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Note: This page contains sample records for the topic "nitric acid cxs" from the National Library of EnergyBeta (NLEBeta).
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1

Separation of americium and europium from solutions of nitric and perchloric acid using dipicolinic acid diamides  

Science Journals Connector (OSTI)

Extraction of nitric acid, perchloric acid, americium, and europium with dialkyldiarylamides of 2,6-pyridinecarboxylic (dipicolinic) acid in polar fluorinated solvents (diluents) was analysed. Among the extrac...

M.Yu. Alyapyshev; V. A. Babain; I. V. Smirnov…

2006-01-01T23:59:59.000Z

2

Separation of americium and europium from solutions of nitric and perchloric acid using dipicolinic acid diamides  

Science Journals Connector (OSTI)

Extraction of nitric acid, perchloric acid, americium, and europium with dialkyldiarylamides of 2,6-pyridinecarboxylic (dipicolinic) acid in polar fluorinated solvents (diluents) was analysed. Among the extrac...

M. Yu. Alyapyshev; V. A. Babain; I. V. Smirnov…

2006-12-01T23:59:59.000Z

3

EFFECTS OF NITRIC ACID ON CRITICALITY SAFETY ANALYSIS  

SciTech Connect

As nitric acid molarity is increased, there are two competing phenomena affecting the reactivity of the system. First, there is interaction between each of the 10 wells in the basket-like insert. As the molarity of the nitric acid solution is increased (it moves from 100% water to 100% HNO{sub 3}), the hydrogen atom density decreases by about 80%. However, it remains a relatively efficient moderator. The moderating ratio of nitric acid is about 90% that of water. As the media between the wells is changed from 100% water to 100% nitric acid, the density of the media increases by 50%. A higher density typically leads to a better reflector. However, when the macroscopic scattering cross sections are considered, nitric acid is a much worse reflector than water. The effectiveness of nitric acid as a reflector is about 40% that of water. Since the media between the wells become a worse reflector and still remains an effective moderator, interaction between the wells increases. This phenomenon will cause reactivity to increase as nitric acid molarity increases. The seond phenomenon is due to the moderating ratio changing in the high concentration fissile-nitric acid solution in the 10 wells. Since the wells contain relatively small volumes of high concentration solutions, a small decrease in moderating power has a large effect on reactivity. This is due to the fact that neutrons are more likely to escape the high concentration fissile solution before causing another fission event. The result of this phenomenon is that as nitric acid molarity increases, reactivity decreases. Recent studies have shown that the second phenomenon is indeed the dominating force in determining reactivity changes in relation to nitric acid molarity changes. When considering the system as a whole, as nitric acid molarity increases, reactivity decreases.

Williamson, B.

2011-08-18T23:59:59.000Z

4

Extraction of nitric acid, uranyl nitrate, and bismuth nitrate from aqueous nitric acid solutions with CMPO  

SciTech Connect

DOE sponsored development of the transuranium extraction (TRUEX) process for removing actinides from radioactive wastes. The solvent is a mixture of CMPO and TBP. Since the extraction characteristics of CMPO are not as well understood as those of TBP, the extraction of nitric acid, uranyl nitrate, and bismuth nitrate with CMPO (dissolved in n-dodecane) were studied. Results indicate that CMPO extracts nitric acid with a 1:1 stoichiometry; equilibrium constant is 2. 660{plus_minus}0.092 at 25 C, and extraction enthalpy is -5. 46{plus_minus}0.46 kcal/mol. Slope analysis indicates that uranyl nitrate extracts with a mixed equilibria of 1:1 and 2:1 stoichiometries in nearly equal proportion. Equil. constant of the 2: 1 extraction was 1.213 {times} 10{sup 6}{plus_minus}3.56 {times} 10{sup 4} at 25 C; reaction enthalpy was -9.610{plus_minus}0.594 kcal/mol. Nitration complexation constant is 8.412{plus_minus}0.579, with an enthalpy of -10.72{plus_minus}1.87 kcal/mol. Bismuth nitrate also extracts with a mixed equilibria of (perhaps) 1:1 and 2:1 stoichiometries. A 2:1 extraction equilibrium and a nitrate complexation adequately model the data. Kinetics and enthalpies were also measured.

Spencer, B.B.

1995-08-01T23:59:59.000Z

5

Mercury-free dissolution of aluminum-clad fuel in nitric acid  

DOE Patents (OSTI)

A mercury-free dissolution process for aluminum involves placing the aluminum in a dissolver vessel in contact with nitric acid-fluoboric acid mixture at an elevated temperature. By maintaining a continuous flow of the acid mixture through the dissolver vessel, an effluent containing aluminum nitrate, nitric acid, fluoboric acid and other dissolved components are removed.

Christian, Jerry D. (Idaho Falls, ID); Anderson, Philip A. (Pocatello, ID)

1994-01-01T23:59:59.000Z

6

Extraction of antimony from nitric acid solutions using tributyl phosphate. I. Tributyl phosphate-antimony(III)-nitric acid system  

SciTech Connect

Experimental data have been reported concerning the extraction of trivalent antimony from nitric acid solutions using tributyl phosphate (TBP). A possible mechanism for the extraction of antimony(III) has been determined and the (pre)concentration constant for the process has been calculated. The effect of temperature on trivalent antimony extraction has also been evaluated. The enthalpy value and standard isobar potential and entropy for this process have been determined.

Lakaev, V.S.; Smelov, V.S.

1989-01-01T23:59:59.000Z

7

Extraction of antimony from nitric acid solutions using tributyl phosphate. II. Tributyl phosphate-antimony(V)-nitric acid system  

SciTech Connect

The extraction of pentavalent antimony from nitric acid solutions using tributyl phosphate has been investigated. A possible mechanism for the extraction of antimony(V) has been determined and the (pre)concentration constant for the process has been calculated. The composition of the extracted antimony(V) complex has been deduced. A negative effect of temperature on the distribution coefficient for antimony(V) has also been demonstrated.

Lakaev, V.S.; Smelov, V.S.

1989-01-01T23:59:59.000Z

8

Nitric-phosphoric acid oxidation of organic waste materials  

SciTech Connect

A wet chemical oxidation technology has been developed to address issues facing defense-related facilities, private industry, and small-volume generators such as university and medical laboratories. Initially tested to destroy and decontaminate a heterogenous mixture of radioactive-contaminated solid waste, the technology can also remediate other hazardous waste forms. The process, unique to Savannah River, offers a valuable alternative to incineration and other high-temperature or high-pressure oxidation processes. The process uses nitric acid in phosphoric acid; phosphoric acid allows nitric acid to be retained in solution well above its normal boiling point. The reaction converts organics to carbon dioxide and water, and generates NO{sub x} vapors which can be recycled using air and water. Oxidation is complete in one to three hours. In previous studies, many organic compounds were completely oxidized, within experimental error, at atmospheric pressure below 180{degrees}C; more stable compounds were decomposed at 200{degrees}C and 170 kPa. Recent studies have evaluated processing parameters and potential throughputs for three primary compounds: EDTA, polyethylene, and cellulose. The study of polyvinylchloride oxidation is incomplete at this time.

Pierce, R.A.; Smith, J.R.

1995-11-01T23:59:59.000Z

9

Use of extractive distillation to produce concentrated nitric acid  

SciTech Connect

Concentrated nitric acid (> 95 wt %) is needed for the treatment of off-gases from a fuels-reprocessing plant. The production of concentrated nitric acid by means of extractive distillation in the two-pot apparatus was studied to determine the steady-state behavior of the system. Four parameters, EDP volume (V/sub EDP/) and temperature (T/sub EDP/), acid feed rate, and solvent recycle, were independently varied. The major response factors were percent recovery (CPRR) and product purity (CCP). Stage efficiencies also provided information about the system response. Correlations developed for the response parameters are: CPRR = 0.02(V/sub EDP/ - 800 cc) + 53.5; CCP = -0.87 (T/sub EDP/ - 140/sup 0/C) + 81; eta/sub V,EDP/ = 9.1(F/sub feed/ - 11.5 cc/min) - 0.047(V/sub EDP/ - 800 cc) - 2.8(F/sub Mg(NO/sub 3/)/sub 2// - 50 cc/min) + 390; and eta/sub L,EDP/ = 1.9(T/sub EDP/ - 140/sup 0/C) + 79. A computer simulation of the process capable of predicting steady-state conditions was developed, but it requires further work.

Campbell, P.C.; Griffin, T.P.; Irwin, C.F.

1981-04-01T23:59:59.000Z

10

Chemistry of tributyl phosphate and nitric acid at constant volume  

SciTech Connect

This paper addresses the reaction of tributyl phosphate (TBP) with nitric acid (HNO{sub 3}). The reaction pressure of TBP/HNO{sub 3} mixtures as a function of time was measured under constant volume. A simplified model, which parametrically includes autocatalysis, was used to plot the total gas production of the reaction as a function of time. Comparison of the functions shows a rough equivalence in the induction time, reaction time, and total gas production. Predictions of the amounts of reaction products as a function of time were made based on assumptions regarding autocatalysis and using rate constants from experimental data. The derived reaction mechanisms and experimental results have several implications. Tests with a large amount of venting and high surface to volume ratio will show very different behavior than tests with increasing confinement and low surface to volume ratios. The amount alkyl nitrate, carbon monoxide, or hydrogen that reacts within the organic phase is limited by their solubilities and volatilities. The overall yield of both heat and gas per mol of nitric acid or TBP will vary significantly depending on the amount of solution, free volume, and vessel vent capacity.

Agnew, S.F.; Eisenhawer, S.W.; Morris, J.S. [Los Alamos National Lab., NM (United States)

1995-12-31T23:59:59.000Z

11

Analysis of Steam Heating of a Two-Layer TBP/N-Paraffin/Nitric Acid Mixtures  

SciTech Connect

This report presents an analysis of steam heating of a two-layer tri-n-butyl phosphate (TBP)/n-paraffin-nitric acid mixture.The purpose of this study is to determine if the degree of mixing provided by the steam jet or by bubbles generated by the TBP/nitric acid reaction is sufficient to prevent a runaway reaction.

Laurinat, J.E. [Westinghouse Savannah River Company, AIKEN, SC (United States); Hassan, N.M.; Rudisill, T.S.; Askew, N.M.

1998-07-22T23:59:59.000Z

12

Effect of the TBP and Water on the Complexation of Uranyl Nitrate and the Dissolution of Nitric Acid into Supercritical CO2. A Theoretical Study  

E-Print Network (OSTI)

started from "random" mixtures of water, TBP, nitric acid, and uranyl nitrate, complexation of uranyl to dissolve nitric acid in the supercritical phase. Indeed, without TBP, nitric acid alone self aggregates via containing the acid and uranyl salts. The simulations show that a high TBP/nitric acid ratio is needed

Boyer, Edmond

13

Scandium nitrate-nitric acid-water-tributyl phosphate system. III. IR spectra of scandium extracts from concentrated nitric acid solutions  

SciTech Connect

Equilibrium organic phases in extraction systems consisting of tributyl phosphate (TBP) (neat or 1 M in CCl{sub 4}) and 8-12 M nitric acid containing scandium or scandium-free have been studied by IR spectroscopy. Extracted complex contains 3, 4, or 5 nitric acid molecules per Sc atom in the case of extraction from 8.3, 10.9, and 12.2 M HNO{sub 3}, respectively, and corresponds to the formula Sc(NO{sub 3}){sub 3}{center_dot}mHNO{sub 3}{center_dot}3TBP. Nitric acid molecules are incorporated into extracted complex via H-bond between oxygen atom of coordinated nitrate ion and acid proton.

Nikitina, G.P.; Egorova, V.P.; Listopadov, A.A. [Khlopin Radium Institute, St. Petersburg (Russian Federation)] [and others

1995-03-01T23:59:59.000Z

14

Features of gadolinium and ytterbium extraction by tributyl phosphate from concentrated nitric acid solutions. I. Compositions of extracted complexes  

SciTech Connect

Distribution of macroquantity (0.3-1.3 M) of Gd and Yb between neat tri-n-butyl phosphate (TBP) and 5-12 M nitric acid solutions has been studied. The species extracted by TBP from 7-12 M nitric acid solutions are rare-earth metal (REM) nitrate trisolvates containing one or several nitric molecules.

Nikitna, G.P.; Seredkina, N.V.; Listopadov, A.A. [Khlopin Radium Institute, St. Petersburg (Russian Federation)

1995-01-01T23:59:59.000Z

15

Amino acids, polyamines, and nitric oxide synthesis in the ovine conceptus  

E-Print Network (OSTI)

The objective of this study was to determine concentrations of amino acids and polyamines as well as nitric oxide (NO) and polyamine synthesis in the ovine conceptus (embryo/fetal and associated placental membrane). Ewes were hysterectomized...

Kwon, Hyuk Jung

2005-08-29T23:59:59.000Z

16

THE SYSTEM THORIUM NITRATE-WATER-NITRIC ACID AT 25 AND THE HYDRATES...  

Office of Scientific and Technical Information (OSTI)

SYSTEM THORIUM NITRATE-WATER-NITRIC ACID AT 25 AND THE HYDRATES OF THORIUM NITRATE Re-direct Destination: Temp Data Fields Ferraro, J.R.; Katzin, L.I. Temp Data Storage 3: Argonne...

17

Isothermal heat measurements of TBP-nitric acid solutions  

SciTech Connect

Net heats of reaction were measured in an isothermal calorimeter for TBP/HNO{sub 3} solutions at ambient pressure and temperatures above 100{degrees}C. Carbon and nitrogen balances were performed giving the reaction stoichiometry. Rate expressions were derived and rate constants determined for both the single and two phase systems which included mass lost from the reacting system by evaporation. This mathematical model was fit to the experimental data (including the measured net heat and off-gas rate) gathered over a wide range of conditions. The oxidation rate constant was determined to be 5.4E-4 min{sup -1} at 110{degrees}C for an open {open_quotes}vented{close_quotes} system as compared to >1E-3min{sup -1} in a closed system. The heat released per unit material oxidized was also reduced due to a decrease in dissolved oxidants and an inefficient reduction of HNO{sub 3}. Oxidation in the organic phase was found to be first order in nitric acid and pseudo-zero order in butylnitrate and water.

Smith, J.R.; Cavin, W.S. [Westinghouse Savannah River Company, Aiken, SC (United States)

1995-12-31T23:59:59.000Z

18

Laboratory studies of 2H evaporator scale dissolution in dilute nitric acid  

SciTech Connect

The rate of 2H evaporator scale solids dissolution in dilute nitric acid has been experimentally evaluated under laboratory conditions in the SRNL shielded cells. The 2H scale sample used for the dissolution study came from the bottom of the evaporator cone section and the wall section of the evaporator cone. The accumulation rate of aluminum and silicon, assumed to be the two principal elemental constituents of the 2H evaporator scale aluminosilicate mineral, were monitored in solution. Aluminum and silicon concentration changes, with heating time at a constant oven temperature of 90 deg C, were used to ascertain the extent of dissolution of the 2H evaporator scale mineral. The 2H evaporator scale solids, assumed to be composed of mostly aluminosilicate mineral, readily dissolves in 1.5 and 1.25 M dilute nitric acid solutions yielding principal elemental components of aluminum and silicon in solution. The 2H scale dissolution rate constant, based on aluminum accumulation in 1.5 and 1.25 M dilute nitric acid solution are, respectively, 9.21E-04 ± 6.39E-04 min{sup -1} and 1.07E-03 ± 7.51E-05 min{sup -1}. Silicon accumulation rate in solution does track the aluminum accumulation profile during the first few minutes of scale dissolution. It however diverges towards the end of the scale dissolution. This divergence therefore means the aluminum-to-silicon ratio in the first phase of the scale dissolution (non-steady state conditions) is different from the ratio towards the end of the scale dissolution. Possible causes of this change in silicon accumulation in solution as the scale dissolution progresses may include silicon precipitation from solution or the 2H evaporator scale is a heterogeneous mixture of aluminosilicate minerals with several impurities. The average half-life for the decomposition of the 2H evaporator scale mineral in 1.5 M nitric acid is 12.5 hours, while the half-life for the decomposition of the 2H evaporator scale in 1.25 M nitric acid is 10.8 hours. Based on averaging the two half-lives from the 2H scale acid dissolution in 1.25 and 1.5 M nitric acid solutions, a reasonable half-live for the dissolution of 2H scales in dilute nitric acid is 11.7 ± 1.3 hours. The plant operational time for chemically cleaning (soaking) the 2H evaporator with dilute nitric acid is 32 hours. It therefore may require about 3 half-lives or less to completely dissolve most of the scales in the Evaporator pot which come into contact with the dilute nitric acid solution. On a mass basis, the Al-to-Si ratio for the scale dissolution in 1.5 M nitric acid averaged 1.30 ± 0.20 and averaged 1.18 ± 0.10 for the 2H scale dissolution in 1.25 M nitric acid. These aluminum-to-silicon ratios are in fairly good agreement with ratios from previous studies. Therefore, there is still more aluminum in the 2H evaporator scales than silicon which implies that there are no significant changes in scale properties which will exclude nitric acid as a viable protic solvent for aluminosilicate scale buildup dissolution from the 2H evaporator. Overall, the monitoring of the scale decomposition reaction in 1.25 and 1.5 M nitric acid may be better ascertained through the determination of aluminum concentration in solution than monitoring silicon in solution. Silicon solution chemistry may lead to partial precipitating of silicon with time as the scale and acid solution is heated.

Oji, L.

2014-09-23T23:59:59.000Z

19

Lunar and solar FTIR nitric acid measurements at Eureka in winter  

E-Print Network (OSTI)

Lunar and solar FTIR nitric acid measurements at Eureka in winter 2001/2002: comparisons acid measurements at Eureka obtained in winter 2001­2002 using solar and lunar Fourier transform Eureka (80.1°N, 86.4°W), Canada, have been made during polar night using lunar spectra recorded

Wirosoetisno, Djoko

20

Isothermal heat measurements of TBP-nitric acid solutions  

SciTech Connect

Net heats of reaction were measured in an isothermal calorimeter for both single phase (organic) and two phase (organic and aqueous) TBP/HNO{sub 3} reacting solutions at temperatures above 100 C. The oxidation rate constant was determined to be 5.4E-4 min{sup {minus}1} at 110 C for an open ``vented`` system as compared to 1.33 E-3 min{sup {minus}1} in the closed system. The heat released per unit material oxidized was also reduced. The oxidation in both phases was found to be first order in nitric acid and pseudo-zero order in butylnitrate and water. The hydrolysis (esterification) rate constant determined by Nichols` (1.33E-3 min{sup {minus}1}) fit the experimental data from this work well. Forced evaporation of the volatile components by the product gases from oxidation resulted in a cooling mechanism which more than balanced the heat from the oxidation reaction in the two-phased systems. Rate expressions were derived and rate constants determined for both the single and two phase systems. An approximating mathematical model was developed to fit the experimental data and to extrapolate beyond the experimental conditions. This model shows that one foot of ``reacting`` 14.3M HNO{sub 3} aqueous phase solution at 121 C will transport sufficient water to the organic phase to replace evaporative losses, maintaining endothermicity, for organic layers up to 12.2 + 6.0 feet deep. If the pressure in a reacting system is allowed to increase due to insufficient venting the temperature of the organic phase would increase in temperature to reach a new equilibrium. The rate of oxidation would increase not only due to the increase in temperature but also from the increased concentration of dissolved HNO{sub 3} reduction products. Another important factor is that the cooling system described in this work becomes less effective as the total pressure increases. These factors probably contributed to the explosion at Tomsk.

Smith, J.R.; Cavin, W.S.

1994-12-16T23:59:59.000Z

Note: This page contains sample records for the topic "nitric acid cxs" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Third phase formation in nitric acid extraction by n-octyl(phenyl)-n,n-diisobutylcarbamoylmethylphosphine oxide  

SciTech Connect

The third phase formation was studied as a function of n-octyl(phenyl)-N,N-diisobutylcarbamoylmethylphosphine oxide (CMPO) and tri-n-butyl phosphate (TBP) concentrations and temperature in the extraction of nitric acid. The concentration fractions of CMPO and TBP in the second and the third phases were determined by gas chromatography. Both CMPO and TBP were found to be enriched in the third phase. The concentrations of nitric acid in the second and the third phases relatively agreed with the calculated concentrations based on the extraction equilibrium constants of nitric acid by CMPO and TBP. The extraction of Np with the third phase formation was also discussed. 21 refs., 4 figs., 3 tabs.

Nagasaki, S.; Wisnubroto, D.S.; Enokida, Y.; Suzuki, A. (Univ. of Tokyo (Japan))

1994-03-01T23:59:59.000Z

22

Reactivity of tributyl phosphate degradation products with nitric acid: Relevance to the Tomsk-7 accident  

SciTech Connect

The reaction of a degraded tributyl phosphate (TBP) solvent with nitric acid is thought to have caused the chemical explosion at the Tomsk-7 reprocessing plant at Tomsk, Russia in 1993. The estimated temperature of the organic layer was not high eneough to cause significant reaction of nitric acid with TBP or hydrocarbon diluent compounds. A more reactive organic compound was likely present in the organic layer that reacted with sufficient heat generation to raise the temperature to the point where an autocatalytic oxidation of the organic solvent was initiated. Two of the most likely reactive compounds that are present in degraded TBP solvents are n-butanol and n-butyl nitrate. The reactions of these compounds with nitric acid are the subject of this study. The objective of laboratory-scale tests was to identify chemical reactions that occur when n-butanol and n-butyl nitrate contact heated nitric acid solutions. Reaction products were identified and quantitified, the temperatures at which these reactions occur and heats of reaction were measured, and reaction variables (temperature, nitric acid concentration, organic concentration, and reaction time) were evaluated. Data showed that n-butyl nitrate is less reactive than n-butanol. An essentially complete oxidation reaction of n-butanol at 110-120 C produced four major reaction products. Mass spectrometry identified the major inorganic oxidation products for both n-butanol and n-butyl nitrate as nitric oxide and carbon dioxide. Calculated heats of reaction for n-butanol and n-butyl nitrate to form propionic acid, a major reaction product, are -1860 cal/g n-butanol and -953 cal/g n-butyl nitrate. These heats of reaction are significant and could have raised the temperature of the organic layer in the Tomsk-7 tank to the point where autocatalytic oxidation of other organic compounds present resulted in an explosion.

Barney, G.S.; Cooper, T.D. [Westinghouse Hanford Company, Richland, WA (United States)

1995-12-31T23:59:59.000Z

23

Tropospheric Nitric Acid Columns from IASI Interpreted with a Chemical Transport Model Matthew Cooper1  

E-Print Network (OSTI)

1 Tropospheric Nitric Acid Columns from IASI Interpreted with a Chemical Transport Model Matthew from the IASI satellite instrument with a global chemical transport model (GEOS-Chem). GEOS the Infrared Atmospheric Sounding Interferometer (IASI) instrument on the MetOp satellite platform. IASI

Martin, Randall

24

Control of nitric acid plant stack opacity during start-up and shutdown  

SciTech Connect

This patent describes an improvement in a process for the production of nitric acid wherein air and ammonia are mixed and combusted in an ammonia burner to produce an effluent containing nitrogen oxides. The effluent is cooled, condensed and separated into a liquid weak acid stream and gas stream. The liquid weak acid and vapor streams are fed into an absorber tower wherein they are countercurrently contacted with water to produce a nitric acid stream and an overhead with a reduced nitrogen oxides content. The overhead is combusted with a fuel in the presence of a catalyst in a catalytic combustor to produce a combustor exhaust, work expanded in an expander to recover energy and vented to the atmosphere as stack exhaust. The improvement involves controlling the opacity of the stack opacity during shutdown of the process.

Adams, J.B.; Gasper, J.A.; Stash, P.J.

1989-09-26T23:59:59.000Z

25

Solvent extraction of uranyl (II) ion with N,N,N,N-tetrabutylsucinylamide from nitric acid solution  

Science Journals Connector (OSTI)

N,N,N,N-tetrabutylsuccinylamide (TBSA) in a diluent composed of 50% trimethylbenzene (TMB) and 50% kerosene (OK) can extract uranyl (II) ion from nitric acid solution. The results of extraction study suggested...

You-Shao Wang; Chao-Hong Shen; Jian-Kang Zhu…

1996-01-20T23:59:59.000Z

26

Extraction behavior of trivalent lanthanides from nitric acid medium by selected structurally related diglycolamides as novel extractants  

Science Journals Connector (OSTI)

Abstract The extraction affinity of trivalent lanthanides, Ln(III), from nitric acid medium has been explored using a series of ten structurally related synthesized diglycolamides (DGA) diluted with toluene. The structure-reactivity relationship with extraction of trivalent lanthanides as well as their atomic number was investigated. The extraction of nitric acid and selected lanthanide ions by N,N,N?,N?-tetradodeceyldiglycolamide (TDDGA), from nitric acid medium was studied in details. Distribution ratio of the trivalent lanthanide ions has been studied as a function of aqueous HNO3 concentrations, DGA concentration, and temperature. The stoichiometry of La(III), Nd(III), and Eu(III) was determined at different nitric acid concentrations by slope analysis of extraction data, and enthalpy change accompanied by extraction was also determined and reported in this work.

E.A. Mowafy; D. Mohamed

2014-01-01T23:59:59.000Z

27

Extraction of uranium(VI) and plutonium(IV) with dihexylbutyramide and dihexylisobutyramide from nitric acid medium  

Science Journals Connector (OSTI)

The extraction of uranium(VI) and plutonium(IV) was carried out with two isomeric monoamides, dihexylbutyramide (DHBA) and dihexylisobutyramide (DHIBA) from nitric acid medium, usingn-dodecane as diluent. The pos...

G. M. Nair; D. R. Prabhu; G. R. Mahajan

1994-08-01T23:59:59.000Z

28

A thermodynamic model of nitric acid extraction by tri-n-butyl phosphate  

SciTech Connect

A thermodynamic model is presented for nitric acid extraction by tri-n-butyl phosphate (TBP). This model is based on the formation of the organic phase species: TBP.HNO/sub 3/ and (TBP)/sub 2/.HNO/sub 3/. The model works successfully at TBP concentrations of 5 to 100 vol% and was found to be effective at predicting the extraction of HNO/sub 3/ from HNO/sub 3//NaNO/sub 3/ and HNO/sub 3//LiNO/sub 3/ solutions. Within the TBP concentration range of 5 to 30%, a single set of extraction constants was sufficient to fit extraction data. Stoichiometric activity coefficients of nitric acid in HNO/sub 3//NaNO/sub 3/ and HNO/sub 3//LiNO/sub 3/ mixtures were calculated using a model developed by Bromley.

Chaiko, D.J.; Vandegrift, G.F.

1988-07-01T23:59:59.000Z

29

Scandium nitrate-nitric acid-water-tributyl phosphate system. I. Scandium extraction isotherms  

SciTech Connect

A study has been made of scandium distribution between neat tributyl phosphate (TBP) and 0.2-1.2 M scandium solutions in 2.7-12.3 M nitric acid. Scandium extracts in equilibrium with 0.2-1 M Sc in 6-12 M HNO{sub 3} contain from 2 to 5 HNO{sub 3} molecules per scandium atom in extracted Sc complex.

Listopadov, A.A.; Nikitina, G.P.; Egorova, V.P. [Khlopin Radium Institute, St. Petersburg (Russian Federation)] [and others

1995-01-01T23:59:59.000Z

30

Initiation Temperature for Runaway Tri-n-Butyl Phosphate/Nitric Acid Reaction  

SciTech Connect

During a review of the H-Canyon authorization basis, Defense Nuclear Facility Safety Board (DNFSB) staff members questioned the margin of safety associated with a postulated tri-n-butyl phosphate (TBP)/nitric acid runaway reaction due to the inadvertent heating of a canyon tank containing greater than 3000 lbs (1362 kg) of TBP. The margin of safety was partially based on experiments and calculations performed by the Actinide Technology Section (ATS) to support deletion of indication of tank agitation as a Safety Class System. In the technical basis for deletion of this system, ATS personnel conservatively calculated the equilibrium temperature distribution of a canyon tank containing TBP and nitric acid layers which were inadvertently heated by a steam jet left on following a transfer. The maximum calculated temperature (128 degrees C) was compared to the minimum initiation temperature for a runaway reaction (greater than 130 degrees C) documented by experimental work in the mid 195 0s. In this work, the initiation temperature as a function of nitric acid concentration was measured for 0 and 20 wt percent dissolved solids. The DNFSB staff members were concerned that data for 0 wt percent dissolved solids were not conservative given the facts that data for 20 wt percent dissolved solids show initiation temperatures at or below 130 degrees C and H-Canyon solutions normally contained a small amount of dissolved solids.

Rudisill, T.S.

2000-11-28T23:59:59.000Z

31

Search for an in-line nitric acid analyzer  

SciTech Connect

A literature search was conducted to identify possible techniques for measuring mineral acid normality in the presence of heavy metal salts, undissolved solids, and high radiation fields. Of the techniques noted, eight were identified that could be applicable to the objective. The possibilities were reduced to two methods, which warrant further investigation. These two are refractometry and a modified coulometric-polarographic method. All methods are discussed in detail followed by rationale for including or rejecting each for further investigation.

Gallagher, K. Y.; Johnson, C. M.

1980-10-01T23:59:59.000Z

32

FY13 GLYCOLIC-NITRIC ACID FLOWSHEET DEMONSTRATIONS OF THE DWPF CHEMICAL PROCESS CELL WITH SIMULANTS  

SciTech Connect

Savannah River Remediation is evaluating changes to its current Defense Waste Processing Facility flowsheet to replace formic acid with glycolic acid in order to improve processing cycle times and decrease by approximately 100x the production of hydrogen, a potentially flammable gas. Higher throughput is needed in the Chemical Processing Cell since the installation of the bubblers into the melter has increased melt rate. Due to the significant maintenance required for the safety significant gas chromatographs and the potential for production of flammable quantities of hydrogen, eliminating the use of formic acid is highly desirable. Previous testing at the Savannah River National Laboratory has shown that replacing formic acid with glycolic acid allows the reduction and removal of mercury without significant catalytic hydrogen generation. Five back-to-back Sludge Receipt and Adjustment Tank (SRAT) cycles and four back-to-back Slurry Mix Evaporator (SME) cycles were successful in demonstrating the viability of the nitric/glycolic acid flowsheet. The testing was completed in FY13 to determine the impact of process heels (approximately 25% of the material is left behind after transfers). In addition, back-to-back experiments might identify longer-term processing problems. The testing was designed to be prototypic by including sludge simulant, Actinide Removal Product simulant, nitric acid, glycolic acid, and Strip Effluent simulant containing Next Generation Solvent in the SRAT processing and SRAT product simulant, decontamination frit slurry, and process frit slurry in the SME processing. A heel was produced in the first cycle and each subsequent cycle utilized the remaining heel from the previous cycle. Lower SRAT purges were utilized due to the low hydrogen generation. Design basis addition rates and boilup rates were used so the processing time was shorter than current processing rates.

Lambert, D.; Zamecnik, J.; Best, D.

2014-03-13T23:59:59.000Z

33

Sorption of uranium from nitric acid solution using TBP-impregnated activated carbons  

SciTech Connect

The concept of extraction chromatography has been used to study the sorption of uranium from nitric acid solutions using tri-n-butyl phosphate (TBP) impregnated activated carbons. Batch equilibrium data and kinetic and breakthrough column behavior of uranium are reported. Wood based activated carbon has shown better capacity and breakthrough characteristics than shell based activated carbon. Sorption rate on impregnated carbons was relatively slow indicating that diffusion is the rate controlling step within the pore structure of the activated carbon. Uranium distribution on impregnated activated carbons is compared with equivalent bulk liquid extraction and a mechanism of uranium sorption is discussed.

Abbasi, W.A. [Pakistan Atomic Energy Commission, Islamabad (Pakistan). Pakistan Inst. of Nuclear Science and Technology; Streat, M. [Loughborough Univ. (United Kingdom). Dept. of Chemical Engineering

1998-08-01T23:59:59.000Z

34

Effect of temperature on the extraction of nitric acid and plutonium(IV) nitrate with 30 vol% tributyl phosphate (TBP)  

SciTech Connect

The author's own and published data were evaluated for characterizing the effect of temperature on the distribution of nitric acid and plutonium(IV). The solutes were distributed between 30 vol% TBP in an aliphatic diluent and aqueous solutions containing nitric acid and zero to macro amounts of plutonium(IV) and uranyl nitrates. The temperature dependence of the distribution ratios is described with empirical model equations and examples of the dependence in the absence and presence of uranium(VI) are given. Taking infinite dilution of all solutes of the system as a standard state, the enthalpy change of the extraction reaction could be estimated as -17 kJ/mol for nitric acid, but no numerical estimate was possible for plutonium(IV).

Kolarik, Z.

1984-01-01T23:59:59.000Z

35

Features of gadolinium and ytterbium extraction by tributyl phosphate from concentrated nitric acid solutions. II. IR spectra of lanthanide extracts  

SciTech Connect

Equilibrium organic phases in extraction systems consisting of tributyl phosphate (TBP) (neat or 1.8 M in CCl{sub 4}) and 8-12 M nitric acid containing Gd or Yb or lanthanide-free have been studied by IR spectroscopy. It was shown that under these conditions lanthanides are extracted as complex trisolvates Ln(NO{sub 3})9{sub 3}{center_dot}mHNO{sub 3}{center_dot}3TBP with m = 3-6. Nitric acid molecules are H-bonded to oxygen atoms of coordinated nitrate ions and do not substitute TBP molecules in coordination sphere of the metal ion.

Nikitina, G.P.; Seredkina, N.V.; Kistopadov, A.A. [Khlopin Radium Institute, St. Petersburg (Russian Federation)

1995-03-01T23:59:59.000Z

36

Solar fuels and chemicals system design study (ammonia/nitric acid production process). Volume 2. Conceptual design. Final report  

SciTech Connect

As part of the Solar Central Receiver Fuels and Chemicals Program, Foster Wheeler Solar Development Corporation (FWSDC), under contract to Sandia National Laboratories-Livermore (SNLL), developed a conceptual design of a facility to produce ammonia and nitric acid using solar energy as the principal external source of process heat. In the selected process, ammonia is produced in an endothermic reaction within a steam methane (natural gas) reformer. The heat of reaction is provided by molten carbonate salt heated by both a solar central receiver and an exothermic ammonia-fired heater. After absorption by water, the product of the latter reaction is nitric acid.

Not Available

1986-06-01T23:59:59.000Z

37

Separation of uranium from nitric and hydrochloric acid solutions with extractant-coated magnetic microparticles.  

SciTech Connect

The magnetically assisted chemical separation (MACS) process utilizes selective magnetic microparticle composites to separate dissolved metals from solution. In this study, MACS particles were coated with neutral and acidic organophosphorus extractants,octyl(phenyl)-N,N-diisobutylcarbamoylmethyl phosphine oxide (CMPO), tributyl phosphate (TBP), trioctylphosphine oxide (TOPO), and bis(2-ethyl-hexyl)phosphoric acid (D{sub 2}EHPA or HDEHP) and were evaluated for the separation of uranyl ions from nitric- and hydrochloric-acid solutions. The results suggest that a synergistic interaction between the particle surface and solvent coating may explain why the particles display, in some cases, orders of magnitude of higher partitioning coefficients than are estimated from solvent-extraction measurements. Particles coated with TBP and those coated with a combination of TOPO and D{sub 2}EHPA displayed the most desirable characteristics for removing uranium from dilute acid environments typical of contaminated groundwater. Uranium separation from moderate to highly acidic waste streams typical of Department of Energy (DOE) nuclear wastes is best accomplished using particles coated with a combination of CMPO and TBP.

Kaminski, M. D.; Nunez, L.; Chemical Engineering

2000-01-01T23:59:59.000Z

38

Safe conditions for contacting nitric acid or nitrates with tri-n-butyl phosphate (TBP)  

SciTech Connect

In response to a request from DOE-SR, the current state of knowledge of the reactions between TBP and aqueous nitrate solutions is critically reviewed, and recommendations are made for the safe operation of SRS separations equipment in which this combination of chemicals may be present. The existing limits for evaporation are validated. Guidelines are presented for cases in which general limits do not apply. The rate of reaction between nitric acid and TBP appears to be controlled by the rate of TBP hydrolysis. The hydrolysis reaction produces dibutyl phosphate and n-butanol. The hydrolysis rate is a strong function of temperature, and becomes very fast at temperatures in the range 130{degrees} to 150{degrees}C. The resulting n-butanol is volatile at high temperatures, boiling at 117.5{degrees}C, but is also subject to exothermic oxidation by nitric acid or nitrates. If oxidation occurs before the n-butanol evaporates, the heat of oxidation may exceed local cooling by convection. The resulting heating will further accelerate the reaction, leading to an energetic runaway and possibly (in confined systems) an explosion. Extensive experiments and practice have shown that in a well-mixed and well-vented aqueous system such as an evaporator, at moderate acidities and temperatures below 130{degrees}C, the heat of reaction is adequately removed by vaporization of steam. In general, the heating will be so slow that natural processes provide adequate cooling at temperatures below 80{degrees}C. Above this temperature, care should be taken to ensure that adequate cooling is available for the amount of TBP that may be present. Experiments suggest that in well-ventilated systems n-butanol evaporation and convective cooling are sufficient to control the reaction at temperatures up to 120{degrees}C.

Hyder, M.L

1994-01-01T23:59:59.000Z

39

Corrosion property of 9Cr-ODS steel in nitric acid solution for spent nuclear fuel reprocessing  

SciTech Connect

Corrosion tests of oxide dispersion strengthened with 9% Cr (9Cr-ODS) steel, which is one of the desirable materials for cladding tube of sodium-cooled fast reactors, in pure nitric acid solution, spent FBR fuel solution, and its simulated solution were performed to understand the corrosion behavior in a spent nuclear fuel reprocessing. In this study, the 9Cr-ODS steel with lower effective chromium content was evaluated to understand the corrosion behavior conservatively. As results, the tube-type specimens of the 9Cr-ODS steels suffered severe weight loss owing to active dissolution at the beginning of the immersion test in pure nitric acid solution in the range from 1 to 3.5 M. In contrast, the weight loss was decreased and they showed a stable corrosion in the higher nitric acid concentration, the dissolved FBR fuel solution, and its simulated solution by passivation. The corrosion rates of the 9Cr-ODS steel in the dissolved FBR fuel solution and its simulated solution were 1-2 mm/y and showed good agreement with each other. The passivation was caused by the shift of corrosion potential to noble side owing to increase in nitric acid concentration or oxidative ions in the dissolved FBR fuel solution and the simulated spent fuel solution. (authors)

Takeuchi, M.; Koizumi, T. [Japan Atomic Energy Agency, Tokai-mura, Naka-gun, Ibaraki 319-1195 (Japan); Inoue, M.; Koyama, S.I. [Japan Atomic Energy Agency, Oarai-machi, Higashi-ibaraki-gun, Ibaraki 311-1393 (Japan)

2013-07-01T23:59:59.000Z

40

Nitric Acid Deposition following an Astrophysical Ionizing Radiation Event is below Critical Loads for Terrestrial and Freshwater Ecosystems  

E-Print Network (OSTI)

Nitric acid rainout is one of the effects of an astrophysical ionizing radiation event. The predicted values of nitrate rainout from previous work for a typical gamma ray burst (GRB) within our galaxy serve as an extreme example and are shown to be below critical loads of eutrophication and acidification for ecoregions in Europe and the US.

Melott, Ben Neuenswander Adrian

2014-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "nitric acid cxs" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Hibiscus Protocatechuic Acid or Esculetin Can Inhibit Oxidative LDL Induced by Either Copper Ion or Nitric Oxide Donor  

Science Journals Connector (OSTI)

Hibiscus Protocatechuic Acid or Esculetin Can Inhibit Oxidative LDL Induced by Either Copper Ion or Nitric Oxide Donor ... Several groups using different flavonoids, such as quercetin, catechin, morin, rutin, fisetin, and gossypetin, also showed that flavonoids could inhibit copper-catalyzed and macrophage-mediated LDL oxidation (13?16). ... morin and fisetin 1 ?M; quercetin and gossypetin 2 ?M). ...

Miao-Jane Lee; Fen-Pi Chou; Tsui-Hwa Tseng; Ming-Hsun Hsieh; Ming-Cheng Lin; Chau-Jong Wang

2002-02-16T23:59:59.000Z

42

Initiation Temperature for Runaway Tri-n-Butyl Phosphate/Nitric Acid Reaction  

SciTech Connect

In a review of the safety basis for solvent extraction processes at the Department of Energy's Savannah River Site, a question was raised concerning the safety margin associated with a postulated accident involving a runaway tri-n-butyl phosphate (TBP)/nitric acid reaction due to the inadvertent heating of a tank. The safety margin was based on studies which showed the maximum temperature would not exceed 128 degrees Celsius compared to 130 degrees Celsius, the minimum initiation temperature for runaway reaction established in the 1950's following damaging incidents at the Savannah River and Hanford Sites. The reviewers were concerned the minimum temperature was not conservative since data for solutions containing 20 wt percent dissolved solids showed initiation temperatures at or below 130 degrees Celsius and process solutions normally contain some dissolved solids.

Rudisill, T.S.

2001-09-14T23:59:59.000Z

43

Extraction equilibria between organic CMPO-n-dodecane and aqueous nitric acid phases for selected tank waste components  

SciTech Connect

Removal of the transuranium elements from tank-stored wastes is an important step in the cost effective treatment and preparation of these wastes for permanent disposal. One promising method of treatment involves dissolving the tank sludges in acid, followed by extraction of the transuranium species. The TRUEX process, which uses an extracting medium composed of octyl(phenyl)-N,N-diisobutylcarbamoylmethyl phosphine oxide (CMPO) and tri-n-butyl phosphate (TBP) dissolved in an organic solvent such as n-dodecane, is being tested for this purpose. Although CMPO is a powerful extractant for all the actinides, concern arises that certain process chemicals present in the waste will compete for the CMPO. Data will be presented on the pure component equilibrium characteristics of nitric acid, uranyl nitrate and bismuth nitrate partitioned between a nitric acid aqueous phase and a CMPO-n-dodecane organic phase.

Spencer, B.B.; Egan, B.Z. [Oak Ridge National Lab., TN (United States); Counce, R.M. [Univ. of Tennessee, Knoxville, TN (United States)

1996-10-01T23:59:59.000Z

44

MATERIAL COMPATIBILITY EVALUATION FOR DWPF NITRIC-GLYCOLIC ACID - LITERATURE REVIEW  

SciTech Connect

Glycolic acid is being evaluated as an alternative for formic and nitric acid in the DWPF flowsheet. Demonstration testing and modeling for this new flowsheet has shown that glycolic acid and glycolate has a potential to remain in certain streams generated during the production of the nuclear waste glass. A literature review was conducted to assess the impact of glycolic acid on the corrosion of the materials of construction for the DWPF facility as well as facilities downstream which may have residual glycolic acid and glycolates present. The literature data was limited to solutions containing principally glycolic acid. The reported corrosion rates and degradation characteristics have shown the following for the materials of construction. ? For C276 alloy, the primary material of construction for the CPC vessels, corrosion rates of either 2 or 20 mpy were reported up to a temperature of 93 ?C. ? For the austenitic stainless steels, 304L and 316L, variable rates were reported over a range of temperatures, varying from 2 mpy up to 200 mpy (at 100 ?C). ? For 690, G30, Allcorr, Ultimet and Stellite alloys no data were available. ? For relevant polymers where data are available, the data suggests that exposure to glycolic acid is not detrimental. The literature data had limited application to the DWPF process since only the storage and feed vessels, pumps and piping used to handle the glycolic acid are directly covered by the available data. These components are either 304L or 316L alloys for which the literature data is inconsistent (See Bullet 2 above). Corrosion rates in pure glycolic acid solutions also are not representative of the DWPF process streams. This stream is complex and contains aggressive species, i.e. chlorides, sulfates, mercury, as well as antifoaming agents which cumulatively have an unknown effect on the corrosion rates of the materials of construction. Therefore, testing is recommended to investigate any synergistic effects of the aggressive species and to verify the performance of materials in the key process vessels as well as downstream vessels and processes such as the evaporator where heating is occurring. The following testing would provide data for establishing the viability of these components. ? Electrochemical testing - evaluate the corrosion rate and susceptibility to localized corrosion within the SRAT, SME, OGCT, Quencher and Evaporator. Testing would be conducted at operational temperatures in simulants with ranges of glycolic acid, iron, chloride, sulfate, mercury, and antifoaming agents. ? Hot-wall testing – evaluate the corrosion under heat transfer conditions to simulate those for heating coils and evaporator coil surfaces. Testing would be at nominal chemistries with concentration of glycolic acid, chloride, sulfate and mercury at high expected concentrations. Some tests would be performed with antifoaming agents. ? Melter coupon testing – evaluate the performance of alloy 690 in melter feeds containing glycolic acid. This testing would be conducted as part of the melter flammability testing. ? Polymer testing – evaluate changes in polymer properties in immersion testing with DWPF simulants to provide product-specific data for service life evaluation and analyze the Hansen solubility parameters for relevant polymers in glycolic vs. formic acid. During this literature review process, the difficulties associated with measuring the liquid level in formic acid tanks were revealed. A test is recommended to resolve this issue prior to the introduction of glycolic acid into the DWPF. This testing would evaluate the feasibility of using ultrasonic inspection techniques to determine liquid level and other desirable attributes of glycolic acid in DWPF storage tanks and related equipment.

Mickalonis, J.; Skidmore, E.

2013-06-05T23:59:59.000Z

45

E-Print Network 3.0 - abandoned nitric acid Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

Wet ashing procedures using nitric ... Source: Canberra, University of - Institute for Applied Ecology Collection: Environmental Sciences and Ecology 16 Human Resources...

