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1

Reactivity of tributyl phosphate degradation products with nitric acid: Relevance to the Tomsk-7 accident  

SciTech Connect (OSTI)

The reaction of a degraded tributyl phosphate (TBP) solvent with nitric acid is thought to have caused the chemical explosion at the Tomsk-7 reprocessing plant at Tomsk, Russia in 1993. The estimated temperature of the organic layer was not high eneough to cause significant reaction of nitric acid with TBP or hydrocarbon diluent compounds. A more reactive organic compound was likely present in the organic layer that reacted with sufficient heat generation to raise the temperature to the point where an autocatalytic oxidation of the organic solvent was initiated. Two of the most likely reactive compounds that are present in degraded TBP solvents are n-butanol and n-butyl nitrate. The reactions of these compounds with nitric acid are the subject of this study. The objective of laboratory-scale tests was to identify chemical reactions that occur when n-butanol and n-butyl nitrate contact heated nitric acid solutions. Reaction products were identified and quantitified, the temperatures at which these reactions occur and heats of reaction were measured, and reaction variables (temperature, nitric acid concentration, organic concentration, and reaction time) were evaluated. Data showed that n-butyl nitrate is less reactive than n-butanol. An essentially complete oxidation reaction of n-butanol at 110-120 C produced four major reaction products. Mass spectrometry identified the major inorganic oxidation products for both n-butanol and n-butyl nitrate as nitric oxide and carbon dioxide. Calculated heats of reaction for n-butanol and n-butyl nitrate to form propionic acid, a major reaction product, are -1860 cal/g n-butanol and -953 cal/g n-butyl nitrate. These heats of reaction are significant and could have raised the temperature of the organic layer in the Tomsk-7 tank to the point where autocatalytic oxidation of other organic compounds present resulted in an explosion.

Barney, G.S.; Cooper, T.D. [Westinghouse Hanford Company, Richland, WA (United States)

1995-12-31T23:59:59.000Z

2

Solar fuels and chemicals system design study (ammonia/nitric acid production process). Volume 2. Conceptual design. Final report  

SciTech Connect (OSTI)

As part of the Solar Central Receiver Fuels and Chemicals Program, Foster Wheeler Solar Development Corporation (FWSDC), under contract to Sandia National Laboratories-Livermore (SNLL), developed a conceptual design of a facility to produce ammonia and nitric acid using solar energy as the principal external source of process heat. In the selected process, ammonia is produced in an endothermic reaction within a steam methane (natural gas) reformer. The heat of reaction is provided by molten carbonate salt heated by both a solar central receiver and an exothermic ammonia-fired heater. After absorption by water, the product of the latter reaction is nitric acid.

Not Available

1986-06-01T23:59:59.000Z

3

A Pulse Radiolysis Investigation of the Reactions of Tributyl Phosphate with the Radical Products of Aqueous Nitric Acid Irradiation  

SciTech Connect (OSTI)

Tributyl phosphate (TBP) is the most common organic compound used in liquid-liquid separations for the recovery of uranium, neptunium, and plutonium from acidic nuclear fuel dissolutions. The goal of these processes is to extract the actinides while leaving fission products in the acidic, aqueous, phase. However, the radiolytic degradation of TBP has been shown to reduce the separation factors for fission products, and to impede the back-extraction of the actinides during stripping. As most previous investigations of the radiation chemistry of TBP have focused on steady state radiolysis and stable product identification, with dibutylphosphoric acid (HDBP) invariably being the major product, here we have determined room temperature rate constants for the reactions TBP and HDBP with the hydroxyl radical ((5.00 +/- 0.02) x 109, (4.40 +/- 0.10) x 109), hydrogen atom ((1.8 +/- 0.2) x 108, (1.1 +/- 0.1) x 108), nitrate radical ((4.3 +/- 0.7) x 106, (2.9 +/- 0.2) x 106) and nitrite radical (< 2 x 105, < 2 x 105) M-1 s-1 with TBP and HDBP, respectively. These data are used to discuss the mechanism of TBP radical-induced degradation.

Bruce J. Mincher; Stephen R. Mezyk; Leigh R. Martin

2008-07-01T23:59:59.000Z

4

Separation of americium and europium from solutions of nitric and perchloric acid using dipicolinic acid diamides  

Science Journals Connector (OSTI)

Extraction of nitric acid, perchloric acid, americium, and europium with dialkyldiarylamides of 2,6-pyridinecarboxylic (dipicolinic) acid in polar fluorinated solvents (diluents) was analysed. Among the extrac...

M.Yu. Alyapyshev; V. A. Babain; I. V. Smirnov…

2006-01-01T23:59:59.000Z

5

Separation of americium and europium from solutions of nitric and perchloric acid using dipicolinic acid diamides  

Science Journals Connector (OSTI)

Extraction of nitric acid, perchloric acid, americium, and europium with dialkyldiarylamides of 2,6-pyridinecarboxylic (dipicolinic) acid in polar fluorinated solvents (diluents) was analysed. Among the extrac...

M. Yu. Alyapyshev; V. A. Babain; I. V. Smirnov…

2006-12-01T23:59:59.000Z

6

EFFECTS OF NITRIC ACID ON CRITICALITY SAFETY ANALYSIS  

SciTech Connect (OSTI)

As nitric acid molarity is increased, there are two competing phenomena affecting the reactivity of the system. First, there is interaction between each of the 10 wells in the basket-like insert. As the molarity of the nitric acid solution is increased (it moves from 100% water to 100% HNO{sub 3}), the hydrogen atom density decreases by about 80%. However, it remains a relatively efficient moderator. The moderating ratio of nitric acid is about 90% that of water. As the media between the wells is changed from 100% water to 100% nitric acid, the density of the media increases by 50%. A higher density typically leads to a better reflector. However, when the macroscopic scattering cross sections are considered, nitric acid is a much worse reflector than water. The effectiveness of nitric acid as a reflector is about 40% that of water. Since the media between the wells become a worse reflector and still remains an effective moderator, interaction between the wells increases. This phenomenon will cause reactivity to increase as nitric acid molarity increases. The seond phenomenon is due to the moderating ratio changing in the high concentration fissile-nitric acid solution in the 10 wells. Since the wells contain relatively small volumes of high concentration solutions, a small decrease in moderating power has a large effect on reactivity. This is due to the fact that neutrons are more likely to escape the high concentration fissile solution before causing another fission event. The result of this phenomenon is that as nitric acid molarity increases, reactivity decreases. Recent studies have shown that the second phenomenon is indeed the dominating force in determining reactivity changes in relation to nitric acid molarity changes. When considering the system as a whole, as nitric acid molarity increases, reactivity decreases.

Williamson, B.

2011-08-18T23:59:59.000Z

7

Use of extractive distillation to produce concentrated nitric acid  

SciTech Connect (OSTI)

Concentrated nitric acid (> 95 wt %) is needed for the treatment of off-gases from a fuels-reprocessing plant. The production of concentrated nitric acid by means of extractive distillation in the two-pot apparatus was studied to determine the steady-state behavior of the system. Four parameters, EDP volume (V/sub EDP/) and temperature (T/sub EDP/), acid feed rate, and solvent recycle, were independently varied. The major response factors were percent recovery (CPRR) and product purity (CCP). Stage efficiencies also provided information about the system response. Correlations developed for the response parameters are: CPRR = 0.02(V/sub EDP/ - 800 cc) + 53.5; CCP = -0.87 (T/sub EDP/ - 140/sup 0/C) + 81; eta/sub V,EDP/ = 9.1(F/sub feed/ - 11.5 cc/min) - 0.047(V/sub EDP/ - 800 cc) - 2.8(F/sub Mg(NO/sub 3/)/sub 2// - 50 cc/min) + 390; and eta/sub L,EDP/ = 1.9(T/sub EDP/ - 140/sup 0/C) + 79. A computer simulation of the process capable of predicting steady-state conditions was developed, but it requires further work.

Campbell, P.C.; Griffin, T.P.; Irwin, C.F.

1981-04-01T23:59:59.000Z

8

Chemistry of tributyl phosphate and nitric acid at constant volume  

SciTech Connect (OSTI)

This paper addresses the reaction of tributyl phosphate (TBP) with nitric acid (HNO{sub 3}). The reaction pressure of TBP/HNO{sub 3} mixtures as a function of time was measured under constant volume. A simplified model, which parametrically includes autocatalysis, was used to plot the total gas production of the reaction as a function of time. Comparison of the functions shows a rough equivalence in the induction time, reaction time, and total gas production. Predictions of the amounts of reaction products as a function of time were made based on assumptions regarding autocatalysis and using rate constants from experimental data. The derived reaction mechanisms and experimental results have several implications. Tests with a large amount of venting and high surface to volume ratio will show very different behavior than tests with increasing confinement and low surface to volume ratios. The amount alkyl nitrate, carbon monoxide, or hydrogen that reacts within the organic phase is limited by their solubilities and volatilities. The overall yield of both heat and gas per mol of nitric acid or TBP will vary significantly depending on the amount of solution, free volume, and vessel vent capacity.

Agnew, S.F.; Eisenhawer, S.W.; Morris, J.S. [Los Alamos National Lab., NM (United States)

1995-12-31T23:59:59.000Z

9

Extraction of nitric acid, uranyl nitrate, and bismuth nitrate from aqueous nitric acid solutions with CMPO  

SciTech Connect (OSTI)

DOE sponsored development of the transuranium extraction (TRUEX) process for removing actinides from radioactive wastes. The solvent is a mixture of CMPO and TBP. Since the extraction characteristics of CMPO are not as well understood as those of TBP, the extraction of nitric acid, uranyl nitrate, and bismuth nitrate with CMPO (dissolved in n-dodecane) were studied. Results indicate that CMPO extracts nitric acid with a 1:1 stoichiometry; equilibrium constant is 2. 660{plus_minus}0.092 at 25 C, and extraction enthalpy is -5. 46{plus_minus}0.46 kcal/mol. Slope analysis indicates that uranyl nitrate extracts with a mixed equilibria of 1:1 and 2:1 stoichiometries in nearly equal proportion. Equil. constant of the 2: 1 extraction was 1.213 {times} 10{sup 6}{plus_minus}3.56 {times} 10{sup 4} at 25 C; reaction enthalpy was -9.610{plus_minus}0.594 kcal/mol. Nitration complexation constant is 8.412{plus_minus}0.579, with an enthalpy of -10.72{plus_minus}1.87 kcal/mol. Bismuth nitrate also extracts with a mixed equilibria of (perhaps) 1:1 and 2:1 stoichiometries. A 2:1 extraction equilibrium and a nitrate complexation adequately model the data. Kinetics and enthalpies were also measured.

Spencer, B.B.

1995-08-01T23:59:59.000Z

10

Control of nitric acid plant stack opacity during start-up and shutdown  

SciTech Connect (OSTI)

This patent describes an improvement in a process for the production of nitric acid wherein air and ammonia are mixed and combusted in an ammonia burner to produce an effluent containing nitrogen oxides. The effluent is cooled, condensed and separated into a liquid weak acid stream and gas stream. The liquid weak acid and vapor streams are fed into an absorber tower wherein they are countercurrently contacted with water to produce a nitric acid stream and an overhead with a reduced nitrogen oxides content. The overhead is combusted with a fuel in the presence of a catalyst in a catalytic combustor to produce a combustor exhaust, work expanded in an expander to recover energy and vented to the atmosphere as stack exhaust. The improvement involves controlling the opacity of the stack opacity during shutdown of the process.

Adams, J.B.; Gasper, J.A.; Stash, P.J.

1989-09-26T23:59:59.000Z

11

Mercury-free dissolution of aluminum-clad fuel in nitric acid  

DOE Patents [OSTI]

A mercury-free dissolution process for aluminum involves placing the aluminum in a dissolver vessel in contact with nitric acid-fluoboric acid mixture at an elevated temperature. By maintaining a continuous flow of the acid mixture through the dissolver vessel, an effluent containing aluminum nitrate, nitric acid, fluoboric acid and other dissolved components are removed.

Christian, Jerry D. (Idaho Falls, ID); Anderson, Philip A. (Pocatello, ID)

1994-01-01T23:59:59.000Z

12

Extraction of antimony from nitric acid solutions using tributyl phosphate. I. Tributyl phosphate-antimony(III)-nitric acid system  

SciTech Connect (OSTI)

Experimental data have been reported concerning the extraction of trivalent antimony from nitric acid solutions using tributyl phosphate (TBP). A possible mechanism for the extraction of antimony(III) has been determined and the (pre)concentration constant for the process has been calculated. The effect of temperature on trivalent antimony extraction has also been evaluated. The enthalpy value and standard isobar potential and entropy for this process have been determined.

Lakaev, V.S.; Smelov, V.S.

1989-01-01T23:59:59.000Z

13

Extraction of antimony from nitric acid solutions using tributyl phosphate. II. Tributyl phosphate-antimony(V)-nitric acid system  

SciTech Connect (OSTI)

The extraction of pentavalent antimony from nitric acid solutions using tributyl phosphate has been investigated. A possible mechanism for the extraction of antimony(V) has been determined and the (pre)concentration constant for the process has been calculated. The composition of the extracted antimony(V) complex has been deduced. A negative effect of temperature on the distribution coefficient for antimony(V) has also been demonstrated.

Lakaev, V.S.; Smelov, V.S.

1989-01-01T23:59:59.000Z

14

Nitric-phosphoric acid oxidation of organic waste materials  

SciTech Connect (OSTI)

A wet chemical oxidation technology has been developed to address issues facing defense-related facilities, private industry, and small-volume generators such as university and medical laboratories. Initially tested to destroy and decontaminate a heterogenous mixture of radioactive-contaminated solid waste, the technology can also remediate other hazardous waste forms. The process, unique to Savannah River, offers a valuable alternative to incineration and other high-temperature or high-pressure oxidation processes. The process uses nitric acid in phosphoric acid; phosphoric acid allows nitric acid to be retained in solution well above its normal boiling point. The reaction converts organics to carbon dioxide and water, and generates NO{sub x} vapors which can be recycled using air and water. Oxidation is complete in one to three hours. In previous studies, many organic compounds were completely oxidized, within experimental error, at atmospheric pressure below 180{degrees}C; more stable compounds were decomposed at 200{degrees}C and 170 kPa. Recent studies have evaluated processing parameters and potential throughputs for three primary compounds: EDTA, polyethylene, and cellulose. The study of polyvinylchloride oxidation is incomplete at this time.

Pierce, R.A.; Smith, J.R.

1995-11-01T23:59:59.000Z

15

Isothermal heat measurements of TBP-nitric acid solutions  

SciTech Connect (OSTI)

Net heats of reaction were measured in an isothermal calorimeter for both single phase (organic) and two phase (organic and aqueous) TBP/HNO{sub 3} reacting solutions at temperatures above 100 C. The oxidation rate constant was determined to be 5.4E-4 min{sup {minus}1} at 110 C for an open ``vented`` system as compared to 1.33 E-3 min{sup {minus}1} in the closed system. The heat released per unit material oxidized was also reduced. The oxidation in both phases was found to be first order in nitric acid and pseudo-zero order in butylnitrate and water. The hydrolysis (esterification) rate constant determined by Nichols` (1.33E-3 min{sup {minus}1}) fit the experimental data from this work well. Forced evaporation of the volatile components by the product gases from oxidation resulted in a cooling mechanism which more than balanced the heat from the oxidation reaction in the two-phased systems. Rate expressions were derived and rate constants determined for both the single and two phase systems. An approximating mathematical model was developed to fit the experimental data and to extrapolate beyond the experimental conditions. This model shows that one foot of ``reacting`` 14.3M HNO{sub 3} aqueous phase solution at 121 C will transport sufficient water to the organic phase to replace evaporative losses, maintaining endothermicity, for organic layers up to 12.2 + 6.0 feet deep. If the pressure in a reacting system is allowed to increase due to insufficient venting the temperature of the organic phase would increase in temperature to reach a new equilibrium. The rate of oxidation would increase not only due to the increase in temperature but also from the increased concentration of dissolved HNO{sub 3} reduction products. Another important factor is that the cooling system described in this work becomes less effective as the total pressure increases. These factors probably contributed to the explosion at Tomsk.

Smith, J.R.; Cavin, W.S.

1994-12-16T23:59:59.000Z

16

FY13 GLYCOLIC-NITRIC ACID FLOWSHEET DEMONSTRATIONS OF THE DWPF CHEMICAL PROCESS CELL WITH SIMULANTS  

SciTech Connect (OSTI)

Savannah River Remediation is evaluating changes to its current Defense Waste Processing Facility flowsheet to replace formic acid with glycolic acid in order to improve processing cycle times and decrease by approximately 100x the production of hydrogen, a potentially flammable gas. Higher throughput is needed in the Chemical Processing Cell since the installation of the bubblers into the melter has increased melt rate. Due to the significant maintenance required for the safety significant gas chromatographs and the potential for production of flammable quantities of hydrogen, eliminating the use of formic acid is highly desirable. Previous testing at the Savannah River National Laboratory has shown that replacing formic acid with glycolic acid allows the reduction and removal of mercury without significant catalytic hydrogen generation. Five back-to-back Sludge Receipt and Adjustment Tank (SRAT) cycles and four back-to-back Slurry Mix Evaporator (SME) cycles were successful in demonstrating the viability of the nitric/glycolic acid flowsheet. The testing was completed in FY13 to determine the impact of process heels (approximately 25% of the material is left behind after transfers). In addition, back-to-back experiments might identify longer-term processing problems. The testing was designed to be prototypic by including sludge simulant, Actinide Removal Product simulant, nitric acid, glycolic acid, and Strip Effluent simulant containing Next Generation Solvent in the SRAT processing and SRAT product simulant, decontamination frit slurry, and process frit slurry in the SME processing. A heel was produced in the first cycle and each subsequent cycle utilized the remaining heel from the previous cycle. Lower SRAT purges were utilized due to the low hydrogen generation. Design basis addition rates and boilup rates were used so the processing time was shorter than current processing rates.

Lambert, D.; Zamecnik, J.; Best, D.

2014-03-13T23:59:59.000Z

17

Analysis of Steam Heating of a Two-Layer TBP/N-Paraffin/Nitric Acid Mixtures  

SciTech Connect (OSTI)

This report presents an analysis of steam heating of a two-layer tri-n-butyl phosphate (TBP)/n-paraffin-nitric acid mixture.The purpose of this study is to determine if the degree of mixing provided by the steam jet or by bubbles generated by the TBP/nitric acid reaction is sufficient to prevent a runaway reaction.

Laurinat, J.E. [Westinghouse Savannah River Company, AIKEN, SC (United States); Hassan, N.M.; Rudisill, T.S.; Askew, N.M.

1998-07-22T23:59:59.000Z

18

Effect of the TBP and Water on the Complexation of Uranyl Nitrate and the Dissolution of Nitric Acid into Supercritical CO2. A Theoretical Study  

E-Print Network [OSTI]

started from "random" mixtures of water, TBP, nitric acid, and uranyl nitrate, complexation of uranyl to dissolve nitric acid in the supercritical phase. Indeed, without TBP, nitric acid alone self aggregates via containing the acid and uranyl salts. The simulations show that a high TBP/nitric acid ratio is needed

Boyer, Edmond

19

Scandium nitrate-nitric acid-water-tributyl phosphate system. III. IR spectra of scandium extracts from concentrated nitric acid solutions  

SciTech Connect (OSTI)

Equilibrium organic phases in extraction systems consisting of tributyl phosphate (TBP) (neat or 1 M in CCl{sub 4}) and 8-12 M nitric acid containing scandium or scandium-free have been studied by IR spectroscopy. Extracted complex contains 3, 4, or 5 nitric acid molecules per Sc atom in the case of extraction from 8.3, 10.9, and 12.2 M HNO{sub 3}, respectively, and corresponds to the formula Sc(NO{sub 3}){sub 3}{center_dot}mHNO{sub 3}{center_dot}3TBP. Nitric acid molecules are incorporated into extracted complex via H-bond between oxygen atom of coordinated nitrate ion and acid proton.

Nikitina, G.P.; Egorova, V.P.; Listopadov, A.A. [Khlopin Radium Institute, St. Petersburg (Russian Federation)] [and others

1995-03-01T23:59:59.000Z

20

Features of gadolinium and ytterbium extraction by tributyl phosphate from concentrated nitric acid solutions. I. Compositions of extracted complexes  

SciTech Connect (OSTI)

Distribution of macroquantity (0.3-1.3 M) of Gd and Yb between neat tri-n-butyl phosphate (TBP) and 5-12 M nitric acid solutions has been studied. The species extracted by TBP from 7-12 M nitric acid solutions are rare-earth metal (REM) nitrate trisolvates containing one or several nitric molecules.

Nikitna, G.P.; Seredkina, N.V.; Listopadov, A.A. [Khlopin Radium Institute, St. Petersburg (Russian Federation)

1995-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "nitric acid production" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Amino acids, polyamines, and nitric oxide synthesis in the ovine conceptus  

E-Print Network [OSTI]

The objective of this study was to determine concentrations of amino acids and polyamines as well as nitric oxide (NO) and polyamine synthesis in the ovine conceptus (embryo/fetal and associated placental membrane). Ewes were hysterectomized...

Kwon, Hyuk Jung

2005-08-29T23:59:59.000Z

22

THE SYSTEM THORIUM NITRATE-WATER-NITRIC ACID AT 25 AND THE HYDRATES...  

Office of Scientific and Technical Information (OSTI)

SYSTEM THORIUM NITRATE-WATER-NITRIC ACID AT 25 AND THE HYDRATES OF THORIUM NITRATE Re-direct Destination: Temp Data Fields Ferraro, J.R.; Katzin, L.I. Temp Data Storage 3: Argonne...

23

Isothermal heat measurements of TBP-nitric acid solutions  

SciTech Connect (OSTI)

Net heats of reaction were measured in an isothermal calorimeter for TBP/HNO{sub 3} solutions at ambient pressure and temperatures above 100{degrees}C. Carbon and nitrogen balances were performed giving the reaction stoichiometry. Rate expressions were derived and rate constants determined for both the single and two phase systems which included mass lost from the reacting system by evaporation. This mathematical model was fit to the experimental data (including the measured net heat and off-gas rate) gathered over a wide range of conditions. The oxidation rate constant was determined to be 5.4E-4 min{sup -1} at 110{degrees}C for an open {open_quotes}vented{close_quotes} system as compared to >1E-3min{sup -1} in a closed system. The heat released per unit material oxidized was also reduced due to a decrease in dissolved oxidants and an inefficient reduction of HNO{sub 3}. Oxidation in the organic phase was found to be first order in nitric acid and pseudo-zero order in butylnitrate and water.

Smith, J.R.; Cavin, W.S. [Westinghouse Savannah River Company, Aiken, SC (United States)

1995-12-31T23:59:59.000Z

24

Oxyfuel CO2 compression: The gas phase reaction of elemental mercury and \\{NOx\\} at high pressure and absorption into nitric acid  

Science Journals Connector (OSTI)

Abstract Oxyfuel combustion is a technology which combusts coal in oxygen and recycled flue gas, producing a carbon dioxide rich flue gas for sequestration. Oxyfuel flue gas contains trace amounts of elemental mercury, which may corrode brazed aluminium heat exchangers used in the carbon dioxide purification system. International gas vendors have tested the use of the compression system to remove other flue gas impurities such as NOx; however, the reaction mechanism of mercury and its reaction products with \\{NOx\\} and nitric acid formed with condensed water vapour are unclear. This study used lab scale experiments to study the absorption of gaseous elemental mercury into nitric acid and the gas phase reaction between mercury and nitrogen dioxide formed from oxidised NO at pressures up to 25 bar. It was observed that mercury has limited absorption into nitric acid and may partially desorb out of solution after depressurisation. On the other hand, mercury reacted readily with nitrogen dioxide (formed from nitric oxide oxidation at high pressure) in the gas phase. These gas phase reactions from the oxidation of nitric oxide to nitrogen dioxide to the subsequent oxidation of elemental mercury by nitrogen dioxide were predicted using existing global kinetic equations. The limited absorption of gaseous elemental mercury in nitric acid and significant oxidation of gaseous elemental mercury by nitrogen dioxide suggests that the primary removal step for elemental mercury is through the gas phase reaction. Oxyfuel compression circuits should therefore allow sufficient residence time for this gas phase reaction to occur.

Timothy Ting; Rohan Stanger; Terry Wall

2014-01-01T23:59:59.000Z

25

Laboratory studies of 2H evaporator scale dissolution in dilute nitric acid  

SciTech Connect (OSTI)

The rate of 2H evaporator scale solids dissolution in dilute nitric acid has been experimentally evaluated under laboratory conditions in the SRNL shielded cells. The 2H scale sample used for the dissolution study came from the bottom of the evaporator cone section and the wall section of the evaporator cone. The accumulation rate of aluminum and silicon, assumed to be the two principal elemental constituents of the 2H evaporator scale aluminosilicate mineral, were monitored in solution. Aluminum and silicon concentration changes, with heating time at a constant oven temperature of 90 deg C, were used to ascertain the extent of dissolution of the 2H evaporator scale mineral. The 2H evaporator scale solids, assumed to be composed of mostly aluminosilicate mineral, readily dissolves in 1.5 and 1.25 M dilute nitric acid solutions yielding principal elemental components of aluminum and silicon in solution. The 2H scale dissolution rate constant, based on aluminum accumulation in 1.5 and 1.25 M dilute nitric acid solution are, respectively, 9.21E-04 ± 6.39E-04 min{sup -1} and 1.07E-03 ± 7.51E-05 min{sup -1}. Silicon accumulation rate in solution does track the aluminum accumulation profile during the first few minutes of scale dissolution. It however diverges towards the end of the scale dissolution. This divergence therefore means the aluminum-to-silicon ratio in the first phase of the scale dissolution (non-steady state conditions) is different from the ratio towards the end of the scale dissolution. Possible causes of this change in silicon accumulation in solution as the scale dissolution progresses may include silicon precipitation from solution or the 2H evaporator scale is a heterogeneous mixture of aluminosilicate minerals with several impurities. The average half-life for the decomposition of the 2H evaporator scale mineral in 1.5 M nitric acid is 12.5 hours, while the half-life for the decomposition of the 2H evaporator scale in 1.25 M nitric acid is 10.8 hours. Based on averaging the two half-lives from the 2H scale acid dissolution in 1.25 and 1.5 M nitric acid solutions, a reasonable half-live for the dissolution of 2H scales in dilute nitric acid is 11.7 ± 1.3 hours. The plant operational time for chemically cleaning (soaking) the 2H evaporator with dilute nitric acid is 32 hours. It therefore may require about 3 half-lives or less to completely dissolve most of the scales in the Evaporator pot which come into contact with the dilute nitric acid solution. On a mass basis, the Al-to-Si ratio for the scale dissolution in 1.5 M nitric acid averaged 1.30 ± 0.20 and averaged 1.18 ± 0.10 for the 2H scale dissolution in 1.25 M nitric acid. These aluminum-to-silicon ratios are in fairly good agreement with ratios from previous studies. Therefore, there is still more aluminum in the 2H evaporator scales than silicon which implies that there are no significant changes in scale properties which will exclude nitric acid as a viable protic solvent for aluminosilicate scale buildup dissolution from the 2H evaporator. Overall, the monitoring of the scale decomposition reaction in 1.25 and 1.5 M nitric acid may be better ascertained through the determination of aluminum concentration in solution than monitoring silicon in solution. Silicon solution chemistry may lead to partial precipitating of silicon with time as the scale and acid solution is heated.

Oji, L.

2014-09-23T23:59:59.000Z

26

Lunar and solar FTIR nitric acid measurements at Eureka in winter  

E-Print Network [OSTI]

Lunar and solar FTIR nitric acid measurements at Eureka in winter 2001/2002: comparisons acid measurements at Eureka obtained in winter 2001­2002 using solar and lunar Fourier transform Eureka (80.1°N, 86.4°W), Canada, have been made during polar night using lunar spectra recorded

Wirosoetisno, Djoko

27

Third phase formation in nitric acid extraction by n-octyl(phenyl)-n,n-diisobutylcarbamoylmethylphosphine oxide  

SciTech Connect (OSTI)

The third phase formation was studied as a function of n-octyl(phenyl)-N,N-diisobutylcarbamoylmethylphosphine oxide (CMPO) and tri-n-butyl phosphate (TBP) concentrations and temperature in the extraction of nitric acid. The concentration fractions of CMPO and TBP in the second and the third phases were determined by gas chromatography. Both CMPO and TBP were found to be enriched in the third phase. The concentrations of nitric acid in the second and the third phases relatively agreed with the calculated concentrations based on the extraction equilibrium constants of nitric acid by CMPO and TBP. The extraction of Np with the third phase formation was also discussed. 21 refs., 4 figs., 3 tabs.

Nagasaki, S.; Wisnubroto, D.S.; Enokida, Y.; Suzuki, A. (Univ. of Tokyo (Japan))

1994-03-01T23:59:59.000Z

28

Process for preparing a chemical compound enriched in isotope content. [nitrogen 15-enriched nitric acid  

DOE Patents [OSTI]

A process to prepare a chemical enriched in isotope content includes: a chemical exchange reaction between a first and second compound which yields an isotopically enriched first compound and an isotopically depleted second compound; the removal of a portion of the first compound as product and the removal of a portion of the second compound as spent material; the conversion of the remainder of the first compound to the second compound for reflux at the product end of the chemical exchange reaction region; the conversion of the remainder of the second compound to the first compound for reflux at the spent material end of the chemical exchange region; and the cycling of the additional chemicals produced by one conversion reaction to the other conversion reaction, for consumption therein. One of the conversion reactions is an oxidation reaction, and the energy that it yields is used to drive the other conversion reaction, a reduction. The reduction reaction is carried out in a solid polymer electrolyte electrolytic reactor. The overall process is energy efficient and yields no waste by-products. A particular embodiment of the process in the production of nitrogen-15-enriched nitric acid.

Michaels, E.D.

1981-02-25T23:59:59.000Z

29

Tropospheric Nitric Acid Columns from IASI Interpreted with a Chemical Transport Model Matthew Cooper1  

E-Print Network [OSTI]

1 Tropospheric Nitric Acid Columns from IASI Interpreted with a Chemical Transport Model Matthew from the IASI satellite instrument with a global chemical transport model (GEOS-Chem). GEOS the Infrared Atmospheric Sounding Interferometer (IASI) instrument on the MetOp satellite platform. IASI

Martin, Randall

30

MATERIAL COMPATIBILITY EVALUATION FOR DWPF NITRIC-GLYCOLIC ACID - LITERATURE REVIEW  

SciTech Connect (OSTI)

Glycolic acid is being evaluated as an alternative for formic and nitric acid in the DWPF flowsheet. Demonstration testing and modeling for this new flowsheet has shown that glycolic acid and glycolate has a potential to remain in certain streams generated during the production of the nuclear waste glass. A literature review was conducted to assess the impact of glycolic acid on the corrosion of the materials of construction for the DWPF facility as well as facilities downstream which may have residual glycolic acid and glycolates present. The literature data was limited to solutions containing principally glycolic acid. The reported corrosion rates and degradation characteristics have shown the following for the materials of construction. ? For C276 alloy, the primary material of construction for the CPC vessels, corrosion rates of either 2 or 20 mpy were reported up to a temperature of 93 ?C. ? For the austenitic stainless steels, 304L and 316L, variable rates were reported over a range of temperatures, varying from 2 mpy up to 200 mpy (at 100 ?C). ? For 690, G30, Allcorr, Ultimet and Stellite alloys no data were available. ? For relevant polymers where data are available, the data suggests that exposure to glycolic acid is not detrimental. The literature data had limited application to the DWPF process since only the storage and feed vessels, pumps and piping used to handle the glycolic acid are directly covered by the available data. These components are either 304L or 316L alloys for which the literature data is inconsistent (See Bullet 2 above). Corrosion rates in pure glycolic acid solutions also are not representative of the DWPF process streams. This stream is complex and contains aggressive species, i.e. chlorides, sulfates, mercury, as well as antifoaming agents which cumulatively have an unknown effect on the corrosion rates of the materials of construction. Therefore, testing is recommended to investigate any synergistic effects of the aggressive species and to verify the performance of materials in the key process vessels as well as downstream vessels and processes such as the evaporator where heating is occurring. The following testing would provide data for establishing the viability of these components. ? Electrochemical testing - evaluate the corrosion rate and susceptibility to localized corrosion within the SRAT, SME, OGCT, Quencher and Evaporator. Testing would be conducted at operational temperatures in simulants with ranges of glycolic acid, iron, chloride, sulfate, mercury, and antifoaming agents. ? Hot-wall testing – evaluate the corrosion under heat transfer conditions to simulate those for heating coils and evaporator coil surfaces. Testing would be at nominal chemistries with concentration of glycolic acid, chloride, sulfate and mercury at high expected concentrations. Some tests would be performed with antifoaming agents. ? Melter coupon testing – evaluate the performance of alloy 690 in melter feeds containing glycolic acid. This testing would be conducted as part of the melter flammability testing. ? Polymer testing – evaluate changes in polymer properties in immersion testing with DWPF simulants to provide product-specific data for service life evaluation and analyze the Hansen solubility parameters for relevant polymers in glycolic vs. formic acid. During this literature review process, the difficulties associated with measuring the liquid level in formic acid tanks were revealed. A test is recommended to resolve this issue prior to the introduction of glycolic acid into the DWPF. This testing would evaluate the feasibility of using ultrasonic inspection techniques to determine liquid level and other desirable attributes of glycolic acid in DWPF storage tanks and related equipment.

Mickalonis, J.; Skidmore, E.

2013-06-05T23:59:59.000Z

31

Measurement of Nitric Oxide Production from Lymphatic Entothelial Cells Under Mechanical Stimuli  

E-Print Network [OSTI]

mechanisms to pump lymph. Intrinsic pumping involves the active contraction of vessels, a phenomenon that is regulated in part by nitric oxide (NO) produced by lymphatic endothelial cells (LECs). NO production by arterial endothelial cells has been shown...

Jafarnejad, Mohammad 1987-

2012-11-16T23:59:59.000Z

32

Nitric oxide inhibits the production of soluble endothelin converting enzyme-1  

Science Journals Connector (OSTI)

This study examined the effect of nitric oxide on the production of soluble ECE-1. Activity of ECE-1 in media was measured using a quenched fluorescent substrate assay, and expressed as a percentage of control...

Sanjaya Kuruppu; Niwanthi W. Rajapakse…

2014-11-01T23:59:59.000Z

33

Hyperbaric oxygen and hypoxia alter production of nitric oxide by J774 murine macrophages  

E-Print Network [OSTI]

Improvements in rates of healing of wounds and bacterial clearance in infected tissue during intermittent exposure to hyperbaric oxygen (HBO) have been documented. Increased bacterial clearance may partly stem from changes in production of nitric...

Burden, Kyland Irle

2012-06-07T23:59:59.000Z

34

Suppressive effects of glucagon-like peptide-1 on interferon-?-induced nitric oxide production in insulinproducing cells is mediated by inhibition of tumor necrosis factor-? production  

Science Journals Connector (OSTI)

During the development of Type 1 diabetes, inflammatory cytokines are known to induce the expression of inducible nitric oxide synthase (iNOS) in pancreatic islets, and subsequent production of nitric oxide (N...

E. Hahm; Y. S. Lee; H. S. Jun PhD

2008-04-01T23:59:59.000Z

35

Solvent extraction of uranyl (II) ion with N,N,N,N-tetrabutylsucinylamide from nitric acid solution  

Science Journals Connector (OSTI)

N,N,N,N-tetrabutylsuccinylamide (TBSA) in a diluent composed of 50% trimethylbenzene (TMB) and 50% kerosene (OK) can extract uranyl (II) ion from nitric acid solution. The results of extraction study suggested...

You-Shao Wang; Chao-Hong Shen; Jian-Kang Zhu…

1996-01-20T23:59:59.000Z

36

Extraction behavior of trivalent lanthanides from nitric acid medium by selected structurally related diglycolamides as novel extractants  

Science Journals Connector (OSTI)

Abstract The extraction affinity of trivalent lanthanides, Ln(III), from nitric acid medium has been explored using a series of ten structurally related synthesized diglycolamides (DGA) diluted with toluene. The structure-reactivity relationship with extraction of trivalent lanthanides as well as their atomic number was investigated. The extraction of nitric acid and selected lanthanide ions by N,N,N?,N?-tetradodeceyldiglycolamide (TDDGA), from nitric acid medium was studied in details. Distribution ratio of the trivalent lanthanide ions has been studied as a function of aqueous HNO3 concentrations, DGA concentration, and temperature. The stoichiometry of La(III), Nd(III), and Eu(III) was determined at different nitric acid concentrations by slope analysis of extraction data, and enthalpy change accompanied by extraction was also determined and reported in this work.

E.A. Mowafy; D. Mohamed

2014-01-01T23:59:59.000Z

37

Extraction of uranium(VI) and plutonium(IV) with dihexylbutyramide and dihexylisobutyramide from nitric acid medium  

Science Journals Connector (OSTI)

The extraction of uranium(VI) and plutonium(IV) was carried out with two isomeric monoamides, dihexylbutyramide (DHBA) and dihexylisobutyramide (DHIBA) from nitric acid medium, usingn-dodecane as diluent. The pos...

G. M. Nair; D. R. Prabhu; G. R. Mahajan

1994-08-01T23:59:59.000Z

38

A thermodynamic model of nitric acid extraction by tri-n-butyl phosphate  

SciTech Connect (OSTI)

A thermodynamic model is presented for nitric acid extraction by tri-n-butyl phosphate (TBP). This model is based on the formation of the organic phase species: TBP.HNO/sub 3/ and (TBP)/sub 2/.HNO/sub 3/. The model works successfully at TBP concentrations of 5 to 100 vol% and was found to be effective at predicting the extraction of HNO/sub 3/ from HNO/sub 3//NaNO/sub 3/ and HNO/sub 3//LiNO/sub 3/ solutions. Within the TBP concentration range of 5 to 30%, a single set of extraction constants was sufficient to fit extraction data. Stoichiometric activity coefficients of nitric acid in HNO/sub 3//NaNO/sub 3/ and HNO/sub 3//LiNO/sub 3/ mixtures were calculated using a model developed by Bromley.

Chaiko, D.J.; Vandegrift, G.F.

1988-07-01T23:59:59.000Z

39

Scandium nitrate-nitric acid-water-tributyl phosphate system. I. Scandium extraction isotherms  

SciTech Connect (OSTI)

A study has been made of scandium distribution between neat tributyl phosphate (TBP) and 0.2-1.2 M scandium solutions in 2.7-12.3 M nitric acid. Scandium extracts in equilibrium with 0.2-1 M Sc in 6-12 M HNO{sub 3} contain from 2 to 5 HNO{sub 3} molecules per scandium atom in extracted Sc complex.

Listopadov, A.A.; Nikitina, G.P.; Egorova, V.P. [Khlopin Radium Institute, St. Petersburg (Russian Federation)] [and others

1995-01-01T23:59:59.000Z

40

Initiation Temperature for Runaway Tri-n-Butyl Phosphate/Nitric Acid Reaction  

SciTech Connect (OSTI)

During a review of the H-Canyon authorization basis, Defense Nuclear Facility Safety Board (DNFSB) staff members questioned the margin of safety associated with a postulated tri-n-butyl phosphate (TBP)/nitric acid runaway reaction due to the inadvertent heating of a canyon tank containing greater than 3000 lbs (1362 kg) of TBP. The margin of safety was partially based on experiments and calculations performed by the Actinide Technology Section (ATS) to support deletion of indication of tank agitation as a Safety Class System. In the technical basis for deletion of this system, ATS personnel conservatively calculated the equilibrium temperature distribution of a canyon tank containing TBP and nitric acid layers which were inadvertently heated by a steam jet left on following a transfer. The maximum calculated temperature (128 degrees C) was compared to the minimum initiation temperature for a runaway reaction (greater than 130 degrees C) documented by experimental work in the mid 195 0s. In this work, the initiation temperature as a function of nitric acid concentration was measured for 0 and 20 wt percent dissolved solids. The DNFSB staff members were concerned that data for 0 wt percent dissolved solids were not conservative given the facts that data for 20 wt percent dissolved solids show initiation temperatures at or below 130 degrees C and H-Canyon solutions normally contained a small amount of dissolved solids.

Rudisill, T.S.

2000-11-28T23:59:59.000Z

Note: This page contains sample records for the topic "nitric acid production" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Search for an in-line nitric acid analyzer  

SciTech Connect (OSTI)

A literature search was conducted to identify possible techniques for measuring mineral acid normality in the presence of heavy metal salts, undissolved solids, and high radiation fields. Of the techniques noted, eight were identified that could be applicable to the objective. The possibilities were reduced to two methods, which warrant further investigation. These two are refractometry and a modified coulometric-polarographic method. All methods are discussed in detail followed by rationale for including or rejecting each for further investigation.

Gallagher, K. Y.; Johnson, C. M.

1980-10-01T23:59:59.000Z

42

Nitrite–dependent nitric oxide production pathway: implications for involvement of active nitrogen species in photoinhibition in vivo  

Science Journals Connector (OSTI)

...as a convenient method for calibration...1. Chemical NO production from nitrite and...Figure 4. Sequential production of the activated...interactions. Like hydrogen peroxide (H2O2...oxide protocols: methods in molecular biology...Nonenzymatic nitric oxide production in humans. Nitric...

2000-01-01T23:59:59.000Z

43

Sorption of uranium from nitric acid solution using TBP-impregnated activated carbons  

SciTech Connect (OSTI)

The concept of extraction chromatography has been used to study the sorption of uranium from nitric acid solutions using tri-n-butyl phosphate (TBP) impregnated activated carbons. Batch equilibrium data and kinetic and breakthrough column behavior of uranium are reported. Wood based activated carbon has shown better capacity and breakthrough characteristics than shell based activated carbon. Sorption rate on impregnated carbons was relatively slow indicating that diffusion is the rate controlling step within the pore structure of the activated carbon. Uranium distribution on impregnated activated carbons is compared with equivalent bulk liquid extraction and a mechanism of uranium sorption is discussed.

Abbasi, W.A. [Pakistan Atomic Energy Commission, Islamabad (Pakistan). Pakistan Inst. of Nuclear Science and Technology; Streat, M. [Loughborough Univ. (United Kingdom). Dept. of Chemical Engineering

1998-08-01T23:59:59.000Z

44

Effect of temperature on the extraction of nitric acid and plutonium(IV) nitrate with 30 vol% tributyl phosphate (TBP)  

SciTech Connect (OSTI)

The author's own and published data were evaluated for characterizing the effect of temperature on the distribution of nitric acid and plutonium(IV). The solutes were distributed between 30 vol% TBP in an aliphatic diluent and aqueous solutions containing nitric acid and zero to macro amounts of plutonium(IV) and uranyl nitrates. The temperature dependence of the distribution ratios is described with empirical model equations and examples of the dependence in the absence and presence of uranium(VI) are given. Taking infinite dilution of all solutes of the system as a standard state, the enthalpy change of the extraction reaction could be estimated as -17 kJ/mol for nitric acid, but no numerical estimate was possible for plutonium(IV).

Kolarik, Z.

1984-01-01T23:59:59.000Z

45

Features of gadolinium and ytterbium extraction by tributyl phosphate from concentrated nitric acid solutions. II. IR spectra of lanthanide extracts  

SciTech Connect (OSTI)

Equilibrium organic phases in extraction systems consisting of tributyl phosphate (TBP) (neat or 1.8 M in CCl{sub 4}) and 8-12 M nitric acid containing Gd or Yb or lanthanide-free have been studied by IR spectroscopy. It was shown that under these conditions lanthanides are extracted as complex trisolvates Ln(NO{sub 3})9{sub 3}{center_dot}mHNO{sub 3}{center_dot}3TBP with m = 3-6. Nitric acid molecules are H-bonded to oxygen atoms of coordinated nitrate ions and do not substitute TBP molecules in coordination sphere of the metal ion.

Nikitina, G.P.; Seredkina, N.V.; Kistopadov, A.A. [Khlopin Radium Institute, St. Petersburg (Russian Federation)

1995-03-01T23:59:59.000Z

46

Separation of uranium from nitric and hydrochloric acid solutions with extractant-coated magnetic microparticles.  

SciTech Connect (OSTI)

The magnetically assisted chemical separation (MACS) process utilizes selective magnetic microparticle composites to separate dissolved metals from solution. In this study, MACS particles were coated with neutral and acidic organophosphorus extractants,octyl(phenyl)-N,N-diisobutylcarbamoylmethyl phosphine oxide (CMPO), tributyl phosphate (TBP), trioctylphosphine oxide (TOPO), and bis(2-ethyl-hexyl)phosphoric acid (D{sub 2}EHPA or HDEHP) and were evaluated for the separation of uranyl ions from nitric- and hydrochloric-acid solutions. The results suggest that a synergistic interaction between the particle surface and solvent coating may explain why the particles display, in some cases, orders of magnitude of higher partitioning coefficients than are estimated from solvent-extraction measurements. Particles coated with TBP and those coated with a combination of TOPO and D{sub 2}EHPA displayed the most desirable characteristics for removing uranium from dilute acid environments typical of contaminated groundwater. Uranium separation from moderate to highly acidic waste streams typical of Department of Energy (DOE) nuclear wastes is best accomplished using particles coated with a combination of CMPO and TBP.

Kaminski, M. D.; Nunez, L.; Chemical Engineering

2000-01-01T23:59:59.000Z

47

Safe conditions for contacting nitric acid or nitrates with tri-n-butyl phosphate (TBP)  

SciTech Connect (OSTI)

In response to a request from DOE-SR, the current state of knowledge of the reactions between TBP and aqueous nitrate solutions is critically reviewed, and recommendations are made for the safe operation of SRS separations equipment in which this combination of chemicals may be present. The existing limits for evaporation are validated. Guidelines are presented for cases in which general limits do not apply. The rate of reaction between nitric acid and TBP appears to be controlled by the rate of TBP hydrolysis. The hydrolysis reaction produces dibutyl phosphate and n-butanol. The hydrolysis rate is a strong function of temperature, and becomes very fast at temperatures in the range 130{degrees} to 150{degrees}C. The resulting n-butanol is volatile at high temperatures, boiling at 117.5{degrees}C, but is also subject to exothermic oxidation by nitric acid or nitrates. If oxidation occurs before the n-butanol evaporates, the heat of oxidation may exceed local cooling by convection. The resulting heating will further accelerate the reaction, leading to an energetic runaway and possibly (in confined systems) an explosion. Extensive experiments and practice have shown that in a well-mixed and well-vented aqueous system such as an evaporator, at moderate acidities and temperatures below 130{degrees}C, the heat of reaction is adequately removed by vaporization of steam. In general, the heating will be so slow that natural processes provide adequate cooling at temperatures below 80{degrees}C. Above this temperature, care should be taken to ensure that adequate cooling is available for the amount of TBP that may be present. Experiments suggest that in well-ventilated systems n-butanol evaporation and convective cooling are sufficient to control the reaction at temperatures up to 120{degrees}C.

Hyder, M.L

1994-01-01T23:59:59.000Z

48

Corrosion property of 9Cr-ODS steel in nitric acid solution for spent nuclear fuel reprocessing  

SciTech Connect (OSTI)

Corrosion tests of oxide dispersion strengthened with 9% Cr (9Cr-ODS) steel, which is one of the desirable materials for cladding tube of sodium-cooled fast reactors, in pure nitric acid solution, spent FBR fuel solution, and its simulated solution were performed to understand the corrosion behavior in a spent nuclear fuel reprocessing. In this study, the 9Cr-ODS steel with lower effective chromium content was evaluated to understand the corrosion behavior conservatively. As results, the tube-type specimens of the 9Cr-ODS steels suffered severe weight loss owing to active dissolution at the beginning of the immersion test in pure nitric acid solution in the range from 1 to 3.5 M. In contrast, the weight loss was decreased and they showed a stable corrosion in the higher nitric acid concentration, the dissolved FBR fuel solution, and its simulated solution by passivation. The corrosion rates of the 9Cr-ODS steel in the dissolved FBR fuel solution and its simulated solution were 1-2 mm/y and showed good agreement with each other. The passivation was caused by the shift of corrosion potential to noble side owing to increase in nitric acid concentration or oxidative ions in the dissolved FBR fuel solution and the simulated spent fuel solution. (authors)

Takeuchi, M.; Koizumi, T. [Japan Atomic Energy Agency, Tokai-mura, Naka-gun, Ibaraki 319-1195 (Japan); Inoue, M.; Koyama, S.I. [Japan Atomic Energy Agency, Oarai-machi, Higashi-ibaraki-gun, Ibaraki 311-1393 (Japan)

2013-07-01T23:59:59.000Z

49

Nitric Acid Deposition following an Astrophysical Ionizing Radiation Event is below Critical Loads for Terrestrial and Freshwater Ecosystems  

E-Print Network [OSTI]

Nitric acid rainout is one of the effects of an astrophysical ionizing radiation event. The predicted values of nitrate rainout from previous work for a typical gamma ray burst (GRB) within our galaxy serve as an extreme example and are shown to be below critical loads of eutrophication and acidification for ecoregions in Europe and the US.

