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Note: This page contains sample records for the topic "nitrogen oxide burner" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
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1

Simulation of Nitrogen Emissions in a Low Swirl Burner J. B. Bell, M. S. Day, X. Gao, M. J. Lijewski  

E-Print Network (OSTI)

Simulation of Nitrogen Emissions in a Low Swirl Burner J. B. Bell, M. S. Day, X. Gao, M. J nitrogen emissions. The simulation shows how the cellular burn- ing structures characteristic of lean premixed hydrogen combustion lead to enhancements in the NOx emissions from these flames. Analysis

Bell, John B.

2

THE NITROGEN OXIDES CONTROVERSY  

E-Print Network (OSTI)

including observed nitrogen dioxide," Pure App. Geophys.HN0 ) and probably nitrogen dioxide (N0 ) at a few parts perorganic molecule and nitrogen dioxide. Several examples

Johnston, Harold S.

2012-01-01T23:59:59.000Z

3

Nitrogen Oxides Emission Control Options  

NLE Websites -- All DOE Office Websites (Extended Search)

Nitrogen Nitrogen Oxides Emission Control Options for Coal-Fired Electric Utility Boilers Ravi K. Srivastava and Robert E. Hall U.S. Environmental Protection Agency, National Risk Management Research Laboratory, Air Pollution Prevention and Control Division, Research Triangle Park, NC Sikander Khan and Kevin Culligan U.S. Environmental Protection Agency, Office of Air and Radiation, Clean Air Markets Division, Washington, DC Bruce W. Lani U.S. Department of Energy, National Energy Technology Laboratory, Environmental Projects Division, Pittsburgh, PA ABSTRACT Recent regulations have required reductions in emissions of nitrogen oxides (NO x ) from electric utility boilers. To comply with these regulatory requirements, it is increas- ingly important to implement state-of-the-art NO x con- trol technologies on coal-fired utility boilers. This paper reviews NO x control

4

ASU nitrogen sweep gas in hydrogen separation membrane for production of HRSG duct burner fuel  

DOE Patents (OSTI)

The present invention relates to the use of low pressure N2 from an air separation unit (ASU) for use as a sweep gas in a hydrogen transport membrane (HTM) to increase syngas H2 recovery and make a near-atmospheric pressure (less than or equal to about 25 psia) fuel for supplemental firing in the heat recovery steam generator (HRSG) duct burner.

Panuccio, Gregory J.; Raybold, Troy M.; Jamal, Agil; Drnevich, Raymond Francis

2013-04-02T23:59:59.000Z

5

Simulation of Nitrogen Emissions in a Premixed Hydrogen Flame Stabilized on a Low Swirl Burner  

E-Print Network (OSTI)

of fuels such as pure hydrogen and hydrogen-seeded hydrocarbon mixtures. However, many hydrogen-rich fuels in the context of a laboratory-scale low swirl burner fueled with a lean hydrogen-air mixture at atmospheric of burning lean hydrogen or hydrogen-enriched lean hydrocar- bon fuels (e.g., [2­5]). For these fuels

Bell, John B.

6

nitrogen oxides | OpenEI  

Open Energy Info (EERE)

20 20 Varnish cache server Browse Upload data GDR 429 Throttled (bot load) Error 429 Throttled (bot load) Throttled (bot load) Guru Meditation: XID: 2142279720 Varnish cache server nitrogen oxides Dataset Summary Description Emissions from energy use in buildings are usually estimated on an annual basis using annual average multipliers. Using annual numbers provides a reasonable estimation of emissions, but it provides no indication of the temporal nature of the emissions. Therefore, there is no way of understanding the impact on emissions from load shifting and peak shaving technologies such as thermal energy storage, on-site renewable energy, and demand control. Source NREL Date Released April 11th, 2011 (3 years ago) Date Updated April 11th, 2011 (3 years ago)

7

Nitrogen oxide delivery systems for biological media  

E-Print Network (OSTI)

Elevated levels of nitric oxide (NO) in vivo are associated with a variety of cellular modifications thought to be mutagenic or carcinogenic. These processes are likely mediated by reactive nitrogen species (RNS) such as ...

Skinn, Brian Thomas

2012-01-01T23:59:59.000Z

8

Pulverized coal burner  

DOE Patents (OSTI)

A burner is described having lower emissions and lower unburned fuel losses by implementing a transition zone in a low NO{sub x} burner. The improved burner includes a pulverized fuel transport nozzle surrounded by the transition zone which shields the central oxygen-lean fuel devolatilization zone from the swirling secondary combustion air. The transition zone acts as a buffer between the primary and the secondary air streams to improve the control of near-burner mixing and flame stability by providing limited recirculation regions between primary and secondary air streams. These limited recirculation regions transport evolved NO{sub x} back towards the oxygen-lean fuel pyrolysis zone for reduction to molecular nitrogen. Alternate embodiments include natural gas and fuel oil firing. 8 figs.

Sivy, J.L.; Rodgers, L.W.; Koslosy, J.V.; LaRue, A.D.; Kaufman, K.C.; Sarv, H.

1998-11-03T23:59:59.000Z

9

Pulverized coal burner  

DOE Patents (OSTI)

A burner having lower emissions and lower unburned fuel losses by implementing a transition zone in a low NO.sub.x burner. The improved burner includes a pulverized fuel transport nozzle surrounded by the transition zone which shields the central oxygen-lean fuel devolatilization zone from the swirling secondary combustion air. The transition zone acts as a buffer between the primary and the secondary air streams to improve the control of near-burner mixing and flame stability by providing limited recirculation regions between primary and secondary air streams. These limited recirculation regions transport evolved NO.sub.x back towards the oxygen-lean fuel pyrolysis zone for reduction to molecular nitrogen. Alternate embodiments include natural gas and fuel oil firing.

Sivy, Jennifer L. (Alliance, OH); Rodgers, Larry W. (Canton, OH); Koslosy, John V. (Akron, OH); LaRue, Albert D. (Uniontown, OH); Kaufman, Keith C. (Canton, OH); Sarv, Hamid (Canton, OH)

1998-01-01T23:59:59.000Z

10

Technology Innovations and Experience Curves for Nitrogen Oxides Control Technologies  

E-Print Network (OSTI)

red power plants. Nitrogen dioxide (NO 2 ) is one of the sixeffects, including nitrogen dioxide (NO 2 ) and ground-levelgradually oxidized to nitrogen dioxide (NO 2 ) once emitted

Yeh, Sonia; Rubin, Edward S.; Taylor, Margaret R.

2007-01-01T23:59:59.000Z

11

MINIMIZATION OF NO EMISSIONS FROM MULTI-BURNER COAL-FIRED BOILERS  

SciTech Connect

The focus of this program is to provide insight into the formation and minimization of NO{sub x} in multi-burner arrays, such as those that would be found in a typical utility boiler. Most detailed studies are performed in single-burner test facilities, and may not capture significant burner-to-burner interactions that could influence NO{sub x} emissions. Thus, investigations of such interactions were made by performing a combination of single and multiple burner experiments in a pilot-scale coal-fired test facility at the University of Utah, and by the use of computational combustion simulations to evaluate full-scale utility boilers. In addition, fundamental studies on nitrogen release from coal were performed to develop greater understanding of the physical processes that control NO formation in pulverized coal flames--particularly under low NO{sub x} conditions. A CO/H{sub 2}/O{sub 2}/N{sub 2} flame was operated under fuel-rich conditions in a flat flame reactor to provide a high temperature, oxygen-free post-flame environment to study secondary reactions of coal volatiles. Effects of temperature, residence time and coal rank on nitrogen evolution and soot formation were examined. Elemental compositions of the char, tar and soot were determined by elemental analysis, gas species distributions were determined using FTIR, and the chemical structure of the tar and soot was analyzed by solid-state {sup 13}C NMR spectroscopy. A laminar flow drop tube furnace was used to study char nitrogen conversion to NO. The experimental evidence and simulation results indicated that some of the nitrogen present in the char is converted to nitric oxide after direct attack of oxygen on the particle, while another portion of the nitrogen, present in more labile functionalities, is released as HCN and further reacts in the bulk gas. The reaction of HCN with NO in the bulk gas has a strong influence on the overall conversion of char-nitrogen to nitric oxide; therefore, any model that aims to predict the conversion of char-nitrogen to nitric oxide should allow for the conversion of char-nitrogen to HCN. The extent of the HCN conversion to NO or N{sub 2} will depend on the composition of the atmosphere surrounding the particle. A pilot-scale testing campaign was carried out to evaluate the impact of multiburner firing on NO{sub x} emissions using a three-burner vertical array. In general, the results indicated that multiburner firing yielded higher NO{sub x} emissions than single burner firing at the same fuel rate and excess air. Mismatched burner operation, due to increases in the firing rate of the middle burner, generally demonstrated an increase in NO{sub x} over uniform firing. Biased firing, operating the middle burner fuel rich with the upper and lower burners fuel lean, demonstrated an overall reduction in NO{sub x} emissions; particularly when the middle burner was operated highly fuel rich. Computational modeling indicated that operating the three burner array with the center burner swirl in a direction opposite to the other two resulted in a slight reduction in NO{sub x}.

E.G. Eddings; A. Molina; D.W. Pershing; A.F. Sarofim; T.H. Fletcher; H. Zhang; K.A. Davis; M. Denison; H. Shim

2002-01-01T23:59:59.000Z

12

EA-1472: Commercial Demonstration fo the Low Nox Burner/Separated Over-Fire  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

472: Commercial Demonstration fo the Low Nox Burner/Separated 472: Commercial Demonstration fo the Low Nox Burner/Separated Over-Fire Air (LNB/SOFA) Integration System Emission Reduction Technology, Holcolm Station, Sunflower Electric Power Corporation Finnety County, Kansas EA-1472: Commercial Demonstration fo the Low Nox Burner/Separated Over-Fire Air (LNB/SOFA) Integration System Emission Reduction Technology, Holcolm Station, Sunflower Electric Power Corporation Finnety County, Kansas SUMMARY The DOE has prepared an Environmental Assessment (EA), to analyze the potential impacts of the commercial application of the Low-NOx Burner/Separated Over-Fire Air (LNB/SOFA) integration system to achieve nitrogen oxide (NOx) emissions reduction at Sunflower's Holcomb Unit No. 1 (Holcomb Station), located near Garden City, in Finney County, Kansas.

13

Method and apparatus for nitrogen oxide determination  

DOE Patents (OSTI)

Method and apparatus for determining nitrogen oxide content in a high temperature process gas, which involves withdrawing a sample portion of a high temperature gas containing nitrogen oxide from a source to be analyzed. The sample portion is passed through a restrictive flow conduit, which may be a capillary or a restriction orifice. The restrictive flow conduit is heated to a temperature sufficient to maintain the flowing sample portion at an elevated temperature at least as great as the temperature of the high temperature gas source, to thereby provide that deposition of ammonium nitrate within the restrictive flow conduit cannot occur. The sample portion is then drawn into an aspirator device. A heated motive gas is passed to the aspirator device at a temperature at least as great as the temperature of the high temperature gas source. The motive gas is passed through the nozzle of the aspirator device under conditions sufficient to aspirate the heated sample portion through the restrictive flow conduit and produce a mixture of the sample portion in the motive gas at a dilution of the sample portion sufficient to provide that deposition of ammonium nitrate from the mixture cannot occur at reduced temperature. A portion of the cooled dilute mixture is then passed to analytical means capable of detecting nitric oxide.

Hohorst, Frederick A. (Idaho Falls, ID)

1990-01-01T23:59:59.000Z

14

Nitrogen oxides emission trends in Monthly emission estimates of nitrogen oxides from space provide  

E-Print Network (OSTI)

Chapter 5 Nitrogen oxides emission trends in East Asia Abstract Monthly emission estimates present first results of a new emission estimation algorithm, specifically designed to use daily satellite observations of column concentrations for fast updates of emission estimates of short-lived atmospheric

Haak, Hein

15

Numerical simulations for the coal/oxidant distribution effects between two-stages for multi opposite burners (MOB) gasifier  

Science Journals Connector (OSTI)

Abstract A 3D CFD model for two-stage entrained flow dry feed coal gasifier with multi opposite burners (MOB) has been developed in this paper. At each stage two opposite nozzles are impinging whereas the two other opposite nozzles are slightly tangential. Various numerical simulations were carried out in standard CFD software to investigate the impacts of coal and oxidant distributions between the two stages of the gasifier. Chemical process was described by Finite Rate/Eddy Dissipation model. Heterogeneous and homogeneous reactions were defined using the published kinetic data and realizable k–? turbulent model was used to solve the turbulence equations. Gas–solid interaction was defined by Euler–Lagrangian frame work. Different reaction mechanism were investigated first for the validation of the model from published experimental results. Then further investigations were made through the validated model for important parameters like species concentrations in syngas, char conversion, maximum inside temperature and syngas exit temperature. The analysis of the results from various simulated cases shows that coal/oxidant distribution between the stages has great influence on the overall performance of gasifier. The maximum char conversion was found 99.79% with coal 60% and oxygen 50% of upper level of injection. The minimum char conversion was observed 95.45% at 30% coal with 40% oxygen at same level. In general with oxygen and coal above or equal to 50% of total at upper injection level has shown an optimized performance.

Imran Nazir Unar; Lijun Wang; Abdul Ghani Pathan; Rasool Bux Mahar; Rundong Li; M. Aslam Uqaili

2014-01-01T23:59:59.000Z

16

Burners and combustion apparatus for carbon nanomaterial production  

DOE Patents (OSTI)

The invention provides improved burners, combustion apparatus, and methods for carbon nanomaterial production. The burners of the invention provide sooting flames of fuel and oxidizing gases. The condensable products of combustion produced by the burners of this invention produce carbon nanomaterials including without limitation, soot, fullerenic soot, and fullerenes. The burners of the invention do not require premixing of the fuel and oxidizing gases and are suitable for use with low vapor pressure fuels such as those containing substantial amounts of polyaromatic hydrocarbons. The burners of the invention can operate with a hot (e.g., uncooled) burner surface and require little, if any, cooling or other forms of heat sinking. The burners of the invention comprise one or more refractory elements forming the outlet of the burner at which a flame can be established. The burners of the invention provide for improved flame stability, can be employed with a wider range of fuel/oxidizer (e.g., air) ratios and a wider range of gas velocities, and are generally more efficient than burners using water-cooled metal burner plates. The burners of the invention can also be operated to reduce the formation of undesirable soot deposits on the burner and on surfaces downstream of the burner.

Alford, J. Michael (Lakewood, CO); Diener, Michael D. (Denver, CO); Nabity, James (Arvada, CO); Karpuk, Michael (Boulder, CO)

2007-10-09T23:59:59.000Z

17

Burners and combustion apparatus for carbon nanomaterial production  

DOE Patents (OSTI)

The invention provides improved burners, combustion apparatus, and methods for carbon nanomaterial production. The burners of the invention provide sooting flames of fuel and oxidizing gases. The condensable products of combustion produced by the burners of this invention produce carbon nanomaterials including without limitation, soot, fullerenic soot, and fullerenes. The burners of the invention do not require premixing of the fuel and oxidizing gases and are suitable for use with low vapor pressure fuels such as those containing substantial amounts of polyaromatic hydrocarbons. The burners of the invention can operate with a hot (e.g., uncooled) burner surface and require little, if any, cooling or other forms of heat sinking. The burners of the invention comprise one or more refractory elements forming the outlet of the burner at which a flame can be established. The burners of the invention provide for improved flame stability, can be employed with a wider range of fuel/oxidizer (e.g., air) ratios and a wider range of gas velocities, and are generally more efficient than burners using water-cooled metal burner plates. The burners of the invention can also be operated to reduce the formation of undesirable soot deposits on the burner and on surfaces downstream of the burner.

Alford, J. Michael; Diener, Michael D; Nabity, James; Karpuk, Michael

2013-02-05T23:59:59.000Z

18

Modeling of Nitrogen Oxides Emissions from CFB Combustion  

Science Journals Connector (OSTI)

In this work, a simplified description of combustion and nitrogen oxides chemistry was implemented in a 1.5D model framework with the aim to compare the results with ones earlier obtained with a detailed react...

S. Kallio; M. Keinonen

2010-01-01T23:59:59.000Z

19

Air Pollution Control Regulations: No.27 - Control of Nitrogen Oxide  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Air Pollution Control Regulations: No.27 - Control of Nitrogen Air Pollution Control Regulations: No.27 - Control of Nitrogen Oxide Emissions (Rhode Island) Air Pollution Control Regulations: No.27 - Control of Nitrogen Oxide Emissions (Rhode Island) < Back Eligibility Commercial Industrial Investor-Owned Utility Municipal/Public Utility Rural Electric Cooperative Utility Program Info State Rhode Island Program Type Environmental Regulations Provider Department of Environmental Management These regulations apply to stationary sources with the potential to emit 50 tons of nitrogen oxides (NOx) per year from all pollutant-emitting equipment or activities. The regulations describe possibilities for exemptions (i.e., for sources which have the potential to emit 50 tons but do not actually reach that level) and Reasonably Available Control

20

Nitrogen Oxide Emission Statements (Ohio) | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Nitrogen Oxide Emission Statements (Ohio) Nitrogen Oxide Emission Statements (Ohio) Nitrogen Oxide Emission Statements (Ohio) < Back Eligibility Agricultural Commercial Construction Fuel Distributor Industrial Investor-Owned Utility Municipal/Public Utility Rural Electric Cooperative Utility Program Info State Ohio Program Type Environmental Regulations Provider Ohio Environmental Protection Agency This chapter of the law establishes that the Ohio Environmental Protection Agency requires any facility that emits 25 tons or more of NOx and/or 25 tons or more of VOC during the calendar year and is located in a county designated as nonattainment for the National Ambient Air Quality Standards for ozone submit emission statements. Any facility that is located in a county described above is exempt from these requirements. If NOx

Note: This page contains sample records for the topic "nitrogen oxide burner" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Rotary Burner Demonstration  

SciTech Connect

The subject technology, the Calcpos Rotary Burner (CRB), is a burner that is proposed to reduce energy consumption and emission levels in comparison to currently available technology. burners are used throughout industry to produce the heat that is required during the refining process. Refineries seek to minimize the use of energy in refining while still meeting EPA regulations for emissions.

Paul Flanagan

2003-04-30T23:59:59.000Z

22

Cybersecurity Front Burner | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Awareness Program Cybersecurity Front Burner Cybersecurity Front Burner Documents Available for Download November 1, 2014 FRONT BURNER - ISSUE 19 The Cybersecurity Front Burner...

23

Silane-propane ignitor/burner  

DOE Patents (OSTI)

A silane propane burner for an underground coal gasification process which is used to ignite the coal and to controllably retract the injection point by cutting the injection pipe. A narrow tube with a burner tip is positioned in the injection pipe through which an oxidant (oxygen or air) is flowed. A charge of silane followed by a supply of fuel, such as propane, is flowed through the tube. The silane spontaneously ignites on contact with oxygen and burns the propane fuel.

Hill, R.W.; Skinner, D.F. Jr.; Thorsness, C.B.

1983-05-26T23:59:59.000Z

24

Silane-propane ignitor/burner  

DOE Patents (OSTI)

A silane propane burner for an underground coal gasification process which is used to ignite the coal and to controllably retract the injection point by cutting the injection pipe. A narrow tube with a burner tip is positioned in the injection pipe through which an oxidant (oxygen or air) is flowed. A charge of silane followed by a supply of fuel, such as propane, is flowed through the tube. The silane spontaneously ignites on contact with oxygen and burns the propane fuel.

Hill, Richard W. (Livermore, CA); Skinner, Dewey F. (Livermore, CA); Thorsness, Charles B. (Livermore, CA)

1985-01-01T23:59:59.000Z

25

Nitrogen doped zinc oxide thin film  

SciTech Connect

To summarize, polycrystalline ZnO thin films were grown by reactive sputtering. Nitrogen was introduced into the films by reactive sputtering in an NO{sub 2} plasma or by N{sup +} implantation. All ZnO films grown show n-type conductivity. In unintentionally doped ZnO films, the n-type conductivities are attributed to Zn{sub i}, a native shallow donor. In NO{sub 2}-grown ZnO films, the n-type conductivity is attributed to (N{sub 2}){sub O}, a shallow double donor. In NO{sub 2}-grown ZnO films, 0.3 atomic % nitrogen was found to exist in the form of N{sub 2}O and N{sub 2}. Upon annealing, N{sub 2}O decomposes into N{sub 2} and O{sub 2}. In furnace-annealed samples N{sub 2} redistributes diffusively and forms gaseous N{sub 2} bubbles in the films. Unintentionally doped ZnO films were grown at different oxygen partial pressures. Zni was found to form even at oxygen-rich condition and led to n-type conductivity. N{sup +} implantation into unintentionally doped ZnO film deteriorates the crystallinity and optical properties and leads to higher electron concentration. The free electrons in the implanted films are attributed to the defects introduced by implantation and formation of (N{sub 2}){sub O} and Zni. Although today there is still no reliable means to produce good quality, stable p-type ZnO material, ZnO remains an attractive material with potential for high performance short wavelength optoelectronic devices. One may argue that gallium nitride was in a similar situation a decade ago. Although we did not obtain any p-type conductivity, we hope our research will provide a valuable reference to the literature.

Li, Sonny X.

2003-12-15T23:59:59.000Z

26

Photochemical doping of graphene oxide with nitrogen for photoluminescence enhancement  

SciTech Connect

Nitrogen-doped graphene oxide (NGO) was synthesized by irradiation of graphene oxide (GO) in NH{sub 3} atmosphere. NGO obtained by irradiation of GO for 10 min has high N content of 13.62 at. %. The photoluminescence (PL) properties of NGO were investigated. The results showed that compared with GO, NGO exhibits significant PL enhancement with a high enhancement ratio of approximately 1501.57%. It may attribute to the high content of amino-like N, which can effectively enhance PL of GO because of the amino conjugation effect.

Liu, Fuchi [Physics Department and Nanjing National Laboratory of Microstructures, Nanjing University, Nanjing 210093 (China) [Physics Department and Nanjing National Laboratory of Microstructures, Nanjing University, Nanjing 210093 (China); College of Physics and Technology, Guangxi Normal University, Guilin 541004 (China); Tang, Nujiang; Tang, Tao; Liu, Yuan; Feng, Qian; Zhong, Wei; Du, Youwei [Physics Department and Nanjing National Laboratory of Microstructures, Nanjing University, Nanjing 210093 (China)] [Physics Department and Nanjing National Laboratory of Microstructures, Nanjing University, Nanjing 210093 (China)

2013-09-16T23:59:59.000Z

27

Biofilter for removal of nitrogen oxides from contaminated gases under aerobic conditions  

DOE Patents (OSTI)

A biofilter for reducing concentrations of gaseous nitrogen oxides in a polluted gas comprises a porous organic filter bed medium disposed in a housing, the filter bed medium including a mixed culture of naturally occurring denitrifying bacteria for converting the nitrogen oxides to nitrogen gas, carbon dioxide, and water. A method of reducing concentrations of nitrogen oxides in polluted gas comprises conducting the polluted gas through the biofilter so that the denitrifying bacteria can degrade the nitrogen oxides. A preferred filter medium is wood compost, however composts of other organic materials are functional. Regulation of pH, moisture content, exogenous carbon sources, and temperature are described.

Apel, William A. (Idaho Falls, ID)

1998-01-01T23:59:59.000Z

28

Assessment of soil nitrogen oxides emissions and implementation in LOTOS-EUROS  

E-Print Network (OSTI)

the formation and transport of nitrogen dioxide, ozone, particulate matter and other species throughout EuropeAssessment of soil nitrogen oxides emissions and implementation in LOTOS-EUROS Date 18 March 2013, climate and nitrogen availability. Nitrogen availability is in turn determined by N-deposition from

Haak, Hein

29

NETL: News Release - Commercial Sales of Low-Polluting Clean Coal Burner  

NLE Websites -- All DOE Office Websites (Extended Search)

March 14, 2001 March 14, 2001 Commercial Sales of Low-Polluting Clean Coal Burner Top $1 Billion Abraham Says Commercial Success Shows Benefits of Clean Coal Investment WASHINGTON, DC - An advanced, low-polluting coal combustor is rapidly becoming one of the government's fastest growing clean coal technology success stories. The U.S. Department of Energy today announced that sales of the "low-NOx concentric firing system" (LNCFS?), first pioneered in 1992-92 as part of the federal Clean Coal Technology Program, now top $1 billion. Results show the system is reducing nitrogen oxides, NOx, by nearly 40 percent in older coal burning plants. NOx is one of the air pollutants that contributes to smog, ground-level ozone, and acid rain. According to data compiled by the Energy Department's National Energy Technology Laboratory, 56,000 megawatts of electricity are now being generated in the United States by power plants equipped with the high-tech burner.

30

Method for reducing nitrogen oxides in combustion effluents  

DOE Patents (OSTI)

Method for reducing nitrogen oxides (NO.sub.x) in the gas stream from the combustion of fossil fuels is disclosed. In a narrow gas temperature zone, NO.sub.x is converted to nitrogen by reaction with urea or ammonia with negligible remaining ammonia and other reaction pollutants. Specially designed injectors are used to introduce air atomized water droplets containing dissolved urea or ammonia into the gaseous combustion products in a manner that widely disperses the droplets exclusively in the optimum reaction temperature zone. The injector operates in a manner that forms droplet of a size that results in their vaporization exclusively in this optimum NO.sub.x -urea/ammonia reaction temperature zone. Also disclosed is a design of a system to effectively accomplish this injection.

Zauderer, Bert (Merion Station, PA)

2000-01-01T23:59:59.000Z

31

EFFECT OF NITROGEN OXIDE PRETREATMENTS ON ENZYMATIC HYDROLYSIS OF CELLULOSE  

E-Print Network (OSTI)

oxygen react to give nitrogen dioxide, which rapidly reactsis simultaneous, the nitrogen dioxide formed reacts withaccomplished by absorbing nitrogen dioxide in water, usually

Borrevik, R.K.

2011-01-01T23:59:59.000Z

32

Method for combined removal of mercury and nitrogen oxides from off-gas streams  

DOE Patents (OSTI)

A method for removing elemental Hg and nitric oxide simultaneously from a gas stream is provided whereby the gas stream is reacted with gaseous chlorinated compound to convert the elemental mercury to soluble mercury compounds and the nitric oxide to nitrogen dioxide. The method works to remove either mercury or nitrogen oxide in the absence or presence of each other.

Mendelsohn, Marshall H. (Downers Grove, IL); Livengood, C. David (Lockport, IL)

2006-10-10T23:59:59.000Z

33

Nitrogen oxide emissions from a kraft recovery furnace  

SciTech Connect

Nitrogen Oxide (NOx) emissions from a rebuilt kraft recovery furnace slightly exceeded the specified limit of 1.1 lb/ton (0.55 kg/metric ton) of black-liquor solids. Mill trials were undertaken to determine whether NOx emissions could be minimized by modifying furnace operation. NOx emissions increased when secondary air was shifted to tertiary ports. NOx emissions fell when the amounts of primary and total air were decreased, but this increased emissions of other pollutants. After demonstrating that best operation of the furnace could not meet the permit with an emissions limit that matched the furnace's performance at best operation.

Prouty, A.L.; Stuart, R.C. (James River Corp., Camas, WA (United States)); Caron, A.L. (NCASI West Coast Regional Office, Corvallis, OR (United States))

1993-01-01T23:59:59.000Z

34

Production of ozone and nitrogen oxides by laser filamentation  

SciTech Connect

We have experimentally measured that laser filaments in air generate up to 10{sup 14}, 3x10{sup 12}, and 3x10{sup 13} molecules of O{sub 3}, NO, and NO{sub 2}, respectively. The corresponding local concentrations in the filament active volume are 10{sup 16}, 3x10{sup 14}, and 3x10{sup 15} cm{sup -3}, and allows efficient oxidative chemistry of nitrogen, resulting in concentrations of HNO{sub 3} in the parts per million range. The latter forming binary clusters with water, our results provide a plausible pathway for the efficient nucleation recently observed in laser filaments.

Petit, Yannick; Henin, Stefano; Kasparian, Jerome; Wolf, Jean-Pierre [GAP Biophotonics, Universite de Geneve, 20 rue de l'Ecole de Medecine, CH1211 Geneve 4 (Switzerland)

2010-07-12T23:59:59.000Z

35

Reduction of nitrogen oxides in diesel exhaust: Prospects for use of synthesis gas  

Science Journals Connector (OSTI)

Already commercialized and some of the most promising technologies of nitrogen oxide reduction in automotive diesel exhaust are compared. The Boreskov Institute of Catalysis... x ...

V. A. Kirillov; E. I. Smirnov; Yu. I. Amosov; A. S. Bobrin…

2009-01-01T23:59:59.000Z

36

Burner control system  

SciTech Connect

A burner control apparatus for use with a furnace installation that has an operating control to produce a request for burner operation, a flame sensor to produce a signal when flame is present in the monitored combustion chamber, and one or more devices for control of ignition and/or fuel flow. The burner control apparatus comprises lockout apparatus for de-energizing the control apparatus, a control device for actuating the ignition and/or fuel control devices, and a timing circuit that provides four successive and partially overlapping timing intervals of precise relation, including a purge timing interval, a pilot ignition interval, and a main fuel ignition interval. The present invention further includes a burner control system which verifies the proper operation of certain sensors in a burner or furnace including particularly the air flow sensor. Additionally, the present system also prevents an attempt to ignite a burner if a condition is detected which indicates that the air flow sensor has been bypassed or wedged in the actuated position.

Cade, P.J.

1981-01-06T23:59:59.000Z

37

Reduction of nitrogen oxides with catalytic acid resistant aluminosilicate molecular sieves and ammonia  

DOE Patents (OSTI)

Noxious nitrogen oxides in a waste gas stream such as the stack gas from a fossil-fuel-fired power generation plant or other industrial plant off-gas stream is catalytically reduced to elemental nitrogen and/or innocuous nitrogen oxides employing ammonia as reductant in the presence of a zeolite catalyst in the hydrogen or sodium form having pore openings of about 3 to 10 A.

Pence, Dallas T. (Idaho Falls, ID); Thomas, Thomas R. (Idaho Falls, ID)

1980-01-01T23:59:59.000Z

38

Nitrogen Oxides (NOx), Why and How They are Controlled  

NLE Websites -- All DOE Office Websites (Extended Search)

Air Quality EPA 456/F-99-006R Air Quality EPA 456/F-99-006R Environmental Protection Planning and Standards November 1999 Agency Research Triangle Park, NC 27711 Air EPA-456/F-99-006R November 1999 Nitrogen Oxides (NOx), Why and How They Are Controlled Prepared by Clean Air Technology Center (MD-12) Information Transfer and Program Integration Division Office of Air Quality Planning and Standards U.S. Environmental Protection Agency Research Triangle Park, North Carolina 27711 ii DISCLAIMER This report has been reviewed by the Information Transfer and Program Integration Division of the Office of Air Quality Planning and Standards, U.S. Environmental Protection Agency and approved for publication. Approval does not signify that the contents of this report reflect the views and policies of the U.S. Environmental Protection Agency. Mention of trade

39

Technology innovations and experience curves for nitrogen oxides control technologies  

SciTech Connect

This paper reviews the regulatory history for nitrogen oxides (NOx) pollutant emissions from stationary sources, primarily in coal-fired power plants. Nitrogen dioxide (NO{sub 2}) is one of the six criteria pollutants regulated by the 1970 Clean Air Act where National Ambient Air Quality Standards were established to protect public health and welfare. Patent data are used to show that in the cases of Japan, Germany, and the United States, innovations in NOx control technologies did not occur until stringent government regulations were in place, thus 'forcing' innovation. It is demonstrated that reductions in the capital and operation and maintenance (O&M) costs of new generations of high-efficiency NOx control technologies, selective catalytic reduction (SCR), are consistently associated with the increasing adoption of the control technology: the so-called learning-by-doing phenomena. The results show that as cumulative world coal-fired SCR capacity doubles, capital costs decline to {approximately} 86% and O&M costs to 58% of their original values. The observed changes in SCR technology reflect the impact of technological advance as well as other factors, such as market competition and economies of scale. 38 refs., 10 figs., 3 tabs.

Sonia Yeh; Edward S. Rubin; Margaret R. Taylor; David A. Hounshell [U.S. Environmental Protection Agency, Research Triangle Park, NC (United States). National Risk Management Research Laboratory, Office of Research and Development,

2005-12-15T23:59:59.000Z

40

Downhole burner systems and methods for heating subsurface formations  

DOE Patents (OSTI)

A gas burner assembly for heating a subsurface formation includes an oxidant conduit, a fuel conduit, and a plurality of oxidizers coupled to the oxidant conduit. At least one of the oxidizers includes a mix chamber for mixing fuel from the fuel conduit with oxidant from the oxidant conduit, an igniter, and a shield. The shield includes a plurality of openings in communication with the oxidant conduit. At least one flame stabilizer is coupled to the shield.

Farmayan, Walter Farman (Houston, TX); Giles, Steven Paul (Damon, TX); Brignac, Jr., Joseph Phillip (Katy, TX); Munshi, Abdul Wahid (Houston, TX); Abbasi, Faraz (Sugarland, TX); Clomburg, Lloyd Anthony (Houston, TX); Anderson, Karl Gregory (Missouri City, TX); Tsai, Kuochen (Katy, TX); Siddoway, Mark Alan (Katy, TX)

2011-05-31T23:59:59.000Z

Note: This page contains sample records for the topic "nitrogen oxide burner" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Chromatographic Determination of Total Nitrogen Following the Kjeldahl Oxidation  

Science Journals Connector (OSTI)

......23745 (1986). 3. B.M. Jones, and C.G. Daughton. Chemiluminescence vs. Kjeldahl determination of nitrogen in oil shale retort waters and organo- nitrogen compounds. Anal. Chem. 57: 232025 (1985). 4. B.T. Croll, T. Tomlinson......

Serban Moldoveanu

1988-01-01T23:59:59.000Z

42

Method for Detection of Microorganisms That Produce Gaseous Nitrogen Oxides  

Science Journals Connector (OSTI)

...with 02-free nitrogen; the tubes were...dishes to reduce water evaporation...Detection of gas producers. Culture...conductivity detector; nitrogen was used as the...Low-pressure solubility of gases in liquid water. Chem. Rev...

Gary E. Jenneman; Anne D. Montgomery; Michael J. McInerney

1986-04-01T23:59:59.000Z

43

Methods of reducing emissions of nitrogen oxides at thermal power plants burning solid domestic waste  

Science Journals Connector (OSTI)

Essentially all the major methods of reducing the emissions of nitrogen oxides from flue gases employed in power generation have been tested on plants in Moscow which burn solid domestic waste for production of h...

A. N. Tugov; V. F. Moskvichev

2009-01-01T23:59:59.000Z

44

Calculation of the emission of nitrogen oxides in electric resistance heating furnaces  

Science Journals Connector (OSTI)

The present paper is devoted to the least studied topic in the field of use of modern electric heating equipment, namely, pollution of the atmosphere by nitrogen oxides and reduction of the intensity of this e...

A. V. Aksenov; V. A. Belyakov; Z. G. Sadykova

1998-02-01T23:59:59.000Z

45

FRONT BURNER - ISSUE 19 | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

FRONT BURNER - ISSUE 19 FRONT BURNER - ISSUE 19 The Cybersecurity Front Burner Issue No. 19 is the campaign newsletter for the 2014 DOE NCSAM event. The newsletter addresses the...

46

Front Burner - Issue 18 | Department of Energy  

Energy Savers (EERE)

Front Burner - Issue 18 Front Burner - Issue 18 The Cybersecurity Front Burner Issue No. 18 addresses keeping kids safe on the Internet, cyber crime, and DOE Cyber awareness and...

47

Front Burner - Issue 13 | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

3 Front Burner - Issue 13 The Cybersecurity Front Burner Issue No. 13 contained a message from the Associate Chief Information Officer (ACIO) for Cybersecurity informing readers...

48

Front Burner - Issue 14 | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

4 Front Burner - Issue 14 The Cybersecurity Front Burner Issue No. 14 addresses the 2013 National Cybersecurity Awareness Month (NCSAM) Campaign and Phishing Scams. Cybersecurity...

49

Oil burner nozzle  

DOE Patents (OSTI)

An oil burner nozzle for use with liquid fuels and solid-containing liquid fuels. The nozzle comprises a fuel-carrying pipe, a barrel concentrically disposed about the pipe, and an outer sleeve retaining member for the barrel. An atomizing vapor passes along an axial passageway in the barrel, through a bore in the barrel and then along the outer surface of the front portion of the barrel. The atomizing vapor is directed by the outer sleeve across the path of the fuel as it emerges from the barrel. The fuel is atomized and may then be ignited.

Wright, Donald G. (Rockville Center, NY)

1982-01-01T23:59:59.000Z

50

Burner balancing Salem Harbor Station  

SciTech Connect

The traditional method of burner balancing is first to determine the fuel distribution, then to measure the economizer outlet excess oxygen distribution and to adjust the burners accordingly. Fuel distribution is typically measured by clean and dirty air probing. Coal pipe flow can then be adjusted, if necessary, through the use of coal pipe orificing or by other means. Primary air flow must be adjusted to meet the design criteria of the burner. Once coal pipe flow is balanced to within the desired criteria, secondary air flow to individual burners can be changed by adjusting windbox dampers, burner registers, shrouds or other devices in the secondary air stream. This paper discusses problems encountered in measuring excess O{sub 2} at the economizer outlet. It is important to recognize that O{sub 2} measurements at the economizer outlet, by themselves, can be very misleading. If measurement problems are suspected or encountered, an alternate approach similar to that described should be considered. The alternate method is not only useful for burner balancing but also can be used to help in calibrating the plant excess O{sub 2} instruments and provide an on line means of cross-checking excess air measurements. Balanced burners operate closer to their design stoichiometry, providing better NO{sub x} reduction. For Salem Harbor Station, this means a significant saving in urea consumption.

Sload, A.W. [New England Power Co., Salem, MA (United States); Dube, R.J. [DB Riley, Inc., Worcester, MA (United States). Fuel Equipment Design

1995-12-31T23:59:59.000Z

51

Energy cost improvement of the nitrogen oxides synthesis in a low pressure plasma  

E-Print Network (OSTI)

of XIXth century, the synthesis of nitrogen oxides by an electric discharge through the air has been a microwave discharge. The total pressure is equal to 50 torr. The optimal value of energy consumption, equal with the industrial process used at present, and by 78 % in comparison with those obtained with a plasmajet arc

Paris-Sud XI, Université de

52

Nitrogen oxides reduction by staged combustion of LCV gas  

E-Print Network (OSTI)

to the high nitrogen content (1-2%) of the agricultural wastes, burning of the LCV gas derived from them can result in NO?emissions in excess of 2000 ppm. NO?emissions during combustion of LCV gas derived from gasification of cotton gin trash have been.... Wayne A. LePori for serving on my committee and for the advice and time he offer me. His experience on gasification and combustion of LCV gas was an invaluable source. I appreciate Dr. Mario A. Colaluca for serving on my committee and for his help...

Cabrera Sixto, Jose Manuel

2012-06-07T23:59:59.000Z

53

Burner ignition system  

DOE Patents (OSTI)

An electronic ignition system for a gas burner is battery operated. The battery voltage is applied through a DC-DC chopper to a step-up transformer to charge a capacitor which provides the ignition spark. The step-up transformer has a significant leakage reactance in order to limit current flow from the battery during initial charging of the capacitor. A tank circuit at the input of the transformer returns magnetizing current resulting from the leakage reactance to the primary in succeeding cycles. An SCR in the output circuit is gated through a voltage divider which senses current flow through a flame. Once the flame is sensed, further sparks are precluded. The same flame sensor enables a thermopile driven main valve actuating circuit. A safety valve in series with the main gas valve responds to a control pressure thermostatically applied through a diaphragm. The valve closes after a predetermined delay determined by a time delay orifice if the pilot gas is not ignited.

Carignan, Forest J. (Bedford, MA)

1986-01-21T23:59:59.000Z

54

Criterion for burner design in thermal weed control  

E-Print Network (OSTI)

A covered infrared burner was designed and constructed so that it could be compared to an open-flame burner. Two covered burners, a high configuration and a low configuration, were constructed. A low configuration covered infrared burner, high...

Gonzalez, Telca Marisa

2001-01-01T23:59:59.000Z

55

Tunneling oxide engineering by ion implantation of nitrogen for 3D vertical silicon pillar SONOS flash memory  

Science Journals Connector (OSTI)

The electrical characteristics of silicon-oxide-nitride-oxide-silicon (SONOS) flash memory with a 3D vertical silicon pillar structure were studied. As an alternative method for the formation of the tunneling oxide, nitrogen ion implantation was applied to thermally grown pure silicon dioxide with a low energy (5 keV). The devices show significant improvement in the erase characteristics compared to conventional tunneling oxide. Secondary ion mass spectrometry was used to analyze the nitrogen distribution within tunnel oxide, and the improved erase properties can be attributed to the incorporation of about 4.8% nitrogen (2 × 1021 atoms/cm3) into the tunnel oxide formed by nitrogen ion implantation.

Jae-Sub Oh; Seong-Dong Yang; Sang-Youl Lee; Young-Su Kim; Min-Ho Kang; Sung-Kyu Lim; Hi-Deok Lee; Ga-Won Lee

2013-01-01T23:59:59.000Z

56

Oxidation of heterocyclic nitrogen yields to nitroheterocycles. [Nitrofurazans  

SciTech Connect

In the process of finding new routes to synthesize nitrofurazans the investigators compared the oxidation of a sulfilimide and a phosphine imine derived from 3-amino-4-(chlorophenyl)furazan (1). The sulfilimine, 3-(4-chlorophenyl)-4-dimethyl-sulfiliminofurazan (2), was prepared by treating 1 with dimethyl sulfide ditriflate. Oxidation of 1 with peroxytrifluoroacetic acid (ptfa) in dichloromethane gave a mixture that was chromatographed to give 3-(4-chlorophenyl)-4- nitro-furazan (5) in 11% yield and azoxy(4-chlorophenylfurazan) (6) in 32% yield. Under the same conditions, 2 gave a 96% yield of 5 with no trace of 6. Oxidation of diaminofurazan (7) with ptfa gives 3-amino-4-nitrofurazan (8), which was converted to the sulfilimine. Treatment of the sulfilimine with anhydrous ptfa in dichloromethane gave a solution that contained dimethyl sulfone according to /sup 13/C-NMR analysis, but no nitrocarbon could be detected. However, the /sup 14/N-NMR spectrum contained a very sharp singlet with a width at half-height of 19 Hz and a chemical shift almost identical to that of 5. Thus, it appears that we may have formed dinitrofurazan in solution, but we have not been able to isolate it in pure form as yet. 10 refs., 4 figs.

Coburn, M.D.

1985-01-01T23:59:59.000Z

57

Front Burner - Issue 16 | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

6 Front Burner - Issue 16 The Cybersecurity Front Burner Issue No. 16 addresses Malware, the Worst Passwords of 2013, and the Flat Stanley and Stop.Think.Connect. Campaign....

58

Pollutant exposures from unvented gas cooking burners: A simulation-based  

NLE Websites -- All DOE Office Websites (Extended Search)

Pollutant exposures from unvented gas cooking burners: A simulation-based Pollutant exposures from unvented gas cooking burners: A simulation-based assessment for Southern California Title Pollutant exposures from unvented gas cooking burners: A simulation-based assessment for Southern California Publication Type Journal Article Year of Publication 2013 Authors Logue, Jennifer M., Neil E. Klepeis, Agnes B. Lobscheid, and Brett C. Singer Journal Environmental Health Perspectives Date Published 11/2013 Abstract Background: Residential natural gas cooking burners (NGCBs) can emit substantial quantities of pollutants and they are typically used without venting. Objective: Quantify pollutant concentrations and occupant exposures resulting from NGCB use in California homes. Methods: A mass balance model was applied to estimate time-dependent pollutant concentrations throughout homes and the "exposure concentrations" experienced by individual occupants. The model was applied to estimate nitrogen dioxide (NO2), carbon monoxide (CO), and formaldehyde (HCHO) concentrations for one week each in summer and winter for a representative sample of Southern California homes. The model simulated pollutant emissions from NGCBs, NO2 and CO entry from outdoors, dilution throughout the home, and removal by ventilation and deposition. Residence characteristics and outdoor concentrations of CO and NO2 were obtained from available databases. Ventilation rates, occupancy patterns, and burner use were inferred from household characteristics. Proximity to the burner(s) and the benefits of using venting range hoods were also explored. Replicate model executions using independently generated sets of stochastic variable values yielded estimated pollutant concentration distributions with geometric means varying less than 10%.

59

Uniform-burning matrix burner  

DOE Patents (OSTI)

Computer simulation was used in the development of an inward-burning, radial matrix gas burner and heat pipe heat exchanger. The burner and exchanger can be used to heat a Stirling engine on cloudy days when a solar dish, the normal source of heat, cannot be used. Geometrical requirements of the application forced the use of the inward burning approach, which presents difficulty in achieving a good flow distribution and air/fuel mixing. The present invention solved the problem by providing a plenum with just the right properties, which include good flow distribution and good air/fuel mixing with minimum residence time. CFD simulations were also used to help design the primary heat exchanger needed for this application which includes a plurality of pins emanating from the heat pipe. The system uses multiple inlet ports, an extended distance from the fuel inlet to the burner matrix, flow divider vanes, and a ring-shaped, porous grid to obtain a high-temperature uniform-heat radial burner. Ideal applications include dish/Stirling engines, steam reforming of hydrocarbons, glass working, and any process requiring high temperature heating of the outside surface of a cylindrical surface.

Bohn, Mark S. (Golden, CO); Anselmo, Mark (Arvada, CO)

2001-01-01T23:59:59.000Z

60

Spatial and diurnal variability in reactive nitrogen oxide chemistry as reflected in the isotopic composition of atmospheric nitrate  

E-Print Network (OSTI)

exchange between gas-phase precursors and variability in reactive nitrogen sources. These findings product of NOx in the atmosphere. Due to its exceptionally high solubility in water, nitrate is rapidly deSpatial and diurnal variability in reactive nitrogen oxide chemistry as reflected in the isotopic

Note: This page contains sample records for the topic "nitrogen oxide burner" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

DOE/EA-1472: Finding of No Significant Impact for the Commercial Demonstration of the Low NOx Burner/Separated Over-Fire Air Integration System Emission Reduction Technology (03/11/03)  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

IMPACT IMPACT COMMERCIAL DEMONSRATION OF THE LOW NOx BURNER/SEPARATED OVER- FIRE AIR (LNB/SOFA) INTEGRATON SYSTEM EMISSION REDUCTION TECHNOLOGY HOLCOMB STATION SUNFLOWER ELECTRIC POWER CORPORATION FINNEY COUNTY, KANSAS AGENCY: U.S. Department of Energy (DOE) ACTION: Finding of No Significant Impact (FONSI) SUMMARY: The DOE has prepared an Environmental Assessment (EA), to analyze the potential impacts of the commercial application of the Low-NOx Burner/Separated Over-Fire Air (LNB/SOFA) integration system to achieve nitrogen oxide (NOx) emissions reduction at Sunflower's Holcomb Unit No. 1 (Holcomb Station), located near Garden City, in Finney County, Kansas. The Holcomb Station would be modified in three distinct phases to demonstrate the synergistic effect of layering NO,

62

3D Matrix Burners: A Method for Small-Scale Syngas Production  

Science Journals Connector (OSTI)

3D Matrix Burners: A Method for Small-Scale Syngas Production ... After passing the mixer, a homogeneous fuel–oxidizer mixture of specified composition is fed through permeable walls and bottom of the 3D matrix burner into its inner cavity, where it burns near the surface. ... However, as is well-known from methane combustion studies,(12) the normal burning velocity decreases with increasing pressure, for both rich and lean methane–air mixtures. ...

Vladimir S. Arutyunov; Vladimir M. Shmelev; Ayan N. Rakhmetov; Oksana V. Shapovalova

2013-11-18T23:59:59.000Z

63

Combustion method for simultaneous control of nitrogen oxides and products of incomplete combustion  

SciTech Connect

A method is described for combusting material with controlled generation of both nitrogen oxides and products of incomplete combustion comprising: (A) combusting material in a first combustion zone to produce gaseous exhaust containing products of incomplete combustion and products of complete combustion; (B) passing the gaseous exhaust from the first combustion zone into a second combustion zone having a width and an axial direction; (C) injecting through a lance with an orientation substantially parallel to said axial direction at least one stream of oxidant, without fuel, having a diameter less than 1/100 of the width of the second combustion zone and having an oxygen concentration of at least 30% into the second combustion zone at a high velocity of at least 300 feet per second; (D) aspirating products of incomplete combustion into the high velocity oxidant; (E) combusting products of incomplete combustion aspirated into the high velocity oxidant with high velocity oxidant within the second combustion zone to carry out a stable combustion by the mixing of the aspirated products of incomplete combustion with the high velocity oxidant; and (F) spreading out the combustion reaction by aspiration of products of complete combustion into the oxidant, said products of complete combustion also serving as a heat sink, to inhibit NO[sub x] formation.

Ho, Min-Da.

1993-05-25T23:59:59.000Z

64

KINETICS OF OXIDATION OF AQUEOUS SULFUR(IV) BY NITROGEN DIOXIDE YIN-NAN LEE AND STEPHEN E. SCHWARTZ  

E-Print Network (OSTI)

, reagent gas solubilities, mass trans- fer, stoichiometry, and reaction rate were not systematicallyKINETICS OF OXIDATION OF AQUEOUS SULFUR(IV) BY NITROGEN DIOXIDE YIN-NAN LEE AND STEPHEN E. SCHWARTZ for the oxidation of these compounds and their incorpo- ration into atmospheric liquid water are not fully

Schwartz, Stephen E.

65

Direct deposition of aluminum oxide gate dielectric on graphene channel using nitrogen plasma treatment  

SciTech Connect

Deposition of high-quality dielectric on a graphene channel is an essential technology to overcome structural constraints for the development of nano-electronic devices. In this study, we investigated a method for directly depositing aluminum oxide (Al{sub 2}O{sub 3}) on a graphene channel through nitrogen plasma treatment. The deposited Al{sub 2}O{sub 3} thin film on graphene demonstrated excellent dielectric properties with negligible charge trapping and de-trapping in the gate insulator. A top-gate-structural graphene transistor was fabricated using Al{sub 2}O{sub 3} as the gate dielectric with nitrogen plasma treatment on graphene channel region, and exhibited p-type transistor characteristics.

Lim, Taekyung; Kim, Dongchool; Ju, Sanghyun [Department of Physics, Kyonggi University, Suwon, Gyeonggi-Do 443-760 (Korea, Republic of)

2013-07-01T23:59:59.000Z

66

Chlorine activation indoors and outdoors via surface-mediated reactions of nitrogen oxides with hydrogen chloride.  

E-Print Network (OSTI)

complexes between nitrogen dioxide, nitric acid, nitrous1992) Indoor ozone and nitrogen dioxide: A potential pathwaybed of SiO 2 pellets. Nitrogen dioxide is introduced from a

2009-01-01T23:59:59.000Z

67

Air Quality Responses to Changes in Black Carbon and Nitrogen Oxide Emissions  

E-Print Network (OSTI)

D. , (2008a). Carbonyl and nitrogen dioxide emissions fromstudy of indoor nitrogen dioxide levels and respiratoryand modeled nitrogen dioxide (NO 2 ) concentrations. All

Millstein, Dev

2009-01-01T23:59:59.000Z

68

Experimental Study on the Basic Phenomena of Flame Stabilization Mechanism in a Porous Burner for Premixed Combustion Application  

Science Journals Connector (OSTI)

This was the driving force for investigation of porous burner application in exothermic thermal partial oxidation (POX) for production of syngas feed for MCFCs (Molten Carbonate Fuel Cells) and SOFCs (Solid Oxide Fuel Cells)(13) or for combustion of low calorific gases from landfills and waste pyrolysis. ... Although, due to the different maximal operational temperatures of the sponges it was not possible to perform all the investigations for the same set of conditions, a comparison between different burners can be made for the overlapping areas of the stable burning regions. ... Porous burners for lean-burn applications ...

Neda Djordjevic; Peter Habisreuther; Nikolaos Zarzalis

2012-10-18T23:59:59.000Z

69

Nitrogen oxide  

E-Print Network (OSTI)

quality regulations may not effectively target a large source of fine, organic particle pollutants that contribute to hazy skies and poor air quality over the Los Angeles region. See also:

Tropospheric Ozone

70

Low-Emissions Burner Technology using Biomass-Derived Liquid...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Emissions Burner Technology using Biomass-Derived Liquid Fuels Low-Emissions Burner Technology using Biomass-Derived Liquid Fuels This factsheet describes a project that developed...

71

Combined Heat and Power (CHP) Integrated with Burners for Packaged...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Combined Heat and Power (CHP) Integrated with Burners for Packaged Boilers Combined Heat and Power (CHP) Integrated with Burners for Packaged Boilers Providing Clean, Low-Cost,...

