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Note: This page contains sample records for the topic "non-methane hydrocarbons nmhc" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


1

Hydrocarbon sensors and materials therefor  

DOE Patents [OSTI]

An electrochemical hydrocarbon sensor and materials for use in sensors. A suitable proton conducting electrolyte and catalytic materials have been found for specific application in the detection and measurement of non-methane hydrocarbons. The sensor comprises a proton conducting electrolyte sandwiched between two electrodes. At least one of the electrodes is covered with a hydrocarbon decomposition catalyst. Two different modes of operation for the hydrocarbon sensors can be used: equilibrium versus non-equilibrium measurements and differential catalytic. The sensor has particular application for on-board monitoring of automobile exhaust gases to evaluate the performance of catalytic converters. In addition, the sensor can be utilized in monitoring any process where hydrocarbons are exhausted, for instance, industrial power plants. The sensor is low cost, rugged, sensitive, simple to fabricate, miniature, and does not suffer cross sensitivities.

Pham, Ai Quoc (San Jose, CA); Glass, Robert S. (Livermore, CA)

2000-01-01T23:59:59.000Z

2

Apparatus for hydrocarbon extraction  

DOE Patents [OSTI]

Systems and methods for hydrocarbon extraction from hydrocarbon-containing material. Such systems and methods relate to extracting hydrocarbon from hydrocarbon-containing material employing a non-aqueous extractant. Additionally, such systems and methods relate to recovering and reusing non-aqueous extractant employed for extracting hydrocarbon from hydrocarbon-containing material.

Bohnert, George W.; Verhulst, Galen G.

2013-03-19T23:59:59.000Z

3

Naphthenic hydrocarbons  

SciTech Connect (OSTI)

An important type of naphthenic hydrocarbons is the monocyclic type, (k/sub 2/, 0, 0). In this instance the number of carbon atoms, n = k/sub 2/, and a formula, C/sub n/H/sub 2n/, can be written where H/C = 2. The value n can vary from 2 to infinity. In the case of n = 2, it is ethylene (I) (2-membered cyclic ring); n = 3, cyclopropane (II) (3-membered cyclic ring); n = 4, cyclobutane (III) (4-membered cyclic ring); etc. If the monocyclic naphthenic is planar, then the bond angle theta can be expressed as theta = (1 - 2/n)..pi.. where n is the number of carbon atoms. However, the tetrahedron angle of the carbon atom being phi = cos/sup -1/ (- 1/3).

Yen, T.F.; Kuo, J.F.; Chilingarian, G.V.

1987-01-01T23:59:59.000Z

4

EDDY RESOLVING NUTRIENT ECODYNAMICS IN THE GLOBAL PARALLEL OCEAN PROGRAM AND CONNECTIONS WITH TRACE GASES IN THE SULFUR, HALOGEN AND NMHC CYCLES  

SciTech Connect (OSTI)

Ecodynamics and the sea-air transfer of climate relevant trace gases are intimately coupled in the oceanic mixed layer. Ventilation of species such as dimethyl sulfide and methyl bromide constitutes a key linkage within the earth system. We are creating a research tool for the study of marine trace gas distributions by implementing coupled ecology-gas chemistry in the high resolution Parallel Ocean Program (POP). The fundamental circulation model is eddy resolving, with cell sizes averaging 0.15 degree (lat/long). Here we describe ecochemistry integration. Density dependent mortality and iron geochemistry have enhanced agreement with chlorophyll measurements. Indications are that dimethyl sulfide production rates must be adjusted for latitude dependence to match recent compilations. This may reflect the need for phytoplankton to conserve nitrogen by favoring sulfurous osmolytes. Global simulations are also available for carbonyl sulfide, the methyl halides and for nonmethane hydrocarbons. We discuss future applications including interaction with atmospheric chemistry models, high resolution biogeochemical snapshots and the study of open ocean fertilization.

S. CHU; S. ELLIOTT

2000-08-01T23:59:59.000Z

5

NATURAL MARINE HYDROCARBON SEEPAGE  

E-Print Network [OSTI]

affects ocean chemistry (Dando and Hovland, 1992) and provides a natural source of petroleum pollution the water column above submarine vents, plumes of hydrocarbon gas bubbles act as acoustic scattering targets

Luyendyk, Bruce

6

Hydrocarbon desulfurization process  

SciTech Connect (OSTI)

A process is described for converting a sour hydrocarbon feedstock having a relatively high sulfur content to a hydrocarbon product having a relatively low sulfur content comprising the steps of: (a) hydrodesulfurizing the feedstock having a relatively high sulfur contact with hydrogen to produce the hydrocarbon product having a relatively low sulfur content and hydrogen sulfide gas; (b) contacting the hydrogen sulfide gas with an anthraquinone dissolved in a polar organic solvent having a polarity greater than about 3 Debye units to produce sulfur and an anthrahydroquinone in the solvent; (c) regenerating the anthraquinone from the anthrahydroquinone upon contact with air to produce the anthraquinone and hydrogen peroxide; (d) recycling the anthraquinone to step (b); (e) reducing the hydrogen peroxide to oxygen and water; (f) partially oxidizing a hydrocarbon fuel with the oxygen to produce carbon dioxide and hydrogen; and (g) recycling the hydrogen to step (a).

Plummer, M.A.; Zimmerman, C.C. Jr.

1986-04-08T23:59:59.000Z

7

Membrane separation of hydrocarbons  

DOE Patents [OSTI]

Mixtures of heavy oils and light hydrocarbons may be separated by passing the mixture over a polymeric membrane which comprises a polymer capable of maintaining its integrity in the presence of hydrocarbon compounds at temperature ranging from about ambient to about 100.degree. C. and pressures ranging from about 50 to about 1000 psi. The membranes which possess pore sizes ranging from about 10 to about 500 Angstroms are cast from a solvent solution and recovered.

Funk, Edward W. (Highland Park, IL); Kulkarni, Sudhir S. (Hoffman Estates, IL); Chang, Y. Alice (Des Plaines, IL)

1986-01-01T23:59:59.000Z

8

Dispersant solutions for dispersing hydrocarbons  

DOE Patents [OSTI]

A dispersant solution includes a hydrocarbon dispersing solution derived from a bacterium from ATCC 75527, ATCC 75529, or ATCC 55638.

Tyndall, Richard L. (Clinton, TN)

1997-01-01T23:59:59.000Z

9

Dispersant solutions for dispersing hydrocarbons  

DOE Patents [OSTI]

A dispersant solution includes a hydrocarbon dispersing solution derived from a bacterium from ATCC 75527, ATCC 75529, or ATCC 55638.

Tyndall, R.L.

1997-03-11T23:59:59.000Z

10

Hydrocarbon cracking catalyst  

SciTech Connect (OSTI)

This patent describes a catalyst composition for cracking hydrocarbons to maximize gasoline comprising: rare earth exchanged ''Y'' crystalline faujasite dispersed in a clay containing matrix material; and which has been subsequently further ion exchanged to contain 0.20 to 3.0 wt% yttrium, calculated as the oxide, whereby the yttrium is chemically combined in the catalyst composition.

Lochow, C.F.; Kovacs, D.B.

1988-12-27T23:59:59.000Z

11

Membrane separation of hydrocarbons  

DOE Patents [OSTI]

Mixtures of heavy oils and light hydrocarbons may be separated by passing the mixture through a polymeric membrane. The membrane which is utilized to effect the separation comprises a polymer which is capable of maintaining its integrity in the presence of hydrocarbon compounds and which has been modified by being subjected to the action of a sulfonating agent. Sulfonating agents which may be employed will include fuming sulfuric acid, chlorosulfonic acid, sulfur trioxide, etc., the surface or bulk modified polymer will contain a degree of sulfonation ranging from about 15 to about 50%. The separation process is effected at temperatures ranging from about ambient to about 100.degree. C. and pressures ranging from about 50 to about 1000 psig.

Chang, Y. Alice (Des Plaines, IL); Kulkarni, Sudhir S. (Hoffman Estates, IL); Funk, Edward W. (Highland Park, IL)

1986-01-01T23:59:59.000Z

12

Direct hydrocarbon fuel cells  

DOE Patents [OSTI]

The direct electrochemical oxidation of hydrocarbons in solid oxide fuel cells, to generate greater power densities at lower temperatures without carbon deposition. The performance obtained is comparable to that of fuel cells used for hydrogen, and is achieved by using novel anode composites at low operating temperatures. Such solid oxide fuel cells, regardless of fuel source or operation, can be configured advantageously using the structural geometries of this invention.

Barnett, Scott A.; Lai, Tammy; Liu, Jiang

2010-05-04T23:59:59.000Z

13

Emissions Benefits From Renewable Fuels and Other Alternatives for Heavy-Duty Vehicles  

E-Print Network [OSTI]

natural gas engines are predominately unburned fuel, therefore, the non-methane hydrocarbon fraction of THC exhaust emissions typically trends

Hajbabaei, Maryam

2013-01-01T23:59:59.000Z

14

Hydrocarbon Observations and Ozone Production Rates in Western Houston During the Texas 2000 Air Quality Study  

SciTech Connect (OSTI)

Measurements of total non-methane hydrocarbon in whole air canisters collected from the top of a skyscraper on the western edge of Houston, Texas are summarized with an emphasis on samples collected during the passage of plumes of O{sub 3} and the associated rapid increase in the mixing ratio of this species. The back-trajectories associated with these events showed a pronounced deceleration of air parcels over central and western Houston and were not necessarily associated with direct passage over the petrochemical plants located in the heavily industrialized eastern part of Houston. As a result of the time these air parcels spent over the central and western parts of Houston, their VOC mix and associated chemical production rates were expected to differ from similar observations made over eastern Houston from aircraft sampling at low altitudes. Although periods of high O{sub 3} in the western part of the city were closely associated with light alkenes, these same observations show isoprene to make a significant contribution to the total VOC reactivity in the early afternoon (the start of peak photochemical activity) in contrast to observations made east of our sampling site that found the reactivity to be dominated by anthropogenic species. By initializing a 0-dimensional chemical kinetic model with observations made at the Williams Tower, we find that the ozone production efficiency scaled linearly to the ratio of total hydrocarbons and NO{sub x}, with an average OPE of 7.2, ranging from 2.3 to 16.9; these values are smaller than those reported in eastern Houston, suggesting a strong gradient in photochemical productivity across the city.

Berkowitz, Carl M.; Spicer, Chet W.; Doskey, Paul V.

2005-06-01T23:59:59.000Z

15

Process for separating an ethylenically unsaturated hydrocarbon from a hydrocarbon mixture  

SciTech Connect (OSTI)

A process is described for separating an ethylenically unsaturated hydrocarbon from a hydrocarbon mixture characterized by: (a) distilling a hydrocarbon mixture containing the unsaturated hydrocarbon with an N-(aminoalkyl) piperazine; and (b) separating the amine/hydrocarbon mixture into at least two factions, one of which contains the amine and the unsaturated hydrocarbon.

vanEijl, A.T.

1986-06-24T23:59:59.000Z

16

Hydrocarbon conversion catalysts  

SciTech Connect (OSTI)

This patent describes a process for hydrocracking hydrocarbon oils into products of lower average molecular weight and lower average boiling point. It comprises contacting a hydrocarbon oil at a temperature between 250{sup 0}C and 500{sup 0}C and a pressure up to 300 bar in the presence of hydrogen with a catalyst consisting essentially of a Y zeolite modified to have a unit cell size below 24.35A, a water absorption capacity (at 25{sup 0}C and a rho/rho/sub o/ value of 0.2) of at least 8% by weight of the zeolite and a pore volume of at least 0.25 ml/g wherein between 10% and 60% of the total pore volume is made up of pores having a diameter of at least 8 nm; an alumina binder and at least one hydrogenation component selected from the group consisting of a Group VI metal, a Group VIII metal and mixtures thereof.

Hoek, A.; Huizinga, T.; Maxwell, I.E.

1989-08-15T23:59:59.000Z

17

Process for recovering hydrocarbons from a hydrocarbon-bearing formation  

SciTech Connect (OSTI)

A method is described for transporting heavy crude oil through a pipeline which involves introducing into a pipeline or well-bore with the viscous hydrocarbons an aqueous solution containing (1) a sulfonate surfactant, (2) a rosin soap or a naphthenic acid soap and, optionally (3) coupling agent whereby there is spontaneously formed a low viscosity, salt tolerant, oil-in-water emulsion. Also disclosed is a method of recovery of hydrocarbons from a hydrocarbon bearing formation employing an aqueous solution containing (1) a sulfonate surfactant, (2) a rosin soap or a naphthenic acid soap and, optionally (3) a coupling agent.

Alston, R.B.; Braden, W.B.; Flournoy, K.H.

1980-03-11T23:59:59.000Z

18

Enrichment of light hydrocarbon mixture  

SciTech Connect (OSTI)

Light hydrocarbon enrichment is accomplished using a vertically oriented distillation column having a plurality of vertically oriented, nonselective micro/mesoporous hollow fibers. Vapor having, for example, both propylene and propane is sent upward through the distillation column in between the hollow fibers. Vapor exits neat the top of the column and is condensed to form a liquid phase that is directed back downward through the lumen of the hollow fibers. As vapor continues to ascend and liquid continues to countercurrently descend, the liquid at the bottom of the column becomes enriched in a higher boiling point, light hydrocarbon (propane, for example) and the vapor at the top becomes enriched in a lower boiling point light hydrocarbon (propylene, for example). The hollow fiber becomes wetted with liquid during the process.

Yang; Dali (Los Alamos, NM); Devlin, David (Santa Fe, NM); Barbero, Robert S. (Santa Cruz, NM); Carrera, Martin E. (Naperville, IL); Colling, Craig W. (Warrenville, IL)

2010-08-10T23:59:59.000Z

19

Enrichment of light hydrocarbon mixture  

DOE Patents [OSTI]

Light hydrocarbon enrichment is accomplished using a vertically oriented distillation column having a plurality of vertically oriented, nonselective micro/mesoporous hollow fibers. Vapor having, for example, both propylene and propane is sent upward through the distillation column in between the hollow fibers. Vapor exits neat the top of the column and is condensed to form a liquid phase that is directed back downward through the lumen of the hollow fibers. As vapor continues to ascend and liquid continues to countercurrently descend, the liquid at the bottom of the column becomes enriched in a higher boiling point, light hydrocarbon (propane, for example) and the vapor at the top becomes enriched in a lower boiling point light hydrocarbon (propylene, for example). The hollow fiber becomes wetted with liquid during the process.

Yang, Dali (Los Alamos, NM); Devlin, David (Santa Fe, NM); Barbero, Robert S. (Santa Cruz, NM); Carrera, Martin E. (Naperville, IL); Colling, Craig W. (Warrenville, IL)

2011-11-29T23:59:59.000Z

20

Biological enhancement of hydrocarbon extraction  

DOE Patents [OSTI]

A method of microbial enhanced oil recovery for recovering oil from an oil-bearing rock formation is provided. The methodology uses a consortium of bacteria including a mixture of surfactant producing bacteria and non-surfactant enzyme producing bacteria which may release hydrocarbons from bitumen containing sands. The described bioprocess can work with existing petroleum recovery protocols. The consortium microorganisms are also useful for treatment of above oil sands, ground waste tailings, subsurface oil recovery, and similar materials to enhance remediation and/or recovery of additional hydrocarbons from the materials.

Brigmon, Robin L. (North Augusta, SC); Berry, Christopher J. (Aiken, SC)

2009-01-06T23:59:59.000Z

Note: This page contains sample records for the topic "non-methane hydrocarbons nmhc" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Observations of nonmethane hydrocarbons and oxygenated volatile organic compounds at a rural site in the southeastern United States  

SciTech Connect (OSTI)

Measurements of an extensive range of nonmethane hydrocarbons (NMHCs) including alkanes, alkenes, and aromatics, and oxygenated volatile organic compounds (OVOCs) including alcohols, ketones, and aldehydes were conducted for several weeks during the summer of 1995 as part of the Southern Oxidants Study (SOS) at a rural experimental site (Youth, Inc.) 32 km southeast of Nashville, Tennessee, in the southeastern United States. These measurements were conducted to (1) determine the absolute magnitude and variability of oxygenated compounds found in a contemporary rural region; (2) assess the importance of the measured ambient levels of OVOCs on a photochemical reactivity basis relative to the more commonly determined NMHCs; and (3) to evaluate our ability to accurately measure oxygenates by the current techniques employed under a field study scenario. Several other physical (temperature, insolation, etc.), meteorological (wind velocity, wind direction, atmospheric structure, and boundary layer height), and chemical (criterion pollutants, NO{sub x}, SO{sub 2}, CO, O{sub 3}, etc.) parameters were measured concurrently with the NMHC and OVOC measurements. During the study period, OVOCs were consistently the dominant compounds present, and methanol and acetone had the highest mixing ratios. Although OVOCs made up the majority of the volatile organic compound component on a mass basis, a substantial sink for OH was isoprene and its immediate oxidation products, methacrolein and methyl vinyl ketone. In combination with CO and formaldehyde, these compounds comprised about 85{percent} of the observed OH reactivity at the site. Acetaldehyde and methanol were responsible for an additional 10{percent}, with the NMHCs and remaining OVOCs making up the final 5{percent} of the measured OH reactivity at the site. These observed patterns reinforce recent studies which find OVOCs to be an important component of the rural troposphere. {copyright} 1998 American Geophysical Union

Riemer, Daniel; Pos, Willer; Milne, Peter; Farmer, Charlesk; Zika, Rod [Division of Marine and Atmospheric Chemistry, Rosenstiel School of Marine and Atmospheric Science, University of Miami, Miami, Florida (United States)] [Atmospheric Chemistry Division, National Center for Atmospheric Research, Boulder, Colorado (United States)] [Atmospheric Sciences, Tennessee Valley Authority, Muscle Shoals, Alabama (United States)] Apel, Eric [Atmospheric Chemistry Group, Mantech Environmental Research Triangle Park, North Carolina (United States)] Olszyna, Ken [National Environmental Research Laboratory, U.S. EPA. Research Triangle Park, North Carolina (United States)] Kliendienst, Tad [Department of Chemistry, Western Michigan University, Kalamazoo, Michigan (United States)] Lonneman, William [Departments of Chemistry, and Earth and Atmospheric Science, Purdue University, West Lafayette, Indiana (United States); Shepson, Paul; Starn, Tim

1998-11-01T23:59:59.000Z

22

Estimating The Thermodynamics And Kinetics Of Chlorinated Hydrocarbon...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Estimating The Thermodynamics And Kinetics Of Chlorinated Hydrocarbon Degradation. Estimating The Thermodynamics And Kinetics Of Chlorinated Hydrocarbon Degradation. Abstract: Many...

23

aromatic hydrocarbon components: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AROMATIC HYDROCARBONS 2005 April 19 ABSTRACT Interstellar polycyclic aromatic hydrocarbon (PAH) infrared emission features 26 Dehydrogenation of polycyclic aromatic...

24

Syngas Upgrading to Hydrocarbon Fuels Technology Pathway  

SciTech Connect (OSTI)

This technology pathway case investigates the upgrading of woody biomass derived synthesis gas (syngas) to hydrocarbon biofuels. While this specific discussion focuses on the conversion of syngas via a methanol intermediate to hydrocarbon blendstocks, there are a number of alternative conversion routes for production of hydrocarbons through a wide array of intermediates from syngas. Future work will also consider the variations to this pathway to determine the most economically viable and lowest risk conversion route. Technical barriers and key research needs have been identified that should be pursued for the syngas-to-hydrocarbon pathway to be competitive with petroleum-derived gasoline-, diesel- and jet-range hydrocarbon blendstocks.

Talmadge, M.; Biddy, M.; Dutta, A.; Jones, S.; Meyer, A.

2013-03-01T23:59:59.000Z

25

Dry reforming of hydrocarbon feedstocks  

SciTech Connect (OSTI)

Developments in catalyst technology for the dry reforming of hydrocarbon feedstocks are reviewed for methane, higher hydrocarbons and alcohols. Thermodynamics, mechanisms and the kinetics of dry reforming are also reviewed. The literature on Ni catalysts, bi-metallic Ni catalysts and the role of promoters on Ni catalysts is critically evaluated. The use of noble and transitional metal catalysts for dry reforming is discussed. The application of solid oxide and metal carbide catalysts to dry reforming is also evaluated. Finally, various mechanisms for catalyst deactivation are assessed. This review also examines the various process related issues associated with dry reforming such as its application and heat optimization. Novel approaches such as supercritical dry reforming and microwave assisted dry reforming are briefly expanded upon.

Shah, Yatish T. [Norfolk State University; Gardner, Todd H. [U.S. DOE

2014-01-01T23:59:59.000Z

26

Underground caverns for hydrocarbon storage  

SciTech Connect (OSTI)

Large, international gas processing projects and growing LPG imports in developing countries are driving the need to store large quantities of hydrocarbon liquids. Even though underground storage is common in the US, many people outside the domestic industry are not familiar with the technology and the benefits underground storage can offer. The latter include lower construction and operating costs than surface storage, added safety, security and greater environmental acceptance.

Barron, T.F. [Exeter Energy Services, Houston, TX (United States)

1998-12-31T23:59:59.000Z

27

Deep desulfurization of hydrocarbon fuels  

DOE Patents [OSTI]

The invention relates to processes for reducing the sulfur content in hydrocarbon fuels such as gasoline, diesel fuel and jet fuel. The invention provides a method and materials for producing ultra low sulfur content transportation fuels for motor vehicles as well as for applications such as fuel cells. The materials and method of the invention may be used at ambient or elevated temperatures and at ambient or elevated pressures without the need for hydrogen.

Song, Chunshan (State College, PA); Ma, Xiaoliang (State College, PA); Sprague, Michael J. (Calgary, CA); Subramani, Velu (State College, PA)

2012-04-17T23:59:59.000Z

28

Membrane separation of hydrocarbons using cycloparaffinic solvents  

DOE Patents [OSTI]

Heavy crude oils which contain metal contaminants such as nickel, vanadium and iron may be separated from light hydrocarbon oils by passing a solution of the crude oil dissolved in a cycloparaffinic hydrocarbon solvent containing from about 5 to about 8 carbon atoms by passing through a polymeric membrane which is capable of maintaining its integrity in the presence of hydrocarbon compounds. The light hydrocarbon oils which possess relatively low molecular weights will be recovered as the permeate while the heavy oils which possess relatively high molecular weights as well as the metal contaminants will be recovered as the retentate.

Kulkarni, Sudhir S. (Hoffman Estates, IL); Chang, Y. Alice (Westmont, IL); Gatsis, John G. (Des Plaines, IL); Funk, Edward W. (Highland Park, IL)

1988-01-01T23:59:59.000Z

29

Application of advanced hydrocarbon characterization and its...  

Broader source: Energy.gov (indexed) [DOE]

advanced hydrocarbon characterization and its consequences on future fuel properties and advanced combustion research Rafal Gieleciak, Craig Fairbridge and Darcy Hager Poster...

30

Membrane separation of hydrocarbons using cycloparaffinic solvents  

DOE Patents [OSTI]

Heavy crude oils which contain metal contaminants such as nickel, vanadium and iron may be separated from light hydrocarbon oils by passing a solution of the crude oil dissolved in a cycloparaffinic hydrocarbon solvent containing from about 5 to about 8 carbon atoms by passing through a polymeric membrane which is capable of maintaining its integrity in the presence of hydrocarbon compounds. The light hydrocarbon oils which possess relatively low molecular weights will be recovered as the permeate while the heavy oils which possess relatively high molecular weights as well as the metal contaminants will be recovered as the retentate.

Kulkarni, S.S.; Chang, Y.A.; Gatsis, J.G.; Funk, E.W.

1988-06-14T23:59:59.000Z

31

Nox reduction system utilizing pulsed hydrocarbon injection  

DOE Patents [OSTI]

Hydrocarbon co-reductants, such as diesel fuel, are added by pulsed injection to internal combustion engine exhaust to reduce exhaust NO.sub.x to N.sub.2 in the presence of a catalyst. Exhaust NO.sub.x reduction of at least 50% in the emissions is achieved with the addition of less than 5% fuel as a source of the hydrocarbon co-reductants. By means of pulsing the hydrocarbon flow, the amount of pulsed hydrocarbon vapor (itself a pollutant) can be minimized relative to the amount of NO.sub.x species removed.

Brusasco, Raymond M. (Livermore, CA); Penetrante, Bernardino M. (San Ramon, CA); Vogtlin, George E. (Fremont, CA); Merritt, Bernard T. (Livermore, CA)

2001-01-01T23:59:59.000Z

32

Polynuclear aromatic hydrocarbons for fullerene synthesis in flames  

DOE Patents [OSTI]

This invention provides improved methods for combustion synthesis of carbon nanomaterials, including fullerenes, employing multiple-ring aromatic hydrocarbon fuels selected for high carbon conversion to extractable fullerenes. The multiple-ring aromatic hydrocarbon fuels include those that contain polynuclear aromatic hydrocarbons. More specifically, multiple-ring aromatic hydrocarbon fuels contain a substantial amount of indene, methylnapthalenes or mixtures thereof. Coal tar and petroleum distillate fractions provide low cost hydrocarbon fuels containing polynuclear aromatic hydrocarbons, including without limitation, indene, methylnapthalenes or mixtures thereof.

Alford, J. Michael; Diener, Michael D.

2006-12-19T23:59:59.000Z

33

Hydrocarbon conversion process and catalysts  

SciTech Connect (OSTI)

This patent describes a process for hydrocracking hydrocarbon oils into products of lower average molecular weight and lower average boiling point. It comprises contacting hydrocarbon oil at a temperature between 250{sup 0}C and 500{sup 0}C and a pressure up to 300 bar in the presence of hydrogen with a catalyst consisting essentially of a Y zeolite modified to have a unit cell size below 24.40 A, a water adsorption capacity (at 25{sup 0}C and a rho/rho/sub o/ value of 0.2) of between 10% and 15% by weight of the zeolite and a pore volume of at least 0.25 ml/g wherein between 10% and 60% of the total pore volume is made up of pores having a diameter of at least 8 nm; am amorphous cracking component, a binder and at least one hydrogenation component selected from the group consisting of a Group VI metal, a Group VIII metal and mixtures thereof.

Hoek, A.; Huizinga, T.; Maxwell, I.E.

1989-08-15T23:59:59.000Z

34

Tensile Effective Stresses in Hydrocarbon Storage Caverns  

E-Print Network [OSTI]

Tensile Effective Stresses in Hydrocarbon Storage Caverns Hippolyte Djizanne and Pierre Bérest LMS, Germany,1-2 October 2012 TENSILE EFFECTIVE STRESSES IN HYDROCARBON STORAGE CAVERNS Hippolyte Djizanne1 that effective tensile stresses can be generated at a cavern wall after a rapid increase or decrease in pressure

Paris-Sud XI, Université de

35

Conversion of organic solids to hydrocarbons  

DOE Patents [OSTI]

A method of converting organic solids to liquid and gaseous hydrocarbons includes impregnating an organic solid with photosensitizing ions and exposing the impregnated solid to light in a non-oxidizing atmosphere for a time sufficient to photocatalytically reduce the solid to at least one of a liquid and a gaseous hydrocarbon.

Greenbaum, Elias (Oak Ridge, TN)

1995-01-01T23:59:59.000Z

36

Conversion of organic solids to hydrocarbons  

DOE Patents [OSTI]

A method of converting organic solids to liquid and gaseous hydrocarbons includes impregnating an organic solid with photosensitizing ions and exposing the impregnated solid to light in a non-oxidizing atmosphere for a time sufficient to photocatalytically reduce the solid to at least one of a liquid and a gaseous hydrocarbon. 5 Figs.

Greenbaum, E.

1995-05-23T23:59:59.000Z

37

Low-Temperature Hydrocarbon/CO Oxidation Catalysis in Support...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

& Publications Low-Temperature HydrocarbonCO Oxidation Catalysis in Support of HCCI Emission Control Low-Temperature HydrocarbonCO Oxidation Catalysis in Support of HCCI...

38

Commercialization of IH2 Biomass Direct-to-Hydrocarbon Fuel...  

Broader source: Energy.gov (indexed) [DOE]

Commercialization of IH2 Biomass Direct-to-Hydrocarbon Fuel Technology Commercialization of IH2 Biomass Direct-to-Hydrocarbon Fuel Technology Breakout Session 2: Frontiers and...

39

Advanced Diesel Combustion with Low Hydrocarbon and Carbon Monoxide...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Combustion with Low Hydrocarbon and Carbon Monoxide Emissions Advanced Diesel Combustion with Low Hydrocarbon and Carbon Monoxide Emissions Poster presented at the 16th Directions...

40

Selective photooxidation of hydrocarbons in zeolites by oxygen  

DOE Patents [OSTI]

A selective photooxidation process for the conversion of hydrocarbon molecules to partially oxygenated derivatives, which comprises the steps of adsorbing a hydrocarbon and oxygen onto a dehydrated zeolite support matrix to form a hydrocarbon-oxygen contact pair, and subsequently exposing the hydrocarbon-oxygen contact pair to visible light, thereby forming a partially oxygenated derivative.

Frei, Heinz (Berkeley, CA); Blatter, Fritz (Berkeley, CA); Sun, Hai (Berkeley, CA)

1998-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "non-methane hydrocarbons nmhc" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Water solubility data for 151 hydrocarbons  

SciTech Connect (OSTI)

The solubility of a hydrocarbon in water is important from both an environmental and a safety perspective. This information is required by engineers who design or operate stripping processes that remove hydrocarbons from air or water, or who must determine the amount of a hydrocarbon that has dissolved in water following a chemical spill. In particular, the water solubilities of paraffins are increasingly important because of more-stringent government regulations. Paraffins, along with naphthenes and aromatics, are the three major components of unrefined fuels. The water solubilities of 151 paraffins are listed in tables. The data are valid between 25 and 121 C, typical temperature in air- and steam-stripping operations. Also included is a correlation equation that allows users to estimate hydrocarbon solubilities above the given temperature range.

Yaws, C.L.; Pan, Xiang; Lin, Xiaoyin (Lamar Univ., Beaumont, TX (United States))

1993-02-01T23:59:59.000Z

42

Solubilization of petroleum hydrocarbons using biosurfactants  

E-Print Network [OSTI]

that bioavailability of the crude oil to the microorganisms limited the degradation rates (Mills, 1994). Preliminary experiments at our laboratories have also indicated enhanced solubilities of petroleum hydrocarbons due to the effects of biosurfactants (Kanga et al...

Kanga, Shahrukh

1995-01-01T23:59:59.000Z

43

Removal of trace olefins from aromatic hydrocarbons  

SciTech Connect (OSTI)

A process is described for treating a hydrocarbon process stream by converting trace quantities of olefinic impurities to nonolefinic hydrocarbons. The process comprises contacting the process stream, which contains trace olefins in an amount of from about 50 to about 2000 as measured by Bromine Index and at least 80% by weight of aromatic and naphthenic hydrocarbons having from 6 to 20 carbon atoms per molecule, at reaction conditions which ensure liquid phase operation with a solid catalyst composite comprising a crystalline aluminosilicate zeolite and a refractory inorganic oxide. A catalytic olefin-consuming alkylation reaction then produces an essentially olefinfree product stream with approximately the same quantity and distribution of aromatic and naphthenic hydrocarbons as contained in the process stream.

Sachtler, J.W.A.; Barger, P.T.

1989-01-03T23:59:59.000Z

44

E-Print Network 3.0 - aromatic hydrocarbons estimated Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Geosciences 26 2006-01-0201 Speciated Hydrocarbon Emissions from an Automotive Diesel Summary: estimated for many hydrocarbons 26, 27. The MIR of a hydrocarbon is the...

45

E-Print Network 3.0 - aromatic hydrocarbons investigated Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

compounds with two multiple-ringed polynuclear aromatic hydrocarbons (PAHs) or naphthenic hydrocarbons... Prediction of hydrocarbon molecular structure using infrared, Raman,...

46

E-Print Network 3.0 - aromatic hydrocarbon investigation Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

compounds with two multiple-ringed polynuclear aromatic hydrocarbons (PAHs) or naphthenic hydrocarbons... Prediction of hydrocarbon molecular structure using infrared, Raman,...

47

E-Print Network 3.0 - aromatic hydrocarbons evaluated Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

compounds with two multiple-ringed polynuclear aromatic hydrocarbons (PAHs) or naphthenic hydrocarbons... Prediction of hydrocarbon molecular structure using infrared, Raman,...

48

E-Print Network 3.0 - aromatic hydrocarbon diol-epoxide Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

compounds with two multiple-ringed polynuclear aromatic hydrocarbons (PAHs) or naphthenic hydrocarbons... Prediction of hydrocarbon molecular structure using infrared, Raman,...

49

E-Print Network 3.0 - aromatic hydrocarbon residues Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

compounds with two multiple-ringed polynuclear aromatic hydrocarbons (PAHs) or naphthenic hydrocarbons... Prediction of hydrocarbon molecular structure using infrared, Raman,...

50

E-Print Network 3.0 - aromatic hydrocarbons analyses Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

compounds with two multiple-ringed polynuclear aromatic hydrocarbons (PAHs) or naphthenic hydrocarbons... Prediction of hydrocarbon molecular structure using infrared, Raman,...

51

Syngas Upgrading to Hydrocarbon Fuels Technology Pathway  

SciTech Connect (OSTI)

In support of the Bioenergy Technologies Office, the National Renewable Energy Laboratory (NREL) and the Pacific Northwest National Laboratory (PNNL) are undertaking studies of biomass conversion technologies to hydrocarbon fuels to identify barriers and target research toward reducing conversion costs. Process designs and preliminary economic estimates for each of these pathway cases were developed using rigorous modeling tools (Aspen Plus and Chemcad). These analyses incorporated the best information available at the time of development, including data from recent pilot and bench-scale demonstrations, collaborative industrial and academic partners, and published literature and patents. This pathway case investigates the upgrading of biomass derived synthesis gas (syngas) to hydrocarbon biofuels. While this specific discussion focuses on the conversion of syngas via a methanol intermediate to hydrocarbon blendstocks, there are a number of alternative conversion routes for production of hydrocarbons through a wide array of intermediates from syngas. Future work will also consider the variations to this pathway to determine the most economically viable and risk adverse conversion route. Technical barriers and key research needs have been identified that should be pursued for the syngas to hydrocarbon pathway to be competitive with petroleum-derived gasoline, diesel and jet range blendstocks.

Talmadge, M.; Biddy, Mary J.; Dutta, Abhijit; Jones, Susanne B.; Meyer, Pimphan A.

2013-03-31T23:59:59.000Z

52

Using supercritical fluids to refine hydrocarbons  

DOE Patents [OSTI]

This is a method to reactively refine hydrocarbons, such as heavy oils with API gravities of less than 20.degree. and bitumen-like hydrocarbons with viscosities greater than 1000 cp at standard temperature and pressure using a selected fluid at supercritical conditions. The reaction portion of the method delivers lighter weight, more volatile hydrocarbons to an attached contacting device that operates in mixed subcritical or supercritical modes. This separates the reaction products into portions that are viable for use or sale without further conventional refining and hydro-processing techniques. This method produces valuable products with fewer processing steps, lower costs, increased worker safety due to less processing and handling, allow greater opportunity for new oil field development and subsequent positive economic impact, reduce related carbon dioxide, and wastes typical with conventional refineries.

Yarbro, Stephen Lee

2014-11-25T23:59:59.000Z

53

Catalysts for synthesizing various short chain hydrocarbons  

DOE Patents [OSTI]

Method and apparatus (10), including novel photocatalysts, are disclosed for the synthesis of various short chain hydrocarbons. Light-transparent SiO.sub.2 aerogels doped with photochemically active uranyl ions (18) are fluidized in a fluidized-bed reactor (12) having a transparent window (16), by hydrogen and CO, C.sub.2 H.sub.4 or C.sub.2 H.sub.6 gas mixtures (20), and exposed to radiation (34) from a light source (32) external to the reactor (12), to produce the short chain hydrocarbons (36).

Colmenares, Carlos (Alamo, CA)

1991-01-01T23:59:59.000Z

54

Conversion of methane and acetylene into gasoline range hydrocarbons  

E-Print Network [OSTI]

Conversion of methane and acetylene to higher molecular weight hydrocarbons over zeolite catalyst (HZSM-5) was studied The reaction between methane and acetylene successfully produced high molecular weight hydrocarbons, such as naphthalene, benzene...

Alkhawaldeh, Ammar

2000-01-01T23:59:59.000Z

55

Seismic Analysis Using Wavelet Transform for Hydrocarbon Detection  

E-Print Network [OSTI]

result in successful hydrocarbon finds because abnormal seismic amplitude variations can sometimes be caused by other factors, such as alternative lithology and residual hydrocarbons in certain depositional environments. Furthermore, not all gas fields...

Cai, Rui

2012-02-14T23:59:59.000Z

56

Chemical nature of high-molecular hydrocarbons of gaseous condensates  

SciTech Connect (OSTI)

Mass spectrometry was used to study the group-structure composition of high-boiling 50 deg (200/degrees/-250/degrees/, 250/degrees/-300/degrees/, and 300/degrees/-350/degrees/C) fractions of East Turkmenistan condensates: the hydrocarbons composition is characterized by a high content of paraffinic hydrocarbons, and that of others by aromatic and naphthenic hydrocarbons. For all the condensates under investigation, as the boiling temperature of fractions increases, the content of paraffinic hydrocarbons in them is increased, while that of naphthenic hydrocarbons is reduced. The distribution of naphthenic hydrocarbons according to the number of rings is identical. In high-paraffin condensates, monoaromatic hydrocarbons consist mainly structures with alkyl substituents, but in condensates with a high content of aromatic and naphthenic hydrocarbons they consist mainly of structures with naphthenic substituents. 4 references, 1 figures, 2 tables.

Kul'dzhayev, B.A.; Makarov, V.V.; Sergiyenko, S.R.; Khramova, E.V.

1987-01-01T23:59:59.000Z

57

Sustainable treatment of hydrocarbon-contaminated industrial land  

E-Print Network [OSTI]

Land contamination by petroleum hydrocarbons is a widespread and global environmental pollution issue from recovery and refining of crude oil and the ubiquitous use of hydrocarbons in industrial processes and applications. ...

Cunningham, Colin John

2012-06-25T23:59:59.000Z

58

A Parametric Study of the Effect of Temperature and Hydrocarbon...  

Broader source: Energy.gov (indexed) [DOE]

of Temperature and Hydrocarbon Species on the Product Distribution from a Non-Thermal Plasma Reactor A Parametric Study of the Effect of Temperature and Hydrocarbon Species on the...

59

E-Print Network 3.0 - aromatic hydrocarbons methyl Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Renewable Energy 2 Quantification of Local Ozone Production Attributable to Automobile Hydrocarbon Emissions Summary: -fueled automobiles, most cyclic hydrocarbons are...

60

E-Print Network 3.0 - aromatic hydrocarbons progress Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Collection: Chemistry 3 Quantification of Local Ozone Production Attributable to Automobile Hydrocarbon Emissions Summary: -fueled automobiles, most cyclic hydrocarbons are...

Note: This page contains sample records for the topic "non-methane hydrocarbons nmhc" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

E-Print Network 3.0 - aromatic hydrocarbons fluorene Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Hydrocarbons... Polycyclic aromatic hydrocarbons (PAHs) are ubiquitous organic pollutants in urban environments... in the urbanized and rapidly urbanizing areas. Keywords...

62

E-Print Network 3.0 - aromatic hydrocarbon phenanthrene Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Abstract Polycyclic aromatic hydrocarbons (PAHs) and dioxins are lipophilic organic pollutants occurring... absorption, pig INTRODUCTION Polycyclic aromatic hydrocarbons (PAHs)...

63

E-Print Network 3.0 - aromatic hydrocarbons based Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Aromatic Hydrocarbons Volatile Organic... Compounds Toxic Organic Halogenated Dioxins Furans (dioxins) Polycyclic Aromatic Hydrocarbons found... Rana Novini ATOC 3500 Burn...

64

E-Print Network 3.0 - aromatic hydrocarbons Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Hydrocarbons... Polycyclic aromatic hydrocarbons (PAHs) are ubiquitous organic pollutants in urban environments... in the urbanized and rapidly urbanizing areas. Keywords...

65

E-Print Network 3.0 - aromatic hydrocarbons pah5 Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

hydrocarbons (PAHs) are ubiquitous, recalcitrant, and potentially carcinogenic pollutants. Plants Summary: 1461 Polycyclic aromatic hydrocarbons (PAHs) are ubiquitous,...

66

E-Print Network 3.0 - aromatic hydrocarbons inenvironmental Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Hydrocarbons... Polycyclic aromatic hydrocarbons (PAHs) are ubiquitous organic pollutants in urban environments... in the urbanized and rapidly urbanizing areas. Keywords...

67

E-Print Network 3.0 - aromatic hydrocarbon o-quinones Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Hydrocarbons... Polycyclic aromatic hydrocarbons (PAHs) are ubiquitous organic pollutants in urban environments... in the urbanized and rapidly urbanizing areas. Keywords...

68

E-Print Network 3.0 - aromatic hydrocarbons assessment Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Aromatic Hydrocarbons Volatile Organic... Compounds Toxic Organic Halogenated Dioxins Furans (dioxins) Polycyclic Aromatic Hydrocarbons found... of airborne soot. The air...

69

Method and apparatus for low temperature destruction of halogenated hydrocarbons  

DOE Patents [OSTI]

A method and apparatus for decomposing halogenated hydrocarbons are provided. The halogenated hydrocarbon is mixed with solvating agents and maintained in a predetermined atmosphere and at a predetermined temperature. The mixture is contacted with recyclable reactive material for chemically reacting with the recyclable material to create dehalogenated hydrocarbons and halogenated inorganic compounds. A feature of the invention is that the process enables low temperature destruction of halogenated hydrocarbons.

Reagen, William Kevin (Stillwater, MN); Janikowski, Stuart Kevin (Idaho Falls, ID)

1999-01-01T23:59:59.000Z

70

aromatic hydrocarbons coated: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Summary: ??Polycyclic aromatic hydrocarbons (PAHs) are ubiquitous environmental pollutants, known human lung carcinogens, and potent mammary carcinogens in animal models....

71

Biological Conversion of Sugars to Hydrocarbons Technology Pathway  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Enzymes Acid + Caustic Wastewater Treatment Process Heat and Power Integration Biogas + Sludge Fuel Finishing (hydroprocessing, as needed) Electricity Hydrogen Hydrocarbon...

72

Production of hydrocarbons from hydrates. [DOE patent application  

DOE Patents [OSTI]

An economical and safe method of producing hydrocarbons (or natural gas) from in situ hydrocarbon-containing hydrates is given. Once started, the method will be self-driven and will continue producing hydrocarbons over an extended period of time (i.e., many days).

McGuire, P.L.

1981-09-08T23:59:59.000Z

73

Method for removing chlorine compounds from hydrocarbon mixtures  

DOE Patents [OSTI]

A process for removing halide ions from a hydrocarbon feedstream containing halogenated hydrocarbons wherein the contaminated feedstock is contacted with a solution of a suitable oxidizing acid containing a lanthanide oxide, the acid being present in a concentration of at least about 50 weight percent for a time sufficient to remove substantially all of the halide ion from the hydrocarbon feedstock.

Janoski, E.J.; Hollstein, E.J.

1984-09-29T23:59:59.000Z

74

Substantially self-powered method and apparatus for recovering hydrocarbons from hydrocarbon-containing solid hydrates  

DOE Patents [OSTI]

A method and apparatus are provided for producing gaseous hydrocarbons from formations comprising solid hydrocarbon hydrates located under either a body of land or a body of water. The vast natural resources of such hydrocarbon hydrates can thus now be economically mined. Relatively warm brine or water is brought down from an elevation above that of the hydrates through a portion of the apparatus, and passes in contact with the hydrates, thus melting them. The liquid then continues up another portion of the apparatus carrying entrained hydrocarbon vapors in the form of bubbles, which can easily be separated from the liquid. After a short startup procedure, the process and apparatus are substantially self-powered.

Elliott, G.R.B.; Barraclough, B.L.; Vanderborgh, N.E.

1981-02-19T23:59:59.000Z

75

Substantially self-powered method and apparatus for recovering hydrocarbons from hydrocarbon-containing solid hydrates  

DOE Patents [OSTI]

A method and apparatus are provided for producing gaseous hydrocarbons from formations comprising solid hydrocarbon hydrates located under either a body of land or a body of water. The vast natural resources of such hydrocarbon hydrates can thus now be economically mined. Relatively warm brine or water is brought down from an elevation above that of the hydrates through a portion of the apparatus and passes in contact with the hydrates, thus melting them. The liquid then continues up another portion of the apparatus, carrying entrained hydrocarbon vapors in the form of bubbles, which can easily be separated from the liquid. After a short startup procedure, the process and apparatus are substantially self-powered.

Elliott, Guy R. B. (Los Alamos, NM); Barraclough, Bruce L. (Santa Fe, NM); Vanderborgh, Nicholas E. (Los Alamos, NM)

1983-01-01T23:59:59.000Z

76

Apparatus for recovering gaseous hydrocarbons from hydrocarbon-containing solid hydrates  

DOE Patents [OSTI]

A method and apparatus are provided for producing gaseous hydrocarbons from formations comprising solid hydrocarbon hydrates located under either a body of land or a body of water. The vast natural resources of such hydrocarbon hydrates can thus now be economically mined. Relatively warm brine or water is brought down from an elevation above that of the hydrates through a portion of the apparatus and passes in contact with the hydrates, thus melting them. The liquid then continues up another portion of the apparatus, carrying entrained hydrocarbon vapors in the form of bubbles, which can easily be separated from the liquid. After a short startup procedure, the process and apparatus are substantially self-powered.

Elliott, Guy R. B. (Los Alamos, NM); Barraclough, Bruce L. (Santa Fe, NM); Vanderborgh, Nicholas E. (Los Alamos, NM)

1984-01-01T23:59:59.000Z

77

Method of dispersing a hydrocarbon using bacteria  

DOE Patents [OSTI]

New protozoan derived microbial consortia and method for their isolation are provided. Consortia and bacteria isolated therefrom are useful for treating wastes such as trichloroethylene and trinitrotoluene. Consortia, bacteria isolated therefrom, and dispersants isolated therefrom are useful for dispersing hydrocarbons such as oil, creosote, wax, and grease.

Tyndall, Richard L. (Clinton, TN)

1996-01-01T23:59:59.000Z

78

Mass Transfer of Polynuclear Aromatic Hydrocarbons from  

E-Print Network [OSTI]

of the individual components of four synthetic dense non-aqueous phase liquid (DNAPL) mixtures into the aqueous hydrocarbons (PAHs), were designed to serve as models for coal tars and creosotes. The reactor employed (PAHs) are often present in the environment as components of such dense non- aqueous phase liquids

Peters, Catherine A.

79

Hydrocarbon composition of crude oils near the Caspian depression  

SciTech Connect (OSTI)

The structural-group composition of hydrocarbons of Mesozoic crude oils near the Caspian depression was investigated by mass-spectrometry, followed by the analysis of the mass-spectra using a computer. The distribution of naphthenic hydrocarbons, according to the number of rings and of aromatic hydrocarbons, according to the degree of hydrogen unsaturation is similar for all the crude oils examined. The hydrocarbon composition of Mesozoic crude oils is characterized by a reduction in the content of aliphatic hydrocarbons and alkyl benzenes.

Botneva, T.A.; Khramova, E.V.; Nekhamkina, L.G.; Polyakova, A.A.

1983-01-01T23:59:59.000Z

80

Composition of paraffinic and naphthenic hydrocarbons in petroleum asphalts  

SciTech Connect (OSTI)

Uses a combination of chromatographic, chemical, and spectroscopic methods to determine the composition of the paraffinic and naphthenic hydrocarbons recovered from asphalts. Monitors the completeness of separation of the hydrocarbons from the aromatics on the basis of UV spectra. Finds that in the mixture of adduct-forming hydrocarbons, along with the n-paraffins there were admixtures of isoparaffins and longchain alkylnaphthenes. Concludes that a comparison of the structural-group composition of the asphalt fractions from the different crudes shows that there are only slight differences in the structure of the paraffinic/naphthenic hydrocarbons present in these asphalts, particularly with regard to those hydrocarbons that do not react with urea.

Botvin'eva, A.M.; Dubkova, R.V.; Shkredova, N.A.

