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Note: This page contains sample records for the topic "non-aqueous phase liquid" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


1

Vibration-induced mobilization of trapped non-aqueous phase liquids in porous media.  

E-Print Network (OSTI)

??Acoustic wave stimulation, such as vibration-induced mobilization, is a promising enhancement approach to remove trapped NAPLs (Non-Aqueous Phase Liquids) usually encountered in multiphase flows through… (more)

Li, Wenqing

2006-01-01T23:59:59.000Z

2

Northeast Site Non-Aqueous Phase Liquids Interim Measures Progress Report-January through March 2003  

Office of Legacy Management (LM)

4-TAC 4-TAC GJO-PIN 13.5.1-1 Pinellas Environmental Restoration Project January through March 2003 Northeast Site Non-Aqueous Phase Liquids Interim Measures Progress Report April 2003 Grand Junction Office U.S. Department of Energy Work Performed Under DOE Contract No. for the U.S. Department of Energy DE-AC13-02GJ79491 Approved for public release; distribution is unlimited. N0060900 GJO-2003-434-TAC GJO-PIN 13.5.1-1 Pinellas Environmental Restoration Project Northeast Site Non-Aqueous Phase Liquids Interim Measures Progress Report January through March 2003 April 2003 Prepared by U.S. Department of Energy Grand Junction Office Grand Junction, Colorado Work Performed Under DOE Contract Number DE-AC13-02GJ79491 Task Order Number ST03-107

3

Northeast Site Non-Aqueous Phase Liquids Interim Measures Progress Report October through December 2002  

Office of Legacy Management (LM)

700 700 GJO-2003-411-TAC GJO-PIN 13.5.1-1 Pinellas Environmental Restoration Project Northeast Site Non-Aqueous Phase Liquids Interim Measures Progress Report October through December 2002 January 2003 Prepared by U.S. Department of Energy Grand Junction Office Grand Junction, Colorado Work Performed Under DOE Contract Number DE-AC13-02GJ79491 Task Order Number ST03-107 Document Number N0057700 Contents DOE/Grand Junction Office Northeast Site NAPL Interim Measures Progress Report January 2003 Page ii Contents Acronyms and Abbreviations ........................................................................................................ iii 1.0 Introduction ............................................................................................................................1

4

Northeast Site Non-Aqueous Phase Liquids Interim Measures Progress...  

Office of Legacy Management (LM)

cis-1,2- DCE (mgkg) Methylene Chloride (mgkg) Toluene (mgkg) TCE (mgkg) Florida Petroleum Range Organics (mgkg) NAPL Remediation Goals 71,000 227,000 15,000 20,400 2,500,000...

5

New methods and materials for solid phase extraction and high performance liquid chromatography  

SciTech Connect

This paper describes methods for solid phase extraction and high performance liquid chromatography (HPLC). The following are described: Effects of Resin Sulfonation on the Retention of Polar Organic Compounds in Solid Phase Extraction; Ion-Chromatographic Separation of Alkali Metals In Non-Aqueous Solvents; Cation-Exchange Chromatography in Non-Aqueous Solvents; and Silicalite As a Stationary Phase For HPLC.

Dumont, P.J.

1996-04-23T23:59:59.000Z

6

Non-Aqueous Battery Systems  

Science Journals Connector (OSTI)

...0 V. Practical non-aqueous batteries have energies extending from 100...electric watches to 20 kWh secondary batteries being developed for vehicle traction...10 years, to a military lithium thermal battery delivering all of its energy in...

1996-01-01T23:59:59.000Z

7

Sliding Luttinger liquid phases  

Science Journals Connector (OSTI)

We study systems of coupled spin-gapped and gapless Luttinger liquids. First, we establish the existence of a sliding Luttinger liquid phase for a system of weakly coupled parallel quantum wires, with and without disorder. It is shown that the coupling can stabilize a Luttinger liquid phase in the presence of disorder. We then extend our analysis to a system of crossed Luttinger liquids and establish the stability of a non-Fermi-liquid state: the crossed sliding Luttinger liquid phase. In this phase the system exhibits a finite-temperature, long-wavelength, isotropic electric conductivity that diverges as a power law in temperature T as T?0. This two-dimensional system has many properties of a true isotropic Luttinger liquid, though at zero temperature it becomes anisotropic. An extension of this model to a three-dimensional stack exhibits a much higher in-plane conductivity than the conductivity in a perpendicular direction.

Ranjan Mukhopadhyay; C. L. Kane; T. C. Lubensky

2001-07-09T23:59:59.000Z

8

Accumulation of a light non-aqueous phase liquid on a flat barrier baffling a descending groundwater flow  

Science Journals Connector (OSTI)

...Riesenkampf's scheme revisited. Water Resour. Res. 47, 11521...the characteristics of ground water movement. Final Report...Dane 1999 Movement and remediation of trichloroethylene...1962-1977 Theory of ground-water movement. Princeton...

2012-01-01T23:59:59.000Z

9

Accumulation of a light non-aqueous phase liquid on a flat barrier baffling a descending groundwater flow  

Science Journals Connector (OSTI)

...which flows past this solid-gas protruding as a static cap...encumbrances with respect to a natural or induced groundwater flow...barriers, in a sense similar to cascades of aerofoils or other barriers...Al-Maamari-et al. 2011) or to rely on natural attenuation (i.e. to leave...

2012-01-01T23:59:59.000Z

10

PHASE CHANGE LIQUIDS  

SciTech Connect

Work is being performed to develop a new shipping system for frozen environmental samples (or other materials) that uses an optimal phase change liquid (PCL) formulation and an insulated shipping container with an on-board digital temperature data logger to provide a history of the temperature profile within the container during shipment. In previous work, several PCL formulations with temperatures of fusion ranging from approximately -14 to -20 C were prepared and evaluated. Both temperature of fusion and heat of fusion of the formulations were measured, and an optimal PCL formulation was selected. The PCL was frozen in plastic bags and tested for its temperature profile in a cooler using a digital temperature data logger. This testing showed that the PCL formulation can maintain freezer temperatures (< -7 to -20 C) for an extended period, such as the time for shipping samples by overnight courier. The results of the experiments described in this report provide significant information for use in developing an integrated freezer system that uses a PCL formulation to maintain freezer temperatures in coolers for shipping environmental samples to the laboratory. Experimental results show the importance of the type of cooler used in the system and that use of an insulating material within the cooler improves the performance of the freezer system. A new optimal PCL formulation for use in the system has been determined. The new formulation has been shown to maintain temperatures at < -7 to -20 C for 47 hours in an insulated cooler system containing soil samples. These results are very promising for developing the new technology.

Susan S. Sorini; John F. Schabron

2006-03-01T23:59:59.000Z

11

Non-aqueous liquid compositions comprising ion exchange polymers  

DOE Patents (OSTI)

Compositions, and methods of making thereof, comprising from about 1% to about 5% of a perfluorinated sulfonic acid ionomer or a hydrocarbon-based ionomer; and from about 95% to about 99% of a solvent, said solvent consisting essentially of a polyol; wherein said composition is substantially free of water and wherein said ionomer is uniformly dispersed in said solvent.

Kim, Yu Seung (Los Alamos, NM); Lee, Kwan-Soo (Blacksburg, VA); Rockward, Tommy Q. T. (Rio Rancho, NM)

2011-07-19T23:59:59.000Z

12

Phenyl boron-based compounds as anion receptors for non-aqueous battery electrolytes  

DOE Patents (OSTI)

Novel fluorinated boronate-based compounds which act as anion receptors in non-aqueous battery electrolytes are provided. When added to non-aqueous battery electrolytes, the fluorinated boronate-based compounds of the invention enhance ionic conductivity and cation transference number of non-aqueous electrolytes. The fluorinated boronate-based anion receptors include different fluorinated alkyl and aryl groups.

Lee, Hung Sui (East Setauket, NY); Yang, Xiao-Qing (Port Jefferson Station, NY); McBreen, James (Bellport, NY); Sun, Xuehui (Middle Island, NY)

2002-01-01T23:59:59.000Z

13

Chiral Discotic Columnar Phases in Liquid Crystals  

E-Print Network (OSTI)

We introduce a model to describe columnar phases of chiral discotic liquid phases in which the normals to disc-like molecules are constrained to lie parallel to columnar axes. The model includes separate chiral interactions favoring, respectively, relative twist of chiral molecules along the axes of the columns and twist of the two-dimensional columnar lattice. It also includes a coupling between the lattice and the orientation of the discotic molecules. We discuss the instability of the aligned hexagonal lattice phase to the formation of a soliton lattice in which molecules twist within their columns without affecting the lattice and to the formation of a moir\\'{e} phase consisting of a periodic array of twist grain boundaries perpendicular to the columns.

Gu Yan; T. C. Lubensky

1996-11-08T23:59:59.000Z

14

Molecular Simulation of Henry's Constant at Vapor-Liquid and Liquid-Liquid Phase Richard J. Sadus  

E-Print Network (OSTI)

coexistence. 1. Introduction Henry's constant is a well-known measure of a solute's solubility in a particularMolecular Simulation of Henry's Constant at Vapor-Liquid and Liquid-Liquid Phase Boundaries Richard to determine Henry's constant from the residual chemical potential at infinite dilution at the vapor-liquid

15

Liquid-Phase Combinatorial Synthesis Technique Could Ease Automation  

Science Journals Connector (OSTI)

A liquid-phase combinatorial synthesis technique developed by researchers at Scripps Research Institute, La Jolla, Calif., could provide advantages over existing solid-phase technology and ease automation of combinatorial techniques.Combinatorial ...

STU BORMAN

1995-07-31T23:59:59.000Z

16

X-ray studies of the phases and phase transitions of liquid crystals  

Science Journals Connector (OSTI)

Recent X-ray diffraction studies of liquid crystals are reviewed. The topics are twist grain-boundary phases, antiferroelectric phases studied using resonant diffraction and smectic phases within gel structures.

Clegg, P.S.

2004-12-22T23:59:59.000Z

17

Transient-Liquid-Phase and Liquid-Film-Assisted Joining ofCeramics  

SciTech Connect

Two joining methods, transient-liquid-phase (TLP) joining and liquid-film-assisted joining (LFAJ), have been used to bond alumina ceramics. Both methods rely on multilayer metallic interlayers designed to form thin liquid films at reduced temperatures. The liquid films either disappear by interdiffusion (TLP) or promote ceramic/metal interface formation and concurrent dewetting of the liquid film (LFAJ). Progress on extending the TLP method to lower temperatures by combining low-melting-point (<450 C) liquids and commercial reactive-metal brazes is described. Recent LFAJ work on joining alumina to niobium using copper films is presented.

Sugar, Joshua D.; McKeown, Joseph T.; Akashi, Takaya; Hong, SungM.; Nakashima, Kunihiko; Glaeser, Andreas M.

2005-02-09T23:59:59.000Z

18

Computer Simulations Indicate Calcium Carbonate Has a Dense Liquid Phase  

NLE Websites -- All DOE Office Websites (Extended Search)

Computer Simulations Computer Simulations Indicate Calcium Carbonate Has a Dense Liquid Phase Computer Simulations Indicate Calcium Carbonate Has a Dense Liquid Phase Berkeley Lab research could help scientists predict how carbon is stored underground August 22, 2013 | Tags: Earth Sciences, Geosciences Dan Krotz 510-486-4019 dakrotz@lbl.gov red2.jpg Artistic rendition of liquid-liquid separation in a supersaturated calcium carbonate solution. New research suggests that a dense liquid phase (shown in red in the background and in full atomistic detail based on computer simulations in the foreground) forms at the onset of calcium carbonate crystallization. (Credit: Berkeley Lab) Computer simulations conducted at the U.S. Department of Energy's Lawrence Berkeley National Laboratory (Berkeley Lab) could help scientists

19

Nonaqueous-Phase Liquid Characterization and Post-Remediation Verification  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Nonaqueous-Phase Liquid Characterization and Post-Remediation Nonaqueous-Phase Liquid Characterization and Post-Remediation Verification Sampling Nonaqueous-Phase Liquid Characterization and Post-Remediation Verification Sampling Proceedings of the Fourth International Conference on Remediation of Chlorinated and Recalcitrant Compounds. May 2004, Monterey, California. Charles Tabor, Randall Juhlin, Paul Darr, Julian Caballero, Joseph Daniel, David Ingle Nonaqueous-Phase Liquid Characterization and Post-Remediation Verification Sampling More Documents & Publications Steam and ET-DSP Combined for DNAPL Remediation: Full-Scale Site Restoration at Young - Rainey STAR Center Project Overview: Successful Field-Scale In Situ Thermal NAPL Remediation Successful Field-Scale In Situ Thermal NAPL Remediation at the Young - Rainey STAR Center

20

Nonaqueous-Phase Liquid Characterization and Post-Remediation Verification  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Nonaqueous-Phase Liquid Characterization and Post-Remediation Nonaqueous-Phase Liquid Characterization and Post-Remediation Verification Sampling Nonaqueous-Phase Liquid Characterization and Post-Remediation Verification Sampling Proceedings of the Fourth International Conference on Remediation of Chlorinated and Recalcitrant Compounds. May 2004, Monterey, California. Charles Tabor, Randall Juhlin, Paul Darr, Julian Caballero, Joseph Daniel, David Ingle Nonaqueous-Phase Liquid Characterization and Post-Remediation Verification Sampling More Documents & Publications Project Overview: Successful Field-Scale In Situ Thermal NAPL Remediation Successful Field-Scale In Situ Thermal NAPL Remediation at the Young - Rainey STAR Center Steam and ET-DSP Combined for DNAPL Remediation: Full-Scale Site Restoration at Young - Rainey STAR Center

Note: This page contains sample records for the topic "non-aqueous phase liquid" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Successive Phase Transitions in Antiferroelectric Liquid Crystal Systems  

E-Print Network (OSTI)

An axial next-nearest-neighbor XY model is studied as a model of chiral liquid crystals which exhibit many ferro-, ferri- and antiferroelectric tilted smectic phases. Depending on the values of interaction parameters, this model exhibits Ising symmetric (i.e., the tilt directions of directors are parallel or anti parallel) phases or XY symmetric phases. Phases with each type-of-symmetry show the character of devil's staircase, which has been observed in experiments.

Masaya Koroishi; Masashi Torikai; Mamoru Yamashita

2005-10-03T23:59:59.000Z

22

Partial-filling micellar electrokinetic chromatography and non-aqueous capillary electrophoresis for the analysis of selected agrochemicals  

Science Journals Connector (OSTI)

Selected agrochemicals (s-triazines and phenoxy acids) have been investigated with partial-filling micellar electrokinetic chromatography (PFMEKC) and non-aqueous capillary electrophoresis (NACE). Because these ...

F. Menzinger; Ph. Schmitt-Kopplin…

2001-09-01T23:59:59.000Z

23

Liquid Phases Used in Packed Gas Chromatographic Columns. Part II. Use of Liquid Phases Which Are Not Polysiloxanes  

Science Journals Connector (OSTI)

......as well as trace water, be removed from the carrier gas by using suitable...in the carrier gas lines. There is...bottles out with nitrogen and seal the filled...liquid phases in gas chromatography...Superoxes show low solubility in the common organic......

Joel A. Yancey

1985-08-01T23:59:59.000Z

24

A Microfluidic System for the Continuous Recycling of Unmodified Homogeneous Palladium Catalysts through Liquid/Liquid Phase Separation  

E-Print Network (OSTI)

A prototype microflow system for the continuous recycling of homogeneous catalysts through liquid/liquid phase separation was developed and its effectiveness demonstrated in a challenging palladium-catalyzed hydroxylation ...

Li, Pengfei

25

Plasmas in Multiphase Media: Bubble Enhanced Discharges in Liquids and Plasma/Liquid Phase Boundaries  

SciTech Connect

In this research project, the interaction of atmospheric pressure plasmas with multi-phase media was computationally investigated. Multi-phase media includes liquids, particles, complex materials and porous surfaces. Although this investigation addressed fundamental plasma transport and chemical processes, the outcomes directly and beneficially affected applications including biotechnology, medicine and environmental remediation (e.g., water purification). During this project, we made advances in our understanding of the interaction of atmospheric pressure plasmas in the form of dielectric barrier discharges and plasma jets with organic materials and liquids. We also made advances in our ability to use computer modeling to represent these complex processes. We determined the method that atmospheric pressure plasmas flow along solid and liquid surfaces, and through endoscopic like tubes, deliver optical and high energy ion activation energy to organic and liquid surfaces, and produce reactivity in thin liquid layers, as might cover a wound. We determined the mechanisms whereby plasmas can deliver activation energy to the inside of liquids by sustaining plasmas in bubbles. These findings are important to the advancement of new technology areas such as plasma medicine

Kushner, Mark Jay [University of Michigan] [University of Michigan

2014-07-10T23:59:59.000Z

26

Phase effects for electrons in liquid water and water vapor  

SciTech Connect

The objective of these studies is to compare transport, energy loss, and other phenomena for electrons in water in the liquid and vapor phases. Understanding the differences and similarities is an interesting physics problem in its own right. It is also important for applying the relatively large body of experimental data available for the vapor to the liquid, which is of greater relevance in radiobiology. This paper presents a summary of results from a series of collaborative studies carried out by the authors at Oak Ridge National Laboratory (ORNL) and the Gesellschaft fuer Strahlen- und Umweltforschung (GSF). 14 figs.

Turner, J.E.; Paretzke, H.G.; Wright, H.A.; Hamm, R.N.; Ritchie, R.H.

1988-01-01T23:59:59.000Z

27

Common non-Fermi liquid phases in quantum impurity physics  

Science Journals Connector (OSTI)

We study correlated quantum impurity models that undergo a local quantum phase transition (QPT) from a strong coupling, Fermi liquid phase to a non-Fermi liquid phase with a globally doubly degenerate ground state. Our aim is to establish what can be shown exactly about such “local moment” (LM) phases, of which the permanent (zero-field) local magnetization is a hallmark, and an order parameter for the QPT. A description of the zero-field LM phase is shown to require two distinct self-energies, which reflect the broken symmetry nature of the phase and together determine the single self-energy of standard field theory. Distinct Friedel sum rules for each phase are obtained, via a Luttinger theorem embodied in the vanishing of appropriate Luttinger integrals. By contrast, the standard Luttinger integral is nonzero in the LM phase but found to have universal magnitude. A range of spin susceptibilites are also considered, including that corresponding to the local order parameter, whose exact form is shown to be RPA-like, and to diverge as the QPT is approached. Particular attention is given to the pseudogap Anderson model, including the basic physical picture of the transition, the low-energy behavior of single-particle dynamics, the quantum critical point itself, and the rather subtle effect of an applied local field. A two-level impurity model that undergoes a QPT (“singlet-triplet”) to an underscreened LM phase is also considered, for which we derive on general grounds some key results for the zero-bias conductance in both phases.

David E. Logan; Adam P. Tucker; Martin R. Galpin

2014-08-28T23:59:59.000Z

28

Continental Liquid-phase Stratus Clouds at SGP: Meteorological Influences  

NLE Websites -- All DOE Office Websites (Extended Search)

Continental Liquid-phase Stratus Clouds at SGP: Meteorological Influences Continental Liquid-phase Stratus Clouds at SGP: Meteorological Influences and Relationship to Adiabacity Kim, Byung-Gon Kangnung National University Schwartz, Stephen Brookhaven National Laboratory Miller, Mark Brookhaven National Laboratory Min, Qilong State University of New York at Albany Category: Cloud Properties The microphysical properties of continental stratus clouds observed over SGP appear to be substantially influenced by micrometeorological conditions, such as static stability and updraft velocity. These influences may contribute to the observed weak correlation of aerosol light scattering coefficient with cloud-drop effective radius [Kim et al., JGR, 2003], although aerosol light scattering coefficient is not necessarily the most suitable surrogate aerosol property for number concentration of cloud

29

Thermal Energy Storage of Polyester Fabric Coated with Paraffin Liquid as Microencapsulated Phase Change Material (PCM)  

Science Journals Connector (OSTI)

This research work involves the production of microencapsulated phase change material (PCM) in which paraffin liquid was...

A. B. M. Dom; A. F. Mohd; N. Tulos; E. Nasir…

2014-01-01T23:59:59.000Z

30

Temperature-controlled ionic liquid dispersive liquid phase microextraction combined with ultra-high-pressure liquid chromatography for the rapid determination of triclosan, triclocarban and methyl-triclosan in aqueous samples  

Science Journals Connector (OSTI)

As extraction solvents, ionic liquids have green characteristics. In this study, an environmentally benign analytical method termed temperature-controlled ionic liquid dispersive liquid phase microextraction (TIL...

JieHong Guo; XingHong Li; XueLi Cao; Lei Qu; DeKun Hou…

2010-12-01T23:59:59.000Z

31

Oxidation Protection of Uranium Nitride Fuel using Liquid Phase Sintering  

SciTech Connect

Two methods are proposed to increase the oxidation resistance of uranium nitride (UN) nuclear fuel. These paths are: (1) Addition of USi{sub x} (e.g. U3Si2) to UN nitride powder, followed by liquid phase sintering, and (2) 'alloying' UN nitride with various compounds (followed by densification via Spark Plasma Sintering or Liquid Phase Sintering) that will greatly increase oxidation resistance. The advantages (high thermal conductivity, very high melting point, and high density) of nitride fuel have long been recognized. The sodium cooled BR-10 reactor in Russia operated for 18 years on uranium nitride fuel (UN was used as the driver fuel for two core loads). However, the potential advantages (large power up-grade, increased cycle lengths, possible high burn-ups) as a Light Water Reactor (LWR) fuel are offset by uranium nitride's extremely low oxidation resistance (UN powders oxidize in air and UN pellets decompose in hot water). Innovative research is proposed to solve this problem and thereby provide an accident tolerant LWR fuel that would resist water leaks and high temperature steam oxidation/spalling during an accident. It is proposed that we investigate two methods to increase the oxidation resistance of UN: (1) Addition of USi{sub x} (e.g. U{sub 3}Si{sub 2}) to UN nitride powder, followed by liquid phase sintering, and (2) 'alloying' UN nitride with compounds (followed by densification via Spark Plasma Sintering) that will greatly increase oxidation resistance.

Dr. Paul A. Lessing

2012-03-01T23:59:59.000Z

32

Ultrafast dynamics of the laser-induced solid-to-liquid phase transition in aluminum  

E-Print Network (OSTI)

Ultrafast dynamics of the laser-induced solid-to-liquid phase transition in aluminum A thesis dynamics of the laser-induced solid-to-liquid phase transition in aluminum Eric Mazur Maria Kandyla Abstract This dissertation reports the ultrafast dynamics of aluminum during the solid-to- liquid phase

Mazur, Eric

33

Modeling of the Phase behavior of light (C2 & C3) olefins in liquid phase epoxidation systems and experimental determination of gas/liquid mass transfer coefficients  

E-Print Network (OSTI)

). HYSYS® software was used to study the phase behavior and generate quantitative data on the solubility of gaseous olefins in the liquid phase which aided in the optimization of the reaction conditions. A detailed stirred tank reactor model was developed...

Ghanta, Madhav

2008-01-01T23:59:59.000Z

34

Effect of dimensionality on vapor-liquid phase transition  

SciTech Connect

Dimensionality play significant role on ‘phase transitions’. Fluids in macroscopic confinement (bulk or 3-Dimensional, 3D) do not show significant changes in their phase transition properties with extent of confinement, since the number of molecules away from the surrounding surfaces is astronomically higher than the number of molecules in close proximity of the confining surfaces. In microscopic confinement (quasi 3D to quasi-2D), however, the number of molecules away from the close proximity of the surface is not as high as is the case with macroscopic (3D) confinement. Hence, under the same thermodynamic conditions ‘phase transition’ properties at microscopic confinement may not remain the same as the macroscopic or 3D values. Phase transitions at extremely small scale become very sensitive to the dimensions as well as the surface characteristics of the system. In this work our investigations reveal the effect of dimensionality on the phase transition from 3D to quasi-2D to 2D behavior. We have used grand canonical transition matrix Monte Carlo simulation to understand the vapor–liquid phase transitions from 3D to quasi-2D behavior. Such studies can be helpful in understanding and controlling the fluid film behaviour confined between solid surfaces of few molecular diameters, for example, in lubrication applications.

Singh, Sudhir Kumar, E-mail: sksingh@thapar.edu [Department Chemical Engineering, Thapar University, Patiala-147004 Punjab (India)

2014-04-24T23:59:59.000Z

35

System for exchange of hydrogen between liquid and solid phases  

DOE Patents (OSTI)

The reversible reaction M + x/2 H/sub 2/ reversible MH/sub x/, wherein M is a reversible metal hydride former that forms a hydride MH/sub x/ in the presence of H/sub 2/, generally used to store and recall H/sub 2/, is found to proceed under an inert liquid, thereby reducing contamination, providing better temperature control, providing in situ mobility of the reactants, and increasing flexibility in process design. Thus, a slurry of particles of a metal hydride former with an inert solvent is subjected to a temperature and pressure controlled atmosphere containing H/sub 2/, to store hydrogen and to release previously stored hydrogen. The direction of the flow of the H/sub 2/ through the liquid is dependent upon the H/sub 2/ pressure in the gas phase at a given temperature. When the actual H/sub 2/ pressure is above the equilibrium absorption pressure of the respective hydride the reaction proceeds to the right, i.e., the metal hydride is formed and hydrogen is stored in the solid particle. When the actual pressure in the gas phase is below the equilibrium dissociation pressure of the respective hydride the reaction proceeds to the left, the metal hydride is decomposed and hydrogen is released into the gas phase.

Reilly, J.J.; Grohse, E.W.; Johnson, J.R.; Winsche, W.E.

1985-02-22T23:59:59.000Z

36

System for exchange of hydrogen between liquid and solid phases  

DOE Patents (OSTI)

The reversible reaction M+x/2 H.sub.2 .rarw..fwdarw.MH.sub.x, wherein M is a reversible metal hydride former that forms a hydride MH.sub.x in the presence of H.sub.2, generally used to store and recall H.sub.2, is found to proceed under an inert liquid, thereby reducing contamination, providing better temperature control, providing in situ mobility of the reactants, and increasing flexibility in process design. Thus, a slurry of particles of a metal hydride former with an inert solvent is subjected to a temperature and pressure controlled atmosphere containing H.sub.2, to store hydrogen and to release previously stored hydrogen. The direction of the flow of the H.sub.2 through the liquid is dependent upon the H.sub.2 pressure in the gas phase at a given temperature. When the actual H.sub.2 pressure is above the equilibrium absorption pressure of the respective hydride the reaction proceeds to the right, i.e., the metal hydride is formed and hydrogen is stored in the solid particles. When the actual pressure in the gas phase is below the equilibrium dissociation pressure of the respective hydride the reaction proceeds to the left, the metal hydride is decomposed and hydrogen is released into the gas phase.

Reilly, James J. (Bellport, NY); Grohse, Edward W. (Port Jefferson Station, NY); Johnson, John R. (Calverton, NY); Winsche, deceased, Warren E. (late of Bellport, NY)

1988-01-01T23:59:59.000Z

37

Environmental information volume: Liquid Phase Methanol (LPMEOH{trademark}) project  

SciTech Connect

The purpose of this project is to demonstrate the commercial viability of the Liquid Phase Methanol Process using coal-derived synthesis gas, a mixture of hydrogen and carbon monoxide. This report describes the proposed actions, alternative to the proposed action, the existing environment at the coal gasification plant at Kingsport, Tennessee, environmental impacts, regulatory requirements, offsite fuel testing, and DME addition to methanol production. Appendices include the air permit application, solid waste permits, water permit, existing air permits, agency correspondence, and Eastman and Air Products literature.

NONE

1996-05-01T23:59:59.000Z

38

Calculations of free energies in liquid and solid phases: Fundamental measure density-functional approach  

E-Print Network (OSTI)

Calculations of free energies in liquid and solid phases: Fundamental measure density energies of liquid and solid phases using a fundamental measure density-functional theory. Namely, we can, a theoretical description of the free energies and correlation functions of hard-sphere (HS) liquid and solid

Song, Xueyu

39

Non-aqueous liquid compositions comprising ion exchange polymers reference to related application  

DOE Patents (OSTI)

Compositions, and methods of making thereof, comprising from about 1% to about 5% of a perfluorinated sulfonic acid ionomer or a hydrocarbon-based ionomer; and from about 95% to about 99% of a solvent, said solvent consisting essentially of a polyol; wherein said composition is substantially free of water and wherein said ionomer is uniformly dispersed in said solvent.

Kim; Yu Seung (Los Alamos, NM), Lee; Kwan-Soo (Los Alamos, NM), Rockward; Tommy Q. T. (Rio Rancho, NM)

2012-08-07T23:59:59.000Z

40

NETL: Bench-Scale Development of a Non-Aqueous Solvent CO2 Capture Process  

NLE Websites -- All DOE Office Websites (Extended Search)

Bench-Scale Development of a Non-Aqueous Solvent (NAS) CO2 Capture Process for Coal-Fired Power Plants Bench-Scale Development of a Non-Aqueous Solvent (NAS) CO2 Capture Process for Coal-Fired Power Plants Project No.: DE-FE0013865 Research Triangle Institute (RTI) is continuing the development process for a non-aqueous solvent (NAS)-based CO2 capture process that was originated at laboratory scale under an ARPA-E project. This project will conduct bench-scale testing to show the potential of the technology to reduce the parasitic energy penalty. Key technical and economic challenges and uncertainties to be addressed include solvent makeup cost, scalable regenerator design, development of a complete NAS process arrangement, and improved confidence in the capital cost estimate that will enable the scale up of the process. One major focus is identification of best-candidate NAS formulations. This will entail reducing solvent makeup costs by reducing the formulation cost. In addition, efforts will be made to reduce evaporative and degradation losses while maintaining the desired CO2 absorption chemistry. A second focus area involves advancing the design of the process. This will be done by developing and evaluating the effectiveness of two process units specific to NASs - the NAS Recovery/Wash Section and NAS Regenerator. As the project proceeds, the testing campaign will evaluate thermal regeneration energy requirements [kJt / kg CO2] and develop a detailed understanding of the operation of the process. Preliminary analyses indicate that the NAS process can reduce energy consumption by 30 to 50 percent compared to current state of the art CO2 capture processes.

Note: This page contains sample records for the topic "non-aqueous phase liquid" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

A Non-Aqueous Reduction Process for Purifying 153Gd Produced in Natural Europium Targets  

SciTech Connect

Gadolinium-153 is a low-energy gamma-emitter used in nuclear medicine imaging quality assurance. Produced in nuclear reactors using natural Eu2O3 targets, 153Gd is radiochemically separated from europium isotopes by europium reduction. However, conventional aqueous europium reduction produces hydrogen gas, a flammability hazard in radiological hot cells. We altered the traditional reduction method, using methanol as the process solvent to nearly eliminate hydrogen gas production. This new, non-aqueous reduction process demonstrates greater than 98% europium removal and gadolinium yields of 90%.

Johnsen, Amanda M.; Soderquist, Chuck Z.; McNamara, Bruce K.; Fisher, Darrell R.

2013-08-01T23:59:59.000Z

42

First-order liquid-liquid phase transition in dense hydrogen  

Science Journals Connector (OSTI)

We use ab initio molecular-dynamics simulations to study the nonmetal-to-metal transition in dense liquid hydrogen. By calculating the equation of state of hydrogen at high pressures up to several megabars and temperatures above the melting line up to 1500 K we confirm the first-order nature of this transition at these temperatures. We characterize both phases based on equation of state data, the electrical conductivity, and the pair-correlation functions, which are all derived self-consistently from these simulations. We locate the respective transition line in the phase diagram and give an estimate for its critical point. We compare with available experimental data and other theoretical predictions.

Winfried Lorenzen, Bastian Holst, and Ronald Redmer

2010-11-09T23:59:59.000Z

43

Thermodynamic Relationships for Bulk Crystalline and Liquid Phases in the Phase-Field Crystal Model  

E-Print Network (OSTI)

We present thermodynamic relationships between the free energy of the phase-field crystal (PFC) model and thermodynamic state variables for bulk phases under hydrostatic pressure. This relationship is derived based on the thermodynamic formalism for crystalline solids of Larch\\'e and Cahn [Larch\\'e and Cahn, Acta Metallurgica, Vol. 21, 1051 (1973)]. We apply the relationship to examine the thermodynamic processes associated with varying the input parameters of the PFC model: temperature, lattice spacing, and the average value of the PFC order parameter, $\\bar{n}$. The equilibrium conditions between bulk crystalline solid and liquid phases are imposed on the thermodynamic relationships for the PFC model to obtain a procedure for determining solid-liquid phase coexistence. The resulting procedure is found to be in agreement with the method commonly used in the PFC community, justifying the use of the common-tangent construction to determine solid-liquid phase coexistence in the PFC model. Finally, we apply the procedure to an eighth-order-fit (EOF) PFC model that has been parameterized to body-centered-cubic ($bcc$) Fe [Jaatinen et al., Physical Review E 80, 031602 (2009)] to demonstrate the procedure as well as to develop physical intuition about the PFC input parameters. We demonstrate that the EOF-PFC model parameterization does not predict stable $bcc$ structures with positive vacancy densities. This result suggests an alternative parameterization of the PFC model, which requires the primary peak position of the two-body direct correlation function to shift as a function of $\\bar{n}$.

Victor W. L. Chan; Nirand Pisutha-Arnond; Katsuyo Thornton

2015-02-06T23:59:59.000Z

44

Transient liquid phase bonding of structural intermetallic compounds  

Science Journals Connector (OSTI)

The intermetallic compound NiAl is a candidate material for high-temperature structural applications, for example in the hot-zone of aero gas turbine engines. However, if this material is to find significant structural applications, methodologies for primary fabrication of complex components and post-service repair will be required. In particular, joining technologies suitable for bonding NiAl to nickel-base alloys are required. This paper examines transient liquid phase (TLP) bonding as a method of joining NiAl to nickel-base alloys. The focus of the paper is microstructural development at the bond-line and in the adjacent (nickel-base and NiAl) substrates. Two different interlayer materials are considered in this paper, namely: Ni – 4.5 wt.% Si – 3.2 wt.%B (designated by the American Welding Society as 'BNi-3') and commercially pure copper. Bonds between binary, nominally-stoichiometric NiAl and both commercially pure nickel and Martin Marietta 247 are examined using edge-on transmission electron microscopy. The paper considers the character of the isothermal solidification process, the formation of second-phases at the bond-line and in the adjacent substrates and the extent to which NiAl-Ni-base alloy TLP bonds obey the assumptions implicit in standard models of the TLP process.

W.F. Gale; Y. Guan; S.V. Orel

1998-01-01T23:59:59.000Z

45

Nuclear symmetry energy effects on liquid-gas phase transition in hot asymmetric nuclear matter  

E-Print Network (OSTI)

The liquid-gas phase transition in hot asymmetric nuclear matter is investigated within relativistic mean-field model using the density dependence of nuclear symmetry energy constrained from the measured neutron skin thickness of finite nuclei. We find symmetry energy has a significant influence on several features of liquid-gas phase transition. The boundary and area of the liquid-gas coexistence region, the maximal isospin asymmetry and the critical values of pressure and isospin asymmetry all of which systematically increase with increasing softness in the density dependence of symmetry energy. The critical temperature below which the liquid-gas mixed phase exists is found higher for a softer symmetry energy.

Bharat K. Sharma; Subrata Pal

2010-01-14T23:59:59.000Z

46

LIQUID PHASE DEPOSITION OF ELECTROCHROMIC THIN FILMS T. J. Richardson and M. D. Rubin  

E-Print Network (OSTI)

1 LIQUID PHASE DEPOSITION OF ELECTROCHROMIC THIN FILMS T. J. Richardson and M. D. Rubin electrochromism with high coloration efficiencies. These nickel oxide films were particularly stable compared, and readily scalable to larger substrates. Keywords: liquid phase deposition; electrochromic films; thin film

47

Selective Liquid Phase Adsorption of 5-Hydroxymethylfurfural on Nanoporous Hyper-Cross-Linked Polymers  

Science Journals Connector (OSTI)

Selective Liquid Phase Adsorption of 5-Hydroxymethylfurfural on Nanoporous Hyper-Cross-Linked Polymers ... Biogenic hydroxymethylfurfural can be separated from aqueous solutions by highly selective liquid phase adsorption on nanoporous hyper-cross-linked polymers. ... Hydroxymethylfurfural (HMF) is considered a high potential biogenic platform chemical that can be produced from carbohydrates by hydrothermal or acid-catalyzed dehydration processes. ...

Chaline Detoni; Christian Henning Gierlich; Marcus Rose; Regina Palkovits

2014-08-19T23:59:59.000Z

48

The non-aqueous chemistry of uranium has been an active area of exploration in recent decades1,2  

E-Print Network (OSTI)

-purity depleted uranium produced as a by-product of nuclear isotope enrichment programmes. The early actinideThe non-aqueous chemistry of uranium has been an active area of exploration in recent decades1 for uranium will be created in part by the quest of researchers to understand the properties and potential

Cai, Long

49

Coupling of a two phase gas liquid compositional 3D Darcy flow with a 1D compositional free gas  

E-Print Network (OSTI)

Coupling of a two phase gas liquid compositional 3D Darcy flow with a 1D compositional free gas. Masson1 , L. Trenty2 , Y. Zhang1 Coupling of a two phase gas liquid compositional 3D Darcy flow #12 analysis K, Brenner1 , R. Masson1 , L. Trenty2 , Y. Zhang1 Coupling of a two phase gas liquid compositional

Ribot, Magali

50

Trace determination of triclosan and triclocarban in environmental water samples with ionic liquid dispersive liquid-phase microextraction prior to HPLC–ESI-MS–MS  

Science Journals Connector (OSTI)

A novel and environmentally friendly microextraction method, termed ionic liquid dispersive liquid-phase microextraction (IL-DLPME), has been developed for rapid enrichment of triclosan and triclocarban before an...

Ru-Song Zhao; Xia Wang; Jing Sun; Shan-Shan Wang…

2010-06-01T23:59:59.000Z

51

Cu-Bi as a Model System For Liquid Phase Sintered Thermal Interface Management Materials  

E-Print Network (OSTI)

relates electrical resistivity to thermal conductivity for materials where electrons are principleCu-Bi as a Model System For Liquid Phase Sintered Thermal Interface Management Materials P to produce composite materials. A high melting phase (HMP) and low melting phase (LMP) are mixed

Collins, Gary S.

52

Liquid-liquid phase transition model incorporating evidence for ferroelectric state near the lambda-point anomaly in supercooled water  

E-Print Network (OSTI)

We propose a unified model combining the first-order liquid-liquid and the second-order ferroelectric phase transitions models and explaining various features of the $\\lambda$-point of liquid water within a single theoretical framework. It becomes clear within the proposed model that not only does the long-range dipole-dipole interaction of water molecules yield a large value of dielectric constant $\\epsilon$ at room temperatures, our analysis shows that the large dipole moment of the water molecules also leads to a ferroelectric phase transition at a temperature close to the lambda-point. Our more refined model suggests that the phase transition occurs only in the low density component of the liquid and is the origin of the singularity of the dielectric constant recently observed in experiments with supercooled liquid water at temperature T~233K. This combined model agrees well with nearly every available set of experiments and explains most of the well-known and even recently obtained results of MD simulations.

Peter O. Fedichev; Leonid I. Menshikov

2012-01-30T23:59:59.000Z

53

High-speed infrared phase modulators using short helical pitch ferroelectric liquid crystals  

E-Print Network (OSTI)

High-speed infrared phase modulators using short helical pitch ferroelectric liquid crystals Ju short helical pitch material and homeotropic alignment structure. This device is driven by periodic in of a thin layer of a ferroelectric liquid crystal with a small pitch and high spontaneous polarization

Wu, Shin-Tson

54

The kinetics of heterogeneous nucleation in vapor-liquid phase transitions in the presence of ions  

Science Journals Connector (OSTI)

A method for calculating the work of nucleus formation in vapor-liquid phase transitions in the presence of ions was suggested. The method took into account ions localized in the boundary surface layer of...

G. V. Anikin; L. S. Podenko

2008-12-01T23:59:59.000Z

55

Kinetics of liquid phase catalytic dehydration of methanol to dimethyl ether  

SciTech Connect

This paper reports the kinetics of the liquid phase catalytic dehydration of methanol to dimethyl ether investigated. The experiments were carried out under low concentrations of feed in a 1-L stirred autoclave, according to a statistical experimental design. The inert liquid phase used for this investigation was a 78:22 blend of paraffinic and naphthenic mineral oils. A complete thermodynamic analysis was carried out in order to determine the liquid phase concentrations of the dissolved species. A global kinetic model was developed for the rate of dimethyl ether synthesis in terms of the liquid phase concentration of methanol. The activation energy of the reaction was found to be 18,830 cal/gmol. Based on a step-wise linear regression analysis of the kinetic data, the order of the reaction which gave the best fit was 0.28 with respect to methanol.

Gogate, M.R.; Lee, B.G.; Lee, S. (Akron Univ., OH (USA). Dept. of Chemical Engineering); Kulik, C.J. (Electric Power Research Inst., Palo Alto, CA (USA))

1990-01-01T23:59:59.000Z

56

Light-Weight, Single-Phase, Liquid-Cooled Cold Plate (Presentation)  

SciTech Connect

This presentation, 'Light-Weight, Low-Cost, Single-Phase Liquid-Cooled Cold Plate,' directly addresses program goals of increased power density, specific power, and lower cost of power electronics components through improved thermal management.

Narumanchi, S.

2013-07-01T23:59:59.000Z

57

Formation of binary phase gratings in photopolymer-liquid crystal composites by a surface-controlled anisotropic phase separation  

SciTech Connect

We report on formation of binary phase gratings in photopolymer-liquid crystal (PLC) composites using a surface-controlled phase separation method. The binary nature of the PLC phase gratings is produced by employing a single step photo-ablation through an amplitude photomask which precisely controls the interfacial interactions between the LC and the photopolymer on the alignment layer. A subsequent illumination of the ultraviolet light onto the whole PLC promotes an anisotropic phase separation resulting in the formation of distinct binary patterns for the PLC structure. The electrically tunable diffraction properties of the binary phase gratings are presented.

Park, Jae-Hong; Khoo, Iam Choon; Yu, Chang-Jae; Jung, Min-Sik; Lee, Sin-Doo [216 Electrical Engineering East, Pennsylvania State University, University Park, Pennsylvania 16802 (United States); School of Electrical Engineering no. 32, Seoul National University, Kwanak P.O. Box 34, Seoul 151-600 (Korea, Republic of)

2005-01-10T23:59:59.000Z

58

Submillisecond-response polymer network liquid crystal phase modulators at 1.06-lm wavelength  

E-Print Network (OSTI)

Submillisecond-response polymer network liquid crystal phase modulators at 1.06-lm wavelength Jie modulator is demonstrated at k ¼ 1.06 lm wavelength. A decay time of 117 ls for 2p phase modulation-response and scattering-free PNLC phase modulator at k ¼ 1.06 lm. The measured response time is 117 ls for a 2p phase

Wu, Shin-Tson

59

Non-congruence of liquid-gas phase transition of asymmetric nuclear matter  

E-Print Network (OSTI)

We first explore the liquid-gas mixed phase in a bulk calculation, where two phases coexist without the geometrical structures. In the case of symmetric nuclear matter, the system behaves congruently, and the Maxwell construction becomes relevant. For asymmetric nuclear matter, on the other hand, the phase equilibrium is no more attained by the Maxwell construction since the liquid and gas phases are non-congruent; the particle fractions become completely different with each other. One of the origins of such non-congruence is attributed to the large symmetry energy. Subsequently we explore the charge-neutral nuclear matter with electrons by fully applying the Gibbs conditions to figure out the geometrical (pasta) structures in the liquid-gas mixed phase. We emphasize the effects of the surface tension and the Coulomb interaction on the pasta structures. We also discuss the thermal effects on the pasta structures.

Maruyama, Toshiki

2012-01-01T23:59:59.000Z

60

Third-order gas-liquid phase transition and the nature of Andrews critical Tian Ma and Shouhong Wang  

E-Print Network (OSTI)

Third-order gas-liquid phase transition and the nature of Andrews critical point Tian Ma-order gas-liquid phase transition and the nature of Andrews critical point Tian Ma1 and Shouhong Wang2 1 is to study the nature of the Andrews critical point in the gas-liquid transition in a physical

Wang, Shouhong

Note: This page contains sample records for the topic "non-aqueous phase liquid" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Steam generators two phase flows numerical simulation with liquid and gas momentum equations  

E-Print Network (OSTI)

Steam generators two phase flows numerical simulation with liquid and gas momentum equations M Abstract This work takes place in steam generators flow studies and we consider here steady state three words: Steam Generator, Two-phase Flow, Finite element Email address: Marc.Grandotto@cea.fr (M

Paris-Sud XI, Université de

62

Synthesis and Liquid Crystal Phase Transitions of Zirconium Phosphate Disks  

E-Print Network (OSTI)

products. Mostly with flask shape, the particles made up the clay which is abundant in the earth covering our planet. Like graphene, some inorganic layered compounds, such as MoS2, Niobium layered oxide (Niobates), and ?-Zirconium phosphates (?-Zr... discotic liquid crystal systems have been studied, including nature clay suspensions [24], monolayer niobate suspensions [25], and 4 recently graphene oxide suspensions [26], the majority of the works are focused on the I- N transitions. One reason...

Shuai, Min

2013-05-07T23:59:59.000Z

63

Toward new solid and liquid phase systems for the containment, transport and delivery of hydrogen  

NLE Websites -- All DOE Office Websites (Extended Search)

new solid and liquid phase systems new solid and liquid phase systems for the containment, transport and delivery of hydrogen By Guido P. Pez Hydrogen Energy Infrastructure for Fuel Cell Vehicle Transportation Scenario A: Distributed H 2 from a Large Scale Plant (150-230 tonne/day) Large Scale H 2 Plant (300-800 psi H 2 ) H 2 Buffer Storage Tube Trailer Liquid H 2 Truck H 2 Pipeline Multi-vehicle filling stations Feedstock: N. gas, Coal, Biomass Pet. Coke, Resids. Future: Carbon sequestration Storage: Underground well? Output: Depends on the vehicle's H 2 storage technology Currently H 2 up to >6000 psi for 5000 psi tanks Scenario B: Hydrogen by a small scale reforming of pipeline natural gas and compression Natural Gas Pipeline Reformer Liquid H 2 Backup Compressor H 2 (>6000 psig) H 2 Production: 100-400 kg/day; 4-5Kg H

64

Disappearance of the Gas-Liquid Phase Transition for Highly Charged Colloids A.-P. Hynninen and A. Z. Panagiotopoulos  

E-Print Network (OSTI)

Disappearance of the Gas-Liquid Phase Transition for Highly Charged Colloids A.-P. Hynninen and A swelling of lyotropic liquid lamel- lar phases when monovalent ions are substituted by diva- lent ions [3 08544, USA (Received 23 January 2007; published 7 May 2007) We calculate the full phase diagram

65

Phase Diagram and Photopolymerization Behavior of Mixtures of UV-Curable Multifunctional Monomer and Low Molar Mass Nematic Liquid Crystal  

Science Journals Connector (OSTI)

A teapot phase diagram was obtained in which an upper critical solution temperature (UCST) overlapped with the nematic?isotropic transition of the liquid crystal. ...

Domasius Nwabunma; Kap Jin Kim; Yuhui Lin; L. C. Chien; Thein Kyu

1998-09-15T23:59:59.000Z

66

Modelling and Numerical Simulation of Liquid-Vapor Phase Transition  

E-Print Network (OSTI)

of pressurized water reactors in the nuclear industry. Indeed, understanding the triggering of boiling crisis, temperatures and chemical potentials, which enables dynamic generation of two-phase interfaces within a pure is a critical safety issue for the nuclear industry: when the transition occurs from nucleate boiling to film

Faccanoni, Gloria

67

Phase-field Models for Solidification and Solid/Liquid Interactions  

E-Print Network (OSTI)

PHASE-FIELD MODELS FOR SOLIDIFICATION AND SOLID/LIQUID INTERACTIONS A Dissertation by MIN SOO PARK Submitted to the O?ce of Graduate Studies of Texas A&M University in partial ful?llment of the requirements for the degree of DOCTOR OF PHILOSOPHY... December 2009 Major Subject: Mechanical Engineering PHASE-FIELD MODELS FOR SOLIDIFICATION AND SOLID/LIQUID INTERACTIONS A Dissertation by MIN SOO PARK Submitted to the O?ce of Graduate Studies of Texas A&M University in partial ful...

