Sample records for nonhydro carbon gases

  1. Carbon Bearing Trace Gases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOnItem NotEnergy,ARMForms About Batteries BatteriesCAESMissionMetal-OrganicCarbon Bearing

  2. New Materials for Capturing Carbon Dioxide from Combustion Gases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to APS Science Highlights rss feed New Materials for Capturing Carbon Dioxide from Combustion Gases April 9, 2014 Bookmark and Share The SIFSIX materials in order of increasing...

  3. Method of producing pyrolysis gases from carbon-containing materials

    DOE Patents [OSTI]

    Mudge, Lyle K. (Richland, WA); Brown, Michael D. (West Richland, WA); Wilcox, Wayne A. (Kennewick, WA); Baker, Eddie G. (Richland, WA)

    1989-01-01T23:59:59.000Z

    A gasification process of improved efficiency is disclosed. A dual bed reactor system is used in which carbon-containing feedstock materials are first treated in a gasification reactor to form pyrolysis gases. The pyrolysis gases are then directed into a catalytic reactor for the destruction of residual tars/oils in the gases. Temperatures are maintained within the catalytic reactor at a level sufficient to crack the tars/oils in the gases, while avoiding thermal breakdown of the catalysts. In order to minimize problems associated with the deposition of carbon-containing materials on the catalysts during cracking, a gaseous oxidizing agent preferably consisting of air, oxygen, steam, and/or mixtures thereof is introduced into the catalytic reactor at a high flow rate in a direction perpendicular to the longitudinal axis of the reactor. This oxidizes any carbon deposits on the catalysts, which would normally cause catalyst deactivation.

  4. C:\\ANNUAL\\Vol2chps.v8\\ANNUAL2.VP

    U.S. Energy Information Administration (EIA) Indexed Site

    per Thousand Cubic Feet) Table Year Gross Withdrawals Used for Repressuring Nonhydro- carbon Gases Removed Vented and Flared Marketed Production Extraction Loss Dry Production...

  5. Atmospheric Trace Gases from the Carbon Dioxide Information Analysis Center (CDIAC)

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    CDIAC products are indexed and searchable through a customized interface powered by ORNL's Mercury search engine. Products include numeric data packages, publications, trend data, atlases, models, etc. and can be searched for by subject area, keywords, authors, product numbers, time periods, collection sites, spatial references, etc. Some of the collections may also be included in the CDIAC publication, Trends Online: A Compendium of Global Change Data. Most data sets, many with numerous data files, are free to download from CDIAC's ftp area. The collections under the CDIAC heading of Atmospheric Trace Gases include: Atmospheric Carbon Dioxide, Atmospheric Methane, Atmospheric Carbon Monoxide, Atmospheric Hydrogen, Isotopes in Greenhouse Gases, Radionuclides, Aerosols, and Other Trace Gases.

  6. Effects of Biochar and Basalt Additions on Carbon Sequestration and Fluxes of Greenhouse Gases in Soils

    E-Print Network [OSTI]

    Vallino, Joseph J.

    Effects of Biochar and Basalt Additions on Carbon Sequestration and Fluxes of Greenhouse Gases Emissions--Carbon Dioxide Emissions--Sequestration and Storage--Biochar--Basalt--Organic Fertilizers, this investigation focuses on the range of potential of different soil additives to enhance sequestration and storage

  7. The origins and concentrations of water, carbon, nitrogen and noble gases on Earth

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 The origins and concentrations of water, carbon, nitrogen and noble gases on Earth Bernard Marty (PSN) are still present in the mantle, presumably signing the sequestration of PSN gas at an early), and up to ~500 ppm C, both largely sequestrated in the solid Earth. This volatile content is equivalent

  8. ARM Carbon Cycle Gases Flasks at SGP Site

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Biraud, Sebastien

    Data from flasks are sampled at the Atmospheric Radiation Measurement Program ARM, Southern Great Plains Site and analyzed by the National Oceanic and Atmospheric Administration NOAA, Earth System Research Laboratory ESRL. The SGP site is included in the NOAA Cooperative Global Air Sampling Network. The surface samples are collected from a 60 m tower at the ARM SGP Central Facility, usually once per week in the afternoon. The aircraft samples are collected approximately weekly from a chartered aircraft, and the collection flight path is centered over the tower where the surface samples are collected. The samples are collected by the ARM and LBNL Carbon Project.

  9. ARM Carbon Cycle Gases Flasks at SGP Site

    SciTech Connect (OSTI)

    Biraud, Sebastien

    2013-03-26T23:59:59.000Z

    Data from flasks are sampled at the Atmospheric Radiation Measurement Program ARM, Southern Great Plains Site and analyzed by the National Oceanic and Atmospheric Administration NOAA, Earth System Research Laboratory ESRL. The SGP site is included in the NOAA Cooperative Global Air Sampling Network. The surface samples are collected from a 60 m tower at the ARM SGP Central Facility, usually once per week in the afternoon. The aircraft samples are collected approximately weekly from a chartered aircraft, and the collection flight path is centered over the tower where the surface samples are collected. The samples are collected by the ARM and LBNL Carbon Project.

  10. ARM-LBNL-NOAA Flask Sampler for Carbon Cycle Gases

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Torn, Margaret

    Data from ccg-flasks are sampled at the ARM SGP site and analyzed by the NOAA Earth System Research Laboratory (ESRL) as part of the NOAA Cooperative Global Air Sampling Network. Surface samples are collected from a 60m tower at the SGP Central Facility, usually once per week on one afternoon. The aircraft samples are collected approximately weekly from a chartered aircraft, and the collection flight path is centered over the tower where the surface samples are collected. Samples are collected by the ARM/LBNL Carbon Project. CO2 flask data contains measurements of CO2 concentration and CO2 stable isotope ratios (13CO2 and C18OO) from flasks collected at the SGP site. The flask samples are collected at 2m, 4m, 25m, and 60m along the 60m tower.

  11. ARM-LBNL-NOAA Flask Sampler for Carbon Cycle Gases

    SciTech Connect (OSTI)

    Torn, Margaret

    2008-01-15T23:59:59.000Z

    Data from ccg-flasks are sampled at the ARM SGP site and analyzed by the NOAA Earth System Research Laboratory (ESRL) as part of the NOAA Cooperative Global Air Sampling Network. Surface samples are collected from a 60m tower at the SGP Central Facility, usually once per week on one afternoon. The aircraft samples are collected approximately weekly from a chartered aircraft, and the collection flight path is centered over the tower where the surface samples are collected. Samples are collected by the ARM/LBNL Carbon Project. CO2 flask data contains measurements of CO2 concentration and CO2 stable isotope ratios (13CO2 and C18OO) from flasks collected at the SGP site. The flask samples are collected at 2m, 4m, 25m, and 60m along the 60m tower.

  12. Method and apparatus for separating gases based on electrically and magnetically enhanced monolithic carbon fiber composite sorbents

    DOE Patents [OSTI]

    Judkins, Roddie R. (9917 Rainbow Dr., Knoxville, TN 37922); Burchell, Timothy D. (109 Greywood Pl., Oak Ridge, TN 37830)

    1999-01-01T23:59:59.000Z

    A method for separating gases or other fluids involves placing a magnetic field on a monolithic carbon fiber composite sorption material to more preferentially attract certain gases or other fluids to the sorption material to which a magnetic field is applied. This technique may be combined with the known "pressure swing adsorption" technique utilizing the same sorption material.

  13. Method and apparatus for separating gases based on electrically and magnetically enhanced monolithic carbon fiber composite sorbents

    DOE Patents [OSTI]

    Judkins, R.R.; Burchell, T.D.

    1999-07-20T23:59:59.000Z

    A method for separating gases or other fluids involves placing a magnetic field on a monolithic carbon fiber composite sorption material to more preferentially attract certain gases or other fluids to the sorption material to which a magnetic field is applied. This technique may be combined with the known pressure swing adsorption'' technique utilizing the same sorption material. 1 fig.

  14. Flame Synthesis of Carbon Nanotubes Using Low Calorific Value Gases

    SciTech Connect (OSTI)

    Jorge Camacho; Mahesh Subramanya; Ahsan R. Choudhuri

    2007-03-31T23:59:59.000Z

    Nanostructures formed in diffusion flames of pure fuels [CH{sub 4}, C{sub 3}H{sub 8}, and C{sub 2}H{sub 2}] at different fuel flow rates have been analyzed. Synthesis samples have been also collected from diffusion flames of various fuel blends [H{sub 2}-CH{sub 4}, H{sub 2}-CO, H{sub 2}-C{sub 3}H{sub 8}, H{sub 2}-C{sub 2}H{sub 2}] at different combustion conditions. SEM images of particulate samples collected from H{sub 2}-CH{sub 4} diffusion flames show formation of nanostructures. However, the formation of nanostructures only occurs at a narrow window of fuel compositions (< 10% H{sub 2} concentration in the mixture) and flow conditions (Jet Exit Reynolds number Re{sub j} = 200). At higher H{sub 2} concentration and flow velocity, formation of nanostructures diminishes and H{sub 2}-CH{sub 4} flames produce amorphous carbon and soot particles.

  15. Emission factors for particles, elemental carbon, and trace gases from the Kuwait oil fires

    SciTech Connect (OSTI)

    Laursen, K.K.; Ferek, R.J.; Hobbs, P.V. [Univ. of Washington, Seattle, WA (United States); Rasmussen, R.A. [Oregon Graduate Institute of Science and Technology, Beaverton, OR (United States)

    1992-09-20T23:59:59.000Z

    Emission factors are presented for particles, elemental carbon (i.e., soot), total organic carbon in particles and vapor, and for various trace gases from the 1991 Kuwait oil fires. Particle emissions accounted for {approximately} 2% of the fuel burned. In general, soot emission factors were substantially lower than those used in recent {open_quotes}nuclear winter{close_quotes} calculations. Differences in the emissions and appearances of some of the individual fires are discussed. Carbon budget data for the composite plumes from the Kuwait fires are summarized; most of the burned carbon in the plumes was in the form of CO{sub 2}. Fluxes are presented for several combustion products. 26 refs., 1 fig., 5 tabs.

  16. Combustion systems and power plants incorporating parallel carbon dioxide capture and sweep-based membrane separation units to remove carbon dioxide from combustion gases

    DOE Patents [OSTI]

    Wijmans, Johannes G. (Menlo Park, CA); Merkel, Timothy C (Menlo Park, CA); Baker, Richard W. (Palo Alto, CA)

    2011-10-11T23:59:59.000Z

    Disclosed herein are combustion systems and power plants that incorporate sweep-based membrane separation units to remove carbon dioxide from combustion gases. In its most basic embodiment, the invention is a combustion system that includes three discrete units: a combustion unit, a carbon dioxide capture unit, and a sweep-based membrane separation unit. In a preferred embodiment, the invention is a power plant including a combustion unit, a power generation system, a carbon dioxide capture unit, and a sweep-based membrane separation unit. In both of these embodiments, the carbon dioxide capture unit and the sweep-based membrane separation unit are configured to be operated in parallel, by which we mean that each unit is adapted to receive exhaust gases from the combustion unit without such gases first passing through the other unit.

  17. Carbon dioxide Information Analysis Center and World Data Center: A for Atmospheric trace gases. Annual progress report, FY 1994

    SciTech Connect (OSTI)

    Burtis, M.D. [comp.] [Tennessee Univ., Knoxville, TN (United States). Energy, Environment and Resources Center; Cushman, R.M.; Boden, T.A.; Jones, S.B.; Nelson, T.R.; Stoss, F.W. [Oak Ridge National Lab., TN (United States)

    1995-03-01T23:59:59.000Z

    This report summarizes the activities and accomplishments made by the Carbon Dioxide Information Analysis Center and World Data Center-A for Atmospheric Trace Gases during the fiscal year 1994. Topics discussed in this report include; organization and staff, user services, systems, communications, Collaborative efforts with China, networking, ocean data and activities of the World Data Center-A.

  18. Oceanic Trace Gases Numeric Data Packages from the Carbon Dioxide Information Analysis Center (CDIAC)

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    CDIAC products include numeric data packages, publications, trend data, atlases, models, etc. and can be searched for by subject area, keywords, authors, product numbers, time periods, collection sites, spatial references, etc. Most data sets or packages, many with numerous data files, are free to download from CDIAC's ftp area. CDIAC lists the following numeric data packages under the broad heading of Oceanic Trace Gases: Carbon Dioxide, Hydrographic, and Chemical Data Obtained during the R/V Ronald H. Brown Repeat Hydrography Cruise in the Atlantic Ocean: CLIVAR CO2 Section A16S_2005 ( 01/11/05 - 022405) • Determination of Carbon Dioxide, Hydrographic, and Chemical Parameters during the R/V Nathaniel B. Palmer Cruise in the Southern Indian Ocean (WOCE Section S04I, 050396 - 070496) • Inorganic Carbon, Nutrient, and Oxygen Data from the R/V Ronald H. Brown Repeat Hydrography Cruise in the Atlantic Ocean: CLIVAR CO2 Section A16N_2003a (060403 – 081103) • Carbon Dioxide, Hydrographic, and Chemical Data Obtained During the R/V Maurice Ewing Cruise in the Atlantic Ocean (WOCE Section A17, 010494 - 032194) • Global Ocean Data Analysis Project GLODAP: Results and Data • Carbon Dioxide, Hydrographic, and Chemical Data Obtained During the R/V Knorr Cruises in the North Atlantic Ocean on WOCE Sections AR24 (1102 – 120596) and A24, A20, and A22 (053097 – 090397) • Carbon Dioxide, Hydrographic and Chemical Data Obtained During the Nine R/V Knorr Cruises Comprising the Indian Ocean CO2 Survey (WOCE Sections I8SI9S, I9N, I8NI5E, I3, I5WI4, I7N, I1, I10, and I2; 120 194 – 012296) • Carbon Dioxide, Hydrographic, and Chemical Data Obtained During the R/V Meteor Cruise 28/1 in the South Atlantic Ocean (WOCE Section A8, 032994 - 051294) • Carbon Dioxide, Hydrographic, and Chemical Data Obtained During the R/V Knorr Cruise 138-3, -4, and -5 in the South Pacific Ocean (WOCE Sections P6E, P6C, and P6W, 050292 - 073092) • Global Distribution of Total Inorganic Carbon and Total Alkalinity below the deepest winter mixed layer depths • Carbon Dioxide, Hydrographic, and Chemical Data Obtained During the R/V John V. Vickers Cruise in the Pacific Ocean (WOCE Section P13, NOAA CGC92 Cruise, 080492 – 102192) • Carbon Dioxide, Hydrographic, and Chemical Data Obtained During the R/V Hesperides Cruise in the Atlantic Ocean (WOCE Section A5, 071492 - 081592) • Carbon Dioxide, Hydrographic, and Chemical Data Obtained During the R/V Thomas G. Thompson Cruise in the Pacific Ocean (WOCE Section P10, 100593 – 111093) • The International Intercomparison Exercise of Underway fCO2 Systems during the R/V Meteor Cruise 36/1 in the North Atlantic Ocean • Carbon Dioxide, Hydrographic, and Chemical Data Obtained during the R/V Meteor Cruise 22/5 in the South Atlantic Ocean (WOCE Section A10, Dec. 1992-Jan, 1993) • Carbon Dioxide, Hydrographic, and Chemical Data Obtained in the South Pacific Ocean (WOCE Sections P16A/P17A, P17E/P19S, and P19C, R/V Knorr , Oct. 1992-April 1993) • Surface Water and Atmospheric Underway Carbon Data Obtained During the World Ocean Circulation Experiment Indian Ocean Survey Cruises (R/V Knorr, Dec. 1994 – Jan, 1996) • Carbon Dioxide, Hydrographic, and Chemical Data Obtained During the R/V Akademik Ioffe Cruise in the South Pacific Ocean (WOCE Section S4P, Feb.-April 1992) • Carbon Dioxide, Hydrographic, and Chemical Data Obtained During the R/V Thomas Washington Cruise TUNES-1 in the Equatorial Pacific Ocean (WOCE section P17C) • Carbon Dioxide, Hydrographic, and Chemical Data Obtained During the R/V Thomas Washington Cruise TUNES-3 in the Equatorial Pacific Ocean (WOCE section P16C) • Carbon-14 Measurements in Surface Water CO2 from the Atlantic, Indian and Pacific Oceans, 1965-1994 • Carbon Dioxide, Hydrographic, and Chemical Data Obtained During R/V Meteor Cruise 18/1 in the North Atlantic Ocean (WOCE Section A1E) • Carbon Dioxide, Hydrographic, and Chemical Data Obtained in the Central South Pacific Ocean (WOCE Sections P17S and P16S) during the TUNES-2 Expedition of the R/V Th

  19. Steam Production from Waste Stack Gases in a Carbon Black Plant

    E-Print Network [OSTI]

    Istre, R. I.

    1981-01-01T23:59:59.000Z

    gases to produce steam has two very important rewards - energy conservation and pollution abatement. Energy conservation is achieved by using waste gases in place of fuel oil to produce the steam required by the various plants. Pollution abatement is due...

  20. Carbon Dioxide Information Analysis Center and World Data Center-A for atmospheric trace gases: FY 1993 activities

    SciTech Connect (OSTI)

    Cushman, R.M. [Oak Ridge National Lab., TN (United States). Carbon Dioxide Information Analysis Center; Stoss, F.W. [Oak Ridge National Lab., TN (United States). Carbon Dioxide Information Analysis Center]|[Univ. of Tennessee, Knoxville, TN (United States). Energy, Environment, and Resources Center

    1994-01-01T23:59:59.000Z

    During the course of a fiscal year, Oak Ridge National Laboratory`s Carbon Dioxide Information Analysis Center (CDIAC) distributes thousands of specialty publications-numeric data packages (NDPs), computer model packages (CMPs), technical reports, public communication publications, newsletters, article reprints, and reference books-in response to requests for information related to global environmental issues, primarily those pertaining to climate change. CDIAC`s staff also provide technical responses to specific inquiries related to carbon dioxide (CO{sub 2}), other trace gases, and climate. Hundreds of referrals to other researchers, policy analysts, information specialists, or organizations are also facilitated by CDIAC`s staff. This report provides an account of the activities accomplished by CDIAC (including World Data Center-A for Atmospheric Trace Gases) during the period October 1, 1992, to September 30, 1993. An organizational overview of CDIAC and its staff is supplemented by a detailed description of inquiries received and CDIAC`s response to those inquiries. An analysis and description of the preparation and distribution of NDPS, CMPS, technical reports, newsletters, fact sheets, specialty publications, and reprints are provided. Comments and descriptions of CDIAC`s information management systems, professional networking, and special bilateral agreements are also presented.

  1. Separation of polar gases from nonpolar gases

    DOE Patents [OSTI]

    Kulprathipanja, Santi (Hoffman Estates, IL); Kulkarni, Sudhir S. (Hoffman Estates, IL)

    1986-01-01T23:59:59.000Z

    Polar gases such as hydrogen sulfide, sulfur dioxide and ammonia may be separated from nonpolar gases such as methane, nitrogen, hydrogen or carbon dioxide by passing a mixture of polar and nonpolar gases over the face of a multicomponent membrane at separation conditions. The multicomponent membrane which is used to effect the separation will comprise a mixture of a glycol plasticizer having a molecular weight of from about 200 to about 600 and an organic polymer cast on a porous support. The use of such membranes as exemplified by polyethylene glycol and silicon rubber composited on polysulfone will permit greater selectivity accompanied by a high flux rate in the separation process.

  2. Separation of polar gases from nonpolar gases

    DOE Patents [OSTI]

    Kulprathipanja, S.; Kulkarni, S.S.

    1986-08-26T23:59:59.000Z

    Polar gases such as hydrogen sulfide, sulfur dioxide and ammonia may be separated from nonpolar gases such as methane, nitrogen, hydrogen or carbon dioxide by passing a mixture of polar and nonpolar gases over the face of a multicomponent membrane at separation conditions. The multicomponent membrane which is used to effect the separation will comprise a mixture of a glycol plasticizer having a molecular weight of from about 200 to about 600 and an organic polymer cast on a porous support. The use of such membranes as exemplified by polyethylene glycol and silicon rubber composited on polysulfone will permit greater selectivity accompanied by a high flux rate in the separation process.

  3. Voluntary Reporting of Greenhouse Gases

    Reports and Publications (EIA)

    2011-01-01T23:59:59.000Z

    The Voluntary Reporting of Greenhouse Gases Program was suspended May 2011. It was a mechanism by which corporations, government agencies, individuals, voluntary organizations, etc., could report to the Energy Information Administration, any actions taken that have or are expected to reduce/avoid emissions of greenhouse gases or sequester carbon.

  4. Thermal device and method for production of carbon monoxide and hydrogen by thermal dissociation of hydrocarbon gases

    DOE Patents [OSTI]

    Detering, Brent A. (Idaho Falls, ID); Kong, Peter C. (Idaho Falls, ID)

    2001-01-01T23:59:59.000Z

    Carbon monoxide is produced in a fast quench reactor. The production of carbon monoxide includes injecting carbon dioxide and some air into a reactor chamber having a high temperature at its inlet and a rapidly expanding a reactant stream, such as a restrictive convergent-divergent nozzle at its outlet end. Carbon dioxide and other reactants such as methane and other low molecular weight hydrocarbons are injected into the reactor chamber. Other gas may be added at different stages in the process to form a desired end product and prevent back reactions. The resulting heated gaseous stream is then rapidly cooled by expansion of the gaseous stream.

  5. Fiscal Year 1998 Annual Report, Carbon Dioxide Information Analysis Center, World Data Center -- A for Atmospheric Trace Gases

    SciTech Connect (OSTI)

    Cushman, R.M.; Boden, T.A.; Hook, L.A.; Jones, S.B.; Kaiser, D.P.; Nelson, T.R.

    1999-03-01T23:59:59.000Z

    Once again, the most recent fiscal year was a productive one for the Carbon Dioxide Information Analysis Center (CDIAC) at Oak Ridge National Laboratory (ORNL), as well as a year for change. The FY 1998 in Review section in this report summarizes quite a few new and updated data and information products, and the ''What's Coming in FY 1999'' section describes our plans for this new fiscal year. During FY 1998, CDIAC began a data-management system for AmeriFlux, a long-term study of carbon fluxes between the terrestrial biosphere of the Western Hemisphere and the atmosphere. The specific objectives of AmeriFlux are to establish an infrastructure for guiding, collecting, synthesizing, and disseminating long-term measurements of CO{sub 2}, water, and energy exchange from a variety of ecosystems; collect critical new information to help define the current global CO{sub 2} budget; enable improved predictions of future concentrations of atmospheric CO{sub 2}; and enhance understanding of carbon fluxes. Net Ecosystem Production (NEP), and carbon sequestration in the terrestrial biosphere. The data-management system, available from CDIAC'S AmeriFlux home page (http://cdiac.esd.ornl.gov/programs/ameriflux/ ) is intended to provide consistent, quality-assured, and documented data across all AmeriFlux sites in the US, Canada, Costa Rica, and Brazil. It is being developed by Antoinette Brenkert and Tom Boden, with assistance from Susan Holladay (who joined CDIAC specifically to support the AmeriFlux data-management effort).

  6. Studies of the terrestrial O{sub 2} and carbon cycles in sand dune gases and in biosphere 2

    SciTech Connect (OSTI)

    Severinghaus, J.P.

    1995-12-31T23:59:59.000Z

    Molecular oxygen in the atmosphere is coupled tightly to the terrestrial carbon cycle by the processes of photosynthesis, respiration, and burning. This dissertation examines different aspects of this coupling in four chapters. Chapter 1 explores the feasibility of using air from sand dunes to reconstruct atmospheric O{sub 2} composition centuries ago. Such a record would reveal changes in the mass of the terrestrial biosphere, after correction for known fossil fuel combustion, and constrain the fate of anthropogenic CO{sub 2}.

  7. Use of molecular modeling to determine the interaction and competition of gases within coal for carbon dioxide sequestration

    SciTech Connect (OSTI)

    Jeffrey D. Evanseck; Jeffry D. Madura; Jonathan P. Mathews

    2006-04-21T23:59:59.000Z

    Molecular modeling was employed to both visualize and probe our understanding of carbon dioxide sequestration within a bituminous coal. A large-scale (>20,000 atoms) 3D molecular representation of Pocahontas No. 3 coal was generated. This model was constructed based on a the review data of Stock and Muntean, oxidation and decarboxylation data for aromatic clustersize frequency of Stock and Obeng, and the combination of Laser Desorption Mass Spectrometry data with HRTEM, enabled the inclusion of a molecular weight distribution. The model contains 21,931 atoms, with a molecular mass of 174,873 amu, and an average molecular weight of 714 amu, with 201 structural components. The structure was evaluated based on several characteristics to ensure a reasonable constitution (chemical and physical representation). The helium density of Pocahontas No. 3 coal is 1.34 g/cm{sup 3} (dmmf) and the model was 1.27 g/cm{sup 3}. The structure is microporous, with a pore volume comprising 34% of the volume as expected for a coal of this rank. The representation was used to visualize CO{sub 2}, and CH{sub 4} capacity, and the role of moisture in swelling and CO{sub 2}, and CH{sub 4} capacity reduction. Inclusion of 0.68% moisture by mass (ash-free) enabled the model to swell by 1.2% (volume). Inclusion of CO{sub 2} enabled volumetric swelling of 4%.

  8. The safe use of low temperature liquefied gases 1. Introduction

    E-Print Network [OSTI]

    Martin, Ralph R.

    dioxide TABLE 1 Property Oxygen (O2) Nitrogen (N2) Argon (Ar) Helium (He) Carbon dioxide (CO2) Molecular.1 Objective 1.2 Gases considered and typical uses 2. Properties of low temperature liquefied atmospheric gases of BOC low temperature liquefied gases information on their properties, the hazards associated

  9. Biological production of products from waste gases

    DOE Patents [OSTI]

    Gaddy, James L. (Fayetteville, AR)

    2002-01-22T23:59:59.000Z

    A method and apparatus are designed for converting waste gases from industrial processes such as oil refining, and carbon black, coke, ammonia, and methanol production, into useful products. The method includes introducing the waste gases into a bioreactor where they are fermented to various products, such as organic acids, alcohols, hydrogen, single cell protein, and salts of organic acids by anaerobic bacteria within the bioreactor. These valuable end products are then recovered, separated and purified.

  10. Separation of polar gases from nonpolar gases

    DOE Patents [OSTI]

    Kulprathipanja, S.

    1986-08-19T23:59:59.000Z

    The separation of polar gases from nonpolar gases may be effected by passing a mixture of nonpolar gases over the face of a multicomponent membrane at separation conditions. The multicomponent membrane which is used to effect the separation will comprise a mixture of a glycol plasticizer having a molecular weight of from about 200 to about 600 and an organic polymer cast on a porous support. The porous support is pretreated prior to casting of the mixture thereon by contact with a polyhydric alcohol whereby the pores of the support are altered, thus adding to the increased permeability of the polar gas.

  11. Separation of polar gases from nonpolar gases

    DOE Patents [OSTI]

    Kulprathipanja, Santi (Hoffman Estates, IL)

    1986-01-01T23:59:59.000Z

    The separation of polar gases from nonpolar gases may be effected by passing a mixture of nonpolar gases over the face of a multicomponent membrane at separation conditions. The multicomponent membrane which is used to effect the separation will comprise a mixture of a glycol plasticizer having a molecular weight of from about 200 to about 600 and an organic polymer cast on a porous support. The porous support is pretreated prior to casting of the mixture thereon by contact with a polyhydric alcohol whereby the pores of the support are altered, thus adding to the increased permeability of the polar gas.

  12. Greenhouse Gases | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Greenhouse Gases Greenhouse Gases Executive Order 13514 requires Federal agencies to inventory and manage greenhouse gas (GHG) emissions to meet Federal goals and mitigate climate...

  13. Carbon Dioxide Information Analysis Center and World Data Center-A for atomspheric trace gases: Catalog of data bases and reports

    SciTech Connect (OSTI)

    Burtis, M.D. [comp.

    1995-04-01T23:59:59.000Z

    This document provides information about the many reports and other materials made available by the US Department of Energy`s Global Change Research Program (GCRP). Section A provides information about the activities, scope, and direction of the GCRP; Sections B,C, D, and E contain information about research that has been sponsered by GCRP; Sections F and G contains information about the numeric data packages and computer model pa kages the have been compiled by the GCRP; Section H describes reports about research dealing with the responses of vegetation to carbon dioxide; and Section I conatins reports from various workshops, symposia, and reviews.

  14. Where do California's greenhouse gases come from?

    ScienceCinema (OSTI)

    Fischer, Marc

    2013-05-29T23:59:59.000Z

    Last March, more than two years after California passed legislation to slash greenhouse gas emissions 25 percent by 2020, Lawrence Berkeley National Laboratory scientist Marc Fischer boarded a Cessna loaded with air monitoring equipment and crisscrossed the skies above Sacramento and the Bay Area. Instruments aboard the aircraft measured a cocktail of greenhouse gases: carbon dioxide from fossil fuel use, methane from livestock and landfills, CO2 from refineries and power plants, traces of nitrous oxide from agriculture and fuel use, and industrially produced other gases like refrigerants. The flight was part of the Airborne Greenhouse Gas Emissions Survey, a collaboration between Berkeley Lab, the National Oceanic and Atmospheric Administration, and the University of California, and UC Davis to pinpoint the sources of greenhouse gases in central California. The survey is intended to improve inventories of the states greenhouse gas emissions, which in turn will help scientists verify the emission reductions mandated by AB-32, the legislation enacted by California in 2006.

  15. Biological production of ethanol from waste gases with Clostridium ljungdahlii

    DOE Patents [OSTI]

    Gaddy, James L. (Fayetteville, AR)

    2000-01-01T23:59:59.000Z

    A method and apparatus for converting waste gases from industrial processes such as oil refining, carbon black, coke, ammonia, and methanol production, into useful products is disclosed. The method includes introducing the waste gases into a bioreactor where they are fermented to various product, such as organic acids, alcohols H.sub.2, SCP, and salts of organic acids by anaerobic bacteria within the bioreactor. These valuable end products are then recovered, separated and purified.

  16. Chapter 46. Ultracold Quantum Gases Ultracold Quantum Gases

    E-Print Network [OSTI]

    of strongly interacting Fermi gases is important for the modeling of neutron stars. Cold atomic gases allow potential of the gas. Away from resonance another length scale comes into play, the scattering length a

  17. Separating hydrogen from coal gasification gases with alumina membranes

    SciTech Connect (OSTI)

    Egan, B.Z. (Oak Ridge National Lab., TN (USA)); Fain, D.E.; Roettger, G.E.; White, D.E. (Oak Ridge K-25 Site, TN (USA))

    1991-01-01T23:59:59.000Z

    Synthesis gas produced in coal gasification processes contains hydrogen, along with carbon monoxide, carbon dioxide, hydrogen sulfide, water, nitrogen, and other gases, depending on the particular gasification process. Development of membrane technology to separate the hydrogen from the raw gas at the high operating temperatures and pressures near exit gas conditions would improve the efficiency of the process. Tubular porous alumina membranes with mean pore radii ranging from about 9 to 22 {Angstrom} have been fabricated and characterized. Based on hydrostatic tests, the burst strength of the membranes ranged from 800 to 1600 psig, with a mean value of about 1300 psig. These membranes were evaluated for separating hydrogen and other gases. Tests of membrane permeabilities were made with helium, nitrogen, and carbon dioxide. Measurements were made at room temperature in the pressure range of 15 to 589 psi. Selected membranes were tested further with mixed gases simulating a coal gasification product gas. 5 refs., 7 figs.

  18. Process for removing hydrogen sulfide from gases particularly coal pyrolysis gases

    SciTech Connect (OSTI)

    Ritter, H.; Herpers, E.T.

    1985-02-12T23:59:59.000Z

    Hydrogen sulfide is first removed by ammoniacal liquor from coke oven gas in the bottom part of a gas scrubber. In the top part of the scrubber, two consecutively-arranged fine scrubbing stages remove hydrogen sulfide by treating the gases, in the upper stage, with a caustic soda solution or a caustic potash solution. Beneath the upper scrubbing stage is the second fine scrubbing stage fed with a subflow of an aqueous carbonate solution collecting at the outlet of the upper fine scrubbing stage and a subflow of cooled, regenerated carbonate solution discharged from the hydrogen-sulfide/hydrogen-cyanide stripper. From the hydrogen-sulfide/hydrogen-cyanide stripper, a second subflow is admixed with coal liquor for removing fixed ammonia therefrom in a separator. The separator produces water vapor with carbon dioxide vapors that are delivered to the hydrogen-sulfide/hydrogen-cyanide stripper for regenerating the aqueous carbonate washing solution.

  19. What are greenhouse gases? Many chemical compounds in the atmosphere act as

    E-Print Network [OSTI]

    , Michigan State University, 2 Michigan State University Extension Climate Change and Agriculture Fact Sheet greenhouse gases carbon dioxide, methane, and nitrous oxide over the past 2000 years. Data are from ice core

  20. Control of pollutants in flue gases and fuel gases

    E-Print Network [OSTI]

    Laughlin, Robert B.

    . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-1 2.2 Flue gases and fuel gases: combustion, gasification, pyrolysis, incineration and other and gasification technologies for heat and power . . . . . . . . 2-3 2.4 Waste incineration and waste . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3-3 3.3 Formation of sulphur compounds during combustion and gasification . 3-5 3.4 Emission

  1. Voluntary reporting of greenhouse gases 1997

    SciTech Connect (OSTI)

    NONE

    1999-05-01T23:59:59.000Z

    The Voluntary Reporting of Greenhouse Gases Program, required by Section 1605(b) of the Energy Policy Act of 1992, records the results of voluntary measures to reduce, avoid, or sequester greenhouse gas emissions. In 1998, 156 US companies and other organizations reported to the Energy information Administration that, during 1997, they had achieved greenhouse gas emission reductions and carbon sequestration equivalent to 166 million tons of carbon dioxide, or about 2.5% of total US emissions for the year. For the 1,229 emission reduction projects reported, reductions usually were measured by comparing an estimate of actual emissions with an estimate of what emissions would have been had the project not been implemented.

  2. Rapid prototyping of carbon-based chemiresistive gas sensors on paper

    E-Print Network [OSTI]

    Mirica, Katherine

    Chemically functionalized carbon nanotubes (CNTs) are promising materials for sensing of gases and volatile organic compounds. However, the poor solubility of carbon nanotubes hinders their chemical functionalization and ...

  3. Separation of gases through gas enrichment membrane composites

    DOE Patents [OSTI]

    Swedo, R.J.; Kurek, P.R.

    1988-07-19T23:59:59.000Z

    Thin film composite membranes having as a permselective layer a film of a homopolymer of certain vinyl alkyl ethers are useful in the separation of various gases. Such homopolymers have a molecular weight of greater than 30,000 and the alkyl group of the vinyl alkyl monomer has from 4 to 20 carbon atoms with branching within the alkyl moiety at least at the carbon atom bonded to the ether oxygen or at the next adjacent carbon atom. These membranes show excellent hydrolytic stability, especially in the presence of acidic or basic gaseous components.

  4. Separation of gases through gas enrichment membrane composites

    DOE Patents [OSTI]

    Swedo, Raymond J. (Mt. Prospect, IL); Kurek, Paul R. (Schaumburg, IL)

    1988-01-01T23:59:59.000Z

    Thin film composite membranes having as a permselective layer a film of a homopolymer of certain vinyl alkyl ethers are useful in the separation of various gases. Such homopolymers have a molecular weight of greater than 30,000 and the alkyl group of the vinyl alkyl monomer has from 4 to 20 carbon atoms with branching within the alkyl moiety at least at the carbon atom bonded to the ether oxygen or at the next adjacent carbon atom. These membranes show excellent hydrolytic stability, especially in the presence of acidic or basic gaseous components.

  5. Emissions of greenhouse gases in the United States 1997

    SciTech Connect (OSTI)

    NONE

    1998-10-01T23:59:59.000Z

    This is the sixth annual report on aggregate US national emissions of greenhouse gases. It covers emissions over the period 1990--1996, with preliminary estimates of emissions for 1997. Chapter one summarizes some background information about global climate change and the greenhouse effect. Important recent developments in global climate change activities are discussed, especially the third Conference of the Parties to the Framework Convention on Climate Change, which was held in December of 1997 in Kyoto, Japan. Chapters two through five cover emissions of carbon dioxide, methane, nitrous oxide, halocarbons and related gases, respectively. Chapter six describes potential sequestration and emissions of greenhouse gases as a result of land use changes. Six appendices are included in the report. 96 refs., 38 tabs.

  6. Improved correlations for retrograde gases 

    E-Print Network [OSTI]

    Crogh, Arne

    1996-01-01T23:59:59.000Z

    Three correlations for retrograde gases have been developed. First, a correlation was developed that relates the composition of a retrograde gas-condensate mixture at any depletion stage to the composition at its dew point ...

  7. Guidance Document CompressedGases

    E-Print Network [OSTI]

    electricity. Oxygen by itself does not burn, but it will support or accelerate combustion of flammable the regulator is completely closed. 3. When possible use flammable and reactive gases in a fume hood. Certain

  8. Emissions of greenhouse gases in the United States 1996

    SciTech Connect (OSTI)

    NONE

    1997-10-01T23:59:59.000Z

    The Energy Information Administration (EIA) is required by the Energy Policy Act of 1992 to prepare a report on aggregate US national emissions of greenhouse gases for the period 1987--1990, with annual updates thereafter. This report is the fifth annual update, covering national emissions over the period 1989--1995, with preliminary estimates of emissions for 1996. The estimates contained in this report have been revised from those in last year`s report. Emissions estimates for carbon dioxide are reported in metric tons of carbon; estimates for other gases are reported in metric tons of gas. Chapter 1 of this report briefly recapitulates some background information about global climate change and the greenhouse effect and discusses important recent developments in global climate change activities. Chapter 2 through 6 cover emissions of carbon dioxide, methane, nitrous oxide, halocarbons, and criteria pollutants, respectively. Chapter 7 describes potential sequestration and emissions of greenhouse gases as a result of land use changes. Five appendixes are included with this report. 216 refs., 11 figs., 38 tabs.

  9. Coal-Fired Power Plants, Greenhouse Gases, and State Statutory Substantial Endangerment Provisions: Climate Change Comes to Kansas

    E-Print Network [OSTI]

    Glicksman, Robert L.

    2008-04-01T23:59:59.000Z

    economy standards on motor vehicles by states such as California. But the states have also targeted stationary sources of greenhouse gases. In particular, they have sought to minimize carbon dioxide emissions from coal-fired power plants. States have used...

  10. Method of removing and recovering elemental sulfur from highly reducing gas streams containing sulfur gases

    DOE Patents [OSTI]

    Gangwal, Santosh K.; Nikolopoulos, Apostolos A.; Dorchak, Thomas P.; Dorchak, Mary Anne

    2005-11-08T23:59:59.000Z

    A method is provided for removal of sulfur gases and recovery of elemental sulfur from sulfur gas containing supply streams, such as syngas or coal gas, by contacting the supply stream with a catalyst, that is either an activated carbon or an oxide based catalyst, and an oxidant, such as sulfur dioxide, in a reaction medium such as molten sulfur, to convert the sulfur gases in the supply stream to elemental sulfur, and recovering the elemental sulfur by separation from the reaction medium.

  11. Emissions of greenhouse gases in the United States 1995

    SciTech Connect (OSTI)

    NONE

    1996-10-01T23:59:59.000Z

    This is the fourth Energy Information Administration (EIA) annual report on US emissions of greenhouse gases. This report presents estimates of US anthropogenic (human-caused) emissions of carbon dioxide, methane, nitrous oxide, and several other greenhouse gases for 1988 through 1994. Estimates of 1995 carbon dioxide, nitrous oxide, and halocarbon emissions are also provided, although complete 1995 estimates for methane are not yet available. Emissions of carbon dioxide increased by 1.9% from 1993 to 1994 and by an additional 0.8% from 1994 to 1995. Most carbon dioxide emissions are caused by the burning of fossil fuels for energy consumption, which is strongly related to economic growth, energy prices, and weather. The US economy grew rapidly in 1994 and slowed in 1995. Estimated emissions of methane increased slightly in 1994, as a result of a rise in emissions from energy and agricultural sources. Estimated nitrous oxide emissions increased by 1.8% in 1995, primarily due to increased use of nitrogen fertilizers and higher output of chemicals linked to nitrous oxide emissions. Estimated emissions of hydrofluorocarbons (HFCs) and perfluorocarbons (PFCs), which are known to contribute to global warming, increased by nearly 11% in 1995, primarily as a result of increasing substitution for chlorofluorocarbons (CFCs). With the exception of methane, the historical emissions estimates presented in this report are only slightly revised from those in last year`s report.

  12. Chemical production from industrial by-product gases: Final report

    SciTech Connect (OSTI)

    Lyke, S.E.; Moore, R.H.

    1981-04-01T23:59:59.000Z

    The potential for conservation of natural gas is studied and the technical and economic feasibility and the implementation of ventures to produce such chemicals using carbon monoxide and hydrogen from byproduct gases are determined. A survey was performed of potential chemical products and byproduct gas sources. Byproduct gases from the elemental phosphorus and the iron and steel industries were selected for detailed study. Gas sampling, preliminary design, market surveys, and economic analyses were performed for specific sources in the selected industries. The study showed that production of methanol or ammonia from byproduct gas at the sites studied in the elemental phosphorus and the iron and steel industries is technically feasible but not economically viable under current conditions. Several other applications are identified as having the potential for better economics. The survey performed identified a need for an improved method of recovering carbon monoxide from dilute gases. A modest experimental program was directed toward the development of a permselective membrane to fulfill that need. A practical membrane was not developed but further investigation along the same lines is recommended. (MCW)

  13. Wildland fire emissions, carbon, and climate: Emission factors Shawn Urbanski

    E-Print Network [OSTI]

    Wildland fire emissions, carbon, and climate: Emission factors Shawn Urbanski Missoula Fire burning Greenhouse gases Emission factors a b s t r a c t While the vast majority of carbon emitted mixture of gases and aerosols. Primary emissions include sig- nificant amounts of CH4 and aerosol (organic

  14. Clostridium stain which produces acetic acid from waste gases

    DOE Patents [OSTI]

    Gaddy, James L. (2207 Tall Oaks Dr., Fayetteville, AR 72703)

    1997-01-01T23:59:59.000Z

    A method and apparatus for converting waste gases from industrial processes such as oil refining, carbon black, coke, ammonia, and methanol production, into useful products. The method includes introducing the waste gases into a bioreactor where they are fermented to various organic acids or alcohols by anaerobic bacteria within the bioreactor. These valuable end products are then recovered, separated and purified. In an exemplary recovery process, the bioreactor raffinate is passed through an extraction chamber into which one or more non-inhibitory solvents are simultaneously introduced to extract the product. Then, the product is separated from the solvent by distillation. Gas conversion rates can be maximized by use of centrifuges, hollow fiber membranes, or other means of ultrafiltration to return entrained anaerobic bacteria from the bioreactor raffinate to the bioreactor itself, thus insuring the highest possible cell concentration.

  15. Clostridium strain which produces acetic acid from waste gases

    DOE Patents [OSTI]

    Gaddy, J.L.

    1997-01-14T23:59:59.000Z

    A method and apparatus are disclosed for converting waste gases from industrial processes such as oil refining, carbon black, coke, ammonia, and methanol production, into useful products. The method includes introducing the waste gases into a bioreactor where they are fermented to various organic acids or alcohols by anaerobic bacteria within the bioreactor. These valuable end products are then recovered, separated and purified. In an exemplary recovery process, the bioreactor raffinate is passed through an extraction chamber into which one or more non-inhibitory solvents are simultaneously introduced to extract the product. Then, the product is separated from the solvent by distillation. Gas conversion rates can be maximized by use of centrifuges, hollow fiber membranes, or other means of ultrafiltration to return entrained anaerobic bacteria from the bioreactor raffinate to the bioreactor itself, thus insuring the highest possible cell concentration. 4 figs.

  16. The Marginal Damage Costs of Different Greenhouse Gases: An Application of FUND

    SciTech Connect (OSTI)

    Waldhoff, Stephanie T.; Anthoff, David; Rose, Steven K.; Tol, Richard

    2014-10-01T23:59:59.000Z

    We use FUND 3.8 to estimate the social cost of four greenhouse gases: carbon dioxide, methane, nitrous oxide, and sulphur hexafluoride emissions. The damage potential for each gas—the ratio of the social cost of the non-carbon dioxide greenhouse gas to the social cost of carbon dioxide—is also estimated. The damage potentials are compared to several metrics, focusing in particular on the global warming potentials, which are frequently used to measure the trade-off between gases in the form of carbon dioxide equivalents. We find that damage potentials could be significantly higher than global warming potentials. This finding implies that previous papers have underestimated the relative importance of reducing non-carbon dioxide greenhouse gas emissions from an economic damage perspective. We show results for a range of sensitivity analyses: carbon dioxide fertilization on agriculture productivity, terrestrial feedbacks, climate sensitivity, discounting, equity weighting, and socioeconomic and emissions scenarios. The sensitivity of the results to carbon dioxide fertilization is a primary focus as it is an important element of climate change that has not been considered in much of the previous literature. We estimate that carbon dioxide fertilization has a large positive impact that reduces the social cost of carbon dioxide with a much smaller effect on the other greenhouse gases. As a result, our estimates of the damage potentials of methane and nitrous oxide are much higher compared to estimates that ignore carbon dioxide fertilization. As a result, our base estimates of the damage potential for methane and nitrous oxide that include carbon dioxide fertilization are twice their respective global warming potentials. Our base estimate of the damage potential of sulphur hexafluoride is similar to the one previous estimate, both almost three times the global warming potential.

  17. Kolstad: EKC Dec 2005 Interpreting Estimated Environmental Kuznets Curves for Greenhouse Gases

    E-Print Network [OSTI]

    Kolstad, Charles

    Kolstad: EKC Dec 2005 Interpreting Estimated Environmental Kuznets Curves for Greenhouse Gases to interpret a relationship between income and carbon emissions in a country (the environmental Kuznets curve), it was primarily concerned with Environmental Kuznets Curves (EKC) for greenhouse gas emissions. The EKC literature

  18. Industrial Gases as a Vehicle for Competitiveness

    E-Print Network [OSTI]

    Dale, J. R.

    -based separation technology was developing to offer an alternative to cryogenic separation for those instances when neither high purity or cryogenic properties were required by the application. It resulted in gas of lower than 99.9995%, "five-nines", purity...INDUSTRIAL GASES AS A VEHICLE FOR COMPETITIVENESS James R. Dale, Director, Technology Programs, Airco Industrial Gases Division, The BOC Group, Inc., Murray Hill, New Jersey ABSTRACT Industrial gases are produced using compressed air...

  19. Particle entanglement in rotating gases

    SciTech Connect (OSTI)

    Liu Zhao; Fan Heng [Institute of Physics, Chinese Academy of Sciences, Beijing 100190 (China)

    2010-06-15T23:59:59.000Z

    In this paper, we investigate the particle entanglement in two-dimensional (2D) weakly interacting rotating Bose and Fermi gases. We find that both particle localization and vortex localization can be indicated by particle entanglement. We also use particle entanglement to show the occurrence of edge reconstruction of rotating fermions. The different properties of condensate phase and vortex liquid phase of bosons can be reflected by particle entanglement and in vortex liquid phase we construct the same trial wave function with that in [Phys. Rev. Lett. 87, 120405 (2001)] from the viewpoint of entanglement to relate the ground state with quantum Hall state. Finally, the relation between particle entanglement and interaction strength is studied.

