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  1. Ardmore, Pennsylvania: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    OpenEI by expanding it. Ardmore is a census-designated place in Delaware County and Montgomery County, Pennsylvania.1 References US Census Bureau 2005 Place to 2006 CBSA...

  2. Alternative Fuels Data Center: Blue Ridge Parkway Incorporates Alternative

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Fuels in Its Fleet Blue Ridge Parkway Incorporates Alternative Fuels in Its Fleet to someone by E-mail Share Alternative Fuels Data Center: Blue Ridge Parkway Incorporates Alternative Fuels in Its Fleet on Facebook Tweet about Alternative Fuels Data Center: Blue Ridge Parkway Incorporates Alternative Fuels in Its Fleet on Twitter Bookmark Alternative Fuels Data Center: Blue Ridge Parkway Incorporates Alternative Fuels in Its Fleet on Google Bookmark Alternative Fuels Data Center: Blue Ridge

  3. Foothills Parkway Section 8B Final Environmental Report, Volume 1

    SciTech Connect (OSTI)

    Blasing, T.J.; Cada, G.F.; Carer, M.; Chin, S.M.; Dickerman, J.A.; Etnier, D.A.; Gibson, R.; Harvey, M.; Hatcher, B.; Lietzske, D.; Mann, L.K.; Mulholland, P.J.; Petrich, C.H.; Pounds, L.; Ranney, J.; Reed, R.M.; Ryan, P.F.; Schweitzer, M.; Smith, D.; Thomason, P.; Wade, M.C.

    1999-07-01

    In 1994, Oak Ridge National Laboratory (ORNL) was tasked by the National Park Service (NPS) to prepare an Environmental Report (ER) for Section 8B of the Foothills Parkway in the Great Smoky Mountains National Park (GSMNP). Section 8B represents 27.7 km (14.2 miles) of a total of 115 km (72 miles) of the planned Foothills Parkway and would connect the Cosby community on the east to the incorporated town of Pittman Center to the west.

  4. Noble gas magnetic resonator

    DOE Patents [OSTI]

    Walker, Thad Gilbert; Lancor, Brian Robert; Wyllie, Robert

    2014-04-15

    Precise measurements of a precessional rate of noble gas in a magnetic field is obtained by constraining the time averaged direction of the spins of a stimulating alkali gas to lie in a plane transverse to the magnetic field. In this way, the magnetic field of the alkali gas does not provide a net contribution to the precessional rate of the noble gas.

  5. HV in Noble Liquids

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in Noble Liquids 8 Nov 2013 High Voltage Tests for MicroBooNE Byron Lundberg Fermilab presenting for the Collaboration & Task Force 4 1 Friday, November 8, 13 HV in Noble Liquids MicroBooNE Experiment  A liquid argon time projection chamber (LAr TPC) containing 170 tons of liquid argon, and located on the Booster Neutrino Beamline.  MiniBooNE  MicroBooNE 8,#256#wires;#U,V,Y#planes;#3#mm#spacing# 32#PMTs#for#fast#light#collec?ons# @ L A r T F 2 Friday, November 8, 13 HV in Noble

  6. Nobles Wind Farm | Open Energy Information

    Open Energy Info (EERE)

    Farm Jump to: navigation, search Name Nobles Wind Farm Facility Nobles Sector Wind energy Facility Type Commercial Scale Wind Facility Status In Service Owner Nobles Cooperative...

  7. Noble Bellmont Wind Farm | Open Energy Information

    Open Energy Info (EERE)

    Noble Bellmont Wind Farm Jump to: navigation, search Name Noble Bellmont Wind Farm Facility Noble Bellmont Sector Wind energy Facility Type Commercial Scale Wind Facility Status...

  8. Noble Group | Open Energy Information

    Open Energy Info (EERE)

    Wealth Fund 2 Noble purchased 5.1% of USEC, a US company which enriches uranium for nuclear power reactors, in June 2010 2 References "Noble Group (HK)" 2.0 2.1 "New...

  9. Noble Americas | Open Energy Information

    Open Energy Info (EERE)

    Place: Stamford, Connecticut Zip: 6902 Product: Wholly owned subsidiary of global supply chain manager Noble Group Coordinates: 42.75294, -73.068531 Show Map Loading...

  10. Noble Environmental Power | Open Energy Information

    Open Energy Info (EERE)

    Environmental Power Jump to: navigation, search Name: Noble Environmental Power Place: Essex, Connecticut Zip: 6426 Sector: Wind energy Product: Backed by JP Morgan, Noble is...

  11. Noble REMC- Residential Energy Efficiency Rebate Incentives

    Broader source: Energy.gov [DOE]

    Through Wabash Valley Power Association, POWER MOVES program, Noble REMC offers residential rebates.

  12. USCA Convocation Center 375 Robert M. Bell Parkway, Aiken, SC 29801

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1, 2013 USCA Convocation Center 375 Robert M. Bell Parkway, Aiken, SC 29801  Cash Bar Reception 6:00-6:45 pm  Banquet/Lecture 7:00 pm  Tickets: $50 per person Must be purchased and paid for in advance DEADLINE for reservations: September 30, 2013 Please make checks payable to: CNTA We are a 501 ( c ) 3 non-profit organization Tax ID #: 57-0953103 Contact CNTA: (803) 649-3456 or email, cnta@bellsouth.net Tickets will be mailed to the address we have on record or as instructed. Tickets

  13. EA-284-C NOBLE AMERICAS ENERGY SOLUTIONS LLC | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    C NOBLE AMERICAS ENERGY SOLUTIONS LLC EA-284-C NOBLE AMERICAS ENERGY SOLUTIONS LLC Order authorizing Noble Americas Energy Solutions to export electric energy to Mexico. PDF icon ...

  14. Lower Pennsylvanian reservoirs of Parkway-Empire south field area, Eddy County, New Mexico

    SciTech Connect (OSTI)

    James, A.D.

    1984-01-01

    The Parkway-Empire area is located on the Northwest shelf in central Eddy County, approximately 15 mi (24 km) northeast of Carlsbad, New Mexico. This area produces oil and gas from the lower and middle Morrow sandstones, Atoka sandstones, and Strawn limestones. Oil is also produced from the Queen and Seven Rivers sandstones, and the Grayburg, San Andres, and Wolfcamp dolomites. All of the these zones are productive from stratigraphic traps. The lower Morrow sandstones occur at a depth of about 11,400 ft (3,474 m). In the Parkway area, the middle Morrow sandstones are thought to be a transgressive series of marine beaches and submarine bars which trend toward the northeast, parallel to depositional strike. Stratigraphic traps are created in the lower and middle Morrow sandstones by variations in cementation and depositional patterns. Productive Atoka sandstones occur at a depth of approximately 10,700 ft (3,261 m). Strawn limestones produce from a series of small, low-relief algal banks developed along depositional strike to the northeast. The Strawn limestone is about 300 ft (91 m) thick and occurs between 10,250 and 10,500 ft (3,124 and 3,200 m). Wells in this area have typical ultimate recoveries of between 1.0 and 3.0 bcf of gas. The combination of stacked reservoirs and good production makes this area of the Morrow trend especially attractive.

  15. Nobles Wind Farm II | Open Energy Information

    Open Energy Info (EERE)

    Farm II Jump to: navigation, search Name Nobles Wind Farm II Facility Nobles Wind Farm II Sector Wind energy Facility Type Commercial Scale Wind Facility Status In Service Owner...

  16. Foothills Parkway Section 8B Final Environmental Report, Volume 5, Appendices J-M

    SciTech Connect (OSTI)

    Blasing, T.J.; Cada, G.F.; Carer, M.; Chin, S.M.; Dickerman, J.A.; Etnier, D.A.; Gibson, R.; Harvey, M.; Hatcher, B.; Lietzske, D.; Mann, L.K.; Mulholland, P.J.; Petrich, C.H.; Pounds, L.; Ranney, J.; Reed, R.M.; Ryan, P.F.; Schweitzer, M.; Smith, D.; Thomason, P.; Wade, M.C.

    1999-07-01

    In 1994, Oak Ridge National Laboratory (ORNL) was tasked by the National Park Service (NPS) to prepare an Environmental Report (ER) for Section 8B of the Foothills Parkway in the Great Smoky Mountains National Park (GSMNP). Section 8B represents 27.7 km (14.2 miles) of a total of 115 km (72 miles) of the planned Foothills Parkway and would connect the Cosby community on the east to the incorporated town of Pittman Center to the west. The major deliverables for the project are listed. From August 1995 through October 1996, NPS, GSMNP, and ORNL staff interacted with Federal Highway Administration staff to develop a conceptual design plan for Section 8B with the intent of protecting critical resources identified during the ER process to the extent possible. In addition, ORNL arranged for bioengineering experts to discuss techniques that might be employed on Section 8B with NPS, GSMNP, and ORNL staff during September 1996. For the purposes of this ER, there are two basic alternatives under consideration: (1) a build alternative and (2) a no-build alternative. Within the build alternative are a number of options including constructing Section 8B with no interchanges, constructing Section 8B with an interchange at SR 416 or U.S. 321, constructing Section 8B with a spur road on Webb Mountain, and considering operation of Section 8B both before and after the operation of Section 8C. The no-build alternative is considered the no-action alternative and is not to construct Section 8B. This volume of the ER consists of Appendices J through M, which describe potential impacts regarding traffic, noise, and aesthetics. The results of the traffic studies described in these appendices resulted in the following conclusions: Unacceptable levels of service will occur on numerous roads within and outside of the park increasingly in the Mure based upon current and future regional growth. However, the results of the traffic assessment indicated that there would be no significant or

  17. Foothills Parkway Section 8B Final Environmental Report, Volume 3, Appendix D

    SciTech Connect (OSTI)

    Blasing, T.J.; Cada, G.F.; Carer, M.; Chin, S.M.; Dickerman, J.A.; Etnier, D.A.; Gibson, R.; Harvey, M.; Hatcher, B.; Lietzske, D.; Mann, L.K.; Mulholland, P.J.; Petrich, C.H.; Pounds, L.; Ranney, J.; Reed, R.M.; Ryan, P.F.; Schweitzer, M.; Smith, D.; Thomason, P.; Wade, M.C.

    1999-07-01

    In 1994, Oak Ridge National Laboratory (ORNL) was tasked by the National Park Service (NPS) to prepare an Environmental Report (ER) for Section 8B of the Foothills Parkway in the Great Smoky Mountains National Park (GSMNP). Section 8B represents 27.7 km (14.2 miles) of a total of 115 km (72 miles) of the planned Foothills Parkway and would connect the Cosby community on the east to the incorporated town of Pittman Center to the west. The major deliverables for the project are listed. From August 1995 through October 1996, NPS, GSMNP, and ORNL staff interacted with Federal Highway Administration staff to develop a conceptual design plan for Section 8B with the intent of protecting critical resources identified during the ER process to the extent possible. In addition, ORNL arranged for bioengineering experts to discuss techniques that might be employed on Section 8B with NPS, GSMNP, and ORNL staff during September 1996. For the purposes of this ER, there are two basic alternatives under consideration: (1) a build alternative and (2) a no-build alternative. Within the build alternative are a number of options including constructing Section 8B with no interchanges, constructing Section 8B with an interchange at SR416 or U.S. 321, constructing Section 8B with a spur road on Webb Mountain, and considering operation of Section 8B both before and after the operation of Section 8C. The no-build alternative is considered the no-action alternative and is not to construct Section 8B. This volume of the ER inventories the fishes and benthic macroinvertebrates inhabiting the aquatic ecosystems potentially affected by the proposed construction of Section 8B. Stream biological surveys were completed at 31 stream sites during the Fall of 1994. The sampling strategy for both invertebrates and fish was to survey the different taxa from all available habitats. For benthic invertebrates, a standardized qualitative manual collection technique was employed for all 31 stations. For fish

  18. Foothills Parkway Section 8B Final Environmental Report, Volume 6, Appendix N

    SciTech Connect (OSTI)

    Blasing, T.J.; Cada, G.F.; Carer, M.; Chin, S.M.; Dickerman, J.A.; Etnier, D.A.; Gibson, R.; Harvey, M.; Hatcher, B.; Lietzske, D.; Mann, L.K.; Mulholland, P.J.; Petrich, C.H.; Pounds, L.; Ranney, J.; Reed, R.M.; Ryan, P.F.; Schweitzer, M.; Smith, D.; Thomason, P.; Wade, M.C.

    1999-07-01

    In 1994, Oak Ridge National Laboratory (ORNL) was tasked by the National Park Service (NPS) to prepare an Environmental Report (ER) for Section 8B of the Foothills Parkway in the Great Smoky Mountains National Park (GSMNP). Section 8B represents 27.7 km (14.2 miles) of a total of 115 km (72 miles) of the planned Foothills Parkway and would connect the Cosby community on the east to the incorporated town of Pittman Center to the west. The major deliverables for the project are listed. From August 1995 through October 1996, NPS, GSMNP, and ORNL staff interacted with Federal Highway Administration staff to develop a conceptual design plan for Section 8B with the intent of protecting critical resources identified during the ER process to the extent possible. In addition, ORNL arranged for bioengineering experts to discuss techniques that might be employed on Section 8B with NPS, GSMNP, and ORNL staff during September 1996. For the purposes of this ER, there are two basic alternatives under consideration: (1) a build alternative and (2) a no-build alternative. Within the build alternative are a number of options including constructing Section 8B with no interchanges, constructing Section 8B with an interchange at SR 416 or U.S. 321, constructing Section 8B with a spur road on Webb Mountain, and considering operation of Section 8B both before and after the operation of Section 8C. The no-build alternative is considered the no-action alternative and is not to construct Section 8B. This volume of the ER documents the results of the architectural, historical, and cultural resources assessment for the entire Section 8B ROW that was completed in May 1995 to document the architectural, historical, and cultural resources located within the project area. The assessment included evaluation of the potential for cultural (i.e., rural historic) landscapes in the area of the ROW. The assessment showed that one National Register-listed property is located 0.3 mile south of the ROW

  19. Foothills Parkway Section 8B Final Environmental Report, Volume 4, Appendices E-I

    SciTech Connect (OSTI)

    Blasing, T.J.; Cada, G.F.; Carer, M.; Chin, S.M.; Dickerman, J.A.; Etnier, D.A.; Gibson, R.; Harvey, M.; Hatcher, B.; Lietzske, D.; Mann, L.K.; Mulholland, P.J.; Petrich, C.H.; Pounds, L.; Ranney, J.; Reed, R.M.; Ryan, P.F.; Schweitzer, M.; Smith, D.; Thomason, P.; Wade, M.C.

    1999-07-01

    In 1994, Oak Ridge National Laboratory (ORNL) was tasked by the National Park Service (NPS) to prepare an Environmental Report (ER) for Section 8B of the Foothills Parkway in the Great Smoky Mountains National Park (GSMNP). Section 8B represents 27.7 km (14.2 miles) of a total of 115 km (72 miles) of the planned Foothills Parkway and would connect the Cosby community on the east to the incorporated town of Pittman Center to the west. The major deliverables for the project are listed. From August 1995 through October 1996, NPS, GSMNP, and ORNL staff interacted with Federal Highway Administration staff to develop a conceptual design plan for Section 8B with the intent of protecting critical, resources identified during the ER process to the extent possible. In addition, ORNL arranged for bioengineering experts to discuss techniques that might be employed on Section 8B with NPS, GSMNP, and ORNL staff during September 1996. For the purposes of this ER, there are two basic alternatives under consideration: (1) a build alternative and (2) a no-build alternative. Within the build alternative are a number of options including constructing Section 8B with no interchanges, constructing Section 8B with an interchange at SR 416 or U.S. 321, constructing Section 8B with a spur road on Webb Mountain, and considering operation of Section 8B both before and after the operation of Section 8C. The no-build alternative is considered the no-action alternative and is not to construct Section 8B. This volume of the ER consists of Appendices E through I (all ecological survey reports), which are summarized individually in the sections that follow. The following conclusions result from the completion of these surveys and the ER impact analysis: (1) Forest clearing should be limited as much as possible; (2) Disturbed areas should be replanted with native trees; (3) Drainages should be bridged rather than leveled with cut and fill; (4) For areas of steep slopes and potential erosion

  20. EA-364-A Noble Americas Gas & Power Corporation | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    -A Noble Americas Gas & Power Corporation EA-364-A Noble Americas Gas & Power Corporation Order authorizing NAG&P to export electric energy to Canada. PDF icon EA-364-A Noble ...

  1. EA-363-A Noble Americas MX.pdf

    Office of Environmental Management (EM)

    3 Noble Americas Gas & Power Corporation EA-363 Noble Americas Gas & Power Corporation Order authorizong Noble Americas Gas & Power Corporation to export electric energy to Mexico EA-363 Noble Americas Gas & Power Corporation (2.58 MB) More Documents & Publications Record of Categorical Exclusion (CS) Determination, Office of Electricity Delivery and Energy Reliability (OE): EA-363 Noble Americas Gas & Power Corporation EA-364 Noble Americas Gas & Power Corporation

  2. EA-363 Noble Americas Gas & Power Corporation | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Gas & Power Corporation Order authorizong Noble Americas Gas & Power Corporation to export electric energy to Mexico PDF icon EA-363 Noble Americas Gas & Power Corporation...

  3. Noble Gas Adsorption in Metal-Organic Frameworks Containing Open...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Noble Gas Adsorption in Metal-Organic Frameworks Containing Open Metal Sites Previous Next ... accessibility in this topology enhance the framework interaction with the noble gases. ...

  4. Noble Gas Geochemistry In Thermal Springs | Open Energy Information

    Open Energy Info (EERE)

    Noble Gas Geochemistry In Thermal Springs Abstract The composition of noble gases in both gas and water samples collected from Horseshoe Spring, Yellowstone National Park, was...

  5. Platinum-coated non-noble metal-noble metal core-shell electrocatalysts

    DOE Patents [OSTI]

    Adzic, Radoslav; Zhang, Junliang; Mo, Yibo; Vukmirovic, Miomir

    2015-04-14

    Core-shell particles encapsulated by a thin film of a catalytically active metal are described. The particles are preferably nanoparticles comprising a non-noble core with a noble metal shell which preferably do not include Pt. The non-noble metal-noble metal core-shell nanoparticles are encapsulated by a catalytically active metal which is preferably Pt. The core-shell nanoparticles are preferably formed by prolonged elevated-temperature annealing of nanoparticle alloys in an inert environment. This causes the noble metal component to surface segregate and form an atomically thin shell. The Pt overlayer is formed by a process involving the underpotential deposition of a monolayer of a non-noble metal followed by immersion in a solution comprising a Pt salt. A thin Pt layer forms via the galvanic displacement of non-noble surface atoms by more noble Pt atoms in the salt. The overall process is a robust and cost-efficient method for forming Pt-coated non-noble metal-noble metal core-shell nanoparticles.

  6. Incorporation of noble metals into aerogels

    DOE Patents [OSTI]

    Hair, L.M.; Sanner, R.D.; Coronado, P.R.

    1998-12-22

    Aerogels or xerogels containing atomically dispersed noble metals for applications such as environmental remediation are disclosed. New noble metal precursors, such as Pt--Si or Pd(Si--P){sub 2}, have been created to bridge the incompatibility between noble metals and oxygen, followed by their incorporation into the aerogel or xerogel through sol-gel chemistry and processing. Applications include oxidation of hydrocarbons and reduction of nitrogen oxide species, complete oxidation of volatile organic carbon species, oxidative membranes for photocatalysis and partial oxidation for synthetic applications.

  7. Incorporation of noble metals into aerogels

    DOE Patents [OSTI]

    Hair, Lucy M.; Sanner, Robert D.; Coronado, Paul R.

    1998-01-01

    Aerogels or xerogels containing atomically dispersed noble metals for applications such environmental remediation. New noble metal precursors, such as Pt--Si or Pd(Si--P).sub.2, have been created to bridge the incompatibility between noble metals and oxygen, followed by their incorporation into the aerogel or xerogel through sol-gel chemistry and processing. Applications include oxidation of hydrocarbons and reduction of nitrogen oxide species, complete oxidation of volatile organic carbon species, oxidative membranes for photocatalysis and partial oxidation for synthetic applications.

  8. Light Collection in Liquid Noble Gases

    SciTech Connect (OSTI)

    McKinsey, Dan [Yale University

    2013-05-29

    Liquid noble gases are increasingly used as active detector materials in particle and nuclear physics. Applications include calorimeters and neutrino oscillation experiments as well as searches for neutrinoless double beta decay, direct dark matter, muon electron conversion, and the neutron electric dipole moment. One of the great advantages of liquid noble gases is their copious production of ultraviolet scintillation light, which contains information about event energy and particle type. I will review the scintillation properties of the various liquid noble gases and the means used to collect their scintillation light, including recent advances in photomultiplier technology and wavelength shifters.