Park, Min Soo

2011-02-22T23:59:59.000Z

68

Lower pseudogap phase of Mott insulators: A spin/vortex liquid state  

Science Journals Connector (OSTI)

The pseudogap phase is considered to be a new state of matter in the phase string model of the doped Mott insulator, which is composed of two distinct regimes known as the upper and lower pseudogap phases, respectively. The former corresponds to the formation of spin-singlet pairing, the magnetic characterizations of which have been recently studied [Phys. Rev. B 72, 104520 (2005)]. The latter, as a low-temperature regime of the pseudogap phase, is systematically explored in this work, which is characterized by the formation of the Cooper pair amplitude and described by a generalized Ginzburg-Landau theory. Elementary excitation in this phase is a charge-neutral object carrying spin-1?2 and locking with a supercurrent vortex, known as a spinon-vortex composite. Such a lower pseudogap phase can be regarded as a vortex liquid state due to the presence of free spinon vortices. Here thermally excited spinon vortices destroy the phase coherence and are responsible for the nontrivial Nernst effect and diamagnetism. The transport entropy and core energy associated with a spinon vortex are determined by the spin degrees of freedom. Such a spontaneous vortex liquid phase can be also considered as a spin liquid with a finite correlation length and gaped S=1?2 excitations, where a resonancelike nonpropagating spin mode emerges at the antiferromagnetic wavevector (?,?) with a doping-dependent characteristic energy. The superconducting phase is closely related to the lower pseudogap phase by a topological transition with spinon vortices and antivortices forming bound pairs and the emergence of fermionic quasiparticles as holon-spinon-vortex bound objects. A quantitative phase diagram in the parameter space of doping, temperature, and magnetic field is determined. Comparisons with experiments are also made.

Zheng-Yu Weng and Xiao-Liang Qi

2006-10-26T23:59:59.000Z

69

A swollen phase observed between the liquid-crystalline phase and the interdigitated phase induced by pressure and/or adding ethanol in DPPC aqueous solution  

E-Print Network (OSTI)

A swollen phase, in which the mean repeat distance of lipid bilayers is larger than the other phases, is found between the liquid-crystalline phase and the interdigitated gel phase in DPPC aqueous solution. Temperature, pressure and ethanol concentration dependences of the structure were investigated by small-angle neutron scattering, and a bending rigidity of lipid bilayers was by neutron spin echo. The nature of the swollen phase is similar to the anomalous swelling reported previously. However, the temperature dependence of the mean repeat distance and the bending rigidity of lipid bilayers are different. This phase could be a precursor to the interdigitated gel phase induced by pressure and/or adding ethanol.

H. Seto; M. Hishida; H. Nobutou; N. L. Yamada; M. Nagao; T. Takeda

2006-02-21T23:59:59.000Z

70

SINGLE-PHASE LIQUID HEAT TRANSFER IN PLAIN AND ENHANCED MICROCHANNELS Mark E. Steinke  

E-Print Network (OSTI)

SINGLE-PHASE LIQUID HEAT TRANSFER IN PLAIN AND ENHANCED MICROCHANNELS Mark E. Steinke Systems upon the understanding of the fundamental heat transfer processes that occur in these systems. There have been great advancements in our understanding of the heat transfer and fluid flow mechanisms

Kandlikar, Satish

71

Liquid-Phase Gallium–Indium Alloy Electronics with Microcontact Printing  

Science Journals Connector (OSTI)

The microcontact printer is composed of a print head mounted to a three-axis Cartesian robot. ... (9) Potential applications include soft and stretchable electronics for wearable technologies that monitor human motion(18-20) and electronic skin for biologically inspired soft robots. ... A paint brush is used to ink the stamps with a coat of liquid-phase GaIn alloy. ...

Arya Tabatabai; Andrew Fassler; Claire Usiak; Carmel Majidi

2013-04-30T23:59:59.000Z

72

Hierarchical Nanoparticle Ensembles Synthesized by Liquid Phase Directed Self-Assembly  

E-Print Network (OSTI)

Hierarchical Nanoparticle Ensembles Synthesized by Liquid Phase Directed Self-Assembly J. D, nanoparticle radius control is demonstrated using a micrometer scale switch. KEYWORDS: Self-assembly, directed assembly, Rayleigh-Plateau, volume-of-Fluid, hierarchical, nanoparticle assembly Chemical synthesis methods

Kondic, Lou

73

DYNAMIC MODELING STRATEGY FOR FLOW REGIME TRANSITION IN GAS-LIQUID TWO-PHASE FLOWS  

SciTech Connect

In modeling gas-liquid two-phase flows, the concept of flow regime has been used to characterize the global interfacial structure of the flows. Nearly all constitutive relations that provide closures to the interfacial transfers in two-phase flow models, such as the two-fluid model, are often flow regime dependent. Currently, the determination of the flow regimes is primarily based on flow regime maps or transition criteria, which are developed for steady-state, fully-developed flows and widely applied in nuclear reactor system safety analysis codes, such as RELAP5. As two-phase flows are observed to be dynamic in nature (fully-developed two-phase flows generally do not exist in real applications), it is of importance to model the flow regime transition dynamically for more accurate predictions of two-phase flows. The present work aims to develop a dynamic modeling strategy for determining flow regimes in gas-liquid two-phase flows through the introduction of interfacial area transport equations (IATEs) within the framework of a two-fluid model. The IATE is a transport equation that models the interfacial area concentration by considering the creation and destruction of the interfacial area, such as the fluid particle (bubble or liquid droplet) disintegration, boiling and evaporation; and fluid particle coalescence and condensation, respectively. For the flow regimes beyond bubbly flows, a two-group IATE has been proposed, in which bubbles are divided into two groups based on their size and shape (which are correlated), namely small bubbles and large bubbles. A preliminary approach to dynamically identifying the flow regimes is provided, in which discriminators are based on the predicted information, such as the void fraction and interfacial area concentration of small bubble and large bubble groups. This method is expected to be applied to computer codes to improve their predictive capabilities of gas-liquid two-phase flows, in particular for the applications in which flow regime transition occurs.

X. Wang; X. Sun; H. Zhao

2011-09-01T23:59:59.000Z

74

Combining Laser Ablation/Liquid Phase Collection Surface Sampling and High-Performance Liquid Chromatography Electrospray Ionization Mass Spectrometry  

SciTech Connect

This paper describes the coupling of ambient pressure transmission geometry laser ablation with a liquid phase sample collection method for surface sampling and ionization with subsequent mass spectral analysis. A commercially available autosampler was adapted to produce a liquid droplet at the end of the syringe injection needle while in close proximity to the surface to collect the sample plume produced by laser ablation. The sample collection was followed by either flow injection or a high performance liquid chromatography (HPLC) separation of the extracted components and detection with electrospray ionization mass spectrometry (ESI-MS). To illustrate the analytical utility of this coupling, thin films of a commercial ink sample containing rhodamine 6G and of mixed isobaric rhodamine B and 6G dyes on glass microscope slides were analyzed. The flow injection and HPLC/ESI-MS analysis revealed successful laser ablation, capture and, with HPLC, the separation of the two compounds. The ablated circular area was about 70 m in diameter for these experiments. The spatial sampling resolution afforded by the laser ablation, as well as the ability to use sample processing methods like HPLC between the sample collection and ionization steps, makes this combined surface sampling/ionization technique a highly versatile analytical tool.

Ovchinnikova, Olga S [ORNL; Kertesz, Vilmos [ORNL; Van Berkel, Gary J [ORNL

2011-01-01T23:59:59.000Z

75

Liquid crystal terahertz phase shifters with functional indium-tin-oxide nanostructures for biasing and alignment  

SciTech Connect

Indium Tin Oxide (ITO) nanowhiskers (NWhs) obliquely evaporated by electron-beam glancing-angle deposition can serve simultaneously as transparent electrodes and alignment layer for liquid crystal (LC) devices in the terahertz (THz) frequency range. To demonstrate, we constructed a THz LC phase shifter with ITO NWhs. Phase shift exceeding ?/2 at 1.0 THz was achieved in a ?517??m-thick cell. The phase shifter exhibits high transmittance (?78%). The driving voltage required for quarter-wave operation is as low as 5.66?V (rms), compatible with complementary metal-oxide-semiconductor (CMOS) and thin-film transistor (TFT) technologies.

Yang, Chan-Shan [Department of Physics, National Tsing Hua University, Hsinchu 30013, Taiwan (China); Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720 (United States); Tang, Tsung-Ta [Taiwan Semiconductor Manufacturing Company, Hsinchu, Taiwan (China); Pan, Ru-Pin [Department of Electrophysics, National Chiao Tung University, Hsinchu 30078, Taiwan (China); Yu, Peichen [Department of Photonics and Institute of Electro-Optical Engineering, National Chiao Tung University, Hsinchu 30010, Taiwan (China); Pan, Ci-Ling, E-mail: clpan@phys.nthu.edu.tw [Department of Physics, National Tsing Hua University, Hsinchu 30013, Taiwan (China); Frontier Research Center on Fundamental and Applied Science of Matters, Hsinchu 30013, Taiwan (China)

2014-04-07T23:59:59.000Z

76

Third-Order Gas-Liquid Phase Transition and the Nature of Andrews Critical Point  

E-Print Network (OSTI)

The main objective of this article is to study the nature of the Andrews critical point in the gas-liquid transition in a physical-vapor transport (PVT) system. A dynamical model, consistent with the van der Waals equation near the Andrews critical point, is derived. With this model, we deduce two physical parameters, which interact exactly at the Andrews critical point, and which dictate the dynamic transition behavior near the Andrews critical point. In particular, it is shown that 1) the Andrews critical point is a switching point where the phase transition changes from the first order to the third order, 2) the gas-liquid co-existence curve can be extended beyond the Andrews critical point, and 3) the liquid-gas phase transition going beyond Andrews point is of the third order. This clearly explains why it is hard to observe the gas-liquid phase transition beyond the Andrews critical point. Furthermore, the analysis leads naturally the introduction of a general asymmetry principle of fluctuations and the preferred transition mechanism for a thermodynamic system.

Tian Ma; Shouhong Wang

2010-07-13T23:59:59.000Z

77

Lattice Boltzmann simulations of liquid crystalline fluids: active gels and blue phases  

E-Print Network (OSTI)

Lattice Boltzmann simulations have become a method of choice to solve the hydrodynamic equations of motion of a number of complex fluids. Here we review some recent applications of lattice Boltzmann to study the hydrodynamics of liquid crystalline materials. In particular, we focus on the study of (a) the exotic blue phases of cholesteric liquid crystals, and (b) active gels - a model system for actin plus myosin solutions or bacterial suspensions. In both cases lattice Boltzmann studies have proved useful to provide new insights into these complex materials.

M. E. Cates; O. Henrich; D. Marenduzzo; K. Stratford

2010-09-06T23:59:59.000Z

78

On the existence of vapor-liquid phase transition in dusty plasmas  

SciTech Connect

The phenomenon of phase transition in a dusty-plasma system (DPS) has attracted some attention in the past. Earlier Farouki and Hamaguchi [J. Chem. Phys. 101, 9876 (1994)] have demonstrated the existence of a liquid to solid transition in DPS where the dust particles interact through a Yukawa potential. However, the question of the existence of a vapor-liquid (VL) transition in such a system remains unanswered and relatively unexplored so far. We have investigated this problem by performing extensive molecular dynamics simulations which show that the VL transition does not have a critical curve in the pressure versus volume diagram for a large range of the Yukawa screening parameter ? and the Coulomb coupling parameter ?. Thus, the VL phase transition is found to be super-critical, meaning that this transition is continuous in the dusty plasma model given by Farouki and Hamaguchi. We provide an approximate analytic explanation of this finding by means of a simple model calculation.

Kundu, M.; Sen, A.; Ganesh, R. [Institute for Plasma Research, Bhat, Gandhinagar 382 428, Gujarat (India); Avinash, K. [Department of Physics and Astrophysics, University of Delhi, Delhi 110007 (India)

2014-10-15T23:59:59.000Z

79

Ice-water and liquid-vapor phase transitions by a Ginzburg–Landau model  

Science Journals Connector (OSTI)

A model for the first order phase transitions as ice-water and liquid-vapor is proposed using the Ginzburg–Landau equation for the order parameter ? . In this model the density ? is composed of two quantities ? 0 and ? 1 such that 1 / ? = 1 / ? 0 + 1 / ? 1 where ? 1 is strictly connected to the order parameter ? . By means of this decomposition we are able to represent the Andrew diagram without the use of the heuristic van der Waals equation.

Mauro Fabrizio

2008-01-01T23:59:59.000Z

80

Structure and phase transitions into ionic adsorption layers on liquid interfaces  

E-Print Network (OSTI)

The structure of ionic adsorption layers is studied via a proper thermodynamic treatment of the electrostatic and non-electrostatic interactions between the surfactant ions as well as of the effect of thermodynamic non-locality. The analysis is also applied to phase transitions into the ionic adsorption layer, which interfere further with the oscillatory-diffusive structure of the electric double layer and hydrodynamic stability of squeezing waves in thin liquid films.

R. Tsekov

2014-03-02T23:59:59.000Z

Note: This page contains sample records for the topic "non-aqueous phase liquid" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Laser-induced chemical liquid phase deposition of copper from aqueous solutions without reducing agents  

SciTech Connect

Laser-induced chemical liquid phase deposition of copper without a traditional reducing agent has been used for the first time to obtain conductive patterns on a dielectric surface having a reducing ability. It is shown that phenol-formaldehyde binder of the dielectric (glass fibre) can successfully play the role of a reducing agent in this process. The resulting copper sediments have low electrical resistance and good topology. (interaction of laser radiation with matter. laser plasmas)

Kochemirovsky, V A; Tumkin, I I; Logunov, L S; Safonov, S V; Menchikov, Leonid G

2012-08-31T23:59:59.000Z

82

DESIGN AND DEVELOPMENT OF GAS-LIQUID CYLINDRICAL CYCLONE COMPACT SEPARATORS FOR THREE-PHASE FLOW  

SciTech Connect

The U.S. Department of Energy (DOE) has awarded a five-year (1997-2002) grant (Mohan and Shoham, DE-FG26-97BC15024, 1997) to The University of Tulsa, to develop compact multiphase separation components for 3-phase flow. The research activities of this project have been conducted through cost sharing by the member companies of the Tulsa University Separation Technology Projects (TUSTP) research consortium and the Oklahoma Center for the Advancement of Science and Technology (OCAST). As part of this project, several individual compact separation components have been developed for onshore and offshore applications. These include gas-liquid cylindrical cyclones (GLCC{copyright}), liquid-liquid cylindrical cyclones (LLCC{copyright}), and the gas-liquid-liquid cylindrical cyclones (GLLCC{copyright}). A detailed study has also been completed for the liquid-liquid hydrocyclones (LLHC). Appropriate control strategies have been developed for proper operation of the GLCC{copyright} and LLCC{copyright}. Testing of GLCC{copyright} at high pressure and real crude conditions for field applications is also completed. Limited studies have been conducted on flow conditioning devices to be used upstream of the compact separators for performance improvement. This report presents a brief overview of the activities and tasks accomplished during the 5-year project period, October 1, 1997-March 31, 2003 (including the no-cost extended period of 6 months). An executive summary is presented initially followed by the tasks of the 5-year budget periods. Then, detailed description of the experimental and modeling investigations are presented. Subsequently, the technical and scientific results of the activities of this project period are presented with some discussions. The findings of this investigation are summarized in the ''Conclusions'' section, followed by relevant references. The publications resulting from this study in the form of MS Theses, Ph.D. Dissertation, Journal Papers and Conference Presentations are provided at the end of this report.

Dr. Ram S. Mohan; Dr. Ovadia Shoham

2003-06-25T23:59:59.000Z

83

Single-reactor process for producing liquid-phase organic compounds from biomass  

DOE Patents (OSTI)

Disclosed is a method for preparing liquid fuel and chemical intermediates from biomass-derived oxygenated hydrocarbons. The method includes the steps of reacting in a single reactor an aqueous solution of a biomass-derived, water-soluble oxygenated hydrocarbon reactant, in the presence of a catalyst comprising a metal selected from the group consisting of Cr, Mn, Fe, Co, Ni, Cu, Mo, Tc, Ru, Rh, Pd, Ag, W, Re, Os, Ir, Pt, and Au, at a temperature, and a pressure, and for a time sufficient to yield a self-separating, three-phase product stream comprising a vapor phase, an organic phase containing linear and/or cyclic mono-oxygenated hydrocarbons, and an aqueous phase.

Dumesic, James A. (Verona, WI); Simonetti, Dante A. (Middleton, WI); Kunkes, Edward L. (Madison, WI)

2011-12-13T23:59:59.000Z

84

Functional design criteria for Project W-252, Phase II Liquid Effluent Treatment and Disposal: Revision 1  

SciTech Connect

This document provides the functional design criteria required for the Phase 2 Liquid Effluent Treatment and Disposal Project, Project W-252. Project W-252 shall provide new facilities and existing facility modifications required to implement Best Available Technology/All Known, Available, and Reasonable Methods of Prevention, Control, and Treatment (BAT/AKART) for the 200 East Phase II Liquid Effluent Streams. The project will also provide a 200 East Area Phase II Effluent Collection System (PTECS) for connection to a disposal system for relevant effluent streams to which BAT/AKART has been applied. Liquid wastestreams generated in the 200 East Area are currently discharged to the soil column. Included in these wastestreams are cooling water, steam condensate, raw water, and sanitary wastewaters. It is the policy of the DOE that the use of soil columns to treat and retain radionuclides and nonradioactive contaminants be discontinued at the earliest practical time in favor of wastewater treatment and waste minimization. In 1989, the DOE entered into an interagency agreement with Ecology and EPA. This agreement is referred to as the Hanford Federal Facility Agreement and Consent Order (Tri-Party Agreement). Project W-252 is one of the projects required to achieve the milestones set forth in the Tri-Party Agreement. One of the milestones requires BAT/AKART implementation for Phase II streams by October 1997. This Functional Design Criteria (FDC) document provides the technical baseline required to initiate Project W-252 to meet the Tri-Party Agreement milestone for the application of BAT/AKART to the Phase II effluents.

Hatch, C.E.

1994-11-10T23:59:59.000Z

85

Commercial-Scale Demonstration of the Liquid Phase Methanol (LOMEOH(TM)) Process  

SciTech Connect

The Liquid Phase Methanol (LPMEOEP") Demonstration Project at K.ingsport, Tennessee, is a $213.7 million cooperative agreement between the U.S. Department of Energy (DOE) and Air Products Liquid Phase Conversion Company, L, P. (the Partnership). The LPMEOHY Process Demonstration Unit is being built at a site located at the Eastman Chemical Company (Eastman) complex in Kingsport. On 4 October 1994, Air Products and Chemicals, Inc. (Air Products) and signed the agreements that would form the Partnership, secure the demonstration site, and provide the financial commitment and overall project management for the project. These partnership agreements became effective on 15 March 1995, when DOE authorized the commencement of Budget Period No. 2 (Mod. AO08 to the Cooperative Agreement). The Partnership has subcontracted with Air Products to provide the overall management of the project, and to act as the primary interface with DOE. As subcontractor to the Partnership, Air Products will also provide the engineering design, procurement, construction, and commissioning of the LPMEOHTM Process Demonstration Unit, and will provide the technical and engineering supervision needed to conduct the operational testing program required as part of the project. As subcontractor to Air Products, Eastman will be responsible for operation of the LPMEOHTM Process Demonstration Unit, and for the interconnection and supply of synthesis gas, utilities, product storage, and other needed sewices. The project involves the construction of an 80,000 gallons per day (260 tons-per-day (TPD)) methanol unit utilizing coal-derived synthesis gas fi-om Eastman's integrated coal gasification facility. The new equipment consists of synthesis gas feed preparation and compression facilities, the liquid phase reactor and auxiliaries, product distillation facilities, and utilities. The technology to be demonstrated is the product of a cooperative development effort by Air Products and DOE in a program that started in 1981. Developed to enhance electric power generation using integrated gasification combined cycle (IGCC) technology, the LPMEOHTM process is ideally suited for directly processing gases produced by modern day coal gasifiers. Originally tested at a small 3,200 gallons per day, DOE-owned experimental unit in LaPorte, Texas, the technology provides several improvements essential for the economic coproduction of methanol and electricity directly from gasified coal. This liquid phase process suspends fine catalyst particles in an inert liquid, forming a slurry. The slurry dissipates the heat of the chemical reaction away from the catalyst surface, protecting the catalyst and allowing the methanol synthesis reaction to proceed at higher rates.

None

1996-03-31T23:59:59.000Z

86

Non-Aqueous Solvation of n-Octanol and Ethanol: Spectroscopic and Computational Lori M. Levering, Carrigan J. Hayes, Karen M. Callahan, Christopher M. Hadad,* and  

E-Print Network (OSTI)

Non-Aqueous Solvation of n-Octanol and Ethanol: Spectroscopic and Computational Studies Lori M-H bonds in n-octanol and ethanol with the organic solvents carbon tetrachloride (CCl4), cyclohexane populations of each ethanol complex and are consistent with the experimental results. Additional spectra were

87

Liquid-crystalline phases formed by DNA duplexes containing pyrophosphate groups  

SciTech Connect

We have studied the interaction between synthetic DNA molecules containing pyrophosphate (PP) groups in various positions, which makes it possible to control the charge distribution along the DNA chain. The PP groups were either symmetrically arranged at the ends or at the center of DNA molecules or uniformly distributed along these molecules. It is shown that, similar to nonmodified DNA, the synthetic PP-modified DNA molecules can form cholesteric liquid crystals. Minima of the pair interaction potential are found, conditions of the symmetry of this potential are formulated, and the dependence of conformation angles on the effective charge is determined. The results of calculations show that the system exhibits polymorphism (i.e., several phases of cholesteric liquid crystals can exist in DNA solutions)

Volkov, Yu. S., E-mail: yu.volkov@gmail.com; Golo, V. L. [Moscow State University (Russian Federation); Kats, E. I. [Russian Academy of Sciences Chernogolovka, Landau Institute for Theoretical Physics (Russian Federation); Kuznetsova, S. A. [Institut Laue-Langevin (France)

2009-03-15T23:59:59.000Z

88

Derivation of a three-dimensional phase-field-crystal model for liquid crystals from density functional theory  

E-Print Network (OSTI)

Using a generalized order parameter gradient expansion within density functional theory, we derive a phase-field-crystal model for liquid crystals composed by apolar particles in three spatial dimensions. Both the translational density and the orientational direction and ordering are included as order parameters. Different terms involving gradients in the order parameters in the resulting free energy functional are compared to the macroscopic Ginzburg-Landau approach as well as to the hydrodynamic description for liquid crystals. Our approach provides microscopic expressions for all prefactors in terms of the particle interactions. Our phase-field-crystal model generalizes the conventional phase-field-crystal model of spherical particles to orientational degrees of freedom and can be used as a starting point to explore phase transitions and interfaces for various liquid-crystalline phases.

Raphael Wittkowski; Hartmut Löwen; Helmut R. Brand

2010-07-09T23:59:59.000Z

89

Commercial-Scale Demonstration of the Liquid Phase methanol (LPMEOH) Process A DOE Assessment  

SciTech Connect

The U.S. Department of Energy (DOE) Clean Coal Technology (CCT) Program seeks to offer the energy marketplace more efficient and environmentally benign coal utilization technology options by demonstrating them in industrial settings. This document is a DOE post-project assessment (PPA) of one of the projects selected in Round III of the CCT Program, the commercial-scale demonstration of the Liquid Phase Methanol (LPMEOH{trademark}) Process, initially described in a Report to Congress by DOE in 1992. Methanol is an important, large-volume chemical with many uses. The desire to demonstrate a new process for the production of methanol from coal, prompted Air Products and Chemicals, Inc. (Air Products) to submit a proposal to DOE. In October 1992, DOE awarded a cooperative agreement to Air Products to conduct this project. In March 1995, this cooperative agreement was transferred to Air Products Liquid Phase Conversion Company, L.P. (the Partnership), a partnership between Air Products and Eastman Chemical Company (Eastman). DOE provided 43 percent of the total project funding of $213.7 million. Operation of the LPMEOH Demonstration Unit, which is sited at Eastman's chemicals-from-coal complex in Kingsport, Tennessee, commenced in April 1997. Although operation of the CCT project was completed in December 2002, Eastman continues to operate the LPMEOH Demonstration Unit for the production of methanol. The independent evaluation contained herein is based primarily on information from Volume 2 of the project's Final Report (Air Products Liquid Phase Conversion Co., L.P. 2003), as well as other references cited.

National Energy Technology Laboratory

2003-10-27T23:59:59.000Z

90

Joining of Ion Transport Membranes Using a Novel Transient Liquid Phase Process  

SciTech Connect

The feasibility of a novel transient liquid phase (TLP) joining method has been demonstrated in joining La{sub 0.9}Ca{sub 0.1}FeO{sub 3} materials. Metal oxide powders were processed to form the TLP compositions which were used in the joining process. The method has been successful in producing joint interfaces that effectively disappear, as they are the same material and have the same properties as the joined parts. The feasibility of the method has been demonstrated for a single system, but many systems where the method can potentially be applied have been identified.

Darryl P. Butt

2006-08-30T23:59:59.000Z

91

COMMERCIAL-SCALE DEMONSTRATION OF THE LIQUID PHASE METHANOL (LPMEOH) PROCESS  

SciTech Connect

This project, which was sponsored by the U.S. Department of Energy (DOE) under the Clean Coal Technology Program to demonstrate the production of methanol from coal-derived synthesis gas (syngas), has completed the 69-month operating phase of the program. The purpose of this Final Report for the ''Commercial-Scale Demonstration of the Liquid Phase Methanol (LPMEOH{trademark}) Process'' is to provide the public with details on the performance and economics of the technology. The LPMEOH{trademark} Demonstration Project was a $213.7 million cooperative agreement between the DOE and Air Products Liquid Phase Conversion Company, L.P. (the Partnership). The DOE's cost share was $92,708,370 with the remaining funds coming from the Partnership. The LPMEOH{trademark} demonstration unit is located at the Eastman Chemical Company (Eastman) chemicals-from-coal complex in Kingsport, Tennessee. The technology was the product of a cooperative development effort by Air Products and Chemicals, Inc. (Air Products) and DOE in a program that started in 1981. Developed to enhance electric power generation using integrated gasification combined cycle (IGCC) technology, the LPMEOH{trademark} Process is ideally suited for directly processing gases produced by modern coal gasifiers. Originally tested at the Alternative Fuels Development Unit (AFDU), a small, DOE-owned process development facility in LaPorte, Texas, the technology provides several improvements essential for the economic coproduction of methanol and electricity directly from gasified coal. This liquid phase process suspends fine catalyst particles in an inert liquid, forming a slurry. The slurry dissipates the heat of the chemical reaction away from the catalyst surface, protecting the catalyst, and allowing the methanol synthesis reaction to proceed at higher rates. The LPMEOH{trademark} Demonstration Project accomplished the objectives set out in the Cooperative Agreement with DOE for this Clean Coal Technology project. Overall plant availability (defined as the percentage of time that the LPMEOH{trademark} demonstration unit was able to operate, with the exclusion of scheduled outages) was 97.5%, and the longest operating run without interruption of any kind was 94 days. Over 103.9 million gallons of methanol was produced; Eastman accepted all of the available methanol for use in the production of methyl acetate, and ultimately cellulose acetate and acetic acid.

E.C. Heydorn; B.W. Diamond; R.D. Lilly

2003-06-01T23:59:59.000Z

92

Investigation of the Rechargeability of Li-O2 Batteries in Non-aqueous Electrolyte  

SciTech Connect

In order to understand the nature of the limited cycle life and poor energy efficiency associated with the secondary Li-O¬2 batteries the discharge products of primary Li-O2 cells at different depth of discharge (DOD) are systematically analyzed in this work. It is revealed that if discharged to 2.0 V a small amount of Li2O2 coexist with Li2CO3 and RO-(C=O)-OLi) in alkyl carbonate-based electrolyte. Further discharging the air electrodes to below 2.0 V the amount of Li2CO3 and LiRCO3 increases significantly due to the severe electrolyte decomposition. There is no Li2O detected in this alkyl carbonate electrolyte regardless of DOD. It is also found that the alkyl carbonate based electrolyte begins to decompose at 4.0 V during charging under the combined influences from the high surface area carbon, the nickel metal current collector and the oxygen atmosphere. Accordingly the impedance of the Li-O2 cell continues to increase after each discharge and recharge process indicating a repeated plating of insoluble lithium salts on the carbon surface. Therefore the whole carbon electrode becomes completely insulated only after a few cycles and loses the function of providing active tri-phase regions for the Li-oxygen batteries.

Xiao, Jie; Hu, Jian Z.; Wang, Deyu; Hu, Dehong; Xu, Wu; Graff, Gordon L.; Nie, Zimin; Liu, Jun; Zhang, Jiguang

2011-07-01T23:59:59.000Z

93

Laser-Directed Hierarchical Assembly of Liquid Crystal Defects and Control of Optical Phase Singularities  

SciTech Connect

Topological defect lines are ubiquitous and important in a wide variety of fascinating phenomena and theories in many fields ranging from materials science to early-universe cosmology, and to engineering of laser beams. However, they are typically hard to control in a reliable manner. Here we describe facile erasable 'optical drawing' of self-assembled defect clusters in liquid crystals. These quadrupolar defect clusters, stabilized by the medium's chirality and the tendency to form twisted configurations, are shaped into arbitrary two-dimensional patterns, including reconfigurable phase gratings capable of generating and controlling optical phase singularities in laser beams. Our findings bridge the studies of defects in condensed matter physics and optics and may enable applications in data storage, singular optics, displays, electro-optic devices, diffraction gratings, as well as in both optically- and electrically-addressed pixel-free spatial light modulators.

Ackerman, P. J.; Qi, Z. Y.; Lin, Y. H.; Twombly, C. W.; Laviada, M. J.; Lansac, Y.; Smalyukh, I. I.

2012-06-07T23:59:59.000Z

94

Liquid-Liquid Transition at Tg and Stable-Glass Phase Nucleation Rate Maximum at the Kauzmann Temperature TK  

E-Print Network (OSTI)

An undercooled liquid is unstable. The driving force of the glass transition at Tg is a change of the undercooled-liquid Gibbs free energy. The classical Gibbs free energy change for a crystal formation is completed including an enthalpy saving. The crystal growth critical nucleus is used as a probe to observe the Laplace pressure change Dp accompanying the enthalpy change -Vm*Dp at Tg where Vm is the molar volume. A stable glass-liquid transition model predicts the specific heat jump of fragile liquids at temperatures smaller than Tg, the Kauzmann temperature TK where the liquid entropy excess with regard to crystal goes to zero, the equilibrium enthalpy between TK and Tg, the maximum nucleation rate at TK of superclusters containing magic atom numbers, and the equilibrium latent heats at Tg and TK. Strong-to-fragile and strong-to-strong liquid transitions at Tg are also described and all their thermodynamic parameters are determined from their specific heat jumps. The existence of fragile liquids quenched in the amorphous state, which do not undergo liquid-liquid transition during heating preceding their crystallization, is predicted. Long ageing times leading to the formation at TK of a stable glass composed of superclusters containing up to 147 atoms, touching and interpenetrating, are evaluated from nucleation rates.

Robert Felix Tournier

2014-04-10T23:59:59.000Z

95

Operation of a GERDA Phase I prototype detector in liquid argon and nitrogen  

E-Print Network (OSTI)

The GERDA (GERmanium Detector Array) experiment aiming to search for the neutrinoless double beta decay of 76Ge at the Laboratori Nazionali Del Gran Sasso (LNGS), Italy, will operate bare enriched high-purity germanium (HPGe) detectors in liquid argon. GERDA Phase I will use the enriched diodes from the previous Heidelberg-Moscow (HdM) and IGEX experiments. With the HPGe detectors mounted in a low-mass holder, GERDA aims at an excellent energy resolution and extremely low background. The goal is to check the claim for the neutrinoless double beta decay evidence in the HdM 76Ge experiment within one year of data taking. Before dismounting the enriched diodes from their cryostat, the performance parameters of the HdM and the IGEX detectors have been measured. The diodes have been removed from their cryostats, their dimensions measured and they have been put under va-cuum in a transportation container. They are now being refurbished for GERDA Phase I at Canberra Semiconductor NV. Before operating the enriched diodes, a non-enriched HPGe p-type detector mounted in a low-mass holder is operated in the liquid argon test facility of the GERDA Detector Laboratory (GDL) at LNGS. Since January 2006, the testing of the prototype detector is being carried out in the GDL as well as at the site of the detector manufacturer.

M. Barnabé Heider; A. Bakalyarov; L. Bezrukov; C. Cattadori; O. Chkvorets; K. Gusev; M. Hult; I. Kirpichnikov; V. Lebedev; G. Marissens; P. Peiffer; S. Schönert; M. Shirchenko; A. Smolnikov; A. Vasenko; S. Vasiliev; S. Zhukov

2008-12-20T23:59:59.000Z

96

Rapid Heating of a Strongly Coupled Plasma near the Solid-Liquid Phase Transition M. J. Jensen,1,* T. Hasegawa,1,2  

E-Print Network (OSTI)

phase transition. We observe an unexpected rapid heating of the 9 Be ions in the region of the predictedRapid Heating of a Strongly Coupled Plasma near the Solid-Liquid Phase Transition M. J. Jensen,1 these systems undergo a liquid-solid phase transition which has been the subject of considerable interest

California at San Diego, University of

97

Small-angle neutron scattering study of structure and interaction during salt-induced liquid-liquid phase transition in protein solutions  

Science Journals Connector (OSTI)

The liquid-liquid phase transition (LLPT) in aqueous salt solutions of lysozyme protein has been studied by small-angle neutron scattering. Measurements have been carried out on fixed protein concentration with varying salt concentration approaching LLPT. The data are fitted considering protein interaction by the two Yukawa (2Y) potential which combines short-range attraction and long-range repulsion. We show that LLPT arises because of enhancement of non-DLVO (Derjaguin-Landau-Verwey-Overbeek) short-range attraction without any conformational structural change of the protein. The salt concentration required for LLPT as well as corresponding short-range attraction decreases significantly with increase in protein concentration.

A. J. Chinchalikar; V. K. Aswal; J. Kohlbrecher; A. G. Wagh

2013-06-18T23:59:59.000Z

98

Prediction of the theoretical capacity of non-aqueous lithium-air Peng Tan, Zhaohuan Wei, W. Shyy, T.S. Zhao  

E-Print Network (OSTI)

/non-aqueous (hybrid), and solid-state. In aqueous [4­10], hybrid [11­16], and solid-state [17­24] lithium-air batter- ies, a solid-state layer is generally used to transport Li+ ions. The internal resistance associated with this solid plate can be a main factor that limits the performance of these types of battery. In non

Zhao, Tianshou

99

Microstructural evolution during transient liquid phase bonding of Inconel 738LC using AMS 4777 filler alloy  

SciTech Connect

IN-738LC nickel-based superalloy was joined by transient liquid phase diffusion bonding using AMS 4777 filler alloy. The bonding process was carried out at 1050 Degree-Sign C under vacuum atmosphere for various hold times. Microstructures of the joints were studied by optical and scanning electron microscopy. Continuous centerline eutectic phases, characterized as nickel-rich boride, chromium-rich boride and nickel-rich silicide were observed at the bonds with incomplete isothermal solidification. In addition to the centerline eutectic products, precipitation of boron-rich particles was observed in the diffusion affected zone. The results showed that, as the bonding time was increased to 75 min, the width of the eutectic zone was completely removed and the joint was isothermally solidified. Homogenization of isothermally solidified joints at 1120 Degree-Sign C for 300 min resulted in the elimination of intermetallic phases formed at the diffusion affected zone and the formation of significant {gamma} Prime precipitates in the joint region. - Highlights: Black-Right-Pointing-Pointer TLP bonding of IN-738LC superalloy was performed using AMS 4777 filler alloy. Black-Right-Pointing-Pointer Insufficient diffusion time resulted in the formation of eutectic product. Black-Right-Pointing-Pointer Precipitation of B-rich particles was observed within the DAZ. Black-Right-Pointing-Pointer The extent of isothermal solidification increased with increasing holding time. Black-Right-Pointing-Pointer Homogenizing of joints resulted in the dissolution of DAZ intermetallics.

Jalilvand, V., E-mail: jalilvand@aut.ac.ir [Department of Mining and Metallurgical Engineering, Amirkabir University of Technology (Tehran Polytechnic), Tehran 15875-4413 (Iran, Islamic Republic of); Omidvar, H. [Department of Mining and Metallurgical Engineering, Amirkabir University of Technology (Tehran Polytechnic), Tehran 15875-4413 (Iran, Islamic Republic of)] [Department of Mining and Metallurgical Engineering, Amirkabir University of Technology (Tehran Polytechnic), Tehran 15875-4413 (Iran, Islamic Republic of); Shakeri, H.R. [Department of Materials Science and Engineering, University of Toronto, Toronto, Ontario M5S 3E4 (Canada)] [Department of Materials Science and Engineering, University of Toronto, Toronto, Ontario M5S 3E4 (Canada); Rahimipour, M.R. [Department of Ceramic, Materials and Energy Research Center, Karaj 31787-316 (Iran, Islamic Republic of)] [Department of Ceramic, Materials and Energy Research Center, Karaj 31787-316 (Iran, Islamic Republic of)

2013-01-15T23:59:59.000Z

100

Continuous phase transition from Néel state to Z2 spin-liquid state on a square lattice  

Science Journals Connector (OSTI)

Recent numerical studies of the J1-J2 model on a square lattice suggest a possible continuous phase transition between the Néel state and a gapped spin-liquid state with Z2 topological order. We show that such a phase transition can be realized through two steps: First bring the Néel state to the U(1) deconfined quantum critical point, which has been studied in the context of Néel–valence bond solid (VBS) state phase transition. Then condense the spinon pair–skyrmion/antiskyrmion bound state, which carries both gauge charge and flux of the U(1) gauge field emerging at the deconfined quantum critical point. We also propose a Schwinger boson projective wave function to realize such a Z2 spin liquid state and find that it has a relatively low variational energy (?0.4893J1/site) for the J1-J2 model at J2=0.5J1. The spin liquid state we obtain breaks the fourfold rotational symmetry of the square lattice and therefore is a nematic spin liquid state. This direct continuous phase transition from the Néel state to a spin liquid state may be realized in the J1-J2 model, or the anisotropic J1x-J1y-J2 model.

Yang Qi and Zheng-Cheng Gu

2014-06-19T23:59:59.000Z

Note: This page contains sample records for the topic "non-aqueous phase liquid" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Partial transient liquid phase diffusion bonding of Zircaloy-4 to stabilized austenitic stainless steel 321  

SciTech Connect

An innovative method was applied for bonding Zircaloy-4 to stabilized austenitic stainless steel 321 using an active titanium interlayer. Specimens were joined by a partial transient liquid phase diffusion bonding method in a vacuum furnace at different temperatures under 1 MPa dynamic pressure of contact. The influence of different bonding temperatures on the microstructure, microindentation hardness, joint strength and interlayer thickness has been studied. The diffusion of Fe, Cr, Ni and Zr has been investigated by scanning electron microscopy and energy dispersive spectroscopy elemental analyses. Results showed that control of the heating and cooling rate and 20 min soaking at 1223 K produces a perfect joint. However, solid-state diffusion of the melting point depressant elements into the joint metal causes the solid/liquid interface to advance until the joint is solidified. The tensile strength of all the bonded specimens was found around 480-670 MPa. Energy dispersive spectroscopy studies indicated that the melting occurred along the interface of the bonded specimens as a result of the transfer of atoms between the interlayer and the matrix during bonding. This technique provides a reliable method of bonding zirconium alloy to stainless steel.

Atabaki, M. Mazar, E-mail: m.mazaratabaki@gmail.com [Department of Materials Engineering, Faculty of Mechanical Engineering, University Technology Malaysia, 81310 (Malaysia); Hanzaei, A. Talebi [Department of Metallurgy and Materials Engineering, Faculty of Engineering, University of Tehran (Iran, Islamic Republic of)

2010-10-15T23:59:59.000Z

102

Liquid phase oxidation of thiophene compounds by tert-butyl hydroperoxide  

SciTech Connect

Oxidative instability problems in both shale and petroleum-derived middle distillate fuels are related to the presence of hydroperoxides. Although a good body of knowledge exists concerning the formation of peroxides in the liquid phase, relatively little is known about the reaction/decomposition pathways when other functional groups are present. One of the significant and undesirable problems is the formation of solid deposits which can plug nozzles and filters and coal heat exchanger surfaces. Deposit formation in fuels is triggered by autoxidation reactions and is closely associated with elemental oxygen and/or hydroperoxide concentration. This paper reports on the reaction between a primary autoxidation product, a hydroperoxide, and sulfur compounds of the type present in petroleum-derived middle distillate fuels. Specifically, we examine the t-butyl hydroperoxide oxidation of thiophene, 2, 5-dimethylthiophene, tetrahydrothiophene and benzothiophene in a deaerated model fuel, tetradecane, at 120{degree}C.

Mushrush, G.W.; Watkins, J.M. Jr.; Hazlett, R.N.; Hardy, D.R.; Eaton, H.G. (Naval Research Laboratory, Washington, DC (USA))

1987-08-01T23:59:59.000Z

103

Methods for sulfate removal in liquid-phase catalytic hydrothermal gasification of biomass  

SciTech Connect

Processing of wet biomass feedstock by liquid-phase catalytic hydrothermal gasification must address catalyst fouling and poisoning. One solution can involve heating the wet biomass with a heating unit to a pre-treatment temperature sufficient for organic constituents in the feedstock to decompose, for precipitates of inorganic wastes to form, for preheating the wet feedstock in preparation for subsequent removal of soluble sulfate contaminants, or combinations thereof. Processing further includes reacting the soluble sulfate contaminants with cations present in the feedstock material to yield a sulfate-containing precipitate and separating the inorganic precipitates and/or the sulfate-containing precipitates out of the wet feedstock. Having removed much of the inorganic wastes and the sulfate contaminants that can cause poisoning and fouling, the wet biomass feedstock can be exposed to the heterogenous catalyst for gasification.

Elliott, Douglas C; Oyler, James

2013-12-17T23:59:59.000Z

104

Methods for sulfate removal in liquid-phase catalytic hydrothermal gasification of biomass  

SciTech Connect

Processing of wet biomass feedstock by liquid-phase catalytic hydrothermal gasification must address catalyst fouling and poisoning. One solution can involve heating the wet biomass with a heating unit to a pre-treatment temperature sufficient for organic constituents in the feedstock to decompose, for precipitates of inorganic wastes to form, for preheating the wet feedstock in preparation for subsequent removal of soluble sulfate contaminants, or combinations thereof. Processing further includes reacting the soluble sulfate contaminants with cations present in the feedstock material to yield a sulfate-containing precipitate and separating the inorganic precipitates and/or the sulfate-containing precipitates out of the wet feedstock. Having removed much of the inorganic wastes and the sulfate contaminants that can cause poisoning and fouling, the wet biomass feedstock can be exposed to the heterogeneous catalyst for gasification.

Elliott, Douglas C; Oyler, James R

2014-11-04T23:59:59.000Z

105

Construction materials for reaction unit in the liquid-phase synthesis of propylene oxide  

SciTech Connect

The main components of the reaction medium in equipment for the synthesis of propylene oxide by liquid-phase oxidation of gaseous propylene with peracetic acid are propylene, peracetic acid, ethyl acetate, acetic acid, propylene oxide, carbon dioxide, oxygen, methane, and propylene glycol acetates. The operating conditions of the equipment and content of the main components of the medium are shown. Results are given for the investigation of the corrosion behavior of 12Kh18N10T, 10Kh17N13M2T, 08Kh22N6T, and 08Kh21N6M2T steels, AD0 and AD1 aluminum, and VT1-0 titanium. VSt3 carbon steel was tested for comparison.

Zaritskii, V.I.D.

1987-09-01T23:59:59.000Z

106

NONAQUEOUS-PHASE LIQUID CHARACTERIZATION AND POST-REMEDIATION VERIFICATION SAMPLING  

SciTech Connect

Light and dense nonaqueous-phase liquids (NAPLs) were identified in the surficial aquifer at the Northeast Site of the Young-Rainey Science, Technology, and Research Center located in Largo, Florida. The composition and the horizontal and vertical extent of NAPLs were determined using historical site information, analysis of ground water and soil boring data, and analysis of free product recovered from wells. Trichloroethene, dichloroethene, methylene chloride, toluene, and oils were identified as NAPLs. Calculations were conducted to determine NAPL remediation goals for both soil and ground water. Following completion of in situ thermal remediation activities at a 9,900-cubic-meter NAPL contamination area, a sampling program was implemented to verify the success of the remediation. The program consisted of using hot media sampling techniques to collect soil and ground water samples at randomly chosen locations in three sampling events during a 6- month period. Verification data indicate that the remediation was successful.

Tabor, Charles [S.M. Stoller Corporation; Juhlin, Randall [S.M. Stoller Corporation; Darr, Paul [S.M. Stoller Corporation; Caballero, Julian [S.M. Stoller Corporation; Daniel, Joseph [S.M. Stoller Corporation; Ingle, David [S.M. Stoller Corporation; none,

2004-05-01T23:59:59.000Z

107

Measurement of the birefringence induced in liquids by ultrasonic waves : application to the study of the isotropic phase of PAA  

E-Print Network (OSTI)

to the study of the isotropic phase of PAA near the transition point P. Martinoty and M. Bader Laboratoire d biréfringence induite par les ultrasons dans les liquides : les mesures effectuées dans la phase isotrope du PAA absorbants. Les résultats dans le PAA montrent que la quantité 0394n/~P, où 0394n est la biré- fringence

Paris-Sud XI, Université de

108

Ga-MCM-41 synthesis and catalytic activity in the liquid-phase isomerisation of ?-pinene  

Science Journals Connector (OSTI)

A procedure to synthesize Ga-MCM-41 materials, using gallium nitrate and tetraethyl orthosilicate (TEOS) as gallium and silica sources, respectively, is reported. Samples were synthesized with a silica/gallium ratio of 40, 30, 20 and 10 and subsequently characterised by XRD, N2 adsorption, SEM, DRIFT measurements and acid properties as surface acidity using pyridine (PY) and 2,6-dimethylpyridine (DMPY) as probe molecules, as well as, \\{DRIFTs\\} of absorbed pyridine in gas phase. Materials were tested in the liquid-phase-?-pinene isomerisation reaction. According to the literature, the isomerisation proceeds via two parallel and competing pathways, one yielding monocyclic products and the other yielding polycyclic products depending on the catalysts acid strength. Camphene and limonene were obtained as major products. Camphene and polycyclic products are formed in weak (Lewis acid sites) whereas stronger (Bronsted) acid sites resulted in limonene and monocyclic derivatives. Materials exhibited an interesting catalytic activity in terms of conversion and selectivity to camphene and limonene under mild reaction conditions (353 K). The highest conversion values (around 60–70%) were achieved after 1 h of reaction and further reaction times did not seem to increase, significantly, the materials activity.

Rafael Luque; Juan Manuel Campelo; Tomas David Conesa; Diego Luna; Jose Maria Marinas; Antonio Angel Romero

2007-01-01T23:59:59.000Z

109

Electronically smecticlike liquid-crystal phase in a nearly half-doped manganite  

SciTech Connect

We use neutron scattering to study the spin and charge-orbital ordering (CO-OO) in the nearly half-doped perovskite manganite Pr{sub 0.55}(Ca{sub 0.8}Sr{sub 0.2}){sub 0.45}MnO{sub 3} (PCSMO). On cooling from room temperature, PCSMO first enters into a CO-OO state below T{sub CO} and then becomes a CE-type long-range ordered antiferromagnet below T{sub N}. At temperatures above T{sub N} but below T{sub CO} (T{sub N}liquid-crystal-like texture with ferromagnetic (FM) quasi-long-range ordered one-dimensional zigzag chains weakly coupled antiferromagnetically. Such a magnetic smecticlike phase results directly from the spin-orbit interaction and demonstrates the presence of textured 'electronic soft' phases in doped Mott insulators.

Ye, F. [Center for Neutron Scattering, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831-6393 (United States); Fernandez-Baca, J.A. [Center for Neutron Scattering, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831-6393 (United States); Department of Physics and Astronomy, University of Tennessee, Knoxville, Tennessee 37996-1200 (United States); Dai Pengcheng [Department of Physics and Astronomy, University of Tennessee, Knoxville, Tennessee 37996-1200 (United States); Center for Neutron Scattering, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831-6393 (United States); Lynn, J.W. [NIST Center for Neutron Research, Gaithersburg, Maryland 20899 (United States); Kawano-Furukawa, H. [Department of Physics, Ochanomizu University, Bunkyo-ku, Tokyo 112-8610 (Japan); Yoshizawa, H. [Neutron Science Laboratory, ISSP, University of Tokyo, Tokai, Ibaraki, 319-1106 (Japan); Tomioka, Y. [Correlated Electron Research Center (CERC), Tsukuba 305-0046 (Japan); Tokura, Y. [Correlated Electron Research Center (CERC), Tsukuba 305-0046 (Japan); Department of Applied Physics, University of Tokyo, Tokyo 113-8656 (Japan)

2005-12-01T23:59:59.000Z

110

Freeze-out temperature and density in heavy-ion collisions at liquid-gas phase transition  

SciTech Connect

The study of properties of hot nuclei and the search for liquid-gas phase transition in nuclei have been the subjects of many investigations in recent decades. We present a short and limited review of the theoretical and experimental status of determining the temperature and density of the disassembling nucleus from ratios of the yields of emitted fragments.

