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1

Denitration of High Nitrate Salts Using Reductants  

SciTech Connect (OSTI)

This report describes work conducted by Pacific Northwest National Laboratory (PNNL), in conjunction with Idaho National Engineering and Environmental Laboratory (INEEL), to remove nitrates in simulated low-activity waste (LAW). The major objective of this work was to provide data for identifying and demonstrating a technically viable and cost-effective approach to condition LAW for immobilization (grout).

HD Smith; EO Jones; AJ Schmidt; AH Zacher; MD Brown; MR Elmore; SR Gano

1999-05-03T23:59:59.000Z

2

Waste Isolation Pilot Plant Nitrate Salt Bearing Waste Container  

E-Print Network [OSTI]

of Energy (DOE) and Nuclear Waste Partnership LLC (NWP), collectively referred to as the Permittees Isolation Plan (Plan) for identified nitrate salt bearing waste disposed in the Waste Isolation Pilot Plant detailed proposal for the expedited closure of underground Hazardous Waste Disposal Unit (HWDU) Panel 6, so

Napp, Nils

3

Effects of Nitrate on Decomposition in Salt Marsh Peats Arianna Goodman  

E-Print Network [OSTI]

Effects of Nitrate on Decomposition in Salt Marsh Peats Arianna Goodman Oberlin College `13 Advisor and loss. Rapid nitrate addition to salt marshes may stimulate bacterial decomposition of existing peat, and the decomposition may contribute to creek bank destabilization and collapse. Alternately, peat deposited in high

Vallino, Joseph J.

4

Project Profile: Advanced Nitrate Salt Central Receiver Power Plant |  

Broader source: Energy.gov (indexed) [DOE]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarly Careerlumens_placard-green.epsEnergy1.pdfMarket |21,-CommitteeItems at6ACity HQdetailsLIFEDepartment

5

Materials corrosion of high temperature alloys immersed in 600C binary nitrate salt.  

SciTech Connect (OSTI)

Thirteen high temperature alloys were immersion tested in a 60/40 binary nitrate salt. Samples were interval tested up to 3000 hours at 600%C2%B0C with air as the ullage gas. Chemical analysis of the molten salt indicated lower nitrite concentrations present in the salt, as predicted by the equilibrium equation. Corrosion rates were generally low for all alloys. Corrosion products were identified using x-ray diffraction and electron microprobe analysis. Fe-Cr based alloys tended to form mixtures of sodium and iron oxides, while Fe-Ni/Cr alloys had similar corrosion products plus oxides of nickel and chromium. Nickel based alloys primarily formed NiO, with chromium oxides near the oxide/base alloy interface. In625 exhibited similar corrosion performance in relation to previous tests, lending confidence in comparisons between past and present experiments. HA230 exhibited internal oxidation that consisted of a nickel/chromium oxide. Alloys with significant aluminum alloying tended to exhibit superior performance, due formation of a thin alumina layer. Soluble corrosion products of chromium, molybdenum, and tungsten were also formed and are thought to be a significant factor in alloy performance.

Kruizenga, Alan Michael; Gill, David Dennis; LaFord, Marianne Elizabeth

2013-03-01T23:59:59.000Z

6

Polyethylene encapsulatin of nitrate salt wastes: Waste form stability, process scale-up, and economics  

SciTech Connect (OSTI)

A polyethylene encapsulation system for treatment of low-level radioactive, hazardous, and mixed wastes has been developed at Brookhaven National Laboratory. Polyethylene has several advantages compared with conventional solidification/stabilization materials such as hydraulic cements. Waste can be encapsulated with greater efficiency and with better waste form performance than is possible with hydraulic cement. The properties of polyethylene relevant to its long-term durability in storage and disposal environments are reviewed. Response to specific potential failure mechanisms including biodegradation, radiation, chemical attack, flammability, environmental stress cracking, and photodegradation are examined. These data are supported by results from extensive waste form performance testing including compressive yield strength, water immersion, thermal cycling, leachability of radioactive and hazardous species, irradiation, biodegradation, and flammability. The bench-scale process has been successfully tested for application with a number of specific problem'' waste streams. Quality assurance and performance testing of the resulting waste form confirmed scale-up feasibility. Use of this system at Rocky Flats Plant can result in over 70% fewer drums processed and shipped for disposal, compared with optimal cement formulations. Based on the current Rocky Flats production of nitrate salt per year, polyethylene encapsulation can yield an estimated annual savings between $1.5 million and $2.7 million, compared with conventional hydraulic cement systems. 72 refs., 23 figs., 16 tabs.

Kalb, P.D.; Heiser, J.H. III; Colombo, P.

1991-07-01T23:59:59.000Z

7

Herbicide and nitrate distribution in central Iowa rainfall  

SciTech Connect (OSTI)

Herbicides are detected in rainfall; however, these are a small fraction of the total applied. This study was designed to evaluate monthly and annual variation in atrazine (6-chloro-N-ethyl-N{prime}-(1-methylethyl)-1,3,5-triazine-2,4-diamine), alachlor (2-chloro-N-(2,6-diethylphenyl)-N-(methoxymethyl)acetamide), metolachlor (2-chloro-N-(2-ethyl-6-methylphenyl)-N-(2-methoxy-1-methylethyl)acetamide), and NO{sub 3}-N concentrations in rainfall over Walnut Creek watershed south of Ames, IA. The study began in 1991 and continued through 1994. Within the watershed, two wet/dry precipitation samplers were positioned 4 km apart. Detections varied during the year with >90% of the herbicide detections occurring in April through early July. Concentrations varied among events from nondetectable amounts to concentrations of 154 {mu}g L{sup {minus}1}, which occurred when atrazine was applied during an extremely humid day immediately followed by rainfall of <10 mm that washed spray drift from the atmosphere. This was a local scale phenomenon, because the other collector had a more typical concentration of 1.7 {mu}g L{sup {minus}1} with an 8-mm rainfall. VAriation between the two collectors suggests that local scale meteorological processes affect herbicide movement. Yearly atrazine deposition totals were >100 {mu}g m{sup {minus}2} representing <0.1% of the amount applied. Nitrate-N concentrations in precipitation were uniformly distributed throughout the year and without annual variation in the concentrations. Deposition rates of NO{sub 3}-N were about 1.2 g m{sup {minus}2}. Annual loading onto the watershed was about 25% of the amount applied from all forms of N fertilizers. Movement and rates of deposition provide an understanding of the processes and magnitude of the impact of agriculture on the environment. 7 refs., 5 figs., 3 tabs.

Hatfield, J.L.; Prueger, J.H.; Pfeiffer, R.L. [National Soil Tilth Lab., Ames, IA (United States); Wesley, C.K. [Princeton Univ., NJ (United States)

1996-03-01T23:59:59.000Z

8

Nitrate reduction  

DOE Patents [OSTI]

Nitrates are reduced to nitrogen gas by contacting the nitrates with a metal to reduce the nitrates to nitrites which are then contacted with an amide to produce nitrogen and carbon dioxide or acid anions which can be released to the atmosphere. Minor amounts of metal catalysts can be useful in the reduction of the nitrates to nitrites. Metal salts which are formed can be treated electrochemically to recover the metals.

Dziewinski, Jacek J. (Los Alamos, NM); Marczak, Stanislaw (Los Alamos, NM)

2000-01-01T23:59:59.000Z

9

Temperature-dependent mechanical property testing of nitrate thermal storage salts.  

SciTech Connect (OSTI)

Three salt compositions for potential use in trough-based solar collectors were tested to determine their mechanical properties as a function of temperature. The mechanical properties determined were unconfined compressive strength, Young's modulus, Poisson's ratio, and indirect tensile strength. Seventeen uniaxial compression and indirect tension tests were completed. It was found that as test temperature increases, unconfined compressive strength and Young's modulus decreased for all salt types. Empirical relationships were developed quantifying the aforementioned behaviors. Poisson's ratio tends to increase with increasing temperature except for one salt type where there is no obvious trend. The variability in measured indirect tensile strength is large, but not atypical for this index test. The average tensile strength for all salt types tested is substantially higher than the upper range of tensile strengths for naturally occurring rock salts. Interest in raising the operating temperature of concentrating solar technologies and the incorporation of thermal storage has motivated studies on the implementation of molten salt as the system working fluid. Recently, salt has been considered for use in trough-based solar collectors and has been shown to offer a reduction in levelized cost of energy as well as increasing availability (Kearney et al., 2003). Concerns regarding the use of molten salt are often related to issues with salt solidification and recovery from freeze events. Differences among salts used for convective heat transfer and storage are typically designated by a comparison of thermal properties. However, the potential for a freeze event necessitates an understanding of salt mechanical properties in order to characterize and mitigate possible detrimental effects. This includes stress imparted by the expanding salt. Samples of solar salt, HITEC salt (Coastal Chemical Co.), and a low melting point quaternary salt were cast for characterization tests to determine unconfined compressive strength, indirect tensile strength, coefficient of thermal expansion (CTE), Young's modulus, and Poisson's ratio. Experiments were conducted at multiple temperatures below the melting point to determine temperature dependence.

Everett, Randy L.; Iverson, Brian D.; Broome, Scott Thomas; Siegel, Nathan Phillip; Bronowski, David R.

2010-09-01T23:59:59.000Z

10

Effect of chloride content of molten nitrate salt on corrosion of A516 carbon steel.  

SciTech Connect (OSTI)

The corrosion behavior of A516 carbon steel was evaluated to determine the effect of the dissolved chloride content in molten binary Solar Salt. Corrosion tests were conducted in a molten salt consisting of a 60-40 weight ratio of NaNO{sub 3} and KNO{sub 3} at 400{sup o}C and 450{sup o}C for up to 800 hours. Chloride concentrations of 0, 0.5 and 1.0 wt.% were investigated to determine the effect on corrosion of this impurity, which can be present in comparable amounts in commercial grades of the constituent salts. Corrosion rates were determined by descaled weight losses, corrosion morphology was examined by metallographic sectioning, and the types of corrosion products were determined by x-ray diffraction. Corrosion proceeded by uniform surface scaling and no pitting or intergranular corrosion was observed. Corrosion rates increased significantly as the concentration of dissolved chloride in the molten salt increased. The adherence of surface scales, and thus their protective properties, was degraded by dissolved chloride, fostering more rapid corrosion. Magnetite was the only corrosion product formed on the carbon steel specimens, regardless of chloride content or temperature.

Bradshaw, Robert W.; Clift, W. Miles

2010-11-01T23:59:59.000Z

11

Corrosion resistance of stainless steels during thermal cycling in alkali nitrate molten salts.  

SciTech Connect (OSTI)

The corrosion behavior of three austenitic stainless steels was evaluated during thermal cycling in molten salt mixtures consisting of NaNO{sub 3} and KNO{sub 3}. Corrosion tests were conducted with Types 316, 316L and 304 stainless steels for more than 4000 hours and 500 thermal cycles at a maximum temperature of 565 C. Corrosion rates were determined by chemically descaling coupons. Metal losses ranged from 5 to 16 microns and thermal cycling resulted in moderately higher corrosion rates compared to isothermal conditions. Type 316 SS was somewhat more corrosion resistant than Type 304 SS in these tests. The effect of carbon content on corrosion resistance was small, as 316L SS corroded only slightly slower than 316 SS. The corrosion rates increased as the dissolved chloride content of the molten salt mixtures increased. Chloride concentrations approximating 1 wt.%, coupled with thermal cycling, resulted in linear weight loss kinetics, rather than parabolic kinetics, which described corrosion rates for all other conditions. Optical microscopy and electron microprobe analysis revealed that the corrosion products consisted of iron-chromium spinel, magnetite, and sodium ferrite, organized as separate layers. Microanalysis of the elemental composition of the corrosion products further demonstrated that the chromium content of the iron-chromium spinel layer was relatively high for conditions in which parabolic kinetics were observed. However, linear kinetics were observed when the spinel layer contained relatively little chromium.

Bradshaw, Robert W.; Goods, Steven Howard

2001-09-01T23:59:59.000Z

12

Advanced Thermal Storage for Central Receivers with Supercritical Coolants  

SciTech Connect (OSTI)

The principal objective of the study is to determine if supercritical heat transport fluids in a central receiver power plant, in combination with ceramic thermocline storage systems, offer a reduction in levelized energy cost over a baseline nitrate salt concept. The baseline concept uses a nitrate salt receiver, two-tank (hot and cold) nitrate salt thermal storage, and a subcritical Rankine cycle. A total of 6 plant designs were analyzed, as follows: Plant Designation Receiver Fluid Thermal Storage Rankine Cycle Subcritical nitrate salt Nitrate salt Two tank nitrate salt Subcritical Supercritical nitrate salt Nitrate salt Two tank nitrate salt Supercritical Low temperature H2O Supercritical H2O Two tank nitrate salt Supercritical High temperature H2O Supercritical H2O Packed bed thermocline Supercritical Low temperature CO2 Supercritical CO2 Two tank nitrate salt Supercritical High temperature CO2 Supercritical CO2 Packed bed thermocline Supercritical Several conclusions have been drawn from the results of the study, as follows: 1) The use of supercritical H2O as the heat transport fluid in a packed bed thermocline is likely not a practical approach. The specific heat of the fluid is a strong function of the temperatures at values near 400 °C, and the temperature profile in the bed during a charging cycle is markedly different than the profile during a discharging cycle. 2) The use of supercritical CO2 as the heat transport fluid in a packed bed thermocline is judged to be technically feasible. Nonetheless, the high operating pressures for the supercritical fluid require the use of pressure vessels to contain the storage inventory. The unit cost of the two-tank nitrate salt system is approximately $24/kWht, while the unit cost of the high pressure thermocline system is nominally 10 times as high. 3) For the supercritical fluids, the outer crown temperatures of the receiver tubes are in the range of 700 to 800 °C. At temperatures of 700 °C and above, intermetallic compounds can precipitate between, and within, the grains of nickel alloys. The precipitation leads to an increase in tensile strength, and a decrease in ductility. Whether the proposed tube materials can provide the required low cycle fatigue life for the supercritical H2O and CO2 receivers is an open question. 4) A ranking of the plants, in descending order of technical and economic feasibility, is as follows: i) Supercritical nitrate salt and baseline nitrate salt: equal ratings ii) Low temperature supercritical H2O iii) Low temperature supercritical CO2 iv) High temperature supercritical CO2 v) High temperature supercritical H2O 5) The two-tank nitrate salt thermal storage systems are strongly preferred over the thermocline systems using supercritical heat transport fluids.

Kelly, Bruce D.

2010-06-15T23:59:59.000Z

13

Potential for future development of salt cavern storage in the upper Silurian Syracuse Formation of south-central New York  

SciTech Connect (OSTI)

Although depleted reservoirs remain the dominant structures used for storage fulfilling the demand for base load gas supply during the heating season, the current general surge in storage projects, nationwide, takes advantage of opportunities in Order 636, and makes greater use of salt caverns for gas storage. This reflects the increasing need by gas users, local distribution companies in particular, to quickly cycle a storage facility`s gas supply for services such as peak shaving, emergency supply, and system balancing to meet hourly swings. Occurrence of thick deposits of bedded salt deposits provides New York the capability to develop high deliverability salt cavern storage facilities. Furthermore, New York is uniquely positioned at the gateway to major northeastern markets to provide peak load storage services of natural gas supply. The thickest units of bedded salt in New York occur in the {open_quotes}F{close_quotes} horizon of the Upper Silurian Syracuse Formation. Three bedded salt cavern storage facilities have been recently proposed in New York. Two of these projects is much larger (with 5 Bcfg ultimate capacity), is under construction, and will provide valuable storage service to the Ellisburg-Leidy market center hub in Pennsylvania. Identification of possible sites for future salt cavern storage projects has been achieved chiefly by defining areas of thick beds of salt at sufficient depths close to gas transmission lines, with access to a freshwater supply for leaching, and possessing an acceptable method of brine disposal.

Bass, J.P.; Sarwar, G.; Guo, B. [Brooklyn College of the City Univ. of New York, Troy, NY (United States)] [and others

1995-09-01T23:59:59.000Z

14

Basin Analysis and Petroleum System Characterization and Modeling, Interior Salt Basins, Central and Eastern Gulf of Mexico  

SciTech Connect (OSTI)

The principal research effort for Phase 1 (Concept Development) of the project has been data compilation; determination of the tectonic, depositional, burial, and thermal maturation histories of the North Louisiana Salt Basin; basin modeling (geohistory, thermal maturation, hydrocarbon expulsion); petroleum system identification; comparative basin evaluation; and resource assessment. Existing information on the North Louisiana Salt Basin has been evaluated, an electronic database has been developed, and regional cross sections have been prepared. Structure, isopach and formation lithology maps have been constructed, and burial history, thermal maturation history, and hydrocarbon expulsion profiles have been prepared. Seismic data, cross sections, subsurface maps and burial history, thermal maturation history, and hydrocarbon expulsion profiles have been used in evaluating the tectonic, depositional, burial and thermal maturation histories of the basin. Oil and gas reservoirs have been found to be associated with salt-supported anticlinal and domal features (salt pillows, turtle structures and piercement domes); with normal faulting associated with the northern basin margin and listric down-to-the-basin faults (state-line fault complex) and faulted salt features; and with combination structural and stratigraphic features (Sabine and Monroe Uplifts) and monoclinal features with lithologic variations. Petroleum reservoirs include Upper Jurassic and Cretaceous fluvial-deltaic sandstone facies; shoreline, marine bar and shallow shelf sandstone facies; and carbonate shoal, shelf and reef facies. Cretaceous unconformities significantly contribute to the hydrocarbon trapping mechanism capacity in the North Louisiana Salt Basin. The chief petroleum source rock in this basin is Upper Jurassic Smackover lime mudstone beds. The generation of hydrocarbons from Smackover lime mudstone was initiated during the Early Cretaceous and continued into the Tertiary. Hydrocarbon expulsion commenced during the Early Cretaceous and continued into the Tertiary with peak expulsion occurring during the Early to Late Cretaceous. The geohistory of the North Louisiana Salt Basin is comparable to the Mississippi Interior Salt Basin with the major difference being the elevated heat flow the strata in the North Louisiana Salt Basin experienced in the Cretaceous due primarily to reactivation of upward movement, igneous activity, and erosion associated with the Monroe and Sabine Uplifts. Potential undiscovered reservoirs in the North Louisiana Salt Basin are Triassic Eagle Mills sandstone and deeply buried Upper Jurassic sandstone and limestone. Potential underdeveloped reservoirs include Lower Cretaceous sandstone and limestone and Upper Cretaceous sandstone.

Ernest A. Mancini; Paul Aharon; Donald A. Goddard; Roger Barnaby

2006-05-26T23:59:59.000Z

15

Batteries using molten salt electrolyte  

DOE Patents [OSTI]

An electrolyte system suitable for a molten salt electrolyte battery is described where the electrolyte system is a molten nitrate compound, an organic compound containing dissolved lithium salts, or a 1-ethyl-3-methlyimidazolium salt with a melting temperature between approximately room temperature and approximately 250.degree. C. With a compatible anode and cathode, the electrolyte system is utilized in a battery as a power source suitable for oil/gas borehole applications and in heat sensors.

Guidotti, Ronald A. (Albuquerque, NM)

2003-04-08T23:59:59.000Z

16

E-Print Network 3.0 - aqueous nitrate solutions Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Biology and Medicine 23 Evaluation for Biological Reduction of Nitrate and Perchlorate in Brine Water Using Summary: in high salt solution. One culture was capable of reducing up...

17

BASIN ANALYSIS AND PETROLEUM SYSTEM CHARACTERIZATION AND MODELING, INTERIOR SALT BASINS, CENTRAL AND EASTERN GULF OF MEXICO  

SciTech Connect (OSTI)

The principal research effort for Year 2 of the project has been data compilation and the determination of the burial and thermal maturation histories of the North Louisiana Salt Basin and basin modeling and petroleum system identification. In the first nine (9) months of Year 2, the research focus was on the determination of the burial and thermal maturation histories, and during the remainder of the year the emphasis has basin modeling and petroleum system identification. Existing information on the North Louisiana Salt Basin has been evaluated, an electronic database has been developed, regional cross sections have been prepared, structure and isopach maps have been constructed, and burial history, thermal maturation history and hydrocarbon expulsion profiles have been prepared. Seismic data, cross sections, subsurface maps and related profiles have been used in evaluating the tectonic, depositional, burial and thermal maturation histories of the basin. Oil and gas reservoirs have been found to be associated with salt-supported anticlinal and domal features (salt pillows, turtle structures and piercement domes); with normal faulting associated with the northern basin margin and listric down-to-the-basin faults (state-line fault complex) and faulted salt features; and with combination structural and stratigraphic features (Sabine and Monroe Uplifts) and monoclinal features with lithologic variations. Petroleum reservoirs are mainly Upper Jurassic and Lower Cretaceous fluvial-deltaic sandstone facies and Lower Cretaceous and Upper Cretaceous shoreline, marine bar and shallow shelf sandstone facies. Cretaceous unconformities significantly contribute to the hydrocarbon trapping mechanism capacity in the North Louisiana Salt Basin. The chief petroleum source rock in this basin is Upper Jurassic Smackover lime mudstone beds. The generation of hydrocarbons from Smackover lime mudstone was initiated during the Early Cretaceous and continued into the Tertiary. Hydrocarbon expulsion commenced during the Early Cretaceous and continued into the Tertiary with peak expulsion occurring mainly during the Late Cretaceous.

Ernest A. Mancini; Donald A. Goddard; Ronald K. Zimmerman

2005-05-10T23:59:59.000Z

18

Basin Analysis and Petroleum System Characterization and Modeling, Interior Salt Basins, Central and Eastern Gulf of Mexico  

SciTech Connect (OSTI)

The principal research effort for Year 3 of the project is basin modeling and petroleum system identification, comparative basin evaluation and resource assessment. In the first six (6) months of Year 3, the research focus is on basin modeling and petroleum system identification and the remainder of the year the emphasis is on the comparative basin evaluation and resource assessment. No major problems have been encountered to date, and the project is on schedule. The principal objectives of the project are to develop through basin analysis and modeling the concept that petroleum systems acting in a basin can be identified through basin modeling and to demonstrate that the information and analysis resulting from characterizing and modeling of these petroleum systems in the North Louisiana Salt Basin and the Mississippi Interior Salt Basin can be used in providing a more reliable and advanced approach for targeting stratigraphic traps and specific reservoir facies within a geologic system and in providing a refined assessment of undiscovered and underdeveloped reservoirs and associated oil and gas resources.

Ernest A. Mancini; Paul Aharon; Donald A. Goddard; Roger Barnaby

2006-02-28T23:59:59.000Z

19

Molten Salt Test Loop (MSTL) system customer interface document.  

SciTech Connect (OSTI)

The National Solar Thermal Test Facility at Sandia National Laboratories has a unique test capability called the Molten Salt Test Loop (MSTL) system. MSTL is a test capability that allows customers and researchers to test components in flowing, molten nitrate salt. The components tested can range from materials samples, to individual components such as flex hoses, ball joints, and valves, up to full solar collecting systems such as central receiver panels, parabolic troughs, or linear Fresnel systems. MSTL provides realistic conditions similar to a portion of a concentrating solar power facility. The facility currently uses 60/40 nitrate %E2%80%9Csolar salt%E2%80%9D and can circulate the salt at pressure up to 40 bar (600psi), temperature to 585%C2%B0C, and flow rate of 44-50kg/s(400-600GPM) depending on temperature. The purpose of this document is to provide a basis for customers to evaluate the applicability to their testing needs, and to provide an outline of expectations for conducting testing on MSTL. The document can serve as the basis for testing agreements including Work for Others (WFO) and Cooperative Research and Development Agreements (CRADA). While this document provides the basis for these agreements and describes some of the requirements for testing using MSTL and on the site at Sandia, the document is not sufficient by itself as a test agreement. The document, however, does provide customers with a uniform set of information to begin the test planning process.

Gill, David Dennis; Kolb, William J.; Briggs, Ronald D.

2013-09-01T23:59:59.000Z

20

Customer interface document for the Molten Salt Test Loop (MSTL) system.  

SciTech Connect (OSTI)

The National Solar Thermal Test Facility at Sandia National Laboratories has a unique test capability called the Molten Salt Test Loop (MSTL) system. MSTL is a test capability that allows customers and researchers to test components in flowing, molten nitrate salt. The components tested can range from materials samples, to individual components such as flex hoses, ball joints, and valves, up to full solar collecting systems such as central receiver panels, parabolic troughs, or linear Fresnel systems. MSTL provides realistic conditions similar to a portion of a concentrating solar power facility. The facility currently uses 60/40 nitrate 'solar salt' and can circulate the salt at pressure up to 600psi, temperature to 585 C, and flow rate of 400-600GPM depending on temperature. The purpose of this document is to provide a basis for customers to evaluate the applicability to their testing needs, and to provide an outline of expectations for conducting testing on MSTL. The document can serve as the basis for testing agreements including Work for Others (WFO) and Cooperative Research and Development Agreements (CRADA). While this document provides the basis for these agreements and describes some of the requirements for testing using MSTL and on the site at Sandia, the document is not sufficient by itself as a test agreement. The document, however, does provide customers with a uniform set of information to begin the test planning process.

Pettit, Kathleen; Kolb, William J.; Gill, David Dennis; Briggs, Ronald D.

2012-03-01T23:59:59.000Z

Note: This page contains sample records for the topic "nitrate salt central" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Molten salt lithium cells  

DOE Patents [OSTI]

Lithium-based cells are promising for applications such as electric vehicles and load-leveling for power plants since lithium is very electropositive and light weight. One type of lithium-based cell utilizes a molten salt electrolyte and is operated in the temperature range of about 400.degree.-500.degree. C. Such high temperature operation accelerates corrosion problems and a substantial amount of energy is lost through heat transfer. The present invention provides an electrochemical cell (10) which may be operated at temperatures between about 100.degree.-170.degree. C. Cell (10) comprises an electrolyte (16), which preferably includes lithium nitrate, and a lithium or lithium alloy electrode (12).

Raistrick, Ian D. (Menlo Park, CA); Poris, Jaime (Portola Valley, CA); Huggins, Robert A. (Stanford, CA)

1982-02-09T23:59:59.000Z

22

Molten salt lithium cells  

DOE Patents [OSTI]

Lithium-based cells are promising for applications such as electric vehicles and load-leveling for power plants since lithium is very electropositive and light weight. One type of lithium-based cell utilizes a molten salt electrolyte and is operated in the temperature range of about 400.degree.-500.degree. C. Such high temperature operation accelerates corrosion problems and a substantial amount of energy is lost through heat transfer. The present invention provides an electrochemical cell (10) which may be operated at temperatures between about 100.degree.-170.degree. C. Cell (10) comprises an electrolyte (16), which preferably includes lithium nitrate, and a lithium or lithium alloy electrode (12).

Raistrick, Ian D. (Menlo Park, CA); Poris, Jaime (Portola Valley, CA); Huggins, Robert A. (Stanford, CA)

1983-01-01T23:59:59.000Z

23

Molten salt lithium cells  

DOE Patents [OSTI]

Lithium-based cells are promising for applications such as electric vehicles and load-leveling for power plants since lithium is very electropositive and light weight. One type of lithium-based cell utilizes a molten salt electrolyte and is operated in the temperature range of about 400 to 500/sup 0/C. Such high temperature operation accelerates corrosion problems and a substantial amount of energy is lost through heat transfer. The present invention provides an electrochemical cell which may be operated at temperatures between about 100 to 170/sup 0/C. The cell is comprised of an electrolyte, which preferably includes lithium nitrate, and a lithium or lithium alloy electrode.

Raistrick, I.D.; Poris, J.; Huggins, R.A.

1980-07-18T23:59:59.000Z

24

Structural and stratigraphic evolution of the central Mississippi Canyon Area: interaction of salt tectonics and slope processes in the formation of engineering and geologic hazards  

E-Print Network [OSTI]

. The analysis focused on salt tectonics and sequence stratigraphy to develop a geologic model for the study area and its potential impact on engineering and geologic hazards. Salt in the study area was found to be established structural end-members derived from...

Brand, John Richard

2006-04-12T23:59:59.000Z

25

Thermochemical nitrate destruction  

DOE Patents [OSTI]

A method is disclosed for denitrification of nitrates and nitrates present in aqueous waste streams. The method comprises the steps of (1) identifying the concentration nitrates and nitrites present in a waste stream, (2) causing formate to be present in the waste stream, (3) heating the mixture to a predetermined reaction temperature from about 200.degree. C. to about 600.degree. C., and (4) holding the mixture and accumulating products at heated and pressurized conditions for a residence time, thereby resulting in nitrogen and carbon dioxide gas, and hydroxides, and reducing the level of nitrates and nitrites to below drinking water standards.

Cox, John L. (Richland, WA); Hallen, Richard T. (Richland, WA); Lilga, Michael A. (Richland, WA)

1992-01-01T23:59:59.000Z

26

Thermochemical nitrate destruction  

DOE Patents [OSTI]

A method is disclosed for denitrification of nitrates and nitrites present in aqueous waste streams. The method comprises the steps of (1) identifying the concentration nitrates and nitrites present in a waste stream, (2) causing formate to be present in the waste stream, (3) heating the mixture to a predetermined reaction temperature from about 200 C to about 600 C, and (4) holding the mixture and accumulating products at heated and pressurized conditions for a residence time, thereby resulting in nitrogen and carbon dioxide gas, and hydroxides, and reducing the level of nitrates and nitrites to below drinking water standards.

Cox, J.L.; Hallen, R.T.; Lilga, M.A.

1992-06-02T23:59:59.000Z

27

Drinking Water Problems: Nitrates  

E-Print Network [OSTI]

. 7). Nitrate ions are drawn through the membrane pores with elec- trical currents. The nitrate is pulled from the water into a brine waste stream. Ni trate-contaminated water Treated water Nitrate Chloride or hydroxide Exchange resin Figure 6. Ion... and Extension Agricultural Engineer, Texas Cooperative Extension, The Texas A&M University System B-6184 3-08 ' the safe levels of chemicals for U.S. drinking water. The EPA conducts research to determine the level of a contaminant in drinking water...

Dozier, Monty; Melton, Rebecca; Hare, Michael; Hopkins, Janie; Lesikar, Bruce J.

2008-03-28T23:59:59.000Z

28

Solar central receiver technology: the Solar Two Project  

SciTech Connect (OSTI)

Solar Two will be the world`s largest operating solar central receiver power plant. It is expected to begin operating in April 1996; it is currently undergoing start-up and checkout. The plant will use sunlight reflected from 1926 sun-tracking mirrors to heat molten nitrate salt flowing in a heat exchanger (receiver) that sits atop a 200 foot tower. The heated salt will be stored in a tank for use, when needed, to generate superheated steam for producing electricity with a conventional Rankine-cycle turbine/generator. The purpose of the project is to validate molten-salt solar central receiver technology and to reduce the perceived risks associated with the first full-scale commercial plants. Already, much has been learned during the project including the effects of trace contaminants in the salt and the large effect of wind on the receiver. There is also much that remains to be learned. This report describes the technical status of the Solar Two project including a summary of lessons learned to date.

Sutherland, J.P. [Southern California Edison Co., Irwindale, CA (United States)

1996-05-01T23:59:59.000Z

29

NITRATE DESTRUCTION LITERATURE SURVEY AND EVALUATION CRITERIA  

SciTech Connect (OSTI)

This report satisfies the initial phase of Task WP-2.3.4 Alternative Sodium Recovery Technology, Subtask 1; Develop Near-Tank Nitrate/Nitrite Destruction Technology. Some of the more common anions in carbon steel waste tanks at SRS and Hanford Site are nitrate which is corrosive, and nitrite and hydroxide which are corrosion inhibitors. At present it is necessary to periodically add large quantities of 50 wt% caustic to waste tanks. There are three primary reasons for this addition. First, when the contents of salt tanks are dissolved, sodium hydroxide preferentially dissolves and is removed. During the dissolution process the concentration of free hydroxide in the tank liquid can decrease from 9 M to less than 0.2 M. As a result, roughly half way through the dissolution process large quantities of sodium hydroxide must be added to the tank to comply with requirements for corrosion control. Second, hydroxide is continuously consumed by reaction with carbon dioxide which occurs naturally in purge air used to prevent buildup of hydrogen gas inside the tanks. The hydrogen is generated by radiolysis of water. Third, increasing the concentration of hydroxide increases solubility of some aluminum compounds, which is desirable in processing waste. A process that converts nitrate and nitrite to hydroxide would reduce certain costs. (1) Less caustic would be purchased. (2) Some of the aluminum solid compounds in the waste tanks would become more soluble so less mass of solids would be sent to High Level Vitrification and therefore it would be not be necessary to make as much expensive high level vitrified product. (3) Less mass of sodium would be fed to Saltstone at SRS or Low Level Vitrification at Hanford Site so it would not be necessary to make as much low level product. (4) At SRS less nitrite and nitrate would be sent to Defense Waste Processing Facility (DWPF) so less formic acid would be consumed there and less hydrogen gas would be generated. This task involves literature survey of technologies to perform the nitrate to hydroxide conversion, selection of the most promising technologies, preparation of a flowsheet and design of a system. The most promising technologies are electrochemical reduction of nitrates and chemical reduction with hydrogen or ammonia. The primary reviewed technologies are listed and they aredescribed in more detail later in the report: (1) Electrochemical destruction; (2) Chemical reduction with agents such as ammonia, hydrazine or hydrogen; (3) Hydrothermal reduction process; and (4) Calcination. Only three of the technologies on the list have been demonstrated to generate usable amounts of caustic; electrochemical reduction and chemical reduction with ammonia, hydrazine or hydrogen and hydrothermal reduction. Chemical reduction with an organic reactant such as formic acid generates carbon dioxide which reacts with caustic and is thus counterproductive. Treatment of nitrate with aluminum or other active metals generates a solid product. High temperature calcination has the potential to generate sodium oxide which may be hydrated to sodium hydroxide, but this is unproven. The following criteria were developed to evaluate the most suitable option. The numbers in brackets after the criteria are relative weighting factors to account for importance: (1) Personnel exposure to radiation for installation, routine operation and maintenance; (2) Non-radioactive safety issues; (3) Whether the technology generates caustic and how many moles of caustic are generated per mole of nitrate plus nitrite decomposed; (4) Whether the technology can handle nitrate and nitrite at the concentrations encountered in waste; (5) Maturity of technology; (6) Estimated annual cost of operation (labor, depreciation, materials, utilities); (7) Capital cost; (8) Selectivity to nitrogen as decomposition product (other products are flammable and/or toxic); (9) Impact of introduced species; (10) Selectivity for destruction of nitrate vs. nitrite; and (11) Cost of deactivation and demolition. Each technology was given a score from one

Steimke, J.

2011-02-01T23:59:59.000Z

30

A final report on the Phase 1 testing of a molten-salt cavity receiver  

SciTech Connect (OSTI)

This report describes the design, construction, and testing of a solar central receiver using molten nitrate salt as a heat exchange fluid. Design studies for large commercial plants (30--100 MWe) have shown molten salt to be an excellent fluid for solar thermal plants as it allows for efficient thermal storage. Plant design studies concluded that an advanced receiver test was required to address uncertainties not covered in prior receiver tests. This recommendation led to the current test program managed by Sandia National Laboratories for the US Department of Energy. The 4.5 MWt receiver is installed at Sandia National Laboratories' Central Receiver Test Facility in Albuquerque, New Mexico. The receiver incorporates features of large commercial receiver designs. This report describes the receiver's configuration, heat absorption surface (design and sizing), the structure and supporting systems, and the methods for control. The receiver was solar tested during a six-month period at the Central Receiver Test Facility in Albuquerque, NM. The purpose of the testing was to characterize the operational capabilities of the receiver under a number of solar operating and stand-by conditions. This testing consisted of initial check-out of the systems, followed by steady-state performance, transient receiver operation, receiver operation in clouds, receiver thermal loss testing, receiver start-up operation, and overnight thermal conditioning tests. This report describes the design, fabrication, and results of testing of the receiver.

Chavez, J M [ed.; Sandia National Labs., Albuquerque, NM (United States); Smith, D C [Babcock and Wilcox Co., Barberton, OH (United States). Nuclear Equipment Div.

1992-05-01T23:59:59.000Z

31

Purification of alkali metal nitrates  

DOE Patents [OSTI]

A process is disclosed for removing heavy metal contaminants from impure alkali metal nitrates containing them. The process comprises mixing the impure nitrates with sufficient water to form a concentrated aqueous solution of the impure nitrates, adjusting the pH of the resulting solution to within the range of between about 2 and about 7, adding sufficient reducing agent to react with heavy metal contaminants within said solution, adjusting the pH of the solution containing reducing agent to effect precipitation of heavy metal impurities and separating the solid impurities from the resulting purified aqueous solution of alkali metal nitrates. The resulting purified solution of alkali metal nitrates may be heated to evaporate water therefrom to produce purified molten alkali metal nitrate suitable for use as a heat transfer medium. If desired, the purified molten form may be granulated and cooled to form discrete solid particles of alkali metal nitrates.

Fiorucci, Louis C. (Hamden, CT); Gregory, Kevin M. (Woodridge, IL)

1985-05-14T23:59:59.000Z

32

Nitrate Salt Bearing Transuranic Waste Container Monitoring | Department of  

Office of Environmental Management (EM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "of EnergyEnergyENERGY TAXBalanced Scorecard Federal2EnergyDepartment ofNews NewsNick Sinai

33

Waste Isolation Pilot Plant Nitrate Salt Bearing Waste Container  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear SecurityTensile Strain Switched Ferromagnetism inS-4500IIVasudhaSurface.Laboratory30,WP-073.99 4.22Primary

34

THERMODYNAMIC PROPERTIES OF MOLTEN NITRATE SALTS Joseph G. Cordaro  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security AdministrationcontrollerNanocrystallineForeign Object DamageSystemsU.S. TALKS1THE WHITE 9086

35

Thermal Decomposition of Nitrated Tributyl Phosphate  

SciTech Connect (OSTI)

Contact between tributyl phosphate and aqueous solutions of nitric acid and/or heavy metal nitrate salts at elevated temperatures can lead to exothermic reactions of explosive violence. Even though such operations have been routinely performed safely for decades as an intrinsic part of the Purex separation processes, several so-called ``red oil`` explosions are known to have occurred in the United States, Canada, and the former Soviet Union. The most recent red oil explosion occurred at the Tomsk-7 separations facility in Siberia, in April 1993. That explosion destroyed part of the unreinforced masonry walls of the canyon-type building in which the process was housed, and allowed the release of a significant quantity of radioactive material.

Paddleford, D.F. [Westinghouse Savannah River Company, Aiken, SC (United States); Hou, Y.; Barefield, E.K.; Tedder, D.W.; Abdel-Khalik, S.I. [Georgia Institute of Technology, GA (United States)

1995-01-01T23:59:59.000Z

36

Stainless steel corrosion by molten nitrates : analysis and lessons learned.  

SciTech Connect (OSTI)

A secondary containment vessel, made of stainless 316, failed due to severe nitrate salt corrosion. Corrosion was in the form of pitting was observed during high temperature, chemical stability experiments. Optical microscopy, scanning electron microscopy and energy dispersive spectroscopy were all used to diagnose the cause of the failure. Failure was caused by potassium oxide that crept into the gap between the primary vessel (alumina) and the stainless steel vessel. Molten nitrate solar salt (89% KNO{sub 3}, 11% NaNO{sub 3} by weight) was used during chemical stability experiments, with an oxygen cover gas, at a salt temperature of 350-700 C. Nitrate salt was primarily contained in an alumina vessel; however salt crept into the gap between the alumina and 316 stainless steel. Corrosion occurred over a period of approximately 2000 hours, with the end result of full wall penetration through the stainless steel vessel; see Figures 1 and 2 for images of the corrosion damage to the vessel. Wall thickness was 0.0625 inches, which, based on previous data, should have been adequate to avoid corrosion-induced failure while in direct contact with salt temperature at 677 C (0.081-inch/year). Salt temperatures exceeding 650 C lasted for approximately 14 days. However, previous corrosion data was performed with air as the cover gas. High temperature combined with an oxygen cover gas obviously drove corrosion rates to a much higher value. Corrosion resulted in the form of uniform pitting. Based on SEM and EDS data, pits contained primarily potassium oxide and potassium chromate, reinforcing the link between oxides and severe corrosion. In addition to the pitting corrosion, a large blister formed on the side wall, which was mainly composed of potassium, chromium and oxygen. All data indicated that corrosion initiated internally and moved outward. There was no evidence of intergranular corrosion nor were there any indication of fast pathways along grain boundaries. Much of the pitting occurred near welds; however this was the hottest region in the chamber. Pitting was observed up to two inches above the weld, indicating independence from weld effects.

Kruizenga, Alan Michael

2011-09-01T23:59:59.000Z

37

Salt Waste Processing Initiatives  

Office of Environmental Management (EM)

1 Patricia Suggs Salt Processing Team Lead Assistant Manager for Waste Disposition Project Office of Environmental Management Savannah River Site Salt Waste Processing Initiatives...

38

Nitrate and Prussic Acid Poisoning  

E-Print Network [OSTI]

Nitrate and prussic acid poisoning in cattle are noninfectious conditions that can kill livestock. This publication explains the causes and symptoms of these conditions as well as preventive measures and sampling and testing steps....

Stichler, Charles; Reagor, John C.

