran char in carbon dioxide/carbon monoxide mixtures at a total pressure near 1 atm (101.3 kPa) and temperatures between 922 and 1046 K. The rate data were tested with a model which involves two-site adsorption and subsequent dissociation of CO/sub 2/ on the char surface. The results indicate that this model adequately explains the catalyzed gasification data. Moreover, the activation energy for desorption of carbon-oxygen complex is lower for the catalyzed case than for the uncatalyzed case. Adsorption of CO and CO/sub 2/ on both catalyzed and uncatalyzed chars was also followed with a volumetric adsorption apparatus at pressures between 1 and 100 kPa and temperatures from 273 to 725 K. The catalyzed char adsorbed an order of magnitude more CO/sub 2/ at 560 K than the uncatalyzed char. Subsequent dissociation of CO/sub 2/ on the carbon surface does not appear to be catalyzed by potassium. Thus, the catalyst's role is to enhance CO/sub 2/ adsorption, thereby creating more oxygen on the surface, and lowering the activation energy for desorption of the resultant carbon-oxygen species.

Koenig, P.C.; Squires, R.G.; Laurendeau, N.M.

1986-07-01T23:59:59.000Z

365

Closed-loop control of a SCR system using a NOx sensor cross-sensitive to NH3  

E-Print Network [OSTI]

Closed-loop control of a SCR system using a NOx sensor cross-sensitive to NH3 A.Bonfils , Y. Creff for an automotive selective catalytic reduction (SCR) system, for which the feedback is based on a NOx sensor the variety of en- countered technologies, selective catalytic reduction (SCR) is one of the most appealing

366

Exhaust gas fuel reforming of Diesel fuel by non-thermal arc discharge for NOx trap regeneration  

E-Print Network [OSTI]

1 Exhaust gas fuel reforming of Diesel fuel by non- thermal arc discharge for NOx trap regeneration to the reforming of Diesel fuel with Diesel engine exhaust gas using a non-thermal plasma torch for NOx trap Diesel fuel reforming with hal-00617141,version1-17May2013 Author manuscript, published in "Energy

Boyer, Edmond

367

Nitrogen Isotopic Composition of Coal-Fired Power Plant NOx: Influence of Emission Controls and Implications for Global Emission  

E-Print Network [OSTI]

Nitrogen Isotopic Composition of Coal-Fired Power Plant NOx: Influence of Emission Controls and Implications for Global Emission Inventories J. David Felix,*, Emily M. Elliott, and Stephanie L. Shaw contributions, prior documentation of 15 N of various NOx emission sources is exceedingly limited

Elliott, Emily M.

368

Dissociation and excitation coefficients of nitrogen molecules and nitrogen monoxide generation  

SciTech Connect (OSTI)

The excitation coefficient ?{sub N2} is calculated for the excited metastable level of N{sub 2}(A{sub 3}?{sub u}{sup +}) in nitrogen molecules. In addition, the dissociation coefficient of nitrogen molecules is investigated by making use of the Boltzmann distribution of the electrons in atmospheric plasmas. The excitation and electron-impact dissociation coefficients of nitrogen molecules are analytically expressed in terms of the electron temperature T{sub e} for evaluations of the reactive oxygen and nitrogen species in atmospheric plasmas. As an application example of these coefficients, the nitrogen monoxide generation through a microwave torch is carried out for a development of medical tool. The nitrogen monoxide concentration from a microwave plasma-torch can be easily controlled by the nitrogen flow rate, mole fraction of the oxygen gas, and the microwave power. A simple analytic expression of the nitrogen monoxide concentration is obtained in terms of the oxygen molecular density and gas flow rate. The experimental data agree remarkably well with the theoretical results from the analytical expression. A microwave nitrogen-torch can easily provide an appropriate nitrogen monoxide concentration for the wound healings.

Uhm, Han S.; Na, Young H.; Choi, Eun H.; Cho, Guangsup [Department of Electronic and Biological Physics, Kwangwoon University 447-1 Wolgye-Dong, Nowon-Gu, Seoul 137-701 (Korea, Republic of)] [Department of Electronic and Biological Physics, Kwangwoon University 447-1 Wolgye-Dong, Nowon-Gu, Seoul 137-701 (Korea, Republic of)

2013-08-15T23:59:59.000Z

369

Remote Sensing of Commercial Aircraft Emissions Peter J. Popp & Donald H. Stedman  

E-Print Network [OSTI]

), and nitrogen oxides (NOx, which is the sum of nitrogen oxide, NO, and nitrogen dioxide, NO2) emitted from,4 The instrument consists of a non-dispersive infrared (IR) component for detecting carbon monoxide, carbon dioxide (CO2), and hydrocarbons (HC), and a dispersive ultraviolet (UV) spectrometer for measuring nitrogen

Denver, University of

370

CARBON-CARBON COMPOSITE ALLCOMP Carbon-Carbon Composite  

E-Print Network [OSTI]

CARBON-CARBON COMPOSITE ALLCOMP Carbon-Carbon Composite · C-C supplied in two forms · T300: C-C composite containing continuous PAN T300 fibers · SWB: Chopped Fiber Composite containing SWB fibers Crush strength 4340 steel, carbon-carbon composite, and Carbon-Silicon Carbide composite were tested to examine

Rollins, Andrew M.

371

NOx Control Options and Integration for US Coal Fired Boilers  

SciTech Connect (OSTI)

This is the fifteenth Quarterly Technical Report for DOE Cooperative Agreement No: DE-FC26-00NT40753. The goal of the project is to develop cost effective analysis tools and techniques for demonstrating and evaluating low NOx control strategies and their possible impact on boiler performance for boilers firing US coals. The Electric Power Research Institute (EPRI) is providing co-funding for this program. At AEP's Gavin Plant, data from the corrosion probes showed that corrosion rate increased as boiler load was increased. During an outage at the plant, the drop in boiler load, sensor temperature and corrosion rate could all be seen clearly. Restarting the boiler saw a resumption of corrosion activity. This behavior is consistent with previous observations made at a 600MWe utility boiler. More data are currently being examined for magnitudes of corrosion rates and changes in boiler operating conditions. Considerable progress was made this quarter in BYU's laboratory study of catalyst deactivation. Surface sulfation appears to partially suppress NO adsorption when the catalyst is not exposed to NH3; NH3 displaces surface-adsorbed NO on SCR catalysts and surface sulfation increases the amount of adsorbed NH3, as confirmed by both spectroscopy and TPD experiments. However, there is no indication of changes in catalyst activity despite changes in the amount of adsorbed NH3. A monolith test reactor (MTR), completed this quarter, provided the first comparative data for one of the fresh and field-exposed monolith SCR catalysts yet developed in this project. Measurements of activity on one of the field-exposed commercial monolith catalysts do not show significant changes in catalyst activity (within experimental error) as compared to the fresh catalyst. The exposed surface of the sample contains large amounts of Ca and Na, neither of which is present in the fresh sample, even after removal of visibly obvious fouling deposits. However, these fouling compounds do not deactivate the catalyst to the extent that these same poisons do in the deliberately wet-impregnated laboratory-prepared samples (1%V{sub 2}O{sub 5}-9%WO{sub 3}/TiO{sub 2}). At least in this case, the fouling deposits generated by field exposure present little if any chemical deactivation or barrier to mass transfer. During this quarter, the slipstream reactor at Rockport operated for 1000 hours on flue gas. Periodic NO{sub x} reduction measurements were made, showing some decrease in activity relative to fresh catalyst samples. Plans are being made to take the reactor out of service at the Rockport plant and move it to Plant Gadsden. At Gadsden, inlet and outlet ports were installed on Unit 1 for the slipstream reactor during an outage.

Mike Bockelie; Kevin Davis; Temi Linjewile; Connie Senior; Eric Eddings; Kevin Whitty; Larry Baxter; Calvin Bartholomew; William Hecker; Stan Harding

2004-03-31T23:59:59.000Z

372

Influence of combustion parameters on NOx production in an industrial boiler  

E-Print Network [OSTI]

Influence of combustion parameters on NOx production in an industrial boiler M.A. Habib a,*, M pollution using a model furnace of an industrial boiler utilizing fuel gas. The importance of this problem is mainly due to its relation to the pollutants produced by large boiler furnaces used widely in thermal

Aldajani, Mansour A.

373

REAL-WORLD EFFICACY OF HEAVY DUTY DIESEL TRUCK NOX AND PM EMISSIONS CONTROLS  

E-Print Network [OSTI]

are International. b DOC = Diesel Oxidation Catalyst; DPF = Diesel Particulate Filter; EGR = Exhaust GasREAL-WORLD EFFICACY OF HEAVY DUTY DIESEL TRUCK NOX AND PM EMISSIONS CONTROLS Gurdas Sandhu H 26-28, 2012 #12;2 Objectives 1. Quantify inter-run variability in exhaust emission rates 2. Assess

Frey, H. Christopher

374

Consequences of propene and propane on plasma remediation of NOx Rajesh Doraia)  

E-Print Network [OSTI]

. INTRODUCTION Plasma remediation of exhaust from internal combustion engines, and diesel engines in particular of achieving high E/N electric field/ gas number density are promising in this regard.11 Actual diesel exhaust discharge DBD reactors are being investigated for plasma remediation of NOx from the exhaust of internal

Kushner, Mark

375

tive emissions from EVs (e.g., power plant NOx) and GPVs (tailpipe and  

E-Print Network [OSTI]

a few sluggish electric vehicles would cause enough traffic slowing that the gasoline- powered fleet Analy- sis article on battery-powered vehicles (Sept. 1996, p. 402A) serves as a useful remindertive emissions from EVs (e.g., power plant NOx) and GPVs (tailpipe and associated NO.,. emissions

Denver, University of

376

Observation of NOx enhancement and ozone depletion in the Northern and Southern  

E-Print Network [OSTI]

Clarmann, G. P. Stiller, M. Ho¨pfner, S. Kellmann, and H. Fischer Institut fu¨r Meteorologie und Clarmann, G. P. Stiller, M. Ho¨pfner, S. Kellmann, H. Fischer, and C. H. Jackman (2005), Observation of NOx

Jackman, Charles H.

377

Atmospheric Environment 38 (2004) 27792787 First detection of nitrogen from NOx in tree rings: a 15  

E-Print Network [OSTI]

abies; Air pollution; Dendroecology; Nitrogen deposition; Stable isotopes; Nitrogen dioxide 1Atmospheric Environment 38 (2004) 2779­2787 First detection of nitrogen from NOx in tree rings 2004; accepted 27 February 2004 Abstract Nitrogen isotope analysis (d15 N) of tree rings is potentially

378

Transport of NOx in East Asia identified by satellite and in situ measurements  

E-Print Network [OSTI]

Research Laboratory, Boulder, Colorado, USA, 3 Cooperative Institute for Research in Environmental Sciences, University of Colorado Boulder, Boulder, Colorado, USA, 4 School of Earth and Environmental Sciences, Seoul burning, and natural phenomena like lightning, wildfires, and soil microbial activity. NOx play

Park, Rokjin

379

NOx reduction with the use of feedlot biomass as a reburn fuel  

E-Print Network [OSTI]

. Additional air called overfire air (about 20 % of total air) is injected in order to complete combustion. Typically reburn fuel is natural gas (NG). From previous research at TAMU, it was found that firing feedlot biomass (FB) as reburn fuel lowers the NOx...

Goughnour, Paul Gordon

2009-05-15T23:59:59.000Z

380

Latest developments and application of DB Riley's low NOx CCV{reg{underscore}sign} burner technology  

SciTech Connect (OSTI)

Recent developments in DB Riley (DBR) low NOx burner technology and the application of this technology in coal fired utility boilers are discussed. Since the promulgation of the Clean Air Act Amendment in 1990, DBR has sold nearly 1,500 Controlled Combustion Venturi (CCV{reg{underscore}sign}) burners on pulverized coal fired utility boilers reducing NOx emissions 50--70% from uncontrolled levels. This technology has been retrofitted on boiler designs ranging in size and type from 50 MW front wall fired boilers to 1,300 MW opposed fired cell type boilers. In DBR's latest version of the CCV{reg{underscore}sign} burner, a second controlled flow air zone was added to enhance NOx control capability. Other developments included improved burner air flow measurement accuracy and several mechanical design upgrades such as new coal spreader designs for 3 year wear life. Test results of the CCV{reg{underscore}sign} dual air zone burner in DBR's 100 million Btu/hr (29 MW) coal burner test facility are presented. In the test program, coals from four utility boiler sites were fired to provide a range of coal properties. A baseline high volatile bituminous coal was also fired to provide a comparison with 1992 test data for the CCV{reg{underscore}sign} single register burner. The tests results showed that the second air zone enhanced NOx reduction capability by an additional 20% over the single register design. Computational fluid dynamic (DFD) modeling results of the CCV{reg{underscore}sign} dual air zone burner are also presented showing near field mixing patterns conducive to low NOx firing. DBR was recently awarded Phase IV of the Low Emission Boiler System (LEBS) program by the US Department of Energy to build a proof of concept facility representing the next major advancement in pulverized coal burning technology. A key part of winning that award were test results of the CCV{reg{underscore}sign} dual air zone burner with advanced air staging and coal reburning in a 100 million Btu/hr (20 MW) U-fired slagging combustor test facility. These results showed NOx emissions of less than 0.2 lb/million Btu (0.086 g/MJ) while converting the coal ash into an inert, non-leachable solid. This results is an 80% reduction in NOx emissions from currently operating U-fired slagging boilers.

Penterson, C.; Ake, T.

1998-07-01T23:59:59.000Z

Note: This page contains sample records for the topic "nox carbon monoxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Chemistry of NOx on TiO2 surfaces studied by ambient pressure XPS:  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Chemistry of NOx on TiO2 surfaces studied by ambient pressure XPS: Chemistry of NOx on TiO2 surfaces studied by ambient pressure XPS: products, effect of UV irradiation, water and coadsorbed K+ Title Chemistry of NOx on TiO2 surfaces studied by ambient pressure XPS: products, effect of UV irradiation, water and coadsorbed K+ Publication Type Journal Article Year of Publication 2013 Authors Rosseler, Olivier, Mohamad Sleiman, Nahuel V. Montesinos, Andrey Shavorskiy, Valerie Keller, Nicolas Keller, Marta I. Litter, Hendrik Bluhm, Miquel Salmeron, and Hugo Destaillats Journal J. Phys. Chem. Lett. Volume 4 Start Page 536 Issue 3 Pagination 536-541 Date Published 01/2013 Abstract Self-cleaning surfaces containing TiO2 nanoparticles have been postulated to efficiently remove NOx from the atmosphere. However, UV irradiation of NOx adsorbed on TiO2 also was shown to form harmful gas-phase byproducts such as HONO and N2O that may limit their depolluting potential. Ambient pressure XPS was used to study surface and gas-phase species formed during adsorption of NO2 on TiO2 and subsequent UV irradiation at λ = 365 nm. It is shown here that NO3-, adsorbed on TiO2 as a byproduct of NO2 disproportionation, was quantitatively converted to surface NO2 and other reduced nitrogenated species under UV irradiation in the absence of moisture. When water vapor was present, a faster NO3- conversion occurred, leading to a net loss of surface-bound nitrogenated species. Strongly adsorbed NO3- in the vicinity of coadsorbed K+ cations was stable under UV light, leading to an efficient capture of nitrogenated compounds.