  20. Granular gases under extreme driving

    E-Print Network [OSTI]

    W. Kang; J. Machta; E. Ben-Naim

    2010-08-06T23:59:59.000Z

    We study inelastic gases in two dimensions using event-driven molecular dynamics simulations. Our focus is the nature of the stationary state attained by rare injection of large amounts of energy to balance the dissipation due to collisions. We find that under such extreme driving, with the injection rate much smaller than the collision rate, the velocity distribution has a power-law high energy tail. The numerically measured exponent characterizing this tail is in excellent agreement with predictions of kinetic theory over a wide range of system parameters. We conclude that driving by rare but powerful energy injection leads to a well-mixed gas and constitutes an alternative mechanism for agitating granular matter. In this distinct nonequilibrium steady-state, energy cascades from large to small scales. Our simulations also show that when the injection rate is comparable with the collision rate, the velocity distribution has a stretched exponential tail.

  1. How are greenhouse gases related to agriculture? Greenhouse gases such as carbon dioxide occur

    E-Print Network [OSTI]

    levels are causing Earth's average global temperature to rise. Consequently, we experience changes States. How will climate change affect Michigan field crop agriculture? Global warming is likely to bring naturally in the atmosphere and keep the Earth warm, allowing us to survive on Earth. Over the last 200

  2. CATALYTIC OXIDATION OF S(IV) ON ACTIVATED CARBON IN AQUEOUS SUSPENSION: KINETICS AND MECHANISM

    E-Print Network [OSTI]

    Brodzinsky, Richard

    2012-01-01T23:59:59.000Z

    carbon has been used as a scrubber for gases and organicuse of activated carbon scrubbers is for the removal ofstyle studies of the scrubber system have been performed and

  3. An Infrared Spectral Database for Detection of Gases Emitted...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Database for Detection of Gases Emitted by Biomass Burning. An Infrared Spectral Database for Detection of Gases Emitted by Biomass Burning. Abstract: We report the construction of...

  4. atmospheric greenhouse gases: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    GASES BACKGROUND CiteSeer Summary: The Earths climate depends on the amount of solar radiation received and the atmospheric abundance of clouds and greenhouse gases. The...

  5. aerosol precursor gases: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    sunlight 11 GREENHOUSE GASES GREENHOUSE GASES BACKGROUND CiteSeer Summary: The Earths climate depends on the amount of solar radiation received and the atmospheric abundance of...

  6. Energy Efficiency and Greenhouse Gases | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Efficiency and Greenhouse Gases Energy Efficiency and Greenhouse Gases Mission The team establishes an energy conservation program, as deemed appropriate for LM operations...

  7. Light Collection in Liquid Noble Gases

    SciTech Connect (OSTI)

    McKinsey, Dan [Yale University

    2013-05-29T23:59:59.000Z

    Liquid noble gases are increasingly used as active detector materials in particle and nuclear physics. Applications include calorimeters and neutrino oscillation experiments as well as searches for neutrinoless double beta decay, direct dark matter, muon electron conversion, and the neutron electric dipole moment. One of the great advantages of liquid noble gases is their copious production of ultraviolet scintillation light, which contains information about event energy and particle type. I will review the scintillation properties of the various liquid noble gases and the means used to collect their scintillation light, including recent advances in photomultiplier technology and wavelength shifters.

  8. Carbon dioxide capture from power or process plant gases

    SciTech Connect (OSTI)

    Bearden, Mark D; Humble, Paul H

    2014-06-10T23:59:59.000Z

    The present invention are methods for removing preselected substances from a mixed flue gas stream characterized by cooling said mixed flue gas by direct contact with a quench liquid to condense at least one preselected substance and form a cooled flue gas without substantial ice formation on a heat exchanger. After cooling additional process methods utilizing a cryogenic approach and physical concentration and separation or pressurization and sorbent capture may be utilized to selectively remove these materials from the mixed flue gas resulting in a clean flue gas.

  9. Methods and compositions for removing carbon dioxide from a gaseous mixture

    DOE Patents [OSTI]

    Li, Jing; Wu, Haohan

    2014-06-24T23:59:59.000Z

    Provided is a method for adsorbing or separating carbon dioxide from a mixture of gases by passing the gas mixture through a porous three-dimensional polymeric coordination compound having a plurality of layers of two-dimensional arrays of repeating structural units, which results in a lower carbon dioxide content in the gas mixture. Thus, this invention provides useful compositions and methods for removal of greenhouse gases, in particular CO.sub.2, from industrial flue gases or from the atmosphere.

  10. Denitrification of combustion gases. [Patent application

    DOE Patents [OSTI]

    Yang, R.T.

    1980-10-09T23:59:59.000Z

    A method for treating waste combustion gas to remove the nitrogen oxygen gases therefrom is disclosed wherein the waste gas is first contacted with calcium oxide which absorbs and chemically reacts with the nitrogen oxide gases therein at a temperature from about 100/sup 0/ to 430/sup 0/C. The thus reacted calcium oxide (now calcium nitrate) is then heated at a temperature range between about 430/sup 0/ and 900/sup 0/C, resulting in regeneration of the calcium oxide and production of the decomposition gas composed of nitrogen and nitrogen oxide gas. The decomposition gases can be recycled to the calcium oxide contacting step to minimize the amount of nitrogen oxide gases in the final product gas.

  11. Voluntary reporting of greenhouse gases, 1995

    SciTech Connect (OSTI)

    NONE

    1996-07-01T23:59:59.000Z

    The Voluntary Reporting Program for greenhouse gases is part of an attempt by the U.S. Government to develop innovative, low-cost, and nonregulatory approaches to limit emissions of greenhouse gases. It is one element in an array of such programs introduced in recent years as part of the effort being made by the United States to comply with its national commitment to stabilize emissions of greenhouse gases under the Framework Convention on Climate Change. The Voluntary Reporting Program, developed pursuant to Section 1605(b) of the Energy Policy Act of 1992, permits corporations, government agencies, households, and voluntary organizations to report to the Energy Information Administration (EIA) on actions taken that have reduced or avoided emissions of greenhouse gases.

  12. Simultaneous gas-chromatographic determination of four toxic gases generally present in combustion atmospheres. Final report

    SciTech Connect (OSTI)

    Endecott, B.R.; Sanders, D.C.; Chaturvedi, A.K.

    1994-09-01T23:59:59.000Z

    Measurement of combustion gases produced by burning aircraft cabin materials poses a continuing limitation for smoke toxicity research. Since toxic effects of gases depend on both their concentrations and duration of exposures, frequent atmosphere sampling is necessary to define the concentration-time curve. A gas chromatographic method was developed for the simultaneous analyses of carbon monoxide (CO), hydrogen sulfide (H2S), sulfur dioxide (SO2), and hydrogen cyanide (HCN). The method utilized an MTI M200 dual-column gas chromatograph (GC) equipped with 4-m molecular sieve-5A and 8-m PoraPlot-U capillary columns and two low-volume, high-sensitivity thermal conductivity detectors. Detectability (ppm)/retention times (seconds) for the gases were: CO (100/28); H2S (50/26); SO2 (125/76); HCN (60/108). The method was effective for determining these gases in mixtures and in the combustion atmospheres generated by burning wool (CO, HCN, and H2S) and modacrylic (CO and HCN) fabrics. Common atmospheric gaseous or combustion products (oxygen, carbon dioxide, nitrogen, water vapor, and other volatiles) did not interfere with the analyses. However, filtration of the combustion atmospheres was necessary to prevent restriction of the GC sampling inlet by smoke particulates. The speed, sensitivity, and selectivity of this method make it suitable for smoke toxicity research and for evaluating performance of passenger protective breathing equipment.

  13. Removal of oxides of nitrogen from gases in multi-stage coal combustion

    DOE Patents [OSTI]

    Mollot, D.J.; Bonk, D.L.; Dowdy, T.E.

    1998-01-13T23:59:59.000Z

    Polluting NO{sub x} gas values are removed from off-gas of a multi-stage coal combustion process which includes an initial carbonizing reaction, firing of char from this reaction in a fluidized bed reactor, and burning of gases from the carbonizing and fluidized bed reactions in a topping combustor having a first, fuel-rich zone and a second, fuel-lean zone. The improvement by means of which NO{sub x} gases are removed is directed to introducing NO{sub x}-free oxidizing gas such as compressor air into the second, fuel-lean zone and completing combustion with this source of oxidizing gas. Excess air fed to the fluidized bed reactor is also controlled to obtain desired stoichiometry in the first, fuel-rich zone of the topping combustor. 2 figs.

  14. Removal of oxides of nitrogen from gases in multi-stage coal combustion

    DOE Patents [OSTI]

    Mollot, Darren J. (Morgantown, WV); Bonk, Donald L. (Louisville, OH); Dowdy, Thomas E. (Orlando, FL)

    1998-01-01T23:59:59.000Z

    Polluting NO.sub.x gas values are removed from off-gas of a multi-stage coal combustion process which includes an initial carbonizing reaction, firing of char from this reaction in a fluidized bed reactor, and burning of gases from the carbonizing and fluidized bed reactions in a topping combustor having a first, fuel-rich zone and a second, fuel-lean zone. The improvement by means of which NO.sub.x gases are removed is directed to introducing NO.sub.x -free oxidizing gas such as compressor air into the second, fuel-lean zone and completing combustion with this source of oxidizing gas. Excess air fed to the fluidized bed reactor is also controlled to obtain desired stoichiometry in the first, fuel-rich zone of the topping combustor.

  15. HELSINKI UNIVERSITY OF TECHNOLOGY ENE-47.153 Greenhouse gases andGreenhouse gases and

    E-Print Network [OSTI]

    Zevenhoven, Ron

    in gas turbinecombustion in gas turbine HELSINKI UNIVERSITY OF TECHNOLOGY ENE-47.153 Effect of COEffect-depleting gases ·· COCO22 removal for gas purificationremoval for gas purification ·· COCO22 removal for greenhouse gas emissions reductionremoval for greenhouse gas emissions reduction ·· Other greenhouse gases

  16. Investigation of feasibility of injecting power plant waste gases for enhanced coalbed methane recovery from low rank coals in Texas 

    E-Print Network [OSTI]

    Saugier, Luke Duncan

    2004-09-30T23:59:59.000Z

    Greenhouse gases such as carbon dioxide (CO2) may be to blame for a gradual rise in the average global temperature. The state of Texas emits more CO2 than any other state in the U.S., and a large fraction of emissions are ...

  17. Method of producing carbon coated nano- and micron-scale particles

    DOE Patents [OSTI]

    Perry, W. Lee; Weigle, John C; Phillips, Jonathan

    2013-12-17T23:59:59.000Z

    A method of making carbon-coated nano- or micron-scale particles comprising entraining particles in an aerosol gas, providing a carbon-containing gas, providing a plasma gas, mixing the aerosol gas, the carbon-containing gas, and the plasma gas proximate a torch, bombarding the mixed gases with microwaves, and collecting resulting carbon-coated nano- or micron-scale particles.

  18. Stationary light in cold atomic gases

    E-Print Network [OSTI]

    Gor Nikoghosyan; Michael Fleischhauer

    2009-09-16T23:59:59.000Z

    We discuss stationary light created by a pair of counter-propagating control fields in Lambda-type atomic gases with electromagnetically induced transparency for the case of negligible Doppler broadening. In this case the secular approximation used in the discussion of stationary light in hot vapors is no longer valid. We discuss the quality of the effective light-trapping system and show that in contrast to previous claims it is finite even for vanishing ground-state dephasing. The dynamics of the photon loss is in general non exponential and can be faster or slower than in hot gases.

  19. Summary Elevated concentrations of atmospheric carbon dioxide ([CO2]) and tropospheric ozone ([O3]) have the poten-

    E-Print Network [OSTI]

    Summary Elevated concentrations of atmospheric carbon dioxide ([CO2]) and tropospheric ozone ([O3 gases (greenhouse gases) altered by human activities (IPCC 2007), only carbon dioxide (CO2 vegeta- tion properties affect local and regional climate, as well as how atmospheric forcing

  20. CARBON-CARBON COMPOSITE ALLCOMP Carbon-Carbon Composite

    E-Print Network [OSTI]

    Rollins, Andrew M.

    materials. MATERIALS AND DESIRED DATA Carbon-Carbon Composites(T300 & SWB): Crush Resistance, Bend StrengthCARBON-CARBON COMPOSITE ALLCOMP Carbon-Carbon Composite · C-C supplied in two forms · T300: C strength 4340 steel, carbon-carbon composite, and Carbon-Silicon Carbide composite were tested to examine

  1. In-Situ Microbial Conversion of Sequestered Greenhouse Gases

    SciTech Connect (OSTI)

    Scott, A R; Mukhopadhyay, M; Balin, D F

    2012-09-06T23:59:59.000Z

    The objectives of the project are to use microbiological in situ bioconversion technology to convert sequestered or naturally-occurring greenhouse gases, including carbon dioxide and carbon monoxide, into methane and other useful organic compounds. The key factors affecting coal bioconversion identified in this research include (1) coal properties, (2) thermal maturation and coalification process, (3) microbial population dynamics, (4) hydrodynamics (5) reservoir conditions, and (6) the methodology of getting the nutrients into the coal seams. While nearly all cultures produced methane, we were unable to confirm sustained methane production from the enrichments. We believe that the methane generation may have been derived from readily metabolized organic matter in the coal samples and/or biosoluble organic material in the coal formation water. This raises the intriguing possibility that pretreatment of the coal in the subsurface to bioactivate the coal prior to the injection of microbes and nutrients might be possible. We determined that it would be more cost effective to inject nutrients into coal seams to stimulate indigenous microbes in the coal seams, than to grow microbes in fermentation vats and transport them to the well site. If the coal bioconversion process can be developed on a larger scale, then the cost to generate methane could be less than $1 per Mcf

  2. Emissions of greenhouse gases from the use of transportation fuels and electricity. Volume 2: Appendixes A--S

    SciTech Connect (OSTI)

    DeLuchi, M.A. [Argonne National Lab., IL (United States); [Univ. of California, Davis, CA (United States). Inst. of Transportation Studies

    1993-11-01T23:59:59.000Z

    This volume contains the appendices to the report on Emission of Greenhouse Gases from the Use of Transportation Fuels and Electricity. Emissions of methane, nitrous oxide, carbon monoxide, and other greenhouse gases are discussed. Sources of emission including vehicles, natural gas operations, oil production, coal mines, and power plants are covered. The various energy industries are examined in terms of greenhouse gas production and emissions. Those industries include electricity generation, transport of goods via trains, trucks, ships and pipelines, coal, natural gas and natural gas liquids, petroleum, nuclear energy, and biofuels.

  3. Method for enhancing microbial utilization rates of gases using perfluorocarbons

    DOE Patents [OSTI]

    Turick, Charles E. (Idaho Falls, ID)

    1997-01-01T23:59:59.000Z

    A method of enhancing the bacterial reduction of industrial gases using perfluorocarbons (PFCs) is disclosed. Because perfluorocarbons (PFCs) allow for a much greater solubility of gases than water does, PFCs have the potential to deliver gases in higher concentrations to microorganisms when used as an additive to microbial growth media thereby increasing the rate of the industrial gas conversion to economically viable chemicals and gases.

  4. Method for enhancing microbial utilization rates of gases using perfluorocarbons

    DOE Patents [OSTI]

    Turick, C.E.

    1997-06-10T23:59:59.000Z

    A method of enhancing the bacterial reduction of industrial gases using perfluorocarbons (PFCs) is disclosed. Because perfluorocarbons (PFCs) allow for a much greater solubility of gases than water does, PFCs have the potential to deliver gases in higher concentrations to microorganisms when used as an additive to microbial growth media thereby increasing the rate of the industrial gas conversion to economically viable chemicals and gases. 3 figs.

  5. Emissions of greenhouse gases in the United States, 1987--1994

    SciTech Connect (OSTI)

    NONE

    1995-09-25T23:59:59.000Z

    The Energy Information Administration (EIA) is required by the Energy Policy Act of 1992 to prepare a report on aggregate US national emissions of greenhouse gases for the period 1987--1992, with annual updates thereafter. This is the third annual update report,covering national emissions over the period 1987--1993, with preliminary estimates of US carbon dioxide and halocarbon emissions for 1994. Calculating national aggregate emissions(or ``national inventories``) of greenhouse gases is a recently developed form of intellectual endeavor. Greenhouse gas emissions are rarely measured directly or reported to statistical agencies. Thus, to prepare emissions inventories usually requires inferring emissions indirectly from information collected for other purposes. Both the available information and the inferences drawn may be of varying reliability. Chapter 1 of this report briefly recapitulates some background information about global climate change and the greenhouse effect and discusses important recent developments in global climate change activities. Chapters 2 through 6 cover emissions of carbon dioxide, methane, nitrous oxide, halocarbons, and criteria pollutants, respectively. Chapter 7 describes potential sequestration and emissions of greenhouse gases as a result of land use changes.

  6. New fluorescence techniques for detecting noble gases

    SciTech Connect (OSTI)

    Whitaker, T.J.; Cannon, B.D.; Bushaw, B.A.

    1986-10-01T23:59:59.000Z

    Two new concepts for detecting noble gases are reported. Both techniques involve formation of the long-lived 1s/sup 5/ metastable state of noble gases. The first technique utilizes the photon-burst method and should be capable of isotopically selective detection at extremely small relative abundances. The second concept incorporates a shelving technique that stores noble gas atoms in the metastable state and then pumps these atoms to a higher excited state that radiatively cascades to the ground state, emitting vacuum ultraviolet (vuv) photons. A significant advantage is that AlGaAs diode lasers can be used for the techniques rather than continuous wave cw dye lasers. 5 refs., 1 fig.

  7. It's not (just) ``the environment, stupid!'' Values, motivations, and routes to engagement of people adopting lower-carbon lifestyles

    E-Print Network [OSTI]

    Colorado at Boulder, University of

    changes to one's lifestyle in order to reduce one's carbon footprint (i.e. the amount of greenhouse gases-average carbon footprint' (although that would be true of many of those involved in this study); `lower- carbon' refers to individuals having a lower carbon footprint now relative to some time previously, through

  8. Glass Membrane For Controlled Diffusion Of Gases

    DOE Patents [OSTI]

    Shelby, James E. (Alfred Station, NY); Kenyon, Brian E. (Pittsburgh, PA)

    2001-05-15T23:59:59.000Z

    A glass structure for controlled permeability of gases includes a glass vessel. The glass vessel has walls and a hollow center for receiving a gas. The glass vessel contains a metal oxide dopant formed with at least one metal selected from the group consisting of transition metals and rare earth metals for controlling diffusion of the gas through the walls of the glass vessel. The vessel releases the gas through its walls upon exposure to a radiation source.

  9. Scanning electron microscopy of cold gases

    E-Print Network [OSTI]

    Santra, Bodhaditya

    2015-01-01T23:59:59.000Z

    Ultracold quantum gases offer unique possibilities to study interacting many-body quantum systems. Probing and manipulating such systems with ever increasing degree of control requires novel experimental techniques. Scanning electron microscopy is a high resolution technique which can be used for in situ imaging, single site addressing in optical lattices and precision density engineering. Here, we review recent advances and achievements obtained with this technique and discuss future perspectives.

  10. Method for introduction of gases into microspheres

    DOE Patents [OSTI]

    Hendricks, Charles D. (Livermore, CA); Koo, Jackson C. (San Ramon, CA); Rosencwaig, Allan (Danville, CA)

    1981-01-01T23:59:59.000Z

    A method for producing small hollow glass spheres filled with a gas by introduction of the gas during formation of the hollow glass spheres. Hollow glass microspheres having a diameter up to about 500.mu. with both thin walls (0.5 to 4.mu.) and thick walls (5 to 20.mu.) that contain various fill gases, such as Ar, Kr, Xe, Br, DT, H.sub.2, D.sub.2, He, N.sub.2, Ne, CO.sub.2, etc. in the interior thereof, can be produced by the diffusion of the fill gas or gases into the microsphere during the formation thereof from a liquid droplet of glass-forming solution. This is accomplished by filling at least a portion of the multiple-zone drop-furnace used in producing hollow microspheres with the gas or gases of interest, and then taking advantage of the high rate of gaseous diffusion of the fill gas through the wall of the gel membrane before it transforms into a glass microsphere as it is processed in the multiple-zone furnace. Almost any gas can be introduced into the inner cavity of a glass microsphere by this method during the formation of the microsphere provided that the gas is diffused into the gel membrane or microsphere prior to its transformation into glass. The process of this invention provides a significant savings of time and related expense of filling glass microspheres with various gases. For example, the time for filling a glass microballoon with 1 atmosphere of DT is reduced from about two hours to a few seconds.

  11. Seeded optical breakdown of molecular and noble gases

    SciTech Connect (OSTI)

    Polynkin, Pavel; Scheller, Maik; Moloney, Jerome V. [College of Optical Sciences, University of Arizona 1630 E. University Blvd., Tucson, Arizona 85721 (United States)

    2012-07-30T23:59:59.000Z

    We report experimental results on the dual laser-pulse plasma excitation in various gases at atmospheric pressure. Dilute plasma channels generated through filamentation of ultraintense femtosecond laser pulses in air, argon, and helium are densified through the application of multi-Joule nanosecond heater pulses. Optical breakdown in atomic gases can be achieved for considerably longer delays between femtosecond and nanosecond pulses compared to that in molecular gases. The densification of the seed channel in molecular gases is always accompanied by its fragmentation into discrete bubbles, while in atomic gases the densified channel remains smooth and continuous.

  12. Biological production of acetic acid from waste gases with Clostridium ljungdahlii

    DOE Patents [OSTI]

    Gaddy, James L. (Fayetteville, AR)

    1998-01-01T23:59:59.000Z

    A method and apparatus for converting waste gases from industrial processes such as oil refining, carbon black, coke, ammonia, and methanol production, into useful products. The method includes introducing the waste gases into a bioreactor where they are fermented to various organic acids or alcohols by anaerobic bacteria within the bioreactor. These valuable end products are then recovered, separated and purified. In an exemplary recovery process, the bioreactor raffinate is passed through an extraction chamber into which one or more non-inhibitory solvents are simultaneously introduced to extract the product. Then, the product is separated from the solvent by distillation. Gas conversion rates can be maximized by use of centrifuges, hollow fiber membranes, or other means of ultrafiltration to return entrained anaerobic bacteria from the bioreactor raffinate to the bioreactor itself, thus insuring the highest possible cell concentration.

  13. Biological production of acetic acid from waste gases with Clostridium ljungdahlii

    DOE Patents [OSTI]

    Gaddy, J.L.

    1998-09-15T23:59:59.000Z

    A method and apparatus are disclosed for converting waste gases from industrial processes such as oil refining, carbon black, coke, ammonia, and methanol production, into useful products. The method includes introducing the waste gases into a bioreactor where they are fermented to various organic acids or alcohols by anaerobic bacteria within the bioreactor. These valuable end products are then recovered, separated and purified. In an exemplary recovery process, the bioreactor raffinate is passed through an extraction chamber into which one or more non-inhibitory solvents are simultaneously introduced to extract the product. Then, the product is separated from the solvent by distillation. Gas conversion rates can be maximized by use of centrifuges, hollow fiber membranes, or other means of ultrafiltration to return entrained anaerobic bacteria from the bioreactor raffinate to the bioreactor itself, thus insuring the highest possible cell concentration. 5 figs.

  14. Process for removal of ammonia and acid gases from contaminated waters

    DOE Patents [OSTI]

    King, C.J.; Mackenzie, P.D.

    1982-09-03T23:59:59.000Z

    Contaminating basic gases, i.e., ammonia and acid gases, e.g., carbon dioxide, are removed from process waters or waste waters in a combined extraction and stripping process. Ammonia in the form of ammonium ion is extracted by an immiscible organic phase comprising a liquid cation exchange component, especially an organic phosphoric acid derivative, and preferably di-2-ethyl hexyl phosphoric acid, dissolved in an alkyl hydrocarbon, aryl hydrocarbon, higher alcohol, oxygenated hydrocarbon, halogenated hydrocarbon, and mixtures thereof. Concurrently, the acidic gaseous contaminants are stripped from the process or waste waters by stripping with stream, air, nitrogen, or the like. The liquid cation exchange component has the ammonia stripped therefrom by heating, and the component may be recycled to extract additional amounts of ammonia.

  15. Process for removal of ammonia and acid gases from contaminated waters

    DOE Patents [OSTI]

    King, C. Judson (Kensington, CA); MacKenzie, Patricia D. (Berkeley, CA)

    1985-01-01T23:59:59.000Z

    Contaminating basic gases, i.e., ammonia, and acid gases, e.g., carbon dioxide, are removed from process waters or waste waters in a combined extraction and stripping process. Ammonia in the form of ammonium ion is extracted by an immiscible organic phase comprising a liquid cation exchange component, especially an organic phosphoric acid derivative, and preferably di-2-ethyl hexyl phosphoric acid, dissolved in an alkyl hydrocarbon, aryl hydrocarbon, higher alcohol, oxygenated hydrocarbon, halogenated hydrocarbon, and mixtures thereof. Concurrently, the acidic gaseous contaminants are stripped from the process or waste waters by stripping with steam, air, nitrogen, or the like. The liquid cation exchange component has the ammonia stripped therefrom by heating, and the component may be recycled to extract additional amounts of ammonia.

  16. Voluntary reporting of greenhouse gases under Section 1605(b) of the Energy Policy Act of 1992: General Guidelines

    SciTech Connect (OSTI)

    Not Available

    1994-10-01T23:59:59.000Z

    Because of concerns with the growing threat of global climate change from increasing emissions of greenhouse gases, Congress authorized a voluntary program for the public to report achievements in reducing those gases. This document offers guidance on recording historic and current greenhouse gas emissions, emissions reductions, and carbon sequestration. Under the Energy Policy Act (EPAct) reporters will have the opportunity to highlight specific achievements. If you have taken actions to lessen the greenhouse gas effect, either by decreasing greenhouse gas emissions or by sequestering carbon, the Department of Energy (DOE) encourages you to report your achievements under this program. The program has two related, but distinct parts. First, the program offers you an opportunity to report your annual emissions of greenhouse gases. Second, the program records your specific projects to reduce greenhouse gas emissions and increase carbon sequestration. Although participants in the program are strongly encouraged to submit reports on both, reports on either annual emissions or emissions reductions and carbon sequestration projects will be accepted. These guidelines and the supporting technical documents outline the rationale for the program and approaches to analyzing emissions and emissions reduction projects. Your annual emissions and emissions reductions achievements will be reported.

  17. Swansea University Carbon Management Plan 2010 -2020 SUMMARY Swansea University

    E-Print Network [OSTI]

    Grant, P. W.

    measurement including the global warming potential (GWP) of each of the six greenhouses gases expressed in terms of the Global Warming Potential (GWP) of one unit of carbon dioxide. The six key emissions covered to this the emissions due to burning biologically sequestered carbon (e.g. biomass or biofuels) are also not included

  18. Cobalt carbonyl catalyzed olefin hydroformylation in supercritical carbon dioxide

    DOE Patents [OSTI]

    Rathke, J.W.; Klingler, R.J.

    1993-03-30T23:59:59.000Z

    A method of olefin hydroformylation is provided wherein an olefin reacts with a carbonyl catalyst and with reaction gases such as hydrogen and carbon monoxide in the presence of a supercritical reaction solvent, such as carbon dioxide. The invention provides higher yields of n-isomer product without the gas-liquid mixing rate limitation seen in conventional Oxo processes using liquid media.

  19. Optimal Production Policy under the Carbon Emission Market

    E-Print Network [OSTI]

    Touzi, Nizar

    with the reduction of the green- house gases including CO2 and is accepted by several countries e.g. Euro- pean Union Scheme (EU ETS) which provides a way to control the emission of CO2 within carbon polluters throughOptimal Production Policy under the Carbon Emission Market Redouane Belaouar Arash Fahim Nizar

  20. The origin of hydrothermal and other gases in the Kenya Rift Valley

    SciTech Connect (OSTI)

    Darling, W.G. [British Geological Survey, Wallingford (United Kingdom)] [British Geological Survey, Wallingford (United Kingdom); Griesshaber, E. [Max-Planck Institut fuer Chemie, Mainz (Germany)] [Max-Planck Institut fuer Chemie, Mainz (Germany); Andrews, J.N. [Univ. of Reading (United Kingdom)] [and others] [Univ. of Reading (United Kingdom); and others

    1995-06-01T23:59:59.000Z

    The Kenya Rift Valley (KRV) is part of a major continental rift system from which much outgassing is presently occurring. Previous research on gases in the KRV has tended to concentrate on their geothermal implications; the present paper is an attempt to broaden the interpretation by consideration of new data including helium and carbon isotope analyses from a wide cross-section of sites. In order to do this, gases have been divided into categories dependent on origin. N{sub 2} and noble gases are for the most part atmospherically derived, although their relative concentrations may be altered from ASW ratios by various physical processes. Reduced carbon (CH{sub 4} and homologues) appears to be exclusively derived from the shallow crust, with thermogenic {delta}{sup 13}C values averaging -25{per_thousand} PDB for CH{sub 4}. H{sub 2} is likely also to be crustally formed. CO{sub 2}, generally a dominant constituent, has a narrow {delta}{sup 13}C range averaging -3.7{per_thousand} PDB, and is likely to be derived with little modification from the upper mantle. Consideration of the ratio C/{sup 3}He supports this view in most cases. Sulphur probably also originates there. Ratios of {sup 3}He/{sup 4}He reach a MORB-like maximum of 8.0 R/R{sub A} and provide the best indication of an upper mantle source of gases beneath the KRV. A correlation between {sup 3}He/{sup 4}He and the hydrocarbon parameter log (C{sub 1}/{Sigma}C{sub 2-4}) appears to be primarily temperature related. The highest {sup 3}He/{sup 4}He ratios in spring waters are associated with basalts, perhaps because of the leaching of basalt glasses. There may be a structural control on {sup 3}He/{sup 4}He ratios in the KRV as a whole.

  1. Activated carbon fiber composite material and method of making

    DOE Patents [OSTI]

    Burchell, Timothy D. (Oak Ridge, TN); Weaver, Charles E. (Knoxville, TN); Chilcoat, Bill R. (Knoxville, TN); Derbyshire, Frank (Lexington, KY); Jagtoyen, Marit (Lexington, KY)

    2001-01-01T23:59:59.000Z

    An activated carbon fiber composite for separation and purification, or catalytic processing of fluids is described. The activated composite comprises carbon fibers rigidly bonded to form an open, permeable, rigid monolith capable of being formed to near-net-shape. Separation and purification of gases are effected by means of a controlled pore structure that is developed in the carbon fibers contained in the composite. The open, permeable structure allows the free flow of gases through the monolith accompanied by high rates of adsorption. By modification of the pore structure and bulk density the composite can be rendered suitable for applications such as gas storage, catalysis, and liquid phase processing.

  2. Activated carbon fiber composite material and method of making

    DOE Patents [OSTI]

    Burchell, Timothy D. (Oak Ridge, TN); Weaver, Charles E. (Knoxville, TN); Chilcoat, Bill R. (Knoxville, TN); Derbyshire, Frank (Lexington, KY); Jagtoyen, Marit (Lexington, KY)

    2000-01-01T23:59:59.000Z

    An activated carbon fiber composite for separation and purification, or catalytic processing of fluids is described. The activated composite comprises carbon fibers rigidly bonded to form an open, permeable, rigid monolith capable of being formed to near-net-shape. Separation and purification of gases are effected by means of a controlled pore structure that is developed in the carbon fibers contained in the composite. The open, permeable structure allows the free flow of gases through the monolith accompanied by high rates of adsorption. By modification of the pore structure and bulk density the composite can be rendered suitable for applications such as gas storage, catalysis, and liquid phase processing.

  3. System and method for coproduction of activated carbon and steam/electricity

    DOE Patents [OSTI]

    Srinivasachar, Srivats (Sturbridge, MA); Benson, Steven (Grand Forks, ND); Crocker, Charlene (Newfolden, MN); Mackenzie, Jill (Carmel, IN)

    2011-07-19T23:59:59.000Z

    A system and method for producing activated carbon comprising carbonizing a solid carbonaceous material in a carbonization zone of an activated carbon production apparatus (ACPA) to yield a carbonized product and carbonization product gases, the carbonization zone comprising carbonaceous material inlet, char outlet and carbonization gas outlet; activating the carbonized product via activation with steam in an activation zone of the ACPA to yield activated carbon and activation product gases, the activation zone comprising activated carbon outlet, activation gas outlet, and activation steam inlet; and utilizing process gas comprising at least a portion of the carbonization product gases or a combustion product thereof; at least a portion of the activation product gases or a combustion product thereof; or a combination thereof in a solid fuel boiler system that burns a solid fuel boiler feed with air to produce boiler-produced steam and flue gas, the boiler upstream of an air heater within a steam/electricity generation plant, said boiler comprising a combustion zone, a boiler-produced steam outlet and at least one flue gas outlet.

  4. AN ISSUE OF PERMANENCE: ASSESSING THE EFFECTIVENESS OF TEMPORARY CARBON STORAGE

    E-Print Network [OSTI]

    with a `leaky' carbon sequestration reservoir, we argue that this is an issue that applies to just about all that the value of relatively deep ocean carbon sequestration can be nearly equivalent to permanent sequestration gases using carbon sequestration technologies (Herzog et al., 2000; Herzog, 2001) is being proposed

  5. CARBON SEQUESTRATION VIA DIRECT INJECTION Howard J. Herzog, Ken Caldeira, and Eric Adams

    E-Print Network [OSTI]

    CARBON SEQUESTRATION VIA DIRECT INJECTION Howard J. Herzog, Ken Caldeira, and Eric Adams and sequestration. Carbon sequestration is often associated with the planting of trees. As they mature, the trees INTRODUCTION The build-up of carbon dioxide (CO2) and other greenhouse gases in the Earth's atmosphere has

  6. Report TKK-ENY-9 Mineral carbonation for long-term storage of CO2

    E-Print Network [OSTI]

    Zevenhoven, Ron

    ://www.entek.chalmers.se/~anly/symp/symp2001.html) "CO2 sequestration by magnesium silicate mineral carbonation in Finland" Ron Zevenhoven of magnesium oxide-based mineral carbonation for CO2 sequestration" Ron Zevenhoven, Jens Kohlmann. underReport TKK-ENY-9 Mineral carbonation for long-term storage of CO2 from flue gases Jens Kohlmann 1

  7. Purchase, Delivery, and Storage of Gases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Science (SC)IntegratedSpeedingTechnicalPurchase, Delivery, and Storage of Gases Print ALS users

  8. Use of sulfide-containing liquors for removing mercury from flue gases

    DOE Patents [OSTI]

    Nolan, Paul S. (North Canton, OH); Downs, William (Alliance, OH); Bailey, Ralph T. (Uniontown, OH); Vecci, Stanley J. (Alliance, OH)

    2003-01-01T23:59:59.000Z

    A method and apparatus for reducing and removing mercury in industrial gases, such as a flue gas, produced by the combustion of fossil fuels, such as coal, adds sulfide ions to the flue gas as it passes through a scrubber. Ideally, the source of these sulfide ions may include at least one of: sulfidic waste water, kraft caustic liquor, kraft carbonate liquor, potassium sulfide, sodium sulfide, and thioacetamide. The sulfide ion source is introduced into the scrubbing liquor as an aqueous sulfide species. The scrubber may be either a wet or dry scrubber for flue gas desulfurization systems.

  9. Use of sulfide-containing liquors for removing mercury from flue gases

    DOE Patents [OSTI]

    Nolan, Paul S.; Downs, William; Bailey, Ralph T.; Vecci, Stanley J.

    2006-05-02T23:59:59.000Z

    A method and apparatus for reducing and removing mercury in industrial gases, such as a flue gas, produced by the combustion of fossil fuels, such as coal, adds sulfide ions to the flue gas as it passes through a scrubber. Ideally, the source of these sulfide ions may include at least one of: sulfidic waste water, kraft caustic liquor, kraft carbonate liquor, potassium sulfide, sodium sulfide, and thioacetamide. The sulfide ion source is introduced into the scrubbing liquor as an aqueous sulfide species. The scrubber may be either a wet or dry scrubber for flue gas desulfurization systems.

  10. Method for controlling corrosion in thermal vapor injection gases

    DOE Patents [OSTI]

    Sperry, John S. (Houston, TX); Krajicek, Richard W. (Houston, TX)

    1981-01-01T23:59:59.000Z

    An improvement in the method for producing high pressure thermal vapor streams from combustion gases for injection into subterranean oil producing formations to stimulate the production of viscous minerals is described. The improvement involves controlling corrosion in such thermal vapor gases by injecting water near the flame in the combustion zone and injecting ammonia into a vapor producing vessel to contact the combustion gases exiting the combustion chamber.

  11. The greenhouse gases HFCs, PFCs Danish consumption and emissions, 2007

    E-Print Network [OSTI]

    The greenhouse gases HFCs, PFCs and SF6 Danish consumption and emissions, 2007 Tomas Sander Poulsen AND EMISSION OF F-GASES 7 1.1.1 Consumption 7 1.1.2 Emission 7 1.1.3 Trends in total GWP contribution from F 21 4 EMISSION OF F-GASES 23 4.1.1 Emissions of HFCs from refrigerants 23 4.1.2 Emissions of HFCs from

  12. Theory of ultracold atomic Fermi gases

    SciTech Connect (OSTI)

    Giorgini, Stefano; Pitaevskii, Lev P.; Stringari, Sandro [Dipartimento di Fisica, Universita di Trento and CNR-INFM BEC Center, I-38050 Povo, Trento (Italy); Dipartimento di Fisica, Universita di Trento and CNR-INFM BEC Center, I-38050 Povo, Trento, Italy and Kapitza Institute for Physical Problems, ul. Kosygina 2, 117334 Moscow (Russian Federation); Dipartimento di Fisica, Universita di Trento and CNR-INFM BEC Center, I-38050 Povo, Trento (Italy)

    2008-10-15T23:59:59.000Z

    The physics of quantum degenerate atomic Fermi gases in uniform as well as in harmonically trapped configurations is reviewed from a theoretical perspective. Emphasis is given to the effect of interactions that play a crucial role, bringing the gas into a superfluid phase at low temperature. In these dilute systems, interactions are characterized by a single parameter, the s-wave scattering length, whose value can be tuned using an external magnetic field near a broad Feshbach resonance. The BCS limit of ordinary Fermi superfluidity, the Bose-Einstein condensation (BEC) of dimers, and the unitary limit of large scattering length are important regimes exhibited by interacting Fermi gases. In particular, the BEC and the unitary regimes are characterized by a high value of the superfluid critical temperature, on the order of the Fermi temperature. Different physical properties are discussed, including the density profiles and the energy of the ground-state configurations, the momentum distribution, the fraction of condensed pairs, collective oscillations and pair-breaking effects, the expansion of the gas, the main thermodynamic properties, the behavior in the presence of optical lattices, and the signatures of superfluidity, such as the existence of quantized vortices, the quenching of the moment of inertia, and the consequences of spin polarization. Various theoretical approaches are considered, ranging from the mean-field description of the BCS-BEC crossover to nonperturbative methods based on quantum Monte Carlo techniques. A major goal of the review is to compare theoretical predictions with available experimental results.

  13. adjacente dos gases: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    nature Le Roy, Robert J. 437 Classical disordered ground states: Super-ideal gases and stealth and equi-luminous materials Chemistry Websites Summary: Classical disordered...

  14. Finalize Historic National Program to Reduce Greenhouse Gases...

    Open Energy Info (EERE)

    Finalize Historic National Program to Reduce Greenhouse Gases and Improve Fuel Economy for Cars and Trucks Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Finalize...

  15. Finite Temperature Gases of Fermionic Strings

    E-Print Network [OSTI]

    Shyamoli Chaudhuri

    2005-09-12T23:59:59.000Z

    We show that in the absence of a Ramond-Ramond sector both the type IIA and type IIB free string gases have a thermal instability due to low temperature tachyon modes. The gas of free IIA strings undergoes a thermal duality transition into a gas of free IIB strings at the self-dual temperature. The free heterotic string gas is a tachyon-free ensemble with gauge symmetry SO(16)$\\times$SO(16) in the presence of a timelike Wilson line background. It exhibits a holographic duality relation undergoing a self-dual phase transition with positive free energy and positive specific heat. The type IB open and closed string ensemble is related by thermal duality to the type I' string ensemble. We identify the order parameter for the Kosterlitz-Thouless phase transition from a low temperature gas of short open strings to a high temperature long string phase at or below T_C. Note Added (Sep 2005).

  16. Continuous cryopump with a method for removal of solidified gases

    DOE Patents [OSTI]

    Carlson, L.W.; Herman, H.

    1988-05-05T23:59:59.000Z

    An improved cryopump for the removal of gases from a high vacuum, comprising a cryopanel incorporating honeycomb structure, refrigerant means thermally connected to the cryopanel, and a rotatable channel moving azimuthally around an axis located near the center of the cryopanel, removing gases adsorbed within the honeycomb structure by subliming them and conducting them outside the vacuum vessel. 4 figs.

  17. AMIII Termodinamica dos Gases Ideais 17 de Janeiro de 2002

    E-Print Network [OSTI]

    Natário, José

    AMIII ­ Termodinâ??amica dos Gases Ideais 17 de Janeiro de 2002 N moles de um gâ??as ideal em equil dos gases ideais). A Primeira Lei da Termodinâ??amica afirma que existe uma funâ?şcâ?ťao E : M # R, dita pela Segunda Lei da Termodinâ??amica. 2 #12;

  18. Biological Removal of Siloxanes from Landfill and Digester Gases

    E-Print Network [OSTI]

    Biological Removal of Siloxanes from Landfill and Digester Gases: Opportunities and Challenges S U) presents challenges for using landfill and digester gases as energy fuels because of the formation volatilize from waste at landfills and wastewater treatment plants (1). As a result, biogas produced

  19. Measurement of transient nonlinear refractive index in gases using xenon

    E-Print Network [OSTI]

    Milchberg, Howard

    Measurement of transient nonlinear refractive index in gases using xenon supercontinuum single measurement of ultrafast high field processes using modest energy lasers, with pump and probe pulses totaling) and instrument resolution. The ultrafast nonlinear Kerr effect in glass, and in Ar, N2, and N2O gases is measured

  20. A Novel "Green" Fully-integrated Ultrasensitive RFID-enabled Gas Sensor Utilizing Inkjet-printed Antennas and Carbon Nanotubes

    E-Print Network [OSTI]

    Tentzeris, Manos

    -cost paper substrate. Carbon nanotube composites change their electric properties (e.g. resistance. Single-Walled Carbon Nanotube (SWCNT) composites were found to have electrical properties highly sensitive to extremely small quantities of gases, such as ammonia (NH3), carbon dioxide (C02), nitrogen

  1. ACID GASES IN CO2-RICH SUBSURFACE GEOLOGIC ENVIRONMENTS

    SciTech Connect (OSTI)

    Chialvo, Ariel A [ORNL] [ORNL; Vlcek, Lukas [ORNL] [ORNL; Cole, David [Ohio State University] [Ohio State University

    2013-01-01T23:59:59.000Z

    The analysis of species behavior involving dilute fluid environments has been crucial for the advance of modern solvation thermodynamics through molecular-based formalisms to guide the development of macroscopic regression tools in the description of fluid behavior and correlation of experimental data (Chialvo 2013). Dilute fluid environments involving geologic formations are of great theoretical and practical relevance regardless of the thermodynamic state conditions. The most challenging systems are those involving highly compressible and reactive confined environments, i.e., where small perturbations of pressure and/or temperature can trigger considerable density changes. This in turn can alter significantly the species solvation, their preferential solvation, and consequently, their reactivity with one another and with the surrounding mineral surfaces whose outcome is the modification of the substrate porosity and permeability, and ultimately, the integrity of the mineral substrates. Considering that changes in porosity and permeability resulting from dissolution and precipitation phenomena in confined environments are at the core of the aqueous CO2-mineral interactions, and that caprock integrity (e.g., sealing capacity) depends on these key parameters, it is imperative to gain fundamental understanding of the mineral-fluid interfacial phenomena and fluid-fluid equilibria under mineral confinement at subsurface conditions. In order to undertand the potential effects of acid gases as contaminants of supercritical CO2 streams, in the next section we will discuss the thermodynamic behavior of CO2 fluid systems by addressing two crucial issues in the context of carbon capture, utilization and sequestration (CCUS) technologies: (i) Why should we consider (acid gas) CO2 impurities? and (ii) Why are CO2 fluid - mineral interactions of paramount relevance?

  2. Case Studies of Potential Facility-Scale and Utility-Scale Non-Hydro Renewable Energy Projects across Reclamation

    SciTech Connect (OSTI)

    Haase, S.; Burman, K.; Dahle, D.; Heimiller, D.; Jimenez, A.; Melius, J.; Stoltenberg, B.; VanGeet, O.

    2013-05-01T23:59:59.000Z

    This report summarizes the results of an assessment and analysis of renewable energy opportunities conducted for the U.S. Department of the Interior, Bureau of Reclamation by the National Renewable Energy Laboratory. Tasks included assessing the suitability for wind and solar on both a utility and facility scale.

  3. Estimation of methane and carbon dioxide surface fluxes using a 3-D global atmospheric chemical transport model

    E-Print Network [OSTI]

    Chen, Yu-Han, 1973-

    2004-01-01T23:59:59.000Z

    Methane (CH?) and carbon dioxide (CO?) are the two most radiatively important greenhouse gases attributable to human activity. Large uncertainties in their source and sink magnitudes currently exist. We estimate global ...

  4. CO.sub.2 separation from low-temperature flue gases

    DOE Patents [OSTI]

    Dilmore, Robert (Irwin, PA); Allen, Douglas (Salem, MA); Soong, Yee (Monroeville, PA); Hedges, Sheila (Bethel Park, PA)

    2010-11-30T23:59:59.000Z

    Two methods are provide for the separation of carbon dioxide from the flue gases. The first method utilizes a phase-separating moiety dissolved in an aqueous solution of a basic moiety to capture carbon dioxide. The second method utilizes a phase-separating moiety as a suspended solid in an aqueous solution of a basic moiety to capture carbon dioxide. The first method takes advantage of the surface-independent nature of the CO.sub.2 absorption reactions in a homogeneous aqueous system. The second method also provides permanent sequestration of the carbon dioxide. Both methods incorporate the kinetic rate enhancements of amine-based scrubbing while eliminating the need to heat the entire amine solution (80% water) in order to regenerate and release CO.sub.2. Both methods also take advantage of the low-regeneration temperatures of CO.sub.2-bearing mineral systems such as Na.sub.2CO.sub.3/NaHCO.sub.3 and K.sub.2CO.sub.3/KHCO.sub.3.

  5. Measuring non-condensable gases in steam

    SciTech Connect (OSTI)

    Doornmalen, J. P. C. M. van; Kopinga, K., E-mail: k.kopinga@tue.nl [Department of Applied Physics, Eindhoven University of Technology, P.O. Box 513, 5600 MB Eindhoven (Netherlands)

    2013-11-15T23:59:59.000Z

    In surgery, medical devices that are used should be sterilized. To obtain surface steam sterilization conditions, not only in the sterilizer chamber itself but also in the loads to be sterilized, the amount of non-condensable gases (NCGs), for instance air, should be very low. Even rather small fractions of NCGs (below 1 %) seriously hamper steam penetration in porous materials or devices with hollow channels (e.g., endoscopes). A recently developed instrument which might detect the presence of residual NCGs in a reliable and reproducible way is the 3M{sup TM} Electronic Test System (ETS). In this paper, a physical model is presented that describes the behavior of this instrument. This model has been validated by experiments in which known fractions of NCGs were introduced in a sterilizer chamber in which an ETS was placed. Despite several approximations made in the model, a good agreement is found between the model predictions and the experimental results. The basic principle of the ETS, measuring the heat transfer by condensation on a cooled surface, permits a very sensitive detection of NCGs in harsh environments like water vapor at high temperatures and pressures. Our model may serve to develop adapted and optimized versions of this instrument for use outside the field of sterilization, e.g., in heat exchangers based on steam condensation.