  9. Noble REMC- Buisness Energy Efficiency Rebate Incentives

    Broader source: Energy.gov [DOE]

    Noble REMC, with the Wabash Vally Power Association offers business rebate incentives through its POWER MOVES program.  Incentives are available on a first-come, first-served basis. View the...

  10. Nobles Cooperative Electric (Iowa) | Open Energy Information

    Open Energy Info (EERE)

    (Iowa) Jump to: navigation, search Name: Nobles Cooperative Electric Place: Iowa Phone Number: 1-507-372-7331 Website: www.noblesce.coop Outage Hotline: 1-507-372-7331 Outage Map:...

  11. Photosensitive dopants for liquid noble gases

    DOE Patents [OSTI]

    Anderson, David F.

    1988-01-01

    In an ionization type detector for high energy radiation wherein the energy of incident radiation is absorbed through the ionization of a liquid noble gas and resulting free charge is collected to form a signal indicative of the energy of the incident radiation, an improvement comprising doping the liquid noble gas with photosensitive molecules to convert scintillation light due to recombination of ions, to additional free charge.

  12. EA-363-A Noble Americas Gas & Power Corporation | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    EA-363-A Noble Americas Gas & Power Corporation Order authorizing NAG&P to export electric energy to Mexico. PDF icon EA-363-A Noble Americas MX.pdf More Documents & Publications ...

  13. Noble County R E M C | Open Energy Information

    Open Energy Info (EERE)

    Noble County R E M C Jump to: navigation, search Name: Noble County R E M C Place: Indiana Phone Number: 800.933.7362 or 260-636-2113 Website: www.nobleremc.com Twitter:...

  14. EA-284-C Noble Americas.pdf

    Office of Environmental Management (EM)

    4-A Sempra Energy Solutions EA-284-A Sempra Energy Solutions Order authorizing Sempra Energy Solutions to export electric energy to Mexico. EA-284-A Sempra Energy Solutions (2.32 MB) More Documents & Publications EA-284-A Sempra Energy Solutions: Temporary Extension EA-406 Sempra Generation, LLC EA-284-C NOBLE AMERICAS ENERGY SOLUTIONS LLC

  15. CONTROL ROD ALLOY CONTAINING NOBLE METAL ADDITIONS

    DOE Patents [OSTI]

    Anderson, W.K.; Ray, W.E.

    1960-05-01

    Silver-base alloys suitable for use in the fabrication of control rods for neutronic reactors are given. The alloy consists of from 0.5 wt.% to about 1.5 wt.% of a noble metal of platinum, ruthenium, rhodium, osmium, or palladium, up to 10 wt.% of cadmium, from 2 to 20 wt.% indium, the balance being silver.

  16. Noble County, Oklahoma: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    County, Oklahoma Billings, Oklahoma Marland, Oklahoma Morrison, Oklahoma Perry, Oklahoma Red Rock, Oklahoma Retrieved from "http:en.openei.orgwindex.php?titleNobleCounty,Okl...

  17. Inert electrode containing metal oxides, copper and noble metal

    DOE Patents [OSTI]

    Ray, Siba P.; Woods, Robert W.; Dawless, Robert K.; Hosler, Robert B.

    2001-01-01

    A cermet composite material is made by treating at an elevated temperature a mixture comprising a compound of iron and a compound of at least one other metal, together with an alloy or mixture of copper and a noble metal. The alloy or mixture preferably comprises particles having an interior portion containing more copper than noble metal and an exterior portion containing more noble metal than copper. The noble metal is preferably silver. The cermet composite material preferably includes alloy phase portions and a ceramic phase portion. At least part of the ceramic phase portion preferably has a spinel structure.

  18. Inert electrode containing metal oxides, copper and noble metal

    DOE Patents [OSTI]

    Ray, Siba P.; Woods, Robert W.; Dawless, Robert K.; Hosler, Robert B.

    2000-01-01

    A cermet composite material is made by treating at an elevated temperature a mixture comprising a compound of iron and a compound of at least one other metal, together with an alloy or mixture of copper and a noble metal. The alloy or mixture preferably comprises particles having an interior portion containing more copper than noble metal and an exterior portion containing more noble metal than copper. The noble metal is preferably silver. The cermet composite material preferably includes alloy phase portions and a ceramic phase portion. At least part of the ceramic phase portion preferably has a spinel structure.

  19. Noble Americas Energy Solutions LLC (Connecticut) | Open Energy...

    Open Energy Info (EERE)

    LLC (Connecticut) Jump to: navigation, search Name: Noble Americas Energy Solutions LLC Place: Connecticut Phone Number: 1 877273-6772 Website: www.noblesolutions.com Outage...

  20. Datang Jilin Wind Power Stockholding Co Ltd Formerly Jilin Noble...

    Open Energy Info (EERE)

    Wind Power Stockholding Co Ltd Formerly Jilin Noble Wind Power Stockholding Co Ltd Jump to: navigation, search Name: Datang Jilin Wind Power Stockholding Co Ltd(Formerly Jilin...

  1. Test Results For Physical Separation Of Tritium From Noble Gases...

    Office of Environmental Management (EM)

    Test Results For Physical Separation Of Tritium From Noble Gases And It's Implications For Sensitivity And Accuracy In Air And Stack Monitoring Test Results For Physical Separation ...

  2. Noble Americas Energy Solutions LLC (District of Columbia) |...

    Open Energy Info (EERE)

    District of Columbia) Jump to: navigation, search Name: Noble Americas Energy Solutions LLC Place: District of Columbia References: EIA Form EIA-861 Final Data File for 2010 -...

  3. Noble Americas Energy Solutions LLC (New Jersey) | Open Energy...

    Open Energy Info (EERE)

    Jersey) Jump to: navigation, search Name: Noble Americas Energy Solutions LLC Place: New Jersey Phone Number: +1 877273-6772 Website: www.noblesolutions.com Outage Map:...

  4. Noble Americas Energy Solutions LLC (New York) | Open Energy...

    Open Energy Info (EERE)

    York) Jump to: navigation, search Name: Noble Americas Energy Solutions LLC Place: New York Phone Number: 1 877273-6772 Website: www.noblesolutions.com Outage Hotline: 1...

  5. Noble Americas Energy Solutions LLC (Ohio) | Open Energy Information

    Open Energy Info (EERE)

    Ohio) Jump to: navigation, search Name: Noble Americas Energy Solutions LLC Place: Ohio Website: www.noblesolutions.com Outage Hotline: 888896-8629 References: EIA Form EIA-861...

  6. Noble Americas Energy Solutions LLC (Pennsylvania) | Open Energy...

    Open Energy Info (EERE)

    Pennsylvania) Jump to: navigation, search Name: Noble Americas Energy Solutions LLC Place: Pennsylvania Phone Number: 1 888-896-8640 Website: www.noblesolutions.com Outage...

  7. Noble Americas Energy Solutions LLC (Illinois) | Open Energy...

    Open Energy Info (EERE)

    Illinois) Jump to: navigation, search Name: Noble Americas Energy Solutions LLC Place: Illinois Phone Number: 1 877-273-6772 Website: noblesolutions.com Outage Hotline: 1...

  8. Noble Americas Energy Solutions LLC (Maryland) | Open Energy...

    Open Energy Info (EERE)

    Maryland) Jump to: navigation, search Name: Noble Americas Energy Solutions LLC Place: Maryland Phone Number: 1 877273-6772 Website: www.noblesolutions.com Outage Hotline: 1 877...

  9. Noble Americas Energy Solutions LLC (Massachusetts) | Open Energy...

    Open Energy Info (EERE)

    Massachusetts) Jump to: navigation, search Name: Noble Americas Energy Solutions LLC Place: Massachusetts Phone Number: 1 877-273-6772 Website: noblesolutions.com Outage Hotline:...

  10. Noble Americas Energy Solutions LLC (Oregon) | Open Energy Information

    Open Energy Info (EERE)

    Oregon) Jump to: navigation, search Name: Noble Americas Energy Solutions LLC Place: Oregon Phone Number: 1 877-273-6772 Website: www.noblesolutions.com Outage Hotline: 1...

  11. EA-364 Noble Americas Gas & Power Corporation | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    4 Noble Americas Gas & Power Corporation EA-364 Noble Americas Gas & Power Corporation Order authorizong Noble Americas Gas & Power Corporation to export electric energy to Canada EA-364 Noble Americas Gas & Power Corporation (3.36 MB) More Documents & Publications Record of Categorical Exclusion (CS) Determination, Office of Electricity Delivery and Energy Reliability (OE): OE Docket EA-364 Noble Americas Gas & Power Corporation EA-363 Noble Americas Gas & Power

  12. Noble Americas Energy Solutions LLC (Maine) | Open Energy Information

    Open Energy Info (EERE)

    Maine) Jump to: navigation, search Name: Noble Americas Energy Solutions LLC Place: Maine Phone Number: 1 877-273-6772 Website: noblesolutions.com Outage Hotline: 1 888-896-8629...

  13. Nobles County, Minnesota: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Hide Map This article is a stub. You can help OpenEI by expanding it. Nobles County is a county in Minnesota. Its FIPS County Code is 105. It is classified as...

  14. Noble Americas Energy Solutions LLC (Texas) | Open Energy Information

    Open Energy Info (EERE)

    Noble Americas Energy Solutions LLC Place: Texas Website: www.noblesolutions.comindex.h Outage Hotline: 1 877273-6772 References: EIA Form EIA-861 Final Data File for 2010 -...

  15. Noble Americas Energy Solutions LLC (Delaware) | Open Energy...

    Open Energy Info (EERE)

    Delaware) Jump to: navigation, search Name: Noble Americas Energy Solutions LLC Place: Delaware Phone Number: 1 877273-6772 or 1 888896-8629 Website: www.noblesolutions.com...

  16. Noble Americas Energy Solutions LLC (Rhode Island) | Open Energy...

    Open Energy Info (EERE)

    Rhode Island) Jump to: navigation, search Name: Noble Americas Energy Solutions LLC Place: Rhode Island Phone Number: 1 877-273-6772 Website: noblesolutions.com Outage Hotline: 1...

  17. Non-Noble Metal Water Electrolysis Catalysts - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Non-Noble Metal Water Electrolysis Catalysts Brookhaven National Laboratory Contact BNL About This Technology Publications: PDF Document Publication Hydrogen-Evolution Catalysts Based on Non-Noble Metal Nickel Molybdenum Nitride Nanosheets (1,161 KB) a) TEM image of the stacked MoN nanosheets on carbon supports. The read and white arrows mark the nanosheets that lay flat and stand vertically, respectively. b) A HRTEM image with the crystal structure overlaid looking down along the

  18. Noble gas atmospheric monitoring at reprocessing facilities

    SciTech Connect (OSTI)

    Nakhleh, C.W.; Perry, R.T. Jr.; Poths, J.; Stanbro, W.D.; Wilson, W.B.; Fearey, B.L.

    1997-05-01

    The discovery in Iraq after the Gulf War of the existence of a large clandestine nuclear-weapon program has led to an across-the-board international effort, dubbed Programme 93+2, to improve the effectiveness and efficiency of International Atomic Energy Agency (IAEA) safeguards. One particularly significant potential change is the introduction of environmental monitoring (EM) techniques as an adjunct to traditional safeguards methods. Monitoring of stable noble gas (Kr, Xe) isotopic abundances at reprocessing plant stacks appears to be able to yield information on the burnup and type of the fuel being processed. To estimate the size of these signals, model calculations of the production of stable Kr, Xe nuclides in reactor fuel and the subsequent dilution of these nuclides in the plant stack are carried out for two case studies: reprocessing of PWR fuel with a burnup of 35 GWd/tU, and reprocessing of CAND fuel with a burnup of 1 GWd/tU. For each case, a maximum-likelihood analysis is used to determine the fuel burnup and type from the isotopic data.

  19. Underground Sources of Radioactive Noble Gas

    SciTech Connect (OSTI)

    Hayes, James C.; Bowyer, Ted W.; Cordova, Elsa A.; Kirkham, Randy R.; Misner, Alex C.; Olsen, Khris B.; Woods, Vincent T.; Emer, Dudley

    2013-05-01

    It is well known that radon is present in relatively high concentrations below the surface of the Earth due to natural decay of uranium and thorium. However, less information is available on the background levels of other isotopes such as 133Xe and 131mXe produced via spontaneous fission of either manmade or naturally occurring elements. The background concentrations of radioxenon in the subsurface are important to understand because these isotopes potentially can be used to confirm violations of the Comprehensive Nuclear-Test-Ban Treaty (CTBT) during an On-Site Inspection (OSI). Recently, Pacific Northwest National Laboratory (PNNL) measured radioxenon concentrations from the subsurface at the Nevada Nuclear Security Site (NNSS—formerly known as the Nevada Test Site) to determine whether xenon isotope background levels could be detected from spontaneous fission of naturally occurring uranium or legacy 240Pu as a result of historic nuclear testing. In this paper, we discuss the results of those measurements and review the sources of xenon background that must be taken into account during OSI noble gas measurements.

  20. Method and apparatus for measuring purity of noble gases

    DOE Patents [OSTI]

    Austin, Robert

    2008-04-01

    A device for detecting impurities in a noble gas includes a detection chamber and a source of pulsed ultraviolet light. The pulse of the ultraviolet light is transferred into the detection chamber and onto a photocathode, thereby emitting a cloud of free electrons into the noble gas within the detection chamber. The cloud of electrons is attracted to the opposite end of the detection chamber by a high positive voltage potential at that end and focused onto a sensing anode. If there are impurities in the noble gas, some or all of the electrons within the cloud will bond with the impurity molecules and not reach the sensing anode. Therefore, measuring a lower signal at the sensing anode indicates a higher level of impurities while sensing a higher signal indicates fewer impurities. Impurities in the range of one part per billion can be measured by this device.

  1. Isotopic mass-dependence of noble gas diffusion coefficients inwater

    SciTech Connect (OSTI)

    Bourg, I.C.; Sposito, G.

    2007-06-25

    Noble gas isotopes are used extensively as tracers inhydrologic and paleoclimatic studies. These applications requireknowledge of the isotopic mass (m) dependence of noble gas diffusioncoefficients in water (D), which has not been measured but is estimatedusing experimental D-values for the major isotopes along with an untestedrelationship from kinetic theory, D prop m-0.5. We applied moleculardynamics methods to determine the mass dependence of D for four noblegases at 298 K, finding that D prop m-beta with beta<0.2, whichrefutes the kinetic theory model underlying all currentapplications.

  2. Method for low temperature preparation of a noble metal alloy

    DOE Patents [OSTI]

    Even, Jr., William R. (Livermore, CA)

    2002-01-01

    A method for producing fine, essentially contamination free, noble metal alloys is disclosed. The alloys comprise particles in a size range of 5 to 500 nm. The method comprises 1. A method for preparing a noble metal alloy at low temperature, the method comprising the steps of forming solution of organometallic compounds by dissolving the compounds into a quantity of a compatible solvent medium capable of solvating the organometallic, mixing a portion of each solution to provide a desired molarity ratio of ions in the mixed solution, adding a support material, rapidly quenching droplets of the mixed solution to initiate a solute-solvent phase separation as the solvent freezes, removing said liquid cryogen, collecting and freezing drying the frozen droplets to produce a dry powder, and finally reducing the powder to a metal by flowing dry hydrogen over the powder while warming the powder to a temperature of about 150.degree. C.

  3. Nuclear magnetic resonance imaging with hyper-polarized noble gases

    SciTech Connect (OSTI)

    Schmidt, D.M.; George, J.S.; Penttila, S.I.; Caprihan, A.

    1997-10-01

    This is the final report of a six-month, Laboratory Directed Research and Development (LDRD) project at Los Alamos National Laboratory (LANL). The nuclei of noble gases can be hyper polarized through a laser-driven spin exchange to a degree many orders of magnitude larger than that attainable by thermal polarization without requiring a strong magnetic field. The increased polarization from the laser pumping enables a good nuclear magnetic resonance (NMR) signal from a gas. The main goal of this project was to demonstrate diffusion-weighted imaging of such hyper-polarized noble gas with magnetic resonance imaging (MRI). Possible applications include characterizing porosity of materials and dynamically imaging pressure distributions in biological or acoustical systems.

  4. New Way to Probe Noble Metal Nanoparticles | The Ames Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    New Way to Probe Noble Metal Nanoparticles For the first time researchers have found a way to study highly-dispersed metal nanoparticles and their reactions using dynamic nuclear polarization (DNP) surface-enhanced nuclear magnetic resonance spectroscopy (SENS). Nuclear magnetic resonance (NMR) spectroscopy is a researcher's equivalent to a physician's MRI, only in this case the patient is not a person but a material. Now researchers have demonstrated new DNP-based measurements that extend

  5. Fluid clathrate system for continuous removal of heavy noble gases from mixtures of lighter gases

    DOE Patents [OSTI]

    Gross, K.C.; Markun, F.; Zawadzki, M.T.

    1998-04-28

    An apparatus and method are disclosed for separation of heavy noble gas in a gas volume. An apparatus and method have been devised which includes a reservoir containing an oil exhibiting a clathrate effect for heavy noble gases with a reservoir input port and the reservoir is designed to enable the input gas volume to bubble through the oil with the heavy noble gas being absorbed by the oil exhibiting a clathrate effect. The gas having reduced amounts of heavy noble gas is output from the oil reservoir, and the oil having absorbed heavy noble gas can be treated by mechanical agitation and/or heating to desorb the heavy noble gas for analysis and/or containment and allow recycling of the oil to the reservoir. 6 figs.

  6. Fluid clathrate system for continuous removal of heavy noble gases from mixtures of lighter gases

    DOE Patents [OSTI]

    Gross, Kenneth C.; Markun, Francis; Zawadzki, Mary T.

    1998-01-01

    An apparatus and method for separation of heavy noble gas in a gas volume. An apparatus and method have been devised which includes a reservoir containing an oil exhibiting a clathrate effect for heavy noble gases with a reservoir input port and the reservoir is designed to enable the input gas volume to bubble through the oil with the heavy noble gas being absorbed by the oil exhibiting a clathrate effect. The gas having reduced amounts of heavy noble gas is output from the oil reservoir, and the oil having absorbed heavy noble gas can be treated by mechanical agitation and/or heating to desorb the heavy noble gas for analysis and/or containment and allow recycling of the oil to the reservoir.

  7. Noble Metals and Spinel Settling in High Level Waste Glass Melters

    SciTech Connect (OSTI)

    Sundaram, S. K.; Perez, Joseph M.

    2000-09-30

    In the continuing effort to support the Defense Waste Processing Facility (DWPF), the noble metals issue is addressed. There is an additional concern about the amount of noble metals expected to be present in the future batches that will be considered for vitrification in the DWPF. Several laboratory, as well as melter-scale, studies have been completed by various organizations (mainly PNNL, SRTC, and WVDP in the USA). This letter report statuses the noble metals issue and focuses at the settling of noble metals in melters.

  8. Inert anode containing base metal and noble metal useful for the electrolytic production of aluminum

    DOE Patents [OSTI]

    Ray, Siba P.; Liu, Xinghua

    2000-01-01

    An inert anode for production of metals such as aluminum is disclosed. The inert anode comprises a base metal selected from Cu and Ag, and at least one noble metal selected from Ag, Pd, Pt, Au, Rh, Ru, Ir and Os. The inert anode may optionally be formed of sintered particles having interior portions containing more base metal than noble metal and exterior portions containing more noble metal than base metal. In a preferred embodiment, the base metal comprises Cu, and the noble metal comprises Ag, Pd or a combination thereof.

  9. Application to Export Electric Energy OE Docket No. EA-363-A Noble Americas

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Gas & Power Corporation | Department of Energy Corporation Application to Export Electric Energy OE Docket No. EA-363-A Noble Americas Gas & Power Corporation Application from NAG&P to export electric energy to Mexico. EA-363-A Noble Americas G&P (MX).pdf (499.71 KB) More Documents & Publications EA-363-A Noble Americas Gas & Power Corporation Application to Export Electric Energy OE Docket No. EA-363-A Noble Americas Gas & Power Corporation: Federal Register

  10. Application to Export Electric Energy OE Docket No. EA-364-A Noble Americas

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Gas & Power Corporation | Department of Energy Corporation Application to Export Electric Energy OE Docket No. EA-364-A Noble Americas Gas & Power Corporation Application from NAG&P to export electric energy to Canada. EA-364-A Noble Americas G&P (CN).pdf (521.88 KB) More Documents & Publications EA-364-A Noble Americas Gas & Power Corporation Application to Export Electric Energy OE Docket No. EA-364-A Noble Americas Gas & Power Corporation: Federal Register

  11. Measuring the Noble Metal and Iodine Composition of Extracted Noble Metal Phase from Spent Nuclear Fuel Using Instrumental Neutron Activation Analysis

    SciTech Connect (OSTI)

    Palomares, R. I.; Dayman, Kenneth J.; Landsberger, Sheldon; Biegalski, Steven R.; Soderquist, Chuck Z.; Casella, Amanda J.; Brady Raap, Michaele C.; Schwantes, Jon M.

