National Library of Energy BETA

Sample records for nox burners ln

  1. Ultra-Low NOx Premixed Industrial Burner | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Ultra-Low NOx Premixed Industrial Burner Ultra-Low NOx Premixed Industrial Burner Reduction of Burner NOx Production with Premixed Combustion Industries that are dependant on combustion processes are faced with more stringent environmental regulations to reduce NOx emissions. Some states require NOx emissions reductions as great as 90% for chemical and refining industries. The recently developed M-PAKT(tm) Ultra-Low NOx Burner uses lean premixed combustion gases and low swirl flow of combustion

  2. Enhanced Combustion Low NOx Pulverized Coal Burner

    SciTech Connect (OSTI)

    Ray Chamberland; Aku Raino; David Towle

    2006-09-30

    For more than two decades, ALSTOM Power Inc. (ALSTOM) has developed a range of low cost, in-furnace technologies for NOx emissions control for the domestic U.S. pulverized coal fired boiler market. This includes ALSTOM's internally developed TFS 2000 firing system, and various enhancements to it developed in concert with the U.S. Department of Energy (DOE). As of 2004, more than 200 units representing approximately 75,000 MWe of domestic coal fired capacity have been retrofit with ALSTOM low NOx technology. Best of class emissions range from 0.18 lb/MMBtu for bituminous coals to 0.10 lb/MMBtu for subbituminous coals, with typical levels at 0.24 lb/MMBtu and 0.13 lb/MMBtu, respectively. Despite these gains, NOx emissions limits in the U.S. continue to ratchet down for new and existing (retrofit) boiler equipment. If enacted, proposed Clear Skies legislation will, by 2008, require an average, effective, domestic NOx emissions rate of 0.16 lb/MMBtu, which number will be reduced to 0.13 lb/MMBtu by 2018. Such levels represent a 60% and 67% reduction, respectively, from the effective 2000 level of 0.40 lb/MMBtu. Low cost solutions to meet such regulations, and in particular those that can avoid the need for a costly selective catalytic reduction system (SCR), provide a strong incentive to continue to improve low NOx firing system technology to meet current and anticipated NOx control regulations. In light of these needs, ALSTOM, in cooperation with the DOE, is developing an enhanced combustion, low NOx pulverized coal burner which, when integrated with ALSTOM's state-of-the-art, globally air staged low NOx firing systems, will provide a means to achieve less than 0.15 lb/MMBtu NOx at less than 3/4 the cost of an SCR with low to no impact on balance of plant issues when firing a high volatile bituminous coal. Such coals can be more economic to fire than subbituminous or Powder River Basin (PRB) coals, but are more problematic from a NOx control standpoint as existing firing system technologies do not provide a means to meet current or anticipated regulations absent the use of an SCR. The DOE/ALSTOM program performed large pilot scale combustion testing in ALSTOM's Industrial Scale Burner Facility (ISBF) at its U.S. Power Plant Laboratories facility in Windsor, Connecticut. During this work, the near-field combustion environment was optimized to maximize NOx reduction while minimizing the impact on unburned carbon in ash, slagging and fouling, corrosion, and flame stability/turn-down under globally reducing conditions. Initially, ALSTOM utilized computational fluid dynamic modeling to evaluate a series of burner and/or near field stoichiometry controls in order to screen promising design concepts in advance of the large pilot scale testing. The third and final test, to be executed, will utilize several variants of the best nozzle tip configuration and compare performance with 3 different coals. The fuels to be tested will cover a wide range of coals commonly fired at US utilities. The completion of this work will provide sufficient data to allow ALSTOM to design, construct, and demonstrate a commercial version of an enhanced combustion low NOx pulverized coal burner. A preliminary cost/performance analysis of the developed enhanced combustion low NOx burner applied to ALSTOM's state-of-the-art TFS 2000 firing system was performed to show that the burner enhancements is a cost effective means to reduce NOx.

  3. Enhanced Combustion Low NOx Pulverized Coal Burner

    SciTech Connect (OSTI)

    David Towle; Richard Donais; Todd Hellewell; Robert Lewis; Robert Schrecengost

    2007-06-30

    For more than two decades, Alstom Power Inc. (Alstom) has developed a range of low cost, infurnace technologies for NOx emissions control for the domestic U.S. pulverized coal fired boiler market. This includes Alstom's internally developed TFS 2000{trademark} firing system, and various enhancements to it developed in concert with the U.S. Department of Energy. As of the date of this report, more than 270 units representing approximately 80,000 MWe of domestic coal fired capacity have been retrofit with Alstom low NOx technology. Best of class emissions range from 0.18 lb/MMBtu for bituminous coal to 0.10 lb/MMBtu for subbituminous coal, with typical levels at 0.24 lb/MMBtu and 0.13 lb/MMBtu, respectively. Despite these gains, NOx emissions limits in the U.S. continue to ratchet down for new and existing boiler equipment. On March 10, 2005, the Environmental Protection Agency (EPA) announced the Clean Air Interstate Rule (CAIR). CAIR requires 25 Eastern states to reduce NOx emissions from the power generation sector by 1.7 million tons in 2009 and 2.0 million tons by 2015. Low cost solutions to meet such regulations, and in particular those that can avoid the need for a costly selective catalytic reduction system (SCR), provide a strong incentive to continue to improve low NOx firing system technology to meet current and anticipated NOx control regulations. The overall objective of the work is to develop an enhanced combustion, low NOx pulverized coal burner, which, when integrated with Alstom's state-of-the-art, globally air staged low NOx firing systems will provide a means to achieve: Less than 0.15 lb/MMBtu NOx emissions when firing a high volatile Eastern or Western bituminous coal, Less than 0.10 lb/MMBtu NOx emissions when firing a subbituminous coal, NOx reduction costs at least 25% lower than the costs of an SCR, Validation of the NOx control technology developed through large (15 MWt) pilot scale demonstration, and Documentation required for economic evaluation and commercial application. During the project performance period, Alstom performed computational fluid dynamics (CFD) modeling and large pilot scale combustion testing in its Industrial Scale Burner Facility (ISBF) at its U.S. Power Plant Laboratories facility in Windsor, Connecticut in support of these objectives. The NOx reduction approach was to optimize near-field combustion to ensure that minimum NOx emissions are achieved with minimal impact on unburned carbon in ash, slagging and fouling, corrosion, and flame stability/turn-down. Several iterations of CFD and combustion testing on a Midwest coal led to an optimized design, which was extensively combustion tested on a range of coals. The data from these tests were then used to validate system costs and benefits versus SCR. Three coals were evaluated during the bench-scale and large pilot-scale testing tasks. The three coals ranged from a very reactive subbituminous coal to a moderately reactive Western bituminous coal to a much less reactive Midwest bituminous coal. Bench-scale testing was comprised of standard ASTM properties evaluation, plus more detailed characterization of fuel properties through drop tube furnace testing and thermogravimetric analysis. Bench-scale characterization of the three test coals showed that both NOx emissions and combustion performance are a strong function of coal properties. The more reactive coals evolved more of their fuel bound nitrogen in the substoichiometric main burner zone than less reactive coal, resulting in the potential for lower NOx emissions. From a combustion point of view, the more reactive coals also showed lower carbon in ash and CO values than the less reactive coal at any given main burner zone stoichiometry. According to bench-scale results, the subbituminous coal was found to be the most amenable to both low NOx, and acceptably low combustibles in the flue gas, in an air staged low NOx system. The Midwest bituminous coal, by contrast, was predicted to be the most challenging of the three coals, with the Western bituminous coal predicted to beh

  4. OPTIMIZATION OF COAL PARTICLE FLOW PATTERNS IN LOW NOX BURNERS

    SciTech Connect (OSTI)

    Jost O.L. Wendt; Gregory E. Ogden; Jennifer Sinclair; Stephanus Budilarto

    2001-09-04

    It is well understood that the stability of axial diffusion flames is dependent on the mixing behavior of the fuel and combustion air streams. Combustion aerodynamic texts typically describe flame stability and transitions from laminar diffusion flames to fully developed turbulent flames as a function of increasing jet velocity. Turbulent diffusion flame stability is greatly influenced by recirculation eddies that transport hot combustion gases back to the burner nozzle. This recirculation enhances mixing and heats the incoming gas streams. Models describing these recirculation eddies utilize conservation of momentum and mass assumptions. Increasing the mass flow rate of either fuel or combustion air increases both the jet velocity and momentum for a fixed burner configuration. Thus, differentiating between gas velocity and momentum is important when evaluating flame stability under various operating conditions. The research efforts described herein are part of an ongoing project directed at evaluating the effect of flame aerodynamics on NO{sub x} emissions from coal fired burners in a systematic manner. This research includes both experimental and modeling efforts being performed at the University of Arizona in collaboration with Purdue University. The objective of this effort is to develop rational design tools for optimizing low NO{sub x} burners. Experimental studies include both cold-and hot-flow evaluations of the following parameters: primary and secondary inlet air velocity, coal concentration in the primary air, coal particle size distribution and flame holder geometry. Hot-flow experiments will also evaluate the effect of wall temperature on burner performance.

  5. DEVELOPMENT AND DEMONSTRATION OF NOVEL LOW-NOx BURNERS IN THE STEEL INDUSTRY

    SciTech Connect (OSTI)

    Cygan, David

    2006-12-28

    Gas Technology Institute (GTI), together with Hamworthy Peabody Combustion Incorporated (formerly Peabody Engineering Corporation), the University of Utah, and Far West Electrochemical have developed and demonstrated an innovative combustion system suitable for natural gas and coke-oven gas firing within the steel industry. The combustion system is a simple, low-cost, energy-efficient burner that can reduce NOx by more than 75%. The U.S. steel industry needs to address NOx control at its steelmaking facilities. A significant part of NOx emissions comes from gas-fired boilers. In steel plants, byproduct gases blast furnace gas (BFG) and coke-oven gas (COG) are widely used together with natural gas to fire furnaces and boilers. In steel plants, natural gas can be fired together with BFG and COG, but, typically, the addition of natural gas raises NOx emissions, which can already be high because of residual fuel-bound nitrogen in COG. The Project Team has applied its expertise in low-NOx burners to lower NOx levels for these applications by combining advanced burner geometry and combustion staging with control strategies tailored to mixtures of natural gas and byproduct fuel gases. These methods reduce all varieties of NOx thermal NOx produced by high flame temperatures, prompt NOx produced by complex chain reactions involving radical hydrocarbon species and NOx from fuel-bound nitrogen compounds such as ammonia found in COG. The Project Team has expanded GTIs highly successful low-NOx forced internal recirculation (FIR) burner, previously developed for natural gas-fired boilers, into facilities that utilize BFG and COG. For natural gas firing, these burners have been shown to reduce NOx emissions from typical uncontrolled levels of 80-100 vppm to single-digit levels (9 vppm). This is done without the energy efficiency penalties incurred by alternative NOx control methods, such as external flue gas recirculation (FGR), water injection, and selective non-catalytic reduction. The FIR burner was previously demonstrated on firetube and watertube boilers, and these units are still operating at several industrial and commercial boiler sites in sizes ranging from 2.5 to 60 million Btu/h. This report covers the development of an innovative combustion system suitable for natural gas or coke-oven gas firing within the steel industry. The prototype FIR burner was evaluated on a 20 million Btu/h watertube boiler. Acceptable burner performance was obtained when firing natural gas and simulated coke-oven gas doped with ammonia. The laboratory data reveals a direct relationship between NOx formation and the ammonia concentration in the fuel. In addition, NOx formation increases as the primary stoichiometric ratio (PSR) increases. Representative ammonia concentrations, as documented in the steel industry, ranged from 200 to 500 vppm. When the laboratory burner/boiler was operated with 500 vppm ammonia in the fuel, NOx emissions ranged from 50 to 75 vppm. This, conservatively, is 75% less than state-of-the-art burner performance. When the burner is operated with 200 vppm ammonia in the fuel, the corresponding NOx emissions would range from 30 to 45 vppm, 84% less than present burner technology. During field evaluation on a 174 million Btu/h industrial prototype burner both natural gas and actual COG from on-site generation were tested. Despite the elevated hydrogen cyanide and ammonia content in the COG throughout the test program, the FIR burner showed an improvement over baseline emissions. At full load; 167 million Btu/h, NOx emissions were relatively low at 169 vppm. This represents a 30% reduction compared to baseline emissions not accounting for the higher hydrogen cyanide content in the COG. CO emissions remained below 20 vppm and were stable across the firing range. This represents a 68% reduction compared to baseline CO emissions. When firing natural gas, emissions were stable as firing rate increased over the range. At low fire; 45 million Btu/h, NOx emissions where 33 vppm and increased at full load; 144 million Btu

  6. OPTIMIZATION OF COAL PARTICLE FLOW PATTERNS IN LOW NOX BURNERS

    SciTech Connect (OSTI)

    Jost O.L. Wendt; Gregory E. Ogden; Jennifer Sinclair; Caner Yurteri

    2001-08-20

    The proposed research is directed at evaluating the effect of flame aerodynamics on NO{sub x} emissions from coal fired burners in a systematic manner. This fundamental research includes both experimental and modeling efforts being performed at the University of Arizona in collaboration with Purdue University. The objective of this effort is to develop rational design tools for optimizing low NO{sub x} burners to the kinetic emissions limit (below 0.2 lb./MMBTU). Experimental studies include both cold and hot flow evaluations of the following parameters: flame holder geometry, secondary air swirl, primary and secondary inlet air velocity, coal concentration in the primary air and coal particle size distribution. Hot flow experiments will also evaluate the effect of wall temperature on burner performance. Cold flow studies will be conducted with surrogate particles as well as pulverized coal. The cold flow furnace will be similar in size and geometry to the hot-flow furnace but will be designed to use a laser Doppler velocimeter/phase Doppler particle size analyzer. The results of these studies will be used to predict particle trajectories in the hot-flow furnace as well as to estimate the effect of flame holder geometry on furnace flow field. The hot-flow experiments will be conducted in a novel near-flame down-flow pulverized coal furnace. The furnace will be equipped with externally heated walls. Both reactors will be sized to minimize wall effects on particle flow fields. The cold-flow results will be compared with Fluent computation fluid dynamics model predictions and correlated with the hot-flow results with the overall goal of providing insight for novel low NO{sub x} burner geometry's.

  7. Method for reducing NOx during combustion of coal in a burner

    DOE Patents [OSTI]

    Zhou, Bing (Cranbury, NJ); Parasher, Sukesh (Lawrenceville, NJ); Hare, Jeffrey J. (Provo, UT); Harding, N. Stanley (North Salt Lake, UT); Black, Stephanie E. (Sandy, UT); Johnson, Kenneth R. (Highland, UT)

    2008-04-15

    An organically complexed nanocatalyst composition is applied to or mixed with coal prior to or upon introducing the coal into a coal burner in order to catalyze the removal of coal nitrogen from the coal and its conversion into nitrogen gas prior to combustion of the coal. This process leads to reduced NOx production during coal combustion. The nanocatalyst compositions include a nanoparticle catalyst that is made using a dispersing agent that can bond with the catalyst atoms. The dispersing agent forms stable, dispersed, nano-sized catalyst particles. The catalyst composition can be formed as a stable suspension to facilitate storage, transportation and application of the catalyst nanoparticles to a coal material. The catalyst composition can be applied before or after pulverizing the coal material or it may be injected directly into the coal burner together with pulverized coal.

  8. Evaluation of Gas Reburning & Low NOx Burners on a Wall Fired Boiler Performance and Economics Report Gas Reburning-Low NOx Burner System Cherokee Station Unit 3 Public Service Company of Colorado

    SciTech Connect (OSTI)

    1998-07-01

    Under the U.S. Department of Energy's Clean Coal Technology Program (Round 3), a project was completed to demonstrate control of boiler NOX emissions and to a lesser degree, due to coal replacement, SO2 emissions. The project involved combining Gas Reburning with Low NOX Burners (GR-LNB) on a coal-fired electric utility boiler to determine if high levels of NOX reduction (70%) could be achieved. Sponsors of the project included the U.S. Department of Energy, the Gas Research Institute, Public Service Company of Colorado, Colorado Interstate Gas, Electric Power Research Institute, and the Energy and Environmental Research Corporation. The GR-LNB demonstration was performed on Public Service Company of Colorado's (PSCO) Cherokee Unit #3, located in Denver, Colorado. This unit is a 172 MW~ wall-fired boiler that uses Colorado Bituminous, low-sulfur coal. It had a baseline NOX emission level of 0.73 lb/106 Btu using conventional burners. Low NOX burners are designed to yield lower NOX emissions than conventional burners. However, the NOX control achieved with this technique is limited to 30-50%. Also, with LNBs, CO emissions can increase to above acceptable standards. Gas Reburning (GR) is designed to reduce NOX in the flue gas by staged fuel combustion. This technology involves the introduction of natural gas into the hot furnace flue gas stream. When combined, GR and LNBs minimize NOX emissions and maintain acceptable levels of CO emissions. A comprehensive test program was completed, operating over a wide range of boiler conditions. Over 4,000 hours of operation were achieved, providing substantial data. Measurements were taken to quantify reductions in NOX emissions, the impact on boiler equipment and operability and factors influencing costs. The GR-LNB technology achieved good NOX emission reductions and the goals of the project were achieved. Although the performance of the low NOX burners (supplied by others) was less than expected, a NOX reduction of 65% was achieved at an average gas heat input of 18Y0. The performance goal of 70% reduction was met on many test runs, but at a higher reburn gas heat input. S02 emissions, based on coal replacement, were reduced by 18Y0. The performance goal of 70% reduction was met on many test runs, but at a higher reburn gas heat input. S02 emissions, based on coal replacement, were reduced by 18Y0. Toward the end of the program, a Second Generation gas injection system was installed. Higher injector gas pressures were used that eliminated the need for flue gas recirculation as used in the first generation design. The Second Generation GR resulted in similar NOX reduction performance as that for the First Generation. With an improvement in the LNB performance in combination with the new gas injection system , the reburn gas could be reduced to 12.5% of the total boiler heat input to achieve al 64?40 reduction in NO, emissions. In addition, the OFA injectors were modified to provide for better mixing to lower CO emissions.

  9. Combustion characteristics and NOx emissions of two kinds of swirl burners in a 300-MWe wall-fired pulverized-coal utility boiler

    SciTech Connect (OSTI)

    Li, Z.Q.; Jing, J.P.; Chen, Z.C.; Ren, F.; Xu, B.; Wei, H.D.; Ge, Z.H.

    2008-07-01

    Measurements were performed in a 300-MWe wall-fired pulverized-coal utility boiler. Enhanced ignition-dual register (EI-DR) burners and centrally fuel rich (CFR) swirl coal combustion burners were installed in the bottom row of the furnace during experiments. Local mean concentrations of O{sub 2}, CO, CO{sub 2} and NOx gas species, gas temperatures, and char burnout were determined in the region of the two types of burners. For centrally fuel rich swirl coal combustion burners, local mean CO concentrations, gas temperatures and the temperature gradient are higher and mean concentrations of O{sub 2} and NOx along the jet flow direction in the burner region are lower than for the enhanced ignition-dual register burners. Moreover, the mean O{sub 2} concentration is higher and the gas temperature and mean CO concentration are lower in the side wall region. For centrally fuel rich swirl coal combustion burners in the bottom row, the combustion efficiency of the boiler increases from 96.73% to 97.09%, and NOx emission decreases from 411.5 to 355 ppm at 6% O{sub 2} compared to enhanced ignition-dual register burners and the boiler operates stably at 110 MWe without auxiliary fuel oil.

  10. Experimental study on NOx emission and unburnt carbon of a radial biased swirl burner for coal combustion

    SciTech Connect (OSTI)

    Shan Xue; Shi'en Hui; Qulan Zhou; Tongmo Xu

    2009-07-15

    Pilot tests were carried out on a 1 MW thermal pulverized coal fired testing furnace. Symmetrical combustion was implemented by use of two whirl burners with dual air adjustment. The burnout air device was installed in various places at the top of the main burner, which consists of a primary air pipe with a varying cross-section and an impact ring. In the primary air pipe, the air pulverized coal (PC) stream was separated into a whirling stream that was thick inside and thin outside, thus realizing the thin-thick distribution at the burner nozzle in the radial direction. From the comparative combustion tests of three coals with relatively great characteristic differences, Shaanbei Shenhua high rank bituminous coal (SH coal), Shanxi Hejin low rank bituminous coal (HJ coal), and Shanxi Changzhi meager coal (CZ coal), were obtained such test results as the primary air ratio, inner secondary air ratio, outer secondary air ratio, impact of the change of outer secondary air, change of the relative position for the layout of burnout air, change of the swirling intensity of the primary air and secondary air, etc., on the NOx emission, and unburnt carbon content in fly ash (CFA). At the same time, the relationship between the NOx emission and burnout ratio and affecting factors of the corresponding test items on the combustion stability and economic results were also acquired. The results may provide a vital guiding significance to engineering designs and practical applications. According to the experimental results, the influence of each individual parameter on NOx formation and unburned carbon in fly ash agrees well with the existing literature. In this study, the influences of various combinations of these parameters are also examined, thus providing some reference for the design of the radial biased swirl burner, the configuration of the furnace, and the distribution of the air. 23 refs., 14 figs., 2 tabs.

  11. Coal Particle Flow Patterns for O2 Enriched, Low NOx Burners

    SciTech Connect (OSTI)

    Jennifer Sinclair Curtis

    2005-08-01

    This project involved a systematic investigation examining the effect of near-flame burner aerodynamics on standoff distance and stability of turbulent diffusion flames and the resultant NO{sub x} emissions from actual pulverized coal diffusion flames. Specifically, the scope of the project was to understand how changes in near-flame aerodynamics and transport air oxygen partial pressure can influence flame attachment and coal ignition, two properties essential to proper operation of low NO{sub x} burners. Results from this investigation utilized a new 2M tall, 0.5m in diameter combustor designed to evaluate near-flame combustion aerodynamics in terms of transport air oxygen partial pressure (Po{sub 2}), coal fines content, primary fuel and secondary air velocities, and furnace wall temperature furnish insight into fundamental processes that occur during combustion of pulverized coal in practical systems. Complementary cold flow studies were conducted in a geometrically similar chamber to analyze the detailed motion of the gas and particles using laser Doppler velocimetry. This final technical report summarizes the key findings from our investigation into coal particle flow patterns in burners. Specifically, we focused on the effects of oxygen enrichment, the effect of fines, and the effect of the nozzle velocity ratio on the resulting flow patterns. In the cold flow studies, detailed measurements using laser Doppler velocimetry (LDV) were made to determine the details of the flow. In the hot flow studies, observations of flame stability and measurements of NO{sub x} were made to determine the effects of the flow patterns on burner operation.

  12. COAL PARTICLE FLOW PATTERNS FOR O2 ENRICHED, LOW NOx BURNERS

    SciTech Connect (OSTI)

    Jennifer L. Sinclair

    2001-09-30

    Over the past year, the hot flow studies have focused on the validation of a novel 2M near-flame combustion furnace. The 2M furnace was specifically designed to investigate burner aerodynamics and flame stability phenomena. Key accomplishments include completion of coal & oxygen mass balance calculations and derivation of emission conversion equations, upgrade of furnace equipment and flame safety systems, shakedown testing and partial completion of a parametric flame stability study. These activities are described in detail below along with a description of the 2M furnace and support systems.

  13. EA-1472: Commercial Demonstration fo the Low Nox Burner/Separated Over-Fire Air (LNB/SOFA) Integration System Emission Reduction Technology, Holcolm Station, Sunflower Electric Power Corporation Finnety County, Kansas

    Broader source: Energy.gov [DOE]

    The DOE has prepared an Environmental Assessment (EA), to analyze the potential impacts of the commercial application of the Low-NOx Burner/Separated Over-Fire Air (LNB/SOFA) integration system to achieve nitrogen oxide (NOx) emissions reduction at Sunflower’s Holcomb Unit No. 1 (Holcomb Station), located near Garden City, in Finney County, Kansas. The Holcomb Station would be modified in three distinct phases to demonstrate the synergistic effect of layering NOx control technologies.

  14. Flexible CHP System with Low NOx, CO and VOC Emissions- Fact Sheet, 2014

    Broader source: Energy.gov [DOE]

    Utilizing Supplemental Ultra-Low-NOx Burner Technology to Meet Emissions Standards and Improve System Efficiency

  15. Startup burner

    DOE Patents [OSTI]

    Zhao, Jian Lian; Northrop, William F.; Bosco, Timothy; Rizzo, Vincent; Kim, Changsik

    2009-08-18

    A startup burner for rapidly heating a catalyst in a reformer, as well as related methods and modules, is disclosed.

  16. Achieving New Source Performance Standards (NSPS) Emission Standards Through Integration of Low-NOx Burners with an Optimization Plan for Boiler Combustion

    SciTech Connect (OSTI)

    Wayne Penrod

    2006-12-31

    The objective of this project was to demonstrate the use of an Integrated Combustion Optimization System to achieve NO{sub X} emission levels in the range of 0.15 to 0.22 lb/MMBtu while simultaneously enabling increased power output. The project plan consisted of the integration of low-NO{sub X} burners and advanced overfire air technology with various process measurement and control devices on the Holcomb Station Unit 1 boiler. The plan included the use of sophisticated neural networks or other artificial intelligence technologies and complex software to optimize several operating parameters, including NO{sub X} emissions, boiler efficiency, and CO emissions. The program was set up in three phases. In Phase I, the boiler was equipped with sensors that can be used to monitor furnace conditions and coal flow to permit improvements in boiler operation. In Phase II, the boiler was equipped with burner modifications designed to reduce NO{sub X} emissions and automated coal flow dampers to permit on-line fuel balancing. In Phase III, the boiler was to be equipped with an overfire air system to permit deep reductions in NO{sub X} emissions. Integration of the overfire air system with the improvements made in Phases I and II would permit optimization of boiler performance, output, and emissions. This report summarizes the overall results from Phases I and II of the project. A significant amount of data was collected from the combustion sensors, coal flow monitoring equipment, and other existing boiler instrumentation to monitor performance of the burner modifications and the coal flow balancing equipment.

  17. PARTICULATE CHARACTERIZATION AND ULTRA LOW-NOx BURNER FOR THE CONTROL OF NO{sub x} AND PM{sub 2.5} FOR COAL FIRED BOILERS

    SciTech Connect (OSTI)

    Ralph Bailey; Hamid Sarv; Jim Warchol; Debi Yurchison

    2001-09-30

    In response to the serious challenge facing coal-fired electric utilities with regards to curbing their NO{sub x} and fine particulate emissions, Babcock and Wilcox and McDermott Technology, Inc. conducted a project entitled, ''Particulate Characterization and Ultra Low-NO{sub x} Burner for the Control of NO{sub x} and PM{sub 2.5} for Coal Fired Boilers.'' The project included pilot-scale demonstration and characterization of technologies for removal of NO{sub x} and primary PM{sub 2.5} emissions. Burner development and PM{sub 2.5} characterization efforts were based on utilizing innovative concepts in combination with sound scientific and fundamental engineering principles and a state-of-the-art test facility. Approximately 1540 metric tonnes (1700 tons) of high-volatile Ohio bituminous coal were fired. Particulate sampling for PM{sub 2.5} emissions characterization was conducted in conjunction with burner testing. Based on modeling recommendations, a prototype ultra low-NO{sub x} burner was fabricated and tested at 100 million Btu/hr in the Babcock and Wilcox Clean Environment Development Facility. Firing the unstaged burner with a high-volatile bituminous Pittsburgh 8 coal at 100 million Btu/hr and 17% excess air achieved a NO{sub x} goal of 0.20 lb NO{sub 2}/million Btu with a fly ash loss on ignition (LOI) of 3.19% and burner pressure drop of 4.7 in H{sub 2}O for staged combustion. With the burner stoichiometry set at 0.88 and the overall combustion stoichiometry at 1.17, average NO{sub x} and LOI values were 0.14 lb NO{sub 2}/million Btu and 4.64% respectively. The burner was also tested with a high-volatile Mahoning 7 coal. Based on the results of this work, commercial demonstration is being pursued. Size classified fly ash samples representative of commercial low-NO{sub x} and ultra low-NO{sub x} combustion of Pittsburgh 8 coal were collected at the inlet and outlet of an ESP. The mass of size classified fly ash at the ESP outlet was sufficient to evaluate the particle size distribution, but was of insufficient size to permit reliable chemical analysis. The size classified fly ash from the inlet of the ESP was used for detailed chemical analyses. Chemical analyses of the fly ash samples from the ESP outlet using a high volume sampler were performed for comparison to the size classified results at the inlet. For all test conditions the particulate removal efficiency of the ESP exceeded 99.3% and emissions were less than the NSPS limits of {approx}48 mg/dscm. With constant combustion conditions, the removal efficiency of the ESP increased as the ESP voltage and Specific Collection Area (SCA) increased. The associated decrease in particle emissions occurred in size fractions both larger and smaller than 2.5 microns. For constant ESP voltage and SCA, the removal efficiency for the ultra low-NO{sub x} combustion ash (99.4-99.6%) was only slightly less than for the low-NO{sub x} combustion ash (99.7%). The decrease in removal efficiency was accompanied by a decrease in ESP current. The emission of PM{sub 2.5} from the ESP did not change significantly as a result of the change in combustion conditions. Most of the increase in emissions was in the size fraction greater than 2.5 microns, indicating particle re-entrainment. These results may be specific to the coal tested in this program. In general, the concentration of inorganic elements and trace species in the fly ash at the ESP inlet was dependent on the particle size fraction. The smallest particles tended to have higher concentrations of inorganic elements/trace species than larger particles. The concentration of most elements by particle size range was independent of combustion condition and the concentration of soluble ions in the fly ash showed little change with combustion condition when evaluated on a carbon free basis.

  18. Fe-Al Weld Overlay and High Velocity Oxy-Fuel Thermal Spray Coatings for Corrosion Protection of Waterwalls in Fossil Fired Plants with Low NOx Burners

    SciTech Connect (OSTI)

    Regina, J.R.

    2002-02-08

    Iron-aluminum-chromium coatings were investigated to determine the best candidates for coatings of boiler tubes in Low NOx fossil fueled power plants. Ten iron-aluminum-chromium weld claddings with aluminum concentrations up to 10wt% were tested in a variety of environments to evaluate their high temperature corrosion resistance. The weld overlay claddings also contained titanium additions to investigate any beneficial effects from these ternary and quaternary alloying additions. Several High-Velocity Oxy-Fuel (HVOF) thermal spray coatings with higher aluminum concentrations were investigated as well. Gaseous corrosion testing revealed that at least 10wt%Al is required for protection in the range of environments examined. Chromium additions were beneficial in all of the environments, but additions of titanium were beneficial only in sulfur rich atmospheres. Similar results were observed when weld claddings were in contact with corrosive slag while simultaneously, exposed to the corrosive environments. An aluminum concentration of 10wt% was required to prevent large amounts of corrosion to take place. Again chromium additions were beneficial with the greatest corrosion protection occurring for welds containing both 10wt%Al and 5wt%Cr. The exposed thermal spray coatings showed either significant cracking within the coating, considerable thickness loss, or corrosion products at the coating substrate interface. Therefore, the thermal spray coatings provided the substrate very little protection. Overall, it was concluded that of the coatings studied weld overlay coatings provide superior protection in these Low NOx environments; specifically, the ternary weld composition of 10wt%Al and 5wt%Cr provided the best corrosion protection in all of the environments tested.

  19. Combined Heat and Power Integrated with Burners for Packaged Boilers

    SciTech Connect (OSTI)

    2010-10-01

    This factsheet describes a project that will seamlessly integrate a gas-fired simple-cycle 100 kWe microturbine with a new ultra-low NOx gas-fired burner to develop a CHP assembly called the Boiler Burner Energy System Technology.

  20. Catalyzed Ceramic Burner Material

    SciTech Connect (OSTI)

    Barnes, Amy S., Dr.

    2012-06-29

    Catalyzed combustion offers the advantages of increased fuel efficiency, decreased emissions (both NOx and CO), and an expanded operating range. These performance improvements are related to the ability of the catalyst to stabilize a flame at or within the burner media and to combust fuel at much lower temperatures. This technology has a diverse set of applications in industrial and commercial heating, including boilers for the paper, food and chemical industries. However, wide spread adoption of catalyzed combustion has been limited by the high cost of precious metals needed for the catalyst materials. The primary objective of this project was the development of an innovative catalyzed burner media for commercial and small industrial boiler applications that drastically reduce the unit cost of the catalyzed media without sacrificing the benefits associated with catalyzed combustion. The scope of this program was to identify both the optimum substrate material as well as the best performing catalyst construction to meet or exceed industry standards for durability, cost, energy efficiency, and emissions. It was anticipated that commercial implementation of this technology would result in significant energy savings and reduced emissions. Based on demonstrated achievements, there is a potential to reduce NOx emissions by 40,000 TPY and natural gas consumption by 8.9 TBtu in industries that heavily utilize natural gas for process heating. These industries include food manufacturing, polymer processing, and pulp and paper manufacturing. Initial evaluation of commercial solutions and upcoming EPA regulations suggests that small to midsized boilers in industrial and commercial markets could possibly see the greatest benefit from this technology. While out of scope for the current program, an extension of this technology could also be applied to catalytic oxidation for volatile organic compounds (VOCs). Considerable progress has been made over the course of the grant period in accomplishing these objectives. Our work in the area of Pd-based, methane oxidation catalysts has led to the development of highly active catalysts with relatively low loadings of Pd metal using proprietary coating methods. The thermal stability of these Pd-based catalysts were characterized using SEM and BET analyses, further demonstrating that certain catalyst supports offer enhanced stability toward both PdO decomposition and/or thermal sintering/growth of Pd particles. When applied to commercially available fiber mesh substrates (both metallic and ceramic) and tested in an open-air burner, these catalyst-support chemistries showed modest improvements in the NOx emissions and radiant output compared to uncatalyzed substrates. More significant, though, was the performance of the catalyst-support chemistries on novel media substrates. These substrates were developed to overcome the limitations that are present with commercially available substrate designs and increase the gas-catalyst contact time. When catalyzed, these substrates demonstrated a 65-75% reduction in NOx emissions across the firing range when tested in an open air burner. In testing in a residential boiler, this translated into NOx emissions of <15 ppm over the 15-150 kBtu/hr firing range.

  1. CHP Integrated with Burners for Packaged Boilers - Fact Sheet, April 2014 |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy CHP Integrated with Burners for Packaged Boilers - Fact Sheet, April 2014 CHP Integrated with Burners for Packaged Boilers - Fact Sheet, April 2014 CMCE, Inc., in collaboration with Altex Technologies Corporation, developed the Boiler Burner Energy System Technology (BBEST), a CHP assembly of a gas-fired simple-cycle 100 kilowatt (kW) microturbine and a new ultra-low NOx gas-fired burner, to increase acceptance of small CHP systems. PDF icon

  2. Burner systems

    DOE Patents [OSTI]

    Doherty, Brian J. (Marblehead, MA)

    1984-07-10

    A burner system particularly useful for downhole deployment includes a tubular combustion chamber unit housed within a tubular coolant jacket assembly. The combustion chamber unit includes a monolithic tube of refractory material whose inner surface defines the combustion zone. A metal reinforcing sleeve surrounds and extends the length of the refractory tube. The inner surface of the coolant jacket assembly and outer surface of the combustion chamber unit are dimensioned so that those surfaces are close to one another in standby condition so that the combustion chamber unit has limited freedom to expand with that expansion being stabilized by the coolant jacket assembly so that compression forces in the refractory tube do not exceed about one-half the safe compressive stress of the material; and the materials of the combustion chamber unit are selected to establish thermal gradient parameters across the combustion chamber unit to maintain the refractory tube in compression during combustion system start up and cool down sequences.

  3. CHP Integrated with Burners for Packaged Boilers

    SciTech Connect (OSTI)

    Castaldini, Carlo; Darby, Eric

    2013-09-30

    The objective of this project was to engineer, design, fabricate, and field demonstrate a Boiler Burner Energy System Technology (BBEST) that integrates a low-cost, clean burning, gas-fired simple-cycle (unrecuperated) 100 kWe (net) microturbine (SCMT) with a new ultra low-NOx gas-fired burner (ULNB) into one compact Combined Heat and Power (CHP) product that can be retrofit on new and existing industrial and commercial boilers in place of conventional burners. The Scope of Work for this project was segmented into two principal phases: (Phase I) Hardware development, assembly and pre-test and (Phase II) Field installation and demonstration testing. Phase I was divided into five technical tasks (Task 2 to 6). These tasks covered the engineering, design, fabrication, testing and optimization of each key component of the CHP system principally, ULNB, SCMT, assembly BBEST CHP package, and integrated controls. Phase I work culminated with the laboratory testing of the completed BBEST assembly prior to shipment for field installation and demonstration. Phase II consisted of two remaining technical tasks (Task 7 and 8), which focused on the installation, startup, and field verification tests at a pre-selected industrial plant to document performance and attainment of all project objectives. Technical direction and administration was under the management of CMCE, Inc. Altex Technologies Corporation lead the design, assembly and testing of the system. Field demonstration was supported by Leva Energy, the commercialization firm founded by executives at CMCE and Altex. Leva Energy has applied for patent protection on the BBEST process under the trade name of Power Burner and holds the license for the burner currently used in the product. The commercial term Power Burner is used throughout this report to refer to the BBEST technology proposed for this project. The project was co-funded by the California Energy Commission and the Southern California Gas Company (SCG), a division of Sempra Energy. These match funds were provided via concurrent contracts and investments available via CMCE, Altex, and Leva Energy The project attained all its objectives and is considered a success. CMCE secured the support of GI&E from Italy to supply 100 kW Turbec T-100 microturbines for the project. One was purchased by the project’s subcontractor, Altex, and a second spare was purchased by CMCE under this project. The microturbines were then modified to convert from their original recuperated design to a simple cycle configuration. Replacement low-NOx silo combustors were designed and bench tested in order to achieve compliance with the California Air Resources Board (CARB) 2007 emission limits for NOx and CO when in CHP operation. The converted microturbine was then mated with a low NOx burner provided by Altex via an integration section that allowed flow control and heat recovery to minimize combustion blower requirements; manage burner turndown; and recover waste heat. A new fully integrated control system was designed and developed that allowed one-touch system operation in all three available modes of operation: (1) CHP with both microturbine and burner firing for boiler heat input greater than 2 MMBtu/hr; (2) burner head only (BHO) when the microturbine is under service; and (3) microturbine only when boiler heat input requirements fall below 2 MMBtu/hr. This capability resulted in a burner turndown performance of nearly 10/1, a key advantage for this technology over conventional low NOx burners. Key components were then assembled into a cabinet with additional support systems for generator cooling and fuel supply. System checkout and performance tests were performed in the laboratory. The assembled system and its support equipment were then shipped and installed at a host facility where final performance tests were conducted following efforts to secure fabrication, air, and operating permits. The installed power burner is now in commercial operation and has achieved all the performance goals.

  4. High Luminosity, Low-NOx Burner

    Broader source: Energy.gov [DOE]

    Glass melters use combustion systems to produce molten glass. While significant progress has been made in developing oxy-fuel combustion systems, current technologies provide low flame luminosity...

  5. Front Burner- Issue 14

    Broader source: Energy.gov [DOE]

    The Cybersecurity Front Burner Issue No. 14 highlights the 2013 National Cybersecurity Awareness Month (NCSAM) Campaign and Phishing Scams.

  6. Front Burner- Issue 15

    Broader source: Energy.gov [DOE]

    The Cybersecurity Front Burner Issue No. 15 addresses the DOE eSCRM Program and Secure Online Shopping.

  7. Development of the Radiation Stabilized Distributed Flux Burner - Phase III Final Report

    SciTech Connect (OSTI)

    J. D. Sullivan; A. Webb

    1999-12-01

    The development and demonstration of the Radiation Stabilized Burner (RSB) was completed as a project funded by the US Department of Energy Office of Industrial Technologies. The technical goals of the project were to demonstrate burner performance that would meet or exceed emissions targets of 9 ppm NOx, 50 ppm CO, and 9 ppm unburned hydrocarbons (UHC), with all values being corrected to 3 percent stack oxygen, and incorporate the burner design into a new industrial boiler configuration that would achieve ultra-low emissions while maintaining or improving thermal efficiency, operating costs, and maintenance costs relative to current generation 30 ppm low NOx burner installations. Both the ultra-low NOx RSB and the RSB boiler-burner package are now commercially available.

  8. Rotary Burner Demonstration

    SciTech Connect (OSTI)

    Paul Flanagan

    2003-04-30

    The subject technology, the Calcpos Rotary Burner (CRB), is a burner that is proposed to reduce energy consumption and emission levels in comparison to currently available technology. burners are used throughout industry to produce the heat that is required during the refining process. Refineries seek to minimize the use of energy in refining while still meeting EPA regulations for emissions.

  9. Front Burner- Issue 13

    Broader source: Energy.gov [DOE]

    The Cybersecurity Front Burner Issue No. 13 contained a message from the Associate Chief Information Officer (ACIO) for Cybersecurity as well as a listing of recommended cybersecurity practices.

  10. Front Burner- Issue 18

    Broader source: Energy.gov [DOE]

    The Cybersecurity Front Burner Issue No. 18 addresses keeping kids safe on the Internet, cyber crime, and DOE Cyber awareness and training initiatives.

  11. Combined Heat and Power (CHP) Integrated with Burners for Packaged Boilers

    Office of Environmental Management (EM)

    | Department of Energy Combined Heat and Power (CHP) Integrated with Burners for Packaged Boilers Combined Heat and Power (CHP) Integrated with Burners for Packaged Boilers Providing Clean, Low-Cost, Onsite Distributed Generation at Very High Fuel Efficiency This project integrated a gas-fired, simple-cycle 100 kilowatt (kW) microturbine (SCMT) with a new ultra-low nitrogen oxide (NOx) gas-fired burner (ULNB) to develop a combined heat and power (CHP) assembly called the Boiler Burner Energy

  12. Variable capacity gasification burner

    SciTech Connect (OSTI)

    Saxon, D.I.

    1985-03-05

    A variable capacity burner that may be used in gasification processes, the burner being adjustable when operating in its intended operating environment to operate at two different flow capacities, with the adjustable parts being dynamically sealed within a statically sealed structural arrangement to prevent dangerous blow-outs of the reactants to the atmosphere.

  13. Combustor burner vanelets

    DOE Patents [OSTI]

    Lacy, Benjamin (Greer, SC); Varatharajan, Balachandar (Loveland, OH); Kraemer, Gilbert Otto (Greer, SC); Yilmaz, Ertan (Albany, NY); Zuo, Baifang (Simpsonville, SC)

    2012-02-14

    The present application provides a burner for use with a combustor of a gas turbine engine. The burner may include a center hub, a shroud, a pair of fuel vanes extending from the center hub to the shroud, and a vanelet extending from the center hub and/or the shroud and positioned between the pair of fuel vanes.

  14. Pulverized coal burner

    DOE Patents [OSTI]

    Sivy, Jennifer L. (Alliance, OH); Rodgers, Larry W. (Canton, OH); Koslosy, John V. (Akron, OH); LaRue, Albert D. (Uniontown, OH); Kaufman, Keith C. (Canton, OH); Sarv, Hamid (Canton, OH)

    1998-01-01

    A burner having lower emissions and lower unburned fuel losses by implementing a transition zone in a low NO.sub.x burner. The improved burner includes a pulverized fuel transport nozzle surrounded by the transition zone which shields the central oxygen-lean fuel devolatilization zone from the swirling secondary combustion air. The transition zone acts as a buffer between the primary and the secondary air streams to improve the control of near-burner mixing and flame stability by providing limited recirculation regions between primary and secondary air streams. These limited recirculation regions transport evolved NO.sub.x back towards the oxygen-lean fuel pyrolysis zone for reduction to molecular nitrogen. Alternate embodiments include natural gas and fuel oil firing.

  15. Pulverized coal burner

    DOE Patents [OSTI]

    Sivy, J.L.; Rodgers, L.W.; Koslosy, J.V.; LaRue, A.D.; Kaufman, K.C.; Sarv, H.

    1998-11-03

    A burner is described having lower emissions and lower unburned fuel losses by implementing a transition zone in a low NO{sub x} burner. The improved burner includes a pulverized fuel transport nozzle surrounded by the transition zone which shields the central oxygen-lean fuel devolatilization zone from the swirling secondary combustion air. The transition zone acts as a buffer between the primary and the secondary air streams to improve the control of near-burner mixing and flame stability by providing limited recirculation regions between primary and secondary air streams. These limited recirculation regions transport evolved NO{sub x} back towards the oxygen-lean fuel pyrolysis zone for reduction to molecular nitrogen. Alternate embodiments include natural gas and fuel oil firing. 8 figs.

  16. Ultralean low swirl burner

    DOE Patents [OSTI]

    Cheng, Robert K. (Kensington, CA)

    1998-01-01

    A novel burner and burner method has been invented which burns an ultra lean premixed fuel-air mixture with a stable flame. The inventive burning method results in efficient burning and much lower emissions of pollutants such as oxides of nitrogen than previous burners and burning methods. The inventive method imparts weak swirl (swirl numbers of between about 0.01 to 3.0) on a fuel-air flow stream. The swirl, too small to cause recirculation, causes an annulus region immediately inside the perimeter of the fuel-air flow to rotate in a plane normal to the axial flow. The rotation in turn causes the diameter of the fuel-air flow to increase with concomitant decrease in axial flow velocity. The flame stabilizes where the fuel-air mixture velocity equals the rate of burning resulting in a stable, turbulent flame.

  17. Ultralean low swirl burner

    DOE Patents [OSTI]

    Cheng, R.K.

    1998-04-07

    A novel burner and burner method has been invented which burns an ultra lean premixed fuel-air mixture with a stable flame. The inventive burning method results in efficient burning and much lower emissions of pollutants such as oxides of nitrogen than previous burners and burning methods. The inventive method imparts weak swirl (swirl numbers of between about 0.01 to 3.0) on a fuel-air flow stream. The swirl, too small to cause recirculation, causes an annulus region immediately inside the perimeter of the fuel-air flow to rotate in a plane normal to the axial flow. The rotation in turn causes the diameter of the fuel-air flow to increase with concomitant decrease in axial flow velocity. The flame stabilizes where the fuel-air mixture velocity equals the rate of burning resulting in a stable, turbulent flame. 11 figs.

  18. Optimization of burners for firing solid fuel and natural gas for boilers with impact pulverizers

    SciTech Connect (OSTI)

    G.T. Levit; V.Ya. Itskovich; A.K. Solov'ev (and others) [ORGRES Company (Russian Federation)

    2003-01-15

    The design of a burner with preliminary mixing of fuel and air for alternate or joint firing of coal and natural gas on a boiler is described. The burner provides steady ignition and economical combustion of coal, low emission of NOx in both operating modes, and possesses an ejecting effect sufficient for operation of pulverizing systems with a shaft mill under pressure. The downward inclination of the burners makes it possible to control the position of the flame in the furnace and the temperature of the superheated steam.

  19. FRONT BURNER - ISSUE 19 | Department of Energy

    Office of Environmental Management (EM)

    FRONT BURNER - ISSUE 19 FRONT BURNER - ISSUE 19 The Cybersecurity Front Burner Issue No. 19 is the 2014 DOE NCSAM event newsletter, which examines Securing the Internet of Things, Facebook Messenger Application, and implementation of the Contractor Training Site. PDF icon Cybersecurity Front Burner Issue No. 19 More Documents & Publications FRONT BURNER - Issue 20 2012 NCSAM Campaign

  20. Front Burner - Issue 16 | Department of Energy

    Office of Environmental Management (EM)

    Front Burner - Issue 16 Front Burner - Issue 16 The Cybersecurity Front Burner Issue No. 16 addresses Malware, the Worst Passwords of 2013, and the Flat Stanley and Stop.Think.Connect. Campaign. PDF icon Cybersecurity Front Burner Newsletter Issue 16 More Documents & Publications April 2014 Cybersecurity Awareness Campaign - Malware FRONT BURNER - Issue 20

  1. High efficiency gas burner

    DOE Patents [OSTI]

    Schuetz, Mark A. (Belmont, MA)

    1983-01-01

    A burner assembly provides for 100% premixing of fuel and air by drawing the air into at least one high velocity stream of fuel without power assist. Specifically, the nozzle assembly for injecting the fuel into a throat comprises a plurality of nozzles in a generally circular array. Preferably, swirl is imparted to the air/fuel mixture by angling the nozzles. The diffuser comprises a conical primary diffuser followed by a cusp diffuser.

  2. AMMONIA-FREE NOx CONTROL SYSTEM

    SciTech Connect (OSTI)

    Song Wu; Zhen Fan; Andrew H. Seltzer; Richard G. Herman

    2006-06-01

    This report describes a novel NOx control system that has the potential to drastically reduce cost, and enhance performance, operation and safety of power plant NOx control. The new system optimizes the burner and the furnace to achieve very low NOx levels and to provide an adequate amount of CO, and uses the CO for reducing NO both in-furnace and over a downstream AFSCR (ammonia-free selective catalytic reduction) reactor. The AF-SCR combines the advantages of the highly successful SCR technology for power plants and the TWC (three-way catalytic converter) widely used on automobiles. Like the SCR, it works in oxidizing environment of combustion flue gas and uses only base metal catalysts. Like the TWC, the AF-SCR removes NO and excess CO simultaneously without using any external reagent, such as ammonia. This new process has been studied in a development program jointed funded by the US Department of Energy and Foster Wheeler. The report outlines the experimental catalyst work performed on a bench-scale reactor, including test procedure, operating conditions, and results of various catalyst formulations. Several candidate catalysts, prepared with readily available transition metal oxides and common substrate materials, have shown over 80-90% removal for both NO and CO in oxidizing gas mixtures and at elevated temperatures. A detailed combustion study of a 400 MWe coal-fired boiler, applying computational fluid dynamics techniques to model boiler and burner design, has been carried out to investigate ways to optimize the combustion process for the lowest NOx formation and optimum CO/NO ratios. Results of this boiler and burner optimization work are reported. The paper further discusses catalyst scale-up considerations and the conceptual design of a 400 MWe size AF-SCR reactor, as well as economics analysis indicating large cost savings of the ammonia-free NOx control process over the current SCR technology.

  3. Rotary Burner Demonstration Fact Sheet

    SciTech Connect (OSTI)

    2003-07-01

    A new Calcpos rotary burner (CRB), eliminates electric motors, providing a simple, cost effective means of retrofitting existing fired heaters for energy and environmental reasons.

  4. High capacity oil burner

    SciTech Connect (OSTI)

    Pedrosa, O.A. Jr.; Couto, N.C.; Fanqueiro, R.C.C.

    1983-11-01

    The present invention relates to a high capacity oil burner comprising a cylindrical atomizer completely surrounded by a protective cylindrical housing having a diameter from 2 to 3 times greater than the diameter of said atomizer; liquid fuels being injected under pressure into said atomizer and accumulating within said atomizer in a chamber for the accumulation of liquid fuels, and compressed air being injected into a chamber for the accumulation of air; cylindrical holes communicating said chamber for the accumulation of liquid fuels with the outside and cylindrical holes communicating said chamber for the accumulation of air with said cylindrical holes communicating the chamber for the accumulation of liquids with the outside so that the injection of compressed air into said liquid fuel discharge holes atomizes said fuel which is expelled to the outside through the end portions of said discharge holes which are circumferentially positioned to be burnt by a pilot flame; said protecting cylindrical housing having at its ends perforated circular rings into which water is injected under pressure to form a protecting fan-like water curtain at the rear end of the housing and a fan-like water curtain at the flame to reduce the formation of soot; the burning efficiency of said burner being superior to 30 barrels of liquid fuel per day/kg of the apparatus.

  5. Evaluation of Gas Reburning and Low N0x Burners on a Wall Fired Boiler

    SciTech Connect (OSTI)

    1998-07-01

    Under the U.S. Department of Energy's Clean Coal Technology Program (Round 3), a project was completed to demonstrate control of boiler NOX emissions and to a lesser degree, due to coal replacement, SO2 emissions. The project involved combining Gas Reburning with Low NOX Burners (GR-LNB) on a coal-fired electric utility boiler to determine if high levels of NO, reduction (70VO) could be achieved. Sponsors of the project included the U.S. Depatiment of Energy, the Gas Research Institute, Public Service Company of Colorado, Colorado Interstate Gas, Electric Power Research Institute, and the Energy and Environmental Research Corporation. The GR-LNB demonstration was petformed on Public Service Company of Colorado's (PSCO) Cherokee Unit #3, located in Denver, Colorado. This unit is a 172 MW~ wall-fired boiler that uses Colorado bituminous, low-sulfur coal. It had a baseline NO, emission level of 0.73 lb/1 OG Btu using conventional burners. Low NOX burners are designed to yield lower NOX emissions than conventional burners. However, the NOX control achieved with this technique is limited to 30-50Y0. Also, with LNBs, CO emissions can increase to above acceptable standards. Gas Reburning (GR) is designed to reduce NO, in the flue gas by staged fuel combustion. This technology involves the introduction of' natural gas into the hot furnace flue gas stream. When combined, GR and LNBs minimize NOX emissions and maintain acceptable levels of CO emissions. A comprehensive test program was completed, operating over a wide range of boiler conditions. Over 4,000 hours of operation were achieved, providing substantial data. Measurements were taken to quantify reductions in NOX emissions, the impact on boiler equipment and operability and factors influencing costs. The GR-LNB technology achieved good NO, emission reductions and the goals of the project were achieved. Although the performance of the low NOX burners (supplied by others) was less than expected, a NOX reduction of 65% was achieved at an average gas heat input of 18%. The performance goal of 70/40 reduction was met on many test runs, but at a higher reburn gas heat input. S02 emissions, based on coal replacement, were reduced by 18%.

  6. Radial lean direct injection burner

    DOE Patents [OSTI]

    Khan, Abdul Rafey; Kraemer, Gilbert Otto; Stevenson, Christian Xavier

    2012-09-04

    A burner for use in a gas turbine engine includes a burner tube having an inlet end and an outlet end; a plurality of air passages extending axially in the burner tube configured to convey air flows from the inlet end to the outlet end; a plurality of fuel passages extending axially along the burner tube and spaced around the plurality of air passage configured to convey fuel from the inlet end to the outlet end; and a radial air swirler provided at the outlet end configured to direct the air flows radially toward the outlet end and impart swirl to the air flows. The radial air swirler includes a plurality of vanes to direct and swirl the air flows and an end plate. The end plate includes a plurality of fuel injection holes to inject the fuel radially into the swirling air flows. A method of mixing air and fuel in a burner of a gas turbine is also provided. The burner includes a burner tube including an inlet end, an outlet end, a plurality of axial air passages, and a plurality of axial fuel passages. The method includes introducing an air flow into the air passages at the inlet end; introducing a fuel into fuel passages; swirling the air flow at the outlet end; and radially injecting the fuel into the swirling air flow.

  7. Burner balancing Salem Harbor Station

    SciTech Connect (OSTI)

    Sload, A.W.; Dube, R.J.