  6. Cryogenic method for measuring nuclides and fission gases

    DOE Patents [OSTI]

    Perdue, P.T.; Haywood, F.F.

    1980-05-02T23:59:59.000Z

    A cryogenic method is provided for determining airborne gases and particulates from which gamma rays are emitted. A special dewar counting vessel is filled with the contents of the sampling flask which is immersed in liquid nitrogen. A vertically placed sodium-iodide or germanium-lithium gamma-ray detector is used. The device and method are of particular use in measuring and identifying the radioactive noble gases including emissions from coal-fired power plants, as well as fission gases released or escaping from nuclear power plants.

  7. Viscosities of natural gases at high pressures and high temperatures

    E-Print Network [OSTI]

    Viswanathan, Anup

    2007-09-17T23:59:59.000Z

    Estimation of viscosities of naturally occurring petroleum gases provides the information needed to accurately work out reservoir-engineering problems. Existing models for viscosity prediction are limited by data, especially at high pressures...

  8. Studying coherence in ultra-cold atomic gases

    E-Print Network [OSTI]

    Miller, Daniel E. (Daniel Edward)

    2007-01-01T23:59:59.000Z

    This thesis will discuss the study of coherence properties of ultra-cold atomic gases. The atomic systems investigated include a thermal cloud of atoms, a Bose-Einstein condensate and a fermion pair condensate. In each ...

  9. The Release of Trapped Gases from Amorphous Solid Water Films...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    I. Top-Down" Crystallization-Induced Crack Propagation Probed The Release of Trapped Gases from Amorphous Solid Water Films: I. Top-Down" Crystallization-Induced Crack Propagation...

  10. Low-Value Waste Gases as an Energy Source 

    E-Print Network [OSTI]

    Waibel, R. T.

    1996-01-01T23:59:59.000Z

    Waste gases with potentially useful fuel value are generated at any number of points in refineries, chemical plants and other industrial and commercial sites. The higher quality streams have been utilized successfully in fuel systems for years...

  11. Method for monitoring stack gases for uranium activity

    DOE Patents [OSTI]

    Beverly, C.R.; Ernstberger, E.G.

    1985-07-03T23:59:59.000Z

    A method for monitoring the stack gases of a purge cascade of gaseous diffusion plant for uranium activity. A sample stream is taken from the stack gases and contacted with a volume of moisture-laden air for converting trace levels of uranium hexafluoride, if any, in the stack gases into particulate uranyl fluoride. A continuous strip of filter paper from a supply roll is passed through this sampling stream to intercept and gather any uranyl fluoride in the sampling stream. This filter paper is then passed by an alpha scintillation counting device where any radioactivity on the filter paper is sensed so as to provide a continuous monitoring of the gas stream for activity indicative of the uranium content in the stack gases. 1 fig.

  12. Helium Isotopes in Geothermal and Volcanic Gases of the Western...

    Open Energy Info (EERE)

    Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: Helium Isotopes in Geothermal and Volcanic Gases of the Western United States, II. Long...

  13. Helium Isotopes In Geothermal And Volcanic Gases Of The Western...

    Open Energy Info (EERE)

    Helium Isotopes In Geothermal And Volcanic Gases Of The Western United States, I, Regional Variability And Magmatic Origin Jump to: navigation, search OpenEI Reference LibraryAdd...

  14. Geochemical Data on Waters, Gases, Scales, and Rocks from the...

    Open Energy Info (EERE)

    Jump to: navigation, search OpenEI Reference LibraryAdd to library Report: Geochemical Data on Waters, Gases, Scales, and Rocks from the Dixie Valley Region, Nevada (1996-1999)...

  15. Low-Value Waste Gases as an Energy Source

    E-Print Network [OSTI]

    Waibel, R. T.

    Waste gases with potentially useful fuel value are generated at any number of points in refineries, chemical plants and other industrial and commercial sites. The higher quality streams have been utilized successfully in fuel systems for years...

  16. Radio-frequency spectroscopy of ultracold atomic Fermi gases

    E-Print Network [OSTI]

    Schirotzek, Andre

    2010-01-01T23:59:59.000Z

    This thesis presents experiments investigating the phase diagram of ultracold atomic Fermi gases using radio-frequency spectroscopy. The tunability of many experimental parameters including the temperature, the interparticle ...

  17. Method for monitoring stack gases for uranium activity

    DOE Patents [OSTI]

    Beverly, Claude R. (Paducah, KY); Ernstberger, Harold G. (Paducah, KY)

    1988-01-01T23:59:59.000Z

    A method for monitoring the stack gases of a purge cascade of a gaseous diffusion plant for uranium activity. A sample stream is taken from the stack gases and contacted with a volume of moisture-laden air for converting trace levels of uranium hexafluoride, if any, in the stack gases into particulate uranyl fluoride. A continuous strip of filter paper from a supply roll is passed through this sampling stream to intercept and gather any uranyl fluoride in the sampling stream. This filter paper is then passed by an alpha scintillation counting device where any radioactivity on the filter paper is sensed so as to provide a continuous monitoring of the gas stream for activity indicative of the uranium content in the stack gases.

  18. active trace gases: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    OF GEOPHYSICAL RESEARCH, VOL. 94, NO. D13, PAGES 16,417-16,421,NOVEMBER 20, 1989 Greenhouse Effect of Chlorofluorocarbons and Other Trace Gases Environmental Sciences and Ecology...

  19. Carbon Smackdown: Carbon Capture

    ScienceCinema (OSTI)

    Jeffrey Long

    2010-09-01T23:59:59.000Z

    In this July 9, 2010 Berkeley Lab summer lecture, Lab scientists Jeff Long of the Materials Sciences and Nancy Brown of the Environmental Energy Technologies Division discuss their efforts to fight climate change by capturing carbon from the flue gas of power plants, as well as directly from the air

  20. Process for the removal of acid forming gases from exhaust gases

    DOE Patents [OSTI]

    Chang, Shih-Ger (El Cerrito, CA); Liu, David K. (San Pablo, CA)

    1992-01-01T23:59:59.000Z

    Exhaust gases are treated to remove NO or NO.sub.x and SO.sub.2 by contacting the gases with an aqueous emulsion or suspension of yellow phosphorus preferably in a wet scrubber. The pressure is not critical, and ambient pressures are used. Hot water temperatures are best, but economics suggest about 50.degree. C. are attractive. The amount of yellow phosphorus used will vary with the composition of the exhaust gas, less than 3% for small concentrations of NO, and 10% or higher for concentrations above say 1000 ppm. Similarly, the pH will vary with the composition being treated, and it is adjusted with a suitable alkali. For mixtures of NO.sub.x and SO.sub.2, alkalis that are used for flue gas desulfurization are preferred. With this process, 100% of the by-products created are usable, and close to 100% of the NO or NO and SO.sub.2 can be removed in an economic fashion.

  1. Process for the removal of acid forming gases from exhaust gases

    DOE Patents [OSTI]

    Chang, S.G.; Liu, D.K.

    1992-11-17T23:59:59.000Z

    Exhaust gases are treated to remove NO or NO[sub x] and SO[sub 2] by contacting the gases with an aqueous emulsion or suspension of yellow phosphorus preferably in a wet scrubber. The pressure is not critical, and ambient pressures are used. Hot water temperatures are best, but economics suggest about 50 C is attractive. The amount of yellow phosphorus used will vary with the composition of the exhaust gas, less than 3% for small concentrations of NO, and 10% or higher for concentrations above say 1000 ppm. Similarly, the pH will vary with the composition being treated, and it is adjusted with a suitable alkali. For mixtures of NO[sub x] and SO[sub 2], alkalis that are used for flue gas desulfurization are preferred. With this process, 100% of the by-products created are usable, and close to 100% of the NO or NO[sub x] and SO[sub 2] can be removed in an economic fashion. 9 figs.

  2. Chapter 4 The Gaseous State Chemistry of Gases

    E-Print Network [OSTI]

    Ihee, Hyotcherl

    .15 V = V0[1+(t/273.15oC)] Kelvin T = 273.15 + t(Celsius) #12;Boyle's Law · The stirling engine, a heatChapter 4 The Gaseous State NO2 #12;AIR #12;Chemistry of Gases SO3 .. corrosive gas SO2...burning) ~1760 Charle The definition of the Temperature All gases expand with increasing temperature by the same

  3. Manufacturing Energy and Carbon Footprints (2006 MECS)

    Broader source: Energy.gov [DOE]

    Energy and Carbon Footprints provide a mapping of energy from supply to end use in manufacturing. They show us where energy is used and lost—and where greenhouse gases (GHGs) are emitted. Footprints are available below for 15 manufacturing sectors (representing 94% of all manufacturing energy use) and for U.S. manufacturing as a whole. Analysis of these footprints is also available in the U.S. Manufacturing Energy Use and Greenhouse Gas Emissions Analysis report.

  4. The ongoing University of Minnesota low carbon fuels policy

    E-Print Network [OSTI]

    Minnesota, University of

    · Most of our CO2 emissions come from electricity production and from transportation · Compared to these · Greenhouse gases are messing with the climate · Most of our GHG emissions are in the form of carbon dioxide-human environment effects of fuels' production and use ·Consider great range of uncertainty for some impacts

  5. The Net Environmental Effects of Carbon Dioxide Reduction Policies

    E-Print Network [OSTI]

    of policy measures have been proposed to reduce the emissions of carbon dioxide (CO2). However, policies which reduce CO2 emissions will also decrease the emissions of greenhouse-relevant gases methane are overlooked the net effect of CO2 reduction policies on global warming is understated. Thus, emissions of all

  6. Magnesium cage shows promise for carbon capture http://www.rsc.org/chemistryworld/News/2009/December/01120901.asp[12/2/2009 12:27:18 PM

    E-Print Network [OSTI]

    Yaghi, Omar M.

    Magnesium cage shows promise for carbon capture http://www.rsc.org/chemistryworld/News/2009 Links Tools Magnesium cage shows promise for carbon capture 01 December 2009 US chemists have shown and selectively capture carbon dioxide from a mixture of gases and subsequently release it using little energy

  7. Method of and apparatus for removing sulfur oxides from exhaust gases formed by combustion

    SciTech Connect (OSTI)

    Voeste, T.

    1981-01-27T23:59:59.000Z

    A process is described for removing sulfur oxides from exhaust gas formed by combustion particularly exhaust gas from an electricity generating power plant. The exhaust gas flows through a reaction zone which operates like a spray dryer. A purifying liquor consisting of an aqueous solution of sodium carbonate and/or sodium bicarbonate is sprayed into the reaction zone, in which the heat content of the exhaust gases causes virtually all of the water content of the purifying liquor to be evaporated. The exhaust gas is subsequently passed through a filter. Anhydrous solids are withdrawn from the reaction zone and the filter and contain at least 75% of sodium sulfite, sodium sulfate and sodium chloride and are processed to form sodium carbonate. To that end the solids are dissolved and sulfite is oxidized to form sulfate so that a solution that contains sodium sulfate and sodium chloride is formed. The sulfate is separated from that solution and the remaining solution is used in the recovery of sodium carbonate by the solvay process.

  8. Greenhouse gases and agriculture. Book chapter

    SciTech Connect (OSTI)

    Jackson, R.B.

    1993-01-01T23:59:59.000Z

    Agriculture ranks third in its contribution to Earth's anthropogenically enhanced greenhouse effect. (Energy use and production and chlorofluorocarbons are ranked first and second, respectively.) Specifically, greenhouse gas sources and sinks are increased, and sinks are decreased, by conversion of land to agricultural use, using fertilizers, cultivating paddy rice, producing other plant and animal crops, and by creating and managing animal and plant wastes. However, some of these same activities increase greenhouse gas sinks and decrease greenhouse gas sources so the net effects are not obvious. The paper identifies the agricultural inputs, outputs, and wastes that alter atmospheric concentrations of carbon dioxide, methane, and nitrous oxides, and discusses agriculture's net impact on greenhouse gas fluxes.

  9. Fluid clathrate system for continuous removal of heavy noble gases from mixtures of lighter gases

    DOE Patents [OSTI]

    Gross, Kenneth C. (Bolingbrook, IL); Markun, Francis (Joliet, IL); Zawadzki, Mary T. (South Bend, IN)

    1998-01-01T23:59:59.000Z

    An apparatus and method for separation of heavy noble gas in a gas volume. An apparatus and method have been devised which includes a reservoir containing an oil exhibiting a clathrate effect for heavy noble gases with a reservoir input port and the reservoir is designed to enable the input gas volume to bubble through the oil with the heavy noble gas being absorbed by the oil exhibiting a clathrate effect. The gas having reduced amounts of heavy noble gas is output from the oil reservoir, and the oil having absorbed heavy noble gas can be treated by mechanical agitation and/or heating to desorb the heavy noble gas for analysis and/or containment and allow recycling of the oil to the reservoir.

  10. Fluid clathrate system for continuous removal of heavy noble gases from mixtures of lighter gases

    DOE Patents [OSTI]

    Gross, K.C.; Markun, F.; Zawadzki, M.T.

    1998-04-28T23:59:59.000Z

    An apparatus and method are disclosed for separation of heavy noble gas in a gas volume. An apparatus and method have been devised which includes a reservoir containing an oil exhibiting a clathrate effect for heavy noble gases with a reservoir input port and the reservoir is designed to enable the input gas volume to bubble through the oil with the heavy noble gas being absorbed by the oil exhibiting a clathrate effect. The gas having reduced amounts of heavy noble gas is output from the oil reservoir, and the oil having absorbed heavy noble gas can be treated by mechanical agitation and/or heating to desorb the heavy noble gas for analysis and/or containment and allow recycling of the oil to the reservoir. 6 figs.

  11. Realization of effective super Tonks-Girardeau gases via strongly attractive one-dimensional Fermi gases

    SciTech Connect (OSTI)

    Chen Shu; Yin Xiangguo; Guan Liming [Institute of Physics, Chinese Academy of Sciences, Beijing 100190 (China); Guan Xiwen [Department of Theoretical Physics, Research School of Physics and Engineering, Australian National University, Canberra ACT 0200 (Australia); Batchelor, M. T. [Department of Theoretical Physics, Research School of Physics and Engineering, Australian National University, Canberra ACT 0200 (Australia); Mathematical Sciences Institute, Australian National University, Canberra ACT 0200 (Australia)

    2010-03-15T23:59:59.000Z

    A significant feature of the one-dimensional super Tonks-Girardeau gas is its metastable gas-like state with a stronger Fermi-like pressure than for free fermions which prevents a collapse of atoms. This naturally suggests a way to search for such strongly correlated behavior in systems of interacting fermions in one dimension. We thus show that the strongly attractive Fermi gas without polarization can be effectively described by a super Tonks-Girardeau gas composed of bosonic Fermi pairs with attractive pair-pair interaction. A natural description of such super Tonks-Girardeau gases is provided by Haldane generalized exclusion statistics. In particular, they are equivalent to ideal particles obeying more exclusive statistics than Fermi-Dirac statistics.

  12. Process for the removal of acid forming gases from exhaust gases and production of phosphoric acid

    DOE Patents [OSTI]

    Chang, Shih-Ger (El Cerrito, CA); Liu, David K. (San Pablo, CA)

    1992-01-01T23:59:59.000Z

    Exhaust gases are treated to remove NO or NO.sub.x and SO.sub.2 by contacting the gases with an aqueous emulsion or suspension of yellow phosphorous preferably in a wet scrubber. The addition of yellow phosphorous in the system induces the production of O.sub.3 which subsequently oxidizes NO to NO.sub.2. The resulting NO.sub.2 dissolves readily and can be reduced to form ammonium ions by dissolved SO.sub.2 under appropriate conditions. In a 20 acfm system, yellow phosphorous is oxidized to yield P.sub.2 O.sub.5 which picks up water to form H.sub.3 PO.sub.4 mists and can be collected as a valuable product. The pressure is not critical, and ambient pressures are used. Hot water temperatures are best, but economics suggest about 50.degree. C. The amount of yellow phosphorus used will vary with the composition of the exhaust gas, less than 3% for small concentrations of NO, and 10% or higher for concentrations above say 1000 ppm. Similarly, the pH will vary with the composition being treated, and it is adjusted with a suitable alkali. For mixtures of NO.sub.x and SO.sub.2, alkalis that are used for flue gas desulfurization are preferred. With this process, better than 90% of SO.sub.2 and NO in simulated flue gas can be removed. Stoichiometric ratios (P/NO) ranging between 0.6 and 1.5 were obtained.

  13. Three-dimensional carbon fibers and method and apparatus for their production

    DOE Patents [OSTI]

    Muradov, Nazim Z. (Melbourne, FL)

    2012-02-21T23:59:59.000Z

    This invention relates to novel three-dimensional (3D) carbon fibers which are original (or primary) carbon fibers (OCF) with secondary carbon filaments (SCF) grown thereon, and, if desired, tertiary carbon filaments (TCF) are grown from the surface of SCF forming a filamentous carbon network with high surface area. The methods and apparatus are provided for growing SCF on the OCF by thermal decomposition of carbonaceous gases (CG) over the hot surface of the OCF without use of metal-based catalysts. The thickness and length of SCF can be controlled by varying operational conditions of the process, e.g., the nature of CG, temperature, residence time, etc. The optional activation step enables one to produce 3D activated carbon fibers with high surface area. The method and apparatus are provided for growing TCF on the SCF by thermal decomposition of carbonaceous gases over the hot surface of the SCF using metal catalyst particles.

  14. CO2-Brine Surface Dissolution and Injection: CO2 Storage Enhancement Paul Emeka Eke, SPE, Mark Naylor, Stuart Haszeldine and Andrew Curtis, Scottish Centre for Carbon Storage,

    E-Print Network [OSTI]

    ) is capable of reducing atmospheric emissions of greenhouse gases from coal or gas fired power plants or supercritical phase, as water-alternating gas cycles, or as carbonated brine. These result in different

  15. Phase Behavior of Light Gases in Hydrocarbon and Aqueous Solvents

    SciTech Connect (OSTI)

    Gasem, K.A.M.; Robinson, R.L., Jr.; Trvedi, N.J., Gao, W.

    1997-09-01T23:59:59.000Z

    Under previous support from the Department of Energy, an experimental facility has been established and operated to measure valuable vapor-liquid equilibrium data for systems of interest in the production and processing of coal fluids. To facilitate the development and testing of models for prediction of the phase behavior for such systems, we have acquired substantial amounts of data on the equilibrium phase compositions for binary mixtures of heavy hydrocarbon solvents with a variety of supercritical solutes, including hydrogen, methane, ethane, carbon monoxide, and carbon dioxide. The present project focuses on measuring the phase behavior of light gases and water in Fischer-Tropsch (F-T) type solvents at conditions encountered in indirect liquefaction processes and evaluating and developing theoretically-based correlating frameworks to predict the phase behavior of such systems. Specific goals of the proposed work include (a) developing a state-of-the-art experimental facility to permit highly accurate measurements of equilibrium phase compositions (solubilities) of challenging F-T systems, (b) measuring these properties for systematically-selected binary, ternary and molten F-T wax mixtures to provide critically needed input data for correlation development, (c) developing and testing models suitable for describing the phase behavior of such mixtures, and (d) presenting the modeling results in generalized, practical formats suitable for use in process engineering calculations. During the present reporting period, our solubility apparatus was refurbished and restored to full service. To test the experimental apparatus and procedures used, measurements were obtained for the solubility Of C0{sub 2} in benzene at 160{degrees}F. Having confirmed the accuracy of the newly acquired data in comparison with our previous measurements and data reported in the literature for this test system, we have begun to measure the solubility of hydrogen in hexane. The measurements for this system will cover the temperature range from 160 to 280{degrees}F at pressures to 2,500 psia. As part of our model evaluation efforts, we examined the predictive abilities of an alternative approach we have proposed for calculating the phase behavior properties of highly non-ideal systems. Using this approach, the liquid phase fugacities generated from an equation of state (EOS) are augmented by a fugacity deviation function correction. The correlative abilities of this approach are compared with those of an EOS equipped with the recently introduced Wong-Sandler (MWS) mixing rules. These two approaches are compared with the current methods for vapor-liquid equilibrium (VLE) calculations, i.e., the EOS (0/0) approach with the van der Waals mixing rules and the split (y/0) approach. The evaluations were conducted on a database comprised of non-ideal low pressure binary systems as well as asymmetric high pressure binary systems. These systems are of interest in the coal liquefaction and utilization processes. The Peng-Robinson EOS was selected for the purposes of this evaluation.

  16. Global Carbon Budget from the Carbon Dioxide Information Analysis Center (CDIAC)

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    The Global Carbon Project (GCP) was established in 2001 in recognition of the scientific challenge and critical importance of the carbon cycle for Earth's sustainability. The growing realization that anthropogenic climate change is a reality has focused the attention of the scientific community, policymakers and the general public on the rising concentration of greenhouse gases, especially carbon dioxide (CO2) in the atmosphere, and on the carbon cycle in general. Initial attempts, through the United Nations Framework Convention on Climate Change and its Kyoto Protocol, are underway to slow the rate of increase of greenhouse gases in the atmosphere. These societal actions require a scientific understanding of the carbon cycle, and are placing increasing demands on the international science community to establish a common, mutually agreed knowledge base to support policy debate and action. The Global Carbon Project is responding to this challenge through a shared partnership between the International Geosphere-Biosphere Programme (IGBP), the International Human Dimensions Programme on Global Environmental Change (IHDP), the World Climate Research Programme (WCRP) and Diversitas. This partnership constitutes the Earth Systems Science Partnership (ESSP). This CDIAC collection includes datasets, images, videos, presentations, and archived data from previous years.

  17. Emissions Of Greenhouse Gases From Rice Agriculture

    SciTech Connect (OSTI)

    M. Aslam K. Khalil

    2009-07-16T23:59:59.000Z

    This project produced detailed data on the processes that affect methane and nitrous oxide emissions from rice agriculture and their inter-relationships. It defines the shifting roles and potential future of these gases in causing global warming and the benefits and tradeoffs of reducing emissions. The major results include: 1). Mechanisms and Processes Leading to Methane Emissions are Delineated. Our experiments have tested the standard model of methane emissions from rice fields and found new results on the processes that control the flux. A mathematical mass balance model was used to unravel the production, oxidation and transport of methane from rice. The results suggested that when large amounts of organic matter are applied, the additional flux that is observed is due to both greater production and reduced oxidation of methane. 2). Methane Emissions From China Have Been Decreasing Over the Last Two Decades. We have calculated that methane emissions from rice fields have been falling in recent decades. This decrease is particularly large in China. While some of this is due to reduced area of rice agriculture, the bigger effect is from the reduction in the emission factor which is the annual amount of methane emitted per hectare of rice. The two most important changes that cause this decreasing emission from China are the reduced use of organic amendments which have been replaced by commercial nitrogen fertilizers, and the increased practice of intermittent flooding as greater demands are placed on water resources. 3). Global Methane Emissions Have Been Constant For More Than 20 Years. While the concentrations of methane in the atmosphere have been leveling off in recent years, our studies show that this is caused by a near constant total global source of methane for the last 20 years or more. This is probably because as some anthropogenic sources have increased, others, such as the rice agriculture source, have fallen. Changes in natural emissions appear small. 4). Nitrous Oxide Emissions From Rice Fields Increase as Methane Emissions Drop. Inundated conditions favor anaerobic methane production with high emission rates and de-nitrification resulting in modest nitrous oxide emissions. Under drier conditions such as intermittent flooding, methane emissions fall and nitrous oxide emissions increase. Increased nitrogen fertilizer use increases nitrous oxide emissions and is usually accompanied by reduced organic matter applications which decreases methane emissions. These mechanisms cause a generally inverse relationship between methane and nitrous oxide emissions. Reduction of methane from rice agriculture to control global warming comes with tradeoffs with increased nitrous oxide emissions. 5). High Spatial Resolution Maps of Emissions Produced. Maps of methane and nitrous oxide emissions at a resolution of 5 min × 5 min have been produced based on the composite results of this research. These maps are necessary for both scientific and policy uses.

  18. Evaluation of exposures of hospital employees to anesthetic gases

    SciTech Connect (OSTI)

    Lambeth, J.D.

    1988-01-01T23:59:59.000Z

    Hospital employees who work in hospital operating and recovery rooms are often exposed to a number of anesthetic gases. There is evidence to support the belief that such exposures have led to higher rates of miscarriages and spontaneous abortions of pregnancies among women directly exposed to these gases than among women not exposed. Most of the studies assessing exposure levels were conducted prior to the widespread use of scavenging systems. Air sampling was conducted in hospital operatories and recovery rooms of three large hospitals to assess the current exposure levels in these areas and determine the effectiveness of these systems in reducing exposures to fluoride-containing anesthetic gases. It was determined that recovery-room personnel are exposed to levels of anesthesia gases that often approach and exceed the recommended Threshold Limit Value-Time Weighted Average (TLV-TWA) of 2.0 ppm. Recovery-room personnel do not have the protection from exposure provided by scavenging systems in operating rooms. Operating-room personnel were exposed to anesthesia gas levels above the TLV-TWA only when patients were masked, or connected and disconnected from the scavenging systems. Recovery-room personnel also need to be protected from exposure to anesthesia gases by a scavenging system.

  19. Carbon dioxide and climate

    SciTech Connect (OSTI)

    Not Available

    1990-10-01T23:59:59.000Z

    Scientific and public interest in greenhouse gases, climate warming, and global change virtually exploded in 1988. The Department's focused research on atmospheric CO{sub 2} contributed sound and timely scientific information to the many questions produced by the groundswell of interest and concern. Research projects summarized in this document provided the data base that made timely responses possible, and the contributions from participating scientists are genuinely appreciated. In the past year, the core CO{sub 2} research has continued to improve the scientific knowledge needed to project future atmospheric CO{sub 2} concentrations, to estimate climate sensitivity, and to assess the responses of vegetation to rising concentrations of CO{sub 2} and to climate change. The Carbon Dioxide Research Program's goal is to develop sound scientific information for policy formulation and governmental action in response to changes of atmospheric CO{sub 2}. The Program Summary describes projects funded by the Carbon Dioxide Research Program during FY 1990 and gives a brief overview of objectives, organization, and accomplishments.

  20. Method for removing acid gases from a gaseous stream

    DOE Patents [OSTI]

    Gorin, Everett (San Rafael, CA); Zielke, Clyde W. (McMurray, PA)

    1981-01-01T23:59:59.000Z

    In a process for hydrocracking a heavy aromatic polynuclear carbonaceous feedstock containing reactive alkaline constituents to produce liquid hydrocarbon fuels boiling below about 475.degree. C. at atmospheric pressure by contacting the feedstock with hydrogen in the presence of a molten metal halide catalyst, thereafter separating a gaseous stream containing hydrogen, at least a portion of the hydrocarbon fuels and acid gases from the molten metal halide and regenerating the molten metal halide, thereby producing a purified molten metal halide stream for recycle to the hydrocracking zone, an improvement comprising; contacting the gaseous acid gas, hydrogen and hydrocarbon fuels-containing stream with the feedstock containing reactive alkaline constituents to remove acid gases from the acid gas containing stream. Optionally at least a portion of the hydrocarbon fuels are separated from gaseous stream containing hydrogen, hydrocarbon fuels and acid gases prior to contacting the gaseous stream with the feedstock.

  1. “Hard probes” of strongly-interacting atomic gases

    SciTech Connect (OSTI)

    Nishida, Yusuke [Los Alamos National Laboratory

    2012-06-18T23:59:59.000Z

    We investigate properties of an energetic atom propagating through strongly interacting atomic gases. The operator product expansion is used to systematically compute a quasiparticle energy and its scattering rate both in a spin-1/2 Fermi gas and in a spinless Bose gas. Reasonable agreement with recent quantum Monte Carlo simulations even at a relatively small momentum k/kF > 1.5 indicates that our large-momentum expansions are valid in a wide range of momentum. We also study a differential scattering rate when a probe atom is shot into atomic gases. Because the number density and current density of the target atomic gas contribute to the forward scattering only, its contact density (measure of short-range pair correlation) gives the leading contribution to the backward scattering. Therefore, such an experiment can be used to measure the contact density and thus provides a new local probe of strongly interacting atomic gases.

  2. Carbonaceous adsorbent regeneration and halocarbon displacement by hydrocarbon gases

    DOE Patents [OSTI]

    Senum, G.I.; Dietz, R.N.

    1994-04-05T23:59:59.000Z

    This invention describes a process for regeneration of halocarbon bearing carbonaceous adsorbents through which a carbonaceous adsorbent is contacted with hydrocarbon gases, preferably propane, butane and pentane at near room temperatures and at atmospheric pressure. As the hydrocarbon gases come in contact with the adsorbent, the hydrocarbons displace the halocarbons by physical adsorption. As a result of using this process, the halocarbon concentration and the hydrocarbon eluant is increased thereby allowing for an easier recovery of pure halocarbons. By using the process of this invention, carbonaceous adsorbents can be regenerated by an inexpensive process which also allows for subsequent re-use of the recovered halocarbons. 8 figures.

  3. Carbonaceous adsorbent regeneration and halocarbon displacement by hydrocarbon gases

    DOE Patents [OSTI]

    Senum, Gunnar I. (Patchogue, NY); Dietz, Russell N. (Patchogue, NY)

    1994-01-01T23:59:59.000Z

    This invention describes a process for regeneration of halocarbon bearing carbonaceous adsorbents through which a carbonaceous adsorbent is contacted with hydrocarbon gases, preferably propane, butane and pentane at near room temperatures and at atmospheric pressure. As the hydrocarbon gases come in contact with the adsorbent, the hydrocarbons displace the halocarbons by physical adsorption. As a result of using this process, the halocarbon concentration and the hydrocarbon eluant is increased thereby allowing for an easier recovery of pure halocarbons. By using the process of this invention, carbonaceous adsorbents can be regenerated by an inexpensive process which also allows for subsequent re-use of the recovered halocarbons.

  4. Removal of sulfur and nitrogen containing pollutants from discharge gases

    DOE Patents [OSTI]

    Joubert, James I. (Pittsburgh, PA)

    1986-01-01T23:59:59.000Z

    Oxides of sulfur and of nitrogen are removed from waste gases by reaction with an unsupported copper oxide powder to form copper sulfate. The resulting copper sulfate is dissolved in water to effect separation from insoluble mineral ash and dried to form solid copper sulfate pentahydrate. This solid sulfate is thermally decomposed to finely divided copper oxide powder with high specific surface area. The copper oxide powder is recycled into contact with the waste gases requiring cleanup. A reducing gas can be introduced to convert the oxide of nitrogen pollutants to nitrogen.

  5. Methods, systems, and devices for deep desulfurization of fuel gases

    DOE Patents [OSTI]

    Li, Liyu (Richland, WA); King, David L. (Richland, WA); Liu, Jun (Richland, WA); Huo, Qisheng (Richland, WA)

    2012-04-17T23:59:59.000Z

    A highly effective and regenerable method, system and device that enables the desulfurization of warm fuel gases by passing these warm gasses over metal-based sorbents arranged in a mesoporous substrate. This technology will protect Fischer-Tropsch synthesis catalysts and other sulfur sensitive catalysts, without drastic cooling of the fuel gases. This invention can be utilized in a process either alone or alongside other separation processes, and allows the total sulfur in such a gas to be reduced to less than 500 ppb and in some instances as low as 50 ppb.

  6. Welcome to Greenhouse Gases: Science and Technology: Editorial

    SciTech Connect (OSTI)

    Oldenburg, C.M.; Maroto-Valer, M.M.

    2011-02-01T23:59:59.000Z

    This editorial introduces readers and contributors to a new online journal. Through the publication of articles ranging from peer-reviewed research papers and short communications, to editorials and interviews on greenhouse gas emissions science and technology, this journal will disseminate research results and information that address the global crisis of anthropogenic climate change. The scope of the journal includes the full spectrum of research areas from capture and separation of greenhouse gases from flue gases and ambient air, to beneficial utilization, and to sequestration in deep geologic formations and terrestrial (plant and soil) systems, as well as policy and technoeconomic analyses of these approaches.

  7. US STATE POLICIES FOR RENEWABLE ENERGY: CONTEXT AND EFFECTIVENESS

    E-Print Network [OSTI]

    Delmas, Magali

    emissions come primarily from the combustion of fossil fuels in energy use. Energy-related carbon dioxide to sell green products, disclosure policies, and subsidies. Analyzing the effectiveness of state renewable://www.eia.doe.gov/bookshelf/brochures/greenhouse/Chapter1.htm This is without hydroelectricity. Biomass (71%) was the predominant non-hydro renewable fuel

  8. Earth is warm because of "greenhouse gases" in atmosphere

    E-Print Network [OSTI]

    Callender, Craig

    " properties of carbon dioxide, water. #12;Early 20th century, scientists realized that if CO2 content changed "Calculation shows that doubling or tripling the amount of the carbon dioxide in the atmosphere increases

  9. AER1301: KINETIC THEORY OF GASES Assignment #1

    E-Print Network [OSTI]

    Groth, Clinton P. T.

    AER1301: KINETIC THEORY OF GASES Assignment #1 1. A hypersonic wind tunnel is contructed so such that the mean free path, , is given by the expression = 16µ 5 1 2RT , where R is the ideal gas constant and p space and the length of each side of the cube is 4v. (a) Obtain an expression for the normalized

  10. AER1301: KINETIC THEORY OF GASES Assignment #1

    E-Print Network [OSTI]

    Groth, Clinton P. T.

    AER1301: KINETIC THEORY OF GASES Assignment #1 1. A hypersonic wind tunnel is contructed so spheres during collisions such that the mean free path, #21;, is given by the expression #21; = 16#22; 5 of the cube is 4v Ć . (a) Obtain an expression for the normalized velocity distribution function, f(v). (b

  11. AER1301: KINETIC THEORY OF GASES Assignment #4

    E-Print Network [OSTI]

    Groth, Clinton P. T.

    - equilibrium cases, up to second order. (b) Derive an expression for the non-conservative form of the kineticAER1301: KINETIC THEORY OF GASES Assignment #4 1. Consider a monatomic gas with one translational by the relaxation time approx- imation. Neglecting external forces, the conserved form of the kinetic equation

  12. AER1301: KINETIC THEORY OF GASES Assignment #4

    E-Print Network [OSTI]

    Groth, Clinton P. T.

    AER1301: KINETIC THEORY OF GASES Assignment #4 1. Consider a monatomic gas with one translational by the relaxation time approx- imation. Neglecting external forces, the conserved form of the kinetic equation function, in both the equilibrium and non- equilibrium cases, up to second order. (b) Derive an expression

  13. Ozone-depleting substances and the greenhouse gases HFCs, PFCs

    E-Print Network [OSTI]

    Ozone-depleting substances and the greenhouse gases HFCs, PFCs and SF6 Danish consumption contribution to the debate on environmental policy in Denmark. #12;3 Contents 1 SUMMARY 5 1.1 OZONE OZONE-DEPLETING SUBSTANCES 19 3.1 IMPORTS AND EXPORTS 19 3.1.1 CFCs 19 3.1.2 Tetrachloromethane 19 3

  14. Nature of superfluidity in ultracold Fermi gases near Feshbach resonances

    SciTech Connect (OSTI)

    Stajic, Jelena; Levin, K. [James Franck Institute and Department of Physics, University of Chicago, Chicago, Illinois 60637 (United States); Milstein, J.N.; Holland, M.J. [JILA, University of Colorado and National Institute of Standards and Technology, Boulder, Colorado 80309 (United States); Chen Qijin [Department of Physics and Astronomy, Johns Hopkins University, Baltimore, Maryland 21218 (United States); Chiofalo, M.L. [Classe di Scienze and INFM, Scuola Normale Superiore, Piazza dei Cavelieri 7, I-56126 Pisa (Italy)

    2004-06-01T23:59:59.000Z

    We study the superfluid state of atomic Fermi gases using a BCS-Bose-Einstein-condensation crossover theory. Our approach emphasizes noncondensed fermion pairs which strongly hybridize with their (Feshbach-induced) molecular boson counterparts. These pairs lead to pseudogap effects above T{sub c} and non-BCS characteristics below. We discuss how these effects influence the experimental signatures of superfluidity.

  15. INTRODUCTION Insects exchange respiratory gases through a complex network of

    E-Print Network [OSTI]

    Socha, Jake

    3409 INTRODUCTION Insects exchange respiratory gases through a complex network of tracheal tubes through the tracheal system using diffusion alone (Krogh, 1920a; Weis-Fogh, 1964), many species are known to augment gas exchange using convection (Buck, 1962; Miller, 1966a). Two general mechanisms are recognized

  16. Higher Dimensional Coulomb Gases and Renormalized Energy Functionals

    E-Print Network [OSTI]

    -Louis Lions, Paris, F-75005 France & Courant Institute, New York University, 251 Mercer st, NY NY 10012, USAHigher Dimensional Coulomb Gases and Renormalized Energy Functionals N. Rougerie and S. Serfaty extract the next to leading order term in the ground state energy, beyond the mean-field limit. We show

  17. Use of low temperature blowers for recirculation of hot gases

    DOE Patents [OSTI]

    Maru, H.C.; Forooque, M.

    1982-08-19T23:59:59.000Z

    An apparatus is described for maintaining motors at low operating temperatures during recirculation of hot gases in fuel cell operations and chemical processes such as fluidized bed coal gasification. The apparatus includes a means for separating the hot process gas from the motor using a secondary lower temperature gas, thereby minimizing the temperature increase of the motor and associated accessories.

  18. Noble gases and radiocarbon in natural gas hydrates Gisela Winckler

    E-Print Network [OSTI]

    Aeschbach-Hertig, Werner

    Noble gases and radiocarbon in natural gas hydrates Gisela Winckler Lamont-Doherty Earth 2001; published 24 May 2002. [1] In samples of pure natural gas hydrates from Hydrate Ridge, Cascadia ones preferentially incorporated into the gas hydrate structure. The hydrate methane is devoid of 14 C

  19. Emissions of greenhouse gases from the use of transportation fuels and electricity. Volume 1, Main text

    SciTech Connect (OSTI)

    DeLuchi, M.A. [California Univ., Davis, CA (United States)

    1991-11-01T23:59:59.000Z

    This report presents estimates of full fuel-cycle emissions of greenhouse gases from using transportation fuels and electricity. The data cover emissions of carbon dioxide (CO{sub 2}), methane, carbon monoxide, nitrous oxide, nitrogen oxides, and nonmethane organic compounds resulting from the end use of fuels, compression or liquefaction of gaseous transportation fuels, fuel distribution, fuel production, feedstock transport, feedstock recovery, manufacture of motor vehicles, maintenance of transportation systems, manufacture of materials used in major energy facilities, and changes in land use that result from using biomass-derived fuels. The results for electricity use are in grams of CO{sub 2}-equivalent emissions per kilowatt-hour of electricity delivered to end users and cover generating plants powered by coal, oil, natural gas, methanol, biomass, and nuclear energy. The transportation analysis compares CO{sub 2}-equivalent emissions, in grams per mile, from base-case gasoline and diesel fuel cycles with emissions from these alternative- fuel cycles: methanol from coal, natural gas, or wood; compressed or liquefied natural gas; synthetic natural gas from wood; ethanol from corn or wood; liquefied petroleum gas from oil or natural gas; hydrogen from nuclear or solar power; electricity from coal, uranium, oil, natural gas, biomass, or solar energy, used in battery-powered electric vehicles; and hydrogen and methanol used in fuel-cell vehicles.

  20. Carbon Capture By Solids | Latest News | Chemical & Engineering News http://pubs.acs.org/cen/news/88/i44/8844notw9.html[11/3/2010 3:56:50 PM

    E-Print Network [OSTI]

    Yaghi, Omar M.

    - capture technology. Carbon cleanup in industrial settings today is often carried out by flowing flue gasesCarbon Capture By Solids | Latest News | Chemical & Engineering News http » Latest News » Carbon Capture By Solids Advertisement Advertise Here NOVEMBER 1, 2010 VOLUME 88, NUMBER 44

  1. Strongly interacting Fermi gases : non-equilibrium dynamics and dimensional crossover

    E-Print Network [OSTI]

    Sommer, Ariel T. (Ariel Tjodolv)

    2013-01-01T23:59:59.000Z

    Experiments using ultracold atomic gases address fundamental problems in many-body physics. This thesis describes experiments on strongly-interacting gases of fermionic atoms, with a focus on non-equilibrium physics and ...

  2. Hydrogen and elemental carbon production from natural gas and other hydrocarbons

    DOE Patents [OSTI]

    Detering, Brent A. (Idaho Falls, ID); Kong, Peter C. (Idaho Falls, ID)

    2002-01-01T23:59:59.000Z

    Diatomic hydrogen and unsaturated hydrocarbons are produced as reactor gases in a fast quench reactor. During the fast quench, the unsaturated hydrocarbons are further decomposed by reheating the reactor gases. More diatomic hydrogen is produced, along with elemental carbon. Other gas may be added at different stages in the process to form a desired end product and prevent back reactions. The product is a substantially clean-burning hydrogen fuel that leaves no greenhouse gas emissions, and elemental carbon that may be used in powder form as a commodity for several processes.

  3. System for trapping and storing gases for subsequent chemical reduction to solids

    DOE Patents [OSTI]

    Vogel, John S. (San Jose, CA); Ognibene, Ted J. (Oakland, CA); Bench, Graham S. (Livermore, CA); Peaslee, Graham F. (Holland, MI)

    2009-11-03T23:59:59.000Z

    A system for quantitatively reducing oxide gases. A pre-selected amount of zinc is provided in a vial. A tube is provided in the vial. The zinc and the tube are separated. A pre-selected amount of a catalyst is provided in the tube. Oxide gases are injected into the vial. The vial, tube, zinc, catalyst, and the oxide gases are cryogenically cooled. At least a portion of the vial, tube, zinc, catalyst, and oxide gases are heated.

  4. Title of Document: INTERACTION OF INTENSE SHORT LASER PULSES WITH GASES OF NANOSCALE

    E-Print Network [OSTI]

    Anlage, Steven

    ABSTRACT Title of Document: INTERACTION OF INTENSE SHORT LASER PULSES WITH GASES OF NANOSCALE-cluster interaction. #12;INTERACTION OF INTENSE SHORT LASER PULSES WITH GASES OF NANOSCALE ATOMIC AND MOLECULAR., Department of Electrical and Computer Engineering We study the interaction of intense laser pulses with gases

  5. Process for separation of CO/sub 2/ from CO/sub 2/-containing gases

    SciTech Connect (OSTI)

    Linde, G.

    1985-07-09T23:59:59.000Z

    For separating CO/sub 2/ from CO/sub 2/-containing gases, especially stack gases and/or blast furnace gases, dimethylformamide is employed as a physical scrubbing medium to ensure high CO/sub 2/ purity. After absorption of CO/sub 2/, the DMF is regenerated and returned into the scrubbing stage. Dimethylformamide is utilized as the scrubbing medium.

  6. Emissions of Non-CO2 Greenhouse Gases From the Production and Use of Transportation Fuels and Electricity

    E-Print Network [OSTI]

    Delucchi, Mark

    1997-01-01T23:59:59.000Z

    CO2 GREENHOUSE GASES FROM THE PRODUCTION AND USE OF TRANSPORTATION FUELS AND ELECTRICITYCO2 GREENHOUSE GASES FROM THE PRODUCTION AND USE OF TRANSPORTATION FUELS AND ELECTRICITY

  7. The extreme nonlinear optics of gases and femtosecond optical filamentation

    SciTech Connect (OSTI)

    Milchberg, H. M.; Chen, Y.-H.; Cheng, Y.-H.; Jhajj, N.; Palastro, J. P.; Rosenthal, E. W.; Varma, S.; Wahlstrand, J. K.; Zahedpour, S. [Institute for Research in Electronics and Applied Physics, University of Maryland, College Park, Maryland 20742 (United States)

    2014-10-15T23:59:59.000Z

    Under certain conditions, powerful ultrashort laser pulses can form greatly extended, propagating filaments of concentrated high intensity in gases, leaving behind a very long trail of plasma. Such filaments can be much longer than the longitudinal scale over which a laser beam typically diverges by diffraction, with possible applications ranging from laser-guided electrical discharges to high power laser propagation in the atmosphere. Understanding in detail the microscopic processes leading to filamentation requires ultrafast measurements of the strong field nonlinear response of gas phase atoms and molecules, including absolute measurements of nonlinear laser-induced polarization and high field ionization. Such measurements enable the assessment of filamentation models and make possible the design of experiments pursuing applications. In this paper, we review filamentation in gases and some applications, and discuss results from diagnostics developed at Maryland for ultrafast measurements of laser-gas interactions.

  8. Apparatus for the plasma destruction of hazardous gases

    DOE Patents [OSTI]

    Kang, Michael (Los Alamos, NM)

    1995-01-01T23:59:59.000Z

    A plasma cell for destroying hazardous gases. An electric-discharge cell having an electrically conducting electrode onto which an alternating high-voltage waveform is impressed and a dielectric barrier adjacent thereto, together forming a high-voltage electrode, generates self-terminating discharges throughout a volume formed between this electrode and a grounded conducting liquid electrode. The gas to be transformed is passed through this volume. The liquid may be flowed, generating thereby a renewable surface. Moreover, since hydrochloric and hydrofluoric acids may be formed from destruction of various chlorofluorocarbons in the presence of water, a conducting liquid may be selected which will neutralize these corrosive compounds. The gases exiting the discharge region may be further scrubbed if additional purification is required.

  9. Apparatus for the plasma destruction of hazardous gases

    DOE Patents [OSTI]

    Kang, M.

    1995-02-07T23:59:59.000Z

    A plasma cell for destroying hazardous gases is described. An electric-discharge cell having an electrically conducting electrode onto which an alternating high-voltage waveform is impressed and a dielectric barrier adjacent thereto, together forming a high-voltage electrode, generates self-terminating discharges throughout a volume formed between this electrode and a grounded conducting liquid electrode. The gas to be transformed is passed through this volume. The liquid may be flowed, generating thereby a renewable surface. Moreover, since hydrochloric and hydrofluoric acids may be formed from destruction of various chlorofluorocarbons in the presence of water, a conducting liquid may be selected which will neutralize these corrosive compounds. The gases exiting the discharge region may be further scrubbed if additional purification is required. 4 figs.

  10. Decontamination of combustion gases in fluidized bed incinerators

    DOE Patents [OSTI]

    Leon, Albert M. (Mamaroneck, NY)

    1982-01-01T23:59:59.000Z

    Sulfur-containing atmospheric pollutants are effectively removed from exit gas streams produced in a fluidized bed combustion system by providing a fluidized bed of particulate material, i.e. limestone and/or dolomite wherein a concentration gradient is maintained in the vertical direction. Countercurrent contacting between upwardly directed sulfur containing combustion gases and descending sorbent particulate material creates a concentration gradient across the vertical extent of the bed characterized in progressively decreasing concentration of sulfur, sulfur dioxide and like contaminants upwardly and decreasing concentration of e.g. calcium oxide, downwardly. In this manner, gases having progressively decreasing sulfur contents contact correspondingly atmospheres having progressively increasing concentrations of calcium oxide thus assuring optimum sulfur removal.

