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Note: This page contains sample records for the topic "nitrogen oxides particulate" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


1

Back-Trajectory Analysis and Source-Receptor Relationships: Particulate Matter and Nitrogen Isotopic Composition in  

E-Print Network (OSTI)

. The chemical components of these acids, including nitrogen oxides (NOx nitric acid [NO] nitrogen dioxide [NO2Back-Trajectory Analysis and Source-Receptor Relationships: Particulate Matter and Nitrogen- search suggests that this agricultural presence emits a significant portion of the state's nitrogen (i

Niyogi, Dev

2

Wiremesh Substrates for Enhanced Particulate Oxidation and Efficient...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Wiremesh Substrates for Enhanced Particulate Oxidation and Efficient Urea SCR NOx Reduction Wiremesh Substrates for Enhanced Particulate Oxidation and Efficient Urea SCR NOx...

3

THE NITROGEN OXIDES CONTROVERSY  

E-Print Network (OSTI)

including observed nitrogen dioxide," Pure App. Geophys.HN0 ) and probably nitrogen dioxide (N0 ) at a few parts perorganic molecule and nitrogen dioxide. Several examples

Johnston, Harold S.

2012-01-01T23:59:59.000Z

4

Assessment of soil nitrogen oxides emissions and implementation in LOTOS-EUROS  

E-Print Network (OSTI)

the formation and transport of nitrogen dioxide, ozone, particulate matter and other species throughout EuropeAssessment of soil nitrogen oxides emissions and implementation in LOTOS-EUROS Date 18 March 2013, climate and nitrogen availability. Nitrogen availability is in turn determined by N-deposition from

Haak, Hein

5

Diesel Particulate Oxidation Model: Combined Effects of Fixed...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Volatile Carbon Diesel Particulate Oxidation Model: Combined Effects of Fixed & Volatile Carbon Poster presented at the 16th Directions in Engine-Efficiency and Emissions Research...

6

Nitrogen Oxides Emission Control Options  

NLE Websites -- All DOE Office Websites (Extended Search)

Nitrogen Nitrogen Oxides Emission Control Options for Coal-Fired Electric Utility Boilers Ravi K. Srivastava and Robert E. Hall U.S. Environmental Protection Agency, National Risk Management Research Laboratory, Air Pollution Prevention and Control Division, Research Triangle Park, NC Sikander Khan and Kevin Culligan U.S. Environmental Protection Agency, Office of Air and Radiation, Clean Air Markets Division, Washington, DC Bruce W. Lani U.S. Department of Energy, National Energy Technology Laboratory, Environmental Projects Division, Pittsburgh, PA ABSTRACT Recent regulations have required reductions in emissions of nitrogen oxides (NO x ) from electric utility boilers. To comply with these regulatory requirements, it is increas- ingly important to implement state-of-the-art NO x con- trol technologies on coal-fired utility boilers. This paper reviews NO x control

7

nitrogen oxides | OpenEI  

Open Energy Info (EERE)

20 20 Varnish cache server Browse Upload data GDR 429 Throttled (bot load) Error 429 Throttled (bot load) Throttled (bot load) Guru Meditation: XID: 2142279720 Varnish cache server nitrogen oxides Dataset Summary Description Emissions from energy use in buildings are usually estimated on an annual basis using annual average multipliers. Using annual numbers provides a reasonable estimation of emissions, but it provides no indication of the temporal nature of the emissions. Therefore, there is no way of understanding the impact on emissions from load shifting and peak shaving technologies such as thermal energy storage, on-site renewable energy, and demand control. Source NREL Date Released April 11th, 2011 (3 years ago) Date Updated April 11th, 2011 (3 years ago)

8

Nitrogen oxide delivery systems for biological media  

E-Print Network (OSTI)

Elevated levels of nitric oxide (NO) in vivo are associated with a variety of cellular modifications thought to be mutagenic or carcinogenic. These processes are likely mediated by reactive nitrogen species (RNS) such as ...

Skinn, Brian Thomas

2012-01-01T23:59:59.000Z

9

Effect of Diesel Oxidation Catalysts on the Diesel Particulate Filter Regeneration Process  

Science Journals Connector (OSTI)

Effect of Diesel Oxidation Catalysts on the Diesel Particulate Filter Regeneration Process ... A Diesel Particulate Filter (DPF) regeneration process was investigated during aftertreatment exhaust of a simulated diesel engine under the influence of a Diesel Oxidation Catalyst (DOC). ... Diesel particulate matter (PM) significantly contributes to urban air pollution and has often been associated with adverse health effects. ...

Leonardo Lizarraga; Stamatios Souentie; Antoinette Boreave; Christian George; Barbara D’Anna; Philippe Vernoux

2011-11-03T23:59:59.000Z

10

Technology Innovations and Experience Curves for Nitrogen Oxides Control Technologies  

E-Print Network (OSTI)

red power plants. Nitrogen dioxide (NO 2 ) is one of the sixeffects, including nitrogen dioxide (NO 2 ) and ground-levelgradually oxidized to nitrogen dioxide (NO 2 ) once emitted

Yeh, Sonia; Rubin, Edward S.; Taylor, Margaret R.

2007-01-01T23:59:59.000Z

11

Method and apparatus for nitrogen oxide determination  

DOE Patents (OSTI)

Method and apparatus for determining nitrogen oxide content in a high temperature process gas, which involves withdrawing a sample portion of a high temperature gas containing nitrogen oxide from a source to be analyzed. The sample portion is passed through a restrictive flow conduit, which may be a capillary or a restriction orifice. The restrictive flow conduit is heated to a temperature sufficient to maintain the flowing sample portion at an elevated temperature at least as great as the temperature of the high temperature gas source, to thereby provide that deposition of ammonium nitrate within the restrictive flow conduit cannot occur. The sample portion is then drawn into an aspirator device. A heated motive gas is passed to the aspirator device at a temperature at least as great as the temperature of the high temperature gas source. The motive gas is passed through the nozzle of the aspirator device under conditions sufficient to aspirate the heated sample portion through the restrictive flow conduit and produce a mixture of the sample portion in the motive gas at a dilution of the sample portion sufficient to provide that deposition of ammonium nitrate from the mixture cannot occur at reduced temperature. A portion of the cooled dilute mixture is then passed to analytical means capable of detecting nitric oxide.

Hohorst, Frederick A. (Idaho Falls, ID)

1990-01-01T23:59:59.000Z

12

Nitrogen oxides emission trends in Monthly emission estimates of nitrogen oxides from space provide  

E-Print Network (OSTI)

Chapter 5 Nitrogen oxides emission trends in East Asia Abstract Monthly emission estimates present first results of a new emission estimation algorithm, specifically designed to use daily satellite observations of column concentrations for fast updates of emission estimates of short-lived atmospheric

Haak, Hein

13

Predicting residential indoor concentrations of nitrogen dioxide, fine particulate matter, and elemental carbon using questionnaire and geographic information system based data  

E-Print Network (OSTI)

1 2 3 4 5 6 7 8 9 Predicting residential indoor concentrations of nitrogen dioxide, fine collected indoor and outdoor 3-4 day samples of nitrogen dioxide (NO2) and fine particulate matter (PM2

Paciorek, Chris

14

Modeling of Nitrogen Oxides Emissions from CFB Combustion  

Science Journals Connector (OSTI)

In this work, a simplified description of combustion and nitrogen oxides chemistry was implemented in a 1.5D model framework with the aim to compare the results with ones earlier obtained with a detailed react...

S. Kallio; M. Keinonen

2010-01-01T23:59:59.000Z

15

Air Pollution Control Regulations: No.27 - Control of Nitrogen Oxide  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Air Pollution Control Regulations: No.27 - Control of Nitrogen Air Pollution Control Regulations: No.27 - Control of Nitrogen Oxide Emissions (Rhode Island) Air Pollution Control Regulations: No.27 - Control of Nitrogen Oxide Emissions (Rhode Island) < Back Eligibility Commercial Industrial Investor-Owned Utility Municipal/Public Utility Rural Electric Cooperative Utility Program Info State Rhode Island Program Type Environmental Regulations Provider Department of Environmental Management These regulations apply to stationary sources with the potential to emit 50 tons of nitrogen oxides (NOx) per year from all pollutant-emitting equipment or activities. The regulations describe possibilities for exemptions (i.e., for sources which have the potential to emit 50 tons but do not actually reach that level) and Reasonably Available Control

16

Nitrogen Oxide Emission Statements (Ohio) | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Nitrogen Oxide Emission Statements (Ohio) Nitrogen Oxide Emission Statements (Ohio) Nitrogen Oxide Emission Statements (Ohio) < Back Eligibility Agricultural Commercial Construction Fuel Distributor Industrial Investor-Owned Utility Municipal/Public Utility Rural Electric Cooperative Utility Program Info State Ohio Program Type Environmental Regulations Provider Ohio Environmental Protection Agency This chapter of the law establishes that the Ohio Environmental Protection Agency requires any facility that emits 25 tons or more of NOx and/or 25 tons or more of VOC during the calendar year and is located in a county designated as nonattainment for the National Ambient Air Quality Standards for ozone submit emission statements. Any facility that is located in a county described above is exempt from these requirements. If NOx

17

Nitrogen doped zinc oxide thin film  

SciTech Connect

To summarize, polycrystalline ZnO thin films were grown by reactive sputtering. Nitrogen was introduced into the films by reactive sputtering in an NO{sub 2} plasma or by N{sup +} implantation. All ZnO films grown show n-type conductivity. In unintentionally doped ZnO films, the n-type conductivities are attributed to Zn{sub i}, a native shallow donor. In NO{sub 2}-grown ZnO films, the n-type conductivity is attributed to (N{sub 2}){sub O}, a shallow double donor. In NO{sub 2}-grown ZnO films, 0.3 atomic % nitrogen was found to exist in the form of N{sub 2}O and N{sub 2}. Upon annealing, N{sub 2}O decomposes into N{sub 2} and O{sub 2}. In furnace-annealed samples N{sub 2} redistributes diffusively and forms gaseous N{sub 2} bubbles in the films. Unintentionally doped ZnO films were grown at different oxygen partial pressures. Zni was found to form even at oxygen-rich condition and led to n-type conductivity. N{sup +} implantation into unintentionally doped ZnO film deteriorates the crystallinity and optical properties and leads to higher electron concentration. The free electrons in the implanted films are attributed to the defects introduced by implantation and formation of (N{sub 2}){sub O} and Zni. Although today there is still no reliable means to produce good quality, stable p-type ZnO material, ZnO remains an attractive material with potential for high performance short wavelength optoelectronic devices. One may argue that gallium nitride was in a similar situation a decade ago. Although we did not obtain any p-type conductivity, we hope our research will provide a valuable reference to the literature.

Li, Sonny X.

2003-12-15T23:59:59.000Z

18

Photochemical doping of graphene oxide with nitrogen for photoluminescence enhancement  

SciTech Connect

Nitrogen-doped graphene oxide (NGO) was synthesized by irradiation of graphene oxide (GO) in NH{sub 3} atmosphere. NGO obtained by irradiation of GO for 10 min has high N content of 13.62 at. %. The photoluminescence (PL) properties of NGO were investigated. The results showed that compared with GO, NGO exhibits significant PL enhancement with a high enhancement ratio of approximately 1501.57%. It may attribute to the high content of amino-like N, which can effectively enhance PL of GO because of the amino conjugation effect.

Liu, Fuchi [Physics Department and Nanjing National Laboratory of Microstructures, Nanjing University, Nanjing 210093 (China) [Physics Department and Nanjing National Laboratory of Microstructures, Nanjing University, Nanjing 210093 (China); College of Physics and Technology, Guangxi Normal University, Guilin 541004 (China); Tang, Nujiang; Tang, Tao; Liu, Yuan; Feng, Qian; Zhong, Wei; Du, Youwei [Physics Department and Nanjing National Laboratory of Microstructures, Nanjing University, Nanjing 210093 (China)] [Physics Department and Nanjing National Laboratory of Microstructures, Nanjing University, Nanjing 210093 (China)

2013-09-16T23:59:59.000Z

19

Biofilter for removal of nitrogen oxides from contaminated gases under aerobic conditions  

DOE Patents (OSTI)

A biofilter for reducing concentrations of gaseous nitrogen oxides in a polluted gas comprises a porous organic filter bed medium disposed in a housing, the filter bed medium including a mixed culture of naturally occurring denitrifying bacteria for converting the nitrogen oxides to nitrogen gas, carbon dioxide, and water. A method of reducing concentrations of nitrogen oxides in polluted gas comprises conducting the polluted gas through the biofilter so that the denitrifying bacteria can degrade the nitrogen oxides. A preferred filter medium is wood compost, however composts of other organic materials are functional. Regulation of pH, moisture content, exogenous carbon sources, and temperature are described.

Apel, William A. (Idaho Falls, ID)

1998-01-01T23:59:59.000Z

20

Method for reducing nitrogen oxides in combustion effluents  

DOE Patents (OSTI)

Method for reducing nitrogen oxides (NO.sub.x) in the gas stream from the combustion of fossil fuels is disclosed. In a narrow gas temperature zone, NO.sub.x is converted to nitrogen by reaction with urea or ammonia with negligible remaining ammonia and other reaction pollutants. Specially designed injectors are used to introduce air atomized water droplets containing dissolved urea or ammonia into the gaseous combustion products in a manner that widely disperses the droplets exclusively in the optimum reaction temperature zone. The injector operates in a manner that forms droplet of a size that results in their vaporization exclusively in this optimum NO.sub.x -urea/ammonia reaction temperature zone. Also disclosed is a design of a system to effectively accomplish this injection.

Zauderer, Bert (Merion Station, PA)

2000-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "nitrogen oxides particulate" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

EFFECT OF NITROGEN OXIDE PRETREATMENTS ON ENZYMATIC HYDROLYSIS OF CELLULOSE  

E-Print Network (OSTI)

oxygen react to give nitrogen dioxide, which rapidly reactsis simultaneous, the nitrogen dioxide formed reacts withaccomplished by absorbing nitrogen dioxide in water, usually

Borrevik, R.K.

2011-01-01T23:59:59.000Z

22

Method for combined removal of mercury and nitrogen oxides from off-gas streams  

DOE Patents (OSTI)

A method for removing elemental Hg and nitric oxide simultaneously from a gas stream is provided whereby the gas stream is reacted with gaseous chlorinated compound to convert the elemental mercury to soluble mercury compounds and the nitric oxide to nitrogen dioxide. The method works to remove either mercury or nitrogen oxide in the absence or presence of each other.

Mendelsohn, Marshall H. (Downers Grove, IL); Livengood, C. David (Lockport, IL)

2006-10-10T23:59:59.000Z

23

Nitrogen oxide emissions from a kraft recovery furnace  

SciTech Connect

Nitrogen Oxide (NOx) emissions from a rebuilt kraft recovery furnace slightly exceeded the specified limit of 1.1 lb/ton (0.55 kg/metric ton) of black-liquor solids. Mill trials were undertaken to determine whether NOx emissions could be minimized by modifying furnace operation. NOx emissions increased when secondary air was shifted to tertiary ports. NOx emissions fell when the amounts of primary and total air were decreased, but this increased emissions of other pollutants. After demonstrating that best operation of the furnace could not meet the permit with an emissions limit that matched the furnace's performance at best operation.

Prouty, A.L.; Stuart, R.C. (James River Corp., Camas, WA (United States)); Caron, A.L. (NCASI West Coast Regional Office, Corvallis, OR (United States))

1993-01-01T23:59:59.000Z

24

Production of ozone and nitrogen oxides by laser filamentation  

SciTech Connect

We have experimentally measured that laser filaments in air generate up to 10{sup 14}, 3x10{sup 12}, and 3x10{sup 13} molecules of O{sub 3}, NO, and NO{sub 2}, respectively. The corresponding local concentrations in the filament active volume are 10{sup 16}, 3x10{sup 14}, and 3x10{sup 15} cm{sup -3}, and allows efficient oxidative chemistry of nitrogen, resulting in concentrations of HNO{sub 3} in the parts per million range. The latter forming binary clusters with water, our results provide a plausible pathway for the efficient nucleation recently observed in laser filaments.

Petit, Yannick; Henin, Stefano; Kasparian, Jerome; Wolf, Jean-Pierre [GAP Biophotonics, Universite de Geneve, 20 rue de l'Ecole de Medecine, CH1211 Geneve 4 (Switzerland)

2010-07-12T23:59:59.000Z

25

Reduction of nitrogen oxides in diesel exhaust: Prospects for use of synthesis gas  

Science Journals Connector (OSTI)

Already commercialized and some of the most promising technologies of nitrogen oxide reduction in automotive diesel exhaust are compared. The Boreskov Institute of Catalysis... x ...

V. A. Kirillov; E. I. Smirnov; Yu. I. Amosov; A. S. Bobrin…

2009-01-01T23:59:59.000Z

26

Reduction of nitrogen oxides with catalytic acid resistant aluminosilicate molecular sieves and ammonia  

DOE Patents (OSTI)

Noxious nitrogen oxides in a waste gas stream such as the stack gas from a fossil-fuel-fired power generation plant or other industrial plant off-gas stream is catalytically reduced to elemental nitrogen and/or innocuous nitrogen oxides employing ammonia as reductant in the presence of a zeolite catalyst in the hydrogen or sodium form having pore openings of about 3 to 10 A.

Pence, Dallas T. (Idaho Falls, ID); Thomas, Thomas R. (Idaho Falls, ID)

1980-01-01T23:59:59.000Z

27

Nitrogen Oxides (NOx), Why and How They are Controlled  

NLE Websites -- All DOE Office Websites (Extended Search)

Air Quality EPA 456/F-99-006R Air Quality EPA 456/F-99-006R Environmental Protection Planning and Standards November 1999 Agency Research Triangle Park, NC 27711 Air EPA-456/F-99-006R November 1999 Nitrogen Oxides (NOx), Why and How They Are Controlled Prepared by Clean Air Technology Center (MD-12) Information Transfer and Program Integration Division Office of Air Quality Planning and Standards U.S. Environmental Protection Agency Research Triangle Park, North Carolina 27711 ii DISCLAIMER This report has been reviewed by the Information Transfer and Program Integration Division of the Office of Air Quality Planning and Standards, U.S. Environmental Protection Agency and approved for publication. Approval does not signify that the contents of this report reflect the views and policies of the U.S. Environmental Protection Agency. Mention of trade

28

Technology innovations and experience curves for nitrogen oxides control technologies  

SciTech Connect

This paper reviews the regulatory history for nitrogen oxides (NOx) pollutant emissions from stationary sources, primarily in coal-fired power plants. Nitrogen dioxide (NO{sub 2}) is one of the six criteria pollutants regulated by the 1970 Clean Air Act where National Ambient Air Quality Standards were established to protect public health and welfare. Patent data are used to show that in the cases of Japan, Germany, and the United States, innovations in NOx control technologies did not occur until stringent government regulations were in place, thus 'forcing' innovation. It is demonstrated that reductions in the capital and operation and maintenance (O&M) costs of new generations of high-efficiency NOx control technologies, selective catalytic reduction (SCR), are consistently associated with the increasing adoption of the control technology: the so-called learning-by-doing phenomena. The results show that as cumulative world coal-fired SCR capacity doubles, capital costs decline to {approximately} 86% and O&M costs to 58% of their original values. The observed changes in SCR technology reflect the impact of technological advance as well as other factors, such as market competition and economies of scale. 38 refs., 10 figs., 3 tabs.

Sonia Yeh; Edward S. Rubin; Margaret R. Taylor; David A. Hounshell [U.S. Environmental Protection Agency, Research Triangle Park, NC (United States). National Risk Management Research Laboratory, Office of Research and Development,

2005-12-15T23:59:59.000Z

29

Chromatographic Determination of Total Nitrogen Following the Kjeldahl Oxidation  

Science Journals Connector (OSTI)

......23745 (1986). 3. B.M. Jones, and C.G. Daughton. Chemiluminescence vs. Kjeldahl determination of nitrogen in oil shale retort waters and organo- nitrogen compounds. Anal. Chem. 57: 232025 (1985). 4. B.T. Croll, T. Tomlinson......

Serban Moldoveanu

1988-01-01T23:59:59.000Z

30

Method for Detection of Microorganisms That Produce Gaseous Nitrogen Oxides  

Science Journals Connector (OSTI)

...with 02-free nitrogen; the tubes were...dishes to reduce water evaporation...Detection of gas producers. Culture...conductivity detector; nitrogen was used as the...Low-pressure solubility of gases in liquid water. Chem. Rev...

Gary E. Jenneman; Anne D. Montgomery; Michael J. McInerney

1986-04-01T23:59:59.000Z

31

Methods of reducing emissions of nitrogen oxides at thermal power plants burning solid domestic waste  

Science Journals Connector (OSTI)

Essentially all the major methods of reducing the emissions of nitrogen oxides from flue gases employed in power generation have been tested on plants in Moscow which burn solid domestic waste for production of h...

A. N. Tugov; V. F. Moskvichev

2009-01-01T23:59:59.000Z

32

Calculation of the emission of nitrogen oxides in electric resistance heating furnaces  

Science Journals Connector (OSTI)

The present paper is devoted to the least studied topic in the field of use of modern electric heating equipment, namely, pollution of the atmosphere by nitrogen oxides and reduction of the intensity of this e...

A. V. Aksenov; V. A. Belyakov; Z. G. Sadykova

1998-02-01T23:59:59.000Z

33

Combustor for fine particulate coal  

DOE Patents (OSTI)

A particulate coal combustor with two combustion chambers is provided. The first combustion chamber is toroidal; air and fuel are injected, mixed, circulated and partially combusted. The air to fuel ratio is controlled to avoid production of soot or nitrogen oxides. The mixture is then moved to a second combustion chamber by injection of additional air where combustion is completed and ash removed. Temperature in the second chamber is controlled by cooling and gas mixing. The clean stream of hot gas is then delivered to a prime mover. 4 figs.

Carlson, L.W.

1988-01-26T23:59:59.000Z

34

Combustor for fine particulate coal  

DOE Patents (OSTI)

A particulate coal combustor with two combustion chambers is provided. The first combustion chamber is toroidal; air and fuel are injected, mixed, circulated and partially combusted. The air to fuel ratio is controlled to avoid production of soot or nitrogen oxides. The mixture is then moved to a second combustion chamber by injection of additional air where combustion is completed and ash removed. Temperature in the second chamber is controlled by cooling and gas mixing. The clean stream of hot gas is then delivered to a prime mover.

Carlson, Larry W. (Oswego, IL)

1988-01-01T23:59:59.000Z

35

Energy cost improvement of the nitrogen oxides synthesis in a low pressure plasma  

E-Print Network (OSTI)

of XIXth century, the synthesis of nitrogen oxides by an electric discharge through the air has been a microwave discharge. The total pressure is equal to 50 torr. The optimal value of energy consumption, equal with the industrial process used at present, and by 78 % in comparison with those obtained with a plasmajet arc

Paris-Sud XI, Université de

36

Nitrogen oxides reduction by staged combustion of LCV gas  

E-Print Network (OSTI)

to the high nitrogen content (1-2%) of the agricultural wastes, burning of the LCV gas derived from them can result in NO?emissions in excess of 2000 ppm. NO?emissions during combustion of LCV gas derived from gasification of cotton gin trash have been.... Wayne A. LePori for serving on my committee and for the advice and time he offer me. His experience on gasification and combustion of LCV gas was an invaluable source. I appreciate Dr. Mario A. Colaluca for serving on my committee and for his help...

Cabrera Sixto, Jose Manuel

2012-06-07T23:59:59.000Z

37

Tunneling oxide engineering by ion implantation of nitrogen for 3D vertical silicon pillar SONOS flash memory  

Science Journals Connector (OSTI)

The electrical characteristics of silicon-oxide-nitride-oxide-silicon (SONOS) flash memory with a 3D vertical silicon pillar structure were studied. As an alternative method for the formation of the tunneling oxide, nitrogen ion implantation was applied to thermally grown pure silicon dioxide with a low energy (5 keV). The devices show significant improvement in the erase characteristics compared to conventional tunneling oxide. Secondary ion mass spectrometry was used to analyze the nitrogen distribution within tunnel oxide, and the improved erase properties can be attributed to the incorporation of about 4.8% nitrogen (2 × 1021 atoms/cm3) into the tunnel oxide formed by nitrogen ion implantation.

Jae-Sub Oh; Seong-Dong Yang; Sang-Youl Lee; Young-Su Kim; Min-Ho Kang; Sung-Kyu Lim; Hi-Deok Lee; Ga-Won Lee

2013-01-01T23:59:59.000Z

38

Oxidation of heterocyclic nitrogen yields to nitroheterocycles. [Nitrofurazans  

SciTech Connect

In the process of finding new routes to synthesize nitrofurazans the investigators compared the oxidation of a sulfilimide and a phosphine imine derived from 3-amino-4-(chlorophenyl)furazan (1). The sulfilimine, 3-(4-chlorophenyl)-4-dimethyl-sulfiliminofurazan (2), was prepared by treating 1 with dimethyl sulfide ditriflate. Oxidation of 1 with peroxytrifluoroacetic acid (ptfa) in dichloromethane gave a mixture that was chromatographed to give 3-(4-chlorophenyl)-4- nitro-furazan (5) in 11% yield and azoxy(4-chlorophenylfurazan) (6) in 32% yield. Under the same conditions, 2 gave a 96% yield of 5 with no trace of 6. Oxidation of diaminofurazan (7) with ptfa gives 3-amino-4-nitrofurazan (8), which was converted to the sulfilimine. Treatment of the sulfilimine with anhydrous ptfa in dichloromethane gave a solution that contained dimethyl sulfone according to /sup 13/C-NMR analysis, but no nitrocarbon could be detected. However, the /sup 14/N-NMR spectrum contained a very sharp singlet with a width at half-height of 19 Hz and a chemical shift almost identical to that of 5. Thus, it appears that we may have formed dinitrofurazan in solution, but we have not been able to isolate it in pure form as yet. 10 refs., 4 figs.

Coburn, M.D.

1985-01-01T23:59:59.000Z

39

Spatial and diurnal variability in reactive nitrogen oxide chemistry as reflected in the isotopic composition of atmospheric nitrate  

E-Print Network (OSTI)

exchange between gas-phase precursors and variability in reactive nitrogen sources. These findings product of NOx in the atmosphere. Due to its exceptionally high solubility in water, nitrate is rapidly deSpatial and diurnal variability in reactive nitrogen oxide chemistry as reflected in the isotopic

40

Combustion method for simultaneous control of nitrogen oxides and products of incomplete combustion  

SciTech Connect

A method is described for combusting material with controlled generation of both nitrogen oxides and products of incomplete combustion comprising: (A) combusting material in a first combustion zone to produce gaseous exhaust containing products of incomplete combustion and products of complete combustion; (B) passing the gaseous exhaust from the first combustion zone into a second combustion zone having a width and an axial direction; (C) injecting through a lance with an orientation substantially parallel to said axial direction at least one stream of oxidant, without fuel, having a diameter less than 1/100 of the width of the second combustion zone and having an oxygen concentration of at least 30% into the second combustion zone at a high velocity of at least 300 feet per second; (D) aspirating products of incomplete combustion into the high velocity oxidant; (E) combusting products of incomplete combustion aspirated into the high velocity oxidant with high velocity oxidant within the second combustion zone to carry out a stable combustion by the mixing of the aspirated products of incomplete combustion with the high velocity oxidant; and (F) spreading out the combustion reaction by aspiration of products of complete combustion into the oxidant, said products of complete combustion also serving as a heat sink, to inhibit NO[sub x] formation.

Ho, Min-Da.

1993-05-25T23:59:59.000Z

Note: This page contains sample records for the topic "nitrogen oxides particulate" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Exposure information in environmental health research: Current opportunities and future directions for particulate matter, ozone, and toxic air pollutants  

E-Print Network (OSTI)

fine particulates and nitrogen dioxide in the elderly withS.and Jerrett M. Nitrogen dioxide prediction in Southernto particles and nitrogen dioxide in Santiago, Chile.

McKone, Thomas E.

2008-01-01T23:59:59.000Z

42

KINETICS OF OXIDATION OF AQUEOUS SULFUR(IV) BY NITROGEN DIOXIDE YIN-NAN LEE AND STEPHEN E. SCHWARTZ  

E-Print Network (OSTI)

, reagent gas solubilities, mass trans- fer, stoichiometry, and reaction rate were not systematicallyKINETICS OF OXIDATION OF AQUEOUS SULFUR(IV) BY NITROGEN DIOXIDE YIN-NAN LEE AND STEPHEN E. SCHWARTZ for the oxidation of these compounds and their incorpo- ration into atmospheric liquid water are not fully

Schwartz, Stephen E.

43

Direct deposition of aluminum oxide gate dielectric on graphene channel using nitrogen plasma treatment  

SciTech Connect

Deposition of high-quality dielectric on a graphene channel is an essential technology to overcome structural constraints for the development of nano-electronic devices. In this study, we investigated a method for directly depositing aluminum oxide (Al{sub 2}O{sub 3}) on a graphene channel through nitrogen plasma treatment. The deposited Al{sub 2}O{sub 3} thin film on graphene demonstrated excellent dielectric properties with negligible charge trapping and de-trapping in the gate insulator. A top-gate-structural graphene transistor was fabricated using Al{sub 2}O{sub 3} as the gate dielectric with nitrogen plasma treatment on graphene channel region, and exhibited p-type transistor characteristics.

Lim, Taekyung; Kim, Dongchool; Ju, Sanghyun [Department of Physics, Kyonggi University, Suwon, Gyeonggi-Do 443-760 (Korea, Republic of)

2013-07-01T23:59:59.000Z

44

Chlorine activation indoors and outdoors via surface-mediated reactions of nitrogen oxides with hydrogen chloride.  

E-Print Network (OSTI)

complexes between nitrogen dioxide, nitric acid, nitrous1992) Indoor ozone and nitrogen dioxide: A potential pathwaybed of SiO 2 pellets. Nitrogen dioxide is introduced from a

2009-01-01T23:59:59.000Z

45

Air Quality Responses to Changes in Black Carbon and Nitrogen Oxide Emissions  

E-Print Network (OSTI)

D. , (2008a). Carbonyl and nitrogen dioxide emissions fromstudy of indoor nitrogen dioxide levels and respiratoryand modeled nitrogen dioxide (NO 2 ) concentrations. All

Millstein, Dev

2009-01-01T23:59:59.000Z

46

Nitrogen oxide  

E-Print Network (OSTI)

quality regulations may not effectively target a large source of fine, organic particle pollutants that contribute to hazy skies and poor air quality over the Los Angeles region. See also:

Tropospheric Ozone

47

Field emission effects of nitrogenated carbon nanotubes on chlorination and oxidation  

SciTech Connect

With reference to our recent reports [Appl. Phys. Lett. 90, 192107 (2007); Appl. Phys. Lett. 91, 202102 (2007)] about the electronic structure of chlorine treated and oxygen-plasma treated nitrogenated carbon nanotubes (N-CNTs), here we studied the electron field emission effects on chlorination (N-CNT:Cl) and oxidation (N-CNT:O) of N-CNT. A high current density (J) of 15.0 mA/cm{sup 2} has been achieved on chlorination, whereas low J of 0.0052 mA/cm{sup 2} is observed on oxidation compared to J=1.3 mA/cm{sup 2} for untreated N-CNT at an applied electric field E{sub A} of {approx}1.9 V/{mu}m. The turn-on electric field (E{sub TO}) was {approx}0.875. The 1.25 V/{mu}m was achieved for N-CNT:Cl and N-CNT:O, respectively, with respect to E{sub TO}=1.0 V/{mu}m for untreated one. These findings are due to the formation of different bonds with carbon and nitrogen in the N-CNT during the process of chlorine (oxygen)-plasma treatment by the charge transfer, or else that changes the density of free charge carriers and hence enhances (reduces) the field emission properties of N-CNTs:Cl (N-CNTs:O)

Ray, S. C.; Palnitkar, U.; Pao, C. W.; Tsai, H. M.; Pong, W. F.; Lin, I-N. [Department of Physics, Tamkang University, Tamsui 251, Taiwan (China); Papakonstantinou, P. [NRI, School of Electrical and Mechanical Engineering, University of Ulster at Jordanstown, Newtownabbey, County Antrim BT37OQB, Northern Ireland (United Kingdom); Ganguly, Abhijit; Chen, L. C. [Center for Condensed Matter Sciences, National Taiwan University, Taipei 106, Taiwan (China); Chen, K. H. [Institute of Atomic and Molecular Sciences, Academia Sinica, Taipei 106, Taiwan (China)

2008-09-15T23:59:59.000Z

48

DETERMINATION OF PARTICULATE ORGANIC NITROGEN  

Science Journals Connector (OSTI)

Energy Commission Contract No. AT ( 1 l-l ) -34, ... ethanol. 8. 50% ethanol. Filtration of sample. Sample volumes generally range from. 100 ml for rich coastal ...

2000-02-08T23:59:59.000Z

49

DEVELOPMENT OF IMPROVED CATALYSTS FOR THE SELECTIVE CATALYTIC REDUCTION OF NITROGEN OXIDES WITH HYDROCARBONS  

SciTech Connect

Significant work has been done by the investigators on the cerium oxide-copper oxide based sorbent/catalysts for the combined removal of sulfur and nitrogen oxides from the flue gases of stationary sources. A relatively wide temperature window was established for the use of alumina-supported cerium oxide-copper oxide mixtures as regenerable sorbents for SO{sub 2} removal. Preliminary evaluation of these sorbents as catalysts for the selective reduction of NO{sub x} gave promising results with ammonia, but indicated low selectivity when methane was used as the reductant. Since the replacement of ammonia by another reductant is commercially very attractive, in this project, four research components will be undertaken. The investigation of the reaction mechanism, the first component, will help in the selection of promoters to improve the catalytic activity and selectivity of the sorbents in the SCR with methane. This will result in new catalyst formulations (second component). If this research is successful, the combined SO{sub 2}-NO{sub x} removal process based on alumina-supported copper oxide-ceria sorbent/catalysts will become very attractive for commercial applications. The objective of the third component of the project is to develop an alternative SCR process using another inexpensive fuel, residual fuel oil, instead of natural gas. This innovative proposal is based on very scant evidence concerning the good performance of coked catalysts in the selective reduction of NO and if proven to work the process will certainly be commercially viable. The fourth component of the project involves our industrial partner TDA Research, and the objective is to evaluate long-term stability and durability of the prepared sorbent/catalysts. In the first year of the project, the catalysts were investigated by the temperature-programmed reduction (TPR) technique. The results from TPR indicated that the interaction with support appears to promote reduction at lower temperatures. Copper oxide in excess of monolayer coverage reduces at temperatures close to the reduction temperature of the unsupported copper oxide. Increased dispersion increases the support effect. Low activity of ceria in NO reduction may be due to its resistance to reduction at low temperatures.

Dr. Ates Akyurtlu; Dr. Jale F. Akyurtlu

2001-05-31T23:59:59.000Z

50

Eddy-covariance observations of the atmosphere-biosphere exchange of nitrogen oxides  

E-Print Network (OSTI)

and Kesselmeier, J. : Nitrogen dioxide (NO 2 ) uptake byM. : Leaf uptake of nitrogen dioxide (NO 2 ) in a tropicalMorikawa, H. : Atmospheric nitrogen dioxide gas is a plant

Min, Kyung-Eun

2012-01-01T23:59:59.000Z

51

NETL: News Release - Projects Selected to Study Coal Plant Particulate  

NLE Websites -- All DOE Office Websites (Extended Search)

5, 2004 5, 2004 Projects Selected to Study Coal Plant Particulate Matter, Human Health PITTSBURGH, PA - The Department of Energy has selected three projects to help determine whether fine particulates emitted from coal-fired power plants affect human health, and which components of the particulates may be most problematic. Past studies have established that particulate matter smaller than 2.5 microns in diameter from all sources does affect human health, but there is scant information to provide a link between PM2.5 emitted specifically from coal plants and cardiac or respiratory health problems in humans. PM2.5 refers to particles-invisible to the eye-no more than 1/30th of the width of a human hair Coal plants emit only small quantities of "primary" PM2.5 (e.g., fly ash) because all plants have high-efficiency particulate-collection devices. However, coal plants are responsible for a great deal of "secondary" PM2.5, which forms in the atmosphere from emissions of sulfur dioxide (SO2) and nitrogen oxides (NOx). Data collected in the new studies will be used to help design standards reviews and to devise strategies for controlling power plant emissions of PM2.5, SO2, and NOx.

52

Chemisorption of carbon monoxide and nitrogen oxides on highly dispersed technetium  

SciTech Connect

The purpose of this work is to study, in infrared spectroscopy, the surface compounds formed on adsorption of carbon monoxide and nitrogen oxides on Tc/SiO/sub 2/. The samples were prepared by soaking Aerosil with aqueous solution of ammonium pertechnetate containing 10 wt.% of Tc. Reduction with hydrogen to the metal was carried out at 700-800/sup 0/C. Results indicated that chemisorption of CO on highly dispersed technetium gives rise to a single type of linear and several types of multicentered adsorption forms. Occurrence of bridge form of adsorbed CO was also suggested on the basis of the data on chemisorption stoichiometry. Formation of a structure characterizable by absorption at 1790 cm/sup -1/ may indicate, only after protracted analysis, that the surface of the technetium introduced gradually suffers significant rearrangement facilitating formation of this type of complexes.

Serebryakova, N.V.; Sokolova, N.P.; Spitsyn, V.S.

1982-08-01T23:59:59.000Z

53

Dissimilatory Metabolism of Nitrogen Oxides in Bacteria:Comparative Reconstruction of Transcriptional Networks  

SciTech Connect

Bacterial response to nitric oxide (NO) is of major importance since NO is an obligatory intermediate of the nitrogen cycle. Transcriptional regulation of the dissimilatory nitric oxides metabolism in bacteria is diverse and involves FNR-like transcription factors HcpR, DNR and NnrR, two-component systems NarXL and NarQP, NO-responsive activator NorR, and nitrite sensitive repressor NsrR. Using comparative genomics approaches we predict DNA-binding signals for these transcriptional factors and describe corresponding regulons in available bacterial genomes. Within the FNR family of regulators, we observed a correlation of two specificity-determining amino acids and contacting bases in corresponding DNA signal. Highly conserved regulon HcpR for the hybrid cluster protein and some other redox enzymes is present in diverse anaerobic bacteria including Clostridia, Thermotogales and delta-proteobacteria. NnrR and DNR control denitrification in alpha- and beta-proteobacteria, respectively. Sigma-54-dependent NorR regulon found in some gamma- and beta-proteobacteria contains various enzymes involved in the NO detoxification. Repressor NsrR, which was previously known to control only nitrite reductase operon in Nitrosomonas spp., appears to be the master regulator of the nitric oxides metabolism not only in most gamma- and beta-proteobacteria (including well-studied species like Escherichia coli), but also in Gram-positive Bacillus and Streptomyces species. Positional analysis and comparison of regulatory regions of NO detoxification genes allows us to propose the candidate NsrR-binding signal. The most conserved member of the predicted NsrR regulon is the NO-detoxifying flavohemoglobin Hmp. In enterobacteria, the regulon includes also two nitrite-responsive loci, nipAB (hcp-hcr) and nipC(dnrN), thus confirming the identity of the effector, i.e., nitrite. The proposed NsrR regulons in Neisseria and some other species are extended to include denitrification genes. As the result, we demonstrate considerable interconnection between various nitrogen-oxides-responsive regulatory systems for the denitrification and NO detoxification genes and evolutionary plasticity of this transcriptional network.

Rodionov, Dmitry A.; Dubchak, Inna L.; Arkin, Adam P.; Alm, EricJ.; Gelfand, Mikhail S.

2005-09-01T23:59:59.000Z

54

System and method for selective catalytic reduction of nitrogen oxides in combustion exhaust gases  

DOE Patents (OSTI)

A multi-stage selective catalytic reduction (SCR) unit (32) provides efficient reduction of NOx and other pollutants from about 50-550.degree. C. in a power plant (19). Hydrogen (24) and ammonia (29) are variably supplied to the SCR unit depending on temperature. An upstream portion (34) of the SCR unit catalyzes NOx+NH.sub.3 reactions above about 200.degree. C. A downstream portion (36) catalyzes NOx+H.sub.2 reactions below about 260.degree. C., and catalyzes oxidation of NH.sub.3, CO, and VOCs with oxygen in the exhaust above about 200.degree. C., efficiently removing NOx and other pollutants over a range of conditions with low slippage of NH.sub.3. An ammonia synthesis unit (28) may be connected to the SCR unit to provide NH.sub.3 as needed, avoiding transport and storage of ammonia or urea at the site. A carbonaceous gasification plant (18) on site may supply hydrogen and nitrogen to the ammonia synthesis unit, and hydrogen to the SCR unit.

Sobolevskiy, Anatoly; Rossin, Joseph A

2014-04-08T23:59:59.000Z

55

Catalytic activity of oxidized (combusted) oil shale for removal of nitrogen oxides with ammonia as a reductant in combustion gas streams, Part 2  

SciTech Connect

Oxidized oil shale from the combustor in the LLNL Hot-Recycled-Solids (HRS) oil shale retorting process has been found to be a catalyst for removing nitrogen oxides from laboratory gas streams using NH{sub 3} as a reductant. Oxidized Green River oil shale heated at 10{degree}C/min in an Ar/O{sub 2}/NO/NH{sub 3} mixture ({approximately}93%/6%/2000 ppM/4000 ppM) with a gas residence time of {approximately}0.6 sec removed NO between 250 and 500{degree}C, with maximum removal of 70% at {approximately}400{degree}C. Under isothermal conditions with the same gas mixture, the maximum NO removal was {approximately}64%. When CO{sub 2} was added to the gas mixture at {approximately}8%, the NO removal dropped to {approximately}50%. However, increasing the gas residence time to {approximately}1.2 sec, increased NO removal to 63%. Nitrogen balances of these experiments suggest selective catalytic reduction of NO is occurring using NH{sub 3} as the reductant. These results are not based on completely optimized process conditions, but indicate oxidized oil shale is an effective catalyst for NO removal from combustion gas streams using NH{sub 3} as the reductant. Parameters calculated for implementing oxidized oil shale for NO{sub x} remediation on the current HRS retort indicate an abatement device is practical to construct.

Reynolds, J.G.; Taylor, R.W.; Morris, C.J.

1993-01-04T23:59:59.000Z

56

Catalytic activity of oxidized (combusted) oil shale for removal of nitrogen oxides with ammonia as a reductant in combustion gas streams, Part 2  

SciTech Connect

Oxidized oil shale from the combustor in the LLNL Hot-Recycled-Solids (HRS) oil shale retorting process has been found to be a catalyst for removing nitrogen oxides from laboratory gas streams using NH[sub 3] as a reductant. Oxidized Green River oil shale heated at 10[degree]C/min in an Ar/O[sub 2]/NO/NH[sub 3] mixture ([approximately]93%/6%/2000 ppM/4000 ppM) with a gas residence time of [approximately]0.6 sec removed NO between 250 and 500[degree]C, with maximum removal of 70% at [approximately]400[degree]C. Under isothermal conditions with the same gas mixture, the maximum NO removal was [approximately]64%. When CO[sub 2] was added to the gas mixture at [approximately]8%, the NO removal dropped to [approximately]50%. However, increasing the gas residence time to [approximately]1.2 sec, increased NO removal to 63%. Nitrogen balances of these experiments suggest selective catalytic reduction of NO is occurring using NH[sub 3] as the reductant. These results are not based on completely optimized process conditions, but indicate oxidized oil shale is an effective catalyst for NO removal from combustion gas streams using NH[sub 3] as the reductant. Parameters calculated for implementing oxidized oil shale for NO[sub x] remediation on the current HRS retort indicate an abatement device is practical to construct.

Reynolds, J.G.; Taylor, R.W.; Morris, C.J.

1993-01-04T23:59:59.000Z

57

Reducing the contribution of the power sector to ground-level ozone pollution : an assessment of time-differentiated pricing of nitrogen oxide emissions  

E-Print Network (OSTI)

Nitrogen oxide (NOx) is a prevalent air pollutant across the United States and a requisite precursor for tropospheric (ground-level) ozone formation. Both pollutants significantly impact human health and welfare, so National ...

Craig, Michael T. (Michael Timothy)

2014-01-01T23:59:59.000Z

58

Nitrogen oxide stack sampling at the U.S. DOE Oak Ridge Y-12 Steam Plant  

SciTech Connect

On November 7, 1997, the EPA proposed a Nitrogen Oxides State Implementation Plan Call (NO{sub x} SIP Call) for 22 states in the Eastern US which included the state of Tennessee. This initial proposal was followed by proposed statewide NO{sub x} budgets in the May 11, 1998, Supplemental Notice of Proposed Rulemaking. In the development of the NO{sub x} SIP Call, EPA performed a number of air quality analyses and determined that NO{sub x} emissions from Tennessee should be reduced. Industrial boilers, turbines, stationary internal combustion engines, and cement manufacturing are the only non-electric generating unit sources for which reductions are assumed in the budget calculation. Emission reductions are required if specific source heat input capacity is greater than 250 million Btu per hour. The US Department of Energy (DOE) Oak Ridge Y-12 Steam Plant consists of four Wickes pulverized coal fired boilers each rated at a maximum heat input capacity of 298 million Btu per hour, and will therefore be impacted by these regulatory actions. Each boiler is equipped with two pulverizing mills. Coal or natural gas or a combination of these two fuels may be fired. This paper provides the results of NO{sub x} emission stack testing conducted June 15--21, 1999, on the Y-12 Steam Plant Boilers 1 and 2. Measurements of oxygen (O{sub 2}), carbon monoxide (CO), carbon dioxide (CO{sub 2}), and stack gas flow were also performed. Information gained from these stack tests will be used to determine NO{sub x} emission control strategies for the steam plant for compliance with future emission requirements resulting from the NO{sub x} SIP Call.

L.V. Gibson, jr.; M.P. Humphreys; J.M. Skinner

2000-03-01T23:59:59.000Z

59

Modeling of formaldehyde and nitrogen oxides from a proposed renewable energy biogas facility in Canada  

Science Journals Connector (OSTI)

The aim of this study was to use the CALPUFF modeling system an effective and reliable atmospheric modeling tool to predict the concentrations of formaldehyde (HCHO) and nitrogen oxides (NOx) released due to the combustion of biogas in the combined heat and power (CHP) engines from the Kawartha renewable energy generation facility at its proposed location in Ontario Canada. In this study HCHO and NOx were selected as the indicator and point source pollutants since they were the most significant products of biogas combustion emitted during the facility's normal operations (production of electricity and heat). The Lambert Conformal Conic projection coordinate system was implemented for the operation of the CALPUFF model. The proposed modeling scheme was coupled with both surface meteorological data (from 00:00 to 23:00) on an hourly basis and 12-h interval-based upper air meteorological data (from 00:00 to 12:00) to simulate the emission of these pollutants for the four seasonal Eastern Time meteorological conditions of winter (January 11–13 2013) spring (April 14–16 2013) summer (July 10–12 2013) and autumn (November 16–18 2013). The results from the CALPUFF dispersion model clearly demonstrated that the maximum 1-h average concentrations of both HCHO and NOx emitted from the combustion of biogas (composed of 60% CH4 and 40% CO2) in five CHP engines (operation load?=?100% maximum electricity generation capacity?=?9.8?MW) were found to be within the limits defined by Ontario Regulation 419/05.

2014-01-01T23:59:59.000Z

60

Solid State Electrochemical Sensors for Nitrogen Oxide (NOx) Detection in Lean Exhaust Gases  

E-Print Network (OSTI)

for Application in Solid Oxide Fuel Cells", (DoctoralImpedance of Solid Oxide Fuel Cell LSM/YSZ CompositeCathode materials of solid oxide fuel cells: a review”, J

Rheaume, Jonathan Michael

2010-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "nitrogen oxides particulate" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

A model cerium oxide matrix composite reinforced with a homogeneous dispersion of silver particulate - prepared using the glycine-nitrate process  

SciTech Connect

Recently a new method of ceramic brazing has been developed. Based on a two-phase liquid composed of silver and copper oxide, brazing is conducted directly in air without the need of an inert cover gas or the use of surface reactive fluxes. Because the braze displays excellent wetting characteristics on a number ceramic surfaces, including alumina, various perovskites, zirconia, and ceria, we were interested in investigating whether a metal-reinforced ceramic matrix composite (CMC) could be developed with this material. In the present study, two sets of homogeneously mixed silver/copper oxide/ceria powders were synthesized using a combustion synthesis technique. The powders were compacted and heat treated in air above the liquidus temperature for the chosen Ag-CuO composition. Metallographic analysis indicates that the resulting composite microstructures are extremely uniform with respect to both the size of the metallic reinforcement as well as its spatial distribution within the ceramic matrix. The size, morphology, and spacing of the metal particulate in the densified composite appears to be dependent on the original size and the structure of the starting combustion synthesized powders.