2001-09-05T23:59:59.000Z

39

Thermal decomposition of nitrated tributyl phosphate  

SciTech Connect (OSTI)

Extended contact between heated mixtures of tri-n-butyl phosphate (TBP) and aqueous solutions of nitric acid and/or heavy metal nitrate salts at elevated temperatures can lead to exothermic reactions of explosive violence. Most solvent extraction operations are conducted at ambient conditions without heating TBP and have been performed safely for decades, but several explosions involving TBP have occurred in the US, Canada, and the former Soviet Union. This investigation was undertaken to characterize the products of thermal decomposition of both single- and two-phase mixtures of TBP, nitric acid, and water under a variety of conditions. The data indicate that the extent of reaction and the rate of gaseous product formation are affected by the presence of Zr{sup 4+}, distillation compared with reflux conditions, temperature, water/HNO{sub 3} and HNO{sub 3}/TBP ratios, and whether the decomposition occurs under constant pressure or constant volume conditions. Higher reaction temperatures accelerate the rate of decomposition, but the extent of decomposition, as measured by the quantity of gaseous products, was greater at lower temperatures when the decomposition was performed under distillation conditions. Higher gas production occurs under reflux conditions, lower H{sub 2}O/HNO{sub 3} ratios, and when a separate water-HNO{sub 3} phase is initially present. The major gaseous products include N{sub 2}, CO, CO{sub 2}, NO, and N{sub 2}O. Measurable amounts of NO{sub 2} were not present in the final product mixture, although an orange color suggesting the presence of NO{sub 2} was observed in the early stages of decomposition. The major liquid products were dibutyl phosphoric acid, butyl nitrate, and water. Small amounts of C{sub 1}-C{sub 4} carboxylic acids were also present. Because of the small sample sizes that were employed and the isothermal conditions of the decomposition, runaway reactions were not observed. Some possible reaction pathways are considered.

Hou, Y.; Barefield, E.K.; Tedder, D.W.; Abdel-Khalik, S.I. [Georgia Inst. of Technology, Atlanta, GA (United States)

1996-03-01T23:59:59.000Z

40

Modified phosphate ceramics for stabilization and solidification of salt mixed wastes.  

SciTech Connect (OSTI)

Novel chemically bonded phosphate ceramics have been investigated for stabilization and solidification of chloride and nitrate salt wastes. Using low-temperature processing, we stabilized and solidified chloride and nitrate surrogate salts (with hazardous metals) in magnesium potassium phosphate ceramics up to waste loadings of 70-80 wt.%. A variety of characterizations, including strength, microstructure, and leaching, were then conducted on the waste forms. Leaching tests show that all heavy metals in the leachant are well below the EPAs universal treatment standard limits. Long-term leaching tests, per ANS 16. 1 procedure, yields leachability index for nitrate ions > 12. Chloride ions are expected to have an even higher (i.e., better) leachability index. Structural performance of these final waste forms, as indicated by compression strength and durability in aqueous environments, satisfies the regulatory criteria. Thus, based on the results of this study, it seems that phosphate ceramics are viable option for containment of salt wastes.

Singh, D.

1998-06-26T23:59:59.000Z

Note: This page contains sample records for the topic "nitrate salt central" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Process for reducing aqueous nitrate to ammonia  

DOE Patents [OSTI]

Powdered aluminum is added to a nitrate-containing alkaline, aqueous solution to reduce the nitrate and/or nitrite to ammonia and co-produce a sinterable ceramic product.

Mattus, Alfred J. (Oak Ridge, TN)

1993-01-01T23:59:59.000Z

42

Aksaray And Ecemis Faults - Diapiric Salt Relationships- Relevance...  

Open Energy Info (EERE)

To The Hydrocarbon Exploration In The Tuz Golu (Salt Lake) Basin, Central Anatolia, Turkey Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article:...

43

A Novel Chemical Nitrate Destruction Process  

SciTech Connect (OSTI)

Nitrates represent one of the most significant pollutant discharged to the Baltic Sea by the Sliiamae hydrometallurgical plant. This article contains a brief overview of the existing nitrate destruction technologies followed by the description of a new process developed by the authors. The new chemical process for nitrate destruction is cost effective and simple to operate. It converts the nitrate to nitrogen gas which goes to the atmosphere.

Dziewinski, J.; Marczak, S.

1999-03-01T23:59:59.000Z

44

Effect of calcium nitrate on the vapor-liquid equilibria of ethanol + water and 2-propanol + water  

SciTech Connect (OSTI)

The effect of calcium nitrate on the vapor-liquid equilibria of ethanol + water and 2-propanol + water was studied using a Swietoslawski ebulliometer. The measurements were performed for two constant salt molalities (1 and 2 mol[center dot]kg[sup [minus]1]) under isobaric conditions at 50.66 kPa. Strong salting-out of the alcohol was observed in all cases, leading to a complete elimination of the azeotropic point at relatively low salt concentrations. The results were correlated using an extension of the NRTL equation for mixed solvent electrolyte systems proposed by Mock, Evans, and Chen.

Polka, H.M.; Gmehling, J. (Univ. of Oldenburg (Germany). Chair of Industrial Chemistry)

1994-07-01T23:59:59.000Z

45

Mixed Waste Salt Encapsulation Using Polysiloxane - Final Report  

SciTech Connect (OSTI)

A proof-of-concept experimental study was performed to investigate the use of Orbit Technologies polysiloxane grouting material for encapsulation of U.S. Department of Energy mixed waste salts leading to a final waste form for disposal. Evaporator pond salt residues and other salt-like material contaminated with both radioactive isotopes and hazardous components are ubiquitous in the DOE complex and may exceed 250,000,000 kg of material. Current treatment involves mixing low waste percentages (less than 10% by mass salt) with cement or costly thermal treatment followed by cementation to the ash residue. The proposed technology involves simple mixing of the granular salt material (with relatively high waste loadings-greater than 50%) in a polysiloxane-based system that polymerizes to form a silicon-based polymer material. This study involved a mixing study to determine optimum waste loadings and compressive strengths of the resultant monoliths. Following the mixing study, durability testing was performed on promising waste forms. Leaching studies including the accelerated leach test and the toxicity characteristic leaching procedure were also performed on a high nitrate salt waste form. In addition to this testing, the waste form was examined by scanning electron microscope. Preliminary cost estimates for applying this technology to the DOE complex mixed waste salt problem is also given.

Miller, C.M.; Loomis, G.G.; Prewett, S.W.

1997-11-01T23:59:59.000Z

46

Molten salt electrolyte separator  

DOE Patents [OSTI]

The patent describes a molten salt electrolyte/separator for battery and related electrochemical systems including a molten electrolyte composition and an electrically insulating solid salt dispersed therein, to provide improved performance at higher current densities and alternate designs through ease of fabrication. 5 figs.

Kaun, T.D.

1996-07-09T23:59:59.000Z

47

The nitrate to ammonia and ceramic (NAC) process -- a newly developed low-temperature technology  

SciTech Connect (OSTI)

Bench-top feasibility studies with Hanford single-shell tank (SST) simulants, using a new low-temperature (50-60C) process for converting nitrate to ammonia and ceramic (NAC), showed that between 90 and 99% of the nitrate at Hanford can be readily converted to ammonia. Aluminum powders or shot can be used to convert alkaline, nitrate-based supernate to ammonia and an alumina-silica-based ceramic solid. The process may utilize already contaminated aluminum scrap metal from various DOE sites to effect the conversion. The final nitrate-free ceramic product can be calcined, pressed, and sintered like any other ceramic. Based on starting volumes of 6.2 and 3.1 M sodium nitrate solution (probable supernate concentrations resulting from salt-cake/sludge removal from Hanford SSTs), volume reductions as high as 70% are currently obtained, compared with an expected 40 to 50% volume increase if the Hanford supernate were grouted. Engineering data indicate that the process will be very economical. Data were used to cost a batch facility with a production rate of 1200 kilograms of nitrate per hour for processing all the Hanford SST waste over 20 years. Process cost analysis indicates that between $2.01 and 2.66 will be required to convert each kilogram of nitrate. These costs are one-third to one-half of the processing costs for electrolytic and thermal processes. The ceramic waste form offers other cost savings associated with a smaller volume of waste as well as eliminates other process steps such as grouting. Silica added to the reactor, based upon the total sodium in the waste, permits us to actually bind the sodium in a nepheline phase of the final ceramic structure as well as bind most metals and nonmetals in the ceramic.

Mattus, A.J.; Lee, D.D.

1993-06-01T23:59:59.000Z

48

Nitrate Enhanced Microbial Cr(VI) Reduction-Final Report  

SciTech Connect (OSTI)

A major challenge for the bioremediation of radionuclides (i.e., uranium, technetium) and metals (i.e., Cr(VI), Hg) is the co-occurrence of nitrate as it can inhibit metal transformation. Denitrification (nitrate reduction to dinitrogen gas) is considered the most important ecological process. For many metal and metalloid reducing bacteria, however, ammonia is the end product through respiratory nitrate reduction (RNRA). The focus of this work was to determine how RNRA impacts Cr(VI) transformation. The goal was to elucidate the specific mechanism(s) that limits Cr(VI) reduction in the presence of nitrate and to use this information to develop strategies that enhance Cr(VI) reduction (and thus detoxification). Our central hypothesis is that nitrate impacts the biotransformation of metals and metalloids in three ways 1) as a competitive alternative electron acceptor (inhibiting transformation), 2) as a co-metabolite (i.e., concomitant reduction, stimulating transformation), and 3) as an inducer of specific proteins and pathways involved in oxidation/reduction reactions (stimulating transformation). We have identified three model organisms, Geobacter metallireducens (mechanism 1), Sulfurospirillum barnesii, (mechasism 2), and Desulfovibrio desulfuricans (mechanisms 3). Our specific aims were to 1) investigate the role of Cr(VI) concentration on the kinetics of both growth and reduction of nitrate, nitrite, and Cr(VI) in these three organisms; 2) develop a profile of bacterial enzymes involved in nitrate transformation (e.g., oxidoreductases) using a proteomic approach; 3) investigate the function of periplasmic nitrite reductase (Nrf) as a chromate reductase; and 4) develop a strategy to maximize microbial chromium reduction in the presence of nitrate. We found that growth on nitrate by G. metallireducens was inhibited by Cr(VI). Over 240 proteins were identified by LC/MS-MS. Redox active proteins, outer membrane heavy metal efflux proteins, and chemotaxis sensory proteins (Gmet_2478 and Gmet_1641) were up-regulated with exposure to Cr(VI). A nine-heme cytochrome C was purified that could reduce nitrite and could be oxidized by Cr(VI). For D. desulfuricans, we found that confirmed that Cr(VI) induced a prolonged lag period when Cr(VI) was reduced. Over three hundred proteins were unequivocally identified by LC/MS-MS and a significant number of down-regulated proteins for which the levels were changed >2 fold compared to control. Sulfite reductase levels were similar, however, nitrate and nitrite reductase were down-regulated. The supernatant of spent cultures was found to contain a filterable, heat stable compound that rapidly reduced Cr(VI). In addition, desulfoviridin was purified from nitrate grown cells and shown to have nitrite reductase activity that was inhibited by Cr(VI). For S. barnesii, periplasmic nitrate reductase (Nap), nitrite reductase (Nrf), and the metalloid reductase (Rar) were purified and characterized. The supernatant of spent cultures was also found to contain a filterable, heat stable compound that rapidly reduced Cr(VI) but that Rar also reduced Cr(VI). Our results from specific aims 1 through 3 indicate that for G. metallireducens, Cr(VI) inhibits nitrate respiration as it oxidizes cytochromes involved in nitrate respiration. Iron reduction is apparently not affected and the inhibitory affects of Cr(VI) may be attenuated by the addition of sufficient Fe(III) to generate Fe(II) that abiotically reduces the chromium. For S. barnesii, although the enzyme assays indicate that the components of the respiratory pathway for nitrate (e.g. Nap and Nrf) are inhibited by chromate, the organism has a mechanism to prevent this from actually occurring. Our current hypothesis is that the non-specific metalloid reductase (Rar) is providing resistance by reducing the Cr(VI). The strategy here would be to enhance its growth and metabolism in the natural setting. Lactate is a suitable electron donor for S. barnesii but other donors are possible. Although the version of the Phylochip used for monitoring the microb

John F. Stolz

2011-06-15T23:59:59.000Z

49

Nitrates and Prussic Acid in Forages  

E-Print Network [OSTI]

When nitrates and prussic acid accumulate in forage, the feed may not be safe for livestock consumption. Learn the symptoms of nitrate and prussic acid poisoning and which plants are most likely to pose a risk to livestock. Also learn sampling...

Provin, Tony; Pitt, John L.

2003-01-06T23:59:59.000Z

50

Amine salts of nitroazoles  

DOE Patents [OSTI]

Compositions of matter, a method of providing chemical energy by burning said compositions, and methods of making said compositions are described. These compositions are amine salts of nitroazoles. 1 figure.

Kienyin Lee; Stinecipher, M.M.

1993-10-26T23:59:59.000Z

51

Atomic structure of nitrate-binding protein crucial for photosynthetic...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

structure of nitrate-binding protein crucial for photosynthetic productivity. Atomic structure of nitrate-binding protein crucial for photosynthetic productivity. Abstract:...

52

Report seeks solutions for nitrate in drinking water  

E-Print Network [OSTI]

Nitrate in California’s Drinking Water report http://Clark Report seeks solutions for nitrate in drinking waternitrate contamination of drinking water in high-risk areas

Editors, By

2012-01-01T23:59:59.000Z

53

Effect of the TBP and Water on the Complexation of Uranyl Nitrate and the Dissolution of Nitric Acid into Supercritical CO2. A Theoretical Study  

E-Print Network [OSTI]

started from "random" mixtures of water, TBP, nitric acid, and uranyl nitrate, complexation of uranyl to dissolve nitric acid in the supercritical phase. Indeed, without TBP, nitric acid alone self aggregates via containing the acid and uranyl salts. The simulations show that a high TBP/nitric acid ratio is needed

Boyer, Edmond

54

Fundamental Properties of Salts  

SciTech Connect (OSTI)

Thermal properties of molten salt systems are of interest to electrorefining operations, pertaining to both the Fuel Cycle Research & Development Program (FCR&D) and Spent Fuel Treatment Mission, currently being pursued by the Department of Energy (DOE). The phase stability of molten salts in an electrorefiner may be adversely impacted by the build-up of fission products in the electrolyte. Potential situations that need to be avoided, during electrorefining operations, include (i) fissile elements build up in the salt that might approach the criticality limits specified for the vessel, (ii) electrolyte freezing at the operating temperature of the electrorefiner due to changes in the liquidus temperature, and (iii) phase separation (non-homogenous solution). The stability (and homogeneity) of the phases can be monitored by studying the thermal characteristics of the molten salts as a function of impurity concentration. Simulated salt compositions consisting of the selected rare earth and alkaline earth chlorides, with a eutectic mixture of LiCl-KCl as the carrier electrolyte, were studied to determine the melting points (thermal characteristics) using a Differential Scanning Calorimeter (DSC). The experimental data were used to model the liquidus temperature. On the basis of the this data, it became possible to predict a spent fuel treatment processing scenario under which electrorefining could no longer be performed as a result of increasing liquidus temperatures of the electrolyte.

Toni Y Gutknecht; Guy L Fredrickson

2012-11-01T23:59:59.000Z

55

Process for the preparation of an energetic nitrate ester  

DOE Patents [OSTI]

A process for the preparation of an energetic nitrate ester compound and related intermediates is provided.

Chavez, David E; Naud, Darren L; Hiskey, Michael A

2013-12-17T23:59:59.000Z

56

Gas releases from salt  

SciTech Connect (OSTI)

The occurrence of gas in salt mines and caverns has presented some serious problems to facility operators. Salt mines have long experienced sudden, usually unexpected expulsions of gas and salt from a production face, commonly known as outbursts. Outbursts can release over one million cubic feet of methane and fractured salt, and are responsible for the lives of numerous miners and explosions. Equipment, production time, and even entire mines have been lost due to outbursts. An outburst creates a cornucopian shaped hole that can reach heights of several hundred feet. The potential occurrence of outbursts must be factored into mine design and mining methods. In caverns, the occurrence of outbursts and steady infiltration of gas into stored product can effect the quality of the product, particularly over the long-term, and in some cases renders the product unusable as is or difficult to transport. Gas has also been known to collect in the roof traps of caverns resulting in safety and operational concerns. The intent of this paper is to summarize the existing knowledge on gas releases from salt. The compiled information can provide a better understanding of the phenomena and gain insight into the causative mechanisms that, once established, can help mitigate the variety of problems associated with gas releases from salt. Outbursts, as documented in mines, are discussed first. This is followed by a discussion of the relatively slow gas infiltration into stored crude oil, as observed and modeled in the caverns of the US Strategic Petroleum Reserve. A model that predicts outburst pressure kicks in caverns is also discussed.

Ehgartner, B.; Neal, J.; Hinkebein, T.

1998-06-01T23:59:59.000Z

57

Synthesis of a new energetic nitrate ester  

SciTech Connect (OSTI)

Nitrate esters have been known as useful energetic materials since the discovery of nitroglycerin by Ascanio Sobrero in 1846. The development of methods to increase the safety and utility of nitroglycerin by Alfred Nobel led to the revolutionary improvement in the utility of nitroglycerin in explosive applications in the form of dynamite. Since then, many nitrate esters have been prepared and incorporated into military applications such as double-based propellants, detonators and as energetic plasticizers. Nitrate esters have also been shown to have vasodilatory effects in humans and thus have been studied and used for treatments of ailments such as angina. The mechanism of the biological response towards nitrate esters has been elucidated recently. Interestingly, many of the nitrate esters used for military purposes are liquids (ethylene glycol dinitrate, propylene glycol dinitrate, etc). Pentaerythritol tetranitrate (PETN) is one of the only solid nitrate esters, besides nitrocellulose, that is used in any application. Unfortunately, PETN melting point is above 100 {sup o}C, and thus must be pressed as a solid for detonator applications. A more practical material would be a melt-castable explosive, for potential simplification of manufacturing processes. Herein we describe the synthesis of a new energetic nitrate ester (1) that is a solid at ambient temperatures, has a melting point of 85-86 {sup o}C and has the highest density of any known nitrate ester composed only of carbon, hydrogen, nitrogen and oxygen. We also describe the chemical, thermal and sensitivity properties of 1 as well as some preliminary explosive performance data.

Chavez, David E [Los Alamos National Laboratory

2008-01-01T23:59:59.000Z

58

Nitrates and detinning in canned carrots  

E-Print Network [OSTI]

NITRATES AND DETINNING IN CANNED CARROTS A Thesis by Thomas Edward Florine Submitted to the Graduate College of the Texas A&M University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE January 1968 Major... Subject: Food Technology NITRATES AND DETINNING IN CANNED CARROTS A Thesis by Thomas Edward Florine Approved as to style and content by: / C-~ (Chairman of Cemi. tee) Head of Department Member) (Member) :-'i ~ (Member) (Member) (Member...

Florine, Thomas Edward

1968-01-01T23:59:59.000Z

59

Elucidation of Mechanisms of Salinity Tolerance in Zoysia matrella Cultivars: A Study of Structure and Function of Salt Glands  

E-Print Network [OSTI]

?Diamond? and ?Cavalier?, before and after salt treatment. For salt-treated cultivars, leaves were collected after salt crystals started becoming clearly visible on the leaf surface. Leaves were fixed by exposure to 100% acrolein vapors (Electron... to four leaf blades was dipped in a 0.01 M (w/v) AgNO3 (silver nitrate) solution for 30 min. The leaves were then dipped in chloroform for 30 s and fixed in 0.1 M HEPES containing 2.5% (v/v) glutaraldehyde and 2% (v/v) acrolein. After post...

Rao, Sheetal

2012-07-16T23:59:59.000Z

60

Engineering Database of Liquid Salt Thermophysical and Thermochemical Properties  

SciTech Connect (OSTI)

The purpose of this report is to provide a review of thermodynamic and thermophysical properties of candidate molten salt coolants, which may be used as a primary coolant within a nuclear reactor or heat transport medium from the Next Generation Nuclear Plant (NGNP) to a processing plant, for example, a hydrogen-production plant. Thermodynamic properties of four types of molten salts, including LiF-BeF2 (67 and 33 mol%, respectively; also known as FLiBe), LiF-NaF-KF (46.5, 11.5, and 52 mol%, also known as FLiNaK), and KCl-MgCl2 (67 and 33 mol%), and sodium nitrate-sodium nitrite-potassium nitrate (NaNO3–NaNO2–KNO3, (7-49-44 or 7-40-53 mol%) have been investigated. Limitations of existing correlations to predict density, viscosity, specific heat capacity, surface tension, and thermal conductivity, were identified. The impact of thermodynamic properties on the heat transfer, especially Nusselt number was also discussed. Stability of the molten salts with structural alloys and their compatibility with the structural alloys was studied. Nickel and alloys with dense Ni coatings are effectively inert to corrosion in fluorides but not so in chlorides. Of the chromium containing alloys, Hastelloy N appears to have the best corrosion resistance in fluorides, while Haynes 230 was most resistant in chloride. In general, alloys with increasing carbon and chromium content are increasingly subject to corrosion by the fluoride salts FLiBe and FLiNaK, due to attack and dissolution of the intergranular chromium carbide. Future research to obtain needed information was identified.

Manohar S. Sohal; Matthias A. Ebner; Piyush Sabharwall; Phil Sharpe

2010-03-01T23:59:59.000Z

Note: This page contains sample records for the topic "nitrate salt central" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Ammoniated salt heat pump  

SciTech Connect (OSTI)

A thermochemical heat pump/energy storage system using liquid ammoniate salts is described. The system, which can be used for space heating or cooling, provides energy storage for both functions. The bulk of the energy is stored as chemical energy and thus can be stored indefinitely. The system is well suited to use with a solar energy source or industrial waste heat.

Haas, W.R.; Jaeger, F.J.; Giordano, T.J.

1981-01-01T23:59:59.000Z

62

Actinide removal from spent salts  

DOE Patents [OSTI]

A method for removing actinide contaminants (uranium and thorium) from the spent salt of a molten salt oxidation (MSO) reactor is described. Spent salt is removed from the reactor and analyzed to determine the contaminants present and the carbonate concentration. The salt is dissolved in water, and one or more reagents are added to precipitate the thorium as thorium oxide and/or the uranium as either uranium oxide or as a diuranate salt. The precipitated materials are filtered, dried and packaged for disposal as radioactive waste. About 90% of the thorium and/or uranium present is removed by filtration. After filtration, salt solutions having a carbonate concentration >20% can be dried and returned to the reactor for re-use. Salt solutions containing a carbonate concentration <20% require further clean-up using an ion exchange column, which yields salt solutions that contain less than 0.1 ppm of thorium or uranium.

Hsu, Peter C. (Pleasanton, CA); von Holtz, Erica H. (Livermore, CA); Hipple, David L. (Livermore, CA); Summers, Leslie J. (Livermore, CA); Adamson, Martyn G. (Danville, CA)

2002-01-01T23:59:59.000Z

63

Design considerations for concentrating solar power tower systems employing molten salt.  

SciTech Connect (OSTI)

The Solar Two Project was a United States Department of Energy sponsored project operated from 1996 to 1999 to demonstrate the coupling of a solar power tower with a molten nitrate salt as a heat transfer media and for thermal storage. Over all, the Solar Two Project was very successful; however many operational challenges were encountered. In this work, the major problems encountered in operation of the Solar Two facility were evaluated and alternative technologies identified for use in a future solar power tower operating with a steam Rankine power cycle. Many of the major problems encountered can be addressed with new technologies that were not available a decade ago. These new technologies include better thermal insulation, analytical equipment, pumps and values specifically designed for molten nitrate salts, and gaskets resistant to thermal cycling and advanced equipment designs.

Moore, Robert Charles; Siegel, Nathan Phillip; Kolb, Gregory J.; Vernon, Milton E.; Ho, Clifford Kuofei

2010-09-01T23:59:59.000Z

64

Perchlorate and nitrate in situ bioremediation of ground water  

SciTech Connect (OSTI)

Nitrate and perchlorate are growing worldwide problems as mobile anionic groundwater contaminants. Biological rduction of nitrate and perchlorate in groundwater is under development as a technology to address these problems.

Strietelmeier, E. A. (Elizabeth A.); Nuttall, H. Eric; Hatzinger, Paul; Goltz, Mark

2002-01-01T23:59:59.000Z

65

Electrolyte salts for nonaqueous electrolytes  

DOE Patents [OSTI]

Metal complex salts may be used in lithium ion batteries. Such metal complex salts not only perform as an electrolyte salt in a lithium ion batteries with high solubility and conductivity, but also can act as redox shuttles that provide overcharge protection of individual cells in a battery pack and/or as electrolyte additives to provide other mechanisms to provide overcharge protection to lithium ion batteries. The metal complex salts have at least one aromatic ring. The aromatic moiety may be reversibly oxidized/reduced at a potential slightly higher than the working potential of the positive electrode in the lithium ion battery. The metal complex salts may also be known as overcharge protection salts.

Amine, Khalil; Zhang, Zhengcheng; Chen, Zonghai

2012-10-09T23:59:59.000Z

66

Deep Eutectic Salt Formulations Suitable as Advanced Heat Transfer Fluids  

SciTech Connect (OSTI)

Concentrating solar power (CSP) facilities are comprised of many miles of fluid-filled pipes arranged in large grids with reflective mirrors used to capture radiation from the sun. Solar radiation heats the fluid which is used to produce steam necessary to power large electricity generation turbines. Currently, organic, oil-based fluid in the pipes has a maximum temperature threshold of 400 °C, allowing for the production of electricity at approximately 15 cents per kilowatt hour. The DOE hopes to foster the development of an advanced heat transfer fluid that can operate within higher temperature ranges. The new heat transfer fluid, when used with other advanced technologies, could significantly decrease solar electricity cost. Lower costs would make solar thermal electricity competitive with gas and coal and would offer a clean, renewable source of energy. Molten salts exhibit many desirable heat transfer qualities within the range of the project objectives. Halotechnics developed advanced heat transfer fluids (HTFs) for application in solar thermal power generation. This project focused on complex mixtures of inorganic salts that exhibited a high thermal stability, a low melting point, and other favorable characteristics. A high-throughput combinatorial research and development program was conducted in order to achieve the project objective. Over 19,000 candidate formulations were screened. The workflow developed to screen various chemical systems to discover salt formulations led to mixtures suitable for use as HTFs in both parabolic trough and heliostat CSP plants. Furthermore, salt mixtures which will not interfere with fertilizer based nitrates were discovered. In addition for use in CSP, the discovered salt mixtures can be applied to electricity storage, heat treatment of alloys and other industrial processes.

Raade, Justin; Roark, Thomas; Vaughn, John; Bradshaw, Robert

2013-07-22T23:59:59.000Z

67

Salt Waste Processing Initiatives  

Office of Environmental Management (EM)

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68

Salt Selected (FINAL)  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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69

Ancient Salt Beds  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth (AOD)ProductssondeadjustsondeadjustAbout theOFFICEAmes Laboratory Site| DepartmentInformation Ancient Salt

70

3, 59195976, 2003 The nitrate aerosol  

E-Print Network [OSTI]

ACPD 3, 5919­5976, 2003 The nitrate aerosol field over Europe M. Schaap et al. Title Page Abstract of Utrecht, Institute of Marine and Atmospheric Science, PO Box 80005, 3508 TA, Utrecht, The Netherlands 2, The Netherlands 3 Netherlands Energy Research Foundation (ECN), PO Box 1, 1755 LE Petten, The Netherlands 4 Joint

Paris-Sud XI, Université de

71

Electrochromic Salts, Solutions, and Devices  

DOE Patents [OSTI]

Electrochromic salts. Electrochromic salts of dicationic viologens such as methyl viologen and benzyl viologen associated with anions selected from bis(trifluoromethylsulfonyl)imide, bis(perfluoroethylsulfonyl)imide, and tris(trifluoromethylsulfonyl)methide are produced by metathesis with the corresponding viologen dihalide. They are highly soluble in molten quarternary ammonium salts and together with a suitable reductant provide electrolyte solutions that are used in electrochromic windows.

Burrell, Anthony K. (Los Alamos, NM); Warner, Benjamin P. (Los Alamos, NM); McClesky, T. Mark (Los Alamos, NM)

2008-10-14T23:59:59.000Z

72

Electrochromic Salts, Solutions, and Devices  

DOE Patents [OSTI]

Electrochromic salts. Electrochromic salts of dicationic viologens such as methyl viologen and benzyl viologen associated with anions selected from bis(trifluoromethylsulfonyl)imide, bis(perfluoroethylsulfonyl)imide, and tris(trifluoromethylsulfonyl)methide are produced by metathesis with the corresponding viologen dihalide. They are highly soluble in molten quarternary ammonium salts and together with a suitable reductant provide electrolyte solutions that are used in electrochromic windows.

Burrell, Anthony K. (Los Alamos, NM); Warner, Benjamin P. (Los Alamos, NM); McClesky, T. Mark (Los Alamos, NM)

2008-11-11T23:59:59.000Z

73

Electrochromic salts, solutions, and devices  

DOE Patents [OSTI]

Electrochromic salts. Electrochromic salts of dicationic viologens such as methyl viologen and benzyl viologen associated with anions selected from bis(trifluoromethylsulfonyl)imide, bis(perfluoroethylsulfonyl)imide, and tris(trifluoromethylsulfonyl)methide are produced by metathesis with the corresponding viologen dihalide. They are highly soluble in molten quarternary ammonium salts and together with a suitable reductant provide electrolyte solutions that are used in electrochromic windows.

Burrell, Anthony K. (Los Alamos, NM); Warner, Benjamin P. (Los Alamos, NM); McClesky,7,064,212 T. Mark (Los Alamos, NM)

2006-06-20T23:59:59.000Z

74

Extraction of nitric acid, uranyl nitrate, and bismuth nitrate from aqueous nitric acid solutions with CMPO  

SciTech Connect (OSTI)

DOE sponsored development of the transuranium extraction (TRUEX) process for removing actinides from radioactive wastes. The solvent is a mixture of CMPO and TBP. Since the extraction characteristics of CMPO are not as well understood as those of TBP, the extraction of nitric acid, uranyl nitrate, and bismuth nitrate with CMPO (dissolved in n-dodecane) were studied. Results indicate that CMPO extracts nitric acid with a 1:1 stoichiometry; equilibrium constant is 2. 660{plus_minus}0.092 at 25 C, and extraction enthalpy is -5. 46{plus_minus}0.46 kcal/mol. Slope analysis indicates that uranyl nitrate extracts with a mixed equilibria of 1:1 and 2:1 stoichiometries in nearly equal proportion. Equil. constant of the 2: 1 extraction was 1.213 {times} 10{sup 6}{plus_minus}3.56 {times} 10{sup 4} at 25 C; reaction enthalpy was -9.610{plus_minus}0.594 kcal/mol. Nitration complexation constant is 8.412{plus_minus}0.579, with an enthalpy of -10.72{plus_minus}1.87 kcal/mol. Bismuth nitrate also extracts with a mixed equilibria of (perhaps) 1:1 and 2:1 stoichiometries. A 2:1 extraction equilibrium and a nitrate complexation adequately model the data. Kinetics and enthalpies were also measured.

Spencer, B.B.

1995-08-01T23:59:59.000Z

75

EMRTC Report RF 10-13: Application to LANL Evaporator Nitrate Salts  

Office of Environmental Management (EM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "of EnergyEnergy CooperationRequirementsDraft Environmental ImpactEM Active SitesofEM's Year in ReviewAmount

76

Memo - Legacy Technical Area (TA)-55 Nitrate Salt Wastes at TA-54,  

Office of Environmental Management (EM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "of EnergyEnergyENERGY TAX POLICIES7.pdfFuel2007NavalMelvin G. Williams, Jr. About Us Melvin

77

Sandia National Laboratories: Molten Nitrate Salt Initial Flow Testing is a  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLas ConchasPassive SolarEducationStation TechnologyWindInternational

78

Technical Area (TA)-54 Area G Nitrate-Salt Waste Container Response  

Office of Environmental Management (EM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "of Energy Power.pdf11-161-LNGInternational EnergyCommitteeRenewable1234 OFTechnetium Retention

79

Test plan for immobilization of salt-containing surrogate mixed wastes using polyester resins  

SciTech Connect (OSTI)

Past operations at many Department of Energy (DOE) sites have resulted in the generation of several waste streams with high salt content. These wastes contain listed and characteristic hazardous constituents and are radioactive. The salts contained in the wastes are primarily chloride, sulfate, nitrate, metal oxides, and hydroxides. DOE has placed these types of wastes under the purview of the Mixed Waste Focus Area (MWFA). The MWFA has been tasked with developing and facilitating the implementation of technologies to treat these wastes in support of customer needs and requirements. The MWFA has developed a Technology Development Requirements Document (TDRD), which specifies performance requirements for technology owners and developers to use as a framework in developing effective waste treatment solutions. This project will demonstrate the use of polyester resins in encapsulating and solidifying DOE`s mixed wastes containing salts, as an alternative to conventional and other emerging immobilization technologies.

Biyani, R.K.; Douglas, J.C.; Hendrickson, D.W.

1997-07-07T23:59:59.000Z

80

Plant salt-tolerance mechanisms  

DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

Crop performance is severely affected by high salt concentrations in soils. To engineer more salt-tolerant plants it is crucial to unravel the key components of the plant salt-tolerance network. Here we review our understanding of the core salt-tolerance mechanisms in plants. Recent studies have shown that stress sensing and signaling components can play important roles in regulating the plant salinity stress response. We also review key Na+ transport and detoxification pathways and the impact of epigenetic chromatin modifications on salinity tolerance. In addition, we discuss the progress that has been made towards engineering salt tolerance in crops, including marker-assisted selection and gene stacking techniques. We also identify key open questions that remain to be addressed in the future.

Deinlein, Ulrich; Stephan, Aaron B.; Horie, Tomoaki; Luo, Wei; Xu, Guohua; Schroeder, Julian I.

2014-06-01T23:59:59.000Z

Note: This page contains sample records for the topic "nitrate salt central" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Independent Oversight Assessment, Salt Waste Processing Facility...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Salt Waste Processing Facility Project - January 2013 January 2013 Assessment of Nuclear Safety Culture at the Salt Waste Processing Facility Project The U.S. Department...

82

Reactions Between Water Soluble Organic Acids and Nitrates in...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Reactions Between Water Soluble Organic Acids and Nitrates in Atmospheric Aerosols: Recycling of Nitric Acid and Formation of Reactions Between Water Soluble Organic Acids and...

83

Aluminum nitrate recrystallization and recovery from liquid extraction raffinates  

SciTech Connect (OSTI)

The solid sludges resulting form biodenitrification of discarded aluminum nitrate are the largest Y-12 Plant process solid waste. Aluminum nitrate feedstocks also represent a major plant materials cost. The chemical constraints on aluminum nitrate recycle were investigated to determine the feasibility of increasing recycle while maintaining acceptable aluminum nitrate purity. Reported phase behavior of analogous systems, together with bench research, indicated that it would be possible to raise the recycle rate from 35% to between 70 and 90% by successive concentration and recrystallization of the mother liquor. A full scale pilot test successfully confirmed the ability to obtain 70% recycle in existing process equipment.

Griffith, W.L.; Compere, A.L.; Googin, J.M.; Huxtable, W.P.

1991-09-01T23:59:59.000Z

84

ammonium nitrate solution: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

2 % in the two experimental seasons. Key words: Date palm Fruit set Yield Fruit quality Boric acid Calcium nitrate INTRODUCTION synthesis, transport of sugars and carbohydrate...

85

acute uranyl nitrate: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

2 % in the two experimental seasons. Key words: Date palm Fruit set Yield Fruit quality Boric acid Calcium nitrate INTRODUCTION synthesis, transport of sugars and carbohydrate...

86

ammonium nitrates: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

2 % in the two experimental seasons. Key words: Date palm Fruit set Yield Fruit quality Boric acid Calcium nitrate INTRODUCTION synthesis, transport of sugars and carbohydrate...

87

ammonium nitrate pills: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

2 % in the two experimental seasons. Key words: Date palm Fruit set Yield Fruit quality Boric acid Calcium nitrate INTRODUCTION synthesis, transport of sugars and carbohydrate...

88

ammonium nitrate solutions: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

2 % in the two experimental seasons. Key words: Date palm Fruit set Yield Fruit quality Boric acid Calcium nitrate INTRODUCTION synthesis, transport of sugars and carbohydrate...

89

Fracture and Healing of Rock Salt Related to Salt Caverns  

SciTech Connect (OSTI)

In recent years, serious investigations of potential extension of the useful life of older caverns or of the use of abandoned caverns for waste disposal have been of interest to the technical community. All of the potential applications depend upon understanding the reamer in which older caverns and sealing systems can fail. Such an understanding will require a more detailed knowledge of the fracture of salt than has been necessary to date. Fortunately, the knowledge of the fracture and healing of salt has made significant advances in the last decade, and is in a position to yield meaningful insights to older cavern behavior. In particular, micromechanical mechanisms of fracture and the concept of a fracture mechanism map have been essential guides, as has the utilization of continuum damage mechanics. The Multimechanism Deformation Coupled Fracture (MDCF) model, which is summarized extensively in this work was developed specifically to treat both the creep and fracture of salt, and was later extended to incorporate the fracture healing process known to occur in rock salt. Fracture in salt is based on the formation and evolution of microfractures, which may take the form of wing tip cracks, either in the body or the boundary of the grain. This type of crack deforms under shear to produce a strain, and furthermore, the opening of the wing cracks produce volume strain or dilatancy. In the presence of a confining pressure, microcrack formation may be suppressed, as is often the case for triaxial compression tests or natural underground stress situations. However, if the confining pressure is insufficient to suppress fracture, then the fractures will evolve with time to give the characteristic tertiary creep response. Two first order kinetics processes, closure of cracks and healing of cracks, control the healing process. Significantly, volume strain produced by microfractures may lead to changes in the permeability of the salt, which can become a major concern in cavern sealing and operation. The MDCF model is used in three simulations of field experiments in which indirect measures were obtained of the generation of damage. The results of the simulations help to verify the model and suggest that the model captures the correct fracture behavior of rock salt. The model is used in this work to estimate the generation and location of damage around a cylindrical storage cavern. The results are interesting because stress conditions around the cylindrical cavern do not lead to large amounts of damage. Moreover, the damage is such that general failure can not readily occur, nor does the extent of the damage suggest possible increased permeation when the surrounding salt is impermeable.

Chan, K.S.; Fossum, A.F.; Munson, D.E.

1999-03-01T23:59:59.000Z

90

E-Print Network 3.0 - aluminium nitrates Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

uranium... for uranium,.contaminated groundwater. Nitrate is a common co.contaminant with uranium. Nitrate inhib- ited U... Mexico. Once nitrate was depleted, both U(VI) and...

91

An evaluation of pressure and flow measurement in the Molten Salt Test Loop (MSTL) system.  

SciTech Connect (OSTI)

The National Solar Thermal Test Facility at Sandia National Laboratories has a unique test capability called the Molten Salt Test Loop (MSTL) system. MSTL allows customers and researchers to test components in flowing, molten nitrate salt at plant-like conditions for pressure, flow, and temperature. An important need in thermal storage systems that utilize molten salts is for accurate flow and pressure measurement at temperatures above 535%C2%B0C. Currently available flow and pressure instrumentation for molten salt is limited to 535%C2%B0C and even at this temperature the pressure measurement appears to have significant variability. It is the design practice in current Concentrating Solar Power plants to measure flow and pressure on the cold side of the process or in dead-legs where the salt can cool, but this practice won't be possible for high temperature salt systems. For this effort, a set of tests was conducted to evaluate the use of the pressure sensors for flow measurement across a device of known flow coefficient Cv. To perform this task, the pressure sensors performance was evaluated and was found to be lacking. The pressure indicators are severely affected by ambient conditions and were indicating pressure changes of nearly 200psi when there was no flow or pressure in the system. Several iterations of performance improvement were undertaken and the pressure changes were reduced to less than 15psi. The results of these pressure improvements were then tested for use as flow measurement. It was found that even with improved pressure sensors, this is not a reliable method of flow measurement. The need for improved flow and pressure measurement at high temperatures remains and will need to be solved before it will be possible to move to high temperature thermal storage systems with molten salts.

Gill, David Dennis; Kolb, William J.; Briggs, Ronald J.

2013-07-01T23:59:59.000Z

92

CU(II): catalyzed hydrazine reduction of ferric nitrate  

SciTech Connect (OSTI)

A method is described for producing ferrous nitrate solutions by the cupric ion-catalyzed reduction of ferric nitrate with hydrazine. The reaction is complete in about 1.5 hours at 40/sup 0/C. Hydrazoic acid is also produced in substantial quantities as a reaction byproduct.

Karraker, D.G.

1981-11-01T23:59:59.000Z

93

Nitrate-Cancrinite Precipitation on Quartz Sand in Simulated Hanford  

E-Print Network [OSTI]

Nitrate-Cancrinite Precipitation on Quartz Sand in Simulated Hanford Tank Solutions B A R R Y R . B minerals at the U.S. Department of Energy's Hanford site in Washington. Nitrate-cancrinite began's (DOE) Hanford Site in southeast Washington since the late 1950s (1). To predict the fate

Illinois at Chicago, University of

94

Salt site performance assessment activities  

SciTech Connect (OSTI)

During this year the first selection of the tools (codes) for performance assessments of potential salt sites have been tentatively selected and documented; the emphasis has shifted from code development to applications. During this period prior to detailed characterization of a salt site, the focus is on bounding calculations, sensitivity and with the data available. The development and application of improved methods for sensitivity and uncertainty analysis is a focus for the coming years activities and the subject of a following paper in these proceedings. Although the assessments to date are preliminary and based on admittedly scant data, the results indicate that suitable salt sites can be identified and repository subsystems designed which will meet the established criteria for protecting the health and safety of the public. 36 references, 5 figures, 2 tables.

Kircher, J.F.; Gupta, S.K.

1983-01-01T23:59:59.000Z

95

E-Print Network 3.0 - aqueous nitrate flowsheet Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Hanford Site, located in Southeastern Washington... tetrachloride (CT) and nitrate contamination covers at least 5 km2. Within this area, CT concentrations up to 1... nitrate...

96

E-Print Network 3.0 - aqueous magnesium nitrate Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

magnesium nitrate Search Powered by Explorit Topic List Advanced Search Sample search results for: aqueous magnesium nitrate Page: << < 1 2 3 4 5 > >> 1 Subscriber access provided...

97

Effect of K loadings on nitrate formation/decomposition and on...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

K loadings on nitrate formationdecomposition and on NOx storage performance of K-based NOx storage-reduction Effect of K loadings on nitrate formationdecomposition and on NOx...