Melott, Ben Neuenswander Adrian

2014-01-01T23:59:59.000Z

50

Hibiscus Protocatechuic Acid or Esculetin Can Inhibit Oxidative LDL Induced by Either Copper Ion or Nitric Oxide Donor  

Science Journals Connector (OSTI)

Hibiscus Protocatechuic Acid or Esculetin Can Inhibit Oxidative LDL Induced by Either Copper Ion or Nitric Oxide Donor ... Several groups using different flavonoids, such as quercetin, catechin, morin, rutin, fisetin, and gossypetin, also showed that flavonoids could inhibit copper-catalyzed and macrophage-mediated LDL oxidation (13?16). ... morin and fisetin 1 ?M; quercetin and gossypetin 2 ?M). ...

Miao-Jane Lee; Fen-Pi Chou; Tsui-Hwa Tseng; Ming-Hsun Hsieh; Ming-Cheng Lin; Chau-Jong Wang

2002-02-16T23:59:59.000Z

51

Initiation Temperature for Runaway Tri-n-Butyl Phosphate/Nitric Acid Reaction  

SciTech Connect (OSTI)

In a review of the safety basis for solvent extraction processes at the Department of Energy's Savannah River Site, a question was raised concerning the safety margin associated with a postulated accident involving a runaway tri-n-butyl phosphate (TBP)/nitric acid reaction due to the inadvertent heating of a tank. The safety margin was based on studies which showed the maximum temperature would not exceed 128 degrees Celsius compared to 130 degrees Celsius, the minimum initiation temperature for runaway reaction established in the 1950's following damaging incidents at the Savannah River and Hanford Sites. The reviewers were concerned the minimum temperature was not conservative since data for solutions containing 20 wt percent dissolved solids showed initiation temperatures at or below 130 degrees Celsius and process solutions normally contain some dissolved solids.

Rudisill, T.S.

2001-09-14T23:59:59.000Z

52

Extraction equilibria between organic CMPO-n-dodecane and aqueous nitric acid phases for selected tank waste components  

SciTech Connect (OSTI)

Removal of the transuranium elements from tank-stored wastes is an important step in the cost effective treatment and preparation of these wastes for permanent disposal. One promising method of treatment involves dissolving the tank sludges in acid, followed by extraction of the transuranium species. The TRUEX process, which uses an extracting medium composed of octyl(phenyl)-N,N-diisobutylcarbamoylmethyl phosphine oxide (CMPO) and tri-n-butyl phosphate (TBP) dissolved in an organic solvent such as n-dodecane, is being tested for this purpose. Although CMPO is a powerful extractant for all the actinides, concern arises that certain process chemicals present in the waste will compete for the CMPO. Data will be presented on the pure component equilibrium characteristics of nitric acid, uranyl nitrate and bismuth nitrate partitioned between a nitric acid aqueous phase and a CMPO-n-dodecane organic phase.

Spencer, B.B.; Egan, B.Z. [Oak Ridge National Lab., TN (United States); Counce, R.M. [Univ. of Tennessee, Knoxville, TN (United States)

1996-10-01T23:59:59.000Z

53

Process for the extraction of strontium from acidic solutions  

DOE Patents [OSTI]

The invention is a process for selectively extracting strontium values from aqueous nitric acid waste solutions containing these and other fission product values. The extractant solution is a macrocyclic polyether in an aliphatic hydrocarbon diluent containing a phase modifier. The process will selectively extract strontium values from nitric acid solutions which are up to 6 molar in nitric acid. 4 figs.

Horwitz, E.P.; Dietz, M.L.

1994-09-06T23:59:59.000Z

54

Process for the extraction of strontium from acidic solutions  

DOE Patents [OSTI]

The invention is a process for selectively extracting strontium values from aqueous nitric acid waste solutions containing these and other fission product values. The extractant solution is a macrocyclic polyether in an aliphatic hydrocarbon diluent containing a phase modifier. The process will selectively extract strontium values from nitric acid solutions which are up to 6 molar in nitric acid.

Horwitz, E.P.; Dietz, M.L.

1993-01-01T23:59:59.000Z

55

E-Print Network 3.0 - abandoned nitric acid Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Wet ashing procedures using nitric ... Source: Canberra, University of - Institute for Applied Ecology Collection: Environmental Sciences and Ecology 16 Human Resources...

56

Amides as phase modifiers for N,N{prime}-tetraalkylmalonamide extraction of actinides and lanthanides from nitric acid solutions  

SciTech Connect (OSTI)

The N,N{prime}-tetraalkylmalonamides are a class of compounds under development for transuranic (TRU) separations under high nitric acid conditions. There are several issues that challenge the further development of these ligands. One is the development of improved synthetic procedures that lend themselves to commercial scale-up. Another major issue is the third-phase formation that occurs when the N,N{prime}-tetraalkylmalonamides are contacted with medium-to-high nitric acid concentrations in hydrocarbon solvents. To address the synthesis issue, the authors have developed a new synthetic approach for preparing these materials. Third-phase formation can be eliminated by addition of diluent modifiers such as tributylphosphate (TBP). TBP is inappropriate if a nonphosphate-containing process stream is required. Amides have been proposed as alternatives for TBP in a variety of applications because of their ease of synthesis and the variety of substituents that can be generated. The authors have been able to develop an amide phase-modified system that extends the working process range of alkylinalonamides (0.5 M) in dodecane: from 3.5 M to 7.5 M nitric acid and in Isopar H (branched hydrocarbon) from 4.0 M to 10.0 M nitric acid using 1.0 M di-2-ethylhexylacetamide/0.5 M alkylmalonamide. The Kd values were comparable to extraction with alkylinalonamide in Isopar H or hydrogenated tetrapropylene (TPH) solvents. The overall extraction system was more robust than the phase-uninodified system allowing for greater temperature and acid concentration fluctuations without third-phase formation.

Smith, B.F.; Wilson, K.V.; Gibson, R.R. [Los Alamos National Lab., NM (United States)

1997-01-01T23:59:59.000Z

57

Remedial investigation report on the abandoned nitric acid pipeline at the Oak Ridge Y-12 Plant, Oak Ridge, Tennessee  

SciTech Connect (OSTI)

Upper East Fork Poplar Creek OU-2 consists of the Abandoned Nitric Acid Pipeline. This pipeline was installed in 1951 to transport liquid wastes {approximately} 4,800 ft from Buildings 9212, 9215, and 9206 to the S-3 Ponds. Materials known to have been discharged through the pipeline include nitric acid, depleted and enriched uranium, various metal nitrates, salts, and lead skimmings. A total of nineteen locations were chosen to be investigated along the pipeline for the first phase of this Remedial Investigation. Sampling consisted of drilling down to obtain a soil sample at a depth immediately below the pipeline. Additional samples were obtained deeper in the subsurface depending upon the depth of the pipeline, the depth of the water table, and the point of auger refusal. The nineteen samples collected below the pipeline were analyzed by the Y-12 Plant laboratory for metals, nitrate/nitrite, and isotopic uranium. Samples collected from three boreholes were also analyzed for volatile organic compounds because these samples produced a response with organic vapor monitoring equipment. The results of the baseline human health risk assessment for the Abandoned Nitric Acid Pipeline contaminants of potential concern show no unacceptable risks to human health via incidental ingestion of soil, inhalation of dust, dermal contact with the soil, or external exposure to radionuclides in the ANAP soils, under the construction worker and/or the residential land-use scenarios.

Not Available

1993-12-01T23:59:59.000Z

58

Effect of temperature on the extraction of uranium(VI) from nitric acid by tri-n-amyl phosphate  

SciTech Connect (OSTI)

Studies have been carried out on the effect of temperature on the extraction of U(VI) from nitric acid medium by tri-n-amyl phosphate/n-dodecane, measured as a function of the extractant concentration and aqueous phase acidity. The results indicate that the extraction is exothermic as in the case of tri-n-butyl phosphate. From the data available an effort has been made to calculate the equilibrium constant, the Gibbs energy change and the entropy changes of the extraction reaction. 21 refs., 3 figs., 4 tabs.

Srinivasan, T.G.; Rao, P.R.V. [Indira Gandhi Centre for Atomic Research, Kalpakkam (India); Sood, D.D. [Indira Gandhi Centre for Atomic Research, Kalpakkam (India)]|[BARC, Mumbai (India)

1997-01-01T23:59:59.000Z

59

Extraction and recovery of plutonium and americium from nitric acid waste solutions by the TRUEX process - continuing development studies  

SciTech Connect (OSTI)

This report summarizes the work done to date on the application of the TRUEX solvent extraction process for removing and separately recovering plutonium and americium from a nitric acid waste solution containing these elements, uranium, and a complement of inert metal ions. This simulated waste stream is typical of a raffinate from a tributyl phosphate (TBP)-based solvent extraction process for removing uranium and plutonium from dissolved plutonium-containing metallurgical scrap. The TRUEX process solvent in these experiments was a solution of TBP and octyl(phenyl)-N,N-diisobutylcarbamoylmethylphosphine oxide (CMPO) dissolved in carbon tetrachloride. A flowsheet was designed on the basis of measured batch distribution ratios to reduce the TRU content of the solidified raffinate to less than or equal to 10 nCi/g and was tested in a countercurrent experiment performed in a 14-stage Argonne-model centrifugal contractor. The process solvent was recycled without cleanup. An unexpectedly high evaporative loss of CCl/sub 4/ resulted in concentration of the active extractant, CMPO, to nearly 0.30M in the solvent. Results are consistent with this higher CMPO concentration. The raffinate contained only 2 nCi/g of TRU, but the higher CMPO concentration resulted in reduced effectiveness in the stripping of americium from the solvent. Conditions can be easily adjusted to give high yields and good separation of americium and plutonium. Experimental studies of the hydrolytic and gamma-radiolytic degradation of the TRUEX-CCl/sub 4/ showed that solvent degradation would be (1) minimal for a year of processing this typical feed, which contained no fission products, and (2) could be explained almost entirely by hydrolytic and radiolytic damage to TBP. Even for gross amounts of solvent damage, scrubbing with aqueous sodium carbonate solution restored the original americium extraction and stripping capability of the solvent. 43 refs., 5 figs., 36 tabs.

Leonard, R.A.; Vandegrift, G.F.; Kalina, D.G.; Fischer, D.F.; Bane, R.W.; Burris, L.; Horwitz, E.P.; Chiarisia, R.; Diamond, H.

1985-09-01T23:59:59.000Z

60

Nitric oxide donors prevent while the nitric oxide synthase inhibitor L-NAME increases arachidonic acid plus CYP2E1-dependent toxicity  

SciTech Connect (OSTI)

Polyunsaturated fatty acids such as arachidonic acid (AA) play an important role in alcohol-induced liver injury. AA promotes toxicity in rat hepatocytes with high levels of cytochrome P4502E1 and in HepG2 E47 cells which express CYP2E1. Nitric oxide (NO) participates in the regulation of various cell activities as well as in cytotoxic events. NO may act as a protectant against cytotoxic stress or may enhance cytotoxicity when produced at elevated concentrations. The goal of the current study was to evaluate the effect of endogenously or exogenously produced NO on AA toxicity in liver cells with high expression of CYP2E1 and assess possible mechanisms for its actions. Pyrazole-induced rat hepatocytes or HepG2 cells expressing CYP2E1 were treated with AA in the presence or absence of an inhibitor of nitric oxide synthase L-N {sup G}-Nitroarginine Methylester (L-NAME) or the NO donors S-nitroso-N-acetylpenicillamine (SNAP), and (Z)-1-[-(2-aminoethyl)-N-(2-aminoethyl)]diazen-1-ium-1,2-diolate (DETA-NONO). AA decreased cell viability from 100% to 48 {+-} 6% after treatment for 48 h. In the presence of L-NAME, viability was further lowered to 23 {+-} 5%, while, SNAP or DETA-NONO increased viability to 66 {+-} 8 or 71 {+-} 6%. The L-NAME potentiated toxicity was primarily necrotic in nature. L-NAME did not affect CYP2E1 activity or CYP2E1 content. SNAP significantly lowered CYP2E1 activity but not protein. AA treatment increased lipid peroxidation and lowered GSH levels. L-NAME potentiated while SNAP prevented these changes. Thus, L-NAME increased, while NO donors decreased AA-induced oxidative stress. Antioxidants prevented the L-NAME potentiation of AA toxicity. Damage to mitochondria by AA was shown by a decline in the mitochondrial membrane potential (MMP). L-NAME potentiated this decline in MMP in association with its increase in AA-induced oxidative stress and toxicity. NO donors decreased this decline in MMP in association with their decrease in AA-induced oxidative stress and toxicity. These results indicate that NO can be hepatoprotective against CYP2E1-dependent toxicity, preventing AA-induced oxidative stress.

Wu Defeng [Department of Pharmacology and Biological Chemistry, Box 1603, One Gustave L. Levy Place, Mount Sinai School of Medicine, New York, NY 10029 (United States); Cederbaum, Arthur [Department of Pharmacology and Biological Chemistry, Box 1603, One Gustave L. Levy Place, Mount Sinai School of Medicine, New York, NY 10029 (United States)]. E-mail: arthur.cederbaum@mssm.edu

2006-10-15T23:59:59.000Z

Note: This page contains sample records for the topic "nitric acid production" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Production of carboxylic acid and salt co-products  

DOE Patents [OSTI]

This invention provide processes for producing carboxylic acid product, along with useful salts. The carboxylic acid product that is produced according to this invention is preferably a C.sub.2-C.sub.12 carboxylic acid. Among the salts produced in the process of the invention are ammonium salts.

Hanchar, Robert J.; Kleff, Susanne; Guettler, Michael V.

2014-09-09T23:59:59.000Z

62

Solvent Extraction Behavior of Neptunium (IV) Ions between Nitric Acid and Diluted 30% Tri-butyl Phosphate in the Presence of Simple Hydroxamic Acids  

SciTech Connect (OSTI)

Formo- and aceto-hydroxamic acids are very effective reagents for stripping tetravalent actinide ions such as Np(IV) and Pu(IV) ions from a tri-butyl phosphate phase into nitric acid. Distribution data for Np(IV) in the presence of these hydroxamate ions have now been accumulated and trends established. Stability constants for aceto-hydroxamate complexes of Np(IV) and Np(V) ions have also been determined in a perchlorate medium, and these reaffirm the affinity of hydroxamate ligands for actinide (IV) ions over actinyl (V,VI) ions.

Taylor, Robin J.; Sinkov, Sergey I.; Choppin, Gregory R.; May, Iain

2008-01-15T23:59:59.000Z

63

Suppression of manganese-dependent production of nitric oxide in astrocytes: implications for therapeutic modulation of glial-derived inflammatory mediators  

E-Print Network [OSTI]

Primary cultured astrocytes were treated with Mn in the absence and presence of proinflammatory cytokines to determine their effect upon stimulation of nitric oxide (NO) production. Treatments of manganese and cytokines raised NO production...

Wright, Tyler T.

2009-05-15T23:59:59.000Z

64

Scandium nitrate-nitric acid-water-tributyl phosphate system. II. Interaction of Sc(NO{sub 3}){sub 3}{center_dot}3TBP with nitric acid in organic solvent  

SciTech Connect (OSTI)

Scandium nitrate solvates Sc(NO{sub 3}){sub 3}{center_dot}qTBP (TBP is tributyl phosphate, q = 3.15, 2.57, and 1.58) were synthesized, and their IR spectra were measured. Model solutions of Sc(NO{sub 3}){sub 3}{center_dot}3TBP in CCl{sub 4} containing nitric acid with Sc:HNO{sub 3} molar ratios 1:1 to 1:3 and 1:7 were prepared, and their IR spectra were also measured. The spectra indicate formation of complexes with formula Sc(NO{sub 3}){sub 3}{center_dot}mHNO{sub 3}{center_dot}3TBP (m = 1-7) through H-bonding of medium strength. In complexes with m = 1-2, nitric acid molecules are presumably bonded to oxygen atoms of nitrate groups coordinated to scandium. The R{sub O{hor_ellipsis}O} distance in these complexes was estimated for the H-bond as 2.68 {angstrom}.

Nikitina, G.P.; Papkov, K.B.; Listopadov, A.A. [Khlopin Radium Institute, St. Petersburg (Russian Federation)

1995-03-01T23:59:59.000Z

65

Synergistic selective extraction of actinides(III) over lanthanides from nitric acid using new aromatic diorganyldithiophosphinic acids and neutral organophosphorus compounds  

SciTech Connect (OSTI)

New aromatic dithiophosphinic acids (R{sub 2}PSSH) with R = C{sub 6}H{sub 5{sup {minus}}}, ClC{sub 6}H{sub 4{sup {minus}}}, FC{sub 6}H{sub 4{sup {minus}}} and CH{sub 3}C{sub 6}H{sub 4{sup {minus}}} were synthesized, characterized and tested as potential separating agents for trivalent actinides over lanthanides. The extraction of Am(III), Eu(III) and other lanthanides was carried out from nitric acid medium with mixtures of R{sub 2}PSSHs and neutral organophosphorus compounds. There was no detectable extraction when R{sub 2}PSSHs were used alone as extractants for either Am(III) or Eu(III) (D{sub Am,Eu} < 10{sup {minus}3}) under the experimental conditions used in this study. High separation factors (D{sub Am}/D{sub Eu} > 20) with D{sub Am} > 1 were achieved in the nitric acid range 0.1--1 mol/L by means of a synergistic mixture of bis(chlorophenyl)dithiophosphinic acid + tributylphosphate (TBP), trioctylphosphine oxide (TOPO) or tributylphosphine oxide (TBPO). The high radiation resistance (up to 10{sup 6} Gy absorbed {gamma}-doses) of the extractants was also demonstrated.

Modolo, G.; Odoj, R. [Forschungszentrum Juelich GmbH (Germany). Inst. fuer Sicherheitsforschung und Reaktortechnik

1999-01-01T23:59:59.000Z

66

Comparative evaluation of DHDECMP (dihexyl-N,N-diethylcarbamoyl-methylphosphonate) and CMPO (octylphenyl-N,N,-diisobutylcarbamoylmethylphosphine oxide) as extractants for recovering actinides from nitric acid waste streams  

SciTech Connect (OSTI)

Certain neutral, bifunctional organophosphorous compounds are of special value to the nuclear industry. Dihexyl-N,N-diethylcarbomoylmethylphosphonate (DHDECMP) and octylphenyl-N,N-diisobutylcarbamoylmethylphosphine oxide (CMPO) are highly selective extractants for removing actinide and lanthanide elements from nitric acid. We obtained these two extractants from newly available commercial sources and evaluated them for recovering Am(III), Pu(IV), and U(VI) from nitric acid waste streams of plutonium processing operations. Variables included the extractant (DHSECMP or CMPO), extractant/tributylphosphate ratio, diluent, nitrate concentration, nitrate salt/nitric acid ratio, fluoride concentration, and contact time. Based on these experimental data, we selected DHDECMP as the perferred extractant for this application. 18 refs., 30 figs.

Marsh, S.F.; Yarbro, S.L.

1988-02-01T23:59:59.000Z

67

K Basin Sludge Conditioning Process Testing Fate of PCBs During K Basin Sludge Dissolution in Nitric Acid and with Hydrogen Peroxide Addition  

SciTech Connect (OSTI)

The work described in this report is part of the studies being performed to address the fate of polychlorinated biphenyls (PCBs) in K Basin sludge before the sludge can be transferred to the Tank Waste Remediation System (TWRS) double shell tanks. One set of tests examined the effect of hydrogen peroxide on the disposition of PCBs in a simulated K Basin dissolver solution containing 0.5 M nitric acid/1 M Fe(NO{sub 3}){sub 3}. A second series of tests examined the disposition of PCBs in a much stronger ({approx}10 M) nitric acid solution, similar to that likely to be encountered in the dissolution of the sludge.

GM Mong; AJ Schmidt; EW Hoppe; KH Pool; KL Silvers; BM Thornton

1999-01-04T23:59:59.000Z

68

Ethylene Production from Linolenic Acid  

Science Journals Connector (OSTI)

... and Mapson1 have shown that linolenic 1 J acid may serve as a precursor of ethylene. The possi -bility that the ... . The possi -bility that the ethylene that is evolved from plants arises from linolenic acid was investigated by determining the relationship ...

F. B. ABELES

1966-04-02T23:59:59.000Z

69

Visualization of nitric oxide production in the mouse main olfactory bulb by a cell-trappable copper(II) fluorescent probe  

E-Print Network [OSTI]

We report the visualization of NO production using fluorescence in tissue slices of the mouse main olfactory bulb. This discovery was possible through the use of a novel, cell-trappable probe for intracellular nitric oxide ...

McQuade, Lindsey E.

70

Production of nitric oxide, lipid peroxidation and oxidase activity of ceruloplasmin in blood of elderly patients with primary hypertension. Effects of perindopril treatment  

Science Journals Connector (OSTI)

Background and aims: One of the factors playing a role in both the aging ... purpose of this work was to estimate the production of nitric oxide (NO), oxidase activity...Methods: The study was ca...

Kornelia K?ziora-Kornatowska MD; PhD…

2006-02-01T23:59:59.000Z

71

Safety of Tri-n-butyl phosphate (TBP) and nitric acid solutions in two-phase systems at elevated temperatures  

SciTech Connect (OSTI)

This paper addresses the prevention of self-accelerating oxidation of nitric acid and tributyl phosphate (TBP). An accident of this type, which occurred at Tomsk-7, Russia, in 1993, resulted from a slow chemical reaction occurring initially at sub-boiling temperatures. The accumulating heat and vapors overpressurized and burst a process tank. Two safety issues are addressed in this summary of experimental data: circumstances under which convection or radiation cooling of vessels will exceed reaction heat, and measures which can prevent or mitigate such reactions. Heat generations rates have been found to range widely. Thermodynamic calculations confirm that heat generation is reduced by a large factor when nitrogen oxides are able to escape from the reaction mixure. Scoping calculations show that the evaporation of water is potentially the most effective mechanism for heat removal in a large vessel, and experiments have demonstrated that water evaporation is effective for preventing runaway reactions in a vented, two-phase system operated below about 120 C. These data indicate that venting is the key to controlling runaway reactions. However, other experiments have indicated that the self-heating reaction did not present a danger, even if reaction heating led to an accelerating reaction, in a sufficiently vented system. To determine how much venting was required, experiments were performed with pure organic phase and two-phase TBP-nitric acid mixtures. Data show a critical ratio of organic mass to vent area, above which the reacting system can reach potentially dangerous pressures. Experiments show runaway reactions occurring in vented systems only as the temperature approaches 130 C. These results clearly indicate that adequate venting of vessels containing heated TBP and nitrate is the key to controlling their reaction.

Hyder, M.L.; Paddleford, D.F.; Thompson, M.C. [Westinghouse Savannah River Company, Aiken, SC (United States)

1995-12-31T23:59:59.000Z

72

Studies on reaction runaways for Urex/Purex solvent-nitric acid and red-oil synthesis  

SciTech Connect (OSTI)

In PUREX/UREX processes for recycling of spent nuclear fuels, 30% TBP solvent is used, This solvent has a small solubility in the aqueous phase. During concentration of the process solutions by an evaporation route, a runaway reaction between TBP and nitric acid is initiated at above 130 deg. C, leading to rapid pressurization and finally containment failure if proper venting is not provided. Red oil was synthesized for the first time in India, and its physical properties as well as thermodynamic parameters for the reaction were determined. It was experimentally established that the presence of metallic nitrates was not essential for red-oil formation as thought earlier. Various experiments have been completed for single-phase as well as two-phase runs. The most important finding of this work was lowering of the limiting acid concentration from the conventional values. In fact, in these experiments, red oil could be formed even at 2 N aqueous acidity. Thus, safety guidelines based on the classical literature are obsolete. New guidelines for the red-oil-safety are required. (authors)

Kumar, Shekhar; Kumar, Rajnish; Koganti, S.B. [Reprocessing R and D Division, Reprocessing Group, Indira Gandhi Centre for Atomic Research, Kalpakkam 603102 (India)

2008-07-01T23:59:59.000Z

73

Arginase inhibition reduces interleukin-1?-stimulated vascular smooth muscle cell proliferation by increasing nitric oxide synthase-dependent nitric oxide production  

SciTech Connect (OSTI)

Highlights: •Arginase inhibition suppressed proliferation of IL-1?-stimulated VSMCs in dose-dependent manner. •NO production from IL-1?-induced iNOS expression was augmented by arginase inhibition, reducing VSMC proliferation. •Incubation with cGMP analogues abolished IL-1?-dependent proliferation of VSMCs. -- Abstract: We investigated whether arginase inhibition suppressed interleukin (IL)-1?-stimulated proliferation in vascular smooth muscle cells (VSMCs) and the possible mechanisms involved. IL-1? stimulation increased VSMC proliferation, while the arginase inhibitor BEC and transfection of the antisense (AS) oligonucleotide against arginase I decreased VSMC proliferation and was associated with increased protein content of the cell cycle regulator p21Waf1/Cip1. IL-1? incubation induced inducible nitric oxide synthase (iNOS) mRNA expression and protein levels in a dose-dependent manner, but did not affect arginase I and II expression. Consistent with this data, IL-1? stimulation resulted in increase in NO production that was significantly augmented by arginase inhibition. The specific iNOS inhibitor 1400W abolished IL-1?-mediated NO production and further accentuated IL-1?-stimulated cell proliferation. Incubation with NO donors GSNO and DETA/NO in the presence of IL-1? abolished VSMCs proliferation and increased p21Waf1/Cip1 protein content. Furthermore, incubation with the cGMP analogue 8-Br-cGMP prevented IL-1?-induced VSMCs proliferation. In conclusion, arginase inhibition augmented iNOS-dependent NO production that resulted in suppression of IL-1?-induced VSMCs proliferation in a cGMP-dependent manner.

Yoon, Jeongyeon; Ryoo, Sungwoo, E-mail: ryoosw08@kangwon.ac.kr

2013-06-07T23:59:59.000Z

74

THERMODYNAMICS OF EXTRACTION OF NITRIC ACID BY TRI-n-BUTYL PHOSPHATE--HYDROCARBON DILUENT SOLUTIONS  

E-Print Network [OSTI]

the mean act ivi ty coefficient T of TBP and TBP.H20 i n the acid-free, water-saturated organic phase

Wallace Davis

1961-01-01T23:59:59.000Z

75

Process for the recovery of strontium from acid solutions  

DOE Patents [OSTI]

The invention is a process for selectively extracting strontium and technetium values from aqueous nitric acid waste solutions containing these and other fission product values. The extractant is a macrocyclic polyether in a diluent which is insoluble in water, but which will itself dissolve a small amount of water. The process will extract strontium and technetium values from nitric acid solutions which are up to 6 molar in nitric acid. 5 figs.

Horwitz, E.P.; Dietz, M.L.

1992-03-31T23:59:59.000Z

76

{open_quotes}Open vessel{close_quotes} heat balance for TBP-nitric acid solutions  

SciTech Connect (OSTI)

Heat balances were performed for both single phase (organic) and two phase (organic and aqueous) TBP/HNO{sub 3} solutions at temperatures above 100{degrees}C. The balance included the heat produced from oxidation minus losses from evaporation and butylnitrate formation by esterification. Net heat measurements were performed using an isothermal calorimeter. Losses from evaporation were determined from the volume of condensate produced (ice bath trap) and the component concentrate Carbon and nitrogen balances were performed to determine the stoichiometry of the reaction. The heat from oxidation was then calculated using the heats of formation of the reactants and products. Balances were obtained assuming that the heat from esterification was near zero (negligibly small). For two layered reaction systems the net heat was maintained endothermic, and constant with time, due to the transport of water to the organic phase by bubble mixing at the interface. This transported was replaced the water lost in the organic phase by evaporation.

Smith, J.R.; Cavin, W.S.; Laurinat, J.E. [Westinghouse Savannah River Company, Aiken, SC (United States)

1995-12-31T23:59:59.000Z

77

Method for production of petroselinic acid and OMEGA12 hexadecanoic acid in transgenic plants  

DOE Patents [OSTI]

The present invention relates to a process for producing lipids containing the fatty acid, petroselinic acid, in plants. The production of petroselinic acid is accomplished by genetically transforming plants which do not normally accumulate petroselinic acid with a gene for a {omega}12 desaturase from another species which does normally accumulate petroselinic acid. 19 figs.

Ohlrogge, J.B.; Cahoon, E.B.; Shanklin, J.; Somerville, C.R.

1995-07-04T23:59:59.000Z

78

Method for production of petroselinic acid and OMEGA12 hexadecanoic acid in transgenic plants  

DOE Patents [OSTI]

The present invention relates to a process for producing lipids containing the fatty acid petroselinic acid in plants. The production of petroselinic acid is accomplished by genetically transforming plants which do not normally accumulate petroselinic acid with a gene for a .omega.12 desaturase from another species which does normally accumulate petroselinic acid.

Ohlrogge, John B. (Okemos, MI); Cahoon, Edgar B. (Lansing, MI); Shanklin, John (Upton, NY); Somerville, Christopher R. (Okemos, MI)

1995-01-01T23:59:59.000Z

79

Naphthenic acid corrosion in synthetic fuels production  

SciTech Connect (OSTI)

Serious corrosion damage to carbon steel piping in a fractionation unit associated with synthetic fuels production has been ascribed to the presence of naphthenic acids. Investigation of the problem revealed total acids numbers (TAN) ranging from 8--12mg KOH/g in the feed to the unit. Damage typically occurred in the temperature range 180--240 C and manifested as localized pitting, preferential weld corrosion, general wall thinning and end-grain attack. Filming amine corrosion inhibitors designed for refinery overhead systems have been proven ineffective and high temperature phosphate-based inhibitors could not be used due to potential catalyst poisoning in downstream refinery units. Coupon exposures indicated corrosion rates in the order of 2 mm/y on carbon steel in a reboiler line as well as pitting to austenitic stainless steel type UNS S30403. Line replacement in austenitic stainless steel UNS S31603 has been proven effective. The performance of this alloy is mainly ascribed to its molybdenum content. The absence of sulfur in the feed to the unit is also contributing to the alloy performance despite the extremely high total acid numbers.

Bruyn, H.I. de [Mossgas Ltd., Mossel Bay (South Africa)

1998-12-31T23:59:59.000Z

80

Nitric Oxide Production in Relation to Spontaneous B-Cell Lymphoma and Myositis in SJL Mice  

Science Journals Connector (OSTI)

...reduced NO- production and muscle inflammation...MATERIALS AND METHODS Mice. Female...colorimetrie method for the measurement of hydrogen peroxide produced...J. Immunol. Methods, 38: 161-170...to lymphokine production of anti body-enhancing...

Snait Tamir; Teresa deRojas-Walker; Aharon Gal; Ann H. Weller; Xiantang Li; James G. Fox; Gerald N. Wogan; and Steven R. Tannenbaum

1995-10-01T23:59:59.000Z

Note: This page contains sample records for the topic "nitric acid production" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Salt Effect Model for Aqueous Solubility of TBP in a 5 to 100% TBP/n-Dodecane-Nitric Acid-Water Biphasic System at 298.2 K  

SciTech Connect (OSTI)

The solubilities of nonelectrolytes in aqueous electrolyte solutions have traditionally been modeled by using the Setschenow equation for salt effect. The aqueous solubility of tri-n-butyl phosphate (TBP) during operating conditions of the Purex process is an important parameter for safety considerations. Use of the Setschenow equation for aqueous solubility of TBP under limited conditions has been reported in the literature. However, there is no general model available to account for the presence of the diluent and for the case of multicomponent electrolyte solutions in which only some electrolytes are solvated and extracted by TBP. An extended salt effect model is proposed for predicting the aqueous solubility of TBP in a 5 to 100% TBP/n-dodecane-nitric acid-water biphasic system at 298.2 K. The literature data on TBP solubility were correlated to aqueous acid concentration, diluent concentration in the solvents, and an interaction parameter for electrolytic solutes (extracted or not extracted by TBP)

Kumar, Shekhar; Koganti, Sudhir Babu [Indira Gandhi Centre for Atomic Research (India)

2000-02-15T23:59:59.000Z

82

Production of Biofuels from High-Acid-Value Waste Oils  

Science Journals Connector (OSTI)

Production of Biofuels from High-Acid-Value Waste Oils ... (1) Biofuel is derived from a renewable, domestic resource, thereby relieving reliance on petroleum fuel imports. ...

Junming Xu; Guomin Xiao; Yonghong Zhou; Jianchun Jiang

2011-08-27T23:59:59.000Z

83

Absolute measurements of nitric acid by kilometer pathlength FT-IR (Fourier transform infrared) spectroscopy and their intercomparison with other measurement methods. Final report  

SciTech Connect (OSTI)

Measurements of ambient nitric acid (HNO/sub 3/) and ammonia (NH/sub 3/) concentrations were conducted using a Fourier transform infrared (FT-IR) spectrometer interfaced to an open-path, multiple-reflection optical system. These measurements provided benchmark data for gaseous HNO/sub 3/ and NH/sub 3/ during a field study, held at Claremont, California, September 11-19, 1985, which compared current analytical methods for determining nitrogenous species concentrations in the atmosphere. Hourly average concentrations of HNO/sub 3/ and NH/sub 3/ are reported, along with the calculated average concentrations for the sampling periods designated for the majority of the other measurement methods.

Winer, A.M.; Tuazon, E.C.; Biermann, H.W.; Wallington, T.J.

1986-05-01T23:59:59.000Z

84

Modeling of the simultaneous extraction of nitric acid and uranyl nitrate with tri-n-butyl phosphate. Application to extraction operation  

SciTech Connect (OSTI)

A mathematical model developed for the equilibrium HNO{sub 3}-UO{sub 2}(NO{sub 3}){sub 2}-tri-n-butyl phosphate (TBP)-diluent is the basis of the computation of distribution isotherms. The isotherms are used to study the influence of TBP concentration on two chosen operation parameters, distribution coefficients and number of theoretical stages, for the selected flow sheets. It is established that an increase in TBP concentration leads to a decrease in the number of theoretical stages for the extraction flow sheets but to their increase for the striping flow sheets. Given diagrams can be used to determine the efficiency of extraction processes. Agreement with available literature calculations on the number of theoretical stages supports the use of the model in the computation of distribution isotherms, of the system quoted above, in a wide range of nitric acid, uranyl nitrate, and TBP concentrations.

Comor, J.J.; Tolic, A.S.; Kopecni, M.M.; Petkovic, D.M. [Vinca Inst. of Nuclear Sciences, Belgrade (Yugoslavia). Chemical Dynamics Lab.] [Vinca Inst. of Nuclear Sciences, Belgrade (Yugoslavia). Chemical Dynamics Lab.

1999-01-01T23:59:59.000Z

85

Lower-Cost Processes Developed for Phosphoric Acid Production  

Science Journals Connector (OSTI)

Two new processes for the production of phosphoric acid have been developed and are ready for commercialization. ... One is the BESA-2 process, developed by Bohna Engineering & Research, San Francisco; the other is Occidental Research Corp.'s KPA process. ...

JOSEPH HAGGIN

1985-10-21T23:59:59.000Z

86

Improvement of D-glucaric acid production in Escherichia coli  

E-Print Network [OSTI]

D-glucaric acid is a naturally occurring compound which has been explored for a plethora of potential uses, including biopolymer production, cancer and diabetes treatment, cholesterol reduction, and as a replacement for ...

Shiue, Eric Chun-Jen

2014-01-01T23:59:59.000Z

87

Fatty acid production in genetically modified cyanobacteria  

Science Journals Connector (OSTI)

...whether they divert energy into production...We found both disadvantages and advantages of FFA overproduction...strains. The disadvantage was the...for sustainable energy: Biochemical...gasoline-secreting diatom solar panels . Ind Eng...

Xinyao Liu; Jie Sheng; Roy Curtiss III

2011-01-01T23:59:59.000Z

88

Fatty acid production in genetically modified cyanobacteria  

Science Journals Connector (OSTI)

...on whether they divert energy into production of substantial...strains will result in economical biofuel...235 – 240 . 2 Dept of Energy ( 2008 ) National Algal Fuels...diatoms for sustainable energy: Biochemical engineering...gasoline-secreting diatom solar panels . Ind Eng Chem...

Xinyao Liu; Jie Sheng; Roy Curtiss III

2011-01-01T23:59:59.000Z

89

Materials and methods for efficient lactic acid production  

DOE Patents [OSTI]

The present invention provides derivatives of ethanologenic Escherichia coli K011 constructed for the production of lactic acid. The transformed E. coli of the invention are prepared by deleting the genes that encode competing pathways followed by a growth-based selection for mutants with improved performance. These transformed E. coli are useful for providing an increased supply of lactic acid for use in food and industrial applications.

Zhou, Shengde (Sycamore, IL); Ingram, Lonnie O'Neal (Gainesville, FL); Shanmugam, Keelnatham T. (Gainesville, FL); Yomano, Lorraine (Gainesville, FL); Grabar, Tammy B. (Gainesville, FL); Moore, Jonathan C. (Gainesville, FL)

2009-12-08T23:59:59.000Z

90

Materials and methods for efficient lactic acid production  

DOE Patents [OSTI]

The present invention provides derivatives of Escherichia coli constructed for the production of lactic acid. The transformed E. coli of the invention are prepared by deleting the genes that encode competing pathways followed by a growth-based selection for mutants with improved performance. These transformed E. coli are useful for providing an increased supply of lactic acid for use in food and industrial applications.

Zhou, Shengde; Ingram, Lonnie O'Neal; Shanmugam, Keelnatham T; Yomano, Lorraine; Grabar, Tammy B; Moore, Jonathan C

2013-04-23T23:59:59.000Z

91

Production of Butyric Acid and Butanol from Biomass  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Production of Butyric Acid and Butanol from Biomass Production of Butyric Acid and Butanol from Biomass Final Report Work Performed Under: Contract No.: DE-F-G02-00ER86106 For: U.S. Department of Energy Morgantown, WV By David Ramey Environmental Energy Inc. 1253 N. Waggoner Road P.O. Box 15 Blacklick, Ohio 43004 And Shang-Tian Yang Department of Chemical and Biomolecular Engineering The Ohio State University 140 West 19 th Avenue Columbus, Ohio 43210 - 2004 - Table of Contents Page Proposal Face Page ..........................................................................................................................1 Table of Contents.............................................................................................................................2 Executive Summary

92

Mechanism of Nitric Oxide Reactivity and Fluorescence Enhancement of the NO-Specific Probe CuFL1  

E-Print Network [OSTI]

The mechanism of the reaction of CuFL1 (FL1 = 2-{2-chloro-6-hydroxy-5-[(2-methylquinolin-8-ylamino)methyl]-3-oxo-3H-xanthen-9-yl}benzoic acid) with nitric oxide (NO) to form the N-nitrosated product FL1-NO in buffered ...

McQuade, Lindsey E.

93

Microbial reverse-electrodialysis chemical-production cell for acid and alkali production  

E-Print Network [OSTI]

Microbial reverse-electrodialysis chemical-production cell for acid and alkali production Xiuping Accepted 7 March 2013 Available online 15 March 2013 Keywords: Microbial fuel cell Reverse electrodialysis Bioenergy A new type of bioelectrochemical system, called a microbial reverse-electrodialysis chemical

94

Production of levulinic acid from glucosamine by dilute-acid catalyzed hydrothermal process  

Science Journals Connector (OSTI)

Abstract Glucosamine is a basic unit of the chitin/chitosan structure, which is derived from crustacean (e.g. crab, shrimp) and insect shells. In this study, the production of levulinic acid (LA) from glucosamine via dilute-acid-catalyzed hydrothermal hydrolysis was investigated. Among the reaction conditions, reaction temperature, reaction time, and substrate concentration were more effective than catalyst concentration. The optimal conditions for LA production, as determined by the response-surface methodology (RSM), were as follows: 188 °C reaction temperature, 4 wt% catalyst concentration, 49 min reaction time, 120 g/L substrate concentration. Under these conditions, the LA yield was 30.3 g/L (25.3 wt%), while the 5-HMF concentration was zero. These results might provide basic knowledge essential to the production of valuable chemicals derivable from renewable marine resources and utilizable as fuel additives and polymer building blocks.

Gwi-Taek Jeong

2014-01-01T23:59:59.000Z

95

MAGNESIUM ABSORPTION IN THE CCUM OF RATS RELATED TO VOLATILE FATTY ACIDS PRODUCTION  

E-Print Network [OSTI]

MAGNESIUM ABSORPTION IN THE C�CUM OF RATS RELATED TO VOLATILE FATTY ACIDS PRODUCTION Y. RAYSSIGUIER RELATIONS ENTRE L'ABSORPTION C,4ECALE DE MAGNESIUM CHEZ LE RAT ET LA PRODUCTION D'ACIDES GRAS VOLATILS du caecum, pH, acides gras volatils, activité microbienne. Introduction The mode of magnesium

Paris-Sud XI, Université de

96

Recovery of mercury from acid waste residues  

DOE Patents [OSTI]

Mercury can be recovered from nitric acid-containing fluids by reacting the fluid with aluminum metal to produce mercury metal, and then quenching the reactivity of the nitric acid prior to nitration of the mercury metal.

Greenhalgh, Wilbur O. (Richland, WA)

1989-01-01T23:59:59.000Z

97

Recovery of mercury from acid waste residues  

DOE Patents [OSTI]

Mercury can be recovered from nitric acid-containing fluids by reacting the fluid with aluminum metal to produce mercury metal, and thence quenching the reactivity of the nitric acid prior to nitration of the mercury metal. 1 fig.

Greenhalgh, W.O.

1987-02-27T23:59:59.000Z

98

Biological Hydrogen Production Using Synthetic Wastewater Biotin and glutamic acid are not required for biological hydrogen production.  

E-Print Network [OSTI]

Biological Hydrogen Production Using Synthetic Wastewater Conclusion ·Biotin and glutamic acid are not required for biological hydrogen production. ·MgSO4 .7H2O is a required nutrient, but hydrogen production work should focus on minimizing the lag time in biological hydrogen production, by varying nutrient

Barthelat, Francois

99

A novel recycling process using the treated citric acid wastewater as ingredients water for citric acid production  

Science Journals Connector (OSTI)

Abstract In this study, an integrated process coupling citric acid and methane fermentations was proposed to solve severe wastewater pollution problem in cassava-based citric acid production. The accumulation patterns of the potential and major inhibitors in this process, including organic compounds, volatile fatty acids (VFAs), total ions and pigments were investigated. Both simulation and experimental results indicated that these inhibitors could reach their equilibrium levels after 3–7 fermentation runs when reutilizing the treated citric acid wastewater. As a result, the proposed citric acid fermentation process by recycling the wastewater treated in methane fermentation could be stably operated for more than 15 runs, which could save a large amount of fresh water and relieve the severe wastewater pollution in citric acid production potentially.

Hong-Jian Zhang; Jian-Hua Zhang; Jian Xu; Lei Tang; Zhong-Gui Mao

2014-01-01T23:59:59.000Z

100

Process for combined control of mercury and nitric oxide.  

SciTech Connect (OSTI)

Continuing concern about the effects of mercury in the environment may lead to requirements for the control of mercury emissions from coal-fired power plants. If such controls are mandated, the use of existing flue-gas cleanup systems, such as wet scrubbers currently employed for flue-gas desulfurization, would be desirable, Such scrubbers have been shown to be effective for capturing oxidized forms of mercury, but cannot capture the very insoluble elemental mercury (Hg{sup 0}) that can form a significant fraction of the total emissions. At Argonne National Laboratory, we have proposed and tested a concept for enhancing removal of Hg{sup 0}, as well as nitric oxide, through introduction of an oxidizing agent into the flue gas upstream of a scrubber, which readily absorbs the soluble reaction products. Recently, we developed a new method for introducing the oxidizing agent into the flue-gas stream that dramatically improved reactant utilization. The oxidizing agent employed was NOXSORB{trademark}, which is a commercial product containing chloric acid and sodium chlorate. When a dilute solution of this agent was introduced into a gas stream containing Hg{sup 0} and other typical flue-gas species at 300 F, we found that about 100% of the mercury was removed from the gas phase and recovered in process liquids. At the same time, approximately 80% of the nitric oxide was removed. The effect of sulfur dioxide on this process was also investigated and the results showed that it slightly decreased the amount of Hg{sup 0} oxidized while appearing to increase the removal of nitric oxide from the gas phase. We are currently testing the effects of variations in NOXSORB{trademark} concentration, sulfur dioxide concentration, nitric oxide concentration, and reaction time (residence time). Preliminary economic projections based on the results to date indicate that the chemical cost for nitric oxide oxidation could be less than $5,000/ton removed, while for Hg{sup 0} oxidation it would be about $20,000/lb removed.

Livengood, C. D.; Mendelsohn, M. H.

1999-11-03T23:59:59.000Z

Note: This page contains sample records for the topic "nitric acid production" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

E-Print Network 3.0 - acid fermentative production Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

SUPPLY Summary: , (12) PC for process monitoring. 2.4 Shake flask fermentations acid Biogas Step 1 Wet oxidation Step 2... ETHANOL PRODUCTION FROM DIFFERENT CARBON SOURCES USING...

102

Non-phosphate degradation products of tributyl phosphate  

SciTech Connect (OSTI)

Tributyl phosphate(TBP) was compulsively degraded with nitric acid and/or uranium nitrate at elevated temperature around 105{degrees}C. Experimental results indicates major non-phosphate degradation products are butyl nitrate (C{sub 4}H{sub 9}NO{sub 3}), propionic acid (C{sub 2}H{sub 5}COOH), acetic acid (CH{sub 3}COOH), butyric acid (C{sub 3}H{sub 7}COOH) and butyl alcohol (C{sub 4}H{sub 9}OH) in ascending order of quantity. Degrading rate in uranium free system is less than that in uranium coexisting system. Carboxylic acids were not produced in uranium free system, and only acetic acid was identified in case of without supplying nitric acid from aqueous phase. Moreover, from the experimental study on the reactivity of each non-phosphate product with nitric acid, carboxylic acids were identified as byproducts of butyl alcohol and butyl nitrate, and each carboxylic acid was stable in these degrading conditions. Finally, butyl alcohol is considered as one of intermediate products to butyl nitrate and carboxylic acids. From this study, the non-phosphate degradation products of TBP is identified and the degrading reaction pass is proposed. Extraction behavior of each non-phosphate product and reactivity of degraded TBP are also elucidated.

Tashiro, Y.; Kodama, R.; Sugai, H. [Japan Nuclear Fuel Ltd., Aomori (Japan)] [and others

1995-12-01T23:59:59.000Z

103

Nonphosphate Degradation Products of Tributyl Phosphate and Their Reactivities in Purex Media Under Extreme Conditions  

SciTech Connect (OSTI)

The chemical degradation of tributyl phosphate (TBP) in liquid systems, where TBP was in contact with aqueous solutions containing nitric acid and/or uranyl nitrate, was studied experimentally to clarify the mechanisms of the formation and successive reactions of nonphosphate products under atmospheric pressure. Butyl nitrate, propionic acid, acetic acid, butric acid, and butyl alcohol were formed as the nonphosphate butyl products derived from the butyl-groups of TBP in an open system. The total amount of these products almost equals the amount of the major intermediate phosphate products reduced, i.e., di- and monobutyl phosphates and phosphoric acid. Butyl alcohol was found to be the precursor of the other nonphosphate products.Even when the extremely degraded solvent was further contacted with 10 M nitric acid at 90 deg. C, no significant heat evolution was observed at atmospheric pressure. Only butyl alcohol changed into carboxylic acids by exothermic oxidative reactions.

Tashiro, Yoshikazu [Sumitomo Metal Mining Company, Ltd. (Japan); Kodama, Ryuji [Sumitomo Metal Mining Company, Ltd. (Japan); Sugai, Hiroshi [Sumitomo Metal Mining Company, Ltd. (Japan); Suzuki, Katsuhiko [Japan Nuclear Fuel, Ltd. (Japan); Matsuoka, Shingo [Japan Nuclear Fuel, Ltd. (Japan)

2000-01-15T23:59:59.000Z

104

Reactions Between Water Soluble Organic Acids and Nitrates in...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Between Water Soluble Organic Acids and Nitrates in Atmospheric Aerosols: Recycling of Nitric Acid and Formation of Reactions Between Water Soluble Organic Acids and Nitrates in...

105

Distribution of 1-butanol between organic solvent and acidic solution  

SciTech Connect (OSTI)

1-butanol, a major TBP-degraded product, is known to react explosively with concentrated nitric acid under non-heated conditions. However, no quantitative data is available on the distribution behavior in the Purex solution. The distribution of 1-butanol between tributyl phosphate(TBP) diluted with n-dodecane and aqueous solution of nitric acid and uranyl nitrate was investigated under various conditions, by changing the concentration of nitric acid, uranyl nitrate, the composition of the organic mixture, the organic to aqueous phase volume ratio, and temperature. 1-butanol was found to distribute more in solvent phase, but the distribution ratio is not large, less than four under typical Purex solution conditions. The ratio was found to be correlated with the molar concentration of free TBP and 1-butanol. Effects of these characteristics on safety in radiochemical plants will be discussed from the local accumulation of 1-butanol.