Weil, K. Scott; Hardy, John S.

2005-01-31T23:59:59.000Z

62

Evaluation of oxides of nitrogen emissions for the purpose of their transient regulation from a direct injection diesel engine  

Science Journals Connector (OSTI)

The concept of defining a regulatory standard for the maximum allowable emissions of oxides of nitrogen (NOx) from a heavy-duty diesel engine on an instantaneous basis is presented. The significance of this concept from a regulatory point of view is the possibility to realise a steady brake specific NOx emissions result independent of the test schedule used. The emissions of oxides of nitrogen from a state-of-the-art direct injection diesel engine have been examined on an integral as well as on an instantaneous basis over the Federal Test Procedure as well as over several other arbitrary transient cycles generated for this study. Three candidate standards of specific NOx emissions have been evaluated on a real-time, continuous basis. These include brake power specific, fuel mass specific, and carbon dioxide mass specific NOx emissions. Retaining the stock engine control module, the carbon dioxide specific emissions of NOx have been shown to be the most uniform, varying only by about 30% of its mean value regardless of the test schedule or engine operation. The instantaneous fuel specific NOx emissions are shown to be relatively less invariant and the least steady are the brake power specific emissions with a coefficient of variation of up to 200%. Advancing injection timing has been shown to have a wide range of authority over the specific emissions of oxides of nitrogen regardless of the units used, when operating at full load in the vicinity of peak torque speeds. The carbon dioxide specific NOx emissions have shown a linear dependence on the power specific emissions, independent of the examined operating conditions. The trade-off between better brake thermal efficiency, lower exhaust gas temperature at advanced timing and lower NOx emissions has also been shown to be independent of the units of the specific standard used.

Yasser Yacoub; Chris Atkinson

2001-01-01T23:59:59.000Z

63

Current emission trends for nitrogen oxides, sulfur dioxide, and volatile organic compounds by month and state: Methodology and results  

SciTech Connect

This report presents estimates of monthly sulfur dioxide (SO{sub 2}), nitrogen oxides (NO{sub x}), and nonmethane voltatile organic compound (VOC) emissions by sector, region, and state in the contiguous United States for the years 1975 through 1988. This work has been funded as part of the National Acid Precipitation Assessment Program`s Emissions and Controls Task Group by the US Department of Energy (DOE) Office of Fossil Energy (FE). The DOE project officer is Edward C. Trexler, DOE/FE Office of Planning and Environment.

Kohout, E.J.; Miller, D.J.; Nieves, L.A.; Rothman, D.S.; Saricks, C.L.; Stodolsky, F.; Hanson, D.A.

1990-08-01T23:59:59.000Z

64

Current emission trends for nitrogen oxides, sulfur dioxide, and volatile organic compounds by month and state: Methodology and results  

SciTech Connect

This report presents estimates of monthly sulfur dioxide (SO{sub 2}), nitrogen oxides (NO{sub x}), and nonmethane voltatile organic compound (VOC) emissions by sector, region, and state in the contiguous United States for the years 1975 through 1988. This work has been funded as part of the National Acid Precipitation Assessment Program's Emissions and Controls Task Group by the US Department of Energy (DOE) Office of Fossil Energy (FE). The DOE project officer is Edward C. Trexler, DOE/FE Office of Planning and Environment.

Kohout, E.J.; Miller, D.J.; Nieves, L.A.; Rothman, D.S.; Saricks, C.L.; Stodolsky, F.; Hanson, D.A.

1990-08-01T23:59:59.000Z

65

The effects of nitrogen oxides on cytochrome P-450 mediated mixed-function oxidations in mammalian lung  

E-Print Network (OSTI)

schema for toxic inhalation of NO2 10 General representation of the proposed steps involved in substrate hydroxylation by cyto- chrome P-450 mediated mixed-function oxida- tions 13 Schematic diagram of the Isolated and Per- fused Lung Apparatus 22... and biochemical functions of the lung is pre- sented in Table 1. This summary is followed by a schematic with a more complete representation of the toxic effects of N02 inhalation (Fig. 1). Nany of the biochemical effects of nitrogen dioxide on the lung...

Tucker, Leo Dean

2012-06-07T23:59:59.000Z

66

Chlorine activation indoors and outdoors via surface-mediated reactions of nitrogen oxides with hydrogen chloride  

Science Journals Connector (OSTI)

...also globally distributed, because NO formed in combustion processes is oxidized to NO2, HNO3, N2O5 and a variety of...also globally distributed, because NO formed in combustion processes is oxidized to NO(2), HNO(3), N(2)O...

Jonathan D. Raff; Bosiljka Njegic; Wayne L. Chang; Mark S. Gordon; Donald Dabdub; R. Benny Gerber; Barbara J. Finlayson-Pitts

2009-01-01T23:59:59.000Z

67

Catalytic activity of oxidized (combusted) oil shale for removal of nitrogen oxides with ammonia as a reductant in combustion gas streams, Part 1  

SciTech Connect

Oxidized oil shale from the combustor in the LLNL hot recycle solids oil shale retorting process has been studied as a catalyst for removing nitrogen oxides from laboratory gas streams using NH{sub 3} as areductant. Combusted Green River oil shale heated at 10{degrees}C/min in an Ar/O{sub 2}/NO/NH{sub 3} mixture ({approximately}93%/6%/2000 ppm/4000 ppm) with a gas residence time of {approximately}0.6 sec exhibited NO removal between 250 and 500{degrees}C, with maximum removal of 70% at {approximately}400{degrees}C. Under isothermal conditions with the same gas mixture, the maximum NO removal was found to be {approximately}64%. When CO{sub 2} was added to the gas mixture at {approximately}8%, the NO removal dropped to {approximately}50%. However, increasing the gas residence time to {approximately}1.2 sec, increased NO removal to 63%. These results are not based on optimized process conditions, but indicate oxidized (combusted) oil shale is an effective catalyst for NO removal from combustion gas streams using NH{sub 3} as the reductant.

Reynolds, J.G.; Taylor, R.W.; Morris, C.J.

1992-06-10T23:59:59.000Z

68

COMBUSTION SOURCES OF UNREGULATED GAS PHASE NITROGENEOUS SPECIES  

E-Print Network (OSTI)

OXIDES OF NITROGEN Nitrogen Dioxide (N0 2) Nitrous Oxide (NFigure 7. Emissions of nitrogen dioxide from gas turbines (by AiResearch(8)) . Nitrogen dioxide emissions from a

Matthews, Ronald D.

2013-01-01T23:59:59.000Z

69

Zevenhoven & Kilpinen NITROGEN 13.4.2002 4-1 Chapter 4 Nitrogen  

E-Print Network (OSTI)

of the nitric oxide is oxidized to nitrogen dioxide, so the environmental effects of emissions of bothZevenhoven & Kilpinen NITROGEN 13.4.2002 4-1 Chapter 4 Nitrogen 4.1 Introduction Probably the most damaging of the hazardous nitrogen compounds formed during combustion are nitric oxide (NO) and nitrogen

Laughlin, Robert B.

70

INVESTIGATION OF MIXED METAL SORBENT/CATALYSTS FOR THE SIMULTANEOUS REMOVAL OF SULFUR AND NITROGEN OXIDES  

SciTech Connect

Simultaneous removal of SO{sub 2} and NO{sub x} using a regenerable solid sorbent will constitute an important improvement over the use of separate processes for the removal of these two pollutants from stack gases and possibly eliminate several shortcomings of the individual SO{sub 2} and NO{sub x} removal operations. The work done at PETC and the DOE-funded investigation of the investigators on the sulfation and regeneration of alumina-supported cerium oxide sorbents have shown that they can perform well at relatively high temperatures (823-900 K) as regenerable desulfurization sorbents. Survey of the recent literature shows that addition of copper oxide to ceria lowers the sulfation temperature of ceria down to 773 K, sulfated ceria-based sorbents can function as selective SCR catalysts even at elevated temperatures, SO{sub 2} can be directly reduced to sulfur by CO on CuO-ceria catalysts, and ceria-based catalysts may have a potential for selective catalytic reduction of NO{sub x} by methane. These observations indicate a possibility of developing a ceria-based sorbent/catalyst which can remove both SO{sub 2} and NO{sub x} from flue gases within a relatively wide temperature window, produce significant amounts of elemental sulfur during regeneration, and use methane for the selective catalytic reduction of NO{sub x}. The objective of this research is to conduct kinetic and parametric studies of the selective catalytic reduction of NO{sub x} with NH{sub 3} and CH{sub 4} over alumina-supported cerium oxide and copper oxide-cerium oxide sorbent/catalysts; investigate SO{sub 2} removal at lower temperatures by supported copper oxide-cerium oxide sorbents; and investigate the possibility of elemental sulfur production during regeneration with CO or with CH{sub 4}-air mixtures.

Ates Akyurtlu; Jale F. Akyurtlu

2000-04-10T23:59:59.000Z

71

INVESTIGATION OF MIXED METAL SORBENT/CATALYSTS FOR THE SIMULTANEOUS REMOVAL OF SULFUR AND NITROGEN OXIDES  

SciTech Connect

Simultaneous removal of SO{sub 2} and NO{sub x} using a regenerable solid sorbent will constitute an important improvement over the use of separate processes for the removal of these two pollutants from stack gases and possibly eliminate several shortcomings of the individual SO{sub 2} and NO{sub x} removal operations. The work done at PETC and the DOE-funded research of the investigators on the sulfation and regeneration of alumina-supported cerium oxide sorbents have shown that they can perform well at relatively high temperatures (823-900 K) as regenerable desulfurization sorbents. Survey of the recent literature shows that addition of copper oxide to ceria lowers the sulfation temperature of ceria down to 773 K, sulfated ceria-based sorbents can function as selective SCR catalysts even at elevated temperatures, SO{sub 2} can be directly reduced to sulfur by CO on CuO-ceria catalysts, and ceria-based catalysts may have a potential for selective catalytic reduction of NO{sub x} by methane. These observations indicate a possibility of developing a ceria-based sorbent/catalyst which can remove both SO{sub 2} and NO{sub x} from flue gases within a relatively wide temperature window, produce significant amounts of elemental sulfur during regeneration, and use methane for the selective catalytic reduction of NO{sub x}. The objective of this research is to conduct kinetic and parametric studies of the selective catalytic reduction of NO{sub x} with NH{sub 3} and CH{sub 4} over alumina-supported cerium oxide and copper oxide-cerium oxide sorbent/catalysts; investigate SO{sub 2} removal at lower temperatures by supported copper oxide-cerium oxide sorbents; and investigate the possibility of elemental sulfur production during regeneration with CO or with CH{sub 4} air mixtures.

Ates Akyurtlu; Jale F. Akyurtlu

1999-11-30T23:59:59.000Z

72

Investigation of mixed metal sorbent/catalysts for the simultaneous removal of sulfur and nitrogen oxides  

SciTech Connect

Simultaneous removal of SO{sub 2} and NO{sub x} using a regenerable solid sorbent will constitute an important improvement over the use of separate processes for the removal of these two pollutants from stack gases and possibly eliminate several shortcomings of the individual SO{sub 2} and NO{sub x} removal operations. The work done at PETC and the DOE-funded investigation of the investigators on the sulfation and regeneration of alumina-supported cerium oxide sorbents have shown that they can perform well at relatively high temperatures (823-900 K) as regenerable desulfurization sorbents. Survey of the recent literature shows that addition of copper oxide to ceria lowers the sulfation temperature of ceria down to 773 K, sulfated ceria-based sorbents can function as selective SCR catalysts even at elevated temperatures, SO{sub 2} can be directly reduced to sulfur by CO on CuO-ceria catalysts, and ceria-based catalysts may have a potential for selective catalytic reduction of NO{sub x} by methane. These observations indicate a possibility of developing a ceria-based sorbent/catalyst which can remove both SO{sub 2} and NO{sub x} from flue gases within a relatively wide temperature window, produce significant amounts of elemental sulfur during regeneration, and use methane for the selective catalytic reduction of NO{sub x}. The objective of this research is to conduct kinetic and parametric studies of the selective catalytic reduction of NO{sub x} with NH{sub 3} and CH{sub 4} over alumina-supported cerium oxide and copper oxide-cerium oxide sorbent/catalysts; investigate SO{sub 2} removal at lower temperatures by supported copper oxide-cerium oxide sorbents; and investigate the possibility of elemental sulfur production during regeneration with CO or with CH{sub 4}-air mixtures.

Akyurtlu, A.; Akyurtlu, J.F.

1999-03-31T23:59:59.000Z

73

Innovative Clean Coal Technology (ICCT): 500 MW demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from coal-fired boilers. Technical progress report, fourth quarter 1991  

SciTech Connect

This quarterly report discusses the technical progress of an Innovative Clean Coal Technology (ICCT) demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from coal-fired boilers. The project is being conducted at Georgia Power Company`s Plant Hammond Unit 4 located near Rome, Georgia. The primary goal of this project is the characterization of the low NO{sub x} combustion equipment through the collection and analysis of long-term emissions data. A target of achieving fifty percent NO{sub x} reduction using combustion modifications has been established for the project. The project provides a stepwise retrofit of an advanced overfire air (AOFA) system followed by low NO{sub x} burners (LNB). During each test phase of the project, diagnostic, performance, long-term, and verification testing will be performed. These tests are used to quantify the NO{sub x} reductions of each technology and evaluate the effects of those reductions on other combustion parameters such as parameters such as particulate characteristics and boiler efficiency.

Not Available

1992-04-21T23:59:59.000Z

74

Innovative Clean Coal Technology (ICCT): 500 MW demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from coal-fired boilers. Technical progress report, Second quarter 1992  

SciTech Connect

This quarterly report discusses the technical progress of an Innovative Clean Coal Technology (ICCT) demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (No{sub x}) emissions from coal-fired boilers. The project is being conducted at Georgia Power Company`s Plant Hammond Unit 4 located near Rome, Georgia. The primary goal of this project is the characterization of the low NO{sub x} combustion equipment through the collection and analysis of long-term emissions data. A target of achieving fifty percent NO{sub x} reduction using combustion modifications has been established for the project. The project provides a stepwise retrofit of an advanced overfire air (AOFA) system followed by low NO{sub x} burners (LNB). During each test phase of the project, diagnostic, performance, long-term, and verification testing will be performed. These tests are used to quantify the NO{sub x} reductions of each technology and evaluate the effects of those reductions on other combustion parameters such as particulate characteristics and boiler efficiency.

Not Available

1992-08-24T23:59:59.000Z

75

Innovative Clean Coal Technology (ICCT): 500 MW demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from coal-fired boilers. Technical progress report, First quarter 1992  

SciTech Connect

This quarterly report discusses the technical progress of an Innovative Clean Coal Technology (ICCT) demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from coal-fired boilers. The project is being conducted at Georgia Power Company`s Plant Hammond Unit 4 located near Rome, Georgia. The primary goal of this project is the characterization of the low NO{sub x} combustion equipment through the collection and analysis of long-term emissions data. A target of achieving fifty percent NO{sub x} reduction using combustion modifications has been established for the project. The project provides a stepwise retrofit of an advanced overfire air (AOFA) system followed by low NO{sub x} burners (LNB). During each test phase of the project, diagnostic, performance, long-term, and verification testing will be performed. These tests are used to quantify the NO{sub x} reductions of each technology and evaluate the effects of those reductions on other combustion parameters such as particulate characteristics and boiler efficiency.

Not Available

1992-12-31T23:59:59.000Z

76

Innovative Clean Coal Technology (ICCT): 500 MW demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NO[sub x]) emissions from coal-fired boilers  

SciTech Connect

This quarterly report discusses the technical progress of an Innovative Clean Coal Technology (ICCT) demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (No[sub x]) emissions from coal-fired boilers. The project is being conducted at Georgia Power Company's Plant Hammond Unit 4 located near Rome, Georgia. The primary goal of this project is the characterization of the low NO[sub x] combustion equipment through the collection and analysis of long-term emissions data. A target of achieving fifty percent NO[sub x] reduction using combustion modifications has been established for the project. The project provides a stepwise retrofit of an advanced overfire air (AOFA) system followed by low NO[sub x] burners (LNB). During each test phase of the project, diagnostic, performance, long-term, and verification testing will be performed. These tests are used to quantify the NO[sub x] reductions of each technology and evaluate the effects of those reductions on other combustion parameters such as particulate characteristics and boiler efficiency.

Not Available

1992-08-24T23:59:59.000Z

77

Innovative Clean Coal Technology (ICCT): 500 MW demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NO sub x ) emissions from coal-fired boilers  

SciTech Connect

This quarterly report discusses the technical progress of an Innovative Clean Coal Technology (ICCT) demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from coal-fired boilers. The project is being conducted at Georgia Power Company's Plant Hammond Unit 4 located near Rome, Georgia. The primary goal of this project is the characterization of the low NO{sub x} combustion equipment through the collection and analysis of long-term emissions data. A target of achieving fifty percent NO{sub x} reduction using combustion modifications has been established for the project. The project provides a stepwise retrofit of an advanced overfire air (AOFA) system followed by low NO{sub x} burners (LNB). During each test phase of the project, diagnostic, performance, long-term, and verification testing will be performed. These tests are used to quantify the NO{sub x} reductions of each technology and evaluate the effects of those reductions on other combustion parameters such as parameters such as particulate characteristics and boiler efficiency.

Not Available

1992-04-21T23:59:59.000Z

78

Innovative Clean Coal Technology (ICCT): 180 MW demonstration of advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from coal-fired boilers. Fourth quarterly technical progress report, [October--December, 1992  

SciTech Connect

This quarterly report discusses the technical progress of a U. S. Department of Energy (DOE) Innovative Clean Coal Technology (ICCT) Project demonstrating advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NOx) emissions from a coal-fired boiler. The project is being conducted at Gulf Power Company`s Plant Lansing Smith Unit 2 located near Panama City, Florida. The primary objective of this demonstration is to determine the long-term effects of commercially available tangentially-fired low NOx combustion technologies on NOx emissions and boiler performance. A target of achieving fifty percent NOx reduction using combustion modifications has been established for the project. The stepwise approach that is being used to evaluate the NOx control technologies requires three plant outages to successively install the test instrumentation and the different levels of the low NOx concentric firing system (LNCFS). Following each outage, a series of four groups of tests are performed. These are (1) diagnostic, (2) performance, (3) long-term, and (4) verification. These tests are used to quantify the NOx reductions of each technology and evaluate the effects of those reductions on other combustion parameters such as particulate characteristics and boiler efficiency. During this quarter, tests of the LNCFS Level III system were conducted to determine the effect that fuel fineness has on NOx emissions and unburned carbon levels. Results showed that changing the fineness of the fuel has almost no effect on NOx emissions; however, unburned carbon levels can be reduced significantly by increasing fuel fineness.

Not Available

1992-12-31T23:59:59.000Z

79

Innovative Clean Coal Technology (ICCT): 180 MW demonstration of advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NO[sub x]) emissions from coal-fired boilers  

SciTech Connect

This quarterly report discusses the technical progress of a US Department of Energy (DOE) Innovative Clean Coal Technology (ICCT) Project demonstrating advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NO[sub x]) emissions from a coal-fired boiler. The project is being conducted at Gulf Power Company's Plant Lansing Smith Unit 2 located near Panama City, Florida. The primary objective of this demonstration is to determine the long-term effects of commercially available tangentially-fired low NO[sub x] combustion technologies on NO[sub x] emissions and boiler performance. A target of achieving fifty percent NO[sub x] reduction using combustion modifications has been established for the project. The stepwise approach that is being used to evaluate the NO[sub x] control technologies requires three plant outages to successively install the test instrumentation and the different levels of the low NO[sub x] concentric firing system (LNCFS). Following each outage, a series of four groups of tests are performed. These are (1) diagnostic, (2) performance, (3) long-term, and (4) verification. These tests are used to quantify the NO[sub x] reductions of each technology and evaluate the effects of those reductions on other combustion parameters such as particulate characteristics and boiler efficiency. This technical progress report presents the LNCFS Level I short-term data collected during this quarter. In addition, a comparison of all the long-term emissions data that have been collected to date is included.

Not Available

1992-11-25T23:59:59.000Z

80

Innovative Clean Coal Technology (ICCT): 180 MW demonstration of advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from coal-fired boilers. Technical progress report, fourth quarter 1991  

SciTech Connect

This quarterly report discusses the technical progress of a US Department of Energy (DOE) Innovative Clean Coal Technology (ICCT) Project demonstrating advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from a coal-fired boiler. The project is being conducted at Gulf Power Company`s Plant Lansing Smith Unit 2 located near Panama City, Florida. The primary objective of this demonstration is to determine the long-term effects of commercially available tangentially-fired low NO{sub x} combustion technologies on NO{sub x} emissions and boiler performance. A target of achieving fifty percent NO{sub x} reduction using combustion modifications has been established for the project. The stepwise approach that is being used to evaluate the NO{sub x} control technologies requires three plant outages to successively install the test instrumentation and the different levels of the low NO{sub x} concentric firing system (LNCFS). Following each outage, a series of four groups of tests are performed. These are (1) diagnostic, (2) performance, (3) long-term, and (4) verification. These tests are used to quantify the NO{sub x} reductions of each technology and evaluate the effects of those reductions on other combustion parameters such as particulate characteristics and boiler efficiency.

Not Available

1992-05-18T23:59:59.000Z

Note: This page contains sample records for the topic "nitrogen oxides particulate" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Innovative Clean Coal Technology (ICCT): 180 MW demonstration of advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NO sub x ) emissions from coal-fired boilers  

SciTech Connect

This quarterly report discusses the technical progress of a US Department of Energy (DOE) Innovative Clean Coal Technology (ICCT) Project demonstrating advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from a coal-fired boiler. The project is being conducted at Gulf Power Company's Plant Lansing Smith Unit 2 located near Panama City, Florida. The primary objective of this demonstration is to determine the long-term effects of commercially available tangentially-fired low NO{sub x} combustion technologies on NO{sub x} emissions and boiler performance. A target of achieving fifty percent NO{sub x} reduction using combustion modifications has been established for the project. The stepwise approach that is being used to evaluate the NO{sub x} control technologies requires three plant outages to successively install the test instrumentation and the different levels of the low NO{sub x} concentric firing system (LNCFS). Following each outage, a series of four groups of tests are performed. These are (1) diagnostic, (2) performance, (3) long-term, and (4) verification. These tests are used to quantify the NO{sub x} reductions of each technology and evaluate the effects of those reductions on other combustion parameters such as particulate characteristics and boiler efficiency.

Not Available

1992-05-18T23:59:59.000Z

82

Removal of oxides of nitrogen from gases in multi-stage coal combustion  

DOE Patents (OSTI)

Polluting NO.sub.x gas values are removed from off-gas of a multi-stage coal combustion process which includes an initial carbonizing reaction, firing of char from this reaction in a fluidized bed reactor, and burning of gases from the carbonizing and fluidized bed reactions in a topping combustor having a first, fuel-rich zone and a second, fuel-lean zone. The improvement by means of which NO.sub.x gases are removed is directed to introducing NO.sub.x -free oxidizing gas such as compressor air into the second, fuel-lean zone and completing combustion with this source of oxidizing gas. Excess air fed to the fluidized bed reactor is also controlled to obtain desired stoichiometry in the first, fuel-rich zone of the topping combustor.

Mollot, Darren J. (Morgantown, WV); Bonk, Donald L. (Louisville, OH); Dowdy, Thomas E. (Orlando, FL)

1998-01-01T23:59:59.000Z

83

Flow reactor experiments on the selective non-catalytic removal of nitrogen oxides  

E-Print Network (OSTI)

?CO, and H, O are initially present in exhaust stream [57]. .. . . . 42 Fig. 21 Fig. 22 Reaction path diagram for RAPRENOx process [63]. .. . Reduction of nitric oxide as a function of temperature, concentration of oxygen, carbon monoxide, and water... the influence of carbon monoxide [89]. . . . . . . . . 58 Fig. 28 Effect of residence time on the NOxOUT process as a function of temperature, NO(initial)=125ppm, 0-ratio of 4 [90]. .. . . . . . . . . . . . . . . 60 Fig. 29 Ammonia slip as a function...

Gentemann, Alexander M.G.

2001-01-01T23:59:59.000Z

84

Demonstration of selective catalytic reduction (SCR) technology for the control of nitrogen oxide (NOx) emissions from high-sulfur coal-fired boilers  

SciTech Connect

The objective of this project is to demonstrate and evaluate commercially available Selective Catalytic Reduction (SCR) catalysts from US, Japanese and European catalyst suppliers on a high-sulfur US coal-fired boiler. SCR is a post-combustion nitrogen oxide (NO{sub x}) control technology that involves injecting ammonia into the flue gas generated from coal combustion in an electric utility boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NO{sub x} to convert it to nitrogen and water vapor.

Not Available

1991-11-01T23:59:59.000Z

85

Method and system for the removal of oxides of nitrogen and sulfur from combustion processes  

DOE Patents (OSTI)

A process for removing oxide contaminants from combustion gas, and employing a solid electrolyte reactor, includes: (a) flowing the combustion gas into a zone containing a solid electrolyte and applying a voltage and at elevated temperature to thereby separate oxygen via the solid electrolyte, (b) removing oxygen from that zone in a first stream and removing hot effluent gas from that zone in a second stream, the effluent gas containing contaminant, (c) and pre-heating the combustion gas flowing to that zone by passing it in heat exchange relation with the hot effluent gas.

Walsh, John V. (Glendora, CA)

1987-12-15T23:59:59.000Z

86

Diesel particulate filters  

Science Journals Connector (OSTI)

Is the broad market introduction of diesel particulate filters throughout Europe wishful thinking or reality? The challenges facing the introduction of diesel particulate filters with a fuel-borne catalyst...

Pierre Macaudičre; Laurent Rocher; Wolfgang Naschke

2004-04-01T23:59:59.000Z

87

Diesel emission control: Catalytic filters for particulate removal  

Science Journals Connector (OSTI)

The European diesel engine industry represents a vital sector across the Continent, with more than 2 million direct work positions and a turnover of over 400 billion Euro. Diesel engines provide large paybacks to society since they are extensively used to transport goods, services and people. In recent years increasing attention has been paid to the emissions from diesel engines which, like gasoline engine emissions, include carbon monoxide (CO), hydrocarbons (HC) and oxides of nitrogen (NOx). Diesel engines also produce significant levels of particulate matter (PM), which consists mostly of carbonaceous soot and a soluble organic fraction (SOF) of hydrocarbons that have condensed on the soot.Meeting the emission levels imposed for NOx and PM by legislation (Euro IV in 2005 and, in the 2008 perspective, Euro V) requires the development of a number of critical technologies to fulfill these very stringent emission limits (e.g. 0.005 g/km for PM). This review is focused on these innovative technologies with special reference to catalytic traps for diesel particulate removal.

Debora Fino

2007-01-01T23:59:59.000Z

88

Non-thermal Aftertreatment of Particulates  

SciTech Connect

Modern diesel passenger vehicles employing common rail, high speed direct injection engines are capable of matching the drivability of gasoline powered vehicles with the additional benefit of providing high torque at low engine speed [1]. The diesel engine also offers considerable fuel economy and CO2 emissions advantages. However, future emissions standards [2,3] present a significant challenge for the diesel engine, as its lean exhaust precludes the use of aftertreatment strategies employing 3- way catalytic converters, which operate under stoichiometric conditions. In recent years significant developments by diesel engine manufacturers have greatly reduced emissions of both particulates (PM) and oxides of nitrogen (NOx) [4,5]. However to achieve compliance with future legislative limits it has been suggested that an integrated approach involving a combination of engine modifications and aftertreatment technology [1] will be required. A relatively new approach to exhaust aftertreatment is the application of non-thermal plasma (NTP) or plasma catalyst hybrid systems. These have the potential for treatment of both NOx and PM emissions [6- 8]. The primary focus of recent plasma aftertreatment studies [9-12] has concentrated on the removal of NOx. It has been shown that by combining plasmas with catalysts it is possible to chemically reduce NOx. The most common approach is to use a 2- stage system relying upon the plasma oxidation of hydrocarbons to promote NO to NO2 conversion as a precursor to NO2 reduction over a catalyst. However, relatively little work has yet been published on the oxidation of PM by plasma [ 8,13]. Previous investigations [8] have reported that a suitably designed NTP reactor containing a packing material designed to filter and retain PM can effect the oxidation of PM in diesel exhausts at low temperatures. It has been suggested that the retained PM competes with hydrocarbons for O, and possibly OH, radicals. This is an important consideration in plasma - catalyst hybrid schemes for the removal of NOx employing an NO2 selective catalyst, as the oxidation of PM may deplete the key radicals necessary for NO to NO2 conversion. It was also suggested that where simultaneous NOx and PM removal are required, alternative catalyst formulations may be needed which may be selective to NO rather than NO2.

Thomas, S.E.

2000-08-20T23:59:59.000Z

89

Innovative Clean Coal Technology (ICCT): 180 MW demonstration of advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from coal-fired boilers. Technical progress report, first quarter 1992  

SciTech Connect

This quarterly report discusses the technical progress of a US Department of Energy (DOE) Innovative Clean Coal Technology (ICCT) Project demonstrating advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from a coal-fired boiler. The project is being conducted at Gulf Power Company`s Plant Lansing Smith Unit 2 located near Panama City, Florida. The primary objective of this demonstration is to determine the long-term effects of commercially available tangentially-fired low NO{sub x} combustion technologies on NO{sub x} emissions and boiler performance. A target of achieving fifty percent NO{sub x} reduction using combustion modifications has been established for the project. The stepwise approach that is being used to evaluate the NO{sub x} control technologies requires three plant outages to successively install the test instrumentation and the different levels of the low NO{sub x} concentric firing system (LNCFS). Following each outage, a series of four groups of tests are performed. These are (1) diagnostic, (2) performance, (3) long-term, and (4) verification. These tests are used to quantify the NO{sub x} reductions of each technology and evaluate the effects of those reductions on other combustion parameters such as particulate characteristics and boiler efficiency. This technical progess report presents the LNCFS Level III long-term data collected during this quarter. NO{sub x} emissions for each day of long-term testing are presented. The average NO{sub x} emission during long-term testing was 0.39 lb/MBtu at an average load of 155 MW. The effect of the low NO{sub x} combustion system on other combustion parameters such as carbon monoxide, excess oxygen level, and carbon carryover are also included.

Not Available

1992-05-20T23:59:59.000Z

90

Innovative Clean Coal Technology (ICCT): 180 MW demonstration of advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NO[sub x]) emissions from coal-fired boilers  

SciTech Connect

This quarterly report discusses the technical progress of a US Department of Energy (DOE) Innovative Clean Coal Technology (ICCT) Project demonstrating advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NO[sub x]) emissions from a coal-fired boiler. The project is being conducted at Gulf Power Company's Plant Lansing Smith Unit 2 located near Panama City, Florida. The primary objective of this demonstration is to determine the long-term effects of commercially available tangentially-fired low NO[sub x] combustion technologies on NO[sub x] emissions and boiler performance. A target of achieving fifty percent NO[sub x] reduction using combustion modifications has been established for the project. The stepwise approach that is being used to evaluate the NO[sub x] control technologies requires three plant outages to successively install the test instrumentation and the different levels of the low NO[sub x] concentric firing system (LNCFS). Following each outage, a series of four groups of tests are performed. These are (1) diagnostic, (2) performance, (3) long-term, and (4) verification. These tests are used to quantify the NO[sub x] reductions of each technology and evaluate the effects of those reductions on other combustion parameters such as particulate characteristics and boiler efficiency. This technical progess report presents the LNCFS Level III long-term data collected during this quarter. NO[sub x] emissions for each day of long-term testing are presented. The average NO[sub x] emission during long-term testing was 0.39 lb/MBtu at an average load of 155 MW. The effect of the low NO[sub x] combustion system on other combustion parameters such as carbon monoxide, excess oxygen level, and carbon carryover are also included.

Not Available

1992-05-20T23:59:59.000Z

91

Innovative Clean Coal Technology (ICCT): 180 MW demonstration of advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from coal-fired boilers. Technical progress report, second quarter 1992  

SciTech Connect

This quarterly report discusses the technical progress of a US Department of Energy (DOE) Innovative Clean Coal Technology (ICCT) Project demonstrating advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from a coal-fired boiler. The project is being conducted at Gulf Power Company`s Plant Lansing Smith Unit 2 located near Panama City, Florida. The primary objective of this demonstration is to determine the long-term effects of commercially available tangentially-fired low NO{sub x} combustion technologies on NO{sub x} emissions and boiler performance. A target of achieving fifty percent NO{sub x} reduction using combustion modifications has been established for the project. The stepwise approach that is being used to evaluate the NO{sub x} control technologies requires three plant outages to successively install the test instrumentation and the different levels of the low NO{sub x} concentric firing system (LNCFS). Following each outage, a series of four groups of tests are performed. These are (1) diagnostic, (2) performance, (3) long-term, and (4) verification. These tests are used to quantify the NO{sub x} reductions of each technology and evaluate the effects of those reductions on other combustion parameters such as particulate characteristics and boiler efficiency. This technical progress report presents the LNCFS Level I short-term data collected during this quarter. In addition, a comparison of all the long-term emissions data that have been collected to date is included.

Not Available

1992-11-25T23:59:59.000Z

92

Measuring PM Distribution in a Catalyzed Particulate Filter using a Terahertz Wave Scanner  

Energy.gov (U.S. Department of Energy (DOE))

Terahertz scanning system produced 3-dimensional image of local PM density in catatalyzed particulate filters tested under loading and oxidizing conditions

93

Pitch based foam with particulate  

DOE Patents (OSTI)

A thermally conductive, pitch based foam composite having a particulate content. The particulate alters the mechanical characteristics of the foam without severely degrading the foam thermal conductivity. The composite is formed by mixing the particulate with pitch prior to foaming.

Klett, James W. (Knoxville, TN)

2001-01-01T23:59:59.000Z

94

ARM - Oxides of Nitrogen  

NLE Websites -- All DOE Office Websites (Extended Search)

dioxide and methane, but as you will see they are important contributors to the greenhouse effect. We hope you are getting an understanding of how important all these gases are...

95

Abatement of Air Pollution: The Clean Air Interstate Rule (CAIR) Nitrogen Oxides (Nox) Ozone Season Trading Program (Connecticut)  

Energy.gov (U.S. Department of Energy (DOE))

These regulations may apply to fossil-fuel fired emission units, and describe nitrogen emission allocations that owners of such units must meet. The regulations also contain provisions for...

96

Photochemical Oxidant Processes in the Presence of Dust: An Evaluation of the Impact of Dust on Particulate Nitrate and Ozone Formation  

Science Journals Connector (OSTI)

The influence of dust on the tropospheric photochemical oxidant cycle is studied through the use of a detailed coupled aerosol and gas-phase chemistry model. Dust is a significant component of the troposphere throughout Asia and provides a ...

Yang Zhang; Young Sunwoo; Veerabhadra Kotamarthi; Gregory R. Carmichael

1994-07-01T23:59:59.000Z

97

Reduction of particulate matter and gaseous emission from marine diesel engines using a catalyzed particulate filter  

Science Journals Connector (OSTI)

Diesel engines are used widely as the power sources of coastal ships and international vessels primarily due to their high thermal efficiency, high fuel economy and durable performance. However, the gaseous and solid substances exhausted from diesel engines during the combustion process cause air pollution, in particular around harbor regions. In order to effectively reduce particulate matter and gaseous pollution emissions, a catalyzed particulate filter was equipped in the tail pipe of a marine diesel engine. The engine's performance and emission characteristics under various engine speeds and torques were measured using a computerized engine data control and acquisition system accompanied with an engine dynamometer. The effectiveness of installing a catalyzed particulate filter on the reduction of pollutant emissions was examined. The experimental results show that the exhaust gas temperature, carbon monoxide and smoke opacity were reduced significantly upon installation of the particulate filter. In particular, larger conversion of carbon monoxide to carbon dioxide — and thus larger CO2 and lower CO emissions — were observed for the marine diesel engine equipped with a catalyzed particulate filter and operated at higher engine speeds. This is presumably due to enhancement of the catalytic oxidation reaction that results from an exhaust gas with stronger stirring motion passing through the filter. The absorption of partial heating energy from the exhaust gas by the physical structure of the particulate filter resulted in a reduction in the exhaust gas temperature. The particulate matter could be burnt to a greater extent due to the effect of the catalyst coated on the surface of the particulate filter. Moreover, the fuel consumption rate was increased slightly while the excess oxygen emission was somewhat decreased with the particulate filter.

Cherng-Yuan Lin

2002-01-01T23:59:59.000Z

98

Field Demonstration of 0.2 Grams Per Horsepower-Hour (g/bhp-hr) Oxides of Nitrogen (NOx) Natural  

E-Print Network (OSTI)

: · Reducing health and environmental impacts from air pollution, and greenhouse gas emissions related pollution and greenhouse gas emissions beyond applicable standards, and that benefit natural gas ratepayers of nitrogen (NOx) emission standard of 0.20 g/bhp-hr for heavy duty engines to reduce levels of this critical

99

Evaluation of the Emission, Transport, and Deposition of Mercury, Arsenic, and Fine Particulate Matter From Coal-Based Power Plants in the Ohio River Valley  

NLE Websites -- All DOE Office Websites (Extended Search)

Kevin crist Kevin crist Principal Investigator Ohio University Research and Technology Center Athens, OH 45701 740-593-4751 cristk@ohiou.edu Environmental and Water Resources Evaluation of thE Emission, transport, and dEposition of mErcury, arsEnic, and finE particulatE mattEr from coal-BasEd powEr plants in thE ohio rivEr vallEy rEgion Background The U.S. Department of Energy's National Energy Technology Laboratory (NETL) has established an aggressive research initiative to address the technical and scientific issues surrounding the impact of coal-based power systems on ambient levels of fine particulate matter (PM 2.5 ), nitrogen oxides (NO X ), mercury/air toxics, and acid gases. Regulatory drivers such as the 1990 Clean Air Act Amendments, the 1997 revised National Ambient Air Quality Standards, and the 2005 Clean Air

100

Solubility of carbon dioxide, nitrous oxide, ethane, and nitrogen in 1-butyl-1-methylpyrrolidinium and trihexyl(tetradecyl)phosphonium tris(pentafluoroethyl)trifluorophosphate (eFAP) ionic liquids  

Science Journals Connector (OSTI)

The density and viscosity of the ionic liquids 1-butyl-1-methylpyrrolidinium tris(pentafluoroethyl)trifluorophosphate [C1C4Pyrro][eFAP] and trihexyl(tetradecyl)phosphonium tris(pentafluoroethyl)trifluorophosphate [P66614][eFAP] were measured as a function of temperature and pressure and as a function of temperature, respectively. These two ionic liquids are more viscous than those based in the same anion associated to imidazolium cations. The effect of the addition of water on the density and viscosity of [P66614][eFAP] was studied at pressures close to atmospheric and as a function of the temperature. This ionic liquid is only partially miscible with water, its solubility being of around X H 2 O = 0.2 in the range of (303 to 315) K. Experimental values of the solubility of carbon dioxide, nitrous oxide, ethane, and nitrogen were obtained as a function of temperature and at pressures close to atmospheric. Carbon dioxide and nitrous oxide are the more soluble gases with mole fraction solubilities up to 7 · 10?2. Ethane is four times and 1.3 times less soluble than carbon dioxide in [C1C4Pyrro][eFAP] and [P66614][eFAP], respectively. Nitrogen is one order of magnitude less soluble than the others gases in the two ionic liquids studied. In order to understand behavior of the different gases with these ionic liquids, the thermodynamic functions of solvation such as enthalpy and entropy were calculated from the variation of the Henry’s law constant with temperature. It is shown that the more favorable interactions of the gases with the ionic liquid explain the larger solubility of carbon dioxide and nitrous oxide in [C1C4Pyrro][eFAP]. In the case of [P66614][eFAP], it is the less favorable entropic contribution that explains the lower solubility of ethane in this ionic liquid.

S. Stevanovic; M.F. Costa Gomes

2013-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "nitrogen oxides particulate" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Nitrite–dependent nitric oxide production pathway: implications for involvement of active nitrogen species in photoinhibition in vivo  

Science Journals Connector (OSTI)

...as a convenient method for calibration...1. Chemical NO production from nitrite and...Figure 4. Sequential production of the activated...interactions. Like hydrogen peroxide (H2O2...oxide protocols: methods in molecular biology...Nonenzymatic nitric oxide production in humans. Nitric...

2000-01-01T23:59:59.000Z

102

Nitrogen Oxides in the Nocturnal Boundary Layer: Chemistry of Nitrous Acid (HONO) and the Nitrate Radical (N03)  

SciTech Connect

Summary Chemical processes occurring at night in the lowest part of the urban atmosphere, the so called nocturnal boundary layer (NBL), can influence the composition of the atmosphere during the night as well as the following day. They may impact the budgets of some of the most important pollutants, such as ozone and nitrogen oxides, as well as influence size and composition of particular matter. Few studies have thus far concentrated on the nocturnal chemistry of the urban NBL, most likely due to the strong influence of vertical transport and mixing, which requires the measurement of trace gas profiles instead of simple point observations. Motivated by our lack of observations and understanding of nocturnal chemistry, the focus of this project was the study of the vertical distribution of trace gases and the altitude dependence of nocturnal chemistry under polluted conditions through field observations and modeling studies. The analysis of three field experiments (TEXAQS, Houston, 2000; Phoenix Sunrise Ozone Experiment, 2001; NAPOX, Boston, 2002), two of which were performed in this project, showed that ozone concentrations typically increase with height in the lowest 150m, while NO2 typically decreases. NO3, the dominant nocturnal radical species, showed much higher concentrations in the upper part of the NBL, and was often not present at the ground. With the help of a one-dimensional chemical transport model, developed in this project, we found that the interaction of ground emissions of NOx and hydrocarbons, together with their vertical transport, is responsible for the vertical profiles. The dominant chemical reactions influencing ozone, NO2 and NO3 are the reaction of ozone and NO3 with freshly emitted NO. Sensitivity studies with our model showed that the magnitude of the trace gas gradients depend both on the emission rates and the vertical stability of the NBL. Observations and model analysis clearly show that nocturnal chemistry in urban areas is altitude dependent. Measurements at one altitude, for example at the ground, where most air quality monitoring stations are located, are not representative for the rest of the NBL. Our model also revealed that radical chemistry is, in general, altitude dependent at night. We distinguish three regions: an unreactive, NO rich, ground layer; an upper, O3 and NO3 dominated layer, and a reactive mixing layer, where RO2 radicals are mixed from aloft with NO from the ground. In this reactive layer an active radical chemistry and elevated OH radical levels can be found. The downward transport of N2O5 and HO2NO2, followed by their thermal decay, was also identified as a radical source in this layer. Our observations also gave insight into the formation of HONO in the NBL. Based on our field experiments we were able to show that the NO2 to HONO conversion was relative humidity dependent. While this fact was well known, we found that it is most likely the uptake of HONO onto surfaces which is R.H. dependent, rather than the NO2 to HONO conversion. This finding led to the proposal of a new NO2 to HONO conversion mechanism, which is based on solid physical chemical principles. Noteworthy is also the observation of enhanced NO2 to HONO conversion during a dust storm event in Phoenix. The final activity in our project investigated the influence of the urban canopy, i.e. building walls and surfaces, on nocturnal chemistry. For the first time the surface area of a city was determined based on a Geographical Information System database of the city of Santa Monica. The surface to volume areas found in this study showed that, in the 2 lower part of the NBL, buildings provide a much larger surface area than the aerosol. In addition, buildings take up a considerable amount of the volume near the ground. The expansion of our model and sensitivity studies based on the Santa Monica data revealed that the surface area of buildings considerably influences HONO levels in urban areas. The volume reduction leads to a decrease of O3 and an increase of NO2 near the ground due to the stronger impact o

Jochen Stutz

2005-05-24T23:59:59.000Z

103

Analysis of Strategies for Reducing Multiple Emissions from Electric Power Plants: Sulfur Dioxide, Nitrogen Oxides, Carbon Dioxide, and Mercury and a Renewable Portfolio Standard  

Gasoline and Diesel Fuel Update (EIA)

3 3 ERRATA Analysis of Strategies for Reducing Multiple Emissions from Electric Power Plants: Sulfur Dioxide, Nitrogen Oxides, Carbon Dioxide, and Mercury and a Renewable Portfolio Standard July 2001 Energy Information Administration Office of Integrated Analysis and Forecasting U.S. Department of Energy Washington, DC 20585 This Service Report was prepared by the Energy Information Administration, the independent statistical and analytical agency within the Department of Energy. The information contained herein should be attributed to the Contacts This report was prepared by the Office of Integrated Analysis and Forecasting, Energy Information Adminis- tration. General questions concerning the report may be directed to Mary J. Hutzler (202/586-2222, mhutzler @eia.doe.gov), Director of the Office of Integrated Analysis and Forecasting, Scott B. Sitzer (202/586-2308,

104

The Advanced Tangentially Fired Combustion Techniques for the Reduction of Nitrogen Oxides (NOx) Emissions From Coal-Fired Boilers Demonstration Project: A DOE Assessment  

NLE Websites -- All DOE Office Websites (Extended Search)

2 2 The Advanced Tangentially Fired Combustion Techniques for the Reduction of Nitrogen Oxides (NO ) Emissions From Coal-Fired Boilers X Demonstration Project: A DOE Assessment March 2000 U.S. Department of Energy National Energy Technology Laboratory P.O. Box 880, 3610 Collins Ferry Road Morgantown, WV 26507-0880 and P.O. Box 10940, 626 Cochrans Mill Road Pittsburgh, PA 15236-0940 2 Disclaimer This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or

105

Demonstration of selective catalytic reduction (SCR) technology for the control of nitrogen oxide (NO[sub x]) emissions from high-sulfur coal-fired boilers  

SciTech Connect

The objective of this project is to demonstrate and evaluate commercially available Selective Catalytic Reduction (SCR) catalysts from US, Japanese and European catalyst suppliers on a high-sulfur US coal-fired boiler. SCR is a post-combustion nitrogen oxide (NO[sub x]) control technology that involves injecting ammonia into the flue gas generated from coal combustion in an electric utility boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NO[sub x] to convert it to nitrogen and water vapor. Although SCR is widely practiced in Japan and Europe, there are numerous technical uncertainties associated with applying SCR to US coals. These uncertainties include: (1) potential catalyst deactivation due to poisoning by trace metal species present in US coals that are not present in other fuels. (2) performance of the technology and effects on the balance-of-plant equipment in the presence of high amounts of SO[sub 2] and SO[sub 3]. (3) performance of a wide variety of SCR catalyst compositions, geometries and methods of manufacture under typical high-sulfur coal-fired utility operating conditions. These uncertainties will be explored by constructing a series of small-scale SCR reactors and simultaneously exposing different SCR catalysts to flue gas derived from the combustion of high sulfur U. S. coal.

Not Available

1992-08-01T23:59:59.000Z

106

ADVANCED HYBRID PARTICULATE COLLECTOR  

SciTech Connect

A new concept in particulate control, called an advanced hybrid particulate collector (AHPC), is being developed under funding from the US Department of Energy. The AHPC combines the best features of electrostatic precipitators (ESPs) and baghouses in a manner that has not been done before. The AHPC concept consists of a combination of fabric filtration and electrostatic precipitation in the same housing, providing major synergism between the two collection methods, both in the particulate collection step and in the transfer of dust to the hopper. The AHPC provides ultrahigh collection efficiency, overcoming the problem of excessive fine-particle emission with conventional ESPs, and it solves the problem of reentrainment and collection of dust in conventional baghouses. The AHPC is currently being tested at the 2.7-MW scale at the Big Stone power station.