98

ARRAYS OF BOTTLES OF PLUTONIUM NITRATE SOLUTION  

SciTech Connect (OSTI)

In October and November of 1981 thirteen approaches-to-critical were performed on a remote split table machine (RSTM) in the Critical Mass Laboratory of Pacific Northwest Laboratory (PNL) in Richland, Washington using planar arrays of polyethylene bottles filled with plutonium (Pu) nitrate solution. Arrays of up to sixteen bottles were used to measure the critical number of bottles and critical array spacing with a tight fitting Plexiglas® reflector on all sides of the arrays except the top. Some experiments used Plexiglas shells fitted around each bottles to determine the effect of moderation on criticality. Each bottle contained approximately 2.4 L of Pu(NO3)4 solution with a Pu content of 105 g Pu/L and a free acid molarity H+ of 5.1. The plutonium was of low 240Pu (2.9 wt.%) content. These experiments were sponsored by Rockwell Hanford Operations because of the lack of experimental data on the criticality of arrays of bottles of Pu solution such as might be found in storage and handling at the Purex Facility at Hanford. The results of these experiments were used “to provide benchmark data to validate calculational codes used in criticality safety assessments of [the] plant configurations” (Ref. 1). Data for this evaluation were collected from the published report (Ref. 1), the approach to critical logbook, the experimenter’s logbook, and communication with the primary experimenter, B. Michael Durst. Of the 13 experiments preformed 10 were evaluated. One of the experiments was not evaluated because it had been thrown out by the experimenter, one was not evaluated because it was a repeat of another experiment and the third was not evaluated because it reported the critical number of bottles as being greater than 25. Seven of the thirteen evaluated experiments were determined to be acceptable benchmark experiments. A similar experiment using uranyl nitrate was benchmarked as U233-SOL-THERM-014.

Margaret A. Marshall

2012-09-01T23:59:59.000Z

99

Salt dome discoveries mounting in Mississippi  

SciTech Connect (OSTI)

Exploratory drilling around piercement salt domes in Mississippi has met with a string of successes in recent months. Exploration of these salt features is reported to have been initiated through the review of non-proprietary, 2D seismic data and subsurface control. This preliminary data and work were then selectively upgraded by the acquisition of additional, generally higher quality, conventional 2D seismic lines. This current flurry of successful exploration and ensuing development drilling by Amerada Hess Corp. on the flanks of salt domes in Mississippi has resulted in a number of significant Hosston discoveries/producers at: Carson salt dome in Jefferson Davis County; Dry Creek salt dome in Covington County, Midway salt dome in lamar County, Monticello salt dome in Lawrence County, and Prentiss salt dome in Jefferson Davis County. The resulting production from these fields is gas and condensate, with wells being completed on 640 acre production units.

Ericksen, R.L. [Mississippi Office of Geology, Jackson, MS (United States)

1996-06-17T23:59:59.000Z

100

Radar investigation of the Hockley salt dome  

E-Print Network [OSTI]

: Geophysics RADAR INVESTIGATION OF THE HOCKLEY SALT DOME A Thesis by UAMES ANDREW HLUCHANEK A'pproved as to style and content by: (Head of Departme t ? Member) May 1. 973 ABSTRACT Radar investigation of the Hockley Salt Dome. . (Nay, 1973) James.... THE PROBLEM. Page A. Probing into Unknown Areas in Salt. . B. Equipment Used. II. BACKGROUND MATERIAL. A. Geology of the Hockley Area. . . B. Economic History of the Hockley Dome Area. . 6 1. Oil 2. Gypsum. 3. Salt C. Geophysical Surveys Over...

Hluchanek, James Andrew

1973-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "nitrate salt central" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

A central composite design to investigate antibody fragment production by Pichia pastoris  

E-Print Network [OSTI]

This study aims to investigate the relationships between growth parameters (agitation, glycerol concentration, salt concentration) and responses (biomass, growth rate, protein expression), by a 3-factor-3-level central ...

Chan, Joyce, M. Eng. Massachusetts Institute of Technology

2005-01-01T23:59:59.000Z

102

Groundwater nitrates in the Seymour Aquifer: problem or resource?  

E-Print Network [OSTI]

24 tx H2O Fall 2012 Story by Alejandra Arreola-Triana In the Rolling Plains of Texas, the Seymour Aquifer is the major source of water for Haskell, Jones and Knox counties. #31;e water from the Seymour Aquifer, however, contains nitrate levels... are working on ways to manage the nitrate levels in this aquifer. Tracking the source Nitrates in groundwater can come from runo#27;, fertilizer use, leaks from septic tanks, sewage and erosion of natural deposits, according to the U.S. Environmental...

Arreola-Triana, Alejandra

2012-01-01T23:59:59.000Z

103

Molten Salt-Carbon Nanotube Thermal Energy Storage for Concentrating Solar Power Systems Final Report  

SciTech Connect (OSTI)

We demonstrated that adding nanoparticles to a molten salt would increase its utility as a thermal energy storage medium for a concentrating solar power system. Specifically, we demonstrated that we could increase the specific heat of nitrate and carbonate salts containing 1% or less of alumina nanoparticles. We fabricated the composite materials using both evaporative and air drying methods. We tested several thermophysical properties of the composite materials, including the specific heat, thermal conductivity, latent heat, and melting point. We also assessed the stability of the composite material with repeated thermal cycling and the effects of adding the nanoparticles on the corrosion of stainless steel by the composite salt. Our results indicate that stable, repeatable 25-50% improvements in specific heat are possible for these materials. We found that using these composite salts as the thermal energy storage material for a concentrating solar thermal power system can reduce the levelized cost of electricity by 10-20%. We conclude that these materials are worth further development and inclusion in future concentrating solar power systems.

Michael Schuller; Frank Little; Darren Malik; Matt Betts; Qian Shao; Jun Luo; Wan Zhong; Sandhya Shankar; Ashwin Padmanaban

2012-03-30T23:59:59.000Z

104

Experiments and analysis on the molten-salt direct-contact absorption receiver concept  

SciTech Connect (OSTI)

This paper presents results of recent experiments on the Direct Absorption Receiver (DAR) concept using molten salt as the working fluid. The DAR concept may result in a solar central receiver that costs 50% less than the current tube receiver and has significantly lower operational and maintenance costs. These experiments were aimed at determining whether the DAR concept is technically feasible and were carried out at the Advanced Components Test Facility, Atlanta, GA. Results are based on several days of operating with solar flux ranging up to 50 W/cm/sup 2/ and also on a numerical model that is capable of predicting the thermal performance of the DAR salt film. Issues relating to thermal efficiency, absorber-to-salt heat transfer, and salt film stability are addressed.

Bohn, M.S.; Wang, K.Y.

1986-11-01T23:59:59.000Z

105

Degradation of the molecular weight and nitrate ester content of cellulose nitrate on thermal aging. [PBX-9404  

SciTech Connect (OSTI)

Changes in molecular weight and nitrate ester content for cellulose nitrate (NC), either pure or as a constituent of PBX-9404, were determined as a function of time and temperature. Changes in the number-averaged molecular weight, M/sub n/, are described by the simple theory of random chain scission, and M/sub n/ is found to correlate well with nitrate ester loss. Significant differences are seen between NC aged in the isolated condition and aged as the binder in PBX-9404.

Leider, H R

1981-06-01T23:59:59.000Z

106

Development of an ammonia emission protocol and preliminary emission factor for a central Texas dairy  

E-Print Network [OSTI]

dairies. The Texas Commission on Environmental Quality (TCEQ), the Texas SAPRA, does not currently use an emission factor to permit or regulate emitted ammonia for the dairy industry. ________________________ This thesis follows the style..., and is subject to gas-phase reaction with photochemically produced hydroxyl (-OH) radicals, reaction with gaseous nitric acid (to form particulate ammonium nitrate), and with aerosols to form ammonium salts (Singh et al., 2001). Ammonia that does not react...

Rose, Adam Joseph

2004-09-30T23:59:59.000Z

107

Decontamination of water using nitrate selective ion exchange resin  

DOE Patents [OSTI]

A method for nitrate decontamination of water which involves passing the water through a bed of alkyl phosphonium anion exchange resin which has pendant alkyl groups of C[sub 3] or larger.

Lockridge, J.E.; Fritz, J.S.

1990-07-31T23:59:59.000Z

108

Nitrate contamination of domestic potable water supplies: a social problem  

SciTech Connect (OSTI)

Nitrate contamination of potable water supplies is a recognized health hazard. Potentially, the contamination of private drinking water supplies could be a problem in the rural Palouse area of Idaho and Washington. Studies have shown that 12% of the rural population of Whitman County, Washington, may be drinking water containing nitrates in excess of the national standard. Yet there is no organized concern about this potential health hazard among local citizens. After reviewing the literature on nitrate contamination of ground water and discussing nitrate contamination of private potable water supplies in the Palouse, we use a social movement theory of social problems to explain why this situation has not been defined as a public health problem.

Holmes, T.; Jensen, E.L.; Conway, J.B.

1985-01-01T23:59:59.000Z

109

Thermal decomposition of nitrated tributyl phosphate  

SciTech Connect (OSTI)

Tri-n-butyl phosphate (TBP), nitric acid and water mixtures are subject to thermal decomposition. The gaseous and liquid decomposition product yields are highly path dependent. Higher temperatures accelerate decomposition rates, but may result in lower extent of reaction than comparable low temperature cases. Actual extent of reaction, and gaseous by-products generation, are affected by the presence of Zr(IV), condensate reflux back into the reaction vessel, the water/HNO{sub 3} and the HNO{sub 3}/TBP molar ratios, and whether the decomposition occurs at isobaric or constant volume conditions. Higher gaseous production results from condensate reflux, lower H{sub 2}O/HNO{sub 3} ratios, and with excess HNO{sub 3} and water present as a second liquid phase. Principal gaseous products include N{sub 2}, CO, CO{sub 2}, NO and N{sub 2}O. Measurable concentrations of NO{sub 2} were not observed, although gas coloration indicative of NO{sub 2} were obsessed during the beginning of decomposition measurements. Principal liquid products are dibutyl phosphoric acid and butyl nitrate. Air sparging of TBP solutions (e.g., thru transfers using air lift pumps) may increase the hazards of TBP decomposition reactions by lowering the H{sub 2}O/HNO{sub 3} molar ratios. Runaway reactions were not observed under the conditions of this study. Possible reaction mechanisms and pathways are discussed.

Hou, Y.; Barefield, E.K.; Tedder, D.W.; Abdel-Khalik, S.I. [Georgia Institute of Technology, Atlanta, GA (United States)

1995-12-31T23:59:59.000Z

110

Immobilization of sodium nitrate waste with polymers: Topical report  

SciTech Connect (OSTI)

This report describes the development of solidification systems for sodium nitrate waste. Sodium nitrate waste was solidified in the polymers polyethylene, polyester-styrene (PES), and water-extendible polyester-styrene (WEP). Evaluations were made of the properties of waste forms containing various amounts of sodium nitrate by leaching immersion in water, measuring compressive strengths and by the EPA Extraction Procedure. Results of the leaching test are presented as cumulative fraction leached (CFL), incremental leaching rate, and average leaching indices (LI). For waste forms containing 30 to 70 wt% sodium nitrate, the CFL ranged from 9.0 x 10/sup -3/ to 7.3 x 10/sup -1/ and the LI from 11 to 7.8. After ninety days immersion in water, the compressive strengths ranged from 720 psi to 2550 psi. The nitrate releases from these samples using the EPA Extraction Procedure were below 500 ppM. The nitrate releases from PES waste forms were similar to those from polyethylene waste forms at the same waste loadings. The compressive yield strengths, measured after ninety-day immersion in water, ranged between 2070 and 7710 psi. In the case of WEP waste forms, only 30 wt% loaded samples passed the immersion test. 23 refs., 24 figs., 12 tabs.

Franz, E.M.; Heiser, J.H. III; Colombo, P.

1987-04-01T23:59:59.000Z

111

Crystal chemistry of thorium nitrates and chromates  

SciTech Connect (OSTI)

The structures and infrared spectra of six novel thorium compounds are reported. Th(NO{sub 3}){sub 2}(OH){sub 2}(H{sub 2}O){sub 2} (1) crystallizes in space group C2/c, a=14.050(1), b=8.992(7), c=5.954(5) A, {beta}=101.014(2){sup o}. K{sub 2}Th(NO{sub 3}){sub 6} (2), P-3, a=13.606(1), c=6.641(6) A. (C{sub 12}H{sub 28}N){sub 2}Th(NO{sub 3}){sub 6} (3), P2{sub 1}/c, a=14.643(4), b=15.772(5), c=22.316(5) A, {beta}=131.01(1){sup o}. KTh(NO{sub 3}){sub 5}(H{sub 2}O){sub 2} (4), P2{sub 1}/c, a=10.070(8), b=12.731(9), c=13.231(8) A, {beta}=128.647(4){sup o}. Th(CrO{sub 4}){sub 2}(H{sub 2}O){sub 2} (5), P2{sub 1}/n, a=12.731(1), b=9.469(8), c=12.972(1) A, {beta}=91.793(2){sup o}. K{sub 2}Th{sub 3}(CrO{sub 4}){sub 7}(H{sub 2}O){sub 10} (6), Ama2, a=19.302(8), b=15.580(6), c=11.318(6) A. The coordination polyhedra about Th in these structures are diverse. Th is coordinated by 9 O atoms in 5 and 6, seven of which are from monodentate (CrO{sub 4}) tetrahedra and two are (H{sub 2}O). The Th in compound 1 is coordinated by ten O atoms, four of which are O atoms of two bidentate (NO{sub 3}) triangles and six of which are (OH) and (H{sub 2}O). In compounds 2, 3 and 4 the Th is coordinate by 12 O atoms. In 2 and 3 there are six bidentate (NO{sub 3}) triangles, and in 4 ten of the O atoms are part of five bidentate (NO{sub 3}) triangles and the others are (H{sub 2}O) groups. The structural units of these compounds consist of a chain of thorium and nitrate polyhedra (1), isolated thorium hexanitrate clusters (2, 3), an isolated thorium pentanitrate dihydrate cluster (4), and a sheet (6) and framework (5) of thorium and chromate polyhedra. These structures illustrate the complexity inherent in the crystal chemistry of Th. - Graphical Abstract: The structures and infrared spectra of four new Th nitrates and two Th chromates are reported. The coordination numbers of the Th cations range from nine to 12 in these compounds. Structural units consist of isolated clusters, chains, sheets and frameworks.

Sigmon, Ginger E. [Department of Civil Engineering and Geological Sciences, University of Notre Dame, 156 Fitzpatrick Hall, Notre Dame, IN 46556 (United States); Burns, Peter C., E-mail: pburns@nd.ed [Department of Civil Engineering and Geological Sciences, University of Notre Dame, 156 Fitzpatrick Hall, Notre Dame, IN 46556 (United States)

2010-07-15T23:59:59.000Z

112

Testing of low temperature stabilization alternatives for salt-containing mixed wastes -- approach and results to date  

SciTech Connect (OSTI)

Through its annual process of identifying technology deficiencies associated with waste treatment, the Department of Energy`s (DOE) Mixed Waste Focus Area (MWFA) determined that the former DOE weapons complex lacks efficient mixed waste stabilization technologies for salt containing wastes. The current method used to stabilize salt waste for compliant disposal is grouting with Portland cement. This method is inefficient since the highly soluble and reactive chloride, nitrate, and sulfate salts interfere with the hydration and setting processes associated with grouting. The following five alternative salt waste stabilization technologies were selected for MWFA development funding in FY97 and FY98: (1) Phosphate Bonded Ceramics, (2) Sol-gel, (3) Polysiloxane, (4) Polyester Resin, and (5) Enhanced Concrete. Comparable evaluations were planned for the stabilization development efforts. Under these evaluations each technology stabilized the same type of salt waste surrogates as specified by the MWFA. Final waste form performance data such as compressive strength, waste loading, and leachability can then be equally compared to the requirements originally specified. In addition to the selected test results provided in this paper, the performance of each alternative stabilization technology, will be documented in formal MWFA Innovative Technology Summary Reports (ITSRs).

Maio, V.; Loomis, G. [Lockheed Martin Idaho Technologies Co., Idaho Falls, ID (United States)] [Lockheed Martin Idaho Technologies Co., Idaho Falls, ID (United States); Biyani, R.K. [SGN Eurisys Services Corp., Richland, WA (United States)] [SGN Eurisys Services Corp., Richland, WA (United States); Smith, G. [Pacific Northwest National Lab., Richland, WA (United States)] [Pacific Northwest National Lab., Richland, WA (United States); Spence, R. [Oak Ridge National Lab., TN (United States)] [Oak Ridge National Lab., TN (United States); Wagh, A. [Argonne National Lab., IL (United States)] [Argonne National Lab., IL (United States)

1998-07-01T23:59:59.000Z

113

Ion Recognition Approach to Volume Reduction of Alkaline Tank Waste by Separation and Recycle of Sodium Hydroxide and Sodium Nitrate  

SciTech Connect (OSTI)

The objective of this research is to explore new liquid-liquid extraction approaches to the selective separation of major sodium salts from alkaline high-level wastes stored in underground tanks at Hanford, Savannah River, and Oak Ridge sites. Disposal of high level waste is horrendously expensive, in large part because the actual radioactive matter in the tanks has been diluted over 1000-fold by ordinary inorganic chemicals. Since the residual bulk chemicals must still undergo expensive treatment and disposal after most of the hazardous radionuclides have been removed, large cost savings will result from processes that reduce the overall waste volume. It is proposed that major cost savings can be expected if sodium hydroxide needed for sludge washing can be obtained from the waste itself, thus avoiding the addition of yet another bulk chemical to the waste and still further increase of the waste volume and disposal cost. Secondary priority is given to separating potassium an d abundant anions, including nitrate, nitrite, aluminate, and carbonate. Salts of these ions represent possible additional value for recycle, alternative disposal, or even use as commodity chemicals. A comprehensive approach toward understanding the extractive chemistry of these salts is envisioned, involving systems of varying complexity, from use of simple solvents to new bifunctional host molecules for ion-pair recognition. These extractants will ideally require no adjustment of the waste composition and will release the extracted salt into water, thereby consuming no additional chemicals and producing no additional waste volume. The overall goal of this research is to provide a scientific foundation upon which the feasibility of new liquid-liquid extraction chemistry applicable to the bulk reduction of the volume of tank waste can be evaluated.

Moyer, Bruce A.; Marchand, Alan P.; Bryan, Jeffrey C.; Bonnesen, Peter V.

1999-06-01T23:59:59.000Z

114

Interior cavern conditions and salt fall potential  

SciTech Connect (OSTI)

A relatively large number of salt caverns are used for fluid hydrocarbon storage, including an extensive set of facilities in the Gulf Coast salt domes for the Strategic Petroleum Reserve (SPR) Program. Attention is focused on the SPR caverns because of available histories that detail events involving loss and damage of the hanging string casing. The total number of events is limited, making the database statistically sparse. The occurrence of the events is not evenly distributed, with some facilities, and some caverns, more susceptible than others. While not all of these events could be attributed to impacts from salt falls, many did show the evidence of such impacts. As a result, a study has been completed to analyze the potential for salt falls in the SPR storage caverns. In this process, it was also possible to deduce some of the cavern interior conditions. Storage caverns are very large systems in which many factors could possibly play a part in casing damage. In this study, all of the potentially important factors such as salt dome geology, operational details, and material characteristics were considered, with all being logically evaluated and most being determined as secondary in nature. As a result of the study, it appears that a principal factor in determining a propensity for casing damage from salt falls is the creep and fracture characteristics of salt in individual caverns. In addition the fracture depends strongly upon the concentration of impurity particles in the salt. Although direct observation of cavern conditions is not possible, the average impurity concentration and the accumulation of salt fall material can be determined. When this is done, there is a reasonable correlation between the propensity for a cavern to show casing damage events and accumulation of salt fall material. The accumulation volumes of salt fall material can be extremely large, indicating that only a few of the salt falls are large enough to cause impact damage.

Munson, D.E.; Molecke, M.A. [Sandia National Labs., Albuquerque, NM (United States); Myers, R.E. [Strategic Petroleum Reserve, New Orleans, LA (United States)

1998-03-01T23:59:59.000Z

115

Electrolytic orthoborate salts for lithium batteries  

DOE Patents [OSTI]

Orthoborate salts suitable for use as electrolytes in lithium batteries and methods for making the electrolyte salts are provided. The electrolytic salts have one of the formulae (I). In this formula anionic orthoborate groups are capped with two bidentate chelating groups, Y1 and Y2. Certain preferred chelating groups are dibasic acid residues, most preferably oxalyl, malonyl and succinyl, disulfonic acid residues, sulfoacetic acid residues and halo-substituted alkylenes. The salts are soluble in non-aqueous solvents and polymeric gels and are useful components of lithium batteries in electrochemical devices.

Angell, Charles Austen [Mesa, AZ; Xu, Wu [Tempe, AZ

2009-05-05T23:59:59.000Z

116

Electrolytic orthoborate salts for lithium batteries  

DOE Patents [OSTI]

Orthoborate salts suitable for use as electrolytes in lithium batteries and methods for making the electrolyte salts are provided. The electrolytic salts have one of the formulae (I). In this formula anionic orthoborate groups are capped with two bidentate chelating groups, Y1 and Y2. Certain preferred chelating groups are dibasic acid residues, most preferably oxalyl, malonyl and succinyl, disulfonic acid residues, sulfoacetic acid residues and halo-substituted alkylenes. The salts are soluble in non-aqueous solvents and polymeric gels and are useful components of lithium batteries in electrochemical devices.

Angell, Charles Austen (Mesa, AZ); Xu, Wu (Tempe, AZ)

2008-01-01T23:59:59.000Z

117

Solubility of hydrocarbons in salt water  

SciTech Connect (OSTI)

In the design and operation of industrial processes, physical and thermodynamic property data are required. Increasingly stringent regulations are making water solubility of substances even more critical. Water solubility data of naphthenes, or cycloalkanes, is applicable for the complete range of salt concentrations, including water without salt to water saturated with salt. The results are intended for use in initial engineering and environmental applications. Solubility values from the correlation are useful in determining the distribution of a hydrocarbon spill on its contact with sea water. Solubility values at other salt concentrations also may be computed. Results are presented for water solubility of hydrocarbons (naphthenes) as a function of salt concentration (log(S) = A + BX + CX[sup 2]). The correlation constants, A, B and C, are displayed in an easy-to-use tabular format that is applicable for rapid engineering use with the personal computer or hand-held calculator. The results for solubility in salt water are applicable for the complete range of salt concentrations. This range covers water without salt, X = 0, to water saturated with salt, X = 358,700 ppM(wt). Correlation and experimental results are in favorable agreement.

Yaws, C.L.; Lin, X. (Lamar Univ., Beaumont, TX (United States). Dept. of Chemical Engineering)

1994-01-01T23:59:59.000Z

118

Granular Salt Summary: Reconsolidation Principles and Applications  

SciTech Connect (OSTI)

The purposes of this paper are to review the vast amount of knowledge concerning crushed salt reconsolidation and its attendant hydraulic properties (i.e., its capability for fluid or gas transport) and to provide a sufficient basis to understand reconsolidation and healing rates under repository conditions. Topics covered include: deformation mechanisms and hydro-mechanical interactions during reconsolidation; the experimental data base pertaining to crushed salt reconsolidation; transport properties of consolidating granulated salt and provides quantitative substantiation of its evolution to characteristics emulating undisturbed rock salt; and extension of microscopic and laboratory observations and data to the applicable field scale.

Frank Hansen; Till Popp; Klaus Wieczorek; Dieter Stührenberg

2014-07-01T23:59:59.000Z

119

Multiphase Flow and Cavern Abandonment in Salt  

SciTech Connect (OSTI)

This report will explore the hypothesis that an underground cavity in gassy salt will eventually be gas filled as is observed on a small scale in some naturally occurring salt inclusions. First, a summary is presented on what is known about gas occurrences, flow mechanisms, and cavern behavior after abandonment. Then, background information is synthesized into theory on how gas can fill a cavern and simultaneously displace cavern fluids into the surrounding salt. Lastly, two-phase (gas and brine) flow visualization experiments are presented that demonstrate some of the associated flow mechanisms and support the theory and hypothesis that a cavity in salt can become gas filled after plugging and abandonment

Ehgartner, Brian; Tidwell, Vince

2001-02-13T23:59:59.000Z

120

LUMINESCENCE SPECTRA OF THE URANYL ION IN TWO GEOMETRICALLY SIMILAR COORDINATION ENVIRONMENTS: URANYL NITRATE HEXAHYDRATE AND DI-u-AQUO-BIS (DIOXODINITRA-TOURANIUM(VI) DI-IMIDAZOLE  

E-Print Network [OSTI]

coordination sphere of uranyl nitrate hexahydrate (UNH). U-Coordination Environments: Uranyl Nitrate Hexahydrate andin the crystal hosts of uranyl nitrate hexahydrate (UNH) and

Brittain, Harry G.

2013-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "nitrate salt central" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Testing thermocline filler materials and molten-salt heat transfer fluids for thermal energy storage systems used in parabolic trough solar power plants.  

SciTech Connect (OSTI)

Parabolic trough power systems that utilize concentrated solar energy to generate electricity are a proven technology. Industry and laboratory research efforts are now focusing on integration of thermal energy storage as a viable means to enhance dispatchability of concentrated solar energy. One option to significantly reduce costs is to use thermocline storage systems, low-cost filler materials as the primary thermal storage medium, and molten nitrate salts as the direct heat transfer fluid. Prior thermocline evaluations and thermal cycling tests at the Sandia National Laboratories' National Solar Thermal Test Facility identified quartzite rock and silica sand as potential filler materials. An expanded series of isothermal and thermal cycling experiments were planned and implemented to extend those studies in order to demonstrate the durability of these filler materials in molten nitrate salts over a range of operating temperatures for extended timeframes. Upon test completion, careful analyses of filler material samples, as well as the molten salt, were conducted to assess long-term durability and degradation mechanisms in these test conditions. Analysis results demonstrate that the quartzite rock and silica sand appear able to withstand the molten salt environment quite well. No significant deterioration that would impact the performance or operability of a thermocline thermal energy storage system was evident. Therefore, additional studies of the thermocline concept can continue armed with confidence that appropriate filler materials have been identified for the intended application.

Kelly, Michael James; Hlava, Paul Frank; Brosseau, Douglas A.

2004-07-01T23:59:59.000Z

122

Laboratory performance testing of an extruded bitumen containing a surrogate, sodium nitrate-based, low-level aqueous waste  

SciTech Connect (OSTI)

Laboratory results of a comprehensive, regulatory performance test program, utilizing an extruded bitumen and a surrogate, sodium nitrate-based waste, have been compiled at the Oak Ridge National Laboratory (ORNL). Using a 53 millimeter, Werner and Pfleiderer extruder, operated by personnel of WasteChem Corporation of Paramus, New Jersey, laboratory-scale, molded samples of type three, air blown bitumen were prepared for laboratory performance testing. A surrogate, low-level, mixed liquid waste, formulated to represent an actual on-site waste at ORNL, containing about 30 wt % sodium nitrate, in addition to eight heavy metals, cold cesium and strontium was utilized. Samples tested contained three levels of waste loading: that is, forty, fifty and sixty wt % salt. Performance test results include the ninety day ANS 16.1 leach test, with leach indices reported for all cations and anions, in addition to the EP Toxicity test, at all levels of waste loading. Additionally, test results presented also include the unconfined compressive strength and surface morphology utilizing scanning electron microscopy. Data presented include correlations between waste form loading and test results, in addition to their relationship to regulatory performance requirements.

Mattus, A.J.; Kaczmarsky, M.M.

1986-12-15T23:59:59.000Z

123

Molten Salt Power Tower Cost Model for the System Advisor Model (SAM)  

SciTech Connect (OSTI)

This report describes a component-based cost model developed for molten-salt power tower solar power plants. The cost model was developed by the National Renewable Energy Laboratory (NREL), using data from several prior studies, including a contracted analysis from WorleyParsons Group, which is included herein as an Appendix. The WorleyParsons' analysis also estimated material composition and mass for the plant to facilitate a life cycle analysis of the molten salt power tower technology. Details of the life cycle assessment have been published elsewhere. The cost model provides a reference plant that interfaces with NREL's System Advisor Model or SAM. The reference plant assumes a nominal 100-MWe (net) power tower running with a nitrate salt heat transfer fluid (HTF). Thermal energy storage is provided by direct storage of the HTF in a two-tank system. The design assumes dry-cooling. The model includes a spreadsheet that interfaces with SAM via the Excel Exchange option in SAM. The spreadsheet allows users to estimate the costs of different-size plants and to take into account changes in commodity prices. This report and the accompanying Excel spreadsheet can be downloaded at https://sam.nrel.gov/cost.

Turchi, C. S.; Heath, G. A.

2013-02-01T23:59:59.000Z

124

Metal salt catalysts for enhancing hydrogen spillover  

DOE Patents [OSTI]

A composition for hydrogen storage includes a receptor, a hydrogen dissociating metal doped on the receptor, and a metal salt doped on the receptor. The hydrogen dissociating metal is configured to spill over hydrogen to the receptor, and the metal salt is configured to increase a rate of the spill over of the hydrogen to the receptor.

Yang, Ralph T; Wang, Yuhe

2013-04-23T23:59:59.000Z

125

STRUCTURE OF PENTAKIS (UREA) DIOXOURANIUM(VI)NITRATE LUO2 (OC (NH2)2)5 (NO3) 2  

E-Print Network [OSTI]

an aqueous solution of uranyl nitrate and urea which wasALL f(O,O.t» URANYL UREA NITRATE FOB AND FCA ARE THEFACTORS CO~TINUE& FOf URANYL UREA NITRATE l F[) B PAGE . ,

Zalkin, Allan

2011-01-01T23:59:59.000Z

126

Solar Policy Environment: Salt Lake  

Broader source: Energy.gov [DOE]

The overall objective of the “Solar Salt Lake” (SSL) team is to develop a fully-scoped city and county-level implementation plan that will facilitate at least an additional ten megawatts of solar photovoltaic (PV) installations in the government, commercial, industrial, and residential sectors by 2015. To achieve this aggressive goal, the program strategy includes a combination of barrier identification, research, and policy analysis that utilizes the input of various stakeholders. Coupled with these activities will be the development and implementation of pilot installations in the government and residential sectors, and broad outreach to builders and potential practitioners of solar energy products in the process. In this way, while creating mechanisms to enable a demand for solar, SSL will also facilitate capacity building for suppliers, thereby helping to ensure long-term sustainability for the regional market.

127

Characterization of Surface and Bulk Nitrates of ?-Al2O3...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Surface and Bulk Nitrates of ?-Al2O3-Supported Alkaline Earth Oxides using Density Functional Theory. Characterization of Surface and Bulk Nitrates of ?-Al2O3-Supported...

128

THE SYSTEM THORIUM NITRATE-WATER-NITRIC ACID AT 25 AND THE HYDRATES...  

Office of Scientific and Technical Information (OSTI)

SYSTEM THORIUM NITRATE-WATER-NITRIC ACID AT 25 AND THE HYDRATES OF THORIUM NITRATE Re-direct Destination: Temp Data Fields Ferraro, J.R.; Katzin, L.I. Temp Data Storage 3: Argonne...

129

THE SYSTEM THORIUM NITRATE-WATER-NITRIC ACID AT 25 AND THE HYDRATES...  

Office of Scientific and Technical Information (OSTI)

SYSTEM THORIUM NITRATE-WATER-NITRIC ACID AT 25 AND THE HYDRATES OF THORIUM NITRATE Re-direct Destination: times redirected to final destination ShortURL Code Published Current...

130

EP-AREAG-PLAN-1248, R.0 TA-54 Area G Nitrate-Salt Waste Container Response Instructions  

Office of Environmental Management (EM)

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131

Correlation of Creep Behavior of Domal Salts  

SciTech Connect (OSTI)

The experimentally determined creep responses of a number of domal salts have been reported in, the literature. Some of these creep results were obtained using standard (conventional) creep tests. However, more typically, the creep data have come from multistage creep tests, where the number of specimens available for testing was small. An incremental test uses abrupt changes in stress and temperature to produce several time increments (stages) of different creep conditions. Clearly, the ability to analyze these limited data and to correlate them with each other could be of considerable potential value in establishing the mechanical characteristics of salt domes, both generally and specifically. In any analysis, it is necessary to have a framework of rules to provide consistency. The basis for the framework is the Multimechanism-Deformation (M-D) constitutive model. This model utilizes considerable general knowledge of material creep deformation to supplement specific knowledge of the material response of salt. Because the creep of salt is controlled by just a few micromechanical mechanisms, regardless of the origin of the salt, certain of the material parameters are values that can be considered universal to salt. Actual data analysis utilizes the methodology developed for the Waste Isolation Pilot Plant (WIPP) program, and the response of a bedded pure WIPP salt as the baseline for comparison of the domal salts. Creep data from Weeks Island, Bryan Mound, West Hackberry, Bayou Choctaw, and Big Hill salt domes, which are all sites of Strategic Petroleum Reserve (SPR) storage caverns, were analyzed, as were data from the Avery Island, Moss Bluff, and Jennings salt domes. The analysis permits the parameter value sets for the domal salts to be determined in terms of the M-D model with various degrees of completeness. In turn this permits detailed numerical calculations simulating cavern response. Where the set is incomplete because of the sparse database, reasonable assumptions permit the set to be completed. From the analysis, two distinct response groups were evident, with the salts of one group measurably more creep resistant than the other group. Interestingly, these groups correspond well with the indirectly determined creep closure of the SPR storage caverns, a correlation that probably should be expected. Certainly, the results suggest a simple laboratory determination of the creep characteristics of a salt material from a dome site can indicate the relative behavior of any potential cavern placed within that dome.

Munson, D.E.

1999-02-16T23:59:59.000Z

132

Development Wells At Salt Wells Area (Nevada Bureau of Mines...  

Open Energy Info (EERE)

Salt Wells Area (Nevada Bureau of Mines and Geology, 2009) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Development Wells At Salt Wells Area...

133

Inexpensive, Nonfluorinated Anions for Lithium Salts and Ionic...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Anions for Lithium Salts and Ionic Liquids for Lithium Battery Electrolytes Inexpensive, Nonfluorinated Anions for Lithium Salts and Ionic Liquids for Lithium Battery Electrolytes...

134

New lithium-based ionic liquid electrolytes that resist salt...  

Energy Savers [EERE]

lithium-based ionic liquid electrolytes that resist salt concentration polarization New lithium-based ionic liquid electrolytes that resist salt concentration polarization...

135

Effects of Carbonate Solvents and Lithium Salts on Morphology...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Carbonate Solvents and Lithium Salts on Morphology and Coulombic Efficiency of Lithium Electrode. Effects of Carbonate Solvents and Lithium Salts on Morphology and Coulombic...

136

Development of Molten-Salt Heat Trasfer Fluid Technology for...  

Broader source: Energy.gov (indexed) [DOE]

Development of Molten-Salt Heat Trasfer Fluid Technology for Parabolic Trough Solar Power Plants Development of Molten-Salt Heat Trasfer Fluid Technology for Parabolic Trough Solar...

137

acid salt solutions: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of nutrients and heavy metals in experimental salt marsh ecosystems. Environmental Pollution,effects of nutrients and heavy metals in experimental salt marsh ecosystems....

138

alkaline salt solution: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of nutrients and heavy metals in experimental salt marsh ecosystems. Environmental Pollution,effects of nutrients and heavy metals in experimental salt marsh ecosystems....

139

alkaline salt solutions: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of nutrients and heavy metals in experimental salt marsh ecosystems. Environmental Pollution,effects of nutrients and heavy metals in experimental salt marsh ecosystems....

140

alkyl ammonium salts: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of nutrients and heavy metals in experimental salt marsh ecosystems. Environmental Pollution,effects of nutrients and heavy metals in experimental salt marsh ecosystems....

Note: This page contains sample records for the topic "nitrate salt central" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

aqueous salt systems: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of nutrients and heavy metals in experimental salt marsh ecosystems. Environmental Pollution,effects of nutrients and heavy metals in experimental salt marsh ecosystems....

142

aromatic diazonium salts: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of nutrients and heavy metals in experimental salt marsh ecosystems. Environmental Pollution,effects of nutrients and heavy metals in experimental salt marsh ecosystems....

143

alkyl ester salts: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of nutrients and heavy metals in experimental salt marsh ecosystems. Environmental Pollution,effects of nutrients and heavy metals in experimental salt marsh ecosystems....

144

allylic silanolate salts: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of nutrients and heavy metals in experimental salt marsh ecosystems. Environmental Pollution,effects of nutrients and heavy metals in experimental salt marsh ecosystems....

145

EIA - Natural Gas Pipeline Network - Salt Cavern Storage Reservoir...  

U.S. Energy Information Administration (EIA) Indexed Site

Salt Cavern Underground Natural Gas Storage Reservoir Configuration Salt Cavern Underground Natural Gas Storage Reservoir Configuration Source: PB Energy Storage Services Inc....

146

Tropospheric Chemistry of Internally Mixed Sea Salt and Organic...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Tropospheric Chemistry of Internally Mixed Sea Salt and Organic Particles: Surprising Reactivity of NaCl with Weak Organic Acids Tropospheric Chemistry of Internally Mixed Sea Salt...

147

Project Profile: Deep Eutectic Salt Formulations Suitable as...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Deep Eutectic Salt Formulations Suitable as Advanced Heat Transfer Fluids Project Profile: Deep Eutectic Salt Formulations Suitable as Advanced Heat Transfer Fluids Halotechnics...

148

Accident Investigation of the February 5, 2014, Underground Salt...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

5, 2014, Underground Salt Haul Truck Fire at the Waste Isolation Pilot Plant, Carlsbad NM Accident Investigation of the February 5, 2014, Underground Salt Haul Truck Fire...

149

Voluntary Protection Program Onsite Review, Salt Waste Processing...  

Broader source: Energy.gov (indexed) [DOE]

Salt Waste Processing Facility Construction Project - February 2013 Voluntary Protection Program Onsite Review, Salt Waste Processing Facility Construction Project - February 2013...

150

Voluntary Protection Program Onsite Review, Parsons Corp., Salt...  

Office of Environmental Management (EM)

Parsons Corp., Salt Waste Processing Facility Construction Project - May 2014 Voluntary Protection Program Onsite Review, Parsons Corp., Salt Waste Processing Facility Construction...

151

Testing of low-temperature stabilization alternatives for salt containing mixed wastes -- Approach and results to date  

SciTech Connect (OSTI)

Through its annual process of identifying technology deficiencies associated with waste treatment, the Department of Energy`s (DOE) Mixed Waste Focus Area (MWFA) determined that the former DOE weapons complex lacks efficient mixed waste stabilization technologies for salt containing wastes. These wastes were generated as sludge and solid effluents from various primary nuclear processes involving acids and metal finishing; and well over 10,000 cubic meters exist at 6 sites. In addition, future volumes of these problematic wastes will be produced as other mixed waste treatment methods such as incineration and melting are deployed. The current method used to stabilize salt waste for compliant disposal is grouting with Portland cement. This method is inefficient since the highly soluble and reactive chloride, nitrate, and sulfate salts interfere with the hydration and setting processes associated with grouting. The inefficiency results from having to use low waste loadings to ensure a durable and leach resistant final waste form. The following five alternatives were selected for MWFA development funding in FY97 and FY98: phosphate bonded ceramics; sol-gel process; polysiloxane; polyester resin; and enhanced concrete. Comparable evaluations were planned for the stabilization development efforts. Under these evaluations each technology stabilized the same type of salt waste surrogates. Final waste form performance data such as compressive strength, waste loading, and leachability could then be equally compared. Selected preliminary test results are provided in this paper.

Maio, V.; Loomis, G. [Lockheed Martin Idaho Technologies Co., Idaho Falls, ID (United States); Spence, R.D. [Oak Ridge National Lab., TN (United States); Smith, G. [Pacific Northwest National Lab., Richland, WA (United States); Biyani, R.K. [SGN Eurisys Services Corp., Richland, WA (United States); Wagh, A. [Argonne National Lab., IL (United States)

1998-05-01T23:59:59.000Z

152

MICHIGAN'S SOIL NITRATE TEST FOR CORN MSU SOIL AND PLANT NUTRIENT LAB  

E-Print Network [OSTI]

MICHIGAN'S SOIL NITRATE TEST FOR CORN MSU SOIL AND PLANT NUTRIENT LAB Michigan State University Extension Crop and Soil Sciences Department Michigan State University WHY TEST SOIL FOR NITRATES Nitrate testing of soil is an excellent and inexpensive way of evaluating the available nitrogen (N) status

Isaacs, Rufus

153

Regulation by nitrate of protein synthesis and translation of RNA in maize roots  

SciTech Connect (OSTI)

Roots of maize seedlings were exposed to /sup 35/S-methionine in the presence or absence of nitrate. Using SDS-PAGE, nitrate-induced changes in labeled polypeptides were noted in the soluble (at 92, 63 and 21kD) and organellar(at 14kD) fractions, as well as in a membrane fraction of putative tonoplast origin (at 31kD). No nitrate-induced changes were noted in a plasmamembrane-enriched fraction or in a membrane fraction of mixed origin. Total RNA from nitrate-treated and control roots was translated in a rabbit reticulocyte system. Five translation products (94, 63, 41, 39 and 21kD) were identified as nitrate-inducible by comparative gel electrophoresis. Changes in protein synthesis and translation of mRNA were apparent within 2-3 h after introduction of nitrate. Within 4-6 h after removal of nitrate, the level of nitrate-inducible translation products diminished to that of control roots. In contrast, the 31kD tonoplast polypeptide was still labeled 26 h after removal of external nitrate and /sup 35/S-methionine. The results will be discussed in relation to the nitrate induction of nitrate reductase, nitrite reductase, and the nitrate uptake system.

McClure, P.R.; Bouthyette, P.Y.