    1995-12-31

    The traditional method of burner balancing is first to determine the fuel distribution, then to measure the economizer outlet excess oxygen distribution and to adjust the burners accordingly. Fuel distribution is typically measured by clean and dirty air probing. Coal pipe flow can then be adjusted, if necessary, through the use of coal pipe orificing or by other means. Primary air flow must be adjusted to meet the design criteria of the burner. Once coal pipe flow is balanced to within the desired criteria, secondary air flow to individual burners can be changed by adjusting windbox dampers, burner registers, shrouds or other devices in the secondary air stream. This paper discusses problems encountered in measuring excess O{sub 2} at the economizer outlet. It is important to recognize that O{sub 2} measurements at the economizer outlet, by themselves, can be very misleading. If measurement problems are suspected or encountered, an alternate approach similar to that described should be considered. The alternate method is not only useful for burner balancing but also can be used to help in calibrating the plant excess O{sub 2} instruments and provide an on line means of cross-checking excess air measurements. Balanced burners operate closer to their design stoichiometry, providing better NO{sub x} reduction. For Salem Harbor Station, this means a significant saving in urea consumption.

  8. Development of the Radiation Stabilized Distributed Flux Burner, Phase II Final Report

    SciTech Connect (OSTI)

    Webb, A.; Sullivan, J.D.

    1997-06-01

    This report covers progress made during Phase 2 of a three-phase DOE-sponsored project to develop and demonstrate the Radiation Stabilized Distributed Flux burner (also referred to as the Radiation Stabilized Burner, or RSB) for use in industrial watertube boilers and process heaters. The goal of the DOE-sponsored work is to demonstrate an industrial boiler burner with NOx emissions below 9 ppm and CO emissions below 50 ppm (corrected to 3% stack oxygen). To be commercially successful, these very low levels of NOx and CO must be achievable without significantly affecting other measures of burner performance such as reliability, turndown, and thermal efficiency. Phase 1 of the project demonstrated that sub-9 ppm NOx emissions and sub-50 ppm CO emissions (corrected to 3% oxygen) could be achieved with the RSB in a 3 million Btu/Hr laboratory boiler using several methods of NOx reduction. The RSB was also tested in a 60 million Btu/hr steam generator used by Chevron for Thermally Enhanced Oil Recovery (TEOR). In the larger scale tests, fuel staging was demonstrated, with the RSB consistently achieving sub-20 ppm NOx and as low as 10 ppm NOx. Large-scale steam generator tests also demonstrated that flue gas recirculation (FGR) provided a more predictable and reliable method of achieving sub-9 ppm NOx levels. Based on the results of tests at San Francisco Thermal and Chevron, the near-term approach selected by Alzeta for achieving low NOx is to use FGR. This decision was based on a number of factors, with the most important being that FGR has proved to be an easier approach to transfer to different facilities and boiler designs. In addition, staging has proved difficult to implement in a way that allows good combustion and emissions performance in a fully modulating system. In Phase 3 of the project, the RSB will be demonstrated as a very low emissions burner product suitable for continuous operation in a commercial installation. As such, the Phase 3 field demonstration will represent the first installation in which the RSB will be operated continuously with a sub-9 ppm guarantee.

  9. GNEP Element:Develop Advanced Burner Reactors | Department of...

    Office of Environmental Management (EM)

    Develop Advanced Burner Reactors GNEP Element:Develop Advanced Burner Reactors An article describing burner reactors and the role in GNEP. PDF icon GNEP Element:Develop Advanced...

  10. LN Innovative Technologies | Open Energy Information

    Open Energy Info (EERE)

    search Name: LN Innovative Technologies Place: Israel Sector: Services Product: General Financial & Legal Services ( Partnership (investment, law etc) ) References: LN Innovative...

  11. Burner ignition system

    DOE Patents [OSTI]

    Carignan, Forest J. (Bedford, MA)

    1986-01-21

    An electronic ignition system for a gas burner is battery operated. The battery voltage is applied through a DC-DC chopper to a step-up transformer to charge a capacitor which provides the ignition spark. The step-up transformer has a significant leakage reactance in order to limit current flow from the battery during initial charging of the capacitor. A tank circuit at the input of the transformer returns magnetizing current resulting from the leakage reactance to the primary in succeeding cycles. An SCR in the output circuit is gated through a voltage divider which senses current flow through a flame. Once the flame is sensed, further sparks are precluded. The same flame sensor enables a thermopile driven main valve actuating circuit. A safety valve in series with the main gas valve responds to a control pressure thermostatically applied through a diaphragm. The valve closes after a predetermined delay determined by a time delay orifice if the pilot gas is not ignited.

  12. LnQl Q51

    Office of Legacy Management (LM)

    v F. ii. hWling LnQl Q51 1. Ltr Pm hr. CyanmId Co. 2. EC of ltr Lo Agar. CyanamId Oo

  13. FRONT BURNER - Issue 20 | Department of Energy

    Office of Environmental Management (EM)

    Issue 20 FRONT BURNER - Issue 20 Cybersecurity Front Burner Issue No. 20 examines Phishing and provides tips for protecting yourself from this common and clever security threat. You'll also see information on wireless networks, supply chains, training events, and cybersecurity resources. PDF icon Cybersecurity Front Burner Issue No. 20 More Documents & Publications 2013 NCSAM Campaign Cybersecurity Flyers/Pamphlets Front Burner - Issue 16

  14. Cybersecurity Front Burner | Department of Energy

    Office of Environmental Management (EM)

    Services » Training » Cybersecurity Training Warehouse » DOE Cybersecurity Awareness Program » Cybersecurity Front Burner Cybersecurity Front Burner Documents Available for Download January 15, 2015 FRONT BURNER - Issue 20 The Cybersecurity Front Burner Issue No. 20 examines Phishing to include defining Phishing and related terms and how to protect yourself from this very common and clever security threat. The newsletter also addresses wireless networks, supply chains, training events, and

  15. OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL

    SciTech Connect (OSTI)

    David R. Thompson; Lawrence E. Bool; Jack C. Chen

    2004-04-01

    Conventional wisdom says adding oxygen to a combustion system enhances product throughput, system efficiency, and, unless special care is taken, increases NOx emissions. This increase in NOx emissions is typically due to elevated flame temperatures associated with oxygen use leading to added thermal NOx formation. Innovative low flame temperature oxy-fuel burner designs have been developed and commercialized to minimize both thermal and fuel NOx formation for gas and oil fired industrial furnaces. To be effective these systems require close to 100% oxy-fuel combustion and the cost of oxygen is paid for by fuel savings and other benefits. For applications to coal-fired utility boilers at the current cost of oxygen, however, it is not economically feasible to use 100% oxygen for NOx control. In spite of this conventional wisdom, Praxair and its team members, in partnership with the US Department of Energy National Energy Technology Laboratory, have developed a novel way to use oxygen to reduce NOx emissions without resorting to complete oxy-fuel conversion. In this concept oxygen is added to the combustion process to enhance operation of a low NOx combustion system. Only a small fraction of combustion air is replaced with oxygen in the process. By selectively adding oxygen to a low NOx combustion system it is possible to reduce NOx emissions from nitrogen-containing fuels, including pulverized coal, while improving combustion characteristics such as unburned carbon. A combination of experimental work and modeling was used to define how well oxygen enhanced combustion could reduce NOx emissions. The results of this work suggest that small amounts of oxygen replacement can reduce the NOx emissions as compared to the air-alone system. NOx emissions significantly below 0.15 lbs/MMBtu were measured. Oxygen addition was also shown to reduce carbon in ash. Comparison of the costs of using oxygen for NOx control against competing technologies, such as SCR, show that this concept offers substantial savings over SCR and is an economically attractive alternative to purchasing NOx credits or installing other conventional technologies. In conjunction with the development of oxygen based low NOx technology, Praxair also worked on developing the economically enhancing oxygen transport membrane (OTM) technology which is ideally suited for integration with combustion systems to achieve further significant cost reductions and efficiency improvements. This OTM oxygen production technology is based on ceramic mixed conductor membranes that operate at high temperatures and can be operated in a pressure driven mode to separate oxygen with infinite selectivity and high flux. An OTM material was selected and characterized. OTM elements were successfully fabricated. A single tube OTM reactor was designed and assembled. Testing of dense OTM elements was conducted with promising oxygen flux results of 100% of target flux. However, based on current natural gas prices and stand-alone air separation processes, ceramic membranes do not offer an economic advantage for this application. Under a different DOE-NETL Cooperative Agreement, Praxair is continuing to develop oxygen transport membranes for the Advanced Boiler where the economics appear more attractive.

  16. Uniform-burning matrix burner

    DOE Patents [OSTI]

    Bohn, Mark S. (Golden, CO); Anselmo, Mark (Arvada, CO)

    2001-01-01

    Computer simulation was used in the development of an inward-burning, radial matrix gas burner and heat pipe heat exchanger. The burner and exchanger can be used to heat a Stirling engine on cloudy days when a solar dish, the normal source of heat, cannot be used. Geometrical requirements of the application forced the use of the inward burning approach, which presents difficulty in achieving a good flow distribution and air/fuel mixing. The present invention solved the problem by providing a plenum with just the right properties, which include good flow distribution and good air/fuel mixing with minimum residence time. CFD simulations were also used to help design the primary heat exchanger needed for this application which includes a plurality of pins emanating from the heat pipe. The system uses multiple inlet ports, an extended distance from the fuel inlet to the burner matrix, flow divider vanes, and a ring-shaped, porous grid to obtain a high-temperature uniform-heat radial burner. Ideal applications include dish/Stirling engines, steam reforming of hydrocarbons, glass working, and any process requiring high temperature heating of the outside surface of a cylindrical surface.

  17. Ceramatec NOx Sensor and NOx Catalyst Technologies | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Ceramatec NOx Sensor and NOx Catalyst Technologies Ceramatec NOx Sensor and NOx Catalyst Technologies 2004 Diesel Engine Emissions Reduction (DEER) Conference Presentation: Ceramatec, Inc., Advanced Ionic Technologies PDF icon 2004_deer_nair.pdf More Documents & Publications Enhanced High Temperature Performance of NOx Storage/Reduction (NSR) Materials Pt-free, Perovskite-based Lean NOx Trap Catalysts Active Soot Filter Regeneration

  18. Optimization of Coal Particle Flow Patterns in Low N0x Burners

    SciTech Connect (OSTI)

    Caner Yurteri; Gregory E. Ogden; Jennifer Sinclair; Jost O.L. Wendt

    1998-03-06

    The proposed research is directed at evaluating the effect of flame aerodynamics on NOX emissions tlom coal fired burners in a systematic manner. This fimdamental research includes both experimental and modeling efforts being petiormed at the University of Arizona in collaboration with Purdue University. The objective of this effort is to develop rational design tools for optimizing low NOX burners to the kinetic emissions limit (below 0.2 lb./MMBTU). Experimental studies include both cold and hot flow evaluations of the following parameters: flame holder geometry, secondary air swirl, primary and secondary inlet air velocity, coal concentration in the primary air and coal particle size distribution. Hot flow experiments will also evaluate the effect of wall temperature on burner performance. Cold flow studies will be conducted with surrogate particles as well as pulverized coal. The cold flow furnace will be similar in size and geometry to the hot-flow furnace but will be designed to use a laser Doppler velocimeter/phase Doppler particle size analyzer. The results of these studies will be used to predict particle trajectories in the hot-flow fhrnace as well as to estimate the effect of flame holder geometry on furnace flow field. The hot-flow experiments will be conducted in a novel near-flame down-flow pulverized coal furnace. The fhrnace will be equipped with externally heated walls. Both reactors will be sized to minimize wall effects on particle flow fields. The cold-flow results will be compared with Fluent computation fluid dynamics model predictions and correlated with the hot-flow results with the overall goal of providing insight for novel low NOX burner geometry's.

  19. Low NOx combustion

    DOE Patents [OSTI]

    Kobayashi, Hisashi (Putnam Valley, NY); Bool, III, Lawrence E. (Aurora, NY)

    2008-10-21

    Combustion of hydrocarbon liquids and solids is achieved with less formation of NOx by feeding a small amount of oxygen into the fuel stream.

  20. Low NOx combustion

    DOE Patents [OSTI]

    Kobayashi; Hisashi (Putnam Valley, NY), Bool, III; Lawrence E. (Aurora, NY)

    2007-06-05

    Combustion of hydrocarbon liquids and solids is achieved with less formation of NOx by feeding a small amount of oxygen into the fuel stream.

  1. Porous radiant burners having increased radiant output

    DOE Patents [OSTI]

    Tong, Timothy W. (Tempe, AZ); Sathe, Sanjeev B. (Tempe, AZ); Peck, Robert E. (Tempe, AZ)

    1990-01-01

    Means and methods for enhancing the output of radiant energy from a porous radiant burner by minimizing the scattering and increasing the adsorption, and thus emission of such energy by the use of randomly dispersed ceramic fibers of sub-micron diameter in the fabrication of ceramic fiber matrix burners and for use therein.

  2. Diesel fuel burner for diesel emissions control system

    DOE Patents [OSTI]

    Webb, Cynthia C.; Mathis, Jeffrey A.

    2006-04-25

    A burner for use in the emissions system of a lean burn internal combustion engine. The burner has a special burner head that enhances atomization of the burner fuel. Its combustion chamber is designed to be submersed in the engine exhaust line so that engine exhaust flows over the outer surface of the combustion chamber, thereby providing efficient heat transfer.

  3. Catalytic reactor with improved burner

    DOE Patents [OSTI]

    Faitani, Joseph J.; Austin, George W.; Chase, Terry J.; Suljak, George T.; Misage, Robert J.

    1981-01-01

    To more uniformly distribute heat to the plurality of catalyst tubes in a catalytic reaction furnace, the burner disposed in the furnace above the tops of the tubes includes concentric primary and secondary annular fuel and air outlets. The fuel-air mixture from the primary outlet is directed towards the tubes adjacent the furnace wall, and the burning secondary fuel-air mixture is directed horizontally from the secondary outlet and a portion thereof is deflected downwardly by a slotted baffle toward the tubes in the center of the furnace while the remaining portion passes through the slotted baffle to another baffle disposed radially outwardly therefrom which deflects it downwardly in the vicinity of the tubes between those in the center and those near the wall of the furnace.

  4. Reverberatory screen for a radiant burner

    DOE Patents [OSTI]

    Gray, Paul E. (North East, MD)

    1999-01-01

    The present invention relates to porous mat gas fired radiant burner panels utilizing improved reverberatory screens. The purpose of these screens is to boost the overall radiant output of the burner relative to a burner using no screen and the same fuel-air flow rates. In one embodiment, the reverberatory screen is fabricated from ceramic composite material, which can withstand higher operating temperatures than its metallic equivalent. In another embodiment the reverberatory screen is corrugated. The corrugations add stiffness which helps to resist creep and thermally induced distortions due to temperature or thermal expansion coefficient differences. As an added benefit, it has been unexpectedly discovered that the corrugations further increase the radiant efficiency of the burner. In a preferred embodiment, the reverberatory screen is both corrugated and made from ceramic composite material.

  5. Check Burner Air to Fuel Ratios

    Broader source: Energy.gov [DOE]

    This tip sheet discusses when to check and reset burner air to fuel ratios as well as why it's a simply way to maximize the efficiency of process heating equipment.

  6. Silane-propane ignitor/burner

    DOE Patents [OSTI]

    Hill, R.W.; Skinner, D.F. Jr.; Thorsness, C.B.

    1983-05-26

    A silane propane burner for an underground coal gasification process which is used to ignite the coal and to controllably retract the injection point by cutting the injection pipe. A narrow tube with a burner tip is positioned in the injection pipe through which an oxidant (oxygen or air) is flowed. A charge of silane followed by a supply of fuel, such as propane, is flowed through the tube. The silane spontaneously ignites on contact with oxygen and burns the propane fuel.

  7. Silane-propane ignitor/burner

    DOE Patents [OSTI]

    Hill, Richard W. (Livermore, CA); Skinner, Dewey F. (Livermore, CA); Thorsness, Charles B. (Livermore, CA)

    1985-01-01

    A silane propane burner for an underground coal gasification process which is used to ignite the coal and to controllably retract the injection point by cutting the injection pipe. A narrow tube with a burner tip is positioned in the injection pipe through which an oxidant (oxygen or air) is flowed. A charge of silane followed by a supply of fuel, such as propane, is flowed through the tube. The silane spontaneously ignites on contact with oxygen and burns the propane fuel.

  8. NOx reduction in combustion with concentrated coal streams and oxygen injection

    DOE Patents [OSTI]

    Kobayashi, Hisashi; Bool, III, Lawrence E.; Snyder, William J.

    2004-03-02

    NOx formation in the combustion of solid hydrocarbonaceous fuel such as coal is reduced by obtaining, from the incoming feed stream of fuel solids and air, a stream having a ratio of fuel solids to air that is higher than that of the feed steam, and injecting the thus obtained stream and a small amount of oxygen to a burner where the fuel solids are combusted.

  9. Beijing LN Green Power Company | Open Energy Information

    Open Energy Info (EERE)

    Beijing LN Green Power Company Jump to: navigation, search Name: Beijing LN Green Power Company Place: Beijing, Beijing Municipality, China Zip: 100000 Sector: Vehicles Product:...

  10. Burners and combustion apparatus for carbon nanomaterial production

    DOE Patents [OSTI]

    Alford, J. Michael; Diener, Michael D; Nabity, James; Karpuk, Michael

    2013-02-05

    The invention provides improved burners, combustion apparatus, and methods for carbon nanomaterial production. The burners of the invention provide sooting flames of fuel and oxidizing gases. The condensable products of combustion produced by the burners of this invention produce carbon nanomaterials including without limitation, soot, fullerenic soot, and fullerenes. The burners of the invention do not require premixing of the fuel and oxidizing gases and are suitable for use with low vapor pressure fuels such as those containing substantial amounts of polyaromatic hydrocarbons. The burners of the invention can operate with a hot (e.g., uncooled) burner surface and require little, if any, cooling or other forms of heat sinking. The burners of the invention comprise one or more refractory elements forming the outlet of the burner at which a flame can be established. The burners of the invention provide for improved flame stability, can be employed with a wider range of fuel/oxidizer (e.g., air) ratios and a wider range of gas velocities, and are generally more efficient than burners using water-cooled metal burner plates. The burners of the invention can also be operated to reduce the formation of undesirable soot deposits on the burner and on surfaces downstream of the burner.

  11. Burners and combustion apparatus for carbon nanomaterial production

    DOE Patents [OSTI]

    Alford, J. Michael (Lakewood, CO); Diener, Michael D. (Denver, CO); Nabity, James (Arvada, CO); Karpuk, Michael (Boulder, CO)

    2007-10-09

    The invention provides improved burners, combustion apparatus, and methods for carbon nanomaterial production. The burners of the invention provide sooting flames of fuel and oxidizing gases. The condensable products of combustion produced by the burners of this invention produce carbon nanomaterials including without limitation, soot, fullerenic soot, and fullerenes. The burners of the invention do not require premixing of the fuel and oxidizing gases and are suitable for use with low vapor pressure fuels such as those containing substantial amounts of polyaromatic hydrocarbons. The burners of the invention can operate with a hot (e.g., uncooled) burner surface and require little, if any, cooling or other forms of heat sinking. The burners of the invention comprise one or more refractory elements forming the outlet of the burner at which a flame can be established. The burners of the invention provide for improved flame stability, can be employed with a wider range of fuel/oxidizer (e.g., air) ratios and a wider range of gas velocities, and are generally more efficient than burners using water-cooled metal burner plates. The burners of the invention can also be operated to reduce the formation of undesirable soot deposits on the burner and on surfaces downstream of the burner.

  12. DOE/NETL's advanced NOx emissions control technology R & D program

    SciTech Connect (OSTI)

    Lani, B.W.; Feeley, T.J. III; Miller, C.E.; Carney, B.A.; Murphy, J.T.

    2006-11-15

    Efforts are underway to provide more cost-effective options for coal-fired power plants to meet stringent emissions limits. Several recently completed DOE/NETL R & D projects were successful in achieving the short-term goal of controlling NOx emissions at 0.15 lb/MMBtu using in-furnace technologies. In anticipation of CAIR and possible congressional multi-pollutant legislation, DOE/NETL issued a solicitation in 2004 to continue R & D efforts to meet the 2007 goal and to initiate R & D targeting the 2010 goal of achieving 0.10 lb/MMBtu using in-furnace technologies in lieu of SCR. As a result, four new NOx R & D projects are currently underway and will be completed over the next three years. The article outlines: ALSTOM's Project on developing an enhanced combustion, low NOx burner for tangentially-fired boilers; Babcock and Wilcox's demonstration of an advanced NOx control technology to achieve an emission rate of 0.10 lb/MMBtu while burning bituminous coal for both wall- and cyclone-fired boilers; Reaction Engineering International's (REI) full-scale field testing of advanced layered technology application (ALTA) NOx control for cyclone fired boilers; and pilot-scale testing of ALTA NOx control of coal-fired boilers also by REI. DOE/NETL has begun an R & D effort to optimize performance of SCR controls to achieve the long term goal of 0.01 lb/MMBtu NOx emission rate by 2020. 1 fig.

  13. Low Emissions Burner Technology for Metal Processing Industry using Byproducts and Biomass Derived Liquid Fuels

    SciTech Connect (OSTI)

    Agrawal, Ajay; Taylor, Robert

    2013-09-30

    This research and development efforts produced low-emission burner technology capable of operating on natural gas as well as crude glycerin and/or fatty acids generated in biodiesel plants. The research was conducted in three stages (1) Concept definition leading to the design and development of a small laboratory scale burner, (2) Scale-up to prototype burner design and development, and (3) Technology demonstration with field vefiication. The burner design relies upon the Flow Blurring (FB) fuel injection based on aerodynamically creating two-phase flow near the injector exit. The fuel tube and discharge orifice both of inside diameter D are separated by gap H. For H < 0.25D, the atomizing air bubbles into liquid fuel to create a two-phase flow near the tip of the fuel tube. Pressurized two-phase fuel-air mixture exits through the discharge orifice, which results in expansion and breakup of air bubbles yielding a spray with fine droplets. First, low-emission combustion of diesel, biodiesel and straight VO (soybean oil) was achieved by utilizing FB injector to yield fine sprays for these fuels with significantly different physical properties. Visual images for these baseline experiments conducted with heat release rate (HRR) of about 8 kW illustrate clean blue flames indicating premixed combustion for all three fuels. Radial profiles of the product gas temperature at the combustor exit overlap each other signifying that the combustion efficiency is independent of the fuel. At the combustor exit, the NOx emissions are within the measurement uncertainties, while CO emissions are slightly higher for straight VO as compared to diesel and biodiesel. Considering the large variations in physical and chemical properties of fuels considered, the small differences observed in CO and NOx emissions show promise for fuel-flexible, clean combustion systems. FB injector has proven to be very effective in atomizing fuels with very different physical properties, and it offers a path forward to utilize both fossil and alternative liquid fuels in the same combustion system. In particular, experiments show that straight VO can be cleanly combusted without the need for chemical processing or preheating steps, which can result in significant economic and environmental benefits. Next, low-emission combustion of glycerol/methane was achieved by utilizing FB injector to yield fine droplets of highly viscous glycerol. Heat released from methane combustion further improves glycerol pre-vaporization and thus its clean combustion. Methane addition results in an intensified reaction zone with locally high temperatures near the injector exit. Reduction in methane flow rate elongates the reaction zone, which leads to higher CO emissions and lower NOx emissions. Similarly, higher air to liquid (ALR) mass ratio improves atomization and fuel pre-vaporization and shifts the flame closer to the injector exit. In spite of these internal variations, all fuel mixes of glycerol with methane produced similar CO and NOx emissions at the combustor exit. Results show that FB concept provides low emissions with the flexibility to utilize gaseous and highly viscous liquid fuels, straight VO and glycerol, without preheating or preprocessing the fuels. Following these initial experiments in quartz combustor, we demonstrated that glycerol combustion can be stably sustained in a metal combustor. Phase Doppler Particle Analyzer (PDPA) measurements in glycerol/methane flames resulted in flow-weighted Sauter Mean Diameter (SMD) of 35 to 40 μm, depending upon the methane percentage. This study verified that lab-scale dual-fuel burner using FB injector can successfully atomize and combust glycerol and presumably other highly viscous liquid fuels at relatively low HRR (<10 kW). For industrial applications, a scaled-up glycerol burner design thus seemed feasible.

  14. CLEERS Activities: Diesel Soot Filter Characterization & NOx...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Activities: Diesel Soot Filter Characterization & NOx Control Fundamentals CLEERS Activities: Diesel Soot Filter Characterization & NOx Control Fundamentals 2009 DOE Hydrogen...

  15. Sealed, nozzle-mix burners for silica deposition

    DOE Patents [OSTI]

    Adler, Meryle D. M.; Brown, John T.; Misra, Mahendra K.

    2003-07-08

    Burners (40) for producing fused silica boules are provided. The burners employ a tube-in-tube (301-306) design with flats (56, 50) on some of the tubes (305, 301) being used to limit the cross-sectional area of certain passages (206, 202) within the burner and/or to atomize a silicon-containing, liquid source material, such as OMCTS. To avoid the possibility of flashback, the burner has separate passages for fuel (205) and oxygen (204, 206), i.e., the burner employs nozzle mixing, rather than premixing, of the fuel and oxygen. The burners are installed in burner holes (26) formed in the crown (20) of a furnace and form a seal with those holes so that ambient air cannot be entrained into the furnace through the holes. An external air cooled jacket (60) can be used to hold the temperature of the burner below a prescribed upper limit, e.g., 400.degree. C.

  16. J.R. Simplot: Burner Upgrade Project Improves Performance and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    J.R. Simplot: Burner Upgrade Project Improves Performance and Saves Energy at a Large Food Processing Plant J.R. Simplot: Burner Upgrade Project Improves Performance and Saves ...

  17. Low NO.sub.x burner system

    DOE Patents [OSTI]

    Kitto, Jr., John B. (North Canton, OH); Kleisley, Roger J. (Plain Twp., Stark County, OH); LaRue, Albert D. (Summit, OH); Latham, Chris E. (Knox Twp., Columbiana County, OH); Laursen, Thomas A. (Canton, OH)

    1993-01-01

    A low NO.sub.x burner system for a furnace having spaced apart front and rear walls, comprises a double row of cell burners on each of the front and rear walls. Each cell burner is either of the inverted type with a secondary air nozzle spaced vertically below a coal nozzle, or the non-inverted type where the coal nozzle is below the secondary air port. The inverted and non-inverted cells alternate or are provided in other specified patterns at least in the lower row of cells. A small percentage of the total air can be also provided through the hopper or hopper throat forming the bottom of the furnace, or through the boiler hopper side walls. A shallow angle impeller design also advances the purpose of the invention which is to reduce CO and H.sub.2 S admissions while maintaining low NO.sub.x generation.

  18. Upgrade Boilers with Energy-Efficient Burners | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Upgrade Boilers with Energy-Efficient Burners Upgrade Boilers with Energy-Efficient Burners This tip sheet on upgrading boilers provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies. STEAM TIP SHEET #24 PDF icon Upgrade Boilers with Energy-Efficient Burners (January 2012) More Documents & Publications Improve Your Boiler's Combustion Efficiency Minimize Boiler Short Cycling Losses J.R. Simplot: Burner Upgrade Project Improves

  19. Fuel burner and combustor assembly for a gas turbine engine

    DOE Patents [OSTI]

    Leto, Anthony (Franklin Lakes, NJ)

    1983-01-01

    A fuel burner and combustor assembly for a gas turbine engine has a housing within the casing of the gas turbine engine which housing defines a combustion chamber and at least one fuel burner secured to one end of the housing and extending into the combustion chamber. The other end of the fuel burner is arranged to slidably engage a fuel inlet connector extending radially inwardly from the engine casing so that fuel is supplied, from a source thereof, to the fuel burner. The fuel inlet connector and fuel burner coact to anchor the housing against axial movement relative to the engine casing while allowing relative radial movement between the engine casing and the fuel burner and, at the same time, providing fuel flow to the fuel burner. For dual fuel capability, a fuel injector is provided in said fuel burner with a flexible fuel supply pipe so that the fuel injector and fuel burner form a unitary structure which moves with the fuel burner.

  20. Refinery burner simulation design architecture summary.

    SciTech Connect (OSTI)

    Pollock, Guylaine M.; McDonald, Michael James; Halbgewachs, Ronald D.

    2011-10-01

    This report describes the architectural design for a high fidelity simulation of a refinery and refinery burner, including demonstrations of impacts to the refinery if errors occur during the refinery process. The refinery burner model and simulation are a part of the capabilities within the Sandia National Laboratories Virtual Control System Environment (VCSE). Three components comprise the simulation: HMIs developed with commercial SCADA software, a PLC controller, and visualization software. All of these components run on different machines. This design, documented after the simulation development, incorporates aspects not traditionally seen in an architectural design, but that were utilized in this particular demonstration development. Key to the success of this model development and presented in this report are the concepts of the multiple aspects of model design and development that must be considered to capture the necessary model representation fidelity of the physical systems.

  1. PULSE DRYING EXPERIMENT AND BURNER CONSTRUCTION

    SciTech Connect (OSTI)

    Robert States

    2006-07-15

    Non steady impingement heat transfer is measured. Impingement heating consumes 130 T-BTU/Yr in paper drying, but is only 25% thermally efficient. Pulse impingement is experimentally shown to enhance heat transfer by 2.8, and may deliver thermal efficiencies near 85%. Experimental results uncovered heat transfer deviations from steady theory and from previous investigators, indicating the need for further study and a better theoretical framework. The pulse burner is described, and its roll in pulse impingement is analyzed.

  2. Measurement and Characterization of NOx Adsorber Regeneration...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Low-Temperature Combustion with Lean-NOx Trap Yields Progress Toward Targets of Efficient NOx Control for Diesels Intra-catalyst Reductant Chemistry in Lean NOx Traps: A Study ...

  3. Coal-water mixture fuel burner

    DOE Patents [OSTI]

    Brown, T.D.; Reehl, D.P.; Walbert, G.F.

    1985-04-29

    The present invention represents an improvement over the prior art by providing a rotating cup burner arrangement for use with a coal-water mixture fuel which applies a thin, uniform sheet of fuel onto the inner surface of the rotating cup, inhibits the collection of unburned fuel on the inner surface of the cup, reduces the slurry to a collection of fine particles upon discharge from the rotating cup, and further atomizes the fuel as it enters the combustion chamber by subjecting it to the high shear force of a high velocity air flow. Accordingly, it is an object of the present invention to provide for improved combustion of a coal-water mixture fuel. It is another object of the present invention to provide an arrangement for introducing a coal-water mixture fuel into a combustion chamber in a manner which provides improved flame control and stability, more efficient combustion of the hydrocarbon fuel, and continuous, reliable burner operation. Yet another object of the present invention is to provide for the continuous, sustained combustion of a coal-water mixture fuel without the need for a secondary combustion source such as natural gas or a liquid hydrocarbon fuel. Still another object of the present invention is to provide a burner arrangement capable of accommodating a coal-water mixture fuel having a wide range of rheological and combustion characteristics in providing for its efficient combustion. 7 figs.

  4. Global Nuclear Energy Partnership Fact Sheet - Develop Advanced Burner

    Energy Savers [EERE]

    Reactors | Department of Energy Develop Advanced Burner Reactors Global Nuclear Energy Partnership Fact Sheet - Develop Advanced Burner Reactors GNEP will develop and demonstrate Advanced Burner Reactors (ABRs) that consume transuranic elements (plutonium and other long-lived radioactive material) while extracting their energy. The development of ABRs will allow us to build an improved nuclear fuel cycle that recycles used fuel. Accordingly, the U.S. will work with participating

  5. Further improvement of conventional diesel NOx aftertreatment...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Further improvement of conventional diesel NOx aftertreatment concepts as pathway for SULEV Further improvement of conventional diesel NOx aftertreatment concepts as pathway for...

  6. Residential oil burners with low input and two stages firing

    SciTech Connect (OSTI)

    Butcher, T.; Krajewski, R.; Leigh, R.

    1997-12-31

    The residential oil burner market is currently dominated by the pressure-atomized, retention head burner. At low firing rates pressure atomizing nozzles suffer rapid fouling of the small internal passages, leading to bad spray patterns and poor combustion performance. To overcome the low input limitations of conventional burners, a low pressure air-atomized burner has been developed watch can operate at fining rates as low as 0.25 gallons of oil per hour (10 kW). In addition, the burner can be operated in a high/low fining rate mode. Field tests with this burner have been conducted at a fixed input rate of 0.35 gph (14 kW) with a side-wall vented boiler/water storage tank combination. At the test home, instrumentation was installed to measure fuel and energy flows and record trends in system temperatures. Laboratory efficiency testing with water heaters and boilers has been completed using standard single purpose and combined appliance test procedures. The tests quantify benefits due to low firing rates and other burner features. A two stage oil burner gains a strong advantage in rated efficiency while maintaining capacity for high domestic hot water and space heating loads.

  7. Ultra Low NOx Catalytic Combustion for IGCC Power Plants

    SciTech Connect (OSTI)

    Shahrokh Etemad; Benjamin Baird; Sandeep Alavandi; William Pfefferle

    2008-03-31

    In order to meet DOE's goals of developing low-emissions coal-based power systems, PCI has further developed and adapted it's Rich-Catalytic Lean-burn (RCL{reg_sign}) catalytic reactor to a combustion system operating on syngas as a fuel. The technology offers ultra-low emissions without the cost of exhaust after-treatment, with high efficiency (avoidance of after-treatment losses and reduced diluent requirements), and with catalytically stabilized combustion which extends the lower Btu limit for syngas operation. Tests were performed in PCI's sub-scale high-pressure (10 atm) test rig, using a two-stage (catalytic then gas-phase) combustion process for syngas fuel. In this process, the first stage consists of a fuel-rich mixture reacting on a catalyst with final and excess combustion air used to cool the catalyst. The second stage is a gas-phase combustor, where the air used for cooling the catalyst mixes with the catalytic reactor effluent to provide for final gas-phase burnout and dilution to fuel-lean combustion products. During testing, operating with a simulated Tampa Electric's Polk Power Station syngas, the NOx emissions program goal of less than 0.03 lbs/MMBtu (6 ppm at 15% O{sub 2}) was met. NOx emissions were generally near 0.01 lbs/MMBtu (2 ppm at 15% O{sub 2}) (PCI's target) over a range on engine firing temperatures. In addition, low emissions were shown for alternative fuels including high hydrogen content refinery fuel gas and low BTU content Blast Furnace Gas (BFG). For the refinery fuel gas increased resistance to combustor flashback was achieved through preferential consumption of hydrogen in the catalytic bed. In the case of BFG, stable combustion for fuels as low as 88 BTU/ft{sup 3} was established and maintained without the need for using co-firing. This was achieved based on the upstream catalytic reaction delivering a hotter (and thus more reactive) product to the flame zone. The PCI catalytic reactor was also shown to be active in ammonia reduction in fuel allowing potential reductions in the burner NOx production. These reductions of NOx emissions and expanded alternative fuel capability make the rich catalytic combustor uniquely situated to provide reductions in capital costs through elimination of requirements for SCR, operating costs through reduction in need for NOx abating dilution, SCR operating costs, and need for co-firing fuels allowing use of lower value but more available fuels, and efficiency of an engine through reduction in dilution flows.

  8. Transient Dynamometer Testing of a Single Leg NOx Adsorber Combined...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Single Leg NOx Adsorber Combined with a Fuel Processor for Enhanced NOx Control Transient Dynamometer Testing of a Single Leg NOx Adsorber Combined with a Fuel Processor for...

  9. Measurement and Characterization of Lean NOx Adsorber Regeneration...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Lean NOx Adsorber Regeneration and Desulfation and Controlling NOx from Multi-mode Measurement and Characterization of Lean NOx Adsorber Regeneration and Desulfation and...

  10. Parametric Study of NOx Adsorber Regeneration in Transient Cycles...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Parametric Study of NOx Adsorber Regeneration in Transient Cycles Parametric Study of NOx ... More Documents & Publications Combining Low-Temperature Combustion with Lean-NOx Trap ...

  11. Fuel burner having a intermittent pilot with pre-ignition testing

    SciTech Connect (OSTI)

    Peterson, S.M.

    1991-07-30

    This patent describes improvement in a fuel burner having a main burner and a pilot burner for lighting the main burner, an electrically-powered igniter for lighting the pilot burner, a source of electric energy, an igniter power supply receiving a demand signal and supplying power to the igniter responsive to the demand signal, a pilot sensor adjacent to the pilot burner and supplying a pilot signal responsive to presence of a pilot flame, and a main burner valve controlling flow of fuel to the main burner and opening responsive to the pilot signal. The improvement comprises: a pilot burner valve controlling flow of fuel to the pilot burner and opening responsive to a pilot valve control signal; igniter sensing means in sensing relation to the igniter for providing an igniter signal responsive to operation of the igniter; and pilot valve control means receiving the igniter signal, for providing the pilot valve control signal responsive to the igniter signal.

  12. Method for control of NOx emission from combustors using fuel dilution

    DOE Patents [OSTI]

    Schefer, Robert W. (Alamo, CA); Keller, Jay O (Oakland, CA)

    2007-01-16

    A method of controlling NOx emission from combustors. The method involves the controlled addition of a diluent such as nitrogen or water vapor, to a base fuel to reduce the flame temperature, thereby reducing NOx production. At the same time, a gas capable of enhancing flame stability and improving low temperature combustion characteristics, such as hydrogen, is added to the fuel mixture. The base fuel can be natural gas for use in industrial and power generation gas turbines and other burners. However, the method described herein is equally applicable to other common fuels such as coal gas, biomass-derived fuels and other common hydrocarbon fuels. The unique combustion characteristics associated with the use of hydrogen, particularly faster flame speed, higher reaction rates, and increased resistance to fluid-mechanical strain, alter the burner combustion characteristics sufficiently to allow operation at the desired lower temperature conditions resulting from diluent addition, without the onset of unstable combustion that can arise at lower combustor operating temperatures.

  13. Apparatus and method for burning a lean, premixed fuel/air mixture with low NOx emission

    DOE Patents [OSTI]

    Kostiuk, Larry W. (Edmonton, CA); Cheng, Robert K. (Kensington, CA)

    1996-01-01

    An apparatus for enabling a burner to stably burn a lean fuel/air mixture. The burner directs the lean fuel/air mixture in a stream. The apparatus comprises an annular flame stabilizer; and a device for mounting the flame stabilizer in the fuel/air mixture stream. The burner may include a body having an internal bore, in which case, the annular flame stabilizer is shaped to conform to the cross-sectional shape of the bore, is spaced from the bore by a distance greater than about 0.5 mm, and the mounting device mounts the flame stabilizer in the bore. An apparatus for burning a gaseous fuel with low NOx emissions comprises a device for premixing air with the fuel to provide a lean fuel/air mixture; a nozzle having an internal bore through which the lean fuel/air mixture passes in a stream; and a flame stabilizer mounted in the stream of the lean fuel/air mixture. The flame stabilizer may be mounted in the internal bore, in which case, it is shaped and is spaced from the bore as just described. In a method of burning a lean fuel/air mixture, a lean fuel/air mixture is provided, and is directed in a stream; an annular eddy is created in the stream of the lean fuel/air mixture; and the lean fuel/air mixture is ignited at the eddy.

  14. Low-Emissions Burner Technology using Biomass-Derived Liquid...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    This factsheet describes a project that developed fuel-flexible, low-emissions burner technology capable of using biomass-derived liquid fuels, such as glycerin or fatty acids, as ...

  15. SEP Success Story: Biomass Burner Cogenerates Jobs and Electricity...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Biomass Burner Cogenerates Jobs and Electricity from Lumber Mill Waste SEP Success Story: ... loan. | Courtesy of Helios USA, LLC. SEP Success Story: Not a Long Time Ago in an Energy ...

  16. NOx adsorber and method of regenerating same

    DOE Patents [OSTI]

    Endicott, Dennis L. (Peoria, IL); Verkiel, Maarten (Metamora, IL); Driscoll, James J. (Dunlap, IL)

    2007-01-30

    New technologies, such as NOx adsorber catalytic converters, are being used to meet increasingly stringent regulations on undesirable emissions, including NOx emissions. NOx adsorbers must be periodically regenerated, which requires an increased fuel consumption. The present disclosure includes a method of regenerating a NOx adsorber within a NOx adsorber catalytic converter. At least one sensor positioned downstream from the NOx adsorber senses, in the downstream exhaust, at least one of NOx, nitrous oxide and ammonia concentrations a plurality of times during a regeneration phase. The sensor is in communication with an electronic control module that includes a regeneration monitoring algorithm operable to end the regeneration phase when a time rate of change of the at least one of NOx, nitrous oxide and ammonia concentrations is after an expected plateau region begins.

  17. NOx sensor development | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    sensor development NOx sensor development PDF icon pm005_glass_2012_o.pdf More Documents & Publications NOxsensor development NOx Sensor Development Vehicle Technologies Office: 2013 Propulsion Materials R&D Annual Progress Report

  18. Pt-free, Perovskite-based Lean NOx Trap Catalysts

    Broader source: Energy.gov [DOE]

    Perovskite-based lean NOx catalysts shown to achieve comparable NOx reduction performance as commercial platinum based counterpart

  19. Scalable, Efficient Solid Waste Burner System - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Biomass and Biofuels Biomass and Biofuels Find More Like This Return to Search Scalable, Efficient Solid Waste Burner System Colorado State University Contact CSU About This Technology Technology Marketing Summary A system that effectively burns solid human waste where traditional waste management practices are not viable, such as forward-operation military bases. Description This innovation is a semi-gasifier, burner device to process solid waste, particularly solid human waste. Developed by

  20. SEP Success Story: Biomass Burner Cogenerates Jobs and Electricity from

    Energy Savers [EERE]

    Lumber Mill Waste | Department of Energy Biomass Burner Cogenerates Jobs and Electricity from Lumber Mill Waste SEP Success Story: Biomass Burner Cogenerates Jobs and Electricity from Lumber Mill Waste December 6, 2011 - 11:20am Addthis Dale and Sharon Borgford, small business owners in Stevens County, WA, break ground with Peter Goldmark, Washington State Commissioner of Public Lands. The pair brought more than 75 jobs to the area with help from DOE's State Energy Program and the U.S.

  1. Biomass Burner Cogenerates Jobs and Electricity from Lumber Mill Waste |

    Energy Savers [EERE]

    Department of Energy Burner Cogenerates Jobs and Electricity from Lumber Mill Waste Biomass Burner Cogenerates Jobs and Electricity from Lumber Mill Waste December 6, 2011 - 3:57pm Addthis Dale and Sharon Borgford, small business owners in Stevens County, WA, break ground with Peter Goldmark, Washington State Commissioner of Public Lands. The pair brought more than 75 jobs to the area with help from DOE's State Energy Program and the U.S. Forest Service. | Photo courtesy of Washington DNR.

  2. Advanced burner test reactor preconceptual design report.

    SciTech Connect (OSTI)

    Chang, Y. I.; Finck, P. J.; Grandy, C.; Cahalan, J.; Deitrich, L.; Dunn, F.; Fallin, D.; Farmer, M.; Fanning, T.; Kim, T.; Krajtl, L.; Lomperski, S.; Moisseytsev, A.; Momozaki, Y.; Sienicki, J.; Park, Y.; Tang, Y.; Reed, C.; Tzanos, C; Wiedmeyer, S.; Yang, W.; Chikazawa, Y.; JAEA

    2008-12-16

    The goals of the Global Nuclear Energy Partnership (GNEP) are to expand the use of nuclear energy to meet increasing global energy demand, to address nuclear waste management concerns and to promote non-proliferation. Implementation of the GNEP requires development and demonstration of three major technologies: (1) Light water reactor (LWR) spent fuel separations technologies that will recover transuranics to be recycled for fuel but not separate plutonium from other transuranics, thereby providing proliferation-resistance; (2) Advanced Burner Reactors (ABRs) based on a fast spectrum that transmute the recycled transuranics to produce energy while also reducing the long term radiotoxicity and decay heat loading in the repository; and (3) Fast reactor fuel recycling technologies to recover and refabricate the transuranics for repeated recycling in the fast reactor system. The primary mission of the ABR Program is to demonstrate the transmutation of transuranics recovered from the LWR spent fuel, and hence the benefits of the fuel cycle closure to nuclear waste management. The transmutation, or burning of the transuranics is accomplished by fissioning and this is most effectively done in a fast spectrum. In the thermal spectrum of commercial LWRs, some transuranics capture neutrons and become even heavier transuranics rather than being fissioned. Even with repeated recycling, only about 30% can be transmuted, which is an intrinsic limitation of all thermal spectrum reactors. Only in a fast spectrum can all transuranics be effectively fissioned to eliminate their long-term radiotoxicity and decay heat. The Advanced Burner Test Reactor (ABTR) is the first step in demonstrating the transmutation technologies. It directly supports development of a prototype full-scale Advanced Burner Reactor, which would be followed by commercial deployment of ABRs. The primary objectives of the ABTR are: (1) To demonstrate reactor-based transmutation of transuranics as part of an advanced fuel cycle; (2) To qualify the transuranics-containing fuels and advanced structural materials needed for a full-scale ABR; and (3) To support the research, development and demonstration required for certification of an ABR standard design by the U.S. Nuclear Regulatory Commission. The ABTR should also address the following additional objectives: (1) To incorporate and demonstrate innovative design concepts and features that may lead to significant improvements in cost, safety, efficiency, reliability, or other favorable characteristics that could promote public acceptance and future private sector investment in ABRs; (2) To demonstrate improved technologies for safeguards and security; and (3) To support development of the U.S. infrastructure for design, fabrication and construction, testing and deployment of systems, structures and components for the ABRs. Based on these objectives, a pre-conceptual design of a 250 MWt ABTR has been developed; it is documented in this report. In addition to meeting the primary and additional objectives listed above, the lessons learned from fast reactor programs in the U.S. and worldwide and the operating experience of more than a dozen fast reactors around the world, in particular the Experimental Breeder Reactor-II have been incorporated into the design of the ABTR to the extent possible.

  3. Compact Potentiometric NOx Sensor | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    1 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation PDF icon pm023_singh_2011_p.pdf More Documents & Publications Compact Potentiometric O2/NOx Sensor Compact Potentiometric NOx Sensor Compact Potentiometric NOx

  4. Compact Potentiometric NOx Sensor | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    0 DOE Vehicle Technologies and Hydrogen Programs Annual Merit Review and Peer Evaluation Meeting, June 7-11, 2010 -- Washington D.C. PDF icon pm023_singh_2010_p.pdf More Documents & Publications Compact Potentiometric NOx Sensor Compact Potentiometric NOx Sensor Compact Potentiometric O2/NOx

  5. Compact Potentiometric NOx Sensor | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    09 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C. PDF icon pmp_16_singh.pdf More Documents & Publications Compact Potentiometric NOx Sensor Compact Potentiometric O2/NOx Sensor Compact Potentiometric NOx

  6. Durability of NOx Absorbers | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of NOx Absorbers Durability of NOx Absorbers 2002 DEER Conference Presentation: EmeraChem LLC PDF icon 2002_deer_parks.pdf More Documents & Publications Cleaner Vehicles, Cleaner Fuel & Cleaner Air APBF-DEC Heavy Duty NOx Adsorber/DPF Project: Heavy Duty Linehaul Platform Project Update LNT + SCR Aftertreatment for Medium-Heavy Duty Applications: A Systems Approach

  7. Dual-water mixture fuel burner

    DOE Patents [OSTI]

    Brown, Thomas D. (Finleyville, PA); Reehl, Douglas P. (Pittsburgh, PA); Walbert, Gary F. (Library, PA)

    1986-08-05

    A coal-water mixture (CWM) burner includes a conically shaped rotating cup into which fuel comprised of coal particles suspended in a slurry is introduced via a first, elongated inner tube coupled to a narrow first end portion of the cup. A second, elongated outer tube is coaxially positioned about the first tube and delivers steam to the narrow first end of the cup. The fuel delivery end of the inner first tube is provided with a helical slot on its lateral surface for directing the CWM onto the inner surface of the rotating cup in the form of a uniform, thin sheet which, under the influence of the cup's centrifugal force, flows toward a second, open, expanded end portion of the rotating cup positioned immediately adjacent to a combustion chamber. The steam delivered to the rotating cup wets its inner surface and inhibits the coal within the CWM from adhering to the rotating cup. A primary air source directs a high velocity air flow coaxially about the expanded discharge end of the rotating cup for applying a shear force to the CWM in atomizing the fuel mixture for improved combustion. A secondary air source directs secondary air into the combustion chamber adjacent to the outlet of the rotating cup at a desired pitch angle relative to the fuel mixture/steam flow to promote recirculation of hot combustion gases within the ignition zone for increased flame stability.

  8. Method And Apparatus For Regenerating Nox Adsorbers

    DOE Patents [OSTI]

    Driscoll, J. Joshua (Dunlap, IL); Endicott, Dennis L. (Peoria, IL); Faulkner, Stephen A. (Stamford, GB); Verkiel, Maarten (Metamora, IL)

    2006-03-28

    Methods and apparatuses for regenerating a NOx adsorber coupled with an exhaust of an engine. An actuator drives a throttle valve to a first position when regeneration of the NOx adsorber is desired. The first position is a position that causes the regeneration of the NOx adsorber. An actuator drives the throttle valve to a second position while regeneration of the NOx adsorber is still desired. The second position being a position that is more open than the first position and operable to regenerate a NOx adsorber.

  9. Controlling NOx emission from industrial sources

    SciTech Connect (OSTI)

    Srivastava, R.K.; Nueffer, W.; Grano, D.; Khan, S.; Staudt, J.E.; Jozewicz, W.

    2005-07-01

    A number of regulatory actions focused on reducing NOx emissions from stationary combustion sources have been taken in the United States in the last decade. These actions include the Acid Rain NOx regulations, the Ozone Transport Commission's NOx Budget Program, and the NOx SIP Call rulemakings. In addition to these regulations, the recent Interstate Air Quality Rulemaking proposal and other bills in the Congress are focusing on additional reductions of NOx. Industrial combustion sources accounted for about 18016 of NOx emissions in the United States in 2000 and constituted the second largest emitting source category within stationary sources, only behind electric utility sources. Based on these data, reduction of NOx emissions from industrial combustion sources is an important consideration in efforts undertaken to address the environmental concerns associated with NOx. This paper discusses primary and secondary NOx control technologies applicable to various major categories of industrial sources. The sources considered in this paper include large boilers, furnaces and fired heaters, combustion turbines, large IC engines, and cement kilns. For each source category considered in this paper, primary NOx controls are discussed first, followed by a discussion of secondary NOx controls.

  10. Advanced Burner Reactor Preliminary NEPA Data Study.

    SciTech Connect (OSTI)

    Briggs, L. L.; Cahalan, J. E.; Deitrich, L. W.; Fanning, T. H.; Grandy, C.; Kellogg, R.; Kim, T. K.; Yang, W. S.; Nuclear Engineering Division

    2007-10-15

    The Global Nuclear Energy Partnership (GNEP) is a new nuclear fuel cycle paradigm with the goals of expanding the use of nuclear power both domestically and internationally, addressing nuclear waste management concerns, and promoting nonproliferation. A key aspect of this program is fast reactor transmutation, in which transuranics recovered from light water reactor spent fuel are to be recycled to create fast reactor transmutation fuels. The benefits of these fuels are to be demonstrated in an Advanced Burner Reactor (ABR), which will provide a representative environment for recycle fuel testing, safety testing, and modern fast reactor design and safeguard features. Because the GNEP programs will require facilities which may have an impact upon the environment within the meaning of the National Environmental Policy Act of 1969 (NEPA), preparation of a Programmatic Environmental Impact Statement (PEIS) for GNEP is being undertaken by Tetra Tech, Inc. The PEIS will include a section on the ABR. In support of the PEIS, the Nuclear Engineering Division of Argonne National Laboratory has been asked to provide a description of the ABR alternative, including graphics, plus estimates of construction and operations data for an ABR plant. The compilation of this information is presented in the remainder of this report. Currently, DOE has started the process of engaging industry on the design of an Advanced Burner Reactor. Therefore, there is no specific, current, vendor-produced ABR design that could be used for this PEIS datacall package. In addition, candidate sites for the ABR vary widely as to available water, geography, etc. Therefore, ANL has based its estimates for construction and operations data largely on generalization of available information from existing plants and from the environmental report assembled for the Clinch River Breeder Reactor Plant (CRBRP) design [CRBRP, 1977]. The CRBRP environmental report was chosen as a resource because it thoroughly documents the extensive evaluation which was performed on the anticipated environmental impacts of that plant. This source can be referenced in the open literature and is publicly available. The CRBRP design was also of a commercial demonstration plant size - 975 MWth - which falls in the middle of the range of ABR plant sizes being considered (250 MWth to 2000 MWth). At the time the project was cancelled, the CRBRP had progressed to the point of having completed the licensing application to the Nuclear Regulatory Commission (NRC) and was in the process of receiving NRC approval. Therefore, it was felt that [CRBRP, 1977] provides some of the best available data and information as input to the GNEP PEIS work. CRBRP was not the source of all the information in this document. It is also expected that the CRBRP data will be bounding from the standpoint of commodity usage because fast reactor vendors will develop designs which will focus on commodity and footprint reduction to reduce the overall cost per kilowatt electric compared with the CRBR plant. Other sources used for this datacall information package are explained throughout this document and in Appendix A. In particular, see Table A.1 for a summary of the data sources used to generate the datacall information.

  11. Flame quality monitor system for fixed firing rate oil burners

    DOE Patents [OSTI]

    Butcher, Thomas A.; Cerniglia, Philip

    1992-01-01

    A method and apparatus for determining and indicating the flame quality, or efficiency of the air-fuel ratio, in a fixed firing rate heating unit, such as an oil burning furnace, is provided. When the flame brightness falls outside a preset range, the flame quality, or excess air, has changed to the point that the unit should be serviced. The flame quality indicator output is in the form of lights mounted on the front of the unit. A green light indicates that the flame is about in the same condition as when the burner was last serviced. A red light indicates a flame which is either too rich or too lean, and that servicing of the burner is required. At the end of each firing cycle, the flame quality indicator goes into a hold mode which is in effect during the period that the burner remains off. A yellow or amber light indicates that the burner is in the hold mode. In this mode, the flame quality lights indicate the flame condition immediately before the burner turned off. Thus the unit can be viewed when it is off, and the flame condition at the end of the previous firing cycle can be observed.

  12. Slurry burner for mixture of carbonaceous material and water

    DOE Patents [OSTI]

    Nodd, D.G.; Walker, R.J.

    1985-11-05

    The present invention is intended to overcome the limitations of the prior art by providing a fuel burner particularly adapted for the combustion of carbonaceous material-water slurries which includes a stationary high pressure tip-emulsion atomizer which directs a uniform fuel into a shearing air flow as the carbonaceous material-water slurry is directed into a combustion chamber, inhibits the collection of unburned fuel upon and within the atomizer, reduces the slurry to a collection of fine particles upon discharge into the combustion chamber, and regulates the operating temperature of the burner as well as primary air flow about the burner and into the combustion chamber for improved combustion efficiency, no atomizer plugging and enhanced flame stability.