Shlomo, Shalom [Cyclotron Institute, Texas A and M University, College Station, TX 77843 (United States)

2010-08-04T23:59:59.000Z

111

On the Liquid/Solid Phase Equilibria in the Al-Rich Corner of the Al-Si-Ti Ternary System  

E-Print Network (OSTI)

On the Liquid/Solid Phase Equilibria in the Al-Rich Corner of the Al-Si-Ti Ternary System O; published online February 5, 2014) The nature of liquid-solid phase equilibria in the Al-rich corner of the Al-Si-Ti system are determined by drawing three isothermal sections at 620, 680 and 727 °C

Paris-Sud XI, Université de

112

Commercial-Scale Demonstration of the Liquid Phase Methanol (LPMEOH(TM)) Process  

SciTech Connect

The Liquid Phase Methanol (LPMEOHTM) Demonstration Project at Kingsport, Tennessee, is a $213.7 million cooperative agreement between the U.S. Department of Energy (DOE) and Air Products Liquid Phase Conversion Company, L.P. (the Partnership). Air Products and Chemicals, Inc. (Air Products) and Eastman Chemical Company (Eastman) formed the Partnership to execute the Demonstration Project. The LPMEOIYM Process Demonstration Unit was built at a site located at the Eastman complex in Kingsport. During this quarter, comments from the DOE on the Topical Report "Economic Analysis - LPMEOHTM Process as an Add-on to IGCC for Coproduction" were received. A recommendation to continue with design verification testing for the coproduction of dimethyl ether (DIME) and methanol was made. DME design verification testing studies show the liquid phase DME (LPDME) process will have a significant economic advantage for the coproduction of DME for local markets. An LPDME catalyst system with reasonable long-term activity and stability is being developed. A recommendation document summarizing catalyst targets, experimental results, and the corresponding economics for a commercially successful LPDME catalyst was issued on 30 June 1997. The off-site, product-use test plan was updated in June of 1997. During this quarter, Acurex Environmental Corporation and Air Products screened proposals for this task by the likelihood of the projects to proceed and the timing for the initial methanol requirement. Eight sites from the list have met these criteria. The formal submission of the eight projects for review and concurrence by the DOE will be made during the next reporting period. The site paving and final painting were completed in May of 1997. Start-up activities were completed during the reporting period, and the initial methanol production from the demonstration unit occurred on 02 April 1997. The first extended stable operation at the nameplate capacity of 80,000 gallons per day (260 tons per day) took place on 06 April 1997. Pressure drop and resistance coefficient across the gas sparger at the bottom of the reactor increased over this initial operating period. The demonstration unit was shut down from 08 May -17 June 1997 as part of a scheduled complex outage for the Kingsport site. During this outage, the gas sparger was removed, cleaned, and reinstalled. After completion of other maintenance activities, the demonstration unit was restarted, and maintained stable operation through the remainder of the reporting period. Again, the gas sparger showed an increase in pressure drop and resistance since the restart, although not as rapidly as during the April-May operation. Fresh oil was introduced online for the first time to a new flush connection on the gas inlet line to the reactov the flush lowered the pressure drop by 1 psi. However, the effects were temporary, and the sparger resistance coefficient continued to increase. Additional flushing with both fresh oil and entrained slurry recovered in the cyclone and secondary oil knock-out drum will be attempted in order to stabilize the sparger resistance coefficient.

None

1997-06-30T23:59:59.000Z

113

Quantum phase transition between the Z2 spin liquid and valence bond crystals on a triangular lattice  

Science Journals Connector (OSTI)

We study the quantum phase transition between the Z2 spin liquid and valence bond solid (VBS) orders on a triangular lattice. With a fully isotropic triangular lattice, the transition from a columnar or resonating-plaquette VBS order can either be first order or there could be two transitions with an intermediate phase. If the transition splits into two, then the Z2 spin liquid will first experience a first-order q=3 Potts transition to a new nematic Z2 spin liquid that breaks the 2?/3 lattice rotation symmetry (but retain translation symmetry, unlike the VBS states). The second transition will then take this new nematic Z2 spin liquid to a columnar or resonating-plaquette VBS state through a second-orderthree-dimensional (3D) XY* transition. On a distorted triangular lattice, the degeneracy between some of the different columnar VBS orders is lifted, and the phase transition can reduce to a single 3D XY* transition.

Kevin Slagle and Cenke Xu

2014-03-21T23:59:59.000Z

114

Evaluating the phase equilibria of liquid water + natural gas mixtures using cubic equations of state with asymmetric mixing rules  

Science Journals Connector (OSTI)

Based on a previously developed liquid–liquid mixing rule we present a modified and robust mixing rule for accurate prediction of water content of natural gas mixtures and the natural gas solubility in liquid water phase. The non-density dependent mixing rule (NDD) and the new mixing rule are incorporated into the Peng–Robinson (PR), Soave–Redlich–Kwong (SRK), and Nasrifar–Bolland (NB) equations of state to investigate their accuracies in estimating the water content of the gas phase as well as the gas solubility in the aqueous phase. For each binary system water + hydrocarbon, water + carbon dioxide, water + hydrogen sulfide, and water + nitrogen, three binary interaction parameters are required to describe the gas–liquid water equilibria. In this work, experimental data from literature were used to tune the parameters. The results are in good agreement with experimental data, demonstrating the reliability of the new mixing rule and the thermodynamic approach used in this work.

P. Reshadi; Kh. Nasrifar; M. Moshfeghian

2011-01-01T23:59:59.000Z

115

Smectic-A and smectic-C phases and phase transitions in 8? S5 liquid-crystal-aerosil gels  

E-Print Network (OSTI)

High-resolution x-ray scattering studies of the nonpolar thermotropic liquid crystal 4-n-pentylphenylthiol-4?-n-octyloxybenzoate (8? S5) in aerosil gel nanonetworks reveal that the aerosil-induced disorder significantly ...

Garland, Carl W.

116

Improved resins and novel materials and methods for solid phase extraction and high performance liquid chromatography  

SciTech Connect

Solid-phase extraction (SPE) has grown to be one of the most widely used methods for isolation and preconcentration of a vast range of compounds from aqueous solutions. By modifying polymeric SPE resins with chelating functional groups, the selective uptake of metals was accomplished. The resin, along with adsorbed metals, was vaporized in the ICP and detection of the metals was then possible using either mass or emission spectroscopy. Drug analyses in biological fluids have received heightened attention as drug testing is on the increase both in sports and in the work environment. By using a direct-injection technique, biological fluids can be injected directly into the liquid chromatographic system with no pretreatment. A new surfactant, a sulfonated form of Brij-30 (Brij-S) is shown to prevent the uptake of serum proteins on commercial HPLC columns by forming a thin coating on the silica C18 surface. Excellent separations of eight or more drugs with a wide range of retention times were obtained. The separations had sharper peaks and lower retention times than similar separations performed with the surfactant sodium dodecylsulfate (SDS). Quantitative recovery of a number of drugs with limits of detection near 1 ppm with a 5 {micro}l injection volume were obtained. Finally, a method for solid-phase extraction in a syringe is introduced. The system greatly reduced the volume of solvent required to elute adsorbed analytes from the SPE bed while providing a semi-automated setup. SPE in a syringe consists of a very small bed of resin-loaded membrane packed into a GC or HPLC syringe. After extraction, elution was performed with just a few {micro}l of solvent. This small elution volume allowed injection of the eluent directly from the syringe into the chromatographic system, eliminating the handling problems associated with such small volumes.

Freeze, R.

1997-10-08T23:59:59.000Z

117

Laboratory Studies of Lead Removal from Liquid Scintillator in Preparation for KamLAND's Low Background Phase  

SciTech Connect

The removal of Radon induced Lead from liquid scintillator was extensively studied in preparation for KamLAND's low background phase. This work presents the results from laboratory experiments performed at the University of Alabama and their implications for KamLAND and future low background experiments using carbon based liquid scintillator. It was observed that distillation was the most effective purification procedure and that one must consider a non-polar and non-ionic component of Lead in order to reach the levels of radio-purity required for these new class of ultra-low background experiments.

Keefer, Gregory [Lawrence Livermore National Laboratory, Livermore, California 94550 (United States)

2011-04-27T23:59:59.000Z

118

Liquid-phase adsorption of organic compounds by granular activated carbon and activated carbon fibers  

SciTech Connect

Liquid-phase adsorption of organic compounds by granular activated carbon (GAC) and activated carbon fibers (ACFs) is investigated. Acetone, isopropyl alcohol (IPA), phenol, and tetrahydrofuran (THF) were employed as the model compounds for the present study. It is observed from the experimental results that adsorption of organic compounds by GAC and ACF is influenced by the BET (Brunauer-Emmett-Teller) surface area of adsorbent and the molecular weight, polarity, and solubility of the adsorbate. The adsorption characteristics of GAC and ACFs were found to differ rather significantly. In terms of the adsorption capacity of organic compounds, the time to reach equilibrium adsorption, and the time for complete desorption, ACFs have been observed to be considerably better than GAC. For the organic compounds tested here, the GAC adsorptions were shown to be represented well by the Langmuir isotherm while the ACF adsorption could be adequately described by the Langmuir or the Freundlich isotherm. Column adsorption tests indicated that the exhausted ACFs can be effectively regenerated by static in situ thermal desorption at 150 C, but the same regeneration conditions do not do as well for the exhausted GAC.

Lin, S.H.; Hsu, F.M. [Yuan Ze Inst. of Tech., Taoyuan (Taiwan, Province of China). Dept. of Chemical Engineering

1995-06-01T23:59:59.000Z

119

A single-phase model for liquid-feed \\{DMFCs\\} with non-Tafel kinetics  

Science Journals Connector (OSTI)

An isothermal single-phase 3D/1D model for liquid-feed direct methanol fuel cells (DMFC) is presented. Three-dimensional (3D) mass, momentum and species transport in the anode channels and gas diffusion layer is modeled using a commercial, finite-volume based, computational fluid dynamics (CFD) software complemented with user supplied subroutines. The 3D model is locally coupled to a one-dimensional (1D) model accounting for the electrochemical reactions in both the anode and the cathode, which provides a physically sound boundary condition for the velocity and methanol concentration fields at the anode gas diffusion layer/catalyst interface. The 1D model – comprising the membrane–electrode assembly, cathode gas diffusion layer, and cathode channel – assumes non-Tafel kinetics to describe the complex kinetics of the multi-step methanol oxidation reaction at the anode, and accounts for the mixed potential associated with methanol crossover, induced both by diffusion and electro-osmotic drag. Polarization curves computed for various methanol feed concentrations, temperatures, and methanol feed velocities show good agreement with recent experimental results. The spatial distribution of methanol in the anode channels, together with the distributions of current density, methanol crossover and fuel utilization at the anode catalyst layer, are also presented for different opperating conditions.

Marcos Vera

2007-01-01T23:59:59.000Z

120

The effect of a micro bubble dispersed gas phase on hydrogen isotope transport in liquid metals under nuclear irradiation  

E-Print Network (OSTI)

The present work intend to be a first step towards the understanding and quantification of the hydrogen isotope complex phenomena in liquid metals for nuclear technology. Liquid metals under nuclear irradiation in,e.g., breeding blankets of a nuclear fusion reactor would generate tritium which is to be extracted and recirculated as fuel. At the same time that tritium is bred, helium is also generated and may precipitate in the form of nano bubbles. Other liquid metal systems of a nuclear reactor involve hydrogen isotope absorption processes, e.g., tritium extraction system. Hence, hydrogen isotope absorption into gas bubbles modelling and control may have a capital importance regarding design, operation and safety. Here general models for hydrogen isotopes transport in liquid metal and absorption into gas phase, that do not depend on the mass transfer limiting regime, are exposed and implemented in OpenFOAMR CFD tool for 0D to 3D simulations. Results for a 0D case show the impact of a He dispersed phase of na...

Fradera, Jorge

2013-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "non-aqueous phase liquid" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Commercial-Scale Demonstration of the Liquid Phase Methanol (LPMEOH) Process  

SciTech Connect

he Liquid Phase Methanol (LPMEOW) Demonstration Project at Kingsport Tennessee, is a $213.7 million cooperative agreement between the U.S. Department of Energy (DOE) and Air Products Liquid Phase Conversion Company, L.P. (the Partnership) to produce methanol from coal-derived synthesis gas (syngas). Air Products and Chemicals, Inc. (Air Products) and Eastman Chemical Company (Eastman) formed the Partnership to execute the Demonstration Project. The LPMEOEP Process Demonstration Unit was built at a site located at the Eastman coal-to-chemicals complex in Kingsport. The LPMEOHW Demonstration Facility completed its first year of operation on 02 April 1998. The LPMEOW Demonstration Facility also completed the longest continuous operating run (65 days) on 21 April 1998. Catalyst activity, as defined by the ratio of the rate constant at any point in time to the rate constant for freshly reduced catalyst (as determined in the laboratory autoclave), was monitored throughout the reporting period. During a six-week test at a reactor temperature of 225oC and Balanced Gas flowrate of 700 KSCFH, the rate of decline in catalyst activity was steady at 0.29-0.36% per day. During a second one-month test at a reactor temperature of 220oC and a Balanced Gas flowrate of 550-600 KSCFH, the rate of decline in catalyst activity was 0.4% per day, which matched the pefiorrnance at 225"C, as well as the 4-month proof-of-concept run at the LaPorte AFDU in 1988/89. Beginning on 08 May 1998, the LPMEOW Reactor temperature was increased to 235oC, which was the operating temperature tier the December 1997 restart with the fresh charge of catalyst (50'Yo of design loading). The flowrate of the primary syngas feed stream (Balanced Gas) was also increased to 700-750 KSCFH. During two stable operating periods between 08 May and 09 June 1998, the average catalyst deactivation rate was 0.8% per day. Due to the scatter of the statistical analysis of the results, this test was extended to better quanti& the catalyst aging behavior. During the reporting perio~ two batches of fresh catalyst were activated and transferred to the reactor (on 02 April and 20 June 1998). The weight of catalyst in the LPMEOW Reactor has reached 80% of the design value. At the end of the reporting period, a step-change in the pressure-drop profile within the LPMEOW Reactor and an increase in the pressure of the steam system which provides cooling to the LPMEOW Reactor were observed. No change in the calculated activity of the catalyst was detected during either of these transients. These parameters will be monitored closely for any additional changes.

None

1998-12-21T23:59:59.000Z

122

The influence of transition metal ions on the catalytic performance of Ru particles during the liquid phase hydrogenation of benzene to cyclohexene  

Science Journals Connector (OSTI)

The influence of some transition metal ions including Fe2+, Ni2+, Cr3+, Mn2+, Zn2+, Cd2+...on the catalytic performance of Ru particles during the liquid phase partial hydrogenation of benzene to cyclohexene was ...

Yixin Qu; Chengxuan Fang; Chengyang Qian…

2014-04-01T23:59:59.000Z

123

Toward new solid and liquid phase systems for the containment, transport and delivery of  

E-Print Network (OSTI)

Storage Tube Trailer Liquid H2 Truck H2 Pipeline Multi-vehicle filling stations Feedstock: N. gas, Coal, Biomass Pet. Coke, Resids. Future: Carbon sequestration Storage: Underground well? Output: Depends

124

Liquid phase epitaxial growth and characterization of germanium far infrared blocked impurity band detectors  

SciTech Connect

Germanium Blocked Impurity Band (BIB) detectors require a high purity blocking layer (< 10{sup 13} cm{sup -3}) approximately 1 mm thick grown on a heavily doped active layer ({approx} 10{sup 16} cm{sup -3}) approximately 20 mm thick. Epilayers were grown using liquid phase epitaxy (LPE) of germanium out of lead solution. The effects of the crystallographic orientation of the germanium substrate on LPE growth modes were explored. Growth was studied on substrates oriented by Laue x-ray diffraction between 0.02{sup o} and 10{sup o} from the {l_brace}111{r_brace} toward the {l_brace}100{r_brace}. Terrace growth was observed, with increasing terrace height for larger misorientation angles. It was found that the purity of the blocking layer was limited by the presence of phosphorus in the lead solvent. Unintentionally doped Ge layers contained {approx}10{sup 15} cm{sup -3} phosphorus as determined by Hall effect measurements and Photothermal Ionization Spectroscopy (PTIS). Lead purification by vacuum distillation and dilution reduced the phosphorus concentration in the layers to {approx} 10{sup 14} cm{sup -3} but further reduction was not observed with successive distillation runs. The graphite distillation and growth components as an additional phosphorus source cannot be ruled out. Antimony ({approx}10{sup 16} cm{sup -3}) was used as a dopant for the active BIB layer. A reduction in the donor binding energy due to impurity banding was observed by variable temperature Hall effect measurements. A BIB detector fabricated from an Sb-doped Ge layer grown on a pure substrate showed a low energy photoconductive onset ({approx}6 meV). Spreading resistance measurements on doped layers revealed a nonuniform dopant distribution with Sb pile-up at the layer surface, which must be removed by chemomechanical polishing. Sb diffusion into the pure substrate was observed by Secondary Ion Mass Spectroscopy (SIMS) for epilayers grown at 650 C. The Sb concentration at the interface dropped by an order of magnitude over {approx} 1.5 {micro}m. Layers grown at 550 C did not show significant Sb diffusion. Sn doped In{sub 2}O{sub 3} (ITO) was studied for use in far infrared transparent low temperature contacts for BIB arrays. It was found that {approx}100 nm of ITO deposited on Ge remains electrically conducting at 4 K and is {approx}90% transparent in the far infrared. ITO should be suitable for passivating contacts to Ge BIB arrays.

Bandaru, Jordana

2001-05-12T23:59:59.000Z

125

Characterization of aqueous two phase systems by combining lab-on-a-chip technology with robotic liquid handling stations  

Science Journals Connector (OSTI)

Abstract Over the last decade, the use of design of experiment approaches in combination with fully automated high throughput (HTP) compatible screenings supported by robotic liquid handling stations (LHS), adequate fast analytics and data processing has been developed in the biopharmaceutical industry into a strategy of high throughput process development (HTPD) resulting in lower experimental effort, sample reduction and an overall higher degree of process optimization. Apart from HTP technologies, lab-on-a-chip technology has experienced an enormous growth in the last years and allows further reduction of sample consumption. A combination of LHS and lab-on-a-chip technology is highly desirable and realized in the present work to characterize aqueous two phase systems with respect to tie lines. In particular, a new high throughput compatible approach for the characterization of aqueous two phase systems regarding tie lines by exploiting differences in phase densities is presented. Densities were measured by a standalone micro fluidic liquid density sensor, which was integrated into a liquid handling station by means of a developed generic Tip2World interface. This combination of liquid handling stations and lab-on-a-chip technology enables fast, fully automated, and highly accurate density measurements. The presented approach was used to determine the phase diagram of \\{ATPSs\\} composed of potassium phosphate (pH 7) and polyethylene glycol (PEG) with a molecular weight of 300, 400, 600 and 1000 Da respectively in the presence and in the absence of 3% (w/w) sodium chloride. Considering the whole ATPS characterization process, two complete \\{ATPSs\\} could be characterized within 24 h, including four runs per ATPS for binodal curve determination (less than 45 min/run), and tie line determination (less than 45 min/run for ATPS preparation and 8 h for density determination), which can be performed fully automated over night without requiring man power. The presented methodology provides a cost, time and material effective approach for characterization of ATPS phase diagram on base on highly accurate and comprehensive data. By this means the derived data opens the door for a more detailed description of ATPS towards generating mechanistic based models, since molecular approaches such as MD simulations or molecular descriptions along the line of QSAR heavily rely on accurate and comprehensive data.

Sven Amrhein; Marie-Luise Schwab; Marc Hoffmann; Jürgen Hubbuch

2014-01-01T23:59:59.000Z

126

Thermophysical and Phase Properties of Polymer/Liquid Crystal Systems: Theoretical Aspects and Experimental Examples  

Science Journals Connector (OSTI)

Phase diagrams exhibit a peculiar teapot configuration with a variety of domains. ... However, the teapot configuration is no longer observed. ... A teapot phase diagram was obtained in which an upper crit. ...

Re?da Benmouna; Mustapha Benmouna

2010-03-23T23:59:59.000Z

127

Liquid-phase plasma synthesis of silicon quantum dots embedded in carbon matrix for lithium battery anodes  

SciTech Connect

Graphical abstract: - Highlights: • Silicon quantum dots embedded in carbon matrix (SiQDs/C) were fabricated. • SiQDs/C exhibits excellent battery performance as anode materials with high specific capacity. • The good performance was attributed to the marriage of small sized SiQDs and carbon. - Abstract: Silicon quantum dots embedded in carbon matrix (SiQDs/C) nanocomposites were prepared by a novel liquid-phase plasma assisted synthetic process. The SiQDs/C nanocomposites were demonstrated to show high specific capacity, good cycling life and high coulmbic efficiency as anode materials for lithium-ion battery.

Wei, Ying [Institute of Functional Nano and Soft Materials (FUNSOM) and Jiangsu Key Laboratory for Carbon-Based Functional Materials and Devices, Soochow University, Suzhou (China); College of Chemistry and Chemical Engineering, Bohai University, Jinzhou 121000 (China); Yu, Hang; Li, Haitao; Ming, Hai; Pan, Keming; Huang, Hui [Institute of Functional Nano and Soft Materials (FUNSOM) and Jiangsu Key Laboratory for Carbon-Based Functional Materials and Devices, Soochow University, Suzhou (China); Liu, Yang, E-mail: yangl@suda.edu.cn [Institute of Functional Nano and Soft Materials (FUNSOM) and Jiangsu Key Laboratory for Carbon-Based Functional Materials and Devices, Soochow University, Suzhou (China); Kang, Zhenhui, E-mail: zhkang@suda.edu.cn [Institute of Functional Nano and Soft Materials (FUNSOM) and Jiangsu Key Laboratory for Carbon-Based Functional Materials and Devices, Soochow University, Suzhou (China)

2013-10-15T23:59:59.000Z

128

Determination of liquid and solid phase composition in partially frozen middle distillate fuels  

SciTech Connect

One of the tasks of the United States Navy Mobility Fuels program at the Naval Research Laboratory is to determine the effect of composition on the freezing properties of liquid fuels. The combination of requirements for ship and jet aircraft fuels of a low freezing point (to permit cold temperature operations around the world) and a flash point minimum (to reduce the hazard of storage and transport of liquid fuels on board ship) leads to opposing compositional needs. This is because many components of a fuel that tend to lower the freezing point (small hydrocarbons with higher vapor pressures) will also reduce the flash point. Because of these constraints, it is not always practical to produce fuels meeting these requirements from available crudes. This limits the amount of crudes and hence the amount of JP-5, the Navy fuel for carrier based aircraft, which can be produced from ''a barrel of crude.'' With increased knowledge and understanding of the components that first crystallize out of a cold fuel, it may be possible to modify refining techniques to increase the yield of Navy liquid fuels per barrel of crude without compromising either the freezing point or the flash point restrictions. This paper deals with the method used to separate the liquid filtrate from the precipitate in fuels cooled to predetermined temperatures below their freezing points, the method of analyzing the fuel and fuel fractions, and the results obtained from a study of one particular jet fuel.

Van Winkle, T.L.; Affens, W.A.; Beal, E.J.; Mushrush, G.W.; Hazlett, R.N.; DeGuzman, J.

1986-04-01T23:59:59.000Z

129

Static structure factor of a suspension of charge-stabilized colloids: Application to liquid-glass transition phase diagram and to micellar solution  

E-Print Network (OSTI)

-glass transition phase diagram and to micellar solution S. K. Lai, J. L. Wang, and G. F. Wang Department of Physics approximately. We contrast the liquid-glass transition phase boundary determined from the latter model approximation MSA . For point-like small ions counterions and electrolyte , this so-called primitive model PM

130

A High-Yield, Liquid-Phase Approach for the Partial Oxidation of Methane to Methanol using SO3 as the Oxidant  

E-Print Network (OSTI)

approach for producing methanol from methane in a three-step, liquid phase process is reported is hydrolyzed in the presence of an organic solvent, to produce an organic phase con- taining methanol the facile separation of methanol. Con- centrated sulfuric acid is produced as a by-product, which can either

Bell, Alexis T.

131

Energy density and volume expansion in solid-liquid phase change, for energy applications.  

E-Print Network (OSTI)

?? Phase change materials (PCMs) have long been studied as thermal energy storage media. However, the Swedish company, Exencotech AB, reaching beyond this usual scope… (more)

Pan, Ruijun

2013-01-01T23:59:59.000Z

132

Compact, Light-Weight, Single-Phase, Liquid-Cooled Cold Plate  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Future 4 RelevanceObjectives * Overall Objective - Develop and demonstrate inverter plastic heat exchanger based on forced convective single-phase jets in conjunction with...

133

Silica, Hybrid Silica, Hydride Silica and Non-Silica Stationary Phases for Liquid Chromatography  

Science Journals Connector (OSTI)

......microm was named HPLC. The price one had to pay was a high pressure...Ascentis Express C18, Acquity Ethylene Bridged Hybrid (BEH). and...the shape of their peaks on ethylene hybrid stationary phase under...contrast to what is observed for ethylene hybrid stationary phases in......

Endler M. Borges

2014-09-01T23:59:59.000Z

134

Spin states of para-water and ortho-water molecule in gas and liquid phases  

E-Print Network (OSTI)

Spin degrees of freedom of water molecule in gas and liquid state were investigated in order to provide a reasonable answer about the unsolved problem of a long-term behavior of water spin isomers. The approach used involves an assumption that molecules change their spin state from a pure state to a mixed one when they interact with some sorts of adsorbent surface. Some models and conceptions of the quantum information processing were used.

V. K. Konyukhov

2009-09-23T23:59:59.000Z

135

Three-Phase Vapor?Liquid?Liquid Equilibria for Methane + n-Octane + Monoethylene Glycol + Water at Pressures from (3.1 to 15.0) MPa and Temperatures from (281 to 363) K  

Science Journals Connector (OSTI)

There are several commercial processes available for the dehydration of gas, such as the use of liquid or solid desiccants and expansion refrigeration. ... The gaseous part of the liquid samples, and the gas phase samples direct from the equilibrium cell, were expanded into a series of evacuated vessels of known volume from which the total amount of substance was determined from the perfect gas equation using the measured low-pressure PVT data. ... To predict the losses of MEG in processes for the dehydration of natural gas, the concentrations of MEG in the vapor phase are of interest to the gas industry. ...

Stanley J. Ashcroft; Gerd Brunner; Hansjörg Vollmer; Christopher W. Sweeney

2009-03-06T23:59:59.000Z

136

Surface tension and vapor-liquid phase coexistence of confined square-well fluid  

E-Print Network (OSTI)

,4 Gibbs-Duhem integration GDI ,5 and N-P-T +test particle.6­8 Panagiotopoulos used GEMC to obtain, Sarkisov and Monson used GDI to get the phase behavior in a disordered porous structure,10 and Forsman

Singh, Jayant K.

137

Reverse phase high performance liquid chromatograph for analysis of casein phosphopeptides  

E-Print Network (OSTI)

phosphopeptides. Initially, sodium casemate was enzymatically digested with trypsin at pH 8.0 for 24 hours. Following a calcium precipitation, preliminary purification was achieved using a reverse phase C-3 (containing propyl hydrocarbons attached to the silica...

McKee, Shelly R.

1994-01-01T23:59:59.000Z

138

Phase behavior of the liquid crystal 8CB in a silica aerogel  

Science Journals Connector (OSTI)

Light scattering and precision calorimetry show that the nematic ordering of octylcyanobiphenyl (8CB) filling the connected network of pores of a silica aerogel does not occur via the first-order phase transition characteristic of the bulk. Rather, ordering is continuous with an orientational correlation length never increasing beyond the aerogel pore size. The heat-capacity anomly of the second-order nematic–smectic-A phase transition seen in the bulk is absent or greatly broadened in the aerogel.

Tommaso Bellini; Noel A. Clark; Chris D. Muzny; Lei Wu; Carl W. Garland; Dale W. Schaefer; Bernard J. Oliver

1992-08-03T23:59:59.000Z

139

Commercial-scale demonstration of the Liquid Phase Methanol (LPMEOH{trademark}) process. Technical progress report number 9, July 1--September 30, 1996  

SciTech Connect

The Liquid Phase Methanol (LPMEOH{trademark}) Demonstration Project at Kingsport, Tennessee, is a $213.7 million cooperative agreement between the US Department of Energy (DOE) and Air Products Liquid Phase Conversion Company, L.P. (the Partnership). The LPMEOH{trademark} Process Demonstration Unit is being built at a site located at the Eastman Chemical Company (Eastman) complex in Kingsport. The project involves the construction of an 80,000 gallons per day (260 tons per day (TPD)) methanol unit utilizing coal-derived synthesis gas from Eastman`s integrated coal gasification facility. The new equipment consists of synthesis gas feed preparation and compression facilities, the liquid phase reactor and auxiliaries, product distillation facilities, and utilities. This liquid phase process suspends fine catalyst particles in an inert liquid, forming a slurry. The slurry dissipates the heat of the chemical reaction away from the catalyst surface, protecting the catalyst and allowing the methanol synthesis reaction to proceed at higher rates. At the Eastman complex, the technology is being integrated with existing coal-gasifiers.

NONE

1997-06-06T23:59:59.000Z

140

Liquid crystal phase transitions in suspensions of mineral colloids: new life from old roots  

Science Journals Connector (OSTI)

...and plates were performed by Camp Allen [73] as shown in figure-5...may conclude that, almost a century after their discovery, MCLCs...with L/T=10. Adapted from Camp Allen-[73]. 1997, American...PhysRevLett.45.1000 ) 73 Camp, PJ , and MP Allen. 1997 Phase...

2013-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "non-aqueous phase liquid" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

A lattice Boltzmann study of phase separation in liquid-vapor systems with gravity  

E-Print Network (OSTI)

Phase separation of a two-dimensional van der Waals fluid subject to a gravitational force is studied by numerical simulations based on lattice Boltzmann methods (LBM) implemented with a finite difference scheme. A growth exponent $\\alpha=1$ is measured in the direction of the external force.

A. Cristea; G. Gonnella; A. Lamura; V. Sofonea

2009-07-16T23:59:59.000Z

142

On preferential diffusion of binary component liquid droplets evaporating in a two-phase mixing layer  

E-Print Network (OSTI)

, momentum, energy and species transport equations governing the carrier gas phase. High resolution can be an important factor in combustion modeling, and can be the controlling factor for energy conversion rates. With the advent of modern high speed computers, high fidelity numerical simulations

Miller, Richard S.

143

Silica, Hybrid Silica, Hydride Silica and Non-Silica Stationary Phases for Liquid Chromatography  

Science Journals Connector (OSTI)

......Marcon G., Tolon-Becerra A. Inputs of heavy metals due to agrochemical use in tobacco fields in Brazil's Southern Region. Environmental...chromatography influence of sorbent character, mobile phase composition, and pH on retention of basic compounds. Journal of Chromatography......

Endler M. Borges

2014-09-01T23:59:59.000Z

144

Electric-pulse discharge as a novel technique to synthesize {beta}-SiC nano-crystallites from liquid-phase organic precursors  

SciTech Connect

{beta}-SiC nano-crystallites have been prepared by electric pulses discharged in liquid-phase organic precursors. The composition and crystal structure of the products were characterized by X-ray diffraction, Raman spectroscopy, field emission scanning electronic and transmission electron microscopy. Transmission electron microscopy showed that the sample synthesized from the precursor (hexamethyl disilane) is composed of uniform grains with only 8 nm, while the one synthesize from the other precursor (dimethyl silicone oil) is of better crystalline structure with average grain size 22 nm, which may be attributed to discharge in liquid-phase source and short discharge intervals.

Du Kai [National Laboratory of Superhard Materials, Jilin University, Changchun 130012, Jilin (China); Yang Haibin [National Laboratory of Superhard Materials, Jilin University, Changchun 130012, Jilin (China); Institute of Materials Science and Engineering, Henan Polytechnic University, Jiaozuo 454003, Henan (China)], E-mail: chinawhirl@hotmail.com; Wei Ronghui; Li Minghui; Yu Qingjiang; Fu Wuyou; Yang Nan; Zhu Hongyang; Zeng Yi [National Laboratory of Superhard Materials, Jilin University, Changchun 130012, Jilin (China)

2008-01-08T23:59:59.000Z

145

Process for CO2 Capture Using Ionic Liquid That Exhibits Phase Change  

Science Journals Connector (OSTI)

An expander turbine powered by the CO2-lean flue gas leaving the absorber recovers 43% of the power expended by the flue gas compressor. ... The authors appreciate the close collaboration with faculty at the University of Notre Dame, including Professors Joan Brennecke, Mark McCready, Mark Stadtherr, Bill Schneider, and Ed Maginn. ... The heat transfer within the adsorbent beds can be managed in situ, using thermal energy storage material: a phase change materials (PCM) for example. ...

Ronald S. Eisinger; George E. Keller; II

2014-10-27T23:59:59.000Z

146

Growth and characterization of liquid phase epitaxial GaP layers  

E-Print Network (OSTI)

Inside a High-vacuum Chamber . . . . . . . . . . . . . . . . . . . . . . . 3 3. Cross Section of Multi-well Sliding Graphite Boat. Solubility Curve of P in Ga Melt 5. Apparatus of LPE Growth by Tipping Method. 10 Dipping System Schematic for LPE... Growth. 10 7. Sliding Boat System Block Diagram for LPE Growth 12 Temperature Profile Along the Graphite Boat. 13 9. Disassembled Graphite Boat for Multi-layer LPE Growth. . . 14 10. Ga-P Phase Diagram 17 Solution Cooling Procedure for Three...

Kao, Yung-Chung

2012-06-07T23:59:59.000Z

147

DESIGN AND DEVELOPMENT OF GAS-LIQUID CYLINDRICAL CYCLONE COMPACT SEPARATORS FOR THREE-PHASE FLOW  

SciTech Connect

This report presents a brief overview of the activities and tasks accomplished during the second half year (April 1, 2001-September 30, 2001) of the fourth project year budget period (October 1, 2000-September 30, 2001). An executive summary is presented initially followed by the tasks of the current budget period. Then, detailed description of the experimental and modeling investigations are presented. Subsequently, the technical and scientific results of the activities of this project period are presented with some discussions. The findings of this investigation are summarized in the ''Conclusions'' section followed by relevant references. The fourth project year activities are divided into three main parts, which are carried out in parallel. The first part is continuation of the experimental program that includes a study of the oil/water two-phase behavior at high pressures and control system development for the three-phase GLCC{copyright}. This investigation will be eventually extended for three-phase flow. The second part consists of the development of a simplified mechanistic model incorporating the experimental results and behavior of dispersion of oil in water and water in oil. This will provide an insight into the hydrodynamic flow behavior and serve as the design tool for the industry. Although useful for sizing GLCC{copyright} for proven applications, the mechanistic model will not provide detailed hydrodynamic flow behavior information needed to screen new geometric variations or to study the effect of fluid property variations. Therefore, in the third part, the more rigorous approach of computational fluid dynamics (CFD) will be utilized. Multidimensional multiphase flow simulation at high pressures and for real crude conditions will provide much greater depth into the understanding of the physical phenomena and the mathematical analysis of three-phase GLCC{copyright} design and performance.

Dr. Ram S. Mohan; Dr. Ovadia Shoham

2001-10-30T23:59:59.000Z

148

DESIGN AND DEVELOPMENT OF GAS-LIQUID CYLINDRICAL CYCLONE COMPACT SEPARATORS FOR THREE-PHASE FLOW  

SciTech Connect

This report presents a brief overview of the activities and tasks accomplished during the first half year (October 1, 2000-March 31, 2001) of the fourth project year budget period (October 1, 2000-September 30, 2001). An executive summary is presented initially followed by the tasks of the current budget period. Then, detailed description of the experimental and modeling investigations are presented. Subsequently, the technical and scientific results of the activities of this project period are presented with some discussions. The findings of this investigation are summarized in the ''Conclusions'' section followed by relevant references. The fourth project year activities are divided into three main parts, which are carried out in parallel. The first part is continuation of the experimental program that includes a study of the oil/water two-phase behavior at high pressures and control system development for the three-phase GLCC{copyright}. This investigation will be eventually extended for three-phase flow. The second part consists of the development of a simplified mechanistic model incorporating the experimental results and behavior of dispersion of oil in water and water in oil. This will provide an insight into the hydrodynamic flow behavior and serve as the design tool for the industry. Although useful for sizing GLCC{copyright} for proven applications, the mechanistic model will not provide detailed hydrodynamic flow behavior information needed to screen new geometric variations or to study the effect of fluid property variations. Therefore, in the third part, the more rigorous approach of computational fluid dynamics (CFD) will be utilized. Multidimensional multiphase flow simulation at high pressures and for real crude conditions will provide much greater depth into the understanding of the physical phenomena and the mathematical analysis of three-phase GLCC{copyright} design and performance.

Dr. Ram S. Mohan; Dr. Ovadia Shoham

2001-04-30T23:59:59.000Z

149

Numerical Simulation of Liquid-Solid, Solid-Liquid Phase Change Using Finite Element Method in h,p,k Framework with Space-Time Variationally Consistent Integral Forms  

E-Print Network (OSTI)

: cp@T@t r (krTs) = 0 8(x;t) 2 sxt = sx t = sx (0; ) (2.1) Liquid Phase: cp@T@t r (krTl) = 0 8(x;t) 2 lxt = lx t = lx (0; ) (2.2) At the interface: Lfvn = [( krTs) ( krTl)] n 8(x;t) 2 x;t = x t (2.3) 10 in which sx and lx are solid... and liquid spatial domains, x(t) = sxT lx is the interface between the two phases, Lf is the latent heat of fusion,n is the unit exterior normal from the solid phase at the interface, and vn is the normal velocity of the interface. Subscripts s and l...

Truex, Michael

2010-07-21T23:59:59.000Z

150

An important recenttechnologicaldevelopmentin commercialF-T conversionis "liquid-phase" synthesis. In a liquid phasereactor,the feedgasis bubbled througha heavyoil (e.g.,the waxy  

E-Print Network (OSTI)

#12;,,- -- An important recenttechnologicaldevelopmentin commercialF-T conversionis "liquidF- T liquids) in which catalystparticlesaresuspended.The vigorousmixing, the intimate gas(Tijm et al., 1997). 2.2. F-T conversion of coal The maindifference betweena processfor producing F

151

Modeling Single-Phase and Boiling Liquid Jet Impingement Cooling in Power Electronics  

SciTech Connect

Jet impingement has been an attractive cooling option in a number of industries over the past few decades. Over the past 15 years, jet impingement has been explored as a cooling option in microelectronics. Recently, interest has been expressed by the automotive industry in exploring jet impingement for cooling power electronics components. This technical report explores, from a modeling perspective, both single-phase and boiling jet impingement cooling in power electronics, primarily from a heat transfer viewpoint. The discussion is from the viewpoint of the cooling of IGBTs (insulated-gate bipolar transistors), which are found in hybrid automobile inverters.

Narumanchi, S. V. J.; Hassani, V.; Bharathan, D.

2005-12-01T23:59:59.000Z

152

Plasma Resonance and Remaining Josephson Coupling in the “Decoupled Vortex Liquid Phase” in Layered Superconductors  

Science Journals Connector (OSTI)

We relate the frequency of the Josephson plasma resonance in layered superconductors with the frequency dependent superconducting response. We demonstrate that the sharp resonance can persist even when the global superconducting coherence is broken provided the resonance frequency is larger than the frequency of interlayer phase slips. In this situation the plasma frequency is determined by the average Josephson energy, which can be calculated using the high temperature expansion. We also find the temperature dependence of the average Josephson energy from the Monte Carlo simulations and determine the applicability region of the high temperature expansion.

A. E. Koshelev

1996-10-28T23:59:59.000Z

153

Pore-scale simulation of liquid CO2 displacement of water using a two-phase lattice Boltzmann model  

SciTech Connect

A lattice Boltzmann color-fluid model, which was recently proposed by Liu et al. [H. Liu, A.J. Valocchi, and Q. Kang. Three-dimensional lattice Boltzmann model for immiscible two-phase flow simulations. Phys. Rev. E, 85:046309, 2012.] based on a concept of continuum surface force, is improved to simulate immiscible two-phase flows in porous media. The new improvements allow the model to account for different kinematic viscosities of both fluids and to model fluid-solid interactions. The capability and accuracy of this model is first validated by two benchmark tests: a layered two-phase flow with a viscosity ratio, and a dynamic capillary intrusion. This model is then used to simulate liquid CO2 (LCO2) displacing water in a dual-permeability pore network. The extent and behavior of LCO2 preferential flow (i.e., fingering) is found to depend on the capillary number (Ca), and three different displacement patterns observed in previous micromodel experiments are reproduced. The predicted variation of LCO2 saturation with Ca, as well as variation of specific interfacial length with LCO2 saturation, are both in good agreement with the experimental observations. To understand the effect of heterogeneity on pore-scale displacement, we also simulate LCO2 displacing water in a randomly heterogeneous pore network, which has the same size and porosity as the dual-permeability pore network. In comparison to the dual-permeability case, the transition from capillary fingering to viscous fingering occurs at a higher Ca, and LCO2 saturation is higher at low Ca but lower at high Ca. In either pore network, the LCO2-water specific interfacial length is found to obey a power-law dependence on LCO2 saturation.

Liu, Haihu; Valocchi, Albert J.; Werth, Charles J.; Kang, Oinjun; Oostrom, Martinus

2014-11-01T23:59:59.000Z

154

High-Pressure Phase Equilibria of Ionic Liquids and Compressed Gases for Applications in Reactions and Absorption Refrigeration  

E-Print Network (OSTI)

of high-melting solids not liquids at processing conditions. Coupling ionic liquids with compressed gases systems may overcome most of these difficulties for their applications in separations, reactions, materials processing and engineering applications...

Ren, Wei

2009-12-29T23:59:59.000Z

155

The conversion of natural gas to liquid fuels using the Sasol Slurry Phase Distillate Process  

SciTech Connect

The natural gas and energy industries have long sought an economically attractive means of converting remote gas reserves into transportable products, such as fuels or petrochemicals. Applicable gas sources include: undeveloped gas fields in locations so remote that pipeline construction is prohibitively expensive and associated gas from oil wells that is either flared, which is becoming environmentally unacceptable in many parts of the world, or reinjected, which is costly. Projects which have been developed to exploit such feeds typically have converted the gas into one of the following: (1) liquefied natural gas (LNG)--the process plants for LNG production are expensive, need to be very large to be economically viable, have costly dedicated shipping requirements, and suffer from a limited market concentrated in few countries; (2) methanol--the market for petrochemical feedstock methanol is limited, for use as a fuel, further downstream processing is needed, for example in a methyl tertiary butyl ether (MTBE) or methanol to gasoline (MTG) unit. Clearly, there is a need for an alternative that produces high quality fuels or value added products that can be transported to far-off markets, while yielding an attractive return on the developers` investment. The Sasol Slurry Phase Distillate Process will fulfill this need.

Silverman, R.W. [Raytheon Engineers and Constructors, Cambridge, MA (United States); Hill, C.R. [Sastech, Johannesburg (South Africa)

1997-12-31T23:59:59.000Z

156

The effect of TDC temperature and density on the liquid-phase fuel penetration in a D.I. Diesel engine  

SciTech Connect

A parametric study of the liquid-phase fuel penetration of evaporating Diesel fuel jets has been conducted in a directinjection Diesel engine using laser elastic-scatter imaging. The experiments were conducted in an optically accessible Diesel engine of the ``heavy-duty`` size class at a representative medium speed (1200 rpm) operating condition. The density and temperature at TDC were varied systematically by adjusting the intake temperature and pressure. At all operating conditions the measurements show that initially the liquid fuel penetrates almost linearly with increasing crank angle until reaching a maximum length. Then, the liquid-fuel penetration length remains fairly constant although fuel injection continues. At a TDC density of 16.6 kg/m{sup 3} and a temperature of about 1000 K the maximum penetration length is approximately 23 mm. However, it varies significantly as TDC conditions are changed, with the liquid-length being less at higher temperatures and at higher densities. The corresponding apparent heat release rate plots are presented and the results of the liquid-phase fuel penetration are discussed with respect to the ignition delay and premixed bum fraction.

Espey, C. [Daimler-Benz AG, Stuttgart (Germany); Dec, J.E. [Sandia National Labs., Albuquerque, NM (United States)

1995-12-01T23:59:59.000Z

157

Mass Transfer of Polynuclear Aromatic Hydrocarbons from  

E-Print Network (OSTI)

of the individual components of four synthetic dense non-aqueous phase liquid (DNAPL) mixtures into the aqueous hydrocarbons (PAHs), were designed to serve as models for coal tars and creosotes. The reactor employed (PAHs) are often present in the environment as components of such dense non- aqueous phase liquids

Peters, Catherine A.

158

Order-parameter-aided temperature-accelerated sampling for the exploration of crystal polymorphism and solid-liquid phase transitions  

SciTech Connect

The problem of predicting polymorphism in atomic and molecular crystals constitutes a significant challenge both experimentally and theoretically. From the theoretical viewpoint, polymorphism prediction falls into the general class of problems characterized by an underlying rough energy landscape, and consequently, free energy based enhanced sampling approaches can be brought to bear on the problem. In this paper, we build on a scheme previously introduced by two of the authors in which the lengths and angles of the supercell are targeted for enhanced sampling via temperature accelerated adiabatic free energy dynamics [T. Q. Yu and M. E. Tuckerman, Phys. Rev. Lett. 107, 015701 (2011)]. Here, that framework is expanded to include general order parameters that distinguish different crystalline arrangements as target collective variables for enhanced sampling. The resulting free energy surface, being of quite high dimension, is nontrivial to reconstruct, and we discuss one particular strategy for performing the free energy analysis. The method is applied to the study of polymorphism in xenon crystals at high pressure and temperature using the Steinhardt order parameters without and with the supercell included in the set of collective variables. The expected fcc and bcc structures are obtained, and when the supercell parameters are included as collective variables, we also find several new structures, including fcc states with hcp stacking faults. We also apply the new method to the solid-liquid phase transition in copper at 1300 K using the same Steinhardt order parameters. Our method is able to melt and refreeze the system repeatedly, and the free energy profile can be obtained with high efficiency.

Yu, Tang-Qing, E-mail: tangqing.yu@nyu.edu; Vanden-Eijnden, Eric, E-mail: eve2@cims.nyu.edu [Courant Institute of Mathematical Sciences, New York University, New York, New York 10012 (United States); Chen, Pei-Yang; Chen, Ming [Department of Chemistry, New York University, New York, New York 10003 (United States); Samanta, Amit [Program in Applied and Computational Mathematics, Princeton University, Princeton, New Jersey 08544, USA and Lawrence Livermore National Laboratory, Livermore, California 94550 (United States); Tuckerman, Mark, E-mail: mark.tuckerman@nyu.edu [Courant Institute of Mathematical Sciences, New York University, New York, New York 10012 (United States); Department of Chemistry, New York University, New York, New York 10003 (United States); NYU-ECNU Center for Computational Chemistry at NYU Shanghai, Shanghai 200062 (China)

2014-06-07T23:59:59.000Z

159

Liquid Phase Heating Systems  

E-Print Network (OSTI)

saturation pressure is ju'st under 278 psig. To this, pump head, pump NPSH and static head due to elevated piping must l be added to arrive at total pressure in a steam cushioned HTW system. Nitrogen cushioned systems are more common, and expansion...

Mordt, E. H.

1979-01-01T23:59:59.000Z

160

Nonaqueous Phase Liquid Dissolution in Porous Media: Multi-Scale Effects of Multi-Component Dissolution Kinetics on Cleanup Time  

SciTech Connect

Industrial organic solvents such as trichloroethylene (TCE) and tetrachloroethylene (PCE) constitute a principal class of groundwater contaminants. Cleanup of groundwater plume source areas associated with these compounds is problematic, in part, because the compounds often exist in the subsurface as dense nonaqueous phase liquids (DNAPLs). Ganglia (or 'blobs') of DNAPL serve as persistent sources of contaminants that are difficult to locate and remediate (e.g. Fenwick and Blunt, 1998). Current understanding of the physical and chemical processes associated with dissolution of DNAPLs in the subsurface is incomplete and yet is critical for evaluating long-term behavior of contaminant migration, groundwater cleanup, and the efficacy of source area cleanup technologies. As such, a goal of this project has been to contribute to this critical understanding by investigating the multi-phase, multi-component physics of DNAPL dissolution using state-of-the-art experimental and computational techniques. Through this research, we have explored efficient and accurate conceptual and numerical models for source area contaminant transport that can be used to better inform the modeling of source area contaminants, including those at the LLNL Superfund sites, to re-evaluate existing remediation technologies, and to inspire or develop new remediation strategies. The problem of DNAPL dissolution in natural porous media must be viewed in the context of several scales (Khachikian and Harmon, 2000), including the microscopic level at which capillary forces, viscous forces, and gravity/buoyancy forces are manifested at the scale of individual pores (Wilson and Conrad, 1984; Chatzis et al., 1988), the mesoscale where dissolution rates are strongly influenced by the local hydrodynamics, and the field-scale. Historically, the physico-chemical processes associated with DNAPL dissolution have been addressed through the use of lumped mass transfer coefficients which attempt to quantify the dissolution rate in response to local dissolved-phase concentrations distributed across the source area using a volume-averaging approach (Figure 1). The fundamental problem with the lumped mass transfer parameter is that its value is typically derived empirically through column-scale experiments that combine the effects of pore-scale flow, diffusion, and pore-scale geometry in a manner that does not provide a robust theoretical basis for upscaling. In our view, upscaling processes from the pore-scale to the field-scale requires new computational approaches (Held and Celia, 2001) that are directly linked to experimental studies of dissolution at the pore scale. As such, our investigation has been multi-pronged, combining theory, experiments, numerical modeling, new data analysis approaches, and a synthesis of previous studies (e.g. Glass et al, 2001; Keller et al., 2002) aimed at quantifying how the mechanisms controlling dissolution at the pore-scale control the long-term dissolution of source areas at larger scales.