1982-11-01T23:59:59.000Z

Note: This page contains sample records for the topic "non-methane hydrocarbons nmhc" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Plasma-assisted conversion of solid hydrocarbon to diamond  

DOE Patents [OSTI]

A process of preparing diamond, e.g., diamond fiber, by subjecting a hydrocarbon material, e.g., a hydrocarbon fiber, to a plasma treatment in a gaseous feedstream for a sufficient period of time to form diamond, e.g., a diamond fiber is disclosed. The method generally further involves pretreating the hydrocarbon material prior to treatment with the plasma by heating within an oxygen-containing atmosphere at temperatures sufficient to increase crosslinking within said hydrocarbon material, but at temperatures insufficient to melt or decompose said hydrocarbon material, followed by heating at temperatures sufficient to promote outgassing of said crosslinked hydrocarbon material, but at temperatures insufficient to convert said hydrocarbon material to carbon.

Valone, Steven M. (Santa Fe, NM); Pattillo, Stevan G. (Los Alamos, NM); Trkula, Mitchell (Los Alamos, NM); Coates, Don M. (Santa Fe, NM); Shah, S. Ismat (Wilmington, DE)

1996-01-01T23:59:59.000Z

82

Hydrous pyrolysis/oxidation process for in situ destruction of chlorinated hydrocarbon and fuel hydrocarbon contaminants in water and soil  

DOE Patents [OSTI]

In situ hydrous pyrolysis/oxidation process is useful for in situ degradation of hydrocarbon water and soil contaminants. Fuel hydrocarbons, chlorinated hydrocarbons, polycyclic aromatic hydrocarbons, petroleum distillates and other organic contaminants present in the soil and water are degraded by the process involving hydrous pyrolysis/oxidation into non-toxic products of the degradation. The process uses heat which is distributed through soils and water, optionally combined with oxygen and/or hydrocarbon degradation catalysts, and is particularly useful for remediation of solvent, fuel or other industrially contaminated sites.

Knauss, Kevin G. (Livermore, CA); Copenhaver, Sally C. (Livermore, CA); Aines, Roger D. (Livermore, CA)

2000-01-01T23:59:59.000Z

83

NMOG Emissions Characterizations and Estimation for Vehicles Using Ethanol-Blended Fuels  

SciTech Connect (OSTI)

Ethanol is a biofuel commonly used in gasoline blends to displace petroleum consumption; its utilization is on the rise in the United States, spurred by the biofuel utilization mandates put in place by the Energy Independence and Security Act of 2007 (EISA). The United States Environmental Protection Agency (EPA) has the statutory responsibility to implement the EISA mandates through the promulgation of the Renewable Fuel Standard. EPA has historically mandated an emissions certification fuel specification that calls for ethanol-free fuel, except for the certification of flex-fuel vehicles. However, since the U.S. gasoline marketplace is now virtually saturated with E10, some organizations have suggested that inclusion of ethanol in emissions certification fuels would be appropriate. The test methodologies and calculations contained in the Code of Federal Regulations for gasoline-fueled vehicles have been developed with the presumption that the certification fuel does not contain ethanol; thus, a number of technical issues would require resolution before such a change could be accomplished. This report makes use of the considerable data gathered during the mid-level blends testing program to investigate one such issue: estimation of non-methane organic gas (NMOG) emissions. The data reported in this paper were gathered from over 600 cold-start Federal Test Procedure (FTP) tests conducted on 68 vehicles representing 21 models from model year 2000 to 2009. Most of the vehicles were certified to the Tier-2 emissions standard, but several older Tier-1 and national low emissions vehicle program (NLEV) vehicles were also included in the study. Exhaust speciation shows that ethanol, acetaldehyde, and formaldehyde dominate the oxygenated species emissions when ethanol is blended into the test fuel. A set of correlations were developed that are derived from the measured non-methane hydrocarbon (NMHC) emissions and the ethanol blend level in the fuel. These correlations were applied to the measured NMHC emissions from the mid-level ethanol blends testing program and the results compared against the measured NMOG emissions. The results show that the composite FTP NMOG emissions estimate has an error of 0.0015 g/mile {+-}0.0074 for 95% of the test results. Estimates for the individual phases of the FTP are also presented with similar error levels. A limited number of tests conducted using the LA92, US06, and highway fuel economy test cycles show that the FTP correlation also holds reasonably well for these cycles, though the error level relative to the measured NMOG value increases for NMOG emissions less than 0.010 g/mile.

Sluder, Scott [ORNL; West, Brian H [ORNL

2011-10-01T23:59:59.000Z

84

NMOG Emissions Characterization and Estimation for Vehicles Using Ethanol-Blended Fuels  

SciTech Connect (OSTI)

Ethanol is a biofuel commonly used in gasoline blends to displace petroleum consumption; its utilization is on the rise in the United States, spurred by the biofuel utilization mandates put in place by the Energy Independence and Security Act of 2007 (EISA). The United States Environmental Protection Agency (EPA) has the statutory responsibility to implement the EISA mandates through the promulgation of the Renewable Fuel Standard. EPA has historically mandated an emissions certification fuel specification that calls for ethanol-free fuel, except for the certification of flex-fuel vehicles. However, since the U.S. gasoline marketplace is now virtually saturated with E10, some organizations have suggested that inclusion of ethanol in emissions certification fuels would be appropriate. The test methodologies and calculations contained in the Code of Federal Regulations for gasoline-fueled vehicles have been developed with the presumption that the certification fuel does not contain ethanol; thus, a number of technical issues would require resolution before such a change could be accomplished. This report makes use of the considerable data gathered during the mid-level blends testing program to investigate one such issue: estimation of non-methane organic gas (NMOG) emissions. The data reported in this paper were gathered from over 600 cold-start Federal Test Procedure (FTP) tests conducted on 68 vehicles representing 21 models from model year 2000 to 2009. Most of the vehicles were certified to the Tier-2 emissions standard, but several older Tier-1 and national low emissions vehicle program (NLEV) vehicles were also included in the study. Exhaust speciation shows that ethanol, acetaldehyde, and formaldehyde dominate the oxygenated species emissions when ethanol is blended into the test fuel. A set of correlations were developed that are derived from the measured non-methane hydrocarbon (NMHC) emissions and the ethanol blend level in the fuel. These correlations were applied to the measured NMHC emissions from the mid-level ethanol blends testing program and the results compared against the measured NMOG emissions. The results show that the composite FTP NMOG emissions estimate has an error of 0.0015 g/mile {+-}0.0074 for 95% of the test results. Estimates for the individual phases of the FTP are also presented with similar error levels. A limited number of tests conducted using the LA92, US06, and highway fuel economy test cycles show that the FTP correlation also holds reasonably well for these cycles, though the error level relative to the measured NMOG value increases for NMOG emissions less than 0.010 g/mile.

Sluder, Scott [ORNL; West, Brian H [ORNL

2012-01-01T23:59:59.000Z

85

HYDROCARBON-DEGRADING BACTERIA AND SURFACTANT ACTIVITY  

SciTech Connect (OSTI)

Fate of benzene ethylbenzene toluene xylenes (BTEX) compounds through biodegradation was investigated using two different bacteria, Ralstonia picketti (BP-20) and Alcaligenes piechaudii (CZOR L-1B). These bacteria were isolated from extremely polluted petroleum hydrocarbon contaminated soils. PCR and Fatty Acid Methyl Ester (FAME) were used to identify the isolates. Biodegradation was measured using each organism individually and in combination. Both bacteria were shown to degrade each of the BTEX compounds. Alcaligenes piechaudii biodegraded BTEXs more efficiently while mixed with BP-20 and individually. Biosurfactant production was observed by culture techniques. In addition 3-hydroxy fatty acids, important in biosurfactant production, was observed by FAME analysis. In the all experiments toluene and m+p- xylenes were better growth substrates for both bacteria than the other BTEX compounds. In addition, the test results indicate that the bacteria could contribute to bioremediation of aromatic hydrocarbons (BTEX) pollution increase biodegradation through the action by biosurfactants.

Brigmon, R; Topher Berry, T; Grazyna A. Plaza, G; jacek Wypych, j

2006-08-15T23:59:59.000Z

86

Behavioral toxicology, risk assessment, and chlorinated hydrocarbons  

SciTech Connect (OSTI)

Behavioral end points are being used with greater frequency in neurotoxicology to detect and characterize the adverse effects of chemicals on the nervous system. Behavioral measures are particularly important for neurotoxicity risk assessment since many known neurotoxicants do not result in neuropathology. The chlorinated hydrocarbon class consists of a wide variety of chemicals including polychlorinated biphenyls, clioquinol, trichloroethylene, hexachlorophene, organochlorine insecticides (DDT, dicofol, chlordecone, dieldrin, and lindane), and phenoxyherbicides. Each of these chemicals has effects on motor, sensory, or cognitive function that are detectable using functional measures such as behavior. Furthermore, there is evidence that if exposure occurs during critical periods of development, many of the chlorinated hydrocarbons are developmental neurotoxicants. Developmental neurotoxicity is frequently expressed as alterations in motor function or cognitive abilities or charges in the ontogeny of sensorimotor reflexes. Neurotoxicity risk assessment should include assessments of the full range of possible neurotoxicological effects, including both structural and functional indicators of neurotoxicity. 121 refs., 1 tab.

Evangelista de Duffard, A.M.; Duffard, R. [Laboratorio de Toxicologia Experimental, Santa Fe (Argentina)

1996-04-01T23:59:59.000Z

87

Method and apparatus for synthesizing hydrocarbons  

DOE Patents [OSTI]

A method and apparatus for synthesizing a mixture of hydrocarbons having five carbons or less is disclosed. An equal molar ratio of CO and H/sub 2/ gases is caused to pass through a ThO/sub 2/ catalyst having a surface area of about 80 to 125 m/sup 2//g. The catalyst further includes Na present as a substitutional cation in an amount of about 5 to 10 atom %. At a temperature of about 340 to 360/sup 0/C, and at pressures of about 20 to 50 atm, CH/sub 3/OH is produced in an amount of about 90 wt % of the total hydrocarbon mixture, and comprised 1 mole % of the effluent gas.

Colmenares, C.A.; Somorjai, G.A.; Maj, J.J.

1983-06-21T23:59:59.000Z

88

Monitoring of vapor phase polycyclic aromatic hydrocarbons  

DOE Patents [OSTI]

An apparatus for monitoring vapor phase polycyclic aromatic hydrocarbons in a high-temperature environment has an excitation source producing electromagnetic radiation, an optical path having an optical probe optically communicating the electromagnetic radiation received at a proximal end to a distal end, a spectrometer or polychromator, a detector, and a positioner coupled to the first optical path. The positioner can slidably move the distal end of the optical probe to maintain the distal end position with respect to an area of a material undergoing combustion. The emitted wavelength can be directed to a detector in a single optical probe 180.degree. backscattered configuration, in a dual optical probe 180.degree. backscattered configuration or in a dual optical probe 90.degree. side scattered configuration. The apparatus can be used to monitor an emitted wavelength of energy from a polycyclic aromatic hydrocarbon as it fluoresces in a high temperature environment.

Vo-Dinh, Tuan; Hajaligol, Mohammad R.

2004-06-01T23:59:59.000Z

89

Production of synthetic hydrocarbon fuels from peat  

SciTech Connect (OSTI)

A process and apparatus for production of synthetic hydrocarbon fuels from peat providing wide variation of the composite proportion of liquid-gas output while maintaining high overall carbon conversion to useful fuel. The process and apparatus utilizes three process stages in a single vessel providing functions of drying wet peat, provisions for addition of both wet and dry peat to a hydropyrolysis zone and gasification of the peat char.

Bodle, W.W.; Punwani, D.; Weil, S.A.

1982-06-22T23:59:59.000Z

90

Getter pump for hydrogen and hydrocarbon gases  

DOE Patents [OSTI]

A gettering device for hydrogen isotopes and gaseous hydrocarbons based on the interaction of a plasma and graphite used as cathodic material. The plasma is maintained at a current density within the range of about 1 to about 1000 mA/cm/sup 2/. The graphite may be heated to a temperature greater than 1000/degree/C. The new device offers high capacity, low noise, and gas species selectivity. 2 figs.

Hsu, Wen Ling

1987-10-14T23:59:59.000Z

91

Oxidative dehydrogenation of alkanes to unsaturated hydrocarbons  

DOE Patents [OSTI]

Oxidative dehydrogenation of alkanes to unsaturated hydrocarbons is carried out over metal vanadate catalysts under oxidizing conditions. The vanadate catalysts are represented by the formulas M[sub 3](VO[sub 4])[sub 2] and MV[sub 2]O[sub 6], M representing Mg, Zn, Ca, Pb, or Cd. The reaction is carried out in the presence of oxygen, but the formation of oxygenate by-products is suppressed.

Kung, H.H.; Chaar, M.A.

1988-10-11T23:59:59.000Z

92

Method for producing hydrocarbon and alcohol mixtures. [Patent application  

DOE Patents [OSTI]

It is an object of this invention to provide an efficient process for extracting alcohols and ketones from an aqueous solution containing the same into hydrocarbon fuel mixtures, such as gasoline, diesel fuel and fuel oil. Another object of the invention is to provide a mixture consisting of hydrocarbon, alcohols or ketones, polyoxyalkylene polymer and water which can be directly added to fuels or further purified. The above stated objects are achieved in accordance with a preferred embodiment of the invention by contacting an aqueous fermentation liquor with a hydrocarbon or hydrocarbon mixture containing carbon compounds having 5 to 18 carbon atoms, which may include gasoline, diesel fuel or fuel oil. The hydrocarbon-aqueous alcohol solution is mixed in the presence or one or more of a group of polyoxyalkylene polymers described in detail hereinafter; the fermentation alcohol being extracted into the hydrocarbon fuel-polyoxyalkylene polymer mixture.

Compere, A.L.; Googin, J.M.; Griffith, W.L.

1980-12-01T23:59:59.000Z

93

An experimental and mathematical investigation of hydrocarbon steam distillation  

E-Print Network [OSTI]

of Committee) Dr. Pau B. Crawford (Member) r. William D. McCain Jr. r. A ber t T. Watson (Member) Dr. i l. iam D. on Gonten ead of Department) December 1984 ABSTRACT An Experimental and Mathematical Investigation of Hydrocarbon Steam Distillation... mechanism associated with steam flooding and in-situ combustion enhanced oil recovery projects. It also takes place in hydrocarbon recovery from deep volatile oil reservoirs. Nethods for predicting the recovery of hydrocarbons by steam distillation have...

Langhoff, John Allan

1984-01-01T23:59:59.000Z

94

Commercialization of IH2 Biomass Direct-to-Hydrocarbon Fuel...  

Broader source: Energy.gov (indexed) [DOE]

Commercialization of IH 2 Biomass Direct-to-Hydrocarbon Fuel Technology Alan Del Paggio, Vice President CRI Catalyst Company 910 Louisiana, Houston, TX 77002 Disclaimer This...

95

Biological Conversion of Sugars to Hydrocarbons Technology Pathway...  

Broader source: Energy.gov (indexed) [DOE]

case investigates the biological conversion of biomass-derived sugars to hydrocarbon biofuels, utilizing data from recent literature references and information consistent with...

96

Systems and methods for producing hydrocarbons from tar sands formations  

DOE Patents [OSTI]

A system for treating a tar sands formation is disclosed. A plurality of heaters are located in the formation. The heaters include at least partially horizontal heating sections at least partially in a hydrocarbon layer of the formation. The heating sections are at least partially arranged in a pattern in the hydrocarbon layer. The heaters are configured to provide heat to the hydrocarbon layer. The provided heat creates a plurality of drainage paths for mobilized fluids. At least two of the drainage paths converge. A production well is located to collect and produce mobilized fluids from at least one of the converged drainage paths in the hydrocarbon layer.

Li, Ruijian (Katy, TX); Karanikas, John Michael (Houston, TX)

2009-07-21T23:59:59.000Z

97

Process for making unsaturated hydrocarbons using microchannel process technology  

DOE Patents [OSTI]

The disclosed invention relates to a process for converting a feed composition comprising one or more hydrocarbons to a product comprising one or more unsaturated hydrocarbons, the process comprising: flowing the feed composition and steam in contact with each other in a microchannel reactor at a temperature in the range from about 200.degree. C. to about 1200.degree. C. to convert the feed composition to the product, the process being characterized by the absence of catalyst for converting the one or more hydrocarbons to one or more unsaturated hydrocarbons. Hydrogen and/or oxygen may be combined with the feed composition and steam.

Tonkovich, Anna Lee (Dublin, OH); Yuschak, Thomas (Lewis Center, OH); LaPlante, Timothy J. (Columbus, OH); Rankin, Scott (Columbus, OH); Perry, Steven T. (Galloway, OH); Fitzgerald, Sean Patrick (Columbus, OH); Simmons, Wayne W. (Dublin, OH); Mazanec, Terry (Solon, OH) Daymo, Eric (Dublin, OH)

2011-04-12T23:59:59.000Z

98

Biological Production of a Hydrocarbon Fuel IntermediatePolyhydroxybu...  

Office of Scientific and Technical Information (OSTI)

Biological Production of a Hydrocarbon Fuel Intermediate Polyhydroxybutyrate (PHB) from a Process Relevant Lignocellulosic Derived Sugar (Poster) Re-direct Destination: PHAs are...

99

Selective aerobic oxidation of hydrocarbons over supported gold catalysts.  

E-Print Network [OSTI]

??The selective oxidation of hydrocarbons is of vital importance for the production of valuable chemicals from crude oil and natural gas resources. Unfortunately, when using (more)

Hereijgers, B.P.C.

2011-01-01T23:59:59.000Z

100

Algal Lipid Extraction and Upgrading to Hydrocarbons Technology...  

Energy Savers [EERE]

of algal biomass followed by further lipid extraction and upgrading to hydrocarbon biofuels. Technical barriers and key research needs have been assessed in order for the algal...

Note: This page contains sample records for the topic "non-methane hydrocarbons nmhc" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Catalytic Upgrading of Sugars to Hydrocarbons Technology Pathway...  

Energy Savers [EERE]

the catalytic conversion of solubilized carbohydrate streams to hydrocarbon biofuels, utilizing data from recent efforts within the National Advanced Biofuels Consortium...

102

Catalytic Upgrading of Sugars to Hydrocarbons Technology Pathway  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Fractionation Hydrogen Acid, Caustic, Enzymes Wastewater Treatment Insoluble solids Biogas + Sludge Process Heat and Power Integration Corn Stover Hydrocarbon Biofuels (i.e....

103

Carbonaceous adsorbent regeneration and halocarbon displacement by hydrocarbon gases  

DOE Patents [OSTI]

This invention describes a process for regeneration of halocarbon bearing carbonaceous adsorbents through which a carbonaceous adsorbent is contacted with hydrocarbon gases, preferably propane, butane and pentane at near room temperatures and at atmospheric pressure. As the hydrocarbon gases come in contact with the adsorbent, the hydrocarbons displace the halocarbons by physical adsorption. As a result of using this process, the halocarbon concentration and the hydrocarbon eluant is increased thereby allowing for an easier recovery of pure halocarbons. By using the process of this invention, carbonaceous adsorbents can be regenerated by an inexpensive process which also allows for subsequent re-use of the recovered halocarbons.

Senum, Gunnar I. (Patchogue, NY); Dietz, Russell N. (Patchogue, NY)

1994-01-01T23:59:59.000Z

104

Carbonaceous adsorbent regeneration and halocarbon displacement by hydrocarbon gases  

DOE Patents [OSTI]

This invention describes a process for regeneration of halocarbon bearing carbonaceous adsorbents through which a carbonaceous adsorbent is contacted with hydrocarbon gases, preferably propane, butane and pentane at near room temperatures and at atmospheric pressure. As the hydrocarbon gases come in contact with the adsorbent, the hydrocarbons displace the halocarbons by physical adsorption. As a result of using this process, the halocarbon concentration and the hydrocarbon eluant is increased thereby allowing for an easier recovery of pure halocarbons. By using the process of this invention, carbonaceous adsorbents can be regenerated by an inexpensive process which also allows for subsequent re-use of the recovered halocarbons. 8 figures.

Senum, G.I.; Dietz, R.N.

1994-04-05T23:59:59.000Z

105

aromatic hydrocarbon carcinogenesis: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

and Ecology Websites Summary: ), and there are oil refineries on the shore. In this environment, input of aromatic hydrocarbons from petroleum and the Yarra River Estuary J. David...

106

Advanced Diesel Combustion with Low Hydrocarbon and Carbon Monoxide...  

Broader source: Energy.gov (indexed) [DOE]

Combustion with Low Hydrocarbon and Carbon Monoxide Emissions Poster Location P-19 Gregory K. Lilik, Andr L. Boehman Department of Energy & Mineral Engineering EMS Energy...

107

Gulf Hydrocarbon Inc | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 No revision hasInformation Earth's Heat Jump to:Photon Place:Net Jump Agency/Company(Redirected fromHydrocarbon

108

Preliminary Geospatial Analysis of Arctic Ocean Hydrocarbon Resources  

SciTech Connect (OSTI)

Ice coverage of the Arctic Ocean is predicted to become thinner and to cover less area with time. The combination of more ice-free waters for exploration and navigation, along with increasing demand for hydrocarbons and improvements in technologies for the discovery and exploitation of new hydrocarbon resources have focused attention on the hydrocarbon potential of the Arctic Basin and its margins. The purpose of this document is to 1) summarize results of a review of published hydrocarbon resources in the Arctic, including both conventional oil and gas and methane hydrates and 2) develop a set of digital maps of the hydrocarbon potential of the Arctic Ocean. These maps can be combined with predictions of ice-free areas to enable estimates of the likely regions and sequence of hydrocarbon production development in the Arctic. In this report, conventional oil and gas resources are explicitly linked with potential gas hydrate resources. This has not been attempted previously and is particularly powerful as the likelihood of gas production from marine gas hydrates increases. Available or planned infrastructure, such as pipelines, combined with the geospatial distribution of hydrocarbons is a very strong determinant of the temporal-spatial development of Arctic hydrocarbon resources. Significant unknowns decrease the certainty of predictions for development of hydrocarbon resources. These include: 1) Areas in the Russian Arctic that are poorly mapped, 2) Disputed ownership: primarily the Lomonosov Ridge, 3) Lack of detailed information on gas hydrate distribution, and 4) Technical risk associated with the ability to extract methane gas from gas hydrates. Logistics may control areas of exploration more than hydrocarbon potential. Accessibility, established ownership, and leasing of exploration blocks may trump quality of source rock, reservoir, and size of target. With this in mind, the main areas that are likely to be explored first are the Bering Strait and Chukchi Sea, in spite of the fact that these areas do not have highest potential for future hydrocarbon reserves. Opportunities for improving the mapping and assessment of Arctic hydrocarbon resources include: 1) Refining hydrocarbon potential on a basin-by-basin basis, 2) Developing more realistic and detailed distribution of gas hydrate, and 3) Assessing the likely future scenarios for development of infrastructure and their interaction with hydrocarbon potential. It would also be useful to develop a more sophisticated approach to merging conventional and gas hydrate resource potential that considers the technical uncertainty associated with exploitation of gas hydrate resources. Taken together, additional work in these areas could significantly improve our understanding of the exploitation of Arctic hydrocarbons as ice-free areas increase in the future.

Long, Philip E.; Wurstner, Signe K.; Sullivan, E. C.; Schaef, Herbert T.; Bradley, Donald J.

2008-10-01T23:59:59.000Z

109

Process for the production of liquid hydrocarbons  

DOE Patents [OSTI]

The present invention concerns a process for the preparation of liquid hydrocarbons which process comprises contacting synthesis gas with a slurry of solid catalyst particles and a liquid in a reactor vessel by introducing the synthesis gas at a low level into the slurry at conditions suitable for conversion of the synthesis gas into liquid hydrocarbons, the solid catalyst particles comprising a catalytic active metal selected from cobalt or iron on a porous refractory oxide carrier, preferably selected from silica, alumina, titania, zirconia or mixtures thereof, the catalyst being present in an amount between 10 and 40 vol. percent based on total slurry volume liquids and solids, and separating liquid material from the solid catalyst particles by using a filtration system comprising an asymmetric filtration medium (the selective side at the slurry side), in which filtration system the average pressure differential over the filtration medium is at least 0.1 bar, in which process the particle size distribution is such that at least a certain amount of the catalyst particles is smaller than the average pore size of the selective layer of the filtration medium. The invention also comprises an apparatus to carry out the process described above.

Bhatt, Bharat Lajjaram; Engel, Dirk Coenraad; Heydorn, Edward Clyde; Senden, Matthijis Maria

2006-06-27T23:59:59.000Z

110

Solubility of hydrocarbons in salt water  

SciTech Connect (OSTI)

In the design and operation of industrial processes, physical and thermodynamic property data are required. Increasingly stringent regulations are making water solubility of substances even more critical. Water solubility data of naphthenes, or cycloalkanes, is applicable for the complete range of salt concentrations, including water without salt to water saturated with salt. The results are intended for use in initial engineering and environmental applications. Solubility values from the correlation are useful in determining the distribution of a hydrocarbon spill on its contact with sea water. Solubility values at other salt concentrations also may be computed. Results are presented for water solubility of hydrocarbons (naphthenes) as a function of salt concentration (log(S) = A + BX + CX[sup 2]). The correlation constants, A, B and C, are displayed in an easy-to-use tabular format that is applicable for rapid engineering use with the personal computer or hand-held calculator. The results for solubility in salt water are applicable for the complete range of salt concentrations. This range covers water without salt, X = 0, to water saturated with salt, X = 358,700 ppM(wt). Correlation and experimental results are in favorable agreement.

Yaws, C.L.; Lin, X. (Lamar Univ., Beaumont, TX (United States). Dept. of Chemical Engineering)

1994-01-01T23:59:59.000Z

111

Scroll compressor modelling for heat pumps using hydrocarbons as refrigerants  

E-Print Network [OSTI]

1 Scroll compressor modelling for heat pumps using hydrocarbons as refrigerants Paul BYRNE and to install heat pumps in unoccupied spaces. Nevertheless manufacturers keep working on components for hydrocarbons. In the frame of a research project on heat pumps for simultaneous heating and cooling, an R407C

Paris-Sud XI, Université de

112

Biological Conversion of Sugars to Hydrocarbons Technology Pathway  

SciTech Connect (OSTI)

This technology pathway case investigates the biological conversion of biomass-derived sugars to hydrocarbon biofuels, utilizing data from recent literature references and information consistent with recent pilot-scale demonstrations at NREL. Technical barriers and key research needs have been identified that should be pursued for the pathway to become competitive with petroleum-derived gasoline-, diesel-, and jet-range hydrocarbon blendstocks.

Davis, R.; Biddy, M.; Tan, E.; Tao, L.; Jones, S.

2013-03-01T23:59:59.000Z

113

.. Polycyclic aromatic hydrocarbons in nearshore marine sediments of Australia*  

E-Print Network [OSTI]

143 . .. Polycyclic aromatic hydrocarbons in nearshore marine sediments of Australia* W.A. Maher and J. Aislabiet Water Research Centre, University of Canberra, PO Box /, Belconnen,ACT 26/6, Australia aromatic hydrocarbons (PAH) in nearshore marine sediments of Australia isdiscussed. Available information

Canberra, University of

114

Selective thermal and photooxidation of hydrocarbons in zeolites by oxygen  

DOE Patents [OSTI]

A process is described for selective thermal oxidation or photooxidation of hydrocarbons adsorbed onto zeolite matrices. A highly selective thermal oxidation and photooxidation of unsubstituted or alkyl substituted alkanes, alkenes, aromatics and cycloalkyls in solvent free zeolites under dark thermal conditions or under irradiation with visible light. The process oxidizes hydrocarbons almost completely selectively without substantial production of byproducts. 19 figs.

Frei, H.; Blatter, F.; Sun, H.

1999-06-22T23:59:59.000Z

115

Selective thermal and photooxidation of hydrocarbons in zeolites by oxygen  

DOE Patents [OSTI]

A process for selective thermal oxidation or photooxidation of hydrocarbons adsorbed onto zeolite matrices. A highly selective thermal oxidation and photooxidation of unsubstituted or alkyl substituted alkanes, alkenes, aromatics and cycloalkyls in solvent free zeolites under dark thermal conditions or under irradiation with visible light. The process oxidizes hydrocarbons almost completely selectively without substantial production of byproducts.

Frei, Heinz (Berkeley, CA); Blatter, Fritz (Basel, CH); Sun, Hai (Saint Charles, MO)

1999-01-01T23:59:59.000Z

116

Selective thermal oxidation of hydrocarbons in zeolites by oxygen  

DOE Patents [OSTI]

A process for selective thermal oxidation of hydrocarbons adsorbed onto zeolite matrices. A highly selective thermal oxidation of unsubstituted or alkyl substituted alkanes, alkenes, aromatics and cycloalkyls is carried out in solvent free zeolites under dark thermal conditions. The process oxidizes hydrocarbons almost completely selectively without substantial production of byproducts.

Frei, Heinz (Berkeley, CA); Blatter, Fritz (Basel, CH); Sun, Hai (Saint Charles, MO)

2000-01-01T23:59:59.000Z

117

Selective thermal and photooxidation of hydrocarbons in zeolites by oxygen  

DOE Patents [OSTI]

A process for a combined selective thermal oxidation and photooxidation of hydrocarbons adsorbed onto zeolite matrices. A highly combined selective thermal oxidation and photooxidation of unsubstituted or alkyl substituted alkanes, alkenes, aromatics and cycloalkyls in solvent free zeolites under dark thermal conditions or under irradiation with visible light. The process oxidizes hydrocarbons almost completely selectively without substantial production of byproducts.

Frei, Heinz (Berkeley, CA); Blatter, Fritz (Basel, CH); Sun, Hai (Saint Charles, MO)

2001-01-01T23:59:59.000Z

118

E-Print Network 3.0 - aromatic hydrocarbon exposure Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Aust. J. Mar. Freshw. Res., 1984, 35, 119-28 Aromatic Hydrocarbons in Waters of Port Phillip Bay... of aromatic hydrocarbons in coastal waters, using solvent extraction and...

119

E-Print Network 3.0 - aromatic hydrocarbons influence Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

; Geosciences 93 Hydrocarbons Heterogeneous Pyrolysis: Experiments and Modeling for Scramjet Thermal Management Summary: of the decomposition of the heavy hydrocarbon fuel is the...

120

E-Print Network 3.0 - aromatic hydrocarbon unresolved Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

40 On the Use, and Reuse, of Polymers for the Treatment of Hydrocarbon Contaminated Water Via a Solidliquid Partitioning Bioreactor Summary: hydrocarbons and more heavily...

Note: This page contains sample records for the topic "non-methane hydrocarbons nmhc" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

E-Print Network 3.0 - aromatic hydrocarbons affect Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Sciences and Ecology 3 Quantification of Local Ozone Production Attributable to Automobile Hydrocarbon Emissions Summary: -fueled automobiles, most cyclic hydrocarbons are...

122

E-Print Network 3.0 - aromatic hydrocarbons annual Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Page: << < 1 2 3 4 5 > >> 1 Quantification of Local Ozone Production Attributable to Automobile Hydrocarbon Emissions Summary: releases about 5 billion kilograms of hydrocarbons...

123

E-Print Network 3.0 - aromatic hydrocarbons implications Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Page: << < 1 2 3 4 5 > >> 1 Quantification of Local Ozone Production Attributable to Automobile Hydrocarbon Emissions Summary: -fueled automobiles, most cyclic hydrocarbons are...

124

E-Print Network 3.0 - aromatic hydrocarbons alcohols Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Mathematics 29 UV Irradiation of Polycyclic Aromatic Hydrocarbons in Ices Summary: UV Irradiation of Polycyclic Aromatic Hydrocarbons in Ices: Production of Alcohols,...

125

E-Print Network 3.0 - aromatic hydrocarbons exhibited Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of Port Phillip Bay... of aromatic hydrocarbons in coastal waters, using solvent extraction and fluorescence emission analysis, shows... of hydrocarbon inputs....

126

E-Print Network 3.0 - aromatic hydrocarbons molecules Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Sciences and Ecology 35 2006-01-0201 Speciated Hydrocarbon Emissions from an Automotive Diesel Summary: to number of carbon atoms per hydrocarbon molecule (Figure 2). For each...

127

E-Print Network 3.0 - aromatic hydrocarbons resulting Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Geosciences 50 2006-01-0201 Speciated Hydrocarbon Emissions from an Automotive Diesel Summary: a retention library developed by performing runs with known hydrocarbon...

128

E-Print Network 3.0 - aromatic hydrocarbons determined Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Mathematics 39 2006-01-0201 Speciated Hydrocarbon Emissions from an Automotive Diesel Summary: hydrocarbons is by their structure. Figure 10 shows conversion efficiency...

129

E-Print Network 3.0 - aromatic hydrocarbons formed Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Sciences and Ecology 31 2006-01-0201 Speciated Hydrocarbon Emissions from an Automotive Diesel Summary: of engine-out hydrocarbons that are partially reacted fuel. LATE FORMING...

130

E-Print Network 3.0 - aromatic hydrocarbon content Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Technologies 23 2006-01-0201 Speciated Hydrocarbon Emissions from an Automotive Diesel Summary: hydrocarbons is by their structure. Figure 10 shows conversion efficiency...

131

E-Print Network 3.0 - aromatic hydrocarbon molecules Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Sciences and Ecology 35 2006-01-0201 Speciated Hydrocarbon Emissions from an Automotive Diesel Summary: to number of carbon atoms per hydrocarbon molecule (Figure 2). For each...

132

E-Print Network 3.0 - aromatic hydrocarbon contamination Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Summary: called aromatic hydrocarbons. These include harmful pollutants like dioxins, PCBs and a group called... polycyclic aromatic hydrocarbons (PAHs). PAHs are...

133

E-Print Network 3.0 - aromatic hydrocarbon receptor Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

aromatic hydrocarbons... the aryl hydrocarbon receptor (AHR), through which dioxins and dioxin-like compounds cause altered gene... -methylcholanthrene AHH: aryl...

134

E-Print Network 3.0 - aromatic hydrocarbons extracted Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of Toxic Contamination Summary: called aromatic hydrocarbons. These include harmful pollutants like dioxins, PCBs and a group called... polycyclic aromatic hydrocarbons (PAHs)....

135

E-Print Network 3.0 - aromatic hydrocarbon metabolism Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

hydrocarbon is introduced into the ocean via oil spillage, offshore drilling leaks, industrial... hydrocarbons have been attributed to inhibition of ... Source: National...

136

The Impact of Low Octane Hydrocarbon Blending Streams on "E85...  

Broader source: Energy.gov (indexed) [DOE]

The Impact of Low Octane Hydrocarbon Blending Streams on "E85" Engine Optimization The Impact of Low Octane Hydrocarbon Blending Streams on "E85" Engine Optimization...

137

E-Print Network 3.0 - aromatic hydrocarbon-degrading bacteria...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

ydrocarbonDegradation It was hypothesized... aromatic hydrocarbon degradation. Hypothesis Test Result Groundwater stimulates Fe(lll) reduction Cell... Hydrocarbon Degradation At...

138

Heating hydrocarbon containing formations in a line drive staged process  

DOE Patents [OSTI]

Method for treating a hydrocarbon containing formation are described herein. Methods may include providing heat to a first section of the formation with one or more first heaters in the first section. First hydrocarbons may be heated in the first section such that at least some of the first hydrocarbons are mobilized. At least some of the mobilized first hydrocarbons may be produced through a production well located in a second section of the formation. The second section may be located substantially adjacent to the first section. A portion of the second section may be provided some heat from the mobilized first hydrocarbons, but is not conductively heated by heat from the first heaters. Heat may be provided to the second section with one or more second heaters in the second section to further heat the second section.

Miller, David Scott (Katy, TX)

2009-07-21T23:59:59.000Z

139

Cogeneration systems and processes for treating hydrocarbon containing formations  

DOE Patents [OSTI]

A system for treating a hydrocarbon containing formation includes a steam and electricity cogeneration facility. At least one injection well is located in a first portion of the formation. The injection well provides steam from the steam and electricity cogeneration facility to the first portion of the formation. At least one production well is located in the first portion of the formation. The production well in the first portion produces first hydrocarbons. At least one electrical heater is located in a second portion of the formation. At least one of the electrical heaters is powered by electricity from the steam and electricity cogeneration facility. At least one production well is located in the second portion of the formation. The production well in the second portion produces second hydrocarbons. The steam and electricity cogeneration facility uses the first hydrocarbons and/or the second hydrocarbons to generate electricity.

Vinegar, Harold J. (Bellaire, TX); Fowler, Thomas David (Houston, TX); Karanikas, John Michael (Houston, TX)

2009-12-29T23:59:59.000Z

140

A generalized viscosity equation for pure heavy hydrocarbons  

SciTech Connect (OSTI)

This paper presents a method for the correlation and prediction of the viscosity of pure heavy hydrocarbons listed in API Research Project 42. The 273 heavy hydrocarbons in the database include branched/unbranched paraffins and olefins together with a variety of complex nonfused/fused aromatic and naphthenic compounds. A generalized one-parameter viscosity-temperature equation, log ({mu} + 0.8) = 100(0.01T){sup b}, is proposed (overall AAD {lt} 7-10%) for all heavy hydrocarbons in the database. For each hydrocarbon, an optimum value of parameter b is provided. It is shown that parameter b varies linearly with the logarithm of molar mass as well as the inverse of boiling temperature (at 10 mmHg). This important observation leads to the development of a predictive method for the liquid-phase viscosity of pure heavy hydrocarbons.

Mehrotra, A.K. (Dept. of Chemical and Petroleum Engineering, Univ. of Calgary, Calgary, Alberta T2N 1N4 (CA))

1991-02-01T23:59:59.000Z

Note: This page contains sample records for the topic "non-methane hydrocarbons nmhc" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Pyrochlore catalysts for hydrocarbon fuel reforming  

DOE Patents [OSTI]

A method of catalytically reforming a reactant gas mixture using a pyrochlore catalyst material comprised of one or more pyrochlores having the composition A2B2-y-zB'yB"zO7-.DELTA., where y>0 and z.gtoreq.0. Distribution of catalytically active metals throughout the structure at the B site creates an active and well dispersed metal locked into place in the crystal structure. This greatly reduces the metal sintering that typically occurs on supported catalysts used in reforming reactions, and reduces deactivation by sulfur and carbon. Further, oxygen mobility may also be enhanced by elemental exchange of promoters at sites in the pyrochlore. The pyrochlore catalyst material may be utilized in catalytic reforming reactions for the conversion of hydrocarbon fuels into synthesis gas (H2+CO) for fuel cells, among other uses.

Berry, David A.; Shekhawat, Dushyant; Haynes, Daniel; Smith, Mark; Spivey, James J.

2012-08-14T23:59:59.000Z

142

Microbial hydrocarbons: back to the future  

SciTech Connect (OSTI)

The defining challenge of energy research in the 21st century is the development and deployment of technologies for large-scale reconfiguration of global energy infrastructure. Modern society is built upon a concentrated yet finite reservoir of diverse hydrocarbons formed through the photosynthetic transformation of several hundred million years of solar energy. In human history, the fossil energy era will be short lived and never repeated. Although the timing of peak oil is extensively debated, it is an eventuality. It is, therefore, imperative that projections for both when it will occur and the degree to which supply will fall short of demand be taken into serious consideration, especially in the sectors of energy technology development, political and economic decision making, and societal energy usage. The requirement for renewable energy systems is no longer a point for discussion, and swift advances on many fronts are vital to counteract current and impending crises in both energy and the environment.

Work, Victoria H.; Beliaev, Alex S.; Konopka, Allan; Posewitz, Matthew C.

2012-03-01T23:59:59.000Z

143

Method and apparatus for synthesizing hydrocarbons  

DOE Patents [OSTI]

A method and apparatus for synthesizing a mixture of aliphatic alcohols having five carbons or less is disclosed. An equal molar ratio of CO and H/sub 2/ gases is caused to pass through a ThO/sub 2/ catalyst having a surface area of about 80 to 125 m/sup 2//g. The catalyst further optionally includes Na ions present as substitutional cations in an amount of about 5 to 10 atom %. At a temperature of about 570 to 630/sup 0/K, and at pressures of about 20 to 50 atm, methanol and isobutanol are the predominant products and are produced in amounts of about 90 wt % of the total hydrocarbon mixture. 6 figs.

Colmenares, C.A.; Somorjai, G.A.; Maj, J.J.

1985-04-16T23:59:59.000Z

144

Geology and hydrocarbon prospects of Latvia  

SciTech Connect (OSTI)

Oil prospects in Latvia are associated with the Baltic syneclise. Latvia occupies about one fourth of that large tectonic depression; zones of oil accumulation continue there from adjacent areas: the Telshai rampart (Lithuania) and the Leba nose (Polish offshore). The oil prospects in separate areas are determined by their position regarding the sources of oil generation--the Gdansk-Kura and Liepaya depressions. The most prospective areas are the Liepaya-Saldus zone of highs and the Pape-Barta trough. The Liepaya-Saldus zone was situated so that the hydrocarbon migration path crossed it. It probably is an important oil accumulation zone. The paper describes the geology of Latvia and the one oil field in Latvia.

Freimanis, A. (Latvian Dept. of Geology, Riga (Latvia)); Margulis, L.; Brangulis, A.; Kanev, S.; Pomerantseva, R. (Inst. of Marine Geology and Geophysics, Riga (Latvia))

1993-12-06T23:59:59.000Z

145

Hydrocarbon provinces and productive trends in Libya and adjacent areas  

SciTech Connect (OSTI)

According to the age of major reservoirs, hydrocarbon occurrences in Libya and adjacent areas can be grouped into six major systems which, according to their geographic locations, can be classified into two major hydrocarbon provinces: (1) Sirte-Pelagian basins province, with major reservoirs ranging from middle-late Mesozoic to early Tertiary, and (2) Murzog-Ghadames basins province, with major reservoirs ranging from early Paleozoic to early Mesozoic. In the Sirte-Pelagian basins province, hydrocarbons have been trapped in structural highs or in stratigraphic wedge-out against structural highs and in carbonate buildups. Here, hydrocarbon generation is characterized by the combined effect of abundant structural relief and reservoir development in the same hydrocarbon systems of the same age, providing an excellent example of hydrocarbon traps in sedimentary basins that have undergone extensive tensional fracturing in a shallow marine environment. In the Murzog-Ghadames basins province, hydrocarbons have been trapped mainly in structural highs controlled by paleostructural trends as basement arches which acted as focal points for oil migration and accumulation.

Missallati, A.A. (Agip (N.A.M.E.)Ltd., Tripoli (Libya))

1988-08-01T23:59:59.000Z

146

Direct conversion of light hydrocarbon gases to liquid fuel  

SciTech Connect (OSTI)

Amoco oil Company, has investigated the direct, non-catalytic conversion of light hydrocarbon gases to liquid fuels (particularly methanol) via partial oxidation. The primary hydrocarbon feed used in these studies was natural gas. This report describes work completed in the course of our two-year project. In general we determined that the methanol yields delivered by this system were not high enough to make it economically attractive. Process variables studied included hydrocarbon feed composition, oxygen concentration, temperature and pressure effects, residence time, reactor design, and reactor recycle.

Kaplan, R.D.; Foral, M.J.

1992-05-16T23:59:59.000Z

147

Method for making hydrogen rich gas from hydrocarbon fuel  

DOE Patents [OSTI]

A method of forming a hydrogen rich gas from a source of hydrocarbon fuel in which the hydrocarbon fuel contacts a two-part catalyst comprising a dehydrogenation portion and an oxide-ion conducting portion at a temperature not less than about 400 C for a time sufficient to generate the hydrogen rich gas while maintaining CO content less than about 5 volume percent. There is also disclosed a method of forming partially oxidized hydrocarbons from ethanes in which ethane gas contacts a two-part catalyst comprising a dehydrogenation portion and an oxide-ion conducting portion for a time and at a temperature sufficient to form an oxide. 4 figs.

Krumpelt, M.; Ahmed, S.; Kumar, R.; Doshi, R.

1999-07-27T23:59:59.000Z

148

Energy loss characteristics of heavy ions in nitrogen, carbon dioxide, argon, hydrocarbon gases and tradescantia tissue  

E-Print Network [OSTI]

Energy loss characteristics of heavy ions in nitrogen, carbon dioxide, argon, hydrocarbon gases and tradescantia tissue

Dennis, J A

1971-01-01T23:59:59.000Z

149

Molecular and Biochemical Characterization of Hydrocarbon Production in the Green Microalga Botryococcus braunii  

E-Print Network [OSTI]

Algae biofuels ................................................................................ 1 Algae .............................................................................................. 2 Botryococcus braunii... ..................................................................... 4 General biology ........................................................................ 4 Biofuel potential ....................................................................... 9 Hydrocarbon synthesis...

Weiss, Taylor Leigh

2012-10-19T23:59:59.000Z

150

Separation of toxic metal ions, hydrophilic hydrocarbons, hydrophobic fuel and halogenated hydrocarbons and recovery of ethanol from a process stream  

DOE Patents [OSTI]

This invention provides a process to tremendously reduce the bulk volume of contaminants obtained from an effluent stream produced subsurface remediation. The chemicals used for the subsurface remediation are reclaimed for recycling to the remediation process. Additional reductions in contaminant bulk volume are achieved by the ultra-violet light destruction of halogenated hydrocarbons, and the complete oxidation of hydrophobic fuel hydrocarbons and hydrophilic hydrocarbons. The contaminated bulk volume will arise primarily from the disposal of the toxic metal ions. The entire process is modular, so if there are any technological breakthroughs in one or more of the component process modules, such modules can be readily replaced.

Kansa, Edward J. (Livermore, CA); Anderson, Brian L. (Lodi, CA); Wijesinghe, Ananda M. (Tracy, CA); Viani, Brian E. (Oakland, CA)

1999-01-01T23:59:59.000Z

151

Separation of toxic metal ions, hydrophilic hydrocarbons, hydrophobic fuel and halogenated hydrocarbons and recovery of ethanol from a process stream  

DOE Patents [OSTI]

This invention provides a process to tremendously reduce the bulk volume of contaminants obtained from an effluent stream produced subsurface remediation. The chemicals used for the subsurface remediation are reclaimed for recycling to the remediation process. Additional reductions in contaminant bulk volume are achieved by the ultra-violet light destruction of halogenated hydrocarbons, and the complete oxidation of hydrophobic fuel hydrocarbons and hydrophilic hydrocarbons. The contaminated bulk volume will arise primarily from the disposal of the toxic metal ions. The entire process is modular, so if there are any technological breakthroughs in one or more of the component process modules, such modules can be readily replaced. 3 figs.

Kansa, E.J.; Anderson, B.L.; Wijesinghe, A.M.; Viani, B.E.

1999-05-25T23:59:59.000Z

152

Mathematical modeling of solid oxide fuel cells using hydrocarbon fuels  

E-Print Network [OSTI]

Solid oxide fuel cells (SOFCs) are high efficiency conversion devices that use hydrogen or light hydrocarbon (HC) fuels in stationary applications to produce quiet and clean power. While successful, HC-fueled SOFCs face ...

Lee, Won Yong, Ph. D. Massachusetts Institute of Technology

2012-01-01T23:59:59.000Z

153

Faults as potential hydrocarbon barriers, Arroyo Grande, California  

E-Print Network [OSTI]

Faulting in a sandstone introduces properties which are different from the country rock. Previous work has shown that these new properties can significantly impede the flow of hydrocarbons through the country rock. This thesis seeks to analyze...

Switek, Daniel Paul

1994-01-01T23:59:59.000Z

154

Effect of the Composition of Hydrocarbon Streams on HCCI Performance  

Broader source: Energy.gov (indexed) [DOE]

of hydrocarbon samples and can be treated as compositional variables which could describe bulk properties of the samples Sample fingerprint STEP 1: Data receiving Q(2d)RPR How...

155

Biodegradability of select polycyclic aromatic hydrocarbon (pah) mixtures  

E-Print Network [OSTI]

Polycyclic aromatic hydrocarbons (PAHs) are environmentally significant because of their ubiquity and the toxicity of some. Their recalcitrance and persistence makes them problematic environmental contaminants. Microbial degradation is considered...

Desai, Anuradha M.

2007-04-25T23:59:59.000Z

156

aromatic hydrocarbon emissions: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Detection of mid-infrared Aromatic Hydrocarbon Emission Features from the Small Magellanic Cloud Astrophysics...

157

aromatic hydrocarbon emission: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Detection of mid-infrared Aromatic Hydrocarbon Emission Features from the Small Magellanic Cloud Astrophysics...