Stanley Miller; Rich Gebert; William Swanson

1999-11-01T23:59:59.000Z

107

Electrically-Assisted Diesel Particulate Filter Regeneration...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

More Documents & Publications Substrate Studies of an Electrically-Assisted Diesel Particulate Filter Electrically-Assisted Diesel Particulate Filter Regeneration...

108

O{sub 2}-mediated oxidation of ferrous nitrosylated human serum heme-albumin is limited by nitrogen monoxide dissociation  

SciTech Connect

Research highlights: {yields} Human serum heme-albumin displays globin-like properties. {yields} O{sub 2}-mediated oxidation of ferrous nitrosylated human serum heme-albumin. {yields} Allosteric modulation of human serum heme-albumin reactivity. {yields} Rifampicin is an allosteric effector of human serum heme-albumin. {yields} Human serum heme-albumin is a ROS and NOS scavenger. -- Abstract: Human serum heme-albumin (HSA-heme-Fe) displays globin-like properties. Here, kinetics of O{sub 2}-mediated oxidation of ferrous nitrosylated HSA-heme-Fe (HSA-heme-Fe(II)-NO) is reported. Values of the first-order rate constants for O{sub 2}-mediated oxidation of HSA-heme-Fe(II)-NO (i.e., for ferric HSA-heme-Fe formation) and for NO dissociation from HSA-heme-Fe(II)-NO (i.e., for NO replacement by CO) are k = 9.8 x 10{sup -5} and 8.3 x 10{sup -4} s{sup -1}, and h = 1.3 x 10{sup -4} and 8.5 x 10{sup -4} s{sup -1}, in the absence and presence of rifampicin, respectively, at pH = 7.0 and T = 20.0 {sup o}C. The coincidence of values of k and h indicates that NO dissociation represents the rate limiting step of O{sub 2}-mediated oxidation of HSA-heme-Fe(II)-NO. Mixing HSA-heme-Fe(II)-NO with O{sub 2} does not lead to the formation of the transient adduct(s), but leads to the final ferric HSA-heme-Fe derivative. These results reflect the fast O{sub 2}-mediated oxidation of ferrous HSA-heme-Fe and highlight the role of drugs in modulating allosterically the heme-Fe-atom reactivity.

Ascenzi, Paolo, E-mail: ascenzi@uniroma3.it [Interdepartmental Laboratory of Electron Microscopy, University Roma Tre, Via della Vasca Navale 79, I-00146 Roma (Italy) [Interdepartmental Laboratory of Electron Microscopy, University Roma Tre, Via della Vasca Navale 79, I-00146 Roma (Italy); National Institute for Infectious Diseases I.R.C.C.S. 'Lazzaro Spallanzani', Via Portuense 292, I-00149 Roma (Italy); Gullotta, Francesca; Gioia, Magda; Coletta, Massimo [Department of Experimental Medicine and Biochemical Sciences, University of Roma 'Tor Vergata', Via Montpellier 1, I-00133 Roma (Italy) [Department of Experimental Medicine and Biochemical Sciences, University of Roma 'Tor Vergata', Via Montpellier 1, I-00133 Roma (Italy); Interuniversity Consortium for the Research on the Chemistry of Metals in Biological Systems, Piazza Umberto I 1, I-87100 Bari (Italy); Fasano, Mauro [Department of Structural and Functional Biology, and Center of Neuroscience, University of Insubria, Via Alberto da Giussano 12a, I-21052 Busto Arsizio, VA (Italy)] [Department of Structural and Functional Biology, and Center of Neuroscience, University of Insubria, Via Alberto da Giussano 12a, I-21052 Busto Arsizio, VA (Italy)

2011-03-04T23:59:59.000Z

109

Fertilizer and Nitrogen 1 billion tons of artificial nitrogen fertilizer used annually.  

E-Print Network (OSTI)

Fertilizer and Nitrogen 1 billion tons of artificial nitrogen fertilizer used annually. Emissions. (fertilizers that use nitric acid or ammonium bicarbonate result in emissions of nitrogen oxides, nitrous oxide, ammonia and carbon dioxide into the atmosphere.) ~Indirect: Phosphorus in excess causes eutrophication

Toohey, Darin W.

110

Methods for making lithium vanadium oxide electrode materials  

DOE Patents (OSTI)

A method of making vanadium oxide formulations is presented. In one method of preparing lithium vanadium oxide for use as an electrode material, the method involves: admixing a particulate form of a lithium compound and a particulate form of a vanadium compound; jet milling the particulate admixture of the lithium and vanadium compounds; and heating the jet milled particulate admixture at a temperature below the melting temperature of the admixture to form lithium vanadium oxide.

Schutts, Scott M. (Menomonie, WI); Kinney, Robert J. (Woodbury, MN)

2000-01-01T23:59:59.000Z

111

High-performance tin oxide-nitrogen doped graphene aerogel hybrids as anode materials for lithium-ion batteries  

Science Journals Connector (OSTI)

Abstract Tin dioxide nanoparticles on nitrogen doped graphene aerogel (SnO2-NGA) hybrid are synthesized by one-step hydrothermal method and successfully applied in lithium-ion batteries as a free-standing anode. The electrochemical performance of SnO2-NGA hybrid is investigated by galvanostatic charge–discharge cycling, rate capability test, cyclic voltammetry and electrochemical impedance spectroscopy. It is found that the SnO2-NGA hybrid with freestanding spongy-like structure exhibit remarkable lithium storage capacity (1100 mAh g?1 after 100 cycles), good cycling stability and high rate capability. The outstanding performance is attributed to the uniform SnO2 nanoparticles, unique spongy-like structure and N doping defect for Li+ diffusion.

Chunhui Tan; Jing Cao; Abdul Muqsit Khattak; Feipeng Cai; Bo Jiang; Gai Yang; Suqin Hu

2014-01-01T23:59:59.000Z

112

Oxygen Reactivity of Devolatilized Diesel Engine Particulates from Conventional and Biodiesel Fuels  

Science Journals Connector (OSTI)

Oxygen Reactivity of Devolatilized Diesel Engine Particulates from Conventional and Biodiesel Fuels ... Abatement of diesel particulates has led to an overall decrease in the fuel efficiency of diesel engines, and overcoming these losses has been one of the more challenging problems in exhaust aftertreatment. ... (16-18) Establishing a general physical basis for modeling diesel particulate oxidation is especially challenging because of the large variations in microscopic structure that it can have. ...

Andrea Strzelec; Todd J. Toops; C. Stuart Daw

2013-06-10T23:59:59.000Z

113

Innovative Clean Coal Technology (ICCT): Demonstration of Selective Catalytic Reduction (SCR) technology for the control of nitrogen oxide (NO{sub x}) emissions from high-sulfur coal-fired boilers. Quarterly report No. 6, October--December, 1991  

SciTech Connect

The objective of this project is to demonstrate and evaluate commercially available Selective Catalytic Reduction (SCR) catalysts from US, Japanese and European catalyst suppliers on a high-sulfur US coal-fired boiler. SCR is a post-combustion nitrogen oxide (NOx) control technology that involves injecting ammonia into the flue gas generated from coal combustion in an electric utility boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NOx to convert it to nitrogen and water vapor.

Not Available

1992-02-01T23:59:59.000Z

114

Innovative Clean Coal Technology (ICCT): Demonstration of Selective Catalytic Reduction (SCR) technology for the control of nitrogen oxide (NO sub x ) emissions from high-sulfur coal-fired boilers  

SciTech Connect

The objective of this project is to demonstrate and evaluate commercially available Selective Catalytic Reduction (SCR) catalysts from US, Japanese and European catalyst suppliers on a high-sulfur US coal-fired boiler. SCR is a post-combustion nitrogen oxide (NOx) control technology that involves injecting ammonia into the flue gas generated from coal combustion in an electric utility boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NOx to convert it to nitrogen and water vapor.

Not Available

1992-02-01T23:59:59.000Z

115

Demonstration of selective catalytic reduction (SCR) technology for the control of nitrogen oxide (NOx) emissions from high-sulfur coal-fired boilers. Quarterly report No. 5, July--September 1991  

SciTech Connect

The objective of this project is to demonstrate and evaluate commercially available Selective Catalytic Reduction (SCR) catalysts from US, Japanese and European catalyst suppliers on a high-sulfur US coal-fired boiler. SCR is a post-combustion nitrogen oxide (NO{sub x}) control technology that involves injecting ammonia into the flue gas generated from coal combustion in an electric utility boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NO{sub x} to convert it to nitrogen and water vapor.

Not Available

1991-11-01T23:59:59.000Z

116

Innovative Clean Coal Technology (ICCT): Demonstration of Selective Catalytic Reduction (SCR) technology for the control of nitrogen oxide (NO{sub x}) emissions from high-sulfur coal-fired boilers. Quarterly report No. 2, October--December 1990  

SciTech Connect

The objective of this project is to demonstrate and evaluate commercially available Selective Catalytic Reduction (SCR) catalysts from US, Japanese and European catalyst suppliers on a high-sulfur US coal-fired boiler. SCR is a post-combustion nitrogen oxide NO{sub x} control technology that involves injecting ammonia into the flue gas generated from coal combustion in an electric utility boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NO{sub x} to convert it to nitrogen and water vapor.

Not Available

1991-02-01T23:59:59.000Z

117

Innovative Clean Coal Technology (ICCT): Demonstration of Selective Catalytic Reduction (SCR) technology for the control of nitrogen oxide (NO sub x ) emissions from high-sulfur coal-fired boilers  

SciTech Connect

The objective of this project is to demonstrate and evaluate commercially available Selective Catalytic Reduction (SCR) catalysts from US, Japanese and European catalyst suppliers on a high-sulfur US coal-fired boiler. SCR is a post-combustion nitrogen oxide NO{sub x} control technology that involves injecting ammonia into the flue gas generated from coal combustion in an electric utility boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NO{sub x} to convert it to nitrogen and water vapor.

Not Available

1991-02-01T23:59:59.000Z

118

Innovative clean coal technology (ICCT): Demonstration of selective catalytic reduction (SCR) technology for the control of nitrogen oxide (NO{sub x}) emissions from high-sulfur coal-fired boilers. Quarterly report No. 3, January--March 1991  

SciTech Connect

The objective of this project is to demonstrate and evaluate commercially available Selective Catalytic Reduction (SCR) catalysts from US, Japanese and European catalyst suppliers on a high-sulfur US coal-fired boiler. SCR is a post-combustion nitrogen oxide (NOx) control technology that involves injecting ammonia into the flue gas generated from coal combustion in an electric utility boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NOx to convert it to nitrogen and water vapor.

Not Available

1991-07-01T23:59:59.000Z

119

Innovative clean coal technology (ICCT): Demonstration of selective catalytic reduction (SCR) technology for the control of nitrogen oxide (NO sub x ) emissions from high-sulfur coal-fired boilers  

SciTech Connect

The objective of this project is to demonstrate and evaluate commercially available Selective Catalytic Reduction (SCR) catalysts from US, Japanese and European catalyst suppliers on a high-sulfur US coal-fired boiler. SCR is a post-combustion nitrogen oxide (NOx) control technology that involves injecting ammonia into the flue gas generated from coal combustion in an electric utility boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NOx to convert it to nitrogen and water vapor.

Not Available

1991-07-01T23:59:59.000Z

120

Particulate matter dynamics  

E-Print Network (OSTI)

A substantial fraction of the particulate matter released into the atmosphere by industrial or natural processes corresponds to particles whose aerodynamic diameters are greater than 50 mm. It has been shown that, for these particles, the classical description of Gaussian plume diffusion processes, is inadequate to describe the transport and deposition. In this paper we present new results concerning the dispersion of coarse particulate matter. The simulations are done with our own code that uses the Bulirsch Stoer numerical integrator to calculate threedimensional trajectories of particles released into the environment under very general conditions. Turbulent processes are simulated by the Langevin equation and weather conditions are modeled after stable (Monin-Obukhov length L> 0) and unstable conditions (L <0). We present several case studies based on Monte Carlo simulations and discusses the effect of weather on the final deposition of these particles.

Cionco, Rodolfo G; Caligaris, Marta G

2012-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "nitrogen oxides particulate" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Clean coal technology: selective catalytic reduction (SCR) technology for the control of nitrogen oxide emissions from coal-fired boilers  

SciTech Connect

The report discusses a project carried out under the US Clean Coal Technology (CCT) Demonstration Program which demonstrated selective catalytic reduction (SCR) technology for the control of NOx emissions from high-sulphur coal-fired boilers under typical boilers conditions in the United States. The project was conducted by Southern Company Services, Inc., who served as a co-funder and as the host at Gulf Power Company's Plant Crist. The SCR process consists of injecting ammonia (NH{sub 3}) into boiler flue gas and passing the flue gas through a catalyst bed where the Nox and NH{sub 3} react to form nitrogen and water vapor. The results of the CCTDP project confirmed the applicability of SCR for US coal-fired power plants. In part as a result of the success of this project, a significant number of commercial SCR units have been installed and are operating successfully in the United States. By 2007, the total installed SCR capacity on US coal-fired units will number about 200, representing about 100,000 MWe of electric generating capacity. This report summarizes the status of SCR technology. 21 refs., 3 figs., 2 tabs., 10 photos.

NONE

2005-05-01T23:59:59.000Z

122

Synthesis of graphene with both high nitrogen content and high surface area by annealing composite of graphene oxide and g-C3N4  

Science Journals Connector (OSTI)

In this paper, we propose a facile, catalyst-free thermal annealing approach for synthesis of N-doping graphene (NG) using graphitic carbon nitride (g...3N4) as the nitrogen source. Graphene with nitrogen content...

Yurong Deng; Kewei Liu; Hongmei Cao…

2014-10-01T23:59:59.000Z

123

Nitrogen sorption  

DOE Patents (OSTI)

Nitrogen-sorbing and -desorbing compositions and methods of using the same are disclosed, which are useful for the selective separation of nitrogen from other gases, especially natural gas.

Friesen, Dwayne T. (Bend, OR); Babcock, Walter C. (Bend, OR); Edlund, David J. (Bend, OR); Miller, Warren K. (Bend, OR)

1996-01-01T23:59:59.000Z

124

Nitrogen sorption  

DOE Patents (OSTI)

Nitrogen-sorbing and -desorbing compositions and methods of using the same are disclosed, which are useful for the selective separation of nitrogen from other gases, especially natural gas.

Friesen, Dwayne T. (Bend, OR); Babcock, Walter C. (Bend, OR); Edlund, David J. (Bend, OR); Miller, Warren K. (Bend, OR)

1993-01-01T23:59:59.000Z

125

Nitrogen sorption  

DOE Patents (OSTI)

Nitrogen-sorbing and -desorbing compositions and methods of using the same are disclosed, which are useful for the selective separation of nitrogen from other gases, especially natural gas.

Friesen, D.T.; Babcock, W.C.; Edlund, D.J.; Miller, W.K.

1993-07-06T23:59:59.000Z

126

Nitrogen sorption  

DOE Patents (OSTI)

Nitrogen-sorbing and -desorbing compositions and methods of using the same are disclosed, which are useful for the selective separation of nitrogen from other gases, especially natural gas. 5 figs.

Friesen, D.T.; Babcock, W.C.; Edlund, D.J.; Miller, W.K.

1996-05-14T23:59:59.000Z

127

Multilayer films of indium tin oxide/TiO2 codoped with vanadium and nitrogen for efficient photocatalytic water splitting  

Science Journals Connector (OSTI)

TiO22 films codoped with V cations and N anions were synthesised by RF-magnetron sputtering. The incorporation of V and N in TiO2 lattice produces isolated energy levels near the conduction and valence bands, respectively, causing an effective narrowing of the band gap to 2.5 eV. Recombination of photo-charges was reduced by depositing multilayer films of indium tin oxide (ITO)/V-N-codoped TiO2 with different numbers of bilayers. In multilayer structure, the generated photoelectrons, travelling into TiO2 film of limited thickness, rapidly enter the space charge interface of the ITO/TiO2 films from where they are instantaneously injected into the ITO layer and then removed towards the cathode. The synergic effects created by band narrowing and enhanced charge separation by using codoping and multilayer structure strategy in TiO2 generate higher photocurrent for water splitting under visible light which definitely exceeds that obtained by doping TiO2 with a single, V or N, element.

Z. El Koura; N. Patel; R. Edla; A. Miotello

2014-01-01T23:59:59.000Z

128

Personal and Ambient Air Pollution is Associated with Increased Exhaled Nitric Oxide in Children with Asthma  

E-Print Network (OSTI)

1994. Nitric oxide and nitrogen dioxide: Method 6014. In:Molecular mechanisms of nitrogen dioxide induced epithelialEC, OC), and 24-hr nitrogen dioxide. Ambient exposures

2006-01-01T23:59:59.000Z

129

Experimental investigation of the effect of combined hydrogen and diesel combustion on the particulate size distribution from a high speed direct injection diesel engine  

Science Journals Connector (OSTI)

The effects of hydrogen addition and exhaust gas recirculation (EGR) levels on the exhaust particulate matter size distribution in a diesel engine have been investigated. The experiments were performed on a 2.0 litre, 4-cylinder, direct injection engine equipped with a modern high-pressure common rail. A nano-Micro-Orifice Uniform Deposit Impactor (nano-MOUDI) was used in this work to study the particulate matter size distribution. All tests were conducted at the set operating point of 1,500 rpm. The experimental work showed that the particulate matter size distribution was not dramatically altered by the addition of EGR, but the main peak was shifted towards the nucleation mode with the addition of hydrogen. The addition of hydrogen increases the emissions of nitrogen oxides (NOx), but reduces the emissions of unburnt hydrocarbons (THC). Conversely, the addition of EGR reduces NOx, but can increase THC. Hydrogen addition increases the peak cylinder pressure and the maximum rate of pressure rise.

L. McWilliam; A. Megaritis

2009-01-01T23:59:59.000Z

130

Pleated Ceramic Fiber Diesel Particulate Filter | Department...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Pleated Ceramic Fiber Diesel Particulate Filter Pleated Ceramic Fiber Diesel Particulate Filter 2005 Diesel Engine Emissions Reduction (DEER) Conference Presentations and Posters...

131

Particle Number & Particulate Mass Emissions Measurements on...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Number & Particulate Mass Emissions Measurements on a 'Euro VI' Heavy-duty Engine using the PMP Methodologies Particle Number & Particulate Mass Emissions Measurements on a 'Euro...

132

Particulate Emissions Control by Advanced Filtration Systems...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Particulate Emissions Control by Advanced Filtration Systems or GDI Engines Particulate Emissions Control by Advanced Filtration Systems or GDI Engines 2013 DOE Hydrogen and Fuel...

133

Biodiesel Fuel Property Effects on Particulate Matter Reactivity  

SciTech Connect

Controlling diesel particulate emissions to meet the 2007 U.S. standard requires the use of a diesel particulate filter (DPF). The reactivity of soot, or the carbon fraction of particulate matter, in the DPF and the kinetics of soot oxidation are important in achieving better control of aftertreatment devices. Studies showed that biodiesel in the fuel can increase soot reactivity. This study therefore investigated which biodiesel fuel properties impact reactivity. Three fuel properties of interest included fuel oxygen content and functionality, fuel aromatic content, and the presence of alkali metals. To determine fuel effects on soot reactivity, the performance of a catalyzed DPF was measured with different test fuels through engine testing and thermo-gravimetric analysis. Results showed no dependence on the aromatic content or the presence of alkali metals in the fuel. The presence and form of fuel oxygen was the dominant contributor to faster DPF regeneration times and soot reactivity.

Williams, A.; Black, S.; McCormick, R. L.

2010-06-01T23:59:59.000Z

134

6/4/2013 Page 1 of 12 Nitrogen Dioxide SOP Standard Operating Procedures  

E-Print Network (OSTI)

6/4/2013 Page 1 of 12 Nitrogen Dioxide SOP Standard Operating Procedures Nitrogen Dioxide and Nitric Oxide Print a copy and insert into your laboratory the precautions and safe handling procedures for the use of Nitrogen Dioxide

Cohen, Ronald C.

135

High Efficiency Particulate Air Filters  

NLE Websites -- All DOE Office Websites (Extended Search)

High Efficiency Particulate Air (HEPA) Filters High Efficiency Particulate Air (HEPA) Filters Home Standards DOE Workshops Nuclear Air Cleaning Conference Proceedings Qualified Filter List News Items Related Sites HEPA Related Lessons Learned Contact Us HSS Logo High Efficiency Particulate Air Filters The HEPA Filter web site provides a forum for informing and reporting department-wide activities related to filtration and ventilation issues with special reference to the High Efficiency Particulate Air (HEPA) Filters' use, inspection, and testing. This site contains essentials of DOE HEPA filter test program, procedures, requirements and quality assurance aspects applicable to HEPA filters used in DOE facilities. This site contains information about the DOE-accepted Filter Test Facility and its management, operation and quality assuranceprogram.

136

Just the Basics: Particulate Matter  

NLE Websites -- All DOE Office Websites (Extended Search)

is Particulate is Particulate Matter? One of the major components of air pollution is particulate matter, or PM. PM refers to airborne particles that include dust, dirt, soot, smoke, and liquid droplets. These particles can range in size from microscopic to large enough to be seen. PM is characterized by its size, with fine particles of less than 2.5 micrometers in size designated as PM 2.5 and coarser particles between 2.5 and 10 micrometers in size designated as PM 10 . PM arises from many sources, including combustion occurring in factories, power plants, cars, trucks, buses, trains, or wood fires; or through simple agitation of existing particulates by tilling of land, quarrying and stone-crushing, and off- road vehicular movement. Of particular interest is PM generated during diesel

137

Particulate Contaminant Descriptions and Definitions  

Science Journals Connector (OSTI)

Particulate contaminants can be either solid or liquid. Many of these materials were originally suspended in air or in a process fluid; others derive from nearby sources, such as activities of personnel working i...

Alvin Lieberman

1992-01-01T23:59:59.000Z

138

The carbon footprint analysis of wastewater treatment plants and nitrous oxide emissions from full-scale biological nitrogen removal processes in Spain  

E-Print Network (OSTI)

This thesis presents a general model for the carbon footprint analysis of advanced wastewater treatment plants (WWTPs) with biological nitrogen removal processes, using a life cycle assessment (LCA) approach. Literature ...

Xu, Xin, S.M. Massachusetts Institute of Technology

2013-01-01T23:59:59.000Z

139

Ensemble forecasting with machine learning algorithms for ozone, nitrogen dioxide and PM10 on the Prev'Air  

E-Print Network (OSTI)

Ensemble forecasting with machine learning algorithms for ozone, nitrogen dioxide and PM10'Air operational platform. This platform aims at forecasting maps, on a daily basis, for ozone, nitrogen dioxide models, ozone, nitrogen dioxide, particulate matter, threshold exceedance 1. Introduction1 Operational

Mallet, Vivien

140

Fluidizable particulate materials and methods of making same  

DOE Patents (OSTI)

The invention provides fluidizable, substantially spherical particulate material of improved attrition resistance having an average particle size from about 100 to about 400 microns useful as sorbents, catalysts, catalytic supports, specialty ceramics or the like. The particles are prepared by spray drying a slurry comprising inorganic starting materials and an organic binder. Exemplary inorganic starting materials include mixtures of zinc oxide with titanium dioxide, or with iron oxide, alumina or the like. Exemplary organic binders include polyvinyl alcohol, hydroxypropylemethyl cellulose, polyvinyl acetate and the like. The spray dried particles are heat treated at a first temperature wherein organic binder material is removed to thereby provide a porous structure to the particles, and thereafter the particles are calcined at a higher temperature to cause reaction of the inorganic starting materials and to thereby form the final inorganic particulate material.

Gupta, Raghubir P. (Durham, NC)

1999-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "nitrogen oxides particulate" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Characterization of Particulate Matter Emissions from a Common-Rail Diesel Engine  

Science Journals Connector (OSTI)

Department of Materials Science and Chemical Engineering, Politecnico di Torino, Corso Duca degli Abruzzi 24, 10129 Torino, Italy ... The preferred approach to control the emissions of diesel engines is the adoption of an exhaust gas recirculation (EGR) system followed by a diesel oxidation catalyst (DOC) in front of a diesel particulate filter (DPF). ... Some fundamental information on the particulate matter (PM) characteristics emitted by an automotive diesel engine was gathered in order to provide a precious tool for the knowledge-based design of a new generation of diesel particulate traps in the EURO VI regulation perspective. ...

D. Fino; N. Russo

2011-02-02T23:59:59.000Z

142

Electrochemical process for the preparation of nitrogen fertilizers  

DOE Patents (OSTI)

The present invention provides methods and apparatus for the preparation of nitrogen fertilizers including ammonium nitrate, urea, urea-ammonium nitrate, and/or ammonia utilizing a source of carbon, a source of nitrogen, and/or a source of hydrogen. Implementing an electrolyte serving as ionic charge carrier, (1) ammonium nitrate is produced via the reduction of a nitrogen source at the cathode and the oxidation of a nitrogen source at the anode; (2) urea or its isomers are produced via the simultaneous cathodic reduction of a carbon source and a nitrogen source; (3) ammonia is produced via the reduction of nitrogen source at the cathode and the oxidation of a hydrogen source at the anode; and (4) urea-ammonium nitrate is produced via the simultaneous cathodic reduction of a carbon source and a nitrogen source, and anodic oxidation of a nitrogen source. The electrolyte can be solid.

Aulich, Ted R.; Olson, Edwin S.; Jiang, Junhua

2013-03-19T23:59:59.000Z

143

Process for particulate removal from coal liquids  

DOE Patents (OSTI)

Suspended solid particulates are removed from liquefied coal products by first subjecting such products to hydroclone action for removal in the underflow of the larger size particulates, and then subjecting the overflow from said hydroclone action, comprising the residual finer particulates, to an electrostatic field in an electrofilter wherein such finer particulates are deposited in the bed of beads of dielectric material on said filter. The beads are periodically cleaned by backwashing to remove the accumulated solids.

Rappe, Gerald C. (Macungie, PA)

1983-01-01T23:59:59.000Z

144

Preserving Diesel Exhaust Ultrafine (Nano-) Particulate Structure...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Preserving Diesel Exhaust Ultrafine (Nano-) Particulate Structure in Genotoxicity Studies to Support Engineering Development of Emission Controls Preserving Diesel Exhaust...

145

ODD NITROGEN PROCESSES  

E-Print Network (OSTI)

including observed nitrogen dioxide, Pure Appl. Geophys,Stratosphere Observation of Nitrogen Dioxide Rates of Ozoneby photolysis of nitrogen dioxide and regeneration of ozone:

Johnston, Harold S.

2013-01-01T23:59:59.000Z

146

Durability of Diesel Particulate Filters - Bench Studies on Cordierite...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

& Publications Requirements-Driven Diesel Catalyzed Particulate Trap Design and Optimization Development of Advanced Diesel Particulate Filtration (DPF) Systems fundamental...

147

Removal of sulfur and nitrogen containing pollutants from discharge gases  

DOE Patents (OSTI)

Oxides of sulfur and of nitrogen are removed from waste gases by reaction with an unsupported copper oxide powder to form copper sulfate. The resulting copper sulfate is dissolved in water to effect separation from insoluble mineral ash and dried to form solid copper sulfate pentahydrate. This solid sulfate is thermally decomposed to finely divided copper oxide powder with high specific surface area. The copper oxide powder is recycled into contact with the waste gases requiring cleanup. A reducing gas can be introduced to convert the oxide of nitrogen pollutants to nitrogen.

Joubert, James I. (Pittsburgh, PA)

1986-01-01T23:59:59.000Z

148

Processing and Protection of Rare Earth Permanent Magnet Particulate for Bonded Magnet Applications  

SciTech Connect

Rapid solidification of novel mixed rare earth-iron-boron, MRE{sub 2}Fe{sub 14}B (MRE = Nd, Y, Dy; currently), magnet alloys via high pressure gas atomization (HPGA) have produced similar properties and structures as closely related alloys produced by melt spinning (MS) at low wheel speeds. Recent additions of titanium carbide and zirconium to the permanent magnet (PM) alloy design in HPGA powder (using He atomization gas) have made it possible to achieve highly refined microstructures with magnetic properties approaching melt spun particulate at cooling rates of 10{sup 5}-10{sup 6}K/s. By producing HPGA powders with the desirable qualities of melt spun ribbon, the need for crushing ribbon was eliminated in bonded magnet fabrication. The spherical geometry of HPGA powders is more ideal for processing of bonded permanent magnets since higher loading fractions can be obtained during compression and injection molding. This increased volume loading of spherical PM powder can be predicted to yield a higher maximum energy product (BH){sub max} for bonded magnets in high performance applications. Passivation of RE-containing powder is warranted for the large-scale manufacturing of bonded magnets in applications with increased temperature and exposure to humidity. Irreversible magnetic losses due to oxidation and corrosion of particulates is a known drawback of RE-Fe-B based alloys during further processing, e.g. injection molding, as well as during use as a bonded magnet. To counteract these effects, a modified gas atomization chamber allowed for a novel approach to in situ passivation of solidified particle surfaces through injection of a reactive gas, nitrogen trifluoride (NF{sub 3}). The ability to control surface chemistry during atomization processing of fine spherical RE-Fe-B powders produced advantages over current processing methodologies. In particular, the capability to coat particles while 'in flight' may eliminate the need for post atomization treatment, otherwise a necessary step for oxidation and corrosion resistance. Stability of these thin films was attributed to the reduction of each RE's respective oxide during processing; recognizing that fluoride compounds exhibit a slightly higher (negative) free energy driving force for formation. Formation of RE-type fluorides on the surface was evidenced through x-ray photoelectron spectroscopy (XPS). Concurrent research with auger electron spectroscopy has been attempted to accurately quantify the depth of fluoride formation in order to grasp the extent of fluorination reactions with spherical and flake particulate. Gas fusion analysis on coated powders (dia. <45 {micro}m) from an optimized experiment indicated an as-atomized oxygen concentration of 343ppm, where typical, nonpassivated RE atomized alloys exhibit an average of 1800ppm oxygen. Thermogravimetric analysis (TGA) on the same powder revealed a decreased rate of oxidation at elevated temperatures up to 300 C, compared to similar uncoated powder.

Peter Kelly Sokolowski

2007-12-01T23:59:59.000Z

149

Tropospheric Reactive Nitrogen Speciation, Deposition, and Chemistry at Harvard Forest  

E-Print Network (OSTI)

and absolute contributions of nitric acid (HNO3) and NOx (nitric oxide (NO) + nitrogen dioxide (NO2)) to totalTropospheric Reactive Nitrogen Speciation, Deposition, and Chemistry at Harvard Forest A thesis. Steven C. Wofsy Cassandra Volpe Horii Tropospheric Reactive Nitrogen Speciation, Deposition

150

Thermodynamic Analysis of the Possibility of Hydrogen Production by Oxidation of n-Butane, n-Pentane, and Carbon by Oxygen-Containing Nitrogen Compounds  

Science Journals Connector (OSTI)

A thermodynamic analysis is performed to study the reactions of hydrogen production by oxidation of hydrocarbons of natural gas ... analysis suggests the possibility of developing a new hydrogen production method

A. M. Alekseev; Z. V. Komova; L. L. Klinova…

2003-07-01T23:59:59.000Z

151

Development of a Spectroscopic Technique for Continuous Online Monitoring of Oxygen and Site-Specific Nitrogen Isotopic Composition of Atmospheric Nitrous Oxide  

E-Print Network (OSTI)

Nitrous oxide is an important greenhouse gas and ozone-depleting-substance. Its sources are diffuse and poorly characterized, complicating efforts to understand anthropogenic impacts and develop mitigation policies. Online, ...

Harris, Eliza

152

Innovative Clean Coal Technology (ICCT): 180 MW demonstration of advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from coal-fired boilers. Technical progress report, third quarter 1991  

SciTech Connect

This quarterly report discusses the technical progress of a US Department of Energy (DOE) Innovative Clean Coal Technology (ICCT) Project demonstrating advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from a coal-fired boiler. The project is being conducted at Gulf Power Company`s Plant Lansing Smith Unit 2 located near Panama City, Florida. The primary objective of this demonstration is to determine the long-term effects of commercially available tangentially-fired low NO{sub x} combustion technologies on NO{sub x} emissions and boiler performance. A target of achieving fifty percent NO{sub x} reduction using combustion modifications has been established for the project.

Not Available

1992-02-03T23:59:59.000Z

153

Innovative Clean Coal Technology (ICCT): 180 MW demonstration of advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NO sub x ) emissions from coal-fired boilers  

SciTech Connect

This quarterly report discusses the technical progress of a US Department of Energy (DOE) Innovative Clean Coal Technology (ICCT) Project demonstrating advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from a coal-fired boiler. The project is being conducted at Gulf Power Company's Plant Lansing Smith Unit 2 located near Panama City, Florida. The primary objective of this demonstration is to determine the long-term effects of commercially available tangentially-fired low NO{sub x} combustion technologies on NO{sub x} emissions and boiler performance. A target of achieving fifty percent NO{sub x} reduction using combustion modifications has been established for the project.

Not Available

1992-02-03T23:59:59.000Z

154

Demonstration of selective catalytic reduction (SCR) technology for the control of nitrogen oxide (NO{sub x}) emissions from high-sulfur coal-fired boilers. Quarterly report No. 8, April--June, 1992  

SciTech Connect

The objective of this project is to demonstrate and evaluate commercially available Selective Catalytic Reduction (SCR) catalysts from US, Japanese and European catalyst suppliers on a high-sulfur US coal-fired boiler. SCR is a post-combustion nitrogen oxide (NO{sub x}) control technology that involves injecting ammonia into the flue gas generated from coal combustion in an electric utility boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NO{sub x} to convert it to nitrogen and water vapor. Although SCR is widely practiced in Japan and Europe, there are numerous technical uncertainties associated with applying SCR to US coals. These uncertainties include: (1) potential catalyst deactivation due to poisoning by trace metal species present in US coals that are not present in other fuels. (2) performance of the technology and effects on the balance-of-plant equipment in the presence of high amounts of SO{sub 2} and SO{sub 3}. (3) performance of a wide variety of SCR catalyst compositions, geometries and methods of manufacture under typical high-sulfur coal-fired utility operating conditions. These uncertainties will be explored by constructing a series of small-scale SCR reactors and simultaneously exposing different SCR catalysts to flue gas derived from the combustion of high sulfur U. S. coal.

Not Available

1992-08-01T23:59:59.000Z

155

Innovative clean coal technology (ICCT): Demonstration of selective catalytic reduction (SCR) technology for the control of nitrogen oxide (NO{sub x}) emissions from high-sulfur coal-fired boilers. Fourth quarterly progress report  

SciTech Connect

The objective of this project is to demonstrate and evaluate commercially available Selective Catalytic Reduction (SCR) catalysts from US, Japanese and European catalyst suppliers on a high-sulfur US coal-fired boiler. SCR is a post-combustion nitrogen oxide (NO{sub x}) control technology that involves injecting ammonia into the flue gas generated from coal combustion in an electric utility boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NO{sub x} to convert it to nitrogen and water vapor. Although SCR is widely practiced in Japan and Europe, there are numerous technical uncertainties include: (1) potential catalyst deactivation due to poisoning by trace metal species present in US coals that are not present in other fuels; (2) performance of the technology and effects on the balance-of-plant equipment in the presence of high amounts of SO{sub 2} and SO{sub 3}; and (3) performance of a wide variety of SCR catalyst compositions, geometries and methods of manufacture under typical high-sulfur coal-fired utility operating conditions. These uncertainties will be explored by constructing a series of small-scale SCR reactors and simultaneously exposing different SCR catalysts to flue gas derived from the combustion of high sulfur US coal.

NONE

1992-12-31T23:59:59.000Z

156

Investigation of mixed metal sorbent/catalysts for the simultaneous removal of sulfur and nitrogen oxides. Semiannual report, Apr 1, 1998--Oct 31, 1998  

SciTech Connect

Simultaneous removal of SO{sub 2} and NO{sub x} using a regenerable solid sorbent will constitute an important improvement over the use of separate processes for the removal of these two pollutants from stack gases and possibly eliminate several shortcomings of the individual SO{sub 2} and NO{sub x} removal operations. The work done at PETC and the DOE-funded investigation of the investigators on the sulfation and regeneration of alumina-supported cerium oxide sorbents have shown that they can perform well at relatively high temperatures (823--900 K) as regenerable desulfurization sorbents. Survey of the recent literature shows that addition of copper oxide to ceria lowers the sulfation temperature of ceria down to 773 K, sulfated ceria-based sorbents can function as selective SCR catalysts even at elevated temperatures, SO{sub 2} can be directly reduced to sulfur by CO on CuO-ceria catalysts, and ceria-based catalysts may have a potential for selective catalytic reduction of NO{sub x} by methane. These observations indicate a possibility of developing a ceria-based sorbent/catalyst which can remove both SO{sub 2} and NO{sub x} from flue gases within a relatively wide temperature window, produce significant amounts of elemental sulfur during regeneration, and use methane for the selective catalytic reduction of NO{sub x}. The objective of this research is to conduct kinetic and parametric studies of the selective catalytic reduction of NO{sub x} with NH{sub 3} and CH{sub 4} over alumina-supported cerium oxide and copper oxide-cerium oxide sorbent/catalysts; investigate SO{sub 2} removal at lower temperatures by supported copper oxide-cerium oxide sorbents; and investigate the possibility of elemental sulfur production during regeneration with CO or with CH{sub 4} air mixtures. The sorbents consisting of cerium oxide and copper oxide impregnated on alumina have been prepared and characterized. Their sulfation performance has been investigated in a TGA setup, studying mainly the effects of temperature and sorbent composition. The results of the sulfation experiments have been evaluated and presented in this report. A study to model the sulfation selectivity of the two constituents of the sorbents is also underway.

Dr. Ates Akyurtlu; Dr. Jale F. Akyurtlu

1998-10-31T23:59:59.000Z

157

Diesel particulate filter with zoned resistive heater  

DOE Patents (OSTI)

A diesel particulate filter assembly comprises a diesel particulate filter (DPF) and a heater assembly. The DPF filters a particulate from exhaust produced by an engine. The heater assembly has a first metallic layer that is applied to the DPF, a resistive layer that is applied to the first metallic layer, and a second metallic layer that is applied to the resistive layer. The second metallic layer is etched to form a plurality of zones.

Gonze, Eugene V [Pinckney, MI

2011-03-08T23:59:59.000Z

158

Zone heated diesel particulate filter electrical connection  

DOE Patents (OSTI)

An electrical connection system for a particulate filter is provided. The system includes: a particulate filter (PF) disposed within an outer shell wherein the PF is segmented into a plurality of heating zones; an outer mat disposed between the particulate filter and the outer shell; an electrical connector coupled to the outer shell of the PF; and a plurality of printed circuit connections that extend along the outer surface of the PF from the electrical connector to the plurality of heating zones.

Gonze, Eugene V. (Pinckney, MI); Paratore, Jr., Michael J. (Howell, MI)

2010-03-30T23:59:59.000Z

159

Quantum-chemical investigation of the interaction of nitrogen and carbon monoxide molecules with the Lewis acid sites of aluminium oxide  

SciTech Connect

Within the framework of the cluster approximation, using covalent and ionic models of Lewis acid sites of aluminumoxide, their electronic structure, as well as that of complexes of nitrogen and carbon monoxide molecules with them, was calculated. It was shown that the Lewis acid sites, representing a truncated tetrahedron, exhibit stronger electron-acceptor properties than the corresponding sites in the form of a truncated octahedron. For both molecules, the linear form of adsorption is energetically more profitable than the T-shaped form. The results obtained by the nonempirical SCF MO LCAO method in the STO-3GF basis and by semiempirical methods in CNDO/2 and INDO approximatations, are qualitatively the same.

Senchenya, I.N.; Chuvylkin, N.D.; Kazanskii, V.B.

1986-11-01T23:59:59.000Z

160

Electrically-Assisted Diesel Particulate Filter Regeneration...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Evaluation pm041lance2011p.pdf More Documents & Publications Electrically-Assisted Diesel Particulate Filter Regeneration Substrate Studies of an Electrically-Assisted Diesel...

Note: This page contains sample records for the topic "nitrogen oxides particulate" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Electrically heated particulate filter embedded heater design  

DOE Patents (OSTI)

An exhaust system that processes exhaust generated by an engine is provided. The system generally includes a particulate filter (PF) that filters particulates from the exhaust wherein an upstream end of the PF receives exhaust from the engine and wherein an upstream surface of the particulate filter includes machined grooves. A grid of electrically resistive material is inserted into the machined grooves of the exterior upstream surface of the PF and selectively heats exhaust passing through the grid to initiate combustion of particulates within the PF.

Gonze, Eugene V.; Chapman, Mark R.

2014-07-01T23:59:59.000Z

162

Electrically heated particulate filter using catalyst striping  

DOE Patents (OSTI)

An exhaust system that processes exhaust generated by an engine is provided. The system generally includes a particulate filter (PF) that filters particulates from the exhaust wherein an upstream end of the PF receives exhaust from the engine. A grid of electrically resistive material is applied to an exterior upstream surface of the PF and selectively heats exhaust passing through the grid to initiate combustion of particulates within the PF. A catalyst coating is applied to the PF that increases a temperature of the combustion of the particulates within the PF.

Gonze, Eugene V; Paratore, Jr., Michael J; Ament, Frank

2013-07-16T23:59:59.000Z

163

Methods of separating particulate residue streams  

DOE Patents (OSTI)

A particulate residue separator and a method for separating a particulate residue stream may include an air plenum borne by a harvesting device, and have a first, intake end and a second, exhaust end; first and second particulate residue air streams that are formed by the harvesting device and that travel, at least in part, along the air plenum and in a direction of the second, exhaust end; and a baffle assembly that is located in partially occluding relation relative to the air plenum and that substantially separates the first and second particulate residue air streams.

Hoskinson, Reed L. (Rigby, ID); Kenney, Kevin L. (Idaho Falls, ID); Wright, Christopher T. (Idaho Falls, ID); Hess, J. Richard (Idaho Falls, ID)

2011-04-05T23:59:59.000Z

164

Demonstration of Selective Catalytic Reduction (SCR) technology for the control of nitrogen oxide (NO{sub x}) emissions from high-sulfur coal-fired boilers. Technical progress report, first and second quarters 1994  

SciTech Connect

The objective of this project is to demonstrate and evaluate commercially available Selective Catalytic Reduction (SCR) catalysts from U.S., Japanese and European catalyst suppliers on a high-sulfur U.S. coal-fired boiler. SCR is a post-combustion nitrogen oxide (NO{sub x}) control technology that involve injecting ammonia into the flue gas generated from coal combustion in a boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NO{sub x} to form nitrogen and water vapor. Although SCR is widely practiced in Japan and Europe on gas-, oil-, and low-sulfur coal-fired boilers, there are several technical uncertainties associated with applying SCR to U.S. coals. These uncertainties include: (1) potential catalyst deactivation due to poisoning by trace metal species present in U.S. coals that are not present in other fuels; (2) performance of the technology and effects on the balance-of-plant equipment in the presence of high amounts of SO{sub 2} and SO{sub 3}; and (3) performance of a wide variety of SCR catalyst compositions, geometries and methods of manufacture under typical high-sulfur coal-fired utility operating conditions. These uncertainties are being explored by operating a series of small-scale SCR reactors and simultaneously exposing different SCR catalysts to flue gas derived from the combustion of high sulfur U.S. coal. The project is being conducted in the following three phases: permitting, environmental monitoring plan and preliminary engineering; detailed design engineering and construction; and operation, testing, disposition and final report. The project was in the operation and testing phase during this reporting period. Accomplishments for this period are described.

NONE

1995-11-01T23:59:59.000Z

165

Lignite-based nitrogenous fertilizers  

SciTech Connect

A sample of lignite from Elbistan was oxidized by nitric acid in two stages, using relatively dilute acid in the first stage and concentrated acid in the second stage, and then the oxidized product was ammoniated so that a coal-based fertilizer could be produced. The experiments of all the stages were designed by a 1/2 X full factorial design. It was observed that base exchange capacity and nitrogen content of coal-based fertilizers produced in this work were as good as or better than those obtained by other investigators.

Baris, H.; Dincer, S.

1983-01-01T23:59:59.000Z

166

Edinburgh Research Explorer Pulmonary diesel particulate increases susceptibility to  

E-Print Network (OSTI)

Edinburgh Research Explorer Pulmonary diesel particulate increases susceptibility to myocardial, MR & Gray, GA 2014, 'Pulmonary diesel particulate increases susceptibility to myocardial ischemia. Pulmonary diesel particulate increases susceptibility to myocardial ischemia/reperfusion injury via

Millar, Andrew J.

167

Advanced particulate matter control apparatus and methods  

DOE Patents (OSTI)

Apparatus and methods for collection and removal of particulate matter, including fine particulate matter, from a gas stream, comprising a unique combination of high collection efficiency and ultralow pressure drop across the filter. The apparatus and method utilize simultaneous electrostatic precipitation and membrane filtration of a particular pore size, wherein electrostatic collection and filtration occur on the same surface.

Miller, Stanley J. (Grand Forks, ND); Zhuang, Ye (Grand Forks, ND); Almlie, Jay C. (East Grand Forks, MN)

2012-01-10T23:59:59.000Z

168

Detailed Assessment of Particulate Characteristics from Low-Temperatur...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Detailed Assessment of Particulate Characteristics from Low-Temperature Combustion Engines Detailed Assessment of Particulate Characteristics from Low-Temperature Combustion...

169

Development of SCR on Diesel Particulate Filter System for Heavy...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

SCR on Diesel Particulate Filter System for Heavy Duty Applications Development of SCR on Diesel Particulate Filter System for Heavy Duty Applications Evaluation of a system...

170

Update on 2007 Diesel Particulate Measurement Research | Department...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

2007 Diesel Particulate Measurement Research Update on 2007 Diesel Particulate Measurement Research 2005 Diesel Engine Emissions Reduction (DEER) Conference Presentations and...

171

Expanded Capacity Microwave-Cleaned Diesel Particulate Filter...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Expanded Capacity Microwave-Cleaned Diesel Particulate Filter Expanded Capacity Microwave-Cleaned Diesel Particulate Filter 2002 DEER Conference Presentation: Industrial Ceramic...

172

Predicting Thermal Stress in Diesel Particulate Filters | Department...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Thermal Stress in Diesel Particulate Filters Predicting Thermal Stress in Diesel Particulate Filters 2004 Diesel Engine Emissions Reduction (DEER) Conference Presentation: Corning...

173

The State of the Science in Diesel Particulate Control | Department...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

The State of the Science in Diesel Particulate Control The State of the Science in Diesel Particulate Control 2005 Diesel Engine Emissions Reduction (DEER) Conference Presentations...

174

A New CFD Model for understanding and Managing Diesel Particulate...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

& Publications Substrate Studies of an Electrically-Assisted Diesel Particulate Filter Diesel Particulate Filter: A Success for Faurecia Exhaust Systems Vehicle Evaluation of...

175

Ultra-Lite Diesel Particulate Filter Cartridge for Reduced Regeneratio...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Lite Diesel Particulate Filter Cartridge for Reduced Regeneration Time and Fuel Consumption Ultra-Lite Diesel Particulate Filter Cartridge for Reduced Regeneration Time and Fuel...

176

Neutron Imaging of Diesel Particulate Filters | Department of...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Neutron Imaging of Diesel Particulate Filters Neutron Imaging of Diesel Particulate Filters Neutron computed tomography shows soot and ash loading in a cordierite diesel...

177

Local Soot Loading Distribution in Cordierite Diesel Particulate...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Local Soot Loading Distribution in Cordierite Diesel Particulate Filters by Dynamic Neutron Radiography Local Soot Loading Distribution in Cordierite Diesel Particulate Filters by...

178

Non-Destructive Neutron Imaging to Analyze Particulate Filters...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Neutron Imaging to Analyze Particulate Filters Non-Destructive Neutron Imaging to Analyze Particulate Filters Non-destructive, non-invasive imaging is being employed in the...

179

Durability of Diesel Engine Particulate Filters (Agreement ID...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Durability of Diesel Engine Particulate Filters (Agreement ID:10461) Durability of Diesel Engine Particulate Filters (Agreement ID:10461) 2013 DOE Hydrogen and Fuel Cells Program...