  13. Study of oil combustion in the TGMP-314 boiler with hearth burners

    SciTech Connect (OSTI)

    Usman, Yu.M.; Shtal'man, S.G.; Enyakin, Yu.P.; Abryutin, A.A.; Levin, M.M.; Taran, O.E.; Chuprov, V.V.; Antonov, A.Yu.

    1983-01-01

    Studies of the TGMP-314 boiler with hearth configured burners included the gas mixture in the boiler, the degree of fuel combustion at various heights in the boiler, hydrogen sulfide content in the near-wall zones of the boiler, and temperature distribution fields. Experimental data showed that the hearth burners, in conjunction with steam-mechanical atomizing burners, operate with the least possible excess air over a wide range of load changes. The operation and performance of the hearth burners are discussed.

  14. Low-Emissions Burner Technology using Biomass-Derived Liquid Fuels

    Broader source: Energy.gov [DOE]

    Factsheet summarizing Univ. of Alabama project to save energy and reduce emissions with fuel-flexible burners

  15. Development of quick repairing technique for ceramic burner in hot stove of blast furnace

    SciTech Connect (OSTI)

    Kondo, Atsushi; Doura, Kouji; Nakamura, Hirofumi

    1997-12-31

    Refractories of ceramic burner in hot stoves at Wakayama No. 4 blast furnace were damaged. There are only three hot stoves, so repairing must be done in a short. Therefore, a quick repairing technique for ceramic burners has been developed, and two ceramic burners were repaired in just 48 hours.

  16. Ammonia-Free NOx Control System

    SciTech Connect (OSTI)

    Song Wu; Zhen Fan; Andrew H. Seltzer

    2005-06-30

    Research is being conducted under United States Department of Energy (DOE) Contract DEFC26-03NT41865 to develop a new technology to achieve very low levels of NOx emissions from pulverized coal fired boiler systems by employing a novel system level integration between the PC combustion process and the catalytic NOx reduction with CO present in the combustion flue gas. The combustor design and operating conditions will be optimized to achieve atypical flue gas conditions. This approach will not only suppress NOx generation during combustion but also further reduce NOx over a downstream catalytic reactor that does not require addition of an external reductant, such as ammonia.

  17. Investigation on continuous soot oxidation and NOx reduction...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    on continuous soot oxidation and NOx reduction by SCR coated DPF Investigation on continuous soot oxidation and NOx reduction by SCR coated DPF Evaluation of CSI catalyst for NOx...

  18. VARIABLE FIRING RATE OIL BURNER USING PULSE FUEL FLOW CONTROL.

    SciTech Connect (OSTI)

    KRISHNA,C.R.; BUTCHER,T.A.; KAMATH,B.R.

    2004-10-01

    The residential oil burner market is currently dominated by the pressure-atomized retention head burner, which has an excellent reputation for reliability and efficiency. In this burner, oil is delivered to a fuel nozzle at pressures from 100 to 150 psi. In addition, to atomizing the fuel, the small, carefully controlled size of the nozzle exit orifice serves to control the burner firing rate. Burners of this type are currently available at firing rates of more than 0.5 gallons-per-hour (70,000 Btu/hr). Nozzles have been made for lower firing rates, but experience has shown that such nozzles suffer rapid fouling of the necessarily small passages, leading to bad spray patterns and poor combustion performance. Also, traditionally burners and the nozzles are oversized to exceed the maximum demand. Typically, this is figured as follows. The heating load of the house on the coldest day for the location is considered to define the maximum heat load. The contractor or installer adds to this to provide a safety margin and for future expansion of the house. If the unit is a boiler that provides domestic hot water through the use of a tankless heating coil, the burner capacity is further increased. On the contrary, for a majority of the time, the heating system is satisfying a much smaller load, as only rarely do all these demands add up. Consequently, the average output of the heating system has to be much less than the design capacity and this is accomplished by start and stop cycling operation of the system so that the time-averaged output equals the demand. However, this has been demonstrated to lead to overall efficiencies lower than the steady-state efficiency. Therefore, the two main reasons for the current practice of using oil burners much larger than necessary for space heating are the unavailability of reliable low firing rate oil burners and the desire to assure adequate input rate for short duration, high draw domestic hot water loads. One approach to solve this problem is to develop a burner, which can operate at two firing rates, with the lower rate being significantly lower than 0.5 gallons per hour. This paper describes the initial results of adopting this approach through a pulsed flow nozzle. It has been shown that the concept of flow modulation with a small solenoid valve is feasible. Especially in the second configuration tested, where the Lee valve was integrated with the nozzle, reasonable modulation in flow of the order of 1.7 could be achieved. For this first prototype, the combustion performance is still not quite satisfactory. Improvements in operation, for example by providing a sharp and positive shut-off so that there is no flow under low pressures with consequent poor atomization could lead to better combustion performance. This could be achieved by using nozzles that have shut off or check valves for example. It is recommended that more work in cooperation with the valve manufacturer could produce a technically viable system. Marketability is of course a far more complex problem to be addressed once a technically viable product is available.

  19. Reduce NOx and Improve Energy Efficiency

    SciTech Connect (OSTI)

    2005-05-01

    The U.S. Department of Energy's NOx and Energy Assessment Tool (NxEAT) is available at no charge to help the petroleum refining and chemicals industries develop a cost-effective, plant-wide strategy for NOx reduction and energy efficiency improvements.

  20. An Experimental Investigation of the Origin of Increased NOx...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Origin of Increased NOx Emissions When Fueling a Heavy-Duty Compression-Ignition Engine with Soy Biodiesel An Experimental Investigation of the Origin of Increased NOx Emissions ...

  1. Dynamometer Evaluation of Plasma-Catalyst for Diesel NOx Reduction...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Evaluation of Plasma-Catalyst for Diesel NOx Reduction Dynamometer Evaluation of Plasma-Catalyst for Diesel NOx Reduction 2003 DEER Conference Presentation: Ford Motor Company PDF...

  2. Selective reduction of NOx in oxygen rich environments with plasma...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    reduction of NOx in oxygen rich environments with plasma-assisted catalysis: Catalyst development and mechanistic studies Selective reduction of NOx in oxygen rich environments...

  3. Retrofit Diesel Emissions Control System Providing 50% NOxControl...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Diesel Emissions Control System Providing 50% NOxControl Retrofit Diesel Emissions Control System Providing 50% NOxControl 2005 Diesel Engine Emissions Reduction (DEER) Conference...

  4. Understanding NOx SCR Mechanism and Activity on Cu/Chabazite...

    Office of Scientific and Technical Information (OSTI)

    Book: Understanding NOx SCR Mechanism and Activity on CuChabazite Structures throughout the Catalyst Life Cycle Citation Details In-Document Search Title: Understanding NOx SCR...

  5. Oxidation State Optimization for Maximum Efficiency of NOx Adsorber...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    State Optimization for Maximum Efficiency of NOx Adsorber Catalysts Oxidation State Optimization for Maximum Efficiency of NOx Adsorber Catalysts Presentation given at the 16th...

  6. Power Generating Stationary Engines Nox Control: A Closed Loop...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Generating Stationary Engines Nox Control: A Closed Loop Control Technology Power Generating Stationary Engines Nox Control: A Closed Loop Control Technology Poster presented at...

  7. Monolithic Metal Oxide based Composite Nanowire Lean NOx Emission...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Monolithic Metal Oxide based Composite Nanowire Lean NOx Emission Control Catalysts Monolithic Metal Oxide based Composite Nanowire Lean NOx Emission Control Catalysts Presents...

  8. Fuel Processor Enabled NOx Adsorber Aftertreatment System for...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Processor Enabled NOx Adsorber Aftertreatment System for Diesel Engine Emissions Control Fuel Processor Enabled NOx Adsorber Aftertreatment System for Diesel Engine Emissions...

  9. Three-Dimensional Composite Nanostructures for Lean NOx Emission...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Monolithic Metal Oxide based Composite Nanowire Lean NOx Emission Control Catalysts Three-Dimensional Composite Nanostructures for Lean NOx...

  10. H2-Assisted NOx Traps: Test Cell Results Vehicle Installations...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    -Assisted NOx Traps: Test Cell Results Vehicle Installations H2-Assisted NOx Traps: Test Cell Results Vehicle Installations 2003 DEER Conference Presentation: ArvinMeritor PDF icon...

  11. Cost Analysis of NOx Control Alternatives for Stationary Gas...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Cost Analysis of NOx Control Alternatives for Stationary Gas Turbines, November 1999 Cost Analysis of NOx Control Alternatives for Stationary Gas Turbines, November 1999 The use of...

  12. Selectlive Catalytic Reducution of NOx wilth Diesel-Based Fuels...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Selectlive Catalytic Reducution of NOx wilth Diesel-Based Fuels as Reductants Selectlive Catalytic Reducution of NOx wilth Diesel-Based Fuels as Reductants 2005 Diesel Engine...

  13. Three-Dimensional Composite Nanostructures for Lean NOx Emission...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Three-Dimensional Composite Nanostructures for Lean NOx Emission Control Monolithic Metal Oxide based Composite Nanowire Lean NOx Emission...

  14. The Impact of Lubricant Formulation on the Performance of NOx...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Formulation on the Performance of NOx Adsorber Catalysts The Impact of Lubricant Formulation on the Performance of NOx Adsorber Catalysts PDF icon 2005deerwhitacre.pdf More...

  15. Transmural Catalysis - High Efficiency Catalyst Systems for NOx...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Transmural Catalysis - High Efficiency Catalyst Systems for NOx Adsorbers and SCR Transmural Catalysis - High Efficiency Catalyst Systems for NOx Adsorbers and SCR Presentation...

  16. Functionality of Commercial NOx Storage-Reduction Catalysts and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Functionality of Commercial NOx Storage-Reduction Catalysts and the Development of a Representative Model Functionality of Commercial NOx Storage-Reduction Catalysts and the...

  17. A Systematic Investigation of Parameters Affecting Diesel NOx...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    A Systematic Investigation of Parameters Affecting Diesel NOx Adsorber Catalyst Performance A Systematic Investigation of Parameters Affecting Diesel NOx Adsorber Catalyst...

  18. Enhanced High and Low Temperature Performance of NOx Reduction...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Low Temperature Performance of NOx Reduction Materials Enhanced High and Low Temperature Performance of NOx Reduction Materials 2013 DOE Hydrogen and Fuel Cells Program and...

  19. Durability Evaluation of an Integrated Diesel NOx Adsorber A...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Evaluation of an Integrated Diesel NOx Adsorber AT Subsystem at Light-Duty Operation Durability Evaluation of an Integrated Diesel NOx Adsorber AT Subsystem at Light-Duty ...

  20. Development of Remove Sensing Instrumentation for NOx and PM...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Development of Remove Sensing Instrumentation for NOx and PM Emissions from Heavy Duty Trucks Development of Remove Sensing Instrumentation for NOx and PM Emissions from Heavy Duty ...

  1. Cummins/ORNL-FEERC CRADA: NOx Control & Measurement Technology...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications CumminsORNL-FEERC CRADA: NOx Control & Measurement Technology for Heavy-Duty Diesel Engines CumminsORNL-FEERC CRADA: NOx Control &...

  2. Enhanced High Temperature Performance of NOx Storage/Reduction...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Enhanced High Temperature Performance of NOx StorageReduction (NSR) Materials Enhanced High Temperature Performance of NOx StorageReduction (NSR) ...

  3. Enhanced High Temperature Performance of NOx Storage/Reduction...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Enhanced High and Low Temperature Performance of NOx Reduction Materials Enhanced High Temperature Performance of NOx StorageReduction (NSR) ...

  4. Two Catalyst Formulations - One Solution for NOx After-treatment...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Catalyst Formulations - One Solution for NOx After-treatment Systems Two Catalyst Formulations - One Solution for NOx After-treatment Systems Low-temperature SCR combined with...

  5. Deactivation mechanisms of NOx storage materials arising from...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    mechanisms of NOx storage materials arising from thermal aging and sulfur poisoning Deactivation mechanisms of NOx storage materials arising from thermal aging and sulfur poisoning...

  6. Antiferromagnetic transitions of osmium-containing rare earth double perovskites Ba{sub 2}LnOsO{sub 6} (Ln=rare earths)

    SciTech Connect (OSTI)

    Hinatsu, Yukio Doi, Yoshihiro; Wakeshima, Makoto

    2013-10-15

    The perovskite-type compounds containing both rare earth and osmium Ba{sub 2}LnOsO{sub 6} (Ln=Pr, Nd, SmLu) have been prepared. Powder X-ray diffraction measurements and Rietveld analysis show that Ln{sup 3+} and Os{sup 5+} ions are structurally ordered at the M site of the perovskite BaMO{sub 3}. Magnetic susceptibility and specific heat measurements show that an antiferromagnetic ordering of Os{sup 5+} ions has been observed for Ba{sub 2}LnOsO{sub 6} (Ln=Pr, Nd, Sm, Eu, Gd, Lu) at 6571 K. Magnetic ordering of Ln{sup 3+} moments occurs when the temperature is furthermore decreased. - Graphical abstract: The perovskite-type compounds containing both rare earth and osmium Ba{sub 2}LnOsO{sub 6} (Ln=Pr, Nd, SmLu) have been prepared. An antiferromagnetic ordering of Os{sup 5+} ions has been observed for Ba{sub 2}LnOsO{sub 6} (Ln=Pr, Nd, Sm, Eu, Gd, Lu) at 6571 K. Measurements and analysis of the specific heat for Ba{sub 2}PrOsO{sub 6} show that magnetic ordering of the Pr{sup 3+} moments should have occurred at ?20 K. Display Omitted.

  7. The zero age main sequence of WIMP burners

    SciTech Connect (OSTI)

    Fairbairn, Malcolm; Scott, Pat; Edsjoe, Joakim

    2008-02-15

    We modify a stellar structure code to estimate the effect upon the main sequence of the accretion of weakly-interacting dark matter onto stars and its subsequent annihilation. The effect upon the stars depends upon whether the energy generation rate from dark matter annihilation is large enough to shut off the nuclear burning in the star. Main sequence weakly-interacting massive particles (WIMP) burners look much like proto-stars moving on the Hayashi track, although they are in principle completely stable. We make some brief comments about where such stars could be found, how they might be observed and more detailed simulations which are currently in progress. Finally we comment on whether or not it is possible to link the paradoxically hot, young stars found at the galactic center with WIMP burners.

  8. Downhole burner systems and methods for heating subsurface formations

    DOE Patents [OSTI]

    Farmayan, Walter Farman (Houston, TX); Giles, Steven Paul (Damon, TX); Brignac, Jr., Joseph Phillip (Katy, TX); Munshi, Abdul Wahid (Houston, TX); Abbasi, Faraz (Sugarland, TX); Clomburg, Lloyd Anthony (Houston, TX); Anderson, Karl Gregory (Missouri City, TX); Tsai, Kuochen (Katy, TX); Siddoway, Mark Alan (Katy, TX)

    2011-05-31

    A gas burner assembly for heating a subsurface formation includes an oxidant conduit, a fuel conduit, and a plurality of oxidizers coupled to the oxidant conduit. At least one of the oxidizers includes a mix chamber for mixing fuel from the fuel conduit with oxidant from the oxidant conduit, an igniter, and a shield. The shield includes a plurality of openings in communication with the oxidant conduit. At least one flame stabilizer is coupled to the shield.

  9. Compact Potentiometric O2/NOx Sensor | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    O2/NOx Sensor Compact Potentiometric O2/NOx Sensor 2012 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting PDF icon pm043_singh_2012_o.pdf More Documents & Publications Compact Potentiometric NOx Sensor Compact Potentiometric NOx

  10. Electrochemical NOxSensor for Monitoring Diesel Emissions | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy NOxSensor for Monitoring Diesel Emissions Electrochemical NOxSensor for Monitoring Diesel Emissions PDF icon pm_02_glass.pdf More Documents & Publications NOxsensor development Electrochemical NOx Sensors for Monitoring Diesel Emissions NOx Sensor Development

  11. Influence of Ceria on the NOx Storage/Reduction Behavior of Lean NOx Trap Catalysts

    SciTech Connect (OSTI)

    Ji, Yaying; Choi, Jae-Soon; Toops, Todd J; Crocker, Dr. Mark; Naseri, Mojghan

    2008-01-01

    The effect of La2O3-stabilized ceria incorporation on the functioning of fully formulated lean NOx trap catalysts was investigated. Monolithic catalysts were prepared, corresponding to loadings of 0, 50 and 100 g CeO2/L, together with a catalyst containing 100 g/L of ceria-zirconia (Ce0.7Zr0.3O2). Loadings of the other main components (Pt, Rh and BaO) were held constant. Catalyst evaluation was performed on a bench flow reactor under simulated diesel exhaust conditions, employing NOx storage/reduction cycles. NOx storage efficiency in the temperature range 150-350 C was observed to increase with ceria loading, resulting in higher NOx conversion levels. At 150 C, high rich phase NOx slip was observed for all of the catalysts, resulting from an imbalance in the rates of nitrate decomposition and NOx reduction. Optimal NOx conversion was obtained in the range 250-350 C for all the catalysts, while at 450 C high rich phase NOx slip from the most highly loaded ceria-containing catalyst resulted in lower NOx conversion than for the ceria-free formulation. N2O was the major NOx reduction product at 150 C over all of the catalysts, although low NOx conversion levels limited the N2O yield. At higher temperatures N2 was the main product of NOx reduction, although NH3 formation was also observed. Selectivity to NH3 decreased with increasing ceria loading, indicating that NH3 is consumed by reaction with stored oxygen in the rear of the catalyst.

  12. Effect of reductive treatments on Pt behavior and NOx storage in lean NOx trap catalysts

    SciTech Connect (OSTI)

    Wang, Xianqin; Kim, Do Heui; Kwak, Ja Hun; Wang, Chong M.; Szanyi, Janos; Peden, Charles HF

    2011-10-01

    Lean NOx trap (LNT) catalysts represent a promising approach to meet increasingly stringent NOx emission regulations on diesel and other lean-burn engines. Pt material properties, including dispersion and particle size, are known to be important factors in determining NOx uptake performance, since Pt provides active sites for NO oxidation to NO2 necessary for storing NOx as nitrates, and for the reduction of nitrates to N2. In this work, the physicochemical properties of Pt in Pt-BaO/Al2O3 LNT catalysts, such as the Pt accessible surface area and particle size, were investigated by using various tools, such as irreversible volumetric H2 chemisorption, high resolution transmission electron microscopy (HRTEM), and X-ray diffraction (XRD), following successive reductive treatments at elevated temperatures. NOx uptake activities were also measured to establish a relationship between the properties of Pt and NOx storage following identical high-temperature reductive treatments. We find that the reductive treatments of Pt-BaO/Al2O3 lean NOx trap catalysts at temperatures up to 500 C promote a significant increase in NOx uptake explained, in part, by an induced close interaction between Pt and BaO phases in the catalyst, thus enabling facilitation of the NOx storage process.

  13. Ammonia-Free NOx Control System

    SciTech Connect (OSTI)

    Zhen Fan; Song Wu; Richard G. Herman

    2004-06-30

    Research is being conducted under United States Department of Energy (DOE) Contract DEFC26-03NT41865 to develop a new technology to achieve very low levels of NOx emissions from pulverized coal fired boiler systems by employing a novel system level integration between the PC combustion process and the catalytic NOx reduction with CO present in the combustion flue gas. The combustor design and operating conditions will be optimized to achieve atypical flue gas conditions. This approach will not only suppress NOx generation during combustion but also further reduce NOx over a downstream catalytic reactor that does not require addition of an external reductant, such as ammonia. This report describes the work performed during the April 1 to June 30, 2004 time period.

  14. NOX: An Object-Oriented Nonlinear Solver

    Energy Science and Technology Software Center (OSTI)

    2002-11-15

    NOX is a C++ object-oriented library for the solving nonlinear equations. It can be used with an linear algebra package and includes interfaces to Epetra and PETSc.

  15. Ammonia-Free NOx Control System

    SciTech Connect (OSTI)

    Song Wu; Zhen Fan; Andrew H. Seltzer

    2005-09-30

    Research is being conducted under United States Department of Energy (DOE) Contract DEFC26-03NT41865 to develop a new technology to achieve very low levels of NOx emissions from pulverized coal fired boiler systems by employing a novel system level integration between the PC combustion process and the catalytic NOx reduction with CO present in the combustion flue gas. The combustor design and operating conditions will be optimized to achieve atypical flue gas conditions. This approach will not only suppress NOx generation during combustion but also further reduce NOx over a downstream catalytic reactor that does not require addition of an external reductant, such as ammonia. This report describes the work performed during the July 1 to September 30, 2005 time period.

  16. Parametric Study of NOx Adsorber Regeneration in Transient Cycles |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Parametric Study of NOx Adsorber Regeneration in Transient Cycles Parametric Study of NOx Adsorber Regeneration in Transient Cycles 2002 DEER Conference Presentation: Oak Ridge National Laboratory PDF icon 2002_deer_west.pdf More Documents & Publications Combining Low-Temperature Combustion with Lean-NOx Trap Yields Progress Toward Targets of Efficient NOx Control for Diesels Measurement and Characterization of NOx Adsorber Regeneration and Desulfation Measurement

  17. Lean-NOx Catalyst Development for Diesel Engine Applications | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy Lean-NOx Catalyst Development for Diesel Engine Applications Lean-NOx Catalyst Development for Diesel Engine Applications 2002 DEER Conference Presentation: Caterpillar Inc. PDF icon 2002_deer_park.pdf More Documents & Publications Lean NOx Catalysis Research and Development Selective reduction of NOx in oxygen rich environments with plasma-assisted catalysis: Catalyst development and mechanistic studies Plasma-Activated Lean NOx Catalysis for Heavy-Duty Diesel Emissions

  18. Retrofit Diesel Emissions Control System Providing 50% NOxControl |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Diesel Emissions Control System Providing 50% NOxControl Retrofit Diesel Emissions Control System Providing 50% NOxControl 2005 Diesel Engine Emissions Reduction (DEER) Conference Presentations and Posters PDF icon 2005_deer_yee.pdf More Documents & Publications Transient Dynamometer Testing of a Single-Leg NOX Adsorber Combined with a Fuel Processor for Enhanced NOx Control Fuel Processor Enabled NOx Adsorber Aftertreatment System for Diesel Engine Emissions Control

  19. Dynamometer Evaluation of Plasma-Catalyst for Diesel NOx Reduction |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Evaluation of Plasma-Catalyst for Diesel NOx Reduction Dynamometer Evaluation of Plasma-Catalyst for Diesel NOx Reduction 2003 DEER Conference Presentation: Ford Motor Company PDF icon 2003_deer_hoard.pdf More Documents & Publications Plasma Assisted Catalysis System for NOx Reduction Plasma-Activated Lean NOx Catalysis for Heavy-Duty Diesel Emissions Control Non-thermal plasma based technologies for the aftertreatment of diesel exhaust particulates and NOx

  20. Electrochemical NOx Sensors for Monitoring Diesel Emissions | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy NOx Sensors for Monitoring Diesel Emissions Electrochemical NOx Sensors for Monitoring Diesel Emissions A unique electrochemical sensing strategy correlating the level of NOx with an impedance-based signal shows promise for sensitivity, stability, and accuracy while incorporating single-cell structures and simple electronics into low-cost designs PDF icon deer10_woo.pdf More Documents & Publications NOxsensor development NOx sensor development Electrochemical NOxSensor for

  1. 01-12-1998 - Bench Top FIre Involving Use of Alcohol and Burner...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1998 - Bench Top FIre Involving Use of Alcohol and Burner Document Number: NA Effective Date: 011998 File (public): PDF icon 01-12-1998...

  2. Solid State eBurner for Supplying Power to Laptops, Cellphones...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Transmission Electricity Transmission Find More Like This Return to Search Solid State eBurner for Supplying Power to Laptops, Cellphones Oak Ridge National Laboratory...

  3. AISI/DOE Technology Roadmap Program: Development of an O2-Enriched Furnace System for Reduced CO2 and NOx Emissions For the Steel Industry

    SciTech Connect (OSTI)

    Edward W. Grandmaison; David J. Poirier; Eric Boyd

    2003-01-20

    An oxygen-enriched furnace system for reduced CO2 and NOx emission has been developed. The furnace geometry, with a sidewall-mounted burner, was similar to configurations commonly encountered in a steel reheat furnace. The effect of stack oxygen concentration, oxygen enrichment level and air infiltration on fuel savings/CO2 reduction, NOx emissions and scale formation were investigated. The firing rate required to maintain the furnace temperature at 1100 C decreased linearly with increasing oxygen enrichment. At full oxygen enrichment a reduction of 40-45% in the firing rate was required to maintain furnace temperature. NOx emissions were relatively constant at oxygen enrichment levels below 60% and decreased concentration at all oxygen enrichment levels. Air infiltration also had an effect on NOx levels leading to emissions similar to those observed with no air infiltration but with similar stack oxygen concentrations. At high oxygen enrichment levels, there was a larger variation in the refractory surface-temperature on the roof and blind sidewall of the furnace. Scale habit, intactness, adhesion and oxidation rates were examined for five grades of steel over a range of stack oxygen concentrations and oxygen enrichment levels at 1100 degree C. The steel grade had the largest effect on scaling properties examined in this work. The stack oxygen concentration and the oxygen enrichment level had much smaller effects on the scaling properties.

  4. Slurry burner for mixture of carbonaceous material and water

    DOE Patents [OSTI]

    Nodd, Dennis G.; Walker, Richard J.

    1987-01-01

    A carbonaceous material-water slurry burner includes a high pressure tip-emulsion atomizer for directing a carbonaceous material-water slurry into a combustion chamber for burning therein without requiring a support fuel or oxygen enrichment of the combustion air. Introduction of the carbonaceous material-water slurry under pressure forces it through a fixed atomizer wherein the slurry is reduced to small droplets by mixing with an atomizing air flow and directed into the combustion chamber. The atomizer includes a swirler located immediately adjacent to where the fuel slurry is introduced into the combustion chamber and which has a single center channel through which the carbonaceous material-water slurry flows into a plurality of diverging channels continuous with the center channel from which the slurry exits the swirler immediately adjacent to an aperture in the combustion chamber. The swirler includes a plurality of slots around its periphery extending the length thereof through which the atomizing air flows and by means of which the atomizing air is deflected so as to exert a maximum shear force upon the carbonaceous material-water slurry as it exits the swirler and enters the combustion chamber. A circulating coolant system or boiler feed water is provided around the periphery of the burner along the length thereof to regulate burner operating temperature, eliminate atomizer plugging, and inhibit the generation of sparklers, thus increasing combustion efficiency. A secondary air source directs heated air into the combustion chamber to promote recirculation of the hot combustion gases within the combustion chamber.

  5. J.R. Simplot: Burner Upgrade Project Improves Performance and Saves Energy at a Large Food Processing Plant

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    BestPractices Case Study BENEFITS * Saves $299,000 in annual energy costs * Saves 52,000 MMBtu of natural gas annually * Improves boiler performance * Saves 526,000 kWh per year * Achieves a simple payback of less than 14 months APPLICATIONS Worn or inefficient burners and burner control systems can lead to boiler malfunctions, production downtime, and excessive energy costs. Upgrading the efficiency of burners and burner control systems can improve a boiler's efficiency and reliability in order

  6. System and method for diagnosing EGR performance using NOx sensor

    DOE Patents [OSTI]

    Mazur, Christopher John

    2003-12-23

    A method and system for diagnosing a condition of an EGR valve used in an engine system. The EGR valve controls the portion exhaust gases produced by such engine system and fed back to an intake of such engine system. The engine system includes a NOx sensor for measuring NOx in such exhaust. The method includes: determining a time rate of change in NOx measured by the NOx sensor; comparing the determined time rate of change in the measured NOx with a predetermined expected time rate of change in measured NOx; and determining the condition of the EGR valve as a function of such comparison. The method also includes: determining from NOx measured by the NOx sensor and engine operating conditions indications of instances when samples of such measured NOx are greater than an expected maximum NOx level for such engine condition and less than an expected minimum NOx level for such engine condition; and determining the condition of the EGR valve as a function of a statistical analysis of such indications. The method includes determining whether the NOx sensor is faulty and wherein the EGR condition determining includes determining whether the NOx sensor is faulty.

  7. Cutting NOx from Diesel Engines with Membrane-Generated Nitrogen...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Cutting NOx from Diesel Engines with Membrane-Generated Nitrogen-Enriched Air Cutting NOx from Diesel Engines with Membrane-Generated Nitrogen-Enriched Air 2005 Diesel Engine ...

  8. Thermal Deactivation Mechanisms of Fully-Formed Lean NOx Trap...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Lean NOx Trap Catalysts Aged by LeanRich Cycling Catalysts in fully formulated lean NOx traps are aged and evaluated in a bench-flow reactor using simulated diesel...

  9. A Systematic Investigation of Parameters Affecting Diesel NOx Adsorber

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Catalyst Performance | Department of Energy A Systematic Investigation of Parameters Affecting Diesel NOx Adsorber Catalyst Performance A Systematic Investigation of Parameters Affecting Diesel NOx Adsorber Catalyst Performance 2002 DEER Conference Presentation: Dephi Corporation PDF icon 2002_deer_dou.pdf More Documents & Publications Pt-free, Perovskite-based Lean NOx Trap Catalysts Use of a Diesel Fuel Processor for Rapid and Efficient Regeneration of Single Leg NOx Adsorber Systems

  10. Measurement and Characterization of NOx Adsorber Regeneration and

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Desulfation | Department of Energy NOx Adsorber Regeneration and Desulfation Measurement and Characterization of NOx Adsorber Regeneration and Desulfation 2003 DEER Conference Presentation: Oak Ridge National Laboratory PDF icon 2003_deer_huff.pdf More Documents & Publications Exploring Advanced Combustion Regimes for Efficiency and Emissions Combining Low-Temperature Combustion with Lean-NOx Trap Yields Progress Toward Targets of Efficient NOx Control for Diesels Intra-catalyst

  11. Fuel Processor Enabled NOx Adsorber Aftertreatment System for Diesel Engine

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Emissions Control | Department of Energy Processor Enabled NOx Adsorber Aftertreatment System for Diesel Engine Emissions Control Fuel Processor Enabled NOx Adsorber Aftertreatment System for Diesel Engine Emissions Control 2004 Diesel Engine Emissions Reduction (DEER) Conference Presentation: Catalytica Energy Systems PDF icon 2004_deer_catalytica.pdf More Documents & Publications Transient Dynamometer Testing of a Single-Leg NOX Adsorber Combined with a Fuel Processor for Enhanced NOx

  12. Benchmark Reaction Mechanisms and Kinetics for Lean NOx Traps | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy Benchmark Reaction Mechanisms and Kinetics for Lean NOx Traps Benchmark Reaction Mechanisms and Kinetics for Lean NOx Traps 2009 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C. PDF icon acep_01_larson.pdf More Documents & Publications Development of Chemical Kinetic Models for Lean NOx Traps Development of Optimal Catalyst Designs and Operating Strategies for Lean NOx Reduction in Coupled

  13. Plasma Assisted Catalysis System for NOx Reduction | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Plasma Assisted Catalysis System for NOx Reduction Plasma Assisted Catalysis System for NOx Reduction 2002 DEER Conference Presentation: Noxtech, Inc. PDF icon 2002_deer_slone.pdf More Documents & Publications Noxtechs PAC System Development and Demonstration Lean NOx Catalysis Research and Development

  14. Lean NOx Catalysis Research and Development | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    NOx Catalysis Research and Development Lean NOx Catalysis Research and Development 2003 DEER Conference Presentation: Caterpillar, Inc. PDF icon 2003_deer_park.pdf More Documents & Publications Lean-NOx Catalyst Development for Diesel Engine Applications Fuel Effects on Emissions Control Technologies Fuel Effects on Emissions Control Technologies

  15. NOx Emission Reduction by Oscillating Combustion

    SciTech Connect (OSTI)

    2005-09-01

    This project focuses on a new technology that reduces NOx emissions while increasing furnace efficiency for both air- and oxygen-fired furnaces. Oscillating combustion is a retrofit technology that involves the forced oscillation of the fuel flow rate to a furnace. These oscillations create successive, fuel-rich and fuel-lean zones within the furnace.

  16. Process and apparatus for igniting a burner in an inert atmosphere

    DOE Patents [OSTI]

    Coolidge, Dennis W. (Katy, TX); Rinker, Franklin G. (Perrysburg, OH)

    1994-01-01

    According to this invention there is provided a process and apparatus for the ignition of a pilot burner in an inert atmosphere without substantially contaminating the inert atmosphere. The process includes the steps of providing a controlled amount of combustion air for a predetermined interval of time to the combustor then substantially simultaneously providing a controlled mixture of fuel and air to the pilot burner and to a flame generator. The controlled mixture of fuel and air to the flame generator is then periodically energized to produce a secondary flame. With the secondary flame the controlled mixture of fuel and air to the pilot burner and the combustion air is ignited to produce a pilot burner flame. The pilot burner flame is then used to ignited a mixture of main fuel and combustion air to produce a main burner flame. The main burner flame then is used to ignite a mixture of process derived fuel and combustion air to produce products of combustion for use as an inert gas in a heat treatment process.

  17. NOx Sensor for Direct Injection Emission Control

    SciTech Connect (OSTI)

    Betteridge, William J

    2006-02-28

    The Electricore/Delphi team continues to leverage the electrochemical planar sensor technology that has produced stoichiometric planar and wide range oxygen sensors as the basis for development of a NOx sensor. Zirconia cell technology with an integrated heater will provide the foundation for the sensor structure. Proven materials and packaging technology will help to ensure a cost-effective approach to the manufacture of this sensor. The electronics technique and interface is considered to be an area where new strategies need to be employed to produce higher S/N ratios of the NOx signal with emphasis on signal stability over time for robustness and durability Both continuous mode and pulse mode control techniques are being evaluated. Packaging the electronics requires careful design and circuit partitioning so that only the necessary signal conditioning electronics are coupled directly in the wiring harness, while the remainder is situated within the ECM for durability and costs reasons. This task continues to be on hold due to the limitation that the definition of the interface electronics was unavailable until very late in the project. The sense element is based on the amperometric method utilizing integrated alumina and zirconia ceramics. Precious metal electrodes are used to form the integrated heater, the cell electrodes and leads. Inside the actual sense cell structure, it is first necessary to separate NOx from the remaining oxygen constituents of the exhaust, without reducing the NOx. Once separated, the NOx will be measured using a measurement cell. Development or test coupons have been used to facilitate material selection and refinement, cell, diffusion barrier, and chamber development. The sense element currently requires elaborate interconnections. To facilitate a robust durable connection, mechanical and metallurgical connections are under investigation. Materials and process refinements continue to play an important role in the development of the sensor.

  18. Upgrade Boilers with Energy-Efficient Burners, Energy Tips: STEAM, Steam Tip Sheet #24 (Fact Sheet), Advanced Manufacturing Office (AMO), Energy Efficiency & Renewable Energy (EERE)

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    4 Upgrade Boilers with Energy-Efficient Burners Background The purpose of the burner is to mix molecules of fuel with molecules of air. A boiler will run only as well as the burner performs. A poorly designed boiler with an effcient burner may perform better than a well-designed boiler with a poor burner. Burners are designed to maximize combustion effciency while minimizing the release of emissions. A power burner mechanically mixes fuel and combustion air and injects the mixture into the

  19. DOE - Fossil Energy: Knocking the NOx Out of Coal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3-Knocking Out NOx An Energy Lesson Cleaning Up Coal Knocking the NOx Out of Coal - How NOx Forms - Formation of NOx - Air is mostly nitrogen molecules (green in the above diagram) and oxygen molecules (purple). When heated hot enough (around 3000 degrees F), the molecules break apart and oxygen atoms link with the nitrogen atoms to form NOx, an air pollutant. Nitrogen is the most common part of the air we breathe. In fact, about 80% of the air is nitrogen. Normally, nitrogen atoms float around

  20. J.R. Simplot: Burner Upgrade Project Improves Performance and Saves Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    at a Large Food Processing Plant | Department of Energy J.R. Simplot: Burner Upgrade Project Improves Performance and Saves Energy at a Large Food Processing Plant J.R. Simplot: Burner Upgrade Project Improves Performance and Saves Energy at a Large Food Processing Plant This case study describes how the J.R. Simplot Company saved energy and money by increasing the efficiency of the steam system in its potato processing plant in Caldwell, Idaho. PDF icon J.R. Simplot: Burner Upgrade Project

  1. Flexible CHP System with Low NOx, CO and VOC Emissions

    SciTech Connect (OSTI)

    2010-10-01

    This factsheet describes a project that will develop a FlexCHP-65 system that incorporates new burner technology into a 65 kW microturbine and 100 HP heat recovery boiler.

  2. 01-12-1998 - Bench Top FIre Involving Use of Alcohol and Burner | The Ames

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Laboratory 1998 - Bench Top FIre Involving Use of Alcohol and Burner Document Number: NA Effective Date: 01/1998 File (public): PDF icon 01-12-1998

  3. Low NO sub x /SO sub x Burner retrofit for utility cyclone boilers

    SciTech Connect (OSTI)

    Not Available

    1991-01-01

    Work on process design and LNS Burner design was deferred during this period, pending a reassessment of the project by TransAlta prior to commencement of Budget Period II, and only limited Balance of Plant engineering work was done.

  4. Heavy-Duty NOx Emissions Control: Reformer-Assisted vs. Plasma-Facilitated

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Lean NOx Catalysis | Department of Energy NOx Emissions Control: Reformer-Assisted vs. Plasma-Facilitated Lean NOx Catalysis Heavy-Duty NOx Emissions Control: Reformer-Assisted vs. Plasma-Facilitated Lean NOx Catalysis 2003 DEER Conference Presentation: Pacific Northwest National Laboratory PDF icon 2003_deer_aardahl.pdf More Documents & Publications Plasma-Activated Lean NOx Catalysis for Heavy-Duty Diesel Emissions Control Selective reduction of NOx in oxygen rich environments with

  5. The rare earth silicon phosphides LnSi{sub 2}P{sub 6} (Ln = La, Ce, Pr, and Nd)

    SciTech Connect (OSTI)

    Kaiser, P.; Jeitschko, W.

    1996-07-01

    The title compounds were prepared in well-crystallized form from a tin flux and their crystal structure was determined from single-crystal diffractometer data of LaSi{sub 2}P{sub 6}: Cmc2{sub 1}, a = 1012.9(3) pm, b = 2817.5(7) pm, c = 1037.4(5) pm, Z = 16, R = 0.034 for 3303 structure factors and 181 variable parameters. The structure of the isotypic compound CeSi{sub 2}P{sub 6} was also refined from single-crystal X-ray data: a = 1011.8(4) pm, b = 2803.1(8) pm, c = 1031.1(4) pm, R = 0.035 for 2132 F values and 181 variables. The silicon and the phosphorus atoms could be distinguished by comparing their occupancy parameters obtained from both structure refinements. The assignments agree with those deduced by structure-chemical arguments. These atoms form a three-dimensionally infinite framework polyanion, which accommodates four different kinds of rare earth atoms: three with nine and one with ten phosphorus neighbors. The silicon atoms are all in tetrahedral phosphorus coordination. There are phosphorus atoms which have only two rare earth and two silicon neighbors, but most phosphorus atoms have--in addition to the rare earth and silicon atoms--phosphorus neighbors, thus forming P{sub 3}, P{sub 4}, P{sub 5}, and P{sub 6} units. Using oxidation numbers, the compounds can be rationalized with the formulas Ln{sup 3+}(Si{sub 2}P{sub 6}){sub 3-} and Ln{sup 3+}(Si{sup 4+}){sub 2}(P{sub 6}){sup 11-}, where the octet rule is obeyed for the silicon and phosphorus atoms and two electrons are counted for each Si-P and P-P interaction.

  6. Low-Emissions Burner Technology using Biomass-Derived Liquid Fuels

    SciTech Connect (OSTI)

    2010-07-01

    The University of Alabama will develop fuel-flexible, low-emissions burner technology for the metal processing industry that is capable of using biomass-derived liquid fuels, such as glycerin or fatty acids, as a substitute for natural gas. By replacing a fossil fuel with biomass fuels, this new burner will enable a reduction in energy consumption and greenhouse gas emissions and an increase in fuel flexibility.

  7. Low No sub x /SO sub x burner retrofit for utility cyclone boilers

    SciTech Connect (OSTI)

    Moore, K.; Martin, L.; Smith, J.

    1991-05-01

    The Low NO{sub x}/SO{sub x} (LNS) Burner Retrofit for Utility Cyclone Boilers program consists of the retrofit and subsequent demonstration of the technology at Southern Illinois Power Cooperative's (SIPC's) 33-MW unit 1 cyclone boiler located near Marion, Illinois. The LNS Burner employs a simple innovative combustion process burning high-sulfur Illinois coal to provide substantial SO{sub 2} and NO{sub x} control within the burner. A complete series of boiler performance and characterization tests, called the baseline tests, was conducted in October 1990 on unit 1 of SIPC's Marion Station. The primary objective of the baseline test was to collect data from the existing plant that could provide a comparison of performance after the LNS Burner retrofit. These data could confirm the LNS Burner's SO{sub x} and NO{sub x} emissions control and any effect on boiler operation. Further, these tests would provide to the project experience with the operating characteristics of the host unit as well as engineering design information to minimize technical uncertainties in the application of the LNS Burner technology.

  8. NOx Reduction with Natural Gas for Lean Large-Bore Engine Applications Using Lean NOx Trap Aftertreatment

    SciTech Connect (OSTI)

    Parks, JE

    2005-02-11

    Large-bore natural gas engines are used for distributed energy and gas compression since natural gas fuel offers a convenient and reliable fuel source via the natural gas pipeline and distribution infrastructure. Lean engines enable better fuel efficiency and lower operating costs; however, NOx emissions from lean engines are difficult to control. Technologies that reduce NOx in lean exhaust are desired to enable broader use of efficient lean engines. Lean NOx trap catalysts have demonstrated greater than 90% NOx reduction in lean exhaust from engines operating with gasoline, diesel, and natural gas fuels. In addition to the clean nature of the technology, lean NOx traps reduce NOx with the fuel source of the engine thereby eliminating the requirement for storage and handling of secondary fuels or reducing agents. A study of lean NOx trap catalysts for lean natural gas engines is presented here. Testing was performed on a Cummins C8.3G (CG-280) engine on a motor dynamometer. Lean NOx trap catalysts were tested for NOx reduction performance under various engine operating conditions, and the utilization of natural gas as the reductant fuel source was characterized. Engine test results show that temperature greatly affects the catalytic processes involved, specifically methane oxidation and NOx storage on the lean NOx trap. Additional studies on a bench flow reactor demonstrate the effect of precious metal loading (a primary cost factor) on lean NOx trap performance at different temperatures. Results and issues related to the potential of the lean NOx trap technology for large-bore engine applications will be discussed.

  9. Catalytic effects of minerals on NOx emission from coal combustion

    SciTech Connect (OSTI)

    Yao, M.Y.; Che, D.F.

    2007-07-01

    The catalytic effects of inherent mineral matters on NOx emissions from coal combustion have been investigated by a thermo-gravimetric analyzer (TGA) equipped with a gas analyzer. The effect of demineralization and the individual effect of Na, K, Ca, Mg, and Fe on the formation of NOx are studied as well as the combined catalytic effects of Ca + Na and Ca + Ti. Demineralization causes more Fuel-N to retain in the char, and reduction of NOx mostly. But the mechanistic effect on NOx formation varies from coal to coal. Ca and Mg promote NOx emission. Na, K, Fe suppress NOx formation to different extents. The effect of transition element Fe is the most obvious. The combination of Ca + Na and Ca + Ti can realize the simultaneous control of sulfur dioxide and nitrogen oxides emissions.

  10. Structure, thermodynamic, and magnetic properties of Ln[sub 4]PdO[sub 7] with Ln = La, Nd, Sm, Eu, and Gd

    SciTech Connect (OSTI)

    Andersson, M.; Grins, J.; Nygren, M. (Stockholm Univ. (Sweden))

    1999-09-01

    The structure of Nd[sub 4]PdO[sub 7] has been determined and refined using the Rietveld method and combined CuK[alpha][sub 1] X-ray and neutron powder data in space group P[bar 1] with unit cell a = 15.972(2), b = 7.1927(7), c = 6.9160(6) [angstrom], [alpha] = 96.299(4), [beta] = 131.643(3), [gamma] = 121.438(3)[degree], V = 353.83(6) [angstrom][sup 3] and Z = 2, to R[sub F] = 2.0% (neutron data) and R[sub F] = 6.2% (X-ray data). The structure is closely related to the monoclinic La[sub 4]PdO[sub 7] structure and exhibits Nd atoms coordinated by seven O atoms and Pd atoms coordinated by a square of O atoms. Isolated chains of trans-corner-sharing PdO[sub 4] squares are straight in the La[sub 4]PdO[sub 7] structure and staggered in the Nd[sub 4]PdO[sub 7] structure. Electron and X-ray powder diffraction data show that Ln[sub 4]PdO[sub 7] with Ln = Sm, Eu, and Gd is isostructural with Nd[sub 4]PdO[sub 7]. The enthalpies of dissolution of Ln[sub 4]PdO[sub 7] (Ln = La, Nd) in 1.000 M HCl have been measured with an in-house built calorimeter, and from these values the enthalpies of formation for the compounds have been calculated. The decomposition temperatures of Ln[sub 4]PdO[sub 7] with Ln = La and Nd in oxygen have been determined by thermogravimetric measurements and found to decrease from 1645 [+-] 10 K for La[sub 4]PdO[sub 7] to 1540 [+-] 10 K for Nd[sub 4]PdO[sub 7]. Using these data, an Ellingham diagram has been constructed assuming temperature-independent [Delta]H[sub f][degree] and [Delta]S[sub f][degree]. The magnetic susceptibilities of Ln[sub 4]PdO[sub 7] with Ln = La, Nd, Sm, Eu, Gd, recorded in the temperature range 10--320 K, were found to be in agreement with the expected ones for noninteracting Ln[sup 3+] ions.

  11. Preliminary safety evaluation of the advanced burner test reactor.

    SciTech Connect (OSTI)

    Dunn, F. E.; Fanning, T. H.; Cahalan, J. E.; Nuclear Engineering Division

    2006-09-15

    Results of a preliminary safety evaluation of the Advanced Burner Test Reactor (ABTR) pre-conceptual design are reported. The ABTR safety design approach is described. Traditional defense-in-depth design features are supplemented with passive safety performance characteristics that include natural circulation emergency decay heat removal and reactor power reduction by inherent reactivity feedbacks in accidents. ABTR safety performance in design-basis and beyond-design-basis accident sequences is estimated based on analyses. Modeling assumptions and input data for safety analyses are presented. Analysis results for simulation of simultaneous loss of coolant pumping power and normal heat rejection are presented and discussed, both for the case with reactor scram and the case without reactor scram. The analysis results indicate that the ABTR pre-conceptual design is capable of undergoing bounding design-basis and beyond-design-basis accidents without fuel cladding failures. The first line of defense for protection of the public against release of radioactivity in accidents remains intact with significant margin. A comparison and evaluation of general safety design criteria for the ABTR conceptual design phase are presented in an appendix. A second appendix presents SASSYS-1 computer code capabilities and modeling enhancements implemented for ABTR analyses.

  12. Oxidation State Optimization for Maximum Efficiency of NOx Adsorber

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Catalysts | Department of Energy State Optimization for Maximum Efficiency of NOx Adsorber Catalysts Oxidation State Optimization for Maximum Efficiency of NOx Adsorber Catalysts Presentation given at the 16th Directions in Engine-Efficiency and Emissions Research (DEER) Conference in Detroit, MI, September 27-30, 2010. PDF icon deer10_li.pdf More Documents & Publications Lean NOx Trap Regeneration Selectivity Towards N2O -- Similarities and Differences Between H2, CO and C3H6 Reductants

  13. Passive Catalytic Approach to Low Temperature NOx Emission Abatement |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Catalytic Approach to Low Temperature NOx Emission Abatement Passive Catalytic Approach to Low Temperature NOx Emission Abatement Numerically evaluated and optimized proposed state-of-the-art passive catalytic technology designed to reduce NOx released during vehicle cold start portion of the FTP-75 cycle PDF icon deer11_henry.pdf More Documents & Publications Advanced Technology Light Duty Diesel Aftertreatment System Cummins' Next Generation Tier 2, Bin 2 Light

  14. Lower Freezing DEF For Higher NOx Reduction Attainment | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Freezing DEF For Higher NOx Reduction Attainment Lower Freezing DEF For Higher NOx Reduction Attainment NOx emissions data from bench-scale experiments and Class III truck operated using a low freezing point diesel exhaust fluid PDF icon deer11_highfield.pdf More Documents & Publications Urea Mixing Design -- Simulation and Test Investigation 3rd Generation SCR System Using Solid Ammonia Storage and Direct Gas Dosing Urea SCR and DPF System for Deisel Sport Utility Vehicle Meeting

  15. Monolithic Metal Oxide based Composite Nanowire Lean NOx Emission Control

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Catalysts | Department of Energy Monolithic Metal Oxide based Composite Nanowire Lean NOx Emission Control Catalysts Monolithic Metal Oxide based Composite Nanowire Lean NOx Emission Control Catalysts Presents latest progress in the development of a new type of lean NOx trapping catalyst based on heterogenous composite nanowires, which could potentially be used in gasoline and diesel engines. PDF icon deer11_gao.pdf More Documents & Publications Three-Dimensional Composite Nanostructures

  16. NOx Adsorber Regeneration Phenomena In Heavy Duty Applications | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy Adsorber Regeneration Phenomena In Heavy Duty Applications NOx Adsorber Regeneration Phenomena In Heavy Duty Applications 2003 DEER Conference Presentation: Oak Ridge National Laboratory PDF icon 2003_deer_west.pdf More Documents & Publications Fuel-Borne Reductants for NOx Aftertreatment: Preliminary EtOH SCR Study Fuels for Advanced CIDI Engines and Fuel Cells: 2000 Annual Progress Report APBF-DEC Heavy Duty NOx Adsorber/DPF Project: Heavy Duty Linehaul Platform Project

  17. NOx Aftertreatment Using Ethanol as Reductant | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Aftertreatment Using Ethanol as Reductant NOx Aftertreatment Using Ethanol as Reductant The hydrocarbon-SCR that was developed using ethanol and E85 as the reductant showed high NOx reduction, no need for thawing, use of existing infrastructure, and reduced system cost making it a viable alternative to urea-based SCR PDF icon deer10_diewald.pdf More Documents & Publications Selective ammonia slip catalyst enabling highly efficient NOx removal requirements of the future SCR-DPF Integrations

  18. Mechanisms of Sulfur Poisoning of NOx Adsorber (LNT) Materials | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy Sulfur Poisoning of NOx Adsorber (LNT) Materials Mechanisms of Sulfur Poisoning of NOx Adsorber (LNT) Materials 2009 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C. PDF icon ace_24_peden.pdf More Documents & Publications Enhanced High Temperature Performance of NOx Storage/Reduction (NSR) Materials Deactivation Mechanisms of Base Metal/Zeolite Urea Selective Catalytic Reduction Materials

  19. Enhanced High Temperature Performance of NOx Storage/Reduction (NSR)

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Materials | Department of Energy 1 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation PDF icon ace026_peden_2011_o.pdf More Documents & Publications Enhanced High Temperature Performance of NOx Storage/Reduction (NSR) Materials Enhanced High Temperature Performance of NOx Storage/Reduction (NSR) Materials Mechanisms of Sulfur Poisoning of NOx Adsorber (LNT)

  20. Deactivation mechanisms of NOx storage materials arising from thermal aging

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and sulfur poisoning | Department of Energy mechanisms of NOx storage materials arising from thermal aging and sulfur poisoning Deactivation mechanisms of NOx storage materials arising from thermal aging and sulfur poisoning Presents the reliationship between Pt particle size and NOx storage performance over model catalysts. Novel reaction protocol designed to decouple effects of thermal deactivation and incomplete desulfation. PDF icon deer08_muntean.pdf More Documents & Publications

  1. Detection of Ammonia Slip Using NOx Sensor Signal Processing | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy Detection of Ammonia Slip Using NOx Sensor Signal Processing Detection of Ammonia Slip Using NOx Sensor Signal Processing Presentation given at the 16th Directions in Engine-Efficiency and Emissions Research (DEER) Conference in Detroit, MI, September 27-30, 2010. PDF icon deer10_gady.pdf More Documents & Publications Spatiotemporal Distribution of NOx Storage: a Factor Controlling NH3 and N2O Selectivities over a Commercial LNT Catalyst Simplification of Diesel Emission

  2. Effect of Biodiesel Blends on NOx Emissions | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Biodiesel Blends on NOx Emissions Effect of Biodiesel Blends on NOx Emissions Poster presentation at the 2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER 2007). 13-16 August, 2007, Detroit, Michigan. Sponsored by the U.S. Department of Energy's (DOE) Office of FreedomCAR and Vehicle Technologies (OFCVT). PDF icon deer07_pedersen.pdf More Documents & Publications Key Benefits in Using Ethanol-Diesel Blends Lean NOx Trap Formulation Effect on Performance with In-Cylinder

  3. Super Duty Diesel Truck with NOx Aftertreatment | Department of Energy

    Energy Savers [EERE]

    Super Duty Diesel Truck with NOx Aftertreatment Super Duty Diesel Truck with NOx Aftertreatment A profile of a Ford-Energy Department program to develop a three-stage aftertreatment technology, which cleans the vehicle exhaust emissions. This profile is part of the U.S. Drive 2011 Accomplishment Report. PDF icon U.S. DRIVE Highlights of Technical Accomplishments 2011: Super Duty Diesel Truck with NOx Aftertreatment More Documents & Publications Development of the 2011MY Ford Super Duty

  4. Three-Dimensional Composite Nanostructures for Lean NOx Emission Control |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy 0 DOE Vehicle Technologies and Hydrogen Programs Annual Merit Review and Peer Evaluation Meeting, June 7-11, 2010 -- Washington D.C. PDF icon ace030_gao_2010_o.pdf More Documents & Publications Three-Dimensional Composite Nanostructures for Lean NOx Emission Control Monolithic Metal Oxide based Composite Nanowire Lean NOx Emission Control Catalysts Three-Dimensional Composite Nanostructures for Lean NOx Emission Control

  5. Transmural Catalysis - High Efficiency Catalyst Systems for NOx Adsorbers

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and SCR | Department of Energy Transmural Catalysis - High Efficiency Catalyst Systems for NOx Adsorbers and SCR Transmural Catalysis - High Efficiency Catalyst Systems for NOx Adsorbers and SCR Presentation given at DEER 2006, August 20-24, 2006, Detroit, Michigan. Sponsored by the U.S. DOE's EERE FreedomCar and Fuel Partnership and 21st Century Truck Programs. PDF icon 2006_deer_atkinson.pdf More Documents & Publications Reductant Utilization in a LNT + SCR System Lean NOx Trap

  6. MINIMIZATION OF NO EMISSIONS FROM MULTI-BURNER COAL-FIRED BOILERS

    SciTech Connect (OSTI)

    E.G. Eddings; A. Molina; D.W. Pershing; A.F. Sarofim; T.H. Fletcher; H. Zhang; K.A. Davis; M. Denison; H. Shim

    2002-01-01

    The focus of this program is to provide insight into the formation and minimization of NO{sub x} in multi-burner arrays, such as those that would be found in a typical utility boiler. Most detailed studies are performed in single-burner test facilities, and may not capture significant burner-to-burner interactions that could influence NO{sub x} emissions. Thus, investigations of such interactions were made by performing a combination of single and multiple burner experiments in a pilot-scale coal-fired test facility at the University of Utah, and by the use of computational combustion simulations to evaluate full-scale utility boilers. In addition, fundamental studies on nitrogen release from coal were performed to develop greater understanding of the physical processes that control NO formation in pulverized coal flames--particularly under low NO{sub x} conditions. A CO/H{sub 2}/O{sub 2}/N{sub 2} flame was operated under fuel-rich conditions in a flat flame reactor to provide a high temperature, oxygen-free post-flame environment to study secondary reactions of coal volatiles. Effects of temperature, residence time and coal rank on nitrogen evolution and soot formation were examined. Elemental compositions of the char, tar and soot were determined by elemental analysis, gas species distributions were determined using FTIR, and the chemical structure of the tar and soot was analyzed by solid-state {sup 13}C NMR spectroscopy. A laminar flow drop tube furnace was used to study char nitrogen conversion to NO. The experimental evidence and simulation results indicated that some of the nitrogen present in the char is converted to nitric oxide after direct attack of oxygen on the particle, while another portion of the nitrogen, present in more labile functionalities, is released as HCN and further reacts in the bulk gas. The reaction of HCN with NO in the bulk gas has a strong influence on the overall conversion of char-nitrogen to nitric oxide; therefore, any model that aims to predict the conversion of char-nitrogen to nitric oxide should allow for the conversion of char-nitrogen to HCN. The extent of the HCN conversion to NO or N{sub 2} will depend on the composition of the atmosphere surrounding the particle. A pilot-scale testing campaign was carried out to evaluate the impact of multiburner firing on NO{sub x} emissions using a three-burner vertical array. In general, the results indicated that multiburner firing yielded higher NO{sub x} emissions than single burner firing at the same fuel rate and excess air. Mismatched burner operation, due to increases in the firing rate of the middle burner, generally demonstrated an increase in NO{sub x} over uniform firing. Biased firing, operating the middle burner fuel rich with the upper and lower burners fuel lean, demonstrated an overall reduction in NO{sub x} emissions; particularly when the middle burner was operated highly fuel rich. Computational modeling indicated that operating the three burner array with the center burner swirl in a direction opposite to the other two resulted in a slight reduction in NO{sub x}.