46

Amides as phase modifiers for N,N{prime}-tetraalkylmalonamide extraction of actinides and lanthanides from nitric acid solutions  

SciTech Connect

The N,N{prime}-tetraalkylmalonamides are a class of compounds under development for transuranic (TRU) separations under high nitric acid conditions. There are several issues that challenge the further development of these ligands. One is the development of improved synthetic procedures that lend themselves to commercial scale-up. Another major issue is the third-phase formation that occurs when the N,N{prime}-tetraalkylmalonamides are contacted with medium-to-high nitric acid concentrations in hydrocarbon solvents. To address the synthesis issue, the authors have developed a new synthetic approach for preparing these materials. Third-phase formation can be eliminated by addition of diluent modifiers such as tributylphosphate (TBP). TBP is inappropriate if a nonphosphate-containing process stream is required. Amides have been proposed as alternatives for TBP in a variety of applications because of their ease of synthesis and the variety of substituents that can be generated. The authors have been able to develop an amide phase-modified system that extends the working process range of alkylinalonamides (0.5 M) in dodecane: from 3.5 M to 7.5 M nitric acid and in Isopar H (branched hydrocarbon) from 4.0 M to 10.0 M nitric acid using 1.0 M di-2-ethylhexylacetamide/0.5 M alkylmalonamide. The Kd values were comparable to extraction with alkylinalonamide in Isopar H or hydrogenated tetrapropylene (TPH) solvents. The overall extraction system was more robust than the phase-uninodified system allowing for greater temperature and acid concentration fluctuations without third-phase formation.

Smith, B.F.; Wilson, K.V.; Gibson, R.R. [Los Alamos National Lab., NM (United States)

1997-01-01T23:59:59.000Z

47

Remedial investigation report on the abandoned nitric acid pipeline at the Oak Ridge Y-12 Plant, Oak Ridge, Tennessee  

SciTech Connect

Upper East Fork Poplar Creek OU-2 consists of the Abandoned Nitric Acid Pipeline. This pipeline was installed in 1951 to transport liquid wastes {approximately} 4,800 ft from Buildings 9212, 9215, and 9206 to the S-3 Ponds. Materials known to have been discharged through the pipeline include nitric acid, depleted and enriched uranium, various metal nitrates, salts, and lead skimmings. A total of nineteen locations were chosen to be investigated along the pipeline for the first phase of this Remedial Investigation. Sampling consisted of drilling down to obtain a soil sample at a depth immediately below the pipeline. Additional samples were obtained deeper in the subsurface depending upon the depth of the pipeline, the depth of the water table, and the point of auger refusal. The nineteen samples collected below the pipeline were analyzed by the Y-12 Plant laboratory for metals, nitrate/nitrite, and isotopic uranium. Samples collected from three boreholes were also analyzed for volatile organic compounds because these samples produced a response with organic vapor monitoring equipment. The results of the baseline human health risk assessment for the Abandoned Nitric Acid Pipeline contaminants of potential concern show no unacceptable risks to human health via incidental ingestion of soil, inhalation of dust, dermal contact with the soil, or external exposure to radionuclides in the ANAP soils, under the construction worker and/or the residential land-use scenarios.

Not Available

1993-12-01T23:59:59.000Z

48

Process for preparing a chemical compound enriched in isotope content. [nitrogen 15-enriched nitric acid  

DOE Patents (OSTI)

A process to prepare a chemical enriched in isotope content includes: a chemical exchange reaction between a first and second compound which yields an isotopically enriched first compound and an isotopically depleted second compound; the removal of a portion of the first compound as product and the removal of a portion of the second compound as spent material; the conversion of the remainder of the first compound to the second compound for reflux at the product end of the chemical exchange reaction region; the conversion of the remainder of the second compound to the first compound for reflux at the spent material end of the chemical exchange region; and the cycling of the additional chemicals produced by one conversion reaction to the other conversion reaction, for consumption therein. One of the conversion reactions is an oxidation reaction, and the energy that it yields is used to drive the other conversion reaction, a reduction. The reduction reaction is carried out in a solid polymer electrolyte electrolytic reactor. The overall process is energy efficient and yields no waste by-products. A particular embodiment of the process in the production of nitrogen-15-enriched nitric acid.

Michaels, E.D.

1981-02-25T23:59:59.000Z

49

Effect of temperature on the extraction of uranium(VI) from nitric acid by tri-n-amyl phosphate  

SciTech Connect

Studies have been carried out on the effect of temperature on the extraction of U(VI) from nitric acid medium by tri-n-amyl phosphate/n-dodecane, measured as a function of the extractant concentration and aqueous phase acidity. The results indicate that the extraction is exothermic as in the case of tri-n-butyl phosphate. From the data available an effort has been made to calculate the equilibrium constant, the Gibbs energy change and the entropy changes of the extraction reaction. 21 refs., 3 figs., 4 tabs.

Srinivasan, T.G.; Rao, P.R.V. [Indira Gandhi Centre for Atomic Research, Kalpakkam (India); Sood, D.D. [Indira Gandhi Centre for Atomic Research, Kalpakkam (India)]|[BARC, Mumbai (India)

1997-01-01T23:59:59.000Z

50

Oxyfuel CO2 compression: The gas phase reaction of elemental mercury and \\{NOx\\} at high pressure and absorption into nitric acid  

Science Journals Connector (OSTI)

Abstract Oxyfuel combustion is a technology which combusts coal in oxygen and recycled flue gas, producing a carbon dioxide rich flue gas for sequestration. Oxyfuel flue gas contains trace amounts of elemental mercury, which may corrode brazed aluminium heat exchangers used in the carbon dioxide purification system. International gas vendors have tested the use of the compression system to remove other flue gas impurities such as NOx; however, the reaction mechanism of mercury and its reaction products with \\{NOx\\} and nitric acid formed with condensed water vapour are unclear. This study used lab scale experiments to study the absorption of gaseous elemental mercury into nitric acid and the gas phase reaction between mercury and nitrogen dioxide formed from oxidised NO at pressures up to 25 bar. It was observed that mercury has limited absorption into nitric acid and may partially desorb out of solution after depressurisation. On the other hand, mercury reacted readily with nitrogen dioxide (formed from nitric oxide oxidation at high pressure) in the gas phase. These gas phase reactions from the oxidation of nitric oxide to nitrogen dioxide to the subsequent oxidation of elemental mercury by nitrogen dioxide were predicted using existing global kinetic equations. The limited absorption of gaseous elemental mercury in nitric acid and significant oxidation of gaseous elemental mercury by nitrogen dioxide suggests that the primary removal step for elemental mercury is through the gas phase reaction. Oxyfuel compression circuits should therefore allow sufficient residence time for this gas phase reaction to occur.

Timothy Ting; Rohan Stanger; Terry Wall

2014-01-01T23:59:59.000Z

51

Nitric oxide donors prevent while the nitric oxide synthase inhibitor L-NAME increases arachidonic acid plus CYP2E1-dependent toxicity  

SciTech Connect

Polyunsaturated fatty acids such as arachidonic acid (AA) play an important role in alcohol-induced liver injury. AA promotes toxicity in rat hepatocytes with high levels of cytochrome P4502E1 and in HepG2 E47 cells which express CYP2E1. Nitric oxide (NO) participates in the regulation of various cell activities as well as in cytotoxic events. NO may act as a protectant against cytotoxic stress or may enhance cytotoxicity when produced at elevated concentrations. The goal of the current study was to evaluate the effect of endogenously or exogenously produced NO on AA toxicity in liver cells with high expression of CYP2E1 and assess possible mechanisms for its actions. Pyrazole-induced rat hepatocytes or HepG2 cells expressing CYP2E1 were treated with AA in the presence or absence of an inhibitor of nitric oxide synthase L-N {sup G}-Nitroarginine Methylester (L-NAME) or the NO donors S-nitroso-N-acetylpenicillamine (SNAP), and (Z)-1-[-(2-aminoethyl)-N-(2-aminoethyl)]diazen-1-ium-1,2-diolate (DETA-NONO). AA decreased cell viability from 100% to 48 {+-} 6% after treatment for 48 h. In the presence of L-NAME, viability was further lowered to 23 {+-} 5%, while, SNAP or DETA-NONO increased viability to 66 {+-} 8 or 71 {+-} 6%. The L-NAME potentiated toxicity was primarily necrotic in nature. L-NAME did not affect CYP2E1 activity or CYP2E1 content. SNAP significantly lowered CYP2E1 activity but not protein. AA treatment increased lipid peroxidation and lowered GSH levels. L-NAME potentiated while SNAP prevented these changes. Thus, L-NAME increased, while NO donors decreased AA-induced oxidative stress. Antioxidants prevented the L-NAME potentiation of AA toxicity. Damage to mitochondria by AA was shown by a decline in the mitochondrial membrane potential (MMP). L-NAME potentiated this decline in MMP in association with its increase in AA-induced oxidative stress and toxicity. NO donors decreased this decline in MMP in association with their decrease in AA-induced oxidative stress and toxicity. These results indicate that NO can be hepatoprotective against CYP2E1-dependent toxicity, preventing AA-induced oxidative stress.

Wu Defeng [Department of Pharmacology and Biological Chemistry, Box 1603, One Gustave L. Levy Place, Mount Sinai School of Medicine, New York, NY 10029 (United States); Cederbaum, Arthur [Department of Pharmacology and Biological Chemistry, Box 1603, One Gustave L. Levy Place, Mount Sinai School of Medicine, New York, NY 10029 (United States)]. E-mail: arthur.cederbaum@mssm.edu

2006-10-15T23:59:59.000Z

52

Solvent Extraction Behavior of Neptunium (IV) Ions between Nitric Acid and Diluted 30% Tri-butyl Phosphate in the Presence of Simple Hydroxamic Acids  

SciTech Connect

Formo- and aceto-hydroxamic acids are very effective reagents for stripping tetravalent actinide ions such as Np(IV) and Pu(IV) ions from a tri-butyl phosphate phase into nitric acid. Distribution data for Np(IV) in the presence of these hydroxamate ions have now been accumulated and trends established. Stability constants for aceto-hydroxamate complexes of Np(IV) and Np(V) ions have also been determined in a perchlorate medium, and these reaffirm the affinity of hydroxamate ligands for actinide (IV) ions over actinyl (V,VI) ions.

Taylor, Robin J.; Sinkov, Sergey I.; Choppin, Gregory R.; May, Iain

2008-01-15T23:59:59.000Z

53

Scandium nitrate-nitric acid-water-tributyl phosphate system. II. Interaction of Sc(NO{sub 3}){sub 3}{center_dot}3TBP with nitric acid in organic solvent  

SciTech Connect

Scandium nitrate solvates Sc(NO{sub 3}){sub 3}{center_dot}qTBP (TBP is tributyl phosphate, q = 3.15, 2.57, and 1.58) were synthesized, and their IR spectra were measured. Model solutions of Sc(NO{sub 3}){sub 3}{center_dot}3TBP in CCl{sub 4} containing nitric acid with Sc:HNO{sub 3} molar ratios 1:1 to 1:3 and 1:7 were prepared, and their IR spectra were also measured. The spectra indicate formation of complexes with formula Sc(NO{sub 3}){sub 3}{center_dot}mHNO{sub 3}{center_dot}3TBP (m = 1-7) through H-bonding of medium strength. In complexes with m = 1-2, nitric acid molecules are presumably bonded to oxygen atoms of nitrate groups coordinated to scandium. The R{sub O{hor_ellipsis}O} distance in these complexes was estimated for the H-bond as 2.68 {angstrom}.

Nikitina, G.P.; Papkov, K.B.; Listopadov, A.A. [Khlopin Radium Institute, St. Petersburg (Russian Federation)

1995-03-01T23:59:59.000Z

54

Synergistic selective extraction of actinides(III) over lanthanides from nitric acid using new aromatic diorganyldithiophosphinic acids and neutral organophosphorus compounds  

SciTech Connect

New aromatic dithiophosphinic acids (R{sub 2}PSSH) with R = C{sub 6}H{sub 5{sup {minus}}}, ClC{sub 6}H{sub 4{sup {minus}}}, FC{sub 6}H{sub 4{sup {minus}}} and CH{sub 3}C{sub 6}H{sub 4{sup {minus}}} were synthesized, characterized and tested as potential separating agents for trivalent actinides over lanthanides. The extraction of Am(III), Eu(III) and other lanthanides was carried out from nitric acid medium with mixtures of R{sub 2}PSSHs and neutral organophosphorus compounds. There was no detectable extraction when R{sub 2}PSSHs were used alone as extractants for either Am(III) or Eu(III) (D{sub Am,Eu} < 10{sup {minus}3}) under the experimental conditions used in this study. High separation factors (D{sub Am}/D{sub Eu} > 20) with D{sub Am} > 1 were achieved in the nitric acid range 0.1--1 mol/L by means of a synergistic mixture of bis(chlorophenyl)dithiophosphinic acid + tributylphosphate (TBP), trioctylphosphine oxide (TOPO) or tributylphosphine oxide (TBPO). The high radiation resistance (up to 10{sup 6} Gy absorbed {gamma}-doses) of the extractants was also demonstrated.

Modolo, G.; Odoj, R. [Forschungszentrum Juelich GmbH (Germany). Inst. fuer Sicherheitsforschung und Reaktortechnik

1999-01-01T23:59:59.000Z

55

Comparative evaluation of DHDECMP (dihexyl-N,N-diethylcarbamoyl-methylphosphonate) and CMPO (octylphenyl-N,N,-diisobutylcarbamoylmethylphosphine oxide) as extractants for recovering actinides from nitric acid waste streams  

SciTech Connect

Certain neutral, bifunctional organophosphorous compounds are of special value to the nuclear industry. Dihexyl-N,N-diethylcarbomoylmethylphosphonate (DHDECMP) and octylphenyl-N,N-diisobutylcarbamoylmethylphosphine oxide (CMPO) are highly selective extractants for removing actinide and lanthanide elements from nitric acid. We obtained these two extractants from newly available commercial sources and evaluated them for recovering Am(III), Pu(IV), and U(VI) from nitric acid waste streams of plutonium processing operations. Variables included the extractant (DHSECMP or CMPO), extractant/tributylphosphate ratio, diluent, nitrate concentration, nitrate salt/nitric acid ratio, fluoride concentration, and contact time. Based on these experimental data, we selected DHDECMP as the perferred extractant for this application. 18 refs., 30 figs.

Marsh, S.F.; Yarbro, S.L.

1988-02-01T23:59:59.000Z

56

K Basin Sludge Conditioning Process Testing Fate of PCBs During K Basin Sludge Dissolution in Nitric Acid and with Hydrogen Peroxide Addition  

SciTech Connect

The work described in this report is part of the studies being performed to address the fate of polychlorinated biphenyls (PCBs) in K Basin sludge before the sludge can be transferred to the Tank Waste Remediation System (TWRS) double shell tanks. One set of tests examined the effect of hydrogen peroxide on the disposition of PCBs in a simulated K Basin dissolver solution containing 0.5 M nitric acid/1 M Fe(NO{sub 3}){sub 3}. A second series of tests examined the disposition of PCBs in a much stronger ({approx}10 M) nitric acid solution, similar to that likely to be encountered in the dissolution of the sludge.

GM Mong; AJ Schmidt; EW Hoppe; KH Pool; KL Silvers; BM Thornton

1999-01-04T23:59:59.000Z

57

Safety of Tri-n-butyl phosphate (TBP) and nitric acid solutions in two-phase systems at elevated temperatures  

SciTech Connect

This paper addresses the prevention of self-accelerating oxidation of nitric acid and tributyl phosphate (TBP). An accident of this type, which occurred at Tomsk-7, Russia, in 1993, resulted from a slow chemical reaction occurring initially at sub-boiling temperatures. The accumulating heat and vapors overpressurized and burst a process tank. Two safety issues are addressed in this summary of experimental data: circumstances under which convection or radiation cooling of vessels will exceed reaction heat, and measures which can prevent or mitigate such reactions. Heat generations rates have been found to range widely. Thermodynamic calculations confirm that heat generation is reduced by a large factor when nitrogen oxides are able to escape from the reaction mixure. Scoping calculations show that the evaporation of water is potentially the most effective mechanism for heat removal in a large vessel, and experiments have demonstrated that water evaporation is effective for preventing runaway reactions in a vented, two-phase system operated below about 120 C. These data indicate that venting is the key to controlling runaway reactions. However, other experiments have indicated that the self-heating reaction did not present a danger, even if reaction heating led to an accelerating reaction, in a sufficiently vented system. To determine how much venting was required, experiments were performed with pure organic phase and two-phase TBP-nitric acid mixtures. Data show a critical ratio of organic mass to vent area, above which the reacting system can reach potentially dangerous pressures. Experiments show runaway reactions occurring in vented systems only as the temperature approaches 130 C. These results clearly indicate that adequate venting of vessels containing heated TBP and nitrate is the key to controlling their reaction.

Hyder, M.L.; Paddleford, D.F.; Thompson, M.C. [Westinghouse Savannah River Company, Aiken, SC (United States)

1995-12-31T23:59:59.000Z

58

Studies on reaction runaways for Urex/Purex solvent-nitric acid and red-oil synthesis  

SciTech Connect

In PUREX/UREX processes for recycling of spent nuclear fuels, 30% TBP solvent is used, This solvent has a small solubility in the aqueous phase. During concentration of the process solutions by an evaporation route, a runaway reaction between TBP and nitric acid is initiated at above 130 deg. C, leading to rapid pressurization and finally containment failure if proper venting is not provided. Red oil was synthesized for the first time in India, and its physical properties as well as thermodynamic parameters for the reaction were determined. It was experimentally established that the presence of metallic nitrates was not essential for red-oil formation as thought earlier. Various experiments have been completed for single-phase as well as two-phase runs. The most important finding of this work was lowering of the limiting acid concentration from the conventional values. In fact, in these experiments, red oil could be formed even at 2 N aqueous acidity. Thus, safety guidelines based on the classical literature are obsolete. New guidelines for the red-oil-safety are required. (authors)

Kumar, Shekhar; Kumar, Rajnish; Koganti, S.B. [Reprocessing R and D Division, Reprocessing Group, Indira Gandhi Centre for Atomic Research, Kalpakkam 603102 (India)

2008-07-01T23:59:59.000Z

59

THERMODYNAMICS OF EXTRACTION OF NITRIC ACID BY TRI-n-BUTYL PHOSPHATE--HYDROCARBON DILUENT SOLUTIONS  

E-Print Network (OSTI)

the mean act ivi ty coefficient T of TBP and TBP.H20 i n the acid-free, water-saturated organic phase

Wallace Davis

1961-01-01T23:59:59.000Z

60

Extraction and recovery of plutonium and americium from nitric acid waste solutions by the TRUEX process - continuing development studies  

SciTech Connect

This report summarizes the work done to date on the application of the TRUEX solvent extraction process for removing and separately recovering plutonium and americium from a nitric acid waste solution containing these elements, uranium, and a complement of inert metal ions. This simulated waste stream is typical of a raffinate from a tributyl phosphate (TBP)-based solvent extraction process for removing uranium and plutonium from dissolved plutonium-containing metallurgical scrap. The TRUEX process solvent in these experiments was a solution of TBP and octyl(phenyl)-N,N-diisobutylcarbamoylmethylphosphine oxide (CMPO) dissolved in carbon tetrachloride. A flowsheet was designed on the basis of measured batch distribution ratios to reduce the TRU content of the solidified raffinate to less than or equal to 10 nCi/g and was tested in a countercurrent experiment performed in a 14-stage Argonne-model centrifugal contractor. The process solvent was recycled without cleanup. An unexpectedly high evaporative loss of CCl/sub 4/ resulted in concentration of the active extractant, CMPO, to nearly 0.30M in the solvent. Results are consistent with this higher CMPO concentration. The raffinate contained only 2 nCi/g of TRU, but the higher CMPO concentration resulted in reduced effectiveness in the stripping of americium from the solvent. Conditions can be easily adjusted to give high yields and good separation of americium and plutonium. Experimental studies of the hydrolytic and gamma-radiolytic degradation of the TRUEX-CCl/sub 4/ showed that solvent degradation would be (1) minimal for a year of processing this typical feed, which contained no fission products, and (2) could be explained almost entirely by hydrolytic and radiolytic damage to TBP. Even for gross amounts of solvent damage, scrubbing with aqueous sodium carbonate solution restored the original americium extraction and stripping capability of the solvent. 43 refs., 5 figs., 36 tabs.

Leonard, R.A.; Vandegrift, G.F.; Kalina, D.G.; Fischer, D.F.; Bane, R.W.; Burris, L.; Horwitz, E.P.; Chiarisia, R.; Diamond, H.

1985-09-01T23:59:59.000Z

Note: This page contains sample records for the topic "nitric acid cxs" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Salt Effect Model for Aqueous Solubility of TBP in a 5 to 100% TBP/n-Dodecane-Nitric Acid-Water Biphasic System at 298.2 K  

SciTech Connect

The solubilities of nonelectrolytes in aqueous electrolyte solutions have traditionally been modeled by using the Setschenow equation for salt effect. The aqueous solubility of tri-n-butyl phosphate (TBP) during operating conditions of the Purex process is an important parameter for safety considerations. Use of the Setschenow equation for aqueous solubility of TBP under limited conditions has been reported in the literature. However, there is no general model available to account for the presence of the diluent and for the case of multicomponent electrolyte solutions in which only some electrolytes are solvated and extracted by TBP. An extended salt effect model is proposed for predicting the aqueous solubility of TBP in a 5 to 100% TBP/n-dodecane-nitric acid-water biphasic system at 298.2 K. The literature data on TBP solubility were correlated to aqueous acid concentration, diluent concentration in the solvents, and an interaction parameter for electrolytic solutes (extracted or not extracted by TBP)

Kumar, Shekhar; Koganti, Sudhir Babu [Indira Gandhi Centre for Atomic Research (India)

2000-02-15T23:59:59.000Z

62

Absolute measurements of nitric acid by kilometer pathlength FT-IR (Fourier transform infrared) spectroscopy and their intercomparison with other measurement methods. Final report  

SciTech Connect

Measurements of ambient nitric acid (HNO/sub 3/) and ammonia (NH/sub 3/) concentrations were conducted using a Fourier transform infrared (FT-IR) spectrometer interfaced to an open-path, multiple-reflection optical system. These measurements provided benchmark data for gaseous HNO/sub 3/ and NH/sub 3/ during a field study, held at Claremont, California, September 11-19, 1985, which compared current analytical methods for determining nitrogenous species concentrations in the atmosphere. Hourly average concentrations of HNO/sub 3/ and NH/sub 3/ are reported, along with the calculated average concentrations for the sampling periods designated for the majority of the other measurement methods.

Winer, A.M.; Tuazon, E.C.; Biermann, H.W.; Wallington, T.J.

1986-05-01T23:59:59.000Z

63

Modeling of the simultaneous extraction of nitric acid and uranyl nitrate with tri-n-butyl phosphate. Application to extraction operation  

SciTech Connect

A mathematical model developed for the equilibrium HNO{sub 3}-UO{sub 2}(NO{sub 3}){sub 2}-tri-n-butyl phosphate (TBP)-diluent is the basis of the computation of distribution isotherms. The isotherms are used to study the influence of TBP concentration on two chosen operation parameters, distribution coefficients and number of theoretical stages, for the selected flow sheets. It is established that an increase in TBP concentration leads to a decrease in the number of theoretical stages for the extraction flow sheets but to their increase for the striping flow sheets. Given diagrams can be used to determine the efficiency of extraction processes. Agreement with available literature calculations on the number of theoretical stages supports the use of the model in the computation of distribution isotherms, of the system quoted above, in a wide range of nitric acid, uranyl nitrate, and TBP concentrations.

Comor, J.J.; Tolic, A.S.; Kopecni, M.M.; Petkovic, D.M. [Vinca Inst. of Nuclear Sciences, Belgrade (Yugoslavia). Chemical Dynamics Lab.] [Vinca Inst. of Nuclear Sciences, Belgrade (Yugoslavia). Chemical Dynamics Lab.

1999-01-01T23:59:59.000Z

64

A Pulse Radiolysis Investigation of the Reactions of Tributyl Phosphate with the Radical Products of Aqueous Nitric Acid Irradiation  

SciTech Connect

Tributyl phosphate (TBP) is the most common organic compound used in liquid-liquid separations for the recovery of uranium, neptunium, and plutonium from acidic nuclear fuel dissolutions. The goal of these processes is to extract the actinides while leaving fission products in the acidic, aqueous, phase. However, the radiolytic degradation of TBP has been shown to reduce the separation factors for fission products, and to impede the back-extraction of the actinides during stripping. As most previous investigations of the radiation chemistry of TBP have focused on steady state radiolysis and stable product identification, with dibutylphosphoric acid (HDBP) invariably being the major product, here we have determined room temperature rate constants for the reactions TBP and HDBP with the hydroxyl radical ((5.00 +/- 0.02) x 109, (4.40 +/- 0.10) x 109), hydrogen atom ((1.8 +/- 0.2) x 108, (1.1 +/- 0.1) x 108), nitrate radical ((4.3 +/- 0.7) x 106, (2.9 +/- 0.2) x 106) and nitrite radical (< 2 x 105, < 2 x 105) M-1 s-1 with TBP and HDBP, respectively. These data are used to discuss the mechanism of TBP radical-induced degradation.

Bruce J. Mincher; Stephen R. Mezyk; Leigh R. Martin

2008-07-01T23:59:59.000Z

65

Recovery of mercury from acid waste residues  

DOE Patents (OSTI)

Mercury can be recovered from nitric acid-containing fluids by reacting the fluid with aluminum metal to produce mercury metal, and then quenching the reactivity of the nitric acid prior to nitration of the mercury metal.

Greenhalgh, Wilbur O. (Richland, WA)

1989-01-01T23:59:59.000Z

66

Recovery of mercury from acid waste residues  

DOE Patents (OSTI)

Mercury can be recovered from nitric acid-containing fluids by reacting the fluid with aluminum metal to produce mercury metal, and thence quenching the reactivity of the nitric acid prior to nitration of the mercury metal. 1 fig.

Greenhalgh, W.O.

1987-02-27T23:59:59.000Z

67

Reactions Between Water Soluble Organic Acids and Nitrates in...  

NLE Websites -- All DOE Office Websites (Extended Search)

Between Water Soluble Organic Acids and Nitrates in Atmospheric Aerosols: Recycling of Nitric Acid and Formation of Reactions Between Water Soluble Organic Acids and Nitrates in...

68

Remedial Investigation Report on the Abandoned Nitric Acid Pipeline at the Oak Ridge Y-12 Plant, Oak Ridge, Tennessee. Energy Systems Environmental Restoration Program; Y-12 Environmental Restoration Program  

SciTech Connect

Upper East Fork Poplar Creek Operable Unit 2 consists of the Abandoned Nitric Acid pipeline (ANAP). This pipeline was installed in 1951 to transport liquid wastes {approximately}4800 ft from Buildings 9212, 9215, and 9206 to the S-3 Ponds. Materials known to have been discharged through the pipeline include nitric acid, depleted and enriched uranium, various metal nitrates, salts, and lead skimmings. During the mid-1980s, sections of the pipeline were removed during various construction projects. A total of 19 locations were chosen to be investigated along the pipeline for the first phase of this Remedial Investigation. Sampling consisted of drilling down to obtain a soil sample at a depth immediately below the pipeline. Additional samples were obtained deeper in the subsurface depending upon the depth of the pipeline, the depth of the water table, and the point of auger refusal. The 19 samples collected below the pipeline were analyzed by the Oak Ridge Y-12 Plant`s laboratory for metals, nitrate/nitrite, and isotopic uranium. Samples collected from three boreholes were also analyzed for volatile organic compounds because these samples produced a response with organic vapor monitoring equipment. Uranium activities in the soil samples ranged from 0.53 to 13.0 pCi/g for {sup 238}U, from 0.075 to 0.75 pCi/g for {sup 235}U, and from 0.71 to 5.0 pCi/g for {sup 238}U. Maximum total values for lead, chromium, and nickel were 75.1 mg/kg, 56.3 mg/kg, and 53.0 mg/kg, respectively. The maximum nitrate/nitrite value detected was 32.0 mg-N/kg. One sample obtained adjacent to a sewer line contained various organic compounds, at least some of which were tentatively identified as fragrance chemicals commonly associated with soaps and cleaning solutions. The results of the baseline human health risk assessment for the ANAP contaminants of potential concern show no unacceptable risks to human health.

Not Available

1994-02-01T23:59:59.000Z

69

Process for the extraction of strontium from acidic solutions  

DOE Patents (OSTI)

The invention is a process for selectively extracting strontium values from aqueous nitric acid waste solutions containing these and other fission product values. The extractant solution is a macrocyclic polyether in an aliphatic hydrocarbon diluent containing a phase modifier. The process will selectively extract strontium values from nitric acid solutions which are up to 6 molar in nitric acid. 4 figs.

Horwitz, E.P.; Dietz, M.L.

1994-09-06T23:59:59.000Z

70

Process for the extraction of strontium from acidic solutions  

DOE Patents (OSTI)

The invention is a process for selectively extracting strontium values from aqueous nitric acid waste solutions containing these and other fission product values. The extractant solution is a macrocyclic polyether in an aliphatic hydrocarbon diluent containing a phase modifier. The process will selectively extract strontium values from nitric acid solutions which are up to 6 molar in nitric acid.

Horwitz, E.P.; Dietz, M.L.

1993-01-01T23:59:59.000Z

71

E-Print Network 3.0 - acid alkyl esters Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

Nitric Acid 34. Sulfuric acid... .5 will not be accepted through this program. Heavy metal, toxic, acidic (without solvents) and basic wastes should... . Mercaptans 4. ......

72

E-Print Network 3.0 - ammonia acetic acid Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

fluminic acid, or hydrogen. NITRIC ACID with: acetic... with: water, carbon dioxide, carbon tetrachloride, and other chlorinated hydrocarbons. ACETIC ACID with......

73

Transuranic decontamination of nitric acid solutions by the TRUEX solvent extraction process: preliminary development studies. [Octyl(phenyl)-N,N-diisobutylcarbamoylmethylphosphine oxide  

SciTech Connect

This report summarizes the work that has been performed to date at Argonne National Laboratory on the development of the TRUEX process, a solvent extraction process employing a bifunctional organophosphorous reagent in a PUREX process solvent (tributyl phosphate-normal paraffinic hydrocarbons). The purpose of this extraction process is to separate and concentrate transuranic (TRU) elements from nuclear waste. Assessments were made of the use of two TRUEX solvents: one incorporating the well-studied dihexyl-N,N-diethylcarbamoylmethylphosphonate (DHDECMP) and a second incorporating an extractant with superior properties for a 1M HNO/sub 3/ acid feed, octyl(phenyl)-N,N-diisobutylcarbamoylmethylphosphine oxide (O/sub phi/D(IB)CMPO). In this report, conceptual flowsheets for the removal of soluble TRUs from high-level nuclear wastes using these two TRUEX proces solvents are presented, and flowsheet features are discussed in detail. The conceptual flowsheet for TRU-element removal from a PUREX waste by the O/sub phi/D(IB)CMPO-TRUEX process solvent was tested in a bench-scale countercurrent experiment, and results of that experiment are presented and discussed. The conclusion of this study is that the TRUEX process is able to separate TRUs from high-level wastes so that the major portion of the solid waste (approx. 99%) can be classified as non-TRU. Areas where more experimentation is needed are listed at the end of the report. 45 references, 17 figures, 56 tables.

Vandegrift, G.F.; Leonard, R.A.; Steindler, M.J.; Horwitz, E.P.; Basile, L.J.; Diamond, H.; Kalina, D.G.; Kaplan, L.

1984-07-01T23:59:59.000Z

74

acid  

Office of Legacy Management (LM)

Acid/Pueblo Canyon, New Mexico, Site is Acid/Pueblo Canyon, New Mexico, Site is located near the town of Los Alamos, New Mexico, approximately 25 miles northwest of Santa Fe and 60 miles north-northeast of Albuquerque. The site is accessible from Canyon Road, which runs just south of the former waste treatment plant. The plant was situated on a mesa that forms the south rim of Acid Canyon. Acid Canyon is a small tributary near the head

75

acid  

NLE Websites -- All DOE Office Websites (Extended Search)

Acid/Pueblo Canyon, New Mexico, Site. Acid/Pueblo Canyon, New Mexico, Site. This site is managed by the U.S. Department of Energy Office of Legacy Management. Site Description and History The Acid/Pueblo Canyon, New Mexico, Site is located near the town of Los Alamos, New Mexico, approximately 25 miles northwest of Santa Fe and 60 miles north-northeast of Albuquerque. The site is accessible from Canyon Road, which runs just south

76

Process for the recovery of strontium from acid solutions  

DOE Patents (OSTI)

The invention is a process for selectively extracting strontium and technetium values from aqueous nitric acid waste solutions containing these and other fission product values. The extractant is a macrocyclic polyether in a diluent which is insoluble in water, but which will itself dissolve a small amount of water. The process will extract strontium and technetium values from nitric acid solutions which are up to 6 molar in nitric acid. 5 figs.

Horwitz, E.P.; Dietz, M.L.

1992-03-31T23:59:59.000Z

77

Controlling acid rain  

E-Print Network (OSTI)

High concentrations of sulfuric and nitric acid in raTn fn the northeastern USA are caused by the large scale combustion of fossil fuels within this region. Average precipitation acidity is pH 4.2, but spatial and temporal ...

Fay, James A.

1983-01-01T23:59:59.000Z

78

Two Dimensional Polymer That Generates Nitric Oxide.  

DOE Patents (OSTI)

A polymeric composition that generates nitric oxide and a process for rendering the surface of a substrate nonthrombogenic by applying a coating of the polymeric composition to the substrate are disclosed. The composition comprises: (1) a crosslinked chemical combination of (i) a polymer having amino group-containing side chains along a backbone forming the polymer, and (ii) a crosslinking agent containing functional groups capable of reacting with the amino groups; and (2) a plurality of nitric oxide generating functional groups associated with the crosslinked chemical combination. Once exposed to a physiological environment, the coating generates nitric oxide thereby inhibiting platelet aggregation. In one embodiment, the nitric oxide generating functional groups are provided by a nitrated compound (e.g., nitrocellulose) imbedded in the polymeric composition. In another embodiment, the nitric oxide generating functional groups comprise N2O2- groups covalently bonded to amino groups on the polymer.

McDonald, William F. (Utica, OH); Koren, Amy B. (Lansing, MI)

2005-10-04T23:59:59.000Z

79

Arginine and Conjugated Linoleic Acid Reduce Fat Mass in Rats  

E-Print Network (OSTI)

????????????????????.. 3 Nitric oxide (NO)????????????????????... 3 NOS synthesis by iNOS and obesity?????????????. 4 Stearoyl CoA desaturase?????????????????? 5 Conjugated linoleic acid?????????????????? 5 MATERIALS... on a liquid scintillation counter. 12 Fatty acid analysis Fatty acid composition in liver and plasma was determined using a fatty acid methylation procedure (FAME). Fatty acids were extracted using Folch et al (38) methods. Methylation...

Nall, Jennifer L.

2010-10-12T23:59:59.000Z

80

Process for combined control of mercury and nitric oxide.  

SciTech Connect

Continuing concern about the effects of mercury in the environment may lead to requirements for the control of mercury emissions from coal-fired power plants. If such controls are mandated, the use of existing flue-gas cleanup systems, such as wet scrubbers currently employed for flue-gas desulfurization, would be desirable, Such scrubbers have been shown to be effective for capturing oxidized forms of mercury, but cannot capture the very insoluble elemental mercury (Hg{sup 0}) that can form a significant fraction of the total emissions. At Argonne National Laboratory, we have proposed and tested a concept for enhancing removal of Hg{sup 0}, as well as nitric oxide, through introduction of an oxidizing agent into the flue gas upstream of a scrubber, which readily absorbs the soluble reaction products. Recently, we developed a new method for introducing the oxidizing agent into the flue-gas stream that dramatically improved reactant utilization. The oxidizing agent employed was NOXSORB{trademark}, which is a commercial product containing chloric acid and sodium chlorate. When a dilute solution of this agent was introduced into a gas stream containing Hg{sup 0} and other typical flue-gas species at 300 F, we found that about 100% of the mercury was removed from the gas phase and recovered in process liquids. At the same time, approximately 80% of the nitric oxide was removed. The effect of sulfur dioxide on this process was also investigated and the results showed that it slightly decreased the amount of Hg{sup 0} oxidized while appearing to increase the removal of nitric oxide from the gas phase. We are currently testing the effects of variations in NOXSORB{trademark} concentration, sulfur dioxide concentration, nitric oxide concentration, and reaction time (residence time). Preliminary economic projections based on the results to date indicate that the chemical cost for nitric oxide oxidation could be less than $5,000/ton removed, while for Hg{sup 0} oxidation it would be about $20,000/lb removed.

Livengood, C. D.; Mendelsohn, M. H.

1999-11-03T23:59:59.000Z

Note: This page contains sample records for the topic "nitric acid cxs" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Oleic AcidDependent Modulation of NITRIC OXIDE ASSOCIATED1 Protein Levels Regulates Nitric  

E-Print Network (OSTI)

the generation of monounsaturated FA in plant cells (Shanklin and Cahoon, 1998; Kachroo et al., 2007

Kachroo, Pradeep

82

Ovarian nitric oxide synthase gene expression during peripubertal development  

E-Print Network (OSTI)

Nitric oxide (NO) is generated from L-arginine by different isoforms of the enzyme nitric oxide synthase. (NOS) and is known to be involved in mediating several biological functions, some of which are associated with reproduction. Much attention...

Jones, Benjamin James

1997-01-01T23:59:59.000Z

83

Mechanism of Nitric Oxide Reactivity and Fluorescence Enhancement of the NO-Specific Probe CuFL1  

E-Print Network (OSTI)

The mechanism of the reaction of CuFL1 (FL1 = 2-{2-chloro-6-hydroxy-5-[(2-methylquinolin-8-ylamino)methyl]-3-oxo-3H-xanthen-9-yl}benzoic acid) with nitric oxide (NO) to form the N-nitrosated product FL1-NO in buffered ...

McQuade, Lindsey E.

84

Hyponitrite Radical, a Stable Adduct of Nitric Oxide and Nitroxyl  

NLE Websites -- All DOE Office Websites (Extended Search)

Publications: Sergei V. Lymar Publications: Sergei V. Lymar Hyponitrite Radical, a Stable Adduct of Nitric Oxide and Nitroxyl G. A. Poskrebyshev, V. Shafirovich and S. V. Lymar J. Am. Chem. Soc., ASAP Article Rate of ON-OO- Bond Homolysis and the Gibbs Energy of Formation of Peroxynitrite S. V. Lymar and G. A. Poskrebyshev J. Phys. Chem. A, 107, 7991-7996 (2003) Spin-Forbidden Deprotonation of Aqueous Nitroxyl (HNO) V. Shafirovich and S. V. Lymar J. Am. Chem. Soc., 125, 6547-6552 (2003) Hydroxyl Radical Formation by O-O Bond Homolysis in Peroxynitrous Acid S. V. Lymar, R. F. Khairutdinov and J. K. Hurst Inorg. Chem., 42, 5259-5266 (2003) Reactions of the Dihydroxylamine (HNO2-.) and Hydronitrite (NO22-.) Radical Ions S. V. Lymar, H. A. Schwarz and G. Czapski J. Phys. Chem. A, 106, 7245-7250 (2002)

85

Relation of the Potash Removed by Crops to the Active, Total, Acid-Soluble, and Acid-Insoluble Potash of the Soil.  

E-Print Network (OSTI)

corresponding fertilizer. The American Association of Official Agricultural Chemists (3), through various Referees, undertook studies of citric acid and other solvents. Nitric acid 0.2 N with correction for neutralization was adopted as official for several... of their potash to 1.2 nitric acid; .biotite and glauconite less than 10 per cent; and microcline and orthoclase prac- tically none, as shown in Texas Bulletin 145. (3) The solubility of soil materials which protect or enclose potash minerals. (4) The power...

Fraps, G. S. (George Stronach)

1927-01-01T23:59:59.000Z

86

The Relation of the Phosphoric Acid of the Soil to Pot Experiments.  

E-Print Network (OSTI)

by crops grown in the pot experiments, on an average, increased regularly with the amount of active phosphoric acid extracted from the soil by N/5 nitric acid. It was pointed out that the soil may pro- vide sufficient phosphoric acid for large field... potash were determined by so*lution in fifth-noml nitric acid, without correction for the acid neutralized. They are expressed in parts per million. The acid con- ~umed represents the percentage of the acid neutralized in the process of extracting...

Fraps, G. S. (George Stronach)

1920-01-01T23:59:59.000Z

87

Active Phosphoric Acid and Its Relation to the Needs of the Soil for Phosphoric Acid in Pot Experiments.  

E-Print Network (OSTI)

. K/5 nitric acid, measured with a flask. Place in ter bath previously heated to 40" C. Digest five hours, shak- ?very half hour. Filter on a large'double folded filter. When cola, take 1800 c.c. for the estimation of phosphoric acid and potael... and silica. The filtrate was measured ancl its vol- ume recorded. The soil on the filter paper was washed back into the bottle with 2000 c.c. N,'5 nitric acid, and again digested. Fonr treatments in all were made with the acid, The quantity of phosphorjc...

Fraps, G. S. (George Stronach)

1909-01-01T23:59:59.000Z

88

Relation of the Water-Soluble Potash, the Replaceable and Acid-Soluble Potash to the Potash Removed by Crops in Pot Experiments.  

E-Print Network (OSTI)

ammonia. This acid is 3.33 N. Digest 10 grams soil for 24 hours with 100 c.c. of the above hydrochloric acid at room temperature, shaking occasionally. Filter and wash with hot water. Add 1 c.c. nitric acid. Evaporate to dryness and heat on steam bath... of the soil with nitric acid become greater as the potash taken up by crops increases. Correlation coefficients for the factors studied show close relations between them. Correction of the 0.2N nitric acid for neutralization by the bases of the soil...

Fraps, G. S. (George Stronach)

1929-01-01T23:59:59.000Z

89

E-Print Network 3.0 - amperometric nitric oxide Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

behavioral... Ref. Neurotransmitters and related compounds Nitric oxide (nitrite) Carbon fiber End-channelInt 8... been studied by microchip CEEC is nitric oxide (NO). NO...

90

E-Print Network 3.0 - acid resistance test Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

> >> 1 JOURNAL OF MATERIALS SCIENCE 32 (1997) 1711--1715 Carbon blackhigh density polyethylene conducting Summary: treated with nitric acid for reaction times of 3, 12 and 24 h....

91

E-Print Network 3.0 - acid based black Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

> >> 1 JOURNAL OF MATERIALS SCIENCE 32 (1997) 1711--1715 Carbon blackhigh density polyethylene conducting Summary: surface. 2.2. Nitric acid treatment 200 g of the high structure...

92

E-Print Network 3.0 - acide nitrique concentre Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

Soc. (1970),%, pp. 320-325 551.510.41 :551.510.534 Summary: on and determinations of nitric acid concentrations in the stratosphere by Murcray, Kyle, Murcray and Williams...

93

Distribution of 1-butanol between organic solvent and acidic solution  

SciTech Connect

1-butanol, a major TBP-degraded product, is known to react explosively with concentrated nitric acid under non-heated conditions. However, no quantitative data is available on the distribution behavior in the Purex solution. The distribution of 1-butanol between tributyl phosphate(TBP) diluted with n-dodecane and aqueous solution of nitric acid and uranyl nitrate was investigated under various conditions, by changing the concentration of nitric acid, uranyl nitrate, the composition of the organic mixture, the organic to aqueous phase volume ratio, and temperature. 1-butanol was found to distribute more in solvent phase, but the distribution ratio is not large, less than four under typical Purex solution conditions. The ratio was found to be correlated with the molar concentration of free TBP and 1-butanol. Effects of these characteristics on safety in radiochemical plants will be discussed from the local accumulation of 1-butanol.

Asakura, T.; Nemoto, H.; Uchiyama, G. [Japan Atomic Energy Research Institute, Ibaraki-ken (Japan)] [and others

1995-12-01T23:59:59.000Z

94

Prediction of nitric oxide concentrations during inflammation and carcinogenesis  

E-Print Network (OSTI)

Nitric oxide is a biological messenger which is synthesized enzymatically throughout the body and which has numerous physiological functions, including roles in blood pressure control, regulation of clotting, and ...

Chin, Melanie Pei-Heng

2010-01-01T23:59:59.000Z

95

Arabidopsis Nonsymbiotic Hemoglobin AHb1 Modulates Nitric Oxide Bioactivity  

Science Journals Connector (OSTI)

...nitric oxide (NO) involves an array of interrelated redox forms with different chemical...is involved in diverse physiological processes, including disease resistance, growth...concentrations far below those at which anaerobic processes are activated. Thus, it is unlikely...

Michele Perazzolli; Paola Dominici; Maria C. Romero-Puertas; Elisa Zago; Jürgen Zeier; Masatoshi Sonoda; Chris Lamb; Massimo Delledonne

2004-09-14T23:59:59.000Z

96

Hydrogen peroxide differentially modulates cardiac myocyte nitric oxide synthesis  

E-Print Network (OSTI)

Nitric oxide (NO) and hydrogen peroxide (H(subscript 2)O(subscript 2)) are synthesized within cardiac myocytes and play key roles in modulating cardiovascular signaling. Cardiac myocytes contain both the endothelial (eNOS) ...

Sartoretto, Juliano

97

One-pot room-temperature conversion of cyclohexane to adipic acid by ozone and UV light  

Science Journals Connector (OSTI)

...nitric acid oxidation method (3). The first step is air oxidation of cyclohexane under high temperatures (125° to 165...Finlayson-Pitts B. J. Pitts J. N. Jr. , Tropospheric air pollution: Ozone, airborne toxics, polycyclic aromatic hydrocarbons...

Kuo Chu Hwang; Arunachalam Sagadevan

2014-12-19T23:59:59.000Z

98

E-Print Network 3.0 - agmatine attenuates nitric Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

attenuates nitric Page: << < 1 2 3 4 5 > >> 1 Learning and memory in agmatine-treated rats B.E. McKay*, W.E. Lado1 Summary: . Inhibition of mammalian nitric oxide synthases by...