180

Improvement and Simplification of Diesel Particulate Filter System...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

and Simplification of Diesel Particulate Filter System using a Ceria-Based Fuel-Borne Catalyst in Serial Applications Improvement and Simplification of Diesel Particulate Filter...

Note: This page contains sample records for the topic "nitrogen oxides particulate" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Reduction of Transient Particulate Matter Spikes with Decision...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Transient Particulate Matter Spikes with Decision Tree Based Control Reduction of Transient Particulate Matter Spikes with Decision Tree Based Control Using a non-parametric...

182

Final Report: Particulate Emissions Testing, Unit 1, Potomac...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Final Report: Particulate Emissions Testing, Unit 1, Potomac River Generating Station, Alexandria, Virginia Final Report: Particulate Emissions Testing, Unit 1, Potomac River...

183

Vehicle Technologies Office Merit Review 2014: Particulate Emissions...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Particulate Emissions Control by Advanced Filtration Systems for GDI Engines Vehicle Technologies Office Merit Review 2014: Particulate Emissions Control by Advanced Filtration...

184

Optical Backscatter Probe for Sensing Particulate Matter - Energy...  

NLE Websites -- All DOE Office Websites (Extended Search)

particulate concentration is then determined by measuring the amount of backscattered light transmitted by particulate matter contained in a sample of engine exhaust. The speed...

185

Partial oxidation process for producing a stream of hot purified gas  

DOE Patents (OSTI)

A partial oxidation process for the production of a stream of hot clean gas substantially free from particulate matter, ammonia, alkali metal compounds, halides and sulfur-containing gas for use as synthesis gas, reducing gas, or fuel gas. A hydrocarbonaceous fuel comprising a solid carbonaceous fuel with or without liquid hydrocarbonaceous fuel or gaseous hydrocarbon fuel, wherein said hydrocarbonaceous fuel contains halides, alkali metal compounds, sulfur, nitrogen and inorganic ash containing components, is reacted in a gasifier by partial oxidation to produce a hot raw gas stream comprising H.sub.2, CO, CO.sub.2, H.sub.2 O, CH.sub.4, NH.sub.3, HCl, HF, H.sub.2 S, COS, N.sub.2, Ar, particulate matter, vapor phase alkali metal compounds, and molten slag. The hot raw gas stream from the gasifier is split into two streams which are separately deslagged, cleaned and recombined. Ammonia in the gas mixture is catalytically disproportionated into N.sub.2 and H.sub.2. The ammonia-free gas stream is then cooled and halides in the gas stream are reacted with a supplementary alkali metal compound to remove HCl and HF. Alkali metal halides, vaporized alkali metal compounds and residual fine particulate matter are removed from the gas stream by further cooling and filtering. The sulfur-containing gases in the process gas stream are then reacted at high temperature with a regenerable sulfur-reactive mixed metal oxide sulfur sorbent material to produce a sulfided sorbent material which is then separated from the hot clean purified gas stream having a temperature of at least 1000.degree. F.

Leininger, Thomas F. (Chino Hills, CA); Robin, Allen M. (Anaheim, CA); Wolfenbarger, James K. (Torrance, CA); Suggitt, Robert M. (Wappingers Falls, NY)

1995-01-01T23:59:59.000Z

186

Selective catalytic reduction of nitrogen oxides by ammonia over Fe{sup 3+}-exchanged TiO{sub 2}-pillared clay catalysts  

SciTech Connect

Fe-exchanged TiO{sub 2}-pillared clay (PILC) catalysts were prepared and used for selective catalytic reduction (SCR) of NO{sub x} by ammonia. They were also characterized for surface area, pore size distribution, and by XRD, H{sub 2}-TPR, and FT-IR methods. The Fe-TiO{sub 2}-PILC catalysts showed high activities in the reduction of NO{sub x} by NH{sub 3} in the presence of excess oxygen. SO{sub 2} further increased the catalytic activities at above 350 C, whereas H{sub 2}O decreased the activity slightly. The catalysts were about twice as active as commercial-type V{sub 2}O{sub 5}-WO{sub 3}/TiO{sub 2} catalyst in the presence of H{sub 2}O and SO{sub 2}. Moreover, compared to the commercial catalyst, the Fe-TiO{sub 2}-PILC catalysts had higher N{sub 2}/N{sub 2}O product selectivities (e.g., 0--1% vs 9% N{sub 2}O at 400 C) and substantially lower activities (by 74--88%) for SO{sub 2} oxidation to SO{sub 3} under the same reaction conditions. The activity was further increased to over three times that of the vanadia-based catalyst when Ce was added. The high activity and low N{sub 2}O selectivity for the Fe-TiO{sub 2}-PILC catalysts were attributed to their low activity in the oxidation of ammonia, as compared with vanadia catalysts. XRD patterns of Fe-TiO{sub 2}-PILC were similar to those of TiO{sub 2}-PILC, showing no peaks due to iron oxide, even when the iron content reached 20.1%. The TPR results indicated that iron in the Fe-TiO{sub 2}-PILC catalysts with lower iron contents existed in the form of isolated Fe{sup 3+} ions. The activities of Fe-TiO{sub 2}-PILC catalysts were consistent with their surface acidities, which were identified by FT-IR of the NH{sub 3}-adsorbed samples. The enhancement of activities by H{sub 2}O + SO{sub 2} was attributed to the increase of surface acidity resulting from the formation of surface sulfate species of iron.

Long, R.Q.; Yang, R.T. [Univ. of Michigan, Ann Arbor, MI (United States). Dept. of Chemical Engineering] [Univ. of Michigan, Ann Arbor, MI (United States). Dept. of Chemical Engineering

1999-09-10T23:59:59.000Z

187

Energy Efficiency in Regulated and Deregulated Markets  

E-Print Network (OSTI)

health effects of nitrogen and sulfur oxides; ozone; large sized, 10 microns and greater, particulate matter from fossil fuel

Rotenberg, Edan

2005-01-01T23:59:59.000Z

188

The Nitrogen-Nitride Anode.  

SciTech Connect

Nitrogen gas N 2 can be reduced to nitride N -3 in molten LiCl-KCl eutectic salt electrolyte. However, the direct oxidation of N -3 back to N 2 is kinetically slow and only occurs at high overvoltage. The overvoltage for N -3 oxidation can be eliminated by coordinating the N -3 with BN to form the dinitridoborate (BN 2 -3 ) anion which forms a 1-D conjugated linear inorganic polymer with -Li-N-B-N- repeating units. This polymer precipitates out of solution as Li 3 BN 2 which becomes a metallic conductor upon delithiation. Li 3 BN 2 is oxidized to Li + + N 2 + BN at about the N 2 /N -3 redox potential with very little overvoltage. In this report we evaluate the N 2 /N -3 redox couple as a battery anode for energy storage.

Delnick, Frank M.

2014-10-01T23:59:59.000Z

189

Development of a Low-Cost Particulate Matter Monitor  

E-Print Network (OSTI)

Forward-looking infrared (FLIR) images taken as a singleforward-looking infrared (FLIR) instrumentation. Particulate

White, Richard M.

2010-01-01T23:59:59.000Z

190

Particulate matter in the south Atlantic Ocean  

E-Print Network (OSTI)

The particulate matter (PM) distribution in the south Atlantic Ocean and its relationship to water masses and currents were determined from optical and hydrographic data. Attenuation coefficients were obtained by interfacing a beam transmissometer...

Wood, Megan Maria

2012-06-07T23:59:59.000Z

191

Investigation of Direct Injection Vehicle Particulate Matter...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Emissions This study focuses primarily on particulate matter mass analysis of a gasoline direct injection engine in a test cell with a chassis dynamometer. p-10gibbs.pdf...

192

E-Print Network 3.0 - atrbohd-mediated oxidative burst Sample...  

NLE Websites -- All DOE Office Websites (Extended Search)

Extinction Brandon Lohman Summary: triggered by cosmic events. A high intensity gamma ray burst directed toward Earth may have irradiated our... of nitrogen oxides. These oxides...

193

NETL: Control Technology: Advanced Hybrid Particulate Collector  

NLE Websites -- All DOE Office Websites (Extended Search)

Advanced Hybrid Particulate Collector Advanced Hybrid Particulate Collector Under DOE-NETL sponsorship, the University of North Dakota, Energy and Environmental Research Center (UND-EERC) has developed a new concept in particulate control, called an advanced hybrid particulate collector (AHPC). In addition to DOE and the EERC, the project team includes W.L. Gore & Associates, Inc., Allied Environmental Technologies, Inc., and the Otter Tail Power Company. The AHPC utilizes both electrostatic collection and filtration in a unique geometric configuration that achieves ultrahigh particle collection with much less collection area than conventional particulate control devices. The primary technologies for state-of-the-art particulate control are fabric filters (baghouses) and electrostatic precipitators (ESPs). A major limitation of ESPs is that the fractional penetration of 0.1- to 1.0-µm particles is typically at least an order of magnitude greater than for 10-µm particles, so a situation exists where the particles that are of greatest health concern are collected with the lowest efficiency. Fabric filters are currently considered to be the best available control technology for fine particles, but emissions are dependent on ash properties and typically increase if the air-to-cloth (A/C) ratio is increased. In addition, many fabrics cannot withstand the rigors of high-SO2 flue gases, which are typical for bituminous fuels. Fabric filters may also have problems with bag cleanability and high pressure drop, which has resulted in conservatively designed, large, costly baghouses.

194

Process for the conversion of carbonaceous feedstocks to particulate carbon and methanol  

DOE Patents (OSTI)

A process is described for the production of a pollutant-free particulate carbon (i.e., a substantially ash-, sulfur- and nitrogen-free carbon) from carbonaceous feedstocks. The basic process involves de-oxygenating one of the gas streams formed in a cyclic hydropyrolysis-methane pyrolysis process in order to improve conversion of the initial carbonaceous feedstock. De-oxygenation is effected by catalytically converting carbon monoxide, carbon dioxide, and hydrogen contained in one of the pyrolysis gas streams, preferably the latter, to a methanol co-product. There are thus produced two products whose use is known per se, viz., a substantially pollutant-free particulate carbon black and methanol. These products may be admixed in the form of a liquid slurry of carbon black in methanol. 3 figs.

Steinberg, M.; Grohse, E.W.

1995-06-27T23:59:59.000Z

195

Process for the conversion of carbonaceous feedstocks to particulate carbon and methanol  

DOE Patents (OSTI)

A process for the production of a pollutant-free particulate carbon (i.e., a substantially ash-, sulfur- and nitrogen-free carbon) from carbonaceous feedstocks. The basic process involves de-oxygenating one of the gas streams formed in a cyclic hydropyrolysis-methane pyrolysis process in order to improve conversion of the initial carbonaceous feedstock. De-oxygenation is effected by catalytically converting carbon monoxide, carbon dioxide, and hydrogen contained in one of the pyrolysis gas streams, preferably the latter, to a methanol co-product. There are thus produced two products whose use is known per se, viz., a substantially pollutant-free particulate carbon black and methanol. These products may be admixed in the form of a liquid slurry of carbon black in methanol.

Steinberg, Meyer (Melville, NY); Grohse, Edward W. (Port Jefferson, NY)

1995-01-01T23:59:59.000Z

196

Nitrogen dioxide detection  

DOE Patents (OSTI)

Method and apparatus for detecting the presence of gaseous nitrogen dioxide and determining the amount of gas which is present. Though polystyrene is normally an insulator, it becomes electrically conductive in the presence of nitrogen dioxide. Conductance or resistance of a polystyrene sensing element is related to the concentration of nitrogen dioxide at the sensing element.

Sinha, Dipen N. (Los Alamos, NM); Agnew, Stephen F. (Los Alamos, NM); Christensen, William H. (Buena Park, CA)

1993-01-01T23:59:59.000Z

197

Electrochemical process for the preparation of nitrogen fertilizers  

DOE Patents (OSTI)

The present invention provides methods and apparatus for the preparation of nitrogen fertilizers including ammonium nitrate, urea, urea-ammonium nitrate, and/or ammonia, at low temperature and pressure, preferably at ambient temperature and pressure, utilizing a source of carbon, a source of nitrogen, and/or a source of hydrogen or hydrogen equivalent. Implementing an electrolyte serving as ionic charge carrier, (1) ammonium nitrate is produced via the reduction of a nitrogen source at the cathode and the oxidation of a nitrogen source at the anode; (2) urea or its isomers are produced via the simultaneous cathodic reduction of a carbon source and a nitrogen source; (3) ammonia is produced via the reduction of nitrogen source at the cathode and the oxidation of a hydrogen source or a hydrogen equivalent such as carbon monoxide or a mixture of carbon monoxide and hydrogen at the anode; and (4) urea-ammonium nitrate is produced via the simultaneous cathodic reduction of a carbon source and a nitrogen source, and anodic oxidation of a nitrogen source. The electrolyte can be aqueous, non-aqueous, or solid.

Aulich, Ted R. (Grand Forks, ND); Olson, Edwin S. (Grand Forks, ND); Jiang, Junhua (Grand Forks, ND)

2012-04-10T23:59:59.000Z

198

Reading Comprehension - Liquid Nitrogen  

NLE Websites -- All DOE Office Websites (Extended Search)

Liquid Nitrogen Liquid Nitrogen Nitrogen is the most common substance in Earth's _________ crust oceans atmosphere trees . In the Earth's atmosphere, nitrogen is a gas. The particles of a gas move very quickly. They run around and bounce into everyone and everything. The hotter a gas is, the _________ slower faster hotter colder the particles move. When a gas is _________ cooled warmed heated compressed , its particles slow down. If a gas is cooled enough, it can change from a gas to a liquid. For nitrogen, this happens at a very _________ strange warm low high temperature. If you want to change nitrogen from a gas to a liquid, you have to bring its temperature down to 77 Kelvin. That's 321 degrees below zero _________ Kelvin Celsius Centigrade Fahrenheit ! Liquid nitrogen looks like water, but it acts very differently. It

199

Method of dispersing particulate aerosol tracer  

DOE Patents (OSTI)

A particulate aerosol tracer which comprises a particulate carrier of sheet silicate composition having a particle size up to one micron, and a cationic dopant chemically absorbed in solid solution in the carrier. The carrier is preferably selected from the group consisting of natural mineral clays such as bentonite, and the dopant is selected from the group consisting of rare earth elements and transition elements. The tracers are dispersed by forming an aqueous salt solution with the dopant present as cations, dispersing the carriers in the solution, and then atomizing the solution under heat sufficient to superheat the solution droplets at a level sufficient to prevent reagglomeration of the carrier particles.

O'Holleran, Thomas P. (Belleville, MI)

1988-01-01T23:59:59.000Z

200

Particulate hot gas stream cleanup technical issues  

SciTech Connect

The analyses of hot gas stream cleanup particulate samples and descriptions of filter performance studied under this contract were designed to address problems with filter operation that have been linked to characteristics of the collected particulate matter. One objective of this work was to generate an interactive, computerized data bank of the key physical and chemical characteristics of ash and char collected from operating advanced particle filters and to relate these characteristics to the operation and performance of these filters. The interactive data bank summarizes analyses of over 160 ash and char samples from fifteen pressurized fluidized-bed combustion and gasification facilities utilizing high-temperature, high pressure barrier filters.

Pontius, D.H.; Snyder, T.R.

1999-09-30T23:59:59.000Z

Note: This page contains sample records for the topic "nitrogen oxides particulate" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

The global nitrogen cycle in the twenty-first century  

Science Journals Connector (OSTI)

...better known than natural fixation, in part...industrial sources. The gases created are the oxidized...derived from the natural or anthropogenic...exchange between semi-natural vegetation and the...of the greenhouse gas nitrous oxide. Phil...2013 The nitrogen cascade from agricultural...

2013-01-01T23:59:59.000Z

202

In Vitro Genotoxicity of Particulate and Semi-Volatile Organic...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Particulate and Semi-Volatile Organic Compound Exhaust Materails from a Set of Gasoline and a Set of Diesel Engine Vehicles Operated at 30F In Vitro Genotoxicity of Particulate...

203

Next Generation Non-particulate Dry Nonwoven Pad for Chemical Warfare Agent Decontamination  

SciTech Connect

New, non-particulate decontamination materials promise to reduce both military and civilian casualties by enabling individuals to decontaminate themselves and their equipment within minutes of exposure to chemical warfare agents or other toxic materials. One of the most promising new materials has been developed using a needlepunching nonwoven process to construct a novel and non-particulate composite fabric of multiple layers, including an inner layer of activated carbon fabric, which is well-suited for the decontamination of both personnel and equipment. This paper describes the development of a composite nonwoven pad and compares efficacy test results for this pad with results from testing other decontamination systems. The efficacy of the dry nonwoven fabric pad was demonstrated specifically for decontamination of the chemical warfare blister agent bis(2-chloroethyl)sulfide (H or sulfur mustard). GC/MS results indicate that the composite fabric was capable of significantly reducing the vapor hazard from mustard liquid absorbed into the nonwoven dry fabric pad. The mustard adsorption efficiency of the nonwoven pad was significantly higher than particulate activated carbon (p=0.041) and was similar to the currently fielded US military M291 kit (p=0.952). The nonwoven pad has several advantages over other materials, especially its non-particulate, yet flexible, construction. This composite fabric was also shown to be chemically compatible with potential toxic and hazardous liquids, which span a range of hydrophilic and hydrophobic chemicals, including a concentrated acid, an organic solvent and a mild oxidant, bleach.

Ramkumar, S S; Love, A; Sata, U R; Koester, C J; Smith, W J; Keating, G A; Hobbs, L; Cox, S B; Lagna, W M; Kendall, R J

2008-05-01T23:59:59.000Z

204

Electrically heated particulate filter preparation methods and systems  

DOE Patents (OSTI)

A control system that controls regeneration of a particulate filter is provided. The system generally includes a fuel control module that controls injection of fuel into exhaust that passes through the particulate filter. A regeneration module controls current to the particulate filter to initiate regeneration after the fuel has been injected into the exhaust.

Gonze, Eugene V [Pinckney, MI

2012-01-31T23:59:59.000Z

205

Microscopy investigations of ash and particulate matter accumulation in diesel particulate filter surface pores  

E-Print Network (OSTI)

There has been increased focus on the environmental impact of automobile emissions in recent years. These environmental concerns have resulted in the creation of more stringent particulate matter emissions regulations in ...

Beauboeuf, Daniel P

2010-01-01T23:59:59.000Z

206

Monolithic Nickel (II) Oxide Aerogels Using an Organic Epoxide: The Importance of the Counter Ion  

SciTech Connect

The synthesis and characterization of nickel (II) oxide aerogel materials prepared using the epoxide addition method is described. The addition of the organic epoxide propylene oxide to an ethanolic solution of NiCl{sub 2} 6H{sub 2}O resulted in the formation of an opaque light green monolithic gel and subsequent drying with supercritical CO{sub 2} gave a monolithic aerogel material of the same color. This material has been characterized using powder X-ray diffraction, electron microscopy, elemental analysis, and nitrogen adsorption/desorption analysis. The results indicate that the nickel (II) oxide aerogel has very low bulk density (98 kg/m{sup 3} ({approx}98 %porous)), high surface area (413 m{sup 2}/g), and has a particulate-type aerogel microstructure made up of very fine spherical particles with an open porous network. By comparison, a precipitate of Ni{sub 3}(NO{sub 3}){sub 2}(OH){sub 4} is obtained when the same preparation is attempted with the common Ni(NO{sub 3}){sub 2} 6H{sub 2}O salt as the precursor. The implications of the difference of reactivity of the two different precursors are discussed in the context of the mechanism of gel formation via the epoxide addition method. The synthesis of nickel (II) oxide aerogel, using the epoxide addition method, is especially unique in our experience. It is our first example of the successful preparation of a metal oxide aerogel using a metal divalent metal ion and may have implications for the application of this method to the preparation of aerogels or nanoparticles of other divalent metal oxides. To our knowledge this is the first report of a monolithic pure nickel (II) oxide aerogel materials.

Gash, A E; Satcher, J H; Simpson, R L

2004-01-13T23:59:59.000Z

207

Nitrogen-Doped Carbon Nanotube/Graphite Felts as Advanced Electrode Materials for Vanadium Redox Flow Batteries  

Science Journals Connector (OSTI)

vanadium redox flow battery; nitrogen doping; carbon nanotubes; graphite felt ... Nanorod Niobium Oxide as Powerful Catalysts for an All Vanadium Redox Flow Battery ... Nanorod Niobium Oxide as Powerful Catalysts for an All Vanadium Redox Flow Battery ...

Shuangyin Wang; Xinsheng Zhao; Thomas Cochell; Arumugam Manthiram

2012-07-27T23:59:59.000Z

208

NITROGEN REMOVAL FROM NATURAL GAS  

SciTech Connect

The objective of this project was to develop a membrane process for the denitrogenation of natural gas. Large proven reserves in the Lower-48 states cannot be produced because of the presence of nitrogen. To exploit these reserves, cost-effective, simple technology able to reduce the nitrogen content of the gas to 4-5% is required. Technology applicable to treatment of small gas streams (below 10 MMscfd) is particularly needed. In this project membranes that selectively permeate methane and reject nitrogen in the gas were developed. Preliminary calculations show that a membrane with a methane/nitrogen selectivity of 3 to 5 is required to make the process economically viable. A number of polymer materials likely to have the required selectivities were evaluated as composite membranes. Polyacetylenes such as poly(1-trimethylsilyl-1-propyne) [PTMSP] and poly(4-methyl-2-pentyne) [PMP] had high selectivities and fluxes, but membranes prepared from these polymers were not stable, showing decreasing flux and selectivity during tests lasting only a few hours. Parel, a poly(propylene oxide allyl glycidyl ether) had a selectivity of 3 at ambient temperatures and 4 or more at temperatures of {minus}20 C. However, Parel is no longer commercially available, and we were unable to find an equivalent material in the time available. Therefore, most of our experimental work focused on silicone rubber membranes, which have a selectivity of 2.5 at ambient temperatures, increasing to 3-4 at low temperatures. Silicone rubber composite membranes were evaluated in bench-scale module tests and with commercial-scale, 4-inch-diameter modules in a small pilot plant. Over six days of continuous operation at a feed gas temperature of {minus}5 to {minus}10 C, the membrane maintained a methane/nitrogen selectivity of about 3.3. Based on the pilot plant performance data, an analysis of the economic potential of the process was prepared. We conclude that a stand-alone membrane process is the lowest-cost technology for small gas streams containing less than 10% nitrogen. The membrane process can recover more than 60-70% of the hydrocarbon content of the gas at a cost of $0.60-0.70/Mscfd. The capital cost of the process is about $100-200/Mscf. A number of small operators appear to be ready to use the technology if these costs can be demonstrated in the field. A second, and perhaps better, application of the technology is to combine the membrane process with a cryogenic process to treat large gas streams containing 10-20% nitrogen. The combination process achieves significant synergies. The membrane process performs a bulk separation of the gas, after which the cryogenic process treats the membrane residue (nitrogen-enriched) gas to recover more methane. Overall, hydrocarbon recoveries are greater than 95%. The capital cost of the combination process is lower than that of either process used alone and the processing costs are in the range $0.30-0.40/Mscf. This operating cost would be attractive to many gas producers. MTR is collaborating with a producer of cryogenic systems to further develop the combination process. A number of innovations in membrane process designs were made during the project; four U.S. patents covering various aspects of the technology were filed and issued.

K.A. Lokhandwala; M.B. Ringer; T.T. Su; Z. He; I. Pinnau; J.G. Wijmans; A. Morisato; K. Amo; A. DaCosta; R.W. Baker; R. Olsen; H. Hassani; T. Rathkamp

1999-12-31T23:59:59.000Z

209

nitrogen metabolism in lakes i. measurement of nitrogen fixation with ...  

Science Journals Connector (OSTI)

the originally introduced nitrogen gas and the total amount of .... This is accom- of spontaneous O2 production, which .... free nitrogen been available; the cost of.

210

Nitrous oxide emissions from wastewater treatment processes  

Science Journals Connector (OSTI)

...specific ammonia oxidation rate. Symbols represent...Research Council (ARC) for funding this...correlated to its ammonia oxidation rate. 51 Arp, D...1146/annurev.micro.61.080706.093449...1146/annurev.micro.61.080706.093449...2004 Anaerobic oxidation of inorganic nitrogen...

2012-01-01T23:59:59.000Z

211

Effectiveness of Diesel Oxidation Catalyst in Reducing HC and CO Emissions from Reactivity Controlled Compression Ignition  

SciTech Connect

Reactivity Controlled Compression Ignition (RCCI) has been shown to allow for diesel-like or better brake thermal efficiency with significant reductions in nitrogen oxide (NOX) particulate matter (PM) emissions. Hydrocarbon (HC) and carbon monoxide (CO) emission levels, on the other hand, are similar to those of port fuel injected gasoline engines. The higher HC and CO emissions combined with the lower exhaust temperatures with RCCI operation present a challenge for current exhaust aftertreatments. The reduction of HC and CO emissions in a lean environment is typically achieved with an oxidation catalyst. In this work, several diesel oxidation catalysts (DOC) with different precious metal loadings were evaluated for effectiveness to control HC and CO emissions from RCCI combustion in a light-duty multi-cylinder engine operating on gasoline and diesel fuels. Each catalyst was evaluated in a steady-state engine operation with temperatures ranging from 160 to 260 C. A shift to a higher light-off temperature was observed during the RCCI operation. In addition to the steady-state experiments, the performances of the DOCs were evaluated during multi-mode engine operation by switching from diesel-like combustion at higher exhaust temperature and low HC/CO emissions to RCCI combustion at lower temperature and higher HC/CO emissions. High CO and HC emissions from RCCI generated an exotherm keeping the catalyst above the light-off temperature.

Prikhodko, Vitaly Y [ORNL; Curran, Scott [ORNL; Parks, II, James E [ORNL; Wagner, Robert M [ORNL

2013-01-01T23:59:59.000Z

212

Influence of different configurations of a catalyst and a trap on particulate emission of a diesel passenger car  

Science Journals Connector (OSTI)

New particulate emission measurements performed on a diesel passenger car to see the influence of different configurations of after-treatment systems are reported. Five combinations of a particle trap and an oxidation catalyst are investigated. These configurations are discussed in view of particulate emission, measured by number and mass. All measurements were carried out at a chassis dynamometer of the EMPA. A diesel passenger car with an IDI engine was operated at four steady state conditions. Exhaust gas was diluted in a standard constant volume sampler (CVS) device (full flow dilution tunnel). Particulate size distributions were measured with a scanning mobility particle sizer (SMPS) and gravimetric measurements were performed according to regulations. Furthermore, measurements without CVS tunnel were done by using external dilution units to see the influence of the sampling method. We used a thermo desorber to distinguish volatile and non-volatile aerosol fractions and we analysed filter samples for determination of organic soluble fraction, water-soluble fraction and sulphur content. Huge differences depending on the configuration of the after-treatment system and load were observed. In general it was found that a large reduction of particulate emission could be obtained by using a particle trap. A catalyst converter has minor effect on particulate emission. Nucleation of new particles was observed under certain conditions depending on configuration and sampling method.

Urs Lehmann; Martin Mohr

2001-01-01T23:59:59.000Z

213

Generator powered electrically heated diesel particulate filter  

DOE Patents (OSTI)

A control circuit for a vehicle powertrain includes a switch that selectivity interrupts current flow between a first terminal and a second terminal. A first power source provides power to the first terminal and a second power source provides power to the second terminal and to a heater of a heated diesel particulate filter (DPF). The switch is opened during a DPF regeneration cycle to prevent the first power source from being loaded by the heater while the heater is energized.

Gonze, Eugene V; Paratore, Jr., Michael J

2014-03-18T23:59:59.000Z

214

Measurement of particulate densities in air  

Science Journals Connector (OSTI)

Clean air is one of the most important issues that govern the health of all live forms. However presently there are not many quick and simple methods for measuring impurities like particulates in air. These impurities have an enormous diversity in their physical and chemical structure. They may be unburned carbon particles from a diesel engine exhaust and chimney pollen grains in the spring air or asbestos in a factory. This paper shows that changes in the composition of the air cause a change in the speed of sound. Therefore by measuring the change in the speed of sound it is possible to monitor the density of particulates in the air. Preliminary tests are conducted on various smoke–air mixtures. The results demonstrate that this methodology is very sensitive to any changes in the composition of the air. Its implementation is very simple and efficient and costs much less than the conventional method currently used in the auto industry. This technique will be used to calculate the mass density of the particulates resulting from a diesel engine and results thus obtained will be compared with those calculated using other methods.

2001-01-01T23:59:59.000Z

215

Nitrogen Trifluoride-Based Fluoride- Volatility Separations Process: Initial Studies  

SciTech Connect

This document describes the results of our investigations on the potential use of nitrogen trifluoride as the fluorinating and oxidizing agent in fluoride volatility-based used nuclear fuel reprocessing. The conceptual process uses differences in reaction temperatures between nitrogen trifluoride and fuel constituents that produce volatile fluorides to achieve separations and recover valuable constituents. We provide results from our thermodynamic evaluations, thermo-analytical experiments, kinetic models, and provide a preliminary process flowsheet. The evaluations found that nitrogen trifluoride can effectively produce volatile fluorides at different temperatures dependent on the fuel constituent.

McNamara, Bruce K.; Scheele, Randall D.; Casella, Andrew M.; Kozelisky, Anne E.

2011-09-28T23:59:59.000Z

216

Rapid thermal oxidation of silicon in mixtures of oxygen and nitrous oxide  

SciTech Connect

Oxidation in nitrous oxide by conventional hot wall furnace processing and by rapid thermal oxidation (RTO) has been a subject of much interest in recent years. RTO is a fundamentally different process than furnace oxidation, however, and the full effects of this type of processing on the oxidation kinetics are not well understood. Oxidation of silicon by RTO at a variety of pressures, temperatures, and oxidation gas mixtures has been studied. Although at lower temperatures (< 850 C) the atmospheric pressure oxidation rate in nitrous oxide is very close to that in oxygen, at higher temperatures the oxidation rate in nitrous oxide is much lower than that in oxygen. At lower pressures in a RTO process, the oxidation rate in nitrous oxide is higher than that in oxygen. The effect of the nitrogen incorporated in the oxide acting as a diffusion barrier has been proposed as the mechanism of temperature dependence for atmospheric pressure oxidation in nitrous oxide. This does not explain the effects seen at lower pressure,s however, The authors propose that some of the intermediate species produced in the decomposition of nitrous oxide into molecular nitrogen, molecular oxygen, and nitric oxide play a role in the initial stages of oxidation by RTO in nitrous oxide.

Grant, J.M.; Karim, Z. [Sharp Microelectronics Technology, Inc., Camas, WA (United States)

1996-12-01T23:59:59.000Z

217

Kinetics of Diesel Nanoparticle Oxidation  

Science Journals Connector (OSTI)

The oxidation rates in air of diesel nanoparticles sampled directly from the exhaust stream of a medium-duty diesel engine were measured over the temperature range of 800?1140 °C using online aerosol techniques. ... Particulate emission from diesel engines is currently a topic of great concern from both pollution and public health standpoints. ... In addition, the fundamental carbon-to-hydrogen ratio may be different in diesel particles as compared to the commonly used surrogates (15). ...

Kelly J. Higgins; Heejung Jung; David B. Kittelson; Jeffrey T. Roberts; Michael R. Zachariah

2003-03-25T23:59:59.000Z

218

Argonne TTRDC - Engines - Emissions Control - Advanced Diesel Particulate  

NLE Websites -- All DOE Office Websites (Extended Search)

Development of Advanced Diesel Particulate Filtration Systems Development of Advanced Diesel Particulate Filtration Systems The U.S. Environmental Protection Agency regulations require that on-highway diesel vehicles have filtration systems to reduce tail-pipe soot emissions, known as particulate matter (PM). Diesel particulate filtration (DPF) systems are currently the most efficient at directly controlling PM. Argonne researchers, working with Corning, Inc., and Caterpillar, Inc., through a cooperative research and development agreement, are exploiting previously unavailable technology and research results on diesel PM filtration and regeneration processes, aiming to the technology transfer of advanced PM emission control to industry. Argonne's Research In operation of DPF systems, the filtration and regeneration of particulate emissions are the key processes to be controlled for high efficiency. Due to difficulties in accessing the micro-scaled structures of DPF membranes and monitoring particulate filtration and high-temperature thermal processes, however, research has been limited to macroscopic observation for the product.

219

Impact of Biofuel Blending on Diesel Soot Oxidation: Implications for Aftertreatment  

SciTech Connect

Control strategies for diesel particulate filters (DPFs) remain one of the most important aspects of aftertreatment research and understanding the soot oxidation mechanism is key to controlling regeneration. Currently, most DPF models contain simple, first order heterogeneous reactions oxidation models with empirically fit parameters. This work improves the understanding of fundamental oxidation kinetics necessary to advance the capabilities of predictive modeling, by leading to better control over regeneration of the device. This study investigated the effects of blending soybean-derived biodiesel fuel on diesel particulate emissions under conventional combustion from a 1.7L direct injection, common rail diesel engine. Five biofuel blend levels were investigated and compared to conventional certification diesel for the nanostructure, surface chemistry and major constituents of the soluble organic fraction (SOF) of diesel particulate matter (PM), and the relationship between these properties and the particulate oxidation kinetics.

Strzelec, Andrea [ORNL; Toops, Todd J [ORNL; Lewis Sr, Samuel Arthur [ORNL; Daw, C Stuart [ORNL; Foster, David [University of Wisconsin; Rutland, Prof. Christopher J. [University of Wisconsin; Vander Wal, Dr. Randy [NASA-Glenn Research Center, Cleveland

2009-01-01T23:59:59.000Z

220

Characterization of particulate matter deposited in diesel particulate filters: Visual and analytical approach in macro-, micro- and nano-scales  

SciTech Connect

Multi-scale analytical investigations of particulate matter (soot and ash) of two loaded diesel particulate filters (DPF) from (a) a truck (DPF1) and (b) a passenger car (DPF2) reveal the following: in DPF1 (without fuel-borne additives), soot aggregates form an approximately 130-270 {mu}m thick, homogeneous porous cake with pronounced orientation. Soot aggregates consist of 15-30 nm large individual particles exhibiting relatively mature internal nanostructures, however, far from being graphite. Ash aggregates largely accumulate at the outlet part of DPF1, while minor amounts are deposited directly on the channel walls all along the filter length. They consist of crystalline phases with individual particles of sizes down to the nanoscale range. Chemically, the ash consists mainly of Mg, S, Ca, Zn and P, elements encountered in lubricating oil additives. In the passenger car DPF2 (with fuel-borne additives), soot aggregates form an approximately 200-500 {mu}m thick, inhomogeneous porous cake consisting of several superposed layers corresponding to different soot generations. The largest part of the soot cake is composed of unburned, oriented soot aggregates left behind despite repeated regenerations, while a small part constitutes a loose layer with randomly oriented aggregates, which was deposited last and has not seen any regeneration. Fe-oxide particles of micro- to nano-scale sizes, originating from the fuel-borne additive, are often dispersed within the part of the soot cake composed of the unburned soot leftovers. The individual soot nanoparticles in DPF2 are approximately 15-40 nm large and generally less mature than in the truck DPF1. The presence of soot leftovers in DPF2 indicates that the addition of fuel-borne material does not fully compensate for the temperatures needed for complete soot removal. Ash in DPF2 is filling up more than half of the filter volume (at the downstream part) and is dominated by Fe-oxide aggregates, due to the Fe-based fuel-borne additive, but otherwise its chemical composition reflects compounds of lubricating oil additives. (author)

Liati, Anthi; Dimopoulos Eggenschwiler, Panayotis [EMPA, Swiss Federal Laboratories for Materials Testing and Research, Laboratory for I.C. Engines, Duebendorf (Switzerland)

2010-09-15T23:59:59.000Z

Note: This page contains sample records for the topic "nitrogen oxides particulate" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Turn-on fluorescent probes for detecting nitric oxide in biology  

E-Print Network (OSTI)

Chapter 1. Investigating the Biological Roles of Nitric Oxide and Other Reactive Nitrogen Species Using Fluorescent Probes: This chapter presents an overview of recent progress in the field of reactive nitrogen species ...

McQuade, Lindsey Elizabeth, 1981-

2010-01-01T23:59:59.000Z

222

A Standard Soot Generator for Diesel Particulate Filter Testing  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

CAMBUSTION A Standard Soot Generator for Diesel Particulate Filter Testing Poster - P10 Diesel Engine Emission Reduction Conference 2007 Chris Nickolaus ...

223

Occupational Medicine Implications of Engineered Nanoscale Particulate Matter  

E-Print Network (OSTI)

Safety in Nanotechnology Research Occupational Medicinenanotechnology revolution promises dramatic advancements in science, technology, medicineMedicine Implications of Engineered Nanoscale Particulate Matter The emerging nanotechnology

Kelly, Richard J.

2008-01-01T23:59:59.000Z

224

Non-Destructive Neutron Imaging to Analyze Particulate Filters  

Energy.gov (U.S. Department of Energy (DOE))

Non-destructive, non-invasive imaging is being employed in the laboratory to understand how soot, ash, and catalytic washcoat are deposited within a diesel particulate filter.

225

Requirements-Driven Diesel Catalyzed Particulate Trap Design...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Driven Diesel Catalyzed Particulate Trap (DCPT) Design and Optimization Tom Harris, Donna McConnell and Danan Dou Delphi Catalyst Tulsa, Oklahoma 2 Euro 45 Light Duty...

226

Failure Stress and Apparent Elastic Modulus of Diesel Particulate...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Elastic Modulus of Diesel Particulate Filter Ceramics Three established mechanical test specimen geometries and test methods for brittle materials are adapted to DPF...

227

The constitutive behaviour of strong cohesive particulate gels in compression  

E-Print Network (OSTI)

A simple and popular constitutive model used to describe the compressional strength of a consolidating strongly cohesive particulate gel is tested further with new experimental data.

A. A. Aziz; R. Buscall; R. de Kretzer; M. Kristjansson; P. J. Scales; A. D. Stickland; H-E Teo; S. P. Usher

2014-10-20T23:59:59.000Z

228

Partitioning of Volatile Organics in Diesel Particulate and Exhaust...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

and Exhaust Partitioning of Volatile Organics in Diesel Particulate and Exhaust Evaluation of how sampling details affect the measurement of volatile organic compounds in...

229

Characterization of Particulate Emissions from GDI Engine Combustion...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Emissions from GDI Engine Combustion with Alcohol-blended Fuels Analysis showed that gasoline direct injection engine particulates from alcohol-blended fuels are significantly...

230

Development of a Criticality Evaluation Method Considering the Particulate Behavior of Nuclear Fuel  

SciTech Connect

In conventional criticality evaluations of nuclear powder systems, effects of particulate behavior were not considered. In other words, it is difficult to take into account the particle motion in the criticality evaluations. We have developed a novel criticality evaluation code to resolve this problem. The criticality evaluation code, coupling a discrete element method simulation code with a continuous-energy Monte Carlo transport code, makes it possible to study the effects of the particulate dynamics on criticality. This criticality evaluation code is applied to the mixed-oxide (MOX) fuel powder agitation process. The criticality evaluations are performed while mixing the MOX fuel powder and an additive powder in a stirred vessel to investigate the effects of the powder free surface deformation and the particulate mixture state on the effective multiplication factor. The evaluation results reveal that the effective multiplication factor decreases due to the powder boundary deformation while it increases as the mixture condition of MOX powder and Zn-St powder is close to homogeneous.

Sakai, Mikio; Yamamoto, Toshihiro; Murazaki, Minoru; Miyoshi, Yoshinori [Japan Atomic Energy Research Institute (Japan)

2005-02-15T23:59:59.000Z

231

Neutron Imaging of Diesel Particulate Filters  

SciTech Connect

This article presents nondestructive neutron computed tomography (nCT) measurements of Diesel Particulate Filters (DPFs) as a method to measure ash and soot loading in the filters. Uncatalyzed and unwashcoated 200cpsi cordierite DPFs exposed to 100% biodiesel (B100) exhaust and conventional ultra low sulfur 2007 certification diesel (ULSD) exhaust at one speed-load point (1500rpm, 2.6bar BMEP) are compared to a brand new (never exposed) filter. Precise structural information about the substrate as well as an attempt to quantify soot and ash loading in the channel of the DPF illustrates the potential strength of the neutron imaging technique.

Strzelec, Andrea [ORNL; Bilheux, Hassina Z [ORNL; FINNEY, Charles E A [ORNL; Daw, C Stuart [ORNL; Foster, Prof. Dave [University of Wisconsin; Rutland, Prof. Christopher J. [University of Wisconsin; Schillinger, Burkhard [FRM-II, Technische Universitaet Munchen; Schulz, Michael [FRM-II, Technische Universitaet Munchen

2009-01-01T23:59:59.000Z

232

Electrically heated particulate filter with reduced stress  

DOE Patents (OSTI)

A system comprises a particulate matter (PM) filter comprising an inlet for receiving exhaust gas. A zoned heater is arranged in the inlet and comprises a resistive heater comprising N zones, where N is an integer greater than one. Each of the N zones comprises M sub-zones, where M is an integer greater than one. A control module selectively activates one of the N zones to initiate regeneration in downstream portions of the PM filter from the one of the N zones and deactivates others of the N zones.

Gonze, Eugene V.

2013-03-05T23:59:59.000Z

233

Interactions of Fluorine Redistribution and Nitrogen Incorporation with Boron Diffusion in Silicon Dioxide  

E-Print Network (OSTI)

Interactions of Fluorine Redistribution and Nitrogen Incorporation with Boron Diffusion in Silicon Dioxide Mitra Navi and Scott Dunham Department of Electrical and Computer Engineering Boston University diffusion. Gate oxides were grown with nitrogen contents varying from 0 to 1.4%. A series of SIMS mea

Dunham, Scott

234

Modeling and interpreting the observed effects of ash on diesel particulate filter performance and regeneration  

E-Print Network (OSTI)

Diesel particulate filters (DPF) are devices that physically capture diesel particulates to prevent their release to the atmosphere. Diesel particulate filters have seen widespread use in on- and off-road applications as ...

Wang, Yujun, Ph. D. Massachusetts Institute of Technology

2014-01-01T23:59:59.000Z

235

Regional variation in the particulate organic carbon to nitrogen ratio in the surface ocean  

E-Print Network (OSTI)

. Martiny,1,2 Jasper A. Vrugt,1,3 Francois W. Primeau,1 and Michael W. Lomas4 Received 22 March 2013 cycles. Citation: Martiny, A. C., J. A. Vrugt, F. W. Primeau, and M. W. Lomas (2013), Regional variation or loss, and other important oceanographic processes [Deutsch and Weber, 2012; Mills and Arrigo, 2010

Vrugt, Jasper A.

236

Method for immobilizing particulate materials in a packed bed  

DOE Patents (OSTI)

The present invention pertains generally to immobilizing particulate matter contained in a "packed" bed reactor so as to prevent powder migration, compaction, coalescence, or the like. More specifically, this invention relates to a technique for immobilizing particulate materials using a microporous foam-like polymer such that a) the particulate retains its essential chemical nature, b) the local movement of the particulate particles is not unduly restricted, c) bulk powder migration and is prevented, d) physical and chemical access to the particulate is unchanged over time, and e) very high particulate densities are achieved. The immobilized bed of the present invention comprises a vessel for holding particulate matter, inlet and an outlet ports or fittings, a loosely packed bed of particulate material contained within the vessel, and a three dimensional porous matrix for surrounding and confining the particles thereby fixing the movement of individual particle to a limited local position. The established matrix is composed of a series of cells or chambers comprising walls surrounding void space, each wall forming the wall of an adjacent cell; each wall containing many holes penetrating through the wall yielding an overall porous structure and allowing useful levels of gas transport.

Even, Jr., William R. (Livermore, CA); Guthrie, Stephen E. (Livermore, CA); Raber, Thomas N. (Livermore, CA); Wally, Karl (Lafayette, CA); Whinnery, LeRoy L. (Livermore, CA); Zifer, Thomas (Manteca, CA)

1999-01-01T23:59:59.000Z

237

Method for removing particulate matter from a gas stream  

DOE Patents (OSTI)

Particulate matter is removed from a stream of pressurized gas by directing the stream of gas upwardly through a bed of porous material, the porous bed being held in an open ended container and at least partially submerged in liquid. The passage of the gas through the porous bed sets up a circulation in the liquid which cleans the particulate matter from the bed.

Postma, Arlin K. (Benton City, WA)

1984-01-01T23:59:59.000Z

238

Advanced Particulate Filter Technologies for Direct Injection Gasoline Engine Applications  

Energy.gov (U.S. Department of Energy (DOE))

Specific designs and material properties have to be developed for gasoline particulate filters based on the different engine and exhaust gas characteristic of gasoline engines compared to diesel engines, e.g., generally lower levels of engine-out particulate emissions or higher GDI exhaust gas temperatures

239

Process for off-gas particulate removal and apparatus therefor  

DOE Patents (OSTI)

In the event of a breach in the off-gas line of a melter operation requiring closure of the line, a secondary vessel vent line is provided with a particulate collector utilizing atomization for removal of large particulates from the off-gas. The collector receives the gas containing particulates and directs a portion of the gas through outer and inner annular channels. The collector further receives a fluid, such as water, which is directed through the outer channel together with a second portion of the particulate-laden gas. The outer and inner channels have respective ring-like termination apertures concentrically disposed adjacent one another on the outer edge of the downstream side of the particulate collector. Each of the outer and inner channels curves outwardly away from the collector's centerline in proceeding toward the downstream side of the collector. Gasflow in the outer channel maintains the fluid on the channel's wall in the form of a "wavy film," while the gas stream from the inner channel shears the fluid film as it exits the outer channel in reducing the fluid to small droplets. Droplets formed by the collector capture particulates in the gas stream by one of three mechanisms: impaction, interception or Brownian diffusion in removing the particulates. The particulate-laden droplets are removed from the fluid stream by a vessel vent condenser or mist eliminator.

Carl, Daniel E. (Orchard Park, NY)

1997-01-01T23:59:59.000Z

240

Process for off-gas particulate removal and apparatus therefor  

DOE Patents (OSTI)

In the event of a breach in the off-gas line of a melter operation requiring closure of the line, a secondary vessel vent line is provided with a particulate collector utilizing atomization for removal of large particulates from the off-gas. The collector receives the gas containing particulates and directs a portion of the gas through outer and inner annular channels. The collector further receives a fluid, such as water, which is directed through the outer channel together with a second portion of the particulate-laden gas. The outer and inner channels have respective ring-like termination apertures concentrically disposed adjacent one another on the outer edge of the downstream side of the particulate collector. Each of the outer and inner channels curves outwardly away from the collector`s centerline in proceeding toward the downstream side of the collector. Gas flow in the outer channel maintains the fluid on the channel`s wall in the form of a ``wavy film,`` while the gas stream from the inner channel shears the fluid film as it exits the outer channel in reducing the fluid to small droplets. Droplets formed by the collector capture particulates in the gas stream by one of three mechanisms: impaction, interception or Brownian diffusion in removing the particulates. The particulate-laden droplets are removed from the fluid stream by a vessel vent condenser or mist eliminator. 4 figs.

Carl, D.E.

1997-10-21T23:59:59.000Z

Note: This page contains sample records for the topic "nitrogen oxides particulate" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

The design of stable high nitrogen systems  

SciTech Connect

A general strategy for the design of high nitrogen systems with an adequate degree of stability has been elaborated. The design of nitro compounds in which terminal nitro groups are bonded to the chain of several heteroatoms is a specific case within the strategy. In the process of working out the strategy a number of new high nitrogen systems (dinitrazenic acid or dinitroamide HN{sub 3}O{sub 4} and its salts, nitrodiazene oxides RN{sub 3}O{sub 3} and tetrazine dioxides) were discovered. A new of new types of nitro compounds (bicyclo nitro-bis-hydroxylamine, nitrohydrazine, nitrohydroxylamine, sulfo-N-nitroimide and bis-N-nitroimide) were synthesized. This study opens new prospects in the field of the synthesis of high energy materials.