  7. Novel Application of Air Separation Membranes Reduces NOx Emissions...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Application of Air Separation Membranes Reduces NOx Emissions Technology available for licensing: Selective permeation of gases using an air separation membrane. Can be retrofitted...

  8. Enhanced High Temperature Performance of NOx Storage/Reduction...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    (LNT) Materials Enhanced High Temperature Performance of NOx StorageReduction (NSR) Materials Deactivation Mechanisms of Base MetalZeolite Urea Selective Catalytic Reduction...

  9. Three-Dimensional Composite Nanostructures for Lean NOx Emission...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Monolithic Metal Oxide based Composite Nanowire Lean NOx Emission Control Catalysts Vehicle Technologies Office Merit Review 2015: Metal Oxide...

  10. Lean NOx Traps - Microstructural Studies of Real World and Model...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Traps - Microstructural Studies of Real World and Model Catalysts Lean NOx Traps - Microstructural Studies of Real World and Model Catalysts 2005 Diesel Engine Emissions Reduction...

  11. NOx Adsorber Regeneration Phenomena In Heavy Duty Applications...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Adsorber Regeneration Phenomena In Heavy Duty Applications NOx Adsorber Regeneration Phenomena In Heavy Duty Applications 2003 DEER Conference Presentation: Oak Ridge National ...

  12. NOx Adsorbers for Heavy Duty Truck Engines - Testing and Simulation...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Adsorbers for Heavy Duty Truck Engines - Testing and Simulation NOx Adsorbers for Heavy Duty Truck Engines - Testing and Simulation This report provides the results of an ...

  13. Cummins/ORNL-FEERC CRADA: NOx Control & Measurement Technology...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    for Heavy-Duty Diesel Engines Vehicle Technologies Office Merit Review 2014: Cummins-ORNLFEERC Emissions CRADA: NOx Control & Measurement Technology for Heavy-Duty Diesel ...

  14. Cummins/ORNL-FEERC CRADA: NOx Control & Measurement Technology...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications CumminsORNL-FEERC CRADA: NOx Control & Measurement Technology for Heavy-Duty Diesel Engines Vehicle Technologies Office Merit Review...

  15. Cummins/ORNL-FEERC CRADA: NOx Control & Measurement Technology...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications CumminsORNL-FEERC CRADA: NOx Control & Measurement Technology for Heavy-Duty Diesel Engines CLEERS Coordination & Development of...

  16. DeNOx characteristics using two staged radical injection techniques

    SciTech Connect (OSTI)

    Kambara, S.; Kumano, Y.; Yukimura, K.

    2009-06-15

    Ammonia radical injection using pulsed dielectric barrier discharge (DBD) plasma has been investigated as a means to control NOx emissions from combustors. When DBD plasma-generated radicals (NH{sub 2}, NH, N, and H) are injected into a flue gas containing nitrogen oxide (NOx), NOx is removed efficiently by chain reactions in the gas phase. However, because the percentage of NOx removal gradually decreases with increasing oxygen concentrations beyond 1% O{sub 2}, improvement of the DeNOx (removal of nitrogen oxide) characteristics at high O{sub 2} concentrations was necessary for commercial combustors. A two-staged injection of the DeNOx agent was developed based on the detailed mechanisms of electron impact reactions and gas phase reactions. A concentration of H radical was observed to play an important role in NOx formation and removal. The effects of applied voltages, oxygen concentrations, and reaction temperatures on NOx removal were investigated under normal and staged injection. NOx removal was improved by approximately 20% using staged injection at O{sub 2} concentrations of 1 to 4%.

  17. Passive Catalytic Approach to Low Temperature NOx Emission Abatement...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Passive Catalytic Approach to Low Temperature NOx Emission Abatement Numerically evaluated and optimized proposed state-of-the-art passive catalytic technology designed to reduce ...

  18. Development of Materials Analysis Tools for Studying NOx Adsorber...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Materials Analysis Tools for Studying NOx Adsorber Catalysts A cooperative research and development agreement with Cummins Engine Company Development of Materials Analysis Tools ...

  19. Development on simultaneous reduction system of NOx and PM from...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    reduction system of NOx and PM from a diesel engine 2003 DEER Converence Presentation: Toyota Motor Corporation PDF icon 2003deerwatanabe.pdf More Documents & Publications An...

  20. Fuel Consumption and NOx Trade-offs on a Port-Fuel-Injected SI...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    NOx Trade-offs on a Port-Fuel-Injected SI Gasoline Engine Equipped with a Lean-NOx Trap Fuel Consumption and NOx Trade-offs on a Port-Fuel-Injected SI Gasoline Engine Equipped with ...

  1. Transient Dynamometer Testing of a Single-Leg NOX Adsorber Combined...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Single-Leg NOX Adsorber Combined with a Fuel Processor for Enhanced NOx Control Transient Dynamometer Testing of a Single-Leg NOX Adsorber Combined with a Fuel Processor for...

  2. Heavy-Duty NOx Emissions Control: Reformer-Assisted vs. Plasma...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Plasma-Facilitated Lean NOx Catalysis Heavy-Duty NOx Emissions Control: Reformer-Assisted ... Plasma-Activated Lean NOx Catalysis for Heavy-Duty Diesel Emissions Control Selective ...

  3. Transient Dynamometer Testing of a Single-Leg NOX Adsorber Combined with a

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fuel Processor for Enhanced NOx Control | Department of Energy Single-Leg NOX Adsorber Combined with a Fuel Processor for Enhanced NOx Control Transient Dynamometer Testing of a Single-Leg NOX Adsorber Combined with a Fuel Processor for Enhanced NOx Control 2005 Diesel Engine Emissions Reduction (DEER) Conference Presentations and Posters PDF icon 2005_deer_dallabetta.pdf More Documents & Publications Fuel Processor Enabled NOx Adsorber Aftertreatment System for Diesel Engine Emissions

  4. Sonochemical synthesis of highly luminescent Ln2O3:Eu3+ (Y, La, Gd) nanocrystals

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Alammar, Tarek; Cybinska, Joanna; Campbell, Paul S.; Mudring, Anja -Verena

    2015-05-12

    In this study, sonication of Ln(CH3COO)3·H2O, Eu(CH3COO)3·H2O and NaOH dissolved in the ionic liquid-butyl-3-methylimidazolium bis(trifluoromethane)sulfonylamide lead to Ln(OH)3:Eu (Ln: Gd, La, Y) nanoparticles. Subsequent calcination at 800 °C for 3 h allowed to obtain Ln2O3:Eu nanopowders. Gd2O3 and Y2O3 were obtained in the C-type lanthanide sequioxide structure, whereas La2O3 crystallized in the A-type. Structure, morphology, and luminescent properties of the nano-oxides were investigated by powder X-ray diffraction (PXRD), scanning electron microscopy (SEM), dispersive X-ray (EDX), and photoluminescence (PL). SEM studies revealed that the synthesized Gd2O3:Eu, La2O3:Eu, and Y2O3:Eu formed nano-spindle, -sheets, and -rods in shape, respectively. The nanoscale materials showmore » very efficient red emission due to the intraconfigurational f–f transitions of Eu3+. The quantum yields for Ln2O3:Eu (5%) were determined to be 4.2% for Ln=Gd, 13.8% for Ln=Y and 5.2% for Ln=La. The asymmetric ratio I02/I01 of Eu3+ varies from 5.3 for Gd2O3, to 5.6 for Y2O3 to 6.5 for La2O3, which increased the color chromaticity.« less

  5. Sonochemical synthesis of highly luminescent Ln2O3:Eu3+ (Y, La, Gd) nanocrystals

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Alammar, Tarek; Cybinska, Joanna; Campbell, Paul S.; Mudring, Anja -Verena

    2015-05-12

    In this study, sonication of Ln(CH3COO)3·H2O, Eu(CH3COO)3·H2O and NaOH dissolved in the ionic liquid-butyl-3-methylimidazolium bis(trifluoromethane)sulfonylamide lead to Ln(OH)3:Eu (Ln: Gd, La, Y) nanoparticles. Subsequent calcination at 800 °C for 3 h allowed to obtain Ln2O3:Eu nanopowders. Gd2O3 and Y2O3 were obtained in the C-type lanthanide sequioxide structure, whereas La2O3 crystallized in the A-type. Structure, morphology, and luminescent properties of the nano-oxides were investigated by powder X-ray diffraction (PXRD), scanning electron microscopy (SEM), dispersive X-ray (EDX), and photoluminescence (PL). SEM studies revealed that the synthesized Gd2O3:Eu, La2O3:Eu, and Y2O3:Eu formed nano-spindle, -sheets, and -rods in shape, respectively. The nanoscale materials showmore »very efficient red emission due to the intraconfigurational f–f transitions of Eu3+. The quantum yields for Ln2O3:Eu (5%) were determined to be 4.2% for Ln=Gd, 13.8% for Ln=Y and 5.2% for Ln=La. The asymmetric ratio I02/I01 of Eu3+ varies from 5.3 for Gd2O3, to 5.6 for Y2O3 to 6.5 for La2O3, which increased the color chromaticity.« less

  6. NOx reduction by electron beam-produced nitrogen atom injection

    DOE Patents [OSTI]

    Penetrante, Bernardino M. (San Ramon, CA)

    2002-01-01

    Deactivated atomic nitrogen generated by an electron beam from a gas stream containing more than 99% N.sub.2 is injected at low temperatures into an engine exhaust to reduce NOx emissions. High NOx reduction efficiency is achieved with compact electron beam devices without use of a catalyst.

  7. Novel Application of Air Separation Membranes Reduces NOx Emissions |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Argonne National Laboratory Application of Air Separation Membranes Reduces NOx Emissions Technology available for licensing: Selective permeation of gases using an air separation membrane. Can be retrofitted to existing engines Significantly reduces NOx emissions (as much as 70%) with just a 2% nitrogen enrichment of intake air PDF icon air_separation_membranes

  8. SCR Technologies for NOx Reduction | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Technologies for NOx Reduction SCR Technologies for NOx Reduction 2005 Diesel Engine Emissions Reduction (DEER) Conference Presentations and Posters PDF icon 2005_deer_hesser.pdf More Documents & Publications Injection System and Engine Strategies for Advanced Emission Standards Advanced Diesel Common Rail Injection System for Future Emission Legislation Powertrain Trends and Future Potential

  9. Enhanced High Temperature Performance of NOx Storage/Reduction (NSR)

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Materials | Department of Energy 2 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting PDF icon ace026_peden_2012_o.pdf More Documents & Publications Enhanced High and Low Temperature Performance of NOx Reduction Materials Enhanced High Temperature Performance of NOx Storage/Reduction (NSR) Materials CLEERS Aftertreatment Modeling and Analysis

  10. Plasma-Activated Lean NOx Catalysis for Heavy-Duty Diesel Emissions...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Plasma-Activated Lean NOx Catalysis for Heavy-Duty Diesel Emissions Control Plasma-Activated Lean NOx Catalysis for Heavy-Duty Diesel Emissions Control PDF icon ...

  11. Lean NOx Reduction with Dual Layer LNT/SCR Catalysts | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    out coupled ammonia generation and NOx reduction, achieving high NOx conversion with minimal ammonia slip PDF icon deer12harold.pdf More Documents & Publications Development of ...

  12. Modeling the Regeneration Chemistry of Lean NOx Traps | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy the Regeneration Chemistry of Lean NOx Traps Modeling the Regeneration Chemistry of Lean NOx Traps Presentation given at DEER 2006, August 20-24, 2006, Detroit, Michigan. Sponsored by the U.S. DOE's EERE FreedomCar and Fuel Partnership and 21st Century Truck Programs. PDF icon 2006_deer_larson.pdf More Documents & Publications Kinetic and Performance Studies of the Regeneration Phase of Model Pt/Rh/Ba NOx Traps for Design and Optimization Production, Storage, and FC Analysis

  13. ASU nitrogen sweep gas in hydrogen separation membrane for production of HRSG duct burner fuel

    DOE Patents [OSTI]

    Panuccio, Gregory J.; Raybold, Troy M.; Jamal, Agil; Drnevich, Raymond Francis

    2013-04-02

    The present invention relates to the use of low pressure N2 from an air separation unit (ASU) for use as a sweep gas in a hydrogen transport membrane (HTM) to increase syngas H2 recovery and make a near-atmospheric pressure (less than or equal to about 25 psia) fuel for supplemental firing in the heat recovery steam generator (HRSG) duct burner.

  14. Low No{sub x}/SO{sub x} burner retrofit for utility cyclone boilers. Baseline test report: Issue A

    SciTech Connect (OSTI)

    Moore, K.; Martin, L.; Smith, J.

    1991-05-01

    The Low NO{sub x}/SO{sub x} (LNS) Burner Retrofit for Utility Cyclone Boilers program consists of the retrofit and subsequent demonstration of the technology at Southern Illinois Power Cooperative`s (SIPC`s) 33-MW unit 1 cyclone boiler located near Marion, Illinois. The LNS Burner employs a simple innovative combustion process burning high-sulfur Illinois coal to provide substantial SO{sub 2} and NO{sub x} control within the burner. A complete series of boiler performance and characterization tests, called the baseline tests, was conducted in October 1990 on unit 1 of SIPC`s Marion Station. The primary objective of the baseline test was to collect data from the existing plant that could provide a comparison of performance after the LNS Burner retrofit. These data could confirm the LNS Burner`s SO{sub x} and NO{sub x} emissions control and any effect on boiler operation. Further, these tests would provide to the project experience with the operating characteristics of the host unit as well as engineering design information to minimize technical uncertainties in the application of the LNS Burner technology.

  15. Low NO sub x /SO sub x Burner retrofit for utility cyclone boilers

    SciTech Connect (OSTI)

    Not Available

    1990-01-01

    The objective of this project is to demonstrate the LNS Burner as retrofitted to the host cyclone boiler for effective low-cost control of NO{sub x} and SO{sub x} emissions while firing a bituminous coal. The LNS Burner employs a simple, innovative combustion process to burn pulverized coal at high temperatures and provides effective, low-cost control of sulfur dioxide (SO{sub 2}) and nitrogen oxides (NO{sub x}) emissions. The coal ash contains sulfur and is removed in the form of molten slag and flyash. Cyclone-fired boiler units are typically older units firing high-sulfur bituminous coals at very high temperatures which results in very high NO{sub x} and SO{sub x} emissions. The addition of conventional emission control equipment, such as wet scrubbers, to these older cyclone units in order to meet current and future environmental regulations is generally not economic. Further, the units are generally not compatible with low sulfur coal switching for S0{sub 2} control or selective catalytic reduction technologies for NO{sub x} control. Because the LNS Burner operates at the same very high temperatures as a typical cyclone boiler and produces a similar slag product, it may offer a viable retrofit option for cyclone boiler emission control. This was confirmed by the Cyclone Boiler Retrofit Feasibility Study carried out by TransAlta and an Operating Committee formed of cyclone boiler owners in 1989. An existing utility cyclone boiler, was then selected for the evaluation of the cost and performance study. It was concluded that the LNS Burner retrofit would be a cost-effective option for control of cyclone boiler emissions. A full-scale demonstration of the LNS Burner retrofit was selected in October 1988 as part of the DOE's Clean Coal Technology Program Round II.

  16. Lean Gasoline Engine Reductant Chemistry During Lean NOx Trap Regeneration

    SciTech Connect (OSTI)

    Choi, Jae-Soon; Prikhodko, Vitaly Y; Partridge Jr, William P; Parks, II, James E; Norman, Kevin M; Huff, Shean P; Chambon, Paul H; Thomas, John F

    2010-01-01

    Lean NOx Trap (LNT) catalysts can effectively reduce NOx from lean engine exhaust. Significant research for LNTs in diesel engine applications has been performed and has led to commercialization of the technology. For lean gasoline engine applications, advanced direct injection engines have led to a renewed interest in the potential for lean gasoline vehicles and, thereby, a renewed demand for lean NOx control. To understand the gasoline-based reductant chemistry during regeneration, a BMW lean gasoline vehicle has been studied on a chassis dynamometer. Exhaust samples were collected and analyzed for key reductant species such as H2, CO, NH3, and hydrocarbons during transient drive cycles. The relation of the reductant species to LNT performance will be discussed. Furthermore, the challenges of NOx storage in the lean gasoline application are reviewed.

  17. Lean NOx Trap Regeneration Selectivity Towards N2O -- Similarities...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Towards N2O -- Similarities and Differences Between H2, CO and C3H6 Reductants Lean NOx Trap Regeneration Selectivity Towards N2O -- Similarities and Differences Between H2,...

  18. Rapid Aging Protocols for Diesel Aftertreatment Devices: NOx...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Thermal Deactivation Mechanisms of Fully-Formed Lean NOx Trap Catalysts Aged by LeanRich Cycling Impacts of Biodiesel on Emission Control Devices Urea SCR and DPF System for Tier ...

  19. Benchmark Reaction Mechanisms and Kinetics for Lean NOx Traps...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C. PDF icon acep01larson.pdf More Documents & Publications Development of Chemical Kinetic Models for Lean NOx ...

  20. Plasma-Activated Lean NOx Catalysis for Heavy-Duty Diesel Emissions Control

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    | Department of Energy Plasma-Activated Lean NOx Catalysis for Heavy-Duty Diesel Emissions Control Plasma-Activated Lean NOx Catalysis for Heavy-Duty Diesel Emissions Control PDF icon 2002_deer_aardahl.pdf More Documents & Publications Heavy-Duty NOx Emissions Control: Reformer-Assisted vs. Plasma-Facilitated Lean NOx Catalysis Selective reduction of NOx in oxygen rich environments with plasma-assisted catalysis: Catalyst development and mechanistic studies

  1. Laboratory Product Speciation Studies of the LNT + in situ SCR NOx Emission

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Control Concept | Department of Energy Product Speciation Studies of the LNT + in situ SCR NOx Emission Control Concept Laboratory Product Speciation Studies of the LNT + in situ SCR NOx Emission Control Concept Understanding the detailed chemistry of Nox Reduction across the combined LNT+SCR system. PDF icon deer10_crocker.pdf More Documents & Publications Development of Optimal Catalyst Designs and Operating Strategies for Lean NOx Reduction in Coupled LNT-SCR Systems Lean NOx

  2. High-Throughput Program for the Discovery of NOx Reduction Catalysts |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy High-Throughput Program for the Discovery of NOx Reduction Catalysts High-Throughput Program for the Discovery of NOx Reduction Catalysts 2004 Diesel Engine Emissions Reduction (DEER) Conference Presentation: General Motors Corporation PDF icon 2004_deer_blint.pdf More Documents & Publications WA_02_042_GENERAL_MOTORS_POWER_TRAIN_DIV_Waiver_of_Domestic_.pdf Heavy-Duty NOx Emissions Control: Reformer-Assisted vs. Plasma-Facilitated Lean NOx Catalysis Lean-NOx Catalyst

  3. APBF-DEC Light-duty NOx Adsorber/DPF Project | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Light-duty NOx Adsorber/DPF Project APBF-DEC Light-duty NOx Adsorber/DPF Project 2003 DEER Conference Presentation: FEV Technology, Inc. PDF icon deer_2003_tomazic.pdf More Documents & Publications Status of APBF-DEC NOx Adsorber/DPF Projects APBF-DEC NOx Adsorber/DPF Project: SUV/Pick-Up Platform APBF- DEC Heavy-Duty NOx Adsorber/DPF Project: Catalyst Aging Study

  4. Combining Low-Temperature Combustion with Lean-NOx Trap Yields Progress

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Toward Targets of Efficient NOx Control for Diesels | Department of Energy Low-Temperature Combustion with Lean-NOx Trap Yields Progress Toward Targets of Efficient NOx Control for Diesels Combining Low-Temperature Combustion with Lean-NOx Trap Yields Progress Toward Targets of Efficient NOx Control for Diesels 2005 Diesel Engine Emissions Reduction (DEER) Conference Presentations and Posters PDF icon 2005_deer_huff.pdf More Documents & Publications Intra-catalyst Reductant Chemistry in

  5. Status of APBF-DEC NOx Adsorber/DPF Projects | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    APBF-DEC NOx Adsorber/DPF Projects Status of APBF-DEC NOx Adsorber/DPF Projects 2002 DEER Conference Presentation: Oak Ridge National Laboratory PDF icon 2002_deer_west.pdf More Documents & Publications APBF-DEC Light-duty NOx Adsorber/DPF Project APBF-DEC NOx Adsorber/DPF Project: SUV/Pick-Up Platform APBF- DEC Heavy-Duty NOx Adsorber/DPF Project: Catalyst Aging Study

  6. Deliverable for F?ST project: Ln Resin based PLE

    SciTech Connect (OSTI)

    Peterson, Dominic S.; Armenta, Claudine E.; Rim, Jung H.

    2012-05-03

    This memo describes the fabrication of a polymer ligand extractant based on Eichrom's LN-1 resin. This work has been in support of the Fast Alpha Spectrometry Tool (F{alpha}ST) project. The first part of LANL's role in this project is to evaluate new extractants for use in polymer ligand extractants (PLEs). The first new extractant evaluated is Di(2-ethyl hexyl) phosphoric acid (HDEHP), which is an effective metal extractant. It has very efficient chelating properties for a wide variety of metal ions. HDEHP is an amphiphillic molecule with two long hydrocarbon chains and a polar end with a phosphoryl oxygen (P=O) and an acidic -OH group as shown in Figure 1. HDEHP has shown effectiveness in extracting lanthanides, selective actinides, and other trivalent elements. Several authors have reported that lanthanides and elements with +3 oxidation state have similar extraction behavior in nitric acid. The distribution ratio for lanthanides rapidly decreases at lower nitric concentration then start to increase at higher concentration as shown in. The trivalent americium, curium, and yttrium exhibit similar trend as trivalent lanthanides. This extraction trend can be also observed from hydrogen chloride solution. This work describes the use of this ligand in a PLE to extract plutonium from solution. Polymer ligand films were prepared by dissolving HDEHP ligands and polystyrene beads in THF. The solution was directly deposited onto a 40 mm diameter stainless steel substrate using an automated pipette. HDEHP based PLEs with direct stippling method are shown in Figure 2. The solution was air dried at room temperature overnight to ensure complete evaporation of THF. The plutonium tracer solution was prepared in 0.01, 0.1, 1, and 8M nitric solutions to study the effect of nitric concentration in plutonium extraction. 0.1667 Bq {sup 239}Pu tracer solution was directly stippled on each PLE and was allowed to equilibrate for 3 hours before removing the solution. The plutonium activity of each sample was measured by direct alpha counting to quantify the plutonium recovery by HDEHP PLE. The alpha spectra from alpha spectroscopy are shown in Figure 3. 1:5, 1:10, and 1:20 PLEs had sharp peak with low tailing. 1:2 had an extremely long tail, which is a possible indication that a large amount of ligands caused the film to not form a smooth surface. Also, it can be noted that 1:2 ratio PLE surface was not as rigid as the other ratio PLEs and it was prone to scratching during sample handing. The resolution of alpha spectra was quantified by measuring Full Width at Half of the Maximum (FWHM) using Bortels equation. The tailing component of the peak was also measured along with FWHM. The peak resolutions and tailing measurements for 0.1M nitric solution samples are given in Table 1. The best resolution was achieved with 1:5 PLE and worst was given by 1:2 PLE. The plutonium recovery by HDEHP PLE was dependent on both nitric concentration and ligand to polymer ratio. 1:2 PLE consistently had the highest recovery followed by 1:5 as shown in Figure 4. It should be noted that 1:2 ratio PLEs consistently had long tailing and the ROI of the spectrum had to be increased to encompass total counts from the tracer. 1:10 and 1:20 PLEs had close to zero percent recovery in all nitric concentration except for 0.01M. The highest plutonium recovery was observed for 0.1M nitric acid. 1:5 PLE gave the best combination of alpha spectroscopy resolution and plutonium recovery. Radiography image of samples were generated to study the plutonium distribution on the PLE surface. Samples were placed on an imaging plate (Fujifilm BAS-TR 2025) for 24 hours and the plate was scanned using GE Typhoon FLA 7000 system. The radiography image in Figure 5 shows uneven distribution with hot spots along the edge and in the center of the samples. These hot spots may be the result of highly localized concentration of ligands or surface defects that were observed in SEM. This unevenness in distribution may cause inaccurate activity measurement by alpha spectroscopy due to a bias in the

  7. Ammonia storage and delivery systems for NOx aftertreatment | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy storage and delivery systems for NOx aftertreatment Ammonia storage and delivery systems for NOx aftertreatment Poster presenation at the 2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER 2007). 13-16 August, 2007, Detroit, Michigan. Sponsored by the U.S. Department of Energy's (DOE) Office of FreedomCAR and Vehicle Technologies (OFCVT). PDF icon deer07_johannessen.pdf More Documents & Publications 3rd Generation SCR System Using Solid Ammonia Storage and

  8. NOx Adsorbers for Heavy Duty Truck Engines - Testing and Simulation |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Adsorbers for Heavy Duty Truck Engines - Testing and Simulation NOx Adsorbers for Heavy Duty Truck Engines - Testing and Simulation This report provides the results of an analytical and experimental sA PDF icon 2002_deer_hakim.pdf More Documents & Publications Use of a Diesel Fuel Processor for Rapid and Efficient Regeneration of Single Leg NOx Adsorber Systems Design, Modeling, and Validation of a Flame Reformer for LNT External Bypass Regeneration Cleaner Vehicles,

  9. Power Generating Stationary Engines Nox Control: A Closed Loop Control

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Technology | Department of Energy Generating Stationary Engines Nox Control: A Closed Loop Control Technology Power Generating Stationary Engines Nox Control: A Closed Loop Control Technology Poster presented at the 16th Directions in Engine-Efficiency and Emissions Research (DEER) Conference in Detroit, MI, September 27-30, 2010. PDF icon p-11_servati.pdf More Documents & Publications A Low-Cost Continuous Emissions Monitoring System for Mobile and Stationary Engine SCR/DPF

  10. Diesel DeNOx Catalyst - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Vehicles and Fuels Vehicles and Fuels Industrial Technologies Industrial Technologies Advanced Materials Advanced Materials Find More Like This Return to Search Diesel DeNOx Catalyst New Argonne-Developed Catalyst Can Reduce NOx Emissions From Diesel Engines by 80-85% Argonne National Laboratory Contact ANL About This Technology Inventor Chris Marshall shows the new catalyst that could help remove nitrogen oxides from diesel engine exhaust while saving energy. Inventor Chris Marshall shows the

  11. Functionality of Commercial NOx Storage-Reduction Catalysts and the

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Development of a Representative Model | Department of Energy Functionality of Commercial NOx Storage-Reduction Catalysts and the Development of a Representative Model Functionality of Commercial NOx Storage-Reduction Catalysts and the Development of a Representative Model Presentation given at the 16th Directions in Engine-Efficiency and Emissions Research (DEER) Conference in Detroit, MI, September 27-30, 2010. PDF icon deer10_toops1.pdf More Documents & Publications Pre-Competitive

  12. Further improvement of conventional diesel NOx aftertreatment concepts as

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    pathway for SULEV | Department of Energy Further improvement of conventional diesel NOx aftertreatment concepts as pathway for SULEV Further improvement of conventional diesel NOx aftertreatment concepts as pathway for SULEV Discusses possible improvement potential and various pathways for LNT after-treatment systems for diesel applications to comply with Tier 2 Bin 5 and SULEV regulations PDF icon deer11_nanjundaswamy.pdf More Documents & Publications Future Directions in Engines and

  13. Enhanced High Temperature Performance of NOx Storage/Reduction (NSR)

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Materials | Department of Energy 0 DOE Vehicle Technologies and Hydrogen Programs Annual Merit Review and Peer Evaluation Meeting, June 7-11, 2010 -- Washington D.C. PDF icon ace026_peden_2010_o.pdf More Documents & Publications Mechanisms of Sulfur Poisoning of NOx Adsorber (LNT) Materials Enhanced High Temperature Performance of NOx Storage/Reduction (NSR) Materials Deactivation Mechanisms of Base Metal/Zeolite Urea Selective Catalytic Reduction

  14. Enhanced High and Low Temperature Performance of NOx Reduction Materials |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy and Low Temperature Performance of NOx Reduction Materials Enhanced High and Low Temperature Performance of NOx Reduction Materials 2013 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting PDF icon ace026_peden_2013_o.pdf More Documents & Publications Vehicle Technologies Office Merit Review 2015: CLEERS: Aftertreatment Modeling and Analysis CLEERS Aftertreatment Modeling and Analysis

  15. Cost Analysis of NOx Control Alternatives for Stationary Gas Turbines,

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    November 1999 | Department of Energy Cost Analysis of NOx Control Alternatives for Stationary Gas Turbines, November 1999 Cost Analysis of NOx Control Alternatives for Stationary Gas Turbines, November 1999 The use of stationary gas turbines for power generation has been growing rapidly with continuing trends predicted well into the future. This study compares the costs of the principal emission control technologies being employed or nearing commercialization for control of oxides of

  16. Development of Materials Analysis Tools for Studying NOx Adsorber Catalysts

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    A cooperative research and development agreement with Cummins Engine Company | Department of Energy Materials Analysis Tools for Studying NOx Adsorber Catalysts A cooperative research and development agreement with Cummins Engine Company Development of Materials Analysis Tools for Studying NOx Adsorber Catalysts A cooperative research and development agreement with Cummins Engine Company 2005 Diesel Engine Emissions Reduction (DEER) Conference Presentations and Posters PDF icon

  17. Virtual Oxygen Sensor for Innovative NOx and PM Emission Control

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Technologies | Department of Energy Virtual Oxygen Sensor for Innovative NOx and PM Emission Control Technologies Virtual Oxygen Sensor for Innovative NOx and PM Emission Control Technologies A virtual O2 sensor for the intake manifold of a diesel engine equipped with EGR, along with a virtual intake manifold O2 sensor, show good accuracy with stationary measurements PDF icon deer09_traver.pdf More Documents & Publications Simulation and Analysis of HP/LP EGR for Heavy-Duty Applications

  18. Bringing the Low NOx Diesel Under Control | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Bringing the Low NOx Diesel Under Control Bringing the Low NOx Diesel Under Control Presentation given at DEER 2006, August 20-24, 2006, Detroit, Michigan. Sponsored by the U.S. DOE's EERE FreedomCar and Fuel Partnership and 21st Century Truck Programs. PDF icon 2006_deer_pinson.pdf More Documents & Publications Diesel Emission Control Technology Review Advanced Diesel Engine Technology Development for HECC Enabling High Efficiency Clean

  19. CLEERS Activities: Diesel Soot Filter Characterization & NOx Control

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fundamentals | Department of Energy Activities: Diesel Soot Filter Characterization & NOx Control Fundamentals CLEERS Activities: Diesel Soot Filter Characterization & NOx Control Fundamentals 2009 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C. PDF icon ace_21_herling.pdf More Documents & Publications CLEERS Aftertreatment Modeling and Analysis Hydrocarbon Inhibition and HC Storage Modeling

  20. Three-Dimensional Composite Nanostructures for Lean NOx Emission Control |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy 2 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting PDF icon ace030_gao_2012_o.pdf More Documents & Publications Monolithic Metal Oxide based Composite Nanowire Lean NOx Emission Control Catalysts Three-Dimensional Composite Nanostructures for Lean NOx Emission Control Vehicle Technologies Office Merit Review 2015: Metal Oxide Nano-Array Catalysts for Low Temperature Diesel Oxidation

  1. Thermal Expansion of the Orthorhombic Phase in the Ln[subscript

    Office of Scientific and Technical Information (OSTI)

    2]TiO[subscript 5] System (Journal Article) | SciTech Connect Journal Article: Thermal Expansion of the Orthorhombic Phase in the Ln[subscript 2]TiO[subscript 5] System Citation Details In-Document Search Title: Thermal Expansion of the Orthorhombic Phase in the Ln[subscript 2]TiO[subscript 5] System Authors: Seymour, Kevin C. ; Hughes, Robert W. ; Kriven, Waltraud M. [1] + Show Author Affiliations (UIUC) Publication Date: 2015-12-10 OSTI Identifier: 1229897 Resource Type: Journal Article

  2. DOE - Office of Legacy Management -- LASL Land Parcels A B C E K LN PL - NM

    Office of Legacy Management (LM)

    07 Land Parcels A B C E K LN PL - NM 07 FUSRAP Considered Sites Site: LASL LAND PARCELS A, B, C, E, K, LN, PL (NM.07 ) Eliminated from consideration under FUSRAP Designated Name: Not Designated Alternate Name: None Location: Los Alamos County , New Mexico NM.07-2 Evaluation Year: 1986 NM.07-1 Site Operations: No specific operations identified for these tracts of land. NM.07-1 NM.07-2 Site Disposition: Eliminated - Radiation levels below criteria. Declared as surplus real property and offered

  3. NOx reduction aftertreatment system using nitrogen nonthermal plasma desorption

    SciTech Connect (OSTI)

    Okubo, M.; Inoue, M.; Kuroki, T.; Yamamoto, T.

    2005-08-01

    In the flue emission from an internal combustion system using diffusing combustion such as coal or oil fuel boiler, incinerator, or diesel engine, around 10% oxygen is usually included. It is difficult to reduce the NOx in the emission completely using catalysts or plasma alone because part of the NO is oxidized under an O{sub 2}-rich environment. In order to overcome these difficulties, we propose a new aftertreatment system of NOx included in the exhaust gas of the combustion system using nonthermal plasma (NTP) desorption and reduction. In this system, exchangeable adsorbent columns are equipped. As an initial step to realize such kind of aftertreatment system, the basic characteristics of the N{sub 2} NTP desorption and NOx reduction were examined experimentally using a pulse corona NTP reactor. After several adsorption/desorption processes, the amount of NOx adsorbed becomes equal to that of the NOx desorbed, that is, all the NO, was desorbed in a single desorption process. It is confirmed that the NOx complete reduction using N{sub 2} NTP desorption is possible not only for a simulated exhaust gas but for a real diesel engine gas. The effective specific energy density can be decreased down to 22 Wh/m{sup 3}.

  4. Structural integrity assessment of type 201LN stainless steel cryogenic pressure vessels

    SciTech Connect (OSTI)

    Rana, M.D.; Zawierucha, R.

    1995-12-01

    The ASME Boiler and Pressure Vessel Code Committee approved the Code Case 2123 in 1992 which allows the use of Type 201LN stainless steel in the construction of ASME Section VIII, Division 1 and Division 2 pressure vessels for -320{degrees}F applications. Type 201LN stainless steel is a nitrogen strengthened modified version of ASTM A240, Type 201 stainless steel with a restricted chemistry. The Code allowable design stresses for Type 201LN for Division 1 vessels are approximately 27% higher than Type 304 stainless steel and equal to that of the 5 Ni and 9 Ni steels. This paper discusses the important features of the Code Case 2123 and the structural integrity assessment of Type 201LN stainless steel cryogenic vessels. Tensile, Charpy-V-notch and fracture properties have been obtained on several heats of this steel including weldments. A linear-elastic fracture mechanics analysis has been conducted to assess the expected fracture mode and the fracture-critical crack sizes. The results have been compared with Type 304 stainless steel, 5 Ni and 9 Ni steel vessels.

  5. Evaluation of Fluid Conduction and Mixing within a Subassembly of the Actinide Burner Test Reactor

    SciTech Connect (OSTI)

    Cliff B. Davis

    2007-09-01

    The RELAP5-3D code is being considered as a thermal-hydraulic system code to support the development of the sodium-cooled Actinide Burner Test Reactor as part of the Global Nuclear Energy Partnership. An evaluation was performed to determine whether the control system could be used to simulate the effects of non-convective mechanisms of heat transport in the fluid, including axial and radial heat conduction and subchannel mixing, that are not currently represented with internal code models. The evaluation also determined the relative importance of axial and radial heat conduction and fluid mixing on peak cladding temperature for a wide range of steady conditions and during a representative loss-of-flow transient. The evaluation was performed using a RELAP5-3D model of a subassembly in the Experimental Breeder Reactor-II, which was used as a surrogate for the Actinide Burner Test Reactor.

  6. Effect of Thermal Aging on NO oxidation and NOx storage in a

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fully-Formulated Lean NOx Trap | Department of Energy Thermal Aging on NO oxidation and NOx storage in a Fully-Formulated Lean NOx Trap Effect of Thermal Aging on NO oxidation and NOx storage in a Fully-Formulated Lean NOx Trap Thermal aging of LNT has numerous material and chemical effects PDF icon deer09_toops.pdf More Documents & Publications Impacts of Biodiesel on Emission Control Devices NOx Abatement Research and Development CRADA with Navistar Incorporated Thermal Deactivation

  7. Pollutant Exposures from Natural Gas Cooking Burners: A Simulation-Based Assessment for Southern California

    SciTech Connect (OSTI)

    Logue, Jennifer M.; Klepeis, Neil E.; Lobscheid, Agnes B.; Singer, Brett C.

    2014-06-01

    Residential natural gas cooking burners (NGCBs) can emit substantial quantities of pollutants and they are typically used without venting. The objective of this study is to quantify pollutant concentrations and occupant exposures resulting from NGCB use in California homes. A mass balance model was applied to estimate time-dependent pollutant concentrations throughout homes and the "exposure concentrations" experienced by individual occupants. The model was applied to estimate nitrogen dioxide (NO{sub 2}), carbon monoxide (CO), and formaldehyde (HCHO) concentrations for one week each in summer and winter for a representative sample of Southern California homes. The model simulated pollutant emissions from NGCBs, NO{sub 2} and CO entry from outdoors, dilution throughout the home, and removal by ventilation and deposition. Residence characteristics and outdoor concentrations of CO and NO{sub 2} were obtained from available databases. Ventilation rates, occupancy patterns, and burner use were inferred from household characteristics. Proximity to the burner(s) and the benefits of using venting range hoods were also explored. Replicate model executions using independently generated sets of stochastic variable values yielded estimated pollutant concentration distributions with geometric means varying less than 10%. The simulation model estimates that in homes using NGCBs without coincident use of venting range hoods, 62%, 9%, and 53% of occupants are routinely exposed to NO{sub 2}, CO, and HCHO levels that exceed acute health-based standards and guidelines. NGCB use increased the sample median of the highest simulated 1-hr indoor concentrations by 100, 3000, and 20 ppb for NO{sub 2}, CO, and HCHO, respectively. Reducing pollutant exposures from NGCBs should be a public health priority. Simulation results suggest that regular use of even moderately effective venting range hoods would dramatically reduce the percentage of homes in which concentrations exceed health-based standards.

  8. Large eddy simulation of forced ignition of an annular bluff-body burner

    SciTech Connect (OSTI)

    Subramanian, V.; Domingo, P.; Vervisch, L.

    2010-03-15

    The optimization of the ignition process is a crucial issue in the design of many combustion systems. Large eddy simulation (LES) of a conical shaped bluff-body turbulent nonpremixed burner has been performed to study the impact of spark location on ignition success. This burner was experimentally investigated by Ahmed et al. [Combust. Flame 151 (2007) 366-385]. The present work focuses on the case without swirl, for which detailed measurements are available. First, cold-flow measurements of velocities and mixture fractions are compared with their LES counterparts, to assess the prediction capabilities of simulations in terms of flow and turbulent mixing. Time histories of velocities and mixture fractions are recorded at selected spots, to probe the resolved probability density function (pdf) of flow variables, in an attempt to reproduce, from the knowledge of LES-resolved instantaneous flow conditions, the experimentally observed reasons for success or failure of spark ignition. A flammability map is also constructed from the resolved mixture fraction pdf and compared with its experimental counterpart. LES of forced ignition is then performed using flamelet fully detailed tabulated chemistry combined with presumed pdfs. Various scenarios of flame kernel development are analyzed and correlated with typical flow conditions observed in this burner. The correlations between, velocities and mixture fraction values at the sparking time and the success or failure of ignition, are then further discussed and analyzed. (author)

  9. Flexible CHP System with Low NOx, CO and VOC Emissions - Fact...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CHP System with Low NOx, CO and VOC Emissions - Fact Sheet, 2014 Flexible CHP System with Low NOx, CO and VOC Emissions - Fact Sheet, 2014 The Gas Technology Institute, in ...

  10. Flexible CHP System with Low NOx, CO, and VOC Emissions - Presentation...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Flexible CHP System with Low NOx, CO, and VOC Emissions - Presentation by the Gas Technology Institute (GTI), June 2011 Flexible CHP System with Low NOx, CO, and VOC Emissions - ...

  11. Diesel NOx-PM Reduction with Fuel Economy Increase by IMET-OBC...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    NOx-PM Reduction with Fuel Economy Increase by IMET-OBC-DPF + Hydrated-EGR System for Retrofit of In-Use Trucks Diesel NOx-PM Reduction with Fuel Economy Increase by...

  12. NH3 generation over commercial Three-Way Catalysts and Lean-NOx...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    generation over commercial Three-Way Catalysts and Lean-NOx Traps NH3 generation over commercial Three-Way Catalysts and Lean-NOx Traps Research to identify most promising...

  13. Simultaneously Low-Engine-Out NOx and PM with Highly Diluted...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Simultaneously Low-Engine-Out NOx and PM with Highly Diluted Diesel Combustuion Simultaneously Low-Engine-Out NOx and PM with Highly Diluted Diesel Combustuion 2002 DEER Conference...

  14. Fuel-Borne Reductants for NOx Aftertreatment: Preliminary EtOH...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Reductants for NOx Aftertreatment: Preliminary EtOH SCR Study Fuel-Borne Reductants for NOx Aftertreatment: Preliminary EtOH SCR Study 2003 DEER Conference Presentation: Oak Ridge...

  15. APBF-DEC Heavy Duty NOx Adsorber/DPF Project: Heavy Duty Linehaul...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Heavy Duty NOx AdsorberDPF Project: Heavy Duty Linehaul Platform Project Update APBF-DEC Heavy Duty NOx AdsorberDPF Project: Heavy Duty Linehaul Platform Project Update 2003 DEER ...

  16. Development of NOx Adsorber System for Dodge Ram 2007 Heavy duty...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    NOx Adsorber System for Dodge Ram 2007 Heavy duty Pickup Truck Development of NOx Adsorber System for Dodge Ram 2007 Heavy duty Pickup Truck Presentation given at the 2007 Diesel ...

  17. APBF- DEC Heavy-Duty NOx Adsorber/DPF Project: Catalyst Aging...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    DEC Heavy-Duty NOx AdsorberDPF Project: Catalyst Aging Study APBF- DEC Heavy-Duty NOx AdsorberDPF Project: Catalyst Aging Study 2004 Diesel Engine Emissions Reduction (DEER) ...

  18. Intra-catalyst Reductant Chemistry in Lean NOx Traps: A Study...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Intra-catalyst Reductant Chemistry in Lean NOx Traps: A Study on Sulfur Effects Intra-catalyst Reductant Chemistry in Lean NOx Traps: A Study on Sulfur Effects Presentation given ...

  19. Combining Low-Temperature Combustion with Lean-NOx Trap Yields...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Low-Temperature Combustion with Lean-NOx Trap Yields Progress Toward Targets of Efficient ... Intra-catalyst Reductant Chemistry in Lean NOx Traps: A Study on Sulfur Effects Reductant ...

  20. A Fast Start-up On-Board Fuel Reformer for NOx Adsorber Regeneration...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    A Fast Start-up On-Board Fuel Reformer for NOx Adsorber Regeneration and Desulfation A Fast Start-up On-Board Fuel Reformer for NOx Adsorber Regeneration and Desulfation 2004 ...

  1. Combining Biodiesel and EGR for Low-Temperature NOx and PM Reductions...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Biodiesel and EGR for Low-Temperature NOx and PM Reductions Combining Biodiesel and EGR for Low-Temperature NOx and PM Reductions Poster presentation at the 2007 Diesel ...

  2. Effect of Engine-Out NOx Control Strategies on PM Size Distribution...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Engine-Out NOx Control Strategies on PM Size Distribution in Heavy-Duty Diesel Engines Developed for 2010 Effect of Engine-Out NOx Control Strategies on PM Size Distribution in ...

  3. Compact Electrochemical Bi-functional NOx/O2 Sensors with an...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Compact Electrochemical Bi-functional NOxO2 Sensors with an Internal Reference for High Temperature Applications Compact Electrochemical Bi-functional NOxO2 Sensors with an...

  4. Investigation of Aging Mechanisms in Lean NOx Traps | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Aging Mechanisms in Lean NOx Traps Investigation of Aging Mechanisms in Lean NOx Traps 2009 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C. PDF icon ace_26_crocker.pdf More Documents & Publications Pt-free, Perovskite-based Lean NOx Trap Catalysts CLEERS Coordination & Development of Catalyst Process Kinetic Data Lean NOx Reduction with Dual Layer LNT/SCR Catalysts

  5. Investigation on continuous soot oxidation and NOx reduction by SCR coated

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    DPF | Department of Energy on continuous soot oxidation and NOx reduction by SCR coated DPF Investigation on continuous soot oxidation and NOx reduction by SCR coated DPF Evaluation of CSI catalyst for NOx removal and soot oxidation. PDF icon deer09_iretskaya.pdf More Documents & Publications Development of SCR on Diesel Particulate Filter System for Heavy Duty Applications Two Catalyst Formulations - One Solution for NOx After-treatment Systems SCR-DPF Integrations for Diesel

  6. Development on simultaneous reduction system of NOx and PM from a diesel

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    engine | Department of Energy on simultaneous reduction system of NOx and PM from a diesel engine Development on simultaneous reduction system of NOx and PM from a diesel engine 2003 DEER Converence Presentation: Toyota Motor Corporation PDF icon 2003_deer_watanabe.pdf More Documents & Publications An Improvement of Diesel PM and NOx Reduction System An Improvement of Diesel PM and NOx Reduction System EPA Mobile Source Rule Update

  7. Two Catalyst Formulations - One Solution for NOx After-treatment Systems |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Catalyst Formulations - One Solution for NOx After-treatment Systems Two Catalyst Formulations - One Solution for NOx After-treatment Systems Low-temperature SCR combined with standard high-temperature SCR catalyst formulation in one system provides high NOx conversion over wide temperature range. PDF icon deer08_iretskaya.pdf More Documents & Publications Investigation on continuous soot oxidation and NOx reduction by SCR coated DPF Advanced Technology Light Duty

  8. Synergies of High-Efficiency Clean Combustion and Lean NOx Trap Catalysts |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Synergies of High-Efficiency Clean Combustion and Lean NOx Trap Catalysts Synergies of High-Efficiency Clean Combustion and Lean NOx Trap Catalysts investigation of potential synergies of low emission advanced combustion techniques and advanced lean exhaust catalytic aftertreatment. PDF icon deer08_parks.pdf More Documents & Publications Measurement and Characterization of Lean NOx Adsorber Regeneration and Desulfation and Controlling NOx from Multi-mode High

  9. Electrochemical NOx Sensor for Monitoring Diesel Emissions

    SciTech Connect (OSTI)

    Woo, L Y; Glass, R S

    2008-11-14

    Increasingly stringent emissions regulations will require the development of advanced gas sensors for a variety of applications. For example, compact, inexpensive sensors are needed for detection of regulated pollutants, including hydrocarbons (HCs), CO, and NO{sub x}, in automotive exhaust. Of particular importance will be a sensor for NO{sub x} to ensure the proper operation of the catalyst system in the next generation of diesel (CIDI) automobiles. Because many emerging applications, particularly monitoring of automotive exhaust, involve operation in harsh, high-temperature environments, robust ceramic-oxide-based electrochemical sensors are a promising technology. Sensors using yttria-stabilized zirconia (YSZ) as an oxygen-ion-conducting electrolyte have been widely reported for both amperometric and potentiometric modes of operation. These include the well-known exhaust gas oxygen (EGO) sensor. More recently, ac impedance-based (i.e., impedance-metric) sensing techniques using YSZ have been reported for sensing water vapor, hydrocarbons, CO, and NO{sub x}. Typically small-amplitude alternating signal is applied, and the sensor response is measured at a specified frequency. Most impedance-metric techniques have used the modulus (or magnitude) at low frequencies (< 1 Hz) as the sensing signal and attribute the measured response to interfacial phenomena. Work by our group has also investigated using phase angle as the sensing signal at somewhat higher frequencies (10 Hz). The higher frequency measurements would potentially allow for reduced sampling times during sensor operation. Another potential advantage of impedance-metric NO{sub x} sensing is the similarity in response to NO and NO{sub 2} (i.e., total-NO{sub x} sensing). Potentiometric NO{sub x} sensors typically show higher sensitivity to NO2 than NO, and responses that are opposite in sign. However, NO is more stable than NO{sub 2} at temperatures > 600 C, and thermodynamic calculations predict {approx}90% NO, balance NO{sub 2}. Since automotive exhaust sensors will probably be required to operate at temperatures > 600 C, NO is the dominant component in thermodynamic equilibrium and the target NOx species. Also, the use of upstream catalysts could further promote the conversion of NO{sub x} species to NO. Therefore, the focus of current work is to investigate the response to NO. Nevertheless, minimizing the sensitivity to a variety of competing species is important in order to obtain the accuracy necessary for achieving the emission limits. Mitigating the effect of interfering gases (e.g., O{sub 2}, water vapor, HCs, etc.) is an area of current study. For impedance metric NO{sub x} sensors, our previous work has demonstrated that the cross-sensitivity to O{sub 2} may be accounted for by comparing measurements at multiple frequencies. Other strategies for compensation are also being explored, including calibration using data from existing sensors located nearby. Our current work has made significant advances in terms of developing prototype sensors more suitable for commercialization. Also, dynamometer testing has provided real-world sensor performance data that will be useful in approaching potential suppliers to whom we can transfer the technology for commercialization. The advances are a direct result of understanding the sensing mechanisms responsible for impedance-based NO{sub x} sensing and the effect of materials choice and sensor design/geometry.

  10. Impact of Sulfur Dioxide on Lean NOx Trap Catalysts | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Sulfur Dioxide on Lean NOx Trap Catalysts Impact of Sulfur Dioxide on Lean NOx Trap Catalysts 2004 Diesel Engine Emissions Reduction (DEER) Conference Presentation: University of New Mexico PDF icon 2004_deer_hammache.pdf More Documents & Publications CLEERS Aftertreatment Modeling and Analysis CLEERS Aftertreatment Modeling and Analysis An Improvement of Diesel PM and NOx Reduction System

  11. Low NOx combustion using cogenerated oxygen and nitrogen streams

    DOE Patents [OSTI]

    Kobayashi, Hisashi (Putnam Valley, NY); Bool, Lawrence E. (East Aurora, NY); Snyder, William J. (Ossining, NY)

    2009-02-03

    Combustion of hydrocarbon fuel is achieved with less formation of NOx by feeding the fuel into a slightly oxygen-enriched atmosphere, and separating air into oxygen-rich and nitrogen-rich streams which are fed separately into the combustion device.

  12. NOx, SOx & CO{sub 2} mitigation using blended coals

    SciTech Connect (OSTI)

    Labbe, D.

    2009-11-15

    Estimates of potential CO{sub 2} reduction achievable through the use of a mixture of bituminous and subbituminous (PRB) coals, whilst attaining NOx and SOx compliance are presented. The optimization considerations to provide satisfactory furnace, boiler and unit performance with blended coal supplies to make such operation feasible are discussed. 6 refs., 7 figs., 1 tab.

  13. The Chemistry of the Thermal DeNOx Process: A Review of the Technology's Possible Application to control of NOx from Diesel Engines

    SciTech Connect (OSTI)

    Lyon, Richard

    2001-08-05

    This paper presents a review of the Thermal DeNOx process with respect to its application to control of NOx emissions from diesel engines. The chemistry of the process is discussed first in empirical and then theoretical terms. Based on this discussion the possibilities of applying the process to controlling NOx emissions from diesel engines is considered. Two options are examined, modifying the requirements of the chemistry of the Thermal DeNOx process to suit the conditions provided by diesel engines and modifying the engines to provide the conditions required by the process chemistry. While the former examination did not reveal any promising opportunities, the latter did. Turbocharged diesel engine systems in which the turbocharger is a net producer of power seem capable of providing the conditions necessary for NOx reduction via the Thermal DeNOx reaction.

  14. Enhanced High Temperature Performance of NOx Reduction Catalyst Materials

    SciTech Connect (OSTI)

    Gao, Feng; Kim, Do Heui; Luo, Jinyong; Muntean, George G.; Peden, Charles HF; Howden, Ken; Currier, Neal; Kamasamudram, Krishna; Kumar, Ashok; Li, Junhui; Stafford, Randy; Yezerets, Aleksey; Castagnola, Mario; Chen, Hai Ying; Hess, Howard ..