99

Reference electrode for strong oxidizing acid solutions  

DOE Patents (OSTI)

A reference electrode for the measurement of the oxidation-reduction potentials of solutions is especially suitable for oxidizing solutions such as highly concentrated and fuming nitric acids, the solutions of nitrogen oxides, N.sub.2 O.sub.4 and N.sub.2 O.sub.5, in nitric acids. The reference electrode is fabricated of entirely inert materials, has a half cell of Pt/Ce(IV)/Ce(III)/70 wt. % HNO.sub.3, and includes a double-junction design with an intermediate solution of 70 wt. % HNO.sub.3. The liquid junctions are made from Corning No. 7930 glass for low resistance and negligible solution leakage.

Rigdon, Lester P. (Livermore, CA); Harrar, Jackson E. (Castro Valley, CA); Bullock, Sr., Jack C. (Pleasanton, CA); McGuire, Raymond R. (Brentwood, CA)

1990-01-01T23:59:59.000Z

100

Measurement of nitric oxide with an antimonide diode laser  

E-Print Network (OSTI)

lasers while retaining the practical advantages of room- temperature or thermoelectrically cooled the selective detection of NO under reduced pressure conditions was identified. With wavelength- modulation cooling is not required. © 1997 Optical Society of America Key words: Diode laser, antimonide, nitric

Note: This page contains sample records for the topic "nitric acid cxs" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Oxidation of trace amounts of transplutonium elements to the tetravalent state in solutions of mineral acids and their stabilities  

SciTech Connect

The behavior of trace amounts of americium(IV) in sulfuric and nitric acid solutions as a function of the mineral acid, potassium phosphotungstate, and ammonium persulfate concentrations was investigated. The stability of americium(IV) was studied. The optimal conditions and time of oxidation of trace amounts of americium to the tetravalent state were found on the basis of the experimental data obtained.

Milyukova, M.S.; Varezhkina, N.S.; Kuzovkina, E.V.; Malikov, D.A.; Myasoedov, B.F.

1989-01-01T23:59:59.000Z

102

Personal and Ambient Air Pollution is Associated with Increased Exhaled Nitric Oxide in Children with Asthma  

E-Print Network (OSTI)

1994. Nitric oxide and nitrogen dioxide: Method 6014. In:Molecular mechanisms of nitrogen dioxide induced epithelialEC, OC), and 24-hr nitrogen dioxide. Ambient exposures

2006-01-01T23:59:59.000Z

103

Electronic Structure Calculations on the Reaction of Vinyl Radical with Nitric Oxide  

Science Journals Connector (OSTI)

Electronic Structure Calculations on the Reaction of Vinyl Radical with Nitric Oxide ... Methyl isocyanate 19 is calculated to be the most stable isomer. ... Methods of Calculation ...

Raman Sumathi; Hue Minh Thi Nguyen; Minh Tho Nguyen; Jozef Peeters

2000-02-15T23:59:59.000Z

104

The Effect of Rock Phosphate Upon the Corn Possibility of Phosphoric Acid of the Soil  

E-Print Network (OSTI)

of Veterinary Medicine, A. and M. College of Texas. **In cooperation with United Statee Department of Agriculture. THE EFFECT OF ROCK PHOSPHATE UPON THE CORN POS- SIBILITY OF PHOSPHORIC ACID OF THE SOIL. In connection vith oil-fertilit~ stuclies..., it is important to lcnow the relation between the effect of the phosphoric acid of the rock phosphate on crops and the phosphoric acid that can be withdrawn from the soil by crops. The phosphoric acid of rock phosphate is readily soluble in K/5 nitric acid...

Fraps, G. S. (George Stronach)

1922-01-01T23:59:59.000Z

105

Type B Accident Investigation of the Acid Vapor Inhalation on June 7, 2005, in TA-48, Building RC-1 Room 402 at the Los Alamos National Laboratory  

Energy.gov (U.S. Department of Energy (DOE))

During the afternoon of June 7, 2005, two postdoctoral (postdoc) employees working at the Los Alamos National Laboratory (LANL) inhaled acid vapors generated by the use of aqua regia (a mixture of hydrochloric and nitric acids) to clean glassware on a laboratory benchtop.

106

{open_quotes}Open vessel{close_quotes} heat balance for TBP-nitric acid solutions  

SciTech Connect

Heat balances were performed for both single phase (organic) and two phase (organic and aqueous) TBP/HNO{sub 3} solutions at temperatures above 100{degrees}C. The balance included the heat produced from oxidation minus losses from evaporation and butylnitrate formation by esterification. Net heat measurements were performed using an isothermal calorimeter. Losses from evaporation were determined from the volume of condensate produced (ice bath trap) and the component concentrate Carbon and nitrogen balances were performed to determine the stoichiometry of the reaction. The heat from oxidation was then calculated using the heats of formation of the reactants and products. Balances were obtained assuming that the heat from esterification was near zero (negligibly small). For two layered reaction systems the net heat was maintained endothermic, and constant with time, due to the transport of water to the organic phase by bubble mixing at the interface. This transported was replaced the water lost in the organic phase by evaporation.

Smith, J.R.; Cavin, W.S.; Laurinat, J.E. [Westinghouse Savannah River Company, Aiken, SC (United States)

1995-12-31T23:59:59.000Z

107

FT-IR spectroscopy of nitric acid in TBP/octane solution.  

SciTech Connect

Infrared studies for the HNO{sub 3}/0.73 M TBP n-octane system are reported. Two extracted species, TBP {center_dot} HNO{sub 3} and TBP {center_dot} 2HNO{sub 3}, were identified in the organic phase. The concentration of the individual species was determined by the analysis of the vibrational band at {approx}1650 cm{sup -1}. The band at 1648 cm{sup -1} was assigned to the monosolvate TBP {center_dot} HNO{sub 3} and the band at 1672 cm{sup -1} to the hemisolvate TBP {center_dot} 2HNO{sub 3}. The infrared spectra revealed that with respect to the P{double_bond}O bond, as well to each other, the HNO{sub 3} molecules in the hemisolvate are spectrally non-equivalent. The predominant structure of TBP {center_dot} 2HNO{sub 3} involves the chain HNO{sub 3} dimer. Some ionic NO{sub 3}{sup -} and hydronium ions were identified in this system but only during formation of the monosolvate. The analyses performed in this system can serve for the characterization of HNO{sub 3} in related systems in the presence of metal species.

Ferraro, J. R.; Borkowski, M.; Chiarizia, R.; McAlister, D. R.; Chemistry; Loyola Univ. Chicago

2001-01-01T23:59:59.000Z

108

Disposition and transportation of surplus radioactive low specific activity nitric acid. Volume 2, Environmental Assessment  

SciTech Connect

This volume consists of two appendices: public comments and DOE responses, and public comments not requiring responses.

NONE

1995-05-01T23:59:59.000Z

109

Nitric acid cycle process for extracting thermal energy from low-level heat sources  

Science Journals Connector (OSTI)

... ENORMOUS amounts of solar energy are stored in the tropical oceans. The first attempt to recover this ' ... energy are stored in the tropical oceans. The first attempt to recover this 'solar sea energy' from the tropical oceans, using the temperature difference between the warm surface ...

N. Wakao; K. Nojo

1978-05-04T23:59:59.000Z

110

Elevation in Exhaled Nitric Oxide Predicts for Radiation Pneumonitis  

SciTech Connect

Purpose: Radiation pneumonitis is a major toxicity after thoracic radiotherapy (RT), with no method available to accurately predict the individual risk. This was a prospective study to evaluate exhaled nitric oxide as a predictive biomarker for radiation pneumonitis in esophageal cancer patients. Patients and Methods: A total of 34 patients prescribed neoadjuvant chemoradiotherapy for esophageal cancer were enrolled in the present trial. Each patient underwent respiratory surveys and exhaled nitric oxide (NO) measurements before, at the end of, and 1 to 2 months after completing RT. Pneumonitis toxicity was scored using the Common Terminology Criteria for Adverse Events, version 4.0. The demographics, dosimetric factors, and exhaled NO levels were evaluated for correlation with symptomatic patients (scores {>=}2). Results: Of the 34 patients, 28 were evaluable. All had received 50.4 Gy RT with concurrent chemotherapy. The pneumonitis toxicity score was Grade 3 for 1, Grade 2 for 3, Grade 1 for 7, and Grade 0 for 17. The dosimetric factors were not predictive of symptoms. The mean exhaled NO level measured before, at completion, and at restaging was 17.3 {+-} 8.5 (range, 5.5-36.7), 16.0 {+-} 14.2 (range, 5.8-67.7), and 14.7 {+-} 6.2 (range, 5.5-28.0) parts per billion, respectively. The ratio of exhaled NO at the end of RT vs. before treatment was 3.4 (range, 1.7-6.7) for the symptomatic and 0.8 (range, 0.3-1.3) for the asymptomatic (p = .0017) patients. The elevation in exhaled NO preceded the peak symptoms by 33 days (range, 21-50). The interval to peak symptoms was inversely related to the exhaled NO elevation. Conclusions: Elevations in exhaled NO at the end of RT was found to predict for radiation pneumonitis symptoms.

Guerrero, Thomas, E-mail: tguerrero@mdanderson.org [Division of Radiation Oncology, University of Texas M. D. Anderson Cancer Center, Houston, TX (United States); University of Texas Graduate School of Biomedical Sciences at Houston, Houston, TX (United States); Martinez, Josue [Department of Statistics, Texas A and M University, College Station, TX (United States); McCurdy, Matthew R. [Department of Radiation Oncology, Baylor College of Medicine, Houston, TX (United States); Wolski, Michael [Department of Radiation Oncology, University of Texas Medical Branch, Galveston, TX (United States); McAleer, Mary Francis [Division of Radiation Oncology, University of Texas M. D. Anderson Cancer Center, Houston, TX (United States)

2012-02-01T23:59:59.000Z

111

Thermal Stability Of Formohydroxamic Acid  

SciTech Connect

The thermal stability of formohydroxamic acid (FHA) was evaluated to address the potential for exothermic decomposition during storage and its use in the uranium extraction process. Accelerating rate calorimetry showed rapid decomposition at a temperature above 65 {degree}?C; although, the rate of pressure rise was greater than two orders of magnitude less than the lower bound for materials which have no explosive properties with respect to transportation. FHA solutions in water and nitric acid did not reach runaway conditions until 150 {degree}?C. Analysis by differential scanning calorimetry showed that FHA melted at 67 {degree}?C and thermally decomposed at 90 {degree}?C with an enthalpy of -1924 J/g. The energics of the FHA thermal decomposition are comparable to those measured for aqueous solutions of hydroxylamine nitrate. Solid FHA should be stored in a location where the temperature does not exceed 20-25 {degree}?C. As a best practice, the solid material should be stored in a climate-controlled environment such as a refrigerator or freezer. FHA solutions in water are not susceptible to degradation by acid hydrolysis and are the preferred way to handle FHA prior to use.

Fondeur, F. F.; Rudisill, T. S.

2011-10-21T23:59:59.000Z

112

Solvent Extraction Behavior of Plutonium (IV) Ions in the Presence of Simple Hydroxamic Acids  

SciTech Connect

Formo-and aceto-hydroxamic acids are very effective reagents for stripping Pu(IV) ions from a tri-butyl phosphate phase into nitric acid. Distribution data for Pu(IV) in the presence of these hydroxamate ions have been obtained and trends established. The affinity of aceto-hydroxamic acid for Pu(IV) ions and its selectivity over U(VI) ions is demonstrated by the values of the stability constants in HCIO4. These data support the applications of simple hydroxamic acids in advanced Purex-type solvent extraction systems.

Carrott, M. J.; Fox, O. D.; Maher, C. J.; Mason, C.; Taylor, Robin J.; Sinkov, Sergey I.; Choppin, Gregory R.

2007-11-15T23:59:59.000Z

113

Corrosion Testing of Carbon Steel in Acid Cleaning Solutions  

SciTech Connect

High level waste is stored in carbon steel tanks at the Savannah River Site (SRS). The site is currently in the process of waste removal from, and ultimately closure of, these tanks. One of the most time consuming steps in the waste removal process is cleaning the sludge heel from the bottom of the tanks to an acceptable residual quantity. The sludge consists primarily of metal oxides that formed after waste from the canyons was neutralized with sodium hydroxide. Since the canyon waste was originally a nitric acid solution, this acid is a prime candidate for sludge heel dissolution.

Wiersma, B.J.

2002-12-06T23:59:59.000Z

114

Measurement of Nitric Oxide Production from Lymphatic Entothelial Cells Under Mechanical Stimuli  

E-Print Network (OSTI)

mechanisms to pump lymph. Intrinsic pumping involves the active contraction of vessels, a phenomenon that is regulated in part by nitric oxide (NO) produced by lymphatic endothelial cells (LECs). NO production by arterial endothelial cells has been shown...

Jafarnejad, Mohammad 1987-

2012-11-16T23:59:59.000Z

115

Nitric oxide inhibits the production of soluble endothelin converting enzyme-1  

Science Journals Connector (OSTI)

This study examined the effect of nitric oxide on the production of soluble ECE-1. Activity of ECE-1 in media was measured using a quenched fluorescent substrate assay, and expressed as a percentage of control...

Sanjaya Kuruppu; Niwanthi W. Rajapakse…

2014-11-01T23:59:59.000Z

116

Two-photon nitric oxide laser-induced fluorescence measurements in a diesel engine  

Science Journals Connector (OSTI)

A two-photon nitric oxide (NO) laser-induced fluorescence (LIF) technique was developed and applied to study in-cylinder diesel combustion. The technique prevents many problems...

Martin, Glen C; Mueller, Charles J; Lee, Chia-Fon F

2006-01-01T23:59:59.000Z

117

Turn-on fluorescent probes for detecting nitric oxide in biology  

E-Print Network (OSTI)

Chapter 1. Investigating the Biological Roles of Nitric Oxide and Other Reactive Nitrogen Species Using Fluorescent Probes: This chapter presents an overview of recent progress in the field of reactive nitrogen species ...

McQuade, Lindsey Elizabeth, 1981-

2010-01-01T23:59:59.000Z

118

Quantum Cascade Laser Technology for the Ultrasensitive Detection of Low-Level Nitric Oxide  

Science Journals Connector (OSTI)

Several spectroscopic methods based on mid-infrared quantum cascade lasers for the ultrasensitive detection of nitric oxide ... the most effective techniques, i.e., laser absorption spectroscopy, cavity-enhanced ...

Angela Elia; Pietro Mario Lugarà; Cinzia Di Franco; Vincenzo Spagnolo

2011-01-01T23:59:59.000Z

119

Pathophysiology of endotoxin: microvascular dysfunction, and the roles of VEGF and nitric oxide (NO)  

E-Print Network (OSTI)

PATHOPHYSIOLOGY OF ENDOTOXIN: MICROVASCULAR DYSFUNCTION, AND THE ROLFS OF VEGF AND NITRIC OXIDE (NO) A Senior Honors Thesis bt MARK ANDREW NAFTANFL Submitted to the Olfice of Honors Programs A. Academic Scholarships Texas A&M University ln...

Naftanel, Mark Andrew

2013-02-22T23:59:59.000Z

120

Cell-Trappable Fluorescent Probes for Nitric Oxide Visualization in Living Cells  

E-Print Network (OSTI)

Two new cell-trappable fluorescent probes for nitric oxide (NO) are reported based on either incorporation of hydrolyzable esters or conjugation to aminodextran polymers. Both probes are highly selective for NO over other ...

Pluth, Michael D.

Note: This page contains sample records for the topic "nitric acid cxs" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Hyperbaric oxygen and hypoxia alter production of nitric oxide by J774 murine macrophages  

E-Print Network (OSTI)

Improvements in rates of healing of wounds and bacterial clearance in infected tissue during intermittent exposure to hyperbaric oxygen (HBO) have been documented. Increased bacterial clearance may partly stem from changes in production of nitric...

Burden, Kyland Irle

2012-06-07T23:59:59.000Z

122

Seminaphthofluorescein-Based Fluorescent Probes for Imaging Nitric Oxide in Live Cells  

E-Print Network (OSTI)

Fluorescent turn-on probes for nitric oxide based on seminaphthofluorescein scaffolds were prepared and spectroscopically characterized. The Cu(II) complexes of these fluorescent probes react with NO under anaerobic ...

Pluth, Michael D.

123

The catalytic reduction of nitric oxide with ammonia over tetraamminecopper (II) complexes  

E-Print Network (OSTI)

THE CATALETIC REDUCTION OF NITRIC OXIDE NITH AMMONIA OVER TETRARPMINECOPPER(11) COMPLEXES A Thesis by Margaret Deron Oates Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirement for the degree... of MASTER OF SCIENCE August 1979 Major Subject: Chemistry THE CATALYTIC REDUCTION OF NITRIC OXIDE WITH AMMONIA OVER TETRAAMMINECOPPER(IZ) COMPLEXES A Thesis by Margaret Deron Dates Approved as to style and content by: (Chairman of Committe (Member...

Oates, Margaret Deron

1979-01-01T23:59:59.000Z

124

Arsenic toxicity induced endothelial dysfunction and dementia: Pharmacological interdiction by histone deacetylase and inducible nitric oxide synthase inhibitors  

SciTech Connect

Arsenic toxicity has been reported to damage all the major organs including the brain and vasculature. Dementia including Alzheimer's disease (AD) and vascular dementia (VaD) are posing greater risk to the world population as it is now increasing at a faster rate. We have investigated the role of sodium butyrate, a selective histone deacetylase (HDAC) inhibitor and aminoguanidine, a selective inducible nitric oxide synthase (iNOS) inhibitor in pharmacological interdiction of arsenic toxicity induced vascular endothelial dysfunction and dementia in rats. Arsenic toxicity was done by administering arsenic drinking water to rats. Morris water-maze (MWM) test was used for assessment of learning and memory. Endothelial function was assessed using student physiograph. Oxidative stress (aortic superoxide anion, serum and brain thiobarbituric acid reactive species, brain glutathione) and nitric oxide levels (serum nitrite/nitrate) were also measured. Arsenic treated rats have shown impairment of endothelial function, learning and memory, reduction in serum nitrite/nitrate and brain GSH levels along with increase in serum and brain TBARS. Sodium butyrate as well as aminoguanidine significantly convalesce arsenic induced impairment of learning, memory, endothelial function, and alterations in various biochemical parameters. It may be concluded that arsenic induces endothelial dysfunction and dementia, whereas, sodium butyrate, a HDAC inhibitor as well as aminoguanidine, a selective iNOS inhibitor may be considered as potential agents for the management of arsenic induced endothelial dysfunction and dementia. - Highlights: • As has induced endothelial dysfunction (Edf) and vascular dementia (VaD). • As has increased oxidative stress, AChE activity and decreased serum NO. • Inhibitors of HDAC and iNOS have attenuated As induced Edf and VaD. • Both the inhibitors have attenuated As induced biochemical changes. • Inhibitor of HDAC and iNOS has shown good potential in As induced VaD.

Sharma, Bhupesh, E-mail: drbhupeshresearch@gmail.com; Sharma, P.M.

2013-11-15T23:59:59.000Z

125

Nitric oxide emissions from the high-temperature viscous boundary layers of hypersonic aircraft within the stratosphere  

SciTech Connect

The authors study the nitric oxide emission characteristics of supersonic aircraft resulting from heating of viscous boundary layers along the skin of the aircraft. Previous study has concentrated on nitric oxide emissions coming from combustion products from the scramjet engines. This work shows that above mach 8, emissions from viscous heating become a significant factor in total emission of nitric oxide. Above mach 16 it becomes the dominant source of emission.

Brooks, S.B.; Lewis, M.J.; Dickerson, R.R. [Univ. of Maryland, College Park, MD (United States)

1993-09-20T23:59:59.000Z

126

Superior catalysts for selective catalytic reduction of nitric oxide. Quarterly technical progress report, April 1, 1995--June 30, 1995  

SciTech Connect

Efforts continued towards the synthesis of new pillared clay catalysts for the selective catalytic reduction of nitric oxide by ammonia. The possibility of utilizing hydrocarbons was also investigated.

Li, W.B.; Yang, R.T.

1995-12-01T23:59:59.000Z

127

Alternative Non-Acid Eluants for Spherical Resorcinol-Formaldehyde  

SciTech Connect

Small-column ion exchange (SCIX) units installed in or near high-level waste tanks to remove Cs-137 from highly alkaline solutions are among the waste treatment plans in the DOE Complex. Spherical Resorcinol-Formaldehyde (sRF) is the ion exchange (IX) resin under consideration for SCIX at the Hanford site. The elution step of the multi-step IX process is typically done with nitric acid. An acid eluant is a potential hazard in the event of a spill, leak, etc. because the waste tanks are made of carbon steel. Corrosion and associated structural damage may ensue. A non-acid eluant may be a viable alternative. It will eliminate the need for special acid handling requirements within the tank farms.

Adu-Wusu, Kofi

2010-11-01T23:59:59.000Z

128

Nitric Oxide Photogeneration from trans-Cr(cyclam)(ONO)2+ in a Reducing Environment. Activation of Soluble Guanylyl Cyclase and Arterial Vasorelaxation  

Science Journals Connector (OSTI)

We also demonstrate that photolysis of 1 in the nM concentration range with a portable blue LED leads to vasorelaxation of porcine coronary arterial rings, a process also attributed to the NO activation of sGC. ... Abbreviations: BSA, bovine serum albumin; CFL, compact fluorescent light-bulb; cGMP, cyclic guanosine monophosphate; cyclam, 1,4,8,11-tetraazacyclotetradecane; DEA/NO, (Z)-l-(N,N-diethylamino)-diazen-l-ium-l,2-diolate; EDTA, ethylenediaminetetraacetic acid; GSH, glutathione; GTP, guanosine triphosphate; sGC, soluble guanylyl cyclase; IBMX, isobutylmethylxanthine; LED, light emitting diode; NO, nitric oxide; NOA, nitric oxide analyzer; ODQ, 1H-[1,2,4]oxadiazolo[4,3-a]quinoxalin-1-one; U46619, 9,11-dideoxy-ll?,9?-epoxy-methanoprostaglandin F2?. ... data show that the expected fluorescence of the pendant chromophores is largely quenched when the macrocyclic ligand is coordinated to these Cr(III) centers, and this is interpreted in terms of fast energy transfer processes from the ligand-centered ??* states to the Cr(III)-centered ligand field states leading to subsequent cleavage of the Cr(III)-coordinated nitrito ligand. ...

Alexis D. Ostrowski; Sherine J. Deakin; Bilal Azhar; Thomas W. Miller; Nestor Franco; Melisa M. Cherney; Andrea J. Lee; Judith N. Burstyn; Jon M. Fukuto; Ian L. Megson; Peter C. Ford

2009-12-01T23:59:59.000Z

129

Acidic dissolution behavior of U containing ZrO2–MgO ceramics  

SciTech Connect

This study explores the possibility of dissolving zirconia-magnesia inert matrix fuel containing uranium oxide as a fissile material and plutonium homolog and erbium oxide as a burnable poison with nitric and sulfuric acid as a potential first step in a reprocessing scheme. The progress of the dissolution is followed by monitoring the amount of material in solution by inductively coupled plasma-atomic emission spectroscopy, assessing the speciation of the material by time resolved laser fluorescence spectroscopy, and determining and quantifying the crystalline phases present in the remaining residue by X-ray diffraction. This study has shown a linear incongruent dissolution of the cubic zirconia phase in concentrated nitric acid under certain chemical compositions, while the magnesium oxide phase is completely soluble. In sulfuric acid uranium, erbium, and magnesium are soluble to different extents while zirconium forms a colloidal suspension that conglomerates and settles out of solution. The feasibility of the dissolution of zirconia-magnesia inert matrix fuel with nitric and sulfuric acid for reprocessing is discussed.

Kiel Holliday; Nicholas Smith; Thomas Hartmann; Gary Cerefice; Ken Czerwinski

2011-11-01T23:59:59.000Z

130

EVALUATION OF POTENTIAL ELUANTS FOR NON-ACID ELUTION OF CESIUM FROM RESORCINOL-FORMALDEHYDE RESIN  

SciTech Connect

Small-column ion exchange (SCIX) units installed in high-level waste tanks to remove Cs-137 from highly alkaline salt solutions are among the waste treatment plans in the DOE-complex. Spherical Resorcinol-Formaldehyde (sRF) is the ion exchange resin selected for use in the Hanford Waste Treatment and Immobilization Plant (WTP). It is also the primary ion exchange material under consideration for SCIX at the Hanford site. The elution step of the multi-step ion exchange process is typically done with 0.5 M nitric acid. An acid eluant is a potential hazard in the event of a spill, leak, etc. because the high-level waste tanks are made of carbon steel. Corrosion and associated structural damage may ensue. A study has been conducted to explore non-acid elution as an alternative. Batch contact sorption equilibrium screening tests have been conducted with 36 potential non-acid eluants. The sorption tests involve equilibrating each cesium-containing eluant solution with the sRF resin for 48 hours at 25 C in a shaker oven. In the sorption tests, an eluant is deemed to have a high cesium elution potential if it minimizes cesium sorption onto the sRF resin. The top candidates (based on lowest cesium sorption distribution coefficients) include ammonium carbonate, ammonium carbonate/ammonium hydroxide, ammonium bicarbonate, rubidium carbonate, ammonium acetate, ammonium acetate/ammonium hydroxide, ammonium bicarbonate/ammonium hydroxide, calcium chloride, and magnesium chloride. A select few of the top candidate eluants from the screening tests were subjected to actual sorption (loading) and elution tests to confirm their elution ability. The actual sorption (loading) and elution tests mimicked the typical sRF-cesium ion exchange process (i.e., sorption or loading, caustic wash, water rinse, and elution) via batch contact sorption and quasi column caustic wash/water rinse/elution. The eluants tested included ammonium carbonate, ammonium acetate, calcium acetate, magnesium acetate, and nitric acid. Calcium acetate and magnesium acetate were substitutes for calcium chloride and magnesium chloride respectively due to corrosion concerns. Nitric acid was selected for benchmarking since it is the baseline cesium eluant for sRF resin. The cesium elution performance of ammonium carbonate and ammonium acetate was approximately the same as the benchmark eluant, nitric acid. Ninety-seven (97), 94, and 100% percent of the cesium sorbed or loaded were eluted by ammonium carbonate, ammonium acetate, and nitric acid was respectively. The performance of calcium acetate and magnesium acetate, on the other hand, was mediocre. Percent elution was 16 and 8 respectively.

Adu-Wusu, K.; Pennebaker, F.

2010-12-22T23:59:59.000Z

131

Suppressive effects of glucagon-like peptide-1 on interferon-?-induced nitric oxide production in insulinproducing cells is mediated by inhibition of tumor necrosis factor-? production  

Science Journals Connector (OSTI)

During the development of Type 1 diabetes, inflammatory cytokines are known to induce the expression of inducible nitric oxide synthase (iNOS) in pancreatic islets, and subsequent production of nitric oxide (N...

E. Hahm; Y. S. Lee; H. S. Jun PhD

2008-04-01T23:59:59.000Z

132

A quantum chemical study of nitric oxide reduction by ammonia (SCR reaction) on V2O5 catalyst surface  

E-Print Network (OSTI)

A quantum chemical study of nitric oxide reduction by ammonia (SCR reaction) on V2O5 catalyst for the selective catalytic reduction (SCR) of nitric oxide by ammonia on (0 1 0) V2O5 surface represented by a V2O9/6-31G** level. The computations indicated that SCR reaction consisted of three main parts

Senkan, Selim M.

133

Nitrite–dependent nitric oxide production pathway: implications for involvement of active nitrogen species in photoinhibition in vivo  

Science Journals Connector (OSTI)

...as a convenient method for calibration...1. Chemical NO production from nitrite and...Figure 4. Sequential production of the activated...interactions. Like hydrogen peroxide (H2O2...oxide protocols: methods in molecular biology...Nonenzymatic nitric oxide production in humans. Nitric...

2000-01-01T23:59:59.000Z

134

Kinetic modeling of nitric oxide removal from exhaust gases by Selective Non-Catalytic Reduction  

E-Print Network (OSTI)

for increased pressure predict a wider temperature range at which significant nitric oxide can be removed and also in the case of RAPRENOx process the levels of N20 (a by-product in the case of the RAPRENOx process) are significantly lower. The accounting...

Chenanda, Cariappa Mudappa

2012-06-07T23:59:59.000Z

135

Joule heating and nitric oxide in the thermosphere, 2 Charles A. Barth1  

E-Print Network (OSTI)

Joule heating and nitric oxide in the thermosphere, 2 Charles A. Barth1 Received 14 April 2010, gravity waves propagate from the polar regions toward the equator heating the thermosphere at 140 km and higher. These gravity waves are produced by Joule heating that occurs at latitudes of 60° and higher

Bailey, Scott

136

Strategies for laser-induced fluorescence detection of nitric oxide in high-pressure flames.  

E-Print Network (OSTI)

engines and gas turbines where the combustion chamber is at high pressure. Despite the use of catalyticStrategies for laser-induced fluorescence detection of nitric oxide in high-pressure flames. II. A combustion systems3�13 and thus develop new schemes to mini- mize NO effluent. The high operating pressure

Lee, Tonghun

137

Modeling gas phase nitric oxide release in lung epithelial cells Jingjing Jiang a  

E-Print Network (OSTI)

Modeling gas phase nitric oxide release in lung epithelial cells Jingjing Jiang a , Steven C- dated our model with experimental results of gas phase NO release and intracellular L enzyme on NO production. Our model predicts intracellular L-arginine and gas phase NO release over a wide

George, Steven C.

138

The role of nitric oxide in testosterone-induced vasodilation in pig coronary arteries and rat thoracic aorta  

E-Print Network (OSTI)

Several studies have provided evidence that the administration of testosterone to vascular tissue causes vasodilation (Costarella, Yue). This study examines the role of nitric oxide (NO) as a potential mechanism of testosterone-induced vasodilation...

Piefer, Jason William

2013-02-22T23:59:59.000Z

139

Specific Visualization of Nitric Oxide in the Vasculature with Two-Photon Microscopy Using a Copper Based Fluorescent Probe  

E-Print Network (OSTI)

To study the role and (sub) cellular nitric oxide (NO) constitution in various disease processes, its direct and specific detection in living cells and tissues is a major requirement. Several methods are available to measure ...

Ghosh, Mitrajit

140

CX-000549: Categorical Exclusion Determination | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

49: Categorical Exclusion Determination 49: Categorical Exclusion Determination CX-000549: Categorical Exclusion Determination Solubility Testing of Boron and Gadolinium in Nitric Acid CX(s) Applied: B3.6 Date: 11/24/2009 Location(s): Aiken, South Carolina Office(s): Environmental Management, Savannah River Operations Office The object of the test is to test solubility of boron and gadolinium in nitric acid for a range of conditions. Nitric acid from 0.3 to 5 moles will be combined with aluminum nitrate (Al(NO3)3) ranging from 1 to 3 moles with either gadolinium nitrate (Gd(NO3)3) or boric acid ranging from 1 to 5 grams per liter. Solutions will be held at constant temperature (20 degrees Celsius) and will be observed for visible solids potentially for several weeks. Solutions may be centrifuged or filtered to aid in determining

Note: This page contains sample records for the topic "nitric acid cxs" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Extraction of Plutonium into 30 Percent Tri-Butyl Phosphate from Nitric Acid Solution Containing Fluoride, Aluminum, and Boron  

SciTech Connect

This work consists of experimental batch extraction data for plutonium into 30 volume-percent tri-butyl phosphate at ambient temperature from such a solution matrix and a model of this data using complexation constants from the literature.

Kyser, E.A.

2000-01-06T23:59:59.000Z

142

Removal of radium from acidic solutions containing same by adsorption on coal fly ash  

DOE Patents (OSTI)

The invention is a process for the removal of radium from acidic aqueous solutions. In one aspect, the invention is a process for removing radium from an inorganic-acid solution. The process comprises contacting the solution with coal fly ash to effect adsorption of the radium on the ash. The radium-containing ash then is separated from the solution. The process is simple, comparatively inexpensive, and efficient. High radium-distribution coefficients are obtained even at room temperature. Coal fly ash is an inexpensive, acid-resistant, high-surface-area material which is available in large quantities throughout the United States. The invention is applicable, for example, to the recovery of .sup.226 Ra from nitric acid solutions which have been used to leach radium from uranium-mill tailings.

Scheitlin, Frank M. (Oak Ridge, TN)

1984-01-01T23:59:59.000Z

143

Selective reduction of nitric oxide with ammonia over vanadia on pillared titanium phosphate  

E-Print Network (OSTI)

in the catalyst. Shikada et al. (1981) compared AlzOz, SiOz, and SiO, ? TiOz (equimolar) supports for VzOs using a simulated flue gas containing 100 ppni SOz. The silica- titanium dioxide supported catalyst showed the highest NO conversions followed by those...SELECTIVE REDUCTION OF NITRIC OXIDE YVITH AMMONIA OVER VANADIA ON PILLARED TITANIUM PHOSPHATE A Thesis LAWRENCE JOSEPH CZARNECKI Submitted to the Graduate College of Texas AkM University in partial fulfillment of the requirement for the degree...

Czarnecki, Lawrence Joseph

1988-01-01T23:59:59.000Z

144

CX-004179: Categorical Exclusion Determination | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

4179: Categorical Exclusion Determination 4179: Categorical Exclusion Determination CX-004179: Categorical Exclusion Determination Bench Scale Testing on the Cesium Nitric Acid Recovery Evaporator (CNP) CX(s) Applied: B3.6 Date: 09/23/2010 Location(s): Aiken, South Carolina Office(s): Environmental Management, Savannah River Operations Office Vapor Liquid Equilibrium (VLE) measurements will be performed on nitric acid solutions as a function of the addition of the following salts: Aluminum nitrate, Lead nitrate, Cesium nitrate, Sodium nitrate and Potassium nitrate. The VLE measurements will be performed at a temperature of 55 degrees Celsius. This work is performed in support of Hanford?s Cesium Nitric Acid Recovery Evaporator. DOCUMENT(S) AVAILABLE FOR DOWNLOAD CX-004179.pdf More Documents & Publications

145

CX-004449: Categorical Exclusion Determination | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

449: Categorical Exclusion Determination 449: Categorical Exclusion Determination CX-004449: Categorical Exclusion Determination Bench Scale Testing to Provide Data on Precipitation Control in the Cesium Nitric Acid Recovery Process CX(s) Applied: B3.6 Date: 10/15/2010 Location(s): Aiken, South Carolina Office(s): Savannah River Operations Office The Hanford Tank Waste Treatment and Immobilization Plant (WPT) project is completing solubility models for nitrate salts to evaluate control of the Cesium Nitric Acid Recovery Process (CNP) in order to avoid precipitation of solids in the evaporator concentrate. In order to do this, bench scale tests to determine salt solubility in nitric acid solutions at expected feed and final evaporated concentrations will be done. This work will provide the necessary data to verify predicted salt solubilities and basic

146

The application of N,N-dimethyl-3-oxa-glutaramic acid (DOGA) in the PUREX process  

SciTech Connect

The new salt-free complexant, DOGA for separating trace Pu(IV) and Np(IV) from U(VI) nitric acid solution was studied. DOGA has stronger complexing abilities to Pu(IV) and Np(IV), but complexing ability of DOGA to U(VI) was weaker. The DOGA can be used in the PUREX process to separate Pu(IV) and Np(IV) from U(VI) nitric solution. On one hand, U(IV) in the nitric acid solution containing trace Pu(IV) and Np(IV) was extracted by 30%TBP - kerosene(v/v) in the presence of DOGA, but Pu(IV) and Np(IV) were kept in the aqueous phase. On the other hand, Pu(IV) and Np(IV) loading in 30% TBP - kerosene were effectively stripped by DOGA into the aqueous phase, but U(VI) loading in 30% TBP - kerosene was remained in 30% TBP - kerosene. DOGA is a promising complexant to separate Pu(IV) and Np(IV) from U(VI) solution in the U-cycle of the PUREX process. (authors)

Jianchen, Wang; Jing, Chen [Institute of Nuclear and New Energy Technology - INET, Tsinghua University, P.O. Box 1021, Beijing 102201 (China)

2007-07-01T23:59:59.000Z

147

Cisplatin upregulates mitochondrial nitric oxide synthase and peroxynitrite formation to promote renal injury  

SciTech Connect

The mitochondria are a critical target for cisplatin-associated nephrotoxicity. Though nitric oxide formation has been implicated in the toxicity of cisplatin, this formation has not so far been related to a possible activation of mitochondrial nitric oxide synthase (mNOS). We show here that the upregulation of oxide mNOS and peroxynitrite formation in cisplatin treatment are key events that influence the development of the harmful parameters described in cisplatin-associated kidney failure. We confirm this by isolating the mitochondrial fraction of the kidney and across different access routes such as the use of a specific inhibitor of neuronal NOS, L-NPA, a peroxynitrite scavenger, FeTMPyP, and a peroxynitrite donor, SIN-1. The in vitro studies corroborated the information obtained in the in vivo experiments. The administration of cisplatin reveals a clear upregulation in the transcription of neuronal NOS and an increase in the levels of nitrites in the mitochondrial fractions of the kidneys. The upregulated transcription directly affects the cytoskeleton structure and the apoptosis. The inhibition of neuronal NOS reduces the levels of nitrites, cell death, and cytoskeleton derangement. Peroxynitrite is involved in the mechanism promoting the NOS transcription. In addition, in controls SIN-1 imitates the effects of cisplatin. In summary, we demonstrate that upregulation of mNOS in cisplatin treatment is a key component in both the initiation and the spread of cisplatin-associated damage in the kidney. Furthermore, peroxynitrite formation is directly involved in this process.

Jung, Michaela [Department of Ischemia and Inflammation, Instituto de Investigaciones Biomedicas, IIBB-CSIC-IDIBAPS, C/ Rossello, 161, 7a, 08036 Barcelona (Spain); Hotter, Georgina; Vinas, Jose Luis [Department of Ischemia and Inflammation, Instituto de Investigaciones Biomedicas, IIBB-CSIC-IDIBAPS, C/ Rossello, 161, 7a, 08036 Barcelona (Spain); CIBER-BBN, Networking Center on Bioengineering, Biomaterials and Nanomedicine, Barcelona (Spain); Sola, Anna [Department of Ischemia and Inflammation, Instituto de Investigaciones Biomedicas, IIBB-CSIC-IDIBAPS, C/ Rossello, 161, 7a, 08036 Barcelona (Spain); CIBER-BBN, Networking Center on Bioengineering, Biomaterials and Nanomedicine, Barcelona (Spain)], E-mail: asmbam@iibb.csic.es

2009-01-15T23:59:59.000Z

148

Development of a Novel Solvent for the Simultaneous Separation of Strontium and Cesium from Acidic Solutions  

SciTech Connect

A synergistic extraction solvent for the simultaneous removal of cesium and strontium from acidic solutions has been investigated. The extraction solvent consists of, 4,4',(5')-di-(t-butyldicyclo-hexano)-18-crown-6 (DtBuCH18C6), calix[4]arene-bis-(tert-octylbenzo-crown-6) (BOBCalixC6), and 1-(2,2,3,3-tetrafluoropropoxy)-3-(4-sec-butylphenoxy)-2-propanol (Cs-7SB modifier) in a branched aliphatic kerosene (Isopar® L). Extraction synergy for strontium was observed when DtBuCH18C6 was combined with the BOBCalixC6 cesium extractant solvent and Cs-7SB modifier or if the Cs-7SB modifier was substituted into the SREX (Strontium Extraction) solvent in place of TBP. The novel process extracted both cesium and strontium simultaneously from 1 M nitric acid solutions with distribution ratios of 8.8 and 7.7 for strontium and cesium, respectively, at ambient temperature. Distribution coefficients for cesium and strontium as a function of nitric acid concentration and temperature were also obtained with 0.5 M<[HNO3]<2.5 M giving favorable distribution ratios. This new process utilizing the combined solvent has been named the Fission Product Extraction Process (FPEX).

Catherine L. Riddle; John D. Baker; Jack D. Law; Christopher A. McGrath; David H. Meikrantz; Bruce J. Mincher; Dean R. Peterman; Terry A. Todd

2005-03-01T23:59:59.000Z

149

Categorical Exclusion Determinations: Environmental Management | Department  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

September 23, 2010 September 23, 2010 CX-004179: Categorical Exclusion Determination Bench Scale Testing on the Cesium Nitric Acid Recovery Evaporator (CNP) CX(s) Applied: B3.6 Date: 09/23/2010 Location(s): Aiken, South Carolina Office(s): Environmental Management, Savannah River Operations Office September 23, 2010 CX-004177: Categorical Exclusion Determination Waste Treatment Plant Secondary Waste Radioactive Bench-Scale Steam Reformer (Module A) CX(s) Applied: B3.6 Date: 09/23/2010 Location(s): Aiken, South Carolina Office(s): Environmental Management, Savannah River Operations Office September 23, 2010 CX-004176: Categorical Exclusion Determination Making Nepheline (NaAlSiO4), Phase Pure Standards CX(s) Applied: B3.6 Date: 09/23/2010 Location(s): Aiken, South Carolina Office(s): Environmental Management, Savannah River Operations Office

150

Categorical Exclusion Determinations: South Carolina | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

October 15, 2010 October 15, 2010 CX-004449: Categorical Exclusion Determination Bench Scale Testing to Provide Data on Precipitation Control in the Cesium Nitric Acid Recovery Process CX(s) Applied: B3.6 Date: 10/15/2010 Location(s): Aiken, South Carolina Office(s): Savannah River Operations Office October 15, 2010 CX-004448: Categorical Exclusion Determination Noble Gas Analysis CX(s) Applied: B3.6 Date: 10/15/2010 Location(s): Aiken, South Carolina Office(s): Savannah River Operations Office October 15, 2010 CX-004447: Categorical Exclusion Determination L Basin Vacuum System Replacement CX(s) Applied: B1.3 Date: 10/15/2010 Location(s): Aiken, South Carolina Office(s): Savannah River Operations Office October 7, 2010 CX-004453: Categorical Exclusion Determination Establish, Maintain, and Monitor Long-Term Lysimeters

151

Categorical Exclusion Determinations: Savannah River Operations Office |  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

October 25, 2010 October 25, 2010 CX-004445: Categorical Exclusion Determination Waste Treatment Plant Secondary Waste Radioactive Fluidized Bed Steam Reforming (Module A) CX(s) Applied: B3.6 Date: 10/25/2010 Location(s): Aiken, South Carolina Office(s): Savannah River Operations Office October 15, 2010 CX-004450: Categorical Exclusion Determination Plutonium Glass Sectioning CX(s) Applied: B3.6 Date: 10/15/2010 Location(s): Aiken, South Carolina Office(s): Savannah River Operations Office October 15, 2010 CX-004449: Categorical Exclusion Determination Bench Scale Testing to Provide Data on Precipitation Control in the Cesium Nitric Acid Recovery Process CX(s) Applied: B3.6 Date: 10/15/2010 Location(s): Aiken, South Carolina Office(s): Savannah River Operations Office October 15, 2010

152

Categorical Exclusion Determinations: B3.6 | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

24, 2009 24, 2009 CX-000549: Categorical Exclusion Determination Solubility Testing of Boron and Gadolinium in Nitric Acid CX(s) Applied: B3.6 Date: 11/24/2009 Location(s): Aiken, South Carolina Office(s): Environmental Management, Savannah River Operations Office November 23, 2009 CX-000207: Categorical Exclusion Determination NaSi (Sodium Silicide) and Na-SG (Sodium Silica Gell) Powder Hydrogen Fuel Cells CX(s) Applied: B3.6 Date: 11/23/2009 Location(s): New York Office(s): Energy Efficiency and Renewable Energy, Golden Field Office November 23, 2009 CX-000206: Categorical Exclusion Determination Michigan Biogas Center of Excellence CX(s) Applied: A9, B3.6 Date: 11/23/2009 Location(s): Flint, Michigan Office(s): Energy Efficiency and Renewable Energy, Golden Field Office

153

Page not found | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

31 - 10540 of 26,764 results. 31 - 10540 of 26,764 results. Download CX-004448: Categorical Exclusion Determination Noble Gas Analysis CX(s) Applied: B3.6 Date: 10/15/2010 Location(s): Aiken, South Carolina Office(s): Savannah River Operations Office http://energy.gov/nepa/downloads/cx-004448-categorical-exclusion-determination Download CX-004449: Categorical Exclusion Determination Bench Scale Testing to Provide Data on Precipitation Control in the Cesium Nitric Acid Recovery Process CX(s) Applied: B3.6 Date: 10/15/2010 Location(s): Aiken, South Carolina Office(s): Savannah River Operations Office http://energy.gov/nepa/downloads/cx-004449-categorical-exclusion-determination Download CX-004450: Categorical Exclusion Determination Plutonium Glass Sectioning CX(s) Applied: B3.6 Date: 10/15/2010

154

Nanomedicine: Action of Metal Nanoparticles on Neuronal Nitric Oxide Synthase—Fluorimetric Analysis on the Mechanism for Fibrillogenesis  

Science Journals Connector (OSTI)

The incubation of neuronal nitric oxide synthase with the five amyloid peptide fragments [A?17–21; A?25–29; A?29–33; A?33–37; A?25–37] catalyzed the formation of fibrils. The role of neuronal isomer (nNOS) involv...

E. R. Padayachee; A. Arowolo; C. G. Whiteley

2014-01-01T23:59:59.000Z

155

Hydrogen Peroxideâ??Mediated Activation of MAP Kinase 6 Modulates Nitric Oxide Biosynthesis and Signal Transduction in Arabidopsis  

Science Journals Connector (OSTI)

...Peroxide-Mediated Activation of MAP Kinase 6 Modulates Nitric Oxide Biosynthesis and Signal Transduction in Arabidopsis [w] Pengcheng Wang a Yanyan Du a Yuan Li b Dongtao Ren b Chun-Peng Song a 1 1 Address correspondence to songcp@henu.edu.cn . a Laboratory...