Asakura, T.; Nemoto, H.; Uchiyama, G. [Japan Atomic Energy Research Institute, Ibaraki-ken (Japan)] [and others

1995-12-01T23:59:59.000Z

106

Production of Butyric Acid and Butanol from Biomass  

SciTech Connect (OSTI)

Environmental Energy Inc has shown that BUTANOL REPLACES GASOLINE - 100 pct and has no pollution problems, and further proved it is possible to produce 2.5 gallons of butanol per bushel corn at a production cost of less than $1.00 per gallon. There are 25 pct more Btu-s available and an additional 17 pct more from hydrogen given off, from the same corn when making butanol instead of ethanol that is 42 pct more Btu-s more energy out than it takes to make - that is the plow to tire equation is positive for butanol. Butanol is far safer to handle than gasoline or ethanol. Butanol when substituted for gasoline gives better gas mileage and does not pollute as attested to in 10 states. Butanol should now receive the same recognition as a fuel alcohol in U.S. legislation as ethanol. There are many benefits to this technology in that Butanol replaces gasoline gallon for gallon as demonstrated in a 10,000 miles trip across the United States July-August 2005. No modifications at all were made to a 1992 Buick Park Avenue; essentially your family car can go down the road on Butanol today with no modifications, Butanol replaces gasoline. It is that simple. Since Butanol replaces gasoline more Butanol needs to be made. There are many small farms across America which can grow energy crops and they can easily apply this technology. There is also an abundance of plant biomass present as low-value agricultural commodities or processing wastes requiring proper disposal to avoid pollution problems. One example is in the corn refinery industry with 10 million metric tons of corn byproducts that pose significant environmental problems. Whey lactose presents another waste management problem, 123,000 metric tons US, which can now be turned into automobile fuel. The fibrous bed bioreactor - FBB - with cells immobilized in the fibrous matrix packed in the reactor has been successfully used for several organic acid fermentations, including butyric and propionic acids with greatly increased reactor productivity, final product concentration, and product yield. Other advantages of the FBB include efficient and continuous operation without requiring repeated inoculation, elimination of cell lag phase, good long-term stability, self cleaning and easier downstream processing. The excellent reactor performance of the FBB can be attributed to the high viable cell density maintained in the bioreactor as a result of the unique cell immobilization mechanism within the porous fibrous matrix Since Butanol replaces gasoline in any car today - right now, its manufacturing from biomass is the focus of EEI and in the long term production of our transportation fuel from biomass will stabilize the cost of our fuel - the underpinning of all commerce. As a Strategic Chemical Butanol has a ready market as an industrial solvent used primarily as paint thinner which sells for twice the price of gasoline and is one entry point for the Company into an established market. However, butanol has demonstrated it is an excellent replacement for gasoline-gallon for gallon. The EEI process has made the economics of producing butanol from biomass for both uses very compelling. With the current costs for gasoline at $3.00 per gallon various size farmstead turn-key Butanol BioRefineries are proposed for 50-1,000 acre farms, to produce butanol as a fuel locally and sold locally. All butanol supplies worldwide are currently being produced from petroleum for $1.50 per gallon and selling for $3.80 wholesale. With the increasing price of gasoline it becomes feasible to manufacture and sell Butanol as a clean-safe replacement for gasoline. Grown locally - sold locally at gas prices. A 500 acre farm at 120 bushels corn per acre would make $150,000 at $2.50 per bushel for its corn, when turned into 150,000 gallons Butanol per year at 2.5 gallons per bushel the gross income would be $430,000. Butanol-s advantage is the fact that no other agricultural product made can be put directly into your gas tank without modifying your car. The farmer making and selling locally has no overhead for shippi

David E. Ramey; Shang-Tian Yang

2005-08-25T23:59:59.000Z

107

Recombinant microorganisms for increased production of organic acids  

DOE Patents [OSTI]

Disclosed are recombinant microorganisms for producing organic acids. The recombinant microorganisms express a polypeptide that has the enzymatic activity of an enzyme that is utilized in the pentose phosphate cycle. The recombinant microorganism may include recombinant Actinobacillus succinogenes that has been transformed to express a Zwischenferment (Zwf) gene. The recombinant microorganisms may be useful in fermentation processes for producing organic acids such as succinic acid and lactic acid. Also disclosed are novel plasmids that are useful for transforming microorganisms to produce recombinant microorganisms that express enzymes such as Zwf.

Yi, Jian; Kleff, Susanne; Guettler, Michael V

2013-04-30T23:59:59.000Z

108

Recombinant microorganisms for increased production of organic acids  

DOE Patents [OSTI]

Disclosed are recombinant microorganisms for producing organic acids. The recombinant microorganisms express a polypeptide that has the enzymatic activity of an enzyme that is utilized in the pentose phosphate cycle. The recombinant microorganism may include recombinant Actinobacillus succinogenes that has been transformed to express a Zwischenferment (Zwf) gene. The recombinant microorganisms may be useful in fermentation processes for producing organic acids such as succinic acid and lactic acid. Also disclosed are novel plasmids that are useful for transforming microorganisms to produce recombinant microorganisms that express enzymes such as Zwf.

Yi, Jian (East Lansing, MI); Kleff, Susanne (East Lansing, MI); Guettler, Michael V. (Holt, MI)

2012-02-21T23:59:59.000Z

109

Production of amino acids using auxotrophic mutants of methylotrophic bacillus  

SciTech Connect (OSTI)

A method of producing amino acids by culturing an amino acid auxotroph of a biologically pure strain of a type I methylotrophic bacterium of the genus Bacillus which exhibits sustained growth at 50.degree. C. using methanol as a carbon and energy source and requiring vitamin B.sub.12 and biotin is provided.

Hanson, Richard S. (Wayzata, MN); Flickinger, Michael C. (St. Paul, MN); Schendel, Frederick J. (Falcon Heights, MN); Guettler, Michael V. (Waconia, MN)

2001-07-17T23:59:59.000Z

110

Scaleable production and separation of fermentation-derived acetic acid. Final CRADA report.  

SciTech Connect (OSTI)

Half of U.S. acetic acid production is used in manufacturing vinyl acetate monomer (VAM) and is economical only in very large production plants. Nearly 80% of the VAM is produced by methanol carbonylation, which requires high temperatures and exotic construction materials and is energy intensive. Fermentation-derived acetic acid production allows for small-scale production at low temperatures, significantly reducing the energy requirement of the process. The goal of the project is to develop a scaleable production and separation process for fermentation-derived acetic acid. Synthesis gas (syngas) will be fermented to acetic acid, and the fermentation broth will be continuously neutralized with ammonia. The acetic acid product will be recovered from the ammonium acid broth using vapor-based membrane separation technology. The process is summarized in Figure 1. The two technical challenges to success are selecting and developing (1) microbial strains that efficiently ferment syngas to acetic acid in high salt environments and (2) membranes that efficiently separate ammonia from the acetic acid/water mixture and are stable at high enough temperature to facilitate high thermal cracking of the ammonium acetate salt. Fermentation - Microbial strains were procured from a variety of public culture collections (Table 1). Strains were incubated and grown in the presence of the ammonium acetate product and the fastest growing cultures were selected and incubated at higher product concentrations. An example of the performance of a selected culture is shown in Figure 2. Separations - Several membranes were considered. Testing was performed on a new product line produced by Sulzer Chemtech (Germany). These are tubular ceramic membranes with weak acid functionality (see Figure 3). The following results were observed: (1) The membranes were relatively fragile in a laboratory setting; (2) Thermally stable {at} 130 C in hot organic acids; (3) Acetic acid rejection > 99%; and (4) Moderate ammonia flux. The advantages of producing acetic acid by fermentation include its appropriateness for small-scale production, lower cost feedstocks, low energy membrane-based purification, and lower temperature and pressure requirements. Potential energy savings of using fermentation are estimated to be approximately 14 trillion Btu by 2020 from a reduction in natural gas use. Decreased transportation needs with regional plants will eliminate approximately 200 million gallons of diesel consumption, for combined savings of 45 trillion Btu. If the fermentation process captures new acetic acid production, savings could include an additional 5 trillion Btu from production and 7 trillion Btu from transportation energy.

Snyder, S. W.; Energy Systems

2010-02-08T23:59:59.000Z

111

Remedial Investigation Report on the Abandoned Nitric Acid Pipeline at the Oak Ridge Y-12 Plant, Oak Ridge, Tennessee. Energy Systems Environmental Restoration Program; Y-12 Environmental Restoration Program  

SciTech Connect (OSTI)

Upper East Fork Poplar Creek Operable Unit 2 consists of the Abandoned Nitric Acid pipeline (ANAP). This pipeline was installed in 1951 to transport liquid wastes {approximately}4800 ft from Buildings 9212, 9215, and 9206 to the S-3 Ponds. Materials known to have been discharged through the pipeline include nitric acid, depleted and enriched uranium, various metal nitrates, salts, and lead skimmings. During the mid-1980s, sections of the pipeline were removed during various construction projects. A total of 19 locations were chosen to be investigated along the pipeline for the first phase of this Remedial Investigation. Sampling consisted of drilling down to obtain a soil sample at a depth immediately below the pipeline. Additional samples were obtained deeper in the subsurface depending upon the depth of the pipeline, the depth of the water table, and the point of auger refusal. The 19 samples collected below the pipeline were analyzed by the Oak Ridge Y-12 Plant`s laboratory for metals, nitrate/nitrite, and isotopic uranium. Samples collected from three boreholes were also analyzed for volatile organic compounds because these samples produced a response with organic vapor monitoring equipment. Uranium activities in the soil samples ranged from 0.53 to 13.0 pCi/g for {sup 238}U, from 0.075 to 0.75 pCi/g for {sup 235}U, and from 0.71 to 5.0 pCi/g for {sup 238}U. Maximum total values for lead, chromium, and nickel were 75.1 mg/kg, 56.3 mg/kg, and 53.0 mg/kg, respectively. The maximum nitrate/nitrite value detected was 32.0 mg-N/kg. One sample obtained adjacent to a sewer line contained various organic compounds, at least some of which were tentatively identified as fragrance chemicals commonly associated with soaps and cleaning solutions. The results of the baseline human health risk assessment for the ANAP contaminants of potential concern show no unacceptable risks to human health.

Not Available

1994-02-01T23:59:59.000Z

112

Production of Benzene Polycarboxylic Acids from Lignite by Alkali-Oxygen Oxidation  

Science Journals Connector (OSTI)

Production of Benzene Polycarboxylic Acids from Lignite by Alkali-Oxygen Oxidation ... The oxidation of coal to produce high-valued benzene polycarboxylic acids (BPCAs), which are obtained currently from diminishing petroleum reserves, is a promising industrial process of the future. ...

Wenhua Wang; Yucui Hou; Weize Wu; Muge Niu; Weina Liu

2012-10-22T23:59:59.000Z

113

Mutant E. coli strain with increased succinic acid production  

DOE Patents [OSTI]

A method for isolating succinic acid producing bacteria is provided comprising increasing the biomass of an organism which lacks the ability to catabolize pyruvate, and then subjecting the biomass to glucose-rich medium in an anaerobic environment to enable pyruvate-catabolizing mutants to grow. The invention also provides for a mutant that produces high amounts of succinic acid, which has been derived from a parent which lacked the genes for pyruvate formate lyase and lactate dehydrogenase, and which belongs to the E.coli Group of Bacteria.

Donnelly, Mark (Warrenville, IL); Millard, Cynthia S. (Plainfield, IL); Stols, Lucy (Woodridge, IL)

2002-01-01T23:59:59.000Z

114

I. Nuclear Production Reaction and Chemical Isolation Procedure for 240Am II. New Superheavy Element Isotopes: 242Pu(48Ca,5n)285-114  

E-Print Network [OSTI]

nitric acid solutions are selectively extracted by organophosphorus extrac- tants such as tributyl phosphate (TBP) [

Ellison, Paul Andrew

2011-01-01T23:59:59.000Z

115

E-Print Network 3.0 - acid alkyl esters Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Nitric Acid 34. Sulfuric acid... .5 will not be accepted through this program. Heavy metal, toxic, acidic (without solvents) and basic wastes should... . Mercaptans 4. ......

116

E-Print Network 3.0 - ammonia acetic acid Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

fluminic acid, or hydrogen. NITRIC ACID with: acetic... with: water, carbon dioxide, carbon tetrachloride, and other chlorinated hydrocarbons. ACETIC ACID with......

117

Continuous Isosorbide Production From Sorbitol Using Solid Acid Catalysis  

SciTech Connect (OSTI)

This is a final report for a project funded by the US Department of Agriculture and managed by the US Department of Energy. The Iowa Corn Promotion Board was the principal contracting entity for the grant. The Iowa Corn Promotion Board subcontracted with General Electric, Pacific Northwest National Lab and New Jersey Institute of Technology to conduct research in this project. The Iowa Corn Promotion Board and General Electric provided cost share for the project. The purpose of this diverse collaboration was to integrate both the conversion and the polymer applications into one project and increase the likelihood of success. This project has led to additional collaborations among other polymer companies. The goals of the project were to develop a renewable route to isosorbide for commercialization that is economically competitive with all existing production technologies and to develop new applications for isosorbide in various products such as polymers and materials. Under this program a novel process for the production of isosorbide was developed and evaluated. The novel process converts corn based sorbitol into isosorbide using a solid catalyst with integrated water removal and product recovery. In addition the work under this program has identified several novel products based on isosorbide chemistries. These market applications include: epoxy resins, UV stabilizers, plasticizers and polyesters. These market applications have commercial interest within the current polymer industry. This report contains an overview summary of the accomplishments. Six inventions and four patent applications have been written as a result of this project. Additional data will be published in the patent applications. The data developed at New Jersey Institute of Technology was presented at two technical conferences held in June of 2006. Several companies have made inquiries about using this material in their products.

Williamson, R.; Holladay,J.; Jaffe, M.; Brunelle, D.

2006-09-29T23:59:59.000Z

118

Transuranic decontamination of nitric acid solutions by the TRUEX solvent extraction process: preliminary development studies. [Octyl(phenyl)-N,N-diisobutylcarbamoylmethylphosphine oxide  

SciTech Connect (OSTI)

This report summarizes the work that has been performed to date at Argonne National Laboratory on the development of the TRUEX process, a solvent extraction process employing a bifunctional organophosphorous reagent in a PUREX process solvent (tributyl phosphate-normal paraffinic hydrocarbons). The purpose of this extraction process is to separate and concentrate transuranic (TRU) elements from nuclear waste. Assessments were made of the use of two TRUEX solvents: one incorporating the well-studied dihexyl-N,N-diethylcarbamoylmethylphosphonate (DHDECMP) and a second incorporating an extractant with superior properties for a 1M HNO/sub 3/ acid feed, octyl(phenyl)-N,N-diisobutylcarbamoylmethylphosphine oxide (O/sub phi/D(IB)CMPO). In this report, conceptual flowsheets for the removal of soluble TRUs from high-level nuclear wastes using these two TRUEX proces solvents are presented, and flowsheet features are discussed in detail. The conceptual flowsheet for TRU-element removal from a PUREX waste by the O/sub phi/D(IB)CMPO-TRUEX process solvent was tested in a bench-scale countercurrent experiment, and results of that experiment are presented and discussed. The conclusion of this study is that the TRUEX process is able to separate TRUs from high-level wastes so that the major portion of the solid waste (approx. 99%) can be classified as non-TRU. Areas where more experimentation is needed are listed at the end of the report. 45 references, 17 figures, 56 tables.

Vandegrift, G.F.; Leonard, R.A.; Steindler, M.J.; Horwitz, E.P.; Basile, L.J.; Diamond, H.; Kalina, D.G.; Kaplan, L.

1984-07-01T23:59:59.000Z

119

The Essential Amino Acid Content of Cottonseed, Peanut and Soybean Products.  

E-Print Network [OSTI]

7 TEXAS AGRICULTURAL EXPERIMENT STATlON R. D. LEWIS, Director College Station, Texaa BULLETIN NO. 692 SEPTEMBER 1947 The Essential Amino Acid Content of Cottonseed, Peanut and Soybean Products CARL M. LYMAN, KENNETH KUIKEN and FRED HALE... With the technical assistance of Shirley Dieterich, Marjory Bradford and Mary Trant AGRICULTURAL AND MECHANICAL COLLEGE OF TEXAS GIBB GILCHRIST, President - [Blank Page in Original Bulletin] Preface . - - -- - . meals seed, Ili5tid hmino acids...

Hale, Fred; Kuiken, Kenneth A. (Kenneth Alfred); Lyman, Carl M. (Carl Morris)

1947-01-01T23:59:59.000Z

120

The effects of glutathione on the production of free fatty acids in Cheddar cheese slurries  

E-Print Network [OSTI]

THE EFFECTS OF GLUTATHIONE ON THE PRUDUCTIUN OF FREE FATTY ACIDS IN CHEDDAR CHEESE SLURRIFS A Thesis by JANE MARGUERITE BROUSSARD Submitted to the Graduate College of Texas AAM University in partial fulfillment of the requirements... for the degree MASTER OF SCIENCE May 1986 Major Subuect: Food Science and Technology THE EFFECTS UF GLUTATHIONE ON THE PRODUCTION OF FREE FATTY ACIDS IN CHEDDAR CHEESE SLURRIES A Thesis by JANE MARGUERITE HROUSSARD Approved as to style and content...

Broussard, Jane Marguerite

2012-06-07T23:59:59.000Z

Note: This page contains sample records for the topic "nitric acid production" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Production and mitigation of acid chlorides in geothermal steam  

SciTech Connect (OSTI)

Measurements of the equilibrium distribution of relatively nonvolatile solutes between aqueous liquid and vapor phases have been made at temperatures to 350{degrees}C for HCl(aq) and chloride salts. These data are directly applicable to problems of corrosive-steam production in geothermal steam systems. Compositions of high-temperature brines which could produce steam having given concentrations of chlorides may be estimated at various boiling temperatures. Effects of mitigation methods (e.g., desuperheating) can be calculated based on liquid-vapor equilibrium constants and solute mass balances under vapor-saturation conditions.

Simonson, J.M.; Palmer, D.A.

1995-06-01T23:59:59.000Z

122

Microbial engineering for the production of fatty acids and fatty acid derivatives  

DOE Patents [OSTI]

Some aspects of this invention relate to methods useful for the conversion of a carbon source to a biofuel or biofuel precursor using engineered microbes. Some aspects of this invention relate to the discovery of a key regulator of lipid metabolism in microbes. Some aspects of this invention relate to engineered microbes for biofuel or biofuel precursor production.

Stephanopoulos, Gregory; Abidi, Syed Hussain Imam

2014-07-01T23:59:59.000Z

123

Expression of a coriander desaturase results in petroselinic acid production in transgenic tobacco  

SciTech Connect (OSTI)

Little is known about the metabolic origin of petroselinic acid (18:1[Delta][sup 6cis]), the principal fatty acid of the seed oil of most Umbelliferae, Araliaceae, and Garryaceae species. To examine the possibility that petroselinic acid is the product of an acyl-acyl carrier protein (ACP) desaturase, Western blots of coriander and other Umbelliferae seed extracts were probed with antibodies against the [Delta][sup 9]-stearoyl-ACP desaturase of avocado. In these extracts, proteins of 39 and 36 kDa were detected. Of these, only the 36-kDa peptide was specific to tissues which synthesize petroselinic acid. A cDNA encoding the 36-kDa peptide was isolated from a coriander endosperm cDNA library, placed under control of the cauliflower mosaic virus 35S promoter, and introduced into tobacco by Agrobacterium tumefaciens-mediated transformation. Expression of this cDNA in transgenic tobacco callus was accompanied by the accumulation of petroselinic acid and [Delta][sup 4]-hexadecenoic acid, both of which were absent from control callus. These results demonstrate the involvement of a 36-kDa putative acyl-ACP desaturase in the biosynthetic pathway of petroselinic acid and the ability to produce fatty acids of unusual structure in transgenic plants by the expression of the gene for this desaturase. 27 refs., 5 figs.

Cahoon, E.B.; Shanklin, J.; Ohlrogge, J.B. (Michigan State Univ., East Lansing (United States))

1992-12-01T23:59:59.000Z

124

Analysis of acidity production during enhanced reductive dechlorination using a simplified reactive  

E-Print Network [OSTI]

on identifying and developing innovative remediation schemes. Chlorinated solvents degrade slowly in natural acidification in a contaminated site were examined, and the extent to which the remediation efficiency the accumulation of acidic products. As a consequence, the flow rate corresponding to the highest remediation

125

Biological production of acetic acid from waste gases with Clostridium ljungdahlii  

DOE Patents [OSTI]

A method and apparatus are disclosed for converting waste gases from industrial processes such as oil refining, carbon black, coke, ammonia, and methanol production, into useful products. The method includes introducing the waste gases into a bioreactor where they are fermented to various organic acids or alcohols by anaerobic bacteria within the bioreactor. These valuable end products are then recovered, separated and purified. In an exemplary recovery process, the bioreactor raffinate is passed through an extraction chamber into which one or more non-inhibitory solvents are simultaneously introduced to extract the product. Then, the product is separated from the solvent by distillation. Gas conversion rates can be maximized by use of centrifuges, hollow fiber membranes, or other means of ultrafiltration to return entrained anaerobic bacteria from the bioreactor raffinate to the bioreactor itself, thus insuring the highest possible cell concentration. 5 figs.

Gaddy, J.L.

1998-09-15T23:59:59.000Z

126

Digestion and rumen volatile fatty acid production by heifers fed reconstituted sorghum grain  

E-Print Network [OSTI]

ce oE M. STER OF SCIENCE January 1969 major Sub dace: Anbmal Science DIGESTION AND RlRCEN VOLATILE FATTY ACE) PRODUCTION BY REIZERS . "~ RECONSTITUTED SCRCEWI GRAIN A Tbests EDUARDO J. FA'is'I XM Approved as to s /le and oontent by...) Appendix 'cable Page Analyses of Variance of Volatile Patty Acids in liicrnno~es/Ill& liliter of Bmaen PluM Analyses of Variance of Nolo Percent Volatile Patty Acids in Ruraen gamples A9 CHAPTER I INTRODUCTION Sorghum grain i. s the principal...

Pantin, Eduardo Jose

1969-01-01T23:59:59.000Z

127

Continuous biodiesel production from acidic oil using a combination of cation- and anion-exchange resins  

Science Journals Connector (OSTI)

Abstract A continuous process was developed to produce biodiesel from acidic oil containing soybean oil and oleic acid, which combined esterification by cation-exchange resin NKC-9, online separation and transesterification by anion-exchange resin D261. The esterification was carried out with soybean oil/oleic acid weight ratio of 5/5, methanol to oleic acid weight ratio of 1.5/1, reaction temperature of 338 K and residence time of 126.6 min. After the reaction, the mixture was settled to online separate into two layers, and the methanol–water–oleic acid mixture at the top layer was reclaimed. The bottom layer, mainly containing soybean oil and methyl oleate, was transesterified under methanol/soybean oil weight ratio of 1/3 and n-hexane/soybean oil weight ratio of 1/2 at 323 K for the residence time of 112.0 min. The high conversions of oleic acid (above 98%) and soybean oil (92.3%) were achieved. The yield of biodiesel in this process reached up to 95.1%. The main parameters of the product met the Chinese Standard of biodiesel.

Benqiao He; Yixuan Shao; Yanbiao Ren; Jianxin Li; Yu Cheng

2015-01-01T23:59:59.000Z

128

acid  

Office of Legacy Management (LM)

Acid/Pueblo Canyon, New Mexico, Site is Acid/Pueblo Canyon, New Mexico, Site is located near the town of Los Alamos, New Mexico, approximately 25 miles northwest of Santa Fe and 60 miles north-northeast of Albuquerque. The site is accessible from Canyon Road, which runs just south of the former waste treatment plant. The plant was situated on a mesa that forms the south rim of Acid Canyon. Acid Canyon is a small tributary near the head

129

Screening Microalgae Strains for Biodiesel Production: Lipid Productivity and Estimation of Fuel Quality Based on Fatty Acids Profiles as Selective Criteria  

Science Journals Connector (OSTI)

The viability of algae-based biodiesel industry depends on the selection of adequate ... fatty acid profiles, used for estimating the biodiesel fuel properties. Volumetric lipid productivity varied among...?1 day

Iracema Andrade Nascimento; Sheyla Santa Izabel Marques…

2013-03-01T23:59:59.000Z

130

acid  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Acid/Pueblo Canyon, New Mexico, Site. Acid/Pueblo Canyon, New Mexico, Site. This site is managed by the U.S. Department of Energy Office of Legacy Management. Site Description and History The Acid/Pueblo Canyon, New Mexico, Site is located near the town of Los Alamos, New Mexico, approximately 25 miles northwest of Santa Fe and 60 miles north-northeast of Albuquerque. The site is accessible from Canyon Road, which runs just south

131

Nitric oxide emissions from the high-temperature viscous boundary layers of hypersonic aircraft within the stratosphere  

SciTech Connect (OSTI)

The authors study the nitric oxide emission characteristics of supersonic aircraft resulting from heating of viscous boundary layers along the skin of the aircraft. Previous study has concentrated on nitric oxide emissions coming from combustion products from the scramjet engines. This work shows that above mach 8, emissions from viscous heating become a significant factor in total emission of nitric oxide. Above mach 16 it becomes the dominant source of emission.

Brooks, S.B.; Lewis, M.J.; Dickerson, R.R. [Univ. of Maryland, College Park, MD (United States)

1993-09-20T23:59:59.000Z

132

Acid-Functionalized SBA-15-Type Periodic Mesoporous Organosilicas and Their Use in the Continuous Production of 5-Hydroxymethylfurfural  

Science Journals Connector (OSTI)

Acid-Functionalized SBA-15-Type Periodic Mesoporous Organosilicas and Their Use in the Continuous Production of 5-Hydroxymethylfurfural ... The activity, selectivity, and stability of several supported acid catalysts were evaluated in tubular reactors designed to produce 5-hydroxymethylfurfural (HMF) continuously from fructose dissolved in a single-phase solution of THF and H2O (4:1 w/w). ... 5-hydroxymethylfurfural; continuous dehydration; packed-bed reactor; SBA-15; periodic mesoporous organosilicas; propylsulfonic acid; catalyst deactivation rate ...

Mark H. Tucker; Anthony J. Crisci; Bethany N. Wigington; Neelay Phadke; Ricardo Alamillo; Jinping Zhang; Susannah L. Scott; James A. Dumesic

2012-07-09T23:59:59.000Z

133

Acetic Acid Production by Clostridium thermoaceticum in pH-Controlled Batch Fermentations at Acidic pH  

Science Journals Connector (OSTI)

...and the conversion efficiencies to acetic acid and...neutral pH. The highest acetic acid concentrations...acetic acid, and efficiency of converting glucose...the CO2 was of the highest purity attainable...valve completely and venting for 90 s, closing...ii) A glass furnace tube was packed...

Robert D. Schwartz; Frederick A. Keller Jr.

1982-06-01T23:59:59.000Z

134

Recent advances in the metabolic engineering of microorganisms for the production of 3-hydroxypropionic acid as C3 platform chemical  

Science Journals Connector (OSTI)

Development of sustainable technologies for the production of 3-hydroxypropionic acid (3HP) as a platform chemical has recently been gaining much attention owing ... in applications for the synthesis of other spe...

Kris Niño G. Valdehuesa; Huaiwei Liu…

2013-04-01T23:59:59.000Z

135

Constructing and engineering fatty acid metabolic pathways for the production of fuels and chemicals  

E-Print Network [OSTI]

0 fatty acids in transgenic canola by overexpression of Ch0 fatty acids in transgenic canola by overexpression of Ch

Steen, Eric James

2010-01-01T23:59:59.000Z

136

Production of D-lactic acid from sugarcane bagasse using steam-explosion  

Science Journals Connector (OSTI)

This study investigated the production of D-lactic acid from unutilized sugarcane bagasse using steam explosion pretreatment. The optimal steam pressure for a steaming time of 5 min was determined. By enzymatic saccharification using Meicellase, the highest recovery of glucose from raw bagasse, 73.7%, was obtained at a steam pressure of 20 atm. For residue washed with water after steam explosion, the glucose recovery increased up to 94.9% at a steam pressure of 20 atm. These results showed that washing with water is effective in removing enzymatic reaction inhibitors. After steam pretreatment (steam pressure of 20 atm), D-lactic acid was produced by Lactobacillus delbrueckii NBRC 3534 from the enzymatic hydrolyzate of steam-exploded bagasse and washed residue. The conversion rate of D-lactic acid obtained from the initial glucose concentration was 66.6% for the hydrolyzate derived from steam-exploded bagasse and 90.0% for that derived from the washed residue after steam explosion. These results also demonstrated that the hydrolyzate of steam-exploded bagasse (without washing with water) contains fermentation inhibitors and washing with water can remove them.

Chizuru Sasaki; Ryosuke Okumura; Ai Asakawa; Chikako Asada; Yoshitoshi Nakamura

2012-01-01T23:59:59.000Z

137

Controlling acid rain  

E-Print Network [OSTI]

High concentrations of sulfuric and nitric acid in raTn fn the northeastern USA are caused by the large scale combustion of fossil fuels within this region. Average precipitation acidity is pH 4.2, but spatial and temporal ...

Fay, James A.

1983-01-01T23:59:59.000Z

138

Acidic soil amendment with a magnesium-containing fluidized bed combustion by-product  

SciTech Connect (OSTI)

Removal of SO{sub 2} from the emissions of coal-fired boilers produces by-products that often consist of CaSO{sub 4}, residual alkalinity, and coal ash. These by-products could be beneficial to acidic soils because of their alkalinity and the ability of gypsum (CaSO{sub 4}{center{underscore}dot}2H{sub 2}O) to reduce Al toxicity in acidic subsoils. A 3-yr field experiment was conducted to determine the liming efficacy of a fluidized bed combustion boiler by-product (FBC) that contained 129 g Mg kg{sup {minus}1} as CaMg(CO{sub 3}){sub 2} and MgO and its effects on surface and subsurface soil chemistry. The FBC was mixed in the surface 10 cm of two acidic soils (Wooster silt loam, an Oxyaquic Fragiudalf, and Coshocton silt loam, an Aquultic Hapludalf) at rates of 0, 0.5, 1, and 2 times each soil's lime requirement (LR). Soils were sampled in 10-cm increments to depths ranging from 20 to 110 cm, and corn (Zea mays L.) and alfalfa (Medicago sativa L.) were grown. Application of Mg-FBC increased alfalfa yields in all six site-years, whereas it had no effect on corn grain yield in five site-years and decreased grain yield in one site-year. Plant tissue concentrations of Mg, S, and Mo were increased by Mg-FBC, while most trace elements were either unaffected or decreased. Application of Mg-FBC at one or two times LR increased surface soil pH to near 7 within 1 wk. Although surface soil pH remained near 7 for 2 yr, there was minimal effect on subjacent soil pH. Application of Mg-FBC increased surface soil concentrations of Ca, Mg, and S, which promoted downward movement of Mg and SO{sub 4}. This had different effects on subsoil chemistry in the two soils: in the high-Ca-status Wooster subsoil, exchangeable Ca was decreased and exchangeable Al was increased, whereas in the high-Al-status Coshocton subsoil, exchangeable Al was decreased and exchangeable Mg was increased. The Mg-FBC was an effective liming material and, because of the presence of both Mg and SO{sub 4}, may be more effective than gypsum in ameliorating subsoil Al phytotoxicity.

Stehouwer, R.C.; Dick, W.A.; Sutton, P.

1999-02-01T23:59:59.000Z

139

A new approach for the production of 2,5-furandicarboxylic acid by in situ oxidation of 5-hydroxymethylfurfural starting from fructose  

Science Journals Connector (OSTI)

The production of 2,5-furandicarboxylic acid (FDCA) starting with fructose as substrate via acid-catalyzed formation and subsequent oxidation of 5-hydroxymethylfurfural (HMF) was investigated. It was shown...

Martin Kröger; Ulf Prüße; Klaus-Dieter Vorlop

140

Towards a desalination initiative using cogeneration with an advanced reactor type and uranium recovered from Moroccan phosphoric acid production  

Science Journals Connector (OSTI)

Morocco is known to be among the first few countries to produce phosphate and phosphoric acid. Moroccan phosphate contains substantial amounts of uranium. This uranium can be recovered from the phosphate ore as a by-product during the production of phosphoric acid. Uranium extraction processes linked with phosphoric acid fabrication have been used industrially in some countries. This is done mainly by solvent extraction. Although, the present price of uranium is low in the international market, such uranium recovery could be considered as a side product of phosphoric acid production. The price of uranium has a very small impact on the cost of nuclear energy obtained from it. This paper focuses on the extraction of uranium salt from phosphate rock. If uranium is recovered in Morocco in the proposed manner, it could serve as feed for a number of nuclear power plants. The natural uranium product would have to be either enriched or blended as mixed-oxide fuel to manufacture adequate nuclear fuel. Part of this fuel would feed a desalination initiative using a high temperature reactor of the new generation, chosen for its intrinsic safety, sturdiness, ease of maintenance, thermodynamic characteristics and long fuel life between reloads, that is, good economy. ?n international cooperation based on commercial contract schemes would concern: the general project and uranium extraction; uranium enrichment and fuel fabrication services; the nuclear power plant; and the desalination plant. This paper presents the overall feasibility of the general project with some quantitative preliminary figures and cost estimates.

Michel Lung; Abdelaali Kossir; Driss Msatef

2005-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "nitric acid production" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Comparison of energy potentials from combined ethanol and methane production using steam-pretreated corn stover impregnated with acetic acid  

Science Journals Connector (OSTI)

Abstract Acetic acid was investigated as a catalyst in steam pretreatment of corn stover. The purpose was to study ethanol production using either baker's yeast or a genetically modified pentose-fermenting version of Saccharomyces cerevisiae, KE6-12. Biogas production was investigated as an alternative for utilization of xylose. The high levels of acetic acid was found to be toxic using KE6-12. Some pentose fermentation was achieved, but the ethanol end concentration was almost the same as using baker's yeast (28 g L?1 compared to 27 g L?1). Using xylose for biogas production resulted in a high total energy recovery. The highest total energy recovery in the products, i.e. ethanol, methane and solids, obtained was 88% compared with the energy in ingoing raw material. This result was achieved when the solids and the liquid was separated after pretreatment.

Pia-Maria Bondesson; Mats Galbe; Guido Zacchi

2014-01-01T23:59:59.000Z

142

Lipid content and fatty acid composition of Mediterranean macro-algae as dynamic factors for biodiesel production  

Science Journals Connector (OSTI)

Summary Using the total lipid contents and fatty acid profiles, the marine macro-algae Jania rubens (Rhodophyceae), Ulva linza (Chlorophyceae) and Padina pavonica (Phaeophyceae) were evaluated for biodiesel production during the spring, summer and autumn. Seawater parameters such as pH, salinity and temperature were measured. The total lipid content varied from 1.56% (J. rubens) to 4.14% (U. linza) of dry weight, with the highest values occurring in spring. The fatty acid methyl ester profiles were analysed using gas chromatography. The highest percentage of total fatty acids was recorded in P. pavonica, with 6.2% in autumn, whereas the lowest was in J. rubens, with 68.6% in summer. The relative amount of saturated to unsaturated fatty acids was significantly higher in P. pavonica than in the other macro-algae. Seasonal variations in pH, salinity and temperature had no significant effect on the total lipid and fatty acid contents. Principal component analysis grouped brown and green algae together, whereas red alga grouped out. Furthermore, methyl ester profiles indicate that brown and green seaweeds are preferred, followed by red seaweeds, which appears to have little potential for oil-based products. Therefore, these seaweeds are not targets for biodiesel production.

Dahlia M. El Maghraby; Eman M. Fakhry

2014-01-01T23:59:59.000Z

143

THE EFFECT OF ANOLYTE PRODUCT ACID CONCENTRATION ON HYBRID SULFUR CYCLE PERFORMANCE  

SciTech Connect (OSTI)

The Hybrid Sulfur (HyS) cycle (Fig. 1) is one of the simplest, all-fluids thermochemical cycles that has been devised for splitting water with a high-temperature nuclear or solar heat source. It was originally patented by Brecher and Wu in 1975 and extensively developed by Westinghouse in the late 1970s and early 1980s. As its name suggests, the only element used besides hydrogen and oxygen is sulfur, which is cycled between the +4 and +6 oxidation states. HyS comprises two steps. One is the thermochemical (>800 C) decomposition of sulfuric acid (H{sub 2}SO{sub 4}) to sulfur dioxide (SO{sub 2}), oxygen (O{sub 2}), and water. H{sub 2}SO{sub 4} = SO{sub 2} + 1/2 O{sub 2} + H{sub 2}O. The other is the SO{sub 2}-depolarized electrolysis of water to H{sub 2}SO{sub 4} and hydrogen (H{sub 2}), SO{sub 2} + 2 H{sub 2}O = H{sub 2}SO{sub 4} + H{sub 2}, E{sup o} = -0.156 V, explaining the 'hybrid' designation. These two steps taken together split water into H{sub 2} and O{sub 2} using heat and electricity. Researchers at the Savannah River National Laboratory (SRNL) and at the University of South Carolina (USC) have successfully demonstrated the use of proton exchange membrane (PEM) electrolyzers (Fig. 2) for the SO{sub 2}-depolarized electrolysis (sulfur oxidation) step, while Sandia National Laboratories (SNL) successfully demonstrated the high-temperature sulfuric acid decomposition (sulfur reduction) step using a bayonet-type reactor (Fig. 3). This latter work was performed as part of the Sulfur-Iodine (SI) cycle Integrated Laboratory Scale demonstration at General Atomics (GA). The combination of these two operations results in a simple process that will be more efficient and cost-effective for the massive production of hydrogen than alkaline electrolysis. Recent developments suggest that the use of PEMs other than Nafion will allow sulfuric acid to be produced at higher concentrations (>60 wt%), offering the possibility of net thermal efficiencies around 50% (HHV basis). The effect of operation at higher anolyte concentrations on the flowsheet, and on the net thermal efficiency for a nuclear-heated HyS process, is examined and quantified.

Gorensek, M.; Summers, W.

2010-03-24T23:59:59.000Z

144

Gas Chromatographic Determination of Carboxylic Acid Chlorides and Residual Carboxylic Acid Precursors Used in the Production of Some Penicillins  

Science Journals Connector (OSTI)

......than the usual titration methods, which do not differentiate...analysis Chromatography, Gas methods Drug Industry Hydrogen-Ion Concentration Methods Microchemistry Penicillins...Precursors Used in the Production of Some Penicillins R......

R.G. Lauback; D.F. Balitz; D.L. Mays

1976-05-01T23:59:59.000Z

145

Production of carrier-peptide conjugates using chemically reactive unnatural amino acids  

DOE Patents [OSTI]

Provided are methods of making carrier polypeptide that include incorporating a first unnatural amino acid into a carrier polypeptide variant, incorporating a second unnatural amino acid into a target polypeptide variant, and reacting the first and second unnatural amino acids to produce the conjugate. Conjugates produced using the provided methods are also provided. In addition, orthogonal translation systems in methylotrophic yeast and methods of using these systems to produce carrier and target polypeptide variants comprising unnatural amino acids are provided.

Young, Travis; Schultz, Peter G

2014-01-28T23:59:59.000Z

146

Two Dimensional Polymer That Generates Nitric Oxide.  

DOE Patents [OSTI]

A polymeric composition that generates nitric oxide and a process for rendering the surface of a substrate nonthrombogenic by applying a coating of the polymeric composition to the substrate are disclosed. The composition comprises: (1) a crosslinked chemical combination of (i) a polymer having amino group-containing side chains along a backbone forming the polymer, and (ii) a crosslinking agent containing functional groups capable of reacting with the amino groups; and (2) a plurality of nitric oxide generating functional groups associated with the crosslinked chemical combination. Once exposed to a physiological environment, the coating generates nitric oxide thereby inhibiting platelet aggregation. In one embodiment, the nitric oxide generating functional groups are provided by a nitrated compound (e.g., nitrocellulose) imbedded in the polymeric composition. In another embodiment, the nitric oxide generating functional groups comprise N2O2- groups covalently bonded to amino groups on the polymer.

McDonald, William F. (Utica, OH); Koren, Amy B. (Lansing, MI)

2005-10-04T23:59:59.000Z

147

Monitoring of Total Type II Pyrethroid Pesticides in Citrus Oils and Water by Converting to a Common Product 3-Phenoxybenzoic Acid  

E-Print Network [OSTI]

Monitoring of Total Type II Pyrethroid Pesticides in Citrus Oils and Water by Converting to a Common Product 3-Phenoxybenzoic Acid Mark R. McCoy, Zheng Yang, Xun Fu,§ Ki Chang Ahn, Shirley J. Gee an alternative method that converts the type II pyrethroids to a common chemical product, 3-phenoxybenzoic acid

Hammock, Bruce D.

148

Biodiesel production from algae cultivated in winter with artificial wastewater through pH regulation by acetic acid  

Science Journals Connector (OSTI)

Abstract Algae have been considered as a promising biodiesel feedstock. One of the major factors affecting large-scale algae technology application is poor wintering cultivation performance. In this study, an integrated approach is investigated combining freshwater microalgae Chlorella zofingiensis wintering cultivation in pilot-scale photobioreactors with artificial wastewater treatment. Mixotrophic culture with the addition of acetic acid (pH-regulation group) and autotrophic culture (control group) were designed, and the characteristics of algal growth, lipid and biodiesel production, and nitrogen and phosphate removal were examined. The results showed that, by using acetic acid three times per day to regulate pH at between 6.8 and 7.2, the total nitrogen (TN) and total phosphate (TP) removal could be increased from 45.2% to 73.5% and from 92.2% to 100%, respectively. Higher biomass productivity of 66.94 mg L?1 day?1 with specific growth rate of 0.260 day?1 was achieved in the pH-regulation group. The lipid content was much higher when using acetic acid to regulate pH, and the relative lipid productivity reached 37.48 mg L?1 day?1. The biodiesel yield in the pH-regulated group was 19.44% of dry weight, with 16–18 carbons as the most abundant composition for fatty acid methyl esters. The findings of the study prove that pH adjustment using acetic acid is efficient in cultivating C. zofingiensis in wastewater in winter for biodiesel production and nutrient reduction.

Liandong Zhu; Erkki Hiltunen; Qing Shu; Weizheng Zhou; Zhaohua Li; Zhongming Wang

2014-01-01T23:59:59.000Z

149

Arginine and Conjugated Linoleic Acid Reduce Fat Mass in Rats  

E-Print Network [OSTI]

????????????????????.. 3 Nitric oxide (NO)????????????????????... 3 NOS synthesis by iNOS and obesity?????????????. 4 Stearoyl CoA desaturase?????????????????? 5 Conjugated linoleic acid?????????????????? 5 MATERIALS... on a liquid scintillation counter. 12 Fatty acid analysis Fatty acid composition in liver and plasma was determined using a fatty acid methylation procedure (FAME). Fatty acids were extracted using Folch et al (38) methods. Methylation...

Nall, Jennifer L.

2010-10-12T23:59:59.000Z

150

Raman Scattering Sensor for Control of the Acid Alkylation Process in Gasoline Production  

SciTech Connect (OSTI)

Gasoline refineries utilize a process called acid alkylation to increase the octane rating of blended gasoline, and this is the single most expensive process in the refinery. For process efficiency and safety reasons, the sulfuric acid can only be used while it is in the concentration range of 98 to 86 %. The conventional technique to monitor the acid concentration is time consuming and is typically conducted only a few times per day. This results in running higher acid concentrations than they would like to ensure that the process proceeds uninterrupted. Maintaining an excessively high acid concentration costs the refineries millions of dollars each year. Using SBIR funding, Process Instruments Inc. has developed an inline sensor for real time monitoring of acid concentrations in gasoline refinery alkylation units. Real time data was then collected over time from the instrument and its responses were matched up with the laboratory analysis. A model was then developed to correlate the laboratory acid values to the Raman signal that is transmitted back to the instrument from the process stream. The instrument was then used to demonstrate that it could create real-time predictions of the acid concentrations. The results from this test showed that the instrument could accurately predict the acid concentrations to within ~0.15% acid strength, and this level of prediction proved to be similar or better then the laboratory analysis. By utilizing a sensor for process monitoring the most economic acid concentrations can be maintained. A single smaller refinery (50,000 barrels/day) estimates that they should save over $120,000/year, with larger refineries saving considerably more.

Uibel, Rory, H.; Smith, Lee M.; Benner, Robert, E.

2006-04-19T23:59:59.000Z

151

Production of Sugars and Levulinic Acid from Marine Biomass Gelidium amansii  

Science Journals Connector (OSTI)

5-Hydroxymethylfurfural (HMF) and levulinic acid are versatile biomass-derived platform compounds that can be used to synthesize a broad range of chemicals and are currently derived from petroleum. In addition, l...

Gwi-Taek Jeong; Don-Hee Park

2010-05-01T23:59:59.000Z

152

Chromatographic extraction with di(2-ethylhexyl)orthophosphoric acid for production and purification of promethium-147  

DOE Patents [OSTI]

A method of producing and purifying promethium-147 including the steps of: irradiating a target material including neodymium-146 with neutrons to produce promethium-147 within the irradiated target material; dissolving the irradiated target material to form an acidic solution; loading the acidic solution onto a chromatographic separation apparatus containing HDEHP; and eluting the apparatus to chromatographically separate the promethium-147 from the neodymium-146.

Boll, Rose A [Knoxville, TN

2008-10-14T23:59:59.000Z

153

Escherichia coli Strains Engineered for Homofermentative Production of d-Lactic Acid from Glycerol  

Science Journals Connector (OSTI)

...platforms to produce fuels and chemicals from this...further confirmed by in-vessel measurements conducted...cell growth, glycerol consumption, and product synthesis...for the production of fuels and chemicals. Appl...for the production of fuels and chemicals. We recently...

Suman Mazumdar; James M. Clomburg; Ramon Gonzalez

2010-05-14T23:59:59.000Z

154

Kinetic modeling of nitric oxide removal from exhaust gases by Selective Non-Catalytic Reduction  

E-Print Network [OSTI]

for increased pressure predict a wider temperature range at which significant nitric oxide can be removed and also in the case of RAPRENOx process the levels of N20 (a by-product in the case of the RAPRENOx process) are significantly lower. The accounting...

Chenanda, Cariappa Mudappa

2012-06-07T23:59:59.000Z

155

Modeling gas phase nitric oxide release in lung epithelial cells Jingjing Jiang a  

E-Print Network [OSTI]

Modeling gas phase nitric oxide release in lung epithelial cells Jingjing Jiang a , Steven C- dated our model with experimental results of gas phase NO release and intracellular L enzyme on NO production. Our model predicts intracellular L-arginine and gas phase NO release over a wide

George, Steven C.

156

The effect of product formulation and homogenization on the physical properties of the milk-fat globule and acid milk gels  

E-Print Network [OSTI]

The elect of homogenization pressure and product formulation on the composition physical and chemical properties of acid milk gels was evaluated. Nonfat dry milk, whey protein concentrate (WPC), cream, Span 60 and Tween 20, were combined to prepare...

Materon, Liliana

2012-06-07T23:59:59.000Z

157

A comparison of the products of the hydrolysis of cottonseed meats with acid and alkali  

E-Print Network [OSTI]

?siege that it aer bo qaaatitaiivelr re assed fan% tho brdr?I+esto ae beri~ self?tee Res?Tery hpdreehierfo acid aep bo roasted br or?per?ties aa4?2 redwood pros?are? Sera sob?tea?os ~ pret?iso ~ sa4 golsti& ero totally hrdrelpaed with? oat tho foeaatioa ef...&relrsato was ~ nalyned eoeer4ing te Ae Vea glyhIP nsthod exospt for soreral changes whish will bo ?nplaiaod ia the outline ef the prooednrw whish fnllewsi Ths hydreohlerie acid was reeeed frwa ihe hydrelyeaie nader redwood pressers, the residne was tohon wp with wares...

Schoch, Henry Bernard

2012-06-07T23:59:59.000Z

158

Production of 5-hydroxymethylfurfural from corn stalk catalyzed by corn stalk-derived carbonaceous solid acid catalyst  

Science Journals Connector (OSTI)

Abstract A carbonaceous solid acid was prepared by hydrothermal carbonization of corn stalk followed by sulfonation and was characterized by FT-IR, XRD, SEM and elemental analysis techniques. The as-prepared corn stalk-derived carbonaceous solid acid catalyst contained SO3H, COOH, and phenolic OH groups, and was used for the one-step conversion of intact corn stalk to 5-hydroxymethylfurfural (5-HMF) in the ionic liquid 1-butyl-3-methyl imidazolium chloride ([BMIM][Cl]), where a 5-HMF yield of 44.1% was achieved at 150 °C in 30 min reaction time. The catalytic system was applicable to initial corn stalk concentration of up to ca. 10 wt.% for the production of 5-HMF. The synthesized catalyst and the developed process of using corn stalk-derived carbon catalyst for corn stalk conversion provide a green and efficient strategy for crude biomass utilization.

Lulu Yan; Nian Liu; Yu Wang; Hiroshi Machida; Xinhua Qi

2014-01-01T23:59:59.000Z

159

E-Print Network 3.0 - amino acid production Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Chemistry, University of Missouri-Columbia Collection: Chemistry 24 Rapid Cycling of Organic Nitrogen in Taiga Forest Ecosystems Summary: successional soil as the product of the...

160

Constructing and engineering fatty acid metabolic pathways for the production of fuels and chemicals  

E-Print Network [OSTI]

T. & Cecil, G. Ethanol production: energy, economic, andand clear: ethanol suffers from low energy density, it is8 . Finally, ethanol has a low energy content compared to

Steen, Eric James

2010-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "nitric acid production" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

E-Print Network 3.0 - acid oxidation products Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of oxidized, S-rich mafic magmas for giant Cu mineralization: Evidence from Pinatubo, Bingham Canyon and El Teniente Summary: eruption products show that mafic magma was...

