National Library of Energy BETA

Sample records for noble parkway ardmore

  1. Ardmore, Pennsylvania: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    OpenEI by expanding it. Ardmore is a census-designated place in Delaware County and Montgomery County, Pennsylvania.1 References US Census Bureau 2005 Place to 2006 CBSA...

  2. Alternative Fuels Data Center: Blue Ridge Parkway Incorporates Alternative

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Fuels in Its Fleet Blue Ridge Parkway Incorporates Alternative Fuels in Its Fleet to someone by E-mail Share Alternative Fuels Data Center: Blue Ridge Parkway Incorporates Alternative Fuels in Its Fleet on Facebook Tweet about Alternative Fuels Data Center: Blue Ridge Parkway Incorporates Alternative Fuels in Its Fleet on Twitter Bookmark Alternative Fuels Data Center: Blue Ridge Parkway Incorporates Alternative Fuels in Its Fleet on Google Bookmark Alternative Fuels Data Center: Blue Ridge

  3. Foothills Parkway Section 8B Final Environmental Report, Volume 1

    SciTech Connect (OSTI)

    Blasing, T.J.; Cada, G.F.; Carer, M.; Chin, S.M.; Dickerman, J.A.; Etnier, D.A.; Gibson, R.; Harvey, M.; Hatcher, B.; Lietzske, D.; Mann, L.K.; Mulholland, P.J.; Petrich, C.H.; Pounds, L.; Ranney, J.; Reed, R.M.; Ryan, P.F.; Schweitzer, M.; Smith, D.; Thomason, P.; Wade, M.C.

    1999-07-01

    In 1994, Oak Ridge National Laboratory (ORNL) was tasked by the National Park Service (NPS) to prepare an Environmental Report (ER) for Section 8B of the Foothills Parkway in the Great Smoky Mountains National Park (GSMNP). Section 8B represents 27.7 km (14.2 miles) of a total of 115 km (72 miles) of the planned Foothills Parkway and would connect the Cosby community on the east to the incorporated town of Pittman Center to the west.

  4. Noble gas magnetic resonator

    DOE Patents [OSTI]

    Walker, Thad Gilbert; Lancor, Brian Robert; Wyllie, Robert

    2014-04-15

    Precise measurements of a precessional rate of noble gas in a magnetic field is obtained by constraining the time averaged direction of the spins of a stimulating alkali gas to lie in a plane transverse to the magnetic field. In this way, the magnetic field of the alkali gas does not provide a net contribution to the precessional rate of the noble gas.

  5. HV in Noble Liquids

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in Noble Liquids 8 Nov 2013 High Voltage Tests for MicroBooNE Byron Lundberg Fermilab presenting for the Collaboration & Task Force 4 1 Friday, November 8, 13 HV in Noble Liquids MicroBooNE Experiment  A liquid argon time projection chamber (LAr TPC) containing 170 tons of liquid argon, and located on the Booster Neutrino Beamline.  MiniBooNE  MicroBooNE 8,#256#wires;#U,V,Y#planes;#3#mm#spacing# 32#PMTs#for#fast#light#collec?ons# @ L A r T F 2 Friday, November 8, 13 HV in Noble

  6. Nobles Wind Farm | Open Energy Information

    Open Energy Info (EERE)

    Farm Jump to: navigation, search Name Nobles Wind Farm Facility Nobles Sector Wind energy Facility Type Commercial Scale Wind Facility Status In Service Owner Nobles Cooperative...

  7. Noble Bellmont Wind Farm | Open Energy Information

    Open Energy Info (EERE)

    Noble Bellmont Wind Farm Jump to: navigation, search Name Noble Bellmont Wind Farm Facility Noble Bellmont Sector Wind energy Facility Type Commercial Scale Wind Facility Status...

  8. Noble Group | Open Energy Information

    Open Energy Info (EERE)

    Wealth Fund 2 Noble purchased 5.1% of USEC, a US company which enriches uranium for nuclear power reactors, in June 2010 2 References "Noble Group (HK)" 2.0 2.1 "New...

  9. Noble Americas | Open Energy Information

    Open Energy Info (EERE)

    Place: Stamford, Connecticut Zip: 6902 Product: Wholly owned subsidiary of global supply chain manager Noble Group Coordinates: 42.75294, -73.068531 Show Map Loading...

  10. Noble Environmental Power | Open Energy Information

    Open Energy Info (EERE)

    Environmental Power Jump to: navigation, search Name: Noble Environmental Power Place: Essex, Connecticut Zip: 6426 Sector: Wind energy Product: Backed by JP Morgan, Noble is...

  11. Noble REMC- Residential Energy Efficiency Rebate Incentives

    Broader source: Energy.gov [DOE]

    Through Wabash Valley Power Association, POWER MOVES program, Noble REMC offers residential rebates.

  12. USCA Convocation Center 375 Robert M. Bell Parkway, Aiken, SC 29801

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1, 2013 USCA Convocation Center 375 Robert M. Bell Parkway, Aiken, SC 29801  Cash Bar Reception 6:00-6:45 pm  Banquet/Lecture 7:00 pm  Tickets: $50 per person Must be purchased and paid for in advance DEADLINE for reservations: September 30, 2013 Please make checks payable to: CNTA We are a 501 ( c ) 3 non-profit organization Tax ID #: 57-0953103 Contact CNTA: (803) 649-3456 or email, cnta@bellsouth.net Tickets will be mailed to the address we have on record or as instructed. Tickets

  13. EA-284-C NOBLE AMERICAS ENERGY SOLUTIONS LLC | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    C NOBLE AMERICAS ENERGY SOLUTIONS LLC EA-284-C NOBLE AMERICAS ENERGY SOLUTIONS LLC Order authorizing Noble Americas Energy Solutions to export electric energy to Mexico. PDF icon ...

  14. Lower Pennsylvanian reservoirs of Parkway-Empire south field area, Eddy County, New Mexico

    SciTech Connect (OSTI)

    James, A.D.

    1984-01-01

    The Parkway-Empire area is located on the Northwest shelf in central Eddy County, approximately 15 mi (24 km) northeast of Carlsbad, New Mexico. This area produces oil and gas from the lower and middle Morrow sandstones, Atoka sandstones, and Strawn limestones. Oil is also produced from the Queen and Seven Rivers sandstones, and the Grayburg, San Andres, and Wolfcamp dolomites. All of the these zones are productive from stratigraphic traps. The lower Morrow sandstones occur at a depth of about 11,400 ft (3,474 m). In the Parkway area, the middle Morrow sandstones are thought to be a transgressive series of marine beaches and submarine bars which trend toward the northeast, parallel to depositional strike. Stratigraphic traps are created in the lower and middle Morrow sandstones by variations in cementation and depositional patterns. Productive Atoka sandstones occur at a depth of approximately 10,700 ft (3,261 m). Strawn limestones produce from a series of small, low-relief algal banks developed along depositional strike to the northeast. The Strawn limestone is about 300 ft (91 m) thick and occurs between 10,250 and 10,500 ft (3,124 and 3,200 m). Wells in this area have typical ultimate recoveries of between 1.0 and 3.0 bcf of gas. The combination of stacked reservoirs and good production makes this area of the Morrow trend especially attractive.

  15. Nobles Wind Farm II | Open Energy Information

    Open Energy Info (EERE)

    Farm II Jump to: navigation, search Name Nobles Wind Farm II Facility Nobles Wind Farm II Sector Wind energy Facility Type Commercial Scale Wind Facility Status In Service Owner...

  16. Foothills Parkway Section 8B Final Environmental Report, Volume 5, Appendices J-M

    SciTech Connect (OSTI)

    Blasing, T.J.; Cada, G.F.; Carer, M.; Chin, S.M.; Dickerman, J.A.; Etnier, D.A.; Gibson, R.; Harvey, M.; Hatcher, B.; Lietzske, D.; Mann, L.K.; Mulholland, P.J.; Petrich, C.H.; Pounds, L.; Ranney, J.; Reed, R.M.; Ryan, P.F.; Schweitzer, M.; Smith, D.; Thomason, P.; Wade, M.C.

    1999-07-01

    In 1994, Oak Ridge National Laboratory (ORNL) was tasked by the National Park Service (NPS) to prepare an Environmental Report (ER) for Section 8B of the Foothills Parkway in the Great Smoky Mountains National Park (GSMNP). Section 8B represents 27.7 km (14.2 miles) of a total of 115 km (72 miles) of the planned Foothills Parkway and would connect the Cosby community on the east to the incorporated town of Pittman Center to the west. The major deliverables for the project are listed. From August 1995 through October 1996, NPS, GSMNP, and ORNL staff interacted with Federal Highway Administration staff to develop a conceptual design plan for Section 8B with the intent of protecting critical resources identified during the ER process to the extent possible. In addition, ORNL arranged for bioengineering experts to discuss techniques that might be employed on Section 8B with NPS, GSMNP, and ORNL staff during September 1996. For the purposes of this ER, there are two basic alternatives under consideration: (1) a build alternative and (2) a no-build alternative. Within the build alternative are a number of options including constructing Section 8B with no interchanges, constructing Section 8B with an interchange at SR 416 or U.S. 321, constructing Section 8B with a spur road on Webb Mountain, and considering operation of Section 8B both before and after the operation of Section 8C. The no-build alternative is considered the no-action alternative and is not to construct Section 8B. This volume of the ER consists of Appendices J through M, which describe potential impacts regarding traffic, noise, and aesthetics. The results of the traffic studies described in these appendices resulted in the following conclusions: Unacceptable levels of service will occur on numerous roads within and outside of the park increasingly in the Mure based upon current and future regional growth. However, the results of the traffic assessment indicated that there would be no significant or

  17. Foothills Parkway Section 8B Final Environmental Report, Volume 3, Appendix D

    SciTech Connect (OSTI)

    Blasing, T.J.; Cada, G.F.; Carer, M.; Chin, S.M.; Dickerman, J.A.; Etnier, D.A.; Gibson, R.; Harvey, M.; Hatcher, B.; Lietzske, D.; Mann, L.K.; Mulholland, P.J.; Petrich, C.H.; Pounds, L.; Ranney, J.; Reed, R.M.; Ryan, P.F.; Schweitzer, M.; Smith, D.; Thomason, P.; Wade, M.C.

    1999-07-01

    In 1994, Oak Ridge National Laboratory (ORNL) was tasked by the National Park Service (NPS) to prepare an Environmental Report (ER) for Section 8B of the Foothills Parkway in the Great Smoky Mountains National Park (GSMNP). Section 8B represents 27.7 km (14.2 miles) of a total of 115 km (72 miles) of the planned Foothills Parkway and would connect the Cosby community on the east to the incorporated town of Pittman Center to the west. The major deliverables for the project are listed. From August 1995 through October 1996, NPS, GSMNP, and ORNL staff interacted with Federal Highway Administration staff to develop a conceptual design plan for Section 8B with the intent of protecting critical resources identified during the ER process to the extent possible. In addition, ORNL arranged for bioengineering experts to discuss techniques that might be employed on Section 8B with NPS, GSMNP, and ORNL staff during September 1996. For the purposes of this ER, there are two basic alternatives under consideration: (1) a build alternative and (2) a no-build alternative. Within the build alternative are a number of options including constructing Section 8B with no interchanges, constructing Section 8B with an interchange at SR416 or U.S. 321, constructing Section 8B with a spur road on Webb Mountain, and considering operation of Section 8B both before and after the operation of Section 8C. The no-build alternative is considered the no-action alternative and is not to construct Section 8B. This volume of the ER inventories the fishes and benthic macroinvertebrates inhabiting the aquatic ecosystems potentially affected by the proposed construction of Section 8B. Stream biological surveys were completed at 31 stream sites during the Fall of 1994. The sampling strategy for both invertebrates and fish was to survey the different taxa from all available habitats. For benthic invertebrates, a standardized qualitative manual collection technique was employed for all 31 stations. For fish

  18. Foothills Parkway Section 8B Final Environmental Report, Volume 4, Appendices E-I

    SciTech Connect (OSTI)

    Blasing, T.J.; Cada, G.F.; Carer, M.; Chin, S.M.; Dickerman, J.A.; Etnier, D.A.; Gibson, R.; Harvey, M.; Hatcher, B.; Lietzske, D.; Mann, L.K.; Mulholland, P.J.; Petrich, C.H.; Pounds, L.; Ranney, J.; Reed, R.M.; Ryan, P.F.; Schweitzer, M.; Smith, D.; Thomason, P.; Wade, M.C.

    1999-07-01

    In 1994, Oak Ridge National Laboratory (ORNL) was tasked by the National Park Service (NPS) to prepare an Environmental Report (ER) for Section 8B of the Foothills Parkway in the Great Smoky Mountains National Park (GSMNP). Section 8B represents 27.7 km (14.2 miles) of a total of 115 km (72 miles) of the planned Foothills Parkway and would connect the Cosby community on the east to the incorporated town of Pittman Center to the west. The major deliverables for the project are listed. From August 1995 through October 1996, NPS, GSMNP, and ORNL staff interacted with Federal Highway Administration staff to develop a conceptual design plan for Section 8B with the intent of protecting critical, resources identified during the ER process to the extent possible. In addition, ORNL arranged for bioengineering experts to discuss techniques that might be employed on Section 8B with NPS, GSMNP, and ORNL staff during September 1996. For the purposes of this ER, there are two basic alternatives under consideration: (1) a build alternative and (2) a no-build alternative. Within the build alternative are a number of options including constructing Section 8B with no interchanges, constructing Section 8B with an interchange at SR 416 or U.S. 321, constructing Section 8B with a spur road on Webb Mountain, and considering operation of Section 8B both before and after the operation of Section 8C. The no-build alternative is considered the no-action alternative and is not to construct Section 8B. This volume of the ER consists of Appendices E through I (all ecological survey reports), which are summarized individually in the sections that follow. The following conclusions result from the completion of these surveys and the ER impact analysis: (1) Forest clearing should be limited as much as possible; (2) Disturbed areas should be replanted with native trees; (3) Drainages should be bridged rather than leveled with cut and fill; (4) For areas of steep slopes and potential erosion

  19. Foothills Parkway Section 8B Final Environmental Report, Volume 6, Appendix N

    SciTech Connect (OSTI)

    Blasing, T.J.; Cada, G.F.; Carer, M.; Chin, S.M.; Dickerman, J.A.; Etnier, D.A.; Gibson, R.; Harvey, M.; Hatcher, B.; Lietzske, D.; Mann, L.K.; Mulholland, P.J.; Petrich, C.H.; Pounds, L.; Ranney, J.; Reed, R.M.; Ryan, P.F.; Schweitzer, M.; Smith, D.; Thomason, P.; Wade, M.C.

    1999-07-01

    In 1994, Oak Ridge National Laboratory (ORNL) was tasked by the National Park Service (NPS) to prepare an Environmental Report (ER) for Section 8B of the Foothills Parkway in the Great Smoky Mountains National Park (GSMNP). Section 8B represents 27.7 km (14.2 miles) of a total of 115 km (72 miles) of the planned Foothills Parkway and would connect the Cosby community on the east to the incorporated town of Pittman Center to the west. The major deliverables for the project are listed. From August 1995 through October 1996, NPS, GSMNP, and ORNL staff interacted with Federal Highway Administration staff to develop a conceptual design plan for Section 8B with the intent of protecting critical resources identified during the ER process to the extent possible. In addition, ORNL arranged for bioengineering experts to discuss techniques that might be employed on Section 8B with NPS, GSMNP, and ORNL staff during September 1996. For the purposes of this ER, there are two basic alternatives under consideration: (1) a build alternative and (2) a no-build alternative. Within the build alternative are a number of options including constructing Section 8B with no interchanges, constructing Section 8B with an interchange at SR 416 or U.S. 321, constructing Section 8B with a spur road on Webb Mountain, and considering operation of Section 8B both before and after the operation of Section 8C. The no-build alternative is considered the no-action alternative and is not to construct Section 8B. This volume of the ER documents the results of the architectural, historical, and cultural resources assessment for the entire Section 8B ROW that was completed in May 1995 to document the architectural, historical, and cultural resources located within the project area. The assessment included evaluation of the potential for cultural (i.e., rural historic) landscapes in the area of the ROW. The assessment showed that one National Register-listed property is located 0.3 mile south of the ROW

  20. EA-364-A Noble Americas Gas & Power Corporation | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    -A Noble Americas Gas & Power Corporation EA-364-A Noble Americas Gas & Power Corporation Order authorizing NAG&P to export electric energy to Canada. PDF icon EA-364-A Noble ...

  1. EA-363-A Noble Americas MX.pdf

    Office of Environmental Management (EM)

    3 Noble Americas Gas & Power Corporation EA-363 Noble Americas Gas & Power Corporation Order authorizong Noble Americas Gas & Power Corporation to export electric energy to Mexico EA-363 Noble Americas Gas & Power Corporation (2.58 MB) More Documents & Publications Record of Categorical Exclusion (CS) Determination, Office of Electricity Delivery and Energy Reliability (OE): EA-363 Noble Americas Gas & Power Corporation EA-364 Noble Americas Gas & Power Corporation

  2. Noble Gas Adsorption in Metal-Organic Frameworks Containing Open...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Noble Gas Adsorption in Metal-Organic Frameworks Containing Open Metal Sites Previous Next ... accessibility in this topology enhance the framework interaction with the noble gases. ...

  3. EA-363 Noble Americas Gas & Power Corporation | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Gas & Power Corporation Order authorizong Noble Americas Gas & Power Corporation to export electric energy to Mexico PDF icon EA-363 Noble Americas Gas & Power Corporation...

  4. Noble Gas Geochemistry In Thermal Springs | Open Energy Information

    Open Energy Info (EERE)

    Noble Gas Geochemistry In Thermal Springs Abstract The composition of noble gases in both gas and water samples collected from Horseshoe Spring, Yellowstone National Park, was...

  5. Platinum-coated non-noble metal-noble metal core-shell electrocatalysts

    DOE Patents [OSTI]

    Adzic, Radoslav; Zhang, Junliang; Mo, Yibo; Vukmirovic, Miomir

    2015-04-14

    Core-shell particles encapsulated by a thin film of a catalytically active metal are described. The particles are preferably nanoparticles comprising a non-noble core with a noble metal shell which preferably do not include Pt. The non-noble metal-noble metal core-shell nanoparticles are encapsulated by a catalytically active metal which is preferably Pt. The core-shell nanoparticles are preferably formed by prolonged elevated-temperature annealing of nanoparticle alloys in an inert environment. This causes the noble metal component to surface segregate and form an atomically thin shell. The Pt overlayer is formed by a process involving the underpotential deposition of a monolayer of a non-noble metal followed by immersion in a solution comprising a Pt salt. A thin Pt layer forms via the galvanic displacement of non-noble surface atoms by more noble Pt atoms in the salt. The overall process is a robust and cost-efficient method for forming Pt-coated non-noble metal-noble metal core-shell nanoparticles.

  6. Incorporation of noble metals into aerogels

    DOE Patents [OSTI]

    Hair, L.M.; Sanner, R.D.; Coronado, P.R.

    1998-12-22

    Aerogels or xerogels containing atomically dispersed noble metals for applications such as environmental remediation are disclosed. New noble metal precursors, such as Pt--Si or Pd(Si--P){sub 2}, have been created to bridge the incompatibility between noble metals and oxygen, followed by their incorporation into the aerogel or xerogel through sol-gel chemistry and processing. Applications include oxidation of hydrocarbons and reduction of nitrogen oxide species, complete oxidation of volatile organic carbon species, oxidative membranes for photocatalysis and partial oxidation for synthetic applications.

  7. Incorporation of noble metals into aerogels

    DOE Patents [OSTI]

    Hair, Lucy M.; Sanner, Robert D.; Coronado, Paul R.

    1998-01-01

    Aerogels or xerogels containing atomically dispersed noble metals for applications such environmental remediation. New noble metal precursors, such as Pt--Si or Pd(Si--P).sub.2, have been created to bridge the incompatibility between noble metals and oxygen, followed by their incorporation into the aerogel or xerogel through sol-gel chemistry and processing. Applications include oxidation of hydrocarbons and reduction of nitrogen oxide species, complete oxidation of volatile organic carbon species, oxidative membranes for photocatalysis and partial oxidation for synthetic applications.

  8. Light Collection in Liquid Noble Gases

    SciTech Connect (OSTI)

    McKinsey, Dan [Yale University

    2013-05-29

    Liquid noble gases are increasingly used as active detector materials in particle and nuclear physics. Applications include calorimeters and neutrino oscillation experiments as well as searches for neutrinoless double beta decay, direct dark matter, muon electron conversion, and the neutron electric dipole moment. One of the great advantages of liquid noble gases is their copious production of ultraviolet scintillation light, which contains information about event energy and particle type. I will review the scintillation properties of the various liquid noble gases and the means used to collect their scintillation light, including recent advances in photomultiplier technology and wavelength shifters.

  9. Nobles Cooperative Electric (Iowa) | Open Energy Information

    Open Energy Info (EERE)

    (Iowa) Jump to: navigation, search Name: Nobles Cooperative Electric Place: Iowa Phone Number: 1-507-372-7331 Website: www.noblesce.coop Outage Hotline: 1-507-372-7331 Outage Map:...

  10. Noble REMC- Buisness Energy Efficiency Rebate Incentives

    Broader source: Energy.gov [DOE]

    Noble REMC, with the Wabash Vally Power Association offers business rebate incentives through its POWER MOVES program.  Incentives are available on a first-come, first-served basis. View the...

  11. Photosensitive dopants for liquid noble gases

    DOE Patents [OSTI]

    Anderson, David F.

    1988-01-01

    In an ionization type detector for high energy radiation wherein the energy of incident radiation is absorbed through the ionization of a liquid noble gas and resulting free charge is collected to form a signal indicative of the energy of the incident radiation, an improvement comprising doping the liquid noble gas with photosensitive molecules to convert scintillation light due to recombination of ions, to additional free charge.

  12. EA-363-A Noble Americas Gas & Power Corporation | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    EA-363-A Noble Americas Gas & Power Corporation Order authorizing NAG&P to export electric energy to Mexico. PDF icon EA-363-A Noble Americas MX.pdf More Documents & Publications ...

  13. Noble County R E M C | Open Energy Information

    Open Energy Info (EERE)

    Noble County R E M C Jump to: navigation, search Name: Noble County R E M C Place: Indiana Phone Number: 800.933.7362 or 260-636-2113 Website: www.nobleremc.com Twitter:...

  14. CONTROL ROD ALLOY CONTAINING NOBLE METAL ADDITIONS

    DOE Patents [OSTI]

    Anderson, W.K.; Ray, W.E.

    1960-05-01

    Silver-base alloys suitable for use in the fabrication of control rods for neutronic reactors are given. The alloy consists of from 0.5 wt.% to about 1.5 wt.% of a noble metal of platinum, ruthenium, rhodium, osmium, or palladium, up to 10 wt.% of cadmium, from 2 to 20 wt.% indium, the balance being silver.

  15. EA-284-C Noble Americas.pdf

    Office of Environmental Management (EM)

    4-A Sempra Energy Solutions EA-284-A Sempra Energy Solutions Order authorizing Sempra Energy Solutions to export electric energy to Mexico. EA-284-A Sempra Energy Solutions (2.32 MB) More Documents & Publications EA-284-A Sempra Energy Solutions: Temporary Extension EA-406 Sempra Generation, LLC EA-284-C NOBLE AMERICAS ENERGY SOLUTIONS LLC

  16. Noble Americas Energy Solutions LLC (Connecticut) | Open Energy...

    Open Energy Info (EERE)

    LLC (Connecticut) Jump to: navigation, search Name: Noble Americas Energy Solutions LLC Place: Connecticut Phone Number: 1 877273-6772 Website: www.noblesolutions.com Outage...

  17. Datang Jilin Wind Power Stockholding Co Ltd Formerly Jilin Noble...

    Open Energy Info (EERE)

    Wind Power Stockholding Co Ltd Formerly Jilin Noble Wind Power Stockholding Co Ltd Jump to: navigation, search Name: Datang Jilin Wind Power Stockholding Co Ltd(Formerly Jilin...

  18. Test Results For Physical Separation Of Tritium From Noble Gases...

    Office of Environmental Management (EM)

    Test Results For Physical Separation Of Tritium From Noble Gases And It's Implications For Sensitivity And Accuracy In Air And Stack Monitoring Test Results For Physical Separation ...

  19. Noble County, Oklahoma: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    County, Oklahoma Billings, Oklahoma Marland, Oklahoma Morrison, Oklahoma Perry, Oklahoma Red Rock, Oklahoma Retrieved from "http:en.openei.orgwindex.php?titleNobleCounty,Okl...

  20. Inert electrode containing metal oxides, copper and noble metal

    DOE Patents [OSTI]

    Ray, Siba P.; Woods, Robert W.; Dawless, Robert K.; Hosler, Robert B.

    2001-01-01

    A cermet composite material is made by treating at an elevated temperature a mixture comprising a compound of iron and a compound of at least one other metal, together with an alloy or mixture of copper and a noble metal. The alloy or mixture preferably comprises particles having an interior portion containing more copper than noble metal and an exterior portion containing more noble metal than copper. The noble metal is preferably silver. The cermet composite material preferably includes alloy phase portions and a ceramic phase portion. At least part of the ceramic phase portion preferably has a spinel structure.

  1. Inert electrode containing metal oxides, copper and noble metal

    DOE Patents [OSTI]

    Ray, Siba P.; Woods, Robert W.; Dawless, Robert K.; Hosler, Robert B.

    2000-01-01

    A cermet composite material is made by treating at an elevated temperature a mixture comprising a compound of iron and a compound of at least one other metal, together with an alloy or mixture of copper and a noble metal. The alloy or mixture preferably comprises particles having an interior portion containing more copper than noble metal and an exterior portion containing more noble metal than copper. The noble metal is preferably silver. The cermet composite material preferably includes alloy phase portions and a ceramic phase portion. At least part of the ceramic phase portion preferably has a spinel structure.

  2. Noble Americas Energy Solutions LLC (District of Columbia) |...

    Open Energy Info (EERE)

    District of Columbia) Jump to: navigation, search Name: Noble Americas Energy Solutions LLC Place: District of Columbia References: EIA Form EIA-861 Final Data File for 2010 -...

  3. Noble Americas Energy Solutions LLC (New Jersey) | Open Energy...

    Open Energy Info (EERE)

    Jersey) Jump to: navigation, search Name: Noble Americas Energy Solutions LLC Place: New Jersey Phone Number: +1 877273-6772 Website: www.noblesolutions.com Outage Map:...

  4. Noble Americas Energy Solutions LLC (New York) | Open Energy...

    Open Energy Info (EERE)

    York) Jump to: navigation, search Name: Noble Americas Energy Solutions LLC Place: New York Phone Number: 1 877273-6772 Website: www.noblesolutions.com Outage Hotline: 1...

  5. Noble Americas Energy Solutions LLC (Ohio) | Open Energy Information

    Open Energy Info (EERE)

    Ohio) Jump to: navigation, search Name: Noble Americas Energy Solutions LLC Place: Ohio Website: www.noblesolutions.com Outage Hotline: 888896-8629 References: EIA Form EIA-861...

  6. Noble Americas Energy Solutions LLC (Pennsylvania) | Open Energy...

    Open Energy Info (EERE)

    Pennsylvania) Jump to: navigation, search Name: Noble Americas Energy Solutions LLC Place: Pennsylvania Phone Number: 1 888-896-8640 Website: www.noblesolutions.com Outage...

  7. Noble Americas Energy Solutions LLC (Illinois) | Open Energy...

    Open Energy Info (EERE)

    Illinois) Jump to: navigation, search Name: Noble Americas Energy Solutions LLC Place: Illinois Phone Number: 1 877-273-6772 Website: noblesolutions.com Outage Hotline: 1...

  8. Noble Americas Energy Solutions LLC (Maryland) | Open Energy...

    Open Energy Info (EERE)

    Maryland) Jump to: navigation, search Name: Noble Americas Energy Solutions LLC Place: Maryland Phone Number: 1 877273-6772 Website: www.noblesolutions.com Outage Hotline: 1 877...

  9. Noble Americas Energy Solutions LLC (Massachusetts) | Open Energy...

    Open Energy Info (EERE)

    Massachusetts) Jump to: navigation, search Name: Noble Americas Energy Solutions LLC Place: Massachusetts Phone Number: 1 877-273-6772 Website: noblesolutions.com Outage Hotline:...

  10. Noble Americas Energy Solutions LLC (Oregon) | Open Energy Information

    Open Energy Info (EERE)

    Oregon) Jump to: navigation, search Name: Noble Americas Energy Solutions LLC Place: Oregon Phone Number: 1 877-273-6772 Website: www.noblesolutions.com Outage Hotline: 1...

  11. EA-364 Noble Americas Gas & Power Corporation | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    4 Noble Americas Gas & Power Corporation EA-364 Noble Americas Gas & Power Corporation Order authorizong Noble Americas Gas & Power Corporation to export electric energy to Canada EA-364 Noble Americas Gas & Power Corporation (3.36 MB) More Documents & Publications Record of Categorical Exclusion (CS) Determination, Office of Electricity Delivery and Energy Reliability (OE): OE Docket EA-364 Noble Americas Gas & Power Corporation EA-363 Noble Americas Gas & Power

  12. Noble Americas Energy Solutions LLC (Maine) | Open Energy Information

    Open Energy Info (EERE)

    Maine) Jump to: navigation, search Name: Noble Americas Energy Solutions LLC Place: Maine Phone Number: 1 877-273-6772 Website: noblesolutions.com Outage Hotline: 1 888-896-8629...

  13. Nobles County, Minnesota: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Hide Map This article is a stub. You can help OpenEI by expanding it. Nobles County is a county in Minnesota. Its FIPS County Code is 105. It is classified as...

  14. Noble Americas Energy Solutions LLC (Texas) | Open Energy Information

    Open Energy Info (EERE)

    Noble Americas Energy Solutions LLC Place: Texas Website: www.noblesolutions.comindex.h Outage Hotline: 1 877273-6772 References: EIA Form EIA-861 Final Data File for 2010 -...

  15. Noble Americas Energy Solutions LLC (Delaware) | Open Energy...

    Open Energy Info (EERE)

    Delaware) Jump to: navigation, search Name: Noble Americas Energy Solutions LLC Place: Delaware Phone Number: 1 877273-6772 or 1 888896-8629 Website: www.noblesolutions.com...

  16. Noble Americas Energy Solutions LLC (Rhode Island) | Open Energy...

    Open Energy Info (EERE)

    Rhode Island) Jump to: navigation, search Name: Noble Americas Energy Solutions LLC Place: Rhode Island Phone Number: 1 877-273-6772 Website: noblesolutions.com Outage Hotline: 1...

  17. Non-Noble Metal Water Electrolysis Catalysts - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Non-Noble Metal Water Electrolysis Catalysts Brookhaven National Laboratory Contact BNL About This Technology Publications: PDF Document Publication Hydrogen-Evolution Catalysts Based on Non-Noble Metal Nickel Molybdenum Nitride Nanosheets (1,161 KB) a) TEM image of the stacked MoN nanosheets on carbon supports. The read and white arrows mark the nanosheets that lay flat and stand vertically, respectively. b) A HRTEM image with the crystal structure overlaid looking down along the

  18. Underground Sources of Radioactive Noble Gas

    SciTech Connect (OSTI)

    Hayes, James C.; Bowyer, Ted W.; Cordova, Elsa A.; Kirkham, Randy R.; Misner, Alex C.; Olsen, Khris B.; Woods, Vincent T.; Emer, Dudley

    2013-05-01

    It is well known that radon is present in relatively high concentrations below the surface of the Earth due to natural decay of uranium and thorium. However, less information is available on the background levels of other isotopes such as 133Xe and 131mXe produced via spontaneous fission of either manmade or naturally occurring elements. The background concentrations of radioxenon in the subsurface are important to understand because these isotopes potentially can be used to confirm violations of the Comprehensive Nuclear-Test-Ban Treaty (CTBT) during an On-Site Inspection (OSI). Recently, Pacific Northwest National Laboratory (PNNL) measured radioxenon concentrations from the subsurface at the Nevada Nuclear Security Site (NNSS—formerly known as the Nevada Test Site) to determine whether xenon isotope background levels could be detected from spontaneous fission of naturally occurring uranium or legacy 240Pu as a result of historic nuclear testing. In this paper, we discuss the results of those measurements and review the sources of xenon background that must be taken into account during OSI noble gas measurements.

  19. Noble gas atmospheric monitoring at reprocessing facilities

    SciTech Connect (OSTI)

    Nakhleh, C.W.; Perry, R.T. Jr.; Poths, J.; Stanbro, W.D.; Wilson, W.B.; Fearey, B.L.

    1997-05-01

    The discovery in Iraq after the Gulf War of the existence of a large clandestine nuclear-weapon program has led to an across-the-board international effort, dubbed Programme 93+2, to improve the effectiveness and efficiency of International Atomic Energy Agency (IAEA) safeguards. One particularly significant potential change is the introduction of environmental monitoring (EM) techniques as an adjunct to traditional safeguards methods. Monitoring of stable noble gas (Kr, Xe) isotopic abundances at reprocessing plant stacks appears to be able to yield information on the burnup and type of the fuel being processed. To estimate the size of these signals, model calculations of the production of stable Kr, Xe nuclides in reactor fuel and the subsequent dilution of these nuclides in the plant stack are carried out for two case studies: reprocessing of PWR fuel with a burnup of 35 GWd/tU, and reprocessing of CAND fuel with a burnup of 1 GWd/tU. For each case, a maximum-likelihood analysis is used to determine the fuel burnup and type from the isotopic data.

  20. Method and apparatus for measuring purity of noble gases

    DOE Patents [OSTI]

    Austin, Robert

    2008-04-01

    A device for detecting impurities in a noble gas includes a detection chamber and a source of pulsed ultraviolet light. The pulse of the ultraviolet light is transferred into the detection chamber and onto a photocathode, thereby emitting a cloud of free electrons into the noble gas within the detection chamber. The cloud of electrons is attracted to the opposite end of the detection chamber by a high positive voltage potential at that end and focused onto a sensing anode. If there are impurities in the noble gas, some or all of the electrons within the cloud will bond with the impurity molecules and not reach the sensing anode. Therefore, measuring a lower signal at the sensing anode indicates a higher level of impurities while sensing a higher signal indicates fewer impurities. Impurities in the range of one part per billion can be measured by this device.

  1. Isotopic mass-dependence of noble gas diffusion coefficients inwater

    SciTech Connect (OSTI)

    Bourg, I.C.; Sposito, G.

    2007-06-25

    Noble gas isotopes are used extensively as tracers inhydrologic and paleoclimatic studies. These applications requireknowledge of the isotopic mass (m) dependence of noble gas diffusioncoefficients in water (D), which has not been measured but is estimatedusing experimental D-values for the major isotopes along with an untestedrelationship from kinetic theory, D prop m-0.5. We applied moleculardynamics methods to determine the mass dependence of D for four noblegases at 298 K, finding that D prop m-beta with beta<0.2, whichrefutes the kinetic theory model underlying all currentapplications.

  2. Method for low temperature preparation of a noble metal alloy

    DOE Patents [OSTI]

    Even, Jr., William R. (Livermore, CA)

    2002-01-01

    A method for producing fine, essentially contamination free, noble metal alloys is disclosed. The alloys comprise particles in a size range of 5 to 500 nm. The method comprises 1. A method for preparing a noble metal alloy at low temperature, the method comprising the steps of forming solution of organometallic compounds by dissolving the compounds into a quantity of a compatible solvent medium capable of solvating the organometallic, mixing a portion of each solution to provide a desired molarity ratio of ions in the mixed solution, adding a support material, rapidly quenching droplets of the mixed solution to initiate a solute-solvent phase separation as the solvent freezes, removing said liquid cryogen, collecting and freezing drying the frozen droplets to produce a dry powder, and finally reducing the powder to a metal by flowing dry hydrogen over the powder while warming the powder to a temperature of about 150.degree. C.

  3. Nuclear magnetic resonance imaging with hyper-polarized noble gases

    SciTech Connect (OSTI)

    Schmidt, D.M.; George, J.S.; Penttila, S.I.; Caprihan, A.

    1997-10-01

    This is the final report of a six-month, Laboratory Directed Research and Development (LDRD) project at Los Alamos National Laboratory (LANL). The nuclei of noble gases can be hyper polarized through a laser-driven spin exchange to a degree many orders of magnitude larger than that attainable by thermal polarization without requiring a strong magnetic field. The increased polarization from the laser pumping enables a good nuclear magnetic resonance (NMR) signal from a gas. The main goal of this project was to demonstrate diffusion-weighted imaging of such hyper-polarized noble gas with magnetic resonance imaging (MRI). Possible applications include characterizing porosity of materials and dynamically imaging pressure distributions in biological or acoustical systems.

  4. New Way to Probe Noble Metal Nanoparticles | The Ames Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    New Way to Probe Noble Metal Nanoparticles For the first time researchers have found a way to study highly-dispersed metal nanoparticles and their reactions using dynamic nuclear polarization (DNP) surface-enhanced nuclear magnetic resonance spectroscopy (SENS). Nuclear magnetic resonance (NMR) spectroscopy is a researcher's equivalent to a physician's MRI, only in this case the patient is not a person but a material. Now researchers have demonstrated new DNP-based measurements that extend

  5. Fluid clathrate system for continuous removal of heavy noble gases from mixtures of lighter gases

    DOE Patents [OSTI]

    Gross, K.C.; Markun, F.; Zawadzki, M.T.

    1998-04-28

    An apparatus and method are disclosed for separation of heavy noble gas in a gas volume. An apparatus and method have been devised which includes a reservoir containing an oil exhibiting a clathrate effect for heavy noble gases with a reservoir input port and the reservoir is designed to enable the input gas volume to bubble through the oil with the heavy noble gas being absorbed by the oil exhibiting a clathrate effect. The gas having reduced amounts of heavy noble gas is output from the oil reservoir, and the oil having absorbed heavy noble gas can be treated by mechanical agitation and/or heating to desorb the heavy noble gas for analysis and/or containment and allow recycling of the oil to the reservoir. 6 figs.

  6. Fluid clathrate system for continuous removal of heavy noble gases from mixtures of lighter gases

    DOE Patents [OSTI]

    Gross, Kenneth C.; Markun, Francis; Zawadzki, Mary T.

    1998-01-01

    An apparatus and method for separation of heavy noble gas in a gas volume. An apparatus and method have been devised which includes a reservoir containing an oil exhibiting a clathrate effect for heavy noble gases with a reservoir input port and the reservoir is designed to enable the input gas volume to bubble through the oil with the heavy noble gas being absorbed by the oil exhibiting a clathrate effect. The gas having reduced amounts of heavy noble gas is output from the oil reservoir, and the oil having absorbed heavy noble gas can be treated by mechanical agitation and/or heating to desorb the heavy noble gas for analysis and/or containment and allow recycling of the oil to the reservoir.

  7. Noble Metals and Spinel Settling in High Level Waste Glass Melters

    SciTech Connect (OSTI)

    Sundaram, S. K.; Perez, Joseph M.

    2000-09-30

    In the continuing effort to support the Defense Waste Processing Facility (DWPF), the noble metals issue is addressed. There is an additional concern about the amount of noble metals expected to be present in the future batches that will be considered for vitrification in the DWPF. Several laboratory, as well as melter-scale, studies have been completed by various organizations (mainly PNNL, SRTC, and WVDP in the USA). This letter report statuses the noble metals issue and focuses at the settling of noble metals in melters.

  8. Inert anode containing base metal and noble metal useful for the electrolytic production of aluminum

    DOE Patents [OSTI]

    Ray, Siba P.; Liu, Xinghua

    2000-01-01

    An inert anode for production of metals such as aluminum is disclosed. The inert anode comprises a base metal selected from Cu and Ag, and at least one noble metal selected from Ag, Pd, Pt, Au, Rh, Ru, Ir and Os. The inert anode may optionally be formed of sintered particles having interior portions containing more base metal than noble metal and exterior portions containing more noble metal than base metal. In a preferred embodiment, the base metal comprises Cu, and the noble metal comprises Ag, Pd or a combination thereof.

  9. Application to Export Electric Energy OE Docket No. EA-363-A Noble Americas

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Gas & Power Corporation | Department of Energy Corporation Application to Export Electric Energy OE Docket No. EA-363-A Noble Americas Gas & Power Corporation Application from NAG&P to export electric energy to Mexico. EA-363-A Noble Americas G&P (MX).pdf (499.71 KB) More Documents & Publications EA-363-A Noble Americas Gas & Power Corporation Application to Export Electric Energy OE Docket No. EA-363-A Noble Americas Gas & Power Corporation: Federal Register

  10. Application to Export Electric Energy OE Docket No. EA-364-A Noble Americas

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Gas & Power Corporation | Department of Energy Corporation Application to Export Electric Energy OE Docket No. EA-364-A Noble Americas Gas & Power Corporation Application from NAG&P to export electric energy to Canada. EA-364-A Noble Americas G&P (CN).pdf (521.88 KB) More Documents & Publications EA-364-A Noble Americas Gas & Power Corporation Application to Export Electric Energy OE Docket No. EA-364-A Noble Americas Gas & Power Corporation: Federal Register

  11. Measuring the Noble Metal and Iodine Composition of Extracted Noble Metal Phase from Spent Nuclear Fuel Using Instrumental Neutron Activation Analysis

    SciTech Connect (OSTI)

    Palomares, R. I.; Dayman, Kenneth J.; Landsberger, Sheldon; Biegalski, Steven R.; Soderquist, Chuck Z.; Casella, Amanda J.; Brady Raap, Michaele C.; Schwantes, Jon M.

    2015-04-01

    Mass quantities of noble metal and iodine nuclides in the metallic noble metal phase extracted from spent fuel are measured using instrumental neutron activation analysis (NAA). Nuclide presence is predicted using fission yield analysis, and mass quantification is derived from standard gamma spectroscopy and radionuclide decay analysis. The nuclide compositions of noble metal phase derived from two dissolution methods, UO2 fuel dissolved in nitric acid and UO2 fuel dissolved in ammonium-carbonate and hydrogen-peroxide solution, are compared. Lastly, the implications of the rapid analytic speed of instrumental NAA are discussed in relation to potential nuclear forensics applications.

  12. Noble gases and cosmogenic radionuclides in the Eltanin Pacific meteorite

    SciTech Connect (OSTI)

    Bogard, D D; Garrison, D H; Caffee, M W; Kyte, F; Nishiizumi, K

    2000-01-14

    A 1.5 cm long, 1.2 g specimen of the Eltanin meteorite was found at 10.97 m depth in Polarstern piston core PS2704-1. The early studies indicated that the small fragments of the Eltanin meteorite was debris from a km-sized asteroid which impacted into the deep-ocean basin. In this study, the authors measured {sup 39}Ar-{sup 40}Ar age, noble gases, and cosmogenic radionuclides in splits of specimen as a part of consortium studies of Eltanin meteorite. They concluded that the specimen was about 3 m deep from the asteroid surface. The exposure age of the Eltanin asteroid was about 20 Myr.