  11. Carbon dioxide absorbent and method of using the same

    DOE Patents [OSTI]

    Perry, Robert James (Niskayuna, NY); Lewis, Larry Neil (Scotia, NY); O'Brien, Michael Joseph (Clifton Park, NY); Soloveichik, Grigorii Lev (Latham, NY); Kniajanski, Sergei (Clifton Park, NY); Lam, Tunchiao Hubert (Clifton Park, NY); Lee, Julia Lam (Niskayuna, NY); Rubinsztajn, Malgorzata Iwona (Ballston Spa, NY)

    2011-10-04T23:59:59.000Z

    In accordance with one aspect, the present invention provides an amino-siloxane composition comprising at least one of structures I, II, III, IV or V said compositions being useful for the capture of carbon dioxide from gas streams such as power plant flue gases. In addition, the present invention provides methods of preparing the amino-siloxane compositions are provided. Also provided are methods for reducing the amount of carbon dioxide in a process stream employing the amino-siloxane compositions of the invention as species which react with carbon dioxide to form an adduct with carbon dioxide. The reaction of the amino-siloxane compositions provided by the present invention with carbon dioxide is reversible and thus, the method provides for multicycle use of said compositions.

  12. Wave Speed in the Macroscopic Extended Model for Ultrarelativistic Gases

    E-Print Network [OSTI]

    F. Borghero; F. Demontis; S. Pennisi

    2010-12-07T23:59:59.000Z

    An exact macroscopic extended model for ultrarelativistic gases, with an arbitrary number of moments, is present in the literature. Here we exploit equations determining wave speeds for that model. We find interesting results; for example, the whole system for their determination can be divided into independent subsystems and some, but not all, wave speeds are expressed by rational numbers. Moreover, the extraordinary property that these wave speeds for the macroscopic model are the same of those in the kinetic model, is proved.

  13. Pulse Radiolysis of Gases H atom yields, OH reactions,

    E-Print Network [OSTI]

    PULSE RADIOLYSIS OP GASES H atom yields, OH reactions, and kinetics of H2S systems Ole John Nielsen, M, in the reaction OH + OH + M · H2O2 + M. 3) In the H2S systems the HS extinction coefficient determined: k(H + H2S · H2 + HS) = 4-6 x 108 M ^ s " 1 k(HS + HS · products) = (1.9 ± 0.1) x io1 0 M ^ s " 1

  14. Performance Demonstration Program Plan for Analysis of Simulated Headspace Gases

    SciTech Connect (OSTI)

    Carlsbad Field Office

    2006-04-01T23:59:59.000Z

    The Performance Demonstration Program (PDP) for headspace gases distributes sample gases of volatile organic compounds (VOCs) for analysis. Participating measurement facilities (i.e., fixed laboratories, mobile analysis systems, and on-line analytical systems) are located across the United States. Each sample distribution is termed a PDP cycle. These evaluation cycles provide an objective measure of the reliability of measurements performed for transuranic (TRU) waste characterization. The primary documents governing the conduct of the PDP are the Quality Assurance Program Document (QAPD) (DOE/CBFO-94-1012) and the Waste Isolation Pilot Plant (WIPP) Waste Analysis Plan (WAP) contained in the Hazardous Waste Facility Permit (NM4890139088-TSDF) issued by the New Mexico Environment Department (NMED). The WAP requires participation in the PDP; the PDP must comply with the QAPD and the WAP. This plan implements the general requirements of the QAPD and the applicable requirements of the WAP for the Headspace Gas (HSG) PDP. Participating measurement facilities analyze blind audit samples of simulated TRU waste package headspace gases according to the criteria set by this PDP Plan. Blind audit samples (hereafter referred to as PDP samples) are used as an independent means to assess each measurement facility’s compliance with the WAP quality assurance objectives (QAOs). To the extent possible, the concentrations of VOC analytes in the PDP samples encompass the range of concentrations anticipated in actual TRU waste package headspace gas samples. Analyses of headspace gases are required by the WIPP to demonstrate compliance with regulatory requirements. These analyses must be performed by measurement facilities that have demonstrated acceptable performance in this PDP. These analyses are referred to as WIPP analyses and the TRU waste package headspace gas samples on which they are performed are referred to as WIPP samples in this document. Participating measurement facilities must analyze PDP samples using the same procedures used for routine waste characterization analyses of WIPP samples.

  15. Steam Production from Waste Stack Gases in a Carbon Black Plant 

    E-Print Network [OSTI]

    Istre, R. I.

    1981-01-01T23:59:59.000Z

    the boilers down in an orderly manner that would not upset the refinery operations. Cylinders of compressed air were connected to the new plant air dryer system to allow normal opera tion of the ignition interlock system and boiler control valves during... the emergency shutdown of the boi 1ers. The ignition interlock system has been used many times other than for Douer fa il ures. SVlitches \\~ere installed in the control room to allow the boiler control operator to shut dOl'in 42" YJaste gas dampers on each...

  16. Compensated infrared absorption sensor for carbon dioxide and other infrared absorbing gases

    DOE Patents [OSTI]

    Owen, Thomas E.

    2005-11-29T23:59:59.000Z

    A gas sensor, whose chamber uses filters and choppers in either a semicircular geometry or annular geometry, and incorporates separate infrared radiation filters and optical choppers. This configuration facilitates the use of a single infrared radiation source and a single detector for infrared measurements at two wavelengths, such that measurement errors may be compensated.

  17. ARM - PI Product - ARM-LBNL-NOAA Flask Sampler for Carbon Cycle Gases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625govInstrumentstdmadap Documentation TDMADAP : XDCnarrowbandheat fluxChinaNews : AMFAlaskaNewsOxidesMC3ECF

  18. Thermodynamics of sustaining gases in the roughness of submerged superhydrophobic surfaces

    E-Print Network [OSTI]

    Neelesh A. Patankar

    2015-05-22T23:59:59.000Z

    Rough surfaces submerged in a liquid can remain almost dry if the liquid does not fully wet the roughness and gases are sustained in roughness grooves. Such partially dry surfaces can help reduce drag or enhance boiling. Gases sustained in roughness grooves would be composed of air and the vapor phase of the liquid itself. The thermodynamics of sustaining vapor was considered in a prior work [Patankar, Soft Matter, 2010, 6:1613]. Here, the thermodynamics of sustaining gases (e.g. air) is considered. Governing equations are presented along with a solution methodology to determine a critical condition to sustain gases. The critical roughness scale to sustain gases is estimated for different degrees of saturation of gases dissolved in the liquid. It is shown that roughness spacings of less than a micron are essential to sustain gases on surfaces submerged in water at atmospheric pressure. This is consistent with prior empirical data.

  19. Carbon Fiber

    ScienceCinema (OSTI)

    McGetrick, Lee

    2014-07-23T23:59:59.000Z

    Lee McGetrick leads ORNL's effort to produce light, durable carbon fiber at lower cost -- a key to improvements in manufacturing that will produce more fuel-efficient vehicles and other advances.

  20. Carbon Sequestration

    SciTech Connect (OSTI)

    None

    2013-05-06T23:59:59.000Z

    Carbon Sequestration- the process of capturing the CO2 released by the burning of fossil fuels and storing it deep withing the Earth, trapped by a non-porous layer of rock.

  1. Carbon Fiber

    SciTech Connect (OSTI)

    McGetrick, Lee

    2014-04-17T23:59:59.000Z

    Lee McGetrick leads ORNL's effort to produce light, durable carbon fiber at lower cost -- a key to improvements in manufacturing that will produce more fuel-efficient vehicles and other advances.

  2. Electrochemical formation of hydroxide for enhancing carbon dioxide and acid gas uptake by a solution

    DOE Patents [OSTI]

    Rau, Gregory Hudson (Castro Valley, CA)

    2012-05-15T23:59:59.000Z

    A system is described for forming metal hydroxide from a metal carbonate utilizing a water electrolysis cell having an acid-producing anode and a hydroxyl-producing cathode immersed in a water solution of sufficient ionic content to allow an electric current to pass between the hydroxyl-producing cathode and the acid-producing anode. A metal carbonate, in particular water-insoluble calcium carbonate or magnesium carbonate, is placed in close proximity to the acid-producing anode. A direct current electrical voltage is provided across the acid-producing anode and the hydroxyl-producing cathode sufficient to generate acid at the acid-producing anode and hydroxyl ions at the hydroxyl-producing cathode. The acid dissolves at least part of the metal carbonate into metal and carbonate ions allowing the metal ions to travel toward the hydroxyl-producing cathode and to combine with the hydroxyl ions to form the metal hydroxide. The carbonate ions travel toward the acid-producing anode and form carbonic acid and/or water and carbon dioxide. Among other uses, the metal hydroxide formed can be employed to absorb acid gases such as carbon dioxide from a gas mixture. The invention can also generate hydrogen and oxidative gases such as oxygen or chlorine.

  3. In situ and ex situ characterization of carbon corrosion in PEMFCs

    SciTech Connect (OSTI)

    Fairweather, Joseph D [Los Alamos National Laboratory; Bo, Li [Los Alamos National Laboratory; Mukundan, Rangachary [Los Alamos National Laboratory; Borup, Rodney L [Los Alamos National Laboratory; Fenton, James [FLORIDA SOLAR ENERGY CENTER

    2010-01-01T23:59:59.000Z

    Carbon corrosion is an important degradation mechanism that impairs PEMFC performance through destruction of catalyst connectivity, collapse of pore structure, and loss of hydrophobic character. In this study, carbon corrosion was quantified in situ by measurement of carbon dioxide in fuel cell exhaust gases through non-dispersive infrared spectroscopy (NDIR). Performance degradation was also studied by a DOE protocol for catalyst support accelerated stress testing. Finally, changes in gas diffusion layer and microporous layer carbon surfaces were observed through an ex situ aging procedure.

  4. Regenerable immobilized aminosilane sorbents for carbon dioxide capture applications

    DOE Patents [OSTI]

    Gay, McMahan; Choi, Sunho; Jones, Christopher W

    2014-09-16T23:59:59.000Z

    A method for the separation of carbon dioxide from ambient air and flue gases is provided wherein a phase separating moiety with a second moiety are simultaneously coupled and bonded onto an inert substrate to create a mixture which is subsequently contacted with flue gases or ambient air. The phase-separating moiety is an amine whereas the second moiety is an aminosilane, or a Group 4 propoxide such as titanium (IV) propoxide (tetrapropyl orthotitanate, C.sub.12H.sub.28O.sub.4Ti). The second moiety makes the phase-separating moiety insoluble in the pores of the inert substrate. The new sorbents have a high carbon dioxide loading capacity and considerable stability over hundreds of cycles. The synthesis method is readily scalable for commercial and industrial production.

  5. Estimation of mass transport parameters of gases for quantifying CH{sub 4} oxidation in landfill soil covers

    SciTech Connect (OSTI)

    Im, J.; Moon, S.; Nam, K.; Kim, Y.-J. [Department of Civil and Environmental Engineering, College of Engineering, Seoul National University, Seoul (Korea, Republic of); Kim, J.Y. [Department of Civil and Environmental Engineering, College of Engineering, Seoul National University, Seoul (Korea, Republic of)], E-mail: jaeykim@snu.ac.kr

    2009-02-15T23:59:59.000Z

    Methane (CH{sub 4}), which is one of the most abundant anthropogenic greenhouse gases, is produced from landfills. CH{sub 4} is biologically oxidized to carbon dioxide, which has a lower global warming potential than methane, when it passes through a cover soil. In order to quantify the amount of CH{sub 4} oxidized in a landfill cover soil, a soil column test, a diffusion cell test, and a mathematical model analysis were carried out. In the column test, maximum oxidation rates of CH{sub 4} (V{sub max}) showed higher values in the upper part of the column than those in the lower part caused by the penetration of O{sub 2} from the top. The organic matter content in the upper area was also higher due to the active microbial growth. The dispersion analysis results for O{sub 2} and CH{sub 4} in the column are counter-intuitive. As the upward flow rate of the landfill gas increased, the dispersion coefficient of CH{sub 4} slightly increased, possibly due to the effect of mechanical dispersion. On the other hand, as the upward flow rate of the landfill gas increased, the dispersion coefficient of O{sub 2} decreased. It is possible that the diffusion of gases in porous media is influenced by the counter-directional flow rate. Further analysis of other gases in the column, N{sub 2} and CO{sub 2}, may be required to support this hypothesis, but in this paper we propose the possibility that the simulations using the diffusion coefficient of O{sub 2} under the natural condition may overestimate the penetration of O{sub 2} into the soil cover layer and consequently overestimate the oxidation of CH{sub 4}.

  6. Proceedings of the International Workshop on Sustainable ForestManagement: Monitoring and Verification of Greenhouse Gases

    SciTech Connect (OSTI)

    Sathaye (Ed.), Jayant; Makundi (Ed.), Willy; Goldberg (Ed.),Beth; Andrasko (Ed.), Ken; Sanchez (Ed.), Arturo

    1997-07-01T23:59:59.000Z

    The International Workshop on Sustainable Forest Management: Monitoring and Verification of Greenhouse Gases was held in San Jose, Costa Rica, July 29-31, 1996. The main objectives of the workshop were to: (1) assemble key practitioners of forestry greenhouse gas (GHG) or carbon offset projects, remote sensing of land cover change, guidelines development, and the forest products certification movement, to offer presentations and small group discussions on findings relevant to the crucial need for the development of guidelines for monitoring and verifying offset projects, and (2) disseminate the findings to interested carbon offset project developers and forestry and climate change policy makers, who need guidance and consistency of methods to reduce project transaction costs and increase probable reliability of carbon benefits, at appropriate venues. The workshop brought together about 45 participants from developed, developing, and transition countries. The participants included researchers, government officials, project developers, and staff from regional and international agencies. Each shared his or her perspectives based on experience in the development and use of methods for monitoring and verifying carbon flows from forest areas and projects. A shared sense among the participants was that methods for monitoring forestry projects are well established, and the techniques are known and used extensively, particularly in production forestry. Introducing climate change with its long-term perspective is often in conflict with the shorter-term perspective of most forestry projects and standard accounting principles. The resolution of these conflicts may require national and international agreements among the affected parties. The establishment of guidelines and protocols for better methods that are sensitive to regional issues will be an important first step to increase the credibility of forestry projects as viable mitigation options. The workshop deliberations led to three primary outputs: (1) a Workshop Statement in the JI Quarterly, September, 1996; (2) the publication of a series of selected peer-reviewed technical papers from the workshop in a report of the Lawrence Berkeley National Laboratory (LBNL. 40501); and (3) a special issue of the journal ''Mitigation and Adaptation Strategies for Global Change'', Kluwer Academic Publishers. The outputs will be distributed to practitioners in this field and to negotiators attending the Framework Convention on Climate Change (FCCC) deliberations leading up to the Third conference of Parties in Kyoto, in December 1997.

  7. Low Carbon Fuel Standards

    E-Print Network [OSTI]

    Sperling, Dan; Yeh, Sonia

    2009-01-01T23:59:59.000Z

    gas, or even coal with carbon capture and sequestration. Afuels that facilitate carbon capture and sequestration. Forenergy and could capture and sequester carbon emissions.

  8. Capturing carbon | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    carbon Released: October 02, 2011 New technology enables molecular-level insight into carbon sequestration Carbon sequestration is a potential solution for reducing greenhouse...

  9. TOWARD DEADLINE AWARE LOW CARBON SUPPLY CHAIN Amirreza Tahamtan, A Min Tjoa

    E-Print Network [OSTI]

    solutions have the potential of reducing global green- house gases by 15%. In addition to the ecological and moving toward a low carbon economy is the great challenge of our time. Aside from the ecological impact technological challenge of our time is tackling climate change with its ecological, economical, social

  10. Development of a Fully-Integrated Ultrasensitive Wireless Sensor Utilizing Carbon Nanotubes and Surface Plasmon Theory

    E-Print Network [OSTI]

    Tentzeris, Manos

    of a direct physical contact. CNT mixtures/composites were found to have electrical properties highly sensitive to extremely small quantities of gases, such as ammonia (NH3), carbon dioxide (CO2), nitrogen require a high temperature for operating conditions. Therefore, a gas sensor that can operate at room

  11. Wildland fire emissions, carbon, and climate: U.S. emissions inventories Narasimhan K. Larkin a,

    E-Print Network [OSTI]

    Wildland fire emissions, carbon, and climate: U.S. emissions inventories Narasimhan K. Larkin a: Fire emissions Emissions inventories Greenhouse gases a b s t r a c t Emissions from wildland fire fire emissions change considerably due to fluctuations from year to year with overall fire season

  12. Carbonation of alkaline paper mill waste to reduce CO2 greenhouse gas emissions into the atmosphere

    E-Print Network [OSTI]

    Montes-Hernandez, German

    Carbonation of alkaline paper mill waste to reduce CO2 greenhouse gas emissions into the atmosphere of anthropogenic emission of greenhouse gases into the atmosphere such as CO2, CH4, N2O and CFCs. The CO2 emissions to reflect, adsorb and emit the solar energy. However, the continuous emissions of CO2 into the atmosphere

  13. Performance Demonstration Program Plan for Analysis of Simulated Headspace Gases

    SciTech Connect (OSTI)

    Carlsbad Field Office

    2007-11-13T23:59:59.000Z

    The Performance Demonstration Program (PDP) for headspace gases distributes blind audit samples in a gas matrix for analysis of volatile organic compounds (VOCs). Participating measurement facilities (i.e., fixed laboratories, mobile analysis systems, and on-line analytical systems) are located across the United States. Each sample distribution is termed a PDP cycle. These evaluation cycles provide an objective measure of the reliability of measurements performed for transuranic (TRU) waste characterization. The primary documents governing the conduct of the PDP are the Quality Assurance Program Document (QAPD) (DOE/CBFO-94-1012) and the Waste Isolation Pilot Plant (WIPP) Waste Analysis Plan (WAP) contained in the Hazardous Waste Facility Permit (NM4890139088-TSDF) issued by the New Mexico Environment Department (NMED). The WAP requires participation in the PDP; the PDP must comply with the QAPD and the WAP. This plan implements the general requirements of the QAPD and the applicable requirements of the WAP for the Headspace Gas (HSG) PDP. Participating measurement facilities analyze blind audit samples of simulated TRU waste package headspace gases according to the criteria set by this PDP Plan. Blind audit samples (hereafter referred to as PDP samples) are used as an independent means to assess each measurement facility’s compliance with the WAP quality assurance objectives (QAOs). To the extent possible, the concentrations of VOC analytes in the PDP samples encompass the range of concentrations anticipated in actual TRU waste package headspace gas samples. Analyses of headspace gases are required by the WIPP to demonstrate compliance with regulatory requirements. These analyses must be performed by measurement facilities that have demonstrated acceptable performance in this PDP. These analyses are referred to as WIPP analyses and the TRU waste package headspace gas samples on which they are performed are referred to as WIPP samples in this document. Participating measurement facilities must analyze PDP samples using the same procedures used for routine waste characterization analyses of WIPP samples.

  14. Performance Demonstration Program Plan for Analysis of Simulated Headspace Gases

    SciTech Connect (OSTI)

    Carlsbad Field Office

    2007-11-19T23:59:59.000Z

    The Performance Demonstration Program (PDP) for headspace gases distributes blind audit samples in a gas matrix for analysis of volatile organic compounds (VOCs). Participating measurement facilities (i.e., fixed laboratories, mobile analysis systems, and on-line analytical systems) are located across the United States. Each sample distribution is termed a PDP cycle. These evaluation cycles provide an objective measure of the reliability of measurements performed for transuranic (TRU) waste characterization. The primary documents governing the conduct of the PDP are the Quality Assurance Program Document (QAPD) (DOE/CBFO-94-1012) and the Waste Isolation Pilot Plant (WIPP) Waste Analysis Plan (WAP) contained in the Hazardous Waste Facility Permit (NM4890139088-TSDF) issued by the New Mexico Environment Department (NMED). The WAP requires participation in the PDP; the PDP must comply with the QAPD and the WAP. This plan implements the general requirements of the QAPD and the applicable requirements of the WAP for the Headspace Gas (HSG) PDP. Participating measurement facilities analyze blind audit samples of simulated TRU waste package headspace gases according to the criteria set by this PDP Plan. Blind audit samples (hereafter referred to as PDP samples) are used as an independent means to assess each measurement facility’s compliance with the WAP quality assurance objectives (QAOs). To the extent possible, the concentrations of VOC analytes in the PDP samples encompass the range of concentrations anticipated in actual TRU waste package headspace gas samples. Analyses of headspace gases are required by the WIPP to demonstrate compliance with regulatory requirements. These analyses must be performed by measurement facilities that have demonstrated acceptable performance in this PDP. These analyses are referred to as WIPP analyses and the TRU waste package headspace gas samples on which they are performed are referred to as WIPP samples in this document. Participating measurement facilities must analyze PDP samples using the same procedures used for routine waste characterization analyses of WIPP samples.

  15. Thermocatalytic process for CO.sub.2-free production of hydrogen and carbon from hydrocarbons

    DOE Patents [OSTI]

    Muradov, Nazim Z. (Melbourne, FL)

    2011-08-23T23:59:59.000Z

    A novel process and apparatus are disclosed for sustainable CO.sub.2-free production of hydrogen and carbon by thermocatalytic decomposition (dissociation, pyrolysis, cracking) of hydrocarbon fuels over carbon-based catalysts in the absence of air and/or water. The apparatus and thermocatalytic process improve the activity and stability of carbon catalysts during the thermocatalytic process and produce both high purity hydrogen (at least, 99.0 volume %) and carbon, from any hydrocarbon fuel, including sulfurous fuels. In a preferred embodiment, production of hydrogen and carbon is achieved by both internal and external activation of carbon catalysts. Internal activation of carbon catalyst is accomplished by recycling of hydrogen-depleted gas containing unsaturated and aromatic hydrocarbons back to the reactor. External activation of the catalyst can be achieved via surface gasification with hot combustion gases during catalyst heating. The process and apparatus can be conveniently integrated with any type of fuel cell to generate electricity.

  16. Direct conversion of light hydrocarbon gases to liquid fuel

    SciTech Connect (OSTI)

    Kaplan, R.D.; Foral, M.J.

    1992-05-16T23:59:59.000Z

    Amoco oil Company, has investigated the direct, non-catalytic conversion of light hydrocarbon gases to liquid fuels (particularly methanol) via partial oxidation. The primary hydrocarbon feed used in these studies was natural gas. This report describes work completed in the course of our two-year project. In general we determined that the methanol yields delivered by this system were not high enough to make it economically attractive. Process variables studied included hydrocarbon feed composition, oxygen concentration, temperature and pressure effects, residence time, reactor design, and reactor recycle.

  17. Prospecting by sampling and analysis of airborne particulates and gases

    DOE Patents [OSTI]

    Sehmel, G.A.

    1984-05-01T23:59:59.000Z

    A method is claimed for prospecting by sampling airborne particulates or gases at a ground position and recording wind direction values at the time of sampling. The samples are subsequently analyzed to determine the concentrations of a desired material or the ratios of the desired material to other identifiable materials in the collected samples. By comparing the measured concentrations or ratios to expected background data in the vicinity sampled, one can select recorded wind directions indicative of the upwind position of the land-based source of the desired material.

  18. Two-phase compressibility factors for retrograde gases 

    E-Print Network [OSTI]

    Rayes, Daniel George

    1989-01-01T23:59:59.000Z

    . K. , M Cain, W. D. , Jr. and Jennings, J. W. : "An Improved Method for the Determination of the Reservoir Specific Gravity for Retrograde Gases, " JPT (July 1989) 747-752. 7. Craft, B. C. and Hawkins, M. F. : A li P 1 m R rv ir En ine rin...). Variable Mean Standard Deviation Minimum Maximum H2S CO2 N2 CI C2 C3 IC4 NC4 IC5 NC5 C6 C7+ M. W. C7+ S. G. C7+ 1, 01840 0. 00997 0. 02545 0. 01840 0. 73233 0. 07584 0. 03948 0. 00859 0. 01482 0. 00611 0. 00637 0. 00857 0. 05404...

  19. EIA-Voluntary Reporting of Greenhouse Gases Program

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere IRaghuraji Agro IndustriesTownDells, Wisconsin:DeploymentSite Name: Email: Terminal2,7,7,of Greenhouse Gases

  20. Equation calculates activated carbon's capacity for adsorbing pollutants

    SciTech Connect (OSTI)

    Yaws, C.L.; Bu, L.; Nijhawan, S. (Lamar Univ., Beaumont, TX (United States))

    1995-02-13T23:59:59.000Z

    Adsorption on activated carbon is an effective method for removing volatile organic compound (VOC) contaminants from gases. A new, simple equation has been developed for calculating activated carbon's adsorption capacity as a function of the VOC concentration in the gas. The correlation shows good agreement with experimental results. Results from the equation are applicable for conditions commonly encountered in air pollution control techniques (25 C, 1 atm). The only input parameters needed are VOC concentrations and a table of correlation coefficients for 292 C[sub 8]-C[sub 14] compounds. The table is suitable for rapid engineering usage with a personal computer or hand calculator.

  1. Carbon supercapacitors

    SciTech Connect (OSTI)

    Delnick, F.M.

    1993-11-01T23:59:59.000Z

    Carbon supercapacitors are represented as distributed RC networks with transmission line equivalent circuits. At low charge/discharge rates and low frequencies these networks approximate a simple series R{sub ESR}C circuit. The energy efficiency of the supercapacitor is limited by the voltage drop across the ESR. The pore structure of the carbon electrode defines the electrochemically active surface area which in turn establishes the volume specific capacitance of the carbon material. To date, the highest volume specific capacitance reported for a supercapacitor electrode is 220F/cm{sup 3} in aqueous H{sub 2}SO{sub 4} (10) and {approximately}60 F/cm{sup 3} in nonaqueous electrolyte (8).

  2. Gel and process for preventing carbon dioxide break through

    SciTech Connect (OSTI)

    Sandiford, B.B.; Zillmer, R.C.

    1987-06-16T23:59:59.000Z

    A process is described for retarding the flow of carbon dioxide in carbon dioxide break-through fingers in a subterranean formation, the process comprising: (a) introducing a gas selected from the group consisting of carbon dioxide and gases containing carbon dioxide into a subterranean deposit containing carbon dioxide break-through fingers; (b) after the carbon dioxide break-through fingers have sorbed a predetermined amount of the gas, stopping the flow of the gas into the subterranean formation, (c) after stopping the flow of the gas into the subterranean formation, introducing an effective amount of a gel-forming composition into the subterranean formation and into the carbon dioxide break-through fingers, the gel-forming composition being operable, when contacting carbon dioxide break-through fingers containing the brine which has absorbed substantial amounts of carbon dioxide to form a gel in the fingers which is operable for retarding the flow of the gas in the finger. The gel-forming composition comprises: i. an aqueous solution comprising a first substance selected from the group consisting of polyvinyl alcohols, polyvinyl alcohol copolymers, and mixtures thereof, and ii. an amount of a second substance selected from the group consisting of aldehydes, aldehyde generating substances, acetals, acetal generating substances, and mixtures thereof.

  3. Carbon microtubes

    DOE Patents [OSTI]

    Peng, Huisheng (Shanghai, CN); Zhu, Yuntian Theodore (Cary, NC); Peterson, Dean E. (Los Alamos, NM); Jia, Quanxi (Los Alamos, NM)

    2011-06-14T23:59:59.000Z

    A carbon microtube comprising a hollow, substantially tubular structure having a porous wall, wherein the microtube has a diameter of from about 10 .mu.m to about 150 .mu.m, and a density of less than 20 mg/cm.sup.3. Also described is a carbon microtube, having a diameter of at least 10 .mu.m and comprising a hollow, substantially tubular structure having a porous wall, wherein the porous wall comprises a plurality of voids, said voids substantially parallel to the length of the microtube, and defined by an inner surface, an outer surface, and a shared surface separating two adjacent voids.

  4. Instantaneous and efficient surface wave excitation of a low pressure gas or gases

    DOE Patents [OSTI]

    Levy, Donald J. (Berkeley, CA); Berman, Samuel M. (San Francisco, CA)

    1988-01-01T23:59:59.000Z

    A system for instantaneously ionizing and continuously delivering energy in the form of surface waves to a low pressure gas or mixture of low pressure gases, comprising a source of rf energy, a discharge container, (such as a fluorescent lamp discharge tube), an rf shield, and a coupling device responsive to rf energy from the source to couple rf energy directly and efficiently to the gas or mixture of gases to ionize at least a portion of the gas or gases and to provide energy to the gas or gases in the form of surface waves. The majority of the rf power is transferred to the gas or gases near the inner surface of the discharge container to efficiently transfer rf energy as excitation energy for at least one of the gases. The most important use of the invention is to provide more efficient fluorescent and/or ultraviolet lamps.

  5. Carbon Storage Program

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Carbon Sequestration Partnership MSU . . . . . . . . . . . . . . . . . . . . . . . Montana State University MVA . . . . . . . . . . . . . . . . . . . . . . . Monitoring,...

  6. Process for recovery of sulfur from acid gases

    DOE Patents [OSTI]

    Towler, Gavin P. (Kirkbymoorside, GB2); Lynn, Scott (Pleasant Hill, CA)

    1995-01-01T23:59:59.000Z

    Elemental sulfur is recovered from the H.sub.2 S present in gases derived from fossil fuels by heating the H.sub.2 S with CO.sub.2 in a high-temperature reactor in the presence of a catalyst selected as one which enhances the thermal dissociation of H.sub.2 S to H.sub.2 and S.sub.2. The equilibrium of the thermal decomposition of H.sub.2 S is shifted by the equilibration of the water-gas-shift reaction so as to favor elemental sulfur formation. The primary products of the overall reaction are S.sub.2, CO, H.sub.2 and H.sub.2 O. Small amounts of COS, SO.sub.2 and CS.sub.2 may also form. Rapid quenching of the reaction mixture results in a substantial increase in the efficiency of the conversion of H.sub.2 S to elemental sulfur. Plant economy is further advanced by treating the product gases to remove byproduct carbonyl sulfide by hydrolysis, which converts the COS back to CO.sub.2 and H.sub.2 S. Unreacted CO.sub.2 and H.sub.2 S are removed from the product gas and recycled to the reactor, leaving a gas consisting chiefly of H.sub.2 and CO, which has value either as a fuel or as a chemical feedstock and recovers the hydrogen value from the H.sub.2 S.

  7. Self-pulsing of hollow cathode discharge in various gases

    SciTech Connect (OSTI)

    Qin, Y.; He, F., E-mail: hefeng@bit.edu.cn; Jiang, X. X.; Ouyang, J. T., E-mail: jtouyang@bit.edu.cn [School of Physics, Beijing Institute of Technology, Beijing 100081 (China); Xie, K. [School of Aerospace Engineering, Beijing Institute of Technology, Beijing 100081 (China)

    2014-07-15T23:59:59.000Z

    In this paper, we investigate the self-pulsing phenomenon of cavity discharge in a cylindrical hollow cathode in various gases including argon, helium, nitrogen, oxygen, and air. The current-voltage characteristics of the cavity discharge, the waveforms of the self-pulsing current and voltage as well as the repetition frequency were measured. The results show that the pulsing frequency ranges from a few to tens kilohertz and depends on the averaged current and the pressure in all gases. The pulsing frequency will increase with the averaged current and decrease with the pressure. The rising time of the current pulse is nearly constant in a given gas or mixture. The self-pulsing does not depend on the external ballast but is affected significantly by the external capacitor in parallel with the discharge cell. The low-current self-pulsing in hollow cathode discharge is the mode transition between Townsend and glow discharges. It can be described by the charging-discharging process of an equivalent circuit consisting of capacitors and resistors.

  8. Dark resonances for ground state transfer of molecular quantum gases

    E-Print Network [OSTI]

    Manfred J. Mark; Johann G. Danzl; Elmar Haller; Mattias Gustavsson; Nadia Bouloufa; Olivier Dulieu; Houssam Salami; Tom Bergeman; Helmut Ritsch; Russell Hart; Hanns-Christoph Nägerl

    2008-11-05T23:59:59.000Z

    One possible way to produce ultracold, high-phase-space-density quantum gases of molecules in the rovibronic ground state is given by molecule association from quantum-degenerate atomic gases on a Feshbach resonance and subsequent coherent optical multi-photon transfer into the rovibronic ground state. In ultracold samples of Cs_2 molecules, we observe two-photon dark resonances that connect the intermediate rovibrational level |v=73,J=2> with the rovibrational ground state |v=0,J=0> of the singlet $X^1\\Sigma_g^+$ ground state potential. For precise dark resonance spectroscopy we exploit the fact that it is possible to efficiently populate the level |v=73,J=2> by two-photon transfer from the dissociation threshold with the stimulated Raman adiabatic passage (STIRAP) technique. We find that at least one of the two-photon resonances is sufficiently strong to allow future implementation of coherent STIRAP transfer of a molecular quantum gas to the rovibrational ground state |v=0,J=0>.

  9. Low Carbon Fuel Standards

    E-Print Network [OSTI]

    Sperling, Dan; Yeh, Sonia

    2009-01-01T23:59:59.000Z

    gas, or even coal with carbon capture and sequestration. Afuels that facilitate carbon capture and sequestration. For

  10. Methanation of Carbon Dioxide

    E-Print Network [OSTI]

    Goodman, Daniel Jacob

    2013-01-01T23:59:59.000Z

    cycle plants, possibly with carbon capture and storage (CCS)natural gas plant with carbon capture and storage technology

  11. Methanation of Carbon Dioxide

    E-Print Network [OSTI]

    Goodman, Daniel Jacob

    2013-01-01T23:59:59.000Z

    gas plant with carbon capture and storage technology werewith carbon capture and storage (CCS) technology, to replace

  12. Carbon Additionality: Discussion Paper

    E-Print Network [OSTI]

    Carbon Additionality: A review Discussion Paper Gregory Valatin November 2009 Forest Research. Voluntary Carbon Standards American Carbon Registry Forest Carbon Project Standard (ACRFCPS) 27 CarbonFix Standard (CFS) 28 Climate, Community and Biodiversity Standard (CCBS) 28 Forest Carbon Standard (FCS) 28

  13. Carbon Trading, Carbon Taxes and Social Discounting

    E-Print Network [OSTI]

    Weiblen, George D

    Carbon Trading, Carbon Taxes and Social Discounting Elisa Belfiori belf0018@umn.edu University of Minnesota Abstract This paper considers the optimal design of policies to carbon emissions in an economy, such as price or quantity controls on the net emissions of carbon, are insufficient to achieve the social

  14. Loschmidt echo in one-dimensional interacting Bose gases

    SciTech Connect (OSTI)

    Lelas, K.; Seva, T.; Buljan, H. [Faculty of Electrical Engineering Mechanical Engineering and Naval Architecture, University of Split, Rudjera Boskovica BB, 21000 Split (Croatia); Department of Physics, University of Zagreb, Bijenicka c. 32, 10000 Zagreb (Croatia)

    2011-12-15T23:59:59.000Z

    We explore Loschmidt echo in two regimes of one-dimensional interacting Bose gases: the strongly interacting Tonks-Girardeau (TG) regime, and the weakly interacting mean-field regime. We find that the Loschmidt echo of a TG gas decays as a Gaussian when small (random and time independent) perturbations are added to the Hamiltonian. The exponent is proportional to the number of particles and the magnitude of a small perturbation squared. In the mean-field regime the Loschmidt echo shows richer behavior: it decays faster for larger nonlinearity, and the decay becomes more abrupt as the nonlinearity increases; it can be very sensitive to the particular realization of the noise potential, especially for relatively small nonlinearities.

  15. Photolysis of water for production of fuel gases

    SciTech Connect (OSTI)

    Eror, N.G.; Blakemore, J.S.

    1981-12-01T23:59:59.000Z

    To better understand the role of the semiconductor electrode in the photocatalytic decomposition of water to form hydrogen and other fuel gases, researchers characterized the defect structure of a number of large-band-gap semiconductor electrode materials. The defect structure of SrTiO/sub 3/ samples has been related to photoelectrochemical cell response, leading to a signficant improvement in the understanding of how electrode properties influence cell performance. Although the large band gap of these materials severely restricts their ability to use the solar spectrum, they are more resistant to photocorrosion than lower-band-gap materials. This band gap has been reduced somewhat in lanthanum-doped SrTiO/sub 3/ samples without compromising photostability or requiring a bias voltage for water decomposition.

  16. Finite-size energy of non-interacting Fermi gases

    E-Print Network [OSTI]

    Martin Gebert

    2014-06-14T23:59:59.000Z

    We prove the asymptotics of the difference of the ground-state energies of two non-interacting $N$-particle Fermi gases on the half line of length $L$ in the thermodynamic limit up to order $1/L$. We are particularly interested in subdominant terms proportional to $1/L$, called finite-size energy. In the nineties Affleck and co-authors [Aff97, ZA97, AL94] claimed that the finite-size energy equals the decay exponent occuring in Anderson's orthogonality catastrophe. It turns out that the finite-size energy depends on the details of the thermodynamic limit and typically also includes a linear term in the scattering phase shift.

  17. Free Energies of Dilute Bose gases: upper bound

    E-Print Network [OSTI]

    Jun Yin

    2010-12-19T23:59:59.000Z

    We derive a upper bound on the free energy of a Bose gas system at density $\\rho$ and temperature $T$. In combination with the lower bound derived previously by Seiringer \\cite{RS1}, our result proves that in the low density limit, i.e., when $a^3\\rho\\ll 1$, where $a$ denotes the scattering length of the pair-interaction potential, the leading term of $\\Delta f$ the free energy difference per volume between interacting and ideal Bose gases is equal to $4\\pi a (2\\rho^2-[\\rho-\\rhoc]^2_+)$. Here, $\\rhoc(T)$ denotes the critical density for Bose-Einstein condensation (for the ideal gas), and $[\\cdot ]_+$ $=$ $\\max\\{\\cdot, 0\\}$ denotes the positive part.

  18. Elliptic flow and nearly perfect fluidity in dilute Fermi gases

    E-Print Network [OSTI]

    Thomas Schaefer

    2010-12-16T23:59:59.000Z

    In this contribution we summarize recent progress in understanding the shear viscosity of strongly correlated dilute Fermi gases. We discuss predictions from kinetic theory, and show how these predictions can be tested using recent experimental data on elliptic flow. We find agreement between theory and experiments in the high temperature regime $T\\gg T_F$, where $T_F$ is the the temperature where quantum degeneracy effects become important. In the low temperature regime, $T\\sim T_F$, the strongest constraints on the shear viscosity come from experimental studies of the damping of collective modes. These experiments indicate that $\\eta/s\\lsim 0.5\\hbar/k_B$, where $\\eta$ is the shear viscosity and $s$ is the entropy density.

  19. Light pulse in {Lambda}-type cold-atom gases

    SciTech Connect (OSTI)

    Wei Ran; Deng Youjin; Chen Shuai; Chen Zengbing; Pan Jianwei [Hefei National Laboratory for Physical Sciences at Microscale and Department of Modern Physics, University of Science and Technology of China, Hefei, Anhui 230026 (China); Zhao Bo [Institute for Theoretical physics, University of Innsbruck, A-6020 Innsbruck (Austria); Institute for Quantum Optics and Quantum Information of the Austrian Academy of Science, A-6020 Innsbruck (Austria)

    2010-04-15T23:59:59.000Z

    We investigate the behavior of the light pulse in {Lambda}-type cold-atom gases with two counter-propagating control lights with equal strength by directly simulating the dynamic equations and exploring the dispersion relation. Our analysis shows that, depending on the length L{sub 0} of the stored wave packet and the decay rate {gamma} of ground-spin coherence, the recreated light can behave differently. For long L{sub 0} and/or large {gamma}, a stationary light pulse is produced, while two propagating light pulses appear for short L{sub 0} and/or small {gamma}. In the {gamma}{yields}0 limit, the light always splits into two propagating pulses for a sufficiently long time. This scenario agrees with a recent experiment [Y.-W. Lin et al., Phys. Rev. Lett. 102, 213601 (2009)] where two propagating light pulses are generated in laser-cooled cold-atom ensembles.

  20. Fuel cell stack with internal manifolds for reactant gases

    DOE Patents [OSTI]

    Schnacke, Arthur W. (Schenectady, NY)

    1985-01-01T23:59:59.000Z

    A fuel cell stack includes a plurality of plate-like fuel cells arranged along an axis generally parallel to cell thickness with electrically conductive separator plates between each pair of cells. A plurality of axial manifolds are provided at opposite sides of the stack in outer marginal portions beyond the edges of electrodes and electrolyte tiles. Sealing rings prevent cross-leakage of oxidant fuel gases through use of pairs of outwardly extending lips from opposite tile surfaces bonded to first and second electrode frames respectively. The frames provide transition between electrode edges and manifold perimeters. The pairs of extension lips are sealingly bonded together through an electrically insulative sealing ring with wedge shaped fastening members.

  1. Fuel cell stack with internal manifolds for reactant gases

    DOE Patents [OSTI]

    Schnacke, A.W.

    1983-10-12T23:59:59.000Z

    A fuel cell stack includes a plurality of plate-like fuel cells arranged along an axis generally parallel to cell thickness with electrically conductive separator plates between each pair of cells. A plurality of axial manifolds are provided at opposite sides of the stack in outer marginal portions beyond the edges of electrodes and electrolyte tiles. Sealing rings prevent cross-leakage of oxidant fuel gases through use of pairs of outwardly extending lips from opposite tile surfaces bonded to first and second electrode frames respectively. The frames provide transition between electrode edges and manifold perimeters. The pairs of extension lips are sealingly bonded together through an electrically insulative sealing ring with wedge shaped fastening members.

  2. A Combustion Chemistry Analysis of Carbonate Solvents in Li-Ion Batteries

    SciTech Connect (OSTI)

    Harris, S J; Timmons, A; Pitz, W J

    2008-11-13T23:59:59.000Z

    Under abusive conditions Li-ion batteries can rupture, ejecting electrolyte and other flammable gases. In this paper we consider some of the thermochemical properties of these gases that will determine whether they ignite and how energetically they burn. We show that flames of carbonate solvents are fundamentally less energetic than those of conventional hydrocarbons. An example of this difference is given using a recently developed mechanism for dimethyl carbonate (DMC) combustion, where we show that a diffusion flame burning DMC has only half the peak energy release rate of an analogous propane flame. We find a significant variation among the carbonate solvents in the factors that are important to determining flammability, such as combustion enthalpy and vaporization enthalpy. This result suggests that thermochemical and kinetic factors might well be considered when choosing solvent mixtures.

  3. Method of depositing multi-layer carbon-based coatings for field emission

    DOE Patents [OSTI]

    Sullivan, John P. (Albuquerque, NM); Friedmann, Thomas A. (Albuquerque, NM)

    1999-01-01T23:59:59.000Z

    A novel field emitter device for cold cathode field emission applications, comprising a multi-layer resistive carbon film. The multi-layered film of the present invention is comprised of at least two layers of a resistive carbon material, preferably amorphous-tetrahedrally coordinated carbon, such that the resistivities of adjacent layers differ. For electron emission from the surface, the preferred structure comprises a top layer having a lower resistivity than the bottom layer. For edge emitting structures, the preferred structure of the film comprises a plurality of carbon layers, wherein adjacent layers have different resistivities. Through selection of deposition conditions, including the energy of the depositing carbon species, the presence or absence of certain elements such as H, N, inert gases or boron, carbon layers having desired resistivities can be produced. Field emitters made according the present invention display improved electron emission characteristics in comparison to conventional field emitter materials.

  4. Public Review Draft: A Method for Assessing Carbon Stocks, Carbon

    E-Print Network [OSTI]

    Public Review Draft: A Method for Assessing Carbon Stocks, Carbon Sequestration, and Greenhouse, and Zhu, Zhiliang, 2010, Public review draft; A method for assessing carbon stocks, carbon sequestration

  5. Carbon-Optimal and Carbon-Neutral Supply Chains

    E-Print Network [OSTI]

    Caro, F.; Corbett, C. J.; Tan, T.; Zuidwijk, R.

    2011-01-01T23:59:59.000Z

    Li, M. Daskin. 2009. Carbon Footprint and the Management ofThe Importance of Carbon Footprint Estimation Boundaries.Carbon accounting and carbon footprint - more than just

  6. Title of Dissertation: HIGH POWER NONLINEAR PROPAGATION OF LASER PULSES IN TENUOUS GASES

    E-Print Network [OSTI]

    Anlage, Steven

    ABSTRACT Title of Dissertation: HIGH POWER NONLINEAR PROPAGATION OF LASER PULSES IN TENUOUS GASES AND PLASMA CHANNELS Jianzhou Wu, Doctor of Philosophy, 2005 Dissertation Directed By: Professor Thomas M PROPAGATION OF LASER PULSES IN TENUOUS GASES AND PLASMA CHANNELS By Jianzhou Wu Dissertation submitted

  7. Monte Carlo Simulation of Radiation in Gases with a NarrowBand Model

    E-Print Network [OSTI]

    Dufresne, Jean-Louis

    , France (\\Phi) now at the Institute of Energy and Power Plant Technology, TH Darmstadt, 64287 DarmstadtMonte Carlo Simulation of Radiation in Gases with a Narrow­Band Model and a Net is used for simulation of radiative heat transfers in non­gray gases. The proposed procedure is based

  8. Abstract--Airborne pollution and explosive gases threaten human health and occupational safety, therefore generating high

    E-Print Network [OSTI]

    Mason, Andrew

    Abstract--Airborne pollution and explosive gases threaten human health and occupational safety and a thumb-drive sized prototype system. I. INTRODUCTION xposure to air pollution consistently ranks among to occupational safety as energy demands rise. Airborne pollutants and explosive gases vary in both time and space

  9. Permeation of Gases in Polymers: Parameter Identification and Nonlinear Regression Analysis

    E-Print Network [OSTI]

    Scheichl, Robert

    Permeation of Gases in Polymers: Parameter Identification and Nonlinear Regression Analysis Robert at PARAOPE, Heidelberg, June 30th, 2004 #12;Overview · Permeation of gases in polymers ­ Application areas for diffusion in polymers ­ Description of the experimental device ­ Mathematical model · Parameter

  10. Heavy noble gases in solar wind delivered by Genesis mission Alex Meshik a,

    E-Print Network [OSTI]

    measured in the Genesis solar wind collectors generally agree with the less precise values obtained fromHeavy noble gases in solar wind delivered by Genesis mission Alex Meshik a, , Charles Hohenberg knowledge of the isotopic composition of the heavy noble gases in solar wind and, by inference, the Sun

  11. Preserving noble gases in a convecting mantle Helge M. Gonnermann1

    E-Print Network [OSTI]

    Mukhopadhyay, Sujoy

    of a processed and out- gassed lower-mantle source, residues of mantle melting10,11 , depleted in uranium and mixing of noble-gas-depleted slabs dilutes the concentrations of noble gases in the mantle, thereby melt, which forms the ocean crust and leaves the residual mantle severely depleted of noble gases

  12. Bose-Einstein condensates in 85 Rb gases at higher densities

    E-Print Network [OSTI]

    Glyde, Henry R.