1986-04-01T23:59:59.000Z

154

Salt Tolerance of Desorption Electrospray Ionization (DESI)  

SciTech Connect (OSTI)

Suppression of ion intensity in the presence of high salt matrices is common in most mass spectrometry ionization techniques. Desorption electrospray ionization (DESI) is an ionization method that exhibits salt tolerance, and this is investigated. DESI analysis was performed on three different drug mixtures in the presence of 0, 0.2, 2, 5, 10, and 20% NaCl:KCl weight by volume from seven different surfaces. At physiological concentrations individual drugs in each mixture were observed with each surface. Collision-induced dissociation (CID) was used to provide additional confirmation for select compounds. Multiple stage experiments, to MS5, were performed for select compounds. Even in the absence of added salt, the benzodiazepine containing mixture yielded sodium and potassium adducts of carbamazepine which masked the ions of interest. These adducts were eliminated by adding 0.1% 7M ammonium acetate to the standard methanol:water (1:1) spray solvent. Comparison of the salt tolerance of DESI with that of electrospray ionization (ESI) demonstrated much better signal/noise characteristics for DESI in this study. The salt tolerance of DESI was also studied by performing limit of detection and dynamic range experiments. Even at a salt concentration significantly above physiological concentrations, select surfaces were effective in providing spectra that allowed the ready identification of the compounds of interest. The already high salt tolerance of DESI can be optimized further by appropriate choices of surface and spray solution.

Jackson, Ayanna U. [Purdue University; Talaty, Nari [Purdue University; Cooks, R G [Purdue University; Van Berkel, Gary J [ORNL

2007-01-01T23:59:59.000Z

155

Destruction of XM-46 (aka LGP-1846) using the Molten Salt Destruction Process  

SciTech Connect (OSTI)

The experimental work done on the destruction of the liquid gun propellant XM-46 (or LGP-1846) using the Molten Salt Destruction (MSD) Process at the Lawrence Livermore National Laboratory (LLNL) for the US Army is described in this report. The current methods of disposal of large quantities of high explosives (HE), propellants and wastes containing energetic materials by open burning or open detonation (OB/OD), or by incineration, are becoming undesirable. LLNL is developing MSD as an alternative to OB/OD and incineration of energetic materials. A series of 18 continuous experimental runs were made wherein a solution of XM-46 and water was injected into a bed of molten salt comprising the carbonates of sodium, potassium and lithium, along with air. The results from these experiments, described in detail in the main body of this report, show that: XM-46 can be safely and completely destroyed in a bed of molten salt at temperatures well below those needed for incineration. Under optimum operating conditions, less than 1% of the chemically bound nitrogen in the XM-46 is converted to NO{sub x}, and less than 1% carbon is converted to CO. There exist, however, a number of technical uncertainties: We need to understand better why nitrates build up in the salt bath, and what we can do to reduce this amount. We need to understand the mechanism of XM-46 oxidation and ways to minimize the formation of CO and NO{sub x}. In addition, we would like to find out ways by which a more concentrated solution of XM-46 can be introduced into the reactor, so as to increase the throughputs.

Upadhye, R.S.; Watkins, B.E.

1994-03-01T23:59:59.000Z

156

Engineering study of the potential uses of salts from selective crystallization of Hanford tank wastes  

SciTech Connect (OSTI)

The Clean Salt Process (CSP) is the fractional crystallization of nitrate salts from tank waste stored on the Hanford Site. This study reviews disposition options for a CSP product made from Hanford Site tank waste. These options range from public release to onsite low-level waste disposal to no action. Process, production, safety, environment, cost, schedule, and the amount of CSP material which may be used are factors considered in each option. The preferred alternative is offsite release of clean salt. Savings all be generated by excluding the material from low-level waste stabilization. Income would be received from sales of salt products. Savings and income from this alternative amount to $1,027 million, excluding the cost of CSP operations. Unless public sale of CSP products is approved, the material should be calcined. The carbonate form of the CSP could then be used as ballast in tank closure and stabilization efforts. Not including the cost of CSP operations, savings of $632 million would be realized. These savings would result from excluding the material from low-level waste stabilization and reducing purchases of chemicals for caustic recycle and stabilization and closure. Dose considerations for either alternative are favorable. No other cost-effective alternatives that were considered had the capacity to handle significant quantities of the CSP products. If CSP occurs, full-scale tank-waste stabilization could be done without building additional treatment facilities after Phase 1 (DOE 1996). Savings in capital and operating cost from this reduction in waste stabilization would be in addition to the other gains described.

Hendrickson, D.W.

1996-04-30T23:59:59.000Z

157

Examination of Liquid Fluoride Salt Heat Transfer  

SciTech Connect (OSTI)

The need for high efficiency power conversion and energy transport systems is increasing as world energy use continues to increase, petroleum supplies decrease, and global warming concerns become more prevalent. There are few heat transport fluids capable of operating above about 600oC that do not require operation at extremely high pressures. Liquid fluoride salts are an exception to that limitation. Fluoride salts have very high boiling points, can operate at high temperatures and low pressures and have very good heat transfer properties. They have been proposed as coolants for next generation fission reactor systems, as coolants for fusion reactor blankets, and as thermal storage media for solar power systems. In each case, these salts are used to either extract or deliver heat through heat exchange equipment, and in order to design this equipment, liquid salt heat transfer must be predicted. This paper discusses the heat transfer characteristics of liquid fluoride salts. Historically, heat transfer in fluoride salts has been assumed to be consistent with that of conventional fluids (air, water, etc.), and correlations used for predicting heat transfer performance of all fluoride salts have been the same or similar to those used for water conventional fluids an, water, etc). A review of existing liquid salt heat transfer data is presented, summarized, and evaluated on a consistent basis. Less than 10 experimental data sets have been found in the literature, with varying degrees of experimental detail and measured parameters provided. The data has been digitized and a limited database has been assembled and compared to existing heat transfer correlations. Results vary as well, with some data sets following traditional correlations; in others the comparisons are less conclusive. This is especially the case for less common salt/materials combinations, and suggests that additional heat transfer data may be needed when using specific salt eutectics in heat transfer equipment designs. All of the data discussed above were taken under forced convective conditions (both laminar and turbulent). Some recent data taken at ORNL under free convection conditions are also presented and results discussed. This data was taken using a simple crucible experiment with an instrumented nickel heater inserted in the salt to induce natural circulation within the crucible. The data was taken over a temperature range of 550oC to 650oC in FLiNaK salt. This data covers both laminar and turbulent natural convection conditions, and is compared to existing forms of natural circulation correlations.

Yoder Jr, Graydon L [ORNL] [ORNL

2014-01-01T23:59:59.000Z

158

Ion Recognition Approach to Volume Reduction of Alkaline Tank Waste by Separation and Recycle of Sodium Hydroxide and Sodium Nitrate  

SciTech Connect (OSTI)

Disposal of high-level nuclear waste is horrendously expensive, in large part because the actual radioactive matter in the tanks has been diluted over 1000-fold by ordinary inorganic chemicals. Treatment processes themselves can exacerbate the problem by adding further volume to the waste. Waste retrieval and sludge washing, for example, will require copious amounts of sodium hydroxide. If the needed sodium hydroxide could be separated from the waste and recycled, however, the addition of fresh sodium hydroxide could be avoided, ultimately reducing the final waste volume and associated disposal costs. The major objective of this research is to explore new liquid-liquid extraction approaches to the selective separation of sodium hydroxide from alkaline high-level wastes stored in underground tanks at the Hanford and Savannah River sites. Consideration is also given to separating potassium and abundant anions, including nitrate, nitrite, aluminate, and carbonate. Salts of these ions represent possible additional value for recycle, alternative disposal, or even use as commodity chemicals. A comprehensive approach toward understanding the extractive chemistry of these salts is envisioned, involving systems of varying complexity, from use of simple solvents to new bifunctional host molecules for ion-pair recognition. These extractants will ideally require no adjustment of the waste composition and will release the extracted salt into water, thereby consuming no additional chemicals and producing no additional waste volume. The overall goal of this research is to provide a scientific foundation upon which the feasibility of new liquid-liquid extraction chemistry applicable to the bulk reduction of the volume of tank waste can be evaluated.

Moyer, Bruce A.; Marchand, Alan P.

2001-06-01T23:59:59.000Z

159

Ion Recognition Approach to Volume Reduction of Alkaline Tank Waste by Separation and Recycle of Sodium Hydroxide and Sodium Nitrate  

SciTech Connect (OSTI)

Disposal of high- level waste is horrendously expensive, in large part because the actual radioactive matter in the tanks has been diluted over 1000-fold by ordinary inorganic chemicals. Treatment processes themselves can exacerbate the problem by adding further volume to the waste. Waste retrieval and sludge washing, for example, will require copious amounts of sodium hydroxide. If the needed sodium hydroxide could be separated from the waste and recycled, however, the addition of fresh sodium hydroxide could be avoided, ultimately reducing the final waste volume and associated disposal costs. The major objective of this research is to explore new liquid- liquid extraction approaches to the selective separation of sodium hydroxide from alkaline high-level wastes stored in underground tanks at the Hanford and Savannah River sites. Consideration is also given to separating potassium and abundant anions, including nitrate, nitrite, aluminate, and carbonate. Salts of these ions represent possible additional value for recycle, alternative disposal, or even use as commodity chemicals. A comprehensive approach toward understanding the extractive chemistry of these salts is envisioned, involving systems of varying complexity, from use of simple solvents to new bifunctional host molecules for ion-pair recognition. These extractants will ideally require no adjustment of the waste composition and will release the extracted salt into water, thereby consuming no additional chemicals and producing no additional waste volume. The overall goal of this research is to provide a scientific foundation upon which the feasibility of new liquid-liquid extraction chemistry applicable to the bulk reduction of the volume of tank waste can be evaluated.

Moyer, Bruce A.; Marchand, Alan P.

2000-06-01T23:59:59.000Z

160

Extraction of metals and/or metalloids from acidic media using supercritical fluids and salts  

DOE Patents [OSTI]

A method of extracting metalloid and metal species from a solid or liquid material by exposing the material to a fluid solvent, particularly supercritical carbon dioxide, containing a chelating agent is described. The chelating agent forms chelates that are soluble in the fluid to allow removal of the species from the material. In preferred embodiments, the extraction solvent is supercritical carbon dioxide and the chelating agent comprises a trialkyl phosphate, a triaryl phosphate, a trialkylphosphine oxide, a triarylphosphine oxide, or mixtures thereof. The method provides an environmentally benign process for removing contaminants from industrial waste. The method is particularly useful for extracting actinides from acidic solutions, and the process can be aided by the addition of nitrate salts. The chelate and supercritical fluid can be regenerated, and the contaminant species recovered, to provide an economic, efficient process.

Wai, Chien M. (Moscow, ID); Smart, Neil G. (Moscow, ID); Lin, Yuehe (Moscow, ID)

1998-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "nitrate salt central" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Extraction of metals and/or metalloids from acidic media using supercritical fluids and salts  

DOE Patents [OSTI]

A method is described for extracting metalloid and metal species from a solid or liquid material by exposing the material to a fluid solvent, particularly supercritical carbon dioxide, containing a chelating agent. The chelating agent forms chelates that are soluble in the fluid to allow removal of the species from the material. In preferred embodiments, the extraction solvent is supercritical carbon dioxide and the chelating agent comprises a trialkyl phosphate, a triaryl phosphate, a trialkylphosphine oxide, a triarylphosphine oxide, or mixtures thereof. The method provides an environmentally benign process for removing contaminants from industrial waste. The method is particularly useful for extracting actinides from acidic solutions, and the process can be aided by the addition of nitrate salts. The chelate and supercritical fluid can be regenerated, and the contaminant species recovered, to provide an economic, efficient process. 7 figs.

Wai, C.M.; Smart, N.G.; Lin, Y.

1998-06-23T23:59:59.000Z

162

West Central School Corp | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 NoPublic Utilities Address: 160 East 300 South Place: SaltTroyer & AssociatesWest Central School Corp Facility

163

Combined Utilization of Cation Exchanger and Neutral Receptor to Volume Reduction of Alkaline Tank Waste by Separation of Sodium Salts  

SciTech Connect (OSTI)

In this report, novel approaches to the selective liquid-liquid extraction separation of sodium hydroxide and sodium nitrate from high-level alkaline tank waste will be discussed. Sodium hydroxide can be successfully separated from alkaline tank-waste supernatants by weakly acidic lipophilic hydroxy compounds via a cation-exchange mechanism referred to as pseudo hydroxide extraction. In a multi-cycle process, as sodium hydroxide in the aqueous phase becomes depleted, it is helpful to have a neutral sodium receptor in the extraction system to exploit the high nitrate concentration in the waste solution to promote sodium removal by an ion-pair extraction process. Simultaneous utilization of an ionizable organic hydroxy compound and a neutral extractant (crown ether) in an organic phase results in the synergistic enhancement of ion exchange and improved separation selectivity due to the receptor's strong and selective sodium binding. Moreover, combination of the hydroxy compound and the crown ether provides for mutually increased solubility, even in a non-polar organic solvent. Accordingly, application of Isopar{reg_sign} L, a kerosene-like alkane solvent, becomes feasible. This investigation involves examination of such dual-mechanism extraction phases for sodium extraction from simulated and actual salt cake waste solutions. Sodium salts can be regenerated upon the contact of the loaded extraction phases with water. Finally, conditions of potential extraction/strip cycling will be discussed.

Levitskaia, Tatiana G.; Lumetta, Gregg J.; Moyer, Bruce A.

2004-03-29T23:59:59.000Z

164

Critical Parameters of Complex Geometries of Intersecting Cylinders Containing Uranyl Nitrate Solution  

SciTech Connect (OSTI)

About three dozen previously unreported critical configurations are presented for very complex geometries filled with high concentration enriched uranyl nitrate solution. These geometries resemble a tall, thin Central Column (or trunk of a ''tree'') having long, thin arms (or ''branches'') extending up to four directions off the column. Arms are equally spaced from one another in vertical planes, and that spacing ranges from arms in contact to quite wide spacings. Both the Central Column and the many different arms are critically safe by themselves with each, alone, is filled with fissile solution; but, in combination, criticality occurs due to the interactions between arms and the column. Such neutronic interactions formed the principal focus of this study. While these results are fresh to the nuclear criticality safety industry and to those seeking novel experiments against which to validate computer codes, the experiments, themselves, are not recent. Over 100 experiments were performed at the Rocky Flats Critical Mass Laboratory between September, 1967, and February of the following year.

J. B. Briggs (INEEL POC); R. E. Rothe

1999-06-14T23:59:59.000Z

165

Ion Recognition Approach to Volume Reduction of Alkaline Tank Waste by Separation of Sodium Salts  

SciTech Connect (OSTI)

In this project, now completing its third year of its second renewal period, a collaborative project involving Oak Ridge National Laboratory, Pacific Northwest National Laboratory, and the University of North Texas has been addressing outstanding questions regarding the separation of the bulk sodium constituents of alkaline tank waste. The principal potential benefit of this research is a major reduction in the volume of radioactive tank waste, obviating the building of expensive new tanks and reducing the costs of vitrification. As a general approach, principles of ion recognition are being explored toward discovery and basic understanding of liquid-liquid extraction systems that selectively separate sodium hydroxide and sodium salts from waste-like matrices. Questions being addressed pertain to applicable extraction equilibria and how extraction properties relate to extractant structure. Progress has included the elucidation of the promising concept of pseudo hydroxide extraction (PHE), demonstration of crown-ether synergized PHE, demonstration of combined sodium hydroxide/sodium nitrate separation, and synthesis of novel ditopic receptors for ditopic PHE. In future efforts (pending renewal), a thermochemical study of PHE relating extractant acidity to extraction strength is proposed, and this study will be extended to systems containing crown ethers, including proton-ionizable ones. A series of crown ethers will be synthesized for this purpose and to investigate the extraction of bulk sodium salts (e.g., nitrate, nitrite, and sulfate), possibly in combination with sodium hydroxide. Simple proof-of-principle tests with real tank waste at PNNL will provide feedback toward solvent designs that have desirable properties. In view of the upcoming milestone of completion of the second renewal period, this report will, in addition to providing a summary of the past year's progress, summarize all of the work completed since the start of this project.

Moyer, Bruce A.; Marchand, Alan P.; Lumetta, Gregg J.

2004-06-30T23:59:59.000Z

166

Novel coordination geometries in fluoroaluminate salts  

SciTech Connect (OSTI)

Two tetramethylammonium salts of new fluoroaluminate species have been crystallographically characterized and reveal structural motifs previously unknown for such species. The elusive tetrahedral [AlF[sub 4][sup [minus

Herron, N.; Harlow, R.L.; Thorn, D.L. (E.I. du Pont de Nemours and Comp., Wilmington, DE (United States))

1993-07-07T23:59:59.000Z

167

Molten salt destruction of energetic waste materials  

DOE Patents [OSTI]

A molten salt destruction process is used to treat and destroy energetic waste materials such as high explosives, propellants, and rocket fuels. The energetic material is pre-blended with a solid or fluid diluent in safe proportions to form a fluid fuel mixture. The fuel mixture is rapidly introduced into a high temperature molten salt bath. A stream of molten salt is removed from the vessel and may be recycled as diluent. Additionally, the molten salt stream may be pumped from the reactor, circulated outside the reactor for further processing, and delivered back into the reactor or cooled and circulated to the feed delivery system to further dilute the fuel mixture entering the reactor.

Brummond, William A. (Livermore, CA); Upadhye, Ravindra S. (Pleasanton, CA); Pruneda, Cesar O. (Livermore, CA)

1995-01-01T23:59:59.000Z

168

Molten salt destruction of energetic waste materials  

DOE Patents [OSTI]

A molten salt destruction process is used to treat and destroy energetic waste materials such as high explosives, propellants, and rocket fuels. The energetic material is pre-blended with a solid or fluid diluent in safe proportions to form a fluid fuel mixture. The fuel mixture is rapidly introduced into a high temperature molten salt bath. A stream of molten salt is removed from the vessel and may be recycled as diluent. Additionally, the molten salt stream may be pumped from the reactor, circulated outside the reactor for further processing, and delivered back into the reactor or cooled and circulated to the feed delivery system to further dilute the fuel mixture entering the reactor. 4 figs.

Brummond, W.A.; Upadhye, R.S.; Pruneda, C.O.

1995-07-18T23:59:59.000Z

169

Salt Lake City- High Performance Buildings Requirement  

Broader source: Energy.gov [DOE]

Salt Lake City's mayor issued an executive order in July 2005 requiring that all public buildings owned and controlled by the city be built or renovated to meet the requirements of LEED "silver"...

170

Ion Recognition Approach to Volume Reduction of Alkaline Tank Waste by Separation of Sodium Salts  

SciTech Connect (OSTI)

The purpose of this research involving collaboration between Oak Ridge National Laboratory (ORNL) and Pacific Northwest National Laboratory (PNNL) is to explore new approaches to the separation of sodium hydroxide, sodium nitrate, and other sodium salts from high-level alkaline tank waste. The principal potential benefit is a major reduction in disposed waste volume, obviating the building of expensive new waste tanks and reducing the costs of vitrification. Principles of ion recognition are being researched toward discovery of liquid-liquid extraction systems that selectively separate sodium hydroxide and sodium nitrate from other waste components. The successful concept of pseudo hydroxide extraction using fluorinated alcohols and phenols is being developed at ORNL and PNNL toward a greater understanding of the controlling equilibria, role of solvation, and of synergistic effects involving crown ethers. Synthesis efforts are being directed toward enhanced sodium binding by crown ethers, both neutral and proton-ionizable. Studies with real tank waste at PNNL will provide feedback toward solvent compositions that have promising properties.

Moyer, Bruce A.; Bonnesen, Peter V.; Custelcean, Radu; Delmau, Laetitia H.; Engle, Nancy L.; Kang, Hyun-Ah; Keever, Tamara J.; Marchand, Alan P.; Gadthula, Srinivas; Gore, Vinayak K.; Huang, Zilin; Sivappa, Rasapalli; Tirunahari, Pavan K.; Levitskaia, Tatiana G.; Lumetta, Gregg J.

2005-09-26T23:59:59.000Z

171

Low temperature oxidation using support molten salt catalysts  

DOE Patents [OSTI]

Molten salt reactions are performed by supporting the molten salt on a particulate support and forming a fluidized bed of the supported salt particles. The method is particularly suitable for combusting hydrocarbon fuels at reduced temperatures, so that the formation NO.sub.x species is reduced. When certain preferred salts are used, such as alkali metal carbonates, sulfur and halide species can be captured by the molten salt, thereby reducing SO.sub.x and HCl emissions.

Weimer, Alan W.; Czerpak, Peter J.; Hilbert, Patrick M.

2003-05-20T23:59:59.000Z

172

Chemistry control and corrosion mitigation of heat transfer salts for the fluoride salt reactor (FHR)  

SciTech Connect (OSTI)

The Molten Salt Reactor Experiment (MSRE) was a prototype nuclear reactor which operated from 1965 to 1969 at Oak Ridge National Laboratory. The MSRE used liquid fluoride salts as a heat transfer fluid and solvent for fluoride based {sup 235}U and {sup 233}U fuel. Extensive research was performed in order to optimize the removal of oxide and metal impurities from the reactor's heat transfer salt, 2LiF-BeF{sub 2} (FLiBe). This was done by sparging a mixture of anhydrous hydrofluoric acid and hydrogen gas through the FLiBe at elevated temperatures. The hydrofluoric acid reacted with oxides and hydroxides, fluorinating them while simultaneously releasing water vapor. Metal impurities such as iron and chromium were reduced by hydrogen gas and filtered out of the salt. By removing these impurities, the corrosion of reactor components was minimized. The Univ. of Wisconsin - Madison is currently researching a new chemical purification process for fluoride salts that make use of a less dangerous cleaning gas, nitrogen trifluoride. Nitrogen trifluoride has been predicted as a superior fluorinating agent for fluoride salts. These purified salts will subsequently be used for static and loop corrosion tests on a variety of reactor materials to ensure materials compatibility for the new FHR designs. Demonstration of chemistry control methodologies along with potential reduction in corrosion is essential for the use of a fluoride salts in a next generator nuclear reactor system. (authors)

Kelleher, B. C.; Sellers, S. R.; Anderson, M. H.; Sridharan, K.; Scheele, R. D. [Dept. of Engineering Physics, Univ.of Wisconsin - Madison, 1500 Engineering Drive, Madison, WI 53706 (United States)

2012-07-01T23:59:59.000Z

173

CX-004179: Categorical Exclusion Determination | Department of...  

Broader source: Energy.gov (indexed) [DOE]

on nitric acid solutions as a function of the addition of the following salts: Aluminum nitrate, Lead nitrate, Cesium nitrate, Sodium nitrate and Potassium nitrate. The VLE...

174

--No Title--  

Broader source: Energy.gov (indexed) [DOE]

on nitric acid solutions as a function of the addition of the following salts: Aluminum nitrate, Lead nitrate, Cesium nitrate, sodium nitrate and potassium nitrate. The VLE...

175

Hybrid solar central receiver for combined cycle power plant  

DOE Patents [OSTI]

A hybrid combined cycle power plant is described including a solar central receiver for receiving solar radiation and converting it to thermal energy. The power plant includes a molten salt heat transfer medium for transferring the thermal energy to an air heater. The air heater uses the thermal energy to preheat the air from the compressor of the gas cycle. The exhaust gases from the gas cycle are directed to a steam turbine for additional energy production. 1 figure.

Bharathan, D.; Bohn, M.S.; Williams, T.A.

1995-05-23T23:59:59.000Z

176

Hybrid solar central receiver for combined cycle power plant  

DOE Patents [OSTI]

A hybrid combined cycle power plant including a solar central receiver for receiving solar radiation and converting it to thermal energy. The power plant includes a molten salt heat transfer medium for transferring the thermal energy to an air heater. The air heater uses the thermal energy to preheat the air from the compressor of the gas cycle. The exhaust gases from the gas cycle are directed to a steam turbine for additional energy production.

Bharathan, Desikan (Lakewood, CO); Bohn, Mark S. (Golden, CO); Williams, Thomas A. (Arvada, CO)

1995-01-01T23:59:59.000Z

177

Geology of Damon Mound Salt Dome, Texas  

SciTech Connect (OSTI)

Geological investigation of the stratigraphy, cap-rock characteristics, deformation and growth history, and growth rate of a shallow coastal diapir. Damon Mound salt dome, located in Brazoria County, has salt less than 600 feet and cap rock less than 100 feet below the surface; a quarry over the dome provides excellent exposures of cap rock as well as overlying Oligocene to Pleistocene strata. These conditions make it ideal as a case study for other coastal diapirs that lack bedrock exposures. Such investigations are important because salt domes are currently being considered by chemical waste disposal companies as possible storage and disposal sites. In this book, the author reviews previous research, presents additional data on the subsurface and surface geology at Damon Mound, and evaluates Oligocene to post-Pleistocene diapir growth.

Collins, E.W.

1989-01-01T23:59:59.000Z

178

Brine flow in heated geologic salt.  

SciTech Connect (OSTI)

This report is a summary of the physical processes, primary governing equations, solution approaches, and historic testing related to brine migration in geologic salt. Although most information presented in this report is not new, we synthesize a large amount of material scattered across dozens of laboratory reports, journal papers, conference proceedings, and textbooks. We present a mathematical description of the governing brine flow mechanisms in geologic salt. We outline the general coupled thermal, multi-phase hydrologic, and mechanical processes. We derive these processes' governing equations, which can be used to predict brine flow. These equations are valid under a wide variety of conditions applicable to radioactive waste disposal in rooms and boreholes excavated into geologic salt.

Kuhlman, Kristopher L.; Malama, Bwalya

2013-03-01T23:59:59.000Z

179

Thermal storage for solar cooling using paired ammoniated salt reactors. Final report  

SciTech Connect (OSTI)

The objectives of the program were to investigate the feasibility of using various solid and liquid ammoniates in heat pump/thermal storage systems for space heating and cooling. The study included corrosion testing of selected metallic and non-metallic specimens in the ammoniates, subscale testing of the candidate ammoniates singly and in pairs, trade studies and conceptual design of a residential system, prototype testing, and ammoniation/deammoniation cyclic testing of manganese chloride. Results of the corrosion testing showed that problems exist with manganese and magnesium chloride ammoniates, except with the teflon which displayed excellent resistance in all environments. Also, all liquid ammoniates are unsuitable for use with uncoated carbon steel. Cycling of the manganese chloride between the high and low ammoniates does not affect its properties. However, the density change between the high and low ammoniates could cause packing problems in a reactor which constrains the salt volume. Subscale tests with solid ammoniates indicated that the heat transfer coefficient in a fixed bed reactor is low (approx. 1 Btu/h-ft/sup 2/-/sup 0/F). Therefore solid ammoniates are not practical because of the high heat exchanger cost requirement. Forced ammonia recirculation was tested as a means of increasing heat transfer rate in the fixed bed reactor with solid salts, but was not successful. Conversely, the subscale testing with liquid ammoniates produced heat transfer coefficients of 40 to 45 Btu/h-ft/sup 2/-/sup 0/F. Thus, the residential design was based on a liquid ammoniate/ammonia system using ammonium nitrate as the salt.

Not Available

1981-09-01T23:59:59.000Z

180

Real time in situ detection of organic nitrates in atmospheric aerosols  

SciTech Connect (OSTI)

A new field instrument is described that quantifies total particle phase organic nitrates. The instrument is based on the thermal dissociation laser induced fluorescence (TD-LIF) method that thermally converts nitrates to NO2 which is then detected by LIF. This instrument is unique in its ability to provide fast sensitive measurements of particle phase organic nitrates, without interference from inorganic nitrate. Here we use it to quantify organic nitrates in SOA generated from high-NOx photooxidation of limonene, a-pinene, D-3-carene, and tridecane. In these experiments the organic nitrate moiety is observed to be 6-15percent of the total SOA mass, depending on the organic precursor.

Rollins, Andrew W.; Smith, Jared D.; Wilson, Kevin R.; Cohen, Ronald C.

2010-06-11T23:59:59.000Z

Note: This page contains sample records for the topic "nitrate salt central" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Control of Soluble Salts in Farming and Gardening.  

E-Print Network [OSTI]

waters pass through beds of salt, dissolving appreciable quantities before they emerge and enter the rivers. Ocean waters, much too salty for irrigation, contain about 3 percent salt, or about 40 tons of salt per acre-foot of water... ater are applied each year are shown in Table 2. Salts I (.in ilrcnmulate very rapidly. The water containing 1 ton of jdt per acre-foot is generally considered to be good ,I~,~lit\\* water, yet in 2 years enough salt could accumu- I,ltr to harm salt...

Longenecker, D. E.; Lyerly, P. J.

1974-01-01T23:59:59.000Z

182

Method for using salt deposits for storage  

SciTech Connect (OSTI)

A method for developing, evacuating, using, sealing, and re-entering multiple stacked cavities which are created from a single well in salt deposits. The cavities are created in a salt deposit by circulating raw water through concentric casing strings in the well. Each of the cavities is evacuated of liquids prior to use. After storage material is injected into a cavity, the cavity is sealed by setting a plug in the well bore above the top of the cavity. The cavities may be re-entered by drilling out the plug or by drilling a directional well directly into the cavity.

Hooper, M. W.; Voorhees, E. J.

1984-12-18T23:59:59.000Z

183

The Salt Industry at Sterling, Kansas  

E-Print Network [OSTI]

. Exhaust stean of the engine plant is ad- mitted to the first evaporator and warms the "brine, then passes to the second and warns it lesD and condenses, causing a partial vacuum in the first where the brine then boils violent- ly. The vapor thus... and is condensed by a jet condenser, whereupon the third boils. Each evaporator has its own electric prop- eller stirrers and its own electric elevator to remove the salt. Nearly all the handling is done by electric conveyors until the salt is discharged...

Horner, Robert Messenger

1914-01-01T23:59:59.000Z

184

E-Print Network 3.0 - ammonium nitrate melt Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

on Peat Decomposition in Plum Summary: , phosphate, ammonium and DIC on all of the water samples. Nitrate concentrations were measured according... ;11 indicating greater...

185

Micro- and Mini-nitrate Sensors for Monitoring of Soils, Groundwater and Aquatic Systems  

E-Print Network [OSTI]

Nitrate Mini-Sensor with PVC membrane containing liquidmin) Mini-sensors with PVC maintain their sensitivity duringfabricated mini- sensors with PVC membranes showed better

2009-01-01T23:59:59.000Z

186

E-Print Network 3.0 - alkaline nitrate solutions Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

2010 www.atmos-chem-phys.net1039992010 Summary: . The model in- cludes explicit transport of size-resolved mineral dust and its alkalinity, nitrate... in terms of...

187

E-Print Network 3.0 - anaerobic nitrate-dependent oxidation Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of the experiment... nitrate- dependent Fe(II) ... Source: Roden, Eric E. - Department of Geology and Geophysics, University of Wisconsin at Madison Collection: Environmental...

188

Ureides in active and nitrate-repressed soybean nodules  

E-Print Network [OSTI]

) detected ureides in his final preparations of two acid soluble peptides which seemed to be associated with nitrogen fixation. He presented evidence that these crude preparations were able to: A) bind and release NH ; and 8) reduce the triple bond... (----1 of nitrate, were analyzed on a Beckman 120B automatic amino acid analyzer. The post arginine peaks (I, II, III) were measured. 38 Table 4. The Effect of N03 on Acid-Soluble Peptide(s) from Soybean Nodules. Acid-soluble ex- tracts were...

Bundy, Timothy K.

1983-01-01T23:59:59.000Z

189

Hybrid Molten Salt Reactor (HMSR) System Study  

SciTech Connect (OSTI)

Can the hybrid system combination of (1) a critical fission Molten Salt Reactor (MSR) having a thermal spectrum and a high Conversion Ratio (CR) with (2) an external source of high energy neutrons provide an attractive solution to the world's expanding demand for energy? The present study indicates the answer is an emphatic yes.

Woolley, Robert D [PPPL; Miller, Laurence F [PPPL

2014-04-01T23:59:59.000Z

190

Salt caverns for oil field waste disposal.  

SciTech Connect (OSTI)

Salt caverns used for oil field waste disposal are created in salt formations by solution mining. When created, caverns are filled with brine. Wastes are introduced into the cavern by pumping them under low pressure. Each barrel of waste injected to the cavern displaces a barrel of brine to the surface. The brine is either used for drilling mud or is disposed of in an injection well. Figure 8 shows an injection pump used at disposal cavern facilities in west Texas. Several types of oil field waste may be pumped into caverns for disposal. These include drilling muds, drill cuttings, produced sands, tank bottoms, contaminated soil, and completion and stimulation wastes. Waste blending facilities are constructed at the site of cavern disposal to mix the waste into a brine solution prior to injection. Overall advantages of salt cavern disposal include a medium price range for disposal cost, large capacity and availability of salt caverns, limited surface land requirement, increased safety, and ease of establishment of individual state regulations.

Veil, J.; Ford, J.; Rawn-Schatzinger, V.; Environmental Assessment; RMC, Consultants, Inc.

2000-07-01T23:59:59.000Z

191

Salt repository project closeout status report  

SciTech Connect (OSTI)

This report provides an overview of the scope and status of the US Department of Energy (DOE`s) Salt Repository Project (SRP) at the time when the project was terminated by the Nuclear Waste Policy Amendments Act of 1987. The report reviews the 10-year program of siting a geologic repository for high-level nuclear waste in rock salt formations. Its purpose is to aid persons interested in the information developed during the course of this effort. Each area is briefly described and the major items of information are noted. This report, the three salt Environmental Assessments, and the Site Characterization Plan are the suggested starting points for any search of the literature and information developed by the program participants. Prior to termination, DOE was preparing to characterize three candidate sites for the first mined geologic repository for the permanent disposal of high-level nuclear waste. The sites were in Nevada, a site in volcanic tuff; Texas, a site in bedded salt (halite); and Washington, a site in basalt. These sites, identified by the screening process described in Chapter 3, were selected from the nine potentially acceptable sites shown on Figure I-1. These sites were identified in accordance with provisions of the Nuclear Waste Policy Act of 1982. 196 refs., 21 figs., 11 tabs.

NONE

1988-06-01T23:59:59.000Z

192

Accelerators for Subcritical Molten-Salt Reactors  

SciTech Connect (OSTI)

Accelerator parameters for subcritical reactors have usually been based on using solid nuclear fuel much like that used in all operating critical reactors as well as the thorium burning accelerator-driven energy amplifier proposed by Rubbia et al. An attractive alternative reactor design that used molten salt fuel was experimentally studied at ORNL in the 1960s, where a critical molten salt reactor was successfully operated using enriched U235 or U233 tetrafluoride fuels. These experiments give confidence that an accelerator-driven subcritical molten salt reactor will work better than conventional reactors, having better efficiency due to their higher operating temperature, having the inherent safety of subcritical operation, and having constant purging of volatile radioactive elements to eliminate their accumulation and potential accidental release in dangerous amounts. Moreover, the requirements to drive a molten salt reactor can be considerably relaxed compared to a solid fuel reactor, especially regarding accelerator reliability and spallation neutron targetry, to the point that much of the required technology exists today. It is proposed that Project-X be developed into a prototype commercial machine to produce energy for the world by, for example, burning thorium in India and nuclear waste from conventional reactors in the USA.

Johnson, Roland (Muons, Inc.) [Muons, Inc.

2011-08-03T23:59:59.000Z

193

Crushed-salt constitutive model update  

SciTech Connect (OSTI)

Modifications to the constitutive model used to describe the deformation of crushed salt are presented in this report. Two mechanisms--dislocation creep and grain boundary diffusional pressure solutioning--defined previously but used separately are combined to form the basis for the constitutive model governing the deformation of crushed salt. The constitutive model is generalized to represent three-dimensional states of stress. New creep consolidation tests are combined with an existing database that includes hydrostatic consolidation and shear consolidation tests conducted on Waste Isolation Pilot Plant and southeastern New Mexico salt to determine material parameters for the constitutive model. Nonlinear least-squares model fitting to data from the shear consolidation tests and a combination of the shear and hydrostatic consolidation tests produced two sets of material parameter values for the model. The change in material parameter values from test group to test group indicates the empirical nature of the model but demonstrates improvement over earlier work with the previous models. Key improvements are the ability to capture lateral strain reversal and better resolve parameter values. To demonstrate the predictive capability of the model, each parameter value set was used to predict each of the tests in the database. Based on the fitting statistics and the ability of the model to predict the test data, the model appears to capture the creep consolidation behavior of crushed salt quite well.

Callahan, G.D.; Loken, M.C.; Mellegard, K.D. [RE/SPEC Inc., Rapid City, SD (United States); Hansen, F.D. [Sandia National Labs., Albuquerque, NM (United States)

1998-01-01T23:59:59.000Z

194

Constitutive behavior of reconsolidating crushed salt  

SciTech Connect (OSTI)

The constitutive model used to describe deformation of crushed salt is presented in this paper. Two mechanisms--dislocation creep and grain boundary diffusional pressure solutioning--are combined to form the basis for the constitutive model governing deformation of crushed salt. The constitutive model is generalized to represent three-dimensional states of stress. Recently completed creep consolidation tests are combined with an existing database that includes hydrostatic consolidation and shear consolidation tests conducted on Waste Isolation Pilot Plant (WIPP) and southeastern New Mexico salt to determine material parameters for the constitutive model. Nonlinear least-squares model fitting to data from shear consolidation tests and a combination of shear and hydrostatic tests produces two sets of material parameter values for the model. Changes in material parameter values from test group to test group indicate the empirical nature of the model but show significant improvement over earlier work. To demonstrate the predictive capability of the model, each parameter value set was used to predict each of the tests in the database. Based on fitting statistics and ability of the model to predict test data, the model appears to capture the creep consolidation behavior of crushed salt quite well.

Callahan, G.D.; Mellegard, K.D. [RE/SPEC, Inc., Rapid City, SD (United States); Hansen, F.D. [Sandia National Labs., Carlsbad, NM (United States)

1998-02-01T23:59:59.000Z

195

Corrosion Studies in High-Temperature Molten Salt Systems for...  

Broader source: Energy.gov (indexed) [DOE]

Corrosion Studies in High-Temperature Molten Salt Systems for CSP Applications - FY13 Q1 Corrosion Studies in High-Temperature Molten Salt Systems for CSP Applications - FY13 Q1...

196

Ketone Production from the Thermal Decomposition of Carboxylate Salts  

E-Print Network [OSTI]

The MixAlco process uses an anaerobic, mixed-culture fermentation to convert lignocellulosic biomass to carboxylate salts. The fermentation broth must be clarified so that only carboxylate salts, water, and minimal impurities remain. Carboxylate...

Landoll, Michael 1984-

2012-08-15T23:59:59.000Z

197

Thorium Molten Salt Reactor : from high breeding to simplified reprocessing  

E-Print Network [OSTI]

Thorium Molten Salt Reactor : from high breeding to simplified reprocessing L. Mathieu, D. Heuer, A- ceptable. The Thorium Molten Salt Reactor (TMSR) may contribute to solve these problems. The thorium cycle

Paris-Sud XI, Université de

198

Colloidal stability of magnetic nanoparticles in molten salts  

E-Print Network [OSTI]

Molten salts are important heat transfer fluids used in nuclear, solar and other high temperature engineering systems. Dispersing nanoparticles in molten salts can enhance the heat transfer capabilities of the fluid. High ...

Somani, Vaibhav (Vaibhav Basantkumar)

2010-01-01T23:59:59.000Z

199

Tank 41-H salt level fill history 1985 to 1987  

SciTech Connect (OSTI)

The fill rate of the evaporator drop waste tank (i.e., salt tank) at Savannah River Site contained in the Waste Management Technology (WMT) monthly data record is based upon a simple formula that apportioned 10 percent of the evaporator output concentrate to the salt fill volume. Periodically, the liquid level of the salt tank would be decanted below the salt level surface and a visual inspection of the salt profile would be accomplished. The salt volume of the drop tank would then be corrected, if necessary, based upon the visual elevation of the salt formation. This correction can erroneously indicate an excess amount of salt fill occurred in a short time period. This report established the correct fill history for Tank 41H.

Ross, R.H.

1996-05-16T23:59:59.000Z

200

Recipient: Lay of Salt Lake ENERGY EFFICIENCY AND CONSERVATION...  

Broader source: Energy.gov (indexed) [DOE]

with this CX. Salt Lake City Traffic Signal Management B5.1 None. Salt Lake City Bicycle Transit Center Task as submitted is not within scope of FOA and not eligible for...

Note: This page contains sample records for the topic "nitrate salt central" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Method for preparing salt solutions having desired properties  

DOE Patents [OSTI]

The specification discloses a method for preparing salt solutions which exhibit desired thermodynamic properties. The method enables prediction of the value of the thermodynamic properties for single and multiple salt solutions over a wide range of conditions from activity data and constants which are independent of concentration and temperature. A particular application of the invention is in the control of salt solutions in a process to provide a salt solution which exhibits the desired properties.

Ally, Moonis R. (Oak Ridge, TN); Braunstein, Jerry (Clinton, TN)

1994-01-01T23:59:59.000Z

202

Energy Efficient Buildings, Salt Lake County, Utah  

SciTech Connect (OSTI)

Executive Summary Salt Lake County's Solar Photovoltaic Project - an unprecedented public/private partnership Salt Lake County is pleased to announce the completion of its unprecedented solar photovoltaic (PV) installation on the Calvin R. Rampton Salt Palace Convention Center. This 1.65 MW installation will be one the largest solar roof top installations in the country and will more than double the current installed solar capacity in the state of Utah. Construction is complete and the system will be operational in May 2012. The County has accomplished this project using a Power Purchase Agreement (PPA) financing model. In a PPA model a third-party solar developer will finance, develop, own, operate, and maintain the solar array. Salt Lake County will lease its roof, and purchase the power from this third-party under a long-term Power Purchase Agreement contract. In fact, this will be one of the first projects in the state of Utah to take advantage of the recent (March 2010) legislation which makes PPA models possible for projects of this type. In addition to utilizing a PPA, this solar project will employ public and private capital, Energy Efficiency and Conservation Block Grants (EECBG), and public/private subsidized bonds that are able to work together efficiently because of the recent stimulus bill. The project also makes use of recent changes to federal tax rules, and the recent re-awakening of private capital markets that make a significant public-private partnership possible. This is an extremely innovative project, and will mark the first time that all of these incentives (EECBG grants, Qualified Energy Conservation Bonds, New Markets tax credits, investment tax credits, public and private funds) have been packaged into one project. All of Salt Lake County's research documents and studies, agreements, and technical information is available to the public. In addition, the County has already shared a variety of information with the public through webinars, site tours, presentations, and written correspondence.