  13. DEVELOPMENT OF A NON-NOBLE METAL HYDROGEN PURIFICATION SYSTEM

    SciTech Connect (OSTI)

    Korinko, P; Kyle Brinkman, K; Thad Adams, T; George Rawls, G

    2008-11-25

    Development of advanced hydrogen separation membranes in support of hydrogen production processes such as coal gasification and as front end gas purifiers for fuel cell based system is paramount to the successful implementation of a national hydrogen economy. Current generation metallic hydrogen separation membranes are based on Pd-alloys. Although the technology has proven successful, at issue is the high cost of palladium. Evaluation of non-noble metal based dense metallic separation membranes is currently receiving national and international attention. The focus of the reported work was to develop a scaled reactor with a VNi-Ti alloy membrane to replace a production Pd-alloy tube-type purification/diffuser system.

  14. DWPF Hydrogen Generation Study-Form of Noble Metal SRAT Testing

    SciTech Connect (OSTI)

    Bannochie, C

    2005-09-01

    The Defense Waste Processing Facility, DWPF, has requested that the Savannah River National Laboratory, SRNL, investigate the factors that contribute to hydrogen generation to determine if current conservatism in setting the DWPF processing window can be reduced. A phased program has been undertaken to increase understanding of the factors that influence hydrogen generation in the DWPF Chemical Process Cell, CPC. The hydrogen generation in the CPC is primarily due to noble metal catalyzed decomposition of formic acid with a minor contribution from radiolytic processes. Noble metals have historically been added as trim chemicals to process simulations. The present study investigated the potential conservatism that might be present from adding the catalytic species as trim chemicals to the final sludge simulant versus co-precipitating the noble metals into the insoluble sludge solids matrix. Two sludge simulants were obtained, one with co-precipitated noble metals and one without noble metals. Co-precipitated noble metals were expected to better match real waste behavior than using trimmed noble metals during CPC simulations. Portions of both sludge simulants were held at 97 C for about eight hours to qualitatively simulate the effects of long term storage on particle morphology and speciation. The two original and two heat-treated sludge simulants were then used as feeds to Sludge Receipt and Adjustment Tank, SRAT, process simulations. Testing was done at relatively high acid stoichiometries, {approx}175%, and without mercury in order to ensure significant hydrogen generation. Hydrogen generation rates were monitored during processing to assess the impact of the form of noble metals. The following observations were made on the data: (1) Co-precipitated noble metal simulant processed similarly to trimmed noble metal simulant in most respects, such as nitrite to nitrate conversion, formate destruction, and pH, but differently with respect to hydrogen generation: (A

  15. Appraisal of transport and deformation in shale reservoirs using natural noble gas tracers

    SciTech Connect (OSTI)

    Heath, Jason E.; Kuhlman, Kristopher L.; Robinson, David G.; Bauer, Stephen J.; Gardner, William Payton

    2015-09-01

    This report presents efforts to develop the use of in situ naturally-occurring noble gas tracers to evaluate transport mechanisms and deformation in shale hydrocarbon reservoirs. Noble gases are promising as shale reservoir diagnostic tools due to their sensitivity of transport to: shale pore structure; phase partitioning between groundwater, liquid, and gaseous hydrocarbons; and deformation from hydraulic fracturing. Approximately 1.5-year time-series of wellhead fluid samples were collected from two hydraulically-fractured wells. The noble gas compositions and isotopes suggest a strong signature of atmospheric contribution to the noble gases that mix with deep, old reservoir fluids. Complex mixing and transport of fracturing fluid and reservoir fluids occurs during production. Real-time laboratory measurements were performed on triaxially-deforming shale samples to link deformation behavior, transport, and gas tracer signatures. Finally, we present improved methods for production forecasts that borrow statistical strength from production data of nearby wells to reduce uncertainty in the forecasts.

  16. Methane activation using noble gases in a dielectric barrier discharge reactor

    SciTech Connect (OSTI)

    Jo, Sungkwon; Hoon Lee, Dae; Seok Kang, Woo; Song, Young-Hoon

    2013-08-15

    The conversion of methane is measured in a planar-type dielectric barrier discharge reactor using three different noble gasesHe, Ne, and Aras additives. The empirical results obtained clearly indicate that methane activation is considerably affected by thy type of noble gas used. Through 0-D calculations, the discharge parameters inside the reactor, i.e., electron temperature and electron density, are estimated using experiment results. A comparison of the discharge characteristics and experimental results shows that the electron temperature is an important factor in achieving high methane activation and the mixture with Ar gas shows the highest methane conversion. These results are constructed using the mechanisms of energy and charge transfer from excited and ionized noble gas atoms to methane molecules, considering the number density of active atoms of noble gases. Finally, electron temperatures obtained for gas mixtures having different reactant compositions and concentrations are analyzed to estimate methane activation.

  17. Saving the Fuel Cell Dream: Making Non Noble Metal Electrocatalysts a Reality?

    Broader source: Energy.gov [DOE]

    Presentation about non noble metal electrocatalysts, presented by Sanjeev Mukerjee, Northeastern University, at the kick-off meeting of the U.S. Department of Energy Fuel Cell Technologies Program's Catalysis Working Group, held May 14, 2012, in Arlington, Virginia.

  18. Fate of Noble Metals during the Pyroprocessing of Spent Nuclear Fuel

    SciTech Connect (OSTI)

    B.R. Westphal; D. Vaden; S.X. Li; G.L. Fredrickson; R.D. Mariani

    2009-09-01

    During the pyroprocessing of spent nuclear fuel by electrochemical techniques, fission products are separated as the fuel is oxidized at the anode and refined uranium is deposited at the cathode. Those fission products that are oxidized into the molten salt electrolyte are considered active metals while those that do not react are considered noble metals. The primary noble metals encountered during pyroprocessing are molybdenum, zirconium, ruthenium, rhodium, palladium, and technetium. Pyroprocessing of spent fuel to date has involved two distinctly different electrorefiner designs, in particular the anode to cathode configuration. For one electrorefiner, the anode and cathode collector are horizontally displaced such that uranium is transported across the electrolyte medium. As expected, the noble metal removal from the uranium during refining is very high, typically in excess of 99%. For the other electrorefiner, the anode and cathode collector are vertically collocated to maximize uranium throughput. This arrangement results in significantly less noble metals removal from the uranium during refining, typically no better than 20%. In addition to electrorefiner design, operating parameters can also influence the retention of noble metals, albeit at the cost of uranium recovery. Experiments performed to date have shown that as much as 100% of the noble metals can be retained by the cladding hulls while affecting the uranium recovery by only 6%. However, it is likely that commercial pyroprocessing of spent fuel will require the uranium recovery to be much closer to 100%. The above mentioned design and operational issues will likely be driven by the effects of noble metal contamination on fuel fabrication and performance. These effects will be presented in terms of thermal properties (expansion, conductivity, and fusion) and radioactivity considerations. Ultimately, the incorporation of minor amounts of noble metals from pyroprocessing into fast reactor metallic fuel

  19. Recovery of Noble Metals and Technetium from Nuclear Waste

    SciTech Connect (OSTI)

    Moon, J.K.; Han, Y.J.; Lee, E.H.; Jung, C.H.; Lee, B.C.

    2006-07-01

    An adsorptive separation of Pd, Rh and Tc was tested by using simulated chemical solutions. Pd(NO{sub 3}){sub 2} and Rh(NO{sub 3}){sub 3} were used for the noble metal sources, and Re 203 after dissolving it in 0.5 M nitric acid was used for the technetium substitute, respectively. A felt type ACF (activated carbon fiber) after being pretreated with 1 M NaOH, and an EIR (extractant impregnated resin) which was prepared by impregnating Aliquat 336 onto Amberlite XAD-4 resin were evaluated on their adsorption equilibrium and kinetic performances. As the results, the ACF showed a high selectivity for the palladium ions over the rhodium and rhenium ions. On the other hand, the EIR was shown to be effective for separation of rhenium from the palladium-free two component system of rhenium and rhodium. Column tests were also performed to confirm the separation efficiency of palladium and rhenium using a jacketed glass column (diam. 11 x L 150). The ACF bed showed the complete separation of palladium from rhenium and rhodium. The breakthrough volume, when 1% of breakthrough is considered, was about 140 BV for palladium, while only a small amount of an adsorption of rhenium and rhodium were found in the column. Then the EIR column was applied to separate rhenium from rhodium and showed successful separation performance with about 122 BV of breakthrough volume. The palladium and rhenium with high purity were recovered effectively by eluting the beds with nitric acid. (authors)

  20. DISRUPTION MITIGATION WITH HIGH-PRESSURE NOBLE GAS INJECTION

    SciTech Connect (OSTI)

    WHYTE, DG; JERNIGAN, TC; HUMPHREYS, DA; HYATT, AW; LASNIER, CJ; PARKS, PB; EVANS, TE; TAYLOR, PL; KELLMAN, AG; GRAY, DS; HOLLMANN, EM

    2002-10-01

    OAK A271 DISRUPTION MITIGATION WITH HIGH-PRESSURE NOBLE GAS INJECTION. High-pressure gas jets of neon and argon are used to mitigate the three principal damaging effects of tokamak disruptions: thermal loading of the divertor surfaces, vessel stress from poloidal halo currents and the buildup and loss of relativistic electrons to the wall. The gas jet penetrates as a neutral species through to the central plasma at its sonic velocity. The injected gas atoms increase up to 500 times the total electron inventory in the plasma volume, resulting in a relatively benign radiative dissipation of >95% of the plasma stored energy. The rapid cooling and the slow movement of the plasma to the wall reduce poloidal halo currents during the current decay. The thermally collapsed plasma is very cold ({approx} 1-2 eV) and the impurity charge distribution can include > 50% fraction neutral species. If a sufficient quantity of gas is injected, the neutrals inhibit runaway electrons. A physical model of radiative cooling is developed and validated against DIII-D experiments. The model shows that gas jet mitigation, including runaway suppression, extrapolates favorably to burning plasmas where disruption damage will be more severe. Initial results of real-time disruption detection triggering gas jet injection for mitigation are shown.

  1. EXTERNAL PHOTOEVAPORATION OF THE SOLAR NEBULA: JUPITER's NOBLE GAS ENRICHMENTS

    SciTech Connect (OSTI)

    Monga, Nikhil; Desch, Steven

    2015-01-01

    We present a model explaining the elemental enrichments in Jupiter's atmosphere, particularly the noble gases Ar, Kr, and Xe. While He, Ne, and O are depleted, seven other elements show similar enrichments (∼3 times solar, relative to H). Being volatile, Ar is difficult to fractionate from H{sub 2}. We argue that external photoevaporation by far-ultraviolet (FUV) radiation from nearby massive stars removed H{sub 2}, He, and Ne from the solar nebula, but Ar and other species were retained because photoevaporation occurred at large heliocentric distances where temperatures were cold enough (≲ 30 K) to trap them in amorphous water ice. As the solar nebula lost H, it became relatively and uniformly enriched in other species. Our model improves on the similar model of Guillot and Hueso. We recognize that cold temperatures alone do not trap volatiles; continuous water vapor production is also necessary. We demonstrate that FUV fluxes that photoevaporated the disk generated sufficient water vapor in regions ≲ 30 K to trap gas-phase species in amorphous water ice in solar proportions. We find more efficient chemical fractionation in the outer disk: whereas the model of Guillot and Hueso predicts a factor of three enrichment when only <2% of the disk mass remains, we find the same enrichments when 30% of the disk mass remains. Finally, we predict the presence of ∼0.1 M {sub ⊕} of water vapor in the outer solar nebula and protoplanetary disks in H II regions.

  2. Environmental effects on noble-gas hydrides: HXeBr, HXeCCH, and HXeH in noble-gas and molecular matrices

    SciTech Connect (OSTI)

    Tsuge, Masashi E-mail: leonid.khriachtchev@helsinki.fi; Lignell, Antti; Rsnen, Markku; Khriachtchev, Leonid E-mail: leonid.khriachtchev@helsinki.fi

    2013-11-28

    Noble-gas hydrides HNgY (Ng is a noble-gas atom and Y is an electronegative group) are sensitive probes of local environment due to their relatively weak bonding and large dipole moments. We experimentally studied HXeBr in Ar, Kr, and N{sub 2} matrices, HXeCCH in Ne and N{sub 2} matrices, and HXeH in an N{sub 2} matrix. These are the first observations of noble-gas hydrides in an N{sub 2} matrix. An N{sub 2} matrix strongly increases the HXe stretching frequency of HXeBr and HXeCCH with respect to a Ne matrix, which is presumably due to a strong interaction between the HNgY dipole moment and quadrupole moments of the surrounding lattice N{sub 2} molecules. The spectral shift of HXeBr in an N{sub 2} matrix is similar to that in a CO{sub 2} matrix, which is a rather unexpected result because the quadrupole moment of CO{sub 2} is about three times as large as that of N{sub 2}. The HXe stretching frequencies of HXeBr and HXeCCH in noble-gas matrices show a trend of ?(Ne) < ?(Xe) < ?(Kr) < ?(Ar), which is a non-monotonous function of the dielectric constants of the noble-gas solids. The MP2(full) calculations of HXeBr and HXeCCH with the polarizable continuum model as well as the CCSD(T) calculations of the HXeBrNg and HXeCCHNg (Ng = Ne, Ar, Kr, and Xe) complexes cannot fully explain the experimental observations. It is concluded that more sophisticated computational models should be used to describe these experimental findings.

  3. First-principles study of noble gas impurities and defects in UO{sub 2}

    SciTech Connect (OSTI)

    Thompson, Alexander E.; Wolverton, C.

    2011-10-01

    We performed a series of density functional theory + U (DFT + U) calculations to explore the energetics of various defects in UO{sub 2}, i.e., noble gases (He, Ne, Ar, Kr, Xe), Schottky defects, and the interaction between these defects. We found the following: (1) collinear antiferromagnetic UO{sub 2} has an energy-lowering distortion of the oxygen sublattice from ideal fluorite positions; (2) DFT + U qualitatively affects the formation volume of Schottky defect clusters in UO{sub 2} (without U the formation volume is negative, but including U the formation volume is positive); (3) the configuration of the Schottky defect cluster is dictated by a competition between electrostatic and surface energy effects; (4) the incorporation energy of inserting noble gas atoms into an interstitial site has a strong dependence on the volume of the noble gas atom, corresponding to the strain it causes in the interstitial site, from He (0.98 eV) to Xe (9.73 eV); (5) the energetics of each of the noble gas atoms incorporated in Schottky defects show strong favorable binding, due to strain relief associated with moving the noble gas atom from the highly strained interstitial position into the vacant space of the Schottky defect; and (6) for argon, krypton, and xenon, the binding energy of a noble gas impurity with the Schottky defect is larger than the formation energy of a Schottky defect, thereby making the formation of Schottky defects thermodynamically favorable in the presence of these large impurities.

  4. Method and apparatus for noble gas atom detection with isotopic selectivity

    DOE Patents [OSTI]

    Hurst, G. Samuel; Payne, Marvin G.; Chen, Chung-Hsuan; Parks, James E.

    1984-01-01

    Apparatus and methods of operation are described for determining, with isotopic selectivity, the number of noble gas atoms in a sample. The analysis is conducted within an evacuated chamber which can be isolated by a valve from a vacuum pumping system capable of producing a pressure of 10.sup.-8 Torr. Provision is made to pass pulses of laser beams through the chamber, these pulses having wavelengths appropriate for the resonance ionization of atoms of the noble gas under analysis. A mass filter within the chamber selects ions of a specific isotope of the noble gas, and means are provided to accelerate these selected ions sufficiently for implantation into a target. Specific types of targets are discussed. An electron measuring device produces a signal relatable to the number of ions implanted into the target and thus to the number of atoms of the selected isotope of the noble gas removed from the gas sample. The measurement can be continued until a substantial fraction, or all, of the atoms in the sample have been counted. Furthermore, additional embodiments of the apparatus are described for bunching the atoms of a noble gas for more rapid analysis, and for changing the target for repetitive cycling of the gas in the chamber. The number of repetitions of the cyclic steps depend upon the concentration of the isotope of interest, the separative efficiency of the mass filter, etc. The cycles are continued until a desired selectivity is achieved. Also described are components and a method of operation for a pre-enrichment operation for use when an introduction of a total sample would elevate the pressure within the chamber to levels in excess of those for operation of the mass filter, specifically a quadrupole mass filter. Specific examples of three noble gas isotope analyses are described.

  5. Application to Export Electric Energy OE Docket No. EA-363-A Noble Americas

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Gas & Power Corporation: Federal Register Notice, Volume 80, No. 42 - March 4, 2015 | Department of Energy Corporation: Federal Register Notice, Volume 80, No. 42 - March 4, 2015 Application to Export Electric Energy OE Docket No. EA-363-A Noble Americas Gas & Power Corporation: Federal Register Notice, Volume 80, No. 42 - March 4, 2015 Application from NAG&P to export electric energy to Mexico. Federal Register Notice. EA-363-A Noble Americas (MX).pdf (250.1 KB) More Documents

  6. Application to Export Electric Energy OE Docket No. EA-364-A Noble Americas

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Gas & Power Corporation: Federal Register Notice, Volume 80, No. 42 - March 4, 2015 | Department of Energy Corporation: Federal Register Notice, Volume 80, No. 42 - March 4, 2015 Application to Export Electric Energy OE Docket No. EA-364-A Noble Americas Gas & Power Corporation: Federal Register Notice, Volume 80, No. 42 - March 4, 2015 Application from NAG&P to export electric energy to Canada. Federal Register Notice. EA-364-A Noble Americas (CN).pdf (245.09 KB) More Documents

  7. Solid polymer electrolyte composite membrane comprising a porous support and a solid polymer electrolyte including a dispersed reduced noble metal or noble metal oxide

    SciTech Connect (OSTI)

    Liu, Han; Mittelsteadt, Cortney K; Norman, Timothy J; Griffith, Arthur E; LaConti, Anthony B

    2015-02-24

    A solid polymer electrolyte composite membrane and method of manufacturing the same. According to one embodiment, the composite membrane comprises a thin, rigid, dimensionally-stable, non-electrically-conducting support, the support having a plurality of cylindrical, straight-through pores extending perpendicularly between opposing top and bottom surfaces of the support. The pores are unevenly distributed, with some or no pores located along the periphery and more pores located centrally. The pores are completely filled with a solid polymer electrolyte, the solid polymer electrolyte including a dispersed reduced noble metal or noble metal oxide. The solid polymer electrolyte may also be deposited over the top and/or bottom surfaces of the support.

  8. NOBLE METAL CHEMISTRY AND HYDROGEN GENERATION DURING SIMULATED DWPF MELTER FEED PREPARATION

    SciTech Connect (OSTI)

    Koopman, D

    2008-06-25

    Simulations of the Defense Waste Processing Facility (DWPF) Chemical Processing Cell vessels were performed with the primary purpose of producing melter feeds for the beaded frit program plus obtaining samples of simulated slurries containing high concentrations of noble metals for off-site analytical studies for the hydrogen program. Eight pairs of 22-L simulations were performed of the Sludge Receipt and Adjustment Tank (SRAT) and Slurry Mix Evaporator (SME) cycles. These sixteen simulations did not contain mercury. Six pairs were trimmed with a single noble metal (Ag, Pd, Rh, or Ru). One pair had all four noble metals, and one pair had no noble metals. One supporting 4-L simulation was completed with Ru and Hg. Several other 4-L supporting tests with mercury have not yet been performed. This report covers the calculations performed on SRNL analytical and process data related to the noble metals and hydrogen generation. It was originally envisioned as a supporting document for the off-site analytical studies. Significant new findings were made, and many previous hypotheses and findings were given additional support as summarized below. The timing of hydrogen generation events was reproduced very well within each of the eight pairs of runs, e.g. the onset of hydrogen, peak in hydrogen, etc. occurred at nearly identical times. Peak generation rates and total SRAT masses of CO{sub 2} and oxides of nitrogen were reproduced well. Comparable measures for hydrogen were reproduced with more variability, but still reasonably well. The extent of the reproducibility of the results validates the conclusions that were drawn from the data.

  9. Electrochemical synthesis of elongated noble metal nanoparticles, such as nanowires and nanorods, on high-surface area carbon supports

    DOE Patents [OSTI]

    Adzic, Radoslav; Blyznakov, Stoyan; Vukmirovic, Miomir

    2015-08-04

    Elongated noble-metal nanoparticles and methods for their manufacture are disclosed. The method involves the formation of a plurality of elongated noble-metal nanoparticles by electrochemical deposition of the noble metal on a high surface area carbon support, such as carbon nanoparticles. Prior to electrochemical deposition, the carbon support may be functionalized by oxidation, thus making the manufacturing process simple and cost-effective. The generated elongated nanoparticles are covalently bound to the carbon support and can be used directly in electrocatalysis. The process provides elongated noble-metal nanoparticles with high catalytic activities and improved durability in combination with high catalyst utilization since the nanoparticles are deposited and covalently bound to the carbon support in their final position and will not change in forming an electrode assembly.

  10. Nano-structured noble metal catalysts based on hexametallate architecture for the reforming of hydrocarbon fuels

    DOE Patents [OSTI]

    Gardner, Todd H.

    2015-09-15

    Nano-structured noble metal catalysts based on hexametallate lattices, of a spinel block type, and which are resistant to carbon deposition and metal sulfide formation are provided. The catalysts are designed for the reforming of hydrocarbon fuels to synthesis gas. The hexametallate lattices are doped with noble metals (Au, Pt, Rh, Ru) which are atomically dispersed as isolated sites throughout the lattice and take the place of hexametallate metal ions such as Cr, Ga, In, and/or Nb. Mirror cations in the crystal lattice are selected from alkali metals, alkaline earth metals, and the lanthanide metals, so as to reduce the acidity of the catalyst crystal lattice and enhance the desorption of carbon deposit forming moieties such as aromatics. The catalysts can be used at temperatures as high as 1000.degree. C. and pressures up to 30 atmospheres. A method for producing these catalysts and applications of their use also is provided.

  11. Highly concentrated nebular noble gases in porous nanocarbon separates from the Saratov (L4) meteorite

    SciTech Connect (OSTI)

    Amari, Sachiko; Matsuda, Jun-ichi; Stroud, Rhonda M.; Chisholm, Matthew F.

    2013-11-20

    The majority of heavy noble gases (Ar, Kr, and Xe) in primitive meteorites are stored in a poorly understood phase called Q. Although Q is thought to be carbonaceous, the full identity of the phase has remained elusive for almost four decades. In order to better characterize phase Q and, in turn, the early solar nebula, we separated carbon-rich fractions from the Saratov (L4) meteorite. We chose this meteorite because Q is most resistant in thermal alteration among carbonaceous noble gas carriers in meteorites and we hoped that, in this highly metamorphosed meteorite, Q would be present but not diamond: these two phases are very difficult to separate from each other. One of the fractions, AJ, has the highest {sup 132}Xe concentration of 2.1 10{sup 6} cm{sup 3} STP g{sup 1}, exceeding any Q-rich fractions that have yet been analyzed. Transmission electron microscopy studies of the fraction AJ and a less Q-rich fraction AI indicate that they both are primarily porous carbon that consists of domains with short-range graphene orders, with variable packing in three dimensions, but no long-range graphitic order. The relative abundance of Xe and C atoms (6:10{sup 9}) in the separates indicates that individual noble gas atoms are associated with only a minor component of the porous carbon, possibly one or more specific arrangements of the nanoparticulate graphene.

  12. Golden Field Office 15013 Denver West Parkway

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Project will not significantly affect the quality of the human and natural environment. ... for research and educational opportunities with energy production as an ancillary benefit. ...

  13. Golden Field Office 15013 Denver West Parkway

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    U.S. Department of Interior, Bureau of Ocean Energy Management (BOEM) off the coast of ... any of the Proposed Project buoys or deployment vessels during the installation, ...

  14. Record of Categorical Exclusion (CS) Determination, Office of Electricity Delivery and Energy Reliability (OE): EA-363 Noble Americas Gas & Power Corporation

    Broader source: Energy.gov [DOE]

    Record of Categorical Exclusion (CS) Determination, Office of Electricity Delivery and Energy Reliability (OE):  Noble Americas Gas & Power Corporation to export electric energy to Mexico

  15. Record of Categorical Exclusion (CS) Determination, Office of Electricity Delivery and Energy Reliability (OE): OE Docket EA-364 Noble Americas Gas & Power Corporation

    Broader source: Energy.gov [DOE]

    Record of Categorical Exclusion (CS) Determination, Office of Electricity Delivery and Energy Reliability (OE):  Application from Noble Americas Gas & Power Corporation to export electric...

  16. Apparatus for preparing a solution of a hyperpolarized noble gas for NMR and MRI analysis

    DOE Patents [OSTI]

    Pines, Alexander; Budinger, Thomas; Navon, Gil; Song, Yi-Qiao; Appelt, Stephan; Bifone, Angelo; Taylor, Rebecca; Goodson, Boyd; Seydoux, Roberto; Room, Toomas; Pietrass, Tanja

    2008-06-10

    The present invention relates generally to nuclear magnetic resonance (NMR) techniques for both spectroscopy and imaging. More particularly, the present invention relates to methods in which hyperpolarized noble gases (e.g., Xe and He) are used to enhance and improve NMR and MRI. Additionally, the hyperpolarized gas solutions of the invention are useful both in vitro and in vivo to study the dynamics or structure of a system. When used with biological systems, either in vivo or in vitro, it is within the scope of the invention to target the hyperpolarized gas and deliver it to specific regions within the system.

  17. Enhancement of NMR and MRI in the presence of hyperpolarized noble gases

    DOE Patents [OSTI]

    Pines, Alexander; Budinger, Thomas; Navon, Gil; Song, Yi-Qiao; Appelt, Stephan; Bifone, Angelo; Taylor, Rebecca; Goodson, Boyd; Seydoux, Roberto; Room, Toomas; Pietrass, Tanja

    2004-11-16

    The present invention relates generally to nuclear magnetic resonance (NMR) techniques for both spectroscopy and imaging. More particularly, the present invention relates to methods in which hyperpolarized noble gases (e.g., Xe and He) are used to enhance and improve NMR and MRI. Additionally, the hyperpolarized gas solutions of the invention are useful both in vitro and in vivo to study the dynamics or structure of a system. When used with biological systems, either in vivo or in vitro, it is within the scope of the invention to target the hyperpolarized gas and deliver it to specific regions within the system.

  18. Method for localized deposition of noble metal catalysts with control of morphology

    DOE Patents [OSTI]

    Ricco, Antonio J.; Manginell, Ronald P.; Huber, Robert J.

    1998-01-01

    A combustible gas sensor that uses a resistively heated, noble metal-coated, micromachined polycrystalline Si filament to calorimetrically detect the presence and concentration of combustible gases. A thin catalytic Pt film was deposited by CVD from the precursor Pt(acac).sub.2 onto microfilaments resistively heated to approximately 500 .degree. C.; Pt deposits only on the hot filament. The filaments tested to date are 2 .mu.m thick .times.10 .mu.m wide .times.100, 250, 500, or 1000 .mu.m-long polycrystalline Si; some are overcoated with a 0.25 .mu.m-thick protective CVD Si.sub.3 N.sub.4 layer.

  19. Results from the XENON10 and the Race to Detect Dark Matter with Noble Liquids

    ScienceCinema (OSTI)

    Shutt, Tom [Case Western Reserve, Cleveland, Ohio, United States

    2009-09-01

    Detectors based on liquid noble gases have the potential to revolutionize the direct search for WIMP dark matter. The XENON10 experiment, of which I am a member, has recently announced the results from it's first data run and is now the leading WIMP search experiment. This and other experiments using xenon, argon and neon have the potential to rapidly move from the current kg-scale target mass to the ton scale and well beyond. This should allow a (nearly) definitive test or discovery of dark matter if it is in the form of weakly interacting massive particles.

  20. Epsilon Metal Waste Form for Immobilization of Noble Metals from Used Nuclear Fuel

    SciTech Connect (OSTI)

    Crum, Jarrod V.; Strachan, Denis M.; Rohatgi, Aashish; Zumhoff, Mac R.

    2013-10-01

    Epsilon metal (?-metal), an alloy of Mo, Pd, Rh, Ru, and Tc, is being developed as a waste form to treat and immobilize the undissolved solids and dissolved noble metals from aqueous reprocessing of commercial used nuclear fuel. Epsilon metal is an attractive waste form for several reasons: increased durability relative to borosilicate glass, it can be fabricated without additives (100% waste loading), and in addition it also benefits borosilicate glass waste loading by eliminating noble metals from the glass and thus the processing problems related there insolubility in glass. This work focused on the processing aspects of the epsilon metal waste form development. Epsilon metal is comprised of refractory metals resulting in high reaction temperatures to form the alloy, expected to be 1500 - 2000C making it a non-trivial phase to fabricate by traditional methods. Three commercially available advanced technologies were identified: spark-plasma sintering, microwave sintering, and hot isostatic pressing, and investigated as potential methods to fabricate this waste form. Results of these investigations are reported and compared in terms of bulk density, phase assemblage (X-ray diffraction and elemental analysis), and microstructure (scanning electron microscopy).

  1. Electric dipole polarizabilities at imaginary frequencies for hydrogen, the alkali-metal, alkaline-earth, and noble gas atoms

    SciTech Connect (OSTI)

    Derevianko, Andrei Porsev, Sergey G. Babb, James F.

    2010-05-15

    The electric dipole polarizabilities evaluated at imaginary frequencies for hydrogen, the alkali-metal atoms, the alkaline-earth atoms, and the noble gases are tabulated along with the resulting values of the atomic static polarizabilities, the atom-surface interaction constants, and the dispersion (or van der Waals) constants for the homonuclear and the heteronuclear diatomic combinations of the atoms.

  2. Demonstration of neutron detection utilizing open cell foam and noble gas scintillation

    SciTech Connect (OSTI)

    Lavelle, C. M. Miller, E. C.; Coplan, M.; Thompson, Alan K.; Vest, Robert E.; Yue, A. T.; Kowler, A. L.; Koeth, T.; Al-Sheikhly, M.; Clark, Charles W.

    2015-03-02

    We present results demonstrating neutron detection via a closely spaced converter structure coupled to low pressure noble gas scintillation instrumented by a single photo-multiplier tube (PMT). The converter is dispersed throughout the gas volume using a reticulated vitreous carbon foam coated with boron carbide (B{sub 4}C). A calibrated cold neutron beam is used to measure the neutron detection properties, using a thin film of enriched {sup 10}B as a reference standard. Monte Carlo computations of the ion energy deposition are discussed, including treatment of the foam random network. Results from this study indicate that the foam shadows a significant portion of the scintillation light from the PMT. The high scintillation yield of Xe appears to overcome the light loss, facilitating neutron detection and presenting interesting opportunities for neutron detector design.

  3. Modelling of noble anaesthetic gases and high hydrostatic pressure effects in lipid bilayers

    SciTech Connect (OSTI)

    Moskovitz, Yevgeny; Yang, Hui

    2015-01-08

    Our objective was to study molecular processes that might be responsible for inert gas narcosis and high-pressure nervous syndrome. The classical molecular dynamics trajectories (200 ns-long) of dioleoylphosphatidylcholine (DOPC) bilayers simulated by the Berger force field were evaluated for water and the atomic distribution of noble gases around DOPC molecules at a pressure range of 1 - 1000 bar and temperature of 310 Kelvin. Xenon and argon have been tested as model gases for general anesthetics, and neon has been investigated for distortions that are potentially responsible for neurological tremor at hyperbaric conditions. The analysis of stacked radial pair distribution functions of DOPC headgroup atoms revealed the explicit solvation potential of gas molecules, which correlates with their dimensions. The orientational dynamics of water molecules at the biomolecular interface should be considered as an influential factor; while excessive solvation effects appearing in the lumen of membrane-embedded ion channels could be a possible cause of inert gas narcosis. All the noble gases tested exhibit similar patterns of the order parameter for both DOPC acyl chains, which is opposite to the patterns found for the order parameter curve at high hydrostatic pressures in intact bilayers. This finding supports the ‘critical volume’ hypothesis of anesthesia pressure reversal. The irregular lipid headgroup-water boundary observed in DOPC bilayers saturated with neon in the pressure range of 1 - 100 bar could be associated with the possible manifestation of neurological tremor at the atomic scale. The non-immobilizer neon also demonstrated the highest momentum impact on the normal component of the DOPC diffusion coefficient representing monolayers undulations rate, which indicates enhanced diffusivity, rather than atom size, as the key factor.

  4. Modelling of noble anaesthetic gases and high hydrostatic pressure effects in lipid bilayers

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Moskovitz, Yevgeny; Yang, Hui

    2015-01-08

    Our objective was to study molecular processes that might be responsible for inert gas narcosis and high-pressure nervous syndrome. The classical molecular dynamics trajectories (200 ns-long) of dioleoylphosphatidylcholine (DOPC) bilayers simulated by the Berger force field were evaluated for water and the atomic distribution of noble gases around DOPC molecules at a pressure range of 1 - 1000 bar and temperature of 310 Kelvin. Xenon and argon have been tested as model gases for general anesthetics, and neon has been investigated for distortions that are potentially responsible for neurological tremor at hyperbaric conditions. The analysis of stacked radial pair distributionmore » functions of DOPC headgroup atoms revealed the explicit solvation potential of gas molecules, which correlates with their dimensions. The orientational dynamics of water molecules at the biomolecular interface should be considered as an influential factor; while excessive solvation effects appearing in the lumen of membrane-embedded ion channels could be a possible cause of inert gas narcosis. All the noble gases tested exhibit similar patterns of the order parameter for both DOPC acyl chains, which is opposite to the patterns found for the order parameter curve at high hydrostatic pressures in intact bilayers. This finding supports the ‘critical volume’ hypothesis of anesthesia pressure reversal. The irregular lipid headgroup-water boundary observed in DOPC bilayers saturated with neon in the pressure range of 1 - 100 bar could be associated with the possible manifestation of neurological tremor at the atomic scale. The non-immobilizer neon also demonstrated the highest momentum impact on the normal component of the DOPC diffusion coefficient representing monolayers undulations rate, which indicates enhanced diffusivity, rather than atom size, as the key factor.« less

  5. Acid Strength and Bifunctional Catalytic Behavior of Alloys Comprised of Noble Metals and Oxophilic Metal Promoters

    SciTech Connect (OSTI)

    Hibbitts, David D.; Tan, Qiaohua; Neurock, Matthew

    2014-06-01

    The promotion of metal catalysts with partially oxidized oxophilic MOx species, such as ReOx-promoted Rh, has been demonstrated to produce Brnsted acid sites that can promote hydrogenolysis of oxygenate intermediates such as those found in biomass-derived species. A wide variety of alloy compositions and structures are examined in this work to investigate strongly acidic promoters by using DFT-calculated deprotonation energies (DPE) as a measure of acid strength. Sites with the highest acid strength had DPE less than 1100 kJ mol-1, similar to DPE values of heteropolyacids or acid-containing zeolites, and were found on alloys composed of an oxophilic metal (such as Re or W) with a noble metal (such as Rh or Pt). NH3 adsorbs more strongly to sites with increasing acid strength and the activation barriers for acid-catalyzed ring opening of a furan ring decrease with increasing acid strength, which was also shown to be stronger for OH acid sites bound to multiple oxophilic metal atoms in a three-fold configuration rather than OH sites adsorbed in an atop configuration on one oxophilic metal, indicating that small MOx clusters may yield sites with the highest acid strength.

  6. Simulated study of plasmonic coupling in noble bimetallic alloy nanosphere arrays

    SciTech Connect (OSTI)

    Bansal, Amit Verma, S. S.

    2014-05-15

    The plasmonic coupling between the interacting noble metal nanoparticles plays an important role to influence the optical properties of arrays. In this work, we have extended the Mie theory results of our recent communication to include the effect of particle interactions between the alloy nanoparticles by varying interparticle distance and number of particles. The localized surface plasmon resonance (LSPR) peak position, full width at half maxima (FWHM) and scattering efficiency of one dimensional (1D) bimetallic alloy nanosphere (BANS) arrays of earlier optimized compositions i.e. Ag{sub 0.75}Au{sub 0.25}, Au{sub 0.25}Cu{sub 0.75} and Ag{sub 0.50}Cu{sub 0.50} have been studied presently by using discrete dipole approximation (DDA) simulations. Studies have been made to optimize size of the nanosphere, number of spheres in the arrays, material and the interparticle distance. It has been found that both the scattering efficiency and FWHM (bandwidth) can be controlled in the large region of the electromagnetic (EM) spectrum by varying the number of interacting particles and interparticle distance. In comparison to other alloy arrays, Ag{sub 0.50}Cu{sub 0.50} BANS arrays (each of particle radius 50 nm) shows larger tunability of LSPR with wide bandwidth (essential condition for plasmonic solar cells)

  7. Isotopic noble gas signatures released from medical isotope production facilities - Simulations and measurements

    SciTech Connect (OSTI)

    Saey, Paul R.; Bowyer, Ted W.; Ringbom, Anders

    2010-09-09

    Journal article on the role that radioxenon isotopes play in confirming whether or not an underground explosion was nuclear in nature. Radioxenon isotopes play a major role in confirming whether or not an underground explosion was nuclear in nature. It is then of key importance to understand the sources of environmental radioxenon to be able to distinguish civil sources from those of a nuclear explosion. Based on several years of measurements, combined with advanced atmospheric transport model results, it was recently shown that the main source of radioxenon observations are strong and regular batch releases from a very limited number of medical isotope production facilities. This paper reviews production processes in different medical isotope facilities during which radioxenon is produced. Radioxenon activity concentrations and isotopic compositions are calculated for six large facilities. The results are compared with calculated signals from nuclear explosions. Further, the outcome is compared and found to be consistent with radioxenon measurements recently performed in and around three of these facilities. Some anomalies in measurements in which {sup 131m}Xe was detected were found and a possible explanation is proposed. It was also calculated that the dose rate of the releases is well below regulatory values. Based on these results, it should be possible to better understand, interpret and verify signals measured in the noble gas measurement systems in the International Monitoring of the Comprehensive Nuclear-Test-Ban Treaty.

  8. Enantioselectivity of (321) chiral noble metal surfaces: A density functional theory study of lactate adsorption

    SciTech Connect (OSTI)

    Franke, J.-H.; Kosov, D. S.

    2013-12-14

    The adsorption of the chiral molecule lactate on the intrinsically chiral noble metal surfaces Pt(321), Au(321), and Ag(321) is studied by density functional theory calculations. We use the oPBE-vdW functional which includes van der Waals forces on an ab initio level. It is shown that the molecule binds via its carboxyl and the hydroxyl oxygen atoms to the surface. The binding energy is larger on Pt(321) and Ag(321) than on Au(321). An analysis of the contributions to the binding energy of the different molecular functional groups reveals that the deprotonated carboxyl group contributes most to the binding energy, with a much smaller contribution of the hydroxyl group. The Pt(321) surface shows considerable enantioselectivity of 0.06 eV. On Au(321) and Ag(321) it is much smaller if not vanishing. The chiral selectivity of the Pt(321) surface can be explained by two factors. First, it derives from the difference in van der Waals attraction of L- and D-lactate to the surface that we trace to differences in the binding energy of the methyl group. Second, the multi-point binding pattern for lactate on the Pt(321) surface is sterically more sensitive to surface chirality and also leads to large binding energy contributions of the hydroxyl group. We also calculate the charge transfer to the molecule and the work function to gauge changes in electronic structure of the adsorbed molecule. The work function is lowered by 0.8 eV on Pt(321) with much smaller changes on Au(321) and Ag(321)

  9. Surface plasmon polariton assisted optical switching in noble bimetallic nanoparticle system

    SciTech Connect (OSTI)

    Dhara, Sandip E-mail: chenkh@pub.iams.sinica.edu.tw; Lu, C.-Y.; Tu, W.-S.; Magudapathy, P.; Huang, Y.-F.; Chen, K.-H. E-mail: chenkh@pub.iams.sinica.edu.tw

    2015-01-12

    Photoresponse of bimetallic Au-Ag nanoparticle embedded soda glass (Au-Ag@SG) substrate is reported for surface plasmon assisted optical switching using 808 nm excitation. Au-Ag@SG system is made by an ion beam technique where Ag{sup +} is introduced first in the soda glass matrix by ion exchange technique. Subsequently, 400 keV Au{sup +} is implanted in the sample for different fluences, which is followed by an ion beam annealing process using 1 MeV Si{sup +} at a fixed fluence of 2 × 10{sup 16} ions·cm{sup −2}. Characteristic surface plasmon resonance (SPR) peaks around 400 and 550 nm provided evidence for the presence of Au and Ag nanoparticles. An optical switching in the Au-Ag@SG system with 808 nm, which is away from the characteristic SPR peaks of Ag and Au nanoparticles, suggests the possible role of two photon absorption (TPA) owing to the presence of interacting electric dipole in these systems. The role of surface plasmon polariton is emphasized for the propagation of electronic carrier belonging to the conduction electron of Au-Ag system in understanding the observed photoresponse. Unique excitation dependent photoresponse measurements confirm the possible role of TPA process. A competitive interband and intraband transitions in the bimetallic system of Au and Ag, which may be primarily responsible for the observation, are validated qualitatively using finite difference time domain calculations where inter-particle separation of Au and Ag plays an important role. Thus, a smart way of optical switching can be envisaged in noble bimetallic nanocluster system where long wavelength with higher skin depth can be used for communication purpose.

  10. The effect of in-situ noble metal chemical addition on crack growth rate behavior of structural materials in 288 C water

    SciTech Connect (OSTI)

    Andresen, P.L.; Angeliu, T.

    1996-10-01

    Stress corrosion cracking (SCC), especially in existing boiling water reactor (BVM) components, is most effectively accomplished by reducing the corrosion potential. This was successfully demonstrated by adding hydrogen to BNM water, which reduced oxidant concentration and corrosion potential by recombining with the radiolytically formed oxygen and hydrogen peroxide. However, reduction in the corrosion potential for some vessel internals is difficult, and others require high hydrogen addition rates, which results in an increase in the main steam radiation level from volatile N{sup 16}. Noble metal electrocatalysis provides a unique opportunity to efficiently achieve a dramatic reduction in corrosion potential and SCC in BWRs, by catalytically reacting all oxidants that diffuse to a (catalytic) metal surface with hydrogen. There are many techniques for creating catalytic surfaces, including alloying with noble metals or applying noble metal alloy powders to existing BWR components by thermal spraying or weld cladding. A novel system-wide approach for producing catalytic surfaces on all wetted components has been developed which employs the reactor coolant water as the medium of transport. This approach is termed in-situ noble metal chemical addition (NMCA), and has been successfully used in extensive laboratory tests to coat a wide range of pre-oxidized structural materials. In turn, these specimens have maintained catalytic response in long term, cyclic exposures to extremes in dissolved gases, impurity levels, pH, flow rate, temperature, straining, etc. With stoichiometric excess H{sub 2}, the corrosion potential drops dramatically and crack initiation and growth are greatly reduced, even at high O{sub 2} or H{sub 2}O{sub 2} levels. Without excess H{sub 2} (i.e., in normal BWR water chemistry), noble metals do not increase the corrosion potential or SCC.