    2012-12-31

    Two primary NOx after-treatment technologies have been recognized as the most promising approaches for meeting stringent NOx emission standards for diesel vehicles within the Environmental Protection Agencys (EPAs) 2007/2010 mandated limits, NOx Storage Reduction (NSR) and NH3 selective catalytic reduction (SCR); both are, in fact being commercialized for this application. However, in looking forward to 2015 and beyond with expected more stringent regulations, the continued viability of the NSR technology for controlling NOx emissions from lean-burn engines such as diesels will require at least two specific, significant and inter-related improvements. First, it is important to reduce system costs by, for example, minimizing the precious metal content while maintaining, even improving, performance and long-term stability. A second critical need for future NSR systems, as well as for NH3 SCR, will be significantly improved higher and lower temperature performance and stability. Furthermore, these critically needed improvements will contribute significantly to minimizing the impacts to fuel economy of incorporating these after-treatment technologies on lean-burn vehicles. To meet these objectives will require, at a minimum an improved scientific understanding of the following things: i) the various roles for the precious and coinage metals used in these catalysts; ii) the mechanisms for these various roles; iii) the effects of high temperatures on the active metal performance in their various roles; iv) mechanisms for higher temperature NOx storage performance for modified and/or alternative storage materials; v) the interactions between the precious metals and the storage materials in both optimum NOx storage performance and long term stability; vi) the sulfur adsorption and regeneration mechanisms for NOx reduction materials; vii) materials degradation mechanisms in CHA-based NH3 SCR catalysts. The objective of this CRADA project between PNNL and Cummins, Inc. is to develop a fundamental understanding of the above-listed issues. Model catalysts that are based on literature formulations are the focus of the work being carried out at PNNL. In addition, the performance and stability of more realistic high temperature NSR catalysts, supplied by JM, are being studied in order to provide baseline data for the model catalysts that are, again, based on formulations described in the open literature. For this short summary, we will primarily highlight representative results from our recent studies of the stability of candidate high temperature NSR materials.

  15. Catalytic Combustion for Ultra-Low NOx Hydrogen Turbines

    SciTech Connect (OSTI)

    Etemad, Shahrokh; Baird, Benjamin; Alavandi, Sandeep

    2011-06-30

    Precision Combustion, Inc., (PCI) in close collaboration with Solar Turbines, Incorporated, has developed and demonstrated a combustion system for hydrogen fueled turbines that reduces NOx to low single digit level while maintaining or improving current levels of efficiency and eliminating emissions of carbon dioxide. Full scale Rich Catalytic Hydrogen (RCH1) injector was developed and successfully tested at Solar Turbines, Incorporated high pressure test facility demonstrating low single digit NOx emissions for hydrogen fuel in the range of 2200F-2750F. This development work was based on initial subscale development for faster turnaround and reduced cost. Subscale testing provided promising results for 42% and 52% H2 with NOx emissions of less than 2 ppm with improved flame stability. In addition, catalytic reactor element testing for substrate oxidation, thermal cyclic injector testing to simulate start-stop operation in a gas turbine environment, and steady state 15 atm. operation testing were performed successfully. The testing demonstrated stable and robust catalytic element component life for gas turbine conditions. The benefit of the catalytic hydrogen combustor technology includes capability of delivering near-zero NOx without costly post-combustion controls and without requirement for added sulfur control. In addition, reduced acoustics increase gas turbine component life. These advantages advances Department of Energy (DOEs) objectives for achievement of low single digit NOx emissions, improvement in efficiency vs. postcombustion controls, fuel flexibility, a significant net reduction in Integrated Gasification Combined Cycle (IGCC) system net capital and operating costs, and a route to commercialization across the power generation field from micro turbines to industrial and utility turbines.

  16. APBF- DEC Heavy-Duty NOx Adsorber/DPF Project: Catalyst Aging Study |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy DEC Heavy-Duty NOx Adsorber/DPF Project: Catalyst Aging Study APBF- DEC Heavy-Duty NOx Adsorber/DPF Project: Catalyst Aging Study 2004 Diesel Engine Emissions Reduction (DEER) Conference Presentation: National Renewable Energy Laboratory PDF icon 2004_deer_whitacre.pdf More Documents & Publications APBF-DEC Light-duty NOx Adsorber/DPF Project Status of APBF-DEC NOx Adsorber/DPF Projects APBF-DEC NOx Adsorber/DPF Project: SUV/Pick-Up Platform

  17. APBF-DEC Heavy Duty NOx Adsorber/DPF Project: Heavy Duty Linehaul Platform

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Project Update | Department of Energy Heavy Duty NOx Adsorber/DPF Project: Heavy Duty Linehaul Platform Project Update APBF-DEC Heavy Duty NOx Adsorber/DPF Project: Heavy Duty Linehaul Platform Project Update 2003 DEER Conference Presentation: Ricardo Inc., Chicago Technical Center PDF icon deer_2003_may.pdf More Documents & Publications Status of APBF-DEC NOx Adsorber/DPF Projects APBF- DEC Heavy-Duty NOx Adsorber/DPF Project: Catalyst Aging Study APBF-DEC Light-duty NOx Adsorber/DPF

  18. Fuel Consumption and NOx Trade-offs on a Port-Fuel-Injected SI Gasoline

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Engine Equipped with a Lean-NOx Trap | Department of Energy NOx Trade-offs on a Port-Fuel-Injected SI Gasoline Engine Equipped with a Lean-NOx Trap Fuel Consumption and NOx Trade-offs on a Port-Fuel-Injected SI Gasoline Engine Equipped with a Lean-NOx Trap Lean-burn improves PFI fuel economy by ~3% relative to best stoichiometric VCT/EGR conditions, when used in combination with VCT & EGR. PDF icon deer09_lymburner.pdf More Documents & Publications Vehicle Technologies Office Merit

  19. Development of ADECS to Meet 2010 Emission Levels: Optimization of NOx, NH3

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Fuel Consumption Using High and Low Engine-Out NOx Calibrations | Department of Energy ADECS to Meet 2010 Emission Levels: Optimization of NOx, NH3 and Fuel Consumption Using High and Low Engine-Out NOx Calibrations Development of ADECS to Meet 2010 Emission Levels: Optimization of NOx, NH3 and Fuel Consumption Using High and Low Engine-Out NOx Calibrations Development and validation of a simple strategy-based technique using four engine parameters to minimize emissions and fuel

  20. Transient Dynamometer Testing of a Single Leg NOx Adsorber Combined with a

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fuel Processor for Enhanced NOx Control | Department of Energy Single Leg NOx Adsorber Combined with a Fuel Processor for Enhanced NOx Control Transient Dynamometer Testing of a Single Leg NOx Adsorber Combined with a Fuel Processor for Enhanced NOx Control Presentation given at DEER 2006, August 20-24, 2006, Detroit, Michigan. Sponsored by the U.S. DOE's EERE FreedomCar and Fuel Partnership and 21st Century Truck Programs. PDF icon 2006_deer_dalla_betta.pdf More Documents & Publications

  1. Hot repair of ceramic burner on hot blast stoves at USS/Kobe`s {number_sign}3 blast furnace

    SciTech Connect (OSTI)

    Bernarding, T.F.; Chemorov, M.; Shimono, S.; Phillips, G.R.

    1997-12-31

    During the 1992 reline of the No. 3 blast furnace, three new stoves were constructed. The design of the stoves, equipped with internal ceramic burners, was for providing a hot blast temperature of 2,000 F at a wind rate of 140,000 SCFM. After 3 years the performance had deteriorated so the burners were cleaned. When a second cleaning did not improve the performance of No. 3 blast furnace, it was decided to repair the refractory while still hot. The paper describes the hot repair procedures, taking a stove off for repairs, maintenance heat up during repairs, two stove operation, stove commissioning, repair of a ceramic burner, and wet gas prevention.

  2. A Metal Fuel Core Concept for 1000 MWt Advanced Burner Reactor

    SciTech Connect (OSTI)

    Yang, W.S.; Kim, T.K.; Grandy, C.

    2007-07-01

    This paper describes the core design and performance characteristics of a metal fuel core concept for a 1000 MWt Advanced Burner Reactor. A ternary metal fuel form of U-TRU-Zr was assumed with weapons grade plutonium feed for the startup core and TRU recovered from LWR spent fuel for the recycled equilibrium core. A compact burner core was developed by trade-off between the burnup reactivity loss and TRU conversion ratio, with a fixed cycle length of one-year. In the startup core, the average TRU enrichment is 15.5%, the TRU conversion ratio is 0.81, and the burnup reactivity loss over a cycle is 3.6% {delta}k. The heavy metal and TRU inventories are 13.1 and 2.0 metric tons, respectively. The average discharge burnup is 93 MWd/kg, and the TRU consumption rate is 55.5 kg/year. For the recycled equilibrium core, the average TRU enrichment is 22.1 %, the TRU conversion ratio is 0.73, and the burnup reactivity loss is 2.2% {delta}k. The TRU inventory and consumption rate are 2.9 metric tons and 81.6 kg/year, respectively. The evaluated reactivity coefficients provide sufficient negative feedbacks. The control systems provide shutdown margins that are more than adequate. The integral reactivity parameters for quasi-static reactivity balance analysis indicate favorable passive safety features, although detailed safety analyses are required to verify passive safety behavior. (authors)

  3. Swozzle based burner tube premixer including inlet air conditioner for low emissions combustion

    DOE Patents [OSTI]

    Tuthill, Richard Sterling (Bolton, CT); Bechtel, II, William Theodore (Scotia, NY); Benoit, Jeffrey Arthur (Scotia, NY); Black, Stephen Hugh (Duanesburg, NY); Bland, Robert James (Clifton Park, NY); DeLeonardo, Guy Wayne (Scotia, NY); Meyer, Stefan Martin (Troy, NY); Taura, Joseph Charles (Clifton Park, NY); Battaglioli, John Luigi (Glenville, NY)

    2002-01-01

    A burner for use in a combustion system of a heavy-duty industrial gas turbine includes a fuel/air premixer having an air inlet, a fuel inlet, and an annular mixing passage. The fuel/air premixer mixes fuel and air into a uniform mixture for injection into a combustor reaction zone. The burner also includes an inlet flow conditioner disposed at the air inlet of the fuel/air premixer for controlling a radial and circumferential distribution of incoming air. The pattern of perforations in the inlet flow conditioner is designed such that a uniform air flow distribution is produced at the swirler inlet annulus in both the radial and circumference directions. The premixer includes a swozzle assembly having a series of preferably air foil shaped turning vanes that impart swirl to the airflow entering via the inlet flow conditioner. Each air foil contains internal fuel flow passages that introduce natural gas fuel into the air stream via fuel metering holes that pass through the walls of the air foil shaped turning vanes. By injecting fuel in this manner, an aerodynamically clean flow field is maintained throughout the premixer. By injecting fuel via two separate passages, the fuel/air mixture strength distribution can be controlled in the radial direction to obtain optimum radial concentration profiles for control of emissions, lean blow outs, and combustion driven dynamic pressure activity as machine and combustor load are varied.

  4. Multi-ported, internally recuperated burners for direct flame impingement heating applications

    DOE Patents [OSTI]

    Abbasi, Hamid A. (Naperville, IL); Kurek, Harry (Dyer, IN); Chudnovsky, Yaroslav (Skokie, IL); Lisienko, Vladimir G. (Ekaterinburg, RU); Malikov, German K. (Ekaterinburg, RU)

    2010-08-03

    A direct flame impingement method and apparatus employing at least one multi-ported, internally recuperated burner. The burner includes an innermost coaxial conduit having a first fluid inlet end and a first fluid outlet end, an outermost coaxial conduit disposed around the innermost coaxial conduit and having a combustion products outlet end proximate the first fluid inlet end of the innermost coaxial conduit and a combustion products inlet end proximate the first fluid outlet end of the innermost coaxial conduit, and a coaxial intermediate conduit disposed between the innermost coaxial conduit and the outermost coaxial conduit, whereby a second fluid annular region is formed between the innermost coaxial conduit and the intermediate coaxial conduit and a combustion products annular region is formed between the intermediate coaxial conduit and the outermost coaxial conduit. The intermediate coaxial conduit has a second fluid inlet end proximate the first fluid inlet end of the innermost coaxial conduit and a second fluid outlet end proximate the combustion products inlet end of the outermost coaxial conduit.

  5. Modeling Population Exposures to Pollutants Emitted from Natural Gas Cooking Burners

    SciTech Connect (OSTI)

    Lobscheid, Agnes; Singer, Brett C.; Klepeis, Neil E.

    2011-06-01

    We developed a physics-based data-supported model to investigate indoor pollutant exposure distributions resulting from use of natural gas cooking appliances across households in California. The model was applied to calculate time-resolved indoor concentrations of CO, NO2 and formaldehyde resulting from cooking burners and entry with outdoor air. Exposure metrics include 1-week average concentrations and frequency of exceeding ambient air quality standards. We present model results for Southern California (SoCal) using two air-exchange scenarios in winter: (1) infiltration-only, and (2) air exchange rate (AER) sampled from lognormal distributions derived from measurements. In roughly 40percent of homes in the SoCal cohort (N=6634) the 1-hour USEPA NO2 standard (190 ?g/m3) was exceeded at least once. The frequency of exceeding this standard was largely independent of AER assumption, and related primarily to building volume, emission rate and amount of burner use. As expected, AER had a more substantial impact on one-week average concentrations.

  6. Investigation on Flame Characteristics and Burner Operability Issues of Oxy-Fuel Combustion

    SciTech Connect (OSTI)

    Choudhuri, Ahsan

    2013-05-30

    Oxy-fuel combustion has been used previously in a wide range of industrial applications. Oxy- combustion is carried out by burning a hydrocarbon fuel with oxygen instead of air. Flames burning in this configuration achieve higher flame temperatures which present opportunities for significant efficiency improvements and direct capture of CO{sub 2} from the exhaust stream. In an effort to better understand and characterize the fundamental flame characteristics of oxy-fuel combustion this research presents the experimental measurements of flame stability of various oxyfuel flames. Effects of H{sub 2} concentration, fuel composition, exhaust gas recirculation ratio, firing inputs, and burner diameters on the flame stability of these fuels are discussed. Effects of exhaust gas recirculation i.e. CO{sub 2} and H{sub 2}O (steam) acting as diluents on burner operability are also presented. The roles of firing input on flame stability are then analyzed. For this study it was observed that many oxy-flames did not stabilize without exhaust gas recirculation due to their higher burning velocities. In addition, the stability regime of all compositions was observed to decrease as the burner diameter increased. A flashback model is also presented, using the critical velocity gradient g{sub F}) values for CH{sub 4}-O{sub 2}-CO{sub 2} flames. The scaling relation (𝐠{sub F} = 𝐜 𝐒{sub 𝐋}{sup 2}/𝛂) for different burner diameters was obtained for various diameter burners. The report shows that results correlated linearly with a scaling value of c =0.0174. The second part of the study focuses on the experimental measurements of the flow field characteristics of premixed CH{sub 4}/21%O{sub 2}/79%N{sub 2} and CH{sub 4}/38%O{sub 2}/72%CO{sub 2} mixtures at constant firing input of 7.5 kW, constant, equivalence ratio of 0.8, constant swirl number of 0.92 and constant Reynolds Numbers. These measurements were taken in a swirl stabilized combustor at atmospheric pressure. The flow field visualization using Particle Imaging Velocimetry (PIV) technique is implemented to make a better understanding of the turbulence characteristics of CH{sub 4}/air and CH{sub 4}/38%O{sub 2}/72%CO{sub 2} combustion. The velocity fluctuations, turbulence intensities and local propagation velocities along the combustion chamber have been determined. The turbulent intensities increase as we move away from the combustor axis. CH{sub 4}-38%O{sub 2}-72%CO{sub 2} flames have low radial velocity and turbulent intensity distributions at different axial distances when compared with CH{sub 4}-Air flames.

  7. Small, Inexpensive Combined NOx Sensor and O2 Sensor

    SciTech Connect (OSTI)

    W. N. Lawless; C. F. Clark, Jr.

    2008-09-08

    It has been successfully demonstrated in this program that a zirconia multilayer structure with rhodium-based porous electrodes performs well as an amperometric NOx sensor. The sensitivity of the sensor bodies operating at 650 to 700 C is large, with demonstrated current outputs of 14 mA at 500 ppm NOx from sensors with 30 layers. The sensor bodies are small (4.5 x 4.2 x 3.1 mm), rugged, and inexpensive. It is projected the sensor bodies will cost $5 - $10 in production. This program has built on another successful development program for an oxygen sensor based on the same principles and sponsored by DOE. This oxygen sensor is not sensitive to NOx. A significant technical hurdle has been identified and solved. It was found that the 100% Rh electrodes oxidize rapidly at the preferred operating temperatures of 650 - 700 C, and this oxidation is accompanied by a volume change which delaminates the sensors. The problem was solved by using alloys of Rh and Pt. It was found that a 10%/90% Rh/Pt alloy dropped the oxidation rate of the electrodes by orders of magnitude without degrading the NOx sensitivity of the sensors, allowing long-term stable operation at the preferred operating temperatures. Degradation in the sensor output caused by temperature cycling was identified as a change in resistance at the junction between the sensor body and the external leads attached to the sensor body. The degradation was eliminated by providing strong mechanical anchors for the wire and processing the junctions to obtain good electrical bonds. The NOx sensors also detect oxygen and therefore the fully-packaged sensor needs to be enclosed with an oxygen sensor in a small, heated zirconia chamber exposed to test gas through a diffusion plug which limits the flow of gas from the outside. Oxygen is pumped from the interior of the chamber to lower the oxygen content and the combination of measurements from the NOx and oxygen sensors yields the NOx content of the gas. Two types of electronic control units were designed and built. One control unit provides independent constant voltages to the NOx and oxygen sensors and reads the current from them (that is, detects the amount of test gas present). The second controller holds the fully-assembled sensor at the desired operating temperature and controllably pumps excess oxygen from the test chamber. While the development of the sensor body was a complete success, the development of the packaging was only partially successful. All of the basic principles were demonstrated, but the packaging was too complex to optimize the operation within the resources of the program. Thus, no fully-assembled sensors were sent to outside labs for testing of cross-sensitivities, response times, etc. Near the end of the program, Sensata Technologies of Attleboro, MA tested the sensor bodies and confirmed the CeramPhysics measurements as indicated in the following attached letter. Sensata was in the process of designing their own packaging for the sensor and performing cross-sensitivity tests when they stopped all sensor development work due to the automotive industry downturn. Recently Ceramatec Inc. of Salt Lake City has expressed an interest in testing the sensor, and other licensing opportunities are being pursued.

  8. NOx CONTROL OPTIONS AND INTEGRATION FOR US COAL FIRED BOILERS

    SciTech Connect (OSTI)

    Mike Bockelie; Marc Cremer; Kevin Davis; Bob Hurt; Eric Eddings

    2001-01-31

    This is the second Quarterly Technical Report for DOE Cooperative Agreement No: DE-FC26-00NT40753. The goal of the project is to develop cost effective analysis tools and techniques for demonstrating and evaluating low NOx control strategies and their possible impact on boiler performance for firing US coals. The focus of our efforts during the last three months have been on: (1) Completion of a long term field test for Rich Reagent Injection (RRI) at the Conectiv BL England Station Unit No.1, a 130 MW Cyclone fired boiler; (2) Extending our Computational Fluid Dynamics (CFD) based NOx model to accommodate the chemistry for RRI in PC fired boilers; (3) Design improvements and calibration tests of the corrosion probe; and (4) Investigations on ammonia adsorption mechanisms and removal processes for Fly Ash.

  9. Novel Application of Air Separation Membranes Reduces Engine NOx Emissions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    - Energy Innovation Portal Vehicles and Fuels Vehicles and Fuels Find More Like This Return to Search Novel Application of Air Separation Membranes Reduces Engine NOx Emissions Alternative to Exhaust Gas Recirculation that involves the nitrogen enrichment of intake air. Argonne National Laboratory Contact ANL About This Technology <p> Schematic representation of the air separation process through a membrane module</p> Schematic representation of the air separation process through

  10. NOx Abatement Research and Development CRADA with Navistar Incorporated |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Abatement Research and Development CRADA with Navistar Incorporated NOx Abatement Research and Development CRADA with Navistar Incorporated 2009 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C. PDF icon ace_33_toops.pdf More Documents & Publications CLEERS Coordination & Joint Development of Benchmark Kinetics for LNT & SCR CLEERS Coordination & Joint Development of

  11. Enhanced High and Low Temperature Performance of NOx Reduction Materials

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Vehicle Technologies Office 1 Enhanced High and Low Temperature Performance of NOx Reduction Materials 2014 DOE AMR Review This presentation does not contain any proprietary, confidential, or otherwise restricted information. The work was funded by the U.S. Department of Energy (DOE) Office of FreedomCar and Vehicle Technologies. Program Managers: Ken Howden and Gurpreet Singh June 19, 2014 Feng Gao, George Muntean, Janos Szányi, Chuck Peden Institute for Integrated Catalysis Pacific Northwest

  12. Three-Dimensional Composite Nanostructures for Lean NOx Emission Control |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy 1 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation PDF icon ace030_gao_2011_o.pdf More Documents & Publications Monolithic Metal Oxide based Composite Nanowire Lean NOx Emission Control Catalysts Vehicle Technologies Office Merit Review 2015: Metal Oxide Nano-Array Catalysts for Low Temperature Diesel Oxidation Ultra-efficient, Robust and Well-defined Nano-Array based Monolithic Catalysts

  13. ULTRA LOW NOx CATALYTIC COMBUSTION FOR IGCC POWER PLANTS

    SciTech Connect (OSTI)

    Lance L. Smith

    2004-03-01

    Tests were performed in PCI's sub-scale high-pressure (10 atm) test rig, using PCI's two-stage (catalytic / gas-phase) combustion process for syngas fuel. In this process, the first stage is a Rich-Catalytic Lean-burn (RCL{trademark}) catalytic reactor, wherein a fuel-rich mixture contacts the catalyst and reacts while final and excess combustion air cool the catalyst. The second stage is a gas-phase combustor, wherein the catalyst cooling air mixes with the catalytic reactor effluent to provide for final gas-phase burnout and dilution to fuel-lean combustion products. During the reporting period, PCI successfully achieved NOx = 0.011 lbs/MMBtu at 10 atm pressure (corresponding to 2.0 ppm NOx corrected to 15% O{sub 2} dry) with near-zero CO emissions, surpassing the project goal of < 0.03 lbs/MMBtu NOx. These emissions levels were achieved at scaled (10 atm, sub-scale) baseload conditions corresponding to Tampa Electric's Polk Power Station operation on 100% syngas (no co-firing of natural gas).

  14. Congressionally Directed Project for Passive NOx Removal Catalysts Research

    SciTech Connect (OSTI)

    Schneider, William

    2014-08-29

    The Recipient proposes to produce new scientific and technical knowledge and tools to enable the discovery and deployment of highly effective materials for the selective catalytic reduction (SCR) of nitrogen oxides (NOx) from lean combustion exhaust. A second goal is to demonstrate a closely coupled experimental and computational approach to heterogeneous catalysis research. These goals will be met through the completion of four primary technical objectives: First, an in-depth kinetic analysis will be performed on two prominent classes of NOx SCR catalysts, Fe- and Cu-exchanged beta and ZSM-5 zeolites, over a wide range of catalyst formulation and under identical, high conversion conditions as a function of gas phase composition. Second, the nanoscale structure and adsorption chemistry of these high temperature (HT) and low temperature (LT) catalysts will be determined using in situ and operando spectroscopy under the same reaction conditions. Third, first-principles molecular simulations will be used to model the metal-zeolite active sites, their adsorption chemistry, and key steps in catalytic function. Fourth, this information will be integrated into chemically detailed mechanistic and kinetic descriptions and models of the operation of these well- defined NOx SCR catalysts under practically relevant reaction conditions. The new knowledge and models that derive from this work will be published in the scientific literature.

  15. Glass Ceramic Waste Forms for Combined CS+LN+TM Fission Products Waste Streams

    SciTech Connect (OSTI)

    Crum, Jarrod V.; Turo, Laura A.; Riley, Brian J.; Tang, Ming; Kossoy, Anna; Sickafus, Kurt E.

    2010-09-23

    In this study, glass ceramics were explored as an alternative waste form for glass, the current baseline, to be used for immobilizing alkaline/alkaline earth + lanthanide (CS+LN) or CS+LN+transition metal (TM) fission-product waste streams generated by a uranium extraction (UREX+) aqueous separations type process. Results from past work on a glass waste form for the combined CS+LN waste streams showed that as waste loading increased, large fractions of crystalline phases precipitated upon slow cooling.[1] The crystalline phases had no noticeable impact on the waste form performance by the 7-day product consistency test (PCT). These results point towards the development of a glass ceramic waste form for treating CS+LN or CS+LN+TM combined waste streams. Three main benefits for exploring glass ceramics are: (1) Glass ceramics offer increased solubility of troublesome components in crystalline phases as compared to glass, leading to increased waste loading; (2) The crystalline network formed in the glass ceramic results in higher heat tolerance than glass; and (3) These glass ceramics are designed to be processed by the same melter technology as the current baseline glass waste form. It will only require adding controlled canister cooling for crystallization into a glass ceramic waste form. Highly annealed waste form (essentially crack free) with up to 50X lower surface area than a typical High-Level Waste (HLW) glass canister. Lower surface area translates directly into increased durability. This was the first full year of exploring glass ceramics for the Option 1 and 2 combined waste stream options. This work has shown that dramatic increases in waste loading are achievable by designing a glass ceramic waste form as an alternative to glass. Table S1 shows the upper limits for heat, waste loading (based on solubility), and the decay time needed before treatment can occur for glass and glass ceramic waste forms. The improvements are significant for both combined waste stream options in terms of waste loading and/or decay time required before treatment. For Option 1, glass ceramics show an increase in waste loading of 15 mass % and reduction in decay time of 24 years. Decay times of {approx}50 years or longer are close to the expected age of the fuel that will be reprocessed when the modified open or closed fuel cycle is expected to be put into action. Option 2 shows a 2x to 2.5x increase in waste loading with decay times of only 45 years. Note that for Option 2 glass, the required decay time before treatment is only 35 years because of the waste loading limits related to the solubility of MoO{sub 3} in glass. If glass was evaluated for similar waste loadings as those achieved in Option 2 glass ceramics, the decay time would be significantly longer than 45 years. These glass ceramics are not optimized, but already they show the potential to dramatically reduce the amount of waste generated while still utilizing the proven processing technology used for glass production.

  16. Lean NOx Trap Catalysis for Lean Natural Gas Engine Applications

    SciTech Connect (OSTI)

    Parks, II, James E; Storey, John Morse; Theiss, Timothy J; Ponnusamy, Senthil; Ferguson, Harley Douglas; Williams, Aaron M; Tassitano, James B

    2007-09-01

    Distributed energy is an approach for meeting energy needs that has several advantages. Distributed energy improves energy security during natural disasters or terrorist actions, improves transmission grid reliability by reducing grid load, and enhances power quality through voltage support and reactive power. In addition, distributed energy can be efficient since transmission losses are minimized. One prime mover for distributed energy is the natural gas reciprocating engine generator set. Natural gas reciprocating engines are flexible and scalable solutions for many distributed energy needs. The engines can be run continuously or occasionally as peak demand requires, and their operation and maintenance is straightforward. Furthermore, system efficiencies can be maximized when natural gas reciprocating engines are combined with thermal energy recovery for cooling, heating, and power applications. Expansion of natural gas reciprocating engines for distributed energy is dependent on several factors, but two prominent factors are efficiency and emissions. Efficiencies must be high enough to enable low operating costs, and emissions must be low enough to permit significant operation hours, especially in non-attainment areas where emissions are stringently regulated. To address these issues the U.S. Department of Energy and the California Energy Commission launched research and development programs called Advanced Reciprocating Engine Systems (ARES) and Advanced Reciprocating Internal Combustion Engines (ARICE), respectively. Fuel efficiency and low emissions are two primary goals of these programs. The work presented here was funded by the ARES program and, thus, addresses the ARES 2010 goals of 50% thermal efficiency (fuel efficiency) and <0.1 g/bhp-hr emissions of oxides of nitrogen (NOx). A summary of the goals for the ARES program is given in Table 1-1. ARICE 2007 goals are 45% thermal efficiency and <0.015 g/bhp-hr NOx. Several approaches for improving the efficiency and emissions of natural gas reciprocating engines are being pursued. Approaches include: stoichiometric engine operation with exhaust gas recirculation and three-way catalysis, advanced combustion modes such as homogeneous charge compression ignition, and extension of the lean combustion limit with advanced ignition concepts and/or hydrogen mixing. The research presented here addresses the technical approach of combining efficient lean spark-ignited natural gas combustion with low emissions obtained from a lean NOx trap catalyst aftertreatment system. This approach can be applied to current lean engine technology or advanced lean engines that may result from related efforts in lean limit extension. Furthermore, the lean NOx trap technology has synergy with hydrogen-assisted lean limit extension since hydrogen is produced from natural gas during the lean NOx trap catalyst system process. The approach is also applicable to other lean engines such as diesel engines, natural gas turbines, and lean gasoline engines; other research activities have focused on those applications. Some commercialization of the technology has occurred for automotive applications (both diesel and lean gasoline engine vehicles) and natural gas turbines for stationary power. The research here specifically addresses barriers to commercialization of the technology for large lean natural gas reciprocating engines for stationary power. The report presented here is a comprehensive collection of research conducted by Oak Ridge National Laboratory (ORNL) on lean NOx trap catalysis for lean natural gas reciprocating engines. The research was performed in the Department of Energy's ARES program from 2003 to 2007 and covers several aspects of the technology. All studies were conducted at ORNL on a Cummins C8.3G+ natural gas engine chosen based on industry input to simulate large lean natural gas engines. Specific technical areas addressed by the research include: NOx reduction efficiency, partial oxidation and reforming chemistry, and the effects of sulfur poisons on the partial oxidation

  17. NOx Control Options and Integration for US Coal Fired Boilers

    SciTech Connect (OSTI)

    Mike Bockelie; Marc Cremer; Kevin Davis; Martin Denison; Adel Sarofim; Connie Senior; Hong-Shig Shim; Dave Swenson; Bob Hurt; Eric Suuberg; Eric Eddings; Kevin Whitty; Larry Baxter; Calvin Bartholomew; William Hecker

    2006-06-30

    This is the Final Report for DOE Cooperative Agreement No: DE-FC26-00NT40753. The goal of the project was to develop cost-effective analysis tools and techniques for demonstrating and evaluating low-NOx control strategies and their possible impact on boiler performance for boilers firing US coals. The Electric Power Research Institute (EPRI) provided co-funding for this program. This project included research on: (1) In furnace NOx control; (2) Impacts of combustion modifications on boiler operation; (3) Selective Catalytic Reduction (SCR) catalyst testing and (4) Ammonia adsorption/removal on fly ash. Important accomplishments were achieved in all aspects of the project. Rich Reagent Injection (RRI), an in-furnace NOx reduction strategy based on injecting urea or anhydrous ammonia into fuel rich regions in the lower furnace, was evaluated for cyclone-barrel and PC fired utility boilers. Field tests successfully demonstrated the ability of the RRI process to significantly reduce NOx emissions from a staged cyclone-fired furnace operating with overfire air. The field tests also verified the accuracy of the Computational Fluid Dynamic (CFD) modeling used to develop the RRI design and highlighted the importance of using CFD modeling to properly locate and configure the reagent injectors within the furnace. Low NOx firing conditions can adversely impact boiler operation due to increased waterwall wastage (corrosion) and increased soot production. A corrosion monitoring system that uses electrochemical noise (ECN) corrosion probes to monitor, on a real-time basis, high temperature corrosion events within the boiler was evaluated. Field tests were successfully conducted at two plants. The Ohio Coal Development Office provided financial assistance to perform the field tests. To investigate soot behavior, an advanced model to predict soot production and destruction was implemented into an existing reacting CFD modeling tool. Comparisons between experimental data collected in a pilot scale furnace and soot behavior predicted by the CFD model showed good agreement. Field and laboratory tests were performed for SCR catalysts used for coal and biomass co-firing applications. Fundamental laboratory studies were performed to better understand mechanisms involved with catalyst deactivation. Field tests with a slip stream reactor were used to create catalyst exposed to boiler flue gas for firing coal and for co-firing coal and biomass. The field data suggests the mechanisms leading to catalyst deactivation are, in order of importance, channel plugging, surface fouling, pore plugging and poisoning. Investigations were performed to better understand the mechanisms involved with catalyst regeneration through mechanical or chemical methods. A computer model was developed to predict NOx reduction across the catalyst in a SCR. Experiments were performed to investigate the fundamentals of ammonia/fly ash interactions with relevance to the operation of advanced NOx control technologies such as selective catalytic reduction. Measurements were performed for ammonia adsorption isotherms on commercial fly ash samples subjected to a variety of treatments and on the chemistry of dry and semi-dry ammonia removal processes. This work resulted in the first fundamental ammonia isotherms on carbon-containing fly ash samples. This work confirms industrial reports that aqueous solution chemistry takes place upon the introduction of even very small amounts of water, while the ash remains in a semi-dry state.

  18. Study of the effects of ambient conditions upon the performance of fan powered, infrared, natural gas burners. Quarterly technical progress report, July 1--September 30, 1995

    SciTech Connect (OSTI)

    Bai, T.; Yeboah, Y.D.; Sampath, R.

    1995-10-01

    The objective of this investigation is to characterize the operation of fan powered infrared burner (PIR) at various gas compositions and ambient conditions and develop design guidelines for appliances in containing PIR burners for satisfactory performance. During this period, experimental setup with optical and electronic instrumentation that is necessary for measuring the radiant heat output and the emission gas output of the burner has been established. The radiation measurement instrument, an FTIR, has been purchased and installed in the porous burner experimental system. The radiation measurement capability of the FTIR was tested and found to be satisfactory. A standard blackbody source, made by Graseby Infrared, was employed to calibrate the FTIR. A collection duct for emission gas measurement was fabricated and connected to the existing Horiba gas analyzer. Test runs are being conducted for flue gas analysis. A number of published research papers on modeling of porous burners were reviewed. The physical mechanism and theoretical analysis of the combustion process of the PIR burner was formulated. The numerical modeling, and implementation of a PIR burner code at CAU`s computing facility is in progress.

  19. Understanding NOx SCR Mechanism and Activity on Cu/Chabazite Structures throughout the Catalyst Life Cycle

    SciTech Connect (OSTI)

    Ribeiro, Fabio; Delgass, Nick; Gounder, Rajmani; Schneider, William F.; Miller, Jeff; Yezerets, Aleksey; McEwen, Jean-Sabin; Peden, Charles HF; Howden, Ken

    2014-12-09

    Oxides of nitrogen (NOx) compounds contribute to acid rain and photochemical smog and have been linked to respiratory ailments. NOx emissions regulations continue to tighten, driving the need for high performance, robust control strategies. The goal of this project is to develop a deep, molecular level understanding of the function of Cu-SSZ-13 and Cu-SAPO-34 materials that catalyze the SCR of NOx with NH3.

  20. H2-Assisted NOx Traps: Test Cell Results Vehicle Installations | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy -Assisted NOx Traps: Test Cell Results Vehicle Installations H2-Assisted NOx Traps: Test Cell Results Vehicle Installations 2003 DEER Conference Presentation: ArvinMeritor PDF icon 2003_deer_crane.pdf More Documents & Publications Hydrogen generation from plasmatron reformers and use for diesel exhaust aftertreatment On-Board Ammonia Generation Using Delphi Diesel Fuel Reformer Use of a Diesel Fuel Processor for Rapid and Efficient Regeneration of Single Leg NOx Adsorber

  1. Selective reduction of NOx in oxygen rich environments with plasma-assisted

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    catalysis: Catalyst development and mechanistic studies | Department of Energy reduction of NOx in oxygen rich environments with plasma-assisted catalysis: Catalyst development and mechanistic studies Selective reduction of NOx in oxygen rich environments with plasma-assisted catalysis: Catalyst development and mechanistic studies 2003 DEER Conference Presentation: Pacific Northwest National Laboratory PDF icon 2003_deer_peden.pdf More Documents & Publications Plasma-Activated Lean NOx

  2. Metal-supported De-NOx SCR Catalysts Prepared by Room Temperature Aerosol

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Deposition for Potential Marine Applications | Department of Energy supported De-NOx SCR Catalysts Prepared by Room Temperature Aerosol Deposition for Potential Marine Applications Metal-supported De-NOx SCR Catalysts Prepared by Room Temperature Aerosol Deposition for Potential Marine Applications Presents preparation of SCR catalyst coatings on cost effective metallic substrates using aerosol deposition technique and their catalytic De-NOx performance PDF icon p-06_choi.pdf More Documents

  3. Flexible CHP System with Low NOx, CO, and VOC Emissions - Presentation by

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    the Gas Technology Institute (GTI), June 2011 | Department of Energy Flexible CHP System with Low NOx, CO, and VOC Emissions - Presentation by the Gas Technology Institute (GTI), June 2011 Flexible CHP System with Low NOx, CO, and VOC Emissions - Presentation by the Gas Technology Institute (GTI), June 2011 Presentation on Flexible CHP System with Low NOx, CO, and VOC Emissions, given by David Cygan of the Gas Technology Institute, at the U.S. DOE Industrial Distributed Energy Portfolio

  4. Development of Chemical Kinetic Models for Lean NOx Traps | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy 0 DOE Vehicle Technologies and Hydrogen Programs Annual Merit Review and Peer Evaluation Meeting, June 7-11, 2010 -- Washington D.C. PDF icon ace035_larson_2010_o.pdf More Documents & Publications Development of Chemical Kinetic Models for Lean NOx Traps Benchmark Reaction Mechanisms and Kinetics for Lean NOx Traps Mechanisms of Sulfur Poisoning of NOx Adsorber (LNT) Materials

  5. Diesel Particulate Filter Technology for Low-Temperature and Low-NOx/PM

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Applications | Department of Energy Filter Technology for Low-Temperature and Low-NOx/PM Applications Diesel Particulate Filter Technology for Low-Temperature and Low-NOx/PM Applications 2004 DEER Conference Presentation: Johnson-Matthey Catalysts PDF icon 2004_deer_chatterjee.pdf More Documents & Publications Performance of Johnson Matthey EGRT’ Emission Control System for NOx and PM Emission Reduction in Retrofit Applications Part 1 Aftertreatment Modeling Status, Futur Potential, and

  6. Durability Evaluation of an Integrated Diesel NOx Adsorber A/T Subsystem at

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Light-Duty Operation | Department of Energy Evaluation of an Integrated Diesel NOx Adsorber A/T Subsystem at Light-Duty Operation Durability Evaluation of an Integrated Diesel NOx Adsorber A/T Subsystem at Light-Duty Operation 2004 Diesel Engine Emissions Reduction (DEER) Conference Presentation: Cummins Inc. and Johnson-Matthey PDF icon 2004_deer_li.pdf More Documents & Publications Development of NOx Adsorber System for Dodge Ram 2007 Heavy duty Pickup Truck Desulfurization Fuel Filter

  7. Flexible CHP System with Low NOx, CO and VOC Emissions | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Flexible CHP System with Low NOx, CO and VOC Emissions Flexible CHP System with Low NOx, CO and VOC Emissions Introduction A combined heat and power (CHP) system can be a financially attractive energy option for many industrial and commercial facilities. This is particularly the case in areas of the country with high electricity rates. However, regions with air quality concerns often have strict limits on criteria pollutants, such as nitrogen oxide (NOx), carbon monoxide (CO), and

  8. Mechanical swirler for a low-NO.sub.x, weak-swirl burner

    DOE Patents [OSTI]

    Cheng, Robert K. (Kensington, CA); Yegian, Derek T. (Berkeley, CA)

    1999-01-01

    Disclosed is a mechanical swirler for generating diverging flow in lean premixed fuel burners. The swirler of the present invention includes a central passage with an entrance for accepting a feed gas, a flow balancing insert that introduces additional pressure drop beyond that occurring in the central passage in the absence of the flow balancing insert, and an exit aligned to direct the feed gas into a combustor. The swirler also has an annular passage about the central passage and including one or more vanes oriented to impart angular momentum to feed gas exiting the annular passage. The diverging flow generated by the swirler stabilizes lean combustion thus allowing for lower production of pollutants, particularly oxides of nitrogen.

  9. Mechanical swirler for a low-NO{sub x}, weak-swirl burner

    DOE Patents [OSTI]

    Cheng, R.K.; Yegian, D.T.

    1999-03-09

    Disclosed is a mechanical swirler for generating diverging flow in lean premixed fuel burners. The swirler of the present invention includes a central passage with an entrance for accepting a feed gas, a flow balancing insert that introduces additional pressure drop beyond that occurring in the central passage in the absence of the flow balancing insert, and an exit aligned to direct the feed gas into a combustor. The swirler also has an annular passage about the central passage and including one or more vanes oriented to impart angular momentum to feed gas exiting the annular passage. The diverging flow generated by the swirler stabilizes lean combustion thus allowing for lower production of pollutants, particularly oxides of nitrogen. 16 figs.

  10. Assessment of Startup Fuel Options for the GNEP Advanced Burner Reactor (ABR)

    SciTech Connect (OSTI)

    Jon Carmack; Kemal O. Pasamehmetoglu; David Alberstein

    2008-02-01

    The Global Nuclear Energy Program (GNEP) includes a program element for the development and construction of an advanced sodium cooled fast reactor to demonstrate the burning (transmutation) of significant quantities of minor actinides obtained from a separations process and fabricated into a transuranic bearing fuel assembly. To demonstrate and qualify transuranic (TRU) fuel in a fast reactor, an Advanced Burner Reactor (ABR) prototype is needed. The ABR would necessarily be started up using conventional metal alloy or oxide (U or U, Pu) fuel. Startup fuel is needed for the ABR for the first 2 to 4 core loads of fuel in the ABR. Following start up, a series of advanced TRU bearing fuel assemblies will be irradiated in qualification lead test assemblies in the ABR. There are multiple options for this startup fuel. This report provides a description of the possible startup fuel options as well as possible fabrication alternatives available to the program in the current domestic and international facilities and infrastructure.

  11. Pollutant exposures from unvented gas cooking burners: A Simulation-based Assessment for Southern California

    SciTech Connect (OSTI)

    Logue, Jennifer M.; Klepeis, Neil E.; Lobscheid, Agnes B.; Singer, Brett C.

    2014-01-01

    Residential natural gas cooking burners (NGCBs) can emit substantial quantities of pollutants, and they are typically used without venting range hoods. In this study, LBNL researchers quantified pollutant concentrations and occupant exposures resulting from NGCB use in California homes.The simulation model estimated thatin homes using NGCBs without coincident use of venting range hoods -- 62%, 9%, and 53% of occupants are routinely exposed to NO2, CO, and HCHO levels that exceed acute health-based standards and guidelines. NGCB use increased the sample median of the highest simulated 1-hr indoor concentrations by 100, 3,000, and 20 ppb for NO2, CO, and HCHO, respectively. The study recommends that reducing pollutant exposures from NGCBs should be a public health priority. Simulation results suggest that regular use of even moderately effective venting range hoods would dramatically reduce the percentage of homes in which concentrations exceed health-based standards.

  12. The Effects of Hydrocarbons on NOx Reduction over Fe-based SCR...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and improve NOx reduction performance and reduce system cost PDF icon deer10lee.pdf More Documents & Publications Hydrocarbon Inhibition and HC Storage Modeling in...

  13. Safe and compact ammonia storage/delivery systems for SCR-DeNOX...

    Broader source: Energy.gov (indexed) [DOE]

    johannessen.pdf More Documents & Publications Ammonia storage and delivery systems for NOx aftertreatment 3rd Generation SCR System Using Solid Ammonia Storage and Direct Gas...

  14. Desulfurization Effects on a Light-Duty Diesel Vehicle NOx Adsorber Exhaust Emission Control System

    SciTech Connect (OSTI)

    Tatur, M.; Tomazic, D.; Tyrer, H.; Thornton, M.; Kubsh, J.

    2006-05-01

    Analyzes the effects on gaseous emissions, before and after desulfurization, on a light-duty diesel vehicle with a NOx adsorber catalyst.

  15. Reduce NOx and Improve Energy Efficiency, Software Tools for Industry, Industrial Technologies Program (ITP) (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2008-12-01

    This fact sheet describes how the Industrial Technologies Program NOx and Energy Assessment Tool (NxEAT) can help petroleum refining and chemical plants improve energy efficiency.

  16. APBF-DEC NOx Adsorber/DPF Project: SUV/Pick-Up Platform | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy NOx Adsorber/DPF Project: SUV/Pick-Up Platform APBF-DEC NOx Adsorber/DPF Project: SUV/Pick-Up Platform 2003 DEER Conference Presentation: Southwest Research Institute PDF icon 2003_deer_webb.pdf More Documents & Publications Status of APBF-DEC NOx Adsorber/DPF Projects Full Useful Life (120,000 miles) Exhaust Emission Performance of a NOx Adsorber and Diesel Particle Filter Equipped Passenger Car and Medium-Duty Engine in Conjunction with Ultralow-Sulfur Fuel APBF-DEC Light-duty

  17. Propane-Diesel Dual Fuel for CO2 and Nox Reduction | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Propane-Diesel Dual Fuel for CO2 and Nox Reduction Propane-Diesel Dual Fuel for CO2 and Nox Reduction Test results show significant CO2 and NOx emission reductions, fuel economy gains, and overall energy savings with propane injection in a diesel engine. PDF icon p-18_servati.pdf More Documents & Publications Active DPF for Off-Road Particulate Matter (PM) Control Power Generating Stationary Engines Nox Control: A Closed Loop Control Technology DPF for a Tractor Auxiliary Power Unit

  18. Impact of Lubricant Formulation on the Performance of NOx Adsorber Catalysts (Presentation)

    SciTech Connect (OSTI)

    Whitacre, S. D.

    2005-08-25

    Discusses the impact of lubricant formulation on the performance of oxides of nitrogen (NOx) Adsorber Catalysts, including background/motivation for study, experimental design, and results.

  19. Effect of Thermal Aging on NO oxidation and NOx storage in a...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Thermal aging of LNT has numerous material and chemical effects PDF icon deer09toops.pdf More Documents & Publications Impacts of Biodiesel on Emission Control Devices NOx ...

  20. Engine and Reactor Evaluations of HC-SCR for Diesel NOx Reduction |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Engine and Reactor Evaluations of HC-SCR for Diesel NOx Reduction Engine and Reactor Evaluations of HC-SCR for Diesel NOx Reduction Focus is the heavy duty, US dynamometer certification using the Duramax 6.6 liter diesel PDF icon deer09_blint.pdf More Documents & Publications Development of Optimal Catalyst Designs and Operating Strategies for Lean NOx Reduction in Coupled LNT-SCR Systems Development of Optimal Catalyst Designs and Operating Strategies for Lean NOx

  1. Lean NOx Trap Formulation Effect on Performance with In-Cylinder...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Formulation Effect on Performance with In-Cylinder Regeneration Strategies Lean NOx Trap Formulation Effect on Performance with In-Cylinder Regeneration Strategies Poster ...

  2. The Effects of Hydrocarbons on NOx Reduction over Fe-based SCR Catalyst |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Hydrocarbons on NOx Reduction over Fe-based SCR Catalyst The Effects of Hydrocarbons on NOx Reduction over Fe-based SCR Catalyst Study of effects of hydrocarbons on ammonia storage and NOx reduction over a commercial Fe-zeolite SCR catalyst to understand catalyst behaviors at low temperatures and improve NOx reduction performance and reduce system cost PDF icon deer10_lee.pdf More Documents & Publications Hydrocarbon Inhibition and HC Storage Modeling in Fe-Zeolite

  3. Thermal Deactivation Mechanisms of Fully-Formed Lean NOx Trap Catalysts

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Aged by Lean/Rich Cycling | Department of Energy Deactivation Mechanisms of Fully-Formed Lean NOx Trap Catalysts Aged by Lean/Rich Cycling Thermal Deactivation Mechanisms of Fully-Formed Lean NOx Trap Catalysts Aged by Lean/Rich Cycling Catalysts in fully formulated lean NOx traps are aged and evaluated in a bench-flow reactor using simulated diesel engine exhaust. PDF icon deer08_toops.pdf More Documents & Publications APBF-DEC Heavy Duty NOx Adsorber/DPF Project: Heavy Duty Linehaul

  4. A Blueprint for GNEP Advanced Burner Reactor Startup Fuel Fabrication Facility

    SciTech Connect (OSTI)

    S. Khericha

    2010-12-01

    The purpose of this article is to identify the requirements and issues associated with design of GNEP Advanced Burner Reactor Fuel Facility. The report was prepared in support of providing data for preparation of a NEPA Environmental Impact Statement in support the U. S. Department of Energy (DOE) Global Nuclear Energy Partnership (GNEP). One of the GNEP objectives was to reduce the inventory of long lived actinide from the light water reactor (LWR) spent fuel. The LWR spent fuel contains Plutonium (Pu) -239 and other transuranics (TRU) such as Americium-241. One of the options is to transmute or burn these actinides in fast neutron spectra as well as generate the electricity. A sodium-cooled Advanced Recycling Reactor (ARR) concept was proposed to achieve this goal. However, fuel with relatively high TRU content has not been used in the fast reactor. To demonstrate the utilization of TRU fuel in a fast reactor, an Advanced Burner Reactor (ABR) prototype of ARR was proposed, which would necessarily be started up using weapons grade (WG) Pu fuel. The WG Pu is distinguished by relatively highest proportions of Pu-239 and lesser amount of other actinides. The WG Pu was assumed to be used as the startup fuel along with TRU fuel in lead test assemblies. Because such fuel is not currently being produced in the US, a new facility (or new capability in an existing facility) was being considered for fabrication of WG Pu fuel for the ABR. It was estimated that the facility will provide the startup fuel for 10-15 years and would take 3 to 5 years to construct.

  5. Three-Dimensional Composite Nanostructures for Lean NOx Emission Control

    SciTech Connect (OSTI)

    Gao, Pu-Xian

    2013-07-31

    This final report to the Department of Energy (DOE) and National Energy Technology Laboratory (NETL) for DE-EE0000210 covers the period from October 1, 2009 to July 31, 2013. Under this project, DOE awarded UConn about $1,248,242 to conduct the research and development on a new class of 3D composite nanostructure based catalysts for lean NOx emission control. Much of the material presented here has already been submitted to DOE/NETL in quarterly technical reports. In this project, through a scalable solution process, we have successfully fabricated a new class of catalytic reactors, i.e., the composite nanostructure array (nano-array) based catalytic converters. These nanocatalysts, distinct from traditional powder washcoat based catalytic converters, directly integrate monolithic substrates together with nanostructures with well-defined size and shape during the scalable hydrothermal process. The new monolithic nanocatalysts are demonstrated to be able to save raw materials including Pt-group metals and support metal oxides by an order of magnitude, while perform well at various oxidation (e.g., CO oxidation and NO oxidation) and reduction reactions (H{sub 2} reduction of NOx) involved in the lean NOx emissions. The size, shape and arrangement of the composite nanostructures within the monolithic substrates are found to be the key in enabling the drastically reduced materials usage while maintaining the good catalytic reactivity in the enabled devices. The further understanding of the reaction kinetics associated with the unique mass transport and surface chemistry behind is needed for further optimizing the design and fabrication of good nanostructure array based catalytic converters. On the other hand, the high temperature stability, hydrothermal aging stability, as well as S-poisoning resistance have been investigated in this project on the nanocatalysts, which revealed promising results toward good chemical and mechanical robustness, as well as S-poisoning resistance. Further investigation is needed for unraveling the understanding, design and selection principles of this new class of nanostructure based monolithic catalysts.

  6. SOx/NOx sorbent and process of use

    DOE Patents [OSTI]

    Ziebarth, M.S.; Hager, M.J.; Beeckman, J.W.; Plecha, S.

    1993-01-19

    An alumina sorbent capable of adsorbing NOx and SOx from waste gases and being regenerated by heating above 600 C. is made by incorporating an alumina stabilizing agent into the sorbent. A preferred method is to add the stabilizer when the alumina is precipitated. The precipitated powder is formed subsequently into a slurry, milled and dripped to form the stabilizing spheroidal alumina particles. These particles are impregnated with an alkali metal or alkaline earth metal to form the stabilized sorbent. Alumina stabilizers include one or more of silica, lanthana, other rare earths, titania, zirconia and alkaline earths.

  7. SOx/NOx sorbent and process of use

    DOE Patents [OSTI]

    Ziebarth, Michael S. (Columbia, MD); Hager, Michael J. (Baltimore, MD); Beeckman, Jean W. (Columbia, MD); Plecha, Stanislaw (Baltimore, MD)

    1993-01-19

    An alumina sorbent capable of adsorbing NOx and SOx from waste gases and being regenerated by heating above 600.degree. C. is made by incorporating an alumina stabilizing agent into the sorbent. A preferred method is to add the stabilizer when the alumina is precipitated. The precipitated powder is formed subsequently into a slurry, milled and dripped to form the stabilizing spheroidal alumina particles. These particles are impregnated with an alkali metal or alkaline earth metal to form the stabilized sorbent. Alumina stabilizers include one or more of silica, lanthana, other rare earths, titania, zirconia and alkaline earths.

  8. Sox/Nox Sorbent And Process Of Use

    DOE Patents [OSTI]

    Ziebarth, Michael S. (Columbia, MD); Hager, Michael J. (Coraopolis, PA); Beeckman, Jean W. (Columbia, MD); Plecha, Stanislaw (Baltimore, MD)

    1996-12-17

    An alumina sorbent capable of adsorbing NOx and SOx from waste gases and being regenerated by heating above 650.degree. C. is made by incorporating an alumina stabilizing agent into the sorbent. A preferred method is to add the stabilizer when the alumina is precipitated. The precipitated powder is formed subsequently into a slurry, milled and spray dried to form the stabilized spheroidal alumina particles having a particle size of less than 500 microns. These particles are impregnated with an alkali metal or alkaline earth metal to form the stabilized sorbent. Alumina stabilizers include one or more of silica, lanthana, other rare earths, titania, zirconia and alkaline earths.

  9. Sox/Nox Sorbent And Process Of Use

    DOE Patents [OSTI]

    Ziebarth, Michael S. (Columbia, MD); Hager, Michael J. (Caraopolis, PA); Beeckman, Jean W. (Columbia, MD); Plecha, Stanislaw (Baltimore, MD)

    1995-06-27

    An alumina sorbent capable of adsorbing NOx and SOx from waste gases and being regenerated by heating above 650.degree. C. is made by incorporating an alumina stabilizing agent into the sorbent. A preferred method is to add the stabilizer when the alumina is precipitated. The precipitated powder is formed subsequently into a slurry, milled and spray dried to form the stabilized spheroidal alumina particles having a particle size of less than 500 microns. These particles are impregnated with an alkali metal or alkaline earth metal to form the stabilized sorbent. Alumina stabilizers include one or more of silica, lanthana, other rare earths, titania, zirconia and alkaline earths.

  10. SOX/NOX sorbent and process of use

    DOE Patents [OSTI]

    Ziebarth, M.S.; Hager, M.J.; Beeckman, J.W.; Plecha, S.