382

SOx-NOx-Rox Box{trademark} flue gas clean-up demonstration. Final report  

SciTech Connect (OSTI)

Babcock and Wilcox`s (B and W) SOx-NOx-Rox Box{trademark} process effectively removes SOx, NOx and particulate (Rox) from flue gas generated from coal-fired boilers in a single unit operation, a high temperature baghouse. The SNRB technology utilizes dry sorbent injection upstream of the baghouse for removal of SOx and ammonia injection upstream of a zeolitic selective catalytic reduction (SCR) catalyst incorporated in the baghouse to reduce NOx emissions. Because the SOx and NOx removal processes require operation at elevated gas temperatures (800--900 F) for high removal efficiency, high-temperature fabric filter bags are used in the baghouse. The SNRB technology evolved from the bench and laboratory pilot scale to be successfully demonstrated at the 5-MWe field scale. This report represents the completion of Milestone M14 as specified in the Work Plan. B and W tested the SNRB pollution control system at a 5-MWe demonstration facility at Ohio Edison`s R.E. Burger Plant located near Shadyside, Ohio. The design and operation were influenced by the results from laboratory pilot testing at B and W`s Alliance Research Center. The intent was to demonstrate the commercial feasibility of the SNRB process. The SNRB facility treated a 30,000 ACFM flue gas slipstream from Boiler No. 8. Operation of the facility began in May 1992 and was completed in May 1993. About 2,300 hours of high-temperature operation were achieved. The main emissions control performance goals of: greater than 70% SO{sub 2} removal using a calcium-based sorbent; greater than 90% NOx removal with minimal ammonia slip; and particulate emissions in compliance with the New Source Performance Standards (NSPS) of 0.03 lb/million Btu were exceeded simultaneously in the demonstration program when the facility was operated at optimal conditions. Testing also showed significant reductions in emissions of some hazardous air pollutants.

NONE

1995-09-01T23:59:59.000Z

383

Combustion and \\{NOx\\} emissions of biomass-derived syngas under various gasification conditions utilizing oxygen-enriched-air and steam  

Science Journals Connector (OSTI)

The purpose of this study is to investigate the \\{NOx\\} emissions from combustion of syngas derived from gasification of three different biomass feedstock (i.e., pine, maple–oak mixture, and seed corn) at different oxygen-enriched-air and steam conditions. Three different oxygen-enriched-air and steam conditions were tested for each feedstock, thus resulting in nine different sets of syngas. The biomass-derived syngas was burned in an industrial burner that was integrated into the gasification system. The gasifier and burner are rated at 800 kW and 879 kW thermal, respectively. For each set of biomass-derived syngas, \\{NOx\\} emissions were measured at different burner operating conditions including various heat rates and equivalence ratios using emission analyzers with chemiluminescence technology. All the combustion test conditions are in the lean mixture ranges in order to avoid the peak temperature limitation of both the burner and combustion chamber. Results show that \\{NOx\\} emissions using syngas obtained from woody feedstock decrease almost linearly as the combustion mixture becomes leaner and the heat rate decreases. When compared to natural gas, syngas from both woody feedstock generates higher \\{NOx\\} emissions even when the heat rates are comparable, indicating that fuel \\{NOx\\} formation is highly important in biomass-derived syngas combustion. In contrast to syngas from woody feedstock, syngas from seed corn results in peak \\{NOx\\} emissions before \\{NOx\\} decreases with leaner conditions. The trend is observed for all fuel flow rates and all oxygen-enriched-air and steam conditions of seed corn-derived syngas. Among the three feedstock, seed corn has the highest nitrogen content which yields the highest ammonia concentration in syngas, which, in turn, results in the highest \\{NOx\\} emissions for all test conditions. Overall, the \\{NOx\\} emissions from seed corn-derived syngas combustion are approximately in the range of 450–900 ppm higher compared to those from wood-derived syngas combustion.

Cuong Van Huynh; Song-Charng Kong

2013-01-01T23:59:59.000Z

384

On the Promoting Effect of Water during NOx Removal over Single-Site Copper in Hydrophobic Silica APD-Aerogels  

Science Journals Connector (OSTI)

Reversibility of the Cu2+/Cu+ redox pair was confirmed in the Cu-aerogel during and after wet redox cycling. ... (1) Popular solutions to selective catalytic reduction of NOx include the use of exhaust hydrocarbon residuals (SCR-HC-deNOx) or ammonia added to the exhaust (SCR-NH3-deNOx) as the reductant; the former technology being suitable for light duty passenger vehicles, whereas the latter is applied to medium or heavy duty vehicles. ... During vehicle use, the converter is exposed to heat, which causes the metal particles to agglomerate and grow, and their overall surface area to decrease. ...

Tina Kristiansen; Karina Mathisen

2014-01-10T23:59:59.000Z

385

Quantification of Black Carbon and Other Pollutant Emissions from a  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Quantification of Black Carbon and Other Pollutant Emissions from a Quantification of Black Carbon and Other Pollutant Emissions from a Traditional and an Improved Cookstove Title Quantification of Black Carbon and Other Pollutant Emissions from a Traditional and an Improved Cookstove Publication Type Report LBNL Report Number LBNL-6062E Year of Publication 2010 Authors Kirchstetter, Thomas W., Chelsea Preble, Odelle L. Hadley, and Ashok J. Gadgil Keywords aethalometer, Berkeley Darfur Stove, black carbon, carbon monoxide, climate change, DustTrak, global warming, improved cookstoves, indoor air quality, LBNL Stove Testing Facility, particulate matter, photoacoustic absorption spectrometer, pollutant emission factor, three-stone fire Abstract Traditional methods of cooking in developing regions of the world emit pollutants that

386

Vacancies in ordered and disordered titanium monoxide: Mechanism of B1 structure stabilization  

SciTech Connect (OSTI)

The electronic structure and stability of three phases of titanium monoxide TiO{sub y} with B1 type of the basic structure have been studied. Cubic phase without structural vacancies, TiO, and two phases with structural vacancies, monoclinic Ti{sub 5}O{sub 5} and cubic disordered TiO{sub 1.0}, was treated by means of first-principles calculations within the density functional theory with pseudo-potential approach based on the plane wave's basis. The ordered monoclinic phase Ti{sub 5}O{sub 5} was found to be the most stable and the cubic TiO without vacancies the less stable one. The role of structural vacancies in the titanium sublattice is to decrease the Fermi energy, the role of vacancies in the oxygen sublattice is to contribute to the appearance of Ti–Ti bonding interactions through these vacancies and to reinforce the Ti–Ti interactions close to them. Listed effects are significantly pronounced if the vacancies in the titanium and oxygen sublattices are associated in the so called “vacancy channels” which determine the formation of vacancy ordered structure of monoclinic Ti{sub 5}O{sub 5}-type. - Graphical abstract: Changes in total DOS of titanium monoxide when going from vacancy-free TiO to TiO with disordered structural vacancies and to TiO with ordered structural vacancies. Highlights: • Ordered monoclinic Ti{sub 5}O{sub 5} is the most stable phase of titanium monoxide. • Vacancy-free TiO is the less stable phase of the titanium monoxide. • Ordering of oxygen vacancies leads to the appearance of Ti–Ti bonding interactions. • Titanium vacancies contribute significantly to the decreasing of the Fermi energy.

Kostenko, M.G. [Institute of Solid State Chemistry, The Ural Branch of the Russian Academy of Sciences, Pervomayskaya 91, Ekaterinburg 620990 (Russian Federation); Lukoyanov, A.V. [Institute of Metal Physics, The Ural Branch of the Russian Academy of Sciences, S. Kovalevskoy 18, Ekaterinburg 620990 (Russian Federation); Ural Federal University named after First President of Russia B.N. Yeltsin, Mira 19, Ekaterinburg 620002 (Russian Federation); Zhukov, V.P. [Institute of Solid State Chemistry, The Ural Branch of the Russian Academy of Sciences, Pervomayskaya 91, Ekaterinburg 620990 (Russian Federation); Rempel, A.A., E-mail: rempel@ihim.uran.ru [Institute of Solid State Chemistry, The Ural Branch of the Russian Academy of Sciences, Pervomayskaya 91, Ekaterinburg 620990 (Russian Federation); Ural Federal University named after First President of Russia B.N. Yeltsin, Mira 19, Ekaterinburg 620002 (Russian Federation)

2013-08-15T23:59:59.000Z

387

HYDROGEN GENERATION FROM PLASMATRON REFORMERS: A PROMISING TECHNOLOGY FOR NOX ADSORBER REGENERATION AND OTHER AUTOMOTIVE APPLICATIONS  

SciTech Connect (OSTI)

Plasmatron reformers are being developed at MIT and ArvinMeritor [1]. In these reformers a special low power electrical discharge is used to promote partial oxidation conversion of hydrocarbon fuels into hydrogen and CO. The partial oxidation reaction of this very fuel rich mixture is difficult to initiate. The plasmatron provides continuous enhanced volume initiation. To minimize electrode erosion and electrical power requirements, a low current, high voltage discharge with wide area electrodes is used. The reformers operate at or slightly above atmospheric pressure. Plasmatron reformers provide the advantages of rapid startup and transient response; efficient conversion of the fuel to hydrogen rich gas; compact size; relaxation or elimination of reformer catalyst requirements; and capability to process difficult to reform fuels, such as diesel and bio-oils. These advantages facilitate use of onboard hydrogen-generation technology for diesel exhaust after-treatment. Plasma-enhanced reformer technology can provide substantial conversion even without the use of a catalyst. Recent progress includes a substantial decrease in electrical power consumption (to about 200 W), increased flow rate (above 1 g/s of diesel fuel corresponding to approximately 40 kW of chemical energy), soot suppression and improvements in other operational features.. Plasmatron reformer technology has been evaluated for regeneration of NOx adsorber after-treatment systems. At ArvinMeritor tests were performed on a dual-leg NOx adsorber system using a Cummins 8.3L diesel engine both in a test cell and on a vehicle. A NOx adsorber system was tested using the plasmatron reformer as a regenerator and without the reformer i.e., with straight diesel fuel based regeneration as the baseline case. The plasmatron reformer was shown to improve NOx regeneration significantly compared to the baseline diesel case. The net result of these initial tests was a significant decrease in fuel penalty, roughly 50% at moderate adsorber temperatures. This fuel penalty improvement is accompanied by a dramatic drop in slipped hydrocarbon emissions, which decreased by 90% or more. Significant advantages are demonstrated across a wide range of engine conditions and temperatures. The study also indicated the potential to regenerate NOx adsorbers at low temperatures where diesel fuel based regeneration is not effective, such as those typical of idle conditions. Two vehicles, a bus and a light duty truck, have been equipped for plasmatron reformer NOx adsorber regeneration tests.

Bromberg, L.; Crane, S; Rabinovich, A.; Kong, Y; Cohn, D; Heywood, J; Alexeev, N.; Samokhin, A.

2003-08-24T23:59:59.000Z

388

An Analysis of the health impacts from PM and NOx emissions resulting from train operations in the Alameda Corridor, CA  

E-Print Network [OSTI]

2009). Estimating PM and NOx Train Emissions in the AlamedaAuthority. Number of Trains Running on the Alameda Corridor.x emissions resulting from train operations in the Alameda

Sangkapichai, Mana; Saphores, Jean-Daniel M; Ogunseitan, Oladele; Ritchie, Stephen G.; You, Soyoung Iris; Lee, Gunwoo

2010-01-01T23:59:59.000Z

389

Heavy-duty diesel vehicle Nox? aftertreatment in 2010 : the infrastructure and compliance challenges of urea-SCR  

E-Print Network [OSTI]

Increasingly stringent heavy-duty vehicle emission regulations are prompting the use of PM and NOx aftertreatment systems in the US, the EU and Japan. In the US, the EPA Highway Diesel Rule, which will be fully implemented ...

Bodek, Kristian M

2008-01-01T23:59:59.000Z

390

Cold-Start Emissions Control in Hybrid Vehicles Equipped with a Passive Adsorber for Hydrocarbons and NOx  

Broader source: Energy.gov [DOE]

Reports results from study of potential for using chemisorbing materials to temporally trap HC and NOx emissions during cold-start of HEVs and PHEVs over transient driving cycles

391

NOx Emissions Reductions from Implementation of the 2000 IECC/IRC Conservation Code to Residential Construction in Texas  

E-Print Network [OSTI]

.1000 0.1500 0.2000 0.2500 0.3000 0.3500 0.4000 0.0000 0.0500 0.1000 0.1500 0.2000 0.2500 0.3000 0.3500 0.4000 To ns - NOx/day (average) Tons - NOX/day (p eak) Apx 2x difference 1:1 2...

Haberl, J. S.; Im, P.; Culp, C.; Yazdani, B.; Fitzpatrick, T.

2004-01-01T23:59:59.000Z

392

Application of Taguchi's orthogonal array in reducing the NOx emission of a stationary diesel engine  

Science Journals Connector (OSTI)

The main objective of this investigation is to reduce the NOx emission of a stationary diesel engine with less sacrifice on smoke intensity and brake thermal efficiency (BTE). Fuel injection timing, percentage of EGR and fuel injection pressure are chosen as factors influencing the objective. Three levels were chosen in each factor and design of experiments method was employed to design the experiments. Taguchi's L9 orthogonal array was used to conduct the engine tests with different levels of the chosen factors. Test results were analysed by analysis of variance (ANOVA) method and ANOVA table was formed for each response variable. From the ANOVA table the most influencing factor and also the significance of each factor affecting the NOx emission, smoke intensity and BTE was found out. Response graph was drawn for each response variable to determine the optimum combination of the factor levels. This optimum combination was confirmed experimentally. [Received: November 14, 2010; Accepted: March 17, 2011

S. Saravanan; G. Nagarajan; R. Ramanujam; S. Sampath

2011-01-01T23:59:59.000Z

393

Low NOx firing technology of Mitsubishi Heavy Industries  

SciTech Connect (OSTI)

This paper presents super low NO{sub x} combustion technologies successfully developed by MHI (Mitsubishi Heavy Industries, Ltd.) and its use in practice. PM (Pollution Minimum) burners directly reduce NO{sub x} from the burners themselves and MACT (Mitsubishi Advanced Combustion Technology) system, an in-furnace NO{sub x} removal system, reduces NO{sub x} generated from the main burners within the boiler. These firing systems are applicable to coal, oil, gas and also to other exotic fuels like Orimulsion or CWM (Coal Water Mixture). MRS (Mitsubishi Rotary Separator) mills minimizes unburnt carbon with its reliable ultra-fine grinding of coal and hence contribute to low NO{sub x}. These technologies have been applied in various combinations to 227 boilers for both new installation and retrofit jobs. Large 1,000 MWe oil or gas fired boilers and 700 MWe coal fired boilers have been put into commercial use, and a 1,000 MWe coal fired boiler is under commissioning. The technologies have been applied to small sized boilers for industrial use as well. All the delivered systems have been working both domestic and overseas to the customers` satisfaction.