McNab, W; Ezzedine, S; Detwiler, R

2007-02-26T23:59:59.000Z

Note: This page contains sample records for the topic "non-aqueous phase liquid" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Characterization of Intermediate Phases Formed Between Solid Nickel and Liquid Zinc During Use as an Encapsulated Phase Change Material in Solar Thermal Energy Storage Systems  

Science Journals Connector (OSTI)

Of the new material systems under investigation for use in higher temperature phase change material-based solar thermal energy storage (TES) ... it is possible that the formation of intermediate phases could impe...

J. C. Sabol; W. Z. Misiolek; A. Oztekin…

2012-10-01T23:59:59.000Z

162

Integrated modeling of CO2 storage and leakage scenarios including transitions between super- and sub-critical conditions, and phase change between liquid and gaseous CO2  

SciTech Connect

Storage of CO{sub 2} in saline aquifers is intended to be at supercritical pressure and temperature conditions, but CO{sub 2} leaking from a geologic storage reservoir and migrating toward the land surface (through faults, fractures, or improperly abandoned wells) would reach subcritical conditions at depths shallower than 500-750 m. At these and shallower depths, subcritical CO{sub 2} can form two-phase mixtures of liquid and gaseous CO{sub 2}, with significant latent heat effects during boiling and condensation. Additional strongly non-isothermal effects can arise from decompression of gas-like subcritical CO{sub 2}, the so-called Joule-Thomson effect. Integrated modeling of CO{sub 2} storage and leakage requires the ability to model non-isothermal flows of brine and CO{sub 2} at conditions that range from supercritical to subcritical, including three-phase flow of aqueous phase, and both liquid and gaseous CO{sub 2}. In this paper, we describe and demonstrate comprehensive simulation capabilities that can cope with all possible phase conditions in brine-CO{sub 2} systems. Our model formulation includes: (1) an accurate description of thermophysical properties of aqueous and CO{sub 2}-rich phases as functions of temperature, pressure, salinity and CO{sub 2} content, including the mutual dissolution of CO{sub 2} and H{sub 2}O; (2) transitions between super- and subcritical conditions, including phase change between liquid and gaseous CO{sub 2}; (3) one-, two-, and three-phase flow of brine-CO{sub 2} mixtures, including heat flow; (4) non-isothermal effects associated with phase change, mutual dissolution of CO{sub 2} and water, and (de-) compression effects; and (5) the effects of dissolved NaCl, and the possibility of precipitating solid halite, with associated porosity and permeability change. Applications to specific leakage scenarios demonstrate that the peculiar thermophysical properties of CO{sub 2} provide a potential for positive as well as negative feedbacks on leakage rates, with a combination of self-enhancing and self-limiting effects. Lower viscosity and density of CO{sub 2} as compared to aqueous fluids provides a potential for self-enhancing effects during leakage, while strong cooling effects from liquid CO{sub 2} boiling into gas, and from expansion of gas rising towards the land surface, act to self-limit discharges. Strong interference between fluid phases under three-phase conditions (aqueous - liquid CO{sub 2} - gaseous CO{sub 2}) also tends to reduce CO{sub 2} fluxes. Feedback on different space and time scales can induce non-monotonic behavior of CO{sub 2} flow rates.

Pruess, K.

2011-05-15T23:59:59.000Z

163

Development of a low-cost black-liquid solar collector, Phase II. Second semi-annual report, March 1, 1980-August 31, 1980  

SciTech Connect

Battelle's Columbus Laboratories (BCL) is continuing its research effort to develop an efficient, low-temperature, low-cost, flat-plate black-liquid solar collector. The research efforts during this second 6-month period of Phase II have been directed toward (1) evaluating the long-term durability of various plastic materials and solar collector designs, (2) obtaining sufficient outdoor performance data to design a full-scale demonstration of a black-liquid solar collector for a commercial application, (3) working closely with a company willing to commercialize black liquid plastic collectors, and (4) incorporating improved black liquids with the identified plastic collector designs. Besides conducting indoor weathering tests of various plastic materials, two outdoor automated test facilities have been operated. One unit has been in use since February 1980 at Battelle in Columbus, Ohio, and the other unit began operation in May 1980 at Ramada Energy Systems, Inc., a collector manufacturing company near Phoenix, Arizona. Since Ramada Energy Systems has been working with extruded polycarbonate panels, Battelle has been working to date with extruded acrylic panel designs. Other potential plastics for solar collectors are being evaluated by exposure testing.

Landstrom, D.K.; Talbert, S.G.; McGinniss, V.D.

1980-09-30T23:59:59.000Z

164

Influence of cross-sectional geometry on the sensitivity and hysteresis of liquid-phase electronic pressure sensors  

E-Print Network (OSTI)

pressure sensors Yong-Lae Park, Daniel Tepayotl-Ramirez, Robert J. Wood, and Carmel Majidi Citation: Appl Institute of Physics. Related Articles Distant mechanical sensors based on cholesteric liquid crystals Appl microstructures Appl. Phys. Lett. 101, 191103 (2012) Silicon nanowire based Pirani sensor for vacuum measurements

Park, Yong-Lae

165

Three-dimensional reconstruction of liquid phases in disordered mesopores using in situ small-angle scattering  

Science Journals Connector (OSTI)

In situ synchrotron small-angle X-ray scattering is used to investigate wetting transitions of liquids confined in disordered mesoporous materials. A plurigaussian stochastic model is proposed, which enables one to analyze the data in terms of changing interface areas, contact angle and triple-line length.

Gommes, C.J.

2013-03-14T23:59:59.000Z

166

Non-aqueous solution preparation of doped and undoped Li{sub x}Mn{sub y}O{sub z}  

DOE Patents (OSTI)

A method is described for generation of phase-pure doped and undoped Li{sub x}Mn{sub y}O{sub z} precursors. The method of this invention uses organic solutions instead of aqueous solutions or nonsolution ball milling of dry powders to produce phase-pure precursors. These precursors can be used as cathodes for lithium-polymer electrolyte batteries. Dopants may be homogeneously incorporated to alter the characteristics of the powder. 1 fig.

Boyle, T.J.; Voigt, J.A.

1997-05-20T23:59:59.000Z

167

Computer Simulations Indicate Calcium Carbonate Has a Dense Liquid...  

NLE Websites -- All DOE Office Websites (Extended Search)

Computer Simulations Indicate Calcium Carbonate Has a Dense Liquid Phase Computer Simulations Indicate Calcium Carbonate Has a Dense Liquid Phase Berkeley Lab research could help...

168

Development of a neural network model for the prediction of liquid holdup in two-phase horizontal flow  

E-Print Network (OSTI)

Edward Shippen, B. S. , Texas A&M University Chair of Advisory Committee: Dr. Stuart Scott Accurate prediction of liquid holdup associated with multiphase flow is a critical element in the design and operation of modern production systems... Intermittent Annular 0 0 0 0 0 0 0 0 0 0 Dispersed bubble Figure 1: Horizontal flow patterns A number of empirical correlations and mechanistic models have been applied to estimate frictional pressure losses associated with multiphase flow in pipes...

Shippen, Mack Edward

2012-06-07T23:59:59.000Z

169

Selective detection of primary aromatic amines in complex mixtures by liquid chromatography with electrochemical detection using a short reversed-phase column  

SciTech Connect

Selective detection of primary aromatic amines (PAAs) in the presence of phenols by liquid chromatography with electrochemical detection was investigated. PAAs were resolved from other aromatic compounds, using three mobile phases, at various electrode potentials and flow rates. The phases used a combination of pH and organic modifiers (tetrahydrofuran, acetonitrile, or n-propanol) to optimize the degree of separation. As the pH of the mobile phase was increased, the signals for two- and three-ring PAAs decreased and became independent of pH at values between 4 and 8, while the signals from aniline and phenols increased. Selective detection of PAAs is feasible at pH 2.2 at potentials of 0.7 to 0.85 V vs Ag/AgCl. The best result was obtained with a 35 vol % tetrahydrofuran/water mobile phase, which yielded the highest signal for aniline and the lowest signal for phenol at pH 2.2 with satisfactory retention times. Electrochemical detectors are about one thousand times more sensitive to PAAs and phenols than ultraviolet detectors. The results obtained will permit design and construction of a portable PAA monitor with an appropriate sample concentrator, pump, and injection system. 20 refs., 11 figs., 2 tabs.

Otagawa, T.; Zaromb, S.; Stetter, J.R.

1985-01-01T23:59:59.000Z

170

Pore-scale analysis of solubilization and mobilization of trapped NAPL blobs in porous media  

E-Print Network (OSTI)

NAPL (non-aqueous phase liquid) blob mobilization and solubilization models were developed to predict residual NAPL fate and describe flow dynamics of various displacing phases (water and surfactant foam). The models were achieved by pore-scale mass...

Yoon, Sun Hee

2009-06-02T23:59:59.000Z

171

Vapor-deposited non-crystalline phase vs ordinary glasses and supercooled liquids: evidence for significant thermodynamic and kinetic differences  

E-Print Network (OSTI)

Vapor deposition of molecules on a substrate often results in glassy materials of high kinetic stability and low enthalpy. The extraordinary properties of such glasses are attributed to high rates of surface diffusion during sample deposition, which makes it possible for constituents to find a configuration of much lower energy on a typical laboratory time scale1,2,7. The exact structure of the resulting phase is often assumed to be identical to that obtained by aging of ordinary glass over exceedingly long times. Using Fast Scanning Calorimetry technique, we show that out-of-equilibrium relaxation kinetics and possibly the enthalpy of vapor-deposited films of toluene, an archetypical fragile glass former, are distinct from those of ordinary supercooled phase even when the deposition takes place at temperatures above the glass softening. These observations provide support to the conjecture that the vapor-deposition may result in formation of non-crystalline phase of unique structural, thermodynamic, and kinetic properties.

Deepanjan Bhattacharya; Vlad Sadtchenko

2014-10-31T23:59:59.000Z

172

"An Economic Process for Coal Liquefaction to Liquid Fuels" SBIR Phase II -- Final Scientific/Technical Report  

SciTech Connect

The current commercial processes for direct coal liquefaction utilize expensive backmix-flow reactor system and conventional catalysts resulting in incomplete and retrogressive reactions that produce low distillate liquid yield and high gas yield, with high hydrogen consumption. The new process we have developed, which uses a less expensive reactor system and highly active special catalysts, resulted in high distillate liquid yield, low gas yield and low hydrogen consumption. The new reactor system using the special catalyst can be operated smoothly for direct catalytic coal liquefaction. Due to high hydrogenation and hydrocracking activities of the special catalysts, moderate temperatures and high residence time in each stage of the reactor system resulted in high distillate yield in the C{sub 4}-650{degrees}F range with no 650{degrees}F{sup +} product formed except for the remaining unconverted coal residue. The C{sub 4}-650{degrees}F distillate is more valuable than the light petroleum crude. Since there is no 650{degrees}F{sup +} liquid product, simple reforming and hydrotreating of the C{sub 4}-650{degrees}F product will produce the commercial grade light liquid fuels. There is no need for further refinement using catalytic cracking process that is currently used in petroleum refining. The special catalysts prepared and used in the experimental runs had surface area between 40-155 m{sup 2}/gm. The liquid distillate yield in the new process is >20 w% higher than that in the current commercial process. Coal conversion in the experimental runs was moderate, in the range of 88 - 94 w% maf-coal. Though coal conversion can be increased by adjustment in operating conditions, the purpose of limiting coal conversion to moderate amounts in the process was to use the remaining unconverted coal for hydrogen production by steam reforming. Hydrogen consumption was in the range of 4.0 - 6.0 w% maf-coal. A preliminary economic analysis of the new coal liquefaction process was carried out by comparing the design and costs of the current commercial plant of the Shenhua Corporation in Erdos, Inner Mongolia. The cost of producing synthetic crude oil from coal in the current commercial process was estimated to be $50.5 per barrel compared to the estimated cost of $41.7 per barrel in the new process. As mentioned earlier, the light distillate product in the new process is of higher quality and value than the C{sub 4}-975{degrees}F product in the current commercial process adopted by the Shenhua Corporation. In sum, the new coal liquefaction process is superior and less capital intensive to current commercial process, and has a high potential for commercialization.

Ganguli, Partha Sarathi

2009-02-19T23:59:59.000Z

173

Direct Analysis of Reversed-Phase HPTLC Separated Tryptic Protein Digests using a Liquid Microjunction Surface Sampling Probe/ESI-MS System  

SciTech Connect

The sampling, ionization and detection of tryptic peptides separated in one-dimension on reversed phase HPTLC plates was performed using liquid microjunction surface sampling probe electrospray ionization mass spectrometry. Tryptic digests of five proteins (cytochrome c., myoglobin, beta-casein, lysozyme, and bovine serum albumin) were spotted on reversed phase HPTLC RP-8 F254s and HPTLC RP-18 F254s plates. The plates were then developed using 70/30 methanol/water with 0.1 M ammonium acetate. A dual purpose extraction/electrospray solution containing 70/30/0.1 water/methanol/formic acid was infused through the sampling probe during analysis of the developed lanes. Both full scan mass spectra and data dependent tandem mass spectra were acquired for each development lane to detect and verify the peptide distributions. Data dependent tandem mass spectra provided both protein identification and sequence coverage information. Highest sequence coverages were achieved for cytochrome c. and myoglobin (62.5% and 58.3%, respectively) on reversed phase RP-8 plates. While the tryptic peptides were separated enough for identification, the peptide bands did show some overlap with most peptides located in the lower half of the development lane. Proteins whose peptides were more separated gave higher sequence coverage. Larger proteins such as beta-casein and BSA which were spotted in lower relative amounts gave much lower sequence coverage than the smaller proteins.

Emory, Joshua F [ORNL; Walworth, Matthew J [ORNL; Van Berkel, Gary J [ORNL; Schulz, Michael [Merck Research Laboratories; Minarik, susanne [Merck Research Laboratories

2010-01-01T23:59:59.000Z

174

Characterization of Volatile Components in Dry Chrysanthemum Flowers Using Headspace—Liquid-Phase Microextraction—Gas Chromatography  

Science Journals Connector (OSTI)

......components to organic phase increases, the convection process intensifies...of the extraction efficiency increase was indistinctive. Therefore...7-methanoazulene * Retention time. Quality of the PBM search. Semiquantitative...of oak wood used for aging wines by headspace SPME-GCMS......

Guoqing Wang; Chunhong Dong; Yu-an Sun; Kui Xie; Haiyu Zheng

2008-02-01T23:59:59.000Z

175

Characterization of the liquid phase obtained by copyrolysis of Mustafa Kemal Pasa (M.K.P.) Lignite (Turkey) with low density polyethylene  

SciTech Connect

This study describes the detailed hydrocarbon type characterization of the tar (liquid phase) obtained by copyrolysis of Mustafa Kemal Paa (M.K.P.) lignite (Turkey) and low density polyethylene (LDPE) and by pyrolysis of coal and LDPE individually. Various spectroscopic techniques (gas chromatography-mass spectroscopy (GC-MS), nuclear magnetic resonance spectroscopy ({sup 1}H NMR), Fourier transform infrared spectroscopy (FTIR), and gel permeation chromatography (GPC)) are used for characterization, and the effect of the experimental conditions (temperature, lignite:low density polyethylene (LDPE) ratio, and catalyst) on the hydrocarbon distributions is discussed. The results show that the tars obtained by copyrolysis have similar properties with commercial gasoline (especially in the presence of Red mud). Red mud and bentonite used as catalysts make a positive effect on the production of olefins instead aromatics. Polyethylene acts as a hydrogenation medium for the coal product as revealed by FTIR results. 18 refs., 9 figs., 5 tabs.

Ali Sinag; Melike Sungur; Mustafa Gullu; Muammer Canel [Ankara University, Beevler-Ankara (Turkey). Department of Chemistry, Science Faculty

2006-10-15T23:59:59.000Z

176

On the influence of solution density on the formation of macroscopic defects in the liquid phase epitaxy of GaN  

Science Journals Connector (OSTI)

This paper reports on a new simple method for avoiding particle-induced macroscopic defects using the liquid phase epitaxy (LPE) of GaN as an example. In a series of growth experiments by LPE of GaN it is demonstrated that the number of particle-induced macrodefects in the epitaxial layers correlates strongly and reproducibly with the density of the solution. In solutions with a density higher than that of the deleterious particles, the particles float on the solution and hence are hindered to get into contact with the seed, which is placed at the bottom of the crucible. Consequently, so-called depressions — a typical particle-induced defect in GaN–LPE layers — are avoided. The principle of avoiding the formation of macroscopic defects originating from particles by adapting the density of the solution (density criterion) should be generally applicable to solution growth processes, regardless of the material system.

S. Hussy; P. Berwian; E. Meissner; J. Friedrich; G. Müller

2008-01-01T23:59:59.000Z

177

Liquid crystalline phase synthesis of nanoporous MnO{sub 2} thin film arrays as an electrode material for electrochemical capacitors  

SciTech Connect

Graphical abstract: Three-dimensional (3D) MnO{sub 2} thin film arrays with nanoporous structure is electrodeposited on Ti foil from hexagonal lyotropic liquid crystalline phase. Low-angle X-ray diffraction (XRD), wide-angle XRD, field emission scanning electron microscopy (FESEM), and transmission electron microscopy (TEM) are employed to study the morphology and the structure of the as-synthesized MnO{sub 2} materials. Galvanostatic charge/discharge measurements show the nanoporous, 3D electrode material exhibits excellent capacitive performance between the potential range of ?0.1 to 0.9 V, and a maximum specific capacitance as high as 462 F g{sup ?1} are achieved in 0.5 M Na{sub 2}SO{sub 4} solution at a charge/discharge current density of 4 A g{sup ?1}. Highlights: ? 3D MnO{sub 2} thin film arrays with nanoporous structure is fabricated for the first time. ? A maximum specific capacitance as high as 462 F g{sup ?1} is obtained. ? The 3D and nanoporous superarchitecture facilitate electrolyte penetration. -- Abstract: Three-dimensional (3D) MnO{sub 2} thin film arrays with nanoporous structure is electrodeposited on Ti foil from hexagonal lyotropic liquid crystalline phase. Low-angle X-ray diffraction (XRD), wide-angle XRD, field emission scanning electron microscopy (FESEM), and transmission electron microscopy (TEM) are employed to study the morphology and the structure of the as-synthesized MnO{sub 2} materials. Galvanostatic charge/discharge measurements show the nanoporous, 3D electrode material exhibits excellent capacitive performance between the potential range of ?0.1 to 0.9 V, and a maximum specific capacitance as high as 462 F g{sup ?1} are achieved in 0.5 M Na{sub 2}SO{sub 4} solution at a charge/discharge current density of 4 A g{sup ?1}.

Yang, Guangwu, E-mail: yanggw@upc.edu.cn [College of Science, China University of Petroleum, Qingdao, Shandong 266555 (China) [College of Science, China University of Petroleum, Qingdao, Shandong 266555 (China); Key Laboratory of New Energy Physics and Materials Science in Universities of Shandong, China University of Petroleum, Qingdao, Shandong 266555 (China); Wang, Baoli [School of Geosciences, China University of Petroleum, Qingdao, Shandong 266555 (China)] [School of Geosciences, China University of Petroleum, Qingdao, Shandong 266555 (China); Guo, Wenyue, E-mail: wyguo@upc.edu.cn [College of Science, China University of Petroleum, Qingdao, Shandong 266555 (China) [College of Science, China University of Petroleum, Qingdao, Shandong 266555 (China); Key Laboratory of New Energy Physics and Materials Science in Universities of Shandong, China University of Petroleum, Qingdao, Shandong 266555 (China); Bu, Zhongheng; Miao, Chengcheng [College of Science, China University of Petroleum, Qingdao, Shandong 266555 (China)] [College of Science, China University of Petroleum, Qingdao, Shandong 266555 (China); Xue, Tong; Li, Hulin [College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000 (China)] [College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000 (China)

2012-11-15T23:59:59.000Z

178

Effect of compressive and tensile strains on the critical current density of liquid-phase diffusion processed Nb{sub 3}Sn  

SciTech Connect

The influence of strain on the critical current density of liquid-phase diffusion processed Nb{sub 3}Sn foil has been examined. Eight different levels of plane stress were applied to the Nb{sub 3}Sn by using differential thermal contraction. This differential thermal contraction was achieved by soldering Nb{sub 3}Sn foil samples between two plates of eight different materials, and cooling the composite structures from the soldering temperature to the test temperature. Brass, copper, stainless steel, Hastelloy X, Inconel 600, nickel, niobium and tungsten plates were used. In addition, bending strains were applied to the Nb{sub 3}Sn foil using a non-symmetric bi-metal structure with a brass or niobium plate placed in a bending fixture. In a transverse field of 5T and at a test temperature of 4.2 K, a thermally applied axial strain of 0.4% increased the critical current by 60%. An axial tensile bending strain of the same magnitude resulted in a critical current increase of only about 9%. These results will be discussed and compared to observations in the literature for solid-phase diffusion processed Nb{sub 3}Sn.

Murray, M.L.; Benz, M.G.; Zabala, R.J.; Raber, T.R. [General Electric Research and Development Center, Schenectady, NY (United States)

1994-12-31T23:59:59.000Z

179

A15 Nb/sub 3/(AlGe) superconductors prepared by transformation from liquid quenched body-centered cubic phase  

SciTech Connect

A supersaturated body-centered cubic (bcc) solid solution of Nb/sub 3/(Al/sub 1-x/Ge/sub x/) up to x = 0.3 has been prepared by the liquid quenching on a hot Cu substrate. The quenched materials are then transformed to the A15 structure by annealing above 800 /sup 0/C. Following the transformation, the critical temperature rises above 18 /sup 0/K. The A15 phase converted from the bcc phase has an extremely small grain size of a few hundred angstroms, resulting in a high critical current density J/sub c/ in high magnetic fields. J/sub c/ of 3.5 x 10/sup 5/ A/cm/sup 2/ at 4.2 /sup 0/K and 16 T has been achieved in the Nb/sub 3/(Al/sub 0.8/Ge/sub 0.2/) sample annealed at 850 /sup 0/C for 7 h.

Togano, K.; Takeuchi, T.; Tachikawa, K.

1982-07-15T23:59:59.000Z

180

Experimental and theoretical modeling of DNAPL transport in vertical fractured media  

E-Print Network (OSTI)

In recent years, groundwater contamination by dense, non-aqueous phase liquids (DNAPLs) such as chlorinated solvents and polychlorinated biphenyls (PCBs) has become an important environmental concern in many industrialized ...

Levy, Laurent Claude, 1973-

2003-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "non-aqueous phase liquid" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Results of Soil Vapor Extraction of a Chlorinated Solvent Dnapl Waste Site at the Rocky Flats Superfund Site  

Science Journals Connector (OSTI)

A full scale Soil Vapor Extraction (SVE) system was evaluated for remediation of subsurface contamination of the chlorinated Dense Non-Aqueous Phase Liquids (DNAPL) at a waste site at the Rocky Flats Environmenta...

S. Grace; E. Dille

1995-01-01T23:59:59.000Z

182

Formation of iron complexs from trifluoroacetic acid based liquid...  

NLE Websites -- All DOE Office Websites (Extended Search)

of iron complexs from trifluoroacetic acid based liquid chromatography mobile phases as interference ions in liquid Formation of iron complexs from trifluoroacetic acid based...

183

Goethite liquid crystals and magnetic field effects.  

E-Print Network (OSTI)

??In this thesis the liquid crystal phase behavior of colloidal, boardlike, goethite (alpha-FeOOH) particles is described. Apart from the nematic phase, a smectic A phase… (more)

Pol, E. van den

2010-01-01T23:59:59.000Z

184

Commercial-scale demonstration of the Liquid Phase Methanol (LPMEOH{trademark}) process. Technical progress report number 11, January 1--March 31, 1997  

SciTech Connect

During this quarter, the third draft of the Topical Report on Process Economics Studies was issued for review. A recommendation to continue with design verification testing on the coproduction of methanol and dimethyl ether (DME) was made. A liquid phase dimethyl ether (LPDME) catalyst system with reasonable long-term activity and stability is being developed, and a decision to proceed with a proof-of-concept test run at the LaPorte Alternative Fuels Development Unit (AFDU) is pending the release of a memo from Air Products on the catalyst targets and corresponding economics for a commercially successful LPDME catalyst. The off-site product-use test plan is to be updated in June of 1997. During this quarter, Air Products and Acurex Environmental Corporation continued developing the listing of product-use test participants who are involved in fuel cell, transportation, and stationary power plant applications. Start-up activities (Task 3.1) began during the reporting period, and coal-derived synthesis gas (syngas) was introduced to the demonstration unit. The recycle compressor was tested successfully on syngas at line pressure of 700 psig, and the reactor loop reached 220 C for carbonyl burnout. Iron carbonyl in the balanced gas feed remained below the 10 ppbv detection limit for all samples but one. Within the reactor loop, iron carbonyl levels peaked out near 200 ppbv after about 40 hours on-stream, before decreasing to between 10--20 ppbv at 160 hours on -stream. Nickel carbonyl measurements reached a peak of about 60 ppbv, and decreased at all sampling locations to below the 10 ppbv detection limit by 70 hours on-stream. Catalyst activation of the nine 2,250 lb batches required for the initial catalyst charge began and concluded. All batches met or slightly exceeded the theoretical maximum uptake of 2.82 SCF of reducing gas/lb catalyst.

NONE

1997-06-11T23:59:59.000Z

185

ECO2M: A TOUGH2 Fluid Property Module for Mixtures of Water, NaCl, and CO2, Including Super- and Sub-Critical Conditions, and Phase Change Between Liquid and Gaseous CO2  

SciTech Connect

ECO2M is a fluid property module for the TOUGH2 simulator (Version 2.0) that was designed for applications to geologic storage of CO{sub 2} in saline aquifers. It includes a comprehensive description of the thermodynamics and thermophysical properties of H{sub 2}O - NaCl - CO{sub 2} mixtures, that reproduces fluid properties largely within experimental error for temperature, pressure and salinity conditions in the range of 10 C {le} T {le} 110 C, P {le} 600 bar, and salinity from zero up to full halite saturation. The fluid property correlations used in ECO2M are identical to the earlier ECO2N fluid property package, but whereas ECO2N could represent only a single CO{sub 2}-rich phase, ECO2M can describe all possible phase conditions for brine-CO{sub 2} mixtures, including transitions between super- and sub-critical conditions, and phase change between liquid and gaseous CO{sub 2}. This allows for seamless modeling of CO{sub 2} storage and leakage. Flow processes can be modeled isothermally or non-isothermally, and phase conditions represented may include a single (aqueous or CO{sub 2}-rich) phase, as well as two-and three-phase mixtures of aqueous, liquid CO{sub 2} and gaseous CO{sub 2} phases. Fluid phases may appear or disappear in the course of a simulation, and solid salt may precipitate or dissolve. TOUGH2/ECO2M is upwardly compatible with ECO2N and accepts ECO2N-style inputs. This report gives technical specifications of ECO2M and includes instructions for preparing input data. Code applications are illustrated by means of several sample problems, including problems that had been previously solved with TOUGH2/ECO2N.

Pruess, K.

2011-04-01T23:59:59.000Z

186

Determination of triclosan and triclocarban in environmental water samples with ionic liquid/ionic liquid dispersive liquid-liquid microextraction prior to HPLC-ESI-MS/MS  

Science Journals Connector (OSTI)

A hydrophobic ionic liquid was finely dispersed in aqueous solution along with a hydrophilic ionic liquid. Following centrifugation, the two phases aggregate to form relatively large droplets. Based on this pheno...

Ru-Song Zhao; Xia Wang; Jing Sun; Cong Hu; Xi-Kui Wang

2011-07-01T23:59:59.000Z

187

Phase-Transfer Catalysis Displacement Reactions with Simple Anions  

Science Journals Connector (OSTI)

Phase-transfer catalysis (PTC) is an excellent technique both in liquid—liquid and liquid—solid (and sometimes in liquid—vapor) modes for conducting displacement reactions with anions.

Charles M. Starks; Charles L. Liotta; Marc E. Halpern

1994-01-01T23:59:59.000Z

188

Carbon-nitrogen bond-forming reactions in supercritical and expanded-liquid carbon dioxide media : green synthetic chemistry with multiscale reaction and phase behavior modeling  

E-Print Network (OSTI)

The goal of this work was to develop a detailed understanding of carbon-nitrogen (C-N) bond-forming reactions of amines carried out in supercritical and expanded-liquid carbon dioxide (CO2) media. Key motivations behind ...

Ciccolini, Rocco P

2008-01-01T23:59:59.000Z

189

Determination of Selected Herbicides and Phenols in Water and Soils by Solid-Phase Extraction and High-Performance Liquid Chromatography  

Science Journals Connector (OSTI)

......1987). 6. G.E. Batley. Applications of liquid chromatography with electro- chemical detection to the analysis of oil shale process waters. J. Chromatogr. 382: 409416 (1987). 7. H. Farber, K. Nick, and H.F. Scoeler. Determination......

Irena Baranowska; Celina Pieszko

2000-05-01T23:59:59.000Z

190

Synchroton X-Ray Studies of Liquid-Vapor Interfaces  

Science Journals Connector (OSTI)

The variation of density across the liquid-vapor interface from essentially zero density far out in the vapor phase to a homogeneous density deep in the liquid phase can be determined by X-ray reflectivity mea...

J. Als-Nielsen

1988-01-01T23:59:59.000Z

191

What constitutes a simple liquid?  

E-Print Network (OSTI)

Simple liquids are traditionally defined as many-body systems of classical particles interacting via radially symmetric pair potentials. We suggest that a simple liquid should be defined instead by the property of having strong correlation between virial and potential energy equilibrium fluctuations in the NVT ensemble. There is considerable overlap between the two definitions, but also some notable differences. For instance, in the new definition simplicity is not a property of the intermolecular potential only because a liquid is usually only strongly correlating in part of its phase diagram. Moreover, according to the new definition not all simple liquids are atomic (i.e., with radially symmetric pair potentials) and not all atomic liquids are simple. The main part of the paper motivates the new definition of liquid simplicity by presenting evidence that a liquid is strongly correlating if and only if its intermolecular interactions may be ignored beyond the first coordination shell (FCS). This is demonstrated by NVT simulations of structure and dynamics of 15 atomic and molecular model liquids with a shifted-forces cutoff placed at the first minimum of the radial distribution function. No proof is given that the chemical characterization follows from the strong correlation property, but it is shown to be consistent with the existence of isomorphs in strongly correlating liquids' phase diagram. Finally, we note that the FCS characterization of simple liquids calls into question the basis for standard perturbation theory, according to which the repulsive and attractive forces play fundamentally different roles for the physics of liquids.

Trond S. Ingebrigtsen; Thomas B. Schrøder; Jeppe C. Dyre

2011-11-15T23:59:59.000Z

192

Thermodynamic Evaluation of Immobilized Cellulose Tris(3,5-Dichlorophenylcarbamate) as a Stationary Phase for Liquid Chromatographic Separation of Darunavir Enantiomers  

Science Journals Connector (OSTI)

......phase conditions using different compositions of n-hexane, organic modifier...pharmaceutical, biomedical, agrochemical and environmental is well known...was evaluated using different compositions of mobile phases between 20 and......

R. Nageswara Rao; K. Nagesh Kumar

2014-06-01T23:59:59.000Z

193

Usage of Nonporous Polymeric Particles for Reversed-Phase High-Performance Liquid Chromatography of Oxidized and Deamidated Forms of Recombinant Human Growth Hormone  

Science Journals Connector (OSTI)

...July 2004 research-article Articles Usage of Nonporous Polymeric Particles for Reversed-Phase...chromatographic separation of several hGH variants. Usage of nonporous polymeric particles for reversed-phase...Chromatographic Science, Vol. 42, July 2004 Usage of Nonporous Polymeric Particles for Reversed-Phase......

Göran Karlsson

2004-07-01T23:59:59.000Z

194

High P/T phase and volumetric behavior of coal liquid constituents. (Quarterly technical progress report), January 1-April 1, 1984. [6 gases in hydrogen-dibenzofuran and in hydrogen-g-methylanthracene  

SciTech Connect

A sophisticated perturbation chromatography technique has been used to study the vapor-liquid equilibrium behavior of six light gases in two hydrogen-coal liquid model compounds systems. Infinite-dilution K values are reported for methane, ethane, propane, n-butane, carbon dioxide and hydrogen sulfide in: (1) hydrogen-dibenzofuran system at 373.2 and 398.2/sup 0/K and up to 6 MPa; and (2) hydrogen-g-methylanthracene systems at 373.2, 398.2, 423.2, 448.2 and 473.2/sup 0/K and up to 21 M Pa. Henry's constants were determined for the light gases in 9-methylanthracene. Second cross virial coefficients and vapor-phase infinite-dilution fugacity coefficients were calculated for the hydrocarbon gases in hydrogen. The results were combined with the experimental K-value measurements to obtain Henry's constants in hydrogen-9-methylanthracene mixtures of fixed liquid composition. The constants thus obtained show a significant dependence of hydrogen solubility. 1 reference.

Kobayshi, R.

1984-01-01T23:59:59.000Z

195

Deviations from Fermi-liquid behavior in (2+1)-dimensional quantum electrodynamics and the normal phase of high-Tc superconductors  

Science Journals Connector (OSTI)

We argue that the gauge-fermion interaction in multiflavor quantum electrodynamics in (2+1) dimensions is responsible for non-Fermi-liquid behavior in the infrared, in the sense of leading to the existence of a nontrivial (quasi)fixed point that lies between the trivial fixed point (at infinite momenta) and the region where dynamical symmetry breaking and mass generation occurs. This quasifixed-point structure implies slowly varying, rather than fixed, couplings in the intermediate regime of momenta, a situation which resembles that of (four-dimensional) "walking technicolor" models of particle physics. The inclusion of wave-function renormalization yields marginal O(1N) corrections to the "bulk" non-Fermi-liquid behavior caused by the gauge inter-action in the limit of infinite flavor number. Such corrections lead to the appearance of modified critical exponents. In particular, at low temperatures there appear to be logarithmic scaling violations of the linear resistivity of the system of order O(1N). The connection with the anomalous normal-state properties of certain condensed-matter systems relevant for high-temperature superconductivity is briefly discussed. The relevance of the large (flavor) N expansion to the Fermi-liquid problem is emphasized. As a partial result of our analysis, we point out the absence of charge-density-wave instabilities from the effective low-energy theory, as a consequence of gauge invariance.

I. J. R. Aitchison and N. E. Mavromatos

1996-04-01T23:59:59.000Z

196

VOLUME 78, NUMBER 12 P H Y S I C A L R E V I E W L E T T E R S 24 MARCH 1997 Liquid-Liquid Phase Transition: Evidence from Simulations  

E-Print Network (OSTI)

Transition: Evidence from Simulations Stephen Harrington,1 Rong Zhang,1 Peter H. Poole,2 Francesco Sciortino]. In the case of water, several studies [2­8] are germane to the hypothesis [2] that in addition to the known by an inter- face. Mass conservation fixes the relative amount of the two different phases. The two coexisting

Stanley, H. Eugene

197

Study of Heat Transfer in Non-boiling Two-phase Gas-liquid Flow in Pipes for Horizontal, Slightly Inclined, and Vertical Orientations.  

E-Print Network (OSTI)

??The main objective of this research is to establish a fundamental understanding of heat transfer in non-boiling two-phase pipe flow. The key processes that govern… (more)

Tang, Clement Chih-Wei

2011-01-01T23:59:59.000Z

198

EMSL - liquids  

NLE Websites -- All DOE Office Websites (Extended Search)

liquids en Iodine Solubility in Low-Activity Waste Borosilicate Glass at 1000 °C. http:www.emsl.pnl.govemslwebpublicationsiodine-solubility-low-activity-waste-borosilicate...

199

Heterophase liquid states: Thermodynamics, structure, dynamics  

E-Print Network (OSTI)

An overview of theoretical results and experimental data on the thermodynamics, structure and dynamics of the heterophase glass-forming liquids is presented. The theoretical approach is based on the mesoscopic heterophase fluctuations model (HPFM) developed within the framework of the bounded partition function approach. The Fischer cluster phenomenon, glass transition, liquid-liquid transformations, parametric phase diagram, cooperative dynamics and fragility of the glass-forming liquids is considered.

A. S. Bakai

2015-01-12T23:59:59.000Z

200

Direct Experimental Evidence for a Negative Heat Capacity in the Liquid-to-Gas Phase Transition in Hydrogen Cluster Ions: Backbending of the Caloric Curve  

Science Journals Connector (OSTI)

By selecting specific decay reactions in high-energy collisions (60??keV/amu) of hydrogen cluster ions with a helium target (utilizing event-by-event data of a recently developed multicoincidence experiment) and by deriving corresponding temperatures for these microcanonical cluster ensembles (analyzing respective fragment distributions), we are able to construct caloric curves for H3+(H2)m cluster ions (6?m?14). All individual curves and the mean of these curves show a backbending in the plateau region, thus constituting direct evidence for a negative microcanonical heat capacity in the liquid-to-gas transition of these finite systems.

F. Gobet; B. Farizon; M. Farizon; M. J. Gaillard; J. P. Buchet; M. Carré; P. Scheier; T. D. Märk

2002-10-11T23:59:59.000Z

Note: This page contains sample records for the topic "non-aqueous phase liquid" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Flowing Liquid Crystal Simulating the Schwarzschild Metric  

E-Print Network (OSTI)

We show how to simulate the equatorial section of the Schwarzschild metric through a flowing liquid crystal in its nematic phase. Inside a liquid crystal in the nematic phase, a traveling light ray feels an effective metric, whose properties are linked to perpendicular and parallel refractive indexes, $n_o$ e $n_e$ respectively, of the rod-like molecule of the liquid crystal. As these indexes depend on the scalar order parameter of the liquid crystal, the Beris-Edwards hydrodynamic theory is used to connect the order parameter with the velocity of a liquid crystal flow at each point. This way we calculate a radial velocity profile that simulates the equatorial section of the Schwarzschild metric, in the region outside of Schwarzschild's radius, in the nematic phase of the liquid crystal. In our model, the higher flow velocity can be of the order of some meters per second.

Erms R. Pereira; Fernando Moraes

2010-11-21T23:59:59.000Z

202

Quantal Ising Liquid  

Science Journals Connector (OSTI)

An example is presented of a model of an amorphous quantum mechanical system, a liquid of quantal Ising spins, which can be solved exactly within certain many-body theories. Analytical solutions of the model in mean-field theory are shown to reveal a decrease in the extent of the ferromagnetic region (compared to an equivalent classical system) and the occurrence of some degree of quantum localization. Both phenomena are analyzed as a competition between quantum mechanics and the condensed phase.

Richard M. Stratt

1984-10-01T23:59:59.000Z

203

Physical Chemistry of Ionic Liquids  

NLE Websites -- All DOE Office Websites (Extended Search)

Ionic liquids are experiencing explosive growth in many areas of research Ionic liquids are experiencing explosive growth in many areas of research and practical applications. They present a wide range of complex physical and chemical behaviors, including ambient vapor pressures ranging from UHV to weakly volatile, a substantial variety of distinct condensed phases, including multiple crystal isomorphs, glasses, amorphous plastic and liquid crystal phases, deep supercooling, and interesting dynamical and transport phenomena. Experiments and simulations have shown that their intrinsic self-organization at the nanoscale is responsible for several of these properties. The symposium will assemble an international array of speakers to discuss ionic liquids in the context of their heterogeneous environments, solvation, dynamics and transport, interfacial properties,

204

Liquid and solid phase compositions in a partially frozen JP-5 fuel low in n-alkanes. Memorandum report April 1983-January 1984  

SciTech Connect

A JP-5 low in n-alkanes was partially frozen at several temperatures 9 to 15 C below its normal freezing point of -53 C. In spite of their low concentrations in the starting fuel, the n-alkanes were the predominant components in the solid phase crystallizing from the fuel. In this respect, this JP-5 behaves in a fashion similar to other jet fuels which contain 3 to 5 times the amounts of n-alkanes.

Van Winkle, T.L.; Hazlett, R.N.; Beal, E.J.; Mushrush, G.W.

1984-06-27T23:59:59.000Z

205

Elimination of liquid discharge to the environment from the TA-50 Radioactive Liquid Waste Treatment Facility  

SciTech Connect

Alternatives were evaluated for management of treated radioactive liquid waste from the radioactive liquid waste treatment facility (RLWTF) at Los Alamos National Laboratory. The alternatives included continued discharge into Mortandad Canyon, diversion to the sanitary wastewater treatment facility and discharge of its effluent to Sandia Canyon or Canada del Buey, and zero liquid discharge. Implementation of a zero liquid discharge system is recommended in addition to two phases of upgrades currently under way. Three additional phases of upgrades to the present radioactive liquid waste system are proposed to accomplish zero liquid discharge. The first phase involves minimization of liquid waste generation, along with improved characterization and monitoring of the remaining liquid waste. The second phase removes dissolved salts from the reverse osmosis concentrate stream to yield a higher effluent quality. In the final phase, the high-quality effluent is reused for industrial purposes within the Laboratory or evaporated. Completion of these three phases will result in zero discharge of treated radioactive liquid wastewater from the RLWTF.

Moss, D.; Williams, N.; Hall, D.; Hargis, K.; Saladen, M.; Sanders, M.; Voit, S.; Worland, P.; Yarbro, S.

1998-06-01T23:59:59.000Z

206

LNG liquid-liquid immiscibility  

SciTech Connect

Although natural gas species rarely exhibit liquid-liquid immiscibility in binary systems, the presence of additional components can extend the domain of immiscibility in those few binary systems where it already exists or produce immiscibility in binary systems where it had not existed. If the solute has the proper molecular relation to the solvent mixture background, liquid-liquid-vapor (LLV) behavior will occur; such phenomena greatly complicate the design of LNG processing equipment. To aid LNG engineers, researchers mapped the thermodynamic behavior of four ternary LLV systems and examined the effects of the second solvents - ethane, propane, n-butane, and CO/sub 2/ - on the binary methane + n-octane system.

Luks, K.D.; Kohn, J.P.

1981-09-01T23:59:59.000Z

207

Phase transitions of helium in aerogel  

Science Journals Connector (OSTI)

The effect of dilute quenched impurities on the liquid-vapor critical point, superfluid and He3?He4 phase separation transitions were studied by introducing liquid helium into aerogel. Aerogel is a highly porous ...

M. H. W. Chan

1996-01-01T23:59:59.000Z

208

Solid-Phase Extraction Combined with High-Performance Liquid Chromatography?Atmospheric Pressure Chemical Ionization?Mass Spectrometry Analysis of Pesticides in Water:? Method Performance and Application in a Reconnaissance Survey of Residues in Drinking Water in Greater Cairo, Egypt  

Science Journals Connector (OSTI)

Solid-Phase Extraction Combined with High-Performance Liquid Chromatography?Atmospheric Pressure Chemical Ionization?Mass Spectrometry Analysis of Pesticides in Water:? Method Performance and Application in a Reconnaissance Survey of Residues in Drinking Water in Greater Cairo, Egypt ... Each shipment, which included 24 cartridges, weighed <454 g and cost approximately 200 Egyptian pounds ($40 U.S.). ...

Thomas L. Potter; Mahmoud A. Mohamed; Hannah Ali

2006-12-22T23:59:59.000Z

209

Pore-scale simulation of liquid CO2 displacement of water using...  

NLE Websites -- All DOE Office Websites (Extended Search)

Pore-scale simulation of liquid CO2 displacement of water using a two-phase lattice Boltzmann model. Pore-scale simulation of liquid CO2 displacement of water using a two-phase...

210

Hot Gas Filtration of Fine and Ultra fine Particles with Liquid...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Hot Gas Filtration of Fine and Ultra fine Particles with Liquid Phase Sintered SiC Ceramic DPF Hot Gas Filtration of Fine and Ultra fine Particles with Liquid Phase Sintered SiC...

211

Dynamics of quantum spin liquid and spin solid phases in IPA-CuCl3 under an applied magnetic field studied with neutron scattering  

SciTech Connect

Inelastic and elastic neutron scattering is used to study spin correlations in the quasi-one-dimensional quantum antiferromagnet IPA-CuCl3 in strong applied magnetic fields. A condensation of magnons and commensurate transverse long-range ordering is observe at a critical field Hc=9.5 T. The field dependencies of the energies and polarizations of all magnon branches are investigated both below and above the transition point. Their dispersion is measured across the entire one-dimensional Brillouin zone in magnetic fields up to 14 T. The critical wave vector of magnon spectrum truncation Masuda et al., Phys. Rev. Lett. 96, 047210 2006 is found to shift from hc0,35 at HHC to hc=0.25 for HHC. A drastic reduction of magnon bandwidths in the ordered phase Garlea et al., Phys. Rev. Lett. 98, 167202 2007 is observed and studied in detail. New features of the spectrum, presumably related to this bandwidth collapse, are observed just above the transition field.

Zheludev, Andrey I [ORNL; Garlea, Vasile O [ORNL; Masuda, T. [Yokohama City University, Japan; Manaka, H. [Kagoshima University, Kagoshima JAPAN; Regnault, L.-P. [CEA, Grenoble, France; Ressouche, E. [CEA, Grenoble, France; Grenier, B. [CEA, Grenoble, France; Chung, J.-H. [National Institute of Standards and Technology (NIST); Qiu, Y. [National Institute of Standards and Technology (NIST); Habicht, Klaus [Hahn-Meitner Institut, Berlin, Germany; Kiefer, K. [Hahn-Meitner Institut, Berlin, Germany; Boehm, Martin [Institut Laue-Langevin (ILL)

2007-01-01T23:59:59.000Z

212

Haze Formation and Behavior in Liquid-Liquid Extraction Processes  

SciTech Connect

Aqueous haze formation and behavior was studied in the liquid-liquid system tri-n-butyl phosphate in odorless kerosene and 3M nitric acid with uranyl nitrate and cesium nitrate representing the major solute and an impurity, respectively. A pulsed column, mixer-settler and centrifugal contactor were chosen to investigate the effect of different turbulence characteristics on the manifestation of haze since these contactors exhibit distinct mixing phenomena. The dispersive processes of drop coalescence and breakage, and water precipitation in the organic phase were observed to lead to the formation of haze drops of {approx}1 um in diameter. The interaction between the haze and primary drops of the dispersion was critical to the separation efficiency of the liquid-liquid extraction equipment. Conditions of high power input and spatially homogeneous mixing enabled the haze drops to become rapidly assimilated within the dispersion to maximize the scrub performance and separation efficiency of the equipment.

Arm, Stuart T.; Jenkins, J. A.

2006-07-31T23:59:59.000Z

213

Optical constants of liquid and solid methane  

Science Journals Connector (OSTI)

The optical constants nr + ini of liquid methane and phase I solid methane were determined over the entire spectral range by the use of various data sources published in the...

Martonchik, John V; Orton, Glenn S

1994-01-01T23:59:59.000Z

214

Behavior of hydrophobic ionic liquids as liquid membranes on phenol removal: Experimental study and optimization  

E-Print Network (OSTI)

Room temperature ionic liquids show potential as an alternative to conventional organic membrane solvents mainly due to their properties of low vapor pressure, low volatility and they are often stable. In the present work, the technical feasibilities of room temperature ionic liquids as bulk liquid membranes for phenol removal were investigated experimentally. Three ionic liquids with high hydrophobicity were used and their phenol removal efficiency, membrane stability and membrane loss were studied. Besides that, the effects of several parameters, namely feed phase pH, feed concentration, NaOH concentration and stirring speeds on the performance of best ionic liquid membrane were also evaluated. Lastly, an optimization study on bulk ionic liquid membrane was conducted and the maximum phenol removal efficiency was compared with the organic liquid membranes. The preliminary study shows that high phenol extraction and stripping efficiencies of 96.21% and 98.10%, respectively can be achieved by ionic liquid memb...

Ng, Y S; Hashim, M A

2014-01-01T23:59:59.000Z

215

Superfund Record of Decision (EPA Region 6): Fourth Street Abandoned Refinery Site, Oklahoma City, OK, September 1993  

SciTech Connect

The decision document presents the selected remedial action for the Fourth Street Refinery Site (FSR site), Oklahoma City, Oklahoma, for the Ground Water Operable Unit. The Record of Decision (ROD) addresses the contamination in the ground water, which includes non-aqueous phase liquids. Principal threat wastes include 'pools' of dense non-aqueous phase liquids (DNAPLs) submerged beneath the ground water or in fractured bedrock, or NAPLs floating on water. This Ground Water Operable Unit addresses the principal threat at the site by monitoring the ground water to ensure that the contaminant levels are reduced with time due to natural attenuation, once the surface contamination is removed.

Not Available

1993-09-01T23:59:59.000Z

216

Liquid electrode  

DOE Patents (OSTI)

A dropping electrolyte electrode is described for use in electrochemical analysis of non-polar sample solutions, such as benzene or cyclohexane. The liquid electrode, preferably an aqueous salt solution immiscible in the sample solution, is introduced into the solution in dropwise fashion from a capillary. The electrolyte is introduced at a known rate, thus, the droplets each have the same volume and surface area. The electrode is used in making standard electrochemical measurements in order to determine properties of non-polar sample solutions. 2 figures.

Ekechukwu, A.A.