Pengcheng Wang; Yanyan Du; Yuan Li; Dongtao Ren; Chun-Peng Song

2010-09-24T23:59:59.000Z

156

Nitric oxide inhibition of soot oxidation by oxygen atoms at 298K  

SciTech Connect

Nitric oxide is observed to inhibit the rate of soot oxidation by oxygen atoms at 298K. Small amounts of added NO reduce the rates of production of CO/sub 2/ and CO by up to 35%. The authors show experimentally that NO is not reducing the gas phase O atom concentration. Thermal desorption mass spectrometry shows a small adsorption of NO on the soot; this NO adsorption corresponds to 1.5% of the carbon atoms on the surface of the individual soot spheres. This inhibition is interpreted in terms of a relatively small number of reactive sites on the soot at which soot gasification occurs and which are effectively blocked by NO.

Wicke, B.G.; Grady, K.A.

1987-08-01T23:59:59.000Z

157

Nitric oxide inhibition of soot oxidation by oxygen atoms at 298/sup 0/Ktiation  

SciTech Connect

Nitric oxide is observed to inhibit the rate of soot oxidation by oxygen atoms at 298 K. Small amounts of added NO reduce the rates of production of CO/sub 2/ and CO by up to 35%. The authors show experimentally that NO is not reducing the gas phase O atom concentration. Thermal description mass spectrometry is used to measure the small adsorption of NO on the soot; this NO adsorption corresponds to 1.5% of the carbon atoms on the surface of the individual soot spheres. This inhibition is interpreted in terms of a relatively small number of reactive sites on the soot at which soot gasification occurs and which are effectively blocked by NO. When considered together with our previously reported work on oxidation of soot by oxygen atoms at 298 K, these results allow a partial mechanism to be formulated for this soot oxidation process.

Wicke, B.G.; Grady, K.A.

1987-01-01T23:59:59.000Z

158

Reaction of nitric oxide with heme proteins and model compounds of hemoglobin  

SciTech Connect

Rates for the reaction of nitric oxide with several ferric heme proteins and model compounds have been measured. The NO combination rates are markedly affected by the presence or absence of distal histidine. Elephant myoglobin in which the E7 distal histidine has been replaced by glutamine reacts with NO 500-1000 times faster than do the native hemoglobins or myoglobins. By contrast, there is not difference in the CO combination rate constants of sperm whale and elephant myoglobins. Studies on ferric model compounds for the R and T states of hemoglobin indicate that their NO combination rate constants are similar to those observed for the combination of CO with the corresponding ferro derivatives. The last observation suggests that the presence of an axial water molecule at the ligand binding site of ferric hemoglobin A prevents it from exhibiting significant cooperativity in its reactions with NO.

Sharma, V.S.; Traylor, T.G.; Gardiner, R.; Mizukami, H.

1987-06-30T23:59:59.000Z

159

Structure of a Loose Dimer: an Intermediate in Nitric Oxide Synthase Assembly  

SciTech Connect

Cooperativity among ligand binding, subunit association, and protein folding has implications for enzyme regulation as well as protein aggregation events associated with disease. The binding of substrate l-arginine or cofactor tetrahydrobiopterin converts nitric oxide synthases (NOSs) from a 'loose dimer', with an exposed active center and higher sensitivity to proteolysis, to a 'tight dimer' competent for catalysis. The crystallographic structure of the Bacillus subtilis NOS loose dimer shows an altered association state with severely destabilized subdomains. Ligand binding or heme reduction converts loose dimers to tight dimers in solution and crystals. Mutations at key positions in the dimer interface that distinguish prokaryotic from eukaryotic NOSs affect the propensity to form loose dimers. The loose dimer structure indicates that non-native interactions can mediate subunit association in NOS.

Pant,K.; Crane, B.

2005-01-01T23:59:59.000Z

160

Citrus nobiletin suppresses inducible nitric oxide synthase gene expression in interleukin-1?-treated hepatocytes  

SciTech Connect

Highlights: •Nobiletin is a polymethoxylated flavone that is abundant in citrus peels. •Nobiletin is a major constituent of the Citrus unshiu peel extract. •Nobiletin suppresses induction of NO and reduces iNOS expression in hepatocytes. •Nobiletin reduces the iNOS promoter activity and the DNA-binding activity of NF-?B. -- Abstract: Background: Nobiletin is a polymethoxylated flavone that is abundant in the peels of citrus fruits, such as Citrus unshiu (Satsuma mandarin) and Citrus sinensis. The dried peels of C. unshiu (chinpi) have been included in several formulae of Japanese Kampo medicines. Nobiletin may suppress the induction of inducible nitric oxide synthase (iNOS), which synthesizes the inflammatory mediator nitric oxide (NO) in hepatocytes. Methods: A C. unshiu peel (CUP) extract was prepared. Primary cultured rat hepatocytes were treated with the CUP extract or nobiletin in the presence of interleukin 1? (IL-1?), which induces iNOS expression. NO production and iNOS gene expression were analyzed. Results: High-performance liquid chromatography analyses revealed that the nobiletin content in the CUP extract was 0.14%. Nobiletin dose-dependently reduced the NO levels and decreased iNOS expression at the protein, mRNA and antisense transcript levels. Flavone, which does not contain any methoxy groups, also suppressed iNOS induction. Nobiletin reduced the transcriptional activity of iNOS promoter-luciferase constructs and the DNA-binding activity of nuclear factor ?B (NF-?B) in the nuclei. Conclusions: The suppression of iNOS induction by nobiletin suggests that nobiletin may be responsible for the anti-inflammatory effects of citrus peels and have a therapeutic potential for liver diseases.

Yoshigai, Emi [Department of Biomedical Sciences, College of Life Sciences, Kusatsu, Shiga (Japan) [Department of Biomedical Sciences, College of Life Sciences, Kusatsu, Shiga (Japan); Ritsumeikan Global Innovation Research Organization (R-GIRO), Kusatsu, Shiga (Japan); Machida, Toru [Department of Biomedical Sciences, College of Life Sciences, Kusatsu, Shiga (Japan)] [Department of Biomedical Sciences, College of Life Sciences, Kusatsu, Shiga (Japan); Okuyama, Tetsuya [Ritsumeikan Global Innovation Research Organization (R-GIRO), Kusatsu, Shiga (Japan)] [Ritsumeikan Global Innovation Research Organization (R-GIRO), Kusatsu, Shiga (Japan); Mori, Masatoshi; Murase, Hiromitsu; Yamanishi, Ryota [Department of Biomedical Sciences, College of Life Sciences, Kusatsu, Shiga (Japan)] [Department of Biomedical Sciences, College of Life Sciences, Kusatsu, Shiga (Japan); Okumura, Tadayoshi [Research Organization of Science and Technology, Ritsumeikan University, Kusatsu, Shiga (Japan) [Research Organization of Science and Technology, Ritsumeikan University, Kusatsu, Shiga (Japan); Department of Surgery, Kansai Medical University, Hirakata, Osaka (Japan); Ikeya, Yukinobu [Department of Pharmacy, College of Pharmaceutical Sciences, Ritsumeikan University, Kusatsu, Shiga (Japan)] [Department of Pharmacy, College of Pharmaceutical Sciences, Ritsumeikan University, Kusatsu, Shiga (Japan); Nishino, Hoyoku [Ritsumeikan Global Innovation Research Organization (R-GIRO), Kusatsu, Shiga (Japan) [Ritsumeikan Global Innovation Research Organization (R-GIRO), Kusatsu, Shiga (Japan); Department of Biochemistry, Kyoto Prefectural University of Medicine, Kyoto (Japan); Nishizawa, Mikio, E-mail: nishizaw@sk.ritsumei.ac.jp [Department of Biomedical Sciences, College of Life Sciences, Kusatsu, Shiga (Japan)] [Department of Biomedical Sciences, College of Life Sciences, Kusatsu, Shiga (Japan)

2013-09-13T23:59:59.000Z

Note: This page contains sample records for the topic "nitric acid cxs" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Fatty acid analogs  

DOE Patents (OSTI)

In one aspect, a radioactively labeled analog of a fatty acid which is capable of being taken up by mammalian tissue and which exhibits an in vivo beta-oxidation rate below that with a corresponding radioactively labeled fatty acid.

Elmaleh, David R. (Newton Center, MA); Livni, Eli (Brookline, MA)

1985-01-01T23:59:59.000Z

162

Arginase inhibition reduces interleukin-1?-stimulated vascular smooth muscle cell proliferation by increasing nitric oxide synthase-dependent nitric oxide production  

SciTech Connect

Highlights: •Arginase inhibition suppressed proliferation of IL-1?-stimulated VSMCs in dose-dependent manner. •NO production from IL-1?-induced iNOS expression was augmented by arginase inhibition, reducing VSMC proliferation. •Incubation with cGMP analogues abolished IL-1?-dependent proliferation of VSMCs. -- Abstract: We investigated whether arginase inhibition suppressed interleukin (IL)-1?-stimulated proliferation in vascular smooth muscle cells (VSMCs) and the possible mechanisms involved. IL-1? stimulation increased VSMC proliferation, while the arginase inhibitor BEC and transfection of the antisense (AS) oligonucleotide against arginase I decreased VSMC proliferation and was associated with increased protein content of the cell cycle regulator p21Waf1/Cip1. IL-1? incubation induced inducible nitric oxide synthase (iNOS) mRNA expression and protein levels in a dose-dependent manner, but did not affect arginase I and II expression. Consistent with this data, IL-1? stimulation resulted in increase in NO production that was significantly augmented by arginase inhibition. The specific iNOS inhibitor 1400W abolished IL-1?-mediated NO production and further accentuated IL-1?-stimulated cell proliferation. Incubation with NO donors GSNO and DETA/NO in the presence of IL-1? abolished VSMCs proliferation and increased p21Waf1/Cip1 protein content. Furthermore, incubation with the cGMP analogue 8-Br-cGMP prevented IL-1?-induced VSMCs proliferation. In conclusion, arginase inhibition augmented iNOS-dependent NO production that resulted in suppression of IL-1?-induced VSMCs proliferation in a cGMP-dependent manner.

Yoon, Jeongyeon; Ryoo, Sungwoo, E-mail: ryoosw08@kangwon.ac.kr

2013-06-07T23:59:59.000Z

163

A ACID RAIN Audrey Gibson  

E-Print Network (OSTI)

- SO2 Emissions of sulfur dioxide (SO2) and oxides of nitrogen (NOx) react in the atmosphere with water;Gas Natural Sources Concentration Carbon dioxide CO2 Decomposition 355 ppm Nitric oxide NO Electric discharge 0.01 ppm Sulfur dioxide SO2 Volcanic gases 0-0.01 ppm Table 1 Carbon dioxide, produced

Toohey, Darin W.

164

Uniform nano-ripples on the sidewall of silicon carbide micro-hole fabricated by femtosecond laser irradiation and acid etching  

SciTech Connect

Uniform nano-ripples were observed on the sidewall of micro-holes in silicon carbide fabricated by 800-nm femtosecond laser and chemical selective etching. The morphology of the ripple was analyzed using scanning electronic microscopy. The formation mechanism of the micro-holes was attributed to the chemical reaction of the laser affected zone with mixed solution of hydrofluoric acid and nitric acid. The formation of nano-ripples on the sidewall of the holes could be attributed to the standing wave generated in z direction due to the interference between the incident wave and the reflected wave.

Khuat, Vanthanh [Key Laboratory for Physical Electronics and Devices of the Ministry of Education and Collaborative Innovation Center of Suzhou Nano Science and Technology, School of Electronics and Information Engineering, Xi'an Jiaotong University, No. 28, Xianning West Road, Xi'an 710049 (China); Le Quy Don Technical University, No. 100, Hoang Quoc Viet Street, Hanoi 7EN-248 (Viet Nam); Chen, Tao; Gao, Bo; Si, Jinhai, E-mail: jinhaisi@mail.xjtu.edu.cn; Ma, Yuncan; Hou, Xun [Key Laboratory for Physical Electronics and Devices of the Ministry of Education and Collaborative Innovation Center of Suzhou Nano Science and Technology, School of Electronics and Information Engineering, Xi'an Jiaotong University, No. 28, Xianning West Road, Xi'an 710049 (China)

2014-06-16T23:59:59.000Z

165

Nucleic acid detection compositions  

DOE Patents (OSTI)

The present invention relates to means for the detection and characterization of nucleic acid sequences, as well as variations in nucleic acid sequences. The present invention also relates to methods for forming a nucleic acid cleavage structure on a target sequence and cleaving the nucleic acid cleavage structure in a site-specific manner. The structure-specific nuclease activity of a variety of enzymes is used to cleave the target-dependent cleavage structure, thereby indicating the presence of specific nucleic acid sequences or specific variations thereof.

Prudent, James R. (Madison, WI); Hall, Jeff G. (Madison, WI); Lyamichev, Victor I. (Madison, WI); Brow, Mary Ann (Madison, WI); Dahlberg, James L. (Madison, WI)

2008-08-05T23:59:59.000Z

166

Cleavage of nucleic acids  

DOE Patents (OSTI)

The present invention relates to means for the detection and characterization of nucleic acid sequences, as well as variations in nucleic acid sequences. The present invention also relates to methods for forming a nucleic acid cleavage structure on a target sequence and cleaving the nucleic acid cleavage structure in a site-specific manner. The structure-specific nuclease activity of a variety of enzymes is used to cleave the target-dependent cleavage structure, thereby indicating the presence of specific nucleic acid sequences or specific variations thereof.

Prudent, James R. (Madison, WI); Hall, Jeff G. (Madison, WI); Lyamichev, Victor L. (Madison, WI); Brow, Mary Ann D. (Madison, WI); Dahlberg, James E. (Madison, WI)

2007-12-11T23:59:59.000Z

167

Suppression of manganese-dependent production of nitric oxide in astrocytes: implications for therapeutic modulation of glial-derived inflammatory mediators  

E-Print Network (OSTI)

Primary cultured astrocytes were treated with Mn in the absence and presence of proinflammatory cytokines to determine their effect upon stimulation of nitric oxide (NO) production. Treatments of manganese and cytokines raised NO production...

Wright, Tyler T.

2009-05-15T23:59:59.000Z

168

Visualization of nitric oxide production in the mouse main olfactory bulb by a cell-trappable copper(II) fluorescent probe  

E-Print Network (OSTI)

We report the visualization of NO production using fluorescence in tissue slices of the mouse main olfactory bulb. This discovery was possible through the use of a novel, cell-trappable probe for intracellular nitric oxide ...

McQuade, Lindsey E.

169

Faraday rotation spectrometer with sub-second response time for detection of nitric oxide using a cw DFB quantum cascade laser at 5.33 ?m  

Science Journals Connector (OSTI)

A Faraday modulation spectrometer for sensitive and fast detection of nitric oxide at 5.33 ?m utilizing a room temperature continuous wave distributed feedback quantum cascade laser and a Peltier cooled MCT detec...

P. Kluczynski; S. Lundqvist; J. Westberg; O. Axner

2011-05-01T23:59:59.000Z

170

Production of nitric oxide, lipid peroxidation and oxidase activity of ceruloplasmin in blood of elderly patients with primary hypertension. Effects of perindopril treatment  

Science Journals Connector (OSTI)

Background and aims: One of the factors playing a role in both the aging ... purpose of this work was to estimate the production of nitric oxide (NO), oxidase activity...Methods: The study was ca...

Kornelia K?ziora-Kornatowska MD; PhD…

2006-02-01T23:59:59.000Z

171

STANDARD OPERATING PROCEDURE ACIDS CONTAINING PHOSPHOROUS  

E-Print Network (OSTI)

12.1 STANDARD OPERATING PROCEDURE for ACIDS CONTAINING PHOSPHOROUS Location(s): ___________________________________________________ Chemical(s): Hypophosphorous acid, methylphosphonic acid, phosphonic acid, phosphoric acid, phosphorous

Pawlowski, Wojtek

172

Microorganisms for producing organic acids  

DOE Patents (OSTI)

Organic acid-producing microorganisms and methods of using same. The organic acid-producing microorganisms comprise modifications that reduce or ablate AcsA activity or AcsA homolog activity. The modifications increase tolerance of the microorganisms to such organic acids as 3-hydroxypropionic acid, acrylic acid, propionic acid, lactic acid, and others. Further modifications to the microorganisms increase production of such organic acids as 3-hydroxypropionic acid, lactate, and others. Methods of producing such organic acids as 3-hydroxypropionic acid, lactate, and others with the modified microorganisms are provided. Methods of using acsA or homologs thereof as counter-selectable markers are also provided.

Pfleger, Brian Frederick; Begemann, Matthew Brett

2014-09-30T23:59:59.000Z

173

Separation Nanotechnology of Diethylenetriaminepentaacetic Acid...  

NLE Websites -- All DOE Office Websites (Extended Search)

Nanotechnology of Diethylenetriaminepentaacetic Acid Bonded Magnetic Nanoparticles for Spent Nuclear Fuel. Separation Nanotechnology of Diethylenetriaminepentaacetic Acid Bonded...

174

Iron porphyrin polymer films: Materials for the modification of electrode surfaces and the detection of nitric oxide  

SciTech Connect

We are currently investigating a new method for the detection and quantification of nitric oxide (NO) based on a carbon electrode chemically modified with an iron porphyrin polymer film. Commercially available vinyl-substituted iron porphyrin monomers can be polymerized directly onto electrode surfaces through a published electrochemical polymerization process. We are also developing a synthesis for a new vinyl-substituted monomer, iron 5,10,15-triphenyl-20-vinyl porphyrin chloride, in hopes of improving polymer film stability. The electrochemistry of NO is also being investigated at electrodes chemically modified with an iron porphyrin polymer film. We are studying the catalytic oxidation of iron porphyrin bound NO to nitrate by molecular oxygen. The reaction with molecular oxygen is preceded by a one electron reduction of the iron porphyrin-NO complex. If currents proportional to nitric oxide concentration can be measured, a new NO electrochemical sensor will be designed.

McGuire, M.; Drew, S.M. [Carleton College, Northfield, MN (United States)

1996-10-01T23:59:59.000Z

175

Equilibrium surface composition of sulfuric acid films in contact with various atmospheric gases (HNO{sub 3}, CO{sub 2}, CH{sub 2}O, Cl{sub 2}, NO, NO{sub 2})  

SciTech Connect

Differentially pumped X-ray photoelectron spectroscopy has been used to study the surface composition of sulfuric acid (H{sub 2}SO{sub 4}) and sulfuric acid/water mixtures in equilibrium with various atmospheric species. Nitric acid uptake in sulfuric acid solutions was observed below {approx}220 K. Compared to the theoretically predicted bulk composition, a significant enrichment of nitrogen was observed at the interface. The uptake of background water in sulfuric acid below 200 K was responsible for the reversible uptake of CO{sub 2}, moderated through the formation of carbonic acid (H{sub 2}CO{sub 3}). For CH{sub 2}O, Cl{sub 2}, NO, and NO{sub 2}, no observable surface species were observed over the temperature range studied ({approx}180--298 K).

Fairbrother, D.H.; Somorjai, G.A.

2000-05-18T23:59:59.000Z

176

Reversible Acid Gas Capture  

SciTech Connect

Pacific Northwest National Laboratory scientist David Heldebrant demonstrates how a new process called reversible acid gas capture works to pull carbon dioxide out of power plant emissions.

Dave Heldebrant

2009-08-01T23:59:59.000Z

177

Reversible Acid Gas Capture  

ScienceCinema (OSTI)

Pacific Northwest National Laboratory scientist David Heldebrant demonstrates how a new process called reversible acid gas capture works to pull carbon dioxide out of power plant emissions.

Dave Heldebrant

2012-12-31T23:59:59.000Z

178

Roles of Glutamates and Metal ions in a Rationally Designed Nitric Oxide Reductase Based on Myoglobin  

SciTech Connect

A structural and functional model of bacterial nitric oxide reductase (NOR) has been designed by introducing two glutamates (Glu) and three histidines (His) in sperm whale myoglobin. X-ray structural data indicate that the three His and one Glu (V68E) residues bind iron, mimicking the putative FeB site in NOR, while the second Glu (I107E) interacts with a water molecule and forms a hydrogen bonding network in the designed protein. Unlike the first Glu (V68E), which lowered the heme reduction potential by {approx}110 mV, the second Glu has little effect on the heme potential, suggesting that the negatively charged Glu has a different role in redox tuning. More importantly, introducing the second Glu resulted in a {approx}100% increase in NOR activity, suggesting the importance of a hydrogen bonding network in facilitating proton delivery during NOR reactivity. In addition, EPR and X-ray structural studies indicate that the designed protein binds iron, copper, or zinc in the FeB site, each with different effects on the structures and NOR activities, suggesting that both redox activity and an intermediate five-coordinate heme-NO species are important for high NOR activity. The designed protein offers an excellent model for NOR and demonstrates the power of using designed proteins as a simpler and more well-defined system to address important chemical and biological issues.

Y Lin; N Yeung; Y Gao; K Miner; S Tian; H Robinson; Y Lu

2011-12-31T23:59:59.000Z

179

Reduction of pertechnetate by acetohydroxamic acid: Formation of [TcNO(AHA)2(H2O)]+ and implications for the UREX process.  

SciTech Connect

Reductive nitrosylation and complexation of ammonium pertechnetate by acetohydroxamic acid has been achieved in aqueous nitric and perchloric acid solutions. The kinetics of the reaction depend on the relative concentrations of the reaction components and are accelerated at higher temperatures. The reaction does not occur unless conditions are acidic. Analysis of the x-ray absorption fine structure spectroscopic data is consistent with a pseudo-octahedral geometry with the linear Tc-N-O bond typical of technetium nitrosyl compounds, and electron spin resonance spectroscopy is consistent with a the d{sup 5} Tc(II) nitrosyl complex. The nitrosyl source is generally AHA, but may be augmented by products of reaction with nitric acid. The resulting low-valency trans-aquonitrosyl(diacetohydroxamic)-technetium(II) complex (1) is highly soluble in water, extremely hydrophilic, and is not extracted by tri-n-butylphosphate in a dodecane diluent. Its extraction properties are not pH-dependent; titration studies indicate a single species from pH 4.5 down to -0.6 (calculated). This molecule is resistant to oxidation by H{sub 2}O{sub 2}, even at high pH, and can undergo substitution to form other technetium nitrosyl complexes. The formation of 1 may strongly impact the fate of technetium in the nuclear fuel cycle.

1Harry Reid Center for Environmental Studies, Nuclear Science and Technology Division, University of Nevada, Las Vegas, Las Vegas, NV, 89154-4006; Gong, Cynthia-May S; Poineau, Frederic; Lukens, Wayne W; Czerwinski, Kenneth R.

2008-02-26T23:59:59.000Z

180

PRELIMINARY REPORT ON EVALUATION OF POTENTIAL ELUANTS FOR NON-ACID ELUTION OF CESIUM FROM RESORCINOL-FORMALDEHYDE RESIN  

SciTech Connect

Small-column ion exchange (SCIX) units installed in high-level waste tanks to remove Cs-137 from highly alkaline salt solutions are among the waste treatment plans in the DOE-complex. Spherical Resorcinol-Formaldehyde (sRF) is the ion exchange resin selected for use in the Hanford Waste Treatment and Immobilization Plant (WTP). It is also the primary ion exchange material under consideration for SCIX at the Hanford site. The elution step of the multi-step ion exchange process is typically done with 0.5 M nitric acid. An acid eluant is a potential hazard in the event of a spill, leak, etc. because the high-level waste tanks are made of carbon steel. Corrosion and associated structural damage may ensue. Studies are ongoing to explore non-acid elution as an alternative. Batch contact sorption equilibrium screening tests have been conducted with 36 potential non-acid eluants. The sorption tests involve equilibrating each cesium-containing eluant solution with the sRF resin for 48 hours at 25 C in a shaker oven. In the sorption tests, an eluant is deemed to have a high cesium elution potential if it minimizes cesium sorption onto the sRF resin. The top candidates (based on lowest cesium sorption distribution coefficients) include ammonium carbonate, ammonium carbonate/ammonium hydroxide, ammonium bicarbonate, rubidium carbonate, ammonium acetate, ammonium acetate/ammonium hydroxide, ammonium bicarbonate/ammonium hydroxide, calcium chloride, and magnesium chloride. The next phase of testing for this work will focus on the following down selected eluants: Ammonium carbonate, ammonium acetate, calcium acetate, magnesium acetate, nitric acid, and ammonium hydroxide. The next testing phase is a confirmation of the elution ability of the selected eluants. It will mimic a typical sRF cesium ion exchange process i.e., sorption or loading, caustic wash, water rinse, and elution via batch contact sorption and quasi column caustic wash/water rinse/elution. Due to corrosion concerns, calcium acetate and magnesium acetate will be tested instead of calcium chloride and magnesium chloride respectively. Nitric acid is for benchmarking since it is the baseline sRF eluant. The information at hand indicates ammonium hydroxide, while a weak base, may hold promise as an effective eluant. Hence, its inclusion among the eluants to be studied despite the fact that it was not tested as a stand-alone eluant earlier.

Adu-Wusu, K.; Pennebaker, F.

2010-09-01T23:59:59.000Z

Note: This page contains sample records for the topic "nitric acid cxs" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Crystal Structures of the Nitrite and Nitric Oxide Complexes of Horse Heart Myoglobin  

SciTech Connect

Nitrite is an important species in the global nitrogen cycle, and the nitrite reductase enzymes convert nitrite to nitric oxide (NO). Recently, it has been shown that hemoglobin and myoglobin catalyze the reduction of nitrite to NO under hypoxic conditions. We have determined the 1.20 Angstroms resolution crystal structure of the nitrite adduct of ferric horse heart myoglobin (hh Mb). The ligand is bound to iron in the nitrito form, and the complex is formulated as Mb{sup III}(ONO{sup -}). The Fe-ONO bond length is 1.94 Angstroms, and the O-N-O angle is 113 degrees. In addition, the nitrite ligand is stabilized by hydrogen bonding with the distal His64 residue. We have also determined the 1.30 Angstroms resolution crystal structures of hh Mb{sup II}NO. When hh Mb{sup II}NO is prepared from the reaction of metMb{sup III} with nitrite/dithionite, the FeNO angle is 144 degrees with a Fe-NO bond length of 1.87 Angstroms. However, when prepared from the reaction of NO with reduced Mb{sup II}, the FeNO angle is 120 degrees with a Fe-NO bond length of 2.13 Angstroms. This difference in FeNO conformations as a function of preparative method is reproducible, and suggests a role of the distal pocket in hh Mb{sup II}NO in stabilizing local FeNO conformational minima.

Copeland,D.; Soares, A.; West, A.; Richter-Addo, G.

2006-01-01T23:59:59.000Z

182

Laser-saturated fluorescence of nitric oxide and chemiluminescence measurements in premixed ethanol flames  

SciTech Connect

In this study, nitric oxide laser-saturated fluorescence (LSF) measurements were acquired from premixed ethanol flames at atmospheric pressure in a burner. NO-LSF experimental profiles for fuel-rich premixed ethanol flames ({phi} = 1.34 and {phi} = 1.66) were determined through the excitation/detection scheme of the Q{sub 2}(26.5) rotational line in the A{sup 2}{sigma}{sup +} - X{sup 2}{pi} (0,0) vibronic band and {gamma}(0,1) emission band. A calibration procedure by NO doping into the flame was applied to establish the NO concentration profiles in these flames. Chemiluminescent emission measurements in the (0, 0) vibronic emission bands of the OH{sup *} (A{sup 2}{sigma}{sup +} - X{sup 2}{pi}) and CH{sup *}(A{sup 2}{delta} - X{sup 2}{pi}) radicals were also obtained with high spatial and spectral resolution for fuel-rich premixed ethanol flames to correlate them with NO concentrations. Experimental chemiluminescence profiles and the ratios of the integrated areas under emission spectra (A{sub CH*}/A{sub CH*}(max.) and A{sub CH*}/A{sub OH*}) were determined. The relationships between chemiluminescence and NO concentrations were established along the premixed ethanol flames. There was a strong connection between CH{sup *} radical chemiluminescence and NO formation and the prompt-NO was identified as the governing mechanism for NO production. The results suggest the optimum ratio of the chemiluminescence of two radicals (A{sub CH*}/A{sub OH*}) for NO diagnostic purposes. (author)

Marques, Carla S.T.; Barreta, Luiz G.; Sbampato, Maria E.; dos Santos, Alberto M. [Aerothermodynamic and Hypersonic Division, Institute of Advanced Studies - General Command of Aerospatial Technology, Rodovia dos Tamoios, km 5.5, 12228-001 Sao Jose dos Campos - SP (Brazil)

2010-11-15T23:59:59.000Z

183

Chlorophyll and acid rain  

NLE Websites -- All DOE Office Websites (Extended Search)

Chlorophyll and acid rain Chlorophyll and acid rain Name: beachbum Status: N/A Age: N/A Location: N/A Country: N/A Date: Around 1993 Question: A while ago I read an article that stated that after a plant received acid rain, there seemed to be less of chlorophyll a and b in the plant. I was wondering where does the chlorophyll go and what is the actual process (cell structure affected?). Replies: I think that less chlorophyll being present would be more likely a result of less being produced. Plant cell constantly turn over cell material, it will also constantly produce more. So if one compares a plant not exposed to acid rain (presumably producing a normal amount of chlorophyll and the exposed plant then one sees that the exposed plant has less chlorophyll than the unexposed plant. I do not think I can answer the rest of your question.

184

Nucleic Acid Softwars  

NLE Websites -- All DOE Office Websites (Extended Search)

Nucleic Acid Software Nucleic Acid Software FR3D, a software for finding local and composite recurrent structural motifs in RNA 3D structures. Sarver, M., Zirbel, C.L., Stombaugh, J., Mokdad, A. and Leontis, N.B. (2008) FR3D: finding local and composite recurrent structural motifs in RNA 3D structures. J Math Biol, 56, 215-252. RNAView, a program for quickly generating a display of RNA/DNA secondary structures with tertiary interactions. Yang, H., Jossinet, F., Leontis, N., Chen, L., Westbrook, J., Berman, H.M. and Westhof, E. (2003) Tools for the automatic identification and classification of RNA base pairs. Nucleic Acids Res, 31, 3450-3460. RNAMLview, a program to display and/or edit RNAView 2-dimensional diagrams. 3DNA, a software package for the analysis, rebuilding and visualization of three-dimensional nucleic acid structures.

185

Reactivity of Acid Generators  

NLE Websites -- All DOE Office Websites (Extended Search)

Reactivity of Acid Generators for Chemically Amplified Resists with Reactivity of Acid Generators for Chemically Amplified Resists with Low-Energy Electrons Atsuro Nakano, Takahiro Kozawa, Seiichi Tagawa, Tomasz Szreder, James F. Wishart, Toshiyuki Kai and Tsutomu Shimokawa Jpn. J. Appl. Phys., 45, L197-L200 (2006). [Find paper at the Japanese Journal of Applied Physics] Abstract: In chemically amplified resists for ionizing radiations such as electron beams and extreme ultraviolet (EUV), low-energy electrons play an important role in the pattern formation processes. The reactivity of acid generators with low-energy electrons was evaluated using solvated electrons in tetrahydrofuran, which were generated by a pulsed electron beam. The rate constants of acid generators with the solvated electrons ranged from 0.6 to 1.9 x 1011 M-1s-1

186

(Acid rain workshop)  

SciTech Connect

The traveler presented a paper entitled Susceptibility of Asian Ecosystems to Soil-Mediated Acid Rain Damage'' at the Second Workshop on Acid Rain in Asia. The workshop was organized by the Asian Institute of Technology (Bangkok, Thailand), Argonne National Laboratory (Argonne, Illinois), and Resource Management Associates (Madison, Wisconsin) and was sponsored by the US Department of Energy, the United Nations Environment Program, the United Nations Economic and Social Commission for Asia and the Pacific, and the World Bank. Papers presented on the first day discussed how the experience gained with acid rain in North America and Europe might be applied to the Asian situation. Papers describing energy use projections, sulfur emissions, and effects of acid rain in several Asian countries were presented on the second day. The remaining time was allotted to discussion, planning, and writing plans for a future research program.

Turner, R.S.

1990-12-05T23:59:59.000Z

187

Fatty Acid Carcass Mapping  

E-Print Network (OSTI)

FATTY ACID CARCASS MAPPING A Thesis by STACEY NICOLE TURK Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE May 2008... Major Subject: Animal Science FATTY ACID CARCASS MAPPING A Thesis by STACEY NICOLE TURK Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE...

Turk, Stacey N.

2010-01-14T23:59:59.000Z

188

The utilization of tricarboxylic acid cycle acids and the uptake of succinic acid by Neurospora crassa  

E-Print Network (OSTI)

THE UTILIZATION OF TRICARBOXYLIC ACID CYCLE ACIDS AND THE UPTAKE OF SUCCINIC ACID BY NEUROSPORA CRASSA A Thesis by PATTI LYNN GILLILAND Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirement... for the degree of MASTER OF SCIENCE August 1978 Ma) or Subject: Microbiology THE UTILIZATION OF TRICARBOXYLIC ACID CYCLE ACIDS AND THE UPTAKE OF SUCCINIC ACID BY NEUROSPORA CRASSA A Thesis by PATTI LYNN GILLILAND Approved as to style and content by...

Gilliland, Patti Lynn

2012-06-07T23:59:59.000Z

189

Focus Sheet | Hydrofluoric Acid Health hazards of hydrofluoric acid  

E-Print Network (OSTI)

Focus Sheet | Hydrofluoric Acid Health hazards of hydrofluoric acid Hydrofluoric acid (HF characterized by weight loss, brittle bones, anemia, and general ill health. Safe use If possible, avoid working to exposures. #12;Focus Sheet | Hydrofluoric Acid Environmental Health and Safety Environmental Programs Office

Wilcock, William

190

Mixture Preparation and Nitric Oxide Formation in a GDI Engine studied by Combined Laser Diagnostics and Numerical Modeling  

SciTech Connect

Through the combination of advanced imaging laser diagnostics with multi-dimensional computer models, a new understanding of the performance of direct-injection gasoline engines is pursuit. The work focuses on the fuel injection process, the breakup of the liquid into a fine spray and the mixing of the fuel with the in-cylinder gases. Non-intrusive laser diagnostics will be used to measure the spatial distribution of droplets and vaporized fuel with very high temporal resolution. These data along with temperature measurements will be used to validate a new spray breakup model for gasoline direct-injection. Experimental data on near wall fuel distributions will be used for comparison with a model that predicts the spray-wall interaction and the dynamics of the liquid film on the surface. Quantitative measurements of local nitric oxide concentrations inside the combustion chamber will provide a critical test for a numerical simulation of the nitric oxide formation process. This model is based on a modified flamelet approach and will be used to study the effects of exhaust gas recirculation.

Volker Sick; Dennis N. Assanis

2002-11-27T23:59:59.000Z

191

Optical high acidity sensor  

DOE Patents (OSTI)

An apparatus and method for determining acid concentrations in solutions having acid concentrations of from about 0.1 Molar to about 16 Molar is disclosed. The apparatus includes a chamber for interrogation of the sample solution, a fiber optic light source for passing light transversely through the chamber, a fiber optic collector for receiving the collimated light after transmission through the chamber, a coating of an acid resistant polymeric composition upon at least one fiber end or lens, the polymeric composition in contact with the sample solution within the chamber and having a detectable response to acid concentrations within the range of from about 0.1 Molar to about 16 Molar, a measurer for the response of the polymeric composition in contact with the sample solution, and, a comparer of the measured response to predetermined standards whereby the acid molarity of the sample solution within the chamber can be determined. Preferably, a first lens is attached to the end of the fiber optic light source, the first lens adapted to collimate light from the fiber optic light source, and a second lens is attached to the end of the fiber optic collector for focusing the collimated light after transmission through the chamber.

Jorgensen, Betty S. (Jemez Springs, NM); Nekimken, Howard L. (Los Alamos, NM); Carey, W. Patrick (Lynnwood, WA); O'Rourke, Patrick E. (Martinez, GA)

1997-01-01T23:59:59.000Z

192

Nucleic Acid Tools  

NLE Websites -- All DOE Office Websites (Extended Search)

Nucleic Acid Tools Nucleic Acid Tools RNA 3D Motif Atlas, a representative collection of RNA 3D internal and hairpin loop motifs. Petrov, A.I., Zirbel, C.L., Leontis, N.B. (2013) Automated classification of RNA 3D motifs and the RNA 3D motif atlas. RNA. Non-redundant List of RNA-containing 3D structures. Leontis, N.B., & Zirbel, C.L. (2012) In Leontis, N. B., Westhof. E. (ed.), RNA 3D structure analysis and prediction. Springer Berlin Heidelberg Vol. 27, pp. 281-298. RNA Base Triple Atlas, a collection of motifs consisting of two RNA basepairs. Abu Almakarem, A.S., Petrov, A.I., Stombaugh, J., Zirbel, C.L. and Leontis, N.B. (2012) Comprehensive survey and geometric classification of base triples in RNA structures. Nucleic Acids Res, 40, 1407-1423. R3D Align, an application for detailed nucleotide to nucleotide

193

A Direct, Biomass-Based Synthesis of Benzoic Acid: Formic Acid-Mediated Deoxygenation of the Glucose-Derived Materials Quinic Acid and Shikimic Acid  

SciTech Connect

An alternative biomass-based route to benzoic acid from the renewable starting materials quinic acid and shikimic acid is described. Benzoic acid is obtained selectively using a highly efficient, one-step formic acid-mediated deoxygenation method.

Arceo, Elena; Ellman, Jonathan; Bergman, Robert

2010-05-03T23:59:59.000Z

194

CX-005102: Categorical Exclusion Determination | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

5102: Categorical Exclusion Determination 5102: Categorical Exclusion Determination CX-005102: Categorical Exclusion Determination Spectroscopic Measurement of IsoparL in Supernate and Dilute Nitric Acid CX(s) Applied: B3.6 Date: 01/12/2011 Location(s): Aiken, South Carolina Office(s): Savannah River Operations Office Supernate (1.91 Moles hydroxide) and dilute nitric acid (0.001 Moles) containing up to 200 parts per million of IsoparL will be pumped across a horizontal containing light sensors for calibrating these sensors at different IsoparL concentrations in water at two temperatures (23 and 40 degrees Celsius). This test aims at build a calibration curve for the light sensors to be used in the field to detect oil-in-water solutions. DOCUMENT(S) AVAILABLE FOR DOWNLOAD CX-005102.pdf More Documents & Publications

195

Synthesis of acid addition salt of delta-aminolevulinic acid from 5-bromo levulinic acid esters  

DOE Patents (OSTI)

A process of preparing an acid addition salt of delta-aminolevulinc acid comprising: a) dissolving a lower alkyl 5-bromolevulinate and hexamethylenetetramine in a solvent selected from the group consisting of water, ethyl acetate, chloroform, acetone, ethanol, tetrahydrofuran and acetonitrile, to form a quaternary ammonium salt of the lower alkyl 5-bromolevulinate; and b) hydrolyzing the quaternary ammonium salt with an inorganic acid to form an acid addition salt of delta-aminolevulinic acid.

Moens, Luc (Lakewood, CO)

2003-06-24T23:59:59.000Z

196

Detailed modeling and laser-induced fluorescence imaging of nitric oxide in a NH3-seeded non-premixed methane/air flame  

E-Print Network (OSTI)

non-premixed methane/air flame John B. Bell, Marcus S. Day, Joseph F. Grcar Computing Sciences-induced fluorescence imaging of nitric oxide in a NH3-seeded non-premixed methane/air flame Abstract In this paper we study the formation of NO in laminar, nitrogen diluted methane diffusion flames that are seeded

Bell, John B.

197

Selective catalytic reduction (SCR) of nitric oxide (NO) with ammonia over vanadia-based and pillared interlayer clay-based catalysts  

E-Print Network (OSTI)

The selective catalytic reduction (SCR) of nitric oxide (NO) with ammonia over vanadia-based (V2O5-WO3/TiO2) and pillared interlayer clay-based (V2O5/Ti-PILC) monolithic honeycomb catalysts using a laboratory laminar-flow reactor was investigated...

Oh, Hyuk Jin

2004-09-30T23:59:59.000Z

198

B16 Melanoma Cell Arrest in the Mouse Liver Induces Nitric Oxide Release and Sinusoidal Cytotoxicity: A Natural Hepatic Defense against Metastasis  

Science Journals Connector (OSTI)

...Measurement of NO Production The method of Doi et al...Nitric oxide production by endothelial...comparison of three methods of quantification...cellular death via production of hydrogen peroxide in murine...Pharmacol. Toxicol. Methods, 35: 11-17...

Hui Helen Wang; Alan R. McIntosh; Brian B. Hasinoff; Edward S. Rector; Naeem Ahmed; Dwight M. Nance; and F. William Orr

2000-10-15T23:59:59.000Z

199

Deposition of Nitric Acid and Reactive Nitrogen at Harvard Forest The hourly gas-phase HNO3 concentration was measured at the Harvard Forest  

E-Print Network (OSTI)

Reactive nitrogen trace gas species play an important role in tropospheric photochemistry by stimulating gas-phase HNO3 concentration was measured at the Harvard Forest Environmental Measurement Site during radicals may be regenerated. Thus conversion of NOx radicals to HNO3 and subsequent deposition

200

Interphase transfer kinetics of thorium between nitric acid and tributyl phosphate solutions using the single drop and the Lewis cell techniques  

SciTech Connect

The kinetic rate constants for the interphase transfer of thorium between an aqueous phase and an organic phase of tributyl phosphate-n-paraffin hydrocarbon have been measured using the single drop and the Lewis cell techniques. Results from individual tests performed with the two techniques agree within experimental error. As with uranium, the data are consistent with a model in which the rate-controlling step is the rate of reaction of the components at the phase interface. An organic-soluble complex, represented by Th(NO/sub 3/)/sub 4/.2TBP, forms in the organic phase. The composition of this complex is confirmed by equilibrium, as well as by kinetic, data. The kinetic data include results from tests showing the effects of TBP concentration and nitrate concentration on the values of the forward and the reverse kinetic constants. Other tests show the effect of temperature on the kinetic constant in both the forward and the reverse transfer directions, and the activation energies and enthalpy for the extraction reactions were estimated from these data. Unlike uranium, thorium extraction was shown to have a Marangoni effect under certain conditions. 10 figures, 1 table.

Horner, D.E.; Mailen, J.C.; Coggins, J.R. Jr.; Thiel, S.W.; Scott, T.C.; Pih, N.; Yates, R.G.

1980-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "nitric acid cxs" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Corrosion of 304 Stainless Steel Exposed To Nitric Acid -Chloride Environments D.G. Kolman, D.K. Ford, D.P. Butt, and T.O. Nelson  

E-Print Network (OSTI)

(HNO3) process streams plays an important role in high-level radioactive waste reduction and long-term storage of radioactive material. Container materials for HNO3 process streams, such as pipes and holding

202

Precipitation of cesium jointly with uranium from nitric acid liquid radioactive wastes to obtain solid matrices for long-term storage  

Science Journals Connector (OSTI)

The possibility of converting liquid radioactive wastes containing Cs into chemically and thermodynamically stable...4U5O17...can be prepared by different procedures. The resulting compounds are characterized by ...

Yu. I. Korneiko; A. A. Murzin; O. V. Shmidt

2009-08-01T23:59:59.000Z

203

Aggregation and Protonation Phenomena in Third Phase Formation: An NMR Study of the Quaternary Malonamide/Dodecane/Nitric Acid/Water System  

Science Journals Connector (OSTI)

(2)?Nigond, L.; Condamines, N.; Cordier, P. Y.; Livet, J.; Madic, C.; Cuillerdier, C.; Musikas, C.; Hudson, M. J. Sep. ... (3)?Nigond, L.; Musikas, C.; Cuillerdier, C. Solvent Extr. ... Nigond, L.; Musikas, C.; Cuillerdier, C. ...

Lydie Lefrançois; Jean-Jacques Delpuech; Marc Hébrant; Jacques Chrisment; Christian Tondre

2001-03-10T23:59:59.000Z

204

Acidizing of Sandstone Reservoirs Using HF and Organic Acids  

E-Print Network (OSTI)

Mud acid, which is composed of HCl and HF, is commonly used to remove the formation damage in sandstone reservoirs. However, many problems are associated with HCl, especially at high temperatures. Formic-HF acids have served as an alternative...

Yang, Fei

2012-10-19T23:59:59.000Z

205

Page not found | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

91 - 25800 of 31,917 results. 91 - 25800 of 31,917 results. Download CX-005102: Categorical Exclusion Determination Spectroscopic Measurement of IsoparL in Supernate and Dilute Nitric Acid CX(s) Applied: B3.6 Date: 01/12/2011 Location(s): Aiken, South Carolina Office(s): Savannah River Operations Office http://energy.gov/nepa/downloads/cx-005102-categorical-exclusion-determination Download CX-005103: Categorical Exclusion Determination Operation of Zeiss Sigma VP Scanning Electron Microscope (SEM) CX(s) Applied: B3.6 Date: 01/12/2011 Location(s): Aiken, South Carolina Office(s): Savannah River Operations Office http://energy.gov/nepa/downloads/cx-005103-categorical-exclusion-determination Download CX-005104: Categorical Exclusion Determination 221-H Warm Gang Valve Corridor Section 9 Air Conditioner Replacement Unit

206

Page not found | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

81 - 8490 of 29,416 results. 81 - 8490 of 29,416 results. Download CX-006642: Categorical Exclusion Determination Actinide Removal Process (ARP)/Modular Caustic Side Solvent Extraction Unit (MCU) Life Extension Support Testing CX(s) Applied: B3.6 Date: 08/18/2011 Location(s): Aiken, South Carolina Office(s): Savannah River Operations Office http://energy.gov/nepa/downloads/cx-006642-categorical-exclusion-determination Download CX-000549: Categorical Exclusion Determination Solubility Testing of Boron and Gadolinium in Nitric Acid CX(s) Applied: B3.6 Date: 11/24/2009 Location(s): Aiken, South Carolina Office(s): Environmental Management, Savannah River Operations Office http://energy.gov/nepa/downloads/cx-000549-categorical-exclusion-determination Download CX-000822: Categorical Exclusion Determination

207

Acid Placement in Acid Jetting Treatments in Long Horizontal Wells  

E-Print Network (OSTI)

In the Middle East, extended reach horizontal wells (on the order of 25,000 feet of horizontal displacement) are commonly acid stimulated by jetting acid out of drill pipe. The acid is jetted onto the face of the openhole wellbore as the drill pipe...