Kaneko, Shozo; Tokuda, Kimishiro; Sato, Susumu [Mitsubishi Heavy Industries, Yokohama (Japan)

1996-01-01T23:59:59.000Z

394

Simultaneous Removal of NOx and Mercury in Low Temperature Selective Catalytic and Adsorptive Reactor  

SciTech Connect (OSTI)

The results of a 18-month investigation to advance the development of a novel Low Temperature Selective Catalytic and Adsorptive Reactor (LTSCAR), for the simultaneous removal of NO{sub x} and mercury (elemental and oxidized) from flue gases in a single unit operation located downstream of the particulate collectors, are reported. In the proposed LTSCAR, NO{sub x} removal is in a traditional SCR mode but at low temperature, and, uniquely, using carbon monoxide as a reductant. The concomitant capture of mercury in the unit is achieved through the incorporation of a novel chelating adsorbent. As conceptualized, the LTSCAR will be located downstream of the particulate collectors (flue gas temperature 140-160 C) and will be similar in structure to a conventional SCR. That is, it will have 3-4 beds that are loaded with catalyst and adsorbent allowing staged replacement of catalyst and adsorbent as required. Various Mn/TiO{sub 2} SCR catalysts were synthesized and evaluated for their ability to reduce NO at low temperature using CO as the reductant. It has been shown that with a suitably tailored catalyst more than 65% NO conversion with 100% N{sub 2} selectivity can be achieved, even at a high space velocity (SV) of 50,000 h-1 and in the presence of 2 v% H{sub 2}O. Three adsorbents for oxidized mercury were developed in this project with thermal stability in the required range. Based on detailed evaluations of their characteristics, the mercaptopropyltrimethoxysilane (MPTS) adsorbent was found to be most promising for the capture of oxidized mercury. This adsorbent has been shown to be thermally stable to 200 C. Fixed-bed evaluations in the targeted temperature range demonstrated effective removal of oxidized mercury from simulated flue gas at very high capacity ({approx}>58 mg Hg/g adsorbent). Extension of the capability of the adsorbent to elemental mercury capture was pursued with two independent approaches: incorporation of a novel nano-layer on the surface of the chelating mercury adsorbent to achieve in situ oxidation on the adsorbent, and the use of a separate titania-supported manganese oxide catalyst upstream of the oxidized mercury adsorbent. Both approaches met with some success. It was demonstrated that the concept of in situ oxidation on the adsorbent is viable, but the future challenge is to raise the operating capacity beyond the achieved limit of 2.7 mg Hg/g adsorbent. With regard to the manganese dioxide catalyst, elemental mercury was very efficiently oxidized in the absence of sulfur dioxide. Adequate resistance to sulfur dioxide must be incorporated for the approach to be feasible in flue gas. A preliminary benefits analysis of the technology suggests significant potential economic and environmental advantages.

Neville G. Pinto; Panagiotis G. Smirniotis

2006-03-31T23:59:59.000Z

395

A decoupled approach for NOx–N2O 3-D CFD modeling in CFB plants  

Science Journals Connector (OSTI)

Abstract In this study, a 3D CFD model for the formation of \\{NOx\\} and N2O in a lignite fired 1.2 MWth CFB pilot plant is developed. The decoupled approach (decoupled from combustion simulation) is tested for the minimization of computational cost. As combustion simulation is prerequired, this was achieved through a simplified 3-D CFD combustion model. The developed model is then applied to the pilot-scale 1.2 MWth CFB plant and validated against experimental data. As concerns the NOx–N2O model, an extensive literature review is also carried out for the incorporation of the appropriate reactions network and respective reaction rates expressions. Results show that homogenous reactions are favoured on the lower section of the bed, due to the abundance of fuel devolatilization products. On the other hand, on the upper section, heterogeneous reactions govern nitric oxide formation/reduction. It is found that for the lignite examined in this work, HCN is released in negligible amounts during char combustion. The proposed and validated CFD model for \\{NOx\\} and N2O, is capable of examining the effect of different operational parameters and coal properties on the overall nitric oxides emissions from a CFB combustor, with low computational cost and without the additional expenses for pilot-scale experiments.

A. Nikolopoulos; I. Malgarinos; N. Nikolopoulos; P. Grammelis; S. Karrelas; E. Kakaras

2014-01-01T23:59:59.000Z

396

Ammonia Generation over TWC for Passive SCR NOX Control for Lean Gasoline Engines  

SciTech Connect (OSTI)

A commercial three-way catalyst (TWC) was evaluated for ammonia (NH3) generation on a 2.0-liter BMW lean burn gasoline direct injection engine as a component in a passive ammonia selective catalytic reduction (SCR) system. The passive NH3 SCR system is a potential low cost approach for controlling nitrogen oxides (NOX) emissions from lean burn gasoline engines. In this system, NH3 is generated over a close-coupled TWC during periodic slightly rich engine operation and subsequently stored on an underfloor SCR catalyst. Upon switching to lean, NOX passes through the TWC and is reduced by the stored NH3 on the SCR catalyst. NH3 generation was evaluated at different air-fuel equivalence ratios at multiple engine speed and load conditions. Near complete conversion of NOX to NH3 was achieved at =0.96 for nearly all conditions studied. At the =0.96 condition, HC emissions were relatively minimal, but CO emissions were significant. Operation at AFRs richer than =0.96 did not provide more NH3 yield and led to higher HC and CO emissions. Results of the reductant conversion and consumption processes were used to calculate a representative fuel consumption of the engine operating with an ideal passive SCR system. The results show a 1-7% fuel economy benefit at various steady-state engine speed and load points relative to a stoichiometric engine operation.

Prikhodko, Vitaly Y [ORNL] [ORNL; Parks, II, James E [ORNL; Pihl, Josh A [ORNL] [ORNL; Toops, Todd J [ORNL] [ORNL

2014-01-01T23:59:59.000Z

397

Modeling Species Inhibition of NO oxidation in Urea-SCR Catalysts for Diesel Engine NOx Control  

SciTech Connect (OSTI)

Urea-selective catalytic reduction (SCR) catalysts are regarded as the leading NOx aftertreatment technology to meet the 2010 NOx emission standards for on-highway vehicles running on heavy-duty diesel engines. However, issues such as low NOx conversion at low temperature conditions still exist due to various factors, including incomplete urea thermolysis, inhibition of SCR reactions by hydrocarbons and H2O. We have observed a noticeable reduction in the standard SCR reaction efficiency at low temperature with increasing water content. We observed a similar effect when hydrocarbons are present in the stream. This effect is absent under fast SCR conditions where NO ~ NO2 in the feed gas. As a first step in understanding the effects of such inhibition on SCR reaction steps, kinetic models that predict the inhibition behavior of H2O and hydrocarbons on NO oxidation are presented in the paper. A one-dimensional SCR model was developed based on conservation of species equations and was coded as a C-language S-function and implemented in Matlab/Simulink environment. NO oxidation and NO2 dissociation kinetics were defined as a function of the respective adsorbate’s storage in the SCR catalyst. The corresponding kinetic models were then validated on temperature ramp tests that showed good match with the test data.

Devarakonda, Maruthi N.; Tonkyn, Russell G.; Tran, Diana N.; Lee, Jong H.; Herling, Darrell R.

2010-09-15T23:59:59.000Z

398

Modeling Species Inhibition of NO Oxidation in Urea-SCR Catalysts for Diesel Engine NOx Control  

SciTech Connect (OSTI)

Urea-selective catalytic reduction (SCR) catalysts are regarded as the leading NOx aftertreatment technology to meet the 2010 NOx emission standards for on-highway vehicles running on heavy-duty diesel engines. However, issues such as low NOx conversion at low temperature conditions still exist due to various factors, including incomplete urea thermolysis, inhibition of SCR reactions by hydrocarbons and H2O. We have observed a noticeable reduction in the standard SCR reaction efficiency at low temperature with increasing water content. We observed a similar effect when hydrocarbons are present in the stream. This effect is absent under fast SCR conditions where NO ~ NO2 in the feed gas. As a first step in understanding the effects of such inhibition on SCR reaction steps, kinetic models that predict the inhibition behavior of H2O and hydrocarbons on NO oxidation are presented in the paper. A one-dimensional SCR model was developed based on conservation of species equations and was coded as a C-language S-function and implemented in Matlab/Simulink environment. NO oxidation and NO2 dissociation kinetics were defined as a function of the respective adsorbate’s storage in the Fe-zeolite SCR catalyst. The corresponding kinetic models were then validated on temperature ramp tests that showed good match with the test data. Such inhibition models will improve the accuracy of model based control design for integrated DPF-SCR aftertreatment systems.

Devarakonda, Maruthi N.; Tonkyn, Russell G.; Tran, Diana N.; Lee, Jong H.; Herling, Darrell R.

2011-04-20T23:59:59.000Z

399

INDOOR AIR QUALITY  

E-Print Network [OSTI]

carbon monoxide, nitrogen dioxide, formaldehyde, radon, andcarbon monoxide (CO), nitrogen dioxide (N0 ), formaldehyde (

Hollowell, C.D.

2010-01-01T23:59:59.000Z

400

Carbon sequestration  

Science Journals Connector (OSTI)

...Leaver and Howard Dalton Carbon sequestration Rattan Lal * * ( lal.1...and biotic technologies. Carbon sequestration implies transfer of atmospheric...and biomass burning. 3. Carbon sequestration Emission rates from fossil...

2008-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "nox carbon monoxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Carbon Sequestration  

Science Journals Connector (OSTI)

Carbon sequestration” refers to a portfolio of activities for ... capture, separation and storage or reuse of carbon or CO2. Carbon sequestration technologies encompass both the prevention of CO2 emissions into ...

Robert L. Kane MS; Daniel E. Klein MBA

2005-01-01T23:59:59.000Z

402

Modification of Y Zeolite with Alkaline Treatment: Textural Properties and Catalytic Activity for Diethyl Carbonate Synthesis  

Science Journals Connector (OSTI)

(1) Compared to dimethyl carbonate (DMC) and ethanol, DEC has been proposed as a potential fuel oxygenate additive to replace methyl tert-butyl ether (MTBE) because of its high oxygen content (40.6 wt %) and favorable fuel/water partition coefficient. ... For CuY using untreated zeolite as a support, there were only two H2-comsumption peaks at 473 and 681 K, ascribed to the Cu+ located on sites III? and II. ... Dunn, B. C.; Guenneau, C.; Hilton, S. A.; Pahnke, J.; Eyring, E. M.Production of diethyl carbonate from ethanol and carbon monoxide over a heterogeneous catalyst Energy Fuels 2002, 16, 177– 181 ...

Shouying Huang; Pengzhen Chen; Bing Yan; Shengping Wang; Yongli Shen; Xinbin Ma

2013-04-20T23:59:59.000Z

403

Pre-Combustion Carbon Capture Research | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Pre-Combustion Carbon Capture Research Pre-Combustion Carbon Capture Research Pre-Combustion Carbon Capture Research Pre-combustion capture refers to removing CO2 from fossil fuels before combustion is completed. For example, in gasification processes a feedstock (such as coal) is partially oxidized in steam and oxygen/air under high temperature and pressure to form synthesis gas. This synthesis gas, or syngas, is a mixture of hydrogen, carbon monoxide, CO2, and smaller amounts of other gaseous components, such as methane. The syngas can then undergo the water-gas shift reaction to convert CO and water (H2O) to H2 and CO2, producing a H2 and CO2-rich gas mixture. The concentration of CO2 in this mixture can range from 15-50%. The CO2 can then be captured and separated, transported, and ultimately sequestered, and the H2-rich fuel combusted.

404

Argonne Chemical Sciences & Engineering - Catalysis & Energy Conversion -  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Catalytic Removal of Oxides of Nitrogen from Diesel Exhaust Streams Catalytic Removal of Oxides of Nitrogen from Diesel Exhaust Streams Nox removal One of the planet's major pollutants, nitrogen oxides (NOx) are formed in all high temperature fuel-air flames, and so they are a particular emissions problem for diesel engines. Although diesel-fueled engines emit very small amounts of carbon monoxide (CO) and hydrocarbons (HCs), they do, however, release relatively high amounts of NOx and particulate matter (PM) or soot--the emissions that lead to acid rain, smog, and poor health conditions. Thus, removing NOx from emission streams has become a global concern. Argonne researchers have developed an innovative diesel DeNOx catalyst technology that provides industry with a totally passive, easy-to-use system for removing NOx from exhaust streams. Vehicle drivers do not need

405

NETL: Coal-Fired Power Plants (CFPPs)  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

NOx Sources NOx Sources Coal-Fired Power Plants (CFPPs) Causes of greenhouse gases, Including NOx What is NOx? Environmental Impacts NOx Sources Reduction Efforts Several greenhouse gases, including NOx, are increasing due to human activities in the following areas: Burning of fossil fuel (for example, coal-fired power plants), Logging (mainly contributes to carbon monoxide), Agriculture processes, Use of chlorofluorocarbons (CFC) in holon fire suppression and refrigeration The chart below shows the three major gases contributing to greenhouse gas emissions along with their source by sector. Annual Greenhouse Gas Emissions by Sector Note: This figure was created and copyrighted by Robert A. Rohde from published data and is part of the Global Warming Art project. This image is an original work created for Global Warming Art Permission is granted to copy, distribute and/or modify this image under either:

406

\\{NOx\\} emission characteristics of fluidized bed combustion in atmospheres rich in oxygen and water vapor for high-nitrogen fuel  

Science Journals Connector (OSTI)

Abstract The present study examines the influence of water vapor in combustion atmosphere on \\{NOx\\} emission from oxygen-enriched combustion of air-dried distilled spirit lees and its char in a laboratory fluidized bed of 760 mm high and 68 mm in inner diameter. Steam was added into the fluidizing gas to vary the vapor content in the combustion atmosphere. At a combustion temperature of 950 °C and a steam-to-fuel mass ratio (S/F) of 0.5, the presence of water vapor reduced the \\{NOx\\} concentration in the flue gas for low O2 contents (?30 vol.%) in the combustion agent but increased the \\{NOx\\} emission for high O2 contents (?40 vol.%). The possible causes were clarified for this shift from suppression to promotion of fuel-N conversion into \\{NOx\\} with raising O2 concentration in the combustion agent. Varying temperature from 850 °C to 1150 °C resulted in a peak conversion of fuel-N to \\{NOx\\} in the temperature range of 950–1050 °C for all the tested O2 concentrations. Increasing the O2 concentration tended to lower the critical temperature corresponding to such a peak fuel-N conversion. Testing results also suggested that the presence of excessive water vapor in the combustion atmosphere would inhibit the release of fuel-N in the devolatilization stage and promote the formation of some reducing gases. In addition to the anticipated diluting effect, the steam addition also shortened the reaction time for homogeneous and heterogeneous \\{NOx\\} reduction by the reducing gases and char. It is postulated that the formation of OH radicals at high O2 content and high temperature could cause the observed increase in the \\{NOx\\} emission.