    Bose-Einstein condensates in 85 Rb gases at higher densities A. R. Sakhel, J. L. DuBois, and H. R August 2002; published 31 December 2002 The Bose-Einstein condensation in trapped gases of 85 Rb find that there is a significant depletion of the condensate at T 0 K, for example, 25% at na3 10 2

  13. Localization of Bogoliubov quasiparticles in interacting Bose gases with correlated disorder P. Lugan1,2

    E-Print Network [OSTI]

    Boyer, Edmond

    ) in a weakly interacting Bose gas of chemical potential µ subjected to a disordered potential V . We introduce-Einstein condensates [40­48], interacting Bose gases at equilibrium [26, 49­72], strongly interacting Fermi gases [73 behaviors can be found in various situa- tions. For instance, weak repulsive interactions in a Bose gas

  14. Geological Sequestration of CO2 by Hydrous Carbonate Formation with Reclaimed Slag

    SciTech Connect (OSTI)

    Von L. Richards; Kent Peaslee; Jeffrey Smith

    2008-02-06T23:59:59.000Z

    The concept of this project is to develop a process that improves the kinetics of the hydrous carbonate formation reaction enabling steelmakers to directly remove CO2 from their furnace exhaust gas. It is proposed to bring the furnace exhaust stream containing CO2 in contact with reclaimed steelmaking slag in a reactor that has an environment near the unit activity of water resulting in the production of carbonates. The CO2 emissions from the plant would be reduced by the amount sequestered in the formation of carbonates. The main raw materials for the process are furnace exhaust gases and specially prepared slag.

  15. Fast-quench reactor for hydrogen and elemental carbon production from natural gas and other hydrocarbons

    DOE Patents [OSTI]

    Detering, Brent A.; Kong, Peter C.

    2006-08-29T23:59:59.000Z

    A fast-quench reactor for production of diatomic hydrogen and unsaturated carbons is provided. During the fast quench in the downstream diverging section of the nozzle, such as in a free expansion chamber, the unsaturated hydrocarbons are further decomposed by reheating the reactor gases. More diatomic hydrogen is produced, along with elemental carbon. Other gas may be added at different stages in the process to form a desired end product and prevent back reactions. The product is a substantially clean-burning hydrogen fuel that leaves no greenhouse gas emissions, and elemental carbon that may be used in powder form as a commodity for several processes.

  16. Method of recovering sulfur from the hydrogen sulfide contained in coke oven gases

    SciTech Connect (OSTI)

    Laufhutte, D.

    1985-04-30T23:59:59.000Z

    Ammonia and hydrogen sulfide are washed out of the coke oven gas and stripped from the wash liquor in the form of gases and fumes or vapors. The ammonia is decomposed in a nickel catalyzer and a small part of the decomposition gases is supplied directly to a combustion furnace, while the larger part of the combustion gases is first cooled and freed from condensate, and only then supplied to the combustion furnace. In the combustion furnace, the proportion of H/sub 2/S/SO/sub 2/ needed for the Claus process is adjusted by a partial combustion of the decomposition gases. The gases from the combustion furnace are then processed in the Claus plant to sulfur.

  17. Combustion characteristics of hydrogen - carbon monoxide-based gaseous fuels

    SciTech Connect (OSTI)

    White, D.J.; Kubasco, A.J.; Lecren, R.T.; Notardonato, J.J.

    1983-01-01T23:59:59.000Z

    An experimental rig program has been conducted with the objective of evaluating the combustion performance of a family of fuel gases based on a mixture of hydrogen and carbon monoxide. These gases, in addition to being members of a family, were also representative of those secondary fuels that could be produced from coal by various gasification schemes. In particular, simulated Winkler, Lurgi, and Blue-water low and medium energy content gases were used as fuels in the experimental combustor rig. The combustor used was originally designed as a low NOx rich-lean system for burning liquid fuels with high bound nitrogen levels. When used with the above gaseous fuels this combustor was operated in a lean-lean mode with ultra long residence times. The Bluewater gas was also operated in a rich-lean mode. The results of these tests indicate the possibility of the existence of an ''optimum'' gas turbine hydrogen - carbon monoxide based secondary fuel. Such a fuel would exhibit low NOx and high efficiency over the entire engine operating range. It would also have sufficient stability range to allow normal light-off and engine acceleration. Solar Turbines Incorporated would like to emphasize that the results presented here have been obtained with experimental rig combustors. The technologies generated could, however, be utilized in future commercial gas turbines.

  18. Feasibility of reconstructing paleoatmospheric records of selected alkanes, methyl halides, and sulfur gases from Greenland ice cores

    E-Print Network [OSTI]

    Aydin, M.; Williams, M. B; Saltzman, E. S

    2007-01-01T23:59:59.000Z

    firn and ice at Summit, Greenland, J. Geophys. Res. , 98,AL. : TRACE GASES IN GREENLAND ICE CORE ¨ . Andreae Kettle,and sulfur gases from Greenland ice cores M. Aydin, 1 M. B.

  19. Emissions of Non-CO2 Greenhouse Gases From the Production and Use of Transportation Fuels and Electricity

    E-Print Network [OSTI]

    Delucchi, Mark

    1997-01-01T23:59:59.000Z

    EMISSIONS OF NON-CO2 GREENHOUSE GASES FROM THE PRODUCTION AND USE OF TRANSPORTATION FUELS AND ELECTRICITYEMISSIONS OF NON-CO2 GREENHOUSE GASES FROM THE PRODUCTION AND USE OF TRANSPORTATION FUELS AND ELECTRICITY

  20. Sources and fluxes of carbon in a large boreal hydroelectric reservoir of eastern Canada: an isotopic approach

    E-Print Network [OSTI]

    Long, Bernard

    Sources and fluxes of carbon in a large boreal hydroelectric reservoir of eastern Canada Hydroelectric reservoirs emit greenhouse gases (GHGs). Although a few hypothesis have been put forward at the surface of a large boreal hydroelectric reservoir of eastern Canada (Robert-Bourassa) as well

  1. CALIFORNIA CARBON SEQUESTRATION THROUGH

    E-Print Network [OSTI]

    CALIFORNIA ENERGY COMMISSION CARBON SEQUESTRATION THROUGH CHANGES IN LAND USE IN WASHINGTON. Carbon Sequestration Through Changes in Land Use in Washington: Costs and Opportunities. California for Terrestrial Carbon Sequestration in Oregon. Report to Winrock International. #12;ii #12;iii Preface

  2. Photophysics of carbon nanotubes

    E-Print Network [OSTI]

    Samsonidze, Georgii G

    2007-01-01T23:59:59.000Z

    This thesis reviews the recent advances made in optical studies of single-wall carbon nanotubes. Studying the electronic and vibrational properties of carbon nanotubes, we find that carbon nanotubes less than 1 nm in ...

  3. Oxygen buffering of Kilauea volcanic gases and the oxygen fugacity of Kilauea basalt

    SciTech Connect (OSTI)

    Gerlach, T.M. (Geological Survey, Vancouver, WA (United States))

    1993-02-01T23:59:59.000Z

    Volcanic gases collected during episode 1 of the Puu Oo eruption along the east rift zone of Kilauea Volcano, Hawaii, have uniform C-O-H-S-Cl-F compositions that are sharply depleted in CO[sub 2]. The CO[sub 2]-poor gases are typical of Type II volcanic gases (GERLACH and GRAEBER, 1985) and were emitted from evolved magma stored for a prolonged period of time in the east rift zone after releasing CO[sub 2]-rich gases during an earlier period of temporary residence in the summit magma chamber. The samples are remarkably free of contamination by atmospheric gases and meteoric water. Thermodynamic evaluation of the analytical data shows that the episode 1 gases have equilibrium compositions appropriate for temperatures between 935 and 1032[degrees]C. Open- and closed-system equilibrium models of species distributions for the episode 1 gases show unequivocally that coexisting lavas buffered the gas oxygen fugacities during cooling. These models indicate that the F[sub o[sub 2

  4. Toward Zero Carbon Energy Production Toward Zero Carbon Energy Production

    E-Print Network [OSTI]

    Narasayya, Vivek

    #12;Toward Zero Carbon Energy Production Toward Zero Carbon Energy Production Toward Zero Carbon Energy Production Toward Zero Carbon Energy Production Toward Zero Carbon Energy Production Toward Zero Carbon Energy Production Toward Zero Carbon Energy Production Toward Zero Carbon Energy Production Toward

  5. Carbon Code Requirements for voluntary carbon sequestration projects

    E-Print Network [OSTI]

    Woodland Carbon Code Requirements for voluntary carbon sequestration projects ® Version 1.2 July trademark 10 3. Carbon sequestration 11 3.1 Units of carbon calculation 11 3.2 Carbon baseline 11 3.3 Carbon leakage 12 3.4 Project carbon sequestration 12 3.5 Net carbon sequestration 13 4. Environmental quality 14

  6. Method of making carbon-carbon composites

    DOE Patents [OSTI]

    Engle, Glen B. (16716 Martincoit Rd., Poway, CA 92064)

    1993-01-01T23:59:59.000Z

    A process for making 2D and 3D carbon-carbon composites having a combined high crystallinity, high strength, high modulus and high thermal and electrical conductivity. High-modulus/high-strength mesophase derived carbon fibers are woven into a suitable cloth. Layers of this easily graphitizible woven cloth are infiltrated with carbon material to form green composites. The carbonized composite is then impregnated several times with pitch by covering the composite with hot pitch under pressure. The composites are given a heat treatment between each impregnant step to crack up the infiltrated carbon and allow additional pitch to enter the microstructure during the next impregnation cycle. The impregnated composites are then given a final heat treatment in the range 2500.degree. to 3100.degree. C. to fully graphitize the fibers and the matrix carbon. The composites are then infiltrated with pyrolytic carbon by chemical vapor deposition in the range 1000.degree. C. to 1300.degree. C. at a reduced. pressure.

  7. 2D Coulomb Gases and the Renormalized Energy

    E-Print Network [OSTI]

    Sandier, Etienne

    2012-01-01T23:59:59.000Z

    We study the statistical mechanics of classical two-dimensional "Coulomb gases" with general potential and arbitrary \\beta, the inverse of the temperature. Such ensembles also correspond to random matrix models in some particular cases. The formal limit case \\beta=\\infty corresponds to "weighted Fekete sets" and also falls within our analysis. It is known that in such a system points should be asymptotically distributed according to a macroscopic "equilibrium measure," and that a large deviations principle holds for this, as proven by Ben Arous and Zeitouni. By a suitable splitting of the Hamiltonian, we connect the problem to the "renormalized energy" W, a Coulombian interaction for points in the plane introduced in our prior work, which is expected to be a good way of measuring the disorder of an infinite configuration of points in the plane. By so doing, we are able to examine the situation at the microscopic scale, and obtain several new results: a next order asymptotic expansion of the partition function...

  8. Noble gases in the howardites Bholghati and Kapoeta

    SciTech Connect (OSTI)

    Swindle, T.D. (Univ. of Arizona, Tucson (USA)); Garrison, D.H.; Hohenberg, C.M.; Nichols, R.H.; Olinger, C.T. (Washington Univ., St. Louis, MO (USA)); Goswami, J.N. (Physical Research Laboratory, Ahmedabad (India))

    1990-08-01T23:59:59.000Z

    Analyses of noble gases in whole rock samples of the howardites Bholghati and Kapoeta and grain-size separates of Kapoeta yield evidence for excesses of the Xe isotopes {sup 129}Xe, {sup 131}Xe, {sup 132}Xe, {sup 134}Xe, and {sup 136}Xe in a low-temperature component, similar to lunar excess fission Xe. Such a component may be able to provide chronometric information if the relative abundances of radioactive progenitors ({sup 129}I, {sup 244}Pu, and {sup 238}U) can be determined, but the isotopic spectra we obtain are not sufficiently precise to do so. Eucritic clast BH-5 in Bholghati contains Xe produced in situ by the decay of {sup 244}Pu. Calculated fission Xe retention ages are 30-70 Ma after the formation of the solar system, consistent with the apparent presence of {sup 146}Sm decay products. Both the clast and the matrix of Bholghati have K-Ar ages of about 2 Ga, suggesting a common thermal event at least that recently.

  9. Carbon Fiber Technology Facility

    Broader source: Energy.gov (indexed) [DOE]

    The Carbon Fiber Technology Facility is relevant in proving the scale- up of low-cost carbon fiber precursor materials and advanced manufacturing technologies * Significant...

  10. Motivating carbon dioxide | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Motivating carbon dioxide Motivating carbon dioxide Released: April 17, 2013 Scientists show what it takes to get the potential fuel feedstock to a reactive spot on a model...

  11. Carbon Capture (Carbon Cycle 2.0)

    ScienceCinema (OSTI)

    Smit, Berend

    2011-06-08T23:59:59.000Z

    Berend Smit speaks at the Carbon Cycle 2.0 kick-off symposium Feb. 3, 2010. We emit more carbon into the atmosphere than natural processes are able to remove - an imbalance with negative consequences. Carbon Cycle 2.0 is a Berkeley Lab initiative to provide the science needed to restore this balance by integrating the Labs diverse research activities and delivering creative solutions toward a carbon-neutral energy future. http://carboncycle2.lbl.gov/

  12. Composite carbon foam electrode

    DOE Patents [OSTI]

    Mayer, S.T.; Pekala, R.W.; Kaschmitter, J.L.

    1997-05-06T23:59:59.000Z

    Carbon aerogels used as a binder for granulated materials, including other forms of carbon and metal additives, are cast onto carbon or metal fiber substrates to form composite carbon thin film sheets. The thin film sheets are utilized in electrochemical energy storage applications, such as electrochemical double layer capacitors (aerocapacitors), lithium based battery insertion electrodes, fuel cell electrodes, and electrocapacitive deionization electrodes. The composite carbon foam may be formed by prior known processes, but with the solid particles being added during the liquid phase of the process, i.e. prior to gelation. The other forms of carbon may include carbon microspheres, carbon powder, carbon aerogel powder or particles, graphite carbons. Metal and/or carbon fibers may be added for increased conductivity. The choice of materials and fibers will depend on the electrolyte used and the relative trade off of system resistivity and power to system energy. 1 fig.

  13. Composite carbon foam electrode

    DOE Patents [OSTI]

    Mayer, Steven T. (San Leandro, CA); Pekala, Richard W. (Pleasant Hill, CA); Kaschmitter, James L. (Pleasanton, CA)

    1997-01-01T23:59:59.000Z

    Carbon aerogels used as a binder for granularized materials, including other forms of carbon and metal additives, are cast onto carbon or metal fiber substrates to form composite carbon thin film sheets. The thin film sheets are utilized in electrochemical energy storage applications, such as electrochemical double layer capacitors (aerocapacitors), lithium based battery insertion electrodes, fuel cell electrodes, and electrocapacitive deionization electrodes. The composite carbon foam may be formed by prior known processes, but with the solid particles being added during the liquid phase of the process, i.e. prior to gelation. The other forms of carbon may include carbon microspheres, carbon powder, carbon aerogel powder or particles, graphite carbons. Metal and/or carbon fibers may be added for increased conductivity. The choice of materials and fibers will depend on the electrolyte used and the relative trade off of system resistivty and power to system energy.

  14. Quantifying emissions of greenhouse gases from South Asia through a targeted measurement campaign

    E-Print Network [OSTI]

    Ganesan, Anita Lakshmi

    2013-01-01T23:59:59.000Z

    Methane (CH 4 ), nitrous oxide (N20) and sulfur hexafluoride (SF6) are powerful greenhouse gases with global budgets that are well-known but regional distributions that are not adequately constrained for the purposes of ...

  15. Spatio-temporal theory of lasing action in optically-pumped rotationally excited molecular gases

    E-Print Network [OSTI]

    Chua, Song-Liang

    We investigate laser emission from optically-pumped rotationally excited molecular gases confined in a metallic cavity. To this end, we have developed a theoretical framework able to accurately describe, both in the spatial ...

  16. Field-driven dynamics of dilute gases, viscous liquids and polymer chains

    E-Print Network [OSTI]

    Mohan, Aruna, 1981-

    2007-01-01T23:59:59.000Z

    This thesis is concerned with the exploration of field-induced dynamical phenomena arising in dilute gases, viscous liquids and polymer chains. The problems considered herein pertain to the slip-induced motion of a rigid, ...

  17. Eddy covariance flux measurements of pollutant gases in urban Mexico City

    E-Print Network [OSTI]

    Velasco, Erik

    Eddy covariance (EC) flux measurements of the atmosphere/surface exchange of gases over an urban area are a direct way to improve and evaluate emissions inventories, and, in turn, to better understand urban atmospheric ...

  18. Fact #825: June 16, 2014 Tier 3 Non-Methane Organic Gases Plus...

    Broader source: Energy.gov (indexed) [DOE]

    organic gases (NMOG) and nitrogen oxides (NOx) that new light vehicles with gasoline engines are allowed to produce for model years 2017 to 2025. These standards apply to a...

  19. Evolution and stability of shock waves in dissipative gases characterized by activated inelastic collisions

    E-Print Network [OSTI]

    Sirmas, Nick

    2015-01-01T23:59:59.000Z

    Previous experiments have revealed that shock waves driven through dissipative gases may become unstable, for example, in granular gases, and in molecular gases undergoing strong relaxation effects. The mechanisms controlling these instabilities are not well understood. We successfully isolated and investigated this instability in the canonical problem of piston driven shock waves propagating into a medium characterized by inelastic collision processes. We treat the standard model of granular gases, where particle collisions are taken as inelastic with constant coefficient of restitution. The inelasticity is activated for sufficiently strong collisions. Molecular dynamic simulations were performed for 30,000 particles. We find that all shock waves investigated become unstable, with density non-uniformities forming in the relaxation region. The wavelength of these fingers is found comparable to the characteristic relaxation thickness. Shock Hugoniot curves for both elastic and inelastic collisions were obtaine...

  20. Biological sweetening of energy gases mimics in biotrickling filters Marc Fortuny a,c

    E-Print Network [OSTI]

    in energy-rich gases such as biogas from anaerobic digesters which may contain H2S concentrations exceeding: Hydrogen sulfide; Gas sweetening; Biotrickling filter; Desulfurization; Fuel gas; Biogas 1. Introduction

  1. Method and apparatus for separating mixtures of gases using an acoustic wave

    DOE Patents [OSTI]

    Geller, Drew A.; Swift, Gregory W.; Backhaus, Scott N.

    2004-05-11T23:59:59.000Z

    A thermoacoustic device separates a mixture of gases. An elongated duct is provided with first and second ends and has a length that is greater than the wavelength of sound in the mixture of gases at a selected frequency, and a diameter that is greater than a thermal penetration depth in the mixture of gases. A first acoustic source is located at the first end of the duct to generate acoustic power at the selected frequency. A plurality of side branch acoustic sources are spaced along the length of the duct and are configured to introduce acoustic power into the mixture of gases so that a first gas is concentrated at the first end of the duct and a second gas is concentrated at the second end of the duct.

  2. Quantum Cattaneo wave equation for ultra-short laser pulses interaction with electron and nucleon gases

    E-Print Network [OSTI]

    Marciak-Kozlowska, J

    2011-01-01T23:59:59.000Z

    In this paper the quantum Cattaneo wave equation for ultra-short laser pulses interaction with medium is obtained . The explicit formulae for electron and nucleon gases are presented

  3. Quantum coherence and magnetism in bosonic and fermionic gases of ultracold atoms

    E-Print Network [OSTI]

    Jo, Gyu-Boong

    2010-01-01T23:59:59.000Z

    In this thesis, two sets of experimental studies in bosonic and fermionic gases are described. In the first part of the thesis, itinerant ferromagnetism was studied in a strongly interacting Fermi gas of ultracold atoms. ...

  4. Quantum Cattaneo wave equation for ultra-short laser pulses interaction with electron and nucleon gases

    E-Print Network [OSTI]

    J Marciak-Kozlowska; Miroslaw Kozlowski

    2011-10-21T23:59:59.000Z

    In this paper the quantum Cattaneo wave equation for ultra-short laser pulses interaction with medium is obtained . The explicit formulae for electron and nucleon gases are presented

  5. Surface interactions involved in flashover with high density electronegative gases.

    SciTech Connect (OSTI)

    Hodge, Keith Conquest; Warne, Larry Kevin; Jorgenson, Roy Eberhardt; Wallace, Zachariah Red; Lehr, Jane Marie

    2010-01-01T23:59:59.000Z

    This report examines the interactions involved with flashover along a surface in high density electronegative gases. The focus is on fast ionization processes rather than the later time ionic drift or thermalization of the discharge. A kinetic simulation of the gas and surface is used to examine electron multiplication and includes gas collision, excitation and ionization, and attachment processes, gas photoionization and surface photoemission processes, as well as surface attachment. These rates are then used in a 1.5D fluid ionization wave (streamer) model to study streamer propagation with and without the surface in air and in SF6. The 1.5D model therefore includes rates for all these processes. To get a better estimate for the behavior of the radius we have studied radial expansion of the streamer in air and in SF6. The focus of the modeling is on voltage and field level changes (with and without a surface) rather than secondary effects, such as, velocities or changes in discharge path. An experiment has been set up to carry out measurements of threshold voltages, streamer velocities, and other discharge characteristics. This setup includes both electrical and photographic diagnostics (streak and framing cameras). We have observed little change in critical field levels (where avalanche multiplication sets in) in the gas alone versus with the surface. Comparisons between model calculations and experimental measurements are in agreement with this. We have examined streamer sustaining fields (field which maintains ionization wave propagation) in the gas and on the surface. Agreement of the gas levels with available literature is good and agreement between experiment and calculation is good also. Model calculations do not indicate much difference between the gas alone versus the surface levels. Experiments have identified differences in velocity between streamers on the surface and in the gas alone (the surface values being larger).

  6. Radiative precursors driven by converging blast waves in noble gases

    SciTech Connect (OSTI)

    Burdiak, G. C.; Lebedev, S. V.; Harvey-Thompson, A. J.; Swadling, G. F.; Suzuki-Vidal, F.; Hall, G. N.; Khoory, E.; Pickworth, L.; Bland, S. N.; Grouchy, P. de; Skidmore, J.; Suttle, L.; Bennett, M.; Niasse, N. P. L. [Blackett Laboratory, Imperial College London SW7 2BW (United Kingdom)] [Blackett Laboratory, Imperial College London SW7 2BW (United Kingdom); Williams, R. J. R. [Atomic Weapons Establishment, Aldermaston RG7 4PR (United Kingdom)] [Atomic Weapons Establishment, Aldermaston RG7 4PR (United Kingdom); Blesener, K.; Atoyan, L.; Cahill, A.; Hoyt, C.; Potter, W. [Laboratory of Plasma Studies, Cornell University, Ithaca, New York 14853 (United States)] [Laboratory of Plasma Studies, Cornell University, Ithaca, New York 14853 (United States); and others

    2014-03-15T23:59:59.000Z

    A detailed study of the radiative precursor that develops ahead of converging blast waves in gas-filled cylindrical liner z-pinch experiments is presented. The experiment is capable of magnetically driving 20?km s{sup ?1} blast waves through gases of densities of the order 10{sup ?5} g cm{sup ?3} (see Burdiak et al. [High Energy Density Phys. 9(1), 52–62 (2013)] for a thorough description). Data were collected for Ne, Ar, and Xe gas-fills. The geometry of the setup allows a determination of the plasma parameters both in the precursor and across the shock, along a nominally uniform line of sight that is perpendicular to the propagation of the shock waves. Radiation from the shock was able to excite NeI, ArII, and XeII/XeIII precursor spectral features. It is shown that the combination of interferometry and optical spectroscopy data is inconsistent with upstream plasmas being in LTE. Specifically, electron density gradients do not correspond to any apparent temperature change in the emission spectra. Experimental data are compared to 1D radiation hydrodynamics HELIOS-CR simulations and to PrismSPECT atomic physics calculations to assist in a physical interpretation of the observations. We show that upstream plasma is likely in the process of being radiatively heated and that the emission from a small percentage of ionised atoms within a cool background plasma dominates the emission spectra. Experiments were carried out on the MAGPIE and COBRA pulsed-power facilities at Imperial College London and Cornell University, respectively.

  7. Methods for separating oxygen from oxygen-containing gases

    DOE Patents [OSTI]

    Mackay, Richard (Lafayette, CO); Schwartz, Michael (Boulder, CO); Sammells, Anthony F. (Boulder, CO)

    2000-01-01T23:59:59.000Z

    This invention provides mixed conducting metal oxides particularly useful for the manufacture of catalytic membranes for gas-phase oxygen separation processes. The materials of this invention have the general formula: A.sub.x A'.sub.x A".sub.2-(x+x') B.sub.y B'.sub.y B".sub.2-(y+y') O.sub.5+z ; where x and x' are greater than 0; y and y' are greater than 0; x+x' is less than or equal to 2; y+y' is less than or equal to 2; z is a number that makes the metal oxide charge neutral; A is an element selected from the f block lanthanide elements; A' is an element selected from Be, Mg, Ca, Sr, Ba and Ra; A" is an element selected from the f block lanthanides or Be, Mg, Ca, Sr, Ba and Ra; B is an element selected from the group consisting of Al, Ga, In or mixtures thereof; and B' and B" are different elements and are independently selected from the group of elements Mg or the d-block transition elements. The invention also provides methods for oxygen separation and oxygen enrichment of oxygen deficient gases which employ mixed conducting metal oxides of the above formula. Examples of the materials used for the preparation of the membrane include A.sub.x Sr.sub.x' B.sub.y Fe.sub.y' Co.sub.2-(y+y') O.sub.5+z, where x is about 0.3 to about 0.5, x' is about 1.5 to about 1.7, y is 0.6, y' is between about 1.0 and 1.4 and B is Ga or Al.

  8. Research Summary Carbon Additionality

    E-Print Network [OSTI]

    of the quality assurance of emissions reduction and carbon sequestration activities, but remains a source of muchResearch Summary Carbon Additionality Additionality is widely considered to be a core aspect controversy in national carbon accounting, international regulatory frameworks and carbon markets. A review

  9. Acetylenic carbon allotrope

    DOE Patents [OSTI]

    Lagow, R.J.

    1998-02-10T23:59:59.000Z

    A fourth allotrope of carbon, an acetylenic carbon allotrope, is described. The acetylenic carbon allotropes of the present invention are more soluble than the other known carbon allotropes in many common organic solvents and possesses other desirable characteristics, e.g. high electron density, ability to burn cleanly, and electrical conductive properties. Many uses for this fourth allotrope are described herein. 17 figs.

  10. Carbon Monoxide Environmental Public

    E-Print Network [OSTI]

    The National Workgroup on Carbon Monoxide Surveillance Formed in April 2005 Membership: EPHT grantees Academic

  11. The Woodland Carbon Code

    E-Print Network [OSTI]

    The Woodland Carbon Code While society must continue to make every effort to reduce greenhouse gas a role by removing carbon dioxide from the atmosphere. The potential of woodlands to soak up carbon to help compensate for their carbon emissions. But before investing in such projects, people want to know

  12. Iron-based alloys with corrosion resistance to oxygen-sulfur mixed gases

    DOE Patents [OSTI]

    Natesan, K.

    1992-11-17T23:59:59.000Z

    An iron-based alloy with improved performance with exposure to oxygen-sulfur mixed gases with the alloy containing about 9--30 wt. % Cr and a small amount of Nb and/or Zr implanted on the surface of the alloy to diffuse a depth into the surface portion, with the alloy exhibiting corrosion resistance to the corrosive gases without bulk addition of Nb and/or Zr and without heat treatment at temperatures of 1000--1100 C. 7 figs.

  13. Iron-based alloys with corrosion resistance to oxygen-sulfur mixed gases

    DOE Patents [OSTI]

    Natesan, Krishnamurti (Naperville, IL)

    1992-01-01T23:59:59.000Z

    An iron-based alloy with improved performance with exposure to oxygen-sulfur mixed gases with the alloy containing about 9-30 wt. % Cr and a small amount of Nb and/or Zr implanted on the surface of the alloy to diffuse a depth into the surface portion, with the alloy exhibiting corrosion resistance to the corrosive gases without bulk addition of Nb and/or Zr and without heat treatment at temperatures of 1000.degree.-1100.degree. C.

  14. Mesoporous carbon materials

    SciTech Connect (OSTI)

    Dai, Sheng; Fulvio, Pasquale Fernando; Mayes, Richard T.; Wang, Xiqing; Sun, Xiao-Guang; Guo, Bingkun

    2014-09-09T23:59:59.000Z

    A conductive mesoporous carbon composite comprising conductive carbon nanoparticles contained within a mesoporous carbon matrix, wherein the conductive mesoporous carbon composite possesses at least a portion of mesopores having a pore size of at least 10 nm and up to 50 nm, and wherein the mesopores are either within the mesoporous carbon matrix, or are spacings delineated by surfaces of said conductive carbon nanoparticles when said conductive carbon nanoparticles are fused with each other, or both. Methods for producing the above-described composite, devices incorporating them (e.g., lithium batteries), and methods of using them, are also described.

  15. Molecular extended thermodynamics of rarefied polyatomic gases and wave velocities for increasing number of moments

    SciTech Connect (OSTI)

    Arima, Takashi, E-mail: tks@stat.nitech.ac.jp [Center for Social Contribution and Collaboration, Nagoya Institute of Technology (Japan); Mentrelli, Andrea, E-mail: andrea.mentrelli@unibo.it [Department of Mathematics and Research Center of Applied Mathematics (CIRAM), University of Bologna (Italy); Ruggeri, Tommaso, E-mail: tommaso.ruggeri@unibo.it [Department of Mathematics and Research Center of Applied Mathematics (CIRAM), University of Bologna (Italy)

    2014-06-15T23:59:59.000Z

    Molecular extended thermodynamics of rarefied polyatomic gases is characterized by two hierarchies of equations for moments of a suitable distribution function in which the internal degrees of freedom of a molecule is taken into account. On the basis of physical relevance the truncation orders of the two hierarchies are proven to be not independent on each other, and the closure procedures based on the maximum entropy principle (MEP) and on the entropy principle (EP) are proven to be equivalent. The characteristic velocities of the emerging hyperbolic system of differential equations are compared to those obtained for monatomic gases and the lower bound estimate for the maximum equilibrium characteristic velocity established for monatomic gases (characterized by only one hierarchy for moments with truncation order of moments N) by Boillat and Ruggeri (1997) (?{sub (N)}{sup E,max})/(c{sub 0}) ??(6/5 (N?1/2 )),(c{sub 0}=?(5/3 k/m T)) is proven to hold also for rarefied polyatomic gases independently from the degrees of freedom of a molecule. -- Highlights: •Molecular extended thermodynamics of rarefied polyatomic gases is studied. •The relation between two hierarchies of equations for moments is derived. •The equivalence of maximum entropy principle and entropy principle is proven. •The characteristic velocities are compared to those of monatomic gases. •The lower bound of the maximum characteristic velocity is estimated.

  16. Electrolytic production of neodymium without perfluorinated carbon compounds on the offgases

    DOE Patents [OSTI]

    Keller, R.; Larimer, K.T.

    1998-09-22T23:59:59.000Z

    A method is described for producing neodymium in an electrolytic cell without formation of perfluorinated carbon gases (PFCs), the method comprising the steps of providing an electrolyte in the electrolytic cell and providing an anode in an anode region of the electrolyte and providing a cathode in a cathode region of the electrolytic cell. Dissolving an oxygen-containing neodymium compound in the electrolyte in the anode region and maintaining a more intense electrolyte circulation in the anode region than in the cathode region. Passing an electrolytic current between said anode and said cathode and depositing neodymium metal at the cathode, preventing the formation of perfluorinated carbon gases by limiting anode over voltage. 4 figs.

  17. Carbon now real factor in denying permits to coal-based generation

    SciTech Connect (OSTI)

    NONE

    2009-01-15T23:59:59.000Z

    Concerns about global climate change and uncertainties about the potential cost of carbon regulation have increased the odds that applications to build coal-fired plants will be denied. In Kansas the coal industry was stunned by the denial of an air-quality permit for a project because of concerns about global warming. It was the first time any official anywhere had invoked greenhouse gases as the reason for denying an operating permit for a proposed fossil-fueled plant.

  18. The solubility of elemental sulfur in methane, carbon dioxide and hydrogen sulfide gas

    E-Print Network [OSTI]

    Wieland, Denton R.

    1958-01-01T23:59:59.000Z

    ABSTRACT The object of the work reported In this dissertation was to determine the solubility of sulfur in gaseous methane carbon dioxide, and hydrogen sulfide and in mixtures of these gases, at various pressures and temperatures* Sulfur solubility... of methane and propane (which has a critical pressure of approximately the same value of hydrogen sulfide) is 1500 psia. To have liquid in this system at 1500 psia, however, would require a maximum temperature of 20?F which is well below the minimum...

  19. Soil metagenomics and carbon cycling

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and carbon cycling Establishing a foundational understanding of the microbial and ecosystem factors that control carbon cycling to improve climate modeling and carbon...

  20. Carbon Nanostructure-Based Sensors

    E-Print Network [OSTI]

    Sarkar, Tapan

    2012-01-01T23:59:59.000Z

    Control of Single-Walled Carbon Nanotube Functionalization.M. S. Characterizing carbon nanotube samples with resonancewith a Single-Walled Carbon Nanotube Capacitor. Science

  1. Large Magnetization at Carbon Surfaces

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Large Magnetization at Carbon Surfaces Large Magnetization at Carbon Surfaces Print Wednesday, 31 August 2011 00:00 From organic matter to pencil lead, carbon is a versatile...

  2. The Australian terrestrial carbon budget

    E-Print Network [OSTI]

    2013-01-01T23:59:59.000Z

    Australian terrestrial carbon budget Open Access 3 , G. P.The Australian terrestrial carbon budget Luo, C. , Mahowald,terrestrial carbon budget Richards, G. P. , Borough, C. ,

  3. Waste Heat Recovery from High Temperature Off-Gases from Electric Arc Furnace

    SciTech Connect (OSTI)

    Nimbalkar, Sachin U [ORNL; Thekdi, Arvind [E3M Inc; Keiser, James R [ORNL; Storey, John Morse [ORNL

    2014-01-01T23:59:59.000Z

    This article presents a study and review of available waste heat in high temperature Electric Arc Furnace (EAF) off gases and heat recovery techniques/methods from these gases. It gives details of the quality and quantity of the sensible and chemical waste heat in typical EAF off gases, energy savings potential by recovering part of this heat, a comprehensive review of currently used waste heat recovery methods and potential for use of advanced designs to achieve a much higher level of heat recovery including scrap preheating, steam production and electric power generation. Based on our preliminary analysis, currently, for all electric arc furnaces used in the US steel industry, the energy savings potential is equivalent to approximately 31 trillion Btu per year or 32.7 peta Joules per year (approximately $182 million US dollars/year). This article describes the EAF off-gas enthalpy model developed at Oak Ridge National Laboratory (ORNL) to calculate available and recoverable heat energy for a given stream of exhaust gases coming out of one or multiple EAF furnaces. This Excel based model calculates sensible and chemical enthalpy of the EAF off-gases during tap to tap time accounting for variation in quantity and quality of off gases. The model can be used to estimate energy saved through scrap preheating and other possible uses such as steam generation and electric power generation using off gas waste heat. This article includes a review of the historical development of existing waste heat recovery methods, their operations, and advantages/limitations of these methods. This paper also describes a program to develop and test advanced concepts for scrap preheating, steam production and electricity generation through use of waste heat recovery from the chemical and sensible heat contained in the EAF off gases with addition of minimum amount of dilution or cooling air upstream of pollution control equipment such as bag houses.

  4. Carbon fuel cells with carbon corrosion suppression

    DOE Patents [OSTI]

    Cooper, John F. (Oakland, CA)

    2012-04-10T23:59:59.000Z

    An electrochemical cell apparatus that can operate as either a fuel cell or a battery includes a cathode compartment, an anode compartment operatively connected to the cathode compartment, and a carbon fuel cell section connected to the anode compartment and the cathode compartment. An effusion plate is operatively positioned adjacent the anode compartment or the cathode compartment. The effusion plate allows passage of carbon dioxide. Carbon dioxide exhaust channels are operatively positioned in the electrochemical cell to direct the carbon dioxide from the electrochemical cell.

  5. Conversion of Hydrogen Sulfide in Coal Gases to Liquid Elemental Sulfur with Monolithic Catalysts

    SciTech Connect (OSTI)

    K. C. Kwon

    2007-09-30T23:59:59.000Z

    Removal of hydrogen sulfide (H{sub 2}S) from coal gasifier gas and sulfur recovery are key steps in the development of Department of Energy's (DOE's) advanced power plants that produce electric power and clean transportation fuels with coal and natural gas. These plants will require highly clean coal gas with H{sub 2}S below 1 ppmv and negligible amounts of trace contaminants such as hydrogen chloride, ammonia, alkali, heavy metals, and particulate. The conventional method of sulfur removal and recovery employing amine, Claus, and tail-gas treatment is very expensive. A second generation approach developed under DOE's sponsorship employs hot-gas desulfurization (HGD) using regenerable metal oxide sorbents followed by Direct Sulfur Recovery Process (DSRP). However, this process sequence does not remove trace contaminants and is targeted primarily towards the development of advanced integrated gasification combined cycle (IGCC) plants that produce electricity (not both electricity and transportation fuels). There is an immediate as well as long-term need for the development of cleanup processes that produce highly clean coal gas for next generation power plants. To this end, a novel process is now under development at several research organizations in which the H{sub 2}S in coal gas is directly oxidized to elemental sulfur over a selective catalyst. Such a process is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S In the Single-Step Sulfur Recovery Process (SSRP), the direct oxidation of H{sub 2}S to elemental sulfur in the presence of SO{sub 2} is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. This direct oxidation process has the potential to produce a super clean coal gas more economically than both conventional amine-based processes and HGD/DSRP. The H{sub 2} and CO components of syngas appear to behave as inert with respect to sulfur formed at the SSRP conditions. One problem in the SSRP process that needs to be eliminated or minimized is COS formation that may occur due to reaction of CO with sulfur formed from the Claus reaction. The objectives of this research are to formulate monolithic catalysts for removal of H{sub 2}S from coal gases and minimum formation of COS with monolithic catalyst supports, {gamma}-alumina wash or carbon coats, and catalytic metals, to develop a catalytic regeneration method for a deactivated monolithic catalyst, to measure kinetics of both direct oxidation of H{sub 2}S to elemental sulfur with SO{sub 2} as an oxidizer and formation of COS in the presence of a simulated coal gas mixture containing H{sub 2}, CO, CO{sub 2}, and moisture, using a monolithic catalyst reactor, and to develop kinetic rate equations and model the direct oxidation process to assist in the design of large-scale plants. This heterogeneous catalytic reaction has gaseous reactants such as H{sub 2}S and SO{sub 2}. However, this heterogeneous catalytic reaction has heterogeneous products such as liquid elemental sulfur and steam. Experiments on conversion of hydrogen sulfide into elemental sulfur and formation of COS were carried out for the space time range of 130-156 seconds at 120-140 C to formulate catalysts suitable for the removal of H{sub 2}S and COS from coal gases, evaluate removal capabilities of hydrogen sulfide and COS from coal gases with formulated catalysts, and develop an economic regeneration method of deactivated catalysts. Simulated coal gas mixtures consist of 3,300-3,800-ppmv hydrogen sulfide, 1,600-1,900 ppmv sulfur dioxide, 18-21 v% hydrogen, 29-34 v% CO, 8-10 v% CO{sub 2}, 5-18 vol % moisture, and nitrogen as remainder. Volumetric feed rates of a simulated coal gas mixture to the reactor are 114-132 SCCM. The temperature of the reactor is controlled in an oven at 120-140 C. The pressure of the reactor is maintained at 116-129 psia. The molar ratio of H{sub 2}S to SO{sub 2} in the monolithic catalyst reactor is

  6. Pretreatment process for forming a smooth surface diamond film on a carbon-coated substrate

    DOE Patents [OSTI]

    Feng, Z.; Brewer, M.; Brown, I.; Komvopoulos, K.

    1994-05-03T23:59:59.000Z

    A process is disclosed for the pretreatment of a carbon-coated substrate to provide a uniform high density of nucleation sites thereon for the subsequent deposition of a continuous diamond film without the application of a bias voltage to the substrate. The process comprises exposing the carbon-coated substrate, in a microwave plasma enhanced chemical vapor deposition system, to a mixture of hydrogen-methane gases, having a methane gas concentration of at least about 4% (as measured by partial pressure), while maintaining the substrate at a pressure of about 10 to about 30 Torr during the pretreatment. 6 figures.

  7. Lanthanum-hexaboride carbon composition for use in corrosive hydrogen-fluorine environments

    DOE Patents [OSTI]

    Holcombe, C.E. Jr.; Kovach, L.; Taylor, A.J.

    1980-01-22T23:59:59.000Z

    The present invention relates to a structural composition useful in corrosive hydrogen-fluorine environments at temperatures in excess of 1400/sup 0/K. The composition is formed of a isostatically pressed and sintered or a hot-pressed mixture of lanthanum hexaboride particles and about 10 to 30 vol% carbon. The lanthanum-hexaboride reacts with the high-temperature fluorine-containing gases to form an adherent layer of corrosion-inhibiting lanthanum trifluoride on exposed surfaces of the composition. The carbon in the composite significantly strengthens the composite, enhances thermal shock resistance, and significantly facilitates the machining of the composition.

  8. Pumping carbon out of underground coal deposits

    SciTech Connect (OSTI)

    Steinberg, M.

    1999-07-01T23:59:59.000Z

    Thin steam and deep coal deposits are difficult and costly to mine. Underground coal gasification (UCG) with air or oxygen was thought to alleviate this problem. Experimental field tests were conducted in Wyoming and Illinois. Problems were encountered concerning a clear path for the team gasification to take place and removal of gas. The high endothermic heat of reaction requiring large quantities of steam and oxygen makes the process expensive. Safety problems due to incomplete reaction is also of concern. A new approach is proposed which can remedy most of these drawbacks for extracting energy from underground coal deposits. It is proposed to hydrogasify the coal underground with a heated hydrogen gas stream under pressure to produce a methane-rich gas effluent stream. The hydrogasification of coal is essentially exothermic so that no steam or oxygen is required. The gases formed are always in a reducing atmosphere making the process safe. The hydrogen is obtained by thermally decomposing the effluent methane above ground to elemental carbon and hydrogen. The hydrogen is returned underground for further hydrogasification of the coal seam. The small amount of oxygen and sulfur in the coal can be processed out above ground by removal as water and H{sub 2}S. Any CO can be removed by a methanation step returning the methane to process. The ash remains in the ground and the elemental carbon produced is the purest form of coal. The particulate carbon can be slurried with water to produce a fuel stream that can be fed to a turbine for efficient combined cycle power plants with lower CO{sub 2} emissions. Coal cannot be used for combined cycle because of its ash and sulfur content destroys the gas turbine. Depending on its composition of coal seam some excess hydrogen is also produced. Hydrogen is, thus, used to pump pure carbon out of the ground.

  9. Carbon Monoxide Safety Tips

    E-Print Network [OSTI]

    Shaw, Bryan W.; Garcia, Monica L.

    1999-07-26T23:59:59.000Z

    Protect yourself and your family from the deadly effects of carbon monoxide--a colorless, odorless poisonous gas. This publication describes the warning signs of carbon monoxide exposure and includes a home safety checklist....

  10. Combustion process for synthesis of carbon nanomaterials from liquid hydrocarbon

    DOE Patents [OSTI]

    Diener, Michael D.; Alford, J. Michael; Nabity, James; Hitch, Bradley D.

    2007-01-02T23:59:59.000Z

    The present invention provides a combustion apparatus for the production of carbon nanomaterials including fullerenes and fullerenic soot. Most generally the combustion apparatus comprises one or more inlets for introducing an oxygen-containing gas and a hydrocarbon fuel gas in the combustion system such that a flame can be established from the mixed gases, a droplet delivery apparatus for introducing droplets of a liquid hydrocarbon feedstock into the flame, and a collector apparatus for collecting condensable products containing carbon nanomaterials that are generated in the combustion system. The combustion system optionally has a reaction zone downstream of the flame. If this reaction zone is present the hydrocarbon feedstock can be introduced into the flame, the reaction zone or both.

  11. SCALE-UP OF CARBON /CARBON BIPOLAR PLATES

    E-Print Network [OSTI]

    Scale-up of Carbon/Carbon Bipolar Plates · Project Objectives ­ Build and demonstrate a pilot facility#12;SCALE-UP OF CARBON /CARBON BIPOLAR PLATES Quarterly Report to the Department of Energy, May 19 #12;DOE PROGRAM OBJECTIVES Scale-up of Carbon/Carbon Bipolar Plates · Phase I ­ Technology Development

  12. ESM 271 Carbon Footprints and Carbon Accounting Instructor: Sangwon Suh

    E-Print Network [OSTI]

    California at Santa Barbara, University of

    1 ESM 271 Carbon Footprints and Carbon Accounting Instructor: Sangwon Suh Bren hall 3422, suh: Homework (1 for each week @10%): 40% Personal carbon account (report): 30% Final exam: 30% Course schedule Week 1: Introduction to carbon footprint and carbon account - Background: carbon awareness, major

  13. Big Sky Carbon Atlas

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    (Acknowledgment to the Big Sky Carbon Sequestration Partnership (BSCSP); see home page at http://www.bigskyco2.org/)

  14. Growing consumption of petroleum products worldwide has resulted in the proliferation of vessels carrying oil, chemicals, and gases

    E-Print Network [OSTI]

    Neimark, Alexander V.

    Growing consumption of petroleum products worldwide has resulted in the proliferation of vessels carrying oil, chemicals, and gases into our harbors. Meeting our society's surging demand for commodities

  15. Intro to Carbon Sequestration

    ScienceCinema (OSTI)

    None

    2010-01-08T23:59:59.000Z

    NETL's Carbon Sequestration Program is helping to develop technologies to capture, purify, and store carbon dioxide (CO2) in order to reduce greenhouse gas emissions without adversely influencing energy use or hindering economic growth. Carbon sequestration technologies capture and store CO2 that would otherwise reside in the atmosphere for long periods of time.

  16. Intro to Carbon Sequestration

    SciTech Connect (OSTI)

    2008-03-06T23:59:59.000Z

    NETL's Carbon Sequestration Program is helping to develop technologies to capture, purify, and store carbon dioxide (CO2) in order to reduce greenhouse gas emissions without adversely influencing energy use or hindering economic growth. Carbon sequestration technologies capture and store CO2 that would otherwise reside in the atmosphere for long periods of time.

  17. Carbon Footprint Towson University

    E-Print Network [OSTI]

    Fath, Brian D.

    Carbon Footprint Towson University GHG Inventory for Educational Institutes Getting Starting.TM The Carbon Footprint 8 The Constellation Experience A Broad Inventory 1. Scope I-Direct Emissions works.TM The Carbon Footprint 10 The Constellation Experience A Broad Inventory 3. Scope III

  18. Dynamics of a geothermal field traced by noble gases: Cerro Prieto, Mexico

    SciTech Connect (OSTI)

    Mazor, E. (Weizmann Inst. of Science, Rehovot, Israel); Truesdell, A.H.

    1981-01-01T23:59:59.000Z

    Noble gases have been measured mass spectrometrically in samples collected during 1977 from producing wells at Cerro Prieto. Positive correlations between concentrations of radiogenic (He, /sup 40/Ar) and atmospheric noble gases (Ne, Ar, and Kr) suggest the following dynamic model: the geothermal fluids originated from meteoric water penetrated to more than 2500 m depth (below the level of first boiling) and mixed with radiogenic helium and argon-40 formed in the aquifer rocks. Subsequently, small amounts of steam were lost by a Raleigh process (0 to 3%) and mixing with shallow cold water occurred (0 to 30%). Noble gases are sensitive tracers of boiling in the initial stages of 0 to 3% steam separation and complement other tracers, such as Cl or temperature, which are effective only beyond this range.