158

Process for conversion of lignin to reformulated hydrocarbon gasoline  

DOE Patents [OSTI]

A process for converting lignin into high-quality reformulated hydrocarbon gasoline compositions in high yields is disclosed. The process is a two-stage, catalytic reaction process that produces a reformulated hydrocarbon gasoline product with a controlled amount of aromatics. In the first stage, a lignin material is subjected to a base-catalyzed depolymerization reaction in the presence of a supercritical alcohol as a reaction medium, to thereby produce a depolymerized lignin product. In the second stage, the depolymerized lignin product is subjected to a sequential two-step hydroprocessing reaction to produce a reformulated hydrocarbon gasoline product. In the first hydroprocessing step, the depolymerized lignin is contacted with a hydrodeoxygenation catalyst to produce a hydrodeoxygenated intermediate product. In the second hydroprocessing step, the hydrodeoxygenated intermediate product is contacted with a hydrocracking/ring hydrogenation catalyst to produce the reformulated hydrocarbon gasoline product which includes various desirable naphthenic and paraffinic compounds.

Shabtai, Joseph S. (Salt Lake City, UT); Zmierczak, Wlodzimierz W. (Salt Lake City, UT); Chornet, Esteban (Golden, CO)

1999-09-28T23:59:59.000Z

159

Process for converting light alkanes to higher hydrocarbons  

DOE Patents [OSTI]

A process is disclosed for the production of aromatic-rich, gasoline boiling range hydrocarbons from the lower alkanes, particularly from methane. The process is carried out in two stages. In the first, alkane is reacted with oxygen and hydrogen chloride over an oxyhydrochlorination catalyst such as copper chloride with minor proportions of potassium chloride and rare earth chloride. This produces an intermediate gaseous mixture containing water and chlorinated alkanes. The chlorinated alkanes are contacted with a crystalline aluminosilicate catalyst in the hydrogen or metal promoted form to produce gasoline range hydrocarbons with a high proportion of aromatics and a small percentage of light hydrocarbons (C.sub.2 -C.sub.4). The light hydrocarbons can be recycled for further processing over the oxyhydrochlorination catalyst.

Noceti, Richard P. (Pittsburgh, PA); Taylor, Charles E. (Pittsburgh, PA)

1988-01-01T23:59:59.000Z

160

Hydrocarbon Inhibition and HC Storage Modeling in Fe-Zeolite...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Inhibition and HC Storage Modeling in Fe-Zeolite Catalysts for HD Diesel Engines Hydrocarbon Inhibition and HC Storage Modeling in Fe-Zeolite Catalysts for HD Diesel Engines...

Note: This page contains sample records for the topic "non-methane hydrocarbons nmhc" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Determination of Total Petroleum Hydrocarbons (TPH) Using Total Carbon Analysis  

SciTech Connect (OSTI)

Several methods have been proposed to replace the Freon(TM)-extraction method to determine total petroleum hydrocarbon (TPH) content. For reasons of cost, sensitivity, precision, or simplicity, none of the replacement methods are feasible for analysis of radioactive samples at our facility. We have developed a method to measure total petroleum hydrocarbon content in aqueous sample matrixes using total organic carbon (total carbon) determination. The total carbon content (TC1) of the sample is measured using a total organic carbon analyzer. The sample is then contacted with a small volume of non-pokar solvent to extract the total petroleum hydrocarbons. The total carbon content of the resultant aqueous phase of the extracted sample (TC2) is measured. Total petroleum hydrocarbon content is calculated (TPH = TC1-TC2). The resultant data are consistent with results obtained using Freon(TM) extraction followed by infrared absorbance.

Ekechukwu, A.A.

2002-05-10T23:59:59.000Z

162

Cooling and solidification of heavy hydrocarbon liquid streams  

DOE Patents [OSTI]

A process and apparatus for cooling and solidifying a stream of heavy hydrocarbon material normally boiling above about 850.degree. F., such as vacuum bottoms material from a coal liquefaction process. The hydrocarbon stream is dropped into a liquid bath, preferably water, which contains a screw conveyor device and the stream is rapidly cooled, solidified and broken therein to form discrete elongated particles. The solid extrudates or prills are then dried separately to remove substantially all surface moisture, and passed to further usage.

Antieri, Salvatore J. (Trenton, NJ); Comolli, Alfred G. (Yardley, PA)

1983-01-01T23:59:59.000Z

163

Catalytic Upgrading of Sugars to Hydrocarbons Technology Pathway  

SciTech Connect (OSTI)

This technology pathway case investigates the catalytic conversion of solubilized carbohydrate streams to hydrocarbon biofuels, utilizing data from recent efforts within the National Advanced Biofuels Consortium (NABC) in collaboration with Virent, Inc. Technical barriers and key research needs that should be pursued for the catalytic conversion of sugars pathway to be competitive with petroleum-derived gasoline-, diesel-, and jet-range hydrocarbon blendstocks have been identified.

Biddy, M.; Jones, S.

2013-03-01T23:59:59.000Z

164

Origin of gaseous hydrocarbons in east-central Texas groundwaters  

E-Print Network [OSTI]

; Follett, 1974). The high transmissivity and sandy lithology of the Sparta are much like those of the Queen City, as is the quality of water. 40 LIGNITE STREAKS 30 Laminated and discontinuous lenticular. Trough cross bedded siltstones. 20 ROAD l... hydrocarbons simply reflects a difference in the 5 C of the substrate. Sparta lignite is about 7%%do enriched in ' C relative to Yegua lignite, comparable to the difference seen in the gaseous hydrocarbons. ACKNOWLEDGMENTS I would like to thank Dr. Steven...

Coffman, Bryan Keith

1988-01-01T23:59:59.000Z

165

Emission of polycyclic aromatic hydrocarbons in China  

SciTech Connect (OSTI)

Emission of 16 polycyclic aromatic hydrocarbons (PAHs) listed as U.S. Environmental Protection Agency (U.S. EPA) priority pollutants from major sources in China were compiled. Geographical distribution and temporal change of the PAH emission, as well as emission profiles, are discussed. It was estimated that the total PAH emission in China was 25,300 tons in 2003. The emission profile featured a relatively higher portion of high molecular weight (HMW) species with carcinogenic potential due to large contributions of domestic coal and coking industry. Among various sources, biomass burning, domestic coal combustion, and the coking industry contributed 60%, 20%, and 16% of the total emission, respectively. Total emission, emission density, emission intensity, and emission per capita showed geographical variations. In general, the southeastern provinces were characterized by higher emission density, while those in western and northern China featured higher emission intensity and population-normalized emission. Although energy consumption in China went up continuously during the past two decades, annual emission of PAHs fluctuated depending on the amount of domestic coal consumption, coke production, and the efficiency of energy utilization. 47 refs., 6 figs.

Shanshan Xu; Wenxin Liu; Shu Tao [Peking University, Beijing (China). Laboratory for Earth Surface Processes, College of Environmental Sciences

2006-02-01T23:59:59.000Z

166

Rock types, pore types, and hydrocarbon exploration  

SciTech Connect (OSTI)

A proposed exploration-oriented method of classifying porosity in sedimentary rocks is based on microscopic examination cores or cuttings. Factors include geometry, size, abundance, and connectivity of the pores. The porosity classification is predictive of key petrophysical characteristics: porosity-permeability relationships, capillary pressures, and (less certainly) relative permeabilities. For instance, intercrystalline macroporosity typically is associated with high permeability for a given porosity, low capillarity, and favorable relative permeabilities. This is found to be true whether this porosity type occurs in a sucrosic dolomite or in a sandstone with pervasive quartz overgrowths. This predictive method was applied in three Rocky Mountain oil plays. Subtle pore throat traps could be recognized in the J sandstone (Cretaceous) in the Denver basin of Colorado by means of porosity permeability plotting. Variations in hydrocarbon productivity from a Teapot Formation (Cretaceous) field in the Powder River basin of Wyoming were related to porosity types and microfacies; the relationships were applied to exploration. Rock and porosity typing in the Red River Formation (Ordovician) reconciled apparent inconsistencies between drill-stem test, log, and mud-log data from a Williston basin wildcat. The well was reevaluated and completed successfully, resulting in a new field discovery. In each of these three examples, petrophysics was fundamental for proper evaluation of wildcat wells and exploration plays.

Coalson, E.B.; Hartmann, D.J.; Thomas, J.B.

1985-05-01T23:59:59.000Z

167

Tailoring hydrocarbon streams for asphaltene removal  

SciTech Connect (OSTI)

Oilfield production is often hindered by asphaltene precipitation which tends to fill the pores of the reservoir rocks and plug the wellbore tubing as well as the other auxiliary equipment used during crude oil recovery. Several remedies to remove these deposits have been proposed and patented but the injection of aromatic solvents such as toluene and light petroleum distillates is normally preferred. Previous studies with a number of pure aromatic hydrocarbons have shown that the solvent capacity of these molecules may be very different and that the degree of condensation plays an important role. In this regard, tetralins and naphthalenes are superior to alkylbenzenes. However, because the use of pure compounds is not economically feasible, the authors examined various industrial streams and the authors correlated their chemical composition to the solvent capacity. This work allowed the identification of the pseudo-components whose relative concentration is crucial for evaluating the solvent performances. Based on these data, the authors were able to find new products with ideal characteristics. The efficiency of one of these products was confirmed by the analysis of the data obtained when using this new solvent to remove asphaltene in damaged wells of an Italian field.

Del Bianco, A.; Stroppa, F.; Bertero, L.

1995-11-01T23:59:59.000Z

168

Kidney cancer and hydrocarbon exposures among petroleum refinery workers  

SciTech Connect (OSTI)

To evaluate the hypothesis of increased kidney cancer risk after exposure to hydrocarbons, especially those present in gasoline, we conducted a case-control study in a cohort of approximately 100,000 male refinery workers from five petroleum companies. A review of 18,323 death certificates identified 102 kidney cancer cases, to each of whom four controls were matched by refinery location and decade of birth. Work histories, containing an average of 15.7 job assignments per subject, were found for 98% of the cases and 94% of the controls. Tb each job, industrial hygienists assigned semiquantitative ratings for the intensity and frequency of exposures to three hydrocarbon categories: nonaromatic liquid gasoline distillates, aromatic hydrocarbons, and the more volatile hydrocarbons. Ratings of {open_quotes}present{close_quotes} or {open_quotes}absent{close_quotes} were assigned for seven additional exposures: higher boiling hydrocarbons, polynuclear aromatic hydrocarbons, asbestos, chlorinated solvents, ionizing radiation, and lead. Each exposure had either no association or a weak association with kidney cancer. For the hydrocarbon category of principal a priori interest, the nonaromatic liquid gasoline distillates, the estimated relative risk (RR) for any exposure above refinery background was 1.0 (95% confidence interval [CI] 0.5-1.9). Analyses of cumulative exposures and of exposures in varying time periods before kidney cancer occurrence also produced null or near-null results. In an analysis of the longest job held by each subject (average duration 9.2 years or 40% of the refiner&y work history), three groups appeared to be at increased risk: laborers (RR = 1.9,95% CI 1.0-3.9); workers in receipt, storage, and movements (RR = 2.5,95% CI 0.9-6.6); and unit cleaners (RR = 2.3, 95% CI 0.5-9.9). 53 refs., 7 tabs.

Poole, C.; Dreyer, N.A.; Satterfield, M.H. [Epidemiology Resources Inc., Newton Lower Falls, MA (United States); Levin, L. [Drexel Univ., Philadelphia, PA (United States)

1993-12-01T23:59:59.000Z

169

Preliminary assessment of hydrocarbon potential in southern Illinois  

SciTech Connect (OSTI)

Hydrocarbon exploration has been sparse south of the Cottage Grove fault system in southern Illinois. Over 240,000 ac in this area are within the Shawnee National Forest (SNF). Upcoming review of mineral exploration policy on SNF land and a recent amendment to the Mineral Leasing Act (1987) will result in release of portions of the SNF for competitive and potentially noncompetitive bidding for mineral exploration tracts in the near future. Preliminary assessment of hydrocarbon potential has been carried out in southern Illinois. Numerous oil shows occur in Paleozoic strata south of the Cottage Grove fault system, which, at present, describes the southern boundary of most oil production in Illinois. Only Mitchellsville oil field in southern Saline County lies south of the Cottage Grove fault system. The Upper Devonian New Albany Shale, though to be the primary source rock for Illinois basin hydrocarbons, underlies most of the area. Older potential source rocks may be present. Depositional trends of prolific oil-productive Mississippian strata in Illinois continue southward through the area. Few drill holes have tested strata older than Mississippian in the area. Complex faulting in the Rough Creek-Shawneetown fault system may have improved the potential for hydrocarbon emplacement and entrapment in this region. Preliminary assessment of hydrocarbon potential indicates that this wildcat region deserves further tests.

Crockett, J.E.; Oltz, D.F. (Illinois State Geological Survey, Champaign (USA))

1989-08-01T23:59:59.000Z

170

Catalytic Upgrading of Sugars to Hydrocarbons Technology Pathway  

SciTech Connect (OSTI)

In support of the Bioenergy Technologies Office, the National Renewable Energy Laboratory (NREL) and the Pacific Northwest National Laboratory (PNNL) are undertaking studies of biomass conversion technologies to hydrocarbon fuels to identify barriers and target research toward reducing conversion costs. Process designs and preliminary economic estimates for each of these pathway cases were developed using rigorous modeling tools (Aspen Plus and Chemcad). These analyses incorporated the best information available at the time of development, including data from recent pilot and bench-scale demonstrations, collaborative industrial and academic partners, and published literature and patents. This technology pathway case investigates the catalytic conversion of solubilized carbohydrate streams to hydrocarbon biofuels, utilizing data from recent efforts within the National Advanced Biofuels Consortium (NABC) in collaboration with Virent, Inc.. Technical barriers and key research needs that should be pursued for the catalytic conversion of sugars pathway to be competitive with petroleum-derived gasoline, diesel and jet range hydrocarbon blendstocks have been identified.

Biddy, Mary J.; Jones, Susanne B.

2013-03-31T23:59:59.000Z

171

Process for light-driven hydrocarbon oxidation at ambient temperatures  

DOE Patents [OSTI]

A photochemical reaction for the oxidation of hydrocarbons uses molecular oxygen as the oxidant. A reductive photoredox cycle that uses a tin(IV)- or antimony(V)-porphyrin photosensitizer generates the reducing equivalents required to activate oxygen. This artificial photosynthesis system drives a catalytic cycle, which mimics the cytochrome P.sub.450 reaction, to oxidize hydrocarbons. An iron(III)- or manganese(III)-porphyrin is used as the hydrocarbon-oxidation catalyst. Methylviologen can be used as a redox relay molecule to provide for electron-transfer from the reduced photosensitizer to the Fe or Mn porphyrin. The system is long-lived and may be used in photo-initiated spectroscopic studies of the reaction to determine reaction rates and intermediates.

Shelnutt, John A. (Tijeras, NM)

1990-01-01T23:59:59.000Z

172

Combustion process for synthesis of carbon nanomaterials from liquid hydrocarbon  

DOE Patents [OSTI]

The present invention provides a combustion apparatus for the production of carbon nanomaterials including fullerenes and fullerenic soot. Most generally the combustion apparatus comprises one or more inlets for introducing an oxygen-containing gas and a hydrocarbon fuel gas in the combustion system such that a flame can be established from the mixed gases, a droplet delivery apparatus for introducing droplets of a liquid hydrocarbon feedstock into the flame, and a collector apparatus for collecting condensable products containing carbon nanomaterials that are generated in the combustion system. The combustion system optionally has a reaction zone downstream of the flame. If this reaction zone is present the hydrocarbon feedstock can be introduced into the flame, the reaction zone or both.

Diener, Michael D.; Alford, J. Michael; Nabity, James; Hitch, Bradley D.

2007-01-02T23:59:59.000Z

173

Method for recovering light hydrocarbons from coal agglomerates  

DOE Patents [OSTI]

A method and apparatus for removing light hydrocarbons, such as heptane, from coal agglomerates includes an enclosed chamber having a substantially horizontal perforate surface therein. The coal agglomerates are introduced into a water bath within the chamber. The agglomerates are advanced over the surface while steam is substantially continuously introduced through the surface into the water bath. Steam heats the water and causes volatilization of the light hydrocarbons, which may be collected from the overhead of the chamber. The resulting agglomerates may be collected at the opposite end from the surface and subjected to final draining processes prior to transportation or use.

Huettenhain, Horst (Benicia, CA); Benz, August D. (Hillsborough, CA); Getsoian, John (Ann Arbor, MI)

1991-01-01T23:59:59.000Z

174

Upgrading of petroleum oil feedstocks using alkali metals and hydrocarbons  

DOE Patents [OSTI]

A method of upgrading an oil feedstock by removing heteroatoms and/or one or more heavy metals from the oil feedstock composition. This method reacts the oil feedstock with an alkali metal and an upgradant hydrocarbon. The alkali metal reacts with a portion of the heteroatoms and/or one or more heavy metals to form an inorganic phase separable from the organic oil feedstock material. The upgradant hydrocarbon bonds to the oil feedstock material and increases the number of carbon atoms in the product. This increase in the number of carbon atoms of the product increases the energy value of the resulting oil feedstock.

Gordon, John Howard

2014-09-09T23:59:59.000Z

175

Process of producing liquid hydrocarbon fuels from biomass  

DOE Patents [OSTI]

A continuous thermochemical indirect liquefaction process is described to convert various biomass materials into diesel-type transportation fuels which fuels are compatible with current engine designs and distribution systems comprising feeding said biomass into a circulating solid fluidized bed gasification system to produce a synthesis gas containing olefins, hydrogen and carbon monoxide and thereafter introducing the synthesis gas into a catalytic liquefaction system to convert the synthesis gas into liquid hydrocarbon fuel consisting essentially of C[sub 7]-C[sub 17] paraffinic hydrocarbons having cetane indices of 50+. 1 fig.

Kuester, J.L.

1987-07-07T23:59:59.000Z

176

Process of producing liquid hydrocarbon fuels from biomass  

DOE Patents [OSTI]

A continuous thermochemical indirect liquefaction process to convert various biomass materials into diesel-type transportation fuels which fuels are compatible with current engine designs and distribution systems comprising feeding said biomass into a circulating solid fluidized bed gasification system to produce a synthesis gas containing olefins, hydrogen and carbon monoxide and thereafter introducing the synthesis gas into a catalytic liquefaction system to convert the synthesis gas into liquid hydrocarbon fuel consisting essentially of C.sub.7 -C.sub.17 paraffinic hydrocarbons having cetane indices of 50+.

Kuester, James L. (Scottsdale, AZ)

1987-07-07T23:59:59.000Z

177

Low-Temperature Catalytic Process To Produce Hydrocarbons From Sugars  

DOE Patents [OSTI]

Disclosed is a method of producing hydrogen from oxygenated hydrocarbon reactants, such as methanol, glycerol, sugars (e.g. glucose and xylose), or sugar alcohols (e.g. sorbitol). The method takes place in the condensed liquid phase. The method includes the steps of reacting water and a water-soluble oxygenated hydrocarbon in the presence of a metal-containing catalyst. The catalyst contains a metal selected from the group consisting of Group VIIIB transitional metals, alloys thereof, and mixtures thereof. The disclosed method can be run at lower temperatures than those used in the conventional steam reforming of alkanes.

Cortright, Randy D. (Madison, WI); Dumesic, James A. (Verona, WI)

2005-11-15T23:59:59.000Z

178

Electrically heated particulate filter regeneration using hydrocarbon adsorbents  

DOE Patents [OSTI]

An exhaust system that processes exhaust generated by an engine is provided. The system generally includes a particulate filter (PF) that filters particulates from the exhaust wherein an upstream end of the PF receives exhaust from the engine. A grid of electrically resistive material selectively heats exhaust passing through the upstream end to initiate combustion of particulates within the PF. A hydrocarbon adsorbent coating applied to the PF releases hydrocarbons into the exhaust to increase a temperature of the combustion of the particulates within the PF.

Gonze, Eugene V [Pinckney, MI

2011-02-01T23:59:59.000Z

179

Hydrocarbon composition of crude oil from Lam Bank  

SciTech Connect (OSTI)

The authors discuss the crude oil from a new offshore field called the Lam Bank in the Caspian Sea. A segregated commercial crude was distilled and the distillation data is shown. In order to determine the content of n-paraffins, the naphthenic-paraffinic part of the narrow cuts was subjected to adsorptive separation on CaA zeolite. Owing to the high contents of naphthenic and isoparaffinic hydrocarbons and the low content of aromatic hydrocarbons in the distillate part, this crude can be used to produce high-quality fuels and oils by the use of the dewaxing processes.

Samedova, F.I.; Agaeva, R.M.; Alieva, F.Z.; Valiev, M.A.

1987-07-01T23:59:59.000Z

180

Method and apparatus for production of subsea hydrocarbon formations  

DOE Patents [OSTI]

A system for controlling, separating, processing and exporting well fluids produced from subsea hydrocarbon formations is disclosed. The subsea well tender system includes a surface buoy supporting one or more decks above the water surface for accommodating equipment to process oil, gas and water recovered from the subsea hydrocarbon formation. The surface buoy includes a surface-piercing central flotation column connected to one or more external flotation tanks located below the water surface. The surface buoy is secured to the sea bed by one or more tendons which are anchored to a foundation with piles imbedded in the sea bed. The system accommodates multiple versions on the surface buoy configuration. 20 figures.

Blandford, J.W.

1995-01-17T23:59:59.000Z

Note: This page contains sample records for the topic "non-methane hydrocarbons nmhc" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Method and apparatus for production of subsea hydrocarbon formations  

DOE Patents [OSTI]

A system for controlling, separating, processing and exporting well fluids produced from subsea hydrocarbon formations is disclosed. The subsea well tender system includes a surface buoy supporting one or more decks above the water surface for accommodating equipment to process oil, gas and water recovered from the subsea hydrocarbon formation. The surface buoy includes a surface-piercing central flotation column connected to one or more external floatation tanks located below the water surface. The surface buoy is secured to the seabed by one or more tendons which are anchored to a foundation with piles imbedded in the seabed. The system accommodates multiple versions on the surface buoy configuration.

Blandford, Joseph W. (15 Mott La., Houston, TX 77024)

1995-01-01T23:59:59.000Z

182

Method for determining processability of a hydrocarbon containing feedstock  

DOE Patents [OSTI]

Disclosed herein is a method involving the steps of (a) precipitating an amount of asphaltenes from a liquid sample of a first hydrocarbon-containing feedstock having solvated asphaltenes therein with one or more first solvents in a column; (b) determining one or more solubility characteristics of the precipitated asphaltenes; (c) analyzing the one or more solubility characteristics of the precipitated asphaltenes; and (d) correlating a measurement of feedstock reactivity for the first hydrocarbon-containing feedstock sample with a mathematical parameter derived from the results of analyzing the one or more solubility characteristics of the precipitated asphaltenes.

Schabron, John F.; Rovani, Jr., Joseph F.

2013-09-10T23:59:59.000Z

183

LiMnPO4 Nanoplate Grown via Solid-State Reaction in Molten Hydrocarbon...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

LiMnPO4 Nanoplate Grown via Solid-State Reaction in Molten Hydrocarbon for Li-ion Battery Cathode. LiMnPO4 Nanoplate Grown via Solid-State Reaction in Molten Hydrocarbon for Li-ion...

184

Oil & Chemical Pollution 6 (19'X)} 81-Hydrocarbon Pollution of  

E-Print Network [OSTI]

distribution offuel distillates is evident with only a small contribution from lubricating and heavier oilOil & Chemical Pollution 6 (19'X)} 81- pollution as all oils contain aromatic hydrocarbons while few, if any, biogenic aromatic hydrocarbons

Canberra, University of

185

Interpretation of side-scan sonar images from hydrocarbon seep areas of the Louisiana continental slope  

E-Print Network [OSTI]

Side-scan sonar images from the Louisiana continental slope were examined to study hydrocarbon seepage and related surficial geologic seafloor features. Three study areas are located in the Green Canyon area and the Garden Bank area. Hydrocarbon...

Hou, Rusheng

2001-01-01T23:59:59.000Z

186

Syngas Conversion to Gasoline-Range Hydrocarbons over Pd/ZnO...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Syngas Conversion to Gasoline-Range Hydrocarbons over PdZnOAl2O3 and ZSM-5 Composite Catalyst System. Syngas Conversion to Gasoline-Range Hydrocarbons over PdZnOAl2O3 and ZSM-5...

187

Evaluation of biological treatment for the degradation of petroleum hydrocarbons in a wastewater treatment plant  

E-Print Network [OSTI]

present. An evaluation of the performance of the biological treatment of petroleum hydrocarbon by the hydrocarbon degrading microbes at the Brayton Fire School??s 4 million gallon per day (MGD) wastewater treatment plant was the main research objective...

Basu, Pradipta Ranjan

2005-08-29T23:59:59.000Z

188

A 4D Synchrotron X-Ray-Tomography Study of the Formation of Hydrocarbon-  

E-Print Network [OSTI]

hydrocarbons and the growing production of hydrocarbons from low-permeability tight rocks. Quantitative models, University of Oslo, Idaho National Laboratory, and Institute for Energy Technology Summary Recovery of oil from oil shales and the natural primary migration of hydrocarbons are closely related processes

Mazzini, Adriano

189

UPTAKE AND LOSS OF PETROLEUM HYDROCARBONS BY THE MUSSEL, MYTILUS EDULIS, IN LABORATORY EXPERIMENTS  

E-Print Network [OSTI]

UPTAKE AND LOSS OF PETROLEUM HYDROCARBONS BY THE MUSSEL, MYTILUS EDULIS, IN LABORATORY EXPERIMENTS ROBERT C. CLARK, JR., AND JOHN S. FINLEY' ABSTRACT Petroleum paraffin hydrocarbons (n-CI4H30 to n-C37H76 system that simulated tides. The mussels were exposed to levels of petroleum hydrocarbons from a surface

190

192 IEEE SENSORS JOURNAL, VOL. 7, NO. 2, FEBRUARY 2007 Hydrocarbon and Fluorocarbon Monitoring by MIS  

E-Print Network [OSTI]

192 IEEE SENSORS JOURNAL, VOL. 7, NO. 2, FEBRUARY 2007 Hydrocarbon and Fluorocarbon Monitoring of hydrocarbon and fluorocarbon molecules on a Ni coil (CE), the products detectable by metal­ insulator Terms--Fluorocarbons, hydrocarbons, metal­ insulator­semiconductor (MIS) and metal

Moritz, Werner

191

Fundamental spectroscopic studies of carbenes and hydrocarbon radicals  

SciTech Connect (OSTI)

Highly reactive carbenes and carbon-chain radicals are studied at millimeter wavelengths by observing their rotational spectra. The purpose is to provide definitive spectroscopic identification, accurate spectroscopic constants in the lowest vibrational states, and reliable structures of the key intermediates in reactions leading to aromatic hydrocarbons and soot particles in combustion.

Gottlieb, C.A.; Thaddeus, P. [Harvard Univ., Cambridge, MA (United States)

1993-12-01T23:59:59.000Z

192

Hydrocarbons Heterogeneous Pyrolysis: Experiments and Modeling for Scramjet Thermal Management  

E-Print Network [OSTI]

1 Hydrocarbons Heterogeneous Pyrolysis: Experiments and Modeling for Scramjet Thermal Management : United States (2008)" #12;2 I. Introduction One of the main issues of the development of scramjet, an air to the endothermicity of its thermal decomposition. Because of the large heat load found in a scramjet, engine

Paris-Sud XI, Université de

193

Hydrocarbon saturation determination using acoustic velocities obtained through casing  

DOE Patents [OSTI]

Compressional and shear velocities of earth formations are measured through casing. The determined compressional and shear velocities are used in a two component mixing model to provides improved quantitative values for the solid, the dry frame, and the pore compressibility. These are used in determination of hydrocarbon saturation.

Moos, Daniel (Houston, TX)

2010-03-09T23:59:59.000Z

194

Formation mechanism for polycyclic aromatic hydrocarbons in methane flames  

E-Print Network [OSTI]

Formation mechanism for polycyclic aromatic hydrocarbons in methane flames K. Siegmanna) Swiss 96822 Received 24 August 1999; accepted 13 October 1999 A laminar diffusion flame of methane exhausts,7­17 coal-fired, electricity generating power plants,18,19 tobacco smoke,20 residential wood

Sattler, Klaus

195

THERMOCATALYTIC CO2-FREE PRODUCTION OF HYDROGEN FROM HYDROCARBON FUELS  

E-Print Network [OSTI]

THERMOCATALYTIC CO2- FREE PRODUCTION OF HYDROGEN FROM HYDROCARBON FUELS N. Muradov Florida Solar Energy Center 1679 Clearlake Road, Cocoa, Florida 32922 tel. 321-638-1448, fax. 321-638-1010, muradov (except for the start-up operation). This results in the following advantages: (1) no CO/CO2 byproducts

196

Chemical Kinetics of Hydrocarbon Ignition in Practical Combustion Systems  

SciTech Connect (OSTI)

Chemical kinetic factors of hydrocarbon oxidation are examined in a variety of ignition problems. Ignition is related to the presence of a dominant chain branching reaction mechanism that can drive a chemical system to completion in a very short period of time. Ignition in laboratory environments is studied for problems including shock tubes and rapid compression machines. Modeling of the laboratory systems are used to develop kinetic models that can be used to analyze ignition in practical systems. Two major chain branching regimes are identified, one consisting of high temperature ignition with a chain branching reaction mechanism based on the reaction between atomic hydrogen with molecular oxygen, and the second based on an intermediate temperature thermal decomposition of hydrogen peroxide. Kinetic models are then used to describe ignition in practical combustion environments, including detonations and pulse combustors for high temperature ignition, and engine knock and diesel ignition for intermediate temperature ignition. The final example of ignition in a practical environment is homogeneous charge, compression ignition (HCCI) which is shown to be a problem dominated by the kinetics intermediate temperature hydrocarbon ignition. Model results show why high hydrocarbon and CO emissions are inevitable in HCCI combustion. The conclusion of this study is that the kinetics of hydrocarbon ignition are actually quite simple, since only one or two elementary reactions are dominant. However, there are many combustion factors that can influence these two major reactions, and these are the features that vary from one practical system to another.

Westbrook, C.K.

2000-07-07T23:59:59.000Z

197

Chlorinated Hydrocarbon Levels in Fishes and Shellfishes of the  

E-Print Network [OSTI]

the utilization by humans of the vast protein resources in the sea. Chlorinated hydrocarbons from both agricultural and industrial chemicals have been found repeatedly in marine organisms throughout the world also analyzed a few samples of fish eggs, liver. oil. and meal. Finfishes from the northeastern Pacific

198

Energy Conservation Opportunities in Hydrocarbon Resin Manufacturing Facilities  

E-Print Network [OSTI]

"The results of a plant-wide assessment of the manufacturing facilities of Neville Chemical Company, a manufacturer of hydrocarbon resins will be presented in this paper. The project was co-funded by US Department of Energy under its Plant...

Ganji, A. R.; Hackett, B.; Chow, S.; Lonergan, R.; Wimer, J.

199

Theoretical studies of hydrocarbon combustion chemistry. Annual progress report  

SciTech Connect (OSTI)

The author reports here the results of DZP CISD calculations for methylcarbene. Geometry, symmetry, and vibrational modes for the radical are reported for both the singlet and the triplet state. Future work will focus on the ethyl radical-oxygen interaction relevant to hydrocarbon combustion.

Schaefer, H.F. III

1994-08-01T23:59:59.000Z

200

FROM INTERSTELLAR POLYCYCLIC AROMATIC HYDROCARBONS AND ICE TO ASTROBIOLOGY  

E-Print Network [OSTI]

photolysis of these ices produces a host of new compounds, some of which show intriguing prebiotic behavior1 FROM INTERSTELLAR POLYCYCLIC AROMATIC HYDROCARBONS AND ICE TO ASTROBIOLOGY LOUIS J. ALLAMANDOLA, the concept of ices in dense molecular clouds ignored, and the notion of large, abundant, gas phase, carbon

Note: This page contains sample records for the topic "non-methane hydrocarbons nmhc" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

RICH METHANE PREMIXED LAMINAR FLAMES DOPED BY LIGHT UNSATURATED HYDROCARBONS  

E-Print Network [OSTI]

RICH METHANE PREMIXED LAMINAR FLAMES DOPED BY LIGHT UNSATURATED HYDROCARBONS PART III: CYCLOPENTENE-length article SHORTENED RUNNING TITLE : METHANE FLAMES DOPED BY CYCLOPENTENE * E-mail : pierre with the studies presented in the parts I and II of this paper, the structure of a laminar rich premixed methane

Paris-Sud XI, Université de

202

RICH METHANE PREMIXED LAMINAR FLAMES DOPED BY LIGHT UNSATURATED HYDROCARBONS  

E-Print Network [OSTI]

RICH METHANE PREMIXED LAMINAR FLAMES DOPED BY LIGHT UNSATURATED HYDROCARBONS PART I: ALLENE Full-length article SHORTENED RUNNING TITLE : METHANE FLAMES DOPED BY ALLENE OR PROPYNE * E investigated: a pure methane flame and two methane flames doped by allene and propyne, respectively. The gases

Paris-Sud XI, Université de

203

RICH METHANE PREMIXED LAMINAR FLAMES DOPED BY LIGHT UNSATURATED HYDROCARBONS  

E-Print Network [OSTI]

RICH METHANE PREMIXED LAMINAR FLAMES DOPED BY LIGHT UNSATURATED HYDROCARBONS PART II: 1,3-BUTADIENE-length article SHORTENED RUNNING TITLE : METHANE FLAMES DOPED BY 1,3-BUTADIENE * E-mail : Pierre of this paper, the structure of a laminar rich premixed methane flame doped with 1,3-butadiene has been

Paris-Sud XI, Université de

204

The toxicity of certain new chlorinated hydrocarbons to cotton pests  

E-Print Network [OSTI]

THE TOXICITY OF CERTAIN NEW CHLORINATED HYDROCARBONS TO COTTON PESTS A Dissertation 5y MARVIN EUGENE MERKL Approved as to style and content by: Chairman of CouBlttee Head of Departnent May 19*3 THE TOXICITY OF CERTAIN NEW CHLORINATED... .....................................................78 CONCLUSIONS............................................... ..81 BIBLIOGRAPHI .............................................. ..82 Pag? FIGURES 1* Dosage-?ortality curve for the toxicity of endrin to aphids...

Merkl, Marvin Eugene

1953-01-01T23:59:59.000Z

205

Moving hydrocarbons through portions of tar sands formations with a fluid  

DOE Patents [OSTI]

A method for treating a tar sands formation is disclosed. The method includes heating a first portion of a hydrocarbon layer in the formation from one or more heaters located in the first portion. The heat is controlled to increase a fluid injectivity of the first portion. A drive fluid and/or an oxidizing fluid is injected and/or created in the first portion to cause at least some hydrocarbons to move from a second portion of the hydrocarbon layer to a third portion of the hydrocarbon layer. The second portion is between the first portion and the third portion. The first, second, and third portions are horizontally displaced from each other. The third portion is heated from one or more heaters located in the third portion. Hydrocarbons are produced from the third portion of the formation. The hydrocarbons include at least some hydrocarbons from the second portion of the formation.

Stegemeier, George Leo; Mudunuri, Ramesh Raju; Vinegar, Harold J.; Karanikas, John Michael; Jaiswal, Namit; Mo, Weijian

2010-05-18T23:59:59.000Z

206

Quantitative Changes in Hydrocarbons over Time in Fecal Pellets of Incisitermes minor May Predict Whether Colonies Are Alive or Dead  

E-Print Network [OSTI]

Food utilization and fecal pellet production by drywoodexploring seasonality in pellet production and hydrocarbon

Lewis, Vernard R.; Nelson, Lori J.; Haverty, Michael I.; Baldwin, James A.

2010-01-01T23:59:59.000Z

207

INTRODUCTION Asphalt is a mixture of a wide variety of chemical compounds that include aliphatic hydrocarbons and highly fused  

E-Print Network [OSTI]

hydrocarbons and highly fused aromatic ring systems.They are classified as asphaltenes (medium molecular weight

Harms, Kyle E.

208

Ambient aromatic hydrocarbon measurements at Welgegund, South Africa  

SciTech Connect (OSTI)

Aromatic hydrocarbons are associated with direct adverse human health effects and can have negative impacts on ecosystems due to their toxicity, as well as indirect negative effects through the formation of tropospheric ozone and secondary organic aerosol that affect human health, crop production and regional climate. Measurements were conducted at the Welgegund measurement station (South Africa) that is considered to be a regionally representative background site. However, the site is occasionally impacted by plumes from major anthropogenic source regions in the interior of South Africa, which include the western Bushveld Igneous Complex (e.g. platinum, base metal and ferrochrome smelters), the eastern Bushveld Igneous Complex (platinum and ferrochrome smelters), the Johannesburg-Pretoria metropolitan conurbation (>10 million people), the Vaal Triangle (e.g. petrochemical and industries), the Mpumalanga Highveld (e.g. coal-fired power plants and petrochemical industry) and also a region of anti-cyclonic recirculation of air mass over the interior of South Africa. The aromatic hydrocarbon measurements were conducted with an automated sampler on Tenax-TA and Carbopack-B adsorbent tubes with heated inlet for one year. Samples were collected twice a week for two hours during daytime and two hours 1 during night-time. A thermal desorption unit, connected to a gas chromatograph and a mass 2 selective detector was used for sample preparation and analysis. Results indicated that the 3 monthly median total aromatic hydrocarbon concentrations ranged between 0.01 to 3.1 ppb. 4 Benzene levels did not exceed local air quality standards. Toluene was the most abundant 5 species, with an annual median concentration of 0.63 ppb. No statistically significant 6 differences in the concentrations measured during daytime and night-time were found and no distinct seasonal patterns were observed. Air mass back trajectory analysis proved that the lack of seasonal cycles could be attributed to patterns determining the origin of the air masses sampled. Aromatic hydrocarbon concentrations were in general significantly higher in air masses that passed over anthropocentrically impacted regions. Interspecies correlations and ratios gave some indications of the possible sources for the different aromatic hydrocarbons in the source regions defined in the paper. The highest contribution of aromatic hydrocarbon concentrations to ozone formation potential was also observed in plumes passing over anthropocentrically impacted regions.

Jaars, K.; Beukes, J. P.; van Zyl, P. G.; Venter, A. D.; Josipovic, M.; Pienaar, J. J.; Vakkari, Ville; Aaltonen, H.; Laakso, H.; Kulmala, M.; Tiitta, P.; Guenther, Alex B.; Hellen, H.; Laakso, L.; Hakola, H.

2014-07-11T23:59:59.000Z

209

Sensitivity of Tropospheric Chemical Composition to Halogen-Radical Chemistry Using a Fully Coupled Size-Resolved Multiphase Chemistry-Global Climate System: Halogen Distributions, Aerosol Composition, and Sensitivity of Climate-Relevant Gases  

SciTech Connect (OSTI)

Observations and model studies suggest a significant but highly non-linear role for halogens, primarily Cl and Br, in multiphase atmospheric processes relevant to tropospheric chemistry and composition, aerosol evolution, radiative transfer, weather, and climate. The sensitivity of global atmospheric chemistry to the production of marine aerosol and the associated activation and cycling of inorganic Cl and Br was tested using a size-resolved multiphase coupled chemistry/global climate model (National Center for Atmospheric Researchs Community Atmosphere Model (CAM); v3.6.33). Simulation results showed strong meridional and vertical gradients in Cl and Br species. The simulation reproduced most available observations with reasonable confidence permitting the formulation of potential mechanisms for several previously unexplained halogen phenomena including the enrichment of Br- in submicron aerosol, and the presence of a BrO maximum in the polar free troposphere. However, simulated total volatile Br mixing ratios were generally high in the troposphere. Br in the stratosphere was lower than observed due to the lack of long-lived organobromine species in the simulation. Comparing simulations using chemical mechanisms with and without reactive Cl and Br species demonstrated a significant temporal and spatial sensitivity of primary atmospheric oxidants (O3, HOx, NOx), CH4, and non-methane hydrocarbons (NMHCs) to halogen cycling. Simulated O3 and NOx were globally lower (65% and 35%, respectively, less in the planetary boundary layer based on median values) in simulations that included halogens. Globally, little impact was seen in SO2 and non-sea-salt SO42- processing due to halogens. Significant regional differences were evident: The lifetime of nss-SO42- was extended downwind of large sources of SO2. The burden and lifetime of DMS (and its oxidation products) were lower by a factor of 5 in simulations that included halogens, versus those without, leading to a 20% reduction in nss-SO42- in the southern hemisphere planetary boundary layer based on median values.

Long, M.; Keene, W. C.; Easter, Richard C.; Sander, Rolf; Liu, Xiaohong; Kerkweg, A.; Erickson, D.

2014-04-07T23:59:59.000Z

210

Plasma-induced conversion of surface-adsorbed hydrocarbons  

SciTech Connect (OSTI)

Experimental results are reported for an electrical device for direct conversion of methane into higher hydrocarbons. A microchannel plate is excited with electrons from a photoemissive source, and electron impact ionization of methane on the inner surfaces of the microchannels creates an ion feedback process. The resulting low-density plasma creates higher hydrocarbons when charged particles impact the surfaces at grazing incidence. The production Of C{sub 2} to C{sub 8}-containing gases was noted, with a selectivity for C{sub 2} of 39% in one case. The proportions of converted products and the conversion rates depend upon the electrical voltage, the microchannel geometry, and the operating pressure. Conversion rates increase with operating pressure.

Sackinger, W.M.

1992-07-01T23:59:59.000Z

211

Plasma-induced conversion of surface-adsorbed hydrocarbons  

SciTech Connect (OSTI)

Experimental results are reported for an electrical device for direct conversion of methane into higher hydrocarbons. A microchannel plate is excited with electrons from a photoemissive source, and electron impact ionization of methane on the inner surfaces of the microchannels creates an ion feedback process. The resulting low-density plasma creates higher hydrocarbons when charged particles impact the surfaces at grazing incidence. The production Of C{sub 2} to C{sub 8}-containing gases was noted, with a selectivity for C{sub 2} of 39% in one case. The proportions of converted products and the conversion rates depend upon the electrical voltage, the microchannel geometry, and the operating pressure. Conversion rates increase with operating pressure.

Sackinger, W.M.

1992-01-01T23:59:59.000Z

212

Biological Conversion of Sugars to Hydrocarbons Technology Pathway  

SciTech Connect (OSTI)

In support of the Bioenergy Technologies Office, the National Renewable Energy Laboratory (NREL) and the Pacific Northwest National Laboratory (PNNL) are undertaking studies of biomass conversion technologies to identify barriers and target research toward reducing conversion costs. Process designs and preliminary economic estimates for each of these pathway cases were developed using rigorous modeling tools (Aspen Plus and Chemcad). These analyses incorporated the best information available at the time of development, including data from recent pilot and bench-scale demonstrations, collaborative industrial and academic partners, and published literature and patents. This technology pathway case investigates the biological conversion of biomass derived sugars to hydrocarbon biofuels, utilizing data from recent literature references and information consistent with recent pilot scale demonstrations at NREL. Technical barriers and key research needs have been identified that should be pursued for the pathway to become competitive with petroleum-derived gasoline, diesel and jet range hydrocarbon blendstocks.

Davis, Ryan; Biddy, Mary J.; Tan, Eric; Tao, Ling; Jones, Susanne B.

2013-03-31T23:59:59.000Z

213

Estimating The Thermodynamics And Kinetics Of Chlorinated Hydrocarbon Degradation  

SciTech Connect (OSTI)

Many different degradation reactions of chlorinated hydrocarbons are possible in natural ground waters. In order to identify which degradation reactions are important, a large number of possible reaction pathways must be sorted out. Recent advances in ab initio electronic structure methods have the potential to help identify relevant environmental degradation reactions by characterizing the thermodynamic properties of all relevant contaminant species and intermediates for which experimental data is usually not available, as well as provide activation energies for relevant pathways. In this paper, strategies based on ab initio electronic structure methods for estimating thermochemical and kinetic properties of reactions with chlorinated hydrocarbons are presented. Particular emphasis is placed on strategies that are computationally fast and can be used for large organochlorine compounds such as 4,4?-DDT.

Bylaska, Eric J.

2006-08-01T23:59:59.000Z

214

Algal Lipid Extraction and Upgrading to Hydrocarbons Technology Pathway  

SciTech Connect (OSTI)

In support of the Bioenergy Technologies Office, the National Renewable Energy Laboratory (NREL) and the Pacific Northwest National Laboratory (PNNL) are undertaking studies of biomass conversion technologies to identify barriers and target research toward reducing conversion costs. Process designs and preliminary economic estimates for each of these pathway cases were developed using rigorous modeling tools (Aspen Plus and Chemcad). These analyses incorporated the best information available at the time of development, including data from recent pilot and bench-scale demonstrations, collaborative industrial and academic partners, and published literature and patents. This technology pathway case investigates the cultivation of algal biomass followed by further lipid extraction and upgrading to hydrocarbon biofuels. Technical barriers and key research needs have been assessed in order for the algal lipid extraction and upgrading pathway to be competitive with petroleum-derived gasoline, diesel and jet range hydrocarbon blendstocks.

Davis, Ryan; Biddy, Mary J.; Jones, Susanne B.

2013-03-31T23:59:59.000Z

215

Method for removing hydrocarbon contaminants from solid materials  

DOE Patents [OSTI]

A system for removing hydrocarbons from solid materials. Contaminated solids are combined with a solvent (preferably terpene based) to produce a mixture. The mixture is washed with water to generate a purified solid product (which is removed from the system) and a drainage product. The drainage product is separated into a first fraction (consisting mostly of contaminated solvent) and a second fraction (containing solids and water). The first fraction is separated into a third fraction (consisting mostly of contaminated solvent) and a fourth fraction (containing residual solids and water). The fourth fraction is combined with the second fraction to produce a sludge which is separated into a fifth fraction (containing water which is ultimately reused) and a sixth fraction (containing solids). The third fraction is then separated into a seventh fraction (consisting of recovered solvent which is ultimately reused) and an eighth fraction (containing hydrocarbon waste).

Bala, Gregory A. (Idaho Falls, ID); Thomas, Charles P. (Idaho Falls, ID)

1995-01-01T23:59:59.000Z

216

Apparatus for removing hydrocarbon contaminants from solid materials  

DOE Patents [OSTI]

A system for removing hydrocarbons from solid materials. Contaminated solids are combined with a solvent (preferably terpene based) to produce a mixture. The mixture is washed with water to generate a purified solid product (which is removed from the system) and a drainage product. The drainage product is separated into a first fraction (consisting mostly of contaminated solvent) and a second fraction (containing solids and water). The first fraction is separated into a third fraction (consisting mostly of contaminated solvent) and a fourth fraction (containing residual solids and water). The fourth fraction is combined with the second fraction to produce a sludge which is separated into a fifth fraction (containing water which is ultimately reused) and a sixth fraction (containing solids). The third fraction is then separated into a seventh fraction (consisting of recovered solvent which is ultimately reused) and an eighth fraction (containing hydrocarbon waste).

Bala, Gregory A. (Idaho Falls, ID); Thomas, Charles P. (Idaho Falls, ID)

1996-01-01T23:59:59.000Z

217

Process for partial oxidation of a hydrocarbon-containing fuel  

SciTech Connect (OSTI)

This patent describes a process for partial oxidation of a hydrocarbon-containing fuel comprising supplying an oxygen-containing gas and a hydrocarbon-containing fuel to a gasification zone through a concentric arrangement of three oxygen channels and one fuel channel, and oxidizing the fuel and producing auto-thermically a gaseous stream containing synthesis gas, the oxygen-containing gas being supplied through the central channel of the concentric arrangement at a velocity of 21-42 m/sec and through the first concentric channel encircling the central channel at a velocity of 60-120 m/sec, fuel being supplied through the second concentric channel encircling the first channel at a velocity of 3.0-3.8 m/sec, and oxygen-containing gas being supplied through the third concentric channel encircling the second channel at a velocity of 60-120 m/sec.

Martens, F.J.A.; Hasenack, H.J.A.