Sasongko, Hari

2012-07-16T23:59:59.000Z

208

Acid placement and coverage in the acid jetting process  

E-Print Network (OSTI)

Many open-hole acid treatments are being conducted by pumping acid through jetting ports placed at the end of coiled tubing or drill pipe. The filter-cake on the bore-hole is broken by the jet; the acid-soluble material is dissolved, creating...

Mikhailov, Miroslav I.

2009-05-15T23:59:59.000Z

209

Studies of Fundamental Properties of Rutherfordium (element 104) using Organic Complexing Agents  

E-Print Network (OSTI)

the studies of TBP hydrolysis used nitric acid systems. The12 M. This is due to TBP extraction of nitric acid. At this1 M TBP in benzene and the concentration of nitric acid in

Czerwinski, K.R.

2010-01-01T23:59:59.000Z

210

Thermodynamic Investigations of Aqueous Ternary Complexes for Am/Cm Separation  

E-Print Network (OSTI)

not extractable by TBP at high nitric acid concentrations.that TBP is also more stable against attack by nitric acid.TBP in kerosene to extract Pu(IV) and U(VI) from nitric acid

Leggett, Christina Joy

2012-01-01T23:59:59.000Z

211

Pantothenic acid biosynthesis in zymomonas  

DOE Patents (OSTI)

Zymomonas is unable to synthesize pantothenic acid and requires this essential vitamin in growth medium. Zymomonas strains transformed with an operon for expression of 2-dehydropantoate reductase and aspartate 1-decarboxylase were able to grow in medium lacking pantothenic acid. These strains may be used for ethanol production without pantothenic acid supplementation in seed culture and fermentation media.

Tao, Luan; Tomb, Jean-Francois; Viitanen, Paul V.

2014-07-01T23:59:59.000Z

212

Carboxylic acid sorption regeneration process  

DOE Patents (OSTI)

Carboxylic acids are sorbed from aqueous feedstocks into an organic liquid phase or onto a solid adsorbent. The acids are freed from the sorbent phase by treating it with aqueous alkylamine thus forming an alkylammonium carboxylate which is dewatered and decomposed to the desired carboxylic acid and the alkylamine.

King, C. Judson (Kensington, CA); Poole, Loree J. (Baton Rouge, LA)

1995-01-01T23:59:59.000Z

213

Carboxylic acid sorption regeneration process  

DOE Patents (OSTI)

Carboxylic acids are sorbed from aqueous feedstocks into an organic liquid phase or onto a solid adsorbent. The acids are freed from the sorbent phase by treating it with aqueous alkylamine thus forming an alkylammonium carboxylate which is dewatered and decomposed to the desired carboxylic acid and the alkylamine. 10 figs.

King, C.J.; Poole, L.J.

1995-05-02T23:59:59.000Z

214

Nucleic acid detection methods  

DOE Patents (OSTI)

The invention relates to methods for rapidly determining the sequence and/or length a target sequence. The target sequence may be a series of known or unknown repeat sequences which are hybridized to an array of probes. The hybridized array is digested with a single-strand nuclease and free 3{prime}-hydroxyl groups extended with a nucleic acid polymerase. Nuclease cleaved heteroduplexes can be easily distinguish from nuclease uncleaved heteroduplexes by differential labeling. Probes and target can be differentially labeled with detectable labels. Matched target can be detected by cleaving resulting loops from the hybridized target and creating free 3-hydroxyl groups. These groups are recognized and extended by polymerases added into the reaction system which also adds or releases one label into solution. Analysis of the resulting products using either solid phase or solution. These methods can be used to detect characteristic nucleic acid sequences, to determine target sequence and to screen for genetic defects and disorders. Assays can be conducted on solid surfaces allowing for multiple reactions to be conducted in parallel and, if desired, automated. 18 figs.

Smith, C.L.; Yaar, R.; Szafranski, P.; Cantor, C.R.

1998-05-19T23:59:59.000Z

215

Acidic gas capture by diamines  

DOE Patents (OSTI)

Compositions and methods related to the removal of acidic gas. In particular, the present disclosure relates to a composition and method for the removal of acidic gas from a gas mixture using a solvent comprising a diamine (e.g., piperazine) and carbon dioxide. One example of a method may involve a method for removing acidic gas comprising contacting a gas mixture having an acidic gas with a solvent, wherein the solvent comprises piperazine in an amount of from about 4 to about 20 moles/kg of water, and carbon dioxide in an amount of from about 0.3 to about 0.9 moles per mole of piperazine.

Rochelle, Gary (Austin, TX); Hilliard, Marcus (Missouri City, TX)

2011-05-10T23:59:59.000Z

216

Pillared clays as superior catalysts for selective catalytic reduction of nitric oxide. Second semiannual report, 1996  

SciTech Connect

During the first six months of the program, the work has progressed as planned. We have constructed a reactor system and assembled all laboratory essentials for conducting the three-year project. First, the catalytic activities of the Cu(2+) ion exchanged alumina-pillared clay for the selective catalytic reduction of NO by ethylene were measured. The temperature range was 250-500{degrees}C. The activities of this catalyst were substantially higher than the catalyst that has been extensively studied in the literature, Cu-ZSM-5. Fourier Transform Infrared Spectroscopy (FTIR) was used to study the acidity of the catalyst. The second part of the work was an in-depth FTIR study of the NO decomposition mechanism on the catalyst. This was planned as the first and the key step to obtain an understanding of the reaction mechanism. Key surface intermediates were identified from the FTIR spectra, and a redox type Eley-Rideal mechanism was proposed for the NO decomposition on this catalyst. This report will be divided into two parts. In Part One, we report results on the catalytic activities of the Cu-alumina-pillared clay and a direct comparison with other known catalysts. In Part two, we focus on the FTIR study and from the results, we propose a NO decomposition mechanism on this new catalyst. Plans for the next six months include tests of different pillared clays as well as the catalytic mechanism. The micro reactor will continue to be the key equipment for measuring the catalytic activities. FTIR will continue to be the major technique for identifying surface species and hence understanding the reaction mechanism.

Yang, R.T.; Li, W.B.; Sirilumpen, M.; Tharapiwattananon, N.

1997-08-01T23:59:59.000Z

217

Ethylene Production from Linolenic Acid  

Science Journals Connector (OSTI)

... and Mapson1 have shown that linolenic 1 J acid may serve as a precursor of ethylene. The possi -bility that the ... . The possi -bility that the ethylene that is evolved from plants arises from linolenic acid was investigated by determining the relationship ...

F. B. ABELES

1966-04-02T23:59:59.000Z

218

Photochemical Studies on Xanthurenic Acid  

NLE Websites -- All DOE Office Websites (Extended Search)

Photochemical Studies on Xanthurenic Acid Photochemical Studies on Xanthurenic Acid J. E. Roberts, J. F. Wishart, L. Martinez, C. F. Chignell Photochem.Photobiol. 72, 467-471 (2000) Abstract: The tryptophan metabolite xanthurenic acid has been isolated from aged human cataractous lenses. The photophysical properties of xanthurenic acid were examined to determine if it is a potential chromophore for age-related cataractogenesis. We found that xanthurenic acid produces singlet oxygen (F*= 0.17; CD3OD) with the same efficiency as the lenticular chromophore N-formyl kynurenine and quenches singlet oxygen at a rate similar to other tryptophan metabolites (2.1 x 107 M-1 s-1; CD3OD) found in the eye. As the mechanisms of induction of cataracts may also involve redox reactions, the interactions of hydrated electrons (e-aq), the azide radical

219

Development of Nitric Oxide Oxidation Catalysts for the Fast SCR Reaction  

SciTech Connect

This study was undertaken in order to assess the potential for oxidizing NO to NO{sub 2} in flue gas environments, with the aim of promoting the so-called fast SCR reaction. In principle this can result in improved SCR kinetics and reduced SCR catalyst volumes. Prior to commencing experimental work, a literature study was undertaken to identify candidate catalysts for screening. Selection criteria comprised (1) proven (or likely) activity for NO oxidation, (2) low activity for SO2 oxidation (where data were available), and (3) inexpensive component materials. Catalysts identified included supported base metal oxides, supported and unsupported mixed metal oxides, and metal ion exchanged ZSM-5 (Fe, Co, Cu). For comparison purposes, several low loaded Pt catalysts (0.5 wt% Pt) were also included in the study. Screening experiments were conducted using a synthetic feed gas representative of flue gas from coal-fired utility boilers: [NO] = 250 ppm, [SO{sub 2}] = 0 or 2800 ppm, [H{sub 2}O] = 7%, [CO{sub 2}] = 12%, [O{sub 2}] = 3.5%, balance = N{sub 2}; T = 275-375 C. Studies conducted in the absence of SO{sub 2} revealed a number of supported and unsupported metal oxides to be extremely active for NO oxidation to NO{sub 2}. These included known catalysts (Co{sub 3}O{sub 4}/SiO{sub 2}, FeMnO{sub 3}, Cr{sub 2}O{sub 3}/TiO{sub 2}), as well as a new one identified in this work, CrFeO{sub x}/SiO{sub 2}. However, in the presence of SO{sub 2}, all the catalysts tested were found to be severely deactivated with respect to NO oxidation. Of these, Co{sub 3}O{sub 4}/SiO{sub 2}, Pt/ZSM-5 and Pt/CeO{sub 2} showed the highest activity for NO oxidation in the presence of SO{sub 2} (based on peak NO conversions to NO{sub 2}), although in no cases did the NO conversion exceed 7%. Reactor studies indicate there are two components to SO{sub 2}-induced deactivation of Co{sub 3}O{sub 4}/SiO{sub 2}, corresponding to an irreversible deactivation due to sulfation of the surface of the Co{sub 3}O{sub 4} phase, together with a reversible inhibition due to competitive adsorption of SO{sub 2} with NO on the catalyst. In an effort to minimize the deactivating effect of SO{sub 2} on Co{sub 3}O{sub 4}/SiO{sub 2}, two synthetic approaches were briefly examined. These consisted of (1) the incorporation of highly dispersed Co(II) ions in silica, as a non-sulfating matrix, via the sol-gel preparation of CoO-SiO{sub 2}; and (2) the sol-gel preparation of a mixed metal oxide, CoO-Nb{sub 2}O{sub 5}-SiO{sub 2}, with the aim of exploiting the acidity of the niobium oxide to minimize SO2 adsorption. While both catalysts showed almost no activity for NO oxidation in the absence of SO{sub 2}, when SO{sub 2} was present low activity was observed, indicating that SO{sub 2} acts as a promoter for NO oxidation over these materials. The kinetics of NO oxidation over Co{sub 3}O{sub 4}/SiO{sub 2}, Pt/SiO{sub 2} and Pt/CeO{sub 2} were also examined. Co{sub 3}O{sub 4}/SiO{sub 2} was found to exhibit a higher apparent activation energy for NO oxidation than the Pt catalysts, while the combined reaction order in NO and O{sub 2} for the three catalysts was very close to one. CO{sub 2} was found to have no effect on the kinetics of NO oxidation over these catalysts. The presence of H{sub 2}O caused a decrease in NO conversion for both Co{sub 3}O{sub 4}/SiO{sub 2} and Pt/CeO{sub 2} catalysts, while no effect was observed for Pt/SiO{sub 2}. The inhibiting effect of water was reversible and is attributed to competitive adsorption with the reactants. In sum, this study has shown that a variety of base metal catalysts are very active for NO oxidation. However, all of the catalysts studied are strongly deactivated in the presence of 2800 ppm SO{sub 2} at typical flue gas temperatures; consequently improving catalyst resistance to SO{sub x} will be a pre-requisite if the fast SCR concept is to be applied to coal-fired flue gas conditions.

Mark Crocker

2005-09-30T23:59:59.000Z

220

Treatment of acid mine wastewaters  

SciTech Connect

Acid mine drainage often results from the oxidation sulfide minerals to form sulfuric acid. As a consequence, high concentrations of metals in the both the suspended and dissolved state result from the low pH water. This paper discusses several of the more common treatment methods for acid mine drainage including the use of chemical precipitation agents, pH correction agents, filtration methods, and biodegradation methods. Advanced treatment technologies are also briefly described and include microfiltration, reverse osmosis, ion exchange, and electrodialysis.

Hayward, D.; Barnard, R.

1993-06-01T23:59:59.000Z

Note: This page contains sample records for the topic "nitric acid cxs" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Naphthenic acid corrosion literature survey  

SciTech Connect

Naphthenic acid corrosion is a growing concern for refineries processing crudes containing high levels of naphthenic acid. Due to this concern initiatives in place to better understand the mechanism of corrosion for mitigating the corrosion. During the 1996 Fall Corrosion Group, organized existing literature relevant to the literature search. Committee Week, NACE International many refineries have and evaluate methods T-8 Refining Industry a task group, T-8-22, to perform a review and compilation of naphthenic acid corrosion. This paper provides a summary of the literature research.

Babaian-Kibala, E. [Nalco/Exxon Energy Chemicals, Sugar Land, TX (United States); Nugent, M.J. [Tosco Refining Co., Linden, NJ (United States)

1999-11-01T23:59:59.000Z

222

Asphaltene damage in matrix acidizing  

E-Print Network (OSTI)

This work addresses the problem of asphaltene deposition that occurs during acid treatments of oil reservoirs. Asphaltenes are present to some degree in most hydrocarbons. Due to the molecular weight of the components these asphaltenes are more...

Hinojosa, Roberto Antonio

2012-06-07T23:59:59.000Z

223

Factors controlling naphthenic acid corrosion  

SciTech Connect

A laboratory study was conducted to elucidate the influence of chemical and physical parameters on corrosion of type 1018 carbon steel (CS, UNS G10180) and 5% Cr-0.5% Mo steel in oils containing naphthenic acids (NAs) for application to crude oil refinery systems. Effects of test duration, temperature, and acid concentration were assessed for a range of single acids of varying carbon numbers and for NA mixtures in mineral oil (MO) and in heavy vacuum gas oil (HGVO). In addition, a limited study of the effect of hydrogen sulfide (H{sub 2}S) addition to the acid-oil mixture was conducted. Use of the total acid number (TAN) as a measure of corrosiveness of a crude oil was discredited further. For the same TAN value, molecular size and structure of the acid were shown to have an important influence. Tests conducted in HGVO showed lower corrosion rates than in MO, suggesting inhibition caused by S species in the oil or the steric hindrance of naphtheno-aromatic acids. In oil containing the mixture of NAs, the corrosion rate of type 1018 CS was lower than that for 5% Cr-0.5% Mo steel. The 0.1% H{sub 2}S that passed through the acid-oil mixtures had an inhibiting effect on corrosion. Predicting corrosiveness of a crude oil from the measurement of TAN, distribution of NA composition, and S content and form was particularly challenging. The simple tests used were informative, but further work will be required to establish a standard test method that can provide an adequate ranking of crudes.

Turnbull, A. [National Physical Lab., Teddington (United Kingdom); Slavcheva, E. [Bulgarian Academy of Sciences, Sofia (Bulgaria); Shone, B. [Ty Isa, Nr Mold (United Kingdom)

1998-11-01T23:59:59.000Z

224

CX-006630: Categorical Exclusion Determination | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

30: Categorical Exclusion Determination 30: Categorical Exclusion Determination CX-006630: Categorical Exclusion Determination Modular Caustic Side Solvent Extraction (MCU) Improved Solvent Testing CX(s) Applied: B3.6 Date: 08/02/2011 Location(s): Aiken, South Carolina Office(s): Savannah River Operations Office In support of the Modular Caustic Side Solvent Extraction Unit (MCU), Savannah River National Laboratory (SRNL) will be investigating the properties of a new organic solvent blend. The new blend will contain a new extractant (MAXCalix) which has physical properties very similar to the current extractant (BoBCalix) (see Evaluation Checklist, TC-A-2005-045). The new solvent may also require a new acid stripping agent, which is boric acid (as opposed to nitric acid). Finally, the suppressor is changed from

225

CX-003634: Categorical Exclusion Determination | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

634: Categorical Exclusion Determination 634: Categorical Exclusion Determination CX-003634: Categorical Exclusion Determination Modular Caustic Side Solvent Extraction (MCU) Improved Solvent Testing CX(s) Applied: B3.6 Date: 08/09/2010 Location(s): Aiken, South Carolina Office(s): Savannah River Operations Office In support of the Modular Caustic Side Solvent Extraction Unit (MCU), Savannah River National Laboratory will be investigating the properties of a new organic solvent blend. The new blend will contain a new extractant (MAXCalix) which has physical properties very similar to the current extractant (BoBCalix). The new solvent may also require a new acid stripping agent, which is likely to be boric acid (as opposed to nitric acid). Finally, the suppressor may be changed from trioctlamine to a

226

I. Nuclear Production Reaction and Chemical Isolation Procedure for 240Am II. New Superheavy Element Isotopes: 242Pu(48Ca,5n)285-114  

E-Print Network (OSTI)

nitric acid solutions are selectively extracted by organophosphorus extrac- tants such as tributyl phosphate (TBP) [

Ellison, Paul Andrew

2011-01-01T23:59:59.000Z

227

Coagulase-Negative Staphylococci Favor Conversion of Arginine into Ornithine despite a Widespread Genetic Potential for Nitric Oxide Synthase Activity  

Science Journals Connector (OSTI)

...1128/JB.187.21.7292-7308.2005 . 38. Weckx, S , P De Rijk, C Van Broeckhoven and J Del-Favero. 2004. SNPbox: Web-based high-throughput primer design from gene to genome. Nucleic Acids Res. 32 :170-172. doi: 10.1093/nar/gkh369...

María Sánchez Mainar; Stefan Weckx; Frédéric Leroy

2014-10-03T23:59:59.000Z

228

A new N-hydroxyethyliminodiacetic acid modified core–shell silica phase for chelation ion chromatography of alkaline earth, transition and rare earth elements  

Science Journals Connector (OSTI)

Abstract Bare core–shell silica (1.7 ?m) has been modified with iminodiacetic acid functional groups via standard silane chemistry, forming a new N-hydroxyethyliminodiacetic acid (HEIDA) functionalised core–shell stationary phase. The column was applied in high-performance chelation ion chromatography and evaluated for the retention of alkaline earth, transition and heavy metal cations. The influence of nitric acid eluent concentration, addition of complexing agent dipicolinic acid, eluent pH and column temperature on the column performance was investigated. The efficiencies obtained for transition and heavy metal cations (and resultant separations) were comparable or better than those previously obtained for alternative fully porous silica based chelation stationary phases, and a similarly modified monolithic silica column, ranging from ?15 to 56 ?m HETP. Increasing the ionic strength of the eluent with the addition of KNO3 (0.75 M) and increasing the column temperature (70 °C) facilitated the isocratic separation of a mixture of 14 lanthanides and yttrium in under 12 min, with HETP averaging 18 ?m (7 ?m for Ce(III))

Nicola McGillicuddy; Ekaterina P. Nesterenko; Pavel N. Nesterenko; Elaine M. Stack; Jesse O. Omamogho; Jeremy D. Glennon; Brett Paull

2013-01-01T23:59:59.000Z

229

Development of All-Solid-State Sensors for Measurement of Nitric Oxide and Ammonia Concentrations by Optical Absorption in Particle-Laden Combustion Exhaust Streams  

SciTech Connect

An all-solid-state continuous-wave (cw) laser system for ultraviolet absorption measurements of the nitric oxide (NO) molecule has been developed and demonstrated. For the NO sensor, 250 nW of tunable cw ultraviolet radiation is produced by sum-frequency-mixing of 532-nm radiation from a diode-pumped Nd:YAG laser and tunable 395-nm radiation from an external cavity diode laser (ECDL). The sum-frequency-mixing process occurs in a beta-barium borate crystal. The nitric oxide absorption measurements are performed by tuning the ECDL and scanning the sum-frequency-mixed radiation over strong nitric oxide absorption lines near 226 nm. In Year 1 of the research, the nitric oxide sensor was used for measurements in the exhaust of a coal-fired laboratory combustion facility. The Texas A&M University boiler burner facility is a 30 kW (100,000 Btu/hr) downward-fired furnace with a steel shell encasing ceramic insulation. Measurements of nitric oxide concentration in the exhaust stream were performed after modification of the facility for laser based NOx diagnostics. The diode-laser-based ultraviolet absorption measurements were successful even when the beam was severely attenuated by particulate in the exhaust stream and window fouling. Single-laser-sweep measurements were demonstrated with an effective time resolution of 100 msec, limited at this time by the scan rate of our mechanically tuned ECDL system. In Year 2, the Toptica ECDL in the original system was replaced with a Sacher Lasers ECDL. The mode-hop-free tuning range and tuning rate of the Toptica ECDL were 25 GHz and a few Hz, respectively. The mode-hop-free tuning range and tuning rate of the Sacher Lasers ECDL were 90 GHz and a few hundred Hz, respectively. The Sacher Lasers ECDL thus allows us to scan over the entire NO absorption line and to determine the absorption baseline with increased accuracy and precision. The increased tuning rate is an advantage in that data can be acquired much more rapidly and the absorption measurements are less susceptible to the effects of transient fluctuations in the properties of the coal combustor exhaust stream. Gas cell measurements were performed using the NO sensor with the new ECDL, and a few spectra were acquired from the coal exhaust stream. However, the laser diode in the new ECDL failed during the coal combustor tests. In Year 3, however, we obtained a new GaN laser diode for our ECDL system, installed it, and completed an extensive series of measurements in the Texas A&M coal-fired laboratory combustion facility. The combustor was operated with coal and coal/biomass as fuels, with and without reburn, and with and without ammonia injection. Several different fuel equivalence ratios were investigated for each operating condition.

Jerald A. Caton; Kalyan Annamalai; Robert P. Lucht

2006-12-31T23:59:59.000Z

230

Method for production of petroselinic acid and OMEGA12 hexadecanoic acid in transgenic plants  

DOE Patents (OSTI)

The present invention relates to a process for producing lipids containing the fatty acid, petroselinic acid, in plants. The production of petroselinic acid is accomplished by genetically transforming plants which do not normally accumulate petroselinic acid with a gene for a {omega}12 desaturase from another species which does normally accumulate petroselinic acid. 19 figs.

Ohlrogge, J.B.; Cahoon, E.B.; Shanklin, J.; Somerville, C.R.

1995-07-04T23:59:59.000Z

231

Method for production of petroselinic acid and OMEGA12 hexadecanoic acid in transgenic plants  

DOE Patents (OSTI)

The present invention relates to a process for producing lipids containing the fatty acid petroselinic acid in plants. The production of petroselinic acid is accomplished by genetically transforming plants which do not normally accumulate petroselinic acid with a gene for a .omega.12 desaturase from another species which does normally accumulate petroselinic acid.

Ohlrogge, John B. (Okemos, MI); Cahoon, Edgar B. (Lansing, MI); Shanklin, John (Upton, NY); Somerville, Christopher R. (Okemos, MI)

1995-01-01T23:59:59.000Z

232

Sandstone Acidizing Using Chelating Agents and their Interaction with Clays  

E-Print Network (OSTI)

Sandstone acidizing has been carried out with mud acid which combines hydrochloric acid and hydrofluoric acid at various ratios. The application of mud acid in sandstone formations has presented quite a large number of difficulties like corrosion...

George, Noble Thekkemelathethil 1987-

2013-01-09T23:59:59.000Z

233

New syntheses of aminoalkylphosphonic acids  

E-Print Network (OSTI)

NEW SYNTHESES OF AMINOALKYLPHOSPHON1C ACIDS A Thesis by John Frederick DeBardeleben, Jr. Su'bmitted to the Graduate School of the Agricultural and Mechanical College of Texas in partial fulfillment of the requirements for the degree of MASTER... OF SCIENCE August 196$ Major Subject: Chemistry NEW SYNTHESES OF AMINOALKYLPHOSPHONIC ACIDS A Thesis BY John Frederick DeBardeleben, Jr. Approved as to style and content hy: (Chairman of Committee) iJ C wc+'. A-c-~-' & (Head of Department...

DeBardeleben, John Frederick

2012-06-07T23:59:59.000Z

234

Kinetic Study on the Acid-Catalyzed Hydrolysis of Cellulose to Levulinic Acid  

Science Journals Connector (OSTI)

A variety of interesting bulk chemicals is accessible by the acid-catalyzed hydrolysis of cellulose. An interesting example is levulinic acid, a versatile precursor for fuel additives, polymers, and resins. A detailed kinetic study on the acid-catalyzed ...

B. Girisuta; L. P. B. M. Janssen; H. J. Heeres

2007-02-13T23:59:59.000Z

235

Acid Catalysis in Modern Organic  

E-Print Network (OSTI)

catalyst for organic synthesis". That is the starting sentence of this book by Yamamoto and Ishihara, which follows their earlier book "Lewis Acids in Organic Synthesis (2000)", and covers the new developments book that should be available in every well-equipped chemistry library. It will certainly be helpful

Snyder, Scott A.

236

E-Print Network 3.0 - acid linoleic acid Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

FAs (linolenic, linoleic) - - monounsaturated FAs (oleic acid) - olive, canola - hydrogenation... Biol 458 Lecture 6 & 7 Fatty Acids 1 A. Introduction to acyl lipids...

237

Studies On Advanced Lead-Acid Batteries.  

E-Print Network (OSTI)

??Subsequent to the studies on precursor lead-acid systems by Daniel, Grove and Sindesten, practical lead-acid batteries began with the research and inventions of Raymond Gaston… (more)

Martha, Surendra Kumar

2005-01-01T23:59:59.000Z

238

Modeling of Acid Fracturing in Carbonate Reservoirs  

E-Print Network (OSTI)

The acid fracturing process is a thermal, hydraulic, mechanical, and geochemical (THMG)-coupled phenomena in which the behavior of these variables are interrelated. To model the flow behavior of an acid into a fracture, mass and momentum balance...

Al Jawad, Murtada s

2014-06-05T23:59:59.000Z

239

Synthesis of Biodiesel via Acid Catalysis  

Science Journals Connector (OSTI)

Synthesis of Biodiesel via Acid Catalysis ... Biodiesel is synthesized via the transesterification of lipid feedstocks with low molecular weight alcohols. ... Nonetheless, acid-catalyzed processes could produce biodiesel from low-cost feedstocks, lowering production costs. ...

Edgar Lotero; Yijun Liu; Dora E. Lopez; Kaewta Suwannakarn; David A. Bruce; James G. Goodwin, Jr.

2005-01-25T23:59:59.000Z

240

Nitric Oxide and Oxygen Radical Attack on GDP-Dissociation Inhibitor 2 (GDI-2) in Spinal Cord Injury of the Rat  

Science Journals Connector (OSTI)

Nitric Oxide and Oxygen Radical Attack on GDP-Dissociation Inhibitor 2 (GDI-2) in Spinal Cord Injury of the Rat ... Herein, mass spectrometry unambiguously identified GDP-dissociation inhibitor-2 (GDI-2) in SCI with post-translational modifications of 3-aminotyrosine (8 h post-injury) and an acrolein adduct of GDI-2 (72 h post-injury). ... Protein profiling in SCI of the rat revealed that, at 8 h following the traumatic lesion, levels of a signalling protein, GDP-dissociation inhibitor-2 protein (GDI-2) (synonym:? Rab GDP dissociation inhibitor beta), were increased about 3-fold, and we therefore decided to use this potentially important signalling structure to study the presence of oxidation- and nitration-induced PTMs in SCI. ...

Julius Paul Pradeep John; Oliver Pintsov; Alexander Petter-Puchner; Heinz Redl; Arnold Pollak; Wei-Qiang Chen; Gert Lubec

2007-02-22T23:59:59.000Z

Note: This page contains sample records for the topic "nitric acid cxs" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

CX-005766: Categorical Exclusion Determination | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

6: Categorical Exclusion Determination 6: Categorical Exclusion Determination CX-005766: Categorical Exclusion Determination Filter Testing with Static Test Cell CX(s) Applied: B3.6 Date: 04/20/2011 Location(s): Aiken, South Carolina Office(s): Environmental Management, Savannah River Operations Office Researchers plan to use the static test cell to conduct filter tests with a variety of filter media. The feed for the tests will consist of water, simulated Savannah River Site (SRS) salt solution, nitric acid, oxalic acid, sodium hydroxide, simulated SRS sludge, monosodium titanate, and crystalline silicotitanate. DOCUMENT(S) AVAILABLE FOR DOWNLOAD CX-005766.pdf More Documents & Publications CX-002994: Categorical Exclusion Determination CX-005870: Categorical Exclusion Determination CX-002992

242

Chemical Additive Selection in Matrix Acidizing  

E-Print Network (OSTI)

critical detail of weak acid chemistry. One concern when using any acid in oilfield operations is the corrosion of well tubulars. Thus operators often choose to pump corrosion inhibitor, a chemical additive electrostatically attracted... in oilfield operations, each of which protects well tubulars using the same mechanism: by impeding the acid?s ability to diffuse to the tubing surface. Because of the unique attraction of corrosion inhibitor to the metal surface, and the corrosion inhibitor...

Weidner, Jason 1981-

2011-05-09T23:59:59.000Z

243

Sandia National Laboratories: Due Diligence on Lead Acid Battery...  

NLE Websites -- All DOE Office Websites (Extended Search)

Due Diligence on Lead Acid Battery Recycling March 23, 2011 Lead Acid Batteries on secondary containment pallet Lead Acid Batteries on secondary containment pallet In 2004, the US...

244

Hydrogen-Bond Acidic Polymers for Chemical Vapor Sensing. | EMSL  

NLE Websites -- All DOE Office Websites (Extended Search)

Acidic Polymers for Chemical Vapor Sensing. Hydrogen-Bond Acidic Polymers for Chemical Vapor Sensing. Abstract: A review with 171 references. Hydrogen-bond acidic polymers for...

245

Unnatural reactive amino acid genetic code additions  

DOE Patents (OSTI)

This invention provides compositions and methods for producing translational components that expand the number of genetically encoded amino acids in eukaryotic cells. The components include orthogonal tRNAs, orthogonal aminoacyl-tRNA synthetases, orthogonal pairs of tRNAs/synthetases and unnatural amino acids. Proteins and methods of producing proteins with unnatural amino acids in eukaryotic cells are also provided.

Deiters, Alexander; Cropp, T. Ashton; Chin, Jason W.; Anderson, J. Christopher; Schultz, Peter G.

2014-08-26T23:59:59.000Z

246

Radioiodinated fatty acid analogs for myocardial imaging  

SciTech Connect

Fatty acids are the preferred substrate for the normoxic heart. About sixty percent of the energy required by the myocardium is provided by fatty acid [beta]-oxidation. Many scientists have focused on the alterations in fatty acid metabolism in the ischemic heart for the development of radiolabelled fatty acids for functional imaging of the heart. Three main categories of compounds were synthesized: tetrazoles (1 and 2), glycidic and [alpha]-methylene acids (3-5), and analogs of oleic acid (6,7 and 7A). The tetrazole group has a similar pKa and size to that of a carboxyl group; however, such fatty acid analogs cannot undergo normal fatty acid metabolism. Glycidic and [alpha]-methylene analogs are potential irreversible inhibitors of fatty acid metabolism. Oleic acid analogs were investigated to assess the affect of stereochemical consequences on biodistribution. The key intermediates in the synthesis of the target compounds were [omega]-nitrophenyl alkylcarboxylic acids and alcohols, which were made using a variety of cross-coupling reactions. The Wittig reaction, which was used in the synthesis of tetrazole 1 and glycidic acid 3, gave low yields of the cross-coupled products. The remaining target compounds were synthesized by condensation of appropriate RCu (CN) ZnI and substituted benzyl bromides or by Pd[sup II] catalyzed cross-coupling of substituted arylhalides with suitable alkynes. The latter two reactions produced much higher yields of the desired products. All of the target compounds were radiolabeled with [sup 125]I by various Cu(I) catalyzed radioiodine exchange procedures and were then subjected to tissue biodistribution (TD) studies in rats. Except for the 15-(4-iodophenyl)-2-methylene-pentadecanoic acid (5), all of the fatty acid analogs failed to surpass clinically-used 15-(4-iodophenyl)pentadecanoic acid (IPPA) in their ability to be taken up and retained by the rat myocardium.

Ruyan, M.K.

1993-01-01T23:59:59.000Z

247

Iron oxide and chromia supported on titania-pillared clay for selective catalytic reduction of nitric oxide with ammonia  

SciTech Connect

TiO{sub 2}-pillard clay (PILC) with high surface area, large pore volume, and large interlayer spacing was used as the support for mixed Fe{sub 2}O{sub 3} and Cr{sub 2}O{sub 3} as the catalyst for selective catalytic reduction (SCR) of NO with NH{sub 3}. The Fe/Cr ratio was varied at a fixed total amount of oxide dopant of 10% (wt). The Fe-Cr/TiO{sub 2}-PILC with Fe/Cr=3 showed the highest activity. Compared with commercial V{sub 2}O{sub 5}/TiO{sub 2} catalysts, the activity (on a per gram basis) of the doped pillared clay was approximately twice as high under H{sub 2}O- and SO{sub 2}-free conditions and was approximately 40% higher under conditions with H{sub 2}O and SO{sub 2}. In addition, its activity for SO{sub 2} oxidation was only 20%-25% of that of the V{sub 2}O{sub 5}-based catalysts. TPD of NH{sub 3} on the Fe-Cr/TiO{sub 2}-PILC catalyst showed that both M=O and M-OH (M=Fe or Cr) were necessary for the SCR reaction. In situ IR spectra of NH{sub 3} showed that there was a higher Bronsted acidity than the Lewis acidity on the surface under reaction conditions and that there existed a direct correlation between the SCR activity and the Bronsted acidity among pillared clays with different Fe/Cr ratios. These results, along with the transient response to O{sub 2}, indicated that a similar mechanism to that on the V{sub 2}O{sub 5} catalyst was operative. The TiO{sub 2}-pillared clay used as the support also contributed to the high activity of the Fe-Cr catalyst. The TiO{sub 2} pillars combined with the tetrahedral SiO{sub 2} surfaces of the clay apparently gave rise to a high dispersion of Fe{sub 2}O{sub 3}. 52 refs., 10 figs., 5 tabs.

Cheng, L.S.; Yang, R.T. [State Univ. of New York, Buffalo, NY (United States)] [State Univ. of New York, Buffalo, NY (United States); Ning Chen [Univ. of Michigan, Ann Arbor, MI (United States)] [Univ. of Michigan, Ann Arbor, MI (United States)

1996-11-01T23:59:59.000Z

248

Acid Fracture and Fracture Conductivity Study of Field Rock Samples  

E-Print Network (OSTI)

Acid fracturing is a well stimulation strategy designed to increase the productivity of a producing well. The parameters of acid fracturing and the effects of acid interaction on specific rock samples can be studied experimentally. Acid injection...

Underwood, Jarrod

2013-11-15T23:59:59.000Z

249

Micro-electro-mechanical systems phosphoric acid fuel cell  

DOE Patents (OSTI)

A phosphoric acid fuel cell system comprising a porous electrolyte support, a phosphoric acid electrolyte in the porous electrolyte support, a cathode electrode contacting the phosphoric acid electrolyte, and an anode electrode contacting the phosphoric acid electrolyte.

Sopchak, David A. (Livermore, CA); Morse, Jeffrey D. (Martinez, CA); Upadhye, Ravindra S. (Pleasanton, CA); Kotovsky, Jack (Oakland, CA); Graff, Robert T. (Modesto, CA)

2010-12-21T23:59:59.000Z

250

Micro-electro-mechanical systems phosphoric acid fuel cell  

DOE Patents (OSTI)

A phosphoric acid fuel cell system comprising a porous electrolyte support, a phosphoric acid electrolyte in the porous electrolyte support, a cathode electrode contacting the phosphoric acid electrolyte, and an anode electrode contacting the phosphoric acid electrolyte.

Sopchak, David A. (Livermore, CA); Morse, Jeffrey D. (Martinez, CA); Upadhye, Ravindra S. (Pleasanton, CA); Kotovsky, Jack (Oakland, CA); Graff, Robert T. (Modesto, CA)

2010-08-17T23:59:59.000Z

251

Common amino acid domain among endopolygalacturonases of ascomycete fungi.  

Science Journals Connector (OSTI)

...How- ever, amino acid compositions of homogeneous PGs appear...Mugnier (Rhone-Poulenc Agrochemical Co., France). C. lindemuthianum...Pharmacia). Amino acid composition. Amino acid analysis was...chromatography. amino acid compositions of the three purified materials...

J P Keon; G Waksman

1990-08-01T23:59:59.000Z

252

Acid-catalytic decomposition of peracetic acid in the liquid phase  

SciTech Connect

This paper elucidates the kinetic relationships of peracetic acid (PAA) decomposition in the presence of mineral acids and their heterogeneous analogs, polystyrene-di-vinylbenzene cation-exchangers, differing in physicochemical and morphological parameters. It is shown that the thermal decomposition of PAA in acetic acid is an acid-catalyzed reaction. The controlling step of the reaction is protonation of the substrate with formation of an active intermediate form. Sulfonated cation-exchangers are twice as effective as sulfuric acid in this process. Polystyrene-divinylbenzene sulfonated cation-exchangers can be used with success as acid catalysts in oxidation processes involving PAA, because of their high effectiveness, stability, and availability.

Kharchuk, V.G.; Kolenko, I.P.; Petrov, L.A.

1985-12-01T23:59:59.000Z

253

Self-assembling multimeric nucleic acid constructs  

DOE Patents (OSTI)

The invention is directed to constructs and compositions containing multimeric forms of nucleic acid. Multimeric nucleic acids comprise single-stranded nucleic acids attached via biotin to streptavidin and bound with a functional group. These constructs can be utilized in vivo to treat or identify diseased tissue or cells. Repeated administrations of multimeric nucleic acid compositions produce a rapid and specific amplification of nucleic acid constructs and their attached functional groups. For treatment purposes, functional groups may be toxins, radioisotopes, genes or enzymes. Diagnostically, labeled multimeric constructs may be used to identify specific targets in vivo or in vitro. Multimeric nucleic acids may also be used in nanotechnology and to create self-assembling polymeric aggregates such as membranes of defined porosity, microcircuits and many other products.

Cantor, Charles R. (Boston, MA); Niemeyer, Christof M. (Bremen, DE); Smith, Cassandra L. (Boston, MA); Sano, Takeshi (Boston, MA); Hnatowich, Donald J. (Brookline, MA); Rusckowski, Mary (Southborough, MA)

1996-01-01T23:59:59.000Z

254

Self-assembling multimeric nucleic acid constructs  

DOE Patents (OSTI)

The invention is directed to constructs and compositions containing multimeric forms of nucleic acid. Multimeric nucleic acids comprise single-stranded nucleic acids attached via biotin to streptavidin and bound with a functional group. These constructs can be utilized in vivo to treat or identify diseased tissue or cells. Repeated administrations of multimeric nucleic acid compositions produce a rapid and specific amplification of nucleic acid constructs and their attached functional groups. For treatment purposes, functional groups may be toxins, radioisotopes, genes or enzymes. Diagnostically, labeled multimeric constructs may be used to identify specific targets in vivo or in vitro. Multimeric nucleic acids may also be used in nanotechnology and to create self-assembling polymeric aggregates such as membranes of defined porosity, microcircuits and many other products.

Cantor, Charles R. (Boston, MA); Niemeyer, Christof M. (Bremen, DE); Smith, Cassandra L. (Boston, MA); Sano, Takeshi (Boston, MA); Hnatowich, Donald J. (Brookline, MA); Rusckowski, Mary (Southborough, MA)

1999-10-12T23:59:59.000Z

255

Testing of organic acids in engine coolants  

SciTech Connect

The effectiveness of 30 organic acids as inhibitors in engine coolants is reported. Tests include glassware corrosion of coupled and uncoupled metals. FORD galvanostatic and cyclic polarization electrochemistry for aluminum pitting, and reserve alkalinity (RA) measurements. Details of each test are discussed as well as some general conclusions. For example, benzoic acid inhibits coupled metals well but is ineffective on cast iron when uncoupled. In benzoic acid inhibits coupled metals well but is ineffective on cast iron when uncoupled. In general, the organic acids provide little RA when titrated to a pH of 5.5, titration to a pH of 4.5 can result in precipitation of the acid. Trends with respect to acid chain length are reported also.

Weir, T.W. [ARCO Chemical Co., Newtown Square, PA (United States)

1999-08-01T23:59:59.000Z

256

Basic and Acidic Leaching of Sludge from Melton Valley Storage Tank W-25  

SciTech Connect

Bench-scale leaching tests were conducted with samples of tank waste sludge from the Melton Valley Storage Tank (MVST) Facility at Oak Ridge National Laboratory (ORNL) to evaluate separation technology processes for use in concentrating the radionuclides and reducing the volume of waste for final disposal. This paper discusses the hot cell apparatus, the characterization of the sludge, the leaching methodology, and the results obtained from a variety of basic and acidic leaching tests of samples of sludge at ambient temperature. Basic leaching tests were also conducted at 75 and 95 deg C. The major alpha-,gamma., and beta-emitting radionuclides in the centrifuged, wet sludge solids were {sup 137}Cs, {sup 60}Co, {sup 154}Eu, {sup 241}Am, {sup 244}Cm {sup 90}Sr, Pu, U, and Th. The other major metals (in addition to the U and Th) and anions were Na, Ca, Al, K, Mg, NO{sub 3}{sup -},CO{sub 3}{sup 2-}, OH{sup -}, and O{sup 2-} organic carbon content was 3.0 +/- 1.0%. The pH was 13. A surprising result was that about 93% of the {sup 137}Cs in the centrifuged, wet sludge solids was bound in the solids and could not be solubilized by basic leaching at ambient temperature and 75 deg C. However, the solubility of the {sup 137}Cs was enhanced by heating the sludge to 95 deg C. In one of the tests,about 42% of the {sup 137}Cs was removed by leaching with 6.3 M NaOH at 95 deg C.Removing {sup 137}Cs from the W-25 sludge with nitric acid was a slow process. About 13% of the {sup 137}Cs was removed in 16 h with 3.0 M HNO{sub 3}. Only 22% of the {sup 137}Cs was removed in 117 h usi 6.0 M HNO{sub 3}. Successive leaching of sludge solids with 0.5 M, 3.0 M, 3.0 M; and 6.0 M HNO{sub 3} for a total mixing time of 558 h removed 84% of the {sup 137}Cs. The use of caustic leaching prior to HNO{sub 3} leaching, and the use of HF with HNO{sub 3} in acidic leaching, increased the rate of {sup 137}Cs dissolution. Gel formation proved to be one of the biggest problems associated with HNO{sub 3} leaching of the W-25 sludge.

Collins, J.L., Egan, B.Z., Beahm, E.C., Chase, C.W., Anderson, K.K.

1997-10-01T23:59:59.000Z

257

Superior catalysts for selective catalytic reduction of nitric oxide. Annual technical report, September 30, 1993--September 29, 1994  

SciTech Connect

A delaminated Fe{sub 2}O{sub 3}-pillared clay catalyst was prepared for the selective catalytic reduction (SCR) of NO by NH{sub 3} at above 300{degrees}C. The delaminated pillard clay was characterized by ICP-AES (Inductively Coupled Plasma-Atomic Emission Spectroscopy) chemical analysis, XRD (X-ray diffraction) structure and line broadening analyses, micropore size probing, and Moessbauer analysis. These analyses showed that the catalyst contained fragmented Fe{sub 2}O{sub 3}-pillared clay forming {open_quotes}house-of-cards{close_quotes} structure with dispersed Fe{sub 2}O{sub 3} particles approximately 170 {angstrom} in size. The SCR activity of the delaminated pillard clay was higher than the commercial-type V{sub 2}O{sub 5} + WO{sub 3}/TiO{sub 2} catalyst, and also higher than the undelaminated pillard clay and supported Fe{sub 2}O{sub 3} catalysts, under conditions with SO{sub 2}. Infrared measurements of adsorbed NH{sub 3} showed strong Bronsted acidity which was caused possibly by interactions between Fe{sub 2}O{sub 3} and clay.

Chen, J.P.; Hausladen, M.C.; Yang, R.T.

1995-03-01T23:59:59.000Z

258

Waste acid recycling via diffusion dialysis  

SciTech Connect

Inorganic acids are commonly used for surface cleaning and finishing of metals. The acids become unuseable due to contamination with metals or diluted and weakened. Diffusion dialysis has become a way to recover the useable acid and allow separation of the metals for recovery and sale to refineries. This technique is made possible by the use of membranes that are strong enough to withstand low ph and have long service life.

Steffani, C.

1995-05-26T23:59:59.000Z

259

Organic Phosphoric Acid of the Soil.  

E-Print Network (OSTI)

TEXAS AGRICULTURAL EXPERIMENT STATIONS BULLETIN NO. +6CT /36 CHEMICAL SECTION, FEBRUARY, 191 1 I TECHNICAL BULLETIN Organic Phosphoric Acid of the Soil BY G. S. FRAPS, Chemist POSTOFFICE College Station, Brazos County, 'Texas. ,\\ustin... . ................................................ introduction 5 .............................. hmmonia-Soluble Phosphoric Acid 5 ................ Solubility of Phosphates in Ammonia 6 I Fixation of Phosphoric Acid from Ammonia .......... 7 Effect of Ratio of Soil to Solvent in Extraction of Phos- I I...

Fraps, G. S. (George Stronach)

1911-01-01T23:59:59.000Z

260

Carboxylic acid accelerated formation of diesters  

DOE Patents (OSTI)

This invention pertains to accelerating the rate of formation of 1,1-dicarboxylic esters from the reaction of an aldehyde with a carboxylic acid anhydride or a ketene in the presence of a non-iodide containing a strong Bronsted acid catalyst by the addition of a carboxylic acid at about one bar pressure and between about 0 and 80 C in the substantial absence of a hydrogenation or carbonylation catalyst.

Tustin, G.C.; Dickson, T.J.