  11. Ultrabright multikilovolt x-ray source: saturated amplification on noble gas transition arrays from hollow atom states

    DOE Patents [OSTI]

    Rhodes, Charles K.; Boyer, Keith

    2004-02-17

    An apparatus and method for the generation of ultrabright multikilovolt x-rays from saturated amplification on noble gas transition arrays from hollow atom states is described. Conditions for x-ray amplification in this spectral region combine the production of cold, high-Z matter, with the direct, selective multiphoton excitation of hollow atoms from clusters using ultraviolet radiation and a nonlinear mode of confined, self-channeled propagation in plasmas. Data obtained is consistent with the presence of saturated amplification on several transition arrays of the hollow atom Xe(L) spectrum (.lambda..about.2.9 .ANG.). An estimate of the peak brightness achieved is .about.10.sup.29 .gamma..multidot.s.sup.-1.multidot.mm.sup.-2.multidot.mr.sup.-2 (0.1% Bandwidth).sup.-1, that is .about.10.sup.5 -fold higher than presently available synchotron technology.

  12. Environmental assessment and finding of no significant impact: Biorecycling Technologies, Inc., Noble Biogas and Fertilizer Plant, Fresno County, California

    SciTech Connect (OSTI)

    1997-09-01

    The US Department of Energy (DOE) is considering a proposal from the California Energy Commission for partial funding up to $1,500,000 of the construction of the biorecycling Technologies, Inc., (BTI) Noble Biogas and Fertilizer Plant in Fresno County, California. BTI along with its contractors and business partners would develop the plant, which would use manure and green waste to produce biogas and a variety of organic fertilizer products. The California Energy Commission has requested funding from the DOE Commercialization Ventures program to assist in the construction of the plant, which would produce up to one megawatt of electricity by burning biogas in a cogeneration unit. The purpose of this environmental assessment (EA) is to provide DOE and the public with information on potential environmental impacts associated with funding development of the proposed project.

  13. Noble gas component organization in Apollo 14 breccia 14318: /sup 129/I and /sup 244/Pu regolith chronology

    SciTech Connect (OSTI)

    Swindle, T.D.; Caffee, M.W.; Hohenberg, C.M.; Hudson, G.B.; Laul, J.C.; Simon, S.B.; Papike, J.J.

    1985-02-15

    Noble gas, petrological, and chemical studies made on grain-size separates from lunar regolith breccia 14318 demonstrate that the noble gases are organized into two functional components, volume-correlated and surface-correlated. As in regolith breccia 14301, volume-correlated xenon in 14318 is primarily spallation-derived and the surface-correlated component contains not only solar wind xenon but also significant amounts of ''parentless' xenon from the fission of now extinct /sup 244/Pu and the decay of now extinct /sup 129/I (''parentless'' means the daughter products were incorporated onto grain surfaces following decay of the parent nuclide elsewhere). The ratio of /sup 129/Xe//sup 136/Xe in the total surface-correlated parentless component, as identified in grain-size analysis, is substantially higher than in the least tightly bound parentless component identified in stepwise heating analyses, confirming the trend seen in 14301. If the order of release of gases in stepwise heating is related to the order of incorporation in the simplest way (first in, last out), incorporation of these grain-surface components was probably time-ordered. The /sup 129/Xe//sup 136/Xe ratio in each identifiable parentless component would then be characteristic of the xenon available for surface adsorption at the particular time of acquisition. Continuous variations in this ratio further suggest that incorporation of the parentless xenon was closely coupled with production. Such observations provide the basis for a new chronometer from which we conclude that acquisition of parentless xenon was an ongoing process spanning at least 90 m.y., beginning no more than 44 +- 34 m.y. after the formation of the most meteorites and possibly predating xenon acquisition for the earth.

  14. USCA Convocation Center 375 Robert Bell Parkway, Aiken, SC 29801

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Workforce of Tomorrow | Department of Energy USA Science and Engineering Festival: Inspiring and Educating the Clean Energy Workforce of Tomorrow USA Science and Engineering Festival: Inspiring and Educating the Clean Energy Workforce of Tomorrow April 23, 2014 - 9:52am Addthis The Energy Department has several free resources that help educators teach students about clean energy including (clockwise, from top left) the <a

  15. A density functional theory study of magneto-electric Jones birefringence of noble gases, furan homologues, and mono-substituted benzenes

    SciTech Connect (OSTI)

    Fahleson, Tobias; Norman, Patrick; Coriani, Sonia; Rizzo, Antonio; Rikken, Geert L. J. A.

    2013-11-21

    We report on the results of a systematic ab initio study of the Jones birefringence of noble gases, of furan homologues, and of monosubstituted benzenes, in the gas phase, with the aim of analyzing the behavior and the trends within a list of systems of varying size and complexity, and of identifying candidates for a combined experimental/theoretical study of the effect. We resort here to analytic linear and nonlinear response functions in the framework of time-dependent density functional theory. A correlation is made between the observable (the Jones constant) and the atomic radius for noble gases, or the permanent electric dipole and a structure/chemical reactivity descriptor as the para Hammett constant for substituted benzenes.

  16. Conceptual Engineering Method for Attenuating He Ion Interactions on First Wall Components in the Fusion Test Facility (FTF) Employing a Low-Pressure Noble Gas

    SciTech Connect (OSTI)

    C.A.Gentile, W.R.Blanchard, T.Kozub, C.Priniski, I.Zatz, S.Obenschain

    2009-09-21

    It has been shown that post detonation energetic helium ions can drastically reduce the useful life of the (dry) first wall of an IFE reactor due to the accumulation of implanted helium. For the purpose of attenuating energetic helium ions from interacting with first wall components in the Fusion Test Facility (FTF) target chamber, several concepts have been advanced. These include magnetic intervention (MI), deployment of a dynamically moving first wall, use of a sacrificial shroud, designing the target chamber large enough to mitigate the damage caused by He ions on the target chamber wall, and the use of a low pressure noble gas resident in the target chamber during pulse power operations. It is proposed that employing a low-pressure (~ 1 torr equivalent) noble gas in the target chamber will thermalize energetic helium ions prior to interaction with the wall. The principle benefit of this concept is the simplicity of the design and the utilization of (modified) existing technologies for pumping and processing the noble ambient gas. Although the gas load in the system would be increased over other proposed methods, the use of a "gas shield" may provide a cost effective method of greatly extending the first wall of the target chamber. An engineering study has been initiated to investigate conceptual engineering metmethods for implementing a viable gas shield strategy in the FTF.

  17. Striving toward noble-metal-free photocatalytic water splitting: The hydrogenated-graphene-TiO2 prototype

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Nguyen-Phan, Thuy -Duong; Luo, Si; Liu, Zongyuan; Gamalski, Andrew D.; Tao, Jing; Xu, Wenqian; Stach, Eric A.; Polyansky, Dmitry E.; Senanayake, Sanjaya D.; Fujita, Etsuko; et al

    2015-08-20

    Graphane, graphone and hydrogenated graphene (HG) have been extensively studied in recent years due to their interesting properties and potential use in commercial and industrial applications. The present study reports investigation of hydrogenated graphene/TiO2-x (HGT) nanocomposites as photocatalysts for H2 and O2 production from water without the assistance of a noble metal co-catalyst. By combination of several techniques, the morphologies, bulk/atomic structure and electronic properties of all the powders were exhaustively interrogated. Hydrogenation treatment efficiently reduces TiO2 nanoparticles, while the graphene oxide sheets undergo the topotactic transformation from a graphene-like structure to a mixture of graphitic and turbostratic carbon (amorphous/disordered)more » upon altering the calcination atmosphere from a mildly reducing to a H2-abundant environment. Remarkably, the hydrogenated graphene-TiO2-x composite that results upon H2-rich reduction exhibits the highest photocatalytic H2 evolution performance equivalent to low loading of Pt (~0.12 wt%), whereas the addition of HG suppresses the O2 production. As a result, we propose that such an enhancement can be attributed to a combination of factors including the introduction of oxygen vacancies and Ti3+ states, retarding the recombination of charge carriers and thus, facilitating the charge transfer from TiO2-x to the carbonaceous sheet.« less

  18. A Concept for a Low Pressure Noble Gas Fill Intervention in the IFE Fusion Test Facility (FTF) Target Chamber

    SciTech Connect (OSTI)

    Gentile, C. A.; Blanchard, W. R.; Kozub, T. A.; Aristova, M.; McGahan, C.; Natta, S.; Pagdon, K.; Zelenty, J.

    2010-01-14

    An engineering evaluation has been initiated to investigate conceptual engineering methods for implementing a viable gas shield strategy in the Fusion Test Facility (FTF) target chamber. The employment of a low pressure noble gas in the target chamber to thermalize energetic helium ions prior to interaction with the wall could dramatically increase the useful life of the first wall in the FTF reactor1. For the purpose of providing flexibility, two target chamber configurations are addressed: a five meter radius sphere and a ten meter radius sphere. Experimental studies at Nike have indicated that a low pressure, ambient gas resident in the target chamber during laser pulsing does not appear to impair the ability of laser light from illuminating targets2. In addition, current investigations into delivering, maintaining, and processing low pressure gas appear to be viable with slight modification to current pumping and plasma exhaust processing technologies3,4. Employment of a gas fill solution for protecting the dry wall target chamber in the FTF may reduce, or possibly eliminate the need for other attenuating technologies designed for keeping He ions from implanting in first wall structures and components. The gas fill concept appears to provide an effective means of extending the life of the first wall while employing mostly commercial off the shelf (COTS) technologies. Although a gas fill configuration may provide a methodology for attenuating damage inflicted on chamber surfaces, issues associated with target injection need to be further analyzed to ensure that the gas fill concept is viable in the integrated FTF design5. In the proposed system, the ambient noble gas is heated via the energetic helium ions produced by target detonation. The gas is subsequently cooled by the chamber wall to approximately 800oC, removed from the chamber, and processed by the chamber gas processing system (CGPS). In an optimized scenario of the above stated concept, the chamber

  19. Molecular dynamics simulation of framework flexibility effects on noble gas diffusion in HKUST-1 and ZIF-8

    SciTech Connect (OSTI)

    Parkes, Marie V.; Demir, Hakan; Teich-McGoldrick, Stephanie L.; Sholl, David S.; Greathouse, Jeffery A.; Allendorf, Mark D.

    2014-03-28

    Molecular dynamics simulations were used to investigate trends in noble gas (Ar, Kr, Xe) diffusion in the metal-organic frameworks HKUST-1 and ZIF-8. Diffusion occurs primarily through inter-cage jump events, with much greater diffusion of guest atoms in HKUST-1 compared to ZIF-8 due to the larger cage and window sizes in the former. We compare diffusion coefficients calculated for both rigid and flexible frameworks. For rigid framework simulations, in which the framework atoms were held at their crystallographic or geometry optimized coordinates, sometimes dramatic differences in guest diffusion were seen depending on the initial framework structure or the choice of framework force field parameters. When framework flexibility effects were included, argon and krypton diffusion increased significantly compared to rigid-framework simulations using general force field parameters. Additionally, for argon and krypton in ZIF-8, guest diffusion increased with loading, demonstrating that guest-guest interactions between cages enhance inter-cage diffusion. No inter-cage jump events were seen for xenon atoms in ZIF-8 regardless of force field or initial structure, and the loading dependence of xenon diffusion in HKUST-1 is different for rigid and flexible frameworks. Diffusion of krypton and xenon in HKUST-1 depends on two competing effects: the steric effect that decreases diffusion as loading increases, and the “small cage effect” that increases diffusion as loading increases. Finally, a detailed analysis of the window size in ZIF-8 reveals that the window increases beyond its normal size to permit passage of a (nominally) larger krypton atom.

  20. Molecular dynamics simulation of framework flexibility effects on noble gas diffusion in HKUST-1 and ZIF-8

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Parkes, Marie V.; Demir, Hakan; Teich-McGoldrick, Stephanie L.; Sholl, David S.; Greathouse, Jeffery A.; Allendorf, Mark D.

    2014-03-28

    Molecular dynamics simulations were used to investigate trends in noble gas (Ar, Kr, Xe) diffusion in the metal-organic frameworks HKUST-1 and ZIF-8. Diffusion occurs primarily through inter-cage jump events, with much greater diffusion of guest atoms in HKUST-1 compared to ZIF-8 due to the larger cage and window sizes in the former. We compare diffusion coefficients calculated for both rigid and flexible frameworks. For rigid framework simulations, in which the framework atoms were held at their crystallographic or geometry optimized coordinates, sometimes dramatic differences in guest diffusion were seen depending on the initial framework structure or the choice of frameworkmore » force field parameters. When framework flexibility effects were included, argon and krypton diffusion increased significantly compared to rigid-framework simulations using general force field parameters. Additionally, for argon and krypton in ZIF-8, guest diffusion increased with loading, demonstrating that guest-guest interactions between cages enhance inter-cage diffusion. No inter-cage jump events were seen for xenon atoms in ZIF-8 regardless of force field or initial structure, and the loading dependence of xenon diffusion in HKUST-1 is different for rigid and flexible frameworks. Diffusion of krypton and xenon in HKUST-1 depends on two competing effects: the steric effect that decreases diffusion as loading increases, and the “small cage effect” that increases diffusion as loading increases. Finally, a detailed analysis of the window size in ZIF-8 reveals that the window increases beyond its normal size to permit passage of a (nominally) larger krypton atom.« less

  1. The solvation radius of silicate melts based on the solubility of noble gases and scaled particle theory

    SciTech Connect (OSTI)

    Ottonello, Giulio; Richet, Pascal

    2014-01-28

    The existing solubility data on noble gases in high-temperature silicate melts have been analyzed in terms of Scaling Particle Theory coupled with an ab initio assessment of the electronic, dispersive, and repulsive energy terms based on the Polarized Continuum Model (PCM). After a preliminary analysis of the role of the contracted Gaussian basis sets and theory level in reproducing appropriate static dipole polarizabilities in a vacuum, we have shown that the procedure returns Henry's law constants consistent with the values experimentally observed in water and benzene at T = 25?C and P = 1 bar for the first four elements of the series. The static dielectric constant (?) of the investigated silicate melts and its optical counterpart (?{sup ?}) were then resolved through the application of a modified form of the Clausius-Mossotti relation. Argon has been adopted as a probe to depict its high-T solubility in melts through an appropriate choice of the solvent diameter ?{sub s}, along the guidelines already used in the past for simple media such as water or benzene. The ?{sub s} obtained was consistent with a simple functional form based on the molecular volume of the solvent. The solubility calculations were then extended to He, Ne, and Kr, whose dispersive and repulsive coefficients are available from theory and we have shown that their ab initio Henry's constants at high T reproduce the observed increase with the static polarizability of the series element with reasonable accuracy. At room temperature (T = 25?C) the calculated Henry's constants of He, Ne, Ar, and Kr in the various silicate media predict higher solubilities than simple extrapolations (i.e., Arrhenius plots) based on high-T experiments and give rise to smooth trends not appreciably affected by the static polarizabilities of the solutes. The present investigation opens new perspectives on a wider application of PCM theory which can be extended to materials of great industrial interest at the core of

  2. Intriguing structures and magic sizes of heavy noble metal nanoclusters around size 55 governed by relativistic effect and covalent bonding

    SciTech Connect (OSTI)

    Zhao, X. J.; Xue, X. L.; Jia, Yu; Guo, Z. X.; Li, S. F.; Zhang, Zhenyu; Gao, Y. F.

    2015-11-07

    Nanoclusters usually display exotic physical and chemical properties due to their intriguing geometric structures in contrast to their bulk counterparts. By means of first-principles calculations within density functional theory, we find that heavy noble metal Pt{sub N} nanoclusters around the size N = 55 begin to prefer an open configuration, rather than previously reported close-packed icosahedron or core-shell structures. Particularly, for Pt{sub N}, the widely supposed icosahedronal magic cluster is changed to a three-atomic-layered structure with D{sub 6h} symmetry, which can be well addressed by our recently established generalized Wulff construction principle (GWCP). However, the magic number of Pt{sub N} clusters around 55 is shifted to a new odd number of 57. The high symmetric three-layered Pt{sub 57} motif is mainly stabilized by the enhanced covalent bonding contributed by both spin-orbital coupling effect and the open d orbital (5d{sup 9}6s{sup 1}) of Pt, which result in a delicate balance between the enhanced Pt–Pt covalent bonding of the interlayers and negligible d dangling bonds on the cluster edges. These findings about Pt{sub N} clusters are also applicable to Ir{sub N} clusters, but qualitatively different from their earlier neighboring element Os and their later neighboring element Au. The magic numbers for Os and Au are even, being 56 and 58, respectively. The findings of the new odd magic number 57 are the important supplementary of the recently established GWCP.

  3. Striving toward noble-metal-free photocatalytic water splitting: The hydrogenated-graphene-TiO2 prototype

    SciTech Connect (OSTI)

    Nguyen-Phan, Thuy -Duong; Luo, Si; Liu, Zongyuan; Gamalski, Andrew D.; Tao, Jing; Xu, Wenqian; Stach, Eric A.; Polyansky, Dmitry E.; Senanayake, Sanjaya D.; Fujita, Etsuko; Rodriguez, Jose A.

    2015-08-20

    Graphane, graphone and hydrogenated graphene (HG) have been extensively studied in recent years due to their interesting properties and potential use in commercial and industrial applications. The present study reports investigation of hydrogenated graphene/TiO2-x (HGT) nanocomposites as photocatalysts for H2 and O2 production from water without the assistance of a noble metal co-catalyst. By combination of several techniques, the morphologies, bulk/atomic structure and electronic properties of all the powders were exhaustively interrogated. Hydrogenation treatment efficiently reduces TiO2 nanoparticles, while the graphene oxide sheets undergo the topotactic transformation from a graphene-like structure to a mixture of graphitic and turbostratic carbon (amorphous/disordered) upon altering the calcination atmosphere from a mildly reducing to a H2-abundant environment. Remarkably, the hydrogenated graphene-TiO2-x composite that results upon H2-rich reduction exhibits the highest photocatalytic H2 evolution performance equivalent to low loading of Pt (~0.12 wt%), whereas the addition of HG suppresses the O2 production. As a result, we propose that such an enhancement can be attributed to a combination of factors including the introduction of oxygen vacancies and Ti3+ states, retarding the recombination of charge carriers and thus, facilitating the charge transfer from TiO2-x to the carbonaceous sheet.

  4. Transferability and accuracy by combining dispersionless density functional and incremental post-Hartree-Fock theories: Noble gases adsorption on coronene/graphene/graphite surfaces

    SciTech Connect (OSTI)

    Lara-Castells, María Pilar de Bartolomei, Massimiliano; Mitrushchenkov, Alexander O.; Stoll, Hermann

    2015-11-21

    The accuracy and transferability of the electronic structure approach combining dispersionless density functional theory (DFT) [K. Pernal et al., Phys. Rev. Lett. 103, 263201 (2009)] with the method of increments [H. Stoll, J. Chem. Phys. 97, 8449 (1992)], are validated for the interaction between the noble-gas Ne, Ar, Kr, and Xe atoms and coronene/graphene/graphite surfaces. This approach uses the method of increments for surface cluster models to extract intermonomer dispersion-like (2- and 3-body) correlation terms at coupled cluster singles and doubles and perturbative triples level, while periodic dispersionless density functionals calculations are performed to estimate the sum of Hartree-Fock and intramonomer correlation contributions. Dispersion energy contributions are also obtained using DFT-based symmetry-adapted perturbation theory [SAPT(DFT)]. An analysis of the structure of the X/surface (X = Ne, Ar, Kr, and Xe) interaction energies shows the excellent transferability properties of the leading intermonomer correlation contributions across the sequence of noble-gas atoms, which are also discussed using the Drude oscillator model. We further compare these results with van der Waals-(vdW)-corrected DFT-based approaches. As a test of accuracy, the energies of the low-lying nuclear bound states supported by the laterally averaged X/graphite potentials (X = {sup 3}He, {sup 4}He, Ne, Ar, Kr, and Xe) are calculated and compared with the best estimations from experimental measurements and an atom-bond potential model using the ab initio-assisted fine-tuning of semiempirical parameters. The bound-state energies determined differ by less than 6–7 meV (6%) from the atom-bond potential model. The crucial importance of including incremental 3-body dispersion-type terms is clearly demonstrated, showing that the SAPT(DFT) approach effectively account for these terms. With the deviations from the best experimental-based estimations smaller than 2.3 meV (1.9%), the

  5. Redox buffered hydrofluoric acid etchant for the reduction of galvanic attack during release etching of MEMS devices having noble material films

    SciTech Connect (OSTI)

    Hankins, Matthew G.

    2009-10-06

    Etchant solutions comprising a redox buffer can be used during the release etch step to reduce damage to the structural layers of a MEMS device that has noble material films. A preferred redox buffer comprises a soluble thiophosphoric acid, ester, or salt that maintains the electrochemical potential of the etchant solution at a level that prevents oxidation of the structural material. Therefore, the redox buffer preferentially oxidizes in place of the structural material. The sacrificial redox buffer thereby protects the exposed structural layers while permitting the dissolution of sacrificial oxide layers during the release etch.

  6. IMPACT OF NOBLE METALS AND MERCURY ON HYDROGEN GENERATION DURING HIGH LEVEL WASTE PRETREATMENT AT THE SAVANNAH RIVER SITE

    SciTech Connect (OSTI)

    Stone, M; Tommy Edwards, T; David Koopman, D

    2009-03-03

    simulant was used for all tests and was spiked with the required amount of noble metals immediately prior to performing the test. Acid addition was kept effectively constant except to compensate for variations in the starting mercury concentration. SME cycles were also performed during six of the tests.

  7. Catching the role of anisotropic electronic distribution and charge transfer in halogen bonded complexes of noble gases

    SciTech Connect (OSTI)

    Bartocci, Alessio; Cappelletti, David; Pirani, Fernando; Belpassi, Leonardo; Falcinelli, Stefano; Grandinetti, Felice; Tarantelli, Francesco

    2015-05-14

    The systems studied in this work are gas-phase weakly bound adducts of the noble-gas (Ng) atoms with CCl{sub 4} and CF{sub 4}. Their investigation was motivated by the widespread current interest for the intermolecular halogen bonding (XB), a structural motif recognized to play a role in fields ranging from elementary processes to biochemistry. The simulation of the static and dynamic behaviors of complex systems featuring XB requires the formulation of reliable and accurate model potentials, whose development relies on the detailed characterization of strength and nature of the interactions occurring in simple exemplary halogenated systems. We thus selected the prototypical Ng-CCl{sub 4} and Ng-CF{sub 4} and performed high-resolution molecular beam scattering experiments to measure the absolute scale of their intermolecular potentials, with high sensitivity. In general, we expected to probe typical van der Waals interactions, consisting of a combination of size (exchange) repulsion with dispersion/induction attraction. For the He/Ne-CF{sub 4}, the analysis of the glory quantum interference pattern, observable in the velocity dependence of the integral cross section, confirmed indeed this expectation. On the other hand, for the He/Ne/Ar-CCl{sub 4}, the scattering data unravelled much deeper potential wells, particularly for certain configurations of the interacting partners. The experimental data can be properly reproduced only including a shifting of the repulsive wall at shorter distances, accompanied by an increased role of the dispersion attraction, and an additional short-range stabilization component. To put these findings on a firmer ground, we performed, for selected geometries of the interacting complexes, accurate theoretical calculations aimed to evaluate the intermolecular interaction and the effects of the complex formation on the electron charge density of the constituting moieties. It was thus ascertained that the adjustments of the potential

  8. PARAMETRIC EFFECTS OF ANTI-FOAM COMPOSITION, SIMULANT PROPERTIES AND NOBLE METALS ON THE GAS HOLDUP AND RELEASE OF A NON-NEWTONIAN WASTE SLURRY SIMULANT

    SciTech Connect (OSTI)

    Guerrero, H; Charles Crawford, C; Mark Fowley, M

    2008-08-07

    Gas holdup tests were performed in bench-scale and small-scale mechanically-agitated mixing systems at the Savannah River National Laboratory (SRNL) for a simulant of waste from the Hanford Tank 241-AZ-101. These featured additions of DOW Corning Q2-3183A anti-foam agent. Results indicated that this anti-foam agent (AFA) increased gas holdup in the waste simulant by about a factor of four and, counter-intuitively, that the holdup increased as the non-newtonian simulant shear strength decreased (apparent viscosity decreased). Such results raised the potential of increased flammable gas retention in Hanford Waste Treatment and Immobilization Plant (WTP) vessels mixed by air sparging and pulse-jet mixers (PJMs) during a Design Basis Event (DBE). Additional testing was performed to determine the effects of simulant properties, composition of alternate AFAs, and presence of trace noble metals. Key results are that: (1) Increased gas holdup resulting from addition of Q2-3183A is due to a decrease in surface tension that supports small bubbles which have low rise velocities. (2) Dow Corning 1520-US AFA shows it to be a viable replacement to Dow Corning Q2-3183A AFA. This alternative AFA, however, requires significantly higher dosage for the same anti-foam function. (3) Addition of noble metals to the AZ-101 waste simulant does not produce a catalytic gas retention effect with the AFA.

  9. In Situ Studies of Surface Mobility on Noble Metal Model Catalysts Using STM and XPS at Ambient Pressure

    SciTech Connect (OSTI)

    Butcher, Derek Robert

    2010-06-14

    High Pressure Scanning Tunneling Microscopy (HP-STM) and Ambient Pressure X-ray Photoelectron Spectroscopy were used to study the structural properties and catalytic behavior of noble metal surfaces at high pressure. HP-STM was used to study the structural rearrangement of the top most atomic surface layer of the metal surfaces in response to changes in gas pressure and reactive conditions. AP-XPS was applied to single crystal and nanoparticle systems to monitor changes in the chemical composition of the surface layer in response to changing gas conditions. STM studies on the Pt(100) crystal face showed the lifting of the Pt(100)-hex surface reconstruction in the presence of CO, H2, and Benzene. The gas adsorption and subsequent charge transfer relieves the surface strain caused by the low coordination number of the (100) surface atoms allowing the formation of a (1 x 1) surface structure commensurate with the bulk terminated crystal structure. The surface phase change causes a transformation of the surface layer from hexagonal packing geometry to a four-fold symmetric surface which is rich in atomic defects. Lifting the hex reconstruction at room temperature resulted in a surface structure decorated with 2-3 nm Pt adatom islands with a high density of step edge sites. Annealing the surface at a modest temperature (150 C) in the presence of a high pressure of CO or H{sub 2} increased the surface diffusion of the Pt atoms causing the adatom islands to aggregate reducing the surface concentration of low coordination defect sites. Ethylene hydrogenation was studied on the Pt(100) surface using HP-STM. At low pressure, the lifting of the hex reconstruction was observed in the STM images. Increasing the ethylene pressure to 1 Torr, was found to regenerate the hexagonally symmetric reconstructed phase. At room temperature ethylene undergoes a structural rearrangement to form ethylidyne. Ethylidyne preferentially binds at the three-fold hollow sites, which are present on

  10. Comparative Study on the Sulfur Tolerance and Carbon Resistance of Supported Noble Metal Catalysts in Steam Reforming of Liquid Hydrocarbon Fuel

    SciTech Connect (OSTI)

    Xie, Chao; Chen, Yongsheng; Engelhard, Mark H.; Song, Chunshan

    2012-04-18

    This work was conducted to clarify the influence of the type of metal and support on the sulfur tolerance and carbon resistance of supported noble metal catalysts in steam reforming of liquid hydrocarbons. Al2O3-supported noble metal catalysts (Rh, Ru, Pt, and Pd), Rh catalysts on different supports (Al2O3, CeO2, SiO2, and MgO), and Pt catalyst supported on CeO2 and Al2O3, were examined for steam reforming of a liquid hydrocarbon fuel (Norpar13 from Exxon Mobil) at 800 C for 55 h. The results indicate that (1) Rh/Al2O3 shows higher sulfur tolerance than the Ru, Pt, and Pd catalysts on the same support; (2) both Al2O3 and CeO2 are promising supports for Rh catalyst to process sulfur-containing hydrocarbons; and (3) Pt/CeO2 exhibits better catalytic performance than Pt/Al2O3 in the reaction with sulfur. TEM results demonstrate that the metal particles in Rh/Al2O3 were better dispersed (mostly in 1-3 nm) compared with the other catalysts after reforming the sulfur-containing feed. As revealed by XPS, the binding energy of Rh 3d for Rh/Al2O3 is notably higher than that for Rh/CeO2, implying the formation of electron-deficient Rh particles in the former. The strong sulfur tolerance of Rh/Al2O3 may be related to the formation of well-dispersed electron-deficient Rh particles on the Al2O3 support. Sulfur K-edge XANES illustrates the preferential formation of sulfonate and sulfate on Rh/Al2O3, which is believed to be beneficial for improving its sulfur tolerance as their oxygen-shielded sulfur structure may hinder direct Rh-S interaction. Due to its strong sulfur tolerance, the carbon deposition on Rh/Al2O3 was significantly lower than that on the Al2O3-supported Ru, Pt, and Pd catalysts after the reaction with sulfur. The superior catalytic performance of CeO2-supported Rh and Pt catalysts in the presence of sulfur can be ascribed mainly to the promotion effect of CeO2 on carbon gasification, leading to much lower carbon deposition compared with the Rh/Al2O3, Rh/MgO, Rh

  11. A reduced mechanism for methane and one-step rate expressions for fuel-lean catalytic combustion of small alkanes on noble metals

    SciTech Connect (OSTI)

    Deshmukh, S.R.; Vlachos, D.G.

    2007-06-15

    A reduced mechanism and a one-step rate expression for fuel-lean methane/air catalytic combustion on an Rh catalyst are proposed. These are developed from a detailed microkinetic model using a computer-aided model reduction strategy that employs reaction path analysis, sensitivity analysis, partial equilibrium analysis, and simple algebra to deduce the most abundant reaction intermediate and the rate-determining step. The mechanism and the one-step rate expression are then tested on Pt catalyst. It is found that the reaction proceeds effectively via the same mechanistic pathway on both noble metals, but the effective reaction orders differ due to the difference in the adsorption strength of oxygen. Based on the homologous series idea, the rate expression is extended to small alkanes (ethane and propane; butane is also briefly discussed) and is found to reasonably describe experimental data. Estimation of the relevant parameters in the rate expression for various fuels and catalysts using the semiempirical bond-order conservation theory, quantum mechanical density functional theory, and/or simple experiments is discussed. Finally, it is proposed that detailed microkinetic models with coverage-dependent parameters can assist in rationalizing the apparent discrepancies between experimental data from various research groups. (author)

  12. Nobles Cooperative Electric | Open Energy Information

    Open Energy Info (EERE)

    Electric Place: Minnesota Phone Number: 507-372-7331 Website: www.noblesce.coop Facebook: https:www.facebook.comnoblescooperativeelectric Outage Hotline: 507-372-7331...

  13. Sintering and ripening resistant noble metal nanostructures

    DOE Patents [OSTI]

    van Swol, Frank B; Song, Yujiang; Shelnutt, John A; Miller, James E; Challa, Sivakumar R

    2013-09-24

    Durable porous metal nanostructures comprising thin metal nanosheets that are metastable under some conditions that commonly produce rapid reduction in surface area due to sintering and/or Ostwald ripening. The invention further comprises the method for making such durable porous metal nanostructures. Durable, high-surface area nanostructures result from the formation of persistent durable holes or pores in metal nanosheets formed from dendritic nanosheets.

  14. Platinum-Coated Non-Noble Metal-Noble Metal Core-Shell Electrocatalyst...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of platinum. The nanoparticles have a core-shell structure and include palladium, gold, and their alloys with other transition metals. The platinum-coated composite can be...

  15. Limestone County, Alabama: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Ardmore, Alabama Athens, Alabama Decatur, Alabama Elkmont, Alabama Huntsville, Alabama Lester, Alabama Madison, Alabama Mooresville, Alabama Retrieved from "http:en.openei.orgw...

  16. SOLID STATE CONTAINMENT OF NOBLE GASES IN SPUTTER DEPOSITED METALS...

    Office of Scientific and Technical Information (OSTI)

    MLA APA Chicago Bibtex Export Metadata Endnote Excel CSV XML Save to My Library Send to Email Send to Email Email address: Content: Close Send Cite: MLA Format Close Cite: ...

  17. Tuning of noble metal work function with organophosphonate nanolayers

    SciTech Connect (OSTI)

    Ramanath, Ganpati Kwan, Matthew; Chow, P. K.; Quintero, Y. Cardona; Ramprasad, R.; Mutin, P. H.

    2014-08-25

    We demonstrate that weak chemical interactions between untethered moieties in molecular nanolayers on metal surfaces can strongly influence the effective work function ?{sub eff}. Electron spectroscopy shows that nanolayers of mercaptan-anchored organophosphonates on Au and Pt decrease ?{sub eff}. The measured ?{sub eff} shifts correlate with the chemical state of phosphonic acid moieties, and scale with molecular length. These results are contrary to predictions of ab initio calculations of monolayer-capped surfaces, but are consistent with calculations of bilayer-capped surfaces with face-to-face hydrogen-bonded phosphonic acid moieties. Our findings indicate that intra-layer bonding and layering in molecular nanolayers can be key to tailoring heterointerfacial electronic properties for applications.

  18. Noble Americas Energy Solutions LLC | Open Energy Information

    Open Energy Info (EERE)

    - File1a1 EIA Form 861 Data Utility Id 16840 Utility Location Yes Ownership R NERC Location WECC Activity Retail Marketing Yes This article is a stub. You can help OpenEI by...

  19. Effect of Noble Gases on Sonoluminescence Temperatures during...

    Office of Scientific and Technical Information (OSTI)

    Authors: Didenko, Yuri T. ; McNamara, William B. III ; Suslick, Kenneth S. Publication Date: 2000-01-24 OSTI Identifier: 20215350 Resource Type: Journal Article Resource Relation: ...

  20. Saving the Fuel Cell Dream: Making Non Noble Metal Electrocatalysts...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    kick-off meeting of the U.S. Department of Energy Fuel Cell Technologies Program's Catalysis Working Group, held May 14, 2012, in Arlington, Virginia. 4cwgmay2012mukerjee.pdf ...

  1. Method for the purification of noble gases, nitrogen and hydrogen

    DOE Patents [OSTI]

    Baker, John D.; Meikrantz, David H.; Tuggle, Dale G.

    1997-01-01

    A method and apparatus for the purification and collection of hydrogen isotopes in a flowing inert gaseous mixture containing impurities, wherein metal alloy getters having the capability of sorbing non-hydrogen impurities such as oxygen, carbon dioxide, carbon monoxide, methane, ammonia, nitrogen and water vapor are utilized to purify the gaseous mixture of impurities. After purification hydrogen isotopes may be more efficiently collected. A plurality of parallel process lines utilizing metal getter alloys can be used to provide for the continuous purification and collection of the hydrogen isotopes.

  2. Noble Americas Energy Solutions LLC (Michigan) | Open Energy...

    Open Energy Info (EERE)

    1 888-896-8640 or 1 877-273-6772 or (248) 351-2660 Website: noblesolutions.comindex.html Outage Hotline: 1 888-896-8640 or Local Utility References: EIA Form EIA-861 Final Data...

  3. Thermodynamic aspects of dehydrogenation reactions on noble metal surfaces

    SciTech Connect (OSTI)

    Svane, K. L. Hammer, B.

    2014-11-07

    The reaction free energy for dehydrogenation of phenol, aniline, thiophenol, benzoic acid, and 1,4-benzenediol on the close packed copper, silver, and gold surfaces has been studied by density functional theory calculations. Dehydrogenation of thiophenol is found to be favourable on all three surfaces while aniline does not dehydrogenate on any of them. For phenol, benzenediol and benzoic acid dehydrogenation is favourable on copper and silver only, following the general trend of an increasing reaction free energy when going form gold to silver to copper. This trend can be correlated with the changes in bond lengths within the molecule upon dehydrogenation. While copper is able to replace hydrogen, leaving small changes in the bond lengths of the aromatic ring, the metal-molecule bond is weaker for silver and gold, resulting in a partial loss of aromaticity. This difference in bond strength leads to pronounced differences in adsorption geometries upon multiple dehydrogenations.

  4. EA-364-A Noble Americas CN.pdf

    Office of Environmental Management (EM)

  5. Noble Americas Energy Solutions LLC | Open Energy Information

    Open Energy Info (EERE)

    Data Utility Id 16840 Utility Location Yes Ownership R NERC Location WECC Activity Retail Marketing Yes This article is a stub. You can help OpenEI by expanding it. Utility Rate...

  6. Atomic Layer Deposition (ALD) Preparation of Noble Metal Catalysts - Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    National Nuclear Security Administration | (NNSA) Explores Peaceful Uses of Nuclear Explosions Atomic Energy Commission Explores Peaceful Uses of Nuclear Explosions Nevada Test Site, NV As part of the Plowshare program seeking to develop peaceful uses for nuclear explosives, the Atomic Energy Commission conducts the Sedan test at the Nevada Test Site Programs | National Nuclear Security Administration | (NNSA)

    Takes Over Responsibility for all Atomic Energy Programs Atomic Energy

  7. Intensive Sampling Of Noble Gases In Fluids At Yellowstone- I...

    Open Energy Info (EERE)

    I, Early Overview Of The Data, Regional Patterns Abstract The Roving Automated Rare Gas Analysis (RARGA) lab of Berkeley's Physics Department was deployed in Yellowstone...

  8. Atomic-Layer Deposition on Noble Metal Powders. (Conference)...

    Office of Scientific and Technical Information (OSTI)

    Authors: Robinson, David ; Cappillino, Patrick. ; Salloum, Maher N. ; Sugar, Joshua Daniel ; El Gabaly Marquez, Farid ; Sheridan, Leah B. ; Jagannathan, Kaushik ; Benson, David M. ...

  9. An electroless approach to atomic layer deposition on noble metal...

    Office of Scientific and Technical Information (OSTI)

    Abstract not provided. Authors: Cappillino, Patrick ; Robinson, David ; Sugar, Joshua Daniel ; El Gabaly Marquez, Farid ; Cai, Trevor ; Liu, Zhi ; Stickney, John Publication Date: ...

  10. Atomic-Layer Deposition on Noble Metal Powders

    Office of Scientific and Technical Information (OSTI)

    J. Cappillino, M. Salloum, J. D. Sugar, F. El Gabaly (Sandia) L. Sheridan, K. ... Georgia Maher Salloum Theorymodeling Farid El Gabaly XPS Leah Sheridan E-ALD films Now at ...

  11. Method for the purification of noble gases, nitrogen and hydrogen

    DOE Patents [OSTI]

    Baker, J.D.; Meikrantz, D.H.; Tuggle, D.G.

    1997-09-23

    A method and apparatus are disclosed for the purification and collection of hydrogen isotopes in a flowing inert gaseous mixture containing impurities, wherein metal alloy getters having the capability of sorbing non-hydrogen impurities such as oxygen, carbon dioxide, carbon monoxide, methane, ammonia, nitrogen and water vapor are utilized to purify the gaseous mixture of impurities. After purification hydrogen isotopes may be more efficiently collected. A plurality of parallel process lines utilizing metal getter alloys can be used to provide for the continuous purification and collection of the hydrogen isotopes. 15 figs.

  12. cs5b02062 1..13

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    T. Beckham* , National Bioenergy Center and Hydrogen and Transportation Systems Center, National Renewable Energy Laboratory, 15013 Denver West Parkway, Golden, ...

  13. CONNECTED LIGHTING SYSTEMS WORKSHOP HOTEL INFORMATION

    Broader source: Energy.gov [DOE]

    Workshop LocationHyatt Regency Santa Clara5101 Great America ParkwaySanta Clara, CA 95051408-200-1234

  14. A generic biokinetic model for noble gases with application to radon

    SciTech Connect (OSTI)

    Leggett, Richard Wayne; Marsh, James; Gregoratto, Demetrio; Blanchardon, Eric

    2013-01-01

    The International Commission for Radiological Protection (ICRP) currently uses a dose conversion coefficient to calculate effective dose per unit exposure to radon and its progeny. The coefficient is derived by dividing the detriment associated with unit exposure to radon, as estimated from epidemiological studies, by the detriment per unit effective dose, as estimated mainly from atomic bomb survivor data and animal studies. In a recent statement the ICRP indicated that future guidance on exposure to radon and its progeny will be developed in the same way as guidance for any other radionuclide. That is, intake of radon and progeny will be limited on the basis of effective dose coefficients derived from biokinetic and dosimetric models. This paper proposes a biokinetic model for systemic (absorbed) radon for use in the calculation of dose coefficients for inhaled or ingested radon. The model is based largely on physical laws governing transfer of a non-reactive and soluble gas between materials. Model predictions are shown to be consistent with results of controlled studies of the fate of internally deposited radon in human subjects.

  15. The miniCLEAN single-phase noble liquid dark mater experiment...

    Office of Scientific and Technical Information (OSTI)

    which observes scintillation light from a 150kg fiducial mass liquid argon target. This detector design strategy emphasizes scalability to target masses of order 10 tons or more. ...

  16. Collective photonic-plasmonic resonances in noble metal - dielectric nanoparticle hybrid arrays

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Hong, Yan; Reinhard, Bjrn M.

    2014-10-27

    Coherent scattering of gold and silver nanoparticles (NPs) in regular arrays can generate Surface Lattice Resonances (SLRs) with characteristically sharp spectral features. Herein, we investigate collective resonances in compositionally more complex arrays comprising NP clusters and NPs with different chemical compositions at pre-defined lattice sites. We first characterize the impact of NP clustering by exchanging individual gold NPs in the array through dimers of electromagnetically strongly coupled gold NPs. Then, we analyze hybrid arrays that contain both gold metal NP dimers and high refractive index dielectric NPs as building blocks. We demonstrate that the integration of gold NP clusters andmoredielectric NPs into one array enhances E-field intensities not only in the vicinity of the NPs but also in the ambient medium of the entire array. In addition, this work shows that the ability to integrate multiple building blocks with different resonance conditions in one array provides new degrees of freedom for engineering optical fields in the array plane with variable amplitude and phase.less

  17. The miniCLEAN single-phase noble liquid dark mater experiment...

    Office of Scientific and Technical Information (OSTI)

    provide a unique test of the expected A squared dependence of the WIMP interaction rate. ... Language: English Subject: 70 PLASMA PHYSICS AND FUSION TECHNOLOGY; ARGON; DESIGN; ...