Barnett, Kimberly

2012-04-30T23:59:59.000Z

203

Salt-stone Oxidation Study: Leaching Method - 13092  

SciTech Connect (OSTI)

Cementitious waste forms can be designed to chemically stabilize selected contaminants, such as Tc{sup +7} and Cr{sup +6}, by chemically reduction to lower valance states, Tc{sup +4} and Cr{sup +3}, respectively, and precipitation of these species in alkaline media as low solubility solid phases. Data for oxidation of this type of cementitious waste form cured under field conditions as a function of time is required for predicting the performance of the waste form and disposal facility. The rate of oxidation (oxidation front advancement) is an important parameter for predicting performance because the solubilities of some radionuclide contaminants, e.g., technetium, are a function of the oxidation state. A non-radioactive experiment was designed for quantifying the oxidation front advancement using chromium, as an approximate redox-sensitive surrogate (Cr{sup +6} / Cr{sup +3}) for technetium (Tc{sup +7} / Tc{sup +4}). Nonradioactive cementitious waste forms were prepared in the laboratory and cured under both laboratory and 'field conditions'. Laboratory conditions were ambient temperature and sealed sample containers. Field conditions were approximated by curing samples in open containers which were placed inside a plastic container stored outdoors at SRS. The container had a lid and was instrumented with temperature and humidity probes. Sub-samples as thin as 0.2 mm were taken as a function of distance from the exposed surface of the as-cast sample. The sub-samples were leached and the leachates were analyzed for chromium, nitrate, nitrite and sodium. Nitrate, nitrite, and sodium concentrations were used to provide baseline data because these species are not chemically retained in the waste form matrix to any significant extent and are not redox sensitive. 'Effective' oxidation fronts for Cr were measured for samples containing 1000, 500 and 20 mg/kg Cr added as soluble sodium chromate, Na{sub 2}CrO{sub 4}. For a sample cured for 129 days under field conditions, leachable Cr (assumed to be the oxidized form, i.e., Cr{sup +6} was detected in the top 15 to 20 mm of the sample spiked with 1000 mg/kg Cr. Below about 20 mm, the Cr concentrations in leachates were below the detection limit (< 0.010 mg/L) which indicates that the oxidation as the result of exposure to air was limited to the top 20 mm of the sample after exposure for 129 days and that the bulk of the waste form was not affected, i.e., the Cr was stabilized and insoluble. For samples cured in the laboratory, leachable Cr was detected in the top 8 mm of the Cr 1000 sample cured in the laboratory for 37 days. Between 8 and 14 mm, the concentration Cr in the leachate dropped by a factor of about 20 to just above the detection limit. These depth of penetration results indicate that the rate of advancement of the oxidation front for samples spiked with 1000 mg/kg Cr cured under 'field conditions' for 129 days is less than that for the sample cured in the laboratory for 37 days, i.e., 0.156 and 0.216 mm/day, respectively. Additional data are presented for samples spiked with 500 and 20 mg/kg Cr. In summary, cementitious waste forms are porous solids with a network of interconnected pores ranging in diameter from 10 E-10 m to greater than a few mm. The oxidation process is assumed to occur as the result of oxygen transport through the interconnected porosity which may be filled with air, aqueous salt solution, or both. Upon oxidation, the Cr becomes soluble and can be transported in solution through aqueous pore fluid or leachate. (authors)

Langton, C.A.; Stefanko, D.B.; Burns, H.H. [Savannah River National Laboratory, Savannah River Remediation, LLC, Savannah River Site, Aiken, SC 29808 (United States)] [Savannah River National Laboratory, Savannah River Remediation, LLC, Savannah River Site, Aiken, SC 29808 (United States)

2013-07-01T23:59:59.000Z

204

SOLUTION MINING IN SALT DOMES OF THE GULF COAST EMBAYMENT  

SciTech Connect (OSTI)

Following a description of salt resources in the salt domes of the gulf coast embayment, mining, particularly solution mining, is described. A scenario is constructed which could lead to release of radioactive waste stored in a salt dome via inadvertent solution mining and the consequences of this scenario are analyzed.

Griswold, G. B.

1981-02-01T23:59:59.000Z

205

Production of carboxylic acid and salt co-products  

DOE Patents [OSTI]

This invention provide processes for producing carboxylic acid product, along with useful salts. The carboxylic acid product that is produced according to this invention is preferably a C.sub.2-C.sub.12 carboxylic acid. Among the salts produced in the process of the invention are ammonium salts.

Hanchar, Robert J.; Kleff, Susanne; Guettler, Michael V.

2014-09-09T23:59:59.000Z

206

Structural restoration of Louann Salt and overlying sediments, De Soto Canyon Salt Basin, northeastern Gulf of Mexico  

E-Print Network [OSTI]

The continental margin of the northeastern Gulf of Mexico is suited for seismic stratigraphic analysis and salt tectonism analysis. Jurassic strata include the Louann Salt on the continental shelf and upper slope of the Destin Dome OCS area...

Guo, Mengdong

1997-01-01T23:59:59.000Z

207

Seismic stratigraphy and salt tectonics of the Alaminos Canyon area, Gulf of Mexico.  

E-Print Network [OSTI]

morphology, salt structure, and suprasalt sediments indicate the majority of the slope is covered by a shallow salt canopy. The salt structure map indicates that the Alaminos Canyon study area represents a transition from a semi-continuous salt sheet...

Mechler, Suzanne Marie

1994-01-01T23:59:59.000Z

208

Infrared Spectroscopy of the Microhydrated Nitrate Ions NO3 Daniel J. Goebbert,,  

E-Print Network [OSTI]

Infrared Spectroscopy of the Microhydrated Nitrate Ions NO3 - (H2O)1-6 Daniel J. Goebbert ReceiVed: April 15, 2009 We present infrared photodissociation spectra of the microhydrated nitrate ions the infrared spectroscopy of NO3 - (H2O)n clusters, n ) 1-6. The gas-phase vibrational spectroscopy of NO3

Neumark, Daniel M.

209

Nitrate-responsive miR393/AFB3 regulatory module controls root system architecture in  

E-Print Network [OSTI]

environmental conditions is the modulation of root system architecture (RSA) in response to nitrate supplyNitrate-responsive miR393/AFB3 regulatory module controls root system architecture in ArabidopsisR393/AFB3 is a unique N- responsive module that controls root system architecture in response

Green, Pamela

210

Strontium sorption and precipitation behaviour during bioreduction in nitrate impacted sediments  

E-Print Network [OSTI]

radionuclides (e.g. U and Tc) from groundwaters at these sites is a key challenge for nuclear decommissioning D. Bryan a , Katherine Morris a, a Research Centre for Radwaste and Decommissioning and Williamson Nitrate Nuclear The behaviour of strontium (Sr2+ ) during microbial reduction in nitrate impacted

Burke, Ian

211

Correction to ``Nitrate and colloid transport through coarse Hanford sediments under steady state,  

E-Print Network [OSTI]

Correction to ``Nitrate and colloid transport through coarse Hanford sediments under steady state), Correction to ``Nitrate and colloid transport through coarse Hanford sediments under steady state, variably and colloid transport through coarse Hanford sediments under steady state, variably saturated flow'' by Kelly

Flury, Markus

212

The fate and transport of nitrate in shallow groundwater in northwestern Mississippi, USA  

E-Print Network [OSTI]

modeling . USA Introduction Nitrate is the primary form of dissolved nitrogen in natural waters (MuellerThe fate and transport of nitrate in shallow groundwater in northwestern Mississippi, USA Heather L. Welch & Christopher T. Green & Richard H. Coupe Abstract Agricultural contamination of groundwater

213

Organic Geochemistry of the CenomanianTuronian Bahloul Formation Petroleum Source Rock, Central and Northern Tunisia  

E-Print Network [OSTI]

1 Organic Geochemistry of the Cenomanian­Turonian Bahloul Formation Petroleum Source Rock, Central and around diapirs of the Triassic salt. Key words: Organic matter, Petroleum Source Rock, Cenomanian (TOC) determination, Rock-Eval pyrolysis, extractable organic matter content (EOM) fractionation

Paris-Sud XI, Université de

214

Radar investigation of the Cote Blanche salt dome  

E-Print Network [OSTI]

THE COTE BLANCHE SALT DOME. Geology of the Cote Blanche Salt-Dome Azea. . Economic History of the Cote BLanche Salt-Dome Azea, Salt. . Oil and gas. III. ELECTROMAGNETIC WAVE PROPAGATION. . . Radar Speed in Air and in Salt. . . Velocity...' zznd i'r. mzznz 1959) . The east, south, end west flanks are nearly vertical. However, the north side oi the dome is characterised by a massive overhang. A well drilled by Shell Oil Company, Caffrey No. 1, confirmed the presence of a minimum of 3300...

Stewart, Robert Donald

1974-01-01T23:59:59.000Z

215

Assessment of the potential for ammonium nitrate formation and reaction in Tank 241-SY-101  

SciTech Connect (OSTI)

Two principal scenarios by which ammonium nitrate may be formed were considered: (a) precipitation of ammonium nitrate in the waste, and (b) ammonium nitrate formation via the gas phase reaction of ammonia and nitrogen dioxide. The first of these can be dismissed because ammonium ions, which are necessary for ammonium nitrate precipitation, can exist only in negligibly small concentrations in strongly alkaline solutions. Gas phase reactions between ammonia, nitrogen dioxide, and water vapor in the gas phase represent the most likely means by which ammonium nitrate aerosols could be formed in Tank 241-SY-101. Predicted ammonium nitrate formation rates are largely controlled by the concentration of nitrogen dioxide. This gas has not been detected among those gases vented from the wastes using Fourier Transform Infrared Spectrometry (FTIR) or mass spectrometry. While detection limits for nitrogen dioxide have not been established experimentally, the maximum concentration of nitrogen dioxide in the gas phase in Tank 241-SY-101 was estimated at 0.1 ppm based on calculations using the HITRAN data base and on FTIR spectra of gases vented from the wastes. At 50 C and with 100 ppm ammonia also present, less than one gram of ammonium nitrate per year is estimated to be formed in the tank. To date, ammonium nitrate has not been detected on HEPA filters in the ventilation system, so any quantity that has been formed in the tank must be quite small, in good agreement with rate calculations. The potential for runaway exothermic reactions involving ammonium nitrate in Tank 241-SY-101 is minimal. Dilution by non-reacting waste components, particularly water, would prevent hazardous exothermic reactions from occurring within the waste slurry, even if ammonium nitrate were present. 41 refs.

Pederson, L.R.; Bryan, S.A.

1994-08-01T23:59:59.000Z

216

E-Print Network 3.0 - ammonium nitrate-fuel oil Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

liquids, chlorates, nitrites, sulfur, finely... hypochlorite, all oxidizing agents Carbon tetrachloride Sodium Chlorates Ammonium salts, acids, powdered metals... Ammonium...

217

Salt Wash Field, Grand Country, Utah  

SciTech Connect (OSTI)

The Salt Wash field is located 15 miles southeast of Green River, Utah, in the Paradox fold and fault belt. The field was discovered in 1961 and has produced over 1.3 million bbl of oil and 11.6 billion ft[sup 3] of gas from the Mississippian Leadville LImestone. The average surface elevation is 4389 ft above sea level, and the depth to the top of the oil production is form 8500 to 8914 ft. Salt Wash field is an anticline with over 200 ft of closure on top of the Leadville. The producing zone is in the lower Leadville with intercrystalline and vuggy porosity developed in limestone and crystalline dolomitic limestone. The produced oil is a 50 to 53 API gravity crude with a 40[degrees]F pour point. The gas, a mixture of two sources, is predominately nitrogen (>70[sup [approximately

Morgan, C.D. (Utah Geological Survey, Salt Lake City, UT (United States))

1993-08-01T23:59:59.000Z

218

Predicting viscosities of aqueous salt mixtures  

SciTech Connect (OSTI)

Viscosity plays an important role in quantifying heat and mass transfer rates as depicted in theoretical and semi-empirical correlations. In practical problems where extreme temperatures and solute concentrations are encountered, viscosity data is usually unavailable. At these conditions, no dependable correlation appears to exist in the literature. This paper uses the hole type model to predict the viscosity of aqueous electrolytes containing single and mixed salts up to the molten salt regime. This model needs two parameters which can be evaluated from sparse data. For LiBr/water and (Li, K, na) NO[sub 3]/water mixtures, it is shown that the agreement between predicted and experimental values is very good over wide temperature and concentration ranges. The deviation between these two values was found to be less than 9%.

Zaltash, A.; Ally, M.R.

1992-01-01T23:59:59.000Z

219

Predicting viscosities of aqueous salt mixtures  

SciTech Connect (OSTI)

Viscosity plays an important role in quantifying heat and mass transfer rates as depicted in theoretical and semi-empirical correlations. In practical problems where extreme temperatures and solute concentrations are encountered, viscosity data is usually unavailable. At these conditions, no dependable correlation appears to exist in the literature. This paper uses the hole type model to predict the viscosity of aqueous electrolytes containing single and mixed salts up to the molten salt regime. This model needs two parameters which can be evaluated from sparse data. For LiBr/water and (Li, K, na) NO{sub 3}/water mixtures, it is shown that the agreement between predicted and experimental values is very good over wide temperature and concentration ranges. The deviation between these two values was found to be less than 9%.

Zaltash, A.; Ally, M.R.

1992-12-01T23:59:59.000Z

220

Polymeric salt bridges for conducting electric current in microfluidic devices  

DOE Patents [OSTI]

A "cast-in-place" monolithic microporous polymer salt bridge for conducting electrical current in microfluidic devices, and methods for manufacture thereof is disclosed. Polymeric salt bridges are formed in place in capillaries or microchannels. Formulations are prepared with monomer, suitable cross-linkers, solvent, and a thermal or radiation responsive initiator. The formulation is placed in a desired location and then suitable radiation such as UV light is used to polymerize the salt bridge within a desired structural location. Embodiments are provided wherein the polymeric salt bridges have sufficient porosity to allow ionic migration without bulk flow of solvents therethrough. The salt bridges form barriers that seal against fluid pressures in excess of 5000 pounds per square inch. The salt bridges can be formulated for carriage of suitable amperage at a desired voltage, and thus microfluidic devices using such salt bridges can be specifically constructed to meet selected analytical requirements.

Shepodd, Timothy J. (Livermore, CA); Tichenor, Mark S. (San Diego, CA); Artau, Alexander (Humacao, PR)

2009-11-17T23:59:59.000Z

Note: This page contains sample records for the topic "nitrate salt central" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Cementitious Stabilization of Mixed Wastes with High Salt Loadings  

SciTech Connect (OSTI)

Salt loadings approaching 50 wt % were tolerated in cementitious waste forms that still met leach and strength criteria, addressing a Technology Deficiency of low salt loadings previously identified by the Mixed Waste Focus Area. A statistical design quantified the effect of different stabilizing ingredients and salt loading on performance at lower loadings, allowing selection of the more effective ingredients for studying the higher salt loadings. In general, the final waste form needed to consist of 25 wt % of the dry stabilizing ingredients to meet the criteria used and 25 wt % water to form a workable paste, leaving 50 wt % for waste solids. The salt loading depends on the salt content of the waste solids but could be as high as 50 wt % if all the waste solids are salt.

Spence, R.D.; Burgess, M.W.; Fedorov, V.V.; Downing, D.J.

1999-04-01T23:59:59.000Z

222

Salt Tolerance of Guayule (Parthenium argentatum).  

E-Print Network [OSTI]

TDOC Z TA245 .7 8873 NO.1651 ---- Salt Tolerance of yUayu{e ~" y r , B -1651 The Texas Agricultural Experiment Station? Charles J. Arntzen, Director? The Texas A&M University System? College Station, Texas (Blank Pille In Origblll.... ?JI. Z 0 t= -t Z :i a: w " 100~----------------------------~ 80 60 40 20 I SEmaln I SElub SELECTION o+-----~----~----~----_,----_, o 5 10 15 20 25 EC OF SOLUTION, dSm-' Figure 1. Seed germination of guayule selections as related...

Miyamoto, S.; Davis, J.; Madrid, L.

1990-01-01T23:59:59.000Z

223

Stationary phase deposition based on onium salts  

DOE Patents [OSTI]

Onium salt chemistry can be used to deposit very uniform thickness stationary phases on the wall of a gas chromatography column. In particular, the stationary phase can be bonded to non-silicon based columns, especially microfabricated metal columns. Non-silicon microfabricated columns may be manufactured and processed at a fraction of the cost of silicon-based columns. In addition, the method can be used to phase-coat conventional capillary columns or silicon-based microfabricated columns.

Wheeler, David R. (Albuquerque, NM); Lewis, Patrick R. (Albuquerque, NM); Dirk, Shawn M. (Albuquerque, NM); Trudell, Daniel E. (Albuquerque, NM)

2008-01-01T23:59:59.000Z

224

Molten Salt Heat Transfer Fluid (HTF)  

Energy Innovation Portal (Marketing Summaries) [EERE]

Sandia has developed a heat transfer fluid (HTF) for use at elevated temperatures that has a lower freezing point than any molten salt mixture available commercially. This allows the HTF to be used in applications in which the expensive parasitic energy costs necessary for freeze protection can be significantly reduced. The higher operating temperature limit significantly increases power cycle efficiency and overall power plan sun-to-net electric efficiency....

2013-03-12T23:59:59.000Z

225

Analysis of Enriched Uranyl Nitrate in Nested Annular Tank Array  

SciTech Connect (OSTI)

Two series of experiments were performed at the Rocky Flats Critical Mass Laboratory during the 1980s using highly enriched (93%) uranyl nitrate solution in annular tanks. [1, 2] Tanks were of typical sizes found in nuclear production plants. Experiments looked at tanks of varying radii in a co-located set of nested tanks, a 1 by 2 array, and a 1 by 3 array. The co-located set of tanks had been analyzed previously [3] as a benchmark for inclusion within the International Handbook of Evaluated Criticality Safety Benchmark Experiments. [4] The current study represents the benchmark analysis of the 1 by 3 array of a series of nested annular tanks. Of the seventeen configurations performed in this set of experiments, twelve were evaluated and nine were judged as acceptable benchmarks.

John D. Bess; James D. Cleaver

2009-06-01T23:59:59.000Z

226

New public information resources on salt caverns.  

SciTech Connect (OSTI)

For the past decade, interest has been growing in using underground salt caverns for disposing of wastes. The Railroad Commission of Texas has permitted a few caverns for disposal of nonhazardous oil field waste (NOW) and one cavern for disposal of naturally occurring radioactive materials (NORM) from oil field activities. Several salt caverns in Canada have also been permitted for disposal of NOW. In addition, oil and gas agencies in Louisiana and New Mexico are developing cavern disposal regulations. The US Department of Energy (DOE) has funded several studies to evaluate the technical feasibility, legality, economic viability, and risk of disposing of NOW and NORM in caverns. The results of these studies have been disseminated to the scientific and regulatory communities. However, as use of caverns for waste disposal increases, more government and industry representatives and members of the public will become aware of this practice and will need adequate information about how disposal caverns operate and the risks they pose. In anticipation of this need, DOE has funded Argonne National Laboratory to develop a salt cavern public outreach program. Key components of this program are an informational brochure designed for nontechnical persons and a website that provides greater detail on cavern operations and allows downloadable access to the reports on the topic funded by DOE. This paper provides an overview of the public outreach program.

Tomasko, D.; Veil, J. A.

1999-08-25T23:59:59.000Z

227

New public information resources on salt caverns.  

SciTech Connect (OSTI)

For the past decade, interest has been growing in using underground salt caverns for disposing of wastes. The Railroad Commission of Texas has permitted a few caverns for disposal of nonhazardous oil field waste (NOW) and one cavern for disposal of naturally occurring radioactive materials (NORM) from oil field activities. Several salt caverns in Canada have also been permitted for disposal of NOW. In addition, oil and gas agencies in Louisiana and New Mexico are developing cavern disposal regulations. The US Department of Energy (DOE) has funded several studies to evaluate the technical feasibility, legality, economic viability, and risk of disposing of NOW and NORM in caverns. The results of these studies have been disseminated to the scientific and regulatory communities. However, as use of caverns for waste disposal increases, more government and industry representatives and members of the public will become aware of this practice and will need adequate information about how disposal caverns operate and the risks they pose. In anticipation of this need, DOE has fi.mded Argonne National Laboratory to develop a salt cavern public outreach program. Key components of this program are an informational brochure designed for nontechnical persons and a website that provides greater detail on cavern operations and allows downloadable access to the reports on the topic funded by DOE. This paper provides an overview of the public outreach program.

Tomasko, D.; Veil, J. A.

1999-08-25T23:59:59.000Z

228

Reference repository design concept for bedded salt  

SciTech Connect (OSTI)

A reference design concept is presented for the subsurface portions of a nuclear waste repository in bedded salt. General geologic, geotechnical, hydrologic and geochemical data as well as descriptions of the physical systems are provided for use on generic analyses of the pre- and post-sealing performance of repositories in this geologic medium. The geology of bedded salt deposits and the regional and repository horizon stratigraphy are discussed. Structural features of salt beds including discontinuities and dissolution features are presented and their effect on repository performance is discussed. Seismic hazards and the potential effects of earthquakes on underground repositories are presented. The effect on structural stability and worker safety during construction from hydrocarbon and inorganic gases is described. Geohydrologic considerations including regional hydrology, repository scale hydrology and several hydrological failure modes are presented in detail as well as the hydrological considerations that effect repository design. Operational phase performance is discussed with respect to operations, ventilation system, shaft conveyances, waste handling and retrieval systems and receival rates of nuclear waste. Performance analysis of the post sealing period of a nuclear repository is discussed, and parameters to be used in such an analysis are presented along with regulatory constraints. Some judgements are made regarding hydrologic failure scenarios. Finally, the design and licensing process, consistent with the current licensing procedure is described in a format that can be easily understood.

Carpenter, D.W.; Martin, R.W.

1980-10-08T23:59:59.000Z

229

Selective and quantitative nitrate electroreduction to ammonium using a porous copper electrode in an electrochemical flow cell  

E-Print Network [OSTI]

,version1-10Jul2014 #12;3 1. Introduction Nitrate ions (NO3 - ) contamination of ground and surface water and physiochemical methods are used for nitrate removal from contaminated water but show drastic limits are costly [10] and produce secondary brine wastes, because the nitrate are only separated but not destroyed

Paris-Sud XI, Université de

230

Geologic technical assessment of the Stratton Ridge salt dome, Texas, for potential expansion of the U.S. strategic petroleum reserve.  

SciTech Connect (OSTI)

The Stratton Ridge salt dome is a large salt diapir located only some ten miles from the currently active Strategic Petroleum Reserve Site at Bryan Mound, Texas. The dome is approximately 15 miles south-southwest of Houston. The Stratton Ridge salt dome has been intensively developed, in the desirable central portions, with caverns for both brine production and product storage. This geologic technical assessment indicates that the Stratton Ridge salt dome may be considered a viable, if less-than-desirable, candidate site for potential expansion of the Strategic Petroleum Reserve (SPR). Past development of underground caverns significantly limits the potential options for use by the SPR. The current conceptual design layout of proposed caverns for such an expansion facility is based upon a decades-old model of salt geometry, and it is unacceptable, according to this reinterpretation of salt dome geology. The easternmost set of conceptual caverns are located within a 300-ft buffer zone of a very major boundary shear zone, fault, or other structural feature of indeterminate origin. This structure transects the salt stock and subdivides it into an shallow western part and a deeper eastern part. In places, the distance from this structural boundary to the design-basis caverns is as little as 150 ft. A 300-ft distance from this boundary is likely to be the minimum acceptable stand-off, from both a geologic and a regulatory perspective. Repositioning of the proposed cavern field is possible, as sufficient currently undeveloped salt acreage appears to be available. However, such reconfiguration would be subject to limitations related to land-parcel boundaries and other existing infrastructure and topographic constraints. More broadly speaking, the past history of cavern operations at the Stratton Ridge salt dome indicates that operation of potential SPR expansion caverns at this site may be difficult, and correspondingly expensive. Although detailed information is difficult to come by, widely accepted industry rumors are that numerous existing caverns have experienced major operational problems, including salt falls, sheared casings, and unintended releases of stored product(s). Many of these difficulties may be related to on-going differential movement of individual salt spines or to lateral movement at the caprock-salt interface. The history of operational problems, only some of which appear to be a matter of public record, combined with the potential for encountering escaped product from other operations, renders the Stratton Ridge salt dome a less-than-desirable site for SPR purposes.

Rautman, Christopher Arthur; Snider, Anna C.; Looff, Karl M. (Geologic Consultant, Lovelady, TX)

2006-11-01T23:59:59.000Z

231

Application of municipal sludge (biosolids) for agricultural purposes and groundwater nitrate concentrations  

SciTech Connect (OSTI)

One of the more popular means of handling sewage sludge from municipalities is its application to agricultural lands. A variety of crops are grown with the expectation that plants will utilize the nitrogen. However, a complex scenario allows some of the nitrate to move below root depth and eventually to the water table at depths of up to 30 ft. The City of Raleigh, NC injects sewage sludge ( residuals'', biosolids'') into soils derived largely from the Rolesville Granite in an area of typical rolling Piedmont topography. A 1975 background study of part of the site demonstrated differences in groundwater quality between areas farmed over a period of years and areas dominated by second-growth pine and harwood forests. Groundwater quality data collected semiannually between 1982 and 1988 show gradual buildup of nitrate in some fields; in others groundwater quality apparently remains unaffected by nitrate from the sludge. Monitoring well placement may play a role in these differences. Minimum time from the sludge application to an increase in groundwater nitrate is from 9 to 12 months. An ongoing study of a 12-acre field which lay fallow for a number of years prior to sludge application in 1990 demonstrates that some nitrate does move downward fairly rapidly, its movement being recorded in both the saprolite and groundwater. Comparison of nitrate content of groundwater from monitoring wells at a nearby dairy farm shows that normal agricultural practices may also increase the nitrate content of the shallow groundwater.

Welby, C.W. (North Carolina State Univ., Raleigh, NC (United States). Dept. of Marine, Earth and Atmospheric Sciences)

1993-03-01T23:59:59.000Z

232

Salt disposal of heat-generating nuclear waste.  

SciTech Connect (OSTI)

This report summarizes the state of salt repository science, reviews many of the technical issues pertaining to disposal of heat-generating nuclear waste in salt, and proposes several avenues for future science-based activities to further the technical basis for disposal in salt. There are extensive salt formations in the forty-eight contiguous states, and many of them may be worthy of consideration for nuclear waste disposal. The United States has extensive experience in salt repository sciences, including an operating facility for disposal of transuranic wastes. The scientific background for salt disposal including laboratory and field tests at ambient and elevated temperature, principles of salt behavior, potential for fracture damage and its mitigation, seal systems, chemical conditions, advanced modeling capabilities and near-future developments, performance assessment processes, and international collaboration are all discussed. The discussion of salt disposal issues is brought current, including a summary of recent international workshops dedicated to high-level waste disposal in salt. Lessons learned from Sandia National Laboratories' experience on the Waste Isolation Pilot Plant and the Yucca Mountain Project as well as related salt experience with the Strategic Petroleum Reserve are applied in this assessment. Disposal of heat-generating nuclear waste in a suitable salt formation is attractive because the material is essentially impermeable, self-sealing, and thermally conductive. Conditions are chemically beneficial, and a significant experience base exists in understanding this environment. Within the period of institutional control, overburden pressure will seal fractures and provide a repository setting that limits radionuclide movement. A salt repository could potentially achieve total containment, with no releases to the environment in undisturbed scenarios for as long as the region is geologically stable. Much of the experience gained from United States repository development, such as seal system design, coupled process simulation, and application of performance assessment methodology, helps define a clear strategy for a heat-generating nuclear waste repository in salt.

Leigh, Christi D. (Sandia National Laboratories, Carlsbad, NM); Hansen, Francis D.

2011-01-01T23:59:59.000Z

233

Conceptual Design of a 100 MWe Modular Molten Salt Power Tower Plant  

SciTech Connect (OSTI)

A conceptual design of a 100 MWe modular molten salt solar power tower plant has been developed which can provide capacity factors in the range of 35 to 75%. Compared to single tower plants, the modular design provides a higher degree of flexibility in achieving the desired customer's capacity factor and is obtained simply by adjusting the number of standard modules. Each module consists of a standard size heliostat field and receiver system, hence reengineering and associated unacceptable performance uncertainties due to scaling are eliminated. The modular approach with multiple towers also improves plant availability. Heliostat field components, receivers and towers are shop assembled allowing for high quality and minimal field assembly. A centralized thermal-storage system stores hot salt from the receivers, allowing nearly continuous power production, independent of solar energy collection, and improved parity with the grid. A molten salt steam generator converts the stored thermal energy into steam, which powers a steam turbine generator to produce electricity. This paper describes the conceptual design of the plant, the advantages of modularity, expected performance, pathways to cost reductions, and environmental impact.

James E. Pacheco; Carter Moursund, Dale Rogers, David Wasyluk

2011-09-20T23:59:59.000Z

234

DELIVERABLE Central North Sea  

E-Print Network [OSTI]

, as that has the same learning, but for more cost and more scale-up risk. The Central North Sea can produce into a guaranteed network for transportation and storage of captured CO2. Recent studies examining the levelised

Haszeldine, Stuart

235

Consolidation and permeability of salt in brine  

SciTech Connect (OSTI)

The consolidation and loss of permeability of salt crystal aggregates, important in assessing the effects of water in salt repositories, has been studied as a function of several variables. The kinetic behavior was similar to that often observed in sintering and suggested the following expression for the time dependence of the void fraction: phi(t) = phi(0) - (A/B)ln(1 + Bt/z(0)/sup 3/), where A and B are rate constants and z(0) is initial average particle size. With brine present, A and phi(0) varied linearly with stress. The initial void fraction was also dependent to some extent on the particle size distribution. The rate of consolidation was most rapid in brine and least rapid in the presence of only air as the fluid. A brine containing 5 m MgCl/sub 2/ showed an intermediate rate, presumably because of the greatly reduced solubility of NaCl. A substantial wall effect was indicated by an observed increase in the void fraction of consolidated columns with distance from the top where the stress was applied and by a dependence of consolidation rate on the column height and radius. The distance through which the stress fell by a factor of phi was estimated to change inversely as the fourth power of the column diameter. With increasing temperature (to 85/sup 0/C), consolidation proceeded somewhat more rapidly and the wall effect was reduced. The permeability of the columns dropped rapidly with consolidation, decreasing with about the sixth power of the void fraction. In general, extrapolation of the results to repository conditions confirms the self-sealing properties of bedded salt as a storage medium for radioactive waste.

Shor, A.J.; Baes, C.F. Jr.; Canonico, C.M.

1981-07-01T23:59:59.000Z

236

NITRATE CONVERSION OF HB-LINE REILLEXTM HPQ RESIN  

SciTech Connect (OSTI)

Reillex{trademark} HPQ ion exchange resin is used by HB Line to remove plutonium from aqueous streams. Reillex{trademark} HPQ resin currently available from Vertellus Specialties LLC is a chloride ionic form, which can cause stress corrosion cracking in stainless steels. Therefore, HB Line Engineering requested that Savannah River National Laboratory (SRNL) convert resin from chloride form to nitrate form in the Engineering Development Laboratory (EDL). To perform this task, SRNL treated two batches of resin in 2012. The first batch of resin from Reilly Industries Batch 80302MA was initially treated at SRNL in 2001 to remove chloride. This batch of resin, nominally 30 liters, has been stored wet in carboys since that time until being retreated in 2012. The second batch of resin from Batch 23408 consisted of 50 kg of new resin purchased from Vertellus Specialties in 2012. Both batches were treated in a column designed to convert resin using downflow of 1.0 M sodium nitrate solution through the resin bed followed by rinsing with deionized water. Both batches were analyzed for chloride concentration, before and after treatment, using Neutron Activation Analysis (NAA). The resin specification [Werling, 2003] states the total chlorine and chloride concentration shall be less than 250 ppm. The resin condition for measuring this concentration is not specified; however, in service the resin would always be fully wet. Measurements in SRNL showed that changing from oven dry resin to fully wet resin, with liquid in the particle interstices but no supernatant, increases the total weight by a factor of at least three. Therefore, concentration of chlorine or chloride expressed as parts per million (ppm) decreases by a factor of three. Therefore, SRNL recommends measuring chlorine concentration on an oven dry basis, then dividing by three to estimate chloride concentration in the fully wet condition. Chloride concentration in the first batch (No.80302MA) was nearly the same before the current treatment (759 ppm dry) and after treatment (745 ppm dry or {approx}248 ppm wet). Treatment of the second batch of resin (No.23408) was very successful. Chloride concentration decreased from 120,000 ppm dry to an average of 44 ppm dry or {approx}15ppm wet, which easily passes the 250 ppm wet criterion. Per guidance from HB Line Engineering, SRNL blended Batch 80302 resin with Batch P9059 resin which had been treated previously by ResinTech to remove chloride. The chloride concentrations for the two drums of Batch P9059 were 248 ppm dry ({approx}83 ppm wet) {+-}22.8% and 583 ppm dry ({approx}194 ppm wet) {+-} 11.8%. The blended resin was packaged in five gallon buckets.

Steimke, J.; Williams, M.; Steeper, T.; Leishear, R.

2012-05-29T23:59:59.000Z

237

Experimental studies of actinides in molten salts  

SciTech Connect (OSTI)

This review stresses techniques used in studies of molten salts containing multigram amounts of actinides exhibiting intense alpha activity but little or no penetrating gamma radiation. The preponderance of studies have used halides because oxygen-containing actinide compounds (other than oxides) are generally unstable at high temperatures. Topics discussed here include special enclosures, materials problems, preparation and purification of actinide elements and compounds, and measurements of various properties of the molten volts. Property measurements discussed are phase relationships, vapor pressure, density, viscosity, absorption spectra, electromotive force, and conductance. 188 refs., 17 figs., 6 tabs.

Reavis, J.G.

1985-06-01T23:59:59.000Z

238

The Effect of Salt Water on Rice.  

E-Print Network [OSTI]

mq A QTF *'. ' . - - . 1 bC1 r*. .. r * - .=.-ksl-, G v $. THE EFFECT OF SALT WATER ON RICE AGRICULTURAL AND MECHANICAL COLLEGE OF TEXAS T. 0. WALTON, President \\ STATION ,,,bfINISTRATION: *B. YOUNGBLOOD, M. S., Ph. D.,, Director A B CONNER... Station, near R. k. HALL, b. S., ~u~eriniendent College Station. Brazos County: No. 2 Troup Smith County: R. M. SHERWOOD, M. S., Animal Husbanri- W.'S. EIOT&HKISS. Superintendent man In Charge of Farm No. 3, Angleton, Brazoria County: L. J. MCCALL...

Fraps, G. S. (George Stronach)

1927-01-01T23:59:59.000Z

239

Acoustic probing of salt using sonar  

E-Print Network [OSTI]

, glycerine, and s1li cone oil provi ded satisfactory performance. In spite of these results, Gupta did not develop a workable means of us1ng 11quid coupl1ng media under mine condit1ons. In his field tests, Gupta used dental impression plaster (a coupling... acoustic pulses which are coupled 1nto the salt via a castor oil coupling medium. The acoustic source signa'i is a square-enveloped pulse of compress1onal waves; a pulse duration of e1ther 0. 3 ms or 1. 1 ms is used. The ranges to discontinuities...

Butler, Kenneth Bryan

1977-01-01T23:59:59.000Z

240

Salt dome gas storage solves curtailment threat  

SciTech Connect (OSTI)

In November 1981, Valero Transmission Co. (San Antonio, TX) opened two salt-dome storage caverns with a combined capacity of 5 billion CF (1.5 billion of cushion gas, 3.5 of working gas). The facility's maximum deliverability is 400 million CF/day for 9 days; when two more caverns are finished in late 1982, the $55 million complex will be able to sustain that level for 18 days, making Valero less dependent on linepacking and spot sales to avoid curtailing deliveries to its customers.

Watts, J.

1982-04-01T23:59:59.000Z

Note: This page contains sample records for the topic "nitrate salt central" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Salt River Project electric vehicle program  

SciTech Connect (OSTI)

Electric vehicles (EV) promise to be a driving force in the future of America. The quest for cleaner air and efforts to trim the nation's appetite for foreign oil are among the reasons why. America's EV future is rapidly approaching, with major automakers targeting EV mass production and sales before the end of the decade. This article describes the Salt River Project (SRP), a leader among electric utilities involved in EV research and development (R and D). R and D efforts are underway to plan and prepare for a significant number of EVs in SRP's service territory and to understand the associated recharging requirements for EVs.

Morrow, K.P.

1994-11-01T23:59:59.000Z

242

Salt Wells Geothermal Project | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 No revisionEnvReviewNonInvasiveExplorationUT-g Grant ofRichardton Abbey Wind Farm(CTIhinderProject SmartSalt Wells

243

Sandia National Laboratories: Molten Salt Test Loop  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administration the1 -theErik Spoerke SSLS ExhibitIowaLosSandiaManagementMolecularFacilityMolten Salt

244

The Salt Defense Disposal Investigations (SDDI)  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLas ConchasPassiveSubmittedStatus TomAboutManusScienceThe Life of EnricoFlickrPhysics LabSalt

245

Delivery system for molten salt oxidation of solid waste  

DOE Patents [OSTI]

The present invention is a delivery system for safety injecting solid waste particles, including mixed wastes, into a molten salt bath for destruction by the process of molten salt oxidation. The delivery system includes a feeder system and an injector that allow the solid waste stream to be accurately metered, evenly dispersed in the oxidant gas, and maintained at a temperature below incineration temperature while entering the molten salt reactor.

Brummond, William A. (Livermore, CA); Squire, Dwight V. (Livermore, CA); Robinson, Jeffrey A. (Manteca, CA); House, Palmer A. (Walnut Creek, CA)

2002-01-01T23:59:59.000Z

246

The Salt or Sodium Chloride Content of Feeds  

E-Print Network [OSTI]

of Sodium Chloride.--In order to test the recovery of added salt, several molasses feeds were selected, weighed out, and varying amounts of salt added, in the form of a N/10 solution of sodium chloride. The salt was added hy a different person from... ............................... . . Preliminary ~vork on laboratory methocls ........ . . ............................... Laboratory method adopted.. ............................. Tests of the laboratory niethod. ................... Application of the methold to feed mixtures...

Fraps, G. S. (George Stronach); Lomanitz, S. (Sebastian)

1920-01-01T23:59:59.000Z

247

Integrated demonstration of molten salt oxidation with salt recycle for mixed waste treatment  

SciTech Connect (OSTI)

Molten Salt Oxidation (MSO) is a thermal, nonflame process that has the inherent capability of completely destroying organic constituents of mixed wastes, hazardous wastes, and energetic materials while retaining inorganic and radioactive constituents in the salt. For this reason, MSO is considered a promising alternative to incineration for the treatment of a variety of organic wastes. Lawrence Livermore National Laboratory (LLNL) has prepared a facility and constructed an integrated pilot-scale MSO treatment system in which tests and demonstrations are performed under carefully controlled (experimental) conditions. The system consists of a MSO processor with dedicated off-gas treatment, a salt recycle system, feed preparation equipment, and equipment for preparing ceramic final waste forms. This integrated system was designed and engineered based on laboratory experience with a smaller engineering-scale reactor unit and extensive laboratory development on salt recycle and final forms preparation. In this paper we present design and engineering details of the system and discuss its capabilities as well as preliminary process demonstration data. A primary purpose of these demonstrations is identification of the most suitable waste streams and waste types for MSO treatment.

Hsu, P.C.

1997-11-01T23:59:59.000Z

248

Molten salt bath circulation design for an electrolytic cell  

DOE Patents [OSTI]

An electrolytic cell for reduction of a metal oxide to a metal and oxygen has an inert anode and an upwardly angled roof covering the inert mode. The angled roof diverts oxygen bubbles into an upcomer channel, thereby agitating a molten salt bath in the upcomer channel and improving dissolution of a metal oxide in the molten salt bath. The molten salt bath has a lower velocity adjacent the inert anode in order to minimize corrosion by substances in the bath. A particularly preferred cell produces aluminum by electrolysis of alumina in a molten salt bath containing aluminum fluoride and sodium fluoride. 4 figs.

Dawless, R.K.; LaCamera, A.F.; Troup, R.L.; Ray, S.P.; Hosler, R.B.

1999-08-17T23:59:59.000Z

249

A trophic cascade regulates salt marsh primary production  

E-Print Network [OSTI]

) Nutrient supply is widely thought to regulate primary production of many ecosystems including salt marshes, predator regulation of marine macrophyte production via trophic cascades (kelps, seagrasses, intertidal

Bertness, Mark D.

250

Molten salt bath circulation design for an electrolytic cell  

DOE Patents [OSTI]

An electrolytic cell for reduction of a metal oxide to a metal and oxygen has an inert anode and an upwardly angled roof covering the inert mode. The angled roof diverts oxygen bubbles into an upcomer channel, thereby agitating a molten salt bath in the upcomer channel and improving dissolution of a metal oxide in the molten salt bath. The molten salt bath has a lower velocity adjacent the inert anode in order to minimize corrosion by substances in the bath. A particularly preferred cell produces aluminum by electrolysis of alumina in a molten salt bath containing aluminum fluoride and sodium fluoride.

Dawless, Robert K. (Monroeville, PA); LaCamera, Alfred F. (Trafford, PA); Troup, R. Lee (Murrysville, PA); Ray, Siba P. (Murrysville, PA); Hosler, Robert B. (Sarver, PA)

1999-01-01T23:59:59.000Z

251

Fundamental Corrosion Studies in High-Temperature Molten Salt...  