72

SEP Success Story: Biomass Burner Cogenerates Jobs and Electricity...  

Office of Environmental Management (EM)

SEP Success Story: Biomass Burner Cogenerates Jobs and Electricity from Lumber Mill Waste SEP Success Story: Biomass Burner Cogenerates Jobs and Electricity from Lumber Mill Waste...

73

Field emission effects of nitrogenated carbon nanotubes on chlorination and oxidation  

SciTech Connect

With reference to our recent reports [Appl. Phys. Lett. 90, 192107 (2007); Appl. Phys. Lett. 91, 202102 (2007)] about the electronic structure of chlorine treated and oxygen-plasma treated nitrogenated carbon nanotubes (N-CNTs), here we studied the electron field emission effects on chlorination (N-CNT:Cl) and oxidation (N-CNT:O) of N-CNT. A high current density (J) of 15.0 mA/cm{sup 2} has been achieved on chlorination, whereas low J of 0.0052 mA/cm{sup 2} is observed on oxidation compared to J=1.3 mA/cm{sup 2} for untreated N-CNT at an applied electric field E{sub A} of {approx}1.9 V/{mu}m. The turn-on electric field (E{sub TO}) was {approx}0.875. The 1.25 V/{mu}m was achieved for N-CNT:Cl and N-CNT:O, respectively, with respect to E{sub TO}=1.0 V/{mu}m for untreated one. These findings are due to the formation of different bonds with carbon and nitrogen in the N-CNT during the process of chlorine (oxygen)-plasma treatment by the charge transfer, or else that changes the density of free charge carriers and hence enhances (reduces) the field emission properties of N-CNTs:Cl (N-CNTs:O)

Ray, S. C.; Palnitkar, U.; Pao, C. W.; Tsai, H. M.; Pong, W. F.; Lin, I-N. [Department of Physics, Tamkang University, Tamsui 251, Taiwan (China); Papakonstantinou, P. [NRI, School of Electrical and Mechanical Engineering, University of Ulster at Jordanstown, Newtownabbey, County Antrim BT37OQB, Northern Ireland (United Kingdom); Ganguly, Abhijit; Chen, L. C. [Center for Condensed Matter Sciences, National Taiwan University, Taipei 106, Taiwan (China); Chen, K. H. [Institute of Atomic and Molecular Sciences, Academia Sinica, Taipei 106, Taiwan (China)

2008-09-15T23:59:59.000Z

74

DEVELOPMENT OF IMPROVED CATALYSTS FOR THE SELECTIVE CATALYTIC REDUCTION OF NITROGEN OXIDES WITH HYDROCARBONS  

SciTech Connect

Significant work has been done by the investigators on the cerium oxide-copper oxide based sorbent/catalysts for the combined removal of sulfur and nitrogen oxides from the flue gases of stationary sources. A relatively wide temperature window was established for the use of alumina-supported cerium oxide-copper oxide mixtures as regenerable sorbents for SO{sub 2} removal. Preliminary evaluation of these sorbents as catalysts for the selective reduction of NO{sub x} gave promising results with ammonia, but indicated low selectivity when methane was used as the reductant. Since the replacement of ammonia by another reductant is commercially very attractive, in this project, four research components will be undertaken. The investigation of the reaction mechanism, the first component, will help in the selection of promoters to improve the catalytic activity and selectivity of the sorbents in the SCR with methane. This will result in new catalyst formulations (second component). If this research is successful, the combined SO{sub 2}-NO{sub x} removal process based on alumina-supported copper oxide-ceria sorbent/catalysts will become very attractive for commercial applications. The objective of the third component of the project is to develop an alternative SCR process using another inexpensive fuel, residual fuel oil, instead of natural gas. This innovative proposal is based on very scant evidence concerning the good performance of coked catalysts in the selective reduction of NO and if proven to work the process will certainly be commercially viable. The fourth component of the project involves our industrial partner TDA Research, and the objective is to evaluate long-term stability and durability of the prepared sorbent/catalysts. In the first year of the project, the catalysts were investigated by the temperature-programmed reduction (TPR) technique. The results from TPR indicated that the interaction with support appears to promote reduction at lower temperatures. Copper oxide in excess of monolayer coverage reduces at temperatures close to the reduction temperature of the unsupported copper oxide. Increased dispersion increases the support effect. Low activity of ceria in NO reduction may be due to its resistance to reduction at low temperatures.

Dr. Ates Akyurtlu; Dr. Jale F. Akyurtlu

2001-05-31T23:59:59.000Z

75

Eddy-covariance observations of the atmosphere-biosphere exchange of nitrogen oxides  

E-Print Network (OSTI)

and Kesselmeier, J. : Nitrogen dioxide (NO 2 ) uptake byM. : Leaf uptake of nitrogen dioxide (NO 2 ) in a tropicalMorikawa, H. : Atmospheric nitrogen dioxide gas is a plant

Min, Kyung-Eun

2012-01-01T23:59:59.000Z

76

Innovative Clean Coal Technology (ICCT): 500 MW demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from coal-fired boilers. Technical progress report, fourth quarter 1991  

SciTech Connect

This quarterly report discusses the technical progress of an Innovative Clean Coal Technology (ICCT) demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from coal-fired boilers. The project is being conducted at Georgia Power Company`s Plant Hammond Unit 4 located near Rome, Georgia. The primary goal of this project is the characterization of the low NO{sub x} combustion equipment through the collection and analysis of long-term emissions data. A target of achieving fifty percent NO{sub x} reduction using combustion modifications has been established for the project. The project provides a stepwise retrofit of an advanced overfire air (AOFA) system followed by low NO{sub x} burners (LNB). During each test phase of the project, diagnostic, performance, long-term, and verification testing will be performed. These tests are used to quantify the NO{sub x} reductions of each technology and evaluate the effects of those reductions on other combustion parameters such as parameters such as particulate characteristics and boiler efficiency.

Not Available

1992-04-21T23:59:59.000Z

77

Innovative Clean Coal Technology (ICCT): 500 MW demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from coal-fired boilers. Technical progress report, Second quarter 1992  

SciTech Connect

This quarterly report discusses the technical progress of an Innovative Clean Coal Technology (ICCT) demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (No{sub x}) emissions from coal-fired boilers. The project is being conducted at Georgia Power Company`s Plant Hammond Unit 4 located near Rome, Georgia. The primary goal of this project is the characterization of the low NO{sub x} combustion equipment through the collection and analysis of long-term emissions data. A target of achieving fifty percent NO{sub x} reduction using combustion modifications has been established for the project. The project provides a stepwise retrofit of an advanced overfire air (AOFA) system followed by low NO{sub x} burners (LNB). During each test phase of the project, diagnostic, performance, long-term, and verification testing will be performed. These tests are used to quantify the NO{sub x} reductions of each technology and evaluate the effects of those reductions on other combustion parameters such as particulate characteristics and boiler efficiency.

Not Available

1992-08-24T23:59:59.000Z

78

Innovative Clean Coal Technology (ICCT): 500 MW demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from coal-fired boilers. Technical progress report, First quarter 1992  

SciTech Connect

This quarterly report discusses the technical progress of an Innovative Clean Coal Technology (ICCT) demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from coal-fired boilers. The project is being conducted at Georgia Power Company`s Plant Hammond Unit 4 located near Rome, Georgia. The primary goal of this project is the characterization of the low NO{sub x} combustion equipment through the collection and analysis of long-term emissions data. A target of achieving fifty percent NO{sub x} reduction using combustion modifications has been established for the project. The project provides a stepwise retrofit of an advanced overfire air (AOFA) system followed by low NO{sub x} burners (LNB). During each test phase of the project, diagnostic, performance, long-term, and verification testing will be performed. These tests are used to quantify the NO{sub x} reductions of each technology and evaluate the effects of those reductions on other combustion parameters such as particulate characteristics and boiler efficiency.

Not Available

1992-12-31T23:59:59.000Z

79

Innovative Clean Coal Technology (ICCT): 500 MW demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NO[sub x]) emissions from coal-fired boilers  

SciTech Connect

This quarterly report discusses the technical progress of an Innovative Clean Coal Technology (ICCT) demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (No[sub x]) emissions from coal-fired boilers. The project is being conducted at Georgia Power Company's Plant Hammond Unit 4 located near Rome, Georgia. The primary goal of this project is the characterization of the low NO[sub x] combustion equipment through the collection and analysis of long-term emissions data. A target of achieving fifty percent NO[sub x] reduction using combustion modifications has been established for the project. The project provides a stepwise retrofit of an advanced overfire air (AOFA) system followed by low NO[sub x] burners (LNB). During each test phase of the project, diagnostic, performance, long-term, and verification testing will be performed. These tests are used to quantify the NO[sub x] reductions of each technology and evaluate the effects of those reductions on other combustion parameters such as particulate characteristics and boiler efficiency.

Not Available

1992-08-24T23:59:59.000Z

80

Innovative Clean Coal Technology (ICCT): 500 MW demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NO sub x ) emissions from coal-fired boilers  

SciTech Connect

This quarterly report discusses the technical progress of an Innovative Clean Coal Technology (ICCT) demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from coal-fired boilers. The project is being conducted at Georgia Power Company's Plant Hammond Unit 4 located near Rome, Georgia. The primary goal of this project is the characterization of the low NO{sub x} combustion equipment through the collection and analysis of long-term emissions data. A target of achieving fifty percent NO{sub x} reduction using combustion modifications has been established for the project. The project provides a stepwise retrofit of an advanced overfire air (AOFA) system followed by low NO{sub x} burners (LNB). During each test phase of the project, diagnostic, performance, long-term, and verification testing will be performed. These tests are used to quantify the NO{sub x} reductions of each technology and evaluate the effects of those reductions on other combustion parameters such as parameters such as particulate characteristics and boiler efficiency.

Not Available

1992-04-21T23:59:59.000Z

Note: This page contains sample records for the topic "nitrogen oxide burner" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Chemisorption of carbon monoxide and nitrogen oxides on highly dispersed technetium  

SciTech Connect

The purpose of this work is to study, in infrared spectroscopy, the surface compounds formed on adsorption of carbon monoxide and nitrogen oxides on Tc/SiO/sub 2/. The samples were prepared by soaking Aerosil with aqueous solution of ammonium pertechnetate containing 10 wt.% of Tc. Reduction with hydrogen to the metal was carried out at 700-800/sup 0/C. Results indicated that chemisorption of CO on highly dispersed technetium gives rise to a single type of linear and several types of multicentered adsorption forms. Occurrence of bridge form of adsorbed CO was also suggested on the basis of the data on chemisorption stoichiometry. Formation of a structure characterizable by absorption at 1790 cm/sup -1/ may indicate, only after protracted analysis, that the surface of the technetium introduced gradually suffers significant rearrangement facilitating formation of this type of complexes.

Serebryakova, N.V.; Sokolova, N.P.; Spitsyn, V.S.

1982-08-01T23:59:59.000Z

82

Dissimilatory Metabolism of Nitrogen Oxides in Bacteria:Comparative Reconstruction of Transcriptional Networks  

SciTech Connect

Bacterial response to nitric oxide (NO) is of major importance since NO is an obligatory intermediate of the nitrogen cycle. Transcriptional regulation of the dissimilatory nitric oxides metabolism in bacteria is diverse and involves FNR-like transcription factors HcpR, DNR and NnrR, two-component systems NarXL and NarQP, NO-responsive activator NorR, and nitrite sensitive repressor NsrR. Using comparative genomics approaches we predict DNA-binding signals for these transcriptional factors and describe corresponding regulons in available bacterial genomes. Within the FNR family of regulators, we observed a correlation of two specificity-determining amino acids and contacting bases in corresponding DNA signal. Highly conserved regulon HcpR for the hybrid cluster protein and some other redox enzymes is present in diverse anaerobic bacteria including Clostridia, Thermotogales and delta-proteobacteria. NnrR and DNR control denitrification in alpha- and beta-proteobacteria, respectively. Sigma-54-dependent NorR regulon found in some gamma- and beta-proteobacteria contains various enzymes involved in the NO detoxification. Repressor NsrR, which was previously known to control only nitrite reductase operon in Nitrosomonas spp., appears to be the master regulator of the nitric oxides metabolism not only in most gamma- and beta-proteobacteria (including well-studied species like Escherichia coli), but also in Gram-positive Bacillus and Streptomyces species. Positional analysis and comparison of regulatory regions of NO detoxification genes allows us to propose the candidate NsrR-binding signal. The most conserved member of the predicted NsrR regulon is the NO-detoxifying flavohemoglobin Hmp. In enterobacteria, the regulon includes also two nitrite-responsive loci, nipAB (hcp-hcr) and nipC(dnrN), thus confirming the identity of the effector, i.e., nitrite. The proposed NsrR regulons in Neisseria and some other species are extended to include denitrification genes. As the result, we demonstrate considerable interconnection between various nitrogen-oxides-responsive regulatory systems for the denitrification and NO detoxification genes and evolutionary plasticity of this transcriptional network.

Rodionov, Dmitry A.; Dubchak, Inna L.; Arkin, Adam P.; Alm, EricJ.; Gelfand, Mikhail S.

2005-09-01T23:59:59.000Z

83

Reverberatory screen for a radiant burner  

DOE Patents (OSTI)

The present invention relates to porous mat gas fired radiant burner panels utilizing improved reverberatory screens. The purpose of these screens is to boost the overall radiant output of the burner relative to a burner using no screen and the same fuel-air flow rates. In one embodiment, the reverberatory screen is fabricated from ceramic composite material, which can withstand higher operating temperatures than its metallic equivalent. In another embodiment the reverberatory screen is corrugated. The corrugations add stiffness which helps to resist creep and thermally induced distortions due to temperature or thermal expansion coefficient differences. As an added benefit, it has been unexpectedly discovered that the corrugations further increase the radiant efficiency of the burner. In a preferred embodiment, the reverberatory screen is both corrugated and made from ceramic composite material.

Gray, Paul E. (North East, MD)

1999-01-01T23:59:59.000Z

84

Alzeta porous radiant burner. CRADA final report  

SciTech Connect

An Alzeta Pyrocore porous radiant burner was tested for the first time at elevated pressures and mass flows. Mapping of the burner`s stability limits (flashback, blowoff, and lean extinction limits) in an outward fired configuration and hot wall environment was carried out at pressures up to 18 atm, firing rates up to 180 kW, and excess air rates up to 100%. A central composite experimental design for parametric testing within the stability limits produced statistically sound correlations of dimensionless burner temperature and NO{sub x} emissions as functions of equivalence ratio, dimensionless firing rate, and reciprocal Reynolds number. The NO{sub x} emissions were below 4 ppmvd at 15% O{sub 2} for all conditions tested, and the CO and unburned hydrocarbon levels were simultaneously low. As a direct result of this cooperative research effort between METC and Alzeta, Solar Turbines has already expressed a strong interest in this novel technology.

NONE

1995-12-01T23:59:59.000Z

85

Enhanced Combustion Low NOx Pulverized Coal Burner  

SciTech Connect

For more than two decades, Alstom Power Inc. (Alstom) has developed a range of low cost, infurnace technologies for NOx emissions control for the domestic U.S. pulverized coal fired boiler market. This includes Alstom's internally developed TFS 2000{trademark} firing system, and various enhancements to it developed in concert with the U.S. Department of Energy. As of the date of this report, more than 270 units representing approximately 80,000 MWe of domestic coal fired capacity have been retrofit with Alstom low NOx technology. Best of class emissions range from 0.18 lb/MMBtu for bituminous coal to 0.10 lb/MMBtu for subbituminous coal, with typical levels at 0.24 lb/MMBtu and 0.13 lb/MMBtu, respectively. Despite these gains, NOx emissions limits in the U.S. continue to ratchet down for new and existing boiler equipment. On March 10, 2005, the Environmental Protection Agency (EPA) announced the Clean Air Interstate Rule (CAIR). CAIR requires 25 Eastern states to reduce NOx emissions from the power generation sector by 1.7 million tons in 2009 and 2.0 million tons by 2015. Low cost solutions to meet such regulations, and in particular those that can avoid the need for a costly selective catalytic reduction system (SCR), provide a strong incentive to continue to improve low NOx firing system technology to meet current and anticipated NOx control regulations. The overall objective of the work is to develop an enhanced combustion, low NOx pulverized coal burner, which, when integrated with Alstom's state-of-the-art, globally air staged low NOx firing systems will provide a means to achieve: Less than 0.15 lb/MMBtu NOx emissions when firing a high volatile Eastern or Western bituminous coal, Less than 0.10 lb/MMBtu NOx emissions when firing a subbituminous coal, NOx reduction costs at least 25% lower than the costs of an SCR, Validation of the NOx control technology developed through large (15 MWt) pilot scale demonstration, and Documentation required for economic evaluation and commercial application. During the project performance period, Alstom performed computational fluid dynamics (CFD) modeling and large pilot scale combustion testing in its Industrial Scale Burner Facility (ISBF) at its U.S. Power Plant Laboratories facility in Windsor, Connecticut in support of these objectives. The NOx reduction approach was to optimize near-field combustion to ensure that minimum NOx emissions are achieved with minimal impact on unburned carbon in ash, slagging and fouling, corrosion, and flame stability/turn-down. Several iterations of CFD and combustion testing on a Midwest coal led to an optimized design, which was extensively combustion tested on a range of coals. The data from these tests were then used to validate system costs and benefits versus SCR. Three coals were evaluated during the bench-scale and large pilot-scale testing tasks. The three coals ranged from a very reactive subbituminous coal to a moderately reactive Western bituminous coal to a much less reactive Midwest bituminous coal. Bench-scale testing was comprised of standard ASTM properties evaluation, plus more detailed characterization of fuel properties through drop tube furnace testing and thermogravimetric analysis. Bench-scale characterization of the three test coals showed that both NOx emissions and combustion performance are a strong function of coal properties. The more reactive coals evolved more of their fuel bound nitrogen in the substoichiometric main burner zone than less reactive coal, resulting in the potential for lower NOx emissions. From a combustion point of view, the more reactive coals also showed lower carbon in ash and CO values than the less reactive coal at any given main burner zone stoichiometry. According to bench-scale results, the subbituminous coal was found to be the most amenable to both low NOx, and acceptably low combustibles in the flue gas, in an air staged low NOx system. The Midwest bituminous coal, by contrast, was predicted to be the most challenging of the three coals, with the Western bituminous coal predicted to beh

David Towle; Richard Donais; Todd Hellewell; Robert Lewis; Robert Schrecengost

2007-06-30T23:59:59.000Z

86

Method for reducing NOx during combustion of coal in a burner  

DOE Patents (OSTI)

An organically complexed nanocatalyst composition is applied to or mixed with coal prior to or upon introducing the coal into a coal burner in order to catalyze the removal of coal nitrogen from the coal and its conversion into nitrogen gas prior to combustion of the coal. This process leads to reduced NOx production during coal combustion. The nanocatalyst compositions include a nanoparticle catalyst that is made using a dispersing agent that can bond with the catalyst atoms. The dispersing agent forms stable, dispersed, nano-sized catalyst particles. The catalyst composition can be formed as a stable suspension to facilitate storage, transportation and application of the catalyst nanoparticles to a coal material. The catalyst composition can be applied before or after pulverizing the coal material or it may be injected directly into the coal burner together with pulverized coal.

Zhou, Bing (Cranbury, NJ); Parasher, Sukesh (Lawrenceville, NJ); Hare, Jeffrey J. (Provo, UT); Harding, N. Stanley (North Salt Lake, UT); Black, Stephanie E. (Sandy, UT); Johnson, Kenneth R. (Highland, UT)

2008-04-15T23:59:59.000Z

87

System and method for selective catalytic reduction of nitrogen oxides in combustion exhaust gases  

DOE Patents (OSTI)

A multi-stage selective catalytic reduction (SCR) unit (32) provides efficient reduction of NOx and other pollutants from about 50-550.degree. C. in a power plant (19). Hydrogen (24) and ammonia (29) are variably supplied to the SCR unit depending on temperature. An upstream portion (34) of the SCR unit catalyzes NOx+NH.sub.3 reactions above about 200.degree. C. A downstream portion (36) catalyzes NOx+H.sub.2 reactions below about 260.degree. C., and catalyzes oxidation of NH.sub.3, CO, and VOCs with oxygen in the exhaust above about 200.degree. C., efficiently removing NOx and other pollutants over a range of conditions with low slippage of NH.sub.3. An ammonia synthesis unit (28) may be connected to the SCR unit to provide NH.sub.3 as needed, avoiding transport and storage of ammonia or urea at the site. A carbonaceous gasification plant (18) on site may supply hydrogen and nitrogen to the ammonia synthesis unit, and hydrogen to the SCR unit.

Sobolevskiy, Anatoly; Rossin, Joseph A

2014-04-08T23:59:59.000Z

88

Catalytic activity of oxidized (combusted) oil shale for removal of nitrogen oxides with ammonia as a reductant in combustion gas streams, Part 2  

SciTech Connect

Oxidized oil shale from the combustor in the LLNL Hot-Recycled-Solids (HRS) oil shale retorting process has been found to be a catalyst for removing nitrogen oxides from laboratory gas streams using NH{sub 3} as a reductant. Oxidized Green River oil shale heated at 10{degree}C/min in an Ar/O{sub 2}/NO/NH{sub 3} mixture ({approximately}93%/6%/2000 ppM/4000 ppM) with a gas residence time of {approximately}0.6 sec removed NO between 250 and 500{degree}C, with maximum removal of 70% at {approximately}400{degree}C. Under isothermal conditions with the same gas mixture, the maximum NO removal was {approximately}64%. When CO{sub 2} was added to the gas mixture at {approximately}8%, the NO removal dropped to {approximately}50%. However, increasing the gas residence time to {approximately}1.2 sec, increased NO removal to 63%. Nitrogen balances of these experiments suggest selective catalytic reduction of NO is occurring using NH{sub 3} as the reductant. These results are not based on completely optimized process conditions, but indicate oxidized oil shale is an effective catalyst for NO removal from combustion gas streams using NH{sub 3} as the reductant. Parameters calculated for implementing oxidized oil shale for NO{sub x} remediation on the current HRS retort indicate an abatement device is practical to construct.

Reynolds, J.G.; Taylor, R.W.; Morris, C.J.

1993-01-04T23:59:59.000Z

89

Catalytic activity of oxidized (combusted) oil shale for removal of nitrogen oxides with ammonia as a reductant in combustion gas streams, Part 2  

SciTech Connect

Oxidized oil shale from the combustor in the LLNL Hot-Recycled-Solids (HRS) oil shale retorting process has been found to be a catalyst for removing nitrogen oxides from laboratory gas streams using NH[sub 3] as a reductant. Oxidized Green River oil shale heated at 10[degree]C/min in an Ar/O[sub 2]/NO/NH[sub 3] mixture ([approximately]93%/6%/2000 ppM/4000 ppM) with a gas residence time of [approximately]0.6 sec removed NO between 250 and 500[degree]C, with maximum removal of 70% at [approximately]400[degree]C. Under isothermal conditions with the same gas mixture, the maximum NO removal was [approximately]64%. When CO[sub 2] was added to the gas mixture at [approximately]8%, the NO removal dropped to [approximately]50%. However, increasing the gas residence time to [approximately]1.2 sec, increased NO removal to 63%. Nitrogen balances of these experiments suggest selective catalytic reduction of NO is occurring using NH[sub 3] as the reductant. These results are not based on completely optimized process conditions, but indicate oxidized oil shale is an effective catalyst for NO removal from combustion gas streams using NH[sub 3] as the reductant. Parameters calculated for implementing oxidized oil shale for NO[sub x] remediation on the current HRS retort indicate an abatement device is practical to construct.

Reynolds, J.G.; Taylor, R.W.; Morris, C.J.

1993-01-04T23:59:59.000Z

90

Reducing the contribution of the power sector to ground-level ozone pollution : an assessment of time-differentiated pricing of nitrogen oxide emissions  

E-Print Network (OSTI)

Nitrogen oxide (NOx) is a prevalent air pollutant across the United States and a requisite precursor for tropospheric (ground-level) ozone formation. Both pollutants significantly impact human health and welfare, so National ...

Craig, Michael T. (Michael Timothy)

2014-01-01T23:59:59.000Z

91

Industrial Energy Conservation, Forced Internal Recirculation Burner  

SciTech Connect

The overall objective of this research project is to develop and evaluate an industrial low NOx burner for existing and new gas-fired combustion systems for intermediate temperature (1400 degree to 2000 degree F) industrial heating devices such as watertube boilers and process fluid heaters. A multi-phase effort is being pursued with decision points to determine advisability of continuance. The current contract over Phases II and III of this work. The objectives of each phase are as follows. Phase II - to design, fabricate, and evaluate prototype burners based on the Forced Internal Recirculation (FIR) concept. Phase III - to evaluate the performance of an FIR burner under actual operating conditions in a full-scale field test and establish the performance necessary for subsequent commercialization

Joseph Rabovitser

2003-06-19T23:59:59.000Z

92

Nitrogen oxide stack sampling at the U.S. DOE Oak Ridge Y-12 Steam Plant  

SciTech Connect

On November 7, 1997, the EPA proposed a Nitrogen Oxides State Implementation Plan Call (NO{sub x} SIP Call) for 22 states in the Eastern US which included the state of Tennessee. This initial proposal was followed by proposed statewide NO{sub x} budgets in the May 11, 1998, Supplemental Notice of Proposed Rulemaking. In the development of the NO{sub x} SIP Call, EPA performed a number of air quality analyses and determined that NO{sub x} emissions from Tennessee should be reduced. Industrial boilers, turbines, stationary internal combustion engines, and cement manufacturing are the only non-electric generating unit sources for which reductions are assumed in the budget calculation. Emission reductions are required if specific source heat input capacity is greater than 250 million Btu per hour. The US Department of Energy (DOE) Oak Ridge Y-12 Steam Plant consists of four Wickes pulverized coal fired boilers each rated at a maximum heat input capacity of 298 million Btu per hour, and will therefore be impacted by these regulatory actions. Each boiler is equipped with two pulverizing mills. Coal or natural gas or a combination of these two fuels may be fired. This paper provides the results of NO{sub x} emission stack testing conducted June 15--21, 1999, on the Y-12 Steam Plant Boilers 1 and 2. Measurements of oxygen (O{sub 2}), carbon monoxide (CO), carbon dioxide (CO{sub 2}), and stack gas flow were also performed. Information gained from these stack tests will be used to determine NO{sub x} emission control strategies for the steam plant for compliance with future emission requirements resulting from the NO{sub x} SIP Call.

L.V. Gibson, jr.; M.P. Humphreys; J.M. Skinner

2000-03-01T23:59:59.000Z

93

Modeling of formaldehyde and nitrogen oxides from a proposed renewable energy biogas facility in Canada  

Science Journals Connector (OSTI)

The aim of this study was to use the CALPUFF modeling system an effective and reliable atmospheric modeling tool to predict the concentrations of formaldehyde (HCHO) and nitrogen oxides (NOx) released due to the combustion of biogas in the combined heat and power (CHP) engines from the Kawartha renewable energy generation facility at its proposed location in Ontario Canada. In this study HCHO and NOx were selected as the indicator and point source pollutants since they were the most significant products of biogas combustion emitted during the facility's normal operations (production of electricity and heat). The Lambert Conformal Conic projection coordinate system was implemented for the operation of the CALPUFF model. The proposed modeling scheme was coupled with both surface meteorological data (from 00:00 to 23:00) on an hourly basis and 12-h interval-based upper air meteorological data (from 00:00 to 12:00) to simulate the emission of these pollutants for the four seasonal Eastern Time meteorological conditions of winter (January 11–13 2013) spring (April 14–16 2013) summer (July 10–12 2013) and autumn (November 16–18 2013). The results from the CALPUFF dispersion model clearly demonstrated that the maximum 1-h average concentrations of both HCHO and NOx emitted from the combustion of biogas (composed of 60% CH4 and 40% CO2) in five CHP engines (operation load?=?100% maximum electricity generation capacity?=?9.8?MW) were found to be within the limits defined by Ontario Regulation 419/05.

2014-01-01T23:59:59.000Z

94

Solid State Electrochemical Sensors for Nitrogen Oxide (NOx) Detection in Lean Exhaust Gases  

E-Print Network (OSTI)

for Application in Solid Oxide Fuel Cells", (DoctoralImpedance of Solid Oxide Fuel Cell LSM/YSZ CompositeCathode materials of solid oxide fuel cells: a review”, J

Rheaume, Jonathan Michael

2010-01-01T23:59:59.000Z

95

Global Nuclear Energy Partnership Fact Sheet - Develop Advanced Burner  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Develop Advanced Develop Advanced Burner Reactors Global Nuclear Energy Partnership Fact Sheet - Develop Advanced Burner Reactors GNEP will develop and demonstrate Advanced Burner Reactors (ABRs) that consume transuranic elements (plutonium and other long-lived radioactive material) while extracting their energy. The development of ABRs will allow us to build an improved nuclear fuel cycle that recycles used fuel. Accordingly, the U.S. will work with participating international partners on the design, development, and demonstration of ABRs as part of the GNEP. Global Nuclear Energy Partnership Fact Sheet - Develop Advanced Burner Reactors More Documents & Publications GNEP Element:Develop Advanced Burner Reactors Global Nuclear Energy Partnership Fact Sheet - Minimize Nuclear Waste

96

Evaluation of oxides of nitrogen emissions for the purpose of their transient regulation from a direct injection diesel engine  

Science Journals Connector (OSTI)

The concept of defining a regulatory standard for the maximum allowable emissions of oxides of nitrogen (NOx) from a heavy-duty diesel engine on an instantaneous basis is presented. The significance of this concept from a regulatory point of view is the possibility to realise a steady brake specific NOx emissions result independent of the test schedule used. The emissions of oxides of nitrogen from a state-of-the-art direct injection diesel engine have been examined on an integral as well as on an instantaneous basis over the Federal Test Procedure as well as over several other arbitrary transient cycles generated for this study. Three candidate standards of specific NOx emissions have been evaluated on a real-time, continuous basis. These include brake power specific, fuel mass specific, and carbon dioxide mass specific NOx emissions. Retaining the stock engine control module, the carbon dioxide specific emissions of NOx have been shown to be the most uniform, varying only by about 30% of its mean value regardless of the test schedule or engine operation. The instantaneous fuel specific NOx emissions are shown to be relatively less invariant and the least steady are the brake power specific emissions with a coefficient of variation of up to 200%. Advancing injection timing has been shown to have a wide range of authority over the specific emissions of oxides of nitrogen regardless of the units used, when operating at full load in the vicinity of peak torque speeds. The carbon dioxide specific NOx emissions have shown a linear dependence on the power specific emissions, independent of the examined operating conditions. The trade-off between better brake thermal efficiency, lower exhaust gas temperature at advanced timing and lower NOx emissions has also been shown to be independent of the units of the specific standard used.

Yasser Yacoub; Chris Atkinson

2001-01-01T23:59:59.000Z

97

Current emission trends for nitrogen oxides, sulfur dioxide, and volatile organic compounds by month and state: Methodology and results  

SciTech Connect

This report presents estimates of monthly sulfur dioxide (SO{sub 2}), nitrogen oxides (NO{sub x}), and nonmethane voltatile organic compound (VOC) emissions by sector, region, and state in the contiguous United States for the years 1975 through 1988. This work has been funded as part of the National Acid Precipitation Assessment Program`s Emissions and Controls Task Group by the US Department of Energy (DOE) Office of Fossil Energy (FE). The DOE project officer is Edward C. Trexler, DOE/FE Office of Planning and Environment.

Kohout, E.J.; Miller, D.J.; Nieves, L.A.; Rothman, D.S.; Saricks, C.L.; Stodolsky, F.; Hanson, D.A.

1990-08-01T23:59:59.000Z

98

Current emission trends for nitrogen oxides, sulfur dioxide, and volatile organic compounds by month and state: Methodology and results  

SciTech Connect

This report presents estimates of monthly sulfur dioxide (SO{sub 2}), nitrogen oxides (NO{sub x}), and nonmethane voltatile organic compound (VOC) emissions by sector, region, and state in the contiguous United States for the years 1975 through 1988. This work has been funded as part of the National Acid Precipitation Assessment Program's Emissions and Controls Task Group by the US Department of Energy (DOE) Office of Fossil Energy (FE). The DOE project officer is Edward C. Trexler, DOE/FE Office of Planning and Environment.

Kohout, E.J.; Miller, D.J.; Nieves, L.A.; Rothman, D.S.; Saricks, C.L.; Stodolsky, F.; Hanson, D.A.

1990-08-01T23:59:59.000Z

99

Fuel burner and combustor assembly for a gas turbine engine  

DOE Patents (OSTI)

A fuel burner and combustor assembly for a gas turbine engine has a housing within the casing of the gas turbine engine which housing defines a combustion chamber and at least one fuel burner secured to one end of the housing and extending into the combustion chamber. The other end of the fuel burner is arranged to slidably engage a fuel inlet connector extending radially inwardly from the engine casing so that fuel is supplied, from a source thereof, to the fuel burner. The fuel inlet connector and fuel burner coact to anchor the housing against axial movement relative to the engine casing while allowing relative radial movement between the engine casing and the fuel burner and, at the same time, providing fuel flow to the fuel burner. For dual fuel capability, a fuel injector is provided in said fuel burner with a flexible fuel supply pipe so that the fuel injector and fuel burner form a unitary structure which moves with the fuel burner.

Leto, Anthony (Franklin Lakes, NJ)

1983-01-01T23:59:59.000Z

100

Refinery burner simulation design architecture summary.  

SciTech Connect

This report describes the architectural design for a high fidelity simulation of a refinery and refinery burner, including demonstrations of impacts to the refinery if errors occur during the refinery process. The refinery burner model and simulation are a part of the capabilities within the Sandia National Laboratories Virtual Control System Environment (VCSE). Three components comprise the simulation: HMIs developed with commercial SCADA software, a PLC controller, and visualization software. All of these components run on different machines. This design, documented after the simulation development, incorporates aspects not traditionally seen in an architectural design, but that were utilized in this particular demonstration development. Key to the success of this model development and presented in this report are the concepts of the multiple aspects of model design and development that must be considered to capture the necessary model representation fidelity of the physical systems.

Pollock, Guylaine M.; McDonald, Michael James; Halbgewachs, Ronald D.

2011-10-01T23:59:59.000Z

Note: This page contains sample records for the topic "nitrogen oxide burner" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

PULSE DRYING EXPERIMENT AND BURNER CONSTRUCTION  

SciTech Connect

Non steady impingement heat transfer is measured. Impingement heating consumes 130 T-BTU/Yr in paper drying, but is only 25% thermally efficient. Pulse impingement is experimentally shown to enhance heat transfer by 2.8, and may deliver thermal efficiencies near 85%. Experimental results uncovered heat transfer deviations from steady theory and from previous investigators, indicating the need for further study and a better theoretical framework. The pulse burner is described, and its roll in pulse impingement is analyzed.

Robert States

2006-07-15T23:59:59.000Z

102

Advanced Burners and Combustion Controls for Industrial Heat Recovery Systems  

E-Print Network (OSTI)

ADVANCED BURNERS AND COMBUSTION CONTROLS FOR INDUSTRIAL HEAT RECOVERY SYSTEMS J.L.FERRI GTE PRODUCTS CORPORATION TOWANDA, PA ABSTRACT When recuperators are installed on indus trial furnaces, burners and ratio control systems must... recuperators by demonstrating their technical and economi cal feasibility in well monitored field installations (1). During the contract, it became evident to GTE that a systems approach (recuperator, burner, and con troIs) is necessary to be accepted...

Ferri, J. L.

103

The effects of nitrogen oxides on cytochrome P-450 mediated mixed-function oxidations in mammalian lung  

E-Print Network (OSTI)

schema for toxic inhalation of NO2 10 General representation of the proposed steps involved in substrate hydroxylation by cyto- chrome P-450 mediated mixed-function oxida- tions 13 Schematic diagram of the Isolated and Per- fused Lung Apparatus 22... and biochemical functions of the lung is pre- sented in Table 1. This summary is followed by a schematic with a more complete representation of the toxic effects of N02 inhalation (Fig. 1). Nany of the biochemical effects of nitrogen dioxide on the lung...

Tucker, Leo Dean

2012-06-07T23:59:59.000Z

104

Chlorine activation indoors and outdoors via surface-mediated reactions of nitrogen oxides with hydrogen chloride  

Science Journals Connector (OSTI)

...also globally distributed, because NO formed in combustion processes is oxidized to NO2, HNO3, N2O5 and a variety of...also globally distributed, because NO formed in combustion processes is oxidized to NO(2), HNO(3), N(2)O...

Jonathan D. Raff; Bosiljka Njegic; Wayne L. Chang; Mark S. Gordon; Donald Dabdub; R. Benny Gerber; Barbara J. Finlayson-Pitts

2009-01-01T23:59:59.000Z

105

7 - Oxy-coal burner design for utility boilers  

Science Journals Connector (OSTI)

Abstract: This chapter discusses the design of oxy-coal burners intended for application in utility boilers, with the understanding that this is an emerging technology. Physical and operational constraints on the oxy-fired design are discussed, relative to traditional air-fired burners. These constraints result in an oxy-fired flame with delayed ignition and inhibited flame stability. Additional degrees of freedom are introduced into the burner design and operation with the use of pure oxygen. Leveraging these degrees of freedom allows the design of an air-like oxy-coal burner and firing system that will produce a stable flame with tailored shape and heat transfer profile.

J. Shan; A. Fry

2011-01-01T23:59:59.000Z

106

Evaluation of gas-reburning and low NO sub x burners on a wall fired boiler  

SciTech Connect

Low NO{sub x} burners operate on the principle of delayed mixing between the coal fuel and burner air, so that less NO{sub x} is formed. Gas reburning is a combustion modification technique that consists of firing 80--85 percent of the fuel corresponding to the total heat release in the lower furnace. Reduction of NO{sub x} to molecular nitrogen (N{sub 2}) is accomplished via the downstream injection of the remaining fuel requirement in the form of natural gas (which also reduces the total SO{sub x} emissions). In a third stage, burnout air is injected at the lower temperatures in the upper furnace to complete the combustion process without generating significant additional NO{sub x}. The specific goal of this project is to demonstrate NO{sub x} emission reductions of 75 percent or more as a result of combing Low NO{sub x} Burners and Gas Reburning on a utility boiler having the design characteristics mentioned above. A Host Site Agreement has been signed by EER and a utility company in the State of Colorado: Public Service Company of Colorado (Cherokee Unit No. 3, 172 MW{sub e}) front wall fired boiler near Denver.

Not Available

1992-01-15T23:59:59.000Z

107

Catalytic activity of oxidized (combusted) oil shale for removal of nitrogen oxides with ammonia as a reductant in combustion gas streams, Part 1  

SciTech Connect

Oxidized oil shale from the combustor in the LLNL hot recycle solids oil shale retorting process has been studied as a catalyst for removing nitrogen oxides from laboratory gas streams using NH{sub 3} as areductant. Combusted Green River oil shale heated at 10{degrees}C/min in an Ar/O{sub 2}/NO/NH{sub 3} mixture ({approximately}93%/6%/2000 ppm/4000 ppm) with a gas residence time of {approximately}0.6 sec exhibited NO removal between 250 and 500{degrees}C, with maximum removal of 70% at {approximately}400{degrees}C. Under isothermal conditions with the same gas mixture, the maximum NO removal was found to be {approximately}64%. When CO{sub 2} was added to the gas mixture at {approximately}8%, the NO removal dropped to {approximately}50%. However, increasing the gas residence time to {approximately}1.2 sec, increased NO removal to 63%. These results are not based on optimized process conditions, but indicate oxidized (combusted) oil shale is an effective catalyst for NO removal from combustion gas streams using NH{sub 3} as the reductant.

Reynolds, J.G.; Taylor, R.W.; Morris, C.J.

1992-06-10T23:59:59.000Z

108

COMBUSTION SOURCES OF UNREGULATED GAS PHASE NITROGENEOUS SPECIES  

E-Print Network (OSTI)

OXIDES OF NITROGEN Nitrogen Dioxide (N0 2) Nitrous Oxide (NFigure 7. Emissions of nitrogen dioxide from gas turbines (by AiResearch(8)) . Nitrogen dioxide emissions from a

Matthews, Ronald D.

2013-01-01T23:59:59.000Z

109

Pollutant Exposures from Natural Gas Cooking Burners: A Simulation-Based Assessment for Southern California  

SciTech Connect

Residential natural gas cooking burners (NGCBs) can emit substantial quantities of pollutants and they are typically used without venting. The objective of this study is to quantify pollutant concentrations and occupant exposures resulting from NGCB use in California homes. A mass balance model was applied to estimate time-dependent pollutant concentrations throughout homes and the "exposure concentrations" experienced by individual occupants. The model was applied to estimate nitrogen dioxide (NO{sub 2}), carbon monoxide (CO), and formaldehyde (HCHO) concentrations for one week each in summer and winter for a representative sample of Southern California homes. The model simulated pollutant emissions from NGCBs, NO{sub 2} and CO entry from outdoors, dilution throughout the home, and removal by ventilation and deposition. Residence characteristics and outdoor concentrations of CO and NO{sub 2} were obtained from available databases. Ventilation rates, occupancy patterns, and burner use were inferred from household characteristics. Proximity to the burner(s) and the benefits of using venting range hoods were also explored. Replicate model executions using independently generated sets of stochastic variable values yielded estimated pollutant concentration distributions with geometric means varying less than 10%. The simulation model estimates that in homes using NGCBs without coincident use of venting range hoods, 62%, 9%, and 53% of occupants are routinely exposed to NO{sub 2}, CO, and HCHO levels that exceed acute health-based standards and guidelines. NGCB use increased the sample median of the highest simulated 1-hr indoor concentrations by 100, 3000, and 20 ppb for NO{sub 2}, CO, and HCHO, respectively. Reducing pollutant exposures from NGCBs should be a public health priority. Simulation results suggest that regular use of even moderately effective venting range hoods would dramatically reduce the percentage of homes in which concentrations exceed health-based standards.

Logue, Jennifer M.; Klepeis, Neil E.; Lobscheid, Agnes B.; Singer, Brett C.

2014-06-01T23:59:59.000Z

110

Influence of reactive species on the lean blowout limit of an industrial DLE gas turbine burner  

Science Journals Connector (OSTI)

Abstract In order to achieve ultra-low emissions of both NOX and CO it is imperative to use a homogeneous premixed combustor. To lower the emissions further, the equivalence ratio can be lowered. By doing so, combustion is moved towards the lean blowout (LBO) limit. To improve the blowout characteristics of a burner, heat and radicals can be supplied to the flame zone. This can be achieved using a pre-chamber combustor. In this study, a central body burner, called the RPL (rich-pilot-lean) section, was used as a pre-chamber combustor to supply heat and radicals to a downscaled industrial burner. The flue gas from the RPL is mixed with the surrounding fresh mixture and form a second flame zone. This zone acts as a stabilizer for the investigated burner. The LBO limit was modeled using two perfectly stirred reactors (PSRs) in series, which allows the chemical influence on the LBO limit to be isolated. The resulting trends for the modeled LBO limit were in agreement with measured data. Increasing the equivalence ratio in the RPL section, thus increasing the energy supplied by the fuel, is a major contributor to combustion stability up to a limit where the temperature decrease is too large support combustion. For lean RPL combustion, the reactive species O, H and OH in combination affect the stability to a greater extent than the temperature alone. At rich equivalence ratios, the conversion of methane to hydrogen and carbon monoxide in the RPL section is a factor influencing the LBO limit. The results are compared with emission probe measurements that were used to investigate the LBO limit for methane and a generic syngas (10% CH4, 67.5% H2, and 22.5% CO). The syngas was also investigated after being diluted with nitrogen to a Wobbe index of 15 MJ/m3.

Ivan R. Sigfrid; Ronald Whiddon; Robert Collin; Jens Klingmann

2014-01-01T23:59:59.000Z

111

Zevenhoven & Kilpinen NITROGEN 13.4.2002 4-1 Chapter 4 Nitrogen  

E-Print Network (OSTI)

of the nitric oxide is oxidized to nitrogen dioxide, so the environmental effects of emissions of bothZevenhoven & Kilpinen NITROGEN 13.4.2002 4-1 Chapter 4 Nitrogen 4.1 Introduction Probably the most damaging of the hazardous nitrogen compounds formed during combustion are nitric oxide (NO) and nitrogen

Laughlin, Robert B.

112

INVESTIGATION OF MIXED METAL SORBENT/CATALYSTS FOR THE SIMULTANEOUS REMOVAL OF SULFUR AND NITROGEN OXIDES  

SciTech Connect

Simultaneous removal of SO{sub 2} and NO{sub x} using a regenerable solid sorbent will constitute an important improvement over the use of separate processes for the removal of these two pollutants from stack gases and possibly eliminate several shortcomings of the individual SO{sub 2} and NO{sub x} removal operations. The work done at PETC and the DOE-funded investigation of the investigators on the sulfation and regeneration of alumina-supported cerium oxide sorbents have shown that they can perform well at relatively high temperatures (823-900 K) as regenerable desulfurization sorbents. Survey of the recent literature shows that addition of copper oxide to ceria lowers the sulfation temperature of ceria down to 773 K, sulfated ceria-based sorbents can function as selective SCR catalysts even at elevated temperatures, SO{sub 2} can be directly reduced to sulfur by CO on CuO-ceria catalysts, and ceria-based catalysts may have a potential for selective catalytic reduction of NO{sub x} by methane. These observations indicate a possibility of developing a ceria-based sorbent/catalyst which can remove both SO{sub 2} and NO{sub x} from flue gases within a relatively wide temperature window, produce significant amounts of elemental sulfur during regeneration, and use methane for the selective catalytic reduction of NO{sub x}. The objective of this research is to conduct kinetic and parametric studies of the selective catalytic reduction of NO{sub x} with NH{sub 3} and CH{sub 4} over alumina-supported cerium oxide and copper oxide-cerium oxide sorbent/catalysts; investigate SO{sub 2} removal at lower temperatures by supported copper oxide-cerium oxide sorbents; and investigate the possibility of elemental sulfur production during regeneration with CO or with CH{sub 4}-air mixtures.

Ates Akyurtlu; Jale F. Akyurtlu

2000-04-10T23:59:59.000Z

113

INVESTIGATION OF MIXED METAL SORBENT/CATALYSTS FOR THE SIMULTANEOUS REMOVAL OF SULFUR AND NITROGEN OXIDES  

SciTech Connect

Simultaneous removal of SO{sub 2} and NO{sub x} using a regenerable solid sorbent will constitute an important improvement over the use of separate processes for the removal of these two pollutants from stack gases and possibly eliminate several shortcomings of the individual SO{sub 2} and NO{sub x} removal operations. The work done at PETC and the DOE-funded research of the investigators on the sulfation and regeneration of alumina-supported cerium oxide sorbents have shown that they can perform well at relatively high temperatures (823-900 K) as regenerable desulfurization sorbents. Survey of the recent literature shows that addition of copper oxide to ceria lowers the sulfation temperature of ceria down to 773 K, sulfated ceria-based sorbents can function as selective SCR catalysts even at elevated temperatures, SO{sub 2} can be directly reduced to sulfur by CO on CuO-ceria catalysts, and ceria-based catalysts may have a potential for selective catalytic reduction of NO{sub x} by methane. These observations indicate a possibility of developing a ceria-based sorbent/catalyst which can remove both SO{sub 2} and NO{sub x} from flue gases within a relatively wide temperature window, produce significant amounts of elemental sulfur during regeneration, and use methane for the selective catalytic reduction of NO{sub x}. The objective of this research is to conduct kinetic and parametric studies of the selective catalytic reduction of NO{sub x} with NH{sub 3} and CH{sub 4} over alumina-supported cerium oxide and copper oxide-cerium oxide sorbent/catalysts; investigate SO{sub 2} removal at lower temperatures by supported copper oxide-cerium oxide sorbents; and investigate the possibility of elemental sulfur production during regeneration with CO or with CH{sub 4} air mixtures.

Ates Akyurtlu; Jale F. Akyurtlu

1999-11-30T23:59:59.000Z

114

Investigation of mixed metal sorbent/catalysts for the simultaneous removal of sulfur and nitrogen oxides  

SciTech Connect

Simultaneous removal of SO{sub 2} and NO{sub x} using a regenerable solid sorbent will constitute an important improvement over the use of separate processes for the removal of these two pollutants from stack gases and possibly eliminate several shortcomings of the individual SO{sub 2} and NO{sub x} removal operations. The work done at PETC and the DOE-funded investigation of the investigators on the sulfation and regeneration of alumina-supported cerium oxide sorbents have shown that they can perform well at relatively high temperatures (823-900 K) as regenerable desulfurization sorbents. Survey of the recent literature shows that addition of copper oxide to ceria lowers the sulfation temperature of ceria down to 773 K, sulfated ceria-based sorbents can function as selective SCR catalysts even at elevated temperatures, SO{sub 2} can be directly reduced to sulfur by CO on CuO-ceria catalysts, and ceria-based catalysts may have a potential for selective catalytic reduction of NO{sub x} by methane. These observations indicate a possibility of developing a ceria-based sorbent/catalyst which can remove both SO{sub 2} and NO{sub x} from flue gases within a relatively wide temperature window, produce significant amounts of elemental sulfur during regeneration, and use methane for the selective catalytic reduction of NO{sub x}. The objective of this research is to conduct kinetic and parametric studies of the selective catalytic reduction of NO{sub x} with NH{sub 3} and CH{sub 4} over alumina-supported cerium oxide and copper oxide-cerium oxide sorbent/catalysts; investigate SO{sub 2} removal at lower temperatures by supported copper oxide-cerium oxide sorbents; and investigate the possibility of elemental sulfur production during regeneration with CO or with CH{sub 4}-air mixtures.

Akyurtlu, A.; Akyurtlu, J.F.

1999-03-31T23:59:59.000Z

115

Residential oil burners with low input and two stages firing  

SciTech Connect

The residential oil burner market is currently dominated by the pressure-atomized, retention head burner. At low firing rates pressure atomizing nozzles suffer rapid fouling of the small internal passages, leading to bad spray patterns and poor combustion performance. To overcome the low input limitations of conventional burners, a low pressure air-atomized burner has been developed watch can operate at fining rates as low as 0.25 gallons of oil per hour (10 kW). In addition, the burner can be operated in a high/low fining rate mode. Field tests with this burner have been conducted at a fixed input rate of 0.35 gph (14 kW) with a side-wall vented boiler/water storage tank combination. At the test home, instrumentation was installed to measure fuel and energy flows and record trends in system temperatures. Laboratory efficiency testing with water heaters and boilers has been completed using standard single purpose and combined appliance test procedures. The tests quantify benefits due to low firing rates and other burner features. A two stage oil burner gains a strong advantage in rated efficiency while maintaining capacity for high domestic hot water and space heating loads.

Butcher, T.; Krajewski, R.; Leigh, R. [and others

1997-12-31T23:59:59.000Z

116

Turbine Burners: Flameholding in Accelerating Flow W. A. Sirignano1  

E-Print Network (OSTI)

1 Turbine Burners: Flameholding in Accelerating Flow W. A. Sirignano1 , D. Dunn-Rankin2 , F. Liu3 B, Irvine Abstract A review of turbine-burner research and some relevant background issues is presented. Previous work on thermal cycle analysis for augmentative combustion in the passages of the turbine

Liu, Feng

117

Advanced oil burner for residential heating -- development report  

SciTech Connect

The development of advanced oil burner concepts has long been a part of Brookhaven National Laboratory`s (BNL) oil heat research program. Generally, goals of this work include: increased system efficiency, reduced emissions of soot and NO{sub x}, and the practical extension of the firing rate range of current burners to lower input rates. The report describes the results of a project at BNL aimed at the development of air atomized burners. Two concepts are discussed. The first is an air atomizer which uses air supplied at pressures ranging from 10 to 20 psi and requiring the integration of an air compressor in the system. The second, more novel, approach involves the use of a low-pressure air atomizing nozzle which requires only 8-14 inches of water air pressure for fuel atomization. This second approach requires the use of a fan in the burner instead of a compressor although the fan pressure is higher than with conventional, pressure atomized retention head burners. In testing the first concept, high pressure air atomization, a conventional retention head burner was modified to accept the new nozzle. In addition, the burner head was modified to reduce the flow area to maintain roughly 1 inch of water pressure drop across the head at a firing rate of 0.25 gallons of oil per hour. The burner ignited easily and could be operated at low excess air levels without smoke. The major disadvantage of this burner approach is the need for the air compressor as part of the system. In evaluating options, a vane-type compressor was selected although the use of a compressor of this type will lead to increased burner maintenance requirements.

Butcher, T.A.