1994-07-05T23:59:59.000Z

217

Mechanism of constitution liquid film migration  

SciTech Connect

Liquid film migration (LFM) in liquid phase sintering classically involves a large metastable liquid volume adjacent to solid, and migration occurs at an isolated solid-liquid (S-L) interface. Constitutional liquid film migration (CLFM), discovered in alloy 718, has major characteristics similar to those of LFM, except that the metastable liquid is from the constitutional liquation of precipitates on the grain boundary. The similarity between LFM and CLFM has led to the theory that coherency lattice strain responsible for LFM is also responsible for CLFM. The coherency strain hypothesis was tested in this study by evaluating whether the Hillert model of LFM would also apply for CLFM. Experimental results of CLFM in alloy 718 showed that migration velocity followed the trend predicted by the Hillert model. This indicates that the coherency strain hypothesis of LFM also applies for CLFM and that the coherency lattice strain responsible for LFM is also the driving force for CLFM.

NONE

1999-06-01T23:59:59.000Z

218

Continuous transitions between composite Fermi liquid and Landau Fermi liquid: A route to fractionalized Mott insulators  

E-Print Network (OSTI)

One of the most successful theories of a non-Fermi-liquid metallic state is the composite Fermi-liquid (CFL) theory of the half-filled Landau level. In this paper, we study continuous quantum phase transitions out of the ...

Barkeshli, Maissam

219

Liquid phase thermal swing chemical air separation  

DOE Patents (OSTI)

A temperature swing absorption separation of oxygen from air is performed with an oxygen acceptor of alkali metal nitrate and nitrite. 2 figs.

Erickson, D.C.

1988-05-24T23:59:59.000Z

220

Liquid phase thermal swing chemical air separation  

DOE Patents (OSTI)

A temperature swing absorption separation of oxygen from air is performed with an oxygen acceptor of alkali metal nitrate and nitrite.

Erickson, Donald C. (Annapolis, MD)

1988-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "non-aqueous phase liquid" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Phase Transition in Bose Liquid. I  

Science Journals Connector (OSTI)

......represented graphically as in Fig. 14, where the momenta of closed thick lines in the second term of the right-hand side ex- ceed p0 Tefi does not give rise to singularity in the integrals (7 2) so that it allOWS the USUal perturbation expansion of which......

Shokichi Kanno

1972-12-01T23:59:59.000Z

222

Monolithic Silica Stationary Phases in Liquid Chromatography  

Science Journals Connector (OSTI)

......second peak), trypsin inhibitor (third peak) (60). A...modified subsequently by chitosan and 2,6-sialyllactose...Different ratio of phosphate 97 inhibitors rofecoxib buffer & acetonitrile...determination of cyclooxygenase II inhibitors in human plasma. J. Chromatogr......

Imran Ali; Vinay D. Gaitonde; Hassan Y. Aboul-Enein

2009-07-01T23:59:59.000Z

223

Guidance Document Cryogenic Liquids  

E-Print Network (OSTI)

Guidance Document Cryogenic Liquids [This is a brief and general summary. Read the full MSDS for more details before handling.] Introduction: All cryogenic liquids are gases at normal temperature liquefies them. Cryogenic liquids are kept in the liquid state at very low temperatures. Cryogenic liquids

224

Phase change based cooling for high burst mode heat loads with temperature regulation above the phase change temperature  

DOE Patents (OSTI)

An apparatus and method for transferring thermal energy from a heat load is disclosed. In particular, use of a phase change material and specific flow designs enables cooling with temperature regulation well above the fusion temperature of the phase change material for medium and high heat loads from devices operated intermittently (in burst mode). Exemplary heat loads include burst mode lasers and laser diodes, flight avionics, and high power space instruments. Thermal energy is transferred from the heat load to liquid phase change material from a phase change material reservoir. The liquid phase change material is split into two flows. Thermal energy is transferred from the first flow via a phase change material heat sink. The second flow bypasses the phase change material heat sink and joins with liquid phase change material exiting from the phase change material heat sink. The combined liquid phase change material is returned to the liquid phase change material reservoir. The ratio of bypass flow to flow into the phase change material heat sink can be varied to adjust the temperature of the liquid phase change material returned to the liquid phase change material reservoir. Varying the flowrate and temperature of the liquid phase change material presented to the heat load determines the magnitude of thermal energy transferred from the heat load.

The United States of America as represented by the United States Department of Energy (Washington, DC)

2009-12-15T23:59:59.000Z

225

Non-aqueous electrolyte for lithium-ion battery  

DOE Patents (OSTI)

The present technology relates to stabilizing additives and electrolytes containing the same for use in electrochemical devices such as lithium ion batteries and capacitors. The stabilizing additives include triazinane triones and bicyclic compounds comprising succinic anhydride, such as compounds of Formulas I and II described herein.

Zhang, Lu; Zhang, Zhengcheng; Amine, Khalil

2014-04-15T23:59:59.000Z

226

A liquid film motor  

Science Journals Connector (OSTI)

It is well known that electro-hydrodynamical effects in freely suspended liquid films can force liquids to flow. Here, we report a purely electrically driven rotation in water and some other liquid suspended film...

A. Amjadi; R. Shirsavar; N. Hamedani Radja…

2009-05-01T23:59:59.000Z

227

Effect of polyethylene glycol on the liquidliquid phase transition in aqueous protein solutions  

E-Print Network (OSTI)

Effect of polyethylene glycol on the liquid­liquid phase transition in aqueous protein solutions, 2002 We have studied the effect of polyethylene glycol (PEG) on the liquid­liquid phase separation. PEG ternary mixtures solubility partitioning Polyethylene glycol (PEG) is a hydrophilic nonionic

Annunziata, Onofrio

228

Phase separation in solutions of monoclonal antibodies and the effect of human serum albumin  

E-Print Network (OSTI)

We report the observation of liquid-liquid phase separation in a solution of human monoclonal antibody, IgG2, and the effects of human serum albumin, a major blood protein, on this phase separation. We find a significant ...

Wang, Ying

229

Three-Field versus Three-Phase Flow Models Jean-Marc Herard  

E-Print Network (OSTI)

platform for advanced nuclear thermal-hydraulics, Nuclear Science Engineering, vol. 156, 2007). These codes-field models (in order to account for the dispersed liquid phase, the continuous liquid phase and the vapour

Helluy, Philippe

230

Hydrogen from Bio-Derived Liquids (Presentation)  

NLE Websites -- All DOE Office Websites (Extended Search)

From Bio-Derived Liquids From Bio-Derived Liquids Hydrogen From Bio Hydrogen From Bio - - Derived Liquids Derived Liquids Dave King, Yong Wang, PNNL BILIWIG Meeting Laurel, Maryland November 6, 2007 Innovation / Overview Innovation / Overview Innovation / Overview Project comprises two components z Ethanol steam reforming z Aqueous phase reforming (APR) Importance to small scale hydrogen production for distributed reforming for hydrogen production ‹ Ethanol is rapidly becoming an infrastructure fuel and is a logical feedstock ‹ APR provides vehicle for facile reforming of a variety of bio-derived feedstocks available in the biorefinery that are not conducive to conventional vapor phase reforming Distinctive technology approach/innovation z We are investigating single step ethanol reforming with emphasis on lower

231

Frostbite Theater - Liquid Oxygen vs. Liquid Nitrogen - Liquid Oxygen and  

NLE Websites -- All DOE Office Websites (Extended Search)

Cells vs. Liquid Nitrogen! Cells vs. Liquid Nitrogen! Previous Video (Cells vs. Liquid Nitrogen!) Frostbite Theater Main Index Next Video (Paramagnetism) Paramagnetism Liquid Oxygen and Fire! What happens when nitrogen and oxygen are exposed to fire? [ Show Transcript ] Announcer: Frostbite Theater presents... Cold Cuts! No baloney! Joanna and Steve: Just science! Joanna: Hi! I'm Joanna! Steve: And I'm Steve! Joanna: And this is a test tube of liquid nitrogen! Steve: And this is a test tube of liquid oxygen! Joanna: Let's see what happens when nitrogen and oxygen are exposed to fire. Steve: Fire?! Joanna: Yeah! Steve: Really?! Joanna: Why not! Steve: Okay! Joanna: As nitrogen boils, it changes into nitrogen gas. Because it's so cold, it's denser than the air in the room. The test tube fills up with

232

A Tracer Test Using Ethanol as a Two-Phase Tracer and 2-Naphthalene...  

Open Energy Info (EERE)

navigation, search GEOTHERMAL ENERGYGeothermal Home Conference Proceedings: A Tracer Test Using Ethanol as a Two-Phase Tracer and 2-Naphthalene Sulfonate as a Liquid-Phase...

233

Reservoir-Wellbore Coupled Simulation of Liquid Loaded Gas Well Performance  

E-Print Network (OSTI)

Liquid loading of gas wells causes production difficulty and reduces ultimate recovery from these wells. In 1969, Turner proposed that existence of annular two-phase flow at the wellhead is necessary for the well to avoid liquid loading...

Riza, Muhammad Feldy

2013-11-12T23:59:59.000Z

234

Safetygram #9- Liquid Hydrogen  

Energy.gov (U.S. Department of Energy (DOE))

Hydrogen is colorless as a liquid. Its vapors are colorless, odorless, tasteless, and highly flammable.

235

PHASE TRANSITIONS, CRITICAL PHENOMENA AND EXACTLY SOLVABLE LATTICE MODELS  

E-Print Network (OSTI)

of common everyday expe- rience. If we boil a kettle of water we observe a change of phase from a liquid in a pond change phase from a liquid state to solid ice. Lastly, if a horseshoe magnet is heated passes through the boling (melting) point. Figure 3 shows the phase diagram of a ferromagnetic material

Pearce, Paul A.

236

Method and apparatus for destroying organic contaminants in aqueous liquids  

DOE Patents (OSTI)

A method and apparatus for destroying organic contaminants, such as trichloroethylene, in aqueous liquids, such as groundwater, utilizing steam stripping integrated with biodegradation. The contaminated aqueous liquid is fed into a steam stripper causing the volatilization of essentially all of the organic contaminants and a portion of the aqueous liquid. The majority of the aqueous liquid is discharged from the steam stripper. The volatilized vapors are then condensed to the liquid phase and introduced into a bioreactor. The bioreactor contains methanotrophic microorganisms which convert the organic contaminants into mainly carbon dioxide. The effluent from the bioreactor is then recycled back to the steam stripper for further processing. 2 figures.

Donaldson, T.L.; Wilson, J.H.

1993-09-21T23:59:59.000Z

237

Author's personal copy Physica D 239 (2010) 18551866  

E-Print Network (OSTI)

, such as those occurring during remediation of contaminated soils using brine solutions and during the geological for containing and/or mobilizing dense non-aqueous phase liquids (DNAPLs) in contaminated subsurface systems through the introduction of brine solutions. The success of such techniques relies on the accurate

McLaughlin, Richard M.

238

Received: 12 November 2007 Revised: 19 May 2008 Accepted: 21 May 2008 Published online in Wiley Interscience: (www.interscience.com) DOI 10.1002/jctb.2002  

E-Print Network (OSTI)

. They are heavier than water (specific gravity >1), sinking into ground as dense non-aqueous-phase liquid (DNAPL in Wiley Interscience: (www.interscience.com) DOI 10.1002/jctb.2002 Cleaner water using bimetallic remediation. Palladium- on-gold bimetallic nanoparticles, in contrast, were recently discovered to exhibit

Alvarez, Pedro J.

239

Phase relations in the system NaCl-KCl-H/sub 2/O. III. Solubilities of halite in vapor-saturated liquids above 445/sup 0/C and redetermination of phase equilibrium properties in the system NaCl-H/sub 2/O to 1000/sup 0/C and 1500 bars  

SciTech Connect

Halite solubilities along the three-phase curve in the binary system NaCl-H/sub 2/O determined by differential thermal analysis (DTA) experiment can be represented by the discussed equation where 447 less than or equal to T less than or equal to 800/sup 0/C. Even though these halite solubilities are up to approx. 7 wt.% higher than those reported in literature, extrapolated values at temperatures below 447/sup 0/C merge with the literature values. It is considered that the equation adequately describes halite solubilities between 382 and 800/sup 0/C. The newly established solubility data are believed to be more reliable because they are compatible with data obtained by using synthetic fluid inclusions and with the observed DTA signals and also because they were measured in a relatively corrosion-free system. In an earlier publication the authors were puzzled greatly by multiple and rather unreproducible DTA peaks appearing during isobaric cooling at pressures below about 500 bars. These DTA signals apparently suggested that the halite liquidus swung sharply upward in temperature as pressure decreased from about 500 bars to that of the halite-saturated boiling curve. Further analysis of the data and helpful discussions with several individuals have revealed that the behavior is a consequence of the initial separation of the fluid into NaCl-poor gas and NaCl-rich liquid that failed to homogenize in the short time encompassed by the DTA experiments. The present analysis is based on extrapolations of the dP/dT slopes from pressures above 500 bars.

Chou, I.

1987-07-01T23:59:59.000Z

240

ARM - Measurement - Hydrometeor phase  

NLE Websites -- All DOE Office Websites (Extended Search)

phase phase ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Hydrometeor phase Hydrometeor phase such as liquid ice or mixed phase Categories Cloud Properties Instruments The above measurement is considered scientifically relevant for the following instruments. Refer to the datastream (netcdf) file headers of each instrument for a list of all available measurements, including those recorded for diagnostic or quality assurance purposes. Value-Added Products VISST : Minnis Cloud Products Using Visst Algorithm (Process) VISSTPX04G08V2MINNIS : VISST-derived pixel-level products from satellite GOES8, version 2 VISSTPX04G08V3MINNIS : VISST-derived pixel-level products from satellite GOES8, version 3

Note: This page contains sample records for the topic "non-aqueous phase liquid" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Handbook of Liquid Crystal Research (ed.s Collings, Peter J.; Patel, Jay S.)  

Science Journals Connector (OSTI)

Handbook of Liquid Crystal Research (ed.s Collings, Peter J.; Patel, Jay S.) ... Begins with the fundamentals of the liquid crystalline phase, progresses to a discussion of important parameters in liquid crystalline systems such as electric field and surface effects, and ends with technological aspects of utilizing liquid crystals in displays. ... It is an all-encompassing monograph that provides a link from the fundamental chemistry of liquid crystals to their technological applications. ...

Mark Dadmun

1998-10-01T23:59:59.000Z

242

E-Print Network 3.0 - alpha phase dipalmitoylphosphatidylcholine...  

NLE Websites -- All DOE Office Websites (Extended Search)

or dipalmitoylphosphatidylglycerol (DPPG) bilayers... -to-liquid-crystalline phase transition, the palmitoylated peptide inducing greater immobilisation of the lipid than does......

243

DECOUPLED ENERGY STABLE SCHEMES FOR PHASE-FIELD ...  

E-Print Network (OSTI)

For phase-field models which satisfy a dissipative energy law, it is especially de- sirable to design ...... Liquids, Wiley, New York, 1994. [5] F. Boyer and S.

2014-02-27T23:59:59.000Z

244

Liquid level detector  

DOE Patents (OSTI)

A liquid level detector for low pressure boilers. A boiler tank, from which apor, such as steam, normally exits via a main vent, is provided with a vertical side tube connected to the tank at the desired low liquid level. When the liquid level falls to the level of the side tube vapor escapes therethrough causing heating of a temperature sensitive device located in the side tube, which, for example, may activate a liquid supply means for adding liquid to the boiler tank. High liquid level in the boiler tank blocks entry of vapor into the side tube, allowing the temperature sensitive device to cool, for example, to ambient temperature.

Grasso, Albert P. (Vernon, CT)

1986-01-01T23:59:59.000Z

245

Liquid level detector  

DOE Patents (OSTI)

A liquid level detector for low pressure boilers. A boiler tank, from which vapor, such as steam, normally exits via a main vent, is provided with a vertical side tube connected to the tank at the desired low liquid level. When the liquid level falls to the level of the side tube vapor escapes therethrough causing heating of a temperature sensitive device located in the side tube, which, for example, may activate a liquid supply means for adding liquid to the boiler tank. High liquid level in the boiler tank blocks entry of vapor into the side tube, allowing the temperature sensitive device to cool, for example, to ambient temperature.

Grasso, A.P.

1984-02-21T23:59:59.000Z

246

Phase equilibrium studies  

SciTech Connect

A phase equilibrium model has been developed for the SRC-I process, as well as the other coal liquefaction processes. It is applicable to both vapor/liquid and liquid/liquid equilibria; it also provides an approximate but adequate description of aqueous mixtures where the volatile electrolyte components dissociate to form ionic species. This report completes the description of the model presented in an earlier report (Mathias and Stein, 1983a). Comparisons of the model to previously published data on coal-fluid mixtures are presented. Further, a preliminary analysis of new data on SRC-I coal fluids is presented. Finally, the current capabilities and deficiencies of the model are discussed. 25 references, 17 figures, 30 tables.

Mathias, P.M.; Stein, F.P.

1983-09-01T23:59:59.000Z

247

Glass melter system technologies for vitrification of high-sodium-content low-level, radioactive, liquid wastes: Phase 1, SBS demonstration with simulated low-level waste. Final test report  

SciTech Connect

The attached vendor report was prepared for Westinghouse Hanford Company by Babcock & Wilcox as documentation of the Phase I Final Test Report, Cyclone Combustion Melter Demonstration.

Holmes, M.J.; Scotto, M.V.; Shiao, S.Y. [Babcock & Wilcox, Alliance, OH (United States) Research Center

1995-12-31T23:59:59.000Z

248

Viscosity, specific (for liquids)  

Science Journals Connector (OSTI)

n. The ratio between the viscosity of a liquid and the viscosity of water at the same temperature. Specific viscosity is sometimes used interchangeably with relative viscosity for liquids.

2007-01-01T23:59:59.000Z

249

Dehydrogenation of liquid fuel in microchannel catalytic reactor  

DOE Patents (OSTI)

The present invention is an improved process for the storage and delivery of hydrogen by the reversible hydrogenation/dehydrogenation of an organic compound wherein the organic compound is initially in its hydrogenated state. The improvement in the route to generating hydrogen is in the dehydrogenation step and recovery of the dehydrogenated organic compound resides in the following steps: introducing a hydrogenated organic compound to a microchannel reactor incorporating a dehydrogenation catalyst; effecting dehydrogenation of said hydrogenated organic compound under conditions whereby said hydrogenated organic compound is present as a liquid phase; generating a reaction product comprised of a liquid phase dehydrogenated organic compound and gaseous hydrogen; separating the liquid phase dehydrogenated organic compound from gaseous hydrogen; and, recovering the hydrogen and liquid phase dehydrogenated organic compound.

Toseland, Bernard Allen (Coopersburg, PA); Pez, Guido Peter (Allentown, PA); Puri, Pushpinder Singh (Emmaus, PA)

2010-08-03T23:59:59.000Z

250

Liquid Piston Stirling Engines  

Science Journals Connector (OSTI)

The Fluidyne liquid piston engine is a simple free-piston Stirling engine that can be made from nothing more...

Graham Walker Ph. D.; J. R. Senft Ph.D.

1985-01-01T23:59:59.000Z

251

Alkyl Chain Ordering of Asymmetric Phosphatidylcholines Adsorbed at a Liquid-Liquid B. L. Smiley and G. L. Richmond*  

E-Print Network (OSTI)

Alkyl Chain Ordering of Asymmetric Phosphatidylcholines Adsorbed at a Liquid-Liquid Interface B. L chain ordering in phosphatidylcholines (PCs) adsorbed from aqueous solution to a carbon tetrachloride-dimensional phases are discussed. Introduction Surfactant monolayers adsorbed at oil-water interfaces in biological

Richmond, Geraldine L.

252

Understanding the importance of the viscosity contrast between the sample solvent plug and the mobile phase and its potential consequences in two-dimensional high-performance liquid chromatography  

SciTech Connect

The effect of solvent viscosity mismatch on elution performance in reversed-phase HPLC was studied using moment analysis. Two conditions were tested: (1) the mobile phase viscosity was less than the injection plug viscosity, and (2) the mobile phase viscosity was greater than the injection plug viscosity. Under the first condition, retention time and elution performance decreased as the viscosity contrast between the mobile phase and injection plug increased. The effect on performance was more marked as the injection volume increased. A decrease in performance of 12% for compounds with retention factors up to 2.8 was apparent even when the viscosity contrast was only 0.165 cP. In the second set of conditions, elution performance was actually observed to increase, by as much as 25% for a 40 {micro}L injection, as the viscosity contrast between the mobile phase and the solute plug increased. No change in the retention factor was observed. This behaviour was attributed to the shape of an injection plug as it enters into the column, whereby a low viscosity plug permeates away from the wall when the column contains a higher viscosity mobile phase, and vice a versa for a high viscosity plug entering a low viscosity mobile phase. At no stage was either a band splitting or shoulders observed with viscosity contrasts up to 1.283 cP, as could have been expected.

Shalliker, R. Andrew [University of Western Sydney, Australia; Guiochon, Georges A [ORNL

2009-01-01T23:59:59.000Z

253

Two phase flow in capillary tubes  

E-Print Network (OSTI)

The flow of two phases, gas and liquid, has been studied in horizontal tubes of capillary diameter. The flow has been primarily studied in the regime where the gas flows as long bubbles separated from the wall of the tube ...

Suo, Mikio

1963-01-01T23:59:59.000Z

254

Liquid Wall Chambers  

SciTech Connect

The key feature of liquid wall chambers is the use of a renewable liquid layer to protect chamber structures from target emissions. Two primary options have been proposed and studied: wetted wall chambers and thick liquid wall (TLW) chambers. With wetted wall designs, a thin layer of liquid shields the structural first wall from short ranged target emissions (x-rays, ions and debris) but not neutrons. Various schemes have been proposed to establish and renew the liquid layer between shots including flow-guiding porous fabrics (e.g., Osiris, HIBALL), porous rigid structures (Prometheus) and thin film flows (KOYO). The thin liquid layer can be the tritium breeding material (e.g., flibe, PbLi, or Li) or another liquid metal such as Pb. TLWs use liquid jets injected by stationary or oscillating nozzles to form a neutronically thick layer (typically with an effective thickness of {approx}50 cm) of liquid between the target and first structural wall. In addition to absorbing short ranged emissions, the thick liquid layer degrades the neutron flux and energy reaching the first wall, typically by {approx}10 x x, so that steel walls can survive for the life of the plant ({approx}30-60 yrs). The thick liquid serves as the primary coolant and tritium breeding material (most recent designs use flibe, but the earliest concepts used Li). In essence, the TLW places the fusion blanket inside the first wall instead of behind the first wall.

Meier, W R

2011-02-24T23:59:59.000Z

255

A Phase-Field Model for Phase Transformations in Glass-Forming Alloys  

SciTech Connect

A phase-field model is proposed for phase transformations in glass-forming alloys. The glass transition is introduced as a structural relaxation, and the competition between the glass and crystalline phases is investigated. The simulations are performed for Cu-Zr alloys, employing thermodynamic and kinetic parameters derived from reported thermodynamic modeling and molecular dynamics simulation results,[1–3] respectively. Four distinct phase fields are treated with a multi-phase-field approach, representing the liquid/glass, Cu10Zr7, CuZr, and CuZr2 phases. In addition, a continuum-field method is applied to the liquid to accommodate the liquid–glass transformation. The combined phase-field approach is used to investigate the glass formation tendency, and critical cooling rates are estimated and compared with the reported experimental values.

Wang, Tao; Napolitano, Ralph E.

2012-03-24T23:59:59.000Z

256

Numerical modeling of the ignition of a liquid hydrocarbon layer by a radiant heat pulse  

Science Journals Connector (OSTI)

A gas-phase model of radiative ignition of a flammable liquid is developed, allowing for absorption of the radiant flux in the gas phase. Using motor fuels (gasoline and diesel fuel), as examples, we demonstra...

Yu. V. Agabekov; F. G. Yagafarov

257

Phase five  

NLE Websites -- All DOE Office Websites (Extended Search)

Phase five Phase five 1663 Los Alamos science and technology magazine Latest Issue:November 2013 All Issues » submit Phase five Los Alamos physicists have conclusively demonstrated the existence of a new phase of matter. November 25, 2013 Phase five Scientists still have more to learn about the exotic physics of specialty materials. What makes the cuprates special? How about a new phase of matter. Ceramic metals known as cuprates have mystified physicists for decades. They exhibit a variety of distinct phases of matter, each with its own specific properties, including a phase bearing an exotic type of magnetism, a high-temperature superconducting phase, an ordinary metal phase, a poorly understood and weird metallic phase simply called a strange metal, and an equally poorly understood metallic phase known as the pseudogap. The

258

Liquid level detector  

DOE Patents (OSTI)

A liquid level detector for conductive liquids for vertical installation in a tank, the detector having a probe positioned within a sheath and insulated therefrom by a seal so that the tip of the probe extends proximate to but not below the lower end of the sheath, the lower end terminating in a rim that is provided with notches, said lower end being tapered, the taper and notches preventing debris collection and bubble formation, said lower end when contacting liquid as it rises will form an airtight cavity defined by the liquid, the interior sheath wall, and the seal, the compression of air in the cavity preventing liquid from further entry into the sheath and contact with the seal. As a result, the liquid cannot deposit a film to form an electrical bridge across the seal.

Tshishiku, Eugene M. (Augusta, GA)

2011-08-09T23:59:59.000Z

259

Ultrasonic liquid level detector  

DOE Patents (OSTI)

An ultrasonic liquid level detector for use within a shielded container, the detector being tubular in shape with a chamber at its lower end into which liquid from in the container may enter and exit, the chamber having an ultrasonic transmitter and receiver in its top wall and a reflector plate or target as its bottom wall whereby when liquid fills the chamber a complete medium is then present through which an ultrasonic wave may be transmitted and reflected from the target thus signaling that the liquid is at chamber level.

Kotz, Dennis M. (North Augusta, SC); Hinz, William R. (Augusta, GA)

2010-09-28T23:59:59.000Z

260

Electric field controlled emulsion phase contactor  

DOE Patents (OSTI)

A system is described for contacting liquid phases comprising a column for transporting a liquid phase contacting system, the column having upper and lower regions. The upper region has a nozzle for introducing a dispersed phase and means for applying thereto a vertically oriented high intensity pulsed electric field. This electric field allows improved flow rates while shattering the dispersed phase into many micro-droplets upon exiting the nozzle to form a dispersion within a continuous phase. The lower region employs means for applying to the dispersed phase a horizontally oriented high intensity pulsed electric field so that the dispersed phase undergoes continuous coalescence and redispersion while being urged from side to side as it progresses through the system, increasing greatly the mass transfer opportunity. 5 figs.

Scott, T.C.

1995-01-31T23:59:59.000Z

Note: This page contains sample records for the topic "non-aqueous phase liquid" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Liquid heat capacity lasers  

DOE Patents (OSTI)

The heat capacity laser concept is extended to systems in which the heat capacity lasing media is a liquid. The laser active liquid is circulated from a reservoir (where the bulk of the media and hence waste heat resides) through a channel so configured for both optical pumping of the media for gain and for light amplification from the resulting gain.

Comaskey, Brian J. (Walnut Creek, CA); Scheibner, Karl F. (Tracy, CA); Ault, Earl R. (Livermore, CA)

2007-05-01T23:59:59.000Z

262

Carbon monoxide absorbing liquid  

SciTech Connect

The present disclosure is directed to a carbon monoxide absorbing liquid containing a cuprous ion, hydrochloric acid and titanum trichloride. Titanium trichloride is effective in increasing the carbon monoxide absorption quantity. Furthermore, titanium trichloride remarkably increases the oxygen resistance. Therefore, this absorbing liquid can be used continuously and for a long time.

Arikawa, Y.; Horigome, S.; Kanehori, K.; Katsumoto, M.

1981-07-07T23:59:59.000Z

263

Precision liquid level sensor  

DOE Patents (OSTI)

A precision liquid level sensor utilizes a balanced R. F. bridge, each arm including an air dielectric line. Changes in liquid level along one air dielectric line imbalance the bridge and create a voltage which is directly measurable across the bridge.

Field, Michael E. (Albuquerque, NM); Sullivan, William H. (Albuquerque, NM)

1985-01-01T23:59:59.000Z

264

Liquid and liquid–gas flows at all speeds  

SciTech Connect

All speed flows and in particular low Mach number flow algorithms are addressed for the numerical approximation of the Kapila et al. [1] multiphase flow model. This model is valid for fluid mixtures evolving in mechanical equilibrium but out of temperature equilibrium and is efficient for material interfaces computation separating miscible and non-miscible fluids. In this context, the interface is considered as a numerically diffused zone, captured as well as all present waves (shocks, expansion waves). The same flow model can be used to solve cavitating and boiling flows [2]. Many applications occurring with liquid–gas interfaces and cavitating flows involve a very wide range of Mach number, from 10{sup ?3} to supersonic (and even hypersonic) conditions with respect to the mixture sound speed. It is thus important to address numerical methods free of restrictions regarding the Mach number. To do this, a preconditioned Riemann solver is built and embedded into the Godunov explicit scheme. It is shown that this method converges to exact solutions but needs too small time steps to be efficient. An implicit version is then derived, first in one dimension and second in the frame of 2D unstructured meshes. Two-phase flow preconditioning is then addressed in the frame of the Saurel et al. [3] algorithm. Modifications of the preconditioned Riemann solver are needed and detailed. Convergence of both single phase and two-phase numerical solutions are demonstrated with the help of single phase and two-phase steady nozzle flow solutions. Last, the method is illustrated by the computation of real cavitating flows in Venturi nozzles. Vapour pocket size and instability frequencies are reproduced by the model and method without using any adjustable parameter.

LeMartelot, S., E-mail: sebastien.lemartelot@polytech.univ-mrs.fr [Polytech'Marseille, Aix-Marseille University, UMR CNRS 7343 IUSTI, 5 rue E. Fermi, 13453 Marseille Cedex 13 (France); Nkonga, B., E-mail: boniface.nkonga@unice.fr [RS2N, Bastidon de la Caou, 13360 Roquevaire (France); University of Nice, LJAD UMR CNRS 7351, Parc Valrose, 06108 Nice Cedex (France); Saurel, R., E-mail: richard.saurel@polytech.univ-mrs.fr [Polytech'Marseille, Aix-Marseille University, UMR CNRS 7343 IUSTI, 5 rue E. Fermi, 13453 Marseille Cedex 13 (France); RS2N, Bastidon de la Caou, 13360 Roquevaire (France); University Institute of France, 5 rue E. Fermi, 13453 Marseille Cedex 13 (France)

2013-12-15T23:59:59.000Z

265

Verification of universal surface scaling behavior in critical binary liquid mixtures with neutron and x-ray reflectometry.  

E-Print Network (OSTI)

??We have studied two critical binary liquid mixtures in the mixed phase regime with x-ray and neutron reflectometry to verify universal critical scaling at a… (more)

Brown, Matthew D.

2007-01-01T23:59:59.000Z

266

CONDENSATION AND EVAPORATION FOR THERMALLY UNEQUILIBRATED PHASES  

E-Print Network (OSTI)

CONDENSATION AND EVAPORATION FOR THERMALLY UNEQUILIBRATED PHASES R. A. Marcus1 , A. V. Fedkin2-K) equation for the rate of condensation of a gas or evaporation of a solid or liquid is used for systems, Tg, differs from that of the condensed phase, Ts . Here, we modify the H-K equation for this case

Grossman, Lawrence

267

Liquid Fuels Market Module  

U.S. Energy Information Administration (EIA) Indexed Site

Liquid Fuels Market Module Liquid Fuels Market Module This page inTenTionally lefT blank 145 U.S. Energy Information Administration | Assumptions to the Annual Energy Outlook 2013 Liquid Fuels Market Module The NEMS Liquid Fuels Market Module (LFMM) projects petroleum product prices and sources of supply for meeting petroleum product demand. The sources of supply include crude oil (both domestic and imported), petroleum product imports, unfinished oil imports, other refinery inputs (including alcohols, ethers, esters, corn, biomass, and coal), natural gas plant liquids production, and refinery processing gain. In addition, the LFMM projects capacity expansion and fuel consumption at domestic refineries. The LFMM contains a linear programming (LP) representation of U.S. petroleum refining

268

Reading Comprehension - Liquid Nitrogen  

NLE Websites -- All DOE Office Websites (Extended Search)

Liquid Nitrogen Liquid Nitrogen Nitrogen is the most common substance in Earth's _________ crust oceans atmosphere trees . In the Earth's atmosphere, nitrogen is a gas. The particles of a gas move very quickly. They run around and bounce into everyone and everything. The hotter a gas is, the _________ slower faster hotter colder the particles move. When a gas is _________ cooled warmed heated compressed , its particles slow down. If a gas is cooled enough, it can change from a gas to a liquid. For nitrogen, this happens at a very _________ strange warm low high temperature. If you want to change nitrogen from a gas to a liquid, you have to bring its temperature down to 77 Kelvin. That's 321 degrees below zero _________ Kelvin Celsius Centigrade Fahrenheit ! Liquid nitrogen looks like water, but it acts very differently. It

269

Metamorphosis: Phases of UF{sub 6}  

SciTech Connect

A 15-minute videotape is presented. The subject matter is 150 grams of UF{sub 6} sealed in a glass tube. Close-up views show the UF{sub 6} as phase changes are effected by the addition or removal of heat from the closed system. The solid-to-liquid transition is shown as heat is added, both slowly and rapidly. The solid phases which result from freezing and from desublimation are contrasted. In the solid state, uranium hexafluoride is a nearly-white, dense crystalline solid. The appearance of this solid depends on whether it is formed by freezing from the liquid or by desublimation from the vapor phase. If frozen from the liquid, the solid particles take the form of irregularly shaped coarse grains, while the solid product of desublimation tends to be a rather formless mass without individually distinguishable particles. The changes in state are presented in terms of the UF{sub 6} phase diagram.

Dyer, R.H. [Department of Energy, Oak Ridge, TN (United States)

1991-12-31T23:59:59.000Z

270

Method and apparatus for the removal of bioconversion of constituents of organic liquids  

DOE Patents (OSTI)

A method and apparatus for the removal or conversion of constituents from bulk organic liquids. A countercurrent biphasic bioreactor system is utilized to disperse and recoalesce a biocatalyst contained in the aqueous liquid phase into the organic liquid phase containing the constituent. Two transient, high-intensity electrical fields rupture the aqueous drops into a plurality of microdroplets and induce continuous coalescence and redispersion as the microdroplets travel through the organic phase, thus increasing surface area. As the aqueous microdroplets progress through the organic phase, the biocatalyst then reacts with the constituent to produce a product which is then removed from the bioreactor in the aqueous phase or retained in the organic phase. The organic liquid, now free of the original constituents, is ready for immediate use or further processing.

Scott, Timothy (Knoxville, TN); Scott, Charles D. (Oak Ridge, TN)

1994-01-01T23:59:59.000Z

271

Air Liquide - Biogas & Fuel Cells  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Liquide - Biogas & Fuel Cells Hydrogen Energy Biogas Upgrading Technology 12 June 2012 Charlie.Anderson@airliquide.com 2 Air Liquide, world leader in gases for industry,...

272

Sandia National Laboratories: ionic liquid  

NLE Websites -- All DOE Office Websites (Extended Search)

liquid Biofuels Blend Right In: Researchers Show Ionic Liquids Effective for Pretreating Mixed Blends of Biofuel Feedstocks On February 26, 2013, in Biofuels, Biomass, Energy,...

273

Liquid sampling system  

DOE Patents (OSTI)

A conduit extends from a reservoir through a sampling station and back to the reservoir in a closed loop. A jet ejector in the conduit establishes suction for withdrawing liquid from the reservoir. The conduit has a self-healing septum therein upstream of the jet ejector for receiving one end of a double-ended cannula, the other end of which is received in a serum bottle for sample collection. Gas is introduced into the conduit at a gas bleed between the sample collection bottle and the reservoir. The jet ejector evacuates gas from the conduit and the bottle and aspirates a column of liquid from the reservoir at a high rate. When the withdrawn liquid reaches the jet ejector the rate of flow therethrough reduces substantially and the gas bleed increases the pressure in the conduit for driving liquid into the sample bottle, the gas bleed forming a column of gas behind the withdrawn liquid column and interrupting the withdrawal of liquid from the reservoir. In the case of hazardous and toxic liquids, the sample bottle and the jet ejector may be isolated from the reservoir and may be further isolated from a control station containing remote manipulation means for the sample bottle and control valves for the jet ejector and gas bleed. 5 figs.

Larson, L.L.

1984-09-17T23:59:59.000Z

274

Liquid sampling system  

DOE Patents (OSTI)

A conduit extends from a reservoir through a sampling station and back to the reservoir in a closed loop. A jet ejector in the conduit establishes suction for withdrawing liquid from the reservoir. The conduit has a self-healing septum therein upstream of the jet ejector for receiving one end of a double-ended cannula, the other end of which is received in a serum bottle for sample collection. Gas is introduced into the conduit at a gas bleed between the sample collection bottle and the reservoir. The jet ejector evacuates gas from the conduit and the bottle and aspirates a column of liquid from the reservoir at a high rate. When the withdrawn liquid reaches the jet ejector the rate of flow therethrough reduces substantially and the gas bleed increases the pressure in the conduit for driving liquid into the sample bottle, the gas bleed forming a column of gas behind the withdrawn liquid column and interrupting the withdrawal of liquid from the reservoir. In the case of hazardous and toxic liquids, the sample bottle and the jet ejector may be isolated from the reservoir and may be further isolated from a control station containing remote manipulation means for the sample bottle and control valves for the jet ejector and gas bleed.

Larson, Loren L. (Idaho Falls, ID)

1987-01-01T23:59:59.000Z

275

Liquid-level detector  

DOE Patents (OSTI)

Aliquid level sensor is described which has a pair of upright conductors spaced by an insulator defining a first high resistance path between the conductors. An electrically conductive path is interposed between the upright conductors at a discrete location at which liquid level is to be measured. It includes a liquid accessible gap of a dimension such that the electrical resistance across the conductor when the gap is filled with the liquid is detectably less than when the gap is emptied. The conductor might also be physically altered by temperature changes to serve also as an indicator of elevated temperature.

Not Available

1981-01-29T23:59:59.000Z

276

Liquid metal electric pump  

DOE Patents (OSTI)

An electrical pump for pumping liquid metals to high pressures in high temperature environments without the use of magnets or moving mechanical parts. The pump employs a non-porous solid electrolyte membrane, typically ceramic, specific to the liquid metal to be pumped. A DC voltage is applied across the thickness of the membrane causing ions to form and enter the membrane on the electrically positive surface, with the ions being neutralized on the opposite surface. This action provides pumping of the liquid metal from one side of the non-porous solid electrolyte membrane to the other. 3 figs.

Abbin, J.P.; Andraka, C.E.; Lukens, L.L.; Moreno, J.B.

1992-01-14T23:59:59.000Z

277

Structure of a liquid crystalline fluid around a macroparticle: Density functional theory study  

E-Print Network (OSTI)

The structure of a molecular liquid, in both the nematic liquid crystalline and isotropic phases, around a cylindrical macroparticle, is studied using density functional theory. In the nematic phase the structure of the fluid is highly anisotropic with respect to the director, in agreement with results from simulation and phenomenological theories. On going into the isotropic phase the structure becomes rotationally invariant around the macroparticle with an oriented layer at the surface.

David L. Cheung; Michael P. Allen

2006-04-10T23:59:59.000Z

278

Surface Crystallization in a Liquid AuSi Alloy  

SciTech Connect

X-ray measurements reveal a crystalline monolayer at the surface of the eutectic liquid Au{sub 82}Si{sub 18}, at temperatures above the alloy's melting point. Surface-induced atomic layering, the hallmark of liquid metals, is also found below the crystalline monolayer. The layering depth, however, is threefold greater than that of all liquid metals studied to date. The crystallinity of the surface monolayer is notable, considering that AuSi does not form stable bulk crystalline phases at any concentration and temperature and that no crystalline surface phase has been detected thus far in any pure liquid metal or nondilute alloy. These results are discussed in relation to recently suggested models of amorphous alloys.

Shpyrko,O.; Streitel, R.; Balagurusamy, V.; Grigoriev, A.; Deutsch, M.; Ocko, B.; Meron, M.; Lin, B.; Pershan, P.

2006-01-01T23:59:59.000Z

279

phase coherence  

Science Journals Connector (OSTI)

The state in which two signals, such as electronic or optical signals, maintain (a) a fixed phase relationship with each other or (b) a fixed phase relationship with a third signal that can serve as a referenc...

2001-01-01T23:59:59.000Z

280

Renewable Liquid Fuels Reforming  

Energy.gov (U.S. Department of Energy (DOE))

The Program anticipates that distributed reforming of biomass-derived liquid fuels could be commercial during the transition to hydrogen and used in the mid- and long-term time frames.

Note: This page contains sample records for the topic "non-aqueous phase liquid" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

U.S. Department of Energy Categorical Exclusion Determination Form  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Dense Non-Aqueous Phase Liquid (DNAPL) Characterization at the M-Area Settling Basin Western Sector Treatment System (WSTS) Dense Non-Aqueous Phase Liquid (DNAPL) Characterization at the M-Area Settling Basin Western Sector Treatment System (WSTS) Savannah River Site Aiken/Aiken/South Carolina Soil bores will be advanced with a Rotosonic drilling rig to confirm the effectiveness of the Western Sector Dynamic Underground Stripping (DUS) project at the M-Area Settling Basin. Replacement monitoring wells will also be installed as part of this effort. These groundwater monitoring wells will replace wells that were abandoned due to the installation and / or operation of the DUS system. Now that the heating phase has ended the DUS is transitioning to the Western Sector Treatment System (WSTS). B3.1 - Site characterization and environmental monitoring Andrew R. Grainger

282

An upper bound on the coarsening rate for mushy zones in a phase-field model  

E-Print Network (OSTI)

Phase field models are used to describe the solid-liquid phase transition of a pure material by means times and the energetic contributions of temperature fluctuations compared to phase changes. We supply of phase change processes initiated by spinodal decomposi- tion, or certain heterogeneously nucleated phase

Dai, Shibin

283

Removing sulphur oxides from a fluid stream  

DOE Patents (OSTI)

A process for removing sulphur oxides from a fluid stream, such as flue gas, comprising: providing a non-aqueous absorption liquid containing at least one hydrophobic amine, the liquid being incompletely miscible with water; treating the fluid stream in an absorption zone with the non-aqueous absorption liquid to transfer at least part of the sulphur oxides into the non-aqueous absorption liquid and to form a sulphur oxide-hydrophobic amine-complex; causing the non-aqueous absorption liquid to be in liquid-liquid contact with an aqueous liquid whereby at least part of the sulphur oxide-hydrophobic amine-complex is hydrolyzed to release the hydrophobic amine and sulphurous hydrolysis products, and at least part of the sulphurous hydrolysis products is transferred into the aqueous liquid; separating the aqueous liquid from the non-aqueous absorption liquid. The process mitigates absorbent degradation problems caused by sulphur dioxide and oxygen in flue gas.

Katz, Torsten; Riemann, Christian; Bartling, Karsten; Rigby, Sean Taylor; Coleman, Luke James Ivor; Lail, Marty Alan

2014-04-08T23:59:59.000Z

284

Frostbite Theater - Liquid Nitrogen Experiments - Dry Ice vs. Liquid  

NLE Websites -- All DOE Office Websites (Extended Search)

Egg + Liquid Nitrogen + Time-lapse! Egg + Liquid Nitrogen + Time-lapse! Previous Video (Egg + Liquid Nitrogen + Time-lapse!) Frostbite Theater Main Index Next Video (Liquid Nitrogen Cooled Dry Ice in Water!) Liquid Nitrogen Cooled Dry Ice in Water! Dry Ice vs. Liquid Nitrogen! Dry ice is cold. Liquid nitrogen is cold, too. What happens when the two are mixed together? [ Show Transcript ] Announcer: Frostbite Theater presents... Cold Cuts! No baloney! Joanna and Steve: Just science! Joanna: Hi! I'm Joanna! Steve: And I'm Steve! Joanna: Have you ever wondered what happens when you mix dry ice and liquid nitrogen? Steve: Well, we just happen to have a chunk of dry ice left over from when we filmed 'How to Make a Cloud Chamber,' and here at Jefferson Lab, liquid nitrogen flows like water, so we're going to find out!

285

Measurement and correlation of phase equilibria for (water + aromatic hydrocarbon) binary mixtures at T = (573 to 623) K using microfluidic mixing  

Science Journals Connector (OSTI)

(Vapour + liquid) and (liquid + liquid) equilibria for (water + p-xylene) and (water + decalin) mixtures at T = (573 to 623) K were measured by a flow type apparatus with microfluidic system. The liquid–liquid slug flows in the microfluidic system were used for mixing of water and hydrocarbon due to high mass transfer between two liquid phases. The formations of the liquid–liquid slugs for (water + p-xylene) system were studied by changing the flow rate. The results of the liquid–liquid slug formations at hydrocarbon and water rich compositions were used for the measurements for (vapour + liquid) and (liquid + liquid) equilibria, respectively. It was found that the phase equilibria using the apparatus with the microfluidic system can be measured in a short residential time (1.6 to 3.2) min. The experimental results of the phase equilibria for (water + p-xylene) and (water + decalin) systems give that the regions of the (vapour + liquid) and (liquid + liquid) equilibria for both mixtures reduce with the increasing temperature. The mixture of (water + decalin) at T = (583 to 623) K forms the two phase regions of the (vapour + liquid) and (liquid + liquid) equilibria larger than those for (water + p-xylene) mixture. The experimental data of the phase equilibria obtained in this work were correlated with Peng–Robinson–Stryjek–Vera equation of state. The correlated results of the (liquid + liquid) equilibria for both systems represent the experimental data. For (vapour + liquid) equilibria, the results give the qualitative representations in the shape of the two phase region for both mixtures.

Masaki Togo; Taisuke Maeda; Akira Ito; Yusuke Shimoyama

2013-01-01T23:59:59.000Z

286

Two component absorption/phase separation chemical heat pump to provide temperature amplification to waste heat streams  

DOE Patents (OSTI)

A chemical heat pump that utilizes liquid/liquid phase separation rather than evaporation to separate two components in a heat of mixing chemical heat pump process. 3 figs.

Scott, T.C.; Kaplan, S.I.

1987-09-04T23:59:59.000Z

287

Local energy landscape in a simple liquid  

Science Journals Connector (OSTI)

It is difficult to relate the properties of liquids and glasses directly to their structure because of complexity in the structure that defies precise definition. The potential energy landscape (PEL) approach is a very insightful way to conceptualize the structure-property relationship in liquids and glasses, particularly the effect of temperature and history. However, because of the highly multidimensional nature of the PEL it is hard to determine, or even visualize, the actual details of the energy landscape. In this article we introduce a modified concept of the local energy landscape (LEL), which is limited in phase space, and demonstrate its usefulness using molecular dynamics simulation on a simple liquid at high temperatures. The local energy landscape is given as a function of the local coordination number, the number of the nearest-neighbor atoms. The excitation in the LEL corresponds to the so-called ?-relaxation process. The LEL offers a simple but useful starting point to discuss complex phenomena in liquids and glasses.

T. Iwashita and T. Egami

2014-11-26T23:59:59.000Z

288

Local Energy Landscape in a Simple Liquid  

E-Print Network (OSTI)

It is difficult to relate the properties of liquids and glasses directly to their structure because of complexity in the structure which defies precise definition. The potential energy landscape (PEL) approach is a very insightful way to conceptualize the structure-property relationship in liquids and glasses, particularly on the effect of temperature and history. However, because of the highly multi-dimensional nature of the PEL it is hard to determine, or even visualize, the actual details of the energy landscape. In this article we introduce a modified concept of the local energy landscape (LEL) which is limited in phase space, and demonstrate its usefulness using molecular dynamics simulation on a simple liquid at high temperatures. The local energy landscape is given as a function of the local coordination number, the number of the nearest neighbor atoms. The excitations in the LEL corresponds to the so-called beta-relaxation process. The LEL offers a simple but useful starting point to discuss complex phenomena in liquids and glasses.