Broader source: Energy.gov (indexed) [DOE]

Molten Salt Systems for CSP Applications - FY13 Q1 Advanced Ceramic Materials and Packaging Technologies for Realizing Sensors for Concentrating Solar Power Systems...

252

Surface Indicators of Geothermal Activity at Salt Wells, Nevada...  

Open Energy Info (EERE)

structural controls, and potential subsurface reservoir temperatures of geothermal fluids. An example is provided by the Salt Wells geothermal system in Churchill County,...

253

Method for the production of uranium chloride salt  

DOE Patents [OSTI]

A method for the production of UCl.sub.3 salt without the use of hazardous chemicals or multiple apparatuses for synthesis and purification is provided. Uranium metal is combined in a reaction vessel with a metal chloride and a eutectic salt- and heated to a first temperature under vacuum conditions to promote reaction of the uranium metal with the metal chloride for the production of a UCl.sub.3 salt. After the reaction has run substantially to completion, the furnace is heated to a second temperature under vacuum conditions. The second temperature is sufficiently high to selectively vaporize the chloride salts and distill them into a condenser region.

Westphal, Brian R.; Mariani, Robert D.

2013-07-02T23:59:59.000Z

254

Multispectral Imaging At Columbus Salt Marsh Area (Shevenell...  

Open Energy Info (EERE)

Area (Shevenell, Et Al., 2008) Exploration Activity Details Location Columbus Salt Marsh Area Exploration Technique Multispectral Imaging Activity Date Usefulness useful...

255

Salt Lake City, Utah: Solar in Action (Brochure), Solar America...  

Broader source: Energy.gov (indexed) [DOE]

a lack of understanding about solar contributed to preventing the widespread adoption of solar energy in all markets. Salt Lake City's prior solar successes with support from...

256

Salt River Electric- Residential Energy Efficiency Rebate Program  

Broader source: Energy.gov [DOE]

Salt River Electric serves as the rural electric provider in Kentucky's Bullitt, Nelson, Spencer, and Washington counties. Residential customers are eligible for a variety of cash incentives for...

257

Project Profile: Modular and Scalable Baseload Molten Salt Plant...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

including all molten salt components (receiver, field piping, thermal storage, and steam generator) and their integration with eSolar's heliostat technology and a conventional...

258

A low-temperature process for the denitration of Hanford single-shell tank, nitrate-based waste utilizing the nitrate to ammonia and ceramic (NAC) process  

SciTech Connect (OSTI)

Bench-top feasibility studies with Hanford single-shell tank (SST) simulants, using a new, low-temperature (50 to 60C) process for converting nitrate to ammonia and ceramic (NAC), have conclusively shown that between 85 to 99% of the nitrate can be readily converted. In this process, aluminum powders or shot can be used to convert alkaline, nitrate-based supernate to ammonia and an aluminum oxide-sodium aluminate-based solid which might function as its own waste form. The process may actually be able to utilize already contaminated aluminum scrap metal from various DOE sites to effect the conversion. The final, nearly nitrate-free ceramic-like product can be pressed and sintered like other ceramics. Based upon the starting volumes of 6.2 and 3.1 M sodium nitrate solution, volume reductions of 50 to 55% were obtained for the waste form produced, compared to an expected 35 to 50% volume increase if the Hanford supernate were grouted. Engineering data extracted from bench-top studies indicate that the process will be very economical to operate, and data were used to cost a batch, 1,200-kg NO{sub 3}/h plant for working off Hanford SST waste over 20 years. Their total process cost analysis presented in the appendix, indicates that between $2.01 to 2.66 per kilogram of nitrate converted will be required. Additionally, data on the fate of select radioelements present in solution are presented in this report as well as kinetic, operational, and control data for a number of experiments. Additionally, if the ceramic product functions as its own waste form, it too will offer other cost savings associated with having a smaller volume of waste form as well as eliminating other process steps such as grouting.

Mattus, A.J.; Lee, D.D.; Dillow, T.A.; Farr, L.L.; Loghry, S.L.; Pitt, W.W.; Gibson, M.R.

1994-12-01T23:59:59.000Z

259

Utilizing Microalgae to Remediate Nitrate-Contaminated Groundwater N. Case, M. Sommerfeld, H. Qiang  

E-Print Network [OSTI]

Utilizing Microalgae to Remediate Nitrate-Contaminated Groundwater N. Case, M. Sommerfeld, H. Qiang or domestic animals. It can also be used as a fertilizer or converted to biofuels. The photobioreactor can

Hall, Sharon J.

260

The Effect of Nanoparticle Concentration on Thermo-physical Properties of Alumina-nitrate Nanofluid  

E-Print Network [OSTI]

The objective of this study was to determine how Al2O3 nanoparticle concentration affected the specific heat, heat of fusion, melting point, thermal diffusivity and thermal conductivity of Alumina-Nitrate nanofluids. Al2O3 nanoparticles were...

Shao, Qian

2013-02-15T23:59:59.000Z

Note: This page contains sample records for the topic "nitrate salt central" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Nighttime Measurements of Dinitrogen Pentoxide and the Nitrate Radical via Cavity Ring-Down Spectroscopy  

E-Print Network [OSTI]

technique, known as cavity ring-down spectroscopy, will be introduced for simultaneously measuring the nitrate radical and dinitrogen pentoxide. The cavity ring-down spectrometer was initially designed and constructed based on the experiments by Steven Brown...

Perkins, Katie C.

2010-10-12T23:59:59.000Z

262

Nitrate and sulphate dynamics in peat subjected to different hydrological conditions: Batch experiments and field comparison  

E-Print Network [OSTI]

Nitrate and sulphate dynamics in peat subjected to different hydrological conditions: Batch concentrations were investigated in bioreactors, using peat samples from field sites influenced by different hydrologic regimes. In this experiment, peat samples were subjected to similar conditions to address

Paris-Sud XI, Université de

263

Sodium-Copper Exchange on Wyoming Montmorillonite in Chloride, Perchlorate, Nitrate, and Sulfate Solutions  

E-Print Network [OSTI]

Sodium-Copper Exchange on Wyoming Montmorillonite in Chloride, Perchlorate, Nitrate, and Sulfate. The copper exchange capacity (CuEC) and Na-Cu exchange reactions on Wyoming montmo- rillonite were studied

Sparks, Donald L.

264

Application of Artificially Immobilized Microorganisms to Nitrate Removal from Drinking Water  

E-Print Network [OSTI]

to Nitrate Removal from Drinking Water By Sean X. Liu andFor biological treatment of drinking water, several crucialalginate gel beads to drinking water treatment has proved to

Liu, Sean X; Hermanowicz, Slawomir W

1997-01-01T23:59:59.000Z

265

E-Print Network 3.0 - alkali metal nitrate Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

0021-91930104.00 0 DOI: 10.1128JB.183.19.54915495.2001 Summary: for this heavy metal for its anaerobic growth mode on nitrate (1). However, also in this organism,...

266

CENTRAL PLATEAU REMEDIATION  

SciTech Connect (OSTI)

A systematic approach to closure planning is being implemented at the Hanford Site's Central Plateau to help achieve the goal of closure by the year 2035. The overall objective of Central Plateau remediation is to protect human health and the environment from the significant quantity of contaminated material that resulted from decades of plutonium production in support of the nation's defense. This goal will be achieved either by removing contaminants or placing the residual contaminated materials in a secure configuration that minimizes further migration to the groundwater and reduces the potential for inadvertent intrusion into contaminated sites. The approach to Central Plateau cleanup used three key concepts--closure zones, closure elements, and closure process steps--to create an organized picture of actions required to complete remediation. These actions were merged with logic ties, constraints, and required resources to produce an integrated time-phased schedule and cost profile for Central Plateau closure. Programmatic risks associated with implementation of Central Plateau closure were identified and analyzed. Actions to mitigate the most significant risks are underway while high priority remediation projects continue to make progress.

ROMINE, L.D.

2006-02-01T23:59:59.000Z

267

A Centrality Detector Concept  

E-Print Network [OSTI]

The nucleus-nucleus impact parameter and collision geometry of a heavy ion collision are typically characterized by assigning a collision "centrality". In all present heavy ion experiments centrality is measured indirectly, by detecting the number of particles or the energy of the particles produced in the interactions, typically at high rapidity. Centrality parameters are associated to the measured detector response using the Glauber model. This approach suffers from systematic uncertainties related to the assumptions about the particle production mechanism and limitations of the Glauber model. In the collider based experiments there is a unique possibility to measure centrality parameters by registering spectator fragments remaining from the collision. This approach does not require model assumptions and relies on the fact that spectators and participants are related via the total number of nucleons in the colliding species. This article describes the concept of the centrality detector for heavy ion experiment, which measures the total mass number of all fragments by measuring their deflection in the magnetic field of the collider elements.

Sourav Tarafdar; Zvi Citron; Alexander Milov

2014-06-07T23:59:59.000Z

268

Estimates of New and Total Productivity in Central Long Island Sound from In Situ Measurements of Nitrate and Dissolved Oxygen  

E-Print Network [OSTI]

Biogeochemical cycles in estuaries are regulated by a diverse set of physical and biological variables that operate over a variety of time scales. Using in situ optical sensors, we conducted a high-frequency time-series ...

Raymond, Peter A.

269

Central Ferry Lower Monumental  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation Proposed New Substation SitesStanding Friedel Waves,TheoryParliament' |CentralCentral

270

Laboratory investigation of crushed salt consolidation and fracture healing  

SciTech Connect (OSTI)

A laboratory test program was conducted to investigate the consolidation behavior of crushed salt and fracture healing in natural and artificial salt. Crushed salt is proposed for use as backfill in a nuclear waste repository in salt. Artificial block salt is proposed for use in sealing a repository. Four consolidation tests were conducted in a hydrostatic pressure vessel at a maximum pressure of 2500 psi (17.2 MPa) and at room temperature. Three 1-month tests were conducted on salt obtained from the Waste Isolation Pilot Plant and one 2-month test was conducted on salt from Avery Island. Permeability was obtained using argon and either a steady-state or transient method. Initial porosities ranged from 0.26 to 0.36 and initial permeabilities from 2000 to 50,000 md. Final porosities and permeabilities ranged from 0.05 to 0.19 and from <10/sup -5/ md to 110 md, respectively. The lowest final porosity (0.05) and permeability (<10/sup -5/ md) were obtained in a 1-month test in which 2.3% moisture was added to the salt at the beginning of the test. The consolidation rate was much more rapid than in any of the dry salt tests. The fracture healing program included 20 permeability tests conducted on fractured and unfractured samples. The tests were conducted in a Hoek cell at hydrostatic pressures up to 3000 psi (20.6 MPa) with durations up to 8 days. For the natural rock salt tested, permeability was strongly dependent on confining pressure and time. The effect of confining pressure was much weaker in the artificial salt. In most cases the combined effects of time and pressure were to reduce the permeability of fractured samples to the same order of magnitude (or less) as the permeability measured prior to fracturing.

Not Available

1987-01-01T23:59:59.000Z

271

POWER CENTRALIZED SEMIGROUPS PRIMOZ MORAVEC  

E-Print Network [OSTI]

POWER CENTRALIZED SEMIGROUPS PRIMOZ MORAVEC Abstract. A semigroup is said to be power centralized if for every pair of elements x and y there exists a power of x commuting with y. The structure of power centralized groups and semigroups is investigated. In particular, we characterize 0-simple power centralized

272

The role of syn-kinematic sedimentation on early salt tectonic processes in the Post-Permian Salt Basin, Southern North Sea  

E-Print Network [OSTI]

The role of syn-kinematic sedimentation on early salt tectonic processes in the Post-Permian Salt- Permian salt basin of the southernmost North Sea using 3D seismic interpretation, structural modelling mechanical concepts for the dynamics of salt structures and related depositional systems as well

Royal Holloway, University of London

273

A quarterly and Central  

E-Print Network [OSTI]

A quarterly report on employment and office markets in Northern and Central New Jersey May 2008- plications for the state's office markets. This year has every indication of being a very difficult capacity. Along with the ongoing Portfields Initiative project, the Port of New York and New Jersey

274

Laboratory Measurements of Sea Salt Aerosol Refractive Index  

E-Print Network [OSTI]

. . . . . . . . . . . . . . . . . . . . . . 6 1.2.3 Complex Refractive Index . . . . . . . . . . . . . . . . . . . . 6 1.2.4 Size Distribution . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13 1.3.5 Coagulation . . . . . . . . . . . . . . . . . . . . . . . . . . . . 14 1.4 Sea Salt AerosolsLaboratory Measurements of Sea Salt Aerosol Refractive Index Thesis submitted for the degree

Oxford, University of

275

ORIGINAL PAPER Geochemical Evolution of Great Salt Lake, Utah, USA  

E-Print Network [OSTI]

Discipline, US Geological Survey, 2329 Orton Circle, Salt Lake City, UT 84119, USA R. J. Spencer GeoscienceORIGINAL PAPER Geochemical Evolution of Great Salt Lake, Utah, USA Blair F. Jones Ã? David L. Naftz Ã? Ronald J. Spencer Ã? Charles G. Oviatt Received: 13 June 2008 / Accepted: 10 November 2008

276

SALT DAMAGE CRITERION PROOF-OF-CONCEPT RESEARCH  

SciTech Connect (OSTI)

The purpose of this study was to conduct a field-scale application demonstrating the use of continuum damage mechanics to determine the minimum allowable operating pressure of compressed natural gas storage caverns in salt formations. A geomechanical study was performed of two natural gas storage caverns (one existing and one planned) utilizing state-of-the-art salt mechanics to assess the potential for cavern instability and collapse. The geomechanical study consisted primarily of laboratory testing, theoretical development, and analytical/numerical tasks. A total of 50 laboratory tests was performed on salt specimens to aid in the development and definition of the material model used to predict the behavior of rock salt. Material model refinement was performed that improved the predictive capability of modeling salt during damage healing, recovery of work-hardened salt, and the behavior of salt at stress states other than triaxial compression. Results of this study showed that the working gas capacity of the existing cavern could be increased by 18 percent and the planned cavern could be increased by 8 percent using the proposed method compared to a conventional stress-based method. Further refinement of the continuum damage model is recommended to account for known behavior of salt at stress conditions other than triaxial compression that is not characterized accurately by the existing model.

Kerry L. DeVries; Kirby D. Mellegard; Gary D. Callahan

2002-11-01T23:59:59.000Z

277

Synthesis of permethyldodecaborate and paramagnetic dodecaborate salt  

DOE Patents [OSTI]

The dodecamethyl closo-borane dianion [closo-B.sub.12 (CH.sub.3).sub.12 ].sup.2- and anion [closo-B.sub.12 (CH.sub.3).sub.12 ].sup.- were synthesized and characterized. Dodecamethyl-closo dodecaborate (2-) was produced from [closo-B.sub.12 H.sub.12 ].sup.2-, using trimethylaluminum, and methyl iodide and modified Friedel-Crafts reaction conditions. The anion was produced from the dianion by chemical oxidation using ceric (4) ammonium nitrate in acetonitrile. The anion and dianion were both characterized by .sup.1 H and .sup.11 B NMR spectroscopy, high-resolution fast atom bombardment (FAB) mass spectrometry, cyclic voltammetry, and single-crystal X-ray diffraction. The "camouflaged" polyhedral borane anion [closo-B.sub.12 (CH.sub.3).sub.12 ].sup.2-, can be used as a precursor to materials that offer a broad spectrum of novel applications ranging from drug applications and supramolecular chemistry to use as a weakly-coordinating dianion.

Hawthorne, M. Frederick (Encino, CA); Peymann, Toralf (Los Angeles, CA)

2002-01-01T23:59:59.000Z

278

Constitutive representation of damage development and healing in WIPP salt  

SciTech Connect (OSTI)

There has been considerable interest in characterizing and modeling the constitutive behavior of rock salt with particular reference to long-term creep and creep failure. The interest is motivated by the projected use of excavated rooms in salt rock formations as repositories for nuclear waste. It is presumed that closure of those rooms by creep ultimately would encapsulate the waste material, resulting in its effective isolation. A continuum mechanics approach for treating damage healing is formulated as part of a constitutive model for describing coupled creep, fracture, and healing in rock salt. Formulation of the healing term is, described and the constitutive model is evaluated against experimental data of rock salt from the Waste Isolation Pilot Plant (WIPP) site. The results indicate that healing anistropy in WIPP salt can be modeled with an appropriate power-conjugate equivalent stress, kinetic equation, and evolution equation for damage healing.

Chan, K.S.; Bodner, S.R. [Southwest Research Inst., San Antonio, TX (United States); Fossum, A.F [RE/SPEC, Inc., Rapid City, SD (United States); Munson, D.E. [Sandia National Labs., Albuquerque, NM (United States)

1994-12-31T23:59:59.000Z

279

Molten-Salt Depleted-Uranium Reactor  

E-Print Network [OSTI]

The supercritical, reactor core melting and nuclear fuel leaking accidents have troubled fission reactors for decades, and greatly limit their extensive applications. Now these troubles are still open. Here we first show a possible perfect reactor, Molten-Salt Depleted-Uranium Reactor which is no above accident trouble. We found this reactor could be realized in practical applications in terms of all of the scientific principle, principle of operation, technology, and engineering. Our results demonstrate how these reactors can possess and realize extraordinary excellent characteristics, no prompt critical, long-term safe and stable operation with negative feedback, closed uranium-plutonium cycle chain within the vessel, normal operation only with depleted-uranium, and depleted-uranium high burnup in reality, to realize with fission nuclear energy sufficiently satisfying humanity long-term energy resource needs, as well as thoroughly solve the challenges of nuclear criticality safety, uranium resource insuffic...

Dong, Bao-Guo; Gu, Ji-Yuan

2015-01-01T23:59:59.000Z

280

Technical review of Molten Salt Oxidation  

SciTech Connect (OSTI)

The process was reviewed for destruction of mixed low-level radioactive waste. Results: extensive development work and scaleup has been documented on coal gasification and hazardous waste which forms a strong experience base for this MSO process; it is clearly applicable to DOE wastes such as organic liquids and low-ash wastes. It also has potential for processing difficult-to-treat wastes such as nuclear grade graphite and TBP, and it may be suitable for other problem waste streams such as sodium metal. MSO operating systems may be constructed in relatively small units for small quantity generators. Public perceptions could be favorable if acceptable performance data are presented fairly; MSO will likely require compliance with regulations for incineration. Use of MSO for offgas treatment may be complicated by salt carryover. Figs, tabs, refs.

Not Available

1993-12-01T23:59:59.000Z

Note: This page contains sample records for the topic "nitrate salt central" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Natural gas storage in bedded salt formations  

SciTech Connect (OSTI)

In 1990 Western Resources Inc. (WRI) identified the need for additional natural gas storage capacity for its intrastate natural gas system operated in the state of Kansas. Western Resources primary need was identified as peak day deliverability with annual storage balancing a secondary objective. Consequently, an underground bedded salt storage facility, Yaggy Storage Field, was developed and placed in operation in November 1993. The current working capacity of the new field is 2.1 BCF. Seventy individual caverns are in service on the 300 acre site. The caverns vary in size from 310,000 CF to 2,600,000 CF. Additional capacity can be added on the existing acreage by increasing the size of some of the smaller existing caverns by further solution mining and by development of an additional 30 potential well sites on the property.

Macha, G.

1996-09-01T23:59:59.000Z

282

Disposal of NORM waste in salt caverns  

SciTech Connect (OSTI)

Some types of oil and gas production and processing wastes contain naturally occurring radioactive materials (NORM). If NORM is present at concentrations above regulatory levels in oil field waste, the waste requires special disposal practices. The existing disposal options for wastes containing NORM are limited and costly. This paper evaluates the legality, technical feasibility, economics, and human health risk of disposing of NORM-contaminated oil field wastes in salt caverns. Cavern disposal of NORM waste is technically feasible and poses a very low human health risk. From a legal perspective, there are no fatal flaws that would prevent a state regulatory agency from approving cavern disposal of NORM. On the basis of the costs charged by caverns currently used for disposal of nonhazardous oil field waste (NOW), NORM waste disposal caverns could be cost competitive with existing NORM waste disposal methods when regulatory agencies approve the practice.

Veil, J.A.; Smith, K.P.; Tomasko, D.; Elcock, D.; Blunt, D.; Williams, G.P.

1998-07-01T23:59:59.000Z

283

Metals concentration in salt marshes plants and kelp around San Diego: A window to environment quality  

E-Print Network [OSTI]

in salt marshes plants and kelp around San Diego: A windowassessing levels of metals in kelp and salt marsh plants inmetals levels found in kelp and salt marsh plants reflect

Deheyn, Dimitri

2009-01-01T23:59:59.000Z

284

E-Print Network 3.0 - alternative salt transfer Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

salt damage to trees | November 2011 Pathology Advisory Note (No. 11) De-icing salt... damage to trees De-icing Salt Damage to Trees Joan F Webber, David R Rose, Martin C ......

285

Analysis of Multistage and Other Creep Data for Domal Salts  

SciTech Connect (OSTI)

There have existed for some time relatively sparse creep databases for a number of domal salts. Although all of these data were analyzed at the time they were reported, to date there has not been a comprehensive, overall evaluation within the same analysis framework. Such an evaluation may prove of value. The analysis methodology is based on the Multimechanism Deformation (M-D) description of salt creep and the corresponding model parameters determined from conventional creep tests. The constitutive model of creep wss formulated through application of principles involved in micromechanical modeling. It was possible, at minimum, to obtain the steady state parameters of the creep model from the data on the domal salts. When this was done, the creep of the domal salts, as compared to the well-defined Waste Isolation Pilot Plant (WIPP) bedded clean salt, was either essentially identical to, or significantly harder (more creep resistant) than WIPP salt. Interestingly, the domal salts form two distinct groups, either sofl or hard, where the difference is roughly a factor often in creep rate between the twcl groups. As might be expected, this classification corresponds quite well to the differences in magnitude of effective creep volume losses of the Strategic Petroleum Reserve (SPR) caverns as determined by the CAVEMAN cavern pressure history analysis, depending upon the specific dome or region within the dome. Creep response shoulcl also correlate to interior cavern conditions that produce salt falls. WMle, in general, the caverns in hard sah have a noticeably greater propensity for salt falls, a smaller number of similar events are exhibited even in the caverns in soft salt.

Munson, D.E.

1998-10-01T23:59:59.000Z

286

Uranyl nitrate-exposed rat alveolar macrophages cell death: Influence of superoxide anion and TNF ? mediators  

SciTech Connect (OSTI)

Uranium compounds are widely used in the nuclear fuel cycle, military and many other diverse industrial processes. Health risks associated with uranium exposure include nephrotoxicity, cancer, respiratory, and immune disorders. Macrophages present in body tissues are the main cell type involved in the internalization of uranium particles. To better understand the pathological effects associated with depleted uranium (DU) inhalation, we examined the metabolic activity, phagocytosis, genotoxicity and inflammation on DU-exposed rat alveolar macrophages (12.5–200 ?M). Stability and dissolution of DU could differ depending on the dissolvent and in turn alter its biological action. We dissolved DU in sodium bicarbonate (NaHCO{sub 3} 100 mM) and in what we consider a more physiological vehicle resembling human internal media: sodium chloride (NaCl 0.9%). We demonstrate that uranyl nitrate in NaCl solubilizes, enters the cell, and elicits its cytotoxic effect similarly to when it is diluted in NaHCO{sub 3}. We show that irrespective of the dissolvent employed, uranyl nitrate impairs cell metabolism, and at low doses induces both phagocytosis and generation of superoxide anion (O{sub 2}{sup ?}). At high doses it provokes the secretion of TNF? and through all the range of doses tested, apoptosis. We herein suggest that at DU low doses O{sub 2}{sup ?} may act as the principal mediator of DNA damage while at higher doses the signaling pathway mediated by O{sub 2}{sup ?} may be blocked, prevailing damage to DNA by the TNF? route. The study of macrophage functions after uranyl nitrate treatment could provide insights into the pathophysiology of uranium?related diseases. -- Highlights: ? Uranyl nitrate effect on cultured macrophages is linked to the doses and independent of its solubility. ? At low doses uranyl nitrate induces generation of superoxide anion. ? At high doses uranyl nitrate provokes secretion of TNF?. ? Uranyl nitrate induces apoptosis through all the range of doses tested.

Orona, N.S. [School of Science and Technology, National University of General Martín, Avda Gral Paz 5445 (1650) San Martín, Buenos Aires (Argentina)] [School of Science and Technology, National University of General Martín, Avda Gral Paz 5445 (1650) San Martín, Buenos Aires (Argentina); Tasat, D.R., E-mail: deborah.tasat@unsam.edu.ar [School of Science and Technology, National University of General Martín, Avda Gral Paz 5445 (1650) San Martín, Buenos Aires (Argentina); School of Dentistry, University of Buenos Aires, M. T. de Alvear 2142 (1122), Buenos Aires (Argentina)

2012-06-15T23:59:59.000Z

287

E-Print Network 3.0 - alternative salt processing Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Assurance Salt Lake City UT Pricewaterhouse... salary) 11 Employment Information Armstrong, Johnson & Seatsen Accountant Salt Lake City UT Baird... Longyear Accounting...

288

Thermal Gradient Holes At Salt Wells Area (Bureau of Land Management...  

Open Energy Info (EERE)

Salt Wells Area (Bureau of Land Management, 2009) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Thermal Gradient Holes At Salt Wells Area...

289

E-Print Network 3.0 - avoid salt induced Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

with Salt Ions: An Electrostatic Theory for the Hofmeister Effect Summary: , an image charge is induced and a repulsive interaction between the salt ion and its image...

290

anion heavy-atom salt: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of nutrients and heavy metals in experimental salt marsh ecosystems. Environmental Pollution,effects of nutrients and heavy metals in experimental salt marsh ecosystems....

291

Invasive Spartina densiflora Brongn. Reduces Primary Productivity in a Northern California Salt Marsh  

E-Print Network [OSTI]

alterniflora and benthic microalgae in salt marsh food webs:dynamics of benthic microalgae in salt marshes. Pages 81-106primary productivity of microalgae and cyanobacteria (Geider

Lagarde, Luc A.

2012-01-01T23:59:59.000Z

292

Levels of metals from salt marsh plants from Southern California, USA  

E-Print Network [OSTI]

alterniflora and benthic microalgae in salt marsh foodalterniflora and benthic microalgae in salt marsh foodSpartina, but feed on microalgae (Currin,1990). Isotope

Hoyt, Kimberly Ann

2009-01-01T23:59:59.000Z

293

Crystal chemistry of new thorium nitrates and chromates  

SciTech Connect (OSTI)

The structures and infrared spectra of six novel thorium compounds are reported. Th(NO{sub 3}){sub 2}(OH){sub 2}(H{sub 2}O){sub 2} (1) crystallizes in space group C2/c, a=14.050(1), b=8.992(7), c=5.954(5) Å, ?=101.014(2)°. K{sub 2}Th(NO{sub 3}){sub 6} (2), P-3, a=13.606(1), c=6.641(6) Å. (C{sub 12}H{sub 28}N){sub 2}Th(NO{sub 3}){sub 6} (3), P21/c, a=14.643(4), b=15.772(5), c=22.316(5) Å, ?=131.01(1)°. KTh(NO{sub 3}){sub 5}(H{sub 2}O){sub 2} (4), P21/c, a=10.070(8), b=12.731(9), c=13.231(8) Å, ?=128.647(4)°. Th(CrO{sub 4}){sub 2}(H{sub 2}O){sub 2} (5), P21/n, a=12.731(1), b=9.469(8), c=12.972(1) Å, ?=91.793(2)°. K{sub 2}Th{sub 3}(CrO{sub 4}){sub 7}(H{sub 2}O){sub 10} (6), Ama2, a=19.302(8), b=15.580(6), c=11.318(6) Å. The coordination polyhedra about Th in these structures are diverse. Th is coordinated by 9 O atoms in 5 and 6, seven of which are from monodentate (CrO{sub 4}) tetrahedra and two are (H{sub 2}O). The Th in compound 1 is coordinated by ten O atoms, four of which are O atoms of two bidentate (NO{sub 3}) triangles and six of which are (OH) and (H{sub 2}O). In compounds 2, 3 and 4 the Th is coordinate by 12 O atoms. In 2 and 3 there are six bidentate (NO{sub 3}) triangles, and in 4 ten of the O atoms are part of five bidentate (NO{sub 3}) triangles and the others are (H{sub 2}O) groups. The structural units of these compounds consist of a chain of thorium and nitrate polyhedra (1), isolated thorium hexanitrate clusters (2, 3), an isolated thorium pentanitrate dihydrate cluster (4), and a sheet (6) and framework (5) of thorium and chromate polyhedra. These structures illustrate the complexity inherent in the crystal chemistry of Th.

Sigmon, Ginger E.; Burns, Peter C

2010-01-01T23:59:59.000Z

294

Controlled black liquor viscosity reduction through salting-in  

SciTech Connect (OSTI)

Black liquor viscosity increases exponentially with solids content and therefore causes processing problems for the paper industry by being a limiting factor in the Kraft pulp process. This study investigates a new approach for achieving viscosity reduction by salting-in black liquor through the addition of thiocyanate salts. These salts generally increase the solubility of the polymer constituents in black liquor, leading to a decrease in its viscosity. Several thiocyanate salts capable of reducing liquor viscosity by more than two orders of magnitude have been identified, with viscosity reduction greatest at high solids content. Salting-in of black liquor depends on the cation paired with the thiocyanate anion, as well as on solution pH and temperature. Comparative studies reveal the most effective viscosity-reducing agent of the series examined and that lignin plays an important role in the viscosity behavior of both unmodified and salted-in black liquor at high solids concentrations. These experimental findings are interpreted in terms of the underlying principles that describe salting-in and how it affects aqueous solution structure.

Roberts, J.E.; Khan, S.A.; Spontak, R.J. [North Carolina State Univ., Raleigh, NC (United States)] [North Carolina State Univ., Raleigh, NC (United States)

1996-08-01T23:59:59.000Z

295

Permeability of WIPP Salt During Damage Evolution and Healing  

SciTech Connect (OSTI)

The presence of damage in the form of microcracks can increase the permeability of salt. In this paper, an analytical formulation of the permeability of damaged rock salt is presented for both initially intact and porous conditions. The analysis shows that permeability is related to the connected (i.e., gas accessible) volumetric strain and porosity according to two different power-laws, which may be summed to give the overall behavior of a porous salt with damage. This relationship was incorporated into a constitutive model, known as the Multimechanism Deformation Coupled Fracture (MDCF) model, which has been formulated to describe the inelastic flow behavior of rock salt due to coupled creep, damage, and healing. The extended model was used to calculate the permeability of rock salt from the Waste Isolation Pilot Plant (WIPP) site under conditions where damage evolved with stress over a time period. Permeability changes resulting from both damage development under deviatoric stresses and damage healing under hydrostatic pressures were considered. The calculated results were compared against experimental data from the literature, which indicated that permeability in damaged intact WIPP salt depends on the magnitude of the gas accessible volumetric strain and not on the total volumetric strain. Consequently, the permeability of WIPP salt is significantly affected by the kinetics of crack closure, but shows little dependence on the kinetics of crack removal by sintering.

BODNER,SOL R.; CHAN,KWAI S.; MUNSON,DARRELL E.

1999-12-03T23:59:59.000Z

296

Comparison of linear and nonlinear acoustic probing of rock salt  

E-Print Network [OSTI]

equation (2) (3) where A = oo ~ = '0'0 0 (4) with c being the sound speed for 1nfin1tesimal-amplitude wave propa- 0 gation. The rat1o 8/A is the nonlinear ity parameter of liquids. It can be written as: where T 1s the absolute temperature c... equipment, Butler (1977) encountered difficulty in obtaining a narrow beam in salt. The sound speed i n salt is higher than the sound speed in the coupling fluid (castor oil or glycerin). Therefore, coupling sound energy into salt, with a coupling fluid...

Wang, Albert Min-Hao

1980-01-01T23:59:59.000Z

297

Electrolyte materials containing highly dissociated metal ion salts  

DOE Patents [OSTI]

The present invention relates to metal ion salts which can be used in electrolytes for producing electrochemical devices, including both primary and secondary batteries, photoelectrochemical cells and electrochromic displays. The salts have a low energy of dissociation and may be dissolved in a suitable polymer to produce a polymer solid electrolyte or in a polar aprotic liquid solvent to produce a liquid electrolyte. The anion of the salts may be covalently attached to polymer backbones to produce polymer solid electrolytes with exclusive cation conductivity.

Lee, Hung-Sui (East Setauket, NY); Geng, Lin (Coram, NY); Skotheim, Terje A. (Shoreham, NY)

1996-07-23T23:59:59.000Z

298

Electrolyte materials containing highly dissociated metal ion salts  

DOE Patents [OSTI]

The present invention relates to metal ion salts which can be used in electrolytes for producing electrochemical devices, including both primary and secondary batteries, photoelectrochemical cells and electrochromic displays. The salts have a low energy of dissociation and may be dissolved in a suitable polymer to produce a polymer solid electrolyte or in a polar aprotic liquid solvent to produce a liquid electrolyte. The anion of the salts may be covalently attached to polymer backbones to produce polymer solid electrolytes with exclusive cation conductivity. 2 figs.

Lee, H.S.; Geng, L.; Skotheim, T.A.

1996-07-23T23:59:59.000Z

299

The Thorium Molten Salt Reactor : Moving on from the MSBR  

E-Print Network [OSTI]

A re-evaluation of the Molten Salt Breeder Reactor concept has revealed problems related to its safety and to the complexity of the reprocessing considered. A reflection is carried out anew in view of finding innovative solutions leading to the Thorium Molten Salt Reactor concept. Several main constraints are established and serve as guides to parametric evaluations. These then give an understanding of the influence of important core parameters on the reactor's operation. The aim of this paper is to discuss this vast research domain and to single out the Molten Salt Reactor configurations that deserve further evaluation.

L. Mathieu; D. Heuer; R. Brissot; C. Le Brun; E. Liatard; J. M. Loiseaux; O. Méplan; E. Merle-Lucotte; A. Nuttin; J. Wilson; C. Garzenne; D. Lecarpentier; E. Walle; the GEDEPEON Collaboration

2005-06-02T23:59:59.000Z

300

Experimental Investigation of Two-Phase Flow in Rock Salt  

SciTech Connect (OSTI)

This Test Plan describes procedures for conducting laboratory scale flow tests on intact, damaged, crushed, and consolidated crushed salt to measure the capillary pressure and relative permeability functions. The primary focus of the tests will be on samples of bedded geologic salt from the WIPP underground. However, the tests described herein are directly applicable to domal salt. Samples being tested will be confined by a range of triaxial stress states ranging from atmospheric pressure up to those approximating lithostatic. Initially these tests will be conducted at room temperature, but testing procedures and equipment will be evaluated to determine adaptability to conducting similar tests under elevated temperatures.

Malama, Bwalya; Howard, Clifford L.

2014-07-01T23:59:59.000Z

Note: This page contains sample records for the topic "nitrate salt central" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Engineering Evaluation of Proposed Alternative Salt Transfer Method for the Molten Salt Reactor Experiement for the Oak Ridge National Laboratory  

SciTech Connect (OSTI)

This evaluation was performed by Pro2Serve in accordance with the Technical Specification for an Engineering Evaluation of the Proposed Alternative Salt Transfer Method for the Molten Salt Reactor Experiment at the Oak Ridge National Laboratory (BJC 2009b). The evaluators reviewed the Engineering Evaluation Work Plan for Molten Salt Reactor Experiment Residual Salt Removal, Oak Ridge National Laboratory, Oak Ridge, Tennessee (DOE 2008). The Work Plan (DOE 2008) involves installing a salt transfer probe and new drain line into the Fuel Drain Tanks and Fuel Flush Tank and connecting them to the new salt transfer line at the drain tank cell shield. The probe is to be inserted through the tank ball valve and the molten salt to the bottom of the tank. The tank would then be pressurized through the Reactive Gas Removal System to force the salt into the salt canisters. The Evaluation Team reviewed the work plan, interviewed site personnel, reviewed numerous documents on the Molten Salt Reactor (Sects. 7 and 8), and inspected the probes planned to be used for the transfer. Based on several concerns identified during this review, the team recommends not proceeding with the salt transfer via the proposed alternate salt transfer method. The major concerns identified during this evaluation are: (1) Structural integrity of the tanks - The main concern is with the corrosion that occurred during the fluorination phase of the uranium removal process. This may also apply to the salt transfer line for the Fuel Flush Tank. Corrosion Associated with Fluorination in the Oak Ridge National Laboratory Fluoride Volatility Process (Litman 1961) shows that this problem is significant. (2) Continued generation of Fluorine - Although the generation of Fluorine will be at a lower rate than experienced before the uranium removal, it will continue to be generated. This needs to be taken into consideration regardless of what actions are taken with the salt. (3) More than one phase of material - There are likely multiple phases of material in the salt (metal or compound), either suspended through the salt matrix, layered in the bottom of the tank, or both. These phases may contribute to plugging during any planned transfer. There is not enough data to know for sure. (4) Probe heat trace - The alternate transfer method does not include heat tracing of the bottom of the probe. There is a concern that this may cool the salt and other phases of materials present enough to block the flow of salt. (5) Stress-corrosion cracking - Additionally, there is a concern regarding moisture that may have been introduced into the tanks. Due to time constraints, this concern was not validated. However, if moisture was introduced into the tanks and not removed during heating the tanks before HF and F2 sparging, there would be an additional concern regarding the potential for stress-corrosion cracking of the tank walls.

Carlberg, Jon A.; Roberts, Kenneth T.; Kollie, Thomas G.; Little, Leslie E.; Brady, Sherman D.

2009-09-30T23:59:59.000Z

302

Low time resolution analysis of polar ice cores cannot detect impulsive nitrate events  

E-Print Network [OSTI]

Ice cores are archives of climate change and possibly large solar proton events (SPEs). Wolff et al. (2012) used a single event, a nitrate peak in the GISP2-H core, which McCracken et al. (2001a) time associated with the poorly quantified 1859 Carrington event, to discredit SPE-produced, impulsive nitrate deposition in polar ice. This is not the ideal test case. We critique the Wolff et al. analysis and demonstrate that the data they used cannot detect impulsive nitrate events because of resolution limitations. We suggest re-examination of the top of the Greenland ice sheet at key intervals over the last two millennia with attention to fine resolution and replicate sampling of multiple species. This will allow further insight into polar depositional processes on a sub-seasonal scale, including atmospheric sources, transport mechanisms to the ice sheet, post-depositional interactions, and a potential SPE association.

Smart, D F; Melott, A L; Laird, C M

2015-01-01T23:59:59.000Z

303

Centralized maintenance procedures  

SciTech Connect (OSTI)

In 1989, shortly after Westinghouse Hanford Company (WHC) assumed maintenance responsibilities for the Hanford site, a Department of Energy (DOE) maintenance audit found that field (working level) maintenance procedures and procedure practices of the facilities scattered across Hanford`s 560 square miles varied as greatly as the locations of those facilities. In some of the audited facilities there were few or no procedures; in others, procedures conflicted with or were redundant to procedures at other facilities. This document presents current efforts to centralize maintenance procedures.

Barber, J.R.

1994-02-01T23:59:59.000Z

304

Centralized Procurement Program  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc DocumentationP-Series to User Group and User ExecutiveCentral Activator Keeps

305

ARM - SGP Central Facility  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc Documentation RUC :ProductsSCM Forcing Data DerivedInstrumentsPolar YearResearchBoundaryCentral

306

A search for regulatory mutants of the nitrate utilization pathway of Neurospora Crassa  

E-Print Network [OSTI]

A SEARCH FOR REGULATORI MUTANTS OF THE NITRATE UTILIZATION PATHWAl OF NEUROSPORA CRASSA A Thesis by CLAUDE STEVEN MCDANIEL Submitted to the Graduate College of Texas ARM University in partial fu1fillment of the requirements for the degree... of MASTER OF SCIENCE December 1976 Major Subject: Genetics A SEARCH FOR REGULATORY MUTANTS OF THE NITRATE U1'IIIZA1'ION PA1'NNAY OF ~N A Thesis by CLAUDE STEVEN MCDANIEL Approved as to style and content by: (Chairman of Committ e) (Head oi' epar...

McDaniel, Claude Steven

1976-01-01T23:59:59.000Z

307

Salt Wells Geothermal Exploratory Drilling Program EA(DOI-BLM...  

Open Energy Info (EERE)

Drilling Program EA (DOI-BLM-NV-C010-2009-0006-EA) Jump to: navigation, search OpenEI Reference LibraryAdd to library Web Site: Salt Wells Geothermal Exploratory Drilling Program...

308

Regional Gravity Survey of the Northern Great Salt Lake Desert...  

Open Energy Info (EERE)

navigation, search OpenEI Reference LibraryAdd to library Journal Article: Regional Gravity Survey of the Northern Great Salt Lake Desert and Adjacent Areas in Utah, Nevada, and...

309

Molten Salt Breeder Reactors Academia Sinica, ITRI, NTHU  

E-Print Network [OSTI]

Molten Salt Breeder Reactors HX Team* Academia Sinica, ITRI, NTHU 6 April 2012 *F. H. Shu, M. J MSRs Can Rid LWR Waste & Safely Breed for U-233 ­LWR spent fuel Th-232 Blanket ­U-238, U-235 in form

Wang, Ming-Jye

310

Expected brine movement at potential nuclear waste repository salt sites  

SciTech Connect (OSTI)

The BRINEMIG brine migration code predicts rates and quantities of brine migration to a waste package emplaced in a high-level nuclear waste repository in salt. The BRINEMIG code is an explicit time-marching finite-difference code that solves a mass balance equation and uses the Jenks equation to predict velocities of brine migration. Predictions were made for the seven potentially acceptable salt sites under consideration as locations for the first US high-level nuclear waste repository. Predicted total quantities of accumulated brine were on the order of 1 m/sup 3/ brine per waste package or less. Less brine accumulation is expected at domal salt sites because of the lower initial moisture contents relative to bedded salt sites. Less total accumulation of brine is predicted for spent fuel than for commercial high-level waste because of the lower temperatures generated by spent fuel. 11 refs., 36 figs., 29 tabs.