Chuanqiang Zhu; Shuyuan Liu; Huan Liu; Juan Yang; Xiaoxing Liu; Guangwen Xu

2015-01-01T23:59:59.000Z

407

Control-oriented input-delay model of the distributed temperature of a SI engine exhaust  

E-Print Network [OSTI]

shifting [8]. This open-loop technique leads to a faster heating of the catalyst but also yields combustion the combustion: hydrocar- bons HC, carbon monoxide CO and nitrogen oxide NOx. Yet, conversion efficiency Delphine to activate chemical re- actions and the catalyst conversion ratio is poor [18]. Therefore, speed

408

Modeling Air Quality Near Freeways Using a Three Dimensional Eulerian Model  

E-Print Network [OSTI]

experiment, conducted at Michigan in 1976. Sensitivity of the model to meteorology and traffic-related parameters are studied in detail. In the second case, the spatial distribution of ozone, carbon monoxide, NOx and 1,3-Butadiene near a simulated 8-lane...

Kota, Sri Harsha

2010-10-12T23:59:59.000Z

409

ILYA KOLMANOVSKY, PAUL MORAAL, MICHIEL VAN NIEUWSTADT AND ANNA STEFANOPOULOU  

E-Print Network [OSTI]

components are increasingly being considered for production of passenger car internal combustion engines), oxides of nitrogen (NOx), hydrocarbons (HC) and carbon monoxide (CO). Speci - cally, increased air gas and it increases the speci c heat capacity of the charge. This reduces the burn rate, lowering

Stefanopoulou, Anna

410

SSEENNSSOORR TTEECCHHNNOOLLOOGGYY AALLEERRTT Date Published: 24 Feb 2006  

E-Print Network [OSTI]

detection of Nitrogen Oxide (NOx) and H2S in coal power plants, Methane (CH4) and CO in coal mines (Sago their concentration reaches lethal levels is driven by events like the Sago coal mine disaster which took place on Jan valuable in situations where sensing of noxious gases such as carbon monoxide, methane, nitrogen oxides

Azad, Abdul-Majeed

411

WearAir: Expressive T-shirts for Air Quality Sensing Sunyoung Kim and Eric Paulos  

E-Print Network [OSTI]

are less proactively concerned with air quality. AIR POLLUTANT: VOLATILE ORGANIC COMPOUNDS Different types of air pollutants contribute to air quality in different locations: Ozone, CO, NOx and VOCs are major contributors to outdoor air pollution; and particulate matters, VOCs, carbon monoxide and lead are common air

Mankoff, Jennifer

412

Air Quality Standards & ATOC/CHEM 5151  

E-Print Network [OSTI]

1 Lecture 22 Air Quality Standards & Control ATOC/CHEM 5151 #12;2 Primary Pollutants Things to reduce air pollution emissions ­ Latest version ­ 1990 (original, 1963) ­ What is an "air pollutant that are directly emitted Nitrogen Oxides (NOx) Hydrocarbons (VOCs) Carbon Monoxide (CO) #12;3 Secondary Pollutants

Toohey, Darin W.

413

Fluorine-Doped Carbon Blacks: Highly Efficient Metal-Free Electrocatalysts for Oxygen Reduction Reaction  

Science Journals Connector (OSTI)

As a result of the energy crisis in the world, fuel cells are attractive as clean and sustainable energy conversion devices because they can help address the ever increasing global energy demand. ... (2, 3) To date, Pt-based materials are the most widely used electrocatalysts for ORR;(4-6) however, Pt-based catalysts suffer from problems, such as sluggish oxygen reduction at any pH, durability, very limited reserves, high cost, and inactivation by carbon monoxide (CO) poisoning. ...

Xiujuan Sun; Yuwei Zhang; Ping Song; Jing Pan; Lin Zhuang; Weilin Xu; Wei Xing

2013-07-03T23:59:59.000Z

414

Carbon Smackdown: Carbon Capture  

SciTech Connect (OSTI)

In this July 9, 2010 Berkeley Lab summer lecture, Lab scientists Jeff Long of the Materials Sciences and Nancy Brown of the Environmental Energy Technologies Division discuss their efforts to fight climate change by capturing carbon from the flue gas of power plants, as well as directly from the air

Jeffrey Long

2010-07-12T23:59:59.000Z

415

Development of a control-oriented model to optimise fuel consumption and NOX emissions in a DI Diesel engine  

Science Journals Connector (OSTI)

Abstract This paper describes a predictive NOX and consumption model, which is oriented to control and optimisation of DI Diesel engines. The model applies the Response Surface Methodology following a two-step process: firstly, the relationship between engine inputs (intake charge conditions and injection settings) and some combustion parameters (peak pressure, indicated mean effective pressure and burn angles) is determined; secondly, engine outputs (NOX and consumption) are predicted from the combustion parameters using NOX and mechanical losses models. Splitting the model into two parts allows using either experimental or modelled combustion parameters, thus enhancing the model flexibility. If experimental in-cylinder pressure is used to obtain combustion parameters, the mean error of predicted NOX and consumption are 2% and 6% respectively, with a calculation time of 5.5 ms. Using modelled parameters reduces the calculation time to 1.5 ms, with a penalty in the accuracy. The model performs well in a multi-objective optimisation, reducing NOX and consumption in different amounts depending on the objective of the optimisation.

S. Molina; C. Guardiola; J. Martín; D. García-Sarmiento

2014-01-01T23:59:59.000Z

416

Process for the conversion of carbonaceous feedstocks to particulate carbon and methanol  

DOE Patents [OSTI]

A process is described for the production of a pollutant-free particulate carbon (i.e., a substantially ash-, sulfur- and nitrogen-free carbon) from carbonaceous feedstocks. The basic process involves de-oxygenating one of the gas streams formed in a cyclic hydropyrolysis-methane pyrolysis process in order to improve conversion of the initial carbonaceous feedstock. De-oxygenation is effected by catalytically converting carbon monoxide, carbon dioxide, and hydrogen contained in one of the pyrolysis gas streams, preferably the latter, to a methanol co-product. There are thus produced two products whose use is known per se, viz., a substantially pollutant-free particulate carbon black and methanol. These products may be admixed in the form of a liquid slurry of carbon black in methanol. 3 figs.

Steinberg, M.; Grohse, E.W.

1995-06-27T23:59:59.000Z

417

Process for the conversion of carbonaceous feedstocks to particulate carbon and methanol  

DOE Patents [OSTI]

A process for the production of a pollutant-free particulate carbon (i.e., a substantially ash-, sulfur- and nitrogen-free carbon) from carbonaceous feedstocks. The basic process involves de-oxygenating one of the gas streams formed in a cyclic hydropyrolysis-methane pyrolysis process in order to improve conversion of the initial carbonaceous feedstock. De-oxygenation is effected by catalytically converting carbon monoxide, carbon dioxide, and hydrogen contained in one of the pyrolysis gas streams, preferably the latter, to a methanol co-product. There are thus produced two products whose use is known per se, viz., a substantially pollutant-free particulate carbon black and methanol. These products may be admixed in the form of a liquid slurry of carbon black in methanol.

Steinberg, Meyer (Melville, NY); Grohse, Edward W. (Port Jefferson, NY)

1995-01-01T23:59:59.000Z

418

Mapping of air quality and human exposure along motorways Steen Solvang JENSEN*  

E-Print Network [OSTI]

of nitrogen oxides (NOx) encompassing hourly data on nitrogen monoxide (NO) and nitrogen dioxide (NO2) were

419

Correcting injection pressure maladjustments to reduce NOX emissions by marine diesel engines  

Science Journals Connector (OSTI)

Emissions from the exhausts of marine diesel engines comprises several different gases including NOX. These are currently regulated at the international level under Regulation 13 of ANNEX VI of MARPOL 73/78, but this regulation only applies to new engines and is based on bench tests, for only a single engine designated the “parent engine”. Here, the need to take measurements from across their whole range and once in operation on board a vessel is examined. This would not only improve assessment of new equipment against the current regulation, but would also detect defects in the functioning of the engine.

C. Vanesa Durán Grados; Zigor Uriondo; Manuel Clemente; Francisco J. Jiménez Espadafor; Juan Moreno Gutiérrez

2009-01-01T23:59:59.000Z

420

ON IRON MONOXIDE NANOPARTICLES AS A CARRIER OF THE MYSTERIOUS 21 ?m EMISSION FEATURE IN POST-ASYMPTOTIC GIANT BRANCH STARS  

SciTech Connect (OSTI)

A prominent mysterious emission feature peaking at ?20.1 ?m—historically known as the '21 ?m' feature—is seen in over two dozen Galactic and Magellanic Cloud carbon-rich, post-asymptotic giant branch (post-AGB) stars. The nature of its carrier remains unknown since the first detection of the 21 ?m feature in 1989. Over a dozen materials have been suggested as possible carrier candidates. However, none of them has been accepted: they either require too much material (compared to what is available in the circumstellar shells around these post-AGB stars), or exhibit additional emission features that are not seen in these 21 ?m sources. Recently, iron monoxide (FeO) nanoparticles seem to be a promising carrier candidate as Fe is an abundant element and FeO emits exclusively at ?21 ?m. In this work, using the proto-typical protoplanetary nebula HD 56126 as a test case, we examine FeO nanoparticles as a carrier for the 21 ?m feature by modeling their infrared emission, with FeO being stochastically heated by single stellar photons. We find that FeO emits too broad a 21 ?m feature to explain that observed and the Fe abundance required to be locked up in FeO exceeds what is available in HD 56126. We therefore conclude that FeO nanoparticles are not likely to be responsible for the 21 ?m feature.

Li, Aigen; Jiang, B. W. [Department of Physics and Astronomy, University of Missouri, Columbia, MO 65211 (United States); Liu, J. M., E-mail: lia@missouri.edu, E-mail: bjiang@bnu.edu.cn [Department of Astronomy, Beijing Normal University, Beijing 100875 (China)

2013-11-10T23:59:59.000Z

Note: This page contains sample records for the topic "nox carbon monoxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Method for control of NOx emission from combustors using fuel dilution  

DOE Patents [OSTI]

A method of controlling NOx emission from combustors. The method involves the controlled addition of a diluent such as nitrogen or water vapor, to a base fuel to reduce the flame temperature, thereby reducing NOx production. At the same time, a gas capable of enhancing flame stability and improving low temperature combustion characteristics, such as hydrogen, is added to the fuel mixture. The base fuel can be natural gas for use in industrial and power generation gas turbines and other burners. However, the method described herein is equally applicable to other common fuels such as coal gas, biomass-derived fuels and other common hydrocarbon fuels. The unique combustion characteristics associated with the use of hydrogen, particularly faster flame speed, higher reaction rates, and increased resistance to fluid-mechanical strain, alter the burner combustion characteristics sufficiently to allow operation at the desired lower temperature conditions resulting from diluent addition, without the onset of unstable combustion that can arise at lower combustor operating temperatures.

Schefer, Robert W. (Alamo, CA); Keller, Jay O (Oakland, CA)

2007-01-16T23:59:59.000Z

422

Carbon Conference  

Science Journals Connector (OSTI)

Carbon Conference ... The Fourth Hienninl Conference on Carbon will be held at the University of Buffalo, June 15 to 19. ... The Pittsburgh Section's coal technology group will meet in the conference room at Mellon Institute, Pittsburgh, June ... ...

1959-06-01T23:59:59.000Z

423

Multi-phase Multi-dimensional Analysis of PEM Fuel Cells with Carbon Monoxide Poisoning and Oxygen Bleeding.  

E-Print Network [OSTI]

??Polymer electrolyte membrane (PEM) fuel cells are promising alternative green power source for mobile, portable and stationary applications. However, their cost, durability, and performance are… (more)

Li, Yaqun

2010-01-01T23:59:59.000Z

424

Daily and 3-hourly variability in global fire emissions and consequences for atmospheric model predictions of carbon monoxide  

E-Print Network [OSTI]

of biomass burning in South?America, Int. J. Remote Sens. ,D24303 fire season in South America, J. Geophys. Res. , 103(across North, South and Central America, Remote Sens.

2011-01-01T23:59:59.000Z

425

REDUCTION OF NITRIC OXIDE BY CARBON MONOXIDE OVER A SILICA SUPPORTED PLATINUM CATALYST: INFRARED AND KINETIC STUDIES  

E-Print Network [OSTI]

System. • B. Procedures. Catalyst Preparation Infrared DiskPreparation. Catalyst Characterization. PreliminaryReduction by CO Over a Pt Catalyst," M.S. thesis, Department

Lorimer, D.H.

2011-01-01T23:59:59.000Z

426

Thermodesorption studies of catalytic systems. 16. The carbon monoxide-water vapor conversion on copper-containing catalysts  

SciTech Connect (OSTI)

Thermodesorption studies have shown the presence of several types of centers: centers for the firm irreversible adsorption of CO, centers for the adsorption of H/sub 2/O, centers for the competitive adsorption of CO and H/sub 2/O, and centers for the CO-H/sub 2/O conversion, on the surface of the skeletal copper catalyst. It is suggested that CO adsorbs in bridged form on the competitive adsorption centers, and in linear form on the reaction centers. The conversion reaction involves CO and H/sub 2/O molecules adsorbed on a small fraction (approx. 1%) of centers, the H/sub 2/O molecules in question being in the associative adsorbed form.

Gel'man, V.N.; Varlamova, A.M.; Sobolevskii, V.S.; Golosman, E.Z.; Yakerson, V.I.

1981-03-01T23:59:59.000Z

427

An infrared spectroscopy study of carbon monoxide adsorption on. alpha. -chromia surfaces: Probing oxidation states of coordinatively unsaturated surface cations  

SciTech Connect (OSTI)

CO adsorption on thermoevacuated, H{sub 2}-reduced and O{sub 2}-treated {alpha}-chromia surfaces was studied by IR spectroscopy in the temperature range 77-298 K. Coordinatively unsaturated (cus) Cr{sup 3+} cation sites, probably in 3-coordinate and to a much lesser extent 5-coordinate states, are the adsorption sites on H{sub 2}-reduced {alpha}-Cr{sub 2}O{sub 3}. The surface containing excess oxygen also exposes cus Cr{sup 4+} and Cr{sup 5+} sites. An empirical procedure is described which permits the determination of oxidation state and coordination number of the cus surface sites. This procedure is based on a correlation between C-O stretching frequency and electric field strength exerted by the cation. The latter is calculated from Pauling's strength of the electrostatic bond and effective ionic radii, both of which take the cation coordination into account.

Zaki, M.I.; Knoezinger, H. (Universitaet Muenchen (West Germany))

1989-10-01T23:59:59.000Z

428

Catalytic oxidation of carbon monoxide over Ir/SiO/sub 2/. An in situ infrared and kinetic study  

SciTech Connect (OSTI)

The oxidation of CO on a highly dispersed Ir/SiO/sub 2/ catalyst has been studied both in a Pyrex microreactor and by using an in situ infrared cell-reactor. Multiple steady states obtained under conditions of increasing and decreasing CO partial pressure were observed to lead to reaction rate hysteresis. The area under the hysteresis loop is strongly dependent on reaction temperature. This is explained by invoking competitive adsorption between CO and O/sub 2/ as a function of temperature. Self-sustained oscillations were obtained when certain conditions of partial pressure and temperature were met. Quantitative estimates of fluctuations in surface coverage and temperature during these oscillations were 10% and 3K, respectively. CO islands of reactivity were not observed under the conditions of this study. The presence of higher oxidation states of IR could not be unequivocally determined by using infrared spectroscopy. 29 references, 8 figures, 2 tables.