1988-12-06T23:59:59.000Z

218

Catalysts for conversion of methane to higher hydrocarbons  

DOE Patents [OSTI]

Catalysts for converting methane to higher hydrocarbons such as ethane and ethylene in the presence of oxygen at temperatures in the range of about 700.degree. to 900.degree. C. are described. These catalysts comprise calcium oxide or gadolinium oxide respectively promoted with about 0.025-0.4 mole and about 0.1-0.7 mole sodium pyrophosphate. A preferred reaction temperature in a range of about 800.degree. to 850.degree. C. with a preferred oxygen-to-methane ratio of about 2:1 provides an essentially constant C.sub.2 hydrocarbon yield in the range of about 12 to 19 percent over a period of time greater than about 20 hours.

Siriwardane, Ranjani V. (Morgantown, WV)

1993-01-01T23:59:59.000Z

219

Composite catalyst for carbon monoxide and hydrocarbon oxidation  

DOE Patents [OSTI]

A method and composition for the complete oxidation of carbon monoxide and/or hydrocarbon compounds. The method involves reacting the carbon monoxide and/or hydrocarbons with an oxidizing agent in the presence of a metal oxide composite catalyst. The catalyst is prepared by combining fluorite-type oxygen ion conductors with active transition metals. The fluorite oxide, selected from the group consisting of cerium oxide, zirconium oxide, thorium oxide, hafnium oxide, and uranium oxide, and may be doped by alkaline earth and rare earth oxides. The transition metals, selected from the group consisting of molybdnum, copper, cobalt, maganese, nickel, and silver, are used as additives. The atomic ratio of transition metal to fluorite oxide is less than one.

Liu, Wei (Cambridge, MA); Flytzani-Stephanopoulos, Maria (Winchester, MA)

1996-01-01T23:59:59.000Z

220

Composite catalyst for carbon monoxide and hydrocarbon oxidation  

DOE Patents [OSTI]

A method and composition are disclosed for the complete oxidation of carbon monoxide and/or hydrocarbon compounds. The method involves reacting the carbon monoxide and/or hydrocarbons with an oxidizing agent in the presence of a metal oxide composite catalyst. The catalyst is prepared by combining fluorite-type oxygen ion conductors with active transition metals. The fluorite oxide, selected from the group consisting of cerium oxide, zirconium oxide, thorium oxide, hafnium oxide, and uranium oxide, and may be doped by alkaline earth and rare earth oxides. The transition metals, selected from the group consisting of molybdenum, copper, cobalt, manganese, nickel, and silver, are used as additives. The atomic ratio of transition metal to fluorite oxide is less than one.

Liu, W.; Flytzani-Stephanopoulos, M.

1996-03-19T23:59:59.000Z

Note: This page contains sample records for the topic "non-methane hydrocarbons nmhc" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Apparatus for removing hydrocarbon contaminants from solid materials  

DOE Patents [OSTI]

A system is described for removing hydrocarbons from solid materials. Contaminated solids are combined with a solvent (preferably terpene based) to produce a mixture. The mixture is washed with water to generate a purified solid product (which is removed from the system) and a drainage product. The drainage product is separated into a first fraction (consisting mostly of contaminated solvent) and a second fraction (containing solids and water). The first fraction is separated into a third fraction (consisting mostly of contaminated solvent) and a fourth fraction (containing residual solids and water). The fourth fraction is combined with the second fraction to produce a sludge which is separated into a fifth fraction (containing water which is ultimately reused) and a sixth fraction (containing solids). The third fraction is then separated into a seventh fraction (consisting of recovered solvent which is ultimately reused) and an eighth fraction (containing hydrocarbon waste). 4 figs.

Bala, G.A.; Thomas, C.P.

1996-02-13T23:59:59.000Z

222

Method for removing hydrocarbon contaminants from solid materials  

DOE Patents [OSTI]

A system is described for removing hydrocarbons from solid materials. Contaminated solids are combined with a solvent (preferably terpene based) to produce a mixture. The mixture is washed with water to generate a purified solid product (which is removed from the system) and a drainage product. The drainage product is separated into a first fraction (consisting mostly of contaminated solvent) and a second fraction (containing solids and water). The first fraction is separated into a third fraction (consisting mostly of contaminated solvent) and a fourth fraction (containing residual solids and water). The fourth fraction is combined with the second fraction to produce a sludge which is separated into a fifth fraction (containing water which is ultimately reused) and a sixth fraction (containing solids). The third fraction is then separated into a seventh fraction (consisting of recovered solvent which is ultimately reused) and an eighth fraction (containing hydrocarbon waste). 4 figs.

Bala, G.A.; Thomas, C.P.

1995-10-03T23:59:59.000Z

223

Fact #825: June 16, 2014 Tier 3 Non-Methane Organic Gases Plus...  

Energy Savers [EERE]

organic gases (NMOG) and nitrogen oxides (NOx) that new light vehicles with gasoline engines are allowed to produce for model years 2017 to 2025. These standards apply to...

224

Fact #825: June 16, 2014 Tier 3 Non-Methane Organic Gases Plus Nitrogen  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-UpHeat PumpRecord ofESPCofConstructionofFYOxide Emission Standards, Model Years 2017-2025

225

Preliminary investigation of the nature of hydrocarbon migration and entrapment  

E-Print Network [OSTI]

structures. The charge time for commercial hydrocarbon accumulation is much longer in oil-water systems than in oil-gas-water systems. Faults are classified into charging faults and ?back doors? ? faults other than charging faults in stacked fault...-bounded reservoirs. The lower the displacement pressure of a fault, the higher its updip oil transportation ability. The downdip oil transportation ability of a fault is usually low and cannot cause commercial downdip oil accumulation. Back doors affect both...

Bai, Jianyong

2004-09-30T23:59:59.000Z

226

Direct production of fractionated and upgraded hydrocarbon fuels from biomass  

SciTech Connect (OSTI)

Multistage processing of biomass to produce at least two separate fungible fuel streams, one dominated by gasoline boiling-point range liquids and the other by diesel boiling-point range liquids. The processing involves hydrotreating the biomass to produce a hydrotreatment product including a deoxygenated hydrocarbon product of gasoline and diesel boiling materials, followed by separating each of the gasoline and diesel boiling materials from the hydrotreatment product and each other.

Felix, Larry G.; Linck, Martin B.; Marker, Terry L.; Roberts, Michael J.

2014-08-26T23:59:59.000Z

227

Polycyclic aromatic hydrocarbon distributions in Mississippi Fan sediments  

E-Print Network [OSTI]

/ / / / / / glg. 4. Diag~am showing the morphology and lithologic bed associations of a submarine fan (adapted from IIANER, 1971). 16 indicative of land-sourced organic matter even in the intraslope basins. Furthermore, KENNICUTT et ai, (1986a) concluded.... Sandberg, B. A. , University of Colorado Chairman of Advisory Committee: Dr. James M. Brooks Polycyclic aromatic hydrocarbon (PAH) distributions in Upper Pleistocene sediments of the Mississippi Fan and two intraslope basins in the Gulf of Mexico...

Sandberg, William Allan

1986-01-01T23:59:59.000Z

228

Irregular spacing of heat sources for treating hydrocarbon containing formations  

DOE Patents [OSTI]

A method for treating a hydrocarbon containing formation includes providing heat input to a first section of the formation from one or more heat sources located in the first section. Fluids are produced from the first section through a production well located at or near the center of the first section. The heat sources are configured such that the average heat input per volume of formation in the first section increases with distance from the production well.

Miller, David Scott (Katy, TX); Uwechue, Uzo Philip (Houston, TX)

2012-06-12T23:59:59.000Z

229

THE INFRARED SPECTROSCOPY OF NEUTRAL POLYCYCLIC AROMATIC HYDROCARBON CLUSTERS  

SciTech Connect (OSTI)

The mid-infrared spectra of neutral homogeneous polycyclic aromatic hydrocarbon (PAH) clusters have been computed using density functional theory including an empirical correction for dispersion. The C-H out-of-plane bending modes are redshifted for all the clusters considered in this work. The magnitude of the redshift and the peak broadening are dependent on PAH size, shape, and on the PAH arrangement in the cluster.

Ricca, Alessandra [Carl Sagan Center, SETI Institute, 189 Bernardo Avenue, Suite 100, Mountain View, CA 94043 (United States); Bauschlicher, Charles W. Jr. [Entry Systems and Technology Division, Mail Stop 230-3, NASA Ames Research Center, Moffett Field, CA 94035 (United States); Allamandola, Louis J., E-mail: Alessandra.Ricca-1@nasa.gov, E-mail: Charles.W.Bauschlicher@nasa.gov [Space Science Division, Mail Stop 245-6, NASA Ames Research Center, Moffett Field, CA 94035 (United States)

2013-10-10T23:59:59.000Z

230

The Formation of Nitriles in Hydrocarbon-Rich Atmospheres  

E-Print Network [OSTI]

as the hydrocarbons ethane (C2H6), acetylene (C2H2), ethyl- ene (C2H4), methylacetylene (CH3CCH), propane (C3H8), methylacetylene (CH3CCH), propane (C3H8), and diacetylene (C4H2).3 Even though the above molecules. Nitriles can be hydrolyzed and react via multistep synthesis ultimately to amino acids, thus pro

Kaiser, Ralf I.

231

Method and apparatus for production of subsea hydrocarbon formations  

DOE Patents [OSTI]

A well tender system for controlling, separating, storing and offloading well fluids produced from subsea hydrocarbon formations. The system comprises a vertically aligned series of tethered cylindrical tanks which are torsionally stabilized by flexible catenary production riser and expert riser bundles, and serviced by separate catenary pipe bundles. Piles are secured to the seabed, each pile assembly being pivotally connected to a lower rigid tendon, which is in turn connected to tendons arranged about the periphery of the interconnected cylindrical tanks.

Blandford, Joseph W. (15 Mott La., Houston, TX 77024)

1992-01-01T23:59:59.000Z

232

Method and apparatus for production of subsea hydrocarbon formations  

DOE Patents [OSTI]

A well tender system for controlling, separating, storing and offloading well fluids produced from subsea hydrocarbon formations. The system comprises a vertically aligned series of tethered cylindrical tanks which are torsionally stabilized by flexible catenary production riser and export riser bundles, and serviced by separate catenary pipe bundles. Piles are secured to the seabed, each pile assembly being pivotally connected to a lower rigid tendon, which is in turn connected to tendons arranged about the periphery of the interconnected cylindrical tanks.

Blandford, Joseph W. (15 Mott La., Houston, TX 77024)

1994-01-01T23:59:59.000Z

233

Production of valuable hydrocarbons by flash pyrolysis of oil shale  

DOE Patents [OSTI]

A process for the production of gas and liquid hydrocarbons from particulated oil shale by reaction with a pyrolysis gas at a temperature of from about 700/sup 0/C to about 1100/sup 0/C, at a pressure of from about 400 psi to about 600 psi, for a period of about 0.2 second to about 20 seconds. Such a pyrolysis gas includes methane, helium, or hydrogen. 3 figs., 3 tabs.

Steinberg, M.; Fallon, P.T.

1985-04-01T23:59:59.000Z

234

Aerobic microorganism for the degradation of chlorinated aliphatic hydrocarbons  

DOE Patents [OSTI]

A chlorinated aliphatic hydrocarbon-degrading microorganism, having American Type Culture Collection accession numbers ATCC 53570 and 53571, in a biologically pure culture aseptically collected from a deep subsurface habitat and enhanced, mineralizes trichloroethylene and tetrachloroethylene to HCl, H.sub.2 O and Co.sub.2 under aerobic conditions stimulated by methane, acetate, methanol, tryptone-yeast extract, propane and propane-methane.

Fliermans, Carl B. (Augusta, GA)

1989-01-01T23:59:59.000Z

235

Thermocatalytic CO2-Free Production of Hydrogen from Hydrocarbon Fuels  

SciTech Connect (OSTI)

The main objective of this project is the development of an economically viable thermocatalytic process for production of hydrogen and carbon from natural gas or other hydrocarbon fuels with minimal environmental impact. The three major technical goals of this project are: (1) to accomplish efficient production of hydrogen and carbon via sustainable catalytic decomposition of methane or other hydrocarbons using inexpensive and durable carbon catalysts, (2) to obviate the concurrent production of CO/CO{sub 2} byproducts and drastically reduce CO{sub 2} emissions from the process, and (3) to produce valuable carbon products in order to reduce the cost of hydrogen production The important feature of the process is that the reaction is catalyzed by carbon particulates produced in the process, so no external catalyst is required (except for the start-up operation). This results in the following advantages: (1) no CO/CO{sub 2} byproducts are generated during hydrocarbon decomposition stage, (2) no expensive catalysts are used in the process, (3) several valuable forms of carbon can be produced in the process depending on the process conditions (e.g., turbostratic carbon, pyrolytic graphite, spherical carbon particles, carbon filaments etc.), and (4) CO{sub 2} emissions could be drastically reduced (compared to conventional processes).

University of Central Florida

2004-01-30T23:59:59.000Z

236

Hydrocarbon reforming catalyst material and configuration of the same  

DOE Patents [OSTI]

A hydrocarbon reforming catalyst material comprising a catalyst support impregnated with catalyst is provided for reforming hydrocarbon fuel gases in an electrochemical generator. Elongated electrochemical cells convert the fuel to electrical power in the presence of an oxidant, after which the spent fuel is recirculated and combined with a fresh hydrocarbon feed fuel forming the reformable gas mixture which is fed to a reforming chamber containing a reforming catalyst material, where the reforming catalyst material includes discrete passageways integrally formed along the length of the catalyst support in the direction of reformable gas flow. The spent fuel and/or combusted exhaust gases discharged from the generator chamber transfer heat to the catalyst support, which in turn transfers heat to the reformable gas and to the catalyst, preferably via a number of discrete passageways disposed adjacent one another in the reforming catalyst support. The passageways can be slots extending inwardly from an outer surface of the support body, which slots are partly defined by an exterior confining wall. According to a preferred embodiment, the catalyst support is non-rigid, porous, fibrous alumina, wherein the fibers are substantially unsintered and compressible, and the reforming catalyst support is impregnated, at least in the discrete passageways with Ni and MgO, and has a number of internal slot passageways for reformable gas, the slot passageways being partly closed by a containing outer wall.

Singh, Prabhakar (Export, PA); Shockling, Larry A. (Plum Borough, PA); George, Raymond A. (Pittsburgh, PA); Basel, Richard A. (Plub Borough, PA)

1996-01-01T23:59:59.000Z

237

Federal Environmental Regulations Impacting Hydrocarbon Exploration, Drilling, and Production Operations  

SciTech Connect (OSTI)

Waste handling and disposal from hydrocarbon exploration, drilling, and production are regulated by the US Environmental Protection Agency (EPA) through federal and state regulations and/or through implementation of federal regulations. Some wastes generated in these operations are exempt under the Resource Conservation and Recovery Act (RCRA) but are not exempt under the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA), Superfund Amendments and Reauthorization Act (SARA), and other federal environmental laws. Exempt wastes remain exempt only if they are not mixed with hazardous wastes or hazardous substances. Once mixture occurs, the waste must be disposed as a hazardous material in an approved hazardous waste disposal facility. Before the Clean Air Act as amended in 1990, air emissions from production, storage, steam generation, and compression facilities associated with hydrocarbon exploration, drilling, and production industry were not regulated. A critical proposed regulatory change which will significantly effect Class II injection wells for disposal of produced brine and injection for enhanced oil recovery is imminent. Federal regulations affecting hydrocarbon exploration, drilling and production, proposed EPA regulatory changes, and a recent significant US Court of Appeals decision are covered in this report. It appears that this industry will, in the future, fall under more stringent environmental regulations leading to increased costs for operators.

Carroll, Herbert B.; Johnson, William I.

1999-04-27T23:59:59.000Z

238

Paleotopography and hydrocarbon accumulation: Williston, Powder River, and Denver basins  

SciTech Connect (OSTI)

Recent geomorphic analyses of 1:24,000 scale topographic maps in the three major basins of the northern Great Plains have disclosed a persistent system of basement paleotopographic features that trend north-northeast throughout the region. Superimposed across this system and subtly influenced by it, are the northwesterly trending Laramide structural features. Paleozoic depositional patterns have been strongly influenced by the paleoridge and trough system formed by the north-northeast features. Mesozoic deposition has also been affected by the ancient subsurface system but in a more subtle manner. Many of the Paleozoic and Mezoxoic hydrocarbon locations in the three basins appear to be the results of paleotopographic control on hydrocarbon accumulation sites. This affect ranges from Paleozoic reef sites in the Williston basin through paleotrough localization of Pennsylvanian Minnelusa production in the Powder River basin to fractured Cretaceous Niobrara production at the Silo field in the Denver basin. Basement paleotopography is the underlying factor in all deposition and subsequent hydrocarbon migration in any basin. As such, it should be considered a major factor in the exploration for oil and gas.

Thomas, G.E. (Thomas and Associates, Denver, CO (United States))

1991-06-01T23:59:59.000Z

239

Hydrocarbon reforming catalyst material and configuration of the same  

DOE Patents [OSTI]

A hydrocarbon reforming catalyst material comprising a catalyst support impregnated with catalyst is provided for reforming hydrocarbon fuel gases in an electrochemical generator. Elongated electrochemical cells convert the fuel to electrical power in the presence of an oxidant, after which the spent fuel is recirculated and combined with a fresh hydrocarbon feed fuel forming the reformable gas mixture which is fed to a reforming chamber containing a reforming catalyst material, where the reforming catalyst material includes discrete passageways integrally formed along the length of the catalyst support in the direction of reformable gas flow. The spent fuel and/or combusted exhaust gases discharged from the generator chamber transfer heat to the catalyst support, which in turn transfers heat to the reformable gas and to the catalyst, preferably via a number of discrete passageways disposed adjacent one another in the reforming catalyst support. The passageways can be slots extending inwardly from an outer surface of the support body, which slots are partly defined by an exterior confining wall. According to a preferred embodiment, the catalyst support is non-rigid, porous, fibrous alumina, wherein the fibers are substantially unsintered and compressible, and the reforming catalyst support is impregnated, at least in the discrete passageways with Ni and MgO, and has a number of internal slot passageways for reformable gas, the slot passageways being partly closed by a containing outer wall. 5 figs.

Singh, P.; Shockling, L.A.; George, R.A.; Basel, R.A.

1996-06-18T23:59:59.000Z

240

Method and apparatus for monitoring a hydrocarbon-selective catalytic reduction device  

DOE Patents [OSTI]

A method for monitoring a hydrocarbon-selective catalytic reactor device of an exhaust aftertreatment system of an internal combustion engine operating lean of stoichiometry includes injecting a reductant into an exhaust gas feedstream upstream of the hydrocarbon-selective catalytic reactor device at a predetermined mass flowrate of the reductant, and determining a space velocity associated with a predetermined forward portion of the hydrocarbon-selective catalytic reactor device. When the space velocity exceeds a predetermined threshold space velocity, a temperature differential across the predetermined forward portion of the hydrocarbon-selective catalytic reactor device is determined, and a threshold temperature as a function of the space velocity and the mass flowrate of the reductant is determined. If the temperature differential across the predetermined forward portion of the hydrocarbon-selective catalytic reactor device is below the threshold temperature, operation of the engine is controlled to regenerate the hydrocarbon-selective catalytic reactor device.

Schmieg, Steven J; Viola, Michael B; Cheng, Shi-Wai S; Mulawa, Patricia A; Hilden, David L; Sloane, Thompson M; Lee, Jong H

2014-05-06T23:59:59.000Z

Note: This page contains sample records for the topic "non-methane hydrocarbons nmhc" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Apparatus and method for rapid separation and detection of hydrocarbon fractions in a fluid stream  

DOE Patents [OSTI]

An apparatus and method for rapid fractionation of hydrocarbon phases in a sample fluid stream are disclosed. Examples of the disclosed apparatus and method include an assembly of elements in fluid communication with one another including one or more valves and at least one sorbent chamber for removing certain classifications of hydrocarbons and detecting the remaining fractions using a detector. The respective ratios of hydrocarbons are determined by comparison with a non separated fluid stream.

Sluder, Charles S.; Storey, John M.; Lewis, Sr., Samuel A.

2013-01-22T23:59:59.000Z

242

A study of the structure of the hydrocarbons of primary hard-coal tar  

SciTech Connect (OSTI)

The hydrocarbons isolated from primary hard-coal (G/sub 6/ gas coal) tar have been investigated by a combination of physicochemical and chemical methods. It has been established that the hydrocarbons boiling up to 573 K are mainly aliphatic, hydroaromatic, and naphthenic and are aromatic only to a smaller degree. Molecular and presumable structural formulas of the oxygen compounds isolated from the 473-573 K hydrocarbon fraction have been derived.

Platonov, V.V.; Gerasimova, N.I.; Ivleva, L.N.; Klyavina, O.A.; Vishnyakov, S.N.

1985-01-01T23:59:59.000Z

243

E-Print Network 3.0 - aromatic hydrocarbons part Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

By Abbas Firoozabadi Reservoir Engineering... Research Institute (RERI), Palo Alto Yale University, New Haven New phase formation is an integral part... of hydrocarbon...

244

E-Print Network 3.0 - adsorption equilibria hydrocarbons Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of water vapor and hydrocarbons by activated carbon beds: thermo- dynamic model for adsorption... of binary adsorption equilibria of solvent and water vapor on acti- Z .vated...

245

E-Print Network 3.0 - aromatic hydrocarbons adducted Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

hydrocarbon... to its high reactivity toward DNA and cellular proteins. The major acrolein-DNA adduct, -hydrox- ypropano... -hy- droxynonenal, and acrolein, that readily form...

246

E-Print Network 3.0 - aliphatic hydrocarbons formed Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

4.3. Lack of Aliphatic Hydrocarbons... might be interpreted as the results of contamination that introduced ... Source: Brocks, Jochen J. - Research School of Earth Sciences,...

247

E-Print Network 3.0 - aromatic hydrocarbon neutrals Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

RANDHIR S. MAKKAR and KARL J. ROCKNE... --Polycyclic aromatic hydrocarbon (PAH) contamination of the environment represents a serious threat to the health... bioremediation...

248

E-Print Network 3.0 - aromatic hydrocarbon pah-degrading Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

degradation Summary: Removal of polycyclic aromatic hydrocarbons (PAHs) from sewage sludge by anaerobic degradation N... , terminate in the sludge, and can be released to the...

249

E-Print Network 3.0 - abundant accessible hydrocarbons Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Functionalization: An Energy Frontier Research... such as hydrocarbons, dioxygen, water, carbon dioxide and dihydrogen are central to new technologies for the use... of...

250

E-Print Network 3.0 - aromatic hydrocarbon exhaust Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Page: << < 1 2 3 4 5 > >> 1 Quantification of Local Ozone Production Attributable to Automobile Hydrocarbon Emissions Summary: : Acetylenes: Aromatics: 57 15 2 26 A breakdown of 17...

251

E-Print Network 3.0 - active natural hydrocarbon Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Biology and Medicine 2 Quantification of Local Ozone Production Attributable to Automobile Hydrocarbon Emissions Summary: Quantification of Local Ozone Production Attributable...

252

Nonthermal plasma systems and methods for natural gas and heavy hydrocarbon co-conversion  

DOE Patents [OSTI]

A reactor for reactive co-conversion of heavy hydrocarbons and hydrocarbon gases and includes a dielectric barrier discharge plasma cell having a pair of electrodes separated by a dielectric material and passageway therebetween. An inlet is provided for feeding heavy hydrocarbons and other reactive materials to the passageway of the discharge plasma cell, and an outlet is provided for discharging reaction products from the reactor. A packed bed catalyst may optionally be used in the reactor to increase efficiency of conversion. The reactor can be modified to allow use of a variety of light sources for providing ultraviolet light within the discharge plasma cell. Methods for upgrading heavy hydrocarbons are also disclosed.

Kong, Peter C.; Nelson, Lee O.; Detering, Brent A.

2005-05-24T23:59:59.000Z

253

E-Print Network 3.0 - aromatic hydrocarbons pah Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Sciences and Ecology 19 Deuterated PAHs in space To appear as Summary: fluorescence from UV pumped, large polycyclic aromatic hydrocarbon molecules (PAHs, Allamandola et al.,...

254

E-Print Network 3.0 - aromatic hydrocarbons pahs Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Sciences and Ecology 19 Deuterated PAHs in space To appear as Summary: fluorescence from UV pumped, large polycyclic aromatic hydrocarbon molecules (PAHs, Allamandola et al.,...

255

E-Print Network 3.0 - aromatic hydrocarbon pah Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Sciences and Ecology 19 Deuterated PAHs in space To appear as Summary: fluorescence from UV pumped, large polycyclic aromatic hydrocarbon molecules (PAHs, Allamandola et al.,...

256

E-Print Network 3.0 - aromatic hydrocarbons distributed Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Engineering 23 2006-01-0201 Speciated Hydrocarbon Emissions from an Automotive Diesel Summary: the relative distribution among the bins, the data in Figure 2 are...

257

E-Print Network 3.0 - active aryl hydrocarbon Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Receptors in Fishes Summary: the aryl hydrocarbon receptor (AHR), through which dioxins and dioxin-like compounds cause altered gene... -methylcholanthrene AHH: aryl...

258

E-Print Network 3.0 - aromatic hydrocarbon compounds Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

bases in Iraq and Afghanistan that lack Summary: Compounds Toxic Organic Halogenated Dioxins Furans (dioxins) Polycyclic Aromatic Hydrocarbons found... and detected all of the...

259

E-Print Network 3.0 - aryl hydrocarbon receptor-dna Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Receptors in Fishes Summary: the aryl hydrocarbon receptor (AHR), through which dioxins and dioxin-like compounds cause altered gene... -methylcholanthrene AHH: aryl...

260

E-Print Network 3.0 - aromatic polycyclic hydrocarbons Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

coal, oil, gas... called aromatic hydrocarbons. These include harmful pollutants like dioxins, PCBs and a group called Source: Rock, Chris - Department of Biological Sciences,...

Note: This page contains sample records for the topic "non-methane hydrocarbons nmhc" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

E-Print Network 3.0 - aromatic hydrocarbons modulate Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

S0045-6535(02)00145-5 Summary: Abstract Polycyclic aromatic hydrocarbons (PAHs) and dioxins are lipophilic organic pollutants occurring... absorption, pig INTRODUCTION...

262

E-Print Network 3.0 - aromatic hydrocarbon aryl Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Receptors in Fishes Summary: the aryl hydrocarbon receptor (AHR), through which dioxins and dioxin-like compounds cause altered gene... -methylcholanthrene AHH: aryl...

263

E-Print Network 3.0 - aryl hydrocarbon monooxygenase Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Receptors in Fishes Summary: the aryl hydrocarbon receptor (AHR), through which dioxins and dioxin-like compounds cause altered gene... -methylcholanthrene AHH: aryl...

264

E-Print Network 3.0 - aromatic hydrocarbon tracers Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

S0045-6535(02)00145-5 Summary: Abstract Polycyclic aromatic hydrocarbons (PAHs) and dioxins are lipophilic organic pollutants occurring... absorption, pig INTRODUCTION...

265

E-Print Network 3.0 - aryl hydrocarbon receptor-regulated Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

classes of the aryl hydrocarbon receptor (AHR). A grander objective is to provide... pollutants is a direct consequence of their interactions with the aryl ... Source: Bradfield,...

266

E-Print Network 3.0 - aryl hydrocarbon receptor-1 Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

PARENTAL FACTORS ON GAMETE CONDITION AND VIABILITY Summary: . 15. 16. 17. 18-21. 22. Pollutants - petroleum aromatic hydrocarbons, aryl Pollutants - pesticides... high levels of...

267

E-Print Network 3.0 - aryl hydrocarbon nuclear Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Receptors in Fishes Summary: the aryl hydrocarbon receptor (AHR), through which dioxins and dioxin-like compounds cause altered gene... -methylcholanthrene AHH: aryl...

268

E-Print Network 3.0 - ahr aryl hydrocarbon Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Receptors in Fishes Summary: the aryl hydrocarbon receptor (AHR), through which dioxins and dioxin-like compounds cause altered gene... -methylcholanthrene AHH: aryl...

269

E-Print Network 3.0 - aromatic hydrocarbon water-soluble Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

S0045-6535(02)00145-5 Summary: Abstract Polycyclic aromatic hydrocarbons (PAHs) and dioxins are lipophilic organic pollutants occurring... with their lipophilicity and water...

270

E-Print Network 3.0 - aromatic hydrocarbons phahs Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

WH, Caton JE. 1983. Extraction of polycyclic aromatic hydrocarbons for qualitative analysis. In... : Handbook of Polycyclic Aromatic ... Source: Rock, Chris - Department of...

271

E-Print Network 3.0 - aryl hydrocarbon receptor-independent Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

PARENTAL FACTORS ON GAMETE CONDITION AND VIABILITY Summary: . 15. 16. 17. 18-21. 22. Pollutants - petroleum aromatic hydrocarbons, aryl Pollutants - pesticides... high levels of...

272

E-Print Network 3.0 - aryl hydrocarbon receptor-mediated Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

4 TOXICOLOGICAL SCIENCES 106(1), 8392 (2008) doi:10.1093toxscikfn149 Summary: ). Analysis of aryl hydrocarbon receptor-mediated signaling during physiological hypoxia reveals...

273

E-Print Network 3.0 - aryl hydrocarbon receptor-dependent Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Receptors in Fishes Summary: the aryl hydrocarbon receptor (AHR), through which dioxins and dioxin-like compounds cause altered gene... -methylcholanthrene AHH: aryl...

274

E-Print Network 3.0 - aryl hydrocarbon receptor Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Receptors in Fishes Summary: the aryl hydrocarbon receptor (AHR), through which dioxins and dioxin-like compounds cause altered gene... -methylcholanthrene AHH: aryl...

275

E-Print Network 3.0 - aromatic hydrocarbon-contaminated soil...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

soil... hydrocarbon degraders, and polycyclic aromatic ... Source: Ma, Lena - Soil and Water Science Department, University of Florida Collection: Environmental Sciences and...

276

aromatic hydrocarbon-degrading marine: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Aromatic Hydrocarbons in Soil Microcosms: A Review CiteSeer Summary: Copyright 2001 Kansas State University Key words: bioremediation, denitrification, PAHs, sulfidogenesis...

277

NOAA Data Report ERL PMEL-2 LOW MOLECULAR WEIGHT HYDROCARBON CONCENTRATIONS (C1 -c4),  

E-Print Network [OSTI]

or imply that the NOAA Environ- mental Research Laboratories approves, recommends, or endorses any pro) variations in the dissolved gaseous hydrocarbon fraction composed of methane, ethane, ethene, propane

278

The Impact of Low Octane Hydrocarbon Blending Streams on "E85...  

Broader source: Energy.gov (indexed) [DOE]

IMPACT OF LOW OCTANE HYDROCARBON BLENDING STREAMS ON "E85" ENGINE OPTIMIZATION Jim Szybist and Brian West Oak Ridge National Laboratory October 19, 2012 Acknowledgement This...

279

Naphthenic/paraffinic hydrocarbons of residual lube stock from West Siberian crudes  

SciTech Connect (OSTI)

The lube stocks from West Siberian crudes are characterized by high contents of aromatic hydrocarbons and by high viscosity indexes of the naphthenic/paraffinic and aromatic hydrocarbons. Mass spectrometric analysis showed that isoparaffins account for one-third of the total naphthenic/paraffinic hydrocarbons. The study showed that the naphthenic/paraffinic hydrocarbons of the residual lube stock from West Siberia crudes, even with a variation of molecular weight over broad limits, are relatively uniform in composition. They consist mainly of isoparaffinic and monocyclic and noncondensed naphthenic structures.

Detusheva, E.P.; Bogdanov, Sh.K.; Khramtsova, L.P.; Nekrasova, A.V.; Shkol'nikov, V.M.

1983-03-01T23:59:59.000Z

280

E-Print Network 3.0 - aggravates hydrocarbon oil-induced Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

systems. For iron-based superconductors... "Can simple hydrocarbon molecular solids superconduct?" Unlike many well established high temperature... of superconductivity in...

Note: This page contains sample records for the topic "non-methane hydrocarbons nmhc" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

E-Print Network 3.0 - anaerobic hydrocarbon degradation Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

for: anaerobic hydrocarbon degradation Page: << < 1 2 3 4 5 > >> 1 APPLIED AND ENVIRONMENTAL MICROBIOLOGY, 0099-22409704.00 0 Summary: . Rabus, R., and F. Widdel. 1995....

282

Chlorinated hydrocarbons in flatfishes from the Southern California, USA, Bight  

SciTech Connect (OSTI)

Although inputs of chlorinated hydrocarbon compounds to the Southern California Bight (SCB) are presently low, historical deposits represent a source of bioaccumulation potential to sediment-associated fauna. To assess this bioaccumulation potential, 14 chlorinated hydrocarbon classes were measured in livers of three species of flatfish collected from 63 randomly selected sites on the coastal shelf between Point Conception and the United States-Mexico international border. Tissue contamination was widespread throughout the SCB, but was limited to just two chlorinated hydrocarbon classes. Virtually 100% of Pacific sanddab (Citharichthys sordidus) and longfin sanddab (Citharichthys xanthostigma) populations were estimated to be contaminated with dichlorodiphenyltrichloroethane (total DDT = sum of o.p{prime} and p,p{prime} isomers of DDT + dichlorodiphenyldichloroethylene [DDE] + dichlorodiphenyldichloroethane [DDD]) and/or polychlorinated biphenyls (total PCBs). Total DDT also contaminated the majority (64%) of the Dover sole (Microstomus pacificus) population in the SCB. Total PCB measurements in tissues of SCB flatfish were dominated by 12 congeners (52, 66, 87, 101, 105, 118, 128, 138, 153, 170, 180, and 187), which averaged 95% of the combined mass of the 27 congeners analyzed. Sediment concentrations accounted for most of the variability observed in tissue concentrations for 8 of these 12 congeners and total PCBs. Normalized sediment concentrations were also significantly correlated to normalized tissue concentrations for total DDT and p,p{prime}-DDE. Tissue concentrations measured in this study from reference areas of the SCB were compared to tissue concentrations measured form reference areas in studies conducted in 1977 and 1985. Total DDT and total PCB liver concentrations were found to have decreased one to two orders of magnitude in pacific and longfin sanddabs between 1985 and 1994. Total DDT and total PCB liver concentrations decreased 5- to 35-fold in Dover sole between 1977 and 1994.

Schiff, K.; Allen, M.J.

2000-06-01T23:59:59.000Z

283

Catalysts and process for liquid hydrocarbon fuel production  

DOE Patents [OSTI]

The present invention provides a novel process and system in which a mixture of carbon monoxide and hydrogen synthesis gas, or syngas, is converted into hydrocarbon mixtures composed of high quality gasoline components, aromatic compounds, and lower molecular weight gaseous olefins in one reactor or step. The invention utilizes a novel molybdenum-zeolite catalyst in high pressure hydrogen for conversion, as well as a novel rhenium-zeolite catalyst in place of the molybdenum-zeolite catalyst, and provides for use of the novel catalysts in the process and system of the invention.

White, Mark G; Liu, Shetian

2014-12-09T23:59:59.000Z

284

A study of the solubility of mercury in liquid hydrocarbons  

E-Print Network [OSTI]

mercury by precipitating HgS out of solution and measuring the metcury activity on a Gieger counter. A second but similar method used by Moser and Voigt used metallic Hg&cs which was obtained by reduction of mercumus nitrate with hypophosphorus acid...A STUDY OF THE SOLUBILITY OF MERCURY IN LIQUID HYDROCARBONS A Thesis by DAVID LARIhKR MCFARLANE Submitted to the Oflice of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER...

McFarlane, David Larimer

1991-01-01T23:59:59.000Z

285

Hydrocarbon analysis of shrimp from oil polluted waters  

E-Print Network [OSTI]

is unaccounted for (Anon. , 1980b). This oil, plus oil from other sources, could become a potential threat to the Gulf shrimp industry. One problem concerning shrimp is that all Gulf shrimp are harvested using a bottom trawl. Tar, or weathered oil, collects...HYDROCARBON ANALYSIS OF SHRIMP FROM OIL POLLUTED WATERS A Thesis by BERNARD JOHN DEWITT III Submitted to the Graduate College of Texas A&M University in partial fulfilment of the requirement for the degree of MASTER OF SCIENCE May 1982...

DeWitt, Bernard John

1982-01-01T23:59:59.000Z

286

Occurrence of chlorinated polynuclear aromatic hydrocarbons in tap water  

SciTech Connect (OSTI)

Organic compounds in tap waters were extracted by a modified continuous liquid-liquid extractor and analyzed by computerized gas chromatography/mass spectrometry using a fused silica capillary column. The results indicate the presence of monochlorinated derivatives of naphthalene, dibenzofuran, fluorene, fluorenone, phenanthrene, and fluoranthene and dichlorinated derivatives of naphthalene, phenanthrene, and fluoranthene. The parent polynuclear aromatic hydrocarbons (PAHs) and their oxygenated derivatives such as fluorenone and anthraquinone were also found. It was demonstrated that chlorinated PAHs (Cl-PAHs) were really present in tap waters at 10/sup -1/-10/sup -2/ ng/L levels.

Shiraishi, H.; Pilkington, N.H.; Otsuki, A.; Fuwa, K.

1985-07-01T23:59:59.000Z

287

Mach 2 combustion characteristics of hydrogen/hydrocarbon fuel mixtures  

SciTech Connect (OSTI)

The combustion of H/sub 2//CH/sub 4/ and H/sub 2//C/sub 2/H/sub 4/ mixtures containing 10 to 70 vol pct hydrocarbon at combustor inlet Mach number 2 and temperatures 2000 to 4000 R is investigated experimentally, applying direct-connect test hardware and techniques similar to those described by Diskin and Northam (1987) in the facilities of the NASA Langley Hypersonic Propulsion Branch. The experimental setup, procedures, and data-reduction methods are described; and the results are presented in extensive tables and graphs and characterized in detail. Fuel type and mixture are found to have little effect on the wall heating rate measured near the combustor exit, but H/sub 2//C/sub 2/H/sub 4/ is shown to burn much more efficiently than H/sub 2//CH/sub 4/, with no pilot-off blowout equivalence ratios greater than 0.5. It is suggested that H/sub 2//hydrocarbon mixtures are feasible fuels (at least in terms of combustion efficiency) for scramjet SSTO vehicles operating at freestream Mach numbers above 4.

Diskin, G.S.; Jachimowski, C.J.; Northam, G.B.; Bell, R.A.

1987-01-01T23:59:59.000Z

288

Oxygen sensor for monitoring gas mixtures containing hydrocarbons  

DOE Patents [OSTI]

A gas sensor measures O.sub.2 content of a reformable monitored gas containing hydrocarbons H.sub.2 O and/or CO.sub.2, preferably in association with an electrochemical power generation system. The gas sensor has a housing communicating with the monitored gas environment and carries the monitored gas through an integral catalytic hydrocarbon reforming chamber containing a reforming catalyst, and over a solid electrolyte electrochemical cell used for sensing purposes. The electrochemical cell includes a solid electrolyte between a sensor electrode that is exposed to the monitored gas, and a reference electrode that is isolated in the housing from the monitored gas and is exposed to a reference gas environment. A heating element is also provided in heat transfer communication with the gas sensor. A circuit that can include controls operable to adjust operations via valves or the like is connected between the sensor electrode and the reference electrode to process the electrical signal developed by the electrochemical cell. The electrical signal varies as a measure of the equilibrium oxygen partial pressure of the monitored gas. Signal noise is effectively reduced by maintaining a constant temperature in the area of the electrochemical cell and providing a monitored gas at chemical equilibria when contacting the electrochemical cell. The output gas from the electrochemical cell of the sensor is fed back into the conduits of the power generating system.

Ruka, Roswell J. (Pittsburgh, PA); Basel, Richard A. (Pittsburgh, PA)

1996-01-01T23:59:59.000Z

289

Libyan Paleozoic: A review of the factors limiting hydrocarbon potential  

SciTech Connect (OSTI)

Of the three main Paleozoic basins - Ghadames, Murquz, and Kufra - only the Ghadames and its continuation into Algeria, the Illizi (or Fort Polignac) basin, has yielded hydrocarbons in significant quantity. The Paleozoic on the Cyrenaica platform and basement of the Sirte basin has a potential not fully considered. The paleogeography of the Paleozoic system is reviewed to illustrate the extent to which inherited and reactivated basement-controlled structures have influenced later Paleozoic sedimentation and hence the distribution of source rocks, reservoirs, and seals. In all instances, the source rocks are restricted to shales of the Tanezufft Formation or occur in the Upper Devonian Aouinet Oeunine Formation. Multiple fine-grained sequences serve as seals in all the fields. The reservoirs range from the well-cemented but highly fractured Cambrian-Ordovician Gargaf sandstones to the Acacus-Tadrart clastics to the fine-grained Lower Carboniferous Tahara Sandstone. The principal plays are associated with minor structures, and stratigraphic trapping mechanisms play a minor role. The average field size (excluding the Sirte basin) is approximately 80 million bbl of recoverable oil. Paleozoic structural plays in the Sirte basin and the Cyrenaica platform include reactivated infra-Cambrian faults. The lower Paleozoic accumulations of the Murzuq basin are tied to large structures. With the exception of local areas in the Ghadames basin, the Paleozoic succession remains a stratigraphic frontier province - still incompletely explored but with several interesting possibilities for large amounts of stratigraphically trapped hydrocarbons.

Kanes, W.H.; Mairn, A.E.M.; Aburawi, R.M.

1988-08-01T23:59:59.000Z

290

Preliminary Economics for Hydrocarbon Fuel Production from Cellulosic Sugars  

SciTech Connect (OSTI)

Biorefinery process and economic models built in CHEMCAD and a preliminary, genome-scale metabolic model for the oleaginous yeast Lipomyces starkeyi were used to simulate the bioconversion of corn stover to lipids, and the upgrading of these hydrocarbon precursors to diesel and jet fuel. The metabolic model was based on the recently released genome sequence for L. starkeyi and on metabolic pathway information from the literature. The process model was based on bioconversion, lipid extraction, and lipid oil upgrading data found in literature, on new laboratory experimental data, and on yield predictions from the preliminary L. starkeyi metabolic model. The current plant gate production cost for a distillate-range hydrocarbon fuel was estimated by the process model Base Case to be $9.5/gallon ($9.0 /gallon of gasoline equivalent) with assumptions of 2011$, 10% internal return on investment, and 2205 ton/day dry feed rate. Opportunities for reducing the cost to below $5.0/gallon, such as improving bioconversion lipid yield and hydrogenation catalyst selectivity, are presented in a Target Case. The process and economic models developed for this work will be updated in 2014 with new experimental data and predictions from a refined metabolic network model for L. starkeyi. Attaining a production cost of $3.0/gallon will require finding higher value uses for lignin other than power generation, such as conversion to additional fuel or to a co-product.

Collett, James R.; Meyer, Pimphan A.; Jones, Susanne B.

2014-05-18T23:59:59.000Z

291

Hydrous metal oxide catalysts for oxidation of hydrocarbons  

SciTech Connect (OSTI)

This report describes work performed at Sandia under a CRADA with Shell Development of Houston, Texas aimed at developing hydrous metal oxide (HMO) catalysts for oxidation of hydrocarbons. Autoxidation as well as selective oxidation of 1-octene was studied in the presence of HMO catalysts based on known oxidation catalysts. The desired reactions were the conversion of olefin to epoxides, alcohols, and ketones, HMOs seem to inhibit autoxidation reactions, perhaps by reacting with peroxides or radicals. Attempts to use HMOs and metal loaded HMOs as epoxidation catalysts were unsuccessful, although their utility for this reaction was not entirely ruled out. Likewise, alcohol formation from olefins in the presence of HMO catalysts was not achieved. However, this work led to the discovery that acidified HMOs can lead to carbocation reactions of hydrocarbons such as cracking. An HMO catalyst containing Rh and Cu that promotes the reaction of {alpha}-olefins with oxygen to form methyl ketones was identified. Although the activity of the catalyst is relatively low and isomerization reactions of the olefin simultaneously occur, results indicate that these problems may be addressed by eliminating mass transfer limitations. Other suggestions for improving the catalyst are also made. 57 refs.

Miller, J.E.; Dosch, R.G.; McLaughlin, L.I. [Sandia National Labs., Albuquerque, NM (United States). Process Research Dept.

1993-07-01T23:59:59.000Z

292

Oxygen sensor for monitoring gas mixtures containing hydrocarbons  

DOE Patents [OSTI]

A gas sensor measures O{sub 2} content of a reformable monitored gas containing hydrocarbons, H{sub 2}O and/or CO{sub 2}, preferably in association with an electrochemical power generation system. The gas sensor has a housing communicating with the monitored gas environment and carries the monitored gas through an integral catalytic hydrocarbon reforming chamber containing a reforming catalyst, and over a solid electrolyte electrochemical cell used for sensing purposes. The electrochemical cell includes a solid electrolyte between a sensor electrode that is exposed to the monitored gas, and a reference electrode that is isolated in the housing from the monitored gas and is exposed to a reference gas environment. A heating element is also provided in heat transfer communication with the gas sensor. A circuit that can include controls operable to adjust operations via valves or the like is connected between the sensor electrode and the reference electrode to process the electrical signal developed by the electrochemical cell. The electrical signal varies as a measure of the equilibrium oxygen partial pressure of the monitored gas. Signal noise is effectively reduced by maintaining a constant temperature in the area of the electrochemical cell and providing a monitored gas at chemical equilibria when contacting the electrochemical cell. The output gas from the electrochemical cell of the sensor is fed back into the conduits of the power generating system. 4 figs.

Ruka, R.J.; Basel, R.A.

1996-03-12T23:59:59.000Z

293

Distillation sequence for the purification and recovery of hydrocarbons  

DOE Patents [OSTI]

This invention is an improved distillation sequence for the separation and purification of ethylene from a cracked gas. A hydrocarbon feed enters a C2 distributor column. The top of the C2 distributor column is thermally coupled to an ethylene distributor column, and the bottoms liquid of a C2 distributor column feeds a deethanizer column. The C2 distributor column utilizes a conventional reboiler. The top of the ethylene distributor is thermally coupled with a demethanizer column, and the bottoms liquid of the ethylene distributor feeds a C2 splitter column. The ethylene distributor column utilizes a conventional reboiler. The deethanizer and C2 splitter columns are also thermally coupled and operated at a substantially lower pressure than the C2 distributor column, the ethylene distributor column, and the demethanizer column. Alternatively, a hydrocarbon feed enters a deethanizer column. The top of the deethanizer is thermally coupled to an ethylene distributor column, and the ethylene distributor column utilizes a conventional reboiler. The top of the ethylene distributor column is thermally coupled with a demethanizer column, and the bottoms liquid of the ethylene distributor column feeds a C2 splitter column. The C2 splitter column operates at a pressure substantially lower than the ethylene distributor column, the demethanizer column, and the deethanizer column.

Reyneke, Rian (Katy, TX); Foral, Michael (Aurora, IL); Papadopoulos, Christos G. (Naperville, IL); Logsdon, Jeffrey S. (Naperville, IL); Eng, Wayne W. Y. (League City, TX); Lee, Guang-Chung (Houston, TX); Sinclair, Ian (Warrington, GB)

2007-12-25T23:59:59.000Z

294

Catalytic autothermal reforming of hydrocarbon fuels for fuel cells.  

SciTech Connect (OSTI)

Fuel cell development has seen remarkable progress in the past decade because of an increasing need to improve energy efficiency as well as to address concerns about the environmental consequences of using fossil fuel for producing electricity and for propulsion of vehicles [1]. The lack of an infrastructure for producing and distributing H{sub 2} has led to a research effort to develop on-board fuel processing technology for reforming hydrocarbon fuels to generate H{sub 2} [2]. The primary focus is on reforming gasoline, because a production and distribution infrastructure for gasoline already exists to supply internal combustion engines [3]. Existing reforming technology for the production of H{sub 2} from hydrocarbon feedstocks used in large-scale manufacturing processes, such as ammonia synthesis, is cost prohibitive when scaled down to the size of the fuel processor required for transportation applications (50-80 kWe) nor is it designed to meet the varying power demands and frequent shutoffs and restarts that will be experienced during normal drive cycles. To meet the performance targets required of a fuel processor for transportation applications will require new reforming reactor technology developed to meet the volume, weight, cost, and operational characteristics for transportation applications and the development of new reforming catalysts that exhibit a higher activity and better thermal and mechanical stability than reforming catalysts currently used in the production of H{sub 2} for large-scale manufacturing processes.

Krumpelt, M.; Krause, T.; Kopasz, J.; Carter, D.; Ahmed, S.