McCauley, V.S.; Raines, G.E.

1987-08-01T23:59:59.000Z

311

Independent Oversight Review, Savannah River Site Salt Waste...  

Office of Environmental Management (EM)

2014 April 2014 Review of the Savannah River Site Salt Waste Processing Facility Construction Quality and Fire Protection Systems The U.S. Department of Energy (DOE) Office of...

312

Energy Department Completes Salt Coolant Material Transfer to...  

Broader source: Energy.gov (indexed) [DOE]

from the salt coolant material testing by e and in other technical areas of mutual interest. "The United States is committed to working closely with the Czech Republic to...

313

Continuous Commissioning of Salt Lake Community College South City Campus  

E-Print Network [OSTI]

The State of Utah's Department of Natural Resources funded two projects in Salt Lake City to demonstrate the feasibility of the Continuous Commissioning® (CC®)1 process. The two sites selected were a modern state building, the Matheson Courthouse [1...

Deng, S.; Turner, W. D.; Hood, J.

2004-01-01T23:59:59.000Z

314

Apparatus and method for making metal chloride salt product  

DOE Patents [OSTI]

A method of producing metal chlorides is disclosed in which chlorine gas is introduced into liquid Cd. CdCl.sub.2 salt is floating on the liquid Cd and as more liquid CdCl.sub.2 is formed it separates from the liquid Cd metal and dissolves in the salt. The salt with the CdCl.sub.2 dissolved therein contacts a metal which reacts with CdCl.sub.2 to form a metal chloride, forming a mixture of metal chloride and CdCl.sub.2. After separation of bulk Cd from the salt, by gravitational means, the metal chloride is obtained by distillation which removes CdCl.sub.2 and any Cd dissolved in the metal chloride.

Miller, William E. (Naperville, IL); Tomczuk, Zygmunt (Homer Glen, IL); Richmann, Michael K. (Carlsbad, NM)

2007-05-15T23:59:59.000Z

315

Liquid Salt Heat Exchanger Technology for VHTR Based Applications  

SciTech Connect (OSTI)

The objective of this research is to evaluate performance of liquid salt fluids for use as a heat carrier for transferring high-temperature process heat from the very high-temperature reactor (VHTR) to chemical process plants. Currently, helium is being considered as the heat transfer fluid; however, the tube size requirements and the power associated with pumping helium may not be economical. Recent work on liquid salts has shown tremendous potential to transport high-temperature heat efficiently at low pressures over long distances. This project has two broad objectives: To investigate the compatibility of Incoloy 617 and coated and uncoated SiC ceramic composite with MgCl2-KCl molten salt to determine component lifetimes and aid in the design of heat exchangers and piping; and, To conduct the necessary research on the development of metallic and ceramic heat exchangers, which are needed for both the helium-to-salt side and salt-to-process side, with the goal of making these heat exchangers technologically viable. The research will consist of three separate tasks. The first task deals with material compatibility issues with liquid salt and the development of techniques for on-line measurement of corrosion products, which can be used to measure material loss in heat exchangers. Researchers will examine static corrosion of candidate materials in specific high-temperature heat transfer salt systems and develop an in situ electrochemical probe to measure metallic species concentrations dissolved in the liquid salt. The second task deals with the design of both the intermediate and process side heat exchanger systems. Researchers will optimize heat exchanger design and study issues related to corrosion, fabrication, and thermal stresses using commercial and in-house codes. The third task focuses integral testing of flowing liquid salts in a heat transfer/materials loop to determine potential issues of using the salts and to capture realistic behavior of the salts in a small scale prototype system. This includes investigations of plugging issues, heat transfer, pressure drop, and the corrosion and erosion of materials in the flowing system.

Mark Anderson; Kumar Sridhara; Todd Allen; Per Peterson

2012-10-11T23:59:59.000Z

316

Study of maximizing acoustic energy coupling to salt  

E-Print Network [OSTI]

CHAPTER I INTRODUCTION Statement of the Problem The knowledge of the geologic discontinuities in the salt which lie in front of a mining face is a great value for both economic and safety reasons. This knowledge can be obtained by core drilling... at the transducer/ coupling media and coupling media/salt boundaries can be considered as being separate and mutually independent. The coupling problem would then be treated by evaluating the normal incidence reflection coefficients at the transducer/ coupling...

Hwang, Yng-Jou

1979-01-01T23:59:59.000Z

317

Le Thorium Molten Salt Reactor : Au del du MSBR  

E-Print Network [OSTI]

Le Thorium Molten Salt Reactor : Au delà du MSBR L. Mathieu, D. Heuer, A. Billebaud, R. Brissot, C réflexion est menée afin de trou- ver des solutions et ainsi d'aboutir au concept du Thorium Mol- ten Salt optimale du minerai d'uranium ou de thorium, une conception résistante à la prolifération, une meilleur

Paris-Sud XI, Université de

318

Vertebrate survey of a dredge spoil salt marsh  

E-Print Network [OSTI]

]ect: Wildlife and Fisheries Science VERTEBRATE SURVEY OF A DREDGE SPOIL SALT MARSH A Thesis by BETTY JO LEE Approved as to style and content by: (Chairman of Committee) (Head of Department) (Member) (Member) December 1976 ABSTRACT Vertebrate Survey... of this ecotone are salinity, amount of fresh water, agitation by tides and currents, temperatut'e, wind, and industrial pollutants (Odum 1971). Clark (1974) points out the environmental importance of salt marshes to the waters of estuaries and bays by acting...

Lee, Betty Jo

1976-01-01T23:59:59.000Z

319

Alkyl nitrate (C1-C3) depth profiles in the tropical Pacific Ocean E. E. Dahl,1,2  

E-Print Network [OSTI]

and distribution of tropo- spheric ozone. Atmospheric alkyl nitrates are normally associated with polluted air free radical processes initiated by radioactive decay or cosmic rays, enzymatically mediated reactions expedition in the equatorial Pacific, an equatorial maximum in atmospheric ethyl and isopropyl nitrate

Saltzman, Eric

320

Biological Oxidation of Fe(II) in Reduced Nontronite Coupled with Nitrate Reduction by Pseudogulbenkiania sp. Strain 2002  

SciTech Connect (OSTI)

Nitrate contamination in soils, sediments, and water bodies is a significant issue. Although much is known about nitrate degradation in these environments, especially via microbial pathways, a complete understanding of all degradation processes, especially in clay mineral-rich soils, is still lacking. The objective of this study was to study the potential of removing nitrate contaminant using structural Fe(II) in clay mineral nontronite. Specifically, the coupled processes of microbial oxidation of Fe(II) in microbially reduced nontronite (NAu-2) and nitrate reduction by Pseudogulbenkiania species strain 2002 was investigated. Bio-oxidation experiments were conducted in bicarbonate-buffered medium under both growth and nongrowth conditions. The extents of Fe(II) oxidation and nitrate reduction were measured by wet chemical methods. X-ray diffraction (XRD), scanning and transmission electron microscopy (SEM and TEM), and 57Fe-Mössbauer spectroscopy were used to observe mineralogical changes associated with Fe(III) reduction and Fe(II) oxidation in nontronite. The bio-oxidation extent under growth and nongrowth conditions reached 93% and 57%, respectively. Over the same time period, nitrate was completely reduced under both conditions to nitrogen gas (N2), via an intermediate product nitrite. Magnetite was a mineral product of nitrate-dependent Fe(II) oxidation, as evidenced by XRD data and TEM diffraction patterns. The results of this study highlight the importance of iron-bearing clay minerals in the global nitrogen cycle with potential applications in nitrate removal in soils.

Zhao, Linduo; Dong, Hailiang; Kukkadapu, Ravi K.; Agrawal, A.; Liu, Deng; Zhang, Jing; Edelmann, Richard E.

2013-10-15T23:59:59.000Z

Note: This page contains sample records for the topic "nitrate salt central" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

NITRATE UTILIZATION BY PHYTOPLANKTON IN LAKE SUPERIOR IS IMPAIRED BY LOW NUTRIENT (P, Fe) AVAILABILITY AND SEASONAL LIGHT LIMITATION--  

E-Print Network [OSTI]

NITRATE UTILIZATION BY PHYTOPLANKTON IN LAKE SUPERIOR IS IMPAIRED BY LOW NUTRIENT (P, Fe utilization in this oligotrophic system. Clean sampling methods were used to collect water from Lake Superior during spring and summer 2004, and nitrate utilization was measured by monitoring bioreporter

Sterner, Robert W.

322

Isotopic evidence for source changes of nitrate in rain at Bermuda Meredith Galanter Hastings and Daniel M. Sigman  

E-Print Network [OSTI]

), or nitrate (NO3 Ã? ), is a significant contributor to acid rain, an important species in marineIsotopic evidence for source changes of nitrate in rain at Bermuda Meredith Galanter Hastings O is 68.6% and 76.9% (versus Vienna Standard Mean Ocean Water). The few cool season rain events

Sigman, Daniel M.

323

Structural Changes of Bimetallic PdX/Cu (1-X) Nanocatalysts Developed for Nitrate Reduction of Drinking Water  

E-Print Network [OSTI]

of Drinking Water Huiping Xu1,2 , Ray Twesten3 , Kathryn Guy4 , John Shapley4 , Charles Werth5 , Anatoly alternative for nitrate removal in drinking water [1]. Fundamental understanding how the atomic arrangement for the purification of drinking water. INTRODUCTION Presently nitrate in drinking water is either not removed

Frenkel, Anatoly

324

Selective Solid-Liquid Extraction of Lithium Halide Salts Using a Ditopic Macrobicyclic Receptor  

E-Print Network [OSTI]

pairs. The receptor can transport these salts from an aqueous phase through a liquid organic membrane and membrane transport, almost all reported efforts have focused on the transfer of lithium salts from this by binding the salts as contact ion pairs. Receptor 1 can also transport alkali metal halide salts out

Smith, Bradley D.

325

CAVERN ROOF STABILITY FOR NATURAL GAS STORAGE IN BEDDED SALT  

SciTech Connect (OSTI)

This report documents research performed to develop a new stress-based criterion for predicting the onset of damage in salt formations surrounding natural gas storage caverns. Laboratory tests were conducted to investigate the effects of shear stress, mean stress, pore pressure, temperature, and Lode angle on the strength and creep characteristics of salt. The laboratory test data were used in the development of the new criterion. The laboratory results indicate that the strength of salt strongly depends on the mean stress and Lode angle. The strength of the salt does not appear to be sensitive to temperature. Pore pressure effects were not readily apparent until a significant level of damage was induced and the permeability was increased to allow penetration of the liquid permeant. Utilizing the new criterion, numerical simulations were used to estimate the minimum allowable gas pressure for hypothetical storage caverns located in a bedded salt formation. The simulations performed illustrate the influence that cavern roof span, depth, roof salt thickness, shale thickness, and shale stiffness have on the allowable operating pressure range. Interestingly, comparison of predictions using the new criterion with that of a commonly used criterion indicate that lower minimum gas pressures may be allowed for caverns at shallow depths. However, as cavern depth is increased, less conservative estimates for minimum gas pressure were determined by the new criterion.

Kerry L. DeVries; Kirby D. Mellegard; Gary D. Callahan; William M. Goodman

2005-06-01T23:59:59.000Z

326

EIS-0099: Remedial Actions at the Former Vitro Chemical Company Site, South Salt Lake, Salt Lake County, Utah  

Broader source: Energy.gov [DOE]

The U.S. Department of Energy developed this statement to evaluate the environmental impacts of various scenarios associated with the cleanup of those residues remaining at the abandoned uranium mill tailings site located in South Salt Lake, Utah.

327

Application of a modified denitrifying bacteria method for analyzing groundwater and vadose zone pore water nitrate at the Hanford Site, WA, USA.  

E-Print Network [OSTI]

zone pore water nitrate at the Hanford Site, WA, USA. Woods,and Conrad, Mark The Hanford Site in southern WashingtonL have been reported for Hanford groundwaters, where nitrate

Woods, Katharine N.; Singleton, Michael J.; Conrad, Mark

2003-01-01T23:59:59.000Z

328

The Effects of Nanoparticle Augmentation of Nitrate Thermal Storage Materials for Use in Concentrating Solar Power Applications  

E-Print Network [OSTI]

The Department of Energy funded a project to determine if the specific heat of thermal energy storage materials could be improved by adding nanoparticles. The standard thermal energy storage materials are molten salts. The chosen molten salt was a...

Betts, Matthew

2011-08-08T23:59:59.000Z

329

LIFE Materails: Molten-Salt Fuels Volume 8  

SciTech Connect (OSTI)

The goals of the Laser Inertial Fusion Fission Energy (LIFE) is to use fusion neutrons to fission materials with no enrichment and minimum processing and have greatly reduced wastes that are not of interest to making weapons. Fusion yields expected to be achieved in NIF a few times per day are called for with a high reliable shot rate of about 15 per second. We have found that the version of LIFE using TRISO fuel discussed in other volumes of this series can be modified by replacing the molten-flibe-cooled TRISO fuel zone with a molten salt in which the same actinides present in the TRISO particles are dissolved in the molten salt. Molten salts have the advantage that they are not subject to radiation damage, and hence overcome the radiation damage effects that may limit the lifetime of solid fuels such as TRISO-containing pebbles. This molten salt is pumped through the LIFE blanket, out to a heat exchanger and back into the blanket. To mitigate corrosion, steel structures in contact with the molten salt would be plated with tungsten or nickel. The salt will be processed during operation to remove certain fission products (volatile and noble and semi-noble fission products), impurities and corrosion products. In this way neutron absorbers (fission products) are removed and neutronics performance of the molten salt is somewhat better than that of the TRISO fuel case owing to the reduced parasitic absorption. In addition, the production of Pu and rare-earth elements (REE) causes these elements to build up in the salt, and leads to a requirement for a process to remove the REE during operation to insure that the solubility of a mixed (Pu,REE)F3 solid solution is not exceeded anywhere in the molten salt system. Removal of the REE will further enhance the neutronics performance. With molten salt fuels, the plant would need to be safeguarded because materials of interest for weapons are produced and could potentially be removed.

Moir, R; Brown, N; Caro, A; Farmer, J; Halsey, W; Kaufman, L; Kramer, K; Latkowski, J; Powers, J; Shaw, H; Turchi, P

2008-12-11T23:59:59.000Z

330

Central solar energy receiver  

DOE Patents [OSTI]

An improved tower-mounted central solar energy receiver for heating air drawn through the receiver by an induced draft fan. A number of vertically oriented, energy absorbing, fin-shaped slats are radially arranged in a number of concentric cylindrical arrays on top of the tower coaxially surrounding a pipe having air holes through which the fan draws air which is heated by the slats which receive the solar radiation from a heliostat field. A number of vertically oriented and wedge-shaped columns are radially arranged in a number of concentric cylindrical clusters surrounding the slat arrays. The columns have two mirror-reflecting sides to reflect radiation into the slat arrays and one energy absorbing side to reduce reradiation and reflection from the slat arrays.

Drost, M. Kevin (Richland, WA)

1983-01-01T23:59:59.000Z

331

Assessment of the Use of Nitrogen Trifluoride for Purifying Coolant and Heat Transfer Salts in the Fluoride Salt-Cooled High-Temperature Reactor  

SciTech Connect (OSTI)

This report provides an assessment of the use of nitrogen trifluoride for removing oxide and water-caused contaminants in the fluoride salts that will be used as coolants in a molten salt cooled reactor.

Scheele, Randall D.; Casella, Andrew M.

2010-09-28T23:59:59.000Z

332

Gas/particle partitioning of total alkyl nitrates observed with TD-LIF in Bakersfield  

E-Print Network [OSTI]

total AN (gas + aerosol) and ANaer show that on average 21% of ANs are in the condensed phaseGas/particle partitioning of total alkyl nitrates observed with TD-LIF in Bakersfield A. W. Rollins samples. These measurements show that ANs are a ubiquitous component of the OA with the ­ONO2 subunit

Cohen, Ronald C.

333

Effect of nitrate on the performance of single chamber air cathode microbial fuel cells  

E-Print Network [OSTI]

Effect of nitrate on the performance of single chamber air cathode microbial fuel cells Chontisa Accepted 26 August 2008 Published online 11 September 2008 Keywords: Microbial fuel cell Denitrification microbial fuel cells (MFCs) has drawn much attention recently as a new approach of waste- water treatment

Tullos, Desiree

334

Nitrogen sources and cycling in the San Francisco Bay Estuary: A nitrate dual isotopic composition approach  

E-Print Network [OSTI]

as 25.0%) at the Sacramento­San Joaquin River delta region give rise to a wide range of d18ONO3 valuesNitrogen sources and cycling in the San Francisco Bay Estuary: A nitrate dual isotopic composition18O) within the estuarine system of San Francisco (SF) Bay, California, to explore the utility

Paytan, Adina

335

Soil Tillage Influences on Soil Mineral Nitrogen and Nitrate Leaching in  

E-Print Network [OSTI]

Soil Tillage Influences on Soil Mineral Nitrogen and Nitrate Leaching in Swedish Arable Soils Åsa Myrbeck Faculty of Natural Resources and Agricultural Sciences Department of Soil and Environment Uppsala field experiment, Paper III. (photo: J. Arvidsson) #12;Soil Tillage Influences on Soil Mineral Nitrogen

336

Quantifying uncertainty in nitrate pollution from land application of sewage sludge  

SciTech Connect (OSTI)

Uncertainty associated with nitrate-nitrogen pollution of ground water from sludge applications was investigated. Three alternative planning models were proposed. The models estimate annual loads and concentrations of nitrate-nitrogen in percolation. Published data from four field studies that included aerobic and anaerobic sludge and surface- and soil-incorporated applications were used for model testing. Point and stochastic validation procedures were used. The models were generally conservative. For three data sets average relative errors were approximately +/- 25% for all three models. The fourth data set had average relative errors of 100-500%. Wilcoxon Signed Rank test results (at ..cap alpha.. = 5%) suggested point-model predictions and observations were drawn from similar distributions. Stochastic validation tests also suggested that observations were samples from distributions of predictions. The models were tested as uncalibrated approximations of nitrate percolation. All three appear sufficiently accurate for planning application systems. A planning procedure was developed which utilizes analytically approximated probability distributions of nitrate loads and concentrations. Distributions are specified with analytical moment expressions and a normal distribution function limited to be non-negative.

Mummert, M.C.

1987-01-01T23:59:59.000Z

337

Materials Chemistry and Physics 100 (2006) 3840 X-ray irradiation induced degradation of cellulose nitrate  

E-Print Network [OSTI]

Abstract Energy-dispersive X-ray fluorescence (EDXRF) spectrometry was previously proposed to measure energy-dispersive X-ray fluorescence (EDXRF) spectrometry. For that method, a reference silver nitrate-ray energy is high enough to avoid total a

Yu, K.N.

338

Alkyl nitrate (C 1 -C 3 ) depth profiles in the tropical Pacific Ocean  

E-Print Network [OSTI]

concentrations with a [ iPr]/[Et] ratio of 0.1±0.0. Noat all depths with an [iPr]/[Et] ratio of 0.2 ± 0.0. Thiswith ethyl nitrate with an [iPr]/[Et] ratio of 0.2 ± 0.0.

Dahl, E. E; Yvon-Lewis, S. A; Saltzman, E. S

2007-01-01T23:59:59.000Z

339

Nitrate and colloid transport through coarse Hanford sediments under steady state, variably saturated flow  

E-Print Network [OSTI]

Nitrate and colloid transport through coarse Hanford sediments under steady state, variably] At the U.S. Department of Energy's Hanford Reservation, colloid-facilitated transport is a potential of colloids through Hanford sediments under steady state, unsaturated flow conditions. We isolated colloids

Flury, Markus

340

Water and nitrate exchange between cultivated ecosystems and groundwater in the Rolling Pampas  

E-Print Network [OSTI]

model (UPFLOW) suggested that at TS groundwater supplied an importanWater and nitrate exchange between cultivated ecosystems and groundwater in the Rolling Pampas Agropecuaria Parana´, INTA, Ruta 11 km 12.5, 3101 Oro Verde, Argentina 1. Introduction Biogeochemical exchange

Nacional de San Luis, Universidad

Note: This page contains sample records for the topic "nitrate salt central" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Combined Effects of UV-B, Nitrate, and Low pH Reduce the Survival and Activity Level of Larval Cascades Frogs (Rana cascadae)  

E-Print Network [OSTI]

Combined Effects of UV-B, Nitrate, and Low pH Reduce the Survival and Activity Level of Larval. We investigated interactions between low pH, high nitrate level, and ultraviolet-B (UV-B) light were significantly reduced in the treatment with low pH, high nitrate, and UV-B together. In both years

Blaustein, Andrew R.

342

Remediation of brine-contaminated soil using calcium nitrate, gypsum, and straw.  

E-Print Network [OSTI]

??Salt-affected soils from point source brine contamination are common in the active oil field in SE Saskatchewan. A remediation process that included dewatering by sub-surface… (more)

Nielsen, Jennifer I.

2013-01-01T23:59:59.000Z

343

Molten Salts for High Temperature Reactors: University of Wisconsin Molten Salt Corrosion and Flow Loop Experiments -- Issues Identified and Path Forward  

SciTech Connect (OSTI)

Considerable amount of work is going on regarding the development of high temperature liquid salts technology to meet future process needs of Next Generation Nuclear Plant. This report identifies the important characteristics and concerns of high temperature molten salts (with lesson learned at University of Wisconsin-Madison, Molten Salt Program) and provides some possible recommendation for future work

Piyush Sabharwall; Matt Ebner; Manohar Sohal; Phil Sharpe; Thermal Hydraulics Group

2010-03-01T23:59:59.000Z

344

In-Drift Precipitates/Salts Model  

SciTech Connect (OSTI)

As directed by ''Technical Work Plan For: Engineered Barrier System Department Modeling and Testing FY03 Work Activities'' (BSC 2003 [165601]), the In-Drift Precipitates/Salts (IDPS) model is developed and refined to predict the aqueous geochemical effects of evaporation in the proposed repository. The purpose of this work is to provide a model for describing and predicting the postclosure effects of evaporation and deliquescence on the chemical composition of water within the proposed Engineered Barrier System (EBS). Application of this model is to be documented elsewhere for the Total System Performance Assessment License Application (TSPA-LA). The principal application of this model is to be documented in REV 02 of ''Engineered Barrier System: Physical and Chemical Environment Model'' (BSC 2003 [165601]). The scope of this document is to develop, describe, and validate the IDPS model. This model is a quasi-equilibrium model. All reactions proceed to equilibrium except for several suppressed minerals in the thermodynamic database not expected to form under the proposed repository conditions within the modeling timeframe. In this revision, upgrades to the EQ3/6 code (Version 8.0) and Pitzer thermodynamic database improve the applicable range of the model. These new additions allow equilibrium and reaction-path modeling of evaporation to highly concentrated brines for potential water compositions of the system Na-K-H-Mg-Ca-Al-Cl-F-NO{sub 3}-SO{sub 4}-Br-CO{sub 3}-SiO{sub 2}-CO{sub 2}-O{sub 2}-H{sub 2}O at temperatures in the range of 0 C to 125 C, pressures in the atmospheric range, and relative humidity in the range of 0 to 100 percent. This system applies to oxidizing conditions only, and therefore limits the model to applications involving oxidizing conditions. A number of thermodynamic parameters in the Pitzer database have values that have not been determined or verified for the entire temperature range. In these cases, the known values are used to approximate the values for the rest of the temperature range. Although such treatment contributes to uncertainty in model outputs, the model validation test cases indicate that the model, with its associated uncertainty, is valid for its intended use. The intended use of this model is to estimate and tabulate, within an appropriate level of confidence, the effects of evaporation, deliquescence, and potential environmental conditions on the pH, ionic strength, and chemical compositions of water and minerals on the drip shield or other location within the drift during the postclosure period.

P. Mariner

2003-10-21T23:59:59.000Z

345

High thermal energy storage density molten salts for parabolic trough solar power generation.  

E-Print Network [OSTI]

??New alkali nitrate-nitrite systems were developed by using thermodynamic modeling and the eutectic points were predicted based on the change of Gibbs energy of fusion.… (more)

Wang, Tao

2011-01-01T23:59:59.000Z

346

Oil field waste disposal in salt caverns: An information website  

SciTech Connect (OSTI)

Argonne National Laboratory has completed the construction of a Website for the US Department of Energy (DOE) that provides detailed information on salt caverns and their use for disposing of nonhazardous oil field wastes (NOW) and naturally occurring radioactive materials (NORM). Specific topics in the Website include the following: descriptions of salt deposits and salt caverns within the US, salt cavern construction methods, potential types of wastes, waste emplacement, regulatory issues, costs, carcinogenic and noncarcinogenic human health risks associated with postulated cavern release scenarios, new information on cavern disposal (e.g., upcoming meetings, regulatory issues, etc.), other studies supported by the National Petroleum Technology Office (NPTO) (e.g., considerations of site location, cavern stability, development issues, and bedded salt characterization in the Midland Basin), and links to other associated Web sites. In addition, the Website allows downloadable access to reports prepared on the topic that were funded by DOE. Because of the large quantities of NOW and NORM wastes generated annually by the oil industry, information presented on this Website is particularly interesting and valuable to project managers, regulators, and concerned citizens.

Tomasko, D.; Veil, J. A.

1999-12-10T23:59:59.000Z

347

Vitrification of IFR and MSBR halide salt reprocessing wastes  

SciTech Connect (OSTI)

Both of the genuinely sustainable (breeder) nuclear fuel cycles (IFR - Integral Fast Reactor - and MSBR - Molten Salt Breeder Reactor -) studied by the USA's national laboratories would generate high level reprocessing waste (HLRW) streams consisting of a relatively small amount ( about 4 mole %) of fission product halide (chloride or fluoride) salts in a matrix comprised primarily (about 95 mole %) of non radioactive alkali metal halide salts. Because leach resistant glasses cannot accommodate much of any of the halides, most of the treatment scenarios previously envisioned for such HLRW have assumed a monolithic waste form comprised of a synthetic analog of an insoluble crystalline halide mineral. In practice, this translates to making a 'substituted' sodalite ('Ceramic Waste Form') of the IFR's chloride salt-based wastes and fluoroapatite of the MSBR's fluoride salt-based wastes. This paper discusses my experimental studies of an alternative waste management scenario for both fuel cycles that would separate/recycle the waste's halide and immobilize everything else in iron phosphate (Fe-P) glass. It will describe both how the work was done and what its results indicate about how a treatment process for both of those wastes should be implemented (fluoride and chloride behave differently). In either case, this scenario's primary advantages include much higher waste loadings, much lower overall cost, and the generation of a product (glass) that is more consistent with current waste management practices. (author)

Siemer, D.D. [Idaho National Laboratory, 12N 3167E, Idaho Falls, ID 83402 (United States)

2013-07-01T23:59:59.000Z

348

Effect of water in salt repositories. Final report  

SciTech Connect (OSTI)

Additional results confirm that during most of the consolidation of polycrystalline salt in brine, the previously proposed rate expression applies. The final consolidation, however, proceeds at a lower rate than predicted. The presence of clay hastens the consolidation process but does not greatly affect the previously observed relationship between permeability and void fraction. Studies of the migration of brine within polycrystalline salt specimens under stress indicate that the principal effect is the exclusion of brine as a result of consolidation, a process that evidently can proceed to completion. No clear effect of a temperature gradient could be identified. A previously reported linear increase with time of the reciprocal permeability of salt-crystal interfaces to brine was confirmed, though the rate of increase appears more nearly proportional to the product of sigma ..delta..P rather than sigma ..delta..P/sup 2/ (sigma is the uniaxial stress normal to the interface and ..delta..P is the hydraulic pressure drop). The new results suggest that a limiting permeability may be reached. A model for the permeability of salt-crystal interfaces to brine is developed that is reasonably consistent with the present results and may be used to predict the permeability of bedded salt. More measurements are needed, however, to choose between two limiting forms of the model.

Baes, C.F. Jr.; Gilpatrick, L.O.; Kitts, F.G.; Bronstein, H.R.; Shor, A.J.

1983-09-01T23:59:59.000Z

349

Method for making a uranium chloride salt product  

DOE Patents [OSTI]

The subject apparatus provides a means to produce UCl.sub.3 in large quantities without incurring corrosion of the containment vessel or associated apparatus. Gaseous Cl is injected into a lower layer of Cd where CdCl.sub.2 is formed. Due to is lower density, the CdCl.sub.2 rises through the Cd layer into a layer of molten LiCl--KCL salt where a rotatable basket containing uranium ingots is suspended. The CdCl.sub.2 reacts with the uranium to form UCl.sub.3 and Cd. Due to density differences, the Cd sinks down to the liquid Cd layer and is reused. The UCl.sub.3 combines with the molten salt. During production the temperature is maintained at about 600.degree. C. while after the uranium has been depleted the salt temperature is lowered, the molten salt is pressure siphoned from the vessel, and the salt product LiCl--KCl-30 mol % UCl.sub.3 is solidified.

Miller, William E. (Naperville, IL); Tomczuk, Zygmunt (Lockport, IL)

2004-10-05T23:59:59.000Z

350

Mechanical modeling of the growth of salt structures  

SciTech Connect (OSTI)

A 2D numerical model for studying the morphology and history of salt structures by way of computer simulations is presented. The model is based on conservation laws for physical systems, a fluid marker equation to keep track of the salt/sediments interface, and two constitutive laws for rocksalt. When buoyancy alone is considered, the fluid-assisted diffusion model predicts evolution of salt structures 2.5 times faster than the power-law creep model. Both rheological laws predict strain rates of the order of 4.0 {times} 10{sup {minus}15}s{sup {minus}1} for similar structural maturity level of salt structures. Equivalent stresses and viscosities predicted by the fluid-assisted diffusion law are 10{sup 2} times smaller than those predicted by the power-law creep rheology. Use of East Texas Basin sedimentation rates and power-law creep rheology indicate that differential loading is an effective mechanism to induce perturbations that amplify and evolve to mature salt structures, similar to those observed under natural geological conditions.

Alfaro, R.A.M.

1993-05-01T23:59:59.000Z

351

Development of high temperature transport technology for LiCl-KCl eutectic salt in pyroprocessing  

SciTech Connect (OSTI)

The development of high-temperature transport technologies for molten salt is a prerequisite and a key issue in the industrialization of pyro-reprocessing for advanced fuel cycle scenarios. The solution of a molten salt centrifugal pump was discarded because of the high corrosion power of a high temperature molten salt, so the suction pump solution was selected. An apparatus for salt transport experiments by suction was designed and tested using LiC-KCl eutectic salt. The experimental results of lab-scale molten salt transport by suction showed a 99.5% transport rate (ratio of transported salt to total salt) under a vacuum range of 100 mtorr - 10 torr at 500 Celsius degrees. The suction system has been integrated to the PRIDE (pyroprocessing integrated inactive demonstration) facility that is a demonstrator using non-irradiated materials (natural uranium and surrogate materials). The performance of the suction pump for the transport of molten salts has been confirmed.

Lee, Sung Ho; Lee, Hansoo; Kim, In Tae; Kim, Jeong-Guk [Korea Atomic Energy Research Institute, 1045 Daedeok-daaro, Yuseong-gu, Daejeon, 305-353 (Korea, Republic of)

2013-07-01T23:59:59.000Z

352

Electrochemical Recovery of Sodium Hydroxide from Alkaline Salt Solution  

SciTech Connect (OSTI)

A statistically designed set of tests determined the effects of current density, temperature, and the concentrations of nitrate/nitrite, hydroxide and aluminate on the recovery of sodium as sodium hydroxide (caustic) from solutions simulating those produced from the Savannah River Site (SRS) In-Tank Precipitation process. These tests included low nitrate and nitrite concentrations which would be produced by electrolytic nitrate/nitrite destruction. The tests used a two compartment electrochemical cell with a Nafion Type 324 ion-exchange membrane. Caustic was successfully recovered from the waste solutions. Evaluation of the testing results indicated that the transport of sodium across the membrane was not significantly affected by any of the varied parameters. The observed variance in the sodium flux is attributed to experimental errors and variations in the performance characteristics of individual pieces of the organic-based Nafion membrane.Additional testing is recommended to determine the maximum current density, to evaluate the chemical durability of the organic membrane as a function of current density and to compare the durability and performance characteristics of the organic-based Nafion membrane with that of other commercially available organic membranes and the inorganic class of membranes under development by Ceramatec and PNNL.

Hobbs, D.T. [Westinghouse Savannah River Company, AIKEN, SC (United States); Edwards, T.B.

1996-10-01T23:59:59.000Z

353

1,4818 pour le nitrate d'uranyle). Les diffrents m-langes prsentaient sensiblement la mme densit.  

E-Print Network [OSTI]

434 1,4818 pour le nitrate d'uranyle). Les différents mé- langes présentaient sensiblement la mème pour des solutions de nitrate d'uranyle dont la densité a été reliée au moyen de chlorure ferrique nitrate d'uranyle sans chlorure fer- rique. En résumé, la mesure précise de l'activité des so- lutions de

Paris-Sud XI, Université de

354

In-Drift Precipitates/Salts Model  

SciTech Connect (OSTI)

This report documents the development and validation of the in-drift precipitates/salts (IDPS) model. The IDPS model is a geochemical model designed to predict the postclosure effects of evaporation and deliquescence on the chemical composition of water within the Engineered Barrier System (EBS) in support of the Total System Performance Assessment for the License Application (TSPA-LA). Application of the model in support of TSPA-LA is documented in ''Engineered Barrier System: Physical and Chemical Environment Model'' (BSC 2004 [DIRS 169860]). Technical Work Plan for: Near-Field Environment and Transport In-Drift Geochemistry Model Report Integration (BSC 2004 [DIRS 171156]) is the technical work plan (TWP) for this report. It called for a revision of the previous version of the report (BSC 2004 [DIRS 167734]) to achieve greater transparency, readability, data traceability, and report integration. The intended use of the IDPS model is to estimate and tabulate, within an appropriate level of confidence, the effects of evaporation, deliquescence, and potential environmental conditions on the pH, ionic strength, and chemical compositions of water and minerals on the drip shield or other location within the drift during the postclosure period. Specifically, the intended use is as follows: (1) To estimate, within an appropriate level of confidence, the effects of evaporation and deliquescence on the presence and composition of water occurring within the repository during the postclosure period (i.e., effects on pH, ionic strength, deliquescence relative humidity, total concentrations of dissolved components in the system Na-K-H-Mg-Ca-Al-Cl-F-NO{sub 3}-SO{sub 4}-Br-CO{sub 3}-SiO{sub 2}-CO{sub 2}-O{sub 2}-H{sub 2}O, and concentrations of the following aqueous species that potentially affect acid neutralizing capacity: HCO{sub 3}{sup -}, CO{sub 3}{sup 2-}, OH{sup -}, H{sup +}, HSO{sub 4}{sup -}, Ca{sup 2+}, Mg{sup 2+}, CaHCO{sub 3}{sup +}, MgHCO{sub 3}{sup +}, HSiO{sub 3}{sup -}, and MgOH{sup +}); (2) To estimate, within an appropriate level of confidence, mineral precipitation resulting from the evaporation of water occurring within the repository during the postclosure period (specifically, minerals of the system Na-K-H-Mg-Ca-Al-Cl-F-NO{sub 3}-SO{sub 4}-Br-CO{sub 3}-SiO{sub 2}-CO{sub 2}-O{sub 2}-H{sub 2}O); (3) To provide a means for abstracting these effects into a set of lookup tables that provide input to downstream models used for performance assessment. The presence and composition of liquid water in the drift depend upon relative humidity, temperature, incoming water composition, in-drift gas composition, and relative rates of evaporation and seepage. In downstream applications of this model, intended input values for these parameters are abstracted results from thermal-hydrological-chemical models, water sample measurements, dust leachate samples, and values used in sensitivity and uncertainty analyses that encompass the expected ranges of these parameters.

P. Mariner

2004-11-09T23:59:59.000Z

355

Stress measurements in rock salt using hydraulic fracturing  

SciTech Connect (OSTI)

Hydraulic fracturing was applied in horizontal drillholes in the Salado salt formation near Carlsbad, New Mexico. Testing took place approximately 650 m below surface in order to support the design of a Waste Isolation Pilot Plant (WIPP) for the disposal of radioactive waste from defense activities of the United States. Hydraulic fracturing was performed primarily to determine whether the virgin in situ stress state at the WIPP site is isotropic and whether the magnitudes of the the virgin in situ stresses correspond to the weight of the overburden. Beyond these limited objectives, measurements are being analyzed to evaluate the usefulness of hydraulic fracturing in salt formations in general. Such measurements are desirable to determine stresses induced by mining and to monitor time-dependent stress changes around underground excavations in salt masses. Hydraulic fracturing measurements are also relevant to the evaluation of allowable pressures before fracturing is induced in pressurized boreholes and storage caverns.

Wawersik, W.R.; Stone, C.M.

1986-01-01T23:59:59.000Z

356

Damage-induced nonassociated inelastic flow in rock salt  

SciTech Connect (OSTI)

The multi-mechanism deformation coupled fracture model recently developed by CHAN, et al. (1992), for describing time-dependent, pressure-sensitive inelastic flow and damage evolution in crystalline solids was evaluated against triaxial creep experiments on rock salt. Guided by experimental observations, the kinetic equation and the flow law for damage-induced inelastic flow in the model were modified to account for the development of damage and inelastic dilatation in the transient creep regime. The revised model was then utilized to obtain the creep response and damage evolution in rock salt as a function of confining pressure and stress difference. Comparison between model calculation and experiment revealed that damage-induced inelastic flow is nonassociated, dilatational, and contributes significantly to the macroscopic strain rate observed in rock salt deformed at low confining pressures. The inelastic strain rate and volumetric strain due to damage decrease with increasing confining pressures, and all are suppressed at sufficiently high confining pressures.

Chan, K.S.; Bodner, S.R. [Southwest Research Inst., San Antonio, TX (United States); Brodsky, N.S.; Fossum, A.F. [RE/SPEC, Inc., Rapid City, SD (United States); Munson, D.E. [Sandia National Labs., Albuquerque, NM (United States)

1993-06-01T23:59:59.000Z

357

Structure and Function of Metal- and Nitrate-reducing Microbial Communities in the FRC Subsurface  

SciTech Connect (OSTI)

The overall goal of this study is to evaluate structure-function relationships of sedimentary microbial communities likely to regulate U(VI) reduction and immobilization in the subsurface of Area 2 at the Field Research Center (FRC), Oak Ridge, TN. Microcosm experiments were conducted under near in situ conditions with FRC subsurface materials cocontaminated with high levels of U(VI) and nitrate. The activity, abundance, and community composition of microorganisms was determined in microcosm samples, stimulated with ethanol or glucose, and compared to those from sediment cores and unamended controls. Activity was assessed by monitoring terminal electron accepting processes (TEAPs; nitrate, sulfate, uranium, and iron reduction) as well as electron donor utilization. Microbial functional groups, nitrate- and iron(III)-reducing bacteria, were enumerated during the nitrate- and metal-reduction phases of the incubation and in sediment core samples using a most probable number (MPN) serial dilution assay. U(VI) and Fe(III) were reduced concurrently in the glucose but not the ethanol treatments. In ethanol-amended microcosms, U(VI) was reduced during a 4-day lag phase between nitrate- and Fe(III)-reduction phases. Biostimulation resulted in 3 to 5 orders of magnitude higher counts of Fe(III)-reducing bacteria, whereas populations of nitrate-reducers were enhanced by 1 to 3 orders of magnitude. One to 2 orders of magnitude more Fe(III)-reducers were observed in ethanol- as compared to glucose-amended treatments in parallel with enhanced U(VI) removal in ethanol treatments. Cultivatable Fe(III)-reducing bacteria in the ethanol treatments were dominated by Geobacter sp. while those cultured on glucose were dominated by fermentative organisms, i.e., Tolumonas sp. Currently, carbon substrate utilization is being examined through HPLC analysis of microcosm porewaters. In addition, changes in the overall microbial community composition are being assessed using cultivation-independent techniques, including fluorescence in situ hybridization (FISH), terminal restriction fragment length polymorphism analysis (T-RFLP) and cloning/sequencing of structural and functional genes. Our results indicate that the microbially-catalyzed mechanism of U(VI) reduction is electron donor dependent and that more effective U(VI) removal is achieved in parallel with an enrichment of Geobacter sp. upon treatment with ethanol.

Akob, Denise M.; Mills, Heath J.; Kerkhof, Lee; Gihring, Thomas M.; Kostk, Joel E.

2006-04-05T23:59:59.000Z

358

Salt transport extraction of transuranium elements from lwr fuel  

DOE Patents [OSTI]

A process of separating transuranium actinide values from uranium values present in spent nuclear oxide fuels which contain rare earth and noble metal fission products. The oxide fuel is reduced with Ca metal in the presence of CaCl.sub.2 and a Cu--Mg alloy containing not less than about 25% by weight Mg at a temperature in the range of from about 750.degree. C. to about 850.degree. C. to precipitate uranium metal and some of the noble metal fission products leaving the Cu--Mg alloy having transuranium actinide metals and rare earth fission product metals and some of the noble metal fission products dissolved therein. The CaCl.sub.2 having CaO and fission products of alkali metals and the alkali earth metals and iodine dissolved therein is separated and electrolytically treated with a carbon electrode to reduce the CaO to Ca metal while converting the carbon electrode to CO and CO.sub.2. The Ca metal and CaCl.sub.2 is recycled to reduce additional oxide fuel. The Cu--Mg alloy having transuranium metals and rare earth fission product metals and the noble metal fission products dissolved therein is contacted with a transport salt including Mg Cl.sub.2 to transfer Mg values from the transport salt to the Cu--Mg alloy while transuranium actinide and rare earth fission product metals transfer from the Cu--Mg alloy to the transport salt. Then the transport salt is mixed with a Mg--Zn alloy to transfer Mg values from the alloy to the transport salt while the transuranium actinide and rare earth fission product values dissolved in the salt are reduced and transferred to the Mg--Zn alloy.