Tartakovsky, V.A. [Russian Academy of Sciences, Moscow (Russian Federation). N.D. Zelinsky Inst. of Organic Chemistry

1996-07-01T23:59:59.000Z

242

Final Report: Particulate Emissions Testing, Unit 1, Potomac River  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Final Report: Particulate Emissions Testing, Unit 1, Potomac River Final Report: Particulate Emissions Testing, Unit 1, Potomac River Generating Station, Alexandria, Virginia Final Report: Particulate Emissions Testing, Unit 1, Potomac River Generating Station, Alexandria, Virginia Docket No. EO-05-01: TRC Environmental Corporation (TRC) of Lowell, Massachusetts was retained by Mirant Potomac River, LLC (Mirant) to provide sampling and analytical support in completing a Particulate Emission Test of Unit 1 of the Potomac River generating facility. The Test Program at the Potomac facility involved the completion of two series of emissions tests for particulate matter (PM), the first during normal unit operation and the second with the injection of TRONA upstream of hot side ESP fields. All tests were completed while Unit 1 was operating at 90% of full load (84MW)

243

180 MW demonstration of advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NOx) emissions from coal-fired boilers. Technical progress report, Third quarter 1992  

SciTech Connect

The project is being conducted at Gulf Power Company`s Plant Lansing Smith Unit 2 located near Panama City, Florida. The primary objective of this demonstration is to determine the long-term effects of commercially available tangentially-fired low NOx combustion technologies on NOx emissions and boiler performance. A target of achieving 50% NOx reduction using combustion modifications has been established for the project. The stepwise approach that is being used to evaluate the NOx control technologies requires three plant outages to successively install the test instrumentation and the different levels of the low NOx concentric firing system (LNCFS). Following each outage, a series of four groups of tests are performed. These are (1) diagnostic, (2) performance, (3) long-term, and (4) verification. These tests are used to quantify the NOx reductions of each technology and evaluate the effects of those reductions on other combustion parameters such as particulate characteristics and boiler efficiency. This technical progress report presents the LNCFS Level 1 long-term data collected during this quarter. In addition, a comparison of all the long-term emissions data that have been collected to date is included.

Not Available

1992-12-31T23:59:59.000Z

244

E-Print Network 3.0 - ambient particulate matter Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

ambient particulate matter Page: << < 1 2 3 4 5 > >> 1 Statistical Issues in the Study of Air Pollution Involving Airborne Particulate Matter Summary: Ambient Air Quality Standards...

245

E-Print Network 3.0 - air particulate analysis Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

air particulate analysis Page: << < 1 2 3 4 5 > >> 1 Statistical Issues in the Study of Air Pollution Involving Airborne Particulate Matter Summary: and the composition of...

246

E-Print Network 3.0 - air particulate samples Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

search results for: air particulate samples Page: << < 1 2 3 4 5 > >> 1 Prevention of Air Pollution from Ships: Diesel Engine Particulate Emission Reduction via...

247

E-Print Network 3.0 - ambient particulate matterpm10 Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

particulate matterpm10 Page: << < 1 2 3 4 5 > >> 1 Statistical Issues in the Study of Air Pollution Involving Airborne Particulate Matter Summary: Ambient Air Quality Standards...

248

E-Print Network 3.0 - ambient particulate matter-induced Sample...  

NLE Websites -- All DOE Office Websites (Extended Search)

particulate matter-induced Page: << < 1 2 3 4 5 > >> 1 Statistical Issues in the Study of Air Pollution Involving Airborne Particulate Matter Summary: Ambient Air Quality Standards...

249

Impact of Transportation on Cost, Energy and Particulate Emissions for Recycled Concrete Aggregate.  

E-Print Network (OSTI)

??IMPACT OF TRANSPORTATION ON COST, ENERGY AND PARTICULATE EMISSIONS FOR RECYCLED CONCRETE AGGREGATE Transportation distances can have a huge impact on cost, energy, and particulate… (more)

Hameed, Mohamed

2009-01-01T23:59:59.000Z

250

New chemistry with gold-nitrogen complexes: synthesis and characterization of tetra-, tri-, and dinuclear gold(I) amidinate complexes. Oxidative-addition to the dinuclear gold(I) amidinate  

E-Print Network (OSTI)

catalyst precursors for CO oxidation on TiO2 surface reported to date (87% conversion). The dinuclear gold(I) amidinate complex with a Auâ ¦Au distance of 2.711(3) Ă is rare. To our knowledge, there is only one other example of a symmetrical dinuclear gold...

Abdou, Hanan Elsayed

2009-06-02T23:59:59.000Z

251

E-Print Network 3.0 - anesthetic nitrous oxide Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

such concentrations of anesthetics are safe... ), hypoxemia (eg, nitrogen and carbon monoxide), addiction (eg, nitrous oxide), or health effects resulting... from chronic exposure...

252

E-Print Network 3.0 - attenuates oxidative damage Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

Collection: Computer Technologies and Information Sciences 40 Charge-trapping properties of gate oxide grown on nitrogen-implanted silicon substrate Summary: Charge-trapping...

253

Impact of Biodiesel Blending on Diesel Soot and the Regeneration of Particulate Filters  

Science Journals Connector (OSTI)

Diesel fuel production from renewable sources such as vegetable oils and animal fats offers the potential of both reducing fossil carbon emissions and producing alternative ultraclean transportation fuels. ... For temperature-programmed oxidation (TPO) tests, bulk samples were collected in quartz filters from diluted exhaust gas via a mini-dilution tunnel (Sierra Instruments BG-1). ... In addition to PM mass measurement, particulate samples were extracted directly from the exhaust stream using a thermophoretic sampling approach patterned after the work of Megaridis15 and Koylu,16 and described previously by Song et al.17 The thermophoretic samples were collected on 3-mm-diameter grids, constructed of 1-?m-thick copper and coated on one side with silicon oxide, using a pneumatically controlled probe to inject the sampling grid into the undiluted exhaust near the location where the other emissions samples were obtained in the exhaust pipe. ...

André L. Boehman; Juhun Song; Mahabubul Alam

2005-06-01T23:59:59.000Z

254

Viscosity Measurements on Nitrogen  

Science Journals Connector (OSTI)

Viscosity Measurements on Nitrogen ... (15)?Clarke, A. G.; Smith, E. B. Low-temperature viscosities and intermolecular forces of simple gases. ... The coupling also serves as a frictionless bearing for a slender rotating cylindrical body which is slowed down due to the viscous drag of the fluid surrounding the cylinder. ...

Daniel Seibt; Eckhard Vogel; Eckard Bich; Daniel Buttig; Egon Hassel

2006-01-11T23:59:59.000Z

255

ODD NITROGEN PROCESSES  

SciTech Connect

This chapter is in three parts. The first concerns interpretations that can be made from atmospheric observations regarding nitrogen compounds and ozone, the second reviews some predictions made by atmospheric models, and the third compares between certain model results and atmospheric measurements with an emphasis on detecting evidence of significant disagreements.

Johnston, Harold S.

1980-01-01T23:59:59.000Z

256

Higher modulus compositions incorporating particulate rubber  

DOE Patents (OSTI)

Rubber particles, to be used as fillers or extenders for various composite polymer systems, are chlorinated by a gas-solid phase reaction with a chlorine-containing gas. A composite polymer containing the chlorinated rubber fillers or extenders exhibits a higher flexural modulus than if prepared using an unchlorinated rubber filler or extender. Chlorination of the rubber particles is carried out by contacting the finely divided rubber particles with a chlorine-containing gas comprising at least about 5 volume percent chlorine. Advantageously, the chlorine can be diluted with air, nitrogen or other essentially inert gases and may contain minor amounts of fluorine. Improved performance is obtained with nitrogen dilution of the chlorine gas over air dilution. Improved polymer composite systems having higher flexural modulus result from the use of the chlorinated rubber particles as fillers instead of unchlorinated rubber particles. 2 figs.

Bauman, B.D.; Williams, M.A.; Bagheri, R.

1997-12-02T23:59:59.000Z

257

Higher modulus compositions incorporating particulate rubber  

DOE Patents (OSTI)

Rubber particles, to be used as fillers or extenders for various composite polymer systems, are chlorinated by a gas-solid phase reaction with a chlorine-containing gas. A composite polymer containing the chlorinated rubber fillers or extenders exhibits a higher flexural modulus than if prepared using an unchlorinated rubber filler or extender. Chlorination of the rubber particles is carried out by contacting the finely divided rubber particles with a chlorine-containing gas comprising at least about 5 volume percent chlorine. Advantageously, the chlorine can be diluted with air, nitrogen or other essentially inert gases and may contain minor amounts of fluorine. Improved performance is obtained with nitrogen dilution of the chlorine gas over air dilution. Improved polymer composite systems having higher flexural modulus result from the use of the chlorinated rubber particles as fillers instead of unchlorinated rubber particles.

Bauman, Bernard D. (Emmaus, PA); Williams, Mark A. (Souderton, PA); Bagheri, Reza (Bethlehem, PA)

1997-12-02T23:59:59.000Z

258

Impact of Filtration Velocities and Particulate Matter Characteristics on Diesel Particulate Filter Wall Loading Performance  

SciTech Connect

The impact of different types of diesel particulate matter (PM) and different sampling conditions on the wall deposition and early soot cake build up within diesel particulate filters has been investigated. The measurements were made possible by a newly developed Diesel Exhaust Filtration Analysis (DEFA) system in which in-situ diesel exhaust filtration can be reproduced with in small cordierite wafer disks, which are essentially thin sections of a Diesel Particulate Filter (DPF) wall. The different types of PM were generated from selected engine operating conditions of a single-cylinder heavy-duty diesel engine. Two filtration velocities 4 and 8 cm/s were used to investigate PM deep-bed filtration processes. The loaded wafers were then analyzed in a thermal mass analyzer that measures the Soluble Organic Fraction (SOF) as well as soot and sulfate fractions of the PM. In addition, the soot residing in the wall of the wafer was examined under an optical microscope illuminated with Ultraviolet light and an Environmental Scanning Electron Microscope (E-SEM) to determine the bulk soot penetration depth for each loading condition. It was found that higher filtration velocity results in higher wall loading with approximately the same penetration depth into the wall. PM characteristics impacted both wall loading and soot cake layer characteristics. Results from imaging analysis indicate that soot the penetration depth into the wall was affected more by PM size (which changes with engine operating conditions) rather than filtration velocity.

Lance, Michael J [ORNL; Walker, Larry R [ORNL; Yapaulo, Renato A [ORNL; Orita, Tetsuo [ORNL; Wirojsakunchai, Ekathai [University of Wisconsin; Foster, David [University of Wisconsin; Akard, Michael [Horiba Instruments Inc.

2009-01-01T23:59:59.000Z

259

180 MW demonstration of advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NOx) emissions from coal-fired boilers. Technical progress report, First quarter 1991  

SciTech Connect

This project is being conducted at Gulf Power Company`s Plant Lansing Smith Unit 2 (LS-2) located near Panama City, Florida. The primary objective of this demonstration is to determine the long-term effects of commercially available tangentially-fired low NOx combustion technologies on NOx emissions and boiler performance. The stepwise approach that is being used to evaluate the NOx control technologies requires three plant outages to successively install the test instrumentation and the different levels of the low NOx concentric firing system (LNCFS). Following each outage, a series of four groups of tests are performed. These are (1) diagnostic, (2) performance, (3) long-term, and (4) verification. These tests are used to quantify the NOx reductions of each technology and evaluate the effects of those reductions on other combustion parameters such as particulate characteristics and boiler efficiency. This quarterly update provides a description of the flow modeling study. This modeling effort centers on evaluating the in-furnace flow and mixing phenomena for the various low NOx firing systems being demonstrated at LS-2. Testing on the 1/12 scale model of the LS-2 boiler and the 1/6 scale model of the overfire air ductwork was completed. The test matrix included an analysis of the overfire air ductwork and three different boiler configurations. This report also contains results from the Phase 1 baseline tests. Data from the diagnostic, performance, and verification tests are presented. In addition, NOx emissions data and unit load profiles collected during long-term testing are reported. At the full load condition, the baseline NOx emission level at LS-2 is 0.62 lb/mBtu.

Not Available

1991-12-31T23:59:59.000Z

260

Particulate contamination removal from wafers using plasmas and mechanical agitation  

DOE Patents (OSTI)

Particulate contamination removal from wafers is disclosed using plasmas and mechanical agitation. The present invention includes the use of plasmas with mechanical agitation for removing particulate matter from the surface of a wafer. The apparatus hereof comprises a mechanical activator, at least one conducting contact pin for transferring the vibration from the activator to the wafer, clamp fingers that maintain the wafer`s position, and means for generating a plasma in the vicinity of the surface of the wafer, all parts of the cleaning apparatus except the mechanical activator and part of the contact pin being contained inside the processing chamber. By exposing a wafer to a plasma and providing motion thereto in a direction perpendicular to its surface, the bonding between the particulate matter and the surface may be overcome. Once free of the wafer surface, the particulates become charged by electrons from the plasma and are drawn into the plasma by attractive forces which keep them from redepositing. The introduction of a flowing gas through the plasma sweeps the particulates away from the wafer and out of the plasma. The entire surface is cleaned during one cleaning step. The use of an rf plasma to accomplish the particulate removal was found to remove more than 90% of the particulates. 4 figs.

Selwyn, G.S.

1998-12-15T23:59:59.000Z

Note: This page contains sample records for the topic "nitrogen oxides particulate" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Particulate contamination removal from wafers using plasmas and mechanical agitation  

DOE Patents (OSTI)

Particulate contamination removal from wafers using plasmas and mechanical agitation. The present invention includes the use of plasmas with mechanical agitation for removing particulate matter from the surface of a wafer. The apparatus hereof comprises a mechanical activator, at least one conducting contact pin for transferring the vibration from the activator to the wafer, clamp fingers that maintain the wafer's position, and means for generating a plasma in the vicinity of the surface of the wafer, all parts of the cleaning apparatus except the mechanical activator and part of the contact pin being contained inside the processing chamber. By exposing a wafer to a plasma and providing motion thereto in a direction perpendicular to its surface, the bonding between the particulate matter and the surface may be overcome. Once free of the wafer surface, the particulates become charged by electrons from the plasma and are drawn into the plasma by attractive forces which keep them from redepositing. The introduction of a flowing gas through the plasma sweeps the particulates away from the wafer and out of the plasma. The entire surface is cleaned during one cleaning step. The use of an rf plasma to accomplish the particulate removal was found to remove more than 90% of the particulates.

Selwyn, Gary S. (Los Alamos, NM)

1998-01-01T23:59:59.000Z

262

Frostbite Theater - Liquid Nitrogen Experiments - Liquid Nitrogen and  

NLE Websites -- All DOE Office Websites (Extended Search)

Freeze the Rainbow! Freeze the Rainbow! Previous Video (Freeze the Rainbow!) Frostbite Theater Main Index Next Video (Liquid Nitrogen and Fire!) Liquid Nitrogen and Fire! Liquid Nitrogen and Antifreeze! What happens when the freezing power of liquid nitrogen meets the antifreezing power of ethylene glycol? [ Show Transcript ] Announcer: Frostbite Theater presents... Cold Cuts! No baloney! Joanna and Steve: Just science! Joanna: Hi! I'm Joanna! Steve: And I'm Steve! Joanna: What happens when the freezing power of liquid nitrogen... Steve: ...meets the antifreezing power of ethylene glycol! Joanna: While a mix of 70 percent ethylene glycol and 30 percent water doesn't freeze until 60 degrees below zero, it's still no match for liquid nitrogen. At 321 degrees below zero, liquid nitrogen easily freezes

263

Frostbite Theater - Liquid Nitrogen Experiments - Liquid Nitrogen in a  

NLE Websites -- All DOE Office Websites (Extended Search)

Freeze Liquid Nitrogen! Freeze Liquid Nitrogen! Previous Video (Let's Freeze Liquid Nitrogen!) Frostbite Theater Main Index Next Video (Freeze the Rainbow!) Freeze the Rainbow! Liquid Nitrogen in a Microwave! What happens when the world's most beloved cryogenic liquid meets one of the most common household appliances? Find out when we try to microwave liquid nitrogen! [ Show Transcript ] Announcer: Frostbite Theater presents... Cold Cuts! No baloney! Joanna and Steve: Just science! Joanna: Hi! I'm Joanna! Steve: And I'm Steve! Joanna: A little while ago we received an email from Star of the Sea Catholic School in Virginia Beach, Virginia, asking what happens when you place liquid nitrogen in a microwave. Well, I just happen to have some liquid nitrogen! Steve: And I just happen to have a microwave!

264

Lanthanides as particulate flow markers in ruminants  

E-Print Network (OSTI)

!er (Langlands e+ al. , 1963; Thompson and Lamming, 1378; Uiyatt and I', acqae, 1974). Som" investigators have concluded that distritoution oi chromic oxide approximated that of t:hc dry matter (Corbett ei al. , 1958; Corbet t et al. , 1959) while others sugg... indicate ei ther adsorption or associ ated flow. For example, chromic oxide would cosediment with digosta solids, solely due to its insolu- b-ility, without being physicaily associated with the feed residues in any mann r. Advancements in analytical...

Conner, Michael Cronan

1977-01-01T23:59:59.000Z

265

Source Contribution Analysis of Surface Particulate Polycyclic Aromatic Hydrocarbon Concentrations in Northeastern Asia by Source-receptor Relationships  

SciTech Connect

We analyzed the sourceereceptor relationships for particulate polycyclic aromatic hydrocarbon (PAH) concentrations in northeastern Asia using an aerosol chemical transport model. The model successfully simulated the observed concentrations. In Beijing (China) benzo[a]pyren (BaP) concentrations are due to emissions from its own domain. In Noto, Oki and Tsushima (Japan), transboundary transport from northern China (>40°N, 40-60%) and central China (30-40°N, 10-40%) largely influences BaP concentrations from winter to spring, whereas the relative contribution from central China is dominant (90%) in Hedo. In the summer, the contribution from Japanese domestic sources increases (40-80%) at the 4 sites. Contributions from Japan and Russia are additional source of BaP over the northwestern Pacific Ocean in summer. The contribution rates for the concentrations from each domain are different among PAH species depending on their particulate phase oxidation rates. Reaction with O3 on particulate surfaces may be an important component of the PAH oxidation processes.

Inomata, Yayoi; Kajino, Mizuo; Sato, Keiichi; Ohara, Toshimasa; Kurokawa, Jun-Ichi; Ueda, Hiromasa; Tang, Ning; Hayakawa, Kazuichi; Ohizumi, Tsuyoshi; Akimoto, Hajime

2013-11-01T23:59:59.000Z

266

Methane/nitrogen separation process  

DOE Patents (OSTI)

A membrane separation process is described for treating a gas stream containing methane and nitrogen, for example, natural gas. The separation process works by preferentially permeating methane and rejecting nitrogen. The authors have found that the process is able to meet natural gas pipeline specifications for nitrogen, with acceptably small methane loss, so long as the membrane can exhibit a methane/nitrogen selectivity of about 4, 5 or more. This selectivity can be achieved with some rubbery and super-glassy membranes at low temperatures. The process can also be used for separating ethylene from nitrogen. 11 figs.

Baker, R.W.; Lokhandwala, K.A.; Pinnau, I.; Segelke, S.

1997-09-23T23:59:59.000Z

267

Methane/nitrogen separation process  

DOE Patents (OSTI)

A membrane separation process for treating a gas stream containing methane and nitrogen, for example, natural gas. The separation process works by preferentially permeating methane and rejecting nitrogen. We have found that the process is able to meet natural gas pipeline specifications for nitrogen, with acceptably small methane loss, so long as the membrane can exhibit a methane/nitrogen selectivity of about 4, 5 or more. This selectivity can be achieved with some rubbery and super-glassy membranes at low temperatures. The process can also be used for separating ethylene from nitrogen.

Baker, Richard W. (Palo Alto, CA); Lokhandwala, Kaaeid A. (Menlo Park, CA); Pinnau, Ingo (Palo Alto, CA); Segelke, Scott (Mountain View, CA)

1997-01-01T23:59:59.000Z

268

Nitrogen enriched combustion of a natural gas internal combustion engine to reduce NO.sub.x emissions  

DOE Patents (OSTI)

A method and system for reducing nitrous oxide emissions from an internal combustion engine. An input gas stream of natural gas includes a nitrogen gas enrichment which reduces nitrous oxide emissions. In addition ignition timing for gas combustion is advanced to improve FCE while maintaining lower nitrous oxide emissions.

Biruduganti, Munidhar S. (Naperville, IL); Gupta, Sreenath Borra (Naperville, IL); Sekar, R. Raj (Naperville, IL); McConnell, Steven S. (Shorewood, IL)

2008-11-25T23:59:59.000Z

269

Regenerative catalytic oxidation  

SciTech Connect

Currently Regenerative Thermal Oxidizers (R.T.O.`s) are an accepted technology for the control of volatile organic compounds (VOC`s) and hazardous air pollutants (HAP`s). This control technology, when introduced, offered substantial reductions in operating costs, especially auxiliary fuel requirements when compared to existing control technologies such as recuperative thermal and recuperative catalytic oxidizers. While these savings still exist, there is a demand for control of new and/or hybrid technologies, one of which is Regenerative Catalytic Oxidizers (R.C.O.`s). This paper will explore the development of regenerative catalytic oxidation from the theoretical stage through pilot testing through a commercial installation. The operating cost of R.C.O.`s will be compared to R.T.O.`s to verify the savings that are achievable through the use of regenerative catalytic oxidation. In the development of this technology, which is a combination of two (2) existing technologies, R.T.O.`s and catalysis, a second hybrid technology was explored and pilot tested. This is a combination R.C.O. for VOC and HAP control and simultaneous SCR (Selective Catalytic Reduction) for NOx (Oxides of Nitrogen) control. Based on the pilot and full scale testing, both regenerative catalytic oxidizers and systems which combine R.C.O. with SCR for both VOC and NOx reduction are economically viable and are in fact commercially available. 6 figs., 2 tabs.

Gribbon, S.T. [Engelhard Process Emission Systems, South Lyon, MI (United States)

1996-12-31T23:59:59.000Z

270

Impacts of a Nanosized Ceria Additive on Diesel Engine Emissions of Particulate and Gaseous Pollutants  

E-Print Network (OSTI)

reductions of CO2, CO, total particulate mass, formaldehyde, acetaldehyde, acrolein, and several polycyclic

Garfunkel, Eric

271

Li2O Particulate Flow Concept, APPLE APEX Interim Report November, 1999  

E-Print Network (OSTI)

Li2O Particulate Flow Concept, APPLE APEX Interim Report November, 1999 9-1 CHAPTER 9: Li2O PARTICULATE FLOW CONCEPT ­ APPLE DESIGN Contributors Lead Author: Dai Kai Sze Dai Kai Sze, Zhanhe Wang (ANL Particulate Flow Concept, APPLE APEX Interim Report November, 1999 9-2 9. LI2O PARTICULATE FLOW CONCEPT

California at Los Angeles, University of

272

NETL Report format template  

NLE Websites -- All DOE Office Websites (Extended Search)

NGCC Natural gas combined cycle NOx Oxides of nitrogen PC Sub Pulverized coal subcritical PC Sup Pulverized coal supercritical PM Particulate matter SO 2 Sulfur dioxide...

273

Investigation of HDDE exhaust flow mixing devices to enhance SCR performance.  

E-Print Network (OSTI)

??The 2010 regulations implemented by the U.S. Environmental Protection Agency (EPA) require significant reduction in Oxides of Nitrogen (NOx) and Particulate Matter (PM). These regulations… (more)

Sathi, Venkata Reddy.

2010-01-01T23:59:59.000Z

274

Hybrid Locomotive | GE Global Research  

NLE Websites -- All DOE Office Websites (Extended Search)

two main culprits: nitrogen oxide (NOx) and particulate matter (PM) like tiny chemical, metal, soil and dust particles. Tier 4 emission standards will kick in for locomotives on...

275

Development of Land Use Regression Models for elemental, organic carbon, PAH and hopanes/steranes in 10 ESCAPE/TRANSPHORM European study areas  

Science Journals Connector (OSTI)

Land use regression (LUR) models have been used to model concentrations of mainly traffic related air pollutants (nitrogen oxides (NOx), particulate matter (PM) mass or absorbance). ...

Aleksandra Jedynska; Gerard Hoek; Meng Wang; Marloes Eeftens; Josef Cyrys; Menno Keuken; Christophe Ampe; Rob Beelen; Giulia Cesaroni; Francesco Forastiere; Marta Cirach; Kees de Hoogh; Audrey De Nazelle; Wenche Nystad; Christophe Declercq; Kirsten Thorup Eriksen; Konstantina Dimakopoulou; Timo Lanki; Kees Meliefste; Mark J Nieuwenhuijsen; Tarja Yli-Tuomi; Ole Raaschou-Nielsen; Bert Brunekreef; Ingeborg Kooter

2014-10-15T23:59:59.000Z

276

Engineering analysis of fugitive particulate matter emissions from cattle feedyards  

E-Print Network (OSTI)

An engineering analysis of the fugitive particulate matter emissions from a feedyard is not simple. The presence of an evening dust peak in concentration measurements downwind of a feedyard complicates the calculation of an average 24-h emission...

Hamm, Lee Bradford

2006-04-12T23:59:59.000Z

277

REVIEW OF DIESEL PARTICULATE MATTER SAMPLING METHODS Supplemental Report # 2  

E-Print Network (OSTI)

Arnold University of Minnesota Department of Mechanical Engineering Center for Diesel Research aerosol. This report focuses on the fundamental chemical and physical processes that affect diesel aerosolREVIEW OF DIESEL PARTICULATE MATTER SAMPLING METHODS Supplemental Report # 2 AEROSOL DYMAMICS

Minnesota, University of

278

Automated particulate sampler field test model operations guide  

SciTech Connect

The Automated Particulate Sampler Field Test Model Operations Guide is a collection of documents which provides a complete picture of the Automated Particulate Sampler (APS) and the Field Test in which it was evaluated. The Pacific Northwest National Laboratory (PNNL) Automated Particulate Sampler was developed for the purpose of radionuclide particulate monitoring for use under the Comprehensive Test Ban Treaty (CTBT). Its design was directed by anticipated requirements of small size, low power consumption, low noise level, fully automatic operation, and most predominantly the sensitivity requirements of the Conference on Disarmament Working Paper 224 (CDWP224). This guide is intended to serve as both a reference document for the APS and to provide detailed instructions on how to operate the sampler. This document provides a complete description of the APS Field Test Model and all the activity related to its evaluation and progression.

Bowyer, S.M.; Miley, H.S.

1996-10-01T23:59:59.000Z

279

Diesel Particulate Filters and NO2 Emission Limits | Department...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Filters and NO2 Emission Limits Diesel Particulate Filters and NO2 Emission Limits EPAs New air quality standards for NO2 will impact future DPF designs deer09ibrahim.pdf More...

280

JV Task 95-Particulate Control Consulting for Minnesota Ore Operations  

SciTech Connect

The purpose of the project was to assist U.S. Steel in the evaluation, selection, planning, design, and testing of potential approaches to help meet U.S. Steel's goal for low-particulate matter emissions and regulatory compliance. The energy-intensive process for producing iron pellets includes treating the pellets in high-temperature kilns in which the iron is converted from magnetite to hematite. The kilns can be fired with either natural gas or a combination of gas and coal or biomass fuel and are equipped with wet venturi scrubbers for particulate control. Particulate measurements at the inlet and outlet of the scrubbers and analysis of size-fractionated particulate samples led to an understanding of the effect of process variables on the measured emissions and an approach to meet regulatory compliance.

Stanley Miller

2008-10-31T23:59:59.000Z

Note: This page contains sample records for the topic "nitrogen oxides particulate" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Zone heated inlet ignited diesel particulate filter regeneration  

SciTech Connect

An exhaust system that processes exhaust generated by an engine is provided. The system includes: a particulate filter (PF) that is disposed downstream of the engine and that filters particulates from the exhaust; and a grid that includes electrically resistive material that is segmented by non-conductive material into a plurality of zones and wherein the grid is applied to an exterior upstream surface of the PF.

Gonze, Eugene V [Pinckney, MI; Ament, Frank [Troy, MI

2012-06-26T23:59:59.000Z

282

PARTICULATE EMISSION ABATEMENT FOR KRAKOW BOILERHOUSES  

SciTech Connect

A U.S./Polish Bilateral Steering Committee (BSC) and the Department of Energy (DOE) selected LSR Technologies, Inc. as a contractor to participate in the Krakow Clean Fuels and Energy Efficiency Program. The objective of this program was the formation of business ventures between U.S. and Polish firms to provide equipment and services to reduce air emissions in the city of Krakow. A cooperative agreement was entered into by DOE and LSR to begin work in April 1994 involving implementation of particulate control technology called a Core Separator{trademark} for coal-fueled boilerhouses in the city. The major work tasks included: (1) conducting a market analysis, (2) completion of a formal marketing plan, (3) obtaining patent protection within Poland, (4) selecting a manufacturing partner, and (5) completing a demonstration unit and commercial installations. In addition to work performed by LSR Technologies, key contributors to this project were (1) the Polish Foundation for Energy Efficiency (FEWE), a non-profit consulting organization specializing in energy and environmental-related technologies, and (2) EcoInstal, a privately held Polish company serving the air pollution control market. As the project concluded in late 1998, five (5) Core Separator{trademark} installations had been implemented in the city of Krakow, while about 40 others were completed in other regions of Poland.

Bruce H. Easom; Leo A, Smolensky; S. Ronald Wysk; Jan Surowka; Miroslaw Litke; Jacek Ginter

1998-09-30T23:59:59.000Z

283

NETL: Ambient Monitoring - Southern Fine Particulate Monitoring Project  

NLE Websites -- All DOE Office Websites (Extended Search)

Southern Fine Particulate Monitoring Project (SRI) Southern Fine Particulate Monitoring Project (SRI) Southern Research Institute (SRI), Birmingham, AL, is operating a research station in North Birmingham for monitoring fine particulate matter (PM2.5) that exists in that part of the Deep South. The station will be a core PM2.5 mass monitoring and chemical speciation station in the nationwide EPA PM2.5 network. As such, it will be a complement and supplement to DOE-NETL's other ongoing projects for monitoring fine particulate matter in the upper Ohio River valley. Locating additional monitoring equipment in the Deep South will fill an important gap in the national particulate monitoring effort. The region's topography, weather patterns, and variety of emission sources may affect the chemical make-up and airborne transport of fine particles in ways that are different than in other parts of the country. The project's results will support DOE's comprehensive program to evaluate ambient fine particulate matter through better understanding of the chemical and physical properties of these materials.

284

Primary production, nutrients, and particulate matter in the southern California bight: Contributions to the C, N, and O/sub 2/ budgets: A component of the California Basin Study (CaBS): (Progress report, November 1988)  

SciTech Connect

A carbon budget has been developed for the euphotic zone in the surface waters of the Santa Monica Basin off Los Angeles, California, by CaBS. This grant provided several components of the budget: primary production, new production (equivalent to the sinking flux of biogenic particles out of the euphotic zone), standing stocks of particulate matter including particulate organic carbon, nitrogen and chlorophyll. Ancillary measurements of plant nutrients (nitrate, phosphate, silicic acid) were also made relative to primary and new production rates. The residence time of particulate matter in the euphotic zone was also determined as this is important for removal of particle-reactive substances, such as certain metals, hydrocarbons and chlorinated hydrocarbons. 12 refs., 1 tab.

Eppley, R.W.

1988-01-01T23:59:59.000Z

285

Method of removing nitrogen monoxide from a nitrogen monoxide-containing gas using a water-soluble iron ion-dithiocarbamate, xanthate or thioxanthate  

DOE Patents (OSTI)

A method of removing nitrogen monoxide from a nitrogen monoxide-containing gas, which method comprises: (a) contacting a nitrogen oxide-containing gas with an aqueous solution of water soluble organic compound-iron ion chelate of the formula: ##STR1## wherein the water-soluble organic compound is selected from compounds of the formula: ##STR2## wherein: R is selected from hydrogen or an organic moiety having at least one polar functional group; Z is selected from oxygen, sulfur, or --N--A wherein N is nitrogen and A is hydrogen or lower alkyl having from one to four carbon atoms; and M is selected from hydrogen, sodium or potassium; and n is 1 or 2, in a contacting zone for a time and at a temperature effective to reduce the nitrogen monoxide. These mixtures are useful to provide an unexpensive method of removing NO from gases, thus reducing atmospheric pollution from flue gases.

Liu, David K. (San Pablo, CA); Chang, Shih-Ger (El Cerrito, CA)

1989-01-01T23:59:59.000Z

286

Oxidation of Proximal Protein Sulfhydryls by Phenanthraquinone, a Component of Diesel Exhaust Particles  

Science Journals Connector (OSTI)

Oxidation of Proximal Protein Sulfhydryls by Phenanthraquinone, a Component of Diesel Exhaust Particles ... Diesel exhaust particles (DEP) contain quinones that are capable of catalyzing the generation of reactive oxygen species in biological systems, resulting in induction of oxidative stress. ... 9,10-Phenanthrenequinone (9,10-PQ) is a PAHQ found in diesel exhaust particulates ... ...

Yoshito Kumagai; Sachie Koide; Keiko Taguchi; Akiko Endo; Yumi Nakai; Toshikazu Yoshikawa; Nobuhiro Shimojo

2002-02-28T23:59:59.000Z

287

TiO2 nanoparticles on nitrogen-doped graphene as anode material for lithium ion batteries  

Science Journals Connector (OSTI)

Anatase TiO2...nanoparticles in situ grown on nitrogen-doped, reduced graphene oxide (rGO) have been successfully synthesized ... as an anode material for the lithium ion battery. The nanosized TiO2 particles wer...

Dan Li; Dongqi Shi; Zongwen Liu; Huakun Liu…

2013-04-01T23:59:59.000Z

288

Oxides Emissions from Coal-Fired Boilers TOPICAL REPORT NUMBER 14  

NLE Websites -- All DOE Office Websites (Extended Search)

Reburning Technologies for the Control of Nitrogen Reburning Technologies for the Control of Nitrogen Oxides Emissions from Coal-Fired Boilers TOPICAL REPORT NUMBER 14 MAY 1999 TOPICAL REPORT NUMBER 14 A report on three projects conducted under separate cooperative agreements between: The U.S. Department of Energy and * The Babcock & Wilcox Company * Energy and Environmental Research Corporation * New York State Electric & Gas Corporation MAY 1999 Reburning Technologies for the Control of Nitrogen Oxides Emissions from Coal-Fired Boilers Cover image: Schematic of reburning technology Source: Energy and Environmental Research Corporation Reburning Technologies for the Control of Nitrogen Oxides Emissions from Coal-Fired Boilers Executive Summary ..................................................................................................

289

Continuous particulate monitoring for emission control  

SciTech Connect

An optical continuous particle monitoring system has been developed to overcome common problems associated with emissions monitoring equipment. Opacity monitors generally use a single- or double-pass system to analyze the presence of dust particles in the flue gas stream. The particles scatter and absorb light as it passes through the stack. As the particle content in the gas stream increases due to bag failure or some other problem, the amount of light that is blocked also increases. The opacity monitor compares the amount of lost light energy to the total energy of the light available and translates the signal to percentage of opacity. Opacity monitors are typically installed to meet the requirements set forth by pollution control agencies. Most opacity monitors are designed to meet all of the requirements of the Environmental Protection Agency (EPA) 40 CFR, Part 60, Appendix B, Performance Specification. The new continuous particle monitor (CPM) increases the accuracy of emission monitoring and overcomes typical problems found in conventional emission monitoring devices. The CPM is an optically based, calibratible, continuous dust monitor that uses a microprocessor, transmitter head, and receiver head. When calibrated with an isokinetic sample, a continuous readout of particulate concentration (in mg/m[sup 3]) in the exhaust gas is provided. The system can be used as a filter bag failure system or a long-term emission trend analyzer. Formal testing was conducted to evaluate the effectiveness of the optically based CPM. The monitor was calibrated using particles of a range of compositions, size distributions, and concentrations. The feasibility of using the instrument to measure particle concentration as low as 10 mg/m[sup 3] was examined.

Bock, A.H. (BHA Group, Inc., Kansas City, MO (United States))

1993-08-01T23:59:59.000Z

290

Diesel Soot Oxidation with NO2:? Engine Experiments and Simulations  

Science Journals Connector (OSTI)

Diesel Soot Oxidation with NO2:? Engine Experiments and Simulations ... Particulate filtration in the exhaust system of diesel engines is increasingly gaining in importance for both light- and heavy-duty applications. ... The reaction rates are, in general, in the same order of magnitude with the engine-out soot emission rates. ...

Ioannis P. Kandylas; Onoufrios A. Haralampous; Grigorios C. Koltsakis

2002-09-20T23:59:59.000Z

291

Single Wall Diesel Particulate Filter (DPF) Filtration Efficiency Studies Using Laboratory Generated Particles  

SciTech Connect

Diesel offers higher fuel efficiency, but produces higher exhaust particulate matter. Diesel particulate filters are presently the most efficient means to reduce these emissions. These filters typically trap particles in two basic modes: at the beginning of the exposure cycle the particles are captured in the filter holes, and at longer times the particles form a "cake" on which particles are trapped. Eventually the "cake" removed by oxidation and the cycle is repeated. We have investigated the properties and behavior of two commonly used filters: silicon carbide (SiC) and cordierite (DuraTrap® RC) by exposing them to nearly-spherical ammonium sulfate particles. We show that the transition from deep bed filtration to "cake" filtration can easily be identified by recording the change in pressure across the filters as a function of exposure. We investigated performance of these filters as a function of flow rate and particle size. The filters trap small and large particles more efficiently than particles that are ~80 to 200 nm in aerodynamic diameter. A comparison between the experimental data and a simulation using incompressible lattice-Boltzmann model shows very good qualitative agreement, but the model overpredicts the filter’s trapping efficiency.

Yang, Juan; Stewart, Marc; Maupin, Gary D.; Herling, Darrell R.; Zelenyuk, Alla

2009-04-15T23:59:59.000Z

292

EIA - Greenhouse Gas Emissions - Nitrous Oxide Emissions  

Gasoline and Diesel Fuel Update (EIA)

4. Nitrous Oxide Emissions 4. Nitrous Oxide Emissions 4.1 Total emissions U.S. nitrous oxide emissions in 2009 were 4 MMTCO2e (1.7 percent) below their 2008 total (Table 22). Sources of U.S. nitrous oxide emissions include agriculture, energy use, industrial processes, and waste management (Figure 22). The largest source is agriculture (73 percent), and the majority of agricultural emissions result from nitrogen fertilization of agricultural soils (87 percent of the agriculture total) and management of animal waste (13 percent). U.S. nitrous oxide emissions rose from 1990 to 1994, fell from 1994 to 2002, and returned to an upward trajectory from 2003 to 2007, largely as a result of increased use of synthetic fertilizers. Fertilizers are the primary contributor of emissions from nitrogen fertilization of soils, which grew by more than 30 percent from

293

Increased Cytotoxicity of Oxidized Flame Soot  

NLE Websites -- All DOE Office Websites (Extended Search)

Increased Cytotoxicity of Oxidized Flame Soot Increased Cytotoxicity of Oxidized Flame Soot Title Increased Cytotoxicity of Oxidized Flame Soot Publication Type Journal Article Year of Publication 2012 Authors Holder, Amara L., Brietta J. Carter, Regine Goth-Goldstein, Donald Lucas, and Catherine P. Koshland Journal Atmospheric Pollution Research Volume 3 Start Page 25 Issue 1 Pagination 25-31 Date Published 01/2012 Keywords health effects, ozone, soot, toxicity Abstract Combustion-generated particles released into the atmosphere undergo reactions with oxidants, which can change the particles' physiochemical characteristics. In this work, we compare the physical and chemical properties and cellular response of particles fresh from a flame with those oxidized by ozone and nitrogen dioxide. The reaction with ozone and nitrogen dioxide does not significantly modify the physical characteristics of the particles (primary particle size, fractal dimension, and surface area). However, oxidation affects the chemical characteristics of the particles, creating more oxygen and nitrogen containing functional groups, and increases their hydrophilicity. In addition, oxidized soot generates more reactive oxygen species, as measured by the dithiothreitol (DTT) assay. Furthermore, oxidized soot is 1.5-2 times more toxic than soot that was not reacted with ozone, but the inflammatory response, measured by interleukin-8 (IL-8) secretion, is unchanged. These results imply that combustion-generated particles released into the atmosphere will have an increased toxicity on or after high ozone days.

294

Frostbite Theater - Liquid Nitrogen Experiments - Liquid Nitrogen and Fire!  

NLE Websites -- All DOE Office Websites (Extended Search)

Antifreeze! Antifreeze! Previous Video (Liquid Nitrogen and Antifreeze!) Frostbite Theater Main Index Next Video (Liquid Nitrogen and the Tea Kettle Mystery!) Liquid Nitrogen and the Tea Kettle Mystery! Liquid Nitrogen and Fire! A burning candle is placed in a container of liquid nitrogen! Filmed in front of a live studio audience. Well, they were live when we started... [ Show Transcript ] Announcer: Frostbite Theater presents... Cold Cuts! No baloney! Joanna and Steve: Just science! Steve: Now, then. I'm a little bit afraid to ask this next question because I think I already know the answer, but is anyone in here feeling a little... dangerous? You're willing to take a chance? Because I am willing to do an experiment they haven't let me do since 'The Incident.' Now, because of the danger, I cannot have a volunteer. I must do this on my

295

Particulate control for low rank coals  

SciTech Connect

The power generating system in Victoria currently comprises a total capacity of 6650 MW. Eighty percent of this capacity consists of base load stations in the Latrobe Valley using brown coal. The Latrobe Valley brown coals have unique characteristics with high moisture content ranging from 58 percent to 70 percent and an ash content which is relatively low but very variable in nature. These and other factors associated with the coal have caused special problems in handling and combustion of the coal and the de-dusting of the boiler flue gases. In recent years, this has been the basis for the design parameters adopted for all the plants in the system. With respect to flue gas de-dusting, the SECV has carried out extensive laboratory studies to characterize the different ashes obtained from the Latrobe Valley brown coals, including precipitability and aerodynamic tests. It also carried out full-scale tests on operating plants and pilot tests have been conducted on inertial collectors, precipitators and bag filters. The Environmental Protection Authority of Victoria has established a particulate emission level of 0.150 grams/m{sup 3} n.t.p. dry for recent Latrobe Valley boilers. However, the mandated emission level takes into account wide variations in operating conditions, and the plants normally achieve much lower emission levels. The Latrobe Valley plants presently in operation include Yallourn W (2x350 MW + 2x375 MW), Morwell (170 MW total and briquette factory), Hazelwood (8x200 MW) and Loy Yang (4x500 MW). The Yalloum W boilers are supplied with coal from the Yalloum Open Cut, the Morwell and Hazelwood boilers from the Morwell Open Cut and Loy Yang boilers from the Loy Yang Open Cut. All boilers are pulverized coal fired (PCF) and incorporate special firing equipment to enable the as-mined wet coal to be fired directly into the furnaces. All boilers are fitted with electrostatic precipitators. The locations of the stations and open cuts are shown.

Touzel, R.McD.

1993-12-31T23:59:59.000Z

296

What Happens to Nitrogen in Soils?  

E-Print Network (OSTI)

This publication explains the chemistry of nitrogen, the processes by which nitrogen is added to and removed from the soil, and methods of preventing nitrogen losses on agricultural lands....

Provin, Tony; Hossner, L. R.

2001-07-09T23:59:59.000Z

297

Contribution of organic carbon to wood smoke particulate matter absorption  

NLE Websites -- All DOE Office Websites (Extended Search)

Contribution of organic carbon to wood smoke particulate matter absorption Contribution of organic carbon to wood smoke particulate matter absorption of solar radiation Title Contribution of organic carbon to wood smoke particulate matter absorption of solar radiation Publication Type Journal Article Year of Publication 2012 Authors Kirchstetter, Thomas W., and Tracy L. Thatcher Journal Atmospheric Chemistry and Physics Volume 12 Pagination 6067-6072 Abstract A spectroscopic analysis of 115 wintertime partic- ulate matter samples collected in rural California shows that wood smoke absorbs solar radiation with a strong spectral se- lectivity. This is consistent with prior work that has demon- strated that organic carbon (OC), in addition to black car- bon (BC), appreciably absorbs solar radiation in the visible and ultraviolet spectral regions. We apportion light absorp-

298

Apparatus and method for void/particulate detection  

DOE Patents (OSTI)

Apparatus and method for detecting voids and particulates in a fluid within a containing vessel. A diffuse ultrasonic signal is coupled into the fluid by a first transducer and the portion of the ultrasonic signal transmitted through the fluid is detected by a second transducer. The received signal is analyzed by a processor to determine the void fraction of the fluid responsive to the attenuation of the received ultrasonic signal. In addition, voids and particulates are detected by evaluating the increase in side-band energy of the received signal.

Claytor, Thomas N. (Woodridge, IL); Ockert, Carl E. (Vienna, VA); Randall, Richard (Canoga Park, CA)

1987-01-01T23:59:59.000Z

299

A particulate non-specific alkaline phosphatase in Saccharomyces cerevisiae  

E-Print Network (OSTI)

. Dennis J. Opheim A previously undefined alkaline phosphatase in yeast, which is particulate, has been found. This latter form has no mobil- ity on polyacrylamide gels and can be sedimented after centri- fugation at 200, 000 x g for one hour. Over 90X... of the enzyme activity can be solubilized from the particulate fraction with 100 mM sodium cholate. In the solubilized state this enzyme has been found to migrate in the same position on polyacrylamide gels as the already known soluble repressible alkaline...

Mitchell, James Kent

1980-01-01T23:59:59.000Z

300

Investigation of formation of nitrogen compounds in coal combustion. Final report  

SciTech Connect

This is the final report on DOE contract number DE-AC21-80MC14061. It concerns the formation of nitrogen oxide from fuel-bound nitrogen during coal combustion. The work reported was divided into three tasks. They addressed problems of time-resolving pyrolysis rates of coal under simulated combustion conditions, the combustion of the tar that results from such pyrolysis, and theoretical modeling of the pyrolysis process. In all of these tasks, special attention was devoted to the fate of coal nitrogen. The first two tasks were performed by Exxon Research and Engineering Company. 49 references.

Blair, D.W.; Crane, I.D.; Wendt, J.O.L.

1983-10-01T23:59:59.000Z

Note: This page contains sample records for the topic "nitrogen oxides particulate" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Imaging of Diesel Particulate Filters using a High-Flux Neutron...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Imaging of Diesel Particulate Filters using a High-Flux Neutron Source Imaging of Diesel Particulate Filters using a High-Flux Neutron Source Detailed images of deposits identified...

302

Radio Frequency Diesel Particulate Filter Sensor Reduces Fuel Consumption, Wins R&D 100 Award  

Office of Energy Efficiency and Renewable Energy (EERE)

Radio Frequency Diesel Particulate Filter Sensor (RF-DPF) is a sensor that uses radio frequencies to measure the amount and distribution of soot and ash in the filters that remove particulate matter from the exhaust of diesel engines.

303

Development of a Sub-Grid Model of a Diesel Particulate Filter...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Sub-Grid Model of a Diesel Particulate Filter: application of the lattice-Boltzmann technique Development of a Sub-Grid Model of a Diesel Particulate Filter: application of the...

304

The effect of lubricant derived ash on the catalytic activity of diesel particulate filters  

E-Print Network (OSTI)

A diesel particulate filter (DPF) is an aftertreatment device used to remove hazardous particulate matter (PM) from diesel engine exhaust. Modem emission restrictions have limited the acceptable amount of PM output by ...

Murray, Timothy Quinn

2014-01-01T23:59:59.000Z

305

Macrophage-Mediated Endothelial Inflammatory Responses to Airborne Particulates: Impact of  

E-Print Network (OSTI)

-Fe/F-Al-Si). We have used these particulates, as well as coal fly ash (CFA) and diesel exhaust particulates (DEP remain unresolved. Using a microporous aluminosilicate zeolite Y as a manifold, we have synthesized 1 µm

Dutta, Prabir K.

306

Testing an Active Diesel Particulate Filter on a 2-Cycle Marine...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Testing an Active Diesel Particulate Filter on a 2-Cycle Marine Engine Testing an Active Diesel Particulate Filter on a 2-Cycle Marine Engine Presentation given at DEER 2006,...