  18. Cryogenic argon ionization chamber detector for analysis of radioactive noble gases. Master's thesis

    SciTech Connect (OSTI)

    Berggren, S.R.

    1982-03-01

    Two ionization chamber detectors, using liquid or solid argon as their medium were designed, constructed and tested as an improved means of analyzing quantitatively xenon 131m and xenon 133. Problems with the first detector, including vibrational noise and inadequate temperature control, limited its use to studies using solid argon. In the second design, many operating problems of the first detector were corrected. Properties of the detectors were studied using external gamma sources and xenon 131m dispersed inside the detector medium. The xenon sample and argon were purified and cryogenically pumped into the detector for spectral analysis. Both the purity of the argon and bias voltages affected resolution by changing the trapping distance of the electrons in the medium. Lower temperatures increased detection efficiency by condensing more of the sample into the cell. No clearly recognizable energy peak could be found in spectra from external or internal sources.

  19. Photo-induced strengthening of weak bonding in noble gas dimers

    SciTech Connect (OSTI)

    Miyamoto, Yoshiyuki; Miyazaki, Takehide; Rubio, Angel

    2014-05-19

    We demonstrate through extensive first-principles time-dependent density functional calculations that attractive van der Waals interaction between closed-shell atoms can be enhanced by light with constant spatial intensity. We illustrate this general phenomenon for a He dimer as a prototypical case of complex van der Waals interactions and show that when excited by light with a frequency close to the 1s → 2p He-atomic transition, an attractive force larger than 7 pN is produced. This force gain is manifested as a larger acceleration of He-He contraction under an optical field. The concerted dynamical motions of the He atoms together with polarity switching of the charge-induced dipole cause the contraction of the dimer. These findings are relevant for the photo-induced control of weakly bonded molecular species, either in gas phase or in solution.

  20. Noble reactions for the actinides: safe gold-based access to organouranium and azide complexes

    SciTech Connect (OSTI)

    Thomson, Robert K; Graves, Christopher R; Scott, Brian L; Kiplinger, Jaqueline L

    2008-01-01

    Gold has had a profound impact on organic chemistry; its compounds are spectacular catalysts for many organic transformations involving the formation of C-C, C-O, C-N and CoS bonds, and have enabled unprecedented pathways for the functionalization of C-H and C-C bonds. In general, gold complexes have not been exploited as reagents in organometallic or inorganic chemistry, although a few gold(l) aryl and alkynyl compounds have been reported to undergo transmetalation with transition metal complexes. We have been developing methods for functionalizing uranium complexes and have shown that Cu(l)-X reagents effect the oxidation of uranium with formation of U-X bonds, providing easy chemical control over uranium in oxidation states ranging from U{sup III}{yields}U{sup VI}. Although a logical approach for the direct generation of U-carbon and U-azide bonds, this Cu-based platform is limited in scope as it only works for pure and isolable copper compounds. This is problematic given the instability of organocuprates and copper azides, which can detonate violently as isolated solids. As such, this route has been confined to the synthesis of select uranium phenylacetylide complexes. Over the past few years, a variety of stable gold(l) alkyl, alkenyl, aryl, alkynyl, and azide complexes have been reported, propelling us to investigate their potential as reagents within the oxidative functionalization platform. Unlike the related CU{sup I} systems, Au{sup I} reagents are easily derivatized, and are safe to handle and isolate. Herein, we report that gold(l)-phosphine compounds can undergo a new class of reaction, and are excellent reagents for the oxidative functionalization of uranium with azide and carbon anions.

  1. Noble Gas Evidence For Two Fluids In The Baca (Valles Caldera...

    Open Energy Info (EERE)

    suggest a deeper source, possibly including gases escaping from a magma. Authors S. P. Smith and B. M. Kennedy Published Journal Geochimica et Cosmochimica Acta, 1985 DOI 10.1016...

  2. Hydrogen Isotope Separation From Noble Gasses in Plasma Exhausts and Other

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hydrogen Infrastructure Transition Analysis M. Melendez and A. Milbrandt Milestone Report NREL/TP-540-38351 January 2006 Hydrogen Infrastructure Transition Analysis M. Melendez and A. Milbrandt Prepared under Task No. HY55.2200 Milestone Report NREL/TP-540-38351 January 2006 National Renewable Energy Laboratory 1617 Cole Boulevard, Golden, Colorado 80401-3393 303-275-3000 * www.nrel.gov Operated for the U.S. Department of Energy Office of Energy Efficiency and Renewable Energy by Midwest

  3. Identifying low-coverage surface species on supported noble metal nanoparticle catalysts by DNP-NMR

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Johnson, Robert L.; Perras, Frédéric A.; Kobayashi, Takeshi; Schwartz, Thomas J.; Dumesic, James A.; Shanks, Brent H.; Pruski, Marek

    2015-11-20

    DNP-NMR spectroscopy has been applied to enhance the signal for organic molecules adsorbed on γ-Al2O3-supported Pd nanoparticles. In addition, by offering >2500-fold time savings, the technique enabled the observation of 13C-13C cross-peaks for low coverage species, which were assigned to products from oxidative degradation of methionine adsorbed on the nanoparticle surface.

  4. Identifying low-coverage surface species on noble metal nanoparticles by DNP-NMR

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Johnson, Robert L.; Perras, Frdric A.; Kobayashi, Takeshi; Schwartz, Thomas J.; Dumesic, James A.; Shanks, Brent H.; Pruski, Marek

    2015-11-20

    DNP-NMR spectroscopy has been applied to enhance the signal for organic molecules adsorbed on ?-Al2O3-supported Pd nanoparticles. In addition, by offering >2500-fold time savings, the technique enabled the observation of 13C-13C cross-peaks for low coverage species, which were assigned to products from oxidative degradation of methionine adsorbed on the nanoparticle surface.

  5. Identifying low-coverage surface species on supported noble metal nanoparticle catalysts by DNP-NMR

    SciTech Connect (OSTI)

    Johnson, Robert L.; Perras, Frdric A.; Kobayashi, Takeshi; Schwartz, Thomas J.; Dumesic, James A.; Shanks, Brent H.; Pruski, Marek

    2015-11-20

    DNP-NMR spectroscopy has been applied to enhance the signal for organic molecules adsorbed on ?-Al2O3-supported Pd nanoparticles. In addition, by offering >2500-fold time savings, the technique enabled the observation of 13C-13C cross-peaks for low coverage species, which were assigned to products from oxidative degradation of methionine adsorbed on the nanoparticle surface.

  6. Comments from

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Forest 3106 Pierce Parkway Suite D Springfield OR 97477 (541) 225-6348 khuddleston@fs.fed.us website: http:www.oregonfeb.usofebpagesofebsh aredneutrals.htm Workplace...

  7. DOE Publishes Notice of Public Meeting for Smart Grid-connected...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Time, in Golden, Colorado at the National Renewable Energy Laboratory (NREL), San Juan Room Conference Room, on the South Table Mountain Campus, 15013 Denver West Parkway,...

  8. Golden Field Office | Open Energy Information

    Open Energy Info (EERE)

    DOE Golden Field Office Abbreviation: DOE GFO Address: 15013 Denver West Parkway Place: Golden, Colorado Zip: 80401 Phone Number: 720-356-1800 ParentHolding Organization: US...

  9. Golden Field Office | Open Energy Information

    Open Energy Info (EERE)

    DOE Golden Field Office) Jump to: navigation, search Name: DOE Golden Field Office Abbreviation: DOE GFO Address: 15013 Denver West Parkway Place: Golden, Colorado Zip: 80401 Phone...

  10. Blue Sun Biodiesel LLC | Open Energy Information

    Open Energy Info (EERE)

    Biodiesel LLC Jump to: navigation, search Logo: Blue Sun Energy, Inc. Name: Blue Sun Energy, Inc. Address: 14143 Denver West Parkway Place: Golden, Colorado Zip: 80401 Region:...

  11. Verenium Corporation (Massachusetts) | Open Energy Information

    Open Energy Info (EERE)

    (Massachusetts) Jump to: navigation, search Name: Verenium Corporation Address: 55 Cambridge Parkway, 8th Floor Place: Cambridge, Massachusetts Zip: 02142 Region: Greater Boston...

  12. Sevin Rosen Funds (Texas - Austin) | Open Energy Information

    Open Energy Info (EERE)

    Austin) Jump to: navigation, search Name: Sevin Rosen Funds (Texas - Austin) Address: 6300 Bridgepoint Parkway, Building 1, Suite 500 Place: Austin, Texas Zip: 78730 Region: Texas...

  13. University of Tennessee | Open Energy Information

    Open Energy Info (EERE)

    Testing Facilities Name University of Tennessee Address University of Tennessee Space Center, 411 B.H. Goethert Parkway Place Tullahoma, Tennessee Zip 37388 Sector Hydro...

  14. Standard Solar | Open Energy Information

    Open Energy Info (EERE)

    Standard Solar Name: Standard Solar Address: 202 Perry Parkway Place: Gaithersburg, Maryland Zip: 20877 Region: Northeast - NY NJ CT PA Area Sector: Solar Product: Solar...

  15. NREL: Education Center - Events

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Education Center Printable Version Events Unless otherwise notified, events listed here will be held at the NREL Education Center, 15013 Denver West Parkway, Golden, CO. The...

  16. Management & Program Analyst

    Broader source: Energy.gov [DOE]

    Where would I be working? Western Area Power Administration, Corporate Services Office, Office of the Chief Financial Officer, Governance and Policy (A8500). 12155 West Alameda Parkway, Lakewood,...

  17. Lighthouse Solar Honolulu Hawaii | Open Energy Information

    Open Energy Info (EERE)

    Solar Honolulu Hawaii Address: 1040 Sand Island parkway Suite 100 Place: Honolulu, HI Zip: 96819 Sector: Solar Phone Number: (808) 783-0357 Website: www.lighthousesolar.com...

  18. A PUBLICATION FOR ALL MEMBERS OF THE NNSA/NV FAMILY Contents

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... Desert Research Institute; Grapevine Junction; Lockheed Martin Systems Management; ... Meeting begins at 6:00 p.m. Clark County Government Center, 500 Grand Central Parkway, Las ...

  19. QA Corporate Board Meeting - November 2008 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Meeting Location: Renaissance Concourse Hotel Atlanta Airport, One Hartsfield Centre, Parkway Atlanta, Georgia 30354 Room: Shannon One and Two Draft Agenda for November 13, 2008 ...

  20. HOTEL-CONNECTED LIGHTING SYSTEMS MEETING AND TECHNOLOGY DEVELOPMENT...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    MEETING AND TECHNOLOGY DEVELOPMENT WORKSHOP Portland Marriott Downtown Waterfront 1401 SW Naito Parkway Portland, OR 97201 1-877-901-6632 The room block reserved at the Portland...

  1. Archer Daniels Midland | Open Energy Information

    Open Energy Info (EERE)

    Daniels Midland Address: 4666 Faries Parkway Place: Decatur, IL Zip: 62526 Sector: Biofuels Product: turn crops into renewable products Phone Number: 800-637-5843 Website:...

  2. Interdisciplinary Civil/Electrical Engineer | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Office of the Chief Operating Officer, Design, Civil Engineering (A7920). 12155 West Alameda Parkway, Lakewood, CO 80228. Find out more about living conditions at this duty...

  3. USAJobs Search | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Office of the Chief Operating Officer, Design, Civil Engineering (A7920). 12155 West Alameda Parkway, Lakewood, CO 80228. Find out more about living conditions at this duty...

  4. USAJobs Search | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Office, Office of the Chief Operating Officer, Natural Resources (A7400). 12155 West Alameda Parkway, Lakewood, CO 80228. Duty location is non-negotiable; this position requires...

  5. USAJobs Search | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    information). Where would I be working? Western Area Power Administration 12155 W. Alameda Parkway Lakewood CO 80228 Find out more about living conditions at this duty station...

  6. USAJobs Search | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Corporate Services Office, Office of the Chief Financial Officer, Governance & Policy (A8500). 12155 West Alameda Parkway, Lakewood, CO 80228. Find out more about living conditions...

  7. USAJobs Search | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    of the Financial Officer, Financial Management, Financial Systems (A8230). 12155 West Alameda Parkway, Lakewood, CO 80228. Find out more about living conditions at this duty...

  8. USAJobs Search | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Services Office, Office of the Chief Operating Officer, Design, Civil Engineering (A7920). 12155 West Alameda Parkway, Lakewood, CO 80228. Find out more about living conditions...

  9. EMAB Meeting - May 2012 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ENVIRONMENTAL MANAGEMENT ADVISORY BOARD Hotel on the Falls 475 River Parkway * Idaho ... KB) EMAB Briefing on Capital Assets Projects and Operations Activities Presentation ...

  10. The physical nature of the phenomenon of positive column plasma constriction in low-pressure noble gas direct current discharges

    SciTech Connect (OSTI)

    Kurbatov, P. F.

    2014-02-15

    The essence of the positive-column plasma constriction for static (the diffusion mode) and dynamic ionization equilibrium (the stratificated and constricted modes) is analyzed. Two physical parameters, namely, the effective ionization rate of gas atoms and the ambipolar diffusion coefficient of electrons and ions, determine the transverse distribution of discharge species and affect the current states of plasma. Transverse constriction of the positive column takes place as the gas ionization level (discharge current) and pressure increase. The stratified mode (including the constricted one) is observed between the two adjacent types of self-sustained discharge phases when they coexist together at the same time or in the same place as a coherent binary mixture. In the case, a occurrence of the discharge phase with more high electron density presently involve a great decrease in the cross-section of the current channel for d.c. discharges. Additional physical factors, such as cataphoresis and electrophoresis phenomena and spatial gas density inhomogeneity correlated with a circulatory flow in d.c. discharges, are mainly responsible for the current hysteresis and partially constricted discharge.

  11. Sources of metals in the Porgera gold deposit, Papua New Guinea: Evidence from alteration, isotope, and noble metal geochemistry

    SciTech Connect (OSTI)

    Richards, J.P.; McCulloch, M.T.; Chappell, B.W. ); Kerrich, R. )

    1991-02-01

    The Porgera gold deposit is spatially and temporally associated with the Late Miocene, Mafic, alkalic, epizonal Porgera Intrusive Complex (PIC), located in the highlands of Papua New Guinea (PNG). The highlands region marks the site of a Tertiary age continent-island-arc collision zone, located on the northeastern edge of the Australasian craton. It is suggested that the hydrothermal fluids acquired their Sr and Pb isotopic signatures by interaction with, or direct derivation from, a plutonic root of the PIC and host sedimentary rocks of the Om Formation. It is likely that Au was also derived from one or both of these two sources. Concentrations of Au in unaltered igneous and sedimentary rocks from Porgera ({le}10 ppb Au) do not indicate that either lithology represents a significantly enriched protore, although Au and platinum-group element (PGE) abundances in the igneous rocks suggest a mild primary magmatic enrichment of Au relative to the PGE (average (Au/(Pt+Pd)) {sub mantle normalized} = 14.0 {plus minus} 6.5 (n = 8)). Evidence that the Porgera magmas were rich in volatiles permits speculation that Au may have been concentrated in a magmatic fluid phase, but alternative possibilities such as derivation of Au by hydrothermal leaching of solidified igneous materials or sedimentary rocks cannot be excluded at this time.

  12. TEST PROCEDURE VALIDATION TEST OF A DISCRIMINATING TRITIUM MONITOR FOR MEASURING TRITIUM OXIDE IN THE PRESENCE OF NOBLE GASES

    Office of Environmental Management (EM)

    Tribal Summit Secretary Steven Chu Remarks as Prepared for Delivery Thursday, May 5, 2011 Arlington, VA Good morning. Thank you all for joining us today, including those of you watching online. The Obama Administration is committed to strong engagement with Tribal Nations. As a sign of that commitment, you heard from Secretary Vilsack yesterday, and today you will also hear from Secretary Salazar, Administrator Jackson, and White House officials. When I started as Energy Secretary, I made a

  13. Determination of plasma frequency, damping constant, and size distribution from the complex dielectric function of noble metal nanoparticles

    SciTech Connect (OSTI)

    Mendoza Herrera, Luis J.; Arboleda, David Muetn; Schinca, Daniel C.; Scaffardi, Luca B.

    2014-12-21

    This paper develops a novel method for simultaneously determining the plasma frequency ?{sub P}?? and the damping constant ?{sub free} in the bulk damped oscillator Drude model, based on experimentally measured real and imaginary parts of the metal refractive index in the IR wavelength range, lifting the usual approximation that restricts frequency values to the UV-deep UV region. Our method was applied to gold, silver, and copper, improving the relative uncertainties in the final values for ?{sub p} (0.5%1.6%) and for ?{sub free} (3%8%), which are smaller than those reported in the literature. These small uncertainties in ?{sub p} and ?{sub free} determination yield a much better fit of the experimental complex dielectric function. For the case of nanoparticles (Nps), a series expansion of the Drude expression (which includes ?{sub p} and ?{sub free} determined using our method) enables size-dependent dielectric function to be written as the sum of three terms: the experimental bulk dielectric function plus two size corrective terms, one for free electron, and the other for bound-electron contributions. Finally, size distribution of nanometric and subnanometric gold Nps in colloidal suspension was determined through fitting its experimental optical extinction spectrum using Mie theory based on the previously determined dielectric function. Results are compared with size histogram obtained from Transmission Electron Microscopy (TEM)

  14. MERCURY-NITRITE-RHODIUM-RUTHENIUM INTERACTIONS IN NOBLE METAL CATALYZED HYDROGEN GENERATION FROM FORMIC ACID DURING NUCLEAR WASTE PROCESSING AT THE SAVANNAH RIVER SITE - 136C

    SciTech Connect (OSTI)

    Koopman, D.; Pickenheim, B.; Lambert, D.; Newell, J; Stone, M.

    2009-09-02

    Chemical pre-treatment of radioactive waste at the Savannah River Site is performed to prepare the waste for vitrification into a stable waste glass form. During pre-treatment, compounds in the waste become catalytically active. Mercury, rhodium, and palladium become active for nitrite destruction by formic acid, while rhodium and ruthenium become active for catalytic conversion of formic acid into hydrogen and carbon dioxide. Nitrite ion is present during the maximum activity of rhodium, but is consumed prior to the activation of ruthenium. Catalytic hydrogen generation during pre-treatment can exceed radiolytic hydrogen generation by several orders of magnitude. Palladium and mercury impact the maximum catalytic hydrogen generation rates of rhodium and ruthenium by altering the kinetics of nitrite ion decomposition. New data are presented that illustrate the interactions of these various species.

  15. Test Results For Physical Separation Of Tritium From Noble Gases And It’s Implications For Sensitivity And Accuracy In Air And Stack Monitoring

    Broader source: Energy.gov [DOE]

    Presentation from the 32nd Tritium Focus Group Meeting held in Germantown, Maryland on April 23-25, 2013.

  16. Synthesis of metal-metal oxide catalysts and electrocatalysts using a metal cation adsorption/reduction and adatom replacement by more noble ones

    DOE Patents [OSTI]

    Adzic, Radoslav; Vukmirovic, Miomir; Sasaki, Kotaro

    2010-04-27

    The invention relates to platinum-metal oxide composite particles and their use as electrocatalysts in oxygen-reducing cathodes and fuel cells. The invention particularly relates to methods for preventing the oxidation of the platinum electrocatalyst in the cathodes of fuel cells by use of these platinum-metal oxide composite particles. The invention additionally relates to methods for producing electrical energy by supplying such a fuel cell with an oxidant, such as oxygen, and a fuel source, such as hydrogen. The invention also relates to methods of making the metal-metal oxide composites.

  17. The Fundamental Role of Nano-Scale Oxide Films in the Oxidation of Hydrogen and the Reduction of Oxygen on Noble Metal Electrocatalysts

    SciTech Connect (OSTI)

    Digby Macdonald

    2005-04-15

    The derivation of successful fuel cell technologies requires the development of more effective, cheaper, and poison-resistant electrocatalysts for both the anode (H{sub 2} oxidation in the presence of small amounts of CO from the reforming of carbonaceous fuels) and the cathode (reduction of oxygen in the presence of carried-over fuel). The proposed work is tightly focused on one specific aspect of electrocatalysis; the fundamental role(s) played by nanoscale (1-2 nm thick) oxide (''passive'') films that form on the electrocatalyst surfaces above substrate-dependent, critical potentials, on charge transfer reactions, particularly at elevated temperatures (25 C < T < 200 C). Once the role(s) of these films is (are) adequately understood, we will then use this information to specify, at the molecular level, optimal properties of the passive layer for the efficient electrocatalysis of the oxygen reduction reaction.

  18. USCA Convocation Center 375 Robert ...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1, 2013 USCA Convocation Center 375 Robert M. Bell Parkway, Aiken, SC 29801 Cash Bar Reception 6:00-6:45 pm BanquetLecture 7:00 pm Tickets: 50 per person Must be...

  19. 2011 October Center Directory.pub

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Watt Way, VHE 309 ningfenh@usc.edu 213-740-0713 Gisele Ragusa, PhD, MS Department of Psychology in Education 3470 Trousdale Parkway, WPH 401 Los Angeles, Ca, 90089 ragusa@usc.edu...

  20. GreenCore Capital | Open Energy Information

    Open Energy Info (EERE)

    GreenCore Capital Jump to: navigation, search Logo: GreenCore Capital Name: GreenCore Capital Address: 10509 Vista Sorrento Parkway Place: San Diego, California Zip: 92121 Region:...

  1. Microsoft Word - Agenda_SSAB_Chairs_6-15-11.FINAL

    Office of Environmental Management (EM)

    Hosted by Nevada Site Specific Advisory Board DRAFT Agenda EM SSAB Chairs Meeting June 15 and 16, 2011 Aliante Station 7300 Aliante Parkway North Las Vegas, Nevada 89084 DAY 1 ...

  2. NCO Directory (by program)

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Efficiency and Renewable Energy (EERE) lori.gray@ee.doe.gov Energy Efficiency and ... West Parkway Golden, CO 80401 EERE Lori Gray Golden Field Office Page 1 NEPA Compliance ...

  3. NOTICE OF AVAILABILITY

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Lori Gray, 15013 Denver West Parkway, Golden, CO 80401, by fax to 720-356-1350, or by email to gonepa@ee.doe.gov. In addition, interested persons are invited to attend an ...

  4. CX-010246: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    South Table Mountain Denver West Parkway Improvements CX(s) Applied: A9, B1.33 Date: 03/21/2013 Location(s): Colorado Offices(s): Golden Field Office

  5. Connected Lighting Systems Workshop Venue and Hotel Information

    Broader source: Energy.gov [DOE]

    The Connected Lighting Systems Workshop will be held in the Grand Ballroom at the Hyatt Regency Santa Clara, 5101 Great America Parkway, Santa Clara, CA, 95051. The Hyatt Regency is connected to...

  6. EMAB Meeting - February 2011 | Department of Energy

    Office of Environmental Management (EM)

    Green Valley Ranch * La Sirena II 2300 Paseo Verde Parkway * Henderson, Nevada 89052 Documents Available for Download Meeting Minutes (416.13 KB) Meeting Agenda (50.35 KB) More ...

  7. Application to Export Electric Energy OE Docket No. EA-363-A...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    OE Docket No. EA-363-A Noble Americas Gas & Power Corporation Application from NAG&P to export electric energy to Mexico. PDF icon EA-363-A Noble Americas G&P (MX).pdf More...

  8. Application to Export Electric Energy OE Docket No. EA-364-A...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    4-A Noble Americas Gas & Power Corporation Application to Export Electric Energy OE Docket No. EA-364-A Noble Americas Gas & Power Corporation Application from NAG&P to export...

  9. In-situ Studies of the Reactions of Bifunctional and Heterocyclic Molecules over Noble Metal Single Crystal and Nanoparticle Catalysts Studied with Kinetics and Sum-Frequency Generation Vibrational Spectroscopy

    SciTech Connect (OSTI)

    Kliewer, Christopher J.

    2009-06-30

    Sum frequency generation surface vibrational spectroscopy (SFG-VS) in combination with gas chromatography (GC) was used in-situ to monitor surface bound reaction intermediates and reaction selectivities for the hydrogenation reactions of pyrrole, furan, pyridine, acrolein, crotonaldehyde, and prenal over Pt(111), Pt(100), Rh(111), and platinum nanoparticles under Torr reactant pressures and temperatures of 300K to 450K. The focus of this work is the correlation between the SFG-VS observed surface bound reaction intermediates and adsorption modes with the reaction selectivity, and how this is affected by catalyst structure and temperature. Pyrrole hydrogenation was investigated over Pt(111) and Rh(111) single crystals at Torr pressures. It was found that pyrrole adsorbs to Pt(111) perpendicularly by cleaving the N-H bond and binding through the nitrogen. However, over Rh(111) pyrrole adsorbs in a tilted geometry binding through the {pi}-aromatic orbitals. A surface-bound pyrroline reaction intermediate was detected over both surfaces with SFG-VS. It was found that the ring-cracking product butylamine is a reaction poison over both surfaces studied. Furan hydrogenation was studied over Pt(111), Pt(100), 10 nm cubic platinum nanoparticles and 1 nm platinum nanoparticles. The product distribution was observed to be highly structure sensitive and the acquired SFG-VS spectra reflected this sensitivity. Pt(100) exhibited more ring-cracking to form butanol than Pt(111), while the nanoparticles yielded higher selectivities for the partially saturated ring dihydrofuran. Pyridine hydrogenation was investigated over Pt(111) and Pt(100). The {alpha}-pyridyl surface adsorption mode was observed with SFG-VS over both surfaces. 1,4-dihydropyridine was seen as a surface intermediate over Pt(100) but not Pt(111). Upon heating the surfaces to 350K, the adsorbed pyridine changes to a flat-lying adsorption mode. No evidence was found for the pyridinium cation. The hydrogenation of the {alpha},{beta}-unsaturated aldehydes acrolein, crotonaldehyde, and prenal were investigated over Pt(111) and Pt(100). The selectivity for the hydrogenation of the C=C bond was found to depend on the number of methyl groups added to the bond. The adsorption modes of the three aldehydes were determined. The hydrogenation of crotonaldehyde was found to be nearly structure insensitive as the TOF and selectivity were very close to the same over Pt(111) and Pt(100). SFG-VS indicated identical surface intermediates over the two crystal faces during crotonaldehyde hydrogenation.

  10. California GAMA Special Study:Archival Data Conversion & Upload

    SciTech Connect (OSTI)

    Visser, A.; Eppich, G.; Bibby, R.; Singleton, M.; Hillegonds, D.; Moran, J.; Esser, B.

    2014-02-18

    LLNL has uploaded over 3000 tritium analyses and over 4000 noble gas analyses to the GeoTracker GAMA database.

  11. CX-100539 Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Incorporation of Solar Powered Safety Lights Along the Blue Ridge Parkway Award Number: DE-EE0006621 CX(s) Applied: B5.1 Federal Emergency Management Program Date: 07/28/2014 Location(s): NC Office(s): Golden Field Office

  12. CX-001060: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Denver West Parkway/Marriott Boulevard Intersection Improvements; National Renewable Energy Laboratory Tracking Number 09-044CX(s) Applied: B1.32Date: 02/23/2010Location(s): Lakewood, ColoradoOffice(s): Energy Efficiency and Renewable Energy, Golden Field Office

  13. PowerPoint Presentation

    National Nuclear Security Administration (NNSA)

    INDEPENDENCE AVE. 23rd STREET BLUE PARKWAY MAIN STREET B O T T S R D 140TH STREET BLUE RIDGE BLVD RED BRIDGE RD G R A N D V I E W R D VOLKER BLVD. UMKC ROCKHURST UNIVERSITY COUNTRY ...

  14. Leaders of DOE Environmental Management Advisory Group to Meet in North Las Vegas

    Broader source: Energy.gov [DOE]

    Nevada Site Office News - The Chairs and Vice-Chairs of the U.S. Department of Energy’s (DOE) Environmental Management (EM) Site-Specific Advisory Board (SSAB) will meet in North Las Vegas, Nevada, June 15-16, at Aliante Station Hotel located at 7300 Aliante Parkway.

  15. Leaders of DOE Environmental Management Advisory Group to Meet in Henderson

    Broader source: Energy.gov [DOE]

    The Chairs and Vice-Chairs of the U.S. Department of Energy’s (DOE) Environmental Management (EM) Site-Specific Advisory Board (SSAB) will meet in Henderson, NV, April 13-14, at Green Valley Ranch located at 2300 Paseo Verde Parkway.

  16. Maria Group Inc | Open Energy Information

    Open Energy Info (EERE)

    Group Inc Jump to: navigation, search Name: Maria Group Inc Place: Friendswood, Texas Zip: 77546 Sector: Wind energy Product: Holds patent to Noble Wind Turbine, a vertical axis...

  17. Stamford, Connecticut: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Registered Energy Companies in Stamford, Connecticut Clean Diesel Technologies Inc International Plasma Sales Group IPSG Natural State Research, Inc. Noble Americas...

  18. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... charge (3) inorganic, organic, physical, and analytical ... electro catalysis on noble metal films, leading to ... towards developing a framework through which solid ...

  19. Electrocatalysis in Alkaline Electrolytes - Research Overview...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    VA PDF icon amfc110811mukerjee.pdf More Documents & Publications Saving the Fuel Cell Dream: Making Non Noble Metal Electrocatalysts a Reality? Fuel Cells: Just a Dream...

  20. Wolf Wind Farm | Open Energy Information

    Open Energy Info (EERE)

    Deere Wind Energy Energy Purchaser Central Minnesota Municipal Power Agency Location Nobles County MN Coordinates 43.583385, -95.774567 Show Map Loading map......

  1. Missouri River Energy Services (MRES) Wind Farm (2002) | Open...

    Open Energy Info (EERE)

    Tom Wind Energy Purchaser MRES Worthington Public Utilities Location Worthington - Nobles County MN Coordinates 43.6659, -95.7493 Show Map Loading map......

  2. Operational and Environmental Monitoring Within a Three-Mile...

    Office of Legacy Management (LM)

    RADIUS OF PROJECT RULISON Prepared for: Noble Energy Inc. EnCana Oil & Gas (USA) Inc. ... 16 5.6.3 Gasoline, Diesel, and Motor Oil Constituent Results......

  3. Fairfield County, Connecticut: Energy Resources | Open Energy...

    Open Energy Info (EERE)

    Sales Group IPSG Levco Energy MissionPoint Capital Partners Natural State Research, Inc. New England Energy Management Inc Noble Americas NuPower LLC Ocenergy Opel International...

  4. Research and Development of Non-Spectroscopic MEMS-Based Sensor...

    Office of Scientific and Technical Information (OSTI)

    While mass spectrometry can readily detect noble gases - the helium leak detector is an obvious example - laser-based methods such as infrared (IR) or Raman spectroscopy are ...

  5. PERFORMANCE

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Jee Choi Kent Czechowski Cong Hou Chris McClanahan David S. Noble, Jr. Richard (Rich) Vuduc Salishan Conference on High-Speed Computing Gleneden Beach, Oregon -...

  6. Cleveland County, Oklahoma: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Veolia Energy Places in Cleveland County, Oklahoma Etowah, Oklahoma Lexington, Oklahoma Moore, Oklahoma Noble, Oklahoma Norman, Oklahoma Oklahoma City, Oklahoma Purcell, Oklahoma...

  7. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... Enhanced Bifunctional Oxygen Catalysis in Strained LaNiO3 Perovskites Petrie, Jonathan R. ... low temperature oxygen electro catalysis on noble metal films, leading to ...

  8. NETL F 451.1/1-1, Categorical Exclusion Designation Form

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    - Grantsburg, IL and Noble, IL FESCCStorage Division Bruce Brown A Nonconventional CO2-EOR Target in the Illinois Basin: Oil Reservoirs of the.. Project planning, data...

  9. DNA Origami Directed Self-Assembly of Discrete Silver Nanoparticle...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    DNA origami nanostructures were utilized as spatially addressable templates to organize noble-metal nanoparticles of silver and gold into well-defined discrete architectures ...

  10. Record of Categorical Exclusion (CS) Determination, Office of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Determination, Office of Electricity Delivery and Energy Reliability (OE): EA-363 Noble Americas Gas & Power Corporation Record of Categorical Exclusion (CS) Determination, ...

  11. Platinum-ruthenium-nickel alloy for use as a fuel cell catalyst

    DOE Patents [OSTI]

    Gorer, Alexander

    2003-01-01

    An improved noble metal alloy composition for a fuel cell catalyst, the alloy containing platinum, ruthenium, and nickel. The alloy shows methanol oxidation activity.

  12. Platinum-ruthenium-nickel alloy for use as a fuel cell catalyst

    DOE Patents [OSTI]

    Gorer, Alexander

    2004-04-20

    An improved noble metal alloy composition for a fuel cell catalyst, the alloy containing platinum, ruthenium, and nickel. The alloy shows methanol oxidation activity.

  13. Compound and Elemental Analysis At Yellowstone Region (Kennedy...

    Open Energy Info (EERE)

    not indicated DOE-funding Unknown References B. M. Kennedy, J. H. Reynolds, S. P. Smith (1988) Noble Gas Geochemistry In Thermal Springs Additional References Retrieved from...

  14. New Opportunities for Outer Solar System Science using Radioisotope

    Office of Scientific and Technical Information (OSTI)

    Opportunities for Outer Solar System Science using Radioisotope Electric Propulsion Noble, Robert J.; SLAC; Amini, Rashied; Beauchamp, Patricia M.; Caltech, JPL; Bennett, Gary...

  15. "Title","Creator/Author","Publication Date","OSTI Identifier...

    Office of Scientific and Technical Information (OSTI)

    New Opportunities for Outer Solar System Science using Radioisotope Electric Propulsion","Noble, Robert J.; SLAC; Amini, Rashied; Beauchamp, Patricia M.; Caltech, JPL; Bennett,...

  16. TITLE AUTHORS SUBJECT SUBJECT RELATED DESCRIPTION PUBLISHER AVAILABILI...

    Office of Scientific and Technical Information (OSTI)

    New Opportunities for Outer Solar System Science using Radioisotope Electric Propulsion Noble Robert J SLAC Amini Rashied Beauchamp Patricia M Caltech JPL Bennett Gary L Metaspace...

  17. Mass Production Cost Estimation for Direct H2 PEM Fuel Cell Systems...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... nickel, conductive metal borides, nitrides and ... niobium, rhodium, rare earth metals, and other noble ... Consequently, a multiplier on the yearly membrane demand ...

  18. mMass Production Cost Estimation for Direct H2 PEM Fuel Cell...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... nickel, conductive metal borides, nitrides and ... niobium, rhodium, rare earth metals, and other noble ... Consequently, a multiplier on the yearly membrane demand ...

  19. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... low temperature oxygen electro catalysis on noble metal films, leading to significant enhancements in bifunctional activity essential for fuel cells and Metal-air batteries. ...

  20. Enhanced Bifunctional Oxygen Catalysis in Strained LaNiO3 Perovskites...

    Office of Scientific and Technical Information (OSTI)

    low temperature oxygen electro catalysis on noble metal films, leading to significant enhancements in bifunctional activity essential for fuel cells and Metal-air batteries. ...

  1. SAND2008-6687

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    6687 Unlimited Release Printed October 2008 Computational Investigation of Noble Gas Adsorption and Separation by Nanoporous Materials Jeffery A. Greathouse, Mark D. Allendorf, and...

  2. Climate Zone 6A | Open Energy Information

    Open Energy Info (EERE)

    Morrison County, Minnesota Morton County, North Dakota Mower County, Minnesota Murray County, Minnesota Newaygo County, Michigan Nicollet County, Minnesota Nobles County,...

  3. Application to Export Electric Energy OE Docket No. EA-364-A...

    Broader source: Energy.gov (indexed) [DOE]

    Publications Application to Export Electric Energy OE Docket No. EA-363-A Noble Americas Gas & Power Corporation: Federal Register Notice, Volume 80, No. 42 - March 4, 2015...

  4. Record of Categorical Exclusion (CS) Determination, Office of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Noble Americas Gas & Power Corporation Record of Categorical Exclusion (CS) Determination, Office of Electricity Delivery and Energy Reliability (OE): EA-365 Centre Land Trading

  5. Sabine Parish, Louisiana: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    3 Climate Zone Subtype A. Places in Sabine Parish, Louisiana Converse, Louisiana Fisher, Louisiana Florien, Louisiana Many, Louisiana Noble, Louisiana Pleasant Hill,...

  6. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... Full Text Available August 2015 Preparation of Electron and X-Ray Transparent Inorganic ... Synthesis of nanostructured bimetallic noble metal powders using Atomic Layer Electroless ...

  7. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... Preparation of Electron and X-Ray Transparent Inorganic Particles for Analytical ... Synthesis of nanostructured bimetallic noble metal powders using Atomic Layer Electroless ...

  8. Dark matter search results from the PICO-60 CF 3 I bubble chamber...

    Office of Scientific and Technical Information (OSTI)

    ; Harris, O. ; Jin, M. ; Krauss, C. B. ; Lafrenire, M. ; Laurin, M. ; Lawson, I. ; Levine, I. ; Lippincott, W. H. ; Mann, E. ; Maurya, D. ; Mitra, P. ; Neilson, R. ; Noble, A. ...

  9. Dark matter search results from the PICO-60 CF3I bubble chamber...

    Office of Scientific and Technical Information (OSTI)

    C. ; Harris, O. ; Jin, M. ; Krauss, C. B. ; Lafreniere, M. ; Laurin, M. ; Lawson, I. ; Levine, I. ; Lippincott, W. H. ; Mann, E. ; Maurya, D. ; Mitra, Pitam ; Neilson, R. ; Noble, ...

  10. EC Publications

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (3308 downloads) Solar Energy Grid Integration Systems: Final Report of the Princeton ... (163) Computational Investigation of Noble Gas Adsorption and Separation by Nanoporous ...

  11. EC Publications

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Popular Downloads Solar Energy Grid Integration Systems: Final Report of the Florida ... (534) Computational Investigation of Noble Gas Adsorption and Separation by Nanoporous ...

  12. EC Publications

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (3308 downloads) Solar Energy Grid Integration Systems: Final Report of the Princeton ... Capturing CO2 via reactions in nanopores (387) Computational Investigation of Noble Gas ...

  13. EC Publications

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Popular Downloads Solar Energy Grid Integration Systems: Final Report of the Florida Solar ... (841) Computational Investigation of Noble Gas Adsorption and Separation by Nanoporous ...

  14. Worksheet

    U.S. Energy Information Administration (EIA) Indexed Site

    ... "MN","Mower",54819,"FPL Energy Mower County LLC",56424,"Mower County ... "MN","Nobles",55821,"Green Acres Breeze LLC",56590,"Green Acres ...

  15. The New Era: NOCs Reach Out for Resources Bob Fryklund, IHS Energy

    U.S. Energy Information Administration (EIA) Indexed Site

    supply and market impacts of US unconventional oil production growth Andrew Slaughter, Vice-President, Energy Insight, IHS Presentation to EIA 2013 Energy Conference June 18 th 2013 Washington, DC CONFIDENTIAL © 2013, All rights reserved, IHS CERA., 55 Cambridge Parkway, Cambridge, Massachusetts 02142 No portion of this presentation may be reproduced, reused or otherwise distributed in any form without prior written consent. Copyright © 2013HS Inc. All Rights Reserved. 1 Today's Themes * US

  16. Agenda20120921 | U.S. DOE Office of Science (SC)

    Office of Science (SC) Website

    Agenda September 21, 2012 Nuclear Science Advisory Committee (NSAC) NSAC Home Meetings NSAC Members Charges/Reports Charter .pdf file (78KB) NP Committees of Visitors Federal Advisory Committees NP Home Meetings Agenda September 21, 2012 Print Text Size: A A A FeedbackShare Page DOE/NSF Nuclear Science Advisory Committee Meeting September 21, 2012 Where: Hilton Washington DC North/Gaithersburg, Montgomery Ballroom, 620 Perry Parkway, Gaithersburg, Maryland 20877, 301-977-8900 Purpose/Topics:

  17. December 1, 2011 | U.S. DOE Office of Science (SC)

    Office of Science (SC) Website

    December 1, 2011 Nuclear Science Advisory Committee (NSAC) NSAC Home Meetings NSAC Members Charges/Reports Charter .pdf file (78KB) NP Committees of Visitors Federal Advisory Committees NP Home Meetings December 1, 2011 Print Text Size: A A A FeedbackShare Page DOE/NSF Nuclear Science Advisory Committee Meeting December 1, 2011 Where: Hilton Washington DC North/Gaithersburg, 620 Perry Parkway, Gaithersburg, MD. Phone Number: 301-977-8900 Purpose/Topics: Perspectives from Department of Energy and

  18. FESAC Agenda - February 2008 | U.S. DOE Office of Science (SC)

    Office of Science (SC) Website

    February 2008 Fusion Energy Sciences Advisory Committee (FESAC) FESAC Home Meetings Members Charges/Reports Charter .pdf file (266KB) FES Committees of Visitors Federal Advisory Committees FES Home Meetings FESAC Agenda - February 2008 Print Text Size: A A A FeedbackShare Page Fusion Energy Sciences Advisory Committee Meeting Gaithersburg Hilton 620 Perry Parkway, Gaithersburg 301-977-8900 February 19-20, 2008 Agenda Time Topic Speaker February 19 9:00 Meeting Agenda and Logistics Prof. Stewart

  19. FESAC Agenda - January 2009 | U.S. DOE Office of Science (SC)

    Office of Science (SC) Website

    January 2009 Fusion Energy Sciences Advisory Committee (FESAC) FESAC Home Meetings Members Charges/Reports Charter .pdf file (266KB) FES Committees of Visitors Federal Advisory Committees FES Home Meetings FESAC Agenda - January 2009 Print Text Size: A A A FeedbackShare Page Fusion Energy Sciences Advisory Committee Meeting Gaithersburg Hilton 620 Perry Parkway 301-977-8900 January 13, 2009 Time Duration Topic Speaker 8:00 5 Meeting Agenda and Logistics Professor Riccardo Betti, University of

  20. FESAC Agenda - July 2007 | U.S. DOE Office of Science (SC)

    Office of Science (SC) Website

    July 2007 Fusion Energy Sciences Advisory Committee (FESAC) FESAC Home Meetings Members Charges/Reports Charter .pdf file (266KB) FES Committees of Visitors Federal Advisory Committees FES Home Meetings FESAC Agenda - July 2007 Print Text Size: A A A FeedbackShare Page Fusion Energy Sciences Advisory Committee Meeting Gaithersburg Hilton 620 Perry Parkway, Gaithersburg July 16-17, 2007 AGENDA Date/Time Topic Speaker July 16 09:00 Meeting Agenda and Logistics Professor Stewart Prager, FESAC Chair

  1. FESAC Agenda - October 2007 | U.S. DOE Office of Science (SC)

    Office of Science (SC) Website

    October 2007 Fusion Energy Sciences Advisory Committee (FESAC) FESAC Home Meetings Members Charges/Reports Charter .pdf file (266KB) FES Committees of Visitors Federal Advisory Committees FES Home Meetings FESAC Agenda - October 2007 Print Text Size: A A A FeedbackShare Page Fusion Energy Sciences Advisory Committee Meeting Gaithersburg Hilton 620 Perry Parkway, Gaithersburg October 23-24, 2007 Agenda Time Topic Speaker October 23 8:30 Meeting Agenda and Logistics Prof. Stewart Prager, UWisc,

  2. Award No. DE-FC36-10GO10589, Federal Assistance Reporting Checklist

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    DE-FG36-10GO10589 2. Program/Project Title: Viability Demonstration of Alternative Energy Systems in High Population Density Environments. 3. Recipient: 212 Degrees Consulting, LLC, 3960 Howard Hughes Parkway, Suite 500, Las Vegas, NV, 89169. 702-990-3954 4. Reporting Requirements: A. MANAGEMENT REPORTING Progress Report Special Status Report B. SCIENTIFIC/TECHNICAL REPORTING (Reports/Products must be submitted with appropriate DOE F 241. The 241 forms are available at www.osti.gov/elink.)