    2015-04-01

    Mass quantities of noble metal and iodine nuclides in the metallic noble metal phase extracted from spent fuel are measured using instrumental neutron activation analysis (NAA). Nuclide presence is predicted using fission yield analysis, and mass quantification is derived from standard gamma spectroscopy and radionuclide decay analysis. The nuclide compositions of noble metal phase derived from two dissolution methods, UO2 fuel dissolved in nitric acid and UO2 fuel dissolved in ammonium-carbonate and hydrogen-peroxide solution, are compared. Lastly, the implications of the rapid analytic speed of instrumental NAA are discussed in relation to potential nuclear forensics applications.

  12. DEVELOPMENT OF A NON-NOBLE METAL HYDROGEN PURIFICATION SYSTEM

    SciTech Connect (OSTI)

    Korinko, P; Kyle Brinkman, K; Thad Adams, T; George Rawls, G

    2008-11-25

    Development of advanced hydrogen separation membranes in support of hydrogen production processes such as coal gasification and as front end gas purifiers for fuel cell based system is paramount to the successful implementation of a national hydrogen economy. Current generation metallic hydrogen separation membranes are based on Pd-alloys. Although the technology has proven successful, at issue is the high cost of palladium. Evaluation of non-noble metal based dense metallic separation membranes is currently receiving national and international attention. The focus of the reported work was to develop a scaled reactor with a VNi-Ti alloy membrane to replace a production Pd-alloy tube-type purification/diffuser system.

  13. Noble gases and cosmogenic radionuclides in the Eltanin Pacific meteorite

    SciTech Connect (OSTI)

    Bogard, D D; Garrison, D H; Caffee, M W; Kyte, F; Nishiizumi, K

    2000-01-14

    A 1.5 cm long, 1.2 g specimen of the Eltanin meteorite was found at 10.97 m depth in Polarstern piston core PS2704-1. The early studies indicated that the small fragments of the Eltanin meteorite was debris from a km-sized asteroid which impacted into the deep-ocean basin. In this study, the authors measured {sup 39}Ar-{sup 40}Ar age, noble gases, and cosmogenic radionuclides in splits of specimen as a part of consortium studies of Eltanin meteorite. They concluded that the specimen was about 3 m deep from the asteroid surface. The exposure age of the Eltanin asteroid was about 20 Myr.

  14. DWPF Hydrogen Generation Study-Form of Noble Metal SRAT Testing

    SciTech Connect (OSTI)

    Bannochie, C

    2005-09-01

    The Defense Waste Processing Facility, DWPF, has requested that the Savannah River National Laboratory, SRNL, investigate the factors that contribute to hydrogen generation to determine if current conservatism in setting the DWPF processing window can be reduced. A phased program has been undertaken to increase understanding of the factors that influence hydrogen generation in the DWPF Chemical Process Cell, CPC. The hydrogen generation in the CPC is primarily due to noble metal catalyzed decomposition of formic acid with a minor contribution from radiolytic processes. Noble metals have historically been added as trim chemicals to process simulations. The present study investigated the potential conservatism that might be present from adding the catalytic species as trim chemicals to the final sludge simulant versus co-precipitating the noble metals into the insoluble sludge solids matrix. Two sludge simulants were obtained, one with co-precipitated noble metals and one without noble metals. Co-precipitated noble metals were expected to better match real waste behavior than using trimmed noble metals during CPC simulations. Portions of both sludge simulants were held at 97 C for about eight hours to qualitatively simulate the effects of long term storage on particle morphology and speciation. The two original and two heat-treated sludge simulants were then used as feeds to Sludge Receipt and Adjustment Tank, SRAT, process simulations. Testing was done at relatively high acid stoichiometries, {approx}175%, and without mercury in order to ensure significant hydrogen generation. Hydrogen generation rates were monitored during processing to assess the impact of the form of noble metals. The following observations were made on the data: (1) Co-precipitated noble metal simulant processed similarly to trimmed noble metal simulant in most respects, such as nitrite to nitrate conversion, formate destruction, and pH, but differently with respect to hydrogen generation: (A

  15. Appraisal of transport and deformation in shale reservoirs using natural noble gas tracers

    SciTech Connect (OSTI)

    Heath, Jason E.; Kuhlman, Kristopher L.; Robinson, David G.; Bauer, Stephen J.; Gardner, William Payton

    2015-09-01

    This report presents efforts to develop the use of in situ naturally-occurring noble gas tracers to evaluate transport mechanisms and deformation in shale hydrocarbon reservoirs. Noble gases are promising as shale reservoir diagnostic tools due to their sensitivity of transport to: shale pore structure; phase partitioning between groundwater, liquid, and gaseous hydrocarbons; and deformation from hydraulic fracturing. Approximately 1.5-year time-series of wellhead fluid samples were collected from two hydraulically-fractured wells. The noble gas compositions and isotopes suggest a strong signature of atmospheric contribution to the noble gases that mix with deep, old reservoir fluids. Complex mixing and transport of fracturing fluid and reservoir fluids occurs during production. Real-time laboratory measurements were performed on triaxially-deforming shale samples to link deformation behavior, transport, and gas tracer signatures. Finally, we present improved methods for production forecasts that borrow statistical strength from production data of nearby wells to reduce uncertainty in the forecasts.

  16. Methane activation using noble gases in a dielectric barrier discharge reactor

    SciTech Connect (OSTI)

    Jo, Sungkwon; Hoon Lee, Dae; Seok Kang, Woo; Song, Young-Hoon

    2013-08-15

    The conversion of methane is measured in a planar-type dielectric barrier discharge reactor using three different noble gasesHe, Ne, and Aras additives. The empirical results obtained clearly indicate that methane activation is considerably affected by thy type of noble gas used. Through 0-D calculations, the discharge parameters inside the reactor, i.e., electron temperature and electron density, are estimated using experiment results. A comparison of the discharge characteristics and experimental results shows that the electron temperature is an important factor in achieving high methane activation and the mixture with Ar gas shows the highest methane conversion. These results are constructed using the mechanisms of energy and charge transfer from excited and ionized noble gas atoms to methane molecules, considering the number density of active atoms of noble gases. Finally, electron temperatures obtained for gas mixtures having different reactant compositions and concentrations are analyzed to estimate methane activation.

  17. Saving the Fuel Cell Dream: Making Non Noble Metal Electrocatalysts a Reality?

    Broader source: Energy.gov [DOE]

    Presentation about non noble metal electrocatalysts, presented by Sanjeev Mukerjee, Northeastern University, at the kick-off meeting of the U.S. Department of Energy Fuel Cell Technologies Program's Catalysis Working Group, held May 14, 2012, in Arlington, Virginia.

  18. Fate of Noble Metals during the Pyroprocessing of Spent Nuclear Fuel

    SciTech Connect (OSTI)

    B.R. Westphal; D. Vaden; S.X. Li; G.L. Fredrickson; R.D. Mariani

    2009-09-01

    During the pyroprocessing of spent nuclear fuel by electrochemical techniques, fission products are separated as the fuel is oxidized at the anode and refined uranium is deposited at the cathode. Those fission products that are oxidized into the molten salt electrolyte are considered active metals while those that do not react are considered noble metals. The primary noble metals encountered during pyroprocessing are molybdenum, zirconium, ruthenium, rhodium, palladium, and technetium. Pyroprocessing of spent fuel to date has involved two distinctly different electrorefiner designs, in particular the anode to cathode configuration. For one electrorefiner, the anode and cathode collector are horizontally displaced such that uranium is transported across the electrolyte medium. As expected, the noble metal removal from the uranium during refining is very high, typically in excess of 99%. For the other electrorefiner, the anode and cathode collector are vertically collocated to maximize uranium throughput. This arrangement results in significantly less noble metals removal from the uranium during refining, typically no better than 20%. In addition to electrorefiner design, operating parameters can also influence the retention of noble metals, albeit at the cost of uranium recovery. Experiments performed to date have shown that as much as 100% of the noble metals can be retained by the cladding hulls while affecting the uranium recovery by only 6%. However, it is likely that commercial pyroprocessing of spent fuel will require the uranium recovery to be much closer to 100%. The above mentioned design and operational issues will likely be driven by the effects of noble metal contamination on fuel fabrication and performance. These effects will be presented in terms of thermal properties (expansion, conductivity, and fusion) and radioactivity considerations. Ultimately, the incorporation of minor amounts of noble metals from pyroprocessing into fast reactor metallic fuel

  19. DISRUPTION MITIGATION WITH HIGH-PRESSURE NOBLE GAS INJECTION

    SciTech Connect (OSTI)

    WHYTE, DG; JERNIGAN, TC; HUMPHREYS, DA; HYATT, AW; LASNIER, CJ; PARKS, PB; EVANS, TE; TAYLOR, PL; KELLMAN, AG; GRAY, DS; HOLLMANN, EM

    2002-10-01

    OAK A271 DISRUPTION MITIGATION WITH HIGH-PRESSURE NOBLE GAS INJECTION. High-pressure gas jets of neon and argon are used to mitigate the three principal damaging effects of tokamak disruptions: thermal loading of the divertor surfaces, vessel stress from poloidal halo currents and the buildup and loss of relativistic electrons to the wall. The gas jet penetrates as a neutral species through to the central plasma at its sonic velocity. The injected gas atoms increase up to 500 times the total electron inventory in the plasma volume, resulting in a relatively benign radiative dissipation of >95% of the plasma stored energy. The rapid cooling and the slow movement of the plasma to the wall reduce poloidal halo currents during the current decay. The thermally collapsed plasma is very cold ({approx} 1-2 eV) and the impurity charge distribution can include > 50% fraction neutral species. If a sufficient quantity of gas is injected, the neutrals inhibit runaway electrons. A physical model of radiative cooling is developed and validated against DIII-D experiments. The model shows that gas jet mitigation, including runaway suppression, extrapolates favorably to burning plasmas where disruption damage will be more severe. Initial results of real-time disruption detection triggering gas jet injection for mitigation are shown.

  20. EXTERNAL PHOTOEVAPORATION OF THE SOLAR NEBULA: JUPITER's NOBLE GAS ENRICHMENTS

    SciTech Connect (OSTI)

    Monga, Nikhil; Desch, Steven

    2015-01-01

    We present a model explaining the elemental enrichments in Jupiter's atmosphere, particularly the noble gases Ar, Kr, and Xe. While He, Ne, and O are depleted, seven other elements show similar enrichments (∼3 times solar, relative to H). Being volatile, Ar is difficult to fractionate from H{sub 2}. We argue that external photoevaporation by far-ultraviolet (FUV) radiation from nearby massive stars removed H{sub 2}, He, and Ne from the solar nebula, but Ar and other species were retained because photoevaporation occurred at large heliocentric distances where temperatures were cold enough (≲ 30 K) to trap them in amorphous water ice. As the solar nebula lost H, it became relatively and uniformly enriched in other species. Our model improves on the similar model of Guillot and Hueso. We recognize that cold temperatures alone do not trap volatiles; continuous water vapor production is also necessary. We demonstrate that FUV fluxes that photoevaporated the disk generated sufficient water vapor in regions ≲ 30 K to trap gas-phase species in amorphous water ice in solar proportions. We find more efficient chemical fractionation in the outer disk: whereas the model of Guillot and Hueso predicts a factor of three enrichment when only <2% of the disk mass remains, we find the same enrichments when 30% of the disk mass remains. Finally, we predict the presence of ∼0.1 M {sub ⊕} of water vapor in the outer solar nebula and protoplanetary disks in H II regions.

  1. Recovery of Noble Metals and Technetium from Nuclear Waste

    SciTech Connect (OSTI)

    Moon, J.K.; Han, Y.J.; Lee, E.H.; Jung, C.H.; Lee, B.C.

    2006-07-01

    An adsorptive separation of Pd, Rh and Tc was tested by using simulated chemical solutions. Pd(NO{sub 3}){sub 2} and Rh(NO{sub 3}){sub 3} were used for the noble metal sources, and Re 203 after dissolving it in 0.5 M nitric acid was used for the technetium substitute, respectively. A felt type ACF (activated carbon fiber) after being pretreated with 1 M NaOH, and an EIR (extractant impregnated resin) which was prepared by impregnating Aliquat 336 onto Amberlite XAD-4 resin were evaluated on their adsorption equilibrium and kinetic performances. As the results, the ACF showed a high selectivity for the palladium ions over the rhodium and rhenium ions. On the other hand, the EIR was shown to be effective for separation of rhenium from the palladium-free two component system of rhenium and rhodium. Column tests were also performed to confirm the separation efficiency of palladium and rhenium using a jacketed glass column (diam. 11 x L 150). The ACF bed showed the complete separation of palladium from rhenium and rhodium. The breakthrough volume, when 1% of breakthrough is considered, was about 140 BV for palladium, while only a small amount of an adsorption of rhenium and rhodium were found in the column. Then the EIR column was applied to separate rhenium from rhodium and showed successful separation performance with about 122 BV of breakthrough volume. The palladium and rhenium with high purity were recovered effectively by eluting the beds with nitric acid. (authors)

  2. Environmental effects on noble-gas hydrides: HXeBr, HXeCCH, and HXeH in noble-gas and molecular matrices

    SciTech Connect (OSTI)

    Tsuge, Masashi E-mail: leonid.khriachtchev@helsinki.fi; Lignell, Antti; Rsnen, Markku; Khriachtchev, Leonid E-mail: leonid.khriachtchev@helsinki.fi

    2013-11-28

    Noble-gas hydrides HNgY (Ng is a noble-gas atom and Y is an electronegative group) are sensitive probes of local environment due to their relatively weak bonding and large dipole moments. We experimentally studied HXeBr in Ar, Kr, and N{sub 2} matrices, HXeCCH in Ne and N{sub 2} matrices, and HXeH in an N{sub 2} matrix. These are the first observations of noble-gas hydrides in an N{sub 2} matrix. An N{sub 2} matrix strongly increases the HXe stretching frequency of HXeBr and HXeCCH with respect to a Ne matrix, which is presumably due to a strong interaction between the HNgY dipole moment and quadrupole moments of the surrounding lattice N{sub 2} molecules. The spectral shift of HXeBr in an N{sub 2} matrix is similar to that in a CO{sub 2} matrix, which is a rather unexpected result because the quadrupole moment of CO{sub 2} is about three times as large as that of N{sub 2}. The HXe stretching frequencies of HXeBr and HXeCCH in noble-gas matrices show a trend of ?(Ne) < ?(Xe) < ?(Kr) < ?(Ar), which is a non-monotonous function of the dielectric constants of the noble-gas solids. The MP2(full) calculations of HXeBr and HXeCCH with the polarizable continuum model as well as the CCSD(T) calculations of the HXeBrNg and HXeCCHNg (Ng = Ne, Ar, Kr, and Xe) complexes cannot fully explain the experimental observations. It is concluded that more sophisticated computational models should be used to describe these experimental findings.

  3. Method and apparatus for noble gas atom detection with isotopic selectivity

    DOE Patents [OSTI]

    Hurst, G. Samuel; Payne, Marvin G.; Chen, Chung-Hsuan; Parks, James E.

    1984-01-01

    Apparatus and methods of operation are described for determining, with isotopic selectivity, the number of noble gas atoms in a sample. The analysis is conducted within an evacuated chamber which can be isolated by a valve from a vacuum pumping system capable of producing a pressure of 10.sup.-8 Torr. Provision is made to pass pulses of laser beams through the chamber, these pulses having wavelengths appropriate for the resonance ionization of atoms of the noble gas under analysis. A mass filter within the chamber selects ions of a specific isotope of the noble gas, and means are provided to accelerate these selected ions sufficiently for implantation into a target. Specific types of targets are discussed. An electron measuring device produces a signal relatable to the number of ions implanted into the target and thus to the number of atoms of the selected isotope of the noble gas removed from the gas sample. The measurement can be continued until a substantial fraction, or all, of the atoms in the sample have been counted. Furthermore, additional embodiments of the apparatus are described for bunching the atoms of a noble gas for more rapid analysis, and for changing the target for repetitive cycling of the gas in the chamber. The number of repetitions of the cyclic steps depend upon the concentration of the isotope of interest, the separative efficiency of the mass filter, etc. The cycles are continued until a desired selectivity is achieved. Also described are components and a method of operation for a pre-enrichment operation for use when an introduction of a total sample would elevate the pressure within the chamber to levels in excess of those for operation of the mass filter, specifically a quadrupole mass filter. Specific examples of three noble gas isotope analyses are described.

  4. First-principles study of noble gas impurities and defects in UO{sub 2}

    SciTech Connect (OSTI)

    Thompson, Alexander E.; Wolverton, C.

    2011-10-01

    We performed a series of density functional theory + U (DFT + U) calculations to explore the energetics of various defects in UO{sub 2}, i.e., noble gases (He, Ne, Ar, Kr, Xe), Schottky defects, and the interaction between these defects. We found the following: (1) collinear antiferromagnetic UO{sub 2} has an energy-lowering distortion of the oxygen sublattice from ideal fluorite positions; (2) DFT + U qualitatively affects the formation volume of Schottky defect clusters in UO{sub 2} (without U the formation volume is negative, but including U the formation volume is positive); (3) the configuration of the Schottky defect cluster is dictated by a competition between electrostatic and surface energy effects; (4) the incorporation energy of inserting noble gas atoms into an interstitial site has a strong dependence on the volume of the noble gas atom, corresponding to the strain it causes in the interstitial site, from He (0.98 eV) to Xe (9.73 eV); (5) the energetics of each of the noble gas atoms incorporated in Schottky defects show strong favorable binding, due to strain relief associated with moving the noble gas atom from the highly strained interstitial position into the vacant space of the Schottky defect; and (6) for argon, krypton, and xenon, the binding energy of a noble gas impurity with the Schottky defect is larger than the formation energy of a Schottky defect, thereby making the formation of Schottky defects thermodynamically favorable in the presence of these large impurities.

  5. Application to Export Electric Energy OE Docket No. EA-363-A Noble Americas

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Gas & Power Corporation: Federal Register Notice, Volume 80, No. 42 - March 4, 2015 | Department of Energy Corporation: Federal Register Notice, Volume 80, No. 42 - March 4, 2015 Application to Export Electric Energy OE Docket No. EA-363-A Noble Americas Gas & Power Corporation: Federal Register Notice, Volume 80, No. 42 - March 4, 2015 Application from NAG&P to export electric energy to Mexico. Federal Register Notice. EA-363-A Noble Americas (MX).pdf (250.1 KB) More Documents

  6. Application to Export Electric Energy OE Docket No. EA-364-A Noble Americas

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Gas & Power Corporation: Federal Register Notice, Volume 80, No. 42 - March 4, 2015 | Department of Energy Corporation: Federal Register Notice, Volume 80, No. 42 - March 4, 2015 Application to Export Electric Energy OE Docket No. EA-364-A Noble Americas Gas & Power Corporation: Federal Register Notice, Volume 80, No. 42 - March 4, 2015 Application from NAG&P to export electric energy to Canada. Federal Register Notice. EA-364-A Noble Americas (CN).pdf (245.09 KB) More Documents

  7. Solid polymer electrolyte composite membrane comprising a porous support and a solid polymer electrolyte including a dispersed reduced noble metal or noble metal oxide

    SciTech Connect (OSTI)

    Liu, Han; Mittelsteadt, Cortney K; Norman, Timothy J; Griffith, Arthur E; LaConti, Anthony B

    2015-02-24

    A solid polymer electrolyte composite membrane and method of manufacturing the same. According to one embodiment, the composite membrane comprises a thin, rigid, dimensionally-stable, non-electrically-conducting support, the support having a plurality of cylindrical, straight-through pores extending perpendicularly between opposing top and bottom surfaces of the support. The pores are unevenly distributed, with some or no pores located along the periphery and more pores located centrally. The pores are completely filled with a solid polymer electrolyte, the solid polymer electrolyte including a dispersed reduced noble metal or noble metal oxide. The solid polymer electrolyte may also be deposited over the top and/or bottom surfaces of the support.

  8. NOBLE METAL CHEMISTRY AND HYDROGEN GENERATION DURING SIMULATED DWPF MELTER FEED PREPARATION

    SciTech Connect (OSTI)

    Koopman, D

    2008-06-25

    Simulations of the Defense Waste Processing Facility (DWPF) Chemical Processing Cell vessels were performed with the primary purpose of producing melter feeds for the beaded frit program plus obtaining samples of simulated slurries containing high concentrations of noble metals for off-site analytical studies for the hydrogen program. Eight pairs of 22-L simulations were performed of the Sludge Receipt and Adjustment Tank (SRAT) and Slurry Mix Evaporator (SME) cycles. These sixteen simulations did not contain mercury. Six pairs were trimmed with a single noble metal (Ag, Pd, Rh, or Ru). One pair had all four noble metals, and one pair had no noble metals. One supporting 4-L simulation was completed with Ru and Hg. Several other 4-L supporting tests with mercury have not yet been performed. This report covers the calculations performed on SRNL analytical and process data related to the noble metals and hydrogen generation. It was originally envisioned as a supporting document for the off-site analytical studies. Significant new findings were made, and many previous hypotheses and findings were given additional support as summarized below. The timing of hydrogen generation events was reproduced very well within each of the eight pairs of runs, e.g. the onset of hydrogen, peak in hydrogen, etc. occurred at nearly identical times. Peak generation rates and total SRAT masses of CO{sub 2} and oxides of nitrogen were reproduced well. Comparable measures for hydrogen were reproduced with more variability, but still reasonably well. The extent of the reproducibility of the results validates the conclusions that were drawn from the data.