1995-07-01T23:59:59.000Z

118

Experimental study of combustion of hydrogen–syngas/methane fuel mixtures in a porous burner  

Science Journals Connector (OSTI)

Lean premixed combustion of hydrogen–syngas/methane fuel mixtures was investigated experimentally to demonstrate fuel flexibility of a two-section porous burner. The un-insulated burner was operated at atmospheric pressure. Combustion was stabilized at the interface of silicon-carbide coated carbon foam of 26 pores per centimeter (ppcm) and 4 ppcm. Methane (CH4) content in the fuel was decreased from 100% to 0% (by volume), with the remaining amount split equally between carbon monoxide (CO) and hydrogen (H2), the two reactive components of the syngas. Experiments for different fuel mixtures were conducted at a fixed air flow rate, while the fuel flow rate was varied to obtain a range of adiabatic flame temperatures. The CO and nitric oxide ( NO x ) emissions were measured downstream of the porous burner, in the axial direction to identify the post-combustion zone and in the transverse direction to quantify combustion uniformity. For a given adiabatic flame temperature, increasing H2/CO content in the fuel mixture decreased both the CO and NO x emissions. Presence of H2/CO in the fuel mixture also decreased temperature near the lean blow-off limit, especially for higher percentages of CO and H2 in the fuel.

S.K. Alavandi; A.K. Agrawal

2008-01-01T23:59:59.000Z

119

Removal of oxides of nitrogen from gases in multi-stage coal combustion  

DOE Patents (OSTI)

Polluting NO.sub.x gas values are removed from off-gas of a multi-stage coal combustion process which includes an initial carbonizing reaction, firing of char from this reaction in a fluidized bed reactor, and burning of gases from the carbonizing and fluidized bed reactions in a topping combustor having a first, fuel-rich zone and a second, fuel-lean zone. The improvement by means of which NO.sub.x gases are removed is directed to introducing NO.sub.x -free oxidizing gas such as compressor air into the second, fuel-lean zone and completing combustion with this source of oxidizing gas. Excess air fed to the fluidized bed reactor is also controlled to obtain desired stoichiometry in the first, fuel-rich zone of the topping combustor.

Mollot, Darren J. (Morgantown, WV); Bonk, Donald L. (Louisville, OH); Dowdy, Thomas E. (Orlando, FL)

1998-01-01T23:59:59.000Z

120

Flow reactor experiments on the selective non-catalytic removal of nitrogen oxides  

E-Print Network (OSTI)

?CO, and H, O are initially present in exhaust stream [57]. .. . . . 42 Fig. 21 Fig. 22 Reaction path diagram for RAPRENOx process [63]. .. . Reduction of nitric oxide as a function of temperature, concentration of oxygen, carbon monoxide, and water... the influence of carbon monoxide [89]. . . . . . . . . 58 Fig. 28 Effect of residence time on the NOxOUT process as a function of temperature, NO(initial)=125ppm, 0-ratio of 4 [90]. .. . . . . . . . . . . . . . . 60 Fig. 29 Ammonia slip as a function...

Gentemann, Alexander M.G.

2001-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "nitrogen oxide burner" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Demonstration of selective catalytic reduction (SCR) technology for the control of nitrogen oxide (NOx) emissions from high-sulfur coal-fired boilers  

SciTech Connect

The objective of this project is to demonstrate and evaluate commercially available Selective Catalytic Reduction (SCR) catalysts from US, Japanese and European catalyst suppliers on a high-sulfur US coal-fired boiler. SCR is a post-combustion nitrogen oxide (NO{sub x}) control technology that involves injecting ammonia into the flue gas generated from coal combustion in an electric utility boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NO{sub x} to convert it to nitrogen and water vapor.

Not Available

1991-11-01T23:59:59.000Z

122

Method and system for the removal of oxides of nitrogen and sulfur from combustion processes  

DOE Patents (OSTI)

A process for removing oxide contaminants from combustion gas, and employing a solid electrolyte reactor, includes: (a) flowing the combustion gas into a zone containing a solid electrolyte and applying a voltage and at elevated temperature to thereby separate oxygen via the solid electrolyte, (b) removing oxygen from that zone in a first stream and removing hot effluent gas from that zone in a second stream, the effluent gas containing contaminant, (c) and pre-heating the combustion gas flowing to that zone by passing it in heat exchange relation with the hot effluent gas.

Walsh, John V. (Glendora, CA)

1987-12-15T23:59:59.000Z

123

Solid Oxide Fuel Cell System Utilizing Syngas from Coal Gasifiers  

Science Journals Connector (OSTI)

Solid Oxide Fuel Cell System Utilizing Syngas from Coal Gasifiers ... The oxidizer is expected to be similar in design to a HRSG duct firing burner (at the inlet of a HRSG). ...

Hossein Ghezel-Ayagh; Stephen Jolly; Dilip Patel; David Stauffer

2013-01-10T23:59:59.000Z

124

NETL: Emissions Characterization - Adv. Low-NOx Burner Emissions  

NLE Websites -- All DOE Office Websites (Extended Search)

Advanced Low-NOx Burner Emissions Characterization Advanced Low-NOx Burner Emissions Characterization The goal of this work is to develop a comprehensive, high-quality database characterizing PM2.5 emissions from utility plants firing high sulfur coals. The specific objectives are to: 1) develop and test an ultra low-NOx pulverized coal burner for plug-in retrofit applications without boiler wall tube modifications, 2) assess the impact of low-NOx PC burner operation on NOx and PM2.5 emissions, and 3) provide high-quality data to ensure that future PM2.5 regulations are based on good scientific information. The work will be performed in the Clean Environment Development Facility (CEDF), a 100 million Btu/hr near-full-scale facility located at the Alliance Research Center. Related Papers and Publications:

125

J.R. Simplot: Burner Upgrade Project Improves Performance and...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Company saved energy and money by increasing the efficiency of the steam system in its potato processing plant in Caldwell, Idaho. J.R. Simplot: Burner Upgrade Project Improves...

126

Selective diagnostics of combustion processes in multi-burner boilers  

Science Journals Connector (OSTI)

The process of gas hydrocarbon combustion was tested in real (industrial) conditions on boilers with many burners. For key operation modes, the main regularities of emission from single flames were studied. Th...

S. M. Borzov; V. V. Garkusha; V. I. Kozik; V. P. Mikheev…

127

Evaluation of gas-reburning and low NO sub x burners on a wall fired boiler  

SciTech Connect

This clean coal technology project will demonstrate a combination of two developed technologies to reduce both NO{sub x} and (to some extent) SO{sub x} emissions: Gas reburning and low NO{sub x} burners. The demonstrations will be conducted on a pre-NSPS utility boiler representative of US boilers that contribute significantly to the inventory of acid rain precursor emissions: a wall fired unit. Low NO{sub x} burners operate on the principle of delayed mixing between the coal fuel and burner air, so that less NO{sub x} is burned. Gas reburning is a combustion modification technique that consists of firing 80--85 percent of the fuel corresponding to the total heat release in the lower furnace. Reduction of NO{sub x} to molecular nitrogen (N{sub 2}) is accomplished via the downstream injection of the remaining fuel requirement in the form of natural gas (which also reduces the total SO{sub x} emissions). In a third stage, burnout air is injected at lower temperatures in the upper furnace to complete the combustion process without generating significant additional NO{sub x}. The specific goal of this project is to demonstrate NO{sub x} and SO{sub x} emission reductions of 75 percent or more as a result of combining LNB and GR to a utility boiler having the design characteristics mentioned above. A Host Site Agreement has been signed by EER and a utility company in the State of Colorado: Public Service Company of Colorado (Cherokee Unit No. 3, 172 MW{sub e}) front wall fired boiler near Denver.

Not Available

1991-04-26T23:59:59.000Z

128

Dual-water mixture fuel burner  

DOE Patents (OSTI)

A coal-water mixture (CWM) burner includes a conically shaped rotating cup into which fuel comprised of coal particles suspended in a slurry is introduced via a first, elongated inner tube coupled to a narrow first end portion of the cup. A second, elongated outer tube is coaxially positioned about the first tube and delivers steam to the narrow first end of the cup. The fuel delivery end of the inner first tube is provided with a helical slot on its lateral surface for directing the CWM onto the inner surface of the rotating cup in the form of a uniform, thin sheet which, under the influence of the cup's centrifugal force, flows toward a second, open, expanded end portion of the rotating cup positioned immediately adjacent to a combustion chamber. The steam delivered to the rotating cup wets its inner surface and inhibits the coal within the CWM from adhering to the rotating cup. A primary air source directs a high velocity air flow coaxially about the expanded discharge end of the rotating cup for applying a shear force to the CWM in atomizing the fuel mixture for improved combustion. A secondary air source directs secondary air into the combustion chamber adjacent to the outlet of the rotating cup at a desired pitch angle relative to the fuel mixture/steam flow to promote recirculation of hot combustion gases within the ignition zone for increased flame stability.

Brown, Thomas D. (Finleyville, PA); Reehl, Douglas P. (Pittsburgh, PA); Walbert, Gary F. (Library, PA)

1986-08-05T23:59:59.000Z

129

Flame quality monitor system for fixed firing rate oil burners  

DOE Patents (OSTI)

A method and apparatus for determining and indicating the flame quality, or efficiency of the air-fuel ratio, in a fixed firing rate heating unit, such as an oil burning furnace, is provided. When the flame brightness falls outside a preset range, the flame quality, or excess air, has changed to the point that the unit should be serviced. The flame quality indicator output is in the form of lights mounted on the front of the unit. A green light indicates that the flame is about in the same condition as when the burner was last serviced. A red light indicates a flame which is either too rich or too lean, and that servicing of the burner is required. At the end of each firing cycle, the flame quality indicator goes into a hold mode which is in effect during the period that the burner remains off. A yellow or amber light indicates that the burner is in the hold mode. In this mode, the flame quality lights indicate the flame condition immediately before the burner turned off. Thus the unit can be viewed when it is off, and the flame condition at the end of the previous firing cycle can be observed.

Butcher, Thomas A. (Pt. Jefferson, NY); Cerniglia, Philip (Moriches, NY)

1992-01-01T23:59:59.000Z

130

High Efficiency Burners by Retrofit - A Simple Inexpensive Way to Improve Combustion Efficiency  

E-Print Network (OSTI)

Existing direct fired process heaters and steam boilers can have their efficiencies remarkably improved, and thus cut the fuel bill, by conversion from conventional type natural draft burners to high intensity, "forced draft" type burners...

Rogers, W. T.

1980-01-01T23:59:59.000Z

131

Applying methods of numerical modeling to optimize a plasma burner of atmospheric pressure  

Science Journals Connector (OSTI)

The shape of a plasma burner is optimized by the methods of numerical modeling. Vortex-free flow is created in the burner merely at the expense of selecting the external tube profile rather than by introductio...

S. M. Perminov; V. N. Perminova…

1993-09-01T23:59:59.000Z

132

E-Print Network 3.0 - atomized oil burner Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

oil burner Search Powered by Explorit Topic List Advanced Search Sample search results for: atomized oil burner Page: << < 1 2 3 4 5 > >> 1 Wood Waste -A Modern Fuel M. A. SERRELL,...

133

ARM - Oxides of Nitrogen  

NLE Websites -- All DOE Office Websites (Extended Search)

dioxide and methane, but as you will see they are important contributors to the greenhouse effect. We hope you are getting an understanding of how important all these gases are...

134

Biomass Burner Cogenerates Jobs and Electricity from Lumber Mill Waste |  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Biomass Burner Cogenerates Jobs and Electricity from Lumber Mill Biomass Burner Cogenerates Jobs and Electricity from Lumber Mill Waste Biomass Burner Cogenerates Jobs and Electricity from Lumber Mill Waste December 6, 2011 - 3:57pm Addthis Dale and Sharon Borgford, small business owners in Stevens County, WA, break ground with Peter Goldmark, Washington State Commissioner of Public Lands. The pair brought more than 75 jobs to the area with help from DOE's State Energy Program and the U.S. Forest Service. | Photo courtesy of Washington DNR. Dale and Sharon Borgford, small business owners in Stevens County, WA, break ground with Peter Goldmark, Washington State Commissioner of Public Lands. The pair brought more than 75 jobs to the area with help from DOE's State Energy Program and the U.S. Forest Service. | Photo courtesy of

135

Biomass Burner Cogenerates Jobs and Electricity from Lumber Mill Waste |  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Biomass Burner Cogenerates Jobs and Electricity from Lumber Mill Biomass Burner Cogenerates Jobs and Electricity from Lumber Mill Waste Biomass Burner Cogenerates Jobs and Electricity from Lumber Mill Waste December 6, 2011 - 3:57pm Addthis Dale and Sharon Borgford, small business owners in Stevens County, WA, break ground with Peter Goldmark, Washington State Commissioner of Public Lands. The pair brought more than 75 jobs to the area with help from DOE's State Energy Program and the U.S. Forest Service. | Photo courtesy of Washington DNR. Dale and Sharon Borgford, small business owners in Stevens County, WA, break ground with Peter Goldmark, Washington State Commissioner of Public Lands. The pair brought more than 75 jobs to the area with help from DOE's State Energy Program and the U.S. Forest Service. | Photo courtesy of

136

Low-Emissions Burner Technology using Biomass-Derived Liquid Fuels  

Energy.gov (U.S. Department of Energy (DOE))

Factsheet summarizing Univ. of Alabama project to save energy and reduce emissions with fuel-flexible burners

137

CHP Integrated with Burners for Packaged Boilers- Fact Sheet, April 2014  

Energy.gov (U.S. Department of Energy (DOE))

Fact sheet overviewing how this project will develop and integrate the Boiler Burner Energy System Technology (BBEST)

138

Abatement of Air Pollution: The Clean Air Interstate Rule (CAIR) Nitrogen Oxides (Nox) Ozone Season Trading Program (Connecticut)  

Energy.gov (U.S. Department of Energy (DOE))

These regulations may apply to fossil-fuel fired emission units, and describe nitrogen emission allocations that owners of such units must meet. The regulations also contain provisions for...

139

Development of an air-atomized oil burner  

SciTech Connect

A new concept for the design of a residential oil burner is presented involving a low pressure, air atomizing nozzle. Advantages of this approach, relative to conventional, pressure atomized burners include: ability to operate at very low excess air levels without smoke, ability to operate at low (and possibly variable) rates, reduced boiler fouling, and low NO{sub x}. The nozzle used is a low pressure, airblast atomizer which can achieve fuel spray drop sizes similar to conventional nozzles and very good combustion performance with air pressure as low as 5 inches of water (1.24 kPa). A burner head has been developed for this nozzle and combustion test results are presented in a wide variety of equipment including cast iron and steel boilers, warm air furnaces, and water heaters over the firing rate range 0.25 gph to 1.0 gph (10 to 41 kW). Beyond the nozzle and combustion head the burner system must be developed and two approaches have been taken. The first involves a small, brushless DC motor/fan combination which uses high fan speed to achieve air pressures from 7 to 9 inches of water (1.74 to 2.24 kPa). Fuel is delivered to the atomizer at less than 1 psig (6.9 kPa) using a solenoid pump and flow metering orifice. At 0.35 gph (14 kW) the electric power draw of this burner is less than 100 watts. In a second configuration a conventional motor is used with a single stage fan which develops 5 to 6 inches of water pressure (1.24 to 1.50 kPa) at similar firing rates. This burner uses a conventional type fuel pump and metering orifice to deliver fuel. The fuel pump is driven by the fan motor, very much like a conventional burner. This second configuration is seen as more attractive to the heating industry and is now being commercialized. Field tests with this burner have been conducted at 0.35 gph (14 kW) with a side-wall vented boiler/water storage tank combination.

Butcher, T.A.; Celebi, Y.

1996-06-01T23:59:59.000Z

140

BURNER DEVELOPMENT AND OPERABILITY ISSUES ASSOCIATED WITH STEADY FLOWING SYNGAS  

E-Print Network (OSTI)

BURNER DEVELOPMENT AND OPERABILITY ISSUES ASSOCIATED WITH STEADY FLOWING SYNGAS FIRED COMBUSTORS Engineering, Georgia Institute of Technology, Atlanta, Georgia, USA 2 UCI Combustion Laboratory, University-Mu¨nchen, Garching, Germany This article addresses the impact of syngas fuel composition on combustor blowout, flash

Lieuwen, Timothy C.

Note: This page contains sample records for the topic "nitrogen oxide burner" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Study of the Effects of Ambient Conditions Upon the Performance of Fan Powered, Infrared Natural Gas Burners  

SciTech Connect

The objective of this investigation was to characterize the operation of a fan-powered, infrared burner (IR burner) at various gas compositions and ambient conditions, develop numerical model to simulate the burner performances, and provide design guidelines for appliances containing PIR burners for satisfactory performance.

Clark Atlanta University

2002-12-02T23:59:59.000Z

142

VARIABLE FIRING RATE OIL BURNER USING PULSE FUEL FLOW CONTROL.  

SciTech Connect

The residential oil burner market is currently dominated by the pressure-atomized retention head burner, which has an excellent reputation for reliability and efficiency. In this burner, oil is delivered to a fuel nozzle at pressures from 100 to 150 psi. In addition, to atomizing the fuel, the small, carefully controlled size of the nozzle exit orifice serves to control the burner firing rate. Burners of this type are currently available at firing rates of more than 0.5 gallons-per-hour (70,000 Btu/hr). Nozzles have been made for lower firing rates, but experience has shown that such nozzles suffer rapid fouling of the necessarily small passages, leading to bad spray patterns and poor combustion performance. Also, traditionally burners and the nozzles are oversized to exceed the maximum demand. Typically, this is figured as follows. The heating load of the house on the coldest day for the location is considered to define the maximum heat load. The contractor or installer adds to this to provide a safety margin and for future expansion of the house. If the unit is a boiler that provides domestic hot water through the use of a tankless heating coil, the burner capacity is further increased. On the contrary, for a majority of the time, the heating system is satisfying a much smaller load, as only rarely do all these demands add up. Consequently, the average output of the heating system has to be much less than the design capacity and this is accomplished by start and stop cycling operation of the system so that the time-averaged output equals the demand. However, this has been demonstrated to lead to overall efficiencies lower than the steady-state efficiency. Therefore, the two main reasons for the current practice of using oil burners much larger than necessary for space heating are the unavailability of reliable low firing rate oil burners and the desire to assure adequate input rate for short duration, high draw domestic hot water loads. One approach to solve this problem is to develop a burner, which can operate at two firing rates, with the lower rate being significantly lower than 0.5 gallons per hour. This paper describes the initial results of adopting this approach through a pulsed flow nozzle. It has been shown that the concept of flow modulation with a small solenoid valve is feasible. Especially in the second configuration tested, where the Lee valve was integrated with the nozzle, reasonable modulation in flow of the order of 1.7 could be achieved. For this first prototype, the combustion performance is still not quite satisfactory. Improvements in operation, for example by providing a sharp and positive shut-off so that there is no flow under low pressures with consequent poor atomization could lead to better combustion performance. This could be achieved by using nozzles that have shut off or check valves for example. It is recommended that more work in cooperation with the valve manufacturer could produce a technically viable system. Marketability is of course a far more complex problem to be addressed once a technically viable product is available.

KRISHNA,C.R.; BUTCHER,T.A.; KAMATH,B.R.

2004-10-01T23:59:59.000Z

143

Field Demonstration of 0.2 Grams Per Horsepower-Hour (g/bhp-hr) Oxides of Nitrogen (NOx) Natural  

E-Print Network (OSTI)

: · Reducing health and environmental impacts from air pollution, and greenhouse gas emissions related pollution and greenhouse gas emissions beyond applicable standards, and that benefit natural gas ratepayers of nitrogen (NOx) emission standard of 0.20 g/bhp-hr for heavy duty engines to reduce levels of this critical

144

Solubility of carbon dioxide, nitrous oxide, ethane, and nitrogen in 1-butyl-1-methylpyrrolidinium and trihexyl(tetradecyl)phosphonium tris(pentafluoroethyl)trifluorophosphate (eFAP) ionic liquids  

Science Journals Connector (OSTI)

The density and viscosity of the ionic liquids 1-butyl-1-methylpyrrolidinium tris(pentafluoroethyl)trifluorophosphate [C1C4Pyrro][eFAP] and trihexyl(tetradecyl)phosphonium tris(pentafluoroethyl)trifluorophosphate [P66614][eFAP] were measured as a function of temperature and pressure and as a function of temperature, respectively. These two ionic liquids are more viscous than those based in the same anion associated to imidazolium cations. The effect of the addition of water on the density and viscosity of [P66614][eFAP] was studied at pressures close to atmospheric and as a function of the temperature. This ionic liquid is only partially miscible with water, its solubility being of around X H 2 O = 0.2 in the range of (303 to 315) K. Experimental values of the solubility of carbon dioxide, nitrous oxide, ethane, and nitrogen were obtained as a function of temperature and at pressures close to atmospheric. Carbon dioxide and nitrous oxide are the more soluble gases with mole fraction solubilities up to 7 · 10?2. Ethane is four times and 1.3 times less soluble than carbon dioxide in [C1C4Pyrro][eFAP] and [P66614][eFAP], respectively. Nitrogen is one order of magnitude less soluble than the others gases in the two ionic liquids studied. In order to understand behavior of the different gases with these ionic liquids, the thermodynamic functions of solvation such as enthalpy and entropy were calculated from the variation of the Henry’s law constant with temperature. It is shown that the more favorable interactions of the gases with the ionic liquid explain the larger solubility of carbon dioxide and nitrous oxide in [C1C4Pyrro][eFAP]. In the case of [P66614][eFAP], it is the less favorable entropic contribution that explains the lower solubility of ethane in this ionic liquid.

S. Stevanovic; M.F. Costa Gomes

2013-01-01T23:59:59.000Z

145

Nitrite–dependent nitric oxide production pathway: implications for involvement of active nitrogen species in photoinhibition in vivo  

Science Journals Connector (OSTI)

...as a convenient method for calibration...1. Chemical NO production from nitrite and...Figure 4. Sequential production of the activated...interactions. Like hydrogen peroxide (H2O2...oxide protocols: methods in molecular biology...Nonenzymatic nitric oxide production in humans. Nitric...

2000-01-01T23:59:59.000Z

146

Nitrogen Oxides in the Nocturnal Boundary Layer: Chemistry of Nitrous Acid (HONO) and the Nitrate Radical (N03)  

SciTech Connect

Summary Chemical processes occurring at night in the lowest part of the urban atmosphere, the so called nocturnal boundary layer (NBL), can influence the composition of the atmosphere during the night as well as the following day. They may impact the budgets of some of the most important pollutants, such as ozone and nitrogen oxides, as well as influence size and composition of particular matter. Few studies have thus far concentrated on the nocturnal chemistry of the urban NBL, most likely due to the strong influence of vertical transport and mixing, which requires the measurement of trace gas profiles instead of simple point observations. Motivated by our lack of observations and understanding of nocturnal chemistry, the focus of this project was the study of the vertical distribution of trace gases and the altitude dependence of nocturnal chemistry under polluted conditions through field observations and modeling studies. The analysis of three field experiments (TEXAQS, Houston, 2000; Phoenix Sunrise Ozone Experiment, 2001; NAPOX, Boston, 2002), two of which were performed in this project, showed that ozone concentrations typically increase with height in the lowest 150m, while NO2 typically decreases. NO3, the dominant nocturnal radical species, showed much higher concentrations in the upper part of the NBL, and was often not present at the ground. With the help of a one-dimensional chemical transport model, developed in this project, we found that the interaction of ground emissions of NOx and hydrocarbons, together with their vertical transport, is responsible for the vertical profiles. The dominant chemical reactions influencing ozone, NO2 and NO3 are the reaction of ozone and NO3 with freshly emitted NO. Sensitivity studies with our model showed that the magnitude of the trace gas gradients depend both on the emission rates and the vertical stability of the NBL. Observations and model analysis clearly show that nocturnal chemistry in urban areas is altitude dependent. Measurements at one altitude, for example at the ground, where most air quality monitoring stations are located, are not representative for the rest of the NBL. Our model also revealed that radical chemistry is, in general, altitude dependent at night. We distinguish three regions: an unreactive, NO rich, ground layer; an upper, O3 and NO3 dominated layer, and a reactive mixing layer, where RO2 radicals are mixed from aloft with NO from the ground. In this reactive layer an active radical chemistry and elevated OH radical levels can be found. The downward transport of N2O5 and HO2NO2, followed by their thermal decay, was also identified as a radical source in this layer. Our observations also gave insight into the formation of HONO in the NBL. Based on our field experiments we were able to show that the NO2 to HONO conversion was relative humidity dependent. While this fact was well known, we found that it is most likely the uptake of HONO onto surfaces which is R.H. dependent, rather than the NO2 to HONO conversion. This finding led to the proposal of a new NO2 to HONO conversion mechanism, which is based on solid physical chemical principles. Noteworthy is also the observation of enhanced NO2 to HONO conversion during a dust storm event in Phoenix. The final activity in our project investigated the influence of the urban canopy, i.e. building walls and surfaces, on nocturnal chemistry. For the first time the surface area of a city was determined based on a Geographical Information System database of the city of Santa Monica. The surface to volume areas found in this study showed that, in the 2 lower part of the NBL, buildings provide a much larger surface area than the aerosol. In addition, buildings take up a considerable amount of the volume near the ground. The expansion of our model and sensitivity studies based on the Santa Monica data revealed that the surface area of buildings considerably influences HONO levels in urban areas. The volume reduction leads to a decrease of O3 and an increase of NO2 near the ground due to the stronger impact o

Jochen Stutz

2005-05-24T23:59:59.000Z

147

Development of a Methane Premixed Catalytic Burner for Household Applications  

Science Journals Connector (OSTI)

The catalytic combustion of methane is currently investigated in a variety of international research programs, thanks to its numerous potential applications (e.g., boilers, process heaters, reciprocating engines, gas-turbine cycles, etc.). ... At low surface heat powers (Q) and excesses of air (Ea), the combustion mostly occurs in a thin layer within the permeable panel (radiant or flameless regime, Figure 1b); the burner outlet surface (burner deck) reaches temperatures varying from 700 to 900 °C, depending on both Q and Ea values, and glows flamelessly. ... The goal is to assemble a boiler capable of coping with variable hot water requests:? from about 2?3 kW (160?240 kW/m2) for apartment heating up to 25 kW (2000 kW/m2) for sanitary purposes, so as to produce hot water with time delays compatible with the users' comfort. ...

Isotta Cerri; Guido Saracco; Francesco Geobaldo; Vito Specchia

2000-01-04T23:59:59.000Z

148

NUMERICAL SIMULATION OF NATURAL GAS-SWIRL BURNER  

SciTech Connect

A numerical simulation of a turbulent natural gas jet diffusion flame at a Reynolds number of 9000 in a swirling air stream is presented. The numerical computations were carried out using the commercially available software package CFDRC. The instantaneous chemistry model was used as the reaction model. The thermal, composition, flow (velocity), as well as stream function fields for both the baseline and air-swirling flames were numerically simulated in the near-burner region, where most of the mixing and reactions occur. The results were useful to interpret the effects of swirl in enhancing the mixing rates in the combustion zone as well as in stabilizing the flame. The results showed the generation of two recirculating regimes induced by the swirling air stream, which account for such effects. The present investigation will be used as a benchmark study of swirl flow combustion analysis as a step in developing an enhanced swirl-cascade burner technology.

Ala Qubbaj

2005-03-01T23:59:59.000Z

149

Analysis of Strategies for Reducing Multiple Emissions from Electric Power Plants: Sulfur Dioxide, Nitrogen Oxides, Carbon Dioxide, and Mercury and a Renewable Portfolio Standard  

Gasoline and Diesel Fuel Update (EIA)

3 3 ERRATA Analysis of Strategies for Reducing Multiple Emissions from Electric Power Plants: Sulfur Dioxide, Nitrogen Oxides, Carbon Dioxide, and Mercury and a Renewable Portfolio Standard July 2001 Energy Information Administration Office of Integrated Analysis and Forecasting U.S. Department of Energy Washington, DC 20585 This Service Report was prepared by the Energy Information Administration, the independent statistical and analytical agency within the Department of Energy. The information contained herein should be attributed to the Contacts This report was prepared by the Office of Integrated Analysis and Forecasting, Energy Information Adminis- tration. General questions concerning the report may be directed to Mary J. Hutzler (202/586-2222, mhutzler @eia.doe.gov), Director of the Office of Integrated Analysis and Forecasting, Scott B. Sitzer (202/586-2308,

150

The Advanced Tangentially Fired Combustion Techniques for the Reduction of Nitrogen Oxides (NOx) Emissions From Coal-Fired Boilers Demonstration Project: A DOE Assessment  

NLE Websites -- All DOE Office Websites (Extended Search)

2 2 The Advanced Tangentially Fired Combustion Techniques for the Reduction of Nitrogen Oxides (NO ) Emissions From Coal-Fired Boilers X Demonstration Project: A DOE Assessment March 2000 U.S. Department of Energy National Energy Technology Laboratory P.O. Box 880, 3610 Collins Ferry Road Morgantown, WV 26507-0880 and P.O. Box 10940, 626 Cochrans Mill Road Pittsburgh, PA 15236-0940 2 Disclaimer This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or

151

Demonstration of selective catalytic reduction (SCR) technology for the control of nitrogen oxide (NO[sub x]) emissions from high-sulfur coal-fired boilers  

SciTech Connect

The objective of this project is to demonstrate and evaluate commercially available Selective Catalytic Reduction (SCR) catalysts from US, Japanese and European catalyst suppliers on a high-sulfur US coal-fired boiler. SCR is a post-combustion nitrogen oxide (NO[sub x]) control technology that involves injecting ammonia into the flue gas generated from coal combustion in an electric utility boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NO[sub x] to convert it to nitrogen and water vapor. Although SCR is widely practiced in Japan and Europe, there are numerous technical uncertainties associated with applying SCR to US coals. These uncertainties include: (1) potential catalyst deactivation due to poisoning by trace metal species present in US coals that are not present in other fuels. (2) performance of the technology and effects on the balance-of-plant equipment in the presence of high amounts of SO[sub 2] and SO[sub 3]. (3) performance of a wide variety of SCR catalyst compositions, geometries and methods of manufacture under typical high-sulfur coal-fired utility operating conditions. These uncertainties will be explored by constructing a series of small-scale SCR reactors and simultaneously exposing different SCR catalysts to flue gas derived from the combustion of high sulfur U. S. coal.

Not Available

1992-08-01T23:59:59.000Z

152

NETL: Investigation on Flame Characteristics and Burner Operability Issues  

NLE Websites -- All DOE Office Websites (Extended Search)

Investigation on Flame Characteristics and Burner Operability Issues of Oxy-Fuel Combustion Investigation on Flame Characteristics and Burner Operability Issues of Oxy-Fuel Combustion Project No.: DE-FE0002402 NETL has partnered with the University of Texas at El Paso (UTEP) to investigate the characteristics of oxy-fuel flames and assess their impact on the operability of oxy-fuel combustion systems. The examination of fundamental flame characteristics data and related burner operability parameters are essential for designing and developing oxy-fuel combustion systems for new power plants and retrofitting existing power generation units. In an oxy-fuel system, coal is combusted in an enriched oxygen environment using pure oxygen diluted with recycled CO2 or water vapor (H2O), resulting in a flue stream consisting only of CO2 and H2O (no other co-contaminants) (Figure 1). Oxy-fuel combustion is promising for CCUS applications because water can be condensed out of the CO2/H2O flue stream to produce a relatively pure CO2 end product for capture. Oxy-fuel combustion and subsequent CO2 capture is currently being considered by the DOE's Innovations for Existing Plants Program as having the potential to meet the goal of 90 percent CO2 capture without increasing the cost of electricity more than 35 percent.

153

E-Print Network 3.0 - actinide burner reactors Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

and Design 85 (2010) 14881491 Contents lists available at ScienceDirect Summary: subcritical advanced burner reactor, Nuclear technology 162 (2008). 9 M. Kotschenreuther,...

154

Fuel-NOx Formation during Low-Grade Fuel Combustion in a Swirling-Flow Burner.  

E-Print Network (OSTI)

?? Insufficient knowledge of fireside behavior in the near-burner region during biomass combustion is one of major factors preventing widespread use of this renewable fuel… (more)

Wu, Chunyang

2006-01-01T23:59:59.000Z

155

Fuel-NOx Formation during Low-Grade Fuel Combustion in a Swirling-Flow Burner.  

E-Print Network (OSTI)

??Insufficient knowledge of fireside behavior in the near-burner region during biomass combustion is one of major factors preventing widespread use of this renewable fuel in… (more)

Wu, Chunyang 1975-

2006-01-01T23:59:59.000Z

156

E-Print Network 3.0 - advanced burner test Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

POWER Vol. 21, No. 1, JanuaryFebruary 2005 Summary: each test sequence. IV. Blowout Phenomenology A. Piloted Burner In this section, we describe... attachment to nonattachment at...

157

Evaluation of gas-reburning and low NO{sub x} burners on a wall fired boiler. Technical progress report No. 5, October 1--December 31, 1991  

SciTech Connect

Low NO{sub x} burners operate on the principle of delayed mixing between the coal fuel and burner air, so that less NO{sub x} is formed. Gas reburning is a combustion modification technique that consists of firing 80--85 percent of the fuel corresponding to the total heat release in the lower furnace. Reduction of NO{sub x} to molecular nitrogen (N{sub 2}) is accomplished via the downstream injection of the remaining fuel requirement in the form of natural gas (which also reduces the total SO{sub x} emissions). In a third stage, burnout air is injected at the lower temperatures in the upper furnace to complete the combustion process without generating significant additional NO{sub x}. The specific goal of this project is to demonstrate NO{sub x} emission reductions of 75 percent or more as a result of combing Low NO{sub x} Burners and Gas Reburning on a utility boiler having the design characteristics mentioned above. A Host Site Agreement has been signed by EER and a utility company in the State of Colorado: Public Service Company of Colorado (Cherokee Unit No. 3, 172 MW{sub e}) front wall fired boiler near Denver.

Not Available

1992-01-15T23:59:59.000Z

158

O{sub 2}-mediated oxidation of ferrous nitrosylated human serum heme-albumin is limited by nitrogen monoxide dissociation  

SciTech Connect

Research highlights: {yields} Human serum heme-albumin displays globin-like properties. {yields} O{sub 2}-mediated oxidation of ferrous nitrosylated human serum heme-albumin. {yields} Allosteric modulation of human serum heme-albumin reactivity. {yields} Rifampicin is an allosteric effector of human serum heme-albumin. {yields} Human serum heme-albumin is a ROS and NOS scavenger. -- Abstract: Human serum heme-albumin (HSA-heme-Fe) displays globin-like properties. Here, kinetics of O{sub 2}-mediated oxidation of ferrous nitrosylated HSA-heme-Fe (HSA-heme-Fe(II)-NO) is reported. Values of the first-order rate constants for O{sub 2}-mediated oxidation of HSA-heme-Fe(II)-NO (i.e., for ferric HSA-heme-Fe formation) and for NO dissociation from HSA-heme-Fe(II)-NO (i.e., for NO replacement by CO) are k = 9.8 x 10{sup -5} and 8.3 x 10{sup -4} s{sup -1}, and h = 1.3 x 10{sup -4} and 8.5 x 10{sup -4} s{sup -1}, in the absence and presence of rifampicin, respectively, at pH = 7.0 and T = 20.0 {sup o}C. The coincidence of values of k and h indicates that NO dissociation represents the rate limiting step of O{sub 2}-mediated oxidation of HSA-heme-Fe(II)-NO. Mixing HSA-heme-Fe(II)-NO with O{sub 2} does not lead to the formation of the transient adduct(s), but leads to the final ferric HSA-heme-Fe derivative. These results reflect the fast O{sub 2}-mediated oxidation of ferrous HSA-heme-Fe and highlight the role of drugs in modulating allosterically the heme-Fe-atom reactivity.

Ascenzi, Paolo, E-mail: ascenzi@uniroma3.it [Interdepartmental Laboratory of Electron Microscopy, University Roma Tre, Via della Vasca Navale 79, I-00146 Roma (Italy) [Interdepartmental Laboratory of Electron Microscopy, University Roma Tre, Via della Vasca Navale 79, I-00146 Roma (Italy); National Institute for Infectious Diseases I.R.C.C.S. 'Lazzaro Spallanzani', Via Portuense 292, I-00149 Roma (Italy); Gullotta, Francesca; Gioia, Magda; Coletta, Massimo [Department of Experimental Medicine and Biochemical Sciences, University of Roma 'Tor Vergata', Via Montpellier 1, I-00133 Roma (Italy) [Department of Experimental Medicine and Biochemical Sciences, University of Roma 'Tor Vergata', Via Montpellier 1, I-00133 Roma (Italy); Interuniversity Consortium for the Research on the Chemistry of Metals in Biological Systems, Piazza Umberto I 1, I-87100 Bari (Italy); Fasano, Mauro [Department of Structural and Functional Biology, and Center of Neuroscience, University of Insubria, Via Alberto da Giussano 12a, I-21052 Busto Arsizio, VA (Italy)] [Department of Structural and Functional Biology, and Center of Neuroscience, University of Insubria, Via Alberto da Giussano 12a, I-21052 Busto Arsizio, VA (Italy)

2011-03-04T23:59:59.000Z

159

Fertilizer and Nitrogen 1 billion tons of artificial nitrogen fertilizer used annually.  

E-Print Network (OSTI)

Fertilizer and Nitrogen 1 billion tons of artificial nitrogen fertilizer used annually. Emissions. (fertilizers that use nitric acid or ammonium bicarbonate result in emissions of nitrogen oxides, nitrous oxide, ammonia and carbon dioxide into the atmosphere.) ~Indirect: Phosphorus in excess causes eutrophication

Toohey, Darin W.

160

High-performance tin oxide-nitrogen doped graphene aerogel hybrids as anode materials for lithium-ion batteries  

Science Journals Connector (OSTI)

Abstract Tin dioxide nanoparticles on nitrogen doped graphene aerogel (SnO2-NGA) hybrid are synthesized by one-step hydrothermal method and successfully applied in lithium-ion batteries as a free-standing anode. The electrochemical performance of SnO2-NGA hybrid is investigated by galvanostatic charge–discharge cycling, rate capability test, cyclic voltammetry and electrochemical impedance spectroscopy. It is found that the SnO2-NGA hybrid with freestanding spongy-like structure exhibit remarkable lithium storage capacity (1100 mAh g?1 after 100 cycles), good cycling stability and high rate capability. The outstanding performance is attributed to the uniform SnO2 nanoparticles, unique spongy-like structure and N doping defect for Li+ diffusion.

Chunhui Tan; Jing Cao; Abdul Muqsit Khattak; Feipeng Cai; Bo Jiang; Gai Yang; Suqin Hu

2014-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "nitrogen oxide burner" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Innovative Clean Coal Technology (ICCT): Demonstration of Selective Catalytic Reduction (SCR) technology for the control of nitrogen oxide (NO{sub x}) emissions from high-sulfur coal-fired boilers. Quarterly report No. 6, October--December, 1991  

SciTech Connect

The objective of this project is to demonstrate and evaluate commercially available Selective Catalytic Reduction (SCR) catalysts from US, Japanese and European catalyst suppliers on a high-sulfur US coal-fired boiler. SCR is a post-combustion nitrogen oxide (NOx) control technology that involves injecting ammonia into the flue gas generated from coal combustion in an electric utility boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NOx to convert it to nitrogen and water vapor.

Not Available

1992-02-01T23:59:59.000Z

162

Innovative Clean Coal Technology (ICCT): Demonstration of Selective Catalytic Reduction (SCR) technology for the control of nitrogen oxide (NO sub x ) emissions from high-sulfur coal-fired boilers  

SciTech Connect

The objective of this project is to demonstrate and evaluate commercially available Selective Catalytic Reduction (SCR) catalysts from US, Japanese and European catalyst suppliers on a high-sulfur US coal-fired boiler. SCR is a post-combustion nitrogen oxide (NOx) control technology that involves injecting ammonia into the flue gas generated from coal combustion in an electric utility boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NOx to convert it to nitrogen and water vapor.

Not Available

1992-02-01T23:59:59.000Z

163

Demonstration of selective catalytic reduction (SCR) technology for the control of nitrogen oxide (NOx) emissions from high-sulfur coal-fired boilers. Quarterly report No. 5, July--September 1991  

SciTech Connect

The objective of this project is to demonstrate and evaluate commercially available Selective Catalytic Reduction (SCR) catalysts from US, Japanese and European catalyst suppliers on a high-sulfur US coal-fired boiler. SCR is a post-combustion nitrogen oxide (NO{sub x}) control technology that involves injecting ammonia into the flue gas generated from coal combustion in an electric utility boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NO{sub x} to convert it to nitrogen and water vapor.

Not Available

1991-11-01T23:59:59.000Z

164

Innovative Clean Coal Technology (ICCT): Demonstration of Selective Catalytic Reduction (SCR) technology for the control of nitrogen oxide (NO{sub x}) emissions from high-sulfur coal-fired boilers. Quarterly report No. 2, October--December 1990  

SciTech Connect

The objective of this project is to demonstrate and evaluate commercially available Selective Catalytic Reduction (SCR) catalysts from US, Japanese and European catalyst suppliers on a high-sulfur US coal-fired boiler. SCR is a post-combustion nitrogen oxide NO{sub x} control technology that involves injecting ammonia into the flue gas generated from coal combustion in an electric utility boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NO{sub x} to convert it to nitrogen and water vapor.

Not Available

1991-02-01T23:59:59.000Z

165

Innovative Clean Coal Technology (ICCT): Demonstration of Selective Catalytic Reduction (SCR) technology for the control of nitrogen oxide (NO sub x ) emissions from high-sulfur coal-fired boilers  

SciTech Connect

The objective of this project is to demonstrate and evaluate commercially available Selective Catalytic Reduction (SCR) catalysts from US, Japanese and European catalyst suppliers on a high-sulfur US coal-fired boiler. SCR is a post-combustion nitrogen oxide NO{sub x} control technology that involves injecting ammonia into the flue gas generated from coal combustion in an electric utility boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NO{sub x} to convert it to nitrogen and water vapor.

Not Available

1991-02-01T23:59:59.000Z

166

Innovative clean coal technology (ICCT): Demonstration of selective catalytic reduction (SCR) technology for the control of nitrogen oxide (NO{sub x}) emissions from high-sulfur coal-fired boilers. Quarterly report No. 3, January--March 1991  

SciTech Connect

The objective of this project is to demonstrate and evaluate commercially available Selective Catalytic Reduction (SCR) catalysts from US, Japanese and European catalyst suppliers on a high-sulfur US coal-fired boiler. SCR is a post-combustion nitrogen oxide (NOx) control technology that involves injecting ammonia into the flue gas generated from coal combustion in an electric utility boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NOx to convert it to nitrogen and water vapor.

Not Available

1991-07-01T23:59:59.000Z

167

Innovative clean coal technology (ICCT): Demonstration of selective catalytic reduction (SCR) technology for the control of nitrogen oxide (NO sub x ) emissions from high-sulfur coal-fired boilers  

SciTech Connect

The objective of this project is to demonstrate and evaluate commercially available Selective Catalytic Reduction (SCR) catalysts from US, Japanese and European catalyst suppliers on a high-sulfur US coal-fired boiler. SCR is a post-combustion nitrogen oxide (NOx) control technology that involves injecting ammonia into the flue gas generated from coal combustion in an electric utility boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NOx to convert it to nitrogen and water vapor.

Not Available

1991-07-01T23:59:59.000Z

168

Making a Low-Cost Soda Can Ethanol Burner for Out-of-Laboratory Flame Test Demonstrations and Experiments  

Science Journals Connector (OSTI)

Making a Low-Cost Soda Can Ethanol Burner for Out-of-Laboratory Flame Test Demonstrations and Experiments ... Video clips for the three flame tests shown in Figure 3, and for turning the burner on and off. ...

Henson L. Lee Yu; Perfecto N. Domingo, Jr.; Elliard Roswell S. Yanza; Armando M. Guidote, Jr.

2014-10-13T23:59:59.000Z

169

Slurry burner for mixture of carbonaceous material and water  

DOE Patents (OSTI)

A carbonaceous material-water slurry burner includes a high pressure tip-emulsion atomizer for directing a carbonaceous material-water slurry into a combustion chamber for burning therein without requiring a support fuel or oxygen enrichment of the combustion air. Introduction of the carbonaceous material-water slurry under pressure forces it through a fixed atomizer wherein the slurry is reduced to small droplets by mixing with an atomizing air flow and directed into the combustion chamber. The atomizer includes a swirler located immediately adjacent to where the fuel slurry is introduced into the combustion chamber and which has a single center channel through which the carbonaceous material-water slurry flows into a plurality of diverging channels continuous with the center channel from which the slurry exits the swirler immediately adjacent to an aperture in the combustion chamber. The swirler includes a plurality of slots around its periphery extending the length thereof through which the atomizing air flows and by means of which the atomizing air is deflected so as to exert a maximum shear force upon the carbonaceous material-water slurry as it exits the swirler and enters the combustion chamber. A circulating coolant system or boiler feed water is provided around the periphery of the burner along the length thereof to regulate burner operating temperature, eliminate atomizer plugging, and inhibit the generation of sparklers, thus increasing combustion efficiency. A secondary air source directs heated air into the combustion chamber to promote recirculation of the hot combustion gases within the combustion chamber.

Nodd, Dennis G. (West Mifflin, PA); Walker, Richard J. (Bethel Park, PA)

1987-01-01T23:59:59.000Z

170

Real Time Flame Monitoring of Gasifier Burner and Injectors  

NLE Websites -- All DOE Office Websites (Extended Search)

Real Time Flame Monitoring of Gasifier Real Time Flame Monitoring of Gasifier Burner and Injectors Background The Gasification Technologies Program at the National Energy Technology Laboratory (NETL) supports research and development (R&D) in the area of gasification-a process whereby carbon-based materials (feedstocks) such as coal are converted into synthesis gas (syngas), which is separated into hydrogen (H 2 ) and carbon dioxide (CO 2 ) gas streams in a combustion turbine-generator as a way to generate clean electricity while

171

REAL TIME FLAME MONITORING OF GASIFIER BURNER AND INJECTORS  

SciTech Connect

This report is submitted to the United States Department of Energy in partial fulfillment of the contractual requirements for Phase I of the project titled, ''Real Time Flame Monitoring of Gasifier Burner and Injectors'', under co-operative agreement number DE-FS26-02NT41585. The project is composed of three one-year budget periods. The work in each year is divided into separate Tasks to facilitate project management, orderly completion of all project objectives, budget control, and critical path application of personnel and equipment. This Topical Report presents results of the Task 1 and 2 work. The 2 D optical sensor was developed to monitor selected UV and visible wavelengths to collect accurate flame characterization information regarding mixing, flame shape, and flame rich/lean characteristic. Flame richness, for example, was determined using OH and CH intensity peaks in the 300 to 500 nanometer range of the UV and visible spectrum. The laboratory burner was operated over a wide range of air to fuel ratio conditions from fuel rich to fuel lean. The sooty oxygen enriched air flames were established to test the sensor ability to characterize flame structures with substantial presence of hot solid particles emitting strong ''black body radiation''. The knowledge gained in these experiments will be very important when the sensor is used for gasifier flame analyses. It is expected that the sensor when installed on the Global Energy gasifier will be exposed to complex radiation patterns. The measured energy will be a combination of spectra emitted by the combusting gases, hot solid particulates, and hot walls of the gasifier chamber. The ability to separate flame emissions from the ''black body emissions'' will allow the sensor to accurately determine flame location relative to the gasifier walls and the injectors, as well as to analyze the flame's structure and condition. Ultimately, this information should enable the gasification processes to be monitored and controlled and as a result increase durability and efficiency of the gasifier. To accomplish goals set for Task 2 GTI will utilize the CANMET Coal Gasification Research facility. The Entrained Coal Gasifier Burner Test Stand has been designed and is currently under construction in the CANMET Energy Technology Center (CETC), the research and technology arm of Natural Resources Canada (NRCan). This Gasifier Burner Stand (GBS) is a scaled-down mock-up of a working gasifier combustion system that can provide the flexible platform needed in the second year of the project to test the flame sensor. The GBS will be capable of simulating combustion and gasification processes occurring in commercial gasifiers, such as Texaco, Shell, and Wabash River.

James Servaites; Serguei Zelepouga; David Rue

2003-10-01T23:59:59.000Z

172

Characterization of syngas laminar flames using the Bunsen burner configuration  

Science Journals Connector (OSTI)

Laminar flame speeds of syngas mixtures (H2/CO/Air) have been studied using the Bunsen flame configuration with both straight and nozzle burners. The flame surface area and flame cone angle methodologies, respectively based on the OH* chemiluminescence and Schlieren imaging techniques, have been performed to extract flame speeds for a wide range of equivalence ratios (0.3 syngas flames with 0.6 < ? < 1.0 and 10% < %H2 < 70% is proposed. A particular attention has been devoted to the development and validation of the OH* chemiluminescence methodology with the identification of important parameters governing the measurement accuracy.

N. Bouvet; C. Chauveau; I. Gökalp; S.-Y. Lee; R.J. Santoro

2011-01-01T23:59:59.000Z

173

Clean coal technology: selective catalytic reduction (SCR) technology for the control of nitrogen oxide emissions from coal-fired boilers  

SciTech Connect

The report discusses a project carried out under the US Clean Coal Technology (CCT) Demonstration Program which demonstrated selective catalytic reduction (SCR) technology for the control of NOx emissions from high-sulphur coal-fired boilers under typical boilers conditions in the United States. The project was conducted by Southern Company Services, Inc., who served as a co-funder and as the host at Gulf Power Company's Plant Crist. The SCR process consists of injecting ammonia (NH{sub 3}) into boiler flue gas and passing the flue gas through a catalyst bed where the Nox and NH{sub 3} react to form nitrogen and water vapor. The results of the CCTDP project confirmed the applicability of SCR for US coal-fired power plants. In part as a result of the success of this project, a significant number of commercial SCR units have been installed and are operating successfully in the United States. By 2007, the total installed SCR capacity on US coal-fired units will number about 200, representing about 100,000 MWe of electric generating capacity. This report summarizes the status of SCR technology. 21 refs., 3 figs., 2 tabs., 10 photos.

NONE

2005-05-01T23:59:59.000Z

174

Industrial pulverized coal low-NO{sub x} burner. Phase 1, Final report  

SciTech Connect

Arthur D. Little, Inc., jointly with its university partner, the Massachusetts Institute of Technology, and its industrial partner, Hauck Manufacturing Corporation, is developing a low NO{sub x} pulverized coal burner for use in industrial processes, including those which may require preheated air or oxygen enrichment. The design of the burner specifically addresses the critical performance requirements of industrial systems, namely: high heat release rates, short flames, even heat flux distribution, and high combustion efficiency. The design is applicable to furnaces, industrial boilers, and cement kilns. The development program for this burner includes a feasibility analysis, performance modelling, development of the burner prototype design, and assessment of the economic viability of the burner. The Phase 1 activities covered by this report consisted of three principal tasks: preliminary burner design; fluid flow/combustion modelling and analyses; and market evaluation. The preliminary design activities included the selection of a design coal for the Phase 1 design, preliminary design layout, and preliminary sizing of the burner components. Modelling and analysis were conducted for the coal pyrolysis zone, the rich combustion zone and the lean bumout zone. Both chemical kinetics and one-dimensional coal combustion modelling were performed. The market evaluation included a review of existing industrial coal use, identification of potential near- and long-term markets and an assessment of the optimum burner sizes.

Not Available

1993-12-01T23:59:59.000Z

175

Low NOx burner retrofits and enhancements for a 518 MW oil and gas fired boiler  

SciTech Connect

Low NOx oil/gas burners originally supplied to Jacksonville Electric Authority, Northside No. 3 .500 MW unit, were based on a duplex air register design with lobed spray oil atomizers providing additional fuel staging. Although the burners could meet the targeted NOx levels of 0.3 and 0.2 lbs/10{sup 6} BTU on oil and gas respectively. There was insufficient margin on these NOx levels to enable continuous low NOx operation to be achieved. Further burner development was undertaken based on improved aerodynamic control within the burner design to give an approximate 25% improvement in NOx emission reduction thus providing an adequate operating margin. This `RoBTAS` (Round Burner with Tilted Air Supply) burner design based on techniques developed successfully for front wall coal firing applications achieved the required NOx reductions in full scale firing demonstrations on both heavy fuel oil and natural gas firing. The paper describes the development work and the subsequent application of the `RoBTAS` burners to the Northside No. 3 boiler. The burner will also be test fired on Orimulsion fuel and thus the comparison between heavy fuel oil firing and Orimulsion firing under ultra low NOx conditions will be made.

King, J.J. [Jacksonville Electric Authority, FL (United States); Allen, J.W.; Beal, P.R. [International Combustion Ltd., Derby (United Kingdom). Rolls-Royce Industrial Power Group

1995-12-31T23:59:59.000Z

176

Establishing criteria for the design of a combination parallel and cross-flaming covered burner  

E-Print Network (OSTI)

-mm in the crop row and height 7-mm in the left and right furrows. Burners traveled at a designated speed (2, 3.5, or 5 km/h) and burner operating pressure combination (207, 276, or 345 kPa). Time versus temperature curves were generated...