  3. Variability in Measured Space Temperatures in 60 Homes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Variability in Measured Space Temperatures in 60 Homes David Roberts National Renewable Energy Laboratory Kerylyn Lay EnerNOC (formerly of the National Renewable Energy Laboratory) Technical Report NREL/TP-5500-58059 March 2013 NREL is a national laboratory of the U.S. Department of Energy, Office of Energy Efficiency & Renewable Energy, operated by the Alliance for Sustainable Energy, LLC. National Renewable Energy Laboratory 15013 Denver West Parkway Golden, Colorado 80401 303-275-3000 *

  4. Waste-to-Energy: Hawaii and Guam Energy Improvement Technology Demonstration Project

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    8GO28308 National Renewable Energy Laboratory 15013 Denver West Parkway Golden, CO 80401 303-275-3000 * www.nrel.gov Waste-to-Energy Hawaii and Guam Energy Improvement Technology Demonstration Project J. Davis, R. Gelman, G. Tomberlin, and R. Bain National Renewable Energy Laboratory Technical Report NREL/TP-7A40-60868 March 2014 Produced under direction of Naval Facilities Engineering Command (NAVFAC) by the National Renewable Energy Laboratory (NREL) under Interagency Agreement 11-01829 and

  5. Meetings | U.S. DOE Office of Science (SC)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Meetings Nuclear Science Advisory Committee (NSAC) NSAC Home Meetings NSAC Members Charges/Reports Charter .pdf file (78KB) NP Committees of Visitors Federal Advisory Committees NP Home Meetings Print Text Size: A A A FeedbackShare Page Currently Scheduled NSAC Meetings Next NSAC Meeting October 28, 2016, Hilton Washington DC North/Gaithersburg, 620 Perry Parkway, Gaithersburg, Maryland If you have not yet registered for this webcast, please CLICK HERE External link for free registration Past

  6. Amendment 1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1 Date: 6/30/2016 ISSUED BY: National Renewable Energy Laboratory 15013 Denver West Parkway Golden, CO 80401 PROJECT NAME & LOCATION Service and Preventive Maintenance Agreement for Standby Power Generators The above numbered solicitation is amended as set forth below. The hour and date specified for receipt of offers [XX ] is not extended. [] is extended to OFFERORS ARE ADVISED TO ACKNOWLEDGE THIS AMENDMENT IN THEIR PROPOSAL. FAILURE TO ACKNOWLEDGE THIS AMENDMENT MAY RESULT IN REJECTION OF

  7. Amendment 2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 Date: 7/25/2016 ISSUED BY: National Renewable Energy Laboratory 15013 Denver West Parkway Golden, CO 80401 PROJECT NAME & LOCATION Service and Preventive Maintenance Agreement for Standby Power Generators The above numbered solicitation is amended as set forth below. The hour and date specified for receipt of offers [] is not extended. [x] is extended to August 3, 2016. OFFERORS ARE ADVISED TO ACKNOWLEDGE THIS AMENDMENT IN THEIR PROPOSAL. FAILURE TO ACKNOWLEDGE THIS AMENDMENT MAY RESULT IN

  8. Fuel Cell Buses in U.S. Transit Fleets: Current Status 2012

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fuel Cell Buses in U.S. Transit Fleets: Current Status 2012 Leslie Eudy National Renewable Energy Laboratory Kevin Chandler Battelle Christina Gikakis Federal Transit Administration Technical Report NREL/TP-5600-56406 November 2012 NREL is a national laboratory of the U.S. Department of Energy, Office of Energy Efficiency & Renewable Energy, operated by the Alliance for Sustainable Energy, LLC. National Renewable Energy Laboratory 15013 Denver West Parkway Golden, Colorado 80401 303-275-3000

  9. Evaluation of the Effective Moisture Penetration Depth Model for Estimating Moisture Buffering in Buildings

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Evaluation of the Effective Moisture Penetration Depth Model for Estimating Moisture Buffering in Buildings J. Woods, J. Winkler, and D. Christensen National Renewable Energy Laboratory Technical Report NREL/TP-5500-57441 January 2013 NREL is a national laboratory of the U.S. Department of Energy, Office of Energy Efficiency & Renewable Energy, operated by the Alliance for Sustainable Energy, LLC. National Renewable Energy Laboratory 15013 Denver West Parkway Golden, Colorado 80401

  10. Built Environment Analysis Tool: April 2013

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Built Environment Analysis Tool April 2013 C. Porter Cambridge Systematics, Inc. Cambridge, Massachusetts NREL Technical Monitor: Laura Vimmerstedt Subcontract Report NREL/SR-6A20-58552 May 2013 NREL is a national laboratory of the U.S. Department of Energy, Office of Energy Efficiency & Renewable Energy, operated by the Alliance for Sustainable Energy, LLC. National Renewable Energy Laboratory 15013 Denver West Parkway Golden, Colorado 80401 303-275-3000 * www.nrel.gov Contract No.

  11. December 3, 2014 SEAB Meeting | Department of Energy

    Energy Savers [EERE]

    December 3, 2014 SEAB Meeting December 3, 2014 SEAB Meeting December 3, 2014 - 2:06pm Addthis National Renewable Energy Laboratory (NREL) Educational Center 15013 Denver West Parkway | Golden, CO Download Meeting Minutes Agenda 9:00 AM Opening Remarks Deputy Secretary Elizabeth Sherwood-Randall 9:15 AM Comments from SEAB Leadership John Deutch, Chair and Arun Majumdar, Vice Chair 9:30 AM Updates from SEAB Task Force Chairs Albert Carnesale - Nuclear Nonproliferation Task Force John Deutch -

  12. IEA Wind Task 26: The Past and Future Cost of Wind Energy, Work Package 2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    IEA Wind Task 26 WP2 The Past and Future Cost of Wind Energy Leading Authors Eric Lantz: National Renewable Energy Laboratory Ryan Wiser: Lawrence Berkeley National Laboratory Maureen Hand: National Renewable Energy Laboratory NREL is a national laboratory of the U.S. Department of Energy, Office of Energy Efficiency & Renewable Energy, operated by the Alliance for Sustainable Energy, LLC. National Renewable Energy Laboratory 15013 Denver West Parkway Golden, Colorado 80401 303-275-3000 *

  13. http://www.hanford.gov/boards/hab/response/054.htm

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    54 From: John D. Wagoner Ms. Merilyn B. Reeves, Chair Hanford Advisory Board 723 The Parkway, Suite 200 Richland, Washington 99352 March 3, 1998 Dear Merilyn Reeves: HANFORD ADVISORY BOARD (HAB) ADVICE ON TANK WASTE REMEDIATION SYSTEM (TWRS) VADOSE ZONE In response to your letter to me, "TWRS Vadose Zone Characterization," dated December 5, 1997, HAB Consensus Advice #83, on Vadose Zone Characterization needed to support the overall mission of the TWRS Program, the U. S. Department of

  14. http://www.hanford.gov/boards/hab/response/072.htm

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 From: John D. Wagoner, Tom Fitzsimmons, and Chuck Clarke Ms. Merilyn Reeves, Chair Hanford Advisory Board 723 The Parkway, Suite 200 Richland, Washington 99352 Dear Ms. Reeves: BOARD CONSENSUS ADVICE #72: PROPOSED TRI-PARTY AGREEMENT (TPA) MODIFICATIONS; K BASINS SPENT NUCLEAR FUEL PROJECT (M-34-OOA), JULY 11, 1997 We appreciate the time taken by you and other members of the Hanford Advisory Board (the Board) in reviewing and commenting on the agencies' proposed modifications to the TPA

  15. http://www.hanford.gov/boards/hab/response/073.htm

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3 From: John D. Wagoner, Tom Fitzsimmons, and Chuck Clarke Ms. Merilyn Reeves, Chair Hanford Advisory Board 723 The Parkway, Suite 200 Richland, Washington 99352 Dear Ms. Reeves: BOARD CONSENSUS ADVICE #73: PROPOSED TRI-PARTY AGREEMENT (TPA) MODIFICATIONS FOR DISPOSITION OF HANFORD SURPLUS REACTORS (M-93-00), JULY 11, l997 Thank you very much for your recent Board consensus advice and support, regarding the agencies' proposed TPA modifications covering the U.S. Department of Energy's reactors on

  16. http://www.hanford.gov/boards/hab/response/082.htm

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 From: John D. Wagoner, Tom Fitzsimmons, and Chuck Clarke Ms. Merilyn Reeves, Chair Hanford Advisory Board 723 The Parkway, Suite 200 Richland, Washington 99352 Dear Ms. Reeves: BOARD CONSENSUS ADVICE #82: PROPOSED TRI-PARTY AGREEMENT (TPA) COMMITMENTS ON THE 200 AREAS ENVIRONMENTAL RESTORATION SOIL REMEDIATION STRATEGY, DECEMBER 5, The Tri-Party agencies have reviewed the consensus advice provided by the Hanford Advisory Board on December 5, 1997. The agencies thank you for the advice and

  17. http://www.hanford.gov/boards/hab/response/083.htm

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3 From: John D. Wagoner Ms. Merilyn B. Reeves, Chair Hanford Advisory Board 723 The Parkway, Suite 200 Richland, Washington 99352 March 3, 1998 Dear Merilyn Reeves: HANFORD ADVISORY BOARD (HAB) ADVICE ON TANK WASTE REMEDIATION SYSTEM (TWRS) VADOSE ZONE In response to your letter to me, "TWRS Vadose Zone Characterization," dated December 5, 1997, HAB Consensus Advice #83, on Vadose Zone Characterization needed to support the overall mission of the TWRS Program, the U. S. Department of

  18. http://www.hanford.gov/boards/hab/response/086.htm

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    6 From: Jay Rhoderick and Martha Crosland Ms. Merilyn Reeves, Chair Hanford Advisory Board 723 The Parkway, Suite 200 Richland, Washington 99352 December 10, 1998 Dear Ms. Reeves: Thank you for your letter of September 11, 1998, regarding Intersite Waste Disposal. Your letter provided consensus advice from the Hanford Advisory Board (HAB) regarding a request from Site- Specific Advisory Board (SSAB) participants at an August 1998 Nevada Low-Level Waste (LLW) Workshop. At that workshop, SSAB

  19. http://www.hanford.gov/boards/hab/response/089.htm

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    9 From: Karen Randolph Ms. Merilyn Reeves, Chair Hanford Advisory Board 723 The Parkway, Suite 200 Richland, Washington 99352 January 14, 1999 Dear Ms. Reeves: This letter is in response to your Hanford Advisory Board letter of advice regarding openness at Hanford, Advice Letter #89 to John Wagoner, RL Manager, and Ralph Lightner, DOE Headquarters, dated December 4, 1998. We appreciate your support for the Hanford Openness Workshops' (HOW) recommendations to the DOE Richland Operations Office

  20. http://www.hanford.gov/boards/hab/response/090-2.htm

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Jackson Kinzer Ms. Merilyn Reeves, Chair Hanford Advisory Board 723 The Parkway, Suite 200 Richland, Washington 99352 February 10, 1999 Dear Ms. Reeves: HANFORD ADVISORY BOARD (HAB) ADVICE #90 CONCERNING THE TANK WASTE TREATMENT CONTRACT, HANFORD FEDERAL FACILITY AGREEMENT AND CONSENT ORDER (TRI-PARTY AGREEMENT) MILESTONES, FINANCING AND FUNDING Thank you for your continuing interest and support in Hanford's tank waste treatment program. Clearly, this complex and expensive cleanup project will

  1. http://www.hanford.gov/boards/hab/response/090.htm

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Tom Fitzsimmons Ms. Merilyn Reeves, Chair Hanford Advisory Board 723 The Parkway, Suite 200 Richland, Washington 99352 January 5, 1999 Dear Ms. Reeves: RE: Hanford Advisory Board Consensus Advice #90 dated December 4 1998. Thank you for your December 4, l998 letter to Assistant Secretary Owendoff, John Wagoner, and me regarding the Department of Energy's (USDOE's) Hanford tank waste treatment contract, and associated Tri-Party Agreement financing and funding considerations. I share the Board's

  2. http://www.hanford.gov/boards/hab/response/091.htm

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1 Ms. Merilyn Reeves, Chair Hanford Advisory Board 723 The Parkway, Suite 200 Richland, Washington 99352 May 3, 1999 Dear Ms. Reeves: RE: Hanford Advisory Board Consensus Advice #91 dated February 12, 1999. Your letter of February 12 raises many issues that have long been of concern to Ecology and EPA. We share your concern that DOE move forward in characterizing wastes within tank 241-Z-361, and that it develop and approve a comprehensive, facility wide baseline for Plutonium Finishing Plant

  3. http://www.hanford.gov/boards/hab/response/092.htm

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 From: Mike Wilson Ms. Merilyn Reeves, Chair Hanford Advisory Board 723 The Parkway, Suite 200 Richland, Washington 99352 April 29, 1999 Dear Ms. Reeves: RE: Hanford Advisory Board Consensus Advice #92. The Department of Ecology appreciates the Hanford Advisory Board's dedication to this important issue. We agree that the Board's recommendations are consistent with Tri-Party Agreement requirements. As outlined in the Tri-Party Agreement Community Relations Plan, Ecology continues to work toward

  4. http://www.hanford.gov/boards/hab/response/092a.htm

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    99352 99-OEA-105 Advice # 92 From: Lloyd Piper for Keith Klein Ms. Merilyn Reeves, Chair Hanford Advisory Board 723 The Parkway, Suite 200: B1 -41 Richland, Washington 99352 May 21, 1999 Dear Ms. Reeves: HANFORD ADVISORY BOARD CONSENSUS ADVICE #92 TRI-PARTIES RESPONSE TO PUBLIC COMMENTS Thank you for your recent advice regarding responses to public comments, concerns, and suggestions. They are good suggestions, and provide us with an improved framework for responding to comments and concerns

  5. http://www.hanford.gov/boards/hab/response/093.htm

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    8, 1999 Advice # 93 From: Tom Fitzsimmons, Dick French, and Chuck Clarke Ms. Merilyn Reeves, Chair Hanford Advisory Board 723 The Parkway, Suite 200 Richland, Washington 99352 Dear Ms. Reeves: RE: Hanford Advisory Board Consensus Advice #93 dated March 26, 1999 We appreciate the Hanford Advisory Board's (HAB) continuing efforts to bring our agencies together to negotiate Tri-Party Agreement (TPA) commitments governing Hanford's tank waste program. As you know, efforts to initiate negotiations

  6. http://www.hanford.gov/boards/hab/response/094.htm

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    4 From: Chuck Clarke and Tom Fitzsimmons Ms. Merilyn Reeves, Chair Hanford Advisory Board 723 The Parkway, Suite 200 Richland, Washington 99352 May 4, 1999 Dear Ms. Reeves: Thank you for transmitting the Hanford Advisory Board's advice on the Richland Operations Office proposed Fiscal Year 2001 budget and integrated priority list. As always, we appreciate the degree of effort individual Board members and the Board as a whole has put into the annual budget advice. We believe the Board can be

  7. http://www.hanford.gov/boards/hab/response/095.htm

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    5 From: Carolyn L. Huntoon Ms. Merilyn Reeves, Chair Hanford Advisory Board 723 The Parkway, Suite 200 Richland, Washington 99352 August 9, 1999 Dear Ms. Reeves: In your letter of June 4, 1999, to James Owendoff, you requested that the Hanford Advisory Board (HAB) provide expert panelists to participate in the alternative financing and contracting mechanisms analysis for the Hanford Tank Waste Remediation Systems (TWRS). By Public Law 105-62, the Congress provided $35 million for external

  8. http://www.hanford.gov/boards/hab/response/097.htm

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    PRO-759 Advice # 97 From: Keith A. Klein Ms. Merilyn Reeves, Chair Hanford Advisory Board 723 The Parkway, Suite 200: B1 -41 Richland, Washington 99352 September 9, 1999 Dear Ms. Reeves: HANFORD ADVISORY BOARD (HAB) CONSENSUS ADVICE #97 TO THE U.S. DEPARTMENT OF ENERGY, RICHLAND OPERATIONS OFFICE (RL) - PROJECT HANFORD MANAGEMENT CONTRACT (PHMC) PERFORMANCE MEASURES Thank you for the input contained in HAB Consensus Advice #97 dated July 16, 1999. The advice has been useful and I believe you

  9. http://www.hanford.gov/boards/hab/response/099.htm

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    9 From: Tom Fitzsimmons Ms. Merilyn Reeves, Chair Hanford Advisory Board 723 The Parkway Suite 200 Richland, Washington 99352 October 12, 1999 Dear Ms. Reeves: This letter is in reference to the Hanford Advisory Board Consensus Advice #99, dated September 10, 1999. I would like to thank both you and Board members for continuing to urge Ecology, the Department of Energy and the Environmental Protection Agency to reach agreement on enforceable milestones designed to effectively govern the

  10. http://www.hanford.gov/boards/hab/response/100-2.htm

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Michael F. Gearheard Ms. Merilyn Reeves, Chair Hanford Advisory Board 723 The Parkway, Suite 200 Richland, Washington 99352 November 10, 1999 Dear Ms Reeves: Thank you for the advice regarding how the agencies respond to Hanford Advisory Board advice. In your letter you raise three key points that the U.S. Environmental Protection Agency (EPA) would like to address. First, EPA agrees with your point regarding the need to continue providing written responses. As we stated in response to advice

  11. http://www.hanford.gov/boards/hab/response/100.htm

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Tom Fitzsimmons Ms. Merilyn Reeves, Chair Hanford Advisory Board 723 The Parkway Suite 200 Richland, Washington 99352 September 27, 1999 Dear Merilyn: Perhaps it is appropriate that Hanford Advisory Board Advice #100 is, in large measure, a reaffirmation of the understanding we, the other Tri-Party Agencies and the Board members reached nearly six years ago. With all the changes we have seen surrounding Hanford cleanup, a reaffirmation of our working relationship is welcome. When the Board

  12. http://www.hanford.gov/boards/hab/response/104.htm

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    IPI-143 Advice # 104 From: Marla K. Marvin Ms. Merilyn Reeves, Chair Hanford Advisory Board 723 The Parkway, Suite 200: B1 -41 Richland, Washington 99352 Dear Ms. Reeves: HANFORD ADVISORY BOARD (HAB) CONSENSUS ADVICE #104 This letter is in response to the HAB's advice regarding openness at Hanford to Carolyn Huntoon, DOE Headquarters, Keith Klein, RL Manager, and Dick French, ORP Manager, dated February 4, 2000 (Advice Letter #104). The advice letter was a follow up to the discussion at the

  13. http://www.hanford.gov/boards/hab/response/107.htm

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    065 Advice # 107 From: Richard T. French Ms. Merilyn B. Reeves, Chair Hanford Advisory Board 723 The Parkway, Suite 200: B1 -41 Richland, Washington 99352 Dear Ms. Reeves: RESPONSE TO COMMENTS ON HANFORD ADVISORY BOARD (HAB) CONSENSUS ADVICE #107 This letter and its attachments are in response to Advice #107 to the U.S. Department of Energy, Office of River Protection (ORP) on its Fiscal Year (FY) 2002 Integrated Priority List (IPL). We appreciate your participation in the FY 2002 budget

  14. http://www.hanford.gov/boards/hab/response/108.htm

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    136 Advice # 108 From: Harry L. Boston Ms. Merilyn B. Reeves, Chair Hanford Advisory Board 723 The Parkway, Suite 200; B1 -41 Richland, Washington 99352 Dear Ms. Reeves: RESPONSE TO HANFORD ADVISORY BOARD (HAB) CONSENSUS ADVICE #108, Thank you for your June 2, 2000 letter (Reference), expressing your viewpoints on making contractor information available to the public on the River Protection Project (RPP). This is of particular interest at this time with the recent solicitation for the design,

  15. http://www.hanford.gov/boards/hab/response/110.htm

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    10 From: Carolyn L. Huntoon Ms. Merilyn B. Reeves Chair, Hanford Advisory Board 723 Parkway; Suite 2000 Richland, WA 99352 Dear Ms. Reeves: Thank you for your letter dated June 2, 2000, expressing concerns of the Hanford Advisory Board with my memorandum dated May 2, 2000, regarding the delegation of approval authority for environmental restoration decision documents. As always, I appreciate your Board's advice on issues affecting the environmental cleanup at Hanford. I would like to clarify the

  16. http://www.hanford.gov/boards/hab/response/111.htm

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1 From: Tom Fitzsimmons September 25, 2000 Ms Merilyn Reeves, Chair Hanford Advisory Board 723 The Parkway, Suite 200 Richland, WA 99352 Dear Ms. Reeves: Thank you for your letter transmitting Hanford Advisory Board Consensus Advice # 111. The advice deals with the Department of Energy's contractor performance agreements. As this advice is directed primarily to the Department of Energy, let me simply express our appreciation for the Board's hard work and attention to this issue. We are grateful

  17. SOUTHEASTERN FEDERAL POWER ALLIANCE - October 9, 2013 | Department of

    Office of Environmental Management (EM)

    Energy October 9, 2013 SOUTHEASTERN FEDERAL POWER ALLIANCE - October 9, 2013 Southeastern Federal Power Alliance meeting was held on October 9, 2013 at the Municipal Electric Authority of Georgia (MEAG) located at 1470 Riveredge Parkway NW, Atlanta, Georgia. Documents Available for Download Southeastern Federal Power Alliance Meeting Agenda (18.16 KB) Bonham - Introduction to MEAG Power (39.01 KB) Coffman - APPA and Federal Hydro (36.18 KB) Coffman Handout - WRDA Letter to Boxer and Vitter -

  18. Secretary of Energy Advisory Board Public Meeting Committee Members: John Deutch, Chair; Arun Majumdar, Vice Chair; Rafael Bras; Albert Carnesale;

    Broader source: Energy.gov (indexed) [DOE]

    Arun Majumdar, Vice Chair; Rafael Bras; Albert Carnesale; Deborah Jin; Paul Joskow (via teleconference); Michael McQuade; Richard Meserve; and Dan Reicher Date and Time: December 3, 2014, 9:00 AM - 12:15 PM MST Location: National Renewable Energy Laboratory (NREL) Education Center 15013 Denver West Parkway, Golden, CO Purpose: Meeting of the Secretary of Energy Advisory Board (SEAB) SEAB Staff: Karen Gibson, Designated Federal Officer; Corey Williams-Allen, Deputy Designated Federal Officer;

  19. Two SBIR Grants Awarded for SSL Technology (FY12 Phase I Release 3) |

    Broader source: Energy.gov (indexed) [DOE]

    SYNTHESIS OF OPERATIONAL MITIGATION STUDIES TO REDUCE BAT FATALITIES AT WIND ENERGY FACILITIES IN NORTH AMERICA Prepared for: The National Renewable Energy Laboratory 15013 Denver West Parkway Golden, CO 80401 Prepared by: Edward B. Arnett 1 , Gregory D. Johnson 2 , Wally P. Erickson 2 , and Cris D. Hein 3 1 Theordore Roosevelt Conservation Partnership 2 Western EcoSystems Technology, Inc. 3 Bat Conservation International March 2013 CITATION Arnett, E. B., G. D. Johnson, W. P. Erickson, and C.

  20. Analysis of Cycling Costs in Western Wind and Solar Integration Study

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Analysis of Cycling Costs in Western Wind and Solar Integration Study Gary Jordan and Sundar Venkataraman GE Energy Schenectady, New York NREL Technical Monitor: Debra Lew Subcontract Report NREL/SR-5500-54864 June 2012 NREL is a national laboratory of the U.S. Department of Energy, Office of Energy Efficiency & Renewable Energy, operated by the Alliance for Sustainable Energy, LLC. National Renewable Energy Laboratory 15013 Denver West Parkway Golden, Colorado 80401 303-275-3000 *

  1. Assessment of the U.S. Department of Energy's Home Energy Scoring Tool

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Assessment of the U.S. Department of Energy's Home Energy Scoring Tool David Roberts, Noel Merket, Ben Polly, Mike Heaney, Sean Casey, and Joseph Robertson National Renewable Energy Laboratory Technical Report NREL/TP-5500-54074 July 2012 NREL is a national laboratory of the U.S. Department of Energy, Office of Energy Efficiency & Renewable Energy, operated by the Alliance for Sustainable Energy, LLC. National Renewable Energy Laboratory 15013 Denver West Parkway Golden, Colorado 80401

  2. An Evaluation of the Total Cost of Ownership of Fuel Cell-Powered Material Handling Equipment

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    An Evaluation of the Total Cost of Ownership of Fuel Cell- Powered Material Handling Equipment Todd Ramsden National Renewable Energy Laboratory Technical Report NREL/TP-5600-56408 April 2013 NREL is a national laboratory of the U.S. Department of Energy, Office of Energy Efficiency & Renewable Energy, operated by the Alliance for Sustainable Energy, LLC. National Renewable Energy Laboratory 15013 Denver West Parkway Golden, Colorado 80401 303-275-3000 * www.nrel.gov Contract No.

  3. RM12-2703 Advanced Rooftop Unit Control Retrofit Kit Field Demonstration: Hawaii and Guam Energy Improvement Technology Demonstration Project

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    8GO28308 National Renewable Energy Laboratory 15013 Denver West Parkway Golden, CO 80401 303-275-3000 * www.nrel.gov RM12-2703 Advanced Rooftop Unit Control Retrofit Kit Field Demonstration Hawaii and Guam Energy Improvement Technology Demonstration Project I. Doebber, J. Dean, J. Dominick, and G. Holland Produced under direction of Naval Facilities Engineering Command (NAVFAC) by the National Renewable Energy Laboratory (NREL) under Interagency Agreement 11-01829 Technical Report

  4. Twin Groves Wind Energy Facility Cut-in Speeds

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    SYNTHESIS OF OPERATIONAL MITIGATION STUDIES TO REDUCE BAT FATALITIES AT WIND ENERGY FACILITIES IN NORTH AMERICA Prepared for: The National Renewable Energy Laboratory 15013 Denver West Parkway Golden, CO 80401 Prepared by: Edward B. Arnett 1 , Gregory D. Johnson 2 , Wally P. Erickson 2 , and Cris D. Hein 3 1 Theordore Roosevelt Conservation Partnership 2 Western EcoSystems Technology, Inc. 3 Bat Conservation International March 2013 CITATION Arnett, E. B., G. D. Johnson, W. P. Erickson, and C.

  5. Microsoft Word - EM SSAB Chairs Public Meeting Agenda - Spring SRS

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    April 22-23, 2015 Doubletree, 2651 Perimeter Parkway, Augusta, Georgia 30909 Wednesday, April 22 8:00 am Welcome and Opening Remarks * David Borak, EM SSAB Designated Federal Officer * Hardie Davis Jr., Mayor, City of Augusta * David Moody, Manager, Savannah River Site * Harold Simon, Chair, Savannah River Site Citizens Advisory Board 8:20 am Meeting Overview * Eric Roberts, Facilitator 8:30 am EM Program Update * Mark Whitney, Acting Assistant Secretary for Environmental Management 9:15 am

  6. Microsoft Word - Final FONSI STM SWEA_DOE-EA-1968

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    68 Page 1 of 10 Department of Energy Golden Field Office 15013 Denver West Parkway Golden, Colorado 80401 FINDING OF NO SIGNIFICANT IMPACT SITE-WIDE ENVIRONMENTAL ASSESSMENT U.S. DEPARTMENT OF ENERGY NATIONAL RENEWABLE ENERGY LABORATORY SOUTH TABLE MOUNTAIN CAMPUS GOLDEN, COLORADO DOE/EA-1968 AGENCY: U.S. Department of Energy (DOE), Office of Energy Efficiency and Renewable Energy (EERE) ACTION: Finding of No Significant Impact (FONSI) SUMMARY: DOE is proposing an action of site operations and

  7. Microsoft Word - NWTC Final SWEA 5.6.2014

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    14 Page 1 of 10 Department of Energy Golden Field Office 15013 Denver West Parkway Golden, Colorado 80401 FINDING OF NO SIGNIFICANT IMPACT SITE-WIDE ENVIRONMENTAL ASSESSMENT OF THE DEPARTMENT OF ENERGY'S NATIONAL WIND TECHNOLOGY CENTER, GOLDEN, COLORADO AT THE NATIONAL RENEWABLE ENERGY LABORATORY DOE/EA-1914 AGENCY: U.S. Department of Energy (DOE), Office of Energy Efficiency and Renewable Energy (EERE) ACTION: Finding of No Significant Impact (FONSI) SUMMARY: DOE is proposing an action to

  8. Microsoft Word - SSAB Meeting Summary for April 2015.FINAL.docx

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    DoubleTree by Hilton Hotel 2651 Perimeter Parkway, Augusta, Georgia 30909 April 22-23, 2015 2 Environmental Management Site-Specific Advisory Board - April 22-23, 2015 Meeting Minutes LIST OF ACRONYMS AIB - Accident Investigation Board AMWTP - Advanced Mixed Waste Treatment Project ANA - Alliance for Nuclear Accountability CAB - Citizens Advisory Board CROET - Community Reuse Organization of East Tennessee DDFO - Deputy Designated Federal Officer DOE - Department of Energy DUF6 - Depleted

  9. URTAC Meeting - September 2012 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Unconventional Resources Technology Advisory Committee Meeting Tuesday, September 25, 2012 Hyatt North Houston North Sam Houston Parkway East Houston, TX Overview of "Section 999" and the Uncoventional Resources Technology Advisory Committee (108.67 KB) DOE Traditional Research and NETL Complementary Research Portfolio (3.83 MB) RPSEA Onshore Program: Project Results - Environment Safety (6.76 MB) URTAC Calendar and Next Steps (87.72 KB) More Documents & Publications URTAC Meeting

  10. Hybrid and Advanced Air Cooling

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Advanced Air Cooling Desikan Bharathan National Renewable Energy Laboratory 15013 Denver West Parkway Golden, CO 80401 ARRA funded Project Officer: Tim Reinhardt Total Project Funding: $1079K April 22-25, 2013 This presentation does not contain any proprietary confidential, or otherwise restricted information. Do not include any proprietary or confidential information. Your presentation is public and will be posted to the DOE Geothermal Technologies Office website. You must include the

  11. Illinois Company Implementing Solar Energy

    Broader source: Energy.gov [DOE]

    J.F. Family Limited Partnership has been awarded $191,000 through the Recovery Act toward the use of solar energy at its Lakefront Parkway property in Edwardsville, Ill., which is the company headquarters for J.F. Electric Inc. The funding will be used to install a 75-kW solar photovoltaic system on the building’s roof, creating electricity on-site and creating or saving a total of 14 jobs.

  12. Community Meeting to Focus on NREL Construction Plans

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Community Meeting to Focus on NREL Construction Plans For more information contact: Kerry Masson (303) 275-4083 Golden, Colo., May 6, 1996 -- The U.S. Department of Energy's (DOE) National Renewable Energy Laboratory (NREL) will host a community meeting May 15 at 6:30 p.m. at the NREL Visitors Center, 15013 Denver West Parkway. Frank Stewart, DOE's Golden Field Officer Manager, will discuss a variety of issues including planned construction projects on NREL's 300-acre campus. Construction plans

  13. Reducible oxide based catalysts

    DOE Patents [OSTI]

    Thompson, Levi T.; Kim, Chang Hwan; Bej, Shyamal K.

    2010-04-06

    A catalyst is disclosed herein. The catalyst includes a reducible oxide support and at least one noble metal fixed on the reducible oxide support. The noble metal(s) is loaded on the support at a substantially constant temperature and pH.

  14. Diamond film growth from fullerene precursors

    DOE Patents [OSTI]

    Gruen, Dieter M.; Liu, Shengzhong; Krauss, Alan R.; Pan, Xianzheng

    1997-01-01

    A method and system for manufacturing diamond film. The method involves forming a fullerene vapor, providing a noble gas stream and combining the gas with the fullerene vapor, passing the combined fullerene vapor and noble gas carrier stream into a chamber, forming a plasma in the chamber causing fragmentation of the fullerene and deposition of a diamond film on a substrate.

  15. Regional setting of Niobrara Formation in Northern Great Plains

    SciTech Connect (OSTI)

    Shurr, G.W.

    1984-05-01

    Natural gas is currently produced from the Upper Cretaceous Niobrara Formation in northeastern Colorado, northwestern Kansas, and several small fields in Nebraska. As a part of studies of low-permeability gas reservoirs in the northern Great Plains, the regional geologic setting of the Niobrara has been investigated in North Dakota, South Dakota, and Nebraska. Structural contours of the Ardmore Bentonite Bed suggest that the area of thin Niobrara strata presently approximates the south flank of the Williston basin and north flank of the Denver and Kennedy basins. Chalk tongues are interpreted as low-angle shelf surfaces, known as carbonate ramps, which sloped gently to the northwest and southeast off a paleotectonic high. The paleotectonic high cut obliquely across the seaway and was close to the position of the Transcontinental arch that influenced Paleozoic sedimentation. As a result, the present-day stratigraphy and structural setting of the Niobrara are different north and south of the arch crest. 58 references, 13 figures, 1 table.

  16. Field trip guide to selected outcrops, Arbuckle Mountains, Oklahoma

    SciTech Connect (OSTI)

    1991-11-17

    The Arbuckle Mountains, named for Brigadier General Matthew Arbuckle, are located in south-central Oklahoma. The formations that comprise the Arbuckle Mountains have been extensively studied for hydrocarbon source rock and reservoir rock characteristics that can be applied to the subsurface in the adjacent Anadarko and Ardmore basins. Numerous reports and guidebooks have been written concerning the Arbuckle Mountains. A few important general publications are provided in the list of selected references. The purpose of this handout is to provide general information on the geology of the Arbuckle Mountains and specific information on the four field trip stops, adapted from the literature. The four stops were at: (1) Sooner Rock and Sand Quarry; (2) Woodford Shale; (3) Hunton Anticline and Hunton Quarry; and (4) Tar Sands of Sulfur Area. As part of this report, two papers are included for more detail: Paleomagnetic dating of basinal fluid migration, base-metal mineralization, and hydrocarbon maturation in the Arbuckle Mountains, Oklahoma and Laminated black shale-bedded chert cyclicity in the Woodford Formation, southern Oklahoma.

  17. Composite materials and method of making

    DOE Patents [OSTI]

    Uribe, Francisco A.; Wilson, Mahlon S.; Garzon, Fernando H.

    2009-09-15

    A method of depositing noble metals on a metal hexaboride support. The hexaboride support is sufficiently electropositive to allow noble metals to deposit spontaneously from solutions containing ionic species of such metals onto the support. The method permits the deposition of metallic films of controlled thickness and particle size at room temperature without using separate reducing agents. Composite materials comprising noble metal films deposited on such metal hexaborides are also described. Such composite materials may be used as catalysts, thermionic emitters, electrical contacts, electrodes, adhesion layers, and optical coatings.

  18. Method for forming gold-containing catalyst with porous structure

    DOE Patents [OSTI]

    Biener, Juergen; Hamza, Alex V; Baeumer, Marcus; Schulz, Christian; Jurgens, Birte; Biener, Monika M.

    2014-07-22

    A method for forming a gold-containing catalyst with porous structure according to one embodiment of the present invention includes producing a starting alloy by melting together of gold and at least one less noble metal that is selected from the group consisting of silver, copper, rhodium, palladium, and platinum; and a dealloying step comprising at least partial removal of the less noble metal by dissolving the at least one less noble metal out of the starting alloy. Additional methods and products thereof are also presented.

  19. Isotopic abundance in atom trap trace analysis

    DOE Patents [OSTI]

    Lu, Zheng-Tian; Hu, Shiu-Ming; Jiang, Wei; Mueller, Peter

    2014-03-18

    A method and system for detecting ratios and amounts of isotopes of noble gases. The method and system is constructed to be able to measure noble gas isotopes in water and ice, which helps reveal the geological age of the samples and understand their movements. The method and system uses a combination of a cooled discharge source, a beam collimator, a beam slower and magneto-optic trap with a laser to apply resonance frequency energy to the noble gas to be quenched and detected.

  20. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... quantum dot, noble metal, magnetic metal oxide, organic polymer, metal salt, and core-shell ... We next explore the positioning of a tet operator site within the T7lacO framework ...

  1. CX-004448: Categorical Exclusion Determination

    Office of Energy Efficiency and Renewable Energy (EERE)

    Noble Gas AnalysisCX(s) Applied: B3.6Date: 10/15/2010Location(s): Aiken, South CarolinaOffice(s): Savannah River Operations Office

  2. Adrian, Minnesota: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Map This article is a stub. You can help OpenEI by expanding it. Adrian is a city in Nobles County, Minnesota. It falls under Minnesota's 1st congressional district.12...

  3. Electrocatalyst for alcohol oxidation at fuel cell anodes

    DOE Patents [OSTI]

    Adzic, Radoslav; Kowal, Andrzej

    2011-11-02

    In some embodiments a ternary electrocatalyst is provided. The electrocatalyst can be used in an anode for oxidizing alcohol in a fuel cell. In some embodiments, the ternary electrocatalyst may include a noble metal particle having a surface decorated with clusters of SnO.sub.2 and Rh. The noble metal particles may include platinum, palladium, ruthenium, iridium, gold, and combinations thereof. In some embodiments, the ternary electrocatalyst includes SnO.sub.2 particles having a surface decorated with clusters of a noble metal and Rh. Some ternary electrocatalysts include noble metal particles with clusters of SnO.sub.2 and Rh at their surfaces. In some embodiments the electrocatalyst particle cores are nanoparticles. Some embodiments of the invention provide a fuel cell including an anode incorporating the ternary electrocatalyst. In some aspects a method of using ternary electrocatalysts of Pt, Rh, and SnO.sub.2 to oxidize an alcohol in a fuel cell is described.

  4. Application to Export Electric Energy OE Docket No. EA-363-A...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Federal Register Notice, Volume 80, No. 42 - March 4, 2015 Application from NAG&P to export electric energy to Mexico. Federal Register Notice. PDF icon EA-363-A Noble...

  5. Radiation Counters

    DOE Patents [OSTI]

    Simpson, Jr, J A

    1950-01-31

    Geiger-Mueller and proportional counters operating at low potentials (about 125-300 v) obtained by utilizing certain ratios of diameters of the electrodes and particular mixtures of noble gases as the ionizing medium are covered in this application.

  6. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... Lang, Jared (1) Meech, Karen J. (1) Newhouse, Alan (1) Noble, Robert J. (1) Oleson, Steven R. (1) Schmidt, George R. (1) Spilker, Thomas (1) West, John L. (1) Save Results Save ...

  7. Platinum-ruthenium-palladium alloys for use as a fuel cell catalyst

    DOE Patents [OSTI]

    Gorer, Alexander

    2002-01-01

    A noble metal alloy composition for a fuel cell catalyst, a ternary alloy composition containing platinum, ruthenium and palladium. The alloy shows increased activity as compared to well-known catalysts.

  8. Compound and Elemental Analysis At Yellowstone Region (Kennedy...

    Open Energy Info (EERE)

    DOE-funding Unknown References B. M. Kennedy, M. A. Lynch, J. H. Reynolds, S. P. Smith (1985) Intensive Sampling Of Noble Gases In Fluids At Yellowstone- I, Early Overview...

  9. Porous Carbon Supports: Recent Advances with Various Morphologies...

    Office of Scientific and Technical Information (OSTI)

    be even more attractive if several characteristics are considered, such as the stability in acidic and basic media or the ease of noble metal recovery through complete burn off. ...

  10. Mass Production Cost Estimation for Direct H2 PEM Fuel Cell Systems...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... or nickel, palladium, niobium, rhodium, rare earth metals, and other noble metals." (Fonk et ... and consists of only two elements: the Nafion ionomer and the ePTFE substrate. ...

  11. Improved dark matter search results from PICO-2L Run 2 (Journal...

    Office of Scientific and Technical Information (OSTI)

    Leblanc, A. ; Levine, I. ; Lippincott, W. H. ; Mann, E. ; Martin, J. P. ; Maurya, D. ; Mitra, P. ; Olson, S. ; Neilson, R. ; Noble, A. J. ; Plante, A. ; Podviianiuk, R. B. ; Priya, ...

  12. G. L. Tingey

    Office of Scientific and Technical Information (OSTI)

    G. L. Tingey E. D. f4cClanahan M. A. Bayne W. J. Gray January 1980 SOLID STATE CONTAINMENT OF NOBLE GASES I f 4 SPUTTER DEPOSITED METALS AND L O W DENSITY GLASSES To be presented a ...

  13. EA-98-A Western Systems Power Pool | Department of Energy

    Energy Savers [EERE]

    energy to Canada PDF icon EA-98-A Western Systems Power Pool More Documents & Publications EA-364 Noble Americas Gas & Power Corporation EA-098 Western Systems Power Pool EA-98-I...

  14. Thin film photovoltaic cells

    DOE Patents [OSTI]

    Rothwarf, Allen

    1981-01-01

    A solar cell has as its transparent electrical contact a grid made from a non-noble metal by providing a layer of copper oxide between the transparent electrical contact and the absorber-generator.

  15. EC Publications

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Computational Investigation of Noble Gas Adsorption and Separation by Nanoporous Materials admin 2016-04-18T20:58:24+00:00 Popular Downloads Solar Energy Grid Integration Systems: ...

  16. Microsoft Word - S04251_2007 Post-Closure Plan.doc

    Office of Legacy Management (LM)

    ... B.R. Anderson Pond Lower Little Cr. 1 Lower Little Cr. 2 Jamel Lowe Pond Nobles Pond Howard Smith Pond Figure 8. Tritium Decay Trend and Off-Site Surface Water Sample ...