2002-01-11T23:59:59.000Z

295

Tectonics and hydrocarbon potential of the Barents Megatrough  

SciTech Connect (OSTI)

Interpretation of geophysical data shows that the geological structure of the Eastern Barents Shelf, named Barents Megatrough (BM), extends sublongitudinally almost from the Baltic shield to the Franz Josef Land archipelago. The earth crust within the axis part of the BM is attenuated up to 28-30 km, whereas in adjacent areas its thickness exceeds 35 km. The depression is filled with of more than 15 km of Upper Paleozoic, Mesozoic, and Cenozoic sediments overlying a folded basement of probable Caledonian age. Paleozoic sediments, with exception of the Upper Permian, are composed mainly of carbonates and evaporites. Mesozoic-Cenozoic sediments are mostly terrigenous. The major force in the development of the BM was due to extensional tectonics. Three rifting phases are recognizable: Late Devonian-Early Carboniferous, Early Triassic, and Jurassic-Early Cretaceous. The principal features of the geologic structure and evolution of the BM during the late Paleozoic-Mesozoic correlate well with those of the Sverdup basin, Canadian Arctic. Significant quantity of Late Jurassic-Early Cretaceous basaltic dikes and sills were intruded within Triassic sequence during the third rifting phase. This was probably the main reason for trap disruption and hydrocarbon loss from Triassic structures. Lower Jurassic and Lower Cretaceous reservoir sandstones are most probably the main future objects for oil and gas discoveries within the BM. Upper Jurassic black shales are probably the main source rocks of the BM basin, as well as excellent structural traps for hydrocarbon fluids from the underlying sediments.

Baturin, D.; Vinogradov, A.; Yunov, A. (LARGE International, Moscow (USSR))

1991-08-01T23:59:59.000Z

296

Geochemical Prospecting of Hydrocarbons in Frontier Basins of India* By  

E-Print Network [OSTI]

India has 26 sedimentary basins with a basinal area of approximately 1.8x 10 6 km 2 (excluding deep waters), out of which seven are producing basins and two have proven potential. Exploration efforts in other basins, called frontier basins are in progress. These basins are characterized by varied geology, age, tectonics, and depositional environments. Hydrocarbon shows in many of these basins are known, and in few basins oil and gas have flowed in commercial /non-commercial quantities. Within the framework of India Hydrocarbon Vision 2025 and New Exploration Licensing Policy, there is a continuous increase in area under active exploration. The asset management concept with multi-disciplinary teams has created a demand for synergic application of risk-reduction technologies, including surface geochemical surveys. National Geophysical Research Institute (NGRI), Hyderabad, India has initiated/planned surface geochemical surveys composed of gas chromatographic and carbon isotopic analyses in few of the frontier basins of India. The adsorbed soil gas data in one of the basins (Saurashtra basin, Gujarat) has shown varied concentrations of CH4 to C4H10. The C1 concentration varies between 3 to 766 ppb and ??C2+, 1 to 543 ppb. This basin has thin soil cover and the Mesozoic sediments (probable source rocks) are overlain by thick cover of Deccan Traps. The scope and perspective of geochemical surveys in frontier basins of India are presented here.

B. Kumar; D. J. Patil; G. Kalpana; C. Vishnu Vardhan

297

The spatial scales, distribution, and intensity of natural marine hydrocarbon seeps near Coal Oil Point, California  

E-Print Network [OSTI]

area) are not well established, either globally or within strong source areas such as near Coal OilThe spatial scales, distribution, and intensity of natural marine hydrocarbon seeps near Coal Oil hydrocarbon seepage from marine environments is an important source of methane and other gases

Washburn, Libe

298

Geologic control of natural marine hydrocarbon seep emissions, Coal Oil Point seep field, California  

E-Print Network [OSTI]

geology and gas-phase (methane) seepage for the Coal Oil Point (COP) seep field, one of the worldORIGINAL Geologic control of natural marine hydrocarbon seep emissions, Coal Oil Point seep field's largest and best-studied marine oil and gas seep fields, located over a producing hydrocarbon reservoir

Luyendyk, Bruce

299

Fracturing controlled primary migration of hydrocarbon fluids during1 heating of organic-rich shales2  

E-Print Network [OSTI]

understand primary migration of16 hydrocarbon fluids in very low permeability source rock. Cracks nucleate.e. the transport of hydrocarbon fluids from extremely low39 permeability source rocks in which they are generated the source rock is42 formed is buried, the organic material is transformed into complex high molecular weight

300

Desiccant bed on hydrocarbon charged to and removed from underground (salt) cavern  

SciTech Connect (OSTI)

A hydrocarbon fluid storage system is described which consists of in operable conjunction: a cavern formed within an underground salt strata below a ground surface, the cavern comprises a lower liquid volume of saturated sodium chloride storage brine and an upper fluid volume of wet hydrocarbon storage fluid, surface fluid handling means; conduit connecting the lower storage brine and upper storage hydrocarbon fluid with the surface fluid handling means, of fluid transfer means enabling transfer of brine and hydrocarbon fluid from the surface to the cavern and from the cavern to the surface, such that brine can be added to or withdrawn from the lower brine volume and hydrocarbon fluids can be added to or withdrawn from the upper hydrocarbon fluid volume, and at least one desiccant drier means positioned at the surface in operable association with the surface fluid handling means whereby the wet hydrocarbon fluid upon withdrawal from the cavern passes through the desiccant drier means and thereby becomes dry, and dry hydrocarbon fluid intended for storage passes through the desiccant drier prior to entering the storage cavern and thereby becomes wet.

Washer, S.P.

1986-06-03T23:59:59.000Z

Note: This page contains sample records for the topic "non-methane hydrocarbons nmhc" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Aryl hydrocarbon receptor polymorphisms and dioxin resistance in Atlantic killifish (Fundulus heteroclitus)  

E-Print Network [OSTI]

Aryl hydrocarbon receptor polymorphisms and dioxin resistance in Atlantic killifish (Fundulus aromatic hydrocarbons (HAHs) such as 2,3,7,8-tetrachlorodibenzo-p-dioxin (TCDD) as well as polynuclear and that the frequencies of the major allele types differ between dioxin- sensitive and dioxin-resistant populations

Hahn, Mark E.

302

Assessment of natural and anthropogenic hydrocarbon inputs using PAHs as tracers.  

E-Print Network [OSTI]

to produce liquid hydrocarbons and water. -- Coal-to-liquids (CTLs) are derived either by pyrolysis of coal authors accept that conventional oil resources are at an advanced stage of depletion and that liquid fuels is a heterogeneous mix of hydrocarbons that remain in liquid phase when extracted to the surface. -- Condensate

303

Interactive physically-based structural modeling of hydrocarbon systems Mael Bosson a,  

E-Print Network [OSTI]

using scripts and/or modeling tools. For many systems, however, these building methods may models of hydrocarbon systems. As the user edits the geometry of the system, atomic positions are alsoInteractive physically-based structural modeling of hydrocarbon systems Mael Bosson a, , Sergei

Redon, Stephane - NRIA Grenoble

304

Biofuel from Bacteria and Sunlight: Shewanella as an Ideal Platform for Producing Hydrocarbons  

SciTech Connect (OSTI)

Broad Funding Opportunity Announcement Project: The University of Minnesota is developing clean-burning, liquid hydrocarbon fuels from bacteria. The University is finding ways to continuously harvest hydrocarbons from a type of bacteria called Shewanella by using a photosynthetic organism to constantly feed Shewanella the sugar it needs for energy and hydrocarbon production. The two organisms live and work together as a system. Using Shewanella to produce hydrocarbon fuels offers several advantages over traditional biofuel production methods. First, it eliminates many of the time-consuming and costly steps involved in growing plants and harvesting biomass. Second, hydrocarbon biofuels resemble current petroleum-based fuels and would therefore require few changes to the existing fuel refining and distribution infrastructure in the U.S.

None

2010-01-01T23:59:59.000Z

305

Time sequenced heating of multiple layers in a hydrocarbon containing formation  

DOE Patents [OSTI]

A method for treating a hydrocarbon containing formation may include providing heat to a first hydrocarbon layer in the formation from a first heater located in an opening in the formation. The opening and the first heater may have a horizontal or inclined portion located in the first hydrocarbon layer and at least one connecting portion extending between the horizontal or inclined portion and the surface. Isolation material is placed in the opening such that the isolation material partially isolates the layer in which the horizontal or inclined portion of the first heater is located. An additional horizontal or inclined opening portion that extends from at least one of the connecting portions of the opening is formed in a second hydrocarbon layer. A second heater to provide heat the second hydrocarbon formation is placed in the additional substantially horizontal opening portion.

Goldberg, Bernard (Houston, TX); Hale, Arthur Herman (Houston, TX); Miller, David Scott (Katy, TX); Vinegar, Harold J. (Bellaire, TX)

2009-12-22T23:59:59.000Z

306

Method for cracking hydrocarbon compositions using a submerged reactive plasma system  

DOE Patents [OSTI]

A method is described for cracking a liquid hydrocarbon composition (e.g. crude oil) to produce a cracked hydrocarbon product. A liquid hydrocarbon composition is initially provided. An electrical arc is generated directly within the hydrocarbon composition so that the arc is entirely submerged in the composition. Arc generation is preferably accomplished using a primary and secondary electrode each having a first end submerged in the composition. The first ends of the electrodes are separated from each other to form a gap there between. An electrical potential is then applied to the electrodes to generate the arc within the gap. A reactive gas is thereafter delivered to the arc which forms a bubble around the arc. Gas delivery may be accomplished by providing a passageway through each electrode and delivering the gas through the passageways. The arc and gas cooperate to produce a plasma which efficiently cracks the hydrocarbon composition. 6 figs.

Kong, P.C.

1997-05-06T23:59:59.000Z

307

Method for cracking hydrocarbon compositions using a submerged reactive plasma system  

DOE Patents [OSTI]

A method for cracking a liquid hydrocarbon composition (e.g. crude oil) to produce a cracked hydrocarbon product. A liquid hydrocarbon composition is initially provided. An electrical arc is generated directly within the hydrocarbon composition so that the arc is entirely submerged in the composition. Arc generation is preferably accomplished using a primary and secondary electrode each having a first end submerged in the composition. The first ends of the electrodes are separated from each other to form a gap therebetween. An electrical potential is then applied to the electrodes to generate the arc within the gap. A reactive gas is thereafter delivered to the arc which forms a bubble around the arc. Gas delivery may be accomplished by providing a passageway through each electrode and delivering the gas through the passageways. The arc and gas cooperate to produce a plasma which efficiently cracks the hydrocarbon composition.

Kong, Peter C. (Idaho Falls, ID)

1997-01-01T23:59:59.000Z

308

Evidence of a Pathway to Hydrocarbon Nanoparticle Formation in Fusion Plasmas and its Impact on Tritium Inventory  

E-Print Network [OSTI]

Evidence of a Pathway to Hydrocarbon Nanoparticle Formation in Fusion Plasmas and its Impact on Tritium Inventory

309

Activated carbon and biochar amendments decrease pore-water concentrations of polycyclic aromatic hydrocarbons (PAHs) in sewage sludge  

E-Print Network [OSTI]

hydrocarbons (PAHs) in sewage sludge Patryk Oleszczuk a,b, , Sarah E. Hale a , Johannes Lehmann c , Gerard Polycyclic aromatic hydrocarbons Bioavailability Sewage sludge a b s t r a c t The aim of the research of polycyclic aromatic hydrocarbons (PAHs) in sewage sludge. Two different biochars (MSB and PMW) and two ACs

Lehmann, Johannes

310

Method and apparatus for hydrocarbon recovery from tar sands  

DOE Patents [OSTI]

A method and apparatus for utilizing tar sands having a broad range of bitumen content is disclosed. More particularly, tar sands are pyrolyzed in a cyclone retort with high temperature gases recycled from the cyclone retort to produce oil and hydrocarbon products. The spent tar sands are then burned at 2000/degree/F in a burner to remove residual char and produce a solid waste that is easily disposable. The process and apparatus have the advantages of being able to utilize tar sands having a broad range of bitumen content and the advantage of producing product gases that are free from combustion gases and thereby have a higher heating value. Another important advantage is rapid pyrolysis of the tar sands in the cyclone so as to effectively utilize smaller sized reactor vessels for reducing capitol and operating costs. 1 fig., 1 tab.

Westhoff, J.D.; Harak, A.E.

1988-05-04T23:59:59.000Z

311

Thermal performance of direct contact heat exchangers for mixed hydrocarbons  

SciTech Connect (OSTI)

This paper describes a physical and a mathematical model for evaluating the tray efficiencies for a direct contact heat exchanger (DCHX). The model is then used to determine the efficiencies for tests conducted on a 60kW sieve tray DCHX as heat is transferred from a geofluid (brine) to a working fluid (mixed hydrocarbons). It is assumed that there are three distinct regions in the column based on the state of the working fluid, as follows: Region I - Preheating with no vaporization; Region II - Preheating with moderate vaporization; and Region III - Major vaporization. The boundaries of these regions can be determined from the experimental data. In the model, mass balance and energy balance is written for a tray ''N'' in each of these regions. Finally, the ''tray efficiency'' or ''heat transfer'' effectiveness of the tray is calculated based on the definition that it is the ratio of the actual heat transfer to the maximum possible, thermodynamically.

Sharpe, L. Jr.; Coswami, D.Y.; Demuth, O.J.; Mines, G.

1985-01-01T23:59:59.000Z

312

Hydrocarbon cracking with yttrium exchanged zeolite y catalyst  

SciTech Connect (OSTI)

A process is described for cracking a gas oil boiling range hydrocarbon feedstock comprising the step of contacting the feedstock in a catalytic cracking zone under catalytic cracking conditions to produce convulsion products comprising gasoline with a catalyst composition. The process comprises: a Y crystalline aluminosilicate zeolite, having the structure of faujasite and having uniform pore diameters and a silica to alumina mole ratio of at least about 5; an inorganic oxide matrix; and the zeolite having been ion exchanged with a mixture of rare earths prior to compositing with the matrix; and the zeolite having been subsequently further ion exchanged with yttrium following compositing with the matrix, whereby the catalyst composition contains 0.30 to 3.0 wt% yttrium.

Lochow, C.F.; Kovacs, D.B.

1987-05-12T23:59:59.000Z

313

Heating hydrocarbon containing formations in a spiral startup staged sequence  

DOE Patents [OSTI]

Methods for treating a hydrocarbon containing formation are described herein. Methods may include treating a first zone of the formation. Treatment of a plurality of zones of the formation may be begun at selected times after the treatment of the first zone begins. The treatment of at least two successively treated zones may begin at a selected time after treatment of the previous zone begins. At least two of the successively treated zones may be adjacent to the zone treated previously. The successive treatment of the zones proceeds in an outward, substantially spiral sequence from the first zone so that the treatment of the zones may move substantially spirally outwards towards a boundary of the treatment area.

Vinegar, Harold J. (Bellaire, TX); Miller, David Scott (Katy, TX)

2009-12-15T23:59:59.000Z

314

Pyrochlore-type catalysts for the reforming of hydrocarbon fuels  

DOE Patents [OSTI]

A method of catalytically reforming a reactant gas mixture using a pyrochlore catalyst material comprised of one or more pyrochlores having the composition A.sub.2-w-xA'.sub.wA''.sub.xB.sub.2-y-zB'.sub.yB''.sub.zO.sub.7-.DELTA.. Distribution of catalytically active metals throughout the structure at the B site creates an active and well dispersed metal locked into place in the crystal structure. This greatly reduces the metal sintering that typically occurs on supported catalysts used in reforming reactions, and reduces deactivation by sulfur and carbon. Further, oxygen mobility may also be enhanced by elemental exchange of promoters at sites in the pyrochlore. The pyrochlore catalyst material may be utilized in catalytic reforming reactions for the conversion of hydrocarbon fuels into synthesis gas (H.sub.2+CO) for fuel cells, among other uses.

Berry, David A. (Morgantown, WV); Shekhawat, Dushyant (Morgantown, WV); Haynes, Daniel (Morgantown, WV); Smith, Mark (Morgantown, WV); Spivey, James J. (Baton Rouge, LA)

2012-03-13T23:59:59.000Z

315

Solution mining systems and methods for treating hydrocarbon containing formations  

DOE Patents [OSTI]

A method for treating an oil shale formation comprising nahcolite is disclosed. The method includes providing a first fluid to a portion of the formation through at least two injection wells. A second fluid is produced from the portion through at least one injection well until at least two injection wells are interconnected such that fluid can flow between the two injection wells. The second fluid includes at least some nahcolite dissolved in the first fluid. The first fluid is injected through one of the interconnected injection wells. The second fluid is produced from at least one of the interconnected injection wells. Heat is provided from one or more heaters to the formation to heat the formation. Hydrocarbon fluids are produced from the formation.

Vinegar, Harold J. (Bellaire, TX); de Rouffignac, Eric Pierre (Rijswijk, NL); Schoeling, Lanny Gene (Katy, TX)

2009-07-14T23:59:59.000Z

316

Thermodynamic properties of hydrocarbon liquids at high pressures and temperatures  

SciTech Connect (OSTI)

Understanding the organic/inorganic interface in the Earth's crust requires values of the thermodynamic properties of hydrocarbon species in crude oil, coal, and natural gas at elevated temperatures and pressures. Values of the apparent standard partial molal Gibbs free energies and enthalpies of formation and the standard partial molal entropies and heat capacities of these organic species can be computed as a function of temperature at 1 bar using the equations of state adopted by Helgeson et al (1991). The pressure dependence of the thermodynamic properties can be calculated from a modified version of the Parameters From Group Contributions (PFGC) equation of state. To improve the accuracy of these predictions, critical evaluation of high-pressure density experiments reported in the literature was used in the present study to characterize b[sub j] as a function of pressure and temperature. The revised PFGC equation of state permits accurate calculation of the standard partial molal volumes of the major hydrocarbon species in the aliphatic, aromatic, and naphthenic fractions of crude oil, as well as fatty acids, phenols, and naphthenic acids at temperatures and pressures to 500 C and 5 kbar. Combining the revised PFGC equation of state and parameters with the standard partial molal properties of these species at one bar and those of aqueous species and minerals permits calculation of the apparent standard partial molal Gibbs Free energies of reaction, and thus equilibrium constants for a wide variety of chemical equilibria among organic liquids, solids, and gases, aqueous species, and minerals at temperatures and pressures characteristic of both diagenetic and low-grade metamorphic processes in the Earth's crust.

Aagaard, P. (Univ. of Oslo (Norway). Dept. of Geology); Oelkers, E.H. (Univ. Paul Sabatier, Toulouse (France). Lab. de Geochimie); Helgeson, H.C. (Univ. of California, Berkeley, CA (United States). Dept. of Geology and Geophysics)

1992-01-01T23:59:59.000Z

317

Soil Iodine Determination in Deccan Syneclise, India: Implications for Near Surface Geochemical Hydrocarbon Prospecting  

SciTech Connect (OSTI)

The association of iodine with organic matter in sedimentary basins is well documented. High iodine concentration in soils overlying oil and gas fields and areas with hydrocarbon microseepage has been observed and used as a geochemical exploratory tool for hydrocarbons in a few studies. In this study, we measure iodine concentration in soil samples collected from parts of Deccan Syneclise in the west central India to investigate its potential application as a geochemical indicator for hydrocarbons. The Deccan Syneclise consists of rifted depositional sites with Gondwana-Mesozoic sediments up to 3.5 km concealed under the Deccan Traps and is considered prospective for hydrocarbons. The concentration of iodine in soil samples is determined using ICP-MS and the values range between 1.1 and 19.3 ppm. High iodine values are characteristic of the northern part of the sampled region. The total organic carbon (TOC) content of the soil samples range between 0.1 and 1.3%. The TOC correlates poorly with the soil iodine (r{sup 2} < 1), indicating a lack of association of iodine with the surficial organic matter and the possibility of interaction between the seeping hydrocarbons and soil iodine. Further, the distribution pattern of iodine compares well with two surface geochemical indicators: the adsorbed light gaseous hydrocarbons (methane through butane) and the propane-oxidizing bacterial populations in the soil. The integration of geochemical observations show the occurrence of elevated values in the northern part of the study area, which is also coincident with the presence of exposed dyke swarms that probably serve as conduits for hydrocarbon microseepage. The corroboration of iodine with existing geological, geophysical, and geochemical data suggests its efficacy as one of the potential tool in surface geochemical exploration of hydrocarbons. Our study supports Deccan Syneclise to be promising in terms of its hydrocarbon prospects.

Mani, Devleena, E-mail: devleenatiwari@ngri.res.in [National Geophysical Research Institute (Council of Scientific and Industrial Research) (India); Kumar, T. Satish [Oil India Limited (India); Rasheed, M. A.; Patil, D. J.; Dayal, A. M.; Rao, T. Gnaneshwar; Balaram, V. [National Geophysical Research Institute (Council of Scientific and Industrial Research) (India)

2011-03-15T23:59:59.000Z

318

Direct conversion of light hydrocarbon gases to liquid fuel. Final report No. 33  

SciTech Connect (OSTI)

Amoco oil Company, has investigated the direct, non-catalytic conversion of light hydrocarbon gases to liquid fuels (particularly methanol) via partial oxidation. The primary hydrocarbon feed used in these studies was natural gas. This report describes work completed in the course of our two-year project. In general we determined that the methanol yields delivered by this system were not high enough to make it economically attractive. Process variables studied included hydrocarbon feed composition, oxygen concentration, temperature and pressure effects, residence time, reactor design, and reactor recycle.

Kaplan, R.D.; Foral, M.J.

1992-05-16T23:59:59.000Z

319

Method for silicon carbide production by reacting silica with hydrocarbon gas  

DOE Patents [OSTI]

A method is described for producing silicon carbide particles using a silicon source material and a hydrocarbon. The method is efficient and is characterized by high yield. Finely divided silicon source material is contacted with hydrocarbon at a temperature of 400.degree. C. to 1000.degree. C. where the hydrocarbon pyrolyzes and coats the particles with carbon. The particles are then heated to 1100.degree. C. to 1600.degree. C. to cause a reaction between the ingredients to form silicon carbide of very small particle size. No grinding of silicon carbide is required to obtain small particles. The method may be carried out as a batch process or as a continuous process.

Glatzmaier, Gregory C. (Boulder, CO)

1994-01-01T23:59:59.000Z

320

Fuel-flexible partial oxidation reforming of hydrocarbons for automotive applications.  

SciTech Connect (OSTI)

Micro-reactor tests indicate that our partial oxidation catalyst is fuel-flexible and can reform conventional (gasoline and diesel) and alternative (ethanol, methanol, natural gas) fuels to hydrogen rich product gases with high hydrogen selectivity. Alcohols are reformed at lower temperatures (< 600 C) while alkanes and unsaturated hydrocarbons require slightly higher temperatures. Cyclic hydrocarbons and aromatics have also been reformed at relatively low temperatures, however, a different mechanism appears to be responsible for their reforming. Complex fuels like gasoline and diesel, which are mixtures of a broad range of hydrocarbons, require temperatures of > 700 C for maximum hydrogen production.

Ahmed, S.; Carter, J. D.; Kopasz, J. P.; Krumpelt, M.; Wilkenhoener, R.

1999-06-07T23:59:59.000Z

Note: This page contains sample records for the topic "non-methane hydrocarbons nmhc" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Method of treating emissions of a hybrid vehicle with a hydrocarbon absorber and a catalyst bypass system  

DOE Patents [OSTI]

A method of treating emissions from an internal combustion engine of a hybrid vehicle includes directing a flow of air created by the internal combustion engine when the internal combustion engine is spinning but not being fueled through a hydrocarbon absorber to collect hydrocarbons within the flow of air. When the hydrocarbon absorber is full and unable to collect additional hydrocarbons, the flow of air is directed through an electrically heated catalyst to treat the flow of air and remove the hydrocarbons. When the hydrocarbon absorber is not full and able to collect additional hydrocarbons, the flow of air is directed through a bypass path that bypasses the electrically heated catalyst to conserve the thermal energy stored within the electrically heated catalyst.

Roos, Bryan Nathaniel; Gonze, Eugene V; Santoso, Halim G; Spohn, Brian L

2014-01-14T23:59:59.000Z

322

Application of Metagenomics for Identification of Novel Petroleum Hydrocarbon Degrading Enzymes in Natural Asphalts from the Rancho La Brea Tar Pits  

E-Print Network [OSTI]

2010. Biodegradation of MTBE by Achromobacter xylosoxidansaromatic hydrocarbons and MTBE (Eixarch and Constanti, 2010,

Baquiran, Jean-Paul Mendoza

2010-01-01T23:59:59.000Z

323

Two-stage Catalytic Reduction of NOx with Hydrocarbons  

SciTech Connect (OSTI)

A two-stage system for the catalytic reduction of NO from lean-burn natural gas reciprocating engine exhaust is investigated. Each of the two stages uses a distinct catalyst. The first stage is oxidation of NO to NO{sub 2} and the second stage is reduction of NO{sub 2} to N{sub 2} with a hydrocarbon. The central idea is that since NO{sub 2} is a more easily reduced species than NO, it should be better able to compete with oxygen for the combustion reaction of hydrocarbon, which is a challenge in lean conditions. Early work focused on demonstrating that the N{sub 2} yield obtained when NO{sub 2} was reduced was greater than when NO was reduced. NO{sub 2} reduction catalysts were designed and silver supported on alumina (Ag/Al{sub 2}O{sub 3}) was found to be quite active, able to achieve 95% N{sub 2} yield in 10% O{sub 2} using propane as the reducing agent. The design of a catalyst for NO oxidation was also investigated, and a Co/TiO{sub 2} catalyst prepared by sol-gel was shown to have high activity for the reaction, able to reach equilibrium conversion of 80% at 300 C at GHSV of 50,000h{sup -1}. After it was shown that NO{sub 2} could be more easily reduced to N{sub 2} than NO, the focus shifted on developing a catalyst that could use methane as the reducing agent. The Ag/Al{sub 2}O{sub 3} catalyst was tested and found to be inactive for NOx reduction with methane. Through iterative catalyst design, a palladium-based catalyst on a sulfated-zirconia support (Pd/SZ) was synthesized and shown to be able to selectively reduce NO{sub 2} in lean conditions using methane. Development of catalysts for the oxidation reaction also continued and higher activity, as well as stability in 10% water, was observed on a Co/ZrO{sub 2} catalyst, which reached equilibrium conversion of 94% at 250 C at the same GHSV. The Co/ZrO{sub 2} catalyst was also found to be extremely active for oxidation of CO, ethane, and propane, which could potential eliminate the need for any separate oxidation catalyst. At every stage, catalyst synthesis was guided by the insights gained through detailed characterization of the catalysts using many surface and bulk analysis techniques such as X-ray diffraction, X-ray photoelectron spectroscopy, Temperature-programmed Reduction, Temperature programmed Desorption, and Diffuse Reflectance InfraRed Fourier Transform Spectroscopy as well as steady state reaction experiments. Once active catalysts for each stage had been developed, a physical mixture of the two catalysts was tested for the reduction of NO with methane in lean conditions. These experiments using a mixture of the catalysts produced N2 yields as high as 90%. In the presence of 10% water, the catalyst mixture produced 75% N{sub 2} yield, without any optimization. The dual catalyst system developed has the potential to be implemented in lean-burn natural gas engines for reducing NOx in lean exhaust as well as eliminating CO and unburned hydrocarbons without any fuel penalty or any system modifications. If funding continues, future work will focus on improving the hydrothermal stability of the system to bring the technology closer to application.

Umit S. Ozkan; Erik M. Holmgreen; Matthew M. Yung; Jonathan Halter; Joel Hiltner

2005-12-21T23:59:59.000Z

324

Complex conductivity tensor of anisotropic hydrocarbon-1 bearing shales and mudrocks2  

E-Print Network [OSTI]

to describe seismic and electromagnetic (EM) measurements in these anisotropic54 materials.55 Oil-shale to release their hydrocarbons. Hence, oil shales and58 mudrocks are typically water-wet, single- or dual

Torres-Verdín, Carlos

325

Hydrocarbon trapping mechanisms in the Miller Creek area of the Powder River Basin, Wyoming  

E-Print Network [OSTI]

'' 1975 43'W'79 ABSTRACT Hydrocarbon Trapoing Mechanisms in the Miller Creek Area of the Powder River Basin, Wyoming. (May 1975) Jennifer Ann Armstrong, B. S. , University of Texas at Austin Chairman of Advisory Committee: 17r. Robert. R. Berg...

Armstrong, Jennifer Ann

1975-01-01T23:59:59.000Z

326

Ten years of marine CSEM for hydrocarbon exploration Steven Constable1  

E-Print Network [OSTI]

Ten years of marine CSEM for hydrocarbon exploration Steven Constable1 ABSTRACT Marine controlled, several more surveys were carried out in the same region Constable and Srnka, 2007 , and within two years

Constable, Steve

327

Impact of retarded spark timing on engine combustion, hydrocarbon emissions, and fast catalyst light-off  

E-Print Network [OSTI]

An experimental study was performed to determine the effects of substantial spark retard on engine combustion, hydrocarbon (HC) emissions, feed gas enthalpy, and catalyst light-off. Engine experiments were conducted at ...

Hallgren, Brian E. (Brian Eric), 1976-

2005-01-01T23:59:59.000Z

328

Method for determining asphaltene stability of a hydrocarbon-containing material  

DOE Patents [OSTI]

A method for determining asphaltene stability in a hydrocarbon-containing material having solvated asphaltenes therein is disclosed. In at least one embodiment, it involves the steps of: (a) precipitating an amount of the asphaltenes from a liquid sample of the hydrocarbon-containing material with an alkane mobile phase solvent in a column; (b) dissolving a first amount and a second amount of the precipitated asphaltenes by changing the alkane mobile phase solvent to a final mobile phase solvent having a solubility parameter that is higher than the alkane mobile phase solvent; (c) monitoring the concentration of eluted fractions from the column; (d) creating a solubility profile of the dissolved asphaltenes in the hydrocarbon-containing material; and (e) determining one or more asphaltene stability parameters of the hydrocarbon-containing material.

Schabron, John F; Rovani, Jr., Joseph F

2013-02-05T23:59:59.000Z

329

From upstream to downstream: Megatrends and latest developments in Latin America`s hydrocarbons sector  

SciTech Connect (OSTI)

In recent years, Latin America`s hydrocarbons sector has been characterized by reorganization, revitalization, regional cooperation, environmental awakening, and steady expansion. The pattern of these changes, which appear to be the megatrends of the region`s hydrocarbons sector development, will continue during the rest of the 1990s. To further study the current situation and future prospects of Latin America`s hydrocarbons sector, we critically summarize in this short article the key issues in the region`s oil and gas development. These megatrends in Latin America`s hydrocarbons sector development will impact not only the future energy demand and supply in the region, but also global oil flows in the North American market and across the Pacific Ocean. Each country is individually discussed; pipelines to be constructed are discussed also.

Wu, Kang; Pezeshki, S.; McMahon, J.

1995-08-01T23:59:59.000Z

330

Underground storage of natural gas, liquid hydrocarbons, and carbon dioxide (Louisiana)  

Broader source: Energy.gov [DOE]

The Louisiana Department of Environmental Quality regulates the underground storage of natural gas or liquid hydrocarbons and carbon dioxide. Prior to the use of any underground reservoir for the...

331

Fouling of reverse osmosis membranes by hydrocarbonated and fluorinated surfactants contained in firefighting water  

E-Print Network [OSTI]

Title: Fouling of reverse osmosis membranes by hydrocarbonated and fluorinated surfactants osmosis efficiently treated the water from fire extinguishment. In this work we focused on the reverse surfactants [1]. Experimental results indicated that electrocoagulation and filtration followed by reverse

Paris-Sud XI, Université de

332

The methanol-to-hydrocarbons reaction : Influence of acid strength on the mechanism of olefin formation.  

E-Print Network [OSTI]

??The methanol-to-hydrocarbons (MTH) reaction is a flexible alternative step in the upgrading of natural gas, coal or biomass. By tuning the catalyst and process conditions, (more)

Erichsen, Marius Westgrd

2010-01-01T23:59:59.000Z

333

Hydrocarbon emissions in a homogeneous direct-injection spark engine : gasoline and gasohol  

E-Print Network [OSTI]

In order to better understand the effects on hydrocarbon emissions of loading, engine temperature, fuel type, and injection timing, a series of experiments was performed. The effect of loading was observed by running the ...

Tharp, Ronald S

2008-01-01T23:59:59.000Z

334

Black carbon in marine sediments : quantification and implications for the sorption of polycyclic aromatic hydrocarbons  

E-Print Network [OSTI]

Sorption is a key factor in determining the fate of polycyclic aromatic hydrocarbons (PAHs) in the environment. Here, PAH sorption is proposed as the sum of two mechanisms: absorption into a biogenic, organic carbon (OC) ...

Accardi-Dey, AmyMarie, 1976-

2003-01-01T23:59:59.000Z

335

Assessing the hydrocarbon emissions in a homogeneous direct injection spark ignited engine  

E-Print Network [OSTI]

For the purpose of researching hydrocarbon (HC) emissions in a direct-injection spark ignited (DISI) engine, five experiments were performed. These experiments clarified the role of coolant temperature, injection pressure, ...

Radovanovic, Michael S

2006-01-01T23:59:59.000Z

336

Effect of Sulfur and Hydrocarbon Fuels on Titanate/Ceria SOFC Anodes  

SciTech Connect (OSTI)

The purpose of the project is to develop low-cost, high-performance anodes that offer low polarization resistance as well as improved tolerance for nonidealities in anode environment such as redox cycles, sulfur and other poisons, and hydrocarbons.

Marina, O.A.; Pedersen, L.R.; Stevenson, J.W.

2005-01-27T23:59:59.000Z

337

Analysis of a direct methane conversion to high molecular weight hydrocarbons  

E-Print Network [OSTI]

Methane conversion to heavier hydrocarbons was studied using electrical furnaces and a plasma apparatus. The experiments were performed with pure methane for the electrical furnace experiments while pure methane and additions such as hydrogen...

Al-Ghafran, Moh'd. J.

2000-01-01T23:59:59.000Z

338

A porous covalent porphyrin framework with exceptional uptake capacity of saturated hydrocarbons oil spill cleanup  

SciTech Connect (OSTI)

Yamamoto homo-coupling reaction of tetra(4-bromophenyl)porphyrin afforded a porous covalent porphyrin framework, PCPF-1, which features strong hydrophobicity and oleophilicity and demonstrates exceptional adsorptive capacities for saturated hydrocarbons and gasoline.

Wang, Xi-Sen; Liu, Jian; Bonefont, Jean M.; Yuan, Da-Qiang; Thallapally, Praveen K.; Ma, Shengqian

2013-01-21T23:59:59.000Z

339

Characteristics of naphthenic and paraffinic hydrocarbons of residual oil from West Siberian crudes  

SciTech Connect (OSTI)

This article examines the naphthenic/paraffinic hydrocarbons segregated by liquid chromatography from a residual oil after removal of the resins and solid hydrocarbons. The studied hydrocarbons were fractionated on the basis of molecular weight (by molecular distillation) and on the basis of the content of rings (by thermal diffusion separation in a laboratory column). The results of mass-spectrometric analysis indicate that the first fraction consists mainly of isoparaffins and naphthenes with few rings. The polycyclic condensed naphthenes are concentrated in the last fraction. The content of isoparaffins drops off and the content of condensed polycyclic naphthenic structures increases from the second fraction to the next to the last. It is concluded that the naphthenic/paraffinic hydrocarbons of the residual oil from mixed West Siberian crudes have a relatively narrow composition and therefore have similar physicochemical properties.

Detusheva, E.P.; Khramtsova, L.P.; Muchinskii, T.D.; Shkol'nikov, V.M.

1984-05-01T23:59:59.000Z

340

OXIDATION OF DRY HYDROCARBONS AT HIGH-POWER DENSITY ANODES  

SciTech Connect (OSTI)

This work builds upon discoveries by the University of Pennsylvania and others pertaining to the oxidation of dry hydrocarbon fuels in high temperature solid oxide fuel cells. The work reported here was restricted primarily to dry methane and confirms that YSZ-based cells, having ceria in the anode as a catalyst and copper in the anode as a current collector, can operate on dry methane for extended periods. Thirty-three lab-scale cells of various designs were fabricated and operated under a variety of conditions. The longest-lived cell gave stable performance on dry methane at 800 C for over 305 hours. Only slight carbon deposition was noted at the completion of the test. A corresponding nickel/YSZ-based anode would have lasted for less than an hour under these test conditions (which included open circuit potential measurements) before carbon fouling essentially destroyed the cell. The best performing cell achieved 112 mW/cm{sub 2} on dry methane at 800 C. Several problems were encountered with carbon fouling and declining open circuit voltages in many of the test cells after switching from operation on hydrogen to dry methane. Although not rigorously confirmed by experimentation, the results suggested that air infiltration through less than perfect perimeter seals or pinholes in the electrolytes, or both gave rise to conditions that caused the carbon fouling and OCV decline. Small amounts of air reacting with methane in a partial oxidation reaction could produce carbon monoxide that, in turn, would deposit the carbon. If this mechanism is confirmed, it implies that near perfect hardware is required for extended operation. Some evidence was also found for the formation of electrical shorts, probably from carbon deposits bridging the electrolyte. Work with odorized methane and with methane containing 100-ppm hydrogen sulfide confirmed that copper is stable at 800 C in dry hydrocarbon fuels in the presence of sulfur. In a number of cases, but not exclusively, the performance life on dry methane with sulfur compounds was much longer than with dry methane alone. The effect of sulfur compounds in these cases appeared to correlate with inhibition of carbon deposition. Mixed results were obtained for the effect of the sulfur compounds on power density. Progress also was made in understanding the mechanisms involved in direct utilization of dry natural gas. Evidence was developed for three possible mechanisms for dry methane utilization in addition to the usually cited mechanism--direct oxidation of methane by oxygen anions. Further work is required at a fundamental level before the knowledge gained here can be translated into higher levels of performance.

K.Krist; O. Spaldon-Stewart; R. Remick

2004-03-01T23:59:59.000Z

Note: This page contains sample records for the topic "non-methane hydrocarbons nmhc" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

OPERATION OF SOLID OXIDE FUEL CELL ANODES WITH PRACTICAL HYDROCARBON FUELS  

SciTech Connect (OSTI)

This work was carried out to achieve a better understanding of how SOFC anodes work with real fuels. The motivation was to improve the fuel flexibility of SOFC anodes, thereby allowing simplification and cost reduction of SOFC power plants. The work was based on prior results indicating that Ni-YSZ anode-supported SOFCs can be operated directly on methane and natural gas, while SOFCs with novel anode compositions can work with higher hydrocarbons. While these results were promising, more work was clearly needed to establish the feasibility of these direct-hydrocarbon SOFCs. Basic information on hydrocarbon-anode reactions should be broadly useful because reformate fuel gas can contain residual hydrocarbons, especially methane. In the Phase I project, we have studied the reaction mechanisms of various hydrocarbons--including methane, natural gas, and higher hydrocarbons--on two kinds of Ni-containing anodes: conventional Ni-YSZ anodes and a novel ceramic-based anode composition that avoid problems with coking. The effect of sulfur impurities was also studied. The program was aimed both at achieving an understanding of the interactions between real fuels and SOFC anodes, and providing enough information to establish the feasibility of operating SOFC stacks directly on hydrocarbon fuels. A combination of techniques was used to provide insight into the hydrocarbon reactions at these anodes during SOFC operation. Differentially-pumped mass spectrometry was be used for product-gas analysis both with and without cell operation. Impedance spectroscopy was used in order to understand electrochemical rate-limiting steps. Open-circuit voltages measurements under a range of conditions was used to help determine anode electrochemical reactions. Life tests over a wide range of conditions were used to establish the conditions for stable operation of anode-supported SOFC stacks directly on methane. Redox cycling was carried out on ceramic-based anodes. Tests on sulfur tolerance of Ni-YSZ anodes were carried out.

Scott A. Barnett; Jiang Liu; Yuanbo Lin

2004-07-30T23:59:59.000Z

342

Polyethylene composites containing a phase change material having a C14 straight chain hydrocarbon  

DOE Patents [OSTI]

A composite useful in thermal energy storage, said composite being formed of a polyethylene matrix having a straight chain alkyl hydrocarbon incorporated therein, said polyethylene being crosslinked to such a degree that said polyethylene matrix is form stable and said polyethylene matrix is capable of absorbing at least 10% by weight of said straight chain alkyl hydrocarbon; the composite is useful in forming pellets or sheets having thermal energy storage characteristics.

Salyer, Ival O. (Dayton, OH)

1987-01-01T23:59:59.000Z

343

Effect of support on catalytic behavior of dispersed rhodium for hydrocarbon hydrogenolyses  

E-Print Network [OSTI]

EFFFCT OF SUPPORT ON CATALYTIC BEHAVIOR OF DISPERSED RHODIUM POR HYDROCARBON HYDROGENOLYSES A Thesis AMINA ARMED KHAL'lFA Submi I ted to the Graduate College of Texas AKM University in partial full illment of the requirement for the degree... of MASTER OF SCIENCE December 1986 Major Subject: Chemistry EFFECT OF SUPPORT ON CATALYTIC BEHAVIOR OF DISPERSED RHODIUM FOR HYDROCARBON HYDROGENOLYSES A Thesis by AMINA AHMED KHALIFA Approved as to style and content by: M. P. osynek (Chairman...

Khalifa, Amina Ahmed

2012-06-07T23:59:59.000Z

344

The particulate and vapor phase components of airborne polyaromatic hydrocarbons (PAHs) in coal gasification pilot plants  

E-Print Network [OSTI]

THE PARTICULATE AND VAPOR PHASE COMPONENTS OF AIRBORNE POLYAROMATIC HYDROCARBONS(PAHs) IN COAL GASIFICATION PILOT PLANTS A Thesis by ERIC JON BRINK Submitted to the Graduate College of Texas A & M University in partial fulfillment... of the requirement for the degree of MASTER OF SCIENCE December 1980 Major Subject: Industrial Hygiene THE PARTICULATE AND VAPOR PHASE COMPONENTS OF AIRBORNE POLYAROMATIC HYDROCARBONS (PAHs) IN COAL GASIFICATION PILOT PLANTS A Thesis by ERIC JON BRINK...

Brink, Eric Jon

1980-01-01T23:59:59.000Z

345

Correlations of fuel economy, exhaust hydro-carbon concentrations, and vehicle performance efficiency  

E-Print Network [OSTI]

CORRELATIONS OF FUEL ECONOMY, EXHAUST HYDROCARBON CONCENTRATIONS, AND VEHICLE PERFORMANCE EFFICIENCY A Thesis by PHILIP DOUGLAS BAUMANN Submitted to the Graduate College of Texas ASM University in partial fulfillment of the requirement... for the degree of MASTER OF SCIENCE December 1974 Major Subject: Civil Engineering CORRELATIONS OF FUEL ECONOMY, EXHAUST HYDROCARBON CONCENTRATIONS, AND VEHICLE PERFORMANCE EFFICIENCY A Thesis by PHILIP DOUGLAS BAUMANN Approved as to style and content by...

Baumann, Philip Douglas

1974-01-01T23:59:59.000Z

346

Potential of producing various hydrocarbons from canola oil by catalytic treatment over Pt-ZSM-5  

SciTech Connect (OSTI)

Canola oil conversion was studied at atmospheric pressure over Pt-ZSM-5 catalyst (0.5 wt% Pt) in a fixed bed micro-reactor. The operating conditions were: temperature range of 400--500 C, weight hourly space velocity (WHSV) of 1.8 and 3.6 h{sup {minus}1} and steam/oil ratio of 4:1. The products were coke, gas, an organic liquid product (OLP) and residue. The gas and OLP consisted mainly of hydrocarbons. The objective of this study was to maximize the amount of gasoline range hydrocarbons in the OLP and the selectivity to isohydrocarbons in the gas. The gas yields varied between 22--65 wt% and were higher in the presence of steam compared to the operation without steam. Also, the gas fraction decreased with increase in space velocity. The olefin/paraffin ratio of C{sub 2}-C{sub 4} hydrocarbon gases varied between 0.31--0.79. The amount of isohydrocarbons relative to n-hydrocarbons were higher with Pt-ZSM-5 (1.6--4.8) compared to pure HZSM-5 catalyst (0.2--0.3). The OLP yields with Pt-ZSM-5 (20--55wt% of canola oil) were slightly lower compared to HZSM-5 (40--63wt% of canola oil) under similar conditions. The major components of OLP were aliphatic and aromatic hydrocarbons. The main aromatic hydrocarbons were benzene, toluene, xylenes and trimethylbenzenes. Alkylated pentane and hexane were the main aliphatic hydrocarbons. In the presence of steam, Pt-ZSM-5 gave higher yields of liquid hydrocarbons within the gasoline boiling range than HZSM-5.

Katikaneni, S.P.R.; Adjaye, J.D.; Bakhshi, N.N. [Univ. of Saskatchewan, Saskatoon (Canada)

1995-12-31T23:59:59.000Z

347

Fluorescent growth bands in irradiated-bitumen nodules: Evidence of episodic hydrocarbon migration  

SciTech Connect (OSTI)

Minute rims of solid bitumen ({approximately}40-50 {mu}m thick) surround detrital radioactive grains in the Permian-Triassic sandstones and Arranoo Member of the Kockatea Shale from the northern Perth basin, Australia. The bitumen formed as Th- and U-bearing minerals (monazite, xenotime, zircon, thorite) irradiated and immobilized fluid hydrocarbons coming within range of alpha-particle emissions. using transmitted light and scanning electron microscopy and rims appear compositionally homogeneous, but under blue/violet epifluorescent illumination the bitumen displays complex concentric and contorted banding. These fluorescent textures indicate that multiple influxes of hydrocarbons passed through the reservoir sandstones. Following radiation-induced immobilization of hydrocarbons from the first oil influx, the bitumen nodules grew through a process of swelling and expansion outward form the mineral core during subsequent oil influxes, producing graded fluorescent growth bands. Oil droplets and lamellae also were adsorbed onto the outer portion of the nodules. Such bitumen nodules are a new and potentially important source of data for understanding the movement of hydrocarbons in sedimentary basins, specifically for identifying hydrocarbon pathways, the number of discrete hydrocarbon pulses, and the relative timing of oil migration.

Rasmussen, B. [Univ. of Western Australia, Nedlands (Australia)

1997-01-01T23:59:59.000Z

348

Polycyclic aromatic hydrocarbons and fatal ischemic heart disease  

SciTech Connect (OSTI)

Several toxicologic and epidemiologic studies have produced evidence that occupational exposure to polycyclic aromatic hydrocarbons (PAH) is a risk factor for ischemic heart disease (IHD). However, a clear exposure-response relation has not been demonstrated. We studied a relation between exposure to PAH and mortality from IHD (418 cases) in a cohort of 12,367 male asphalt workers from Denmark, Finland, France, Germany, Israel, The Netherlands and Norway. Exposures to benzo(a)pyrene were assessed quantitatively using measurement-driven exposure models. Exposure to coal tar was assessed in a semiquantitative manner on the basis of information supplied by company representatives. We carried out sensitivity analyses to assess potential confounding by tobacco smoking. Both cumulative and average exposure indices for benzo(a)pyrene were positively associated with mortality from IHD. The highest relative risk for fatal IHD was observed for average benzo(a)pyrene exposures of 273 ng/m{sup 3} or higher, for which the relative risk was 1.64(95% confidence interval = 1.13-2.38). Similar results were obtained for coal tar exposure. Sensitivity analysis indicated that even in a realistic scenario of confounding by smoking, we would observe approximately 20% to 40% excess risk in IHD in the highest PAH-exposure categories. Our results lend support to the hypothesis that occupational PAH exposure causes fatal IHD and demonstrate a consistent exposure-response relation for this association.