  19. The Spectral Backbone of Excitation Transport in Ultra-Cold Rydberg Gases

    E-Print Network [OSTI]

    Scholak, Torsten; Buchleitner, Andreas

    2014-01-01T23:59:59.000Z

    The spectral structure underlying excitonic energy transfer in ultra-cold Rydberg gases is studied numerically, in the framework of random matrix theory, and via self-consistent diagrammatic techniques. Rydberg gases are made up of randomly distributed, highly polarizable atoms that interact via strong dipolar forces. Dynamics in such a system is fundamentally different from cases in which the interactions are of short range, and is ultimately determined by the spectral and eigenvector structure. In the energy levels' spacing statistics, we find evidence for a critical energy that separates delocalized eigenstates from states that are localized at pairs or clusters of atoms separated by less than the typical nearest-neighbor distance. We argue that the dipole blockade effect in Rydberg gases can be leveraged to manipulate this transition across a wide range: As the blockade radius increases, the relative weight of localized states is reduced. At the same time, the spectral statistics -- in particular, the den...

  20. Carbon emissions and sequestration in forests: Case studies from seven developing countries

    SciTech Connect (OSTI)

    Makundi, W.; Sathaye, J. (eds.) (Lawrence Berkeley Lab., CA (United States)); Fearnside, P.M. (Instituto Nacional de Pesquisas da Amazonia (INPA), Manaus, AM (Brazil). Departmento de Ecologia)

    1992-08-01T23:59:59.000Z

    Deforestation in Brazilian Amazonia in 1990 was releasing approximately 281--282 X 10{sup 6} metric tons (MT) of carbon on conversion to a landscape of agriculture, productive pasture, degraded pasture, secondary forest and regenerated forest in the proportions corresponding to the equilibrium condition implied by current land-use patterns. Emissions are expressed as committed carbon,'' or the carbon released over a period of years as the carbon stock in each hectare deforested approaches a new equilibrium in the landscape that replaces the original forest. To the extent that deforestation rates have remained constant, current releases from the areas deforested in previous years will be equal to the future releases from the areas being cleared now. Considering the quantities of carbon dioxide, carbon monoxide, methane, nitrous oxide, NO{sub x} and non-methane hydrocarbons released raises the impact by 22--37%. The relative impact on the greenhouse effect of each gas is based on the Intergovernmental Panel on Climate Change (IPCC) calculations over a 20-year time period (including indirect effects). The six gases considered have a combined global warming impact equivalent to 343 to 386 million MT of C0{sub 2}-equivalent carbon, depending on assumptions regarding the release of methane and other gases from the various sources such as burning and termites. These emissions represent 7--8 times the 50 million MT annual carbon release from Brazil's use of fossil fuels, but bring little benefit to the country. Stopping deforestation in Brazil would prevent as much greenhouse emission as tripling the fuel efficiency of all the automobiles in the world. The relatively cheap measures needed to contain deforestation, together with the many complementary benefits of doing so, make this the first priority for funds intended to slow global warming.

  1. Manufacture of finely divided carbon

    SciTech Connect (OSTI)

    Walker, D.G.

    1980-01-22T23:59:59.000Z

    Finely divided carbon is manufactured by a process producing a gaseous stream containing carbon monoxide by reacting coal and air in a slagging ash gasifier, separating carbon monoxide from the gaseous mixture, and disproportionating the carbon monoxide to produce finely divided carbon and carbon dioxide, the latter of which is recycled to the gasifier.

  2. SmallholderSmallholder CarbonCarbon AgroforestryAgroforestry && Carbon for Poverty ReductionCarbon for Poverty Reduction

    E-Print Network [OSTI]

    SmallholderSmallholder CarbonCarbon AgroforestryAgroforestry && Carbon for Poverty ReductionCarbon for Poverty Reduction Roundtable (CAPR)Roundtable (CAPR) GEO Forest Monitoring SymposiumGEO Forest Monitoring)Amazon Initiative Consortium (IA) #12;Carbon for Poverty Reduction Roundtable (CAPR)Carbon for Poverty Reduction

  3. Burners and combustion apparatus for carbon nanomaterial production

    DOE Patents [OSTI]

    Alford, J. Michael (Lakewood, CO); Diener, Michael D. (Denver, CO); Nabity, James (Arvada, CO); Karpuk, Michael (Boulder, CO)

    2007-10-09T23:59:59.000Z

    The invention provides improved burners, combustion apparatus, and methods for carbon nanomaterial production. The burners of the invention provide sooting flames of fuel and oxidizing gases. The condensable products of combustion produced by the burners of this invention produce carbon nanomaterials including without limitation, soot, fullerenic soot, and fullerenes. The burners of the invention do not require premixing of the fuel and oxidizing gases and are suitable for use with low vapor pressure fuels such as those containing substantial amounts of polyaromatic hydrocarbons. The burners of the invention can operate with a hot (e.g., uncooled) burner surface and require little, if any, cooling or other forms of heat sinking. The burners of the invention comprise one or more refractory elements forming the outlet of the burner at which a flame can be established. The burners of the invention provide for improved flame stability, can be employed with a wider range of fuel/oxidizer (e.g., air) ratios and a wider range of gas velocities, and are generally more efficient than burners using water-cooled metal burner plates. The burners of the invention can also be operated to reduce the formation of undesirable soot deposits on the burner and on surfaces downstream of the burner.

  4. Burners and combustion apparatus for carbon nanomaterial production

    DOE Patents [OSTI]

    Alford, J. Michael; Diener, Michael D; Nabity, James; Karpuk, Michael

    2013-02-05T23:59:59.000Z

    The invention provides improved burners, combustion apparatus, and methods for carbon nanomaterial production. The burners of the invention provide sooting flames of fuel and oxidizing gases. The condensable products of combustion produced by the burners of this invention produce carbon nanomaterials including without limitation, soot, fullerenic soot, and fullerenes. The burners of the invention do not require premixing of the fuel and oxidizing gases and are suitable for use with low vapor pressure fuels such as those containing substantial amounts of polyaromatic hydrocarbons. The burners of the invention can operate with a hot (e.g., uncooled) burner surface and require little, if any, cooling or other forms of heat sinking. The burners of the invention comprise one or more refractory elements forming the outlet of the burner at which a flame can be established. The burners of the invention provide for improved flame stability, can be employed with a wider range of fuel/oxidizer (e.g., air) ratios and a wider range of gas velocities, and are generally more efficient than burners using water-cooled metal burner plates. The burners of the invention can also be operated to reduce the formation of undesirable soot deposits on the burner and on surfaces downstream of the burner.

  5. Identification and Selection of Major Carbon Dioxide Stream Compositions

    SciTech Connect (OSTI)

    Last, George V.; Schmick, Mary T.

    2011-06-30T23:59:59.000Z

    A critical component in the assessment of long-term risk from geologic sequestration of CO2 is the ability to predict mineralogical and geochemical changes within storage reservoirs due to rock-brine-CO2 reactions. Impurities and/or other constituents selected for co-sequestration can affect both the chemical and physical (e.g. density, viscosity, interfacial tension) behavior of CO2 in the deep subsurface. These impurities and concentrations are a function of both the industrial source(s) of the CO2, as well as the carbon capture technology used to extract the CO2 and produce a concentrated stream for geologic sequestration. This report summarizes the relative concentrations of CO2 and other constituents in exhaust gases from major non-energy related industrial sources of CO2. Assuming that carbon-capture technology would remove most of the incondensable gases N2, O2, and Ar, leaving SO2 and NOx as the main impurities, we selected four test fluid compositions for use in geochemical experiments. These included: 1) a pure CO2 stream representative of food grade CO2 used in most enhanced oil recovery projects: 2) a test fluid composition containing low concentrations (0.5 mole %) SO2 and NOx (representative of that generated from cement production), 3) a test fluid composition with higher concentrations (2.5 mole %) of SO2, and 4) and test fluid composition containing 3 mole % H2S.

  6. High-temperature sorbent method for removal of sulfur containing gases from gaseous mixtures

    DOE Patents [OSTI]

    Young, John E. (Woodridge, IL); Jalan, Vinod M. (Concord, MA)

    1984-01-01T23:59:59.000Z

    A copper oxide-zinc oxide mixture is used as a sorbent for removing hydrogen sulfide and other sulfur containing gases at high temperatures from a gaseous fuel mixture. This high-temperature sorbent is especially useful for preparing fuel gases for high temperature fuel cells. The copper oxide is initially reduced in a preconditioning step to elemental copper and is present in a highly dispersed state throughout the zinc oxide which serves as a support as well as adding to the sulfur sorption capacity. The spent sorbent is regenerated by high-temperature treatment with an air fuel, air steam mixture followed by hydrogen reduction to remove and recover the sulfur.

  7. High-temperature sorbent method for removal of sulfur containing gases from gaseous mixtures

    DOE Patents [OSTI]

    Young, J.E.; Jalan, V.M.

    1984-06-19T23:59:59.000Z

    A copper oxide-zinc oxide mixture is used as a sorbent for removing hydrogen sulfide and other sulfur containing gases at high temperatures from a gaseous fuel mixture. This high-temperature sorbent is especially useful for preparing fuel gases for high temperature fuel cells. The copper oxide is initially reduced in a preconditioning step to elemental copper and is present in a highly dispersed state throughout the zinc oxide which serves as a support as well as adding to the sulfur sorption capacity. The spent sorbent is regenerated by high-temperature treatment with an air fuel, air steam mixture followed by hydrogen reduction to remove and recover the sulfur.

  8. High-temperature sorbent method for removal of sulfur-containing gases from gaseous mixtures

    DOE Patents [OSTI]

    Young, J.E.; Jalan, V.M.

    1982-07-07T23:59:59.000Z

    A copper oxide-zinc oxide mixture is used as a sorbent for removing hydrogen sulfide and other sulfur containing gases at high temperatures from a gaseous fuel mixture. This high-temperature sorbent is especially useful for preparing fuel gases for high temperature fuel cells. The copper oxide is initially reduced in a preconditioning step to elemental copper and is present in a highly dispersed state throughout the zinc oxide which serves as a support as well as adding to the sulfur sorbtion capacity. The spent sorbent is regenerated by high-temperature treatment with an air fuel, air steam mixture followed by hydrogen reduction to remove and recover the sulfur.

  9. Combined Power Generation and Carbon Sequestration Using Direct FuelCell

    SciTech Connect (OSTI)

    Hossein Ghezel-Ayagh

    2006-03-01T23:59:59.000Z

    The unique chemistry of carbonate fuel cell offers an innovative approach for separation of carbon dioxide from greenhouse gases (GHG). The carbonate fuel cell system also produces electric power at high efficiency. The simultaneous generation of power and sequestration of greenhouse gases offer an attractive scenario for re-powering the existing coal-fueled power plants, in which the carbonate fuel cell would separate the carbon dioxide from the flue gas and would generate additional pollutant-free electric power. Development of this system is concurrent with emergence of Direct FuelCell{reg_sign} (DFC{reg_sign}) technology for generation of electric power from fossil fuels. DFC is based on carbonate fuel cell featuring internal reforming. This technology has been deployed in MW-scale power plants and is readily available as a manufactured product. This final report describes the results of the conceptualization study conducted to assess the DFC-based system concept for separation of CO2 from GHG. Design and development studies were focused on integration of the DFC systems with coal-based power plants, which emit large amounts of GHG. In parallel to the system design and simulation activities, operation of laboratory scale DFC verified the technical concept and provided input to the design activity. The system was studied to determine its effectiveness in capturing more than ninety percent of CO2 from the flue gases. Cost analysis was performed to estimate the change in cost of electricity for a 200 MW pulverized coal boiler steam cycle plant retrofitted with the DFC-based CO2 separation system producing an additional 127 MW of electric power. The cost increments as percentage of levelized cost of electricity were estimated for a range of separation plant installations per year and a range of natural gas cost. The parametric envelope meeting the goal (<20% increase in COE) was identified. Results of this feasibility study indicated that DFC-based separation systems have the potential for capturing at least 90% of the emissions from the greenhouse gases generated by power plants and other industrial exhaust streams, and yet entail in less than 20% increase in the cost of energy services for long-term deployment (beyond 2012). The anticipated cost of energy increase is in line with DOE's goal for post-combustion systems as outlined in the ''Carbon Capture and Sequestration Systems Analysis Guidelines'', published by NETL, April 2005. During the course of this study certain enabling technologies were identified and the needs for further research and development were discussed.

  10. USE OF MOLECULAR MODELING TO DETERMINE THE INTERACTION AND COMPETITION OF GASES WITHIN COAL FOR CARBON DIOXIDE SEQUESTRATION

    SciTech Connect (OSTI)

    Jeffrey D. Evanseck; Jeffry D. Madura; Jonathan P. Mathews

    2005-05-27T23:59:59.000Z

    We have made progress in carrying out large scale molecular dynamics simulations using the CHARMM force field in order to refine our coal/guest interactions. There have been two issues facing us over the last year. First, we have had to create a completely new topology and parameter definition for coal. Since we are using a classical force field, we have adopted the strategy of treating coal composed of individual common fragments based upon a distribution of mass, composition, and bonding. Our procedure is similar to treating a protein as being composed of the discrete set of amino acids. Second, we have had to incorporate the quality CO{sub 2} parameters that we have developed over the last two years. There are the geometric and arithmetic procedures, which we have successfully implemented. We have utilized computational molecular modeling to generate a state-of-the-art large scale structural representation of a bituminous coal of low volatile bituminous rank. This structure(s) has been used to investigate the molecular forces between the bituminous coal structure (or idealized pores) and the molecular species CH{sub 4} and CO{sub 2}. We are close to carrying out molecular dynamics simulations, which will allow us to explore and test the newly created model of coal.

  11. Formation of Carbon Dwarfs

    E-Print Network [OSTI]

    Charles L. Steinhardt; Dimitar D. Sasselov

    2012-01-27T23:59:59.000Z

    We consider the formation of dwarf carbon stars via accretion from a carbon AGB companion in light of the new 107 object sample of Downes et al. (2004). This sample is now large enough to allow good mass determination via comparison of a composite spectrum to theoretical atmospheric models. Carbon dwarfs of spectral type M are indeed main sequence M dwarfs with enhanced metallicity and carbon abundance. We also calculate the predicted abundance of both M and of F/G carbon dwarfs, and show that the latter should be falsifiable in the near future.

  12. Study of fire retardant behavior of carbon nanotube membranes and carbon nanofiber paper in carbon fiber

    E-Print Network [OSTI]

    Das, Suman

    Study of fire retardant behavior of carbon nanotube membranes and carbon nanofiber paper in carbon Accepted 14 January 2010 Available online 20 January 2010 A B S T R A C T Single-walled carbon nanotube (SWCNT) and multi-walled carbon nanotube (MWCNT) membranes (buckypaper) and carbon nanofiber (CNF) paper

  13. Feasibility of reconstructing paleoatmospheric records of selected alkanes, methyl halides, and sulfur gases from Greenland ice cores

    E-Print Network [OSTI]

    Saltzman, Eric

    , and sulfur gases from Greenland ice cores M. Aydin,1 M. B. Williams,1 and E. S. Saltzman1 Received 7-lived atmospheric trace gases were measured in 25 ice core samples from Summit, Greenland. Samples were selected. The CH3Br results are consistent with previous observations of ``excess'' CH3Br in Greenland firn air

  14. A conceptual design of a Reactive Ion Etch back end system for the direct reuse of process gases

    E-Print Network [OSTI]

    Tiner, Paul Alan

    1994-01-01T23:59:59.000Z

    of these gases have proven to be detrimental to the environment. Because of the low percentage of utilization of the gas in a plasma process, these effects are a major concern. Few methods exist in industry today to dispose of unused gases, and all of the known...

  15. Hydroelectric Reservoirs -the Carbon Dioxide and Methane

    E-Print Network [OSTI]

    Fischlin, Andreas

    and contribute to global warming. The problem of greenhouse gases and their impact on global warming have become gas source. #12;1 1. Introduction The electricity produced by hydroelectric reservoirs is commonly greenhouse gases. One good point to know by dealing with these two greenhouse gases is that the global

  16. Carbon dioxide sensor

    DOE Patents [OSTI]

    Dutta, Prabir K. (Worthington, OH); Lee, Inhee (Columbus, OH); Akbar, Sheikh A. (Hilliard, OH)

    2011-11-15T23:59:59.000Z

    The present invention generally relates to carbon dioxide (CO.sub.2) sensors. In one embodiment, the present invention relates to a carbon dioxide (CO.sub.2) sensor that incorporates lithium phosphate (Li.sub.3PO.sub.4) as an electrolyte and sensing electrode comprising a combination of lithium carbonate (Li.sub.2CO.sub.3) and barium carbonate (BaCO.sub.3). In another embodiment, the present invention relates to a carbon dioxide (CO.sub.2) sensor has a reduced sensitivity to humidity due to a sensing electrode with a layered structure of lithium carbonate and barium carbonate. In still another embodiment, the present invention relates to a method of producing carbon dioxide (CO.sub.2) sensors having lithium phosphate (Li.sub.3PO.sub.4) as an electrolyte and sensing electrode comprising a combination of lithium carbonate (Li.sub.2CO.sub.3) and barium carbonate (BaCO.sub.3).

  17. Constraining bubble dynamics and mixing with dissolved gases: Implications for productivity measurements by oxygen mass balance

    E-Print Network [OSTI]

    Hamme, Roberta C; Emerson, Steven R

    2006-01-01T23:59:59.000Z

    ux estimates and bubble dynamics. Organic carbon export fromcarbon export estimates for the whole euphotic zone. Both bubblebubble ?uxes would have had a much larger effect. Previous observations of organic carbon

  18. Kinetic theory for dilute cohesive granular gases with a square well potential

    E-Print Network [OSTI]

    Satoshi Takada; Kuniyasu Saitoh; Hisao Hayakawa

    2015-06-15T23:59:59.000Z

    We develop the kinetic theory of dilute cohesive granular gases in which the attractive part is described by a square well potential. We derive the hydrodynamic equations from the kinetic theory with the microscopic expressions for the dissipation rate and the transport coefficients. We check the validity of our theory by performing the direct simulation Monte Carlo.

  19. ESTABoues, a decision tool to assess greenhouse gases of sewage sludge treatment and di

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    ORBIT2012 G ESTABoues, a decision tool to assess greenhouse gases of sewage sludge treatment and di-laure.reverdy@irstea.fr EXECUTIVE SUMMARY Sewage sludge production increases continuously reaching almost 20% (946 700 t 1 118 795% was incinerated (with or without household wastes) or landfilled. Nowadays, sludge reduction is a major concern

  20. Operational aspects of the desulfurization process of energy gases mimics in biotrickling filters5

    E-Print Network [OSTI]

    . Introduction Energy rich off-gases such as biogas are sometimes not used for electric power generation due impurities. H2S concentrations in biogas can range from 0.1 to 5 We dedicate this article to the memory/v (1000e20,000 ppmv), whereas the specifications for the maximum content of H2S in typical biogas

  1. Heat and Mass Transfer Modeling of Dry Gases in the Cathode of PEM Fuel Cells

    E-Print Network [OSTI]

    Stockie, John

    Heat and Mass Transfer Modeling of Dry Gases in the Cathode of PEM Fuel Cells M.J. Kermani1 J and N2, through the cathode of a proton exchange membrane (PEM) fuel cell is studied numerically) an energy equation, written in a form that has enthalpy as the dependent variable. Keywords: PEM fuel cells

  2. Diffusion of gases in air and its affect on oxygen deficiency hazard abatement

    SciTech Connect (OSTI)

    Theilacker, J.C.; White, M.J.; /Fermilab

    2005-09-01T23:59:59.000Z

    Density differences between air and released gases of cryogenic systems have been used to either require special oxygen deficiency hazard (ODH) control measures, or as a means of abatement. For example, it is not uncommon to assume that helium spills will quickly collect at the ceiling of a building or enclosure and will efficiently exit at the nearest vertical penetration or vent. Oxygen concentration reduction was found to be detectable during a localized helium spill throughout the entire 6.3 km Tevatron tunnel. This prompted us to perform diffusion tests in air with common gases used at Fermilab. The tests showed that gases, more readily than expected, diffused through an air column in the direction opposing buoyancy. Test results for helium and sulfur hexafluoride are presented. A system of tests were performed to better understand how easily released gases would fully mix with air and whether they remained fully mixed. The test results have been applied to a new system at Fermilab for ODH abatement.

  3. Ozone-depleting substances and the greenhouse gases HFCs, PFCs and

    E-Print Network [OSTI]

    Ozone-depleting substances and the greenhouse gases HFCs, PFCs and SF6 Danish consumption contribution to the debate on environmental policy in Denmark. #12;3 Contents 1 SUMMARY 5 1.1 OZONE OZONE-DEPLETING SUBSTANCES 18 3.1 IMPORTS AND EXPORTS 18 3.1.1 CFCs 18 3.1.2 Tetrachloromethane 19 3

  4. Anode supported single chamber solid oxide fuel cells operating in exhaust gases of thermal engine

    E-Print Network [OSTI]

    Boyer, Edmond

    Anode supported single chamber solid oxide fuel cells operating in exhaust gases of thermal engine. Conventional solid oxide fuel cells are separated into two compartments containing each electrode split hydrocarbons, pollutant emissions reduction hal-01056363,version1-21Aug2014 #12;1. Introduction Solid oxide

  5. A Biomass-based Model to Estimate the Plausibility of Exoplanet Biosignature Gases

    E-Print Network [OSTI]

    Seager, S; Hu, R

    2013-01-01T23:59:59.000Z

    Biosignature gas detection is one of the ultimate future goals for exoplanet atmosphere studies. We have created a framework for linking biosignature gas detectability to biomass estimates, including atmospheric photochemistry and biological thermodynamics. The new framework is intended to liberate predictive atmosphere models from requiring fixed, Earth-like biosignature gas source fluxes. New biosignature gases can be considered with a check that the biomass estimate is physically plausible. We have validated the models on terrestrial production of NO, H2S, CH4, CH3Cl, and DMS. We have applied the models to propose NH3 as a biosignature gas on a "cold Haber World," a planet with a N2-H2 atmosphere, and to demonstrate why gases such as CH3Cl must have too large of a biomass to be a plausible biosignature gas on planets with Earth or early-Earth-like atmospheres orbiting a Sun-like star. To construct the biomass models, we developed a functional classification of biosignature gases, and found that gases (such...

  6. Greenhouse gases accounting and reporting for waste management - A South African perspective

    SciTech Connect (OSTI)

    Friedrich, Elena, E-mail: Friedriche@ukzn.ac.z [University of KwaZulu-Natal, CRECHE, School of Civil Engineering, Surveying and Construction, Howard College Campus, Durban (South Africa); Trois, Cristina [University of KwaZulu-Natal, CRECHE, School of Civil Engineering, Surveying and Construction, Howard College Campus, Durban (South Africa)

    2010-11-15T23:59:59.000Z

    This paper investigates how greenhouse gases are accounted and reported in the waste sector in South Africa. Developing countries (including South Africa) do not have binding emission reduction targets, but many of them publish different greenhouse gas emissions data which have been accounted and reported in different ways. Results show that for South Africa, inventories at national and municipal level are the most important tools in the process of accounting and reporting greenhouse gases from waste. For the development of these inventories international initiatives were important catalysts at national and municipal levels, and assisted in developing local expertise, resulting in increased output quality. However, discrepancies in the methodology used to account greenhouse gases from waste between inventories still remain a concern. This is a challenging issue for developing countries, especially African ones, since higher accuracy methods are more data intensive. Analysis of the South African inventories shows that results from the recent inventories can not be compared with older ones due to the use of different accounting methodologies. More recently the use of Clean Development Mechanism (CDM) procedures in Africa, geared towards direct measurements of greenhouse gases from landfill sites, has increased and resulted in an improvement of the quality of greenhouse gas inventories at municipal level.

  7. Analise Matematica III Turma Especial Ficha Extra 2 Termodinamica dos Gases Ideais

    E-Print Network [OSTI]

    Natário, José

    Anâ??alise Matemâ??atica III ­ Turma Especial Ficha Extra 2 ­ Termodinâ??amica dos Gases Ideais N Termodinâ??amica afirma que existe uma funâ?şcâ?ťao E : M # R, dita a energia interna do gâ??as, cuja derivadaâ??amicos gerais pela Segunda Lei da Termodinâ??amica. 2 #12;

  8. Abstract--Energy consumption and the concomitant Green House Gases (GHG) emissions of network infrastructures are

    E-Print Network [OSTI]

    Politčcnica de Catalunya, Universitat

    Abstract--Energy consumption and the concomitant Green House Gases (GHG) emissions of network as for their energy consumption. Renewable energy sources (e.g. solar, wind, tide, etc.) are emerging as a promising and the comparison of several energy-aware static routing and wavelength assignment (RWA) strategies for wavelength

  9. Classical disordered ground states: Super-ideal gases and stealth and equi-luminous materials

    E-Print Network [OSTI]

    Torquato, Salvatore

    Classical disordered ground states: Super-ideal gases and stealth and equi-luminous materials of Materials, Princeton University, Princeton, New Jersey 08544, USA 4 Program in Applied and Computational focus on three classes of configurations with unique radiation scattering characteristics: i "stealth

  10. Survey and assessment of the effects of nonconventional gases on gas distribution equipment

    SciTech Connect (OSTI)

    Jasionowski, W.J.; Scott, M.I.; Gracey, W.C.

    1982-10-01T23:59:59.000Z

    A literature search and a survey of the gas industry were conducted to assess potential problems in the distribution of nonconventional gases. Available literature did not uncover data that would describe potential problems or substantiate the presence of harmful trace elements in final gas compositions produced from various SNG processes. Information from the survey indicates that some companies have encountered problems with nonconventional gases and extraneous additives such as landfill gas, refinery off-gases, oil gas, carbureted water gas, coke-oven gas, propane-air, and compressor lubricant oils. These nonconventional gases and compressor oils may 1) cause pipeline corrosion, 2) degrade some elastomeric materials and greases and affect the integrity of seals, gaskets, O-rings, and meter and regulator diaphragms, and 3) cause operational and safety problems. The survey indicated that 62% of the responding companies plan to use supplemental gas, with most planning on more than one type. Distribution companies intend to significantly increase their use of polyethylene piping from 11.6% in 1980 to 22.4% in 2000 for gas mains and from 33.4% to 50.3% in 2000 for gas service lines.

  11. Centre for Business History to study development of industrial gases industry

    E-Print Network [OSTI]

    Guo, Zaoyang

    be overestimated and the study - funded by German-based gas and engineering company, the Linde Group - aims to give. Wolfgang Reitzle, Chief Executive Officer of Linde AG said: "Over time, industrial gases have changed fellow, also funded by Linde AG, and co-ordinating the project board monitoring progress on the project

  12. Nuclear fusion in gases of deuterium clusters heated with a femtosecond T. Ditmire,

    E-Print Network [OSTI]

    Ditmire, Todd

    Nuclear fusion in gases of deuterium clusters heated with a femtosecond laser* T. Ditmire, J deuterium­deuterium DD nuclear fusion. By diagnosing the fusion yield through measurements of 2.45 Me release of kinetic energy in fast ions can be harnessed to drive nuclear fusion between deuterium ions

  13. Experimental observation of a traveling plasma grating formed by two crossing filaments in gases

    SciTech Connect (OSTI)

    Durand, Magali [Laboratoire d'Optique Appliquee, ENSTA ParisTech-Ecole Polytechnique-CNRS, 91761 Palaiseau (France); ONERA, Chemin de la Huniere, 91761 Palaiseau (France); Liu Yi; Forestier, Benjamin; Houard, Aurelien; Mysyrowicz, Andre [Laboratoire d'Optique Appliquee, ENSTA ParisTech-Ecole Polytechnique-CNRS, 91761 Palaiseau (France)

    2011-03-21T23:59:59.000Z

    The spatial motion and effective duration of a traveling plasma grating formed by two interfering femtosecond laser filaments in gases is characterized by its Doppler effect imparted on a probe pulse. The shift velocity determined experimentally agrees with the theoretical calculations.

  14. Intercomparison of tritium and noble gases analyses, 3 and derived parameters excess air and recharge temperature

    E-Print Network [OSTI]

    Intercomparison of tritium and noble gases analyses, 3 H/3 He ages and derived parameters excess with the tritium­helium (3 H/3 He) method has become a powerful tool for hydrogeologists. The uncertainty in the inter- comparison for tritium analyses and ten laboratories participated in the noble gas

  15. PHYSICAL REVIEW A 81, 023611 (2010) Critical temperature of dilute Bose gases

    E-Print Network [OSTI]

    Ueltschi, Daniel

    2010-01-01T23:59:59.000Z

    and Daniel Ueltschi* Department of Mathematics, University of Warwick, Coventry CV4 7AL, United Kingdom quantum particles become winding Brownian bridges in one more dimension [1,16]. For dilute gases, Bose method to a test by computing the free energy of the effective model. As it turns out, it is equal

  16. On the Critical Temperature of Dilute Bose Gases Volker Betz and Daniel Ueltschi

    E-Print Network [OSTI]

    Betz, Volker

    of Mathematics, University of Warwick, Coventry, CV4 7AL, United Kingdom We compute the critical temperature quantum particles become winding Brownian bridges in one more dimension [1, 16]. For dilute gases, Bose responsible. Finally, we put our method to a test by computing the free energy of the effective model

  17. Internal structure and expansion dynamics of laser ablation plumes into ambient gases

    E-Print Network [OSTI]

    Harilal, S. S.

    Internal structure and expansion dynamics of laser ablation plumes into ambient gases S. S. Harilal 13 December 2002 The effect of ambient gas on the expansion dynamics of the plasma generated by laser together with time resolved emission diagnostics, a triple structure of the plume was observed

  18. Measurement and Analysis of the Relationship between Ammonia, Acid Gases, and Fine Particles in Eastern North

    E-Print Network [OSTI]

    Aneja, Viney P.

    ).2­4 Gas-to-particle conversion can be accomplished by condensation, which adds mass onto preMeasurement and Analysis of the Relationship between Ammonia, Acid Gases, and Fine Particles acid gas con- centrations of 0.23 g/m3 hydrochloric acid (standard deviation [SD] 0.2 g/m3 ); 1.14 g/m3

  19. Atmospheric Environment 42 (2008) 30763086 Scavenging of soluble gases by evaporating and growing cloud

    E-Print Network [OSTI]

    Elperin, Tov

    and condensation of a cloud droplet in the presence of soluble gases. It is assumed that gas absorption we performed numerical analysis of simultaneous heat and mass transfer during evaporation into account thermal effect of gas absorption. It was shown that nonlinear behavior of different parameters

  20. Truck Stop Electrification as a Strategy To Reduce Greenhouse Gases, Fuel Consumption and Pollutant Emissions

    E-Print Network [OSTI]

    Truck Stop Electrification as a Strategy To Reduce Greenhouse Gases, Fuel Consumption and Pollutant, Schneider, Lee, Bubbosh 2 ABSTRACT Extended truck idling is a very large source of fuel wastage, greenhouse, most long-haul truck drivers idle their vehicles for close to 10 hours per day to operate heating

  1. Theoretical Gas Phase Mass Transfer Coefficients for Endogenous Gases in the Lungs

    E-Print Network [OSTI]

    George, Steven C.

    Theoretical Gas Phase Mass Transfer Coefficients for Endogenous Gases in the Lungs PETER CONDORELLI, is produced within the tissue of the airways of the lungs.16 As an intercellular messenger, NO is involved is available regarding the basic gas exchange dynamics of NO in the lungs. Ingested ethanol EtOH is transported

  2. Multiphase Sequestration Geochemistry: Model for Mineral Carbonation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Multiphase Sequestration Geochemistry: Model for Mineral Carbonation. Multiphase Sequestration Geochemistry: Model for Mineral Carbonation. Abstract: Carbonation of formation...

  3. Carbon Sequestration via Mineral Carbonation: Overview and Assessment

    E-Print Network [OSTI]

    1 Carbon Sequestration via Mineral Carbonation: Overview and Assessment 14 March 2002 Howard Herzog overview and assessment of carbon sequestration by mineral carbonation (referred to as "mineral sequestration R&D. The first is that carbonates have a lower energy state than CO2. Therefore, at least

  4. Would Border Carbon Adjustments prevent carbon leakage and heavy industry

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    No 52-2013 Would Border Carbon Adjustments prevent carbon leakage and heavy industry halshs-00870689,version1-7Oct2013 #12;Would Border Carbon Adjustments prevent carbon leakage and heavy The efficiency of unilateral climate policies may be hampered by carbon leakage and competitiveness losses

  5. Carbon RRLs Carbon RRLs towards Ultra-compact HII Regions

    E-Print Network [OSTI]

    Balser, Dana S.

    Carbon RRLs Carbon RRLs towards Ultra-compact HII Regions Dana S. Balser D. Anish Roshi (Raman (Agnes Scott College) #12;Carbon RRLs Carbon Radio Recombination Lines (RRLs) NGC 2024 (Orion B) IC 1795 (W3) Palmer et al. (1967) #12;Carbon RRLs Photodissociation Regions (PDRs) Hollenbach & Tielens (1997

  6. Cumulative Carbon and Just Allocation of the Global Carbon Commons

    E-Print Network [OSTI]

    Pierrehumbert, Raymond

    Cumulative Carbon and Just Allocation of the Global Carbon Commons R.T. Pierrehumbert1 on climate can be characterized by a single statistic, called Cumulative Carbon. This is the aggregate amount of carbon emitted in the form of carbon dioxide by activities such as fossil fuel burning and deforestation

  7. Pyrolytic carbon electrodes Lithographically Defined Porous Carbon Electrodes**

    E-Print Network [OSTI]

    New Mexico, University of

    Pyrolytic carbon electrodes Lithographically Defined Porous Carbon Electrodes** D. Bruce Burckel Polsky* The special nature of the CŔC bond can lead to various polymorphic forms of carbon such as graphite, glassy-carbon, fullerenes (such as buckyballs), carbon nanotubes, and diamond. Electrodes made

  8. Characterization of Fine Particulate Matter (PM) and Secondary PM Precursor Gases in the Mexico City Metropolitan Area

    SciTech Connect (OSTI)

    Luisa T. Molina, Rainer Volkamer, Benjamin de Foy, Wenfang Lei, Miguel Zavala, Erik Velasco; Mario J. Molina

    2008-10-31T23:59:59.000Z

    This project was one of three collaborating grants funded by DOE/ASP to characterize the fine particulate matter (PM) and secondary PM precursors in the Mexico City Metropolitan Area (MCMA) during the MILAGRO Campaign. The overall effort of MCMA-2006, one of the four components, focused on i) examination of the primary emissions of fine particles and precursor gases leading to photochemical production of atmospheric oxidants and secondary aerosol particles; ii) measurement and analysis of secondary oxidants and secondary fine PM production, with particular emphasis on secondary organic aerosol (SOA), and iii) evaluation of the photochemical and meteorological processes characteristic of the Mexico City Basin. The collaborative teams pursued the goals through three main tasks: i) analyses of fine PM and secondary PM precursor gaseous species data taken during the MCMA-2002/2003 campaigns and preparation of publications; ii) planning of the MILAGRO Campaign and deployment of the instrument around the MCMA; and iii) analysis of MCMA-2006 data and publication preparation. The measurement phase of the MILAGRO Campaign was successfully completed in March 2006 with excellent participation from the international scientific community and outstanding cooperation from the Mexican government agencies and institutions. The project reported here was led by the Massachusetts Institute of Technology/Molina Center for Energy and the Environment (MIT/MCE2) team and coordinated with DOE/ASP-funded collaborators at Aerodyne Research Inc., University of Colorado at Boulder and Montana State University. Currently 24 papers documenting the findings from this project have been published. The results from the project have improved significantly our understanding of the meteorological and photochemical processes contributing to the formation of ozone, secondary aerosols and other pollutants. Key findings from the MCMA-2003 include a vastly improved speciated emissions inventory from on-road vehicles: the MCMA motor vehicles produce abundant amounts of primary PM, elemental carbon, particle-bound polycyclic aromatic hydrocarbons, carbon monoxide and a wide range of air toxics; the feasibility of using eddy covariance techniques to measure fluxes of volatile organic compounds in an urban core and a valuable tool for validating local emissions inventory; a much better understanding of the sources and atmospheric loadings of volatile organic compounds; the first spectroscopic detection of glyoxal in the atmosphere; a unique analysis of the high fraction of ambient formaldehyde from primary emission sources; characterization of ozone formation and its sensitivity to VOCs and NOx; a much more extensive knowledge of the composition, size distribution and atmospheric mass loadings of both primary and secondary fine PM, including the fact that the rate of MCMA SOA production greatly exceeded that predicted by current atmospheric models; evaluations of significant errors that can arise from standard air quality monitors for O3 and NO2; and the implementation of an innovative Markov Chain Monte Carlo method for inorganic aerosol modeling as a powerful tool to analyze aerosol data and predict gas phase concentrations where these are unavailable. During the MILAGRO Campaign the collaborative team utilized a combination of central fixed sites and a mobile laboratory deployed throughout the MCMA to representative urban and boundary sites to measure trace gases and fine particles. Analysis of the extensive 2006 data sets has confirmed the key findings from MCMA-2002/2003; additionally MCMA-2006 provided more detailed gas and aerosol chemistry and wider regional scale coverage. Key results include an updated 2006 emissions inventory; extension of the flux system to measure fluxes of fine particles; better understanding of the sources and apportionment of aerosols, including contribution from biomass burning and industrial sources; a comprehensive evaluation of metal containing particles in a complex urban environment; identification of a close correlation between

  9. Mesoporous carbon materials

    DOE Patents [OSTI]

    Dai, Sheng; Wang, Xiqing

    2013-08-20T23:59:59.000Z

    The invention is directed to a method for fabricating a mesoporous carbon material, the method comprising subjecting a precursor composition to a curing step followed by a carbonization step, the precursor composition comprising: (i) a templating component comprised of a block copolymer, (ii) a phenolic compound or material, (iii) a crosslinkable aldehyde component, and (iv) at least 0.5 M concentration of a strong acid having a pKa of or less than -2, wherein said carbonization step comprises heating the precursor composition at a carbonizing temperature for sufficient time to convert the precursor composition to a mesoporous carbon material. The invention is also directed to a mesoporous carbon material having an improved thermal stability, preferably produced according to the above method.

  10. Mesoporous carbon materials

    DOE Patents [OSTI]

    Dai, Sheng (Knoxville, TN); Wang, Xiqing (Oak Ridge, TN)

    2012-02-14T23:59:59.000Z

    The invention is directed to a method for fabricating a mesoporous carbon material, the method comprising subjecting a precursor composition to a curing step followed by a carbonization step, the precursor composition comprising: (i) a templating component comprised of a block copolymer, (ii) a phenolic compound or material, (iii) a crosslinkable aldehyde component, and (iv) at least 0.5 M concentration of a strong acid having a pKa of or less than -2, wherein said carbonization step comprises heating the precursor composition at a carbonizing temperature for sufficient time to convert the precursor composition to a mesoporous carbon material. The invention is also directed to a mesoporous carbon material having an improved thermal stability, preferably produced according to the above method.

  11. Southeast Regional Carbon Sequestration Partnership (SECARB)

    SciTech Connect (OSTI)

    Kenneth J. Nemeth

    2005-09-30T23:59:59.000Z

    The Southeast Regional Carbon Sequestration Partnership (SECARB) is a diverse partnership covering eleven states involving the Southern States Energy Board (SSEB) an interstate compact; regulatory agencies and/or geological surveys from member states; the Electric Power Research Institute (EPRI); academic institutions; a Native American enterprise; and multiple entities from the private sector. Figure 1 shows the team structure for the partnership. In addition to the Technical Team, the Technology Coalition, an alliance of auxiliary participants, in the project lends yet more strength and support to the project. The Technology Coalition, with its diverse representation of various sectors, is integral to the technical information transfer, outreach, and public perception activities of the partnership. The Technology Coalition members, shown in Figure 2, also provide a breadth of knowledge and capabilities in the multiplicity of technologies needed to assure a successful outcome to the project and serve as an extremely important asset to the partnership. The eleven states comprising the multi-state region are: Alabama; Arkansas; Florida; Georgia; Louisiana; Mississippi; North Carolina; South Carolina; Tennessee; Texas; and Virginia. The states making up the SECARB area are illustrated in Figure 3. The primary objectives of the SECARB project include: (1) Supporting the U.S. Department of Energy (DOE) Carbon Sequestration Program by promoting the development of a framework and infrastructure necessary for the validation and deployment of carbon sequestration technologies. This requires the development of relevant data to reduce the uncertainties and risks that are barriers to sequestration, especially for geologic storage in the SECARB region. Information and knowledge are the keys to establishing a regional carbon dioxide (CO{sub 2}) storage industry with public acceptance. (2) Supporting the President's Global Climate Change Initiative with the goal of reducing greenhouse gas intensity by 18 percent by 2012. A corollary to the first objective, this objective requires the development of a broad awareness across government, industry, and the general public of sequestration issues and establishment of the technological and legal frameworks necessary to achieve the President's goal. The information developed by the SECARB team will play a vital role in achieving the President's goal for the southeastern region of the United States. (3) Evaluating options and potential opportunities for regional CO{sub 2} sequestration. This requires characterization of the region regarding the presence and location of sources of greenhouse gases (GHGs), primarily CO{sub 2}, the presence and location of potential carbon sinks and geological parameters, geographical features and environmental concerns, demographics, state and interstate regulations, and existing infrastructure.

  12. Diffusion through Carbon Nanotube Semipermeable membranes

    SciTech Connect (OSTI)

    Bakajin, O

    2006-02-13T23:59:59.000Z

    The goal of this project is to measure transport through CNTs and study effects of confinement at molecular scale. This work is motivated by several simulation papers in high profile journals that predict significantly higher transport rates of gases and liquids through carbon nanotubes as compared with similarly-sized nanomaterials (e.g. zeolites). The predictions are based on the effects of confinement, atomically smooth pore walls and high pore density. Our work will provide the first measurements that would compare to and hopefully validate the simulations. Gas flux is predicted to be >1000X greater for SWNTs versus zeolitesi. A high flux of 6-30 H2O/NT/ns {approx} 8-40 L/min for a 1cm{sup 2} membrane is also predicted. Neutron diffraction measurements indicate existence of a 1D water chain within a cylindrical ice sheet inside carbon nanotubes, which is consistent with the predictions of the simulation. The enabling experimental platform that we are developing is a semipermeable membrane made out of vertically aligned carbon nanotubes with gaps between nanotubes filled so that the transport occurs through the nanotubes. The major challenges of this project included: (1) Growth of CNTs in the suitable vertically aligned configuration, especially the single wall carbon nanotubes; (2) Development of a process for void-free filling gaps between CNTs; and (3) Design of the experiments that will probe the small amounts of analyte that go through. Knowledge of the behavior of water upon nanometer-scale confinement is key to understanding many biological processes. For example, the protein folding process is believed to involve water confined in a hydrophobic environment. In transmembrane proteins such as aquaporins, water transport occurs under similar conditions. And in fields as far removed as oil recovery and catalysis, an understanding of the nanoscale molecular transport occurring within the nanomaterials used (e.g. zeolites) is the key to process optimization. Furthermore, advancement of many emerging nanotechnologies in chemistry and biology will undoubtedly be aided by an understanding confined water transport, particularly the details of hydrogen bonding and solvation that become crucial on this length scale. We can envision several practical applications for our devices, including desalination, gas separations, dialysis, and semipermeable fabrics for protection against CW agents etc. The single wall carbon nanotube membranes will be the key platform for applications because they will allow high transport rates of small molecules such as water and eliminate solvated ions or CW agents.

  13. Process for separating carbon dioxide from flue gas using sweep-based membrane separation and absorption steps

    DOE Patents [OSTI]

    Wijmans, Johannes G.; Baker, Richard W.; Merkel, Timothy C.

    2012-08-21T23:59:59.000Z

    A gas separation process for treating flue gases from combustion processes, and combustion processes including such gas separation. The invention involves routing a first portion of the flue gas stream to be treated to an absorption-based carbon dioxide capture step, while simultaneously flowing a second portion of the flue gas across the feed side of a membrane, flowing a sweep gas stream, usually air, across the permeate side, then passing the permeate/sweep gas to the combustor.

  14. Activated Carbon Injection

    ScienceCinema (OSTI)

    None

    2014-07-22T23:59:59.000Z

    History of the Clean Air Act and how the injection of carbon into a coal power plant's flu smoke can reduce the amount of mercury in the smoke.

  15. Carbon Fiber SMC

    Broader source: Energy.gov (indexed) [DOE]

    confidential, or otherwise restricted information. ACC932 Materials and Processes Technology Development Carbon Fiber SMC 5-20-09 Charles Knakal USCAR C. S. Wang General Motors...

  16. Activated Carbon Injection

    SciTech Connect (OSTI)

    None

    2014-07-16T23:59:59.000Z

    History of the Clean Air Act and how the injection of carbon into a coal power plant's flu smoke can reduce the amount of mercury in the smoke.

  17. Reinforced Carbon Nanotubes.

    DOE Patents [OSTI]

    Ren, Zhifen (Newton, MA); Wen, Jian Guo (Newton, MA); Lao, Jing Y. (Chestnut Hill, MA); Li, Wenzhi (Brookline, MA)

    2005-06-28T23:59:59.000Z

    The present invention relates generally to reinforced carbon nanotubes, and more particularly to reinforced carbon nanotubes having a plurality of microparticulate carbide or oxide materials formed substantially on the surface of such reinforced carbon nanotubes composite materials. In particular, the present invention provides reinforced carbon nanotubes (CNTs) having a plurality of boron carbide nanolumps formed substantially on a surface of the reinforced CNTs that provide a reinforcing effect on CNTs, enabling their use as effective reinforcing fillers for matrix materials to give high-strength composites. The present invention also provides methods for producing such carbide reinforced CNTs.

  18. Carbon Fiber Technology Facility

    Broader source: Energy.gov (indexed) [DOE]

    conventional and alternative precursors to carbon fiber Advance high-volume composite design and manufacturing capabilities Transition technology to industry partners...

  19. EMBODIED CARBON TARIFFS Christoph Bhringer

    E-Print Network [OSTI]

    EMBODIED CARBON TARIFFS Christoph Böhringer Jared C. Carbone Thomas F. Rutherford Revised: August 2013 Abstract Embodied carbon tariffs tax the direct and indirect carbon emissions embodied in trade -- an idea popularized by countries seeking to extend the reach of domestic carbon regu- lations. We

  20. Carbon-Optimal and Carbon-Neutral Supply Chains

    E-Print Network [OSTI]

    Caro, F.; Corbett, C. J.; Tan, T.; Zuidwijk, R.

    2011-01-01T23:59:59.000Z

    Y. Li, M. Daskin. 2009. Carbon Footprint and the ManagementJ. van Houtum. 2011. E?ect of carbon emission regulations onStreamlined Enterprise Carbon Footprinting. Environmental

  1. Tunneling effects in the kinetics of helium and hydrogen isotopes desorption from single-walled carbon nanotube bundles

    SciTech Connect (OSTI)

    Danilchenko, B. A., E-mail: danil@iop.kiev.ua; Yaskovets, I. I.; Uvarova, I. Y. [Institute of Physics NASU, Pr. Nauki 46, 03680 Kiev (Ukraine); Dolbin, A. V.; Esel'son, V. B.; Basnukaeva, R. M.; Vinnikov, N. A. [B. Verkin Institute for Low Temperature Physics and Engineering NASU, 47 Lenin Ave., Kharkov 61103 (Ukraine)

    2014-04-28T23:59:59.000Z

    The kinetics of desorption both helium isotopes and molecules of hydrogen and deuterium from open-ended or ?-irradiated single-walled carbon nanotube bundles was investigated in temperature range of 10–300?K. The gases desorption rates obey the Arrhenius law at high temperatures, deviate from it with temperature reduction and become constant at low temperatures. These results indicate the quantum nature of gas outflow from carbon nanotube bundles. We had deduced the crossover temperature below which the quantum corrections to the effective activation energy of desorption become significant. This temperature follows linear dependence against the inverse mass of gas molecule and is consistent with theoretical prediction.