1998-04-28T23:59:59.000Z

Note: This page contains sample records for the topic "nitric acid cxs" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Acid Doped Membranes for High Temperature PEMFC  

Energy.gov (U.S. Department of Energy (DOE))

Presentation on Acid Doped Membranes for High Temperature PEMFC to the High Temperature Membrane Working Group, May 25, 2004 in Philadelphia, PA.

262

Biomedical Application of Hyaluronic Acid Nanoparticles  

E-Print Network (OSTI)

Hyaluronic acid (HA) is a naturally occurring biodegradable polymer with a variety of applications in medicine including tissue engineering, dermatological fillers, and viscosupplementation for osteoarthritis treatment. ...

Fakhari, Amir

2012-05-31T23:59:59.000Z

263

Nucleic Acid Standards - Program List  

NLE Websites -- All DOE Office Websites (Extended Search)

List of Programs and References List of Programs and References CEHS M. A. El Hassan & C. R. Calladine (1995). ``The Assessment of the Geometry of Dinucleotide Steps in Double-Helical DNA: A New Local Calculation Scheme.'' J. Mol. Biol. 251, 648-664. X. J. Lu, M. A. El Hassan & C. A. Hunter (1997). ``Structure and Conformation of Helical Nucleic Acids: Analysis Program (SCHNAaP).''J. Mol. Biol. 273, 668-680. CompDNA (Please refer to Dr. Andrey A. Gorin: agor@sbnmr1.ski.mskcc.org OR Dr. Victor B. Zhurkin: zhurkin@lmmb.nci.nih.gov) A. A. Gorin, V. B. Zhurkin & W. K. Olson (1995). ``B-DNA Twisting Correlates with Base-pair Morphology.'' J. Mol. Biol. 247, 34-48. K. M. Kosikov, A. A. Gorin, V. B. Zhurkin & W. K. Olson (1999). ``DNA Stretching and Compression: Large-scale Simulations of Double Helical

264

Nucleic Acid Standards - Refinement Parameters  

NLE Websites -- All DOE Office Websites (Extended Search)

Refinement Parameters Refinement Parameters The DNA/RNA topology and parameter files for X-PLOR are shown below. These were tested with DNA structures and with protein-DNA complexes. X-PLOR topology file X-PLOR parameter files: X-PLOR parameter file For the refinement of high resolution structures (< 1.7 Angstroms) the parameter file with distinct bond distances and bond angles for both C2'-endo and C3'-endo conformations should be considered: X-PLOR parameter file for high resolution structures "New Parameters for the Refinement of Nucleic Acid Containing Structures." Gary Parkinson, Jaroslav Vojtechovsky, Lester Clowney, Axel Brunger*, and Helen M. Berman. (1996) Acta Cryst. D 52, 57-64 Rutgers University, Department of Chemistry, Piscataway, NJ 08855-0939; *The Howard Hughes Medical Institute and Departments of Molecular and

265

E-Print Network 3.0 - acid eicosapentaenoic acid Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

Sample search results for: acid eicosapentaenoic acid Page: << < 1 2 3 4 5 > >> 1 Fish or Fish Oil in the Diet and Heart Attacks MAURICE E. STANSBY Summary: . Further...

266

E-Print Network 3.0 - acids eicosapentaenoic acid Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

Sample search results for: acids eicosapentaenoic acid Page: << < 1 2 3 4 5 > >> 1 Fish or Fish Oil in the Diet and Heart Attacks MAURICE E. STANSBY Summary: . Further...

267

Organic acid-tolerant microorganisms and uses thereof for producing organic acids  

DOE Patents (OSTI)

Organic acid-tolerant microorganisms and methods of using same. The organic acid-tolerant microorganisms comprise modifications that reduce or ablate AcsA activity or AcsA homolog activity. The modifications increase tolerance of the microorganisms to such organic acids as 3-hydroxypropionic acid (3HP), acrylic acid, and propionic acid. Further modifications to the microorganisms such as increasing expression of malonyl-CoA reductase and/or acetyl-CoA carboxylase provide or increase the ability of the microorganisms to produce 3HP. Methods of generating an organic acid with the modified microorganisms are provided. Methods of using acsA or homologs thereof as counter-selectable markers include replacing acsA or homologs thereof in cells with genes of interest and selecting for the cells comprising the genes of interest with amounts of organic acids effective to inhibit growth of cells harboring acsA or the homologs.

Pfleger, Brian Frederick; Begemann, Matthew Brett

2014-05-06T23:59:59.000Z

268

Catalytic transformations of cellulose and its derived carbohydrates into 5-hydroxymethylfurfural, levulinic acid, and lactic acid  

Science Journals Connector (OSTI)

The catalytic transformation of cellulose into key building-block or platform chemicals such as 5-hydoxymethylfurfural (HMF), levulinic acid, and lactic acid under mild conditions, has attracted much attention...

Weiping Deng; Qinghong Zhang; Ye Wang

2014-12-01T23:59:59.000Z

269

Yeast display evolution of a kinetically efficient 13-amino acid substrate for lipoic acid ligase  

E-Print Network (OSTI)

Escherichia coli lipoic acid ligase (LplA) catalyzes ATP-dependent covalent ligation of lipoic acid onto specific lysine side chains of three acceptor proteins involved in oxidative metabolism. Our lab has shown that LplA ...

Puthenveetil, Sujiet

270

2006 DOE Hydrogen Program Poly (p-phenylene Sulfonic Acid)s with...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

2006 DOE Hydrogen Program Poly (p-phenylene Sulfonic Acid)s with Frozen-in Free Volume for use in High Temperature Fuel Cells 2006 DOE Hydrogen Program Poly (p-phenylene Sulfonic...

271

The Arabidopsis hrl1 mutation reveals novel overlapping roles for salicylic acid, jasmonic acid and ethylene  

E-Print Network (OSTI)

and ethylene signalling in cell death and defence against pathogens Sendil K. Devadas1 , Alexander Enyedi2 molecules: salicylic acid (SA), jasmonic acid (JA) and ethylene (ET). The hrl1 (hypersensitive response

Raina, Ramesh

272

Superior catalysts for selective catalytic reduction of nitric oxide. Final technical report, October 1, 1993--September 30, 1995  

SciTech Connect

The most advanced and proven technology for NO{sub x} control for stationary sources is Selective Catalytic Reduction (SCR). In SCR, NO{sub x} is reduced by NH{sub 3} to N{sub 2} and H{sub 2}O. The commercial catalysts are based on V{sub 2}O{sub 5}/TiO{sub 2}, and the vanadium-based catalysts are patented by the Japanese (Mitsubishi). However, there are three main advantages for the vanadium-based SCR catalyst: (a) a tendency to be poisoned in the flue gas; (b) oxidation of SO{sub 2} to SO{sub 3} by V{sub 2}O{sub 5}, this is a particularly severe problem due to the higher sulfur content of American coals compared with coals used in Japan (from Australia) and in Europe; (c) environmental problems involved in the disposal of the spent catalyst (due to the toxicity of vanadium). In order to overcome these problems, in addition to the undesirable dominance by the Japanese patent position, the authors have studied in this project a new type of catalyst for the SCR reaction; namely, pillared clays, which have adjustable, unique structures and acidity. Three types of catalysts were developed and tested for this reaction, i.e. Fe{sub 2}O{sub 3}-pillared clays, delaminated Fe{sub 2}O{sub 3}-pillared clays, and ion-exchanged pillared clays. The project was divided into sixteen tasks, and will be reported as such.

Yang, R.T.; Li, W.B.; Chen, J.P.; Hausladen, M.C.; Cheng, L.S.; Kikkinides, E.S.

1995-12-31T23:59:59.000Z

273

Effect of dietary cysteine, methionine, and sterculic acid on fatty acid distribution in rat adipose tissue  

E-Print Network (OSTI)

EFFECT OF DIETARY CYSTEINE, MFTHIONINE, AND STERCULIC ACID ON FATTY ACID DISTRIBUTION IN RAT ADIPOSE TISSUE A Thesis By MARY FRANCES BROTZE Submitted to the Graduate College of the Texas A(M University in partial fulfillment... of the requirements for the degree of MASTER OF SCIENCE January 1968 Major Subject: BIOCHEMISTRY EFFECT OF DIETARY CYSTEINE, METHIONINE, AND STERCULIC ACID ON FATTY ACID DISTRIBUTION IN RAT ADIPOSE TISSUE A Thesis MAaY FRANCES BRC ~ '!E Approved as to style...

Brotze, Mary Frances

2012-06-07T23:59:59.000Z

274

Sub-Doppler Spectra of Infrared Hyperfine Transitions of Nitric Oxide Using a Pulse Modulated Quantum Cascade Laser: Rapid Passage, Free Induction Decay and the AC Stark Effect  

SciTech Connect

Using a low power, rapid (nsec) pulse-modulated quantum cascade (QC) laser, collective coherent effects in the 5 {micro}m spectrum of nitric oxide have been demonstrated by the observation of sub-Doppler hyperfine splitting and also Autler-Townes splitting of Doppler broadened lines. For nitrous oxide, experiments and model calculations have demonstrated that two main effects occur with ulsemodulated (chirped) quantum cascade lasers: free induction decay signals, and signals induced by rapid passage during the laser chirp. In the open shell molecule, NO, in which both {Lambda}-doubling splitting and hyperfine structure occur, laser field-induced coupling between the hyperfine levels of the two {Lambda}-doublet components can induce a large AC Stark effect. This may be observed as sub-Doppler structure, field-induced splittings, or Autler-Townes splitting of a Doppler broadened line. These represent an extension of the types of behaviour observed in the closed shell molecule nitrous oxide, using the same apparatus, when probed with an 8 {micro}m QC laser.

Duxbury, Geoffrey; Kelly, James F.; Blake, Thomas A.; Langford, Nigel

2012-05-07T23:59:59.000Z

275

Further Investigation of Fluoboric Acid in Sandstone Acidizing Using ^(11)B and ^(19)F NMR  

E-Print Network (OSTI)

Although fluoboric acid (HBF_(4)) has long been known as one of the low-damaging acid treatments for clayey sandstone formations, little is known of its chemistry which could explain the mixed results of fluoboric acid in actual field application. A...

Pituckchon, Arpajit

2014-05-01T23:59:59.000Z

276

Effect of defaunation and amino acid supplementation on growth and amino acid balance in growing sheep  

E-Print Network (OSTI)

, and the wool growth. The supplementation with protected amino acids may increase the growth rate and may lead and the addition of protected methionine and lysine on animal growth and amino acids digestibility in the body week for 9 weeks. Amino acids were determined in feed, blood, wool and feces in order to calculate

Paris-Sud XI, Université de

277

Nitrates and Prussic Acid in Forages  

E-Print Network (OSTI)

When nitrates and prussic acid accumulate in forage, the feed may not be safe for livestock consumption. Learn the symptoms of nitrate and prussic acid poisoning and which plants are most likely to pose a risk to livestock. Also learn sampling...

Provin, Tony; Pitt, John L.

2003-01-06T23:59:59.000Z

278

Naphthenic acid corrosion by Venezuelan crudes  

SciTech Connect

Venezuelan crudes can contain levels of naphthenic acids that cause corrosion in distillation units designed for sweet crudes. This naphthenic acid corrosion can be mitigated in several ways, the most common of which is selective alloying. This paper will provide information from field experience on how various refineries worldwide have upgraded materials to run Venezuelan crudes in a cost effective way.

Hopkinson, B.E.; Penuela, L.E. [Lagoven, S.A., Judibana (Venezuela). Amuay Refinery

1997-09-01T23:59:59.000Z

279

Naphthenic acid corrosion in crude distillation units  

SciTech Connect

This paper summarizes corrosion experience in crude distillation units processing highly naphthenic California crude oils. Correlations have been developed relating corrosion rates to temperature and total acid number. There is a threshold acid number in the range of 1.5 to 2 mg KOH/g below which corrosion is minimal. High concentrations of hydrogen sulfide may raise this threshold value.

Piehl, R.L.

1988-01-01T23:59:59.000Z

280

CX-003632: Categorical Exclusion Determination | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

3632: Categorical Exclusion Determination 3632: Categorical Exclusion Determination CX-003632: Categorical Exclusion Determination Analysis of Evaporator Scale Sample CX(s) Applied: B3.6 Date: 08/10/2010 Location(s): Aiken, South Carolina Office(s): Savannah River Operations Office We will perform an analysis of samples of scale removed from the Gravity Drain Line (GDL) and the pot of the 2H Evaporator. The analysis will support the development of a Nuclear Criticality Safety Analysis (NCSA) for evaporator operation and chemical cleaning. Previous chemical cleaning operations were performed using a nitric acid flow sheet that involved copious amounts of depleted uranyl nitrate used as a neutron poison. Current interest and focus is on a chemical cleaning operation involving only a sodium hydroxide solution. Therefore, testing will involve

Note: This page contains sample records for the topic "nitric acid cxs" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

CX-000801: Categorical Exclusion Determination | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

801: Categorical Exclusion Determination 801: Categorical Exclusion Determination CX-000801: Categorical Exclusion Determination Salt Disposition Integration Project Blend and Feed Tanks Testing CX(s) Applied: B3.6 Date: 01/05/2010 Location(s): Aiken, South Carolina Office(s): Environmental Management, Savannah River Operations Office 786-A personnel will conduct testing to recommend pump requirements for blending salt solution in the Salt Disposition Integration Project Blend and Feed Tanks. Testing will be conducted at a suitable scale, using a single pump with two opposing nozzles. The testing will consist of blending weak solutions of nitric acid (pH 4) and sodium hydroxide (pH 10) while monitoring pH in several locations of the tank. DOCUMENT(S) AVAILABLE FOR DOWNLOAD CX-000801.pdf More Documents & Publications

282

Page not found | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

21 - 3530 of 28,905 results. 21 - 3530 of 28,905 results. Download CX-010738: Categorical Exclusion Determination 2013 Spacer and Insulator Replacement Program; Third and Fourth Quarter Projects CX(s) Applied: B1.3 Date: 07/15/2013 Location(s): Washington, Washington, Washington Offices(s): Bonneville Power Administration http://energy.gov/nepa/downloads/cx-010738-categorical-exclusion-determination Download EIS-0285-SA-137: Supplement Analysis Transmission System Vegetation Management Program http://energy.gov/nepa/downloads/eis-0285-sa-137-supplement-analysis Download Preliminary Notice of Violation, Savannah River Nuclear Solutions, LLC- WEA-2010-05 Preliminary Notice of Violation issued to Savannah River Nuclear Solutions, LLC related to a Nitric Acid Spill Event and an Electrical Arc Flash Injury

283

Interaction of inflammatory and anti-inflammatory responses in microglia by Staphylococcus aureus-derived lipoteichoic acid  

SciTech Connect

We investigated the interaction between proinflammatory and inflammatory responses caused by Staphylococcus aureus-derived lipoteichoic acid (LTA) in primary cultured microglial cells and BV-2 microglia. LTA induced inducible nitric oxide synthase (iNOS) and cyclooxygenase-2 (COX-2) protein levels increase in a concentration- and time-dependent manner. Meanwhile, LTA also increased nitric oxide (NO) and PGE{sub 2} production in microglia. Administration of TLR2 antagonist effectively inhibited LTA-induced NO, iNOS, and COX-2 expression. Moreover, treatment of cells with LTA caused a time-dependent activation of ERK, p38, JNK, as well as AKT. We also found that LTA-induced iNOS and COX-2 up-regulation were attenuated by p38, JNK, and PI3-kinase inhibitors. On the other hand, LTA-enhanced HO-1 expression was attenuated by p38 and PI3-kinase inhibitors. Treatment of cells with NF-?B and AP-1 inhibitors antagonized LTA-induced iNOS and COX-2 expression. However, only NF-?B inhibitors reduced LTA-induced HO-1 expression in microglia. Furthermore, stimulation of cells with LTA also activated I?B? phosphorylation, p65 phosphorylation at Ser{sup 536}, and c-Jun phosphorylation. Moreover, LTA-induced increases of ?B-DNA and AP-1-DNA binding activity were inhibited by p38, JNK, and PI3-kinase inhibitors. HO-1 activator CoPP IX dramatically reversed LTA-induced iNOS expression. Our results provided mechanisms linking LTA and inflammation/anti-inflammation, and indicated that LTA plays a regulatory role in microglia activation. - Highlights: • LTA causes an increase in iNOS, COX-2, and HO-1 expression in microglia. • LTA induces iNOS and COX-2 expression through TLR-2/NF-?B and AP-1 pathways. • HO-1 expression is regulated through p38, JNK, PI3K/AKT and AP-1 pathways. • Induced HO-1 reduces LTA-induced iNOS expression. • LTA plays a regulatory role on inflammatory/anti-inflammatory responses.

Huang, Bor-Ren [Department of Neurosurgery, Buddhist Tzu Chi General Hospital, Taichung Branch, Taichung, Taiwan (China); Institute of Clinical Medical Science, China Medical University, Taichung, Taiwan (China); Tsai, Cheng-Fang [Department of Biotechnology, Asia University, Taichung, Taiwan (China); Lin, Hsiao-Yun [Department of Life Sciences, National Chung Hsing University, Taichung, Taiwan (China); Tseng, Wen-Pei [Graduate Institute of Sports and Health, National Changhua University of Education, Changhua County, Taiwan (China); Huang, Shiang-Suo [Department of Pharmacology and Institute of Medicine, College of Medicine, Chung Shan Medical University, Taiwan (China); Wu, Chi-Rei [Graduate Institute of Chinese Pharmaceutical Sciences, College of Pharmacy, China Medical University, Taiwan (China); Lin, Chingju [Department of Physiology, School of Medicine, China Medical University, Taichung, Taiwan (China); Yeh, Wei-Lan [Cancer Research Center, Department of Medical Research, Changhua Christian Hospital, Changhua, Taiwan (China); Lu, Dah-Yuu, E-mail: dahyuu@mail.cmu.edu.tw [Graduate Institute of Neural and Cognitive Sciences, China Medical University, Taichung, Taiwan (China)

2013-05-15T23:59:59.000Z

284

Experimental Study of Acid Fracture Conductivity of Austin Chalk Formation  

E-Print Network (OSTI)

Acid fracture conductivity and the effect of key variables in the etching process during acid fracturing can be assessed at the laboratory scale. This is accomplished by using an experimental apparatus that simulates acid injection fluxes comparable...

Nino Penaloza, Andrea

2013-05-01T23:59:59.000Z

285

Experimental High Velocity Acid Jetting in Limestone Carbonates  

E-Print Network (OSTI)

Acid jetting is a well stimulation technique that is used in carbonate reservoirs. It typically involves injecting acid down hole at high flow rates through small orifices which cause high velocities of acid to strike the borehole wall...

Holland, Christopher

2014-04-30T23:59:59.000Z

286

Investigations of amino acid-based surfactants at liquid interfaces  

E-Print Network (OSTI)

Herein are presented collective studies of amino acid-based surfactants, also known as lipoamino acids, at liquid interfaces. Chapter III describes an investigation of domain morphology of N-Stearoylglutamic acid (N-SGA) Langmuir monolayers...

Yang, Dengliang

2005-11-01T23:59:59.000Z

287

Naphthenic acid corrosion in refinery settings  

SciTech Connect

Naphthenic acid corrosion has been a problem in the refining industry for many years. Recently interest in this problem has grown because crudes that contain naphthenic acid are being recovered from areas which were not known to produce this type of crude, such as china, India, and Africa. New techniques for identifying naphthenic acid corrosion and chemical treatments for preventing this attack are presented. Refinery case studies include stream analysis, failure analysis, and inhibitor use. Laboratory tests to show the effect of hydrogen sulfide and phosphorus-based inhibitors are discussed.

Babaian-Kibala, E. (Nalco Chemical Co., Sugar Land, TX (United States)); Craig, H.L. Jr. (Mobil Research and Development Corp., Paulsboro, NJ (United States)); Rusk, G.L. (Mobil Oil Co., Torrance, CA (United States)); Blanchard, K.V.; Rose, T.J.; Uehlein, B.L. (Nalco Chemical Co., Paulsboro, NJ (United States)); Quinter, R.C. (Sun Co., Newtown Square, PA (United States)); Summers, M.A. (Sun Co., Marcus Hook, PA (United States))

1993-04-01T23:59:59.000Z

288

Experimental Investigation for the Effects of the Core Geometry on the Optimum Acid Flux in Carbonate Acidizing  

E-Print Network (OSTI)

Previous matrix acidizing experimental research showed that there exists an optimum acid interstitial velocity (Vi-opt) that results in the minimum volume of acid used while providing the best stimulation results. There are already several...

Jin, Xiao

2013-11-21T23:59:59.000Z

289

Aerobic Heterotrophic Bacteria Indigenous to pH 2.8 Acid Mine Water: Microscopic Examination of Acid Streamers  

Science Journals Connector (OSTI)

...streamers" found in acid coal mine drainage consist of bacteria...than one species. Acidic coal mine drainage is characterized...of 11 states that comprise Appalachia and includes numerous other coal mining areas ofthe world. The acidic...

Patrick R. Dugan; Carol B. MacMillan; Robert M. Pfister

1970-03-01T23:59:59.000Z

290

Studying Cellulose Fiber Structure by SEM, XRD, NMR and Acid...  

NLE Websites -- All DOE Office Websites (Extended Search)

Studying Cellulose Fiber Structure by SEM, XRD, NMR and Acid Hydrolysis. Abstract: Cotton linters were partially hydrolyzed in dilute acid and the morphology of remaining...

291

adenylic acid: Topics by E-print Network  

NLE Websites -- All DOE Office Websites (Extended Search)

preservation A Rauramaa A Tommila J Ltd, Espoo Reseach Centre, PO Box 44, 02271 Espoo, Finland Formic acid is known to improve silage hygienic quality. Formic acid based...

292

acid rain program: Topics by E-print Network  

NLE Websites -- All DOE Office Websites (Extended Search)

preservation A Rauramaa A Tommila J Ltd, Espoo Reseach Centre, PO Box 44, 02271 Espoo, Finland Formic acid is known to improve silage hygienic quality. Formic acid based...

293

Formation of iron complexs from trifluoroacetic acid based liquid...  

NLE Websites -- All DOE Office Websites (Extended Search)

of iron complexs from trifluoroacetic acid based liquid chromatography mobile phases as interference ions in liquid Formation of iron complexs from trifluoroacetic acid based...

294

Copper isotope fractionation in acid mine drainage. | EMSL  

NLE Websites -- All DOE Office Websites (Extended Search)

Copper isotope fractionation in acid mine drainage. Copper isotope fractionation in acid mine drainage. Abstract: We surveyed the Cu isotopic composition of primary minerals and...

295

Hydrogen-bond acidic functionalized carbon nanotubes (CNTs) with...  

NLE Websites -- All DOE Office Websites (Extended Search)

Hydrogen-bond acidic functionalized carbon nanotubes (CNTs) with covalently-bound hexafluoroisopropanol groups. Hydrogen-bond acidic functionalized carbon nanotubes (CNTs) with...

296

AVTA: 2010 Honda Civic HEV with Experimental Ultra Lead Acid...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

2010 Honda Civic HEV with Experimental Ultra Lead Acid Battery Testing Results AVTA: 2010 Honda Civic HEV with Experimental Ultra Lead Acid Battery Testing Results The Vehicle...

297

Effects of Continuous Triiodothyronine Infusion on Citric Acid...  

NLE Websites -- All DOE Office Websites (Extended Search)

Continuous Triiodothyronine Infusion on Citric Acid Cycle in the Normal Immature Swine Heart under Extracorporeal Effects of Continuous Triiodothyronine Infusion on Citric Acid...

298

Acid Initiation of Ammonia-Borane Dehydrogenation for Hydrogen...  

NLE Websites -- All DOE Office Websites (Extended Search)

Acid Initiation of Ammonia-Borane Dehydrogenation for Hydrogen Storage. Acid Initiation of Ammonia-Borane Dehydrogenation for Hydrogen Storage. Abstract: An abstract for this...

299

Fraud in the acid rain debate  

SciTech Connect

Electric utility executives, according to the author, and millions of other Americans are the victims of a gigantic fraud being carried on in the name of controlling acid rain. This fraud, states the author, involves the distorted, dire image of acidity in nature being created by environmental groups, politicians and others - to gain public sympathy for their legislative goals. The alleged fraud involves the very nature of the legislation being promoted as a low-cost cure for acid rain. On the basis of scientific evidence to date there is no assurance it will reduce acidity by any appreciable amount, but on the other hand it most certainly will cost users of electricity hundreds of billions of dollars in new costs. What has already happened to the nuclear industry is also meant for coal.

Bagge, C.

1984-06-01T23:59:59.000Z

300

Ascorbic Acid and Cancer: A Review  

Science Journals Connector (OSTI)

...groups, together with the formation of hydrogen bonds, offer a probable explanation...and Landeau, B. R. Ascorbic acid economy in surgical patients. Ann. N. Y...Culver, P. L. Horseradish peroxidase/ hydrogen peroxide-catalyzed oxidation of the...

Ewan Cameron; Linus Pauling; and Brian Leibovitz

1979-03-01T23:59:59.000Z

Note: This page contains sample records for the topic "nitric acid cxs" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Lactic acid fermentation of crude sorghum extract  

SciTech Connect

Crude extract from sweet sorghum supplemented with vetch juice was utilized as the carbohydrate source for fermentative production of lactic acid. Fermentation of media containing 7% (w/v) total sugar was completed in 60-80 hours by Lactobacillus plantarum, product yield averaging 85%. Maximum acid production rates were dependent on pH, initial substrate distribution, and concentration, the rates varying from 2 to 5 g/liter per hour. Under limited medium supplementation the lactic acid yield was lowered to 67%. The fermented ammoniated product contained over eight times as much equivalent crude protein (N x 6.25) as the original medium. Unstructured kinetic models were developed for cell growth, lactic acid formation, and substrate consumption in batch fermentation. With the provision of experimentally determined kinetic parameters, the proposed models accurately described the fermentation process. 15 references.

Samuel, W.A.; Lee, Y.Y.; Anthony, W.B.

1980-04-01T23:59:59.000Z

302

A Direct, Biomass-Based Synthesis of Benzoic Acid: Formic Acid-Mediated Deoxygenation of the Glucose-Derived Materials Quinic Acid and Shikimic Acid  

E-Print Network (OSTI)

R.G.B and J.A.E. ). Keywords: biomass · carboxylic acids ·10.1002/cssc.201000111 A Direct, Biomass-Based Synthesis ofaro- matic compounds from biomass resources could provide a

2010-01-01T23:59:59.000Z

303

Heterogeneous Reactions of Epoxides in Acidic Media  

E-Print Network (OSTI)

on sulfuric acid using Ion drift-Chemical Ionization Mass Spectrometry (ID-CIMS) showed an irreversible uptake of epoxides at room temperature resulting in the formation of less volatile products like diols, organosulfates and acetals. However, at lower...

Lal, Vinita

2012-02-14T23:59:59.000Z

304

Ascorbic Acid and Cancer: A Review  

Science Journals Connector (OSTI)

...skinned individuals resident in areas of high solar intensity, such as the southern United States, South Africa, and Australia. Experimentally, the...Effects of Ascorbic Acid Ascorbate and Energy Production. Cytochromes P-450 and b5are...

Ewan Cameron; Linus Pauling; and Brian Leibovitz

1979-03-01T23:59:59.000Z

305

PREDICTING TEMPERATURE BEHAVIOR IN CARBONATE ACIDIZING TREATMENTS  

E-Print Network (OSTI)

PREDICTING TEMPERATURE BEHAVIOR IN CARBONATE ACIDIZING TREATMENTS A Thesis by XUEHAO TAN Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree... of MASTER OF SCIENCE May 2009 Major Subject: Petroleum Engineering PREDICTING TEMPERATURE BEHAVIOR IN CARBONATE ACIDIZING TREATMENTS A Thesis by XUEHAO TAN Submitted to the Office of Graduate Studies of Texas A&M University...

Tan, Xuehao

2010-01-16T23:59:59.000Z

306

Primer on lead-acid storage batteries  

SciTech Connect

This handbook was developed to help DOE facility contractors prevent accidents caused during operation and maintenance of lead-acid storage batteries. Major types of lead-acid storage batteries are discussed as well as their operation, application, selection, maintenance, and disposal (storage, transportation, as well). Safety hazards and precautions are discussed in the section on battery maintenance. References to industry standards are included for selection, maintenance, and disposal.

NONE

1995-09-01T23:59:59.000Z

307

Amplification of trace amounts of nucleic acids  

DOE Patents (OSTI)

Methods of reducing background during amplification of small amounts of nucleic acids employ careful analysis of sources of low level contamination. Ultraviolet light can be used to reduce nucleic acid contaminants in reagents and equipment. "Primer-dimer" background can be reduced by judicious design of primers. We have shown clean signal-to-noise with as little as starting material as one single human cell (.about.6 picogram), E. coli cell (.about.5 femtogram) or Prochlorococcus cell (.about.3 femtogram).

Church, George M. (Brookline, MA); Zhang, Kun (Brighton, MA)

2008-06-17T23:59:59.000Z

308

Biologically produced acid precipitable polymeric lignin  

DOE Patents (OSTI)

A water soluble, acid precipitable polymeric degraded lignin (APPL), having a molecular weight of at least 12,000 daltons, and comprising, by percentage of total weight, at least three times the number of phenolic hydroxyl groups and carboxylic acid groups present in native lignin. The APPL may be modified by chemical oxidation and reduction to increase its phenolic hydroxyl content and reduce the number of its antioxidant inhibitory side chains, thereby improving antioxidant properties.

Crawford, Don L. (Moscow, ID); Pometto, III, Anthony L. (Moscow, ID)

1984-01-01T23:59:59.000Z

309

Catalytic oxidative conversion of cellulosic biomass to formic acid and acetic acid with exceptionally high yields  

Science Journals Connector (OSTI)

Abstract Direct conversion of raw biomass materials to fine chemicals is of great significance from both economic and ecological perspectives. In this paper, we report that a Keggin-type vanadium-substituted phosphomolybdic acid catalyst, namely H4PVMo11O40, is capable of converting various biomass-derived substrates to formic acid and acetic acid with high selectivity in a water medium and oxygen atmosphere. Under optimized reaction conditions, \\{H4PVMo11O40\\} gave an exceptionally high yield of formic acid (67.8%) from cellulose, far exceeding the values achieved in previous catalytic systems. Our study demonstrates that heteropoly acids are generally effective catalysts for biomass conversion due to their strong acidities, whereas the composition of metal addenda atoms in the catalysts has crucial influence on the reaction pathway and the product selectivity.

Jizhe Zhang; Miao Sun; Xin Liu; Yu Han

2014-01-01T23:59:59.000Z

310

The Transuranium Elements  

E-Print Network (OSTI)

TBP diluted with a kerosene type solvent is used. The uranium slugs are dissolved in nitric acid,nitric acid solution containing a reducing is agent. LJranium(~1) left in the TBP

Hyde, Earl K.; Seaborg, Glenn T.

1956-01-01T23:59:59.000Z

311

The inability of rats to synthesize linoleic acid from cis-2-octenoic acid  

E-Print Network (OSTI)

THE INABILITY OF RATS TO SYNTHESI2E LINOLEIC ACID FROM CIS-2-OCTENOIC ACID A Thesis Robert Eugene Anderson Submitted to the Graduate College of the Texas A g: M University in partia1 fulfillment of the requirerents for the degree of MASTER... OF SCIENCE January 1965 Major Subjeot: Bioohemistry THE INABILITY OF RATS TQ SYNTHESIEE LINOLEIC ACID FROM CIS-2E)CTENOIC ACID A Thesis Robert, Eugene Anderson Approved as to style and content by: Chair n of Committee)~ (Head of Depart~ant, Member...

Anderson, Robert Eugene

2012-06-07T23:59:59.000Z

312

E-Print Network 3.0 - acids amino acids Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

State University Collection: Biology and Medicine 77 CHE 427627 THE ORGANIC CHEMISTRY OF BIOLOGICAL MOLECULES Summary: macromolecules: carbohydrates, amino acids, nucleic...

313

E-Print Network 3.0 - acid amino acid Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

State University Collection: Biology and Medicine 77 CHE 427627 THE ORGANIC CHEMISTRY OF BIOLOGICAL MOLECULES Summary: macromolecules: carbohydrates, amino acids, nucleic...

314

E-Print Network 3.0 - acid docosahexaenoic acid Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

SAGE-Hindawi Access to Research International Journal of Alzheimer's Disease Summary: APP secretion 19. 2.2. Fatty Acids on Membrane Physical Properties and APP Processing. Fatty...

315

E-Print Network 3.0 - acid-amino acid conjugates Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

amino acids is reported with the incorporation of one example into a ... Source: Beal, Peter A. - Department of Chemistry, University of Utah Collection: Chemistry 13 An...

316

N e w E n g l a n d W a t e r T r e a t m e n t Technology Assistance Center  

E-Print Network (OSTI)

), then acidified with 2 drops of concentrated nitric acid and stored in a refrigerator. The arsenic concentration

317

Correlation between Fibroin Amino Acid Sequence and Physical Silk Properties*  

E-Print Network (OSTI)

moth (Ephe- stia kuehniella), and Indian meal moth (Plodia inter- punctella). The amino acid repeats

Â?urovec, Michal

318

Transcription factor-based biosensors for detecting dicarboxylic acids  

DOE Patents (OSTI)

The invention provides methods and compositions for detecting dicarboxylic acids using a transcription factor biosensor.

Dietrich, Jeffrey; Keasling, Jay

2014-02-18T23:59:59.000Z

319

Purification Or Organic Acids Using Anion Exchange Chromatography.  

DOE Patents (OSTI)

Disclosed is a cost-effective method for purifying and acidifying carboxylic acids, including organic acids and amino acids. The method involves removing impurities by allowing the anionic form of the carboxylic acid to bind to an anion exchange column and washing the column. The carboxylic anion is displaced as carboxylic acid by washing the resin with a strong inorganic anion. This method is effective in removing organic carboxylic acids and amino acids from a variety of industrial sources, including fermentation broths, hydrolysates, and waste streams.

Ponnampalam; Elankovan (Okemos, MI)

2001-09-04T23:59:59.000Z

320

Synergy of Lewis and Brønsted Acids on Catalytic Hydrothermal Decomposition of Hexose to Levulinic Acid  

Science Journals Connector (OSTI)

Levulinic acid (LA), an important platform chemical, is regarded as one of top 12 block chemicals. ... Phosphate standard concentrate (85%), glucose (99%), and levulinic acid (99%) were purchased from Aladdin Chemistry Co., Ltd. ... Fructose, chromium(III) chloride hexahydrate, and 5-HMF (purities of these chemicals ? 98%) were purchased from J&K Chemica, Ltd. ...

Fan Yang; Jie Fu; Jing Mo; Xiuyang Lu

2013-10-15T23:59:59.000Z

Note: This page contains sample records for the topic "nitric acid cxs" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Acid Diversion in Carbonate Reservoirs Using Polymer-Based In-Situ Gelled Acids  

E-Print Network (OSTI)

Diversion in carbonates is more difficult than in sandstones because of the ability of acid to significantly increase the permeability in carbonates as it reacts in the pore spaces and flow channels of matrix. In-situ gelled acids that are based...

Gomaa, Ahmed Mohamed Mohamed

2012-07-16T23:59:59.000Z

322

Nucleic Acid Standards - Standard Ref. Frame  

NLE Websites -- All DOE Office Websites (Extended Search)

Standard Reference Standard Reference Standard Reference Frame Supplemental Information Ideal Geometries X-PLOR Parameters Valence Geometries RNA Ontology Consortium mmCIF Resources PDBML Resources A Standard Reference Frame for the Description of Nucleic Acid Base-pair Geometry A common point of reference is needed to describe the three-dimensional arrangements of bases and base pairs in nucleic acid structures. [1]. For example, parts of a structure, which appear "normal" according to one computational scheme, may be highly unusual according to another and vice versa. It is thus difficult to carry out comprehensive comparisons of nucleic acid structures and to pinpoint unique conformational features in individual structures. In order to resolve these issues, a group of

323

Water and UV degradable lactic acid polymers  

DOE Patents (OSTI)

A water and UV light degradable copolymer of monomers of lactic acid and a modifying monomer were selected from the class consisting of ethylene and polyethylene glycols, propylene and polypropylene glycols, P-dioxanone, 1,5 dioxepan-2-one, 1,4 -oxathialan-2-one, 1,4-dioxide and mixtures. These copolymers are useful for waste disposal and agricultural purposes. Also disclosed is a water degradable blend of polylactic acid or modified polylactic acid and high molecular weight polyethylene oxide where the high molecular weight polyethylene oxide is present in the range of from about 2% by weight to about 50% by weight, suitable for films. A method of applying an active material selected from the class of seeds, seedlings, pesticides, herbicides, fertilizers and mixtures to an agricultural site is also disclosed.

Bonsignore, P.V.; Coleman, R.D.

1994-11-01T23:59:59.000Z

324

Water and UV degradable lactic acid polymers  

DOE Patents (OSTI)

A water and UV light degradable copolymer of monomers of lactic acid and a modifying monomer selected from the class consisting of ethylene and polyethylene glycols, propylene and polypropylene glycols, P-dioxanone, 1,5 dioxepan-2-one, 1,4 -oxathialan-2-one, 1,4-dioxide and mixtures thereof. These copolymers are useful for waste disposal and agricultural purposes. Also disclosed is a water degradable blend of polylactic acid or modified polylactic acid and high molecular weight polyethylene oxide wherein the high molecular weight polyethylene oxide is present in the range of from about 2% by weight to about 50% by weight, suitable for films. A method of applying an active material selected from the class of seeds, seedlings, pesticides, herbicides, fertilizers and mixtures thereof to an agricultural site is also disclosed.

Bonsignore, Patrick V. (Joliet, IL); Coleman, Robert D. (Wheaton, IL)

1994-01-01T23:59:59.000Z

325

Water and UV degradable lactic acid polymers  

DOE Patents (OSTI)

A water and UV light degradable copolymer is described made from monomers of lactic acid and a modifying monomer selected from the class consisting of ethylene glycol, propylene glycol, P-dioxanone, 1,5 dioxepan-2-one, 1,4-oxathialan-2-one, 1,4-dioxide and mixtures thereof. These copolymers are useful for waste disposal and agricultural purposes. Also disclosed is a water degradable blend of polylactic acid or modified polylactic acid and high molecular weight polyethylene oxide wherein the high molecular weight polyethylene oxide is present in the range of from about 2 by weight to about 50% by weight, suitable for films. A method of applying an active material selected from the class of seeds, seedlings, pesticides, herbicides, fertilizers and mixtures thereof to an agricultural site is also disclosed.

Bonsignore, P.V.; Coleman, R.D.

1996-10-08T23:59:59.000Z

326

Water and UV degradable lactic acid polymers  

DOE Patents (OSTI)

A water and UV light degradable copolymer of monomers of lactic acid and a modifying monomer selected from the class consisting of ethylene glycol, propylene glycol, P-dioxanone, 1,5 dioxepan-2-one, 1,4-oxathialan-2-one, 1,4-dioxide and mixtures thereof. These copolymers are useful for waste disposal and agricultural purposes. Also disclosed is a water degradable blend of polylactic acid or modified polylactic acid and high molecular weight polyethylene oxide wherein the high molecular weight polyethylene oxide is present in the range of from about 2 by weight to about 50% by weight, suitable for films. A method of applying an active material selected from the class of seeds, seedlings, pesticides, herbicides, fertilizers and mixtures thereof to an agricultural site is also disclosed.

Bonsignore, Patrick V. (Joliet, IL); Coleman, Robert D. (Wheaton, IL)

1996-01-01T23:59:59.000Z

327

Photoenhanced anaerobic digestion of organic acids  

DOE Patents (OSTI)

A process is described for rapid conversion of organic acids and alcohols anaerobic digesters into hydrogen and carbon dioxide, the optimal precursor substrates for production of methane. The process includes addition of photosynthetic bacteria to the digester and exposure of the bacteria to radiant energy (e.g., solar energy). The process also increases the pH stability of the digester to prevent failure of the digester. Preferred substrates for photosynthetic bacteria are the organic acid and alcohol waste products of fermentative bacteria. In mixed culture with methanogenic bacteria or in defined co-culture with non-aceticlastic methanogenic bacteria, photosynthetic bacteria are capable of facilitating the conversion or organic acids and alcohols into methane with low levels of light energy input.

Weaver, Paul F. (Golden, CO)

1990-01-01T23:59:59.000Z

328

E-Print Network 3.0 - acid analysis including Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

predict the relative acid strength of a set... section. Findings Our analysis led to the identification of four distinct mental models of acid and acid... models of acid and acid...

329

Relative reactivities of solid benzoic acids  

E-Print Network (OSTI)

was always the acid salt, (RBZA) HK. For the reaction, RBZAH + Z R'BZAK, where R g R', the products were those predicted from Hammett o-constants for R and R'. Observations on the mode of reaction and free energy changes are given. The desirability... reaction series chosen was that. one most directly related to the Hammett substituent constants; namely, the reactions of various m- or p- monosubstituted benzoic acids with m- or p-monosubstituted potas- sium benzoate salts. CHAPTER Il RES ULTS...

Warwas, Edwin James

2012-06-07T23:59:59.000Z

330

Acid mine water aeration and treatment system  

DOE Patents (OSTI)

An in-line system is provided for treating acid mine drainage which basically comprises the combination of a jet pump (or pumps) and a static mixer. The jet pump entrains air into the acid waste water using a Venturi effect so as to provide aeration of the waste water while further aeration is provided by the helical vanes of the static mixer. A neutralizing agent is injected into the suction chamber of the jet pump and the static mixer is formed by plural sections offset by 90 degrees.

Ackman, Terry E. (Finleyville, PA); Place, John M. (Bethel Park, PA)

1987-01-01T23:59:59.000Z

331

Effect of Conjugated Linoleic Acid or Oleic Acid Addition on Fatty Acid Composition Profiles of Poultry Meat  

E-Print Network (OSTI)

on the omega-6 fatty acid accumulation in broiler chicken breast and thigh meat. Eight broilers from each treatment were processed at 4 and 6 weeks of age, respectively. Regarding the diets containing five different fat sources, broiler chickens fed CLA...

Shin, Dae Keun

2011-08-08T23:59:59.000Z

332

A method to attenuate U(VI) mobility in acidic waste plumes using humic acids  

SciTech Connect

Acidic uranium (U) contaminated plumes have resulted from acid-extraction of plutonium during the Cold War and from U mining and milling operations. A sustainable method for in-situ immobilization of U under acidic conditions is not yet available. Here, we propose to use humic acids (HAs) for in-situ U immobilization in acidic waste plumes. Our laboratory batch experiments show that HA can adsorb onto aquifer sediments rapidly, strongly and practically irreversibly. Adding HA greatly enhanced U adsorption capacity to sediments at pH below 5.0. Our column experiments using historically contaminated sediments from the Savannah River Site under slow flow rates (120 and 12 m/y) show that desorption of U and HA were non-detectable over 100 pore-volumes of leaching with simulated acidic groundwaters. Upon HA-treatment, 99% of the contaminant [U] was immobilized at pH < 4.5, compared to 5% and 58% immobilized in the control columns at pH 3.5 and 4.5, respectively. These results demonstrated that HA-treatment is a promising in-situ remediation method for acidic U waste plumes. As a remediation reagent, HAs are resistant to biodegradation, cost effective, nontoxic, and easily introducible to the subsurface.

Wan, J.; Dong, W.; Tokunaga, T.K.

2011-02-01T23:59:59.000Z

333

Preparation of Some Substituted Terephthalic Acids  

E-Print Network (OSTI)

, with the dilithiation of 2,5-dibromotoluene with t-BuLi at ­78 8C, followed by reaction with dry ice and subsequent acid (3) is esterified,[9] then side-chain brominated with NBS, to produce dimethyl 2

Benin, Vladimir

334

Acid dyes removal using low cost adsorbents  

Science Journals Connector (OSTI)

Dyestuff production units and dyeing units have always had pressing need techniques that allow economical pre-treatment for colour in the effluent. The effectiveness of adsorption for dye removal from wastewaters has made it an ideal alternative to other expensive treatment options. Removal of acid green

A.H. Aydin; Y. Bulut; O. Yavuz

2004-01-01T23:59:59.000Z

335

Heterogeneous organic acid uptake on soot surfaces  

E-Print Network (OSTI)

observed the interaction between a number of carboxylic acids and soot from different fuel sources and formation mechanisms. A low pressure fast flow reactor was used to control the contact between the solid phase soot and gas phase organics, while chemical...

Levitt, Nicholas Paul

2009-05-15T23:59:59.000Z

336

Peer review plan muddies acid rain talks  

Science Journals Connector (OSTI)

Bilateral U.S./Canadian talks on an acid rain treaty are being buffeted by bitter winds of national politics and uncertain science. The latest ill wind to blow north, as far as the Canadians are concerned, is the U.S. plan to have peer reviewed all ...

1982-05-10T23:59:59.000Z

337

MFR PAPER 1339 Phosphonoacetic Acid Inhibition of  

E-Print Network (OSTI)

phosphonoace- tic acid (PAA), functions specifically by inhibiting the herpesvirus coded DNA dependent DNA polymerase in its process of replicating virus DNA (Mao and Robishaw, [975). In tissue culture systems, PAA and Overby, 1975). In all cases, the effec- tive tissue culture dose of PAA which inhibited herpesvirus

338

Corrosion free phosphoric acid fuel cell  

DOE Patents (OSTI)

A phosphoric acid fuel cell with an electrolyte fuel system which supplies electrolyte via a wick disposed adjacent a cathode to an absorbent matrix which transports the electrolyte to portions of the cathode and an anode which overlaps the cathode on all sides to prevent corrosion within the cell.