162

Engineering of thermotolerant Bacillus coagulans for production of D(-)-lactic acid  

DOE Patents [OSTI]

Genetically modified microorganisms having the ability to produce D(-)-lactic acid at temperatures between 30.degree. C. and 55.degree. C. are provided. In various embodiments, the microorganisms may have the chromosomal lactate dehydrogenase (ldh) gene and/or the chromosomal acetolactate synthase (alsS) gene inactivated. Exemplary microorganisms for use in the disclosed methods are Bacillus spp., such as Bacillus coagulans.

Wang, Qingzhao; Shanmugam, Keelnatham T; Ingram, Lonnie O

2014-12-02T23:59:59.000Z

163

Photochemistry of Matrix-Isolated and Thin Film Acid Chlorides: Quantum Yields and Product Structures  

E-Print Network [OSTI]

the differences between gas- and condensed-phase photochemistry strengthens our understanding of many, and well-known gas-phase reaction mechanisms are often modified in the condensed phase or completely the photoreaction of condensed acid chloride samples by comparison of reaction quantum yields for acetyl (CH3COCl

Ellison, Barney

164

Engineering the Xylan Utilization System in Bacillus subtilis for Production of Acidic Xylooligosaccharides  

Science Journals Connector (OSTI)

...A and Z Hromadkova. 1999. Xylans of industrial and biomedical...active-site subsites and at the surface of glycoside hydrolase family...4-O-Methyl-alpha-d-glucurono)-d-xylan from Rudbeckia fulgida, var...Immunomodulatory activity of acidic xylans in relation to their structural...

Mun Su Rhee; Lusha Wei; Neha Sawhney; John D. Rice; Franz J. St. John; Jason C. Hurlbert; James F. Preston

2013-11-22T23:59:59.000Z

165

Techno-Economic Study of a Biodiesel Production from Palm Fatty Acid Distillate  

Science Journals Connector (OSTI)

A simulation model for this biodiesel production process has been developed, which provided the basis for the estimation of capital expenditure and operating cost. ... The largest contributors to the equipment cost, accounting for nearly one third of expenditures, were storage tanks to contain a 25 day capacity of feedstock and product. ...

Hyun Jun Cho; Jin-Kuk Kim; Hyun-Jea Cho; Yeong-Koo Yeo

2012-11-19T23:59:59.000Z

166

Escherichia coli Strains Engineered for Homofermentative Production of d-Lactic Acid from Glycerol  

Science Journals Connector (OSTI)

...lactate accumulation upon the introduction of these mutations appears...the pyruvate pool, as the introduction of defects in pta and pflB...by-product in the production of biodiesel supplemented only with mineral...supporting the metabolic engineering strategies employed in this...

Suman Mazumdar; James M. Clomburg; Ramon Gonzalez

2010-05-14T23:59:59.000Z

167

Oleic AcidDependent Modulation of NITRIC OXIDE ASSOCIATED1 Protein Levels Regulates Nitric  

E-Print Network [OSTI]

the generation of monounsaturated FA in plant cells (Shanklin and Cahoon, 1998; Kachroo et al., 2007

Kachroo, Pradeep

168

Ovarian nitric oxide synthase gene expression during peripubertal development  

E-Print Network [OSTI]

Nitric oxide (NO) is generated from L-arginine by different isoforms of the enzyme nitric oxide synthase. (NOS) and is known to be involved in mediating several biological functions, some of which are associated with reproduction. Much attention...

Jones, Benjamin James

1997-01-01T23:59:59.000Z

169

Biodiesel production from algae oil high in free fatty acids by two-step catalytic conversion  

Science Journals Connector (OSTI)

The effect of storage temperature and time on lipid composition of Scenedesmus sp. was studied. When stored at 4 °C or higher, the free fatty acid content in the wet biomass increased from a trace to 62.0% by day 4. Using two-step catalytic conversion, algae oil with a high free fatty acid content was converted to biodiesel by pre-esterification and transesterification. The conversion rate of triacylglycerols reached 100% under the methanol to oil molar ratio of 12:1 during catalysis with 2% potassium hydroxide at 65 °C for 30 min. This process was scaled up to produce biodiesel from Scenedesmus sp. and Nannochloropsis sp. oil. The crude biodiesel was purified using bleaching earth. Except for moisture content, the biodiesel conformed to Chinese National Standards.

Lin Chen; Tianzhong Liu; Wei Zhang; Xiaolin Chen; Junfeng Wang

2012-01-01T23:59:59.000Z

170

Biotechnol. Bioprocess Eng. 2000, 5: 379-381 Fermentative Production of Succinic Acid from Glucose and  

E-Print Network [OSTI]

, but also because CO2, a greenhouse gas, is in- corporated into succinic acid during the fermentation 1 (AnS1) plus 5 g/L glucose, 2.5 g/L polypep- tone, and 2.5 g/L yeast extract with CO2 as the gas the pH to 6.5. The nitrogen headspace was replaced by CO2, and Na2S 9H2O was added to a final

171

Engineering Escherichia coli for Biodiesel Production Utilizing a Bacterial Fatty Acid Methyltransferase  

Science Journals Connector (OSTI)

...Biotechnology Engineering Escherichia coli for Biodiesel Production...demands. Biodiesel is a renewable fuel that can...component of biodiesel and can be...synthesis. INTRODUCTION Biofuel research...1). The engineering of bacteria...

Parwez Nawabi; Stefan Bauer; Nikos Kyrpides; Athanasios Lykidis

2011-09-16T23:59:59.000Z

172

Zeolite deactivation during hydrocarbon reactions: characterisation of coke precursors and acidity, product distribution.  

E-Print Network [OSTI]

??The catalytic conversion of hydrocarbons over zeolites has been applied in large scale petroleum-refining processes. However, there is always formation and retention of heavy by-products,… (more)

Wang, B.

2008-01-01T23:59:59.000Z

173

Pyrolysis products from amino acids and protein: Highest mutagenicity requires cytochrome P1-450  

Science Journals Connector (OSTI)

...and halogenated dibenzo-p-dioxins present in combustion processes (e.g., charcoal cooking, cigarette...etiology of envi- ronmental carcinogenesis caused by combustion processes. Pyrolysis Products Are Ineffective as Inducers...

Daniel W. Nebert; Sanford W. Bigelow; Allan B. Okey; Takie Yahagi; Yuko Mori; Minako Nagao; Takashi Sugimura

1979-01-01T23:59:59.000Z

174

Hyponitrite Radical, a Stable Adduct of Nitric Oxide and Nitroxyl  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Publications: Sergei V. Lymar Publications: Sergei V. Lymar Hyponitrite Radical, a Stable Adduct of Nitric Oxide and Nitroxyl G. A. Poskrebyshev, V. Shafirovich and S. V. Lymar J. Am. Chem. Soc., ASAP Article Rate of ON-OO- Bond Homolysis and the Gibbs Energy of Formation of Peroxynitrite S. V. Lymar and G. A. Poskrebyshev J. Phys. Chem. A, 107, 7991-7996 (2003) Spin-Forbidden Deprotonation of Aqueous Nitroxyl (HNO) V. Shafirovich and S. V. Lymar J. Am. Chem. Soc., 125, 6547-6552 (2003) Hydroxyl Radical Formation by O-O Bond Homolysis in Peroxynitrous Acid S. V. Lymar, R. F. Khairutdinov and J. K. Hurst Inorg. Chem., 42, 5259-5266 (2003) Reactions of the Dihydroxylamine (HNO2-.) and Hydronitrite (NO22-.) Radical Ions S. V. Lymar, H. A. Schwarz and G. Czapski J. Phys. Chem. A, 106, 7245-7250 (2002)

175

Novel Cyclotron-Based Radiometal Production  

SciTech Connect (OSTI)

Accomplishments: (1) Construction of prototype solution target for radiometal production; (2) Testing of prototype target for production of following isotopes: a. Zr-89. Investigation of Zr-89 production from Y-89 nitrate solution. i. Defined problems of gas evolution and salt precipitation. ii. Solved problem of precipitation by addition of nitric acid. iii. Solved gas evolution problem with addition of backpressure regulator and constant degassing of target during irradiations. iv. Investigated effects of Y-89 nitrate concentration and beam current. v. Published abstracts at SNM and ISRS meetings; (3) Design of 2nd generation radiometal solution target. a. Included reflux chamber and smaller target volume to conserve precious target materials. b. Included aluminum for prototype and tantalum for working model. c. Included greater varicosities for improved heat transfer; and, (4) Construction of 2nd generation radiometal solution target started.

DeGrado, Timothy R. [Mayo Clinic] [Mayo Clinic (United States)

2013-10-31T23:59:59.000Z

176

Effect of Water Transport on the Production of Hydrogen and Sulfuric Acid in a PEM Electrolyzer  

E-Print Network [OSTI]

be developed that provides efficient production of clean hydrogen. The methods existing today for large-scale produc- tion of hydrogen typically involve hydrocarbon reforming of natural gas or coal gasification% , the overall efficiency is 40%.7 Two issues remain, however, that make the future of this technology un

Weidner, John W.

177

Rapid Screening Method for Analyzing the Conjugated Linoleic Acid Production Capabilities of Bacterial Cultures  

Science Journals Connector (OSTI)

...highlighted. FIG. 1. Standard curves for the absorbance...calculated from the standard curve for bacterial...National Development Plan 2000-2006 and by...Stanton. 2004. Mining the microbiota of...dairy products-a review. Int. Dairy J...compares well with the standard gas-liquid chromatography...

E. Barrett; R. P. Ross; G. F. Fitzgerald; C. Stanton

2007-02-02T23:59:59.000Z

178

Engineering Escherichia coli for Biodiesel Production Utilizing a Bacterial Fatty Acid Methyltransferase  

Science Journals Connector (OSTI)

...production of low-cost biofuels in...the world's energy demands. Biodiesel is a renewable fuel that can...in microbes cost-effectively...the world's energy demands. Biodiesel is a renewable fuel that can...in microbes cost-effectively...

Parwez Nawabi; Stefan Bauer; Nikos Kyrpides; Athanasios Lykidis

2011-09-16T23:59:59.000Z

179

Improved volatile fatty acid and biomethane production from lipid removed microalgal residue (LR?AR) through pretreatment  

Science Journals Connector (OSTI)

Abstract Renewable energy from lipid removed microalgal residues (LR?ARs) serves as a promising tool for sustainable development of the microalgal biodiesel industry. Hence, in this study, LR?AR from Ettlia sp. was characterized for its physico-biochemical parameters, and applied to various pretreatment to increase the biodegradability and used in batch experiments for the production of volatile fatty acids (VFA) and biomethane. After various pretreatments, the soluble organic matters were increased at a maximum of 82% in total organic matters in alkali-autoclaved sample. In addition, VFA and methane production was enhanced by 30% and 40% in alkali-sonicated and alkali-autoclaved samples, respectively. Methane heating value was recovered at maximum of 6.6 MJ kg?1 VS in alkali-autoclaved conditions with comparison to non-pretreated samples. The pretreatment remarkably improved LR?AR solubilization and enhanced VFA and biomethane production, which holds immense potential to eventually reduce the cost of algal biodiesel.

Arumuganainar Suresh; Charles Seo; Ho Nam Chang; Yeu-Chun Kim

2013-01-01T23:59:59.000Z

180

Relation of the Potash Removed by Crops to the Active, Total, Acid-Soluble, and Acid-Insoluble Potash of the Soil.  

E-Print Network [OSTI]

corresponding fertilizer. The American Association of Official Agricultural Chemists (3), through various Referees, undertook studies of citric acid and other solvents. Nitric acid 0.2 N with correction for neutralization was adopted as official for several... of their potash to 1.2 nitric acid; .biotite and glauconite less than 10 per cent; and microcline and orthoclase prac- tically none, as shown in Texas Bulletin 145. (3) The solubility of soil materials which protect or enclose potash minerals. (4) The power...

Fraps, G. S. (George Stronach)

1927-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "nitric acid production" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

ENERGY EFFICIENCY LIMITS FOR A RECUPERATIVE BAYONET SULFURIC ACID DECOMPOSITION REACTOR FOR SULFUR CYCLE THERMOCHEMICAL HYDROGEN PRODUCTION  

SciTech Connect (OSTI)

A recuperative bayonet reactor design for the high-temperature sulfuric acid decomposition step in sulfur-based thermochemical hydrogen cycles was evaluated using pinch analysis in conjunction with statistical methods. The objective was to establish the minimum energy requirement. Taking hydrogen production via alkaline electrolysis with nuclear power as the benchmark, the acid decomposition step can consume no more than 450 kJ/mol SO{sub 2} for sulfur cycles to be competitive. The lowest value of the minimum heating target, 320.9 kJ/mol SO{sub 2}, was found at the highest pressure (90 bar) and peak process temperature (900 C) considered, and at a feed concentration of 42.5 mol% H{sub 2}SO{sub 4}. This should be low enough for a practical water-splitting process, even including the additional energy required to concentrate the acid feed. Lower temperatures consistently gave higher minimum heating targets. The lowest peak process temperature that could meet the 450-kJ/mol SO{sub 2} benchmark was 750 C. If the decomposition reactor were to be heated indirectly by an advanced gas-cooled reactor heat source (50 C temperature difference between primary and secondary coolants, 25 C minimum temperature difference between the secondary coolant and the process), then sulfur cycles using this concept could be competitive with alkaline electrolysis provided the primary heat source temperature is at least 825 C. The bayonet design will not be practical if the (primary heat source) reactor outlet temperature is below 825 C.

Gorensek, M.; Edwards, T.

2009-06-11T23:59:59.000Z

182

Final technical report: Commercialization of the Biofine technology for levulinic acid production from paper sludge  

SciTech Connect (OSTI)

This project involved a three-year program managed by BioMetics, Inc. (Waltham, MA) to demonstrate the commercial feasibility of Biofine thermochemical process technology for conversion of cellulose-containing wastes or renewable materials into levulinic acid, a versatile platform chemical. The program, commencing in October 1995, involved the design, procurement, construction and operation of a plant utilizing the Biofine process to convert 1 dry ton per day of paper sludge waste. The plant was successfully designed, constructed, and commissioned in 1997. It was operated for a period of one year on paper sludge from a variety of source paper mills to collect data to verify the design for a commercial scale plant. Operational results were obtained for four different feedstock varieties. Stable, continuous operation was achieved for two of the feedstocks. Continuous operation of the plant at demonstration scale provided the opportunity for process optimization, development of operational protocols, operator training and identification of suitable materials of construction for scale up to commercial operation . Separated fiber from municipal waster was also successfully processed. The project team consisted of BioMetics Inc., Great Lakes Chemical Corporation (West Lafayette, IN), and New York State Energy Research and Development Authority (Albany, NY).

Fitzpatrick, Stephen W.

2002-04-23T23:59:59.000Z

183

The Relation of the Phosphoric Acid of the Soil to Pot Experiments.  

E-Print Network [OSTI]

by crops grown in the pot experiments, on an average, increased regularly with the amount of active phosphoric acid extracted from the soil by N/5 nitric acid. It was pointed out that the soil may pro- vide sufficient phosphoric acid for large field... potash were determined by so*lution in fifth-noml nitric acid, without correction for the acid neutralized. They are expressed in parts per million. The acid con- ~umed represents the percentage of the acid neutralized in the process of extracting...

Fraps, G. S. (George Stronach)

1920-01-01T23:59:59.000Z

184

B16 Melanoma Cell Arrest in the Mouse Liver Induces Nitric Oxide Release and Sinusoidal Cytotoxicity: A Natural Hepatic Defense against Metastasis  

Science Journals Connector (OSTI)

...Measurement of NO Production The method of Doi et al...Nitric oxide production by endothelial...comparison of three methods of quantification...cellular death via production of hydrogen peroxide in murine...Pharmacol. Toxicol. Methods, 35: 11-17...

Hui Helen Wang; Alan R. McIntosh; Brian B. Hasinoff; Edward S. Rector; Naeem Ahmed; Dwight M. Nance; and F. William Orr

2000-10-15T23:59:59.000Z

185

Study on Production Process of Biodiesel from Rubber Seed (Hevea Brasiliensis) by in Situ (Trans)Esterification Method with Acid Catalyst  

Science Journals Connector (OSTI)

Abstract Biodiesel is fatty acid methyl or ethyl esters made from vegetable oils (edible and non edible) or animal fats. The objective of this research was to produce biodiesel from rubber seed by in situ method with acid catalyst with a goal for obtaining environmentally friendly alternative fuels from non edible raw material. This research focuses on influence of reaction time, concentration of acid catalyst and ratio raw material to methanol. The first stage was carried out in order to get reaction time based on the density and viscosity of mixture produced. In this process H2SO4 0.5% (v/v) was used as catalyst and ratio of raw material to methanol (1:2). The experiments were conducted by investigating the catalyst concentration in range 0.1-1%(v/v) and ratio of raw material to methanol in range 1:1.5-1:3. The research method included, the preparation of samples, biodiesel production, biodiesel separation, and biodiesel characterization i.e density, viscosity, GC analysis, acid value and Iodine number. The results shows that the operation time for biodiesel production by in situ method with acid catalyst was 120 minutes and the yield of Fatty Acid Methyl Ester (FAME) obtained was at 91,05%.

Widayat; Agam Duma Kalista Wibowo; Hadiyanto

2013-01-01T23:59:59.000Z

186

Active Phosphoric Acid and Its Relation to the Needs of the Soil for Phosphoric Acid in Pot Experiments.  

E-Print Network [OSTI]

. K/5 nitric acid, measured with a flask. Place in ter bath previously heated to 40" C. Digest five hours, shak- ?very half hour. Filter on a large'double folded filter. When cola, take 1800 c.c. for the estimation of phosphoric acid and potael... and silica. The filtrate was measured ancl its vol- ume recorded. The soil on the filter paper was washed back into the bottle with 2000 c.c. N,'5 nitric acid, and again digested. Fonr treatments in all were made with the acid, The quantity of phosphorjc...

Fraps, G. S. (George Stronach)

1909-01-01T23:59:59.000Z

187

Pd and Pd–Ag Nanoparticles within a Macroreticular Basic Resin: An Efficient Catalyst for Hydrogen Production from Formic Acid Decomposition  

Science Journals Connector (OSTI)

Pd and Pd–Ag Nanoparticles within a Macroreticular Basic Resin: An Efficient Catalyst for Hydrogen Production from Formic Acid Decomposition ... Palladium nanoparticles were immobilized within the pores of metal organic frameworks MIL-125 and amine-functionalized NH2-MIL-125 using photoassisted and ion exchange deposition methods. ...

Kohsuke Mori; Masahiro Dojo; Hiromi Yamashita

2013-04-15T23:59:59.000Z

188

Relation of the Water-Soluble Potash, the Replaceable and Acid-Soluble Potash to the Potash Removed by Crops in Pot Experiments.  

E-Print Network [OSTI]

ammonia. This acid is 3.33 N. Digest 10 grams soil for 24 hours with 100 c.c. of the above hydrochloric acid at room temperature, shaking occasionally. Filter and wash with hot water. Add 1 c.c. nitric acid. Evaporate to dryness and heat on steam bath... of the soil with nitric acid become greater as the potash taken up by crops increases. Correlation coefficients for the factors studied show close relations between them. Correction of the 0.2N nitric acid for neutralization by the bases of the soil...

Fraps, G. S. (George Stronach)

1929-01-01T23:59:59.000Z

189

Production of 5-Hydroxymethylfurfural from Glucose Using a Combination of Lewis and Brønsted Acid Catalysts in Water in a Biphasic Reactor with an Alkylphenol Solvent  

Science Journals Connector (OSTI)

Production of 5-Hydroxymethylfurfural from Glucose Using a Combination of Lewis and Brønsted Acid Catalysts in Water in a Biphasic Reactor with an Alkylphenol Solvent ... We report the catalytic conversion of glucose in high yields (62%) to 5-hydroxymethylfurfural (HMF), a versatile platform chemical. ... The development of economically viable processes for the production of chemical intermediates from biomass-derived carbohydrates has become an important challenge for research in this area, such as the development of efficient processes for the production of the platform chemical 5-hydroxymethylfurfural (HMF). ...

Yomaira J. Pagán-Torres; Tianfu Wang; Jean Marcel R. Gallo; Brent H. Shanks; James A. Dumesic

2012-04-18T23:59:59.000Z

190

E-Print Network 3.0 - amperometric nitric oxide Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

behavioral... Ref. Neurotransmitters and related compounds Nitric oxide (nitrite) Carbon fiber End-channelInt 8... been studied by microchip CEEC is nitric oxide (NO). NO...

191

Development of a Novel Solvent for the Simultaneous Separation of Strontium and Cesium from Acidic Solutions  

SciTech Connect (OSTI)

A synergistic extraction solvent for the simultaneous removal of cesium and strontium from acidic solutions has been investigated. The extraction solvent consists of, 4,4',(5')-di-(t-butyldicyclo-hexano)-18-crown-6 (DtBuCH18C6), calix[4]arene-bis-(tert-octylbenzo-crown-6) (BOBCalixC6), and 1-(2,2,3,3-tetrafluoropropoxy)-3-(4-sec-butylphenoxy)-2-propanol (Cs-7SB modifier) in a branched aliphatic kerosene (Isopar® L). Extraction synergy for strontium was observed when DtBuCH18C6 was combined with the BOBCalixC6 cesium extractant solvent and Cs-7SB modifier or if the Cs-7SB modifier was substituted into the SREX (Strontium Extraction) solvent in place of TBP. The novel process extracted both cesium and strontium simultaneously from 1 M nitric acid solutions with distribution ratios of 8.8 and 7.7 for strontium and cesium, respectively, at ambient temperature. Distribution coefficients for cesium and strontium as a function of nitric acid concentration and temperature were also obtained with 0.5 M<[HNO3]<2.5 M giving favorable distribution ratios. This new process utilizing the combined solvent has been named the Fission Product Extraction Process (FPEX).

Catherine L. Riddle; John D. Baker; Jack D. Law; Christopher A. McGrath; David H. Meikrantz; Bruce J. Mincher; Dean R. Peterman; Terry A. Todd

2005-03-01T23:59:59.000Z

192

Production  

Science Journals Connector (OSTI)

Production is obtained from proved reserves but the determinants of the scale of production in the industry and country components of the world total are many and complex with some unique to the individual com...

D. C. Ion

1980-01-01T23:59:59.000Z

193

Condensation reactions between phenol, formaldehyde and 5-hydroxymethylfurfural, formed as intermediate in the acid catalyzed dehydration of starchy products  

Science Journals Connector (OSTI)

The incorporation of starch hydrolysates in phenolic resins of the novolak and resol type via intermediate acid catalyzed dehydration to 5-hydroxymethylfurfural (HMF) has been investigated. The course...

Helmut Koch; Joachim Pein

1985-06-28T23:59:59.000Z

194

E-Print Network 3.0 - acid resistance test Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

> >> 1 JOURNAL OF MATERIALS SCIENCE 32 (1997) 1711--1715 Carbon blackhigh density polyethylene conducting Summary: treated with nitric acid for reaction times of 3, 12 and 24 h....

195

E-Print Network 3.0 - acid based black Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

> >> 1 JOURNAL OF MATERIALS SCIENCE 32 (1997) 1711--1715 Carbon blackhigh density polyethylene conducting Summary: surface. 2.2. Nitric acid treatment 200 g of the high structure...

196

E-Print Network 3.0 - acide nitrique concentre Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Soc. (1970),%, pp. 320-325 551.510.41 :551.510.534 Summary: on and determinations of nitric acid concentrations in the stratosphere by Murcray, Kyle, Murcray and Williams...

197

Production  

Broader source: Energy.gov [DOE]

Algae production R&D focuses on exploring resource use and availability, algal biomass development and improvements, characterizing algal biomass components, and the ecology and engineering of...

198

High-level production of poly (?-l-malic acid) with a new isolated Aureobasidium pullulans strain  

Science Journals Connector (OSTI)

Poly (?-l-malic acid) (PMLA) is a water-soluble polyester with many attractive properties in chemical industry and medicine development. However, the low titer of PMLA in the available producer strains limits fur...

Huili Zhang; Jin Cai; Jiaqi Dong; Danping Zhang…

2011-10-01T23:59:59.000Z

199

Reduction of pertechnetate by acetohydroxamic acid: Formation of [TcNO(AHA)2(H2O)]+ and implications for the UREX process.  

SciTech Connect (OSTI)

Reductive nitrosylation and complexation of ammonium pertechnetate by acetohydroxamic acid has been achieved in aqueous nitric and perchloric acid solutions. The kinetics of the reaction depend on the relative concentrations of the reaction components and are accelerated at higher temperatures. The reaction does not occur unless conditions are acidic. Analysis of the x-ray absorption fine structure spectroscopic data is consistent with a pseudo-octahedral geometry with the linear Tc-N-O bond typical of technetium nitrosyl compounds, and electron spin resonance spectroscopy is consistent with a the d{sup 5} Tc(II) nitrosyl complex. The nitrosyl source is generally AHA, but may be augmented by products of reaction with nitric acid. The resulting low-valency trans-aquonitrosyl(diacetohydroxamic)-technetium(II) complex (1) is highly soluble in water, extremely hydrophilic, and is not extracted by tri-n-butylphosphate in a dodecane diluent. Its extraction properties are not pH-dependent; titration studies indicate a single species from pH 4.5 down to -0.6 (calculated). This molecule is resistant to oxidation by H{sub 2}O{sub 2}, even at high pH, and can undergo substitution to form other technetium nitrosyl complexes. The formation of 1 may strongly impact the fate of technetium in the nuclear fuel cycle.

1Harry Reid Center for Environmental Studies, Nuclear Science and Technology Division, University of Nevada, Las Vegas, Las Vegas, NV, 89154-4006; Gong, Cynthia-May S; Poineau, Frederic; Lukens, Wayne W; Czerwinski, Kenneth R.

2008-02-26T23:59:59.000Z

200

Production  

Broader source: Energy.gov [DOE]

Algae production R&D focuses on exploring resource use and availability, algal biomass development and improvements, characterizing algal biomass components, and the ecology and engineering of cultivation systems.

Note: This page contains sample records for the topic "nitric acid production" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Prediction of nitric oxide concentrations during inflammation and carcinogenesis  

E-Print Network [OSTI]

Nitric oxide is a biological messenger which is synthesized enzymatically throughout the body and which has numerous physiological functions, including roles in blood pressure control, regulation of clotting, and ...

Chin, Melanie Pei-Heng

2010-01-01T23:59:59.000Z

202

Arabidopsis Nonsymbiotic Hemoglobin AHb1 Modulates Nitric Oxide Bioactivity  

Science Journals Connector (OSTI)

...nitric oxide (NO) involves an array of interrelated redox forms with different chemical...is involved in diverse physiological processes, including disease resistance, growth...concentrations far below those at which anaerobic processes are activated. Thus, it is unlikely...

Michele Perazzolli; Paola Dominici; Maria C. Romero-Puertas; Elisa Zago; Jürgen Zeier; Masatoshi Sonoda; Chris Lamb; Massimo Delledonne

2004-09-14T23:59:59.000Z

203

Hydrogen peroxide differentially modulates cardiac myocyte nitric oxide synthesis  

E-Print Network [OSTI]

Nitric oxide (NO) and hydrogen peroxide (H(subscript 2)O(subscript 2)) are synthesized within cardiac myocytes and play key roles in modulating cardiovascular signaling. Cardiac myocytes contain both the endothelial (eNOS) ...

Sartoretto, Juliano

204

Microorganisms for producing organic acids  

DOE Patents [OSTI]

Organic acid-producing microorganisms and methods of using same. The organic acid-producing microorganisms comprise modifications that reduce or ablate AcsA activity or AcsA homolog activity. The modifications increase tolerance of the microorganisms to such organic acids as 3-hydroxypropionic acid, acrylic acid, propionic acid, lactic acid, and others. Further modifications to the microorganisms increase production of such organic acids as 3-hydroxypropionic acid, lactate, and others. Methods of producing such organic acids as 3-hydroxypropionic acid, lactate, and others with the modified microorganisms are provided. Methods of using acsA or homologs thereof as counter-selectable markers are also provided.

Pfleger, Brian Frederick; Begemann, Matthew Brett

2014-09-30T23:59:59.000Z

205

One-pot room-temperature conversion of cyclohexane to adipic acid by ozone and UV light  

Science Journals Connector (OSTI)

...nitric acid oxidation method (3). The first step is air oxidation of cyclohexane under high temperatures (125° to 165...Finlayson-Pitts B. J. Pitts J. N. Jr. , Tropospheric air pollution: Ozone, airborne toxics, polycyclic aromatic hydrocarbons...

Kuo Chu Hwang; Arunachalam Sagadevan

2014-12-19T23:59:59.000Z

206

Engineered Respiro-Fermentative Metabolism for the Production of Biofuels and Biochemicals from Fatty Acid-Rich Feedstocks  

Science Journals Connector (OSTI)

...E. coli for biofuel production from...their higher energy content and reduced...more efficient alternative, as each b-oxidation...Second generation biofuels: high-efficiency...run vehicles on algae-based oil...microbes for biofuels production...of renewable energy in Malaysia...

Clementina Dellomonaco; Carlos Rivera; Paul Campbell; Ramon Gonzalez

2010-06-04T23:59:59.000Z

207

Combined Dilute Acid and Solvent Based Pretreatment of Agricultural Wastes for Efficient Lignocellulosic Fractionation and Biofuels Production  

SciTech Connect (OSTI)

A true biorefinery for processing lignocellulosic biomass should achieve maximum utilization of all major constituents (cellulose, hemicellulose, & lignin) within the feedstock. In this work a combined pretreatment process of dilute acid (DA) and N-methyl morpholine N-oxide (NMMO) is described that allows for both fractionation and subsequent complete hydrolysis of the feedstocks (corn stover and sugarcane bagasse). During this multi-step processing, the dilute acid pretreatment solubilizes the majority (>90%) of the hemicellulosic fraction, while the NMMO treatment yields a cellulosic fraction that is completely digestible within 48 hours at low enzyme loadings. With both the cellulosic and hemicellulosic fractions being converted into separate, dissolved sugar fractions, the remaining portion is nearly pure lignin. When used independently, DA and NMMO pretreatments are only able to achieve ~80% and ~45% cellulosic conversion, respectively. Mass balance calculations along with experimental results are used to illustrate the feasibility of separation and recycling of NMMO.

Brodeur, G.; Ramakrishnan, S.; Wilson, C.; Telotte, J.; Collier, J.; Stickel, J.

2013-01-01T23:59:59.000Z

208

Engineered Respiro-Fermentative Metabolism for the Production of Biofuels and Biochemicals from Fatty Acid-Rich Feedstocks  

Science Journals Connector (OSTI)

...chemical conversion to biodiesel (6), while oleaginous algae and nonedible FA-rich...light for engineered algae: redirecting metabolism...high-efficiency microalgae for biodiesel production. BioEnerg...to run vehicles on algae-based oil. Science...

Clementina Dellomonaco; Carlos Rivera; Paul Campbell; Ramon Gonzalez

2010-06-04T23:59:59.000Z

209

Engineered Respiro-Fermentative Metabolism for the Production of Biofuels and Biochemicals from Fatty Acid-Rich Feedstocks  

Science Journals Connector (OSTI)

...while oleaginous algae and nonedible FA-rich...biological production of fuels and chemicals...for engineered algae: redirecting metabolism to fuel a biotechnology...2009. ExxonMobil fuels Venters efforts to run vehicles on algae-based oil. Science...

Clementina Dellomonaco; Carlos Rivera; Paul Campbell; Ramon Gonzalez

2010-06-04T23:59:59.000Z

210

Ball-milling, a novel extraction process for production of W from WO{sub 3} using Mg as a reductant  

SciTech Connect (OSTI)

The synthesis of tungsten (W) metal by the chemical reduction of tungsten oxide (WO{sub 3}), using magnesium (Mg) as a reductant, has been investigated by the mechanical alloying process. Complete transformation to W was observed after 60 sec of milling. W metal was recovered from the reaction products of W and magnesium oxide (MgO) by dilute nitric acid leaching. The powders were characterized by X-ray Diffraction (XRD), Scanning Electron Microscopy (SEM) and Transmission Electron Microscopy (TEM) techniques. Electron microscopic studies indicated that nano-meter sized grains were present in the W powder after leaching.

Mukhopadhyay, D.K.; Suryanarayana, C.; Fores, F.H.; Prisbrey, K.A. [Univ. of Idaho, Moscow, ID (United States)

1996-06-01T23:59:59.000Z

211

Studies in the Respiratory and Carbohydrate Metabolism of Plant Tissues. II. Interrelationship between the Rates of Production of Carbon Dioxide, of Lactic acid and of Alcohol in Potato Tubers under Anaerobic Conditions  

Science Journals Connector (OSTI)

...Production of Carbon Dioxide, of Lactic acid and of Alcohol in Potato Tubers under Anaerobic Conditions J. Barker A. F. El Saifi Data, presented in part I of this communication, for the changes in air and in nitrogen in the rate of production by potato...

1952-01-01T23:59:59.000Z

212

Process for the production of aqueous hydrochloric acid having a concentration of at least 35. 5% by weight  

SciTech Connect (OSTI)

The present invention is directed to a process for continuously producing aqueous hydrochloric acid having a concentration of at least 3.5% by weight comprising: continuously introducing water to the top of an absorption unit, continuously introducing a gas stream containing anhydrous hydrogen chloride to the bottom of said absorption unit, removing an overhead gaseous stream from said unit, said gaseous stream containing no more than 3% by weight, and preferably no more than 1% by weight hydrogen chloride, and removing a bottom liquid stream from said unit, said bottom stream containing at least 35.5% by weight hydrogen chloride, and returning a portion of said bottom stream to said unit.

Parigi, J.V.

1984-12-18T23:59:59.000Z

213

E-Print Network 3.0 - agmatine attenuates nitric Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

attenuates nitric Page: << < 1 2 3 4 5 > >> 1 Learning and memory in agmatine-treated rats B.E. McKay*, W.E. Lado1 Summary: . Inhibition of mammalian nitric oxide synthases by...

214

Recombinant Polycistronic Structure of Hydantoinase Process Genes in Escherichia coli for the Production of Optically Pure d-Amino Acids  

Science Journals Connector (OSTI)

...products of interest for the pharmaceutical, food, and agrochemical industries (22, 25). The enzymatic method to synthesize...conditions and in different E. coli strains) and Fig. S1 (Composition of plasmids pSER42 and pAMG3) and S2 (SDS-PAGE analysis...

Ana Isabel Martínez-Gómez; Sergio Martínez-Rodríguez; Josefa María Clemente-Jiménez; Joaquín Pozo-Dengra; Felipe Rodríguez-Vico; Francisco Javier Las Heras-Vázquez

2007-01-12T23:59:59.000Z

215

Studies on the production of ultra-clean coal by alkali-acid leaching of low-grade coals  

SciTech Connect (OSTI)

The use of low-grade coal in thermal power stations is leading to environmental pollution due to the generation of large amounts of fly ash, bottom ash, and CO{sub 2} besides other pollutants. It is therefore important to clean the coal before using it in thermal power stations, steel plants, or cement industries etc. Physical beneficiation of coal results in only limited cleaning of coal. The increasing environmental pollution problems from the use of coal have led to the development of clean coal technologies. In fact, the clean use of coal requires the cleaning of coal to ultra low ash contents, keeping environmental norms and problems in view and the ever-growing need to increase the efficiency of coal-based power generation. Therefore this requires the adaptation of chemical cleaning techniques for cleaning the coal to obtain ultra clean coal having ultra low ash contents. Presently the reaction conditions for chemical demineralization of low-grade coal using 20% aq NaOH treatment followed by 10% H{sub 2}SO{sub 4} leaching under reflux conditions have been optimized. In order to reduce the concentration of alkali and acid used in this process of chemical demineralization of low-grade coals, stepwise, i.e., three step process of chemical demineralization of coal using 1% or 5% aq NaOH treatment followed by 1% or 5% H{sub 2}SO{sub 4} leaching has been developed, which has shown good results in demineralization of low-grade coals. In order to conserve energy, the alkali-acid leaching of coal was also carried out at room temperature, which gave good results.

Nabeel, A.; Khan, T.A.; Sharma, D.K. [Jamia Millia Islamia, New Delhi (India). Dept. of Chemistry

2009-07-01T23:59:59.000Z

216

Chemical behavior of degradation products of tributylphosphate in purex reprocessing  

SciTech Connect (OSTI)

Chemical behavior of butyl nitrate/butyl alcohol, degradation products from dealkylation of tri-n-butylphosphate(TBP) in PUREX reprocessing, which has not so far been reported, was investigated. No accumulation of those compounds in the organic phase of TBP(30%)-dodecane was observed in any separation cycle of PUREX despite the fact that the apparent distribution of the compounds lies to the organic phase at their high concentrations. The distribution of butyl nitrate/butyl alcohol between organic/aqueous phases is found to be dependent on their concentrations and on nitric acid concentration, which could explain the above phenomena. Only butyl nitrate of the above two compounds was slightly detected in the organic streams. It is probable from this investigation that butyl nitrate is removed into aqueous waste stream primarily through alkali scrubber.

Kuno, Y.; Sato, S.; Masui, J. [Power Reactor and Nuclear Fuel Development Corp., Ibaraki (Japan)] [and others

1995-12-01T23:59:59.000Z

217

Fatty Acids Isolated from Toxoplasma gondii Reduce Glycosylphosphatidylinositol-Induced Tumor Necrosis Factor Alpha Production through Inhibition of the NF-?B Signaling Pathway  

Science Journals Connector (OSTI)

...Palmitic acid crosses the macrophage plasma membrane. In all experiments, inhibitory...indicating its entrance through the plasma membrane. Thus, fatty acids were not...block the access of fatty acids to the plasma membrane or form complexes with them...

Françoise Debierre-Grockiego; Khamran Rabi; Jörg Schmidt; Hildegard Geyer; Rudolf Geyer; Ralph T. Schwarz

2007-03-26T23:59:59.000Z

218

Reference electrode for strong oxidizing acid solutions  

DOE Patents [OSTI]

A reference electrode for the measurement of the oxidation-reduction potentials of solutions is especially suitable for oxidizing solutions such as highly concentrated and fuming nitric acids, the solutions of nitrogen oxides, N.sub.2 O.sub.4 and N.sub.2 O.sub.5, in nitric acids. The reference electrode is fabricated of entirely inert materials, has a half cell of Pt/Ce(IV)/Ce(III)/70 wt. % HNO.sub.3, and includes a double-junction design with an intermediate solution of 70 wt. % HNO.sub.3. The liquid junctions are made from Corning No. 7930 glass for low resistance and negligible solution leakage.

Rigdon, Lester P. (Livermore, CA); Harrar, Jackson E. (Castro Valley, CA); Bullock, Sr., Jack C. (Pleasanton, CA); McGuire, Raymond R. (Brentwood, CA)

1990-01-01T23:59:59.000Z

219

Measurement of nitric oxide with an antimonide diode laser  

E-Print Network [OSTI]

lasers while retaining the practical advantages of room- temperature or thermoelectrically cooled the selective detection of NO under reduced pressure conditions was identified. With wavelength- modulation cooling is not required. © 1997 Optical Society of America Key words: Diode laser, antimonide, nitric

220

Studies in the Respiratory and Carbohydrate Metabolism of Plant Tissues. I. Experimental Studies of the Formation of Carbon Dioxide, Lactic Acid and other Products in Potato Tubers Under Anaerobic Conditions  

Science Journals Connector (OSTI)

...Formation of Carbon Dioxide, Lactic Acid and other Products in Potato Tubers Under Anaerobic Conditions J. Barker A. F. El Saifi Using mature potatoes of low sugar content, held at 10 degrees C both in air and in nitrogen, the following metabolic changes...

1952-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "nitric acid production" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Studies in the Respiratory and Carbohydrate Metabolism of Plant Tissues. IV. The Relation between the Rate of Carbon Dioxide Production in Potato Tubers in Air Following Anaerobic Conditions, and the Accompanying Changes in Lactic Acid Content and Sugar Concentration  

Science Journals Connector (OSTI)

...Following Anaerobic Conditions, and the Accompanying Changes in Lactic Acid Content and Sugar Concentration J. Barker A. F. El Saifi In part III of this series data were presented for the changes in air following periods of anaerobiosis in the rate of production...

1953-01-01T23:59:59.000Z

222

Nitric oxide inhibition of soot oxidation by oxygen atoms at 298K  

SciTech Connect (OSTI)

Nitric oxide is observed to inhibit the rate of soot oxidation by oxygen atoms at 298K. Small amounts of added NO reduce the rates of production of CO/sub 2/ and CO by up to 35%. The authors show experimentally that NO is not reducing the gas phase O atom concentration. Thermal desorption mass spectrometry shows a small adsorption of NO on the soot; this NO adsorption corresponds to 1.5% of the carbon atoms on the surface of the individual soot spheres. This inhibition is interpreted in terms of a relatively small number of reactive sites on the soot at which soot gasification occurs and which are effectively blocked by NO.

Wicke, B.G.; Grady, K.A.

1987-08-01T23:59:59.000Z

223

Nitric oxide inhibition of soot oxidation by oxygen atoms at 298/sup 0/Ktiation  

SciTech Connect (OSTI)

Nitric oxide is observed to inhibit the rate of soot oxidation by oxygen atoms at 298 K. Small amounts of added NO reduce the rates of production of CO/sub 2/ and CO by up to 35%. The authors show experimentally that NO is not reducing the gas phase O atom concentration. Thermal description mass spectrometry is used to measure the small adsorption of NO on the soot; this NO adsorption corresponds to 1.5% of the carbon atoms on the surface of the individual soot spheres. This inhibition is interpreted in terms of a relatively small number of reactive sites on the soot at which soot gasification occurs and which are effectively blocked by NO. When considered together with our previously reported work on oxidation of soot by oxygen atoms at 298 K, these results allow a partial mechanism to be formulated for this soot oxidation process.

Wicke, B.G.; Grady, K.A.

1987-01-01T23:59:59.000Z

224

The Production of Active Nitrogen in the Soil.  

E-Print Network [OSTI]

relation between the basicity of the soil and the effect of calcium carbonate. Basicity was determined by three methods: (1) Ten grams of soil were digested with 100 cc fifth normal nitric acid, for 12 hours and 10 cc. of the filtrate was titrated.... The basicity measured is due to carbonates and easily de- composed silicates of lime, magnesia, and the alkalies. (2) Fifty grams of soil were digested with 100 cc. tenth normal nitric acid, for one-half hour, and 20 cc. of the filtrate titrated with caustic...

Fraps, G. S. (George Stronach)

1908-01-01T23:59:59.000Z

225

Comparison of simulants to actual neutralized current acid waste: process and product testing of three NCAW core samples from Tanks 101-AZ and 102-AZ  

SciTech Connect (OSTI)

A vitrification plant is planned to process the high-level waste (HLW) solids from Hanford Site tanks into canistered glass logs for disposal in a national repository. Programs were established within the Pacific Northwest Laboratory Vitrification Technology Development (PVTD) Project to test and model simulated waste to support design, feed processability, operations, permitting, safety, and waste-form qualification. Parallel testing with actual radioactive waste was performed on a laboratory-scale to confirm the validity of using simulants and glass property models developed from simulants. Laboratory-scale testing has been completed on three radioactive core samples from tanks 101-AZ and 102-AZ containing neutralized current acid waste (NCAW), which is one of the first waste types to be processed in the high-level waste vitrification plant under a privatization scenario. Properties of the radioactive waste measured during process and product testing were compared to simulant properties and model predictions to confirm the validity of simulant and glass property ,models work. This report includes results from the three NCAW core samples, comparable results from slurry and glass simulants, and comparisons to glass property model predictions.

Morrey, E.V.; Tingey, J.M.; Elliott, M.L.

1996-10-01T23:59:59.000Z

226

Oxidation of trace amounts of transplutonium elements to the tetravalent state in solutions of mineral acids and their stabilities  

SciTech Connect (OSTI)

The behavior of trace amounts of americium(IV) in sulfuric and nitric acid solutions as a function of the mineral acid, potassium phosphotungstate, and ammonium persulfate concentrations was investigated. The stability of americium(IV) was studied. The optimal conditions and time of oxidation of trace amounts of americium to the tetravalent state were found on the basis of the experimental data obtained.

Milyukova, M.S.; Varezhkina, N.S.; Kuzovkina, E.V.; Malikov, D.A.; Myasoedov, B.F.

1989-01-01T23:59:59.000Z

227

Acid Fracture and Fracture Conductivity Study of Field Rock Samples  

E-Print Network [OSTI]

Acid fracturing is a well stimulation strategy designed to increase the productivity of a producing well. The parameters of acid fracturing and the effects of acid interaction on specific rock samples can be studied experimentally. Acid injection...

Underwood, Jarrod

2013-11-15T23:59:59.000Z

228

Personal and Ambient Air Pollution is Associated with Increased Exhaled Nitric Oxide in Children with Asthma  

E-Print Network [OSTI]

1994. Nitric oxide and nitrogen dioxide: Method 6014. In:Molecular mechanisms of nitrogen dioxide induced epithelialEC, OC), and 24-hr nitrogen dioxide. Ambient exposures

2006-01-01T23:59:59.000Z

229

Electronic Structure Calculations on the Reaction of Vinyl Radical with Nitric Oxide  

Science Journals Connector (OSTI)

Electronic Structure Calculations on the Reaction of Vinyl Radical with Nitric Oxide ... Methyl isocyanate 19 is calculated to be the most stable isomer. ... Methods of Calculation ...

Raman Sumathi; Hue Minh Thi Nguyen; Minh Tho Nguyen; Jozef Peeters

2000-02-15T23:59:59.000Z

230

Citrus nobiletin suppresses inducible nitric oxide synthase gene expression in interleukin-1?-treated hepatocytes  

SciTech Connect (OSTI)

Highlights: •Nobiletin is a polymethoxylated flavone that is abundant in citrus peels. •Nobiletin is a major constituent of the Citrus unshiu peel extract. •Nobiletin suppresses induction of NO and reduces iNOS expression in hepatocytes. •Nobiletin reduces the iNOS promoter activity and the DNA-binding activity of NF-?B. -- Abstract: Background: Nobiletin is a polymethoxylated flavone that is abundant in the peels of citrus fruits, such as Citrus unshiu (Satsuma mandarin) and Citrus sinensis. The dried peels of C. unshiu (chinpi) have been included in several formulae of Japanese Kampo medicines. Nobiletin may suppress the induction of inducible nitric oxide synthase (iNOS), which synthesizes the inflammatory mediator nitric oxide (NO) in hepatocytes. Methods: A C. unshiu peel (CUP) extract was prepared. Primary cultured rat hepatocytes were treated with the CUP extract or nobiletin in the presence of interleukin 1? (IL-1?), which induces iNOS expression. NO production and iNOS gene expression were analyzed. Results: High-performance liquid chromatography analyses revealed that the nobiletin content in the CUP extract was 0.14%. Nobiletin dose-dependently reduced the NO levels and decreased iNOS expression at the protein, mRNA and antisense transcript levels. Flavone, which does not contain any methoxy groups, also suppressed iNOS induction. Nobiletin reduced the transcriptional activity of iNOS promoter-luciferase constructs and the DNA-binding activity of nuclear factor ?B (NF-?B) in the nuclei. Conclusions: The suppression of iNOS induction by nobiletin suggests that nobiletin may be responsible for the anti-inflammatory effects of citrus peels and have a therapeutic potential for liver diseases.

Yoshigai, Emi [Department of Biomedical Sciences, College of Life Sciences, Kusatsu, Shiga (Japan) [Department of Biomedical Sciences, College of Life Sciences, Kusatsu, Shiga (Japan); Ritsumeikan Global Innovation Research Organization (R-GIRO), Kusatsu, Shiga (Japan); Machida, Toru [Department of Biomedical Sciences, College of Life Sciences, Kusatsu, Shiga (Japan)] [Department of Biomedical Sciences, College of Life Sciences, Kusatsu, Shiga (Japan); Okuyama, Tetsuya [Ritsumeikan Global Innovation Research Organization (R-GIRO), Kusatsu, Shiga (Japan)] [Ritsumeikan Global Innovation Research Organization (R-GIRO), Kusatsu, Shiga (Japan); Mori, Masatoshi; Murase, Hiromitsu; Yamanishi, Ryota [Department of Biomedical Sciences, College of Life Sciences, Kusatsu, Shiga (Japan)] [Department of Biomedical Sciences, College of Life Sciences, Kusatsu, Shiga (Japan); Okumura, Tadayoshi [Research Organization of Science and Technology, Ritsumeikan University, Kusatsu, Shiga (Japan) [Research Organization of Science and Technology, Ritsumeikan University, Kusatsu, Shiga (Japan); Department of Surgery, Kansai Medical University, Hirakata, Osaka (Japan); Ikeya, Yukinobu [Department of Pharmacy, College of Pharmaceutical Sciences, Ritsumeikan University, Kusatsu, Shiga (Japan)] [Department of Pharmacy, College of Pharmaceutical Sciences, Ritsumeikan University, Kusatsu, Shiga (Japan); Nishino, Hoyoku [Ritsumeikan Global Innovation Research Organization (R-GIRO), Kusatsu, Shiga (Japan) [Ritsumeikan Global Innovation Research Organization (R-GIRO), Kusatsu, Shiga (Japan); Department of Biochemistry, Kyoto Prefectural University of Medicine, Kyoto (Japan); Nishizawa, Mikio, E-mail: nishizaw@sk.ritsumei.ac.jp [Department of Biomedical Sciences, College of Life Sciences, Kusatsu, Shiga (Japan)] [Department of Biomedical Sciences, College of Life Sciences, Kusatsu, Shiga (Japan)

2013-09-13T23:59:59.000Z

231

Pantothenic acid biosynthesis in zymomonas  

DOE Patents [OSTI]

Zymomonas is unable to synthesize pantothenic acid and requires this essential vitamin in growth medium. Zymomonas strains transformed with an operon for expression of 2-dehydropantoate reductase and aspartate 1-decarboxylase were able to grow in medium lacking pantothenic acid. These strains may be used for ethanol production without pantothenic acid supplementation in seed culture and fermentation media.