  9. Electrochemical synthesis of elongated noble metal nanoparticles, such as nanowires and nanorods, on high-surface area carbon supports

    DOE Patents [OSTI]

    Adzic, Radoslav; Blyznakov, Stoyan; Vukmirovic, Miomir

    2015-08-04

    Elongated noble-metal nanoparticles and methods for their manufacture are disclosed. The method involves the formation of a plurality of elongated noble-metal nanoparticles by electrochemical deposition of the noble metal on a high surface area carbon support, such as carbon nanoparticles. Prior to electrochemical deposition, the carbon support may be functionalized by oxidation, thus making the manufacturing process simple and cost-effective. The generated elongated nanoparticles are covalently bound to the carbon support and can be used directly in electrocatalysis. The process provides elongated noble-metal nanoparticles with high catalytic activities and improved durability in combination with high catalyst utilization since the nanoparticles are deposited and covalently bound to the carbon support in their final position and will not change in forming an electrode assembly.

  10. Nano-structured noble metal catalysts based on hexametallate architecture for the reforming of hydrocarbon fuels

    DOE Patents [OSTI]

    Gardner, Todd H.

    2015-09-15

    Nano-structured noble metal catalysts based on hexametallate lattices, of a spinel block type, and which are resistant to carbon deposition and metal sulfide formation are provided. The catalysts are designed for the reforming of hydrocarbon fuels to synthesis gas. The hexametallate lattices are doped with noble metals (Au, Pt, Rh, Ru) which are atomically dispersed as isolated sites throughout the lattice and take the place of hexametallate metal ions such as Cr, Ga, In, and/or Nb. Mirror cations in the crystal lattice are selected from alkali metals, alkaline earth metals, and the lanthanide metals, so as to reduce the acidity of the catalyst crystal lattice and enhance the desorption of carbon deposit forming moieties such as aromatics. The catalysts can be used at temperatures as high as 1000.degree. C. and pressures up to 30 atmospheres. A method for producing these catalysts and applications of their use also is provided.

  11. Highly concentrated nebular noble gases in porous nanocarbon separates from the Saratov (L4) meteorite

    SciTech Connect (OSTI)

    Amari, Sachiko; Matsuda, Jun-ichi; Stroud, Rhonda M.; Chisholm, Matthew F.

    2013-11-20

    The majority of heavy noble gases (Ar, Kr, and Xe) in primitive meteorites are stored in a poorly understood phase called Q. Although Q is thought to be carbonaceous, the full identity of the phase has remained elusive for almost four decades. In order to better characterize phase Q and, in turn, the early solar nebula, we separated carbon-rich fractions from the Saratov (L4) meteorite. We chose this meteorite because Q is most resistant in thermal alteration among carbonaceous noble gas carriers in meteorites and we hoped that, in this highly metamorphosed meteorite, Q would be present but not diamond: these two phases are very difficult to separate from each other. One of the fractions, AJ, has the highest {sup 132}Xe concentration of 2.1 10{sup 6} cm{sup 3} STP g{sup 1}, exceeding any Q-rich fractions that have yet been analyzed. Transmission electron microscopy studies of the fraction AJ and a less Q-rich fraction AI indicate that they both are primarily porous carbon that consists of domains with short-range graphene orders, with variable packing in three dimensions, but no long-range graphitic order. The relative abundance of Xe and C atoms (6:10{sup 9}) in the separates indicates that individual noble gas atoms are associated with only a minor component of the porous carbon, possibly one or more specific arrangements of the nanoparticulate graphene.

  12. Golden Field Office 15013 Denver West Parkway

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Project will not significantly affect the quality of the human and natural environment. ... for research and educational opportunities with energy production as an ancillary benefit. ...

  13. Golden Field Office 15013 Denver West Parkway

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    U.S. Department of Interior, Bureau of Ocean Energy Management (BOEM) off the coast of ... any of the Proposed Project buoys or deployment vessels during the installation, ...

  14. Record of Categorical Exclusion (CS) Determination, Office of Electricity Delivery and Energy Reliability (OE): EA-363 Noble Americas Gas & Power Corporation

    Broader source: Energy.gov [DOE]

    Record of Categorical Exclusion (CS) Determination, Office of Electricity Delivery and Energy Reliability (OE):  Noble Americas Gas & Power Corporation to export electric energy to Mexico

  15. Record of Categorical Exclusion (CS) Determination, Office of Electricity Delivery and Energy Reliability (OE): OE Docket EA-364 Noble Americas Gas & Power Corporation

    Broader source: Energy.gov [DOE]

    Record of Categorical Exclusion (CS) Determination, Office of Electricity Delivery and Energy Reliability (OE):  Application from Noble Americas Gas & Power Corporation to export electric...

  16. Method for localized deposition of noble metal catalysts with control of morphology

    DOE Patents [OSTI]

    Ricco, Antonio J.; Manginell, Ronald P.; Huber, Robert J.

    1998-01-01

    A combustible gas sensor that uses a resistively heated, noble metal-coated, micromachined polycrystalline Si filament to calorimetrically detect the presence and concentration of combustible gases. A thin catalytic Pt film was deposited by CVD from the precursor Pt(acac).sub.2 onto microfilaments resistively heated to approximately 500 .degree. C.; Pt deposits only on the hot filament. The filaments tested to date are 2 .mu.m thick .times.10 .mu.m wide .times.100, 250, 500, or 1000 .mu.m-long polycrystalline Si; some are overcoated with a 0.25 .mu.m-thick protective CVD Si.sub.3 N.sub.4 layer.

  17. Results from the XENON10 and the Race to Detect Dark Matter with Noble Liquids

    ScienceCinema (OSTI)

    Shutt, Tom [Case Western Reserve, Cleveland, Ohio, United States

    2009-09-01

    Detectors based on liquid noble gases have the potential to revolutionize the direct search for WIMP dark matter. The XENON10 experiment, of which I am a member, has recently announced the results from it's first data run and is now the leading WIMP search experiment. This and other experiments using xenon, argon and neon have the potential to rapidly move from the current kg-scale target mass to the ton scale and well beyond. This should allow a (nearly) definitive test or discovery of dark matter if it is in the form of weakly interacting massive particles.

  18. Apparatus for preparing a solution of a hyperpolarized noble gas for NMR and MRI analysis

    DOE Patents [OSTI]

    Pines, Alexander; Budinger, Thomas; Navon, Gil; Song, Yi-Qiao; Appelt, Stephan; Bifone, Angelo; Taylor, Rebecca; Goodson, Boyd; Seydoux, Roberto; Room, Toomas; Pietrass, Tanja

    2008-06-10

    The present invention relates generally to nuclear magnetic resonance (NMR) techniques for both spectroscopy and imaging. More particularly, the present invention relates to methods in which hyperpolarized noble gases (e.g., Xe and He) are used to enhance and improve NMR and MRI. Additionally, the hyperpolarized gas solutions of the invention are useful both in vitro and in vivo to study the dynamics or structure of a system. When used with biological systems, either in vivo or in vitro, it is within the scope of the invention to target the hyperpolarized gas and deliver it to specific regions within the system.

  19. Enhancement of NMR and MRI in the presence of hyperpolarized noble gases

    DOE Patents [OSTI]

    Pines, Alexander; Budinger, Thomas; Navon, Gil; Song, Yi-Qiao; Appelt, Stephan; Bifone, Angelo; Taylor, Rebecca; Goodson, Boyd; Seydoux, Roberto; Room, Toomas; Pietrass, Tanja

    2004-11-16

    The present invention relates generally to nuclear magnetic resonance (NMR) techniques for both spectroscopy and imaging. More particularly, the present invention relates to methods in which hyperpolarized noble gases (e.g., Xe and He) are used to enhance and improve NMR and MRI. Additionally, the hyperpolarized gas solutions of the invention are useful both in vitro and in vivo to study the dynamics or structure of a system. When used with biological systems, either in vivo or in vitro, it is within the scope of the invention to target the hyperpolarized gas and deliver it to specific regions within the system.

  20. Epsilon Metal Waste Form for Immobilization of Noble Metals from Used Nuclear Fuel

    SciTech Connect (OSTI)

    Crum, Jarrod V.; Strachan, Denis M.; Rohatgi, Aashish; Zumhoff, Mac R.

    2013-10-01

    Epsilon metal (?-metal), an alloy of Mo, Pd, Rh, Ru, and Tc, is being developed as a waste form to treat and immobilize the undissolved solids and dissolved noble metals from aqueous reprocessing of commercial used nuclear fuel. Epsilon metal is an attractive waste form for several reasons: increased durability relative to borosilicate glass, it can be fabricated without additives (100% waste loading), and in addition it also benefits borosilicate glass waste loading by eliminating noble metals from the glass and thus the processing problems related there insolubility in glass. This work focused on the processing aspects of the epsilon metal waste form development. Epsilon metal is comprised of refractory metals resulting in high reaction temperatures to form the alloy, expected to be 1500 - 2000C making it a non-trivial phase to fabricate by traditional methods. Three commercially available advanced technologies were identified: spark-plasma sintering, microwave sintering, and hot isostatic pressing, and investigated as potential methods to fabricate this waste form. Results of these investigations are reported and compared in terms of bulk density, phase assemblage (X-ray diffraction and elemental analysis), and microstructure (scanning electron microscopy).

  1. Electric dipole polarizabilities at imaginary frequencies for hydrogen, the alkali-metal, alkaline-earth, and noble gas atoms

    SciTech Connect (OSTI)

    Derevianko, Andrei Porsev, Sergey G. Babb, James F.

    2010-05-15

    The electric dipole polarizabilities evaluated at imaginary frequencies for hydrogen, the alkali-metal atoms, the alkaline-earth atoms, and the noble gases are tabulated along with the resulting values of the atomic static polarizabilities, the atom-surface interaction constants, and the dispersion (or van der Waals) constants for the homonuclear and the heteronuclear diatomic combinations of the atoms.

  2. Demonstration of neutron detection utilizing open cell foam and noble gas scintillation

    SciTech Connect (OSTI)

    Lavelle, C. M. Miller, E. C.; Coplan, M.; Thompson, Alan K.; Vest, Robert E.; Yue, A. T.; Kowler, A. L.; Koeth, T.; Al-Sheikhly, M.; Clark, Charles W.

    2015-03-02

    We present results demonstrating neutron detection via a closely spaced converter structure coupled to low pressure noble gas scintillation instrumented by a single photo-multiplier tube (PMT). The converter is dispersed throughout the gas volume using a reticulated vitreous carbon foam coated with boron carbide (B{sub 4}C). A calibrated cold neutron beam is used to measure the neutron detection properties, using a thin film of enriched {sup 10}B as a reference standard. Monte Carlo computations of the ion energy deposition are discussed, including treatment of the foam random network. Results from this study indicate that the foam shadows a significant portion of the scintillation light from the PMT. The high scintillation yield of Xe appears to overcome the light loss, facilitating neutron detection and presenting interesting opportunities for neutron detector design.

  3. Modelling of noble anaesthetic gases and high hydrostatic pressure effects in lipid bilayers

    SciTech Connect (OSTI)

    Moskovitz, Yevgeny; Yang, Hui

    2015-01-08

    Our objective was to study molecular processes that might be responsible for inert gas narcosis and high-pressure nervous syndrome. The classical molecular dynamics trajectories (200 ns-long) of dioleoylphosphatidylcholine (DOPC) bilayers simulated by the Berger force field were evaluated for water and the atomic distribution of noble gases around DOPC molecules at a pressure range of 1 - 1000 bar and temperature of 310 Kelvin. Xenon and argon have been tested as model gases for general anesthetics, and neon has been investigated for distortions that are potentially responsible for neurological tremor at hyperbaric conditions. The analysis of stacked radial pair distribution functions of DOPC headgroup atoms revealed the explicit solvation potential of gas molecules, which correlates with their dimensions. The orientational dynamics of water molecules at the biomolecular interface should be considered as an influential factor; while excessive solvation effects appearing in the lumen of membrane-embedded ion channels could be a possible cause of inert gas narcosis. All the noble gases tested exhibit similar patterns of the order parameter for both DOPC acyl chains, which is opposite to the patterns found for the order parameter curve at high hydrostatic pressures in intact bilayers. This finding supports the ‘critical volume’ hypothesis of anesthesia pressure reversal. The irregular lipid headgroup-water boundary observed in DOPC bilayers saturated with neon in the pressure range of 1 - 100 bar could be associated with the possible manifestation of neurological tremor at the atomic scale. The non-immobilizer neon also demonstrated the highest momentum impact on the normal component of the DOPC diffusion coefficient representing monolayers undulations rate, which indicates enhanced diffusivity, rather than atom size, as the key factor.

  4. Modelling of noble anaesthetic gases and high hydrostatic pressure effects in lipid bilayers

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Moskovitz, Yevgeny; Yang, Hui

    2015-01-08

    Our objective was to study molecular processes that might be responsible for inert gas narcosis and high-pressure nervous syndrome. The classical molecular dynamics trajectories (200 ns-long) of dioleoylphosphatidylcholine (DOPC) bilayers simulated by the Berger force field were evaluated for water and the atomic distribution of noble gases around DOPC molecules at a pressure range of 1 - 1000 bar and temperature of 310 Kelvin. Xenon and argon have been tested as model gases for general anesthetics, and neon has been investigated for distortions that are potentially responsible for neurological tremor at hyperbaric conditions. The analysis of stacked radial pair distributionmore » functions of DOPC headgroup atoms revealed the explicit solvation potential of gas molecules, which correlates with their dimensions. The orientational dynamics of water molecules at the biomolecular interface should be considered as an influential factor; while excessive solvation effects appearing in the lumen of membrane-embedded ion channels could be a possible cause of inert gas narcosis. All the noble gases tested exhibit similar patterns of the order parameter for both DOPC acyl chains, which is opposite to the patterns found for the order parameter curve at high hydrostatic pressures in intact bilayers. This finding supports the ‘critical volume’ hypothesis of anesthesia pressure reversal. The irregular lipid headgroup-water boundary observed in DOPC bilayers saturated with neon in the pressure range of 1 - 100 bar could be associated with the possible manifestation of neurological tremor at the atomic scale. The non-immobilizer neon also demonstrated the highest momentum impact on the normal component of the DOPC diffusion coefficient representing monolayers undulations rate, which indicates enhanced diffusivity, rather than atom size, as the key factor.« less

  5. Acid Strength and Bifunctional Catalytic Behavior of Alloys Comprised of Noble Metals and Oxophilic Metal Promoters

    SciTech Connect (OSTI)

    Hibbitts, David D.; Tan, Qiaohua; Neurock, Matthew

    2014-06-01

    The promotion of metal catalysts with partially oxidized oxophilic MOx species, such as ReOx-promoted Rh, has been demonstrated to produce Brnsted acid sites that can promote hydrogenolysis of oxygenate intermediates such as those found in biomass-derived species. A wide variety of alloy compositions and structures are examined in this work to investigate strongly acidic promoters by using DFT-calculated deprotonation energies (DPE) as a measure of acid strength. Sites with the highest acid strength had DPE less than 1100 kJ mol-1, similar to DPE values of heteropolyacids or acid-containing zeolites, and were found on alloys composed of an oxophilic metal (such as Re or W) with a noble metal (such as Rh or Pt). NH3 adsorbs more strongly to sites with increasing acid strength and the activation barriers for acid-catalyzed ring opening of a furan ring decrease with increasing acid strength, which was also shown to be stronger for OH acid sites bound to multiple oxophilic metal atoms in a three-fold configuration rather than OH sites adsorbed in an atop configuration on one oxophilic metal, indicating that small MOx clusters may yield sites with the highest acid strength.

  6. Simulated study of plasmonic coupling in noble bimetallic alloy nanosphere arrays

    SciTech Connect (OSTI)

    Bansal, Amit Verma, S. S.

    2014-05-15

    The plasmonic coupling between the interacting noble metal nanoparticles plays an important role to influence the optical properties of arrays. In this work, we have extended the Mie theory results of our recent communication to include the effect of particle interactions between the alloy nanoparticles by varying interparticle distance and number of particles. The localized surface plasmon resonance (LSPR) peak position, full width at half maxima (FWHM) and scattering efficiency of one dimensional (1D) bimetallic alloy nanosphere (BANS) arrays of earlier optimized compositions i.e. Ag{sub 0.75}Au{sub 0.25}, Au{sub 0.25}Cu{sub 0.75} and Ag{sub 0.50}Cu{sub 0.50} have been studied presently by using discrete dipole approximation (DDA) simulations. Studies have been made to optimize size of the nanosphere, number of spheres in the arrays, material and the interparticle distance. It has been found that both the scattering efficiency and FWHM (bandwidth) can be controlled in the large region of the electromagnetic (EM) spectrum by varying the number of interacting particles and interparticle distance. In comparison to other alloy arrays, Ag{sub 0.50}Cu{sub 0.50} BANS arrays (each of particle radius 50 nm) shows larger tunability of LSPR with wide bandwidth (essential condition for plasmonic solar cells)

  7. Isotopic noble gas signatures released from medical isotope production facilities - Simulations and measurements

    SciTech Connect (OSTI)

    Saey, Paul R.; Bowyer, Ted W.; Ringbom, Anders

    2010-09-09

    Journal article on the role that radioxenon isotopes play in confirming whether or not an underground explosion was nuclear in nature. Radioxenon isotopes play a major role in confirming whether or not an underground explosion was nuclear in nature. It is then of key importance to understand the sources of environmental radioxenon to be able to distinguish civil sources from those of a nuclear explosion. Based on several years of measurements, combined with advanced atmospheric transport model results, it was recently shown that the main source of radioxenon observations are strong and regular batch releases from a very limited number of medical isotope production facilities. This paper reviews production processes in different medical isotope facilities during which radioxenon is produced. Radioxenon activity concentrations and isotopic compositions are calculated for six large facilities. The results are compared with calculated signals from nuclear explosions. Further, the outcome is compared and found to be consistent with radioxenon measurements recently performed in and around three of these facilities. Some anomalies in measurements in which {sup 131m}Xe was detected were found and a possible explanation is proposed. It was also calculated that the dose rate of the releases is well below regulatory values. Based on these results, it should be possible to better understand, interpret and verify signals measured in the noble gas measurement systems in the International Monitoring of the Comprehensive Nuclear-Test-Ban Treaty.

  8. Surface plasmon polariton assisted optical switching in noble bimetallic nanoparticle system

    SciTech Connect (OSTI)

    Dhara, Sandip E-mail: chenkh@pub.iams.sinica.edu.tw; Lu, C.-Y.; Tu, W.-S.; Magudapathy, P.; Huang, Y.-F.; Chen, K.-H. E-mail: chenkh@pub.iams.sinica.edu.tw

    2015-01-12

    Photoresponse of bimetallic Au-Ag nanoparticle embedded soda glass (Au-Ag@SG) substrate is reported for surface plasmon assisted optical switching using 808 nm excitation. Au-Ag@SG system is made by an ion beam technique where Ag{sup +} is introduced first in the soda glass matrix by ion exchange technique. Subsequently, 400 keV Au{sup +} is implanted in the sample for different fluences, which is followed by an ion beam annealing process using 1 MeV Si{sup +} at a fixed fluence of 2 × 10{sup 16} ions·cm{sup −2}. Characteristic surface plasmon resonance (SPR) peaks around 400 and 550 nm provided evidence for the presence of Au and Ag nanoparticles. An optical switching in the Au-Ag@SG system with 808 nm, which is away from the characteristic SPR peaks of Ag and Au nanoparticles, suggests the possible role of two photon absorption (TPA) owing to the presence of interacting electric dipole in these systems. The role of surface plasmon polariton is emphasized for the propagation of electronic carrier belonging to the conduction electron of Au-Ag system in understanding the observed photoresponse. Unique excitation dependent photoresponse measurements confirm the possible role of TPA process. A competitive interband and intraband transitions in the bimetallic system of Au and Ag, which may be primarily responsible for the observation, are validated qualitatively using finite difference time domain calculations where inter-particle separation of Au and Ag plays an important role. Thus, a smart way of optical switching can be envisaged in noble bimetallic nanocluster system where long wavelength with higher skin depth can be used for communication purpose.

  9. Enantioselectivity of (321) chiral noble metal surfaces: A density functional theory study of lactate adsorption

    SciTech Connect (OSTI)

    Franke, J.-H.; Kosov, D. S.