Wright, Maynard K. (Bethel Park, PA)

1990-01-01T23:59:59.000Z

339

Detection of nucleic acid sequences by invader-directed cleavage  

DOE Patents (OSTI)

The present invention relates to means for the detection and characterization of nucleic acid sequences, as well as variations in nucleic acid sequences. The present invention also relates to methods for forming a nucleic acid cleavage structure on a target sequence and cleaving the nucleic acid cleavage structure in a site-specific manner. The 5' nuclease activity of a variety of enzymes is used to cleave the target-dependent cleavage structure, thereby indicating the presence of specific nucleic acid sequences or specific variations thereof. The present invention further relates to methods and devices for the separation of nucleic acid molecules based by charge.

Brow, Mary Ann D. (Madison, WI); Hall, Jeff Steven Grotelueschen (Madison, WI); Lyamichev, Victor (Madison, WI); Olive, David Michael (Madison, WI); Prudent, James Robert (Madison, WI)

1999-01-01T23:59:59.000Z

340

Producing a trimethylpentanoic acid using hybrid polyketide synthases  

DOE Patents (OSTI)

The present invention provides for a polyketide synthase (PKS) capable of synthesizing trimethylpentanoic acid. The present invention also provides for a host cell comprising the PKS and when cultured produces the trimethylpentanoic acid. The present invention also provides for a method of producing the trimethylpentanoic acid, comprising: providing a host cell of the present invention, and culturing said host cell in a suitable culture medium such that the trimethylpentanoic acid is produced, optionally isolating the trimethylpentanoic acid, and optionally, reducing the isolated trimethylpentanoic acid into a trimethylpentanol or an iso-octane.

Katz, Leonard; Fortman, Jeffrey L; Keasling, Jay D

2014-10-07T23:59:59.000Z

Note: This page contains sample records for the topic "nitric acid cxs" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Investigating the Effect of Oil Saturation on Acid Propagation during Matrix Acidization of Carbonate Rocks  

E-Print Network (OSTI)

The existence of an optimum injection rate for wormhole propagation, and face dissolution at low injection rates during matrix acidizing are well established. However, little has been documented that describes how the presence of residual oil...

Kumar, Rahul Pradeep

2014-01-02T23:59:59.000Z

342

Effects of Acid Additives on Spent Acid Flowback through Carbonate Cores  

E-Print Network (OSTI)

Matrix acidizing is a well stimulation technique used to remove formation damage in the near wellbore region. But it comes with an associated set of challenges such as corrosion of the tubulars and iron precipitation in the formation. To counter...

Nasir, Ehsaan Ahmad

2012-07-16T23:59:59.000Z

343

Modeling Acid Transport and Non-Uniform Etching in a Stochastic Domain in Acid Fracturing  

E-Print Network (OSTI)

Success of acid fracturing depends on uneven etching along the fracture surfaces caused by heterogeneities such as variations in local mineralogy and variations in leakoff behavior. The heterogeneities tend to create channeling characteristics...

Mou, Jianye

2010-10-12T23:59:59.000Z

344

A study of the distribution of fatty acids in the system: cottonseed oil-oleic acid-isopropanol-water  

E-Print Network (OSTI)

A STDDY OF THI' DISTBIRliTION OF FATTY ACIDS IN THE SYSTEM: COTTONSFED OIL - OLEIC ACID - ISOPBOPANOL - YlATEB A Thesis Frank E. Lomb January 1948 Approval as to style and content recommended: Head ' t Te epartm nt of hem cal Engineer ng A... STUDY OF THE DISTHIBUTION OF FATTY ACIDS IN THE SYSTEM: COTTONSEED OIL - OLEIC ACID - ISOFHOPANOL - WATER A Thesis By Frank E. Lamb January 1948 A STUDY QF TNE DISTRIBUTION OF FATTY ACIDS IN TRE SYSTEM: COTTONSEED OII, - OIEIC ACID - ISOPROPANOL...

Lamb, Frank E

2012-06-07T23:59:59.000Z

345

A First Look at Yeast Fatty Acid Synthase  

NLE Websites -- All DOE Office Websites (Extended Search)

A First Look at Yeast Fatty Acid Synthase Print A First Look at Yeast Fatty Acid Synthase Print Fatty acids are the major constituents of eukaryotic and bacterial cellular membranes. They are used for functionally important post-translational protein modifications, and chains of fatty acids are the main storage compartments of an organism's chemical energy. Fatty acid synthesis is carried out by fatty acid sythase (FAS), which catalyzes cycles of multistep chemical reactions that are essentially the same in all organisms. FAS uses one acetyl-coenzyme A (CoA) and seven malonyl-CoA molecules to synthesize the 16-carbon palmitic acid, the most abundant fatty acid in eukaryotes. Now, for the first time, a group of researchers has determined the atomic structure of yeast Saccharomyces cerevisiae FAS derived from two crystals of the enzyme, using data collected at ALS Beamlines 8.2.1 and 8.2.2, as well as other synchrotron facilities.

346

Acid-catalyzed dehydrogenation of amine-boranes  

NLE Websites -- All DOE Office Websites (Extended Search)

Acid-catalyzed dehydrogenation of amine-boranes Acid-catalyzed dehydrogenation of amine-boranes Acid-catalyzed dehydrogenation of amine-boranes A method of dehydrogenating an amine-borane using an acid-catalyzed reaction. June 25, 2013 Acid-catalyzed dehydrogenation of amine-boranes A method of dehydrogenating an amine-borane using an acid-catalyzed reaction. Available for thumbnail of Feynman Center (505) 665-9090 Email Acid-catalyzed dehydrogenation of amine-boranes A method of dehydrogenating an amine-borane using an acid-catalyzed reaction. The method generates hydrogen and produces a solid polymeric product. The method of dehydrogenating amine-boranes may be used to generate hydrogen for power generation sources such as fuel cells. U.S. Patent No.: 7,645,902 (DOE S-104,909) Patent Application Filing Date: June 22, 2006

347

A First Look at Yeast Fatty Acid Synthase  

NLE Websites -- All DOE Office Websites (Extended Search)

A First Look at Yeast Fatty Acid Synthase Print A First Look at Yeast Fatty Acid Synthase Print Fatty acids are the major constituents of eukaryotic and bacterial cellular membranes. They are used for functionally important post-translational protein modifications, and chains of fatty acids are the main storage compartments of an organism's chemical energy. Fatty acid synthesis is carried out by fatty acid sythase (FAS), which catalyzes cycles of multistep chemical reactions that are essentially the same in all organisms. FAS uses one acetyl-coenzyme A (CoA) and seven malonyl-CoA molecules to synthesize the 16-carbon palmitic acid, the most abundant fatty acid in eukaryotes. Now, for the first time, a group of researchers has determined the atomic structure of yeast Saccharomyces cerevisiae FAS derived from two crystals of the enzyme, using data collected at ALS Beamlines 8.2.1 and 8.2.2, as well as other synchrotron facilities.

348

Mid-ultraviolet Light-Emitting Diode Detects Dipicolinic Acid  

Science Journals Connector (OSTI)

Dipicolinic acid (DPA, 2,6-pyridinedicarboxylic acid) is a substance uniquely present in bacterial spores such as that from anthrax (B. anthracis). It is known that DPA can be...

Li, Qingyang; Dasgupta, Purnendu K; Temkin, Henryk; Crawford, M H; Fischer, A J; Allerman, A A; Bogart, K H A; Lee, S R

2004-01-01T23:59:59.000Z

349

TRL Acid and Solvent Wet Processing Rules and Guidelines  

E-Print Network (OSTI)

: General rules and guidelines for wet chemical processing in TRL. Author: KFlo hood and when transporting or handling chemicals. An acid-proof apron, sleeveTRL Acid and Solvent Wet Processing Rules and Guidelines Purpose

Reif, Rafael

350

Development and testing of an advanced acid fracture conductivity apparatus  

E-Print Network (OSTI)

wells. Acid fracturing is a standard practice to increase the production rate and to improve ultimate recovery in carbonate reservoirs. There have been successful cases in most carbonate reservoirs around the world. However acid fracture performance...

Zou, ChunLei

2006-08-16T23:59:59.000Z

351

Choline for neutralizing naphthenic acid in fuel and lubricating oils  

SciTech Connect

A method is described of neutralizing at least a portion of the naphthenic acids present in fuel and lubricating oils which contain naphthenic acids which comprises treating these oils with a neutralizing amount of choline.

Ries, D.G.; Roof, G.L.

1986-07-15T23:59:59.000Z

352

Identification of petroleum acids in Liaohe super-heavy oil  

Science Journals Connector (OSTI)

In this study, petroleum acids were extracted from the super-heavy oil of Liaohe oilfield, North-east China, by using acetic acid, and their structural components and properties were investigated by using FT-I...

Bencheng Wu; Jianhua Zhu

2009-12-01T23:59:59.000Z

353

Integrated 3D Acid Fracturing Model for Carbonate Reservoir Stimulation  

E-Print Network (OSTI)

in integrating fracture propagation, acid transport and dissolution, and well performance models in a seamless fashion for acid fracturing design. In this new approach, the fracture geometry data of a hydraulic fracture is first obtained from commercial models...

Wu, Xi

2014-06-23T23:59:59.000Z

354

High Temperature Fuel Cell (Phosphoric Acid) Manufacturing R...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Fuel Cell (Phosphoric Acid) Manufacturing R&D High Temperature Fuel Cell (Phosphoric Acid) Manufacturing R&D Presented at the NREL Hydrogen and Fuel Cell Manufacturing R&D Workshop...

355

Nucleic acid based fluorescent sensor for copper detection  

DOE Patents (OSTI)

A nucleic acid enzyme responsive to copper, comprising an oligonucleotide comprising a nucleotide sequence of SEQ ID NO:1, wherein the nucleic acid enzyme is not self-cleaving.

Lu, Yi; Liu, Juewen

2013-04-02T23:59:59.000Z

356

Conversion of carboxylate salts to carboxylic acids via reactive distillation.  

E-Print Network (OSTI)

??The purpose of this study is to convert carboxylate salts (e.g. calcium acetate, propionate, and butyrate) into carboxylic acids (e.g., acetic, propionic, and butyric acids).… (more)

Williamson, Shelly Ann

2012-01-01T23:59:59.000Z

357

Influence of boric acid additive size on green lubricant performance  

Science Journals Connector (OSTI)

...towards green manufacturing processes, there...boric acid powder additives with canola oil...change present manufacturing process lines...powder-based lubricant additives As conceptually...of boric acid additive size on green...towards green manufacturing processes, there...

2010-01-01T23:59:59.000Z

358

The Effect of Heterogeneity on Matrix Acidizing of Carbonate Rocks  

E-Print Network (OSTI)

In matrix acidizing, the goal is to dissolve minerals in the rock to increase well productivity. This is accomplished by injecting an application-specific solution of acid into the formation at a pressure between the pore pressure and fracture...

Keys, Ryan S.

2010-07-14T23:59:59.000Z

359

Kinetic evaluation of the esterification of fatty acids to biodiesel  

Science Journals Connector (OSTI)

The free fatty acids of cotton seed oil were processed with methanol and ethanol into the corresponding alkyl fatty esters in the presence of diluted sulfuric acid. The products characterized as biodiesels pre...

Frederico A. D. Araújo; Sonia V. Pereira…

2012-10-01T23:59:59.000Z

360

The determination of potential acidity in overburden sediments  

E-Print Network (OSTI)

Weathered Overburden Samples. Determination of Total Sulfur by LECO. Determination of Non-Sulfate Sulfur by LECO. Pyritic Iron Using the ASTM Method Potential Acidity Using a Rapid Oxidation Technique - Original Method. Potential Acidity Using a Rapid... the Sample. The Addition of Excess H 02. Catalysing the Decomposition of Excess H202. Leaching the Oxidized Sample with CaC12. Comparison of Potential Acidity Methods. F and T Tests. Potential Acidity of Weathered vs. Unweathered Samples. Total S...

O'Shay, Tracey Ann

2012-06-07T23:59:59.000Z

Note: This page contains sample records for the topic "nitric acid cxs" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

The biodegradation of organic acids by a heterogeneous bacterial culture  

E-Print Network (OSTI)

- tion of fatty acids results in multiple cleavage of the molecules to form shorter chain acids. It has been found (1I) that ethanoic and butanoic are the principle volatile acids present during digestion of sewage sludge while propanoic and pentanoic... was developed from a heterogeneous culture found in a sewage plant effluent. The culture was developed in a bench scale continuous flow activated. sludge reactor, and individual studies were made in a bench scale aerated batch reactor. The acids used were...

Tyer, Bobby Ray

1968-01-01T23:59:59.000Z

362

Nucleic Acid Standards - Sugar and Phosphate Constituents  

NLE Websites -- All DOE Office Websites (Extended Search)

Sugar and Phosphate Constituents Sugar and Phosphate Constituents The following tables contain the complete references for the structures used in a statistical survey of well-refined mononucleoside, mononucleotide, dinucleoside monophosphate, and trinucleoside diphosphate crystal structures found in the Cambridge Structural Database and the Nucleic Acid Database that appeared in The Journal of the American Chemical Society (Anke Gelbin, Bohdan Schneider, Lester Clowney, Shu-Hsin Hsieh, Wilma K. Olson, and Helen M. Berman. "Geometric Parameters in Nucleic Acids: Sugar Phosphate Constituents" (1996) 118, 519-529.) Table 1: References for Mononucleoside and Mononucleotide Structures Table 2: References for Dinucleoside Monophosphate and Trinucleoside Diphosphate Structures The following tables are summaries of the bond lengths, angles, and torsion

363

Improved Processes to Remove Naphthenic Acids  

NLE Websites -- All DOE Office Websites (Extended Search)

Improved Processes to Remove Naphthenic Acids Improved Processes to Remove Naphthenic Acids Final Technical Report (From October 1, 2002 to September 30, 2005) Principle Authors Aihua Zhang, Qisheng Ma, Kangshi Wang, Yongchun Tang (co-PI), William A. Goddard (PI), Date Report was issued: December 9, 2005 DOE Award number: DE-FC26-02NT15383 Name and Address of Submitting Organization California Institute of Technology 1200 East California Blvd., Pasadena, CA91125 Disclaimer This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any

364

Critical review of naphthenic acid corrosion  

SciTech Connect

Naphthenic acid corrosion continues to be a reliability issue in refinery distillation units. A review of the subject is presented herein with special focus on field and laboratory data and on areas where research is needed. The review shows that several parameters are known to affect the corrosion process and their individual effect on crude corrosivity are somewhat understood. However, their combined effect is still subject to much controversy. The determination of a critical factor--naphthenic acid content--is still not standardized. It is shown herein that, by arranging the literature findings into three groups (1) furnace tubes and transfer lines, (2) vacuum column and (3) side cut piping, a better agreement of the literature data is achieved.

Tebbal, S. [SET Labs., Inc., Stafford, TX (United States)

1999-11-01T23:59:59.000Z

365

Sulfate and acid resistant concrete and mortar  

DOE Patents (OSTI)

The present invention relates to concrete, mortar and other hardenable mixtures comprising cement and fly ash for use in construction and other applications, which hardenable mixtures demonstrate significant levels of acid and sulfate resistance while maintaining acceptable compressive strength properties. The acid and sulfate hardenable mixtures of the invention containing fly ash comprise cementitious materials and a fine aggregate. The cementitous materials may comprise fly ash as well as cement. The fine aggregate may comprise fly ash as well as sand. The total amount of fly ash in the hardenable mixture ranges from about 60% to about 120% of the total amount of cement, by weight, whether the fly ash is included as a cementious material, fine aggregate, or an additive, or any combination of the foregoing. In specific examples, mortar containing 50% fly ash and 50% cement in cementitious materials demonstrated superior properties of corrosion resistance. 6 figs.

Liskowitz, J.W.; Wecharatana, M.; Jaturapitakkul, C.; Cerkanowicz, A.E.

1998-06-30T23:59:59.000Z

366

Sulfate and acid resistant concrete and mortar  

DOE Patents (OSTI)

The present invention relates to concrete, mortar and other hardenable mixtures comprising cement and fly ash for use in construction and other applications, which hardenable mixtures demonstrate significant levels of acid and sulfate resistance while maintaining acceptable compressive strength properties. The acid and sulfate hardenable mixtures of the invention containing fly ash comprise cementitious materials and a fine aggregate. The cementitous materials may comprise fly ash as well as cement. The fine aggregate may comprise fly ash as well as sand. The total amount of fly ash in the hardenable mixture ranges from about 60% to about 120% of the total amount of cement, by weight, whether the fly ash is included as a cementious material, fine aggregate, or an additive, or any combination of the foregoing. In specific examples, mortar containing 50% fly ash and 50% cement in cementitious materials demonstrated superior properties of corrosion resistance.

Liskowitz, John W. (Belle Mead, NJ); Wecharatana, Methi (Parsippany, NJ); Jaturapitakkul, Chai (Bangkok, TH); Cerkanowicz, deceased, Anthony E. (late of Livingston, NJ)

1998-01-01T23:59:59.000Z

367

Lightweight, durable lead-acid batteries  

DOE Patents (OSTI)

A lightweight, durable lead-acid battery is disclosed. Alternative electrode materials and configurations are used to reduce weight, to increase material utilization and to extend service life. The electrode can include a current collector having a buffer layer in contact with the current collector and an electrochemically active material in contact with the buffer layer. In one form, the buffer layer includes a carbide, and the current collector includes carbon fibers having the buffer layer. The buffer layer can include a carbide and/or a noble metal selected from of gold, silver, tantalum, platinum, palladium and rhodium. When the electrode is to be used in a lead-acid battery, the electrochemically active material is selected from metallic lead (for a negative electrode) or lead peroxide (for a positive electrode).

Lara-Curzio, Edgar (Lenoir City, TN); An, Ke (Knoxville, TX); Kiggans, Jr., James O. (Oak Ridge, TN); Dudney, Nancy J. (Knoxville, TN); Contescu, Cristian I. (Knoxville, TN); Baker, Frederick S. (Oak Ridge, TN); Armstrong, Beth L. (Clinton, TN)

2011-09-13T23:59:59.000Z

368

Lightweight, durable lead-acid batteries  

SciTech Connect

A lightweight, durable lead-acid battery is disclosed. Alternative electrode materials and configurations are used to reduce weight, to increase material utilization and to extend service life. The electrode can include a current collector having a buffer layer in contact with the current collector and an electrochemically active material in contact with the buffer layer. In one form, the buffer layer includes a carbide, and the current collector includes carbon fibers having the buffer layer. The buffer layer can include a carbide and/or a noble metal selected from of gold, silver, tantalum, platinum, palladium and rhodium. When the electrode is to be used in a lead-acid battery, the electrochemically active material is selected from metallic lead (for a negative electrode) or lead peroxide (for a positive electrode).

Lara-Curzio, Edgar; An, Ke; Kiggans, Jr., James O; Dudney, Nancy J; Contescu, Cristian I; Baker, Frederick S; Armstrong, Beth L

2013-05-21T23:59:59.000Z

369

Nucleic acids, compositions and uses thereof  

DOE Patents (OSTI)

The subject invention provides at least one nucleic acid sequence encoding an aldouronate-utilization regulon isolated from Paenibacillus sp. strain JDR-2, a bacterium which efficiently utilizes xylan and metabolizes aldouronates (methylglucuronoxylosaccharides). The subject invention also provides a means for providing a coordinately regulated process in which xylan depolymerization and product assimilation are coupled in Paenibacillus sp. strain JDR-2 to provide a favorable system for the conversion of lignocellulosic biomass to biobased products. Additionally, the nucleic acid sequences encoding the aldouronate-utilization regulon can be used to transform other bacteria to form organisms capable of producing a desired product (e.g., ethanol, 1-butanol, acetoin, 2,3-butanediol, 1,3-propanediol, succinate, lactate, acetate, malate or alanine) from lignocellulosic biomass.

Preston, III, James F. (Micanopy, FL); Chow, Virginia (Gainesville, FL); Nong, Guang (Gainesville, FL); Rice, John D. (Gainesville, FL); St. John, Franz J. (Baltimore, MD)

2012-02-21T23:59:59.000Z

370

Nucleic acid compositions and the encoding proteins  

SciTech Connect

The subject invention provides at least one nucleic acid sequence encoding an aldouronate-utilization regulon isolated from Paenibacillus sp. strain JDR-2, a bacterium which efficiently utilizes xylan and metabolizes aldouronates (methylglucuronoxylosaccharides). The subject invention also provides a means for providing a coordinately regulated process in which xylan depolymerization and product assimilation are coupled in Paenibacillus sp. strain JDR-2 to provide a favorable system for the conversion of lignocellulosic biomass to biobased products. Additionally, the nucleic acid sequences encoding the aldouronate-utilization regulon can be used to transform other bacteria to form organisms capable of producing a desired product (e.g., ethanol, 1-butanol, acetoin, 2,3-butanediol, 1,3-propanediol, succinate, lactate, acetate, malate or alanine) from lignocellulosic biomass.

Preston, III, James F.; Chow, Virginia; Nong, Guang; Rice, John D.; St. John, Franz J.

2014-09-02T23:59:59.000Z

371

E-Print Network 3.0 - acid improves hypertriglyceridemia Sample...  

NLE Websites -- All DOE Office Websites (Extended Search)

contain unusual fatty acids that are valuable... p. 1 Lipid signals: jasmonic acid & green leaf volatiles i. Jasmonic acid and jasmonates... agronomic species i) diffent...

372

E-Print Network 3.0 - acid promotes detoxification Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

Bile acid Detoxification, Synthesis... acid transport, synthesis and detoxification. The LCA-induced altered enzymes and transporter... ;Regulation of bile acid detoxification and...

373

E-Print Network 3.0 - acid operational experiences Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

acetic acid, propionic acid, butyric acid, valeric ... Source: Manning, Sturt - Cornell Tree-Ring Laboratory, Cornell University Collection: Environmental Sciences and Ecology 34...

374

E-Print Network 3.0 - acid requirements based Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

(Eichhornia crassipes) to levulinic acid (LA) through an acid-catalysed hydrolysis reaction. LA has been... OHOH OH Diphenolic acid O CH3 Methyltetrahydrofuran O O OHNH2 ......

375

E-Print Network 3.0 - aminocyclopropane carboxylic acid Sample...  

NLE Websites -- All DOE Office Websites (Extended Search)

acid, which primarily loses the ele... -methylaziridinecarboxylic acid via an internal SN2 pathway, rather than protonated vinylglycine. Protonated amino acids... readily expel...

376

E-Print Network 3.0 - aromatic sulfonic acids Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

examples: Methane sulfonic... acid Ethane sulfonic acid 1-Propane sulfonic acid 1-Butane ... Source: Wikswo, John - Department of Physics and Astronomy, Vanderbilt University...

377

Naphthenic acid corrosion in the refinery  

SciTech Connect

Field tests and laboratory studies of refinery process streams are presented. The effects of temperature, velocity and physical state were studied with respect to alloy selection for corrosion resistant service. The amount of molybdenum in the austenitic stainless steel alloys is the dominant factor in conferring corrosion resistance. The Naphthenic Acid Corrosion Index (NACI) is useful in assessing the severity of corrosion under a variety of circumstances.

Craig, H.L. Jr. [Mobil Research and Development Corp., Paulsboro, NJ (United States)

1995-11-01T23:59:59.000Z

378

Alkaline earth cation extraction from acid solution  

DOE Patents (OSTI)

An extractant medium for extracting alkaline earth cations from an aqueous acidic sample solution is described as are a method and apparatus for using the same. The separation medium is free of diluent, free-flowing and particulate, and comprises a Crown ether that is a 4,4'(5')[C.sub.4 -C.sub.8 -alkylcyclohexano]18-Crown-6 dispersed on an inert substrate material.

Dietz, Mark (Elmhurst, IL); Horwitz, E. Philip (Naperville, IL)

2003-01-01T23:59:59.000Z

379

The Effect of Supercritical Fluids on Solid Acid Catalyst Alkylation  

Science Journals Connector (OSTI)

Box 1625, Idaho Falls, Idaho 83415-2208, and Marathon-Ashland Petroleum LLC, P.O. ... The liquid acid processes present serious safety and environmental concerns in both the transport and storage of concentrated liquid acids and the disposal of acid?oil sludges. ...

Daniel M. Ginosar; David N. Thompson; Kyle Coates; David J. Zalewski

2002-05-15T23:59:59.000Z

380

The Fixation of Phosphoric Acid by the Soil  

E-Print Network (OSTI)

KAS AtiRICULTURAL EXPERIMENT STATION AGRICULTURAL AND MECHANICAL COLLEGE OF TEXAS W. B. BII BULLETIN NO. 304 eddent CEMBER, 1922 'ION OF PHOSPI ACID BY THE SOIL B. YOUNGBLOOD, DIRECTOR, COLLEGE STATION, BRAZOS COUNTY, TEXA STATION STAFF... ............................................... '7 ............................................... ;t of Acid 7' ........................................... of Ignition 8 ........................................ on by Minerals 10 ...................... on of Phosphoric Acid of Fertilizers 11...

Fraps, G. S. (George Stronach)

1922-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "nitric acid cxs" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

How is ferulic acid transported into the Golgi apparatus? Lignin  

E-Print Network (OSTI)

How is ferulic acid transported into the Golgi apparatus? Lignin polymerization is also influenced]. These ferulic acid residues are thought to initiate lignin polymerization. It is not known how ferulic acid in the cell wall field, but also creates novel opportunities for the manipulation of lignin in crop plants

382

Production of carboxylic acid and salt co-products  

DOE Patents (OSTI)

This invention provide processes for producing carboxylic acid product, along with useful salts. The carboxylic acid product that is produced according to this invention is preferably a C.sub.2-C.sub.12 carboxylic acid. Among the salts produced in the process of the invention are ammonium salts.

Hanchar, Robert J.; Kleff, Susanne; Guettler, Michael V.

2014-09-09T23:59:59.000Z

383

EGVII endoglucanase and nucleic acids encoding the same  

DOE Patents (OSTI)

The present invention provides a novel endoglucanase nucleic acid sequence, designated egl7, and the corresponding EGVII amino acid sequence. The invention also provides expression vectors and host cells comprising a nucleic acid sequence encoding EGVII, recombinant EGVII proteins and methods for producing the same.

Dunn-Coleman, Nigel; Goedegebuur, Frits; Ward, Michael; Yao, Jian

2014-02-25T23:59:59.000Z

384

--No Title--  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

simulated SRS salt solution, nitric acid, oxalic acid, sodium hydroxide, simulated SRS sludge, monosodium titanate, and crystalline silicotitanate. Filter Testing with Static Test...

385

The Effects of Initial Condition of Fracture Surfaces, Acid Spending, and Type on Conductivity of Acid Fracture  

E-Print Network (OSTI)

. Another area of interest is the variation of conductivity along the fracture due to acid spending. We also investigated the contact time, acid system type, and treatment temperature effects on conductivity using San Andres dolomite cores. The results...

Almomen, Ali Mansour

2013-07-24T23:59:59.000Z

386

Naphthenic acid corrosion in synthetic fuels production  

SciTech Connect

Serious corrosion damage to carbon steel piping in a fractionation unit associated with synthetic fuels production has been ascribed to the presence of naphthenic acids. Investigation of the problem revealed total acids numbers (TAN) ranging from 8--12mg KOH/g in the feed to the unit. Damage typically occurred in the temperature range 180--240 C and manifested as localized pitting, preferential weld corrosion, general wall thinning and end-grain attack. Filming amine corrosion inhibitors designed for refinery overhead systems have been proven ineffective and high temperature phosphate-based inhibitors could not be used due to potential catalyst poisoning in downstream refinery units. Coupon exposures indicated corrosion rates in the order of 2 mm/y on carbon steel in a reboiler line as well as pitting to austenitic stainless steel type UNS S30403. Line replacement in austenitic stainless steel UNS S31603 has been proven effective. The performance of this alloy is mainly ascribed to its molybdenum content. The absence of sulfur in the feed to the unit is also contributing to the alloy performance despite the extremely high total acid numbers.

Bruyn, H.I. de [Mossgas Ltd., Mossel Bay (South Africa)

1998-12-31T23:59:59.000Z

387

The effects of solvent mixtures on the gel permeation chromatography of alkanes, fatty acids, and fatty acid esters  

E-Print Network (OSTI)

THE EFFECTS OF SOLVENT MIXTURES ON THE GEL PERMEATION CHROMATOGRAPHY OF ALKANES, FATTY ACIDS, AND FATTY ACID ESTERS A Thesis PATRICK LEE BOLTON Submitted to the Graduate College of Texas A&M University in partial fulfillment... of the requirements for the degree of MASTER OF SCIENCE December 1985 Major Subject: Chemistry THE EFFECTS OP SOLVENT MIXTURES ON THE GEL PERMEATION CHROMATOGRAPHY OF ALKANES, FATTY ACIDS, AND FATTY ACID ESTERS A Thesis by PATRICK LEE BOLTON Approved...

Bolton, Patrick Lee

1985-01-01T23:59:59.000Z

388

Type II Diacylglycerol Acyltransferase from Claviceps purpurea with Ricinoleic Acid, a Hydroxyl Fatty Acid of Industrial Importance, as Preferred Substrate  

Science Journals Connector (OSTI)

...total fatty acids in sclerotium oil (2). Ricinoleic acid, a...CpDGAT2 cDNA were obtained using a Marathon cDNA amplification kit (BD...purified from Ricinus communis oil according to Donaldson (11...fatty acids in the sclerotium oil of this fungus (2). DGAT2...

Ioannis Mavraganis; Dauenpen Meesapyodsuk; Patricia Vrinten; Mark Smith; Xiao Qiu

2009-12-18T23:59:59.000Z

389

Dosage de la lignine insoluble en milieu acide : influence du prtraitement par hydrolyse acide sur la lignine Kla-  

E-Print Network (OSTI)

Dosage de la lignine insoluble en milieu acide : influence du prétraitement par hydrolyse acide sur la lignine Kla- son de bois et de paille Bernard MONTIES LN.R.A., Laboratoire de Chimie biologique et la lignine insoluble dans l'acide sulfurique concentré, lignine Klason, est décrit : il comporte une

Paris-Sud XI, Université de

390

Rate dependent finite deformation stressstrain behavior of an ethylene methacrylic acid copolymer and an ethylene methacrylic acid butyl  

E-Print Network (OSTI)

Rate dependent finite deformation stress­strain behavior of an ethylene methacrylic acid copolymer and an ethylene methacrylic acid butyl acrylate copolymer S. Deschanel a,*, B.P. Greviskes a , K. Bertoldi a , S dependence a b s t r a c t The large strain deformation behaviors of an ethylene methacrylic acid (EMAA

391

Acetic Acid Production by Clostridium thermoaceticum in pH-Controlled Batch Fermentations at Acidic pH  

Science Journals Connector (OSTI)

...and the conversion efficiencies to acetic acid and...neutral pH. The highest acetic acid concentrations...acetic acid, and efficiency of converting glucose...the CO2 was of the highest purity attainable...valve completely and venting for 90 s, closing...ii) A glass furnace tube was packed...

Robert D. Schwartz; Frederick A. Keller Jr.

1982-06-01T23:59:59.000Z

392

Phosphatidic acid: an emerging plant lipid second messenger  

Science Journals Connector (OSTI)

Evidence is accumulating that phosphatidic acid is a second messenger. Its level increases within minutes of a wide variety of stress treatments including ethylene, wounding, pathogen elicitors, osmotic and oxidative stress, and abscisic acid. Enhanced signal levels are rapidly attenuated by phosphorylating phosphatidic acid to diacylglycerol pyrophosphate. Phosphatidic acid is the product of two signalling pathways, those of phospholipases C and D, the former in combination with diacylglycerol kinase. Families of these genes are now being cloned from plants. Several downstream targets of phosphatidic acid have been identified, including protein kinases and ion channels.

Teun Munnik

2001-01-01T23:59:59.000Z

393

Continuous-flow free acid monitoring method and system  

DOE Patents (OSTI)

A free acid monitoring method and apparatus is provided for continuously measuring the excess acid present in a process stream. The disclosed monitoring system and method is based on the relationship of the partial pressure ratio of water and acid in equilibrium with an acid solution at constant temperature. A portion of the process stream is pumped into and flows through the monitor under the influence of gravity and back to the process stream. A continuous flowing sample is vaporized at a constant temperature and the vapor is subsequently condensed. Conductivity measurements of the condensate produces a nonlinear response function from which the free acid molarity of the sample process stream is determined.

Strain, J.E.; Ross, H.H.

1980-01-11T23:59:59.000Z

394

Naphthenic acids as antiwear additives for jet fuels  

SciTech Connect

One of the ways in which the antiwear properties of jet fuels can be improved is the use of lubricity agents, otherwise known as antiwear additives. Among the various compounds that have antiwear properties in these fuels, naphthenic, acids merit special attention. These are alicyclic carboxylic acids, in most cases monobasic, with five- and six-membered carbon rings; they have the general formula R(CH{sub 2}){sub n}COOH, where R is a naphthene radical. Natural naphthenic acids consist mainly of acids of the cyclopentane series, beginning with the simplest, in particular cyclopentylacetic acid. The lower naphthenic acids are monocyclic; the higher acids, beginning with C{sub 13}, are bicyclic and polycyclic. Naphthenic acids of the cyclohexane series are encountered less frequently; they may be found, for example, in Baku, California, and Sakhalin crudes. The most widely used method for obtaining naphthenic acids is the treatment of light distillates, lube distillates, and diesel fuels. The standard GOST 13302-77 establishes several grades of naphthenic acids, depending on the raw material and the production technology. This work was aimed at the utilization of wastes containing naphthenic acids, with subsequent use as jet fuel additives.

Deineko, P.S.; Vasil`eva, E.N.; Popova, O.V.; Bashkatova, S.T.

1995-05-01T23:59:59.000Z

395

Interaction of Uranium(VI) with Phthalic Acid  

SciTech Connect

Phthalic acid, a ubiquitous organic compound found in soil, water, and in domestic and nuclear wastes can affect the mobility and bioavailability of metals and radionuclides. We examined the complexation of uranium with phthalic acid by potentiometric titration, electrospray ionization-mass spectroscopy (ESI-MS), and extended X-ray absorption fine structure (EXAFS) analysis. Potentiometric titration of a 1:1 U/phthalic acid indicated uranyl ion bonding with both carboxylate groups of phthalic acid; above pH 5 the uranyl ion underwent hydrolysis with one hydroxyl group coordinated to the inner-sphere of uranium. In the presence of excess phthalic acid, ESI-MS analysis revealed the formation of both 1:1 and 1:2 U/phthalic acid complexes. EXAFS studies confirmed the mononuclear biligand 1:2 U/phthalic acid complex as the predominant form. These results show that phthalates can form soluble stable complexes with uranium and may affect its mobility.

Vazquez, G.; Dodge, C; Francis, A

2008-01-01T23:59:59.000Z

396

Processes to remove acid forming gases from exhaust gases  

DOE Patents (OSTI)

The present invention relates to a process for reducing the concentration of NO in a gas, which process comprises: (A) contacting a gas sample containing NO with a gaseous oxidizing agent to oxidize the NO to NO[sub 2]; (B) contacting the gas sample of step (A) comprising NO[sub 2] with an aqueous reagent of bisulfite/sulfite and a compound selected from urea, sulfamic acid, hydrazinium ion, hydrazoic acid, nitroaniline, sulfanilamide, sulfanilic acid, mercaptopropanoic acid, mercaptosuccinic acid, cysteine or combinations thereof at between about 0 and 100 C at a pH of between about 1 and 7 for between about 0.01 and 60 sec; and (C) optionally contacting the reaction product of step (A) with conventional chemical reagents to reduce the concentrations of the organic products of the reaction in step (B) to environmentally acceptable levels. Urea or sulfamic acid are preferred, especially sulfamic acid, and step (C) is not necessary or performed. 16 figs.

Chang, S.G.

1994-09-20T23:59:59.000Z

397

Effect of Hydrolysis on the Properties of a New Viscoelastic Surfactant-Based Acid  

E-Print Network (OSTI)

Viscoelastic surfactants (VES) have been widely used in acidizing and acid fracturing. They are used as diversion agents during matrix acid treatments and leakoff control agents during acid fracturing. At high temperatures, viscoelastic surfactants...

He, Zhenhua

2013-08-07T23:59:59.000Z

398

E-Print Network 3.0 - acid-base equilibrium Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

Principles of Environmental Engineering Date Topic Reading Summary: Acid-Base Chemistry 86-195 28 Acid-Base Chemistry 31 Acid Base Chemistry Sept. 2 Acid-Base Chemistry...

399

Constructing and engineering fatty acid metabolic pathways for the production of fuels and chemicals  

E-Print Network (OSTI)

0 fatty acids in transgenic canola by overexpression of Ch0 fatty acids in transgenic canola by overexpression of Ch

Steen, Eric James

2010-01-01T23:59:59.000Z

400

Investigating fatty acid biosynthesis within the algal chloroplast using Chlamydomonas reinhardtii as a model  

E-Print Network (OSTI)

0 fatty acids in transgenic canola by overexpression of Ch0 fatty acids in transgenic canola by overexpression of Ch

Blatti, Jillian L.

2012-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "nitric acid cxs" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

E-Print Network 3.0 - active lewis acid Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

levulinic acid. Proceeding... chemicals: kinetic study on the decomposition of 5-hydroxymethylfurfural into levulinic acid. ... Source: Groningen, Rijksuniversiteit - Centre for...

402

Phosphoric acid impurities in phosphoric acid fuel cell electrolytes. 2: Effects on the oxygen reduction reaction at platinum electrodes  

SciTech Connect

The effects of phosphorus acid additions on the oxygen reduction reaction at platinum electrodes in concentrated phosphoric acid were studied. The oxygen reduction currents decreased, and the Tafel slopes became more negative upon the addition of small concentrations of phosphorus acid. In addition,the phosphorus acid oxidation current tended to complete with the oxygen reduction current. These effects became more pronounced at higher phosphorus acid concentrations and at higher temperatures. Upon the addition of phosphorus acid the number of electrons involved in the oxygen reduction reaction decreased from a value close to four to a value approaching two, suggesting promotion of a two-electron reduction to peroxide. Therefore, in studies of the electrochemical reduction of oxygen in hot concentrated phosphoric acid or in fuel cell systems using hot concentrated phosphoric acid as electrolyte, it is recommended that precautions be taken against the inadvertent formation of the phosphorus acid. The removal of phosphorus acid from concentrated phosphoric acid by repeated potential cycling at 100 mV/s between + 0.5 and +1.50 V (vs. dynamic hydrogen electrode) was demonstrated.

Sugishima, Noboru; Hinatsu, J.T.; Foulkes, F.R. (Univ. of Toronto, Ontario (Canada). Dept. of Chemical Engineering and Applied Chemistry)

1994-12-01T23:59:59.000Z

403

Nucleic acid amplification using modular branched primers  

DOE Patents (OSTI)

Methods and compositions expand the options for making primers for use in amplifying nucleic acid segments. The invention eliminates the step of custom synthesis of primers for Polymerase Chain Reactions (PCR). Instead of being custom-synthesized, a primer is replaced by a combination of several oligonucleotide modules selected from a pre-synthesized library. A modular combination of just a few oligonucleotides essentially mimics the performance of a conventional, custom-made primer by matching the sequence of the priming site in the template. Each oligonucleotide module has a segment that matches one of the stretches within the priming site.

Ulanovsky, Levy (Westmont, IL)

2001-01-01T23:59:59.000Z

404

Solvent extraction of rare-earth metals by carboxylic acids  

SciTech Connect

The solvent extraction of the trivalent lanthanides and yttrium from nitrate media by solutions of carboxylic acids in xylene has been studied. Commercially available carboxylic acids such as Versatic 10 and naphthenic acids were used, as well as model compounds of known structure, such as 2-ethylhexanoic and 3-cyclohexylpropanoic acids. In a few cases, extraction of the metals from sulphate and chloride solutions was also investigated. The dependence of the extraction properties of the carboxylic acids on the atomic number of the lanthanide shows a definite relationship to the steric bulk of the carboxylic acid molecule quantified by means of the steric parameter, E{sub s}{prime} of the substituent alkyl group. The stoichiometries of the extracted complexes for representative light (La), middle (Gd) and heavy (Lu) rare-earth metals were investigated by the slope-analysis technique for a sterically hindered acid (Versatic 10 acid; -E{prime}{sub s} = 3.83) and an acid with low steric hindrance (3-cyclohexylpropanoic acid; -E{prime}{sub s} = 0.28). 14 refs., 13 figs., 3 tabs.

Preez, A.C. du; Preston, J.S. [Mintek, Randburg (South Africa)

1992-04-01T23:59:59.000Z

405

Nucleic Acid Standards - Standard Ref. Frame  

NLE Websites -- All DOE Office Websites (Extended Search)

A Standard Reference Frame for the Description A Standard Reference Frame for the Description of Nucleic Acid Base-pair Geometry Supplementary Material The report is available at Journal of Molecular Biology (2001) 313: 229 - 237 and The Nucleic Acid Cartesian coordinates for A, C, G, T, and U in the optimized reference frame Adenine, Cytosine, Guanine, Thymine, Uracil Standard chemical structures taken from Clowney et al. (1996), J. Am. Chem. Soc., 118, 509-518). These data do not include C1' atoms, which are placed here in the least-squares plane of the base atoms, with the purine C1'-N9 bond length and C1'-N9-C4 valence angle set respectively to 1.46 Å and 126.5° and the pyrimidine C1'-N1 bond and C1-N1-C2 angle to 1.47 Å and 118.1°. These distances and angles are based on the average glycosyl

406

in amino-acid concentration enhanced amino-acid and glucose utilization for lipogenesis, with no  

E-Print Network (OSTI)

. In contrast, insulin decreased lipid secretion measured by glycerol (-35%) and glucose incor- poration increased glycerol incorporation (+35%) into cellular lipids and consequently lipogenesis. Insulin increased more strongly amino-acid and glucose incorporation into cellular lipids, the glu- cose incorporation

Boyer, Edmond

407

Evalutaion of Multi-Stage Sandstone Acidizing Uging an Organic Mud Acid and a Clay Stabalizer  

E-Print Network (OSTI)

and clay particles. The purpose of this study is to present and evaluate multi-stage acid injection into the Bandera sandstone cores to remove formation damage. In this study, coreflood experiments were conducted on Bandera sandstone cores (1.5 in. x 6 in...

Sakipour, Armin

2013-05-29T23:59:59.000Z

408

DOE - Office of Legacy Management -- Acid Pueblo Canyon - NM 03  

NLE Websites -- All DOE Office Websites (Extended Search)

Acid Pueblo Canyon - NM 03 Acid Pueblo Canyon - NM 03 FUSRAP Considered Sites Acid/Pueblo Canyon, NM Alternate Name(s): Radioactive Liquid Waste Treatment Plant (TA-45) Acid/Pueblo and Los Alamos Canyon NM.03-3 Location: Canyons in the Pajarito Plateau Region in Los Alamos County, Los Alamos, NM NM.03-3 Historical Operations: Late 1943 or early 1944, head of the south fork of Acid Canyon received untreated liquid waste containing tritium and isotopes of strontium, cesium, uranium, plutonium, and americium discharged from main acid sewer lines and subsequently from the TA-3 plutonium treatment plant. NM.03-3 Eligibility Determination: Radiological Survey(s): Verification Surveys NM.03-5 NM.03-6 Site Status: Certified- Certification Basis and Federal Register Notice NM.03-2

409

Newer method for analyzing naphthenic acids in petroleum  

SciTech Connect

The naphthenic acids in petroleum are considered a class of biological markers. Their potential use in source correlation and as indicator of biodegradation have been reported in the past. Their presence in waste water at refineries may also cause corrosion problems and fish toxicity. Due to their highly complicated nature, detailed characterization of the acids has been difficult and time consuming. This talk will describe a relatively simple approach in characterizing the acids based on their group types. The acids were first separated from petroleum followed by mass spectrometric determinations. Two newer methods were developed to analyze the acid components, namely Chemical Ionization with NF{sub 3} as reagent gas and negative ion Fast Atom Bombardment. The geochemical interpretation based on acid distribution will be demonstrated with a set of well understood crude oil samples.

Fan, T.P. (Shell Development Co., Houston, TX (United States))

1990-08-01T23:59:59.000Z

410

The iron powder test for naphthenic acid corrosion studies  

SciTech Connect

In the course of an ongoing investigation into the phenomenon of naphthenic acid corrosion, a new test method has evolved and is currently being further developed to substitute the total acid number (TAN or neutralization number) as an indicator for naphthenic acid corrosion potential. It can also be used to complement conventional autoclave corrosion tests in high temperature environments, which are based on weight loss of steel coupons. In this new method an oil sample reacts with pure iron powder within an autoclave heated to the testing temperature. The result is based on the amount of dissolved iron found in the oil sample. The oil sample can dissolve an amount of iron for a given time at a given temperature, depending on the naphthenic acid corrosion, since these acids react with iron to produce oil soluble iron naphthenates. This paper describes the method, compares it with conventional crude corrosiveness testing, and proposes it as a new way of measuring naphthenic acid corrosion potential.

Hau, J.L.; Yepez, O.; Specht, M.I.; Lorenzo, R. [PDVSA-Intevep, Caracas (Venezuela)

1999-11-01T23:59:59.000Z

411

Investigating the Effects of Core Length on Pore Volume to Breakthrough (PVBT) Behavior in Carbonate Core Samples during Matrix Acidizing with Hydrochloric Acid  

E-Print Network (OSTI)

Most literature contains Hydrochloric acid (HCl) carbonate acidizing experiments performed on short (2 - 6 inch) cores. These cores do not accurately represent reservoir conditions, as spent acid is not propagated for any appreciable distance along...

Nour, Mohamed

2014-05-06T23:59:59.000Z

412

An Improved Model for Sandstone Acidizing and Study of the Effect of Mineralogy and Temperature on Sandstone Acidizing Treatments and Simulation  

E-Print Network (OSTI)

Sandstone acidizing is a complex operation because the acidizing fluid reacts with a variety of minerals present in the formation that results in a wide range of reaction products. The hydrofluoric acid (HF) reaction rate differs widely from mineral...