Tao, Luan; Tomb, Jean-Francois; Viitanen, Paul V.

2014-07-01T23:59:59.000Z

232

Biochemical and Structural Studies of NADH-Dependent FabG Used To Increase the Bacterial Production of Fatty Acids under Anaerobic Conditions  

Science Journals Connector (OSTI)

...of fatty acid-based fuels, including fatty acid...Bar heights represent average titers from 3 replicates...Bar heights represent average titers from 3 biological...Bennett and KY San. 2004. Effect of different levels of...2011.07.001 . 17. Price, AC , YM Zhang, CO...

Pouya Javidpour; Jose H. Pereira; Ee-Been Goh; Ryan P. McAndrew; Suzanne M. Ma; Gregory D. Friedland; Jay D. Keasling; Swapnil R. Chhabra; Paul D. Adams; Harry R. Beller

2013-11-08T23:59:59.000Z

233

Product Identification and Kinetics of Reactions of HCl with HNO3/H2SO4/H2O Solutions Christopher D. Cappa, Sarah E. Kuipers, Jeanine M. Roberts, Abigail S. Gilbert, and  

E-Print Network [OSTI]

as nitric acid trihydrate or water ice) under winter Antarctic conditions,3 an increasing preponderance the catalysts and to produce high yields. A more direct method to produce Cl2 and ClNO directly from a reaction

Elrod, Matthew J.

234

The Effect of Rock Phosphate Upon the Corn Possibility of Phosphoric Acid of the Soil  

E-Print Network [OSTI]

of Veterinary Medicine, A. and M. College of Texas. **In cooperation with United Statee Department of Agriculture. THE EFFECT OF ROCK PHOSPHATE UPON THE CORN POS- SIBILITY OF PHOSPHORIC ACID OF THE SOIL. In connection vith oil-fertilit~ stuclies..., it is important to lcnow the relation between the effect of the phosphoric acid of the rock phosphate on crops and the phosphoric acid that can be withdrawn from the soil by crops. The phosphoric acid of rock phosphate is readily soluble in K/5 nitric acid...

Fraps, G. S. (George Stronach)

1922-01-01T23:59:59.000Z

235

Type B Accident Investigation of the Acid Vapor Inhalation on June 7, 2005, in TA-48, Building RC-1 Room 402 at the Los Alamos National Laboratory  

Broader source: Energy.gov [DOE]

During the afternoon of June 7, 2005, two postdoctoral (postdoc) employees working at the Los Alamos National Laboratory (LANL) inhaled acid vapors generated by the use of aqua regia (a mixture of hydrochloric and nitric acids) to clean glassware on a laboratory benchtop.

236

FT-IR spectroscopy of nitric acid in TBP/octane solution.  

SciTech Connect (OSTI)

Infrared studies for the HNO{sub 3}/0.73 M TBP n-octane system are reported. Two extracted species, TBP {center_dot} HNO{sub 3} and TBP {center_dot} 2HNO{sub 3}, were identified in the organic phase. The concentration of the individual species was determined by the analysis of the vibrational band at {approx}1650 cm{sup -1}. The band at 1648 cm{sup -1} was assigned to the monosolvate TBP {center_dot} HNO{sub 3} and the band at 1672 cm{sup -1} to the hemisolvate TBP {center_dot} 2HNO{sub 3}. The infrared spectra revealed that with respect to the P{double_bond}O bond, as well to each other, the HNO{sub 3} molecules in the hemisolvate are spectrally non-equivalent. The predominant structure of TBP {center_dot} 2HNO{sub 3} involves the chain HNO{sub 3} dimer. Some ionic NO{sub 3}{sup -} and hydronium ions were identified in this system but only during formation of the monosolvate. The analyses performed in this system can serve for the characterization of HNO{sub 3} in related systems in the presence of metal species.

Ferraro, J. R.; Borkowski, M.; Chiarizia, R.; McAlister, D. R.; Chemistry; Loyola Univ. Chicago

2001-01-01T23:59:59.000Z

237

Disposition and transportation of surplus radioactive low specific activity nitric acid. Volume 2, Environmental Assessment  

SciTech Connect (OSTI)

This volume consists of two appendices: public comments and DOE responses, and public comments not requiring responses.

NONE

1995-05-01T23:59:59.000Z

238

Nitric acid cycle process for extracting thermal energy from low-level heat sources  

Science Journals Connector (OSTI)

... ENORMOUS amounts of solar energy are stored in the tropical oceans. The first attempt to recover this ' ... energy are stored in the tropical oceans. The first attempt to recover this 'solar sea energy' from the tropical oceans, using the temperature difference between the warm surface ...

N. Wakao; K. Nojo

1978-05-04T23:59:59.000Z

239

Elevation in Exhaled Nitric Oxide Predicts for Radiation Pneumonitis  

SciTech Connect (OSTI)

Purpose: Radiation pneumonitis is a major toxicity after thoracic radiotherapy (RT), with no method available to accurately predict the individual risk. This was a prospective study to evaluate exhaled nitric oxide as a predictive biomarker for radiation pneumonitis in esophageal cancer patients. Patients and Methods: A total of 34 patients prescribed neoadjuvant chemoradiotherapy for esophageal cancer were enrolled in the present trial. Each patient underwent respiratory surveys and exhaled nitric oxide (NO) measurements before, at the end of, and 1 to 2 months after completing RT. Pneumonitis toxicity was scored using the Common Terminology Criteria for Adverse Events, version 4.0. The demographics, dosimetric factors, and exhaled NO levels were evaluated for correlation with symptomatic patients (scores {>=}2). Results: Of the 34 patients, 28 were evaluable. All had received 50.4 Gy RT with concurrent chemotherapy. The pneumonitis toxicity score was Grade 3 for 1, Grade 2 for 3, Grade 1 for 7, and Grade 0 for 17. The dosimetric factors were not predictive of symptoms. The mean exhaled NO level measured before, at completion, and at restaging was 17.3 {+-} 8.5 (range, 5.5-36.7), 16.0 {+-} 14.2 (range, 5.8-67.7), and 14.7 {+-} 6.2 (range, 5.5-28.0) parts per billion, respectively. The ratio of exhaled NO at the end of RT vs. before treatment was 3.4 (range, 1.7-6.7) for the symptomatic and 0.8 (range, 0.3-1.3) for the asymptomatic (p = .0017) patients. The elevation in exhaled NO preceded the peak symptoms by 33 days (range, 21-50). The interval to peak symptoms was inversely related to the exhaled NO elevation. Conclusions: Elevations in exhaled NO at the end of RT was found to predict for radiation pneumonitis symptoms.

Guerrero, Thomas, E-mail: tguerrero@mdanderson.org [Division of Radiation Oncology, University of Texas M. D. Anderson Cancer Center, Houston, TX (United States); University of Texas Graduate School of Biomedical Sciences at Houston, Houston, TX (United States); Martinez, Josue [Department of Statistics, Texas A and M University, College Station, TX (United States); McCurdy, Matthew R. [Department of Radiation Oncology, Baylor College of Medicine, Houston, TX (United States); Wolski, Michael [Department of Radiation Oncology, University of Texas Medical Branch, Galveston, TX (United States); McAleer, Mary Francis [Division of Radiation Oncology, University of Texas M. D. Anderson Cancer Center, Houston, TX (United States)

2012-02-01T23:59:59.000Z

240

Digestibility of amino acids and energy in three soybean products measured at the end of the small intestine and over the entire track of growing-finishing swine  

E-Print Network [OSTI]

availability of lysine from wheat, flour, bread and gluten. Ousterhout et al. (1959) derived an index of availability by comparing chick growth on a basal diet that was missing one amino acid to the basal diet with a test protein and the basal diet... availability of lysine from wheat, flour, bread and gluten. Ousterhout et al. (1959) derived an index of availability by comparing chick growth on a basal diet that was missing one amino acid to the basal diet with a test protein and the basal diet...

Rudolph, Bryan Charles

2012-06-07T23:59:59.000Z

Note: This page contains sample records for the topic "nitric acid production" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Isobutyraldehyde production from Escherichia coli by removing aldehyde reductase activity  

E-Print Network [OSTI]

for production of the platform chemical isobutyric acid.platform for the production of non- natural chemical

Rodriguez, Gabriel M; Atsumi, Shota

2012-01-01T23:59:59.000Z

242

Synthesis of Biodiesel via Acid Catalysis  

Science Journals Connector (OSTI)

Synthesis of Biodiesel via Acid Catalysis ... Biodiesel is synthesized via the transesterification of lipid feedstocks with low molecular weight alcohols. ... Nonetheless, acid-catalyzed processes could produce biodiesel from low-cost feedstocks, lowering production costs. ...

Edgar Lotero; Yijun Liu; Dora E. Lopez; Kaewta Suwannakarn; David A. Bruce; James G. Goodwin, Jr.

2005-01-25T23:59:59.000Z

243

Biochemical and Structural Studies of NADH-Dependent FabG Used To Increase the Bacterial Production of Fatty Acids under Anaerobic Conditions  

Science Journals Connector (OSTI)

...Institutes of Health, National Institute of General Medical Sciences. The Advanced Light...acid synthesis. XV. Preparation and general properties of beta-ketoacyl acyl carrier...synthesis during the Escherichia coli cell cycle. J. Bacteriol. 145 :472-478. 38...

Pouya Javidpour; Jose H. Pereira; Ee-Been Goh; Ryan P. McAndrew; Suzanne M. Ma; Gregory D. Friedland; Jay D. Keasling; Swapnil R. Chhabra; Paul D. Adams; Harry R. Beller

2013-11-08T23:59:59.000Z

244

Thermal Stability Of Formohydroxamic Acid  

SciTech Connect (OSTI)

The thermal stability of formohydroxamic acid (FHA) was evaluated to address the potential for exothermic decomposition during storage and its use in the uranium extraction process. Accelerating rate calorimetry showed rapid decomposition at a temperature above 65 {degree}?C; although, the rate of pressure rise was greater than two orders of magnitude less than the lower bound for materials which have no explosive properties with respect to transportation. FHA solutions in water and nitric acid did not reach runaway conditions until 150 {degree}?C. Analysis by differential scanning calorimetry showed that FHA melted at 67 {degree}?C and thermally decomposed at 90 {degree}?C with an enthalpy of -1924 J/g. The energics of the FHA thermal decomposition are comparable to those measured for aqueous solutions of hydroxylamine nitrate. Solid FHA should be stored in a location where the temperature does not exceed 20-25 {degree}?C. As a best practice, the solid material should be stored in a climate-controlled environment such as a refrigerator or freezer. FHA solutions in water are not susceptible to degradation by acid hydrolysis and are the preferred way to handle FHA prior to use.

Fondeur, F. F.; Rudisill, T. S.

2011-10-21T23:59:59.000Z

245

Solvent Extraction Behavior of Plutonium (IV) Ions in the Presence of Simple Hydroxamic Acids  

SciTech Connect (OSTI)

Formo-and aceto-hydroxamic acids are very effective reagents for stripping Pu(IV) ions from a tri-butyl phosphate phase into nitric acid. Distribution data for Pu(IV) in the presence of these hydroxamate ions have been obtained and trends established. The affinity of aceto-hydroxamic acid for Pu(IV) ions and its selectivity over U(VI) ions is demonstrated by the values of the stability constants in HCIO4. These data support the applications of simple hydroxamic acids in advanced Purex-type solvent extraction systems.

Carrott, M. J.; Fox, O. D.; Maher, C. J.; Mason, C.; Taylor, Robin J.; Sinkov, Sergey I.; Choppin, Gregory R.

2007-11-15T23:59:59.000Z

246

Corrosion Testing of Carbon Steel in Acid Cleaning Solutions  

SciTech Connect (OSTI)

High level waste is stored in carbon steel tanks at the Savannah River Site (SRS). The site is currently in the process of waste removal from, and ultimately closure of, these tanks. One of the most time consuming steps in the waste removal process is cleaning the sludge heel from the bottom of the tanks to an acceptable residual quantity. The sludge consists primarily of metal oxides that formed after waste from the canyons was neutralized with sodium hydroxide. Since the canyon waste was originally a nitric acid solution, this acid is a prime candidate for sludge heel dissolution.

Wiersma, B.J.

2002-12-06T23:59:59.000Z

247

Two-photon nitric oxide laser-induced fluorescence measurements in a diesel engine  

Science Journals Connector (OSTI)

A two-photon nitric oxide (NO) laser-induced fluorescence (LIF) technique was developed and applied to study in-cylinder diesel combustion. The technique prevents many problems...

Martin, Glen C; Mueller, Charles J; Lee, Chia-Fon F

2006-01-01T23:59:59.000Z

248

Turn-on fluorescent probes for detecting nitric oxide in biology  

E-Print Network [OSTI]

Chapter 1. Investigating the Biological Roles of Nitric Oxide and Other Reactive Nitrogen Species Using Fluorescent Probes: This chapter presents an overview of recent progress in the field of reactive nitrogen species ...

McQuade, Lindsey Elizabeth, 1981-

2010-01-01T23:59:59.000Z

249

Quantum Cascade Laser Technology for the Ultrasensitive Detection of Low-Level Nitric Oxide  

Science Journals Connector (OSTI)

Several spectroscopic methods based on mid-infrared quantum cascade lasers for the ultrasensitive detection of nitric oxide ... the most effective techniques, i.e., laser absorption spectroscopy, cavity-enhanced ...

Angela Elia; Pietro Mario Lugarà; Cinzia Di Franco; Vincenzo Spagnolo

2011-01-01T23:59:59.000Z

250

Pathophysiology of endotoxin: microvascular dysfunction, and the roles of VEGF and nitric oxide (NO)  

E-Print Network [OSTI]

PATHOPHYSIOLOGY OF ENDOTOXIN: MICROVASCULAR DYSFUNCTION, AND THE ROLFS OF VEGF AND NITRIC OXIDE (NO) A Senior Honors Thesis bt MARK ANDREW NAFTANFL Submitted to the Olfice of Honors Programs A. Academic Scholarships Texas A&M University ln...

Naftanel, Mark Andrew

2013-02-22T23:59:59.000Z

251

Cell-Trappable Fluorescent Probes for Nitric Oxide Visualization in Living Cells  

E-Print Network [OSTI]

Two new cell-trappable fluorescent probes for nitric oxide (NO) are reported based on either incorporation of hydrolyzable esters or conjugation to aminodextran polymers. Both probes are highly selective for NO over other ...

Pluth, Michael D.

252

Seminaphthofluorescein-Based Fluorescent Probes for Imaging Nitric Oxide in Live Cells  

E-Print Network [OSTI]

Fluorescent turn-on probes for nitric oxide based on seminaphthofluorescein scaffolds were prepared and spectroscopically characterized. The Cu(II) complexes of these fluorescent probes react with NO under anaerobic ...

Pluth, Michael D.

253

The catalytic reduction of nitric oxide with ammonia over tetraamminecopper (II) complexes  

E-Print Network [OSTI]

THE CATALETIC REDUCTION OF NITRIC OXIDE NITH AMMONIA OVER TETRARPMINECOPPER(11) COMPLEXES A Thesis by Margaret Deron Oates Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirement for the degree... of MASTER OF SCIENCE August 1979 Major Subject: Chemistry THE CATALYTIC REDUCTION OF NITRIC OXIDE WITH AMMONIA OVER TETRAAMMINECOPPER(IZ) COMPLEXES A Thesis by Margaret Deron Dates Approved as to style and content by: (Chairman of Committe (Member...

Oates, Margaret Deron

1979-01-01T23:59:59.000Z

254

Arsenic toxicity induced endothelial dysfunction and dementia: Pharmacological interdiction by histone deacetylase and inducible nitric oxide synthase inhibitors  

SciTech Connect (OSTI)

Arsenic toxicity has been reported to damage all the major organs including the brain and vasculature. Dementia including Alzheimer's disease (AD) and vascular dementia (VaD) are posing greater risk to the world population as it is now increasing at a faster rate. We have investigated the role of sodium butyrate, a selective histone deacetylase (HDAC) inhibitor and aminoguanidine, a selective inducible nitric oxide synthase (iNOS) inhibitor in pharmacological interdiction of arsenic toxicity induced vascular endothelial dysfunction and dementia in rats. Arsenic toxicity was done by administering arsenic drinking water to rats. Morris water-maze (MWM) test was used for assessment of learning and memory. Endothelial function was assessed using student physiograph. Oxidative stress (aortic superoxide anion, serum and brain thiobarbituric acid reactive species, brain glutathione) and nitric oxide levels (serum nitrite/nitrate) were also measured. Arsenic treated rats have shown impairment of endothelial function, learning and memory, reduction in serum nitrite/nitrate and brain GSH levels along with increase in serum and brain TBARS. Sodium butyrate as well as aminoguanidine significantly convalesce arsenic induced impairment of learning, memory, endothelial function, and alterations in various biochemical parameters. It may be concluded that arsenic induces endothelial dysfunction and dementia, whereas, sodium butyrate, a HDAC inhibitor as well as aminoguanidine, a selective iNOS inhibitor may be considered as potential agents for the management of arsenic induced endothelial dysfunction and dementia. - Highlights: • As has induced endothelial dysfunction (Edf) and vascular dementia (VaD). • As has increased oxidative stress, AChE activity and decreased serum NO. • Inhibitors of HDAC and iNOS have attenuated As induced Edf and VaD. • Both the inhibitors have attenuated As induced biochemical changes. • Inhibitor of HDAC and iNOS has shown good potential in As induced VaD.

Sharma, Bhupesh, E-mail: drbhupeshresearch@gmail.com; Sharma, P.M.

2013-11-15T23:59:59.000Z

255

CRADA Final Report For CRADA NO. CR-12-006 [Operation and Testing of an SO{sub 2}-depolarized Electrolyzer (SDE) for the Purpose of Hydrogen and Sulfuric Acid Production  

SciTech Connect (OSTI)

Over the past several years, Savannah River National Laboratory (SRNL) has led a team of collaborators under the Department of Energy’s (DOE) nuclear hydrogen production program to develop the Hybrid Sulfur (HyS) Process. HyS is a 2-step water-splitting process consisting of high temperature decomposition of sulfuric acid to generate SO{sub 2}, followed by the electrolysis of aqueous SO{sub 2} to generate hydrogen and sulfuric acid. The latter is fed back into the high temperature reactor. SRNL designed and built an SO{sub 2}-depolarized electrolyzer (SDE) and a test facility. Over 40 SDE’s were tested using different catalysts, membranes and other components. SRNL demonstrated that an SDE could be operated continuously for approximately 200 hours under certain conditions without buildup of sulfur at the SDE’s cathode, thus solving a key technical problem with SDE technology. Air Products and Chemicals, Inc. (APCI) is a major supplier of hydrogen production systems, and they have proprietary technology that could benefit from the SDE developed by SRNS, or some improved version thereof. However, to demonstrate that SRNL’s SDE is a truly viable approach to the electrolyzer design, continuous operation for far greater periods of time than 200 hours must be demonstrated, and the electrolyzer must be scaled up to greater hydrogen production capacities. SRNL and Air Products entered into a Cooperative Research and Development Agreement with the objective of demonstrating the effectiveness of the SDE for hydrogen and sulfuric acid production and to demonstrate long-term continuous operation so as to dramatically increase the confidence in the SDE design for commercial operation. SRNL prepared a detailed technical report documenting previous SDE development, including the current SDE design and operating conditions that led to the 200-hour sulfurfree testing. SRNL refurbished its single cell SDE test facility and qualified the equipment for continuous operation. A new membrane electrode assembly (MEA) was fabricated and installed in the single cell electrolyzer (60 cm{sup 2} active cell area). Shakedown testing was conducted, and several modifications were made to the test facility equipment. Seven different MEAs were used during testing. Beginning on May 20, 2013, SRNL was able to test the SDE continuously for 1200 hours, including 1000 hours under power to generate hydrogen at an average rate of 10.8 liters per hour. The SDE was not removed or repaired during the 50-day test and was successfully restarted after each shutdown. The test was intentionally stopped after 1200 hours (1000 hours of hydrogen production) due to funding constraints. Post-test examination of the MEA using Scanning Electron Microscopy (SEM) and Energy Dispersive X-ray Microanalysis (EDAX) showed no elemental sulfur deposits or sulfur layer inside the cell, thus successfully achieving the test goals. The results demonstrated that the SDE could be operated for extended periods without major performance degradation or the buildup of sulfur inside the MEA. Air Products conducted an assessment of the economic viability of the SDE based on the “as tested” design. The results indicated that the SDE faces significant economic obstacles in its current state. Further development and scale-up are necessary before the SDE is ready for commercialization.

Summers, W. A.; Colon-Mercado, H. R.; Steimke, J. L.; Zahn, Steffen

2014-02-24T23:59:59.000Z

256

Superior catalysts for selective catalytic reduction of nitric oxide. Quarterly technical progress report, April 1, 1995--June 30, 1995  

SciTech Connect (OSTI)

Efforts continued towards the synthesis of new pillared clay catalysts for the selective catalytic reduction of nitric oxide by ammonia. The possibility of utilizing hydrocarbons was also investigated.

Li, W.B.; Yang, R.T.

1995-12-01T23:59:59.000Z

257

[Ni(PPh2NBn2)2(CH3CN)]2+ as an Electrocatalyst for H2 Production: Dependence on Acid Strength and Isomer Distribution  

Science Journals Connector (OSTI)

[Ni(PPh2NBn2)2(CH3CN)]2+ (where PPh2NBn2 is 1,5-dibenzyl-3,7-diphenyl-1,5-diaza-3,7-diphosphacyclooctane), has been studied as an electrocatalyst for the production of hydrogen in acetonitrile. ... Proton-Coupled Electron Transfer in Molecular Electrocatalysis: Theoretical Methods and Design Principles ...

Aaron M. Appel; Douglas H. Pool; Molly O’Hagan; Wendy J. Shaw; Jenny Y. Yang; M. Rakowski DuBois; Daniel L. DuBois; R. Morris Bullock

2011-04-22T23:59:59.000Z

258

Alternative Non-Acid Eluants for Spherical Resorcinol-Formaldehyde  

SciTech Connect (OSTI)

Small-column ion exchange (SCIX) units installed in or near high-level waste tanks to remove Cs-137 from highly alkaline solutions are among the waste treatment plans in the DOE Complex. Spherical Resorcinol-Formaldehyde (sRF) is the ion exchange (IX) resin under consideration for SCIX at the Hanford site. The elution step of the multi-step IX process is typically done with nitric acid. An acid eluant is a potential hazard in the event of a spill, leak, etc. because the waste tanks are made of carbon steel. Corrosion and associated structural damage may ensue. A non-acid eluant may be a viable alternative. It will eliminate the need for special acid handling requirements within the tank farms.

Adu-Wusu, Kofi

2010-11-01T23:59:59.000Z

259

Nitric Oxide Photogeneration from trans-Cr(cyclam)(ONO)2+ in a Reducing Environment. Activation of Soluble Guanylyl Cyclase and Arterial Vasorelaxation  

Science Journals Connector (OSTI)

We also demonstrate that photolysis of 1 in the nM concentration range with a portable blue LED leads to vasorelaxation of porcine coronary arterial rings, a process also attributed to the NO activation of sGC. ... Abbreviations: BSA, bovine serum albumin; CFL, compact fluorescent light-bulb; cGMP, cyclic guanosine monophosphate; cyclam, 1,4,8,11-tetraazacyclotetradecane; DEA/NO, (Z)-l-(N,N-diethylamino)-diazen-l-ium-l,2-diolate; EDTA, ethylenediaminetetraacetic acid; GSH, glutathione; GTP, guanosine triphosphate; sGC, soluble guanylyl cyclase; IBMX, isobutylmethylxanthine; LED, light emitting diode; NO, nitric oxide; NOA, nitric oxide analyzer; ODQ, 1H-[1,2,4]oxadiazolo[4,3-a]quinoxalin-1-one; U46619, 9,11-dideoxy-ll?,9?-epoxy-methanoprostaglandin F2?. ... data show that the expected fluorescence of the pendant chromophores is largely quenched when the macrocyclic ligand is coordinated to these Cr(III) centers, and this is interpreted in terms of fast energy transfer processes from the ligand-centered ??* states to the Cr(III)-centered ligand field states leading to subsequent cleavage of the Cr(III)-coordinated nitrito ligand. ...

Alexis D. Ostrowski; Sherine J. Deakin; Bilal Azhar; Thomas W. Miller; Nestor Franco; Melisa M. Cherney; Andrea J. Lee; Judith N. Burstyn; Jon M. Fukuto; Ian L. Megson; Peter C. Ford

2009-12-01T23:59:59.000Z

260

Acidic dissolution behavior of U containing ZrO2–MgO ceramics  

SciTech Connect (OSTI)

This study explores the possibility of dissolving zirconia-magnesia inert matrix fuel containing uranium oxide as a fissile material and plutonium homolog and erbium oxide as a burnable poison with nitric and sulfuric acid as a potential first step in a reprocessing scheme. The progress of the dissolution is followed by monitoring the amount of material in solution by inductively coupled plasma-atomic emission spectroscopy, assessing the speciation of the material by time resolved laser fluorescence spectroscopy, and determining and quantifying the crystalline phases present in the remaining residue by X-ray diffraction. This study has shown a linear incongruent dissolution of the cubic zirconia phase in concentrated nitric acid under certain chemical compositions, while the magnesium oxide phase is completely soluble. In sulfuric acid uranium, erbium, and magnesium are soluble to different extents while zirconium forms a colloidal suspension that conglomerates and settles out of solution. The feasibility of the dissolution of zirconia-magnesia inert matrix fuel with nitric and sulfuric acid for reprocessing is discussed.

Kiel Holliday; Nicholas Smith; Thomas Hartmann; Gary Cerefice; Ken Czerwinski

2011-11-01T23:59:59.000Z

Note: This page contains sample records for the topic "nitric acid production" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Laser-saturated fluorescence of nitric oxide and chemiluminescence measurements in premixed ethanol flames  

SciTech Connect (OSTI)

In this study, nitric oxide laser-saturated fluorescence (LSF) measurements were acquired from premixed ethanol flames at atmospheric pressure in a burner. NO-LSF experimental profiles for fuel-rich premixed ethanol flames ({phi} = 1.34 and {phi} = 1.66) were determined through the excitation/detection scheme of the Q{sub 2}(26.5) rotational line in the A{sup 2}{sigma}{sup +} - X{sup 2}{pi} (0,0) vibronic band and {gamma}(0,1) emission band. A calibration procedure by NO doping into the flame was applied to establish the NO concentration profiles in these flames. Chemiluminescent emission measurements in the (0, 0) vibronic emission bands of the OH{sup *} (A{sup 2}{sigma}{sup +} - X{sup 2}{pi}) and CH{sup *}(A{sup 2}{delta} - X{sup 2}{pi}) radicals were also obtained with high spatial and spectral resolution for fuel-rich premixed ethanol flames to correlate them with NO concentrations. Experimental chemiluminescence profiles and the ratios of the integrated areas under emission spectra (A{sub CH*}/A{sub CH*}(max.) and A{sub CH*}/A{sub OH*}) were determined. The relationships between chemiluminescence and NO concentrations were established along the premixed ethanol flames. There was a strong connection between CH{sup *} radical chemiluminescence and NO formation and the prompt-NO was identified as the governing mechanism for NO production. The results suggest the optimum ratio of the chemiluminescence of two radicals (A{sub CH*}/A{sub OH*}) for NO diagnostic purposes. (author)

Marques, Carla S.T.; Barreta, Luiz G.; Sbampato, Maria E.; dos Santos, Alberto M. [Aerothermodynamic and Hypersonic Division, Institute of Advanced Studies - General Command of Aerospatial Technology, Rodovia dos Tamoios, km 5.5, 12228-001 Sao Jose dos Campos - SP (Brazil)

2010-11-15T23:59:59.000Z

262

An Oleaginous Bacterium That Intrinsically Accumulates Long-Chain Free Fatty Acids in its Cytoplasm  

Science Journals Connector (OSTI)

...biodiesel production. INTRODUCTION Fatty acids with medium-length...practicality and yield of biodiesel production. Published...coli: implications for biodiesel production. Metab...fatty-acid-derived fuels and chemicals from plant...BF Pfleger. 2012. Engineering Escherichia coli to...

Taiki Katayama; Manabu Kanno; Naoki Morita; Tomoyuki Hori; Takashi Narihiro; Yasuo Mitani; Yoichi Kamagata

2013-12-02T23:59:59.000Z

263

EVALUATION OF POTENTIAL ELUANTS FOR NON-ACID ELUTION OF CESIUM FROM RESORCINOL-FORMALDEHYDE RESIN  

SciTech Connect (OSTI)

Small-column ion exchange (SCIX) units installed in high-level waste tanks to remove Cs-137 from highly alkaline salt solutions are among the waste treatment plans in the DOE-complex. Spherical Resorcinol-Formaldehyde (sRF) is the ion exchange resin selected for use in the Hanford Waste Treatment and Immobilization Plant (WTP). It is also the primary ion exchange material under consideration for SCIX at the Hanford site. The elution step of the multi-step ion exchange process is typically done with 0.5 M nitric acid. An acid eluant is a potential hazard in the event of a spill, leak, etc. because the high-level waste tanks are made of carbon steel. Corrosion and associated structural damage may ensue. A study has been conducted to explore non-acid elution as an alternative. Batch contact sorption equilibrium screening tests have been conducted with 36 potential non-acid eluants. The sorption tests involve equilibrating each cesium-containing eluant solution with the sRF resin for 48 hours at 25 C in a shaker oven. In the sorption tests, an eluant is deemed to have a high cesium elution potential if it minimizes cesium sorption onto the sRF resin. The top candidates (based on lowest cesium sorption distribution coefficients) include ammonium carbonate, ammonium carbonate/ammonium hydroxide, ammonium bicarbonate, rubidium carbonate, ammonium acetate, ammonium acetate/ammonium hydroxide, ammonium bicarbonate/ammonium hydroxide, calcium chloride, and magnesium chloride. A select few of the top candidate eluants from the screening tests were subjected to actual sorption (loading) and elution tests to confirm their elution ability. The actual sorption (loading) and elution tests mimicked the typical sRF-cesium ion exchange process (i.e., sorption or loading, caustic wash, water rinse, and elution) via batch contact sorption and quasi column caustic wash/water rinse/elution. The eluants tested included ammonium carbonate, ammonium acetate, calcium acetate, magnesium acetate, and nitric acid. Calcium acetate and magnesium acetate were substitutes for calcium chloride and magnesium chloride respectively due to corrosion concerns. Nitric acid was selected for benchmarking since it is the baseline cesium eluant for sRF resin. The cesium elution performance of ammonium carbonate and ammonium acetate was approximately the same as the benchmark eluant, nitric acid. Ninety-seven (97), 94, and 100% percent of the cesium sorbed or loaded were eluted by ammonium carbonate, ammonium acetate, and nitric acid was respectively. The performance of calcium acetate and magnesium acetate, on the other hand, was mediocre. Percent elution was 16 and 8 respectively.

Adu-Wusu, K.; Pennebaker, F.

2010-12-22T23:59:59.000Z

264

Neonatal Pulmonary Hypertension — Urea-Cycle Intermediates, Nitric Oxide Production, and Carbamoyl-Phosphate Synthetase Function  

Science Journals Connector (OSTI)

...mutation (unpublished data). We speculate that persons with the AA genotype may have an advantage in terms of urea-cycle function and interrelated metabolic processes, especially under conditions of environmental stress. Although the functional status of carbamoyl-phosphate synthetase appears to affect... Failure of the transition to a cardiorespiratory circulation at birth results in persistent pulmonary hypertension of the newborn. Characterized by elevated pulmonary vascular resistance with extrapulmonary right-to-left shunting of blood across the ...

Pearson D.L.; Dawling S.; Walsh W.F.

2001-06-14T23:59:59.000Z

265

A quantum chemical study of nitric oxide reduction by ammonia (SCR reaction) on V2O5 catalyst surface  

E-Print Network [OSTI]

A quantum chemical study of nitric oxide reduction by ammonia (SCR reaction) on V2O5 catalyst for the selective catalytic reduction (SCR) of nitric oxide by ammonia on (0 1 0) V2O5 surface represented by a V2O9/6-31G** level. The computations indicated that SCR reaction consisted of three main parts

Senkan, Selim M.

266

E-Print Network 3.0 - acid protects human Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Introduction: Scope of the Thesis Ansar A. Khan Summary: , 155). The major products of LCA metabolism in human and rat liver microsomes are hyodeoxycholic acid... bile acids such...

267

E-Print Network 3.0 - acid reactivity reaction Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

; Biology and Medicine 42 A Kinetic Study on the Decomposition of 5-Hydroxymethylfurfural into Summary: -soluble products Levulinic acid + Formic acid Figure 3.1...

268

E-Print Network 3.0 - acid-soluble organic matrix Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Environmental Sciences and Ecology 38 A Kinetic Study on the Decomposition of 5-Hydroxymethylfurfural into Summary: - methylfurfural Acid-soluble products Levulinic acid + Formic...

269

The Scientific Basis of Tobacco Product Regulation  

E-Print Network [OSTI]

contains nitric oxide, nitrogen dioxide and nitrous oxide,nitric oxide, while nitrogen dioxide is rapidly formedreadily oxidized to nitrogen dioxide, a pulmonary irritant.

World Health Organization

2008-01-01T23:59:59.000Z

270

An Improved Model for Sandstone Acidizing and Study of the Effect of Mineralogy and Temperature on Sandstone Acidizing Treatments and Simulation  

E-Print Network [OSTI]

Sandstone acidizing is a complex operation because the acidizing fluid reacts with a variety of minerals present in the formation that results in a wide range of reaction products. The hydrofluoric acid (HF) reaction rate differs widely from mineral...

Agarwal, Amit Kumar

2013-01-14T23:59:59.000Z

271

Joule heating and nitric oxide in the thermosphere, 2 Charles A. Barth1  

E-Print Network [OSTI]

Joule heating and nitric oxide in the thermosphere, 2 Charles A. Barth1 Received 14 April 2010, gravity waves propagate from the polar regions toward the equator heating the thermosphere at 140 km and higher. These gravity waves are produced by Joule heating that occurs at latitudes of 60° and higher

Bailey, Scott

272

Strategies for laser-induced fluorescence detection of nitric oxide in high-pressure flames.  

E-Print Network [OSTI]

engines and gas turbines where the combustion chamber is at high pressure. Despite the use of catalyticStrategies for laser-induced fluorescence detection of nitric oxide in high-pressure flames. II. A combustion systems3�13 and thus develop new schemes to mini- mize NO effluent. The high operating pressure

Lee, Tonghun

273

Development and testing of an advanced acid fracture conductivity apparatus  

E-Print Network [OSTI]

wells. Acid fracturing is a standard practice to increase the production rate and to improve ultimate recovery in carbonate reservoirs. There have been successful cases in most carbonate reservoirs around the world. However acid fracture performance...

Zou, ChunLei

2006-08-16T23:59:59.000Z

274

The Effect of Heterogeneity on Matrix Acidizing of Carbonate Rocks  

E-Print Network [OSTI]

In matrix acidizing, the goal is to dissolve minerals in the rock to increase well productivity. This is accomplished by injecting an application-specific solution of acid into the formation at a pressure between the pore pressure and fracture...

Keys, Ryan S.

2010-07-14T23:59:59.000Z

275

Kinetic evaluation of the esterification of fatty acids to biodiesel  

Science Journals Connector (OSTI)

The free fatty acids of cotton seed oil were processed with methanol and ethanol into the corresponding alkyl fatty esters in the presence of diluted sulfuric acid. The products characterized as biodiesels pre...

Frederico A. D. Araújo; Sonia V. Pereira…

2012-10-01T23:59:59.000Z

276

The role of nitric oxide in testosterone-induced vasodilation in pig coronary arteries and rat thoracic aorta  

E-Print Network [OSTI]

Several studies have provided evidence that the administration of testosterone to vascular tissue causes vasodilation (Costarella, Yue). This study examines the role of nitric oxide (NO) as a potential mechanism of testosterone-induced vasodilation...

Piefer, Jason William

2013-02-22T23:59:59.000Z

277

Specific Visualization of Nitric Oxide in the Vasculature with Two-Photon Microscopy Using a Copper Based Fluorescent Probe  

E-Print Network [OSTI]

To study the role and (sub) cellular nitric oxide (NO) constitution in various disease processes, its direct and specific detection in living cells and tissues is a major requirement. Several methods are available to measure ...

Ghosh, Mitrajit

278

Radioiodinated fatty acid analogs for myocardial imaging  

SciTech Connect (OSTI)

Fatty acids are the preferred substrate for the normoxic heart. About sixty percent of the energy required by the myocardium is provided by fatty acid [beta]-oxidation. Many scientists have focused on the alterations in fatty acid metabolism in the ischemic heart for the development of radiolabelled fatty acids for functional imaging of the heart. Three main categories of compounds were synthesized: tetrazoles (1 and 2), glycidic and [alpha]-methylene acids (3-5), and analogs of oleic acid (6,7 and 7A). The tetrazole group has a similar pKa and size to that of a carboxyl group; however, such fatty acid analogs cannot undergo normal fatty acid metabolism. Glycidic and [alpha]-methylene analogs are potential irreversible inhibitors of fatty acid metabolism. Oleic acid analogs were investigated to assess the affect of stereochemical consequences on biodistribution. The key intermediates in the synthesis of the target compounds were [omega]-nitrophenyl alkylcarboxylic acids and alcohols, which were made using a variety of cross-coupling reactions. The Wittig reaction, which was used in the synthesis of tetrazole 1 and glycidic acid 3, gave low yields of the cross-coupled products. The remaining target compounds were synthesized by condensation of appropriate RCu (CN) ZnI and substituted benzyl bromides or by Pd[sup II] catalyzed cross-coupling of substituted arylhalides with suitable alkynes. The latter two reactions produced much higher yields of the desired products. All of the target compounds were radiolabeled with [sup 125]I by various Cu(I) catalyzed radioiodine exchange procedures and were then subjected to tissue biodistribution (TD) studies in rats. Except for the 15-(4-iodophenyl)-2-methylene-pentadecanoic acid (5), all of the fatty acid analogs failed to surpass clinically-used 15-(4-iodophenyl)pentadecanoic acid (IPPA) in their ability to be taken up and retained by the rat myocardium.

Ruyan, M.K.

1993-01-01T23:59:59.000Z

279

Fatty acid production in genetically modified cyanobacteria  

Science Journals Connector (OSTI)

...genetically manipulatable than algae (5). In the field of algal or cyanobacterial...which can be converted into biodiesel by esterification...green light for engineered algae: redirecting metabolism to fuel...436 . 6 Chisti Y ( 2008 ) Biodiesel from microalgae beats bioethanol...

Xinyao Liu; Jie Sheng; Roy Curtiss III

2011-01-01T23:59:59.000Z

280

Lactic acid fermentation of crude sorghum extract  

SciTech Connect (OSTI)

Crude extract from sweet sorghum supplemented with vetch juice was utilized as the carbohydrate source for fermentative production of lactic acid. Fermentation of media containing 7% (w/v) total sugar was completed in 60-80 hours by Lactobacillus plantarum, product yield averaging 85%. Maximum acid production rates were dependent on pH, initial substrate distribution, and concentration, the rates varying from 2 to 5 g/liter per hour. Under limited medium supplementation the lactic acid yield was lowered to 67%. The fermented ammoniated product contained over eight times as much equivalent crude protein (N x 6.25) as the original medium. Unstructured kinetic models were developed for cell growth, lactic acid formation, and substrate consumption in batch fermentation. With the provision of experimentally determined kinetic parameters, the proposed models accurately described the fermentation process. 15 references.

Samuel, W.A.; Lee, Y.Y.; Anthony, W.B.

1980-04-01T23:59:59.000Z

Note: This page contains sample records for the topic "nitric acid production" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Heterogeneous Reactions of Epoxides in Acidic Media  

E-Print Network [OSTI]

on sulfuric acid using Ion drift-Chemical Ionization Mass Spectrometry (ID-CIMS) showed an irreversible uptake of epoxides at room temperature resulting in the formation of less volatile products like diols, organosulfates and acetals. However, at lower...

Lal, Vinita

2012-02-14T23:59:59.000Z

282

Ascorbic Acid and Cancer: A Review  

Science Journals Connector (OSTI)

...skinned individuals resident in areas of high solar intensity, such as the southern United States, South Africa, and Australia. Experimentally, the...Effects of Ascorbic Acid Ascorbate and Energy Production. Cytochromes P-450 and b5are...

Ewan Cameron; Linus Pauling; and Brian Leibovitz

1979-03-01T23:59:59.000Z

283

Investigating fatty acid biosynthesis within the algal chloroplast using Chlamydomonas reinhardtii as a model  

E-Print Network [OSTI]

offering a continuous algal production-secretion system thatalgal lipids [124]. As such, there are many research groups interested in engineering fatty acid production and secretion

Blatti, Jillian L.

2012-01-01T23:59:59.000Z

284

E-Print Network 3.0 - acid tar sludges Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of diethylphosphorodithioic acid in the production of phorate. K040 Wastewater treatment sludge from the production of phorate... of facilities within the iron and steel...

285

Extraction of Plutonium into 30 Percent Tri-Butyl Phosphate from Nitric Acid Solution Containing Fluoride, Aluminum, and Boron  

SciTech Connect (OSTI)

This work consists of experimental batch extraction data for plutonium into 30 volume-percent tri-butyl phosphate at ambient temperature from such a solution matrix and a model of this data using complexation constants from the literature.

Kyser, E.A.

2000-01-06T23:59:59.000Z

286

Removal of radium from acidic solutions containing same by adsorption on coal fly ash  

DOE Patents [OSTI]

The invention is a process for the removal of radium from acidic aqueous solutions. In one aspect, the invention is a process for removing radium from an inorganic-acid solution. The process comprises contacting the solution with coal fly ash to effect adsorption of the radium on the ash. The radium-containing ash then is separated from the solution. The process is simple, comparatively inexpensive, and efficient. High radium-distribution coefficients are obtained even at room temperature. Coal fly ash is an inexpensive, acid-resistant, high-surface-area material which is available in large quantities throughout the United States. The invention is applicable, for example, to the recovery of .sup.226 Ra from nitric acid solutions which have been used to leach radium from uranium-mill tailings.

Scheitlin, Frank M. (Oak Ridge, TN)

1984-01-01T23:59:59.000Z

287

Self-assembling multimeric nucleic acid constructs  

DOE Patents [OSTI]

The invention is directed to constructs and compositions containing multimeric forms of nucleic acid. Multimeric nucleic acids comprise single-stranded nucleic acids attached via biotin to streptavidin and bound with a functional group. These constructs can be utilized in vivo to treat or identify diseased tissue or cells. Repeated administrations of multimeric nucleic acid compositions produce a rapid and specific amplification of nucleic acid constructs and their attached functional groups. For treatment purposes, functional groups may be toxins, radioisotopes, genes or enzymes. Diagnostically, labeled multimeric constructs may be used to identify specific targets in vivo or in vitro. Multimeric nucleic acids may also be used in nanotechnology and to create self-assembling polymeric aggregates such as membranes of defined porosity, microcircuits and many other products.

Cantor, Charles R. (Boston, MA); Niemeyer, Christof M. (Bremen, DE); Smith, Cassandra L. (Boston, MA); Sano, Takeshi (Boston, MA); Hnatowich, Donald J. (Brookline, MA); Rusckowski, Mary (Southborough, MA)

1996-01-01T23:59:59.000Z

288

Self-assembling multimeric nucleic acid constructs  

DOE Patents [OSTI]

The invention is directed to constructs and compositions containing multimeric forms of nucleic acid. Multimeric nucleic acids comprise single-stranded nucleic acids attached via biotin to streptavidin and bound with a functional group. These constructs can be utilized in vivo to treat or identify diseased tissue or cells. Repeated administrations of multimeric nucleic acid compositions produce a rapid and specific amplification of nucleic acid constructs and their attached functional groups. For treatment purposes, functional groups may be toxins, radioisotopes, genes or enzymes. Diagnostically, labeled multimeric constructs may be used to identify specific targets in vivo or in vitro. Multimeric nucleic acids may also be used in nanotechnology and to create self-assembling polymeric aggregates such as membranes of defined porosity, microcircuits and many other products.

Cantor, Charles R. (Boston, MA); Niemeyer, Christof M. (Bremen, DE); Smith, Cassandra L. (Boston, MA); Sano, Takeshi (Boston, MA); Hnatowich, Donald J. (Brookline, MA); Rusckowski, Mary (Southborough, MA)

1999-10-12T23:59:59.000Z

289

Interaction of inflammatory and anti-inflammatory responses in microglia by Staphylococcus aureus-derived lipoteichoic acid  

SciTech Connect (OSTI)

We investigated the interaction between proinflammatory and inflammatory responses caused by Staphylococcus aureus-derived lipoteichoic acid (LTA) in primary cultured microglial cells and BV-2 microglia. LTA induced inducible nitric oxide synthase (iNOS) and cyclooxygenase-2 (COX-2) protein levels increase in a concentration- and time-dependent manner. Meanwhile, LTA also increased nitric oxide (NO) and PGE{sub 2} production in microglia. Administration of TLR2 antagonist effectively inhibited LTA-induced NO, iNOS, and COX-2 expression. Moreover, treatment of cells with LTA caused a time-dependent activation of ERK, p38, JNK, as well as AKT. We also found that LTA-induced iNOS and COX-2 up-regulation were attenuated by p38, JNK, and PI3-kinase inhibitors. On the other hand, LTA-enhanced HO-1 expression was attenuated by p38 and PI3-kinase inhibitors. Treatment of cells with NF-?B and AP-1 inhibitors antagonized LTA-induced iNOS and COX-2 expression. However, only NF-?B inhibitors reduced LTA-induced HO-1 expression in microglia. Furthermore, stimulation of cells with LTA also activated I?B? phosphorylation, p65 phosphorylation at Ser{sup 536}, and c-Jun phosphorylation. Moreover, LTA-induced increases of ?B-DNA and AP-1-DNA binding activity were inhibited by p38, JNK, and PI3-kinase inhibitors. HO-1 activator CoPP IX dramatically reversed LTA-induced iNOS expression. Our results provided mechanisms linking LTA and inflammation/anti-inflammation, and indicated that LTA plays a regulatory role in microglia activation. - Highlights: • LTA causes an increase in iNOS, COX-2, and HO-1 expression in microglia. • LTA induces iNOS and COX-2 expression through TLR-2/NF-?B and AP-1 pathways. • HO-1 expression is regulated through p38, JNK, PI3K/AKT and AP-1 pathways. • Induced HO-1 reduces LTA-induced iNOS expression. • LTA plays a regulatory role on inflammatory/anti-inflammatory responses.

Huang, Bor-Ren [Department of Neurosurgery, Buddhist Tzu Chi General Hospital, Taichung Branch, Taichung, Taiwan (China); Institute of Clinical Medical Science, China Medical University, Taichung, Taiwan (China); Tsai, Cheng-Fang [Department of Biotechnology, Asia University, Taichung, Taiwan (China); Lin, Hsiao-Yun [Department of Life Sciences, National Chung Hsing University, Taichung, Taiwan (China); Tseng, Wen-Pei [Graduate Institute of Sports and Health, National Changhua University of Education, Changhua County, Taiwan (China); Huang, Shiang-Suo [Department of Pharmacology and Institute of Medicine, College of Medicine, Chung Shan Medical University, Taiwan (China); Wu, Chi-Rei [Graduate Institute of Chinese Pharmaceutical Sciences, College of Pharmacy, China Medical University, Taiwan (China); Lin, Chingju [Department of Physiology, School of Medicine, China Medical University, Taichung, Taiwan (China); Yeh, Wei-Lan [Cancer Research Center, Department of Medical Research, Changhua Christian Hospital, Changhua, Taiwan (China); Lu, Dah-Yuu, E-mail: dahyuu@mail.cmu.edu.tw [Graduate Institute of Neural and Cognitive Sciences, China Medical University, Taichung, Taiwan (China)

2013-05-15T23:59:59.000Z

290

Plasma Production via Field Ionization  

SciTech Connect (OSTI)

Plasma production via field ionization occurs when an incoming particle beam is sufficiently dense that the electric field associated with the beam ionizes a neutral vapor or gas. Experiments conducted at the Stanford Linear Accelerator Center explore the threshold conditions necessary to induce field ionization by an electron beam in a neutral lithium vapor. By independently varying the transverse beam size, number of electrons per bunch or bunch length, the radial component of the electric field is controlled to be above or below the threshold for field ionization. Additional experiments ionized neutral xenon and neutral nitric oxide by varying the incoming beam's bunch length. A self-ionized plasma is an essential step for the viability of plasma-based accelerators for future high-energy experiments.