Takuya Iwashita; Takeshi Egami

2014-10-31T23:59:59.000Z

289

A Tracer Test Using Ethanol as a Two-Phase Tracer and 2-Naphthalene  

Open Energy Info (EERE)

Tracer Test Using Ethanol as a Two-Phase Tracer and 2-Naphthalene Tracer Test Using Ethanol as a Two-Phase Tracer and 2-Naphthalene Sulfonate as a Liquid-Phase Tracer at the Coso Geothermal Field Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Conference Proceedings: A Tracer Test Using Ethanol as a Two-Phase Tracer and 2-Naphthalene Sulfonate as a Liquid-Phase Tracer at the Coso Geothermal Field Details Activities (1) Areas (1) Regions (0) Abstract: A tracer test was conducted at the Coso geothermal field in order to characterize the flow patterns of fluid injected into well 68-20RD. A conservative liquid phase tracer, 2-naphthalene sulfonate, and a two-phase tracer, ethanol, were injected into well 68-20RD. Surrounding production wells were sampled over the subsequent 125 days and analyzed for the two tracers. The liquid-phase tracer showed negligible returns, whereas the

290

Synergism by co-assembly at the origin of ion selectivity in liquid-liquid extraction  

SciTech Connect

In liquid-liquid extraction, synergism emerges when for a defined formulation of the solvent phase, there is an increase of distribution coefficients for some cations in a mixture. To characterize the synergistic mechanisms, we determine the free energy of mixed co-assembly in aggregates. Aggregation in any point of a phase diagram can be followed not only structurally by SANS, SAXS, and SLS, but also thermodynamically by determining the concentration of monomers coexisting with reverse aggregates. Using the industrially used couple HDEHP/TOPO forming mixed reverse aggregates, and the representative couple U/Fe, we show that there is no peculiarity in the aggregates microstructure at the maximum of synergism. Nevertheless, the free energy of aggregation necessary to form mixed aggregates containing extracted ions in their polar core is comparable to the transfer free energy difference between target and nontarget ions, as deduced from the synergistic selectivity peak. (authors)

Dourdain, S.; Hofmeister, I.; Dufreche, J.F.; Turgis, R.; Pellet-Rostaing, S.; Zemb, T. [CEA CNRS UM2 ENSCM UMR5257, ICSM LTSM, F-30207 Bagnols Sur Ceze, (France); Pecheur, O.; Leydier, A. [CEA, Nucl Energy Div, RadioChem and Proc Dept, F-30207 Bagnols Sur Ceze, (France); Jestin, J. [CEA Saclay, Lab Leon Brillouin CEA CNRS, F-91191 Gif Sur Yvette, (France); Testard, F. [CEA Saclay, DSM IRAMIS LIONS SIS2M, F-91191 Gif Sur Yvette, (France)

2012-08-15T23:59:59.000Z

291

Phase change material storage heater  

DOE Patents (OSTI)

A storage heater for storing heat and for heating a fluid, such as water, has an enclosure defining a chamber therein. The chamber has a lower portion and an upper portion with a heating element being disposed within the enclosure. A tube through which the fluid flows has an inlet and an outlet, both being disposed outside of the enclosure, and has a portion interconnecting the inlet and the outlet that passes through the enclosure. A densely packed bed of phase change material pellets is disposed within the enclosure and is surrounded by a viscous liquid, such as propylene glycol. The viscous liquid is in thermal communication with the heating element, the phase change material pellets, and the tube and transfers heat from the heating element to the pellets and from the pellets to the tube. The viscous fluid has a viscosity so that the frictional pressure drop of the fluid in contact with the phase change material pellets substantially reduces vertical thermal convection in the fluid. As the fluid flows through the tube heat is transferred from the viscous liquid to the fluid flowing through the tube, thereby heating the fluid.

Goswami, D. Yogi (Gainesville, FL); Hsieh, Chung K. (Gainesville, FL); Jotshi, Chand K. (Gainesville, FL); Klausner, James F. (Gainesville, FL)

1997-01-01T23:59:59.000Z

292

Liquid Scintillator Purification  

SciTech Connect

The KamLAND collaboration has studied background requirements and purification methods needed to observe the 7Be neutrino from the sun. First we will discuss the present background situation in KamLAND where it is found that the main background components are 210Pb and 85Kr. It is then described how to purify the liquid scintillator. The present status and results on how to remove 210Pb from the liquid scintillator are discussed. Specifically, the detailed analysis of the effects of distillation and adsorption techniques are presented.

Kishimoto, Y. [Research Center for Neutrino Science, Tohoku University (Japan)

2005-09-08T23:59:59.000Z

293

Microphysical Properties of Single and Mixed-Phase Arctic Clouds...  

NLE Websites -- All DOE Office Websites (Extended Search)

droplets in liquid-only and mid-phase clouds, a lack of temperature dependence in the ice fraction for temperatures above 240 K, seasonal trends in the optical depth with the...

294

Frostbite Theater - Liquid Nitrogen Experiments - Liquid Nitrogen in a  

NLE Websites -- All DOE Office Websites (Extended Search)

Freeze Liquid Nitrogen! Freeze Liquid Nitrogen! Previous Video (Let's Freeze Liquid Nitrogen!) Frostbite Theater Main Index Next Video (Freeze the Rainbow!) Freeze the Rainbow! Liquid Nitrogen in a Microwave! What happens when the world's most beloved cryogenic liquid meets one of the most common household appliances? Find out when we try to microwave liquid nitrogen! [ Show Transcript ] Announcer: Frostbite Theater presents... Cold Cuts! No baloney! Joanna and Steve: Just science! Joanna: Hi! I'm Joanna! Steve: And I'm Steve! Joanna: A little while ago we received an email from Star of the Sea Catholic School in Virginia Beach, Virginia, asking what happens when you place liquid nitrogen in a microwave. Well, I just happen to have some liquid nitrogen! Steve: And I just happen to have a microwave!

295

Lyophilic liquid porosimetry and a new liquid autoporosimeter  

SciTech Connect

Lyophilic liquid porosimetry determines the volumes of different size pores by measuring the amount of liquid in these pores, thus, providing pore volume distribution (PVD) data for porous structures. Any liquid that wets the sample may be used. This opens unique opportunities for porous structure evaluation. It provides realistic PVD analysis when the liquid of interest changes the porous structure. It determines uptake/drainage hysteresis of real liquids. It allows direct measurements of uptake and retention capillary pressures with different amounts of liquid in a sample. Lyophilic liquid porosimetry determines liquid/solid contact angles of different size pores within the sample. It can also be used for PVD analysis of both soft, brittle materials and porous metal materials.

Tyomkin, I. [TRI/Princeton, NJ (United States)

1998-12-31T23:59:59.000Z

296

Fermi-liquid droplets in liquid-solid solutions of the helium isotopes  

SciTech Connect

For temperatures below phase separation of 1000-ppm /sup 3/He in solid /sup 4/He we measure a heat capacity ..gamma..T for a pressure between melting of pure /sup 3/He and /sup 4/He. Together with the confined sample geometry this results in liquid /sup 3/He droplets (phiapprox.10/sup 3/A) either dilute or pure depending on the phase diagram topology which is discussed theoretically. In the case of a pure /sup 3/He droplet we find an anomalously high effective mass m*/m=10, which could be explained by paramagnon effects enhanced by the confined geometry.

Hebral, B.; Greenberg, A.S.; Beal-Monod, M.T.; Papoular, M.; Frossati, G.; Godfrin, H.; Thoulouze, D.

1981-01-05T23:59:59.000Z

297

Mechanical Stability of Pixel-Isolated Liquid Crystal Mode with Plastic Substrates  

Science Journals Connector (OSTI)

We have fabricated a plastic liquid crystal display using the pixel-isolated liquid crystal (PILC) mode and characterized the mechanical stability of the sample against mechanical pressure and bending. Since the liquid crystal molecules are fully isolated in the pixels by the phase-separated polymer walls in the PILC mode, the electrooptic properties of the sample show good mechanical stability. In addition, a polymer layer formed on the upper substrate enhances the adhesion between two plastic substrates.

Jong-Wook Jung; Min Young Jin; Hak-Rin Kim; You-Jin Lee; Jae-Hoon Kim

2005-01-01T23:59:59.000Z

298

Microsoft Word - DOE_RM_DM-#350832-v1-NAPL_Quarterly_April-June_2006.DOC  

Office of Legacy Management (LM)

Northeast Site Northeast Site Non-Aqueous Phase Liquids Interim Measures Progress Report April through June 2006 July 2006 Office of Legacy Management DOE M/1253-2006 -L Work Performed Under DOE Contract No. for the U.S. Department of Energy Office of Legacy Management. DE-AC01-02GJ79491 Approved for public release; distribution is unlimited. Office of Legacy Management Office of Legacy Management Office of Legacy Management U.S. Department of Energy DOE-LM/1253-2006 Pinellas Environmental Restoration Project Northeast Site Non-Aqueous Phase Liquids Interim Measures Progress Report April through June 2006 July 2006 Work Performed by S.M. Stoller Corporation under DOE Contract No. DE-AC01-02GJ79491 for the U.S. Department of Energy Office of Legacy Management, Grand Junction, Colorado

299

Microsoft Word - DOE_RM_DM-#102768-v1-NAPL_Quarterly_Report_Jan-March_2005.ƒ  

Office of Legacy Management (LM)

6 6 U.S. Department of Energy Work Performed Under DOE Contract No. for the U.S. Department of Energy Office of Legacy Management. DE-AC01-02GJ79491 Approved for public release; distribution is unlimited. Office of Legacy Management Office of Legacy Management Office of Legacy Management Pinellas Environmental Restoration Project Northeast Site Non-Aqueous Phase Liquids Interim Measure Progress Report January through March 2005 April 2005 DOE-LM/GJ876-2005 Pinellas Environmental Restoration Project Northeast Site Non-Aqueous Phase Liquids Interim Measures Progress Report January through March 2005 April 2005 Work Performed by S.M. Stoller Corporation under DOE Contract No. DE-AC01-02GJ79491 for the U.S. Department of Energy Office of Legacy Management, Grand Junction, Colorado

300

Microsoft Word - DOE_RM_DM-#345139-v1-NAPL_Quarterly_Oct-Dec_2005.DOC  

Office of Legacy Management (LM)

5 5 2006 - -L U.S. Department of Energy Work Performed Under DOE Contract No. for the U.S. Department of Energy Office of Legacy Management. DE-AC01-02GJ79491 Approved for public release; distribution is unlimited. Office of Legacy Management Office of Legacy Management Office of Legacy Management Pinellas Environmental Restoration Project Northeast Site Non-Aqueous Phase Liquids Interim Measure Progress Report October Through December 2005 January 2006 DOE-LM/GJ1105-2006 Pinellas Environmental Restoration Project Northeast Site Non-Aqueous Phase Liquids Interim Measures Progress Report October through December 2005 January 2006 Work Performed by S.M. Stoller Corporation under DOE Contract No. DE-AC01-02GJ79491 for the U.S. Department of Energy Office of Legacy Management, Grand Junction, Colorado

Note: This page contains sample records for the topic "non-aqueous phase liquid" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Microsoft Word - DOE_RM_DM-#100069-v1-NAPL_Quarterly_Oct-Dec_2004.DOC  

Office of Legacy Management (LM)

1 1 U.S. Department of Energy Work Performed Under DOE Contract No. for the U.S. Department of Energy Office of Legacy Management. DE-AC01-02GJ79491 Approved for public release; distribution is unlimited. Office of Legacy Management Office of Legacy Management Office of Legacy Management Pinellas Environmental Restoration Project Northeast Site Non-Aqueous Phase Liquids Interim Measure Progress Report October through December 2004 January 2005 DOE-LM/GJ801-2005 Pinellas Environmental Restoration Project Northeast Site Non-Aqueous Phase Liquids Interim Measures Progress Report October through December 2004 January 2005 Work Performed by S.M. Stoller Corporation under DOE Contract No. DE-AC01-02GJ79491 for the U.S. Department of Energy Office of Legacy Management, Grand Junction, Colorado

302

Microsoft Word - N0071600-NAPL-Oct to Dec.doc  

Office of Legacy Management (LM)

6-TAC 6-TAC U.S. Department of Energy Pinellas Environmental Restoration Project Northeast Site Non-Aqueous Phase Liquids Interim Measure Progress Report October Through December 2003 January 2004 Work Performed Under DOE Contract No. for the U.S. Department of Energy Office of Legacy Management, Grand Junction, Colorado. DE-AC01-02GJ79491 Approved for public release; distribution is unlimited. Office of Legacy Management Office of Legacy Management Office of Legacy Management N0071600 GJO-2004-556-TAC PIN 700.15.10 Pinellas Environmental Restoration Project Northeast Site Non-Aqueous Phase Liquids Interim Measures Progress Report October through December 2003 January 2004 Work Performed by S.M. Stoller Corporation under DOE Contract No. DE-AC01-02GJ79491

303

Adsorption and desorption of contaminants  

SciTech Connect

The microbial remediation of sites Contaminated with organics is well documented, however, there are some significant problems that remain to be solved in the areas of contaminants sorbed to soils and non-aqueous phase liquid (NAPL) contamination. Methods of in situ bioremediation techniques employ either the stimulation of indigenous populations by nutrient addition, or the addition of prepared bacterial cultures to the subsurface environment. Problems of contaminant sorption and NAPL`s are related in that both encompass reduced contaminant bioavailability. Non-aqueous phase liquids have been identified as a priority area for research in the In situ Program due to their presence at DOE sites and the lack of adequate technology to effectively treat this contamination. Bioremediation technologies developed as a result of this project are easily transferred to industry.

Palumbo, A.V.; Strong-Gunderson, J.M. [Oak Ridge National Lab., TN (United States); DeFlaun, M.; Ensley, B. [Envirogen, Inc., Lawrenceville, NJ (United States)

1994-02-01T23:59:59.000Z

304

Viscosity of Liquids  

Science Journals Connector (OSTI)

6 November 1952 research-article Viscosity of Liquids E. N. da C. Andrade The Royal Society is collaborating with JSTOR to digitize, preserve, and extend access to Proceedings of the Royal Society of London. Series A, Mathematical and Physical Sciences. www.jstor.org

1952-01-01T23:59:59.000Z

305

The Viscosity of Liquids  

Science Journals Connector (OSTI)

... of momentum between them. In the case of a gas, Maxwell showed how the viscosity can be derived by considering this momentum as being communicated by molecules transferring themselves bodily ... fulfilment of the conditions postulated in Maxwell's treatment, and the fact that while gas viscosity goes up with temperature liquid ...

E. N. DA C. ANDRADE

1930-04-12T23:59:59.000Z

306

Detonation in Liquid Explosives  

Science Journals Connector (OSTI)

... Laboratory, on the initiative of Dr. A. H. Davis, into the process of detonation in explosives, the programme including a photographic study of the ... in explosives, the programme including a photographic study of the detonation Waves in transparent liquid explosives—the sensitivity of some of which can be varied by ...

D. CRONEY

1948-09-25T23:59:59.000Z

307

Liquid Natural Gas  

Science Journals Connector (OSTI)

Liquid Natural Gas ... IN A new technique for storing natural gas at the East Ohio Gas Co. plant, Cleveland, Ohio, the gas is liquefied before passing to the gas holders. ... Natural gas contains moisture and carbon dioxide, both of which liquefy before the natural gas and are somewhat of a nuisance because upon solidification they clog the pipes. ...

W. F. SCHAPHORST

1941-04-25T23:59:59.000Z

308

E-Print Network 3.0 - aqueous media catalyzed Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

ionic liquids: the stereoconvergent hydrolysis of Summary: of the most commonly proposed green alternatives to organic solvents, the use of enzymes in non-aqueous media... ...

309

Air Liquide- Biogas & Fuel Cells  

Energy.gov (U.S. Department of Energy (DOE))

Presentation about Air Liquide's biogas technologies and integration with fuel cells. Presented by Charlie Anderson, Air Liquide, at the NREL/DOE Biogas and Fuel Cells Workshop held June 11-13, 2012, in Golden, Colorado.

310

P-56 / A. Murauski P-56: Aligning Liquid Crystals Using Self-Assembled Monolayers  

E-Print Network (OSTI)

P-56 / A. Murauski P-56: Aligning Liquid Crystals Using Self-Assembled Monolayers Anatoli Murauski, this method is incompatible with localized control over LC alignment. Recently, anchoring of LC was demonstrated using low energy surfaces from self-assembled monolayers (SAMs) deposited from a liquid phase

311

Probing Liquid Water Saturation in Diffusion Media of Polymer Electrolyte Fuel Cells  

E-Print Network (OSTI)

of information strongly needed to characterize the level of cathode DM flooding or anode dry-out. In this paper liquid water in the anode DM for the thin membrane case. In addition, the two-phase simulation results be realized. One of these is related to flooding phenomena. Due to the presence of liquid water inside a PEFC

312

Capillary waves and the inherent density profile for the liquid-vapor interface  

E-Print Network (OSTI)

. This approach in turn allows: (1) identification of an "outermost layer" of particles on the liquid. (2). is a nonmonotonic function of normal distance through the interface. and is expected to reflect the diverging bulk distribution for the system in a state of liquid-vapor phase coexistence. This leads to identification

Stillinger, Frank

313

Dependence of the morphology of polymer dispersed liquid crystals on the UV polymerization process  

E-Print Network (OSTI)

temperature. Instead, high-temperature cures result in coalescence and the formation of elliptical temperature of the PDLC mixture matches the temperature of this phase sepa- ration line Tps . At this point liquid crystals PDLC as a function of polymer/liquid crystal composition, polymer cure temperature

Carter, Sue

314

Under consideration for publication in J. Fluid Mech. 1 Bubble entrainment and liquid-bubble  

E-Print Network (OSTI)

Under consideration for publication in J. Fluid Mech. 1 Bubble entrainment and liquid-bubble ?; accepted ?.) Liquid-bubble interaction, especially in complex two-phase bubbly flow under breaking waves-Stokes solver extended to incorporate entrained bubble populations, using an Eulerian-Eulerian formulation

Kirby, James T.

315

Tuning the defect configurations in nematic and smectic liquid crystalline shells  

Science Journals Connector (OSTI)

...arrangements in smectic liquid crystal shells utilizing the...Nematic-smectic transition in spherical shells. Phys. Rev...Topological defects in spherical nematics. Phys. Rev...a smectic-a from a bent nematic phase and smectic...The physics of liquid crystals. Oxford, UK: Clarendon...

2013-01-01T23:59:59.000Z

316

Fundamentals of Nucleate Pool Boiling of Highly-Wetting Dielectric Liquids  

Science Journals Connector (OSTI)

Direct cooling with inert, dielectric liquids may well become the technique of choice for the thermal management of future electronic systems. Due to the efficiency of phase-change processes and the simplicity...

Avram Bar-Cohen

1994-01-01T23:59:59.000Z

317

NMR STUDIES OF LIQUID CRYSTALS AND MOLECULES DISSOLVED IN LIQUID CRYSTAL SOLVENTS  

SciTech Connect

This thesis describes several studies in which nuclear magnetic resonance (nmr) spectroscopy has been used to probe the structure, orientation and dynamics of liquid crystal mesogens and molecules dissolved in liquid crystalline phases. In addition, a modern high field nmr spectrometer is described which has been used to perform such nmr studies. Chapter 1 introduces the quantum mechanical formalisms used throughout this thesis and briefly reviews the fundamentals of nuclear spin physics and pulsed nmr spectroscopy. First the density operator is described and a specific form for the canonical ensemble is derived. Then Clebsch-Gordon coefficients, Wigner rotation matrices, and irreducible tensor operators are reviewed. An expression for the equilibrium (Curie) magnetization is obtained and the linear response of a spin system to a strong pulsed r.f. irradiation is described. Finally, the spin interaction Hamiltonians relevant to this work are reviewed together with their truncated forms. Chapter 2 is a deuterium magnetic resonance study of two 'nom' liquid crystals which possess several low temperature mesomorphic phases. Specifically, deuterium quadrupolar echo spectroscopy is used to determine the orientation of the liquid crystal molecules in smectic phases, the changes in molecular orientation and motion that occur at smectic-smectic phase transitions, and the order of the phase transitions. For both compounds, the phase sequence is determined to be isotropic, nematic, smectic A, smectic C, smectic B{sub A}, smectic B{sub C}, and crystalline. The structure of the smectic A phase is found to be consistent with the well-known model of a two dimensional liquid in which molecules are rapidly rotating about their long axes and oriented at right angles to the plane of the layers. Molecules in the smectic C phase are found to have their long axes tilted with respect to the layer normal, and the tilt angle is temperature dependent, increasing from zero at the smectic A - smectic C transition and reaching a maximum at 9{sup o} at the smectic C - smectic B{sub A} transition. This finding contradicts the results of X-ray diffraction studies which indicate that the tilt angle is 18{sup o} and temperature independent. The smectic B{sub A} - smectic B{sub C} phase transition is observed for the first time, and is found to be first order, a result that contradicts the prediction of a mean theory by McMillian. Chapter 3 is a multiple quantum nmr study of n-hexane oriented in a nematic liquid crystal solvent. The basic three pulse multiple quantum experiment is discussed which enables the observation of transitions for which |{Delta}m|>1, and then the technique of the separation of multiple quantum orders by phase incrementation in the multiple quantum evolution period is reviewed (TPPI). An explicit example of multiple quantum nmr is given by the calculation of the multiple quantum spectrum of an oriented methyl group.

Drobny, G.P.

1982-11-01T23:59:59.000Z

318

Liquid metal thermal electric converter  

DOE Patents (OSTI)

A liquid metal thermal electric converter which converts heat energy to electrical energy. The design of the liquid metal thermal electric converter incorporates a unique configuration which directs the metal fluid pressure to the outside of the tube which results in the structural loads in the tube to be compressive. A liquid metal thermal electric converter refluxing boiler with series connection of tubes and a multiple cell liquid metal thermal electric converter are also provided.

Abbin, Joseph P. (Albuquerque, NM); Andraka, Charles E. (Albuquerque, NM); Lukens, Laurance L. (Albuquerque, NM); Moreno, James B. (Albuquerque, NM)

1989-01-01T23:59:59.000Z

319

Liquid suspensions of reversible metal hydrides  

DOE Patents (OSTI)

The reversibility of the process M + x/2 H/sub 2/ ..-->.. MH/sub x/, where M is a metal hydride former that forms a hydride MH/sub x/ in the presence of H/sub 2/, generally used to store and recall H/sub 2/, is found to proceed under a liquid, thereby to reduce contamination, provide better temperature control and provide in situ mobility of the reactants. Thus, a slurry of particles of a metal hydride former with an inert solvent is subjected to temperature and pressure controlled atmosphere containing H/sub 2/, to store hydrogen (at high pressures) and to release (at low pressures) previously stored hydrogen. The direction of the flow of the H/sub 2/ through the liquid is dependent upon the H/sub 2/ pressure in the gas phase at a given temperature. When the former is above the equilibrium absorption pressure of the respective hydride the reaction proceeds to the right, i.e., the metal hydride is formed and hydrogen is stored in the solid particle. When the H/sub 2/ pressure in the gas phase is below the equilibrium dissociation pressure of the respective hydride the reaction proceeds to the left, the metal hydride is decomposed and hydrogen is released into the gas phase.

Reilly, J.J.; Grohse, E.W.; Winsche, W.E.

1983-12-08T23:59:59.000Z

320

High temperature liquid level sensor  

DOE Patents (OSTI)

A length of metal sheathed metal oxide cable is perforated to permit liquid access to the insulation about a pair of conductors spaced close to one another. Changes in resistance across the conductors will be a function of liquid level, since the wetted insulation will have greater electrical conductivity than that of the dry insulation above the liquid elevation.

Tokarz, Richard D. (West Richland, WA)

1983-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "non-aqueous phase liquid" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

STABILITY OF EQUILIBRIA FOR TWO-PHASE FLOWS WITH SOLUBLE SURFACTANT  

E-Print Network (OSTI)

effect on the surface tension, hence on the stress balance at the phase boundary: local variations. Key words: two-phase Navier-Stokes equations, surface tension, Marangoni stress, as- ymptotic behavior that are adsorbed at gas/liquid or liq- uid/liquid interfaces, where they typically lower the surface tension

Bothe, Dieter

322

Possible Martensitic Transformation in Hydrated Phospholipid Liquid Crystals  

Science Journals Connector (OSTI)

The main phase transition in smectic liquid crystals of a hydrated phospholipid involves a Martensitic transformation driven by the molecular-conformation changes. This inhomogeneous shear transformation generates periodic crystallographic twins that appear as corrugations of the molecular bilayer sheets. The model accounts for the observed lipid shedding, hysteresis, double corrugation periodicities, and diffusion anomalies, and may account for other smectic herringbone structures.

Winston K. Chan and Watt W. Webb

1981-01-05T23:59:59.000Z

323

Studies of a Liquid Argon Time Projection Chamber  

E-Print Network (OSTI)

, industrial- scale purification of argon to 0.1 ppb of O2. Here, we propose to undertake R&D on the two of these topics that can be addressed by a relatively small-scale effort: 1. Verification that a liquid argon phase could be studied. At this scale of detector, the best technology ­ a total absorption tracking

McDonald, Kirk

324

Soft ionization of thermally evaporated hypergolic ionic liquid aerosols  

SciTech Connect

Isolated ion pairs of a conventional ionic liquid, 1-Ethyl-3-Methyl-Imidazolium Bis(trifluoromethylsulfonyl)imide ([Emim+][Tf2N?]), and a reactive hypergolic ionic liquid, 1- Butyl-3-Methyl-Imidazolium Dicyanamide ([Bmim+][Dca?]), are generated by vaporizing ionic liquid submicron aerosol particles for the first time; the vaporized species are investigated by dissociative ionization with tunable vacuum ultraviolet (VUV) light, exhibiting clear intact cations, Emim+ and Bmim+, presumably originating from intact ion pairs. Mass spectra of ion pair vapor from an effusive source of the hypergolic ionic liquid show substantial reactive decomposition due to the internal energy of the molecules emanating from the source. Photoionization efficiency curves in the near threshold ionization region of isolated ion pairs of [Emim+][Tf2N?] ionic liquid vapor are compared for an aerosol source and an effusive source, revealing changes in the appearance energy due to the amount of internal energy in the ion pairs. The aerosol source has a shift to higher threshold energy (~;;0.3 eV), attributed to reduced internal energy of the isolated ion pairs. The method of ionic liquid submicron aerosol particle vaporization, for reactive ionic liquids such as hypergolic species, is a convenient, thermally ?cooler? source of isolated intact ion pairs in the gas phase compared to effusive sources.

University of California; ERC, Incorporated, Edwards Air Force Base; Air Force Research Laboratory, Edwards Air Force Base; National Synchrotron Radiation Research Center (NSRRC); Koh, Christine J.; Liu, Chen-Lin; Harmon, Christopher W.; Strasser, Daniel; Golan, Amir; Kostko, Oleg; Chambreau, Steven D.; L.Vaghjiani, Ghanshyam; Leone, Stephen R.

2012-03-16T23:59:59.000Z

325

Ion Distributions Near a Liquid-Liquid Interface  

NLE Websites -- All DOE Office Websites (Extended Search)

Ion Distributions Near a Liquid-Liquid Interface Ion Distributions Near a Liquid-Liquid Interface Researchers from the University of Illinois at Chicago; Northern Illinois University; the University of California, Santa Cruz; and ChemMatCARS (sector 15 at the APS) used x-ray reflectivity from ion distributions at the liquid-liquid interface to provide strong evidence that the interfacial structure of a liquid alters the ion distributions near a charged interface, contrary to earlier theories about ions at charged surfaces. Coulomb's Law describes the interaction between two, otherwise isolated, point charges. If many charges are present in the region between these two charges, the net interaction between them is modified. This is commonly found in real systems, such as a plasma gas of electrons and ionized

326

Frostbite Theater - Liquid Nitrogen Experiments - Liquid Nitrogen and  

NLE Websites -- All DOE Office Websites (Extended Search)

Freeze the Rainbow! Freeze the Rainbow! Previous Video (Freeze the Rainbow!) Frostbite Theater Main Index Next Video (Liquid Nitrogen and Fire!) Liquid Nitrogen and Fire! Liquid Nitrogen and Antifreeze! What happens when the freezing power of liquid nitrogen meets the antifreezing power of ethylene glycol? [ Show Transcript ] Announcer: Frostbite Theater presents... Cold Cuts! No baloney! Joanna and Steve: Just science! Joanna: Hi! I'm Joanna! Steve: And I'm Steve! Joanna: What happens when the freezing power of liquid nitrogen... Steve: ...meets the antifreezing power of ethylene glycol! Joanna: While a mix of 70 percent ethylene glycol and 30 percent water doesn't freeze until 60 degrees below zero, it's still no match for liquid nitrogen. At 321 degrees below zero, liquid nitrogen easily freezes

327

Frostbite Theater - Liquid Nitrogen Experiments - Let's Freeze Liquid  

NLE Websites -- All DOE Office Websites (Extended Search)

Shattering Pennies! Shattering Pennies! Previous Video (Shattering Pennies!) Frostbite Theater Main Index Next Video (Liquid Nitrogen in a Microwave!) Liquid Nitrogen in a Microwave! Let's Freeze Liquid Nitrogen! By removing the hottest molecules, we're able to freeze liquid nitrogen! [ Show Transcript ] Announcer: Frostbite Theater presents... Cold Cuts! No baloney! Joanna and Steve: Just science! Joanna: Hi! I'm Joanna! Steve: And I'm Steve! Joanna: Today, we're going to freeze liquid nitrogen! Joanna and Steve: Yeah! Joanna: The obvious way to do this is to put the liquid nitrogen into something colder. Something that we have lots of around here! Something like... liquid helium! Steve: Yes! Joanna: Yeah, but we're not going to do that. Instead, we're going to freeze the nitrogen by removing the hottest molecules!

328

The Quantum Nature of a Nuclear Phase Transition  

E-Print Network (OSTI)

In their ground states, atomic nuclei are quantum Fermi liquids. At finite temperatures and low densities, these nuclei may undergo a phase change similar to, but substantially different from, a classical liquid gas phase transition. As in the classical case, temperature is the control parameter while density and pressure are the conjugate variables. At variance with the classical case, in the nucleus the difference between the proton and neutron concentrations acts as an additional order parameter, for which the symmetry potential is the conjugate variable. Different ratios of the neutron to proton concentrations lead to different critical points for the phase transition. This is analogous to the phase transitions occurring in $^{4}$He-$^{3}$He liquid mixtures. We present experimental results which reveal the N/Z dependence of the phase transition and discuss possible implications of these observations in terms of the Landau Free Energy description of critical phenomena.

A. Bonasera; Z. Chen; R. Wada; K. Hagel; J. Natowitz; P. Sahu; L. Qin; S. Kowalski; Th. Keutgen; T. Materna; T. Nakagawa

2008-03-26T23:59:59.000Z

329

Determinants of Hospital's Financial Liquidity  

Science Journals Connector (OSTI)

Abstract The purpose of the articles is to identify key factors that may affect the level of hospital's liquidity ratio. We’ve posed four research hypotheses, assuming that, the level of financial liquidity in hospitals depends on several factors (number of beds, annual income per bed, profitability ratios, debt ratio). We’ve found that: 1) there is a positive relationship between debt ratio and liquidity and profitability ratio and liquidity 2) the relationship between the size of the hospital and the financial liquidity is not statistically significant. In the study we’ve use statistical tools: Pearson's correlation coefficient, T-Student's test with Cohran-Cox's correction.

Agnieszka Bem; Katarzyna Pr?dkiewicz; Pawe? Pr?dkiewicz; Paulina Ucieklak-Je?

2014-01-01T23:59:59.000Z

330

Microrheology close to an equilibrium phase transition  

SciTech Connect

We investigate the microstructural and microrheological response to a tracer particle of a two-dimensional colloidal suspension under thermodynamic conditions close to a liquid-gas phase boundary. On the liquid side of the binodal, increasing the velocity of the (repulsive) tracer leads to the development of a pronounced cavitation bubble, within which the concentration of colloidal particles is strongly depleted. The tendency of the liquid to cavitate is characterized by a dimensionless “colloidal cavitation” number. On the gas side of the binodal, a pulled (attractive) tracer leaves behind it an extended trail of colloidal liquid, arising from downstream advection of a wetting layer on its surface. For both situations the velocity dependent friction is calculated.

Reinhardt, J.; Scacchi, A.; Brader, J. M., E-mail: joseph.brader@unifr.ch [Department of Physics, University of Fribourg, CH-1700 Fribourg (Switzerland)

2014-04-14T23:59:59.000Z

331

RHIC The Perfect Liquid  

ScienceCinema (OSTI)

Evidence to date suggests that gold-gold collisions the Relativistic Heavy Ion Collider at Brookhaven are indeed creating a new state of hot, dense matter, but one quite different and even more remarkable than had been predicted. Instead of behaving like a gas of free quarks and gluons, as was expected, the matter created in RHIC's heavy ion collisions appears to be more like a "perfect" liquid.

BNL

2009-09-01T23:59:59.000Z

332

Theory of fermion liquids  

Science Journals Connector (OSTI)

We develop a general theory of fermion liquids in spatial dimensions greater than 1. The principal method, bosonization, is applied to the cases of short- and long-range longitudinal interactions and to transverse gauge interactions. All the correlation funtions of the system may be obtained with the use of a generating functional. Short-range and Coulomb interactions do not destroy the Landau-Fermi fixed point. Non-Fermi liquid fixed points are found, however, in the cases of a super-long-range longitudinal interaction in two dimensions and transverse gauge interactions in two and three spatial dimensions. We consider in some detail the (2+1)-dimensional problem of a Chern-Simons gauge action combined with a longitudinal two-body interaction V(q)??q?y-1, which controls the density, and hence gauge, fluctuations. For y0 the interaction is relevant and the fixed point cannot be accessed by bosonization. Of special importance is the case y=0 (Coulomb interaction), which describes the Halperin-Lee-Read theory of the half-filled Landau level. We obtain the full quasiparticle propagator, which is of a marginal Fermi-liquid form. Using Ward identities, we show that neither the inclusion of nonlinear terms in the fermion dispersion nor vertex corrections alters our results: the fixed point is accessible by bosonization. As the two-point fermion Green’s function is not gauge invariant, we also invetigate the gauge-invariant density response function. Near momentum Q=2kF, in addition to the Kohn anomaly we find other nonanalytic behavior. In the appendies we present a numerical calculation of the spectral function for a Fermi liquid with Landau parameter f0?0. We also show how Kohn’s theorem is satisfied within the bosonization framework.

H.-J. Kwon; A. Houghton; J. B. Marston

1995-09-15T23:59:59.000Z

333

Liquid fossil fuel technology  

SciTech Connect

Progress reports are presented under the following headings: (1) extraction (technology assessment, oil research, gas research); (2) liquid processing (characterization, thermodynamics, processing technology); (3) utilization (energy conservation); and (4) project integration and technology transfer. BETC publications are also listed. Some of the highlights for this period are: the Bartlesville Energy Technology Center was converted into NIPER, the National Institute for Petroleum and Energy Research on October 1, 1983; modelling of enthalpies, heat capacities and volumes of aqueous surfactant solutions began using a mass action model; a series of experiments were run on upgrading by hydrogenation SRC-II coal liquid at different degrees of severity and the products have been analyzed; heavy crude oil extracts were separated into fraction with high performance liquid chromatography by Lawrence Berkeley Laboratory and the mass spectra and electron spin resonance were determin ed; and particulates from exhaust gases of diesel engines using fire fuel types are being collected and will be analyzed by chemical methods and results will be compared with those obtained by biological assay. (ATT)

Not Available

1983-01-01T23:59:59.000Z

334

Landau theory of phase separation in cuprates  

Science Journals Connector (OSTI)

I discuss the problem of phase separation in cuprates from the point of view of the Landau theory of Fermi liquids. I calculate the rate of growth of unstable regions for the hydrodynamics and collisionless limit and, in presence of long-range Coulomb interactions, the size of these regions. These are analytic results valid for any strength of the Landau parameters.

A. H. Castro Neto

1995-02-01T23:59:59.000Z

335

MODELLING AND SIMULATION OF LIQUID-VAPOR PHASE TRANSITION  

E-Print Network (OSTI)

Generator Turbine Generator Cooling Tower Condenser Cooling Water Pump Reactor Core Reactor Vessel Control and Steam (secondary loop) Water (cooling loop) Pump Steam Generator Turbine Generator Cooling Tower Water pressurized (primary loop) Water and Steam (secondary loop) Water (cooling loop) Pump Steam

Faccanoni, Gloria

336

Hydrogenation with monolith reactor under conditions of immiscible liquid phases  

DOE Patents (OSTI)

The present invention relates to an improved for the hydrogenation of an immiscible mixture of an organic reactant in water. The immiscible mixture can result from the generation of water by the hydrogenation reaction itself or, by the addition of, water to the reactant prior to contact with the catalyst. The improvement resides in effecting the hydrogenation reaction in a monolith catalytic reactor from 100 to 800 cpi, at a superficial velocity of from 0.1 to 2 m/second in the absence of a cosolvent for the immiscible mixture. In a preferred embodiment, the hydrogenation is carried out using a monolith support which has a polymer network/carbon coating onto which a transition metal is deposited.

Nordquist, Andrew Francis (Whitehall, PA); Wilhelm, Frederick Carl (Zionsville, PA); Waller, Francis Joseph (Allentown, PA); Machado, Reinaldo Mario (Allentown, PA)

2002-01-01T23:59:59.000Z

337

Review of Liquid Phases in Gas Chromatography, Part II: Applications  

Science Journals Connector (OSTI)

......in the carrier gas; this sharpens...oxygen) and water (20,22,23...in the carrier gas, from leaks in...tochromic (12) and solubility parameter (36...Eon. Expanded solubility param eter treatment...for capillary gas chromatography...capillaries and a nitrogen selective detector......

J.A. Yancey

1994-09-01T23:59:59.000Z

338

Introduction The release of nonaqueous phase liquids (NAPLs) to  

E-Print Network (OSTI)

produced through the -decay of radium-226 Abstract Naturally occurring radon in ground water can create long-term sources of ground water contamination as the NAPL slowly dissolves into ground water (Mercer and Cohen 1990; Cohen and Mercer 1993). Effective remediation of subsurface NAPL contamination

Semprini, Lewis

339

Review of Liquid Phases in Gas Chromatography, Part II: Applications  

Science Journals Connector (OSTI)

......reported by Jones (19). B. Poly(ethylene glycol) or PEG PEG is the second most...PEG degrades to form acetaldehyde and ethylene oxide (20,22), and the acetaldehyde...J. Laub, B.H. Luh- mann, A. Price, W . L Roberts, T.J. Shaw, and C......

J.A. Yancey

1994-09-01T23:59:59.000Z

340

Ultrasonic Synergistic Effects in Liquid-Phase Chemical Sterilization  

Science Journals Connector (OSTI)

...In either case, ultrasonic energy accelerates the sterilizing ability...ultrasonic frequency, acoustic energy density, temperature, and sterilization...a research contract from Wave Energy Systems, Inc., New York, N.Y. LITERATURE CITED 1...

Gonzalo Sierra; Raymond M. G. Boucher

1971-08-01T23:59:59.000Z

Note: This page contains sample records for the topic "non-aqueous phase liquid" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Liquid phase epitaxial growth of GaAs  

SciTech Connect

Research into new semiconductor materials for measurement of electromagnetic radiation over a wide range of energies has been an active field for several decades. There is a strong desire to identify and develop new materials which can lead to improved detectors. Such devices are expected to solve problems that cannot be solved using the semiconductor materials and device structures which have been traditionally used for radiation detection. In order for a detector which is subjected to some type of irradiation to respond, the radiation must undergo an interaction with the detector. The net result of the radiation interaction in a broad category of detectors is the generation of mobile electric charge carriers (electrons and/or holes) within the detector active volume. This charge is collected at the detector contacts and it forms the basic electrical signal. Typically, the collection of the charge is accomplished through the imposition of an electric field within the detector which causes the positive and/or negative charges created by the radiation to flow in opposite directions to the contacts. For the material to serve as a good radiation detector, a large fraction (preferably 100%) of all carriers created by the interacting incident radiation must be collected. Charge trapping by deep level impurities and structural defects can seriously degrade detector performance. The focus of this thesis is on far infrared and X-ray detection. In X-ray detector applications of p-I-n diodes, the object is to measure accurately the energy distribution of the incident radiation quanta. One important property of such detectors is their ability to measure the energy of individual incident photons with high energy resolution.

Wynne, D.I. [Univ. of California, Berkeley, CA (United States). Materials Science and Mineral Engineering; [Lawrence Berkeley National Lab., CA (United States)

1997-10-01T23:59:59.000Z

342

Liquid-phase oxidation of components of compression process gasoline  

SciTech Connect

This report investigated the oxidation of hydrocarbons of various classes, the principal components of straight-run gasoline, under conditions similar to those used for industrial production of carboxylic acids at the Erevan Petroleum Refinery ''Nairit''. The study was carried out in the temperature range from 155 to 195/sup 0/C at a pressure of 5 MPa on an installation whose scheme was described previously. Normal paraffinic C/sub 5/-C/sub 8/ hydrocarbons, isoparaffinic hydrocarbons such as isopentane and isooctane (2,2,4-trimethylpentane), as well as cyclohexane were subjected to oxidation. The effluent gases were analyzed chromatographically for CO, CO/sub 2/ and hydrocarbon content, the oxidate was analyzed chemically for a total content of acids and chromatographically for its content of formic, acetic, propionic and butyric acids. This study also determined the content of acetone and water (chromatographically) and dicarboxylic acids (chemically).

Dayan, V.M.; Astratsatryan, S.A.; Kushina, I.D.; Pyzh, M.I.; Pazderskii, Y.A.; Bryukhovetskii, V.A.; Levush, S.S.

1982-06-01T23:59:59.000Z

343

Liquid dispersion and holdup in a small-scale upflow hydrotreater at high temperatures and pressure  

Science Journals Connector (OSTI)

Residence time distribution experiments were carried out at high temperatures and pressure in a small-scale upflow reactor. A diluted and a non-diluted bed were tested. Middle distillates and hydrogen were used as feeds. The axial dispersion model was used to describe the liquid flow through the packed bed. The dependency of Pe and liquid holdup on feed velocity and temperature was examined. The behaviour of the beds tested at hot flow conditions is compared with that of identical beds tested at ambient conditions using toluene as liquid feed and the effect of liquid-phase properties is discussed.

A.M. Thanos; P.A. Galtier; N.G. Papayannakos

2001-01-01T23:59:59.000Z

344

Influence of the Anisometry of Magnetic Particles on the Isotropic-Nematic Phase Transition  

E-Print Network (OSTI)

The influence of the shape anisotropy of magnetic particles on the isotropic-nematic phase transition was studied in ferronematics based on the nematic liquid crystal 4-(trans-4-n-hexylcyclohexyl)-isothiocyanato-benzene (6CHBT). The liquid crystal was doped with spherical or rod-like magnetic particles of different size and volume concentrations. The phase transition from isotropic to nematic phase was observed by polarizing microscope as well as by capacitance measurements. The influence of the concentration and the shape anisotropy of the magnetic particles on the isotropic-nematic phase transition in liquid crystal is demonstrated. The results are in a good agreement with recent theoretical predictions.

V. Gdovinová; N. Tomašovi?ová; N. Éber; T. Tóth-Katona; V. Závišová; M. Timko; P. Kop?anský

2014-09-05T23:59:59.000Z

345

Chirality in Liquid Crystals: from Microscopic Origins to Macroscopic Structure  

E-Print Network (OSTI)

Molecular chirality leads to a wonderful variety of equilibrium structures, from the simple cholesteric phase to the twist-grain-boundary phases, and it is responsible for interesting and technologically important materials like ferroelectric liquid crystals. This paper will review some recent advances in our understanding of the connection between the chiral geometry of individual molecules and the important phenomenological parameters that determine macroscopic chiral structure. It will then consider chiral structure in columnar systems and propose a new equilibrium phase consisting of a regular lattice of twisted ropes.

T. C. Lubensky; A. B. Harris; Randall D. Kamien; Gu Yan

1997-10-31T23:59:59.000Z

346

Capillary Condensation of Liquid 4He in Aerogel on Cooling Through {lambda} Point  

SciTech Connect

Capillary condensation of liquid 4He in silica aerogel with a 90% porosity was investigated visually. The initial condition of the experiment was such that liquid 4He was present in the sample cell but not in the aerogel. This situation was realized by introducing the liquid into the cell at a fast rate to avoid liquefaction in the aerogel. The free surface of the liquid rose up in the cell with filling and eventually reached the bottom of the aerogel. Then, the aerogel absorbed the liquid by capillary condensation. The height of the liquid in the aerogel rose with time t roughly as t1/2 in the normal fluid phase. This behavior was consistent with the Washburn model. When the system was cooled through the {lambda} point during the condensation, the liquid height started to rise faster in the superfluid phase with a constant velocity of about 0.3 mm/sec. The dynamics of capillary condensation was strongly dependent on whether the liquid 4He was in the normal or the superfluid phase.

Miyashita, W.; Yoneyama, K.; Kato, H.; Nomura, R.; Okuda, Y. [Department of Condensed Matter Physics, Tokyo Institute of Technology, 2-12-1, O-okayama, Meguro, Tokyo 152-8551 (Japan)

2006-09-07T23:59:59.000Z

347

Frostbite Theater - Liquid Nitrogen Experiments - Let's Pour Liquid  

NLE Websites -- All DOE Office Websites (Extended Search)

Shattering Flowers! Shattering Flowers! Previous Video (Shattering Flowers!) Frostbite Theater Main Index Next Video (Giant Koosh Ball!) Giant Koosh Ball! Let's Pour Liquid Nitrogen on the Floor! Liquid nitrogen?! On the floor?! Who's going to clean that mess up?! See what really happens when one of the world's most beloved cryogenic liquids comes into contact with a room temperature floor. [ Show Transcript ] Announcer: Frostbite Theater presents... Cold Cuts! No baloney! Joanna and Steve: Just science! Joanna: Hi! I'm Joanna! Steve: And I'm Steve! Joanna: From time to time, we spill a little liquid nitrogen! The reaction we sometimes get is.... Shannon: Did they just pour LIQUID NITROGEN on the FLOOR?!?! Joanna: Yes. Yes we did. Steve: One thing people seem to have a problem with is the mess that liquid

348

Gas-Liquid Coexistence in the Primitive Model for Water  

E-Print Network (OSTI)

We evaluate the location of the gas-liquid coexistence line and of the associated critical point for the primitive model for water (PMW), introduced by Kolafa and Nezbeda [J. Kolafa and I. Nezbeda, Mol. Phys. 61, 161 (1987)]. Besides being a simple model for a molecular network forming liquid, the PMW is representative of patchy proteins and novel colloidal particles interacting with localized directional short-range attractions. We show that the gas-liquid phase separation is metastable, i.e. it takes place in the region of the phase diagram where the crystal phase is thermodynamically favored, as in the case of articles interacting via short-range attractive spherical potentials. Differently from spherical potentials, we do not observe crystallization close to the critical point. The region of gas-liquid instability of this patchy model is significantly reduced as compared to equivalent models of spherically interacting particles, confirming the possibility of observing kinetic arrest in an homogeneous sample driven by bonding as opposed to packing.

F. Romano; P. Tartaglia; F. Sciortino

2007-05-08T23:59:59.000Z

349

A Characterization of a Dual Chambered, Two Phase Separator  

E-Print Network (OSTI)

A new two phase separator for use in space applications has been invented. It is a vortex separator designed to accommodate gas driven two phase flows of gas and liquid. The work presented here is a first of a kind study of this newly invented...

Klein, Casey

2012-02-14T23:59:59.000Z

350

Substrate-Free Gas-Phase Synthesis of Graphene Sheets  

E-Print Network (OSTI)

Substrate-Free Gas-Phase Synthesis of Graphene Sheets Albert Dato,*, Velimir Radmilovic, Zonghoon graphene sheets in the gas phase using a substrate-free, atmospheric-pressure microwave plasma reactor. Graphene sheets were synthesized by passing liquid ethanol droplets into an argon plasma. The graphene

Frenklach, Michael

351

Three-dimensional reconstruction of bubble distribution in two-phase bubbly flows with the dynamic programming method  

E-Print Network (OSTI)

A three-dimensional bubble reconstruction method is proposed in this thesis to analyze two-phase bubbly flows. Gas/liquid two-phase flows have important roles in the nuclear and chemical industries and other engineering fields...

Furukawa, Toru

2002-01-01T23:59:59.000Z

352

Quantum Nature of a Nuclear Phase Transition  

Science Journals Connector (OSTI)

At finite temperatures and low densities, nuclei may undergo a phase change similar to a classical liquid-gas phase transition. Temperature is the control parameter while density and pressure are the conjugate variables. In the nucleus the difference between the proton and neutron concentrations acts as an additional order parameter, for which the symmetry potential is the conjugate variable. We present experimental results which reveal the N/Z dependence of the phase transition and discuss possible implications of these observations in terms of the Landau free energy description of critical phenomena.

A. Bonasera; Z. Chen; R. Wada; K. Hagel; J. Natowitz; P. Sahu; L. Qin; S. Kowalski; Th. Keutgen; T. Materna; T. Nakagawa

2008-09-18T23:59:59.000Z

353

Radiation Chemistry of Ionic Liquids  

NLE Websites -- All DOE Office Websites (Extended Search)

Liquids Liquids James F. Wishart, Alison M. Funston, and Tomasz Szreder in "Molten Salts XIV" Mantz, R. A., et al., Eds.; The Electrochemical Society, Pennington, NJ, (2006) pp. 802-813. [Information about the volume (look just above this link)] Abstract: Ionic liquids have potentially important applications in nuclear fuel and waste processing, energy production, improving the efficiency and safety of industrial chemical processes, and pollution prevention. Successful use of ionic liquids in radiation-filled environments will require an understanding of ionic liquid radiation chemistry. For example, characterizing the primary steps of ionic liquid radiolysis will reveal radiolytic degradation pathways and suggest ways to prevent them or mitigate their effects on the properties of the material

354

Protein folding, anisotropic collapse and blue phases  

E-Print Network (OSTI)

We study a homopolymer model of a protein chain, where each monomer carries a dipole moment. To mimic the geometry of the peptidic bond, these dipoles are constrained to be locally perpendicular to the chain. The tensorial character of the dipolar interaction leads naturally to a (tensorial) liquid crystal-like order parameter. For non chiral chains, a mean field study of this model shows that a classical $\\theta$ collapse transition occurs first; at lower temperature, nematic order sets in. For chiral chains, an anisotropic (tensorial) collapse transition may occur before the $\\theta$ temperature is reached: the ordered phase can be described as a ``compact phase of secondary structures'', and possesses great similarities with the liquid crystal blue phases.