  2. Physical and chemical properties of the regional mixed layer of Mexico's Megapolis – Part II: Evaluation of measured and modeled trace gases and particle size distributions

    SciTech Connect (OSTI)

    Ochoa, Carlos; Baumgardner, Darrel; Grutter, M.; Allan, James D.; Fast, Jerome D.; Rappengluck, B.

    2012-10-31T23:59:59.000Z

    This study extends the work of Baumgardner et al. (2009) in which measurements of trace gases and particles at a remote, high-altitude mountain site 60 km from Mexico City were analyzed with respect to the origin of air masses. In the current evaluation, the temperature, water vapor, ozone (O3), carbon monoxide (CO), acyl peroxy nitrate (APN) and particle size distributions (PSDs) of the mass concentrations of sulfate, nitrate, ammonium and organic mass (OM) were simulated with the WRF-Chem chemical transport model and compared with the measurements at the mountain site. The model prediction of the diurnal trends of the gases were well correlated with the measurements before the regional boundary layer reached the measurement site but underestimated the concentrations after that time. The differences are caused by an overly rapid growth of the boundary layer by the model with too much dilution. There also appears to be more O3 produced by photochemical production, downwind of the emission sources, than predicted by the model. The measured and modeled PSDs compare very well with respect to their general shape and diameter of the peak concentrations. The spectra are log normally distributed with most of the mass in the accumulation mode and the geometric diameter centered at 200 ±20 nm, with little observed or predicted change with respect to the origin of the air mass or the time when the RBL is above the Altzomoni research. Only the total mass changed with time and air mass origin. The invariability of the average diameter of the accumulation mode suggests that there is very little growth of the particles by condensation or coagulation after six hours of aging downwind of the major sources of anthropogenic emissions in Mexico’s Megapolis.

  3. Molybdenum-based additives to mixed-metal oxides for use in hot gas cleanup sorbents for the catalytic decomposition of ammonia in coal gases

    DOE Patents [OSTI]

    Ayala, Raul E. (Clifton Park, NY)

    1993-01-01T23:59:59.000Z

    This invention relates to additives to mixed-metal oxides that act simultaneously as sorbents and catalysts in cleanup systems for hot coal gases. Such additives of this type, generally, act as a sorbent to remove sulfur from the coal gases while substantially simultaneously, catalytically decomposing appreciable amounts of ammonia from the coal gases.

  4. Carbon-Optimal and Carbon-Neutral Supply Chains

    E-Print Network [OSTI]

    Caro, F.; Corbett, C. J.; Tan, T.; Zuidwijk, R.

    2011-01-01T23:59:59.000Z

    Pearce, D. 2003. The Social Cost Of Carbon And Its PolicyR.S.J. 2008. The Social Cost of Carbon: Trends, Outliers and

  5. Carbon Park Environmental Impact Assessment

    E-Print Network [OSTI]

    of offsetting the University's carbon footprint, promoting biodiversity and establishing easily maintained Carbon Park Environmental Impact Assessment A B.E.S.T. Project By, Adam Bond 2011 #12; Bishop's University Carbon Park

  6. First Proof of Ferromagnetic Carbon

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Proof of Ferromagnetic Carbon First Proof of Ferromagnetic Carbon Print Wednesday, 25 July 2007 00:00 Although it has long been suspected that carbon belongs on the short list of...

  7. Lead carbonate scintillator materials

    DOE Patents [OSTI]

    Derenzo, Stephen E. (Pinole, CA); Moses, William W. (Berkeley, CA)

    1991-01-01T23:59:59.000Z

    Improved radiation detectors containing lead carbonate or basic lead carbonate as the scintillator element are disclosed. Both of these scintillators have been found to provide a balance of good stopping power, high light yield and short decay constant that is superior to other known scintillator materials. The radiation detectors disclosed are favorably suited for use in general purpose detection and in medical uses.

  8. Fly ash carbon passivation

    DOE Patents [OSTI]

    La Count, Robert B; Baltrus, John P; Kern, Douglas G

    2013-05-14T23:59:59.000Z

    A thermal method to passivate the carbon and/or other components in fly ash significantly decreases adsorption. The passivated carbon remains in the fly ash. Heating the fly ash to about 500 and 800 degrees C. under inert gas conditions sharply decreases the amount of surfactant adsorbed by the fly ash recovered after thermal treatment despite the fact that the carbon content remains in the fly ash. Using oxygen and inert gas mixtures, the present invention shows that a thermal treatment to about 500 degrees C. also sharply decreases the surfactant adsorption of the recovered fly ash even though most of the carbon remains intact. Also, thermal treatment to about 800 degrees C. under these same oxidative conditions shows a sharp decrease in surfactant adsorption of the recovered fly ash due to the fact that the carbon has been removed. This experiment simulates the various "carbon burnout" methods and is not a claim in this method. The present invention provides a thermal method of deactivating high carbon fly ash toward adsorption of AEAs while retaining the fly ash carbon. The fly ash can be used, for example, as a partial Portland cement replacement in air-entrained concrete, in conductive and other concretes, and for other applications.

  9. Interaction with thermal radiation in the free expansion and mixing of ideal gases and Gibbs' paradox in classical thermodynamics

    E-Print Network [OSTI]

    A. Paglietti

    2009-04-26T23:59:59.000Z

    The standard theory of ideal gases ignores the interaction of the gas particles with the thermal radiation (photon gas) that fills the otherwise vacuum space between them. This is an unphysical feature of the theory since every material in this universe, and hence also the particles of a gas, absorbs and radiates thermal energy. The interaction with the thermal radiation that is contained within the volume of the body may be important in gases since the latter, unlike solids and liquids, are capable of undergoing conspicuous volume changes. Taking this interaction into account makes the behaviour of the ideal gases more realistic and removes Gibbs' paradox.

  10. CARBON SEQUESTRATION STRATEGIES FOR CALIFORNIA

    E-Print Network [OSTI]

    GEOLOGIC CARBON SEQUESTRATION STRATEGIES FOR CALIFORNIA: REPORT TO THE LEGISLATURE Regional Carbon Sequestration Partnership (WESTCARB) studies that we used, including Cameron Downey

  11. Nuclear magnetic resonance of laser-polarized noble gases in molecules, materials and organisms

    SciTech Connect (OSTI)

    Goodson, Boyd M.

    1999-12-01T23:59:59.000Z

    Conventional nuclear magnetic resonance (NMR) spectroscopy and magnetic resonance imaging (MRI) are fundamentally challenged by the insensitivity that stems from the ordinarily low spin polarization achievable in even the strongest NMR magnets. However, by transferring angular momentum from laser light to electronic and nuclear spins, optical pumping methods can increase the nuclear spin polarization of noble gases by several orders of magnitude, thereby greatly enhancing their NMR sensitivity. This dissertation is primarily concerned with the principles and practice of optically pumped nuclear magnetic resonance (OPNMR). The enormous sensitivity enhancement afforded by optical pumping noble gases can be exploited to permit a variety of novel NMR experiments across many disciplines. Many such experiments are reviewed, including the void-space imaging of organisms and materials, NMR and MRI of living tissues, probing structure and dynamics of molecules in solution and on surfaces, and zero-field NMR and MRI.

  12. Free cooling and high-energy tails of granular gases with variable restitution coefficient

    E-Print Network [OSTI]

    Ricardo J. Alonso; Bertrand Lods

    2010-05-31T23:59:59.000Z

    We prove the so-called generalized Haff's law yielding the optimal algebraic cooling rate of the temperature of a granular gas described by the homogeneous Boltzmann equation for inelastic interactions with non constant restitution coefficient. Our analysis is carried through a careful study of the infinite system of moments of the solution to the Boltzmann equation for granular gases and precise Lp estimates in the selfsimilar variables. In the process, we generalize several results on the Boltzmann collision operator obtained recently for homogeneous granular gases with constant restitution coefficient to a broader class of physical restitution coefficients that depend on the collision impact velocity. This generalization leads to the so-called L1-exponential tails theorem. for this model.

  13. Radiolytic and radiolytically induced generation of gases in simulated waste solutions

    SciTech Connect (OSTI)

    Meisel, D.; Sauer, M.C. Jr.; Jonah, C.D.; Diamond, H.; Matheson, M.S.; Barnabas, F.; Cerny, E.; Cheng, Y.

    1990-12-31T23:59:59.000Z

    The radiolytic generation of gases in simulated mixed waste solutions was studied. Computer modeling of the non-homogeneous kinetic processes in these highly concentrated homogeneous solutions was attempted. The predictions of the modeling simulations were verified experimentally. Two sources for the radiolytic generation of H{sub 2} are identified: direct dissociation of highly energetic water molecules and hydrogen abstraction from the organic molecules by hydrogen atoms. Computer simulation of the homogeneous kinetics of the NO{sub X} system indicate that no N{sub 2}O will be produced in the absence of organic solutes and none was experimentally detected. It was also found that long term pre-irradiation of the simulated waste solutions leads to enhanced thermal production of these two gases. 22 refs., 5 figs., 3 tabs.

  14. Radiolytic and radiolytically induced generation of gases in simulated waste solutions

    SciTech Connect (OSTI)

    Meisel, D.; Sauer, M.C. Jr.; Jonah, C.D.; Diamond, H.; Matheson, M.S.; Barnabas, F.; Cerny, E.; Cheng, Y.

    1990-01-01T23:59:59.000Z

    The radiolytic generation of gases in simulated mixed waste solutions was studied. Computer modeling of the non-homogeneous kinetic processes in these highly concentrated homogeneous solutions was attempted. The predictions of the modeling simulations were verified experimentally. Two sources for the radiolytic generation of H{sub 2} are identified: direct dissociation of highly energetic water molecules and hydrogen abstraction from the organic molecules by hydrogen atoms. Computer simulation of the homogeneous kinetics of the NO{sub X} system indicate that no N{sub 2}O will be produced in the absence of organic solutes and none was experimentally detected. It was also found that long term pre-irradiation of the simulated waste solutions leads to enhanced thermal production of these two gases. 22 refs., 5 figs., 3 tabs.

  15. A simple method to estimate entropy of atmospheric gases from their action

    E-Print Network [OSTI]

    Kennedy, Ivan R; Rose, Michael T; Crossan, Angus N

    2015-01-01T23:59:59.000Z

    A convenient model for estimating the total entropy ({\\Sigma}Si) of atmospheric gases based on physical action is proposed. This realistic approach is fully consistent with statistical mechanics, but uses the properties of translational, rotational and vibrational action to partition the entropy. When all sources of action are computed as appropriate non-linear functions, the total input of thermal energy ({\\Sigma}SiT) required to sustain a chemical system at specific temperatures (T) and pressures (p) can be estimated, yielding results in close agreement with published experimental third law values. Thermodynamic properties of gases including enthalpy, Gibbs energy and Helmholtz energy can be easily calculated from simple molecular and physical properties. We propose that these values for entropy are employed both chemically for reactions and physically for computing atmospheric profiles, the latter based on steady state heat flow equilibrating thermodynamics with gravity. We also predict that this applicati...

  16. Membranes, methods of making membranes, and methods of separating gases using membranes

    DOE Patents [OSTI]

    Ho, W. S. Winston

    2012-10-02T23:59:59.000Z

    Membranes, methods of making membranes, and methods of separating gases using membranes are provided. The membranes can include at least one hydrophilic polymer, at least one cross-linking agent, at least one base, and at least one amino compound. The methods of separating gases using membranes can include contacting a gas stream containing at least one of CO.sub.2, H.sub.2S, and HCl with one side of a nonporous and at least one of CO.sub.2, H.sub.2S, and HCl selectively permeable membrane such that at least one of CO.sub.2, H.sub.2S, and HCl is selectively transported through the membrane.

  17. Isotopic measurements of solar noble gases in individual micrometeorites from Greenland and Antarctica

    SciTech Connect (OSTI)

    Olinger, C.T.

    1990-01-01T23:59:59.000Z

    Noble gases are studied in individual 100 micron-size particles selected from Greenland and Antarctic glacial sediments. Noble gas isotopic and elemental patterns confirm the extraterrestrial origin of 81 out of 302 particles studied. Micrometeorites in this size range are particularly interesting because they correspond to the peak of the meteoritic mass flux distribution. Many particles studied are compositionally and morphologically similar to known meteoritic materials.

  18. Evolution and stability of shock waves in dissipative gases characterized by activated inelastic collisions

    E-Print Network [OSTI]

    Nick Sirmas; Matei I. Radulescu

    2015-01-14T23:59:59.000Z

    Previous experiments have revealed that shock waves driven through dissipative gases may become unstable, for example, in granular gases, and in molecular gases undergoing strong relaxation effects. The mechanisms controlling these instabilities are not well understood. We successfully isolated and investigated this instability in the canonical problem of piston driven shock waves propagating into a medium characterized by inelastic collision processes. We treat the standard model of granular gases, where particle collisions are taken as inelastic with constant coefficient of restitution. The inelasticity is activated for sufficiently strong collisions. Molecular dynamic simulations were performed for 30,000 particles. We find that all shock waves investigated become unstable, with density non-uniformities forming in the relaxation region. The wavelength of these fingers is found comparable to the characteristic relaxation thickness. Shock Hugoniot curves for both elastic and inelastic collisions were obtained analytically and numerically. Analysis of these curves indicate that the instability is not of the Bethe-Zeldovich-Thompson or Dyakov-Kontorovich types. Analysis of the shock relaxation rates and rates for clustering in a convected fluid element with the same thermodynamic history outruled the clustering instability of a homogeneous granular gas. Instead, wave reconstruction of the early transient evolution indicates that the onset of instability occurs during the re-pressurization of the gas following the initial relaxation of the medium behind the lead shock. This re-pressurization gives rise to internal pressure waves in the presence of strong density gradients. This indicates that the mechanism of instability is more likely of the vorticity-generating Richtmyer-Meshkov type, relying on the action of the inner pressure waves development during the transient relaxation.

  19. Selective Catalytic Oxidation of Hydrogen Sulfide to Elemental Sulfur from Coal-Derived Fuel Gases

    SciTech Connect (OSTI)

    Gardner, Todd H.; Berry, David A.; Lyons, K. David; Beer, Stephen K.; Monahan, Michael J.

    2001-11-06T23:59:59.000Z

    The development of low cost, highly efficient, desulfurization technology with integrated sulfur recovery remains a principle barrier issue for Vision 21 integrated gasification combined cycle (IGCC) power generation plants. In this plan, the U. S. Department of Energy will construct ultra-clean, modular, co-production IGCC power plants each with chemical products tailored to meet the demands of specific regional markets. The catalysts employed in these co-production modules, for example water-gas-shift and Fischer-Tropsch catalysts, are readily poisoned by hydrogen sulfide (H{sub 2}S), a sulfur contaminant, present in the coal-derived fuel gases. To prevent poisoning of these catalysts, the removal of H{sub 2}S down to the parts-per-billion level is necessary. Historically, research into the purification of coal-derived fuel gases has focused on dry technologies that offer the prospect of higher combined cycle efficiencies as well as improved thermal integration with co-production modules. Primarily, these concepts rely on a highly selective process separation step to remove low concentrations of H{sub 2}S present in the fuel gases and produce a concentrated stream of sulfur bearing effluent. This effluent must then undergo further processing to be converted to its final form, usually elemental sulfur. Ultimately, desulfurization of coal-derived fuel gases may cost as much as 15% of the total fixed capital investment (Chen et al., 1992). It is, therefore, desirable to develop new technology that can accomplish H{sub 2}S separation and direct conversion to elemental sulfur more efficiently and with a lower initial fixed capital investment.

  20. One-dimensional ultracold atomic gases: impact of the effective range on integrability

    E-Print Network [OSTI]

    Tom Kristensen; Ludovic Pricoupenko

    2015-06-12T23:59:59.000Z

    The one-dimensional one-component Bose and Fermi gases are considered in a regime of large effective range. We focus our study on the three-body problem, which is at the heart of the integra-bility issue. For fermions, the vicinity of the integrability is characterized by large deviations with respect to the predictions of the Bethe ansatz. For the consistency of the contact model, it appears essential to take into account the contact of three particles.

  1. Temperature jump in degenerate quantum gases in the presence of a Bose - Einstein condensate

    E-Print Network [OSTI]

    A. V. Latyshev; A. A. Yushkanov

    2010-01-04T23:59:59.000Z

    We construct a kinetic equation modeling the behavior of degenerate quantum Bose gases whose collision rate depends on the momentum of elementary excitations. We consider the case where the phonon component is the decisive factor in the elementary excitations. We analytically solve the half-space boundary value problem of the temperature jump at the boundary of the degenerate Bose gas in the presence of a Bose -- Einstein condensate.

  2. New York Nonhydrocarbon Gases Removed from Natural Gas (Million Cubic Feet)

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5 Tables July 1996 Energy Information Administration Office ofthrough 1996) inThousandWithdrawals (Million CubicYearNonhydrocarbon Gases

  3. Trace water vapor determination in nitrogen and corrosive gases using infrared spectroscopy

    SciTech Connect (OSTI)

    Espinoza, L.H.; Niemczyk, T.M. [Univ. of New Mexico, Albuquerque, NM (United States). Dept. of Chemistry; Stallard, B.R.; Garcia, M.J. [Sandia National Labs., Albuquerque, NM (United States)

    1997-06-01T23:59:59.000Z

    The generation of particles in gas handling systems as a result of corrosion is a major concern in the microelectronics industry. The corrosion can be caused by the presence of trace quantities of water in corrosive gases such as HCl or HBr. FTIR spectroscopy has been shown to be a method that can be made compatible with corrosive gases and is capable of detecting low ppb levels of water vapor. In this report, the application of FTIR spectroscopy combined with classical least squares multivariate calibration to detect trace H{sub 2}O in N{sub 2}, HCl and HBr is discussed. Chapter 2 discusses the gas handling system and instrumentation required to handle corrosive gases. A method of generating a background spectrum useful to the measurements discussed in this report, as well as in other application areas such as gas phase environmental monitoring, is discussed in Chapter 3. Experimental results obtained with the first system are presented in Chapter 4. Those results made it possible to optimize the design options for the construction of a dedicate system for low ppb water vapor determination. These designs options are discussed in Chapter 5. An FTIR prototype accessory was built. In addition, a commercially available evacuable FTIR system was obtained for evaluation. Test results obtained with both systems are discussed in Chapter 6. Experiments dealing with the interaction between H{sub 2}O-HCl and potential improvements to the detection system are discussed in Chapter 7.

  4. The Spectral Backbone of Excitation Transport in Ultra-Cold Rydberg Gases

    E-Print Network [OSTI]

    Torsten Scholak; Thomas Wellens; Andreas Buchleitner

    2014-11-26T23:59:59.000Z

    The spectral structure underlying excitonic energy transfer in ultra-cold Rydberg gases is studied numerically, in the framework of random matrix theory, and via self-consistent diagrammatic techniques. Rydberg gases are made up of randomly distributed, highly polarizable atoms that interact via strong dipolar forces. Dynamics in such a system is fundamentally different from cases in which the interactions are of short range, and is ultimately determined by the spectral and eigenvector structure. In the energy levels' spacing statistics, we find evidence for a critical energy that separates delocalized eigenstates from states that are localized at pairs or clusters of atoms separated by less than the typical nearest-neighbor distance. We argue that the dipole blockade effect in Rydberg gases can be leveraged to manipulate this transition across a wide range: As the blockade radius increases, the relative weight of localized states is reduced. At the same time, the spectral statistics -- in particular, the density of states and the nearest neighbor level spacing statistics -- exhibits a transition from approximately a 1-stable L\\'evy to a Gaussian orthogonal ensemble. Deviations from random matrix statistics are shown to stem from correlations between interatomic interaction strengths that lead to an asymmetry of the spectral density and profoundly affect localization properties. We discuss approximations to the self-consistent Matsubara-Toyozawa locator expansion that incorporate these effects.

  5. advanced carbon-carbon composites: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 CARBON-CARBON COMPOSITE ALLCOMP Carbon-Carbon Composite Biology and Medicine Websites Summary: CARBON-CARBON...

  6. Molten carbonate fuel cell

    DOE Patents [OSTI]

    Kaun, T.D.; Smith, J.L.

    1986-07-08T23:59:59.000Z

    A molten electrolyte fuel cell is disclosed with an array of stacked cells and cell enclosures isolating each cell except for access to gas manifolds for the supply of fuel or oxidant gas or the removal of waste gas. The cell enclosures collectively provide an enclosure for the array and effectively avoid the problems of electrolyte migration and the previous need for compression of stack components. The fuel cell further includes an inner housing about and in cooperation with the array enclosure to provide a manifold system with isolated chambers for the supply and removal of gases. An external insulated housing about the inner housing provides thermal isolation to the cell components.

  7. Trading Water for Carbon with Biological Carbon Sequestration

    E-Print Network [OSTI]

    Nacional de San Luis, Universidad

    Trading Water for Carbon with Biological Carbon Sequestration Robert B. Jackson,1 * Esteban G. Farley,1 David C. le Maitre,5 Bruce A. McCarl,6 Brian C. Murray7 Carbon sequestration strategies plantations feature prominently among tools for carbon sequestration (1­8). Plantations typi- cally combine

  8. Cumulative Carbon and Just Allocation of the Global Carbon Commons

    E-Print Network [OSTI]

    Pierrehumbert, Raymond

    Cumulative Carbon and Just Allocation of the Global Carbon Commons R.T. Pierrehumbert* Abstract statistic, called cumulative carbon. This statistic is the aggregate amount ofcarbon emitted in theform such activitiespersist.In thispaper the conceptis usedto addressthe question offair allocation of carbon emissions

  9. International Conference on Carbon Nanotechnology: Potential and Challenges (Carbon 10)

    E-Print Network [OSTI]

    Srivastava, Kumar Vaibhav

    International Conference on Carbon Nanotechnology: Potential and Challenges (Carbon 10) 15 - 17th Since the discovery of the carbon nanotube (CNT) about two decades ago, research related to its of Materials and Process Engineering Kanpur Chapter hosted the `International Conference on Carbon

  10. Trichloroethene Removal From Waste Gases in Anaerobic Biotrickling Filters Through Reductive Dechlorination

    E-Print Network [OSTI]

    Popat, Sudeep Chandrakant

    2010-01-01T23:59:59.000Z

    in a foamed emulsion bioreactor. Environ. Sci. Technol.in a foamed emulsion bioreactor. Environ. Sci. Technol.of a trickle-bed bioreactor: Carbon disulfide removal.

  11. Trichloroethene Removal From Waste Gases in Anaerobic Biotrickling Filters Through Reductive Dechlorination

    E-Print Network [OSTI]

    Popat, Sudeep Chandrakant

    2010-01-01T23:59:59.000Z

    this has been done using incineration or adsorption ontoIn the case of TCE, incineration or adsorption ontoonto activated carbon, incineration etc. The principle of

  12. Molten carbonate fuel cell technology improvement

    SciTech Connect (OSTI)

    Not Available

    1991-06-01T23:59:59.000Z

    This report summarizes the work performed under Department of Energy Contract DEAC21-87MC23270, Molten Carbonate Fuel Cell Technology Improvement.'' This work was conducted over a three year period and consisted of three major efforts. The first major effort was the power plant system study which reviewed the competitive requirements for a coal gasifier/molten carbonate fuel cell power plant, produced a conceptual design of a CG/MCFC, and defined the technology development requirements. This effort is discussed in Section 1 of the report. The second major effort involved the design and development of a new MCFC cell configuration which reduced the material content of the cell to a level competitive with competing power plants, simplified the cell configuration to make the components more manufacturable and adaptable to continuous low cost processing techniques, and introduced new-low-pressure drop flow fields for both reactant gases. The new flow fields permitted the incorporation of recirculation systems in both reactant gas systems, permitting simplified cooling techniques and the ability to operate on both natural gas and a wide variety of gasifier fuels. This cell technology improvement is discussed in Section 2. The third major effort involved the scaleup of the new cell configuration to the full-area, 8-sq-ft size and resulted in components used for a 25-kW, 20-cell stack verification test. The verification test was completed with a run of 2200 hours, exceeding the goal of 2000 hours and verifying the new cell design. TWs test, in turn, provided the confidence to proceed to a 100-kW demonstration which is the goal of the subsequent DOE program. The scaleup and stack verification tests are discussed in Sections 3, 4, 5, and 6 of this report.

  13. High-Pressure Phase Equilibria of Ionic Liquids and Compressed Gases for Applications in Reactions and Absorption Refrigeration

    E-Print Network [OSTI]

    Ren, Wei

    2009-12-29T23:59:59.000Z

    for reactions and separations. However, without understanding the phase equilibrium, the kinetics results cannot be properly interpreted. This work also demonstrates that the absorption refrigeration system using ionic liquids and compressed gases in vehicles...

  14. ENVIRON SCIENCE AND TECHNOLOGY IN ROMANIA--ESTROM PROJECT Sources and emission of greenhouse gases in Danube

    E-Print Network [OSTI]

    Wehrli, Bernhard

    gases in Danube Delta lakes Alina Pavel & Edith Durisch-Kaiser & Sorin Balan & Silviu Radan & Sebastian. Radan GeoEcoMar, National Institute for Marine Geology and Geoecology, 024053 Bucharest, Romania E

  15. An analytical inversion method for determining regional and global emissions of greenhouse gases: Sensitivity studies and application to halocarbons

    E-Print Network [OSTI]

    Stohl, A.

    A new analytical inversion method has been developed to determine the regional and global emissions of long-lived atmospheric trace gases. It exploits in situ measurement data from three global networks and builds on ...

  16. IMPACCT: Carbon Capture Technology

    SciTech Connect (OSTI)

    None

    2012-01-01T23:59:59.000Z

    IMPACCT Project: IMPACCT’s 15 projects seek to develop technologies for existing coal-fired power plants that will lower the cost of carbon capture. Short for “Innovative Materials and Processes for Advanced Carbon Capture Technologies,” the IMPACCT Project is geared toward minimizing the cost of removing carbon dioxide (CO2) from coal-fired power plant exhaust by developing materials and processes that have never before been considered for this application. Retrofitting coal-fired power plants to capture the CO2 they produce would enable greenhouse gas reductions without forcing these plants to close, shifting away from the inexpensive and abundant U.S. coal supply.

  17. Self-organisation Processes In The Carbon ARC For Nanosynthis

    SciTech Connect (OSTI)

    Ng, Jonathan; Raitses, Yevgeny

    2014-02-26T23:59:59.000Z

    The atmospheric pressure carbon arc in inert gases such as helium is an important method for the production of nanomaterials. It has recently been shown that the formation of the carbon deposit on the cathode from gaseous carbon plays a crucial role in the operation of the arc, reaching the high temperatures necessary for thermionic emission to take place even with low melting point cathodes. Based on observed ablation and deposition rates, we explore the implications of deposit formation on the energy balance at the cathode surface, and show how the operation of the arc is self-organised process. Our results suggest that the can arc operate in two di erent regimes, one of which has an important contribution from latent heat to the cathode energy balance. This regime is characterised by the enhanced ablation rate, which may be favourable for high yield synthesis of nanomaterials. The second regime has a small and approximately constant ablation rate with a negligible contribution from latent heat.

  18. Self-organisation Processes In The Carbon ARC For Nanosynthis

    SciTech Connect (OSTI)

    Ng, J.; Raitses, Yefgeny [Princeton Plasma Physics Lab., Princeton, NJ (United States)

    2014-02-02T23:59:59.000Z

    The atmospheric pressure carbon arc in inert gases such as helium is an important method for the production of nanomaterials. It has recently been shown that the formation of the carbon deposit on the cathode from gaseous carbon plays a crucial role in the operation of the arc, reaching the high temperatures necessary for thermionic emission to take place even with low melting point cathodes. Based on observed ablation and deposition rates, we explore the implications of deposit formation on the energy balance at the cathode surface, and show how the operation of the arc is self-organised process. Our results suggest that the can arc operate in two di erent regimes, one of which has an important contribution from latent heat to the cathode energy balance. This regime is characterised by the enhanced ablation rate, which may be favourable for high yield synthesis of nanomaterials. The second regime has a small and approximately constant ablation rate with a negligible contribution from latent heat.

  19. Black Carbon’s Properties and Role in the Environment: A Comprehensive Review

    E-Print Network [OSTI]

    Shrestha, Gyami

    2010-01-01T23:59:59.000Z

    carbon has a high carbon sequestration potential due to itsin soil can lead to sustainable carbon sequestration.process takes carbon sequestration from afforestation a step

  20. Method for synthesizing carbon nanotubes

    DOE Patents [OSTI]

    Fan, Hongyou

    2012-09-04T23:59:59.000Z

    A method for preparing a precursor solution for synthesis of carbon nanomaterials, where a polar solvent is added to at least one block copolymer and at least one carbohydrate compound, and the precursor solution is processed using a self-assembly process and subsequent heating to form nanoporous carbon films, porous carbon nanotubes, and porous carbon nanoparticles.

  1. GETTING CARBON CAPTURE AND STORAGE

    E-Print Network [OSTI]

    Haszeldine, Stuart

    GETTING CARBON CAPTURE AND STORAGE TECHNOLOGIES TO MARKET BREAKING THE DEADLOCK Report of a Science: Carbon Capture and Storage © OECD/IEA 2009, fig. 1, p. 6 Figures 2 and 3 reprinted with permission from `UK Carbon storage and capture, where is it?' by Stuart Haszeldine, Professor of Carbon Capture

  2. Research Report Forests and carbon

    E-Print Network [OSTI]

    , baseline, carbon, climate change mitigation, forestry, quality assurance, sequestration. FCRP013/FCResearch Report Forests and carbon: a review of additionality #12;#12;Forests and carbon: a review. ISBN 978-0-85538-816-4 Valatin, G. (2011). Forests and carbon: a review of additionality. Forestry

  3. 4, 1367, 2007 Modelling carbon

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    BGD 4, 13­67, 2007 Modelling carbon overconsumption and extracellular POC formation M. Schartau et carbon overconsumption and the formation of extracellular particulate organic carbon M. Schartau1 , A Correspondence to: M. Schartau (markus.schartau@gkss.de) 13 #12;BGD 4, 13­67, 2007 Modelling carbon

  4. ATK - Supersonic Carbon Capture

    ScienceCinema (OSTI)

    Castrogiovanni, Anthony (ACEnT Laboratories, President and CEO); Calayag, Bon (ATK, Program Manager)

    2014-04-11T23:59:59.000Z

    ATK and ACEnt Laboratories, with the help of ARPA-E funding, have taken an aerospace problem, supersonic condensation, and turned it into a viable clean energy solution for carbon capture.

  5. Carbon Capture Pilots (Kentucky)

    Broader source: Energy.gov [DOE]

    Support for the Carbon Management Research Group (CMRG), a public/private partnership consisting of most of the Commonwealth’s utilities, the Electric Power Research Institute, the Center for...

  6. Extrasolar Carbon Planets

    E-Print Network [OSTI]

    Marc J. Kuchner; S. Seager

    2005-05-02T23:59:59.000Z

    We suggest that some extrasolar planets planets and low-mass white dwarf planets are especially good candidate members of this new class of planets, but these objects could also conceivably form around stars like the Sun. This planet-formation pathway requires only a factor of two local enhancement of the protoplanetary disk's C/O ratio above solar, a condition that pileups of carbonaceous grains may create in ordinary protoplanetary disks. Hot, Neptune-mass carbon planets should show a significant paucity of water vapor in their spectra compared to hot planets with solar abundances. Cooler, less massive carbon planets may show hydrocarbon-rich spectra and tar-covered surfaces. The high sublimation temperatures of diamond, SiC, and other carbon compounds could protect these planets from carbon depletion at high temperatures.

  7. Regional Carbon Sequestration Partnerships

    Broader source: Energy.gov [DOE]

    DOE has created a network of seven Regional Carbon Sequestration Partnerships (RCSPs) to help develop the technology, infrastructure, and regulations to implement large-scale CO2 storage (also...

  8. Low Carbon Fuel Standards

    E-Print Network [OSTI]

    Sperling, Dan; Yeh, Sonia

    2009-01-01T23:59:59.000Z

    S O N I A YE H Low Carbon Fuel Standards The most direct andalternative transportation fuels is to spur innovation withstandard for upstream fuel producers. hen it comes to energy

  9. Activated carbon aerogels

    SciTech Connect (OSTI)

    Hanzawa, Y.; Kaneko, K. [Chiba Univ. (Japan)] [Chiba Univ. (Japan); Pekala, R.W. [Lawrence Livermore National Lab., CA (United States)] [Lawrence Livermore National Lab., CA (United States); Dresselhaus, M.S. [Massachusetts Inst. of Technology, Cambridge, MA (United States)] [Massachusetts Inst. of Technology, Cambridge, MA (United States)

    1996-12-25T23:59:59.000Z

    Activated carbon aerogels were obtained from the CO{sub 2} activation of the carbon aerogels. The adsorption isotherms of nitrogen on activated carbon aerogels at 77 K were measured and analyzed by the high-resolution {alpha}{sub s} plot to evaluate their porosities. The {alpha}{sub s} plot showed an upward deviation from linearity below {alpha}{sub s} = 0.5, suggesting that the presence of micropores becomes more predominant with the extent of the activation. Activation increased noticeably the pore volume and the surface area (the maximum value: 2600 m{sup 2}.g{sup -1}) without change of the basic network structure of primary particles. Activated carbon aerogels had a bimodal pore size distribution of uniform micropores and mesopores. 16 refs., 2 figs., 1 tab.

  10. ATK - Supersonic Carbon Capture

    SciTech Connect (OSTI)

    Castrogiovanni, Anthony (ACEnT Laboratories, President and CEO) [ACEnT Laboratories, President and CEO; Calayag, Bon (ATK, Program Manager) [ATK, Program Manager

    2014-03-05T23:59:59.000Z

    ATK and ACEnt Laboratories, with the help of ARPA-E funding, have taken an aerospace problem, supersonic condensation, and turned it into a viable clean energy solution for carbon capture.

  11. Apparatus and method for carbon fiber surface treatment

    SciTech Connect (OSTI)

    Paulauskas, Felix L; Sherman, Daniel M

    2014-06-03T23:59:59.000Z

    An apparatus and method for enhancing the surface energy and/or surface chemistry of carbon fibers involves exposing the fibers to direct or indirect contact with atmospheric pressure plasma generated using a background gas containing at least some oxygen or other reactive species. The fiber may be exposed directly to the plasma, provided that the plasma is nonfilamentary, or the fiber may be exposed indirectly through contact with gases exhausting from a plasma discharge maintained in a separate volume. In either case, the process is carried out at or near atmospheric pressure, thereby eliminating the need for vacuum equipment. The process may be further modified by moistening the fibers with selected oxygen-containing liquids before exposure to the plasma.

  12. Apparatus and method for carbon fiber surface treatment

    DOE Patents [OSTI]

    Paulauskas, Felix L. (Knoxville, TN); Sherman, Daniel M. (Knoxville, TN)

    2012-07-24T23:59:59.000Z

    An apparatus and method for enhancing the surface energy and/or surface chemistry of carbon fibers involves exposing the fibers to direct or indirect contact with atmospheric pressure plasma generated using a background gas containing at least some oxygen or other reactive species. The fiber may be exposed directly to the plasma, provided that the plasma is nonfilamentary, or the fiber may be exposed indirectly through contact with gases exhausting from a plasma discharge maintained in a separate volume. In either case, the process is carried out at or near atmospheric pressure, thereby eliminating the need for vacuum equipment. The process may be further modified by moistening the fibers with selected oxygen-containing liquids before exposure to the plasma.

  13. Greenhouse Gases

    Broader source: Energy.gov [DOE]

    Federal agencies are required to inventory and manage greenhouse gas (GHG) emissions to meet Federal goals and mitigate climate change.

  14. An investigation of the sub-grid variability of trace gases and aerosols for global climate modeling

    SciTech Connect (OSTI)

    Qian, Yun; Gustafson, William I.; Fast, Jerome D.

    2010-07-29T23:59:59.000Z

    One fundamental property and limitation of grid based models is their inability to identify spatial details smaller than the grid cell size. While decades of work have gone into developing sub-grid treatments for clouds and land surface processes in climate models, the quantitative understanding of sub-grid processes and variability for aerosols and their precursors is much poorer. In this study, WRF-Chem is used to simulate the trace gases and aerosols over central Mexico during the 2006 MILAGRO field campaign, with multiple spatial resolutions and emission/terrain scenarios. Our analysis focuses on quantifying the sub-grid variability (SGV) of trace gases and aerosols within a typical global climate model grid cell, i.e. 75x75 km2. Our results suggest that a simulation with 3-km horizontal grid spacing adequately reproduces the overall transport and mixing of trace gases and aerosols downwind of Mexico City, while 75-km horizontal grid spacing is insufficient to represent local emission and terrain-induced flows along the mountain ridge, subsequently affecting the transport and mixing of plumes from nearby sources. Therefore, the coarse model grid cell average may not correctly represent aerosol properties measured over polluted areas. Probability density functions (PDFs) for trace gases and aerosols show that secondary trace gases and aerosols, such as O3, sulfate, ammonium, and nitrate, are more likely to have a relatively uniform probability distribution (i.e. smaller SGV) over a narrow range of concentration values. Mostly inert and long-lived trace gases and aerosols, such as CO and BC, are more likely to have broad and skewed distributions (i.e. larger SGV) over polluted regions. Over remote areas, all trace gases and aerosols are more uniformly distributed compared to polluted areas. Both CO and O3 SGV vertical profiles are nearly constant within the PBL during daytime, indicating that trace gases are very efficiently transported and mixed vertically by turbulence. But, simulated horizontal variability indicates that trace gases and aerosols are not well mixed horizontally in the PBL. During nighttime the SGV for trace gases is maximum at the surface, and quickly decreases with height. Unlike the trace gases, the SGV of BC and secondary aerosols reaches a maximum at the PBL top during the day. The SGV decreases with distance away from the polluted urban area, has a more rapid decrease for long-lived trace gases and aerosols than for secondary ones, and is greater during daytime than nighttime. The SGV of trace gases and aerosols is generally larger than for meteorological quantities. Emissions can account for up to 50% of the SGV over urban areas such as Mexico City during daytime for less-reactive trace gases and aerosols, such as CO and BC. The impact of emission spatial variability on SGV decays with altitude in the PBL and is insignificant in the free troposphere. The emission variability affects SGV more significantly during daytime (rather than nighttime) and over urban (rather than rural or remote) areas. The terrain, through its impact on meteorological fields such as wind and the PBL structure, affects dispersion and transport of trace gases and aerosols and their SGV.

  15. Lead carbonate scintillator materials

    DOE Patents [OSTI]

    Derenzo, S.E.; Moses, W.W.

    1991-05-14T23:59:59.000Z

    Improved radiation detectors containing lead carbonate or basic lead carbonate as the scintillator element are disclosed. Both of these scintillators have been found to provide a balance of good stopping power, high light yield and short decay constant that is superior to other known scintillator materials. The radiation detectors disclosed are favorably suited for use in general purpose detection and in medical uses. 3 figures.

  16. Carbon dioxide removal process

    DOE Patents [OSTI]

    Baker, Richard W.; Da Costa, Andre R.; Lokhandwala, Kaaeid A.

    2003-11-18T23:59:59.000Z

    A process and apparatus for separating carbon dioxide from gas, especially natural gas, that also contains C.sub.3+ hydrocarbons. The invention uses two or three membrane separation steps, optionally in conjunction with cooling/condensation under pressure, to yield a lighter, sweeter product natural gas stream, and/or a carbon dioxide stream of reinjection quality and/or a natural gas liquids (NGL) stream.

  17. Carbon based prosthetic devices

    SciTech Connect (OSTI)

    Devlin, D.J.; Carroll, D.W.; Barbero, R.S.; Archuleta, T. [Los Alamos National Lab., NM (US); Klawitter, J.J.; Ogilvie, W.; Strzepa, P. [Ascension Orthopedics (US); Cook, S.D. [Tulane Univ., New Orleans, LA (US). School of Medicine

    1998-12-31T23:59:59.000Z

    This is the final report of a one-year, Laboratory Directed Research and Development (LDRD) project at the Los Alamos National Laboratory (LANL). The project objective was to evaluate the use of carbon/carbon-fiber-reinforced composites for use in endoprosthetic devices. The application of these materials for the metacarpophalangeal (MP) joints of the hand was investigated. Issues concerning mechanical properties, bone fixation, biocompatibility, and wear are discussed. A system consisting of fiber reinforced materials with a pyrolytic carbon matrix and diamond-like, carbon-coated wear surfaces was developed. Processes were developed for the chemical vapor infiltration (CVI) of pyrolytic carbon into porous fiber preforms with the ability to tailor the outer porosity of the device to provide a surface for bone in-growth. A method for coating diamond-like carbon (DLC) on the articulating surface by plasma-assisted chemical vapor deposition (CVD) was developed. Preliminary results on mechanical properties of the composite system are discussed and initial biocompatibility studies were performed.

  18. Carbon Characterization Laboratory Report

    SciTech Connect (OSTI)

    David Swank; William Windes; D.C. Haggard; David Rohrbaugh; Karen Moore

    2009-03-01T23:59:59.000Z

    The newly completed Idaho National Laboratory (INL) Carbon Characterization Laboratory (CCL) is located in Lab-C20 of the Idaho National Laboratory Research Center. This laboratory was established under the Next Generation Nuclear Plant (NGNP) Project to support graphite research and development activities. The CCL is designed to characterize and test carbon-based materials such as graphite, carbon-carbon composites, and silicon-carbide composite materials. The laboratory is fully prepared to measure material properties for nonirradiated carbon-based materials. Plans to establish the laboratory as a radiological facility within the next year are definitive. This laboratory will be modified to accommodate irradiated materials, after which it can be used to perform material property measurements on both irradiated and nonirradiated carbon-based material. Instruments, fixtures, and methods are in place for preirradiation measurements of bulk density, thermal diffusivity, coefficient of thermal expansion, elastic modulus, Young’s modulus, Shear modulus, Poisson ratio, and electrical resistivity. The measurement protocol consists of functional validation, calibration, and automated data acquisition.

  19. Measurement of carbon capture efficiency and stored carbon leakage

    DOE Patents [OSTI]

    Keeling, Ralph F.; Dubey, Manvendra K.

    2013-01-29T23:59:59.000Z

    Data representative of a measured carbon dioxide (CO.sub.2) concentration and of a measured oxygen (O.sub.2) concentration at a measurement location can be used to determine whether the measured carbon dioxide concentration at the measurement location is elevated relative to a baseline carbon dioxide concentration due to escape of carbon dioxide from a source associated with a carbon capture and storage process. Optionally, the data can be used to quantify a carbon dioxide concentration increase at the first location that is attributable to escape of carbon dioxide from the source and to calculate a rate of escape of carbon dioxide from the source by executing a model of gas-phase transport using at least the first carbon dioxide concentration increase. Related systems, methods, and articles of manufacture are also described.

  20. Chlorofluorocarbons, Sulfur Hexafluoride, and Dissolved Permanent Gases in Ground Water from Selected Sites In and Near the Idaho National Engineering and Environmental Laboratory, Idaho, 1994 - 1997

    SciTech Connect (OSTI)

    Busenberg, E.; Plummer, L.N.; Bartholomay, R.C.; Wayland, J.E.

    1998-08-01T23:59:59.000Z

    From July 1994 through May 1997, the U.S. Geological Survey, in cooperations with the Department of Energy, sampled 86 wells completed in the Snake River Plain aquifer at and near the Idaho National Engineering and Environmental Laboratory (INEEL). The wells were sampled for a variety of constituents including one- and two-carbon halocarbons. Concentrations of dichlorodifluoromethane (CFC-12), trichlorofluoromethane (CFC-11), and trichlorotrifluororoethane (CFC-113) were determined. The data will be used to evaluate the ages of ground waters at INEEL. The ages of the ground water will be used to determine recharge rates, residence time, and travel time of water in the Snake River Plain aquifer in and near INEEL. The chromatograms of 139 ground waters are presented showing a large number of halomethanes, haloethanes, and haloethenes present in the ground waters underlying the INEEL. The chromatograms can be used to qualitatively evaluate a large number of contaminants at parts per trillion to parts per billion concentrations. The data can be used to study temporal and spatial distribution of contaminants in the Snake River Plain aquifer. Representative compressed chromatograms for all ground waters sampled in this study are available on two 3.5-inch high density computer disks. The data and the program required to decompress the data can be obtained from the U.S. Geological Survey office at Idaho Falls, Idaho. Sulfur hexafluoride (SF6) concentrations were measured in selected wells to determine the feasibility of using this environmental tracer as an age dating tool of ground water. Concentrations of dissolved nitrogen, argon, carbon dioxide, oxygen, and methane were measured in 79 ground waters. Concentrations of dissolved permanent gases are tabulated and will be used to evaluate the temperature of recharge of ground water in and near the INEEL.

  1. WESTCARB Carbon Atlas

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    The West Coast Regional Carbon Sequestration Partnership (known as WESTCARB) was established in Fall 2003. It is one of seven research partnerships co-funded by DOE to characterize regional carbon sequestration opportunities and conduct pilot-scale validation tests. The California Energy Commission manages WESTCARB and is a major co-funder. WESTCARB is characterizing the extent and capacity of geologic formations capable of storing CO2, known as sinks. Results are entered into a geographic information system (GIS) database, along with the location of major CO2-emitting point sources in each of the six WESTCARB states, enabling researchers and the public to gauge the proximity of candidate CO2 storage sites to emission sources and the feasibility of linking them via pipelines. Specifically, the WESTCARB GIS database (also known as the carbon atlas) stores layers of geologic information about potential underground storage sites, such as porosity and nearby fault-lines and aquifers. Researchers use these data, along with interpreted geophysical data and available oil and gas well logs to estimate the region's potential geologic storage capacity. The database also depicts existing pipeline routes and rights-of-way and lands that could be off-limits, which can aid the development of a regional carbon management strategy. The WESTCARB Carbon Atlas, which is accessible to the public, provides a resource for public discourse on practical solutions for regional CO2 management. A key WESTCARB partner, the Utah Automated Geographic Reference Center, has developed data serving procedures to enable the WESTCARB Carbon Atlas to be integrated with those from other regional partnerships, thereby supporting the U.S. Department of Energy's national carbon atlas, NATCARB

  2. Carbon Fuel Particles Used in Direct Carbon Conversion Fuel Cells

    DOE Patents [OSTI]

    Cooper, John F. (Oakland, CA); Cherepy, Nerine (Oakland, CA)

    2008-10-21T23:59:59.000Z

    A system for preparing particulate carbon fuel and using the particulate carbon fuel in a fuel cell. Carbon particles are finely divided. The finely dividing carbon particles are introduced into the fuel cell. A gas containing oxygen is introduced into the fuel cell. The finely divided carbon particles are exposed to carbonate salts, or to molten NaOH or KOH or LiOH or mixtures of NaOH or KOH or LiOH, or to mixed hydroxides, or to alkali and alkaline earth nitrates.

  3. Carbon fuel particles used in direct carbon conversion fuel cells

    DOE Patents [OSTI]

    Cooper, John F. (Oakland, CA); Cherepy, Nerine (Oakland, CA)

    2012-01-24T23:59:59.000Z

    A system for preparing particulate carbon fuel and using the particulate carbon fuel in a fuel cell. Carbon particles are finely divided. The finely dividing carbon particles are introduced into the fuel cell. A gas containing oxygen is introduced into the fuel cell. The finely divided carbon particles are exposed to carbonate salts, or to molten NaOH or KOH or LiOH or mixtures of NaOH or KOH or LiOH, or to mixed hydroxides, or to alkali and alkaline earth nitrates.