    2013-12-14

    The adsorption of the chiral molecule lactate on the intrinsically chiral noble metal surfaces Pt(321), Au(321), and Ag(321) is studied by density functional theory calculations. We use the oPBE-vdW functional which includes van der Waals forces on an ab initio level. It is shown that the molecule binds via its carboxyl and the hydroxyl oxygen atoms to the surface. The binding energy is larger on Pt(321) and Ag(321) than on Au(321). An analysis of the contributions to the binding energy of the different molecular functional groups reveals that the deprotonated carboxyl group contributes most to the binding energy, with a much smaller contribution of the hydroxyl group. The Pt(321) surface shows considerable enantioselectivity of 0.06 eV. On Au(321) and Ag(321) it is much smaller if not vanishing. The chiral selectivity of the Pt(321) surface can be explained by two factors. First, it derives from the difference in van der Waals attraction of L- and D-lactate to the surface that we trace to differences in the binding energy of the methyl group. Second, the multi-point binding pattern for lactate on the Pt(321) surface is sterically more sensitive to surface chirality and also leads to large binding energy contributions of the hydroxyl group. We also calculate the charge transfer to the molecule and the work function to gauge changes in electronic structure of the adsorbed molecule. The work function is lowered by 0.8 eV on Pt(321) with much smaller changes on Au(321) and Ag(321)

  10. The effect of in-situ noble metal chemical addition on crack growth rate behavior of structural materials in 288 C water

    SciTech Connect (OSTI)

    Andresen, P.L.; Angeliu, T.

    1996-10-01

    Stress corrosion cracking (SCC), especially in existing boiling water reactor (BVM) components, is most effectively accomplished by reducing the corrosion potential. This was successfully demonstrated by adding hydrogen to BNM water, which reduced oxidant concentration and corrosion potential by recombining with the radiolytically formed oxygen and hydrogen peroxide. However, reduction in the corrosion potential for some vessel internals is difficult, and others require high hydrogen addition rates, which results in an increase in the main steam radiation level from volatile N{sup 16}. Noble metal electrocatalysis provides a unique opportunity to efficiently achieve a dramatic reduction in corrosion potential and SCC in BWRs, by catalytically reacting all oxidants that diffuse to a (catalytic) metal surface with hydrogen. There are many techniques for creating catalytic surfaces, including alloying with noble metals or applying noble metal alloy powders to existing BWR components by thermal spraying or weld cladding. A novel system-wide approach for producing catalytic surfaces on all wetted components has been developed which employs the reactor coolant water as the medium of transport. This approach is termed in-situ noble metal chemical addition (NMCA), and has been successfully used in extensive laboratory tests to coat a wide range of pre-oxidized structural materials. In turn, these specimens have maintained catalytic response in long term, cyclic exposures to extremes in dissolved gases, impurity levels, pH, flow rate, temperature, straining, etc. With stoichiometric excess H{sub 2}, the corrosion potential drops dramatically and crack initiation and growth are greatly reduced, even at high O{sub 2} or H{sub 2}O{sub 2} levels. Without excess H{sub 2} (i.e., in normal BWR water chemistry), noble metals do not increase the corrosion potential or SCC.

  11. Environmental assessment and finding of no significant impact: Biorecycling Technologies, Inc., Noble Biogas and Fertilizer Plant, Fresno County, California

    SciTech Connect (OSTI)

    1997-09-01

    The US Department of Energy (DOE) is considering a proposal from the California Energy Commission for partial funding up to $1,500,000 of the construction of the biorecycling Technologies, Inc., (BTI) Noble Biogas and Fertilizer Plant in Fresno County, California. BTI along with its contractors and business partners would develop the plant, which would use manure and green waste to produce biogas and a variety of organic fertilizer products. The California Energy Commission has requested funding from the DOE Commercialization Ventures program to assist in the construction of the plant, which would produce up to one megawatt of electricity by burning biogas in a cogeneration unit. The purpose of this environmental assessment (EA) is to provide DOE and the public with information on potential environmental impacts associated with funding development of the proposed project.

  12. Ultrabright multikilovolt x-ray source: saturated amplification on noble gas transition arrays from hollow atom states

    DOE Patents [OSTI]

    Rhodes, Charles K.; Boyer, Keith

    2004-02-17

    An apparatus and method for the generation of ultrabright multikilovolt x-rays from saturated amplification on noble gas transition arrays from hollow atom states is described. Conditions for x-ray amplification in this spectral region combine the production of cold, high-Z matter, with the direct, selective multiphoton excitation of hollow atoms from clusters using ultraviolet radiation and a nonlinear mode of confined, self-channeled propagation in plasmas. Data obtained is consistent with the presence of saturated amplification on several transition arrays of the hollow atom Xe(L) spectrum (.lambda..about.2.9 .ANG.). An estimate of the peak brightness achieved is .about.10.sup.29 .gamma..multidot.s.sup.-1.multidot.mm.sup.-2.multidot.mr.sup.-2 (0.1% Bandwidth).sup.-1, that is .about.10.sup.5 -fold higher than presently available synchotron technology.

  13. Noble gas component organization in Apollo 14 breccia 14318: /sup 129/I and /sup 244/Pu regolith chronology

    SciTech Connect (OSTI)

    Swindle, T.D.; Caffee, M.W.; Hohenberg, C.M.; Hudson, G.B.; Laul, J.C.; Simon, S.B.; Papike, J.J.

    1985-02-15

    Noble gas, petrological, and chemical studies made on grain-size separates from lunar regolith breccia 14318 demonstrate that the noble gases are organized into two functional components, volume-correlated and surface-correlated. As in regolith breccia 14301, volume-correlated xenon in 14318 is primarily spallation-derived and the surface-correlated component contains not only solar wind xenon but also significant amounts of ''parentless' xenon from the fission of now extinct /sup 244/Pu and the decay of now extinct /sup 129/I (''parentless'' means the daughter products were incorporated onto grain surfaces following decay of the parent nuclide elsewhere). The ratio of /sup 129/Xe//sup 136/Xe in the total surface-correlated parentless component, as identified in grain-size analysis, is substantially higher than in the least tightly bound parentless component identified in stepwise heating analyses, confirming the trend seen in 14301. If the order of release of gases in stepwise heating is related to the order of incorporation in the simplest way (first in, last out), incorporation of these grain-surface components was probably time-ordered. The /sup 129/Xe//sup 136/Xe ratio in each identifiable parentless component would then be characteristic of the xenon available for surface adsorption at the particular time of acquisition. Continuous variations in this ratio further suggest that incorporation of the parentless xenon was closely coupled with production. Such observations provide the basis for a new chronometer from which we conclude that acquisition of parentless xenon was an ongoing process spanning at least 90 m.y., beginning no more than 44 +- 34 m.y. after the formation of the most meteorites and possibly predating xenon acquisition for the earth.

  14. USCA Convocation Center 375 Robert Bell Parkway, Aiken, SC 29801

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Workforce of Tomorrow | Department of Energy USA Science and Engineering Festival: Inspiring and Educating the Clean Energy Workforce of Tomorrow USA Science and Engineering Festival: Inspiring and Educating the Clean Energy Workforce of Tomorrow April 23, 2014 - 9:52am Addthis The Energy Department has several free resources that help educators teach students about clean energy including (clockwise, from top left) the <a

  15. A density functional theory study of magneto-electric Jones birefringence of noble gases, furan homologues, and mono-substituted benzenes

    SciTech Connect (OSTI)

    Fahleson, Tobias; Norman, Patrick; Coriani, Sonia; Rizzo, Antonio; Rikken, Geert L. J. A.

    2013-11-21

    We report on the results of a systematic ab initio study of the Jones birefringence of noble gases, of furan homologues, and of monosubstituted benzenes, in the gas phase, with the aim of analyzing the behavior and the trends within a list of systems of varying size and complexity, and of identifying candidates for a combined experimental/theoretical study of the effect. We resort here to analytic linear and nonlinear response functions in the framework of time-dependent density functional theory. A correlation is made between the observable (the Jones constant) and the atomic radius for noble gases, or the permanent electric dipole and a structure/chemical reactivity descriptor as the para Hammett constant for substituted benzenes.

  16. Conceptual Engineering Method for Attenuating He Ion Interactions on First Wall Components in the Fusion Test Facility (FTF) Employing a Low-Pressure Noble Gas

    SciTech Connect (OSTI)

    C.A.Gentile, W.R.Blanchard, T.Kozub, C.Priniski, I.Zatz, S.Obenschain

    2009-09-21

    It has been shown that post detonation energetic helium ions can drastically reduce the useful life of the (dry) first wall of an IFE reactor due to the accumulation of implanted helium. For the purpose of attenuating energetic helium ions from interacting with first wall components in the Fusion Test Facility (FTF) target chamber, several concepts have been advanced. These include magnetic intervention (MI), deployment of a dynamically moving first wall, use of a sacrificial shroud, designing the target chamber large enough to mitigate the damage caused by He ions on the target chamber wall, and the use of a low pressure noble gas resident in the target chamber during pulse power operations. It is proposed that employing a low-pressure (~ 1 torr equivalent) noble gas in the target chamber will thermalize energetic helium ions prior to interaction with the wall. The principle benefit of this concept is the simplicity of the design and the utilization of (modified) existing technologies for pumping and processing the noble ambient gas. Although the gas load in the system would be increased over other proposed methods, the use of a "gas shield" may provide a cost effective method of greatly extending the first wall of the target chamber. An engineering study has been initiated to investigate conceptual engineering metmethods for implementing a viable gas shield strategy in the FTF.

  17. Striving toward noble-metal-free photocatalytic water splitting: The hydrogenated-graphene-TiO2 prototype

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Nguyen-Phan, Thuy -Duong; Luo, Si; Liu, Zongyuan; Gamalski, Andrew D.; Tao, Jing; Xu, Wenqian; Stach, Eric A.; Polyansky, Dmitry E.; Senanayake, Sanjaya D.; Fujita, Etsuko; et al

    2015-08-20

    Graphane, graphone and hydrogenated graphene (HG) have been extensively studied in recent years due to their interesting properties and potential use in commercial and industrial applications. The present study reports investigation of hydrogenated graphene/TiO2-x (HGT) nanocomposites as photocatalysts for H2 and O2 production from water without the assistance of a noble metal co-catalyst. By combination of several techniques, the morphologies, bulk/atomic structure and electronic properties of all the powders were exhaustively interrogated. Hydrogenation treatment efficiently reduces TiO2 nanoparticles, while the graphene oxide sheets undergo the topotactic transformation from a graphene-like structure to a mixture of graphitic and turbostratic carbon (amorphous/disordered)more » upon altering the calcination atmosphere from a mildly reducing to a H2-abundant environment. Remarkably, the hydrogenated graphene-TiO2-x composite that results upon H2-rich reduction exhibits the highest photocatalytic H2 evolution performance equivalent to low loading of Pt (~0.12 wt%), whereas the addition of HG suppresses the O2 production. As a result, we propose that such an enhancement can be attributed to a combination of factors including the introduction of oxygen vacancies and Ti3+ states, retarding the recombination of charge carriers and thus, facilitating the charge transfer from TiO2-x to the carbonaceous sheet.« less

  18. A Concept for a Low Pressure Noble Gas Fill Intervention in the IFE Fusion Test Facility (FTF) Target Chamber

    SciTech Connect (OSTI)

    Gentile, C. A.; Blanchard, W. R.; Kozub, T. A.; Aristova, M.; McGahan, C.; Natta, S.; Pagdon, K.; Zelenty, J.

    2010-01-14

    An engineering evaluation has been initiated to investigate conceptual engineering methods for implementing a viable gas shield strategy in the Fusion Test Facility (FTF) target chamber. The employment of a low pressure noble gas in the target chamber to thermalize energetic helium ions prior to interaction with the wall could dramatically increase the useful life of the first wall in the FTF reactor1. For the purpose of providing flexibility, two target chamber configurations are addressed: a five meter radius sphere and a ten meter radius sphere. Experimental studies at Nike have indicated that a low pressure, ambient gas resident in the target chamber during laser pulsing does not appear to impair the ability of laser light from illuminating targets2. In addition, current investigations into delivering, maintaining, and processing low pressure gas appear to be viable with slight modification to current pumping and plasma exhaust processing technologies3,4. Employment of a gas fill solution for protecting the dry wall target chamber in the FTF may reduce, or possibly eliminate the need for other attenuating technologies designed for keeping He ions from implanting in first wall structures and components. The gas fill concept appears to provide an effective means of extending the life of the first wall while employing mostly commercial off the shelf (COTS) technologies. Although a gas fill configuration may provide a methodology for attenuating damage inflicted on chamber surfaces, issues associated with target injection need to be further analyzed to ensure that the gas fill concept is viable in the integrated FTF design5. In the proposed system, the ambient noble gas is heated via the energetic helium ions produced by target detonation. The gas is subsequently cooled by the chamber wall to approximately 800oC, removed from the chamber, and processed by the chamber gas processing system (CGPS). In an optimized scenario of the above stated concept, the chamber

  19. Striving toward noble-metal-free photocatalytic water splitting: The hydrogenated-graphene-TiO2 prototype

    SciTech Connect (OSTI)

    Nguyen-Phan, Thuy -Duong; Luo, Si; Liu, Zongyuan; Gamalski, Andrew D.; Tao, Jing; Xu, Wenqian; Stach, Eric A.; Polyansky, Dmitry E.; Senanayake, Sanjaya D.; Fujita, Etsuko; Rodriguez, Jose A.

    2015-08-20

    Graphane, graphone and hydrogenated graphene (HG) have been extensively studied in recent years due to their interesting properties and potential use in commercial and industrial applications. The present study reports investigation of hydrogenated graphene/TiO2-x (HGT) nanocomposites as photocatalysts for H2 and O2 production from water without the assistance of a noble metal co-catalyst. By combination of several techniques, the morphologies, bulk/atomic structure and electronic properties of all the powders were exhaustively interrogated. Hydrogenation treatment efficiently reduces TiO2 nanoparticles, while the graphene oxide sheets undergo the topotactic transformation from a graphene-like structure to a mixture of graphitic and turbostratic carbon (amorphous/disordered) upon altering the calcination atmosphere from a mildly reducing to a H2-abundant environment. Remarkably, the hydrogenated graphene-TiO2-x composite that results upon H2-rich reduction exhibits the highest photocatalytic H2 evolution performance equivalent to low loading of Pt (~0.12 wt%), whereas the addition of HG suppresses the O2 production. As a result, we propose that such an enhancement can be attributed to a combination of factors including the introduction of oxygen vacancies and Ti3+ states, retarding the recombination of charge carriers and thus, facilitating the charge transfer from TiO2-x to the carbonaceous sheet.

  20. Molecular dynamics simulation of framework flexibility effects on noble gas diffusion in HKUST-1 and ZIF-8

    SciTech Connect (OSTI)

    Parkes, Marie V.; Demir, Hakan; Teich-McGoldrick, Stephanie L.; Sholl, David S.; Greathouse, Jeffery A.; Allendorf, Mark D.

    2014-03-28

    Molecular dynamics simulations were used to investigate trends in noble gas (Ar, Kr, Xe) diffusion in the metal-organic frameworks HKUST-1 and ZIF-8. Diffusion occurs primarily through inter-cage jump events, with much greater diffusion of guest atoms in HKUST-1 compared to ZIF-8 due to the larger cage and window sizes in the former. We compare diffusion coefficients calculated for both rigid and flexible frameworks. For rigid framework simulations, in which the framework atoms were held at their crystallographic or geometry optimized coordinates, sometimes dramatic differences in guest diffusion were seen depending on the initial framework structure or the choice of framework force field parameters. When framework flexibility effects were included, argon and krypton diffusion increased significantly compared to rigid-framework simulations using general force field parameters. Additionally, for argon and krypton in ZIF-8, guest diffusion increased with loading, demonstrating that guest-guest interactions between cages enhance inter-cage diffusion. No inter-cage jump events were seen for xenon atoms in ZIF-8 regardless of force field or initial structure, and the loading dependence of xenon diffusion in HKUST-1 is different for rigid and flexible frameworks. Diffusion of krypton and xenon in HKUST-1 depends on two competing effects: the steric effect that decreases diffusion as loading increases, and the “small cage effect” that increases diffusion as loading increases. Finally, a detailed analysis of the window size in ZIF-8 reveals that the window increases beyond its normal size to permit passage of a (nominally) larger krypton atom.

  1. Molecular dynamics simulation of framework flexibility effects on noble gas diffusion in HKUST-1 and ZIF-8

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Parkes, Marie V.; Demir, Hakan; Teich-McGoldrick, Stephanie L.; Sholl, David S.; Greathouse, Jeffery A.; Allendorf, Mark D.

    2014-03-28

    Molecular dynamics simulations were used to investigate trends in noble gas (Ar, Kr, Xe) diffusion in the metal-organic frameworks HKUST-1 and ZIF-8. Diffusion occurs primarily through inter-cage jump events, with much greater diffusion of guest atoms in HKUST-1 compared to ZIF-8 due to the larger cage and window sizes in the former. We compare diffusion coefficients calculated for both rigid and flexible frameworks. For rigid framework simulations, in which the framework atoms were held at their crystallographic or geometry optimized coordinates, sometimes dramatic differences in guest diffusion were seen depending on the initial framework structure or the choice of frameworkmore » force field parameters. When framework flexibility effects were included, argon and krypton diffusion increased significantly compared to rigid-framework simulations using general force field parameters. Additionally, for argon and krypton in ZIF-8, guest diffusion increased with loading, demonstrating that guest-guest interactions between cages enhance inter-cage diffusion. No inter-cage jump events were seen for xenon atoms in ZIF-8 regardless of force field or initial structure, and the loading dependence of xenon diffusion in HKUST-1 is different for rigid and flexible frameworks. Diffusion of krypton and xenon in HKUST-1 depends on two competing effects: the steric effect that decreases diffusion as loading increases, and the “small cage effect” that increases diffusion as loading increases. Finally, a detailed analysis of the window size in ZIF-8 reveals that the window increases beyond its normal size to permit passage of a (nominally) larger krypton atom.« less

  2. The solvation radius of silicate melts based on the solubility of noble gases and scaled particle theory

    SciTech Connect (OSTI)

    Ottonello, Giulio; Richet, Pascal

    2014-01-28

    The existing solubility data on noble gases in high-temperature silicate melts have been analyzed in terms of Scaling Particle Theory coupled with an ab initio assessment of the electronic, dispersive, and repulsive energy terms based on the Polarized Continuum Model (PCM). After a preliminary analysis of the role of the contracted Gaussian basis sets and theory level in reproducing appropriate static dipole polarizabilities in a vacuum, we have shown that the procedure returns Henry's law constants consistent with the values experimentally observed in water and benzene at T = 25?C and P = 1 bar for the first four elements of the series. The static dielectric constant (?) of the investigated silicate melts and its optical counterpart (?{sup ?}) were then resolved through the application of a modified form of the Clausius-Mossotti relation. Argon has been adopted as a probe to depict its high-T solubility in melts through an appropriate choice of the solvent diameter ?{sub s}, along the guidelines already used in the past for simple media such as water or benzene. The ?{sub s} obtained was consistent with a simple functional form based on the molecular volume of the solvent. The solubility calculations were then extended to He, Ne, and Kr, whose dispersive and repulsive coefficients are available from theory and we have shown that their ab initio Henry's constants at high T reproduce the observed increase with the static polarizability of the series element with reasonable accuracy. At room temperature (T = 25?C) the calculated Henry's constants of He, Ne, Ar, and Kr in the various silicate media predict higher solubilities than simple extrapolations (i.e., Arrhenius plots) based on high-T experiments and give rise to smooth trends not appreciably affected by the static polarizabilities of the solutes. The present investigation opens new perspectives on a wider application of PCM theory which can be extended to materials of great industrial interest at the core of

  3. Intriguing structures and magic sizes of heavy noble metal nanoclusters around size 55 governed by relativistic effect and covalent bonding

    SciTech Connect (OSTI)

    Zhao, X. J.; Xue, X. L.; Jia, Yu; Guo, Z. X.; Li, S. F.; Zhang, Zhenyu; Gao, Y. F.

    2015-11-07

    Nanoclusters usually display exotic physical and chemical properties due to their intriguing geometric structures in contrast to their bulk counterparts. By means of first-principles calculations within density functional theory, we find that heavy noble metal Pt{sub N} nanoclusters around the size N = 55 begin to prefer an open configuration, rather than previously reported close-packed icosahedron or core-shell structures. Particularly, for Pt{sub N}, the widely supposed icosahedronal magic cluster is changed to a three-atomic-layered structure with D{sub 6h} symmetry, which can be well addressed by our recently established generalized Wulff construction principle (GWCP). However, the magic number of Pt{sub N} clusters around 55 is shifted to a new odd number of 57. The high symmetric three-layered Pt{sub 57} motif is mainly stabilized by the enhanced covalent bonding contributed by both spin-orbital coupling effect and the open d orbital (5d{sup 9}6s{sup 1}) of Pt, which result in a delicate balance between the enhanced Pt–Pt covalent bonding of the interlayers and negligible d dangling bonds on the cluster edges. These findings about Pt{sub N} clusters are also applicable to Ir{sub N} clusters, but qualitatively different from their earlier neighboring element Os and their later neighboring element Au. The magic numbers for Os and Au are even, being 56 and 58, respectively. The findings of the new odd magic number 57 are the important supplementary of the recently established GWCP.