E. Pitard; T. Garel; H. Orland

1997-06-11T23:59:59.000Z

355

Dipolar origin of the gas-liquid coexistence of the hard-core 1:1 electrolyte model J. M. Romero-Enrique,1,  

E-Print Network (OSTI)

as a transition between two dimerized fluid phases. The role of the unpaired ions can be considered-liquid phase transition of hard-core 1:1 electrolyte models. We study a class of dipolar dimer models small values of Rc . This fact allows us to describe the gas-liquid transition in the free ion model

356

Evidence of a liquid–liquid phase transition in hot dense hydrogen  

Science Journals Connector (OSTI)

...reflection, as the small mirror of the Schwarzschild objective substantially blocks...Attenuater Nd:Yag Mirror Reflecting >99% Nd-vanadate...pulsed Laser 1064 nm YAG mirror Beam Dumps Video CCD...illuminates sample; 7, Schwarzschild objective. BS is a...

Vasily Dzyabura; Mohamed Zaghoo; Isaac F. Silvera

2013-01-01T23:59:59.000Z

357

Process for preparing liquid wastes  

DOE Patents (OSTI)

A process for preparing radioactive and other hazardous liquid wastes for treatment by the method of vitrification or melting is provided for.

Oden, Laurance L. (Albany, OR); Turner, Paul C. (Albany, OR); O'Connor, William K. (Lebanon, OR); Hansen, Jeffrey S. (Corvallis, OR)

1997-01-01T23:59:59.000Z

358

FLARE, Fermilab Liquid Argon Experiments  

E-Print Network (OSTI)

Mature technology of Liquid Argon Time Projection Chambers in conjunction with intense neutrino beams constructed at Fermilab offer a broad program of neutrino physics for the next decade.

L. Bartoszek

2004-08-24T23:59:59.000Z

359

Phase equilibrium data for development of correlations for coal fluids  

SciTech Connect

The overall objective of the authors' work is to develop accurate predictive methods for representations of vapor-liquid equilibria in systems encountered in coal-conversion processes. The objectives pursued in the present project include: (1) Measurements of binary vapor-liquid phase behavior data for selected solute gases (e.g., C{sub 2}H{sub 6}, CH{sub 4}) in a series of paraffinic, naphthenic, and aromatic hydrocarbon solvents to permit evaluations of interaction parameters in models for phase behavior. Solubilities of the gases in the liquid phase have been determined. (2) Evaluation of existing equations of state and other models for representations of phase behavior in systems of the type studied experimentally; development of new correlation frameworks as needed. (3) Generalization of the interaction parameters for the solutes studied to a wide spectrum of heavy solvents; presentation of final results in formats useful in the design/optimization of coal liquefaction processes.

Robinson, R.L. Jr.; Gasem, K.A.M.; Darwish, N.A.; Raff, A.M.

1991-02-01T23:59:59.000Z

360

Thermodynamic and rheological properties of solid-liquid systems in coal processing. Final technical report  

SciTech Connect

The work on this project was initiated on September 1, 1991. The project consisted of two different tasks: (1) Development of a model to compute viscosities of coal derived liquids, and (2) Investigate new models for estimation of thermodynamic properties of solid and liquid compounds of the type that exist in coal, or are encountered during coal processing. As for task 1, a model for viscosity computation of coal model compound liquids and coal derived liquids has been developed. The detailed model is presented in this report. Two papers, the first describing the pure liquid model and the second one discussing the application to coal derived liquids, are expected to be published in Energy & Fuels shortly. Marginal progress is reported on task 2. Literature review for this work included compilation of a number of data sets, critical investigation of data measurement techniques available in the literature, investigation of models for liquid and solid phase thermodynamic computations. During the preliminary stages it was discovered that for development of a liquid or solid state equation of state, accurate predictive models for a number of saturation properties, such as, liquid and solid vapor pressures, saturated liquid and solid volumes, heat capacities of liquids and solids at saturation, etc. Most the remaining time on this task was spent in developing predictive correlations for vapor pressures and saturated liquid volumes of organic liquids in general and coal model liquids in particular. All these developments are discussed in this report. Some recommendations for future direction of research in this area are also listed.

Kabadi, V.N.

1995-06-30T23:59:59.000Z

Note: This page contains sample records for the topic "non-aqueous phase liquid" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Frostbite Theater - Liquid Nitrogen Experiments - Liquid Nitrogen and Fire!  

NLE Websites -- All DOE Office Websites (Extended Search)

Antifreeze! Antifreeze! Previous Video (Liquid Nitrogen and Antifreeze!) Frostbite Theater Main Index Next Video (Liquid Nitrogen and the Tea Kettle Mystery!) Liquid Nitrogen and the Tea Kettle Mystery! Liquid Nitrogen and Fire! A burning candle is placed in a container of liquid nitrogen! Filmed in front of a live studio audience. Well, they were live when we started... [ Show Transcript ] Announcer: Frostbite Theater presents... Cold Cuts! No baloney! Joanna and Steve: Just science! Steve: Now, then. I'm a little bit afraid to ask this next question because I think I already know the answer, but is anyone in here feeling a little... dangerous? You're willing to take a chance? Because I am willing to do an experiment they haven't let me do since 'The Incident.' Now, because of the danger, I cannot have a volunteer. I must do this on my

362

A new Diffractometer for Studies of Liquid-Liquid Interfaces  

SciTech Connect

We have designed a novel, dedicated diffractometer for surface x-ray scattering studies of liquid-liquid and liquid-gas interfaces for the PETRA III High Resolution Diffraction Beamline. Using a double crystal beam-tilter in Bragg geometry this new instrument enables reflectivity and grazing incidence diffraction investigations without moving the sample, which is mechanically decoupled from the rest of the diffractometer. This design minimizes external excitation of surface vibrations, a key prerequisite for studies of liquid interfaces. The instrument operates over the energy range 6.4 keV to 30 keV, the higher energy range being optimal for penetration through liquid sample environments. Vertical momentum transfer up to q{sub z} 2.5 A{sup -1} and lateral q{sub ||} up to 4 A{sup -1}will be available.

Murphy, B. M.; Greve, M.; Runge, B.; Koops, C. T.; Elsen, A.; Stettner, J.; Magnussen, O. M. [IEAP, Christian-Albrechts-Universitaet zu Kiel, D-24098 Kiel (Germany); Seeck, O. H. [PETRA III at DESY, Notkestr. 85, D-22603 Hamburg (Germany)

2010-06-23T23:59:59.000Z

363

Frostbite Theater - Liquid Nitrogen Experiments - Cells vs. Liquid  

NLE Websites -- All DOE Office Websites (Extended Search)

Superconductors! Superconductors! Previous Video (Superconductors!) Frostbite Theater Main Index Next Video (Liquid Oxygen and Fire!) Liquid Oxygen and Fire! Cells vs. Liquid Nitrogen! Let's say you've carelessly dunked your hand into a vat of liquid nitrogen and let it freeze solid. Every movie you've seen where this happens tells you that your hand will shatter like fine china should you bump it into something. If you're extremely careful, will your hand be okay once it thaws out? We'll explore this issue, using flower and onion cells rather than our hands! [ Show Transcript ] Announcer: Frostbite Theater presents... Cold Cuts! No baloney! Joanna and Steve: Just science! Joanna: Hi! I'm Joanna! Steve: And I'm Steve! Joanna: By now, we all know what happens when you place a flower in liquid

364

Unexpectedly high pressure for molecular dissociation in liquid hydrogen by a reliable electronic simulation  

E-Print Network (OSTI)

The study of the high pressure phase diagram of hydrogen has continued with renewed effort for about one century as it remains a fundamental challenge for experimental and theoretical techniques. Here we employ an efficient molecular dynamics based on the quantum Monte Carlo method, which can describe accurately the electronic correlation and treat a large number of hydrogen atoms, allowing a realistic and reliable prediction of thermodynamic roperties. We find that the molecular liquid phase is unexpectedly stable and the transition towards a fully atomic liquid phase occurs at much higher pressure than previously believed. The old standing problem of low temperature atomization is, therefore, still far from experimental reach.

Mazzola, Guglielmo; Sorella, Sandro

2014-01-01T23:59:59.000Z

365

Enhanced liquid hydrocarbon recovery process  

SciTech Connect

This patent describes a process for recovering liquid hydrocarbons. It comprises: injecting into a fractured subterranean formation a polymer enhanced foam comprising a polymer selected from a synthetic polymer or a biopolymer, a surfactant, an aqueous solvent and a gas, recovering liquid hydrocarbons from the formation.

Sydansk, R.D.

1992-07-14T23:59:59.000Z

366

Laboratory solvent reuse -- Liquid chromatography  

SciTech Connect

The objective of this work was to develop a method for reduction of waste solvent in the Process Engineering Chemistry Laboratory. The liquid chromatographs are the largest generators of explosive-contaminated waste in the laboratory. We developed a successful process for the reuse of solvents from the liquid chromatographs and demonstrated the utility of the process in the assay of hexanitrostilbene.

Quinlin, W.T.; Schaffer, C.L.

1992-11-01T23:59:59.000Z

367

Orifice mixing of immiscible liquids  

E-Print Network (OSTI)

measured with an Ostwald Viscosimeter relative to tap water also, All of these physical measurements were made at 83c F, the average tempera- ture noted during the runs. The liquid upon which these measurements were made were samples of the liquids...

McDonough, Joseph Aloysius

1960-01-01T23:59:59.000Z

368

Ab initio calculation of the electronic absorption spectrum of liquid water  

SciTech Connect

The electronic absorption spectrum of liquid water was investigated by coupling a one-body energy decomposition scheme to configurations generated by classical and Born-Oppenheimer Molecular Dynamics (BOMD). A Frenkel exciton Hamiltonian formalism was adopted and the excitation energies in the liquid phase were calculated with the equation of motion coupled cluster with single and double excitations method. Molecular dynamics configurations were generated by different approaches. Classical MD were carried out with the TIP4P-Ew and AMOEBA force fields. The BLYP and BLYP-D3 exchange-correlation functionals were used in BOMD. Theoretical and experimental results for the electronic absorption spectrum of liquid water are in good agreement. Emphasis is placed on the relationship between the structure of liquid water predicted by the different models and the electronic absorption spectrum. The theoretical gas to liquid phase blue-shift of the peak positions of the electronic absorption spectrum is in good agreement with experiment. The overall shift is determined by a competition between the O–H stretching of the water monomer in liquid water that leads to a red-shift and polarization effects that induce a blue-shift. The results illustrate the importance of coupling many-body energy decomposition schemes to molecular dynamics configurations to carry out ab initio calculations of the electronic properties in liquid phase.

Martiniano, Hugo F. M. C.; Galamba, Nuno [Grupo de Física Matemática da Universidade de Lisboa, Av. Professor Gama Pinto 2, 1649-003 Lisboa (Portugal)] [Grupo de Física Matemática da Universidade de Lisboa, Av. Professor Gama Pinto 2, 1649-003 Lisboa (Portugal); Cabral, Benedito J. Costa, E-mail: ben@cii.fc.ul.pt [Grupo de Física Matemática da Universidade de Lisboa, Av. Professor Gama Pinto 2, 1649-003 Lisboa (Portugal) [Grupo de Física Matemática da Universidade de Lisboa, Av. Professor Gama Pinto 2, 1649-003 Lisboa (Portugal); Departamento de Química e Bioquímica, Faculdade de Ciências, Universidade de Lisboa, 1749-016 Lisboa (Portugal); Instituto de Física da Universidade de São Paulo, CP 66318, 05314-970 São Paulo, SP (Brazil)

2014-04-28T23:59:59.000Z

369

Atomistic simulation of CdTe solid-liquid coexistence equilibria  

SciTech Connect

Atomistic simulations of CdTe using a Stillinger-Weber (S-W) interatomic potential were undertaken to model the solid-liquid phase equilibria of this important compound semiconductor. Although this potential has been used by others to study liquid CdTe and vapor-liquid interface, it is based on fitting parameters optimized only for the zincblende solid. It has not been fully explored as a potential for solid-liquid phase equilibria until this work. This research reports an accurate determination of the melting temperature, TM=1305K near P=0, the heat of fusion at melting and as a function of temperature up to 1700K, and on the relative phase densities with a particular emphasis on the melting line. The S-W potential for CdTe predicts a liquid with a density slightly less than that of the solid and, hence, the pressure-temperature melting line has a positive slope. The pair correlation structure of the liquid is determined and favorably compared to neutron scattering data. The liquid-solid interface is discussed using density profiles and a short-range order parameter for models having principal orientations along <100>, <110>, and <111> crystallographic directions.

Henager, Charles H.; Morris, James R.

2009-12-07T23:59:59.000Z

370

Liquid-permeable electrode  

DOE Patents (OSTI)

Electrodes for use in an electrolytic cell, which are liquid-permeable and have low electrical resistance and high internal surface area are provided of a rigid, porous, carbonaceous matrix having activated carbon uniformly embedded throughout. The activated carbon may be catalyzed with platinum for improved electron transfer between electrode and electrolyte. Activated carbon is mixed with a powdered thermosetting phenolic resin and compacted to the desired shape in a heated mold to melt the resin and form the green electrode. The compact is then heated to a pyrolyzing temperature to carbonize and volatilize the resin, forming a rigid, porous structure. The permeable structure and high internal surface area are useful in electrolytic cells where it is necessary to continuously remove the products of the electrochemical reaction.

Folser, George R. (Lower Burrell, PA)

1980-01-01T23:59:59.000Z

371

Magnetically focused liquid drop radiator  

DOE Patents (OSTI)

A magnetically focused liquid drop radiator for application in rejecting energy from a spacecraft, characterized by a magnetizable liquid or slurry disposed in operative relationship within the liquid droplet generator and its fluid delivery system, in combination with magnetic means disposed in operative relationship around a liquid droplet collector of the LDR. The magnetic means are effective to focus streams of droplets directed from the generator toward the collector, thereby to assure that essentially all of the droplets are directed into the collector, even though some of the streams may be misdirected as they leave the generator. The magnetic focusing means is also effective to suppress splashing of liquid when the droplets impinge on the collector.

Botts, T.E.; Powell, J.R.; Lenard, R.

1984-12-10T23:59:59.000Z

372

Freezing of a Liquid Marble  

E-Print Network (OSTI)

In this study, we present for the first time the observations of a freezing liquid marble. In the experiment, liquid marbles are gently placed on the cold side of a Thermo-Electric Cooler (TEC) and the morphological changes are recorded and characterized thereafter. These liquid marbles are noticed to undergo a shape transition from a spherical to a flying-saucer shaped morphology. The freezing dynamics of liquid marbles is observed to be very different from that of a freezing water droplet on a superhydrophobic surface. For example, the pointy tip appearing on a frozen water drop could not be observed for a frozen liquid marble. In the end, we highlight a possible explanation for the observed morphology.

Ali Hashmi; Adam Strauss; Jie Xu

2012-07-03T23:59:59.000Z

373

Critical point analysis of phase envelope diagram  

SciTech Connect

Phase diagram or phase envelope is a relation between temperature and pressure that shows the condition of equilibria between the different phases of chemical compounds, mixture of compounds, and solutions. Phase diagram is an important issue in chemical thermodynamics and hydrocarbon reservoir. It is very useful for process simulation, hydrocarbon reactor design, and petroleum engineering studies. It is constructed from the bubble line, dew line, and critical point. Bubble line and dew line are composed of bubble points and dew points, respectively. Bubble point is the first point at which the gas is formed when a liquid is heated. Meanwhile, dew point is the first point where the liquid is formed when the gas is cooled. Critical point is the point where all of the properties of gases and liquids are equal, such as temperature, pressure, amount of substance, and others. Critical point is very useful in fuel processing and dissolution of certain chemicals. Here in this paper, we will show the critical point analytically. Then, it will be compared with numerical calculations of Peng-Robinson equation by using Newton-Raphson method. As case studies, several hydrocarbon mixtures are simulated using by Matlab.

Soetikno, Darmadi; Siagian, Ucok W. R. [Department of Petroleum Engineering, Institut Teknologi Bandung, Jl. Ganesha 10, Bandung 40132 (Indonesia); Kusdiantara, Rudy, E-mail: rkusdiantara@s.itb.ac.id; Puspita, Dila, E-mail: rkusdiantara@s.itb.ac.id; Sidarto, Kuntjoro A., E-mail: rkusdiantara@s.itb.ac.id; Soewono, Edy; Gunawan, Agus Y. [Department of Mathematics, Institut Teknologi Bandung, Jl. Ganesha 10, Bandung 40132 (Indonesia)

2014-03-24T23:59:59.000Z

374

Onset and Subsequent Transient Phenomena of Liquid Loading in Gas Wells: Experimental Investigation Using a Large Scale Flow Loop  

E-Print Network (OSTI)

was carried out to study the onset of liquid loading and the subsequent transient phenomena, using a large scale flow loop to visualize two-phase flow regimes, and to measure pressure and liquid holdup along a 42-m long vertical tube. From this investigation...

Waltrich, Paulo

2012-10-19T23:59:59.000Z

375

Gas–liquid flow stability and bubble formation in non-Newtonian fluids in microfluidic flow-focusing devices  

Science Journals Connector (OSTI)

This communication describes the gas–liquid two-phase flow patterns and the formation of bubbles in non-Newtonian fluids in microfluidic flow-focusing devices. Experiments were conducted in two different polym...

Taotao Fu; Youguang Ma; Denis Funfschilling; Huai Z. Li

2011-05-01T23:59:59.000Z

376

Method of measuring a liquid pool volume  

DOE Patents (OSTI)

A method of measuring a molten metal liquid pool volume and in particular molten titanium liquid pools, including the steps of (a) generating an ultrasonic wave at the surface of the molten metal liquid pool, (b) shining a light on the surface of a molten metal liquid pool, (c) detecting a change in the frequency of light, (d) detecting an ultrasonic wave echo at the surface of the molten metal liquid pool, and (e) computing the volume of the molten metal liquid.

Garcia, Gabe V. (Las Cruces, NM); Carlson, Nancy M. (Idaho Falls, ID); Donaldson, Alan D. (Idaho Falls, ID)

1991-01-01T23:59:59.000Z

377

Method for beam steering compensation in an ultra-high power liquid laser  

DOE Patents (OSTI)

Thermally induced distortion of the optical wavefront caused by heating of the laser media by waste heat from the excitation process and absorption of laser radiation creates optical phase errors. A system generates an error signal derived from the optical phase errors. The error signal is fed back to the power supplies driving semiconductor diodes that excite the lasing liquid thereby introducing an electrically controllable wedge into the optical cavity to correct the optical phase errors.

Ault, Earl R. (Livermore, CA)

2002-01-01T23:59:59.000Z

378

New theories for smectic and nematic liquid crystalline polymers  

SciTech Connect

A summary of results from new statistical-physics theories for both backbone and side-chain liquid crystalline polymers (LCPs) and for mixtures with LCPs is presented. Thermodynamic and molecular ordering properties (including odd-even effects) have been calculated as a function of pressure, density, temperature, and molecule chemical structures (including degree of polymerization and the following properties of the chemical structures of the repeat units: lengths and shapes, intra-chain rotation energies, dipole moments, site-site polarizabilities and Lennard-Jones potentials, etc.) in nematic and multiple smectic-A LC phases and in the isotropic liquid phase. These theories can also be applied to combined LCPs. Since these theories have no ad hoc or arbitrarily adjustable parameters, these theories have been used to design new LCPs and new solvents and to predict and explain properties.

Dowell, F.

1987-01-01T23:59:59.000Z

379

Liquid Hydrogen Delivery - Strategic Directions for Hydrogen...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Liquid Hydrogen Delivery - Strategic Directions for Hydrogen Delivery Workshop Liquid Hydrogen Delivery - Strategic Directions for Hydrogen Delivery Workshop Targets, barriers and...

380

Study on the melting and solidification in a glass block containing a phase change material  

E-Print Network (OSTI)

Study on the melting and solidification in a glass block containing a phase change material.virgone@insa-lyon.fr and kevy.johannes@insa-lyon.fr Abstract This paper presents an experimental analysis of a phase change the phenomenon of phase change in an enclosure, focusing the research on the role of natural convection in liquid

Paris-Sud XI, Université de

Note: This page contains sample records for the topic "non-aqueous phase liquid" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Reduced gravity rankine cycle design and optimization with passive vortex phase separation  

E-Print Network (OSTI)

. Potential drawbacks to the technology in a reduced gravity environment include two-phase fluid management processes such as liquid-vapor phase separation. The most critical location for phase separation is at the boiler exit where only vapor must be sent...

Supak, Kevin Robert

2009-05-15T23:59:59.000Z

382

A Network Model for The Genesis and Migration of Gas Phase  

E-Print Network (OSTI)

1 A Network Model for The Genesis and Migration of Gas Phase Koukung Alex Chang and W. Brent, of a compositional fluid consisting of water with a dissolved hydrocarbon gas. The model captures both single phase 99% of the (effectively) stored CO2 resides in the liquid phase. Key Words: network model, gas

New York at Stoney Brook, State University of

383

Frostbite Theater - Liquid Nitrogen Experiments - Instant Liquid Nitrogen  

NLE Websites -- All DOE Office Websites (Extended Search)

Freezing Balloons! Freezing Balloons! Previous Video (Freezing Balloons!) Frostbite Theater Main Index Next Video (Shattering Flowers!) Shattering Flowers! Instant Liquid Nitrogen Balloon Party! Need a bunch of balloons blown-up quickly? Liquid nitrogen to the rescue! [ Show Transcript ] Announcer: Frostbite Theater presents... Cold Cuts! No baloney! Joanna and Steve: Just science! Joanna: Hi! I'm Joanna! Steve: And I'm Steve! Joanna: We've been making videos for a while now and we've learned that people like balloons and liquid nitrogen! Steve: So... Here you go! Balloon: Crackling... Balloon: Pop! Joanna: Ooh! Balloon: Pop! Balloon: Pop! Steve: If you'd like to know the science of what's going on behind this, please one of our first videos, "Liquid Nitrogen Experiments: The Balloon."

384

Performance evaluation of organic emulsion liquid membrane on phenol removal  

E-Print Network (OSTI)

The percentage removal of phenol from aqueous solution by emulsion liquid membrane and emulsion leakage was investigated experimentally for various parameters such as membrane:internal phase ratio, membrane:external phase ratio, emulsification speed, emulsification time, carrier concentration, surfactant concentration and internal agent concentration. These parameters strongly influence the percentage removal of phenol and emulsion leakage. Under optimum membrane properties, the percentage removal of phenol was as high as 98.33%, with emulsion leakage of 1.25%. It was also found that the necessity of carrier for enhancing phenol removal was strongly dependent on the internal agent concentration.

Ng, Y S; Hashim, M A

2014-01-01T23:59:59.000Z

385

Microwave dielectric heating of non-aqueous droplets in a microfluidic device for nanoparticle synthesis  

E-Print Network (OSTI)

of segmented ow reactors, in comparison with their continuous counterparts, allows nanoliter volumes. Recent developments have been directed toward scaling out of the processes by adding reactors working to directly determine the temperature inside a single droplet. The maximum temperature achieved

386

Membrane permeation process for dehydration of organic liquid mixtures using sulfonated ion-exchange polyalkene membranes  

DOE Patents (OSTI)

A membrane permeation process for dehydrating a mixture of organic liquids, such as alcohols or close boiling, heat sensitive mixtures. The process comprises causing a component of the mixture to selectively sorb into one side of sulfonated ion-exchange polyalkene (e.g., polyethylene) membranes and selectively diffuse or flow therethrough, and then desorbing the component into a gas or liquid phase on the other side of the membranes.

Cabasso, Israel (131 Buckingham Ave., Syracuse, NY 13210); Korngold, Emmanuel (P.O. Box 1025, Beer-Sheva 84110, IL)

1988-01-01T23:59:59.000Z

387

The Viscosity of Liquid Helium  

Science Journals Connector (OSTI)

2 September 1935 research-article The Viscosity of Liquid Helium J. O. Wilhelm A. D. Misener A. R. Clark The Royal Society is collaborating with JSTOR to digitize, preserve...

1935-01-01T23:59:59.000Z

388

Liquid Oxygen and its Uses  

Science Journals Connector (OSTI)

... of the liquid. At present, however, there is no known method of rendering them flameless, and their use in the majority of coal-mines is therefore inadmissible. If this ...

HENRY BRIGGS

1924-02-02T23:59:59.000Z

389

Gaseous and Liquid Hydrogen Storage  

Energy.gov (U.S. Department of Energy (DOE))

Today's state of the art for hydrogen storage includes 5,000- and 10,000-psi compressed gas tanks and cryogenic liquid hydrogen tanks for on-board hydrogen storage.

390

Liquid helium cryo TEM | EMSL  

NLE Websites -- All DOE Office Websites (Extended Search)

cryo TEM Liquid helium cryo TEM The JEOL JEM-3000SFF was designed for high-resolution cryogenic transmission electron microscopy (cryo-EM) of biological samples and expands EMSL...

391

Essays on liquidity and information  

E-Print Network (OSTI)

This dissertation studies the interaction of liquidity and incomplete or asymmetric information. In Chapter 1, I study a dynamic economy with illiquidity due to adverse selection in financial markets. Investment is undertaken ...

Kurlat, Pablo (Pablo Daniel)

2010-01-01T23:59:59.000Z

392

Implementation of controlled phase shift gates and Collins version of Deutsch-Jozsa algorithm on a quadrupolar spin-7/2 nucleus using non-adiabatic geometric phases  

E-Print Network (OSTI)

In this work Controlled phase shift gates are implemented on a qaudrupolar system, by using non-adiabatic geometric phases. A general procedure is given, for implementing controlled phase shift gates in an 'N' level system. The utility of such controlled phase shift gates, is demonstrated here by implementing 3-qubit Deutsch-Jozsa algorithm on a 7/2 quadrupolar nucleus oriented in a liquid crystal matrix.

T. Gopinath; Anil Kumar

2009-09-22T23:59:59.000Z

393

Simultaneous liquid–liquid and vapour–liquid equilibria predictions of selected oxygenated aromatic molecules in mixtures with alkanes, alcohols, water, using the polar GC-PC-SAFT  

Science Journals Connector (OSTI)

Abstract Phase equilibria of oxygen-bearing aromatic compounds, hydrocarbons and water mixtures are of essential interest in many processes using feeds originating from biomass. The strong non-ideal thermodynamic behavior of these systems sometimes results in immiscibility with both water and alkanes. To address this problem, the GC-PPC-SAFT equation of state [Tamouza et al., 2004; Nguyen-Huynh et al., 2008a] is extended to some selected components: phenol, alkyl-phenols, alkyl-benzoates, benzaldehyde and anisole. However, as in these multifunctional compounds, the proximity of polar functional groups may result in a lack of transferability of the parameters from the monofunctional homologous species, some parameters have been adapted in view of physical arguments. Next, liquid–vapour and liquid–liquid equilibria of mixtures with n-alkanes were evaluated, using a predictive method for the binary interaction parameters (kij) [Nguyen-Huynh et al., 2008b]. Finally, mixtures with other associating compounds, as alcohols and water have also been considered. In all cases, both correlations and predictions are qualitatively and quantitatively satisfactory. The relative deviations obtained on bubble pressure of vapor–liquid equilibria are 4–8%, that is comparable to those obtained on previously investigated systems.

Nguyen-Huynh Dong; de Hemptinne Jean-Charles; Lugo Rafael; Passarello Jean-Philippe; Tobaly Pascal

2014-01-01T23:59:59.000Z

394

SRS - Programs - Liquid Waste Disposition  

NLE Websites -- All DOE Office Websites (Extended Search)

Liquid Waste Disposition Liquid Waste Disposition This includes both the solidification of highly radioactive liquid wastes stored in SRS's tank farms and disposal of liquid low-level waste generated as a by-product of the separations process and tank farm operations. This low-level waste is treated in the Effluent Treatment Facility. High-activity liquid waste is generated at SRS as by-products from the processing of nuclear materials for national defense, research and medical programs. The waste, totaling about 36 million gallons, is currently stored in 49 underground carbon-steel waste tanks grouped into two "tank farms" at SRS. While the waste is stored in the tanks, it separates into two parts: a sludge that settles on the bottom of the tank, and a liquid supernate that resides on top of the sludge. The waste is reduced to about 30 percent of its original volume by evaporation. The condensed evaporator "overheads" are transferred to the Effluent Treatment Project for final cleanup prior to release to the environment. As the concentrate cools a portion of it crystallizes forming solid saltcake. The concentrated supernate and saltcake are less mobile and therefore less likely to escape to the environment in the event of a tank crack or leak.

395

Laboratory and pilot field-scale testing of surfactants for environmental restoration of chlorinated solvent DNAPLs  

SciTech Connect

This project is composed of two phases and has the objective of demonstrating surfactant-enhanced aquifer remediation (SEAR) as a practical remediation technology at DOE sites with ground water contaminated by dense, non-aqueous phase liquids (DNAPLs), in particular, chlorinated solvents. The first phase of this project, Laboratory and Pilot Field Scale Testing, which is the subject of the work so far, involves (1) laboratory experiments to examine the solubilization of multiple component DNAPLs, e.g., solvents such as perchloroethylene (PCE) and trichloroethylene (TCE), by dilute surfactant solutions, and (2) a field test to demonstrate SEAR technology on a small scale and in an existing well.

Jackson, R.E. [INTERA, Inc., Austin, TX (United States); Fountain, J.C. [State Univ. of New York, Buffalo, NY (United States)

1994-12-31T23:59:59.000Z

396

Heating-induced glass-glass and glass-liquid transformations in computer simulations of water  

SciTech Connect

Water exists in at least two families of glassy states, broadly categorized as the low-density (LDA) and high-density amorphous ice (HDA). Remarkably, LDA and HDA can be reversibly interconverted via appropriate thermodynamic paths, such as isothermal compression and isobaric heating, exhibiting first-order-like phase transitions. We perform out-of-equilibrium molecular dynamics simulations of glassy water using the ST2 model to study the evolution of LDA and HDA upon isobaric heating. Depending on pressure, glass-to-glass, glass-to-crystal, glass-to-vapor, as well as glass-to-liquid transformations are found. Specifically, heating LDA results in the following transformations, with increasing heating pressures: (i) LDA-to-vapor (sublimation), (ii) LDA-to-liquid (glass transition), (iii) LDA-to-HDA-to-liquid, (iv) LDA-to-HDA-to-liquid-to-crystal, and (v) LDA-to-HDA-to-crystal. Similarly, heating HDA results in the following transformations, with decreasing heating pressures: (a) HDA-to-crystal, (b) HDA-to-liquid-to-crystal, (c) HDA-to-liquid (glass transition), (d) HDA-to-LDA-to-liquid, and (e) HDA-to-LDA-to-vapor. A more complex sequence may be possible using lower heating rates. For each of these transformations, we determine the corresponding transformation temperature as function of pressure, and provide a P-T “phase diagram” for glassy water based on isobaric heating. Our results for isobaric heating dovetail with the LDA-HDA transformations reported for ST2 glassy water based on isothermal compression/decompression processes [Chiu et al., J. Chem. Phys. 139, 184504 (2013)]. The resulting phase diagram is consistent with the liquid-liquid phase transition hypothesis. At the same time, the glass phase diagram is sensitive to sample preparation, such as heating or compression rates. Interestingly, at least for the rates explored, our results suggest that the LDA-to-liquid (HDA-to-liquid) and LDA-to-HDA (HDA-to-LDA) transformation lines on heating are related, both being associated with the limit of kinetic stability of LDA (HDA)

Chiu, Janet; Giovambattista, Nicolas [Department of Physics, Brooklyn College of the City University of New York, Brooklyn, New York 11210 (United States)] [Department of Physics, Brooklyn College of the City University of New York, Brooklyn, New York 11210 (United States); Starr, Francis W. [Department of Physics, Wesleyan University, Middletown, Connecticut 06459 (United States)] [Department of Physics, Wesleyan University, Middletown, Connecticut 06459 (United States)

2014-03-21T23:59:59.000Z

397

Extremely Correlated Fermi Liquids B. Sriram Shastry  

E-Print Network (OSTI)

Extremely Correlated Fermi Liquids B. Sriram Shastry Physics Department, University of California the theory of an extremely correlated Fermi liquid with U ! 1. This liquid has an underlying auxiliary Fermi liquid Green's function that is further caparisoned by extreme correlations. The theory leads to two

California at Santa Cruz, University of

398

Commercialization of Coal-to-Liquids Technology  

SciTech Connect

The report provides an overview of the current status of coal-to-liquids (CTL) commercialization efforts, including an analysis of efforts to develop and implement large-scale, commercial coal-to-liquids projects to create transportation fuels. Topics covered include: an overview of the history of coal usage and the current market for coal; a detailed description of what coal-to-liquids technology is; the history of coal-to-liquids development and commercial application; an analysis of the key business factors that are driving the increased interest in coal-to-liquids; an analysis of the issues and challenges that are hindering the commercialization of coal-to-liquids technology; a review of available coal-to-liquids technology; a discussion of the economic drivers of coal-to-liquids project success; profiles of key coal-to-liquids developers; and profiles of key coal-to-liquids projects under development.

NONE

2007-08-15T23:59:59.000Z

399

USE OF NATURALLY-OCCURRING TRACERS TO MONITOR TWO-PHASE CONDITIONS IN THE  

Open Energy Info (EERE)

NATURALLY-OCCURRING TRACERS TO MONITOR TWO-PHASE CONDITIONS IN THE NATURALLY-OCCURRING TRACERS TO MONITOR TWO-PHASE CONDITIONS IN THE COSO EGS PROJECT Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Conference Proceedings: USE OF NATURALLY-OCCURRING TRACERS TO MONITOR TWO-PHASE CONDITIONS IN THE COSO EGS PROJECT Details Activities (1) Areas (1) Regions (0) Abstract: A dramatic decrease in the ratio of chloride to boron was observed in the liquid discharge of a well proposed for EGS development in the Coso geothermal field. The decrease appears to be related to the transformation of some feed zones in the well from liquid-dominated to vapor-dominated. High concentrations of boron are transported to the wellbore in the steam, where it fractionates to the liquid phase flowing in from liquid-dominated feed zones. The high-boron steam is created when the

400

Rheological response and dynamics of the amphiphilic diamond phase from kinetic lattice–Boltzmann simulations  

Science Journals Connector (OSTI)

...diamond phase from kinetic lattice-Boltzmann simulations R.S. Saksena...are performed using a kinetic lattice-Boltzmann method. Lyotropic liquid crystals...studied previously using our lattice-Boltzmann (LB) approach (Gonzalez-Segredo...

2009-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "non-aqueous phase liquid" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

A high order moment method for the simulation of polydisperse two-phase flows  

E-Print Network (OSTI)

gas phase and a more natural coupling with the pri- mary atomization methods than Lagrangian methods of a liquid fuel in a gaseous flow field (automo- tive engines, aeronautical combustors, industrial furnaces

Paris-Sud XI, Université de

402

Analytical Investigation of Glaciation Time in Mixed-Phase Adiabatic Cloud Volumes  

Science Journals Connector (OSTI)

Glaciation in mixed-phase adiabatic cloudy parcels is investigated analytically using two new equations: the equation for coexistence of liquid water and ice and the mass balance equation. The analysis of glaciation time is performed for a ...

M. Pinsky; A. Khain; A. Korolev

2014-11-01T23:59:59.000Z

403

High temperature ceramic membrane reactors for coal liquid upgrading  

SciTech Connect

Membrane reactors are today finding extensive applications for gas and vapor phase catalytic reactions (see discussion in the introduction and recent reviews by Armor [92], Hsieh [93] and Tsotsis et al. [941]). There have not been any published reports, however, of their use in high pressure and temperature liquid-phase applications. The idea to apply membrane reactor technology to coal liquid upgrading has resulted from a series of experimental investigations by our group of petroleum and coal asphaltene transport through model membranes. Coal liquids contain polycyclic aromatic compounds, which not only present potential difficulties in upgrading, storage and coprocessing, but are also bioactive. Direct coal liquefaction is perceived today as a two-stage process, which involves a first stage of thermal (or catalytic) dissolution of coal, followed by a second stage, in which the resulting products of the first stage are catalytically upgraded. Even in the presence of hydrogen, the oil products of the second stage are thought to equilibrate with the heavier (asphaltenic and preasphaltenic) components found in the feedstream. The possibility exists for this smaller molecular fraction to recondense with the unreacted heavy components and form even heavier undesirable components like char and coke. One way to diminish these regressive reactions is to selectively remove these smaller molecular weight fractions once they are formed and prior to recondensation. This can, at least in principle, be accomplished through the use of high temperature membrane reactors, using ceramic membranes which are permselective for the desired products of the coal liquid upgrading process. An additional incentive to do so is in order to eliminate the further hydrogenation and hydrocracking of liquid products to undesirable light gases.

Tsotsis, T.T. (University of Southern California, Los Angeles, CA (United States). Dept. of Chemical Engineering); Liu, P.K.T. (Aluminum Co. of America, Pittsburgh, PA (United States)); Webster, I.A. (Unocal Corp., Los Angeles, CA (United States))

1992-01-01T23:59:59.000Z

404

Core-softened Fluids, Water-like Anomalies and the Liquid-Liquid Critical Points  

E-Print Network (OSTI)

. INTRODUCTION Water is characterized by well-known thermodynamic and kinetic liquid-state anomalies; for examplePREPRINT Core-softened Fluids, Water-like Anomalies and the Liquid-Liquid Critical Points Evy simulations are used to examine the relationship between water-like anoma- lies and the liquid-liquid critical

Barbosa, Marcia C. B.

405

From an insulating to a superfluid pair-bond liquid  

Science Journals Connector (OSTI)

We study an exchange coupled system of itinerant electrons and localized fermion pairs resulting in a resonant pairing formation. This system inherently contains resonating fermion pairs on bonds that lead to a superconducting phase, provided that long-range phase coherence between their constituents can be established. The prerequisite is that the resonating fermion pairs can become itinerant. This is rendered possible through the emergence of two kinds of bond fermions: individual and composite fermions made of one individual electron attached to a bound pair on a bond. If the strength of the exchange coupling exceeds a certain value, then the superconducting ground state undergoes a quantum phase transition into an insulating pair-bond liquid state. The gap of the superfluid phase thereby goes over continuously into a charge gap of the insulator. The changeover from the superconducting to the insulating phase is accompanied by a corresponding qualitative modification of the dispersion of the two kinds of fermionic excitations. Using a bond operator formalism, we derive the phase diagram of such a scenario together with the elementary excitations characterizing the various phases as a function of the exchange coupling and the temperature.

M. Cuoco and J. Ranninger

2006-09-20T23:59:59.000Z

406

Phase-field theory of brine entrapment in sea ice: Short-time frozen microstructures  

E-Print Network (OSTI)

We analyze the early phase of brine entrapment in sea ice, using a phase field model. This model for a first-order phase transition couples non-conserved order parameter kinetics to salt diffusion. The evolution equations are derived from a Landau-Ginzburg order parameter gradient dynamics together with salinity conservation. The numerical solution of model equations by an exponential time differencing scheme describes the time evolution of phase separation between liquid water with high salinity and the ice phase with low salinity. The numerical solution in one and two dimensions indicates the formation of one dominant wavelength which sets the length scale of short-time frozen structures. A stability analysis provides the phase diagram in terms of two Landau parameters. It is distinguished an uniform ice phase, a homogeneous liquid saline water solution and a phase where solidification structures can be formed. The Landau parameters are extracted from the supercooling and superheating as well as the freezin...

Thoms, Silke; Morawetz, Klaus

2014-01-01T23:59:59.000Z

407

Journal of Molecular Catalysis B: Enzymatic 27 (2004) 243248 Biocatalysis in ionic liquids: the stereoconvergent hydrolysis of  

E-Print Network (OSTI)

of the most commonly proposed green alternatives to organic solvents, the use of enzymes in non-aqueous media it was established that enzymes could work in organic solvents, with little or no-water, research in this area surged, and the use of organic solvents has raised questions of en- vironmental concern, in particular when

Hammock, Bruce D.

408

Gas: A Neglected Phase in Remediation of Metals and Radionuclides  

SciTech Connect

The gas phase is generally ignored in remediation of metals and radionuclides because it is assumed that there is no efficient way to exploit it. In the literal sense, all remediations involve the gas phase because this phase is linked to the liquid and solid phases by vapor pressure and thermodynamic relationships. Remediation methods that specifically use the gas phase as a central feature have primarily targeted volatile organic contaminants, not metals and radionuclides. Unlike many organic contaminants, the vapor pressure and Henry's Law constants of metals and radionuclides are not generally conducive to direct air stripping of dissolved contaminants. Nevertheless, the gas phase can play an important role in remediation of inorganic contaminants and provide opportunities for efficient, cost effective remediation. The objective here is to explore ways in which manipulation of the gas phase can be used to facilitate remediation of metals and radionuclides.

Denham, Miles E.; Looney, Brian B

2005-09-28T23:59:59.000Z

409

Nuclear collective excitations in a two-phase coexistence region  

SciTech Connect

The relation between collective modes and phase transitions in nuclear matter is examined. The dispersion relations for the low-lying excitations in a linear approach are evaluated within a Landau-Fermi liquid scheme by assuming coexisting phases in thermodynamical equilibrium. Temperature and isospin composition are used as relevant parameters. The in-medium nuclear interaction is provided by a recently proposed density functional model. The low density liquid-gas phase transition is taken as a typical situation for examination. We found significative modifications in the energy spectrum, within a certain range of temperatures and isospin asymmetry, due to the separation of matter into independent phases. The influence of the electromagnetic interaction over the dispersion relation of these collective excitations is also examined.

Aguirre, R. M.; De Paoli, A. L. [Departamento de Fisica, Facultad de Ciencias Exactas, Universidad Nacional de La Plata, and IFLP, CCT-La Plata, CONICET. Argentina (Argentina)

2011-04-15T23:59:59.000Z

410

Physical Properties of Ionic Liquids  

NLE Websites -- All DOE Office Websites (Extended Search)

Physical Properties of Ionic Liquids Consisting of the Physical Properties of Ionic Liquids Consisting of the 1-Butyl-3-Methylimidazolium Cation with Various Anions and the Bis(trifluoromethylsulfonyl)imide Anion with Various Cations Hui Jin, Bernie O'Hare, Jing Dong, Sergei Arzhantsev, Gary A. Baker, James F. Wishart, Alan J. Benesi, and Mark Maroncelli J. Phys. Chem. B 112, 81-92 (2008). [Find paper at ACS Publications] Abstract: Physical properties of 4 room-temperature ionic liquids consisting of the 1-butyl-3-methylimidazolium cation with various perfluorinated anions and the bis(trifluoromethylsulfonyl)imide (Tf2N-) anion with 12 pyrrolidinium-, ammonium-, and hydroxyl-containing cations are reported. Electronic structure methods are used to calculate properties related to the size, shape, and dipole moment of individual ions. Experimental measurements of

411

The ATLAS Liquid Argon Calorimeter: Construction, Integration, Commissioning  

SciTech Connect

The ATLAS liquid argon (LAr) calorimeter system consists of an electromagnetic barrel calorimeter and two end caps with electromagnetic, hadronic and forward calorimeters. The liquid argon sampling technique, with an accordion geometry was chosen for the barrel electromagnetic calorimeter (EMB) and adapted to the end cap (EMEC). The hadronic end cap calorimeter (HEC) uses a copper-liquid argon sampling technique with flat plate geometry and is subdivided in depth in two wheels per end-cap. Finally, the forward calorimeter (FCAL) is composed of three modules employing cylindrical electrodes with thin liquid argon gaps.The construction of the full calorimeter system is complete since mid-2004. Production modules constructed in the home institutes were integrated into wheels at CERN in 2003-2004, and inserted into the three cryostats. They passed their first complete cold test before the lowering into the ATLAS cavern. Results of quality checks (e.g. electrical, mechanical, ...) performed on all the 190304 read-out channels after cool down will be reported. End 2004 the ATLAS barrel electromagnetic (EM) calorimeter was installed in the ATLAS cavern and since summer 2005 the front-end electronics are being connected and tested. Results of this first commissioning phase will be shown to demonstrate the high standards of quality control for our detectors.

Aleksa, Martin [PH-Department, CERN, 1211 Geneva (Switzerland)

2006-10-27T23:59:59.000Z

412

Generation of vector beams with liquid crystal disclination lines  

E-Print Network (OSTI)

We report that guiding light beams, ranging from continuous beams to femtosecond pulses, along liquid crystal defect lines can transform them into vector beams with various polarization profiles. Using Finite Difference Time Domain numerical solving of Maxwell equations, we confirm that the defect in the orientational order of the liquid crystal induces a defect in the light field with twice the winding number of the liquid crystal defect, coupling the topological invariants of both fields. For example, it is possible to transform uniformly-polarized light into light with a radial polarization profile. Our approach also correctly yields a zero-intensity region near the defect core, which is always present in areas of discontinuous light polarization or phase. Using circularly polarized incident light, we show that defects with non-integer winding numbers can be obtained, where topological constants are preserved by phase vortices, demonstrating coupling between the light's spin, orbital angular momentum and polarization profile. Further, we find an ultrafast femtosecond laser pulse travelling along a defect line splits into multiple intensity regions, again depending on the defect's winding number, allowing applications in beam steering and filtering. Finally, our approach describing generation of complex optical fields via coupling with topological defect lines in optically birefringent nematic fluids can be easily extended to high-intensity beams that affect nematic ordering.

Miha ?an?ula; Miha Ravnik; Slobodan Žumer

2014-08-12T23:59:59.000Z

413

Liquid soap film generates electricity  

E-Print Network (OSTI)

We have observed that a rotating liquid soap film generates electricity when placed between two non-contact electrodes with a sufficiently large potential difference. In our experiments suspended liquid film (water + soap film) is formed on the surface of a circular frame, which is forced to rotate in the $x-y$ horizontal plane by a motor. This system is located at the center of two capacitor-like vertical plates to apply an external electric voltage difference in the $x-$direction. The produced electric current is collected from the liquid film using two conducting electrodes that are separated in the $y-$direction. We previously reported that a liquid film in an external electric field rotates when an electric current passes through it, naming it the liquid film motor (LFM). In this paper we report a novel technique, in which a similar device can be used as an electric generator, converting the rotating mechanical energy to electrical energy. The liquid film electric generator (LFEG) is in stark contrast to the LFM, both of which could be designed similarly in very small scales like micro scales with different applications. Although the device is comparable to commercial electric motors or electric generators, there is a significant difference in their working principles. Usually in an electric motor or generator the magnetic field causes the driving force, while in a LFM or LFEG the Coulomb force is the driving force. This fact is also interesting from the Bio-science point of view and brings a similarity to bio motors. Here we have investigated the electrical characteristics of such a generator for the first time experimentally and modelled the phenomenon with electroconvection governing equations. A numerical simulation is performed using the local approximation for the charge-potential relation and results are in qualitative agreement with experiments.

Ahmad Amjadi; Sadegh Feiz; Reza Montazeri Namin

2014-04-24T23:59:59.000Z

414

CrowdPhase: crowdsourcing the phase problem  

Science Journals Connector (OSTI)

The idea of attacking the phase problem by crowdsourcing is introduced. Using an interactive, multi-player, web-based system, participants work simultaneously to select phase sets that correspond to better electron-density maps in order to solve low-resolution phasing problems.

Jorda, J.

2014-05-23T23:59:59.000Z

415

Intercomparison of the Cloud Water Phase among Global Climate Models  

SciTech Connect

Mixed-phase clouds (clouds that consist of both cloud droplets and ice crystals) are frequently present in the Earth’s atmosphere and influence the Earth’s energy budget through their radiative properties, which are highly dependent on the cloud water phase. In this study, the phase partitioning of cloud water is compared among six global climate models (GCMs) and with Cloud and Aerosol Lidar with Orthogonal Polarization retrievals. It is found that the GCMs predict vastly different distributions of cloud phase for a given temperature, and none of them are capable of reproducing the spatial distribution or magnitude of the observed phase partitioning. While some GCMs produced liquid water paths comparable to satellite observations, they all failed to preserve sufficient liquid water at mixed-phase cloud temperatures. Our results suggest that validating GCMs using only the vertically integrated water contents could lead to amplified differences in cloud radiative feedback. The sensitivity of the simulated cloud phase in GCMs to the choice of heterogeneous ice nucleation parameterization is also investigated. The response to a change in ice nucleation is quite different for each GCM, and the implementation of the same ice nucleation parameterization in all models does not reduce the spread in simulated phase among GCMs. The results suggest that processes subsequent to ice nucleation are at least as important in determining phase and should be the focus of future studies aimed at understanding and reducing differences among the models.

Komurcu, Muge; Storelvmo, Trude; Tan, Ivy; Lohmann, U.; Yun, Yuxing; Penner, Joyce E.; Wang, Yong; Liu, Xiaohong; Takemura, T.

2014-03-27T23:59:59.000Z

416

Application of Ionic Liquids in Liquid Chromatography and Electrodriven Separation  

Science Journals Connector (OSTI)

......processing (5), solvent extraction (6, 7), electrolytes in batteries (8), metal deposition (9, 10) and gas treatment (11...Polymerized ionic liquid sorbents for CO2 separation. Energy and Fuels (2010) 24:5797-5804. 13 Ho T.D. , Canestraro A......