    1995-05-09

    An alumina sorbent capable of adsorbing NOx and SOx from waste gases and being regenerated by heating above 600 C is made by incorporating an alumina stabilizing agent into the sorbent. A preferred method is to add the stabilizer when the alumina is precipitated. The precipitated powder is formed subsequently into a slurry, milled and dripped to form the stabilized spheroidal alumina particles. These particles are impregnated with an alkali metal or alkaline earth metal to form the stabilized sorbent. Alumina stabilizers include one or more of silica, lanthana, other rare earths, titania, zirconia and alkaline earths. 3 figs.

  11. SOX/NOX sorbent and process of use

    DOE Patents [OSTI]

    Ziebarth, Michael S. (Columbia, MD); Hager, Michael J. (Baltimore, MD); Beeckman, Jean W. (Columbia, MD); Plecha, Stanislaw (Baltimore, MD)

    1995-01-01

    An alumina sorbent capable of adsorbing NOx and SOx from waste gases and being regenerated by heating above 600.degree. C. is made by incorporating an alumina stabilizing agent into the sorbent. A preferred method is to add the stabilizer when the alumina is precipitated. The precipitated powder is formed subsequently into a slurry, milled and dripped to form the stabilized spheroidal alumina particles. These particles are impregnated with an alkali metal or alkaline earth metal to form the stabilized sorbent. Alumina stabilizers include one or more of silica, lanthana, other rare earths, titania, zirconia and alkaline earths.

  12. Low NO{sub x}/SO{sub x} Burner retrofit for utility cyclone boilers. Quarterly technical progress report, July--September 1991

    SciTech Connect (OSTI)

    Not Available

    1991-12-31

    Work on process design and LNS Burner design was deferred during this period, pending a reassessment of the project by TransAlta prior to commencement of Budget Period II, and only limited Balance of Plant engineering work was done.

  13. An Improvement of Diesel PM and NOx Reduction System | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    PDF icon 2005_deer_watanabe.pdf More Documents & Publications Development on simultaneous reduction system of NOx and PM from a diesel engine An Improvement of Diesel PM and NOx Reduction System New Diesel Emissions Control Strategy for U.S. Tier 2

  14. Development of Chemical Kinetic Models for Lean NOx Traps | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy 1 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation PDF icon ace035_larson_2011_o.pdf More Documents & Publications Development of Chemical Kinetic Models for Lean NOx Traps Benchmark Reaction Mechanisms and Kinetics for Lean NOx Traps CLEERS Coordination & Development of Catalyst Process Kinetic Data

  15. Modeling of NOx Destruction Options for INEEL Sodium-Bearing Waste Vitrification

    SciTech Connect (OSTI)

    Wood, Richard Arthur

    2001-09-01

    Off-gas NOx concentrations in the range of 1-5 mol% are expected as a result of the proposed vitrification of sodium-bearing waste at the Idaho National Engineering and Environmental Laboratory. An existing kinetic model for staged combustion (originally developed for NOx abatement from the calcination process) was updated for application to vitrification offgas. In addition, two new kinetic models were developed to assess the feasibility of using selective non-catalytic reduction (SNCR) or high-temperature alone for NOx abatement. Each of the models was developed using the Chemkin code. Results indicate that SNCR is a viable option, reducing NOx levels to below 1000 ppmv. In addition, SNCR may be capable of simultaneously reducing CO emissions to below 100 ppmv. Results for using high-temperature alone were not as promising, indicating that a minimum NOx concentration of 3950 ppmv is achievable at 3344F.

  16. Simplified configuration for the combustor of an oil burner using a low pressure, high flow air-atomizing nozzle

    DOE Patents [OSTI]

    Butcher, Thomas A. (Port Jefferson, NY); Celebi, Yusuf (Middle Island, NY); Fisher, Leonard (Colrain, MA)

    2000-09-15

    The invention relates to clean burning of fuel oil with air. More specifically, to a fuel burning combustion head using a low-pressure, high air flow atomizing nozzle so that there will be a complete combustion of oil resulting in a minimum emission of pollutants. The improved fuel burner uses a low pressure air atomizing nozzle that does not result in the use of additional compressors or the introduction of pressurized gases downstream, nor does it require a complex design. Inventors:

  17. Metal/metal oxide doped oxide catalysts having high deNOx selectivity for lean NOx exhaust aftertreatment systems

    DOE Patents [OSTI]

    Park, Paul W.

    2004-03-16

    A lean NOx catalyst and method of preparing the same is disclosed. The lean NOx catalyst includes a ceramic substrate, an oxide support material, preferably .gamma.-alumina, deposited on the substrate and a metal promoter or dopant introduced into the oxide support material. The metal promoters or dopants are selected from the group consisting of indium, gallium, tin, silver, germanium, gold, nickel, cobalt, copper, iron, manganese, molybdenum, chromium, cerium, vanadium, oxides thereof, and combinations thereof. The .gamma.-alumina preferably has a pore volume of from about 0.5 to about 2.0 cc/g; a surface area of between about 80 to 350 m.sup.2 /g; an average pore size diameter of between about 3 to 30 nm; and an impurity level of less than or equal to 0.2 weight percent. In a preferred embodiment the .gamma.-alumina is prepared by a sol-gel method, with the metal doping of the .gamma.-alumina preferably accomplished using an incipient wetness impregnation technique.

  18. Selective NOx Recirculation for Stationary Lean-Burn Natural Gas Engines

    SciTech Connect (OSTI)

    Nigel N. Clark

    2006-12-31

    Nitric oxide (NO) and nitrogen dioxide (NO2) generated by internal combustion (IC) engines are implicated in adverse environmental and health effects. Even though lean-burn natural gas engines have traditionally emitted lower oxides of nitrogen (NOx) emissions compared to their diesel counterparts, natural gas engines are being further challenged to reduce NOx emissions to 0.1 g/bhp-hr. The Selective NOx Recirculation (SNR) approach for NOx reduction involves cooling the engine exhaust gas and then adsorbing the NOx from the exhaust stream, followed by the periodic desorption of NOx. By sending the desorbed NOx back into the intake and through the engine, a percentage of the NOx can be decomposed during the combustion process. SNR technology has the support of the Department of Energy (DOE), under the Advanced Reciprocating Engine Systems (ARES) program to reduce NOx emissions to under 0.1 g/bhp-hr from stationary natural gas engines by 2010. The NO decomposition phenomenon was studied using two Cummins L10G natural gas fueled spark-ignited (SI) engines in three experimental campaigns. It was observed that the air/fuel ratio ({lambda}), injected NO quantity, added exhaust gas recirculation (EGR) percentage, and engine operating points affected NOx decomposition rates within the engine. Chemical kinetic model predictions using the software package CHEMKIN were performed to relate the experimental data with established rate and equilibrium models. The model was used to predict NO decomposition during lean-burn, stoichiometric burn, and slightly rich-burn cases with added EGR. NOx decomposition rates were estimated from the model to be from 35 to 42% for the lean-burn cases and from 50 to 70% for the rich-burn cases. The modeling results provided an insight as to how to maximize NOx decomposition rates for the experimental engine. Results from this experiment along with chemical kinetic modeling solutions prompted the investigation of rich-burn operating conditions, with added EGR to prevent preignition. It was observed that the relative air/fuel ratio, injected NO quantity, added EGR fraction, and engine operating points affected the NO decomposition rates. While operating under these modified conditions, the highest NO decomposition rate of 92% was observed. In-cylinder pressure data gathered during the experiments showed minimum deviation from peak pressure as a result of NO injections into the engine. A NOx adsorption system, from Sorbent Technologies, Inc., was integrated with the Cummins engine, comprised a NOx adsorbent chamber, heat exchanger, demister, and a hot air blower. Data were gathered to show the possibility of NOx adsorption from the engine exhaust, and desorption of NOx from the sorbent material. In order to quantify the NOx adsorption/desorption characteristics of the sorbent material, a benchtop adsorption system was constructed. The temperature of this apparatus was controlled while data were gathered on the characteristics of the sorbent material for development of a system model. A simplified linear driving force model was developed to predict NOx adsorption into the sorbent material as cooled exhaust passed over fresh sorbent material. A mass heat transfer analysis was conducted to analyze the possibility of using hot exhaust gas for the desorption process. It was found in the adsorption studies, and through literature review, that NO adsorption was poor when the carrier gas was nitrogen, but that NO in the presence of oxygen was adsorbed at levels exceeding 1% by mass of the sorbent. From the three experimental campaigns, chemical kinetic modeling analysis, and the scaled benchtop NOx adsorption system, an overall SNR system model was developed. An economic analysis was completed, and showed that the system was impractical in cost for small engines, but that economies of scale favored the technology.

  19. Oxy-Combustion Burner and Integrated Pollutant Removal Research and Development Test Facility

    SciTech Connect (OSTI)

    Mark Schoenfield; Manny Menendez; Thomas Ochs; Rigel Woodside; Danylo Oryshchyn

    2012-09-30

    A high flame temperature oxy-combustion test facility consisting of a 5 MWe equivalent test boiler facility and 20 KWe equivalent IPR® was constructed at the Hammond, Indiana manufacturing site. The test facility was operated natural gas and coal fuels and parametric studies were performed to determine the optimal performance conditions and generated the necessary technical data required to demonstrate the technologies are viable for technical and economic scale-up. Flame temperatures between 4930-6120F were achieved with high flame temperature oxy-natural gas combustion depending on whether additional recirculated flue gases are added to balance the heat transfer. For high flame temperature oxy-coal combustion, flame temperatures in excess of 4500F were achieved and demonstrated to be consistent with computational fluid dynamic modeling of the burner system. The project demonstrated feasibility and effectiveness of the Jupiter Oxygen high flame temperature oxy-combustion process with Integrated Pollutant Removal process for CCS and CCUS. With these technologies total parasitic power requirements for both oxygen production and carbon capture currently are in the range of 20% of the gross power output. The Jupiter Oxygen high flame temperature oxy-combustion process has been demonstrated at a Technology Readiness Level of 6 and is ready for commencement of a demonstration project.

  20. Laminar burn rates of gun propellants measured in the high-pressure strand burner

    SciTech Connect (OSTI)

    Reaugh, J. E., LLNL

    1997-10-01

    The pressure dependence of the laminar burn rate of gun propellants plays a role in the design and behavior of high-performance guns. We have begun a program to investigate the effects of processing variables on the laminar burn rates, using our high-pressure strand burner to measure these rates at pressures exceeding 700 MPa. We have burned JA2 and M43 propellant samples, provided by Dr. Arpad Juhasz, ARL, from propellant lots previously used in round-robin tests. Our results at room temperature are in accord with other measurements. In addition, we present results measured for propellant that has been preheated to 50 C before burning. We used our thermochemical equilibrium code, CHEETAH, to help interpret the simultaneous pressure and temperature measurements taken during the testing, and show examples of its use. It has been modified to provide performance measures and equations of state for the products that are familiar to the gun-propellant community users of BLAKE.

  1. Low NOx nozzle tip for a pulverized solid fuel furnace

    DOE Patents [OSTI]

    Donais, Richard E; Hellewell, Todd D; Lewis, Robert D; Richards, Galen H; Towle, David P

    2014-04-22

    A nozzle tip [100] for a pulverized solid fuel pipe nozzle [200] of a pulverized solid fuel-fired furnace includes: a primary air shroud [120] having an inlet [102] and an outlet [104], wherein the inlet [102] receives a fuel flow [230]; and a flow splitter [180] disposed within the primary air shroud [120], wherein the flow splitter disperses particles in the fuel flow [230] to the outlet [104] to provide a fuel flow jet which reduces NOx in the pulverized solid fuel-fired furnace. In alternative embodiments, the flow splitter [180] may be wedge shaped and extend partially or entirely across the outlet [104]. In another alternative embodiment, flow splitter [180] may be moved forward toward the inlet [102] to create a recessed design.

  2. SELECTIVE NOx RECIRCULATION FOR STATIONARY LEAN-BURN NATURAL GAS ENGINES

    SciTech Connect (OSTI)

    Nigel Clark; Gregory Thompson; Richard Atkinson; Chamila Tissera; Matt Swartz; Emre Tatli; Ramprabhu Vellaisamy

    2005-01-01

    The research program conducted at the West Virginia University Engine and Emissions Research Laboratory (EERL) is working towards the verification and optimization of an approach to remove nitric oxides from the exhaust gas of lean burn natural gas engines. This project was sponsored by the US Department of Energy, National Energy Technology Laboratory (NETL) under contract number: DE-FC26-02NT41608. Selective NOx Recirculation (SNR) involves three main steps. First, NOx is adsorbed from the exhaust stream, followed by periodic desorption from the aftertreatment medium. Finally the desorbed NOx is passed back into the intake air stream and fed into the engine, where a percentage of the NOx is decomposed. This reporting period focuses on the NOx decomposition capability in the combustion process. Although researchers have demonstrated NOx reduction with SNR in other contexts, the proposed program is needed to further understand the process as it applies to lean burn natural gas engines. SNR is in support of the Department of Energy goal of enabling future use of environmentally acceptable reciprocating natural gas engines through NOx reduction under 0.1 g/bhp-hr. The study of decomposition of oxides of nitrogen (NOx) during combustion in the cylinder was conducted on a 1993 Cummins L10G 240 hp lean burn natural gas engine. The engine was operated at different air/fuel ratios, and at a speed of 800 rpm to mimic a larger bore engine. A full scale dilution tunnel and analyzers capable of measuring NOx, CO{sub 2}, CO, HC concentrations were used to characterize the exhaust gas. Commercially available nitric oxide (NO) was used to mimic the NOx stream from the desorption process through a mass flow controller and an injection nozzle. The same quantity of NOx was injected into the intake and exhaust line of the engine for 20 seconds at various steady state engine operating points. NOx decomposition rates were obtained by averaging the peak values at each set point minus the baseline and finding the ratio between the injected NO amounts. It was observed that the air/fuel ratio, injected NO quantity and engine operating points affected the NOx decomposition rates of the natural gas engine. A highest NOx decomposition rate of 27% was measured from this engine. A separate exploratory tests conducted with a gasoline engine with a low air/fuel ratio yielded results that suggested, that high NOx decomposition rates may be possible if a normally lean burn engine were operated at conditions closer to stoichiometric, with high exhaust gas recirculation (EGR) for a brief period of time during the NOx decomposition phase and with a wider range of air/fuel ratios. Chemical kinetic model predictions using CHEMKIN were performed to relate the experimental data with the established rate and equilibrium models. NOx decomposition rates from 35% to 42% were estimated using the CHEMKIN software. This provided insight on how to maximize NOx decomposition rates for a large bore engine. In the future, the modeling will be used to examine the effect of higher NO{sub 2}/NO ratios that are associated with lower speed and larger bore lean burn operation.

  3. Effects of Coaxial Air on Nitrogen-Diluted Hydrogen Jet Diffusion Flame Length and NOx Emission

    SciTech Connect (OSTI)

    Weiland, N.T.; Chen, R.-H.; Strakey, P.A.

    2007-10-01

    Turbulent nitrogen-diluted hydrogen jet diffusion flames with high velocity coaxial air flows are investigated for their NOx emission levels. This study is motivated by the DOE turbine programs goal of achieving 2 ppm dry low NOx from turbine combustors running on nitrogen-diluted high-hydrogen fuels. In this study, effects of coaxial air velocity and momentum are varied while maintaining low overall equivalence ratios to eliminate the effects of recirculation of combustion products on flame lengths, flame temperatures, and resulting NOx emission levels. The nature of flame length and NOx emission scaling relationships are found to vary, depending on whether the combined fuel and coaxial air jet is fuel-rich or fuel-lean. In the absence of differential diffusion effects, flame lengths agree well with predicted trends, and NOx emissions levels are shown to decrease with increasing coaxial air velocity, as expected. Normalizing the NOx emission index with a flame residence time reveals some interesting trends, and indicates that a global flame strain based on the difference between the fuel and coaxial air velocities, as is traditionally used, is not a viable parameter for scaling the normalized NOx emissions of coaxial air jet diffusion flames.

  4. Global NOx Measurements in Turbulent Nitrogen-Diluted Hydrogen Jet Flames

    SciTech Connect (OSTI)

    Weiland, N.T.; Strakey, P.A.

    2007-03-01

    Turbulent hydrogen diffusion flames diluted with nitrogen are currently being studied to assess their ability to achieve the DOE Turbine Programs aggressive emissions goal of 2 ppm NOx in a hydrogen-fueled IGCC gas turbine combustor. Since the unstrained adiabatic flame temperatures of these diluted flames are not low enough to eliminate thermal NOx formation the focus of the current work is to study how the effects of flame residence time and global flame strain can be used to help achieve the stated NOx emissions goal. Dry NOx measurements are presented as a function of jet diameter nitrogen dilution and jet velocity for a turbulent hydrogen/nitrogen jet issuing from a thin-lipped tube in an atmospheric pressure combustor. The NOx emission indices from these experiments are normalized by the flame residence time to ascertain the effects of global flame strain and fuel Lewis Number on the NOx emissions. In addition dilute hydrogen diffusion flame experiments were performed in a high-pressure combustor at 2 4 and 8 atm. The NOx emission data from these experiments are discussed as well as the results from a Computational Fluid Dynamics modeling effort currently underway to help explain the experimental data.

  5. NOx/O2 Sensors for High-Temperature Applications | Argonne National

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Laboratory NOx/O2 Sensors for High-Temperature Applications Technology available for licensing: Low-cost bifunctional high-temperature NOx/oxygen sensor that provides real-time sensing inside a combustion chamber without the requirement of a reference air supply. Placement in combustion chamber provide accurate oxygen-sensing, extremely low drift 2-10% energy saving from sensor optimization of air-flow ratio and fuel oil viscosity PDF icon high-temp_NOx-O2_sensor

  6. NOx reduction technology for natural-gas-industry prime movers. Special report, August 1990

    SciTech Connect (OSTI)

    Castaldini, C.

    1990-08-01

    The applicability, performance, and costs are summarized for state-of-the-art NOx emission controls for prime movers used by the natural gas industry to drive pipeline compressors. Nearly 7700 prime movers of 300 hp or greater are in operation at compressor stations. NOx control technologies for application to reciprocating engines are catalytic reduction, engine modification, exhaust gas recirculation, and pre-stratified charge. Technologies discussed for application to gas turbines are catalytic reduction, water or steam injection, and low-NOx combustors.

  7. Fuel-Borne Reductants for NOx Aftertreatment: Preliminary EtOH SCR Study |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Reductants for NOx Aftertreatment: Preliminary EtOH SCR Study Fuel-Borne Reductants for NOx Aftertreatment: Preliminary EtOH SCR Study 2003 DEER Conference Presentation: Oak Ridge National Laboratory PDF icon 2003_deer_thomas.pdf More Documents & Publications Ag-Al2O3 Catalyst HC-SCR: Performance with Light Alcohols and Other Reductants Fuel-Borne Catalyst Assisted DPF regeneration on a Renault truck MD9 Engine Outfitted with SCR NOx Adsorber Regeneration Phenomena

  8. Development of a Stand-Alone Urea-SCR System for NOx Reduction in Marine

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Diesel Engines | Department of Energy a Stand-Alone Urea-SCR System for NOx Reduction in Marine Diesel Engines Development of a Stand-Alone Urea-SCR System for NOx Reduction in Marine Diesel Engines Stand-alone urea SCR system was developed for marine diesel engines and showed a 50-percent reduction in NOx. PDF icon deer08_bedick.pdf More Documents & Publications Difficulty of Measuring Emissions from Heavy-Duty Engines Equipped with SCR and DPF Evaluation of 2010 Urea-SCR Technology for

  9. Boosted HCCI for High Power without Engine Knock, and with Ultra-Low NOX

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Emissions | Department of Energy Boosted HCCI for High Power without Engine Knock, and with Ultra-Low NOX Emissions Boosted HCCI for High Power without Engine Knock, and with Ultra-Low NOX Emissions Advanced engines using HCCI or HCCI-like combustion can provide both high efficiencies and very low emissions of NOX and PM PDF icon deer09_dec.pdf More Documents & Publications HCCI and Stratified-Charge CI Engine Combustion Research HCCI and Stratified-Charge CI Engine Combustion Research

  10. Safe and compact ammonia storage/delivery systems for SCR-DeNOX in

    Energy Savers [EERE]

    automotive units | Department of Energy Safe and compact ammonia storage/delivery systems for SCR-DeNOX in automotive units Safe and compact ammonia storage/delivery systems for SCR-DeNOX in automotive units Presentation given at DEER 2006, August 20-24, 2006, Detroit, Michigan. Sponsored by the U.S. DOE's EERE FreedomCar and Fuel Partnership and 21st Century Truck Programs. PDF icon 2006_deer_johannessen.pdf More Documents & Publications Ammonia storage and delivery systems for NOx

  11. Extraction Based on in situ Formation of Dithiocarbamate for Separation of Am(III) from Ln(III)

    SciTech Connect (OSTI)

    Miyashita, Sunao; Yanaga, Makoto; Okuno, Kenji; Suganuma, Hideo; Satoh, Isamu

    2007-07-01

    A new solvent extraction technique based on in situ extractant formation of dithiocarbamate derivatives was constructed for the purpose of separation of Am(III) from Ln(III). Ammonium salts of dithiocarbamate in this technique are formed during the extraction course by the reaction between secondary amines and carbon disulfide in organic phase. The effects of substituent of secondary amines against the behavior of in situ formation of dithiocarbamate and the distribution behaviors of Am(III) and Ln(III)(especially Eu(III)) into nitrobenzene phase using in situ formation of dithiocarbamate were investigated. It was revealed that amines containing substituent in {alpha} position of amine were not suited that for in situ extractant formation method. The values of separation factor of Am(III)/Eu(III) >10{sup 4} were obtained by the new method using five di-substituted amines/CS{sub 2}/nitrobenzene system. (authors)

  12. PRELIMINARY DATA CALL REPORT ADVANCED BURNER REACTOR START UP FUEL FABRICATION FACILITY

    SciTech Connect (OSTI)

    S. T. Khericha

    2007-04-01

    The purpose of this report is to provide data for preparation of a NEPA Environmental Impact Statement in support the U. S. Department of Energy (DOE) Global Nuclear Energy Partnership (GNEP). One of the GNEP objectives is to reduce the inventory of long lived actinide from the light water reactor (LWR) spent fuel. The LWR spent fuel contains Plutonium (Pu) -239 and other transuranics (TRU) such as Americium-241. One of the options is to transmute or burn these actinides in fast neutron spectra as well as generate the electricity. A sodium-cooled Advanced Recycling Reactor (ARR) concept has been proposed to achieve this goal. However, fuel with relatively high TRU content has not been used in the fast reactor. To demonstrate the utilization of TRU fuel in a fast reactor, an Advanced Burner Reactor (ABR) prototype of ARR is proposed, which would necessarily be started up using weapons grade (WG) Pu fuel. The WG Pu is distinguished by relatively highest proportions of Pu-239 and lesser amount of other actinides. The WG Pu will be used as the startup fuel along with TRU fuel in lead test assemblies. Because such fuel is not currently being produced in the US, a new facility (or new capability in an existing facility) is being considered for fabrication of WG Pu fuel for the ABR. This report is provided in response to Data Call for the construction of startup fuel fabrication facility. It is anticipated that the facility will provide the startup fuel for 10-15 years and will take to 3 to 5 years to construct.

  13. Advanced Fuel Cycle Economic Analysis of Symbiotic Light-Water Reactor and Fast Burner Reactor Systems

    SciTech Connect (OSTI)

    D. E. Shropshire

    2009-01-01

    The Advanced Fuel Cycle Economic Analysis of Symbiotic Light-Water Reactor and Fast Burner Reactor Systems, prepared to support the U.S. Advanced Fuel Cycle Initiative (AFCI) systems analysis, provides a technology-oriented baseline system cost comparison between the open fuel cycle and closed fuel cycle systems. The intent is to understand their overall cost trends, cost sensitivities, and trade-offs. This analysis also improves the AFCI Program’s understanding of the cost drivers that will determine nuclear power’s cost competitiveness vis-a-vis other baseload generation systems. The common reactor-related costs consist of capital, operating, and decontamination and decommissioning costs. Fuel cycle costs include front-end (pre-irradiation) and back-end (post-iradiation) costs, as well as costs specifically associated with fuel recycling. This analysis reveals that there are large cost uncertainties associated with all the fuel cycle strategies, and that overall systems (reactor plus fuel cycle) using a closed fuel cycle are about 10% more expensive in terms of electricity generation cost than open cycle systems. The study concludes that further U.S. and joint international-based design studies are needed to reduce the cost uncertainties with respect to fast reactor, fuel separation and fabrication, and waste disposition. The results of this work can help provide insight to the cost-related factors and conditions needed to keep nuclear energy (including closed fuel cycles) economically competitive in the U.S. and worldwide. These results may be updated over time based on new cost information, revised assumptions, and feedback received from additional reviews.

  14. Cost analysis for compliance with EPA's regional NOx emissions reductions for fossil-fired power generation

    SciTech Connect (OSTI)

    Smith, D.; Mann, A.; Ward, J.; Ramezan, M.

    1999-07-01

    To achieve a more stringent ambient-air ozone standard promulgated in 1997, the U.S. EPA has established summer NOx emissions limits for fossil-fired electric power generating units in the Ozone Transport Rulemaking region, consisting of 22 eastern and midwestern states and the District of Columbia. These jurisdictions are required to submit State Implementation Plans by September 1999 in response to EPA's rule, with compliance required by 2007. There are 1757 affected units in this region. In the present study, projected state-by-state growth rates for power production are used to estimate power production and NOx emissions by unit in the year 2007. NOx emissions reductions expected by January 1, 2000 due to Title IV compliance are estimated, leaving a substantial balance of emissions reductions to be achieved by post-combustion NOx control. Cost estimates are developed for achieving these remaining reductions.

  15. Metal-supported De-NOx SCR Catalysts Prepared by Room Temperature...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Presents preparation of SCR catalyst coatings on cost effective metallic substrates using aerosol deposition technique and their catalytic De-NOx performance PDF icon p-06choi.pdf ...

  16. Demonstration of a Low-NOx Heavy-Duty Natural Gas Engine

    SciTech Connect (OSTI)

    Not Available

    2004-02-01

    Results of a Next Generation Natural Gas Vehicle engine research project: A Caterpillar C-12 natural gas engine with Clean Air Power Dual-Fuel technology and exhaust gas recirculation demonstrated low NOx and PM emissions.

  17. NH3 generation over commercial Three-Way Catalysts and Lean-NOx Traps

    Broader source: Energy.gov [DOE]

    Research to identify most promising catalytic formulations and operation for the in-situ generation of NH3, storage on a downstream SCR catalyst, and utilized to reduce the remaining NOx

  18. A Fast Start-up On-Board Fuel Reformer for NOx Adsorber Regeneration and

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Desulfation | Department of Energy A Fast Start-up On-Board Fuel Reformer for NOx Adsorber Regeneration and Desulfation A Fast Start-up On-Board Fuel Reformer for NOx Adsorber Regeneration and Desulfation 2004 Diesel Engine Emissions Reduction (DEER) Conference: ArvinMeritor PDF icon 2004_deer_crane.pdf More Documents & Publications Plasmatron Fuel Reformer Development and Internal Combustion Engine Vehicle Applications Use of a Diesel Fuel Processor for Rapid and Efficient Regeneration

  19. Performance of Johnson Matthey EGRT’ Emission Control System for NOx and

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    PM Emission Reduction in Retrofit Applications Part 1 | Department of Energy 1 Performance of Johnson Matthey EGRT’ Emission Control System for NOx and PM Emission Reduction in Retrofit Applications Part 1 2002 DEER Conference Presentation: Johnson Matthey PDF icon 2002_deer_chatterjee1.pdf More Documents & Publications Performance of Johnson Matthey EGRT’ Emission Control System for NOx and PM Emission Reduction in Retrofit Applications Part 2 SCRT Technology for Retrofit of

  20. Performance of Johnson Matthey EGRT’ Emission Control System for NOx and

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    PM Emission Reduction in Retrofit Applications Part 2 | Department of Energy 2 Performance of Johnson Matthey EGRT’ Emission Control System for NOx and PM Emission Reduction in Retrofit Applications Part 2 2002 DEER Conference Presentation: Johnson Matthey PDF icon 2002_deer_chatterjee2.pdf More Documents & Publications Performance of Johnson Matthey EGRT’ Emission Control System for NOx and PM Emission Reduction in Retrofit Applications Part 1 Development and Field Demonstrations of

  1. Lean NOx Traps - Microstructural Studies of Real World and Model Catalysts

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    | Department of Energy Traps - Microstructural Studies of Real World and Model Catalysts Lean NOx Traps - Microstructural Studies of Real World and Model Catalysts 2005 Diesel Engine Emissions Reduction (DEER) Conference Presentations and Posters PDF icon 2005_deer_narula.pdf More Documents & Publications Low Temperature Emission Control Pre-Competitive Catalysis Research: Fundamental Sulfation/Desulfation Studies of Lean NOx Traps Investigation of Aging Mechanisms in Lean

  2. An Experimental Investigation of the Origin of Increased NOx Emissions When

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fueling a Heavy-Duty Compression-Ignition Engine with Soy Biodiesel | Department of Energy the Origin of Increased NOx Emissions When Fueling a Heavy-Duty Compression-Ignition Engine with Soy Biodiesel An Experimental Investigation of the Origin of Increased NOx Emissions When Fueling a Heavy-Duty Compression-Ignition Engine with Soy Biodiesel Optical engine experiments suggest that near stoichiometric charge-gas mixtures in the standing premixed autoignition zone near flame lift-off length

  3. An Improvement of Diesel PM and NOx Reduction System | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Presentation given at the 2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER 2007). 13-16 August, 2007, Detroit, Michigan. Sponsored by the U.S. Department of Energy's (DOE) Office of FreedomCAR and Vehicle Technologies (OFCVT). PDF icon deer07_shoji.pdf More Documents & Publications An Improvement of Diesel PM and NOx Reduction System Development on simultaneous reduction system of NOx and PM from a diesel engine Simplification of Diesel Emission Control System

  4. NOx Measurement Errors in Ammonia-Containing Exhaust | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Measurement Errors in Ammonia-Containing Exhaust NOx Measurement Errors in Ammonia-Containing Exhaust Presentation given at DEER 2006, August 20-24, 2006, Detroit, Michigan. Sponsored by the U.S. DOE's EERE FreedomCar and Fuel Partnership and 21st Century Truck Programs. PDF icon 2006_deer_hoard.pdf More Documents & Publications Reductant Utilization in a LNT + SCR System Laboratory Product Speciation Studies of the LNT + in situ SCR NOx Emission Control Concept Function Specific Analysis of

  5. Selectlive Catalytic Reducution of NOx wilth Diesel-Based Fuels as

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Reductants | Department of Energy Selectlive Catalytic Reducution of NOx wilth Diesel-Based Fuels as Reductants Selectlive Catalytic Reducution of NOx wilth Diesel-Based Fuels as Reductants 2005 Diesel Engine Emissions Reduction (DEER) Conference Presentations and Posters PDF icon 2005_deer_marshall.pdf More Documents & Publications Bifunctional Catalysts for the Selective Catalytic Reduction of NO by Hydrocarbons Bifunctional Catalysts for the Selective Catalytic Reduction of NO by

  6. Simultaneously Low-Engine-Out NOx and PM with Highly Diluted Diesel

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Combustuion | Department of Energy Simultaneously Low-Engine-Out NOx and PM with Highly Diluted Diesel Combustuion Simultaneously Low-Engine-Out NOx and PM with Highly Diluted Diesel Combustuion 2002 DEER Conference Presentation: Oak Ridge National Laboratory PDF icon 2002_deer_wagner.pdf More Documents & Publications Exploring Advanced Combustion Regimes for Efficiency and Emissions Achieving High-Effiency Clean Ccombustion in Diesel Engines Light-Duty Diesel EngineTechnology to Meet

  7. Real-World Studies of Ambient Ozone Formation as a Function of NOx

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Reductions … Summary and Implications for Air Quality Impacts | Department of Energy Studies of Ambient Ozone Formation as a Function of NOx Reductions … Summary and Implications for Air Quality Impacts Real-World Studies of Ambient Ozone Formation as a Function of NOx Reductions … Summary and Implications for Air Quality Impacts 2009 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C. PDF icon

  8. Characterizing the In-Use Emissions Performance of Novel PM and NOx Control

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Technologies on Diesel Construction Equipment | Department of Energy the In-Use Emissions Performance of Novel PM and NOx Control Technologies on Diesel Construction Equipment Characterizing the In-Use Emissions Performance of Novel PM and NOx Control Technologies on Diesel Construction Equipment Poster presentation at the 2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER 2007). 13-16 August, 2007, Detroit, Michigan. Sponsored by the U.S. Department of Energy's (DOE)

  9. Compact Electrochemical Bi-functional NOx/O2 Sensors with an Internal

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Reference for High Temperature Applications | Department of Energy Compact Electrochemical Bi-functional NOx/O2 Sensors with an Internal Reference for High Temperature Applications Compact Electrochemical Bi-functional NOx/O2 Sensors with an Internal Reference for High Temperature Applications A inexpensive compact O2 sensor has been developed using internal reference gas that is stable for months, has no complex electronics, and is amenable to mass production PDF icon deer09_singh.pdf More

  10. Cummins/ORNL-FEERC CRADA: NOx Control & Measurement Technology for

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Heavy-Duty Diesel Engines | Department of Energy 1 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation PDF icon ace032_partridge_2011_o.pdf More Documents & Publications Cummins/ORNL-FEERC CRADA: NOx Control & Measurement Technology for Heavy-Duty Diesel Engines Vehicle Technologies Office Merit Review 2014: Cummins-ORNL/FEERC Emissions CRADA: NOx Control & Measurement Technology for Heavy-Duty Diesel Engines Vehicle

  11. Cummins/ORNL-FEERC CRADA: NOx Control & Measurement Technology for

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Heavy-Duty Diesel Engines | Department of Energy 10 DOE Vehicle Technologies and Hydrogen Programs Annual Merit Review and Peer Evaluation Meeting, June 7-11, 2010 -- Washington D.C. PDF icon ace032_partridge_2010_o.pdf More Documents & Publications Cummins/ORNL-FEERC CRADA: NOx Control & Measurement Technology for Heavy-Duty Diesel Engines Cummins/ORNL-FEERC CRADA: NOx Control & Measurement Technology for Heavy-Duty Diesel Engines

  12. Cummins/ORNL-FEERC CRADA: NOx Control & Measurement Technology for

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Heavy-Duty Diesel Engines | Department of Energy 12 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting PDF icon ace032_partridge_2012_o.pdf More Documents & Publications Cummins/ORNL-FEERC CRADA: NOx Control & Measurement Technology for Heavy-Duty Diesel Engines Vehicle Technologies Office Merit Review 2015: Cummins-ORNL\FEERC Emissions CRADA: NOx Control & Measurement Technology for Heavy-Duty Diesel Engines,

  13. Cutting NOx from Diesel Engines with Membrane-Generated Nitrogen-Enriched

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Air | Department of Energy Cutting NOx from Diesel Engines with Membrane-Generated Nitrogen-Enriched Air Cutting NOx from Diesel Engines with Membrane-Generated Nitrogen-Enriched Air 2005 Diesel Engine Emissions Reduction (DEER) Conference Presentations and Posters PDF icon 2005_deer_bowser.pdf More Documents & Publications Membrane Technology Workshop Advanced Reciprocating Engine Systems (ARES) R&D - Presentation by Argonne National Laboratory, June 2011 Diesel Engine Alternatives

  14. Development of NOx Adsorber System for Dodge Ram 2007 Heavy duty Pickup

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Truck | Department of Energy NOx Adsorber System for Dodge Ram 2007 Heavy duty Pickup Truck Development of NOx Adsorber System for Dodge Ram 2007 Heavy duty Pickup Truck Presentation given at the 2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER 2007). 13-16 August, 2007, Detroit, Michigan. Sponsored by the U.S. Department of Energy's (DOE) Office of FreedomCAR and Vehicle Technologies (OFCVT). PDF icon deer07_yezerets.pdf More Documents & Publications Durability

  15. Development of Remove Sensing Instrumentation for NOx and PM Emissions from

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Heavy Duty Trucks | Department of Energy Development of Remove Sensing Instrumentation for NOx and PM Emissions from Heavy Duty Trucks Development of Remove Sensing Instrumentation for NOx and PM Emissions from Heavy Duty Trucks 2002 DEER Conference Presentation: Oak Ridge National Laboratory PDF icon 2002_deer_mcgill.pdf More Documents & Publications Measurement of Real-World Emissions from Heavy-Duty Diesel Vehicles: The State-of-the-Art 21st Century Truck Partnership Roadmap Roadmap

  16. Unique Catalyst System for NOx Reduction in Diesel Exhaust | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Catalyst System for NOx Reduction in Diesel Exhaust Unique Catalyst System for NOx Reduction in Diesel Exhaust Poster presentation at the 2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER 2007). 13-16 August, 2007, Detroit, Michigan. Sponsored by the U.S. Department of Energy's (DOE) Office of FreedomCAR and Vehicle Technologies (OFCVT). PDF icon deer07_slone.pdf More Documents & Publications Clean Diesel Engine Component Improvement Program Noxtechs PAC

  17. The Impact of Lubricant Formulation on the Performance of NOx Adsorber

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Catalysts | Department of Energy Formulation on the Performance of NOx Adsorber Catalysts The Impact of Lubricant Formulation on the Performance of NOx Adsorber Catalysts PDF icon 2005_deer_whitacre.pdf More Documents & Publications The Impact of Lubricant on Emissions from a Medium-Duty Diesel Engine Diesel Aftertreatment Systems development Reducing Lubricant Ash Impact on Exhaust Aftertreatment with a Oil Conditioning Filter

  18. Spatiotemporal Distribution of NOx Storage: a Factor Controlling NH3 and

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    N2O Selectivities over a Commercial LNT Catalyst | Department of Energy Spatiotemporal Distribution of NOx Storage: a Factor Controlling NH3 and N2O Selectivities over a Commercial LNT Catalyst Spatiotemporal Distribution of NOx Storage: a Factor Controlling NH3 and N2O Selectivities over a Commercial LNT Catalyst Evaluation of commercial Ba-based LNT (CLEERS benchmark catalyst; containing oxygen storage capacity) in a bench flow reactor under fast-cycling conditions, varying reductant type,

  19. Low-NOx Gas Turbine Injectors Utilizing Hydrogen-Rich Opportunity Fuels -

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fact Sheet, 2015 | Department of Energy Low-NOx Gas Turbine Injectors Utilizing Hydrogen-Rich Opportunity Fuels - Fact Sheet, 2015 Low-NOx Gas Turbine Injectors Utilizing Hydrogen-Rich Opportunity Fuels - Fact Sheet, 2015 Solar Turbines Incorporated, in collaboration with The Pennsylvania State University and the University of Southern California, modified a gas turbine combustion system to operate on hydrogen-rich opportunity fuels. Increasing the usability of opportunity fuels will avoid

  20. Check Burner Air to Fuel Ratios; Industrial Technologies Program (ITP) Process Heating Tip Sheet #2 (Fact Sheet)

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    checking and resetting of air-fuel ratios for burners is one of the simplest ways to get maximum efficiency out of fuel-fired process heating equipment such as furnaces, ovens, heaters, and boilers. Most high temperature direct-fired furnaces, radiant tubes, and boilers operate with about 10% to 20% excess combustion air at high fire to prevent the formation of dangerous carbon monoxide and soot deposits on heat transfer surfaces and inside radiant tubes. For the fuels most commonly used by U.S.

  1. bectcom-new | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Low-NOxSOx Burner Retrofit for Utility Cyclone Boilers - Project Brief not available (Withdrawn) TransAlta Technologies, Inc., Los Angeles, CA Design Reports Low NOxSOx Burner...

  2. NOx Control Options and Integration for US Coal Fired Boilers

    SciTech Connect (OSTI)

    Mike Bockelie; Kevin Davis; Connie Senior; Darren Shino; Dave Swenson; Larry Baxter; Calvin Bartholomew; William Hecker; Stan Harding

    2004-12-31

    This is the eighteenth Quarterly Technical Report for DOE Cooperative Agreement No: DEFC26-00NT40753. The goal of the project is to develop cost effective analysis tools and techniques for demonstrating and evaluating low NOx control strategies and their possible impact on boiler performance for boilers firing US coals. The Electric Power Research Institute (EPRI) is providing co-funding for this program. Safety equipment for ammonia for the SCR slipstream reactor at Plant Gadsden was installed. The slipstream reactor was started and operated for about 1400 hours during the last performance period. Laboratory analysis of exposed catalyst and investigations of the sulfation of fresh catalyst continued at BYU. Thicker end-caps for the ECN probes were designed and fabricated to prevent the warpage and failure that occurred at Gavin with the previous design. A refurbished ECN probe was successfully tested at the University of Utah combustion laboratory. Improvements were implemented to the software that controls the flow of cooling air to the ECN probes.

  3. NOx Control Options and Integration for US Coal Fired Boilers

    SciTech Connect (OSTI)

    Mike Bockelie; Kevin Davis; Connie Senior Darren Shino; Dave Swenson; Larry Baxter; Calvin Bartholomew; William Hecker; Stan Harding

    2004-09-30

    This is the seventeenth Quarterly Technical Report for DOE Cooperative Agreement No: DEFC26-00NT40753. The goal of the project is to develop cost effective analysis tools and techniques for demonstrating and evaluating low NOx control strategies and their possible impact on boiler performance for boilers firing US coals. The Electric Power Research Institute (EPRI) is providing co-funding for this program. The SCR slipstream reactor was assembled and installed at Plant Gadsden this quarter. Safety equipment for ammonia had not been installed at the end of the quarter, but will be installed at the beginning of next quarter. The reactor will be started up next quarter. Four ECN corrosion probes were reinstalled at Gavin and collected corrosion data for approximately one month. Two additional probes were installed and removed after about 30 hours for future profilometry analysis. Preliminary analysis of the ECN probes, the KEMA coupons and the CFD modeling results all agree with the ultrasonic tube test measurements gathered by AEP personnel.

  4. Method of preparing doped oxide catalysts for lean NOx exhaust

    DOE Patents [OSTI]

    Park, Paul W.

    2004-03-09

    The lean NOx catalyst includes a substrate, an oxide support material, preferably .gamma.-alumina deposited on the substrate and a metal or metal oxide promoter or dopant introduced into the oxide support material. The metal promoters or dopants are selected from the group consisting of indium, gallium, tin, silver, germanium, gold, nickel, cobalt, copper, iron, manganese, molybdenum, chromium cerium, and vanadium, and oxides thereof, and any combinations thereof. The .gamma.-alumina preferably has a pore volume of from about 0.5 to about 2.0 cc/g; a surface area of between 80 and 350 m.sup.2 /g; an average pore size diameter of between about 3 to 30 nm; and an impurity level of less than or equal to about 0.2 weight percent. In a preferred embodiment the .gamma.-alumina is prepared by a sol-gel method, with the metal doping of the .gamma.-alumina preferably accomplished using an incipient wetness impregnation technique.

  5. Release of Ammonium and Mercury from NOx Controlled Fly Ash

    SciTech Connect (OSTI)

    Schroeder, K.T.; Cardone, C.R.; Kim, A.G

    2007-07-01

    One of the goals of the Department of Energy is to increase the reuse of coal utilization byproducts (CUB) to 50% by 2010. This will require both developing new markets and maintaining traditional ones such as the use of fly ash in concrete. However, the addition of pollution control devices can introduce side-effects that affect the marketability of the CUB. Such can be the case when NOx control is achieved using selective catalytic or non-catalytic reduction (SCR or SNCR). Depending on site-specific details, the ammonia slip can cause elevated levels of NH3 in the fly ash. Disposal of ammoniated fly ash can present environmental concerns related to the amount of ammonia that might be released, the amount of water that might become contaminated, and the extent to which metals might be mobilized by the presence of the ammonia. Ammonia retained in fly ash appears to be present as either an ammonium salt or as a chemisorbed species. Mercury in the leachates correlated to neither the amount of leachable ammonium nor to the total amount of Hg in the ash. The strongest correlation was between the decreases in the amount of Hg leached with increased LOI.

  6. Crystal structure of fluorite-related Ln{sub 3}SbO{sub 7} (Ln=LaDy) ceramics studied by synchrotron X-ray diffraction and Raman scattering

    SciTech Connect (OSTI)

    Siqueira, K.P.F.; Borges, R.M.; Granado, E.; Malard, L.M.; Paula, A.M. de; Moreira, R.L.; Bittar, E.M.; Dias, A.

    2013-07-15

    Ln{sub 3}SbO{sub 7} (Ln=La, Pr, Nd, Sm, Eu, Gd, Tb and Dy) ceramics were synthesized by solid-state reaction in optimized conditions of temperature and time to yield single-phase ceramics. The crystal structures of the obtained ceramics were investigated by synchrotron X-ray diffraction, second harmonic generation (SHG) and Raman scattering. All samples exhibited fluorite-type orthorhombic structures with different oxygen arrangements as a function of the ionic radius of the lanthanide metal. For ceramics with the largest ionic radii (LaNd), the ceramics crystallized into the Cmcm space group, while the ceramics with intermediate and smallest ionic radii (SmDy) exhibited a different crystal structure belonging to the same space group, described under the Ccmm setting. The results from SHG and Raman scattering confirmed these settings and ruled out any possibility for the non-centrosymmetric C222{sub 1} space group describing the structure of the small ionic radii ceramics, solving a recent controversy in the literature. Besides, the Raman modes for all samples are reported for the first time, showing characteristic features for each group of samples. - Graphical abstract: Raman spectrum for La{sub 3}SbO{sub 7} ceramics showing their 22 phonon modes adjusted through Lorentzian lines. According to synchrotron X-ray diffraction and Raman scattering, this material belongs to the space group Cmcm. - Highlights: Ln{sub 3}SbO{sub 7} ceramics belonging to the space groups Cmcm and Ccmm are synthesized. SXRD, SHG and Raman scattering confirmed the orthorhombic structures. Ccmm instead of C222{sub 1} is the correct one based on SHG and Raman data.

  7. Synchrotron X-ray diffraction and Raman spectroscopy of Ln{sub 3}NbO{sub 7} (Ln=La, Pr, Nd, Sm-Lu) ceramics obtained by molten-salt synthesis

    SciTech Connect (OSTI)

    Siqueira, K.P.F.; Soares, J.C.; Granado, E.; Bittar, E.M.; Paula, A.M. de; Moreira, R.L.; Dias, A.

    2014-01-15

    Ln{sub 3}NbO{sub 7} (Ln=La, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, and Lu) ceramics were obtained by molten-salt synthesis and their structures were systematically investigated by synchrotron X-ray diffraction (SXRD), second harmonic generation (SHG) and Raman spectroscopy. It was observed that ceramics with the largest ionic radii (La, Pr, Nd) crystallized into the Pmcn space group, while the ceramics with intermediate ionic radii (Sm-Gd) exhibited a different crystal structure belonging to the Ccmm space group. For this last group of ceramics, this result was corroborated by SHG and Raman scattering and ruled out any possibility for the non-centrosymmetric C 222{sub 1} space group, solving a recent controversy in the literature. Finally, according to SXRD, Tb-Lu containing samples exhibited an average defect fluorite structure (Fm3{sup }m space group). Nonetheless, broad scattering at forbidden Bragg reflections indicates the presence of short-range domains with lower symmetry. Vibrational spectroscopy showed the presence of six Raman-active modes, inconsistent with the average cubic fluorite structure, and in line with the existence of lower-symmetry nano-domains immersed in the average fluorite structure of these ceramics. - Graphical abstract: Raman spectrum for Sm{sub 3}NbO{sub 7} ceramics showing their 27 phonon modes adjusted through Lorentzian lines. According to synchrotron X-ray diffraction and Raman scattering, this material belongs to the space group Cmcm. Display Omitted - Highlights: Ln{sub 3}NbO{sub 7} ceramics were obtained by molten-salt synthesis. SXRD, SHG and Raman scattering confirmed orthorhombic and cubic structures. Ccmm instead of C222{sub 1} is the correct structure for SmGd ceramics. Pmcn space group was confirmed for La-, Pr- and Nd-based ceramics. For TbLu ceramics, ordered domains of a pyrochlore structure were observed.

  8. Discovery of New NOx Reduction Catalysts for CIDI Engines Using Combinatorial Techniques

    SciTech Connect (OSTI)

    Blint, Richard J

    2005-08-15

    This project for the discovery of new lean reduction NOx catalysts was initiated on August 16th, 2002 and is now into its fourth year. Several materials have already been identified as NOx reduction catalysts for possible future application. NOx reduction catalysts are a critical need in the North American vehicle market since these catalysts are needed to enable both diesels and lean gasoline engines to meet the 2007-2010 emission standards. Hydrocarbon selective catalytic reduction (SCR) is a preferred technology since it requires no infrastructure changes (as may be expected for urea SCR) and most likely has the simplest engine control strategy of the three proposed NOx reduction approaches. The use of fast throughput techniques and informatics greatly enhances the possibility of discovering new NOx reduction catalysts. Using fast throughput techniques this project has already screened over 3000 new materials and evaluates hundreds of new materials a month. Evaluating such a high number of new materials puts this approach into a very different paradigm than previous discovery approaches for new NOx reduction catalysts. With so much data on materials it is necessary to use statistical techniques to identify the potential catalysts and these statistical techniques are needed to optimize compositions of the multi-component materials that are identified under the program as possible new lean NOx catalysts. Several new materials have conversions in excess of 80% at temperatures above 300 C. That is more than twice the activity of previous HC SCR materials. These materials are candidates for emission control on heavy-duty systems (i.e.; over 8500 pounds gross weight). Tests of one of the downselected materials on an engine dynamometer show NOx reductions greater than 80% under some conditions even though the net NOx reductions on the HWFET and the US06 cycles were relatively low. The program is scheduled to continue until the end of the 2006 calendar year. Work in the final year will focus on continued discovery and identity of candidate materials, and also on refining the engine operating strategies to increase NOx reduction over a full engine cycle.

  9. Use of freeze-casting in advanced burner reactor fuel design

    SciTech Connect (OSTI)

    Lang, A. L.; Yablinsky, C. A.; Allen, T. R. [Dept. of Engineering Physics, Univ. of Wisconsin Madison, 1500 Engineering Drive, Madison, WI 53711 (United States); Burger, J.; Hunger, P. M.; Wegst, U. G. K. [Thayer School of Engineering, Dartmouth College, 8000 Cummings Hall, Hanover, NH 03755 (United States)

    2012-07-01

    This paper will detail the modeling of a fast reactor with fuel pins created using a freeze-casting process. Freeze-casting is a method of creating an inert scaffold within a fuel pin. The scaffold is created using a directional solidification process and results in open porosity for emplacement of fuel, with pores ranging in size from 300 microns to 500 microns in diameter. These pores allow multiple fuel types and enrichments to be loaded into one fuel pin. Also, each pore could be filled with varying amounts of fuel to allow for the specific volume of fission gases created by that fuel type. Currently fast reactors, including advanced burner reactors (ABR's), are not economically feasible due to the high cost of operating the reactors and of reprocessing the fuel. However, if the fuel could be very precisely placed, such as within a freeze-cast scaffold, this could increase fuel performance and result in a valid design with a much lower cost per megawatt. In addition to competitive costs, freeze-cast fuel would also allow for selective breeding or burning of actinides within specific locations in fast reactors. For example, fast flux peak locations could be utilized on a minute scale to target specific actinides for transmutation. Freeze-cast fuel is extremely flexible and has great potential in a variety of applications. This paper performs initial modeling of freeze-cast fuel, with the generic fast reactor parameters for this model based on EBR-II. The core has an assumed power of 62.5 MWt. The neutronics code used was Monte Carlo N-Particle (MCNP5) transport code. Uniform pore sizes were used in increments of 100 microns. Two different freeze-cast scaffold materials were used: ceramic (MgO-ZrO{sub 2}) and steel (SS316L). Separate models were needed for each material because the freeze-cast ceramic and metal scaffolds have different structural characteristics and overall porosities. Basic criticality results were compiled for the various models. Preliminary results show that criticality is achievable with freeze-cast fuel pins despite the significant amount of inert fuel matrix. Freeze casting is a promising method to achieve very precise fuel placement within fuel pins. (authors)

  10. Selective NOx Recirculation for Stationary Lean-Burn Natural Gas Engines

    SciTech Connect (OSTI)

    Nigel Clark; Gregory Thompson; Richard Atkinson; Richard Turton; Chamila Tissera; Emre Tatli; Andy Zimmerman

    2005-12-28

    Selective NOx Recirculation (SNR) involves cooling the engine exhaust gas and then adsorbing the oxides of nitrogen (NOx) from the exhaust stream, followed by the periodic desorption of NOx. By returning the desorbed, concentrated NOx into the engine intake and through the combustion chamber, a percentage of the NOx is decomposed during the combustion process. An initial study of NOx decomposition during lean-burn combustion was concluded in 2004 using a 1993 Cummins L10G 240hp natural gas engine. It was observed that the air/fuel ratio, injected NO (nitric oxide) quantity and engine operating points affected NOx decomposition rates of the engine. Chemical kinetic modeling results were also used to determine optimum NOx decomposition operating points and were published in the 2004 annual report. A NOx decomposition rate of 27% was measured from this engine under lean-burn conditions while the software model predicted between 35-42% NOx decomposition for similar conditions. A later technology 1998 Cummins L10G 280hp natural gas engine was procured with the assistance of Cummins Inc. to replace the previous engine used for 2005 experimental research. The new engine was equipped with an electronic fuel management system with closed-loop control that provided a more stable air/fuel ratio control and improved the repeatability of the tests. The engine was instrumented with an in-cylinder pressure measurement system and electronic controls, and was adapted to operate over a range of air/fuel ratios. The engine was connected to a newly commissioned 300hp alternating current (AC) motoring dynamometer. The second experimental campaign was performed to acquire both stoichiometric and slightly rich (0.97 lambda ratio) burn NOx decomposition rates. Effects of engine load and speed on decomposition were quantified, but Exhaust Gas Recirculation (EGR) was not varied independently. Decomposition rates of up to 92% were demonstrated. Following recommendations at the 2004 ARES peer review meeting at Argonne National Laboratories, in-cylinder pressure was measured to calculate engine indicated mean effective pressure (IMEP) changes due to NOx injections and EGR variations, and to observe conditions in the cylinder. The third experimental campaign gathered NOx decomposition data at 800, 1200 and 1800 rpm. EGR was added via an external loop, with EGR ranging from zero to the point of misfire. The air/fuel ratio was set at both stoichiometric and slightly rich conditions, and NOx decomposition rates were calculated for each set of runs. Modifications were made to the engine exhaust manifold to record individual exhaust temperatures. The three experimental campaigns have provided the data needed for a comprehensive model of NOx decomposition during the combustion process, and data have confirmed that there was no significant impact of injected NO on in-cylinder pressure. The NOx adsorption system provided by Sorbent Technologies Corp. (Twinsburg, OH), comprised a NOx adsorber, heat exchanger and a demister. These components were connected to the engine, and data were gathered to show both the adsorption of NOx from the engine, and desorption of NOx from the carbon-based sorbent material back into the engine intake, using a heated air stream. In order to quantify the NOx adsorption/desorption characteristics of the sorbent material, a bench top adsorption system was constructed and instrumented with thermocouples and the system output was fed into a NOx analyzer. The temperature of this apparatus was controlled while gathering data on the characteristics of the sorbent material. These data were required for development of a system model. Preliminary data were gathered in 2005, and will continue in early 2006. To assess the economic benefits of the proposed SNR technology the WVU research team has been joined in the last quarter by Dr Richard Turton (WVU-Chemical Engineering), who is modeling, sizing and costing the major components. The tasks will address modeling and preliminary design of the heat exchanger, demister and NOx sorbent chamber s

  11. Cyclone Boiler Field Testing of Advanced Layered NOx Control Technology in Sioux Unit 1

    SciTech Connect (OSTI)

    Marc A. Cremer; Bradley R. Adams

    2006-06-30

    A four week testing program was completed during this project to assess the ability of the combination of deep staging, Rich Reagent Injection (RRI), and Selective Non-Catalytic Reduction (SNCR) to reduce NOx emissions below 0.15 lb/MBtu in a cyclone fired boiler. The host site for the tests was AmerenUE's Sioux Unit 1, a 500 MW cyclone fired boiler located near St. Louis, MO. Reaction Engineering International (REI) led the project team including AmerenUE, FuelTech Inc., and the Electric Power Research Institute (EPRI). This layered approach to NOx reduction is termed the Advanced Layered Technology Approach (ALTA). Installed RRI and SNCR port locations were guided by computational fluid dynamics (CFD) based modeling conducted by REI. During the parametric testing, NOx emissions of 0.12 lb/MBtu were achieved consistently from overfire air (OFA)-only baseline NOx emissions of 0.25 lb/MBtu or less, when firing the typical 80/20 fuel blend of Powder River Basin (PRB) and Illinois No.6 coals. From OFA-only baseline levels of 0.20 lb/MBtu, NOx emissions of 0.12 lb/MBtu were also achieved, but at significantly reduced urea flow rates. Under the deeply staged conditions that were tested, RRI performance was observed to degrade as higher blends of Illinois No.6 were used. NOx emissions achieved with ALTA while firing a 60/40 blend were approximately 0.15 lb/MBtu. NOx emissions while firing 100% Illinois No.6 were approximately 0.165 lb/MBtu. Based on the performance results of these tests, economics analyses of the application of ALTA to a nominal 500 MW cyclone unit show that the levelized cost to achieve 0.15 lb/MBtu is well below 75% of the cost of a state of the art SCR.