307

Frostbite Theater - Liquid Nitrogen Experiments - Instant Liquid Nitrogen  

NLE Websites -- All DOE Office Websites (Extended Search)

Freezing Balloons! Freezing Balloons! Previous Video (Freezing Balloons!) Frostbite Theater Main Index Next Video (Shattering Flowers!) Shattering Flowers! Instant Liquid Nitrogen Balloon Party! Need a bunch of balloons blown-up quickly? Liquid nitrogen to the rescue! [ Show Transcript ] Announcer: Frostbite Theater presents... Cold Cuts! No baloney! Joanna and Steve: Just science! Joanna: Hi! I'm Joanna! Steve: And I'm Steve! Joanna: We've been making videos for a while now and we've learned that people like balloons and liquid nitrogen! Steve: So... Here you go! Balloon: Crackling... Balloon: Pop! Joanna: Ooh! Balloon: Pop! Balloon: Pop! Steve: If you'd like to know the science of what's going on behind this, please one of our first videos, "Liquid Nitrogen Experiments: The Balloon."

308

Characterization of Particulate Emissions from GDI Engine Combustion with Alcohol-blended Fuels  

Energy.gov (U.S. Department of Energy (DOE))

Analysis showed that gasoline direct injection engine particulates from alcohol-blended fuels are significantly different in morphology and nanostructures

309

Characterization of Pre-Commercial Gasoline Engine Particulates Through Advanced Aerosol Methods  

Energy.gov (U.S. Department of Energy (DOE))

Advanced aerosol analysis methods were used to examine particulates from single cylinder test engines running on gasoline and ethanol blends.

310

Higher modulus compositions incorporating particulate rubber  

DOE Patents (OSTI)

A plastic article having a number of surfaces with at least one surface being modified by contacting that surface with a reactive gas atmosphere containing F.sub.2, Cl.sub.2, O.sub.2, Ozone, SO.sub.3, oxidative acids, or mixtures thereof, at a temperature and gas partial pressure sufficient to increase the surface energy of the at least one surface being modified to at least 40 dynes/cm at a temperature of 20.degree. C., to enhance bonding of non-slip polymer coatings to the modified surface, to which coatings elastomeric or rigid particles may be admixed for imparting a surface profile and increasing the coefficient of friction between the coated surface and the counter-surface.

Bauman, Bernard D. (Emmaus, PA); Williams, Mark A. (Souderton, PA)

1999-01-01T23:59:59.000Z

311

Policy Brief October 2014  

E-Print Network (OSTI)

Standard) for electricity generation, reduced fuel carbon intensity (Low Carbon Fuel Standard), improvement by each AB 32 sector or sub-sector for total particulate matter (PM), particulate elemental carbon (EC), particulate organic carbon (OC), oxides of nitrogen (NOx), oxides of sulfur (SOx), reactive organic gases (ROG

California at Davis, University of

312

Direct Capillary Gas Chromatography of Filter-Borne Particulate Emissions from Diesel Engines  

Science Journals Connector (OSTI)

......Filter-Borne Particulate Emissions from Diesel Engines R.D. Cuthbertson P.R. Shore...Filter-Borne Particulate Emissions from Diesel Engines R.D. Cuthbertson and P.R...oil-derived material. Introduction Diesel engines emit particulate matter consisting......

R.D. Cuthbertson; P.R. Shore

1988-03-01T23:59:59.000Z

313

PII S0016-7037(99)00361-0 Dissolved and particulate carbohydrates in contrasting marine sediments  

E-Print Network (OSTI)

PII S0016-7037(99)00361-0 Dissolved and particulate carbohydrates in contrasting marine sediments D) and mid-Atlantic shelf/slope break (continental margin) sediments. Particulate carbohydrates (PCHOs) rep- resented 5­9% of the total sediment particulate organic carbon (POC), and PCHO remineralization appeared

Burdige, David

314

REVIEW OF DIESEL PARTICULATE MATTER SAMPLING METHODS Supplemental Report # 1  

E-Print Network (OSTI)

.D. and Megan Arnold University of Minnesota Department of Mechanical Engineering Center for Diesel Research obtained from engine laboratory visits and present results from a diesel aerosol sampling questionnaireREVIEW OF DIESEL PARTICULATE MATTER SAMPLING METHODS Supplemental Report # 1 DIESEL EXHAUST

Minnesota, University of

315

Removal of residual particulate matter from filter media  

DOE Patents (OSTI)

A method for removing residual filter cakes that remain adhered to a filter after typical particulate removal methodologies have been employed, such as pulse-jet filter element cleaning, for all cleanable filters used for air pollution control, dust control, or powder control.

Almlie, Jay C; Miller, Stanley J

2014-11-11T23:59:59.000Z

316

NUCLEATION PHENOMENON IN SiC PARTICULATE REINFORCED MAGNESIUM COMPOSITE  

E-Print Network (OSTI)

NUCLEATION PHENOMENON IN SiC PARTICULATE REINFORCED MAGNESIUM COMPOSITE Y. Cai, D. Taplin, M.J. Tan performance of matrix metals and alloys. Most magnesium alloy based MMCs are produced via a casting process into the last freezing interdendritic regions. For magnesium based composites, both particle pushing (or capture

Zhou, Wei

317

The distribution of particulate aluminum in the Gulf of Mexico  

E-Print Network (OSTI)

of runoff water in the oceans. Toyota and Okabe (1967) reported vertical distri- butions of particulate aluminum ranging from 1-50 ug Al/L in samples from the Western North Pacific, Indian and Antarctic Oceans. , Stefansson and Atkinson (1969) used...

Feely, Richard Alan

1971-01-01T23:59:59.000Z

318

Particulate matter as an amplifier for astronomical light pollution  

Science Journals Connector (OSTI)

......increased emission of particulate matter in the winter, mainly from coal-fired home heating systems (so-called low emission...Nielsen C. P., eds. Clearing the Air: The Health and Economic Damages of Air Pollution in China (2007) Cambridge, MA......

T. ?ci?zor; M. Kubala

2014-01-01T23:59:59.000Z

319

It's Elemental - The Element Nitrogen  

NLE Websites -- All DOE Office Websites (Extended Search)

Carbon Carbon Previous Element (Carbon) The Periodic Table of Elements Next Element (Oxygen) Oxygen The Element Nitrogen [Click for Isotope Data] 7 N Nitrogen 14.0067 Atomic Number: 7 Atomic Weight: 14.0067 Melting Point: 63.15 K (-210.00°C or -346.00°F) Boiling Point: 77.36 K (-195.79°C or -320.44°F) Density: 0.0012506 grams per cubic centimeter Phase at Room Temperature: Gas Element Classification: Non-metal Period Number: 2 Group Number: 15 Group Name: Pnictogen What's in a name? From the Greek words nitron and genes, which together mean "saltpetre forming." Say what? Nitrogen is pronounced as NYE-treh-gen. History and Uses: Nitrogen was discovered by the Scottish physician Daniel Rutherford in 1772. It is the fifth most abundant element in the universe and makes up

320

Nitrogen removal from natural gas  

SciTech Connect

According to a 1991 Energy Information Administration estimate, U.S. reserves of natural gas are about 165 trillion cubic feet (TCF). To meet the long-term demand for natural gas, new gas fields from these reserves will have to be developed. Gas Research Institute studies reveal that 14% (or about 19 TCF) of known reserves in the United States are subquality due to high nitrogen content. Nitrogen-contaminated natural gas has a low Btu value and must be upgraded by removing the nitrogen. In response to the problem, the Department of Energy is seeking innovative, efficient nitrogen-removal methods. Membrane processes have been considered for natural gas denitrogenation. The challenge, not yet overcome, is to develop membranes with the required nitrogen/methane separation characteristics. Our calculations show that a methane-permeable membrane with a methane/nitrogen selectivity of 4 to 6 would make denitrogenation by a membrane process viable. The objective of Phase I of this project was to show that membranes with this target selectivity can be developed, and that the economics of the process based on these membranes would be competitive. Gas permeation measurements with membranes prepared from two rubbery polymers and a superglassy polymer showed that two of these materials had the target selectivity of 4 to 6 when operated at temperatures below - 20{degrees}C. An economic analysis showed that a process based on these membranes is competitive with other technologies for small streams containing less than 10% nitrogen. Hybrid designs combining membranes with other technologies are suitable for high-flow, higher-nitrogen-content streams.

NONE

1997-04-01T23:59:59.000Z

Note: This page contains sample records for the topic "nitrogen oxides particulate" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Superior catalysts for selective catalytic reduction of nitric oxide. Quarterly technical progress report, January 1, 1995--March 31, 1995  

SciTech Connect

During this quarter, progress was made on the following tasks: TPD techniques were employed to study the reaction mechanism of the selective catalytic reduction of nitrogen oxide with ammonia over iron oxide pillared clay catalyst; and a sulfur dioxide resistant iron oxide/titanium oxide catalyst was developed.

Li, W.B.; Yang, R.T.

1995-12-01T23:59:59.000Z

322

Seasonal trends in the composition and ROS activity of fine particulate matter in Baghdad, Iraq  

Science Journals Connector (OSTI)

Abstract Baghdad suffers from severe atmospheric particulate matter (PM) pollution and has limited infrastructure to monitor and control PM-pollution. To help better understand the nature of particulate matter in Baghdad, daily PM2.5 samples were collected every 6th day from September, 2012 to September, 2013. The samples were analyzed for chemical composition and cellular oxidative stress activity using a macrophage-based assay. The annual average PM2.5 concentration was 50 ± 19 ?g m?3, and was comprised of approximately 28% crustal materials, 26% organic carbon (OC), 17% sulfate, 12% elemental carbon (EC), and 8.0% ammonium ion. No clear seasonal trend was observed for the total PM2.5 mass and PM2.5 OC, but EC exhibited higher concentrations in the warmer months, likely due to the extensive use of electric generators operated by diesel and gasoline for cooling. April showed the lowest levels of both EC and OC compared with other months due to both sand and rainstorm events which led to increased deposition and dispersion of local emissions. Concentrations of nitrate ion were low in all seasons due to the high temperatures and low humidity, but slightly higher levels were observed in the cooler months of winter. The oxidative stress (reactive oxygen species (ROS)) activity (59 ± 35 ?g Zymosan equivalents m?3) of the PM was relatively lower than in other studied areas. Association between the water soluble PM constituents and the oxidative activity was investigated using a multi-linear regression model which showed no strong relationships between ROS activity and the water soluble components of PM2.5, but a moderate correlation of water soluble organic carbon from biomass burning (WSOC-BB) was observed (R2 = 0.52). Biomass burning PM has been shown to be an important contributor to ROS activity in other published studies, but additional work is needed to better understand the sources leading to the ROS activity in Baghdad.

Samera Hussein Hamad; Martin Merrill Shafer; Ahmed K.H. Kadhim; Sabah M. Al-Omran; James Jay Schauer

2015-01-01T23:59:59.000Z

323

Biodiesel versus diesel exposure: Enhanced pulmonary inflammation, oxidative stress, and differential morphological changes in the mouse lung  

SciTech Connect

The use of biodiesel (BD) or its blends with petroleum diesel (D) is considered to be a viable approach to reduce occupational and environmental exposures to particulate matter (PM). Due to its lower particulate mass emissions compared to D, use of BD is thought to alleviate adverse health effects. Considering BD fuel is mainly composed of unsaturated fatty acids, we hypothesize that BD exhaust particles could induce pronounced adverse outcomes, due to their ability to readily oxidize. The main objective of this study was to compare the effects of particles generated by engine fueled with neat BD and neat petroleum-based D. Biomarkers of tissue damage and inflammation were significantly elevated in lungs of mice exposed to BD particulates. Additionally, BD particulates caused a significant accumulation of oxidatively modified proteins and an increase in 4-hydroxynonenal. The up-regulation of inflammatory cytokines/chemokines/growth factors was higher in lungs upon BD particulate exposure. Histological evaluation of lung sections indicated presence of lymphocytic infiltrate and impaired clearance with prolonged retention of BD particulate in pigment laden macrophages. Taken together, these results clearly indicate that BD exhaust particles could exert more toxic effects compared to D. - Highlights: • Exposure of mice to BDPM caused higher pulmonary toxicity compared to DPM. • Oxidative stress and inflammation were higher in BD vs to D exposed mice. • Inflammatory lymphocyte infiltrates were seen only in lungs of mice exposed to BD. • Ineffective clearance, prolonged PM retention was present only after BD exposure.

Yanamala, Naveena, E-mail: wqu1@cdc.gov [Pathology and Physiology Research Branch/NIOSH/CDC, Morgantown, WV 26505 (United States); Hatfield, Meghan K., E-mail: wla4@cdc.gov [Pathology and Physiology Research Branch/NIOSH/CDC, Morgantown, WV 26505 (United States); Farcas, Mariana T., E-mail: woe7@cdc.gov [Pathology and Physiology Research Branch/NIOSH/CDC, Morgantown, WV 26505 (United States); Schwegler-Berry, Diane [Pathology and Physiology Research Branch/NIOSH/CDC, Morgantown, WV 26505 (United States); Hummer, Jon A., E-mail: qzh3@cdc.gov [Office of Mine Safety and Health Research/NIOSH/CDC, Pittsburgh, PA 15236 (United States); Shurin, Michael R., E-mail: shurinmr@upmc.edu [Department of Pathology, University of Pittsburgh Medical Center, Pittsburgh, PA (United States); Birch, M. Eileen, E-mail: mib2@cdc.gov [NIOSH/CDC, 4676 Columbia Parkway, Cincinnati, OH 45226 (United States); Gutkin, Dmitriy W., E-mail: dwgutkin@hotmail.com [Department of Pathology, University of Pittsburgh Medical Center, Pittsburgh, PA (United States); Kisin, Elena, E-mail: edk8@cdc.gov [Pathology and Physiology Research Branch/NIOSH/CDC, Morgantown, WV 26505 (United States); Kagan, Valerian E., E-mail: kagan@pitt.edu [Department of Environmental and Occupational Health, University of Pittsburgh, PA (United States); Bugarski, Aleksandar D., E-mail: zjl1@cdc.gov [Office of Mine Safety and Health Research/NIOSH/CDC, Pittsburgh, PA 15236 (United States); Shvedova, Anna A., E-mail: ats1@cdc.gov [Pathology and Physiology Research Branch/NIOSH/CDC, Morgantown, WV 26505 (United States); Department Physiology and Pharmacology, WVU, Morgantown, WV 26505 (United States)

2013-10-15T23:59:59.000Z

324

Assessment of the Use of Nitrogen Trifluoride for Purifying Coolant and Heat Transfer Salts in the Fluoride Salt-Cooled High-Temperature Reactor  

SciTech Connect

This report provides an assessment of the use of nitrogen trifluoride for removing oxide and water-caused contaminants in the fluoride salts that will be used as coolants in a molten salt cooled reactor.

Scheele, Randall D.; Casella, Andrew M.

2010-09-28T23:59:59.000Z

325

Metal Oxides  

Science Journals Connector (OSTI)

Metal oxides are the class of materials having the widest application in gas sensors. This chapter presents information related to the application of various metal oxides in gas sensors designed on different p...

Ghenadii Korotcenkov

2013-01-01T23:59:59.000Z

326

Nitrogen-doped graphene as transparent counter electrode for efficient dye-sensitized solar cells  

SciTech Connect

Graphical abstract: Display Omitted Highlights: ? NG sheets are prepared through a hydrothermal reduction of graphite oxide. ? The transparent NG counter electrodes of DSCs are fabricated at room temperature. ? Transparent NG electrode exhibits excellent catalytic activity for the reduction of I{sub 3}{sup ?}. ? The DSC with NG electrode achieves a comparable efficiency to that of the Pt-based cell. ? The efficiency of rear illumination is about 85% that of front illumination. -- Abstract: Nitrogen-doped graphene sheets are prepared through a hydrothermal reduction of graphite oxide in the presence of ammonia and applied to fabricate the transparent counter electrode of dye-sensitized solar cells. The atomic percentage of nitrogen in doped graphene sample is about 2.5%, and the nitrogen bonds display pyridine and pyrrole-like configurations. Cyclic voltammetry studies demonstrate a much higher electrocatalytic activity toward I{sup ?}/I{sub 3}{sup ?} redox reaction for nitrogen-doped graphene, as compared with pristine graphene. The dye-sensitized solar cell with this transparent nitrogen-doped graphene counter electrode shows conversion efficiencies of 6.12% and 5.23% corresponding to front-side and rear-side illumination, respectively. Meanwhile, the cell with a Pt counter electrode shows a conversion efficiency of 6.97% under the same experimental condition. These promising results highlight the potential application of nitrogen-doped graphene in cost-effective, transparent dye-sensitized solar cells.

Wang, Guiqiang, E-mail: wgqiang123@163.com [School of Chemical Engineering, Shandong University of Technology, Zibo 255049 (China)] [School of Chemical Engineering, Shandong University of Technology, Zibo 255049 (China); Fang, Yanyan; Lin, Yuan [Institute of Chemistry, Chinese Academy of Science, Beijing 100080 (China)] [Institute of Chemistry, Chinese Academy of Science, Beijing 100080 (China); Xing, Wei; Zhuo, Shuping [School of Chemical Engineering, Shandong University of Technology, Zibo 255049 (China)] [School of Chemical Engineering, Shandong University of Technology, Zibo 255049 (China)

2012-12-15T23:59:59.000Z

327

Technology Innovations and Experience Curves for Nitrogen Oxides Control Technologies  

E-Print Network (OSTI)

air preheater interactions). SCR pro- cess improvements that1987; CS-5361s. 13. 13. SCR Projects Bid and Award Tracking;Catalytic Reduction (SCR) Control of NO x Emissions; SCR

Yeh, Sonia; Rubin, Edward S.; Taylor, Margaret R.

2007-01-01T23:59:59.000Z

328

Persistent sensitivity of Asian aerosol to emissions of nitrogen oxides  

E-Print Network (OSTI)

We use a chemical transport model and its adjoint to examine the sensitivity of secondary inorganic aerosol formation to emissions of precursor trace gases from Asia. Sensitivity simulations indicate that secondary inorganic ...

Kharol, S. K.

329

EFFECT OF NITROGEN OXIDE PRETREATMENTS ON ENZYMATIC HYDROLYSIS OF CELLULOSE  

E-Print Network (OSTI)

Bioconversion of Cellulose and Production of Ethanol," LBL-of Cellulose and the Production of Ethanol," LBL-6859,the cellulose is a major obstacle to hydrolysis. Ethanol The

Borrevik, R.K.

2011-01-01T23:59:59.000Z

330

EFFECT OF NITROGEN OXIDE PRETREATMENTS ON ENZYMATIC HYDROLYSIS OF CELLULOSE  

E-Print Network (OSTI)

Jerusalem, loR. Parkinson, Tappi, Meller, Holzforschung,L.L. Schaleger and D.L. Brink, Tappi, No.4, 65 ( 1978). N.I.Holocellulose in Wood," Tappi Standard T9 m-54. C.R.

Borrevik, R.K.

2011-01-01T23:59:59.000Z

331

Characterization of vanadate-dependent NADH oxidation stimulated by Saccharomyces cerevisiae plasma membranes.  

Science Journals Connector (OSTI)

...oxidation activity of yeast plasma membranes for molecular DH...vanadate-dependent nonenzymatic and plasma mem- DH. Each point is brane-stimulated...aFor nonenzymatic nitrogen atmosphere, but NADH oxidation resumed...consumption of oxygen during Plasma membrane- the oxidation of...

L A Minasi; G R Willsky

1991-01-01T23:59:59.000Z

332

Engines - Particulate Studies - Revealing the True Nature of Diesel  

NLE Websites -- All DOE Office Websites (Extended Search)

Engine Nanoparticle Research: Revealing the True Nature of Diesel Particulates Engine Nanoparticle Research: Revealing the True Nature of Diesel Particulates Thermophoretic sampling device Argonne's test engine with the thermophoretic sampling device attached. Nanostructure of graphitic diesel soot under high engine load A transmission electron microscope reveals the nanostructures of graphitic diesel soot sampled under high engine loads. Morphology of particles collected from diesel combustion with iso-paraffin-enriched fuel. Morphology of particles collected from diesel combution with iso-paraffin-enriched fuel. Amorphous soot particle collected from biodiesel combustion undera low-temperature condition. Amorphous soot particle collected from biodiesel combustion under low temperature conditions. Researchers have many ideas about how to reduce the soot produced by diesel

333

Design characteristics for facilities which process hazardous particulate  

SciTech Connect

Los Alamos National Laboratory is establishing a research and processing capability for beryllium. The unique properties of beryllium, including light weight, rigidity, thermal conductivity, heat capacity, and nuclear properties make it critical to a number of US defense and aerospace programs. Concomitant with the unique engineering properties are the health hazards associated with processing beryllium in a particulate form and the potential for worker inhalation of aerosolized beryllium. Beryllium has the lowest airborne standard for worker protection compared to all other nonradioactive metals by more than an order of magnitude. This paper describes the design characteristics of the new beryllium facility at Los Alamos as they relate to protection of the workforce. Design characteristics to be reviewed include; facility layout, support systems to minimize aerosol exposure and spread, and detailed review of the ventilation system design for general room air cleanliness and extraction of particulate at the source.

Abeln, S.P.; Creek, K.; Salisbury, S.

1998-12-01T23:59:59.000Z

334

High efficiency particulate removal with sintered metal filters  

SciTech Connect

Because of their particle removal efficiencies and durability, sintered metal filters have been chosen for high efficiency particulate air (HEPA) filter protection in the off-gas treatment system for the proposed Idaho National Engineering Laboratory Transuranic Waste Treatment Facility. Process evaluation of sintered metal filters indicated a lack of sufficient process design data to ensure trouble-free operation. Subsequence pilot scale testing was performed with flyash as the test particulate. The test results showed that the sintered metal filters can have an efficiency greater than 0.9999999 for the specific test conditions used. Stable pressure drop characteristics were observed in pulsed and reversed flow blowback modes of operation. Over 4900 hours of operation were obtained with operating conditions ranging up to approximately 90/sup 0/C and 24 vol % water vapor in the gas stream.

Kirstein, B.E.; Paplawsky, W.J.; Pence, D.T.; Hedahl, T.G.

1981-01-01T23:59:59.000Z

335

Advanced hybrid particulate collector and method of operation  

DOE Patents (OSTI)

A device and method for controlling particulate air pollutants of the present invention combines filtration and electrostatic collection devices. The invention includes a chamber housing a plurality of rows of filter elements. Between the rows of filter elements are rows of high voltage discharge electrodes. Between the rows of discharge electrodes and the rows of filter elements are grounded perforated plates for creating electrostatic precipitation zones.

Miller, Stanley J. (Grand Forks, ND)

2003-04-08T23:59:59.000Z

336

Kinetics and mechanisms of interactions of nitrogen and carbon monoxide with liquid niobium  

SciTech Connect

The kinetics and mechanisms of interactions of N{sub 2} and CO with liquid niobium were investigated in the temperature range of 2,700 to 3,000 K in samples levitated in N{sub 2}/Ar and CO/Ar streams. The nitrogen absorption and desorption processes were found to be second-order with respect to nitrogen concentration, indicating that the rate controlling step is either the adsorption of nitrogen molecules on the liquid surface or dissociation of absorbed nitrogen molecules into adsorbed atoms. The carbon and oxygen dissolution in liquid niobium from CO gas is an exothermic process and the solubilities of carbon and oxygen (C{sub Ce}, C{sub Oe} in at%) are related to the temperature and the partial pressure of CO. The reaction CO {yields} (C) + (O) along with the evaporation of niobium oxide takes place during C and O dissolution, whereas C and O desorption occurs via CO evolution only.

Park, H.G.

1990-01-01T23:59:59.000Z

337

Source Apportionment of Airborne Particulate Matter using Inorganic and  

NLE Websites -- All DOE Office Websites (Extended Search)

Source Apportionment of Airborne Particulate Matter using Inorganic and Source Apportionment of Airborne Particulate Matter using Inorganic and Organic Species as Tracers Title Source Apportionment of Airborne Particulate Matter using Inorganic and Organic Species as Tracers Publication Type Journal Article Year of Publication 2012 Authors Wang, Yungang, Philip K. Hopke, X. Xia, Oliver V. Rattigan, David C. Chalupa, and M. J. Source Journal Atmospheric Environment Volume 55 Start Page 525 Pagination 525-532 Date Published 01/2012 Keywords source apportionment positive matrix factorization (pmf) particulate matter (pm) molecular markers (mm) aethalometer delta-c Abstract Source apportionment is typically performed on chemical composition data derived from particulate matter (PM) samples. However, many common sources no longer emit significant amounts of characteristic trace elements requiring the use of more comprehensive chemical characterization in order to fully resolve the PM sources. Positive matrix factorization (EPA PMF, version 4.1) was used to analyze 24-hr integrated molecular marker (MM), secondary inorganic ions, trace elements, carbonaceous species and light absorption data to investigate sources of PM2.5 in Rochester, New York between October 2009 and October 2010 to explore the role of specific MMs. An eight-factor solutionwas found for which the factors were identified as isoprene secondary organic aerosol (SOA), airborne soil, other SOA, diesel emissions, secondary sulfate, wood combustion, gasoline vehicle, and secondary nitrate contributing 6.9%, 12.8%, 3.7%, 7.8%, 45.5%, 9.1%, 7.9%, and 6.3% to the average PM2.5 concentration, respectively Concentrations of pentacosane, hexacosane, heptacosane, and octacosane in the gasoline vehicles factor were larger compared to diesel emissions. Aethalometer Delta-C was strongly associated with wood combustion. The compounds, n-heptacosanoic acid and n-octacosanoic acid, occasionally used in the past as tracers for road dust, were found to largely associate with SOA in this study. In comparison with a standard PMF analyses without MM, inclusion of themwas necessary to resolve SOA and wood combustion factors in urban areas.

338

Stanford Nitrogen Group | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Stanford Nitrogen Group Stanford Nitrogen Group National Clean Energy Business Plan Competition Stanford Nitrogen Group Stanford University The Stanford Nitrogen Group developed a new wastewater treatment process for the removal and recovery of energy from waste nitrogen (i.e. ammonia). This process improves the efficiency and lowers the cost of nitrogen treatment. The process is termed the Coupled Aerobic-anoxic Nitrous Decomposition Operation (CANDO) and consists of 2 principal steps: biological conversion of ammonia to N2O gas, and combustion of a fuel (i.e. biogas) with N2O to recover energy. It's the first wastewater treatment process to recover energy from nitrogen. Wastewater treatment facilities experience dual financial pressures - rising energy costs and meeting increasingly stringent nitrogen discharge

339

Stanford Nitrogen Group | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Stanford Nitrogen Group Stanford Nitrogen Group National Clean Energy Business Plan Competition Stanford Nitrogen Group Stanford University The Stanford Nitrogen Group developed a new wastewater treatment process for the removal and recovery of energy from waste nitrogen (i.e. ammonia). This process improves the efficiency and lowers the cost of nitrogen treatment. The process is termed the Coupled Aerobic-anoxic Nitrous Decomposition Operation (CANDO) and consists of 2 principal steps: biological conversion of ammonia to N2O gas, and combustion of a fuel (i.e. biogas) with N2O to recover energy. It's the first wastewater treatment process to recover energy from nitrogen. Wastewater treatment facilities experience dual financial pressures - rising energy costs and meeting increasingly stringent nitrogen discharge

340

IN THIS ISSUE Nitrogen on Cotton . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2  

E-Print Network (OSTI)

AGRONOMY NOTES July 2005 IN THIS ISSUE COTTON Nitrogen on Cotton . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2 Protecting Cotton Squares and Blooms / University of Florida / Larry Arrington, Interim Dean. #12;2 Nitrogen on Cotton Now is the time to apply N

Watson, Craig A.

Note: This page contains sample records for the topic "nitrogen oxides particulate" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Identifying the Active Site in Nitrogen-Doped Graphene for the VO2+/VO2+ Redox Reaction  

Science Journals Connector (OSTI)

Nitrogen-doped graphene sheets (NGS), synthesized by annealing graphite oxide (GO) with urea at 700–1050 °C, were studied as positive electrodes in a vanadium redox flow battery. ... graphene sheets; nitrogen doping; [VO]2+/[VO2]+ couple reaction; redox flow battery ... (7) Among these energy storage technologies, the vanadium redox flow battery (VRFB) has been considered as a competitive and promising grid energy storage system for renewable energy due to its low cost, high efficiency, and good cycling stability. ...

Jutao Jin; Xiaogang Fu; Qiao Liu; Yanru Liu; Zhiyang Wei; Kexing Niu; Junyan Zhang

2013-05-06T23:59:59.000Z

342

Impacts of Atmospheric Anthropogenic Nitrogen on the  

E-Print Network (OSTI)

anthropogenic carbon dioxide may result from this atmospheric nitrogen fertilization, leading to a decreaseImpacts of Atmospheric Anthropogenic Nitrogen on the Open Ocean R. A. Duce,1 * J. LaRoche,2 K quantities of atmospheric anthropogenic fixed nitrogen entering the open ocean could account for up to about

Ward, Bess

343

Frostbite Theater - Liquid Nitrogen Experiments - Liquid Nitrogen Show!  

NLE Websites -- All DOE Office Websites (Extended Search)

Insulators! Insulators! Previous Video (Insulators!) Frostbite Theater Main Index Next Video (Superconductors!) Superconductors! Liquid Nitrogen Show! All of your favorite liquid nitrogen experiments all in one place! Flowers! Balloons! Racquetballs! Nothing is safe! Just sit back, relax, and enjoy the show! [ Show Transcript ] Announcer: Frostbite Theater presents... Cold Cuts! No baloney! Joanna and Steve: Just science! Joanna: Hi! I'm Joanna! Steve: And I'm Steve! Joanna: Usually, every couple years, Jefferson Lab hosts an Open House. This is the one time the public and come and tour our accelerator and end stations. Steve: During the 2010 Open House, our cameraman snuck into one of the ongoing cryo shows that are held throughout the day. He missed half of it. So if you want to see the entire thing, check our website to see when the

344

On-Board Engine Exhaust Particulate Matter Sensor for HCCI and...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Demonstration of an Electronic Particulate Matter Sensor for Both Engine-Out and Post-DPF Exhaust Monitoring Particle Sensor for Diesel Combustion Monitoring NOx sensor development...

345

On-Board Engine Exhaust Particulate Matter Sensor for HCCI and...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Matter Sensor for Both Engine-Out and Post-DPF Exhaust Monitoring On-Board Engine Exhaust Particulate Matter Sensor for HCCI and Conventional Diesel Engines Vehicle...

346

Using rare earth elements to constrain particulate organic carbon flux in marginal seas.  

E-Print Network (OSTI)

??Fluxes of particulate organic carbon (POC) in the East China Sea (ECS) have been reported to decrease from the inner continental shelf towards the outer… (more)

Chen, Ya-Feng

2014-01-01T23:59:59.000Z

347

E-Print Network 3.0 - airborne particulates european Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

de mathmatiques Collection: Mathematics 12 Statistical Issues in the Study of Air Pollution Involving Airborne Particulate Matter Summary: Statistical Issues in the Study of...

348

Real-Time Particulate Mass Measurements Pre and Post Diesel Particulat...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

2005deeranderson.pdf More Documents & Publications Advanced Radio Frequency-Based Sensors for Monitoring Diesel Particulate Filter Loading and Regeneration Real-Time...

349

Vehicle Technologies Office Merit Review 2014: Particulate Emissions Control by Advanced Filtration Systems for GDI Engines  

Energy.gov (U.S. Department of Energy (DOE))

Presentation given by Argonne National Laboratory at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about particulate...

350

E-Print Network 3.0 - airborne particulates impact Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

public health threat of air pollution Summary: . Currently there are six "criteria pollutants" for air pollution: PM10 (defined as particulate matter... a more specific human...

351

E-Print Network 3.0 - airborne fine particulate Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

particulate matter otherwise known as aerosols. However health risks from these pollutants... Airborne Pollution In urban environments What are the real health effects of...

352

Development of particulate-based EPR oximetry for regional, temporal, and rapid measurements in tissue.  

E-Print Network (OSTI)

??Electron paramagnetic resonance (EPR) oximetry is a useful research technique and a potential clinical tool. The goal of this dissertation was to establish particulate-based EPR… (more)

Vikram, Deepti S.

2008-01-01T23:59:59.000Z

353

E-Print Network 3.0 - atmospheric fine particulate Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

and characterizing the diversity of particulate matter produced from fossil fuel and biomass burn combustion... studies on the mixing state of atmospheric particles and their...

354

E-Print Network 3.0 - air pollution particulate Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

Search Powered by Explorit Topic List Advanced Search Sample search results for: air pollution particulate Page: << < 1 2 3 4 5 > >> 1 COLUMBIA UNIVERSITY Department of...

355

E-Print Network 3.0 - air particulate matter Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

Collection: Engineering ; Renewable Energy 3 Statistical Issues in the Study of Air Pollution Involving Airborne Particulate Matter Summary: Statistical Issues in the...

356

E-Print Network 3.0 - assisted particulate filter Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

University of Nebraska-Lincoln Collection: Engineering 3 Prevention of Air Pollution from Ships: Diesel Engine Particulate Emission Reduction via Lube-Oil-Consumption...

357

Particulate matter and atherosclerosis: role of particle size, composition and oxidative stress  

E-Print Network (OSTI)

the APHEA2 (Air Pollution and Health: A European Approach)Series Studies of Air Pollution and Health. Boston, MA:association of air pollution with adverse health effects [1-

Araujo, Jesus A; Nel, Andre E

2009-01-01T23:59:59.000Z

358

Gas-Phase OH Oxidation of Monoterpenes: Gaseous and Particulate Products  

Science Journals Connector (OSTI)

Smog chamber experiments have beenconducted in which cyclic monoterpenes were oxidisedin the gas phase by OH. The evolved secondary organicaerosol (SOA) was analysed by LC-MSn and thegas-phase products were analy...

Bo. R. Larsen; Dario Di Bella; Marianne Glasius…

2001-03-01T23:59:59.000Z

359

Exploring relationships between outdoor air particulate-associated  

NLE Websites -- All DOE Office Websites (Extended Search)

Exploring relationships between outdoor air particulate-associated Exploring relationships between outdoor air particulate-associated polycyclic aromatic hydrocarbon and PM2.5: A case study of benzo(a)pyrene in California metropolitan regions Title Exploring relationships between outdoor air particulate-associated polycyclic aromatic hydrocarbon and PM2.5: A case study of benzo(a)pyrene in California metropolitan regions Publication Type Journal Article LBNL Report Number LBNL-514E Year of Publication 2008 Authors Lobscheid, Agnes B., Thomas E. McKone, and D. A. Valleroc Journal Atmospheric Environment Volume 41 Start Page Chapter Pagination 5659-5672 Abstract Polycyclic aromatic hydrocarbons (PAHs) and particulate matter (PM) are co-pollutants emitted as by-products of combustion processes. Convincing evidence exists for PAHs as a primary toxic component of fine PM (PM2.5). Because PM2.5 is listed by the US EPA as a "Criteria Pollutant," it is monitored regularly at sites nationwide. In contrast, very limited data is available on measured ambient air concentrations of PAHs. However, between 1999-2001, ambient air concentrations of PM2.5 and benzo(a)pyrene (BaP) are available for California locations. We use multivariate linear regression models (MLRMs) to predict ambient air levels of BaP in four air basins based on reported PM2.5 concentrations and spatial, temporal and meteorological variables as variates. We obtain an R2 ranging from 0.57-0.72 among these basins. Significant variables (p<0.05) include the average daily PM2.5 concentration, wind speed, temperature and relative humidity, and the coastal distance as well as season, and holiday or weekend. Combining the data from all sites and using only these variables to estimate ambient BaP levels, we obtain an R2 of 0.55. These R2-values, combined with analysis of the residual error and cross validation using the PRESS-statistic, demonstrate the potential of our method to estimate reported outdoor air PAH exposure levels in metropolitan regions. These MLRMs provide a first step towards relating outdoor ambient PM2.5 and PAH concentrations for epidemiological studies when PAH measurements are unavailable, or limited in spatial coverage, based on publicly available meteorological and PM2.5 data

360

Electrically heated particulate filter with zoned exhaust flow control  

DOE Patents (OSTI)

A system includes a particulate matter (PM) filter that includes X zones. An electrical heater includes Y heater segments that are associated with respective ones of the X zones. The electrical heater is arranged upstream from and proximate with the PM filter. A valve assembly includes Z sections that are associated with respective ones of the X zones. A control module adjusts flow through each of the Z sections during regeneration of the PM filter via control of the valve assembly. X, Y and Z are integers.

Gonze, Eugene V [Pinckney, MI

2012-06-26T23:59:59.000Z

Note: This page contains sample records for the topic "nitrogen oxides particulate" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Apparatus for removal of particulate matter from gas streams  

DOE Patents (OSTI)

An apparatus for the removal of particulate matter from the gaseous product stream of an entrained flow coal gasifier which apparatus includes an initial screen, an intermediate screen which is aligned with the direction of flow of the gaseous product stream and a final screen transversely disposed to the flow of gaseous product and which apparatus is capable of withstanding at least a pressure differential of about 10 psi (68.95 kPa) or greater at the temperatures of the gaseous product stream.

Smith, Peyton L. (Baton Rouge, LA); Morse, John C. (Baton Rouge, LA)

2000-01-01T23:59:59.000Z

362

Prospecting by sampling and analysis of airborne particulates and gases  

DOE Patents (OSTI)

A method is claimed for prospecting by sampling airborne particulates or gases at a ground position and recording wind direction values at the time of sampling. The samples are subsequently analyzed to determine the concentrations of a desired material or the ratios of the desired material to other identifiable materials in the collected samples. By comparing the measured concentrations or ratios to expected background data in the vicinity sampled, one can select recorded wind directions indicative of the upwind position of the land-based source of the desired material.

Sehmel, G.A.

1984-05-01T23:59:59.000Z

363

Crystal Structure and Characterization of Particulate Methane Monooxygenase from Methylocystis species Strain M  

SciTech Connect

Particulate methane monooxygenase (pMMO) is an integral membrane metalloenzyme that oxidizes methane to methanol in methanotrophic bacteria. Previous biochemical and structural studies of pMMO have focused on preparations from Methylococcus capsulatus (Bath) and Methylosinus trichosporium OB3b. A pMMO from a third organism, Methylocystis species strain M, has been isolated and characterized. Both membrane-bound and solubilized Methylocystis sp. strain M pMMO contain {approx}2 copper ions per 100 kDa protomer and exhibit copper-dependent propylene epoxidation activity. Spectroscopic data indicate that Methylocystis sp. strain M pMMO contains a mixture of Cu{sup I} and Cu{sup II}, of which the latter exhibits two distinct type 2 Cu{sup II} electron paramagnetic resonance (EPR) signals. Extended X-ray absorption fine structure (EXAFS) data are best fit with a mixture of Cu-O/N and Cu-Cu ligand environments with a Cu-Cu interaction at 2.52-2.64 {angstrom}. The crystal structure of Methylocystis sp. strain M pMMO was determined to 2.68 {angstrom} resolution and is the best quality pMMO structure obtained to date. It provides a revised model for the pmoA and pmoC subunits and has led to an improved model of M. capsulatus (Bath) pMMO. In these new structures, the intramembrane zinc/copper binding site has a different coordination environment from that in previous models.

Smith, Stephen M.; Rawat, Swati; Telser, Joshua; Hoffman, Brian M.; Stemmler, Timothy L.; Rosenzweig, Amy C. (WSU-MED); (NWU)

2012-02-08T23:59:59.000Z

364

Particulate matter characteristics during agricultural waste burning in Taichung City, Taiwan  

Science Journals Connector (OSTI)

Agricultural waste burning is performed after harvest periods in June and November in Taiwan. Typically, farmers use open burning to dispose of excess rice straw. PM2.5 and PM2.5–10 measurements were conducted at National Chung Hsing University in Taichung City using a dichotomous sampler. The sampling times were during straw burning periods after rice harvest during 2002–2005. Ionic species including SO42?, NO3?, NH4+, K+, Ca2+, Cl? and Na+ and carbonaceous species (EC and OC) in PM2.5 and PM2.5–10 were analyzed. The results showed that the average PM2.5 and PM2.5–10 concentrations were 123.6 and 31.5 ?g m?3 during agricultural waste burning periods and 32.6 and 21.4 ?g m?3 during non-waste burning periods, respectively. The fine aerosol ionic species including Cl?, K+ and NO3? increased 11.0, 6.7 and 5.5 times during agricultural burning periods compared with periods when agricultural waste burning is not performed. K+ was found mainly in the fine mode during agricultural burning. High nitrogen oxidation ratio was found during agricultural waste burning periods which might be caused by the conversion of Nitrogen dioxide (NO2) to NO3?. It is concluded that agricultural waste burning with low dispersion often causes high PM2.5 and gases pollutant events.

Man-Ting Cheng; Chuen-Liang Horng; Yi-Ru Su; Li-Kai Lin; Yu-Chi Lin; Charles C.-K. Chou

2009-01-01T23:59:59.000Z

365

Toward Distinguishing Woodsmoke and Diesel Exhaust in Ambient Particulate Matter  

SciTech Connect

Particulate matter (PM) from biomass burning and diesel exhaust has distinct X-ray spectroscopic, carbon specific signatures, which can be employed for source apportionment. Characterization of the functional groups of a wide selection of PM samples (woodsmoke, diesel soot, urban air PM) was carried out using the soft X-ray spectroscopy capabilities at the synchrotron radiation sources in Berkeley (ALS) and Brookhaven (NSLS). The spectra reveal that diesel exhaust particulate (DEP) matter is made up from a semigraphitic solid core and soluble organic matter, predominantly with carboxylic functional groups. Woodsmoke PM has no or a less prevalent, graphitic signature, instead it contains carbon-hydroxyl groups. Using these features to apportion the carbonaceous PM in ambient samples we estimate that the relative contribution of DEP to ambient PM in an urban area such as Lexington, KY and St. Louis, MO is 7% and 13.5%, respectively. These values are comparable to dispersion modeling data from nonurban and urban areas in California, and with elemental carbon measurements in urban locations such as Boston, MA, Rochester, NY, and Washington, DC.

Braun,A.; Huggins, F.; Kubatova, A.; Wirick, S.; Maricq, M.; Mun, B.; McDonald, J.; Kelly, K.; Shah, N.; Huffman, G.

2008-01-01T23:59:59.000Z

366

Cooler and particulate separator for an off-gas stack  

DOE Patents (OSTI)

This report describes an off-gas stack for a melter, furnace or reaction vessel comprising an air conduit leading to two sets of holes, one set injecting air into the off-gas stack near the melter plenum and the second set injecting air downstream of the first set. The first set injects air at a compound angle, having both downward and tangential components, to create a reverse vortex flow, counter to the direction of flow of gas through the stack and also along the periphery of the stack interior surface. Air from the first set of holes prevents recirculation zones from forming and the attendant accumulation of particulate deposits on the wall of the stack and will also return to the plenum any particulate swept up in the gas entering the stack. The second set of holes injects air in the same direction as the gas in the stack to compensate for the pressure drop and to prevent the concentration of condensate in the stack. A set of sprayers, receiving water from a second conduit, is located downstream of the second set of holes and sprays water into the gas to further cool it.

Wright, G.T.

1991-04-08T23:59:59.000Z

367

Characterization and modification of particulate properties to enhance filtration performance  

SciTech Connect

The specific objectives of this project are to characterize the particulate properties that determine the filtration performance of fabric filters, and to investigate methods for modifying these particulate properties to enhance filtration performance. Inherent in these objectives is the development of an experimental approach that will lead to full-scale implementation of beneficial conditioning processes identified during the project. The general approach has included a large number of laboratory evaluations to be followed by optional field tests of a new successful conditioning processes performed on a sidestream device. This project was divided into five tasks. The schedule followed for these tasks is shown in Figure 4. Tasks 2 and 3 each focus on one of the two complementary parts of the project. Task 2 Parametric Tests of Ashes and Fabrics, evaluates the degree to which ash properties and fabric design determine filtration performance. Task 3 Survey of Methods to Modify the Particle Filtration Properties, provides a literature review and laboratory study of techniques to modify ash properties. The results of these two tasks were used in Task 4 Proof-of-Concept Tests of Methods to Modify Particle Filtration Properties to demonstrate the effects on filtration performance of modifying ash properties. The findings of all the tasks are summarized in this Final Report. 13 refs.

Snyder, T.R.; Vann Bush, P.; Robinson, M.S.

1990-06-01T23:59:59.000Z

368

Cooler and particulate separator for an off-gas stack  

DOE Patents (OSTI)

An off-gas stack for a melter comprising an air conduit leading to two sets of holes, one set injecting air into the off-gas stack near the melter plenum and the second set injecting air downstream of the first set. The first set injects air at a compound angle, having both downward and tangential components, to create a reverse vortex flow, counter to the direction of flow of gas through the stack and also along the periphery of the stack interior surface. Air from the first set of holes pervents recirculation zones from forming and the attendant accumulation of particulate deposits on the wall of the stack and will also return to the plenum any particulate swept up in the gas entering the stack. The second set of holes injects air in the same direction as the gas in the stack to compensate for the pressure drop and to prevent the concentration of condensate in the stack. A set of sprayers, receiving water from a second conduit, is located downstream of the second set of holes and sprays water into the gas to further cool it.

Wright, George T. (15 Cherry Hills Dr., Aiken, SC 29803)

1992-01-01T23:59:59.000Z

369

Enrichment and Association of Bacteria and Particulates in Salt Marsh Surface Water  

Science Journals Connector (OSTI)

...Bacteria and Particulates in Salt Marsh Surface Water R. W. Harvey L. Y. Young Environmental...Bacteria and Particulates in Salt Marsh Surface Water R. W. HARVEY AND L. Y. YOUNG...surface. (A) Sippewissett marsh, n = 23, r = 0.91. (B) Palo Alto marsh...

R. W. Harvey; L. Y. Young

1980-04-01T23:59:59.000Z

370

Seasonality and Interaction of Biogenic and Lithogenic Particulate Flux at the Panama Basin  

Science Journals Connector (OSTI)

...particulate flux at the Panama Basin Honjo Susumu Author Woods Hole...Particulate Flux at the Panama Basin Abstract. Time-series sediment...3860 meters) in the Panama Basin. The amount ofhorizontal and...to deep water in the Panama Bight. During January through March...

SUSUMU HONJO

1982-11-26T23:59:59.000Z

371

Probing into regional ozone and particulate matter pollution in the United States  

E-Print Network (OSTI)

) and fine particulate matter (PM2.5) air pollution and associated health effects have been one of the majorProbing into regional ozone and particulate matter pollution in the United States: 1. A 1 year CMAQ-term simulations using the Community Multiscale Air Quality (CMAQ) modeling system and subsequent process analyses

Jacobson, Mark

372

Developing an accelerated aging system for gasoline particulate filters and an evaluation test for effects on engine performance  

E-Print Network (OSTI)

Stringent regulations worldwide will limit the level of particulate matter (PM) emitted from gasoline engines equipped with direct fuel injection. Gasoline particulate filters (GPFs) present one strategy for meeting PM ...

Jorgensen, James E. (James Eastman)

2014-01-01T23:59:59.000Z

373

Stanford Nitrogen Group | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Science & Innovation » Innovation » Commercialization » National Science & Innovation » Innovation » Commercialization » National Clean Energy Business Plan Competition » Stanford Nitrogen Group National Clean Energy Business Plan Competition Stanford Nitrogen Group Stanford University The Stanford Nitrogen Group developed a new wastewater treatment process for the removal and recovery of energy from waste nitrogen (i.e. ammonia). This process improves the efficiency and lowers the cost of nitrogen treatment. The process is termed the Coupled Aerobic-anoxic Nitrous Decomposition Operation (CANDO) and consists of 2 principal steps: biological conversion of ammonia to N2O gas, and combustion of a fuel (i.e. biogas) with N2O to recover energy. It's the first wastewater treatment process to recover energy from nitrogen.

374

Nitrogen fixation method and apparatus  

DOE Patents (OSTI)

A method and apparatus for achieving nitrogen fixation includes a volumetric electric discharge chamber. The volumetric discharge chamber provides an even distribution of an electron beam, and enables the chamber to be maintained at a controlled energy to pressure (E/p) ratio. An E/p ratio of from 5 to 15 kV/atm of O[sub 2]/cm promotes the formation of vibrationally excited N[sub 2]. Atomic oxygen interacts with vibrationally excited N[sub 2] at a much quicker rate than unexcited N[sub 2], greatly improving the rate at which NO is formed. 1 fig.

Chen, H.L.