Saymeh, R.A.; Gonzalez, R.D.

1986-02-13T23:59:59.000Z

429

The isotopic record of Northern Hemisphere atmospheric carbon monoxide1 since 1950; implications for the CO budget Supplementary Material2  

E-Print Network [OSTI]

), the mass balance calculation can be performed with the following equation:54 13 C= i=1 7 [COi ]/[CO]Ã? 13

Meskhidze, Nicholas

430

Spectroscopic study of a Cu/CeO{sub 2} catalyst subjected to redox treatments in carbon monoxide and oxygen  

SciTech Connect (OSTI)

Redox processes induced by interaction of a calcined Cu/CeO{sub 2} catalyst with CO and reoxidation with O{sub 2} have been investigated by CO-TPR, EPR, FTIR of adsorbed CO, and XPS. The initial calcined samples shows the presence of dispersed Cu{sup 2+} species, which give rise in the EPR spectrum to signals due to isolated entities, a somewhat more aggregated Cu{sup 2+}-containing phase, and copper ionic pairs, in coexistence with an EPR-silent CuO-type phase, revealed by XPS. A significant reduction of copper is produced already by contact with CO at room temperature, EPR results suggesting that reducibility of Cu{sup 2+} species decreases with their aggregation degree. Simultaneously, the ceria surface is also reduced by this interaction, copper acting as a strong promoter of this process. A singular consequence of the synergistic reduction of both components is observed by subjecting the catalyst to CO at T{sub r} {ge} 473 K, at which the CO adsorption capability of copper is apparently suppressed, in view of the absence of copper carbonyls in the FTIR spectrum. This is attributed to the establishment of electronic interactions between reduced ceria and small metallic copper particles generated by the reduction process. Contact of the CO-reduced sample with O{sub 2} at room or higher temperature produces an important reoxidation of both copper and ceria, revealed by FTIR and EPR. The synergetic effects between copper and ceria in the reduction process and the easy reoxidation of deeply reduced ceria are thought to be crucial to explaining the high catalytic activity shown by this system for CO oxidation.

Martinez-Arias, A.; Fernandez-Garcia, M.; Soria, J.; Conesa, J.C. [CSIC, Madrid (Spain). Instituto de Catalisis y Petroleoquimica] [CSIC, Madrid (Spain). Instituto de Catalisis y Petroleoquimica

1999-03-10T23:59:59.000Z

431

Seasonal variation of carbon monoxide in northern Japan: Fourier transform IR measurements and source-labeled model calculations  

E-Print Network [OSTI]

doi:10.1029/2002JD003093. Stricker, N. C. M. , A. Hahne, D.satellite measurements [ Stricker et al . , 1995] are shown

2006-01-01T23:59:59.000Z

432

Seasonal variation of carbon monoxide in northern Japan: Fourier transform IR measurements and source-labeled model calculations  

E-Print Network [OSTI]

emissions, fossil and bio- fuel burning and biomass burningof contributions from fossil and bio- fuel burning (FF) and

2006-01-01T23:59:59.000Z

433

Broadband carbon monoxide laser system operating in the wavelength range of 2.5 - 8.3 {mu}m  

SciTech Connect (OSTI)

A two-cascade frequency conversion of CO-laser radiation is demonstrated in a single sample of a nonlinear ZnGeP{sub 2} crystal. The crystal is pumped by a repetitively pulsed cryogenic lowpressure CO laser operating on {approx}150 vibration - rotational transitions in the wavelength range 5.0 - 7.5 {mu}m, which corresponds to the frequency range of a half octave. In the first conversion cascade, generation of second harmonic and sum frequencies of various pairs of CO-laser radiation give {approx}350 emission lines in the wavelength range 2.5 - 3.7 {mu}m. In the second cascade, by mixing the radiation converted in the first cascade with the residual radiation of the CO laser we have obtained {approx}90 lines in the range 4.3 - 5.0 {mu}m and more than 80 lines in the range 7.5 - 8.3 {mu}m. Thus, using a single sample of the nonlinear ZnGeP{sub 2} crystal pumped by the radiation of a single CO laser we have produced a source of broadband (more than one and a half octaves) laser radiation, simultaneously operating at {approx}670 lines in the wavelength range 2.5 - 8.3 {mu}m. (lasers)

Andreev, Yu M; Ionin, Andrei A; Kinyaevsky, I O; Klimachev, Yu M; Kozlov, A Yu; Kotkov, A A; Lanskii, G V; Shaiduko, A V

2013-02-28T23:59:59.000Z

434

Isolation of carbon monoxide dehydrogenase from Acetobacterium woodii and comparison of its properties with those of the Clostridium thermoaceticum enzyme.  

Science Journals Connector (OSTI)

...to be the primary natural electron carrier...to be the primary natural electron carrier...to be the primary natural electron carrier...Chemical Co., Inc., Corpus Christi, Tex.). A. woodii...H2-CO2 (66/33) gas mixture or on fructose...

S W Ragsdale; L G Ljungdahl; D V DerVartanian

1983-09-01T23:59:59.000Z

435

Analysis of mid-tropospheric carbon monoxide data using a three- dimensional Global atmospheric Chemistry numerical Model  

SciTech Connect (OSTI)

The GChM atmospheric chemistry and transport model has been used to analyze the mid-tropospheric CO dataset obtained from NASA`s Measurement of Air Pollution by Satellites (MAPS) program. Fourteen simulations with a 3.75 horizontal resolution have been performed, including a base case and 13 sensitivity runs. The model reproduces many, but not all, of the major features of the MAPS dataset. Locations of peak CO mixing ratios associated with biomass burning as observed in the MAPS experiment are slightly farther south than the model result, indicating either greater horizontal transport than present in the model representation or a spatial difference between the location of modeled biomass fires and actual fires. The current version of GChM was shown to be relatively insensitive to the magnitude of the prescribed NO{sub x} and O{sub 3} global distributions and very insensitive to the depth of the mixed layer as parameterized in the model. Cloud convective transport was shown to play an important role in venting boundary layer CO to the free troposphere. This result agrees with prior meteorological analyses of the MAPS dataset that have-indirectly inferred the presence of convective activity through satellite-based information. Work is continuing to analyze the results of these simulations further and to perform more detailed comparisons between model results and MAPS data.

Easter, R.C.; Saylor, R.D.; Chapman, E.G.

1993-12-01T23:59:59.000Z

436

GALLIUM NITRIDE INTEGRATED GAS/TEMPERATURE SENSORS FOR FUEL CELL SYSTEM MONITORING FOR HYDROGEN AND CARBON MONOXIDE  

E-Print Network [OSTI]

on field effect devices using catalytic metal gates on silicon carbide substrates has been reviewed (Spetz-10%) of transition metals such as copper, silver, and chromium (Feinstein et al 1997 and Pyke 1993). High temperature. Introduction Gas sensing and analysis based on gas adsorption on a catalytic metal surface has been extensively

437

Atmospheric Trace Gases from the Carbon Dioxide Information Analysis Center (CDIAC)  

DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

CDIAC products are indexed and searchable through a customized interface powered by ORNL's Mercury search engine. Products include numeric data packages, publications, trend data, atlases, models, etc. and can be searched for by subject area, keywords, authors, product numbers, time periods, collection sites, spatial references, etc. Some of the collections may also be included in the CDIAC publication, Trends Online: A Compendium of Global Change Data. Most data sets, many with numerous data files, are free to download from CDIAC's ftp area. The collections under the CDIAC heading of Atmospheric Trace Gases include: Atmospheric Carbon Dioxide, Atmospheric Methane, Atmospheric Carbon Monoxide, Atmospheric Hydrogen, Isotopes in Greenhouse Gases, Radionuclides, Aerosols, and Other Trace Gases.

438

Carbon Cycle  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Carbon Cycle Carbon Cycle Latest Global Carbon Budget Estimates Including CDIAC Estimates Terrestrial Carbon Management Data Sets and Analyses Carbon Dioxide Emissions from Fossil-Fuel Consumption and Cement Manufacture, (2011) Annual Fossil-Fuel CO2 Emissions: Mass of Emissions Gridded by One Degree Latitude by One Degree Longitude (2012) Monthly Fossil-Fuel CO2 Emissions: Mass of Emissions Gridded by One Degree Latitude by One Degree Longitude (2012) Annual Fossil-Fuel CO2 Emissions: Global Stable Carbon Isotopic Signature (2012) Monthly Fossil-Fuel CO2 Emissions: Isomass (δ 13C) of Emissions Gridded by One Degree Latitude by One Degree Longitude (2012) AmeriFlux - Terrestrial Carbon Dioxide, Water Vapor, and Energy Balance Measurements Estimates of Monthly CO2 Emissions and Associated 13C/12C Values

439

Carbon Isotopes  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Atmospheric Trace Gases » Carbon Isotopes Atmospheric Trace Gases » Carbon Isotopes Carbon Isotopes Gateway Pages to Isotopes Data Modern Records of Carbon and Oxygen Isotopes in Atmospheric Carbon Dioxide and Carbon-13 in Methane 800,000 Deuterium Record and Shorter Records of Various Isotopic Species from Ice Cores Carbon-13 13C in CO Measurements from Niwot Ridge, Colorado and Montana de Oro, California (Tyler) 13C in CO2 NOAA/CMDL Flask Network (White and Vaughn) CSIRO GASLAB Flask Network (Allison, Francey, and Krummel) CSIRO in situ measurements at Cape Grim, Tasmania (Francey and Allison) Scripps Institution of Oceanography (Keeling et al.) 13C in CH4 NOAA/CMDL Flask Network (Miller and White) Northern & Southern Hemisphere Sites (Quay and Stutsman) Northern & Southern Hemisphere Sites (Stevens)

440

Nox reduction with CO over supported Pd catalysts under simulated post Euro-IV diesel exhaust conditions  

Science Journals Connector (OSTI)

The catalytic reduction of NOx with CO over Pd/Al2O3 and Pd/TiO2/Al2O3 under simulated post Euro-IV diesel exhaust conditions was studied. The catalytic activities obtained...2 loadings and total amounts of reduc...

Yinghua Li; Dae-Won Lee; Young-Chul Ko…

2008-12-01T23:59:59.000Z

Note: This page contains sample records for the topic "nox carbon monoxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Implications of Near-Term Coal Power Plant Retirement for SO2 and NOX and Life Cycle GHG Emissions  

Science Journals Connector (OSTI)

Implications of Near-Term Coal Power Plant Retirement for SO2 and NOX and Life Cycle GHG Emissions ... Life cycle GHG emissions were found to decrease by less than 4% in almost all scenarios modeled. ... Resulting changes in fuel use, life cycle greenhouse gas (GHG) emissions, and emissions of sulfur and nitrogen oxides are estimated. ...

Aranya Venkatesh; Paulina Jaramillo; W. Michael Griffin; H. Scott Matthews

2012-08-13T23:59:59.000Z

442

Flexible CHP System with Low NOx, CO, and VOC Emissions- Presentation by the Gas Technology Institute (GTI), June 2011  

Broader source: Energy.gov [DOE]

Presentation on Flexible CHP System with Low NOx, CO, and VOC Emissions, given by David Cygan of the Gas Technology Institute, at the U.S. DOE Industrial Distributed Energy Portfolio Review Meeting in Washington, D.C. on June 1-2, 2011.

443

Implications of near-term coal power plant retirement for SO2 and NOX, and life cycle GHG emissions  

E-Print Network [OSTI]

prices of electricity production Plant type Unit Price Nuclear ($/MWh) 16.51 Wind ($/MWh) 201 Hydro Top SO2 100 430 95 440 100 430 Top NOX 105 350 100 380 105 345 Small, inefficient 125 410 125 405 125) Manitoba Hydro Manitoba Hydro Undertaking # 57 http://www.pub.gov.mb.ca/exhibits/mh-83.pdf. (5) Sotkiewicz

Jaramillo, Paulina

444

Global partitioning of NOx sources using satellite observations: Relative roles of fossil fuel combustion, biomass burning and  

E-Print Network [OSTI]

combustion, biomass burning and soil emissions Lyatt Jaegle´ ,a Linda Steinberger,a Randall V. Martinbc anthropogenic emissions, mostly resulting from fossil fuel combustion and biomass burning, are superimposed-CHEM chemical transport model. Top-down NOx sources are partitioned among fuel combustion (fossil fuel

Lyatt Jaeglé

445

Field Demonstration of 0.2 Grams Per Horsepower-Hour (g/bhp-hr) Oxides of Nitrogen (NOx) Natural  

E-Print Network [OSTI]

: · Reducing health and environmental impacts from air pollution, and greenhouse gas emissions related pollution and greenhouse gas emissions beyond applicable standards, and that benefit natural gas ratepayers of nitrogen (NOx) emission standard of 0.20 g/bhp-hr for heavy duty engines to reduce levels of this critical

446

Integration of carbonate fuel cells with advanced coal gasification systems  

SciTech Connect (OSTI)

Carbonate fuel cells have attributes which make them ideally suited to operate on coal-derived fuel gas; they can convert the methane, hydrogen, and carbon monoxide present in coal derived fuel gas directly to electricity, are not subject to thermodynamic cycle limits as are heat engines, and operate at temperatures compatible with coal gasifiers. Some new opportunities for improved efficiency have been identified in integrated coal gasification/carbonate fuel cells which take advantage of low temperature catalytic coal gasification producing a methane-rich fuel gas, and the internal methane reforming capabilities of Energy Research Corporation`s carbonate fuel cells. By selecting the appropriate operating conditions and catalyst in the gasifier, methane formation is maximized to improve gasification efficiency and to take advantage of the heat management aspects of the internal reforming carbonate fuel cell. These advanced integrated gasification/carbonate fuel cell systems are projected to have better efficiencies than gasification/carbonate fuel cell systems employing conventional gasification, and also competing non-fuel cell systems. These improved efficiencies would be accompanied by a corresponding reduction in impact on the environment as well.

Steinfeld, G. [Energy Research Corp., Danbury, CT (United States); Meyers, S.J. [Fluor Daniel, Inc., Irvine, CA (United States); Hauserman, W.B. [North Dakota Univ., Grand Forks, ND (United States). Energy and Environmental Research Center

1992-12-01T23:59:59.000Z

447

Integration of carbonate fuel cells with advanced coal gasification systems  

SciTech Connect (OSTI)

Carbonate fuel cells have attributes which make them ideally suited to operate on coal-derived fuel gas; they can convert the methane, hydrogen, and carbon monoxide present in coal derived fuel gas directly to electricity, are not subject to thermodynamic cycle limits as are heat engines, and operate at temperatures compatible with coal gasifiers. Some new opportunities for improved efficiency have been identified in integrated coal gasification/carbonate fuel cells which take advantage of low temperature catalytic coal gasification producing a methane-rich fuel gas, and the internal methane reforming capabilities of Energy Research Corporation's carbonate fuel cells. By selecting the appropriate operating conditions and catalyst in the gasifier, methane formation is maximized to improve gasification efficiency and to take advantage of the heat management aspects of the internal reforming carbonate fuel cell. These advanced integrated gasification/carbonate fuel cell systems are projected to have better efficiencies than gasification/carbonate fuel cell systems employing conventional gasification, and also competing non-fuel cell systems. These improved efficiencies would be accompanied by a corresponding reduction in impact on the environment as well.