Burstyn, I.; Kromhout, H.; Partanen, T.; Svane, O.; Langard, S.; Ahrens, W.; Kauppinen, T.; Stucker, I.; Shaham, J.; Heederik, D.; Ferro, G.; Heikkila, P.; Hooiveld, M.; Johansen, C.; Randem, B.G.; Boffetta, P. [International Agency for Research on Cancer, Lyon (France)

2005-11-01T23:59:59.000Z

349

Methods of reforming hydrocarbon fuels using hexaaluminate catalysts  

DOE Patents [OSTI]

A metal substituted hexaaluminate catalyst for reforming hydrocarbon fuels to synthesis gas of the general formula AB.sub.yAl.sub.12-yO.sub.19-.delta., A being selected from alkali metals, alkaline earth metals and lanthanide metals or mixtures thereof. A dopant or surface modifier selected from a transitions metal, a spinel of an oxygen-ion conductor is incorporated. The dopant may be Ca, Cs, K, La, Sr, Ba, Li, Mg, Ce, Co, Fe, Ir, Rh, Ni, Ru, Cu, Pe, Os, Pd, Cr, Mn, W, Re, Sn, Gd, V, Ti, Ag, Au, and mixtures thereof. The oxygen-ion conductor may be a perovskite selected from M'RhO.sub.3, M'PtO.sub.3, M'PdO.sub.3, M'IrO.sub.3, M'RuO.sub.3 wherein M'=Mg, Sr, Ba, La, Ca; a spinel selected from MRh.sub.2O.sub.4, MPt.sub.2O.sub.4, MPd.sub.2O.sub.4, MIr.sub.2O.sub.4, MRu.sub.2O.sub.4 wherein M=Mg, Sr, Ba, La, Ca and mixtures thereof; a florite is selected from M''O.sub.2.

Gardner, Todd H. (Morgantown, WV); Berry, David A. (Morgantown, WV); Shekhawat, Dushyant (Morgantown, WV)

2012-03-27T23:59:59.000Z

350

North African geology: exploration matrix for potential major hydrocarbon discoveries  

SciTech Connect (OSTI)

Based on results and models presented previously, it is possible to consider an exploration matrix that examines the 5 basic exploration parameters: source, reservoir, timing, structure, and seal. This matrix indicates that even those basins that have had marginal exploration successes, including the Paleozoic megabasin and downfaulted Triassic grabens of Morocco, the Cyrenaican platform of Libya, and the Tunisia-Sicily shelf, have untested plays. The exploration matrix also suggests these high-risk areas could change significantly, if one of the 5 basic matrix parameters is upgraded or if adjustments in political or financial risk are made. The Sirte basin and the Gulf of Suez, 2 of the more intensely explored areas, also present attractive matrix prospects, particularly with deeper Nubian beds or with the very shallow Tertiary sections. The Ghadames basin of Libya and Tunisia shows some potential, but its evaluation responds strongly to stratigraphic and external nongeologic matrix variations based on degree of risk exposure to be assumed. Of greatest risk in the matrix are the very deep Moroccan Paleozoic clastic plays and the Jurassic of Sinai. However, recent discoveries may upgrade these untested frontier areas. Based on the matrix generated by the data presented at a North African Petroleum Geology symposium, significant hydrocarbon accumulations are yet to be found. The remaining questions are: where in the matrix does each individual company wish to place its exploration capital and how much should be the risk exposure.

Kanes, W.H.; O'Connor, T.E.

1985-02-01T23:59:59.000Z

351

Persistence of chlorinated hydrocarbon contamination in a California marine ecosystem  

SciTech Connect (OSTI)

Despite major reductions in the dominant DDT and polychlorinated biphenyls (PCB) input off Los Angeles (California, U.S.A.) in the early 1970s, the levels of these pollutants decreased only slightly from 1972 to 1975 both in surficial bottom sediments and in a flatfish bioindicator (Dover sole, Microstomus pacificus) collected near the submarine outfall. Concentrations of these pollutants in the soft tissues of the mussel Mytilus californianus, collected intertidally well inshore of the highly contaminated bottom sediments, followed much more closely the decreases in the outfall discharges. These observations suggest that contaminated sediments on the seafloor were the principal (although not necessarily direct) cause of the relatively high and persistent concentrations of DDT and PCB residues in tissues. The study indicated that residues of the higher-molecular-weight chlorinated hydrocarbons, such as DDT and PCB, can be highly persistent once released to coastal marine ecosystems and that their accumulation in surficial bottom sediments is the most likely cause of this persistence observed in the biota of the discharge zone.

Young, D.R.; Gossett, R.W.; Heesen, T.C.

1989-01-01T23:59:59.000Z

352

Using Ionic Liquids in Selective Hydrocarbon Conversion Processes  

SciTech Connect (OSTI)

This is the Final Report of the five-year project Using Ionic Liquids in Selective Hydrocarbon Conversion Processes (DE-FC36-04GO14276, July 1, 2004- June 30, 2009), in which we present our major accomplishments with detailed descriptions of our experimental and theoretical efforts. Upon the successful conduction of this project, we have followed our proposed breakdown work structure completing most of the technical tasks. Finally, we have developed and demonstrated several optimized homogenously catalytic methane conversion systems involving applications of novel ionic liquids, which present much more superior performance than the Catalytica system (the best-to-date system) in terms of three times higher reaction rates and longer catalysts lifetime and much stronger resistance to water deactivation. We have developed in-depth mechanistic understandings on the complicated chemistry involved in homogenously catalytic methane oxidation as well as developed the unique yet effective experimental protocols (reactors, analytical tools and screening methodologies) for achieving a highly efficient yet economically feasible and environmentally friendly catalytic methane conversion system. The most important findings have been published, patented as well as reported to DOE in this Final Report and our 20 Quarterly Reports.

Tang, Yongchun; Periana, Roy; Chen, Weiqun; van Duin, Adri; Nielsen, Robert; Shuler, Patrick; Ma, Qisheng; Blanco, Mario; Li, Zaiwei; Oxgaard, Jonas; Cheng, Jihong; Cheung, Sam; Pudar, Sanja

2009-09-28T23:59:59.000Z

353

Conversion of Ethanol to Hydrocarbons on Hierarchical HZSM-5 Zeolites  

SciTech Connect (OSTI)

This study reports synthesis, characterization, and catalytic activity of the nano-size hierarchical HZSM-5 zeolite with high mesoporosity produced via a solvent evaporation procedure. Further, this study compares hierarchical zeolites with conventional HZSM-5 zeolite with similar Si/Al ratios for the ethanol-to-hydrocarbon conversion process. The catalytic performance of the hierarchical and conventional zeolites was evaluated using a fixed-bed reactor at 360 C, 300 psig, and a weight hourly space velocity of 7.9 h-1. For the low Si/Al ratio zeolite (~40), the catalytic life-time for the hierarchical HZSM-5 was approximately 2 times greater than the conventional HZSM-5 despite its coking amount deposited 1.6 times higher than conventional HZSM-5. For the high Si/Al ratio zeolite (~140), the catalytic life-time for the hierarchical zeolite was approximately 5 times greater than the conventional zeolite and the amount of coking deposited was 2.1 times higher. Correlation was observed between catalyst life time, porosity, and the crystal size of the zeolite. The nano-size hierarchical HZSM-5 zeolites containing mesoporosity demonstrated improved catalyst life-time compared to the conventional catalyst due to faster removal of products, shorter diffusion path length, and the migration of the coke deposits to the external surface from the pore structure.

Ramasamy, Karthikeyan K.; Zhang, He; Sun, Junming; Wang, Yong

2014-12-15T23:59:59.000Z

354

Emergency action -- Hydrocarbon spill MCB Camp Pendleton, California  

SciTech Connect (OSTI)

On 10 April 1991, the Camp Pendleton Natural Resources Management Office received notice that a diesel fuel pipeline located at the Naval Regional Medical Center near Lake O`Neill had leaked on 5 April 1991. The leakage occurred from an exposed, ruptured fuel line that was used to transfer fuel between 12 underground storage tanks at a fuel farm and two large underground day tanks next to the hospital boiler building. The loss consisted of approximately 8,000 gallons of diesel {number_sign}2 fuel oil. The spill saturated the soil around the pipeline as well as overflowing into downslope utility conduits and vaults with termination upon a river terrace approximately 0.5 miles downslope of the spill area, and within 500 feet of the Santa Margarita River Channel, an aquifer recharge area. Because local groundwater is the primary freshwater resource for Camp Pendleton, the concern that this spill could immediately contaminate the local groundwater supply initiated an on-site emergency task order that consisted of emergency containment, neutralization, assessment, remediation and restoration of the hydrocarbon spill. The emergency action included containment and removal of free product in electrical conduits and vaults, neutralization of existing utility containment sources, removal and assessment of contaminated soils using excavation equipment, hollow-stem auger/dual percussion/and air rotary drilling rigs, and the creation of a bioremediation treatment cell adjacent to the spill site.

O`Connor, D. [IT Corp., San Diego, CA (United States)

1994-12-31T23:59:59.000Z

355

Simple rules help select best hydrocarbon distillation scheme  

SciTech Connect (OSTI)

Separation economics depend mainly on investment for major equipment and energy consumption. This relationship, together with the fact that, in most cases, many alternative schemes will be proposed, make it essential to find an optimum scheme that minimizes overall costs. Practical solutions are found by applying heuristics -- exploratory problem-solving techniques that eliminate alternatives without applying rigorous mathematical procedures. These techniques have been applied to a case study. In the case study, a hydrocarbon mixture will be transported through a pipeline to a fractionation plant, where it will be separated into commercial products for distribution. The fractionation will consist of a simple train of distillation columns, the sequence of which will be defined by applying heuristic rules and determining the required thermal duties for each column. The facility must separate ethane, propane and mixed butanes, natural gasoline (light straight-run, or LSR, gasoline), and condensate (heavy naphtha). The ethane will be delivered to an ethylene plant as a gaseous stream, the propane and butanes will be stored in cryogenic tanks, and the gasoline and heavy naphtha also will be stored.

Sanchezllanes, M.T.; Perez, A.L.; Martinez, M.P.; Aguilar-Rodriguez, E.; Rosal, R. del (Inst. Mexicano del Petroleo, Mexico City (Mexico))

1993-12-06T23:59:59.000Z

356

Mid-continent rift system: a frontier hydrocarbon province  

SciTech Connect (OSTI)

The Mid-continent rift system can be traced by the Mid-continent geophysical anomaly (MGA) from the surface exposure of the Keweenawan Supergroup in the Lake Superior basin southwest in the subsurface through Wisconsin, Minnesota, Iowa, Nebraska, and Kansas. Outcrop and well penetrations of the late rift Keweenawan sedimentary rocks reveal sediments reflecting a characteristic early continental rift clastic sequence, including alluvial fans, deep organic-rich basins, and prograding fluvial plains. Sedimentary basins where these early rift sediments are preserved can be located by upward continuation of the aeromagnetic profiles across the rift trend and by gravity models. Studies of analog continental rifts and aulacogens show that these gravity models should incorporate (1) a deep mafic rift pillow body to create the narrow gravity high of the MGA, and (2) anomalously thick crust to account for the more regional gravity low. Preserved accumulations of rift clastics in central rift positions can then be modeled to explain the small scale notches which are found within the narrow gravity high. Indigenous oil in Keweenawan sediments in the outcrop area and coaly partings in the subsurface penetrations of the Keweenawan clastics support the analogy between these rift sediments and the exceptionally organic-rich sediments of the East African rift. COCORP data across the rift trend in Kansas show layered deep reflectors and large structures. There is demonstrable source, reservoir, and trap potential within the Keweenawan trend, making the Mid-Continent rift system a frontier hydrocarbon province.

Lee, C.K.; Kerr, S.D. Jr.

1984-04-01T23:59:59.000Z

357

Mid-Continent rift system: a frontier hydrocarbon province  

SciTech Connect (OSTI)

The Mid-Continent rift system can be traced by the Mid-Continent geophysical anomaly (MGA) from the surface exposure of the Keweenawan Supergroup in the Lake Superior basin southwest in the subsurface through Wisconsin, Minnesota, Iowa, Nebraska, and Kansas. Outcrop and well penetrations of the late rift Keweenawan sedimentary rocks reveal sediments reflecting a characteristic early continental rift clastic sequence, including alluvial fans, deep organic-rich basins, and prograding fluvial plains. Sedimentary basins where these early rift sediments are preserved can be located by upward continuation of the aeromagnetic profiles across the rift trend and by gravity models. Studies of analog continental rifts and aulacogens show that these gravity models should incorporate (1) a deep mafic rift pillow body to create the narrow gravity high of the MGA, and (2) anomalously thick crust to account for the more regional gravity low. Preserved accumulations of rift clastics in central rift positions can then be modeled to explain the small scale notches which are found within the narrow gravity high. Indigenous oil in Keweenawan sediments in the outcrop area and coaly partings in the subsurface penetrations of the Keweenawan clastics support the analogy between these rift sediments and the exceptionally organic-rich sediments of the East African rift. COCORP data across the rift trend in Kansas show layered deep reflectors and large structures. There is demonstrable source, reservoir, and trap potential within the Keweenawan trend, making the Mid-Continent rift system a frontier hydrocarbon province.

Lee, C.K.; Kerr, S.D. Jr.

1984-04-01T23:59:59.000Z

358

Ethanol Conversion to Hydrocarbons on HZSM-5: Effect of Reaction Conditions and Si/Al Ratio on the Product Distributions  

SciTech Connect (OSTI)

The Conversion of ethanol to hydrocarbon over HZSM-5 zeolite with different Si/Al ratios was investigated under various reaction conditions. The catalyst with a higher Si/Al ratio (low acid density) deactivated faster and generated more unsaturated compounds at a similar time-on-stream. Temperature affects the catalytic activity with respect to liquid hydrocarbon generation and the hydrocarbon product composition. At lower temperatures (~300C), the catalyst deactivated faster with respect to the liquid hydrocarbon formation. Higher temperatures (~400C) reduced the formation of liquid range hydrocarbons and formed more gaseous fractions. Weight hourly space velocity was also found to affect product selectivity with higher weight hourly space velocity leading to a higher extent of ethylene formation. The experimental results were analyzed in terms of the product composition and the coke content with respect to catalyst time-on-stream and compared with the catalyst lifetime with respect to the variables tested on the conversion of ethanol to hydrocarbon.

Ramasamy, Karthikeyan K.; Wang, Yong

2014-11-17T23:59:59.000Z

359

Final Report, "Molecular Design of Hydrocarbon Oxidation Catalytic Processes"  

SciTech Connect (OSTI)

The main goal of this project had been to use model systems to correlate selectivities in partial oxidation catalysis with the presence of specific sites on the surface of the catalyst. Extensive work was performed this year on characterizing oxygen-treated nickel surfaces by chemical means. Specifically, the surface chemistry of ammonia coadsorbed with atomic oxygen on Ni(110) single-crystal surfaces was studied by temperature-programmed desorption (TPD) and X-ray photoelectron spectroscopy (XPS). It was determined that at intermediate oxygen coverages direct ammonia adsorption on nickel sites is suppressed, but a new high-temperature reaction regime is generated at 400 K where NHx surface fragments are rehydrogenated concurrently with the production of water and molecular hydrogen. The extensive isotope scrambling and hydrogen transfer seen from nitrogen- to oxygen-containing surface intermediates, and the optimum yields seen for this 400 K state at intermediate oxygen coverages, strongly suggest the direct interaction of the adsorbed ammonia with oxygen atoms at the end of the NiO- rows that form upon reconstruction of the surface. Hydrogen transfer between ammonia and oxygen appears to take place directly via hydrogen bonding, and to be reversible but biased towards water formation. An equilibrium is reached between the produced water and the reacting surface oxygen and hydrogen. The strong influence of the OH surface groups on the thermal chemistry of the adsorbed ammonia was interpreted in terms of the adsorbing geometry of the OH groups on the surface, and of hydrogen bonding between adsorbed OH and NH3 species. In terms of alcohol reactivity, the adsorption of 2-iodoethanol, a precursor for the preparation of 2-hydroxyethyl and oxametallacycle surface species, was found to lead to two configurations involving either just the iodine atom or both iodine and hydroxyl ends of the molecule. A complex chemical behavior starts around 140 K with the production of small amounts of ethylene and water, most likely via the concerted decomposition or disproportionation of the adsorbed molecular species. The bulk of the 2-iodoethanol decomposes at about 150 K via an initial carbon-iodine scission to form O(H)CH2CH2 (~80%) and 2-hydroxyethyl (~20%) intermediates. Two competing reactions are involved with the subsequent conversion of the 2-hydroxyethyl species around 160 K, a reductive elimination with surface hydrogen to yield ethanol, and a ?-H elimination to surface vinyl alcohol. The O(H)CH2CH2, on the other hand, dehydrogenates to a OCH2CH2 oxametallacycle species about the same temperature. Both 2-hydroxyethyl and oxametallacycle species tautomerize to acetaldehyde, around 210 K and above 250 K, respectively, and some of that acetaldehyde desorbs while the rest decomposes to hydrogen and carbon monoxide. We contend that a better understanding of the surface chemistry of oxygen-containing surfaces can lead to better selectivities in catalysis. This is arguably the most important issue in the field of catalysis in the near future, and one that impacts several technologies of interest to DOE such as the manufacturing of speciality chemicals and the control and removal of pollutants. Additional work was performed on the characterization of the chemistry of methyl and methylene adsorbed species on oxygen-treated nickel surfaces. Complex chemistry was observed involving not only hydrogenation and dehydrogenation steps, but also C-C couplings and methylene insertions to produce heavier hydrocarbons, and oxygen insertion reactions that yield oxygenates. Finally, a dual titration technique employing xenon and a chemically sensitive probe was developed to identify minority catalytic sites on oxide surfaces. In the case of oxygen-treated Ni(110) single crystals, it was found that both hydrogen transfer with adsorbed water or ammonia and certain hydrocarbon hydrogenation reactions take place at the end of the NiO rows that form in this system. Carbon and nitrogen oxides, on the other hand, display no pre

Professor Francisco Zaera

2007-08-09T23:59:59.000Z

360

A three-phase K-value study for pure hydrocarbons/water and crude oil/water systems  

E-Print Network [OSTI]

Steam distillation, or vaporization of crude oil in porous media is on of the major mechanisms responsible for high oil recovery by steamflooding from heavy oil as well as light oil reservoir systems. Several authors have reported steam dsitillation...-phase equilibrium data for hydrocarbon/water systems ranging from light to heavy crude oil fractions. ! Experimental data describing the phase behavior and the hydrocarbon/water separation process for multi-component hydrocarbon/water and crude oil...

Lanclos, Ritchie Paul

1990-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "non-methane hydrocarbons nmhc" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Kinetics and intermediate products in the interaction of straight-chain and cyclic hydrocarbon radicals with 9,10-Anthraquinone  

SciTech Connect (OSTI)

The authors use a pulse radiolysis technique with optical registration of the destruction of hydrocarbon radicals R in determining the rate constants for the interaction of cyclododecyl radicals and n-dodecyl radicals with 9,10-anthraquinone in the corresponding liquid hydrocarbons, at various temperatures. It is shown that in the presence of oxygen, hydrocarbon radicals with the quinone form oxygen-containing species that are capable of propagating the oxidation chain and regenerating the original quinone.

Ladygin, B.V.; Revina, A.A.

1986-04-01T23:59:59.000Z

362

Sorption characteristics of polycyclic aromatic hydrocarbons in aluminum smelter residues  

SciTech Connect (OSTI)

High temperature carbon oxidation in primary aluminum smelters results in the release of polycyclic aromatic hydrocarbons (PAH) into the environment. The main source of PAH are the anodes, which are composed of petroleum coke (black carbon, BC) and coal tar pitch. To elucidate the dominant carbonaceous phase controlling the environmental fate of PAH in aluminum smelter residues (coke BC and/or coal tar), the sorptive behavior of PAHs has been determined, using passive samplers and infinite-sink desorption methods. Samples directly from the wet scrubber were studied as well as ones from an adjacent 20-year old storage lagoon and roof dust from the smelter. Carbon-normalized distribution coefficients of native PAHs were 2 orders of magnitude higher than expected based on amorphous organic carbon (AOC)/water partitioning, which is in the same order of magnitude as reported literature values for soots and charcoals. Sorption isotherms of laboratory-spiked deuterated phenanthrene showed strong (about 100 times stronger than AOC) but nonetheless linear sorption in both fresh and aged aluminum smelter residues. The absence of nonlinear behavior typical for adsorption to BC indicates that PAH sorption in aluminum smelter residues is dominated by absorption into the semi-solid coal tar pitch matrix. Desorption experiments using Tenax showed that fresh smelter residues had a relatively large rapidly desorbing fraction of PAH (35-50%), whereas this fraction was strongly reduced (11-16%) in the lagoon and roof dust material. Weathering of the coal tar residue and/or redistribution of PAH between coal tar and BC phases could explain the reduced availability in aged samples. 38 refs., 5 figs., 1 tab.

Gijs D. Breedveld; Emilien Pelletier; Richard St. Louis; Gerard Cornelissen [Norwegian Geotechnical Institute, Oslo (Norway)

2007-04-01T23:59:59.000Z

363

Carbon and oxygen stable isotopes in the Toa Baja Well, Puerto Rico: implications for burial diagenesis and hydrocarbon generation  

E-Print Network [OSTI]

that the bulk of the sediment pile has not been exposed to temperatures above the oil window and possibly hydrocarbons have been generated deeper in the basin....

Gonzalez, Luis A.

1991-03-01T23:59:59.000Z

364

Applications of contaminant fate and bioaccumulation models in assessing ecological risks of chemicals: A case study for gasoline hydrocarbons  

E-Print Network [OSTI]

the composition of the gasoline inventory, and can beand exposure assessment for gasoline; Trent University:of Chemicals: A Case Study for Gasoline Hydrocarbons Matthew

MacLeod, Matthew; McKone, Thomas E.; Foster, Karen L.; Maddalena, Randy L.; Parkerton, Thomas F.; Mackay, Don

2004-01-01T23:59:59.000Z

365

Calorimetric study of adsorption of aliphatic hydrocarbons on reduced cobalt catalyst  

SciTech Connect (OSTI)

A study has been made of the heats of adsorption and the adsorption isotherms of saturated and unsaturated hydrocarbons on Co at 298/sup 0/K; the content of organic matter in the catalyst has been determined after use in the Fischer-Tropsch synthesis. It is concluded that the Fischer-Tropsch process includes stages of diffusion of the original reactants and the products through a liquid film of hydrocarbons coating the catalyst; the hydrocarbon molecules are adsorbed on the surface in the ''lying down'' position; the adsorption of paraffins is reversible and is described by the BET theory; olefins form an irreversibly chemisorbed monolayer, above which reversible adsorption takes place; the ease of desorption of the paraffins explains their preferential formation in the Fischer-Tropsch synthesis.

Ostrovskii, V.E.; Medvedkova, E.A.

1986-06-01T23:59:59.000Z

366

Catalysts for the production of hydrocarbons from carbon monoxide and water  

DOE Patents [OSTI]

A method of converting low H.sub.2 /CO ratio syngas to carbonaceous products comprising reacting the syngas with water or steam at 200.degree. to 350.degree. C. in the presence of a metal catalyst supported on zinc oxide. Hydrocarbons are produced with a catalyst selected from cobalt, nickel or ruthenium and alcohols are produced with a catalyst selected from palladium, platinium, ruthenium or copper on the zinc oxide support. The ratio of the reactants are such that for alcohols and saturated hydrocarbons: (2n+1).gtoreq.x.gtoreq.O and for olefinic hydrocarbons: 2n.gtoreq.x.gtoreq.O where n is the number of carbon atoms in the product and x is the molar amount of water in the reaction mixture.

Sapienza, Richard S. (Shoreham, NY); Slegeir, William A. (Hampton Bays, NY); Goldberg, Robert I. (Selden, NY)

1987-01-01T23:59:59.000Z

367

Catalysts for the production of hydrocarbons from carbon monoxide and water  

DOE Patents [OSTI]

A method of converting low H/sub 2//CO ratio syngas to carbonaceous products comprising reacting the syngas with water or steam at 200 to 350/sup 0/C in the presence of a metal catalyst supported on zinc oxide. Hydrocarbons are produced with a catalyst selected from cobalt, nickel or ruthenium and alcohols are produced with a catalyst selected from palladium, platinum, ruthenium or copper on the zinc oxide support. The ratio of the reactants are such that for alcohols and saturated hydrocarbons: (2n + 1) greater than or equal to x greater than or equal to O and for olefinic hydrocarbons: 2n greater than or equal to x greater than or equal to O where n is the number of carbon atoms in the product and x is the molar amount of water in the reaction mixture.

Sapienza, R.S.; Slegeir, W.A.; Goldberg, R.I.

1985-11-06T23:59:59.000Z

368

Aliphatic hydrocarbons in sediment cores from the southern basin of Lake Michigan  

SciTech Connect (OSTI)

Aliphatic hydrocarbons in sediments of the southern basin of Lake Michigan have planktonic, terrigenous, and petroleum residue origins. Surficial sediments collected near the eastern shore in 60-80 m of water contained more petroleum residue and planktonic hydrocarbons and exhibited less terrigenous character than sediments collected from the deepest location in the basin. Petroleum residue inputs have increased since 1900 as evidenced by a change in the flux of an unresolved complex mixture (UCM) of hydrocarbons from 6 ng/cm{sup 2}{center_dot}yr to a flux of approximately 100 ng/cm{sup 2}{center_dot}yr in 1980. Sediment profiles of the UCM exhibited subsurface concentration maxima that may be due to reduced inputs of combustion products or feeding by oligochaetes. Profiles of n-C{sub l7} and pristane indicated that planktonic n-alkanes undergo degradation in the aerobic, mixed zone of the sediments.

Doskey, P.V. [Argonne National Lab., IL (United States). Environmental Research Division; Andren, A.W. [Univ. of Wisconsin, Madison, WI (United States). Water Chemistry Program

1991-10-01T23:59:59.000Z

369

Pb-Pb dating of hydrocarbon migration into a bitumen-bearing ore deposit, North Wales  

SciTech Connect (OSTI)

Previous attempts at U-Pb dating of uraniferous bitumens have had limited significance because of radioelement migration. Pb-Pb dating which can be undertaken regardless of recent lead migration, has been successfully applied to uraniferous solidified bitumen from the Ty Gwyn copper deposit, North Wales. Analyses of five bitumen samples with variable mixtures of radiogenic and common lead yield a {sup 207}Pb/{sup 206}Pb age of 248 {plus minus} 21 Ma (Early Triassic). This age is interpreted as the date of hydrocarbon migration into the deposit and is reasonably consistent with the timing of hydrocarbon generation calculated from the regional burial history. The Pb-Pb dating method could be applied to date uraniferous bitumens representing hydrocarbon migration in diverse geologic environments.

Parnell, J. (Queens's Univ., Belfast (Ireland)); Swainbank, I. (NERC Isotope Geology Centre, Nottingham (England))

1990-10-01T23:59:59.000Z

370

Thermocatalytic process for CO.sub.2-free production of hydrogen and carbon from hydrocarbons  

DOE Patents [OSTI]

A novel process and apparatus are disclosed for sustainable CO.sub.2-free production of hydrogen and carbon by thermocatalytic decomposition (dissociation, pyrolysis, cracking) of hydrocarbon fuels over carbon-based catalysts in the absence of air and/or water. The apparatus and thermocatalytic process improve the activity and stability of carbon catalysts during the thermocatalytic process and produce both high purity hydrogen (at least, 99.0 volume %) and carbon, from any hydrocarbon fuel, including sulfurous fuels. In a preferred embodiment, production of hydrogen and carbon is achieved by both internal and external activation of carbon catalysts. Internal activation of carbon catalyst is accomplished by recycling of hydrogen-depleted gas containing unsaturated and aromatic hydrocarbons back to the reactor. External activation of the catalyst can be achieved via surface gasification with hot combustion gases during catalyst heating. The process and apparatus can be conveniently integrated with any type of fuel cell to generate electricity.

Muradov, Nazim Z. (Melbourne, FL)

2011-08-23T23:59:59.000Z

371

Systems including catalysts in porous zeolite materials within a reactor for use in synthesizing hydrocarbons  

DOE Patents [OSTI]

Catalytic structures include a catalytic material disposed within a zeolite material. The catalytic material may be capable of catalyzing a formation of methanol from carbon monoxide and/or carbon dioxide, and the zeolite material may be capable of catalyzing a formation of hydrocarbon molecules from methanol. The catalytic material may include copper and zinc oxide. The zeolite material may include a first plurality of pores substantially defined by a crystal structure of the zeolite material and a second plurality of pores dispersed throughout the zeolite material. Systems for synthesizing hydrocarbon molecules also include catalytic structures. Methods for synthesizing hydrocarbon molecules include contacting hydrogen and at least one of carbon monoxide and carbon dioxide with such catalytic structures. Catalytic structures are fabricated by forming a zeolite material at least partially around a template structure, removing the template structure, and introducing a catalytic material into the zeolite material.

Rolllins, Harry W. (Idaho Falls, ID); Petkovic, Lucia M. (Idaho Falls, ID); Ginosar, Daniel M. (Idaho Falls, ID)

2012-07-24T23:59:59.000Z

372

Methods of using structures including catalytic materials disposed within porous zeolite materials to synthesize hydrocarbons  

DOE Patents [OSTI]

Catalytic structures include a catalytic material disposed within a zeolite material. The catalytic material may be capable of catalyzing a formation of methanol from carbon monoxide and/or carbon dioxide, and the zeolite material may be capable of catalyzing a formation of hydrocarbon molecules from methanol. The catalytic material may include copper and zinc oxide. The zeolite material may include a first plurality of pores substantially defined by a crystal structure of the zeolite material and a second plurality of pores dispersed throughout the zeolite material. Systems for synthesizing hydrocarbon molecules also include catalytic structures. Methods for synthesizing hydrocarbon molecules include contacting hydrogen and at least one of carbon monoxide and carbon dioxide with such catalytic structures. Catalytic structures are fabricated by forming a zeolite material at least partially around a template structure, removing the template structure, and introducing a catalytic material into the zeolite material.

Rollins, Harry W. (Idaho Falls, ID); Petkovic, Lucia M. (Idaho Falls, ID); Ginosar, Daniel M. (Idaho Falls, ID)

2011-02-01T23:59:59.000Z

373

Study of net soot formation in hydrocarbon reforming for hydrogen fuel cells. Final report  

SciTech Connect (OSTI)

The hydrogen fuel cell is expected to be a valuable addition to the electric utility industry; however, the current fuel supply availability requires that conventional heavier hydrocarbon fuels also be considered as primary fuels. Typical heavier fuels would be No. 2 fuel oil with its accompanying sulfur impurities, compared with the currently used light hydrocarbon gases. The potential future use of alternate fuels which are rich in aromatics would exacerbate the problems associated with hydrogen production. Among the more severe of these problems, is the greater tendency of heavier hydrocarbons to form soot. The development of a quasi-global kinetics model to represent the homogeneous and heterogeneous reactions which control the autothermal hydrogen reforming process and the accompanying soot formation and gasification was the objective of this study.

Edelman, R. B.; Farmer, R. C.; Wang, T. S.

1982-08-01T23:59:59.000Z

374

Distribution and elimination routes of a naphthenic hydrocarbon (Dodecylcyclohexane) in rainbow trout (Salmo gairdneri)  

SciTech Connect (OSTI)

Contamination of fish by hydrocarbons, whether it occurred directly via the water or indirectly via the food chain has been the object of many studies during the last decade. The interest of laboratories have been focused on the most toxic components of crude oils, i.e., aromatic hydrocarbons but there is a lack of information on the fate of cyclic alkanes in fish. Naphthenic hydrocarbons are the least biologically active of the more mobile fractions of petroleum; nevertheless the fate of these compounds are worth considering, because they constitute respectively 41% and 19.2% of light and heavy crude oils. This paper reports the results of our experiment in which /sup 3/H-dodecylcyclohexane has been given per os to rainbow trout in order to evaluate the distribution and elimination routes of this cycloparaffin.

Cravedi, J.P.; Tulliez, J.

1981-03-01T23:59:59.000Z

375

Hydrogen and elemental carbon production from natural gas and other hydrocarbons  

DOE Patents [OSTI]

Diatomic hydrogen and unsaturated hydrocarbons are produced as reactor gases in a fast quench reactor. During the fast quench, the unsaturated hydrocarbons are further decomposed by reheating the reactor gases. More diatomic hydrogen is produced, along with elemental carbon. Other gas may be added at different stages in the process to form a desired end product and prevent back reactions. The product is a substantially clean-burning hydrogen fuel that leaves no greenhouse gas emissions, and elemental carbon that may be used in powder form as a commodity for several processes.

Detering, Brent A. (Idaho Falls, ID); Kong, Peter C. (Idaho Falls, ID)

2002-01-01T23:59:59.000Z

376

Method for predicting fouling tendency of a hydrocarbon-containing feedstock  

DOE Patents [OSTI]

Disclosed herein is a method involving the steps of (a) precipitating an amount of asphaltenes from a liquid sample of a first hydrocarbon-containing feedstock having solvated asphaltenes therein with one or more first solvents in a column; (b) determining one or more solubility characteristics of the precipitated asphaltenes; (c) analyzing the one or more solubility characteristics of the precipitated asphaltenes; and (d) correlating a measurement of feedstock fouling tendency for the first hydrocarbon-containing feedstock sample with a mathematical parameter derived from the results of analyzing the one or more solubility characteristics of the precipitated asphaltenes.

Schabron, John F; Rovani, Jr., Joseph F

2013-07-23T23:59:59.000Z

377

2013 Survey of Non-Starch Ethanol and Renewable Hydrocarbon Biofuels Producers  

SciTech Connect (OSTI)

In order to understand the status of the industry for non-starch ethanol and renewable hydrocarbon biofuels as of the end of calendar year 2013, the National Renewable Energy Laboratory (NREL) conducted the first of what is anticipated to be an annual survey of U.S. non-starch ethanol and renewable hydrocarbon biofuels producers. This report presents the results of this initial survey and describes the survey methodology. Subsequent surveys will report on the progress over time of the development of these facilities and companies.

Schwab, A.; Geiger, J.; Lewis, J.

2015-01-01T23:59:59.000Z

378

Process and catalyst for converting synthesis gas to liquid hydrocarbon mixture  

DOE Patents [OSTI]

Synthesis gas containing CO and H.sub.2 is converted to a high-octane hydrocarbon liquid in the gasoline boiling point range by bringing the gas into contact with a heterogeneous catalyst including, in physical mixture, a zeolite molecular sieve, cobalt at 6-20% by weight, and thoria at 0.5-3.9% by weight. The contacting occurs at a temperature of 250.degree.-300.degree. C., and a pressure of 10-30 atmospheres. The conditions can be selected to form a major portion of the hydrocarbon product in the gasoline boiling range with a research octane of more than 80 and less than 10% by weight aromatics.

Rao, V. Udaya S. (Monroeville, PA); Gormley, Robert J. (Pittsburgh, PA)

1987-01-01T23:59:59.000Z

379

Scaling Relationships for Adsorption Energies of C2 Hydrocarbons on Transition Metal Surfaces  

SciTech Connect (OSTI)

Using density functional theory calculations we show that the adsorption energies for C{sub 2}H{sub x}-type adsorbates on transition metal surfaces scale with each other according to a simple bond order conservation model. This observation generalizes some recently recognized adsorption energy scaling laws for AH{sub x}-type adsorbates to unsaturated hydrocarbons and establishes a coherent simplified description of saturated as well as unsaturated hydrocarbons adsorbed on transition metal surfaces. A number of potential applications are discussed. We apply the model to the dehydrogenation of ethane over pure transition metal catalysts. Comparison with the corresponding full density functional theory calculations shows excellent agreement.

Jones, G

2011-08-18T23:59:59.000Z

380

Process for the production of ethylene and other hydrocarbons from coal  

DOE Patents [OSTI]

A process for the production of economically significant amounts of ethyl and other hydrocarbon compounds, such as benzene, from coal is disclosed wherein coal is reacted with methane at a temperature in the approximate range of 500.degree. C. to 1100.degree. C. at a partial pressure less than about 200 psig for a period of less than 10 seconds. Ethylene and other hydrocarbon compounds may be separated from the product stream so produced, and the methane recycled for further production of ethylene. In another embodiment, other compounds produced, such as by-product tars, may be burned to heat the recycled methane.

Steinberg, Meyer (Huntington Station, NY); Fallon, Peter (East Moriches, NY)

1986-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "non-methane hydrocarbons nmhc" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Conversion of synthesis gas and methanol to hydrocarbons using zeolite catalysts  

E-Print Network [OSTI]

of methanol to hydrocarbons: 2CHsOH ~ (CH, ), O ~ C, -C, Olefinsr paraf f ins aromatics (2l coke This pathway and stoichiometry illustrates that conversion of methanol will yield a maximum of 43. 75 % by weight hydrocarbons and 56. 25% water. Langner... is readily calculated. CO + 2Ht ? + CHsOH /)G tppx = 12. 1 kcal/mol (3) With a feed ratio of 2/1 Hz/CO, the equilibrium CO conversion at 573K and 1, 500 psi is 46. 1%. Commercially, the conversions are much less than equilibrium. It would be desirable...

Matthews, Michael Anthony

2012-06-07T23:59:59.000Z

382

The effect of chemical dispersants on the solution of volatile liquid hydrocarbons from spilled crude oil  

E-Print Network [OSTI]

THE EFFECT OF CHEMICAL DISPERSANTS ON THE SOLUTION OF VOLATILE LIQUID HYDROCARBONS FROM SPILLED CRUDE OIL A Thesis by THOMAS JOSEPH McDONALD Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirement... for the degree of MASTER OF SCIENCE August 1982 Major Subject: Oceanography THE EFFECT OF CHEMICAL DISPERSANTS ON THE SOLUTION OF VOLATILE LIQUID HYDROCARBONS FROM SPILLED CRUDE OIL A Thesis by THOMAS JOSEPH McDONALD Approved as to style and content by...

McDonald, Thomas Joseph

1982-01-01T23:59:59.000Z

383

A Preliminary Report to the U.S. Coast Guard, Part 2 Petroleum Hydrocarbons in Sediment from the  

E-Print Network [OSTI]

..............................................................................................................................7 Appendix 1. Definition of geochemical parameters used in petroleum correlation studiesA Preliminary Report to the U.S. Coast Guard, Part 2 Petroleum Hydrocarbons in Sediment from., and Wong, F.L., 2011, Petroleum hydrocarbons in sediment from the northern Gulf of Mexico shoreline, Texas

Torgersen, Christian

384

Microbial community response to a release of neat ethanol onto residual hydrocarbons in a pilot-scale  

E-Print Network [OSTI]

Microbial community response to a release of neat ethanol onto residual hydrocarbons in a pilot ethanol release (E100, 76 l) onto residual hydrocarbons in sandy soil was evaluated in a continuous-flow 8 shifts were assessed using quantitative real-time PCR analysis. High ethanol concentrations

Alvarez, Pedro J.

385

The WaterHydrophobic Interface: Neutral and Charged Solute Adsorption at Fluorocarbon and Hydrocarbon Self-Assembled  

E-Print Network [OSTI]

The Water­Hydrophobic Interface: Neutral and Charged Solute Adsorption at Fluorocarbon on hydrocarbon and fluorocarbon self-assembled monolayers by using vibrational sum frequency spectroscopy molecular-scale interactions of adsorbates with fluorocarbon and hydrocarbon surfaces is of great importance

Richmond, Geraldine L.

386

IARC Monographs on the Evaluation of Carcinogenic Risks to Humans Some Inorganic Substances, Chlorinated Hydrocarbons, Aromatic Amines, N-Nitroso Compounds,  

E-Print Network [OSTI]

, and Acrolein 1979; 513 pages ISBN 92 832 1219 3 (out of print) Volume 20 Some Halogenated Hydrocarbons 1979

Barthelat, Francois

387

Phase Behavior of Light Gases in Hydrocarbon and Aqueous Solvents  

SciTech Connect (OSTI)

Under previous support from the Department of Energy, an experimental facility has been established and operated to measure valuable vapor-liquid equilibrium data for systems of interest in the production and processing of coal fluids. To facilitate the development and testing of models for prediction of the phase behavior for such systems, we have acquired substantial amounts of data on the equilibrium phase compositions for binary mixtures of heavy hydrocarbon solvents with a variety of supercritical solutes, including hydrogen, methane, ethane, carbon monoxide, and carbon dioxide. The present project focuses on measuring the phase behavior of light gases and water in Fischer-Tropsch (F-T) type solvents at conditions encountered in indirect liquefaction processes and evaluating and developing theoretically-based correlating frameworks to predict the phase behavior of such systems. Specific goals of the proposed work include (a) developing a state-of-the-art experimental facility to permit highly accurate measurements of equilibrium phase compositions (solubilities) of challenging F-T systems, (b) measuring these properties for systematically-selected binary, ternary and molten F-T wax mixtures to provide critically needed input data for correlation development, (c) developing and testing models suitable for describing the phase behavior of such mixtures, and (d) presenting the modeling results in generalized, practical formats suitable for use in process engineering calculations. During the present reporting period, our solubility apparatus was refurbished and restored to full service. To test the experimental apparatus and procedures used, measurements were obtained for the solubility Of C0{sub 2} in benzene at 160{degrees}F. Having confirmed the accuracy of the newly acquired data in comparison with our previous measurements and data reported in the literature for this test system, we have begun to measure the solubility of hydrogen in hexane. The measurements for this system will cover the temperature range from 160 to 280{degrees}F at pressures to 2,500 psia. As part of our model evaluation efforts, we examined the predictive abilities of an alternative approach we have proposed for calculating the phase behavior properties of highly non-ideal systems. Using this approach, the liquid phase fugacities generated from an equation of state (EOS) are augmented by a fugacity deviation function correction. The correlative abilities of this approach are compared with those of an EOS equipped with the recently introduced Wong-Sandler (MWS) mixing rules. These two approaches are compared with the current methods for vapor-liquid equilibrium (VLE) calculations, i.e., the EOS (0/0) approach with the van der Waals mixing rules and the split (y/0) approach. The evaluations were conducted on a database comprised of non-ideal low pressure binary systems as well as asymmetric high pressure binary systems. These systems are of interest in the coal liquefaction and utilization processes. The Peng-Robinson EOS was selected for the purposes of this evaluation.

Gasem, K.A.M.; Robinson, R.L., Jr.; Trvedi, N.J., Gao, W.

1997-09-01T23:59:59.000Z

388

Seismic interpretation of hydrocarbon seep features, Garden Banks, Gulf of Mexico  

E-Print Network [OSTI]

identified and interpreted in Garden Banks lease blocks 424 and 425. The seep features consisted of two mud volcanoes and a mud in-filled depression. The hydrocarbon seep features were characterized by their rates and styles of seepage. All of the seep...

Mullins, Adam Joseph

2001-01-01T23:59:59.000Z

389

Lithium Ion Solvation: Amine and Unsaturated Hydrocarbon Solvates of Lithium Hexamethyldisilazide (LiHMDS)  

E-Print Network [OSTI]

Lithium Ion Solvation: Amine and Unsaturated Hydrocarbon Solvates of Lithium Hexamethyldisilazide, and 13C NMR spectroscopic studies of 6Li-15N labeled lithium hexamethyldisilazide ([6Li,15N]- Li ligand structure and lithium amide aggregation state is a complex and sensitive function of amine alkyl

Collum, David B.

390

Chemistry in the Center for Catalytic Hydrocarbon Functionalization: An Energy Frontier Research Center  

E-Print Network [OSTI]

in 2007 [3]. The C:H ratio of methane (CH4) is favor- able when compared to petroleum (­CH2­) or coal (­CH% reduction when compared to petroleum and a 47% reduction when compared to coal [4]. Methane is also cleaner. Keywords Carbon dioxide Á Catalysis Á Energy Á Fuel cell Á Functionalization Á Hydrocarbon Á Methane Á

Goddard III, William A.

391

BP Oil Spill and Air Chemistry Crude oil contains various hydrocarbons  

E-Print Network [OSTI]

BP Oil Spill and Air Chemistry Crude oil contains various hydrocarbons NOAA and CIRES here at CU went to the oil spill in an aircraft that was equipped with instruments to measure the air quality. 1/3 of the oil dissolved into the water column (methane completely, benzene and ethane almost completely) Showed

Toohey, Darin W.

392

SPE 159255-PP Rock Classification from Conventional Well Logs in Hydrocarbon-Bearing  

E-Print Network [OSTI]

typing method for application in hydrocarbon-bearing shale (specifically source rock) reservoirs using conventional well logs and core data. Source rock reservoirs are known to be highly heterogeneous and often, petrophysical description of source rock reservoirs with well logs has been focused to quantifying rock

Torres-Verdn, Carlos

393

Anthropogenic emissions of nonmethane hydrocarbons in the northeastern United States: Measured seasonal variations from  

E-Print Network [OSTI]

influenced by sources not associated with fuel combustion. Changes in the observed correlations of CO2 and CO relative to acetylene are consistent with published changes in the estimated emissions of CO2 and CO over these emissions in the United States. Hydrocarbon, NOx and CO sources include fuel combustion in both mobile

Cohen, Ronald C.

394

Effect of Temperature on Carbon-Black Agglomeration in Hydrocarbon Liquid with Adsorbed Dispersant  

E-Print Network [OSTI]

can agglomerate, increasing the viscosity of the oil and significantly diminishing its lubrication performance. The soot can also form a high-viscosity sludge which can also degrade lubricant effectivenessEffect of Temperature on Carbon-Black Agglomeration in Hydrocarbon Liquid with Adsorbed Dispersant

395

Identification of Sediment Organic Carbon Location and Association with Polycyclic Aromatic Hydrocarbons (PAHs) in Contaminated Sediment  

E-Print Network [OSTI]

Identification of Sediment Organic Carbon Location and Association with Polycyclic Aromatic Hydrocarbons (PAHs) in Contaminated Sediment Upal Ghosh1 , Richard G. Luthy1 , J. Seb Gillette2 , and Richard N long-term issue confronting sediment bioremediation is the lack of understanding of contaminant-sediment

396

Removal of polycyclic aromatic hydrocarbons (PAHs) from sewage sludge by anaerobic degradation  

E-Print Network [OSTI]

for treatment in EU, followed by spreading on land, which accounted for 37% of the sewage sludge produced allow recycling of nutrients. Hence, bioprocessed sewage sludge application on agricultural soilRemoval of polycyclic aromatic hydrocarbons (PAHs) from sewage sludge by anaerobic degradation N

397

UV absorption of CO2 for temperature diagnostics of hydrocarbon combustion applications  

E-Print Network [OSTI]

UV absorption of CO2 for temperature diagnostics of hydrocarbon combustion applications J temperature, CO2 is transparent in the ultraviolet (UV) at wavelengths longer than 205 nm; however, at temperatures above 1000 K the CO2 absorption cross-section becomes significant in the region between 200

Lee, Tonghun

398

The nature and formation of coke in the reaction of methanol to hydrocarbons over chabazite  

E-Print Network [OSTI]

). Reactant: methanol t-butanol 1-heotanol Reaction conditions Temp. (K) LHSV (hr ) 644 1. 0 644 1. 0 644 0. 7 Conversion (g) 1 00 100 99. 9 Hydrocarbon distribution (wt g) methane ethane ethylene propane propylene i-butane n-butane bu...

McLaughlin, Kenneth Woot

1983-01-01T23:59:59.000Z

399

Forecasting, Sensitivity and Economic Analysis of Hydrocarbon Production from Shale Plays Using Artificial Intelligence & Data Mining  

E-Print Network [OSTI]

SPE 162700 Forecasting, Sensitivity and Economic Analysis of Hydrocarbon Production from Shale-cluster, multi-stage hydraulic fractures, that have proven to be essential for economic recovery from Shale plays, sensitivity and economic analysis are performed in order to identify the impact of different reservoir

Mohaghegh, Shahab

400

Degradation of Total Petroleum Hydrocarbon and BTEX Compounds in Produced Water  

SciTech Connect (OSTI)

Petroleum Environmental Technologies, LLC entered into a Cooperative Research and Development agreement with the Rocky Mountain Oilfield Testing Center to an in-situ pit treatment demonstration and produced water treatment demonstration. The purpose of the test is to demonstrate the degradation of petroleum hydrocarbon compounds in soil and aqueous matrices where ECOSAFE is applied to enhance the degradation of these contaminants.