Agarwal, Amit Kumar

2013-01-14T23:59:59.000Z

413

Study of Acid Response of Qatar Carbonate Rocks  

E-Print Network (OSTI)

STUDY OF ACID RESPONSE OF QATAR CARBONATE ROCKS A Thesis by ZHAOHONG WANG Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE... December 2011 Major Subject: Petroleum Engineering Study of Acid Response of Qatar Carbonate Rocks Copyright 2011 Zhaohong Wang STUDY OF ACID RESPONSE OF QATAR CARBONATE ROCKS A Thesis...

Wang, Zhaohong

2012-02-14T23:59:59.000Z

414

Phosphate ester inhibitors solve naphthenic acid corrosion problems  

SciTech Connect

Crude oils containing naphthenic acids can cause a variety of corrosion problems in any of several process areas. But because of the complexity of naphthenic acid corrosion, no routine technique is available for predicting corrosion from this source. Certain high-temperature corrosion inhibitors with a general phosphate ester structure have shown good mitigation of naphthenic acid corrosion in commercial applications. A description of two such cases will help refiners know what to look for to prevent similar occurrences in their plants.

Babaian-Kibala, E. (Nalco Chemical Co., Sugar Land, TX (United States))

1994-02-28T23:59:59.000Z

415

The reaction of cesium hydroxide with 4-phenylvaleric acid  

E-Print Network (OSTI)

Alkali Metal Hycroxide Solutions Used in Potentio- metric and Spectrophotometric Titrations with 4-Phenylvaleric Acid 17 Samples for Nuclear Magnetic Resonance Spectra 18 Concentration of 4-Phenylvaleric Acid in Carbon Tetrachloride for Infrared.... Similarly, nuclear magnetic resonance techniques may be used to determine whether any TT-bonding involving the phenyl ring of 4- phenylvaleric acid occurs during its reaction with cesium hydroxide. If any such bonding to the n-electrons of the ring occurs...

Caughfield, Arvie Jeane

2012-06-07T23:59:59.000Z

416

A First Look at Yeast Fatty Acid Synthase  

NLE Websites -- All DOE Office Websites (Extended Search)

A First Look at Yeast Fatty Acid A First Look at Yeast Fatty Acid Synthase A First Look at Yeast Fatty Acid Synthase Print Wednesday, 28 November 2007 00:00 Fatty acids are the major constituents of eukaryotic and bacterial cellular membranes. They are used for functionally important post-translational protein modifications, and chains of fatty acids are the main storage compartments of an organism's chemical energy. Fatty acid synthesis is carried out by fatty acid sythase (FAS), which catalyzes cycles of multistep chemical reactions that are essentially the same in all organisms. FAS uses one acetyl-coenzyme A (CoA) and seven malonyl-CoA molecules to synthesize the 16-carbon palmitic acid, the most abundant fatty acid in eukaryotes. Now, for the first time, a group of researchers has determined the atomic structure of yeast Saccharomyces cerevisiae FAS derived from two crystals of the enzyme, using data collected at ALS Beamlines 8.2.1 and 8.2.2, as well as other synchrotron facilities.

417

Production of Biofuels from High-Acid-Value Waste Oils  

Science Journals Connector (OSTI)

Production of Biofuels from High-Acid-Value Waste Oils ... (1) Biofuel is derived from a renewable, domestic resource, thereby relieving reliance on petroleum fuel imports. ...

Junming Xu; Guomin Xiao; Yonghong Zhou; Jianchun Jiang

2011-08-27T23:59:59.000Z

418

Regulating for the long term: SMCRA and acid mine drainage  

SciTech Connect

With the passage of the Surface Mining Control and Reclamation Act of 1977 (SMCRA), regulators and industry representatives expected to solve the problem of pollution of the Nation`s waterways caused by acidic discharges from coal mines. Eighteen years after the passage of SMCRA, hard issues of predicting, regulating and treating acid mine drainage remain. Acid mine drainage is most common in the coal seams of the Midwest and Appalachia: Pennsylvania, West Virginia, Maryland, Ohio, Illinois, and Tennessee. This article discusses regulation of coal mines and acid mine drainage for the long term.

Shea, C.W.

1995-12-31T23:59:59.000Z

419

E-Print Network 3.0 - acid glycosaminoglycan mucopolysaccharide...  

NLE Websites -- All DOE Office Websites (Extended Search)

used: HA, hyaluronic acid; hexosa- minidase, 3-IV-acetyl ... Source: Geiger, Benjamin - Department of Molecular Cell Biology, Weizmann Institute of Science Collection:...

420

Recombinant microorganisms for increased production of organic acids  

DOE Patents (OSTI)

Disclosed are recombinant microorganisms for producing organic acids. The recombinant microorganisms express a polypeptide that has the enzymatic activity of an enzyme that is utilized in the pentose phosphate cycle. The recombinant microorganism may include recombinant Actinobacillus succinogenes that has been transformed to express a Zwischenferment (Zwf) gene. The recombinant microorganisms may be useful in fermentation processes for producing organic acids such as succinic acid and lactic acid. Also disclosed are novel plasmids that are useful for transforming microorganisms to produce recombinant microorganisms that express enzymes such as Zwf.

Yi, Jian; Kleff, Susanne; Guettler, Michael V

2013-04-30T23:59:59.000Z

Note: This page contains sample records for the topic "nitric acid cxs" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Recombinant microorganisms for increased production of organic acids  

DOE Patents (OSTI)

Disclosed are recombinant microorganisms for producing organic acids. The recombinant microorganisms express a polypeptide that has the enzymatic activity of an enzyme that is utilized in the pentose phosphate cycle. The recombinant microorganism may include recombinant Actinobacillus succinogenes that has been transformed to express a Zwischenferment (Zwf) gene. The recombinant microorganisms may be useful in fermentation processes for producing organic acids such as succinic acid and lactic acid. Also disclosed are novel plasmids that are useful for transforming microorganisms to produce recombinant microorganisms that express enzymes such as Zwf.

Yi, Jian (East Lansing, MI); Kleff, Susanne (East Lansing, MI); Guettler, Michael V. (Holt, MI)

2012-02-21T23:59:59.000Z

422

Amino acid treatment enhances protein recovery from sediment...  

NLE Websites -- All DOE Office Websites (Extended Search)

treatment enhances protein recovery from sediment and soils for metaproteomic studies . Amino acid treatment enhances protein recovery from sediment and soils for metaproteomic...

423

Dissociative Binding of Carboxylic Acid Ligand on Nanoceria Surface...  

NLE Websites -- All DOE Office Websites (Extended Search)

Abstract: Carboxylic acid is a common ligand anchoring group to functionalize nanoparticle surfaces. Its binding structures and mechanisms as a function of the oxidation...

424

Membrane Stresses Induced by Overproduction of Free Fatty Acids...  

NLE Websites -- All DOE Office Websites (Extended Search)

coli. Abstract: Microbially produced fatty acids are potential precursors to high energy density biofuels, including alkanes and alkyl ethyl esters by either catalytic...

425

amino acid conjugates: Topics by E-print Network  

NLE Websites -- All DOE Office Websites (Extended Search)

the measured distributions. Guang Wu; Shaomin Yan 71 Amino acid classes and the protein folding problem Condensed Matter (arXiv) Summary: We present and implement a...

426

The corrosion of aluminum in boric acid solutions  

E-Print Network (OSTI)

vs. Time of at 40oC . vs. Time of 40 C . 34 ~ ~ ~ 35 3S Aluminum in Boric ~ ~ ~ 24S Aluminum in Boric Corrosion Rate Acid Solutions vs. Time of at 50oC . 2S Aluminum in Boric 36 Corrosion Rate Acid Solutions vs. Time of at 50oC 3S... Solutions vs. Time of 3S Aluminum in Boric at 70oC 40 Corrosion Rate Acid Solutions vs. Time of at 70oC 24S Aluminum in Boric ~ ~ ~ . a ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ /+1 14. Corrosion Rate Acid Solutions vs. Time of at 90cC 2S Aluminum in Boric 42 15...

Bass, Henry Kinsolving

2012-06-07T23:59:59.000Z

427

A novel recycling process using the treated citric acid wastewater as ingredients water for citric acid production  

Science Journals Connector (OSTI)

Abstract In this study, an integrated process coupling citric acid and methane fermentations was proposed to solve severe wastewater pollution problem in cassava-based citric acid production. The accumulation patterns of the potential and major inhibitors in this process, including organic compounds, volatile fatty acids (VFAs), total ions and pigments were investigated. Both simulation and experimental results indicated that these inhibitors could reach their equilibrium levels after 3–7 fermentation runs when reutilizing the treated citric acid wastewater. As a result, the proposed citric acid fermentation process by recycling the wastewater treated in methane fermentation could be stably operated for more than 15 runs, which could save a large amount of fresh water and relieve the severe wastewater pollution in citric acid production potentially.

Hong-Jian Zhang; Jian-Hua Zhang; Jian Xu; Lei Tang; Zhong-Gui Mao

2014-01-01T23:59:59.000Z

428

Interaction of divalent cations with triethylenetetraminehexaacetic acid  

Science Journals Connector (OSTI)

Further studies of the interactions of divalent metal ions with triethylenetetraminehexaacetic acid (TTHA) have revealed that mononuclear, binuclear, and protonated mononuclear complexes are formed in solution with Zn(II), Cd(II), Hg(II) and Pb(II) iions. Equilibrium constants are reported for the various complex species formed, and possible structures for the mononuclear are reported for the various complex species formed, and possible structures for the mononuclear species are suggested. Other reports describing the nature of the complexes formed by this ligand with divalent metal ions are confirmed in that the binuclear complexes are resistant to hydrolysis in alkaline solution, and that the symmetrical binuclear complex is considered the most likely structure.

Austin Yingst; Arthur E. Martell

1971-01-01T23:59:59.000Z

429

Naphthenic acid corrosion and its control  

SciTech Connect

This paper first presents a brief description of naphthenic acid corrosion and the main factors which influence its onset and severity. After a brief discussion of traditional control methods, it proceeds to a discussion of chemical inhibition, which is a relatively new control technique. Chemical inhibitors can be divided into two broad classifications: phosphorus-based and non-phosphorus-based. Three types of phosphorus-based inhibitors have been reported: amine-neutralized phosphate esters, alkaline earth phosphonate phenate sulfide plus trialkyl phosphate, and thiazolines plus di and tri-alkyl phosphates. Non-phosphorus based inhibitors include: thiazolines, organic polysulfides, and sulfonated alkyl phenols. A description of each inhibitor and its effectiveness in the laboratory and field is presented.

Zetlmeisl, M.J. [Petrolite Corp., St. Louis, MO (United States)

1996-08-01T23:59:59.000Z

430

Corrosion of carbons in acid electrolytes  

SciTech Connect

The stability of the electrode materials used in hot phosphoric acid fuel cells, in particular the conductive carbon electrocatalyst support, is a continuing concern. The Tafel slope of the carbon corrosion reaction appears to be indicative of the degree of disorder on the carbon surface--the larger the Tafel slope, the greater the degree of disorder. The effect of heat-treatment was found to depend on the structure of the parent carbon. Differences in the electrochemical behavior of samples of heattreated Vulcan XC-72R were correlated with the structural properties of the carbon produced, as reflected by lattice parameters. Changes in BET surface areas and lattice parameters as well as in electrochemical behavior showed evidence that the addition of boron resulted in ''graphitization'' that was not achieved by heat-treatment alone.

Stonehart, P.; MacDonald, J.

1983-08-01T23:59:59.000Z

431

Production of levulinic acid from glucosamine by dilute-acid catalyzed hydrothermal process  

Science Journals Connector (OSTI)

Abstract Glucosamine is a basic unit of the chitin/chitosan structure, which is derived from crustacean (e.g. crab, shrimp) and insect shells. In this study, the production of levulinic acid (LA) from glucosamine via dilute-acid-catalyzed hydrothermal hydrolysis was investigated. Among the reaction conditions, reaction temperature, reaction time, and substrate concentration were more effective than catalyst concentration. The optimal conditions for LA production, as determined by the response-surface methodology (RSM), were as follows: 188 °C reaction temperature, 4 wt% catalyst concentration, 49 min reaction time, 120 g/L substrate concentration. Under these conditions, the LA yield was 30.3 g/L (25.3 wt%), while the 5-HMF concentration was zero. These results might provide basic knowledge essential to the production of valuable chemicals derivable from renewable marine resources and utilizable as fuel additives and polymer building blocks.

Gwi-Taek Jeong

2014-01-01T23:59:59.000Z

432

Behavior of copper in acidic sulfate solution: Comparison with acidic chloride  

SciTech Connect

The anodic polarization behavior of copper in a 0.1 M sulfuric acid (H{sub 2}SO{sub 4}) + 1 M sodium sulfate (Na{sub 2}SO{sub 4}) solution (pH = 2.0) was studied at room temperature under quiescent and stirred conditions. The behavior was compared with aqueous equilibria via construction of a potential-vs-pH (E-pH) diagram for the copper-sulfate-water (Cu-SO{sub 4}{sup 2}-H{sub 2}O) system. Interpretation of the behavior was aided by comparison with aqueous equilibria and polarization studies of copper in a 0.2 M hydrochloric acid (HCl) + 1 M sodium chloride (NaCl) solution(pH = 0.8). The initial anodic dissolution region in the acidic sulfate solution exhibited Tafel behavior with a slope consistent with formation of cupric ions (Cu{sup 2+}) whose rate of formation was charge-transfer controlled. At higher potentials, limiting current density (i{sub L}) behavior was observed under E-pH conditions that were consistent with formation of a film of copper sulfate pentahydrate (CuSO{sub 4} {degree} 5H{sub 2}O). Comparison of experimental i{sub L} values with those predicted by mass transport-controlled processes, using estimates of the diffusion layer thickness obtained from the mass transfer-influenced region of apparent Tafel behavior in the acidic chloride solution, were in sufficient agreement to indicate i{sub L} was controlled by the rate of dissolution of the CuSO{sub 4} {degree} 5H{sub 2}O film via transport of Cu{sup 2+} from the film-electrolyte interface into the bulk solution.

Tromans, D.; Silva, J.C. [Univ. of British Columbia, Vancouver, British Columbia (Canada). Dept. of Metals and Materials Engineering

1997-03-01T23:59:59.000Z

433

Abc Amino Acids: Design, Synthesis, and Properties of New Photoelastic Amino Acids  

SciTech Connect

Photoisomerizable amino acids provide a direct avenue to the experimental manipulation of bioactive polypeptides, potentially allowing real-time, remote control of biological systems and enabling useful applications in nanobiotechnology. Herein, we report a new class of photoisomerizable amino acids intended to cause pronounced expansion and contraction in the polypeptide backbone, i.e., to be photoelastic. These compounds, termed Abc amino acids, employ a photoisomerizable azobiphenyl chromophore to control the relative disposition of aminomethyl and carboxyl substituents. Molecular modeling of nine Abc isomers led to the identification of one with particularly attractive properties, including the ability to induce contractions up to 13A in the backbone upon transa?cis photoisomerization. This isomer, designated mpAbc, has substituents at meta and para positions on the inner (azo-linked) and outer rings, respectively. An efficient synthesis of Fmoc-protected mpAbc was executed in which the biaryl components were formed via Suzuki couplings and the azo linkage was formed via amine/nitroso condensation; protected forms of three other Abc isomers were prepared similarly. A decapeptide incorporating mpAbc was synthesized by conventional solid-phase methods and displayed characteristic azobenzene photochemical behavior with optimal conversion to the cis isomer at 360 nm and a thermal cisa?trans half life of 100 min. at 80 AoC.

Standaert, Robert F [ORNL; Park, Dr Seung Bum [Seoul National University

2006-01-01T23:59:59.000Z

434

Original article Ethanol and acetic-acid tolerance  

E-Print Network (OSTI)

Original article Ethanol and acetic-acid tolerance in Indian geographical populations of Drosophila clines of ethanol toler- ance (1.5-4.2%) and acetic-acid tolerance (2.9-4.9%) were observed in adult individuals of 4 geographical populations of Drosophila immigrans. Thus, both ethanol and acetic

Paris-Sud XI, Université de

435

Original article Ethanol and acetic-acid tolerances  

E-Print Network (OSTI)

Original article Ethanol and acetic-acid tolerances in Drosophila melanogaster: similar maternal) Summary - Ethanol and acetic-acid tolerances were studied in a cross between 2 geo- graphic races disappeared in the F2. Further investigations demonstrated that for ethanol tolerance, the large difference

Paris-Sud XI, Université de

436

Stimulation of Carbonate Reservoirs Using a New Emulsified Acid System  

E-Print Network (OSTI)

The scope of work can be divided into; the measurement of the rheological properties of a new emulsified acid system that can be suitable for high temperature applications, a study of the performance of the new emulsified acid in stimulating both...

Sayed, Mohammed Ali Ibrahim

2013-05-15T23:59:59.000Z

437

Ancient insights into uric acid metabolism in primates  

E-Print Network (OSTI)

such as gout and hypertension have plagued us for centu- ries. The prevalence of gout in the United States has, a key enzyme that metabolizes uric acid, leaving us vulnerable to diseases such as gout rise to the well-known joint pain associated with gout. Elevated uric acid levels have also been

Chang, Belinda

438

Solvent extraction studies of holmium with acidic extractants  

SciTech Connect

Liquid-liquid extraction studies of holmium with 2-ethylhexyl phosphoric acid mono-2-ethylhexyl ester, naphthenic, and Versatic 10 acids have been carried out. The nature of the extracted species and the extraction equilibrium constants of these systems have been determined from aqueous nitrate solution. The extraction mechanism and complexation models have been proposed. 11 refs., 8 figs.

Gaikwad, A.G.; Damodaran, A.D. (CSIR, Trivandrum (India))

1993-03-01T23:59:59.000Z

439

Evaporative Hydrochloric Acid Recovery: Something Old, Something New...  

E-Print Network (OSTI)

. If zinc is present from the pickling of galvanizing racks or stripping of parts, the zinc concentration will range from as low as zinc chloride solution remains. In the evaporative process of the Hydrochloric Acid Recovery System, the waste acid is pumped through a pre-filter into the evaporator section oftI1e recovery system. This solution is heated by means...

Cullivan, B.

440

Boron-containing amino carboxylic acid compounds and uses thereof  

DOE Patents (OSTI)

Novel compounds which are useful for boron neutron capture therapy (BNCT) are disclosed. The compounds comprise a stable boron-containing group and an aminocycloalkane carboxylic acid group or a boronated acyclic hydrocarbon-linked amino carboxylic acid. Methods for synthesis of the compounds and for use of the compounds in BNCT are disclosed.

Kabalka, George W. (Knoxville, TN); Srivastava, Rajiv R. (Knoxville, TN)

2000-03-14T23:59:59.000Z

Note: This page contains sample records for the topic "nitric acid cxs" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

AcidBase Regulation in Fishes: Cellular and Molecular Mechanisms  

E-Print Network (OSTI)

, and functional studies that have begun to define the protein transporters involved in the acid­base relevant ion gill membrane transport processes in acid­base balance. J. Exp. Zool. 293:302­319, 2002. r 2002 Wiley on recent advances in our understand- ing of membrane transport systems which are responsible for the net

Claiborne, James Berkeley

442

Effects of the Biologically Produced Polymer Alginic Acid on  

E-Print Network (OSTI)

. Using a combined atomic force microscopy (AFM)/flow- through reactor apparatus, we investigated. In alginic acid, the acute step retreat rate is nearly unchanged in comparison to water, whereas the obtuse but propagate faster in the obtuse direction. To explain these observations, we propose that alginic acid

443

Production of amino acids using auxotrophic mutants of methylotrophic bacillus  

SciTech Connect

A method of producing amino acids by culturing an amino acid auxotroph of a biologically pure strain of a type I methylotrophic bacterium of the genus Bacillus which exhibits sustained growth at 50.degree. C. using methanol as a carbon and energy source and requiring vitamin B.sub.12 and biotin is provided.

Hanson, Richard S. (Wayzata, MN); Flickinger, Michael C. (St. Paul, MN); Schendel, Frederick J. (Falcon Heights, MN); Guettler, Michael V. (Waconia, MN)

2001-07-17T23:59:59.000Z

444

Propionic-Acid-Terminated Silicon Nanoparticles: Synthesis and Optical Characterization  

E-Print Network (OSTI)

producing water-dispersible, propionic-acid-terminated particles. From transmission electron microscope (TEM oxidation of the nanocrystals. The silicon nanocrystals could be transferred into water or methanol in acrylic acid, water, and methanol and showed essentially the same optical properties in all three solvents

Swihart, Mark T.

445

Inhibition of Aluminum Oxyhydroxide Precipitation with Citric Acid  

E-Print Network (OSTI)

Inhibition of Aluminum Oxyhydroxide Precipitation with Citric Acid Daniel M. Dabbs, Usha as an agent for increasing the solubility of aluminum oxyhydroxides in aqueous solutions of high (>2.47 mol/mol) hydroxide-to-aluminum ratios. Conversely, citric acid also colloidally stabilizes particles in aqueous

Aksay, Ilhan A.

446

Preparation of {alpha},{beta}-unsaturated carboxylic acids and esters  

DOE Patents (OSTI)

Disclosed is a process for the preparation of {alpha},{beta}-unsaturated carboxylic acids and esters thereof which comprises contacting formaldehyde or a source of formaldehyde with a carboxylic acid, ester or anhydride in the presence of a catalyst comprising an oxide of niobium.

Gogate, M.R.; Spivey, J.J.; Zoeller, J.R.

1998-09-15T23:59:59.000Z

447

Membrane Bound: C2-Domain Abscisic Acid-Related Proteins Help Abscisic Acid Receptors Get Where They Need to Go  

Science Journals Connector (OSTI)

...Membrane Bound: C2-Domain Abscisic Acid-Related Proteins Help Abscisic Acid Receptors Get Where They Need to Go Jennifer Lockhart jlockhart@aspb.org Science Editor www.plantcell.org/cgi/doi/10.1105/tpc.114.134411

Jennifer Lockhart

2014-12-02T23:59:59.000Z

448

Nucleic Acid Standards | Base Pair Geometry  

NLE Websites -- All DOE Office Websites (Extended Search)

A Standard Reference Frame for the Description A Standard Reference Frame for the Description of Nucleic Acid Base-pair Geometry Table 1. Cartesian coordinates of non-hydrogen atoms in the standard reference frames of the five common nitrogenous bases Atom Base x(Ã…) y(Ã…) z(Ã…) Adenine ATOM 1 C1' A A 1 -2.479 5.346 0.000 ATOM 2 N9 A A 1 -1.291 4.498 0.000 ATOM 3 C8 A A 1 0.024 4.897 0.000 ATOM 4 N7 A A 1 0.877 3.902 0.000 ATOM 5 C5 A A 1 0.071 2.771 0.000 ATOM 6 C6 A A 1 0.369 1.398 0.000 ATOM 7 N6 A A 1 1.611 0.909 0.000 ATOM 8 N1 A A 1 -0.668 0.532 0.000 ATOM 9 C2 A A 1 -1.912 1.023 0.000 ATOM 10 N3 A A 1 -2.320 2.290 0.000

449

Nucleic acids encoding human trithorax protein  

DOE Patents (OSTI)

In accordance with the present invention, there is provided an isolated peptide having the characteristics of human trithorax protein (as well as DNA encoding same, antisense DNA derived therefrom and antagonists therefor). The invention peptide is characterized by having a DNA binding domain comprising multiple zinc fingers and at least 40% amino acid identity with respect to the DNA binding domain of Drosophila trithorax protein and at least 70% conserved sequence with respect to the DNA binding domain of Drosophila trithorax protein, and wherein said peptide is encoded by a gene located at chromosome 11 of the human genome at q23. Also provided are methods for the treatment of subject(s) suffering from immunodeficiency, developmental abnormality, inherited disease, or cancer by administering to said subject a therapeutically effective amount of one of the above-described agents (i.e., peptide, antagonist therefor, DNA encoding said peptide or antisense DNA derived therefrom). Also provided is a method for the diagnosis, in a subject, of immunodeficiency, developmental abnormality, inherited disease, or cancer associated with disruption of chromosome 11 at q23.

Evans, Glen A. (Encinitas, CA); Djabali, Malek (Marseilles, FR); Selleri, Licia (Del Mar, CA); Parry, Pauline (San Diego, CA)

2001-01-01T23:59:59.000Z

450

GENETIC ANALYSIS OF ABSCISIC ACID BIOSYNTHESIS  

SciTech Connect

The carotenoid cleavage dioxygenases (CCD) catalyze synthesis of a variety of apo-carotenoid secondary metabolites in plants, animals and bacteria. In plants, the reaction catalyzed by the 11, 12, 9-cis-epoxy carotenoid dioxygenase (NCED) is the first committed and key regulated step in synthesis of the plant hormone, abscisic acid (ABA). ABA is a key regulator of plant stress responses and has critical functions in normal root and seed development. The molecular mechanisms responsible for developmental control of ABA synthesis in plant tissues are poorly understood. Five of the nine CCD genes present in the Arabidopsis genome encode NCED's involved in control of ABA synthesis in the plant. This project is focused on functional analysis of these five AtNCED genes as a key to understanding developmental regulation of ABA synthesis and dissecting the role of ABA in plant development. For this purpose, the project developed a comprehensive set of gene knockouts in the AtNCED genes that facilitate genetic dissection of ABA synthesis. These mutants were used in combination with key molecular tools to address the following specific objectives: (1) the role of ABA synthesis in root development; (2) developmental control of ABA synthesis in seeds; (3) analysis of ATNCED over-expressers; (4) preliminary crystallography of the maize VP14 protein.

MCCARTY D R

2012-01-10T23:59:59.000Z

451

Fate of the naphthenic acid, U-{sup 14}C-palmitic acid, in constructed wetlands; A microcosm study  

SciTech Connect

This study represents part of an overall initiative to assess the ecological viability of constructed wetlands for the treatment of oil sands wastewater. To determine the fate of naphthenic acids (C{sub n}H{sub 2n+z}O{sub 2}), the most toxic component of oil sands wastewater, in constructed wetlands, a representative naphthenic acid (NA), U-{sup 14}C-palmitic acid was added to microcosms placed within three control and three treatment wetlands. Treatment wetlands receive wastewater typical of effluent resulting from the oil sands extraction process. In each of the 6 microcosms, biotic compartments measured for {sup 14}C at t = 0, 1, 3, 5, 7, 14 and 21 days were: mineralized palmitic acid (evolved {sup 14}C-CO{sub 2}), water, suspended sediments, bottom sediments, cattail, chironomid larvae, and sticklebacks (liver, muscle and skin). The fate of the {sup 14}C-palmitic acid was similar between the control versus treatment microcosms. Exceptions were greater amounts of {sup 14}C-palmitic acid detected in water and suspended sediments of treatment versus control microcosms. Of the biotic compartments, at t = 21 days, the majority of the {sup 14}C-palmitic acid was found in chironomids and fish tissues. Mineralization and partitioning of {sup 14}C-palmitic acid onto sediments also represented important fates. From the initial addition of the labelled compound, with the exception of bottom sediments, by t = 1 day {sup 14}C was detected in ail biotic compartments. {sup 14}C was detected in bottom sediments by t = 7 days. These results indicate that in addition to mineralization being an important process influencing the fate palmitic acid within the wetlands, partitioning into biotic compartments such as chironomids and fish are also important fates. Hence, when considering the use of constructed wetlands for the treatment of oil sands effluent, the adverse effects of naphthenic acids on the biota needs to be fully addressed.

Wood, A.; Barjaktarovic, L.; Moore, M.; Kennedy, C.; Farrell, A.P.; Bendell-Young, L.I. [Simon Fraser Univ., Burnaby, British Columbia (Canada). Dept. of Biological Sciences

1995-12-31T23:59:59.000Z

452

Process for removing naphthenic acids from petroleum distillates  

SciTech Connect

A liquid extraction process is described for removing naphthenic acids from naphthenic acid containing petroleum distillates boiling within the range of about 180/sup 0/-600/sup 0/C. and having an acid number of at least about 0.2 which process comprises the steps of: (a) intimately contacting the petroleum distillates with a solvent consisting essentially of methanol, water, and about from 2-20 wt. % ammonia and having a methanol: water ratio in the range of about from 0.2 to 3 parts by weight of methanol per part by weight of water and using an ammonia to petroleum distillate ratio of about 0.1-1 part by weight of ammonia per 100 parts by weight of the petroleum distillate. This selectively extracts the naphthenic acids into the solvent and yielding an immiscible two-phase liquid mixture, one of which is naphthenic acid-rich solvent phase and the other of which is a substantially napthenic acid-free petroleum distillate phase; and (b) separating and respectively recovering the naphtenic acid-rich solvent phase and petroleum distillate phase.

Danzik, M.

1987-01-06T23:59:59.000Z

453

Ursolic acid improves domoic acid-induced cognitive deficits in mice  

SciTech Connect

Our previous findings suggest that mitochondrial dysfunction is the mechanism underlying cognitive deficits induced by domoic acid (DA). Ursolic acid (UA), a natural triterpenoid compound, possesses many important biological functions. Evidence shows that UA can activate PI3K/Akt signaling and suppress Forkhead box protein O1 (FoxO1) activity. FoxO1 is an important regulator of mitochondrial function. Here we investigate whether FoxO1 is involved in the oxidative stress-induced mitochondrial dysfunction in DA-treated mice and whether UA inhibits DA-induced mitochondrial dysfunction and cognitive deficits through regulating the PI3K/Akt and FoxO1 signaling pathways. Our results showed that FoxO1 knockdown reversed the mitochondrial abnormalities and cognitive deficits induced by DA in mice through decreasing HO-1 expression. Mechanistically, FoxO1 activation was associated with oxidative stress-induced JNK activation and decrease of Akt phosphorylation. Moreover, UA attenuated the mitochondrial dysfunction and cognitive deficits through promoting Akt phosphorylation and FoxO1 nuclear exclusion in the hippocampus of DA-treated mice. LY294002, an inhibitor of PI3K/Akt signaling, significantly decreased Akt phosphorylation in the hippocampus of DA/UA mice, which weakened UA actions. These results suggest that UA could be recommended as a possible candidate for the prevention and therapy of cognitive deficits in excitotoxic brain disorders. - Highlights: • Ursolic acid (UA) is a naturally triterpenoid compound. • UA attenuated the mitochondrial dysfunction and cognitive deficits. • Mechanistically, UA activates PI3K/Akt signaling and suppresses FoxO1 activity. • UA could be recommended as a possible candidate for anti-excitotoxic brain disorders.

Wu, Dong-mei [School of Environment and Spatial Informatics, China University of Mining and Technology, Xuzhou 221008, Jiangsu Province (China); Key Laboratory for Biotechnology on Medicinal Plants of Jiangsu Province, School of Life Science, Xuzhou Normal University, Xuzhou 221116, Jiangsu Province (China); Lu, Jun, E-mail: lu-jun75@163.com [Key Laboratory for Biotechnology on Medicinal Plants of Jiangsu Province, School of Life Science, Xuzhou Normal University, Xuzhou 221116, Jiangsu Province (China); Zhang, Yan-qiu [School of Environment and Spatial Informatics, China University of Mining and Technology, Xuzhou 221008, Jiangsu Province (China); Zheng, Yuan-lin, E-mail: ylzheng@xznu.edu.cn [Key Laboratory for Biotechnology on Medicinal Plants of Jiangsu Province, School of Life Science, Xuzhou Normal University, Xuzhou 221116, Jiangsu Province (China); Hu, Bin [Key Laboratory for Biotechnology on Medicinal Plants of Jiangsu Province, School of Life Science, Xuzhou Normal University, Xuzhou 221116, Jiangsu Province (China); Cheng, Wei [School of Environment and Spatial Informatics, China University of Mining and Technology, Xuzhou 221008, Jiangsu Province (China); Zhang, Zi-feng; Li, Meng-qiu [Key Laboratory for Biotechnology on Medicinal Plants of Jiangsu Province, School of Life Science, Xuzhou Normal University, Xuzhou 221116, Jiangsu Province (China)

2013-09-01T23:59:59.000Z

454

An In-depth Investigation of an Aluminum Chloride Retarded Mud Acid System on Sandstone Reservoirs  

E-Print Network (OSTI)

Sandstone acidizing using mud acid is a quick and complex process where dissolution and precipitation occur simultaneously. Retarded mud acids are less reactive with the rock reducing the reaction rate hence increased penetration into the formation...

Aneto, Nnenna

2012-07-16T23:59:59.000Z

455

The Effect Of Viscoelastic Surfactants Used In Carbonate Matrix Acidizing On Wettability  

E-Print Network (OSTI)

Carbonate reservoirs are heterogeneous; therefore, proper acid placement/diversion is required to make matrix acid treatments effective. Viscoelastic surfactants (VES) are used as diverting agents in carbonate matrix acidizing. However...

Adejare, Oladapo

2012-07-16T23:59:59.000Z

456

E-Print Network 3.0 - acid-induced bile duct Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

of Lithocholic Acid in the Regulation of Bile acid Detoxification, Synthesis... acid (LCA), a common ligand of VDR, FXR and PXR, on the regulation of proteins involved in bile...

457

E-Print Network 3.0 - acid sensor fxr Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

Role of Lithocholic Acid in the Regulation of Bile acid Detoxification, Summary: acid (LCA), a common ligand of VDR, FXR and PXR, on the regulation of proteins involved in bile...

458

E-Print Network 3.0 - acid base regulation Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

12 Bio390 ACID-BASE thanks to Dr. J.F. Anderson, Summary: Bio390 ACID-BASE thanks to Dr. J.F. Anderson, Dept Zoology Univ of Florida, Gainesville... , there is more acid than base...

459

E-Print Network 3.0 - acids reduce body Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

that is causing thialkalosis. Thus, the Pa... Bio390 ACID-BASE thanks to Dr. J.F. Anderson, Dept Zoology Univ of Florida, Gainesville... " "acid" ) log( "salt" "acid"...

460

E-Print Network 3.0 - acid sequence analysis Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

Acid Analysis Page 77 An Introduction to Amino Acid Analysis Summary: as a whole, and ISO 17025:2005 Technical competence in amino acid analysis and protein sequencing... An...

Note: This page contains sample records for the topic "nitric acid cxs" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

A novel method for the purification of prephenic acid  

E-Print Network (OSTI)

in the K ? of components eluting av with prephenate from G-10/NH4HC03 column. . III Elemental analysis of barium prephenate. . Page 22 28 30 is P rfi ti of p phe ic acid f ~oos o c essa. . . 35 LIST OF FIGURES Figure Prephenic acid Page... of the degree of cross-linking, type of gel and eluting solvent polarity on the separation of cis and trans-cin- namic acids. They found that the degree of cross-linking influences the degree of adsorption, as defined by K . The K for Sephadex 1 av av G-10...

Harding, Tammy Tiner

2012-06-07T23:59:59.000Z

462

Human retroviruses and AIDS 1996. A compilation and analysis of nucleic acid and amino acid sequences  

SciTech Connect

This compendium and the accompanying floppy diskettes are the result of an effort to compile and rapidly publish all relevant molecular data concerning the human immunodeficiency viruses (HIV) and related retroviruses. The scope of the compendium and database is best summarized by the five parts that it comprises: (1) Nuclear Acid Alignments and Sequences; (2) Amino Acid Alignments; (3) Analysis; (4) Related Sequences; and (5) Database Communications. Information within all the parts is updated throughout the year on the Web site, http://hiv-web.lanl.gov. While this publication could take the form of a review or sequence monograph, it is not so conceived. Instead, the literature from which the database is derived has simply been summarized and some elementary computational analyses have been performed upon the data. Interpretation and commentary have been avoided insofar as possible so that the reader can form his or her own judgments concerning the complex information. In addition to the general descriptions of the parts of the compendium, the user should read the individual introductions for each part.

Myers, G.; Foley, B.; Korber, B. [eds.] [Los Alamos National Lab., NM (United States). Theoretical Div.] [eds.; Los Alamos National Lab., NM (United States). Theoretical Div.; Mellors, J.W. [ed.] [Univ. of Pittsburgh, PA (United States)] [ed.; Univ. of Pittsburgh, PA (United States); Jeang, K.T. [ed.] [National Institutes of Health, Bethesda, MD (United States). Molecular Virology Section] [ed.; National Institutes of Health, Bethesda, MD (United States). Molecular Virology Section; Wain-Hobson, S. [Pasteur Inst., Paris (France)] [ed.] [Pasteur Inst., Paris (France); ed.

1997-04-01T23:59:59.000Z

463

E-Print Network 3.0 - amino acid restriction Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

of amino acid encoding to present amino acid sequences in the most beneficial way for machine learning... are calculated from position specific ... Source: Bodn, Mikael - School...

464

E-Print Network 3.0 - acid-metabolizing enzyme cytochrome Sample...  

NLE Websites -- All DOE Office Websites (Extended Search)

on metabolic enzyme activities in the freshwater Summary: elegans. These include enzymes of carbohydrate, fatty acid, adenylate, and amino acid metabolism. Anoxia... recovery...

465

E-Print Network 3.0 - acid desaturase gene Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

fatty acids. Mutagenesis and selection in E. coli yielded variants... . Cahoon EB, Shanklin J: Substrate-dependent mutant complementation to select fatty acid desaturase......

466

E-Print Network 3.0 - acid suppresses uv-b-induced Sample Search...  

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are discussed in relation to the Summary: in Chapter 3, carboxylic acids are the actual additives responsible for the suppression of catalase... excess of carboxylic acid in...

467

acid overcomes bcl-2-mediated: Topics by E-print Network  

NLE Websites -- All DOE Office Websites (Extended Search)

preservation A Rauramaa A Tommila J Ltd, Espoo Reseach Centre, PO Box 44, 02271 Espoo, Finland Formic acid is known to improve silage hygienic quality. Formic acid based...

468

E-Print Network 3.0 - acids electronic resource Sample Search...  

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of Dicarboxylic Acid Clusters with Water Molecules Summary: Cluster Phase Chemistry: Gas-Phase Reactions of Anionic Sodium Salts of Dicarboxylic Acid Clusters... -phase...

469

E-Print Network 3.0 - acid electronic resource Sample Search...  

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of Dicarboxylic Acid Clusters with Water Molecules Summary: Cluster Phase Chemistry: Gas-Phase Reactions of Anionic Sodium Salts of Dicarboxylic Acid Clusters... -phase...

470

E-Print Network 3.0 - acid derivative entrapped Sample Search...  

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2003 ) Biodegradable hydrophilic polymers poly-lactic-co-glycolic acid (PLGA) and polyethylene oxide... -co-lactic acid (PELA) were used to encapsulate a small hydrophilic...

471

E-Print Network 3.0 - acid protects human Sample Search Results  

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Introduction: Scope of the Thesis Ansar A. Khan Summary: , 155). The major products of LCA metabolism in human and rat liver microsomes are hyodeoxycholic acid... bile acids such...

472

E-Print Network 3.0 - acid dicamba dicloran Sample Search Results  

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weed control. Acetic acid (vinegar) WeedGrass Killer, Natural... weed control. Ammoniated soap of fatty acid Garden Safe Weed & Grass ... Source: Liskiewicz, Maciej -...

473

E-Print Network 3.0 - acid sequence determination Sample Search...  

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by Scatchard analysis of 3 H nicotinic acid binding saturation isotherms. Relative cell surface... sequences from GPR109B. B, nicotinic acid- and ... Source: Hall, Randy A -...

474

E-Print Network 3.0 - amino acid-linked dialkyl Sample Search...  

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Amino acid may raise risk... tested blood for homocysteine, an amino acid known to mark heart ... Source: Portland State University, Center for Lakes and Reservoirs...

475

E-Print Network 3.0 - acid suppression predict Sample Search...  

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the situation... the cloud condensation nucleus activity of organic acids on the basis of surface tension and osmolality... in the solutions of organic acids. The surface tension...

476

E-Print Network 3.0 - acid process effluent Sample Search Results  

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plant every few weeks, with the exception of fatty acid... characteristics of the wastewater effluent, the acidity of wastewater effluent was determined by...

477

E-Print Network 3.0 - acid pre hydrolysis Sample Search Results  

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at Madison Collection: Chemistry ; Biology and Medicine 9 Notes & Tips Mass spectrometric identification of pyroglutamic acid Summary: used for carboxylic acid ester- ification...

478

E-Print Network 3.0 - acid complex films Sample Search Results  

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doping acid during the formation of thin films. Both the electrical switching and electrochromic... and forms sulfuric acid within the PBZT film. The ... Source: Guo, John Zhanhu...

479

E-Print Network 3.0 - acid leach solutions Sample Search Results  

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acid produced by the decay fungi plays during leaching... acids. The soluble heavy metal complex can then be ... Source: Miha, Humar - Biotehnike fakultete, University of...

480

E-Print Network 3.0 - acid leaching present Sample Search Results  

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acid produced by the decay fungi plays during leaching... acids. The soluble heavy metal complex can then be leached from the wood. Thus, both the remediated wood... between...

Note: This page contains sample records for the topic "nitric acid cxs" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

E-Print Network 3.0 - ascorbic acid-related genes Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

was to examine whether glutathione (GSH) and ascorbic acid, two reac- tive... groups: acrolein, acroleinGSH and acroleinascorbic acid. Re- sults: We found that while GSH resulted...

482

E-Print Network 3.0 - acid recruits beneficial Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

was to examine whether glutathione (GSH) and ascorbic acid, two reac- tive... groups: acrolein, acroleinGSH and acroleinascorbic acid. Re- sults: We found that while GSH resulted...

483

E-Print Network 3.0 - acid brittleness Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

search results for: acid brittleness Page: << < 1 2 3 4 5 > >> 1 Acid Fumigation of Sediment Samples (From UC Davis Isotope Lab website, http:stableisotopefacility.ucdavis.edu...

484

E-Print Network 3.0 - acid bilayers observed Sample Search Results  

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of Docosahexaenoic Acid-Containing Phospholipid Bilayers as Studied by 2H NMR... of vinyl perdeuterated arachidonic acid chains in bilayers of 1-palmitoyl-2-vinylperdeuterioara...

485

E-Print Network 3.0 - abscisic acid sensitivity Sample Search...  

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altered sensitivity of growth responses to abscisic acid, auxin, gibberellins and ethylene... plant stress hormones - abscisic acid and ethylene - in opposite ways. Recent...

486

E-Print Network 3.0 - acid oligomerisation manipulating Sample...  

NLE Websites -- All DOE Office Websites (Extended Search)

of oxidising proteins or lipids and causing chemi- cal modication to nucleic acids (Gilbert... . The sec- ondary structure is mapped onto the amino acid sequence in Figure 3...

487

E-Print Network 3.0 - adding zoledronic acid Sample Search Results  

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Cancer Receiving... cancer is well recognized. We assessed the effects of quarterly infusion of zoledronic acid on bone... to treatment with zoledronic acid (4 mg) ... Source:...

488

E-Print Network 3.0 - administering zoledronic acid Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

Cancer Receiving... cancer is well recognized. We assessed the effects of quarterly infusion of zoledronic acid on bone... to treatment with zoledronic acid (4 mg) ... Source:...

489

E-Print Network 3.0 - acids cells humans Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

the stomach... the effects of PPI action on acid levels 36. Our original gastric acid secretion model tracks four cell... popula- tions in the stomach considered critical for...

490

E-Print Network 3.0 - acid rain effects Sample Search Results  

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of Mexican Mayan monuments. Ingenieria... eroding because of acid rain. Just as water dis- solves an Alka-Seltzer tablet, acid rain erodes... Autonomous University of...

491

E-Print Network 3.0 - acid induced chemical Sample Search Results  

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levulinic acid. Proceeding... chemicals: kinetic study on the decomposition of 5-hydroxymethylfurfural into levulinic acid. Proceeding... ., Green chemicals: A kinetic study on the...

492

E-Print Network 3.0 - acid reactivity reaction Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

; Biology and Medicine 42 A Kinetic Study on the Decomposition of 5-Hydroxymethylfurfural into Summary: -soluble products Levulinic acid + Formic acid Figure 3.1...

493

E-Print Network 3.0 - acid allied chemical Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

levulinic acid. Proceeding... chemicals: kinetic study on the decomposition of 5-hydroxymethylfurfural into levulinic acid. Proceeding... ., Green chemicals: A kinetic study on the...

494

E-Print Network 3.0 - acid-soluble organic matrix Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

Environmental Sciences and Ecology 38 A Kinetic Study on the Decomposition of 5-Hydroxymethylfurfural into Summary: - methylfurfural Acid-soluble products Levulinic acid + Formic...

495

E-Print Network 3.0 - acid dha implications Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

this effect remain uncertain. In general... to phosphocholine). The actions of DHA aere reproduced by eicosapentaenoic acid, another omega-3 compound... acid (DHA), a uridine...

496

Adsorption of (poly)maleic acid and aquatic fulvic accids by goethite.  

E-Print Network (OSTI)

?? The adsorption characteristics of a synthetic organic polymer - polymaleic acid (PMA) and Suwannee River fulvic acid (SRFA) by goethite was studied. The adsorption… (more)

Wang, Lili

1996-01-01T23:59:59.000Z

497

Reaction kinetics of the esterification reaction between ethanol and acetic acid catalyzed by Keggin heteropolyacids  

Science Journals Connector (OSTI)

Heteropolyacids (HPAs), such as silicotungstic (HSiW), phosphotungstic (HPW), and phosphomolybdic (HPMo) acids, effectively catalyzed the esterification reaction between ethanol and acetic acid. The catalytic act...

Xiufeng Lu; Hengbo Yin; Lingqin Shen…

2014-02-01T23:59:59.000Z

498

E-Print Network 3.0 - amino acid polymorphisms Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

Summary: by ascertainment bias. Contrasting Divergence and Polymorphism for the 75 Elementary Amino Acid Changes... . The potential biases toward collecting com- mon amino acid...

499

E-Print Network 3.0 - acid copper sulfate Sample Search Results  

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with chalcopyrite. 5239Cu isotopes in the supergene environment 12;with the copper isotope variation of acid-sulfate... bonding in the Cu mineral during acid- sulfate leaching...

500

E-Print Network 3.0 - adipocyte fatty acid-binding Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

Biochemistry 221: 127132, 2001. 2001 Kluwer Academic Publishers. Printed in the Netherlands. Summary: acid, gene regulation Introduction Fatty acid-binding proteins (FABPs)...