  4. Redox buffered hydrofluoric acid etchant for the reduction of galvanic attack during release etching of MEMS devices having noble material films

    SciTech Connect (OSTI)

    Hankins, Matthew G.

    2009-10-06

    Etchant solutions comprising a redox buffer can be used during the release etch step to reduce damage to the structural layers of a MEMS device that has noble material films. A preferred redox buffer comprises a soluble thiophosphoric acid, ester, or salt that maintains the electrochemical potential of the etchant solution at a level that prevents oxidation of the structural material. Therefore, the redox buffer preferentially oxidizes in place of the structural material. The sacrificial redox buffer thereby protects the exposed structural layers while permitting the dissolution of sacrificial oxide layers during the release etch.

  5. Transferability and accuracy by combining dispersionless density functional and incremental post-Hartree-Fock theories: Noble gases adsorption on coronene/graphene/graphite surfaces

    SciTech Connect (OSTI)

    Lara-Castells, María Pilar de Bartolomei, Massimiliano; Mitrushchenkov, Alexander O.; Stoll, Hermann

    2015-11-21

    The accuracy and transferability of the electronic structure approach combining dispersionless density functional theory (DFT) [K. Pernal et al., Phys. Rev. Lett. 103, 263201 (2009)] with the method of increments [H. Stoll, J. Chem. Phys. 97, 8449 (1992)], are validated for the interaction between the noble-gas Ne, Ar, Kr, and Xe atoms and coronene/graphene/graphite surfaces. This approach uses the method of increments for surface cluster models to extract intermonomer dispersion-like (2- and 3-body) correlation terms at coupled cluster singles and doubles and perturbative triples level, while periodic dispersionless density functionals calculations are performed to estimate the sum of Hartree-Fock and intramonomer correlation contributions. Dispersion energy contributions are also obtained using DFT-based symmetry-adapted perturbation theory [SAPT(DFT)]. An analysis of the structure of the X/surface (X = Ne, Ar, Kr, and Xe) interaction energies shows the excellent transferability properties of the leading intermonomer correlation contributions across the sequence of noble-gas atoms, which are also discussed using the Drude oscillator model. We further compare these results with van der Waals-(vdW)-corrected DFT-based approaches. As a test of accuracy, the energies of the low-lying nuclear bound states supported by the laterally averaged X/graphite potentials (X = {sup 3}He, {sup 4}He, Ne, Ar, Kr, and Xe) are calculated and compared with the best estimations from experimental measurements and an atom-bond potential model using the ab initio-assisted fine-tuning of semiempirical parameters. The bound-state energies determined differ by less than 6–7 meV (6%) from the atom-bond potential model. The crucial importance of including incremental 3-body dispersion-type terms is clearly demonstrated, showing that the SAPT(DFT) approach effectively account for these terms. With the deviations from the best experimental-based estimations smaller than 2.3 meV (1.9%), the

  6. IMPACT OF NOBLE METALS AND MERCURY ON HYDROGEN GENERATION DURING HIGH LEVEL WASTE PRETREATMENT AT THE SAVANNAH RIVER SITE

    SciTech Connect (OSTI)

    Stone, M; Tommy Edwards, T; David Koopman, D

    2009-03-03

    simulant was used for all tests and was spiked with the required amount of noble metals immediately prior to performing the test. Acid addition was kept effectively constant except to compensate for variations in the starting mercury concentration. SME cycles were also performed during six of the tests.

  7. Catching the role of anisotropic electronic distribution and charge transfer in halogen bonded complexes of noble gases

    SciTech Connect (OSTI)

    Bartocci, Alessio; Cappelletti, David; Pirani, Fernando; Belpassi, Leonardo; Falcinelli, Stefano; Grandinetti, Felice; Tarantelli, Francesco

    2015-05-14

    The systems studied in this work are gas-phase weakly bound adducts of the noble-gas (Ng) atoms with CCl{sub 4} and CF{sub 4}. Their investigation was motivated by the widespread current interest for the intermolecular halogen bonding (XB), a structural motif recognized to play a role in fields ranging from elementary processes to biochemistry. The simulation of the static and dynamic behaviors of complex systems featuring XB requires the formulation of reliable and accurate model potentials, whose development relies on the detailed characterization of strength and nature of the interactions occurring in simple exemplary halogenated systems. We thus selected the prototypical Ng-CCl{sub 4} and Ng-CF{sub 4} and performed high-resolution molecular beam scattering experiments to measure the absolute scale of their intermolecular potentials, with high sensitivity. In general, we expected to probe typical van der Waals interactions, consisting of a combination of size (exchange) repulsion with dispersion/induction attraction. For the He/Ne-CF{sub 4}, the analysis of the glory quantum interference pattern, observable in the velocity dependence of the integral cross section, confirmed indeed this expectation. On the other hand, for the He/Ne/Ar-CCl{sub 4}, the scattering data unravelled much deeper potential wells, particularly for certain configurations of the interacting partners. The experimental data can be properly reproduced only including a shifting of the repulsive wall at shorter distances, accompanied by an increased role of the dispersion attraction, and an additional short-range stabilization component. To put these findings on a firmer ground, we performed, for selected geometries of the interacting complexes, accurate theoretical calculations aimed to evaluate the intermolecular interaction and the effects of the complex formation on the electron charge density of the constituting moieties. It was thus ascertained that the adjustments of the potential

  8. PARAMETRIC EFFECTS OF ANTI-FOAM COMPOSITION, SIMULANT PROPERTIES AND NOBLE METALS ON THE GAS HOLDUP AND RELEASE OF A NON-NEWTONIAN WASTE SLURRY SIMULANT

    SciTech Connect (OSTI)

    Guerrero, H; Charles Crawford, C; Mark Fowley, M

    2008-08-07

    Gas holdup tests were performed in bench-scale and small-scale mechanically-agitated mixing systems at the Savannah River National Laboratory (SRNL) for a simulant of waste from the Hanford Tank 241-AZ-101. These featured additions of DOW Corning Q2-3183A anti-foam agent. Results indicated that this anti-foam agent (AFA) increased gas holdup in the waste simulant by about a factor of four and, counter-intuitively, that the holdup increased as the non-newtonian simulant shear strength decreased (apparent viscosity decreased). Such results raised the potential of increased flammable gas retention in Hanford Waste Treatment and Immobilization Plant (WTP) vessels mixed by air sparging and pulse-jet mixers (PJMs) during a Design Basis Event (DBE). Additional testing was performed to determine the effects of simulant properties, composition of alternate AFAs, and presence of trace noble metals. Key results are that: (1) Increased gas holdup resulting from addition of Q2-3183A is due to a decrease in surface tension that supports small bubbles which have low rise velocities. (2) Dow Corning 1520-US AFA shows it to be a viable replacement to Dow Corning Q2-3183A AFA. This alternative AFA, however, requires significantly higher dosage for the same anti-foam function. (3) Addition of noble metals to the AZ-101 waste simulant does not produce a catalytic gas retention effect with the AFA.

  9. In Situ Studies of Surface Mobility on Noble Metal Model Catalysts Using STM and XPS at Ambient Pressure

    SciTech Connect (OSTI)

    Butcher, Derek Robert

    2010-06-14

    High Pressure Scanning Tunneling Microscopy (HP-STM) and Ambient Pressure X-ray Photoelectron Spectroscopy were used to study the structural properties and catalytic behavior of noble metal surfaces at high pressure. HP-STM was used to study the structural rearrangement of the top most atomic surface layer of the metal surfaces in response to changes in gas pressure and reactive conditions. AP-XPS was applied to single crystal and nanoparticle systems to monitor changes in the chemical composition of the surface layer in response to changing gas conditions. STM studies on the Pt(100) crystal face showed the lifting of the Pt(100)-hex surface reconstruction in the presence of CO, H2, and Benzene. The gas adsorption and subsequent charge transfer relieves the surface strain caused by the low coordination number of the (100) surface atoms allowing the formation of a (1 x 1) surface structure commensurate with the bulk terminated crystal structure. The surface phase change causes a transformation of the surface layer from hexagonal packing geometry to a four-fold symmetric surface which is rich in atomic defects. Lifting the hex reconstruction at room temperature resulted in a surface structure decorated with 2-3 nm Pt adatom islands with a high density of step edge sites. Annealing the surface at a modest temperature (150 C) in the presence of a high pressure of CO or H{sub 2} increased the surface diffusion of the Pt atoms causing the adatom islands to aggregate reducing the surface concentration of low coordination defect sites. Ethylene hydrogenation was studied on the Pt(100) surface using HP-STM. At low pressure, the lifting of the hex reconstruction was observed in the STM images. Increasing the ethylene pressure to 1 Torr, was found to regenerate the hexagonally symmetric reconstructed phase. At room temperature ethylene undergoes a structural rearrangement to form ethylidyne. Ethylidyne preferentially binds at the three-fold hollow sites, which are present on

  10. Comparative Study on the Sulfur Tolerance and Carbon Resistance of Supported Noble Metal Catalysts in Steam Reforming of Liquid Hydrocarbon Fuel

    SciTech Connect (OSTI)

    Xie, Chao; Chen, Yongsheng; Engelhard, Mark H.; Song, Chunshan

    2012-04-18

    This work was conducted to clarify the influence of the type of metal and support on the sulfur tolerance and carbon resistance of supported noble metal catalysts in steam reforming of liquid hydrocarbons. Al2O3-supported noble metal catalysts (Rh, Ru, Pt, and Pd), Rh catalysts on different supports (Al2O3, CeO2, SiO2, and MgO), and Pt catalyst supported on CeO2 and Al2O3, were examined for steam reforming of a liquid hydrocarbon fuel (Norpar13 from Exxon Mobil) at 800 C for 55 h. The results indicate that (1) Rh/Al2O3 shows higher sulfur tolerance than the Ru, Pt, and Pd catalysts on the same support; (2) both Al2O3 and CeO2 are promising supports for Rh catalyst to process sulfur-containing hydrocarbons; and (3) Pt/CeO2 exhibits better catalytic performance than Pt/Al2O3 in the reaction with sulfur. TEM results demonstrate that the metal particles in Rh/Al2O3 were better dispersed (mostly in 1-3 nm) compared with the other catalysts after reforming the sulfur-containing feed. As revealed by XPS, the binding energy of Rh 3d for Rh/Al2O3 is notably higher than that for Rh/CeO2, implying the formation of electron-deficient Rh particles in the former. The strong sulfur tolerance of Rh/Al2O3 may be related to the formation of well-dispersed electron-deficient Rh particles on the Al2O3 support. Sulfur K-edge XANES illustrates the preferential formation of sulfonate and sulfate on Rh/Al2O3, which is believed to be beneficial for improving its sulfur tolerance as their oxygen-shielded sulfur structure may hinder direct Rh-S interaction. Due to its strong sulfur tolerance, the carbon deposition on Rh/Al2O3 was significantly lower than that on the Al2O3-supported Ru, Pt, and Pd catalysts after the reaction with sulfur. The superior catalytic performance of CeO2-supported Rh and Pt catalysts in the presence of sulfur can be ascribed mainly to the promotion effect of CeO2 on carbon gasification, leading to much lower carbon deposition compared with the Rh/Al2O3, Rh/MgO, Rh

  11. A reduced mechanism for methane and one-step rate expressions for fuel-lean catalytic combustion of small alkanes on noble metals

    SciTech Connect (OSTI)

    Deshmukh, S.R.; Vlachos, D.G.

    2007-06-15

    A reduced mechanism and a one-step rate expression for fuel-lean methane/air catalytic combustion on an Rh catalyst are proposed. These are developed from a detailed microkinetic model using a computer-aided model reduction strategy that employs reaction path analysis, sensitivity analysis, partial equilibrium analysis, and simple algebra to deduce the most abundant reaction intermediate and the rate-determining step. The mechanism and the one-step rate expression are then tested on Pt catalyst. It is found that the reaction proceeds effectively via the same mechanistic pathway on both noble metals, but the effective reaction orders differ due to the difference in the adsorption strength of oxygen. Based on the homologous series idea, the rate expression is extended to small alkanes (ethane and propane; butane is also briefly discussed) and is found to reasonably describe experimental data. Estimation of the relevant parameters in the rate expression for various fuels and catalysts using the semiempirical bond-order conservation theory, quantum mechanical density functional theory, and/or simple experiments is discussed. Finally, it is proposed that detailed microkinetic models with coverage-dependent parameters can assist in rationalizing the apparent discrepancies between experimental data from various research groups. (author)

  12. Sintering and ripening resistant noble metal nanostructures

    DOE Patents [OSTI]

    van Swol, Frank B; Song, Yujiang; Shelnutt, John A; Miller, James E; Challa, Sivakumar R

    2013-09-24

    Durable porous metal nanostructures comprising thin metal nanosheets that are metastable under some conditions that commonly produce rapid reduction in surface area due to sintering and/or Ostwald ripening. The invention further comprises the method for making such durable porous metal nanostructures. Durable, high-surface area nanostructures result from the formation of persistent durable holes or pores in metal nanosheets formed from dendritic nanosheets.

  13. Nobles Cooperative Electric | Open Energy Information

    Open Energy Info (EERE)

    Electric Place: Minnesota Phone Number: 507-372-7331 Website: www.noblesce.coop Facebook: https:www.facebook.comnoblescooperativeelectric Outage Hotline: 507-372-7331...

  14. Platinum-Coated Non-Noble Metal-Noble Metal Core-Shell Electrocatalyst...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of platinum. The nanoparticles have a core-shell structure and include palladium, gold, and their alloys with other transition metals. The platinum-coated composite can be...

  15. Limestone County, Alabama: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Ardmore, Alabama Athens, Alabama Decatur, Alabama Elkmont, Alabama Huntsville, Alabama Lester, Alabama Madison, Alabama Mooresville, Alabama Retrieved from "http:en.openei.orgw...

  16. Atomic-Layer Deposition on Noble Metal Powders. (Conference)...

    Office of Scientific and Technical Information (OSTI)

    Authors: Robinson, David ; Cappillino, Patrick. ; Salloum, Maher N. ; Sugar, Joshua Daniel ; El Gabaly Marquez, Farid ; Sheridan, Leah B. ; Jagannathan, Kaushik ; Benson, David M. ...

  17. An electroless approach to atomic layer deposition on noble metal...

    Office of Scientific and Technical Information (OSTI)

    Abstract not provided. Authors: Cappillino, Patrick ; Robinson, David ; Sugar, Joshua Daniel ; El Gabaly Marquez, Farid ; Cai, Trevor ; Liu, Zhi ; Stickney, John Publication Date: ...

  18. Atomic-Layer Deposition on Noble Metal Powders

    Office of Scientific and Technical Information (OSTI)

    J. Cappillino, M. Salloum, J. D. Sugar, F. El Gabaly (Sandia) L. Sheridan, K. ... Georgia Maher Salloum Theorymodeling Farid El Gabaly XPS Leah Sheridan E-ALD films Now at ...

  19. Method for the purification of noble gases, nitrogen and hydrogen

    DOE Patents [OSTI]

    Baker, John D.; Meikrantz, David H.; Tuggle, Dale G.

    1997-01-01

    A method and apparatus for the purification and collection of hydrogen isotopes in a flowing inert gaseous mixture containing impurities, wherein metal alloy getters having the capability of sorbing non-hydrogen impurities such as oxygen, carbon dioxide, carbon monoxide, methane, ammonia, nitrogen and water vapor are utilized to purify the gaseous mixture of impurities. After purification hydrogen isotopes may be more efficiently collected. A plurality of parallel process lines utilizing metal getter alloys can be used to provide for the continuous purification and collection of the hydrogen isotopes.

  20. Noble Americas Energy Solutions LLC (Michigan) | Open Energy...

    Open Energy Info (EERE)

    1 888-896-8640 or 1 877-273-6772 or (248) 351-2660 Website: noblesolutions.comindex.html Outage Hotline: 1 888-896-8640 or Local Utility References: EIA Form EIA-861 Final Data...

  1. Thermodynamic aspects of dehydrogenation reactions on noble metal surfaces

    SciTech Connect (OSTI)

    Svane, K. L. Hammer, B.

    2014-11-07

    The reaction free energy for dehydrogenation of phenol, aniline, thiophenol, benzoic acid, and 1,4-benzenediol on the close packed copper, silver, and gold surfaces has been studied by density functional theory calculations. Dehydrogenation of thiophenol is found to be favourable on all three surfaces while aniline does not dehydrogenate on any of them. For phenol, benzenediol and benzoic acid dehydrogenation is favourable on copper and silver only, following the general trend of an increasing reaction free energy when going form gold to silver to copper. This trend can be correlated with the changes in bond lengths within the molecule upon dehydrogenation. While copper is able to replace hydrogen, leaving small changes in the bond lengths of the aromatic ring, the metal-molecule bond is weaker for silver and gold, resulting in a partial loss of aromaticity. This difference in bond strength leads to pronounced differences in adsorption geometries upon multiple dehydrogenations.

  2. EA-364-A Noble Americas CN.pdf

    Office of Environmental Management (EM)

  3. SOLID STATE CONTAINMENT OF NOBLE GASES IN SPUTTER DEPOSITED METALS...

    Office of Scientific and Technical Information (OSTI)

    MLA APA Chicago Bibtex Export Metadata Endnote Excel CSV XML Save to My Library Send to Email Send to Email Email address: Content: Close Send Cite: MLA Format Close Cite: ...

  4. Tuning of noble metal work function with organophosphonate nanolayers

    SciTech Connect (OSTI)

    Ramanath, Ganpati Kwan, Matthew; Chow, P. K.; Quintero, Y. Cardona; Ramprasad, R.; Mutin, P. H.

    2014-08-25

    We demonstrate that weak chemical interactions between untethered moieties in molecular nanolayers on metal surfaces can strongly influence the effective work function ?{sub eff}. Electron spectroscopy shows that nanolayers of mercaptan-anchored organophosphonates on Au and Pt decrease ?{sub eff}. The measured ?{sub eff} shifts correlate with the chemical state of phosphonic acid moieties, and scale with molecular length. These results are contrary to predictions of ab initio calculations of monolayer-capped surfaces, but are consistent with calculations of bilayer-capped surfaces with face-to-face hydrogen-bonded phosphonic acid moieties. Our findings indicate that intra-layer bonding and layering in molecular nanolayers can be key to tailoring heterointerfacial electronic properties for applications.

  5. Noble Americas Energy Solutions LLC | Open Energy Information

    Open Energy Info (EERE)

    - File1a1 EIA Form 861 Data Utility Id 16840 Utility Location Yes Ownership R NERC Location WECC Activity Retail Marketing Yes This article is a stub. You can help OpenEI by...

  6. Effect of Noble Gases on Sonoluminescence Temperatures during...

    Office of Scientific and Technical Information (OSTI)

    Authors: Didenko, Yuri T. ; McNamara, William B. III ; Suslick, Kenneth S. Publication Date: 2000-01-24 OSTI Identifier: 20215350 Resource Type: Journal Article Resource Relation: ...

  7. Saving the Fuel Cell Dream: Making Non Noble Metal Electrocatalysts...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    kick-off meeting of the U.S. Department of Energy Fuel Cell Technologies Program's Catalysis Working Group, held May 14, 2012, in Arlington, Virginia. 4cwgmay2012mukerjee.pdf ...

  8. Method for the purification of noble gases, nitrogen and hydrogen

    DOE Patents [OSTI]

    Baker, J.D.; Meikrantz, D.H.; Tuggle, D.G.

    1997-09-23

    A method and apparatus are disclosed for the purification and collection of hydrogen isotopes in a flowing inert gaseous mixture containing impurities, wherein metal alloy getters having the capability of sorbing non-hydrogen impurities such as oxygen, carbon dioxide, carbon monoxide, methane, ammonia, nitrogen and water vapor are utilized to purify the gaseous mixture of impurities. After purification hydrogen isotopes may be more efficiently collected. A plurality of parallel process lines utilizing metal getter alloys can be used to provide for the continuous purification and collection of the hydrogen isotopes. 15 figs.

  9. Intensive Sampling Of Noble Gases In Fluids At Yellowstone- I...

    Open Energy Info (EERE)

    I, Early Overview Of The Data, Regional Patterns Abstract The Roving Automated Rare Gas Analysis (RARGA) lab of Berkeley's Physics Department was deployed in Yellowstone...

  10. Noble Americas Energy Solutions LLC | Open Energy Information

    Open Energy Info (EERE)

    Data Utility Id 16840 Utility Location Yes Ownership R NERC Location WECC Activity Retail Marketing Yes This article is a stub. You can help OpenEI by expanding it. Utility Rate...