O'Connell, C.L.; Barnes, C.D.; Decker, F.; Hogan, M.J.; Iverson, R.; Krejcik, P.; Siemann, R.; Walz, D.R.; /SLAC; Clayton, C.E.; Huang, C.; Johnson, D.K.; Joshi, C.; Lu,; Marsh, K.A.; Mori, W.; Zhou, M.; /UCLA; Deng, S.; Katsouleas, T.; Muggli, P.; Oz, E.; /Southern California U.

2007-01-02T23:59:59.000Z

291

Selective reduction of nitric oxide with ammonia over vanadia on pillared titanium phosphate  

E-Print Network [OSTI]

in the catalyst. Shikada et al. (1981) compared AlzOz, SiOz, and SiO, ? TiOz (equimolar) supports for VzOs using a simulated flue gas containing 100 ppni SOz. The silica- titanium dioxide supported catalyst showed the highest NO conversions followed by those...SELECTIVE REDUCTION OF NITRIC OXIDE YVITH AMMONIA OVER VANADIA ON PILLARED TITANIUM PHOSPHATE A Thesis LAWRENCE JOSEPH CZARNECKI Submitted to the Graduate College of Texas AkM University in partial fulfillment of the requirement for the degree...

Czarnecki, Lawrence Joseph

1988-01-01T23:59:59.000Z

292

Some Suggested Pest Control Products Appropriate for an IPM Program  

E-Print Network [OSTI]

Some Suggested Pest Control Products Appropriate for an IPM Program I P M (professional use products) Cockroaches Product Formulation Active Ingredient Maxforce bait stations Hydramethylnon Station (IGR) Hydroprene Dusts Silica aerogel or boric acid Compressed air flushing agent air Carpenter

Virginia Tech

293

Nucleic acid detection methods  

DOE Patents [OSTI]

The invention relates to methods for rapidly determining the sequence and/or length a target sequence. The target sequence may be a series of known or unknown repeat sequences which are hybridized to an array of probes. The hybridized array is digested with a single-strand nuclease and free 3{prime}-hydroxyl groups extended with a nucleic acid polymerase. Nuclease cleaved heteroduplexes can be easily distinguish from nuclease uncleaved heteroduplexes by differential labeling. Probes and target can be differentially labeled with detectable labels. Matched target can be detected by cleaving resulting loops from the hybridized target and creating free 3-hydroxyl groups. These groups are recognized and extended by polymerases added into the reaction system which also adds or releases one label into solution. Analysis of the resulting products using either solid phase or solution. These methods can be used to detect characteristic nucleic acid sequences, to determine target sequence and to screen for genetic defects and disorders. Assays can be conducted on solid surfaces allowing for multiple reactions to be conducted in parallel and, if desired, automated. 18 figs.

Smith, C.L.; Yaar, R.; Szafranski, P.; Cantor, C.R.

1998-05-19T23:59:59.000Z

294

The application of N,N-dimethyl-3-oxa-glutaramic acid (DOGA) in the PUREX process  

SciTech Connect (OSTI)

The new salt-free complexant, DOGA for separating trace Pu(IV) and Np(IV) from U(VI) nitric acid solution was studied. DOGA has stronger complexing abilities to Pu(IV) and Np(IV), but complexing ability of DOGA to U(VI) was weaker. The DOGA can be used in the PUREX process to separate Pu(IV) and Np(IV) from U(VI) nitric solution. On one hand, U(IV) in the nitric acid solution containing trace Pu(IV) and Np(IV) was extracted by 30%TBP - kerosene(v/v) in the presence of DOGA, but Pu(IV) and Np(IV) were kept in the aqueous phase. On the other hand, Pu(IV) and Np(IV) loading in 30% TBP - kerosene were effectively stripped by DOGA into the aqueous phase, but U(VI) loading in 30% TBP - kerosene was remained in 30% TBP - kerosene. DOGA is a promising complexant to separate Pu(IV) and Np(IV) from U(VI) solution in the U-cycle of the PUREX process. (authors)

Jianchen, Wang; Jing, Chen [Institute of Nuclear and New Energy Technology - INET, Tsinghua University, P.O. Box 1021, Beijing 102201 (China)

2007-07-01T23:59:59.000Z

295

Cisplatin upregulates mitochondrial nitric oxide synthase and peroxynitrite formation to promote renal injury  

SciTech Connect (OSTI)

The mitochondria are a critical target for cisplatin-associated nephrotoxicity. Though nitric oxide formation has been implicated in the toxicity of cisplatin, this formation has not so far been related to a possible activation of mitochondrial nitric oxide synthase (mNOS). We show here that the upregulation of oxide mNOS and peroxynitrite formation in cisplatin treatment are key events that influence the development of the harmful parameters described in cisplatin-associated kidney failure. We confirm this by isolating the mitochondrial fraction of the kidney and across different access routes such as the use of a specific inhibitor of neuronal NOS, L-NPA, a peroxynitrite scavenger, FeTMPyP, and a peroxynitrite donor, SIN-1. The in vitro studies corroborated the information obtained in the in vivo experiments. The administration of cisplatin reveals a clear upregulation in the transcription of neuronal NOS and an increase in the levels of nitrites in the mitochondrial fractions of the kidneys. The upregulated transcription directly affects the cytoskeleton structure and the apoptosis. The inhibition of neuronal NOS reduces the levels of nitrites, cell death, and cytoskeleton derangement. Peroxynitrite is involved in the mechanism promoting the NOS transcription. In addition, in controls SIN-1 imitates the effects of cisplatin. In summary, we demonstrate that upregulation of mNOS in cisplatin treatment is a key component in both the initiation and the spread of cisplatin-associated damage in the kidney. Furthermore, peroxynitrite formation is directly involved in this process.

Jung, Michaela [Department of Ischemia and Inflammation, Instituto de Investigaciones Biomedicas, IIBB-CSIC-IDIBAPS, C/ Rossello, 161, 7a, 08036 Barcelona (Spain); Hotter, Georgina; Vinas, Jose Luis [Department of Ischemia and Inflammation, Instituto de Investigaciones Biomedicas, IIBB-CSIC-IDIBAPS, C/ Rossello, 161, 7a, 08036 Barcelona (Spain); CIBER-BBN, Networking Center on Bioengineering, Biomaterials and Nanomedicine, Barcelona (Spain); Sola, Anna [Department of Ischemia and Inflammation, Instituto de Investigaciones Biomedicas, IIBB-CSIC-IDIBAPS, C/ Rossello, 161, 7a, 08036 Barcelona (Spain); CIBER-BBN, Networking Center on Bioengineering, Biomaterials and Nanomedicine, Barcelona (Spain)], E-mail: asmbam@iibb.csic.es

2009-01-15T23:59:59.000Z

296

Using GIS to predict, quantify and visualise water quality and long term stream ecology effects/changes caused by acid mining drainage.  

E-Print Network [OSTI]

??Acid mine drainage (AMD) has been a detrimental by-product of coal mining for many years. At present, acid mine drainage continues to pose a potential… (more)

Mischker, J??rgen

2004-01-01T23:59:59.000Z

297

Effect of potassium permanganate as an oxidizing agent in the production of lignite-based fertilizers  

SciTech Connect (OSTI)

The purpose of this work was to observe the effect of potassium permanganate oxidation of lignites from Elbistan for end use as fertilizers, after being ammoniated. The experiments at each stage were designed by a 1/2 x full factorial design. The oxidation was carried out by three different methods. In the first two methods potassium permanganate in neutral or basic medium was used. In the other method two stages of oxidation were used: nitric acid followed by potassium permanganate in acidic medium. The latter proved to be more successful.

Baris, S.; Dincer, S.

1986-01-01T23:59:59.000Z

298

Processes to remove acid forming gases from exhaust gases  

DOE Patents [OSTI]

The present invention relates to a process for reducing the concentration of NO in a gas, which process comprises: (A) contacting a gas sample containing NO with a gaseous oxidizing agent to oxidize the NO to NO[sub 2]; (B) contacting the gas sample of step (A) comprising NO[sub 2] with an aqueous reagent of bisulfite/sulfite and a compound selected from urea, sulfamic acid, hydrazinium ion, hydrazoic acid, nitroaniline, sulfanilamide, sulfanilic acid, mercaptopropanoic acid, mercaptosuccinic acid, cysteine or combinations thereof at between about 0 and 100 C at a pH of between about 1 and 7 for between about 0.01 and 60 sec; and (C) optionally contacting the reaction product of step (A) with conventional chemical reagents to reduce the concentrations of the organic products of the reaction in step (B) to environmentally acceptable levels. Urea or sulfamic acid are preferred, especially sulfamic acid, and step (C) is not necessary or performed. 16 figs.

Chang, S.G.

1994-09-20T23:59:59.000Z

299

Nanomedicine: Action of Metal Nanoparticles on Neuronal Nitric Oxide Synthase—Fluorimetric Analysis on the Mechanism for Fibrillogenesis  

Science Journals Connector (OSTI)

The incubation of neuronal nitric oxide synthase with the five amyloid peptide fragments [A?17–21; A?25–29; A?29–33; A?33–37; A?25–37] catalyzed the formation of fibrils. The role of neuronal isomer (nNOS) involv...

E. R. Padayachee; A. Arowolo; C. G. Whiteley

2014-01-01T23:59:59.000Z

300

Hydrogen Peroxideâ??Mediated Activation of MAP Kinase 6 Modulates Nitric Oxide Biosynthesis and Signal Transduction in Arabidopsis  

Science Journals Connector (OSTI)

...Peroxide-Mediated Activation of MAP Kinase 6 Modulates Nitric Oxide Biosynthesis and Signal Transduction in Arabidopsis [w] Pengcheng Wang a Yanyan Du a Yuan Li b Dongtao Ren b Chun-Peng Song a 1 1 Address correspondence to songcp@henu.edu.cn . a Laboratory...

Pengcheng Wang; Yanyan Du; Yuan Li; Dongtao Ren; Chun-Peng Song

2010-09-24T23:59:59.000Z

Note: This page contains sample records for the topic "nitric acid production" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Catalytic oxidative conversion of cellulosic biomass to formic acid and acetic acid with exceptionally high yields  

Science Journals Connector (OSTI)

Abstract Direct conversion of raw biomass materials to fine chemicals is of great significance from both economic and ecological perspectives. In this paper, we report that a Keggin-type vanadium-substituted phosphomolybdic acid catalyst, namely H4PVMo11O40, is capable of converting various biomass-derived substrates to formic acid and acetic acid with high selectivity in a water medium and oxygen atmosphere. Under optimized reaction conditions, \\{H4PVMo11O40\\} gave an exceptionally high yield of formic acid (67.8%) from cellulose, far exceeding the values achieved in previous catalytic systems. Our study demonstrates that heteropoly acids are generally effective catalysts for biomass conversion due to their strong acidities, whereas the composition of metal addenda atoms in the catalysts has crucial influence on the reaction pathway and the product selectivity.

Jizhe Zhang; Miao Sun; Xin Liu; Yu Han

2014-01-01T23:59:59.000Z

302

Acid-catalyzed dehydrogenation of amine-boranes  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Acid-catalyzed dehydrogenation of amine-boranes Acid-catalyzed dehydrogenation of amine-boranes Acid-catalyzed dehydrogenation of amine-boranes A method of dehydrogenating an amine-borane using an acid-catalyzed reaction. June 25, 2013 Acid-catalyzed dehydrogenation of amine-boranes A method of dehydrogenating an amine-borane using an acid-catalyzed reaction. Available for thumbnail of Feynman Center (505) 665-9090 Email Acid-catalyzed dehydrogenation of amine-boranes A method of dehydrogenating an amine-borane using an acid-catalyzed reaction. The method generates hydrogen and produces a solid polymeric product. The method of dehydrogenating amine-boranes may be used to generate hydrogen for power generation sources such as fuel cells. U.S. Patent No.: 7,645,902 (DOE S-104,909) Patent Application Filing Date: June 22, 2006

303

Reaction of nitric oxide with heme proteins and model compounds of hemoglobin  

SciTech Connect (OSTI)

Rates for the reaction of nitric oxide with several ferric heme proteins and model compounds have been measured. The NO combination rates are markedly affected by the presence or absence of distal histidine. Elephant myoglobin in which the E7 distal histidine has been replaced by glutamine reacts with NO 500-1000 times faster than do the native hemoglobins or myoglobins. By contrast, there is not difference in the CO combination rate constants of sperm whale and elephant myoglobins. Studies on ferric model compounds for the R and T states of hemoglobin indicate that their NO combination rate constants are similar to those observed for the combination of CO with the corresponding ferro derivatives. The last observation suggests that the presence of an axial water molecule at the ligand binding site of ferric hemoglobin A prevents it from exhibiting significant cooperativity in its reactions with NO.

Sharma, V.S.; Traylor, T.G.; Gardiner, R.; Mizukami, H.

1987-06-30T23:59:59.000Z

304

Structure of a Loose Dimer: an Intermediate in Nitric Oxide Synthase Assembly  

SciTech Connect (OSTI)

Cooperativity among ligand binding, subunit association, and protein folding has implications for enzyme regulation as well as protein aggregation events associated with disease. The binding of substrate l-arginine or cofactor tetrahydrobiopterin converts nitric oxide synthases (NOSs) from a 'loose dimer', with an exposed active center and higher sensitivity to proteolysis, to a 'tight dimer' competent for catalysis. The crystallographic structure of the Bacillus subtilis NOS loose dimer shows an altered association state with severely destabilized subdomains. Ligand binding or heme reduction converts loose dimers to tight dimers in solution and crystals. Mutations at key positions in the dimer interface that distinguish prokaryotic from eukaryotic NOSs affect the propensity to form loose dimers. The loose dimer structure indicates that non-native interactions can mediate subunit association in NOS.

Pant,K.; Crane, B.

2005-01-01T23:59:59.000Z

305

A Comparative Study of Dolomite Dissolution in Simple Organic Acids and Chelating Agents  

E-Print Network [OSTI]

Acid treatments have predominantly been conducted using HCl for its availability, high rock dissolving power and soluble reaction products. At high temperatures, rapid spending of the acid with carbonates prevents deeper penetration distance...

Adenuga, Olusegun O

2013-05-03T23:59:59.000Z

306

Three-dimensional Modeling of Acid Transport and Etching in a Fracture  

E-Print Network [OSTI]

Acid fracture stimulation generates higher well production but requires engineering design for treatment optimization. To quantify the cost and benefit of a particular acid fracture treatment an engineer must predict the resulting fracture...

Oeth, Cassandra V

2013-11-25T23:59:59.000Z

307

In vivo unnatural amino acid expression in the methylotrophic yeast Pichia pastoris  

DOE Patents [OSTI]

The invention provides orthogonal translation systems for the production of polypeptides comprising unnatural amino acids in methyltrophic yeast such as Pichia pastoris. Methods for producing polypeptides comprising unnatural amino acids in methyltrophic yeast such as Pichia pastoris are also provided.

Young, Travis [San Diego, CA; Schultz, Peter G [La Jolla, CA

2014-02-11T23:59:59.000Z

308

Identification of Transport Proteins Involved in Free Fatty Acid Efflux in Escherichia coli  

Science Journals Connector (OSTI)

...Dunlop MJ . 2011. Engineering microbes for tolerance...Mukhopadhyay. 2011. Engineering microbial biofuel tolerance...implications for biodiesel production. Metab...fatty-acid-derived fuels and chemicals from...Quantitative analysis and engineering of fatty acid biosynthesis...

Rebecca M. Lennen; Mark G. Politz; Max A. Kruziki; Brian F. Pfleger

2012-10-26T23:59:59.000Z

309

Docosahexaenoic acid and butyrate synergistically modulate intracellular calcium compartmentalization to induce colonocyte apoptosis  

E-Print Network [OSTI]

Docosahexaenoic acid (DHA, 22:6n-3) from fish oil, and butyrate, a short-chain fatty acid fiber-fermentation product, protect against colon tumorigenesis in part by coordinately inducing apoptosis. We have demonstrated that the combination...

Kolar, Satya Sree N.

2009-05-15T23:59:59.000Z

310

Phosphatidic acid: an emerging plant lipid second messenger  

Science Journals Connector (OSTI)

Evidence is accumulating that phosphatidic acid is a second messenger. Its level increases within minutes of a wide variety of stress treatments including ethylene, wounding, pathogen elicitors, osmotic and oxidative stress, and abscisic acid. Enhanced signal levels are rapidly attenuated by phosphorylating phosphatidic acid to diacylglycerol pyrophosphate. Phosphatidic acid is the product of two signalling pathways, those of phospholipases C and D, the former in combination with diacylglycerol kinase. Families of these genes are now being cloned from plants. Several downstream targets of phosphatidic acid have been identified, including protein kinases and ion channels.

Teun Munnik

2001-01-01T23:59:59.000Z

311

Methods and systems for chemoautotrophic production of organic compounds  

DOE Patents [OSTI]

The present disclosure identifies pathways, mechanisms, systems and methods to confer chemoautotrophic production of carbon-based products of interest, such as sugars, alcohols, chemicals, amino acids, polymers, fatty acids and their derivatives, hydrocarbons, isoprenoids, and intermediates thereof, in organisms such that these organisms efficiently convert inorganic carbon to organic carbon-based products of interest using inorganic energy, such as formate, and in particular the use of organisms for the commercial production of various carbon-based products of interest.

Fischer, Curt R.; Che, Austin J.; Shetty, Reshma P.; Kelly, Jason R.

2013-01-08T23:59:59.000Z

312

Fatty acid analogs  

DOE Patents [OSTI]

In one aspect, a radioactively labeled analog of a fatty acid which is capable of being taken up by mammalian tissue and which exhibits an in vivo beta-oxidation rate below that with a corresponding radioactively labeled fatty acid.

Elmaleh, David R. (Newton Center, MA); Livni, Eli (Brookline, MA)

1985-01-01T23:59:59.000Z

313

A ACID RAIN Audrey Gibson  

E-Print Network [OSTI]

- SO2 Emissions of sulfur dioxide (SO2) and oxides of nitrogen (NOx) react in the atmosphere with water;Gas Natural Sources Concentration Carbon dioxide CO2 Decomposition 355 ppm Nitric oxide NO Electric discharge 0.01 ppm Sulfur dioxide SO2 Volcanic gases 0-0.01 ppm Table 1 Carbon dioxide, produced

Toohey, Darin W.

314

Uniform nano-ripples on the sidewall of silicon carbide micro-hole fabricated by femtosecond laser irradiation and acid etching  

SciTech Connect (OSTI)

Uniform nano-ripples were observed on the sidewall of micro-holes in silicon carbide fabricated by 800-nm femtosecond laser and chemical selective etching. The morphology of the ripple was analyzed using scanning electronic microscopy. The formation mechanism of the micro-holes was attributed to the chemical reaction of the laser affected zone with mixed solution of hydrofluoric acid and nitric acid. The formation of nano-ripples on the sidewall of the holes could be attributed to the standing wave generated in z direction due to the interference between the incident wave and the reflected wave.

Khuat, Vanthanh [Key Laboratory for Physical Electronics and Devices of the Ministry of Education and Collaborative Innovation Center of Suzhou Nano Science and Technology, School of Electronics and Information Engineering, Xi'an Jiaotong University, No. 28, Xianning West Road, Xi'an 710049 (China); Le Quy Don Technical University, No. 100, Hoang Quoc Viet Street, Hanoi 7EN-248 (Viet Nam); Chen, Tao; Gao, Bo; Si, Jinhai, E-mail: jinhaisi@mail.xjtu.edu.cn; Ma, Yuncan; Hou, Xun [Key Laboratory for Physical Electronics and Devices of the Ministry of Education and Collaborative Innovation Center of Suzhou Nano Science and Technology, School of Electronics and Information Engineering, Xi'an Jiaotong University, No. 28, Xianning West Road, Xi'an 710049 (China)

2014-06-16T23:59:59.000Z

315

Nucleic acid detection compositions  

DOE Patents [OSTI]

The present invention relates to means for the detection and characterization of nucleic acid sequences, as well as variations in nucleic acid sequences. The present invention also relates to methods for forming a nucleic acid cleavage structure on a target sequence and cleaving the nucleic acid cleavage structure in a site-specific manner. The structure-specific nuclease activity of a variety of enzymes is used to cleave the target-dependent cleavage structure, thereby indicating the presence of specific nucleic acid sequences or specific variations thereof.

Prudent, James R. (Madison, WI); Hall, Jeff G. (Madison, WI); Lyamichev, Victor I. (Madison, WI); Brow, Mary Ann (Madison, WI); Dahlberg, James L. (Madison, WI)

2008-08-05T23:59:59.000Z

316

Cleavage of nucleic acids  

DOE Patents [OSTI]

The present invention relates to means for the detection and characterization of nucleic acid sequences, as well as variations in nucleic acid sequences. The present invention also relates to methods for forming a nucleic acid cleavage structure on a target sequence and cleaving the nucleic acid cleavage structure in a site-specific manner. The structure-specific nuclease activity of a variety of enzymes is used to cleave the target-dependent cleavage structure, thereby indicating the presence of specific nucleic acid sequences or specific variations thereof.

Prudent, James R. (Madison, WI); Hall, Jeff G. (Madison, WI); Lyamichev, Victor L. (Madison, WI); Brow, Mary Ann D. (Madison, WI); Dahlberg, James E. (Madison, WI)

2007-12-11T23:59:59.000Z

317

Faraday rotation spectrometer with sub-second response time for detection of nitric oxide using a cw DFB quantum cascade laser at 5.33 ?m  

Science Journals Connector (OSTI)

A Faraday modulation spectrometer for sensitive and fast detection of nitric oxide at 5.33 ?m utilizing a room temperature continuous wave distributed feedback quantum cascade laser and a Peltier cooled MCT detec...

P. Kluczynski; S. Lundqvist; J. Westberg; O. Axner

2011-05-01T23:59:59.000Z

318

Decreased Mitochondrial Nitric Oxide Synthase Activity and Hydrogen Peroxide Relate Persistent Tumoral Proliferation to Embryonic Behavior  

Science Journals Connector (OSTI)

...involves the production of superoxide...O2 ) and hydrogen peroxide...pathways for NO production and utilization...MATERIALS AND METHODS Experimental...assessed by Lowry method. For transmission...Mitochondrial Production of Hydrogen Peroxide...

Soledad Galli; Mariana Inés Labato; Elisa Bal de Kier Joffé; María Cecilia Carreras; and Juan José Poderoso

2003-10-01T23:59:59.000Z

319

Photoenhanced anaerobic digestion of organic acids  

DOE Patents [OSTI]

A process is described for rapid conversion of organic acids and alcohols anaerobic digesters into hydrogen and carbon dioxide, the optimal precursor substrates for production of methane. The process includes addition of photosynthetic bacteria to the digester and exposure of the bacteria to radiant energy (e.g., solar energy). The process also increases the pH stability of the digester to prevent failure of the digester. Preferred substrates for photosynthetic bacteria are the organic acid and alcohol waste products of fermentative bacteria. In mixed culture with methanogenic bacteria or in defined co-culture with non-aceticlastic methanogenic bacteria, photosynthetic bacteria are capable of facilitating the conversion or organic acids and alcohols into methane with low levels of light energy input.

Weaver, Paul F. (Golden, CO)

1990-01-01T23:59:59.000Z

320

Acid dyes removal using low cost adsorbents  

Science Journals Connector (OSTI)

Dyestuff production units and dyeing units have always had pressing need techniques that allow economical pre-treatment for colour in the effluent. The effectiveness of adsorption for dye removal from wastewaters has made it an ideal alternative to other expensive treatment options. Removal of acid green

A.H. Aydin; Y. Bulut; O. Yavuz

2004-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "nitric acid production" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

STANDARD OPERATING PROCEDURE ACIDS CONTAINING PHOSPHOROUS  

E-Print Network [OSTI]

12.1 STANDARD OPERATING PROCEDURE for ACIDS CONTAINING PHOSPHOROUS Location(s): ___________________________________________________ Chemical(s): Hypophosphorous acid, methylphosphonic acid, phosphonic acid, phosphoric acid, phosphorous

Pawlowski, Wojtek

322

Design, set up, and testing of a matrix acidizing apparatus  

E-Print Network [OSTI]

Well stimulation techniques are applied on a regular basis to enhance productivity and maximize recovery in oil and gas wells. Among these techniques, matrix acidizing is probably the most widely performed job because of its relative low cost...

Nevito Gomez, Javier

2006-10-30T23:59:59.000Z

323

Evaluation of Acid Fracturing Using the Method of Distributed Volumetric Sources  

E-Print Network [OSTI]

acid volume versus cumulative production with optimum fracture half length............................................................................................40 4.1 For Well SA-2, IPR and VLP curves shows production rates... at the beginning of production....................................................................................47 4.2 For Well SA-2, IPR & VLP curves shows production rates at the end of production history; the absolute open flow (AOF) of IPR is much less...

Lee, Jaehun

2010-01-14T23:59:59.000Z

324

Separation Nanotechnology of Diethylenetriaminepentaacetic Acid...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Nanotechnology of Diethylenetriaminepentaacetic Acid Bonded Magnetic Nanoparticles for Spent Nuclear Fuel. Separation Nanotechnology of Diethylenetriaminepentaacetic Acid Bonded...

325

E-Print Network 3.0 - acidic oligotrophic fen Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

beyond the nutrient-productivity paradigm. For example, acid precipitation, heavy metal and toxic... of their trophic status. Lakes with low nutrients and low organic...

326

E-Print Network 3.0 - acidic wastes synthesis Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

food waste: Current status, problems and an alternative product Summary: alternative to biogas generation. The volatile fatty acids (VFA) produced from food waste in a...

327

E-Print Network 3.0 - adenosine triphosphoric acid Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

34559. 7... a series of breakdown products to, ultimately, uric acid. The degradation of ATP and adenosine is extremely... receptors for extracellular ... Source: Burnstock,...

328

E-Print Network 3.0 - antioxidant alpha-lipoic acid Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

sex, religion, age, disability, political beliefs, sexual orientation, o Summary: production of antioxidants. In plants, antioxidants a-tocopherol (vitamin E) and ascorbic acid...

329

Iron porphyrin polymer films: Materials for the modification of electrode surfaces and the detection of nitric oxide  

SciTech Connect (OSTI)

We are currently investigating a new method for the detection and quantification of nitric oxide (NO) based on a carbon electrode chemically modified with an iron porphyrin polymer film. Commercially available vinyl-substituted iron porphyrin monomers can be polymerized directly onto electrode surfaces through a published electrochemical polymerization process. We are also developing a synthesis for a new vinyl-substituted monomer, iron 5,10,15-triphenyl-20-vinyl porphyrin chloride, in hopes of improving polymer film stability. The electrochemistry of NO is also being investigated at electrodes chemically modified with an iron porphyrin polymer film. We are studying the catalytic oxidation of iron porphyrin bound NO to nitrate by molecular oxygen. The reaction with molecular oxygen is preceded by a one electron reduction of the iron porphyrin-NO complex. If currents proportional to nitric oxide concentration can be measured, a new NO electrochemical sensor will be designed.

McGuire, M.; Drew, S.M. [Carleton College, Northfield, MN (United States)

1996-10-01T23:59:59.000Z

330

The Effect of Acid Additives on Carbonate Rock Wettability and Spent Acid Recovery in Low Permeability Gas Carbonates  

E-Print Network [OSTI]

Spent acid retention in the near-wellbore region causes reduction of relative permeability to gas and eventually curtailed gas production. In low-permeability gas carbonate reservoirs, capillary forces are the key parameters that affect the trapping...

Saneifar, Mehrnoosh

2012-10-19T23:59:59.000Z

331

Equilibrium surface composition of sulfuric acid films in contact with various atmospheric gases (HNO{sub 3}, CO{sub 2}, CH{sub 2}O, Cl{sub 2}, NO, NO{sub 2})  

SciTech Connect (OSTI)

Differentially pumped X-ray photoelectron spectroscopy has been used to study the surface composition of sulfuric acid (H{sub 2}SO{sub 4}) and sulfuric acid/water mixtures in equilibrium with various atmospheric species. Nitric acid uptake in sulfuric acid solutions was observed below {approx}220 K. Compared to the theoretically predicted bulk composition, a significant enrichment of nitrogen was observed at the interface. The uptake of background water in sulfuric acid below 200 K was responsible for the reversible uptake of CO{sub 2}, moderated through the formation of carbonic acid (H{sub 2}CO{sub 3}). For CH{sub 2}O, Cl{sub 2}, NO, and NO{sub 2}, no observable surface species were observed over the temperature range studied ({approx}180--298 K).

Fairbrother, D.H.; Somorjai, G.A.

2000-05-18T23:59:59.000Z

332

Specialty Cellular Glass Products and Their Applications  

E-Print Network [OSTI]

and boroaluminosilicate fields which exhibit a high degree of resistance to corrosion by aggressive chemicals as well. One product, sold as PENNGUARDTM block by Pennwalt Corporation, is used as a liner for chimneys where acid corrosion had previously caused substantial...

Rostoker, D.

1979-01-01T23:59:59.000Z

333

Nucleic acids, compositions and uses thereof  

DOE Patents [OSTI]

The subject invention provides at least one nucleic acid sequence encoding an aldouronate-utilization regulon isolated from Paenibacillus sp. strain JDR-2, a bacterium which efficiently utilizes xylan and metabolizes aldouronates (methylglucuronoxylosaccharides). The subject invention also provides a means for providing a coordinately regulated process in which xylan depolymerization and product assimilation are coupled in Paenibacillus sp. strain JDR-2 to provide a favorable system for the conversion of lignocellulosic biomass to biobased products. Additionally, the nucleic acid sequences encoding the aldouronate-utilization regulon can be used to transform other bacteria to form organisms capable of producing a desired product (e.g., ethanol, 1-butanol, acetoin, 2,3-butanediol, 1,3-propanediol, succinate, lactate, acetate, malate or alanine) from lignocellulosic biomass.

Preston, III, James F. (Micanopy, FL); Chow, Virginia (Gainesville, FL); Nong, Guang (Gainesville, FL); Rice, John D. (Gainesville, FL); St. John, Franz J. (Baltimore, MD)

2012-02-21T23:59:59.000Z

334

Nucleic acid compositions and the encoding proteins  

SciTech Connect (OSTI)

The subject invention provides at least one nucleic acid sequence encoding an aldouronate-utilization regulon isolated from Paenibacillus sp. strain JDR-2, a bacterium which efficiently utilizes xylan and metabolizes aldouronates (methylglucuronoxylosaccharides). The subject invention also provides a means for providing a coordinately regulated process in which xylan depolymerization and product assimilation are coupled in Paenibacillus sp. strain JDR-2 to provide a favorable system for the conversion of lignocellulosic biomass to biobased products. Additionally, the nucleic acid sequences encoding the aldouronate-utilization regulon can be used to transform other bacteria to form organisms capable of producing a desired product (e.g., ethanol, 1-butanol, acetoin, 2,3-butanediol, 1,3-propanediol, succinate, lactate, acetate, malate or alanine) from lignocellulosic biomass.

Preston, III, James F.; Chow, Virginia; Nong, Guang; Rice, John D.; St. John, Franz J.

2014-09-02T23:59:59.000Z

335

Reversible Acid Gas Capture  

SciTech Connect (OSTI)

Pacific Northwest National Laboratory scientist David Heldebrant demonstrates how a new process called reversible acid gas capture works to pull carbon dioxide out of power plant emissions.

Dave Heldebrant

2009-08-01T23:59:59.000Z

336

Reversible Acid Gas Capture  

ScienceCinema (OSTI)

Pacific Northwest National Laboratory scientist David Heldebrant demonstrates how a new process called reversible acid gas capture works to pull carbon dioxide out of power plant emissions.

Dave Heldebrant

2012-12-31T23:59:59.000Z

337

Roles of Glutamates and Metal ions in a Rationally Designed Nitric Oxide Reductase Based on Myoglobin  

SciTech Connect (OSTI)

A structural and functional model of bacterial nitric oxide reductase (NOR) has been designed by introducing two glutamates (Glu) and three histidines (His) in sperm whale myoglobin. X-ray structural data indicate that the three His and one Glu (V68E) residues bind iron, mimicking the putative FeB site in NOR, while the second Glu (I107E) interacts with a water molecule and forms a hydrogen bonding network in the designed protein. Unlike the first Glu (V68E), which lowered the heme reduction potential by {approx}110 mV, the second Glu has little effect on the heme potential, suggesting that the negatively charged Glu has a different role in redox tuning. More importantly, introducing the second Glu resulted in a {approx}100% increase in NOR activity, suggesting the importance of a hydrogen bonding network in facilitating proton delivery during NOR reactivity. In addition, EPR and X-ray structural studies indicate that the designed protein binds iron, copper, or zinc in the FeB site, each with different effects on the structures and NOR activities, suggesting that both redox activity and an intermediate five-coordinate heme-NO species are important for high NOR activity. The designed protein offers an excellent model for NOR and demonstrates the power of using designed proteins as a simpler and more well-defined system to address important chemical and biological issues.

Y Lin; N Yeung; Y Gao; K Miner; S Tian; H Robinson; Y Lu

2011-12-31T23:59:59.000Z

338

Phosphate bonded structural products from high volume wastes  

DOE Patents [OSTI]

A method to produce structural products from benign waste is provided comprising mixing pretreated oxide with phosphoric acid to produce an acid solution, mixing the acid solution with waste particles to produce a slurry, and allowing the slurry to cure. The invention also provides for a structural material comprising waste particles enveloped by an inorganic binder. 1 fig.

Singh, D.; Wagh, A.S.

1998-12-08T23:59:59.000Z

339

E-Print Network 3.0 - atmospheric oxidation by-products Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

only a few electrode materials are known... exhibits some selectivity towards the reduction of nitric oxide in a net oxidising atmosphere. Several... and in the nitric oxide...

340

Relative reactivities of solid benzoic acids  

E-Print Network [OSTI]

was always the acid salt, (RBZA) HK. For the reaction, RBZAH + Z R'BZAK, where R g R', the products were those predicted from Hammett o-constants for R and R'. Observations on the mode of reaction and free energy changes are given. The desirability... reaction series chosen was that. one most directly related to the Hammett substituent constants; namely, the reactions of various m- or p- monosubstituted benzoic acids with m- or p-monosubstituted potas- sium benzoate salts. CHAPTER Il RES ULTS...

Warwas, Edwin James

2012-06-07T23:59:59.000Z

Note: This page contains sample records for the topic "nitric acid production" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Naphthenic acids as antiwear additives for jet fuels  

SciTech Connect (OSTI)

One of the ways in which the antiwear properties of jet fuels can be improved is the use of lubricity agents, otherwise known as antiwear additives. Among the various compounds that have antiwear properties in these fuels, naphthenic, acids merit special attention. These are alicyclic carboxylic acids, in most cases monobasic, with five- and six-membered carbon rings; they have the general formula R(CH{sub 2}){sub n}COOH, where R is a naphthene radical. Natural naphthenic acids consist mainly of acids of the cyclopentane series, beginning with the simplest, in particular cyclopentylacetic acid. The lower naphthenic acids are monocyclic; the higher acids, beginning with C{sub 13}, are bicyclic and polycyclic. Naphthenic acids of the cyclohexane series are encountered less frequently; they may be found, for example, in Baku, California, and Sakhalin crudes. The most widely used method for obtaining naphthenic acids is the treatment of light distillates, lube distillates, and diesel fuels. The standard GOST 13302-77 establishes several grades of naphthenic acids, depending on the raw material and the production technology. This work was aimed at the utilization of wastes containing naphthenic acids, with subsequent use as jet fuel additives.

Deineko, P.S.; Vasil`eva, E.N.; Popova, O.V.; Bashkatova, S.T.

1995-05-01T23:59:59.000Z

342

Production of Hydrogen and Syngas via Steam Gasification of Glycerol in a Fixed-Bed Reactor  

Science Journals Connector (OSTI)

Glycerol is one of the by-products of transesterification of fatty acids to produce bio-diesel. Increased production of bio-diesel would lead to increased production of glycerol in Canadian market. Therefore, the...

T. Valliyappan; D. Ferdous; N. N. Bakhshi; A. K. Dalai

2008-07-01T23:59:59.000Z

343

Firmness and cell wall characteristics of pasteurized jalapeno pepper rings affected by acetic acid, calcium chloride and preheating  

E-Print Network [OSTI]

pasteurization and storage, especially when high acid brines are used. Development of treatments to retard softening may result in a higher quality product. This study was undertaken to investigate the effects of calcium chloride (CaCI2), acetic acid...

Burma, Prashanthi V

2012-06-07T23:59:59.000Z

344

RMOTC - Production  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Production Production RMOTC Pumpjack in action During the process of the sale of NPR-3, RMOTC will focus on maximizing the value of the NPR-3 site and will continue with its Production Optimization Projects. NPR-3 includes 9,481 acres with more than 400 oil-producing wells. Current oil production is at approximately 240 barrels of oil per day. In July 2013, RMOTC began working on a number of Production Optimization Projects within the NPR-3 field, with the goal to optimize and improve flow and efficiency. Production Optimization Projects include repairing and replacing existing infrastructure with new infrastructure in order to optimize current wells and bring additional wells online. These Production Optimization Projects will continue throughout 2013 and are focused on improving current production and creating revenue for the America tax payer.

345

PRODUCTS & MATERIALS  

Science Journals Connector (OSTI)

...1995-96 Spectrum Chemical and Safety Prod-ucts Catalog features products for molecular and life science laboratories and cleanroom environments. Spectrum Chemical Manu-facturing. Circle 150. SCIENCE * VOL. 268 * 23 JUNE 1995

1995-06-23T23:59:59.000Z

346

PRELIMINARY REPORT ON EVALUATION OF POTENTIAL ELUANTS FOR NON-ACID ELUTION OF CESIUM FROM RESORCINOL-FORMALDEHYDE RESIN  

SciTech Connect (OSTI)

Small-column ion exchange (SCIX) units installed in high-level waste tanks to remove Cs-137 from highly alkaline salt solutions are among the waste treatment plans in the DOE-complex. Spherical Resorcinol-Formaldehyde (sRF) is the ion exchange resin selected for use in the Hanford Waste Treatment and Immobilization Plant (WTP). It is also the primary ion exchange material under consideration for SCIX at the Hanford site. The elution step of the multi-step ion exchange process is typically done with 0.5 M nitric acid. An acid eluant is a potential hazard in the event of a spill, leak, etc. because the high-level waste tanks are made of carbon steel. Corrosion and associated structural damage may ensue. Studies are ongoing to explore non-acid elution as an alternative. Batch contact sorption equilibrium screening tests have been conducted with 36 potential non-acid eluants. The sorption tests involve equilibrating each cesium-containing eluant solution with the sRF resin for 48 hours at 25 C in a shaker oven. In the sorption tests, an eluant is deemed to have a high cesium elution potential if it minimizes cesium sorption onto the sRF resin. The top candidates (based on lowest cesium sorption distribution coefficients) include ammonium carbonate, ammonium carbonate/ammonium hydroxide, ammonium bicarbonate, rubidium carbonate, ammonium acetate, ammonium acetate/ammonium hydroxide, ammonium bicarbonate/ammonium hydroxide, calcium chloride, and magnesium chloride. The next phase of testing for this work will focus on the following down selected eluants: Ammonium carbonate, ammonium acetate, calcium acetate, magnesium acetate, nitric acid, and ammonium hydroxide. The next testing phase is a confirmation of the elution ability of the selected eluants. It will mimic a typical sRF cesium ion exchange process i.e., sorption or loading, caustic wash, water rinse, and elution via batch contact sorption and quasi column caustic wash/water rinse/elution. Due to corrosion concerns, calcium acetate and magnesium acetate will be tested instead of calcium chloride and magnesium chloride respectively. Nitric acid is for benchmarking since it is the baseline sRF eluant. The information at hand indicates ammonium hydroxide, while a weak base, may hold promise as an effective eluant. Hence, its inclusion among the eluants to be studied despite the fact that it was not tested as a stand-alone eluant earlier.

Adu-Wusu, K.; Pennebaker, F.

2010-09-01T23:59:59.000Z

347

Crystal Structures of the Nitrite and Nitric Oxide Complexes of Horse Heart Myoglobin  

SciTech Connect (OSTI)

Nitrite is an important species in the global nitrogen cycle, and the nitrite reductase enzymes convert nitrite to nitric oxide (NO). Recently, it has been shown that hemoglobin and myoglobin catalyze the reduction of nitrite to NO under hypoxic conditions. We have determined the 1.20 Angstroms resolution crystal structure of the nitrite adduct of ferric horse heart myoglobin (hh Mb). The ligand is bound to iron in the nitrito form, and the complex is formulated as Mb{sup III}(ONO{sup -}). The Fe-ONO bond length is 1.94 Angstroms, and the O-N-O angle is 113 degrees. In addition, the nitrite ligand is stabilized by hydrogen bonding with the distal His64 residue. We have also determined the 1.30 Angstroms resolution crystal structures of hh Mb{sup II}NO. When hh Mb{sup II}NO is prepared from the reaction of metMb{sup III} with nitrite/dithionite, the FeNO angle is 144 degrees with a Fe-NO bond length of 1.87 Angstroms. However, when prepared from the reaction of NO with reduced Mb{sup II}, the FeNO angle is 120 degrees with a Fe-NO bond length of 2.13 Angstroms. This difference in FeNO conformations as a function of preparative method is reproducible, and suggests a role of the distal pocket in hh Mb{sup II}NO in stabilizing local FeNO conformational minima.

Copeland,D.; Soares, A.; West, A.; Richter-Addo, G.

2006-01-01T23:59:59.000Z

348

Membrane Stresses Induced by Overproduction of Free Fatty Acids in Escherichia coli  

Science Journals Connector (OSTI)

...Application and engineering of fatty acid...for advanced fuels and chemicals...engineered for fuel production...G. 2010. Biodiesel and renewable...analysis and engineering of fatty acid...implications for biodiesel production...derivatives. Energy Fuels 21 :30-41...

Rebecca M. Lennen; Max A. Kruziki; Kritika Kumar; Robert A. Zinkel; Kristin E. Burnum; Mary S. Lipton; Spencer W. Hoover; Don R. Ranatunga; Tyler M. Wittkopp; Wesley D. Marner II; Brian F. Pfleger

2011-09-23T23:59:59.000Z

349

Chlorophyll and acid rain  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Chlorophyll and acid rain Chlorophyll and acid rain Name: beachbum Status: N/A Age: N/A Location: N/A Country: N/A Date: Around 1993 Question: A while ago I read an article that stated that after a plant received acid rain, there seemed to be less of chlorophyll a and b in the plant. I was wondering where does the chlorophyll go and what is the actual process (cell structure affected?). Replies: I think that less chlorophyll being present would be more likely a result of less being produced. Plant cell constantly turn over cell material, it will also constantly produce more. So if one compares a plant not exposed to acid rain (presumably producing a normal amount of chlorophyll and the exposed plant then one sees that the exposed plant has less chlorophyll than the unexposed plant. I do not think I can answer the rest of your question.

350

Nucleic Acid Softwars  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Nucleic Acid Software Nucleic Acid Software FR3D, a software for finding local and composite recurrent structural motifs in RNA 3D structures. Sarver, M., Zirbel, C.L., Stombaugh, J., Mokdad, A. and Leontis, N.B. (2008) FR3D: finding local and composite recurrent structural motifs in RNA 3D structures. J Math Biol, 56, 215-252. RNAView, a program for quickly generating a display of RNA/DNA secondary structures with tertiary interactions. Yang, H., Jossinet, F., Leontis, N., Chen, L., Westbrook, J., Berman, H.M. and Westhof, E. (2003) Tools for the automatic identification and classification of RNA base pairs. Nucleic Acids Res, 31, 3450-3460. RNAMLview, a program to display and/or edit RNAView 2-dimensional diagrams. 3DNA, a software package for the analysis, rebuilding and visualization of three-dimensional nucleic acid structures.

351

Reactivity of Acid Generators  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Reactivity of Acid Generators for Chemically Amplified Resists with Reactivity of Acid Generators for Chemically Amplified Resists with Low-Energy Electrons Atsuro Nakano, Takahiro Kozawa, Seiichi Tagawa, Tomasz Szreder, James F. Wishart, Toshiyuki Kai and Tsutomu Shimokawa Jpn. J. Appl. Phys., 45, L197-L200 (2006). [Find paper at the Japanese Journal of Applied Physics] Abstract: In chemically amplified resists for ionizing radiations such as electron beams and extreme ultraviolet (EUV), low-energy electrons play an important role in the pattern formation processes. The reactivity of acid generators with low-energy electrons was evaluated using solvated electrons in tetrahydrofuran, which were generated by a pulsed electron beam. The rate constants of acid generators with the solvated electrons ranged from 0.6 to 1.9 x 1011 M-1s-1

352

(Acid rain workshop)  

SciTech Connect (OSTI)

The traveler presented a paper entitled Susceptibility of Asian Ecosystems to Soil-Mediated Acid Rain Damage'' at the Second Workshop on Acid Rain in Asia. The workshop was organized by the Asian Institute of Technology (Bangkok, Thailand), Argonne National Laboratory (Argonne, Illinois), and Resource Management Associates (Madison, Wisconsin) and was sponsored by the US Department of Energy, the United Nations Environment Program, the United Nations Economic and Social Commission for Asia and the Pacific, and the World Bank. Papers presented on the first day discussed how the experience gained with acid rain in North America and Europe might be applied to the Asian situation. Papers describing energy use projections, sulfur emissions, and effects of acid rain in several Asian countries were presented on the second day. The remaining time was allotted to discussion, planning, and writing plans for a future research program.

Turner, R.S.

1990-12-05T23:59:59.000Z

353

Fatty Acid Carcass Mapping  

E-Print Network [OSTI]

FATTY ACID CARCASS MAPPING A Thesis by STACEY NICOLE TURK Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE May 2008... Major Subject: Animal Science FATTY ACID CARCASS MAPPING A Thesis by STACEY NICOLE TURK Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE...

Turk, Stacey N.

2010-01-14T23:59:59.000Z

354

The utilization of tricarboxylic acid cycle acids and the uptake of succinic acid by Neurospora crassa  

E-Print Network [OSTI]

THE UTILIZATION OF TRICARBOXYLIC ACID CYCLE ACIDS AND THE UPTAKE OF SUCCINIC ACID BY NEUROSPORA CRASSA A Thesis by PATTI LYNN GILLILAND Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirement... for the degree of MASTER OF SCIENCE August 1978 Ma) or Subject: Microbiology THE UTILIZATION OF TRICARBOXYLIC ACID CYCLE ACIDS AND THE UPTAKE OF SUCCINIC ACID BY NEUROSPORA CRASSA A Thesis by PATTI LYNN GILLILAND Approved as to style and content by...

Gilliland, Patti Lynn

2012-06-07T23:59:59.000Z

355

Focus Sheet | Hydrofluoric Acid Health hazards of hydrofluoric acid  

E-Print Network [OSTI]

Focus Sheet | Hydrofluoric Acid Health hazards of hydrofluoric acid Hydrofluoric acid (HF characterized by weight loss, brittle bones, anemia, and general ill health. Safe use If possible, avoid working to exposures. #12;Focus Sheet | Hydrofluoric Acid Environmental Health and Safety Environmental Programs Office

Wilcock, William

356

A convenient and highly productive aminohydroxylation protocol employing an osmium-diamine catalyst .  

E-Print Network [OSTI]

??In situ generated osmium-diamine chelates from 2,3-diaminopropionic acid or diaminosuccinic acid represent efficient catalysts for the highly productive aminohydroxylation of alkenes. The reaction can be… (more)

Muñiz, Kilian

2006-01-01T23:59:59.000Z

357

Oxidation and Surface Segregation Behavior of a Pt–Pd–Rh Alloy Catalyst  

Science Journals Connector (OSTI)

Platinum gauze catalysts are used extensively in the production of nitric acid from ammonia, where they are subject to harsh operating conditions combining elevated temperatures and oxidizing environments. These cause significant loss of metal species as ...

Paul A. J. Bagot; Karen Kruska; Daniel Haley; Xavier Carrier; Eric Marceau; Michael. P. Moody; George D. W. Smith

2014-10-16T23:59:59.000Z

358

Separation of actinides from Low Level Liquid Wastes (LLLW) by extraction chromatography using novel DMDOHEMA and TODGA impregnated resins  

Science Journals Connector (OSTI)

The uptake of several actinides [U(VI), Th(IV), Am(III), Cm(III)] and fission products was investigated from nitric acid solutions by two novel extraction chromatographic sorbents containing 2-(2-hexyloxy-ethy...

K. Van Hecke; G. Modolo

2004-08-01T23:59:59.000Z

359

Abscisic Acid Activation of Plasma Membrane Ca2+ Channels in Guard Cells Requires Cytosolic NAD(P)H and Is Differentially Disrupted Upstream and Downstream of Reactive Oxygen Species Production in abi1-1 and abi2-1 Protein Phosphatase 2C Mutants  

Science Journals Connector (OSTI)

...Orlandi, 1995). DPI, an inhibitor of neutrophil NADPH oxidases...oligogalacturonic acid and chitosan reduce stomatal aperture and...1986). The effect of the inhibitor diphenylene iodonium on the...Oligogalacturonic acid and chitosan reduce stomatal aperture by...