1983-08-16T23:59:59.000Z

375

Thermo-Oxidation of Tokamak Carbon Dust  

SciTech Connect

The oxidation of dust and flakes collected from the DIII-D tokamak, and various commercial dust specimens, has been measured at 350 şC and 2.0 kPa O2 pressure. Following an initial small mass loss, most of the commercial dust specimens showed very little effect due to O2 exposure. Similarly, dust collected from underneath DIII-D tiles, which is thought to comprise largely Grafoil™ particulates, also showed little susceptibility to oxidation at this temperature. However, oxidation of the dust collected from tile surfaces has led to ~ 18% mass loss after 8 hours; thereafter, little change in mass was observed. This suggests that the surface dust includes some components of different composition and/or structure – possibly fragments of codeposited layers. The oxidation of codeposit flakes scraped form DIII-D upper divertor tiles showed an initial 25% loss in mass due to heating in vacuum, and the gradual loss of 30-38% mass during the subsequent 24 hours exposure to O2. This behavior is significantly different from that observed for the oxidation of thinner DIII-D codeposit specimens which were still adhered to tile surfaces, and this is thought to be related to the low deuterium content (D/C ~ 0.03 – 0.04) of the flakes.

J.W. Davis; B.W.N. Fitzpatrick; J.P. Sharpe; A.A. Haasz

2008-04-01T23:59:59.000Z

376

Environmental biogeochemistry. V. 1: Carbon, nitrogen, phosphorus ...  

Science Journals Connector (OSTI)

V. 1: Carbon, nitrogen, phosphorus, sulfur and selenium cycles. V. 2: Metals transfer and ecological mass balances. Ann Arbor Sci. Publ., Inc., Ann. Arbor, Mich.

2000-01-06T23:59:59.000Z

377

Nitrogen Deposition in the Southern High Plains  

E-Print Network (OSTI)

Nitrogen Deposition in the Southern High Plains Nitrogen is necessary for life on earth, but getting too much of it can be harmful. Recent research in delicate alpine watersheds of the western United States has suggested that the amount... Nitrogen Deposition in the Southern High Plains Conservation of mass: It?s not just a good idea, it?s the law Nitrogen, along with every other element in nature, obeys certain physical laws. The first of those laws, the law of conservation of mass...

Upadhyay, Jeetendra; Auvermann, Brent W.; Bush, K. Jack; Mukhtar, Saqib

2008-02-11T23:59:59.000Z

378

An Optical Backscatter Sensor for Particulate Matter Measurement  

SciTech Connect

Diesel engines are prone to emit particulate matter (PM) emissions under certain operation conditions. In-cylinder production of PM from diesel combustion control can occur under a wide variety of operating conditions, and in some cases, operation of a multi-cylinder engine can further complicate PM emissions due to variations in air or fuel charge due to manifold mixing effects. In this study, a probe for detecting PM in diesel exhaust was evaluated on a light-duty diesel engine. The probe is based on an optical backscattering effect. Due to the optical nature of the probe, PM sensing can occur at high rates. The feasibility of the probe for examining PM emissions in the exhaust manifold will be discussed.

Parks, II, James E [ORNL; Prikhodko, Vitaly Y [ORNL; Partridge Jr, William P [ORNL

2009-01-01T23:59:59.000Z

379

Direct and quantitative photothermal absorption spectroscopy of individual particulates  

SciTech Connect

Photonic structures can exhibit significant absorption enhancement when an object's length scale is comparable to or smaller than the wavelength of light. This property has enabled photonic structures to be an integral component in many applications such as solar cells, light emitting diodes, and photothermal therapy. To characterize this enhancement at the single particulate level, conventional methods have consisted of indirect or qualitative approaches which are often limited to certain sample types. To overcome these limitations, we used a bilayer cantilever to directly and quantitatively measure the spectral absorption efficiency of a single silicon microwire in the visible wavelength range. We demonstrate an absorption enhancement on a per unit volume basis compared to a thin film, which shows good agreement with Mie theory calculations. This approach offers a quantitative approach for broadband absorption measurements on a wide range of photonic structures of different geometric and material compositions.

Tong, Jonathan K.; Hsu, Wei-Chun; Eon Han, Sang; Burg, Brian R.; Chen, Gang, E-mail: gchen2@mit.edu [Department of Mechanical Engineering, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139 (United States)] [Department of Mechanical Engineering, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139 (United States); Zheng, Ruiting [Key Laboratory of Radiation Beam Technology and Materials Modification of Ministry of Education, College of Nuclear Science and Technology, Beijing Normal University, Beijing 100875 (China)] [Key Laboratory of Radiation Beam Technology and Materials Modification of Ministry of Education, College of Nuclear Science and Technology, Beijing Normal University, Beijing 100875 (China); Shen, Sheng [Department of Mechanical Engineering, Carnegie Mellon University, Pittsburgh, Pennsylvania 15213 (United States)] [Department of Mechanical Engineering, Carnegie Mellon University, Pittsburgh, Pennsylvania 15213 (United States)

2013-12-23T23:59:59.000Z

380

Mechanisms governing fine particulate emissions from coal flames  

SciTech Connect

The primary objective of this program was to provide a basic understanding of the principal processes that govern the formation of particulate matter in the 0.5--10 {mu}m size range in pulverized coal flames. The mechanism that produces ash particles in this size range is not clear. Particle sizes smaller than the 0.5--10 {mu}m size range are generally accepted to result from a vaporization/condensation mechanism while particles larger than this size result from the coalescence of ash in coal particles which may breakup as they burn. This program combined experimental and theoretical studies to understand the mechanisms which control the production of ash in the 0.5--10 {mu}m size range. (VC)

Newton, G.H.; Schieber, C.; Socha, R.G.; Kramlich, J.C.

1990-04-01T23:59:59.000Z

Note: This page contains sample records for the topic "nitrogen oxides particulate" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Mechanisms governing fine particulate emissions from coal flames. Final report  

SciTech Connect

The primary objective of this program was to provide a basic understanding of the principal processes that govern the formation of particulate matter in the 0.5--10 {mu}m size range in pulverized coal flames. The mechanism that produces ash particles in this size range is not clear. Particle sizes smaller than the 0.5--10 {mu}m size range are generally accepted to result from a vaporization/condensation mechanism while particles larger than this size result from the coalescence of ash in coal particles which may breakup as they burn. This program combined experimental and theoretical studies to understand the mechanisms which control the production of ash in the 0.5--10 {mu}m size range. (VC)

Newton, G.H.; Schieber, C.; Socha, R.G.; Kramlich, J.C.

1990-04-01T23:59:59.000Z

382

The Abundance of Interstellar Nitrogen  

E-Print Network (OSTI)

Using the HST Goddard High Resolution Spectrograph (GHRS), we have obtained high S/N echelle observations of the weak interstellar N I 1160, 1161 A absorption doublet toward the stars Gamma Cas, Lambda Ori, Iota Ori, Kappa Ori, Delta Sco, and Kappa Sco. In combination with a previous GHRS measurement of N I toward Zeta Oph, these new observations yield a mean interstellar gas phase nitrogen abundance (per 10$^6$ H atoms) of 10$^6$ N/H = 75 +/- 4. There are no statistically significant variations in the measured N abundances from sightline to sightline and no evidence of density-dependent depletion from the gas-phase. Since N is not expected to be depleted much into dust grains in these diffuse sightlines, its gas-phase abundance should reflect the total interstellar abundance. Consequently, the GHRS observations imply that the abundance of interstellar nitrogen (gas plus grains) in the local Milky Way is about 80% of the solar system value of 10$^6$ N/H = 93 +/- 16. Although this interstellar abundance deficit is somewhat less than that recently found for oxygen and krypton with GHRS, the solar N abundance and the N I oscillator strengths are too uncertain to definitively rule out either a solar ISM N abundance or a 2/3 solar ISM N abundance similar to that of O and Kr.

David M. Meyer; Jason A. Cardelli; Ulysses J. Sofia

1997-10-15T23:59:59.000Z

383

Mechanisms of plant species impacts on ecosystem nitrogen cycling  

E-Print Network (OSTI)

, this microbial nitrogen loop is driven by plant-supplied carbon and provides a strong negative feedback through by an increase in the relative nitrogen content in decomposing litter and a much lower carbon-to-nitrogen ratio by a microbial nitrogen loop. Nitrogen is released from the soil organic matter and incorporated into microbial

Minnesota, University of

384

Smoking Status and Occupational Exposure Affects Oxidative DNA Injury in Boilermakers Exposed to Metal Fume and Residual Oil Fly Ash  

Science Journals Connector (OSTI)

...sensitization by residual oil fly ash particles...composition of residual oil fly ash determines...coupled plasma sector field mass spectrometry...particulate-mediated cytokine production in lung epithelial...et al. Residual oil fly ash induces cytotoxicity...probably through cumulative oxidative DNA damage...

Sutapa Mukherjee; Lyle J. Palmer; Jee Young Kim; David B. Aeschliman; Robert S. Houk; Mark A. Woodin; and David C. Christiani

2004-03-01T23:59:59.000Z

385

Using carbon adsorbents for removing nitrogen oxides and sulphur oxides from flue gases  

Science Journals Connector (OSTI)

The use of carbon adsorbents in industrial power engineering outside Russia is briefly reviewed and the results of our own experimental investigations, made in the laboratory and at a pilot commercial installation, are given. The proposal to use the described device in a KE-25-24-C industrial boiler is outlined.

A.I. Blokhin; A.N. Nikitin; A.O. Gabibov

2003-01-01T23:59:59.000Z

386

Ab initio atomistic thermodynamics study of the early stages of Cu(100) oxidation  

E-Print Network (OSTI)

­3 catalytic conversion of nitrogen oxides,4 water-gas shift,5,6 and preventing CO poisoning in fuel cells.7 the nucleation limit of Cu2O, they are likely to exist due to kinetic hindrance. 1 #12;I. INTRODUCTION Oxidation

McGaughey, Alan

387

Nutrient Management Module No. 3 Nitrogen Cycling,  

E-Print Network (OSTI)

, it is important to first understand the various transformations that N undergoes within the soil. Nitrogen Cycling to be the sum of ammonium and nitrate, although urea, a type of organic N, may also be plant available. Nitrogen a fraction) by dry yield (in lb/ac). It's useful to compare actual uptake rates to N fertilizer rates

Lawrence, Rick L.

388

NITROGEN ISOTOPES IN PALEOCLIMATE JULIAN P. SACHS  

E-Print Network (OSTI)

denitrification, the conversion of nitrate to N2 gas with its subsequent loss to the atmosphere (25-180 Tg N of atmospheric carbon dioxide, and is the precursor to petroleum deposits it is important to understand nitrogen of nitrogen is atmospheric dinitrogen gas (N2), consisting of 3.9 x 109 Tg N (Wada and Hattori, 1990

Sachs, Julian P.

389

Oxygen and Nitrogen Contamination During Arc Welding  

E-Print Network (OSTI)

) ) : ,- Oxygen and Nitrogen Contamination During Arc Welding T. W. Eagar Department of }faterials, mechanisms, and expected levels of oxygen and nitrogen contamination during gas tungsten arc, gas metal arc indicating the importance of dec9mposition of SiOz into silicon monoxide and oxygen are presented, indicating

Eagar, Thomas W.

390

Nature of airborne particulates at tropic exposure sites. Final report, November 1982-September 1984  

SciTech Connect

Airborne particulates were collected at five exposure sites in Panama using cascade impactor air samplers. Scanning electron microscopy, energy dispersive x-ray analysis, and culture identification techniques were used to analyze the particulates. Analysis revealed that the particulates consist of silicates, chlorides, and sulfur-rich and phosphorus-rich particles. Atmospheric particle levels were higher in the dry season than in the rainy season, and the predominant fungal species varied at each exposure site. The open direct exposure of culture plates served as a simple, appropriate method for monitoring atmospheric fungal spores.

Chen, F.; Dement, W.A.

1984-09-01T23:59:59.000Z

391

Anaerobic Ammonium-Oxidizing Bacteria: Unique Microorganisms with Exceptional Properties  

Science Journals Connector (OSTI)

...membrane to the outer membrane to drive a number of outer membrane receptors...nitrate reduction to dinitrogen gas via nitrite and ammonium. Environ...ammonium-oxidizing bacteria. ASM News 67 :456-463. 49. Kuypers...associated with global nitrogen gas production. Environ. Microbiol...

Laura van Niftrik; Mike S. M. Jetten

2012-09-01T23:59:59.000Z

392

Frostbite Theater - Liquid Nitrogen Experiments - Insulators!  

NLE Websites -- All DOE Office Websites (Extended Search)

Popping Film Canisters! Popping Film Canisters! Previous Video (Popping Film Canisters!) Frostbite Theater Main Index Next Video (Liquid Nitrogen Show!) Liquid Nitrogen Show! Insulators! Cups full of water are placed into bowls of liquid nitrogen! Which cup will insulate the best? [ Show Transcript ] Announcer: Frostbite Theater presents... Cold Cuts! No baloney! Joanna and Steve: Just science! Joanna: Hi! I'm Joanna! Steve: And I'm Steve! Joanna: And this is a container of liquid nitrogen! Steve: And these are two plastic cups! Joanna: Let's see which cup is the better insulator! Steve: Okay! So, um, how do we do that? Joanna: Well, we'll pour water into each of the cups and then we'll pour the liquid nitrogen into each of the bowls. If we then place the cup in the bowl, the heat from the water will try to pass through the cup into the

393

Frostbite Theater - Liquid Nitrogen Experiments - Freezing Balloons!  

NLE Websites -- All DOE Office Websites (Extended Search)

Season Two Bloopers Season Two Bloopers Previous Video (Season Two Bloopers) Frostbite Theater Main Index Next Video (Instant Liquid Nitrogen Balloon Party!) Instant Liquid Nitrogen Balloon Party! Freezing Balloons! What happens when a balloon full of air is plunged into a container full of liquid nitrogen? Play the video to find out! [ Show Transcript ] Announcer: Frostbite Theater presents... Cold Cuts! No baloney! Joanna and Steve: Just science! Joanna: Hi! I'm Joanna! Steve: And I'm Steve! Joanna: And this is a container of liquid nitrogen! Steve: And this is a really big balloon! Joanna: Let's see what happens when we place the balloon in the liquid nitrogen! Steve: Okay! Wait! Wait! Wait! Wait! Wait! Isn't the balloon going to pop? Joanna: We'll see! Steve: Aw, man... Huh. Okay, so the balloon didn't pop. But, there's

394

Size-Resolved Density Measurements of Particulate Emissions from an Advanced Combustion Diesel Engine: Effect of Aggregate Morphology  

SciTech Connect

We report the first in situ size-resolved density measurements of particles produced by premixed charge compression ignition (PCCI) and compare these with conventional diesel particles. The densities of size-classified particles were determined by measurements with a differential mobility analyzer (DMA) and an aerosol particle mass analyzer (APM). Particle masses of the different size classes were evaluated with a proposed DMA-APM response function for aggregates. Our results indicate that the effective densities of PCCI and conventional diesel particles were approximately the same for 50 and 100 nm electrical mobility diameters (0.9 and 0.6 g/cc, respectively), but the PCCI particle effective density (0.4 g/cc) was less than the conventional (0.5 g/cc) for 150 nm. The lowest effective particle densities were observed for exhaust gas recirculation (EGR) levels somewhat less than that required for PCCI operation. The inherent densities of conventional particles in the 50 and 100 nm size classes were 1.22 and 1.77 g/cc, which is in good agreement with Park et al. (2004). PCCI inherent particle densities for these same size classes were higher (1.27 and 2.10 g/cc), suggesting that there may have been additional adsorbed liquid hydrocarbons. For 150 nm particles, the inherent densities were nearly the same for PCCI and conventional particles at 2.20 g/cc. We expect that the lower effective density of PCCI particles may improve particulate emissions control with diesel particulate filters (DPFs). The presence of liquid hydrocarbons may also promote oxidation in DPFs.

Barone, Teresa L [ORNL; Storey, John Morse [ORNL; Prikhodko, Vitaly Y [ORNL; Parks, II, James E [ORNL

2011-01-01T23:59:59.000Z

395

The Southeastern Aerosol Research and Characterization Study, Part 3: Continuous measurements of fine particulate matter mass and composition  

SciTech Connect

Deployment of continuous analyzers in the Southeastern Aerosol Research and Characterization Study (SEARCH) network began in 1998 and continues today as new technologies are developed. Measurement of fine particulate matter (PM2.5) mass is performed using a dried, 30 {sup o}C tapered element oscillating microbalance (TEOM). TEOM measurements are complemented by observations of light scattering by nephelometry. Measurements of major constituents include: (1) SO{sub 4}{sup 2-} via reduction to SO{sub 2}; (2) NH{sub 4}{sup +} and NO{sub 3}{sup -} via respective catalytic oxidation and reduction to NO, (3) black carbon (BC) by optical absorption,(4) total carbon by combustion to CO{sup 2}, and (5) organic carbon by difference between the latter two measurements. Several illustrative examples of continuous data from the SEARCH network are presented. A distinctive composite annual average diurnal pattern is observed for PM2.5 mass, nitrate, and BC, likely indicating the influence of traffic-related emissions, growth, and break up of the boundary layer and formation of ammonium nitrate. Examination of PM2.5 components indicates the need to better understand the continuous composition of the unmeasured 'other' category, because it contributes a significant fraction to total mass during periods of high PM2.5 loading. Selected episodes are presented to illustrate applications of SEARCH data. An SO{sub 2} conversion rate of 0.2%/hr is derived from an observation of a plume from a coal-fired power plant during early spring, and the importance of local, rural sources of NH{sub 3} to the formation of ammonium nitrate in particulate matter (PM) is demonstrated. 41 refs., 15 figs., 3 tabs.

Edgerton, E.S.; Hartsell, B.E.; Saylor, R.D.; Jansen, J.J.; Hansen, D.A.; Hidy, G.M. [Atmospheric Research & Analysis, Inc., Cary, NC (United States)

2006-09-15T23:59:59.000Z

396

INSENSITIVE HIGH-NITROGEN COMPOUNDS  

SciTech Connect

The conventional approach to developing energetic molecules is to chemically place one or more nitro groups onto a carbon skeleton, which is why the term ''nitration'' is synonymous to explosives preparation. The nitro group carries the oxygen that reacts with the skeletal carbon and hydrogen fuels, which in turn produces the heat and gaseous reaction products necessary for driving an explosive shock. These nitro-containing energetic molecules typically have heats of formation near zero and therefore most of the released energy is derived from the combustion process. Our investigation of the tetrazine, furazan and tetrazole ring systems has offered a different approach to explosives development, where a significant amount of the chemical potential energy is derived from their large positive heats of formation. Because these compounds often contain a large percentage of nitrogen atoms, they are usually regarded as high-nitrogen fuels or explosives. A general artifact of these high-nitrogen compounds is that they are less sensitive to initiation (e.g. by impact) when compared to traditional nitro-containing explosives of similar performances. Using the precursor, 3,6-bis-(3,5-dimethylpyrazol-1-yl)-s-tetrazine, several useful energetic compounds based on the s-tetrazine system have been synthesized and studied. Some of the first compounds are 3,6-diamino-s-tetrazine-1,4-dioxide (LAX-112) and 3,6-dihydrazino-s-tetrazine (DHT). LAX-112 was once extensively studied as an insensitive explosive by Los Alamos; DHT is an example of a high-nitrogen explosive that relies entirely on its heat of formation for sustaining a detonation. Recent synthesis efforts have yielded an azo-s-tetrazine, 3,3'-azobis(6-amino-s-tetrazine) or DAAT, which has a very high positive heat of formation. The compounds, 4,4'-diamino-3,3'-azoxyfurazan (DAAF) and 4,4'-diamino-3,3'-azofurazan (DAAzF), may have important future roles in insensitive explosive applications. Neither DAAF nor DAAzF can be initiated by laboratory impact drop tests, yet both have in some aspects better explosive performances than 1,3,5-triamino-2,4,6-trinitrobenzene TATB--the standard of insensitive high explosives. The thermal stability of DAAzF is equal to that of hexanitrostilbene (HNS), yet it too is a better explosive performer. The recently discovered tetrazol derivative, 3,6-bis-(1H-1,2,3,4-tetrazol-5-ylamino)-s-tetrazine (BTATz) was measured to have exceptional positive heats of formation and to be insensitive to explosive initiation. Because of its high burn rate with low sensitivity to pressure, this material is of great interest to the propellant community.

D. CHAVEZ; ET AL

2001-03-01T23:59:59.000Z

397

Atmos. Chem. Phys., 11, 88098823, 2011 www.atmos-chem-phys.net/11/8809/2011/  

E-Print Network (OSTI)

of the particulate matter were carbonaceous materials, such as humic acid, water sol- uble organics, and less soluble in public concern regarding the emission of atmospheric pollutants, including gas phase and particulate from livestock include methane (CH4), ammonia (NH3), nitrogen oxides (NOx), and nitrous oxide (N2O

Meskhidze, Nicholas

398

Nitrogen Fixation and Dentrification in Sediments of Eutrophic Mediterranean-Type Estuaries: Seasonal Patterns and Responses to Anthropogenic Nitrogen Inputs  

E-Print Network (OSTI)

and mechanisms controlling sediment nitrogen fixation in aKane T & Fong P. 2007. Sediment nitrogen fixation in UpperKane T & Fong P. 2007. Sediment nitrogen fixation in Upper

Kane, Tonya Lynn

2012-01-01T23:59:59.000Z

399

Nitrogen-doped Graphene and Its Electrochemical Applications...  

NLE Websites -- All DOE Office Websites (Extended Search)

doped Graphene and Its Electrochemical Applications. Nitrogen-doped Graphene and Its Electrochemical Applications. Abstract: Nitrogen-doped graphene (N-graphene) is obtained by...

400

Nitrogen Control in Electric Arc Furnace Steelmaking by Direct...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Nitrogen Control in Electric Arc Furnace Steelmaking by Direct Reduced Iron Fines Injection Nitrogen Control in Electric Arc Furnace Steelmaking by Direct Reduced Iron Fines...

Note: This page contains sample records for the topic "nitrogen oxides particulate" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

A science based emission factor for particulate matter emitted from cotton harvesting  

E-Print Network (OSTI)

practice plans detailing the actions taken by the producer to reduce fugitive PM emissions from field operations. The objective of this work was to develop accurate PM emission factors for cotton harvesting in terms of total suspended particulate (TSP), PM...

Wanjura, John David

2009-05-15T23:59:59.000Z

402

Air Pollution Control Regulations: No. 3- Particulate Emissions from Industrial Processes (Rhode Island)  

Energy.gov (U.S. Department of Energy (DOE))

These regulations limit particulate emissions into the atmosphere by process weight per hour, where process weight is the total weight of all materials introduced into any specific process which...

403

E-Print Network 3.0 - airborne fungi particulate Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

<< < 1 2 3 4 5 > >> 1 Correlating Bioaerosol Load with PM2.5 and PM10 Concentrations Jordan Peccia1, Ann M. Dillner1,2, Justin Boreson1 Summary: of airborne particulate matter....

404

E-Print Network 3.0 - airborne particulates Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

<< < 1 2 3 4 5 > >> 1 Correlating Bioaerosol Load with PM2.5 and PM10 Concentrations Jordan Peccia1, Ann M. Dillner1,2, Justin Boreson1 Summary: of airborne particulate matter....

405

E-Print Network 3.0 - airborne particulate matter Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

<< < 1 2 3 4 5 > >> 1 Correlating Bioaerosol Load with PM2.5 and PM10 Concentrations Jordan Peccia1, Ann M. Dillner1,2, Justin Boreson1 Summary: of airborne particulate matter....

406

Errors associated with particulate matter measurements on rural sources: appropriate basis for regulating cotton gins  

E-Print Network (OSTI)

Agricultural operations across the United States are encountering difficulties complying with current air pollution regulations for particulate matter (PM). PM is currently regulated in terms of particle diameters less than or equal to a nominal 10...

Buser, Michael Dean

2004-09-30T23:59:59.000Z

407

Engine-External HC-Dosing for Regeneration of Diesel Particulate...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

for Heavy Duty and NRMM According to Annex XXVII StVZO This presentation discusses how a diesel particulate filter can be integrated in the exhaust piping of a heavy-duty engine....

408

fundamental Modeling and Experimental Studies of Acicular Mullite Diesel Particulate Filters  

Energy.gov (U.S. Department of Energy (DOE))

Pore-scale simulations of filtration and regeneration in acicular muillite diesel particulate filters have suggested underlying mechanisms that contribute to lower back pressures compared to other common DPF substrates.

409

Currents and suspended particulate matter in tidal channels of the Sylt-Rřmř basin  

Science Journals Connector (OSTI)

Measurements of fluxes of water and suspended particulate matter (SPM) through the inlet and the three major channels of the Sylt-Rřmř bight covering several tidal periods in August 1992 ... budgets a relationshi...

Jens Kappenberg; Hans-Ulrich Fanger; Agmar Müller

410

Determination of particulate lead using aerosol mass spectrometry: MILAGRO/MCMA-2006 observations  

E-Print Network (OSTI)

We report the first measurements of particulate lead (Pb) from Aerodyne Aerosol Mass Spectrometers, which were deployed in and around Mexico City during the Megacity Initiative: Local and Global Research Observations ...

Salcedo, D.

411

Impact of Biomass Combustion on Urban Fine Particulate Matter in Central and Northern Europe  

Science Journals Connector (OSTI)

The impact of biomass combustion on atmospheric particulate matter was investigated at...2.5...) and size-segregated samples were collected with a virtual impactor and a ten-stage Berner low-pressure impactor, re...

Sanna K. Saarikoski; Markus K. Sillanpää…

2008-06-01T23:59:59.000Z

412

Source Apportionment of Heavy Metals in Air Particulate Matter Using Automated Electron Probe Micro Analysis  

Science Journals Connector (OSTI)

Source apportionment of air particulate matter, using receptor ... not well adapted for situations with a complex source composition because of the inherent inability to resolve chemically equivalent sources. Alt...

W. Van Borm; F. Adams

1988-01-01T23:59:59.000Z

413

Occurrence of Aliphatic Hydrocarbons in Water, Suspended Particulate Matter and Sediments of Daliao River System, China  

Science Journals Connector (OSTI)

In August of 2005 a study was carried out to evaluate contamination of aliphatic hydrocarbons(AHc) in water, suspended particulate matter (SPM) and sediments...?1 in surface water, from 22.68 to 5,725.36...?1 in ...

W. Guo; M. C. He; Z. F. Yang; C. Y. Lin…

2010-05-01T23:59:59.000Z

414

Optical backscatter probe for sensing particulate in a combustion gas stream  

DOE Patents (OSTI)

A system for sensing particulate in a combustion gas stream is disclosed. The system transmits light into a combustion gas stream, and thereafter detects a portion of the transmitted light as scattered light in an amount corresponding to the amount of particulates in the emissions. Purge gas may be supplied adjacent the light supply and the detector to reduce particles in the emissions from coating or otherwise compromising the transmission of light into the emissions and recovery of scattered light from the emissions.

Parks, James E; Partridge, William P

2013-05-28T23:59:59.000Z

415

Oxidation of Propane by Doped Nickel Oxides  

Science Journals Connector (OSTI)

... present study, however, indicate that in the absence of excess oxygen, direct oxidation of propane by the oxide lattice can occur.

D. W. McKEE

1964-04-11T23:59:59.000Z

416

Dissociation and excitation coefficients of nitrogen molecules and nitrogen monoxide generation  

SciTech Connect

The excitation coefficient ?{sub N2} is calculated for the excited metastable level of N{sub 2}(A{sub 3}?{sub u}{sup +}) in nitrogen molecules. In addition, the dissociation coefficient of nitrogen molecules is investigated by making use of the Boltzmann distribution of the electrons in atmospheric plasmas. The excitation and electron-impact dissociation coefficients of nitrogen molecules are analytically expressed in terms of the electron temperature T{sub e} for evaluations of the reactive oxygen and nitrogen species in atmospheric plasmas. As an application example of these coefficients, the nitrogen monoxide generation through a microwave torch is carried out for a development of medical tool. The nitrogen monoxide concentration from a microwave plasma-torch can be easily controlled by the nitrogen flow rate, mole fraction of the oxygen gas, and the microwave power. A simple analytic expression of the nitrogen monoxide concentration is obtained in terms of the oxygen molecular density and gas flow rate. The experimental data agree remarkably well with the theoretical results from the analytical expression. A microwave nitrogen-torch can easily provide an appropriate nitrogen monoxide concentration for the wound healings.

Uhm, Han S.; Na, Young H.; Choi, Eun H.; Cho, Guangsup [Department of Electronic and Biological Physics, Kwangwoon University 447-1 Wolgye-Dong, Nowon-Gu, Seoul 137-701 (Korea, Republic of)] [Department of Electronic and Biological Physics, Kwangwoon University 447-1 Wolgye-Dong, Nowon-Gu, Seoul 137-701 (Korea, Republic of)

2013-08-15T23:59:59.000Z

417

Particulate matter and heart disease: Evidence from epidemiological studies  

SciTech Connect

The association between particulate matter and heart disease was noted in the mid-nineties of last century when the epidemiological evidence for an association between air pollution and hospital admissions due to cardiovascular disease accumulated and first hypotheses regarding the pathomechanism were formulated. Nowadays, epidemiological studies have demonstrated coherent associations between daily changes in concentrations of ambient particles and cardiovascular disease mortality, hospital admission, disease exacerbation in patients with cardiovascular disease and early physiological responses in healthy individuals consistent with a risk factor profile deterioration. In addition, evidence was found that annual average PM{sub 2.5} exposures are associated with increased risks for mortality caused by ischemic heart disease and dysrhythmia. Thereby, evidence is suggesting not only a short-term exacerbation of cardiovascular disease by ambient particle concentrations but also a potential role of particles in defining patients' vulnerability to acute coronary events. While this concept is consistent with the current understanding of the factors defining patients' vulnerability, the mechanisms and the time-scales on which the particle-induced vulnerability might operate are unknown.

Peters, Annette [GSF-National Research Center for Environment and Health, Institute of Epidemiology, Ingolstaedter Landstr. 1, 85764 Neuherberg (Germany)]. E-mail: peters@gsf.de

2005-09-01T23:59:59.000Z

418

Reference electrode for strong oxidizing acid solutions  

DOE Patents (OSTI)

A reference electrode for the measurement of the oxidation-reduction potentials of solutions is especially suitable for oxidizing solutions such as highly concentrated and fuming nitric acids, the solutions of nitrogen oxides, N.sub.2 O.sub.4 and N.sub.2 O.sub.5, in nitric acids. The reference electrode is fabricated of entirely inert materials, has a half cell of Pt/Ce(IV)/Ce(III)/70 wt. % HNO.sub.3, and includes a double-junction design with an intermediate solution of 70 wt. % HNO.sub.3. The liquid junctions are made from Corning No. 7930 glass for low resistance and negligible solution leakage.

Rigdon, Lester P. (Livermore, CA); Harrar, Jackson E. (Castro Valley, CA); Bullock, Sr., Jack C. (Pleasanton, CA); McGuire, Raymond R. (Brentwood, CA)

1990-01-01T23:59:59.000Z

419

Economic Removal of Nitrogen from LNG  

Science Journals Connector (OSTI)

In recent years, economic factors have made transportation of natural gas in the form of LNG increasingly attractive. Shipping costs and heating value ... control necessitate specifications limiting the nitrogen ...

J-P. G. Jacks; J. C. McMillan

1978-01-01T23:59:59.000Z

420

Nitrogen fixation by a methanogenic archaebacterium  

Science Journals Connector (OSTI)

... fixing microbial systems able to convert wastes which are low in combined nitrogen, including lignocellulose biomass substrates, industrial wastes and food process wastes such as ... substrates, industrial wastes and food process wastes such as whey, to CH4.

Patti A. Murray; Stephen H. Zinder

1984-11-15T23:59:59.000Z

Note: This page contains sample records for the topic "nitrogen oxides particulate" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Nitrogen Removal From Low Quality Natural Gas  

SciTech Connect

Natural gas provides more than one-fifth of all the primary energy used in the United States. It is especially important in the residential sector, where it supplies nearly half of all the energy consumed in U.S. homes. However, significant quantities of natural gas cannot be produced economically because its quality is too low to enter the pipeline transportation system without some type of processing, other than dehydration, to remove the undesired gas fraction. Such low-quality natural gas (LQNG) contains significant concentration or quantities of gas other than methane. These non- hydrocarbons are predominantly nitrogen, carbon dioxide, and hydrogen sulfide, but may also include other gaseous components. The nitrogen concentrations usually exceeds 4%. Nitrogen rejection is presently an expensive operation which can present uneconomic scenarios in the potential development of natural gas fields containing high nitrogen concentrations. The most reliable and widely used process for nitrogen rejection from natural gas consists of liquefying the feed stream using temperatures in the order of - 300{degrees}F and separating the nitrogen via fractionation. In order to reduce the gas temperature to this level, the gas is compressed, cooled by mullet-stream heat exchangers, and expanded to low pressure. Significant energy for compression and expensive materials of construction are required. Water and carbon dioxide concentrations must be reduced to levels required to prevent freezing. SRI`s proposed research involves screening new nitrogen selective absorbents and developing a more cost effective nitrogen removal process from natural gas using those compounds. The long-term objective of this project is to determine the technical and economical feasibility of a N{sub 2}2 removal concept based on complexation of molecular N{sub 2} with novel complexing agents. Successful development of a selective, reversible, and stable reagent with an appropriate combination of capacity and N{sub 2} absorption/desorption characteristics will allow selective separation of N{sub 2} from LQNG.

Alvarado, D.B.; Asaro, M.F.; Bomben, J.L.; Damle, A.S.; Bhown, A.S.

1997-10-01T23:59:59.000Z

422

Microfluidic Facility, Harvard Medical School LIQUID NITROGEN TANK HANDLING  

E-Print Network (OSTI)

Microfluidic Facility, Harvard Medical School LIQUID NITROGEN TANK HANDLING HMS microfluidics/microfabrication facility has one high pressure liquid nitrogen tank which supplies the nitrogen for some equipment normal operation. In case the liquid nitrogen tank is malfunctioning and requires to be shut down or replaced make

Paulsson, Johan

423

SHORT COMMUNICATION Nitrogen recovery from shrimp pond efuent  

E-Print Network (OSTI)

the water as ammonia (total ammonia nitrogen, TAN), through either direct excretion by animals or ammoni

Lorenzen, Kai

424

Reformulated diesel fuel  

DOE Patents (OSTI)

Reformulated diesel fuels for automotive diesel engines which meet the requirements of ASTM 975-02 and provide significantly reduced emissions of nitrogen oxides (NO.sub.x) and particulate matter (PM) relative to commercially available diesel fuels.

McAdams, Hiramie T [Carrollton, IL; Crawford, Robert W [Tucson, AZ; Hadder, Gerald R [Oak Ridge, TN; McNutt, Barry D [Arlington, VA

2006-03-28T23:59:59.000Z

425

Nitrogen is a natural and necessary part of every healthy ecosystem, but too much nitrogen in our rivers,  

E-Print Network (OSTI)

), sewage treatment plants, and animal ma- nure. Once in water, nitrogen can change in chemical form

Torgersen, Christian

426

Catalyst Additives to Enhance Mercury Oxidation and Capture  

SciTech Connect

Preliminary research has shown that SCR catalysts employed for nitrogen-oxide reduction can effectively oxidize mercury. Three different SCR catalysts are currently being studied in this project--honeycomb-type, plate-type, and a hybrid-type catalyst. The catalysts were manufactured and supplied by Cormetech Inc., Hitachi America Ltd., and Haldor-Topsoe Inc., respectively. Parametric testing was performed to investigate the contribution of flue-gas chemistry on mercury oxidation via SCR catalysts. Future work to characterize flue gas simulations typically derived from low and high sulfur bituminous coal are being performed in a stepwise manner, to avoid the constant interruptions in testing that occur when leaks in the system are generated during temperature transitions. Specifically, chlorine concentration vs. mercury oxidation correlations will be developed for each catalyst. The contributions of temperature are also being investigated. SO2 oxidation is also being investigated for each test condition.

Thomas K. Gale

2005-12-31T23:59:59.000Z

427

Effect of ammonia plasma treatment on graphene oxide LB monolayers  

SciTech Connect

Graphene oxide monolayer sheets were transferred on Si and SiO{sub 2}/Si substrates by Langmuir-Blodgett technique and were exposed to ammonia plasma at room temperature. The monolayer character of both graphene oxide and plasma treated graphene oxide sheets were ascertained by atomic force microscopy. X-ray photoelectron spectroscopy and Raman spectroscopy revealed that ammonia plasma treatment results in enhancement of graphitic carbon content along with the incorporation of nitrogen. The conductivity of graphene oxide monolayers, which was in the range of 10{sup -6}-10{sup -7} S/cm, increased to 10{sup -2}-10{sup -3} S/cm after the ammonia plasma treatment. These results indicate that the graphene oxide was simultaneously reduced and N-doped during ammonia plasma treatment, without affecting the morphological stability of sheets.

Singh, Gulbagh; Botcha, V. Divakar; Narayanam, Pavan K.; Sutar, D. S.; Talwar, S. S.; Major, S. S. [Department of Physics, Indian Institute of Technology Bombay, Mumbai - 400076 (India); Srinivasa, R. S. [Department of Metallurgical Engineering and Materials Science, Indian Institute of Technology Bombay, Mumbai - 400076 (India)

2013-02-05T23:59:59.000Z

428

Air Pollution Control Regulations: No. 13- Particulate Emissions from Fossil Fuel Fired Steam or Hot Water Generating Units (Rhode Island)  

Energy.gov (U.S. Department of Energy (DOE))

The purpose of this regulation is to limit emissions of particulate matter from fossil fuel fired and wood-fired steam or hot water generating units.

429

110K Bi-Sr-Ca-Cu-O superconductor oxide and method for making same  

DOE Patents (OSTI)

A superconductor is disclosed consisting of a sufficiently pure phase of the oxides of Bi, Sr, Ca, and Cu to exhibit a resistive zero near 110K resulting from the process of forming a mixture of Bi[sub 2]O[sub 3], SrCO[sub 3], CaCO[sub 3] and CuO into a particulate compact wherein the atom ratios are Bi[sub 2], Sr[sub 1.2-2.2], Ca[sub 1.8-2.4], Cu[sub 3]. Thereafter, heating the particulate compact rapidly in the presence of oxygen to an elevated temperature near the melting point of the oxides to form a sintered compact, and then maintaining the sintered compact at the elevated temperature for a prolonged period of time. The sintered compact is cooled and reground. Thereafter, the reground particulate material is compacted and heated in the presence of oxygen to an elevated temperature near the melting point of the oxide and maintained at the elevated temperature for a time sufficient to provide a sufficiently pure phase to exhibit a resistive zero near 110K. 7 figs.

Veal, B.W.; Downey, J.W.; Lam, D.J.; Paulikas, A.P.

1992-12-22T23:59:59.000Z

430

DEMONSTRATION OF A FULL-SCALE RETROFIT OF THE ADVANCED HYBRID PARTICULATE COLLECTOR TECHNOLOGY  

SciTech Connect

The Advanced Hybrid Particulate Collector (AHPC), developed in cooperation between W.L. Gore & Associates and the Energy & Environmental Research Center (EERC), is an innovative approach to removing particulates from power plant flue gas. The AHPC combines the elements of a traditional baghouse and electrostatic precipitator (ESP) into one device to achieve increased particulate collection efficiency. As part of the Power Plant Improvement Initiative (PPII), this project was demonstrated under joint sponsorship from the U.S. Department of Energy and Otter Tail Power Company. The EERC is the patent holder for the technology, and W.L. Gore & Associates was the exclusive licensee for this project. The project objective was to demonstrate the improved particulate collection efficiency obtained by a full-scale retrofit of the AHPC to an existing electrostatic precipitator. The full-scale retrofit was installed on an electric power plant burning Powder River Basin (PRB) coal, Otter Tail Power Company's Big Stone Plant, in Big Stone City, South Dakota. The $13.4 million project was installed in October 2002. Project related testing concluded in December 2005. The following Final Technical Report has been prepared for the project entitled ''Demonstration of a Full-Scale Retrofit of the Advanced Hybrid Particulate Collector Technology'' as described in DOE Award No. DE-FC26-02NT41420. The report presents the operation and performance results of the system.

Tom Hrdlicka; William Swanson

2005-12-01T23:59:59.000Z

431

Nitrogen Deposition in the Southern High Plains Nitrogen is necessary for life on earth, but  

E-Print Network (OSTI)

to the environment. Dinitrogen contains two nitrogen atoms held together by one of nature's strongest chemical bonds in the environment include ammonia (NH3) and its related compounds, amines (NH2), nitrite (NO2) and nitrate (NO3 responsible for producing 500 million tons of nitrogen fertilizer each year, combines dinitro- gen

Mukhtar, Saqib

432

Quantification and characterization of dissolved organic nitrogen in wastewater effluents by electrodialysis treatment followed by size-exclusion chromatography with nitrogen detection  

Science Journals Connector (OSTI)

Abstract Dissolved organic nitrogen (DON) can act as a precursor of nitrogenous disinfection byproducts during oxidative water treatment. Quantification and characterization of DON are still challenging for waters with high concentrations of dissolved inorganic nitrogen (DIN, including ammonia, nitrate and nitrite) relative to total dissolved nitrogen (TDN) due to the cumulative analytical errors of independently measured nitrogen species (i.e., DON = TDN ?  NO 2 ?  ?  NO 3 ?  ?  NH 4 + /NH3) and interference of DIN species to TDN quantification. In this study, a novel electrodialysis (ED)-based treatment for selective DIN removal was developed and optimized with respect to type of ion-exchange membrane, sample pH, and ED duration. The optimized ED method was then coupled with size-exclusion chromatography with organic carbon, UV, and nitrogen detection (SEC-OCD-ND) for advanced DON analysis in wastewater effluents. Among the tested ion-exchange membranes, the PC-AR anion- and CMT cation-exchange membranes showed the lowest DOC loss (1–7%) during ED treatment of a wastewater effluent at ambient pH (8.0). A good correlation was found between the decrease of the DIN/TDN ratio and conductivity. Therefore, conductivity has been adopted as a convenient way to determine the optimal duration of the ED treatment. In the pH range of 7.0–8.3, ED treatment of various wastewater effluents with the PC-AR/CMT membranes showed that the relative residual conductivity could be reduced to less than 0.50 (DIN removal >90%; DIN/TDN ratio ?0.60) with lower DOC losses (6%) than the previous dialysis and nanofiltration methods (DOC loss >10%). In addition, the ED method is shorter (0.5 h) than the previous methods (>1–24 h). The relative residual conductivity was further reduced to ?0.20 (DIN removal >95%; DIN/TDN ratio ?0.35) by increasing the ED duration to 0.7 h (DOC loss = 8%) for analysis by SEC-OCD-ND, which provided new information on distribution and ratio of organic carbon and nitrogen in different molecular weight fractions of effluent organic matter.

Kangmin Chon; Yunho Lee; Jacqueline Traber; Urs von Gunten

2013-01-01T23:59:59.000Z

433

Effect of Nitrogen Additives on Flame Retardant Action of Tributyl Phosphate: Phosphorus – Nitrogen Synergism  

SciTech Connect

The effect of nitrogen additives like urea, guanidine carbonate and melamine formaldehyde on the flame retardant efficacy of tributyl phosphate (TBP) has been investigated. From the LOI tests on treated cotton it is clear that the nitrogen additives have synergistic action. Estimation of activation energy of decomposition of treated cotton indicated that nitrogen additives enhance the thermal stability during the burning process. SEM pictures of chars formed after LOI test showed the formation of protective polymeric coating on the surface. The surface of chars formed were evaluated using FTIR-ATR and XPS analysis which showed that the coating was composed of Phosphorus-Nitrogen-Oxygen containing species. Formation of this coating during the burning process could lead to the synergistic interaction of phosphorus and nitrogen. Based on the experimental data we have further proposed several reaction mechanisms which could contribute to synergistic action and formation of protective coating on the surface of char.

Gaan, Sabyasachi; Sun, Gang; Hutches, Katherine; Engelhard, Mark H.

2008-01-01T23:59:59.000Z

434

Development of a Low-Cost Particulate Matter Monitor  

SciTech Connect

We describe a small, inexpensive portable monitor for airborne particulates, composed of the following elements: a. A simple size-selective inlet (vertical elutriator) that permits only particles below a pre-set diameter to pass and enter the measurement section; b. A measurement section in which passing particles are deposited thermophoretically on a micro-fabricated resonant piezoelectric mass sensor; c. An optical characterization module co-located with the mass sensor module that directs infrared and ultraviolet beams through the deposit. The emergent optical beams are detected by a photodiode. The optical absorption of the deposit can be measured in order to characterize the deposit, and determine how much is due to diesel exhaust and/or environmental tobacco smoke; and d. A small pump that moves air through the device, which may also be operated in a passive mode. The component modules were designed by the project team, and fabricated at UCB andLBNL. Testing and validation were performed in a room-sized environmental chamber at LBNL in to which was added either environmental tobacco smoke (ETS, produced by a cigarette smoking machine) or diesel exhaust (from a conventional diesel engine). Two pilot field tests in a dwelling compared the monitor with existing aerosol instruments during exposure to infiltrated ambient air to which cigarette smoke, diesel exhaust, wood smoke and cooking fumes were added. The limit of detection (LOD) derived from statistical analysis of field data is 18 mu g m-3, at the 99percent confidence level. The monitor weighs less than 120 g and has a volume of roughly 250 cm3. Power consumption is approximately 100 milliwatts. During this study, the optical component of the device was not fully implemented and has been left for future efforts. Suggested improvements in the current prototype include use of integrated thermal correction, reconfiguration of the resonator for increased particle collection area, increased thermophoretic collection efficiency using an increased temperature gradient, and shielding the resonator electronics from deposition of ultrafine particles.

White, Richard M.; Apte, Michael G.; Gundel, Lara A.; Black, Justin

2008-08-01T23:59:59.000Z

435

Frostbite Theater - Liquid Nitrogen Experiments - Dry Ice vs. Liquid  

NLE Websites -- All DOE Office Websites (Extended Search)

Egg + Liquid Nitrogen + Time-lapse! Egg + Liquid Nitrogen + Time-lapse! Previous Video (Egg + Liquid Nitrogen + Time-lapse!) Frostbite Theater Main Index Next Video (Liquid Nitrogen Cooled Dry Ice in Water!) Liquid Nitrogen Cooled Dry Ice in Water! Dry Ice vs. Liquid Nitrogen! Dry ice is cold. Liquid nitrogen is cold, too. What happens when the two are mixed together? [ Show Transcript ] Announcer: Frostbite Theater presents... Cold Cuts! No baloney! Joanna and Steve: Just science! Joanna: Hi! I'm Joanna! Steve: And I'm Steve! Joanna: Have you ever wondered what happens when you mix dry ice and liquid nitrogen? Steve: Well, we just happen to have a chunk of dry ice left over from when we filmed 'How to Make a Cloud Chamber,' and here at Jefferson Lab, liquid nitrogen flows like water, so we're going to find out!

436

The effect of porosity on the mechanical properties of cordierite diesel particulate filter substrates  

SciTech Connect

Diesel particulate filter (DPF) technology depends on porous ceramic structures that trap the particulate matter in the diesel engine exhaust gas stream. The design of DPFs requires balancing the functional requirement of soot filtration with the mechanical properties and both are influenced by the porosity of the substrate. In addition, increasing the porosity of the substrate can assist with the catalytic washcoating, engine back pressure and engine efficiency. The effect of porosity on the elastic and fracture mechanical properties of cordierite based ceramic particulate filters was examined and will be described. Elastic modulus of DPF substrates was determined using resonant ultrasound spectroscopy while fracture toughness was characterized using the double-torsion test method. The interrelationships among specimen thickness, wall orientation, porosity and mechanical properties of the filter substrates will be discussed. A materials selection procedure to obtain filters with high thermal shock resistance and optimal mechanical properties will be described.