Stark, Christopher Charles

2003-01-01T23:59:59.000Z

177

Synthesis of graphene with both high nitrogen content and high surface area by annealing composite of graphene oxide and g-C3N4  

Science Journals Connector (OSTI)

In this paper, we propose a facile, catalyst-free thermal annealing approach for synthesis of N-doping graphene (NG) using graphitic carbon nitride (g...3N4) as the nitrogen source. Graphene with nitrogen content...

Yurong Deng; Kewei Liu; Hongmei Cao…

2014-10-01T23:59:59.000Z

178

NETL: PPII - Integration of Low-NOx Burners with an Optimization Plan for  

NLE Websites -- All DOE Office Websites (Extended Search)

Integration of Low-NOx Burners with an Optimization Plan for Boiler Combustion Integration of Low-NOx Burners with an Optimization Plan for Boiler Combustion - Project Brief [PDF-72KB] Sunflower Electric Power Corp., Garden City, Finney County, KS PROJECT FACT SHEET Achieving New Source Performance Standards (NSPS) Through Integration of Low-NOx Burners with an Optimization Plan for Boiler Combustion [PDF-260KB] (Oct 2008) PROGRAM PUBLICATIONS Final Report Achieving NSPS Emission Standards Through Integration of Low NOx Burners with an Optimization Plan for Boiler Combustion [PDF-3.4MB] (June 2006) CCT Reports: Project Performance Summaries, Post-Project Assessments, & Topical Reports Achieving New Source Performance Standards (NSPS) Emission Standards through Integration of Low-NOx Burners with an Optimization Plan for Boiler Combustion: A DOE Assessment [PDF-1.4MB] (Nov 2006)

179

Nitrogen sorption  

DOE Patents (OSTI)

Nitrogen-sorbing and -desorbing compositions and methods of using the same are disclosed, which are useful for the selective separation of nitrogen from other gases, especially natural gas.

Friesen, Dwayne T. (Bend, OR); Babcock, Walter C. (Bend, OR); Edlund, David J. (Bend, OR); Miller, Warren K. (Bend, OR)

1996-01-01T23:59:59.000Z

180

Nitrogen sorption  

DOE Patents (OSTI)

Nitrogen-sorbing and -desorbing compositions and methods of using the same are disclosed, which are useful for the selective separation of nitrogen from other gases, especially natural gas.

Friesen, Dwayne T. (Bend, OR); Babcock, Walter C. (Bend, OR); Edlund, David J. (Bend, OR); Miller, Warren K. (Bend, OR)

1993-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "nitrogen oxide burner" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Nitrogen sorption  

DOE Patents (OSTI)

Nitrogen-sorbing and -desorbing compositions and methods of using the same are disclosed, which are useful for the selective separation of nitrogen from other gases, especially natural gas.

Friesen, D.T.; Babcock, W.C.; Edlund, D.J.; Miller, W.K.

1993-07-06T23:59:59.000Z

182

Nitrogen sorption  

DOE Patents (OSTI)

Nitrogen-sorbing and -desorbing compositions and methods of using the same are disclosed, which are useful for the selective separation of nitrogen from other gases, especially natural gas. 5 figs.

Friesen, D.T.; Babcock, W.C.; Edlund, D.J.; Miller, W.K.

1996-05-14T23:59:59.000Z

183

Multilayer films of indium tin oxide/TiO2 codoped with vanadium and nitrogen for efficient photocatalytic water splitting  

Science Journals Connector (OSTI)

TiO22 films codoped with V cations and N anions were synthesised by RF-magnetron sputtering. The incorporation of V and N in TiO2 lattice produces isolated energy levels near the conduction and valence bands, respectively, causing an effective narrowing of the band gap to 2.5 eV. Recombination of photo-charges was reduced by depositing multilayer films of indium tin oxide (ITO)/V-N-codoped TiO2 with different numbers of bilayers. In multilayer structure, the generated photoelectrons, travelling into TiO2 film of limited thickness, rapidly enter the space charge interface of the ITO/TiO2 films from where they are instantaneously injected into the ITO layer and then removed towards the cathode. The synergic effects created by band narrowing and enhanced charge separation by using codoping and multilayer structure strategy in TiO2 generate higher photocurrent for water splitting under visible light which definitely exceeds that obtained by doping TiO2 with a single, V or N, element.

Z. El Koura; N. Patel; R. Edla; A. Miotello

2014-01-01T23:59:59.000Z

184

Personal and Ambient Air Pollution is Associated with Increased Exhaled Nitric Oxide in Children with Asthma  

E-Print Network (OSTI)

1994. Nitric oxide and nitrogen dioxide: Method 6014. In:Molecular mechanisms of nitrogen dioxide induced epithelialEC, OC), and 24-hr nitrogen dioxide. Ambient exposures

2006-01-01T23:59:59.000Z

185

Effects of Fuel-Side Nitrogen Dilution on Structure and NOx Formation of Turbulent Syngas Non-premixed Jet Flames  

Science Journals Connector (OSTI)

In this syngas non-premixed burner, the nozzle inner and outer diameters are 7.72 mm and 9.46 mm, respectively. ... Prathap, C.; Ray, A.; Ravi, M. R.Investigation of nitrogen dilution effects on laminar burning velocity and flame stability of syngas fuel at atmospheric condition Combust. ...

Jeongwon Lee; Sangwoon Park; Yongmo Kim

2012-05-01T23:59:59.000Z

186

Low NOx modifications on front-fired pulverized coal fuel burners  

SciTech Connect

Burner optimizations and modifications were performed on Public Service of New Hampshire`s Schiller Units 4, 5, and 6. These are Foster-Wheeler 50 MWg pulverized coal and No.6 fuel oil-fired boilers with six burners each. Burner optimizations consisted of fuel flow, primary air, secondary air testing and balancing. Burner modifications consisted of the addition of circumferentially and radially staged flame stabilizers, circumferentially-staged coal spreaders, and modifications to the existing pulverized coal pipe. NO{sub x} emissions on Unit 6 of .41 lb/mmBtu were achieved at optimized burner settings at full load with all burners in service and without the use of overfire air or bias firing. This represented a 50% NO{sub x} reduction from the average pre-modification baseline NO{sub x} emissions of .81 lb/mmBtu prior to the optimizations and burner modification program. NO{sub x} emissions as low as .38 lb/mmBtu were achieved with the use of overfire air. There was essentially no quantifiable change in LOIs (baseline LOIs averaged 40%). Furnace excess O{sub 2} as low as 1.2% was achieved with CO emissions of less than 200 ppm. Total installed costs including the overfire air system were approximately $7/kW.

Owens, B.; Hitchko, M. [Public Service of New Hampshire, Manchester, NH (United States); Broderick, R.G. [RJM Corp., Ridgefield, CT (United States)

1996-01-01T23:59:59.000Z

187

Process and apparatus for igniting a burner in an inert atmosphere  

DOE Patents (OSTI)

According to this invention there is provided a process and apparatus for the ignition of a pilot burner in an inert atmosphere without substantially contaminating the inert atmosphere. The process includes the steps of providing a controlled amount of combustion air for a predetermined interval of time to the combustor then substantially simultaneously providing a controlled mixture of fuel and air to the pilot burner and to a flame generator. The controlled mixture of fuel and air to the flame generator is then periodically energized to produce a secondary flame. With the secondary flame the controlled mixture of fuel and air to the pilot burner and the combustion air is ignited to produce a pilot burner flame. The pilot burner flame is then used to ignited a mixture of main fuel and combustion air to produce a main burner flame. The main burner flame then is used to ignite a mixture of process derived fuel and combustion air to produce products of combustion for use as an inert gas in a heat treatment process.

Coolidge, Dennis W. (Katy, TX); Rinker, Franklin G. (Perrysburg, OH)

1994-01-01T23:59:59.000Z

188

Simulation Modeling of an Enhanced Low-Emission Swirl-Cascade Burner  

SciTech Connect

''Cascade-burners'' is a passive technique to control the stoichiometry of the flame through changing the flow dynamics and rates of mixing in the combustion zone with a set of venturis surrounding the flame. Cascade-burners have shown advantages over other techniques; its reliability, flexibility, safety, and cost makes it more attractive and desirable. On the other hand, the application of ''Swirl-burners'' has shown superiority in producing a stable flame under a variety of operating conditions and fuel types. The basic idea is to impart swirl to the air or fuel stream, or both. This not only helps to stabilize the flame but also enhances mixing in the combustion zone. As a result, nonpremixed (diffusion) swirl burners have been increasingly used in industrial combustion systems such as gas turbines, boilers, and furnaces, due to their advantages of safety and stability. Despite the advantages of cascade and swirl burners, both are passive control techniques, which resulted in a moderate pollutant emissions reduction compared to SCR, SNCR and FGR (active) methods. The present investigation will study the prospects of combining both techniques in what to be named as ''an enhanced swirl-cascade burner''. Natural gas jet diffusion flames in baseline, cascade, swirl, and swirl-cascade burners were numerically modeled using CFDRC package. The thermal, composition, and flow (velocity) fields were simulated. The numerical results showed that swirl and cascade burners have a more efficient fuel/air mixing, a shorter flame, and a lower NOx emission levels, compared to the baseline case. The results also revealed that the optimal configurations of the cascaded and swirling flames have not produced an improved performance when combined together in a ''swirl-cascade burner''. The non-linearity and complexity of the system accounts for such a result, and therefore, all possible combinations, i.e. swirl numbers (SN) versus venturi diameter ratios (D/d), need to be considered.

Ala Qubbaj

2004-09-01T23:59:59.000Z

189

Real Time Flame Monitoring of Gasifier Burner and Injectors  

NLE Websites -- All DOE Office Websites (Extended Search)

8 8 Gasification Technologies contacts Gary J. stiegel Gasification Technology Manager National Energy Technology Laboratory 626 Cochrans Mill Road P.O. Box 10940 Pittsburgh, PA 15236 412-386-4499 gary.stiegel@netl.doe.gov Jenny tennant Project Manager National Energy Technology Laboratory 3610 Collins Ferry Road P.O. Box 880 Morgantown, WV 26507 304-285-4830 jenny.tennant@netl.doe.gov David Rue Principal Investigator Gas Technology Institute 1700 South Mount Prospect Road Des Plaines, IL 60018 847-768-0508 david.rue@gastechnology.org Real Time Flame moniToRing oF gasiFieR BuRneR and injecToRs Description Combustion scientists and engineers have studied radiant emissions of various flames for many years. For some time, technologists have understood the rich potential for

190

Heat transfer and combustion characteristics of a burner with a rotary regenerative heat exchanger  

SciTech Connect

The authors have developed a Rotary Regenerative Combustion (RRX) System, which is coupled with a compact high efficiency regenerative air heat exchanger and a combustion burner. This system contributes to saving energy of fuel firing industrial furnaces and decreases NO{sub x} emission. This technology can be considered as a solution of greenhouse problem. This paper, discusses a compact high efficiency regenerative air heat exchanger in comparison with the existing types of regenerative burners and reverse firing with high momentum fuel jet (with motive fluid) in the furnace. This burner is compact in size, with high fuel efficiency, low NOx emission, easy to operate, and reliable, based on the results of field tests and commercial operations. The authors can say that the RRX system is a regenerative burner of the second generation.

Hirose, Yasuo; Kaji, Hitoshi; Arai, Norio

1998-07-01T23:59:59.000Z

191

A Small Scale Solar Agricultural Dryer with Biomass Burner and Heat Storage Back-Up Heater  

Science Journals Connector (OSTI)

This paper describes a small scale solar agricultural dryer with a simple biomass burner and heat storage back-up heater. The key design features ... are the combination of direct and indirect type solar dryer, t...

Elieser Tarigan; Perapong Tekasakul

2009-01-01T23:59:59.000Z

192

Characterization of a gas burner to simulate a propellant flame and evaluate aluminum particle combustion  

SciTech Connect

This study details the characterization and implementation of a burner designed to simulate solid propellant fires. The burner was designed with the ability to introduce particles (particularly aluminum) into a gas flame. The aluminized flame conditions produced by this burner are characterized based on temperature and heat flux measurements. Using these results, flame conditions are quantified in comparison to other well-characterized reactions including hydrocarbon and propellant fires. The aluminized flame is also used to measure the burning rate of the particles. This work describes the application of this burner for re-creating small-scale propellant flame conditions and as a test platform for experiments that contribute to the development of a particle combustion model, particularly in propellant fires. (author)

Jackson, Matt [Engineering Department, West Texas A and M University, Canyon, TX 79016 (United States); Pantoya, Michelle L. [Mechanical Engineering Department, Texas Tech University, Lubbock, TX 79409 (United States); Gill, Walt [Sandia National Laboratories, Albuquerque, NM 87185 (United States)

2008-04-15T23:59:59.000Z

193

Optimization of Gas Nozzles Geometry in Dual-Fuel Burners of Power Stations  

Science Journals Connector (OSTI)

Thermal power required by boilers in steam power stations is supplied through gas or heavy oil fueled burners. Incorrect functioning ... in the boilers of Shazand 325 MW power station in Arak. Gas-fueled nozzles ...

Ebrahim Moussavi Torshizi…

2008-08-01T23:59:59.000Z

194

Variable firing rate power burner for high efficiency gas furnaces. Final report  

SciTech Connect

One method for increasing the efficiency of residential furnaces and boilers is to retrofit a burner capable of firing rate (FR) modulation. While maximum FR is still attainable, the average FR is significantly lower, resulting in more effective heat exchanger performance. Equally important is the capability for continuous firing at a very low rate (simmering) which eliminates off-cycle loss, a heavy contributor to inefficiency. Additional performance can be gained by reducing the excess air required by a burner. Based on its previous experience, Foster-Miller Associates, Inc. has designed and tested a low excess air (about 15%) variable firing rate (VFR) burner. The theory of operation and the construction of the test burner are described. Test results are given along with a conclusion/recommendation. A Phase II plan is outlined which suggests methods and steps for fabrication and field testing of a number of prototype units.

Fuller, H.H.; Demler, R.L.; Poulin, E.

1980-02-01T23:59:59.000Z

195

Refractory products and ramming bodies for high pressure burners of steam boilers  

Science Journals Connector (OSTI)

Silicon carbide rammed bodies are suitable for lining the combustion zones of high-pressure cyclone burners of steam boilers. The life of the silicon carbide body depends on the heat resistance of the supporti...

N. I. Voronin; N. I. Krasotkina; A. I. kulik; T. S. Karmanova; G. E. Levin…

196

An experimental study on combustion processes and nox emission characteristics of the air-staged burner  

Science Journals Connector (OSTI)

The combustion processes and emission characteristics in air-staged burner...5H5N) is used to investigate the fuel NOX emission characteristics. Experiments are carried out for a wide range of operating condition...

Kook-Young Ahn; Han-Seok Kim; Eun-Seong Cho; Jin-Hyuk Ahn…

1999-06-01T23:59:59.000Z

197

Low NOx Burner Design and Analysis for Conceptual Design of Oxygen-Based PC Boiler  

SciTech Connect

The objective of the low NOx burner design and analysis task of the Conceptual Design of Oxygen-Based PC Boiler study is to optimize the burner design to ensure stable ignition, to provide safe operation, and to minimize pollutant formation. The burners were designed and analyzed using the Fluent computer program. Four burner designs were developed: (1) with no over-fire gas (OFG) and 65% flue gas recycle, (2) with 20% OFG and 65% flue gas recycle, (3) with no OFG and 56% flue gas recycle and (4) with 20% OFG and 56% flue gas recycle. A 3-D Fluent simulation was made of a single wall-fired burner and horizontal portion of the furnace from the wall to the center. Without primary gas swirl, coal burnout was relatively small, due to the low oxygen content of the primary gas stream. Consequently, the burners were modified to include primary gas swirl to bring the coal particles in contact with the secondary gas. An optimal primary gas swirl was chosen to achieve sufficient burnout.

Andrew Seltzer

2005-05-01T23:59:59.000Z

198

Modeling Population Exposures to Pollutants Emitted from Natural Gas Cooking Burners  

E-Print Network (OSTI)

air exchange rate, nitrogen dioxide, carbon monoxidemonoxide (CO), nitrogen dioxide (NO 2 ), formaldehyde,

Lobscheid, Agnes

2012-01-01T23:59:59.000Z

199

6/4/2013 Page 1 of 12 Nitrogen Dioxide SOP Standard Operating Procedures  

E-Print Network (OSTI)

6/4/2013 Page 1 of 12 Nitrogen Dioxide SOP Standard Operating Procedures Nitrogen Dioxide and Nitric Oxide Print a copy and insert into your laboratory the precautions and safe handling procedures for the use of Nitrogen Dioxide

Cohen, Ronald C.

200

The carbon footprint analysis of wastewater treatment plants and nitrous oxide emissions from full-scale biological nitrogen removal processes in Spain  

E-Print Network (OSTI)

This thesis presents a general model for the carbon footprint analysis of advanced wastewater treatment plants (WWTPs) with biological nitrogen removal processes, using a life cycle assessment (LCA) approach. Literature ...

Xu, Xin, S.M. Massachusetts Institute of Technology

2013-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "nitrogen oxide burner" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Development, Application and Performance of Venturi Register L. E. A. Burner System for Firing Oil and Gas Fuels  

E-Print Network (OSTI)

DEVELOPMENT, APPLICATION AND PERFORMANCE OF VENTURI REGISTER L. E. A. BURNER SYSTEM FOR FIRING OIL AND GAS FUELS A. D. Cawte CEA Combustion, Inc. Stamford, Connecticut INTRODUCTION The effect of reducing excess air as a means of curtailing..., extensive investigation work was undertaken us ing the water analog model techniques developed by Associated British Combustion for burner design. The development work resulted in the burner design known today as the Venturi Register, LEA (low excess air...

Cawte, A. D.

1979-01-01T23:59:59.000Z

202

Latest developments and application of DB Riley's low NOx CCV{reg{underscore}sign} burner technology  

SciTech Connect

Recent developments in DB Riley (DBR) low NOx burner technology and the application of this technology in coal fired utility boilers are discussed. Since the promulgation of the Clean Air Act Amendment in 1990, DBR has sold nearly 1,500 Controlled Combustion Venturi (CCV{reg{underscore}sign}) burners on pulverized coal fired utility boilers reducing NOx emissions 50--70% from uncontrolled levels. This technology has been retrofitted on boiler designs ranging in size and type from 50 MW front wall fired boilers to 1,300 MW opposed fired cell type boilers. In DBR's latest version of the CCV{reg{underscore}sign} burner, a second controlled flow air zone was added to enhance NOx control capability. Other developments included improved burner air flow measurement accuracy and several mechanical design upgrades such as new coal spreader designs for 3 year wear life. Test results of the CCV{reg{underscore}sign} dual air zone burner in DBR's 100 million Btu/hr (29 MW) coal burner test facility are presented. In the test program, coals from four utility boiler sites were fired to provide a range of coal properties. A baseline high volatile bituminous coal was also fired to provide a comparison with 1992 test data for the CCV{reg{underscore}sign} single register burner. The tests results showed that the second air zone enhanced NOx reduction capability by an additional 20% over the single register design. Computational fluid dynamic (DFD) modeling results of the CCV{reg{underscore}sign} dual air zone burner are also presented showing near field mixing patterns conducive to low NOx firing. DBR was recently awarded Phase IV of the Low Emission Boiler System (LEBS) program by the US Department of Energy to build a proof of concept facility representing the next major advancement in pulverized coal burning technology. A key part of winning that award were test results of the CCV{reg{underscore}sign} dual air zone burner with advanced air staging and coal reburning in a 100 million Btu/hr (20 MW) U-fired slagging combustor test facility. These results showed NOx emissions of less than 0.2 lb/million Btu (0.086 g/MJ) while converting the coal ash into an inert, non-leachable solid. This results is an 80% reduction in NOx emissions from currently operating U-fired slagging boilers.

Penterson, C.; Ake, T.

1998-07-01T23:59:59.000Z

203

Microscopic characteristics of solid particles in opposed multi-burner gasifier  

Science Journals Connector (OSTI)

Abstract The microscopic characteristics of solid particles have important influence on the formation of fluid slag, coarse slag and fine slag during entrained-flow gasification process. Based on the bench-scale opposed multi-burner (OMB) gasifier, solid particles were sampled at different axial distances along the gasifier chamber under typical operating conditions (oxygen and carbon atomic ratio at 1.0). The microscopic characteristics of solid particles were studied by using N2 adsorption-desorption and scanning electron microscopy (SEM) methods. The results show that the solid particles are comprised mainly of porous irregular particle and spherical particle, and few solid particles generated at burner plane perform as dense irregular and hollow shape. As the gasification reaction proceeds along the axis of gasifier, the surface structure of particles becomes rougher, and the pore structure increases. The isotherms of particle samples are all type II, and the particle samples consist of continuous and complete system of pores. The hysteresis loops are H3-type, and there are a large amount of fractured pores. BET surface area and pore volume increase with increasing distance from the burner plane, and average pore diameter gradually reduces, and larger changes occur in the vicinity of the burner plane. The mesopores less than 10 nm vary apparently and increase with increasing distances from the burner plane, while the pores larger than 10 nm are almost unchanged.

Li-jun SUN; Yan GONG; Qing-hua GUO; Guang-suo YU

2014-01-01T23:59:59.000Z

204

Thermophotovoltaic power generation systems using natural gas-fired radiant burners  

Science Journals Connector (OSTI)

Thermophotovoltaic (TPV) power generation in gas-fired furnaces is attracting technical attention. Considerable work has been done in the area of low bandgap GaSb cell-based TPV systems as well as silicon solar cell-based TPV systems. Previous investigations have shown that a radiant burner with a high conversion level of fuel to radiation energy must be developed to realize an efficient TPV system. In our work, we investigated different natural gas-fired radiant burners in order to raise the conversion of fuel energy to thermal radiation. These burners were used as radiation sources to establish and test two TPV prototype systems. It was found that for a non-surface combustion radiant burner, the radiation output can be enhanced using a thermal radiator with a porous structure. Also, we developed a cascaded radiant burner that generates two streams of radiation output. One stream illuminates silicon concentrator solar cells while the other drives low bandgap GaSb cells. In this way, useful radiation output and thus TPV system efficiency are significantly increased due to the cascaded utilization of combustion heat and optimized thermal management.

K. Qiu; A.C.S. Hayden

2007-01-01T23:59:59.000Z

205

Stability Regimes of Turbulent Nitrogen-Diluted Hydrogen Jet Flames  

SciTech Connect

One option for combustion in zero-emission Integrated Gasification Combined Cycle (IGCC) power plants is non-premixed combustion of nitrogen-diluted hydrogen in air. An important aspect to non-premixed combustion is flame stability or anchoring, though only a few fundamental stability studies of these flames have taken place to date. The following paper presents the results of experiments investigating the effects of nitrogen diluent fraction, jet diameter, and exit velocity on the static stability limits of a turbulent hydrogen jet flame issuing from a thin-lipped tube into a quiescent atmosphere. Four different stability limits are observed: detachment from the burner lip, reattachment to the burner lip, transition from a laminar lifted flame base to blowout or to a turbulent lifted flame, and transition from a turbulent lifted flame to blowout. The applicability of existing theories and correlations to the stability results is discussed. These results are an important step in assessing the viability of a non-premixed combustion approach using hydrogen diluted with nitrogen as a fuel.

Weiland, N.T.; Strakey, P.A.

2007-03-01T23:59:59.000Z

206

Electrochemical process for the preparation of nitrogen fertilizers  

DOE Patents (OSTI)

The present invention provides methods and apparatus for the preparation of nitrogen fertilizers including ammonium nitrate, urea, urea-ammonium nitrate, and/or ammonia utilizing a source of carbon, a source of nitrogen, and/or a source of hydrogen. Implementing an electrolyte serving as ionic charge carrier, (1) ammonium nitrate is produced via the reduction of a nitrogen source at the cathode and the oxidation of a nitrogen source at the anode; (2) urea or its isomers are produced via the simultaneous cathodic reduction of a carbon source and a nitrogen source; (3) ammonia is produced via the reduction of nitrogen source at the cathode and the oxidation of a hydrogen source at the anode; and (4) urea-ammonium nitrate is produced via the simultaneous cathodic reduction of a carbon source and a nitrogen source, and anodic oxidation of a nitrogen source. The electrolyte can be solid.

Aulich, Ted R.; Olson, Edwin S.; Jiang, Junhua

2013-03-19T23:59:59.000Z

207

Study of the effects of ambient conditions upon the performance of fan powered, infrared, natural gas burners. Quarterly technical progress report, October 1, 1995--December 31, 1995  

SciTech Connect

Infrared burner is a surface combustor that elevates the temperature of the burner head to a radiant condition. Applications of radiant burners includes boilers, air heaters, deep fat fryers, process heaters, and immersion heaters. On reason for the present interest in this type of burner is its low NO{sub x} emissions, which is attributed to the fact that a large proportion of the combustion heat is given out as radiation from the burner surface, which results in relatively low gas temperature in the combustion zone compared to that of a conventional free-flame burner. As a consequence, such burners produce less NO{sub x}, mainly by the so-called prompt-NO mechanism. A porous radiant burner testing facility was built, consisting of spectral radiance as well as flue gas composition measurements. Measurement capabilities were tested using methane; results were consistent with literature.

Bai, Tiejun; Yeboah, Y.D.; Sampath, R.

1996-01-01T23:59:59.000Z

208

500 MW demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NO[sub x]) emissions from coal-fired boilers  

SciTech Connect

The project provides a stepwise retrofit of an advanced overfire air (AOFA) system followed by low NO[sub x] burners (LNB). During each test phase of the project, diagnostic, performance, long-term, and verification testing will be performed. These tests are used to quantify the NO[sub x] reductions of each technology and evaluate the effects of those reductions on other combustion parameters such as particulatecharacteristics and boiler efficiency. Baseline, AOFA, and LNB without AOFA test segments have been completed. Analysis of the 94 days of LNB long-term data collected show the full-load NO[sub x] emission levels to be approximately 0.65 lb/MBtu. Flyash LOI values for the LNB configuration are approximately 8 percent at full-load. Corresponding values for the AOFA configuration are 0.94 lb/MBtu and approximately 10 percent. Abbreviated diagnostic tests for the LNB+AOFA configuration indicate that at 500 MWe, NO[sub x] emissions are approximately 0.55 lb/MBtu with corresponding flyash LOI values of approximately 11 percent. For comparison, the long-term full-load, baseline NO[sub x] emission level was approximately 1.24 lb/MBtu at 5.2 percent LOI. Comprehensive testing of the LNB+AOFA configuration will be performed when the stackparticulate emissions issue is resolved. Testing of a process optimization package on Plant Hammond Unit 4 was performed during this quarter. The software was configured to minimize NO[sub x] emissions using total combustion air flow and advanced overfire air distribution as the controlled parameters. Preliminary results from this testing indicate that this package shows promise in reducing NO[sub x] emissions while maintaining or improving other boiler performance parameters.

Not Available

1992-01-01T23:59:59.000Z

209

SIMULATION MODELING OF AN ENHANCED LOW-EMISSION SWIRL-CASCADE BURNER  

SciTech Connect

Based on the physical and computational models outlined in the previous technical progress reports, Natural gas jet diffusion flames in baseline, cascade, swirl, and swirlcascade burners were numerically modeled. The thermal, composition, and flow (velocity) fields were simulated. The temperature, CO{sub 2} and O{sub 2} concentrations, as well as the axial and radial velocity profiles were computed and analyzed. The numerical results showed that swirl and cascade burners have a more efficient fuel/air mixing, a shorter flame, and a lower NOx emission levels, compared to the baseline case. The results also revealed that the optimal configurations of the cascaded and swirling flames have not produced an improved performance when combined together in a ''swirl-cascade burner''.

Ala Qubbaj

2004-04-01T23:59:59.000Z

210

System approach to reducing NO{sub x} emissions on a three cell high burner, heavy oil-fired boiler  

SciTech Connect

This paper documents the installation of plug-in low NO{sub x} burners on a utility boiler with cell burners. The original rapid mix burners and typical close burner centerline spacing produced a very hot furnace environment resulting in extremely high NO{sub x} emissions, in this case as high as 1.0 lbs/MMBtu. The unit was a {number_sign}6 oil-fired, 560 MW{sub e} supercritical pressure, three-cell burner boiler at Commonwealth Electric`s Canal Station, Unit {number_sign}1. This paper presents the results including emissions and boiler performance of the retrofit of DB Riley low NO{sub x} STS (Swirl Tertiary Stage) burners. Low NO{sub x} burners were used in conjunction with close-coupled overfire air using existing burner openings. The project reduced NO{sub x} emissions greater than 705 while firing {number_sign}6 oil, and this was accomplished with less than 10% flue gas recirculation.

Green, R.W.; Dorai, X.A. [DB Riley, Inc., Worcester, MA (United States); Hurley, B.A. [Commonwealth Electric Co., Wareham, MA (United States)

1996-11-01T23:59:59.000Z

211

ODD NITROGEN PROCESSES  

E-Print Network (OSTI)

including observed nitrogen dioxide, Pure Appl. Geophys,Stratosphere Observation of Nitrogen Dioxide Rates of Ozoneby photolysis of nitrogen dioxide and regeneration of ozone:

Johnston, Harold S.

2013-01-01T23:59:59.000Z

212

Mercury oxidation promoted by a selective catalytic reduction catalyst under simulated Powder River Basin coal combustion conditions  

SciTech Connect

A bench-scale reactor consisting of a natural gas burner and an electrically heated reactor housing a selective catalytic reduction (SCR) catalyst was constructed for studying elemental mercury (Hg{sup 0}) oxidation under SCR conditions. A low sulfur Powder River Basin (PRB) subbituminous coal combustion fly ash was injected into the entrained-flow reactor along with sulfur dioxide (SO{sub 2}), nitrogen oxides (NOx), hydrogen chloride (HCl), and trace Hg{sup 0}. Concentrations of Hg{sup 0} and total mercury (Hg) upstream and downstream of the SCR catalyst were measured using a Hg monitor. The effects of HCl concentration, SCR operating temperature, catalyst space velocity, and feed rate of PRB fly ash on Hg0 oxidation were evaluated. It was observed that HCl provides the source of chlorine for Hg{sup 0} oxidation under simulated PRB coal-fired SCR conditions. The decrease in Hg mass balance closure across the catalyst with decreasing HCl concentration suggests that transient Hg capture on the SCR catalyst occurred during the short test exposure periods and that the outlet speciation observed may not be representative of steady-state operation at longer exposure times. Increasing the space velocity and operating temperature of the SCR led to less Hg{sup 0} oxidized. Introduction of PRB coal fly ash resulted in slightly decreased outlet oxidized mercury (Hg{sup 2+}) as a percentage of total inlet Hg and correspondingly resulted in an incremental increase in Hg capture. The injection of ammonia (NH{sub 3}) for NOx reduction by SCR was found to have a strong effect to decrease Hg oxidation. The observations suggest that Hg{sup 0} oxidation may occur near the exit region of commercial SCR reactors. Passage of flue gas through SCR systems without NH{sub 3} injection, such as during the low-ozone season, may also impact Hg speciation and capture in the flue gas. 18 refs., 7 figs., 3 tabs.

Chun W. Lee; Shannon D. Serre; Yongxin Zhao; Sung Jun Lee; Thomas W. Hastings [U.S. Environmental Protection Agency, Research Triangle Park, NC (United States). Office of Research and Development, National Risk Management Research Laboratory

2008-04-15T23:59:59.000Z

213

Polonium release from an ATW burner system with liquid lead-bismuth coolant  

SciTech Connect

The authors analyzed polonium release hazards in a conceptual pool-type ATW burner with liquid lead-bismuth eutectic (LBE) coolant. Simplified quantitative models are used based on experiments and real NPP experience. They found little Po contamination outside the burner under normal operating conditions with nominal leakage from the gas system. In sudden gas leak and/or coolant spill accidents, the P contamination level can reach above the regulation limit but short exposure would not lead to severe health consequences. They are evaluating and developing mitigation methods.

Li, N. [Los Alamos National Lab., NM (United States); Yefimov, E.; Pankratov, D. [Inst. of Physics and Power Engineering, Obninsk (Russian Federation)

1998-04-01T23:59:59.000Z

214

An evolution of nozzle design: The low NOx burner experience at the Baldwin Power Station  

SciTech Connect

Illinois Power Company (IPC) installed low NO{sub x} burners on Baldwin Unit 3 in the Spring of 1994. Although the NO{sub x} reduction performance of these burners has been outstanding, IPC suffered catastrophic nozzle failure in the first 8 weeks of operation. The nozzles were then modified and later, replaced. Within 1 week of operation, 2 of the new nozzles also failed. This paper traces the development of the original nozzle, the influences-of other nozzle failures on its design, the determination of the cause of the original and subsequent failures, and the current state of the nozzles.

Forney, D.W. [Illinois Power Co., Decatur, IL (United States); Murray, D.G. [Rolls Royce Industrial Power, Inc., Atlanta, GA (United States); Beal, P.R. [Rolls-Royce Industrial Power, Inc., Derby (United Kingdom)

1996-01-01T23:59:59.000Z

215

Removal of sulfur and nitrogen containing pollutants from discharge gases  

DOE Patents (OSTI)

Oxides of sulfur and of nitrogen are removed from waste gases by reaction with an unsupported copper oxide powder to form copper sulfate. The resulting copper sulfate is dissolved in water to effect separation from insoluble mineral ash and dried to form solid copper sulfate pentahydrate. This solid sulfate is thermally decomposed to finely divided copper oxide powder with high specific surface area. The copper oxide powder is recycled into contact with the waste gases requiring cleanup. A reducing gas can be introduced to convert the oxide of nitrogen pollutants to nitrogen.

Joubert, James I. (Pittsburgh, PA)

1986-01-01T23:59:59.000Z

216

Effect of the Catalyst Load on Syngas Production in Short Contact Time Catalytic Partial Oxidation Reactors  

Science Journals Connector (OSTI)

Effect of the Catalyst Load on Syngas Production in Short Contact Time Catalytic Partial Oxidation Reactors ... For safety and environmental protection reasons (to avoid syngas release into the atmosphere), after the analysis section, the reacted gas stream was completely oxidized by forced air in a catalytic honeycomb burner (Figure 2). ...

S. Specchia; L. D. Vella; B. Lorenzut; T. Montini; V. Specchia; P. Fornasiero

2009-07-22T23:59:59.000Z

217

Tropospheric Reactive Nitrogen Speciation, Deposition, and Chemistry at Harvard Forest  

E-Print Network (OSTI)

and absolute contributions of nitric acid (HNO3) and NOx (nitric oxide (NO) + nitrogen dioxide (NO2)) to totalTropospheric Reactive Nitrogen Speciation, Deposition, and Chemistry at Harvard Forest A thesis. Steven C. Wofsy Cassandra Volpe Horii Tropospheric Reactive Nitrogen Speciation, Deposition

218

Thermodynamic Analysis of the Possibility of Hydrogen Production by Oxidation of n-Butane, n-Pentane, and Carbon by Oxygen-Containing Nitrogen Compounds  

Science Journals Connector (OSTI)

A thermodynamic analysis is performed to study the reactions of hydrogen production by oxidation of hydrocarbons of natural gas ... analysis suggests the possibility of developing a new hydrogen production method

A. M. Alekseev; Z. V. Komova; L. L. Klinova…

2003-07-01T23:59:59.000Z

219

Development of a Spectroscopic Technique for Continuous Online Monitoring of Oxygen and Site-Specific Nitrogen Isotopic Composition of Atmospheric Nitrous Oxide  

E-Print Network (OSTI)

Nitrous oxide is an important greenhouse gas and ozone-depleting-substance. Its sources are diffuse and poorly characterized, complicating efforts to understand anthropogenic impacts and develop mitigation policies. Online, ...

Harris, Eliza

220

Measurement and analysis of heating of paper with gas-fired infrared burner  

E-Print Network (OSTI)

. Gas-fired IR heaters produce combustion on the burner surface by ignition of a pre-mixed air and fuel streams. The combustion raises the surface temperature to ranges of 800-1,100°C to emit radiation, mainly in the medium IR range, which has a...

Husain, Abdullah Nadir

2000-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "nitrogen oxide burner" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

A Novel Integrated TPV Power Generation System Based on a Cascaded Radiant Burner  

Science Journals Connector (OSTI)

A cascaded radiant burner has been developed and based on this burner a novel integrated TPV system has been built. In this system low bandgap GaSb cells and silicon concentrator solar cells are employed integratedly. The unique cascaded radiant burner consists of two different radiators which cascade?emit two streams of radiation with different spectra. The two different radiators are arranged in tandem with their surface temperatures being different as well. Two streams of radiation output are matched respectively to the bandgaps of silicon cells and GaSb cells. Thus one stream of radiation output illuminates silicon concentrator solar cells while the other drives low bandgap GaSb cells in the integrated system. In this work the combustion performance of the cascaded radiant burner was investigated at varying degrees of exhaust heat recuperation. The electrical output characteristics of both silicon concentrator solar cells and GaSb cells in the gas combustion?driven TPV system were measured under various operating conditions. It is shown that this innovative design considerably increases the TPV system efficiency due to the cascaded utilization of heat released during natural gas combustion and the optimized thermal management.

K. Qiu; A. C. S. Hayden

2004-01-01T23:59:59.000Z

222

Design and Evaluation of a High Temperature Burner Duct Recuperator System  

E-Print Network (OSTI)

"The Babcock & Wilcox Company (B&W) has completed a program to design, construct, install, and field test a ceramic-based high-temperature burner-duct-recuperator (HTBDR) in an industrial setting. The unit was capable of operating in corrosive, high...

Parks, W. P.; DeBellis, C. L.; Kneidel, K.

223

Effect of fatty acid composition in vegetable oils on combustion processes in an emulsion burner  

Science Journals Connector (OSTI)

Abstract The use of vegetable oils as a fuel in burners is an alternative which offers certain advantages over the use of vegetable oils in engines. The present work explores the use of four oils: rapeseed, sunflower, soya, and a commercial mixture-seed as heating fuel oil (HFO). The article relates the composition of the fatty acids in the various vegetable oils to the combustion products obtained in an emulsion burner. The work has been carried out in three stages. Firstly, describing the use of vegetable oils as a fuel and determining the fatty acid composition by proton NMR. Secondly, combustion of the vegetable oils studied is performed using an emulsion burner, varying the burner adjustments, and analysing combustion gases. Thirdly, exploring the link between the fatty acids contained in each oil and the combustion efficiency and combustion gas concentration for each oil type. Due to the fatty acids they contain, not all the oils behave equally, even though their description as fuels is very similar.

J. San José; M.A. Sanz-Tejedor; Y. Arroyo

2015-01-01T23:59:59.000Z

224

Innovative Clean Coal Technology (ICCT): 180 MW demonstration of advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from coal-fired boilers. Technical progress report, third quarter 1991  

SciTech Connect

This quarterly report discusses the technical progress of a US Department of Energy (DOE) Innovative Clean Coal Technology (ICCT) Project demonstrating advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from a coal-fired boiler. The project is being conducted at Gulf Power Company`s Plant Lansing Smith Unit 2 located near Panama City, Florida. The primary objective of this demonstration is to determine the long-term effects of commercially available tangentially-fired low NO{sub x} combustion technologies on NO{sub x} emissions and boiler performance. A target of achieving fifty percent NO{sub x} reduction using combustion modifications has been established for the project.

Not Available

1992-02-03T23:59:59.000Z

225

Innovative Clean Coal Technology (ICCT): 180 MW demonstration of advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NO sub x ) emissions from coal-fired boilers  

SciTech Connect

This quarterly report discusses the technical progress of a US Department of Energy (DOE) Innovative Clean Coal Technology (ICCT) Project demonstrating advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from a coal-fired boiler. The project is being conducted at Gulf Power Company's Plant Lansing Smith Unit 2 located near Panama City, Florida. The primary objective of this demonstration is to determine the long-term effects of commercially available tangentially-fired low NO{sub x} combustion technologies on NO{sub x} emissions and boiler performance. A target of achieving fifty percent NO{sub x} reduction using combustion modifications has been established for the project.

Not Available

1992-02-03T23:59:59.000Z

226

CONTROL OF POLLUTANT EMISSIONS IN NATURAL GAS DIFFUSION FLAMES BY USING CASCADE BURNERS  

SciTech Connect

The goal of this exploratory research project is to control the pollutant emissions of diffusion flames by modifying the air infusion rate into the flame. The modification was achieved by installing a cascade of venturis around the burning gas jet. The basic idea behind this technique is controlling the stoichiometry of the flame through changing the flow dynamics and rates of mixing in the combustion zone with a set of venturis surrounding the flame. A natural gas jet diffusion flame at burner-exit Reynolds number of 5100 was examined with a set of venturis of specific sizes and spacing arrangement. The thermal and composition fields of the baseline and venturi-cascaded flames were numerically simulated using CFD-ACE+, an advanced computational environment software package. The instantaneous chemistry model was used as the reaction model. The concentration of NO was determined through CFD-POST, a post processing utility program for CFD-ACE+. The numerical results showed that, in the near-burner, midflame and far-burner regions, the venturi-cascaded flame had lower temperature by an average of 13%, 19% and 17%, respectively, and lower CO{sub 2} concentration by 35%, 37% and 32%, respectively, than the baseline flame. An opposite trend was noticed for O{sub 2} concentration; the cascaded flame has higher O{sub 2} concentration by 7%, 26% and 44%, in average values, in the near-burner, mid-flame and far-burner regions, respectively, than in the baseline case. The results also showed that, in the near-burner, mid-flame, and far-burner regions, the venturi-cascaded flame has lower NO concentrations by 89%, 70% and 70%, in average values, respectively, compared to the baseline case. The numerical results substantiate that venturi-cascading is a feasible method for controlling the pollutant emissions of a burning gas jet. In addition, the numerical results were useful to understand the thermo-chemical processes involved. The results showed that the prompt-NO mechanism plays an important role besides the conventional thermal-NO mechanism. The computational results of the present study need to be validated experimentally.

Dr. Ala Qubbaj

2001-12-30T23:59:59.000Z

227

Demonstration of selective catalytic reduction (SCR) technology for the control of nitrogen oxide (NO{sub x}) emissions from high-sulfur coal-fired boilers. Quarterly report No. 8, April--June, 1992  

SciTech Connect

The objective of this project is to demonstrate and evaluate commercially available Selective Catalytic Reduction (SCR) catalysts from US, Japanese and European catalyst suppliers on a high-sulfur US coal-fired boiler. SCR is a post-combustion nitrogen oxide (NO{sub x}) control technology that involves injecting ammonia into the flue gas generated from coal combustion in an electric utility boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NO{sub x} to convert it to nitrogen and water vapor. Although SCR is widely practiced in Japan and Europe, there are numerous technical uncertainties associated with applying SCR to US coals. These uncertainties include: (1) potential catalyst deactivation due to poisoning by trace metal species present in US coals that are not present in other fuels. (2) performance of the technology and effects on the balance-of-plant equipment in the presence of high amounts of SO{sub 2} and SO{sub 3}. (3) performance of a wide variety of SCR catalyst compositions, geometries and methods of manufacture under typical high-sulfur coal-fired utility operating conditions. These uncertainties will be explored by constructing a series of small-scale SCR reactors and simultaneously exposing different SCR catalysts to flue gas derived from the combustion of high sulfur U. S. coal.

Not Available

1992-08-01T23:59:59.000Z

228

Innovative clean coal technology (ICCT): Demonstration of selective catalytic reduction (SCR) technology for the control of nitrogen oxide (NO{sub x}) emissions from high-sulfur coal-fired boilers. Fourth quarterly progress report  

SciTech Connect

The objective of this project is to demonstrate and evaluate commercially available Selective Catalytic Reduction (SCR) catalysts from US, Japanese and European catalyst suppliers on a high-sulfur US coal-fired boiler. SCR is a post-combustion nitrogen oxide (NO{sub x}) control technology that involves injecting ammonia into the flue gas generated from coal combustion in an electric utility boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NO{sub x} to convert it to nitrogen and water vapor. Although SCR is widely practiced in Japan and Europe, there are numerous technical uncertainties include: (1) potential catalyst deactivation due to poisoning by trace metal species present in US coals that are not present in other fuels; (2) performance of the technology and effects on the balance-of-plant equipment in the presence of high amounts of SO{sub 2} and SO{sub 3}; and (3) performance of a wide variety of SCR catalyst compositions, geometries and methods of manufacture under typical high-sulfur coal-fired utility operating conditions. These uncertainties will be explored by constructing a series of small-scale SCR reactors and simultaneously exposing different SCR catalysts to flue gas derived from the combustion of high sulfur US coal.

NONE

1992-12-31T23:59:59.000Z

229

Utilization of computational fluid dynamics technique in low NOx burner/furnace retrofits  

SciTech Connect

A computational fluid dynamics (CFD) technique has been utilized to provide design guidance for retrofitting low NOx combustion systems and incorporating associated furnace modifications into existing utility boilers. The CFD program utilized is FW-FIRES (Fossil fuel, Water-walled Furnace Integrated Reaction and Emission Simulation) which simulates furnace combustion, heat transfer and pollutant formation based on fundamental principals of mass, momentum and energy conservations. The program models the gas flow field as a three-dimensional turbulent reacting continuum and the particle flow as a series of discrete particle trajectories through the gas continuum. Chemical reaction, heat transfer, and pollutant formation mechanisms are incorporated in the program. FW-FIRES furnace simulation of low NOx combustion system retrofits has been performed for various furnace configurations including front wall-fired, front and real wall-fired, and tangentially-fired furnaces, to determine the effects of burner/furnace modifications on the NOx emission, furnace exit gas temperature, furnace heat absorption, unburned carbon, and furnace wall corrosion. For front wall-fired, and front and real wall-fired furnaces, the NOx emission requirement is met by the use of Foster Wheeler lox NOx burners and overfire air (OFA) staging. Studies of burner and OFA quantify and spacing are conducted to limit NOx emission and unburned carbon to acceptable levels. A major concern in once-through supercritical units with OFA is furnace wall corrosion which is caused by high furnace wall metal temperature and corrosive hydrogen sulfide (H{sub 2}S) created in a reducing atmosphere from part of coal sulfur. The FW-FIRES code is used to minimize this corrosion potential by selecting the proper location and quantity of boundary air. A simulation of tangentially-fired unit, which has been retrofitted with low NOx burners, is used to study the effect of the burner tilt on the furnace exit gas temperature. This paper details the basis and results of several CFD analyses conducted for potential retrofit programs.

Cho, S.M.; Seltzer, A.H.; Ma, J.; Steitz, T.H.; Grusha, J.; Cole, R.W.

1999-07-01T23:59:59.000Z

230

Investigation of mixed metal sorbent/catalysts for the simultaneous removal of sulfur and nitrogen oxides. Semiannual report, Apr 1, 1998--Oct 31, 1998  

SciTech Connect

Simultaneous removal of SO{sub 2} and NO{sub x} using a regenerable solid sorbent will constitute an important improvement over the use of separate processes for the removal of these two pollutants from stack gases and possibly eliminate several shortcomings of the individual SO{sub 2} and NO{sub x} removal operations. The work done at PETC and the DOE-funded investigation of the investigators on the sulfation and regeneration of alumina-supported cerium oxide sorbents have shown that they can perform well at relatively high temperatures (823--900 K) as regenerable desulfurization sorbents. Survey of the recent literature shows that addition of copper oxide to ceria lowers the sulfation temperature of ceria down to 773 K, sulfated ceria-based sorbents can function as selective SCR catalysts even at elevated temperatures, SO{sub 2} can be directly reduced to sulfur by CO on CuO-ceria catalysts, and ceria-based catalysts may have a potential for selective catalytic reduction of NO{sub x} by methane. These observations indicate a possibility of developing a ceria-based sorbent/catalyst which can remove both SO{sub 2} and NO{sub x} from flue gases within a relatively wide temperature window, produce significant amounts of elemental sulfur during regeneration, and use methane for the selective catalytic reduction of NO{sub x}. The objective of this research is to conduct kinetic and parametric studies of the selective catalytic reduction of NO{sub x} with NH{sub 3} and CH{sub 4} over alumina-supported cerium oxide and copper oxide-cerium oxide sorbent/catalysts; investigate SO{sub 2} removal at lower temperatures by supported copper oxide-cerium oxide sorbents; and investigate the possibility of elemental sulfur production during regeneration with CO or with CH{sub 4} air mixtures. The sorbents consisting of cerium oxide and copper oxide impregnated on alumina have been prepared and characterized. Their sulfation performance has been investigated in a TGA setup, studying mainly the effects of temperature and sorbent composition. The results of the sulfation experiments have been evaluated and presented in this report. A study to model the sulfation selectivity of the two constituents of the sorbents is also underway.

Dr. Ates Akyurtlu; Dr. Jale F. Akyurtlu

1998-10-31T23:59:59.000Z

231

Results of initial operation of the Jupiter Oxygen Corporation oxy-fuel 15 MWth burner test facility  

SciTech Connect

Jupiter Oxygen Corporation (JOC), in cooperation with the National Energy Technology Laboratory (NETL), constructed a 15 MWth oxy-fuel burner test facility with Integrated Pollutant Removal (IPRTM) to test high flame temperature oxy-fuel combustion and advanced carbon capture. Combustion protocols include baseline air firing with natural gas, oxygen and natural gas firing with and without flue gas recirculation, and oxygen and pulverized coal firing with flue gas recirculation. Testing focuses on characterizing burner performance, determining heat transfer characteristics, optimizing CO2 capture, and maximizing heat recovery, with an emphasis on data traceability to address retrofit of existing boilers by directly transforming burner systems to oxy-fuel firing.

Thomas Ochs, Danylo Oryshchyn, Rigel Woodside, Cathy Summers, Brian Patrick, Dietrich Gross, Mark Schoenfield, Thomas Weber and Dan O'Brien

2009-04-01T23:59:59.000Z

232

Cover and startup gas supply system for solid oxide fuel cell generator  

DOE Patents (OSTI)

A cover and startup gas supply system for a solid oxide fuel cell power generator is disclosed. Hydrocarbon fuel, such as natural gas or diesel fuel, and oxygen-containing gas are supplied to a burner. Combustion gas exiting the burner is cooled prior to delivery to the solid oxide fuel cell. The system mixes the combusted hydrocarbon fuel constituents with hydrogen which is preferably stored in solid form to obtain a non-explosive gas mixture. The system may be used to provide both non-explosive cover gas and hydrogen-rich startup gas to the fuel cell.

Singh, Prabhakar (Export, PA); George, Raymond A. (Pittsburgh, PA)

1999-01-01T23:59:59.000Z

233

Cover and startup gas supply system for solid oxide fuel cell generator  

DOE Patents (OSTI)

A cover and startup gas supply system for a solid oxide fuel cell power generator is disclosed. Hydrocarbon fuel, such as natural gas or diesel fuel, and oxygen-containing gas are supplied to a burner. Combustion gas exiting the burner is cooled prior to delivery to the solid oxide fuel cell. The system mixes the combusted hydrocarbon fuel constituents with hydrogen which is preferably stored in solid form to obtain a non-explosive gas mixture. The system may be used to provide both non-explosive cover gas and hydrogen-rich startup gas to the fuel cell. 4 figs.

Singh, P.; George, R.A.

1999-07-27T23:59:59.000Z

234

Back-Trajectory Analysis and Source-Receptor Relationships: Particulate Matter and Nitrogen Isotopic Composition in  

E-Print Network (OSTI)

. The chemical components of these acids, including nitrogen oxides (NOx nitric acid [NO] nitrogen dioxide [NO2Back-Trajectory Analysis and Source-Receptor Relationships: Particulate Matter and Nitrogen- search suggests that this agricultural presence emits a significant portion of the state's nitrogen (i

Niyogi, Dev

235

Quantum-chemical investigation of the interaction of nitrogen and carbon monoxide molecules with the Lewis acid sites of aluminium oxide  

SciTech Connect

Within the framework of the cluster approximation, using covalent and ionic models of Lewis acid sites of aluminumoxide, their electronic structure, as well as that of complexes of nitrogen and carbon monoxide molecules with them, was calculated. It was shown that the Lewis acid sites, representing a truncated tetrahedron, exhibit stronger electron-acceptor properties than the corresponding sites in the form of a truncated octahedron. For both molecules, the linear form of adsorption is energetically more profitable than the T-shaped form. The results obtained by the nonempirical SCF MO LCAO method in the STO-3GF basis and by semiempirical methods in CNDO/2 and INDO approximatations, are qualitatively the same.

Senchenya, I.N.; Chuvylkin, N.D.; Kazanskii, V.B.