  11. Atomic Layer Deposition (ALD) Preparation of Noble Metal Catalysts - Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    National Nuclear Security Administration | (NNSA) Explores Peaceful Uses of Nuclear Explosions Atomic Energy Commission Explores Peaceful Uses of Nuclear Explosions Nevada Test Site, NV As part of the Plowshare program seeking to develop peaceful uses for nuclear explosives, the Atomic Energy Commission conducts the Sedan test at the Nevada Test Site Programs | National Nuclear Security Administration | (NNSA)

    Takes Over Responsibility for all Atomic Energy Programs Atomic Energy

  12. CONNECTED LIGHTING SYSTEMS WORKSHOP HOTEL INFORMATION

    Broader source: Energy.gov [DOE]

    Workshop LocationHyatt Regency Santa Clara5101 Great America ParkwaySanta Clara, CA 95051408-200-1234

  13. cs5b02062 1..13

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    T. Beckham* , National Bioenergy Center and Hydrogen and Transportation Systems Center, National Renewable Energy Laboratory, 15013 Denver West Parkway, Golden, ...

  14. Identifying low-coverage surface species on noble metal nanoparticles by DNP-NMR

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Johnson, Robert L.; Perras, Frdric A.; Kobayashi, Takeshi; Schwartz, Thomas J.; Dumesic, James A.; Shanks, Brent H.; Pruski, Marek

    2015-11-20

    DNP-NMR spectroscopy has been applied to enhance the signal for organic molecules adsorbed on ?-Al2O3-supported Pd nanoparticles. In addition, by offering >2500-fold time savings, the technique enabled the observation of 13C-13C cross-peaks for low coverage species, which were assigned to products from oxidative degradation of methionine adsorbed on the nanoparticle surface.

  15. Photo-induced strengthening of weak bonding in noble gas dimers

    SciTech Connect (OSTI)

    Miyamoto, Yoshiyuki; Miyazaki, Takehide; Rubio, Angel

    2014-05-19

    We demonstrate through extensive first-principles time-dependent density functional calculations that attractive van der Waals interaction between closed-shell atoms can be enhanced by light with constant spatial intensity. We illustrate this general phenomenon for a He dimer as a prototypical case of complex van der Waals interactions and show that when excited by light with a frequency close to the 1s → 2p He-atomic transition, an attractive force larger than 7 pN is produced. This force gain is manifested as a larger acceleration of He-He contraction under an optical field. The concerted dynamical motions of the He atoms together with polarity switching of the charge-induced dipole cause the contraction of the dimer. These findings are relevant for the photo-induced control of weakly bonded molecular species, either in gas phase or in solution.

  16. Noble reactions for the actinides: safe gold-based access to organouranium and azide complexes

    SciTech Connect (OSTI)

    Thomson, Robert K; Graves, Christopher R; Scott, Brian L; Kiplinger, Jaqueline L

    2008-01-01

    Gold has had a profound impact on organic chemistry; its compounds are spectacular catalysts for many organic transformations involving the formation of C-C, C-O, C-N and CoS bonds, and have enabled unprecedented pathways for the functionalization of C-H and C-C bonds. In general, gold complexes have not been exploited as reagents in organometallic or inorganic chemistry, although a few gold(l) aryl and alkynyl compounds have been reported to undergo transmetalation with transition metal complexes. We have been developing methods for functionalizing uranium complexes and have shown that Cu(l)-X reagents effect the oxidation of uranium with formation of U-X bonds, providing easy chemical control over uranium in oxidation states ranging from U{sup III}{yields}U{sup VI}. Although a logical approach for the direct generation of U-carbon and U-azide bonds, this Cu-based platform is limited in scope as it only works for pure and isolable copper compounds. This is problematic given the instability of organocuprates and copper azides, which can detonate violently as isolated solids. As such, this route has been confined to the synthesis of select uranium phenylacetylide complexes. Over the past few years, a variety of stable gold(l) alkyl, alkenyl, aryl, alkynyl, and azide complexes have been reported, propelling us to investigate their potential as reagents within the oxidative functionalization platform. Unlike the related CU{sup I} systems, Au{sup I} reagents are easily derivatized, and are safe to handle and isolate. Herein, we report that gold(l)-phosphine compounds can undergo a new class of reaction, and are excellent reagents for the oxidative functionalization of uranium with azide and carbon anions.

  17. Noble Gas Evidence For Two Fluids In The Baca (Valles Caldera...

    Open Energy Info (EERE)

    suggest a deeper source, possibly including gases escaping from a magma. Authors S. P. Smith and B. M. Kennedy Published Journal Geochimica et Cosmochimica Acta, 1985 DOI 10.1016...

  18. A generic biokinetic model for noble gases with application to radon

    SciTech Connect (OSTI)

    Leggett, Richard Wayne; Marsh, James; Gregoratto, Demetrio; Blanchardon, Eric

    2013-01-01

    The International Commission for Radiological Protection (ICRP) currently uses a dose conversion coefficient to calculate effective dose per unit exposure to radon and its progeny. The coefficient is derived by dividing the detriment associated with unit exposure to radon, as estimated from epidemiological studies, by the detriment per unit effective dose, as estimated mainly from atomic bomb survivor data and animal studies. In a recent statement the ICRP indicated that future guidance on exposure to radon and its progeny will be developed in the same way as guidance for any other radionuclide. That is, intake of radon and progeny will be limited on the basis of effective dose coefficients derived from biokinetic and dosimetric models. This paper proposes a biokinetic model for systemic (absorbed) radon for use in the calculation of dose coefficients for inhaled or ingested radon. The model is based largely on physical laws governing transfer of a non-reactive and soluble gas between materials. Model predictions are shown to be consistent with results of controlled studies of the fate of internally deposited radon in human subjects.

  19. The miniCLEAN single-phase noble liquid dark mater experiment...

    Office of Scientific and Technical Information (OSTI)

    which observes scintillation light from a 150kg fiducial mass liquid argon target. This detector design strategy emphasizes scalability to target masses of order 10 tons or more. ...

  20. Collective photonic-plasmonic resonances in noble metal - dielectric nanoparticle hybrid arrays

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Hong, Yan; Reinhard, Bjrn M.

    2014-10-27

    Coherent scattering of gold and silver nanoparticles (NPs) in regular arrays can generate Surface Lattice Resonances (SLRs) with characteristically sharp spectral features. Herein, we investigate collective resonances in compositionally more complex arrays comprising NP clusters and NPs with different chemical compositions at pre-defined lattice sites. We first characterize the impact of NP clustering by exchanging individual gold NPs in the array through dimers of electromagnetically strongly coupled gold NPs. Then, we analyze hybrid arrays that contain both gold metal NP dimers and high refractive index dielectric NPs as building blocks. We demonstrate that the integration of gold NP clusters andmoredielectric NPs into one array enhances E-field intensities not only in the vicinity of the NPs but also in the ambient medium of the entire array. In addition, this work shows that the ability to integrate multiple building blocks with different resonance conditions in one array provides new degrees of freedom for engineering optical fields in the array plane with variable amplitude and phase.less

  1. The miniCLEAN single-phase noble liquid dark mater experiment...

    Office of Scientific and Technical Information (OSTI)

    provide a unique test of the expected A squared dependence of the WIMP interaction rate. ... Language: English Subject: 70 PLASMA PHYSICS AND FUSION TECHNOLOGY; ARGON; DESIGN; ...

  2. Cryogenic argon ionization chamber detector for analysis of radioactive noble gases. Master's thesis

    SciTech Connect (OSTI)

    Berggren, S.R.

    1982-03-01

    Two ionization chamber detectors, using liquid or solid argon as their medium were designed, constructed and tested as an improved means of analyzing quantitatively xenon 131m and xenon 133. Problems with the first detector, including vibrational noise and inadequate temperature control, limited its use to studies using solid argon. In the second design, many operating problems of the first detector were corrected. Properties of the detectors were studied using external gamma sources and xenon 131m dispersed inside the detector medium. The xenon sample and argon were purified and cryogenically pumped into the detector for spectral analysis. Both the purity of the argon and bias voltages affected resolution by changing the trapping distance of the electrons in the medium. Lower temperatures increased detection efficiency by condensing more of the sample into the cell. No clearly recognizable energy peak could be found in spectra from external or internal sources.

  3. Identifying low-coverage surface species on supported noble metal nanoparticle catalysts by DNP-NMR

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Johnson, Robert L.; Perras, Frédéric A.; Kobayashi, Takeshi; Schwartz, Thomas J.; Dumesic, James A.; Shanks, Brent H.; Pruski, Marek

    2015-11-20

    DNP-NMR spectroscopy has been applied to enhance the signal for organic molecules adsorbed on γ-Al2O3-supported Pd nanoparticles. In addition, by offering >2500-fold time savings, the technique enabled the observation of 13C-13C cross-peaks for low coverage species, which were assigned to products from oxidative degradation of methionine adsorbed on the nanoparticle surface.

  4. Hydrogen Isotope Separation From Noble Gasses in Plasma Exhausts and Other

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hydrogen Infrastructure Transition Analysis M. Melendez and A. Milbrandt Milestone Report NREL/TP-540-38351 January 2006 Hydrogen Infrastructure Transition Analysis M. Melendez and A. Milbrandt Prepared under Task No. HY55.2200 Milestone Report NREL/TP-540-38351 January 2006 National Renewable Energy Laboratory 1617 Cole Boulevard, Golden, Colorado 80401-3393 303-275-3000 * www.nrel.gov Operated for the U.S. Department of Energy Office of Energy Efficiency and Renewable Energy by Midwest

  5. Identifying low-coverage surface species on supported noble metal nanoparticle catalysts by DNP-NMR

    SciTech Connect (OSTI)

    Johnson, Robert L.; Perras, Frdric A.; Kobayashi, Takeshi; Schwartz, Thomas J.; Dumesic, James A.; Shanks, Brent H.; Pruski, Marek

    2015-11-20

    DNP-NMR spectroscopy has been applied to enhance the signal for organic molecules adsorbed on ?-Al2O3-supported Pd nanoparticles. In addition, by offering >2500-fold time savings, the technique enabled the observation of 13C-13C cross-peaks for low coverage species, which were assigned to products from oxidative degradation of methionine adsorbed on the nanoparticle surface.

  6. EMAB Meeting - May 2012 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ENVIRONMENTAL MANAGEMENT ADVISORY BOARD Hotel on the Falls 475 River Parkway * Idaho ... KB) EMAB Briefing on Capital Assets Projects and Operations Activities Presentation ...

  7. Archer Daniels Midland | Open Energy Information

    Open Energy Info (EERE)

    Daniels Midland Address: 4666 Faries Parkway Place: Decatur, IL Zip: 62526 Sector: Biofuels Product: turn crops into renewable products Phone Number: 800-637-5843 Website:...

  8. Interdisciplinary Civil/Electrical Engineer | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Office of the Chief Operating Officer, Design, Civil Engineering (A7920). 12155 West Alameda Parkway, Lakewood, CO 80228. Find out more about living conditions at this duty...

  9. USAJobs Search | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Office of the Chief Operating Officer, Design, Civil Engineering (A7920). 12155 West Alameda Parkway, Lakewood, CO 80228. Find out more about living conditions at this duty...

  10. USAJobs Search | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Office, Office of the Chief Operating Officer, Natural Resources (A7400). 12155 West Alameda Parkway, Lakewood, CO 80228. Duty location is non-negotiable; this position requires...

  11. USAJobs Search | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    information). Where would I be working? Western Area Power Administration 12155 W. Alameda Parkway Lakewood CO 80228 Find out more about living conditions at this duty station...

  12. USAJobs Search | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Corporate Services Office, Office of the Chief Financial Officer, Governance & Policy (A8500). 12155 West Alameda Parkway, Lakewood, CO 80228. Find out more about living conditions...

  13. USAJobs Search | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    of the Financial Officer, Financial Management, Financial Systems (A8230). 12155 West Alameda Parkway, Lakewood, CO 80228. Find out more about living conditions at this duty...

  14. USAJobs Search | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Services Office, Office of the Chief Operating Officer, Design, Civil Engineering (A7920). 12155 West Alameda Parkway, Lakewood, CO 80228. Find out more about living conditions...

  15. Verenium Corporation (Massachusetts) | Open Energy Information

    Open Energy Info (EERE)

    (Massachusetts) Jump to: navigation, search Name: Verenium Corporation Address: 55 Cambridge Parkway, 8th Floor Place: Cambridge, Massachusetts Zip: 02142 Region: Greater Boston...

  16. Sevin Rosen Funds (Texas - Austin) | Open Energy Information

    Open Energy Info (EERE)

    Austin) Jump to: navigation, search Name: Sevin Rosen Funds (Texas - Austin) Address: 6300 Bridgepoint Parkway, Building 1, Suite 500 Place: Austin, Texas Zip: 78730 Region: Texas...

  17. University of Tennessee | Open Energy Information

    Open Energy Info (EERE)

    Testing Facilities Name University of Tennessee Address University of Tennessee Space Center, 411 B.H. Goethert Parkway Place Tullahoma, Tennessee Zip 37388 Sector Hydro...

  18. Standard Solar | Open Energy Information

    Open Energy Info (EERE)

    Standard Solar Name: Standard Solar Address: 202 Perry Parkway Place: Gaithersburg, Maryland Zip: 20877 Region: Northeast - NY NJ CT PA Area Sector: Solar Product: Solar...

  19. NREL: Education Center - Events

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Education Center Printable Version Events Unless otherwise notified, events listed here will be held at the NREL Education Center, 15013 Denver West Parkway, Golden, CO. The...

  20. Management & Program Analyst

    Broader source: Energy.gov [DOE]

    Where would I be working? Western Area Power Administration, Corporate Services Office, Office of the Chief Financial Officer, Governance and Policy (A8500). 12155 West Alameda Parkway, Lakewood,...

  1. Lighthouse Solar Honolulu Hawaii | Open Energy Information

    Open Energy Info (EERE)

    Solar Honolulu Hawaii Address: 1040 Sand Island parkway Suite 100 Place: Honolulu, HI Zip: 96819 Sector: Solar Phone Number: (808) 783-0357 Website: www.lighthousesolar.com...

  2. Comments from

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Forest 3106 Pierce Parkway Suite D Springfield OR 97477 (541) 225-6348 khuddleston@fs.fed.us website: http:www.oregonfeb.usofebpagesofebsh aredneutrals.htm Workplace...

  3. DOE Publishes Notice of Public Meeting for Smart Grid-connected...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Time, in Golden, Colorado at the National Renewable Energy Laboratory (NREL), San Juan Room Conference Room, on the South Table Mountain Campus, 15013 Denver West Parkway,...

  4. Golden Field Office | Open Energy Information

    Open Energy Info (EERE)

    DOE Golden Field Office Abbreviation: DOE GFO Address: 15013 Denver West Parkway Place: Golden, Colorado Zip: 80401 Phone Number: 720-356-1800 ParentHolding Organization: US...

  5. Golden Field Office | Open Energy Information

    Open Energy Info (EERE)

    DOE Golden Field Office) Jump to: navigation, search Name: DOE Golden Field Office Abbreviation: DOE GFO Address: 15013 Denver West Parkway Place: Golden, Colorado Zip: 80401 Phone...

  6. Blue Sun Biodiesel LLC | Open Energy Information

    Open Energy Info (EERE)

    Biodiesel LLC Jump to: navigation, search Logo: Blue Sun Energy, Inc. Name: Blue Sun Energy, Inc. Address: 14143 Denver West Parkway Place: Golden, Colorado Zip: 80401 Region:...

  7. HOTEL-CONNECTED LIGHTING SYSTEMS MEETING AND TECHNOLOGY DEVELOPMENT...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    MEETING AND TECHNOLOGY DEVELOPMENT WORKSHOP Portland Marriott Downtown Waterfront 1401 SW Naito Parkway Portland, OR 97201 1-877-901-6632 The room block reserved at the Portland...

  8. A PUBLICATION FOR ALL MEMBERS OF THE NNSA/NV FAMILY Contents

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... Desert Research Institute; Grapevine Junction; Lockheed Martin Systems Management; ... Meeting begins at 6:00 p.m. Clark County Government Center, 500 Grand Central Parkway, Las ...

  9. QA Corporate Board Meeting - November 2008 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Meeting Location: Renaissance Concourse Hotel Atlanta Airport, One Hartsfield Centre, Parkway Atlanta, Georgia 30354 Room: Shannon One and Two Draft Agenda for November 13, 2008 ...

  10. The physical nature of the phenomenon of positive column plasma constriction in low-pressure noble gas direct current discharges

    SciTech Connect (OSTI)

    Kurbatov, P. F.

    2014-02-15

    The essence of the positive-column plasma constriction for static (the diffusion mode) and dynamic ionization equilibrium (the stratificated and constricted modes) is analyzed. Two physical parameters, namely, the effective ionization rate of gas atoms and the ambipolar diffusion coefficient of electrons and ions, determine the transverse distribution of discharge species and affect the current states of plasma. Transverse constriction of the positive column takes place as the gas ionization level (discharge current) and pressure increase. The stratified mode (including the constricted one) is observed between the two adjacent types of self-sustained discharge phases when they coexist together at the same time or in the same place as a coherent binary mixture. In the case, a occurrence of the discharge phase with more high electron density presently involve a great decrease in the cross-section of the current channel for d.c. discharges. Additional physical factors, such as cataphoresis and electrophoresis phenomena and spatial gas density inhomogeneity correlated with a circulatory flow in d.c. discharges, are mainly responsible for the current hysteresis and partially constricted discharge.

  11. Sources of metals in the Porgera gold deposit, Papua New Guinea: Evidence from alteration, isotope, and noble metal geochemistry

    SciTech Connect (OSTI)

    Richards, J.P.; McCulloch, M.T.; Chappell, B.W. ); Kerrich, R. )

    1991-02-01

    The Porgera gold deposit is spatially and temporally associated with the Late Miocene, Mafic, alkalic, epizonal Porgera Intrusive Complex (PIC), located in the highlands of Papua New Guinea (PNG). The highlands region marks the site of a Tertiary age continent-island-arc collision zone, located on the northeastern edge of the Australasian craton. It is suggested that the hydrothermal fluids acquired their Sr and Pb isotopic signatures by interaction with, or direct derivation from, a plutonic root of the PIC and host sedimentary rocks of the Om Formation. It is likely that Au was also derived from one or both of these two sources. Concentrations of Au in unaltered igneous and sedimentary rocks from Porgera ({le}10 ppb Au) do not indicate that either lithology represents a significantly enriched protore, although Au and platinum-group element (PGE) abundances in the igneous rocks suggest a mild primary magmatic enrichment of Au relative to the PGE (average (Au/(Pt+Pd)) {sub mantle normalized} = 14.0 {plus minus} 6.5 (n = 8)). Evidence that the Porgera magmas were rich in volatiles permits speculation that Au may have been concentrated in a magmatic fluid phase, but alternative possibilities such as derivation of Au by hydrothermal leaching of solidified igneous materials or sedimentary rocks cannot be excluded at this time.

  12. TEST PROCEDURE VALIDATION TEST OF A DISCRIMINATING TRITIUM MONITOR FOR MEASURING TRITIUM OXIDE IN THE PRESENCE OF NOBLE GASES

    Office of Environmental Management (EM)

    Tribal Summit Secretary Steven Chu Remarks as Prepared for Delivery Thursday, May 5, 2011 Arlington, VA Good morning. Thank you all for joining us today, including those of you watching online. The Obama Administration is committed to strong engagement with Tribal Nations. As a sign of that commitment, you heard from Secretary Vilsack yesterday, and today you will also hear from Secretary Salazar, Administrator Jackson, and White House officials. When I started as Energy Secretary, I made a

  13. Determination of plasma frequency, damping constant, and size distribution from the complex dielectric function of noble metal nanoparticles

    SciTech Connect (OSTI)

    Mendoza Herrera, Luis J.; Arboleda, David Muetn; Schinca, Daniel C.; Scaffardi, Luca B.