Shyam, Amit [ORNL; Lara-Curzio, Edgar [ORNL; Watkins, Thomas R [ORNL

2009-01-01T23:59:59.000Z

437

Investigations of release phenomenon of volatile organic compounds and particulates from residual storage chip piles  

SciTech Connect

This paper outlines the method for estimating Particulate Matter and Volatile Organic Compounds (VOCs) emissions from wood handling and storage operations at a pulp mill. Fugitive particulate matter emissions from wood handling and storage operations are due to material load/dropout operations, wind erosion from storage piles and vehicular traffic on paved roads. The particulate matter emissions are a function of a number of variables like windspeed, surface moisture content, material silt content, and number of days of precipitation. Literature review attributes VOC emissions to biological, microbiological, chemical, and physical processes occurring in wood material storage pile. The VOC emissions are from the surface of these piles and the VOC released during retrieval of chips from the pile. VOC emissions are based on the chip throughput, number of turnovers, moisture content and surface area of the pile. The emission factors with the requisite calculation methodology to be utilized for quantifying VOC emissions from chip piles has been discussed in this paper.

Mohan, S.; Nagarkatti, M. [Trinity Consultants, Inc., Baton Rouge, LA (United States)

1996-12-31T23:59:59.000Z

438

A Neo-Rumsfeldian Framework for the Thermodynamics of Organic Particulate  

NLE Websites -- All DOE Office Websites (Extended Search)

A Neo-Rumsfeldian Framework for the Thermodynamics of Organic Particulate A Neo-Rumsfeldian Framework for the Thermodynamics of Organic Particulate Matter Formation in the Atmosphere: Successes and Challenges Speaker(s): James F. Pankow Date: March 6, 2008 - 12:00pm Location: 90-3122 James F. Pankow. The thermodynamic principles according to which organic particulate matter (OPM) forms in the atmosphere have become well identified because of research progress made since about the mid 1990s. These are, ahem, known knowns. However, many unknowns exist regarding the concentrations and chemical characteristics of the biogenic and anthropogenic compounds present in the atmosphere that are important in OPM formation. In this context, since we know what we need to know more about, these are, well, known unknowns. Other known important unknowns are

439

Availability of Nitrous Nitrogen to Plants.  

E-Print Network (OSTI)

V, .=DL ULL LI~C a~ailability 01 ILILKLL~: IIILIU~~I~ LU curn, l~aa, 8011 31LY3 1 27.3 .53 .I447 1 I 1 5: 1250 .I349 ic nitrogen ( 37.P' 1 -59 1 .2195 ru.. nv / 36.6 .57 1 .2086 I -2141 1 .O7b/ I 1. gm. nitrous nitrogen 30.2 1 .64 1 .I933 1... .12 -.01 ' .09 V1 -- I w 01 ---- I ------ el M - 1 --O6 X * ---- ------ U1 $ !z - --- i d $ --- - I -20 2 Y * F - I M 4 M .34 I --- .20 M .14 5 nitrogen --- --- -.02 .14 -.48 -.01 -12 .18 .OS...

Fraps, G. S. (George Stronach); Sterges, A. J.

1935-01-01T23:59:59.000Z

440

Asphalt Oxidation Kinetics and Pavement Oxidation Modeling  

E-Print Network (OSTI)

Most paved roads in the United States are surfaced with asphalt. These asphalt pavements suffer from fatigue cracking and thermal cracking, aggravated by the oxidation and hardening of asphalt. This negative impact of asphalt oxidation on pavement...

Jin, Xin

2012-07-16T23:59:59.000Z

Note: This page contains sample records for the topic "nitrogen oxides particulate" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Method for the Removal of Ultrafine Particulates from an Aqueous Suspension  

SciTech Connect

A method of separating ultra-fine particulate from an aqueous suspension such as a process stream or a waste stream. The method involves the addition of alkali silicate and an organic gelling agent to a volume of liquid, from the respective process or waste stream, to form a gel. The gel then undergoes syneresis to remove water and soluble salts from the gel-containing the particulate, thus, forming a silica monolith. The silica monolith is then sintered to form a hard, nonporous waste form.

Chaiko, David J.; Kopasz, John P.; Ellison, Adam J.G.

1999-03-05T23:59:59.000Z

442

Comparative Study on Physicochemical Properties and Combustion Behaviors of Diesel Particulates and Model Soot  

Science Journals Connector (OSTI)

In the IR spectra of real diesel particulates, the absorption peaks at around 2928 and 3048 cm?1 are corresponding to the C?H vibration of the aromatic cycle, the peak at around 764 cm?1 is due to the vibration of substituted aromatic carbon, and the absorption peaks at around 1600 and 1724 cm?1 are assigned to the ?C?O? vibration. ... In general, it can be concluded that Printex U is a suitable model soot for the study on the combustion performances of the soot fraction of diesel particulates. ...

Jian Liu; Zhen Zhao; Chunming Xu; Aijun Duan; Guiyuan Jiang

2010-01-14T23:59:59.000Z

443

E-Print Network 3.0 - additional nitrogen responses Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

tons of nitrogen fertilizer each year, combines dinitro- gen... National Park (Colorado, USA): a response to anthropogenic nitrogen deposition." Geobiology 1... Nitrogen...

444

The importance of cytosolic glutamine synthetase in nitrogen assimilation and recycling  

E-Print Network (OSTI)

nitrogen mobilization and recycling in trees. Photosynthesisloci mapping for nitrogen recycling in rice. Journal ofNitrogen Assimilation and Recycling Stéphanie M. Bernard 1

Bernard, S.M.

2009-01-01T23:59:59.000Z

445

E-Print Network 3.0 - aerobic nitrogen cycle Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

biological nitrogen fixation of gaseous nitrogen. The water cycle is important to ecosystem... and Nitrogen Cycles As ... Source: Barboza, Perry - Institute of Arctic Biology,...

446

Optimizing hydrocarbon recoveries in nitrogen rejection units  

SciTech Connect

In order to address conceptual questions such as process selection and natural gas liquids plant integration, an understanding of the effects of several additional factors on nitrogen rejection unit design is important. These factors, which may influence optimum hydrocarbon recovery, installed compression, etc., include current and forecast values for natural gas and utilities, project life, plant size, feed gas composition and product specifications, feed pressure, and process variations. Prices, project life, and plant size are analyzed in detail and presented in terms of methane recoveries as a function of nitrogen content in the feed for both double and single column processes. Trends are qualitatively discussed for the remaining factors. 13 references.

Chesney, J.D.; Davis, R.A.; Hilton, M.F.; Vines, H.L.

1983-01-01T23:59:59.000Z

447

Enzymatic solubilization of nitrogenous constituents of carrots  

E-Print Network (OSTI)

of enzyme concentration upon nitrogen so1ubi 1i zed in carrot tops ( 10g dry weight) . Conditions of assay: pH = 3. 5, i ncubati on time = 20 hr, incubation temperature = 45'C. 24 hydrolysis. These data confirm earlier reports that -. 01% is the pro... roots and tops, a concentration of 1. 0% A-12-C at pH 3. 5 provided the maximum increase in soluble ni trogenous consti tuents . For car~ot roots, a concentration of 1. 0/ ficin at pH 4, 5 provided the maximum increase in soluble nitrogen. With carrot...

Curry, James Cannon

1971-01-01T23:59:59.000Z

448

Study on the Respirable Particulate Matter Generated from the Petroleum Coke and Coal Mixed-Fired CFB Boiler  

Science Journals Connector (OSTI)

The dust generated from the fuel combustion is one of the important sources for air pollution. This paper has made a comprehensive research on the particulate matter generated from the petroleum coke and coal mixed-fired circulating fluidized bed (CFB) ... Keywords: petroleum coke, respirable particulate matter, air pollution, circulating fluidized bed boiler

Yan Ma; Hao Bai; Lihua Zhao; Yang Ma; Daqiang Cang

2010-12-01T23:59:59.000Z

449

Biexciton emission from single isoelectronic traps formed by nitrogen-nitrogen pairs in GaAs  

SciTech Connect

We have studied photoluminescence (PL) from individual isoelectronic traps formed by nitrogen-nitrogen (NN) pairs in GaAs. Sharp emission lines due to exciton and biexciton were observed from individual isoelectronic traps in nitrogen atomic-layer doped (ALD) GaAs. The binding energy of biexciton bound to individual isoelectronic traps was approximately 8 meV. Both the exciton and biexciton luminescence lines show completely random polarization and no fine-structure splitting. These results are desirable to the application to the quantum cryptography used in the field of quantum information technology.

Takamiya, Kengo; Fukushima, Toshiyuki; Yagi, Shuhei; Hijikata, Yasuto; Yaguchi, Hiroyuki [Graduate School of Science and Engineering, Saitama University, 255 Shimo-Okubo, Sakura-ku , Saitama 338-8570 (Japan); Mochizuki, Toshimitsu; Yoshita, Masahiro; Akiyama, Hidefumi [Institute for Solid State Physics, The University of Tokyo, 5-1-5 Kashiwanoha, Kashiwa, Chiba 277-8581 (Japan); Kuboya, Shigeyuki; Onabe, Kentaro [Department of Advanced Materials Science, The University of Tokyo, 5-1-5 Kashiwanoha, Kashiwa, Chiba 277-8581 (Japan); Katayama, Ryuji [Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577 (Japan)

2013-12-04T23:59:59.000Z

450

Mechanisms of synfuel degradation. 3. Interactive effects in nitrogen compound induced storage instability in shale derived diesel fuel  

SciTech Connect

Deterioration in fuel quality upon storage has been a continuing problem in the utilization of middle distillate fuels. For diesel fuels, instability is usually defined by the formation of insoluble sediments and gums and by the accumulation of hydroperoxides. Gravimetric accelerated storage stability tests conducted with model compounds as dopants in otherwise stable distillate fuels have demonstrated that oxidative condensation reactions of polar heterocycles are deleterious to stability. In particular, nitrogen containing aromatics (pyrroles, pyridines, indoles, etc.) appear to be very harmful.

Cooney, J.V.; Beal, E.J.; Beaver, B.D.

1986-01-01T23:59:59.000Z

451

Neutral nitrogen acceptors in ZnO: The {sup 67}Zn hyperfine interactions  

SciTech Connect

Electron paramagnetic resonance (EPR) is used to characterize the {sup 67}Zn hyperfine interactions associated with neutral nitrogen acceptors in zinc oxide. Data are obtained from an n-type bulk crystal grown by the seeded chemical vapor transport method. Singly ionized nitrogen acceptors (N{sup ?}) initially present in the crystal are converted to their paramagnetic neutral charge state (N{sup 0}) during exposure at low temperature to 442 or 633?nm laser light. The EPR signals from these N{sup 0} acceptors are best observed near 5?K. Nitrogen substitutes for oxygen ions and has four nearest-neighbor cations. The zinc ion along the [0001] direction is referred to as an axial neighbor and the three equivalent zinc ions in the basal plane are referred to as nonaxial neighbors. For axial neighbors, the {sup 67}Zn hyperfine parameters are A{sub ?}?=?37.0?MHz and A{sub ?}?=?8.4?MHz with the unique direction being [0001]. For nonaxial neighbors, the {sup 67}Zn parameters are A{sub 1}?=?14.5?MHz, A{sub 2}?=?18.3?MHz, and A{sub 3}?=?20.5?MHz with A{sub 3} along a [101{sup Ż}0] direction (i.e., in the basal plane toward the nitrogen) and A{sub 2} along the [0001] direction. These {sup 67}Zn results and the related {sup 14}N hyperfine parameters provide information about the distribution of unpaired spin density at substitutional neutral nitrogen acceptors in ZnO.

Golden, E. M.; Giles, N. C., E-mail: Nancy.Giles@afit.edu [Department of Engineering Physics, Air Force Institute of Technology, Wright-Patterson Air Force Base, Ohio 45433 (United States); Evans, S. M.; Halliburton, L. E. [Department of Physics, West Virginia University, Morgantown, West Virginia 26506 (United States)

2014-03-14T23:59:59.000Z

452

Surface modification of nitrogen-doped carbon nanotubes by ozone via atomic layer deposition  

SciTech Connect

The use of ozone as an oxidizing agent for atomic layer deposition (ALD) processes is rapidly growing due to its strong oxidizing capabilities. However, the effect of ozone on nanostructured substrates such as nitrogen-doped multiwalled carbon nanotubes (NCNTs) and pristine multiwalled carbon nanotubes (PCNTs) are not very well understood and may provide an avenue toward functionalizing the carbon nanotube surface prior to deposition. The effects of ALD ozone treatment on NCNTs and PCNTs using 10?wt. % ozone at temperatures of 150, 250, and 300?°C are studied. The effect of ozone pulse time and ALD cycle number on NCNTs and PCNTs was also investigated. Morphological changes to the substrate were observed by scanning electron microscopy and high resolution transmission electron microscopy. Brunauer-Emmett-Teller measurements were also conducted to determine surface area, pore size, and pore size distribution following ozone treatment. The graphitic nature of both NCNTs and PCNTs was determined using Raman analysis while x-ray photoelectron spectroscopy (XPS) was employed to probe the chemical nature of NCNTs. It was found that O{sub 3} attack occurs preferentially to the outermost geometric surface of NCNTs. Our research also revealed that the deleterious effects of ozone are found only on NCNTs while little or no damage occurs on PCNTs. Furthermore, XPS analysis indicated that ALD ozone treatment on NCNTs, at elevated temperatures, results in loss of nitrogen content. Our studies demonstrate that ALD ozone treatment is an effective avenue toward creating low nitrogen content, defect rich substrates for use in electrochemical applications and ALD of various metal/metal oxides.

Lushington, Andrew; Liu, Jian; Tang, Yongji; Li, Ruying; Sun, Xueliang, E-mail: xsun@eng.uwo.ca [Department of Mechanical and Materials Engineering, University of Western Ontario, London, Ontario N6A 5B9 (Canada)

2014-01-15T23:59:59.000Z

453

Frostbite Theater - Liquid Oxygen vs. Liquid Nitrogen - Liquid Oxygen and  

NLE Websites -- All DOE Office Websites (Extended Search)

Cells vs. Liquid Nitrogen! Cells vs. Liquid Nitrogen! Previous Video (Cells vs. Liquid Nitrogen!) Frostbite Theater Main Index Next Video (Paramagnetism) Paramagnetism Liquid Oxygen and Fire! What happens when nitrogen and oxygen are exposed to fire? [ Show Transcript ] Announcer: Frostbite Theater presents... Cold Cuts! No baloney! Joanna and Steve: Just science! Joanna: Hi! I'm Joanna! Steve: And I'm Steve! Joanna: And this is a test tube of liquid nitrogen! Steve: And this is a test tube of liquid oxygen! Joanna: Let's see what happens when nitrogen and oxygen are exposed to fire. Steve: Fire?! Joanna: Yeah! Steve: Really?! Joanna: Why not! Steve: Okay! Joanna: As nitrogen boils, it changes into nitrogen gas. Because it's so cold, it's denser than the air in the room. The test tube fills up with

454

Liquid absorbent solutions for separating nitrogen from natural gas  

DOE Patents (OSTI)

Nitrogen-absorbing and -desorbing compositions, novel ligands and transition metal complexes, and methods of using the same, which are useful for the selective separation of nitrogen from other gases, especially natural gas.

Friesen, Dwayne T. (Bend, OR); Babcock, Walter C. (Bend, OR); Edlund, David J. (Redmond, OR); Lyon, David K. (Bend, OR); Miller, Warren K. (Bend, OR)

2000-01-01T23:59:59.000Z

455

First Principles Prediction of Nitrogen-doped Carbon Nanotubes...  

NLE Websites -- All DOE Office Websites (Extended Search)

First Principles Prediction of Nitrogen-doped Carbon Nanotubes as a High-Performance Cathode for Li-S Batteries. First Principles Prediction of Nitrogen-doped Carbon Nanotubes as a...

456

Breath is a mixture of nitrogen, oxygen, carbon dioxide, water  

E-Print Network (OSTI)

12 SCIENCE Breath is a mixture of nitrogen, oxygen, carbon dioxide, water vapour, inert gases. On the basis of proton affinity, the major constituents of air and breath (nitrogen, oxygen, carbon dioxide

457

Nitrogen chemistry during oil shale pyrolysis  

SciTech Connect

Real time evolution of ammonia (NH{sub 3}) and hydrogen cyanide (HCN), two major nitrogen-containing volatiles evolved during oil shale pyrolysis, was measured by means of a mass spectrometer using chemical ionization and by infrared spectroscopy. While the on-line monitoring of NH{sub 3} in oil shale pyrolysis games was possible by both techniques, HCN measurements were only possible by IR. We studied one Green River Formation oil shale and one New Albany oil shale. The ammonia from the Green River oil shale showed one broad NH{sub 3} peak maximizing at a high temperature. For both oil shales, most NH{sub 3} evolves at temperatures above oil-evolving temperature. The important factors governing ammonia salts such as Buddingtonite in Green River oil shales, the distribution of nitrogen functional groups in kerogen, and the retorting conditions. The gas phase reactions, such as NH{sub 3} decomposition and HCN conversion reactions, also play an important role in the distribution of nitrogen volatiles, especially at high temperatures. Although pyrolysis studies of model compounds suggests the primary nitrogen product from kerogen pyrolysis to be HCN at high temperatures, we found only a trace amount of HCN at oil-evolving temperatures and none at high temperatures (T {gt} 600{degree}C). 24 refs., 6 figs., 2 tabs.

Oh, Myongsook S.; Crawford, R.W.; Foster, K.G.; Alcaraz, A.

1990-01-10T23:59:59.000Z

458

Introduction Air Quality and Nitrogen Dioxide  

E-Print Network (OSTI)

- Global update 2005. Primary sources of air pollutants include combustion products from power generationIntroduction Air Quality and Nitrogen Dioxide Air pollution can be defined as "the presence effects to man and/or the environment". (DEFRA) "Clean air is considered to be a basic requirement

459

groundwater nitrogen source identification and remediation  

E-Print Network (OSTI)

producer profits. This will, in turn, benefit water bodies in the area that receive stream baseflow fromgroundwater nitrogen source identification and remediation The Seymour Aquifer is a shallow aquifer water withdraws are used for irrigation while the cities of Vernon, Burk- burnett and Electra and many

460

OXYGEN ADSORPTION ON NITROGEN CONTAINING CARBON SURFACES  

E-Print Network (OSTI)

OXYGEN ADSORPTION ON NITROGEN CONTAINING CARBON SURFACES Alejandro Montoya, Jorge O. Gil, Fanor-rich site of the carbon basal plane of graphite and then, it dissociates into oxygen atoms.1,2 Oxygen atoms at the edge of the carbon surface can form covalent bonds with oxygen. These sites can chemisorb

Truong, Thanh N.

Note: This page contains sample records for the topic "nitrogen oxides particulate" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Dissolved and particulate aluminum in the Columbia River and coastal waters of Oregon and Washington: behavior in near-field and far-field plumes  

E-Print Network (OSTI)

1 Dissolved and particulate aluminum in the Columbia River and coastal waters of Oregon) and particulate (leachable and total) aluminum was examined in the Columbia River and estuary, in near Influence on Shelf Ecosystems (RISE) cruise of May/June 2006. Dissolved and particulate aluminum (Al

Hickey, Barbara

462

HELSINKI UNIVERSITY OF TECHNOLOGY ENE-47.153 NITROGEN #2NITROGEN #2  

E-Print Network (OSTI)

(BFB), (CFB) (BFB), (CFB) Fuel nitrogen content Excess air Air staging Limestone addition , - (BFB), (CFB) SO2 level SNCR ­ NH3 , - SNCR ­ urea SCR - Pressure , (but NO2 ) #12;HELSINKI

Zevenhoven, Ron

463

Evolutionary tradeoffs can select against nitrogen fixation and thereby maintain nitrogen limitation  

E-Print Network (OSTI)

. evolutionary ecology model Biological nitrogen (N) fixation--the conversion of atmo- spheric N2 gas) but is equally important to explaining the paradox of N limitation. Unlike the successional question

Menge, Duncan

464

Temperature and nutrient supply interact to control nitrogen fixation ...  

Science Journals Connector (OSTI)

Temperature and nutrient supply interact to control nitrogen fixation in oligotrophic streams: An experimental examination. Marcarelli, Amy M., Wayne A.

465

Analytical solutions for the trajectories and thermal histories of unforced particulates  

Science Journals Connector (OSTI)

Dilute suspensions of finely dispersed particulates are found in many engineering applications. This article shows that the nonlinear equations of motion and heat transfer for the particles may be solved analytically for certain realistic drag and heat transfer functions under idealized conditions. Some applications are discussed.

Lawrence D. Cloutman

1988-01-01T23:59:59.000Z

466

Modeling water column structure and suspended particulate matter on the Middle Atlantic continental shelf  

E-Print Network (OSTI)

that contributed to the evolution of observed thermal structure and resuspension of particulate matter during resuspension processes. It is concluded that wave-current bottom shear stress was clearly the most important process for sediment resuspension during and following both hurricanes. Discrepancies between modeled

Chang, Grace C.

467

Deposition, resuspension, and decomposition of particulate organic matter in the sediments of Lake Itasca, Minnesota, USA  

Science Journals Connector (OSTI)

Sediment traps were used to investigate the settling, resuspension, and decomposition of particulate organic matter in...?2 d?1 at 4 m and increased to 2.1 to 3.2 g m?2 d?1 two meters above the bottom sediment in...

Randall E. Hicks; Christopher J. Owen; Peter Aas

1994-05-13T23:59:59.000Z

468

Dual Fuel Diesel Engine Operation Using H2. Effect on Particulate Emissions  

Science Journals Connector (OSTI)

Dual Fuel Diesel Engine Operation Using H2. ... School of Engineering, Mechanical and Manufacturing Engineering, The University of Birmingham, Birmingham B15 2TT, United Kingdom, Universidad de Castilla?La Mancha, Edificio Politecnico, Escuela Tecnica Superior de Ingenieros Industriales, Avda. ... In diesel engines, the reduction of particulate emissions must be achieved in conjunction with the reduction of NOx emissions. ...

A. Tsolakis; J. J. Hernandez; A. Megaritis; M. Crampton

2005-01-11T23:59:59.000Z

469

Magnetic properties and Mössbauer spectra of urban atmospheric particulate matter: a case study from Munich, Germany  

Science Journals Connector (OSTI)

......in urban pollution PM, the...impurities in fossil fuels convert on...found in air-conditioning...isopropanol solution was wet-sieved...Report of the Air Quality of Urban Air Review Group...particulates from pollution in the environment...distance from fossil fuel power stations......

A. R. Muxworthy; E. Schmidbauer; N. Petersen

2002-08-01T23:59:59.000Z

470

Source apportionment of time-and size-resolved ambient particulate matter , Philip K. Hopke b,  

E-Print Network (OSTI)

International Airport were analyzed for the elemental composition using synchrotron X-ray fluorescence Airport emission sources Size- and time-resolved particulate matter samples collected using eight-stage Davis Rotating-drum Universal- size-cut Monitoring (DRUM) impactors at the Washington-Dulles

Navasca, Carmeliza

471

Z .Marine Chemistry 67 1999 3342 Differences in seawater particulate organic carbon concentration  

E-Print Network (OSTI)

of the organic carbon retained by a glass-fiber filter against the volume filtered. The interceptZ .Marine Chemistry 67 1999 33­42 Differences in seawater particulate organic carbon concentration August 1998; accepted 11 May 1999 Abstract Z . Z . ZParticulate organic carbon POC data collected

472

Radionuclide concentrations in air particulate at Palermo (Italy) following Fukushima accident  

Science Journals Connector (OSTI)

......Ethernet environment. Data analysis was performed using...evaluation of the burnup of a reactor, but it is also capable...confirms with sufficient reliability the origin of the radioactive...particulate by multi-spectra analysis. (1990) Quaderni D...Spectrometric analysis of the filters highlights......

S. Rizzo; E. Tomarchio

2013-03-01T23:59:59.000Z

473

Direct Capillary Gas Chromatography of Filter-Borne Particulate Emissions from Diesel Engines  

Science Journals Connector (OSTI)

......core (13). The hydrocarbons, which typically...products of the diesel combustion process (49...from incomplete combustion of fuel. Techniques...particulate- bound hydrocarbons have most often...analysis in individual heat-sealed plastic...Chromatograms and associated data were obtained via......

R.D. Cuthbertson; P.R. Shore

1988-03-01T23:59:59.000Z

474

Particulate Matter Science for Policy Makers: A NARSTO Assessment is a concise and  

E-Print Network (OSTI)

Shepherd #12;1 - 2 CHAPTER 1 atmospheric processes, and the resultant atmospheric pollution loadings. Exposure and Impacts: Understanding of cause-effect relationships among atmospheric pollutants, exposures discussion of the current understanding of airborne particulate matter (PM) among atmospheric scientists. Its

Weber, Rodney

475

Respiratory disease and particulate air pollution in Santiago Chile: Contribution of erosion particles from fine sediments  

E-Print Network (OSTI)

August) that make atmospheric conditions highly vulnerable, preventing polluting particles in the airCommentary Respiratory disease and particulate air pollution in Santiago Chile: Contribution pollution Santiago Erosion Sedimentation a b s t r a c t Air pollution in Santiago is a serious problem

476

Deep-Sea Research II 50 (2003) 655674 Determining true particulate organic carbon: bottles, pumps  

E-Print Network (OSTI)

Deep-Sea Research II 50 (2003) 655­674 Determining true particulate organic carbon: bottles, pumps or by in situ filtration with pumps and analyzing the filters. The concentrations measured by these two methods-latitude waters. Here we report that the ratio of bottle POC to pump POC ranged between 20 and 200 in the Ross Sea

Hansell, Dennis

477

Conduction in Multiphase ParticulateFibrous Networks Simulations and Experiments on Li-ion Anodes  

E-Print Network (OSTI)

promising Li-ion battery technologies incorporate nanoarchitectured carbon networks, typically in the form electronically February 7, 2003. Several promising Li-ion battery technologies incorporate nanoarchitecturedConduction in Multiphase ParticulateĂ?Fibrous Networks Simulations and Experiments on Li-ion Anodes

Sastry, Ann Marie

478

A FUNCTIONAL DATA ANALYSIS APPROACH FOR EVALUATING TEMPORAL PHYSIOLOGIC RESPONSES TO PARTICULATE MATTER  

E-Print Network (OSTI)

, including air pollutants such as ozone and particulate matter. Bradycardia and hypothermia are often Hypertensive rats (n=35; 8­9/group) were intratracheally instilled with a bolus dose of saline (control that effects between the control and high dose group persisted for at least 48 hr. The applicability of FDA

Lee, Chihoon

479

Ecological Effects and In-situ Detection of Particulate Contaminants in Aqueous Environments  

E-Print Network (OSTI)

investigates crude oil toxicity as a particulate suspension, suitability of in-situ instrumentation to measure crude oil suspensions, and the applicability of using acoustic backscatter to measure suspended solids and sub-surface oil droplet suspension... and Discussion................................................................... 132 x CHAPTER Page Suspended solids characterization......................................... 132 Acoustic backscatter depth profiles...

Fuller, Christopher Byron

2012-07-16T23:59:59.000Z

480

Core-level spectroscopy of thin oxides and oxynitrides  

SciTech Connect

Several spectroscopic methods are discussed that use core levels, such as photoelectron spectroscopy and absorption spectroscopy with photoelectron or fluorescence detection. Measurements are presented on the desorption of a chemical oxide and the growth of oxynitrides with N{sub 2}0 on Si(100). The stoichiometry is found to change strongly with thickness, from a nitrogen-terminated Si surface to a nearly-pure oxide in the outer region of 40--60 {Angstrom} films. Using a third generation synchrotron beam line a sensitivity of better than a tenth of a monolayer is achieved by a simple photocurrent measurement.

Himpsel, F.J.; Akatsu, H. [International Business Machines Corp., Yorktown Heights, NY (United States). Thomas J. Watson Research Center; Carlisle, J.A. [Lawrence Livermore National Lab., CA (United States)] [and others

1994-07-19T23:59:59.000Z

Note: This page contains sample records for the topic "nitrogen oxides particulate" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

Vapour nucleation in a cryogenic–fluid–dissolved–nitrogen mixture during rapid depressurization  

Science Journals Connector (OSTI)

...the dissolved nitrogen comes out of the...effect of dissolved nitrogen was not addressed...non-condensable gas (nitrogen) in a cryogenic...g. superheated water or pure refrigerants...to estimate the solubility of nitrogen in...

1999-01-01T23:59:59.000Z

482

Nitrogen use in switchgrass grown for bioenergy across the USA  

E-Print Network (OSTI)

Nitrogen use in switchgrass grown for bioenergy across the USA V.N. Owens a , D.R. Viands b , H Available online 17 August 2013 Keywords: Nitrogen removal Switchgrass Bioenergy Nitrogen use efficiency as a forage, conservation, and bioenergy crop [1e5]. It offers a number of distinct benefits including broad

Pawlowski, Wojtek

483

Relation of Soil Nitrogen, Nitrification and Ammonification to Pot Experiments.  

E-Print Network (OSTI)

............................................ 6 Relation of the Crops to the Total Nitrogen of the Soil ........... 7 Relation of the Different Crops ................................. 8 Relation of Surface Soil to Subsoil ............................. 13 Acid Soils Compared with Non-Acid... of Production of Nitrates to the Results of the Pot Ex- periments ................................................ 21 Extensive Work ............................................ 24 Relation of Nitric Nitrogen to Nitrogen Removed by First Crop .... 24...

Fraps, G. S. (George Stronach)

1921-01-01T23:59:59.000Z

484

QuestionQuestion How does nitrogen deposition affect roadside  

E-Print Network (OSTI)

al. 2004. Concentrations of ammonia and nitrogen dioxide at roadside verges, and their contributionQuestionQuestion How does nitrogen deposition affect roadside plant community composition? 1. Is there a gradient of nitrogen deposition to freeway verges from traffic exhaust? 2. Are there other sources of N

Hall, Sharon J.

485

Simple approaches for measuring dry atmospheric nitrogen deposition to watersheds  

E-Print Network (OSTI)

'' and spatial variations of gaseous dry N deposition (i.e., nitrogen dioxide (NO2) and ammonia (NH3)), thoughSimple approaches for measuring dry atmospheric nitrogen deposition to watersheds Heather E. Golden the effects of atmospheric nitrogen (N) deposition on surface water quality requires accurate accounts

Elliott, Emily M.

486

A chronology of human understanding of the nitrogen cycle  

Science Journals Connector (OSTI)

...nitrogen and hydrogen gas [7,22,23...process surpassed natural N fixation [31...of the nitrogen cascade was proposed...terrestrial 104 118 --natural - - 30 50 50 170...consequences in the natural environment...2003 The nitrogen cascade. Bioscience 53...anthropogenic trace gases. In Interactions...

2013-01-01T23:59:59.000Z

487

How extensive are the impacts of nitrogen pollution in Great  

E-Print Network (OSTI)

the 1940s atmospheric nitrogen pollution has steadily increased, primarily as a consequence in the deposition of atmospheric nitrogen pollutants are likely to have contributed to improved forest productivityHow extensive are the impacts of nitrogen pollution in Great Britain's forests? Protecting our

488

Special Aspects of Nitrogen Fixation by Blue-Green Algae  

Science Journals Connector (OSTI)

...Aspects of Nitrogen Fixation by Blue-Green Algae Rosalie M. Cox P. Fay When carbon dioxide...required for nitrogen fixation in this alga. A ratio of pyruvate decarboxylation to...independent of photosynthesis in blue-green algae. Special aspects of nitrogen fixation...

1969-01-01T23:59:59.000Z

489

Stress dependent oxidation of sputtered niobium and effects on superconductivity  

SciTech Connect

We report on the suppression of room temperature oxidation of DC sputtered niobium films and the effects upon the superconductive transition temperature, T{sub c}. Niobium was sputter-deposited on silicon dioxide coated 150?mm wafers and permitted to oxidize at room temperature and pressure for up to two years. Resistivity and stress measurements indicate that tensile films greater than 400?MPa resist bulk oxidation with measurements using transmission electron microscope, electron dispersive X-ray spectroscopy, x-ray photoelectric spectroscopy, and secondary ion mass spectrometry confirming this result. Although a surface oxide, Nb{sub 2}O{sub 5}, consumed the top 6–10?nm, we measure less than 1 at. % oxygen and nitrogen in the bulk of the films after the oxidation period. T{sub c} measurements using a SQUID magnetometer indicate that the tensile films maintained a T{sub c} approaching the dirty superconductive limit of 8.4?K after two years of oxidation while maintaining room temperature sheet resistance. This work demonstrates that control over niobium film stress during deposition can prevent bulk oxidation by limiting the vertical grain boundaries ability to oxidize, prolonging the superconductive properties of sputtered niobium when exposed to atmosphere.

David Henry, M., E-mail: mdhenry@sandia.gov; Wolfley, Steve; Monson, Todd; Clark, Blythe G.; Shaner, Eric; Jarecki, Robert [Sandia National Labs, MESA Fabrication Facility PO Box 5800 MS 1084, Albuquerque, New Mexico 87185-1084 (United States)

2014-02-28T23:59:59.000Z

490

Nitrogen-concentration control in GaNAs/AlGaAs quantum wells using nitrogen ?-doping technique  

SciTech Connect

GaNAs/Al{sub 0.35}Ga{sub 0.65}As multiple quantum wells (MQWs) with nitrogen ?-doping were fabricated on GaAs (100) substrates by plasma-assisted molecular beam epitaxy. High controllability of nitrogen-concentrations in the MQWs was achieved by tuning nitrogen ?-doping time. The maximum nitrogen concentration in the MQWs was 2.8%. The MQWs exhibit intense, narrow photoluminescence emission.

Mano, Takaaki; Jo, Masafumi; Kuroda, Takashi; Noda, Takeshi; Sugimoto, Yoshimasa; Sakuma, Yoshiki [National Institute for Materials Science, 1-2-1 Sengen, Tsukuba, Ibaraki 305-0047 (Japan); Elborg, Martin; Sakoda, Kazuaki [National Institute for Materials Science, 1-2-1 Sengen, Tsukuba, Ibaraki 305-0047, Japan and Graduate School of Pure and Applied Sciences, University of Tsukuba, 1-1-1 Tennodai, Tsukuba, Ibaraki 305-8577 (Japan)

2014-05-15T23:59:59.000Z

491

Toward a mechanistic modeling of nitrogen limitation on vegetation dynamics  

SciTech Connect

Nitrogen is a dominant regulator of vegetation dynamics, net primary production, and terrestrial carbon cycles; however, most ecosystem models use a rather simplistic relationship between leaf nitrogen content and photosynthetic capacity. Such an approach does not consider how patterns of nitrogen allocation may change with differences in light intensity, growing-season temperature and CO{sub 2} concentration. To account for this known variability in nitrogen-photosynthesis relationships, we develop a mechanistic nitrogen allocation model based on a trade-off of nitrogen allocated between growth and storage, and an optimization of nitrogen allocated among light capture, electron transport, carboxylation, and respiration. The developed model is able to predict the acclimation of photosynthetic capacity to changes in CO{sub 2} concentration, temperature, and radiation when evaluated against published data of V{sub c,max} (maximum carboxylation rate) and J{sub max} (maximum electron transport rate). A sensitivity analysis of the model for herbaceous plants, deciduous and evergreen trees implies that elevated CO{sub 2} concentrations lead to lower allocation of nitrogen to carboxylation but higher allocation to storage. Higher growing-season temperatures cause lower allocation of nitrogen to carboxylation, due to higher nitrogen requirements for light capture pigments and for storage. Lower levels of radiation have a much stronger effect on allocation of nitrogen to carboxylation for herbaceous plants than for trees, resulting from higher nitrogen requirements for light capture for herbaceous plants. As far as we know, this is the first model of complete nitrogen allocation that simultaneously considers nitrogen allocation to light capture, electron transport, carboxylation, respiration and storage, and the responses of each to altered environmental conditions. We expect this model could potentially improve our confidence in simulations of carbon-nitrogen interactions and the vegetation feedbacks to climate in Earth system models.

Xu, Chonggang [Los Alamos National Laboratory (LANL); Fisher, Rosie [National Center for Atmospheric Research (NCAR); Wullschleger, Stan D [ORNL; Wilson, Cathy [Los Alamos National Laboratory (LANL); Cai, Michael [Los Alamos National Laboratory (LANL); McDowell, Nathan [Los Alamos National Laboratory (LANL)

2012-01-01T23:59:59.000Z

492

Oxidation of propylene over copper oxide catalysts  

E-Print Network (OSTI)

to the study of propylene oxidation. Dunlop (17) reported that small quantities of iron compounds substantially enhanced the catalytic activity of chromia-alumina catalysts with respect to propylene oxidation, Woodharn (72) has suggested that under... between 360 C and 430oC the rate of propane oxidation decreases as the teznperature is increased, and the rate of conversion to olefins, especially propylene, becomes progressively greater. Above 430 C the proportion of propane converted to ethylene in...

Billingsley, David Stuart

2012-06-07T23:59:59.000Z

493

Frostbite Theater - Liquid Nitrogen Experiments - Freeze the Rainbow!  

NLE Websites -- All DOE Office Websites (Extended Search)

Liquid Nitrogen in a Microwave! Liquid Nitrogen in a Microwave! Previous Video (Liquid Nitrogen in a Microwave!) Frostbite Theater Main Index Next Video (Liquid Nitrogen and Antifreeze!) Liquid Nitrogen and Antifreeze! Freeze the Rainbow! Starburst candy. They're fruity. They're chewy. They're delicious! But, can they survive taking a bath in liquid nitrogen? [ Show Transcript ] Announcer: Frostbite Theater presents... Cold Cuts! No baloney! Joanna and Steve: Just science! Joanna: Hi! I'm Joanna! Steve: And I'm Steve! Joanna: A student visiting Jefferson Lab from Huntington Middle School in Newport News, Virginia, asked what happens to a starburst if you put it in liquid nitrogen. Well, we're going to find out! Steve: At room temperature, starburst isn't really all that special. I can kind of squish it if I squeeze it hard enough and, if I drop it, nothing

494

Frostbite Theater - Liquid Nitrogen Experiments - Giant Koosh Ball!  

NLE Websites -- All DOE Office Websites (Extended Search)

Let's Pour Liquid Nitrogen on the Floor! Let's Pour Liquid Nitrogen on the Floor! Previous Video (Let's Pour Liquid Nitrogen on the Floor!) Frostbite Theater Main Index Next Video (Egg + Liquid Nitrogen + Time-lapse!) Egg + Liquid Nitrogen + Time-lapse! Giant Koosh Ball! Sometimes, you just want to know what's going to happen! [ Show Transcript ] Announcer: Frostbite Theater presents... Cold Cuts! No baloney! Joanna and Steve: Just science! Joanna: Hi! I'm Joanna! Steve: And I'm Steve! A while ago, I was at the mall and I saw this. And, the first thing that popped into my head was 'I wonder what would happen if we were to put this in liquid nitrogen?' Now, that's one thing I really love about science. If you have a question, you can, sometimes, do an experiment to find out what the answer is! Here at the Lab, we have a lot of liquid nitrogen, so that's

495

Frostbite Theater - Liquid Nitrogen Experiments - Let's Freeze Liquid  

NLE Websites -- All DOE Office Websites (Extended Search)

Shattering Pennies! Shattering Pennies! Previous Video (Shattering Pennies!) Frostbite Theater Main Index Next Video (Liquid Nitrogen in a Microwave!) Liquid Nitrogen in a Microwave! Let's Freeze Liquid Nitrogen! By removing the hottest molecules, we're able to freeze liquid nitrogen! [ Show Transcript ] Announcer: Frostbite Theater presents... Cold Cuts! No baloney! Joanna and Steve: Just science! Joanna: Hi! I'm Joanna! Steve: And I'm Steve! Joanna: Today, we're going to freeze liquid nitrogen! Joanna and Steve: Yeah! Joanna: The obvious way to do this is to put the liquid nitrogen into something colder. Something that we have lots of around here! Something like... liquid helium! Steve: Yes! Joanna: Yeah, but we're not going to do that. Instead, we're going to freeze the nitrogen by removing the hottest molecules!

496

SURFACE OXIDATION OF DIESEL PARTICULATE MATTER IN PRESENCE OF O3 +NOX: NEW TD/GC/MS ANALYSIS METHOD  

E-Print Network (OSTI)

in the atmosphere. TD-GC-MS ANALYSIS METHODOLOGY A thermal desorption (TD) injection device (M. Ezrin, 1991. Valve Spindle 10. Carrier Gas Inlet 11. Inlet Assembly 12. Injection Port Insert PAH standard Solution, 1ppm, 1µL injection Alkanes Standard Solution, 0.1ppm, 1µL injection FUTURE EXPERIMENTS Verify PM

Holmén, Britt A.

497

Oxidation of Mercury in Products of Coal Combustion  

SciTech Connect

Laboratory measurements of mercury oxidation during selective catalytic reduction (SCR) of nitric oxide, simulation of pilot-scale measurements of mercury oxidation and adsorption by unburned carbon and fly ash, and synthesis of new materials for simultaneous oxidation and adsorption of mercury, were performed in support of the development of technology for control of mercury emissions from coal-fired boilers and furnaces. Conversion of gas-phase mercury from the elemental state to water-soluble oxidized form (HgCl{sub 2}) enables removal of mercury during wet flue gas desulfurization. The increase in mercury oxidation in a monolithic V{sub 2}O{sub 5}-WO{sub 3}/TiO{sub 2} SCR catalyst with increasing HCl at low levels of HCl (< 10 ppmv) and decrease in mercury oxidation with increasing NH{sub 3}/NO ratio during SCR were consistent with results of previous work by others. The most significant finding of the present work was the inhibition of mercury oxidation in the presence of CO during SCR of NO at low levels of HCl. In the presence of 2 ppmv HCl, expected in combustion products from some Powder River Basin coals, an increase in CO from 0 to 50 ppmv reduced the extent of mercury oxidation from 24 {+-} 3 to 1 {+-} 4%. Further increase in CO to 100 ppmv completely suppressed mercury oxidation. In the presence of 11-12 ppmv HCl, increasing CO from 0 to {approx}120 ppmv reduced mercury oxidation from {approx}70% to 50%. Conversion of SO{sub 2} to sulfate also decreased with increasing NH{sub 3}/NO ratio, but the effects of HCl and CO in flue gas on SO{sub 2} oxidation were unclear. Oxidation and adsorption of mercury by unburned carbon and fly ash enables mercury removal in a particulate control device. A chemical kinetic mechanism consisting of nine homogeneous and heterogeneous reactions for mercury oxidation and removal was developed to interpret pilot-scale measurements of mercury oxidation and adsorption by unburned carbon and fly ash in experiments at pilot scale, burning bituminous coals (Gale, 2006) and blends of bituminous coals with Powder River Basin coal (Gale, 2005). The removal of mercury by fly ash and unburned carbon in the flue gas from combustion of the bituminous coals and blends was reproduced with satisfactory accuracy by the model. The enhancement of mercury capture in the presence of calcium (Gale, 2005) explained a synergistic effect of blending on mercury removal across the baghouse. The extent of mercury oxidation, on the other hand, was not so well described by the simulation, because of oversensitivity of the oxidation process in the model to the concentration of unburned carbon. Combined catalysts and sorbents for oxidation and removal of mercury from flue gas at low temperature were based on surfactant-templated silicas containing a transition metal and an organic functional group. The presence of both metal ions and organic groups within the pore structure of the materials is expected to impart to them the ability to simultaneously oxidize elemental mercury and adsorb the resulting oxidized mercury. Twelve mesoporous organosilicate catalysts/sorbents were synthesized, with and without metals (manganese, titanium, vanadium) and organic functional groups (aminopropyl, chloropropyl, mercaptopropyl). Measurement of mercury oxidation and adsorption by the candidate materials remains for future work.

Peter Walsh; Giang Tong; Neeles Bhopatkar; Thomas Gale; George Blankenship; Conrad Ingram; Selasi Blavo Tesfamariam Mehreteab; Victor Banjoko; Yohannes Ghirmazion; Heng Ban; April Sibley

2009-09-14T23:59:59.000Z

498

DISSOLUTION OF NEPTUNIUM OXIDE RESIDUES  

SciTech Connect

This report describes the development of a dissolution flowsheet for neptunium (Np) oxide (NpO{sub 2}) residues (i.e., various NpO{sub 2} sources, HB-Line glovebox sweepings, and Savannah River National Laboratory (SRNL) thermogravimetric analysis samples). Samples of each type of materials proposed for processing were dissolved in a closed laboratory apparatus and the rate and total quantity of off-gas were measured. Samples of the off-gas were also analyzed. The quantity and type of solids remaining (when visible) were determined after post-dissolution filtration of the solution. Recommended conditions for dissolution of the NpO{sub 2} residues are: Solution Matrix and Loading: {approx}50 g Np/L (750 g Np in 15 L of dissolver solution), using 8 M nitric acid (HNO{sub 3}), 0.025 M potassium fluoride (KF) at greater than 100 C for at least 3 hours. Off-gas: Analysis of the off-gas indicated nitric oxide (NO), nitrogen dioxide (NO{sub 2}) and nitrous oxide (N{sub 2}O) as the only identified components. No hydrogen (H{sub 2}) was detected. The molar ratio of off-gas produced per mole of Np dissolved ranged from 0.25 to 0.4 moles of gas per mole of Np dissolved. A peak off-gas rate of {approx}0.1 scfm/kg bulk oxide was observed. Residual Solids: Pure NpO{sub 2} dissolved with little or no residue with the proposed flowsheet but the NpCo and both sweepings samples left visible solid residue after dissolution. For the NpCo and Part II Sweepings samples the residue amounted to {approx}1% of the initial material, but for the Part I Sweepings sample, the residue amounted to {approx}8 % of the initial material. These residues contained primarily aluminum (Al) and silicon (Si) compounds that did not completely dissolve under the flowsheet conditions. The residues from both sweepings samples contained minor amounts of plutonium (Pu) particles. Overall, the undissolved Np and Pu particles in the residues were a very small fraction of the total solids.

Kyser, E

2009-01-12T23:59:59.000Z

499

NATURAL GAS VARIABILITY IN CALIFORNIA: ENVIRONMENTAL IMPACTS AND DEVICE PERFORMANCE EXPERIMENTAL EVALUATION OF POLLUTANT EMISSIONS FROM RESIDENTIAL APPLIANCES  

E-Print Network (OSTI)

nitrogen oxides, nitrogen dioxide, and  the number of (liquefied natural gas, nitrogen  dioxide, nitrogen oxides, nitrogen oxides, nitrogen dioxide, particle  number,  and 

Singer, Brett C.

2010-01-01T23:59:59.000Z

500

Development and validation of a semi-empirical model for the estimation of particulate matter in diesel engines  

Science Journals Connector (OSTI)

Abstract A semi-empirical correlation for the estimation of PM (particulate matter) emissions in diesel engines, as a function of significant engine operating variables, has been developed and validated on a GM (General Motors) Euro 5 diesel engine. The experimental data used in the present study have been acquired at the dynamic test bench of ICEAL-PT (Internal Combustion Engine Advanced Laboratory at the Politecnico di Torino), in the frame of a research activity with GMPT-E (General Motors PowerTrain-Europe) for the calibration of a Euro 5 prototype 2.0 liter diesel engine equipped with a twin-stage turbine and a piezo-driven Common Rail injection system. The experimental data were acquired for six key-points representative of the engine working conditions over a NEDC (New European Driving Cycle). The experimental tests have been carried out according to the Design of Experiment approach and for each point several variation lists of the main engine variables have been considered. As a first step, the main engine variables which are expected to be related to the formation and oxidation of PM have been identified. An exponential mathematical model has then been introduced and a detailed statistical analysis has been carried out for each key-point in order to identify the most robust combination of the input variables among all the possible ones. It was verified that PM emissions are correlated to a great extent to the value of the chemical heat release at the end of the injection of the main pulse. This quantity is in fact related to the mass of burned gases which is generated by the oxidation of the pilot pulses that precede the main injection. Such a mass can have a large impact on the local oxygen concentration and temperature of the charge in which the fuel of the main pulse is injected, with a consequent effect on PM formation. Additional quantities have also been considered in the investigation: the relative air-to-fuel ratio ?, the intake charge oxygen concentration, the accumulated fuel mass, the equivalence ratio of the spray at the main pulse start of combustion and some combustion metrics related to the heat release rate. At the end of the statistical analysis, the most influencing parameters have been selected and a semi-empirical model to predict the in-cylinder formed PM mass has been developed. The model has hence been tested under both steady-state and transient conditions.

Roberto Finesso; Daniela Misul; Ezio Spessa

2014-01-01T23:59:59.000Z