1986-11-01T23:59:59.000Z

236

Latest developments and application of DB Riley`s low NOx CCV{reg_sign} burner technology  

SciTech Connect

Recent developments in DB Riley (DBR) low NO{sub x} burner technology and the application of this technology in coal fired utility boilers are discussed. Since the promulgation of the Clean Air Act Amendment in 1990, DBR has sold nearly 1500 Controlled Combustion Venturi (CCV{reg_sign}) burners on pulverized coal fired utility boilers reducing NOx emissions 50 - 70% from uncontrolled levels. This technology has been retrofitted on boiler designs ranging in size and type from 50 MW front wall fired boilers to 1300 MW opposed fired cell type boilers. In DBR`s latest version of the CCV{reg_sign} burner, a second controlled flow air zone was added to enhance NO{sub x} control capability. Other developments included improved burner air flow measurement accuracy and several mechanical design upgrades such as new coal spreader designs for 3 year wear life. Test results of the CCV{reg_sign} dual air zone burner in DBR`s 100 million Btu/hr (29 MW) coal burner test facility are presented. In the test program, coals from four utility boiler sites were fired to provide a range of coal properties. A baseline high volatile bituminous coal was also fired to provide a comparison with 1992 test data for the CCV{reg_sign} single register burner. The test results showed that the second air zone enhanced NO{sub x} reduction capability by an additional 20% over the single register design. Computational fluid dynamic (CFD) modeling results of the CCV{reg_sign} dual air zone burner are also presented showing near field mixing patterns conducive to low NO{sub x} firing.

Penterson, C.; Ake, T. [DB Riley, Inc., Worcester, MA (United States)

1998-04-01T23:59:59.000Z

237

Orimulsion in low NO{sub x} burner based combustion systems  

SciTech Connect

The potential of Orimulsion (a bitumen in water emulsion) as a suitable fuel for power generation boilers has been established subject to full recognition being given to the environmental aspects of its application. An important factor is the control of NO{sub x} emissions from the combustion process. Work on NO{sub x} control when firing Orimulsion has inevitably been based on the techniques utilized for low NO{sub x} fuel oil combustion. This fundamental work has indicated the different performance characteristics of these two fuels when fired in similar low NO{sub x} burner configurations. Nevertheless it has been demonstrated that Orimulsion can achieve similar, and perhaps even improved, low NO{sub x} performance when compared to heavy (No. 6) fuel oil, and can be used with equal flexibility to that of heavy fuel oil in low NO{sub x} combustion systems based on both burner and in furnace staging techniques.

Allen, J.W.; Beal, P. [International Combustion Ltd., Derby (United Kingdom). Rolls-Royce Industrial Power Group

1996-12-31T23:59:59.000Z

238

Demonstration of Selective Catalytic Reduction (SCR) technology for the control of nitrogen oxide (NO{sub x}) emissions from high-sulfur coal-fired boilers. Technical progress report, first and second quarters 1994  

SciTech Connect

The objective of this project is to demonstrate and evaluate commercially available Selective Catalytic Reduction (SCR) catalysts from U.S., Japanese and European catalyst suppliers on a high-sulfur U.S. coal-fired boiler. SCR is a post-combustion nitrogen oxide (NO{sub x}) control technology that involve injecting ammonia into the flue gas generated from coal combustion in a boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NO{sub x} to form nitrogen and water vapor. Although SCR is widely practiced in Japan and Europe on gas-, oil-, and low-sulfur coal-fired boilers, there are several technical uncertainties associated with applying SCR to U.S. coals. These uncertainties include: (1) potential catalyst deactivation due to poisoning by trace metal species present in U.S. coals that are not present in other fuels; (2) performance of the technology and effects on the balance-of-plant equipment in the presence of high amounts of SO{sub 2} and SO{sub 3}; and (3) performance of a wide variety of SCR catalyst compositions, geometries and methods of manufacture under typical high-sulfur coal-fired utility operating conditions. These uncertainties are being explored by operating a series of small-scale SCR reactors and simultaneously exposing different SCR catalysts to flue gas derived from the combustion of high sulfur U.S. coal. The project is being conducted in the following three phases: permitting, environmental monitoring plan and preliminary engineering; detailed design engineering and construction; and operation, testing, disposition and final report. The project was in the operation and testing phase during this reporting period. Accomplishments for this period are described.

NONE

1995-11-01T23:59:59.000Z

239

Lignite-based nitrogenous fertilizers  

SciTech Connect

A sample of lignite from Elbistan was oxidized by nitric acid in two stages, using relatively dilute acid in the first stage and concentrated acid in the second stage, and then the oxidized product was ammoniated so that a coal-based fertilizer could be produced. The experiments of all the stages were designed by a 1/2 X full factorial design. It was observed that base exchange capacity and nitrogen content of coal-based fertilizers produced in this work were as good as or better than those obtained by other investigators.

Baris, H.; Dincer, S.

1983-01-01T23:59:59.000Z

240

Premixed burner studies of NO{sub x} formation and control  

SciTech Connect

With the enactment of the Clean Air Act Amendments of 1990, there is now additional incentive for the development of gas turbine systems with very low NO{sub x} emissions characteristics. Further, the development of low NO{sub x} burners that are capable of utilizing low-heating-value gases derived from coal based systems is an essential component for a number of fossil energy technologies including IGCC and second-generation PFBC. However, the chemistry associated with NO{sub x} formation is complicated, and attempts to reduce these emissions often result in increases in other undesirable species such as CO or N{sub 2}O. In view of these complexities, it is useful to study NO{sub x} formation and NO{sub x} control strategies in a well-controlled, lab-scale burner system. In this way, detailed knowledge about the intricate interrelationships between the various chemical pathways can be obtained and subsequently applied to bench-scale and larger systems. The current project involves both chemical kinetic modeling as well as experimental studies performed in a premixed burner system to generate these data.

Castleton, K.H.; Straub, D.L. [USDOE Morgantown Energy Technology Center, WV (United States); Stephens, J.W. [National Research Council, Washington, DC (United States); McManus, T.J. [Oak Ridge Associated Universities, Inc., TN (United States)

1993-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "nitrogen oxide burner" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

TPV Power Generation System Using a High Temperature Metal Radiant Burner  

Science Journals Connector (OSTI)

Interest has grown in micro?combined heat and power (micro?CHP). Thermophotovoltaic (TPV) generation of electricity in fuel?fired furnaces is one of the micro?CHP technologies that are attracting technical attention. Previous investigations have shown that a radiant burner that can efficiently convert fuel chemical energy into radiation energy is crucial to realize a practical TPV power system. In this work we developed a TPV power generation system using a gas?fired metal radiant burner. The burner consists of a high temperature alloy emitter which could have an increased emissivity at short wavelengths and low emissivity at long wavelengths. The metal emitter is capable of bearing high temperatures of interest to fuel?fired TPV power conversion. GaSb TPV cells were tested in the combustion?driven radiant source. Electric output characteristics of the TPV cells were investigated at various operating conditions. The electric power output of the TPV cells was demonstrated to be promising. At an emitter temperature of 1185°C an electric power density of 0.476 W/cm2 was generated by the GaSb cells. It is shown that the metal emitter is attractive and could be applied to practical fuel?fired TPV power systems.

K. Qiu; A. C. S. Hayden; E. Entchev

2007-01-01T23:59:59.000Z

242

Large eddy simulation of forced ignition of an annular bluff-body burner  

SciTech Connect

The optimization of the ignition process is a crucial issue in the design of many combustion systems. Large eddy simulation (LES) of a conical shaped bluff-body turbulent nonpremixed burner has been performed to study the impact of spark location on ignition success. This burner was experimentally investigated by Ahmed et al. [Combust. Flame 151 (2007) 366-385]. The present work focuses on the case without swirl, for which detailed measurements are available. First, cold-flow measurements of velocities and mixture fractions are compared with their LES counterparts, to assess the prediction capabilities of simulations in terms of flow and turbulent mixing. Time histories of velocities and mixture fractions are recorded at selected spots, to probe the resolved probability density function (pdf) of flow variables, in an attempt to reproduce, from the knowledge of LES-resolved instantaneous flow conditions, the experimentally observed reasons for success or failure of spark ignition. A flammability map is also constructed from the resolved mixture fraction pdf and compared with its experimental counterpart. LES of forced ignition is then performed using flamelet fully detailed tabulated chemistry combined with presumed pdfs. Various scenarios of flame kernel development are analyzed and correlated with typical flow conditions observed in this burner. The correlations between, velocities and mixture fraction values at the sparking time and the success or failure of ignition, are then further discussed and analyzed. (author)

Subramanian, V.; Domingo, P.; Vervisch, L. [CORIA-CNRS and INSA de Rouen, Technopole du Madrillet, BP 8, 76801 Saint-Etienne-du-Rouvray (France)

2010-03-15T23:59:59.000Z

243

Evaluation of Gas Reburning and Low N0x Burners on a Wall Fired Boiler  

SciTech Connect

Under the U.S. Department of Energy's Clean Coal Technology Program (Round 3), a project was completed to demonstrate control of boiler NOX emissions and to a lesser degree, due to coal replacement, SO2 emissions. The project involved combining Gas Reburning with Low NOX Burners (GR-LNB) on a coal-fired electric utility boiler to determine if high levels of NO, reduction (70VO) could be achieved. Sponsors of the project included the U.S. Depatiment of Energy, the Gas Research Institute, Public Service Company of Colorado, Colorado Interstate Gas, Electric Power Research Institute, and the Energy and Environmental Research Corporation. The GR-LNB demonstration was petformed on Public Service Company of Colorado's (PSCO) Cherokee Unit #3, located in Denver, Colorado. This unit is a 172 MW~ wall-fired boiler that uses Colorado bituminous, low-sulfur coal. It had a baseline NO, emission level of 0.73 lb/1 OG Btu using conventional burners. Low NOX burners are designed to yield lower NOX emissions than conventional burners. However, the NOX control achieved with this technique is limited to 30-50Y0. Also, with LNBs, CO emissions can increase to above acceptable standards. Gas Reburning (GR) is designed to reduce NO, in the flue gas by staged fuel combustion. This technology involves the introduction of' natural gas into the hot furnace flue gas stream. When combined, GR and LNBs minimize NOX emissions and maintain acceptable levels of CO emissions. A comprehensive test program was completed, operating over a wide range of boiler conditions. Over 4,000 hours of operation were achieved, providing substantial data. Measurements were taken to quantify reductions in NOX emissions, the impact on boiler equipment and operability and factors influencing costs. The GR-LNB technology achieved good NO, emission reductions and the goals of the project were achieved. Although the performance of the low NOX burners (supplied by others) was less than expected, a NOX reduction of 65% was achieved at an average gas heat input of 18%. The performance goal of 70/40 reduction was met on many test runs, but at a higher reburn gas heat input. S02 emissions, based on coal replacement, were reduced by 18%.

None

1998-07-01T23:59:59.000Z

244

Selective catalytic reduction of nitrogen oxides by ammonia over Fe{sup 3+}-exchanged TiO{sub 2}-pillared clay catalysts  

SciTech Connect

Fe-exchanged TiO{sub 2}-pillared clay (PILC) catalysts were prepared and used for selective catalytic reduction (SCR) of NO{sub x} by ammonia. They were also characterized for surface area, pore size distribution, and by XRD, H{sub 2}-TPR, and FT-IR methods. The Fe-TiO{sub 2}-PILC catalysts showed high activities in the reduction of NO{sub x} by NH{sub 3} in the presence of excess oxygen. SO{sub 2} further increased the catalytic activities at above 350 C, whereas H{sub 2}O decreased the activity slightly. The catalysts were about twice as active as commercial-type V{sub 2}O{sub 5}-WO{sub 3}/TiO{sub 2} catalyst in the presence of H{sub 2}O and SO{sub 2}. Moreover, compared to the commercial catalyst, the Fe-TiO{sub 2}-PILC catalysts had higher N{sub 2}/N{sub 2}O product selectivities (e.g., 0--1% vs 9% N{sub 2}O at 400 C) and substantially lower activities (by 74--88%) for SO{sub 2} oxidation to SO{sub 3} under the same reaction conditions. The activity was further increased to over three times that of the vanadia-based catalyst when Ce was added. The high activity and low N{sub 2}O selectivity for the Fe-TiO{sub 2}-PILC catalysts were attributed to their low activity in the oxidation of ammonia, as compared with vanadia catalysts. XRD patterns of Fe-TiO{sub 2}-PILC were similar to those of TiO{sub 2}-PILC, showing no peaks due to iron oxide, even when the iron content reached 20.1%. The TPR results indicated that iron in the Fe-TiO{sub 2}-PILC catalysts with lower iron contents existed in the form of isolated Fe{sup 3+} ions. The activities of Fe-TiO{sub 2}-PILC catalysts were consistent with their surface acidities, which were identified by FT-IR of the NH{sub 3}-adsorbed samples. The enhancement of activities by H{sub 2}O + SO{sub 2} was attributed to the increase of surface acidity resulting from the formation of surface sulfate species of iron.

Long, R.Q.; Yang, R.T. [Univ. of Michigan, Ann Arbor, MI (United States). Dept. of Chemical Engineering] [Univ. of Michigan, Ann Arbor, MI (United States). Dept. of Chemical Engineering

1999-09-10T23:59:59.000Z

245

Innovative Clean Coal Technology (ICCT): 180 MW demonstration of advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from coal-fired boilers. Fourth quarterly technical progress report, [October--December, 1992  

SciTech Connect

This quarterly report discusses the technical progress of a U. S. Department of Energy (DOE) Innovative Clean Coal Technology (ICCT) Project demonstrating advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NOx) emissions from a coal-fired boiler. The project is being conducted at Gulf Power Company`s Plant Lansing Smith Unit 2 located near Panama City, Florida. The primary objective of this demonstration is to determine the long-term effects of commercially available tangentially-fired low NOx combustion technologies on NOx emissions and boiler performance. A target of achieving fifty percent NOx reduction using combustion modifications has been established for the project. The stepwise approach that is being used to evaluate the NOx control technologies requires three plant outages to successively install the test instrumentation and the different levels of the low NOx concentric firing system (LNCFS). Following each outage, a series of four groups of tests are performed. These are (1) diagnostic, (2) performance, (3) long-term, and (4) verification. These tests are used to quantify the NOx reductions of each technology and evaluate the effects of those reductions on other combustion parameters such as particulate characteristics and boiler efficiency. During this quarter, tests of the LNCFS Level III system were conducted to determine the effect that fuel fineness has on NOx emissions and unburned carbon levels. Results showed that changing the fineness of the fuel has almost no effect on NOx emissions; however, unburned carbon levels can be reduced significantly by increasing fuel fineness.

Not Available

1992-12-31T23:59:59.000Z

246

Innovative Clean Coal Technology (ICCT): 180 MW demonstration of advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NO[sub x]) emissions from coal-fired boilers  

SciTech Connect

This quarterly report discusses the technical progress of a US Department of Energy (DOE) Innovative Clean Coal Technology (ICCT) Project demonstrating advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NO[sub x]) emissions from a coal-fired boiler. The project is being conducted at Gulf Power Company's Plant Lansing Smith Unit 2 located near Panama City, Florida. The primary objective of this demonstration is to determine the long-term effects of commercially available tangentially-fired low NO[sub x] combustion technologies on NO[sub x] emissions and boiler performance. A target of achieving fifty percent NO[sub x] reduction using combustion modifications has been established for the project. The stepwise approach that is being used to evaluate the NO[sub x] control technologies requires three plant outages to successively install the test instrumentation and the different levels of the low NO[sub x] concentric firing system (LNCFS). Following each outage, a series of four groups of tests are performed. These are (1) diagnostic, (2) performance, (3) long-term, and (4) verification. These tests are used to quantify the NO[sub x] reductions of each technology and evaluate the effects of those reductions on other combustion parameters such as particulate characteristics and boiler efficiency. This technical progress report presents the LNCFS Level I short-term data collected during this quarter. In addition, a comparison of all the long-term emissions data that have been collected to date is included.

Not Available

1992-11-25T23:59:59.000Z

247

Innovative Clean Coal Technology (ICCT): 180 MW demonstration of advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from coal-fired boilers. Technical progress report, fourth quarter 1991  

SciTech Connect

This quarterly report discusses the technical progress of a US Department of Energy (DOE) Innovative Clean Coal Technology (ICCT) Project demonstrating advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from a coal-fired boiler. The project is being conducted at Gulf Power Company`s Plant Lansing Smith Unit 2 located near Panama City, Florida. The primary objective of this demonstration is to determine the long-term effects of commercially available tangentially-fired low NO{sub x} combustion technologies on NO{sub x} emissions and boiler performance. A target of achieving fifty percent NO{sub x} reduction using combustion modifications has been established for the project. The stepwise approach that is being used to evaluate the NO{sub x} control technologies requires three plant outages to successively install the test instrumentation and the different levels of the low NO{sub x} concentric firing system (LNCFS). Following each outage, a series of four groups of tests are performed. These are (1) diagnostic, (2) performance, (3) long-term, and (4) verification. These tests are used to quantify the NO{sub x} reductions of each technology and evaluate the effects of those reductions on other combustion parameters such as particulate characteristics and boiler efficiency.

Not Available

1992-05-18T23:59:59.000Z

248

Innovative Clean Coal Technology (ICCT): 180 MW demonstration of advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NO sub x ) emissions from coal-fired boilers  

SciTech Connect

This quarterly report discusses the technical progress of a US Department of Energy (DOE) Innovative Clean Coal Technology (ICCT) Project demonstrating advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from a coal-fired boiler. The project is being conducted at Gulf Power Company's Plant Lansing Smith Unit 2 located near Panama City, Florida. The primary objective of this demonstration is to determine the long-term effects of commercially available tangentially-fired low NO{sub x} combustion technologies on NO{sub x} emissions and boiler performance. A target of achieving fifty percent NO{sub x} reduction using combustion modifications has been established for the project. The stepwise approach that is being used to evaluate the NO{sub x} control technologies requires three plant outages to successively install the test instrumentation and the different levels of the low NO{sub x} concentric firing system (LNCFS). Following each outage, a series of four groups of tests are performed. These are (1) diagnostic, (2) performance, (3) long-term, and (4) verification. These tests are used to quantify the NO{sub x} reductions of each technology and evaluate the effects of those reductions on other combustion parameters such as particulate characteristics and boiler efficiency.

Not Available

1992-05-18T23:59:59.000Z

249

The Nitrogen-Nitride Anode.  

SciTech Connect

Nitrogen gas N 2 can be reduced to nitride N -3 in molten LiCl-KCl eutectic salt electrolyte. However, the direct oxidation of N -3 back to N 2 is kinetically slow and only occurs at high overvoltage. The overvoltage for N -3 oxidation can be eliminated by coordinating the N -3 with BN to form the dinitridoborate (BN 2 -3 ) anion which forms a 1-D conjugated linear inorganic polymer with -Li-N-B-N- repeating units. This polymer precipitates out of solution as Li 3 BN 2 which becomes a metallic conductor upon delithiation. Li 3 BN 2 is oxidized to Li + + N 2 + BN at about the N 2 /N -3 redox potential with very little overvoltage. In this report we evaluate the N 2 /N -3 redox couple as a battery anode for energy storage.

Delnick, Frank M.

2014-10-01T23:59:59.000Z

250

Evaluation of Gas Reburning and Low N0x Burners on a Wall Fired Boiler  

SciTech Connect

Under the U.S. Department of Energy's Clean Coal Technology Program (Round 3), a project was completed to demonstrate control of boiler emissions that comprise acid rain precursors, especially NOX. The project involved operating gas reburning technology combined with low NO, burner technology (GR-LNB) on a coal-fired utility boiler. Low NOX burners are designed to create less NOX than conventional burners. However, the NO, control achieved is in the range of 30-60-40, and typically 50%. At the higher NO, reduction levels, CO emissions tend to be higher than acceptable standards. Gas Reburning (GR) is designed to reduce the level of NO. in the flue gas by staged fuel combustion. When combined, GR and LNBs work in harmony to both minimize NOX emissions and maintain an acceptable level of CO emissions. The demonstration was performed at Public Service Company of Colorado's (PSCO) Cherokee Unit 3, located in Denver, Colorado. This unit is a 172 MW. wall-fired boiler that uses Colorado bituminous, low-sulfur coal and had a pre GR-LNB baseline NOX emission of 0.73 lb/1 Oe Btu. The target for the project was a reduction of 70 percent in NOX emissions. Project sponsors included the U.S. Department of Energy, the Gas Research Institute, Public Service Company of Colorado, Colorado Interstate Gas, Electric Power Research Institute, and the Energy and Environmental Research Corporation (EER). EER conducted a comprehensive test demonstration program over a wide range of boiler conditions. Over 4,000 hours of operation were achieved. Intensive measurements were taken to quantify the reductions in NOX emissions, the impact on boiler equipment and operability, and all factors influencing costs. The results showed that GR-LNB technology achieved excellent emission reductions. Although the performance of the low NOX burners (supplied by others) was somewhat less than expected, a NOX reduction of 65% was achieved at an average gas heat input of 180A. The performance goal of 70% reduction was met on many test runs, but at higher gas heat inputs. The impact on boiler equipment was determined to be very minimal. Toward the end of the testing, the flue gas recirculation (used to enhance gas penetration into the furnace) system was removed and new high pressure gas injectors were installed. Further, the low NOX burners were modified and gave better NO. reduction performance. These modifications resulted in a similar NO, reduction performance (64%) at a reduced level of gas heat input (-13Yo). In addition, the OFA injectors were re-designed to provide for better control of CO emissions. Although not a part of this project, the use of natural gas as the primary fuel with gas reburning was also tested. The gas/gas reburning tests demonstrated a reduction in NOX emissions of 43% (0.30 lb/1 OG Btu reduced to 0.17 lb/1 OG Btu) using 7% gas heat input. Economics are a key issue affecting technology development. Application of GR-LNB requires modifications to existing power plant equipment and as a result, the capital and operating costs depend largely on site-specific factors such as: gas availability at the site, gas to coal delivered price differential, sulfur dioxide removal requirements, windbox pressure, existing burner throat diameters, and reburn zone residence time available. Based on the results of this CCT project, EER expects that most GR-LNB installations will achieve at least 60% NOX control when firing 10-15% gas. The capital cost estimate for installing a GR-LNB system on a 300 MW, unit is approximately $25/kW. plus the cost of a gas pipeline (if required). Operating costs are almost entirely related to the differential cost of the natural gas compared to coal.

None

1998-09-01T23:59:59.000Z

251

Low Emissions Burner Technology for Metal Processing Industry using Byproducts and Biomass Derived Liquid Fuels  

SciTech Connect

This research and development efforts produced low-emission burner technology capable of operating on natural gas as well as crude glycerin and/or fatty acids generated in biodiesel plants. The research was conducted in three stages (1) Concept definition leading to the design and development of a small laboratory scale burner, (2) Scale-up to prototype burner design and development, and (3) Technology demonstration with field vefiication. The burner design relies upon the Flow Blurring (FB) fuel injection based on aerodynamically creating two-phase flow near the injector exit. The fuel tube and discharge orifice both of inside diameter D are separated by gap H. For H < 0.25D, the atomizing air bubbles into liquid fuel to create a two-phase flow near the tip of the fuel tube. Pressurized two-phase fuel-air mixture exits through the discharge orifice, which results in expansion and breakup of air bubbles yielding a spray with fine droplets. First, low-emission combustion of diesel, biodiesel and straight VO (soybean oil) was achieved by utilizing FB injector to yield fine sprays for these fuels with significantly different physical properties. Visual images for these baseline experiments conducted with heat release rate (HRR) of about 8 kW illustrate clean blue flames indicating premixed combustion for all three fuels. Radial profiles of the product gas temperature at the combustor exit overlap each other signifying that the combustion efficiency is independent of the fuel. At the combustor exit, the NOx emissions are within the measurement uncertainties, while CO emissions are slightly higher for straight VO as compared to diesel and biodiesel. Considering the large variations in physical and chemical properties of fuels considered, the small differences observed in CO and NOx emissions show promise for fuel-flexible, clean combustion systems. FB injector has proven to be very effective in atomizing fuels with very different physical properties, and it offers a path forward to utilize both fossil and alternative liquid fuels in the same combustion system. In particular, experiments show that straight VO can be cleanly combusted without the need for chemical processing or preheating steps, which can result in significant economic and environmental benefits. Next, low-emission combustion of glycerol/methane was achieved by utilizing FB injector to yield fine droplets of highly viscous glycerol. Heat released from methane combustion further improves glycerol pre-vaporization and thus its clean combustion. Methane addition results in an intensified reaction zone with locally high temperatures near the injector exit. Reduction in methane flow rate elongates the reaction zone, which leads to higher CO emissions and lower NOx emissions. Similarly, higher air to liquid (ALR) mass ratio improves atomization and fuel pre-vaporization and shifts the flame closer to the injector exit. In spite of these internal variations, all fuel mixes of glycerol with methane produced similar CO and NOx emissions at the combustor exit. Results show that FB concept provides low emissions with the flexibility to utilize gaseous and highly viscous liquid fuels, straight VO and glycerol, without preheating or preprocessing the fuels. Following these initial experiments in quartz combustor, we demonstrated that glycerol combustion can be stably sustained in a metal combustor. Phase Doppler Particle Analyzer (PDPA) measurements in glycerol/methane flames resulted in flow-weighted Sauter Mean Diameter (SMD) of 35 to 40 ?m, depending upon the methane percentage. This study verified that lab-scale dual-fuel burner using FB injector can successfully atomize and combust glycerol and presumably other highly viscous liquid fuels at relatively low HRR (<10 kW). For industrial applications, a scaled-up glycerol burner design thus seemed feasible.

Agrawal, Ajay; Taylor, Robert

2013-09-30T23:59:59.000Z

252

Comprehensive report to Congress: Clean Coal Technology program: Evaluation of gas reburning and low-NO sub x burners on a wall-fired boiler  

SciTech Connect

This report briefly describes the Gas Reburning and Low-NO{sub x} Burners technology which is a low-cost technology that can be applied in both retrofit and new applications. This demonstration will be conducted on a utility boiler in Colorado at Cherokee Station {number sign}3; however, the technology is applicable to industrial boilers and other combustion systems. Although this technology is primarily a NO{sub x} reduction technology, some reductions in other emissions will take place. Since 15--20% of the coal is replaced with natural gas, SO{sub 2} and particulate emissions are reduced commensurately. Also the lower carbon-to-hydrogen ratio of natural gas compared to coal reduces CO{sub 2} emissions. The formation of NO{sub x} is controlled by several factors: (1) the amount of nitrogen that is chemically bound in the fuel; (2) the flame temperature; (3) the residence time that combustion products remain at very high temperatures; and (4) the amount of excess oxygen available, especially at the hottest parts of the flame. Decreasing any of these parameters, tends to reduce NO{sub x} formation. 6 figs., 1 tab.

Not Available

1990-09-01T23:59:59.000Z

253

SAS Output  

U.S. Energy Information Administration (EIA) Indexed Site

4. Nitrogen Oxides Control Technology Emissions Reduction Factors 4. Nitrogen Oxides Control Technology Emissions Reduction Factors Nitrogen Oxides Control Technology EIA-Code(s) Reduction Factor Advanced Overfire Air AA 30% Alternate Burners BF 20% Flue Gas Recirculation FR 40% Fluidized Bed Combustor CF 20% Fuel Reburning FU 30% Low Excess Air LA 20% Low NOx Burners LN 30% Other (or Unspecified) OT 20% Overfire Air OV 20% Selective Catalytic Reduction SR 70% Selective Catalytic Reduction With Low Nitrogen Oxide Burners SR and LN 90% Selective Noncatalytic Reduction SN 30% Selective Noncatalytic Reduction With Low NOx Burners SN and LN 50% Slagging SC 20% Notes: Starting with 1995 data, reduction factors for Advanced Overfire Air, Low NOx Burners, and Overfire Air were reduced by 10 percent.

254

3 - Fuel considerations and burner design for ultra-supercritical power plants  

Science Journals Connector (OSTI)

Abstract: This chapter discusses fuel quality and its influence on utility boiler design and impact on performance, with the emphasis on coal and biomass as fuels. Performance issues addressed include system capacity, heat rate, availability, and maintenance, and how they are affected by fuel quality. The effect of fuel quality on handling, storage, processing, and preparation is discussed. In addition, the effect of fuel quality on burner design and ignition stability is presented. Future trends are discussed, specifically focusing on continued use of biomass as a means to reduce greenhouse gas emissions in the utility sector.

B. Miller

2013-01-01T23:59:59.000Z

255

A Study of Gasification of Municipal Solid Waste Using a Double Inverse Diffusion Flame Burner  

Science Journals Connector (OSTI)

A Study of Gasification of Municipal Solid Waste Using a Double Inverse Diffusion Flame Burner ... Furthermore, the experiences of the waste incineration industry driven in the past by regulatory as well as technical issues may facilitate their commercial potentials outside the common market, especially in highly populated developing countries such as Korea with scarce landfill sites. ... Recently, several new technologies that involve gasification or combinations of pyrolysis, combustion, and gasification processes are currently being brought into the market for energy-efficient, environmentally friendly and economically sound methods of thermal processing of wastes. ...

Tae-Heon Kwak; Seungmoon Lee; Sanjeev Maken; Ho-Chul Shin; Jin-Won Park; Young Done Yoo

2005-08-24T23:59:59.000Z

256

E-Print Network 3.0 - atrbohd-mediated oxidative burst Sample...  

NLE Websites -- All DOE Office Websites (Extended Search)

Extinction Brandon Lohman Summary: triggered by cosmic events. A high intensity gamma ray burst directed toward Earth may have irradiated our... of nitrogen oxides. These oxides...

257

Combustion characteristics and NOx emissions of two kinds of swirl burners in a 300-MWe wall-fired pulverized-coal utility boiler  

SciTech Connect

Measurements were performed in a 300-MWe wall-fired pulverized-coal utility boiler. Enhanced ignition-dual register (EI-DR) burners and centrally fuel rich (CFR) swirl coal combustion burners were installed in the bottom row of the furnace during experiments. Local mean concentrations of O{sub 2}, CO, CO{sub 2} and NOx gas species, gas temperatures, and char burnout were determined in the region of the two types of burners. For centrally fuel rich swirl coal combustion burners, local mean CO concentrations, gas temperatures and the temperature gradient are higher and mean concentrations of O{sub 2} and NOx along the jet flow direction in the burner region are lower than for the enhanced ignition-dual register burners. Moreover, the mean O{sub 2} concentration is higher and the gas temperature and mean CO concentration are lower in the side wall region. For centrally fuel rich swirl coal combustion burners in the bottom row, the combustion efficiency of the boiler increases from 96.73% to 97.09%, and NOx emission decreases from 411.5 to 355 ppm at 6% O{sub 2} compared to enhanced ignition-dual register burners and the boiler operates stably at 110 MWe without auxiliary fuel oil.

Li, Z.Q.; Jing, J.P.; Chen, Z.C.; Ren, F.; Xu, B.; Wei, H.D.; Ge, Z.H. [Harbin Institute for Technology, Harbin (China). School for Energy Science & Engineering

2008-07-01T23:59:59.000Z

258

Study of the effects of ambient conditions upon the performance of fan powered, infrared, natural gas burners. Quarterly technical progress report, September 1--September 30, 1994  

SciTech Connect

The objective of this investigation is to characterize the operation of fan powered infrared(PIR) burner at various barometric pressures (operating altitude) and gas compositions and develop design guidelines for appliances containing PIR burners for satisfactory performance. In this program, the theoretical basis for the behavior of PIR burners will be established through analysis of the combustion, heat and mass transfer, and other related processes which determine the performance of PIR burners. Based on the results of this study, a first order model of the performance of the burner, including radiant output will be developed. The model will be applied to predict the performance of the selected burner and modified through comparison with test results. Concurrently, an experimental setup will be devised and built. This experimental rig will be a modified appliance, capable of measuring the heat and combustion product output, as well as providing a means by which the radiant heat output can be measured. The burner will be selected from an existing commercial appliance, a commercial deep fat fryer, and will be of a scale that will be compatible with the laboratory facilities in the Combustion Laboratory at Clark Atlanta University. Theoretical analysis and formulation of the PIR burner performance model has been started and the development of the test facilities and experimental setup has also been initiated. These are described.

Bai, T.

1994-10-01T23:59:59.000Z

259

Innovative Clean Coal Technology (ICCT): 180 MW demonstration of advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from coal-fired boilers. Technical progress report, first quarter 1992  

SciTech Connect

This quarterly report discusses the technical progress of a US Department of Energy (DOE) Innovative Clean Coal Technology (ICCT) Project demonstrating advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from a coal-fired boiler. The project is being conducted at Gulf Power Company`s Plant Lansing Smith Unit 2 located near Panama City, Florida. The primary objective of this demonstration is to determine the long-term effects of commercially available tangentially-fired low NO{sub x} combustion technologies on NO{sub x} emissions and boiler performance. A target of achieving fifty percent NO{sub x} reduction using combustion modifications has been established for the project. The stepwise approach that is being used to evaluate the NO{sub x} control technologies requires three plant outages to successively install the test instrumentation and the different levels of the low NO{sub x} concentric firing system (LNCFS). Following each outage, a series of four groups of tests are performed. These are (1) diagnostic, (2) performance, (3) long-term, and (4) verification. These tests are used to quantify the NO{sub x} reductions of each technology and evaluate the effects of those reductions on other combustion parameters such as particulate characteristics and boiler efficiency. This technical progess report presents the LNCFS Level III long-term data collected during this quarter. NO{sub x} emissions for each day of long-term testing are presented. The average NO{sub x} emission during long-term testing was 0.39 lb/MBtu at an average load of 155 MW. The effect of the low NO{sub x} combustion system on other combustion parameters such as carbon monoxide, excess oxygen level, and carbon carryover are also included.

Not Available

1992-05-20T23:59:59.000Z

260

Innovative Clean Coal Technology (ICCT): 180 MW demonstration of advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NO[sub x]) emissions from coal-fired boilers  

SciTech Connect

This quarterly report discusses the technical progress of a US Department of Energy (DOE) Innovative Clean Coal Technology (ICCT) Project demonstrating advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NO[sub x]) emissions from a coal-fired boiler. The project is being conducted at Gulf Power Company's Plant Lansing Smith Unit 2 located near Panama City, Florida. The primary objective of this demonstration is to determine the long-term effects of commercially available tangentially-fired low NO[sub x] combustion technologies on NO[sub x] emissions and boiler performance. A target of achieving fifty percent NO[sub x] reduction using combustion modifications has been established for the project. The stepwise approach that is being used to evaluate the NO[sub x] control technologies requires three plant outages to successively install the test instrumentation and the different levels of the low NO[sub x] concentric firing system (LNCFS). Following each outage, a series of four groups of tests are performed. These are (1) diagnostic, (2) performance, (3) long-term, and (4) verification. These tests are used to quantify the NO[sub x] reductions of each technology and evaluate the effects of those reductions on other combustion parameters such as particulate characteristics and boiler efficiency. This technical progess report presents the LNCFS Level III long-term data collected during this quarter. NO[sub x] emissions for each day of long-term testing are presented. The average NO[sub x] emission during long-term testing was 0.39 lb/MBtu at an average load of 155 MW. The effect of the low NO[sub x] combustion system on other combustion parameters such as carbon monoxide, excess oxygen level, and carbon carryover are also included.

Not Available

1992-05-20T23:59:59.000Z

Note: This page contains sample records for the topic "nitrogen oxide burner" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
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261

Innovative Clean Coal Technology (ICCT): 180 MW demonstration of advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from coal-fired boilers. Technical progress report, second quarter 1992  

SciTech Connect

This quarterly report discusses the technical progress of a US Department of Energy (DOE) Innovative Clean Coal Technology (ICCT) Project demonstrating advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from a coal-fired boiler. The project is being conducted at Gulf Power Company`s Plant Lansing Smith Unit 2 located near Panama City, Florida. The primary objective of this demonstration is to determine the long-term effects of commercially available tangentially-fired low NO{sub x} combustion technologies on NO{sub x} emissions and boiler performance. A target of achieving fifty percent NO{sub x} reduction using combustion modifications has been established for the project. The stepwise approach that is being used to evaluate the NO{sub x} control technologies requires three plant outages to successively install the test instrumentation and the different levels of the low NO{sub x} concentric firing system (LNCFS). Following each outage, a series of four groups of tests are performed. These are (1) diagnostic, (2) performance, (3) long-term, and (4) verification. These tests are used to quantify the NO{sub x} reductions of each technology and evaluate the effects of those reductions on other combustion parameters such as particulate characteristics and boiler efficiency. This technical progress report presents the LNCFS Level I short-term data collected during this quarter. In addition, a comparison of all the long-term emissions data that have been collected to date is included.

Not Available

1992-11-25T23:59:59.000Z

262

Swozzle based burner tube premixer including inlet air conditioner for low emissions combustion  

DOE Patents (OSTI)

A burner for use in a combustion system of a heavy-duty industrial gas turbine includes a fuel/air premixer having an air inlet, a fuel inlet, and an annular mixing passage. The fuel/air premixer mixes fuel and air into a uniform mixture for injection into a combustor reaction zone. The burner also includes an inlet flow conditioner disposed at the air inlet of the fuel/air premixer for controlling a radial and circumferential distribution of incoming air. The pattern of perforations in the inlet flow conditioner is designed such that a uniform air flow distribution is produced at the swirler inlet annulus in both the radial and circumference directions. The premixer includes a swozzle assembly having a series of preferably air foil shaped turning vanes that impart swirl to the airflow entering via the inlet flow conditioner. Each air foil contains internal fuel flow passages that introduce natural gas fuel into the air stream via fuel metering holes that pass through the walls of the air foil shaped turning vanes. By injecting fuel in this manner, an aerodynamically clean flow field is maintained throughout the premixer. By injecting fuel via two separate passages, the fuel/air mixture strength distribution can be controlled in the radial direction to obtain optimum radial concentration profiles for control of emissions, lean blow outs, and combustion driven dynamic pressure activity as machine and combustor load are varied.

Tuthill, Richard Sterling (Bolton, CT); Bechtel, II, William Theodore (Scotia, NY); Benoit, Jeffrey Arthur (Scotia, NY); Black, Stephen Hugh (Duanesburg, NY); Bland, Robert James (Clifton Park, NY); DeLeonardo, Guy Wayne (Scotia, NY); Meyer, Stefan Martin (Troy, NY); Taura, Joseph Charles (Clifton Park, NY); Battaglioli, John Luigi (Glenville, NY)

2002-01-01T23:59:59.000Z

263

Advanced furnace air staging and burner modifications for ultra-low NOx firing systems  

SciTech Connect

Overfire air is an effective means to reduce NOx emissions from coal fired furnaces. The current range of overfire air usage on wall-fired boilers in the US is in the range of 10 to 20%. In most cases this is enough to achieve current Title IV NOx reduction requirements. Future applications are likely to go beyond 20% Overfire Air to reduce NOx further for lower investment and operating costs of SCR retrofits. Summer ozone reduction requires NOx emissions of 0.15 lb/MBtu. Currently, industry is exploring the conditions under which this goal is attainable. The paper discussed the approach to achieve ultra-low NOx emissions by using advanced furnace air staging. It describes the unique approach of redesigning the burner to maintain low NOx burner performance when the overfire air system is added or increased in capacity. The impact on furnace corrosion and unburned carbon losses are presented. A case study is used to show the effects of overfire air both on emissions and unburned carbon.

McCarthy, K.; Laux, S.; Grusha, J.

1999-07-01T23:59:59.000Z

264

Nitrogen dioxide detection  

DOE Patents (OSTI)

Method and apparatus for detecting the presence of gaseous nitrogen dioxide and determining the amount of gas which is present. Though polystyrene is normally an insulator, it becomes electrically conductive in the presence of nitrogen dioxide. Conductance or resistance of a polystyrene sensing element is related to the concentration of nitrogen dioxide at the sensing element.

Sinha, Dipen N. (Los Alamos, NM); Agnew, Stephen F. (Los Alamos, NM); Christensen, William H. (Buena Park, CA)

1993-01-01T23:59:59.000Z

265

Smoking Status and Occupational Exposure Affects Oxidative DNA Injury in Boilermakers Exposed to Metal Fume and Residual Oil Fly Ash  

Science Journals Connector (OSTI)

...oxidative damage on the weekends (e.g., marathon running and exposure to environmental tobacco...coal tars and derived products, shale oils and soots. Part 4. 35. Lyon, France...Williams N. Vanadium poisoning from cleaning oil-fired burners. Br J Ind Med, 1952...

Sutapa Mukherjee; Lyle J. Palmer; Jee Young Kim; David B. Aeschliman; Robert S. Houk; Mark A. Woodin; and David C. Christiani

2004-03-01T23:59:59.000Z

266

Electrochemical process for the preparation of nitrogen fertilizers  

DOE Patents (OSTI)

The present invention provides methods and apparatus for the preparation of nitrogen fertilizers including ammonium nitrate, urea, urea-ammonium nitrate, and/or ammonia, at low temperature and pressure, preferably at ambient temperature and pressure, utilizing a source of carbon, a source of nitrogen, and/or a source of hydrogen or hydrogen equivalent. Implementing an electrolyte serving as ionic charge carrier, (1) ammonium nitrate is produced via the reduction of a nitrogen source at the cathode and the oxidation of a nitrogen source at the anode; (2) urea or its isomers are produced via the simultaneous cathodic reduction of a carbon source and a nitrogen source; (3) ammonia is produced via the reduction of nitrogen source at the cathode and the oxidation of a hydrogen source or a hydrogen equivalent such as carbon monoxide or a mixture of carbon monoxide and hydrogen at the anode; and (4) urea-ammonium nitrate is produced via the simultaneous cathodic reduction of a carbon source and a nitrogen source, and anodic oxidation of a nitrogen source. The electrolyte can be aqueous, non-aqueous, or solid.

Aulich, Ted R. (Grand Forks, ND); Olson, Edwin S. (Grand Forks, ND); Jiang, Junhua (Grand Forks, ND)

2012-04-10T23:59:59.000Z

267

Reading Comprehension - Liquid Nitrogen  

NLE Websites -- All DOE Office Websites (Extended Search)

Liquid Nitrogen Liquid Nitrogen Nitrogen is the most common substance in Earth's _________ crust oceans atmosphere trees . In the Earth's atmosphere, nitrogen is a gas. The particles of a gas move very quickly. They run around and bounce into everyone and everything. The hotter a gas is, the _________ slower faster hotter colder the particles move. When a gas is _________ cooled warmed heated compressed , its particles slow down. If a gas is cooled enough, it can change from a gas to a liquid. For nitrogen, this happens at a very _________ strange warm low high temperature. If you want to change nitrogen from a gas to a liquid, you have to bring its temperature down to 77 Kelvin. That's 321 degrees below zero _________ Kelvin Celsius Centigrade Fahrenheit ! Liquid nitrogen looks like water, but it acts very differently. It

268

The global nitrogen cycle in the twenty-first century  

Science Journals Connector (OSTI)

...better known than natural fixation, in part...industrial sources. The gases created are the oxidized...derived from the natural or anthropogenic...exchange between semi-natural vegetation and the...of the greenhouse gas nitrous oxide. Phil...2013 The nitrogen cascade from agricultural...

2013-01-01T23:59:59.000Z

269

Evaluation of Gas Reburning and Low-NOx Burners on a Wall-Fired Boiler  

NLE Websites -- All DOE Office Websites (Extended Search)

3 3 Evaluation of Gas Reburning and Low-NO x Burners on a Wall-Fired Boiler A DOE Assessment February 2001 U.S. Department of Energy National Energy Technology Laboratory P.O. Box 880, 3610 Collins Ferry Road Morgantown, WV 26507-0880 and P.O. Box 10940, 626 Cochrans Mill Road Pittsburgh, PA 15236-0940 website: www.netl.doe.gov Disclaimer This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. Reference

270

Burning syngas in a high swirl burner: Effects of fuel composition  

Science Journals Connector (OSTI)

Abstract Flame characteristics of swirling non-premixed H2/CO syngas fuel mixtures have been simulated using large eddy simulation and detailed chemistry. The selected combustor configuration is the TECFLAM burner which has been used for extensive experimental investigations for natural gas combustion. The large eddy simulation (LES) solves the governing equations on a structured Cartesian grid using a finite volume method, with turbulence and combustion modelling based on the localised dynamic Smagorinsky model and the steady laminar flamelet model respectively. The predictions for H2-rich and CO-rich flames show considerable differences between them for velocity and scalar fields and this demonstrates the effects of fuel variability on the flame characteristics in swirling environment. In general, the higher diffusivity of hydrogen in H2-rich fuel is largely responsible for forming a much thicker flame with a larger vortex breakdown bubble (VBB) in a swirling flame compare to the H2-lean but CO-rich syngas flames.

K.K.J. Ranga Dinesh; K.H. Luo; M.P. Kirkpatrick; W. Malalasekera

2013-01-01T23:59:59.000Z

271

Multifractal detrended fluctuation analysis of combustion flames in four-burner impinging entrained-flow gasifier  

E-Print Network (OSTI)

On a laboratory-scale testing platform of impinging entrained-flow gasifier with four opposed burners, the flame images for diesel combustion and gasification process were measured with a single charge coupled device (CCD) camera. The two-dimensional multifractal detrended fluctuation analysis was employed to investigate the multifractal nature of the flame images. Sound power-law scaling in the annealed average of detrended fluctuations was unveiled when the order $q>0$ and the multifractal feature of flame images were confirmed. Further analyses identified two multifractal parameters, the minimum and maximum singularity $\\alpha_{\\min}$ and $\\alpha_{\\max}$, serving as characteristic parameters of the multifractal flames. These two characteristic multifractal parameters vary with respect to different experimental conditions.

Niu, Miao-Ren; Yan, Zhuo-Yong; Guo, Qing-Hua; Liang, Qin-Feng; Wang, Fu-Chen; Yu, Zun-Hong

2007-01-01T23:59:59.000Z

272

Thermophotovoltaics for Combined Heat and Power Using Low NOx Gas Fired Radiant Tube Burners  

Science Journals Connector (OSTI)

Three new developments have now occurred making economical TPV systems possible. The first development is the diffused junction GaSb cell that responds out to 1.8 microns producing over 1 W/cm2 electric given a blackbody IR emitter temperature of 1250 C. This high power density along with a simple diffused junction cell makes an array cost of $0.50 per Watt possible. The second development is new IR emitters and filters that put 75% of the radiant energy in the cell convertible band. The third development is a set of commercially available ceramic radiant tube burners that operate at up to 1250 C. Herein we present near term and longer term spectral control designs leading to a 1.5 kW TPV generator / furnace incorporating these new features. This TPV generator / furnace is designed to replace the residential furnace for combined heat and power for the home.

Lewis Fraas; James Avery; Enrico Malfa; Joachim G. Wuenning; Gary Kovacik; Chris Astle

2003-01-01T23:59:59.000Z

273

A Blueprint for GNEP Advanced Burner Reactor Startup Fuel Fabrication Facility  

SciTech Connect

The purpose of this article is to identify the requirements and issues associated with design of GNEP Advanced Burner Reactor Fuel Facility. The report was prepared in support of providing data for preparation of a NEPA Environmental Impact Statement in support the U. S. Department of Energy (DOE) Global Nuclear Energy Partnership (GNEP). One of the GNEP objectives was to reduce the inventory of long lived actinide from the light water reactor (LWR) spent fuel. The LWR spent fuel contains Plutonium (Pu) -239 and other transuranics (TRU) such as Americium-241. One of the options is to transmute or burn these actinides in fast neutron spectra as well as generate the electricity. A sodium-cooled Advanced Recycling Reactor (ARR) concept was proposed to achieve this goal. However, fuel with relatively high TRU content has not been used in the fast reactor. To demonstrate the utilization of TRU fuel in a fast reactor, an Advanced Burner Reactor (ABR) prototype of ARR was proposed, which would necessarily be started up using weapons grade (WG) Pu fuel. The WG Pu is distinguished by relatively highest proportions of Pu-239 and lesser amount of other actinides. The WG Pu was assumed to be used as the startup fuel along with TRU fuel in lead test assemblies. Because such fuel is not currently being produced in the US, a new facility (or new capability in an existing facility) was being considered for fabrication of WG Pu fuel for the ABR. It was estimated that the facility will provide the startup fuel for 10-15 years and would take 3 to 5 years to construct.

S. Khericha

2010-12-01T23:59:59.000Z

274

Syngas Production from Catalytic Partial Oxidation of n-Butane: Comparison between Incipient Wetness and Sol?gel Prepared Pt/Al2O3  

Science Journals Connector (OSTI)

Syngas Production from Catalytic Partial Oxidation of n-Butane: Comparison between Incipient Wetness and Sol?gel Prepared Pt/Al2O3 ... (30, 31) To start the reaction, a Bunsen burner was used to heat the catalyst bed to its ignition temperature. ... for fuel-efficient, lean-burn vehicles, both diesel and spark-ignited. ...

Rainer J. Bass; Timothy M. Dunn; Yu-Chuan Lin; Keith L. Hohn

2008-09-10T23:59:59.000Z

275

Size-Selected Nanoparticle Chemistry: Kinetics of Soot Oxidation Kelly J. Higgins, Heejung Jung, David B. Kittelson, Jeffrey T. Roberts,*, and  

E-Print Network (OSTI)

products. Virtually every combustion system from laboratory burners to coal-fired power plants and dieselSize-Selected Nanoparticle Chemistry: Kinetics of Soot Oxidation Kelly J. Higgins, Heejung Jung, David B. Kittelson, Jeffrey T. Roberts,*, and Michael R. Zachariah*,, Department of Chemistry, Uni

Zachariah, Michael R.

276

Nitrogen-Doped Carbon Nanotube/Graphite Felts as Advanced Electrode Materials for Vanadium Redox Flow Batteries  

Science Journals Connector (OSTI)

vanadium redox flow battery; nitrogen doping; carbon nanotubes; graphite felt ... Nanorod Niobium Oxide as Powerful Catalysts for an All Vanadium Redox Flow Battery ... Nanorod Niobium Oxide as Powerful Catalysts for an All Vanadium Redox Flow Battery ...

Shuangyin Wang; Xinsheng Zhao; Thomas Cochell; Arumugam Manthiram

2012-07-27T23:59:59.000Z

277

NITROGEN REMOVAL FROM NATURAL GAS  

SciTech Connect

The objective of this project was to develop a membrane process for the denitrogenation of natural gas. Large proven reserves in the Lower-48 states cannot be produced because of the presence of nitrogen. To exploit these reserves, cost-effective, simple technology able to reduce the nitrogen content of the gas to 4-5% is required. Technology applicable to treatment of small gas streams (below 10 MMscfd) is particularly needed. In this project membranes that selectively permeate methane and reject nitrogen in the gas were developed. Preliminary calculations show that a membrane with a methane/nitrogen selectivity of 3 to 5 is required to make the process economically viable. A number of polymer materials likely to have the required selectivities were evaluated as composite membranes. Polyacetylenes such as poly(1-trimethylsilyl-1-propyne) [PTMSP] and poly(4-methyl-2-pentyne) [PMP] had high selectivities and fluxes, but membranes prepared from these polymers were not stable, showing decreasing flux and selectivity during tests lasting only a few hours. Parel, a poly(propylene oxide allyl glycidyl ether) had a selectivity of 3 at ambient temperatures and 4 or more at temperatures of {minus}20 C. However, Parel is no longer commercially available, and we were unable to find an equivalent material in the time available. Therefore, most of our experimental work focused on silicone rubber membranes, which have a selectivity of 2.5 at ambient temperatures, increasing to 3-4 at low temperatures. Silicone rubber composite membranes were evaluated in bench-scale module tests and with commercial-scale, 4-inch-diameter modules in a small pilot plant. Over six days of continuous operation at a feed gas temperature of {minus}5 to {minus}10 C, the membrane maintained a methane/nitrogen selectivity of about 3.3. Based on the pilot plant performance data, an analysis of the economic potential of the process was prepared. We conclude that a stand-alone membrane process is the lowest-cost technology for small gas streams containing less than 10% nitrogen. The membrane process can recover more than 60-70% of the hydrocarbon content of the gas at a cost of $0.60-0.70/Mscfd. The capital cost of the process is about $100-200/Mscf. A number of small operators appear to be ready to use the technology if these costs can be demonstrated in the field. A second, and perhaps better, application of the technology is to combine the membrane process with a cryogenic process to treat large gas streams containing 10-20% nitrogen. The combination process achieves significant synergies. The membrane process performs a bulk separation of the gas, after which the cryogenic process treats the membrane residue (nitrogen-enriched) gas to recover more methane. Overall, hydrocarbon recoveries are greater than 95%. The capital cost of the combination process is lower than that of either process used alone and the processing costs are in the range $0.30-0.40/Mscf. This operating cost would be attractive to many gas producers. MTR is collaborating with a producer of cryogenic systems to further develop the combination process. A number of innovations in membrane process designs were made during the project; four U.S. patents covering various aspects of the technology were filed and issued.

K.A. Lokhandwala; M.B. Ringer; T.T. Su; Z. He; I. Pinnau; J.G. Wijmans; A. Morisato; K. Amo; A. DaCosta; R.W. Baker; R. Olsen; H. Hassani; T. Rathkamp

1999-12-31T23:59:59.000Z

278

nitrogen metabolism in lakes i. measurement of nitrogen fixation with ...  

Science Journals Connector (OSTI)

the originally introduced nitrogen gas and the total amount of .... This is accom- of spontaneous O2 production, which .... free nitrogen been available; the cost of.