  17. NREL Bilateral Nondisclosure Agreement - Sample

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (REV 07/09) Page 1 of 3 BILATERAL NON-DISCLOSURE AGREEMENT No. XX - XXXX ("Agreement") This Agreement is entered into by and between the Alliance for Sustainable Energy, LLC ("Alliance"), the Manager and Operator of the National Renewable Energy Laboratory ("NREL") under Prime Contract No. DE- AC36-08GO28308 for the U.S. Department of Energy (the "DOE"), located at 15013 Denver West Parkway, Golden, CO, 80401 and COMPANY NAME ("Company"), whose

  18. NREL Unilateral Nondisclosure Agreement - Company Disclosing - Sample

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    REV 07/09) Page 1 of 2 UNILATERAL (IN) NON-DISCLOSURE AGREEMENT No. XX - XXXX ("Agreement") This Agreement is entered into by and between the Alliance for Sustainable Energy, LLC ("Alliance"), the Manager and Operator of the National Renewable Energy Laboratory ("NREL") under Prime Contract No. DE- AC36-08GO28308 for the U.S. Department of Energy (the "DOE"), located at 15013 Denver West Parkway, Golden, CO 80401, and DISCLOSING PARTY NAME

  19. Nevada Field Office News News Media Contact: For Immediate Release:

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    September 10, 2015 darwin.morgan@nnsa.doe.gov U.S. Department of Energy (DOE) Advisory Board to Meet A public meeting hosted by the Nevada Site Specific Advisory Board (NSSAB) will begin at 4 p.m., Wednesday, September 16, 2015, at the Clark County Government Center's Pueblo Room, 500 South Grand Central Parkway, Las Vegas, Nevada. The agenda will focus on developing the Board's fiscal year 2016 work plan. The NSSAB is a federally-chartered board comprised of rural and urban southern Nevada

  20. Chairs Meeting - June 2011 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    June 2011 Chairs Meeting - June 2011 Environmental Management Site-Specific Advisory Board Chairs Meeting June 15 and 16, 2011 Aliante Station 7300 Aliante Parkway North Las Vegas, Nevada 89084 Documents Available for Download Meeting Agenda (160.53 KB) EM Program Update by Shirley J. Olinger (7.41 MB) Top Three Topics and Achievements by Site (3.11 MB) EM Budget Update by Joann Luczak (1.65 MB) Waste Materials and Disposition Update by Shirley J. Olinger (5.17 MB) Federal Advisory Committee Act

  1. Coca-Cola Refreshments Class 8 Diesel Electric Hybrid Tractor Evaluation: 13-Month Final Report

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Coca-Cola Refreshments Class 8 Diesel Electric Hybrid Tractor Evaluation: 13-Month Final Report K. Walkowicz, M. Lammert, and P. Curran Technical Report NREL/TP-5400-53502 August 2012 NREL is a national laboratory of the U.S. Department of Energy, Office of Energy Efficiency & Renewable Energy, operated by the Alliance for Sustainable Energy, LLC. National Renewable Energy Laboratory 15013 Denver West Parkway Golden, Colorado 80401 303-275-3000 * www.nrel.gov Contract No. DE-AC36-08GO28308

  2. FESAC Agenda - November 2008 | U.S. DOE Office of Science (SC)

    Office of Science (SC) Website

    November 2008 Fusion Energy Sciences Advisory Committee (FESAC) FESAC Home Meetings Members Charges/Reports Charter .pdf file (266KB) FES Committees of Visitors Federal Advisory Committees FES Home Meetings FESAC Agenda - November 2008 Print Text Size: A A A FeedbackShare Page Fusion Energy Sciences Advisory Committee Meeting Gaithersburg Hilton 620 Perry Parkway 301-977-8900 Agenda November 6-7, 2008 Time Topic Speaker November 6 8:30 During this time we will swear in new members. ALL MEMBERS

  3. Golden_Poster

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Golden Field Office » Golden Field Office Contacts Golden Field Office Contacts On this page you will find address and contact information for the Golden Field Office of the Office of Energy Efficiency and Renewable Energy (EERE). Mailing Address U.S. Department of Energy Golden Field Office 15013 Denver West Parkway Golden, Colorado 80401 Main Number: 720-356-1800 Main Fax: 720-356-1750 Media Inquiries For media inquiries, please email the EERE communications team at EE.Media@ee.doe.gov.

  4. Western Wind and Solar Integration Study Phase 3 … Frequency Response and Transient Stability

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Stability N.W. Miller, M. Shao, S. Pajic, and R. D'Aquila GE Energy Management Schenectady, New York NREL Technical Monitor: Kara Clark Link to Executive Summary Subcontract Report NREL/SR-5D00-62906 December 2014 NREL is a national laboratory of the U.S. Department of Energy, Office of Energy Efficiency & Renewable Energy, operated by the Alliance for Sustainable Energy, LLC. National Renewable Energy Laboratory 15013 Denver West Parkway Golden, Colorado 80401 303-275-3000 * www.nrel.gov

  5. Western Wind and Solar Integration Study Phase 3 … Frequency Response and Transient Stability: Executive Summary

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Stability: Executive Summary N.W. Miller, M. Shao, S. Pajic, and R. D'Aquila GE Energy Management Schenectady, New York NREL Technical Monitor: Kara Clark Link to full report Subcontract Report NREL/SR-5D00-62906-ES December 2014 NREL is a national laboratory of the U.S. Department of Energy, Office of Energy Efficiency & Renewable Energy, operated by the Alliance for Sustainable Energy, LLC. National Renewable Energy Laboratory 15013 Denver West Parkway Golden, Colorado 80401 303-275-3000 *

  6. Wind Powering Americas Wind for Schools Project: Summary Report

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Powering America's Wind for Schools Project Summary Report I. Baring-Gould and C. Newcomb Management Report NREL/MP-7A20-51180 June 2012 NREL is a national laboratory of the U.S. Department of Energy, Office of Energy Efficiency & Renewable Energy, operated by the Alliance for Sustainable Energy, LLC. National Renewable Energy Laboratory 15013 Denver West Parkway Golden, Colorado 80401 303-275-3000 * www.nrel.gov Contract No. DE-AC36-08GO28308 Wind Powering America's Wind for Schools Project

  7. Wind Turbine Gearbox Condition Monitoring Round Robin Study - Vibration Analysis

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Turbine Gearbox Condition Monitoring Round Robin Study - Vibration Analysis S. Sheng, Editor National Renewable Energy Laboratory Technical Report NREL/TP-5000-54530 July 2012 NREL is a national laboratory of the U.S. Department of Energy, Office of Energy Efficiency & Renewable Energy, operated by the Alliance for Sustainable Energy, LLC. National Renewable Energy Laboratory 15013 Denver West Parkway Golden, Colorado 80401 303-275-3000 * www.nrel.gov Contract No. DE-AC36-08GO28308 Wind

  8. NREL Job Task Analysis: Retrofit Installer Technician (Revised)

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Retrofit Installer Technician Chuck Kurnik National Renewable Energy Laboratory Cynthia Woodley Professional Testing Inc. Technical Report NREL/TP-7A20-51671 Revised April 2012 NREL is a national laboratory of the U.S. Department of Energy, Office of Energy Efficiency & Renewable Energy, operated by the Alliance for Sustainable Energy, LLC. National Renewable Energy Laboratory 15013 Denver West Parkway Golden, Colorado 80401 303-275-3000 * www.nrel.gov Contract No. DE-AC36-08GO28308 NREL Job

  9. H2FIRST Reference Station Design Task: Stand-Alone Piping and Instrumentation Diagrams

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    DESCRIPTION ENERGY SYSTEMS INTEGRATION LABORATORY P&ID DRAWING NO PREFIX PID DRAWING NO. REVISION NO. 0 NREL PROJECT NUMBER A/E PROJ NO. 15013 Denver West Parkway Golden, CO 80401-3305 Operated for the U.S. Department of Energy by the Alliance for Sustainable Energy, LLC DESIGNER ENGINEER CHECKED BY A/E APPR. BY NREL APPR BY BLD AREA ENG APPROVAL DATE DATE 12/18/2014 SHEET 1 OF 6 SCALE NONE DRAWN BY C. AINSCOUGH PLATFORM VISIO 2010 PRO FULL FILENAME

  10. Development and Analysis of Desiccant Enhanced Evaporative Air Conditioner Prototype

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Development and Analysis of Desiccant Enhanced Evaporative Air Conditioner Prototype Eric Kozubal, Jason Woods, and Ron Judkoff Technical Report NREL/TP-5500-54755 April 2012 NREL is a national laboratory of the U.S. Department of Energy, Office of Energy Efficiency & Renewable Energy, operated by the Alliance for Sustainable Energy, LLC. National Renewable Energy Laboratory 15013 Denver West Parkway Golden, Colorado 80401 303-275-3000 * www.nrel.gov Contract No. DE-AC36-08GO28308

  11. Microsoft Word - EMAB Minutes _control version_ 081413

    Office of Environmental Management (EM)

    DoubleTree Hotel- Richmond I & II 2651 Perimeter Parkway-Augusta, GA 30909 June 14, 2013 2 Environmental Management Advisory Board - June 14, 2013 - Meeting Minutes TABLE OF CONTENTS The Environmental Management Advisory Board (EMAB) was convened at 9:00 a.m. EDT on Friday, June 14, 2013, at the DoubleTree by Hilton Hotel in Augusta, Georgia. Board Vice Chair Dennis Ferrigno introduced the Board members for the meeting. Board members present: Dr. Frank Coffman, AECOM Government Services Mr.

  12. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    High Occupancy Vehicle (HOV) Lane Exemption and Discount New Jersey Turnpike Authority (Authority) allows qualified hybrid electric vehicles to travel in the HOV lanes located between Interchange 11 and Interchange 14 on the New Jersey Turnpike. The Authority offers a 10% discount on off-peak New Jersey Turnpike and Garden State Parkway toll rates through NJ EZ-Pass for drivers of vehicles that have a fuel economy of 45 miles per gallon or higher and meet the California Super Ultra Low Emission

  13. Golden Field Office Contacts | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Golden Field Office » Golden Field Office Contacts Golden Field Office Contacts On this page you will find address and contact information for the Golden Field Office of the Office of Energy Efficiency and Renewable Energy (EERE). Mailing Address U.S. Department of Energy Golden Field Office 15013 Denver West Parkway Golden, Colorado 80401 Main Number: 720-356-1800 Main Fax: 720-356-1750 Media Inquiries For media inquiries, please email the EERE communications team at EE.Media@ee.doe.gov.

  14. Logistics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Logistics Logistics Location and Schedule Large Scale Production Computing and Storage Requirements for Basic Energy Sciences: Target 2017 BES / ASCR / NERSC Requirements Review The day-and-a-half meeting was held Tuesday, October 8 and Wednesday, October 9, 2013. Hotel HILTON WASHINGTON DC NORTH/GAITHERSBURG 620 Perry Parkway I Gaithersburg MD 20877 I USA TEL: 301-977-8900 Reservations The cutoff date for reservations is September 16th. The group name is "NERS BES REVIEW DOE" The room

  15. Hydrogen Storage Needs for Early Motive Fuel Cell Markets

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Storage Needs for Early Motive Fuel Cell Markets J. Kurtz, C. Ainscough, L. Simpson, and M. Caton Technical Report NREL/TP-5600-52783 November 2012 NREL is a national laboratory of the U.S. Department of Energy, Office of Energy Efficiency & Renewable Energy, operated by the Alliance for Sustainable Energy, LLC. National Renewable Energy Laboratory 15013 Denver West Parkway Golden, Colorado 80401 303-275-3000 * www.nrel.gov Contract No. DE-AC36-08GO28308 Hydrogen Storage Needs for Early

  16. http://www.hanford.gov/boards/hab/response/080.htm

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    0 From: John D. Wagoner Ms. Merilyn Reeves, Chair Hanford Advisory Board 723 The Parkway, Suite 200 Richland, Washington 99352 FEB 05 1998 Dear Ms. Reeves: RESPONSE TO HANFORD ADVISORY BOARD'S (HAB) ADVICE NO. 80 ON "TIMELINE FOR PUBLIC INPUT TO FY 2000 BUDGET PRIORITIZATION INTEGRATED PRIORITY LIST (IPL) AND 2006 PLAN PROCESS FOR 1998" In response to the subject Advice No. 80 dated December 5, 1997, DOE HQ has agreed to extend the due date for the FY 2000 IPL submittal to April 15,

  17. http://www.hanford.gov/boards/hab/response/081.htm

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1 From: Tom Fitzsimmons STATE OF WASHINGTON DEPARTMENT OF ECOLOGY P.O. Box 47600 × Olympia, Washington 98504-7600 (360) 407-6000 × TDD Only (Hearing Impaired) (360) 407-6006 December 23,1997 Ms. Merilyn Reeves, Chair Hanford Advisory Board 723 The Parkway, #200 MSIN: Bl-41 Richland, WA 99352 Dear Ms. Reeves: Thank you for forwarding Hanford Advisory Board Advice #81, in which the Board sets out some significant principles concerning Hanford's safety culture. Ecology welcomes the adoption of

  18. http://www.hanford.gov/boards/hab/response/088.htm

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    8 From: Jackson Kinzer Ms. Merilyn Reeves, Chair Hanford Advisory Board 723 The Parkway, Suite 200 Richland, Washington 99352 January 5, 1999 Dear Ms. Reeves: HANFORD ADVISORY BOARD (HAB) ADVICE #88 CONCERNING THE OFFICE OF RIVER PROTECTION (ORP) Thank you for your advice to be considered during development of the ORP management plan that is to be submitted to Congress in mid-January 1999. We are preparing that plan now and are considering your advice. However, we will not be able to make the

  19. http://www.hanford.gov/boards/hab/response/092b.htm

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Region 10 1200 Sixth Avenue Seattle, Washington 98101 Advice # 92 From: Michael F. Gearheard Ms. Merilyn Reeves, Chair Hanford Advisory Board 723 The Parkway, Suite 200 Richland, Washington 99352 May 24, 1999 Re: EPA Response to Consensus Advice #92 Dear Ms. Reeves: Thank you for the advice on the Tri-Parties Response to Public Comments. In the spirit of your advice, I want to start by saying we agree with the points you raised. In addition, I want to know I have taken the liverty of

  20. http://www.hanford.gov/boards/hab/response/094a.htm

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Washington, D.C. 20460 Advice # 94a From: Timothy Fields, Jr. June 4, 1999 Ms. Merilyn B. Reeves, Chair Hanford Advisory Board 723 The Parkway, Suite 200 Richland, Washington 99352 Dear Ms. Reeves: Thank you for your letter dated April 21, 1999, to Administrator Carol M. Browner of the U.S. Environmental Protection Agency (EPA). Administrator Browner has asked me to respond to your letter from the Hanford Advisory Board on the proposed fiscal year 2001 budget for the U.S. Department of Energy

  1. http://www.hanford.gov/boards/hab/response/098.htm

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    8 From: Carolyn L. Huntoon Ms. Merilyn Reeves, Chair Hanford Advisory Board 723 The Parkway Suite 200 Richland, Washington 99352 September 13, 1999 Dear Ms. Reeves: In your letter of July 16, 1999, you express concerns and offered advice, on behalf of the Hanford Advisory Board (HAB), concerning the Department of Energy's (Department) impending Record of Decision for low-level waste and mixed low-level waste disposal. Issuing the Record of Decision (ROD) for disposal of low-level waste and mixed

  2. http://www.hanford.gov/boards/hab/response/102.htm

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    WMD-062 Advice # 102 From: Keith A. Klein Ms. Merilyn B. Reeves, Chair Hanford Advisory Board 723 The Parkway, Suite 200: B1 -41 Richland, Washington 99352 Dear Ms. Reeves: RESPONSE TO HANFORD ADVISORY BOARD (HAB) ON POSSIBLE TRANSFER OF LOW- LEVEL (LLW) AND MIXED LOW-LEVEL WASTE (MLLW) TO HANFORD In reference to your letter to me, same subject as above, dated February 4, 2000, a concern was raised that the then-pending Record of Decision (ROD) for the U.S. Department of Energy, (DOE) Richland

  3. http://www.hanford.gov/boards/hab/response/106.htm

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ERD- 114 Advice # 106 From: Keith A. Klein Ms. Merilyn B. Reeves, Chair Hanford Advisory Board 723 Parkway Suite 200: B1-41 Richland, Washington 99352 Dear Ms. Reeves: RESPONSE TO THE HANFORD ADVISORY BOARD (HAB) ADVICE ON THE 618-10 AND 618- 11 BURIAL GROUNDS Thank you for the clear HAB position and advice spelled out in your April 7, 2000, letter addressing the 618-10 and 618-11 Burial Grounds. I appreciate your concern regarding these two significant sites. To address the board's main

  4. Summary and Findings from the NREL/DOE Hydrogen Sensor Workshop (June 8, 2011)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Summary and Findings from the NREL/DOE Hydrogen Sensor Workshop (June 8, 2011) W. Buttner, R. Burgess, M. Post, and C. Rivkin National Renewable Energy Laboratory Technical Report NREL/TP-5600-55645 July 2012 NREL is a national laboratory of the U.S. Department of Energy, Office of Energy Efficiency & Renewable Energy, operated by the Alliance for Sustainable Energy, LLC. National Renewable Energy Laboratory 15013 Denver West Parkway Golden, Colorado 80401 303-275-3000 * www.nrel.gov

  5. Coca-Cola Refreshments Class 8 Diesel Electric Hybrid Tractor Evaluation: 13-Month Final Report

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Coca-Cola Refreshments Class 8 Diesel Electric Hybrid Tractor Evaluation: 13-Month Final Report K. Walkowicz, M. Lammert, and P. Curran Technical Report NREL/TP-5400-53502 August 2012 NREL is a national laboratory of the U.S. Department of Energy, Office of Energy Efficiency & Renewable Energy, operated by the Alliance for Sustainable Energy, LLC. National Renewable Energy Laboratory 15013 Denver West Parkway Golden, Colorado 80401 303-275-3000 * www.nrel.gov Contract No. DE-AC36-08GO28308

  6. NETL Carbon Capture Technologies to Be Used in Commercial

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Biomass-to-Biofuel Conversion Process with Power Generation | Department of Energy Carbon Capture Technologies to Be Used in Commercial Biomass-to-Biofuel Conversion Process with Power Generation NETL Carbon Capture Technologies to Be Used in Commercial Biomass-to-Biofuel Conversion Process with Power Generation January 20, 2016 - 10:14am Addthis Photo courtesy of Noble Foundation. Some rights reserved Photo courtesy of Noble Foundation. Some rights reserved The National Energy Technology

  7. NETL F 451.1/1-1, Categorical Exclusion Designation Form

    Office of Environmental Management (EM)

    Biomass-to-Biofuel Conversion Process with Power Generation | Department of Energy Carbon Capture Technologies to Be Used in Commercial Biomass-to-Biofuel Conversion Process with Power Generation NETL Carbon Capture Technologies to Be Used in Commercial Biomass-to-Biofuel Conversion Process with Power Generation January 20, 2016 - 10:14am Addthis Photo courtesy of Noble Foundation. Some rights reserved Photo courtesy of Noble Foundation. Some rights reserved The National Energy Technology

  8. Process for recycling components of a PEM fuel cell membrane electrode assembly

    SciTech Connect (OSTI)

    Shore, Lawrence

    2012-02-28

    The membrane electrode assembly (MEA) of a PEM fuel cell can be recycled by contacting the MEA with a lower alkyl alcohol solvent which separates the membrane from the anode and cathode layers of the assembly. The resulting solution containing both the polymer membrane and supported noble metal catalysts can be heated under mild conditions to disperse the polymer membrane as particles and the supported noble metal catalysts and polymer membrane particles separated by known filtration means.

  9. NETL F 451.1/1-1, Categorical Exclusion Designation Form

    Broader source: Energy.gov (indexed) [DOE]

    Biomass-to-Biofuel Conversion Process with Power Generation | Department of Energy Photo courtesy of Noble Foundation. Some rights reserved Photo courtesy of Noble Foundation. Some rights reserved The National Energy Technology Laboratory (NETL) has granted a license for two patented sorbent technologies that capture carbon dioxide (CO2) from streams of mixed gases and enable cleaner, more-efficient energy production from renewable fuels. The license was granted to renewable energy systems

  10. Diamond film growth from fullerene precursors

    DOE Patents [OSTI]

    Gruen, D.M.; Liu, S.; Krauss, A.R.; Pan, X.

    1997-04-15

    A method and system are disclosed for manufacturing diamond film. The method involves forming a fullerene vapor, providing a noble gas stream and combining the gas with the fullerene vapor, passing the combined fullerene vapor and noble gas carrier stream into a chamber, forming a plasma in the chamber causing fragmentation of the fullerene and deposition of a diamond film on a substrate. 10 figs.

  11. Processes and catalysts for conducting fischer-tropsch synthesis in a slurry bubble column reactor

    DOE Patents [OSTI]

    Singleton, Alan H.; Oukaci, Rachid; Goodwin, James G.

    1999-01-01

    Processes and catalysts for conducting Fischer-Tropsch synthesis in a slurry bubble column reactor (SBCR). One aspect of the invention involves the use of cobalt catalysts without noble metal promotion in an SBCR. Another aspect involves using palladium promoted cobalt catalysts in an SBCR. Methods for preparing noble metal promoted catalysts via totally aqueous impregnation and procedures for producing attrition resistant catalysts are also provided.

  12. Processes and catalysts for conducting Fischer-Tropsch synthesis in a slurry bubble column reactor

    DOE Patents [OSTI]

    Singleton, A.H.; Oukaci, R.; Goodwin, J.G.

    1999-08-17

    Processes and catalysts are disclosed for conducting Fischer-Tropsch synthesis in a slurry bubble column reactor (SBCR). One aspect of the invention involves the use of cobalt catalysts without noble metal promotion in an SBCR. Another aspect involves using palladium promoted cobalt catalysts in an SBCR. Methods for preparing noble metal promoted catalysts via totally aqueous impregnation and procedures for producing attrition resistant catalysts are also provided. 1 fig.

  13. Platinum-based electrocatalysts synthesized by depositing contiguous adlayers on carbon nanostructures

    DOE Patents [OSTI]

    Adzic, Radoslav R.; Harris, Alexander

    2015-10-06

    High-surface-area carbon nanostructures coated with a smooth and conformal submonolayer-to-multilayer thin metal films and their method of manufacture are described. The manufacturing process may involve initial oxidation of the carbon nanostructures followed by immersion in a solution with the desired pH to create negative surface dipoles. The nanostructures are subsequently immersed in an alkaline solution containing non-noble metal ions which adsorb at surface reaction sites. The metal ions are then reduced via chemical or electrical means and the nanostructures are exposed to a solution containing a salt of one or more noble metals which replace adsorbed non-noble surface metal atoms by galvanic displacement. Subsequent film growth may be performed via the initial quasi-underpotential deposition of a non-noble metal followed by immersion in a solution comprising a more noble metal. The resulting coated nanostructures may be used, for example, as high-performance electrodes in supercapacitors, batteries, or other electric storage devices.

  14. Platinum-based electrocatalysts synthesized by depositing contiguous adlayers on carbon nanostructures

    DOE Patents [OSTI]

    Adzic, Radoslav; Harris, Alexander

    2013-03-26

    High-surface-area carbon nanostructures coated with a smooth and conformal submonolayer-to-multilayer thin metal films and their method of manufacture are described. The preferred manufacturing process involves the initial oxidation of the carbon nanostructures followed by immersion in a solution with the desired pH to create negative surface dipoles. The nanostructures are subsequently immersed in an alkaline solution containing non-noble metal ions which adsorb at surface reaction sites. The metal ions are then reduced via chemical or electrical means and the nanostructures are exposed to a solution containing a salt of one or more noble metals which replace adsorbed non-noble surface metal atoms by galvanic displacement. Subsequent film growth may be performed via the initial quasi-underpotential deposition of a non-noble metal followed by immersion in a solution comprising a more noble metal. The resulting coated nanostructures may be used, for example, as high-performance electrodes in supercapacitors, batteries, or other electric storage devices.

  15. Preliminary melter performance assessment report

    SciTech Connect (OSTI)

    Elliott, M.L.; Eyler, L.L.; Mahoney, L.A.; Cooper, M.F.; Whitney, L.D.; Shafer, P.J.

    1994-08-01

    The Melter Performance Assessment activity, a component of the Pacific Northwest Laboratory`s (PNL) Vitrification Technology Development (PVTD) effort, was designed to determine the impact of noble metals on the operational life of the reference Hanford Waste Vitrification Plant (HWVP) melter. The melter performance assessment consisted of several activities, including a literature review of all work done with noble metals in glass, gradient furnace testing to study the behavior of noble metals during the melting process, research-scale and engineering-scale melter testing to evaluate effects of noble metals on melter operation, and computer modeling that used the experimental data to predict effects of noble metals on the full-scale melter. Feed used in these tests simulated neutralized current acid waste (NCAW) feed. This report summarizes the results of the melter performance assessment and predicts the lifetime of the HWVP melter. It should be noted that this work was conducted before the recent Tri-Party Agreement changes, so the reference melter referred to here is the Defense Waste Processing Facility (DWPF) melter design.

  16. Characterization of Irradiated Metal Waste from the Pyrometallurgical Treatment of Used EBR-II Fuel

    SciTech Connect (OSTI)

    B.R. Westphal; K.C. Marsden; W.M. McCartin; S.M. Frank; D.D. Keiser, Jr.; T.S. Yoo; D. Vaden; D.G. Cummings; K.J. Bateman; J. J. Giglio; T. P. O'Holleran; P. A. Hahn; M. N. Patterson

    2013-03-01

    As part of the pyrometallurgical treatment of used Experimental Breeder Reactor-II fuel, a metal waste stream is generated consisting primarily of cladding hulls laden with fission products noble to the electrorefining process. Consolidation by melting at high temperature [1873 K (1600 degrees C)] has been developed to sequester the noble metal fission products (Zr, Mo, Tc, Ru, Rh, Te, and Pd) which remain in the iron-based cladding hulls. Zirconium from the uranium fuel alloy (U-10Zr) is also deposited on the hulls and forms Fe-Zr intermetallics which incorporate the noble metals as well as residual actinides during processing. Hence, Zr has been chosen as the primary indicator for consistency of the metal waste. Recently, the first production-scale metal waste ingot was generated and sampled to monitor Zr content for Fe-Zr intermetallic phase formation and validation of processing conditions. Chemical assay of the metal waste ingot revealed a homogeneous distribution of the noble metal fission products as well as the primary fuel constituents U and Zr. Microstructural characterization of the ingot confirmed the immobilization of the noble metals in the Fe-Zr intermetallic phase.

  17. Method and system to measure temperature of gases using coherent anti-stokes doppler spectroscopy

    DOE Patents [OSTI]

    Rhodes, Mark

    2013-12-17

    A method of measuring a temperature of a noble gas in a chamber includes providing the noble gas in the chamber. The noble gas is characterized by a pressure and a temperature. The method also includes directing a first laser beam into the chamber and directing a second laser beam into the chamber. The first laser beam is characterized by a first frequency and the second laser beam is characterized by a second frequency. The method further includes converting at least a portion of the first laser beam and the second laser beam into a coherent anti-Stokes beam, measuring a Doppler broadening of the coherent anti-Stokes beam, and computing the temperature using the Doppler broadening.

  18. Method and electrochemical cell for synthesis and treatment of metal monolayer electrocatalysts metal, carbon, and oxide nanoparticles ion batch, or in continuous fashion

    SciTech Connect (OSTI)

    Adzic, Radoslav; Zhang, Junliang; Sasaki, Kotaro

    2015-04-28

    An apparatus and method for synthesis and treatment of electrocatalyst particles in batch or continuous fashion is provided. In one embodiment, the apparatus comprises a sonication bath and a two-compartment chamber submerged in the sonication bath. The upper and lower compartments are separated by a microporous material surface. The upper compartment comprises a cover and a working electrode (WE) connected to a Pt foil contact, with the foil contact connected to the microporous material. The upper chamber further comprises reference counter electrodes. The lower compartment comprises an electrochemical cell containing a solution of metal ions. In one embodiment, the method for synthesis of electrocatalysts comprises introducing a plurality of particles into the apparatus and applying sonication and an electrical potential to the microporous material connected to the WE. After the non-noble metal ions are deposited onto the particles, the non-noble metal ions are displaced by noble-metal ions by galvanic displacement.

  19. Precursor composites for oxygen dispersion hardened silver sheathed superconductor composites

    DOE Patents [OSTI]

    Podtburg, Eric R.

    1999-01-01

    An oxide superconductor composite having improved texture and durability. The oxide superconductor composite includes an oxide superconductor phase substantially surrounded with/by a noble metal matrix, the noble metal matrix comprising a metal oxide in an amount effective to form metal oxide domains that increase hardness of the composite. The composite is characterized by a degree of texture at least 10% greater than a comparable oxide superconductor composite lacking metal oxide domains. An oxide superconducting composite may be prepared by oxidizing the precursor composite under conditions effective to form solute metal oxide domains within the silver matrix and to form a precursor oxide in the precursor alloy phase; subjecting the oxidized composite to a softening anneal under conditions effective to relieve stress within the noble metal phase; and converting the oxide precursor into an oxide superconductor.

  20. Precursor composites for oxygen dispersion hardened silver sheathed superconductor composites

    DOE Patents [OSTI]

    Podtburg, E.R.

    1999-06-22

    An oxide superconductor composite having improved texture and durability is disclosed. The oxide superconductor composite includes an oxide superconductor phase substantially surrounded with/by a noble metal matrix, the noble metal matrix comprising a metal oxide in an amount effective to form metal oxide domains that increase hardness of the composite. The composite is characterized by a degree of texture at least 10% greater than a comparable oxide superconductor composite lacking metal oxide domains. An oxide superconducting composite may be prepared by oxidizing the precursor composite under conditions effective to form solute metal oxide domains within the silver matrix and to form a precursor oxide in the precursor alloy phase; subjecting the oxidized composite to a softening anneal under conditions effective to relieve stress within the noble metal phase; and converting the oxide precursor into an oxide superconductor. 1 fig.

  1. Electrodes synthesized from carbon nanostructures coated with a smooth and conformal metal adlayer

    DOE Patents [OSTI]

    Adzic, Radoslav; Harris, Alexander

    2014-04-15

    High-surface-area carbon nanostructures coated with a smooth and conformal submonolayer-to-multilayer thin metal films and their method of manufacture are described. The preferred manufacturing process involves the initial oxidation of the carbon nanostructures followed by a surface preparation process involving immersion in a solution with the desired pH to create negative surface dipoles. The nanostructures are subsequently immersed in an alkaline solution containing a suitable quantity of non-noble metal ions which adsorb at surface reaction sites. The metal ions are then reduced via chemical or electrical means. The nanostructures are exposed to a solution containing a salt of one or more noble metals which replace adsorbed non-noble surface metal atoms by galvanic displacement. The process can be controlled and repeated to obtain a desired film coverage. The resulting coated nanostructures may be used, for example, as high-performance electrodes in supercapacitors, batteries, or other electric storage devices.

  2. Electrocatalyst for alcohol oxidation in fuel cells

    DOE Patents [OSTI]

    Adzic, Radoslav R.; Marinkovic, Nebojsa S.

    2001-01-01

    Binary and ternary electrocatalysts are provided for oxidizing alcohol in a fuel cell. The binary electrocatalyst includes 1) a substrate selected from the group consisting of NiWO.sub.4 or CoWO.sub.4 or a combination thereof, and 2) Group VIII noble metal catalyst supported on the substrate. The ternary electrocatalyst includes 1) a substrate as described above, and 2) a catalyst comprising Group VIII noble metal, and ruthenium oxide or molybdenum oxide or a combination thereof, said catalyst being supported on said substrate.

  3. Oct08.doc

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    8 ANL/EVS/NL-08-10 Technical Contact: Brad W. Orr Phone: 630-252-8665 Email: brad.orr@anl.gov Editor: Donna J. Holdridge Contributor: John Schatz Website: http://www.arm.gov ACRF Southern Great Plains Newsletter is published by Argonne National Laboratory, managed by UChicago Argonne, LLC, for the U.S. Department of Energy under contract number DE-AC02-06CH11357. Leadership Noble County Members Tour SGP Site Members of the non-profit organization Leadership Noble County

  4. Progress on radiometric dating of Wolfcamp brines using /sup 4/He and /sup 40/Ar

    SciTech Connect (OSTI)

    Zaikowski, A.; Kosanke, B.J.; Hubbard, N.

    1984-01-01

    Ground water samples (brines) from deep wells in the Palo Duro Basin, Texas are being analyzed for noble gases in an attempt to obtain radiometric ages for these brines. The brines contain radiogenic /sup 4/He and /sup 40/Ar produced from the radioactive decay of U, Th, and K. Consideration of hydrochemical data for the brines, various isotopic, chemical, and mineralogical data for the aquifer rocks and noble gas production rates allow estimating the age of the brines to be about 130 million years at two wells. At a third well interaquifer mixing has occurred and the age is presently indeterminate. 9 references, 3 figures, 1 table.

  5. Carbon monoxide tolerant electrocatalyst with low platinum loading and a process for its preparation

    DOE Patents [OSTI]

    Adzic, Radoslav; Brankovic, Stanko; Wang, Jia

    2003-12-30

    An electrocatalyst is provided for use in a fuel cell that has low platinum loading and a high tolerance to carbon monoxide poisoning. The fuel cell anode includes an electrocatalyst that has a conductive support material, ruthenium nanoparticles reduced in H.sub.2 and a Group VIII noble metal in an amount of between about 0.1 and 25 wt % of the ruthenium nanoparticles, preferably between about 0.5 and 15 wt %. The preferred Group VIII noble metal is platinum. In one embodiment, the anode can also have a perfluorinated polymer membrane on its surface.

  6. High temperature superconducting composite conductor and method for manufacturing the same

    DOE Patents [OSTI]

    Holesinger, Terry G.; Bingert, John F.

    2002-01-01

    A high temperature superconducting composite conductor is provided including a high temperature superconducting material surrounded by a noble metal layer, the high temperature superconducting composite conductor characterized as having a fill factor of greater than about 40. Additionally, the conductor can be further characterized as containing multiple cores of high temperature superconducting material surrounded by a noble metal layer, said multiple cores characterized as having substantially uniform geometry in the cross-sectional dimensions. Processes of forming such a high temperature superconducting composite conductor are also provided.

  7. Galvanic currents and hydrogen permeation currents caused by galvanic coupling

    SciTech Connect (OSTI)

    Armacanquil, M.E. ); Harasyn, D.E. )

    1990-05-01

    This paper reports on galvanic coupling and hydrogen permeation experiments performed in a Devanathan-Stachurski cell to measure simultaneously the galvanic currents and the hydrogen permeation currents in an attempt to determine the extent of hydrogen charging into noble metals as a result of galvanic coupling. Large amounts of hydrogen permeated through the more noble element of the couple. The magnitude of the hydrogen permeation flux varied depending on the galvanic coupling conditions. No simple direct relationship between galvanic currents and hydrogen permeation currents was observed, although large hydrogen permeation currents were usually developed whenever large galvanic currents were established.

  8. Conceptual design of a high throughput electrorefining of a uranium by using graphite cathode

    SciTech Connect (OSTI)

    Lee, J.H.; Kang, Y.H.; Hwang, S.C.; Park, S.B.; Shim, J.B.; Lee, H.S.; Kim, E.H.; Park, S.W.

    2007-07-01

    Conceptual designing of a high throughput electro-refiner was performed by using basic experimental data and a commercial computational fluid dynamic code, CFX. An electro-refiner concept equipped with a graphite cathode bundle was designed to recover a high purity uranium product continuously without a noble metal contamination. The performance of the process for a decontamination of a noble metal in a uranium product was evaluated as a function of the process parameters such as the rotation speeds of the stirrer and the anode basket. (authors)

  9. PCTFE as a solution to birefringence in atom trap viewports

    SciTech Connect (OSTI)

    Warner, C. L.; Behr, J. A.; Gorelov, A.

    2014-11-15

    We have developed and characterized optical viewports with the glass-to-metal seal made by the plastic PCTFE (polychlorotrifluoroethylene). The goal is to reduce stress-induced birefringence while maintaining ultra-high vacuum compatibility. We have maintained a Stokes parameter S{sub 3} of 0.9986, and achieved <5 × 10{sup −11} Torr partial pressure of air. We have also measured the diffusion and permeation of helium through PCTFE and placed upper limits on nitrogen, oxygen, and argon permeation, as PCTFE has been suggested as an o-ring for transport of environmental noble gas samples, though we know of no other noble gas measurements.

  10. California Statewide Plug-In Electric Vehicle Infrastructure Assessment

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Prepared for: California Energy Commission Prepared by: National Renewable Energy Laboratory A l t e r n a t i v e a n d R e n e w a b l e F u e l a n d V e h i c l e T e c h n o l o g y P r o g r a m F I N A L P R O J E C T R E P O R T CALIFORNIA STATEWIDE PLUG-IN ELECTRIC VEHICLE INFRASTRUCTURE ASSESSMENT May 2014 CEC-600-2014-003 Prepared by: Primary Author(s): Marc Melaina, Ph.D. Michael Helwig, Ph.D. National Renewable Energy Laboratory 15013 Denver West Parkway Golden, CO 80401 Agreement

  11. PowerPoint Presentation

    National Nuclear Security Administration (NNSA)

    4 40 350 150 169 24 56 S T A T E L IN E R D . W O R N A L L R D . HO LM ES RD . TROO ST AVE. P R O S P E C T SWOPE PARK ZOO 87th STREET 31st STREET INDEPENDENCE AVE. 23rd STREET BLUE PARKWAY MAIN STREET B O T T S R D 140TH STREET BLUE RIDGE BLVD RED BRIDGE RD G R A N D V I E W R D VOLKER BLVD. UMKC ROCKHURST UNIVERSITY COUNTRY CLUB PLAZA 110th L A M A R A V E . R O E A V E . N A L L A V E . Q U I V I R A R D . K A N S A S M I S S O U R I TRUMAN SPORTS COMPLEX KANSAS SPEEDWAY WORLDS OF FUN HARRY

  12. Ultra-high sensitivity radiation detection apparatus and method

    DOE Patents [OSTI]

    Gross, Kenneth C. (Bolingbrook, IL); Valentine, John D. (Cincinnati, OH); Markum, Francis (Joliet, IL); Zawadzki, Mary (Rouses Point, NY); Dickerman, Charles (Downers Grove, IL)

    1999-01-01

    A method and apparatus are provided to concentrate and detect very low levels of radioactive noble gases from the atmosphere. More specifically the invention provides a method and apparatus to concentrate xenon, krypton and radon in an organic fluid and to detect these gases by the radioactive emissions.

  13. U.S. Department of Energy, Nevada Operations Office Environmental Monitoring Program, Summary Data Report, First Calendar Quarter 1996

    SciTech Connect (OSTI)

    Black, S.C.; Townsednd, Y.E.

    1996-11-01

    This report discusses environmental surveillance activities conducted on the Nevada Test Site during the first calendar quarter of 1996. Surveillance activities included collection and analysis of air, noble gas, tritiated water vapor, and other water samples. Samples were analyzed for both radiological and non-radiological effluents.

  14. Advanced neutron absorber materials

    DOE Patents [OSTI]

    Branagan, Daniel J.; Smolik, Galen R.

    2000-01-01

    A neutron absorbing material and method utilizing rare earth elements such as gadolinium, europium and samarium to form metallic glasses and/or noble base nano/microcrystalline materials, the neutron absorbing material having a combination of superior neutron capture cross sections coupled with enhanced resistance to corrosion, oxidation and leaching.

  15. METAL COMPOSITIONS

    DOE Patents [OSTI]

    Seybolt, A.U.

    1959-02-01

    Alloys of uranium which are strong, hard, and machinable are presented, These alloys of uranium contain bctween 0.1 to 5.0% by weight of at least one noble metal such as rhodium, palladium, and gold. The alloys may be heat treated to obtain a product with iniproved tensile and compression strengths,

  16. Metal oxide films on metal

    DOE Patents [OSTI]

    Wu, Xin D. (Los Alamos, NM); Tiwari, Prabhat (Los Alamos, NM)

    1995-01-01

    A structure including a thin film of a conductive alkaline earth metal oxide selected from the group consisting of strontium ruthenium trioxide, calcium ruthenium trioxide, barium ruthenium trioxide, lanthanum-strontium cobalt oxide or mixed alkaline earth ruthenium trioxides thereof upon a thin film of a noble metal such as platinum is provided.

  17. National emmission standards for hazardous air pollutants, Submittal -- 1993

    SciTech Connect (OSTI)

    Black, S.C.

    1994-06-01

    This report discusses the effects on the environment caused by weapons testing at the Nevada Test Site. Topics include: emission of radionuclides into the air, atmospheric pumping of noble gases, tunnel operations, drillbacks, laboratories, radioactive waste management site, and plutonium contamination of surface areas.

  18. 17th DOE nuclear air cleaning conference: proceedings. Volume 2

    SciTech Connect (OSTI)

    First, M.W.

    1983-02-01

    Volume 2 contains papers presented at the following sessions: adsorption; noble gas treatment; personnel education and training; filtration and filter testing; measurement and instrumentation; air cleaning equipment response to accident related stress; containment venting air cleaning; and an open end session. Twenty-eight papers were indexed separately for inclusion in the Energy Data Base. Ten papers had been entered earlier.

  19. Method and means of monitoring the effluent from nuclear facilities

    DOE Patents [OSTI]

    Lattin, Kenneth R.; Erickson, Gerald L.

    1976-01-01

    Radioactive iodine is detected in the effluent cooling gas from a nuclear reactor or nuclear facility by passing the effluent gas through a continuously moving adsorbent filter material which is then purged of noble gases and conveyed continuously to a detector of radioactivity. The purging operation has little or no effect upon the concentration of radioactive iodine which is adsorbed on the filter material.

  20. Explosive laser light initiation of propellants

    DOE Patents [OSTI]

    Piltch, M.S.

    1993-05-18

    A improved initiator for artillery shell using an explosively generated laser light to uniformly initiate the propellent. A small quantity of a high explosive, when detonated, creates a high pressure and temperature, causing the surrounding noble gas to fluoresce. This fluorescence is directed into a lasing material, which lases, and directs laser light into a cavity in the propellant, uniformly initiating the propellant.

  1. Biomass-derived Lignin to Jet Fuel Range Hydrocarbons via Aqueous Phase Hydrodeoxygenation

    SciTech Connect (OSTI)

    Wang, Hongliang; Ruan, Hao; Pei, Haisheng; Wang, Huamin; Chen, Xiaowen; Tucker, Melvin P.; Cort, John R.; Yang, Bin

    2015-09-14

    A catalytic process, involving the hydrodeoxygenation (HDO) of the dilute alkali extracted corn stover lignin catalysed by noble metal catalyst (Ru/Al2O3) and acidic zeolite (H+-Y), to produce lignin-substructure-based hydrocarbons (C7-C18), primarily C12-C18 cyclic structure hydrocarbons in the jet fuel range, was demonstrated.