Steinfeld, G. (Energy Research Corp., Danbury, CT (United States)); Meyers, S.J. (Fluor Daniel, Inc., Irvine, CA (United States)); Hauserman, W.B. (North Dakota Univ., Grand Forks, ND (United States). Energy and Environmental Research Center)

1992-01-01T23:59:59.000Z

448

Effect of B20 and Low Aromatic Diesel on Transit Bus NOx Emissions Over Driving Cycles with a Range of Kinetic Intensity  

SciTech Connect (OSTI)

Oxides of nitrogen (NOx) emissions for transit buses for up to five different fuels and three standard transit duty cycles were compared to establish whether there is a real-world biodiesel NOx increase for transit bus duty cycles and engine calibrations. Six buses representing the majority of the current national transit fleet and including hybrid and selective catalyst reduction systems were tested on a heavy-duty chassis dynamometer with certification diesel, certification B20 blend, low aromatic (California Air Resources Board) diesel, low aromatic B20 blend, and B100 fuels over the Manhattan, Orange County and UDDS test cycles. Engine emissions certification level had the dominant effect on NOx; kinetic intensity was the secondary driving factor. The biodiesel effect on NOx emissions was not statistically significant for most buses and duty cycles for blends with certification diesel, except for a 2008 model year bus. CARB fuel had many more instances of a statistically significant effect of reducing NOx. SCR systems proved effective at reducing NOx to near the detection limit on all duty cycles and fuels, including B100. While offering a fuel economy benefit, a hybrid system significantly increased NOx emissions over a same year bus with a conventional drivetrain and the same engine.

Lammert, M. P.; McCormick, R. L.; Sindler, P.; Williams, A.

2012-10-01T23:59:59.000Z

449

NOx, SO{sub 3} in the spotlight at NETL's 2006 Environmental Controls conference  

SciTech Connect (OSTI)

As emissions caps drop, technological solutions must become increasingly effective and efficient. Researchers, equipment vendors, and plant operators are exploring alternatives to SCR and SNCR, with a view to reducing the overall costs of NOx reduction. They have also achieved 95% to 99% removal of SO{sub 3}, with no visible plume opacity. These topics were discussed at ECC 2006. The first conference session focussed on selective catalytic reduction (SCR) and selective non-catalytic reduction (SNCR) control of nitrogen oxide emissions; the second session addressed the related issue of reducing stack emissions and flue gas concentrations of sulfur trioxide. The article summarises many papers presented. Summaries and/or full versions of all the papers mentioned, and others, are posted at www.netl.doe.gov/publications/proceedings/06/ecc/index.html. 2 figs.

Mann, A.N.; Makovsky, L.E.; Sarkus, T.A. [Technology and Management Services Inc. (United States)

2007-02-15T23:59:59.000Z

450

Method for reducing NOx during combustion of coal in a burner  

DOE Patents [OSTI]

An organically complexed nanocatalyst composition is applied to or mixed with coal prior to or upon introducing the coal into a coal burner in order to catalyze the removal of coal nitrogen from the coal and its conversion into nitrogen gas prior to combustion of the coal. This process leads to reduced NOx production during coal combustion. The nanocatalyst compositions include a nanoparticle catalyst that is made using a dispersing agent that can bond with the catalyst atoms. The dispersing agent forms stable, dispersed, nano-sized catalyst particles. The catalyst composition can be formed as a stable suspension to facilitate storage, transportation and application of the catalyst nanoparticles to a coal material. The catalyst composition can be applied before or after pulverizing the coal material or it may be injected directly into the coal burner together with pulverized coal.

Zhou, Bing (Cranbury, NJ); Parasher, Sukesh (Lawrenceville, NJ); Hare, Jeffrey J. (Provo, UT); Harding, N. Stanley (North Salt Lake, UT); Black, Stephanie E. (Sandy, UT); Johnson, Kenneth R. (Highland, UT)

2008-04-15T23:59:59.000Z

451

Exhaust Gas Fuel Reforming of Diesel Fuel by Nonthermal Arc Discharge for NOx Trap Regeneration Application  

Science Journals Connector (OSTI)

Exhaust Gas Fuel Reforming of Diesel Fuel by Nonthermal Arc Discharge for NOx Trap Regeneration Application ... It has been demonstrated that low current arc discharges are highly nonhomogenous. ... In the second case, which corresponds to the most favorable one, assuming (i) a 100 kW car engine thermal power (i.e., 40 kW mechanical power), (ii) that the plasma will treat only a small fraction of the exhaust gas (typically 3.5%), (iii) that the plasma will operate under a cycling operating mode, and (iv) an 80% efficiency for the onboard production of electricity from the car engine, one can estimate that the electric power needed to run the plasma will be around 2.2% of the engine power only during 12 s every 11 km (6.8 miles), that is, 12 s every 6 min assuming a 110 km·h?1 (68 mph) average car velocity. ...

Alexandre Lebouvier; Franc?ois Fresnet; Fre?de?ric Fabry; Vale?rie Boch; Vandad Rohani; Franc?ois Cauneau; Laurent Fulcheri

2011-02-03T23:59:59.000Z

452

New CoO?SiO2-Sol Pillared Clays as Catalysts for NOx Conversion  

Science Journals Connector (OSTI)

For this purpose, codoped SiO2 sol PILC (CoSi?PILC) is prepared via an organic template route and the interlayer pillar structure is systematically investigated by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), X-ray absorption spectroscopy (XAS), and nitrogen adsorption isotherm measurement, along with a preliminary test on the de-NOx catalytic activity. ... The steady-state selective catalytic reduction of NO with CO over CoSi?PILC catalyst was carried out in an isothermal fixed-bed continuous flow quartz reactor (o.d. ... The elemental composition of CoSi?PILC was analyzed to estimate the pillar content of SiO2 and CoO. ...

Jin-Ho Choy; Hyun Jung; Yang-Su Han; Joo-Byoung Yoon; Yong-Gun Shul; Hyun-Jong Kim

2002-08-20T23:59:59.000Z

453

Carbon Nanotubes.  

E-Print Network [OSTI]

?? Carbon nanotubes have extraordinary mechanical, electrical, thermal andoptical properties. They are harder than diamond yet exible, have betterelectrical conductor than copper, but can also… (more)

Fredriksson, Tore

2014-01-01T23:59:59.000Z

454

MOBILE6 Vehicle Emission Modeling Software | Open Energy Information  

Open Energy Info (EERE)

MOBILE6 Vehicle Emission Modeling Software MOBILE6 Vehicle Emission Modeling Software Jump to: navigation, search Tool Summary Name: MOBILE6 Agency/Company /Organization: United States Environmental Protection Agency Sector: Energy Focus Area: Transportation Topics: GHG inventory Resource Type: Software/modeling tools User Interface: Desktop Application Website: www.epa.gov/oms/m6.htm Cost: Free References: http://www.epa.gov/oms/m6.htm MOBILE6 is an emission factor model for predicting gram per mile emissions of Hydrocarbons (HC), Carbon Monoxide (CO), Nitrogen Oxides (NOx), Carbon Dioxide (CO2), Particulate Matter (PM), and toxics from cars, trucks, and motorcycles under various conditions. MOBILE6 is an emission factor model for predicting gram per mile emissions of Hydrocarbons (HC), Carbon Monoxide (CO), Nitrogen Oxides (NOx), Carbon

455

Capturing carbon | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Capturing carbon Capturing carbon New technology enables molecular-level insight into carbon sequestration Carbon sequestration is a potential solution for reducing greenhouse...

456

Carbon dioxide adsorption and methanation on ruthenium  

SciTech Connect (OSTI)

The adsorption and methanation of carbon dioxide on a ruthenium-silica catalyst were studied using temperature-programmed desorption (TPD) and temperature-programmed reaction (TPR). Carbon dioxide adsorption was found to be activated; CO/sub 2/ adsorption increased significantly as the temperature increased from 298 to 435 K. During adsorption, some of the CO/sub 2/ dissociated to carbon monoxide and oxygen; upon hydrogen exposure at room temperature, the oxygen reacted to water. Methanation of adsorbed CO and of adsorbed CO/sub 2/, using TPR in flowing hydrogen, yielded a CH/sub 4/ peak with a peak temperature of 459 K for both adsorbates, indicating that both reactions follow the same mechanism after adsorption. This peak temperature did not change with initial surface coverage of CO, indicating that methanation is first order in CO coverage. The desorption and reaction spectra for Ru/SiO/sub 2/ were similar to those previously obtained for Ni/SiO/sub 2/, but both CO/sub 2/ formation and CH/sub 4/ formation proceeded faster on Ru. Also, the details of CO desorption and the changes in CO/sub 2/ and CO desorptions with initial coverage were different on the two metals. 5 figures, 3 tables.

Zagli, E.; Falconer, J.L.

1981-05-01T23:59:59.000Z

457

Carbon-based Fuel Cell  

SciTech Connect (OSTI)

The direct use of coal in the solid oxide fuel cell to generate electricity is an innovative concept for power generation. The C-fuel cell (carbon-based fuel cell) could offer significant advantages: (1) minimization of NOx emissions due to its operating temperature range of 700-1000 C, (2) high overall efficiency because of the direct conversion of coal to CO{sub 2}, and (3) the production of a nearly pure CO{sub 2} exhaust stream for the direct CO{sub 2} sequestration. The objective of this project is to determine the technical feasibility of using a highly active anode catalyst in a solid oxide fuel for the direct electrochemical oxidation of coal to produce electricity. Results of this study showed that the electric power generation from Ohio No 5 coal (Lower Kittanning) Seam, Mahoning County, is higher than those of coal gas and pure methane on a solid oxide fuel cell assembly with a promoted metal anode catalyst at 950 C. Further study is needed to test the long term activity, selectivity, and stability of anode catalysts.

Steven S. C. Chuang

2005-08-31T23:59:59.000Z

458

An Experimental Investigation of the Origin of Increased NOx Emissions When Fueling a Heavy-Duty Compression-Ignition Engine with Soy Biodiesel  

Broader source: Energy.gov [DOE]

Optical engine experiments suggest that near stoichiometric charge-gas mixtures in the standing premixed autoignition zone near flame lift-off length explains biodiesel NOx increase under all conditions

459

STRATEGIES AND TECHNOLOGY FOR MANAGING HIGH-CARBON ASH  

SciTech Connect (OSTI)

The overall objective of the present project is to identify and assess strategies and solutions for the management of industry problems related to carbon in ash. Specific research issues to be addressed include: (1) the effect of parent fuel selection on ash properties and adsorptivity, including a first ever examination of the air entrainment behavior of ashes from alternative (non-coal) fuels; (2) the effect of various low-NOx firing modes on ash properties and adsorptivity; and (3) the kinetics and mechanism of ash ozonation. This data will provide scientific and engineering support of the ongoing process development activities. During this fourth project period we completed the characterization of ozone-treated carbon surfaces and wrote a comprehensive report on the mechanism through which ozone suppresses the adsorption of concrete surfactants.

Robert Hurt; Eric Suuberg; John Veranth; Xu Chen

2003-05-20T23:59:59.000Z

460

STRATEGIES AND TECHNOLOGY FOR MANAGING HIGH-CARBON ASH  

SciTech Connect (OSTI)

The overall objective of the present project is to identify and assess strategies and solutions for the management of industry problems related to carbon in ash. Specific research issues to be addressed include: (1) the effect of parent fuel selection on ash properties and adsorptivity, including a first ever examination of the air entrainment behavior of ashes from alternative (non-coal) fuels; (2) the effect of various low-NOx firing modes on ash properties and adsorptivity; and (3) the kinetics and mechanism of ash ozonation. This data will provide scientific and engineering support of the ongoing process development activities. During this fourth project period we completed the characterization of ozone-treated carbon surfaces and wrote a comprehensive report on the mechanism through which ozone suppresses the adsorption of concrete surfactants.

Robert Hurt; Eric Suuberg; John Veranth; Xu Chen

2002-09-10T23:59:59.000Z

Note: This page contains sample records for the topic "nox carbon monoxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Development of a dry low-NOx gas turbine combustor for a natural-gas fueled 2MW co-generation system  

SciTech Connect (OSTI)

A dry low-NOx gas turbine combustor has been developed for natural-gas fueled co-generation systems in the power range of 1--4MW. The combustor. called the Double Swirler Combustor, uses the lean premixed combustion to reduce NOx emission. The combustor is characterized by two staged lean premixed combustion with two coaxial annular burners and a simple fuel control system without the complex variable geometry. Substantially low NOx level has been achieved to meet the strict NOx regulation to co-generation systems in Japan. High combustion efficiency has been obtained for a wide operating range. In 1994, Tokyo Gas and Ishikawajima-Harima Heavy Industries initiated a collaborative program to develop a natural-gas fueled low NOx gas turbine engine for new 2MW class co-generation system, named IM270. The Double Swirler Combustor, originally developed by Tokyo Gas, was introduced into the natural gas fueled version of the IM270. Engine test of the first production unit was successfully conducted to confirm substantially low NOx level of less than 15 ppm (O{sub 2} = 16%) with the output power of more than 2MW. Test for the durability and the reliability of the system is being conducted at Tokyo Gas Negishi LNG Terminal in Kanagawa, Japan and successful results have been so far obtained.

Mori, Masaaki; Sato, Hiroshi

1998-07-01T23:59:59.000Z

462

Evaluation of the Impacts of Biodiesel and Second Generation Biofuels on NOx Emissions for CARB Diesel Fuels  

Science Journals Connector (OSTI)

McCormick, R. L.; Graboski, M. S.; Alleman, T. L.; Herring, A. M.; Tyson, K. S.Impact of Biodiesel Source Material and Chemical Structure on Emissions of Criteria Pollutants from a Heavy-Duty Engine Environ. ... McCormick, Robert L.; Graboski, Michael S.; Alleman, Teresa L.; Herring, Andrew M.; Tyson, K. Shaine ... McCormick, R.; Alvarez, J.; Graboski, M.; Tyson, K.Fuel Additive and Blending Approaches to Reducing NOx Emissions from Biodiesel SAE Tech. ...