Yoshiyuki Murata; Zhen-Ming Pei; Izumi C. Mori; Julian Schroeder

360

Mixture Preparation and Nitric Oxide Formation in a GDI Engine studied by Combined Laser Diagnostics and Numerical Modeling  

SciTech Connect (OSTI)

Through the combination of advanced imaging laser diagnostics with multi-dimensional computer models, a new understanding of the performance of direct-injection gasoline engines is pursuit. The work focuses on the fuel injection process, the breakup of the liquid into a fine spray and the mixing of the fuel with the in-cylinder gases. Non-intrusive laser diagnostics will be used to measure the spatial distribution of droplets and vaporized fuel with very high temporal resolution. These data along with temperature measurements will be used to validate a new spray breakup model for gasoline direct-injection. Experimental data on near wall fuel distributions will be used for comparison with a model that predicts the spray-wall interaction and the dynamics of the liquid film on the surface. Quantitative measurements of local nitric oxide concentrations inside the combustion chamber will provide a critical test for a numerical simulation of the nitric oxide formation process. This model is based on a modified flamelet approach and will be used to study the effects of exhaust gas recirculation.

Volker Sick; Dennis N. Assanis

2002-11-27T23:59:59.000Z

Note: This page contains sample records for the topic "nitric acid production" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

PRODUCTS & MATERIALS  

Science Journals Connector (OSTI)

...Phar-macia Biotech. Circle 141. Cell Culture Production The CellCube offers the fastest, most com-pact system available for high-volume...culture production, according to the manu-facturer. The CellCube not only saves up to four times the space of roller bottles...

1995-08-04T23:59:59.000Z

362

Optical high acidity sensor  

DOE Patents [OSTI]

An apparatus and method for determining acid concentrations in solutions having acid concentrations of from about 0.1 Molar to about 16 Molar is disclosed. The apparatus includes a chamber for interrogation of the sample solution, a fiber optic light source for passing light transversely through the chamber, a fiber optic collector for receiving the collimated light after transmission through the chamber, a coating of an acid resistant polymeric composition upon at least one fiber end or lens, the polymeric composition in contact with the sample solution within the chamber and having a detectable response to acid concentrations within the range of from about 0.1 Molar to about 16 Molar, a measurer for the response of the polymeric composition in contact with the sample solution, and, a comparer of the measured response to predetermined standards whereby the acid molarity of the sample solution within the chamber can be determined. Preferably, a first lens is attached to the end of the fiber optic light source, the first lens adapted to collimate light from the fiber optic light source, and a second lens is attached to the end of the fiber optic collector for focusing the collimated light after transmission through the chamber.

Jorgensen, Betty S. (Jemez Springs, NM); Nekimken, Howard L. (Los Alamos, NM); Carey, W. Patrick (Lynnwood, WA); O'Rourke, Patrick E. (Martinez, GA)

1997-01-01T23:59:59.000Z

363

Nucleic Acid Tools  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Nucleic Acid Tools Nucleic Acid Tools RNA 3D Motif Atlas, a representative collection of RNA 3D internal and hairpin loop motifs. Petrov, A.I., Zirbel, C.L., Leontis, N.B. (2013) Automated classification of RNA 3D motifs and the RNA 3D motif atlas. RNA. Non-redundant List of RNA-containing 3D structures. Leontis, N.B., & Zirbel, C.L. (2012) In Leontis, N. B., Westhof. E. (ed.), RNA 3D structure analysis and prediction. Springer Berlin Heidelberg Vol. 27, pp. 281-298. RNA Base Triple Atlas, a collection of motifs consisting of two RNA basepairs. Abu Almakarem, A.S., Petrov, A.I., Stombaugh, J., Zirbel, C.L. and Leontis, N.B. (2012) Comprehensive survey and geometric classification of base triples in RNA structures. Nucleic Acids Res, 40, 1407-1423. R3D Align, an application for detailed nucleotide to nucleotide

364

A Direct, Biomass-Based Synthesis of Benzoic Acid: Formic Acid-Mediated Deoxygenation of the Glucose-Derived Materials Quinic Acid and Shikimic Acid  

SciTech Connect (OSTI)

An alternative biomass-based route to benzoic acid from the renewable starting materials quinic acid and shikimic acid is described. Benzoic acid is obtained selectively using a highly efficient, one-step formic acid-mediated deoxygenation method.

Arceo, Elena; Ellman, Jonathan; Bergman, Robert

2010-05-03T23:59:59.000Z

365

Identification of the molecular genetic basis of the low palmitic acid seed oil trait in soybean mutant line RG3 and association analysis of molecular markers with elevated seed stearic acid and reduced seed palmitic acid  

Science Journals Connector (OSTI)

The fatty acid composition of vegetable oil is becoming increasingly critical for its ultimate functionality and utilization in foods and industrial products. Partial chemical hydrogenation of soybean [Glycine ma...

Jason D. Gillman; Ashley Tetlow; Katherine Hagely; Jeffery G. Boersma…

2014-08-01T23:59:59.000Z

366

Synthesis of acid addition salt of delta-aminolevulinic acid from 5-bromo levulinic acid esters  

DOE Patents [OSTI]

A process of preparing an acid addition salt of delta-aminolevulinc acid comprising: a) dissolving a lower alkyl 5-bromolevulinate and hexamethylenetetramine in a solvent selected from the group consisting of water, ethyl acetate, chloroform, acetone, ethanol, tetrahydrofuran and acetonitrile, to form a quaternary ammonium salt of the lower alkyl 5-bromolevulinate; and b) hydrolyzing the quaternary ammonium salt with an inorganic acid to form an acid addition salt of delta-aminolevulinic acid.

Moens, Luc (Lakewood, CO)

2003-06-24T23:59:59.000Z

367

Detailed modeling and laser-induced fluorescence imaging of nitric oxide in a NH3-seeded non-premixed methane/air flame  

E-Print Network [OSTI]

non-premixed methane/air flame John B. Bell, Marcus S. Day, Joseph F. Grcar Computing Sciences-induced fluorescence imaging of nitric oxide in a NH3-seeded non-premixed methane/air flame Abstract In this paper we study the formation of NO in laminar, nitrogen diluted methane diffusion flames that are seeded

Bell, John B.

368

Selective catalytic reduction (SCR) of nitric oxide (NO) with ammonia over vanadia-based and pillared interlayer clay-based catalysts  

E-Print Network [OSTI]

The selective catalytic reduction (SCR) of nitric oxide (NO) with ammonia over vanadia-based (V2O5-WO3/TiO2) and pillared interlayer clay-based (V2O5/Ti-PILC) monolithic honeycomb catalysts using a laboratory laminar-flow reactor was investigated...

Oh, Hyuk Jin

2004-09-30T23:59:59.000Z

369

New Products  

Science Journals Connector (OSTI)

...security of unmatched sample traceability. Manufactured from high-quality polypropylene in a fully automated class-7 cleanroom environment ensures the laser-etched alphanumeric tubes exhibit absolute product consistency, near-zero contaminants...

2013-01-11T23:59:59.000Z

370

New Products  

Science Journals Connector (OSTI)

...bind cells and biomolecules through passive hydrophobic interactions. Molded from ultrapure polystyrene in a class 100,000 cleanroom production environment, the untreated culture plates are supplied with lids in individual sterile packs. The plates include...

2013-06-28T23:59:59.000Z

371

Production Materials  

Science Journals Connector (OSTI)

It is obvious that we must bring a number of things into our controlled environment besides clean conditioned air, equipment, and ultrapure water. If we are to do any production work, or research involving the pr...

M. Kozicki; S. Hoenig; P. Robinson

1991-01-01T23:59:59.000Z

372

New Products  

Science Journals Connector (OSTI)

...Finally, as a personal pipetting system, Liquidator 96 fits any benchtop or laminar-flow cabinet making it suitable for cleanroom conditions. Mettler Toledo For info: 800-472-4646 www.mt.com/liquidator Electronically submit your new product...

2014-01-03T23:59:59.000Z

373

Forest Products  

Broader source: Energy.gov [DOE]

Purchased energy remains the third largest manufacturing cost for the forest products industry–despite its extensive use of highly efficient co-generation technology. The industry has worked with...

374

NEW PRODUCTS:  

Science Journals Connector (OSTI)

......also be used with other heating elements and probes...content of diesel and heating oils. A highly specific titration...requirements for fuel oil products are consistently...de- scriptions, and prices are included for columns......

New Products

1979-12-01T23:59:59.000Z

375

New Products  

Science Journals Connector (OSTI)

...the area scanned. When the earth's thermal gradient appears, the vibrating mirror...Write for a Product Data Sheet giving specifications, typical drying perform-ance, and...pebble-bed heaters and electrical insulation at elevated temperatures. (Minneapolis-Honeywell...

Joshua Stern

1961-11-10T23:59:59.000Z

376

Hydrogen Production  

Fuel Cell Technologies Publication and Product Library (EERE)

This 2-page fact sheet provides a brief introduction to hydrogen production technologies. Intended for a non-technical audience, it explains how different resources and processes can be used to produ

377

Insights into the Interplay of Lewis and Brønsted Acid Catalysts in Glucose and Fructose Conversion to 5-(Hydroxymethyl)furfural and Levulinic Acid in Aqueous Media  

Science Journals Connector (OSTI)

† Center for Catalytic Science and Technology and Catalysis Center for Energy Innovation, Department of Chemical & Biomolecular Engineering, University of Delaware, Newark, Delaware 19716, United States ... 5-(Hydroxymethyl)furfural (HMF) and levulinic acid production from glucose in a cascade of reactions using a Lewis acid (CrCl3) catalyst together with a Brønsted acid (HCl) catalyst in aqueous media is investigated. ... Fructose is a key intermediate in the conversion of cellulosic biomass to biofuels and renewable platform chemicals. ...

Vinit Choudhary; Samir H. Mushrif; Christopher Ho; Andrzej Anderko; Vladimiros Nikolakis; Nebojsa S. Marinkovic; Anatoly I. Frenkel; Stanley I. Sandler; Dionisios G. Vlachos

2013-02-22T23:59:59.000Z

378

Deposition of Nitric Acid and Reactive Nitrogen at Harvard Forest The hourly gas-phase HNO3 concentration was measured at the Harvard Forest  

E-Print Network [OSTI]

Reactive nitrogen trace gas species play an important role in tropospheric photochemistry by stimulating gas-phase HNO3 concentration was measured at the Harvard Forest Environmental Measurement Site during radicals may be regenerated. Thus conversion of NOx radicals to HNO3 and subsequent deposition

379

Interphase transfer kinetics of thorium between nitric acid and tributyl phosphate solutions using the single drop and the Lewis cell techniques  

SciTech Connect (OSTI)

The kinetic rate constants for the interphase transfer of thorium between an aqueous phase and an organic phase of tributyl phosphate-n-paraffin hydrocarbon have been measured using the single drop and the Lewis cell techniques. Results from individual tests performed with the two techniques agree within experimental error. As with uranium, the data are consistent with a model in which the rate-controlling step is the rate of reaction of the components at the phase interface. An organic-soluble complex, represented by Th(NO/sub 3/)/sub 4/.2TBP, forms in the organic phase. The composition of this complex is confirmed by equilibrium, as well as by kinetic, data. The kinetic data include results from tests showing the effects of TBP concentration and nitrate concentration on the values of the forward and the reverse kinetic constants. Other tests show the effect of temperature on the kinetic constant in both the forward and the reverse transfer directions, and the activation energies and enthalpy for the extraction reactions were estimated from these data. Unlike uranium, thorium extraction was shown to have a Marangoni effect under certain conditions. 10 figures, 1 table.

Horner, D.E.; Mailen, J.C.; Coggins, J.R. Jr.; Thiel, S.W.; Scott, T.C.; Pih, N.; Yates, R.G.

1980-01-01T23:59:59.000Z

380

Corrosion of 304 Stainless Steel Exposed To Nitric Acid -Chloride Environments D.G. Kolman, D.K. Ford, D.P. Butt, and T.O. Nelson  

E-Print Network [OSTI]

(HNO3) process streams plays an important role in high-level radioactive waste reduction and long-term storage of radioactive material. Container materials for HNO3 process streams, such as pipes and holding

Note: This page contains sample records for the topic "nitric acid production" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Precipitation of cesium jointly with uranium from nitric acid liquid radioactive wastes to obtain solid matrices for long-term storage  

Science Journals Connector (OSTI)

The possibility of converting liquid radioactive wastes containing Cs into chemically and thermodynamically stable...4U5O17...can be prepared by different procedures. The resulting compounds are characterized by ...

Yu. I. Korneiko; A. A. Murzin; O. V. Shmidt

2009-08-01T23:59:59.000Z

382

Aggregation and Protonation Phenomena in Third Phase Formation: An NMR Study of the Quaternary Malonamide/Dodecane/Nitric Acid/Water System  

Science Journals Connector (OSTI)

(2)?Nigond, L.; Condamines, N.; Cordier, P. Y.; Livet, J.; Madic, C.; Cuillerdier, C.; Musikas, C.; Hudson, M. J. Sep. ... (3)?Nigond, L.; Musikas, C.; Cuillerdier, C. Solvent Extr. ... Nigond, L.; Musikas, C.; Cuillerdier, C. ...

Lydie Lefrançois; Jean-Jacques Delpuech; Marc Hébrant; Jacques Chrisment; Christian Tondre

2001-03-10T23:59:59.000Z

383

Co-Solvent Enhanced Production of Platform Fuel Precursors From Lignocellulosic Biomass  

E-Print Network [OSTI]

Acid and Use as a Platform Chemical for Derived Products."to the Platform Chemical 5-Hydroxymethylfurfural Usingare the primary platform chemicals from which renewable

Cai, Charles Miao-Zi

2014-01-01T23:59:59.000Z

384

Acidizing of Sandstone Reservoirs Using HF and Organic Acids  

E-Print Network [OSTI]

Mud acid, which is composed of HCl and HF, is commonly used to remove the formation damage in sandstone reservoirs. However, many problems are associated with HCl, especially at high temperatures. Formic-HF acids have served as an alternative...

Yang, Fei

2012-10-19T23:59:59.000Z

385

Acidity deterioration and coke deposition in a HZSM5 zeolite in the MTG process  

Science Journals Connector (OSTI)

Summary The total acidity deterioration and the acidity strength distribution of a catalyst prepared from a H-ZSM-5 zeolite has been studied in the MTG process carried out in catalytic chamber and in an isothermal fixed bed integral reactor. The acidity deterioration has been related to coke deposition. The evolution of the acidic structure and of coke deposition has been analysed in situ by diffuse reflectance FTIR in a catalytic chamber. The effect of operating conditions (time on stream and temperature) on acidity deterioration, coke deposition and coke nature has been studied from experiments in a fixed integral reactor. The technique for studying acidity yields a reproducible measurement of total acidity and acidity strength distribution of the catalyst deactivated by coke. The NH3 adsorption-desorption is measured by combination of scanning differential calorimetry and the FTIR analysis of the products desorbed.

A.T. Aguayo; P.L. Benito; A.G. Gayubo; M. Olazar; J. Bilbao

1994-01-01T23:59:59.000Z

386

1,2-Diazole and 2,2,2-Trifluoroethanol and Their Regulatory Effects on Ethanol and Lactic Acid Formation in the Living Culture of Rhizopus oryzae  

Science Journals Connector (OSTI)

In heterofermentation of Rhizopus oryzae, ethanol is the major byproduct which reduces the...l...-lactic acid. To improve lactic acid production, regulating the alcohol fermentative pathway to limit ethanol produ...

Sitanan Thitiprasert; Sarintip Sooksai…

2014-02-01T23:59:59.000Z

387

Engineering a Cyanobacterial Cell Factory for Production of Lactic Acid  

Science Journals Connector (OSTI)

...the triglyceride fraction from, e.g., green algae into biodiesel, which relaxes the competition between energy and...triglyceride fraction must be extracted and converted into biodiesel. For these reasons, a third-generation type of...

S. Andreas Angermayr; Michal Paszota; Klaas J. Hellingwerf

2012-08-03T23:59:59.000Z

388

Engineering a Cyanobacterial Cell Factory for Production of Lactic Acid  

Science Journals Connector (OSTI)

...source of biofuel and bioplastic...sustainable alternatives to provide...produce solar biofuel have been...between the energy sector and...green algae into biodiesel...2009. Energy biotechnology...2009. Alternative routes to biofuels: light-driven...

S. Andreas Angermayr; Michal Paszota; Klaas J. Hellingwerf

2012-08-03T23:59:59.000Z

389

Engineering a Cyanobacterial Cell Factory for Production of Lactic Acid  

Science Journals Connector (OSTI)

...efficient and sustainable harvesting of solar biofuel. As a model system for this...a cyanobacterium as the catalyst and solar energy as the free energy source, higher...for standard assembly of biobricks. Massachusetts Institute of Technology, Cambridge...

S. Andreas Angermayr; Michal Paszota; Klaas J. Hellingwerf

2012-08-03T23:59:59.000Z

390

Engineering a Cyanobacterial Cell Factory for Production of Lactic Acid  

Science Journals Connector (OSTI)

...Biotechnology Engineering a Cyanobacterial...Metabolic engineering of microorganisms...chemicals, fuels, etc. Accordingly...indicate that the introduction of a lactate...to provide fuel and chemical...algae into biodiesel, which relaxes...accomplished by the introduction of genes encoding...contribute to the engineering of a cyanobacterial...

S. Andreas Angermayr; Michal Paszota; Klaas J. Hellingwerf

2012-08-03T23:59:59.000Z

391

Acid Placement in Acid Jetting Treatments in Long Horizontal Wells  

E-Print Network [OSTI]

In the Middle East, extended reach horizontal wells (on the order of 25,000 feet of horizontal displacement) are commonly acid stimulated by jetting acid out of drill pipe. The acid is jetted onto the face of the openhole wellbore as the drill pipe...

Sasongko, Hari

2012-07-16T23:59:59.000Z

392

Acid placement and coverage in the acid jetting process  

E-Print Network [OSTI]

Many open-hole acid treatments are being conducted by pumping acid through jetting ports placed at the end of coiled tubing or drill pipe. The filter-cake on the bore-hole is broken by the jet; the acid-soluble material is dissolved, creating...

Mikhailov, Miroslav I.

2009-05-15T23:59:59.000Z

393

Studies of Fundamental Properties of Rutherfordium (element 104) using Organic Complexing Agents  

E-Print Network [OSTI]

the studies of TBP hydrolysis used nitric acid systems. The12 M. This is due to TBP extraction of nitric acid. At this1 M TBP in benzene and the concentration of nitric acid in

Czerwinski, K.R.

2010-01-01T23:59:59.000Z

394

Thermodynamic Investigations of Aqueous Ternary Complexes for Am/Cm Separation  

E-Print Network [OSTI]

not extractable by TBP at high nitric acid concentrations.that TBP is also more stable against attack by nitric acid.TBP in kerosene to extract Pu(IV) and U(VI) from nitric acid

Leggett, Christina Joy

2012-01-01T23:59:59.000Z

395

Carboxylic acid sorption regeneration process  

DOE Patents [OSTI]

Carboxylic acids are sorbed from aqueous feedstocks into an organic liquid phase or onto a solid adsorbent. The acids are freed from the sorbent phase by treating it with aqueous alkylamine thus forming an alkylammonium carboxylate which is dewatered and decomposed to the desired carboxylic acid and the alkylamine.

King, C. Judson (Kensington, CA); Poole, Loree J. (Baton Rouge, LA)

1995-01-01T23:59:59.000Z

396

Carboxylic acid sorption regeneration process  

DOE Patents [OSTI]

Carboxylic acids are sorbed from aqueous feedstocks into an organic liquid phase or onto a solid adsorbent. The acids are freed from the sorbent phase by treating it with aqueous alkylamine thus forming an alkylammonium carboxylate which is dewatered and decomposed to the desired carboxylic acid and the alkylamine. 10 figs.

King, C.J.; Poole, L.J.

1995-05-02T23:59:59.000Z

397

Bioconversion of waste biomass to useful products  

DOE Patents [OSTI]

A process is provided for converting waste biomass to useful products by gasifying the biomass to produce synthesis gas and converting the synthesis gas substrate to one or more useful products. The present invention is directed to the conversion of biomass wastes including municipal solid waste, sewage sludge, plastic, tires, agricultural residues and the like, as well as coal, to useful products such as hydrogen, ethanol and acetic acid. The overall process includes the steps of gasifying the waste biomass to produce raw synthesis gas, cooling the synthesis gas, converting the synthesis gas to the desired product or products using anaerobic bioconversion, and then recovering the product or products. In accordance with a particular embodiment of the present invention, waste biomass is converted to synthesis gas containing carbon monoxide and, then, the carbon monoxide is converted to hydrogen by an anaerobic microorganism ERIH2, bacillus smithii ATCC No. 55404.

Grady, James L. (Fayetteville, AR); Chen, Guang Jiong (Fayetteville, AR)

1998-01-01T23:59:59.000Z

398

Bioconversion of waste biomass to useful products  

DOE Patents [OSTI]

A process is provided for converting waste biomass to useful products by gasifying the biomass to produce synthesis gas and converting the synthesis gas substrate to one or more useful products. The present invention is directed to the conversion of biomass wastes including municipal solid waste, sewage sludge, plastic, tires, agricultural residues and the like, as well as coal, to useful products such as hydrogen, ethanol and acetic acid. The overall process includes the steps of gasifying the waste biomass to produce raw synthesis gas, cooling the synthesis gas, converting the synthesis gas to the desired product or products using anaerobic bioconversion, and then recovering the product or products. In accordance with a particular embodiment of the present invention, waste biomass is converted to synthesis gas containing carbon monoxide and, then, the carbon monoxide is converted to hydrogen by an anaerobic microorganism ERIH2, Bacillus smithii ATCC No. 55404. 82 figs.

Grady, J.L.; Chen, G.J.

1998-10-13T23:59:59.000Z

399

Engineering metabolic systems for production of advanced fuels  

E-Print Network [OSTI]

keto acid pathways for bio- fuel production. The productionmaking bio- gasoline, bio-jet fuel, and biodiesel, as welldevelopment of bio-ethanol as an alternative fuel have led

Yan, Yajun; Liao, James C.

2009-01-01T23:59:59.000Z

400

Comparing the biodiesel and biogasoil production from different natural triglycerides  

Science Journals Connector (OSTI)

Regarding the sustainable mobility, product quality and environmental aspects fatty acids methyl esters and biogasoils were compared. They were produced by the transesterification and special hydrocracking (including the isomerization, as well) of triglycerides, ... Keywords: biodiesel, biogasoil, feedstock supply, quality comparison

Jenö Hancsók; Zoltán Varga; Sándor Kovács; Tamás Kasza

2011-12-01T23:59:59.000Z

Note: This page contains sample records for the topic "nitric acid production" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Nucleic acid isolation  

DOE Patents [OSTI]

A method is provided for isolating DNA from eukaryotic cell and flow sorted chromosomes. When DNA is removed from chromosome and cell structure, detergent and proteolytic digestion products remain with the DNA. These products can be removed with organic extraction, but the process steps associated with organic extraction reduces the size of DNA fragments available for experimental use. The present process removes the waste products by dialyzing a solution containing the DNA against a solution containing polyethylene glycol (PEG). The waste products dialyze into the PEG leaving isolated DNA. The remaining DNA has been prepared with fragments containing more than 160 kb. The isolated DNA has been used in conventional protocols without effect on the protocol.

Longmire, J.L.; Lewis, A.K.; Hildebrand, C.E.

1988-01-21T23:59:59.000Z

402

Nucleic acid isolation process  

DOE Patents [OSTI]

A method is provided for isolating DNA from eukaryotic cell and flow sorted chromosomes. When DNA is removed from chromosome and cell structure, detergent and proteolytic digestion products remain with the DNA. These products can be removed with organic extraction, but the process steps associated with organic extraction reduce the size of DNA fragments available for experimental use. The present process removes the waste products by dialyzing a solution containing the DNA against a solution containing polyethylene glycol (PEG). The waste products dialyze into the PEG leaving isolated DNA. The remaining DNA has been prepared with fragments containing more than 160 kb. The isolated DNA has been used in conventional protocols without affect on the protocol.

Longmire, Jonathan L. (Los Alamos, NM); Lewis, Annette K. (La Jolla, CA); Hildebrand, Carl E. (Los Alamos, NM)

1990-01-01T23:59:59.000Z

403

New Products  

Science Journals Connector (OSTI)

...syrris.com Crimping Tool The La-Pha-Pack stainless steel cleanroom crimping tools are designed for a controlled, low-effort...product range is ideal for highly sensitive chromatography cleanroom applications where it is essential that the environment remains...

2011-01-14T23:59:59.000Z

404

New Products  

Science Journals Connector (OSTI)

...qiagen.com Crimping Tool The La-Pha-Pack stainless steel cleanroom crimping tools are designed for a controlled, low-effort...product range is ideal for highly sensitive chromatography cleanroom applications where it is essential that the environment remains...

2011-01-21T23:59:59.000Z

405

New Products  

Science Journals Connector (OSTI)

...three regulated d-c power supplies, a digital...Product Data Sheet giving specifications, typical drying perform-ance...than 4 lb. Nominal power consumption is less...heaters and electrical insulation at elevated temperatures...and 0.01 xsec. Power source is a 5-Mw...

Joshua Stern

1961-11-10T23:59:59.000Z

406

Wastes and by-products - alternatives for agricultural use  

SciTech Connect (OSTI)

Top address a growing national problem with generation of wastes and by-products, TVA has been involved for several years with developing and commercializing environmentally responsible practices for eliminating, minimizing, or utilizing various wastes/by-products. In many cases, reducing waste generation is impractical, but the wastes/by-products can be converted into other environmentally sound products. In some instances, conversion of safe, value-added agricultural products in the best or only practical alternative. TVA is currently involved with a diversity of projects converting wastes/by-products into safe, economical, and agriculturally beneficial products. Environmental improvement projects have involved poultry litter, cellulosic wastes, used battery acid, ammonium sulfate fines, lead smelting effluents, deep-welled sulfuric acid/ammonium bisulfate solutions, wood ash, waste magnesium ammonium sulfate slurry from recording tape production, and ammunition plant waste sodium nitrate/ammonium nitrate streams.

Boles, J.L.; Craft, D.J.; Parker, B.R.

1994-10-01T23:59:59.000Z

407

Metabolic evolution of Escherichia coli strains that produce organic acids  

DOE Patents [OSTI]

This invention relates to the metabolic evolution of a microbial organism previously optimized for producing an organic acid in commercially significant quantities under fermentative conditions using a hexose sugar as sole source of carbon in a minimal mineral medium. As a result of this metabolic evolution, the microbial organism acquires the ability to use pentose sugars derived from cellulosic materials for its growth while retaining the original growth kinetics, the rate of organic acid production and the ability to use hexose sugars as a source of carbon. This invention also discloses the genetic change in the microorganism that confers the ability to use both the hexose and pentose sugars simultaneously in the production of commercially significant quantities of organic acids.

Grabar, Tammy; Gong, Wei; Yocum, R Rogers

2014-10-28T23:59:59.000Z

408

Availability of selected amino acids in sorghum grain and corn determined in ileocecal cannulated finishing pigs  

E-Print Network [OSTI]

trials to determine the availability of selected amino acids in corn and sorghum grain when measured at the distal ileum and in the feces. The cereal diets were based on grains representative of commercial production in Texas. Each pig received both... the corn and sorghum grain diets alternatively during two consecutive 18 day periods. A purified, non-protein diet was used to determine the endogenous amino acids in the ileal digests and feces. The apparent availability of amino acids from both grains...

Easter, Robert Arnold

2012-06-07T23:59:59.000Z

409

Acid-Catalyzed Dehydrogenation of Amine-Boranes  

Energy Innovation Portal (Marketing Summaries) [EERE]

A method of dehydrogenating an amine-borane using an acid-catalyzed reaction. The method generates hydrogen and produces a solid polymeric product. The method of dehydrogenating amine-boranes may be used to generate hydrogen for power generation sources such as fuel cells....

2013-03-28T23:59:59.000Z

410

Facile Lewis Acid Catalyzed Synthesis of C4 Symmetric Resorcinarenes  

Science Journals Connector (OSTI)

The Lewis acid catalyzed condensation of 3-methoxyphenol with octanal produced the C4 symmetric calix[4]resorcinarene 2, in high yield. Of the numerous stereo- and regioisomers possible, the rccc isomer with C4 symmetry was the only product isolated (as a ...

Matthew J. McIldowie; Mauro Mocerino; Brian W. Skelton; Allan H. White

2000-11-05T23:59:59.000Z

411

Communication no. 14 Fatty acid metabolism in liver slices  

E-Print Network [OSTI]

and in perchloric acid soluble products, ASP), and of oleate secretion as part of lipids in VLDL particles (purified by the hepatocytes in both species. After 7 h of labelling, rats secreted 7.22 ± 2.35 nmol of oleate into the lipids calves receive a milk replacer rich in lipids which are largely utilised as energy substrates for growth

Boyer, Edmond

412

Effect of Bioreactor Mode of Operation on Mixed-Acid Fermentations  

E-Print Network [OSTI]

acid concentration. Maximum conversion was achieved with a single stage. Recycling residual biomass retained microorganisms and nutrients and increased yield and productivity. Relative to lower biomass reflux, higher reflux increased conversion...

Golub, Kristina

2012-10-19T23:59:59.000Z

413

Steel--Project Fact Sheet: Recycling Acid and Metal Salts from Pickling Liquors  

SciTech Connect (OSTI)

Regenerating hydrochloric acids from metal finishing pickling baths reduces costs, wastes, and produces a valuable by-product--ferrous sulfate. Order your copy of this OIT project fact sheet and learn more about how your company can benefit.

Poole, L.; Recca, L.

1999-01-14T23:59:59.000Z

414

Evaluation of various sulphur amino acid compounds in the diet of red drum, Sciaenops ocellatus  

E-Print Network [OSTI]

Refinement of diet formulations to enhance the efficiency of red drum production continues to be pursued. Based on previous studies, the sulfur amino acid (SAA) requirement of red drum for methionine plus cystine appears to be most limiting, which...

Goff, Jonathan B

2003-01-01T23:59:59.000Z

415

Ethylene oxidation by lithium nitrate in the presence of palladium acetate in acetic acid  

Science Journals Connector (OSTI)

Data are reported on variations of the gas phase volume and product accumulation in ethylene oxidation by lithium nitrate in acetic acid solutions, catalyzed by palladium acetate. An assumption is made on the rou...

N. I. Kuznetsova; A. F. Danilyuk…

416

E-Print Network 3.0 - abnormal fatty acid Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

2C involved... that include Ca2+ uxes, the production of free fatty acids from membrane lipids, as well as the activation... of the MAPK pathway by wound-induced Ca2+ and fatty...

417

Acetic Acid from the Carbonylation of Chloride Methane Over Rhodium Based Catalysts  

E-Print Network [OSTI]

of commercially important materials like vinyl acetate monomer (VAM), cellulose acetate, and acetate esters. MoreAcetic Acid from the Carbonylation of Chloride Methane Over Rhodium Based Catalysts Yafang Fan Ã? that makes use of the latest advance in methyl chloride production is reported. Acetic acid was produced from

Bao, Xinhe

418

Enzyme and Microbial Technology 35 (2004) 648653 Batch and continuous fermentation of succinic acid from wood  

E-Print Network [OSTI]

acid from wood hydrolysate by Mannheimia succiniciproducens MBEL55E Do Yun Kim, Seong Chun Yim, Pyung out in a complex medium containing a NaOH- treated wood hydrolysate for the production of succinic acid. The wood hydrolysate based medium was treated with NaOH before sterilization to reduce

419

Broiler Production.  

E-Print Network [OSTI]

,","efficient broiler production. ,. . , .: I-A +>+ Panels or translucent plastic curtains which close and open easily when weather varies are helpful in providing comfortable temperatures for the birds. A damper is needed so that ridge ventilatm can be dosed... easily during ooM weather. inclement weather. However, poultry housing costs should be kept within a range whereby earnings can justify the investment. Location Orient the house with the long axis run- ning east and west to prevent the early morn...

Cawley, W. O.; Wormeli, B. C.; Quisenberry, J. H.

1962-01-01T23:59:59.000Z

420

Fermentation inhibitors and their recovery from acid wood hydrolyzates as chemicals of value  

SciTech Connect (OSTI)

The principal objective of this study was to demonstrate the technical feasibility of fermentation inhibition removal from acid hydrolyzates of lignocellulosic materials and recovery of the by-products of acid hydrolysis as chemicals of value. The acid hydrolyzates of mixed hardwoods were produced from the continuous flow demonstration unit (CFDU) at the University of California Forest Products Laboratory. Two separate liquid product streams were the prehydrolyzate (S1H) and the second stage hydrolyzate (S2H). Candida utilis NRRL Y-900 and Saccharomyces cerevisiae NRRL 2034 were used to monitor the fermentability of these two product streams, respectively. Two pretreatment methods were investigated in detail: flashing and solvent extraction. For the S1H, flashing was adequate to enable cell production with Candida utilis. The S2H rehired solvent extraction to ensure ethanolic fermentation at high concentrations of glucose (12% or higher). A solvent was selected for the extraction process and process flow designs were proposed to recycle the solvent and isolate commercial by-products, including furfural, methanol, acetic acid and, potentially, formic acid, levulinic acid and 5-hydroxymethylfurfural.

Tran, Hao Cao.

1986-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "nitric acid production" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Sugar Production  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Sugar Production Sugar Production Name: Lauren Location: N/A Country: N/A Date: N/A Question: This is the experiment I did: our class took 6 sugars, placed them in test tubes and put three drops of yeast in each test tube. we then placed them in the incubator for one day and the next day looked at our results. the purpose was to find out with sugar would produce the most carbon dioxide. two of the sugars that we tested were LACTOSE and STARCH. my question is, why are lactose and starch the only sugars who didn't produce any, or very very little, carbon dioxide? and how is this process related to glycolysis? Replies: Bacteria and yeast are very efficient with their enzyme systems. They don't make enzymes they can't use. Yeast don't have the enzymes necessary to metabolize lactose. Starch is a complex sugar and yeast needs certain enzymes to break starch down into sugar. Every chemical reaction needs its own enzyme.

422

Heterogeneous and Monolithic Catalyst Development for the Biodiesel Production Process & Evaluation of Static Mixers for the Esterification Process .  

E-Print Network [OSTI]

??In the present biodiesel production process, sodium hydroxide and sulphuric acid are the conventional homogeneous catalysts used, in spite of their drawbacks, such as soap… (more)

Annamalai, Nagarajan

2012-01-01T23:59:59.000Z

423

Acidic gas capture by diamines  

DOE Patents [OSTI]

Compositions and methods related to the removal of acidic gas. In particular, the present disclosure relates to a composition and method for the removal of acidic gas from a gas mixture using a solvent comprising a diamine (e.g., piperazine) and carbon dioxide. One example of a method may involve a method for removing acidic gas comprising contacting a gas mixture having an acidic gas with a solvent, wherein the solvent comprises piperazine in an amount of from about 4 to about 20 moles/kg of water, and carbon dioxide in an amount of from about 0.3 to about 0.9 moles per mole of piperazine.

Rochelle, Gary (Austin, TX); Hilliard, Marcus (Missouri City, TX)

2011-05-10T23:59:59.000Z

424

Pillared clays as superior catalysts for selective catalytic reduction of nitric oxide. Second semiannual report, 1996  

SciTech Connect (OSTI)

During the first six months of the program, the work has progressed as planned. We have constructed a reactor system and assembled all laboratory essentials for conducting the three-year project. First, the catalytic activities of the Cu(2+) ion exchanged alumina-pillared clay for the selective catalytic reduction of NO by ethylene were measured. The temperature range was 250-500{degrees}C. The activities of this catalyst were substantially higher than the catalyst that has been extensively studied in the literature, Cu-ZSM-5. Fourier Transform Infrared Spectroscopy (FTIR) was used to study the acidity of the catalyst. The second part of the work was an in-depth FTIR study of the NO decomposition mechanism on the catalyst. This was planned as the first and the key step to obtain an understanding of the reaction mechanism. Key surface intermediates were identified from the FTIR spectra, and a redox type Eley-Rideal mechanism was proposed for the NO decomposition on this catalyst. This report will be divided into two parts. In Part One, we report results on the catalytic activities of the Cu-alumina-pillared clay and a direct comparison with other known catalysts. In Part two, we focus on the FTIR study and from the results, we propose a NO decomposition mechanism on this new catalyst. Plans for the next six months include tests of different pillared clays as well as the catalytic mechanism. The micro reactor will continue to be the key equipment for measuring the catalytic activities. FTIR will continue to be the major technique for identifying surface species and hence understanding the reaction mechanism.

Yang, R.T.; Li, W.B.; Sirilumpen, M.; Tharapiwattananon, N.

1997-08-01T23:59:59.000Z

425

Production Services  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Welcome Welcome The Production Services site contains links to each of the division's groups with descriptions of their services. Our goal is to update this website frequently to reflect ongoing service upgrades which, by planning and design, are added so that we can continue to meet your needs in a constantly changing work environment. Note: The Graphic Design Studio has been relocated to the second floor in the north wing of the Research Support Building 400. The telephone number remains the same, X7288. If you have any questions, please call supervisor, Rick Backofen, X6183. Photography Photography services are available at no charge to BNL and Guest users. See a list of the complete range of photography services available. Video Video services are available at no charge to BNL and Guest users. See a list of the complete range of video services available.

426

Experimental Study of Mechanistic Acid Deconstruction of Lignin  

SciTech Connect (OSTI)

Lignin is a major component of biomass, which remains highly underutilized in selective biomass conversion strategies to renewable fuels and chemicals. Here we are interested in studying the mechanisms related to the acid deconstruction of lignin with a combined theoretical and experimental approach. Quantum mechanical calculations were employed to elucidate possible deconstruction mechanisms with transition state theory. Model dimers, imitating H, S, and G lignins, were synthesized with the most abundant {beta} - O - 4 linkage in lignin. These compounds were then depolymerized using various acids and at different operating conditions. The deconstruction products were analyzed to complement the QM studies and investigate proposed mechanisms.

Sturgeon, M.; Kim, S.; Chmely, S. C.; Katahira, R.; Foust, T. D.; Beckham, G. T.

2012-01-01T23:59:59.000Z

427

Product lines for digital information products.  

E-Print Network [OSTI]

??Digital information products are an important class of widely used digital products, whose core benefit is the delivery of information or education (e.g., electronic books,… (more)

Pankratius, Victor

2007-01-01T23:59:59.000Z

428

Photochemical Studies on Xanthurenic Acid  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Photochemical Studies on Xanthurenic Acid Photochemical Studies on Xanthurenic Acid J. E. Roberts, J. F. Wishart, L. Martinez, C. F. Chignell Photochem.Photobiol. 72, 467-471 (2000) Abstract: The tryptophan metabolite xanthurenic acid has been isolated from aged human cataractous lenses. The photophysical properties of xanthurenic acid were examined to determine if it is a potential chromophore for age-related cataractogenesis. We found that xanthurenic acid produces singlet oxygen (F*= 0.17; CD3OD) with the same efficiency as the lenticular chromophore N-formyl kynurenine and quenches singlet oxygen at a rate similar to other tryptophan metabolites (2.1 x 107 M-1 s-1; CD3OD) found in the eye. As the mechanisms of induction of cataracts may also involve redox reactions, the interactions of hydrated electrons (e-aq), the azide radical

429

Rehydration of the Lichen Ramalina lacera Results in Production of Reactive Oxygen Species and Nitric Oxide and a Decrease in Antioxidants  

Science Journals Connector (OSTI)

...over distilled water. This air stream...and to prevent water condensation on its inner walls...Vainio exposed to atmospheric pollutants. Physiol...as a function of water content and suggestion...D. S. 1988. Recovery of net photosynthesis...

Lior Weissman; Jacob Garty; Ayala Hochman

2005-04-01T23:59:59.000Z

430

Nitric oxide production occurs downstream of reactive oxygen species in guard cells during stomatal closure induced by chitosan in abaxial epidermis of Pisum sativum  

Science Journals Connector (OSTI)

The effects of chitosan (?-1,4 linked glucosamine, a ... (NO scavenger), sodium tungstate (nitrate reductase inhibitor) or l-NAME (NO synthase inhibitor) restricted the chitosan induced stomatal closure, demonstr...

Nupur Srivastava; Vijay K. Gonugunta; Mallikarjuna R. Puli…

2009-03-01T23:59:59.000Z

431

Effect of acetic acid on lipid accumulation by glucose-fed activated sludge cultures  

SciTech Connect (OSTI)

The effect of acetic acid, a lignocellulose hydrolysis by-product, on lipid accumulation by activated sludge cultures grown on glucose was investigated. This was done to assess the possible application of lignocellulose as low-cost and renewable fermentation substrates for biofuel feedstock production. Results: Biomass yield was reduced by around 54% at a 2 g L -1 acetic acid dosage but was increased by around 18% at 10 g L -1 acetic acid dosage relative to the control run. The final gravimetric lipid contents at 2 and 10 g L -1 acetic acid levels were 12.5 ���± 0.7% and 8.8 ���± 3.2% w/w, respectively, which were lower than the control (17.8 ���± 2.8% w/w). However, biodiesel yields from activated sludge grown with acetic acid (5.6 ���± 0.6% w/w for 2 g L -1 acetic acid and 4.2 ���± 3.0% w/w for 10 g L -1 acetic acid) were higher than in raw activated sludge (1-2% w/w). The fatty acid profiles of the accumulated lipids were similar with conventional plant oil biodiesel feedstocks. Conclusions: Acetic acid enhanced biomass production by activated sludge at high levels but reduced lipid production. Further studies are needed to enhance acetic acid utilization by activated sludge microorganisms for lipid biosynthesis.

Mondala, Andro; Hernandez, Rafael; French, Todd; McFarland, Linda; Sparks, Darrell; Holmes, William; Haque, Monica

2012-01-01T23:59:59.000Z

432

@Title = Definitions of Petroleum Products and Other Terms  

U.S. Energy Information Administration (EIA) Indexed Site

Definitions of Petroleum Products and Other Terms (Revised January 2010) Alcohol. The family name of a group of organic chemical compounds composed of carbon, hydrogen, and oxygen. The series of molecules vary in chain length and are composed of a hydrocarbon plus a hydroxyl group; CH 3 - (CH 2 )n-OH (e.g., methanol, ethanol, and tertiary butyl alcohol). Alkylate. The product of an alkylation reaction. It usually refers to the high octane product from alkylation units. This alkylate is used in blending high octane gasoline. Alkylation. A refining process for chemically combining isobutane with olefin hydrocarbons (e.g., propylene, butylene) through the control of temperature and pressure in the presence of an acid catalyst, usually sulfuric acid or hydrofluoric acid. The product, alkylate, an

433

Plants and Night Oxygen Production  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Plants and Night Oxygen Production Plants and Night Oxygen Production Name: Ashar Status: other Grade: other Location: Outside U.S. Country: India Date: Winter 2011-2012 Question: I would like to know if there are any plants which produces oxygen at night (without photosynthesis). I was told by a friend that Holy Basil (Ocimum tenuiflorum) produces oxygen even at night and I'm not convinced. I would like to get confirmation from experts. Replies: Some plants (particularly those of dry regions, e.g., deserts) only open their stomates at night to avoid drying out to intake CO2 (and output O2) (CAM photosynthesis) http://en.wikipedia.org/wiki/Crassulacean_acid_metabolism Sincerely, Anthony R. Brach, PhD Missouri Botanical Garden Bringing oxygen producing plants into your home is a way to mimic the healthy lifestyle factors of longevity in humans from the longest lived cultures.

434

An integrated computational and experimental study for overproducing fatty acids in Escherichia coli  

E-Print Network [OSTI]

for the catalytic production of industrial chemicals and diesel- like biofuels. However, bio-production of fatty., 2010) as gasoline bio-alternatives and fatty acids as promising intermediates for diesel bio, such as bio- ethanol (Fortman et al., 2008) produced from corn has relatively low energy density and water

Maranas, Costas

435

In vitro reconstitution and steady-state analysis of the fatty acid synthase from Escherichia coli  

Science Journals Connector (OSTI)

...the production of diesel-like fuels. Due to...Fig. 1. Catalytic cycle of the E. coli fatty...chain elongation cycle of the FAS. A plausible explanation...enzymatic chains. General properties, control...role in completing cycles of fatty acid elongation...the production of diesel-like fuels...

Xingye Yu; Tiangang Liu; Fayin Zhu; Chaitan Khosla

2011-01-01T23:59:59.000Z

436

Composition of the ozonolytic degradation products of the organic matter of Barzasskii sapromyxite coal  

SciTech Connect (OSTI)

The ozonization of Barzasskii sapromyxite coal in chloroform and the composition of ozonolytic degradation products were studied. Water-insoluble high-molecular-weight products were predominant among the ozonization products. A half of water-soluble substances consisted of aliphatic C{sub 5}-C{sub 12} dicarboxylic acids and benzenedicarboxylic acid derivatives. Sapromyxite has been suggested as a substitute for crude petroleum in the manufacture of motor fuels.

S.A. Semenova; Y.F.Patrakov [Russian Academy of Sciences, Kemerovo (Russian Federation). Institute of Coal and Coal Chemistry

2009-04-15T23:59:59.000Z

437

Development of Nitric Oxide Oxidation Catalysts for the Fast SCR Reaction  

SciTech Connect (OSTI)

This study was undertaken in order to assess the potential for oxidizing NO to NO{sub 2} in flue gas environments, with the aim of promoting the so-called fast SCR reaction. In principle this can result in improved SCR kinetics and reduced SCR catalyst volumes. Prior to commencing experimental work, a literature study was undertaken to identify candidate catalysts for screening. Selection criteria comprised (1) proven (or likely) activity for NO oxidation, (2) low activity for SO2 oxidation (where data were available), and (3) inexpensive component materials. Catalysts identified included supported base metal oxides, supported and unsupported mixed metal oxides, and metal ion exchanged ZSM-5 (Fe, Co, Cu). For comparison purposes, several low loaded Pt catalysts (0.5 wt% Pt) were also included in the study. Screening experiments were conducted using a synthetic feed gas representative of flue gas from coal-fired utility boilers: [NO] = 250 ppm, [SO{sub 2}] = 0 or 2800 ppm, [H{sub 2}O] = 7%, [CO{sub 2}] = 12%, [O{sub 2}] = 3.5%, balance = N{sub 2}; T = 275-375 C. Studies conducted in the absence of SO{sub 2} revealed a number of supported and unsupported metal oxides to be extremely active for NO oxidation to NO{sub 2}. These included known catalysts (Co{sub 3}O{sub 4}/SiO{sub 2}, FeMnO{sub 3}, Cr{sub 2}O{sub 3}/TiO{sub 2}), as well as a new one identified in this work, CrFeO{sub x}/SiO{sub 2}. However, in the presence of SO{sub 2}, all the catalysts tested were found to be severely deactivated with respect to NO oxidation. Of these, Co{sub 3}O{sub 4}/SiO{sub 2}, Pt/ZSM-5 and Pt/CeO{sub 2} showed the highest activity for NO oxidation in the presence of SO{sub 2} (based on peak NO conversions to NO{sub 2}), although in no cases did the NO conversion exceed 7%. Reactor studies indicate there are two components to SO{sub 2}-induced deactivation of Co{sub 3}O{sub 4}/SiO{sub 2}, corresponding to an irreversible deactivation due to sulfation of the surface of the Co{sub 3}O{sub 4} phase, together with a reversible inhibition due to competitive adsorption of SO{sub 2} with NO on the catalyst. In an effort to minimize the deactivating effect of SO{sub 2} on Co{sub 3}O{sub 4}/SiO{sub 2}, two synthetic approaches were briefly examined. These consisted of (1) the incorporation of highly dispersed Co(II) ions in silica, as a non-sulfating matrix, via the sol-gel preparation of CoO-SiO{sub 2}; and (2) the sol-gel preparation of a mixed metal oxide, CoO-Nb{sub 2}O{sub 5}-SiO{sub 2}, with the aim of exploiting the acidity of the niobium oxide to minimize SO2 adsorption. While both catalysts showed almost no activity for NO oxidation in the absence of SO{sub 2}, when SO{sub 2} was present low activity was observed, indicating that SO{sub 2} acts as a promoter for NO oxidation over these materials. The kinetics of NO oxidation over Co{sub 3}O{sub 4}/SiO{sub 2}, Pt/SiO{sub 2} and Pt/CeO{sub 2} were also examined. Co{sub 3}O{sub 4}/SiO{sub 2} was found to exhibit a higher apparent activation energy for NO oxidation than the Pt catalysts, while the combined reaction order in NO and O{sub 2} for the three catalysts was very close to one. CO{sub 2} was found to have no effect on the kinetics of NO oxidation over these catalysts. The presence of H{sub 2}O caused a decrease in NO conversion for both Co{sub 3}O{sub 4}/SiO{sub 2} and Pt/CeO{sub 2} catalysts, while no effect was observed for Pt/SiO{sub 2}. The inhibiting effect of water was reversible and is attributed to competitive adsorption with the reactants. In sum, this study has shown that a variety of base metal catalysts are very active for NO oxidation. However, all of the catalysts studied are strongly deactivated in the presence of 2800 ppm SO{sub 2} at typical flue gas temperatures; consequently improving catalyst resistance to SO{sub x} will be a pre-requisite if the fast SCR concept is to be applied to coal-fired flue gas conditions.