  2. Redox mediation and hydrogen-generation with bipyridinium reagents

    DOE Patents [OSTI]

    Wrighton, Mark S.; Bookbinder, Dana C.; Bruce, James A.; Dominey, Raymond N.; Lewis, Nathan S.

    1984-03-27

    A variety of redox mediating agents employing bipyridinium reagents and such reagents in conjunction with dispersed noble metals, such as platinium, are disclosed as coatings for substrates and electrodes. The agents may be charged by an applied voltage or by photoelectric effects or may be equilibrated with hydrogen. The agents are useful in reducing biological materials and electrolytic hydrogen production.

  3. Magnesium transport extraction of transuranium elements from LWR fuel

    DOE Patents [OSTI]

    Ackerman, John P.; Battles, James E.; Johnson, Terry R.; Miller, William E.; Pierce, R. Dean

    1992-01-01

    A process of separating transuranium actinide values from uranium values present in spent nuclear oxide fuels which contain rare earth and noble metal fission products. The oxide fuel is reduced with Ca metal in the presence of CaCl.sub.2 and a U-Fe alloy containing not less than about 84% by weight uranium at a temperature in the range of from about 800.degree. C. to about 850.degree. C. to produce additional uranium metal which dissolves in the U-Fe alloy raising the uranium concentration and having transuranium actinide metals and rare earth fission product metals and the noble metal fission products dissolved therein. The CaCl.sub.2 having CaO and fission products of alkali metals and the alkali earth metals and iodine dissolved therein is separated and electrolytically treated with a carbon electrode to reduce the CaO to Ca metal while converting the carbon electrode to CO and CO.sub.2. The Ca metal and CaCl.sub.2 is recycled to reduce additional oxide fuel. The U-Fe alloy having transuranium actinide metals and rare earth fission product metals and the noble metal fission products dissolved therein is contacted with Mg metal which takes up the actinide and rare earth fission product metals. The U-Fe alloy retains the noble metal fission products and is stored while the Mg is distilled and recycled leaving the transuranium actinide and rare earth fission products isolated.

  4. SISGR-Fundamental Experimental and Theoretical Studies on a Novel Family of Oxide Catalyst Supports for Water Electrolysis

    SciTech Connect (OSTI)

    Kumta, Prashant

    2014-10-03

    Identification and development of non-noble metal based electro-catalysts or electro-catalysts with significant reduction of expensive noble metal contents (E.g. IrO2, Pt) with comparable electrochemical performance as the standard noble metal/metal oxide for proton exchange membrane (PEM) based water electrolysis would constitute a major breakthrough in the generation of hydrogen by water electrolysis. Accomplishing such a system would not only result reduction of the overall capital costs of PEM based water electrolyzers, but also help attain the targeted hydrogen production cost [< $ 3.0 / gallon gasoline equivalent (gge)] comparable to conventional liquid fuels. In line with these goals, it was demonstrated that fluorine doped IrO2 thin films and nanostructured high surface area powders display remarkably higher electrochemical activity, and comparable durability as pure IrO2 electro-catalyst for the oxygen evolution reaction (OER) in PEM based water electrolysis. Furthermore, corrosion resistant SnO2 and NbO2 support has been doped with F and coupled with IrO2 or RuO2 for use as an OER electro-catalyst. A solid solution of SnO2:F or NbO2:F with only 20 - 30 mol.% IrO2 or RuO2 yielding a rutile structure in the form of thin films and bulk nanoparticles displays similar electrochemical activity and stability as pure IrO2/RuO2. This would lead to more than 70 mol.% reduction in the noble metal oxide content. Novel nanostructured ternary (Ir,Sn,Nb)O2 thin films of different compositions FUNDAMENTAL STUDY OF NANOSTRUCTURED ELECTRO-CATALYSTS WITH REDUCED NOBLE METAL CONTENT FOR PEM BASED WATER ELECTROLYSIS 4 have also been studied. It has been shown that (Ir0.40Sn0.30Nb0.30)O2 shows similar electrochemical activity and enhanced chemical robustness as compared to pure IrO2. F doping of the ternary (Ir,Sn,Nb)O2 catalyst helps in further decreasing the noble metal oxide content of the catalyst. As a result, these reduced noble metal oxide catalyst systems would

  5. Separation of metallic residues from the dissolution of a high-burnup BWR fuel using nitrogen trifluoride

    SciTech Connect (OSTI)

    McNamara, Bruce K.; Buck, Edgar C.; Soderquist, Chuck Z.; Smith, Frances N.; Mausolf, Edward J.; Scheele, Randall D.

    2014-02-10

    Nitrogen trifluoride (NF3) was used to fluorinate the metallic residue from the dissolution of a high burnup, boiling water reactor fuel (?70 MWd/kgU). The metallic residue included the noble metal phase (containing ruthenium, rhodium, palladium, technetium, and molybdenum), and smaller amounts of zirconium, selenium, tellurium, and silver. Exposing the noble metal phase to 10% NF3 in argon between 400 and 550?C, removed molybdenum and technetium near 400?C as their volatile fluorides, and ruthenium near 500?C as its volatile fluoride. The events were thermally and temporally distinct and the conditions specified are a recipe to separate these transition metals from each other and from the noble metal phase nonvolatile residue. Depletion of the volatile fluorides resulted in substantial exothermicity. Thermal excursion behavior was recorded under non-adiabatic, isothermal conditions that typically minimize heat release. Physical characterization of the metallic noble phase and its thermal behavior are consistent with high kinetic velocity reactions encouraged by the nanoparticulate phase or perhaps catalytic influences of the mixed platinum metals with nearly pure phase structure. Post-fluorination, only two phases were present in the residual nonvolatile fraction. These were identified as a nano-crystalline, metallic palladium cubic phase and a hexagonal rhodium trifluoride (RhF3) phase. The two phases were distinct as the sub-m crystallites of metallic palladium were in contrast to the RhF3 phase, which grew from the parent nano-crystalline noble-metal phase during fluorination, to acicular crystals exceeding 20-m in length.

  6. Review of Catalytic Hydrogen Generation in the Defense Waste Processing Facility (DWPF) Chemical Processing Cell

    SciTech Connect (OSTI)

    Koopman, D. C.

    2004-12-31

    This report was prepared to fulfill the Phase I deliverable for HLW/DWPF/TTR-98-0018, Rev. 2, ''Hydrogen Generation in the DWPF Chemical Processing Cell'', 6/4/2001. The primary objective for the preliminary phase of the hydrogen generation study was to complete a review of past data on hydrogen generation and to prepare a summary of the findings. The understanding was that the focus should be on catalytic hydrogen generation, not on hydrogen generation by radiolysis. The secondary objective was to develop scope for follow-up experimental and analytical work. The majority of this report provides a summary of past hydrogen generation work with radioactive and simulated Savannah River Site (SRS) waste sludges. The report also includes some work done with Hanford waste sludges and simulants. The review extends to idealized systems containing no sludge, such as solutions of sodium formate and formic acid doped with a noble metal catalyst. This includes general information from the literature, as well as the focused study done by the University of Georgia for the SRS. The various studies had a number of points of universal agreement. For example, noble metals, such as Pd, Rh, and Ru, catalyze hydrogen generation from formic acid and formate ions, and more acid leads to more hydrogen generation. There were also some points of disagreement between different sources on a few topics such as the impact of mercury on the noble metal catalysts and the identity of the most active catalyst species. Finally, there were some issues of potential interest to SRS that apparently have not been systematically studied, e.g. the role of nitrite ion in catalyst activation and reactivity. The review includes studies covering the period from about 1924-2002, or from before the discovery of hydrogen generation during simulant sludge processing in 1988 through the Shielded Cells qualification testing for Sludge Batch 2. The review of prior studies is followed by a discussion of proposed

  7. Fischer-Tropsch activity for non-promoted cobalt-on-alumina catalysts

    DOE Patents [OSTI]

    Singleton, Alan H.; Oukaci, Rachid; Goodwin, James G.

    2001-01-01

    Cobalt catalysts, and processes employing these inventive catalysts, for hydrocarbon synthesis. The inventive catalyst comprises cobalt on an alumina support and is not promoted with any noble or near noble metals. In one aspect of the invention, the alumina support preferably includes a dopant in an amount effective for increasing the activity of the inventive catalyst. The dopant is preferably a titanium dopant. In another aspect of the invention, the cobalt catalyst is preferably reduced in the presence of hydrogen at a water vapor partial pressure effective to increase the activity of the cobalt catalyst for hydrocarbon synthesis. The water vapor partial pressure is preferably in the range of from 0 to about 0.1 atmospheres.

  8. Molten salt extraction of transuranic and reactive fission products from used uranium oxide fuel

    DOE Patents [OSTI]

    Herrmann, Steven Douglas

    2014-05-27

    Used uranium oxide fuel is detoxified by extracting transuranic and reactive fission products into molten salt. By contacting declad and crushed used uranium oxide fuel with a molten halide salt containing a minor fraction of the respective uranium trihalide, transuranic and reactive fission products partition from the fuel to the molten salt phase, while uranium oxide and non-reactive, or noble metal, fission products remain in an insoluble solid phase. The salt is then separated from the fuel via draining and distillation. By this method, the bulk of the decay heat, fission poisoning capacity, and radiotoxicity are removed from the used fuel. The remaining radioactivity from the noble metal fission products in the detoxified fuel is primarily limited to soft beta emitters. The extracted transuranic and reactive fission products are amenable to existing technologies for group uranium/transuranic product recovery and fission product immobilization in engineered waste forms.

  9. Methods and apparatus for cleaning objects in a chamber of an optical instrument by generating reactive ions using photon radiation

    SciTech Connect (OSTI)

    Klebanoff, Leonard E.; Delgado, Gildardo R.; Hollenshead, Jeromy T.; Umstadter, Karl R.; Starodub, Elena; Zhuang, Guorong V.

    2015-10-13

    An optical instrument, including a chamber, an object exposed to an interior of the chamber, a source of low-pressure gas, the gas comprising at least one of low-pressure molecular hydrogen gas, low-pressure molecular oxygen and a low-pressure noble gas, the source of low pressure gas being fluidly coupled to the chamber, a low voltage source electrically coupled between the object and a remaining portion of the instrument that is exposed to the interior of the chamber so as to maintain the object at a low voltage relative to the remaining portion, and an EUV/VUV light source adapted to direct EUV/VUV light through the low pressure gas in the chamber onto the object. In such a system, when the EUV/VUV light source is activated ions of the low-pressure gas are formed and directed to the object. The ions may be ions of Hydrogen, Oxygen or a noble gas.

  10. Recent advances of lanthanum-based perovskite oxides for catalysis

    SciTech Connect (OSTI)

    Zhu, Huiyuan; Zhang, Pengfei; Dai, Sheng

    2015-09-21

    There is a need to reduce the use of noble metal elements especially in the field of catalysis, where noble metals are ubiquitously applied. To this end, perovskite oxides, an important class of mixed oxide, have been attracting increasing attention for decades as potential replacements. Benefiting from the extraordinary tunability of their compositions and structures, perovskite oxides can be rationally tailored and equipped with targeted physical and chemical properties e.g. redox behavior, oxygen mobility, and ion conductivity for enhanced catalysis. Recently, the development of highly efficient perovskite oxide catalysts has been extensively studied. This review article summarizes the recent development of lanthanum-based perovskite oxides as advanced catalysts for both energy conversion applications and traditional heterogeneous reactions.

  11. Methane activation using Kr and Xe in a dielectric barrier discharge reactor

    SciTech Connect (OSTI)

    Jo, Sungkwon; Lee, Dae Hoon Kim, Kwan-Tae; Kang, Woo Seok; Song, Young-Hoon

    2014-10-15

    Methane has interested many researchers as a possible new energy source, but the high stability of methane causes a bottleneck in methane activation, limiting its practical utilization. To determine how to effectively activate methane using non-thermal plasma, the conversion of methane is measured in a planar-type dielectric barrier discharge reactor using three different noble gases—Ar, Kr, and Xe—as additives. In addition to the methane conversion results at various applied voltages, the discharge characteristics such as electron temperature and electron density were calculated through zero-dimensional calculations. Moreover, the threshold energies of excitation and ionization were used to distinguish the dominant particle for activating methane between electrons, excited atoms, and ionized atoms. From the experiments and calculations, the selection of the additive noble gas is found to affect not only the conversion of methane but also the selectivity of product gases even under similar electron temperature and electron density conditions.

  12. Recent advances of lanthanum-based perovskite oxides for catalysis

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhu, Huiyuan; Zhang, Pengfei; Dai, Sheng

    2015-09-21

    There is a need to reduce the use of noble metal elements especially in the field of catalysis, where noble metals are ubiquitously applied. To this end, perovskite oxides, an important class of mixed oxide, have been attracting increasing attention for decades as potential replacements. Benefiting from the extraordinary tunability of their compositions and structures, perovskite oxides can be rationally tailored and equipped with targeted physical and chemical properties e.g. redox behavior, oxygen mobility, and ion conductivity for enhanced catalysis. Recently, the development of highly efficient perovskite oxide catalysts has been extensively studied. This review article summarizes the recent developmentmore » of lanthanum-based perovskite oxides as advanced catalysts for both energy conversion applications and traditional heterogeneous reactions.« less

  13. Short protection device for stack of electrolytic cells

    DOE Patents [OSTI]

    Katz, Murray; Schroll, Craig R.

    1985-10-22

    Electrical short protection is provided in an electrolytic cell stack by the combination of a thin, nonporous ceramic shield and a noble metal foil disposed on opposite sides of the sealing medium in a gas manifold gasket. The thin ceramic shield, such as alumina, is placed between the porous gasket and the cell stack face at the margins of the negative end plate to the most negative cells to impede ion current flow. The noble metal foil, for instance gold, is electrically coupled to the negative potential of the stack to collect positive ions at a harmless location away from the stack face. Consequently, corrosion products from the stack structure deposit on the foil rather than on the stack face to eliminate electrical shorting of cells at the negative end of the stack.

  14. Pressure cryocooling protein crystals

    DOE Patents [OSTI]

    Kim, Chae Un; Gruner, Sol M.

    2011-10-04

    Preparation of cryocooled protein crystal is provided by use of helium pressurizing and cryocooling to obtain cryocooled protein crystal allowing collection of high resolution data and by heavier noble gas (krypton or xenon) binding followed by helium pressurizing and cryocooling to obtain cryocooled protein crystal for collection of high resolution data and SAD phasing simultaneously. The helium pressurizing is carried out on crystal coated to prevent dehydration or on crystal grown in aqueous solution in a capillary.

  15. The application of electrorefining for recovery and purification of fuel discharged from the Integral Fast Reactor

    SciTech Connect (OSTI)

    Burris, L.; Steunenberg, R.K.; Miller, W.E.

    1986-01-01

    An electrorefining process employing a molten salt electrolyte and a molten cadmium anode is proposed for the separation of uranium and plutonium from fission products and cladding material in discharged IFR driver fuel. The use of a liquid cadmium anode, which is the unique feature of the process, permits selective dissolution of the fuel from the cladding and prevents electrolytic corrosion of the steel container and contamination of the product by noble metal fission products.

  16. Matrix Infrared Spectroscopic and Computational Investigations of Novel Small Uranium Containing Molecules - Final Technical Report

    SciTech Connect (OSTI)

    Andrews, Lester

    2014-10-17

    Direct reactions of f-element uranium, thorium and lanthanide metal atoms were investigated with small molecules. These metal atoms were generated by laser ablation and mixed with the reagent molecules then condensed with noble gases at 4K. The products were analyzed by absorption of infrared light to measure vibrational frequencies which were confirmed by quantum chemical calculations. We have learned more about the reactivity of uranium atoms with common molecules, which will aid in the develolpment of further applications of uranium.

  17. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CCN and Vertical Velocity Influences Submitter: Hudson, J. G., Desert Research Institute Area of Research: Cloud-Aerosol-Precipitation Interactions Working Group(s): Cloud-Aerosol-Precipitation Interactions Journal Reference: Hudson JG and S Noble. 2013. "CCN and vertical velocity influences on droplet concentrations and supersaturations in clean and polluted stratus clouds." Journal of the Atmospheric Sciences, 71(1), 10.1175/JAS-D-13-086.1. Figure 1. Effective cloud supersaturation

  18. FE Petroleum Reserves News | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Petroleum Reserves News FE Petroleum Reserves News RSS April 9, 2015 Contracts Awarded to Repurchase Oil for the Strategic Petroleum Reserve The U. S. Department of Energy announced the award of contracts for delivery of crude oil to the Strategic Petroleum Reserve. BP Products North America, Inc., will deliver 2,197,500 barrels and Noble Americas will deliver 2,000,000 barrels to the Reserve's Bryan Mound site in Freeport, Texas. Deliveries are expected to be completed by July 31, 2015.

  19. Simultaneous in-situ synthesis and characterization of Co@Cu core-shell nanoparticle arrays

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    McKeown, Joseph T.; Wu, Yueying; Fowlkes, Jason D.; Rack, Philip D.; Campbell, Geoffrey H.

    2014-12-23

    Core-shell nanostructures have attracted much attention due to their unique and tunable properties relative to bulk structures of the same materials, making core-shell nanoparticles candidates for a variety of applications with multiple functionalities.[1,2] Intriguing magnetic behavior can be tailored by variation of size, interface, crystal orientation, and composition, and core-shell nanostructures with noble-metal shells yield novel optical responses[3] and enhanced electrocatalytic activity.[4

  20. EC Publications

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Computational Investigation of Noble Gas Adsorption and Separation by Nanoporous Materials admin 2016-04-18T20:58:24+00:00 Popular Downloads Solar Energy Grid Integration Systems: Final Report of the Florida Solar Energy Center Team (11367 downloads) Modeling System Losses in PVsyst (9344 downloads) Numerical Manufacturing And Design Tool (NuMAD v2.0) for Wind Turbine Blades: User's Guide (7613 downloads) Solar Energy Grid Integration Systems (SEGIS) Proactive Intelligent Advances for

  1. Wet-chemical systems and methods for producing black silicon substrates

    DOE Patents [OSTI]

    Yost, Vernon; Yuan, Hao-Chih; Page, Matthew

    2015-05-19

    A wet-chemical method of producing a black silicon substrate. The method comprising soaking single crystalline silicon wafers in a predetermined volume of a diluted inorganic compound solution. The substrate is combined with an etchant solution that forms a uniform noble metal nanoparticle induced Black Etch of the silicon wafer, resulting in a nanoparticle that is kinetically stabilized. The method comprising combining with an etchant solution having equal volumes acetonitrile/acetic acid:hydrofluoric acid:hydrogen peroxide.

  2. Electrocatalysts having gold monolayers on platinum nanoparticle cores, and uses thereof

    DOE Patents [OSTI]

    Adzic, Radoslav; Zhang, Junliang

    2010-04-27

    The invention relates to gold-coated particles useful as fuel cell electrocatalysts. The particles are composed of an electrocatalytically active core at least partially encapsulated by an outer shell of gold or gold alloy. The invention more particularly relates to such particles having a noble metal-containing core, and more particularly, a platinum or platinum alloy core. In other embodiments, the invention relates to fuel cells containing these electrocatalysts and methods for generating electrical energy therefrom.

  3. Electrocatalysts having platium monolayers on palladium, palladium alloy, and gold alloy core-shell nanoparticles, and uses thereof

    DOE Patents [OSTI]

    Adzic, Radoslav; Mo, Yibo; Vukmirovic, Miomir; Zhang, Junliang

    2010-12-21

    The invention relates to platinum-coated particles useful as fuel cell electrocatalysts. The particles are composed of a noble metal or metal alloy core at least partially encapsulated by an atomically thin surface layer of platinum atoms. The invention particularly relates to such particles having a palladium, palladium alloy, gold alloy, or rhenium alloy core encapsulated by an atomic monolayer of platinum. In other embodiments, the invention relates to fuel cells containing these electrocatalysts and methods for generating electrical energy therefrom.

  4. Application of Diffusion Monte Carlo to Materials Dominated by van der Waals Interactions

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Benali, Anouar; Shulenburger, Luke; Romero, Nichols A.; Kim, Jeongnim; von Lilienfeld, O. Anatole

    2014-06-12

    Van der Waals forces are notoriously difficult to account for from first principles. We perform extensive calculation to assess the usefulness and validity of diffusion quantum Monte Carlo when applied to van der Waals forces. We present results for noble gas solids and clusters - archetypical van der Waals dominated assemblies, as well as a relevant pi-pi stacking supramolecular complex: DNA + intercalating anti-cancer drug Ellipticine.

  5. A new paradigm: near-complete recycling of spent fuel - A path to sustainable nuclear energy

    SciTech Connect (OSTI)

    Del Cul, Guillermo D.; Spencer, Barry B.; Collins, Emory D.

    2007-07-01

    Recent studies indicate that maximized recycling, where more than 95% of the components of spent nuclear fuel are reused, can be economically justified and can reduce the mass of waste products by a substantial amount. The potentially removable and reusable components include the uranium, zirconium from the cladding, structural hardware, certain noble metal fission products, and the transuranic radionuclides. The approach to maximizing recycle and minimizing emissions and wastes should improve public acceptance of nuclear energy. (authors)

  6. Electrocatalysts having Platinum Monolayers on Palladium, Palladium Alloy,

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and Gold Alloy Core-Shell Nanoparticles, and Uses Thereof - Energy Innovation Portal Hydrogen and Fuel Cell Hydrogen and Fuel Cell Find More Like This Return to Search Electrocatalysts having Platinum Monolayers on Palladium, Palladium Alloy, and Gold Alloy Core-Shell Nanoparticles, and Uses Thereof Brookhaven National Laboratory Contact BNL About This Technology Publications: PDF Document Publication Platinum Monolayer on Nonnoble Metal-Noble Metal Core-Shell Nanoparticle Electrocatalysts

  7. Microsoft Word - DOE-ID-14-086 Virginia Tech EC B3-6.doc

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    6 SECTION A. Project Title: Thermal Conductivity of Metallic Fuels - Virginia Polytechnic Institute and State University SECTION B. Project Description Virginia Tech, in collaboration with Idaho National Laboratory and Oak Ridge National Laboratory, proposes to determine the electronic structure and phonon spectrum of U-Zr and Np-Zr alloys with and without the presence of noble gases. U-Zr and Np-Zr alloys will be fabricated for a composition range from 0 to 20% Zr. The thermal conductivity of

  8. Process for treating fission waste

    DOE Patents [OSTI]

    Rohrmann, Charles A.; Wick, Oswald J.

    1983-01-01

    A method is described for the treatment of fission waste. A glass forming agent, a metal oxide, and a reducing agent are mixed with the fission waste and the mixture is heated. After melting, the mixture separates into a glass phase and a metal phase. The glass phase may be used to safely store the fission waste, while the metal phase contains noble metals recovered from the fission waste.

  9. Process for treating fission waste. [Patent application

    DOE Patents [OSTI]

    Rohrmann, C.A.; Wick, O.J.

    1981-11-17

    A method is described for the treatment of fission waste. A glass forming agent, a metal oxide, and a reducing agent are mixed with the fission waste and the mixture is heated. After melting, the mixture separates into a glass phase and a metal phase. The glass phase may be used to safely store the fission waste, while the metal phase contains noble metals recovered from the fission waste.

  10. Improved Dye-Sensitized Solar Cell (DSSC) for Higher Energy Conversion

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Efficiency - Energy Innovation Portal Dye-Sensitized Solar Cell (DSSC) for Higher Energy Conversion Efficiency University of Colorado Contact CU About This Technology Publications: PDF Document Publication CU2480B (Improved DSSC) Marketing Summary.pdf (213 KB) <em>DSSC schematic.</em> DSSC schematic. Technology Marketing Summary A University of Colorado research group led by Rich Noble has developed a novel approach to dye-sensitized solar cells that increases solar-to-electrical

  11. Radon and helium in soil gases in the Phlegraean Fields, central Italy

    SciTech Connect (OSTI)

    Lombardi, S. ); Reimer, G.M. )

    1990-05-01

    The distribution and migration of radon and helium soil-gas concentrations in the Phlegraean Fields, Italy, are controlled by the tectonic features of the area. Radon is supplied from surficial sources and helium has both surficial and deep origins. There is no direct correlation between the two noble gases on a point-to-point basis but the areal distribution of both gases is similar, suggesting that the distribution is controlled primarily by fractures and movement of geothermal fluids.

  12. Pt and Pd catalyzed oxidation of Li2O2 and DMSO during Li–O2 battery charging

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Gittleson, Forrest S.; Ryu, Won-Hee; Schwab, Mark; Tong, Xiao; Taylor, André D.

    2016-01-01

    Rechargeable Li-O2 and Li-air batteries require electrode and electrolyte materials that synergistcally promote long-term cell operation. We investigate the role of noble metals Pt and Pd as catalysts for the Li-O2 oxidation process and their compatibility with a dimethyl sulfoxide (DMSO) based electrolyte. Lastly, we identify a basis for low potential Li2O2 evolution followed by oxidative decomposition of the electrolyte to form carbonate side products.

  13. Mound Facility activities in chemical and physical research: July-December 1979

    SciTech Connect (OSTI)

    Not Available

    1980-06-18

    Research is reported in the following fields: isotope separation (Ar, C, He, Kr, Ne, O, Xe), low-temperature research (H intermolecular potential functions, gas analysis in trennschaukel), separation chemistry (/sup 229/Th, /sup 231/Pa, /sup 230/Th, /sup 234/U), separation research (liquid thermal diffusion, Ca isotope separation, molecular beam scattering, mutual diffusion of noble gas mixtures, lithium chemical exchange with cryptands), and calculations in plutonium chemistry (algorithms, valence in natural water). (DLC)

  14. Porous Carbon Supports: Recent Advances with Various Morphologies and Compositions

    SciTech Connect (OSTI)

    Zhang, Pengfei; Zhu, Huiyuan; Dai, Sheng

    2015-08-31

    The importance of porous carbon as the support material is well recognized in the catalysis community, and it would be even more attractive if several characteristics are considered, such as the stability in acidic and basic media or the ease of noble metal recovery through complete burn off. Because it is still difficult to obtain constant properties even from batch to batch, activated carbons are not popular in industrial catalysis now.

  15. Hard and low friction nitride coatings and methods for forming the same

    DOE Patents [OSTI]

    Erdemir, Ali; Urgen, Mustafa; Cakir, Ali Fuat; Eryilmaz, Osman Levent; Kazmanli, Kursat; Keles, Ozgul

    2007-05-01

    An improved coating material possessing super-hard and low friction properties and a method for forming the same. The improved coating material includes the use of a noble metal or soft metal homogeneously distributed within a hard nitride material. The addition of small amounts of such metals into nitrides such as molybdenum nitride, titanium nitride, and chromium nitride results in as much as increasing of the hardness of the material as well as decreasing the friction coefficient and increasing the oxidation resistance.

  16. Salt transport extraction of transuranium elements from lwr fuel

    DOE Patents [OSTI]

    Pierce, R. Dean; Ackerman, John P.; Battles, James E.; Johnson, Terry R.; Miller, William E.

    1992-01-01

    A process of separating transuranium actinide values from uranium values present in spent nuclear oxide fuels which contain rare earth and noble metal fission products. The oxide fuel is reduced with Ca metal in the presence of CaCl.sub.2 and a Cu--Mg alloy containing not less than about 25% by weight Mg at a temperature in the range of from about 750.degree. C. to about 850.degree. C. to precipitate uranium metal and some of the noble metal fission products leaving the Cu--Mg alloy having transuranium actinide metals and rare earth fission product metals and some of the noble metal fission products dissolved therein. The CaCl.sub.2 having CaO and fission products of alkali metals and the alkali earth metals and iodine dissolved therein is separated and electrolytically treated with a carbon electrode to reduce the CaO to Ca metal while converting the carbon electrode to CO and CO.sub.2. The Ca metal and CaCl.sub.2 is recycled to reduce additional oxide fuel. The Cu--Mg alloy having transuranium metals and rare earth fission product metals and the noble metal fission products dissolved therein is contacted with a transport salt including Mg Cl.sub.2 to transfer Mg values from the transport salt to the Cu--Mg alloy while transuranium actinide and rare earth fission product metals transfer from the Cu--Mg alloy to the transport salt. Then the transport salt is mixed with a Mg--Zn alloy to transfer Mg values from the alloy to the transport salt while the transuranium actinide and rare earth fission product values dissolved in the salt are reduced and transferred to the Mg--Zn alloy.

  17. Salt transport extraction of transuranium elements from LWR fuel

    DOE Patents [OSTI]

    Pierce, R.D.; Ackerman, J.P.; Battles, J.E.; Johnson, T.R.; Miller, W.E.

    1992-11-03

    A process is described for separating transuranium actinide values from uranium values present in spent nuclear oxide fuels which contain rare earth and noble metal fission products. The oxide fuel is reduced with Ca metal in the presence of CaCl[sub 2] and a Cu--Mg alloy containing not less than about 25% by weight Mg at a temperature in the range of from about 750 C to about 850 C to precipitate uranium metal and some of the noble metal fission products leaving the Cu--Mg alloy having transuranium actinide metals and rare earth fission product metals and some of the noble metal fission products dissolved therein. The CaCl[sub 2] having CaO and fission products of alkali metals and the alkali earth metals and iodine dissolved therein is separated and electrolytically treated with a carbon electrode to reduce the CaO to Ca metal while converting the carbon electrode to CO and CO[sub 2]. The Ca metal and CaCl[sub 2] is recycled to reduce additional oxide fuel. The Cu--Mg alloy having transuranium metals and rare earth fission product metals and the noble metal fission products dissolved therein is contacted with a transport salt including MgCl[sub 2] to transfer Mg values from the transport salt to the Cu--Mg alloy while transuranium actinide and rare earth fission product metals transfer from the Cu--Mg alloy to the transport salt. Then the transport salt is mixed with a Mg--Zn alloy to transfer Mg values from the alloy to the transport salt while the transuranium actinide and rare earth fission product values dissolved in the salt are reduced and transferred to the Mg--Zn alloy. 2 figs.

  18. Pyrite cathode material for a thermal battery

    SciTech Connect (OSTI)

    Pemsler, J.P.; Litchfield, J.K.

    1991-02-07

    The present invention relates in general to a synthetic cathode material for a molten salt battery and, more particularly, to a process of providing and using synthetic pyrite for use as a cathode in a thermal battery. These batteries, which have been successfully used in a number of military applications, include iron disulfide cathode material obtained as benefacted or from natural occurring pyrite deposits, or as a byproduct of flotation concentrate from the processing of base or noble metal ores.

  19. Lithography-free large-area metamaterials for stable thermophotovoltaic energy conversion

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Coppens, Zachary J.; Kravchenko, Ivan I.; Valentine, Jason G.

    2016-02-08

    A large-area metamaterial thermal emitter is fabricated using facile, lithography-free techniques. The device is composed of conductive oxides, refractory ceramics, and noble metals and shows stable, selective emission after exposure to 1173 K for 22 h in oxidizing and inert atmospheres. Lastly, the results indicate that the metamaterial can be used to achieve high-performance thermophotovoltaic devices for applications such as portable power generation.

  20. Isotopic Constraints on the Chemical Evolution of Geothermal Fluids, Long Valley, CA

    SciTech Connect (OSTI)

    Brown, Shaun; Kennedy, Burton; DePaolo, Donald; Evans, William

    2008-08-01

    A spatial survey of the chemical and isotopic composition of fluids from the Long Valley hydrothermal system was conducted. Starting at the presumed hydrothermal upwelling zone in the west moat of the caldera, samples were collected from the Casa Diablo geothermal field and a series of monitoring wells defining a nearly linear, ~;;14 km long, west-to-east trend along the proposed fluid flow path (Sorey et al., 1991). Samples were analyzed for the isotopes of water, Sr, Ca, and noble gases, the concentrations of major cations and anions and total CO2. Our data confirm earlier models in which the variations in water isotopes along the flow path reflect mixing of a single hydrothermal fluid with local groundwater. Variations in Sr data are poorly constrained and reflect fluid mixing, multiple fluid-pathways or water-rock exchange along the flow path as suggested by Goff et al. (1991). Correlated variations among total CO2, noble gases and the concentration and isotopic composition of Ca suggest progressive fluid degassing (loss of CO2, noble gases) driving calcite precipitation as the fluid flows west-to-east across the caldera. This is the first evidence that Ca isotopes may trace and provide definitive evidence of calcite precipitation along fluid flow paths in geothermal systems.

  1. Control of high level radioactive waste-glass melters

    SciTech Connect (OSTI)

    Bickford, D.F.; Choi, A.S.

    1991-01-01

    Slurry Fed Melters (SFM) are being developed in the United States, Europe and Japan for the conversion of high-level radioactive waste to borosilicate glass for permanent disposal. The high transition metal, noble metal, nitrate, organic, and sulfate contents of these wastes lead to unique melter redox control requirements. Pilot waste-glass melter operations have indicated the possibility of nickel sulfide or noble-metal fission-product accumulation on melter floors, which can lead to distortion of electric heating patterns, and decrease melter life. Sulfide formation is prevented by control of the redox chemistry of the melter feed. The redox state of waste-glass melters is determined by balance between the reducing potential of organic compounds in the feed, and the oxidizing potential of gases above the melt, and nitrates and polyvalent elements in the waste. Semiquantitative models predicting limitations of organic content have been developed based on crucible testing. Computerized thermodynamic computations are being developed to predict the sequence and products of redox reactions and is assessing process variations. Continuous melter test results have been compared to improved computer staged-thermodynamic-models of redox behavior. Feed chemistry control to prevent sulfide and moderate noble metal accumulations are discussed. 17 refs., 3 figs.

  2. Control of high level radioactive waste-glass melters. Part 5, Modelling of complex redox effects

    SciTech Connect (OSTI)

    Bickford, D.F.; Choi, A.S.

    1991-12-31

    Slurry Fed Melters (SFM) are being developed in the United States, Europe and Japan for the conversion of high-level radioactive waste to borosilicate glass for permanent disposal. The high transition metal, noble metal, nitrate, organic, and sulfate contents of these wastes lead to unique melter redox control requirements. Pilot waste-glass melter operations have indicated the possibility of nickel sulfide or noble-metal fission-product accumulation on melter floors, which can lead to distortion of electric heating patterns, and decrease melter life. Sulfide formation is prevented by control of the redox chemistry of the melter feed. The redox state of waste-glass melters is determined by balance between the reducing potential of organic compounds in the feed, and the oxidizing potential of gases above the melt, and nitrates and polyvalent elements in the waste. Semiquantitative models predicting limitations of organic content have been developed based on crucible testing. Computerized thermodynamic computations are being developed to predict the sequence and products of redox reactions and is assessing process variations. Continuous melter test results have been compared to improved computer staged-thermodynamic-models of redox behavior. Feed chemistry control to prevent sulfide and moderate noble metal accumulations are discussed. 17 refs., 3 figs.

  3. The Radiochemical Analysis of Gaseous Samples (RAGS) Apparatus for Nuclear Diagnostics at the National Ignition Facility

    SciTech Connect (OSTI)

    Shaughnessy, D A; Velsko, C A; Jedlovec, D R; Yeamans, C B; Moody, K J; Tereshatov, E; Stoeffl, W; Riddle, A

    2012-05-11

    The RAGS (Radiochemical Analysis of Gaseous Samples) diagnostic apparatus was recently installed at the National Ignition Facility. Following a NIF shot, RAGS is used to pump the gas load from the NIF chamber for purification and isolation of the noble gases. After collection, the activated gaseous species are counted via gamma spectroscopy for measurement of the capsule areal density and fuel-ablator mix. Collection efficiency was determined by injecting a known amount of {sup 135}Xe into the NIF chamber, which was then collected with RAGS. Commissioning was performed with an exploding pusher capsule filled with isotopically enriched {sup 124}Xe and {sup 126}Xe added to the DT gas fill. Activated xenon species were recovered post-shot and counted via gamma spectroscopy. Results from the collection and commissioning tests are presented. The performance of RAGS allows us to establish a noble gas collection method for measurement of noble gas species produced via neutron and charged particle reactions in a NIF capsule.

  4. Enhanced Bifunctional Oxygen Catalysis in Strained LaNiO3 Perovskites

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Petrie, Jonathan R.; Cooper, Valentino R.; Freeland, John W.; Meyer, Tricia L.; Zhang, Zhiyong; Lutterman, Daniel A.; Lee, Ho Nyung

    2016-02-11

    Strain is known to greatly influence low-temperature oxygen electrocatalysis on noble metal films, leading to significant enhancements in bifunctional activity essential for fuel cells and metal-air batteries. Still, its catalytic impact on transition-metal oxide thin films, such as perovskites, is not widely understood. Here, we epitaxially strain the conducting perovskite LaNiO3 to systematically determine its influence on both the oxygen reduction and oxygen evolution reaction. Uniquely, we found that compressive strain could significantly enhance both reactions, yielding a bifunctional catalyst that surpasses the performance of noble metals such as Pt. We attribute the improved bifunctionality to strain-induced splitting of themore » eg orbitals, which can customize orbital asymmetry at the surface. Lastly, analogous to strain-induced shifts in the d-band center of noble metals relative to the Fermi level, such splitting can dramatically affect catalytic activity in this perovskite and other potentially more active oxides.« less

  5. Monodisperse Platinum and Rhodium Nanoparticles as Model Heterogeneous Catalysts

    SciTech Connect (OSTI)

    Coble, Inger M

    2008-08-15

    Model heterogeneous catalysts have been synthesized and studied to better understand how the surface structure of noble metal nanoparticles affects catalytic performance. In this project, monodisperse rhodium and platinum nanoparticles of controlled size and shape have been synthesized by solution phase polyol reduction, stabilized by polyvinylpyrrolidone (PVP). Model catalysts have been developed using these nanoparticles by two methods: synthesis of mesoporous silica (SBA-15) in the presence of nanoparticles (nanoparticle encapsulation, NE) to form a composite of metal nanoparticles supported on SBA-15 and by deposition of the particles onto a silicon wafer using Langmuir-Blodgett (LB) monolayer deposition. The particle shapes were analyzed by transmission electron microscopy (TEM) and high resolution TEM (HRTEM) and the sizes were determined by TEM, X-ray diffraction (XRD), and in the case of NE samples, room temperature H2 and CO adsorption isotherms. Catalytic studies were carried out in homebuilt gas-phase reactors. For the nanoparticles supported on SBA-15, the catalysts are in powder form and were studied using the homebuilt systems as plug-flow reactors. In the case of nanoparticles deposited on silicon wafers, the same systems were operated as batch reactors. This dissertation has focused on the synthesis, characterization, and reaction studies of model noble metal heterogeneous catalysts. Careful control of particle size and shape has been accomplished though solution phase synthesis of Pt and Rh nanoparticles in order to elucidate further structure-reactivity relationships in noble metal catalysis.

  6. The Radiochemical Analysis of Gaseous Samples (RAGS) apparatus for nuclear diagnostics at the National Ignition Facility (invited)

    SciTech Connect (OSTI)

    Shaughnessy, D. A.; Velsko, C. A.; Jedlovec, D. R.; Yeamans, C. B.; Moody, K. J.; Tereshatov, E.; Stoeffl, W.; Riddle, A.

    2012-10-15

    The Radiochemical Analysis of Gaseous Samples (RAGS) diagnostic apparatus was recently installed at the National Ignition Facility (NIF). Following a NIF shot, RAGS is used to pump the gas load from the NIF chamber for purification and isolation of the noble gases. After collection, the activated gaseous species are counted via gamma spectroscopy for measurement of the capsule areal density and fuel-ablator mix. Collection efficiency was determined by injecting a known amount of {sup 135}Xe into the NIF chamber, which was then collected with RAGS. Commissioning was performed with an exploding pusher capsule filled with isotopically enriched {sup 124}Xe and {sup 126}Xe added to the DT gas fill. Activated xenon species were recovered post-shot and counted via gamma spectroscopy. Results from the collection and commissioning tests are presented. The performance of RAGS allows us to establish a noble gas collection method for measurement of noble gas species produced via neutron and charged particle reactions in a NIF capsule.

  7. Uranium chloride extraction of transuranium elements from LWR fuel

    DOE Patents [OSTI]

    Miller, William E.; Ackerman, John P.; Battles, James E.; Johnson, Terry R.; Pierce, R. Dean

    1992-01-01

    A process of separating transuranium actinide values from uranium values present in spent nuclear oxide fuels containing rare earth and noble metal fission products as well as other fission products is disclosed. The oxide fuel is reduced with Ca metal in the presence of Ca chloride and a U-Fe alloy which is liquid at about 800.degree. C. to dissolve uranium metal and the noble metal fission product metals and transuranium actinide metals and rare earth fission product metals leaving Ca chloride having CaO and fission products of alkali metals and the alkali earth metals and iodine dissolved therein. The Ca chloride and CaO and the fission products contained therein are separated from the U-Fe alloy and the metal values dissolved therein. The U-Fe alloy having dissolved therein reduced metals from the spent nuclear fuel is contacted with a mixture of one or more alkali metal or alkaline earth metal halides selected from the class consisting of alkali metal or alkaline earth metal and Fe or U halide or a combination thereof to transfer transuranium actinide metals and rare earth metals to the halide salt leaving the uranium and some noble metal fission products in the U-Fe alloy and thereafter separating the halide salt and the transuranium metals dissolved therein from the U-Fe alloy and the metals dissolved therein.

  8. Uranium chloride extraction of transuranium elements from LWR fuel

    DOE Patents [OSTI]

    Miller, W.E.; Ackerman, J.P.; Battles, J.E.; Johnson, T.R.; Pierce, R.D.

    1992-08-25

    A process of separating transuranium actinide values from uranium values present in spent nuclear oxide fuels containing rare earth and noble metal fission products as well as other fission products is disclosed. The oxide fuel is reduced with Ca metal in the presence of Ca chloride and a U-Fe alloy which is liquid at about 800 C to dissolve uranium metal and the noble metal fission product metals and transuranium actinide metals and rare earth fission product metals leaving Ca chloride having CaO and fission products of alkali metals and the alkali earth metals and iodine dissolved therein. The Ca chloride and CaO and the fission products contained therein are separated from the U-Fe alloy and the metal values dissolved therein. The U-Fe alloy having dissolved therein reduced metals from the spent nuclear fuel is contacted with a mixture of one or more alkali metal or alkaline earth metal halides selected from the class consisting of alkali metal or alkaline earth metal and Fe or U halide or a combination thereof to transfer transuranium actinide metals and rare earth metals to the halide salt leaving the uranium and some noble metal fission products in the U-Fe alloy and thereafter separating the halide salt and the transuranium metals dissolved therein from the U-Fe alloy and the metals dissolved therein. 1 figure.