  12. Two-stage Catalytic Reduction of NOx with Hydrocarbons

    SciTech Connect (OSTI)

    Umit S. Ozkan; Erik M. Holmgreen; Matthew M. Yung; Jonathan Halter; Joel Hiltner

    2005-12-21

    A two-stage system for the catalytic reduction of NO from lean-burn natural gas reciprocating engine exhaust is investigated. Each of the two stages uses a distinct catalyst. The first stage is oxidation of NO to NO{sub 2} and the second stage is reduction of NO{sub 2} to N{sub 2} with a hydrocarbon. The central idea is that since NO{sub 2} is a more easily reduced species than NO, it should be better able to compete with oxygen for the combustion reaction of hydrocarbon, which is a challenge in lean conditions. Early work focused on demonstrating that the N{sub 2} yield obtained when NO{sub 2} was reduced was greater than when NO was reduced. NO{sub 2} reduction catalysts were designed and silver supported on alumina (Ag/Al{sub 2}O{sub 3}) was found to be quite active, able to achieve 95% N{sub 2} yield in 10% O{sub 2} using propane as the reducing agent. The design of a catalyst for NO oxidation was also investigated, and a Co/TiO{sub 2} catalyst prepared by sol-gel was shown to have high activity for the reaction, able to reach equilibrium conversion of 80% at 300 C at GHSV of 50,000h{sup -1}. After it was shown that NO{sub 2} could be more easily reduced to N{sub 2} than NO, the focus shifted on developing a catalyst that could use methane as the reducing agent. The Ag/Al{sub 2}O{sub 3} catalyst was tested and found to be inactive for NOx reduction with methane. Through iterative catalyst design, a palladium-based catalyst on a sulfated-zirconia support (Pd/SZ) was synthesized and shown to be able to selectively reduce NO{sub 2} in lean conditions using methane. Development of catalysts for the oxidation reaction also continued and higher activity, as well as stability in 10% water, was observed on a Co/ZrO{sub 2} catalyst, which reached equilibrium conversion of 94% at 250 C at the same GHSV. The Co/ZrO{sub 2} catalyst was also found to be extremely active for oxidation of CO, ethane, and propane, which could potential eliminate the need for any separate oxidation catalyst. At every stage, catalyst synthesis was guided by the insights gained through detailed characterization of the catalysts using many surface and bulk analysis techniques such as X-ray diffraction, X-ray photoelectron spectroscopy, Temperature-programmed Reduction, Temperature programmed Desorption, and Diffuse Reflectance InfraRed Fourier Transform Spectroscopy as well as steady state reaction experiments. Once active catalysts for each stage had been developed, a physical mixture of the two catalysts was tested for the reduction of NO with methane in lean conditions. These experiments using a mixture of the catalysts produced N2 yields as high as 90%. In the presence of 10% water, the catalyst mixture produced 75% N{sub 2} yield, without any optimization. The dual catalyst system developed has the potential to be implemented in lean-burn natural gas engines for reducing NOx in lean exhaust as well as eliminating CO and unburned hydrocarbons without any fuel penalty or any system modifications. If funding continues, future work will focus on improving the hydrothermal stability of the system to bring the technology closer to application.

  13. Preliminary core design studies for the advanced burner reactor over a wide range of conversion ratios.

    SciTech Connect (OSTI)

    Hoffman, E. A.; Yang, W. S.; Hill, R. N.; Nuclear Engineering Division

    2008-05-05

    A consistent set of designs for 1000 MWt commercial-scale sodium-cooled Advance Burner Reactors (ABR) have been developed for both metal and oxide-fueled cores with conversion ratios from breakeven (CR=1.0) to fertile-free (CR=0.0). These designs are expected to satisfy thermal and irradiation damage limits based on the currently available data. The very low conversion ratio designs require fuel that is beyond the current fuel database, which is anticipated to be qualified by and for the Advanced Burned Test Reactor. Safety and kinetic parameters were calculated, but a safety analysis was not performed. Development of these designs was required to achieve the primary goal of this study, which was to generate representative fuel cycle mass flows for system studies of ABRs as part of the Global Nuclear Energy Partnership (GNEP). There are slight variations with conversion ratio but the basic ABR configuration consists of 144 fuel assemblies and between 9 and 22 primary control assemblies for both the metal and oxide-fueled cores. Preliminary design studies indicated that it is feasible to design the ABR to accommodate a wide range of conversion ratio by employing different assembly designs and including sufficient control assemblies to accommodate the large reactivity swing at low conversion ratios. The assemblies are designed to fit within the same geometry, but the size and number of fuel pins within each assembly are significantly different in order to achieve the target conversion ratio while still satisfying thermal limits. Current irradiation experience would allow for a conversion ratio of somewhat below 0.75. The fuel qualification for the first ABR should expand this experience to allow for much lower conversion ratios and higher bunrups. The current designs were based on assumptions about the performance of high and very high enrichment fuel, which results in significant uncertainty about the details of the designs. However, the basic fuel cycle performance trends such as conversion ratio and mass flow parameters are less sensitive to these parameters and the current results should provide a good basis for static and dynamic system analysis. The conversion ratio is fundamentally a ratio of the macroscopic cross section of U-238 capture to that of TRU fission. Since the microscopic cross sections only change moderately with fuel design and isotopic concentration for the fast reactor, a specific conversion ratio requires a specific enrichment. The approximate average charge enrichment (TRU/HM) is 14%, 21%, 33%, 56%, and 100% for conversion ratios of 1.0, 0.75, 0.50, 0.25, and 0.0 for the metal-fueled cores. The approximate average charge enrichment is 17%, 25%, 38%, 60%, and 100% for conversion ratios of 1.0, 0.75, 0.50, 0.25, and 0.0 for the oxide-fueled core. For the split batch cores, the maximum enrichment will be somewhat higher. For both the metal and oxide-fueled cores, the reactivity feedback coefficients and kinetics parameters seem reasonable. The maximum single control assembly reactivity faults may be too large for the low conversion ratio designs. The average reactivity of the primary control assemblies was increased, which may cause the maximum reactivity of the central control assembly to be excessive. The values of the reactivity coefficients and kinetics parameters show that some values appear to improve significantly at lower conversion ratios while others appear far less favorable. Detailed safety analysis is required to determine if these designs have adequate safety margins or if appropriate design modifications are required. Detailed system analysis data has been generated for both metal and oxide-fueled core designs over the entire range of potential burner reactors. Additional data has been calculated for a few alternative fuel cycles. The systems data has been summarized in this report and the detailed data will be provided to the systems analysis team so that static and dynamic system analyses can be performed.

  14. Nitrogen isotopes as indicators of NOx source contributions to atmospheric nitrate deposition across the Midwestern and Northeastern United States

    SciTech Connect (OSTI)

    E.M. Elliott; C. Kendall; S.D. Wanke; D.A. Burns; E.W. Boyer; K. Harlin; D.J. Bain; T.J. Butler

    2007-11-15

    Global inputs of NOx are dominated by fossil fuel combustion from both stationary and vehicular sources and far exceed natural NOx sources. However, elucidating NOx sources to any given location remains a difficult challenge, despite the need for this information to develop sound regulatory and mitigation strategies. We present results from a regional-scale study of nitrogen isotopes (15N) in wet nitrate deposition across 33 sites in the midwestern and northeastern U.S. We demonstrate that spatial variations in 15N are strongly correlated with NOx emissions from surrounding stationary sources and additionally that 15N is more strongly correlated with surrounding stationary source NOx emissions than pH, SO{sub 4}{sup 2-}, or NO{sub 3}{sup -} concentrations. Although emission inventories indicate that vehicle emissions are the dominant NOx source in the eastern U.S., our results suggest that wet NO{sub 3}{sup -} deposition at sites in this study is strongly associated with NOx emissions from power plants. This suggests that large areas of the landscape potentially receive atmospheric NOy deposition inputs in excess of what one would infer from existing monitoring data alone. Moreover, we determined that spatial patterns in 15N values are a robust indicator of stationary NOx contributions to wet NO{sub 3}{sup -} deposition and hence a valuable complement to existing tools for assessing relationships between NO{sub 3}{sup -} deposition, regional emission inventories, and for evaluating progress toward NOx reduction goals. 44 refs., 3 figs.

  15. Laboratory and Vehicle Demonstration of a "2nd-Generation" LNT+in-situ SCR Diesel NOx Emission Control Concept

    Broader source: Energy.gov [DOE]

    Experimental results show low-emissions potential - possibly T2/B2 (SULEV) NOx with low-emitting engines and system optimization.

  16. Luminescent pillared Ln{sup III}Zn{sup II} heterometallic coordination frameworks with two kinds of N-heterocyclic carboxylate ligands

    SciTech Connect (OSTI)

    Liu, Sui-Jun; Jia, Ji-Min; Cui, Yu; Han, Song-De; Chang, Ze

    2014-04-01

    In our efforts toward rational design and systematic synthesis of pillar-layer structure coordination frameworks, four new Ln{sup III}Zn{sup II} heterometallic coordination polymers (CPs) based on two kinds of N-heterocyclic carboxylic ligands with formula ([LnZn(L1){sub 2}(L2)(H{sub 2}O){sub m}]nH{sub 2}O){sub ?} (Ln=La (1), Eu (2), Gd (3) and Dy (4), m=3 (for 1) and 2 (for 24), n=8 (for 1) and 7 (for 24), H{sub 2}L1=pyridine-2,3-dicarboxylate acid, HL2=isonicotinic acid), have been synthesized under hydrothermal reaction of Ln{sub 2}O{sub 3}, ZnO, H{sub 2}L1 and HL2. CP 1 has a three-dimensional (3D) structure with a (3,6)-connected sit topology network, while CPs 24 are isostructural with 3D single-node pcu alpha-Po topology network. Also, luminescent properties of these CPs have also been investigated. The emission of 1 and 3 should be attributed to the coordination-perturbed ligand-centered luminescence and the emission spectra of 2 and 4 show the characteristic bands of the corresponding Ln{sup III} ions. - Graphical abstract: Four new 3D Ln{sup III}Zn{sup II} coordination frameworks with pillar-layer sit or pcu alpha-Po topology have been successfully obtained. Moreover, the photoluminescent properties of compounds 14 have also been investigated. - Highlights: Four new Ln{sup III}Zn{sup II} heterometallic coordination frameworks with two types of topologies have been synthesized. Metal oxides and two kinds of N-heterocyclic carboxylate ligands were used for the construction of targeted coordination polymers. The luminescent properties of the coordination polymers are investigated.

  17. Synergies of PCCI-Type Combustion and Lean NOx Trap Catalysis for Diesel Engines

    SciTech Connect (OSTI)

    Parks, II, James E; Prikhodko, Vitaly Y; Kass, Michael D; Huff, Shean P

    2008-01-01

    It is widely recognized that future NOx and PM emission targets for diesel engines cannot be met solely via advanced combustion over the full engine drive cycle. Therefore some combination of advanced combustion methodology with an aftertreatment technology will be required. In this study, NOx reduction, fuel efficiency, and regeneration performance of lean NOx trap (LNT) were evaluated for four operating conditions. The combustion approaches included baseline engine operation with and without EGR, two exhaust enrichment methods (post injection and delayed injection), and one advanced combustion mode to enable high efficiency clean combustion (HECC). A 1.7 liter 4-cylinder diesel engine was operated under five conditions, which represent key interest points for light-duty diesel operation. At the low load setting the exhaust temperature was too low to enable LNT regeneration and oxidation; however, HECC (low NOx) was achievable. HECC was also reached under more moderate loads and the exhaust temperatures were high enough to enable even further NOx reductions by the LNT. At high loads HECC becomes difficult but the LNT performance improves and acceptable regeneration can be met with enrichment methodologies.

  18. Turbulent Flame Speeds and NOx Kinetics of HHC Fuels with Contaminants and High Dilution Levels

    SciTech Connect (OSTI)

    Peterson, Eric; Krejci, Michael; Mathieu, Olivier; Vissotski, Andrew; Ravi, Sankat; Plichta, Drew; Sikes, Travis; Levacque, Anthony; Camou, Alejandro; Aul, Christopher

    2013-09-30

    This final report documents the technical results of the 3-year project entitled, “Turbulent Flame Speeds and NOx Kinetics of HHC Fuels with Contaminants and High Dilution Levels,” funded under the NETL of DOE. The research was conducted under six main tasks: 1) program management and planning; 2) turbulent flame speed measurements of syngas mixtures; 3) laminar flame speed measurements with diluents; 4) NOx mechanism validation experiments; 5) fundamental NOx kinetics; and 6) the effect of impurities on NOx kinetics. Experiments were performed using primary constant-volume vessels for laminar and turbulent flame speeds and shock tubes for ignition delay times and species concentrations. In addition to the existing shock- tube and flame speed facilities, a new capability in measuring turbulent flame speeds was developed under this grant. Other highlights include an improved NOx kinetics mechanism; a database on syngas blends for real fuel mixtures with and without impurities; an improved hydrogen sulfide mechanism; an improved ammonia kintics mechanism; laminar flame speed data at high pressures with water addition; and the development of an inexpensive absorption spectroscopy diagnostic for shock-tube measurements of OH time histories. The Project Results for this work can be divided into 13 major sections, which form the basis of this report. These 13 topics are divided into the five areas: 1) laminar flame speeds; 2) Nitrogen Oxide and Ammonia chemical kinetics; 3) syngas impurities chemical kinetics; 4) turbulent flame speeds; and 5) OH absorption measurements for chemical kinetics.

  19. Simulation of NOx emission in circulating fluidized beds burning low-grade fuels

    SciTech Connect (OSTI)

    Afsin Gungor

    2009-05-15

    Nitrogen oxides are a major environmental pollutant resulting from combustion. This paper presents a modeling study of pollutant NOx emission resulting from low-grade fuel combustion in a circulating fluidized bed. The simulation model accounts for the axial and radial distribution of NOx emission in a circulating fluidized bed (CFB). The model results are compared with and validated against experimental data both for small-size and industrial-size CFBs that use different types of low-grade fuels given in the literature. The present study proves that CFB combustion demonstrated by both experimental data and model predictions produces low and acceptable levels of NOx emissions resulting from the combustion of low-grade fuels. Developed model can also investigate the effects of different operational parameters on overall NOx emission. As a result of this investigation, both experimental data and model predictions show that NOx emission increases with the bed temperature but decreases with excess air if other parameters are kept unchanged. 37 refs., 5 figs., 5 tabs.

  20. Total integrated NOx compliance for existing pulverized coal-fired units

    SciTech Connect (OSTI)

    Camody, G.; Lewis, R.; Cohen, M.B.; Buschmann, J.; Hilton, R.; Larsson, A.C.; Tobiasz, R.

    1999-07-01

    The EPA Title 1 NOx emission limits along with the corresponding OTR regulations are mandating coal-fired NOx emission levels below 0.15 lb/MBtu. For tangentially fired units, experience has shown that the technology is currently available to achieve these limits. The question for each unit owner-operator becomes; what is the most economical technology or combination of technologies to achieve the required results? This paper provides a brief overview of Combustion Engineering, Inc.'s (ABB C-E) latest NOx control technologies, both in-furnace and post-combustion, for tangential coal-fired steam generators. The paper further reviews options of both stand-alone and combined multiple technologies to achieve the most cost-effective NOx compliance, while maintaining the high levels of unit efficiency and performance that is required to by successful in their deregulated power industry. Current operational data of both in-furnace and SCR NOx reduction systems are presented, as well as the latest historical cost data for the systems.

  1. Low NO{sub x}/SO{sub x} Burner retrofit for utility cyclone boilers. Quarterly technical progress report, June--September 1990

    SciTech Connect (OSTI)

    Not Available

    1990-12-31

    The objective of this project is to demonstrate the LNS Burner as retrofitted to the host cyclone boiler for effective low-cost control of NO{sub x} and SO{sub x} emissions while firing a bituminous coal. The LNS Burner employs a simple, innovative combustion process to burn pulverized coal at high temperatures and provides effective, low-cost control of sulfur dioxide (SO{sub 2}) and nitrogen oxides (NO{sub x}) emissions. The coal ash contains sulfur and is removed in the form of molten slag and flyash. Cyclone-fired boiler units are typically older units firing high-sulfur bituminous coals at very high temperatures which results in very high NO{sub x} and SO{sub x} emissions. The addition of conventional emission control equipment, such as wet scrubbers, to these older cyclone units in order to meet current and future environmental regulations is generally not economic. Further, the units are generally not compatible with low sulfur coal switching for S0{sub 2} control or selective catalytic reduction technologies for NO{sub x} control. Because the LNS Burner operates at the same very high temperatures as a typical cyclone boiler and produces a similar slag product, it may offer a viable retrofit option for cyclone boiler emission control. This was confirmed by the Cyclone Boiler Retrofit Feasibility Study carried out by TransAlta and an Operating Committee formed of cyclone boiler owners in 1989. An existing utility cyclone boiler, was then selected for the evaluation of the cost and performance study. It was concluded that the LNS Burner retrofit would be a cost-effective option for control of cyclone boiler emissions. A full-scale demonstration of the LNS Burner retrofit was selected in October 1988 as part of the DOE`s Clean Coal Technology Program Round II.

  2. Preparation and spectroscopic properties of rare-earth (RE) (RE = Sm, Eu, Tb, Dy, Tm)-activated K{sub 2}LnZr(PO{sub 4}){sub 3} (Ln = Y, La, Gd and Lu) phosphate in vacuum ultraviolet region

    SciTech Connect (OSTI)

    Zhang, Zhi-Jun; Lin, Xiao; Graduate School of Chinese Academy of Science, Beijing, 100039 ; Zhao, Jing-Tai; Zhang, Guo-Bin

    2013-02-15

    Graphical abstract: Display Omitted Highlights: ? We report the VUV spectroscopic properties of rare-earth ions in K{sub 2}LnZr(PO{sub 4}){sub 3}. ? The O{sup 2?}-Eu{sup 3+} charge transfer bands at about 220 nm have been observed. ? The 4f5d spin-allowed and spin-forbidden transitions of Tb{sup 3+} have been observed. ? There is energy transfer between the host and rare-earth activators. -- Abstract: Rare earth (RE = Sm, Eu, Tb, Dy and Tm)-activated K{sub 2}LnZr(PO{sub 4}){sub 3} (Ln = Y, La, Gd and Lu) have been synthesized by solid-state reaction method, and their vacuum ultraviolet (VUV) excitation luminescent characteristics have been investigated. The band in the wavelength range of 130157 nm and the other one range from 155 to 216 nm with the maximum at about 187 nm in the VUV excitation spectra of these compounds are attributed to the host lattice absorption and OZr charge transfer transition, respectively. The charge transfer bands (CTB) of O{sup 2?}-Sm{sup 3+}, O{sup 2?}-Dy{sup 3+} and O{sup 2?}-Tm{sup 3+}, in Sm{sup 3+}, Dy{sup 3+} and Tm{sup 3+}-activated samples, have not been obviously observed probably because the 2p electrons of oxygen are tightly bound to the zirconium ion in the host lattice. For Eu{sup 3+}-activated samples, the relatively weak O{sup 2?}-Eu{sup 3+} CTB at about 220 nm is observed. And for Tb{sup 3+}-activated samples, the bands at 223 and 258 nm are related to the 4f-5d spin-allowed and spin-forbidden transitions of Tb{sup 3+}, respectively. It is observed that there is energy transfer between the host lattice and the luminescent activators (e.g. Eu{sup 3+}, Tb{sup 3+}). From the standpoint of luminescent efficiency, color purity and chemical stability, K{sub 2}GdZr(PO{sub 4}){sub 3}:Sm{sup 3+}, Eu{sup 3+}, Tb{sup 3+} are attractive candidates for novel yellow, red, green-emitting PDP phosphors.

  3. Supercritical Carbon Dioxide Brayton Cycle Energy Conversion for Sodium-Cooled Fast Reactors/Advanced Burner Reactors

    SciTech Connect (OSTI)

    Sienicki, James J.; Moisseytsev, Anton; Cho, Dae H.; Momozaki, Yoichi; Kilsdonk, Dennis J.; Haglund, Robert C.; Reed, Claude B.; Farmer, Mitchell T.

    2007-07-01

    An optimized supercritical carbon dioxide (S-CO{sub 2}) Brayton cycle power converter has been developed for the 100 MWe (250 MWt) Advanced Burner Test Reactor (ABTR) eliminating the potential for sodium-water reactions and achieving a small power converter and turbine generator building. Cycle and plant efficiencies of 39.1 and 38.3 %, respectively, are calculated for the ABTR core outlet temperature of 510 deg. C. The ABTR S-CO{sub 2} Brayton cycle will incorporate Printed Circuit Heat Exchanger{sup TM} units in the Na-to-CO{sub 2} heat exchangers, high and low temperature recuperators, and cooler. A new sodium test facility is being completed to investigate the potential for transient plugging of narrow sodium channels typical of a Na-to-CO{sub 2} heat exchanger under postulated off-normal or accident conditions. (authors)

  4. Impact of Biodiesel-based Na on the Selective Catalytic Reduction of NOx by

    Office of Scientific and Technical Information (OSTI)

    NH3 Over Cu-zeolite Catalysts (Journal Article) | SciTech Connect Journal Article: Impact of Biodiesel-based Na on the Selective Catalytic Reduction of NOx by NH3 Over Cu-zeolite Catalysts Citation Details In-Document Search Title: Impact of Biodiesel-based Na on the Selective Catalytic Reduction of NOx by NH3 Over Cu-zeolite Catalysts Authors: Brookshear, D. William [1] ; Nguyen, Ke [1] ; Toops, Todd J [2] ; Bunting, Bruce G [2] ; Rohr, William F [2] + Show Author Affiliations University of

  5. Intra-catalyst Reductant Chemistry in Lean NOx Traps: A Study on Sulfur

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Effects | Department of Energy Intra-catalyst Reductant Chemistry in Lean NOx Traps: A Study on Sulfur Effects Intra-catalyst Reductant Chemistry in Lean NOx Traps: A Study on Sulfur Effects Presentation given at DEER 2006, August 20-24, 2006, Detroit, Michigan. Sponsored by the U.S. DOE's EERE FreedomCar and Fuel Partnership and 21st Century Truck Programs. PDF icon 2006_deer_parks.pdf More Documents & Publications The Next Regulatory Chapter for Commercial Vehicles Review of Diesel

  6. Long-Term Aging of NOx Sensors in Heavy-Duty Engine Exhaust | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Aging of NOx Sensors in Heavy-Duty Engine Exhaust Long-Term Aging of NOx Sensors in Heavy-Duty Engine Exhaust 2004 Diesel Engine Emissions Reduction (DEER) Conference Presentation: Advanced Petroleum-Based Fuels-Diesel Emission Control (APBF-DEC) Project PDF icon 2004_deer_orban.pdf More Documents & Publications Robust Nitrogen Oxide/Ammonia Sensors for Vehicle On-board Emissions Control Vehicle Technologies Office Merit Review 2015: Robust Nitrogen Oxide/Ammonia Sensors for

  7. SCReaming for Low NOx - SCR for the Light Duty Market | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy SCReaming for Low NOx - SCR for the Light Duty Market SCReaming for Low NOx - SCR for the Light Duty Market Presentation given at DEER 2006, August 20-24, 2006, Detroit, Michigan. Sponsored by the U.S. DOE's EERE FreedomCar and Fuel Partnership and 21st Century Truck Programs. PDF icon 2006_deer_traver.pdf More Documents & Publications Validated SCR Concept Development Simulation and Analysis of HP/LP EGR for Heavy-Duty Applications New Demands on Heavy Duty Engine Management

  8. Full Useful Life (120,000 miles) Exhaust Emission Performance of a NOx

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Adsorber and Diesel Particle Filter Equipped Passenger Car and Medium-Duty Engine in Conjunction with Ultralow-Sulfur Fuel | Department of Energy Full Useful Life (120,000 miles) Exhaust Emission Performance of a NOx Adsorber and Diesel Particle Filter Equipped Passenger Car and Medium-Duty Engine in Conjunction with Ultralow-Sulfur Fuel Full Useful Life (120,000 miles) Exhaust Emission Performance of a NOx Adsorber and Diesel Particle Filter Equipped Passenger Car and Medium-Duty Engine in

  9. Combining Biodiesel and EGR for Low-Temperature NOx and PM Reductions |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Biodiesel and EGR for Low-Temperature NOx and PM Reductions Combining Biodiesel and EGR for Low-Temperature NOx and PM Reductions Poster presentation at the 2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER 2007). 13-16 August, 2007, Detroit, Michigan. Sponsored by the U.S. Department of Energy's (DOE) Office of FreedomCAR and Vehicle Technologies (OFCVT). PDF icon deer07_muncrief.pdf More Documents & Publications Design of Integrated Laboratory

  10. Effect of Engine-Out NOx Control Strategies on PM Size Distribution in

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Heavy-Duty Diesel Engines Developed for 2010 | Department of Energy Engine-Out NOx Control Strategies on PM Size Distribution in Heavy-Duty Diesel Engines Developed for 2010 Effect of Engine-Out NOx Control Strategies on PM Size Distribution in Heavy-Duty Diesel Engines Developed for 2010 A distinct relationship was found between engine-out and SCR-out PM distributions for single-mode testing. PDF icon deer08_ardanese.pdf More Documents & Publications Development of ADECS to Meet 2010

  11. USE OF A DIESEL FUEL PROCESSOR FOR RAPID AND EFFICIENT REGENERATION OF SINGLE LEG NOX ADSORBER SYSTEMS

    SciTech Connect (OSTI)

    Betta, R; Cizeron, J; Sheridan, D; Davis, T

    2003-08-24

    Lean NOx adsorber systems are one of the primary candidate technologies for the control of NOx from diesel engines to meet the 2007-2010 US emissions regulations, which require a 90% reduction of NOx from the 2004 regulations. Several of the technical challenges facing this technology are regeneration at low exhaust temperatures and the efficient use of diesel fuel to minimize fuel penalty. A diesel processor system has been developed and tested in a single leg NOx adsorber configuration on a diesel engine test stand. During NOx adsorber regeneration, this fuel processor system performs reduces the exhaust O2 level to zero and efficiently processes the diesel fuel to H2 and CO. Combined with a Nox adsorber catalyst, this system has demonstrated NOx reduction above 90%, regeneration of the NOx adsorber H2/CO pulses as short as 1 second and fuel penalties in the 3 to 4% range at 50% load. This fuel processor system can also be used to provide the desulfation cycle required with sulfur containing fuels as well as providing thermal management for PM filter regeneration.

  12. Small, Inexpensive Combined NOx and O2 Sensor

    SciTech Connect (OSTI)

    W. Lawless; C. Clark

    2008-09-01

    It has been successfully demonstrated in this program that a zirconia multilayer structure with rhodium-based porous electrodes performs well as an amperometric NO{sub x} sensor. The sensitivity of the sensor bodies operating at 650 to 700 C is large, with demonstrated current outputs of 14 mA at 500 ppm NO{sub x} from sensors with 30 layers. The sensor bodies are small (4.5 x 4.2 x 3.1 mm), rugged, and inexpensive. It is projected the sensor bodies will cost $5-$10 in production. This program has built on another successful development program for an oxygen sensor based on the same principles and sponsored by DOE. This oxygen sensor is not sensitive to NO{sub x}. A significant technical hurdle has been identified and solved. It was found that the 100% Rh electrodes oxidize rapidly at the preferred operating temperatures of 650-700 C, and this oxidation is accompanied by a volume change which delaminates the sensors. The problem was solved by using alloys of Rh and Pt. It was found that a 10%/90% Rh/Pt alloy dropped the oxidation rate of the electrodes by orders of magnitude without degrading the NO{sub x} sensitivity of the sensors, allowing long-term stable operation at the preferred operating temperatures. Degradation in the sensor output caused by temperature cycling was identified as a change in resistance at the junction between the sensor body and the external leads attached to the sensor body. The degradation was eliminated by providing strong mechanical anchors for the wire and processing the junctions to obtain good electrical bonds. The NO{sub x} sensors also detect oxygen and therefore the fully-packaged sensor needs to be enclosed with an oxygen sensor in a small, heated zirconia chamber exposed to test gas through a diffusion plug which limits the flow of gas from the outside. Oxygen is pumped from the interior of the chamber to lower the oxygen content and the combination of measurements from the NO{sub x} and oxygen sensors yields the NO{sub x} content of the gas. Two types of electronic control units were designed and built. One control unit provides independent constant voltages to the NOx and oxygen sensors and reads the current from them (that is, detects the amount of test gas present). The second controller holds the fully-assembled sensor at the desired operating temperature and controllably pumps excess oxygen from the test chamber. While the development of the sensor body was a complete success, the development of the packaging was only partially successful. All of the basic principles were demonstrated, but the packaging was too complex to optimize the operation within the resources of the program. Thus, no fully-assembled sensors were sent to outside labs for testing of cross-sensitivities, response times, etc. Near the end of the program, Sensata Technologies of Attleboro, MA tested the sensor bodies and confirmed the CeramPhysics measurements as indicated in the following attached letter. Sensata was in the process of designing their own packaging for the sensor and performing cross-sensitivity tests when they stopped all sensor development work due to the automotive industry downturn. Recently Ceramatec Inc. of Salt Lake City has expressed an interest in testing the sensor, and other licensing opportunities are being pursued.

  13. A Numerical Investigation into the Anomalous Slight NOx Increase when Burning Biodiesel: A New (Old) Theory

    SciTech Connect (OSTI)

    Ban-Weiss, G A; Chen, J Y; Buchholz, B A; Dibble, R W

    2007-01-30

    Biodiesel is a notable alternative to petroleum derived diesel fuel because it comes from natural domestic sources and thus reduces dependence on diminishing petroleum fuel from foreign sources, it likely lowers lifecycle greenhouse gas emissions, and it lowers an engine's emission of most pollutants as compared to petroleum derived diesel. However, the use of biodiesel often slightly increases a diesel engine's emission of smog forming nitrogen oxides (NO{sub x}) relative to petroleum diesel. In this paper, previously proposed theories for this slight NOx increase are reviewed, including theories based on biodiesel's cetane number, which leads to differing amounts of charge preheating, and theories based on the fuel's bulk modulus, which affects injection timing. This paper proposes an additional theory for the slight NO{sub x} increase of biodiesel. Biodiesel typically contains more double bonded molecules than petroleum derived diesel. These double bonded molecules have a slightly higher adiabatic flame temperature, which leads to the increase in NOx production for biodiesel. Our theory was verified using numerical simulations to show a NOx increase, due to the double bonded molecules, that is consistent with observation. Further, the details of these numerical simulations show that NOx is predominantly due to the Zeldovich mechanism.

  14. Impact of sulfation and desulfation on NOx reduction using Cu-chabazite SCR catalysts

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Brookshear, Daniel William; Nam, Jeong -Gil; Nguyen, Ke; Toops, Todd J.; Binder, Andrew J.

    2015-06-05

    This bench reactor study investigates the impact of gaseous sulfur on the NOx reduction activity of Cu-chabazite SCR (Cu-CHA) catalysts at SO2 concentrations representative of marine diesel engine exhaust. After two hours of 500 ppm SO2 exposure at 250 and 400 °C in the simulated diesel exhaust gases, the NOx reduction activity of the sulfated Cu-CHA SCR catalysts is severely degraded at evaluation temperatures below 250 °C; however, above 250 °C the impact of sulfur exposure is minimal. EPMA shows that sulfur is located throughout the washcoat and along the entire length of the sulfated samples. Interestingly, BET measurements revealmore » that the sulfated samples have a 20% decrease in surface area. Moreover, the sulfated samples show a decrease in NOx/nitrate absorption during NO exposure in a DRIFTS reactor which suggests that Cu sites in the catalyst are blocked by the presence of sulfur. SO2 exposure also results in an increase in NH3 storage capacity, possibly due to the formation of ammonium sulfate species in the sulfated samples. In all cases, lean thermal treatments as low as 500 °C reverse the effects of sulfur exposure and restore the NOx reduction activity of the Cu-CHA catalyst to that of the fresh condition.« less

  15. Impact of Sulfation and Desulfation on NOx Reduction Using Cu-Chabazite SCR Catalysts

    SciTech Connect (OSTI)

    Brookshear, Daniel W; Nam, Jeong-Gil; Nguyen, Ke; Toops, Todd J; Binder, Andrew J

    2015-01-01

    This bench reactor study investigates the impact of gaseous sulfur on the NOx reduction activity of Cu-chabazite SCR (Cu-CHA) catalysts at SO2 concentrations representative of marine diesel engine exhaust. After two hours of 500 ppm SO2 exposure at 250 and 400 C in the simulated diesel exhaust gases, the NOx reduction activity of the sulfated Cu-CHA SCR catalysts is severely degraded at evaluation temperatures below 250 C; however, above 250 C the impact of sulfur exposure is minimal. EPMA shows that sulfur is located throughout the washcoat and along the entire length of the sulfated samples. Interestingly, BET measurements reveal that the sulfated samples have a 20% decrease in surface area. Furthermore, the sulfated samples show a decrease in NOx/nitrate absorption during NO exposure in a DRIFTS reactor which suggests that Cu sites in the catalyst are blocked by the presence of sulfur. SO2 exposure also results in an increase in NH3 storage capacity, possibly due to the formation of ammonium sulfate species in the sulfated samples. In all cases, lean thermal treatments as low as 500 C reverse the effects of sulfur exposure and restore the NOx reduction activity of the Cu-CHA catalyst to that of the fresh condition.

  16. Recent advances in automotive catalysis for NOx emission control by small-pore microporous materials

    SciTech Connect (OSTI)

    Beale, Andrew M.; Gao, Feng; Lezcano-Gonzalez, Ines; Peden, Charles HF; Szanyi, Janos

    2015-10-05

    The ever increasing demand to develop highly fuel efficient engines coincides with the need to minimize air pollution originating from the exhaust gases of internal combustion engines. Dramatically improved fuel efficiency can be achieved at air-to-fuel ratios much higher than stoichiometric. In the presence of oxygen in large excess, however, traditional three-way catalysts are unable to reduce NOx. Among the number of lean-NOx reduction technologies, selective catalytic reduction (SCR) of NOx by NH3 over Cu- and Fe-ion exchanged zeolite catalysts has been extensively studied over the past 30+ years. Despite the significant advances in developing a viable practical zeolite-based catalyst for lean NOx reduction, the insufficient hydrothermal stabilities of the zeolite structures considered cast doubts about their real-world applicability. During the past decade a renewed interest in zeolite-based lean NOx reduction was spurred by the discovery of the very high activity of Cu-SSZ-13 (and the isostructural Cu-SAPO-34) in the NH3 SCR of NOx. These new, small-pore zeolite-based catalysts not only exhibited very high NOx conversion and N2 selectivity, but also exhibited exceptional high hydrothermal stability at high temperatures. In this review we summarize the key discoveries of the past ~5 years that lead to the introduction of these catalysts into practical application. The review first briefly discusses the structure and preparation of the CHA structure-based zeolite catalysts, and then summarizes the key learnings of the rather extensive (but not complete) characterisation work. Then we summarize the key findings of reaction kinetics studies, and provide some mechanistic details emerging from these investigations. At the end of the review we highlight some of the issues that are still need to be addressed in automotive exhaust control catalysis. Funding A.M.B. and I.L.G. would like to thank EPSRC for funding. F.G., C.H.F.P. and J.Sz. gratefully acknowledge financial support from the US Department of Energy (DOE), Office of Energy Efficiency and Renewable Energy, Vehicle Technologies Program.

  17. Effect of air-staging on anthracite combustion and NOx formation

    SciTech Connect (OSTI)

    Weidong Fan; Zhengchun Lin; Youyi Li; Jinguo Kuang; Mingchuan Zhang

    2009-01-15

    Experiments were carried out in a multipath air inlet one-dimensional furnace to assess NOx emission characteristics of the staged combustion of anthracite coal. These experiments allowed us to study the impact of pulverized coal fineness and burnout air position on emission under both deep and shallow air-staged combustion conditions. We also studied the impact of char-nitrogen release on both the burning-out process of the pulverized coal and the corresponding carbon content in fly ash. We found that air-staged combustion affects a pronounced reduction in NOx emissions from the combustion of anthracite coal. The more the air is staged, the more NOx emission is reduced. In shallow air-staged combustion (f{sub M} = 0.85), the fineness of the pulverized coal strongly influences emissions, and finer coals result in lower emissions. Meanwhile, the burnout air position has only a weak effect. In the deep air-staged combustion (f{sub M} = 0.6), the effect of coal fineness is smaller, and the burnout air position has a stronger effect. When the primary combustion air is stable, NOx emissions increase with increasing burnout air. This proves that, in the burnout zone, coal char is responsible for the discharge of fuel-nitrogen that is oxidized to NOx. The measurement of secondary air staging in a burnout zone can help inhibit the oxidization of NO caused by nitrogen release. Air-staged combustion has little effect on the burnout of anthracite coal, which proves to be suitable for air-staged combustion. 31 refs., 11 figs., 1 tab.

  18. SOx-NOx-Rox Box{trademark} flue gas clean-up demonstration. Final report

    SciTech Connect (OSTI)

    1995-09-01

    Babcock and Wilcox`s (B and W) SOx-NOx-Rox Box{trademark} process effectively removes SOx, NOx and particulate (Rox) from flue gas generated from coal-fired boilers in a single unit operation, a high temperature baghouse. The SNRB technology utilizes dry sorbent injection upstream of the baghouse for removal of SOx and ammonia injection upstream of a zeolitic selective catalytic reduction (SCR) catalyst incorporated in the baghouse to reduce NOx emissions. Because the SOx and NOx removal processes require operation at elevated gas temperatures (800--900 F) for high removal efficiency, high-temperature fabric filter bags are used in the baghouse. The SNRB technology evolved from the bench and laboratory pilot scale to be successfully demonstrated at the 5-MWe field scale. This report represents the completion of Milestone M14 as specified in the Work Plan. B and W tested the SNRB pollution control system at a 5-MWe demonstration facility at Ohio Edison`s R.E. Burger Plant located near Shadyside, Ohio. The design and operation were influenced by the results from laboratory pilot testing at B and W`s Alliance Research Center. The intent was to demonstrate the commercial feasibility of the SNRB process. The SNRB facility treated a 30,000 ACFM flue gas slipstream from Boiler No. 8. Operation of the facility began in May 1992 and was completed in May 1993. About 2,300 hours of high-temperature operation were achieved. The main emissions control performance goals of: greater than 70% SO{sub 2} removal using a calcium-based sorbent; greater than 90% NOx removal with minimal ammonia slip; and particulate emissions in compliance with the New Source Performance Standards (NSPS) of 0.03 lb/million Btu were exceeded simultaneously in the demonstration program when the facility was operated at optimal conditions. Testing also showed significant reductions in emissions of some hazardous air pollutants.

  19. Greenhouse gas emissions trading in U.S. States: observations and lessons from the OTC NOx Budget Program

    SciTech Connect (OSTI)

    Andrew Aulisi; Alexander E. Farrell; Jonathan Pershing; Stacy VanDeveer

    2005-07-01

    A number of U.S. states are considering market-based policies to reduce emissions of greenhouse gases (GHGs). The experience gained from emissions trading for sulfur dioxide and oxides of nitrogen (NOx) offers a useful body of information and data to draw on to design a GHG emissions trading system. This report examines NOx trading under the Ozone Transport Commission (OTC) NOx Budget Program, which resulted principally from the leadership, decisions, and actions by a group of states, ultimately becoming the first multilateral cap-and-trade system for emissions of air pollutants. 72 refs.

  20. Low NO{sub x} combustion system with DSVS{trademark} rotating classifier retrofit for a 630 MW{sub e} cell burner unit

    SciTech Connect (OSTI)

    Bryk, S.A.; Maringo, G.J.; Shah, A.I.; Madden, V.F.

    1996-12-31

    New England Power Company`s (NEP) 630 MW{sub e} Brayton Point Unit 3 is a universal pressure (UP) type supercritical boiler originally equipped with pulverized coal (PC) fired cell burners. In order to comply with the Phase 1 NO{sub x} emissions requirements under Title I of the 1990 Clean Air Act Amendments, the unit has been retrofitted with a low NO{sub x} staged combustion system during the spring 1995 outage. The unit was restarted in early May 1995 and was operating under the State Compliance emission levels by the end of the month. Additional optimization testing was performed in August, 1995. The retrofit scope consisted of replacing the cell burners with low NO{sub x} DRB-XCL{reg_sign} type PC/oil burners and overfire air ports within the existing open windbox, with no change in the firing pattern. A 70% NO{sub x} reduction from baseline levels was achieved while maintaining acceptable unburned carbon (UBC) and carbon monoxide (CO) emission levels. To maintain low UBC levels, the scope included modifying the MPS-89 pulverizers by replacing the existing stationary classifiers with the B and W DSVS{trademark} (Dynamically Staged Variable Speed) two stage rotating classifiers. The DSVS{trademark} classifiers provide higher fineness for UBC control without derating the mill capacity. This paper will describe the project and discuss the retrofit emissions data. The paper will conclude with recommendations for retrofitting other similarly designed units.

  1. Flame-synthesis limits and self-catalytic behavior of carbon nanotubes using a double-faced wall stagnation flow burner

    SciTech Connect (OSTI)

    Woo, S.K.; Hong, Y.T.; Kwon, O.C.

    2009-10-15

    Flame-synthesis limits of carbon nanotubes (CNTs) are measured using a double-faced wall stagnation flow (DWSF) burner that shows potential in mass production of CNTs. With nitrogen-diluted premixed ethylene-air flames established on the nickel-coated stainless steel double-faced plate wall, the limits of CNT formation are determined using field-emission scanning and transmission electron microscopies and Raman spectroscopy. Also, self-catalytic behavior of the synthesized CNTs is evaluated using the DWSF burner with a CNT-deposited stainless steel double-faced plate wall. Results show narrow fuel-equivalence ratio limits of multi-walled CNT (MWCNT)-synthesis at high flame stretch rates and substantially extended limits at low flame stretch rates. This implies that the synthesis limits are very sensitive to the fuel-equivalence ratio variation for the high stretch rate conditions, yielding a lot of impurities and soot rather than MWCNTs. The enhanced ratio of tube inner diameter to wall thickness of the MWCNTs synthesized using a CNT self-catalytic flame-synthesis process is observed, indicating that the quality of metal-catalytic, flame-synthesized MWCNTs can be much improved via the process. Thus, using a DWSF burner with the CNT self-catalytic process has potential in mass production of MWCNTs with improved quality. (author)

  2. New operation strategy for driving the selectivity of NOx reduction to N2, NH3 or N2O during lean/rich cycling of a lean NOx trap catalyst

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Mr?ek, David; Koci, Petr; Choi, Jae -Soon; Partridge, Jr., William P.

    2015-09-08

    Periodical regeneration of NOx storage catalyst (also known as lean NOx trap) by short rich pulses of CO, H2 and hydrocarbons is necessary for the reduction of nitrogen oxides adsorbed on the catalyst surface. Ideally, the stored NOx is converted into N2, but N2O and NH3 by-products can be formed as well, particularly at low-intermediate temperatures. The N2 and N2O products are formed concurrently in two peaks. The primary peaks appear immediately after the rich-phase inception, and tail off with the breakthrough of the reductant front accompanied by NH3 product. In addition, the secondary N2 and N2O peaks then appearmoreat the rich-to-lean transition as a result of reactions between surface-deposited reductants/intermediates (CO, HC, NH3, NCO) and residual stored NOx under increasingly lean conditions.less

  3. Laboratory evaluation of a reactive baffle approach to NOx control. Final technical report, February-April 1993

    SciTech Connect (OSTI)

    Nelson, S.G.; Van Stone, D.A.; Little, R.C.; Peterson, R.A.

    1993-09-01

    Vermiculite, vermiculite coated with magnesia, and activated carbon sorbents have successfully removed NOx (and carbon monoxide and particles) from combustion exhausts in a subscale drone jet engine test cell (JETC), but back pressure so generated elevated the temperature of the JETC and of the engine. The objective of this effort was to explore the feasibility of locating the sorbents in the face of the duct or of baffles parallel to the direction of flow within the ducts. Jet engine test cells (JETCs) are stationary sources of oxides of nitrogen (NOx), soot, and unburned or partially oxidized carbon compounds that form as byproducts of imperfect combustion. Regulation of NOx emissions is being considered for implementation under the Clean Air Act Amendments of 1990. Several principles have been examined as candidate methods to control NOx emissions from JETCs.

  4. Satellite-observed US power plant NOx emission reductions and their impact on air quality - article no. L22812

    SciTech Connect (OSTI)

    Kim, S.W.; Heckel, A.; McKeen, S.A.; Frost, G.J.; Hsie, E.Y.; Trainer, M.K.; Richter, A.; Burrows, J.P.; Peckham, S.E.; Grell, G.A.

    2006-11-29

    Nitrogen oxide (NOx) emissions resulting from fossil fuel combustion lead to unhealthy levels of near-surface ozone (O{sub 3}). One of the largest U.S. sources, electric power generation, represented about 25% of the U.S. anthropogenic NOx emissions in 1999. Here we show that space-based instruments observed declining regional NOx levels between 1999 and 2005 in response to the recent implementation of pollution controls by utility companies in the eastern U.S. Satellite-retrieved summertime nitrogen dioxide (NO{sub 2}) columns and bottom-up emission estimates show larger decreases in the Ohio River Valley, where power plants dominate NOx emissions, than in the northeast U.S. urban corridor. Model simulations predict lower O{sub 3} across much of the eastern U.S. in response to these emission reductions.

  5. Simulation of catalytic oxidation and selective catalytic NOx reduction in lean-exhaust hybrid vehicles

    SciTech Connect (OSTI)

    Gao, Zhiming; Daw, C Stuart; Chakravarthy, Veerathu K

    2012-01-01

    We utilize physically-based models for diesel exhaust catalytic oxidation and urea-based selective catalytic NOx reduction to study their impact on drive cycle performance of hypothetical light-duty diesel powered hybrid vehicles. The models have been implemented as highly flexible SIMULINK block modules that can be used to study multiple engine-aftertreatment system configurations. The parameters of the NOx reduction model have been adjusted to reflect the characteristics of Cu-zeolite catalysts, which are of widespread current interest. We demonstrate application of these models using the Powertrain System Analysis Toolkit (PSAT) software for vehicle simulations, along with a previously published methodology that accounts for emissions and temperature transients in the engine exhaust. Our results illustrate the potential impact of DOC and SCR interactions for lean hybrid electric and plug-in hybrid electric vehicles.

  6. Initial Results of the DeNOx SCR System by Urea Injection in the Euro 5 Bus

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    | Department of Energy Initial Results of the DeNOx SCR System by Urea Injection in the Euro 5 Bus Initial Results of the DeNOx SCR System by Urea Injection in the Euro 5 Bus 2005 Diesel Engine Emissions Reduction (DEER) Conference Presentations and Posters PDF icon 2005_deer_seguelong.pdf More Documents & Publications Potential Effect of Pollutantn Emissions on Global Warming: First Comparisong Using External Costs on Urban Buses Vehicle Emissions Review - 2012 Comparative Study on

  7. Closed loop engine control for regulating NOx emissions, using a two-dimensional fuel-air curve

    DOE Patents [OSTI]

    Bourn, Gary D.; Smith, Jack A.; Gingrich, Jess W.

    2007-01-30

    An engine control strategy that ensures that NOx emissions from the engine will be maintained at an acceptable level. The control strategy is based on a two-dimensional fuel-air curve, in which air manifold pressure (AMP) is a function of fuel header pressure and engine speed. The control strategy provides for closed loop NOx adjustment to a base AMP value derived from the fuel-air curve.

  8. Development of METHANE de-NOX Reburn Process for Wood Waste and Biomass Fired Stoker Boilers - Final Report - METHANE de-NOX Reburn Technology Manual

    SciTech Connect (OSTI)

    J. Rabovitser; B. Bryan; S. Wohadlo; S. Nester; J. Vaught; M. Tartan L. Szymanski; R. Glickert

    2007-12-31

    The overall objective of this project was to demonstrate the effectiveness of the METHANE de-NOX (MdN) Reburn process in the Forest Products Industry (FPI) to provide more efficient use of wood and sludge waste (biosolids) combustion for both energy generation and emissions reduction (specifically from nitrogen oxides (NOx)) and to promote the transfer of the technology to the wide range of wood waste-fired stoker boilers populating the FPI. This document, MdN Reburn Commercial Technology Manual, was prepared to be a resource to promote technology transfer and commercialization activities of MdN in the industry and to assist potential users understand its application and installation requirements. The Manual includes a compilation of MdN commercial design data from four different stoker boiler designs that were baseline tested as part of the development effort. Design information in the Manual include boiler CFD model studies, process design protocols, engineering data sheets and commercial installation drawings. Each design package is unique and implemented in a manner to meet specific mill requirements.

  9. Lean NOx Trap Formulation Effect on Performance with In-Cylinder

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Regeneration Strategies | Department of Energy Formulation Effect on Performance with In-Cylinder Regeneration Strategies Lean NOx Trap Formulation Effect on Performance with In-Cylinder Regeneration Strategies Poster presentation at the 2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER 2007). 13-16 August, 2007, Detroit, Michigan. Sponsored by the U.S. Department of Energy's (DOE) Office of FreedomCAR and Vehicle Technologies (OFCVT). PDF icon deer07_parks.pdf More

  10. Compact Combination NOx/O2 Sensors for High-Temperature Applications -

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Innovation Portal Find More Like This Return to Search Compact Combination NOx/O2 Sensors for High-Temperature Applications Argonne National Laboratory Contact ANL About This Technology <p> <em>High-temperature potentiometric oxygen sensor with internal reference. The deformation bonding method produces pore-free, gas-tight joints between ceramic shell components while retaining material strength and ion conductivity.</em></p> High-temperature potentiometric

  11. Cummins/ORNL-FEERC CRADA: NOx Control & Measurement Technology for

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Heavy-Duty Diesel Engines | Department of Energy 09 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C. PDF icon ace_32_partridge.pdf More Documents & Publications Cummins/ORNL-FEERC CRADA: NOx Control & Measurement Technology for Heavy-Duty Diesel Engines CLEERS Coordination & Development of Catalyst Process Kinetic Data

  12. Electron-stimulated desorption from polished and vacuum fired 316LN stainless steel coated with Ti-Zr-Hf-V

    SciTech Connect (OSTI)

    Malyshev, Oleg B. Valizadeh, Reza; Hogan, Benjamin T.; Hannah, Adrian N.

    2014-11-01

    In this study, two identical 316LN stainless steel tubular samples, which had previously been polished and vacuum-fired and then used for the electron-stimulated desorption (ESD) experiments, were coated with Ti-Zr-Hf-V with different morphologies: columnar and dense. ESD measurement results after nonevaporable getter (NEG) activation to 150, 180, 250, and 350?C indicated that the values for the ESD yields are significantly (220 times) lower than the data from our previous study with similar coatings on nonvacuum-fired samples. Based on these results, the lowest pressure and best long-term performance in particle accelerators will be achieved with a vacuum-fired vacuum chamber coated with dense Ti-Zr-Hf-V coating activated at 180?C. This is likely due to the following facts: after NEG activation, the hydrogen concentration inside the NEG was lower than in the bulk stainless steel substrate; the NEG coating created a barrier for gas diffusion from the sample bulk to vacuum; the dense NEG coating performed better as a barrier than the columnar NEG coating.

  13. Ammonia Generation over TWC for Passive SCR NOX Control for Lean Gasoline Engines

    SciTech Connect (OSTI)

    Prikhodko, Vitaly Y; Parks, II, James E; Pihl, Josh A; Toops, Todd J

    2014-01-01

    A commercial three-way catalyst (TWC) was evaluated for ammonia (NH3) generation on a 2.0-liter BMW lean burn gasoline direct injection engine as a component in a passive ammonia selective catalytic reduction (SCR) system. The passive NH3 SCR system is a potential low cost approach for controlling nitrogen oxides (NOX) emissions from lean burn gasoline engines. In this system, NH3 is generated over a close-coupled TWC during periodic slightly rich engine operation and subsequently stored on an underfloor SCR catalyst. Upon switching to lean, NOX passes through the TWC and is reduced by the stored NH3 on the SCR catalyst. NH3 generation was evaluated at different air-fuel equivalence ratios at multiple engine speed and load conditions. Near complete conversion of NOX to NH3 was achieved at =0.96 for nearly all conditions studied. At the =0.96 condition, HC emissions were relatively minimal, but CO emissions were significant. Operation at AFRs richer than =0.96 did not provide more NH3 yield and led to higher HC and CO emissions. Results of the reductant conversion and consumption processes were used to calculate a representative fuel consumption of the engine operating with an ideal passive SCR system. The results show a 1-7% fuel economy benefit at various steady-state engine speed and load points relative to a stoichiometric engine operation.