Maryam Hajbabaei; Kent C. Johnson; Robert A. Okamoto; Alexander Mitchell; Marcie Pullman; Thomas D. Durbin

2012-07-12T23:59:59.000Z

463

NOx, FINE PARTICLE AND TOXIC METAL EMISSIONS FROM THE COMBUSTION OF SEWAGE SLUDGE/COAL MIXTURES: A SYSTEMATIC ASSESSMENT  

SciTech Connect (OSTI)

This research project focuses on pollutants from the combustion of mixtures of dried municipal sewage sludge (MSS) and coal. The objective is to determine the relationship between (1) fraction sludge in the sludge/coal mixture, and (2) combustion conditions on (a) NOx concentrations in the exhaust, (b) the size segregated fine and ultra-fine particle composition in the exhaust, and (c) the partitioning of toxic metals between vapor and condenses phases, within the process. The proposed study will be conducted in concert with an existing ongoing research on toxic metal partitioning mechanisms for very well characterized pulverized coals alone. Both high NOx and low NOx combustion conditions will be investigated (unstaged and staged combustion). Tradeoffs between CO{sub 2} control, NO{sub x} control, and inorganic fine particle and toxic metal emissions will be determined. Previous research results have demonstrated that the inhalation of coal/MSS ash particles cause an increase in lung permeability than coal ash particles alone. Elemental analysis of the coal/MSS ash particles showed that Zn was more abundant in these ash particles than the ash particles of coal ash alone.

Jost O.L. Wendt

2003-01-31T23:59:59.000Z

464

Carbon Sequestration  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

David a. Lang David a. Lang Project Manager National Energy Technology Laboratory 626 Cochrans Mill Road P.O. Box 10940 Pittsburgh, PA 15236 412-386-4881 david.lang@netl.doe.gov andrew chizmeshya Arizona State University Center for Solid State Science Tempe, AZ 85287-1704 480-965-6072 chizmesh@asu.edu A Novel ApproAch to MiNerAl cArboNAtioN: eNhANciNg cArboNAtioN While AvoidiNg MiNerAl pretreAtMeNt process cost Background Carbonation of the widely occurring minerals of the olivine group, such as forsterite (Mg 2 SiO 4 ), is a potential large-scale sequestration process that converts CO 2 into the environmentally benign mineral magnesite (MgCO 3 ). Because the process is exothermic, it inherently offers low-cost potential. Enhancing carbonation reactivity is the key to economic viability. Previous

465

Carbon Nanotubes  

Science Journals Connector (OSTI)

A broad review of the structure and properties of carbon nanotubes is presented. Particular emphasis is given to ... dimensional density of states predicted for single-wall nanotubes of small diameter. The eviden...

M. S. Dresselhaus; G. Dresselhaus…

2000-01-01T23:59:59.000Z

466

Carbon Fiber  

ScienceCinema (OSTI)

Lee McGetrick leads ORNL's effort to produce light, durable carbon fiber at lower cost -- a key to improvements in manufacturing that will produce more fuel-efficient vehicles and other advances.

McGetrick, Lee

2014-07-23T23:59:59.000Z

467

Carbon Fiber  

SciTech Connect (OSTI)

Lee McGetrick leads ORNL's effort to produce light, durable carbon fiber at lower cost -- a key to improvements in manufacturing that will produce more fuel-efficient vehicles and other advances.

McGetrick, Lee

2014-04-17T23:59:59.000Z

468

NOx diesel exhaust treatment using a pulsed corona discharge: the pulse repetition rate effect  

Science Journals Connector (OSTI)

The pulsed corona offers real promise for degradation of pollutants in gas and water streams. This paper presents a study of NOx removal from diesel exhaust. Special emphasis is laid on the investigation of the dependence of the NO removal rate and efficiency on the pulse repetition rate (PRR). A nanosecond solid state power supply (45?kV, 60?ns, up to 1?kHz) was used for driving the corona reactor. A Mitsubishi 10?kW 3-cylinder diesel-generator engine with a total volume of 1300?cm3 was used as a source of exhaust gas. At an NO removal rate of 35% the NO removal efficiency was 53?g?kW?1h?1 for PRR = 500?Hz and the initial NO concentration was 375?ppm. A semi-empirical expression for the corona reactor removal efficiency related both to PRR and to the residence time is presented. The removal efficiency decreases with increasing PRR at constant flow rate or constant residence time. This expression demonstrates reasonable agreement between the calculation results and the experimental data.

Y Yankelevich; M Wolf; R Baksht; A Pokryvailo; J Vinogradov; B Rivin; E Sher

2007-01-01T23:59:59.000Z

469

Low NOx Burner Design and Analysis for Conceptual Design of Oxygen-Based PC Boiler  

SciTech Connect (OSTI)

The objective of the low NOx burner design and analysis task of the Conceptual Design of Oxygen-Based PC Boiler study is to optimize the burner design to ensure stable ignition, to provide safe operation, and to minimize pollutant formation. The burners were designed and analyzed using the Fluent computer program. Four burner designs were developed: (1) with no over-fire gas (OFG) and 65% flue gas recycle, (2) with 20% OFG and 65% flue gas recycle, (3) with no OFG and 56% flue gas recycle and (4) with 20% OFG and 56% flue gas recycle. A 3-D Fluent simulation was made of a single wall-fired burner and horizontal portion of the furnace from the wall to the center. Without primary gas swirl, coal burnout was relatively small, due to the low oxygen content of the primary gas stream. Consequently, the burners were modified to include primary gas swirl to bring the coal particles in contact with the secondary gas. An optimal primary gas swirl was chosen to achieve sufficient burnout.

Andrew Seltzer

2005-05-01T23:59:59.000Z

470

Growth direction of oblique angle electron beam deposited silicon monoxide thin films identified by optical second-harmonic generation  

SciTech Connect (OSTI)

Oblique angle deposited (OAD) silicon monoxide (SiO) thin films forming tilted columnar structures have been characterized by second-harmonic generation. It was found that OAD SiO leads to a rotationally anisotropic second-harmonic response, depending on the optical angle of incidence. A model for the observed dependence of the second-harmonic signal on optical angle of incidence allows extraction of the growth direction of OAD films. The optically determined growth directions show convincing agreement with cross-sectional scanning electron microscopy images. In addition to a powerful characterization tool, these results demonstrate the possibilities for designing nonlinear optical devices through SiO OAD.

Vejling Andersen, Søren; Lund Trolle, Mads; Pedersen, Kjeld [Department of Physics and Nanotechnology, Aalborg University, Skjernvej 4A, DK-9220 Aalborg Øst (Denmark)] [Department of Physics and Nanotechnology, Aalborg University, Skjernvej 4A, DK-9220 Aalborg Øst (Denmark)

2013-12-02T23:59:59.000Z

471

Low Carbon Fuel Standards  

E-Print Network [OSTI]

gas, or even coal with carbon capture and sequestration. Afuels that facilitate carbon capture and sequestration. Forenergy and could capture and sequester carbon emissions.

Sperling, Dan; Yeh, Sonia

2009-01-01T23:59:59.000Z

472

Delayed carbon sequestration and rising carbon prices  

Science Journals Connector (OSTI)

We set out a dynamic model to investigate optimal time paths of emissions, carbon stocks and carbon sequestration by land conversion, allowing for non-instantaneous carbon sequestration. Previous research in a dy...

Alejandro Caparrós

2009-10-01T23:59:59.000Z

473

Calculation of NOx Emission Reduction from Implementation of the 2000 IECC/IRC Conservation Code in Texas  

E-Print Network [OSTI]

building prototypes, which will be constructed to be representative of the new building construction in Texas. 12 The NAHB characteristics divided the state into east (E), and west (W) divisions: window-to-wall area E=15.28%, W=20.6%, glazing U.... Division (East and West Texas): From NAHB survey data. 17. AFUE (%),SEER and Water Heater Efficiency for 1999 standard and IECC 2000 house are 80%, 11 and 76%, respectively. Table 1: 2002 NOx emissions reductions from implementation of the 2000 IECC...

Turner, W. D.; Yazdani, B.; Im, P.; Verdict, M.; Bryant, J.; Fitzpatrick, T.; Haberl, J. S.; Culp, C.

2003-01-01T23:59:59.000Z

474

Intergrated Nox Emissions Reductions from Energy Efficiency and Renewable Energy (EE/RE) Programs across State Agencies in Texas  

E-Print Network [OSTI]

1 Calculation of Integrated NOx Emissions Reductions from Energy Efficiency and Renewable Energy (EE/RE) Programs across State Agencies in Texas Juan-Carlos Baltazar, Ph.D., P.E.,Jeff S. Haberl, Ph.D., P.E., and Bahman Yazdani, P... on Environmental Quality (TCEQ) from the state-wide energy efficiency and renewable energy programs. These programs include: the impact of code-complaint construction, the Texas Public Utility Commission (PUC), the energy efficiency programs managed by the Texas...

Baltazar, J.C.; Haberl, J.; Yazdani, B.

2014-01-01T23:59:59.000Z

475

Impact of the Driving Cycle on the NOx and Particulate Matter Exhaust Emissions of Diesel Passenger Cars  

Science Journals Connector (OSTI)

Impact of the Driving Cycle on the NOx and Particulate Matter Exhaust Emissions of Diesel Passenger Cars ... The driving cycles used are the New European Driving Cycle (NEDC), the 11 and 15 modes Japanese cycles, and three U.S. driving cycles: Federal Test Procedure (FTP-75), US06, and Highway. ... In general, we can state that a reduction in compression ratio in combination with an advanced boosting system and a fast response of the EGR system with advanced EGR cooling leads to a reduction of the emission level. ...

Efthimios Zervas; George Bikas

2008-02-19T23:59:59.000Z

476

Development of a Low NOx Medium sized Industrial Gas Turbine Operating on Hydrogen-Rich Renewable and Opportunity Fuels  

SciTech Connect (OSTI)

This report presents the accomplishments at the completion of the DOE sponsored project (Contract # DE-FC26-09NT05873) undertaken by Solar Turbines Incorporated. The objective of this 54-month project was to develop a low NOx combustion system for a medium sized industrial gas turbine engine operating on Hydrogen-rich renewable and opportunity Fuels. The work in this project was focused on development of a combustion system sized for 15MW Titan 130 gas turbine engine based on design analysis and rig test results. Although detailed engine evaluation of the complete system is required prior to commercial application, those tasks were beyond the scope of this DOE sponsored project. The project tasks were organized in three stages, Stages 2 through 4. In Stage 2 of this project, Solar Turbines Incorporated characterized the low emission capability of current Titan 130 SoLoNOx fuel injector while operating on a matrix of fuel blends with varying Hydrogen concentration. The mapping in this phase was performed on a fuel injector designed for natural gas operation. Favorable test results were obtained in this phase on emissions and operability. However, the resulting fuel supply pressure needed to operate the engine with the lower Wobbe Index opportunity fuels would require additional gas compression, resulting in parasitic load and reduced thermal efficiency. In Stage 3, Solar characterized the pressure loss in the fuel injector and developed modifications to the fuel injection system through detailed network analysis. In this modification, only the fuel delivery flowpath was modified and the air-side of the injector and the premixing passages were not altered. The modified injector was fabricated and tested and verified to produce similar operability and emissions as the Stage 2 results. In parallel, Solar also fabricated a dual fuel capable injector with the same air-side flowpath to improve commercialization potential. This injector was also test verified to produce 15-ppm NOx capability on high Hydrogen fuels. In Stage 4, Solar fabricated a complete set of injectors and a combustor liner to test the system capability in a full-scale atmospheric rig. Extensive high-pressure single injector rig test results show that 15-ppm NOx guarantee is achievable from 50% to 100% Load with fuel blends containing up to 65% Hydrogen. Because of safety limitations in Solar Test Facility, the atmospheric rig tests were limited to methane-based fuel blends. Further work to validate the durability and installed engine capability would require long-term engine field test.

Srinivasan, Ram

2013-07-31T23:59:59.000Z

477

Carbon Additionality: Discussion Paper  

E-Print Network [OSTI]

ahead, and identifying the carbon pools and other green house gas emissions sources and savings coveredCarbon Additionality: A review Discussion Paper Gregory Valatin November 2009 Forest Research. Voluntary Carbon Standards American Carbon Registry Forest Carbon Project Standard (ACRFCPS) 27 Carbon

478

Establishing Policy Relevant Background (PRB) Ozone Concentrations in the United States  

Science Journals Connector (OSTI)

National Oceanic and Atmospheric Administration, Boulder, Colorado ... Processes that contribute to PRB ozone concentrations include photochemistry associated with natural emissions of volatile organic compounds (VOCs), nitrogen oxides (NOx), and carbon monoxide (CO) from sources such as biogenic emissions (not including agricultural activities), wildfires, lightning, the long-range transport of ozone and its precursors from outside of North America, and stratospheric-tropospheric exchange (STE) of ozone. ... Models generally find little ozone production in wildfire plumes for short aging times (days) because NOx emissions are low and conversion to peroxyacetylnitrate (PAN) is rapid. ...

Elena C. McDonald-Buller; David T Allen; Nancy Brown; Daniel J. Jacob; Daniel Jaffe; Charles E. Kolb; Allen S. Lefohn; Samuel Oltmans; David D. Parrish; Greg Yarwood; Lin Zhang

2011-10-10T23:59:59.000Z

479

Analysis of Strategies for Reducing Multiple Emissions from Electric Power Plants: SO2, Nox, CO2  

Reports and Publications (EIA)

This report responds to a request received from Senator David McIntosh on June 29, 2000 to analyze the impacts on energy consumers and producers of coordinated strategies to reduce emissions of sulfur dioxide, nitrogen oxides, and carbon dioxide at U.S. power plants.

2001-01-01T23:59:59.000Z

480

Utilization of low NOx coal combustion by-products. Quarterly report, July 1--September 30, 1996  

SciTech Connect (OSTI)

The objective of this project was to commercialize fly ash beneficiation at various facilities around the country. The paper describes laboratory characterization of fly ash samples, pilot plant testing, product testing, and market and economic analyses. Products include concrete, concrete blocks and bricks, plastic fillers, activated carbon, and metal matrix composites.

NONE

1996-12-31T23:59:59.000Z

Note: This page contains sample records for the topic "nox carbon monoxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

Carbon Sequestration  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Technology Technology Laboratory 626 Cochrans Mill Road P.O. Box 10940 Pittsburgh, PA 15236-0940 412-386-4966 jose.figueroa@netl.doe.gov Kevin o'Brien Principal Investigator SRI International Materials Research Laboratory 333 Ravenswood Avenue Menlo Park, AK 94025 650-859-3528 kevin.obrien@sri.com Fabrication and Scale-Up oF polybenzimidazole - baSed membrane SyStem For pre - combUStion captUre oF carbon dioxide Background In order to effectively sequester carbon dioxide (CO 2 ) from a gasification plant, there must be an economically viable method for removing the CO 2 from other gases. While CO 2 separation technologies currently exist, their effectiveness is limited. Amine-based separation technologies work only at low temperatures, while pressure-swing absorption and cryogenic distillation consume significantly

482

Carbon Sequestration  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

andrea Mcnemar andrea Mcnemar National Energy Technology Laboratory 3610 Collins Ferry Road P.O. Box 880 Morgantown, WV 26507-0880 304-285-2024 andrea.mcnemar@netl.doe.gov Gregory J. Elbring Principal Investigator Sandia National Laboratory P.O. Box 5800 Albuquerque, NM 87185 505-844-4904 gjelbri@sandia.gov GeoloGic SequeStration of carbon DioxiDe in a DepleteD oil reServoir: a comprehenSive moDelinG anD Site monitorinG project Background The use of carbon dioxide (CO 2 ) to enhance oil recovery (EOR) is a familiar and frequently used technique in the United States. The oil and gas industry has significant experience with well drilling and injecting CO 2 into oil-bearing formations to enhance production. While using similar techniques as in oil production, this sequestration field

483

Understanding the Synergistic Catalytic Effect between La2O3 and CaO for the CH4 Lean De-NOx Reaction:? Kinetic and Mechanistic Studies  

Science Journals Connector (OSTI)

Department of Chemistry, Heterogeneous Catalysis Laboratory, University of Cyprus, P.O. ... 3-5 Methane is of particular interest as a reductant hydrocarbon species because of the large availability of natural gas, the use of the latter at gas-fired power plants (main stationary NOx polluting source), and the potential to be considered as an alternative to NH3 reductant used in industrial practice (NH3?SCR technology), which faces various problems. ... However, the likelihood for the presence of inactive but exchangeable NOx species with gaseous 15NO cannot be excluded. ...