  9. New Tracers of Gas Migration in the Continental Crust

    SciTech Connect (OSTI)

    Kurz, Mark D.

    2015-11-01

    Noble gases are exceptional tracers in continental settings due to the remarkable isotopic variability between the mantle, crust, and atmosphere, and because they are inert. Due to systematic variability in physical properties, such as diffusion, solubility, and production rates, the combination of helium, neon, and argon provides unique but under-utilized indices of gas migration. Existing noble gas data sets are dominated by measurements of gas and fluid phases from gas wells, ground waters and hot springs. There are very few noble gas measurements from the solid continental crust itself, which means that this important reservoir is poorly characterized. The central goal of this project was to enhance understanding of gas distribution and migration in the continental crust using new measurements of noble gases in whole rocks and minerals from existing continental drill cores, with an emphasis on helium, neon, argon. We carried out whole-rock and mineral-separate noble gas measurements on Precambrian basement samples from the Texas Panhandle. The Texas Panhandle gas field is the southern limb of the giant Hugoton-Panhandle oil and gas field; it has high helium contents (up to ~ 2 %) and 3He/4He of 0.21 (± 0.03) Ra. Because the total amount of helium in the Panhandle gas field is relatively well known, crustal isotopic data and mass balance calculations can be used to constrain the ultimate source rocks, and hence the helium migration paths. The new 3He/4He data range from 0.03 to 0.11 Ra (total), all of which are lower than the gas field values. There is internal isotopic heterogeneity in helium, neon, and argon, within all the samples; crushing extractions yield less radiogenic values than melting, demonstrating that fluid inclusions preserve less radiogenic gases. The new data suggest that the Precambrian basement has lost significant amounts of helium, and shows the importance of measuring helium with neon and argon. The 4He/40Ar values are particularly useful

  10. Building a barrier wall through boulders

    SciTech Connect (OSTI)

    McMahon, D.R.; Mann, M.J. ); Tulett, R.C. )

    1994-10-01

    When the Occidental Chemical Co., Niagara Falls, N.Y., set out to remediate and contain wastes and ground water at its upstate New York site, they found that part of the proposed cutoff wall would be located in land reclaimed from the Niagara River. The fill was rock blasted out for a tunnel years ago, and the presence of boulders rule out conventional barrier-wall construction techniques. Occidental's first approach to containment had been a conventional soil-bentonite wall. Because of the area's geography and the location of the wastes, a portion of the wall had to be aligned along the riverbank. The company wanted to separate the plant area from the river, and decided to extend the barrier to the concrete headwall for intakes at the nearby Robert Moses Niagara Power Plant. This meant about 2,000 ft of the barrier wall would run through shot-rock fill placed during construction of the powerplant in the 1960s. Conduits for that plant were constructed by blasting rock to form open-cut tunnels several miles long. Some of the resulting shot rock was placed along the riverbank, extending the shoreline about 200 ft into the river near the now-contaminated site. The Rober Moses Parkway, a four-land highway, was constructed on the reclaimed land about 100 ft from the new shoreline.

  11. Structural and electrochemical properties of nanostructured nickel silicides by reduction and silicification of high-surface-area nickel oxide

    SciTech Connect (OSTI)

    Chen, Xiao [Laboratory of Advanced Materials and Catalytic Engineering, State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116024 (China)] [Laboratory of Advanced Materials and Catalytic Engineering, State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116024 (China); Zhang, Bingsen [Department of Inorganic Chemistry, Fritz Haber Institute of the Max Planck Society (Germany)] [Department of Inorganic Chemistry, Fritz Haber Institute of the Max Planck Society (Germany); Li, Chuang; Shao, Zhengfeng [Laboratory of Advanced Materials and Catalytic Engineering, State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116024 (China)] [Laboratory of Advanced Materials and Catalytic Engineering, State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116024 (China); Su, Dangsheng [Department of Inorganic Chemistry, Fritz Haber Institute of the Max Planck Society (Germany)] [Department of Inorganic Chemistry, Fritz Haber Institute of the Max Planck Society (Germany); Williams, Christopher T. [Department of Chemical Engineering, Swearingen Engineering Center, University of South Carolina (United States)] [Department of Chemical Engineering, Swearingen Engineering Center, University of South Carolina (United States); Liang, Changhai, E-mail: changhai@dlut.edu.cn [Laboratory of Advanced Materials and Catalytic Engineering, State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116024 (China)] [Laboratory of Advanced Materials and Catalytic Engineering, State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116024 (China)

    2012-03-15

    Graphical abstract: Nanostructured nickel silicides have been synthesized by reduction and silification of high-surface-area nickel oxide, and exhibited remarkably like-noble metal property, lower electric resistivity, and ferromagnetism at room temperature. Highlights: Black-Right-Pointing-Pointer NiSi{sub x} have been prepared by reduction and silification of high-surface-area NiO. Black-Right-Pointing-Pointer The structure of nickel silicides changed with increasing reaction temperature. Black-Right-Pointing-Pointer Si doping into nickel changed the magnetic properties of metallic nickel. Black-Right-Pointing-Pointer NiSi{sub x} have remarkably lower electric resistivity and like-noble metal property. -- Abstract: Nanostructured nickel silicides have been prepared by reduction and silicification of high-surface-area nickel oxide (145 m{sup 2} g{sup -1}) produced via precipitation. The prepared materials were characterized by nitrogen adsorption, X-ray diffraction, thermal analysis, FT-IR spectroscopy, scanning electron microscopy, transmission electron microscopy, magnetic and electrochemical measurements. The nickel silicide formation involves the following sequence: NiO (cubic) {yields} Ni (cubic) {yields} Ni{sub 2}Si (orthorhombic) {yields} NiSi (orthorhombic) {yields} NiSi{sub 2} (cubic), with particles growing from 13.7 to 21.3 nm. The nickel silicides are ferromagnetic at room temperature, and their saturation magnetization values change drastically with the increase of Si content. Nickel silicides have remarkably low electrical resistivity and noble metal-like properties because of a constriction of the Ni d band and an increase of the electronic density of states. The results suggest that such silicides are promising candidates as inexpensive yet functional materials for applications in electrochemistry as well as catalysis.

  12. The legacy of Cf-252 operations at Savannah River Technology Center: Continuous releases of radioiodine to the atmosphere

    SciTech Connect (OSTI)

    Kantelo, M.V.; Crandall, B.S.

    1992-12-31

    The iodine isotopes I-132, 1-133, I-134, and I-135, which have half-lives ranging from 53 minutes to 21 hours, are measured in the atmospheric effluent from the Savannah River Technology Center (SRTC) at the Savannah River Site (SRS) near Aiken, South Carolina. SRS is operated by Westinghouse Savannah River Company for the US Department of Energy (DOE). The isotopes` release rates range from 10 to 300 microcuries per week compared to the rate. The resulting annual dose from all iodine isotopes is minor; it comprises 0.01 percent of the total offsite dose due to atmospheric releases from SRS in 1990. Circumstantial evidence indicates the radioiodine originates from traces of unencapsulated Cf-252. The determination that spontaneous fission of Cf-252 is the source of the radioiodine has several ramifications. Radioactive fission-product isotopes of the noble gas elements krypton and xenon must also be released. Noble gases are more volatile and mobile than iodine. Also, the released iodine isotopes decay to xenon isotopes. The noble gases decay to non-gaseous elements that are transported along with radioiodine to the terrestrial environment by deposition from the SRTC plume. Only Sr-89 is believed to accumulate sufficiently in the environment to approach detectable levels. Given similar conditions in earlier years, releases of short-lived radioiodine have occurred undetected in routine monitoring since the early 1970s. Release rates 20 years ago would have been 200 times greater than current release rates. This report documents preliminary experiments conducted by SRTC and Environmental Monitoring Section (EMS) scientists. The release process and the environmental impact of fission products from Cf-252 should be thoroughly researched.

  13. Molecular Electronic Level Alignment at Weakly Coupled Organic Film/Metal Interfaces

    SciTech Connect (OSTI)

    Zhao, Jin; Feng, Min; Dougherty, Daniel B.; Sun, Hao; Petek, Hrvoje

    2014-10-28

    Electronic level alignment at interfaces of molecular materials with inorganic semiconductors and metals controls many interfacial phenomena. How the intrinsic properties of the interacting systems define the electronic structure of their interface remains one of the most important problems in molecular electronics and nanotechnology that can be solved through a combination of surface science experimental techniques and theoretical modeling. In this article, we address this fundamental problem through experimental and computational studies of molecular electronic level alignment of thin films of C6F6 on noble metal surfaces. The unoccupied electronic structure of C6F6 is characterized with single molecule resolution using low-temperature scanning tunneling microscopy-based constant-current distance-voltage spectroscopy. The experiments are performed on several noble metal surfaces with different work functions and distinct surface-normal projected band structures. In parallel, the electronic structures of the quantum wells (QWs) formed by the lowest unoccupied molecular orbital state of the C6F6 monolayer and multilayer films and their alignment with respect to the vacuum level of the metallic substrates are calculated by solving the Schrdinger equation for a semiempirical one-dimensional (1D) potential of the combined system using input from density functional theory. Our analysis shows that the level alignment for C6F6 molecules bound through weak van der Waals interactions to noble metal surfaces is primarily defined by the image potential of metal, the electron affinity of the molecule, and the molecule surface distance. We expect the same factors to determine the interfacial electronic structure for a broad range of molecule/metal interfaces.

  14. Recent advances in hydrotreating of pyrolysis bio-oil and its oxygen-containing model compounds

    SciTech Connect (OSTI)

    Wang, Huamin; Male, Jonathan L.; Wang, Yong

    2013-05-01

    There is considerable world-wide interest in discovering renewable sources of energy that can substitute for fossil fuels. Lignocellulosic biomass, which is the most abundant and inexpensive renewable feedstock on the planet, has a great potential for sustainable production of fuels, chemicals, and carbon-based materials. Fast pyrolysis integrated with hydrotreating is one of the simplest, most cost-effective and most efficient processes to convert lignocellulosic biomass to liquid hydrocarbon fuels for transportation, which has attracted significant attention in recent decades. However, effective hydrotreating of pyrolysis bio-oil presents a daunting challenge to the commercialization of biomass conversion via pyrolysis-hydrotreating. Specifically, development of active, selective, and stable hydrotreating catalysts is the bottleneck due to the poor quality of pyrolysis bio-oil feedstock (high oxygen content, molecular complexity, coking propensity, and corrosiveness). Significant research has been conducted to address the practical issues and provide the fundamental understanding of the hydrotreating/hydrodeoxygenation (HDO) of bio-oils and their oxygen-containing model compounds, including phenolics, furans, and carboxylic acids. A wide range of catalysts have been studied, including conventional Mo-based sulfide catalysts and noble metal catalysts, with the latter being the primary focus of the recent research because of their excellent catalytic performances and no requirement of environmentally unfriendly sulfur. The reaction mechanisms of HDO of model compounds on noble metal catalysts as well as their efficacy for hydrotreating or stabilization of bio-oil have been recently reported. This review provides a survey of the relevant literatures of recent 10 years about the advances in the understanding of the HDO chemistry of bio-oils and their model compounds mainly on noble metal catalysts.

  15. Electrorefining Experience For Pyrochemical Reprocessing of Spent EBR-II Driver Fuel

    SciTech Connect (OSTI)

    S. X. Li; T. A. Johnson; B. R. Westphal; K. M. Goff; R. W. Benedict

    2005-10-01

    Pyrochemical processing has been implemented for the treatment of spent fuel from the Experimental Breeder Reactor-II (EBR-II) at Idaho National Laboratory since 1996. This report summarizes technical advancements made in electrorefining of spent EBR-II driver fuel in the Mk-IV electrorefiner since the pyrochemical processing was integrated into the AFCI program in 2002. The significant advancements include improving uranium dissolution and noble metal retention from chopped fuel segments, increasing cathode current efficiency, and achieving co-collection of zirconium along with uranium from the cadmium pool.

  16. Nonlocal control of electron temperature in short direct current glow discharge plasma

    SciTech Connect (OSTI)

    Demidov, V. I.; Kudryavtsev, A. A.; Stepanova, O. M.; Kurlyandskaya, I. P.

    2014-09-15

    To demonstrate controlling the electron temperature in nonlocal plasma, experiments have been performed on a short (without positive column) dc glow discharge with a cold cathode by applying different voltages to the conducting discharge wall. The experiments have been performed for low-pressure noble gas discharges. The applied voltage can modify trapping the energetic electrons emitted from the cathode sheath and arising from the atomic and molecular processes in the plasma within the device volume. This phenomenon results in the energetic electrons heating the slow plasma electrons, which consequently modifies the electron temperature. Furthermore, a numerical model of the discharge has demonstrated the electron temperature modification for the above case.

  17. Enforcement Letter, Oak Ridge National Laboratory LLC- May 13, 2009 |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Oak Ridge National Laboratory LLC- May 13, 2009 Enforcement Letter, Oak Ridge National Laboratory LLC- May 13, 2009 May 13, 2009 Issued to UT-Battelle, LLC related to a Radioactive Material Release at the Holifield Radioactive Ion Beam Facility at Oak Ridge National Laboratory On May 13, 2009, the U.S. Department of Energy (DOE) Office of Health, Safety and Security's Office of Enforcement issued an Enforcement Letter to UT-Battelle related to radioactive noble gas

  18. Apparatus for the electrolytic production of metals

    DOE Patents [OSTI]

    Sadoway, Donald R. (Belmont, MA)

    1993-01-01

    Improved electrolytic cells for producing metals by the electrolytic reduction of a compound dissolved in a molten electrolyte are disclosed. In the improved cells, at least one electrode includes a protective layer comprising an oxide of the cell product metal formed upon an alloy of the cell product metal and a more noble metal. In the case of an aluminum reduction cell, the electrode can comprise an alloy of aluminum with copper, nickel, iron, or combinations thereof, upon which is formed an aluminum oxide protective layer.

  19. Volume-labeled nanoparticles and methods of preparation

    SciTech Connect (OSTI)

    Wang, Wei; Gu, Baohua; Retterer, Scott T; Doktycz, Mitchel J

    2015-04-21

    Compositions comprising nanosized objects (i.e., nanoparticles) in which at least one observable marker, such as a radioisotope or fluorophore, is incorporated within the nanosized object. The nanosized objects include, for example, metal or semi-metal oxide (e.g., silica), quantum dot, noble metal, magnetic metal oxide, organic polymer, metal salt, and core-shell nanoparticles, wherein the label is incorporated within the nanoparticle or selectively in a metal oxide shell of a core-shell nanoparticle. Methods of preparing the volume-labeled nanoparticles are also described.

  20. Methods for isolation and viability assessment of biological organisms

    DOE Patents [OSTI]

    Letant, Sonia Edith; Baker, Sarah Elyse; Bond, Tiziana; Chang, Allan Shih-Ping

    2015-02-03

    Isolation of biological or chemical organisms can be accomplished using a surface enhanced Raman scattering (SERS) system. The SERS system can be a single or a stacked plurality of photonic crystal membranes with noble-metal lined through pores for flowing analyte potentially containing the biological or chemical organisms. The through pores can be adapted to trap individual biological or chemical organisms and emit SERS spectra, which can then be detected by a detector and further analyzed for viability of the biological or chemical organism.

  1. Recent advances in the kinetics of oxygen reduction

    SciTech Connect (OSTI)

    Adzic, R.

    1996-07-01

    Oxygen reduction is considered an important electrocatalytic reaction; the most notable need remains improvement of the catalytic activity of existing metal electrocatalysts and development of new ones. A review is given of new advances in the understanding of reaction kinetics and improvements of the electrocatalytic properties of some surfaces, with focus on recent studies of relationship of the surface properties to its activity and reaction kinetics. The urgent need is to improve catalytic activity of Pt and synthesize new, possibly non- noble metal catalysts. New experimental techniques for obtaining new level of information include various {ital in situ} spectroscopies and scanning probes, some involving synchrotron radiation. 138 refs, 18 figs, 2 tabs.

  2. Cryogenic method for measuring nuclides and fission gases

    DOE Patents [OSTI]

    Perdue, P.T.; Haywood, F.F.

    1980-05-02

    A cryogenic method is provided for determining airborne gases and particulates from which gamma rays are emitted. A special dewar counting vessel is filled with the contents of the sampling flask which is immersed in liquid nitrogen. A vertically placed sodium-iodide or germanium-lithium gamma-ray detector is used. The device and method are of particular use in measuring and identifying the radioactive noble gases including emissions from coal-fired power plants, as well as fission gases released or escaping from nuclear power plants.

  3. Microsoft Word - May_2008_BM26-42_Data_Rpt.doc

    Office of Legacy Management (LM)

    26-42 Well: Gas production well, Battlement Mesa 26-42, API # 05-045-10666. (Pad 26 is near the Rulison, CO, Site.) Operator: Noble Energy, Incorporated Sampler: U.S. Department of Energy, Office of Legacy Management, Grand Junction, CO. Date of Sampling Event: 28 May 2008 Samples of natural gas and produced water were collected from production well BM 26-42. Location data for the surface collection point and the sample location are given in Table 1. A description of the samples collected is

  4. Microsoft Word - May_2008_BM35-12.doc

    Office of Legacy Management (LM)

    well, Battlement Mesa 35-12, API # 05-045-10412. (Pad 35 is near the Rulison, CO, Site.) Operator: Noble Energy, Incorporated Sampler: U.S. Department of Energy, Office of Legacy Management, Grand Junction, CO. Date of Sampling Event: 28 May 2008 Samples of natural gas and produced water were collected from production well BM 35-12. Location data for the surface collection point and the sample location are given in Table 1. A description of the samples collected is found in Table 2. Table 1.

  5. Operational and Environmental Monitoring Within a Three-Mile Radius of Project Rulison

    Office of Legacy Management (LM)

    FOURTH QUARTER 20 08 REPORT Operational and Environmental Monitoring Within a Three-Mile Radius of Project Rulison F F Prepared by: M A R C H 2 0 0 9 FOURTH QUARTER 2008 REPORT OPERATIONAL AND ENVIRONMENTAL MONITORING WITHIN A THREE-MILE RADIUS OF PROJECT RULISON Prepared for: Noble Energy Inc. EnCana Oil & Gas (USA) Inc. Williams Production RMT Inc. Prepared by: URS Corporation 8181 East Tufts Avenue Denver, CO 80237 March 26, 2009 Rulison Fourth Quarter 2008 Report March 2009 i TABLE OF

  6. Regarding Confinement Resonances

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Regarding Confinement Resonances Print When an atom is encapsulated inside a hollow spherical carbon buckyball, the complex is called an "endofullerene." Theoretically, if the atom is an unreactive noble gas like xenon, it should be centered within the cage. If one or more of the atom's electrons are boosted out of the cage by an x-ray photon, the electron waves may be transmitted through or reflected off the carbon cage, giving rise to an interference effect similar to waves in a

  7. Fermilab | Science at Fermilab | Experiments & Projects | Intensity

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Frontier | ArgoNeuT ArgoNeuT ArgoNeut detector at Proton Assembly Building Intensity Frontier ArgoNeuT The Argon Neutrino Teststand or ArgoNeuT detector, nicknamed for Jason and the Argonauts of Greek mythology, is a liquid argon neutrino detector at Fermilab. Argon is a noble, non-toxic element that in its gaseous form constitutes about 1 percent of air. It exists as a colorless liquid only in the narrow temperature range of minus 186 to minus 189 degrees Celsius. Neutrinos passing through

  8. Cubic to Tetragonal Phase Transformation in Cold-Compressed Pd Nanocubes

    SciTech Connect (OSTI)

    Guo, Q.X.; Zhao, Y.S.; Mao, W.L.; Wang, Z.W.; Xiong, Y.J.; Xia, Y.N.; /Los Alamos /SLAC /Cornell U., LNS /Washington U., Seattle

    2009-06-09

    Pd nanocubes with an average side length of {approx}10 nm were compressed up to 24.8 GPa in a diamond-anvil cell (DAC). In situ synchrotron X-ray diffraction was used to monitor structural changes, and a face-centered cubic (fcc) to face-centered tetragonal (fct) distortion was observed for the first time. This novel discovery not only provides new insights into the pressure-induced behavior of faceted nanocrystals of palladium and other noble metals but also gives guidance for finding new phases in close-packed metals.

  9. Data Report

    Office of Legacy Management (LM)

    well Battlement Mesa 35-12, API # 05-045-10412. (Pad 35 is near the Rulison, CO, Site) Operator: Noble Energy, Incorporated Sampler: U.S. Department of Energy, Office of Legacy Management, Grand Junction, CO. Date of Sampling Event: August 15, 2007 Samples of natural gas and produced water were collected from production well BM 35-12. Details concerning this well are listed in Table1. A description of the samples collected is found in Table 2. Table 1. Well BM 35-12, API # 05-045-10412 Distance

  10. Data Report

    Office of Legacy Management (LM)

    well Battlement Mesa 35-21D, API # 05-045-12505. (Pad 35 is near the Rulison, CO, Site) Operator: Noble Energy, Incorporated Sampler: U.S. Department of Energy, Office of Legacy Management, Grand Junction, CO Date of Sampling Event: October 31, 2007 Samples of natural gas and production water were collected from production well BM 35-21D. Details concerning this well are listed in Table1. A description of the samples collected is found in Table 2. Table 1. Well BM 35-21D, API # 05-045-12505

  11. Data Report

    Office of Legacy Management (LM)

    well, Battlement Mesa 35-21D, API # 05-045-12505. (Pad 26 is near the Rulison, CO, Site.) Operator: Noble Energy, Incorporated Sampler: U.S. Department of Energy, Office of Legacy Management, Grand Junction, CO. Date of Sampling Event: 28 May 2008 Samples of natural gas and produced water were collected from production well BM 35-21D. Location data for the surface collection point and the sample location are given in Table 1. A description of the samples collected is found in Table 2. Table 1.

  12. Data Report

    Office of Legacy Management (LM)

    Well: Gas production well, Battlement Mesa 35-32A, API # 05-045-10919. (Pad 35 is near the Rulison, CO, Site.) Operator: Noble Energy, Incorporated Sampler: U.S. Department of Energy, Office of Legacy Management, Grand Junction, CO. Date of Sampling Event: 28 May 2008 Samples of natural gas and produced water were collected from production well BM 35-32A. Location data for the surface collection point and the sample location are given in Table 1. A description of the samples collected is found

  13. Data Report

    Office of Legacy Management (LM)

    well, Battlement Mesa 36-13, API # 05-045-10840. (Pad 26 is near the Rulison, CO, Site.) Operator: Noble Energy, Incorporated Sampler: U.S. Department of Energy, Office of Legacy Management, Grand Junction, CO. Date of Sampling Event: 28 May 2008 Samples of natural gas and produced water were collected from production well BM 26-42. Location data for the surface collection point and the sample location are given in Table 1. A description of the samples collected is found in Table 2. Table 1.

  14. Data Report

    Office of Legacy Management (LM)

    well Battlement Mesa 36-13, API # 05-045-10840. (Pad 36 is near the Rulison, CO, Site.) Operator: Noble Energy, Incorporated Sampler: U.S. Department of Energy, Office of Legacy Management, Grand Junction, CO. Date of Sampling Event: October 31, 2007 Samples of natural gas and produced water were collected from production well BM 36-13. Details concerning this well are listed in Table 1. A description of the samples collected is found in Table 2. Table 1. Well BM 36-13, API # 05-045-10840

  15. Low oxygen biomass-derived pyrolysis oils and methods for producing the same

    DOE Patents [OSTI]

    Marinangeli, Richard; Brandvold, Timothy A; Kocal, Joseph A

    2013-08-27

    Low oxygen biomass-derived pyrolysis oils and methods for producing them from carbonaceous biomass feedstock are provided. The carbonaceous biomass feedstock is pyrolyzed in the presence of a catalyst comprising base metal-based catalysts, noble metal-based catalysts, treated zeolitic catalysts, or combinations thereof to produce pyrolysis gases. During pyrolysis, the catalyst catalyzes a deoxygenation reaction whereby at least a portion of the oxygenated hydrocarbons in the pyrolysis gases are converted into hydrocarbons. The oxygen is removed as carbon oxides and water. A condensable portion (the vapors) of the pyrolysis gases is condensed to low oxygen biomass-derived pyrolysis oil.

  16. Method of synthesizing polymers from a solid electrolyte

    DOE Patents [OSTI]

    Skotheim, T.A.

    1984-10-19

    A method of synthesizing electrically conductive polymers from a solvent-free solid polymer electrolyte is disclosed. An assembly of a substrate having an electrode thereon, a thin coating of solid electrolyte including a solution of PEO complexed with an alkali salt, and a thin transparent noble metal electrode are disposed in an evacuated chamber into which a selected monomer vapor is introduced while an electric potential is applied across the solid electrolyte to hold the thin transparent electrode at a positive potential relative to the electrode on the substrate, whereby a highly conductive polymer film is grown on the transparent electrode between it and the solid electrolyte.

  17. Method of synthesizing polymers from a solid electrolyte

    DOE Patents [OSTI]

    Skotheim, Terje A.

    1985-01-01

    A method of synthesizing electrically conductive polymers from a solvent-free solid polymer electrolyte wherein an assembly of a substrate having an electrode thereon, a thin coating of solid electrolyte including a solution of PEO complexed with an alkali salt, and a thin transparent noble metal electrode are disposed in an evacuated chamber into which a selected monomer vapor is introduced while an electric potential is applied across the solid electrolyte to hold the thin transparent electrode at a positive potential relative to the electrode on the substrate, whereby a highly conductive polymer film is grown on the transparent electrode between it and the solid electrolyte.

  18. Gasless sputtering: Opportunities for ultraclean metallization, coatings in space, and propulsion

    SciTech Connect (OSTI)

    Andersson, Joakim; Anders, Andre

    2008-06-02

    Pulsed magnetron sputtering was demonstrated in high vacuum: no sputter gas was used at any time. Sustained self-sputtering was initiated by multiply charged ions from a short vacuum arc. Copper ion currents to an ion collector in excess of 30 A were measured, implying a plasma density of about 6x10{sup 18} m{sup -3}. This technology may prove useful for metal coatings free of noble gas inclusions and suggests that magnetrons could operate in the vacuum of space. In addition to coating objects in space, the momentum of the sputtered atoms and ions may be utilized in space thrusters.

  19. HXeOBr in a xenon matrix

    SciTech Connect (OSTI)

    Khriachtchev, Leonid; Tapio, Salla; Domanskaya, Alexandra V.; Raesaenen, Markku; Isokoski, Karoliina; Lundell, Jan

    2011-03-28

    We report on a new noble-gas molecule HXeOBr prepared in a low-temperature xenon matrix from the HBr and N{sub 2}O precursors by UV photolysis and thermal annealing. This molecule is assigned with the help of deuteration experiments and ab initio calculations including anharmonic methods. The H-Xe stretching frequency of HXeOBr is observed at 1634 cm{sup -1}, which is larger by 56 cm{sup -1} than the frequency of HXeOH identified previously. The experiments show a higher thermal stability of HXeOBr molecules in a xenon matrix compared to HXeOH.

  20. Sandwich-type electrode

    DOE Patents [OSTI]

    Lu, Wen-Tong P.; Garcia, Earl R.

    1983-01-01

    Disclosed is an improvement on a method of making an electrode wherein a suspension in a liquid is prepared of a powdered catalyst containing a noble metal, carbon powder and a binder, and the suspension is poured over a carbon substrate dried, compressed and sintered to form a solid catalyst layer bonded to the carbon substrate. The improvement is placing a carbon paper on the catalyst layer prior to compressing. The improved electrode can be used as either a cathode or an anode in a sulfur dioxide depolarized electrolyzer in a process for producing hydrogen from water.

  1. Liquid Argon Dielectric Strength Measurements Sarah Lockwitz

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Argon Dielectric Strength Measurements Sarah Lockwitz Fermilab LArTPC R&D Workshop July, 9 2014 Fermilab LAr Dielectric Strength July 9, 2014 S. Lockwitz et al. Recent Interest in LAr High Voltage (HV) 2 Experiment Voltage ICARUS 75 kV Darkside 50 60 kV MicroBooNE 128 kV CAPTAIN 50 kV LBNE 170 kV GLACIER 1-2 MV LAr Dielectric Strength July 9, 2014 S. Lockwitz et al. Recent Interest in LAr High Voltage (HV) * Noble liquids are becoming a popular detector medium 2 Experiment Voltage ICARUS 75

  2. Attosecond nanoscale near-field sampling

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Forg, B.; Schotz, J.; SuBmann, F.; Forster, M.; Kruger, M.; Ahn, B.; Okell, W. A.; Wintersperger, K.; Zherebtsov, S.; Guggenmos, A.; et al

    2016-05-31

    The promise of ultrafast light-field-driven electronic nanocircuits has stimulated the development of the new research field of attosecond nanophysics. An essential prerequisite for advancing this new area is the ability to characterize optical near fields from light interaction with nanostructures, with sub-cycle resolution. Here we experimentally demonstrate attosecond near-field retrieval for a tapered gold nanowire. Furthermore, by comparison of the results to those obtained from noble gas experiments and trajectory simulations, the spectral response of the nanotaper near field arising from laser excitation can be extracted.

  3. Method of depositing a high-emissivity layer

    DOE Patents [OSTI]

    Wickersham, Charles E.; Foster, Ellis L.

    1983-01-01

    A method of depositing a high-emissivity layer on a substrate comprising RF sputter deposition of a carbide-containing target in an atmosphere of a hydrocarbon gas and a noble gas. As the carbide is deposited on the substrate the hydrocarbon gas decomposes to hydrogen and carbon. The carbon deposits on the target and substrate causing a carbide/carbon composition gradient to form on the substrate. At a sufficiently high partial pressure of hydrocarbon gas, a film of high-emissivity pure carbon will eventually form over the substrate.

  4. Regarding Confinement Resonances

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Regarding Confinement Resonances Print When an atom is encapsulated inside a hollow spherical carbon buckyball, the complex is called an "endofullerene." Theoretically, if the atom is an unreactive noble gas like xenon, it should be centered within the cage. If one or more of the atom's electrons are boosted out of the cage by an x-ray photon, the electron waves may be transmitted through or reflected off the carbon cage, giving rise to an interference effect similar to waves in a

  5. Regarding Confinement Resonances

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Regarding Confinement Resonances Print When an atom is encapsulated inside a hollow spherical carbon buckyball, the complex is called an "endofullerene." Theoretically, if the atom is an unreactive noble gas like xenon, it should be centered within the cage. If one or more of the atom's electrons are boosted out of the cage by an x-ray photon, the electron waves may be transmitted through or reflected off the carbon cage, giving rise to an interference effect similar to waves in a

  6. Regarding Confinement Resonances

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Regarding Confinement Resonances Print When an atom is encapsulated inside a hollow spherical carbon buckyball, the complex is called an "endofullerene." Theoretically, if the atom is an unreactive noble gas like xenon, it should be centered within the cage. If one or more of the atom's electrons are boosted out of the cage by an x-ray photon, the electron waves may be transmitted through or reflected off the carbon cage, giving rise to an interference effect similar to waves in a

  7. Regarding Confinement Resonances

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Regarding Confinement Resonances Regarding Confinement Resonances Print Wednesday, 27 July 2011 00:00 When an atom is encapsulated inside a hollow spherical carbon buckyball, the complex is called an "endofullerene." Theoretically, if the atom is an unreactive noble gas like xenon, it should be centered within the cage. If one or more of the atom's electrons are boosted out of the cage by an x-ray photon, the electron waves may be transmitted through or reflected off the carbon cage,

  8. Microsoft Word - R10008 Final_Report 10-13-11

    Office of Scientific and Technical Information (OSTI)

    Aspen Aerogels, Inc. DE- EE0003488 Final Report AAI # R-10008 Page 1 of 37 Final Technical Report Date of Report: October 13, 2011 Award Number: DE-EE0003488 Project Title: Aerogel Based Insulation for High Temperature Industrial Processes Project Period: 08/16/2010 - 08/15/2011 Recipient Organization: Aspen Aerogels, Inc. 30 Forbes Road, Building B Northborough, MA 01532 Partner(s): NextEra Energy Inc. (Florida Power & Light) Bernie C. Noble 700 Universe Boulevard Juno Beach, FL 33408 Tel:

  9. Californium--palladium metal neutron source material

    DOE Patents [OSTI]

    Dahlen, B.L.; Mosly, W.C. Jr.; Smith, P.K.; Albenesius, E.L.

    1974-01-22

    Californium, as metal or oxide, is uniformly dispersed throughout a noble metal matrix, provided in compact, rod or wire form. A solution of californium values is added to palladium metal powder, dried, blended and pressed into a compact having a uni-form distribution of californium. The californium values are decomposed to californium oxide or metal by heating in an inert or reducing atmosphere. Sintering the compact to a high density closes the matrix around the dispersed californium. The sintered compact is then mechanically shaped into an elongated rod or wire form. (4 claims, no drawings) (Official Gazette)

  10. DRFM: A new package for the evaluation of gas-phase transport properties

    SciTech Connect (OSTI)

    Paul, P.H.

    1997-11-01

    This report describes a complete and modernized procedure to evaluate pure species, binary and mixture transport properties of gases in the low density limit. This includes a description of the relationships used to calculate these quantities and the means used to obtain the necessary input data. The purpose of this work is to rectify certain limitations of previous transport packages, specifically: to employ collision integrals suitable for high temperatures, to modernize the mixture formula, and to modernize the input data base. This report includes a set of input parameters for: the species involved in H{sub 2}-, CO - air combustion, the noble gases, methane and the oxides of nitrogen.

  11. Tailoring nanocrystalline diamond film properties

    DOE Patents [OSTI]

    Gruen, Dieter M.; McCauley, Thomas G.; Zhou, Dan; Krauss, Alan R.

    2003-07-15

    A method for controlling the crystallite size and growth rate of plasma-deposited diamond films. A plasma is established at a pressure in excess of about 55 Torr with controlled concentrations of hydrogen up to about 98% by volume, of unsubstituted hydrocarbons up to about 3% by volume and an inert gas of one or more of the noble gases and nitrogen up to about 98% by volume. The volume ratio of inert gas to hydrogen is preferably maintained at greater than about 4, to deposit a diamond film on a suitable substrate. The diamond film is deposited with a predetermined crystallite size and at a predetermined growth rate.

  12. Theory of melting at high pressures: Amending density functional theory with quantum Monte Carlo

    SciTech Connect (OSTI)

    Shulenburger, L.; Desjarlais, M. P.; Mattsson, T. R.

    2014-10-01

    We present an improved first-principles description of melting under pressure based on thermodynamic integration comparing Density Functional Theory (DFT) and quantum Monte Carlo (QMC) treatments of the system. The method is applied to address the longstanding discrepancy between density functional theory (DFT) calculations and diamond anvil cell (DAC) experiments on the melting curve of xenon, a noble gas solid where van der Waals binding is challenging for traditional DFT methods. The calculations show excellent agreement with data below 20 GPa and that the high-pressure melt curve is well described by a Lindemann behavior up to at least 80 GPa, a finding in stark contrast to DAC data.

  13. Material and system for catalytic reduction of nitrogen oxide in an exhaust stream of a combustion process

    DOE Patents [OSTI]

    Gardner, Timothy J.; Lott, Stephen E.; Lockwood, Steven J.; McLaughlin, Linda I.

    1998-01-01

    A catalytic material of activated hydrous metal oxide doped with platinum, palladium, or a combination of these, and optionally containing an alkali or alkaline earth metal, that is effective for NO.sub.X reduction in an oxidizing exhaust stream from a combustion process is disclosed. A device for reduction of nitrogen oxides in an exhaust stream, particularly an automotive exhaust stream, the device having a substrate coated with the activated noble-metal doped hydrous metal oxide of the invention is also provided.

  14. Using {sup 222}Rn as a tracer of geophysical processes in underground environments

    SciTech Connect (OSTI)

    Lacerda, T.; Anjos, R. M.; Silva, A. A. R. da; Yoshimura, E. M.

    2014-11-11

    Radon levels in two old mines in San Luis, Argentina, are reported and analyzed. These mines are today used for touristic visitation. Our goal was to assess the potential use of such radioactive noble gas as tracer of geological processes in underground environments. CR-39 nuclear track detectors were used during the winter and summer seasons. The findings show that the significant radon concentrations reported in this environment are subject to large seasonal modulations, due to the strong dependence of natural ventilation on the variations of outside temperature. The results also indicate that radon pattern distribution appear as a good method to localize unknown ducts, fissures or secondary tunnels in subterranean environments.

  15. Carbon aerogel electrodes for direct energy conversion

    DOE Patents [OSTI]

    Mayer, Steven T. (San Leandro, CA); Kaschmitter, James L. (Pleasanton, CA); Pekala, Richard W. (Pleasant Hill, CA)

    1997-01-01

    A direct energy conversion device, such as a fuel cell, using carbon aerogel electrodes, wherein the carbon aerogel is loaded with a noble catalyst, such as platinum or rhodium and soaked with phosphoric acid, for example. A separator is located between the electrodes, which are placed in a cylinder having plate current collectors positioned adjacent the electrodes and connected to a power supply, and a pair of gas manifolds, containing hydrogen and oxygen positioned adjacent the current collectors. Due to the high surface area and excellent electrical conductivity of carbon aerogels, the problems relative to high polarization resistance of carbon composite electrodes conventionally used in fuel cells are overcome.

  16. Carbon aerogel electrodes for direct energy conversion

    DOE Patents [OSTI]

    Mayer, S.T.; Kaschmitter, J.L.; Pekala, R.W.

    1997-02-11

    A direct energy conversion device, such as a fuel cell, using carbon aerogel electrodes is described, wherein the carbon aerogel is loaded with a noble catalyst, such as platinum or rhodium and soaked with phosphoric acid, for example. A separator is located between the electrodes, which are placed in a cylinder having plate current collectors positioned adjacent the electrodes and connected to a power supply, and a pair of gas manifolds, containing hydrogen and oxygen positioned adjacent the current collectors. Due to the high surface area and excellent electrical conductivity of carbon aerogels, the problems relative to high polarization resistance of carbon composite electrodes conventionally used in fuel cells are overcome. 1 fig.

  17. High Temperature Strength of YSZ Joints Brazed with Palladium Silver Copper Oxide Filler Metals

    SciTech Connect (OSTI)

    Darsell, Jens T.; Weil, K. Scott

    2010-06-09

    The Ag-CuOx system is being investigated as potential filler metals for use in air brazing high-temperature electrochemical devices such as solid oxide fuel cells and gas concentrators. The current study examines the effects of palladium addition on the high temperature joint strength of specimens prepared from yttria stabilized zirconia (YSZ) bars brazed with the binary Ag-CuOx, and 15Pd-Ag-CuO. It was found that while the binary Ag-CuOx system exhibits stronger room temperature strength than the 15Pd system the strength is reduced to values equivalent of the 15Pd system at 800C. The 15Pd system exhibits a lower ambient temperature strength that is retained at 800C. In both systems the failure mechanism at high temperature appears to be peeling of the noble metal component from the oxide phases and tearing through the noble metal phase whereas sufficient adhesion is retained at lower temperatures to cause fracture of the YSZ substrate.

  18. Developing the model of laser ablation by considering the interplay between emission and expansion of aluminum plasma

    SciTech Connect (OSTI)

    Rezaei, F.; Tavassoli, S. H.

    2013-01-15

    In the present study, the ablation behavior of aluminum target and its plasma radiation in noble ambient gases by a laser pulse with wavelength of 266 nm and pulse duration of 10 ns are numerically studied. A thermal model of laser ablation considering heat conduction, Euler equations, Saha-Eggert equations, Knudsen layer, mass and energy balance relations and optical shielding effects are used for calculation of plasma parameters. Effects of excitation energy on plasma expansion and its emissivity are investigated. Time and spatial-resolved plasma emission including bremsstrahlung, recombination and spectral emission at early delay times after laser irradiation is obtained. Effects of two ambient gases (He and Ar) as well as different gas pressures of 100, 300, 500, and 760 Torr on plasma expansion and its spectrum are studied. Results illustrate that at initial delay times, especially at high noble gas pressures, ionic lines have the maximum intensities, while at later times neutral lines dominate. When the pressure of ambient gas increases, a confinement of the plasma plume is predicted and the intensity of neutral lines decreases. Continuous emission increases with wavelength in both ambient gases. Spatially resolved analysis shows that an intense continuous emission is predicted next to the sample surface decreasing with distance from the latter.

  19. Ultra-high-performance core–shell structured Ru@Pt/C catalyst prepared by a facile pulse electrochemical deposition method

    SciTech Connect (OSTI)

    Chen, Dan; Li, Yuexia; Liao, Shijun; Su, Dong; Song, Huiyu; Li, Yingwei; Yang, Lijun; Li, Can

    2015-08-03

    Core–shell structured catalysts, made by placing either a monolayer or a thin layer of a noble metal on relatively cheap core-metal nanoparticles, are fascinating and promising fuel cell catalysts due to their high utilization of noble metals. Here, we report our development of a core–shell structured catalyst, Ru@Pt/C, generated by a novel and facile pulse electrochemical deposition (PED) approach. We demonstrate that compared with a commercial Pt/C catalyst, this novel catalyst achieves over four times higher mass activity towards the anodic oxidation of methanol, and 3.6 times higher mass activity towards the cathodic reduction of oxygen. Importantly, we find that the intrinsic activity of Pt in this Ru@Pt/C catalyst is doubled due to the formation of the core–shell structure. The catalyst also shows superior stability: even after 2000 scans, it still retains up to 90% of the peak current. As a result, our findings demonstrate that this novel PED approach is a promising method for preparing high-performance core–shell catalysts for fuel cell applications.

  20. Ultra-high-performance core–shell structured Ru@Pt/C catalyst prepared by a facile pulse electrochemical deposition method

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Chen, Dan; Li, Yuexia; Liao, Shijun; Su, Dong; Song, Huiyu; Li, Yingwei; Yang, Lijun; Li, Can

    2015-08-03

    Core–shell structured catalysts, made by placing either a monolayer or a thin layer of a noble metal on relatively cheap core-metal nanoparticles, are fascinating and promising fuel cell catalysts due to their high utilization of noble metals. Here, we report our development of a core–shell structured catalyst, Ru@Pt/C, generated by a novel and facile pulse electrochemical deposition (PED) approach. We demonstrate that compared with a commercial Pt/C catalyst, this novel catalyst achieves over four times higher mass activity towards the anodic oxidation of methanol, and 3.6 times higher mass activity towards the cathodic reduction of oxygen. Importantly, we find thatmore » the intrinsic activity of Pt in this Ru@Pt/C catalyst is doubled due to the formation of the core–shell structure. The catalyst also shows superior stability: even after 2000 scans, it still retains up to 90% of the peak current. As a result, our findings demonstrate that this novel PED approach is a promising method for preparing high-performance core–shell catalysts for fuel cell applications.« less