279

Achieving New Source Performance Standards (NSPS) Through Integration of Low-NOx Burners with an Optimization Plan for Boiler Combustion  

NLE Websites -- All DOE Office Websites (Extended Search)

Improvement Improvement Initiative (PPII) CONTACTS Brad Tomer Director Office of Major Demonstrations National Energy Technology Laboratory 3610 Collins Ferry Road P.O. Box 880 Morgantown, WV 26507-0880 304-285-4692 brad.tomer@netl.doe.gov PARTNER Sunflower Electric Power Corporation Garden City, KS Sunflower's 360 MWe Wall-fired Holcomb Station Achieving new Source PerformAnce StAndArdS (nSPS) through integrAtion of Low-no X BurnerS with An oPtimizAtion PLAn for BoiLer comBuStion (comPLeted) A unique combination of high-tech combustion modifications and sophisticated control systems was planned to be tested on a coal-fired boiler at Sunflower Electric's Holcomb Power Station in Finney County, Kansas, to demonstrate how new technology can reduce air emissions and save costs for ratepayers. However, due to larger than anticipated costs

280

On the Combustion of Hydrogen-Rich Gaseous Fuels with Low Calorific Value in a Porous Burner  

Science Journals Connector (OSTI)

It was also observed that, for the Wobbe Index varying from 5 to 44 MJ/Nm3, it is possible to burn stably at ?260 kW/m2, which reveals the fuel interchangeability potential of the present burner design. ... A range of low calorific value gaseous fuel mixtures containing CH4, H2, CO2, CO, and N2 have been burned in a porous radiant burner to analyze the effects of the fuel composition on flame stability and pollutant emissions. ... There are, however, gaps in the fundamental understanding of syngas combustion and emissions, as most previous research has focused on flames burning individual fuel components such as H2 and CH4, rather than syngas mixts. ...

R. W. Francisco, Jr.; F. Rua; M. Costa; R. C. Catapan; A. A. M. Oliveira

2009-12-30T23:59:59.000Z

Note: This page contains sample records for the topic "nitrogen oxide burner" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Nitrous oxide emissions from wastewater treatment processes  

Science Journals Connector (OSTI)

...specific ammonia oxidation rate. Symbols represent...Research Council (ARC) for funding this...correlated to its ammonia oxidation rate. 51 Arp, D...1146/annurev.micro.61.080706.093449...1146/annurev.micro.61.080706.093449...2004 Anaerobic oxidation of inorganic nitrogen...

2012-01-01T23:59:59.000Z

282

Experimental Investigations of the Lean Blowout Limit of Different Syngas Mixtures in an Atmospheric, Premixed, Variable-Swirl Burner  

Science Journals Connector (OSTI)

Experimental Investigations of the Lean Blowout Limit of Different Syngas Mixtures in an Atmospheric, Premixed, Variable-Swirl Burner ... The observed higher LBO limit of the diluted generic syngas could be due to the effect of N2 addition on the adiabatic flame temperature (Figure 18) and burning velocity of the generic syngas. ... The LSI does not need to undergo significant alteration to operate with the hydrocarbon fuels but needs further studies for adaptation to burn dild. ...

Parisa Sayad; Alessandro Schönborn; Jens Klingmann

2013-04-05T23:59:59.000Z

283

Simplified configuration for the combustor of an oil burner using a low pressure, high flow air-atomizing nozzle  

DOE Patents (OSTI)

The invention relates to clean burning of fuel oil with air. More specifically, to a fuel burning combustion head using a low-pressure, high air flow atomizing nozzle so that there will be a complete combustion of oil resulting in a minimum emission of pollutants. The improved fuel burner uses a low pressure air atomizing nozzle that does not result in the use of additional compressors or the introduction of pressurized gases downstream, nor does it require a complex design. Inventors:

Butcher, Thomas A. (Port Jefferson, NY); Celebi, Yusuf (Middle Island, NY); Fisher, Leonard (Colrain, MA)

2000-09-15T23:59:59.000Z

284

Combined Heat and Power | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

nitrogen oxide (NOx) gas-fired burner for the U.S. small industrial plant, school, and health care facility boiler market. Partners: CMCE, Inc., Santa Clara, CA, and Altex...

285

Successful low NO{sub x} burner retrofit at Delmarva Power`s Edge Moor {number_sign}5  

SciTech Connect

A team approach between the low NO{sub x} burner supplier, the architect engineer and the utility customer has led to a successful NO{sub x} reduction program that was brought in on time and under budget. Delmarva Power`s Edge Moor No. 5 a 440 MW ``El Paso`` style oil and natural gas fired unit, was successfully retrofitted with twenty-eight (28) TODD Combustion Dynaswirl-LN burners. A 55% reduction in NO{sub x} was achieved compared to the existing system of burners and overfire air; a 40% reduction was achieved with the OFA set at minimum. In addition to the NO{sub x} reduction, CO and opacity problems were reduced, excess O{sub 2} was reduced, steam temperatures were maintained and FD fan requirements were reduced. A combination of windbox modeling and advanced atomization techniques allowed the OFA ports to be fully opened, enhancing their NO{sub x} reduction effectiveness. The results presented in this paper are the first part of an on going study to determine the long term effectiveness of a LNB retrofit on NO{sub x} emission rates.

Deater, S.W.; Ward, H.J. [Delmarva Power and Light Co., Wilmington, DE (United States); Paschadag, A.E. [Burns and Roe Co., Oradell, NJ (United States); Schindler, E.S.; Guarco, J.P. [TODD Combustion, Inc., Shelton, CT (United States)

1995-12-31T23:59:59.000Z

286

Nitrogen Trifluoride-Based Fluoride- Volatility Separations Process: Initial Studies  

SciTech Connect

This document describes the results of our investigations on the potential use of nitrogen trifluoride as the fluorinating and oxidizing agent in fluoride volatility-based used nuclear fuel reprocessing. The conceptual process uses differences in reaction temperatures between nitrogen trifluoride and fuel constituents that produce volatile fluorides to achieve separations and recover valuable constituents. We provide results from our thermodynamic evaluations, thermo-analytical experiments, kinetic models, and provide a preliminary process flowsheet. The evaluations found that nitrogen trifluoride can effectively produce volatile fluorides at different temperatures dependent on the fuel constituent.

McNamara, Bruce K.; Scheele, Randall D.; Casella, Andrew M.; Kozelisky, Anne E.

2011-09-28T23:59:59.000Z

287

Rapid thermal oxidation of silicon in mixtures of oxygen and nitrous oxide  

SciTech Connect

Oxidation in nitrous oxide by conventional hot wall furnace processing and by rapid thermal oxidation (RTO) has been a subject of much interest in recent years. RTO is a fundamentally different process than furnace oxidation, however, and the full effects of this type of processing on the oxidation kinetics are not well understood. Oxidation of silicon by RTO at a variety of pressures, temperatures, and oxidation gas mixtures has been studied. Although at lower temperatures (< 850 C) the atmospheric pressure oxidation rate in nitrous oxide is very close to that in oxygen, at higher temperatures the oxidation rate in nitrous oxide is much lower than that in oxygen. At lower pressures in a RTO process, the oxidation rate in nitrous oxide is higher than that in oxygen. The effect of the nitrogen incorporated in the oxide acting as a diffusion barrier has been proposed as the mechanism of temperature dependence for atmospheric pressure oxidation in nitrous oxide. This does not explain the effects seen at lower pressure,s however, The authors propose that some of the intermediate species produced in the decomposition of nitrous oxide into molecular nitrogen, molecular oxygen, and nitric oxide play a role in the initial stages of oxidation by RTO in nitrous oxide.

Grant, J.M.; Karim, Z. [Sharp Microelectronics Technology, Inc., Camas, WA (United States)

1996-12-01T23:59:59.000Z

288

Application of multiple swirl burners in pilot-scale entrained bed gasifier for short residence time  

Science Journals Connector (OSTI)

Abstract The design concept of an entrained bed gasifier is presented. A 3 t/d-scale gasification system was constructed based on this concept. Syngas residence time in the gasifier was set to 2 s, relatively shorter than that of commercial gasifiers, to verify the possibility of complete gasification reaction within a short residence time. A series of gasification tests were conducted under high pressures and high temperatures. Performance data of the gasification experiment using multiple swirl burners showed that the carbon conversion and cold gas efficiency were higher than 98% and 72%, respectively. This high performance seemed to be attributable to the effects of rigorous mixing of oxygen and pulverized coal by the strong swirl flow and the relatively uniform oxygen concentration by the swirling plug flow. Syngas composition of the experimental result well agreed with that of the equilibrium state. This project demonstrated the feasibility of complete gasification reaction within a short residence time for low-rank coal of high reactivity.

Jin-Wook Lee; Yongseung Yun; Seok-Woo Chung; Suk-Hwan Kang; Jae-Hong Ryu; Gyoo-Tae Kim; Yong-Jeon Kim

2014-01-01T23:59:59.000Z

289

Syngas production from burner-stabilized methane/air flames: The effect of preheated reactants  

Science Journals Connector (OSTI)

The effect of preheated reactants on syngas production from a methane/air flame was investigated over a range of inlet temperatures up to 630 K. In addition to experimental measurements, the results from a burner-stabilized flame and freely-propagating flame models are presented. A comparison of the modeling and experimental results in terms of flame standoff distance, stability limit conditions and species yields show excellent agreement across a broad range of equivalence ratios and preheat temperatures. Preheating of reactants increased the rich limit for stable operation from 1.26 to 1.75 for a given inlet velocity, and syngas yields were shown to increase with equivalence ratio. The preheat temperature of the reactants was shown to have little impact on syngas yields beyond extending the limits of stable operation. The results of this study are useful for the design and analysis of heat recirculating reactors and other reactors that are designed for producing syngas through the combustion of rich mixtures.

Colin H. Smith; Daniel I. Pineda; Janet L. Ellzey

2013-01-01T23:59:59.000Z

290

Syngas production from liquid fuels in a non-catalytic porous burner  

Science Journals Connector (OSTI)

This paper investigates rich combustion of n-heptane, diesel oil, kerosene and rapeseed-oil methyl ester (RME) bio-diesel for the purpose of producing syngas ready for the clean-up stages for fuel-cell applications or for traditional combustor enrichment. Rich flames have been stabilised in a two-layer inert porous medium combustor and a range of equivalence ratios and porous materials have been examined. n-heptane was successfully reformed up to an equivalence ratio of 3, reaching a conversion efficiency (based on the lower heating value of H2 and CO over the fuel input) up to 75% for a packed bed of alumina beads. Similarly, diesel, kerosene and bio-diesel were reformed to syngas in a Zirconia foam burner with conversion efficiency over 60%. A preliminary attempt to reduce the content of CO and hydrocarbons in the reformate has been also conducted using commercial steam reforming and water–gas shift reaction catalysts, obtaining encouraging results. Finally, soot emission has been assessed, demonstrating particle formation for diesel oil above ? = 2, whereas bio-diesel showed the lowest soot formation tendency among all the fuels tested.

A. Pastore; E. Mastorakos

2011-01-01T23:59:59.000Z

291

Experimental study on particle characteristics in an opposed multi-burner gasifier  

Science Journals Connector (OSTI)

Abstract Based on the bench-scale opposed multi-burner (OMB) coal-water slurry (CWS) gasifier, temperature distributions of particles at different spatial regions, reactivity characteristics of particles and their interactions were studied with a variety of visualization techniques. The particles in gasifier are mainly classified to five types, and the principles of transformation between them are concluded as: low temperature particle without wake (LTP) could transform to low temperature particle with high temperature wake (LTP-HTW) when contacted with high temperature flame, then transform to LTP as reactions terminate and the particles become non-reactive; low temperature particle with low temperature wake (LTP-LTW) would transform to LTP-HTW when transfer to high temperature regions; as LTP-HTW adhere to the refractory wall, their wakes vanish and particles transform to high temperature particle without wake (HTP); high temperature particle with high temperature wake (HTP-HTW) could finally transform to HTP after the end of reactions. Particle groups with irregular shapes, flake-shaped and hollowed spherical structure are the forms of existence for larger size particles in gasifier.

Yan Gong; Guangsuo Yu; Qinghua Guo; Zhijie Zhou; Fuchen Wang; Yongdi Liu

2014-01-01T23:59:59.000Z

292

Turn-on fluorescent probes for detecting nitric oxide in biology  

E-Print Network (OSTI)

Chapter 1. Investigating the Biological Roles of Nitric Oxide and Other Reactive Nitrogen Species Using Fluorescent Probes: This chapter presents an overview of recent progress in the field of reactive nitrogen species ...

McQuade, Lindsey Elizabeth, 1981-

2010-01-01T23:59:59.000Z

293

NETL: Clean Coal Technology Demonstration Program (CCTDP) - Round 3  

NLE Websites -- All DOE Office Websites (Extended Search)

Full-Scale Demonstration of Low-NOx Cell Burner Retrofit - Project Brief [PDF-294KB] Full-Scale Demonstration of Low-NOx Cell Burner Retrofit - Project Brief [PDF-294KB] The Babcock & Wilcox Company, Aberdeen, OH PROGRAM PUBLICATIONS Final Reports Full-Scale Demonstration of Low-NOx Cell Burner Retrofit, Final Report [PDF-3.6MB] (July 1994) CCT Reports: Project Performance Summaries, Post-Project Assessments, & Topical Reports Full-Scale Demonstration of Low-NOx Cell Burner Retrofit, Project Performance Summary [PDF-1.18MB] (June 1999) Full-Scale Demonstration of Low-NOx Cell Burner Retrofit: A DOE Assessment [PDF-1.1MB] (Nov 2000) Reducing Emissions of Nitrogen Oxides via Low-NOx Burner Technologies, Topical Report No. 5 [PDF-825KB] (Sept 1996) Design Reports Full-Scale Demonstration of Low-NOx Cell Burner Retrofit, Public Design Report [PDF-2.68MB] (Aug 1991)

294

Advanced Fuel Cycle Economic Analysis of Symbiotic Light-Water Reactor and Fast Burner Reactor Systems  

SciTech Connect

The Advanced Fuel Cycle Economic Analysis of Symbiotic Light-Water Reactor and Fast Burner Reactor Systems, prepared to support the U.S. Advanced Fuel Cycle Initiative (AFCI) systems analysis, provides a technology-oriented baseline system cost comparison between the open fuel cycle and closed fuel cycle systems. The intent is to understand their overall cost trends, cost sensitivities, and trade-offs. This analysis also improves the AFCI Program’s understanding of the cost drivers that will determine nuclear power’s cost competitiveness vis-a-vis other baseload generation systems. The common reactor-related costs consist of capital, operating, and decontamination and decommissioning costs. Fuel cycle costs include front-end (pre-irradiation) and back-end (post-iradiation) costs, as well as costs specifically associated with fuel recycling. This analysis reveals that there are large cost uncertainties associated with all the fuel cycle strategies, and that overall systems (reactor plus fuel cycle) using a closed fuel cycle are about 10% more expensive in terms of electricity generation cost than open cycle systems. The study concludes that further U.S. and joint international-based design studies are needed to reduce the cost uncertainties with respect to fast reactor, fuel separation and fabrication, and waste disposition. The results of this work can help provide insight to the cost-related factors and conditions needed to keep nuclear energy (including closed fuel cycles) economically competitive in the U.S. and worldwide. These results may be updated over time based on new cost information, revised assumptions, and feedback received from additional reviews.

D. E. Shropshire

2009-01-01T23:59:59.000Z

295

Interactions of Fluorine Redistribution and Nitrogen Incorporation with Boron Diffusion in Silicon Dioxide  

E-Print Network (OSTI)

Interactions of Fluorine Redistribution and Nitrogen Incorporation with Boron Diffusion in Silicon Dioxide Mitra Navi and Scott Dunham Department of Electrical and Computer Engineering Boston University diffusion. Gate oxides were grown with nitrogen contents varying from 0 to 1.4%. A series of SIMS mea

Dunham, Scott

296

Combustion analysis of an equimolar mixture of methane and syngas in a surface-stabilized combustion burner for household appliances  

Science Journals Connector (OSTI)

Abstract The primary objective of this work is to study the combustion of an equimolar mixture of methane and syngas (CH4–SG) in a ceramic surface-stabilized combustion burner. We examine the effects of the fuel composition, the air-to-fuel ratio and the thermal input on the flame stability, the radiation efficiency and the pollutant emissions (CO and NOx). In this study, we evaluate a syngas with a high hydrogen content that is similar to those obtained by coal gasification (50–60% H2) using Sasol/Lurgi gasification technology and biomass gasification, for example. To determine the effect of the air-to-fuel ratio (?), the burner performance is analyzed at ? = 1.4 and ? = 1.1. Some studies have reported optimal operating conditions for ? = 1.4, whereas for hydrocarbons, the proximity to stoichiometric conditions at the ? = 1.1 air-to-fuel ratio produces the highest possible laminar burning velocity and flame temperature. The thermal inputs evaluated in this study correspond to three values (1.0, 1.8, and 2.5 kW) found in household appliances and for cooking appliances in particular. The results for this experimental burner design indicate that the macroscopic flame shape for an equimolar CH4–SG mixture is approximately the same as that for CH4. Moreover, the pollutant concentrations in the flue gas are generally below 85 ppm for CO and 15 ppm for NOx. However, the thermal input and the air-to-fuel ratio significantly affect the flame structure, the radiation efficiency and the pollutant emissions.

Carlos E. Arrieta; Andrés A. Amell

2014-01-01T23:59:59.000Z

297

Oil burners: Crude oil, atomization, and combustion efficiency. (Latest citations from the NTIS bibliographic database). Published Search  

SciTech Connect

The bibliography contains citations concerning fuel properties and boiler operations techniques to make maximum use of heavy crude oil, shale oil, and low grade fuels to reduce energy costs in boiler firing. Fuel properties pertain to chemical constituents, viscosity, desulfurization, and processing methods to upgrade the fuels. Operating techniques include atomization, dual-fuel burners, emission characteristics, and cost factors. Combustion efficiency is examined and some citations report on additives or processing techniques to improve the efficiency. The citations also report on studies of health effects in the use of synfuels, mostly as coal liquids to replace oil. (Contains 250 citations and includes a subject term index and title list.)

Not Available

1994-12-01T23:59:59.000Z

298

The design of stable high nitrogen systems  

SciTech Connect

A general strategy for the design of high nitrogen systems with an adequate degree of stability has been elaborated. The design of nitro compounds in which terminal nitro groups are bonded to the chain of several heteroatoms is a specific case within the strategy. In the process of working out the strategy a number of new high nitrogen systems (dinitrazenic acid or dinitroamide HN{sub 3}O{sub 4} and its salts, nitrodiazene oxides RN{sub 3}O{sub 3} and tetrazine dioxides) were discovered. A new of new types of nitro compounds (bicyclo nitro-bis-hydroxylamine, nitrohydrazine, nitrohydroxylamine, sulfo-N-nitroimide and bis-N-nitroimide) were synthesized. This study opens new prospects in the field of the synthesis of high energy materials.

Tartakovsky, V.A. [Russian Academy of Sciences, Moscow (Russian Federation). N.D. Zelinsky Inst. of Organic Chemistry

1996-07-01T23:59:59.000Z

299

Small (5 million Btu/h) and large (300 million Btu/h) thermal test rigs for coal and coal slurry burner development  

SciTech Connect

NEI International Combustion Ltd. of Derby, England, now operates two thermal test rigs for the development of burners capable of handling coal-water slurries (CWS). A general description of the large rig and its capacity was given. Also, the necessary conversions of the equipment to handle CWS were described. Information on the properties of the CWS was included. This consisted of chemical analysis of the parent coal and the slurry, sieve analysis of a dry sample, and viscosity versus temperature data of the CWS. The process of design development of the burner was outlined. Ten illustrations were presented, including schematic diagrams of equipment and graphs of data.

Allen, J.W.; Beal, P.R.; Hufton, P.F.

1983-01-01T23:59:59.000Z

300

New chemistry with gold-nitrogen complexes: synthesis and characterization of tetra-, tri-, and dinuclear gold(I) amidinate complexes. Oxidative-addition to the dinuclear gold(I) amidinate  

E-Print Network (OSTI)

catalyst precursors for CO oxidation on TiO2 surface reported to date (87% conversion). The dinuclear gold(I) amidinate complex with a Auâ ¦Au distance of 2.711(3) Ã is rare. To our knowledge, there is only one other example of a symmetrical dinuclear gold...

Abdou, Hanan Elsayed

2009-06-02T23:59:59.000Z

Note: This page contains sample records for the topic "nitrogen oxide burner" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

E-Print Network 3.0 - anesthetic nitrous oxide Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

such concentrations of anesthetics are safe... ), hypoxemia (eg, nitrogen and carbon monoxide), addiction (eg, nitrous oxide), or health effects resulting... from chronic exposure...

302

E-Print Network 3.0 - attenuates oxidative damage Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

Collection: Computer Technologies and Information Sciences 40 Charge-trapping properties of gate oxide grown on nitrogen-implanted silicon substrate Summary: Charge-trapping...

303

FUEL CELLS – SOLID OXIDE FUEL CELLS | Systems  

Science Journals Connector (OSTI)

In this article, some basic arrangements of solid oxide fuel cell (SOFC) systems are described, starting with atmospheric systems using a catalytic burner or a thermal burner and anode gas recycling. For illustrating the potential electrical efficiency of SOFC systems, their combination with a gas turbine and also with a steam turbine (ST) are described. To be able to evaluate the potential of the different systems, first the essential efficiencies relevant to fuel cell systems are defined and then the basics of calculating energy balance are illustrated. Equations are given to describe, for example, the effect of fuel recycling on system fuel utilization and of internal reforming on the necessary air flow for cooling the stack. It is obvious that electrical efficiency depends strongly on cell voltage and fuel utilization. In the case of cells that operate with a high fuel utilization at cell voltages of 800 mV, a net electrical efficiency above 55% can be achieved. The combination in a pressurized system with a gas turbine enables efficiencies of up to 70% and combining this system with an additional ST allows efficiencies of up to 75%. However, an investigation into the size of these \\{STs\\} shows that such combined systems make sense only above a gas input of 10 MW.

L. Blum; E. Riensche

2009-01-01T23:59:59.000Z

304

Viscosity Measurements on Nitrogen  

Science Journals Connector (OSTI)

Viscosity Measurements on Nitrogen ... (15)?Clarke, A. G.; Smith, E. B. Low-temperature viscosities and intermolecular forces of simple gases. ... The coupling also serves as a frictionless bearing for a slender rotating cylindrical body which is slowed down due to the viscous drag of the fluid surrounding the cylinder. ...

Daniel Seibt; Eckhard Vogel; Eckard Bich; Daniel Buttig; Egon Hassel

2006-01-11T23:59:59.000Z

305

ODD NITROGEN PROCESSES  

SciTech Connect

This chapter is in three parts. The first concerns interpretations that can be made from atmospheric observations regarding nitrogen compounds and ozone, the second reviews some predictions made by atmospheric models, and the third compares between certain model results and atmospheric measurements with an emphasis on detecting evidence of significant disagreements.

Johnston, Harold S.

1980-01-01T23:59:59.000Z

306

ACS Div of Fuel Chem Preprints 44:4, 1016-1019 (August, 1999) KINETICS OF HIGH PRESSURE CHAR OXIDATION  

E-Print Network (OSTI)

) and are fairly well agreed upon; however, kinetic data for char oxidation at elevated pressures are very limited in a fixed-bed reactor from 2-10 atmospheres and 850-1200K with a bituminous coal char, and showed a decrease ­ designated P1 and P2 - were used in this study. Both were produced in a methane flat-flame burner (FFB

Fletcher, Thomas H.

307

DURABILITY OF VERY LOW CAPACITY PRESSURE ATOMIZED FUEL NOZZLES USED WITH LOW FIRING RATE RESIDENTIAL OIL BURNERS.  

SciTech Connect

Brookhaven National Laboratory (BNL), working for the United States Department of Energy (DOE), has conducted a preliminary evaluation of the potential of very low fuel input capacity Simplex type pressure atomizing nozzles for use with oil burners designed for residential boilers, furnaces and water heaters. These nozzles under suitable conditions can be sufficiently reliable to enable new heating system designs. This would allow for the design of heating appliances that match the smaller load demands of energy efficient homes built with modern components and architectural systems designed to minimize energy use. When heating systems are installed with excessive capacity, oversized by three to four times the load, the result is a loss of up to ten percent as compared to the rated appliance efficiency. The use of low capacity nozzles in systems designed to closely match the load can thereby result in significant energy savings. BNL investigated the limitations of low flow rate nozzles and designed long-term experiments to see if ways could be determined that would be beneficial to long-term operation at low input capacities without failures. In order to maximize the potential for success the best possible industry practices available were employed. Low flow rate nozzles primarily fail by blockage or partial blockage of internal fuel flow passages inside the nozzle. To prevent any contaminants from entering the nozzle BNL investigated the geometry and critical dimensions and the current sate of the art of fuel filter design. Based on this investigation it was concluded that the best available filters should be more than capable of filtering contaminants from the fuel prior to entering the oil burner itself. This position was indeed validated based on the long-term trials conducted under this study no evidence resulted to change our position. It is highly recommended that these filters rated at 10 microns and with large filter capacity (surface area), should be used with all oil burner installations. The other possible failure mode had been attributed to fuel degradation and this became the main focus of the evaluation. The degradation of fuel usually occurs faster under higher temperature conditions. To preclude this as much as possible controls that provided for a post-purge of combustion airflow after burner shut down were selected. This provided a short period of time where the burner's combustion air blower continues to operate after the flame has gone out. This tends to cool the nozzle and in turn the fuel inside the small flow pathways inside the nozzle components. This study concludes that the use of low capacity nozzles is possible but only when the temperature and thermal mass environment of the combustion chamber result in a relatively ''cool'' condition. This was accomplished in one long-term experiment that essentially operated for a full heating season equivalent with no evidence of nozzle plugging or failure. The nozzle body surface temperature was kept at or below 150 F during the duration of the trial. On the other hand, a second system was studied that ended in a partial nozzle blockage and a system failure. In this ''hot environment'' system the nozzle body temperature reached 210 F. This occurred at close to a full heating season equivalent, yet it still would have resulted in a no-heat complaint by the homeowner.

MCDONALD,R.J.

2007-05-01T23:59:59.000Z

308

Frostbite Theater - Liquid Nitrogen Experiments - Liquid Nitrogen and  

NLE Websites -- All DOE Office Websites (Extended Search)

Freeze the Rainbow! Freeze the Rainbow! Previous Video (Freeze the Rainbow!) Frostbite Theater Main Index Next Video (Liquid Nitrogen and Fire!) Liquid Nitrogen and Fire! Liquid Nitrogen and Antifreeze! What happens when the freezing power of liquid nitrogen meets the antifreezing power of ethylene glycol? [ Show Transcript ] Announcer: Frostbite Theater presents... Cold Cuts! No baloney! Joanna and Steve: Just science! Joanna: Hi! I'm Joanna! Steve: And I'm Steve! Joanna: What happens when the freezing power of liquid nitrogen... Steve: ...meets the antifreezing power of ethylene glycol! Joanna: While a mix of 70 percent ethylene glycol and 30 percent water doesn't freeze until 60 degrees below zero, it's still no match for liquid nitrogen. At 321 degrees below zero, liquid nitrogen easily freezes

309

Frostbite Theater - Liquid Nitrogen Experiments - Liquid Nitrogen in a  

NLE Websites -- All DOE Office Websites (Extended Search)

Freeze Liquid Nitrogen! Freeze Liquid Nitrogen! Previous Video (Let's Freeze Liquid Nitrogen!) Frostbite Theater Main Index Next Video (Freeze the Rainbow!) Freeze the Rainbow! Liquid Nitrogen in a Microwave! What happens when the world's most beloved cryogenic liquid meets one of the most common household appliances? Find out when we try to microwave liquid nitrogen! [ Show Transcript ] Announcer: Frostbite Theater presents... Cold Cuts! No baloney! Joanna and Steve: Just science! Joanna: Hi! I'm Joanna! Steve: And I'm Steve! Joanna: A little while ago we received an email from Star of the Sea Catholic School in Virginia Beach, Virginia, asking what happens when you place liquid nitrogen in a microwave. Well, I just happen to have some liquid nitrogen! Steve: And I just happen to have a microwave!

310

Methane/nitrogen separation process  

DOE Patents (OSTI)

A membrane separation process is described for treating a gas stream containing methane and nitrogen, for example, natural gas. The separation process works by preferentially permeating methane and rejecting nitrogen. The authors have found that the process is able to meet natural gas pipeline specifications for nitrogen, with acceptably small methane loss, so long as the membrane can exhibit a methane/nitrogen selectivity of about 4, 5 or more. This selectivity can be achieved with some rubbery and super-glassy membranes at low temperatures. The process can also be used for separating ethylene from nitrogen. 11 figs.

Baker, R.W.; Lokhandwala, K.A.; Pinnau, I.; Segelke, S.

1997-09-23T23:59:59.000Z

311

Methane/nitrogen separation process  

DOE Patents (OSTI)

A membrane separation process for treating a gas stream containing methane and nitrogen, for example, natural gas. The separation process works by preferentially permeating methane and rejecting nitrogen. We have found that the process is able to meet natural gas pipeline specifications for nitrogen, with acceptably small methane loss, so long as the membrane can exhibit a methane/nitrogen selectivity of about 4, 5 or more. This selectivity can be achieved with some rubbery and super-glassy membranes at low temperatures. The process can also be used for separating ethylene from nitrogen.

Baker, Richard W. (Palo Alto, CA); Lokhandwala, Kaaeid A. (Menlo Park, CA); Pinnau, Ingo (Palo Alto, CA); Segelke, Scott (Mountain View, CA)

1997-01-01T23:59:59.000Z

312

Nitrogen enriched combustion of a natural gas internal combustion engine to reduce NO.sub.x emissions  

DOE Patents (OSTI)

A method and system for reducing nitrous oxide emissions from an internal combustion engine. An input gas stream of natural gas includes a nitrogen gas enrichment which reduces nitrous oxide emissions. In addition ignition timing for gas combustion is advanced to improve FCE while maintaining lower nitrous oxide emissions.

Biruduganti, Munidhar S. (Naperville, IL); Gupta, Sreenath Borra (Naperville, IL); Sekar, R. Raj (Naperville, IL); McConnell, Steven S. (Shorewood, IL)

2008-11-25T23:59:59.000Z

313

Gas-phase and catalytic combustion in heat-recirculating burners Jeongmin Ahn, Craig Eastwood, Lars Sitzki* and Paul D. Ronney  

E-Print Network (OSTI)

title: Extinction limits in excess enthalpy burners To be published in Proceedings of the Combustion that hydrocarbon fuels contain 100 times more energy per unit mass than lithium-ion batteries, thus devices engines may be impractical. Consequently, many groups have considered heat-recirculating, or "excess

314

Low-Emission Premixed Porous Inert Media (PIM) Burner System Fueled with Vegetable (Rapeseed) Oil Using a Flow Velocity Flame Stabilization Technique  

Science Journals Connector (OSTI)

† Mechanical Engineering Department, Faculty of Engineering and Technology, University of Tanta, Tanta, Egypt ... In the present work, the suitability of vegetable (rapeseed) oil as a renewable, biodegradable, and environmentally friendly source of energy to operate porous inert medium (PIM) atmospheric burners was examined. ...

Ayman Bakry; A. Al-Salaymeh; Ala H. Al-Muhtaseb; A. Abu-Jrai; D. Trimis; F. Durst

2009-10-29T23:59:59.000Z

315

Regenerative catalytic oxidation  

SciTech Connect

Currently Regenerative Thermal Oxidizers (R.T.O.`s) are an accepted technology for the control of volatile organic compounds (VOC`s) and hazardous air pollutants (HAP`s). This control technology, when introduced, offered substantial reductions in operating costs, especially auxiliary fuel requirements when compared to existing control technologies such as recuperative thermal and recuperative catalytic oxidizers. While these savings still exist, there is a demand for control of new and/or hybrid technologies, one of which is Regenerative Catalytic Oxidizers (R.C.O.`s). This paper will explore the development of regenerative catalytic oxidation from the theoretical stage through pilot testing through a commercial installation. The operating cost of R.C.O.`s will be compared to R.T.O.`s to verify the savings that are achievable through the use of regenerative catalytic oxidation. In the development of this technology, which is a combination of two (2) existing technologies, R.T.O.`s and catalysis, a second hybrid technology was explored and pilot tested. This is a combination R.C.O. for VOC and HAP control and simultaneous SCR (Selective Catalytic Reduction) for NOx (Oxides of Nitrogen) control. Based on the pilot and full scale testing, both regenerative catalytic oxidizers and systems which combine R.C.O. with SCR for both VOC and NOx reduction are economically viable and are in fact commercially available. 6 figs., 2 tabs.

Gribbon, S.T. [Engelhard Process Emission Systems, South Lyon, MI (United States)

1996-12-31T23:59:59.000Z

316

Effect of Co-Firing Torrefied Woody Biomass with Coal in a 30 kWt Downfired Burner  

E-Print Network (OSTI)

emission plotted against respective fuel nitrogen loading numbers for ER = 0.9. ..................................................................................................... 141 Fig. 55. Variation of OHTC ratios with time for the combustion...

Thanapal, Siva S

2014-04-25T23:59:59.000Z

317

CO2 Gasification Rates of Petroleum Coke in a Pressurized Flat-Flame Burner Entrained-Flow Reactor  

Science Journals Connector (OSTI)

Two petcoke samples were gasified by CO2 at total pressures of 10 and 15 atm in a high-pressure flat-flame burner reactor at conditions where the bulk phase consisted of either 40 or 90 mol % CO2 with gas temperatures up to 1909 K. Particle diameters of 45–75 ?m were used in the experiments. ... The mass release data caused by CO2 gasification of the petcoke chars were fit to a global first-order model, and the optimal kinetic parameters are reported. ... The CO2 char gasification rates of both petcokes were shown to be higher than Illinois #6 coal when reacted at conditions of high temperature and pressure, even though most reactivity comparisons between petcoke and coal at lower temperature, pressure, and heating rates typically result in coal being more reactive. ...

Aaron D. Lewis; Emmett G. Fletcher; Thomas H. Fletcher

2014-06-05T23:59:59.000Z

318

Oil burners: Crude oil, atomization, and combustion efficiency. (Latest citations from the NTIS bibliographic database). Published Search  

SciTech Connect

The bibliography contains citations concerning fuel properties and boiler operations techniques to make maximum use of heavy crude oil, shale oil, and low grade fuels to reduce energy costs in boiler firing. Fuel properties pertain to chemical constituents, viscosity, desulfurization, and processing methods to upgrade the fuels. Operating techniques include atomization, dual-fuel burners, emission characteristics, and cost factors. Combustion efficiency is examined and some citations report on additives or processing techniques to improve the efficiency. The citations also report on studies of health effects in the use of synfuels, mostly as coal liquids to replace oil. (Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)

NONE

1996-03-01T23:59:59.000Z

319

Oil burners: Crude oil, atomization, and combustion efficiency. (Latest citations from the NTIS bibliographic database). Published Search  

SciTech Connect

The bibliography contains citations concerning fuel properties and boiler operations techniques to make maximum use of heavy crude oil, shale oil, and low grade fuels to reduce energy costs in boiler firing. Fuel properties pertain to chemical constituents, viscosity, desulfurization, and processing methods to upgrade the fuels. Operating techniques include atomization, dual-fuel burners, emission characteristics, and cost factors. Combustion efficiency is examined and some citations report on additives or processing techniques to improve the efficiency. The citations also report on studies of health effects in the use of synfuels, mostly as coal liquids to replace oil. (Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)

NONE

1997-06-01T23:59:59.000Z

320

Method of removing nitrogen monoxide from a nitrogen monoxide-containing gas using a water-soluble iron ion-dithiocarbamate, xanthate or thioxanthate  

DOE Patents (OSTI)

A method of removing nitrogen monoxide from a nitrogen monoxide-containing gas, which method comprises: (a) contacting a nitrogen oxide-containing gas with an aqueous solution of water soluble organic compound-iron ion chelate of the formula: ##STR1## wherein the water-soluble organic compound is selected from compounds of the formula: ##STR2## wherein: R is selected from hydrogen or an organic moiety having at least one polar functional group; Z is selected from oxygen, sulfur, or --N--A wherein N is nitrogen and A is hydrogen or lower alkyl having from one to four carbon atoms; and M is selected from hydrogen, sodium or potassium; and n is 1 or 2, in a contacting zone for a time and at a temperature effective to reduce the nitrogen monoxide. These mixtures are useful to provide an unexpensive method of removing NO from gases, thus reducing atmospheric pollution from flue gases.

Liu, David K. (San Pablo, CA); Chang, Shih-Ger (El Cerrito, CA)

1989-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "nitrogen oxide burner" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

TiO2 nanoparticles on nitrogen-doped graphene as anode material for lithium ion batteries  

Science Journals Connector (OSTI)

Anatase TiO2...nanoparticles in situ grown on nitrogen-doped, reduced graphene oxide (rGO) have been successfully synthesized ... as an anode material for the lithium ion battery. The nanosized TiO2 particles wer...

Dan Li; Dongqi Shi; Zongwen Liu; Huakun Liu…

2013-04-01T23:59:59.000Z

322

Oxides Emissions from Coal-Fired Boilers TOPICAL REPORT NUMBER 14  

NLE Websites -- All DOE Office Websites (Extended Search)

Reburning Technologies for the Control of Nitrogen Reburning Technologies for the Control of Nitrogen Oxides Emissions from Coal-Fired Boilers TOPICAL REPORT NUMBER 14 MAY 1999 TOPICAL REPORT NUMBER 14 A report on three projects conducted under separate cooperative agreements between: The U.S. Department of Energy and * The Babcock & Wilcox Company * Energy and Environmental Research Corporation * New York State Electric & Gas Corporation MAY 1999 Reburning Technologies for the Control of Nitrogen Oxides Emissions from Coal-Fired Boilers Cover image: Schematic of reburning technology Source: Energy and Environmental Research Corporation Reburning Technologies for the Control of Nitrogen Oxides Emissions from Coal-Fired Boilers Executive Summary ..................................................................................................

323

Radiation Damage in Nuclear Fuel for Advanced Burner Reactors: Modeling and Experimental Validation  

SciTech Connect

The consortium has completed its existence and we are here highlighting work and accomplishments. As outlined in the proposal, the objective of the work was to advance the theoretical understanding of advanced nuclear fuel materials (oxides) toward a comprehensive modeling strategy that incorporates the different relevant scales involved in radiation damage in oxide fuels. Approaching this we set out to investigate and develop a set of directions: 1) Fission fragment and ion trajectory studies through advanced molecular dynamics methods that allow for statistical multi-scale simulations. This work also includes an investigation of appropriate interatomic force fields useful for the energetic multi-scale phenomena of high energy collisions; 2) Studies of defect and gas bubble formation through electronic structure and Monte Carlo simulations; and 3) an experimental component for the characterization of materials such that comparisons can be obtained between theory and experiment.

Niels Gronbech Jensen; Mark Asta; Nigel Browning'Vidvuds Ozolins; Axel van de Walle; Christopher Wolverton

2011-12-29T23:59:59.000Z

324

EIA - Greenhouse Gas Emissions - Nitrous Oxide Emissions  

Gasoline and Diesel Fuel Update (EIA)

4. Nitrous Oxide Emissions 4. Nitrous Oxide Emissions 4.1 Total emissions U.S. nitrous oxide emissions in 2009 were 4 MMTCO2e (1.7 percent) below their 2008 total (Table 22). Sources of U.S. nitrous oxide emissions include agriculture, energy use, industrial processes, and waste management (Figure 22). The largest source is agriculture (73 percent), and the majority of agricultural emissions result from nitrogen fertilization of agricultural soils (87 percent of the agriculture total) and management of animal waste (13 percent). U.S. nitrous oxide emissions rose from 1990 to 1994, fell from 1994 to 2002, and returned to an upward trajectory from 2003 to 2007, largely as a result of increased use of synthetic fertilizers. Fertilizers are the primary contributor of emissions from nitrogen fertilization of soils, which grew by more than 30 percent from

325

Increased Cytotoxicity of Oxidized Flame Soot  

NLE Websites -- All DOE Office Websites (Extended Search)

Increased Cytotoxicity of Oxidized Flame Soot Increased Cytotoxicity of Oxidized Flame Soot Title Increased Cytotoxicity of Oxidized Flame Soot Publication Type Journal Article Year of Publication 2012 Authors Holder, Amara L., Brietta J. Carter, Regine Goth-Goldstein, Donald Lucas, and Catherine P. Koshland Journal Atmospheric Pollution Research Volume 3 Start Page 25 Issue 1 Pagination 25-31 Date Published 01/2012 Keywords health effects, ozone, soot, toxicity Abstract Combustion-generated particles released into the atmosphere undergo reactions with oxidants, which can change the particles' physiochemical characteristics. In this work, we compare the physical and chemical properties and cellular response of particles fresh from a flame with those oxidized by ozone and nitrogen dioxide. The reaction with ozone and nitrogen dioxide does not significantly modify the physical characteristics of the particles (primary particle size, fractal dimension, and surface area). However, oxidation affects the chemical characteristics of the particles, creating more oxygen and nitrogen containing functional groups, and increases their hydrophilicity. In addition, oxidized soot generates more reactive oxygen species, as measured by the dithiothreitol (DTT) assay. Furthermore, oxidized soot is 1.5-2 times more toxic than soot that was not reacted with ozone, but the inflammatory response, measured by interleukin-8 (IL-8) secretion, is unchanged. These results imply that combustion-generated particles released into the atmosphere will have an increased toxicity on or after high ozone days.

326

Frostbite Theater - Liquid Nitrogen Experiments - Liquid Nitrogen and Fire!  

NLE Websites -- All DOE Office Websites (Extended Search)

Antifreeze! Antifreeze! Previous Video (Liquid Nitrogen and Antifreeze!) Frostbite Theater Main Index Next Video (Liquid Nitrogen and the Tea Kettle Mystery!) Liquid Nitrogen and the Tea Kettle Mystery! Liquid Nitrogen and Fire! A burning candle is placed in a container of liquid nitrogen! Filmed in front of a live studio audience. Well, they were live when we started... [ Show Transcript ] Announcer: Frostbite Theater presents... Cold Cuts! No baloney! Joanna and Steve: Just science! Steve: Now, then. I'm a little bit afraid to ask this next question because I think I already know the answer, but is anyone in here feeling a little... dangerous? You're willing to take a chance? Because I am willing to do an experiment they haven't let me do since 'The Incident.' Now, because of the danger, I cannot have a volunteer. I must do this on my

327

What Happens to Nitrogen in Soils?  

E-Print Network (OSTI)

This publication explains the chemistry of nitrogen, the processes by which nitrogen is added to and removed from the soil, and methods of preventing nitrogen losses on agricultural lands....

Provin, Tony; Hossner, L. R.

2001-07-09T23:59:59.000Z

328

Operational results of a low NO{sub x} burner retrofit on a 780 net MW{sub e} PC-fired utility boiler  

SciTech Connect

The primary objective of this project was to comply with state and federal clean air regulations while maintaining operational flexibility and control. This objective was accomplished with the installation of DRB-XCL{reg_sign} burners with a separated overfire air system. The DRB-XCL{reg_sign} burners can consistently achieve 0.5 lbs/10{sup 6} Btu NO{sub x} or less. Even lower NO{sub x} levels can be achieved with the new equipment. However, increased carbon levels affecting stack opacity prevent long-term operation at this level with the existing scrubbing equipment. Final test results indicated that the project goals were met with some exceeded. The results of this project pointed out the numerous interactions of all of the interrelated complex systems in today`s state-of-the-art power plants. The increase in unburned carbon levels affected the wet scrubber and impacted stack plume color. Being one indicator of inefficiency, this item is currently being reviewed to take advantage of further improving operating efficiency. Mechanical reliability of the Babcock & Wilcox DRB-XCL{reg_sign} burner has been good and it is estimated that long-term maintenance costs will be low. Close cooperation between Ohio Edison and B&W contributed positively to the success of this project.

Bryk, S.A.; Cioffi, P.L.; Tucker, T.J. [Babcock & Wilcox, Barberton, OH (United States); Mellody, J.G. [Ohio Edison Co., Akron, OH (United States); Hooks, M.E. [Pennsylvania Power Co., Shippingport, PA (United States)

1995-12-31T23:59:59.000Z

329

Investigation of formation of nitrogen compounds in coal combustion. Final report  

SciTech Connect

This is the final report on DOE contract number DE-AC21-80MC14061. It concerns the formation of nitrogen oxide from fuel-bound nitrogen during coal combustion. The work reported was divided into three tasks. They addressed problems of time-resolving pyrolysis rates of coal under simulated combustion conditions, the combustion of the tar that results from such pyrolysis, and theoretical modeling of the pyrolysis process. In all of these tasks, special attention was devoted to the fate of coal nitrogen. The first two tasks were performed by Exxon Research and Engineering Company. 49 references.

Blair, D.W.; Crane, I.D.; Wendt, J.O.L.

1983-10-01T23:59:59.000Z

330

Frostbite Theater - Liquid Nitrogen Experiments - Instant Liquid Nitrogen  

NLE Websites -- All DOE Office Websites (Extended Search)

Freezing Balloons! Freezing Balloons! Previous Video (Freezing Balloons!) Frostbite Theater Main Index Next Video (Shattering Flowers!) Shattering Flowers! Instant Liquid Nitrogen Balloon Party! Need a bunch of balloons blown-up quickly? Liquid nitrogen to the rescue! [ Show Transcript ] Announcer: Frostbite Theater presents... Cold Cuts! No baloney! Joanna and Steve: Just science! Joanna: Hi! I'm Joanna! Steve: And I'm Steve! Joanna: We've been making videos for a while now and we've learned that people like balloons and liquid nitrogen! Steve: So... Here you go! Balloon: Crackling... Balloon: Pop! Joanna: Ooh! Balloon: Pop! Balloon: Pop! Steve: If you'd like to know the science of what's going on behind this, please one of our first videos, "Liquid Nitrogen Experiments: The Balloon."

331

Initial test results of the limestone injection multistage burner (LIMB) demonstration project. Report for September 1984-April 1988  

SciTech Connect

This paper discusses SO/sub 2/ removal efficiency and low-NOx burner performance obtained during short term tests, as well as the impact of LIMB ash on electrostatic precipitator (ESP) performance at Ohio Edison's Edgewater Station. Project goals are to demonstrate 50% or more SO/sub 2/ removal at a Ca/S molar stoichiometry of 2.0 and NOx emissions of less than 0.5 lb/million Btu while maintaining boiler operability and reliability. The tests, conducted before September 1987, indicated that 55-60% SO/sub 2/ removal and NOx emissions on the order of 0.48 lb/million Btu are achievable. The increased dust loading of a high-resistivity ash typically limited continuous operation to 2-6 hr. The paper discusses how the LIMB ash gave rise to back corona which, in turn, increased stack opacity to regulated levels. The extension of the project to include humidification of the flue gas is also described as a way to minimize these effects.

Nolan, P.S.; Hendriks, R.V.

1988-05-01T23:59:59.000Z

332

It's Elemental - The Element Nitrogen  

NLE Websites -- All DOE Office Websites (Extended Search)

Carbon Carbon Previous Element (Carbon) The Periodic Table of Elements Next Element (Oxygen) Oxygen The Element Nitrogen [Click for Isotope Data] 7 N Nitrogen 14.0067 Atomic Number: 7 Atomic Weight: 14.0067 Melting Point: 63.15 K (-210.00°C or -346.00°F) Boiling Point: 77.36 K (-195.79°C or -320.44°F) Density: 0.0012506 grams per cubic centimeter Phase at Room Temperature: Gas Element Classification: Non-metal Period Number: 2 Group Number: 15 Group Name: Pnictogen What's in a name? From the Greek words nitron and genes, which together mean "saltpetre forming." Say what? Nitrogen is pronounced as NYE-treh-gen. History and Uses: Nitrogen was discovered by the Scottish physician Daniel Rutherford in 1772. It is the fifth most abundant element in the universe and makes up

333

Nitrogen removal from natural gas  

SciTech Connect

According to a 1991 Energy Information Administration estimate, U.S. reserves of natural gas are about 165 trillion cubic feet (TCF). To meet the long-term demand for natural gas, new gas fields from these reserves will have to be developed. Gas Research Institute studies reveal that 14% (or about 19 TCF) of known reserves in the United States are subquality due to high nitrogen content. Nitrogen-contaminated natural gas has a low Btu value and must be upgraded by removing the nitrogen. In response to the problem, the Department of Energy is seeking innovative, efficient nitrogen-removal methods. Membrane processes have been considered for natural gas denitrogenation. The challenge, not yet overcome, is to develop membranes with the required nitrogen/methane separation characteristics. Our calculations show that a methane-permeable membrane with a methane/nitrogen selectivity of 4 to 6 would make denitrogenation by a membrane process viable. The objective of Phase I of this project was to show that membranes with this target selectivity can be developed, and that the economics of the process based on these membranes would be competitive. Gas permeation measurements with membranes prepared from two rubbery polymers and a superglassy polymer showed that two of these materials had the target selectivity of 4 to 6 when operated at temperatures below - 20{degrees}C. An economic analysis showed that a process based on these membranes is competitive with other technologies for small streams containing less than 10% nitrogen. Hybrid designs combining membranes with other technologies are suitable for high-flow, higher-nitrogen-content streams.

NONE

1997-04-01T23:59:59.000Z

334

Superior catalysts for selective catalytic reduction of nitric oxide. Quarterly technical progress report, January 1, 1995--March 31, 1995  

SciTech Connect

During this quarter, progress was made on the following tasks: TPD techniques were employed to study the reaction mechanism of the selective catalytic reduction of nitrogen oxide with ammonia over iron oxide pillared clay catalyst; and a sulfur dioxide resistant iron oxide/titanium oxide catalyst was developed.

Li, W.B.; Yang, R.T.

1995-12-01T23:59:59.000Z

335

Evaluation of gas reburning and low NO{sub x} burners on a wall-fired boiler  

SciTech Connect

An evaluation of Gas Reburning (GR) and Low NO{sub x}, Burners (LNB) has been completed at Public Service Company of Colorado`s Cherokee Station Unit 3. The goal of the demonstration, which was carried out in a US DOE Clean Coal Technology Round 3 Program, was to reduce NO{sub x} emissions by 70%. The reduction was to be achieved from the pre-project level, prior to LNB retrofit. The GR system was supplied by Energy and Environmental Research Corporation (EER) and the LNBs were supplied by the Foster Wheeler Energy Corporation. The project was carried out in three phases in which EER designed the GR system and obtained necessary permits (Phase 1), constructed the system and completed start-up tasks (Phase 2), and evaluated its performance with both Optimization Tests and a Long-Term Demonstration (Phase 3). As directed by the cooperative agreement, environmental monitoring was conducted in each phase. Measurements were taken by plant personnel and an EER Field Testing Team and were divided into two types. ``Compliance Monitoring`` was conducted by plant personnel to satisfy requirements of regulatory agencies, while ``Supplemental Monitoring`` was conducted by EER personnel to develop a database of environmental impacts of the technology and to ensure environmental acceptability of the project. This document presents environmental monitoring data obtained during the Long-Term Testing period, April 27, 1993 to January 27, 1995. During this period, ten months of testing of the GR-LNB system was followed by a modification into a ``second-generation`` GR-LNB system, which was evaluated for six months. Compliance Monitoring was conducted primarily in two areas, air emissions and aqueous discharges.

NONE

1995-06-01T23:59:59.000Z

336

Evaluation of gas reburning and low NO{sub x} burners on a wall-fired boiler  

SciTech Connect

An evaluation of Gas Reburning (GR) and Low NO{sub x} Burners (LNB) has been completed at Public Service Company of Colorado`s Cherokee Station Unit 3. The goal of the demonstration was to reduce NO{sub x} emissions by 70%. The reduction was to be achieved from the pre-project level prior to LNB retrofit. The GR system was supplied by Energy and Environmental Research Corporation (EER) and the LNBs were supplied by the Foster Wheeler Energy Corporation. The project was carried out in three phases in which EER designed the GR system and obtained necessary permits (Phase 1), constructed the system and completed start-up tasks (Phase 2), and evaluated its performance with both Optimization Tests and a Long-Term Demonstration (Phase 3). As directed by the Cooperative Agreement, environmental monitoring was conducted in each phase. Measurements were taken by plant personnel and an EER Field Testing Team and were divided into two types. ``Compliance Monitoring`` was conducted by plant personnel to satisfy requirements of regulatory agencies, while ``Supplemental Monitoring`` was conducted by EER personnel to develop a database of environmental impacts of the technology and to ensure environmental acceptability of the project. This document presents environmental monitoring data obtained during the Optimization Testing period, November 11, 1992 to April 23, 1993. Compliance Monitoring was conducted primarily in two areas, air emissions and aqueous discharges. The unit is required to meet an SO{sub 2} limit of 1.2 lb/MBtu and an opacity limit of 20 percent (6 minute average). Therefore, the plant monitors flue gas SO{sub 2} and opacity continuously and submits Excess Emissions Reports to the Colorado Air Pollution Control Division on a quarterly basis. Discharge limits for the aqueous effluent from the plant and monitoring requirements are specified by a permit issued by the Colorado Water Quality Control Division.