Jackson, Lorri

2002-04-01T23:59:59.000Z

Note: This page contains sample records for the topic "non-methane hydrocarbons nmhc" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Chlorinated hydrocarbon contaminants in feces of river otters from the southern Pacific  

E-Print Network [OSTI]

, and polychlorinated dioxins (PCDDs) and furans (PCDFs), while in 2004, chemistry was confined to PCBs and OC) detected in all samples. In 1998, octachlorodibenzo-p-dioxin (OCDD) and other higher chlorinated PCDD, polychlorinated biphenyls (PCBs), dioxins (PCDDs), furans (PCDFs), polycyclic aromatic hydrocarbons (PAHs

402

UV Resonance Raman Characterization of Polycyclic Aromatic Hydrocarbons in Coal Liquid Distillates*  

E-Print Network [OSTI]

UV Resonance Raman Characterization of Polycyclic Aromatic Hydrocarbons in Coal Liquid Distillates samples, such as petroleum and coal, or for man-made samples, such as coal liquids, a major desire- nique for studying coal-liquid samples. 1-4 We demon- strated that the Raman spectra of polycyclic

Asher, Sanford A.

403

Nitrated and oxygenated derivatives of polycyclic aromatic hydrocarbons in the ambient air of two  

E-Print Network [OSTI]

polycyclic aromatic hydrocarbons; Size distribution; Atmospheric pollution; POVA (POllution des Vallées, published in "Atmospheric Environment 42, 173 (2008) 55 à 64" DOI : 10.1016/j.atmosenv.2007.10.008 #12 was determined during the intensive sampling campaigns of the POVA (POllution des Vallées Alpines) research

Boyer, Edmond

404

Hypothetical Thermodynamic Properties. Subcooled Vaporization Enthalpies and Vapor Pressures of Polyaromatic Hydrocarbons  

E-Print Network [OSTI]

of Polyaromatic Hydrocarbons William Hanshaw, Marjorie Nutt, and James S. Chickos* Department of Chemistry enthalpies, they can provide sublimation enthalpies of compounds that are too nonvolatile to be measured of a sublimation enthalpy measurement. Despite their usefulness, there is only a limited amount of such data

Chickos, James S.

405

Final technical report [ACCELERATED MOLECULAR DYNAMICS SIMULATIONS OF REACTIVE HYDROCARBON SYSTEMS  

SciTech Connect (OSTI)

The research activities in this project consisted of four different sub-projects. Three different accelerated dynamics techniques (parallel replica dynamics, hyperdynamics, and temperature-accelerated dynamics) were applied to the modeling of pyrolysis of hydrocarbons. In addition, parallel replica dynamics was applied to modeling of polymerization.

Stuart, Steven J.

2014-02-25T23:59:59.000Z

406

Process, including PSA and membrane separation, for separating hydrogen from hydrocarbons  

DOE Patents [OSTI]

An improved process for separating hydrogen from hydrocarbons. The process includes a pressure swing adsorption step, a compression/cooling step and a membrane separation step. The membrane step relies on achieving a methane/hydrogen selectivity of at least about 2.5 under the conditions of the process.

Baker, Richard W. (Palo Alto, CA); Lokhandwala, Kaaeid A. (Union City, CA); He, Zhenjie (Fremont, CA); Pinnau, Ingo (Palo Alto, CA)

2001-01-01T23:59:59.000Z

407

CHEMISTRY OF METHANE AND RELATED HYDROCARBONS IN THE ATMOSPHERE OF MARS.  

E-Print Network [OSTI]

CHEMISTRY OF METHANE AND RELATED HYDROCARBONS IN THE ATMOSPHERE OF MARS. F. Lefèvre, LATMOS, Paris detection of methane on Mars [1,2,3,4] has revived the possibility of past or extant life on this planet of the recent observations of methane on Mars is that methane concentrations appear to be locally enhanced

408

Prediction of Solid Polycyclic Aromatic Hydrocarbons Solubility in Water with the NRTL-PR Model  

E-Print Network [OSTI]

processes of PAH with subcritical water [5,6] since it provides the extractability limit which can be used groups, for the representation of the solubility of solid PAH in subcritical water. These hal-00872639Prediction of Solid Polycyclic Aromatic Hydrocarbons Solubility in Water with the NRTL-PR Model

Paris-Sud XI, Université de

409

Mathematical Modeling of Carbon Dioxide Injection in the Subsurface for Improved Hydrocarbon Recovery and Sequestration  

E-Print Network [OSTI]

Mathematical Modeling of Carbon Dioxide Injection in the Subsurface for Improved Hydrocarbon Recovery and Sequestration Philip C. Myint, Laurence Rongy, Kjetil B. Haugen, Abbas Firoozabadi Department. Combustion of fossil fuels contributes to rising atmospheric carbon dioxide (CO2) levels that have been

Firoozabadi, Abbas

410

Novel Methane, Ethane, and Propane Oxidizing Bacteria at Marine Hydrocarbon Seeps Identified by Stable Isotope Probing  

E-Print Network [OSTI]

Novel Methane, Ethane, and Propane Oxidizing Bacteria at Marine Hydrocarbon Seeps Identified by Stable Isotope Probing Running Title: Novel Methane, Ethane, and Propane Oxidizing Bacteria Section incubating sediment with 13 C-labeled methane, ethane, or propane, we5 confirmed the incorporation of 13 C

Sessions, Alex L.

411

Glow Discharge Enhanced Chemical Reaction: Application in Ammonia Synthesis and Hydrocarbon Gas Cleanup  

E-Print Network [OSTI]

hydrocarbons mixture such as EPE (74.8% methane, 8% ethane, 8% ethylene, 2.1% propane and 1.1% Propene). Non-thermal plasmas, due to their unique non-equilibrium characteristics, offer advantages as method of reforming at lower temperature (100-150 ...

Ming, Pingjia

2014-06-05T23:59:59.000Z

412

Oil and Gas CDT Quantifying the role of groundwater in hydrocarbon systems using noble gas  

E-Print Network [OSTI]

Oil and Gas CDT Quantifying the role of groundwater in hydrocarbon systems using noble gas isotopes by groundwater (or oil) degassing. Other natural gas fields may have been produced in-situ or migrated as a free expert academics from across the CDT and also experienced oil and gas industry professionals

Henderson, Gideon

413

Hydrocarbon anomaly in soil gas as near-surface expressions of upflows and outflows in geothermal systems  

SciTech Connect (OSTI)

A variety of hydrocarbons, C1 - C12, have been found in volcanic gases (fumarolic) and in geothermal waters and gases. The hydrocarbons are thought to have come from products of pyrolysis of kerogen in sedimentary rocks or they could be fed into the geothermal system by the recharging waters which may contain dissolved hydrocarbons or hydrocarbons extracted by the waters from the rocks. In the hot geothermal zone, 300+ C, many of these hydrocarbons are in their critical state. It is thought that they move upwards due to buoyancy and flux up with the upflowing geothermal fluids in the upflow zones together with the magmatic gases. Permeability which could be provided by faults, fissures, mini and micro fractures are thought to provide pathways for the upward flux. A sensitive technique (Petrex) utilizing passive integrative adsorption of the hydrocarbons in soil gas on activated charcoal followed by desorption and analysis of the hydrocarbons by direct introduction mass spectrometry allows mapping of the anomalous areas. Surveys for geothermal resources conducted in Japan and in Indonesia show that the hydrocarbon anomaly occur over known fields and over areas strongly suspected of geothermal potential. The hydrocarbons found and identified were n-paraffins (C7-C9) and aromatics (C7-C8). Detection of permeable, i.e. active or open faults, parts of older faults which have been reactivated, e.g. by younger intersecting faults, and the area surrounding these faulted and permeable region is possible. The mechanism leading to the appearance of the hydrocarbon in the soil gas over upflow zones of the geothermal reservoir is proposed. The paraffins seems to be better pathfinders for the location of upflows than the aromatics. However the aromatics may, under certain circumstances, give better indications of the direction of the outflow of the geothermal system. It is thought that an upflow zone can be defined when conditions exist where the recharging waters containing the hydrocarbons feed into the geothermal kitchen. The existence of open and active faults, fissures, mini and micro fractures allow sufficient permeability for the gases to flux up and express themselves at the surface as hydrocarbon anomaly in the soil gas. When any of the requirements is absent, i.e. in the absence of the recharging waters, hydrocarbons, temperature, or permeability, no anomaly can be expected. It assumes a dynamic convective system, i.e. recharging waters, upflow and outflow. The anomalies however can define to a certain extent, regions of geothermal upflow, buoyant transport of gases, and frequently down-gradient of cooling waters.

Ong, H.L.; Higashihara, M.; Klusman, R.W.; Voorhees, K.J.; Pudjianto, R.; Ong, J

1996-01-24T23:59:59.000Z

414

ASSESSMENT OF HYDROCARBON SEEPAGE DETECTION METHODS ON THE FORT PECK RESERVATION, NORTHEAST MONTANA  

SciTech Connect (OSTI)

Surface exploration techniques have been employed in separate study areas on the Fort Peck Reservation in northeastern Montana. Anomalies associated with hydrocarbon seepage are documented in all three areas and a variety of surface exploration techniques can be compared. In a small area with established production, Head Gas and Thermal Desorption methods best match production; other methods also map depletion. In a moderate-size area that has prospects defined by 3D seismic data, Head Gas along with Microbial, Iodine, and Eh soil anomalies are all associated with the best hydrocarbon prospect. In a large area that contains many curvilinear patterns observed on Landsat images, that could represent micro-seepage chimneys, results are inconclusive. Reconnaissance mapping using Magnetic Susceptibility has identified a potential prospect; subsequent Soil Gas and Head Gas surveys suggest hydrocarbon potential. In the final year of this project the principle contractor, the Fort Peck Tribes, completed a second survey in the Wicape 3D Seismic Prospect Area (also known as Area 6 in Phase I of the project) and sampled several Landsat image features contained in the Smoke Creek Aeromag Anomaly Area (also known as Area 1 in Phase II of the project). Methods determined to be most useful in Phases I and II, were employed in this final Phase III of the study. The Southwest Wicape seismic anomaly was only partially confirmed. The abundant curvilinears proposed to be possible hydrocarbon micro-seepage chimneys in the Smoke Creek Area were not conclusively verified as such. Insufficient sampling of background data precludes affirmative identification of these mostly topographic Landsat features as gas induced soil and vegetation anomalies. However relatively higher light gas concentrations were found associated with some of the curvilinears. Based on the findings of this work the Assiniboine & Sioux Tribes of the Fort Peck Reservation intend to utilize surface hydrocarbon exploration techniques for future identification and confirmation of oil and gas prospects.

Lawrence M. Monson

2003-06-30T23:59:59.000Z

415

A chemical kinetic model of hydrocarbon generation from the Bakken Formation, Williston Basin, North Dakota  

SciTech Connect (OSTI)

This report describes a model of hydrocarbon generation and expulsion in the North Dakota portion of the Williston Basin. The modeling incorporates kinetic methods to simulate chemical reactions and 1-dimensional conductive heat flow models to simulate thermal histories of the Mississippian-Devonian Bakken Formation source rock. We developed thermal histories of the source rock for 53 wells in the basin using stratigraphic and heat flow data obtained by the University of North Dakota. Chemical kinetics for hydrocarbon generation, determined from Pyromat pyrolysis, were, then used with the diennal histories to calculate the present day value of the Rock-Eval T{sub max} for each well. The calculated Rock-Eval T{sub max} values agreed with measured values within amounts attributable to uncertainties in the chemical kinetics and the heat flow. These optimized thermal histories were then used with a more detailed chemical kinetic model of hydrocarbon generation and expulsion, modified from a model developed for the Cretaceous La Luna shale, to simulate pore pressure development and detailed aspects of the hydrocarbon chemistry. When compared to values estimated from sonic logs, the pore pressure calculation underestimates the role of hydrocarbon generation and overestimates the role of compaction disequilibrium, but it matches well the general areal extent of pore pressures of 0.7 times lithostatic and higher. The simulated chemistry agrees very well with measured values of HI, PI, H/C atomic ratio of the kerogen, and Rock-Eval S1. The model is not as successful in simulating the amount of extracted bitumen and its saturate content, suggesting that detailed hydrous pyrolysis experiments will probably be needed to further refine the chemical model.

Sweeney, J.J.; Braun, R.L.; Burnham, A.K. [Lawrence Livermore National Lab., CA (United States); Gosnold, W.D. [North Dakota Univ., Grand Forks, ND (United States)

1992-10-01T23:59:59.000Z

416

Recognition of hydrocarbon expulsion using well logs: Bakken Formation, Williston Basin  

SciTech Connect (OSTI)

The Upper Mississippian-Lower Devonian Bakken Formation forms a source/carrier/reservoir system in the Williston basin. Hydrocarbon expulsion within the Bakken has been identified by overlaying sonic and resistivity logs. Typically, these curves track in organically lean, water-saturated mudrocks because both respond mainly to porosity; however, in thermally mature organic-rich rocks and hydrocarbon reservoirs or carrier beds, the curves separate due to the anomalously high resistivity associated with replacement of pore water by hydrocarbons. Sonic/resistivity-log overlays for wells throughout the Montana and North Dakota parts of the Williston basin reveal significant increases and maximum in-curve separation within the middle siltstone member of the Bakken at subsurface temperatures of about 170 and 200{degree}F, respectively. Sequence-stratigraphic characteristics of the Bakken define the framework within which the expulsion process operates. The organic-rich upper and lower shale members represent the transgressive and early highstand systems tracts of two adjacent depositional sequences. A sequence boundary within the intervening middle siltstone member separates nearshore siltstone and sandstone of the late highstand systems tract in the lower sequence from cross-bedded subtidal to intertidal sandstones of the lowstand systems tract in the upper sequence. Reservoir properties vary across this sequence boundary. The authors attribute the log separation in the siltstone member to hydrocarbons expelled from the adjacent shales. Abrupt shifts in several geochemical properties of the shale members, indicative of hydrocarbon generation occur over the same subsurface temperature range as the rapid increase in log separation in the middle siltstone, thus indicating the contemporaneity of generation and expulsion.

Cunningham, R.; Zelt, F.B.; Morgan, S.R.; Passey, Q.R. (Exxon Production Research Co., Houston, TX (USA)); Snavely, P.D. III; Webster, R.L. (Exxon Co., U.S.A., Houston, TX (USA))

1990-05-01T23:59:59.000Z

417

Correlation between speciated hydrocarbon emissions and flame ionization detector response for gasoline/alcohol blends .  

SciTech Connect (OSTI)

The U.S. renewable fuel standard has made it a requirement to increase the production of ethanol and advanced biofuels to 36 billion by 2022. Ethanol will be capped at 15 billion, which leaves 21 billion to come from other sources such as butanol. Butanol has a higher energy density and lower affinity for water than ethanol. Moreover, alcohol fueled engines in general have been shown to positively affect engine-out emissions of oxides of nitrogen and carbon monoxide compared with their gasoline fueled counterparts. In light of these developments, the variety and blend levels of oxygenated constituents is likely to increase in the foreseeable future. The effect on engine-out emissions for total hydrocarbons is less clear due to the relative insensitivity of the flame ionization detector (FID) toward alcohols and aldehydes. It is well documented that hydrocarbon (HC) measurement using a conventional FID in the presence of oxygenates in the engine exhaust stream can lead to a misinterpretation of HC emissions trends for alcohol fuel blends. Characterization of the exhaust stream for all expected hydrocarbon constituents is required to accurately determine the actual concentration of unburned fuel components in the exhaust. In addition to a conventional exhaust emissions bench, this characterization requires supplementary instrumentation capable of hydrocarbon speciation and response factor independent quantification. Although required for certification testing, this sort of instrumentation is not yet widely available in engine development facilities. Therefore, an attempt is made to empirically determine FID correction factors for oxygenate fuels. Exhaust emissions of an engine fueled with several blends of gasoline and ethanol, n-butanol and iso-Butanol were characterized using both a conventional FID and a Fourier transform infrared. Based on these results, a response factor predicting the actual hydrocarbon emissions based solely on FID results as a function of alcohol type and content is presented. Finally, the correlation derived from data presented in this study is compared with equations and results found in the literature.

Wallner, T. (Energy Systems)

2011-08-01T23:59:59.000Z

418

The evolution and hydrocarbon habitat of the Papuan fold belt, PNG  

SciTech Connect (OSTI)

After over 70 years of hydrocarbon exploration in the Papuan fold belt of PNG (Papua New Guinea) there have been a number of hydrocarbon discoveries over recent years that have confirmed its potential as a significant producing province. The Papuan basin developed during the early Mesozoic as part of the northeast corner of the Australian passive margin. The basin's tertiary evolution and the development of the Papuan fold belt within the Papuan basin has evolved in response to oblique convergence between the northerly moving Australian plate and westerly moving Pacific plate. Restacking of the Mesozoic passive margin sequence within the Papuan Basin was initiated in the early miocene by southward abduction of the Solomon Sea plate and the subsequent collision, in the late Miocene, of the Melanesian Island arc along the northeastern margin of PNG. This later collision provided the driving mechanism for the development of the papuan thrust belt. To date, all the significant hydrocarbon discoveries made within the Papuan fold belt have been located within the frontal zone of the fold belt, which is characterized by relatively simple ramp anticlines and thick-skinned inversion structures. The primary proven reservoir fairway is the Jurassic Toro formation, which is a sequence of stacked submarine bars prograding out across a shallow-marine low-gradient shelf. Geochemical analysis of produced hydrocarbons and samples collected from the many surface seeps found in the fold belt indicate two main families of oil. A model explains the distribution of hydrocarbons discovered to date, which involves Jurassic and Cretaceous source intervals and a complex history of secondary migration and entrapment. The unique technical problems associated with exploration of the Papuan fold belt leave many elements of the proven play systems uncertain, but in so doing, they present many challenges and opportunities for the future.

Dalton, D.G.; Smith, R.I.; Cawley, S.J. (BP Australia Ltd., Melbourne, Victoria (Australia))

1990-05-01T23:59:59.000Z

419

A 4D synchrotron X-ray tomography study of the formation of hydrocarbon migration pathways in heated organic-rich shale  

E-Print Network [OSTI]

Recovery of oil from oil shales and the natural primary migration of hydrocarbons are closely related processes that have received renewed interests in recent years because of the ever tightening supply of conventional hydrocarbons and the growing production of hydrocarbons from low permeability tight rocks. Quantitative models for conversion of kerogen into oil and gas and the timing of hydrocarbon generation have been well documented. However, lack of consensus about the kinetics of hydrocarbon formation in source rocks, expulsion timing and how the resulting hydrocarbons escape from or are retained in the source rocks motivates further investigation. In particular, many mechanisms for the transport of hydrocarbons from the source rocks in which they are generated into adjacent rocks with higher permeabilities and smaller capillary entry pressures have been proposed, and a better understanding of this complex process (primary migration) is needed. To characterize these processes it is imperative to use the ...

Panahi, Hamed; Renard, Francois; Mazzini, Adriano; Scheibert, Julien; Dysthe, Dag Kristian; Jamtveit, Bjorn; Malthe-Srenssen, Anders; Meakin, Paul

2014-01-01T23:59:59.000Z

420

Process Design and Economics for the Conversion of Lignocellulosic Biomass to Hydrocarbons: Dilute-Acid and Enzymatic Deconstruction of Biomass to Sugars and Biological Conversion of Sugars to Hydrocarbons  

SciTech Connect (OSTI)

This report describes one potential conversion process to hydrocarbon products by way of biological conversion of lingnocellulosic-dervied sugars. The process design converts biomass to a hydrocarbon intermediate, a free fatty acid, using dilute-acid pretreatement, enzymatic saccharification, and bioconversion. Ancillary areas--feed handling, hydrolysate conditioning, product recovery and upgrading (hydrotreating) to a final blendstock material, wastewater treatment, lignin combusion, and utilities--are also included in the design.

Davis, R.; Tao, L.; Tan, E. C. D.; Biddy, M. J.; Beckham, G. T.; Scarlata, C.; Jacobson, J.; Cafferty, K.; Ross, J.; Lukas, J.; Knorr, D.; Schoen, P.

2013-10-01T23:59:59.000Z

Note: This page contains sample records for the topic "non-methane hydrocarbons nmhc" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

242-A Evaporator/plutonium uranium extraction (PUREX) effluent treatment facility (ETF) nonradioactive air emission test report  

SciTech Connect (OSTI)

This report shows the methods used to test the stack gas outlet concentration and emission rate of Volatile Organic Compounds as Total Non-Methane Hydrocarbons in parts per million by volume,grams per dry standard cubic meter, and grams per minute from the PUREX ETF stream number G6 on the Hanford Site. Test results are shown in Appendix B.1.

Hill, J.S., Westinghouse Hanford

1996-05-10T23:59:59.000Z

422

Tap cogen-plant steam for process, NO[sub x] control  

SciTech Connect (OSTI)

This article describes the Monsanto's Indian Orchard plant gas-fired, combined-cycle cogeneration facility in Springfield, Massachusetts. The topics of the article include project configuration, the thermodynamic cycle, fuel selection, electrical distribution system, plant control, and air pollution control of NO[sub X], SO[sub 2], CO, particulates, non-methane hydrocarbons, opacity and ammonia.

Engel, W.J.; Haviland, R.W.; Devine, D.A.

1993-04-01T23:59:59.000Z

423

Sequence stratigraphy of the upper San Andres and Grayburg formations, Waddell Field, Crane County, Texas: implications for hydrocarbon reservoir distribution  

E-Print Network [OSTI]

The upper San Andres and Grayburg formations (Guadalupian) were deposited on carbonate platforms around the Permian Basin region and are extensive hydrocarbon reservoirs in the region. The Waddell Field (East Waddell Ranch) on the eastern margin...

Pinsonnault, Scott Michael

1996-01-01T23:59:59.000Z

424

Reducing cold start hydrocarbon emissions from port fuel injected spark ignition engines with improved management of hardware & controls  

E-Print Network [OSTI]

An experimental study was performed to investigate strategies for reducing cold start hydrocarbon (HC) emissions from port fuel injected (PFI) spark ignition (SI) engines with better use of existing hardware and control ...

Lang, Kevin R., 1980-

2006-01-01T23:59:59.000Z

425

Z .Comparative Biochemistry and Physiology Part B 129 2001 871 882 Hydrocarbon-released nestmate aggression in the  

E-Print Network [OSTI]

Z .Comparative Biochemistry and Physiology Part B 129 2001 871 882 Hydrocarbon-released nestmate;( )D. Liang et al. rComparati¨e Biochemistry and Physiology Part B 129 2001 871 882872 The Argentine

Buckel, Jeffrey A.

426

Long-Range Atmospheric Transport of Polycyclic Aromatic Hydrocarbons: A Global 3-D Model Analysis Including Evaluation of Arctic Sources  

E-Print Network [OSTI]

We use the global 3-D chemical transport model GEOS-Chem to simulate long-range atmospheric transport of polycyclic aromatic hydrocarbons (PAHs). To evaluate the models ability to simulate PAHs with different volatilities, ...

Friedman, Carey

427

Effect of in-cylinder liquid fuel films on engine-out unburned hydrocarbon emissions for SI engines  

E-Print Network [OSTI]

Nearly all of the hydrocarbon emissions from a modern gasoline-fueled vehicle occur when the engine is first started. One important contributing factor to this is the fact that, during this time, temperatures throughout ...

Costanzo, Vincent S. (Vincent Stanley), 1979-

2011-01-01T23:59:59.000Z

428

Exhaust after-treatment system with in-cylinder addition of unburnt hydrocarbons  

DOE Patents [OSTI]

Certain exhaust after-treatment devices, at least periodically, require the addition of unburnt hydrocarbons in order to create reductant-rich exhaust conditions. The present disclosure adds unburnt hydrocarbons to exhaust from at least one combustion chamber by positioning, at least partially within a combustion chamber, a mixed-mode fuel injector operable to inject fuel into the combustion chamber in a first spray pattern with a small average angle relative to a centerline of the combustion chamber and a second spray pattern with a large average angle relative to the centerline of the combustion chamber. An amount of fuel is injected in the first spray pattern into a non-combustible environment within the at least one combustion chamber during at least one of an expansion stroke and exhaust stroke. The exhaust with the unburnt amount of fuel is moved into an exhaust passage via an exhaust valve.

Coleman, Gerald N. (Corby, GB); Kesse, Mary L. (Peoria, IL)

2007-10-30T23:59:59.000Z

429

Process and apparatus for the production of hydrogen by steam reforming of hydrocarbon  

DOE Patents [OSTI]

In the steam reforming of hydrocarbon, particularly methane, under elevated temperature and pressure to produce hydrogen, a feed of steam and hydrocarbon is fed into a first reaction volume containing essentially only reforming catalyst to partially reform the feed. The balance of the feed and the reaction products of carbon dioxide and hydrogen are then fed into a second reaction volume containing a mixture of catalyst and adsorbent which removes the carbon dioxide from the reaction zone as it is formed. The process is conducted in a cycle which includes these reactions followed by countercurrent depressurization and purge of the adsorbent to regenerate it and repressurization of the reaction volumes preparatory to repeating the reaction-sorption phase of the cycle.

Sircar, Shivaji (Wescosville, PA); Hufton, Jeffrey Raymond (Fogelsville, PA); Nataraj, Shankar (Allentown, PA)

2000-01-01T23:59:59.000Z

430

Method of upgrading oils containing hydroxyaromatic hydrocarbon compounds to highly aromatic gasoline  

DOE Patents [OSTI]

The present invention is a multi-stepped method of converting an oil which is produced by various biomass and coal conversion processes and contains primarily single and multiple ring hydroxyaromatic hydrocarbon compounds to highly aromatic gasoline. The single and multiple ring hydroxyaromatic hydrocarbon compounds in a raw oil material are first deoxygenated to produce a deoxygenated oil material containing single and multiple ring aromatic compounds. Then, water is removed from the deoxygenated oil material. The next step is distillation to remove the single ring aromatic compounds as gasoline. In the third step, the multiple ring aromatics remaining in the deoxygenated oil material are cracked in the presence of hydrogen to produce a cracked oil material containing single ring aromatic compounds. Finally, the cracked oil material is then distilled to remove the single ring aromatics as gasoline.

Baker, E.G.; Elliott, D.C.

1993-01-19T23:59:59.000Z

431

Investigations on potential bacteria for the bioremediation treatment of environments contaminated with hydrocarbons  

SciTech Connect (OSTI)

In Romania after more than 135 years of oil production and processing, some severe environmental pollution problems have accumulated. In this context a joint research group from Institute of Biology Bucharest and S.C. Petrostar S.A. Ploiesti became involved in a research project on bioremediation of an environment contaminated with hydrocarbon waste. In the first stage of this project, investigations on microbial communities occurring in environments contaminated with oil were carried out. In the second stage, the hundreds of bacterial strains and populations isolated from soils, slops, and water sites contaminated with waste oil and water waste oil mix were submitted to a screening program, to select a naturally occurring mixed culture with a high ability to degrade hydrocarbons.

Lazar, I.; Voicu, A.; Dobrota, S.; Stefanescu, M. [Institute of Biology of Romanian Academy, Bucharest (Romania)] [and others

1995-12-31T23:59:59.000Z

432

Counterdiffusion of liquid hydrocarbon pairs in ion-exchanged forms of zeolite X  

SciTech Connect (OSTI)

Adsorptive counterdiffusion rates of liquid benzene, ethyl benzene, 1,3,5-trimethyl benzene, and 1-methyl naphthalene into Na/sup +/, K/sup +/, Cs/sup +/, and Ca/sup 2 +/ ion exchanged forms of zeolite X saturated with cyclohexane were measured. The diffusivity of the adsorbing hydrocarbon decreases as the effective pore size of the zeolite is decreased by ion exchange. The effective pore size in CaX and CsX was so small as not to allow the adsorptive counterdiffusion of 1,3,5-trimethyl benzene and 1-methyl naphthalene. Diffusion took place only after the cations in the pore mouths were displaced to other cation sites in the structure under the influence of the adsorbing hydrocarbon molecules, and thus the rate of counterdiffusion appeared to increase with time.

Culfaz, A.; Erguen, G.

1986-01-01T23:59:59.000Z

433

Ignition quality determination of diesel fuels from hydrogen type distribution of hydrocarbons  

SciTech Connect (OSTI)

Hydrogen types of diesel like hydrocarbon fuels which have dominant effect on the ignition quality have been identified. A scheme of characterizing the chemistry of hydrocarbon fuels in terms of these hydrogen types using proton nuclear resonance spectrometry has been proposed. Using this analysis technique on 70 different diesel fuels, whose cetane numbers were determined on a number of standard cetane rating engines, an empirical expression which relates the ignition quality to the hydrogen type distribution of the fuels has been developed. The developed expression and the relationship between the ignition delay and cetane number imply that the effective activation energy term in the usual semiempirical ignition delay expression is not a constant for a given fuel but is a function of pressure and temperature as well as the fuel chemistry.

Gulder, O.L.; Glavincevski, B.

1986-02-01T23:59:59.000Z

434

High-energy-density solid and liquid hydrocarbon fuels. Final report, July 1987-December 1988  

SciTech Connect (OSTI)

The development of new high-energy hydrocarbon fuels for use in air-breathing missiles has been the objective of a number of investigations which have received support during the past decade through programs sponsored by the Air Force Systems Command and/or the Naval Air Systems Command. The key characteristics which must be met by potential cruise missile fuels have been described by Burdette and coworkers. A primary requirement in this regard is that candidate fuels must possess high net volumetric heat of combustion (preferably greater than 160,000 BTU/gallon). In order to meet the primary requirement of high net volumetric heat of combustion, hydrocarbon systems have been sought which maximize the ratio of carbon-atom to hydrogen-atom content have been sought that maximize the ratio n/m.(JES)

Marchand, A.P.

1989-02-01T23:59:59.000Z

435

Method for estimating processability of a hydrocarbon-containing feedstock for hydroprocessing  

DOE Patents [OSTI]

Disclosed herein is a method involving the steps of (a) precipitating an amount of asphaltenes from a liquid sample of a first hydrocarbon-containing feedstock having solvated asphaltenes therein with one or more first solvents in a column; (b) determining one or more solubility characteristics of the precipitated asphaltenes; (c) analyzing the one or more solubility characteristics of the precipitated asphaltenes; and (d) correlating a measurement of feedstock reactivity for the first hydrocarbon-containing feedstock sample with a mathematical parameter derived from the results of analyzing the one or more solubility characteristics of the precipitates asphaltenes. Determined parameters and processabilities for a plurality of feedstocks can be used to generate a mathematical relationship between parameter and processability; this relationship can be used to estimate the processability for hydroprocessing for a feedstock of unknown processability.

Schabron, John F; Rovani, Jr., Joseph F

2014-01-14T23:59:59.000Z

436

Autothermal reforming of sulfur-free and sulfur-containing hydrocarbon liquids  

SciTech Connect (OSTI)

The mechanisms by which various fuel component hydrocarbons related to both heavy petroleum and coal-derived liquids are converted to hydrogen without forming carbon were investigated. Reactive differences between paraffins and aromatics in autothermal reforming (ATR) were shown to be responsible for the observed fuel-specific carbon formation characteristics. The types of carbon formed in the reformer were identified by SEM and XRD analyses of catalyst samples and carbon deposits. From tests with both light and heavy paraffins and aromatics, it is concluded that high boiling point hydrocarbons and polynuclear aromatics enhance the propensity for carbon formation. The effects of propylene addition on the ATR performance of benzene are described. In ATR tests with mixtures of paraffins and aromatics, synergistic effects on conversion characteristics were identified. Indications that the sulfur content of the fuel may be the limiting factor for efficient ATR operation were found. The conversion and degradation effects of the sulfur additive (thiophene) were examined.

Not Available

1981-10-01T23:59:59.000Z

437

Apparatus for converting hydrocarbon fuel into hydrogen gas and carbon dioxide  

DOE Patents [OSTI]

Hydrocarbon fuel reformer 100 suitable for producing synthesis hydrogen gas from reactions with hydrocarbons fuels, oxygen, and steam. A first tube 108 has a first tube inlet 110 and a first tube outlet 112. The first tube inlet 110 is adapted for receiving a first mixture including an oxygen-containing gas and a first fuel. A partially oxidized first reaction reformate is directed out of the first tube 108 into a mixing zone 114. A second tube 116 is annularly disposed about the first tube 108 and has a second tube inlet 118 and a second tube outlet 120. The second tube inlet 118 is adapted for receiving a second mixture including steam and a second fuel. A steam reformed second reaction reformate is directed out of the second tube 116 and into the mixing zone 114. From the mixing zone 114, the first and second reaction reformates may be directed into a catalytic reforming zone 144 containing a reforming catalyst 147.

Clawson, Lawrence G. (7 Rocky Brook Rd., Dover, MA 02030); Mitchell, William L. (111 Oakley Rd., Belmont, MA 02178); Bentley, Jeffrey M. (20 Landmark Rd., Westford, MA 01886); Thijssen, Johannes H. J. (1 Richdale Ave.#2, Cambridge, MA 02140)

2002-01-01T23:59:59.000Z

438

Process for the production of ethylene and other hydrocarbons from coal  

SciTech Connect (OSTI)

A process is claimed for the production of substantial amounts of ethylene and other hydrocarbon compounds, such as benzene from coal. Coal is reacted with methane at a temperature in the approximate range of 500/sup 0/C to 1100/sup 0/C at a partial pressure less than about 200 psig for a period of less than 10 seconds, and preferably at a temperature of approximately 850/sup 0/C, and a partial pressure of 50 psig for a period of approximately 2 seconds. Ethylene and other hydrocarbon compounds may be separated from the product stream so produced, and the methane recycled for further production of ethylene. In another embodiment, other compounds produced, such as by-product tars, may be burned to heat the recycled methane.

Steinberg, M.; Fallon, P.

1982-02-16T23:59:59.000Z

439

Method of upgrading oils containing hydroxyaromatic hydrocarbon compounds to highly aromatic gasoline  

DOE Patents [OSTI]

The present invention is a multi-stepped method of converting an oil which is produced by various biomass and coal conversion processes and contains primarily single and multiple ring hydroxyaromatic hydrocarbon compounds to highly aromatic gasoline. The single and multiple ring hydroxyaromatic hydrocarbon compounds in a raw oil material are first deoxygenated to produce a deoxygenated oil material containing single and multiple ring aromatic compounds. Then, water is removed from the deoxygenated oil material. The next step is distillation to remove the single ring aromatic compouns as gasoline. In the third step, the multiple ring aromatics remaining in the deoxygenated oil material are cracked in the presence of hydrogen to produce a cracked oil material containing single ring aromatic compounds. Finally, the cracked oil material is then distilled to remove the single ring aromatics as gasoline.

Baker, Eddie G. (Richland, WA); Elliott, Douglas C. (Richland, WA)

1993-01-01T23:59:59.000Z

440

Method for forming a potential hydrocarbon sensor with low sensitivity to methane and CO  

DOE Patents [OSTI]

A hydrocarbon sensor is formed with an electrolyte body having a first electrolyte surface with a reference electrode depending therefrom and a metal oxide electrode body contained within the electrolyte body and having a first electrode surface coplanar with the first electrolyte surface. The sensor was formed by forming a sintered metal-oxide electrode body and placing the metal-oxide electrode body within an electrolyte powder. The electrolyte powder with the metal-oxide electrode body was pressed to form a pressed electrolyte body containing the metal-oxide electrode body. The electrolyte was removed from an electrolyte surface above the metal-oxide electrode body to expose a metal-oxide electrode surface that is coplanar with the electrolyte surface. The electrolyte body and the metal-oxide electrode body were then sintered to form the hydrocarbon sensor.

Mukundan, Rangachary (Santa Fe, NM); Brosha, Eric L. (Los Alamos, NM); Garzon, Fernando (Santa Fe, NM)

2003-12-02T23:59:59.000Z

Note: This page contains sample records for the topic "non-methane hydrocarbons nmhc" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

The effect of hydrocarbons on the electrochemical potential across porous media  

E-Print Network [OSTI]

and potential across porous media containing hydro- carbons. To fill this need, research was uruiegtaken with the objective to measure the electrochemical potential across porous media at various hydrocarbon saturations, and to correlate any significant... Central Scientific Co. Megavac vacuum pump, capable of reducing the pressure to . 000i mm of mercury. Centrifuge Water saturation was controlled in each sample by means of an International Equipment Co. Model CAK Centrifuge shown in Figure 6. A...

McCall, Charles Mark

1970-01-01T23:59:59.000Z

442

Catalytic hydrodechlorination of industrial wastewater containing chlorinated hydrocarbons in a trickle bed reactor  

E-Print Network [OSTI]

reaction has long been applied in chemical synthesis and liquid organic waste decomposition, very little attention is devoted to direct treatment of chlorinated hydrocarbons in wastewater (aqueous) or contannnated groundwater with hydrogen. The main..., Trichlorobenzene m Benzene Catal sts Group VIII Metals (Pt, Pd, Rh, Ru, Os, Ir, Ni) Rare earth oxide of the Lanthanide series and metal of the Platinum u Supported Palladium catalyst Tem efature 80 - 2750C 400 - 600'C 170 C Pressure atm...

Leong, Chee Kong

1996-01-01T23:59:59.000Z

443

Method for simultaneous recovery of hydrogen from water and from hydrocarbons  

DOE Patents [OSTI]

Method for simultaneous recovery of hydrogen and hydrogen isotopes from water and from hydrocarbons. A palladium membrane, when utilized in cooperation with a nickel catalyst in a reactor, has been found to drive reactions such as water gas shift, steam reforming and methane cracking to substantial completion by removing the product hydrogen from the reacting mixture. In addition, ultrapure hydrogen is produced, thereby eliminating the need for an additional processing step.

Willms, R. Scott (Los Alamos, NM)

1996-01-01T23:59:59.000Z

444

Hydrocarbon filling history from diagenetic evidence: Brent Group, UK North Sea  

E-Print Network [OSTI]

North Sea Mark Wilkinsona,*, R. Stuart Haszeldinea , Robert M. Ellamb , Tony E. Fallickb a Department, slow, filling phase (45­70 8C; 80­50 Ma) that formed an oil column with the oil­water contact of the present-day hydrocarbon charge was the last event in the history of the reservoir (90­100 8C; 10­0 Ma). q

Haszeldine, Stuart

445

Pyrolysis process for producing condensed stabilized hydrocarbons utilizing a beneficially reactive gas  

DOE Patents [OSTI]

In a process for recovery of values contained in solid carbonaceous material, the solid carbonaceous material is comminuted and then subjected to pyrolysis, in the presence of a carbon containing solid particulate source of heat and a beneficially reactive transport gas in a transport flash pyrolysis reactor, to form a pyrolysis product stream. The pyrolysis product stream contains a gaseous mixture and particulate solids. The solids are separated from the gaseous mixture to form a substantially solids-free gaseous stream which comprises volatilized hydrocarbon free radicals newly formed by pyrolysis. Preferably the solid particulate source of heat is formed by oxidizing part of the separated particulate solids. The beneficially reactive transport gas inhibits the reactivity of the char product and the carbon-containing solid particulate source of heat. Condensed stabilized hydrocarbons are obtained by quenching the gaseous mixture stream with a quench fluid which contains a capping agent for stabilizing and terminating newly formed volatilized hydrocarbon free radicals. The capping agent is partially depleted of hydrogen by the stabilization and termination reaction. Hydrocarbons of four or more carbon atoms in the gaseous mixture stream are condensed. A liquid stream containing the stabilized liquid product is then treated or separated into various fractions. A liquid containing the hydrogen depleted capping agent is hydrogenated to form a regenerated capping agent. At least a portion of the regenerated capping agent is recycled to the quench zone as the quench fluid. In another embodiment capping agent is produced by the process, separated from the liquid product mixture, and recycled.

Durai-Swamy, Kandaswamy (Culver City, CA)

1982-01-01T23:59:59.000Z

446

Method of Generating Hydrocarbon Reagents from Diesel, Natural Gas and Other Logistical Fuels  

DOE Patents [OSTI]

The present invention provides a process for producing reagents for a chemical reaction by introducing a fuel containing hydrocarbons into a flash distillation process wherein the fuel is separated into a first component having a lower average molecular weight and a second component having a higher average molecular weight. The first component is then reformed to produce synthesis gas wherein the synthesis gas is reacted catalytically to produce the desire reagent.

Herling, Darrell R (Richland, WA) [Richland, WA; Aardahl, Chris L. (Richland, WA) [Richland, WA; Rozmiarek, Robert T. (Middleton, WI) [Middleton, WI; Rappe, Kenneth G. (Richland, WA) [Richland, WA; Wang, Yong (Richland, WA) [Richland, WA; Holladay, Jamelyn D. (Kennewick, WA) [Kennewick, WA

2008-10-14T23:59:59.000Z

447

Optimum energy and by-product recovery in chlorinated hydrocarbon disposal systems  

SciTech Connect (OSTI)

This paper covers the three principal areas of a chlorinated hydrocarbon waste disposal system for a typical vinyl chloride monomer facility. These are the incineration, the energy recovery system, and the by-product recovery system. It is shown that the overall efficiency of the energy and by-product recovery systems is dependent on the optimization of the primary combustor (incineration system). 11 refs.

Santoleri, J.J.

1982-01-01T23:59:59.000Z

448

Hydrocarbon-bearing fluid inclusions in fluorite associated with the Windy Knoll bitumen deposit, UK  

SciTech Connect (OSTI)

Hydrocarbon-bearing fluid inclusions in fluorite, associated with an outcropping bitumen deposit at Windy Knoll, Derbyshire, have been analyzed in situ using a combination of microthermometry, Fourier transform infrared (FTIR) microspectrometry, and ultraviolet (UV) microscopy. The inclusions in these samples can be considered as a series with two end members: aqueous inclusions containing a low-density vapor phase and inclusions containing liquid oil' with no detectable aqueous phase. The majority of the inclusions are mixed types containing both aqueous and liquid hydrocarbon phases. Although microthermometry distinguishes at least two different aqueous fluids with varying homogenization temperatures and salinities, the oil fraction is cogenetic and trapped together with just one fluid, a low-salinity, low-calcium brine with an average homogenization temperature of 134C. The majority of the liquid hydrocarbon-bearing inclusions fluoresce bright blue under UV illumination with peaks around 475 nm, characteristic of paraffinic oils. The FTIR spectra of these inclusions are dominated by peaks assigned to aliphatic C-H bonding. However, inclusions have also been found which display a fluorescence typical of the red-shift associated with less mature oils. The FTIR spectra display peaks assigned to C{double bond}O, C-O, and O-CH{sub 2} bonding. This study presents new data on the in-situ analysis of hydrocarbon-bearing fluid inclusion from this important area of natural petroleum seepage and ore mineralization. The results suggest a direct link between the fluid inclusion populations, the outcropping bitumens, and fluorite deposition.

Moser, M.R. (Imperial College, London (United Kingdom) University College, London (United Kingdom)); Rankin, A.H. (Imperial College, London (United Kingdom)); Milledge, H.J. (University College, London (United Kingdom))

1992-01-01T23:59:59.000Z

449

Low-density hydrocarbon foams for laser fusion targets: Progress report, 1987  

SciTech Connect (OSTI)

This report describes progress made in the development of direct-drive hydrocarbon foam targets for laser inertial confinement fusion during 1987. The foam materials are polystyrene, resorcinol-formaldehyde, carbonized resorcinol-formaldehyde, and cellulose acetate. The processes for making the foams, their properties, characterization techniques, and the relationship of their properties to target specifications are presented. Progress in the creation and testing of prototype targets is also described.

Haendler, B.L.; Buckley, S.R.; Chen, C.; Cook, A.R.; Cook, R.C.; Hair, L.M.; Kong, F.M.; Kramer, H.D.; Letts, S.A.; Overturf, G.E. III

1988-06-01T23:59:59.000Z

450

Evaluation of open pit incineration for the disposal of hydrocarbon wastes  

E-Print Network [OSTI]

of hydrocarbon wastes using an open pit air curtain destructor (ACD) type incinerator was investigated. A prototype experi- mental incinerator was designed and constructed, and experiments were performed with it to determine the relationships among various... design and operational parameters (such as incinerator configuration, fuel flow- rate, and smoke emissions) and to further improve the design. The investigation was conducted in three phases. First air flow studies were performed using a full scale...

Bell, Stuart Ray

1981-01-01T23:59:59.000Z

451

Ancestral Nesson anticline and associated geothermal anomalies: Enhanced hydrocarbon generation controlled by crustal structure  

SciTech Connect (OSTI)

Hydrocarbon generation in the Williston basin is influenced by crustal motions and geothermal gradient anomalies associated with the ancestral Nesson anticline, a long-lived crustal structure located along 103{degree} longitude. This structure and its effects are particularly important in Canada where most petroleum source rocks were not sufficiently buried to have generated hydrocarbons in a normal geothermal gradient environment. High geothermal gradients associated with this structure raise the oil window and expand the region of source rock thermal maturity. Ancestral Nesson structure subsided differentially throughout the Phanerozoic, controlling paleobathymetry and facies over its crest. During the Upper Ordovician the structure was positive; rich potential petroleum source rocks were deposited on the western flank of the structure, generally excluding them from the zone of elevated heat flows. The total petroleum potential of this oil-source system exceeds 5.5 billion bbl of oil equivalent in Canada alone. Unfortunately, its exclusion from the maturation anomaly results in no more than 200 million bbl of oil being expelled from these sources. During the Middle Devonian, the structure was a negative feature that formed a starved subbasin separating the Winnipegosis and Elm Point carbonate shelves. Rich potential petroleum source rocks that accumulated on the crest of the structure at that time now overlie the region of elevated heat that flows and enhanced hydrocarbon maturation. Two billion barrels of oil are estimated to have been expelled from this source rock. Understanding the history and tectonics of the ancestral Nesson anticline is fundamental to a correct appraisal of hydrocarbon resources in the Williston basin.

Osadetz, K.G.; Snowdon, L.R. (Geological Survey of Canada, Calgary, Alberta (Canada))

1989-09-01T23:59:59.000Z

452

Quantification of in situ polycyclic aromatic hydrocarbon biodegradation at a petroleum contaminated site  

E-Print Network [OSTI]

contaminated area located in the Port Arthur Refinery of Fina Oil and Chemical Company (FINA). The soil within these area had been chronically contaminated with Bunker C fuel oil spills. As this contamination was considered a potential threat... formed as products of combustion (Gibson, 1977). Their hydrophobic properties and low water solubility make them adsorb to sediments and migrate with them through rivers, lakes and oceans (Cerniglia and Heitkamp, 1989). Polycyclic aromatic hydrocarbons...

Conti, Enzo Mario

1994-01-01T23:59:59.000Z

453

Natural gas conversion to higher hydrocarbons using plasma interactions with surfaces. Final report  

SciTech Connect (OSTI)

Experiments are reported in which a methane plasma is created, and the methyl ions and hydrogen ions are accelerated within a microchannel array so that they interact with neutral methane molecules on the inside surfaces of the microchannels. No catalysts are used, and the device operates at room temperature. Impact energies of the ions are in the range of 10 eV to greater than 100 eV, and the energy delivered in the interaction at the surfaces causes the production of larger hydrocarbon molecules, such as C{sub 2}H{sub 2}, C{sub 2}H{sub 4}, and C{sub 2}H{sub 6}, along with C{sub 3}, C{sub 4}, C{sub 5}m C{sub 6}, C{sub 7}m and C{sub 8} molecules. There is a decreasing percentage of larger molecules produced, in comparison with the C{sub 2} and C{sub 3} types. Conversion effectiveness is greater at higher pressure, due to the increased ionic activity. The yield of the higher hydrocarbons depends upon the external voltage used, and voltage can be used as a control parameter to adjust the output mixture proportions. A conversion energy of 2.59 kilowatt hours/killogram of output has been demonstrated, and a reduction of this by a factor of 10 is possible using known techniques. In batch experiments, the selectivity for C{sub 2} has varied from 47% to 88%, and selectivity for C{sub 6} has ranged from 0% to 12.8%. Other hydrocarbon selectivities also span a wide and useful range. The estimated costs for hydrocarbons produced with this technology are in the range of $200 per tonne, in production quantities, depending upon natural gas costs. Pilot production experiments are recommended to make these estimates more precise, and to address strategies for scaling the technology up to production levels. Applications are discussed.

Sackinger, W.M.; Kamath, V.A.; Morgan, B.L.; Airey, R.W.

1993-12-01T23:59:59.000Z

454

Solution mining dawsonite from hydrocarbon containing formations with a chelating agent  

DOE Patents [OSTI]

A method for treating an oil shale formation comprising dawsonite includes providing heat from one or more heaters to the formation to heat the formation. Hydrocarbon fluids are produced from the formation. At least some dawsonite in the formation is decomposed with the provided heat. A chelating agent is provided to the formation to dissolve at least some dawsonite decomposition products. The dissolved dawsonite decomposition products are produced from the formation.