Yi Huang; Shun Yao; Hang Song

2013-08-01T23:59:59.000Z

417

Hard-sphere and hard-disk freezing from the differential formulation of the generalized effective liquid approximation  

Science Journals Connector (OSTI)

We apply the differential formulation of the generalized effective liquid approximation to the study of hard-sphere and hard-disk freezing. We show that the thermodynamic properties of the solid phase are rather insensitive to the compressibility factor of the fluid phase used to map the solid onto the effective liquid. The solid-fluid coexistence data instead are quite dependent on the equation of state describing the fluid phase. Very accurate results, as compared with the simulation data, are obtained for both the freezing of hard spheres and hard disks.

C. F. Tejero and J. A. Cuesta

1993-01-01T23:59:59.000Z

418

Method of measuring a liquid pool volume  

DOE Patents (OSTI)

A method of measuring a molten metal liquid pool volume and in particular molten titanium liquid pools is disclosed, including the steps of (a) generating an ultrasonic wave at the surface of the molten metal liquid pool, (b) shining a light on the surface of a molten metal liquid pool, (c) detecting a change in the frequency of light, (d) detecting an ultrasonic wave echo at the surface of the molten metal liquid pool, and (e) computing the volume of the molten metal liquid. 3 figures.

Garcia, G.V.; Carlson, N.M.; Donaldson, A.D.

1991-03-19T23:59:59.000Z

419

Structure H hydrate phase equilibria of paraffins, naphthalenes, and olefins with methane  

SciTech Connect

Initial phase equilibrium data are reported for 10 methane + liquid hydrocarbon systems forming structure H hydrates in the pressure range of 1--6 MPa. Four-phase equilibrium conditions were measured for each system, with paraffinic, naphthenic, and olefinic liquid hydrocarbons filling the large cage of structure H, and methane stabilizing the two smaller cages present in the hydrate. Many of these liquid hydrocarbons constitute a small fraction of crude oils and condensates, and the high stability and relative ease of formation of structure H suggest a possible impact of these hydrates upon hydrocarbon facilities.

Mehta, A.P.; Sloan, E.D. Jr. (Colorado School of Mines, Golden, CO (United States))

1994-10-01T23:59:59.000Z

420

Calculation of complex phase equilibria of DMF/alkane systems using the PCP-SAFT equation of state  

Science Journals Connector (OSTI)

Abstract The Perturbed Chain Polar Statistical Association Fluid Theory (PCP-SAFT) equation of state is applied to calculate phase equilibria data for several DMF/alkane systems. DMF/alkane systems exhibit a peculiar phase behavior, due to overlapping liquid–liquid and vapor–liquid coexistence regions. Hetero- and homoazeotropes appear and disappear depending on temperature/pressure conditions and the chain length of the alkane. The vapor–liquid, liquid–liquid and vapor–liquid–liquid equilibria of DMF/alkanes systems including alkanes from C5 to C10 were studied in detail over wide temperature and pressure ranges. A single, linear expression for the binary interaction parameter kij as function of temperature and alkane chain length was used to model the experimental data. This expression was determined only by using experimental liquid–liquid equilibria (LLE) data of DMF/alkane systems. Using that, the PCP-SAFT equation of state provides very satisfying results for the description of the phase behavior in all considered systems.

Elisabeth Schäfer; Gabriele Sadowski; Sabine Enders

2014-01-01T23:59:59.000Z

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421

Electrodeposition of Crystalline GaAs on Liquid Gallium Electrodes in Aqueous Electrolytes  

Science Journals Connector (OSTI)

Crystalline gallium arsenide (c-GaAs) possesses many desirable optoelectronic properties suited for solar energy conversion,(1) light and radiation detection,(2) chemical sensing,(3) lighting,(4) and high speed electronics. ... In contrast to conflicting previous reports on the electrodeposition of GaAs,(17, 18) we posit that c-GaAs(s) can be synthesized predictably through the electrodeposition of As from dissolved As2O3 specifically on a Ga(l) electrode at modest temperatures in water. ... Specifically, for any binary system composed of a solid dissolving into a liquid, the rate of dissolution of the solid into the liquid phase is given by eq 5:(60)(5)where kdiss is the dissolution rate constant, s is the surface area of the solid in contact with the liquid, V is the volume of the liquid, Csat is the solubility of the solid in the liquid, and Cdiss is the concentration of the dissolved solid in the bulk of the liquid phase. ...

Eli Fahrenkrug; Junsi Gu; Stephen Maldonado

2012-12-24T23:59:59.000Z

422

Gas-liquid critical point in ionic fluids  

E-Print Network (OSTI)

Based on the method of collective variables we develop the statistical field theory for the study of a simple charge-asymmetric $1:z$ primitive model (SPM). It is shown that the well-known approximations for the free energy, in particular DHLL and ORPA, can be obtained within the framework of this theory. In order to study the gas-liquid critical point of SPM we propose the method for the calculation of chemical potential conjugate to the total number density which allows us to take into account the higher order fluctuation effects. As a result, the gas-liquid phase diagrams are calculated for $z=2-4$. The results demonstrate the qualitative agreement with MC simulation data: critical temperature decreases when $z$ increases and critical density increases rapidly with $z$.

O. Patsahan; I. Mryglod; T. Patsahan

2006-06-27T23:59:59.000Z

423

Program predicts two-phase pressure gradients  

SciTech Connect

The calculator program discussed, ORK, was designed for the HP-41CV hand-held calculator and uses the Orkiszewski correlation for predicting 2-phase pressure gradients in vertical tubulars. Accurate predictions of pressure gradients in flowing and gas lift wells over a wide range of well conditions can be obtained with this method, which was developed based on data from 148 wells. The correlation is one of the best generalized 2-phase pressure gradient prediction methods developed to date for vertical flow. It is unique in that hold-up is derived from observed physical phenomena, and the pressure gradient is related to the geometrical distribution of the liquid and gas phase (flow regime).

Jacks, D.C.; Hill, A.D.

1983-11-18T23:59:59.000Z

424

Stiffening solids with liquid inclusions  

E-Print Network (OSTI)

From bone and wood to concrete and carbon fibre, composites are ubiquitous natural and engineering materials. Eshelby's inclusion theory describes how macroscopic stress fields couple to isolated microscopic inclusions, allowing prediction of a composite's bulk mechanical properties from a knowledge of its microstructure. It has been extended to describe a wide variety of phenomena from solid fracture to cell adhesion. Here, we show experimentally and theoretically that Eshelby's theory breaks down for small liquid inclusions in a soft solid. In this limit, an isolated droplet's deformation is strongly size-dependent with the smallest droplets mimicking the behaviour of solid inclusions. Furthermore, in opposition to the predictions of conventional composite theory, we find that finite concentrations of small liquid inclusions enhance the stiffness of soft solids. A straight-forward extension of Eshelby's theory, accounting for the surface tension of the solid-liquid interface, explains our experimental observations. The counterintuitive effect of liquid-stiffening of solids is expected whenever droplet radii are smaller than an elastocapillary length, given by the ratio of the surface tension to Young's modulus of the solid matrix.

Robert W. Style; Rostislav Boltyanskiy; Benjamin Allen; Katharine E. Jensen; Henry P. Foote; John S. Wettlaufer; Eric R. Dufresne

2014-07-24T23:59:59.000Z

425

Low Temperature Reduction of Alumina Using Fluorine Containing Ionic Liquids  

SciTech Connect

The major objective of the project is to establish the feasibility of using specific ionic liquids capable of sustaining aluminum electrolysis near room temperature at laboratory and batch recirculation scales. It will explore new technologies for aluminum and other valuable metal extraction and process methods. The new technology will overcome many of the limitations associated with high temperatures processes such as high energy consumption and corrosion attack. Furthermore, ionic liquids are non-toxic and could be recycled after purification, thus minimizing extraction reagent losses and environmental pollutant emissions. Ionic liquids are mixture of inorganic and organic salts which are liquid at room temperature and have wide operational temperature range. During the last several years, they were emerging as novel electrolytes for extracting and refining of aluminum metals and/or alloys, which are otherwise impossible using aqueous media. The superior high temperature characteristics and high solvating capabilities of ionic liquids provide a unique solution to high temperature organic solvent problems associated with device internal pressure build-up, corrosion, and thermal stability. However their applications have not yet been fully implemented due to the insufficient understanding of the electrochemical mechanisms involved in processing of aluminum with ionic liquids. Laboratory aluminum electrodeposition in ionic liquids has been investigated in chloride and bis (trifluoromethylsulfonyl) imide based ionic liquids. The electrowinning process yielded current density in the range of 200-500 A/m2, and current efficiency of about 90%. The results indicated that high purity aluminum (>99.99%) can be obtained as cathodic deposits. Cyclic voltammetry and chronoamperometry studies have shown that initial stages of aluminum electrodeposition in ionic liquid electrolyte at 30°C was found to be quasi-reversible, with the charge transfer coefficient (0.40). Nucleation phenomena involved in aluminum deposition on copper in AlCl3-BMIMCl electrolyte was found to be instantaneous followed by diffusion controlled three-dimensional growth of nuclei. Diffusion coefficient (Do) of the electroactive species Al2Cl7¯ ion was in the range from 6.5 to 3.9×10–7 cm2?s–1 at a temperature of 30°C. Relatively little research efforts have been made toward the fundamental understanding and modeling of the species transport and transformation information involved in ionic liquid mixtures, which eventually could lead to quantification of electrochemical properties. Except that experimental work in this aspect usually is time consuming and expensive, certain characteristics of ionic liquids also made barriers for such analyses. Low vapor pressure and high viscosity make them not suitable for atomic absorption spectroscopic measurement. In addition, aluminum electrodeposition in ionic liquid electrolytes are considered to be governed by multi-component mass, heat and charge transport in laminar and turbulent flows that are often multi-phase due to the gas evolution at the electrodes. The kinetics of the electrochemical reactions is in general complex. Furthermore, the mass transfer boundary layer is about one order of magnitude smaller than the thermal and hydrodynamic boundary layer (Re=10,000). Other phenomena that frequently occur are side reactions and temperature or concentration driven natural convection. As a result of this complexity, quantitative knowledge of the local parameters (current densities, ion concentrations, electrical potential, temperature, etc.) is very difficult to obtain. This situation is a serious obstacle for improving the quality of products, efficiency of manufacturing and energy consumption. The gap between laboratory/batch scale processing with global process control and nanoscale deposit surface and materials specifications needs to be bridged. A breakthrough can only be realized if on each scale the occurring phenomena are understood and quantified. Multiscale numerical modeling nevertheless can help t

Dr. R. G. Reddy

2007-09-01T23:59:59.000Z

426

Arch. Rational Mech. Anal. 142 (1998) 293329. c Springer-Verlag 1998 An Analysis of Phase-Field Alloys  

E-Print Network (OSTI)

are induced due to the change in phase and the change in material diffusion across the interface. Excess the modified Stefan model) in which a material in a spatial region Rd is in one of two phases, e.g., liquidArch. Rational Mech. Anal. 142 (1998) 293­329. c Springer-Verlag 1998 An Analysis of Phase

Ã?aginalp, Gunduz

427

Physical Chemistry of Ionic Liquids Symposium Schedule  

NLE Websites -- All DOE Office Websites (Extended Search)

(Tentative Schedule, locations and times to be determined) (Tentative Schedule, locations and times to be determined) Sunday Morning Structure and Heterogeneity of Ionic Liquids I. James Wishart and Edward Castner Introductory Remarks Andre Pinkert Hydroxyamine ionic liquids and their properties Thomas Strassner TAAILs - Tunable Aryl-Alkyl Ionic Liquids: A new generation of ionic liquids Laura Sprunger Grubbs Thermodynamic Properties of New Generation Ionic Liquids Christopher Hardacre Prediction methods for physical properties of ionic liquids BREAK Patricia Hunt What happens when you functionalise an ionic liquid with a "silicone" side chain? Edward L Quitevis Effect of cation symmetry and nanoscale segregation on the morphology, physical properties, and low-frequency vibrational dynamics of 1,3-dialkylimidazolium cation ionic liquids

428

Nanopatterned anchoring layers for liquid crystals  

E-Print Network (OSTI)

This thesis describes the theory and fabrication of inhomogeneous Liquid Crystal anchoring layers. While chemical anchoring techniques have proved useful for many applications, especially Liquid Crystal Displays, they have ...

Gear, Christopher S. (Christopher Stanwood)

2014-01-01T23:59:59.000Z

429

Application of the PC-SAFT equation of state to modeling of solid-liquid equilibria in systems with organic components forming chemical compounds  

Science Journals Connector (OSTI)

Equilibrium diagrams of liquid and solid phases were calculated by the equation of state, based on the perturbed-chain statistical associating fluid theory (PC-SAFT) for binary and ternary systems constituted by....

I. V. Prikhod’ko; F. Tumakaka; G. Sadowski

2007-04-01T23:59:59.000Z

430

Nanoparticle enhanced ionic liquid heat transfer fluids  

DOE Patents (OSTI)

A heat transfer fluid created from nanoparticles that are dispersed into an ionic liquid is provided. Small volumes of nanoparticles are created from e.g., metals or metal oxides and/or alloys of such materials are dispersed into ionic liquids to create a heat transfer fluid. The nanoparticles can be dispersed directly into the ionic liquid during nanoparticle formation or the nanoparticles can be formed and then, in a subsequent step, dispersed into the ionic liquid using e.g., agitation.

Fox, Elise B.; Visser, Ann E.; Bridges, Nicholas J.; Gray, Joshua R.; Garcia-Diaz, Brenda L.

2014-08-12T23:59:59.000Z

431

Ionic Liquids for Utilization of Geothermal Energy  

Energy.gov (U.S. Department of Energy (DOE))

DOE Geothermal Program Peer Review 2010 - Presentation. Project objective: to develop ionic liquids for two geothermal energy related applications.

432

Liquid Propane Injection Applications | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Liquid propane injection technology meets manufacturingassembly guidelines, maintenancerepair strategy, and regulations, with same functionality, horsepower, and torque as...

433

First measurement of the ionization yield of nuclear recoils in liquid argon  

SciTech Connect

Liquid phase argon has long been used as a target medium for particle detection via scintillation light. Recently there has been considerable interest in direct detection of both hypothetical darkmatter particles and coherent elastic neutrino nucleus scattering. These as-yet unobserved neutral particle interactions are expected to result in a recoiling argon atom O(keV), generally referred to in the literature as a nuclear recoil. This prompts the question of the available electromagnetic signal in a liquid argon detector. In this Letter we report the first measurement of the ionization yield (Qy), detected electrons per unit energy, resulting from nuclear recoils in liquid argon, measured at 6.7 keV. This is also the lowest energy measurement of nuclear recoils in liquid argon.

Joshi, T. [Univ. of California, Berkeley, CA (United States). Dept. of Nuclear Engineering; Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States); Sangiorgio, Samuele [Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States); Bernstein, A. [Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States); Foxe, Michael P. [Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States); Pennsylvania State Univ., University Park, PA (United States). Dept. of Mechanical and Nuclear Engineering; Hagmann, Chris [Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States); Jovanovic, Igor [Pennsylvania State Univ., University Park, PA (United States). Dept. of Mechanical and Nuclear Engineering; Kazkaz, K. [Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States); Mozin, Vladimir V. [Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States); Norman, E. B. [Univ. of California, Berkeley, CA (United States). Dept. of Nuclear Engineering; Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States); Pereverzev, S. V. [Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States); Rebassoo, Finn O. [Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States); Sorensen, Peter F. [Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States)

2014-05-01T23:59:59.000Z

434

Elementary excitations in liquid 4He confined in MCM-41  

Science Journals Connector (OSTI)

We present neutron scattering measurements of the excitations of liquid 4He confined in MCM-41 at wave vectors 0.35 Å-1<~q<~2.15 Å-1. MCM-41 is a uniform porous material consisting of cylindrical pores, here of 32 Å diameter. The location and phase of 4He in the pores was well characterized by pressure isotherms and by exploratory neutron scattering measurements. The first 60% of 4He entering the MCM-41 is tightly bound on the media surface. This 4He supports no excitations in the energy range investigated (0.3 meV <~?<~2.0 meV). The 4He added between 60 and 70% filling is less tightly bound. At 70% filling, 4He in MCM-41 supports an excitation that is interpreted as a ripplon propagating on the liquid surface. This excitation disappears on further filling. The subsequent liquid 4He added supports well defined phonon-roton excitations which at low temperatures T<~1.4 K, have energies and widths that are the same as those in bulk superfluid 4He within precision. There is some indication that the phonon energy for q<~0.5 Å-1 lies above the bulk value. The liquid also supports layers modes for wavevectors in the roton region (1.90 Å-1<~q<~ 2.15 Å-1) as observed in aerogel, Vycor, and Geltech silica. Accurate measurements at higher temperatures were not possible because of the small volume of liquid in the MCM-41 and the present sample cell design.

Francesco Albergamo; Jacques Bossy; Henry R. Glyde; Albert-Jose Dianoux

2003-06-13T23:59:59.000Z

435

Remarks on Liquid Wall Research Mohamed Abdou  

E-Print Network (OSTI)

Wall Research Advances the Science and Energy Goals of Fusion in a Perfect Fit · If we can make liquidRemarks on Liquid Wall Research Mohamed Abdou Professor Mechanical and Aerospace Engineering UCLA Note For recent presentations and papers on liquid wall research by the APEX team see website: http

Abdou, Mohamed

436

Commercialization of coal to liquids technology  

SciTech Connect

After an overview of the coal market, technologies for producing liquids from coal are outlined. Commercialisation of coal-to-liquid fuels, the economics of coal-to-liquids development and the role of the government are discussed. Profiles of 8 key players and the profiles of 14 projects are finally given. 17 figs., 8 tabs.

NONE

2007-07-01T23:59:59.000Z

437

QCD Viscosity to Entropy Density Ratio in the Hadronic Phase  

E-Print Network (OSTI)

Shear viscosity (eta) of QCD in the hadronic phase is computed by the coupled Boltzmann equations of pions and nucleons in low temperatures and low baryon number densities. The eta to entropy density ratio eta/s maps out the nuclear gas-liquid phase transition by forming a valley tracing the phase transition line in the temperature-chemical potential plane. When the phase transition turns into a crossover, the eta/s valley gradually disappears. We suspect the general feature for a first-order phase transition is that eta/s has a discontinuity in the bottom of the eta/s valley. The discontinuity coincides with the phase transition line and ends at the critical point. Beyond the critical point, a smooth eta/s valley is seen. However, the valley could disappear further away from the critical point. The eta/s measurements might provide an alternative to identify the critical points.

Jiunn-Wei Chen; Yen-Han Li; Yen-Fu Liu; Eiji Nakano

2007-03-21T23:59:59.000Z

438

Frostbite Theater - Liquid Nitrogen Experiments - Liquid Nitrogen Show!  

NLE Websites -- All DOE Office Websites (Extended Search)

Insulators! Insulators! Previous Video (Insulators!) Frostbite Theater Main Index Next Video (Superconductors!) Superconductors! Liquid Nitrogen Show! All of your favorite liquid nitrogen experiments all in one place! Flowers! Balloons! Racquetballs! Nothing is safe! Just sit back, relax, and enjoy the show! [ Show Transcript ] Announcer: Frostbite Theater presents... Cold Cuts! No baloney! Joanna and Steve: Just science! Joanna: Hi! I'm Joanna! Steve: And I'm Steve! Joanna: Usually, every couple years, Jefferson Lab hosts an Open House. This is the one time the public and come and tour our accelerator and end stations. Steve: During the 2010 Open House, our cameraman snuck into one of the ongoing cryo shows that are held throughout the day. He missed half of it. So if you want to see the entire thing, check our website to see when the

439

Temperature dependence of the structure of Langmuir films of normal-alkanes on liquid mercury  

E-Print Network (OSTI)

Temperature dependence of the structure of Langmuir films of normal-alkanes on liquid mercury H phase behavior of Langmuir films of n-alkanes CH3(CH2)n 2CH3 , denote Cn on mercury was studied surface normal, alkanes on mercury are always oriented surface parallel and show no long-range in

Ocko, Ben

440

Heat Transfer Measurements for a Horizontal Micro-Tube Using Liquid Crystal Thermography  

E-Print Network (OSTI)

62 TC02-007 Heat Transfer Measurements for a Horizontal Micro-Tube Using Liquid Crystal-tube and 1000m micro-tube. In the single-phase heat transfer experiments, the fully-developed flow heat transfer were also measured using thermocouples (TC). The results showed that the heat transfer coefficient

Ghajar, Afshin J.

Note: This page contains sample records for the topic "non-aqueous phase liquid" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Selective Solid-Liquid Extraction of Lithium Halide Salts Using a Ditopic Macrobicyclic Receptor  

E-Print Network (OSTI)

pairs. The receptor can transport these salts from an aqueous phase through a liquid organic membrane and membrane transport, almost all reported efforts have focused on the transfer of lithium salts from this by binding the salts as contact ion pairs. Receptor 1 can also transport alkali metal halide salts out

Smith, Bradley D.

442

Field-Induced Freezing of a Quantum Spin Liquid on the Kagome Lattice P. Mendels,1  

E-Print Network (OSTI)

a gapless spin-liquid behavior in zero field, we uncover an instability toward a spin-solid phase at sub with dense sets of low energy excitations in all spin sectors [5,6]. A recent state-of-the-art calculation [7 planes which ensure the quasi-two-dimensionality of the magnetic net (Fig. 1). Despite a sizable

Paris-Sud 11, Université de

443

Gas-Liquid Chromatographic Analysis of Long-Chain Fatty Alcohols  

Science Journals Connector (OSTI)

......6 FEBRUARY 1968 of lithium aluminum hydride hydrogenolysis...starting materials for the synthesis of glyceryl ethers...polar liquid phases. Acetate derivatives used by...TMS) and trifluoro- acetate (TFA) derivatives...the methyl esters by lithium aluminum hydride reduction......

Randall Wood

1968-02-01T23:59:59.000Z

444

Quantum Spin Hall Phases  

Science Journals Connector (OSTI)

......even it is called the weak topological in- sulator (WTI). The STI and WTI correspond to the QSH and I phases, respectively...are used to distinguish various phases in the STI or WTI phases, and each phase can be associated with a mod......

Shuichi Murakami

2008-06-01T23:59:59.000Z

445

Bubbles in Insulating Liquids: Stability in an Electric Field  

Science Journals Connector (OSTI)

...July 1964 research-article Bubbles in Insulating Liquids: Stability in an Electric Field C. G...Krasucki It is shown that a bubble of gas or liquid, immersed...of incompressible (liquid) bubbles immersed in an insulating liquid...

1964-01-01T23:59:59.000Z

446

Liquid Propane Injection Technology Conductive to Today's North...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Technology Conductive to Today's North American Specification Liquid Propane Injection Technology Conductive to Today's North American Specification Liquid propane injection...

447

Two-phase flow and transport in the air cathode of proton exchange membrane fuel cells  

SciTech Connect

Two-phase flow and transport of reactants and products in the air cathode of proton exchange membrane (PEM) fuel cells is studied analytically and numerically. Four regimes of water distribution and transport are classified by defining three threshold current densities and a maximum current density. They correspond to first appearance of liquid water at the membrane/cathode interface, extension of the gas-liquid two-phase zone to the cathode/channel interface, saturated moist air exiting the gas channel, and complete consumption of oxygen by the electrochemical reaction. When the cell operates above the first threshold current density, liquid water appears and a two-phase zone forms within the porous cathode. A two-phase, multi-component mixture model in conjunction with a finite-volume-based computational fluid dynamics (CFD) technique is applied to simulate the cathode operation in this regime. The model is able to handle the situation where a single-phase region co-exists with a two-phase zone in the air cathode. For the first time, the polarization curve as well as water and oxygen concentration distributions encompassing both single- and two-phase regimes of the air cathode are presented. Capillary action is found to be the dominant mechanism for water transport inside the two-phase zone. The liquid water saturation within the cathode is predicted to reach 6.3% at 1.4 A/cm{sup 2}.

WANG,Z.H.; WANG,C.Y.; CHEN,KEN S.

2000-03-20T23:59:59.000Z

448

Nanoparticle-induced twist-grain boundary phase Maja Trcek,1  

E-Print Network (OSTI)

Nanoparticle-induced twist-grain boundary phase Maja Trcek,1 George Cordoyiannis,1, 2, Vassilios optical microscopy it is demonstrated that surface- functionalized spherical CdSSe nanoparticles induce a twist-grain boundary phase when dispersed in a chiral liquid crystal. These nanoparticles can

449

Viscosity of liquid Fe at high pressure  

Science Journals Connector (OSTI)

Synchrotron x-ray radiography has been used to measure the viscosity of pure liquid Fe at high pressure and temperature in a large volume press. A probe sphere rising through liquid Fe at high pressure and temperature is imaged, in situ, allowing for the derivation of sample viscosity through a modified form of Stokes’ equation. The effect of pressure on viscosity is fit by the semi empirical framework for transport coefficients in liquid metals, providing experimental verification of constant viscosity at the pressure-dependent melting temperature of liquid Fe where no change in liquid structure occurs.

Michael D. Rutter; Richard A. Secco; Hongjian Liu; Takeyuki Uchida; Mark L. Rivers; Stephen R. Sutton; Yanbin Wang

2002-08-14T23:59:59.000Z

450

TETRAALKYLPHOSPHONIUM POLYOXOMETALATES AS NOVEL IONIC LIQUIDS.  

SciTech Connect

The pairing of a Lindqvist or Keggin polyoxometalate (POM) anion with an appropriate tetraalkylphosphonium cation, [R{sub 3}R{prime}P]{sup +}, has been shown to yield an original family of ionic liquids (POM-ILs), among them salts liquid at or near ambient temperature. The physicochemical properties of several such 'inorganic liquids', in particular their thermal properties, suggests the possible application of these compounds as robust, thermally-stable solvents for liquid-liquid extraction. A preliminary evaluation of the potential of POM-ILs in this application is presented.

DIETZ,M.L.; RICKERT, P.G.; ANTONIO, M.R.; FIRESTONE, M.A.; WISHART, J.F.; SZREDER, T.

2007-11-30T23:59:59.000Z

451

"Phase freezeout" in isentropically expanding matter  

E-Print Network (OSTI)

Features of isentropic expansion of warm dense matter (WDM) created by intense energy fluxes (strong shock compression or instant isochoric heating by laser or heavy ions) are under discussion in situation when ($i$) -- thermodynamic trajectory of such expansion crosses binodal of liquid-gas phase transition, and ($ii$) -- expansion within the two-phase region is going along equilibrium branch (not metastable one) of the two-phase mixture isentrope. It is known in the plane case that because of break in the expansion isentrope at binodal point (in $P-V$ plane) i.e. jump of sound velocity in this point, there appears extended zone ("boiling layer") of uniformity in expanding material with constant thermodynamic and kinematic parameters. It corresponds just to the state on this binodal of boiling liquid. The point is that because of self-similarity of such expansion (in plane case) this boiling layer contains finite and fixed part of whole expanding material. This property makes it possible (at least formally) ...

Iosilevskiy, Igor

2014-01-01T23:59:59.000Z

452

Catalyst for hydrotreating carbonaceous liquids  

DOE Patents (OSTI)

A catalyst for denitrogenating and desulfurating carbonaceous liquid such as solvent refined coal includes catalytic metal oxides impregnated within a porous base of mostly alumina with relatively large pore diameters, surface area and pore volume. The base material includes pore volumes of 0.7-0.85 ml/g, surface areas of 200-350 m.sup.2 /g and pore diameters of 85-200 Angstroms. The catalytic metals impregnated into these base materials include the oxides of Group VI metals, molybdenum and tungsten, and the oxides of Group VIII metals, nickel and cobalt, in various combinations. These catalysts and bases in combination have effectively promoted the removal of chemically combined sulfur and nitrogen within a continuous flowing mixture of carbonaceous liquid and hydrogen gas.

Berg, Lloyd (Bozeman, MT); McCandless, Frank P. (Bozeman, MT); Ramer, Ronald J. (Idaho Falls, ID)

1982-01-01T23:59:59.000Z

453

Alien liquid detector and control  

SciTech Connect

An alien liquid detector employs a monitoring element and an energizing circuit for maintaining the temperature of the monitoring element substantially above ambient temperature. For this purpose an electronic circit controls a flow of heating current to the monitoring element. The presence of an alien liquid is detected by sensing a predetermined change in heating current flow to the monitoring element, e.g., to distinguish between water and oil. In preferred embodiments the monitoring element is a thermistor whose resistance is compared with a reference resistance and heating current through the thermistor is controlled in accordance with the difference. In one embodiment a bridge circuit senses the resistance difference; the difference may be sensed by an operational amplifier arrangement. Features of the invention include positioning the monitoring element at the surface of water, slightly immersed, so that the power required to maintain the thermistor temperature substantially above ambient temperature serves to detect presence of oil pollution at the surface.

Potter, B.M.

1980-09-02T23:59:59.000Z

454

A New Phase in Cellular Communication | Advanced Photon Source  

NLE Websites -- All DOE Office Websites (Extended Search)

Engineering Thin-Film Oxide Interfaces Engineering Thin-Film Oxide Interfaces Novel Materials Become Multifunctional at the Ultimate Quantum Limit Outsmarting Flu Viruses How Lead-Free Solder (Mis)Behaves under Stress Dynamics of Polymer Chains Atop Different Materials Science Highlights Archives: 2013 | 2012 | 2011 | 2010 2009 | 2008 | 2007 | 2006 2005 | 2004 | 2003 | 2002 2001 | 2000 | 1998 | Subscribe to APS Science Highlights rss feed A New Phase in Cellular Communication NOVEMBER 15, 2012 Bookmark and Share Interactions between N-WASP, phospho-Nephrin and Nck produce large polymers (top panel) that phase separate to produce liquid droplets suspended in aqueous solution (bottom panel). In many physical processes, substances undergo phase transitions, where they are transformed from one state (solid, liquid, or gas) to another.

455

Membrane Separations of Liquid Mixtures  

E-Print Network (OSTI)

MEMBRANE SEPARATIONS OF LIQUID MIXTURES Douglas R. Lloyd Separations Research Program Department of Chemical Engineering The University of Texas at Austin Austin, Texas In recent years considerable attention has been given to the need... for reduced energy costs in the chemical processing industry. A major portion of the energy consumed in this industry is associated with the separation and recovery of chemicals. Membrane processes offer energy-efficient, cost effective methods...

Lloyd, D. R.

456

EIA - International Energy Outlook 2008-Liquid Fuels  

Gasoline and Diesel Fuel Update (EIA)

Liquid Fuels Liquid Fuels International Energy Outlook 2008 Chapter 2 - Liquid Fuels World liquids consumption increases from 84 million barrels per day in 2005 to 99 million barrels per day in 2030 in the IEO2008 high price case. In the reference case, which reflects a price path that departs significantly from prices prevailing in the first 8 months of 2008, liquids use rises to 113 million barrels per day in 2030. Figure 26. World Liquids Production in the Reference Case, 1990-2030 (Million Barrels Oil Equivalent per Day). Need help, contact the National Energy Information Center at 202-586-8800. Figure Data Figure 27. World Production of Unconventional Liquid Fuels, 2005-2030 (Million Barrels Oil Equivalent per Day). Need help, contact the National Energy Information Center at 202-586-8800.

457

Generation of non-thermal plasma at atmospheric pressure in hetero-phase media of air with water aerosol  

Science Journals Connector (OSTI)

The results of experimental investigations on non-thermal plasma generation using of high-voltage discharge in hetero-phase media of airflow at atmospheric pressure with liquid aerosol are presented in...B. subti...

Yu. S. Akishev; G. I. Aponin; M. E. Grushin…

2006-10-01T23:59:59.000Z

458

characterization and visualization of two-phase flow properties of gas diffusion layers used in a PEM fuel cell  

E-Print Network (OSTI)

Due to the low-temperature operation of Polymer Electrolyte Membrane fuel cell (PEMFC), liquid water can build up in either flow channels or gas diffusion layers (GDL). Better understanding of the effect of two-phase ...

Gao, Yan

2011-04-26T23:59:59.000Z

459

Two-phase xenon emission detector with electron multiplier and optical readout by multipixel avalanche Geiger photodiodes  

E-Print Network (OSTI)

A successful operation of a new optical readout system (THGEM + WLS + MGPDs (multichannel array of multipixel avalanche Geiger photodiodes) in a two-phase liquid xenon detector was demonstrated.

Akimov, D Yu; Alexandrov, I S; Belov, V A; Bolozdynya, A I; Burenkov, A A; Buzulutskov, A F; Danilov, M V; Efremenko, Yu V; Kirsanov, M A; Kovalenko, A G; Stekhanov, V N

2013-01-01T23:59:59.000Z

460

Formation of amorphous superconducting transition-metal alloys by liquid quenching on hot substrates  

SciTech Connect

An improved cooling rate has been achieved by liquid quenching on a hot substrate, which facilitates the preparation of amorphous and metastable crystalline states of refractory-metal-based alloys. The effectiveness has been proved by the experimental results for Mo-Zr and Nb-Si-Ge alloys. A single amorphous phase was obtained from 40--60 at. % Zr. In the Nb-Si-Ge alloy system, amorphous and metastable A15 phases were obtained in a wide composition range. The superconducting properties and thermal stability of these phases have been studied.

Togano, K.; Kumakura, H.; Tachikawa, K.

1982-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "non-aqueous phase liquid" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Computational simulation of liquid-fuelled HVOF thermal spraying  

Science Journals Connector (OSTI)

Liquid-fuelled high-velocity oxygen–fuel (HVOF) thermal spraying systems are gaining more attentions due to their advantage of producing denser coatings in comparison to their gas-fuelled counterparts. The flow through a HVOF gun is characterized by a complex array of thermodynamic phenomena involving combustion, turbulence and compressible flow. Advanced computational models have been developed to gain insight to the thermochemical processes of thermal spraying, however little work has been reported for the liquid-fuelled systems. This investigation employs a commercial finite volume CFD code to simulate the flow field through the most widely used liquid-fuel HVOF gun, JP5000 (Praxair, US). By combining numerical combustion and discrete phase models the turbulent spray flame is captured and the development of supersonic gas flow is revealed. The flow field is thoroughly examined by adjusting the nozzle throat diameter and combustion chamber size. The influence of fuel droplet size on the flame shame shape and combusting gas flow is also examined.

H. Tabbara; S. Gu

2009-01-01T23:59:59.000Z

462

Structure of liquid and glassy ZnCl2  

Science Journals Connector (OSTI)

The method of isotope substitution in neutron diffraction was used to measure the structure of liquid ZnCl2 at 332(5)?°C and glassy ZnCl2 at 25(1)?°C. The partial structure factors were obtained from the measured diffraction patterns by using the method of singular value decomposition and by using the reverse Monte Carlo procedure. The partial structure factors reproduce the diffraction patterns measured by high-energy x-ray diffraction once a correction for the resolution function of the neutron diffractometer has been made. The results show that the predominant structural motif in both phases is the corner sharing ZnCl4 tetrahedron and that there is a small number of edge-sharing configurations, these being more abundant in the liquid. The tetrahedra organize on an intermediate length scale to give a first sharp diffraction peak in the measured diffraction patterns at a scattering vector kFSDP?1?Å?1 that is most prominent for the Zn-Zn correlations. The results support the notion that the relative fragility of tetrahedral glass forming MX2 liquids is related to the occurrence of edge-sharing units.

Anita Zeidler; Philip S. Salmon; Richard A. Martin; Takeshi Usuki; Philip E. Mason; Gabriel J. Cuello; Shinji Kohara; Henry E. Fischer

2010-09-23T23:59:59.000Z

463

Liquid Exfoliation of Layered Materials  

Science Journals Connector (OSTI)

...Generalizing solubility parameter theory...of multicomponent solubility parameters for...N. , Role of solubility parameters in understanding...Bourlinos A. B. ., Aqueous-phase exfoliation...hexagonal boron nitride nanosheets . Journal...into indium and gallium selenides . Phys...

Valeria Nicolosi; Manish Chhowalla; Mercouri G. Kanatzidis; Michael S. Strano; Jonathan N. Coleman

2013-06-21T23:59:59.000Z

464

Phase Transformations in Binary Colloidal Monolayers  

E-Print Network (OSTI)

Phase transformations can be difficult to characterize at the microscopic level due to the inability to directly observe individual atomic motions. Model colloidal systems, by contrast, permit the direct observation of individual particle dynamics and of collective rearrangements, which allows for real-space characterization of phase transitions. Here, we study a quasi-two-dimensional, binary colloidal alloy that exhibits liquid-solid and solid-solid phase transitions, focusing on the kinetics of a diffusionless transformation between two crystal phases. Experiments are conducted on a monolayer of magnetic and nonmagnetic spheres suspended in a thin layer of ferrofluid and exposed to a tunable magnetic field. A theoretical model of hard spheres with point dipoles at their centers is used to guide the choice of experimental parameters and characterize the underlying materials physics. When the applied field is normal to the fluid layer, a checkerboard crystal forms; when the angle between the field and the normal is sufficiently large, a striped crystal assembles. As the field is slowly tilted away from the normal, we find that the transformation pathway between the two phases depends strongly on crystal orientation, field strength, and degree of confinement of the monolayer. In some cases, the pathway occurs by smooth magnetostrictive shear, while in others it involves the sudden formation of martensitic plates.

Ye Yang; Lin Fu; Catherine Marcoux; Joshua E. S. Socolar; Patrick Charbonneau; Benjamin B. Yellen

2015-02-10T23:59:59.000Z

465

Phase-Transfer Catalysts  

Science Journals Connector (OSTI)

In previous chapters we learned that a phase-transfer catalyst must have two particular chemical functions to be successful, that is, it must rapidly transfer one of the reactant species into the normal phase ...

Charles M. Starks; Charles L. Liotta; Marc E. Halpern

1994-01-01T23:59:59.000Z

466

Heat storage system utilizing phase change materials government rights  

DOE Patents (OSTI)

A thermal energy transport and storage system is provided which includes an evaporator containing a mixture of a first phase change material and a silica powder, and a condenser containing a second phase change material. The silica powder/PCM mixture absorbs heat energy from a source such as a solar collector such that the phase change material forms a vapor which is transported from the evaporator to the condenser, where the second phase change material melts and stores the heat energy, then releases the energy to an environmental space via a heat exchanger. The vapor is condensed to a liquid which is transported back to the evaporator. The system allows the repeated transfer of thermal energy using the heat of vaporization and condensation of the phase change material.

Salyer, Ival O. (Dayton, OH)

2000-09-12T23:59:59.000Z

467

Piecewise Linear Phase Transitions  

E-Print Network (OSTI)

It is shown how simple assumptions lead to piecewise linear behavior, which is observed in certain phase transitions.

Joseph B. Keller

2007-11-26T23:59:59.000Z

468

Multimedia Phase-Spaces  

Science Journals Connector (OSTI)

Dynamic phase-spaces are suggested as a way of designing and implementing interactive multimedia systems. A dynamic phase-space is a space of properties overlayed with dynamics. The space is “decorated” with multimedia resources such ... Keywords: catastrophe theory, dynamics, installation, interactive narrative, museums, phase-space

Peter Bøgh Andersen

1998-05-01T23:59:59.000Z

469

Closed cycle liquid helium refrigerators  

Science Journals Connector (OSTI)

We have developed closed cycle liquid helium refrigerators using a Joule Thomson circuit precooled by commercially available two staged Gifford Mac Mahon cryocoolers. The Joule Thomson counterflow heat exchangers are modular and have been thermo-hydraulically characterized. Fully automatic cool down and operation are achieved by two pneumatically driven by pass and expansion valves. Several apparatus have been built or are under assembly with cooling power ranging from 100 mW up to 5 Watt, for temperature ranging from 2.8 K up to 4.5 K. A trouble free operation with several warm up and cool down cycles has been proven over 7000 hours.

G. Claudet; R. Lagnier; A. Ravex

1992-01-01T23:59:59.000Z

470

Two-phase flow in horizontal wells  

SciTech Connect

Flow in horizontal wells and two-phase flow interaction with the reservoir were investigated experimentally and theoretically. Two-phase flow behavior has been recognized as one of the most important problems in production engineering. The authors designed and constructed a new test facility suitable for acquiring data on the relationship between pressure drop and liquid holdup along the well and fluid influx from the reservoir. For the theoretical work, an initial model was proposed to describe the flow behavior in a horizontal well configuration. The model uses the inflow-performance-relationship (IPR) approach and empirical correlations or mechanistic models for wellbore hydraulics. Although good agreement was found between the model and experimental data, a new IPR apart from the extension of Darcy`s law must be investigated extensively to aid in the proper design of horizontal wells.

Ihara, Masaru [Japan National Oil Corp., Chiba (Japan); Yanai, Koji [Nippon Kokan Corp., Yokohama (Japan); Yanai, Koji

1995-11-01T23:59:59.000Z

471

Study of Liquid Dynamics by Neutron Scattering  

Science Journals Connector (OSTI)

This paper reviews the information about the collective motions of atoms in liquids which can be obtained from neutron scattering experiments with particular attention to the rare gases and liquid metals. The current status of the theoretical interpretation is examined. Coherent neutron scattering from a monatomic liquid gives directly the spectrum of the correlation function for density fluctuations in the system for wavelengths in the range 1–10 Å. The results have a dual interpretation. On the one hand they may be understood in terms of a viscoelastic theory which takes into account the microscopic structure of the liquid; on the other hand fluctuations at these wavelengths may be interpreted in terms of vibrational modes as in an amorphous solid. The paper attempts to reconcile these two points of view. Qualitative differences between liquidargon and the liquid metals are discussed with reference to the connection between the neutron results and the microscopic properties of these liquids.

P. Schofield

1969-01-01T23:59:59.000Z

472

Short- and medium-range order in Zr[subscript 80]Pt[subscript 20] liquids  

SciTech Connect

The atomic structures in equilibrium and supercooled liquids of Zr{sub 80}Pt{sub 20} were determined as a function of temperature by in situ high-energy synchrotron diffraction studies of the levitated liquids (containerless processing) using the beamline electrostatic levitation (BESL) technique. The presence of a pronounced pre-peak at q - 1.7 {angstrom}{sup -1} in the static structure factor indicates medium-range order (MRO) in the liquid. The position and intensity of the pre-peak remain constant with cooling, indicating that the MRO is already present in the liquid above its melting temperature. An analysis of the liquid atomic structures obtained using the Reverse Monte Carlo method utilizing both the structure factor S(q) from x-ray diffraction experiments and the partial pair-correlation functions from ab initio molecular dynamics simulations show that the pre-peak arises from a Pt-Pt correlation that can be identified with icosahedral short-range order around the Pt atoms. The local atomic ordering is dominated by icosahedral-like structures, raising the nucleation barrier between the liquid and these phases, thus assisting glass formation.

Mauro, N.A.; Wessels, V.; Bendert, J.C.; Klein, S.; Gangopadhyay, A.K.; Kramer, M.J.; Hao, S.G.; Rustan, G.E.; Kreyssig, A.; Goldman, A.I.; Kelton, K.F. (WU); (ETH Zurich); (Iowa State); (IMW-Germany)

2011-12-09T23:59:59.000Z

473

Solubility of Carbohydrates in Ionic Liquids  

Science Journals Connector (OSTI)

‡ Laboratório Nacional de Energia e Geologia, I.P., Unit of Bioenergy, Estrada do Paço do Lumiar 22, 1649-038, Lisboa, Portugal ... The aim of this Review is to assess the current state of knowledge regarding the solubility of carbohydrates in ionic liquids but not on modifications of carbohydrates in ionic liquids. ... We herein collect all of the available literature data about the solubility of various carbohydrates in ionic liquids and highlight their interactions with carbohydrates. ...

Ma?gorzata Ewa Zakrzewska; Ewa Bogel-?ukasik; Rafa? Bogel-?ukasik

2010-01-07T23:59:59.000Z

474

Tokamak with liquid metal toroidal field coil  

DOE Patents (OSTI)

Tokamak apparatus includes a pressure vessel for defining a reservoir and confining liquid therein. A toroidal liner disposed within the pressure vessel defines a toroidal space within the liner. Liquid metal fills the reservoir outside said liner. Electric current is passed through the liquid metal over a conductive path linking the toroidal space to produce a toroidal magnetic field within the toroidal space about the major axis thereof. Toroidal plasma is developed within the toroidal space about the major axis thereof.

Ohkawa, Tihiro (La Jolla, CA); Schaffer, Michael J. (San Diego, CA)

1981-01-01T23:59:59.000Z

475

Liquid metal cooled nuclear reactor plant system  

DOE Patents (OSTI)

A liquid metal cooled nuclear reactor having a passive cooling system for removing residual heat resulting for fuel decay during reactor shutdown, or heat produced during a mishap. The reactor system is enhanced with sealing means for excluding external air from contact with the liquid metal coolant leaking from the reactor vessel during an accident. The invention also includes a silo structure which resists attack by leaking liquid metal coolant, and an added unique cooling means.

Hunsbedt, Anstein (Los Gatos, CA); Boardman, Charles E. (Saratoga, CA)

1993-01-01T23:59:59.000Z

476

Gas well operation with liquid production  

SciTech Connect

Prediction of liquid loading in gas wells is discussed in terms of intersecting tubing or system performance curves with IPR curves and by using a more simplified critical velocity relationship. Different methods of liquid removal are discussed including such methods as intermittent lift, plunger lift, use of foam, gas lift, and rod, jet, and electric submersible pumps. Advantages, disadvantages, and techniques for design and application of the methods of liquid removal are discussed.

Lea, J.F.; Tighe, R.E.

1983-02-01T23:59:59.000Z

477

Chaotic vibration of a liquid-filled thin cylindrical shell  

SciTech Connect

Recently, a large number of thin walled cylindrical tanks have been widely used, such as oil-storage tanks, and LMFBR primary components. To assess the safety of these systems against earthquakes, it is of great technical importance to clarify the fluid-coupled vibration characteristics of the systems subjected to certain kinds of dynamic loads. This paper describes an experimental study on the chaos of a partially liquid-filled cylindrical tank under horizontal excitation. The test cylinder with a mean radius of 170 mm was made of polyester film with a nominal thickness of 0.188 mm which was lap-joined along a longitudinal seam and bonded with an aluminum end plate along one edge. Shaking table tests were conducted in order to investigate the dynamic characteristics of the shell response. Several types of limit cycles were observed at lower accelerations, and the instability phenomenon, which jumped at some excitation frequencies, occurred for acceleration amplitudes above a critical value. Finally, at higher excitation accelerations, the shell responses became chaotic. The occurrence of the chaos was recognized by the time history, Poincare map, phase trajectory, power spectrum and a positive Lyapunov exponent calculated from the orbits in the three dimensional phase space. In order to visualize the strange attractor, phase portraits were constructed by embedding the trajectories in the phase space.

Toyoda, Y.; Masuko, Y. [Central Research Inst. of Electric Power Industry, Abiko, Chiba (Japan). Abiko Research Lab.

1996-12-01T23:59:59.000Z

478

Liquid metal Flow Meter - Final Report  

SciTech Connect

Measuring the flow of liquid metal presents serious challenges. Current commercially-available flow meters use ultrasonic, electromagnetic, and other technologies to measure flow, but are inadequate for liquid metal flow measurement because of the high temperatures required by most liquid metals. As a result of the reactivity and high temperatures of most liquid metals, corrosion and leakage become very serious safety concerns. The purpose of this project is to develop a flow meter for Lockheed Martin that measures the flow rate of molten metal in a conduit.

Andersen C, Hoogendoom S, Hudson B, Prince J, Teichert K, Wood J, Chase K

2007-01-30T23:59:59.000Z

479

Exciplex Fluorescence Thermometry of Liquid Fuel  

Science Journals Connector (OSTI)

An experimental program is described that investigates the application of exciplex fluorescence to the internal thermometry of flowing liquid decane in the temperature range 24-91°C....

Stufflebeam, John H

1989-01-01T23:59:59.000Z

480

,"Natural Gas Plant Liquids Proved Reserves"  

U.S. Energy Information Administration (EIA) Indexed Site

,"Worksheet Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","Natural Gas Plant Liquids Proved Reserves",49,"Annual",2012,"6301979" ,"Release...

Note: This page contains sample records for the topic "non-aqueous phase liquid" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

Viscosity of Liquid Sodium and Potassium  

Science Journals Connector (OSTI)

2 November 1936 research-article Viscosity of Liquid Sodium and Potassium Y. S. Chiong The Royal Society is collaborating with JSTOR to digitize, preserve, and extend...

1936-01-01T23:59:59.000Z

482

,"Natural Gas Plant Liquids Proved Reserves"  

U.S. Energy Information Administration (EIA) Indexed Site

,"Worksheet Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","Natural Gas Plant Liquids Proved Reserves",49,"Annual",2013,"6301979" ,"Release...

483

Closed-field capacitive liquid level sensor  

DOE Patents (OSTI)

A liquid level sensor based on a closed field circuit comprises a ring oscillator using a symmetrical array of plate units that creates a displacement current. The displacement current varies as a function of the proximity of a liquid to the plate units. The ring oscillator circuit produces an output signal with a frequency inversely proportional to the presence of a liquid. A continuous liquid level sensing device and a two point sensing device are both proposed sensing arrangements. A second set of plates may be located inside of the probe housing relative to the sensing plate units. The second set of plates prevent any interference between the sensing plate units.

Kronberg, J.W.

1995-01-01T23:59:59.000Z

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