NONE

1995-06-01T23:59:59.000Z

337

Investigations of ash fouling with cattle wastes as reburn fuel in a small-scale boiler burner under transient conditions  

SciTech Connect

Fouling behavior under reburn conditions was investigated with cattle wastes (termed as feedlot biomass, FB) and coal as reburn fuels under a transient condition and short-time operation. A small-scale (30 kW or 100,000 Btu/hr) boiler burner research facility was used for the reburn experiments. The fuels considered for these experiments were natural gas (NG) for the ashless case, pure coal, pure FB, and blends of coal and FB. Two parameters that were used to characterize the ash 'fouling' were (1) the overall heat-transfer coefficient (OHTC) when burning NG and solid fuels as reburn fuels, and (2) the combustible loss through ash deposited on the surfaces of heat exchanger tubes and the bottom ash in the ash port. A new methodology is presented for determining ash fouling behavior under transient conditions. Results on the OHTCs for solid reburn fuels are compared with the OHTCs for NG. It was found that the growth of the layer of ash depositions over longer periods typically lowers OHTC, and the increased concentration of ash in gas phase promotes radiation in high-temperature zones during initial periods while decreasing the heat transfer in low-temperature zones. The ash analyses indicated that the bottom ash in the ash port contained a smaller percentage of combustibles with a higher FB percentage in the fuels, indicating better performance compared with coal because small particles in FB burn faster and the FB has higher volatile matter on a dry ash-free basis promoting more burn out. 16 refs., 12 figs., 6 tabs.

Hyukjin Oh; Kalyan Annamalai; John M. Sweeten [Texas A& amp; M University, College Station, TX (United States). Department of Mechanical Engineering

2008-04-15T23:59:59.000Z

338

Assessment of the Use of Nitrogen Trifluoride for Purifying Coolant and Heat Transfer Salts in the Fluoride Salt-Cooled High-Temperature Reactor  

SciTech Connect

This report provides an assessment of the use of nitrogen trifluoride for removing oxide and water-caused contaminants in the fluoride salts that will be used as coolants in a molten salt cooled reactor.

Scheele, Randall D.; Casella, Andrew M.

2010-09-28T23:59:59.000Z

339

Metal Oxides  

Science Journals Connector (OSTI)

Metal oxides are the class of materials having the widest application in gas sensors. This chapter presents information related to the application of various metal oxides in gas sensors designed on different p...

Ghenadii Korotcenkov

2013-01-01T23:59:59.000Z

340

Choose the best heat-recovery method for thermal oxidizers  

SciTech Connect

Thermal oxidation is current the most economically favorable add-on method of controlling hydrocarbon air emissions of moderate to low concentration (below 10,000 ppm). This concentration range covers emissions from a wide variety of chemical process industries (CPI) sources, including dryers, reactor vents, tank vents, and coaters. Thermal oxidizer systems consist of three basic sub-systems--burner, combustion chamber, and primary heat recovery. Selecting the type of primary heat recovery is probably the most important decision in the design of a thermal oxidizer, and requires consideration of a wide range of factors. The two most widely used types of primary heat recovery--recuperative and regenerative--each have distinct advantages and disadvantages. In general, recuperative oxidizers are simpler and less costly to purchase, whereas regenerative oxidizers offer substantially lower operating costs. Selecting between recuperative and regenerative heat recovery requires balancing a number of factors, such as capital and operating costs, exhaust gas composition and temperature, and secondary heat demand. This article provides guidance on when, where, and how to use each.

Klobucar, J.M.

1995-04-01T23:59:59.000Z

Note: This page contains sample records for the topic "nitrogen oxide burner" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Nitrogen-doped graphene as transparent counter electrode for efficient dye-sensitized solar cells  

SciTech Connect

Graphical abstract: Display Omitted Highlights: ? NG sheets are prepared through a hydrothermal reduction of graphite oxide. ? The transparent NG counter electrodes of DSCs are fabricated at room temperature. ? Transparent NG electrode exhibits excellent catalytic activity for the reduction of I{sub 3}{sup ?}. ? The DSC with NG electrode achieves a comparable efficiency to that of the Pt-based cell. ? The efficiency of rear illumination is about 85% that of front illumination. -- Abstract: Nitrogen-doped graphene sheets are prepared through a hydrothermal reduction of graphite oxide in the presence of ammonia and applied to fabricate the transparent counter electrode of dye-sensitized solar cells. The atomic percentage of nitrogen in doped graphene sample is about 2.5%, and the nitrogen bonds display pyridine and pyrrole-like configurations. Cyclic voltammetry studies demonstrate a much higher electrocatalytic activity toward I{sup ?}/I{sub 3}{sup ?} redox reaction for nitrogen-doped graphene, as compared with pristine graphene. The dye-sensitized solar cell with this transparent nitrogen-doped graphene counter electrode shows conversion efficiencies of 6.12% and 5.23% corresponding to front-side and rear-side illumination, respectively. Meanwhile, the cell with a Pt counter electrode shows a conversion efficiency of 6.97% under the same experimental condition. These promising results highlight the potential application of nitrogen-doped graphene in cost-effective, transparent dye-sensitized solar cells.

Wang, Guiqiang, E-mail: wgqiang123@163.com [School of Chemical Engineering, Shandong University of Technology, Zibo 255049 (China)] [School of Chemical Engineering, Shandong University of Technology, Zibo 255049 (China); Fang, Yanyan; Lin, Yuan [Institute of Chemistry, Chinese Academy of Science, Beijing 100080 (China)] [Institute of Chemistry, Chinese Academy of Science, Beijing 100080 (China); Xing, Wei; Zhuo, Shuping [School of Chemical Engineering, Shandong University of Technology, Zibo 255049 (China)] [School of Chemical Engineering, Shandong University of Technology, Zibo 255049 (China)

2012-12-15T23:59:59.000Z

342

Technology Innovations and Experience Curves for Nitrogen Oxides Control Technologies  

E-Print Network (OSTI)

air preheater interactions). SCR pro- cess improvements that1987; CS-5361s. 13. 13. SCR Projects Bid and Award Tracking;Catalytic Reduction (SCR) Control of NO x Emissions; SCR

Yeh, Sonia; Rubin, Edward S.; Taylor, Margaret R.

2007-01-01T23:59:59.000Z

343

Persistent sensitivity of Asian aerosol to emissions of nitrogen oxides  

E-Print Network (OSTI)

We use a chemical transport model and its adjoint to examine the sensitivity of secondary inorganic aerosol formation to emissions of precursor trace gases from Asia. Sensitivity simulations indicate that secondary inorganic ...

Kharol, S. K.

344

EFFECT OF NITROGEN OXIDE PRETREATMENTS ON ENZYMATIC HYDROLYSIS OF CELLULOSE  

E-Print Network (OSTI)

Bioconversion of Cellulose and Production of Ethanol," LBL-of Cellulose and the Production of Ethanol," LBL-6859,the cellulose is a major obstacle to hydrolysis. Ethanol The

Borrevik, R.K.

2011-01-01T23:59:59.000Z

345

EFFECT OF NITROGEN OXIDE PRETREATMENTS ON ENZYMATIC HYDROLYSIS OF CELLULOSE  

E-Print Network (OSTI)

Jerusalem, loR. Parkinson, Tappi, Meller, Holzforschung,L.L. Schaleger and D.L. Brink, Tappi, No.4, 65 ( 1978). N.I.Holocellulose in Wood," Tappi Standard T9 m-54. C.R.

Borrevik, R.K.

2011-01-01T23:59:59.000Z

346

Characterization of vanadate-dependent NADH oxidation stimulated by Saccharomyces cerevisiae plasma membranes.  

Science Journals Connector (OSTI)

...oxidation activity of yeast plasma membranes for molecular DH...vanadate-dependent nonenzymatic and plasma mem- DH. Each point is brane-stimulated...aFor nonenzymatic nitrogen atmosphere, but NADH oxidation resumed...consumption of oxygen during Plasma membrane- the oxidation of...

L A Minasi; G R Willsky

1991-01-01T23:59:59.000Z

347

Achieving New Source Performance Standards (NSPS) Emission Standards Through Integration of Low-NOx Burners with an Optimization Plan for Boiler Combustion  

SciTech Connect

The objective of this project was to demonstrate the use of an Integrated Combustion Optimization System to achieve NO{sub X} emission levels in the range of 0.15 to 0.22 lb/MMBtu while simultaneously enabling increased power output. The project plan consisted of the integration of low-NO{sub X} burners and advanced overfire air technology with various process measurement and control devices on the Holcomb Station Unit 1 boiler. The plan included the use of sophisticated neural networks or other artificial intelligence technologies and complex software to optimize several operating parameters, including NO{sub X} emissions, boiler efficiency, and CO emissions. The program was set up in three phases. In Phase I, the boiler was equipped with sensors that can be used to monitor furnace conditions and coal flow to permit improvements in boiler operation. In Phase II, the boiler was equipped with burner modifications designed to reduce NO{sub X} emissions and automated coal flow dampers to permit on-line fuel balancing. In Phase III, the boiler was to be equipped with an overfire air system to permit deep reductions in NO{sub X} emissions. Integration of the overfire air system with the improvements made in Phases I and II would permit optimization of boiler performance, output, and emissions. This report summarizes the overall results from Phases I and II of the project. A significant amount of data was collected from the combustion sensors, coal flow monitoring equipment, and other existing boiler instrumentation to monitor performance of the burner modifications and the coal flow balancing equipment.

Wayne Penrod

2006-12-31T23:59:59.000Z

348

Kinetics and mechanisms of interactions of nitrogen and carbon monoxide with liquid niobium  

SciTech Connect

The kinetics and mechanisms of interactions of N{sub 2} and CO with liquid niobium were investigated in the temperature range of 2,700 to 3,000 K in samples levitated in N{sub 2}/Ar and CO/Ar streams. The nitrogen absorption and desorption processes were found to be second-order with respect to nitrogen concentration, indicating that the rate controlling step is either the adsorption of nitrogen molecules on the liquid surface or dissociation of absorbed nitrogen molecules into adsorbed atoms. The carbon and oxygen dissolution in liquid niobium from CO gas is an exothermic process and the solubilities of carbon and oxygen (C{sub Ce}, C{sub Oe} in at%) are related to the temperature and the partial pressure of CO. The reaction CO {yields} (C) + (O) along with the evaporation of niobium oxide takes place during C and O dissolution, whereas C and O desorption occurs via CO evolution only.

Park, H.G.

1990-01-01T23:59:59.000Z

349

Tr5-cover.jpg:Corel PHOTO-PAINT  

NLE Websites -- All DOE Office Websites (Extended Search)

5 5 SEPTEMBER 1996 Reducing Emissions of Nitrogen Oxides via Low-NO X Burner Technologies A report on projects conducted jointly under cooperative agreements between: The U.S. Department of Energy and * The Babcock & Wilcox Company * Southern Company Services, Inc. * Public Service Company of Colorado Reducing Emissions of Nitrogen Oxides via Low-NO X Burner Technologies Cover image: Inside a wall-fired boiler. Introduction and Executive Summary ......................................................................... 1 Background ................................................................................................................ 2 NO X Control Technologies ......................................................................................... 2 NO X Regulations under the Clean Air Act Amendments of 1990 ..............................

350

Stanford Nitrogen Group | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Stanford Nitrogen Group Stanford Nitrogen Group National Clean Energy Business Plan Competition Stanford Nitrogen Group Stanford University The Stanford Nitrogen Group developed a new wastewater treatment process for the removal and recovery of energy from waste nitrogen (i.e. ammonia). This process improves the efficiency and lowers the cost of nitrogen treatment. The process is termed the Coupled Aerobic-anoxic Nitrous Decomposition Operation (CANDO) and consists of 2 principal steps: biological conversion of ammonia to N2O gas, and combustion of a fuel (i.e. biogas) with N2O to recover energy. It's the first wastewater treatment process to recover energy from nitrogen. Wastewater treatment facilities experience dual financial pressures - rising energy costs and meeting increasingly stringent nitrogen discharge

351

Stanford Nitrogen Group | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Stanford Nitrogen Group Stanford Nitrogen Group National Clean Energy Business Plan Competition Stanford Nitrogen Group Stanford University The Stanford Nitrogen Group developed a new wastewater treatment process for the removal and recovery of energy from waste nitrogen (i.e. ammonia). This process improves the efficiency and lowers the cost of nitrogen treatment. The process is termed the Coupled Aerobic-anoxic Nitrous Decomposition Operation (CANDO) and consists of 2 principal steps: biological conversion of ammonia to N2O gas, and combustion of a fuel (i.e. biogas) with N2O to recover energy. It's the first wastewater treatment process to recover energy from nitrogen. Wastewater treatment facilities experience dual financial pressures - rising energy costs and meeting increasingly stringent nitrogen discharge

352

IN THIS ISSUE Nitrogen on Cotton . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2  

E-Print Network (OSTI)

AGRONOMY NOTES July 2005 IN THIS ISSUE COTTON Nitrogen on Cotton . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2 Protecting Cotton Squares and Blooms / University of Florida / Larry Arrington, Interim Dean. #12;2 Nitrogen on Cotton Now is the time to apply N

Watson, Craig A.

353

Identifying the Active Site in Nitrogen-Doped Graphene for the VO2+/VO2+ Redox Reaction  

Science Journals Connector (OSTI)

Nitrogen-doped graphene sheets (NGS), synthesized by annealing graphite oxide (GO) with urea at 700–1050 °C, were studied as positive electrodes in a vanadium redox flow battery. ... graphene sheets; nitrogen doping; [VO]2+/[VO2]+ couple reaction; redox flow battery ... (7) Among these energy storage technologies, the vanadium redox flow battery (VRFB) has been considered as a competitive and promising grid energy storage system for renewable energy due to its low cost, high efficiency, and good cycling stability. ...

Jutao Jin; Xiaogang Fu; Qiao Liu; Yanru Liu; Zhiyang Wei; Kexing Niu; Junyan Zhang

2013-05-06T23:59:59.000Z

354

Impacts of Atmospheric Anthropogenic Nitrogen on the  

E-Print Network (OSTI)

anthropogenic carbon dioxide may result from this atmospheric nitrogen fertilization, leading to a decreaseImpacts of Atmospheric Anthropogenic Nitrogen on the Open Ocean R. A. Duce,1 * J. LaRoche,2 K quantities of atmospheric anthropogenic fixed nitrogen entering the open ocean could account for up to about

Ward, Bess

355

Frostbite Theater - Liquid Nitrogen Experiments - Liquid Nitrogen Show!  

NLE Websites -- All DOE Office Websites (Extended Search)

Insulators! Insulators! Previous Video (Insulators!) Frostbite Theater Main Index Next Video (Superconductors!) Superconductors! Liquid Nitrogen Show! All of your favorite liquid nitrogen experiments all in one place! Flowers! Balloons! Racquetballs! Nothing is safe! Just sit back, relax, and enjoy the show! [ Show Transcript ] Announcer: Frostbite Theater presents... Cold Cuts! No baloney! Joanna and Steve: Just science! Joanna: Hi! I'm Joanna! Steve: And I'm Steve! Joanna: Usually, every couple years, Jefferson Lab hosts an Open House. This is the one time the public and come and tour our accelerator and end stations. Steve: During the 2010 Open House, our cameraman snuck into one of the ongoing cryo shows that are held throughout the day. He missed half of it. So if you want to see the entire thing, check our website to see when the

356

MATE (Materials for Advanced Turbine Engines) Program, Project 3. Volume 2: Design, fabrication and evaluation of an oxide dispersion strengthened sheet alloy combustor liner. Final report  

SciTech Connect

The suitability of wrought oxide dispersion strengthened (ODS) superalloy sheet for gas turbine engine combustor applications was evaluated. Two yttria (Y2O3) dispersion strengthened alloys were evaluated; Incoloy MA956 and Haynes Development Alloy (HDA) 8077 (NiCrAl base). Preliminary tests showed both alloys to be potentially viable combustor materials, with neither alloy exhibiting a significant advantage over the other. MA956 was selected as the final alloy based on manufacturing reproducibility for evaluation as a burner liner. A hybrid PW2037 inner burner liner containing MA956 and Hastelloy X components and using a louvered configuration was designed and constructed. The louvered configuration was chosen because of field experience and compatibility with the bill of material PW2037 design. The simulated flight cycle for the ground based engine tests consisted of 4.5 min idle, 1.5 min takeoff and intermediate conditions in a PW2037 engine with average uncorrected combustor exit temperature of 1527 C. Post test evaluation consisting of visual observations and fluorescent penetrant inspections was conducted after 500 cycles of testing. No loss of integrity in the burner liner was shown.

Bose, S.; Sheffler, K.D.

1988-02-01T23:59:59.000Z

357

Sensor for Individual Burner Control of Coal Firing Rate, Fuel-Air Ratio and Coal Fineness Correlation  

SciTech Connect

Accurate, cost-efficient monitoring instrumentation has long been considered essential to the operation of power plants. Nonetheless, for the monitoring of coal flow, such instrumentation has been sorely lacking and technically difficult to achieve. With more than half of the electrical power in the United States currently supplied by coal, energy generated by this resource is critical to the US economy. The demand for improvement in this area has only increased as a result of the following two situations: First, deregulation has produced a heightened demand for both reduced electrical cost and improved grid connectivity. Second, environmental concerns have simultaneously resulted in a need for both increased efficiency and reduced carbon and NOx emissions. A potential approach to addressing both these needs would be improvement in the area of combustion control. This would result in a better heat rate, reduced unburned carbon in ash, and reduced NOx emissions. However, before feedback control can be implemented, the ability to monitor coal flow to the burners in real-time must be established. While there are several ''commercially available'' products for real-time coal flow measurement, power plant personnel are highly skeptical about the accuracy and longevity of these systems in their current state of development. In fact, following several demonstration projects of in-situ coal flow measurement systems in full scale utility boilers, it became obvious that there were still many unknown influences on these instruments during field applications. Due to the operational environment of the power plant, it has been difficult if not impossible to sort out what parameters could be influencing the various probe technologies. Additionally, it has been recognized for some time that little is known regarding the performance of coal flow splitters, even where rifflers are employed. Often the coal flow distribution from these splitters remains mal-distributed. There have been mixed results in the field using variable orifices in coal pipes. Development of other coal flow control devices has been limited. An underlying difficulty that, to date, has hindered the development of an accurate instrument for coal flow measurements is the fact that coal flow is characterized by irregular temporal and spatial variation. However, despite the inherent complexity of the dynamic system, the system is in fact deterministic. Therefore, in principle, the coal flow can be deduced from the dynamics it exhibits. Nonetheless, the interactions are highly nonlinear, rendering standard signal processing approaches, which rely on techniques such as frequency decomposition, to be of little value. Foster-Miller, Inc. has developed a methodology that relates the complex variation in such systems to the information of interest. This technology will be described in detail in Section 2. A second concern regarding the current measurement systems is installation, which can be labor-intensive and cost-prohibitive. A process that does not require the pulverizer to be taken off line would be highly desirable. Most microwave and electrostatic methods require drilling up to 20 holes in the pipe, all with a high degree of precision so as to produce a proper alignment of the probes. At least one electrostatic method requires a special spool piece to be fitted into each existing coal pipe. Overall, these procedures are both difficult and very expensive. An alternative approach is pursued here, namely the development of an instrument that relies on an acoustic signal captured by way of a commercial accelerometer. The installation of this type of sensor is both simpler and less invasive than other techniques. An accelerometer installed in a pipe wall need not penetrate through the wall, which means that the system may be able to remain on line during the installation. Further, due to the fact that the Dynamical Instruments technology, unlike other systems, does not rely on uniformity of the air or coal profile, the installation location need not be on a long, straight run

R. Demler

2006-04-01T23:59:59.000Z

358

Applicability of RELAP5-3D for Thermal-Hydraulic Analyses of a Sodium-Cooled Actinide Burner Test Reactor  

SciTech Connect

The Actinide Burner Test Reactor (ABTR) is envisioned as a sodium-cooled, fast reactor that will burn the actinides generated in light water reactors to reduce nuclear waste and ease proliferation concerns. The RELAP5-3D computer code is being considered as the thermal-hydraulic system code to support the development of the ABTR. An evaluation was performed to determine the applicability of RELAP5-3D for the analysis of a sodium-cooled fast reactor. The applicability evaluation consisted of several steps, including identifying the important transients and phenomena expected in the ABTR, identifying the models and correlations that affect the code’s calculation of the important phenomena, and evaluating the applicability of the important models and correlations for calculating the important phenomena expected in the ABTR. The applicability evaluation identified code improvements and additional models needed to simulate the ABTR. The accuracy of the calculated thermodynamic and transport properties for sodium was also evaluated.

C. B. Davis

2006-07-01T23:59:59.000Z

359

Evaluation of gas-reburning and low NO{sub x} burners on a wall fired boiler. Technical progress report number 17, October 1--December 31, 1994  

SciTech Connect

The primary objective of this CCT project is to evaluate the use of Gas Reburning and Low NO{sub x} Burners (GR-LNB) for NO{sub x} emission control from a wall fired boiler. Low NO{sub x} burners are designed to delay the mixing of the coal fuel with combustion air to minimize the NO{sub x} formation. With GR, about 80--85% of the coal fuel is fired in the main combustion zone. The balance of the fuel is added downstream as natural gas to create a slightly fuel rich environment in which NO{sub x} is converted to N{sub 2}. The combustion process is completed by over fire air addition. SO{sub x} emissions are reduced to the extent that natural gas replaces sulfur-containing coal. The level of NO{sub x} reduction achievable with 15--20% natural gas is on the order of 50--60%. Thus the emission reduction target of the combination of these two developed technologies is about 70%. This project is being conducted in three phases at the host site, a 172 MW wall fired boiler of Public Service Company of Colorado (PSCo), Cherokee Unit 3 in Denver, Colorado: Phase 1--Design and Permitting; Phase 2--Construction and Start-up; and Phase 3--Operation, Data Collection, Reporting and Disposition. Phase 3 activities during this reporting period involved initiation of the second generation gas reburning parametric testing. This technology utilizes enhanced natural gas and overfire air injectors with elimination of the flue gas recirculation system. The objective is to demonstrate NO{sub x} reductions similar to that of long term testing but with a reduced capital cost requirement through elimination of the FGR system.

NONE

1994-12-13T23:59:59.000Z

360

Stanford Nitrogen Group | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Science & Innovation » Innovation » Commercialization » National Science & Innovation » Innovation » Commercialization » National Clean Energy Business Plan Competition » Stanford Nitrogen Group National Clean Energy Business Plan Competition Stanford Nitrogen Group Stanford University The Stanford Nitrogen Group developed a new wastewater treatment process for the removal and recovery of energy from waste nitrogen (i.e. ammonia). This process improves the efficiency and lowers the cost of nitrogen treatment. The process is termed the Coupled Aerobic-anoxic Nitrous Decomposition Operation (CANDO) and consists of 2 principal steps: biological conversion of ammonia to N2O gas, and combustion of a fuel (i.e. biogas) with N2O to recover energy. It's the first wastewater treatment process to recover energy from nitrogen.

Note: This page contains sample records for the topic "nitrogen oxide burner" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Nitrogen fixation method and apparatus  

DOE Patents (OSTI)

A method and apparatus for achieving nitrogen fixation includes a volumetric electric discharge chamber. The volumetric discharge chamber provides an even distribution of an electron beam, and enables the chamber to be maintained at a controlled energy to pressure (E/p) ratio. An E/p ratio of from 5 to 15 kV/atm of O[sub 2]/cm promotes the formation of vibrationally excited N[sub 2]. Atomic oxygen interacts with vibrationally excited N[sub 2] at a much quicker rate than unexcited N[sub 2], greatly improving the rate at which NO is formed. 1 fig.

Chen, H.L.

1983-08-16T23:59:59.000Z

362

Environmental biogeochemistry. V. 1: Carbon, nitrogen, phosphorus ...  

Science Journals Connector (OSTI)

V. 1: Carbon, nitrogen, phosphorus, sulfur and selenium cycles. V. 2: Metals transfer and ecological mass balances. Ann Arbor Sci. Publ., Inc., Ann. Arbor, Mich.

2000-01-06T23:59:59.000Z

363

Nitrogen Deposition in the Southern High Plains  

E-Print Network (OSTI)

Nitrogen Deposition in the Southern High Plains Nitrogen is necessary for life on earth, but getting too much of it can be harmful. Recent research in delicate alpine watersheds of the western United States has suggested that the amount... Nitrogen Deposition in the Southern High Plains Conservation of mass: It?s not just a good idea, it?s the law Nitrogen, along with every other element in nature, obeys certain physical laws. The first of those laws, the law of conservation of mass...

Upadhyay, Jeetendra; Auvermann, Brent W.; Bush, K. Jack; Mukhtar, Saqib

2008-02-11T23:59:59.000Z

364

The Abundance of Interstellar Nitrogen  

E-Print Network (OSTI)

Using the HST Goddard High Resolution Spectrograph (GHRS), we have obtained high S/N echelle observations of the weak interstellar N I 1160, 1161 A absorption doublet toward the stars Gamma Cas, Lambda Ori, Iota Ori, Kappa Ori, Delta Sco, and Kappa Sco. In combination with a previous GHRS measurement of N I toward Zeta Oph, these new observations yield a mean interstellar gas phase nitrogen abundance (per 10$^6$ H atoms) of 10$^6$ N/H = 75 +/- 4. There are no statistically significant variations in the measured N abundances from sightline to sightline and no evidence of density-dependent depletion from the gas-phase. Since N is not expected to be depleted much into dust grains in these diffuse sightlines, its gas-phase abundance should reflect the total interstellar abundance. Consequently, the GHRS observations imply that the abundance of interstellar nitrogen (gas plus grains) in the local Milky Way is about 80% of the solar system value of 10$^6$ N/H = 93 +/- 16. Although this interstellar abundance deficit is somewhat less than that recently found for oxygen and krypton with GHRS, the solar N abundance and the N I oscillator strengths are too uncertain to definitively rule out either a solar ISM N abundance or a 2/3 solar ISM N abundance similar to that of O and Kr.

David M. Meyer; Jason A. Cardelli; Ulysses J. Sofia

1997-10-15T23:59:59.000Z

365

Mechanisms of plant species impacts on ecosystem nitrogen cycling  

E-Print Network (OSTI)

, this microbial nitrogen loop is driven by plant-supplied carbon and provides a strong negative feedback through by an increase in the relative nitrogen content in decomposing litter and a much lower carbon-to-nitrogen ratio by a microbial nitrogen loop. Nitrogen is released from the soil organic matter and incorporated into microbial

Minnesota, University of

366

Using carbon adsorbents for removing nitrogen oxides and sulphur oxides from flue gases  

Science Journals Connector (OSTI)

The use of carbon adsorbents in industrial power engineering outside Russia is briefly reviewed and the results of our own experimental investigations, made in the laboratory and at a pilot commercial installation, are given. The proposal to use the described device in a KE-25-24-C industrial boiler is outlined.

A.I. Blokhin; A.N. Nikitin; A.O. Gabibov

2003-01-01T23:59:59.000Z

367

Ab initio atomistic thermodynamics study of the early stages of Cu(100) oxidation  

E-Print Network (OSTI)

­3 catalytic conversion of nitrogen oxides,4 water-gas shift,5,6 and preventing CO poisoning in fuel cells.7 the nucleation limit of Cu2O, they are likely to exist due to kinetic hindrance. 1 #12;I. INTRODUCTION Oxidation

McGaughey, Alan

368

Nutrient Management Module No. 3 Nitrogen Cycling,  

E-Print Network (OSTI)

, it is important to first understand the various transformations that N undergoes within the soil. Nitrogen Cycling to be the sum of ammonium and nitrate, although urea, a type of organic N, may also be plant available. Nitrogen a fraction) by dry yield (in lb/ac). It's useful to compare actual uptake rates to N fertilizer rates

Lawrence, Rick L.

369

NITROGEN ISOTOPES IN PALEOCLIMATE JULIAN P. SACHS  

E-Print Network (OSTI)

denitrification, the conversion of nitrate to N2 gas with its subsequent loss to the atmosphere (25-180 Tg N of atmospheric carbon dioxide, and is the precursor to petroleum deposits it is important to understand nitrogen of nitrogen is atmospheric dinitrogen gas (N2), consisting of 3.9 x 109 Tg N (Wada and Hattori, 1990

Sachs, Julian P.

370

Oxygen and Nitrogen Contamination During Arc Welding  

E-Print Network (OSTI)

) ) : ,- Oxygen and Nitrogen Contamination During Arc Welding T. W. Eagar Department of }faterials, mechanisms, and expected levels of oxygen and nitrogen contamination during gas tungsten arc, gas metal arc indicating the importance of dec9mposition of SiOz into silicon monoxide and oxygen are presented, indicating

Eagar, Thomas W.

371

Anaerobic Ammonium-Oxidizing Bacteria: Unique Microorganisms with Exceptional Properties  

Science Journals Connector (OSTI)

...membrane to the outer membrane to drive a number of outer membrane receptors...nitrate reduction to dinitrogen gas via nitrite and ammonium. Environ...ammonium-oxidizing bacteria. ASM News 67 :456-463. 49. Kuypers...associated with global nitrogen gas production. Environ. Microbiol...

Laura van Niftrik; Mike S. M. Jetten

2012-09-01T23:59:59.000Z

372

Frostbite Theater - Liquid Nitrogen Experiments - Insulators!  

NLE Websites -- All DOE Office Websites (Extended Search)

Popping Film Canisters! Popping Film Canisters! Previous Video (Popping Film Canisters!) Frostbite Theater Main Index Next Video (Liquid Nitrogen Show!) Liquid Nitrogen Show! Insulators! Cups full of water are placed into bowls of liquid nitrogen! Which cup will insulate the best? [ Show Transcript ] Announcer: Frostbite Theater presents... Cold Cuts! No baloney! Joanna and Steve: Just science! Joanna: Hi! I'm Joanna! Steve: And I'm Steve! Joanna: And this is a container of liquid nitrogen! Steve: And these are two plastic cups! Joanna: Let's see which cup is the better insulator! Steve: Okay! So, um, how do we do that? Joanna: Well, we'll pour water into each of the cups and then we'll pour the liquid nitrogen into each of the bowls. If we then place the cup in the bowl, the heat from the water will try to pass through the cup into the

373

Frostbite Theater - Liquid Nitrogen Experiments - Freezing Balloons!  

NLE Websites -- All DOE Office Websites (Extended Search)

Season Two Bloopers Season Two Bloopers Previous Video (Season Two Bloopers) Frostbite Theater Main Index Next Video (Instant Liquid Nitrogen Balloon Party!) Instant Liquid Nitrogen Balloon Party! Freezing Balloons! What happens when a balloon full of air is plunged into a container full of liquid nitrogen? Play the video to find out! [ Show Transcript ] Announcer: Frostbite Theater presents... Cold Cuts! No baloney! Joanna and Steve: Just science! Joanna: Hi! I'm Joanna! Steve: And I'm Steve! Joanna: And this is a container of liquid nitrogen! Steve: And this is a really big balloon! Joanna: Let's see what happens when we place the balloon in the liquid nitrogen! Steve: Okay! Wait! Wait! Wait! Wait! Wait! Isn't the balloon going to pop? Joanna: We'll see! Steve: Aw, man... Huh. Okay, so the balloon didn't pop. But, there's

374

INSENSITIVE HIGH-NITROGEN COMPOUNDS  

SciTech Connect

The conventional approach to developing energetic molecules is to chemically place one or more nitro groups onto a carbon skeleton, which is why the term ''nitration'' is synonymous to explosives preparation. The nitro group carries the oxygen that reacts with the skeletal carbon and hydrogen fuels, which in turn produces the heat and gaseous reaction products necessary for driving an explosive shock. These nitro-containing energetic molecules typically have heats of formation near zero and therefore most of the released energy is derived from the combustion process. Our investigation of the tetrazine, furazan and tetrazole ring systems has offered a different approach to explosives development, where a significant amount of the chemical potential energy is derived from their large positive heats of formation. Because these compounds often contain a large percentage of nitrogen atoms, they are usually regarded as high-nitrogen fuels or explosives. A general artifact of these high-nitrogen compounds is that they are less sensitive to initiation (e.g. by impact) when compared to traditional nitro-containing explosives of similar performances. Using the precursor, 3,6-bis-(3,5-dimethylpyrazol-1-yl)-s-tetrazine, several useful energetic compounds based on the s-tetrazine system have been synthesized and studied. Some of the first compounds are 3,6-diamino-s-tetrazine-1,4-dioxide (LAX-112) and 3,6-dihydrazino-s-tetrazine (DHT). LAX-112 was once extensively studied as an insensitive explosive by Los Alamos; DHT is an example of a high-nitrogen explosive that relies entirely on its heat of formation for sustaining a detonation. Recent synthesis efforts have yielded an azo-s-tetrazine, 3,3'-azobis(6-amino-s-tetrazine) or DAAT, which has a very high positive heat of formation. The compounds, 4,4'-diamino-3,3'-azoxyfurazan (DAAF) and 4,4'-diamino-3,3'-azofurazan (DAAzF), may have important future roles in insensitive explosive applications. Neither DAAF nor DAAzF can be initiated by laboratory impact drop tests, yet both have in some aspects better explosive performances than 1,3,5-triamino-2,4,6-trinitrobenzene TATB--the standard of insensitive high explosives. The thermal stability of DAAzF is equal to that of hexanitrostilbene (HNS), yet it too is a better explosive performer. The recently discovered tetrazol derivative, 3,6-bis-(1H-1,2,3,4-tetrazol-5-ylamino)-s-tetrazine (BTATz) was measured to have exceptional positive heats of formation and to be insensitive to explosive initiation. Because of its high burn rate with low sensitivity to pressure, this material is of great interest to the propellant community.

D. CHAVEZ; ET AL

2001-03-01T23:59:59.000Z

375

Nitrogen Fixation and Dentrification in Sediments of Eutrophic Mediterranean-Type Estuaries: Seasonal Patterns and Responses to Anthropogenic Nitrogen Inputs  

E-Print Network (OSTI)

and mechanisms controlling sediment nitrogen fixation in aKane T & Fong P. 2007. Sediment nitrogen fixation in UpperKane T & Fong P. 2007. Sediment nitrogen fixation in Upper

Kane, Tonya Lynn

2012-01-01T23:59:59.000Z

376

Nitrogen-doped Graphene and Its Electrochemical Applications...  

NLE Websites -- All DOE Office Websites (Extended Search)

doped Graphene and Its Electrochemical Applications. Nitrogen-doped Graphene and Its Electrochemical Applications. Abstract: Nitrogen-doped graphene (N-graphene) is obtained by...

377

Nitrogen Control in Electric Arc Furnace Steelmaking by Direct...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Nitrogen Control in Electric Arc Furnace Steelmaking by Direct Reduced Iron Fines Injection Nitrogen Control in Electric Arc Furnace Steelmaking by Direct Reduced Iron Fines...

378

Oxidation of Propane by Doped Nickel Oxides  

Science Journals Connector (OSTI)

... present study, however, indicate that in the absence of excess oxygen, direct oxidation of propane by the oxide lattice can occur.

D. W. McKEE

1964-04-11T23:59:59.000Z

379

Dissociation and excitation coefficients of nitrogen molecules and nitrogen monoxide generation  

SciTech Connect

The excitation coefficient ?{sub N2} is calculated for the excited metastable level of N{sub 2}(A{sub 3}?{sub u}{sup +}) in nitrogen molecules. In addition, the dissociation coefficient of nitrogen molecules is investigated by making use of the Boltzmann distribution of the electrons in atmospheric plasmas. The excitation and electron-impact dissociation coefficients of nitrogen molecules are analytically expressed in terms of the electron temperature T{sub e} for evaluations of the reactive oxygen and nitrogen species in atmospheric plasmas. As an application example of these coefficients, the nitrogen monoxide generation through a microwave torch is carried out for a development of medical tool. The nitrogen monoxide concentration from a microwave plasma-torch can be easily controlled by the nitrogen flow rate, mole fraction of the oxygen gas, and the microwave power. A simple analytic expression of the nitrogen monoxide concentration is obtained in terms of the oxygen molecular density and gas flow rate. The experimental data agree remarkably well with the theoretical results from the analytical expression. A microwave nitrogen-torch can easily provide an appropriate nitrogen monoxide concentration for the wound healings.

Uhm, Han S.; Na, Young H.; Choi, Eun H.; Cho, Guangsup [Department of Electronic and Biological Physics, Kwangwoon University 447-1 Wolgye-Dong, Nowon-Gu, Seoul 137-701 (Korea, Republic of)] [Department of Electronic and Biological Physics, Kwangwoon University 447-1 Wolgye-Dong, Nowon-Gu, Seoul 137-701 (Korea, Republic of)

2013-08-15T23:59:59.000Z

380

Reference electrode for strong oxidizing acid solutions  

DOE Patents (OSTI)

A reference electrode for the measurement of the oxidation-reduction potentials of solutions is especially suitable for oxidizing solutions such as highly concentrated and fuming nitric acids, the solutions of nitrogen oxides, N.sub.2 O.sub.4 and N.sub.2 O.sub.5, in nitric acids. The reference electrode is fabricated of entirely inert materials, has a half cell of Pt/Ce(IV)/Ce(III)/70 wt. % HNO.sub.3, and includes a double-junction design with an intermediate solution of 70 wt. % HNO.sub.3. The liquid junctions are made from Corning No. 7930 glass for low resistance and negligible solution leakage.

Rigdon, Lester P. (Livermore, CA); Harrar, Jackson E. (Castro Valley, CA); Bullock, Sr., Jack C. (Pleasanton, CA); McGuire, Raymond R. (Brentwood, CA)

1990-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "nitrogen oxide burner" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Evaluation of gas-reburning and low NO{sub x} burners on a wall fired boiler. Progress report, January 1--March 31, 1996  

SciTech Connect

The primary objective of this Clean Coal Technology project is to evaluate the use of Gas Reburning and Low NO{sub x} Burners (GR-LNB) for NO{sub x} emission control from a wall fired boiler. This project is being conducted in three phases at the host site, a 172 MW{sub e} wall fired boiler of Public Service Company of Colorado, Cherokee Unit 3 in Denver, Colorado: Phase I, design and permitting has been completed on June 30, 1992; Phase II, construction and start-up has been completed on September 1991; and Phase III, operation, data collection, reporting and disposition. Phase III activities during this reporting period involved the following: compilation, analysis and assembly of the final report and initiation of restoration activities; restoration of the gas reburning system involving removal of the flue gas recirculation system (permanent Second Generation Gas Reburning); and participants meeting and reburning workshop. Long term testing of the equipment demonstrated an average NO{sub x} reduction of 65% using 18% gas heat input. After removing the flue gas recirculation system, (Second Generation GR), an average NO{sub x} of 64% was achieved using 13% gas heat input. The project goal of 70% reduction was achieved, but no on an average basis due to the load requirements of the utility.

NONE

1996-04-15T23:59:59.000Z

382

Economic Removal of Nitrogen from LNG  

Science Journals Connector (OSTI)

In recent years, economic factors have made transportation of natural gas in the form of LNG increasingly attractive. Shipping costs and heating value ... control necessitate specifications limiting the nitrogen ...

J-P. G. Jacks; J. C. McMillan

1978-01-01T23:59:59.000Z

383

Nitrogen fixation by a methanogenic archaebacterium  

Science Journals Connector (OSTI)

... fixing microbial systems able to convert wastes which are low in combined nitrogen, including lignocellulose biomass substrates, industrial wastes and food process wastes such as ... substrates, industrial wastes and food process wastes such as whey, to CH4.

Patti A. Murray; Stephen H. Zinder

1984-11-15T23:59:59.000Z

384

NATURAL GAS VARIABILITY IN CALIFORNIA: ENVIRONMENTAL IMPACTS AND DEVICE PERFORMANCE EXPERIMENTAL EVALUATION OF POLLUTANT EMISSIONS FROM RESIDENTIAL APPLIANCES  

SciTech Connect

The effect of liquefied natural gas on pollutant emissions was evaluated experimentally with used and new appliances in the laboratory and with appliances installed in residences, targeting information gaps from previous studies. Burner selection targeted available technologies that are projected to comprise the majority of installed appliances over the next decade. Experiments were conducted on 13 cooktop sets, 12 ovens, 5 broiler burners, 5 storage water heaters, 4 forced air furnaces, 1 wall furnace, and 6 tankless water heaters. Air-free concentrations and fuel-based emission factors were determined for carbon monoxide, nitrogen oxides, nitrogen dioxide, and the number of (predominantly ultrafine) particles over complete burns?including transient effects (device warm-up and intermittent firing of burners) following ignition--and during more stable end-of-burn conditions. Formaldehyde was measured over multi-burn cycles. The baseline fuel was Northern California line gas with Wobbe number (a measure of fuel energy delivery rate) of 1320-1340; test fuels had Wobbe numbers of roughly 1390 and 1420, and in some cases 1360. No ignition or operational problems were observed during test fuel use. Baseline emissions varied widely across and within burner groups and with burner operational mode. Statistically significant emissions changes were observed for some pollutants on some burners.

Singer, Brett C.; Apte, Michael G.; Black, Douglas R.; Hotchi, Toshifumi; Lucas, Donald; Lunden, Melissa M.; Mirer, Anna G.; Spears, Michael; Sullivan, Douglas P.

2009-12-01T23:59:59.000Z

385

Nitrogen Removal From Low Quality Natural Gas  

SciTech Connect

Natural gas provides more than one-fifth of all the primary energy used in the United States. It is especially important in the residential sector, where it supplies nearly half of all the energy consumed in U.S. homes. However, significant quantities of natural gas cannot be produced economically because its quality is too low to enter the pipeline transportation system without some type of processing, other than dehydration, to remove the undesired gas fraction. Such low-quality natural gas (LQNG) contains significant concentration or quantities of gas other than methane. These non- hydrocarbons are predominantly nitrogen, carbon dioxide, and hydrogen sulfide, but may also include other gaseous components. The nitrogen concentrations usually exceeds 4%. Nitrogen rejection is presently an expensive operation which can present uneconomic scenarios in the potential development of natural gas fields containing high nitrogen concentrations. The most reliable and widely used process for nitrogen rejection from natural gas consists of liquefying the feed stream using temperatures in the order of - 300{degrees}F and separating the nitrogen via fractionation. In order to reduce the gas temperature to this level, the gas is compressed, cooled by mullet-stream heat exchangers, and expanded to low pressure. Significant energy for compression and expensive materials of construction are required. Water and carbon dioxide concentrations must be reduced to levels required to prevent freezing. SRI`s proposed research involves screening new nitrogen selective absorbents and developing a more cost effective nitrogen removal process from natural gas using those compounds. The long-term objective of this project is to determine the technical and economical feasibility of a N{sub 2}2 removal concept based on complexation of molecular N{sub 2} with novel complexing agents. Successful development of a selective, reversible, and stable reagent with an appropriate combination of capacity and N{sub 2} absorption/desorption characteristics will allow selective separation of N{sub 2} from LQNG.

Alvarado, D.B.; Asaro, M.F.; Bomben, J.L.; Damle, A.S.; Bhown, A.S.

1997-10-01T23:59:59.000Z

386

Microfluidic Facility, Harvard Medical School LIQUID NITROGEN TANK HANDLING  

E-Print Network (OSTI)

Microfluidic Facility, Harvard Medical School LIQUID NITROGEN TANK HANDLING HMS microfluidics/microfabrication facility has one high pressure liquid nitrogen tank which supplies the nitrogen for some equipment normal operation. In case the liquid nitrogen tank is malfunctioning and requires to be shut down or replaced make

Paulsson, Johan

387

SHORT COMMUNICATION Nitrogen recovery from shrimp pond efuent  

E-Print Network (OSTI)

the water as ammonia (total ammonia nitrogen, TAN), through either direct excretion by animals or ammoni

Lorenzen, Kai

388

Nitrogen is a natural and necessary part of every healthy ecosystem, but too much nitrogen in our rivers,  

E-Print Network (OSTI)

), sewage treatment plants, and animal ma- nure. Once in water, nitrogen can change in chemical form

Torgersen, Christian

389

Catalyst Additives to Enhance Mercury Oxidation and Capture  

SciTech Connect

Preliminary research has shown that SCR catalysts employed for nitrogen-oxide reduction can effectively oxidize mercury. Three different SCR catalysts are currently being studied in this project--honeycomb-type, plate-type, and a hybrid-type catalyst. The catalysts were manufactured and supplied by Cormetech Inc., Hitachi America Ltd., and Haldor-Topsoe Inc., respectively. Parametric testing was performed to investigate the contribution of flue-gas chemistry on mercury oxidation via SCR catalysts. Future work to characterize flue gas simulations typically derived from low and high sulfur bituminous coal are being performed in a stepwise manner, to avoid the constant interruptions in testing that occur when leaks in the system are generated during temperature transitions. Specifically, chlorine concentration vs. mercury oxidation correlations will be developed for each catalyst. The contributions of temperature are also being investigated. SO2 oxidation is also being investigated for each test condition.

Thomas K. Gale

2005-12-31T23:59:59.000Z

390

Effect of ammonia plasma treatment on graphene oxide LB monolayers  

SciTech Connect

Graphene oxide monolayer sheets were transferred on Si and SiO{sub 2}/Si substrates by Langmuir-Blodgett technique and were exposed to ammonia plasma at room temperature. The monolayer character of both graphene oxide and plasma treated graphene oxide sheets were ascertained by atomic force microscopy. X-ray photoelectron spectroscopy and Raman spectroscopy revealed that ammonia plasma treatment results in enhancement of graphitic carbon content along with the incorporation of nitrogen. The conductivity of graphene oxide monolayers, which was in the range of 10{sup -6}-10{sup -7} S/cm, increased to 10{sup -2}-10{sup -3} S/cm after the ammonia plasma treatment. These results indicate that the graphene oxide was simultaneously reduced and N-doped during ammonia plasma treatment, without affecting the morphological stability of sheets.

Singh, Gulbagh; Botcha, V. Divakar; Narayanam, Pavan K.; Sutar, D. S.; Talwar, S. S.; Major, S. S. [Department of Physics, Indian Institute of Technology Bombay, Mumbai - 400076 (India); Srinivasa, R. S. [Department of Metallurgical Engineering and Materials Science, Indian Institute of Technology Bombay, Mumbai - 400076 (India)

2013-02-05T23:59:59.000Z

391

Nitrogen Deposition in the Southern High Plains Nitrogen is necessary for life on earth, but  

E-Print Network (OSTI)

to the environment. Dinitrogen contains two nitrogen atoms held together by one of nature's strongest chemical bonds in the environment include ammonia (NH3) and its related compounds, amines (NH2), nitrite (NO2) and nitrate (NO3 responsible for producing 500 million tons of nitrogen fertilizer each year, combines dinitro- gen

Mukhtar, Saqib

392

Quantification and characterization of dissolved organic nitrogen in wastewater effluents by electrodialysis treatment followed by size-exclusion chromatography with nitrogen detection  

Science Journals Connector (OSTI)

Abstract Dissolved organic nitrogen (DON) can act as a precursor of nitrogenous disinfection byproducts during oxidative water treatment. Quantification and characterization of DON are still challenging for waters with high concentrations of dissolved inorganic nitrogen (DIN, including ammonia, nitrate and nitrite) relative to total dissolved nitrogen (TDN) due to the cumulative analytical errors of independently measured nitrogen species (i.e., DON = TDN ?  NO 2 ?  ?  NO 3 ?  ?  NH 4 + /NH3) and interference of DIN species to TDN quantification. In this study, a novel electrodialysis (ED)-based treatment for selective DIN removal was developed and optimized with respect to type of ion-exchange membrane, sample pH, and ED duration. The optimized ED method was then coupled with size-exclusion chromatography with organic carbon, UV, and nitrogen detection (SEC-OCD-ND) for advanced DON analysis in wastewater effluents. Among the tested ion-exchange membranes, the PC-AR anion- and CMT cation-exchange membranes showed the lowest DOC loss (1–7%) during ED treatment of a wastewater effluent at ambient pH (8.0). A good correlation was found between the decrease of the DIN/TDN ratio and conductivity. Therefore, conductivity has been adopted as a convenient way to determine the optimal duration of the ED treatment. In the pH range of 7.0–8.3, ED treatment of various wastewater effluents with the PC-AR/CMT membranes showed that the relative residual conductivity could be reduced to less than 0.50 (DIN removal >90%; DIN/TDN ratio ?0.60) with lower DOC losses (6%) than the previous dialysis and nanofiltration methods (DOC loss >10%). In addition, the ED method is shorter (0.5 h) than the previous methods (>1–24 h). The relative residual conductivity was further reduced to ?0.20 (DIN removal >95%; DIN/TDN ratio ?0.35) by increasing the ED duration to 0.7 h (DOC loss = 8%) for analysis by SEC-OCD-ND, which provided new information on distribution and ratio of organic carbon and nitrogen in different molecular weight fractions of effluent organic matter.

Kangmin Chon; Yunho Lee; Jacqueline Traber; Urs von Gunten

2013-01-01T23:59:59.000Z

393

Effect of Nitrogen Additives on Flame Retardant Action of Tributyl Phosphate: Phosphorus – Nitrogen Synergism  

SciTech Connect

The effect of nitrogen additives like urea, guanidine carbonate and melamine formaldehyde on the flame retardant efficacy of tributyl phosphate (TBP) has been investigated. From the LOI tests on treated cotton it is clear that the nitrogen additives have synergistic action. Estimation of activation energy of decomposition of treated cotton indicated that nitrogen additives enhance the thermal stability during the burning process. SEM pictures of chars formed after LOI test showed the formation of protective polymeric coating on the surface. The surface of chars formed were evaluated using FTIR-ATR and XPS analysis which showed that the coating was composed of Phosphorus-Nitrogen-Oxygen containing species. Formation of this coating during the burning process could lead to the synergistic interaction of phosphorus and nitrogen. Based on the experimental data we have further proposed several reaction mechanisms which could contribute to synergistic action and formation of protective coating on the surface of char.

Gaan, Sabyasachi; Sun, Gang; Hutches, Katherine; Engelhard, Mark H.

2008-01-01T23:59:59.000Z

394

Frostbite Theater - Liquid Nitrogen Experiments - Dry Ice vs. Liquid  

NLE Websites -- All DOE Office Websites (Extended Search)

Egg + Liquid Nitrogen + Time-lapse! Egg + Liquid Nitrogen + Time-lapse! Previous Video (Egg + Liquid Nitrogen + Time-lapse!) Frostbite Theater Main Index Next Video (Liquid Nitrogen Cooled Dry Ice in Water!) Liquid Nitrogen Cooled Dry Ice in Water! Dry Ice vs. Liquid Nitrogen! Dry ice is cold. Liquid nitrogen is cold, too. What happens when the two are mixed together? [ Show Transcript ] Announcer: Frostbite Theater presents... Cold Cuts! No baloney! Joanna and Steve: Just science! Joanna: Hi! I'm Joanna! Steve: And I'm Steve! Joanna: Have you ever wondered what happens when you mix dry ice and liquid nitrogen? Steve: Well, we just happen to have a chunk of dry ice left over from when we filmed 'How to Make a Cloud Chamber,' and here at Jefferson Lab, liquid nitrogen flows like water, so we're going to find out!

395

Availability of Nitrous Nitrogen to Plants.  

E-Print Network (OSTI)

V, .=DL ULL LI~C a~ailability 01 ILILKLL~: IIILIU~~I~ LU curn, l~aa, 8011 31LY3 1 27.3 .53 .I447 1 I 1 5: 1250 .I349 ic nitrogen ( 37.P' 1 -59 1 .2195 ru.. nv / 36.6 .57 1 .2086 I -2141 1 .O7b/ I 1. gm. nitrous nitrogen 30.2 1 .64 1 .I933 1... .12 -.01 ' .09 V1 -- I w 01 ---- I ------ el M - 1 --O6 X * ---- ------ U1 $ !z - --- i d $ --- - I -20 2 Y * F - I M 4 M .34 I --- .20 M .14 5 nitrogen --- --- -.02 .14 -.48 -.01 -12 .18 .OS...

Fraps, G. S. (George Stronach); Sterges, A. J.

1935-01-01T23:59:59.000Z

396

Asphalt Oxidation Kinetics and Pavement Oxidation Modeling  

E-Print Network (OSTI)

Most paved roads in the United States are surfaced with asphalt. These asphalt pavements suffer from fatigue cracking and thermal cracking, aggravated by the oxidation and hardening of asphalt. This negative impact of asphalt oxidation on pavement...

Jin, Xin

2012-07-16T23:59:59.000Z

397

E-Print Network 3.0 - additional nitrogen responses Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

tons of nitrogen fertilizer each year, combines dinitro- gen... National Park (Colorado, USA): a response to anthropogenic nitrogen deposition." Geobiology 1... Nitrogen...