    2014-12-21

    This paper develops a novel method for simultaneously determining the plasma frequency ?{sub P}?? and the damping constant ?{sub free} in the bulk damped oscillator Drude model, based on experimentally measured real and imaginary parts of the metal refractive index in the IR wavelength range, lifting the usual approximation that restricts frequency values to the UV-deep UV region. Our method was applied to gold, silver, and copper, improving the relative uncertainties in the final values for ?{sub p} (0.5%1.6%) and for ?{sub free} (3%8%), which are smaller than those reported in the literature. These small uncertainties in ?{sub p} and ?{sub free} determination yield a much better fit of the experimental complex dielectric function. For the case of nanoparticles (Nps), a series expansion of the Drude expression (which includes ?{sub p} and ?{sub free} determined using our method) enables size-dependent dielectric function to be written as the sum of three terms: the experimental bulk dielectric function plus two size corrective terms, one for free electron, and the other for bound-electron contributions. Finally, size distribution of nanometric and subnanometric gold Nps in colloidal suspension was determined through fitting its experimental optical extinction spectrum using Mie theory based on the previously determined dielectric function. Results are compared with size histogram obtained from Transmission Electron Microscopy (TEM)

  14. Synthesis of metal-metal oxide catalysts and electrocatalysts using a metal cation adsorption/reduction and adatom replacement by more noble ones

    DOE Patents [OSTI]

    Adzic, Radoslav; Vukmirovic, Miomir; Sasaki, Kotaro

    2010-04-27

    The invention relates to platinum-metal oxide composite particles and their use as electrocatalysts in oxygen-reducing cathodes and fuel cells. The invention particularly relates to methods for preventing the oxidation of the platinum electrocatalyst in the cathodes of fuel cells by use of these platinum-metal oxide composite particles. The invention additionally relates to methods for producing electrical energy by supplying such a fuel cell with an oxidant, such as oxygen, and a fuel source, such as hydrogen. The invention also relates to methods of making the metal-metal oxide composites.

  15. MERCURY-NITRITE-RHODIUM-RUTHENIUM INTERACTIONS IN NOBLE METAL CATALYZED HYDROGEN GENERATION FROM FORMIC ACID DURING NUCLEAR WASTE PROCESSING AT THE SAVANNAH RIVER SITE - 136C

    SciTech Connect (OSTI)

    Koopman, D.; Pickenheim, B.; Lambert, D.; Newell, J; Stone, M.

    2009-09-02

    Chemical pre-treatment of radioactive waste at the Savannah River Site is performed to prepare the waste for vitrification into a stable waste glass form. During pre-treatment, compounds in the waste become catalytically active. Mercury, rhodium, and palladium become active for nitrite destruction by formic acid, while rhodium and ruthenium become active for catalytic conversion of formic acid into hydrogen and carbon dioxide. Nitrite ion is present during the maximum activity of rhodium, but is consumed prior to the activation of ruthenium. Catalytic hydrogen generation during pre-treatment can exceed radiolytic hydrogen generation by several orders of magnitude. Palladium and mercury impact the maximum catalytic hydrogen generation rates of rhodium and ruthenium by altering the kinetics of nitrite ion decomposition. New data are presented that illustrate the interactions of these various species.

  16. Test Results For Physical Separation Of Tritium From Noble Gases And It’s Implications For Sensitivity And Accuracy In Air And Stack Monitoring

    Broader source: Energy.gov [DOE]

    Presentation from the 32nd Tritium Focus Group Meeting held in Germantown, Maryland on April 23-25, 2013.

  17. The Fundamental Role of Nano-Scale Oxide Films in the Oxidation of Hydrogen and the Reduction of Oxygen on Noble Metal Electrocatalysts

    SciTech Connect (OSTI)

    Digby Macdonald

    2005-04-15

    The derivation of successful fuel cell technologies requires the development of more effective, cheaper, and poison-resistant electrocatalysts for both the anode (H{sub 2} oxidation in the presence of small amounts of CO from the reforming of carbonaceous fuels) and the cathode (reduction of oxygen in the presence of carried-over fuel). The proposed work is tightly focused on one specific aspect of electrocatalysis; the fundamental role(s) played by nanoscale (1-2 nm thick) oxide (''passive'') films that form on the electrocatalyst surfaces above substrate-dependent, critical potentials, on charge transfer reactions, particularly at elevated temperatures (25 C < T < 200 C). Once the role(s) of these films is (are) adequately understood, we will then use this information to specify, at the molecular level, optimal properties of the passive layer for the efficient electrocatalysis of the oxygen reduction reaction.

  18. CX-010246: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    South Table Mountain Denver West Parkway Improvements CX(s) Applied: A9, B1.33 Date: 03/21/2013 Location(s): Colorado Offices(s): Golden Field Office

  19. Connected Lighting Systems Workshop Venue and Hotel Information

    Broader source: Energy.gov [DOE]

    The Connected Lighting Systems Workshop will be held in the Grand Ballroom at the Hyatt Regency Santa Clara, 5101 Great America Parkway, Santa Clara, CA, 95051. The Hyatt Regency is connected to...

  20. 2011 October Center Directory.pub

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Watt Way, VHE 309 ningfenh@usc.edu 213-740-0713 Gisele Ragusa, PhD, MS Department of Psychology in Education 3470 Trousdale Parkway, WPH 401 Los Angeles, Ca, 90089 ragusa@usc.edu...

  1. GreenCore Capital | Open Energy Information

    Open Energy Info (EERE)

    GreenCore Capital Jump to: navigation, search Logo: GreenCore Capital Name: GreenCore Capital Address: 10509 Vista Sorrento Parkway Place: San Diego, California Zip: 92121 Region:...

  2. Microsoft Word - Agenda_SSAB_Chairs_6-15-11.FINAL

    Office of Environmental Management (EM)

    Hosted by Nevada Site Specific Advisory Board DRAFT Agenda EM SSAB Chairs Meeting June 15 and 16, 2011 Aliante Station 7300 Aliante Parkway North Las Vegas, Nevada 89084 DAY 1 ...

  3. USCA Convocation Center 375 Robert ...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1, 2013 USCA Convocation Center 375 Robert M. Bell Parkway, Aiken, SC 29801 Cash Bar Reception 6:00-6:45 pm BanquetLecture 7:00 pm Tickets: 50 per person Must be...

  4. NCO Directory (by program)

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Efficiency and Renewable Energy (EERE) lori.gray@ee.doe.gov Energy Efficiency and ... West Parkway Golden, CO 80401 EERE Lori Gray Golden Field Office Page 1 NEPA Compliance ...

  5. NOTICE OF AVAILABILITY

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Lori Gray, 15013 Denver West Parkway, Golden, CO 80401, by fax to 720-356-1350, or by email to gonepa@ee.doe.gov. In addition, interested persons are invited to attend an ...

  6. EMAB Meeting - February 2011 | Department of Energy

    Office of Environmental Management (EM)

    Green Valley Ranch * La Sirena II 2300 Paseo Verde Parkway * Henderson, Nevada 89052 Documents Available for Download Meeting Minutes (416.13 KB) Meeting Agenda (50.35 KB) More ...

  7. Application to Export Electric Energy OE Docket No. EA-363-A...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    OE Docket No. EA-363-A Noble Americas Gas & Power Corporation Application from NAG&P to export electric energy to Mexico. PDF icon EA-363-A Noble Americas G&P (MX).pdf More...

  8. Application to Export Electric Energy OE Docket No. EA-364-A...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    4-A Noble Americas Gas & Power Corporation Application to Export Electric Energy OE Docket No. EA-364-A Noble Americas Gas & Power Corporation Application from NAG&P to export...

  9. In-situ Studies of the Reactions of Bifunctional and Heterocyclic Molecules over Noble Metal Single Crystal and Nanoparticle Catalysts Studied with Kinetics and Sum-Frequency Generation Vibrational Spectroscopy

    SciTech Connect (OSTI)

    Kliewer, Christopher J.

    2009-06-30

    Sum frequency generation surface vibrational spectroscopy (SFG-VS) in combination with gas chromatography (GC) was used in-situ to monitor surface bound reaction intermediates and reaction selectivities for the hydrogenation reactions of pyrrole, furan, pyridine, acrolein, crotonaldehyde, and prenal over Pt(111), Pt(100), Rh(111), and platinum nanoparticles under Torr reactant pressures and temperatures of 300K to 450K. The focus of this work is the correlation between the SFG-VS observed surface bound reaction intermediates and adsorption modes with the reaction selectivity, and how this is affected by catalyst structure and temperature. Pyrrole hydrogenation was investigated over Pt(111) and Rh(111) single crystals at Torr pressures. It was found that pyrrole adsorbs to Pt(111) perpendicularly by cleaving the N-H bond and binding through the nitrogen. However, over Rh(111) pyrrole adsorbs in a tilted geometry binding through the {pi}-aromatic orbitals. A surface-bound pyrroline reaction intermediate was detected over both surfaces with SFG-VS. It was found that the ring-cracking product butylamine is a reaction poison over both surfaces studied. Furan hydrogenation was studied over Pt(111), Pt(100), 10 nm cubic platinum nanoparticles and 1 nm platinum nanoparticles. The product distribution was observed to be highly structure sensitive and the acquired SFG-VS spectra reflected this sensitivity. Pt(100) exhibited more ring-cracking to form butanol than Pt(111), while the nanoparticles yielded higher selectivities for the partially saturated ring dihydrofuran. Pyridine hydrogenation was investigated over Pt(111) and Pt(100). The {alpha}-pyridyl surface adsorption mode was observed with SFG-VS over both surfaces. 1,4-dihydropyridine was seen as a surface intermediate over Pt(100) but not Pt(111). Upon heating the surfaces to 350K, the adsorbed pyridine changes to a flat-lying adsorption mode. No evidence was found for the pyridinium cation. The hydrogenation of the {alpha},{beta}-unsaturated aldehydes acrolein, crotonaldehyde, and prenal were investigated over Pt(111) and Pt(100). The selectivity for the hydrogenation of the C=C bond was found to depend on the number of methyl groups added to the bond. The adsorption modes of the three aldehydes were determined. The hydrogenation of crotonaldehyde was found to be nearly structure insensitive as the TOF and selectivity were very close to the same over Pt(111) and Pt(100). SFG-VS indicated identical surface intermediates over the two crystal faces during crotonaldehyde hydrogenation.

  10. California GAMA Special Study:Archival Data Conversion & Upload

    SciTech Connect (OSTI)

    Visser, A.; Eppich, G.; Bibby, R.; Singleton, M.; Hillegonds, D.; Moran, J.; Esser, B.

    2014-02-18

    LLNL has uploaded over 3000 tritium analyses and over 4000 noble gas analyses to the GeoTracker GAMA database.

  11. PowerPoint Presentation

    National Nuclear Security Administration (NNSA)

    INDEPENDENCE AVE. 23rd STREET BLUE PARKWAY MAIN STREET B O T T S R D 140TH STREET BLUE RIDGE BLVD RED BRIDGE RD G R A N D V I E W R D VOLKER BLVD. UMKC ROCKHURST UNIVERSITY COUNTRY ...

  12. CX-100539 Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Incorporation of Solar Powered Safety Lights Along the Blue Ridge Parkway Award Number: DE-EE0006621 CX(s) Applied: B5.1 Federal Emergency Management Program Date: 07/28/2014 Location(s): NC Office(s): Golden Field Office

  13. CX-001060: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Denver West Parkway/Marriott Boulevard Intersection Improvements; National Renewable Energy Laboratory Tracking Number 09-044CX(s) Applied: B1.32Date: 02/23/2010Location(s): Lakewood, ColoradoOffice(s): Energy Efficiency and Renewable Energy, Golden Field Office

  14. Leaders of DOE Environmental Management Advisory Group to Meet in North Las Vegas

    Broader source: Energy.gov [DOE]

    Nevada Site Office News - The Chairs and Vice-Chairs of the U.S. Department of Energy’s (DOE) Environmental Management (EM) Site-Specific Advisory Board (SSAB) will meet in North Las Vegas, Nevada, June 15-16, at Aliante Station Hotel located at 7300 Aliante Parkway.

  15. Leaders of DOE Environmental Management Advisory Group to Meet in Henderson

    Broader source: Energy.gov [DOE]

    The Chairs and Vice-Chairs of the U.S. Department of Energy’s (DOE) Environmental Management (EM) Site-Specific Advisory Board (SSAB) will meet in Henderson, NV, April 13-14, at Green Valley Ranch located at 2300 Paseo Verde Parkway.

  16. Climate Zone 6A | Open Energy Information

    Open Energy Info (EERE)

    Morrison County, Minnesota Morton County, North Dakota Mower County, Minnesota Murray County, Minnesota Newaygo County, Michigan Nicollet County, Minnesota Nobles County,...

  17. Sabine Parish, Louisiana: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    3 Climate Zone Subtype A. Places in Sabine Parish, Louisiana Converse, Louisiana Fisher, Louisiana Florien, Louisiana Many, Louisiana Noble, Louisiana Pleasant Hill,...

  18. NETL F 451.1/1-1, Categorical Exclusion Designation Form

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    - Grantsburg, IL and Noble, IL FESCCStorage Division Bruce Brown A Nonconventional CO2-EOR Target in the Illinois Basin: Oil Reservoirs of the.. Project planning, data...

  19. DNA Origami Directed Self-Assembly of Discrete Silver Nanoparticle...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    DNA origami nanostructures were utilized as spatially addressable templates to organize noble-metal nanoparticles of silver and gold into well-defined discrete architectures ...

  20. Record of Categorical Exclusion (CS) Determination, Office of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Determination, Office of Electricity Delivery and Energy Reliability (OE): EA-363 Noble Americas Gas & Power Corporation Record of Categorical Exclusion (CS) Determination, ...

  1. Platinum-ruthenium-nickel alloy for use as a fuel cell catalyst

    DOE Patents [OSTI]

    Gorer, Alexander

    2003-01-01

    An improved noble metal alloy composition for a fuel cell catalyst, the alloy containing platinum, ruthenium, and nickel. The alloy shows methanol oxidation activity.

  2. Platinum-ruthenium-nickel alloy for use as a fuel cell catalyst

    DOE Patents [OSTI]

    Gorer, Alexander

    2004-04-20

    An improved noble metal alloy composition for a fuel cell catalyst, the alloy containing platinum, ruthenium, and nickel. The alloy shows methanol oxidation activity.

  3. Compound and Elemental Analysis At Yellowstone Region (Kennedy...

    Open Energy Info (EERE)

    not indicated DOE-funding Unknown References B. M. Kennedy, J. H. Reynolds, S. P. Smith (1988) Noble Gas Geochemistry In Thermal Springs Additional References Retrieved from...

  4. New Opportunities for Outer Solar System Science using Radioisotope

    Office of Scientific and Technical Information (OSTI)

    Opportunities for Outer Solar System Science using Radioisotope Electric Propulsion Noble, Robert J.; SLAC; Amini, Rashied; Beauchamp, Patricia M.; Caltech, JPL; Bennett, Gary...

  5. "Title","Creator/Author","Publication Date","OSTI Identifier...

    Office of Scientific and Technical Information (OSTI)

    New Opportunities for Outer Solar System Science using Radioisotope Electric Propulsion","Noble, Robert J.; SLAC; Amini, Rashied; Beauchamp, Patricia M.; Caltech, JPL; Bennett,...

  6. TITLE AUTHORS SUBJECT SUBJECT RELATED DESCRIPTION PUBLISHER AVAILABILI...

    Office of Scientific and Technical Information (OSTI)

    New Opportunities for Outer Solar System Science using Radioisotope Electric Propulsion Noble Robert J SLAC Amini Rashied Beauchamp Patricia M Caltech JPL Bennett Gary L Metaspace...

  7. Mass Production Cost Estimation for Direct H2 PEM Fuel Cell Systems...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... nickel, conductive metal borides, nitrides and ... niobium, rhodium, rare earth metals, and other noble ... Consequently, a multiplier on the yearly membrane demand ...

  8. mMass Production Cost Estimation for Direct H2 PEM Fuel Cell...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... nickel, conductive metal borides, nitrides and ... niobium, rhodium, rare earth metals, and other noble ... Consequently, a multiplier on the yearly membrane demand ...

  9. Dark matter search results from the PICO-60 CF 3 I bubble chamber...

    Office of Scientific and Technical Information (OSTI)

    ; Harris, O. ; Jin, M. ; Krauss, C. B. ; Lafrenire, M. ; Laurin, M. ; Lawson, I. ; Levine, I. ; Lippincott, W. H. ; Mann, E. ; Maurya, D. ; Mitra, P. ; Neilson, R. ; Noble, A. ...

  10. Dark matter search results from the PICO-60 CF3I bubble chamber...

    Office of Scientific and Technical Information (OSTI)

    C. ; Harris, O. ; Jin, M. ; Krauss, C. B. ; Lafreniere, M. ; Laurin, M. ; Lawson, I. ; Levine, I. ; Lippincott, W. H. ; Mann, E. ; Maurya, D. ; Mitra, Pitam ; Neilson, R. ; Noble, ...

  11. Maria Group Inc | Open Energy Information

    Open Energy Info (EERE)

    Group Inc Jump to: navigation, search Name: Maria Group Inc Place: Friendswood, Texas Zip: 77546 Sector: Wind energy Product: Holds patent to Noble Wind Turbine, a vertical axis...

  12. Stamford, Connecticut: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Registered Energy Companies in Stamford, Connecticut Clean Diesel Technologies Inc International Plasma Sales Group IPSG Natural State Research, Inc. Noble Americas...

  13. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... charge (3) inorganic, organic, physical, and analytical ... electro catalysis on noble metal films, leading to ... towards developing a framework through which solid ...

  14. Electrocatalysis in Alkaline Electrolytes - Research Overview...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    VA PDF icon amfc110811mukerjee.pdf More Documents & Publications Saving the Fuel Cell Dream: Making Non Noble Metal Electrocatalysts a Reality? Fuel Cells: Just a Dream...

  15. Wolf Wind Farm | Open Energy Information

    Open Energy Info (EERE)

    Deere Wind Energy Energy Purchaser Central Minnesota Municipal Power Agency Location Nobles County MN Coordinates 43.583385, -95.774567 Show Map Loading map......

  16. Missouri River Energy Services (MRES) Wind Farm (2002) | Open...

    Open Energy Info (EERE)

    Tom Wind Energy Purchaser MRES Worthington Public Utilities Location Worthington - Nobles County MN Coordinates 43.6659, -95.7493 Show Map Loading map......

  17. Operational and Environmental Monitoring Within a Three-Mile...

    Office of Legacy Management (LM)

    RADIUS OF PROJECT RULISON Prepared for: Noble Energy Inc. EnCana Oil & Gas (USA) Inc. ... 16 5.6.3 Gasoline, Diesel, and Motor Oil Constituent Results......

  18. Fairfield County, Connecticut: Energy Resources | Open Energy...

    Open Energy Info (EERE)

    Sales Group IPSG Levco Energy MissionPoint Capital Partners Natural State Research, Inc. New England Energy Management Inc Noble Americas NuPower LLC Ocenergy Opel International...

  19. Research and Development of Non-Spectroscopic MEMS-Based Sensor...

    Office of Scientific and Technical Information (OSTI)

    While mass spectrometry can readily detect noble gases - the helium leak detector is an obvious example - laser-based methods such as infrared (IR) or Raman spectroscopy are ...

  20. PERFORMANCE

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Jee Choi Kent Czechowski Cong Hou Chris McClanahan David S. Noble, Jr. Richard (Rich) Vuduc Salishan Conference on High-Speed Computing Gleneden Beach, Oregon -...

  1. Cleveland County, Oklahoma: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Veolia Energy Places in Cleveland County, Oklahoma Etowah, Oklahoma Lexington, Oklahoma Moore, Oklahoma Noble, Oklahoma Norman, Oklahoma Oklahoma City, Oklahoma Purcell, Oklahoma...

  2. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... Enhanced Bifunctional Oxygen Catalysis in Strained LaNiO3 Perovskites Petrie, Jonathan R. ... low temperature oxygen electro catalysis on noble metal films, leading to ...

  3. Record of Categorical Exclusion (CS) Determination, Office of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Noble Americas Gas & Power Corporation Record of Categorical Exclusion (CS) Determination, Office of Electricity Delivery and Energy Reliability (OE): EA-365 Centre Land Trading

  4. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... low temperature oxygen electro catalysis on noble metal films, leading to significant enhancements in bifunctional activity essential for fuel cells and Metal-air batteries. ...

  5. Enhanced Bifunctional Oxygen Catalysis in Strained LaNiO3 Perovskites...

    Office of Scientific and Technical Information (OSTI)

    low temperature oxygen electro catalysis on noble metal films, leading to significant enhancements in bifunctional activity essential for fuel cells and Metal-air batteries. ...

  6. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... Full Text Available August 2015 Preparation of Electron and X-Ray Transparent Inorganic ... Synthesis of nanostructured bimetallic noble metal powders using Atomic Layer Electroless ...

  7. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... Preparation of Electron and X-Ray Transparent Inorganic Particles for Analytical ... Synthesis of nanostructured bimetallic noble metal powders using Atomic Layer Electroless ...

  8. SAND2008-6687

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    6687 Unlimited Release Printed October 2008 Computational Investigation of Noble Gas Adsorption and Separation by Nanoporous Materials Jeffery A. Greathouse, Mark D. Allendorf, and...

  9. Application to Export Electric Energy OE Docket No. EA-364-A...

    Broader source: Energy.gov (indexed) [DOE]

    Publications Application to Export Electric Energy OE Docket No. EA-363-A Noble Americas Gas & Power Corporation: Federal Register Notice, Volume 80, No. 42 - March 4, 2015...

  10. EC Publications

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (3308 downloads) Solar Energy Grid Integration Systems: Final Report of the Princeton ... (163) Computational Investigation of Noble Gas Adsorption and Separation by Nanoporous ...