Mark Crocker

2005-09-30T23:59:59.000Z

438

Treatment of acid mine wastewaters  

SciTech Connect (OSTI)

Acid mine drainage often results from the oxidation sulfide minerals to form sulfuric acid. As a consequence, high concentrations of metals in the both the suspended and dissolved state result from the low pH water. This paper discusses several of the more common treatment methods for acid mine drainage including the use of chemical precipitation agents, pH correction agents, filtration methods, and biodegradation methods. Advanced treatment technologies are also briefly described and include microfiltration, reverse osmosis, ion exchange, and electrodialysis.

Hayward, D.; Barnard, R.

1993-06-01T23:59:59.000Z

439

Naphthenic acid corrosion literature survey  

SciTech Connect (OSTI)

Naphthenic acid corrosion is a growing concern for refineries processing crudes containing high levels of naphthenic acid. Due to this concern initiatives in place to better understand the mechanism of corrosion for mitigating the corrosion. During the 1996 Fall Corrosion Group, organized existing literature relevant to the literature search. Committee Week, NACE International many refineries have and evaluate methods T-8 Refining Industry a task group, T-8-22, to perform a review and compilation of naphthenic acid corrosion. This paper provides a summary of the literature research.

Babaian-Kibala, E. [Nalco/Exxon Energy Chemicals, Sugar Land, TX (United States); Nugent, M.J. [Tosco Refining Co., Linden, NJ (United States)

1999-11-01T23:59:59.000Z

440

Interrelated influence of superoxides and free fatty acids over mitochondrial uncoupling in skeletal muscle  

Science Journals Connector (OSTI)

Mitochondrial uncoupling protein 3 (UCP3)-mediated uncoupling has been postulated to depend on several factors, including superoxides, free fatty acids (FFAs), and fatty acid hydroperoxides and/or their derivatives. We investigated whether there is an interrelation between endogenous mitochondrial superoxides and fatty acids in inducing skeletal muscle mitochondrial uncoupling, and we speculated on the possible involvement of UCP3 in this process. In the absence of FFAs, no differences in proton-leak kinetic were detected between succinate-energized mitochondria respiring in the absence or presence of rotenone, despite a large difference in complex I superoxide production. The addition of either arachidic acid or arachidonic acid induced an increase in proton-leak kinetic, with arachidonic acid having the more marked effect. The uncoupling effect of arachidic acid was independent of the presence of GDP, rotenone and vitamin E, while that of arachidonic acid was dependent on these factors. These data demonstrate that FFA and O2? play interrelated roles in inducing mitochondrial uncoupling, and we hypothesize that a likely formation of mitochondrial fatty acid hydroperoxides is a key event in the arachidonic acid-induced GDP-dependent inhibition of mitochondrial uncoupling.

Assunta Lombardi; Paola Grasso; Maria Moreno; Pieter de Lange; Elena Silvestri; Antonia Lanni; Fernando Goglia

2008-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "nitric acid production" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Asphaltene damage in matrix acidizing  

E-Print Network [OSTI]

This work addresses the problem of asphaltene deposition that occurs during acid treatments of oil reservoirs. Asphaltenes are present to some degree in most hydrocarbons. Due to the molecular weight of the components these asphaltenes are more...

Hinojosa, Roberto Antonio

2012-06-07T23:59:59.000Z

442

Factors controlling naphthenic acid corrosion  

SciTech Connect (OSTI)

A laboratory study was conducted to elucidate the influence of chemical and physical parameters on corrosion of type 1018 carbon steel (CS, UNS G10180) and 5% Cr-0.5% Mo steel in oils containing naphthenic acids (NAs) for application to crude oil refinery systems. Effects of test duration, temperature, and acid concentration were assessed for a range of single acids of varying carbon numbers and for NA mixtures in mineral oil (MO) and in heavy vacuum gas oil (HGVO). In addition, a limited study of the effect of hydrogen sulfide (H{sub 2}S) addition to the acid-oil mixture was conducted. Use of the total acid number (TAN) as a measure of corrosiveness of a crude oil was discredited further. For the same TAN value, molecular size and structure of the acid were shown to have an important influence. Tests conducted in HGVO showed lower corrosion rates than in MO, suggesting inhibition caused by S species in the oil or the steric hindrance of naphtheno-aromatic acids. In oil containing the mixture of NAs, the corrosion rate of type 1018 CS was lower than that for 5% Cr-0.5% Mo steel. The 0.1% H{sub 2}S that passed through the acid-oil mixtures had an inhibiting effect on corrosion. Predicting corrosiveness of a crude oil from the measurement of TAN, distribution of NA composition, and S content and form was particularly challenging. The simple tests used were informative, but further work will be required to establish a standard test method that can provide an adequate ranking of crudes.

Turnbull, A. [National Physical Lab., Teddington (United Kingdom); Slavcheva, E. [Bulgarian Academy of Sciences, Sofia (Bulgaria); Shone, B. [Ty Isa, Nr Mold (United Kingdom)

1998-11-01T23:59:59.000Z

443

Characterization and analysis of the cotton cyclopropane fatty acid synthase family and their contribution to cyclopropane fatty acid synthesis  

SciTech Connect (OSTI)

Cyclopropane fatty acids (CPA) have been found in certain gymnosperms, Malvales, Litchi and other Sapindales. The presence of their unique strained ring structures confers physical and chemical properties characteristic of unsaturated fatty acids with the oxidative stability displayed by saturated fatty acids making them of considerable industrial interest. While cyclopropenoid fatty acids (CPE) are well-known inhibitors of fatty acid desaturation in animals, CPE can also inhibit the stearoyl-CoA desaturase and interfere with the maturation and reproduction of some insect species suggesting that in addition to their traditional role as storage lipids, CPE can contribute to the protection of plants from herbivory. Three genes encoding cyclopropane synthase homologues GhCPS1, GhCPS2 and GhCPS3 were identified in cotton. Determination of gene transcript abundance revealed differences among the expression of GhCPS1, 2 and 3 showing high, intermediate and low levels, respectively, of transcripts in roots and stems; whereas GhCPS1 and 2 are both expressed at low levels in seeds. Analyses of fatty acid composition in different tissues indicate that the expression patterns of GhCPS1 and 2 correlate with cyclic fatty acid (CFA) distribution. Deletion of the N-terminal oxidase domain lowered GhCPS's ability to produce cyclopropane fatty acid by approximately 70%. GhCPS1 and 2, but not 3 resulted in the production of cyclopropane fatty acids upon heterologous expression in yeast, tobacco BY2 cell and Arabidopsis seed. In cotton GhCPS1 and 2 gene expression correlates with the total CFA content in roots, stems and seeds. That GhCPS1 and 2 are expressed at a similar level in seed suggests both of them can be considered potential targets for gene silencing to reduce undesirable seed CPE accumulation. Because GhCPS1 is more active in yeast than the published Sterculia CPS and shows similar activity when expressed in model plant systems, it represents a strong candidate gene for CFA accumulation via heterologous expression in production plants.

Yu X. H.; Shanklin J.; Rawat, R.

2011-05-01T23:59:59.000Z

444

Proceedings of the Seventh Walnut Council Research Symposium 15GTR-NRS-P-115 BIOREFINERY OPPORTUNITIES FOR FOREST PRODUCTS INDUSTRIES  

E-Print Network [OSTI]

, lactic acid used to produce polylactic acids for producing biodegradable plastic to replace polystyrene gasifies biomass to produce hydrogen and carbon monoxide and then reforms it into products including diesel or aviation fuel and methanol. The literature on the chemical and biochemical processes for these new products

445

Coagulase-Negative Staphylococci Favor Conversion of Arginine into Ornithine despite a Widespread Genetic Potential for Nitric Oxide Synthase Activity  

Science Journals Connector (OSTI)

...1128/JB.187.21.7292-7308.2005 . 38. Weckx, S , P De Rijk, C Van Broeckhoven and J Del-Favero. 2004. SNPbox: Web-based high-throughput primer design from gene to genome. Nucleic Acids Res. 32 :170-172. doi: 10.1093/nar/gkh369...

María Sánchez Mainar; Stefan Weckx; Frédéric Leroy

2014-10-03T23:59:59.000Z

446

Metabolic evolution of energy-conserving pathways for succinate production in Escherichia coli  

Science Journals Connector (OSTI)

...plastics and solvents with a potential global market of $15 billion (2). Although succinate is primarily...because of the global increase in bio-diesel production. Being more reduced than glucose...Biotechnology of succinic acid production and markets for derived industrial products . Appl...

Xueli Zhang; Kaemwich Jantama; Jonathan C. Moore; Laura R. Jarboe; Keelnatham T. Shanmugam; Lonnie O. Ingram

2009-01-01T23:59:59.000Z

447

Crevice corrosion products of dental amalgam  

SciTech Connect (OSTI)

The objective of this study was to determine the in vitro corrosion products that resulted from crevice corrosion of low- and high-copper dental amalgams. Specimens were potentiostatically polarized in a chloride-containing electrolyte while set against a PTFE surface to form a crevice. After 16 h, corrosion products were examined by light microscopy, SEM, EDS, and XRD. Analysis showed the presence of three previously reported products (Sn4(OH)6Cl2, SnO, and Cu2O) and a new product, CuCl, which formed on high-copper, {gamma} 2-free amalgams. Thermodynamic considerations show that CuCl is stable for the reported in vivo potentials of amalgam restorations and the high acidity and high chloride ion concentration associated with crevice corrosion.

Sutow, E.J.; Jones, D.W.; Hall, G.C.; Owen, C.G. (Division of Dental Biomaterials Science, Faculty of Dentistry, Dalhousie University, Halifax, Nova Scotia (Canada))

1991-07-01T23:59:59.000Z

448

A new N-hydroxyethyliminodiacetic acid modified core–shell silica phase for chelation ion chromatography of alkaline earth, transition and rare earth elements  

Science Journals Connector (OSTI)

Abstract Bare core–shell silica (1.7 ?m) has been modified with iminodiacetic acid functional groups via standard silane chemistry, forming a new N-hydroxyethyliminodiacetic acid (HEIDA) functionalised core–shell stationary phase. The column was applied in high-performance chelation ion chromatography and evaluated for the retention of alkaline earth, transition and heavy metal cations. The influence of nitric acid eluent concentration, addition of complexing agent dipicolinic acid, eluent pH and column temperature on the column performance was investigated. The efficiencies obtained for transition and heavy metal cations (and resultant separations) were comparable or better than those previously obtained for alternative fully porous silica based chelation stationary phases, and a similarly modified monolithic silica column, ranging from ?15 to 56 ?m HETP. Increasing the ionic strength of the eluent with the addition of KNO3 (0.75 M) and increasing the column temperature (70 °C) facilitated the isocratic separation of a mixture of 14 lanthanides and yttrium in under 12 min, with HETP averaging 18 ?m (7 ?m for Ce(III))

Nicola McGillicuddy; Ekaterina P. Nesterenko; Pavel N. Nesterenko; Elaine M. Stack; Jesse O. Omamogho; Jeremy D. Glennon; Brett Paull

2013-01-01T23:59:59.000Z

449

NO/sub x/ control and recovery from products of combustion  

SciTech Connect (OSTI)

The disclosed method for removing nitric oxide and or nitrogen dioxide (NO/sub x/) from a gaseous stream comprises the step of intimately mixing sodium or potassium carbonate and either ferric oxide or manganese dioxide. The gaseous stream containing NO/sub x/ is subsequently brought into contact with the mixture at a temperature between 300/sup 0/C and 500/sup 0/C to cause absorption of the NO/sub x/ in the mixture. Nitric oxide can be desorbed from the mixture by elevating its temperature or by other chemical processes. It is also possible to return the concentrated NO/sub x/ gaseous products to the producing combustion chamber for decomposition at the equilibrium concentration at the combustion chamber temperature. It is a first object of this disclosure to provide an effective solid sorbent for NO/sub x/ in a gaseous stream, the sorbent being produced by simple mixing without requiring further preprocessing of the chemicals before or after their mixture. Another object of this invention is to provide a solid sorbent having higher absorbing capabilities than those previously reported. Another object is to provide a solid sorbent which is effective in gaseous streams containing substantial quantities of either carbon dioxide or oxygen.

Evoniuk, C.J.; McCandless, F.P.

1980-06-20T23:59:59.000Z

450

Production of Polyethylene Terephthalate using a Nonmetallic Catalyst Dr. Marsha Winston1, Jared Langson2, Angus Ferguson2, Dr. Robert Posey2  

E-Print Network [OSTI]

Production of Polyethylene Terephthalate using a Nonmetallic Catalyst Dr. Marsha Winston1, Jared Department of Chemistry Polyethylene terephthalate (PET) is a condensation polymer of terephthalic acid (HOOC

451

Covered Product Category: Cool Roof Products  

Broader source: Energy.gov [DOE]

FEMP provides acquisition guidance across a variety of product categories, including cool roof products, which are an ENERGY STAR®-qualified product category. Federal laws and requirements mandate that agencies meet these efficiency requirements in all procurement and acquisition actions that are not specifically exempted by law.

452

Development of All-Solid-State Sensors for Measurement of Nitric Oxide and Ammonia Concentrations by Optical Absorption in Particle-Laden Combustion Exhaust Streams  

SciTech Connect (OSTI)

An all-solid-state continuous-wave (cw) laser system for ultraviolet absorption measurements of the nitric oxide (NO) molecule has been developed and demonstrated. For the NO sensor, 250 nW of tunable cw ultraviolet radiation is produced by sum-frequency-mixing of 532-nm radiation from a diode-pumped Nd:YAG laser and tunable 395-nm radiation from an external cavity diode laser (ECDL). The sum-frequency-mixing process occurs in a beta-barium borate crystal. The nitric oxide absorption measurements are performed by tuning the ECDL and scanning the sum-frequency-mixed radiation over strong nitric oxide absorption lines near 226 nm. In Year 1 of the research, the nitric oxide sensor was used for measurements in the exhaust of a coal-fired laboratory combustion facility. The Texas A&M University boiler burner facility is a 30 kW (100,000 Btu/hr) downward-fired furnace with a steel shell encasing ceramic insulation. Measurements of nitric oxide concentration in the exhaust stream were performed after modification of the facility for laser based NOx diagnostics. The diode-laser-based ultraviolet absorption measurements were successful even when the beam was severely attenuated by particulate in the exhaust stream and window fouling. Single-laser-sweep measurements were demonstrated with an effective time resolution of 100 msec, limited at this time by the scan rate of our mechanically tuned ECDL system. In Year 2, the Toptica ECDL in the original system was replaced with a Sacher Lasers ECDL. The mode-hop-free tuning range and tuning rate of the Toptica ECDL were 25 GHz and a few Hz, respectively. The mode-hop-free tuning range and tuning rate of the Sacher Lasers ECDL were 90 GHz and a few hundred Hz, respectively. The Sacher Lasers ECDL thus allows us to scan over the entire NO absorption line and to determine the absorption baseline with increased accuracy and precision. The increased tuning rate is an advantage in that data can be acquired much more rapidly and the absorption measurements are less susceptible to the effects of transient fluctuations in the properties of the coal combustor exhaust stream. Gas cell measurements were performed using the NO sensor with the new ECDL, and a few spectra were acquired from the coal exhaust stream. However, the laser diode in the new ECDL failed during the coal combustor tests. In Year 3, however, we obtained a new GaN laser diode for our ECDL system, installed it, and completed an extensive series of measurements in the Texas A&M coal-fired laboratory combustion facility. The combustor was operated with coal and coal/biomass as fuels, with and without reburn, and with and without ammonia injection. Several different fuel equivalence ratios were investigated for each operating condition.

Jerald A. Caton; Kalyan Annamalai; Robert P. Lucht

2006-12-31T23:59:59.000Z

453

Aesculap, Inc. Air Products  

E-Print Network [OSTI]

Aesculap, Inc. Air Products Air Products Foundation Alaric Compliance Services, LLC Alvin H. Butz & Herger, Inc. Sodexo Campus Services Sodexo Inc. and Affiliates Stupp Bros., Inc. Sugarbush Products, Inc

Napier, Terrence

454

Sandstone Acidizing Using Chelating Agents and their Interaction with Clays  

E-Print Network [OSTI]

Sandstone acidizing has been carried out with mud acid which combines hydrochloric acid and hydrofluoric acid at various ratios. The application of mud acid in sandstone formations has presented quite a large number of difficulties like corrosion...

George, Noble Thekkemelathethil 1987-

2013-01-09T23:59:59.000Z

455

Degradation of Cellulose to Organic Acids in its Homogeneous Alkaline Aqueous Solution  

Science Journals Connector (OSTI)

Hefei National Laboratory for Physical Sciences at Microscale and Department of Chemical Physics, CAS Key Laboratory of Soft Matter Chemistry, University of Science and Technology of China, Hefei, 230026, P.R. ... Malonic acid (MA), lactic acid (LA), formic acid (FA), and acetic acid (AA) are the major valuable products, among them MA and LA are the top valuable platform molecules for synthesis of bulk chemicals and fuels. ... (21-24) Plenty of research has been reported using ionic liquid as solvent to convert cellulose in its homogeneous solution over solid or liquid catalysts, such as conversion of cellulose to 5-hydroxymethylfurfural (HMF) or lactic acid, etc.(25-27) However, the high-cost of ionic liquids and the difficult in recovery and the difficult in reutilization of ionic liquid limit their application in large scale by now. ...

Lifeng Yan; Xiaoya Qi

2014-01-09T23:59:59.000Z

456

Acid mine drainage potential of raw, retorted, and combusted Eastern oil shale: Final report  

SciTech Connect (OSTI)

In order to manage the oxidation of pyritic materials effectively, it is necessary to understand the chemistry of both the waste and its disposal environment. The objective of this two-year study was to characterize the acid production of Eastern oil shale waste products as a function of process conditions, waste properties, and disposal practice. Two Eastern oil shales were selected, a high pyrite shale (unweathered 4.6% pyrite) and a low pyrite shale (weathered 1.5% pyrite). Each shale was retorted and combusted to produce waste products representative of potential mining and energy conversion processes. By using the standard EPA leaching tests (TCLP), each waste was characterized by determining (1) mineralogy, (2) trace element residency, and (3) acid-base account. Characterizing the acid producing potential of each waste and potential trace element hazards was completed with laboratory weathering studies. 32 refs., 21 figs., 12 tabs.

Sullivan, P.J.; Yelton, J.L.; Reddy, K.J.

1987-09-01T23:59:59.000Z

457

from Isotope Production Facility  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Cancer-fighting treatment gets boost from Isotope Production Facility April 13, 2012 Isotope Production Facility produces cancer-fighting actinium 2:32 Isotope cancer treatment...

458

New syntheses of aminoalkylphosphonic acids  

E-Print Network [OSTI]

NEW SYNTHESES OF AMINOALKYLPHOSPHON1C ACIDS A Thesis by John Frederick DeBardeleben, Jr. Su'bmitted to the Graduate School of the Agricultural and Mechanical College of Texas in partial fulfillment of the requirements for the degree of MASTER... OF SCIENCE August 196$ Major Subject: Chemistry NEW SYNTHESES OF AMINOALKYLPHOSPHONIC ACIDS A Thesis BY John Frederick DeBardeleben, Jr. Approved as to style and content hy: (Chairman of Committee) iJ C wc+'. A-c-~-' & (Head of Department...

DeBardeleben, John Frederick

2012-06-07T23:59:59.000Z

459

Fumaric acid: an overlooked form of fixed carbon in Arabidopsis and other plant species  

SciTech Connect (OSTI)

Photoassimilates are used by plants for production of energy, as carbon skeletons and in transport of fixed carbon between different plant organs. Many studies have been devoted to characterizing the factors that. regulate photoassimilate concentrations in different plant species. Most studies examining photoassimilate concentrations in C{sub 3} plants have focused on analyzing starch and soluble sugars. However, work presented here demonstrates that a number of C{sub 3} plants, including the popular model organism Arabidopsis thaliana (L.) Heynh., and agriculturally important plants, such as soybean [Glycine ma (L.) Merr.], contain significant quantities of furnaric acid. In fact, furnaric acid can accumulate to levels of several mg per g fresh weight in A-abidopsis leaves, often exceeding starch and soluble sugar levels. Furnaric acid is a component of the tricarboxylic acid cycle and, like starch and soluble sugars, can be metabolized to yield energy and carbon skeletons for production of other compounds. Fumaric acid concentrations increase with plant age and light intensity in Arabidopsis leaves. Arabidopsis phloem exudates contain significant quantities of fumaric acid, raising the possibility that fumaric acid may function in carbon transport.

Chia, D.W.; Yoder, T.J.; Reiter, W.D.; Gibson, S.I.

2000-10-01T23:59:59.000Z

460

Relation of Soil Nitrogen, Nitrification and Ammonification to Pot Experiments.  

E-Print Network [OSTI]

............................................ 6 Relation of the Crops to the Total Nitrogen of the Soil ........... 7 Relation of the Different Crops ................................. 8 Relation of Surface Soil to Subsoil ............................. 13 Acid Soils Compared with Non-Acid... of Production of Nitrates to the Results of the Pot Ex- periments ................................................ 21 Extensive Work ............................................ 24 Relation of Nitric Nitrogen to Nitrogen Removed by First Crop .... 24...

Fraps, G. S. (George Stronach)

1921-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "nitric acid production" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Nitric Oxideâ??Triggered Remodeling of Chloroplast Bioenergetics and Thylakoid Proteins upon Nitrogen Starvation in Chlamydomonas reinhardtii  

Science Journals Connector (OSTI)

...a most promising source for renewable biofuel production (Wijffels...This process converts these energy-producing membranes into...matrix that dissipates the energy stored in stromal reductants...Microalgae: A green source of renewable H(2). Trends Biotechnol...

Lili Wei; Benoit Derrien; Arnaud Gautier; Laura Houille-Vernes; Alix Boulouis; Denis Saint-Marcoux; Alizée Malnoë; Fabrice Rappaport; Catherine de Vitry; Olivier Vallon; Yves Choquet; Francis-André Wollman

2014-01-28T23:59:59.000Z

462

Kinetic Study on the Acid-Catalyzed Hydrolysis of Cellulose to Levulinic Acid  

Science Journals Connector (OSTI)

A variety of interesting bulk chemicals is accessible by the acid-catalyzed hydrolysis of cellulose. An interesting example is levulinic acid, a versatile precursor for fuel additives, polymers, and resins. A detailed kinetic study on the acid-catalyzed ...

B. Girisuta; L. P. B. M. Janssen; H. J. Heeres

2007-02-13T23:59:59.000Z

463

Fine Root Dynamics and Forest Production Across a Calcium Gradient in Northern Hardwood and Conifer Ecosystems  

Science Journals Connector (OSTI)

Losses of soil base cations due to acid rain have been implicated in declines of red spruce and sugar maple in the northeastern USA. We studied fine root and aboveground biomass and production in five northern ha...

Byung Bae Park; Ruth D. Yanai; Timothy J. Fahey; Scott W. Bailey…

2008-03-01T23:59:59.000Z

464

Removing arsenic from aqueous solution and long-term product storage  

Science Journals Connector (OSTI)

The removal of arsenic from hydrometallurgical solutions, waste waters, and acid drainage mine waters has ... and co-precipitation processes; and, on the long-term outdoor storage of the arsenic bearing products.

L. G. Twidwell; J. W. McCloskey

2011-08-01T23:59:59.000Z

465

Optimization of ethanol production from spent tea waste by Saccharomyces cerevisiae using statistical experimental designs  

Science Journals Connector (OSTI)

The aim of this study was to investigate the prospect for the use of spent tea waste (STW), an important municipal waste, as a potential substrate to generate hydrolysates for fuel ethanol production. Acid pretre...

Yasin Yücel; Sezer Göyc?nc?k

2014-07-01T23:59:59.000Z

466

NETL: Gasification Systems - Advanced Acid Gas Separation Technology for  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Feed Systems Feed Systems Advanced Acid Gas Separation Technology for the Utilization of Low-Rank Coals Project Number: DE-FE0007759 Refinery offgas PSA at Air Products' facility in Baytown, TX Refinery offgas PSA at Air Products' facility in Baytown, TX. Air Products, in collaboration with the University of North Dakota Energy and Environmental Research Center (EERC), is testing its Sour Pressure Swing Adsorption (Sour PSA) process that separates syngas into an hydrogen-rich stream and second stream comprising of sulfur compounds(primarily hydrogen sulfide)carbon dioxide (CO2), and other impurities. The adsorbent technology testing that has been performed to date utilized syngas streams derived from higher rank coals and petcoke. Using data from experiments based on petcoke-derived syngas, replacing the

467

The Path of Carbon in Photosynthesis V. Paper Chromatography and Radioautography of the Products  

DOE R&D Accomplishments [OSTI]

Detailed procedure and results for the separation and identification of labeled carboxylic acids and phosphate esters, formed during photosynthesis in C{sup 14}O{sub 2}; the first observed product of CO{sub 2} assimilation during photosynthesis was isolated and shown to be phosphoglyceric acid; tracer use of P{sup 32} and C{sup 14}.

Benson, A. A.; Bassham, J. A.; Calvin, M.; Goodale, T. C.; Haas, V. A.; Stepka, W.

1949-06-13T23:59:59.000Z

468

Acid Catalysis in Modern Organic  

E-Print Network [OSTI]

catalyst for organic synthesis". That is the starting sentence of this book by Yamamoto and Ishihara, which follows their earlier book "Lewis Acids in Organic Synthesis (2000)", and covers the new developments book that should be available in every well-equipped chemistry library. It will certainly be helpful

Snyder, Scott A.

469

Application of a 3D hydraulic-fracturing simulator for design of acid-fracturing treatments  

SciTech Connect (OSTI)

Field experience during 1989--90 shows that application of a 3D hydraulic-fracturing simulator increases success of acid-fracturing well treatments. Fracture extension can be limited to the oil-bearing pay, maximum lateral extension can be realized within the height constraint, and acid/rock contact time can be increased by a factor of between 3 and 30. Oil-production response can be improved over other stimulation designs while water-production response can be limited. These methods have been applied in mature waterfloods of the Permian Basin and Cedar Creek anticline.

Morgenthaler, L.N. (Shell Development Co., Houston, TX (United States))

1994-02-01T23:59:59.000Z

470

Anaerobic fermentation of rice straw and chicken manure to carboxylic acids  

E-Print Network [OSTI]

biomass (Lynd et al., 2002). Carboxylic acids (C2? C7) are produced from anaerobic fermentation. Because they have a high market value, these acids can be recovered and sold. Alternatively, they can be converted to methane (biogas) or chemicals (e... conditions, both of which contribute heavily to production costs. Zhang and Zhang (1999) studied biogasification of rice straw to produce biogas (CH4 (50%)); however, methane is a low-value product. 1.6 The MixAlco Process An alternative to SSF...

Agbogbo, Frank Kwesi

2007-04-25T23:59:59.000Z

471

RECOVERY OF LACTIC ACID FROM AMERICAN CRYSTAL SUGAR COMPANY WASTEWATER  

SciTech Connect (OSTI)

This project has shown that the recovery of several valuable lactic acid products is both technically feasible and economically viable. One of the original objectives of this project was to recover lactic acid. However, the presence of a variety of indigenous bacteria in the wastewater stream and technical issues related to recovery and purification have resulted in the production of lactic acid esters. These esters could by hydrolyzed to lactic acid, but only with unacceptable product losses that would be economically prohibitive. The developed process is projected to produce approximately 200,000 lb per day of lactate esters from wastewater at a single factory at costs that compete with conventional solvents. The lactate esters are good solvents for polymers and resins and could replace acetone, methyl ethyl ketone, MIBK, and other polar solvents used in the polymer industry. Because of their low volatility and viscosity-lowering properties, they will be especially useful for inks for jet printers, alkyl resins, and high-solid paints. Owing to their efficiency in dissolving salts and flux as well as oils and sealants, lactate esters can be used in cleaning circuit boards and machine and engine parts. Unlike conventional solvents, lactate esters exhibit low toxicity, are biodegradable, and are not hazardous air pollutants. Another application for lactate esters is in the production of plasticizers. Severe health problems have been attributed to widely used phthalate ester plasticizers. The U.S. Department of Agriculture showed that replacement of these with inexpensive lactate esters is feasible, owing to their superior polymer compatibility properties. A very large market is projected for polymers prepared from lactic acid. These are called polylactides and are a type of polyester. Thermoplastics of this type have a variety of uses, including moldings, fibers, films, and packaging of both manufactured goods and food products. Polylactides form tough, orientable, self-supporting thin films and have, therefore, been used for adhesives, safety glass, and finishes. If the bacterial culture produces the L-lactic acid enanatiomer form exclusively, the L-lactide prepared from this form can be used for making polymers with good fiber-forming properties. We have not currently achieved the exclusive production of L-lactate in our efforts. However, markets in films and structural shapes are available for polymers and copolymers prepared from the mixed D,L-lactide forms that result from processing the D,L-lactic acid obtained from fermentation such as that occurring naturally in sugar beet wastewater. These materials are slowly biodegraded to harmless compounds in the environment, and they burn with a clean blue flame when incinerated. These materials represent excellent opportunities for utilization of the D,L-lactic mixture produced from natural fermentation of the ACS flume water. Esters can be converted into a lactide, and the alcohol released from the ester can be recycled with no net consumption of the alcohol. Lactide intermediates could be produced locally and shipped to polymer producers elsewhere. The polymer and copolymer markets are extremely large, and the role of lactides in these markets is continuously expanding. The overall process can be readily integrated into existing factory wastewater operations. There are several environmental benefits that would be realized at the factories with incorporation of the lactate recovery process. The process reduces the organic loading to the existing wastewater treatment system that should result in enhanced operability with respect to both solids handling and treated-water quality. A higher-quality treated water will also help reduce odor levels from holding ponds. Several water reuse opportunities are probable, depending on the quality of treated water from the FT process.

Daniel J. Stepan; Edwin S. Olson; Richard E. Shockey; Bradley G. Stevens; John R. Gallagher

2001-04-30T23:59:59.000Z

472

By-Products Utilization  

E-Print Network [OSTI]

Center for By-Products Utilization PROPERTIES OF CONCRETE CONTAINING SCRAP TIRE RUBBER in a variety of rubber and plastic products, thermal incineration of waste tires for production of electricity rubber in asphalt mixes, (ii) thermal incineration of worn-out tires for the production of electricity

Wisconsin-Milwaukee, University of

473

E-Print Network 3.0 - acid linoleic acid Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

FAs (linolenic, linoleic) - - monounsaturated FAs (oleic acid) - olive, canola - hydrogenation... Biol 458 Lecture 6 & 7 Fatty Acids 1 A. Introduction to acyl lipids...

474

Advanced Lead Acid Battery Consortium | Open Energy Information  

Open Energy Info (EERE)

Lead Acid Battery Consortium Lead Acid Battery Consortium Jump to: navigation, search Name Advanced Lead-Acid Battery Consortium Place Durham, North Carolina Zip 27713 Sector Vehicles Product The ALABC is a research consortium of more than 50 battery-related companies that was originally formed in 1992 to advance the capabilities of the valve-regulated lead acid battery to help electric vehicles become a reality. Coordinates 45.396265°, -122.755099° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":45.396265,"lon":-122.755099,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

475

Succinic Acid as a Byproduct in a Corn-based Ethanol Biorefinery  

SciTech Connect (OSTI)

MBI endeavored to develop a process for succinic acid production suitable for integration into a corn-based ethanol biorefinery. The project investigated the fermentative production of succinic acid using byproducts of corn mill operations. The fermentation process was attuned to include raw starch, endosperm, as the sugar source. A clean-not-sterile process was established to treat the endosperm and release the monomeric sugars. We developed the fermentation process to utilize a byproduct of corn ethanol fermentations, thin stillage, as the source of complex nitrogen and vitamin components needed to support succinic acid production in A. succinogenes. Further supplementations were eliminated without lowering titers and yields and a productivity above 0.6 g l-1 hr-1was achieved. Strain development was accomplished through generation of a recombinant strain that increased yields of succinic acid production. Isolation of additional strains with improved features was also pursued and frozen stocks were prepared from enriched, characterized cultures. Two recovery processes were evaluated at pilot scale and data obtained was incorporated into our economic analyses.

MBI International

2007-12-31T23:59:59.000Z

476

Lighting Up Enzymes for Solar Hydrogen Production (Fact Sheet)  

SciTech Connect (OSTI)

Scientists at the National Renewable Energy Laboratory (NREL) have combined quantum dots, which are spherical nanoparticles that possess unique size-tunable photophysical properties, with the high substrate selectivity and fast turnover of hydrogenase enzymes to achieve light-driven hydrogen (H2) production. They found that quantum dots of cadmium telluride coated in carboxylic acids easily formed highly stable complexes with the hydrogenase and that these hybrid assemblies functioned to catalyze H2 production using the energy of sunlight.

Not Available

2011-02-01T23:59:59.000Z

477

Hydrogen and Sulfur Production from Hydrogen Sulfide Wastes  

E-Print Network [OSTI]

HYDROGEN AND SULFUR PRODUCTION FROM HYDROGEN SULFIDE WASTES? John B.L. Harkness and Richard D. Doctor, Argonne National Laboratory, Argonne. IL ABSTRACT A new hydrogen sulfide waste-treatment process that uses microwave plasma... to be economically competitive. In addition, the experiments show-that. typical refinery acid-gas streams are compatible with the plasma process and that all by-products can be treated with existing technology. BACKGROUND In 1987, Argonne staff found the first...

Harkness, J.; Doctor, R. D.

478

Hydrogen (H2) Production by Oxygenic Phototrophs  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Production by Oxygenic Phototrophs Eric L. Hegg Michigan State University Great Lakes Bioenergy Research Center Bioresour. Technol. 2011, 102, 8589-8604 Major Challenges to H 2 Photoproduction Biological Challenges * Poor efficiency of H 2 production * Poor heterologous expression of H 2 -forming enzymes * Low quantum yields * Competition for reducing equivalents; poor electron coupling * Sensitivity of H 2 -forming enzymes to O 2 M. Ghirardi, Abstract #1751, Honolulu PRiME 2012 Technical Challenges * Mixture of H 2 and O 2 ; H 2 separation and storage * CO 2 addition and overall reactor design Overcoming Low Efficiency: Improving ET * Eliminate or down-regulate pathways competing for ele * Production of organic acids * Formation of NADPH/carbon fixation

479

Studies On Advanced Lead-Acid Batteries.  

E-Print Network [OSTI]

??Subsequent to the studies on precursor lead-acid systems by Daniel, Grove and Sindesten, practical lead-acid batteries began with the research and inventions of Raymond Gaston… (more)

Martha, Surendra Kumar

2005-01-01T23:59:59.000Z

480

Modeling of Acid Fracturing in Carbonate Reservoirs  

E-Print Network [OSTI]

The acid fracturing process is a thermal, hydraulic, mechanical, and geochemical (THMG)-coupled phenomena in which the behavior of these variables are interrelated. To model the flow behavior of an acid into a fracture, mass and momentum balance...

Al Jawad, Murtada s

2014-06-05T23:59:59.000Z

Note: This page contains sample records for the topic "nitric acid production" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

Nitric Oxide and Oxygen Radical Attack on GDP-Dissociation Inhibitor 2 (GDI-2) in Spinal Cord Injury of the Rat  

Science Journals Connector (OSTI)

Nitric Oxide and Oxygen Radical Attack on GDP-Dissociation Inhibitor 2 (GDI-2) in Spinal Cord Injury of the Rat ... Herein, mass spectrometry unambiguously identified GDP-dissociation inhibitor-2 (GDI-2) in SCI with post-translational modifications of 3-aminotyrosine (8 h post-injury) and an acrolein adduct of GDI-2 (72 h post-injury). ... Protein profiling in SCI of the rat revealed that, at 8 h following the traumatic lesion, levels of a signalling protein, GDP-dissociation inhibitor-2 protein (GDI-2) (synonym:? Rab GDP dissociation inhibitor beta), were increased about 3-fold, and we therefore decided to use this potentially important signalling structure to study the presence of oxidation- and nitration-induced PTMs in SCI. ...

Julius Paul Pradeep John; Oliver Pintsov; Alexander Petter-Puchner; Heinz Redl; Arnold Pollak; Wei-Qiang Chen; Gert Lubec

2007-02-22T23:59:59.000Z

482

Toward Zero Carbon Energy Production Toward Zero Carbon Energy Production  

E-Print Network [OSTI]

#12;Toward Zero Carbon Energy Production Toward Zero Carbon Energy Production Toward Zero Carbon Energy Production Toward Zero Carbon Energy Production Toward Zero Carbon Energy Production Toward Zero Carbon Energy Production Toward Zero Carbon Energy Production Toward Zero Carbon Energy Production Toward

Narasayya, Vivek

483

Chemical Additive Selection in Matrix Acidizing  

E-Print Network [OSTI]

critical detail of weak acid chemistry. One concern when using any acid in oilfield operations is the corrosion of well tubulars. Thus operators often choose to pump corrosion inhibitor, a chemical additive electrostatically attracted... in oilfield operations, each of which protects well tubulars using the same mechanism: by impeding the acid?s ability to diffuse to the tubing surface. Because of the unique attraction of corrosion inhibitor to the metal surface, and the corrosion inhibitor...

Weidner, Jason 1981-

2011-05-09T23:59:59.000Z

484

Sandia National Laboratories: Due Diligence on Lead Acid Battery...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Due Diligence on Lead Acid Battery Recycling March 23, 2011 Lead Acid Batteries on secondary containment pallet Lead Acid Batteries on secondary containment pallet In 2004, the US...

485

Hydrogen-Bond Acidic Polymers for Chemical Vapor Sensing. | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Acidic Polymers for Chemical Vapor Sensing. Hydrogen-Bond Acidic Polymers for Chemical Vapor Sensing. Abstract: A review with 171 references. Hydrogen-bond acidic polymers for...

486

Unnatural reactive amino acid genetic code additions  

DOE Patents [OSTI]

This invention provides compositions and methods for producing translational components that expand the number of genetically encoded amino acids in eukaryotic cells. The components include orthogonal tRNAs, orthogonal aminoacyl-tRNA synthetases, orthogonal pairs of tRNAs/synthetases and unnatural amino acids. Proteins and methods of producing proteins with unnatural amino acids in eukaryotic cells are also provided.

Deiters, Alexander; Cropp, T. Ashton; Chin, Jason W.; Anderson, J. Christopher; Schultz, Peter G.

2014-08-26T23:59:59.000Z

487

Bio-Based Product Basics | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Bio-Based Product Basics Bio-Based Product Basics Bio-Based Product Basics August 14, 2013 - 1:19pm Addthis Almost all of the products we currently make from fossil fuels can also be made from biomass. These bioproducts, or bio-based products, are not only made from renewable sources, but they also often require less energy to produce than petroleum-based ones. Researchers have discovered that the process for making biofuels also can be used to make antifreeze, plastics, glues, artificial sweeteners, and gel for toothpaste. Other important building blocks for bio-based products are carbon monoxide and hydrogen. When biomass is heated with a small amount of oxygen, these two gases are produced in abundance. Scientists call this mixture biosynthesis gas. Biosynthesis gas can be used to make plastics and acids,

488

Bio-Based Product Basics | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Bio-Based Product Basics Bio-Based Product Basics Bio-Based Product Basics August 14, 2013 - 1:19pm Addthis Almost all of the products we currently make from fossil fuels can also be made from biomass. These bioproducts, or bio-based products, are not only made from renewable sources, but they also often require less energy to produce than petroleum-based ones. Researchers have discovered that the process for making biofuels also can be used to make antifreeze, plastics, glues, artificial sweeteners, and gel for toothpaste. Other important building blocks for bio-based products are carbon monoxide and hydrogen. When biomass is heated with a small amount of oxygen, these two gases are produced in abundance. Scientists call this mixture biosynthesis gas. Biosynthesis gas can be used to make plastics and acids,

489

Two Dimensional Polyamides Prepared From Unsaturated Carboxylic Acids And Amines.  

DOE Patents [OSTI]

A polyamide and a process for preparing the polyamide are disclosed. The process comprises reacting in a reaction mixture a monomer selected from unsaturated carboxylic acids, esters of unsaturated carboxylic acids, anhydrides of unsaturated carboxylic acids, and mixtures thereof, and a first amine to form an intermediate reaction product in the reaction mixture, wherein the first amine is selected from RR.sub.1 NH, RNH.sub.2, RR.sub.1 NH.sub.2.sup.+, RNH.sub.3.sup.+ and mixtures thereof, wherein R and R.sub.1 can be the same or different and each contain between about 1 and 50 carbon atoms and are optionally substituted with heteroatoms oxygen, nitrogen, sulfur, and phosphorus and combinations thereof, and reacting the intermediate reaction product and a second amine to form a polyamide, wherein the second amine is selected from R.sub.2 R.sub.3 NH, R.sub.2 NH.sub.2, R.sub.2 R.sub.3 NH.sub.2.sup.+, R.sub.2 NH.sub.3.sup.+ and mixtures thereof wherein R.sub.2 and R.sub.3 can be the same or different and each contain between about 1 and 50 carbon atoms and are optionally substituted with heteroatoms oxygen, nitrogen, sulfur, and phosphorus and combinations thereof, wherein multiple of the R, R.sub.1, R.sub.2, and R.sub.3 are in vertically aligned spaced relationship along a backbone formed by the polyamide. In one version of the invention, the monomer is selected from maleic anhydride, maleic acid esters, and mixtures thereof. In another version of the invention, the first amine is an alkylamine, such as tetradecylamine, and the second amine is a polyalkylene polyamine, such as pentaethylenehexamine. In yet another version of the invention, the first amine and the second amine are olefinic or acetylenic amines, such as the reaction products of an alkyldiamine and an acetylenic carboxylic acid. The first amine and the second amine may be the same or different depending on the desired polyamide polymer structure.

McDonald, William F. (Utica, OH); Huang, Zhi Heng (East Lansing, MI); Wright, Stacy C. (Lansing, MI); Danzig, Morris (Northbrook, IL); Taylor, Andrew C. (Ann Arbor, MI)

2002-07-17T23:59:59.000Z

490

Myricetin inhibits matrix metalloproteinase 2 protein expression and enzyme activity in colorectal carcinoma cells  

Science Journals Connector (OSTI)

...involvement of caspase 3 activation, p21 gene...activation of the caspase 3 cascade and production...lipopolysaccharide-induced nitric oxide production by flavonoids...isoforms alpha and epsilon on gastric acid secretion...epigallocatechin-3-gallate. Cancer...of flavonoids with iron and copper ions...

Ching-Huai Ko; Shing-Chuan Shen; Tony J.F. Lee; and Yen-Chou Chen

2005-02-01T23:59:59.000Z

491

FCT Hydrogen Production: Basics  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Basics to someone by E-mail Basics to someone by E-mail Share FCT Hydrogen Production: Basics on Facebook Tweet about FCT Hydrogen Production: Basics on Twitter Bookmark FCT Hydrogen Production: Basics on Google Bookmark FCT Hydrogen Production: Basics on Delicious Rank FCT Hydrogen Production: Basics on Digg Find More places to share FCT Hydrogen Production: Basics on AddThis.com... Home Basics Central Versus Distributed Production Current Technology R&D Activities Quick Links Hydrogen Delivery Hydrogen Storage Fuel Cells Technology Validation Manufacturing Codes & Standards Education Systems Analysis Contacts Basics Photo of hydrogen production in photobioreactor Hydrogen, chemical symbol "H", is the simplest element on earth. An atom of hydrogen has only one proton and one electron. Hydrogen gas is a diatomic

492

MODIS Land Products Subsets  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

MODIS ASCII Subset Products - FTP Access MODIS ASCII Subset Products - FTP Access All of the MODIS ASCII Subsets are available from the ORNL DAAC's ftp site. The directory structure of the ftp site is based on the abbreviated names for the MODIS Products. Terra MODIS products are abbreviated "MOD", Aqua MODIS products are abbreviated "MYD" and combined Terra and Aqua MODIS products are abbreviated "MCD". The abbreviated names also include the version number (also known as collection). For specific products, please refer to the following table: Product Acronym Spatial Resolution Temporal Frequency Terra V005 SIN Aqua V005 SIN Terra/Aqua Combined V005 SIN Surface Reflectance SREF 500 m 8 day composites MOD09A1 MYD09A1 ---------- Land Surface Temperature and Emissivity TEMP 1 km 8 day composites MOD11A2 MYD11A2 ----------

493

Hydrogen Production- Current Technology  

Broader source: Energy.gov [DOE]

The development of clean, sustainable, and cost-competitive hydrogen production processes is key to a viable future clean energy economy. Hydrogen production technologies fall into three general...

494

State Energy Production Estimates  

U.S. Energy Information Administration (EIA) Indexed Site

State Energy Production Estimates 1960 Through 2012 2012 Summary Tables Table P1. Energy Production Estimates in Physical Units, 2012 Alabama 19,455 215,710 9,525 0 Alaska 2,052...

495

MODIS Land Product Subsets  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Validation > MODIS Land Subsets Validation > MODIS Land Subsets MODIS Land Product Subsets Overview Earth, Western Hemisphere The goal of the MODIS Land Product Subsets project is to provide summaries of selected MODIS Land Products for the community to use for validation of models and remote-sensing products and to characterize field sites. Output files contain pixel values of MODIS land products in text format and in GeoTIFF format. In addition, data visualizations (time series plots and grids showing single composite periods) are available. MODIS Land Product Subsets Resources The following MODIS Land Product Subsets resources are maintained by the ORNL DAAC: MODIS Land Products Offered Background Citation Policy Methods and formats MODIS Sinusoidal Grid - Google Earth KMZ Classroom Exercises

496

Iron oxide and chromia supported on titania-pillared clay for selective catalytic reduction of nitric oxide with ammonia  

SciTech Connect (OSTI)

TiO{sub 2}-pillard clay (PILC) with high surface area, large pore volume, and large interlayer spacing was used as the support for mixed Fe{sub 2}O{sub 3} and Cr{sub 2}O{sub 3} as the catalyst for selective catalytic reduction (SCR) of NO with NH{sub 3}. The Fe/Cr ratio was varied at a fixed total amount of oxide dopant of 10% (wt). The Fe-Cr/TiO{sub 2}-PILC with Fe/Cr=3 showed the highest activity. Compared with commercial V{sub 2}O{sub 5}/TiO{sub 2} catalysts, the activity (on a per gram basis) of the doped pillared clay was approximately twice as high under H{sub 2}O- and SO{sub 2}-free conditions and was approximately 40% higher under conditions with H{sub 2}O and SO{sub 2}. In addition, its activity for SO{sub 2} oxidation was only 20%-25% of that of the V{sub 2}O{sub 5}-based catalysts. TPD of NH{sub 3} on the Fe-Cr/TiO{sub 2}-PILC catalyst showed that both M=O and M-OH (M=Fe or Cr) were necessary for the SCR reaction. In situ IR spectra of NH{sub 3} showed that there was a higher Bronsted acidity than the Lewis acidity on the surface under reaction conditions and that there existed a direct correlation between the SCR activity and the Bronsted acidity among pillared clays with different Fe/Cr ratios. These results, along with the transient response to O{sub 2}, indicated that a similar mechanism to that on the V{sub 2}O{sub 5} catalyst was operative. The TiO{sub 2}-pillared clay used as the support also contributed to the high activity of the Fe-Cr catalyst. The TiO{sub 2} pillars combined with the tetrahedral SiO{sub 2} surfaces of the clay apparently gave rise to a high dispersion of Fe{sub 2}O{sub 3}. 52 refs., 10 figs., 5 tabs.

Cheng, L.S.; Yang, R.T. [State Univ. of New York, Buffalo, NY (United States)] [State Univ. of New York, Buffalo, NY (United States); Ning Chen [Univ. of Michigan, Ann Arbor, MI (United States)] [Univ. of Michigan, Ann Arbor, MI (United States)

1996-11-01T23:59:59.000Z

497

Lord Justice of Appeal John Fletcher Moulton and explosives production in World War I: ‘the mathematical mind triumphant’  

Science Journals Connector (OSTI)

...total British prewar toluene production. When gas companies distilled...guncotton is weighed into an India rubber bag. The required volume...30 Unforeseen snags delayed production, so A6 filled the gap by...and expanding picric acid production. 37 Enough nitrate was available...

2014-01-01T23:59:59.000Z

498

MECS 2006- Forest Products  

Broader source: Energy.gov [DOE]

Manufacturing Energy and Carbon Footprint for Forest Products (NAICS 321, 322) Sector with Total Energy Input, October 2012 (MECS 2006)

499

Conversion of carboxylate salts to carboxylic acids via reactive distillation  

E-Print Network [OSTI]

biomass used in this study . . . 1-2 Approxitnate annual production and spot selling price of various carboxylic acids. 1-3 Names used for biomass feedstocks. . 1-4 2-1 Sample processing. Rinsing scheme for precipitated solids. 12 3-1 Concentration... fermentation broth derived trom various wastes. Table 1-4 describes the studies performed for each fermentation broth, as well as reagent-grade chemicals. Table 1-3. Names used for biomass feedstocks. Sample Name MSW1 MSW2 MSW3 MSW4 MSWS PF/Biol PF...

Williamson, Shelly Ann

2012-06-07T23:59:59.000Z

500

By-Products Utilization  

E-Print Network [OSTI]

Fellow at the UWM-CBU. His research interests include the use of coal fly ash, coal bottom ash, and usedCenter for By-Products Utilization USE OF UNDER-UTILIZED COAL- COMBUSTION PRODUCTS IN PERMEABLE-Utilized Coal-Combustion Products in Permeable Roadway Base Construction 1 (MS #LV-R67) Use of Under

Wisconsin-Milwaukee, University of