398

The importance of cytosolic glutamine synthetase in nitrogen assimilation and recycling  

E-Print Network (OSTI)

nitrogen mobilization and recycling in trees. Photosynthesisloci mapping for nitrogen recycling in rice. Journal ofNitrogen Assimilation and Recycling Stéphanie M. Bernard 1

Bernard, S.M.

2009-01-01T23:59:59.000Z

399

E-Print Network 3.0 - aerobic nitrogen cycle Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

biological nitrogen fixation of gaseous nitrogen. The water cycle is important to ecosystem... and Nitrogen Cycles As ... Source: Barboza, Perry - Institute of Arctic Biology,...

400

Optimizing hydrocarbon recoveries in nitrogen rejection units  

SciTech Connect

In order to address conceptual questions such as process selection and natural gas liquids plant integration, an understanding of the effects of several additional factors on nitrogen rejection unit design is important. These factors, which may influence optimum hydrocarbon recovery, installed compression, etc., include current and forecast values for natural gas and utilities, project life, plant size, feed gas composition and product specifications, feed pressure, and process variations. Prices, project life, and plant size are analyzed in detail and presented in terms of methane recoveries as a function of nitrogen content in the feed for both double and single column processes. Trends are qualitatively discussed for the remaining factors. 13 references.

Chesney, J.D.; Davis, R.A.; Hilton, M.F.; Vines, H.L.

1983-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "nitrogen oxide burner" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Enzymatic solubilization of nitrogenous constituents of carrots  

E-Print Network (OSTI)

of enzyme concentration upon nitrogen so1ubi 1i zed in carrot tops ( 10g dry weight) . Conditions of assay: pH = 3. 5, i ncubati on time = 20 hr, incubation temperature = 45'C. 24 hydrolysis. These data confirm earlier reports that -. 01% is the pro... roots and tops, a concentration of 1. 0% A-12-C at pH 3. 5 provided the maximum increase in soluble ni trogenous consti tuents . For car~ot roots, a concentration of 1. 0/ ficin at pH 4, 5 provided the maximum increase in soluble nitrogen. With carrot...

Curry, James Cannon

1971-01-01T23:59:59.000Z

402

Biexciton emission from single isoelectronic traps formed by nitrogen-nitrogen pairs in GaAs  

SciTech Connect

We have studied photoluminescence (PL) from individual isoelectronic traps formed by nitrogen-nitrogen (NN) pairs in GaAs. Sharp emission lines due to exciton and biexciton were observed from individual isoelectronic traps in nitrogen atomic-layer doped (ALD) GaAs. The binding energy of biexciton bound to individual isoelectronic traps was approximately 8 meV. Both the exciton and biexciton luminescence lines show completely random polarization and no fine-structure splitting. These results are desirable to the application to the quantum cryptography used in the field of quantum information technology.

Takamiya, Kengo; Fukushima, Toshiyuki; Yagi, Shuhei; Hijikata, Yasuto; Yaguchi, Hiroyuki [Graduate School of Science and Engineering, Saitama University, 255 Shimo-Okubo, Sakura-ku , Saitama 338-8570 (Japan); Mochizuki, Toshimitsu; Yoshita, Masahiro; Akiyama, Hidefumi [Institute for Solid State Physics, The University of Tokyo, 5-1-5 Kashiwanoha, Kashiwa, Chiba 277-8581 (Japan); Kuboya, Shigeyuki; Onabe, Kentaro [Department of Advanced Materials Science, The University of Tokyo, 5-1-5 Kashiwanoha, Kashiwa, Chiba 277-8581 (Japan); Katayama, Ryuji [Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577 (Japan)

2013-12-04T23:59:59.000Z

403

Mechanisms of synfuel degradation. 3. Interactive effects in nitrogen compound induced storage instability in shale derived diesel fuel  

SciTech Connect

Deterioration in fuel quality upon storage has been a continuing problem in the utilization of middle distillate fuels. For diesel fuels, instability is usually defined by the formation of insoluble sediments and gums and by the accumulation of hydroperoxides. Gravimetric accelerated storage stability tests conducted with model compounds as dopants in otherwise stable distillate fuels have demonstrated that oxidative condensation reactions of polar heterocycles are deleterious to stability. In particular, nitrogen containing aromatics (pyrroles, pyridines, indoles, etc.) appear to be very harmful.

Cooney, J.V.; Beal, E.J.; Beaver, B.D.

1986-01-01T23:59:59.000Z

404

Neutral nitrogen acceptors in ZnO: The {sup 67}Zn hyperfine interactions  

SciTech Connect

Electron paramagnetic resonance (EPR) is used to characterize the {sup 67}Zn hyperfine interactions associated with neutral nitrogen acceptors in zinc oxide. Data are obtained from an n-type bulk crystal grown by the seeded chemical vapor transport method. Singly ionized nitrogen acceptors (N{sup ?}) initially present in the crystal are converted to their paramagnetic neutral charge state (N{sup 0}) during exposure at low temperature to 442 or 633?nm laser light. The EPR signals from these N{sup 0} acceptors are best observed near 5?K. Nitrogen substitutes for oxygen ions and has four nearest-neighbor cations. The zinc ion along the [0001] direction is referred to as an axial neighbor and the three equivalent zinc ions in the basal plane are referred to as nonaxial neighbors. For axial neighbors, the {sup 67}Zn hyperfine parameters are A{sub ?}?=?37.0?MHz and A{sub ?}?=?8.4?MHz with the unique direction being [0001]. For nonaxial neighbors, the {sup 67}Zn parameters are A{sub 1}?=?14.5?MHz, A{sub 2}?=?18.3?MHz, and A{sub 3}?=?20.5?MHz with A{sub 3} along a [101{sup ¯}0] direction (i.e., in the basal plane toward the nitrogen) and A{sub 2} along the [0001] direction. These {sup 67}Zn results and the related {sup 14}N hyperfine parameters provide information about the distribution of unpaired spin density at substitutional neutral nitrogen acceptors in ZnO.

Golden, E. M.; Giles, N. C., E-mail: Nancy.Giles@afit.edu [Department of Engineering Physics, Air Force Institute of Technology, Wright-Patterson Air Force Base, Ohio 45433 (United States); Evans, S. M.; Halliburton, L. E. [Department of Physics, West Virginia University, Morgantown, West Virginia 26506 (United States)

2014-03-14T23:59:59.000Z

405

Surface modification of nitrogen-doped carbon nanotubes by ozone via atomic layer deposition  

SciTech Connect

The use of ozone as an oxidizing agent for atomic layer deposition (ALD) processes is rapidly growing due to its strong oxidizing capabilities. However, the effect of ozone on nanostructured substrates such as nitrogen-doped multiwalled carbon nanotubes (NCNTs) and pristine multiwalled carbon nanotubes (PCNTs) are not very well understood and may provide an avenue toward functionalizing the carbon nanotube surface prior to deposition. The effects of ALD ozone treatment on NCNTs and PCNTs using 10?wt. % ozone at temperatures of 150, 250, and 300?°C are studied. The effect of ozone pulse time and ALD cycle number on NCNTs and PCNTs was also investigated. Morphological changes to the substrate were observed by scanning electron microscopy and high resolution transmission electron microscopy. Brunauer-Emmett-Teller measurements were also conducted to determine surface area, pore size, and pore size distribution following ozone treatment. The graphitic nature of both NCNTs and PCNTs was determined using Raman analysis while x-ray photoelectron spectroscopy (XPS) was employed to probe the chemical nature of NCNTs. It was found that O{sub 3} attack occurs preferentially to the outermost geometric surface of NCNTs. Our research also revealed that the deleterious effects of ozone are found only on NCNTs while little or no damage occurs on PCNTs. Furthermore, XPS analysis indicated that ALD ozone treatment on NCNTs, at elevated temperatures, results in loss of nitrogen content. Our studies demonstrate that ALD ozone treatment is an effective avenue toward creating low nitrogen content, defect rich substrates for use in electrochemical applications and ALD of various metal/metal oxides.

Lushington, Andrew; Liu, Jian; Tang, Yongji; Li, Ruying; Sun, Xueliang, E-mail: xsun@eng.uwo.ca [Department of Mechanical and Materials Engineering, University of Western Ontario, London, Ontario N6A 5B9 (Canada)

2014-01-15T23:59:59.000Z

406

INFRARED and PHOTOELECTRON SPECTROSCOPIC STUDY OF S02 OXIDATION ON SOOT PARTICLES  

E-Print Network (OSTI)

generated with a conventional Bunsen burner using propaneor propane saturated with benzene vapor as fuel.The propane (Matheson) was either of research or instrument

Chang, S.G.

2010-01-01T23:59:59.000Z

407

Frostbite Theater - Liquid Oxygen vs. Liquid Nitrogen - Liquid Oxygen and  

NLE Websites -- All DOE Office Websites (Extended Search)

Cells vs. Liquid Nitrogen! Cells vs. Liquid Nitrogen! Previous Video (Cells vs. Liquid Nitrogen!) Frostbite Theater Main Index Next Video (Paramagnetism) Paramagnetism Liquid Oxygen and Fire! What happens when nitrogen and oxygen are exposed to fire? [ Show Transcript ] Announcer: Frostbite Theater presents... Cold Cuts! No baloney! Joanna and Steve: Just science! Joanna: Hi! I'm Joanna! Steve: And I'm Steve! Joanna: And this is a test tube of liquid nitrogen! Steve: And this is a test tube of liquid oxygen! Joanna: Let's see what happens when nitrogen and oxygen are exposed to fire. Steve: Fire?! Joanna: Yeah! Steve: Really?! Joanna: Why not! Steve: Okay! Joanna: As nitrogen boils, it changes into nitrogen gas. Because it's so cold, it's denser than the air in the room. The test tube fills up with

408

Liquid absorbent solutions for separating nitrogen from natural gas  

DOE Patents (OSTI)

Nitrogen-absorbing and -desorbing compositions, novel ligands and transition metal complexes, and methods of using the same, which are useful for the selective separation of nitrogen from other gases, especially natural gas.

Friesen, Dwayne T. (Bend, OR); Babcock, Walter C. (Bend, OR); Edlund, David J. (Redmond, OR); Lyon, David K. (Bend, OR); Miller, Warren K. (Bend, OR)

2000-01-01T23:59:59.000Z

409

First Principles Prediction of Nitrogen-doped Carbon Nanotubes...  

NLE Websites -- All DOE Office Websites (Extended Search)

First Principles Prediction of Nitrogen-doped Carbon Nanotubes as a High-Performance Cathode for Li-S Batteries. First Principles Prediction of Nitrogen-doped Carbon Nanotubes as a...

410

Breath is a mixture of nitrogen, oxygen, carbon dioxide, water  

E-Print Network (OSTI)

12 SCIENCE Breath is a mixture of nitrogen, oxygen, carbon dioxide, water vapour, inert gases. On the basis of proton affinity, the major constituents of air and breath (nitrogen, oxygen, carbon dioxide

411

Nitrogen chemistry during oil shale pyrolysis  

SciTech Connect

Real time evolution of ammonia (NH{sub 3}) and hydrogen cyanide (HCN), two major nitrogen-containing volatiles evolved during oil shale pyrolysis, was measured by means of a mass spectrometer using chemical ionization and by infrared spectroscopy. While the on-line monitoring of NH{sub 3} in oil shale pyrolysis games was possible by both techniques, HCN measurements were only possible by IR. We studied one Green River Formation oil shale and one New Albany oil shale. The ammonia from the Green River oil shale showed one broad NH{sub 3} peak maximizing at a high temperature. For both oil shales, most NH{sub 3} evolves at temperatures above oil-evolving temperature. The important factors governing ammonia salts such as Buddingtonite in Green River oil shales, the distribution of nitrogen functional groups in kerogen, and the retorting conditions. The gas phase reactions, such as NH{sub 3} decomposition and HCN conversion reactions, also play an important role in the distribution of nitrogen volatiles, especially at high temperatures. Although pyrolysis studies of model compounds suggests the primary nitrogen product from kerogen pyrolysis to be HCN at high temperatures, we found only a trace amount of HCN at oil-evolving temperatures and none at high temperatures (T {gt} 600{degree}C). 24 refs., 6 figs., 2 tabs.

Oh, Myongsook S.; Crawford, R.W.; Foster, K.G.; Alcaraz, A.

1990-01-10T23:59:59.000Z

412

Introduction Air Quality and Nitrogen Dioxide  

E-Print Network (OSTI)

- Global update 2005. Primary sources of air pollutants include combustion products from power generationIntroduction Air Quality and Nitrogen Dioxide Air pollution can be defined as "the presence effects to man and/or the environment". (DEFRA) "Clean air is considered to be a basic requirement

413

groundwater nitrogen source identification and remediation  

E-Print Network (OSTI)

producer profits. This will, in turn, benefit water bodies in the area that receive stream baseflow fromgroundwater nitrogen source identification and remediation The Seymour Aquifer is a shallow aquifer water withdraws are used for irrigation while the cities of Vernon, Burk- burnett and Electra and many

414

OXYGEN ADSORPTION ON NITROGEN CONTAINING CARBON SURFACES  

E-Print Network (OSTI)

OXYGEN ADSORPTION ON NITROGEN CONTAINING CARBON SURFACES Alejandro Montoya, Jorge O. Gil, Fanor-rich site of the carbon basal plane of graphite and then, it dissociates into oxygen atoms.1,2 Oxygen atoms at the edge of the carbon surface can form covalent bonds with oxygen. These sites can chemisorb

Truong, Thanh N.

415

HELSINKI UNIVERSITY OF TECHNOLOGY ENE-47.153 NITROGEN #2NITROGEN #2  

E-Print Network (OSTI)

(BFB), (CFB) (BFB), (CFB) Fuel nitrogen content Excess air Air staging Limestone addition , - (BFB), (CFB) SO2 level SNCR ­ NH3 , - SNCR ­ urea SCR - Pressure , (but NO2 ) #12;HELSINKI

Zevenhoven, Ron

416

Evolutionary tradeoffs can select against nitrogen fixation and thereby maintain nitrogen limitation  

E-Print Network (OSTI)

. evolutionary ecology model Biological nitrogen (N) fixation--the conversion of atmo- spheric N2 gas) but is equally important to explaining the paradox of N limitation. Unlike the successional question

Menge, Duncan

417

Temperature and nutrient supply interact to control nitrogen fixation ...  

Science Journals Connector (OSTI)

Temperature and nutrient supply interact to control nitrogen fixation in oligotrophic streams: An experimental examination. Marcarelli, Amy M., Wayne A.

418

Core-level spectroscopy of thin oxides and oxynitrides  

SciTech Connect

Several spectroscopic methods are discussed that use core levels, such as photoelectron spectroscopy and absorption spectroscopy with photoelectron or fluorescence detection. Measurements are presented on the desorption of a chemical oxide and the growth of oxynitrides with N{sub 2}0 on Si(100). The stoichiometry is found to change strongly with thickness, from a nitrogen-terminated Si surface to a nearly-pure oxide in the outer region of 40--60 {Angstrom} films. Using a third generation synchrotron beam line a sensitivity of better than a tenth of a monolayer is achieved by a simple photocurrent measurement.

Himpsel, F.J.; Akatsu, H. [International Business Machines Corp., Yorktown Heights, NY (United States). Thomas J. Watson Research Center; Carlisle, J.A. [Lawrence Livermore National Lab., CA (United States)] [and others

1994-07-19T23:59:59.000Z

419

Vapour nucleation in a cryogenic–fluid–dissolved–nitrogen mixture during rapid depressurization  

Science Journals Connector (OSTI)

...the dissolved nitrogen comes out of the...effect of dissolved nitrogen was not addressed...non-condensable gas (nitrogen) in a cryogenic...g. superheated water or pure refrigerants...to estimate the solubility of nitrogen in...

1999-01-01T23:59:59.000Z

420

Nitrogen use in switchgrass grown for bioenergy across the USA  

E-Print Network (OSTI)

Nitrogen use in switchgrass grown for bioenergy across the USA V.N. Owens a , D.R. Viands b , H Available online 17 August 2013 Keywords: Nitrogen removal Switchgrass Bioenergy Nitrogen use efficiency as a forage, conservation, and bioenergy crop [1e5]. It offers a number of distinct benefits including broad

Pawlowski, Wojtek

Note: This page contains sample records for the topic "nitrogen oxide burner" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Relation of Soil Nitrogen, Nitrification and Ammonification to Pot Experiments.  

E-Print Network (OSTI)

............................................ 6 Relation of the Crops to the Total Nitrogen of the Soil ........... 7 Relation of the Different Crops ................................. 8 Relation of Surface Soil to Subsoil ............................. 13 Acid Soils Compared with Non-Acid... of Production of Nitrates to the Results of the Pot Ex- periments ................................................ 21 Extensive Work ............................................ 24 Relation of Nitric Nitrogen to Nitrogen Removed by First Crop .... 24...

Fraps, G. S. (George Stronach)

1921-01-01T23:59:59.000Z

422

QuestionQuestion How does nitrogen deposition affect roadside  

E-Print Network (OSTI)

al. 2004. Concentrations of ammonia and nitrogen dioxide at roadside verges, and their contributionQuestionQuestion How does nitrogen deposition affect roadside plant community composition? 1. Is there a gradient of nitrogen deposition to freeway verges from traffic exhaust? 2. Are there other sources of N

Hall, Sharon J.

423

Simple approaches for measuring dry atmospheric nitrogen deposition to watersheds  

E-Print Network (OSTI)

'' and spatial variations of gaseous dry N deposition (i.e., nitrogen dioxide (NO2) and ammonia (NH3)), thoughSimple approaches for measuring dry atmospheric nitrogen deposition to watersheds Heather E. Golden the effects of atmospheric nitrogen (N) deposition on surface water quality requires accurate accounts

Elliott, Emily M.

424

A chronology of human understanding of the nitrogen cycle  

Science Journals Connector (OSTI)

...nitrogen and hydrogen gas [7,22,23...process surpassed natural N fixation [31...of the nitrogen cascade was proposed...terrestrial 104 118 --natural - - 30 50 50 170...consequences in the natural environment...2003 The nitrogen cascade. Bioscience 53...anthropogenic trace gases. In Interactions...

2013-01-01T23:59:59.000Z

425

How extensive are the impacts of nitrogen pollution in Great  

E-Print Network (OSTI)

the 1940s atmospheric nitrogen pollution has steadily increased, primarily as a consequence in the deposition of atmospheric nitrogen pollutants are likely to have contributed to improved forest productivityHow extensive are the impacts of nitrogen pollution in Great Britain's forests? Protecting our

426

Special Aspects of Nitrogen Fixation by Blue-Green Algae  

Science Journals Connector (OSTI)

...Aspects of Nitrogen Fixation by Blue-Green Algae Rosalie M. Cox P. Fay When carbon dioxide...required for nitrogen fixation in this alga. A ratio of pyruvate decarboxylation to...independent of photosynthesis in blue-green algae. Special aspects of nitrogen fixation...

1969-01-01T23:59:59.000Z

427

Stress dependent oxidation of sputtered niobium and effects on superconductivity  

SciTech Connect

We report on the suppression of room temperature oxidation of DC sputtered niobium films and the effects upon the superconductive transition temperature, T{sub c}. Niobium was sputter-deposited on silicon dioxide coated 150?mm wafers and permitted to oxidize at room temperature and pressure for up to two years. Resistivity and stress measurements indicate that tensile films greater than 400?MPa resist bulk oxidation with measurements using transmission electron microscope, electron dispersive X-ray spectroscopy, x-ray photoelectric spectroscopy, and secondary ion mass spectrometry confirming this result. Although a surface oxide, Nb{sub 2}O{sub 5}, consumed the top 6–10?nm, we measure less than 1 at. % oxygen and nitrogen in the bulk of the films after the oxidation period. T{sub c} measurements using a SQUID magnetometer indicate that the tensile films maintained a T{sub c} approaching the dirty superconductive limit of 8.4?K after two years of oxidation while maintaining room temperature sheet resistance. This work demonstrates that control over niobium film stress during deposition can prevent bulk oxidation by limiting the vertical grain boundaries ability to oxidize, prolonging the superconductive properties of sputtered niobium when exposed to atmosphere.

David Henry, M., E-mail: mdhenry@sandia.gov; Wolfley, Steve; Monson, Todd; Clark, Blythe G.; Shaner, Eric; Jarecki, Robert [Sandia National Labs, MESA Fabrication Facility PO Box 5800 MS 1084, Albuquerque, New Mexico 87185-1084 (United States)

2014-02-28T23:59:59.000Z

428

Dilute Oxygen Combustion - Phase 3 Report  

SciTech Connect

Dilute Oxygen Combustion (DOC) burners have been successfully installed and operated in the reheat furnace at Auburn Steel Co., Inc., Auburn, NY, under Phase 3 of the Dilute Oxygen Combustion project. Two new preheat zones were created employing a total of eight 6.5 MMBtu/hr capacity burners. The preheat zones provide a 30 percent increase in maximum furnace production rate, from 75 tph to 100 tph. The fuel rate is essentially unchanged, with the fuel savings expected from oxy-fuel combustion being offset by higher flue gas temperatures. When allowance is made for the high nitrogen level and high gas phase temperature in the furnace, measured NOx emissions are in line with laboratory data on DOC burners developed in Phase 1 of the project. Burner performance has been good, and there have been no operating or maintenance problems. The DOC system continues to be used as part of Auburn Steel's standard reheat furnace practice. High gas phase temperature is a result of the high firing density needed to achieve high production rates, and little opportunity exists for improvement in that area. However, fuel and NOx performance can be improved by further conversion on furnace zones to DOC burners, which will lower furnace nitrogen levels. Major obstacles are cost and concern about increased formation of oxide scale on the steel. Oxide scale formation may be enhanced by exposure of the steel to higher concentrations of oxidizing gas components (primarily products of combustion) in the higher temperature zones of the furnace. Phase 4 of the DOC project will examine the rate of oxide scale formation in these higher temperature zones and develop countermeasures that will allow DOC burners to be used successfully in these furnace zones.

Riley, Michael F.

2000-05-31T23:59:59.000Z

429

Dilute Oxygen Combustion Phase 3 Final Report  

SciTech Connect

Dilute Oxygen Combustion (DOC) burners have been successfully installed and operated in the reheat furnace at Auburn Steel Co., Inc., Auburn, NY, under Phase 3 of the Dilute Oxygen Combustion project. Two new preheat zones were created employing a total of eight 6.5 MMBtu/hr capacity burners. The preheat zones provide a 30 percent increase in maximum furnace production rate, from 75 tph to 100 tph. The fuel rate is essentially unchanged, with the fuel savings expected from oxy-fuel combustion being offset by higher flue gas temperatures. When allowance is made for the high nitrogen level and high gas phase temperature in the furnace, measured NOx emissions are in line with laboratory data on DOC burners developed in Phase 1 of the project. Burner performance has been good and there have been no operating or maintenance problems. The DOC system continues to be used as part of Auburn Steel?s standard reheat furnace practice. High gas phase temperature is a result of the high firing density needed to achieve high production rates, and little opportunity exists for improvement in that area. However, fuel and NOx performance can be improved by further conversion of furnace zones to DOC burners, which will lower furnace nitrogen levels. Major obstacles are cost and concern about increased formation of oxide scale on the steel. Oxide scale formation may be enhanced by exposure of the steel to higher concentrations of oxidizing gas components (primarily products of combustion) in the higher temperature zones of the furnace. Phase 4 of the DOC project will examine the rate of oxide scale formation in these higher temperature zones and develop countermeasures that will allow DOC burners to be used successfully in these furnace zones.

Riley, M.F.; Ryan, H.M.

2000-05-31T23:59:59.000Z

430

Nitrogen-concentration control in GaNAs/AlGaAs quantum wells using nitrogen ?-doping technique  

SciTech Connect

GaNAs/Al{sub 0.35}Ga{sub 0.65}As multiple quantum wells (MQWs) with nitrogen ?-doping were fabricated on GaAs (100) substrates by plasma-assisted molecular beam epitaxy. High controllability of nitrogen-concentrations in the MQWs was achieved by tuning nitrogen ?-doping time. The maximum nitrogen concentration in the MQWs was 2.8%. The MQWs exhibit intense, narrow photoluminescence emission.

Mano, Takaaki; Jo, Masafumi; Kuroda, Takashi; Noda, Takeshi; Sugimoto, Yoshimasa; Sakuma, Yoshiki [National Institute for Materials Science, 1-2-1 Sengen, Tsukuba, Ibaraki 305-0047 (Japan); Elborg, Martin; Sakoda, Kazuaki [National Institute for Materials Science, 1-2-1 Sengen, Tsukuba, Ibaraki 305-0047, Japan and Graduate School of Pure and Applied Sciences, University of Tsukuba, 1-1-1 Tennodai, Tsukuba, Ibaraki 305-8577 (Japan)

2014-05-15T23:59:59.000Z

431

Toward a mechanistic modeling of nitrogen limitation on vegetation dynamics  

SciTech Connect

Nitrogen is a dominant regulator of vegetation dynamics, net primary production, and terrestrial carbon cycles; however, most ecosystem models use a rather simplistic relationship between leaf nitrogen content and photosynthetic capacity. Such an approach does not consider how patterns of nitrogen allocation may change with differences in light intensity, growing-season temperature and CO{sub 2} concentration. To account for this known variability in nitrogen-photosynthesis relationships, we develop a mechanistic nitrogen allocation model based on a trade-off of nitrogen allocated between growth and storage, and an optimization of nitrogen allocated among light capture, electron transport, carboxylation, and respiration. The developed model is able to predict the acclimation of photosynthetic capacity to changes in CO{sub 2} concentration, temperature, and radiation when evaluated against published data of V{sub c,max} (maximum carboxylation rate) and J{sub max} (maximum electron transport rate). A sensitivity analysis of the model for herbaceous plants, deciduous and evergreen trees implies that elevated CO{sub 2} concentrations lead to lower allocation of nitrogen to carboxylation but higher allocation to storage. Higher growing-season temperatures cause lower allocation of nitrogen to carboxylation, due to higher nitrogen requirements for light capture pigments and for storage. Lower levels of radiation have a much stronger effect on allocation of nitrogen to carboxylation for herbaceous plants than for trees, resulting from higher nitrogen requirements for light capture for herbaceous plants. As far as we know, this is the first model of complete nitrogen allocation that simultaneously considers nitrogen allocation to light capture, electron transport, carboxylation, respiration and storage, and the responses of each to altered environmental conditions. We expect this model could potentially improve our confidence in simulations of carbon-nitrogen interactions and the vegetation feedbacks to climate in Earth system models.

Xu, Chonggang [Los Alamos National Laboratory (LANL); Fisher, Rosie [National Center for Atmospheric Research (NCAR); Wullschleger, Stan D [ORNL; Wilson, Cathy [Los Alamos National Laboratory (LANL); Cai, Michael [Los Alamos National Laboratory (LANL); McDowell, Nathan [Los Alamos National Laboratory (LANL)

2012-01-01T23:59:59.000Z

432

Oxidation of propylene over copper oxide catalysts  

E-Print Network (OSTI)

to the study of propylene oxidation. Dunlop (17) reported that small quantities of iron compounds substantially enhanced the catalytic activity of chromia-alumina catalysts with respect to propylene oxidation, Woodharn (72) has suggested that under... between 360 C and 430oC the rate of propane oxidation decreases as the teznperature is increased, and the rate of conversion to olefins, especially propylene, becomes progressively greater. Above 430 C the proportion of propane converted to ethylene in...

Billingsley, David Stuart

2012-06-07T23:59:59.000Z

433

Frostbite Theater - Liquid Nitrogen Experiments - Freeze the Rainbow!  

NLE Websites -- All DOE Office Websites (Extended Search)

Liquid Nitrogen in a Microwave! Liquid Nitrogen in a Microwave! Previous Video (Liquid Nitrogen in a Microwave!) Frostbite Theater Main Index Next Video (Liquid Nitrogen and Antifreeze!) Liquid Nitrogen and Antifreeze! Freeze the Rainbow! Starburst candy. They're fruity. They're chewy. They're delicious! But, can they survive taking a bath in liquid nitrogen? [ Show Transcript ] Announcer: Frostbite Theater presents... Cold Cuts! No baloney! Joanna and Steve: Just science! Joanna: Hi! I'm Joanna! Steve: And I'm Steve! Joanna: A student visiting Jefferson Lab from Huntington Middle School in Newport News, Virginia, asked what happens to a starburst if you put it in liquid nitrogen. Well, we're going to find out! Steve: At room temperature, starburst isn't really all that special. I can kind of squish it if I squeeze it hard enough and, if I drop it, nothing

434

Frostbite Theater - Liquid Nitrogen Experiments - Giant Koosh Ball!  

NLE Websites -- All DOE Office Websites (Extended Search)

Let's Pour Liquid Nitrogen on the Floor! Let's Pour Liquid Nitrogen on the Floor! Previous Video (Let's Pour Liquid Nitrogen on the Floor!) Frostbite Theater Main Index Next Video (Egg + Liquid Nitrogen + Time-lapse!) Egg + Liquid Nitrogen + Time-lapse! Giant Koosh Ball! Sometimes, you just want to know what's going to happen! [ Show Transcript ] Announcer: Frostbite Theater presents... Cold Cuts! No baloney! Joanna and Steve: Just science! Joanna: Hi! I'm Joanna! Steve: And I'm Steve! A while ago, I was at the mall and I saw this. And, the first thing that popped into my head was 'I wonder what would happen if we were to put this in liquid nitrogen?' Now, that's one thing I really love about science. If you have a question, you can, sometimes, do an experiment to find out what the answer is! Here at the Lab, we have a lot of liquid nitrogen, so that's

435

Frostbite Theater - Liquid Nitrogen Experiments - Let's Freeze Liquid  

NLE Websites -- All DOE Office Websites (Extended Search)

Shattering Pennies! Shattering Pennies! Previous Video (Shattering Pennies!) Frostbite Theater Main Index Next Video (Liquid Nitrogen in a Microwave!) Liquid Nitrogen in a Microwave! Let's Freeze Liquid Nitrogen! By removing the hottest molecules, we're able to freeze liquid nitrogen! [ Show Transcript ] Announcer: Frostbite Theater presents... Cold Cuts! No baloney! Joanna and Steve: Just science! Joanna: Hi! I'm Joanna! Steve: And I'm Steve! Joanna: Today, we're going to freeze liquid nitrogen! Joanna and Steve: Yeah! Joanna: The obvious way to do this is to put the liquid nitrogen into something colder. Something that we have lots of around here! Something like... liquid helium! Steve: Yes! Joanna: Yeah, but we're not going to do that. Instead, we're going to freeze the nitrogen by removing the hottest molecules!

436

DISSOLUTION OF NEPTUNIUM OXIDE RESIDUES  

SciTech Connect

This report describes the development of a dissolution flowsheet for neptunium (Np) oxide (NpO{sub 2}) residues (i.e., various NpO{sub 2} sources, HB-Line glovebox sweepings, and Savannah River National Laboratory (SRNL) thermogravimetric analysis samples). Samples of each type of materials proposed for processing were dissolved in a closed laboratory apparatus and the rate and total quantity of off-gas were measured. Samples of the off-gas were also analyzed. The quantity and type of solids remaining (when visible) were determined after post-dissolution filtration of the solution. Recommended conditions for dissolution of the NpO{sub 2} residues are: Solution Matrix and Loading: {approx}50 g Np/L (750 g Np in 15 L of dissolver solution), using 8 M nitric acid (HNO{sub 3}), 0.025 M potassium fluoride (KF) at greater than 100 C for at least 3 hours. Off-gas: Analysis of the off-gas indicated nitric oxide (NO), nitrogen dioxide (NO{sub 2}) and nitrous oxide (N{sub 2}O) as the only identified components. No hydrogen (H{sub 2}) was detected. The molar ratio of off-gas produced per mole of Np dissolved ranged from 0.25 to 0.4 moles of gas per mole of Np dissolved. A peak off-gas rate of {approx}0.1 scfm/kg bulk oxide was observed. Residual Solids: Pure NpO{sub 2} dissolved with little or no residue with the proposed flowsheet but the NpCo and both sweepings samples left visible solid residue after dissolution. For the NpCo and Part II Sweepings samples the residue amounted to {approx}1% of the initial material, but for the Part I Sweepings sample, the residue amounted to {approx}8 % of the initial material. These residues contained primarily aluminum (Al) and silicon (Si) compounds that did not completely dissolve under the flowsheet conditions. The residues from both sweepings samples contained minor amounts of plutonium (Pu) particles. Overall, the undissolved Np and Pu particles in the residues were a very small fraction of the total solids.

Kyser, E

2009-01-12T23:59:59.000Z

437

NATURAL GAS VARIABILITY IN CALIFORNIA: ENVIRONMENTAL IMPACTS AND DEVICE PERFORMANCE EXPERIMENTAL EVALUATION OF POLLUTANT EMISSIONS FROM RESIDENTIAL APPLIANCES  

E-Print Network (OSTI)

nitrogen oxides, nitrogen dioxide, and  the number of (liquefied natural gas, nitrogen  dioxide, nitrogen oxides, nitrogen oxides, nitrogen dioxide, particle  number,  and 

Singer, Brett C.

2010-01-01T23:59:59.000Z

438

Solid Oxide Fuel Cells  

Science Journals Connector (OSTI)

A Solid Oxide Fuel Cell (SOFC) is typically composed of two porous electrodes, interposed between an electrolyte made of a particular solid oxide ceramic material. The system originates from the work of Nernst...

Nigel M. Sammes; Roberto Bove; Jakub Pusz

2006-01-01T23:59:59.000Z

439

Evolution of Photosynthesis and Biospheric Oxygenation Contingent Upon Nitrogen Fixation?  

E-Print Network (OSTI)

How photosynthesis by Precambrian cyanobacteria oxygenated Earth's biosphere remains incompletely understood. Here it is argued that the oxic transition, which took place between approximately 2.3 and 0.5 Gyr ago, required a great proliferation of cyanobacteria, and this in turn depended on their ability to fix nitrogen via the nitrogenase enzyme system. However, the ability to fix nitrogen was not a panacea, and the rate of biospheric oxygenation may still have been affected by nitrogen constraints on cyanobacterial expansion. Evidence is presented for why cyanobacteria probably have a great need for fixed nitrogen than other prokaryotes, underscoring the importance of their ability to fix nitrogen. The connection between nitrogen fixation and the evolution of photosynthesis is demonstrated by the similarities between nitrogenase and enzymes critical for the biosynthesis of (bacterio)chlorophyll. It is hypothesized that biospheric oxygenation would not have occurred if the emergence of cyanobacteria had not been preceded by the evolution of nitrogen fixation, and if these organisms had not also acquired the ability to fix nitrogen at the beginning of or very early in their history. The evolution of nitrogen fixation also appears to have been a precondition for the evolution of (bacterio)chlorophyll-based photosynthesis. Given that some form of chlorophyll is obligatory for true photosynthesis, and its light absorption and chemical properties make it a "universal pigment," it may be predicted that the evolution of nitrogen fixation and photosynthesis are also closely linked on other Earth- like planets.

John W. Grula

2006-05-12T23:59:59.000Z

440

Failure of ozone and nitrogen dioxide to enhance lung tumor development in hamsters  

SciTech Connect

We tested the hypothesis that the two common oxidant air pollutants, ozone and nitrogen dioxide, modulate the development of respiratory tract tumors in Syrian golden hamsters. The animals received subcutaneous injections of the carcinogen diethylnitrosamine (20 mg/kg) twice a week while being exposed continuously to an atmosphere of 0.8 parts per million (ppm)* of ozone or 15 ppm of nitrogen dioxide. Animals were killed 16 weeks or 24 to 32 weeks after the beginning of the treatment. Ozone delayed the appearance of tracheal tumors and reduced the incidence of tumors in the lung periphery. A suspected neuroendocrine differentiation of those lung tumors could not be established by immunocytochemistry due to overfixation of tissues. On the other hand, ozone seemed to mitigate development of hepatotoxic lesions mediated by diethylnitrosamine. In animals treated with diethylnitrosamine and exposed to nitrogen dioxide, fewer tracheal tumors and no lung tumors were found. Only a few lung tumors were produced in animals treated with diethylnitrosamine and kept in an atmosphere of 65% oxygen. The previously observed neuroendocrine nature of tumors induced by simultaneous exposure to diethylnitrosamine and hyperoxia could not be established because the long fixation of tissues precluded immunocytochemical stains. Animals treated with diethylnitrosamine and kept in filtered air while being housed in wire-mesh cages developed fewer lung tumors than animals given the same treatment and kept on conventional bedding in shoebox cages. Although all inhalants tested are known to produce substantial cell proliferation in the respiratory tract, it was not possible to document whether this would enhance lung tumor development. The role of the two common air pollutants, ozone and nitrogen dioxide, as possible additional risks in the pathogenesis of lung cancer in animals continues to remain uncertain.

Witschi, H.; Breider, M.A.; Schuller, H.M. (Univ. of California, Davis, CA (United States))

1993-09-01T23:59:59.000Z

Note: This page contains sample records for the topic "nitrogen oxide burner" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Measurements of reactive trace gases and variable O3 formation rates in some South Carolina biomass burning plumes  

E-Print Network (OSTI)

nitric ox- ide (NO), nitrogen dioxide (NO 2 ), ammonia (NHNitric Oxide (NO) Nitrogen Dioxide (NO 2 ) Nitrogen Oxides (Nitric Oxide (NO) Nitrogen Dioxide (NO 2 ) Nitrogen Oxides (

2013-01-01T23:59:59.000Z

442

Towards closing the nitrogen flow in UK agriculture: An explorative study of integrated food and bioenergy production with increased nitrogen recirculation.  

E-Print Network (OSTI)

??Nitrogen is an essential growth factor in nature and for food production. It exists in many forms, including reactive nitrogen compounds available for plant uptake,… (more)

Skenhall, Sara Alongi

2011-01-01T23:59:59.000Z

443

On the Use of Thermal NF3 as the Fluorination and Oxidation Agent in Treatment of Used Nuclear Fuels  

SciTech Connect

This paper presents results of our investigation on the use of nitrogen trifluoride as the fluorination or fluorination/oxidation agent for use in a process for separating valuable constituents from used nuclear fuels by employing the volatility of many transition metal and actinide fluorides. Nitrogen trifluoride is less chemically and reactively hazardous than the hazardous and aggressive fluorinating agents used to prepare uranium hexafluoride and considered for fluoride volatility based nuclear fuels reprocessing. In addition, nitrogen trifluoride’s less aggressive character may be used to separate the volatile fluorides from used fuel and from themselves based on the fluorination reaction’s temperature sensitivity (thermal tunability) rather than relying on differences in sublimation/boiling temperature and sorbents. Our thermodynamic calculations found that nitrogen trifluoride has the potential to produce volatile fission product and actinide fluorides from candidate oxides and metals. Our simultaneous thermogravimetric and differential thermal analyses found that the oxides of lanthanum, cerium, rhodium, and plutonium fluorinated but did not form volatile fluorides and that depending on temperature volatile fluorides formed from the oxides of niobium, molybdenum, ruthenium, tellurium, uranium, and neptunium. We also demonstrated near-quantitative removal of uranium from plutonium in a mixed oxide.

Scheele, Randall D.; McNamara, Bruce K.; Casella, Andrew M.; Kozelisky, Anne E.

2012-05-01T23:59:59.000Z

444

Evolution of Photosynthesis and Biospheric Oxygenation Contingent Upon Nitrogen Fixation?  

E-Print Network (OSTI)

How photosynthesis by Precambrian cyanobacteria oxygenated Earth's biosphere remains incompletely understood. Here it is argued that the oxic transition, which took place between approximately 2.3 and 0.5 Gyr ago, required a great proliferation of cyanobacteria, and this in turn depended on their ability to fix nitrogen via the nitrogenase enzyme system. However, the ability to fix nitrogen was not a panacea, and the rate of biospheric oxygenation may still have been affected by nitrogen constraints on cyanobacterial expansion. Evidence is presented for why cyanobacteria probably have a great need for fixed nitrogen than other prokaryotes, underscoring the importance of their ability to fix nitrogen. The connection between nitrogen fixation and the evolution of photosynthesis is demonstrated by the similarities between nitrogenase and enzymes critical for the biosynthesis of (bacterio)chlorophyll. It is hypothesized that biospheric oxygenation would not have occurred if the emergence of cyanobacteria had not ...

Grula, J W

2006-01-01T23:59:59.000Z

445

Strengthening of metallic alloys with nanometer-size oxide dispersions  

DOE Patents (OSTI)

Austenitic stainless steels and nickel-base alloys containing, by wt. %, 0.1 to 3.0% V, 0.01 to 0.08% C, 0.01 to 0.5% N, 0.05% max. each of Al and Ti, and 0.005 to 0.10% O, are strengthened and ductility retained by atomization of a metal melt under cover of an inert gas with added oxygen to form approximately 8 nanometer-size hollow oxides within the alloy grains and, when the alloy is aged, strengthened by precipitation of carbides and nitrides nucleated by the hollow oxides. Added strengthening is achieved by nitrogen solid solution strengthening and by the effect of solid oxides precipitated along and pinning grain boundaries to provide temperature-stabilization and refinement of the alloy grains.

Flinn, John E. (Idaho Falls, ID); Kelly, Thomas F. (Madison, WI)

1999-01-01T23:59:59.000Z

446

Strengthening of metallic alloys with nanometer-size oxide dispersions  

DOE Patents (OSTI)

Austenitic stainless steels and nickel-base alloys containing, by wt. %, 0.1 to 3.0% V, 0.01 to 0.08% C, 0.01 to 0.5% N, 0.05% max. each of Al and Ti, and 0.005 to 0.10% O, are strengthened and ductility retained by atomization of a metal melt under cover of an inert gas with added oxygen to form approximately 8 nanometer-size hollow oxides within the alloy grains and, when the alloy is aged, strengthened by precipitation of carbides and nitrides nucleated by the hollow oxides. Added strengthening is achieved by nitrogen solid solution strengthening and by the effect of solid oxides precipitated along and pinning grain boundaries to provide temperature-stabilization and refinement of the alloy grains. 20 figs.

Flinn, J.E.; Kelly, T.F.

1999-06-01T23:59:59.000Z

447

Reductions of NO{sub x} emissions on oil and gas firing at Bowline Unit 1  

SciTech Connect

In response to the NYSDEC, Part 227 regulations for the emissions of nitrogen oxides (NO{sub x}), Orange and Rockland Utilities, Inc. (ORU) and Burns & Roe Company (BRC) evaluated the options available to reduce the NO{sub x} emissions at two oil and gas fired units at Bowline Point Generating Station. Replacement of all of the existing burners with new low NO{sub x} burners and possibly overfire air ports presents the most costly method of achieving this goal. Therefore, other methods of NO{sub x} reduction were considered including utilizing some form of off-stoichiometric, burners out of service (BOOS), firing. It was determined that the stringent emission limits could be met utilizing off-stoichiometric firing techniques. New oil gun atomizer tips allowing off-stoichiometric firing with mechanical atomization and swirlers of a new design are replacing the existing atomizers. The new hardware eliminates the problems of opacity while operating with off-stoichiometric firing.

Paschedag, A.E.; Martinsen, R.A.; O`Sullivan, R.C.; Schmidt, D.W. [and others

1996-01-01T23:59:59.000Z

448

Increasing Price of Nitrogen Nitrogen fertilizer is often the largest contributor to the  

E-Print Network (OSTI)

events; the distribution of more than 5,700 publications; and access to web-based guidance on deep and associated costs. Since 2007, the importance of deep-soil testing for nitrogen management has been-sampling methods and procedures. Economic and Environmental Impact The economic impact of deep-soil testing

449

Effect of Nitrogen Additives on Flame Retardant Action of Tributyl...  

NLE Websites -- All DOE Office Websites (Extended Search)

of tributyl phosphate (TBP) has been investigated. From the LOI tests on treated cotton it is clear that the nitrogen additives have synergistic action. Estimation of...

450

Nitrogen-Doped Graphene and its Application in Electrochemical...  

NLE Websites -- All DOE Office Websites (Extended Search)

Doped Graphene and its Application in Electrochemical Biosensing. Nitrogen-Doped Graphene and its Application in Electrochemical Biosensing. Abstract: Chemical doping with foreign...

451

Flexible, integrated NGL recovery/nitrogen rejection systems  

SciTech Connect

As the oil and gas industry uses nitrogen to recover more of the expensive hydrocarbons below the ground, there is a need for gas processing facilities above the ground that can efficiently and effectively handle the nitrogen coproduced with the hydrocarbon stream. Some of the key general economic variables that must be considered when evaluating proposed nitrogen rejection projects are reviewed. This work discusses the design of the nitrogen/ natural gas processing facilities. It also reviews these process specific criteria and examines some pertinent examples of process design and equipment selection features, which provide the flexibility and integration required to meet the demands of these interrelated driving forces.

Browne, L.W.; Aberle, J.L.

1983-01-01T23:59:59.000Z

452

Absorption of Foliar-Applied Nitrogen by Cotton  

E-Print Network (OSTI)

wax, and nitrogen-15 absorption. Crop Science 37:807-811.water- deficit stress, and the absorption of foliar-appliedgrowth favorable for N absorption and translocation. Four

Oosterhuis, Derrick M

2009-01-01T23:59:59.000Z

453

Introduction Ammonium is the most reduced form of inorganic nitrogen  

E-Print Network (OSTI)

144 Introduction Ammonium is the most reduced form of inorganic nitrogen in seawater time. Uncertainties result from a com- bination of factors including: sample storage effects, contami

454

Thermal bubble behaviour in liquid nitrogen under electric fields.  

E-Print Network (OSTI)

??This thesis describes thermally induced bubble behaviour changes in liquid nitrogen (LN2) under electric fields. Cryogenic liquids such as LN2 have been used not only… (more)

Wang, Ping

2008-01-01T23:59:59.000Z

455

Comparison of the Catalytic Oxidation Reaction on Graphene Oxide and Reduced Graphene Oxide  

E-Print Network (OSTI)

Comparison of the Catalytic Oxidation Reaction on Graphene Oxide and Reduced Graphene Oxide Laboratory (PAL), Pohang 790-784, Republic of Korea ABSTRACT: The capacities of graphene oxide (GO) and reduced graphene oxide (rGO) films grown on silicon substrate to cause the aniline to azobenzene oxidation

Kim, Sehun

456

Effect of nitrogen incorporation on improvement of leakage properties in high-k HfO{sub 2} capacitors treated by N{sub 2}-plasma  

SciTech Connect

The nitrogen incorporation into the HfO{sub 2} films with an EOT (equivalent oxide thickness) of 9 A was performed by N{sub 2}-plasma to improve the electrical properties. The dielectric properties and a leakage current characteristics of the capacitors were investigated as a function of plasma power and plasma treatment temperature. The dielectric constant of the capacitors is not influenced by nitrogen incorporation. The N{sub 2}-plasma treatment at 300 deg. C and 70 W exhibits the most effective influence on improvement of the leakage current characteristics. Leakage current density of the capacitors treated at 300 deg. C and 70 W exhibits a half order of magnitude lower than that without plasma treatment. Nitrogen incorporated into the HfO{sub 2} films possesses the intrinsic effect that drastically reduce the electron leakage current through HfO{sub 2} dielectrics by deactivating the V{sub O} (oxygen vacancy) related gap states.

Seong, Nak-Jin; Yoon, Soon-Gil; Yeom, Seung-Jin; Woo, Hyun-Kyung; Kil, Deok-Sin; Roh, Jae-Sung; Sohn, Hyun-Chul [Department of Materials Science and Engineering, Chungnam National University, Daeduk Science Town, 305-764, Daejon (Korea, Republic of); Hynix Semiconductor Inc., San 136-1 Ami-ri Bubal-eub Icheon-si Kyoungki-do, 467-701 (Korea, Republic of)

2005-09-26T23:59:59.000Z

457

Continuous improvement in nitrogen rejection unit design  

SciTech Connect

The design and fabrication of Nitrogen Rejection Units (NRU) has advanced considerably over the past 15 years. Improvements have been made in all aspects of producing an NRU plant and cold box. This paper presents the primary areas involved that have seen these improvements. (1) Process design: the two-column process has been superseded by an approach which utilizes multiple flash drums and one column. This leads to a smaller and lower cost cold box. With low nitrogen content feeds, the prefractionater recovers half the methane as a high pressure residue gas and reduces the cold box size. (2) Mechanical Design: improved software enables the design process to be more accurate, eliminate piping and equipment interferences, reduce the size of the box and save design time. (3) Manufacturing: the interfacing of the 3D software design tools and the manufacturing process enables the shop floor personnel to reduce the manufacturing time by 10%. All of these individual improvements have reduced the real cost of an NRU substantially over the past 15 years.

O`Brien, J.V. [Process Systems International, Inc., Westborough, MA (United States); Maloney, J.J. [Praxair, Inc., Tonawanda, NY (United States)

1997-12-31T23:59:59.000Z

458

Oxidation Resistant Graphite Studies  

SciTech Connect

The Very High Temperature Reactor (VHTR) Graphite Research and Development Program is investigating doped nuclear graphite grades exhibiting oxidation resistance. During a oxygen ingress accident the oxidation rates of the high temperature graphite core region would be extremely high resulting in significant structural damage to the core. Reducing the oxidation rate of the graphite core material would reduce the structural effects and keep the core integrity intact during any air-ingress accident. Oxidation testing of graphite doped with oxidation resistant material is being conducted to determine the extent of oxidation rate reduction. Nuclear grade graphite doped with varying levels of Boron-Carbide (B4C) was oxidized in air at nominal 740°C at 10/90% (air/He) and 100% air. The oxidation rates of the boronated and unboronated graphite grade were compared. With increasing boron-carbide content (up to 6 vol%) the oxidation rate was observed to have a 20 fold reduction from unboronated graphite. Visual inspection and uniformity of oxidation across the surface of the specimens were conducted. Future work to determine the remaining mechanical strength as well as graphite grades with SiC doped material are discussed.

W. Windes; R. Smith

2014-07-01T23:59:59.000Z

459

Coal-fired power generation: Proven technologies and pollution control systems  

SciTech Connect

During the last two decades, significant advances have been made in the reduction of emissions from coal-fired power generating plants. New technologies include better understanding of the fundamentals of the formation and destruction of criteria pollutants in combustion processes (low nitrogen oxides burners) and improved methods for separating criteria pollutants from stack gases (FGD technology), as well as efficiency improvements in power plants (clean coal technologies). Future demand for more environmentally benign electric power, however, will lead to even more stringent controls of pollutants (sulphur dioxide and nitrogen oxides) and greenhouse gases such as carbon dioxide.

Balat, M. [University of Mah, Trabzon (Turkey)

2008-07-01T23:59:59.000Z

460

Environmental monitoring for the DOE coolside and LIMB demonstration extension projects  

SciTech Connect

The purpose of this document is to present environmental monitoring data collected during the US DOE Limestone Injection Multistage Burner (LIMB) Demonstration Project Extension. The objective of the LIMB program is to demonstrate the sulfur dioxide (SO{sub 2}) and nitrogen oxide (NO{sub x}) emission reduction capabilities of the LIMB system. The LIMB system is a retrofit technology to be used for existing coal-fired boilers equipped with electrostatic precipitators. (VC)

White, T.; Contos, L.; Adams, L. (Radian Corp., Research Triangle Park, NC (United States). Progress Center)

1992-02-01T23:59:59.000Z

Note: This page contains sample records for the topic "nitrogen oxide burner" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Environmental monitoring for the DOE coolside and LIMB demonstration extension projects. Quarterly report for the period of February, March and April 1991  

SciTech Connect

The purpose of this document is to present environmental monitoring data collected during the US DOE Limestone Injection Multistage Burner (LIMB) Demonstration Project Extension. The objective of the LIMB program is to demonstrate the sulfur dioxide (SO{sub 2}) and nitrogen oxide (NO{sub x}) emission reduction capabilities of the LIMB system. The LIMB system is a retrofit technology to be used for existing coal-fired boilers equipped with electrostatic precipitators. (VC)

White, T.; Contos, L.; Adams, L. [Radian Corp., Research Triangle Park, NC (United States). Progress Center

1992-02-01T23:59:59.000Z

462

METAL OXIDE NANOPARTICLES  

SciTech Connect

This chapter covers the fundamental science, synthesis, characterization, physicochemical properties and applications of oxide nanomaterials. Explains fundamental aspects that determine the growth and behavior of these systems, briefly examines synthetic procedures using bottom-up and top-down fabrication technologies, discusses the sophisticated experimental techniques and state of the art theory results used to characterize the physico-chemical properties of oxide solids and describe the current knowledge concerning key oxide materials with important technological applications.

FERNANDEZ-GARCIA,M.; RODGRIGUEZ, J.A.

2007-10-01T23:59:59.000Z

463

Solubility of Nitrogen in Water at High Pressures and Temperatures  

Science Journals Connector (OSTI)

Gas Solubility Measurement and Modeling for the Nitrogen + Water System from 274.18 K to 363.02 K ... Two recent events allow a more detailed picture of the solubility of hydrogen, nitrogen, oxygen, and the noble gases in water to be given, than could have been given even a year ago. ...

John B. Goodman; Norman W. Krase

1931-01-01T23:59:59.000Z