T. Anastasiadou; L. A. Loukatzikou; C. N. Costa; A. M. Efstathiou

2005-06-28T23:59:59.000Z

484

Analysis of different control strategies for the simultaneous reduction of CO2 and NOx emissions of a diesel hybrid passenger car  

Science Journals Connector (OSTI)

Different control strategies for a diesel parallel hybrid passenger car were evaluated through numerical simulations. Two different control strategies were analysed: the first focused on fuel consumption minimisation, the second on NOx emissions cuts. Each of these goals was addressed through two different methodologies, the first based on a group of heuristic laws, the second focused on the instantaneous minimisation of a cost function that takes into account both the fuel and battery energies. A first assessment of the potential of a diesel hybrid passenger car as far as fuel consumption and NOx emissions reductions are concerned was obtained.

Federico Millo; Carlo V. Ferraro; Luciano Rolando

2012-01-01T23:59:59.000Z

485

Carbon Trading, Carbon Taxes and Social Discounting  

E-Print Network [OSTI]

Carbon Trading, Carbon Taxes and Social Discounting Elisa Belfiori belf0018@umn.edu University of Minnesota Abstract This paper considers the optimal design of policies to carbon emissions in an economy, such as price or quantity controls on the net emissions of carbon, are insufficient to achieve the social

Weiblen, George D

486

Gasification behavior of carbon residue in bed solids of black liquor gasifier  

SciTech Connect (OSTI)

Steam gasification of carbon residue in bed solids of a low-temperature black liquor gasifier was studied using a thermogravimetric system at 3 bar. Complete gasification of the carbon residue, which remained unreactive at 600 C, was achieved in about 10 min as the temperature increased to 800 C. The rate of gasification and its temperature dependence were evaluated from the non-isothermal experiment results. Effects of particle size and adding H{sub 2} and CO to the gasification agent were also studied. The rate of steam gasification could be taken as zero order in carbon until 80% of carbon was gasified, and for the rest of the gasification process the rate appeared to be first order in carbon. The maximum rate of carbon conversion was around 0.003/s and the activation energy was estimated to be in the range of 230-300 kJ/mol. The particle size did not show significant effect on the rate of gasification. Hydrogen and carbon monoxide appeared to retard the onset of the gasification process. (author)

Preto, Fernando; Zhang, Xiaojie (Frank); Wang, Jinsheng [CANMET Energy Technology Centre, Natural Resources (Canada)

2008-07-15T23:59:59.000Z

487

Incorporation of catalytic dehydrogenation into Fischer-Tropsch synthesis to lower carbon dioxide emissions  

DOE Patents [OSTI]

A method for producing liquid fuels includes the steps of gasifying a starting material selected from a group consisting of coal, biomass, carbon nanotubes and mixtures thereof to produce a syngas, subjecting that syngas to Fischer-Tropsch synthesis (FTS) to produce a hyrdrocarbon product stream, separating that hydrocarbon product stream into C1-C4 hydrocarbons and C5+ hydrocarbons to be used as liquid fuels and subjecting the C1-C4 hydrocarbons to catalytic dehydrogenation (CDH) to produce hydrogen and carbon nanotubes. The hydrogen produced by CDH is recycled to be mixed with the syngas incident to the FTS reactor in order to raise the hydrogen to carbon monoxide ratio of the syngas to values of 2 or higher, which is required to produce liquid hydrocarbon fuels. This is accomplished with little or no production of carbon dioxide, a greenhouse gas. The carbon is captured in the form of a potentially valuable by-product, multi-walled carbon nanotubes (MWNT), while huge emissions of carbon dioxide are avoided and very large quantities of water employed for the water-gas shift in traditional FTS systems are saved.

Huffman, Gerald P

2012-09-18T23:59:59.000Z

488

Carbon Fiber Consortium | Partnerships | ORNL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Carbon Fiber Consortium SHARE Carbon Fiber Consortium Oak Ridge Carbon Fiber Composites Consortium The Oak Ridge Carbon Fiber Composites Consortium was established in 2011 to...

489

JV Task 117 - Impact of Lignite Properties on Powerspan's NOx Oxidation System  

SciTech Connect (OSTI)

Powerspan's multipollutant control process called electrocatalytic oxidation (ECO) technology is designed to simultaneously remove SO{sub 2}, NO{sub x}, PM{sub 2.5}, acid gases (such as hydrogen fluoride [HF], hydrochloric acid [HCl], and sulfur trioxide [SO{sub 3}]), Hg, and other metals from the flue gas of coal-fired power plants. The core of this technology is a dielectric barrier discharge reactor composed of cylindrical quartz electrodes residing in metal tubes. Electrical discharge through the flue gas, passing between the electrode and the tube, produces reactive O and OH radicals. The O and OH radicals react with flue gas components to oxidize NO to NO{sub 2} and HNO{sub 3} and a small portion of the SO{sub 2} to SO{sub 3} and H{sub 2}SO{sub 4}. The oxidized compounds are subsequently removed in a downstream scrubber and wet electrostatic precipitator. A challenging characteristic of selected North Dakota lignites is their high sodium content. During high-sodium lignite combustion and gas cooling, the sodium vaporizes and condenses to produce sodium- and sulfur-rich aerosols. Based on past work, it was hypothesized that the sodium aerosols would deposit on and react with the silica electrodes and react with the silica electrodes, resulting in the formation of sodium silicate. The deposit and reacted surface layer would then electrically alter the electrode, thus impacting its dielectric properties and NO{sub x} conversion capability. The purpose of this project was to determine the impact of lignite-derived flue gas containing sodium aerosols on Powerspan's dielectric barrier discharge (DBD) reactor with specific focus on the interaction with the quartz electrodes. Partners in the project were Minnkota Power Cooperative; Basin Electric Power Cooperative; Montana Dakota Utilities Co.; Minnesota Power; the North Dakota Industrial Commission, the Lignite Energy Council, and the Lignite Research Council; the Energy & Environmental Research Center (EERC); and the U.S. Department of Energy. An electrocatalytic oxidation (ECO) reactor slipstream system was designed by Powerspan and the EERC. The slipstream system was installed by the EERC at Minnkota Power Cooperative's Milton R. Young Station Unit 1 downstream of the electrostatic precipitator where the flue gas temperature ranged from 300 to 350 F. The system was commissioned on July 3, 2007, operated for 107 days, and then winterized upon completion of the testing campaign. Operational performance of the system was monitored, and data were archived for postprocessing. A pair of electrodes were extracted and replaced on a biweekly basis. Each pair of electrodes was shipped to Powerspan to determine NO conversion efficiency in Powerspan's laboratory reactor. Tested electrodes were then shipped to the EERC for scanning electron microscopy (SEM) and x-ray microanalysis. Measurement of NO{sub x} conversion online in operating the slipstream system was not possible because the nitric and sulfuric acid production by the DBD reactor results in conditioning corrosion challenges in the sample extraction system and NO measurement technologies. The operational observations, performance results, and lab testing showed that the system was adversely affected by accumulation of the aerosol materials on the electrode. NO{sub x} conversion by ash-covered electrodes was significantly reduced; however, with electrodes that were rinsed with water, the NOx conversion efficiency recovered to nearly that of a new electrode. In addition, the visual appearance of the electrode after washing did not show evidence of a cloudy reacted surface but appeared similar to an unexposed electrode. Examination of the electrodes using SEM x-ray microanalysis showed significant elemental sodium, sulfur, calcium, potassium, and silica in the ash coating the electrodes. There was no evidence of the reaction of the sodium with the silica electrodes to produce sodium silicate layers. All SEM images showed a clearly marked boundary between the ash and the silica. Sodium and sulfur are the main culprits in the

Scott Tolbert; Steven Benson

2008-02-29T23:59:59.000Z

490

Near-Zero Emissions Oxy-Combustion Flue Gas Purification Task 2: SOx/Nox/Hg Removal for High Sulfur Coal  

SciTech Connect (OSTI)

The goal of this project is to develop a near-zero emissions flue gas purification technology for existing PC (pulverized coal) power plants that are retrofitted with oxy-combustion technology. The objective of Task 2 of this project was to evaluate an alternative method of SOx, NOx and Hg removal from flue gas produced by burning high sulfur coal in oxy-combustion power plants. The goal of the program was not only to investigate a new method of flue gas purification but also to produce useful acid byproduct streams as an alternative to using a traditional FGD and SCR for flue gas processing. During the project two main constraints were identified that limit the ability of the process to achieve project goals. 1) Due to boiler island corrosion issues >60% of the sulfur must be removed in the boiler island with the use of an FGD. 2) A suitable method could not be found to remove NOx from the concentrated sulfuric acid product, which limits sale-ability of the acid, as well as the NOx removal efficiency of the process. Given the complexity and safety issues inherent in the cycle it is concluded that the acid product would not be directly saleable and, in this case, other flue gas purification schemes are better suited for SOx/NOx/Hg control when burning high sulfur coal, e.g. this project's Task 3 process or a traditional FGD and SCR.

Nick Degenstein; Minish Shah; Doughlas Louie

2012-05-01T23:59:59.000Z

491

Effects of diesel-water emulsion combustion on diesel engine NOx emissions. Final report, 1 January 1998--1 May 1999  

SciTech Connect (OSTI)

This study examines the effects of combusting a mixture of diesel fuel, water, and surfactant on the nitrogen oxides (NOx) emissions from a compression ignition diesel engine. Extensive previous research in the literature has attributed the observed reduction of nitrogen oxide emissions to a suppression of flame temperature due to quenching effects from the water, thereby reducing thermal NOx formation. The report highlights the relevant theory, operation, and design parameters of diesel internal combustion engines. Experimental procedures conducted using a Detroit Diesel 4-cylinder diesel engine are discussed. Results from testing diesel fuel with varying ratios of water balanced with a surfactant to stabilize the emulsion are presented and discussed. The data shows significant NOx emission reduction with up to 45 percent water, by volume, in the fuel. These results are correlated with thermodynamic first law and equilibrium combustion products analyses to estimate the adiabatic flame temperature of the standard fuel and fuel-water emulsion cases. Results indicate that thermal NOx is indeed reduced by quenching and flame temperature suppression, confirming reports in the literature. Recommendations are given for further studies, including improving the fuel-water emulsion and considerations for long-term testing.

Canfield, A.C.

1999-05-01T23:59:59.000Z

492

Carbon Ionic Conductors for use in Novel Carbon-Ion Fuel Cells  

SciTech Connect (OSTI)

Carbon-consuming fuel cells have many potential advantages, including increased efficiency and reduced pollution in power generation from coal. A large amount of work has already been done on coal fuel cells that utilize yttria-stabilized zirconium carbide as an oxygen-ion superionic membrane material. But high-temperature fuel cells utilizing yttria-stabilized zirconium require partial combustion of coal to carbon monoxide before final oxidation to carbon dioxide occurs via utilization of the oxygen- ion zirconia membrane. A carbon-ion superionic membrane material would enable an entirely new class of carbon fuel cell to be developed, one that would use coal directly as the fuel source, without any intervening combustion process. However, a superionic membrane material for carbon ions has not yet been found. Because no partial combustion of coal would be required, a carbon-ion superionic conductor would allow the direct conversion of coal to electricity and pure CO{sub 2} without the formation of gaseous pollutants. The objective of this research was to investigate ionic lanthanide carbides, which have an unusually high carbon-bond ionicity as potential superionic carbide-ion conductors. A first step in this process is the stabilization of these carbides in the cubic structure, and this stabilization has been achieved via the preparation of pseudobinary lanthanide carbides. The diffusion rates of carbon have been measured in these carbides as stabilized to preserve the high temperature cubic structure down to room temperature. To prepare these new compounds and measure these diffusion rates, a novel, oxide-based preparation method and a new C{sup 13}/C{sup 12} diffusion technique have been developed. The carbon diffusion rates in La{sup 0.5}Er{sup 0.5}C{sub 2}, Ce{sup 0.5}Er{sup 0.5}C{sub 2}, and La{sup 0.5}Y{sup 0.5}C{sub 2}, and Ce{sup 0.5}Tm0.5C{sub 2} modified by the addition of 5 wt %Be{sub 2}C, have been determined at temperatures from 850 C to 1150 C. The resulting diffusion constants as measured were all less than 10{sup -11} cm{sup 2}/sec, and therefore these compounds are not superionic. However, there remain a large number of potentially superionic pseudobinary lanthanide compounds and a number of alternate ionic carbides which might act as dopants to produce vacancies on the carbon-ion sublattice and thereby increase carbon-ion diffusion rates. The discovery of a superionic carbon conductor would usher in a truly revolutionary new coal technology, and could dramatically improve the way in which we generate electricity from coal. The work completed to date is a promising first step towards this end.

Franklin H. Cocks; W. Neal Simmons; Paul A. Klenk

2005-11-01T23:59:59.000Z

493

Carbon Sequestration Project Portfolio  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Home > Technologies > Carbon Storage > Reference Shelf > Project Portfolio Home > Technologies > Carbon Storage > Reference Shelf > Project Portfolio Carbon Storage 2011 Carbon Storage Project Portfolio Table of Contents CARBON STORAGE OVERVIEW Carbon Storage Program Contacts [PDF-26KB] Carbon Storage Projects National Map [PDF-169KB] State Projects Summary Table [PDF-39KB] Carbon Storage Program Structure [PDF-181KB] Selected Carbon Sequestration Program Papers and Publications The U.S. Department of Energy's R&D Program to Reduce Greenhouse Gas Emissions Through Beneficial Uses of Carbon Dioxide (2011) [PDF-3.3MB] Greenhouse Gas Science and Technology Carbon Capture and Sequestration: The U.S. Department of Energy's R&D Efforts to Characterize Opportunities for Deep Geologic Storage of Carbon Dioxide in Offshore Resources (2011) [PDF-445KB]

494

CALIFORNIA CARBON SEQUESTRATION THROUGH  

E-Print Network [OSTI]

CALIFORNIA ENERGY COMMISSION CARBON SEQUESTRATION THROUGH CHANGES IN LAND USE IN WASHINGTON. Carbon Sequestration Through Changes in Land Use in Washington: Costs and Opportunities