  14. MODELING COMPETITIVE ADSORPTION IN UREA-SCR CATALYSTS FOR EFFECTIVE LOW TEMPERATURE NOX CONTROL

    SciTech Connect (OSTI)

    Devarakonda, Maruthi N.; Tonkyn, Russell G.; Tran, Diana N.; Lee, Jong H.; Herling, Darrell R.

    2010-09-17

    Although the SCR technology exhibits higher NOx reduction efficiency over a wider range of temperatures among the lean NOx reduction technologies, further improvement in low-temperature performance is required to meet the future emission standards and to lower the system cost. In order to improve the catalyst technologies and optimize the system performance, it is critical to understand the reaction mechanisms and catalyst behaviors with respect to operating conditions. For example, it is well known that the ammonia coverage on catalyst surface is critical for NOx reduction efficiency. However, the level of ammonia storage is influenced by competitive adsorption by other species, such as H2O and NO2. Moreover, hydrocarbon species that slip through the upstream DOC during the cold-start period can also inhibit the SCR performance, especially at low temperatures. Therefore, a one-dimensional detailed kinetic model that can account for the effects of such competitive adsorption has been developed based on steady state surface isotherm tests on a commercial Fe-zeolite catalyst. The model is developed as a C language S-function and implemented in Matlab/Simulink environment. Rate kinetics of adsorption and desorption of each of the adsorbents are determined from individual adsorption tests and validated for a set of test conditions that had all the adsorbents in the feed gas.

  15. Modeling Species Inhibition of NO Oxidation in Urea-SCR Catalysts for Diesel Engine NOx Control

    SciTech Connect (OSTI)

    Devarakonda, Maruthi N.; Tonkyn, Russell G.; Tran, Diana N.; Lee, Jong H.; Herling, Darrell R.

    2011-04-20

    Urea-selective catalytic reduction (SCR) catalysts are regarded as the leading NOx aftertreatment technology to meet the 2010 NOx emission standards for on-highway vehicles running on heavy-duty diesel engines. However, issues such as low NOx conversion at low temperature conditions still exist due to various factors, including incomplete urea thermolysis, inhibition of SCR reactions by hydrocarbons and H2O. We have observed a noticeable reduction in the standard SCR reaction efficiency at low temperature with increasing water content. We observed a similar effect when hydrocarbons are present in the stream. This effect is absent under fast SCR conditions where NO ~ NO2 in the feed gas. As a first step in understanding the effects of such inhibition on SCR reaction steps, kinetic models that predict the inhibition behavior of H2O and hydrocarbons on NO oxidation are presented in the paper. A one-dimensional SCR model was developed based on conservation of species equations and was coded as a C-language S-function and implemented in Matlab/Simulink environment. NO oxidation and NO2 dissociation kinetics were defined as a function of the respective adsorbates storage in the Fe-zeolite SCR catalyst. The corresponding kinetic models were then validated on temperature ramp tests that showed good match with the test data. Such inhibition models will improve the accuracy of model based control design for integrated DPF-SCR aftertreatment systems.

  16. Cold-Start Emissions Control in Hybrid Vehicles Equipped with a Passive Hydrocarbon and NOx Adsorber

    SciTech Connect (OSTI)

    Gao, Zhiming; Kim, Miyoung; Choi, Jae-Soon; Daw, C Stuart; Parks, II, James E; Smith, David E

    2012-01-01

    We presents a study of the potential for using low-cost sorbent materials (i.e. Ag-Beta-zeolite and Fe-Mn-Zr transition metal oxides) to temporally trap hydrocarbons (HCs) and nitrogen oxides (NOx) emissions during cold-start periods in HEVs and PHEVs over transient driving cycles. The adsorption behavior of the candidate sorbent materials was characterized in our laboratory flow reactor experiments. The parameters were then used to develop a one-dimensional, transient device model which has been implemented in the Powertrain Systems Analysis Toolkit (PSAT) to simulate a passive HC and NOx absorber device. The results show that such an absorber can substantially reduce HC and NOx emissions by storing them when the 3-way catalyst is too cool to function and re-releasing them when the exhaust temperature rises. These improved emission controls do not involve any penalty in fuel consumption or require any change in engine operation. The cost of these sorbent materials is also much less than conventional 3-way catalysts.

  17. Modeling Species Inhibition of NO oxidation in Urea-SCR Catalysts for Diesel Engine NOx Control

    SciTech Connect (OSTI)

    Devarakonda, Maruthi N.; Tonkyn, Russell G.; Tran, Diana N.; Lee, Jong H.; Herling, Darrell R.

    2010-09-15

    Urea-selective catalytic reduction (SCR) catalysts are regarded as the leading NOx aftertreatment technology to meet the 2010 NOx emission standards for on-highway vehicles running on heavy-duty diesel engines. However, issues such as low NOx conversion at low temperature conditions still exist due to various factors, including incomplete urea thermolysis, inhibition of SCR reactions by hydrocarbons and H2O. We have observed a noticeable reduction in the standard SCR reaction efficiency at low temperature with increasing water content. We observed a similar effect when hydrocarbons are present in the stream. This effect is absent under fast SCR conditions where NO ~ NO2 in the feed gas. As a first step in understanding the effects of such inhibition on SCR reaction steps, kinetic models that predict the inhibition behavior of H2O and hydrocarbons on NO oxidation are presented in the paper. A one-dimensional SCR model was developed based on conservation of species equations and was coded as a C-language S-function and implemented in Matlab/Simulink environment. NO oxidation and NO2 dissociation kinetics were defined as a function of the respective adsorbates storage in the SCR catalyst. The corresponding kinetic models were then validated on temperature ramp tests that showed good match with the test data.

  18. Advanced In-Furnace NOx Control for Wall and Cyclone-Fired Boilers

    SciTech Connect (OSTI)

    Hamid Sarv

    2009-02-28

    A NO{sub x} minimization strategy for coal-burning wall-fired and cyclone boilers was developed that included deep air staging, innovative oxygen use, reburning, and advanced combustion control enhancements. Computational fluid dynamics modeling was applied to refine and select the best arrangements. Pilot-scale tests were conducted by firing an eastern high-volatile bituminous Pittsburgh No.8 coal at 5 million Btu/hr in a facility that was set up with two-level overfire air (OFA) ports. In the wall-fired mode, pulverized coal was burned in a geometrically scaled down version of the B and W DRB-4Z{reg_sign} low-NO{sub x} burner. At a fixed overall excess air level of 17%, NO{sub x} emissions with single-level OFA ports were around 0.32 lb/million Btu at 0.80 burner stoichiometry. Two-level OFA operation lowered the NO{sub x} levels to 0.25 lb/million Btu. Oxygen enrichment in the staged burner reduced the NO{sub x} values to 0.21 lb/million Btu. Oxygen enrichment plus reburning and 2-level OFA operation further curbed the NO{sub x} emissions to 0.19 lb/million Btu or by 41% from conventional air-staged operation with single-level OFA ports. In the cyclone firing arrangement, oxygen enrichment of the cyclone combustor enabled high-temperature and deeply staged operation while maintaining good slag tapping. Firing the Pittsburgh No.8 coal in the optimum arrangement generated 112 ppmv NO{sub x} (0.15 lb/million Btu) and 59 ppmv CO. The optimum emissions results represent 88% NO{sub x} reduction from the uncontrolled operation. Levelized costs for additional NO{sub x} removal by various in-furnace control methods in reference wall-fired or cyclone-fired units already equipped with single-level OFA ports were estimated and compared with figures for SCR systems achieving 0.1 lb NO{sub x}/10{sup 6} Btu. Two-level OFA ports could offer the most economical approach for moderate NO{sub x} control, especially for smaller units. O{sub 2} enrichment in combination with 2-level OFA was not cost effective for wall-firing. For cyclone units, NO{sub x} removal by two-level OFA plus O{sub 2} enrichment but without coal reburning was economically attractive.

  19. Ofloxacin induces apoptosis via ?1 integrin-EGFR-Rac1-Nox2 pathway in microencapsulated chondrocytes

    SciTech Connect (OSTI)

    Sheng, Zhi-Guo; Huang, Wei; Liu, Yu-Xiang; Yuan, Ye; Zhu, Ben-Zhan

    2013-02-15

    Quinolones (QNs)-induced arthropathy is an important toxic side-effect in immature animals leading to the restriction of their therapeutic use in pediatrics. Ofloxacin, a typical QN, was found to induce the chondrocytes apoptosis in the early phase (1248 h) of arthropathy in our previous study. However, the exact mechanism(s) is unclear. Microencapsulated juvenile rabbit joint chondrocytes, a three-dimensional culture system, is utilized to perform the present study. Ofloxacin, at a therapeutically relevant concentration (10 ?g/ml), disturbs the interaction between ?1 integrin and activated intracellular signaling proteins at 12 h, which is inhibited when supplementing Mg{sup 2+}. Intracellular reactive oxygen species (ROS) significantly increases in a time-dependent manner after exposure to ofloxacin for 1248 h. Furthermore, ofloxacin markedly enhances the level of activated Rac1 and epidermal growth factor receptor (EGFR) phosphorylation, and its inhibition in turn reduces the ROS production, apoptosis and Rac1 activation. Silencing Nox2, Rac1 or supplementing Mg{sup 2+} inhibits ROS accumulation, apoptosis occurrence and EGFR phosphorylation induced by ofloxacin. However, depletion of Nox2, Rac1 and inhibition of EGFR do not affect ofloxacin-mediated loss of interaction between ?1 integrin and activated intracellular signaling proteins. In addition, ofloxacin also induces Vav2 phosphorylation, which is markedly suppressed after inactivating EGFR or supplementing Mg{sup 2+}. These results suggest that ofloxacin causes Nox2-mediated intracellular ROS production by disrupting the ?1 integrin function and then activating the EGFR-Vav2-Rac1 pathway, finally resulting in apoptosis within 1248 h exposure. The present study provides a novel insight regarding the potential role of Nox-driven ROS in QNs-induced arthropathy. - Highlights: ? Ofloxacin induces Nox2-driven ROS in encapsulated chondrocyte at 1248 h. ? Ofloxacin stimulates ROS production via the ?1 integrin-EGFR-Vav2-Rac1 pathway. ? Ofloxacin induces ROS-dependent apoptosis in encapsulated chondrocyte at 1248 h.

  20. Device to lower NOx in a gas turbine engine combustion system

    DOE Patents [OSTI]

    Laster, Walter R; Schilp, Reinhard; Wiebe, David J

    2015-02-24

    An emissions control system for a gas turbine engine including a flow-directing structure (24) that delivers combustion gases (22) from a burner (32) to a turbine. The emissions control system includes: a conduit (48) configured to establish fluid communication between compressed air (22) and the combustion gases within the flow-directing structure (24). The compressed air (22) is disposed at a location upstream of a combustor head-end and exhibits an intermediate static pressure less than a static pressure of the combustion gases within the combustor (14). During operation of the gas turbine engine a pressure difference between the intermediate static pressure and a static pressure of the combustion gases within the flow-directing structure (24) is effective to generate a fluid flow through the conduit (48).

  1. Comparison of Methods for Estimating the NOx Emission Impacts of Energy Efficiency and Renewable Energy Projects: Shreveport, Louisiana Case Study (Revised)

    SciTech Connect (OSTI)

    Chambers, A.; Kline, D. M.; Vimmerstedt, L.; Diem, A.; Dismukes, D.; Mesyanzhinov, D.

    2005-07-01

    This is a case study comparing methods of estimating the NOx emission impacts of energy efficiency and renewable energy projects in Shreveport, Louisiana.

  2. Advanced wall-fired boiler combustion techniques for the reduction of nitrogen oxides (NO[sub x]): Low NO[sub x] burner test phase results

    SciTech Connect (OSTI)

    Sorge, J.N. ); Baldwin, A.L. ); Smith, L.L. )

    1992-06-02

    This paper discusses the technical progress of a US Department of Energy Innovative Clean Coal Technology project demonstrating advanced wall-fired combustion techniques for the reduction of nitrogen oxide(NO[sub x]) emissions from coal-fired boilers. The primary objective of the demonstration is to determine the performance of two low NO[sub x] combustion technologies applied in a stepwise fashion to a 500 MW boiler. A target of achieving 50 percent NO[sub x] reductions has been established for the project. The main focus of this paper is the presentation of the low NO[sub x] burner (LNB) short and long-term tests results.

  3. Advanced wall-fired boiler combustion techniques for the reduction of nitrogen oxides (NO{sub x}): Low NO{sub x} burner test phase results

    SciTech Connect (OSTI)

    Sorge, J.N.; Baldwin, A.L.; Smith, L.L.

    1992-06-02

    This paper discusses the technical progress of a US Department of Energy Innovative Clean Coal Technology project demonstrating advanced wall-fired combustion techniques for the reduction of nitrogen oxide(NO{sub x}) emissions from coal-fired boilers. The primary objective of the demonstration is to determine the performance of two low NO{sub x} combustion technologies applied in a stepwise fashion to a 500 MW boiler. A target of achieving 50 percent NO{sub x} reductions has been established for the project. The main focus of this paper is the presentation of the low NO{sub x} burner (LNB) short and long-term tests results.

  4. Method for synthesizing fine-grained phosphor powders of the type (RE.sub.1- Ln.sub.x)(P.sub.1-y V.sub.y)O.sub.4

    DOE Patents [OSTI]

    Phillips, Mark L. F. (83 Lagarto Rd., Tijeras, NM 87059)

    1998-01-01

    A method for generating well-crystallized photo- and cathodoluminescent oxide phosphor powders. The method of this invention uses hydrothermal synthesis and annealing to produce nearly monosized (RE.sub.1-x Ln.sub.x)(P.sub.1-y V.sub.y)O.sub.4 (Ln.dbd.Ce.fwdarw.Lu) phosphor grains with crystallite sizes from 0.04 to 5 .mu.m. Such phosphors find application in cathode-ray tube, flat-panel, and projection displays.

  5. Kinetic and Performance Studies of the Regeneration Phase of Model Pt/Ba/Rh NOx Traps for Design and Optimization

    SciTech Connect (OSTI)

    Michael Harold; Vemuri Balakotaiah

    2010-05-31

    In this project a combined experimental and theoretical approach was taken to advance our understanding of lean NOx trap (LNT) technology. Fundamental kinetics studies were carried out of model LNT catalysts containing variable loadings of precious metals (Pt, Rh), and storage components (BaO, CeO{sub 2}). The Temporal Analysis of Products (TAP) reactor provided transient data under well-characterized conditions for both powder and monolith catalysts, enabling the identification of key reaction pathways and estimation of the corresponding kinetic parameters. The performance of model NOx storage and reduction (NSR) monolith catalysts were evaluated in a bench scale NOx trap using synthetic exhaust, with attention placed on the effect of the pulse timing and composition on the instantaneous and cycle-averaged product distributions. From these experiments we formulated a global model that predicts the main spatio-temporal features of the LNT and a mechanistic-based microkinetic models that incorporates a detailed understanding of the chemistry and predicts more detailed selectivity features of the LNT. The NOx trap models were used to determine its ability to simulate bench-scale data and ultimately to evaluate alternative LNT designs and operating strategies. The four-year project led to the training of several doctoral students and the dissemination of the findings as 47 presentations in conferences, catalysis societies, and academic departments as well 23 manuscripts in peer-reviewed journals. A condensed review of NOx storage and reduction was published in an encyclopedia of technology.

  6. UTILIZING WATER EMULSIFICATION TO REDUCE NOX AND PARTICULATE EMISSIONS ASSOCIATED WITH BIODIESEL

    SciTech Connect (OSTI)

    Kass, Michael D; Lewis Sr, Samuel Arthur; Lee, Doh-Won; Huff, Shean P; Storey, John Morse; Swartz, Matthew M; Wagner, Robert M

    2009-01-01

    A key barrier limiting extended utilization of biodiesel is higher NOx emissions compared to petrodiesel fuels. The reason for this effect is unclear, but various researchers have attributed this phenomena to the higher liquid bulk modulus associated with biodiesel and the additional heat released during the breaking of C-C double bonds in the methyl ester groups. In this study water was incorporated into neat biodiesel (B100) as an emulsion in an attempt to lower NOx and particulate matter (PM) emissions. A biodiesel emulsion containing 10wt% water was formulated and evaluated against an ultra-low sulfur petroleum diesel (ULSD) and neat biodiesel (B100) in a light-duty diesel engine operated at 1500RPM and at loads of 68Nm (50ft-lbs) and 102Nm (75ft-lbs). The influence of exhaust gas recirculation (EGR) was also examined. The incorporation of water was found to significantly lower the NOx emissions of B100, while maintaining fuel efficiency when operating at 0 and 27% EGR. The soot fraction of the particulates (as determined using an opacity meter) was much lower for the B100 and B100-water emulsion compared ULSD. In contrast, total PM mass (for the three fuel types) was unchanged for the 0% EGR condition but was significantly lower for the B100 and B100-emulsion during the 27% EGR condition compared to the ULSD fuel. Analysis of the emissions and heat release data indicate that water enhances air-fuel premixing to maintain fuel economy and lower soot formation. The exhaust chemistry of the biodiesel base fuels (B100 and water-emulsified B100) was found to be unique in that they contained measurable levels of methyl alkenoates, which were not found for the ULSD. These compounds were formed by the partial cracking of the methyl ester groups during combustion.

  7. Fuel NOx production during the combustion of low caloric value fuel

    SciTech Connect (OSTI)

    Colaluca, M.A.; Caraway, J.P.

    1997-07-01

    The objective of this investigation is to identify and qualify physical mechanisms and parameters that affect the combustion of low caloric value gases (LCVG) and the formation of NOx pollutants produced form fuel bound nitrogen. Average physical properties of a low caloric value gas were determined from the products of several industrial coal gasifiers. A computer model was developed, utilizing the PHOENICS computational fluid dynamics software to model the combustion of LCVG. The model incorporates a 3-dimensional physical design and is based on typical industrial combustors. Feed stock to the gasifier can be wood, feed stock manure, cotton gin trash, coal, lignite and numerous forms of organic industrial wastes.

  8. Retrofit costs for SO sub 2 and NOx control options at 200 coal-fired plants

    SciTech Connect (OSTI)

    Not Available

    1990-11-01

    This 5-volume report gives the results of site-specific cost estimations for retrofitting six control technologies to coal-fired power plants. The six technologies were: lime/limestone flue gas desulfurization, lime spray drying, coal switching and cleaning, furnace and duct sorbent injection, low NOx combustion or natural gas reburning, and selective catalytic reduction. Volume 1 gives the methodology. The other four volumes each cover 5-7 specific states east of the Mississippi River. Maine, Vermont, Rhode Island, and Connecticut are not included.

  9. SO{sub 2} and NOx trading markets: providing flexibility and results

    SciTech Connect (OSTI)

    Sam Napolitano; Melanie LaCount; Daniel Chartier

    2007-06-15

    Experience with the Acid Rain and NOx Budget Trading Programs demonstrates that cap-and-trade programs are an effective means of achieving broad improvements in air quality. Results demonstrate that the combination of mandatory emissions caps, a viable allowance trading market, rigorous emissions monitoring and reporting protocols, and automatic enforcement provide accountability and ensure results in a cost-effective manner. The market developments discussed in this article demonstrate a successful environmental partnership. With a government focused on results and a private sector motivated to innovate, cap-and trade systems deliver environmental results as efficiently and effectively as possible. 3 refs., 4 figs,

  10. CO-FIRING COAL: FEEDLOT AND LITTER BIOMASS (CFB AND CLB) FUELS IN PULVERIZED FUEL AND FIXED BED BURNERS

    SciTech Connect (OSTI)

    Kalyan Annamalai; John Sweeten; Saqib Mukhtar; Ben Thein; Gengsheng Wei; Soyuz Priyadarsan; Senthil Arumugam; Kevin Heflin

    2003-08-28

    Intensive animal feeding operations create large amounts of animal waste that must be safely disposed of in order to avoid environmental degradation. Cattle feedlots and chicken houses are two examples. In feedlots, cattle are confined to small pens and fed a high calorie grain-diet diet in preparation for slaughter. In chicken houses, thousands of chickens are kept in close proximity. In both of these operations, millions of tons of manure are produced every year. The manure could be used as a fuel by mixing it with coal in a 90:10 blend and firing it in an existing coal suspension fired combustion systems. This technique is known as co-firing, and the high temperatures produced by the coal will allow the biomass to be completely combusted. Reburn is a process where a small percentage of fuel called reburn fuel is injected above the NO{sub x} producing, conventional coal fired burners in order to reduce NO{sub x}. The manure could also be used as reburn fuel for reducing NO{sub x} in coal fired plants. An alternate approach of using animal waste is to adopt the gasification process using a fixed bed gasifier and then use the gases for firing in gas turbine combustors. In this report, the cattle manure is referred to as feedlot biomass (FB) and chicken manure as litter biomass (LB). The report generates data on FB and LB fuel characteristics. Co-firing, reburn, and gasification tests of coal, FB, LB, coal: FB blends, and coal: LB blends and modeling on cofiring, reburn systems and economics of use of FB and LB have also been conducted. The biomass fuels are higher in ash, lower in heat content, higher in moisture, and higher in nitrogen and sulfur (which can cause air pollution) compared to coal. Small-scale cofiring experiments revealed that the biomass blends can be successfully fired, and NO{sub x} emissions will be similar to or lower than pollutant emissions when firing coal. Further experiments showed that biomass is twice or more effective than coal when used in a reburning process. Computer simulations for coal: LB blends were performed by modifying an existing computer code to include the drying and phosphorus (P) oxidation models. The gasification studies revealed that there is bed agglomeration in the case of chicken litter biomass due to its higher alkaline oxide content in the ash. Finally, the results of the economic analysis show that considerable fuel cost savings can be achieved with the use of biomass. In the case of higher ash and moisture biomass, the fuel cost savings is reduced.

  11. Nitrogen and hydrogen CARS temperature measurements in a hydrogen/air flame using a near-adiabatic flat-flame burner

    SciTech Connect (OSTI)

    Hancock, R.D.; Bertagnolli, K.E.; Lucht, R.P.

    1997-05-01

    Coherent anti-Stokes Raman scattering (CARS) spectroscopy of diatomic nitrogen and hydrogen was used to measure flame temperatures in hydrogen/air flames produced using a nonpremixed, near-adiabatic, flat-flame Hencken burner. The CARS temperature measurements are compared with adiabatic flame temperatures calculated by the NASA-Lewis equilibrium code for equivalence ratios from 0.5--2.5. The nitrogen CARS temperatures are in excellent agreement with the equilibrium code calculations. Comparison of nitrogen CARS data and the equilibrium code calculations confirms that for sufficiently high flow rates the Hencken burner produces nearly adiabatic flames. Hydrogen CARS temperature measurements are compared to both nitrogen CARS temperature measurements and equilibrium code predictions in order to evaluate and improve the accuracy of hydrogen CARS as a temperature diagnostic tool. Hydrogen CARS temperatures for fuel-rich flames are on average 70 K ({approximately}3%) above the equilibrium code predictions and nitrogen CARS temperatures. The difference between temperatures measured using hydrogen and nitrogen CARS is probably due primarily to uncertainties in hydrogen linewidths and line-broadening mechanisms at these conditions.

  12. Experimental and numerical study of the accuracy of flame-speed measurements for methane/air combustion in a slot burner

    SciTech Connect (OSTI)

    Selle, L.; Ferret, B. [Universite de Toulouse, INPT, UPS, IMFT, Institut de Mecanique des Fluides de Toulouse (France); CNRS, IMFT, Toulouse (France); Poinsot, T. [Universite de Toulouse, INPT, UPS, IMFT, Institut de Mecanique des Fluides de Toulouse (France); CNRS, IMFT, Toulouse (France); CERFACS, Toulouse (France)

    2011-01-15

    Measuring the velocities of premixed laminar flames with precision remains a controversial issue in the combustion community. This paper studies the accuracy of such measurements in two-dimensional slot burners and shows that while methane/air flame speeds can be measured with reasonable accuracy, the method may lack precision for other mixtures such as hydrogen/air. Curvature at the flame tip, strain on the flame sides and local quenching at the flame base can modify local flame speeds and require corrections which are studied using two-dimensional DNS. Numerical simulations also provide stretch, displacement and consumption flame speeds along the flame front. For methane/air flames, DNS show that the local stretch remains small so that the local consumption speed is very close to the unstretched premixed flame speed. The only correction needed to correctly predict flame speeds in this case is due to the finite aspect ratio of the slot used to inject the premixed gases which induces a flow acceleration in the measurement region (this correction can be evaluated from velocity measurement in the slot section or from an analytical solution). The method is applied to methane/air flames with and without water addition and results are compared to experimental data found in the literature. The paper then discusses the limitations of the slot-burner method to measure flame speeds for other mixtures and shows that it is not well adapted to mixtures with a Lewis number far from unity, such as hydrogen/air flames. (author)

  13. Monodisperse and core-shell structured SiO{sub 2}-Lu{sub 2}O{sub 3}:Ln{sup 3+} (Ln=Eu, Tb, Dy, Sm, Er, Ho, and Tm) spherical particles: A facile synthesis and luminescent properties

    SciTech Connect (OSTI)

    Xu, Zhenhe; Feng, Bin; Bian, Shasha; Liu, Tao; Wang, Mingli; Gao, Yu; Sun, Di; Gao, Xin; Sun, Yaguang

    2012-12-15

    The core-shell structured SiO{sub 2}-Lu{sub 2}O{sub 3}:Ln{sup 3+} particles were realized by coating the Lu{sub 2}O{sub 3}:Ln{sup 3+} phosphors onto the surface of non-aggregated, monodisperse and spherical SiO{sub 2} particles by the Pechini sol-gel method. The as-synthesized products were characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), energy-dispersive X-ray (EDX) spectra, scanning electron microscopy (SEM), transmission electron microscopy (TEM), high-resolution transmission electron microscopy (HRTEM), photolumiminescence (PL), and low-voltage cathodoluminescence (CL). The results indicate that the 800 Degree-Sign C annealed sample consists of crystalline Lu{sub 2}O{sub 3} shells and amorphous SiO{sub 2} cores, in spherical shape with a narrow size distribution. The as-obtained particles show strong light emission with different colors corresponding to different Ln{sup 3+} ions under ultraviolet-visible light excitation and low-voltage electron beams excitation, which have potential applications in fluorescent lamps and field emission displays. - Graphical Abstract: Representative SEM and TEM images of the core-shell structured SiO{sub 2}-Lu{sub 2}O{sub 3}:Eu{sup 3+} particles; CIE chromaticity diagram showing the emission colors for SiO{sub 2}-Lu{sub 2}O{sub 3}:Ln{sup 3+}; Multicolor emissions of SiO{sub 2}-Lu{sub 2}O{sub 3}:Ln{sup 3+} particles. Highlights: Black-Right-Pointing-Pointer The core-shell particles were realized by coating the phosphors onto the surface of SiO{sub 2} particles. Black-Right-Pointing-Pointer The sample consists of crystalline Lu{sub 2}O{sub 3} shells and amorphous SiO{sub 2} cores. Black-Right-Pointing-Pointer The particles show different light emission colors corresponding to Ln{sup 3+} ions. Black-Right-Pointing-Pointer They have potential applications in fluorescent lamps and field emission displays.

  14. Application of hybrid coal reburning/SNCR processes for NOx reduction in a coal-fired boiler

    SciTech Connect (OSTI)

    Yang, W.J.; Zhou, Z.J.; Zhou, J.H.; Hongkun, L.V.; Liu, J.Z.; Cen, K.F.

    2009-07-01

    Boilers in Beijing Thermal Power Plant of Zhongdian Guohua Co. in China are coal-fired with natural circulation and tangential fired method, and the economical continuous rate is 410 ton per hour of steam. Hybrid coal reburning/SNCR technology was applied and it successfully reduced NOx to about 170 mg/Nm{sup 3} from about 540 mg/Nm{sup 3}, meanwhile ammonia slip was lower than 10 ppm at 450-210 t/h load and the total reduction efficiency was about 70%. Normal fineness pulverized coal from the bin was chosen as the reburning fuel and the nozzles of the upper primary air were retrofitted to be used as the reburning fuel nozzles. The reducing agent of SNCR was an urea solution, and it was injected by the four layer injectors after online dilution. At 410 t/h load, NOx emission was about 300 mg/Nm{sup 3} when the ratio of reburning fuel to the total fuel was 25.9%-33.4%. Controlling the oxygen content of the gas in the reversal chamber to less than 3.4% resulted in not only low NOx emission but also high combustion efficiency. Ammonia slip distribution in the down gas pass was uneven and ammonia slip was higher in the front of the down gas pass than in the rear of the down gas pass. NSR and NOx reduction were proportional to each other and usually resulted in more ammonia slip with reduction in NOx. About 100 mg/Nm{sup 3} NOx emission could be achieved with about 40 ppm NH{sub 3} slip at 300-450 t/h, and ammonia slip from the SNCR reactions could be used as reducing agent of SCR, which was favorable for the future SCR retrofit.

  15. Anthropogenic emissions of NOx over China: Reconciling the difference of inverse modeling results using GOME-2 and OMI measurements

    SciTech Connect (OSTI)

    Gu, Dasa; Wang, Yuhang; Smeltzer, Charles; Boersma, K. Folkert

    2014-06-27

    Inverse modeling using satellite observations of nitrogen dioxide (NO2) columns has been extensively used to estimate nitrogen oxides (NOx) emissions in China. Recently, the Global Ozone Monitoring Experiment-2 (GOME-2) and Ozone Monitoring Instrument (OMI) provide independent global NO2 column measurements on a nearly daily basis at around 9:30 and 13:30 local time across the equator, respectively. Anthropogenic NOx emission estimates by applying previously developed monthly inversion (MI) or daily inversion (DI) methods to these two sets of measurements show substantial differences. We improve the DI method by conducting model simulation, satellite retrieval, and inverse modeling sequentially on a daily basis. After each inversion, we update anthropogenic NOx emissions in the model simulation with the newly obtained a posteriori results. Consequently, the inversion-optimized emissions are used to compute the a priori NO2 profiles for satellite retrievals. As such, the a priori profiles used in satellite retrievals are now coupled to inverse modeling results. The improved procedure was applied to GOME-2 and OMI NO2 measurements in 2011. The new daily retrieval-inversion (DRI) method estimates an average NOx emission of 6.9 Tg N/yr over China, and the difference between using GOME-2 and OMI measurements is 0.4 Tg N/yr, which is significantly smaller than the difference of 1.3 Tg N/yr using the previous DI method. Using the more consistent DRI inversion results, we find that anthropogenic NOx emissions tend to be higher in winter and summer than spring (and possibly fall) and the weekday-to-weekend emission ratio tends to increase with NOx emission in China.

  16. NOx Emission Reduction and its Effects on Ozone during the 2008 Olympic Games

    SciTech Connect (OSTI)

    Yang, Qing; Wang, Yuhang; Zhao, Chun; Liu, Zhen; Gustafson, William I.; Shao, Min

    2011-07-15

    We applied a daily-assimilated inversion method to estimate NOx (NO+NO2) emissions for June-September 2007 and 2008 on the basis of the Aura Ozone Monitoring Instrument (OMI) observations of nitrogen dioxide (NO2) and model simulations using the Regional chEmistry and trAnsport Model (REAM). Over urban Beijing, rural Beijing, and the Huabei Plain, OMI column NO2 reductions are approximately 45%, 33%, and 14%, respectively, while the corresponding anthropogenic NOx emission reductions are only 28%, 24%, and 6%, during the full emission control period (July 20 Sep 20, 2008). The emission reduction began in early July and was in full force by July 20, corresponding to the scheduled implementation of emission controls over Beijing. The emissions did not appear to recover after the emission control period. Meteorological change from summer 2007 to 2008 is the main factor contributing to the column NO2 decreases not accounted for by the emission reduction. Model simulations suggest that the effect of emission reduction on ozone concentrations over Beijing is relatively minor using a standard VOC emission inventory in China. With an adjustment of the model emissions to reflect in situ observations of VOCs in Beijing, the model simulation suggests a larger effect of the emission reduction.

  17. Agricultural Bio-Fueled Generation of Electricity and Development of Durable and Efficent NOx Reduction

    SciTech Connect (OSTI)

    Boyd, Rodney

    2007-08-08

    The objective of this project was to define the scope and cost of a technology research and development program that will demonstrate the feasibility of using an off-the-shelf, unmodified, large bore diesel powered generator in a grid-connected application, utilizing various blends of BioDiesel as fuel. Furthermore, the objective of project was to develop an emissions control device that uses a catalytic process and BioDiesel (without the presence of Ammonia or Urea)to reduce NOx and other pollutants present in a reciprocating engine exhaust stream with the goal of redefining the highest emission reduction efficiencies possible for a diesel reciprocating generator. Process: Caterpillar Power Generation adapted an off-the-shelf Diesel Generator to run on BioDiesel and various Petroleum Diesel/BioDiesel blends. EmeraChem developed and installed an exhaust gas cleanup system to reduce NOx, SOx, volatile organics, and particulates. The system design and function was optimized for emissions reduction with results in the 90-95% range;

  18. APBF-DEC NOx Adsorber/DPF Project: Light-Duty Passenger Car Platform

    SciTech Connect (OSTI)

    Tomazic, D; Tatur, M; Thornton, M

    2003-08-24

    A 1.9L turbo direct injection (TDI) diesel engine was modified to achieve the upcoming Tier 2 Bin 5 emission standard in combination with a NOx adsorber catalyst (NAC) and a diesel particulate filter (DPF). The primary objective for developing this test bed is to investigating the effects of different fuel sulfur contents on the performance of an advanced emission control system (ECS) in a light-duty application. During the development process, the engine-out emissions were minimized by applying a state-of-the-art combustion system in combination with cooled exhaust gas recirculation (EGR). The subsequent calibration effort resulted in emission levels requiring 80-90 percent nitrogen-oxide (NOx) and particulate matter (PM) conversion rates by the corresponding ECS. The strategy development included ean/rich modulation for NAC regeneration, as well as, the desulfurization of the NAC and the regeneration of the DPF. Two slightly different ECS were investigated and calibrated. The initial vehicle results in an Audi A4 station wagon over the federal test procedure (FTP), US 06, and the highway fuel economy test (HFET) cycle indicate the potential of these configuration to meet the future Tier 2 emission standard.

  19. Pyrolysis with cyclone burner

    DOE Patents [OSTI]

    Green, Norman W.; Duraiswamy, Kandaswamy; Lumpkin, Robert E.

    1978-07-25

    In a continuous process for recovery of values contained in a solid carbonaceous material, the carbonaceous material is comminuted and then subjected to flash pyrolysis in the presence of a particulate heat source over an overflow weir to form a pyrolysis product stream containing a carbon containing solid residue and volatilized hydrocarbons. After the carbon containing solid residue is separated from the pyrolysis product stream, values are obtained by condensing volatilized hydrocarbons. The particulate source of heat is formed by oxidizing carbon in the solid residue and separating out the fines.

  20. Enhanced control of fine particles following Title IV coal switching and NOx control

    SciTech Connect (OSTI)

    Durham, M.D.; Baldrey, K.E.; Bustard, C.J.; Martin, C.

    1997-12-31

    Electrostatic precipitators (ESPs) serve as the primary particle control devices for a majority of coal-fired power generating units in the United States. ESPs are used to collect particulate matter that range in size from less than one micrometer in diameter to several hundred micrometers. Many of the options that utilities will use to respond to Title IV of the 1990 Clean Air Act Amendments will result in changes to the ash that will be detrimental to the performance of the ESP causing increased emissions of fine particles and higher opacity. For example, a switch to low-sulfur coal significantly increases particle resistivity while low-NO{sub x} burners increase the carbon content of ashes. Both of these changes could result in derating of the boiler to comply with emissions standards. ADA has developed a chemical additive that is designed to improve the operation of ESI`s to bring these systems into compliance operation without the need for expensive capital modifications. The additives provide advantages over competing technologies in terms of low capital cost, easy to handle chemicals, and relatively non-toxic chemicals. In addition, the new additive is insensitive to ash chemistry which will allow the utility complete flexibility to select the most economical coal. Results from full-scale and pilot plant demonstrations are reported.

  1. Analysis of Strategies for Multiple Emissions from Electric Power SO2, NOX, CO2, Mercury and RPS

    Reports and Publications (EIA)

    2001-01-01

    At the request of the Subcommittee, the Energy Information Administration prepared an initial report that focused on the impacts of reducing power sector NOx, SO2, and CO2 emissions. The current report extends the earlier analysis to add the impacts of reducing power sector mercury emissions and introducing renewable portfolio standard (RPS) requirements.

  2. bectno-evgreb | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Evaluation of Gas Reburning and Low-NOx Burners on a Wall-Fired Boiler - Project Brief [PDF-252KB] Energy and Environmental Research Corp., Denver, CO PROGRAM PUBLICATIONS Final Reports Evaluation of Gas Reburning and Low NOx Burners on a Wall-Fired Boiler: Performance and Economics Report, Gas Reburning-Low NOx Burner System, Cherokee Station Unit No. 3, Final Report [PDF-17.2MB] (July 1998) CCT Reports: Project Performance Summaries, Post-Project Assessments, & Topical Reports Evaluation

  3. bib-sunflower | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Integration of Low-NOx Burners with an Optimization Plan for Boiler Combustion - Project Brief [PDF-72KB] (Withdrawn) Sunflower Electric Power Corp., Garden City, Finney County, KS PROJECT FACT SHEET Achieving New Source Performance Standards (NSPS) Through Integration of Low-NOx Burners with an Optimization Plan for Boiler Combustion [PDF-260KB] (Oct 2008) PROGRAM PUBLICATIONS Final Report Achieving NSPS Emission Standards Through Integration of Low NOx Burners with an Optimization Plan for

  4. Vortex combustor for low NOx emissions when burning lean premixed high hydrogen content fuel

    DOE Patents [OSTI]

    Steele, Robert C. (Woodinville, WA); Edmonds, Ryan G. (Renton, WA); Williams, Joseph T. (Kirkland, WA); Baldwin, Stephen P. (Winchester, MA)

    2009-10-20

    A trapped vortex combustor. The trapped vortex combustor is configured for receiving a lean premixed gaseous fuel and oxidant stream, where the fuel includes hydrogen gas. The trapped vortex combustor is configured to receive the lean premixed fuel and oxidant stream at a velocity which significantly exceeds combustion flame speed in a selected lean premixed fuel and oxidant mixture. The combustor is configured to operate at relatively high bulk fluid velocities while maintaining stable combustion, and low NOx emissions. The combustor is useful in gas turbines in a process of burning synfuels, as it offers the opportunity to avoid use of diluent gas to reduce combustion temperatures. The combustor also offers the possibility of avoiding the use of selected catalytic reaction units for removal of oxides of nitrogen from combustion gases exiting a gas turbine.

  5. Vortex combustor for low NOX emissions when burning lean premixed high hydrogen content fuel

    DOE Patents [OSTI]

    Steele, Robert C; Edmonds, Ryan G; Williams, Joseph T; Baldwin, Stephen P

    2012-11-20

    A trapped vortex combustor. The trapped vortex combustor is configured for receiving a lean premixed gaseous fuel and oxidant stream, where the fuel includes hydrogen gas. The trapped vortex combustor is configured to receive the lean premixed fuel and oxidant stream at a velocity which significantly exceeds combustion flame speed in a selected lean premixed fuel and oxidant mixture. The combustor is configured to operate at relatively high bulk fluid velocities while maintaining stable combustion, and low NOx emissions. The combustor is useful in gas turbines in a process of burning synfuels, as it offers the opportunity to avoid use of diluent gas to reduce combustion temperatures. The combustor also offers the possibility of avoiding the use of selected catalytic reaction units for removal of oxides of nitrogen from combustion gases exiting a gas turbine.

  6. Titanium subhydride potassium perchlorate (TiH1.65/KClO4) burn rates from hybrid closed bomb-strand burner experiments.

    SciTech Connect (OSTI)

    Cooper, Marcia A.; Oliver, Michael S.

    2012-08-01

    A hybrid closed bomb-strand burner is used to measure the burning behavior of the titanium subhydride potassium perchlorate pyrotechnic with an equivalent hydrogen concentration of 1.65. This experimental facility allows for simultaneous measurement of the closed bomb pressure rise and pyrotechnic burn rate as detected by electrical break wires over a range of pressures. Strands were formed by pressing the pyrotechnic powders to bulk densities between 60% and 90% theoretical maximum density. The burn rate dependance on initial density and vessel pressure are measured. At all initial strand densities, the burn is observed to transition from conductive to convective burning within the strand. The measured vessel pressure history is further analyzed following the closed bomb analysis methods developed for solid propellants.

  7. Formation of NOx precursors during Chinese pulverized coal pyrolysis in an arc plasma jet

    SciTech Connect (OSTI)

    Wei-ren Bao; Jin-cao Zhang; Fan Li; Li-ping Chang

    2007-08-15

    The formation of NOx precursors (HCN and NH{sub 3}) from the pyrolysis of several Chinese pulverized coals in an arc plasma jet was investigated through both thermodynamic analysis of the C-H-O-N system and experiments. Results of thermodynamic analysis show that the dominant N-containing gaseous species is HCN together with a small amount of ammonia above the temperature of 2000 K. The increase of H content advances the formation of HCN and NH{sub 3}, but the yields of HCN and NH{sub 3} are decreased with a high concentration of O in the system. These results are accordant with the experimental data. The increasing of input power promotes the formation of HCN and NH{sub 3} from coal pyrolysis in an arc plasma jet. Tar-N is not formed during the process. The yield of HCN changes insignificantly with the changing of the residence time of coal particles in the reactor, but that of NH{sub 3} decreases as residence times increase because of the relative instability at high temperature. Adsorption and gasification of CO{sub 2} on the coal surface also can restrain the formation of HCN and NH{sub 3} compare to the results in an Ar plasma jet. Yields of HCN and NH{sub 3} are sensitive to the coal feeding rate, indicating that NOx precursors could interact with the nascent char to form other N-containing species. The formation of HCN and NH{sub 3} during coal pyrolysis in a H{sub 2}/Ar plasma jet are not dependent on coal rank. The N-containing gaseous species is released faster than others in the volatiles during coal pyrolysis in an arc plasma jet, and the final nitrogen content in the char is lower than that in the parent coal, which it is independent of coal type. 16 refs., 9 figs., 1 tab.

  8. Effect of B20 and Low Aromatic Diesel on Transit Bus NOx Emissions Over Driving Cycles with a Range of Kinetic Intensity

    SciTech Connect (OSTI)

    Lammert, M. P.; McCormick, R. L.; Sindler, P.; Williams, A.

    2012-10-01

    Oxides of nitrogen (NOx) emissions for transit buses for up to five different fuels and three standard transit duty cycles were compared to establish whether there is a real-world biodiesel NOx increase for transit bus duty cycles and engine calibrations. Six buses representing the majority of the current national transit fleet and including hybrid and selective catalyst reduction systems were tested on a heavy-duty chassis dynamometer with certification diesel, certification B20 blend, low aromatic (California Air Resources Board) diesel, low aromatic B20 blend, and B100 fuels over the Manhattan, Orange County and UDDS test cycles. Engine emissions certification level had the dominant effect on NOx; kinetic intensity was the secondary driving factor. The biodiesel effect on NOx emissions was not statistically significant for most buses and duty cycles for blends with certification diesel, except for a 2008 model year bus. CARB fuel had many more instances of a statistically significant effect of reducing NOx. SCR systems proved effective at reducing NOx to near the detection limit on all duty cycles and fuels, including B100. While offering a fuel economy benefit, a hybrid system significantly increased NOx emissions over a same year bus with a conventional drivetrain and the same engine.

  9. Bis-diglycol-amides (Bis-DGA) as new extractants for An(III) and Ln(III) from aqueous high-level wastes issued from the Purex process

    SciTech Connect (OSTI)

    Espartero, A.G.; Murillo, M.T.; Almaraz, M.; Sanchez-Quesada, J.; Iglesias-Sanchez, J.C.; Prados, P.; Segura, M.; Mendoza, J. de

    2008-07-01

    A new family of compounds with two diglycolamide moieties in their molecule have been synthesized and studied as suitable extractants for trivalent actinides (An(III)) and trivalent lanthanides (Ln(III)) present in high-level wastes (HLW) issued from the PUREX process. Although the obtained distribution ratios are comparable with those from TODGA under similar experimental conditions, the bis-DGA compounds showed higher selectivity towards Ln(III). The number of bis-DGA molecules involved in the formation of the dominant complex is two, and it is possible to recover more than 99% of the extracted An and Ln with 0.01 M nitric acid in order to recycle the solvent in subsequent extraction cycles. (authors)

  10. bectcom-new | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Low-NOx/SOx Burner Retrofit for Utility Cyclone Boilers - Project Brief not available (Withdrawn) TransAlta Technologies, Inc., Los Angeles, CA Design Reports Low NOx/SOx Burner Retrofit for Utility Cyclone Boilers: Public Design Report [PDF-5.8MB] (Sept 1991) Interim Reports Low NOx/SOx Burner Retrofit for Utility Cyclone Boilers, Baseline Test Report [PDF-1.6MB] (May 1991) Low NOx/SOx Burner Retrofit for Utility Cyclone Boilers, Topical Report, Termination of LNSB Cyclone Retrofit Project

  11. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... Prototype evaluation of commercial second-generation low-NOx burner performance and sulfur dioxide capture potential. Final report, March 1983-June 1984 Abele, A. ; Jones, F. ; ...

  12. EA-1472: Finding of No Significant Impact

    Broader source: Energy.gov [DOE]

    Commercial Demonstration fo the Low Nox Burner/Separated Over-Fire Air (LNB/SOFA) Integration System Emission Reduction Technology, Holcolm Station, Sunflower Electric Power Corporation Finnety...

  13. Method for synthesizing fine-grained phosphor powders of the type (RE{sub 1{minus}x}Ln{sub x})(P{sub 1{minus}y}V{sub y})O{sub 4}

    DOE Patents [OSTI]

    Phillips, M.L.F.

    1998-04-28

    A method for generating well-crystallized photo- and cathodoluminescent oxide phosphor powders is disclosed. The method of this invention uses hydrothermal synthesis and annealing to produce nearly monosized (RE{sub 1{minus}x}Ln{sub x})(P{sub 1{minus}y}V{sub y}O{sub 4}) (Ln{double_bond}Ce{yields}Lu) phosphor grains with crystallite sizes from 0.04 to 5 {micro}m. Such phosphors find application in cathode-ray tube, flat-panel, and projection displays. 4 figs.

  14. APBF-DEC NOx Adsorber/DPF Project: SUV / Pick-up Truck Platform

    SciTech Connect (OSTI)

    Webb, C; Weber, P; Thornton,M

    2003-08-24

    The objective of this project is to determine the influence of diesel fuel composition on the ability of NOX adsorber catalyst (NAC) technology, in conjunction with diesel particle filters (DPFs), to achieve stringent emissions levels with a minimal fuel economy impact. The test bed for this project was intended to be a light-duty sport utility vehicle (SUV) with a goal of achieving light-duty Tier 2-Bin 5 tail pipe emission levels (0.07 g/mi. NOX and 0.01 g/mi. PM). However, with the current US market share of light-duty diesel applications being so low, no US 2002 model year (MY) light-duty truck (LDT) or SUV platforms equipped with a diesel engine and having a gross vehicle weight rating (GVWR) less than 8500 lb exist. While the current level of diesel engine use is relatively small in the light-duty class, there exists considerable potential for the diesel engine to gain a much larger market share in the future as manufacturers of heavy light-duty trucks (HLDTs) attempt to offset the negative impact on cooperate average fuel economy (CAFE) that the recent rise in market share of the SUVs and LDTs has caused. The US EPA Tier 2 emission standards also contain regulation to prevent the migration of heavy light-duty trucks and SUV's to the medium duty class. This preventive measure requires that all medium duty trucks, SUV's and vans in the 8,500 to 10,000 lb GVWR range being used as passenger vehicles, meet light-duty Tier 2 standards. In meeting the Tier 2 emission standards, the HLDTs and medium-duty passenger vehicles (MDPVs) will face the greatest technological challenges. Because the MDPV is the closest weight class and application relative to the potential upcoming HLDTs and SUV's, a weight class compromise was made in this program to allow the examination of using a diesel engine with a NAC-DPF system on a 2002 production vehicle. The test bed for this project is a 2500 series Chevrolet Silverado equipped with a 6.6L Duramax diesel engine certified to 2002 MY Federal heavy-duty and 2002 MY California medium-duty emission standards. The stock vehicle included cooled air charge (CAC), turbocharger (TC), direct fuel injection (DFI), oxidation catalyst (OC), and exhaust gas recirculation (EGR)

  15. Selective catalytic reduction system and process for treating NOx emissions using a palladium and rhodium or ruthenium catalyst

    DOE Patents [OSTI]

    Sobolevskiy, Anatoly (Orlando, FL); Rossin, Joseph A. (Columbus, OH); Knapke, Michael J. (Columbus, OH)

    2011-07-12

    A process for the catalytic reduction of nitrogen oxides (NOx) in a gas stream (29) in the presence of H.sub.2 is provided. The process comprises contacting the gas stream with a catalyst system (38) comprising zirconia-silica washcoat particles (41), a pre-sulfated zirconia binder (44), and a catalyst combination (40) comprising palladium and at least one of rhodium, ruthenium, or a mixture of ruthenium and rhodium.

  16. PASSIVE CONTROL OF PARTICLE DISPERSION IN A PARTICLE-LADEN CIRCULAR JET USING ELLIPTIC CO-ANNULAR FLOW: A MEANS FOR IMPROVING UTILIZATION AND EMISSION REDUCTIONS IN PULVERIZED COAL BURNER

    SciTech Connect (OSTI)

    Ahsan R. Choudhuri

    2003-06-01

    A passive control technology utilizing elliptic co-flow to control the particle flinging and particle dispersion in a particle (coal)-laden flow was investigated using experimental and numerical techniques. Preferential concentration of particles occurs in particle-laden jets used in pulverized coal burner and causes uncontrollable NO{sub x} formation due to inhomogeneous local stoichiometry. This particular project was aimed at characterizing the near-field flow behavior of elliptic coaxial jets. The knowledge gained from the project will serve as the basis of further investigation on fluid-particle interactions in an asymmetric coaxial jet flow-field and thus is important to improve the design of pulverized coal burners where non-homogeneity of particle concentration causes increased NO{sub x} formation.

  17. Low Temperature Combustion using nitrogen enrichment to mitigate nox from large bore natural gas-filled engines.

    SciTech Connect (OSTI)

    Biruduganti, M. S.; Gupta, S. B.; Sekar, R. R.

    2008-01-01

    Low Temperature Combustion (LTC) is identified as one of the pathways to meet the mandatory ultra low NOx emissions levels set by regulatory agencies. This phenomenon can be realized by utilizing various advanced combustion control strategies. The present work discusses nitrogen enrichment using an Air Separation Membrane (ASM) as a better alternative to the mature Exhaust Gas Re-circulation (EGR) technique currently in use. A 70% NOx reduction was realized with a moderate 2% nitrogen enrichment while maintaining power density and simultaneously improving Fuel Conversion Efficiency (FCE). The maximum acceptable Nitrogen Enriched Air (NEA) in a single cylinder spark ignited natural gas engine was investigated in this paper. Any enrichment beyond this level degraded engine performance both in terms of power density and FCE, and unburned hydrocarbon (UHC) emissions. The effect of ignition timing was also studied with and without N2 enrichment. Finally, lean burn versus stoichiometric operation utilizing NEA was compared. Analysis showed that lean burn operation along with NEA is one of the effective pathways for realizing better FCE and lower NOx emissions.

  18. Economics of pollution trading for SO{sub 2} and NOx

    SciTech Connect (OSTI)

    Dallas Burtraw; David A. Evans; Alan Krupnick; Karen Palmer; Russell Toth

    2005-03-15

    For years economists have urged policymakers to use market-based approaches such as cap-and-trade programs or emission taxes to control pollution. The sulphur dioxide (SO{sub 2}) allowance market created by Title IV of the 1990 US Clean Air Act Amendments represents the first real test of the wisdom of economists' advice. Subsequent urban and regional applications of NOx emission allowance trading took shape in the 1990s in the United States, culminating in a second large experiment in emission trading in the eastern United States that began in 2003. This paper provides an overview of the economic rationale for emission trading and a description of the major US programs for SO{sub 2} and nitrogen oxides. These programs are evaluated along measures of performance including cost savings, environmental integrity, and incentives for technological innovation. The authors offer lessons for the design of future programs including, most importantly, those reducing carbon dioxide. 128 refs., 1 fig., 1 tab.

  19. Integrating low-NO{sub x} burners, overfire air, and selective non-catalytic reduction on a utility coal-fired boiler

    SciTech Connect (OSTI)

    Hunt, T.; Muzio, L.; Smith, R.

    1995-05-01

    Public Service Company of Colorado (PSCo), in cooperation with the US Department of Energy (DOE) and the Electric Power Research Institute (EPRI), is testing the Integrated Dry NO{sub x}/SO{sub 2} Emissions Control system. This system combines low-NO{sub x} burners, overfire air, selective non-catalytic reduction (SNCR), and dry sorbent injection with humidification to reduce by up to 70% both NO{sub x} and SO{sub 2} emissions from a 100 MW coal-fired utility boiler. The project is being conducted at PSCo`s Arapahoe Unit 4 located in Denver, Colorado as part of the DOE`s Clean Coal Technology Round 3 program. The urea-based SNCR system, supplied by Noell, Inc., was installed in late 1991 and was tested with the unmodified boiler in 1992. At full load, it reduced NO{sub x} emissions by about 35% with an associated ammonia slip limit of 10 ppm. Babcock & Wilcox XLS{reg_sign} burners and a dual-zone overfire air system were retrofit to the top-fired boiler in mid-1992 and demonstrated a NO{sub x} reduction of nearly 70% across the load range. Integrated testing of the combustion modifications and the SNCR system were conducted in 1993 and showed that the SNCR system could reduce NO{sub x} emissions by an additional 45% while maintaining 10 ppm of ammonia slip limit at full load. Lower than expect4ed flue-gas temperatures caused low-load operation to be less effective than at high loads. NO{sub x} reduction decreased to as low as 11% at 60 MWe at an ammonia slip limit of 10 ppm. An ammonia conversion system was installed to improve performance at low loads. Other improvements to increase NO{sub x} removal at low-loads are planned. The combined system of combustion modifications and SNCR reduced NO{sub x} emissions by over 80% from the original full-load baseline. 11 figs.

  20. Combustion in a multiburner furnace with selective flow of oxygen

    DOE Patents [OSTI]

    Bool, III, Lawrence E.; Kobayashi, Hisashi

    2004-03-02

    Improved operational characteristics such as improved fuel efficiency, reduction of NOx formation, reduction of the amount of unburned carbon in the ash, and lessened tendency to corrosion at the tube wall, in a multi-burner furnace are obtained by reducing the flow rate of combustion air to the burners and selectively individually feeding oxidant to only some of the burners.