Vinegar, Harold J. (Bellaire, TX)

2009-07-07T23:59:59.000Z

455

Experimental and analytical studies of hydrocarbon yields under dry-, steam-, and steam-with-propane distillation  

E-Print Network [OSTI]

EXPERIMENTAL AND ANALYTICAL STUDIES OF HYDROCARBON YIELDS UNDER DRY-, STEAM-, AND STEAM-WITH- PROPANE DISTILLATION A Dissertation by NAMIT JAISWAL Submitted to the Office of Graduate Studies of Texas A&M University...-WITH- PROPANE-DISTILLATION A Dissertation by NAMIT JAISWAL Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree of DOCTOR OF PHILOSOPHY Approved...

Jaiswal, Namit

2007-09-17T23:59:59.000Z

456

Reconnaissance survey for lightweight and carbon tetrachloride extractable hydrocarbons in the central and eastern basins of Lake Erie: September 1978  

SciTech Connect (OSTI)

A reconnaissance survey of the central and eastern basins of Lake Erie (22,240 km/sup 2/) was conducted from September 17 to 27, 1978. The survey provided baseline information on natural gas and oil losses from geologic formations, prior to any potential development of natural gas resources beneath the United States portion of the Lake. Lightweight hydrocarbons indicative of natural gas (methane, ethane, propane, isobutane, and n-butane) are introduced into the waters of Lake Erie by escape from geologic formations and by biological/photochemical processes. The geochemical exploration technique of hydrocarbon sniffing provided enough data to reveal significant distribution patterns, approximate concentrations, and potential sources. Twelve sites with elevated lightweight hydrocarbon concentrations had a composition similar to natural gas. In one area of natural gas input, data analysis suggested a potential negative effect of natural gas on phytoplanktonic metabolism (i.e., ethylene concentration). Samples taken for liquid hydrocarbon analysis (carbon tetrachloride extractable hydrocarbons) correlated best with biologically derived lightweight hydrocarbons.

Zapotosky, J.E.; White, W.S.

1980-10-01T23:59:59.000Z

457

Design and Testing of a Labview- Controlled Catalytic Packed- Bed Reactor System For Production of Hydrocarbon Fuels  

SciTech Connect (OSTI)

Gasified woody biomass (producer gas) was converted over a Mo/H+ZSM-5 catalyst to produce gasolinerange hydrocarbons. The effect of contaminants in the producer gas showed that key retardants in the system included ammonia and oxygen. The production of gasoline-range hydrocarbons derived from producer gas was studied and compared with gasoline-range hydrocarbon production from two control syngas mixes. Certain mole ratios of syngas mixes were introduced into the system to evaluate whether or not the heat created from the exothermic reaction could be properly controlled. Contaminant-free syngas was used to determine hydrocarbon production with similar mole values of the producer gas from the gasifier. Contaminant-free syngas was also used to test an ideal contaminant-free synthesis gas situation to mimic our particular downdraft gasifier. Producer gas was used in this study to determine the feasibility of using producer gas to create gasoline-range hydrocarbons on an industrial scale using a specific Mo/H+ZSM-5 catalyst. It was determined that after removing the ammonia, other contaminants poisoned the catalyst and retarded the hydrocarbon production process as well.

Street, J.; Yu, F.; Warnock, J.; Wooten, J.; Columbus, E.; White, M. G.

2012-05-01T23:59:59.000Z

458

Membrane-Extraction Ion Mobility Spectrometry for In-Situ Detection of Chlorinated Hydrocarbons in Water  

SciTech Connect (OSTI)

Membrane-extraction ion mobility spectrometry (ME-IMS) has been developed for in-situ sampling and analysis of trace chlorinated hydrocarbons in water in a single procedure. The sampling is configured so that aqueous contaminants permeate through a spiral hollow polydimethylsiloxane (PDMS) membrane and are carried away by a vapor flow through the membrane tube. The extracted analyte flows into an atmospheric pressure chemical ionization (APCI) chamber and is analyzed in a home-made IMS analyzer. PDMS membrane is found to effectively extract chlorinated hydrocarbon solvents from liquid phase to vapor. The specialized IMS analyzer has been found to have resolutions of R=33 and 41, respectively, for negative- and positive-modes and is capable of detecting aqueous tetrachloroethylene (PCE) and trichloroethylene (TCE) as low as 80 g/L and 74 g/L in negative ion mode, respectively. The time-dependent characteristics of sampling and detection of TCE are both experimentally and theoretically studied for various concentrations, membrane lengths, and flow rates. These characteristics demonstrate that membrane-extraction IMS is feasible for the continuous monitoring of chlorinated hydrocarbons in water.

Du, Yongzhai [ORNL; Zhang, Wei [ORNL; Whitten, William B [ORNL; Li, Haiyang [ORNL; Watson, David B [ORNL; Xu, Jun [ORNL

2010-01-01T23:59:59.000Z

459

Computer integrated manufacturing/processing in the HPI. [Hydrocarbon Processing Industry  

SciTech Connect (OSTI)

Hydrocarbon Processing and Systemhouse Inc., developed a comprehensive survey on the status of computer integrated manufacturing/processing (CIM/CIP) targeted specifically to the unique requirements of the hydrocarbon processing industry. These types of surveys and other benchmarking techniques can be invaluable in assisting companies to maximize business benefits from technology investments. The survey was organized into 5 major areas: CIM/CIP planning, management perspective, functional applications, integration and technology infrastructure and trends. The CIM/CIP planning area dealt with the use and type of planning methods to plan, justify implement information technology projects. The management perspective section addressed management priorities, expenditure levels and implementation barriers. The functional application area covered virtually all functional areas of organization and focused on the specific solutions and benefits in each of the functional areas. The integration section addressed the needs and integration status of the organization's functional areas. Finally, the technology infrastructure and trends section dealt with specific technologies in use as well as trends over the next three years. In February 1993, summary areas from preliminary results were presented at the 2nd International Conference on Productivity and Quality in the Hydrocarbon Processing Industry.

Yoshimura, J.S. (Systemhouse Inc., Houston, TX (United States))

1993-05-01T23:59:59.000Z

460

Experimental and modeling investigation of aromatic and polycyclic aromatic hydrocarbon formation in a premixed ethylene flame  

SciTech Connect (OSTI)

Experimental and detailed chemical kinetic modeling has been performed to investigate aromatic and polyaromatic hydrocarbon formation pathways in a rich, sooting, ethylene-oxygen-argon premixed flame. An atmospheric pressure, laminar flat flame operated at an equivalence ratio of 2.5 was used to acquire experimental data for model validation. Gas composition analysis was conducted by an on-line gas chromatograph/mass spectrometer (GC/MS) technique. Measurements were made in the flame and post-flame zone for a number of low molecular weight species, aliphatics, aromatics and polycyclic aromatic hydrocarbons (PAHs) ranging from two to five-aromatic fused rings. The modeling results show the key reaction sequences leading to aromatic and polycyclic aromatic hydrocarbon growth involve the combination of resonantly stabilized radicals. In particular, propargyl and 1-methylallenyl combination reactions lead to benzene and methyl substituted benzene formation, while polycyclic aromatics are formed from cyclopentadienyl radicals and fused rings that have a shared C{sub 5} side structure. Naphthalene production through the reaction step of cyclopentadienyl self-combination and phenanthrene formation from indenyl and cyclopentadienyl combination were shown to be important in the flame modeling study. The removal of phenyl by O{sub 2} leading to cyclopentadienyl formation is expected to play a pivotal role in the PAH or soot precursor growth process under fuel-rich oxidation conditions.

Castaldi, M.J.; Marinov, N.M.; Melius, C.F. [and others

1996-02-01T23:59:59.000Z

Note: This page contains sample records for the topic "non-methane hydrocarbons nmhc" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Role of minerals in formation of hydrocarbons during pyrolysis of organic matter - a material balance approach  

SciTech Connect (OSTI)

Monterey Formation and Green River Formation kerogens (types II and I, respectively) were isolated, mixed with common sedimentary minerals, and pyrolyzed under dry and hydrous conditions for various times and temperatures. Analysis of all the pyrolyses products were conducted to perform a material balance and to infer reaction kinetics and mechanisms. Material balance of the pyrolyses products, in the presence and absence of minerals, reveals that the kerogen degradation results in the formation of bitumen rich in high molecular weight compounds in the initial stages, followed by additional cracking of kerogen and bitumen. However, amount and type of hydrocarbons in the pyrolyses products of kerogen in the presence of montmorillonite are markedly different from those produced by heating kerogen alone or with other minerals. The initial amounts of products in the presence of montmorillonite, and in particular the quantities of low molecular weight hydrocarbons, are higher than those in the presence of illite, calcite, and kerogen alone. The composition of these low molecular weight compounds is dominated by branched hydrocarbons, indicating catalytic cracking via carbonium ion mechanism, which is initiated on acidic sites of the clay. Composition differences are evident also in the distribution of n-alkanes and in the pristane/phytane ratio. The catalytic effect of montmorillonite, however, disappears in the presence of excess water. These differences may have important implications for the composition and quantities of petroleum generated from source rocks with different mineralogies.

Tannenbaum, E.; Huizinga, B.J.; Kaplan, I.R.

1985-02-01T23:59:59.000Z

462

Liquid-liquid equilibria of fuel oxygenate + water + hydrocarbon mixtures. 3: Effect of temperature  

SciTech Connect (OSTI)

The authors have measured the ternary liquid-liquid equilibria of water + ethanol mixtures with, separately, 2,2,4-trimethylpentane and toluene at 5 and 40 C, water + tert-amyl alcohol (TAOH) mixtures with, separately, toluene and hexane at 5 and 40 C, and of water + TAOH + pentane mixtures at 5 C. The ethanol-containing systems exhibit type 1 liquid-liquid phase behavior, and the TAOH-containing systems exhibit type 2 behavior. These data, together with the data they have previously reported at 25 C, provide information on how the liquid-liquid equilibria of these systems change as a function of temperature. While the addition of ethanol is found to increase the solubility of hydrocarbons in the aqueous phase, the concentration of the hydrocarbon in the water-rich phase decreases with increasing temperature. With the exception of hydrocarbon in the water-rich phase, the experimental data could be correlated quite well with either the UNIQUAC or NRTL models. For most of the systems considered here the predictions of the phase behavior with the liquid-liquid UNIFAC group-contribution model are only qualitatively correct. However, the liquid-liquid UNIFAC model erroneously predicts type 2 phase behavior to occur for water + ethanol + 2,2,4-trimethylpentane system at 5 C.

Wagner, G. [Universitaet Karlsruhe (Germany). Institut fuer Thermische Verfahrenstechnik; Sandler, S.I. [Univ. of Delaware, Newark, DE (United States). Center for Molecular and Engineering Thermodynamics

1995-09-01T23:59:59.000Z

463

Gas-liquid-liquid equilibria in mixtures of water, light gases, and hydrocarbons  

SciTech Connect (OSTI)

Phase equilibrium in mixtures of water + light gases and water + heavy hydrocarbons has been investigated with the development of new local composition theory, new equations of state, and new experimental data. The preferential segregation and orientation of molecules due to different energies of molecular interaction has been simulated with square well molecules. Extensive simulation has been made for pure square well fluids and mixtures to find the local composition at wide ranges of states. A theory of local composition has been developed and an equation of state has been obtained for square well fluids. The new local composition theory has been embedded in several equations of state. The pressure of water is decoupled into a polar pressure and non-polar pressure according to the molecular model of water of Jorgensen et al. The polar pressure of water is combined with the BACK equation for the general description of polar fluids and their mixtures. Being derived from the steam table, the Augmented BACK equation is particularly suited for mixtures of water + non-polar substances such as the hydrocarbons. The hydrophobic character of the hydrocarbons had made their mixtures with water a special challenge. A new group contribution equation of state is developed to describe phase equilibrium and volumetric behavior of fluids while requiring only to know the molecular structure of the components. 15 refs., 1 fig.

Chao, K.C.

1990-01-01T23:59:59.000Z

464

Comparisons of hydrocarbon and nitrogen distributions in geologically diverse tar sand bitumen  

SciTech Connect (OSTI)

The characteristics of bitumens from different tar sand deposits are generally significantly different and affect the utilization of the resource. The chemical and physical properties of bitumen are a result of maturation reactions on the varied organic sediments. For example, saturated hydrocarbon distributions have been related to the geochemical history of organic matter. Very paraffinic or sometimes paraffinic-naphthenic distributions in organic matter are derived from a nonmarine depositional environment. More aromatic and paraffinic-naphthenic hydrocarbon distributions are derived from organic matter deposited in a marine environment. The characteristics of the bitumen also influence the potential for recovery and subsequent processing of the material. For example, saturated hydrocarbons contribute to the high pour points of recovered oils. The origin and composition of an oil influence its viscosity, API gravity, and coke formation during processing, particularly under low-temperature oxidation conditions. The objective of this work is to determine the chemical and physical properties of several samples of bitumen from geologically diverse tar sand deposits. The compound-type distributions and LTD properties of these bitumens are discussed relative to the depositional environment and processing potential of the organic matter.

Holmes, S.A.

1988-06-01T23:59:59.000Z

465

Parameters controlling hydrocarbon distribution at Tatums Camp Field, Lamar County, Mississippi  

SciTech Connect (OSTI)

Structural setting, stratigraphy, diagenesis, and hydraulic pathways all have played an important role in the development of reservoir at Tatums Camp field in Lamar County, Mississippi. The field is a domal anticline located on the southern flank of Midway Salt Dome within the confines of the Mississippi Salt basin. Production is from the Booth Sandstone of the Lower Cretaceous Hosston Formation. The Booth Sandstone contains productive mouth bar sands that pinch out across the northeast half of the dome, and nonproductive channel sands on the west. The mouth bars appear to have been deposited in a marginal marine, perhaps, estuarine environment. Porosity is secondary in origin, the result of leaching of framework constituents. Diagenetic studies indicate that hydrocarbons migrated into the sands when they were at or close to their present depth of 15,700 15,800 ft (4,785-4,815 m). Hydraulic head estimates within the upper Hosston Formation decrease from north to south. This pattern suggests that fluid movement is to the south away from Midway Salt Dome. It is probable that these hydraulic pathways were established at the time of hydrocarbon migration. The reservoir at Tatums Camp field appears to be the result of hydrocarbon migration from the north into a stratigraphic pinchout lying across a structurally positive feature.

Jackson, P. (Stephen F. Austin State Univ., Nacogdoches, TX (USA))

1990-09-01T23:59:59.000Z

466

Catalytic multi-stage process for hydroconversion and refining hydrocarbon feeds  

DOE Patents [OSTI]

A multi-stage catalytic hydrogenation and hydroconversion process for heavy hydrocarbon feed materials such as coal, heavy petroleum fractions, and plastic waste materials. In the process, the feedstock is reacted in a first-stage, back-mixed catalytic reactor with a highly dispersed iron-based catalyst having a powder, gel or liquid form. The reactor effluent is pressure-reduced, vapors and light distillate fractions are removed overhead, and the heavier liquid fraction is fed to a second stage back-mixed catalytic reactor. The first and second stage catalytic reactors are operated at 700-850.degree. F. temperature, 1000-3500 psig hydrogen partial pressure and 20-80 lb./hr per ft.sup.3 reactor space velocity. The vapor and light distillates liquid fractions removed from both the first and second stage reactor effluent streams are combined and passed to an in-line, fixed-bed catalytic hydrotreater for heteroatom removal and for producing high quality naphtha and mid-distillate or a full-range distillate product. The remaining separator bottoms liquid fractions are distilled at successive atmospheric and vacuum pressures, low and intermediate-boiling hydrocarbon liquid products are withdrawn, and heavier distillate fractions are recycled and further upgraded to provide additional low-boiling hydrocarbon liquid products. This catalytic multistage hydrogenation process provides improved flexibility for hydroprocessing the various carbonaceous feedstocks and adjusting to desired product structures and for improved economy of operations.

Comolli, Alfred G. (Yardley, PA); Lee, Lap-Keung (Cranbury, NJ)

2001-01-01T23:59:59.000Z

467

Childhood nervous system tumors--an evaluation of the association with paternal occupational exposure to hydrocarbons  

SciTech Connect (OSTI)

Paternal occupational exposures to hydrocarbons have been associated with childhood nervous system cancer, but study results have not been consistent. This population-based case-control study was designed to examine this association using a large sample size to increase the precision of risk estimates. The birth certificates of 499 children who died in Texas from intracranial and spinal cord tumors were compared with 998 control certificates randomly selected from all Texas live births. Information on parental job title and industry at the time of birth was obtained from the birth certificates. No significant associations were identified for the dichotomized variable of all hydrocarbon-related occupations combined, as variously defined in previous studies, or for most of the specific jobs affiliated with exposures to hydrocarbons. Significant, relatively stable odds ratios (OR) were found for printers and graphics arts workers (OR = 4.5; 95% confidence interval (CI) = 1.4-14.7) and chemical and petroleum workers with high exposure levels (OR = 3.0; CI = 1.1-8.5). A discussion of the biases involved in this type of study design is presented.

Johnson, C.C.; Annegers, J.F.; Frankowski, R.F.; Spitz, M.R.; Buffler, P.A.

1987-10-01T23:59:59.000Z

468

Modeling of structure H hydrate equilibria for methane, intermediate hydrocarbon molecules and water systems  

SciTech Connect (OSTI)

Clathrate hydrates are inclusion compounds in which guest molecules are engaged by water molecules under favorable conditions of pressure and temperature. The well known structures 1 and 2 have been discovered since last century, while a new structure called H has been recently described in the literature. Since that time, structure H hydrate equilibrium data involving methane and different intermediate liquid hydrocarbon molecules have been published. The equilibrium calculations involving hydrates are based on the fact that the chemical potential of water in the aqueous liquid phase is equal to the one in the hydrate phase. The chemical potential of water in the liquid aqueous phase can be easily described by classical thermodynamic relations, while the chemical potential of water in the hydrates phase is described by the expressions proposed by Van der Walls and Platteeuw derived from an adsorption model based on statistical thermodynamics. The authors present in this paper a set of Kihara potential parameters which enable the calculation of Langmuir constants which characterize the adsorption of some naphthenic and iso-paraffinic intermediate hydrocarbons in the larger cage of structure H hydrates. This work thus allows the computation of structural H hydrate equilibrium conditions for systems made of methane, intermediate hydrocarbon molecules and water.

Thomas, M.; Behar, E. [Inst. Francais du Petrole, Rueil-Malmaison (France)

1996-12-31T23:59:59.000Z

469

BIOTIGER, A NATURAL MICROBIAL PRODUCT FOR ENHANCED HYDROCARBON RECOVERY FROM OIL SANDS.  

SciTech Connect (OSTI)

BioTiger{trademark} is a unique microbial consortia that resulted from over 8 years of extensive microbiology screening and characterization of samples collected from a century-old Polish waste lagoon. BioTiger{trademark} shows rapid and complete degradation of aliphatic and aromatic hydrocarbons, produces novel surfactants, is tolerant of both chemical and metal toxicity and shows good activity at temperature and pH extremes. Although originally developed and used by the U.S. Department of Energy for bioremediation of oil-contaminated soils, recent efforts have proven that BioTiger{trademark} can also be used to increase hydrocarbon recovery from oil sands. This enhanced ex situ oil recovery process utilizes BioTiger{trademark} to optimize bitumen separation. A floatation test protocol with oil sands from Ft. McMurray, Canada was used for the BioTiger{trademark} evaluation. A comparison of hot water extraction/floatation test of the oil sands performed with BioTiger{trademark} demonstrated a 50% improvement in separation as measured by gravimetric analysis in 4 h and a five-fold increase at 25 hr. Since BioTiger{trademark} performs well at high temperatures and process engineering can enhance and sustain metabolic activity, it can be applied to enhance recovery of hydrocarbons from oil sands or other complex recalcitrant matrices.

Brigmon, R; Topher Berry, T; Whitney Jones, W; Charles Milliken, C

2008-05-27T23:59:59.000Z

470

BIODEGRADATION OF MACONDO OIL BY AEROBIC HYDROCARBON?DEGRADING BACTERIA IN THE WATER COLUMN AND DEEPSEA SEDIMENTS OF THE NORTHERN GULF OF MEXICO.  

E-Print Network [OSTI]

??Previous studies have come to contrasting conclusions regarding nutrient limitation of hydrocarbon biodegradation in the Gulf of Mexico, and rate measurements are needed to support (more)

Sun, Xiaoxu

2014-01-01T23:59:59.000Z

471

Onshore and offshore basins of northeast Libya: Their origin and hydrocarbon potential  

SciTech Connect (OSTI)

A comprehensive data base of more than 3000 km of seismic lines, gravity and magnetic data, more than 30 subsurface well logs, and surface geology data were utilized to examine and interpret the sedimentary and tectonic history of the onshore and offshore parts of Northeast Libya and their hydrocarbon potential. The Dernah-Tobruk and Benghazi offshore basins form the northern parts of the study area. The Cyrenaica Stable Platform represents the southern parts. The Sirual Trough stretches E-W and opens into the Antelat Trough in the west. Between these elements is the uplifted areas of the Al Jabal Al Akhdar. Six principal tectonic phases were responsible for the formation and development of these structural elements: the pre-Mesozoic phase, the Triassic-Jurassic rifting phase, the Neocomian and the Aptian-Albian renewed rifting phases, the Late Cretaceous-Paleocene uplifting phase; and the Eocene-Middle Oligocene rifting phase. Oceanic crust of probable Aptian-Albian age is evident on the seismic lines north of the master fault marking the southern boundary of the rift separating the north African plate and Apulia. The western boundary of the Dernah High displayed clearly NE-SW strike-slip movement of these trajectories. Oceanic crust is also present west of the Dernah High. Positive gravity and magnetic anomalies traverse parallel to the boundary of this oceanic plate Mesogea. The prerequisites for commercial hydrocarbon production are present in abundance. Reservoirs ranging in age from Paleozoic clastics in the Cyrenaica Stable Platform to Mesozoic and Tertiary carbonates throughout the rest of the region. Several deep sites for the generation of hydrocarbons were also present, including the rifted northern parts of the Dernah-Tobruk basin, the Antelat Trough and the Cyrenaica Passive Margin. The Cretaceous and Tertiary section in the study area contain several potential seal rocks. Several potential trap types are also present.

Shegewi, O.M.

1992-01-01T23:59:59.000Z

472

Distribution of high molecular weight hydrocarbons in northern Gulf of Mexico continental slope sediments  

E-Print Network [OSTI]

odd- carbon preference in the n-C23 to n-C33 region. Marine inputs are often distinguishable by the presence of odd-chain normal alkanes with 15, 17, and 19 carbon 8'toms . 3- In petroleum, pristane and phytane are present at similar... in the upper 15 cm of marine sand ranged from 0. 2 to 19. 9 pg/g. No strong evidence for oil pollution was found in the study area. However, one sample with a relatively high hydrocarbon/organic carbon ratio may have been contaminated with petroleum...

Sericano, Jose Luis

1986-01-01T23:59:59.000Z

473

Fast-quench reactor for hydrogen and elemental carbon production from natural gas and other hydrocarbons  

DOE Patents [OSTI]

A fast-quench reactor for production of diatomic hydrogen and unsaturated carbons is provided. During the fast quench in the downstream diverging section of the nozzle, such as in a free expansion chamber, the unsaturated hydrocarbons are further decomposed by reheating the reactor gases. More diatomic hydrogen is produced, along with elemental carbon. Other gas may be added at different stages in the process to form a desired end product and prevent back reactions. The product is a substantially clean-burning hydrogen fuel that leaves no greenhouse gas emissions, and elemental carbon that may be used in powder form as a commodity for several processes.

Detering, Brent A.; Kong, Peter C.

2006-08-29T23:59:59.000Z

474

Isomerization of hydrocarbons in the presence of zeolite-containing catalysts  

SciTech Connect (OSTI)

Y-type zeolites with 97% of the sodium removed and after aluminium removal (modulus close to 8) and without precious metal activation - are active and fairly selective catalysts for the isomerization of paraffinic and naphthenic hydrocarbons at 200/sup 0/-280/sup 0/C. The isomerization activity of HY and HM zeolites correlates with the concentration of strong acid sites; the isomerization of paraffins requires stronger centres sites than are needed for the isomerization of naphthenes. HY Catalysts may be used for increasing the octane number of refined oils in catalytic reforming.

Zhorov, Yu.M.; Kartashev, Yu.N.; Panchenkov, G.M.

1983-01-01T23:59:59.000Z

475

Radionuclides, Metals, and Hydrocarbons in Oil and Gas Operational Discharges and Environmental Samples Associated with Offshore Production Facilities on the Texas/Louisiana Continental Shelf with an Environmental Assessment of Metals and Hydrocarbons  

SciTech Connect (OSTI)

This report presents concentrations of radionuclides, metals, and hydrocarbons in samples of produced water and produced sand from oil and gas production platforms located offshore Texas and Louisiana. Concentrations in produced water discharge plume/receiving water, ambient seawater, sediment, interstitial water, and marine animal tissue samples collected in the vicinity of discharging platforms and reference sites distant from discharges are also reported and discussed. An environmental risk assessment is made on the basis of the concentrations of metals and hydrocarbons determined in the samples.

Continental Shelf Associates, Inc.

1999-08-16T23:59:59.000Z

476

Radionuclides, Metals, and Hydrocarbons in Oil and Gas Operational Discharges and Environmental Samples Associated with Offshore Production Facilities on the Texas/Louisiana Continental Shelf with an Environmental Assessment of Metals and Hydrocarbons.  

SciTech Connect (OSTI)

This report presents concentrations of radionuclides, metals, and hydrocarbons in samples of produced water and produced sand from oil and gas production platforms located offshore Texas and Louisiana. concentrations in produced water discharge plume / receiving water, ambient seawater, sediment, interstitial water, and marine animal tissue samples collected in the vicinity of discharging platforms and reference sites distant from discharges are also reported and discussed. An environmental risk assessment is made on the basis of the concentration of metals and hydrocarbons determined in the samples.

NONE

1997-06-01T23:59:59.000Z

477

Development of a Raman spectroscopy technique to detect alternate transportation fuel hydrocarbon intermediates in complex combustion environments.  

SciTech Connect (OSTI)

Spontaneous Raman spectra for important hydrocarbon fuels and combustion intermediates were recorded over a range of low-to-moderate flame temperatures using the multiscalar measurement facility located at Sandia/CA. Recorded spectra were extrapolated to higher flame temperatures and then converted into empirical spectral libraries that can readily be incorporated into existing post-processing analysis models that account for crosstalk from overlapping hydrocarbon channel signal. Performance testing of the developed libraries and reduction methods was conducted through an examination of results from well-characterized laminar reference flames, and was found to provide good agreement. The diagnostic development allows for temporally and spatially resolved flame measurements of speciated hydrocarbon concentrations whose parent is more chemically complex than methane. Such data are needed to validate increasingly complex flame simulations.

Ekoto, Isaac W.; Barlow, Robert S.

2012-12-01T23:59:59.000Z

478

Topical viscosity control for light hydrocarbon displacing fluids in petroleum recovery and in fracturing fluids for well stimulation  

DOE Patents [OSTI]

Solvent-type flooding fluids comprising light hydrocarbons in the range of ethane to hexane (and mixtures thereof) are used to displace crude oil in formations having temperatures of about 20 degrees to about 150 degrees Centigrade and pressures above about 650 psi, the light hydrocarbons having dissolved therein from about 0.05% to about 3% of an organotin compound of the formula R.sub.3 SnF where each R is independently an alkyl, aryl or alkyaryl group from 3 to 12 carbon atoms. Under the pressures and temperatures described, the organotin compounds become pentacoordinated and linked through the electronegative bridges, forming polymers within the light hydrocarbon flooding media to render them highly viscous. Under ambient conditions, the viscosity control agents will not readily be produced from the formation with either crude oil or water, since they are insoluble in the former and only sparingly soluble in the latter.

Heller, John P. (Socorro, NM); Dandge, Dileep K. (Socorro, NM)

1986-01-01T23:59:59.000Z

479

Chlorinated Hydrocarbons  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation Proposed New Substation SitesStandingtheirCheck InChemistry OxideChenChevron,|X Iby Satish C.

480

Requirements Hydrocarbon  

E-Print Network [OSTI]

. He considered two coolants: Butane and R134a (freon replacement used in auto air conditioners). About

Cinabro, David

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481

Transport Modeling of Membrane Extraction of Chlorinated Hydrocarbon from Water for Ion Mobility Spectrometry  

SciTech Connect (OSTI)

Membrane-extraction Ion Mobility Spectrometry (ME-IMS) is a feasible technique for the continuous monitoring of chlorinated hydrocarbons in water. This work studies theoretically the time-dependent characteristics of sampling and detection of trichloroethylene (TCE). The sampling is configured so that aqueous contaminants permeate through a hollow polydimethylsiloxane (PDMS) membrane and are carried away by a transport gas flowing through the membrane tube into IMS analyzer. The theoretical study is based on a two-dimensional transient fluid flow and mass transport model. The model describes the TCE mixing in the water, permeation through the membrane layer, and convective diffusion in the air flow inside membrane tube. The effect of various transport gas flow rates on temporal profiles of IMS signal intensity is investigated. The results show that fast time response and high transport yield can be achieved for ME-IMS by controlling the flow rate in the extraction membrane tube. These modeled time-response profiles are important for determining duty cycles of field-deployable sensors for monitoring chlorinated hydrocarbons in water.

Zhang, Wei [ORNL; Du, Yongzhai [ORNL; Feng, Zhili [ORNL; Xu, Jun [ORNL

2010-01-01T23:59:59.000Z

482

Geology and hydrocarbon potential of the Hamada and Murzuq basins in western Libya  

SciTech Connect (OSTI)

The Hamada and Murzuq intracratonic basins of western Libya form a continuation of the Saharan basin which stretches from Algeria eastward into Tunisia and Libya. The tectonics and sedimentology of this region have been greatly influenced by the Caledonian and Hercynian orogenies. Northwest- and northeast-trending faults are characteristic of the broad, shallow basins. The Cambrian-Ordovician sediments are fluvial to shallow marine. The Silurian constitutes a complete sedimentary cycle, ranging from deep marine shales to shallow marine and deltaic sediments. The Devonian occupies a unique position between two major orogenies. The Mesozoic strata are relatively thin. The Triassic consists of well-developed continental sands, whereas the Jurassic and Cretaceous sediments are mainly lagoonal dolomites, evaporites, and shales. Silurian shales are the primary source rock in the area. The quality of the source rock appears to be better in the deeper part of the basin than on its periphery. The Paleozoic has the best hydrocarbon potential. Hydrocarbons have also been encountered in the Triassic and Carboniferous. In the Hamada basin, the best-known field is the El Hamra, with reserves estimated at 155 million bbl from the Devonian. Significant accumulations of oil have been found in the Silurian. Tlacsin and Tigi are two fields with Silurian production. In the Murzuq basin the Cambrian-Ordovician has the best production capability. However, substantial reserves need to be established before developing any field in this basin. Large areas still remain unexplored in western Libya.

Kirmani, K.U.; Elhaj, F.

1988-08-01T23:59:59.000Z

483

Hydrotreating the bitumen-derived hydrocarbon liquid produced in a fluidized-bed pyrolysis reactor  

SciTech Connect (OSTI)

The pyrolysis of bitumen-impregnated sandstone produces three primary product streams: C{sub 1}-C{sub 4} hydrocarbons gases, a C{sub 5}{sup +} total liquid product, and a carbonaceous residue on the spent sand. The bitumen-derived hydrocarbon liquid was significantly upgraded relative to the native bitumen: it had a higher API gravity, lower Conradson carbon residue, asphaltene content, pour point and viscosity and a reduced distillation endpoint relative to the native bitumen. The elemental composition was little different from that of the native bitumen except for the hydrogen content which was lower. The bitumen-derived liquid produced in a 4-inch diameter fluidized-bed reactor from the Whiterocks tar sand deposit has been hydrotreated in a fixed-bed reactor to determine the extent of upgrading as a function of process operating variables. The extent of denitrogenation and desulfurization of the bitumen-derived liquid was used to monitor catalyst activity as a function of process operating variables and to estimate the extent of catalyst deactivation as a function of time on-stream. The apparent kinetics for the nitrogen and sulfur removal reactions were determined. Product distribution and yield data were also obtained.

Longstaff, D.C.; Deo, M.D.; Hanson, F.V.; Oblad, A.G.; Tsai, C.H.

1991-12-31T23:59:59.000Z

484

Production of bitumen-derived hydrocarbon liquids from Utah's tar sands: Final report  

SciTech Connect (OSTI)

In previous work done on Utah's tar sands, it had been shown that the fluidized-bed pyrolysis of the sands to produce a bitumen-derived hydrocarbon liquid was feasible. The research and development work conducted in the small-scale equipment utilized as feed a number of samples from the various tar sand deposits of Utah elsewhere. The results from these studies in yields and quality of products and the operating experience gained strongly suggested that larger scale operation was in order to advance this technology. Accordingly, funding was obtained from the State of Utah through Mineral Leasing Funds administered by the College of Mines and Earth Sciences of the University of Utah to design and build a 4-1/2 inch diameter fluidized-bed pilot plant reactor with the necessary feeding and recovery equipment. This report covers the calibration and testing studies carried out on this equipment. The tests conducted with the Circle Cliffs tar sand ore gave good results. The equipment was found to operate as expected with this lean tar sand (less than 5% bitumen saturation). The hydrocarbon liquid yield with the Circle Cliffs tar sand was found to be greater in the pilot plant than it was in the small unit at comparable conditions. Following this work, the program called for an extensive run to be carried out on tar sands obtained from a large representative tar sand deposit to produce barrel quantities of liquid product. 10 refs., 45 figs., 11 tabs.

Oblad, A.G.; Hanson, F.V.

1988-07-01T23:59:59.000Z

485

Hydrotreating the bitumen-derived hydrocarbon liquid produced in a fluidized-bed pyrolysis reactor  

SciTech Connect (OSTI)

The pyrolysis of bitumen-impregnated sandstone produces three primary product streams: C{sub 1}-C{sub 4} hydrocarbons gases, a C{sub 5}{sup +} total liquid product, and a carbonaceous residue on the spent sand. The bitumen-derived hydrocarbon liquid was significantly upgraded relative to the native bitumen: it had a higher API gravity, lower Conradson carbon residue, asphaltene content, pour point and viscosity and a reduced distillation endpoint relative to the native bitumen. The elemental composition was little different from that of the native bitumen except for the hydrogen content which was lower. The bitumen-derived liquid produced in a 4-inch diameter fluidized-bed reactor from the Whiterocks tar sand deposit has been hydrotreated in a fixed-bed reactor to determine the extent of upgrading as a function of process operating variables. The extent of denitrogenation and desulfurization of the bitumen-derived liquid was used to monitor catalyst activity as a function of process operating variables and to estimate the extent of catalyst deactivation as a function of time on-stream. The apparent kinetics for the nitrogen and sulfur removal reactions were determined. Product distribution and yield data were also obtained.

Longstaff, D.C.; Deo, M.D.; Hanson, F.V.; Oblad, A.G.; Tsai, C.H.

1991-01-01T23:59:59.000Z

486

Integrated process and apparatus for the primary and secondary catalytic steam reforming of hydrocarbons  

SciTech Connect (OSTI)

An apparatus is described for the essentially autothermal, integrated primary and secondary reforming of hydrocarbons comprising: (a) an internally insulated outer reactor shell adapted for the positioning of primary and secondary reforming zones therein; (b) means defining a primary reforming zone within the outer reactor shell and having catalyst-containing reformer tubes positioned therein, the primary reforming zone not requiring an external fuel fired source of heat for the endothermic primary reforming reaction occurring therein; (c) means for introducing a fluid hydrocarbon feed stream and steam to the outer reactor shell for passage through the reformer tubes in the primary reforming zone; (d) means defining a secondary reforming zone within the outer reactor shell comprising a secondary reforming catalyst bed, a catalyst-free reaction space defining a feed end adjacent to the catalyst bed and a discharge end at the opposite side of the secondary reforming catalyst bed to the feed end; and (e) conduit means positioned entirely within the outer reactor shell and extending through the secondary reforming catalyst bed for passing partly reformed product effluent from the primary reforming zone to the catalyst-free reaction space in the secondary reforming zone.

Fuderer, A.

1987-03-17T23:59:59.000Z

487

Hydrocarbons in Soil Gas as Pathfinders in Geothermal Resource Surveys in Indonesia  

SciTech Connect (OSTI)

A surface geochemical technique utilizing normal paraffin (C{sub 7+}) and aromatic (C{sub 8}) hydrocarbons in soil gas has been successfully used as pathfinders in surveys for geothermal resources in Indonesia. The Dieng field was used to test the technique. The result shows the paraffin anomalies to be near and over productive wells. Because productive wells usually lie over upflow zones it reinforces our hypothesis that paraffins define the upflow of geothermal systems. The aromatic hydrocarbon alkylbenzene C{sub 8} was found near and around productive wells in the southeast quadrant of the Dieng field (Sikidang-Merdada area) but they are more spread out and more diffuse than the paraffins. The shape of their anomaly seems to suggest a tendency of spreading into the direction of lower elevations. It is thought that the aromatics, which are much more soluble than their corresponding paraffins, express at the surface as anomalies not only of locations of the upflow but also of the outflow of the geothermal system as well. Therefore the combined paraffin and aromatic anomalies, and topography, may be used as an indicator for the direction of the outflow or the flow of the under ground waters. The scarcity of the aromatics in the northwest quadrant of the Dieng field (Sileri area) is unique. A hypothesis has been proposed which could explain this unique feature.

Pudjianto, R.; Suroto, M.; Higashihara, M.; Fukuda, M.; Ong, Akhadiana and Jan

1995-01-01T23:59:59.000Z

488

Determination of characteristic alterations of the mass transfer process of thermodynamically nonequilibrium hydrocarbon systems  

SciTech Connect (OSTI)

The results of research on hydrocarbon mixture sorption in porous medium showed that adsorbent activity with regard to separate components of a gas mixture changes in partial dependence on pressure. The alteration of vented gas content will take place not only in gas condensate fields, when this effect is conditioned by the losses of condensate in the stratum, but also in gas fields, by methods connected with desorption processes. At the same time, gas composition is the basis for different process calculations, such as separation, gas transport, gas filtration in porous medium, and others. Thus the determination of characteristic alterations of gas mixture composition in thermodynamically nonequilibrium hydrocarbon systems mass transfer process becomes important. The binary (methane + pentane) and tricomponent (methane + butane + pentane) systems composed of individual gases of high purity have been researched. Then with help of mathematical methods of experimental data processing the moment of the more characteristic changes of the mass transfer process was discovered. Processing of experimental data for tricomponent system by statistical differentiation allowed the discovery of a pressure below of which lightening of the vented gas was observed.

Ramazanova, E.E.; Nurmamedova, Z.A. [Azerbaijan State Oil Academy, Baku (Azerbaijan). Geotechnological Research Inst. of Oil, Gas, and Chemistry

1997-06-01T23:59:59.000Z

489

Chronology of trap formation and migration of hydrocarbons in Zagros sector of southwest Iran  

SciTech Connect (OSTI)

Sixty-three orogenically controlled oil and gas fields have been discovered in the Zagros sector of southwest Iran since teh turn of the present century. Most of the fields are giant, multi-reservoir accumulations producing from fractured carbonate pay zones ranging in age from permo-Triassic to Oligo-Miocene. The most prolific oil-producing zones are the Asmari formation (Oligo-Miocene( and the Bangestan Group (Upper Cretaceous). The available geochemical evidence indicates taht the major source of the oil is the underlying Lower Cretaceous (Albian) Kazhdumi Formation. It is argued that, in the main oil-producing area, the Kazhdumi source rock was not buried to the depth required for hydrocarbon generation until the Eocene, and that not significant oil explusion took place until the Miocene. entry of oil into the reservoirs is geologically a recent event; it postdates the late Miocene-Holocene Zagros orogeny that resulted in the formation of the present structural traps. It is suggested that the development of growth structures during the Late Cretaceous and Palogene could have contributed to some hydrocarbon localization prior to the formation of the late Tertiary traps.

Ala, M.A.

1982-10-01T23:59:59.000Z

490

Method of preparing and utilizing a catalyst system for an oxidation process on a gaseous hydrocarbon stream  

DOE Patents [OSTI]

The disclosure relates to a method of utilizing a catalyst system for an oxidation process on a gaseous hydrocarbon stream with a mitigation of carbon accumulation. The system is comprised of a catalytically active phase deposited onto an oxygen conducting phase, with or without supplemental support. The catalytically active phase has a specified crystal structure where at least one catalytically active metal is a cation within the crystal structure and coordinated with oxygen atoms within the crystal structure. The catalyst system employs an optimum coverage ratio for a given set of oxidation conditions, based on a specified hydrocarbon conversion and a carbon deposition limit. Specific embodiments of the catalyst system are disclosed.

Berry, David A; Shekhawat, Dushyant; Smith, Mark; Haynes, Daniel

2013-07-16T23:59:59.000Z

491

Use of Advanced Oxidation and Aerobic Degradation for Remediation of Various Hydrocarbon Contaminates  

SciTech Connect (OSTI)

Western Research Institute in conjunction with Sierra West Consultants, Inc., Tetra Tech, Inc., and the U.S. Department of Energy conducted laboratory and field studies to test different approaches to enhance degradation of hydrocarbons and associated contaminants. WRI in conjunction with Sierra West Consultants, Inc., conducted a laboratory and field study for using ozone to treat a site contaminated with MTBE and other hydrocarbons. Results from this study demonstrate that a TOD test can be used to resolve the O{sub 3} dosage problem by establishing a site-specific benchmark dosage for field ozone applications. The follow-up testing of the laboratory samples provided indications that intrinsic biodegradation could be stimulated by adding oxygen. Laboratory studies also suggests that O3 dosage in the full-scale field implementation could be dialed lower than stoichiometrically designed to eliminate the formation of Cr(VI). WRI conducted a study involving a series of different ISCO oxidant applications to diesel-contaminated soil and determined the effects on enhancing biodegradation to degrade the residual hydrocarbons. Soils treated with permanganate followed by nutrients and with persulfate followed by nutrients resulted in the largest decrease in TPH. The possible intermediates and conditions formed from NOM and TPH oxidation by permanganate and activated persulfate favors microbial TPH degrading activity. A 'passive-oxidation' method using microbial fuel cell (MFC) technology was conducted by WRI in conjunction with Tetra Tech, Inc., to degrade MTBE in groundwater. These experiments have demonstrated that a working MFC (i.e., one generating power) could be established in the laboratory using contaminated site water or buffered media inoculated with site water and spiked with MTBE, benzene, or toluene. Electrochemical methods were studied by WRI with goal of utilizing low voltage and amperage electrical sources for 'geo-oxidation' of organic contaminants. The results from a study with TCE contaminated-clay indicate that electrochemically inducing reductive dechlorination of TCE in a saturated matrix may offer an effective and viable alternative to remediation TCE and other contaminants with potential of being reduced. Another study focused on steel wool oxidation to electrochemically increase population of hydrocarbon-degrading denitrifying bacteria. Significantly larger denitrifying activity was observed in the cathode chamber of a treatment unit setup like an MFC with steel wool as the anode. This enhanced nitrate reduction could be due to direct electron utilization by denitrifying bacteria on the cathode, thereby stimulating microbial denitrification or a combination of electron transfer directly to NO{sub 3}{sup -} and electron transfer to nitrate reducing bacteria, which may serve as a type of bio-catalyst on the cathode for nitrate reduction. Overall, the studies conducted under Task 72 demonstrated different innovative methods to enhance petroleum hydrocarbon degradation and associated contaminants.

Paul Fallgren

2009-03-06T23:59:59.000Z

492

Thermochemistry for Hydrocarbon Intermediates Chemisorbed on Metal Surfaces: CHn-m(CH3)m with n ) 1, 2, 3 and m e n on Pt, Ir,  

E-Print Network [OSTI]

for hydrocarbons on metal surfaces similar to the Benson scheme so useful for gas-phase hydrocarbons. This is used-bond isomerization of olefins, (3) dehydrogenation and dehydro- isomerization to aromatics, (4) isomerization processes. Although molecular orbital and valence bond theories have helped explain the nature of reactivity

Goddard III, William A.

493

THE IN VITRO INFLUENCE OF THE BURROWING POLYCHAETE NEREIS DIVERSICOLOR ON THE FATE OF PETROLEUM HYDROCARBONS IN MARINE SEDIMENTS.  

E-Print Network [OSTI]

HYDROCARBONS IN MARINE SEDIMENTS. F. GILBERT a, L. RIVET b and J-C. BERTRAND a a Centre d'Océanologie de (SF) of Arabian Light crude oil has been studied in PVC cores filled with a coastal marine sediment. The luminophore tracer technique was used to quantify the mixing of sediment by worms. Presence of crude oil

Paris-Sud XI, Université de

494

DO THE INFRARED EMISSION FEATURES NEED ULTRAVIOLET EXCITATION? THE POLYCYCLIC AROMATIC HYDROCARBON MODEL IN UV-POOR REFLECTION NEBULAE  

E-Print Network [OSTI]

'' PAHs in reflection nebulae near stars as cool as Teff 3000 K can result in observable emis- sion at 6DO THE INFRARED EMISSION FEATURES NEED ULTRAVIOLET EXCITATION? THE POLYCYCLIC AROMATIC HYDROCARBON MODEL IN UV-POOR REFLECTION NEBULAE Aigen Li and B. T. Draine Department of Astrophysical Sciences

Draine, Bruce T.

495

Mechanisms of hormonal regulation of CAD gene expression and inhibition by Aryl hydrocarbon receptor agonist in human breast cancer cells  

E-Print Network [OSTI]

-mediated pathway. 2,3,7,8-Tetrachlorodibenzo-p-dioxin (TCDD) and other aryl hydrocarbon receptor (AhR) ligands suppress several E2-induced responses in the rodent uterus and mammary tumors and in human breast cancer cells. TCDD inhibited hormone...

Khan, Shaheen Munawar Ali

2007-04-25T23:59:59.000Z

496

Controlled-source electromagnetic modeling of the masking effect of marine gas hydrate on a deeper hydrocarbon reservoir  

E-Print Network [OSTI]

that electric field data were reliable to roughly 5000 m of TX-RX offset for the 1 Hz and 3 Hz cases, and to 6500 m offset for 10 Hz. The gas hydrate/hydrocarbon model was then run with zero-value boundary conditions. The goal was to determine what effect...

Dickins, David

2009-06-02T23:59:59.000Z

497

Geostatistical Inversion for the Lateral Delineation of Thin-Layer Hydrocarbon Reservoirs: A Case Study in San Jorge Basin, Argentina.  

E-Print Network [OSTI]

Study in San Jorge Basin, Argentina. Germán Merletti, and Julio Hlebszevitsch, Repsol-YPF, and Carlos, Argentina, is the Bajo Barreal formation and its equivalents, which to date have supplied more than 90 in La Itala field, San Jorge Basin, Argentina Statistically, hydrocarbon production originates not only

Torres-Verdín, Carlos

498

Envlron. Sci. Technol. 1993, 27, 1885-1891 On-Road Hydrocarbon Remote Sensing in the Denver Area  

E-Print Network [OSTI]

), oxides of nitrogen (NO,), and other toxic air pollutants. These emissions play important roles in all emission control technology. Introduction Automobile emissionsoriginate from fuelrich-burning, misfiring or nonfunctional emission control system can produce high emission rates for carbon monoxide (CO), hydrocarbon (HC

Denver, University of

499

Comparative Study for the Interpretation of Mineral Concentrations, Total Porosity, and TOC in Hydrocarbon-Bearing Shale from Conventional Well  

E-Print Network [OSTI]

, and TOC in Hydrocarbon-Bearing Shale from Conventional Well Logs Haryanto Adiguna, SPE, Anadarko Petroleum, and mineral composition is an integral part of unconventional shale reservoir formation evaluation. Porosity requirement for economically viable flow of gas in very-low permeability shales. Brittle shales are favorable

Torres-Verdín, Carlos

500

3-D multichannel seismic reflection study of variable-flux hydrocarbon seeps, continental slope, northern Gulf of Mexico  

E-Print Network [OSTI]

3D multi-channel seismic (MCS) data augmented with side-scan sonar (Garden Banks site) to characterize hydrocarbon seep activity and develop an understanding of the processes that led to their formation. Side-scan sonar data provided high resolution...

Thomas, Ryan Douglas

2004-11-15T23:59:59.000Z