  4. Carbon fuel particles used in direct carbon conversion fuel cells

    DOE Patents [OSTI]

    Cooper, John F.; Cherepy, Nerine

    2012-10-09T23:59:59.000Z

    A system for preparing particulate carbon fuel and using the particulate carbon fuel in a fuel cell. Carbon particles are finely divided. The finely dividing carbon particles are introduced into the fuel cell. A gas containing oxygen is introduced into the fuel cell. The finely divided carbon particles are exposed to carbonate salts, or to molten NaOH or KOH or LiOH or mixtures of NaOH or KOH or LiOH, or to mixed hydroxides, or to alkali and alkaline earth nitrates.

  5. Carbon fuel particles used in direct carbon conversion fuel cells

    DOE Patents [OSTI]

    Cooper, John F. (Oakland, CA); Cherepy, Nerine (Oakland, CA)

    2011-08-16T23:59:59.000Z

    A system for preparing particulate carbon fuel and using the particulate carbon fuel in a fuel cell. Carbon particles are finely divided. The finely dividing carbon particles are introduced into the fuel cell. A gas containing oxygen is introduced into the fuel cell. The finely divided carbon particles are exposed to carbonate salts, or to molten NaOH or KOH or LiOH or mixtures of NaOH or KOH or LiOH, or to mixed hydroxides, or to alkali and alkaline earth nitrates.

  6. Chemically modified carbonic anhydrases useful in carbon capture systems

    DOE Patents [OSTI]

    Novick, Scott J; Alvizo, Oscar

    2013-10-29T23:59:59.000Z

    The present disclosure relates to chemically modified carbonic anhydrase polypeptides and soluble compositions, homogenous liquid formulations comprising them. The chemically modified carbonic anhydrase polypeptides have improved properties relative to the same carbonic anhydrase polypeptide that is not chemically modified including the improved properties of increased activity and/or stability in the presence of amine compounds, ammonia, or carbonate ion. The present disclosure also provides methods of preparing the chemically modified polypeptides and methods of using the chemically modified polypeptides for accelerating the absorption of carbon dioxide from a gas stream into a solution as well as for the release of the absorbed carbon dioxide for further treatment and/or sequestering.

  7. Chemically modified carbonic anhydrases useful in carbon capture systems

    DOE Patents [OSTI]

    Novick, Scott; Alvizo, Oscar

    2013-01-15T23:59:59.000Z

    The present disclosure relates to chemically modified carbonic anhydrase polypeptides and soluble compositions, homogenous liquid formulations comprising them. The chemically modified carbonic anhydrase polypeptides have improved properties relative to the same carbonic anhydrase polypeptide that is not chemically modified including the improved properties of increased activity and/or stability in the presence of amine compounds, ammonia, or carbonate ion. The present disclosure also provides methods of preparing the chemically modified polypeptides and methods of using the chemically modified polypeptides for accelerating the absorption of carbon dioxide from a gas stream into a solution as well as for the release of the absorbed carbon dioxide for further treatment and/or sequestering.

  8. Technical basis for storage of Zircaloy-clad spent fuel in inert gases

    SciTech Connect (OSTI)

    Johnson, A.B. Jr.; Gilbert, E.R.

    1983-09-01T23:59:59.000Z

    This report summarizes the technical bases to establish safe conditions for dry storage of Zircaloy-clad fuel. Dry storage of fuel with zirconium alloy cladding has been licensed in Canada, the Federal Republic of Germany, and Switzerland. In addition, dry storage demonstrations, hot cell tests, and modeling have been conducted using Zircaloy-clad fuel. The demonstrations have included irradiated boiling water reactor, pressurized heavy-water reactor, and pressurized water reactor (PWR) fuel assemblies. Irradiated fuel has been emplaced in and retrieved from metal casks, dry wells, silos, and a vault. Dry storage tests and demonstrations have involved {similar_to}5,000 fuel rods, and {similar_to}600 rods have been monitored during dry storage in inert gases with maximum cladding temperatures ranging from 50 to 570{sup 0}C. Although some tests and demonstrations are still in progress, there is currently no evidence that any rods exposed to inert gases have failed (one PWR rod exposed to an air cover gas failed at {similar_to}70{sup 0}C). Based on this favorable experience, it is concluded that there is sufficient information on fuel rod behavior, storage conditions, and potential cladding failure mechanisms to support licensing of dry storage in the United States. This licensing position includes a requirement for inert cover gases and a maximum cladding temperature guideline of 380{sup 0}C for Zircaloy-clad fuel. Using an inert cover gas assures that even if fuel with cladding defects were placed in dry storage, or if defects develop during storage, the defects would not propagate. Tests and demonstrations involving Zircaloy-clad rods and assemblies with maximum cladding temperatures above 400{sup 0}C are in progress. When the results from these tests have been evaluated, the viability of higher temperature limits should be examined. Acceptable conditions for storage in air and dry storage of consolidated fuel are issues yet to be resolved.

  9. Modelling of noble anaesthetic gases and high hydrostatic pressure effects in lipid bilayers

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Moskovitz, Yevgeny [Department of Chemistry, Middle Tennessee State University; Yang, Hui [Department of Chemistry, Middle Tennessee State University

    2015-01-01T23:59:59.000Z

    Our objective was to study molecular processes that might be responsible for inert gas narcosis and high-pressure nervous syndrome. The classical molecular dynamics trajectories (200 ns-long) of dioleoylphosphatidylcholine (DOPC) bilayers simulated by the Berger force field were evaluated for water and the atomic distribution of noble gases around DOPC molecules at a pressure range of 1 - 1000 bar and temperature of 310 Kelvin. Xenon and argon have been tested as model gases for general anesthetics, and neon has been investigated for distortions that are potentially responsible for neurological tremor at hyperbaric conditions. The analysis of stacked radial pair distribution functions of DOPC headgroup atoms revealed the explicit solvation potential of gas molecules, which correlates with their dimensions. The orientational dynamics of water molecules at the biomolecular interface should be considered as an influential factor; while excessive solvation effects appearing in the lumen of membrane-embedded ion channels could be a possible cause of inert gas narcosis. All the noble gases tested exhibit similar patterns of the order parameter for both DOPC acyl chains, which is opposite to the patterns found for the order parameter curve at high hydrostatic pressures in intact bilayers. This finding supports the ‘critical volume’ hypothesis of anesthesia pressure reversal. The irregular lipid headgroup-water boundary observed in DOPC bilayers saturated with neon in the pressure range of 1 - 100 bar could be associated with the possible manifestation of neurological tremor at the atomic scale. The non-immobilizer neon also demonstrated the highest momentum impact on the normal component of the DOPC diffusion coefficient representing monolayers undulations rate, which indicates enhanced diffusivity, rather than atom size, as the key factor.

  10. Modelling of noble anaesthetic gases and high hydrostatic pressure effects in lipid bilayers

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Moskovitz, Yevgeny; Yang, Hui

    2015-01-01T23:59:59.000Z

    Our objective was to study molecular processes that might be responsible for inert gas narcosis and high-pressure nervous syndrome. The classical molecular dynamics trajectories (200 ns-long) of dioleoylphosphatidylcholine (DOPC) bilayers simulated by the Berger force field were evaluated for water and the atomic distribution of noble gases around DOPC molecules at a pressure range of 1 - 1000 bar and temperature of 310 Kelvin. Xenon and argon have been tested as model gases for general anesthetics, and neon has been investigated for distortions that are potentially responsible for neurological tremor at hyperbaric conditions. The analysis of stacked radial pair distributionmore »functions of DOPC headgroup atoms revealed the explicit solvation potential of gas molecules, which correlates with their dimensions. The orientational dynamics of water molecules at the biomolecular interface should be considered as an influential factor; while excessive solvation effects appearing in the lumen of membrane-embedded ion channels could be a possible cause of inert gas narcosis. All the noble gases tested exhibit similar patterns of the order parameter for both DOPC acyl chains, which is opposite to the patterns found for the order parameter curve at high hydrostatic pressures in intact bilayers. This finding supports the ‘critical volume’ hypothesis of anesthesia pressure reversal. The irregular lipid headgroup-water boundary observed in DOPC bilayers saturated with neon in the pressure range of 1 - 100 bar could be associated with the possible manifestation of neurological tremor at the atomic scale. The non-immobilizer neon also demonstrated the highest momentum impact on the normal component of the DOPC diffusion coefficient representing monolayers undulations rate, which indicates enhanced diffusivity, rather than atom size, as the key factor.« less

  11. Sequestration of noble gases by H3+ in protoplanetary disks and outer solar system composition

    E-Print Network [OSTI]

    Olivier Mousis; Francoise Pauzat; Yves Ellinger; Cecilia Ceccarelli

    2007-09-23T23:59:59.000Z

    We study the efficiency of the noble gases sequestration by the ion H3+ in the form of XH3+ complexes (with X = argon, krypton or xenon) in gas phase conditions similar to those encountered during the cooling of protoplanetary disks, at the epoch of icy planetesimals formation. We show that XH3+ complexes form very stable structures in the gas phase and that their binding energies are much higher than those involved in the structures of X-H2O hydrates or pure X-X condensates. This implies that, in presence of H3+ ions, argon, krypton or xenon are likely to remain sequestrated in the form of XH3+ complexes embedded in the gas phase rather than forming ices during the cooling of protoplanetary disks. The amount of the deficiency depends on how much H3+ is available and efficient in capturing noble gases. In the dense gas of the mid-plane of solar nebula, H3+ is formed by the ionization of H2 from energetic particles, as those in cosmic rays or those ejected by the young Sun. Even using the largest estimate of the cosmic rays ionization rate, we compute that the H3+ abundance is two and three orders of magnitude lower than the xenon and krypton abundance, respectively. Estimating the ionization induced by the young Sun, on the other hand, is very uncertain but leaves the possibility to have enough H3+ to make krypton and xenon trapping efficent. Finally, additional source of H3+ formation may be provided by the presence of a nearby supernova, as discussed in the literature. Recent solar system observations show a deficiency of Ar, and, even more, of Kr and Xe in Titan and in comets. In this article, we consider the possibility that this deficiency is caused by the afore-mentioned process, namely trapping of those noble gases by H3+ ions in the solar nebula.

  12. activated carbon composites: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    T300: C strength 4340 steel, carbon-carbon composite, and Carbon-Silicon Carbide composite were tested to examine materials. MATERIALS AND DESIRED DATA Carbon-Carbon...

  13. ammonium carbonates: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    T300: C strength 4340 steel, carbon-carbon composite, and Carbon-Silicon Carbide composite were tested to examine materials. MATERIALS AND DESIRED DATA Carbon-Carbon...

  14. a537 carbon steel: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    T300: C strength 4340 steel, carbon-carbon composite, and Carbon-Silicon Carbide composite were tested to examine materials. MATERIALS AND DESIRED DATA Carbon-Carbon...

  15. americium carbonates: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    T300: C strength 4340 steel, carbon-carbon composite, and Carbon-Silicon Carbide composite were tested to examine materials. MATERIALS AND DESIRED DATA Carbon-Carbon...

  16. affecting carbon tetrachloride: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    T300: C strength 4340 steel, carbon-carbon composite, and Carbon-Silicon Carbide composite were tested to examine materials. MATERIALS AND DESIRED DATA Carbon-Carbon...

  17. Coherent spin mixing dynamics in thermal $^{87}$Rb spin-1 and spin-2 gases

    E-Print Network [OSTI]

    He, Xiaodong; Li, Xiaoke; Wang, Fudong; Xu, Zhifang; Wang, Dajun

    2015-01-01T23:59:59.000Z

    We study the non-equilibrium coherent spin mixing dynamics in ferromagnetic spin-1 and antiferromagnetic spin-2 thermal gases of ultracold $^{87}$Rb atoms. Long lasting spin population oscillations with magnetic field dependent resonances are observed in both cases. Our observations are well reproduced by Boltzmann equations of the Wigner distribution function. Compared to the equation of motion of spinor Bose-Einstein condensates, the only difference here is a factor of two increase in the spin-dependent interaction, which is confirmed directly in the spin-2 case by measuring the relation between the oscillation amplitude and the sample's density.

  18. Effective super Tonks-Girardeau gases as ground states of strongly attractive multicomponent fermions

    SciTech Connect (OSTI)

    Yin Xiangguo; Chen Shu [Institute of Physics, Chinese Academy of Sciences, Beijing 100190 (China); Guan Xiwen [Department of Theoretical Physics, Research School of Physics and Engineering, Australian National University, Canberra ACT 0200 (Australia); Batchelor, M. T. [Department of Theoretical Physics, Research School of Physics and Engineering, Australian National University, Canberra ACT 0200 (Australia); Mathematical Sciences Institute, Australian National University, Canberra ACT 0200 (Australia)

    2011-01-15T23:59:59.000Z

    In the strong interaction limit, attractive fermions with N-component hyperfine states in a one-dimensional waveguide form unbreakable bound cluster states. We demonstrate that the ground state of strongly attractive SU(N) Fermi gases can be effectively described by a super Tonks-Girardeau gaslike state composed of bosonic cluster states with strongly attractive cluster-cluster interaction for even N and a Fermi duality of a super Tonks-Girardeau gaslike state composed of fermionic cluster states with weakly interacting cluster-cluster p-wave interaction for odd N.

  19. Overview of the Flammability of Gases Generated in Hanford Waste Tanks

    SciTech Connect (OSTI)

    Mahoney, Lenna A.; Huckaby, James L.; Bryan, Samuel A.; Johnson, Gerald D.

    2000-07-19T23:59:59.000Z

    This report presents an overview of what is known about the flammability of the gases generated and retained in Hanford waste tanks in terms of the gas composition, flammability and detonability limits of the gas constituents, and availability of ignition sources. The intrinsic flammability (or non-flammability) of waste gas mixtures is one major determinant of whether a flammable region develops in the tank headspace; other factors are the rate, surface area, and volume of the release and the tank ventilation rate, which are not covered in this report.

  20. Monte Carlo simulation of the nuclear medium: Fermi gases, nuclei and the role of Pauli potentials

    E-Print Network [OSTI]

    M. A. Perez-Garcia

    2007-08-26T23:59:59.000Z

    The role of Pauli potentials in the semiclassical simulation of Fermi gases at low temperatures is investigated. An alternative Pauli potential to the usual bivariate Gaussian form by Dorso et al. is proposed. This new Pauli potential allows for a simultaneous good reproduction of not only the kinetic energy per particle but also the momentum distribution and the two-body correlation function. The reproduction of the binding energies in finite nuclei in the low and medium mass range is also analyzed. What is found is that given a reasonable short-range atractive nuclear interaction one can include correlation effects in a suitable chosen density dependent Pauli potential.

  1. Separation of rare gases and chiral molecules by selective binding in porous organic cages

    SciTech Connect (OSTI)

    Chen, Linjiang; Reiss, Paul S.; Chong, Samantha Y.; Holden, Daniel; Jelfs, Kim E.; Hasell, Tom; Little, Marc A.; Kewley, Adam; Briggs, Michael E.; Stephenson, Andrew; Thomas, K. M.; Armstrong, Jayne A.; Bell, Jon; Busto, Jose; Noel, Raymond; Liu, Jian; Strachan, Denis M.; Thallapally, Praveen K.; Cooper, Andrew I.

    2014-10-31T23:59:59.000Z

    Abstract: The rare gases krypton, xenon, and radon pose both an economic opportunity and a potential environmental hazard. Xenon is used in commercial lighting, medical imaging, and anesthesia, and can sell for $5,000 per kilogram. Radon, by contrast, Is naturally radioactive and the second largest cause of lung cancer, and radioactive xenon, 133Xe, was a major pollutant released In the Fukushima Daiichi Nuclear Power Plant disaster. We describe an organic cage molecule that can capture xenon and radon with unprecedented selectivity, suggesting new technologies for environmental monitoring, removal of pollutants, or the recovery of rare, valuable elements from air.

  2. Enhancement of NMR and MRI in the presence of hyperpolarized noble gases

    DOE Patents [OSTI]

    Pines, Alexander; Budinger, Thomas; Navon, Gil; Song, Yi-Qiao; Appelt, Stephan; Bifone, Angelo; Taylor, Rebecca; Goodson, Boyd; Seydoux, Roberto; Room, Toomas; Pietrass, Tanja

    2004-11-16T23:59:59.000Z

    The present invention relates generally to nuclear magnetic resonance (NMR) techniques for both spectroscopy and imaging. More particularly, the present invention relates to methods in which hyperpolarized noble gases (e.g., Xe and He) are used to enhance and improve NMR and MRI. Additionally, the hyperpolarized gas solutions of the invention are useful both in vitro and in vivo to study the dynamics or structure of a system. When used with biological systems, either in vivo or in vitro, it is within the scope of the invention to target the hyperpolarized gas and deliver it to specific regions within the system.

  3. Direct conversion of light hydrocarbon gases to liquid fuel. Final report No. 33

    SciTech Connect (OSTI)

    Kaplan, R.D.; Foral, M.J.

    1992-05-16T23:59:59.000Z

    Amoco oil Company, has investigated the direct, non-catalytic conversion of light hydrocarbon gases to liquid fuels (particularly methanol) via partial oxidation. The primary hydrocarbon feed used in these studies was natural gas. This report describes work completed in the course of our two-year project. In general we determined that the methanol yields delivered by this system were not high enough to make it economically attractive. Process variables studied included hydrocarbon feed composition, oxygen concentration, temperature and pressure effects, residence time, reactor design, and reactor recycle.

  4. Overview of the Flammability of Gases Generated in Hanford Waste Tanks

    SciTech Connect (OSTI)

    LA Mahoney; JL Huckaby; SA Bryan; GD Johnson

    2000-07-21T23:59:59.000Z

    This report presents an overview of what is known about the flammability of the gases generated and retained in Hanford waste tanks in terms of the gas composition, the flammability and detonability limits of the gas constituents, and the availability of ignition sources. The intrinsic flammability (or nonflammability) of waste gas mixtures is one major determinant of whether a flammable region develops in the tank headspace; other factors are the rate, surface area, volume of the release, and the tank ventilation rate, which are not covered in this report.

  5. Pressurized release of liquefied fuel gases (LNG and LPG). Topical report, May 1993-February 1996

    SciTech Connect (OSTI)

    Atallah, S.; Janardhan, A.

    1996-02-01T23:59:59.000Z

    This report is an important contribution to the behavior of pressurized liquefied gases when accidentally released into the atmosphere. LNG vehicle fueling stations and LPG storage facilities operate at elevated pressures. Accidental releases could result in rainout and the formation of an aerosol in the vapor cloud. These factors must be considered when estimating the extent of the hazard zone of the vapor cloud using a heavier-than-air gas dispersion model such as DEGADIS (or its Windows equivalent DEGATEC). The DOS program PREL has been incorporated in the Windows program LFGRISK.

  6. Changes in atmospheric gases during isobaric storage of beef packaged pre- and post-rigor

    E-Print Network [OSTI]

    Hoermann, Karen Lee

    1980-01-01T23:59:59.000Z

    of C mmittee o-Chairman o Committee !, ' '2s r Mem er Member H d fop t ~t August 1980 ABSTRACT Changes in Atmospheric Gases During Isobaric Storage of Beef Packaged Pre- and Post-Rigor. (August 1980) Karen Lee Hoermann, B. S. , Texas ASM... and support. Thanks are g1ven to Don Bernard, David Hill, Karen Tanksley, and Julie Vrana for the1r assistance 1n the analysis of the samples. For his statist1cal expertise, the author thanks Dr. Iti. C. Parr for h1s help in analysis of variance and covari...

  7. Carbon contamination topography analysis of EUV masks

    E-Print Network [OSTI]

    Fan, Y.-J.

    2010-01-01T23:59:59.000Z

    induced carbon contamination of extreme ultraviolet optics,"and A. Izumi. "Carbon contamination of EL'V mask: filmEffect of Carbon Contamination on the Printing Performance

  8. Carbon Trading Protocols for Geologic Sequestration

    E-Print Network [OSTI]

    Hoversten, Shanna

    2009-01-01T23:59:59.000Z

    H. , 2005, IPCC: Carbon Capture and Storage: Technical05CH11231. INTRODUCTION Carbon capture and storage (CCS)Development Mechanism CCS: Carbon Capture and Storage C02e:

  9. Sandia National Laboratories: Carbon Capture & Storage

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Carbon Capture & Storage High-Pressure and High-Temperature Neutron Reflectometry Cell for Solid-Fluid Interface Studies On February 21, 2013, in Carbon Capture, Carbon Capture &...

  10. ASSESSMENT OF HOUSEHOLD CARBON FOOTPRINT REDUCTION POTENTIALS

    E-Print Network [OSTI]

    Masanet, Eric

    2010-01-01T23:59:59.000Z

    of  American household carbon footprint. ” Ecological and  limitations) of carbon footprint estimates toward of the art in carbon footprint analyses for California, 

  11. On carbon footprints and growing energy use

    E-Print Network [OSTI]

    Oldenburg, C.M.

    2012-01-01T23:59:59.000Z

    On carbon footprints and growing energy use Curtis M.reductions in the carbon footprint of a growing organizationhis own organization's carbon footprint and answers this

  12. Carbon nanotubes : synthesis, characterization, and applications

    E-Print Network [OSTI]

    Deck, Christian Peter

    2009-01-01T23:59:59.000Z

    around Surface-Attached Carbon Nanotubes. Ind. Eng. Chem.the flexural rigidity of carbon nanotube ensembles. AppliedNanotechnology in Carbon Materials. Acta Metallurgica, 1997.

  13. Participatory Carbon Monitoring: Operational Guidance for National...

    Open Energy Info (EERE)

    Participatory Carbon Monitoring: Operational Guidance for National REDD+ Carbon Accounting Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Participatory Carbon...

  14. Carbon Chemistry in interstellar clouds

    E-Print Network [OSTI]

    Maryvonne Gerin; David Fosse; Evelyne Roueff

    2002-12-03T23:59:59.000Z

    We discuss new developments of interstellar chemistry, with particular emphasis on the carbon chemistry. We confirm that carbon chains and cycles are ubiquitous in the ISM and closely chemically related to ea ch other, and to carbon. Investigation of the carbon budget in shielded and UV illuminated gas shows that the inventory of interstellar molecules is not complete and more complex molecules with 4 or more carbon atoms must be present. Finally we discuss the consequences for the evolution of clouds and conclude that the ubiquitous presence of carbon chains and cycles is not a necessary consequence of a very young age for interstellar clouds.

  15. Carbon Dioxide Separation with Supported Ionic Liquid Membranes

    SciTech Connect (OSTI)

    Luebke, D.R.; Ilconich, J.B.; Myers, C.R.; Pennline, H.W.

    2007-04-01T23:59:59.000Z

    Supported liquid membranes are a class of materials that allow the researcher to utilize the wealth of knowledge available on liquid properties as a direct guide in the development of a capture technology. These membranes also have the advantage of liquid phase diffusivities higher than those observed in polymeric membranes which grant proportionally greater permeabilities. The primary shortcoming of the supported liquid membranes demonstrated in past research has been the lack of stability caused by volatilization of the transport liquid. Ionic liquids, which possess high carbon dioxide solubility relative to light gases such as hydrogen, are an excellent candidate for this type of membrane since they have negligible vapor pressure and are not susceptible to evaporation. A study has been conducted evaluating the use of several ionic liquids, including 1-hexyl-3-methyl-imidazolium bis(trifuoromethylsulfonyl)imide, 1-butyl-3-methyl-imidazolium nitrate, and 1-ethyl-3-methyl-imidazolium sulfate in supported ionic liquid membranes for the capture of carbon dioxide from streams containing hydrogen. In a joint project, researchers at the University of Notre Dame lent expertise in ionic liquid synthesis and characterization, and researchers at the National Energy Technology Laboratory incorporated candidate ionic liquids into supports and evaluated the resulting materials for membrane performance. Initial results have been very promising with carbon dioxide permeabilities as high as 950 barrers and significant improvements in carbon dioxide/hydrogen selectivity over conventional polymers at 37C and at elevated temperatures. Results include a comparison of the performance of several ionic liquids and a number of supports as well as a discussion of innovative fabrication techniques currently under development.

  16. Formation of rare earth carbonates using supercritical carbon dioxide

    DOE Patents [OSTI]

    Fernando, Quintus (Tucson, AZ); Yanagihara, Naohisa (Zacopan, MX); Dyke, James T. (Santa Fe, NM); Vemulapalli, Krishna (Tuscon, AZ)

    1991-09-03T23:59:59.000Z

    The invention relates to a process for the rapid, high yield conversion of select rare earth oxides or hydroxides, to their corresponding carbonates by contact with supercritical carbon dioxide.

  17. Carbon-particle generator

    DOE Patents [OSTI]

    Hunt, A.J.

    1982-09-29T23:59:59.000Z

    A method and apparatus whereby small carbon particles are made by pyrolysis of a mixture of acetylene carried in argon. The mixture is injected through a nozzle into a heated tube. A small amount of air is added to the mixture. In order to prevent carbon build-up at the nozzle, the nozzle tip is externally cooled. The tube is also elongated sufficiently to assure efficient pyrolysis at the desired flow rates. A key feature of the method is that the acetylene and argon, for example, are premixed in a dilute ratio, and such mixture is injected while cool to minimize the agglomeration of the particles, which produces carbon particles with desired optical properties for use as a solar radiant heat absorber.

  18. Global Biogeochemistry Models and Global Carbon Cycle Research at Lawrence Livermore National Laboratory

    SciTech Connect (OSTI)

    Covey, C; Caldeira, K; Guilderson, T; Cameron-Smith, P; Govindasamy, B; Swanston, C; Wickett, M; Mirin, A; Bader, D

    2005-05-27T23:59:59.000Z

    The climate modeling community has long envisioned an evolution from physical climate models to ''earth system'' models that include the effects of biology and chemistry, particularly those processes related to the global carbon cycle. The widely reproduced Box 3, Figure 1 from the 2001 IPCC Scientific Assessment schematically describes that evolution. The community generally accepts the premise that understanding and predicting global and regional climate change requires the inclusion of carbon cycle processes in models to fully simulate the feedbacks between the climate system and the carbon cycle. Moreover, models will ultimately be employed to predict atmospheric concentrations of CO{sub 2} and other greenhouse gases as a function of anthropogenic and natural processes, such as industrial emissions, terrestrial carbon fixation, sequestration, land use patterns, etc. Nevertheless, the development of coupled climate-carbon models with demonstrable quantitative skill will require a significant amount of effort and time to understand and validate their behavior at both the process level and as integrated systems. It is important to consider objectively whether the currently proposed strategies to develop and validate earth system models are optimal, or even sufficient, and whether alternative strategies should be pursued. Carbon-climate models are going to be complex, with the carbon cycle strongly interacting with many other components. Off-line process validation will be insufficient. As was found in coupled atmosphere-ocean GCMs, feedbacks between model components can amplify small errors and uncertainties in one process to produce large biases in the simulated climate. The persistent tropical western Pacific Ocean ''double ITCZ'' and upper troposphere ''cold pole'' problems are examples. Finding and fixing similar types of problems in coupled carbon-climate models especially will be difficult, given the lack of observations required for diagnosis and validation of biogeochemical processes.

  19. ISSUES IN EVALUATING CARBON SEQUESTRATION AND ATTRIBUTING CARBON CREDITS TO GRASSLAND RESTORATION EFFORTS

    E-Print Network [OSTI]

    Wisconsin at Madison, University of

    ISSUES IN EVALUATING CARBON SEQUESTRATION AND ATTRIBUTING CARBON CREDITS TO GRASSLAND RESTORATION examines biological carbon sequestration using a grassland restoration as a model system. Chapter 1 for biological carbon sequestration. In this analysis, we found that significantly greater soil carbon

  20. Method of removing hydrogen sulfide from gases utilizing a zinc oxide sorbent and regenerating the sorbent

    DOE Patents [OSTI]

    Jalan, Vinod M. (Concord, MA); Frost, David G. (Maynard, MA)

    1984-01-01T23:59:59.000Z

    A spent solid sorbent resulting from the removal of hydrogen sulfide from a fuel gas flow is regenerated with a steam-air mixture. The mixture of steam and air may also include additional nitrogen or carbon dioxide. The gas mixture contacts the spent sorbent containing metal sulfide at a temperature above 500.degree. C. to regenerate the sulfide to metal oxide or carbonate. Various metal species including the period four transition metals and the lanthanides are suitable sorbents that may be regenerated by this method. In addition, the introduction of carbon dioxide gas permits carbonates such as those of strontium, barium and calcium to be regenerated. The steam permits regeneration of spent sorbent without formation of metal sulfate. Moreover, the regeneration will proceed with low oxygen concentrations and will occur without the increase in temperature to minimize the risk of sintering and densification of the sorbent.

  1. Sequestration of noble gases by H3+ in protoplanetary disks and outer solar system composition

    E-Print Network [OSTI]

    Mousis, Olivier; Ellinger, Yves; Ceccarelli, Cecilia

    2007-01-01T23:59:59.000Z

    We study the efficiency of the noble gases sequestration by the ion H3+ in the form of XH3+ complexes (with X = argon, krypton or xenon) in gas phase conditions similar to those encountered during the cooling of protoplanetary disks, at the epoch of icy planetesimals formation. We show that XH3+ complexes form very stable structures in the gas phase and that their binding energies are much higher than those involved in the structures of X-H2O hydrates or pure X-X condensates. This implies that, in presence of H3+ ions, argon, krypton or xenon are likely to remain sequestrated in the form of XH3+ complexes embedded in the gas phase rather than forming ices during the cooling of protoplanetary disks. The amount of the deficiency depends on how much H3+ is available and efficient in capturing noble gases. In the dense gas of the mid-plane of solar nebula, H3+ is formed by the ionization of H2 from energetic particles, as those in cosmic rays or those ejected by the young Sun. Even using the largest estimate of t...

  2. Characterization of particles entrained in the effluent gases of an 18-inch AFBC

    SciTech Connect (OSTI)

    Anderson, R.J.; Childers, E.E.; Chidester, G.E.

    1983-02-01T23:59:59.000Z

    This experimental investigation was directed at measurements of the mass loading and size distribution of the particles entrained in the effluent gases of the Morgantown Energy Technology Center (METC) 18-inch, atmospheric pressure fluidized-bed combustor (AFBC). This information was required to aid in the continuing characterization of the AFBC, and to assess the efficiency or performance of an associated cleanup device. The particle-laden flow from the AFBC was introduced into a prototype granular-bed filter (GBF) designed for hot gas cleanup. In order to assess the efficiency of the GBF for particle removal, the mass loading and size distribution of particles contained in the cleaned gas emerging from the GBF were also determined. The effluent gases exit the AFBC at a nominal 1500/sup 0/F and a heavy particle loading (>1 g/scm). These conditions represent a harsh sampling environment. Filter samples obtained by extractive sampling formed the basis of the experimental information. Gravimetric and Coulter counter analyses were performed on each sample to provide mass loading and particle size data, respectively. Mass loadings of particles, as determined from filter samples collected at the inlet and outlet of the GBF, indicated particle removal efficiencies of about 80%. No significant variation in the particle removal efficiency was observed. Analysis of collected particulate samples showed no significant preferential removal of particles as a function of particle size. 2 figs., 1 tab.

  3. Particulate removal from high-temperature, high-pressure combustion gases

    SciTech Connect (OSTI)

    Henry, R.F.; Saxena, S.C.; Podolski, W.F.

    1983-10-01T23:59:59.000Z

    The adoption by utilities of coal-fired pressurized fluidized-bed/combined cycle combustion systems for electric power generation depends to a large extent on the development of an efficient and economic cleanup system for the high-temperature, high-pressure combustion gases. For adequate turbine protection, these gases must be sufficiently cleaned to bring particulate erosion and alkali vapor corrosion to a level acceptable to gas turbine manufacturers. At the same time, the total particulate content of the flue gas must be reduced to the limit set by the Environmental Protection Agency. To accomplish particulate removal from a dust-laden gas stream, a number of separation devices have been developed. These include conventional and augmented cyclones; porous metal, fiber, fabric, and ceramic filters, as well as fixed, moving, and fluidized-bed granular filters; and electrostatic precipitators. Several other novel separation devices have been proposed and developed to different degrees such as: contactors using molten salt, metal, or glass, dry scrubbers, acoustic agglomerators, as well as cyclones and granular-bed filters with external electrostatic or magnetic fields. Some of these separation devices in various combinations have been tested in process development units or in hot gas simulators by ANL, CPC, CURL, C-W, Exxon, GE, Westinghouse, etc. The results are discussed and evaluated for PFBC applications.

  4. JV Task 125-Mercury Measurement in Combustion Flue Gases Short Course

    SciTech Connect (OSTI)

    Dennis Laudal

    2008-09-30T23:59:59.000Z

    The short course, designed to train personnel who have an interest in measuring mercury in combustion flue gases, was held twice at the Drury Inn in Marion, Illinois. The short course helped to provide attendees with the knowledge necessary to avoid the many pitfalls that can and do occur when measuring mercury in combustion flue gases. The first short course, May 5-8, 2008, included both a classroom-type session and hands-on demonstration of mercury-sampling equipment. The hands-on demonstration of equipment was staged at Southern Illinois Power Cooperative. Not including the Illinois Clean Coal Institute and the U.S. Department of Energy project managers, there were 12 attendees. The second short course was conducted September 16-17, 2008, but only included the classroom portion of the course; 14 people attended. In both cases, lectures were provided on the various mercury measurement methods, and interaction between attendees and EERC research personnel to discuss specific mercury measurement problems was promoted. Overall, the response to the course was excellent.

  5. Simulations of greenhouse trace gases using the Los Alamos chemical tracer model

    SciTech Connect (OSTI)

    Kao, C.Y.J.; Morz, E. (Los Alamos National Lab., NM (United States)); Tie, X. (Scripps Institution of Oceanography, San Diego, CA (United States))

    1991-11-01T23:59:59.000Z

    Through three-dimensional global model studies on atmospheric composition and transport, we are improving our quantitative understanding of the origins and behavior of trace gases that affect Earth's radiative energy balance and climate. We will focus, in this paper, on the simulations of three individual trace gases including CFC-11, methyl chloroform, and methane. We first used our chemical tracer model to study the global distribution and trend of chemically inert CFC-11 observed by the Atmospheric Lifetime Experiment. The results show that the model has the ability to reproduce the time-series of the observations. The purpose of this CFC-11 simulation was to test the transport of the model. We then used to model introduce methyl chloroform into the atmosphere according to the known emission patterns and iteratively varied OH fields so that the observed concentrations of methyl chloroform from the observations could be simulated well. The rationale behind this approach is that the reaction with OH is the dominant sink for metyl chloroform and the transport of the model has been tested in the previous CFC-11 study. Finally, using the inferred OH distributions, we conducted a steady-state simulation to reproduce the current methane distribution. The general agreement between the modeled an observed methane surface concentrations has laid a foundation for the simulation of the transient increase of methane.

  6. Simulations of greenhouse trace gases using the Los Alamos chemical tracer model

    SciTech Connect (OSTI)

    Kao, C.Y.J.; Morz, E. [Los Alamos National Lab., NM (United States); Tie, X. [Scripps Institution of Oceanography, San Diego, CA (United States)

    1991-11-01T23:59:59.000Z

    Through three-dimensional global model studies on atmospheric composition and transport, we are improving our quantitative understanding of the origins and behavior of trace gases that affect Earth`s radiative energy balance and climate. We will focus, in this paper, on the simulations of three individual trace gases including CFC-11, methyl chloroform, and methane. We first used our chemical tracer model to study the global distribution and trend of chemically inert CFC-11 observed by the Atmospheric Lifetime Experiment. The results show that the model has the ability to reproduce the time-series of the observations. The purpose of this CFC-11 simulation was to test the transport of the model. We then used to model introduce methyl chloroform into the atmosphere according to the known emission patterns and iteratively varied OH fields so that the observed concentrations of methyl chloroform from the observations could be simulated well. The rationale behind this approach is that the reaction with OH is the dominant sink for metyl chloroform and the transport of the model has been tested in the previous CFC-11 study. Finally, using the inferred OH distributions, we conducted a steady-state simulation to reproduce the current methane distribution. The general agreement between the modeled an observed methane surface concentrations has laid a foundation for the simulation of the transient increase of methane.

  7. Molecular formations in ultracold mixtures of interacting and noninteracting atomic gases

    E-Print Network [OSTI]

    T. Nishimura; A. Matsumoto; H. Yabu

    2008-08-06T23:59:59.000Z

    Atom-molecule equilibrium for molecular formation processes is discussed for boson-fermion, fermion-fermion, and boson-boson mixtures of ultracold atomic gases in the framework of quasichemical equilibrium theory. After presentation of the general formulation, zero-temperature phase diagrams of the atom-molecule equilibrium states are calculated analytically; molecular, mixed, and dissociated phases are shown to appear for the change of the binding energy of the molecules. The temperature dependences of the atom or molecule densities are calculated numerically, and finite-temperature phase structures are obtained of the atom-molecule equilibrium in the mixtures. The transition temperatures of the atom or molecule Bose-Einstein condensations are also evaluated from these results. Quantum-statistical deviations of the law of mass action in atom-molecule equilibrium, which should be satisfied in mixtures of classical Maxwell-Boltzmann gases, are calculated, and the difference in the different types of quantum-statistical effects is clarified. Mean-field calculations with interparticle interactions (atom-atom, atom-molecule, and molecule-molecule) are formulated, where interaction effects are found to give the linear density-dependent term in the effective molecular binding energies. This method is applied to calculations of zero-temperature phase diagrams, where new phases with coexisting local-equilibrium states are shown to appear in the case of strongly repulsive interactions.

  8. Ultrahard carbon nanocomposite films

    SciTech Connect (OSTI)

    SIEGAL,MICHAEL P.; TALLANT,DAVID R.; PROVENCIO,PAULA P.; OVERMYER,DONALD L.; SIMPSON,REGINA L.; MARTINEZ-MIRANDA,L.J.

    2000-01-27T23:59:59.000Z

    Modest thermal annealing to 600 C of diamondlike amorphous-carbon (a-C) films grown at room temperature results in the formation of carbon nanocomposites with hardness similar to diamond. These nanocomposite films consist of nanometer-sized regions of high density a-C embedded in an a-C matrix with a reduced density of 5--10%. The authors report on the evolution of density and bonding topologies as a function of annealing temperature. Despite a decrease in density, film hardness actually increases {approximately} 15% due to the development of the nanocomposite structure.

  9. Modifying the Soil and Water Assessment Tool to Simulate Cropland Carbon Flux: Model Development and Initial Evaluation

    SciTech Connect (OSTI)

    Zhang, Xuesong; Izaurralde, Roberto C.; Arnold, Jeffrey; Williams, Jimmy R.; Srinivasan, Raghavan

    2013-10-01T23:59:59.000Z

    Climate change is one of the most compelling modern issues and has important implications for almost every aspect of natural and human systems. The Soil and Water Assessment Tool (SWAT) model has been applied worldwide to support sustainable land and water management in a changing climate. However, the inadequacies of the existing carbon algorithm in SWAT limit its application in assessing impacts of human activities on CO2 emission, one important source of greenhouse gases (GHGs) that traps heat in the earth system and results in global warming. In this research, we incorporate a revised version of the CENTURY carbon model into SWAT to describe dynamics of soil organic matter (SOM)- residue and simulate land-atmosphere carbon exchange.

  10. Low Cost Carbon Fiber Production Carbon Fiber Manufacturing Cost Modeling

    E-Print Network [OSTI]

    to bond with composite matrix material. It is important that a carbon fiber manufacturing cost model manufactured with carbon fiber as opposed to traditional materials such as steel, automotive parts are able associated with both the manufacture of carbon fibers themselves as well as their composites. Traditional

  11. China Energy Databook -- User Guide and Documentation, Version 7.0

    E-Print Network [OSTI]

    Fridley, Ed., David

    2008-01-01T23:59:59.000Z

    Shares Country China India Japan USA Russian Federation Solid Chapter 9, International Comparisons Electricity Non-hydro renewable China Energy

  12. Irradiation Stability of Carbon Nanotubes 

    E-Print Network [OSTI]

    Aitkaliyeva, Assel

    2010-01-14T23:59:59.000Z

    Ion irradiation of carbon nanotubes is a tool that can be used to achieve modification of the structure. Irradiation stability of carbon nanotubes was studied by ion and electron bombardment of the samples. Different ion ...

  13. Sensor applications of carbon nanotubes

    E-Print Network [OSTI]

    Rushfeldt, Scott I

    2005-01-01T23:59:59.000Z

    A search of published research on sensing mechanisms of carbon nanotubes was performed to identify applications in which carbon nanotubes might improve on current sensor technologies, in either offering improved performance, ...

  14. First Proof of Ferromagnetic Carbon

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Proof of Ferromagnetic Carbon Print Although it has long been suspected that carbon belongs on the short list of materials that can be magnetic at room temperature, attempts to...

  15. Large Magnetization at Carbon Surfaces

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Large Magnetization at Carbon Surfaces Print From organic matter to pencil lead, carbon is a versatile element. Now, another use has been found: magnets. One would not expect pure...

  16. Carbon nanotubes: synthesis and functionalization 

    E-Print Network [OSTI]

    Andrews, Robert

    2007-01-01T23:59:59.000Z

    conditions were then used as the basis of several comparative CVD experiments showing that the quality of nanotubes and the yield of carbon depended on the availability of carbon to react. The availability could be controlled by the varying concentration...

  17. First Proof of Ferromagnetic Carbon

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    First Proof of Ferromagnetic Carbon Print Although it has long been suspected that carbon belongs on the short list of materials that can be magnetic at room temperature, attempts...

  18. The Midwest Regional Carbon Sequestration Partnership (MRCSP)

    SciTech Connect (OSTI)

    James J. Dooley; Robert Dahowski; Casie Davidson

    2005-12-01T23:59:59.000Z

    This final report summarizes the Phase I research conducted by the Midwest regional Carbon Sequestration Partnership (MRCSP). The Phase I effort began in October 2003 and the project period ended on September 31, 2005. The MRCSP is a public/private partnership led by Battelle with the mission of identifying the technical, economic, and social issues associated with implementation of carbon sequestration technologies in its seven state geographic region (Indiana, Kentucky, Maryland, Michigan, Ohio, Pennsylvania, and West Virginia) and identifying viable pathways for their deployment. It is one of seven partnerships that together span most of the U.S. and parts of Canada that comprise the U.S. Department of Energy's (DOE's) Regional Carbon Sequestration Program led by DOE's national Energy Technology Laboratory (NETL). The MRCSP Phase I research was carried out under DOE Cooperative Agreement No. DE-FC26-03NT41981. The total value of Phase I was $3,513,513 of which the DOE share was $2,410,967 or 68.62%. The remainder of the cost share was provided in varying amounts by the rest of the 38 members of MRCSP's Phase I project. The next largest cost sharing participant to DOE in Phase I was the Ohio Coal Development Office within the Ohio Air Quality Development Authority (OCDO). OCDO's contribution was $100,000 and was contributed under Grant Agreement No. CDO/D-02-17. In this report, the MRCSP's research shows that the seven state MRCSP region is a major contributor to the U. S. economy and also to total emissions of CO2, the most significant of the greenhouse gases thought to contribute to global climate change. But, the research has also shown that the region has substantial resources for sequestering carbon, both in deep geological reservoirs (geological sequestration) and through improved agricultural and land management practices (terrestrial sequestration). Geological reservoirs, especially deep saline reservoirs, offer the potential to permanently store CO2 for literally 100s of years even if all the CO2 emissions from the region's large point sources were stored there, an unlikely scenario under any set of national carbon emission mitigation strategies. The terrestrial sequestration opportunities in the region have the biophysical potential to sequester up to 20% of annual emissions from the region's large point sources of CO2. This report describes the assumptions made and methods employed to arrive at the results leading to these conclusions. It also describes the results of analyses of regulatory issues in the region affecting the potential for deployment of sequestration technologies. Finally, it describes the public outreach and education efforts carried out in Phase I including the creation of a web site dedicated to the MRCSP at www.mrcsp.org.

  19. 14 April 2001 tmospheric carbon dioxide

    E-Print Network [OSTI]

    Teskey, Robert O.

    emissions is through increased carbon sequestration into forests. In a large-scale assessment, Birdsey- ing carbon sequestration in southern forests. Carbon sequestration via southern pine forests may policy commitments. Keywords: carbon sequestration; southern pine forests ABSTRACT MEETING GLOBAL POLICY

  20. Development of a Method for Measuring Carbon Balance in Chemical Sequestration of CO2

    SciTech Connect (OSTI)

    Cheng, Zhongxian; Pan, Wei-Ping; Riley, John T.

    2006-09-09T23:59:59.000Z

    Anthropogenic CO2 released from fossil fuel combustion is a primary greenhouse gas which contributes to “global warming.” It is estimated that stationary power generation contributes over one-third of total CO2 emissions. Reducing CO2 in the atmosphere can be accomplished either by decreasing the rate at which CO2 is emitted into the atmosphere or by increasing the rate at which it is removed from it. Extensive research has been conducted on determining a fast and inexpensive method to sequester carbon dioxide. These methods can be classified into two categories, CO2 fixation by natural sink process for CO2, or direct CO2 sequestration by artificial processes. In direct sequestration, CO2 produced from sources such as coal-fired power plants, would be captured from the exhausted gases. CO2 from a combustion exhaust gas is absorbed with an aqueous ammonia solution through scrubbing. The captured CO2 is then used to synthesize ammonium bicarbonate (ABC or NH4HCO3), an economical source of nitrogen fertilizer. In this work, we studied the carbon distribution after fertilizer is synthesized from CO2. The synthesized fertilizer in laboratory is used as a “CO2 carrier” to “transport” CO2 from the atmosphere to crops. After biological assimilation and metabolism in crops treated with ABC, a considerable amount of the carbon source is absorbed by the plants with increased biomass production. The majority of the unused carbon source percolates into the soil as carbonates, such as calcium carbonate (CaCO3) and magnesium carbonate (MgCO3). These carbonates are environmentally benign. As insoluble salts, they are found in normal rocks and can be stored safely and permanently in soil. This investigation mainly focuses on the carbon distribution after the synthesized fertilizer is applied to soil. Quantitative examination of carbon distribution in an ecosystem is a challenging task since the carbon in the soil may come from various sources. Therefore synthesized 14C tagged NH4HCO3 (ABC) was used. Products of ammonium bicarbonate (ABC) or long-term effect ammonium bicarbonate (LEABC) were tagged with 14C when they were synthesized in the laboratory. An indoor greenhouse was built and wheat was chosen as the plant to study in this ecosystem. The investigated ecosystem consists of plant (wheat), soils with three different pH values (alkaline, neutral and acid), and three types of underground water (different Ca2+ and Mg2+ concentrations). After biological assimilation and metabolism in wheat receiving ABC or LEABC, it was found that a considerable amount (up to 10%) of the carbon source is absorbed by the wheat with increased biomass production. The majority of the unused carbon source (up to 76%) percolated into the soil as carbonates, such as environmentally benign calcium carbonate (CaCO3). Generally speaking, alkaline soil has a higher capability to capture and store carbon. For the same soil, there is no apparent difference in carbon capturing capability between ABC fertilizer and LEABC fertilizer. These findings answer the question how carbon is distributed after synthesized fertilizer is applied into the ecosystem. In addition, a separate post-experiment on fertilizer carbon forms that exist in the soil was made. It was found that the up to 88% of the trapped carbon exists in the form of insoluble salts (i.e., CaCO3) in alkaline soils. This indicates that alkaline soil has a greater potential for storing carbon after the use of the synthesized fertilizer from exhausted CO2.