Pierce, R. Dean (Naperville, IL); Ackerman, John P. (Downers Grove, IL); Battles, James E. (Oak Forest, IL); Johnson, Terry R. (Wheaton, IL); Miller, William E. (Naperville, IL)

1992-01-01T23:59:59.000Z

359

Salt transport extraction of transuranium elements from LWR fuel  

DOE Patents [OSTI]

A process is described for separating transuranium actinide values from uranium values present in spent nuclear oxide fuels which contain rare earth and noble metal fission products. The oxide fuel is reduced with Ca metal in the presence of CaCl[sub 2] and a Cu--Mg alloy containing not less than about 25% by weight Mg at a temperature in the range of from about 750 C to about 850 C to precipitate uranium metal and some of the noble metal fission products leaving the Cu--Mg alloy having transuranium actinide metals and rare earth fission product metals and some of the noble metal fission products dissolved therein. The CaCl[sub 2] having CaO and fission products of alkali metals and the alkali earth metals and iodine dissolved therein is separated and electrolytically treated with a carbon electrode to reduce the CaO to Ca metal while converting the carbon electrode to CO and CO[sub 2]. The Ca metal and CaCl[sub 2] is recycled to reduce additional oxide fuel. The Cu--Mg alloy having transuranium metals and rare earth fission product metals and the noble metal fission products dissolved therein is contacted with a transport salt including MgCl[sub 2] to transfer Mg values from the transport salt to the Cu--Mg alloy while transuranium actinide and rare earth fission product metals transfer from the Cu--Mg alloy to the transport salt. Then the transport salt is mixed with a Mg--Zn alloy to transfer Mg values from the alloy to the transport salt while the transuranium actinide and rare earth fission product values dissolved in the salt are reduced and transferred to the Mg--Zn alloy. 2 figs.

Pierce, R.D.; Ackerman, J.P.; Battles, J.E.; Johnson, T.R.; Miller, W.E.

1992-11-03T23:59:59.000Z

360

Seismic stratigraphy and salt tectonics along the Sigsbee Escarpment, southeastern Green Canyon region  

E-Print Network [OSTI]

nsobil layer of salt which has been emplaced at least 10 ? 15 km seav"ard as a result of sediment loading up dip by the Mississippi River. The tabular or lobate nature ol' salt in this region is nrarkedly different frona the typical domes and ridges... of salt domes as well as along the base of salt layers or tongues. The salt within the study area is generally tabular or tongue ? like in nature (as opposed to the predominantlv vertical salt spines and domes found on thc upper slope and shell). Since...

Swiercz, Alan Mark

1986-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "nitrate salt central" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Atmospheric chemistry effects of the 1998 Mexican/Central American fires measured in central New Mexico USA.  

SciTech Connect (OSTI)

Atmospheric effects from large fires have received a great deal of interest recently, especially when the fires have the potential to effect human health when the plumes are transported long distances over areas of high population density. Examples are the recent large fires in Southeast Asia in 1997 (1) and the wildfires occurring in southern Mexico and Central America that were manifested in decreased visibility and high aerosol concentrations in the United States at distances of 2500-4000 km from the fires. In addition to fine aerosols, these biomass fires have the potential to produce and transport large quantities of oxygenated organic species such as aldehydes, ketones and carboxylic acids, hydrocarbons, and sulfate and nitrate species. Most of the literature reports dealing with products of biomass burning have been related to fireplace and wood burning stove emissions (2,3) and with local effects from forest fires(4). The recent super-large fires occurring in Indonesia and Mexico/Central America also bring about the issue of atmospheric reactivity because long-range transport affords long reaction times for photochemical reactions, wet and dry deposition and surface reactions on the aerosol particles. The smoke/haze conditions prompted considerable concern among the general population in New Mexico regarding health hazards and a large number of calls to the Albuquerque, NM Air Quality Division which reported the PM{sub 10} samples collected showed no significant increase in mass(5). The conclusion was that the particles were very fine and therefore had considerable influence on the visibility but did not violate health standards. In this study, organic and inorganic chemical species in the gaseous and aerosol phases have been identified and quantified under non-smoky and smoky conditions in Central New Mexico approximately 3000 km from the source of the fires.

Popp, C. J.

1998-12-16T23:59:59.000Z

362

Heat driven heat pump using paired ammoniated salts  

SciTech Connect (OSTI)

A cycle for a heat driven heat pump using two salts CaCl/sup 2/.8NH/sup 3/, and ZnCl/sup 2/.4NH3 which may reversibly react with ammonia with the addition or evolution of heat. These salts were chosen so that both ammoniation processes occur at the same temperature so that the heat evolved may be used for comfort heating. The heat to drive the system need only be slightly hotter than 122 C. The low temperature source need only be slightly warmer than 0 C.

Dunlap, R.M.

1980-08-29T23:59:59.000Z

363

Geology of the Salt Creek area, Mason County, Texas  

E-Print Network [OSTI]

and to the entrapment of. surface water in the fractures. GEOLXiBPBOLOGY The Salt Creek area in @aeon County, Texas is located on the southwestern flank of the Llano Uplift, a structural dome which has been reduced to a topographic basin by erosional processes.... STSUCT "SALCEOL00Y IIegional Structure The Llano region, which includes the Salt Creek area, is a structural dome which has been reduced to a topographic basin by erosional processes. The dose is roughly elliptical with a maximum diameter...

Harwood, William Eugene

1959-01-01T23:59:59.000Z

364

A mechanical model of early salt dome growth  

E-Print Network [OSTI]

of Department) December 1988 A Mechanical Analysis of Early Salt Dome Growth. (December 1988) Frank Albert Irwin, B. S. , Texas A&M University Chair of Advisory Committee: Dr. Raymond C. Fletcher A two-layer superposition model, the lower layer representing... of the sediments results in growth rates much higher than those observed. Analysis of the case with a diffusivity of 104m2/Ka agrees with all observa- tions. A range of diffusivities which will produce a realistic salt dome model is then determined. The lower...

Irwin, Frank Albert

1988-01-01T23:59:59.000Z

365

Analysis of salt concentrations in the Brazos River Basin, Texas  

E-Print Network [OSTI]

Oct 48 . Nov 51 Oct 48 Nov 51 08080540 NcDcnsld Creek Neer Post 080810DD Selt Fork Srszon River Neer I'escock MMI200 Croton Creek Neer Jsyton 08081500 Salt Croton Creek Near Aspermont 08082000 Salt Fork Srszos Aiver Near Anperamnt 103 4, 619 64..., 988 Nov 49 . Nov df- Oct 81 Sep Sl Sep 79 Sep 84 Nov 49 . Nov 67 . Oct 81 Scp 51 Sep 79 Sep 84 0808605 D 08086100 08086150 08086212 08086260 08086290 08086300 08086500 08087300 08088000 Deep Creek at Horan HiARerd Creek Near...

Ganze, Charles Keith

1990-01-01T23:59:59.000Z

366

Materials and methods for stabilizing nanoparticles in salt solutions  

DOE Patents [OSTI]

Sequence-specific polymers are proving to be a powerful approach to assembly and manipulation of matter on the nanometer scale. Ligands that are peptoids, or sequence-specific N-functional glycine oligomers, allow precise and flexible control over the arrangement of binding groups, steric spacers, charge, and other functionality. We have synthesized short peptoids that can prevent the aggregation of gold nanoparticles in high-salt environments including divalent salt, and allow co-adsorption of a single DNA molecule. This degree of precision and versatility is likely to prove essential in bottom-up assembly of nanostructures and in biomedical applications of nanomaterials.

Robinson, David Bruce; Zuckermann, Ronald; Buffleben, George M.

2013-06-11T23:59:59.000Z

367

Summary of aluminum nitrate tests at the F/H-ETF  

SciTech Connect (OSTI)

Biofouling of the Norton ceramic filters in the F/H Effluent Treatment Facility (ETF) has been minimized by bacterial control strategies on the influent streams. However, enough bacteria still exists in the routine influent to impact the filter performance. One method of remediating biofouling in routine influent, initially observed in laboratory tests on simulant solutions, involves addition of aluminum nitrate to the influent wastewater. Tests on actual feed at the ETF using aluminum nitrate showed significantly improved performance, with increases in filter permeability of up to four-fold compared to the baseline case. These improvements were only realized after modifications to the pH adjustment system were completed which minimized upsets in the pH of the feed solutions.

McCabe, D.J.; Wiggins, A.W.

1992-01-01T23:59:59.000Z

368

Summary of aluminum nitrate tests at the F/H-ETF  

SciTech Connect (OSTI)

Biofouling of the Norton ceramic filters in the F/H Effluent Treatment Facility (ETF) has been minimized by bacterial control strategies on the influent streams. However, enough bacteria still exists in the routine influent to impact the filter performance. One method of remediating biofouling in routine influent, initially observed in laboratory tests on simulant solutions, involves addition of aluminum nitrate to the influent wastewater. Tests on actual feed at the ETF using aluminum nitrate showed significantly improved performance, with increases in filter permeability of up to four-fold compared to the baseline case. These improvements were only realized after modifications to the pH adjustment system were completed which minimized upsets in the pH of the feed solutions.

McCabe, D.J.; Wiggins, A.W.

1992-05-01T23:59:59.000Z

369

University of California Radiation Laboratory Progress Report for November, 1947  

E-Print Network [OSTI]

preparE Since anhydrous uranyl nitrate for use in the studyevacuation of the hydrated uranyl nitrate salts resulted in

Perlman, I.

2010-01-01T23:59:59.000Z

370

Impact of pH on the removal of fluoride, nitrate and boron by nanofiltration/reverse osmosis   

E-Print Network [OSTI]

The objective of this study was to evaluate the impact of pH on boron, fluoride, and nitrate retention by comparing modelled speciation predictions with retention using six different nanofiltration (NF) and reverse osmosis ...

Richards, Laura A.; Vuachère, Marion; Schäfer, Andrea

2010-01-01T23:59:59.000Z

371

Supporting Information for Impact of Chlorine Emissions from Sea-Salt Aerosol on Coastal Urban Ozone  

E-Print Network [OSTI]

DIOXIDE H2O2 HYDROGEN PEROXIDE NH3 AMMONIA NIT AEROSOL NITRATE SO2 SULFUR DIOXIDE SO3 SULFUR TRIOXIDE OSD extensions* NO NITRIC OXIDE NO2 NITROGEN DIOXIDE O3 OZONE HONO NITROUS ACID HNO3 NITRIC ACID HNO4 PERNITRIC ACID N2O5 NITROGEN PENTOXIDE NO3 NITRATE RADICAL HO2 HYDROPEROXY RADICAL CO CARBON MONOXIDE CO2 CARBON

Dabdub, Donald

372

Centralized digital control of accelerators  

SciTech Connect (OSTI)

In contrasting the title of this paper with a second paper to be presented at this conference entitled Distributed Digital Control of Accelerators, a potential reader might be led to believe that this paper will focus on systems whose computing intelligence is centered in one or more computers in a centralized location. Instead, this paper will describe the architectural evolution of SLAC's computer based accelerator control systems with respect to the distribution of their intelligence. However, the use of the word centralized in the title is appropriate because these systems are based on the use of centralized large and computationally powerful processors that are typically supported by networks of smaller distributed processors.

Melen, R.E.

1983-09-01T23:59:59.000Z

373

Model validation and uncertainty analysis -- An example using a nitrate percolation model  

SciTech Connect (OSTI)

Model validation and uncertainty analysis are demonstrated using a model previously developed for estimating nitrate-nitrogen (nitrate) concentrations in percolation water from land application of sewage sludge. The objectives are to demonstrate alternate validation techniques and to analyze uncertainty associated with model use following validation. Field data from three published sludge application studies and two separate methods are used for the validation. The first method, point validation, is accomplished by inserting mean values into the model to make point predictions. Model accuracy is then assessed by calculating coefficient of determination (r{sup 2}), relative error and standard error. Statistical accuracy is tested using the Wilcoxon Signed Rank Test. The second method, statistical validation, uses Monte Carlo simulation to obtain distributions of model predictions. The hypothesis that field data represent reasonable samples from the distribution of model predictions is tested by checking whether observed values are within a range bounded by the 5 and 95% quantities of the distribution. Both validation methods demonstrate that the land application model generally overestimates nitrate concentrations. Monte Carlo simulation is used to identify which model input parameters are the largest contributors to the uncertainty in model predictions.

Mummert, M.C. [R.E. Wright Environmental, Inc., Middletown, PA (United States)

1996-12-31T23:59:59.000Z

374

Effect of Phosphate, Fluoride, and Nitrate on Gibbsite Dissolution Rate and Solubility  

SciTech Connect (OSTI)

Laboratory tests have been completed with simulated tank waste samples to investigate the effects of phosphate, fluoride, and nitrate on the dissolution rate and equilibrium solubility of gibbsite in sodium hydroxide solution at 22 and 40{degrees}C. Results are compared to relevant literature data and to computer model predictions. The presence of sodium nitrate (3 M) caused a reduction in the rate of gibbsite dissolution in NaOH, but a modest increase in the equilibrium solubility of aluminum. The increase in solubility was not as large, though, as the increase predicted by the computer model. The presence of phosphate, either as sodium phosphate or sodium fluoride phosphate, had a negligible effect on the rate of gibbsite dissolution, but caused a slight increase in aluminum solubility. The magnitude of the increased solubility, relative to the increase caused by sodium nitrate, suggests that the increase is due to ionic strength (or water activity) effects, rather than being associated with the specific ion involved. The computer model predicted that phosphate would cause a slight decrease in aluminum solubility, suggesting some Al-PO4 interaction. No evidence was found of such an interaction.

Herting, Daniel L. [Washington River Protection Solutions LLC (United States)

2014-01-29T23:59:59.000Z

375

Aqueous nitrate waste treatment: Technology comparison, cost/benefit, and market analysis  

SciTech Connect (OSTI)

The purpose of this analysis is to provide information necessary for the Department of Energy (DOE) to evaluate the practical utility of the Nitrate to Ammonia and Ceramic or Glass (NAC/NAG/NAX) process, which is under development in the Oak Ridge National Laboratory. The NAC/NACx/NAX process can convert aqueous radioactive nitrate-laden waste to a glass, ceramic, or grout solid waste form. The tasks include, but are not limited to, the following: Identify current commercial technologies to meet hazardous and radiological waste disposal requirements. The technologies may be thermal or non-thermal but must be all inclusive (i.e., must convert a radionuclide-containing nitrate waste with a pH around 12 to a stable form that can be disposed at permitted facilities); evaluate and compare DOE-sponsored vitrification, grouting, and minimum additive waste stabilization projects for life-cycle costs; compare the technologies above with respect to material costs, capital equipment costs, operating costs, and operating efficiencies. For the NAC/NAG/NAX process, assume aluminum reactant is government furnished and ammonia gas may be marketed; compare the identified technologies with respect to frequency of use within DOE for environmental management applications with appropriate rationale for use; Assess the potential size of the DOE market for the NAC/NAG/NAX process; assess and off-gas issues; and compare with international technologies, including life-cycle estimates.

Not Available

1994-01-01T23:59:59.000Z

376

TREATMENT TESTS FOR EX SITU REMOVAL OF CHROMATE & NITRATE & URANIUM (VI) FROM HANFORD (100-HR-3) GROUNDWATER FINAL REPORT  

SciTech Connect (OSTI)

This report describes batch and ion exchange column laboratory scale studies investigating ex situ methods to remove chromate (chromium [VI]), nitrate (NO{sub 3}{sup -}) and uranium (present as uranium [VI]) from contaminated Hanford site groundwaters. The technologies investigated include: chemical precipitation or coprecipitation to remove chromate and uranium; and anion exchange to remove chromate, uranium and nitrate. The technologies investigated were specified in the 100-HR-3 Groundwater Treatability Test Plan. The method suggested for future study is anion exchange.

BECK MA; DUNCAN JB

1994-01-03T23:59:59.000Z

377

The Effect of Time and Rate of Application of Nitrate of Soda on the Yield of Cotton.  

E-Print Network [OSTI]

TEXAS AGRICULTURAL EXPERIHENT STATIDJ A. R. CONNER, DIRECTOR COLLEGE STATION, BRAZOS COUNTY. TEXAS BULLETIN NO. 490 MARCH, 1934 .--' --7 , The Effect of Time and Rate of Application of Nitrate of Soda on the Yield of Cotton - AGRICULTURAL... of nitrate of soda on yield, length and percentage of lint, size of boll, shedding, and other characters of the cotton plant on the sandy soils of eastern Texas, as a basis for developing a more intelligent and profitable fertilizer practice for cotton...

Reynolds, E. B. (Elbert Brunner); Langley, B. C. (Bryon Caldwell); Johnson, P. R. (Paul Rufus)

1934-01-01T23:59:59.000Z

378

Supporting Information for: Salt concentration differences alter membrane  

E-Print Network [OSTI]

). The membrane area available for ion transport was 11.4 cm2 . Platinum mesh electrodes that spanned the crossS1 Supporting Information for: Salt concentration differences alter membrane resistance in reverse-814-867-1847 #12;S2 Membrane resistance measurement Without a concentration difference Membrane resistance

379

Salt Lake City, Utah: Solar in Action (Brochure)  

SciTech Connect (OSTI)

This brochure provides an overview of the challenges and successes of Salt Lake City, UT, a 2007 Solar America City awardee, on the path toward becoming a solar-powered community. Accomplishments, case studies, key lessons learned, and local resource information are given.

Not Available

2011-10-01T23:59:59.000Z

380

ARE DEICING SALTS NECESSARY TO PROMOTE SCALING IN CONCRETE?  

E-Print Network [OSTI]

. Keywords: Concrete, cryosuction, durability, frost, poromechanics, porous media, thermo- dynamics, spallingARE DEICING SALTS NECESSARY TO PROMOTE SCALING IN CONCRETE? A. Fabbri1,2 , O. Coussy1 , T. Fen of the different phases that form the porous material. It eventually predicts that a less perme- able sample

Paris-Sud XI, Université de

Note: This page contains sample records for the topic "nitrate salt central" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

THORIUM FUEL CYCLES: A GRAPHITE-MODERATED MOLTEN SALT REACTOR  

E-Print Network [OSTI]

THORIUM FUEL CYCLES: A GRAPHITE-MODERATED MOLTEN SALT REACTOR VERSUS A FAST SPECTRUM SOLID FUEL is to compare two main options dedicated to long-term energy production with Thorium: solid fuel with fast its be- haviour until it reaches the 232Th/233U equilibrium from two di erent starting fuels: 232Th

Paris-Sud XI, Université de

382

Water, Vapor, and Salt Dynamics in a Hot Repository  

SciTech Connect (OSTI)

The purpose of this paper is to report the results of a new model study examining the high temperature nuclear waste disposal concept at Yucca Mountain using MULTIFLUX, an integrated in-drift- and mountain-scale thermal-hydrologic model. The results show that a large amount of vapor flow into the drift is expected during the period of above-boiling temperatures. This phenomenon makes the emplacement drift a water/moisture attractor during the above-boiling temperature operation. The evaporation of the percolation water into the drift gives rise to salt accumulation in the rock wall, especially in the crown of the drift for about 1500 years in the example. The deposited salts over the drift footprint, almost entirely present in the fractures, may enter the drift either by rock fall or by water drippage. During the high temperature operation mode, the barometric pressure variation creates fluctuating relative humidity in the emplacement drift with a time period of approximately 10 days. Potentially wet and dry conditions and condensation on salt-laden drift wall sections may adversely affect the storage environment. Salt accumulations during the above-boiling temperature operation must be sufficiently addressed to fully understand the waste package environment during the thermal period. Until the questions are resolved, a below-boiling repository design is favored where the Alloy-22 will be less susceptible to localized corrosion. (authors)

Bahrami, Davood; Danko, George [Department of Mining Engineering, University of Nevada, Reno, 1664 N. Virginia St., Reno, NV, 89557 (United States); Walton, John [Department of Civil Engineering, University of Texas at El Paso, 500 W. University, El Paso, TX, 79968 (United States)

2007-07-01T23:59:59.000Z

383

Bile Salts and Nuclear Receptors in Biliary Epithelial Cell Pathophysiology  

E-Print Network [OSTI]

Bile Salts and Nuclear Receptors in Biliary Epithelial Cell Pathophysiology by Dr. Nicolas Chignard shaped the way I perform my work today. Among many other examples, she showed me how to simply performed by students that I had the pleasure to supervise. I'm grateful to all of them. I especially would

Boyer, Edmond

384

Molten salts and nuclear energy production Christian Le Bruna*  

E-Print Network [OSTI]

Molten salts and nuclear energy production Christian Le Bruna* a Laboratoire de Physique or chlorides) have been taken in consideration very soon in nuclear energy production researches, thorium cycle 1. Introduction The main characteristic of nuclear energy production is the large energy

Boyer, Edmond

385

SALT DAMAGE CRITERION PROOF-OF-CONCEPT RESEARCH  

SciTech Connect (OSTI)

This document is the annual technical progress report for Department of Energy Contract No. DE-FC26-00NT41026 entitled Proof-of-Concept Research for an Advanced Design Criterion to Improve Working Gas Capacity for Natural Gas Storage Caverns in Salt Formations. This report covers the reporting period from October 1, 2000, through September 30, 2001. During this reporting period, the project was initiated and work was performed to develop structural models that will be used to evaluate two compressed natural gas storage caverns in the McIntosh Dome northwest of Mobile, Alabama. Information necessary to define the structural models include site-specific stress, temperature, geometry, stratigraphy, and operating scenarios in the dome and for the caverns. Additionally, material model development for the salt at the McIntosh Dome was initiated. Material model development activities include acquisition of salt core for testing, laboratory testing, and regression analyses to determine site-specific model parameter values that describe the behavior of salt around a storage cavern. Although not performed during this reporting period, the information and models developed will be used to perform advanced design storage cavern analyses for the Bay Gas caverns to determine the operating pressure ranges to maintain stable conditions.

Kerry L. DeVries; Kirby D. Mellegard; Gary D. Callahan

2001-12-01T23:59:59.000Z

386

Molten-Salt-Based Growth of Group III Nitrides  

DOE Patents [OSTI]

A method for growing Group III nitride materials using a molten halide salt as a solvent to solubilize the Group-III ions and nitride ions that react to form the Group III nitride material. The concentration of at least one of the nitride ion or Group III cation is determined by electrochemical generation of the ions.

Waldrip, Karen E. (Albuquerque, NM); Tsao, Jeffrey Y. (Albuquerque, NM); Kerley, Thomas M. (Albuquerque, NM)

2008-10-14T23:59:59.000Z

387

Simulation of salt migrations in density dependent groundwater flow  

E-Print Network [OSTI]

and uses a finite element method for the simulation of groundwater flow in the lateral (2D) direction (third dimension) a finite difference method is used in the simula- tions. Numerical experiments are done of this thesis is to investigate the possibilities of modelling salt migrations in density dependent groundwater

Vuik, Kees

388

New Opportunities for Metals Extraction and Waste Treatment by Electrochemical Processing in Molten Salts  

E-Print Network [OSTI]

Molten salt electrolysis is a proven technology for the extraction of metals -- all the world's primary aluminum is produced in this manner. The unique properties of molten salts also make them

Sadoway, Donald R.

2001-01-01T23:59:59.000Z

389

Effects of Nutrient Additions on Three Coastal Salt Marsh Plants Found in Sunset Cove, Texas  

E-Print Network [OSTI]

Eutrophication, particularly due to nitrogen (N) and phosphorus (P) input, has been massively altered by anthropogenic activities. Thus it is important to understand the impact on salt marsh plants; however studies on salt marsh plants within...

Rulon, Leslie

2012-02-14T23:59:59.000Z

390

Corrosion in Very High-Temperature Molten Salt for Next Generation...  

Broader source: Energy.gov (indexed) [DOE]

Corrosion in Very High-Temperature Molten Salt for Next Generation CSP Systems Corrosion in Very High-Temperature Molten Salt for Next Generation CSP Systems This presentation was...

391

E-Print Network 3.0 - air pollution salt Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

salt Search Powered by Explorit Topic List Advanced Search Sample search results for: air pollution salt Page: << < 1 2 3 4 5 > >> 1 Contact: Lori M. Quillen, Director of...

392

Freestall Facilities in Central Texas  

E-Print Network [OSTI]

surveyed recently for infor- L-5311 5-99 Freestall Dairy Facilities in Central Texas Sandy Stokes and Mike Gamroth* *Extension Dairy Specialist, Texas A&M University System, and Extension Dairy Specialist, Oregon State University. Freestall housing...

Stokes, Sandra R.; Gamroth, Mike

1999-06-04T23:59:59.000Z

393

E-Print Network 3.0 - arutlus salt lake Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

IN... Accounting Master's Degree Summary: salary) 11 Employment Information Armstrong, Johnson & Seatsen Accountant Salt Lake City UT Baird... Longyear Accounting...

394

E-Print Network 3.0 - awra salt lake Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

IN... Accounting Master's Degree Summary: salary) 11 Employment Information Armstrong, Johnson & Seatsen Accountant Salt Lake City UT Baird... Longyear Accounting...

395

Synthesis of acid addition salt of delta-aminolevulinic acid from 5-bromo levulinic acid esters  

DOE Patents [OSTI]

A process of preparing an acid addition salt of delta-aminolevulinc acid comprising: a) dissolving a lower alkyl 5-bromolevulinate and hexamethylenetetramine in a solvent selected from the group consisting of water, ethyl acetate, chloroform, acetone, ethanol, tetrahydrofuran and acetonitrile, to form a quaternary ammonium salt of the lower alkyl 5-bromolevulinate; and b) hydrolyzing the quaternary ammonium salt with an inorganic acid to form an acid addition salt of delta-aminolevulinic acid.

Moens, Luc (Lakewood, CO)

2003-06-24T23:59:59.000Z

396

Water Balance, Salt Loading, and Salinity Control Options of Red Bluff Reservoir, Texas  

E-Print Network [OSTI]

objectives: i) to outline water balance of the reservoir, ii) to establish salt loading trends over the past several decades, and iii) to evaluate the impact of salt loading on salinity of the reservoir and its outflow. We also outlined the needs... presumably has less seepage losses. The study reported here was conducted i) for examining the reservoir water balance of Red Bluff over the past several decades, ii) for establishing salt loading trends, and iii) for evaluating the impact of salt...

Miyamoto, S.; Yuan, Fasong; Anand, Shilpa

397

E-Print Network 3.0 - alkali salt deposition Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

formation and salt ... Source: Zachariah, Michael R. - Departments of Chemistry & Mechanical Engineering, University of Minnesota Collection: Chemistry ; Materials Science...

398

E-Print Network 3.0 - acids lead salts Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

-Partial list Chemical Incompatibilities Summary: hypochlorite, all oxidizing agents Carbon tetrachloride Sodium Chlorates Ammonium salts, acids, powdered metals... ammonium...

399

E-Print Network 3.0 - acid ammonium salt Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

-Partial list Chemical Incompatibilities Summary: hypochlorite, all oxidizing agents Carbon tetrachloride Sodium Chlorates Ammonium salts, acids, powdered metals... ammonium...

400

Electrodialysis-based separation process for salt recovery and recycling from waste water  

DOE Patents [OSTI]

A method for recovering salt from a process stream containing organic contaminants is provided, comprising directing the waste stream to a desalting electrodialysis unit so as to create a concentrated and purified salt permeate and an organic contaminants-containing stream, and contacting said concentrated salt permeate to a water-splitting electrodialysis unit so as to convert the salt to its corresponding base and acid. 6 figs.

Tsai, S.P.

1997-07-08T23:59:59.000Z

Note: This page contains sample records for the topic "nitrate salt central" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Electrodialysis-based separation process for salt recovery and recycling from waste water  

DOE Patents [OSTI]

A method for recovering salt from a process stream containing organic contaminants is provided, comprising directing the waste stream to a desalting electrodialysis unit so as to create a concentrated and purified salt permeate and an organic contaminants containing stream, and contacting said concentrated salt permeate to a water-splitting electrodialysis unit so as to convert the salt to its corresponding base and acid.

Tsai, Shih-Perng (Naperville, IL)

1997-01-01T23:59:59.000Z

402

Refueling Liquid-Salt-Cooled Very High-Temperature Reactors  

SciTech Connect (OSTI)

The liquid-salt-cooled very high-temperature reactor (LS-VHTR), also called the Advanced High-Temperature Reactor (AHTR), is a new reactor concept that combines in a novel way four established technologies: (1) coated-particle graphite-matrix nuclear fuels, (2) Brayton power cycles, (3) passive safety systems and plant designs previously developed for liquid-metal-cooled fast reactors, and (4) low-pressure liquid-salt coolants. Depending upon goals, the peak coolant operating temperatures are between 700 and 1000 deg. C, with reactor outputs between 2400 and 4000 MW(t). Several fluoride salt coolants that are being evaluated have melting points between 350 and 500 deg. C, values that imply minimum refueling temperatures between 400 and 550 deg. C. At operating conditions, the liquid salts are transparent and have physical properties similar to those of water. A series of refueling studies have been initiated to (1) confirm the viability of refueling, (2) define methods for safe rapid refueling, and (3) aid the selection of the preferred AHTR design. Three reactor cores with different fuel element designs (prismatic, pebble bed, and pin-type fuel assembly) are being evaluated. Each is a liquid-salt-cooled variant of a graphite-moderated high-temperature reactor. The refueling studies examined applicable refueling experience from high-temperature reactors (similar fuel element designs) and sodium-cooled fast reactors (similar plant design with liquid coolant, high temperatures, and low pressures). The findings indicate that refueling is viable, and several approaches have been identified. The study results are described in this paper. (authors)

Forsberg, Charles W. [Oak Ridge National Laboratory, P.O. Box 2008 Oak Ridge, TN 37831 (United States); Peterson, Per F. [Nuclear Engineering Department, University of California at Berkeley, 6124a Etcheverry Hall, Berkeley, CA 94720 (United States); Cahalan, James E. [Argonne National Laboratory, 9700 S. Cass Avenue, Argonne, IL 60439 (United States); Enneking, Jeffrey A. [Areva NP (United States); Phil MacDonald [Consultant, Cedar Hill, TX (United States)

2006-07-01T23:59:59.000Z

403

CENTRAL PLATEAU REMEDIATION OPTIMIZATION STUDY  

SciTech Connect (OSTI)

THE CENTRAL PLATEAU REMEDIATION OPTIMIZATION STUDY WAS CONDUCTED TO DEVELOP AN OPTIMAL SEQUENCE OF REMEDIATION ACTIVITIES IMPLEMENTING THE CERCLA DECISION ON THE CENTRAL PLATEAU. THE STUDY DEFINES A SEQUENCE OF ACTIVITIES THAT RESULT IN AN EFFECTIVE USE OF RESOURCES FROM A STRATEGIC PERSPECTIVE WHEN CONSIDERING EQUIPMENT PROCUREMENT AND STAGING, WORKFORCE MOBILIZATION/DEMOBILIZATION, WORKFORCE LEVELING, WORKFORCE SKILL-MIX, AND OTHER REMEDIATION/DISPOSITION PROJECT EXECUTION PARAMETERS.

BERGMAN TB; STEFANSKI LD; SEELEY PN; ZINSLI LC; CUSACK LJ

2012-09-19T23:59:59.000Z

404

Density of Gadolinium Nitrate Solutions for the High Flux Isotope Reactor  

SciTech Connect (OSTI)

In late 1992, the High Flux Isotope Reactor (HFIR) was planning to switch the solution contained in the poison injection tank from cadmium nitrate to gadolinium nitrate. The poison injection system is an emergency system used to shut down the reactor by adding a neutron poison to the cooling water. This system must be able to supply a minimum of 69 pounds of gadolinium to the reactor coolant system in order to guarantee that the reactor would become subcritical. A graph of the density of gadolinium nitrate solutions over a concentration range of 5 to 30 wt% and a temperature range of 15 to 40{sup o}C was prepared. Routine density measurements of the solution in the poison injection tank are made by HFIR personnel, and an adaptation of the original graph is used to determine the gadolinium nitrate concentration. In late 2008, HFIR personnel decided that the heat tracing that was present on the piping for the poison injection system could be removed without any danger of freezing the solution; however, the gadolinium nitrate solution might get as cold as 5{sup o}C. This was outside the range of the current density-concentration correlation, so the range needed to be expanded. This report supplies a new density-concentration correlation that covers the extended temperature range. The correlation is given in new units, which greatly simplifies the calculation that is required to determine the pounds of gadolinium in the tank solution. The procedure for calculating the amount of gadolinium in the HFIR poison injection system is as follows: (1) Calculate the usable volume in the system; (2) Measure the density of the solution; (3) Calculate the gadolinium concentration using the following equation: Gd(lb/ft{sup 3}) = measured density (g/mL) x 34.681 - 34.785; (4) Calculate the amount of gadolinium in the system using the following equation: Amount of Gd(lb) = Gd concentration (lb/ft{sup 3}) x usable volume (ft{sup 3}). The equation in step 3 is exact for a temperature of 5{sup o}C, and overestimates the gadolinium concentration at all higher temperatures. This guarantees that the calculation is conservative, in that the actual concentration will be at least as high as that calculated. If an additional safety factor is desired, it is recommended that an administrative control limit be set that is higher than the required minimum amount of gadolinium.

Taylor, Paul Allen [ORNL; Lee, Denise L [ORNL

2009-05-01T23:59:59.000Z

405

A hypothesis concerning the distribution of salt and salt structures in the Gulf of Mexico  

E-Print Network [OSTI]

. oils an. l domes on abyssal plain anil in Bay ot' Cainp che as surveyei. '. by iA'orzel et al. (1968). Inse t is cioss-section A-A' bas d cn. seismic refracton me" sure- ments (Eiving et al. , 1960; Antoine and Ev:ing, 1963) 26 Known and inferred...) shows a re tricted oattern in the central and south!vest. rn parts of the G!!1! of !nf xico. Th= v'ell-defined caste" n and s out( em boundari. s o. th-. kr!oil-and-dome province apparently are associated, w"th th cutline of the Can peche Bank. Th...

Antoine, John Woodworth

1970-01-01T23:59:59.000Z

406

New Central American Cinema (2001-2010)  

E-Print Network [OSTI]

This dissertation explores New Central American Cinema, a film movement that emerged in Central America during the 2000s. It examines feature-length fictional films produced and released in Central America between 2001-2010. ...

Duró n, Hispano

2014-05-31T23:59:59.000Z

407

Universidad Central de Venezuela Facultad de Ciencias  

E-Print Network [OSTI]

Universidad Central de Venezuela Facultad de Ciencias Escuela de Computación Lecturas en Ciencias, Universidad Central de Venezuela, Ap. 47002, Caracas 1041-A, Venezuela (mmonsalv, Universidad Central de Venezuela, Ap. 47002, Caracas 1041-A, Venezuela (mraydan

Raydan, Marcos

408

Bases, Assumptions, and Results of the Flowsheet Calculations for the Decision Phase Salt Disposition Alternatives  

SciTech Connect (OSTI)

The HLW salt waste (salt cake and supernate) now stored at the SRS must be treated to remove insoluble sludge solids and reduce the soluble concentration of radioactive cesium radioactive strontium and transuranic contaminants (principally Pu and Np). These treatments will enable the salt solution to be processed for disposal as saltstone, a solid low-level waste.

Elder, H.H.

2001-07-11T23:59:59.000Z

409

Direct conversion of carboxylate salts to carboxylic acids via reactive extraction  

E-Print Network [OSTI]

the fermentation conversion. In this case, fermentation broth contains ammonium salts (e.g., ammonium acetate, propionate, butyrate, pentanoate). Therefore, the downstream processing steps (including extraction, purification, esterification, and product... separation) must be compatible with the ammonium carboxylate salts formed in the fermentation. This research focuses on converting fermentation broth carboxylate salts into their corresponding acids via “acid springing.” Reactive extraction and thermal...

Xu, Xin

2008-10-10T23:59:59.000Z

410

Sample Results From The Interim Salt Disposition Program Macrobatch 6 Tank 21H Qualification Samples  

SciTech Connect (OSTI)

Savannah River National Laboratory (SRNL) analyzed samples from Tank 21H in support of qualification of Macrobatch (Salt Batch) 6 for the Interim Salt Disposition Project (ISDP). This document reports partial results of the analyses of samples of Tank 21H. No issues with the projected Salt Batch 6 strategy are identified.

Peters, T. B.; Fink, S. D.

2012-12-20T23:59:59.000Z

411

Sample Results from the Interim Salt Disposition Program Macrobatch 6 Tank 21H Qualification Samples  

SciTech Connect (OSTI)

Savannah River National Laboratory (SRNL) analyzed samples from Tank 21H in support of qualification of Macrobatch (Salt Batch) 6 for the Interim Salt Disposition Project (ISDP). This document reports partial results of the analyses of samples of Tank 21H. No issues with the projected Salt Batch 6 strategy are identified.

Peters, T. B.; Fink, S. D.

2012-12-11T23:59:59.000Z

412

THE THORIUM MOLTEN SALT REACTOR: LAUNCHING THE THORIUM CYCLE WHILE CLOSING THE CURRENT  

E-Print Network [OSTI]

THE THORIUM MOLTEN SALT REACTOR: LAUNCHING THE THORIUM CYCLE WHILE CLOSING THE CURRENT FUEL CYCLE E ABSTRACT Molten salt reactors, in the configuration presented here and called Thorium Molten Salt Reactor on a Thorium base, i.e. started in the Th/Pu fuel cycle. We study the transition between the reactors of second

Paris-Sud XI, Université de

413

Insulators for cold urban areas: The problem of Road Salt Ravi Gorur and Sreeram Venkataraman  

E-Print Network [OSTI]

Insulators for cold urban areas: The problem of Road Salt Ravi Gorur and Sreeram Venkataraman of insulators in winter due to road salt. We have started a research project at Arizona State University are more concerned with the effect that the road salts have on insulators, both ceramic and composite

414

Growth and metal uptake of microalgae produced using salt groundwaters from the Bay of Bourgneuf  

E-Print Network [OSTI]

Growth and metal uptake of microalgae produced using salt groundwaters from the Bay of Bourgneuf production of microalgae. Salt groundwaters, available in this region, support a large part of four microalgae grown in two salt groundwaters or in enriched coastal seawater. Cultures of microalgae

Paris-Sud XI, Université de

415

Salt Disposal Investigations to Study Thermally Hot Radioactive Waste In A Deep Geologic Repository in Bedded Rock Salt - 12488  

SciTech Connect (OSTI)

A research program is proposed to investigate the behavior of salt when subjected to thermal loads like those that would be present in a high-level waste repository. This research would build upon results of decades of previous salt repository program efforts in the US and Germany and the successful licensing and operation of a repository in salt for disposal of defense transuranic waste. The proposal includes a combination of laboratory-scale investigations, numerical simulations conducted to develop validated models that could be used for future repository design and safety case development, and a thermal field test in an underground salt formation with a configuration that replicates a small portion of a conceptual repository design. Laboratory tests are proposed to measure salt and brine properties across and beyond the range of possible repository conditions. Coupled numerical models will seek to describe phenomenology (thermal, mechanical, and hydrological) observed in the laboratory tests. Finally, the field test will investigate many phenomena that have been variously cited as potential issues for disposal of thermally hot waste in salt, including buoyancy effects and migration of pre-existing trapped brine up the thermal gradient (including vapor phase migration). These studies are proposed to be coordinated and managed by the Carlsbad Field Office of DOE, which is also responsible for the operation of the Waste Isolation Pilot Plant (WIPP) within the Office of Environmental Management. The field test portion of the proposed research would be conducted in experimental areas of the WIPP underground, far from disposal operations. It is believed that such tests may be accomplished using the existing infrastructure of the WIPP repository at a lower cost than if such research were conducted at a commercial salt mine at another location. The phased field test is proposed to be performed over almost a decade, including instrumentation development, several years of measurements during heating and then subsequent cooling periods, and the eventual forensic mining back of the test bed to determine the multi-year behavior of the simulated waste/rock environment. Funding possibilities are described, and prospects for near term start-up are discussed. Mining of the access drifts required to create the test area in the WIPP underground began in November 2011. Because this mining uses existing WIPP infrastructure and labor, it is estimated to take about two years to complete the access drifts. WIPP disposal operations and facility maintenance activities will take priority over the SDI field test area mining. Funding of the SDI proposal was still being considered by DOE's Offices of Environmental Management and Nuclear Energy at the time this paper was written, so no specific estimates of the progress in 2012 have been included. (authors)

Nelson, Roger A. [DOE, Carlsbad Field Office, Carlsbad NM (United States); Buschman, Nancy [DOE, Office of Environmental Management, Washington DC (United States)

2012-07-01T23:59:59.000Z

416

Process for the preparation of protected dihydroxypropyl trialkylammonium salts and derivatives thereof  

DOE Patents [OSTI]

A process for the preparation of protected dihydroxypropyl trialkylammonium salts, particularly in chiral form is described. In particular, a process for the preparation of (2,2-dimethyl-1,3-dioxolan-4-ylmethyl)trialkylammonium salts, particularly in chiral form is described. Furthermore, a process is described wherein the (2,2-dimethyl-1,3-dioxolan-4ylmethyl)trialkylammonium salts is a 2,2-dimethyl-1,3-dioxolan-4-ylmethyl trimethylammonium salt, preferably in chiral form. The protected dihydroxypropyl trialkylammonium salts lead to L-carnitine (9) when in chiral form (5).

Hollingsworth, Rawle I. (Haslett, MI); Wang, Guijun (East Lansing, MI)

2000-01-01T23:59:59.000Z

417

Nuclear Hybrid Energy Systems: Molten Salt Energy Storage  

SciTech Connect (OSTI)

With growing concerns in the production of reliable energy sources, the next generation in reliable power generation, hybrid energy systems, are being developed to stabilize these growing energy needs. The hybrid energy system incorporates multiple inputs and multiple outputs. The vitality and efficiency of these systems resides in the energy storage application. Energy storage is necessary for grid stabilizing and storing the overproduction of energy to meet peak demands of energy at the time of need. With high thermal energy production of the primary nuclear heat generation source, molten salt energy storage is an intriguing option because of its distinct properties. This paper will discuss the different energy storage options with the criteria for efficient energy storage set forth, and will primarily focus on different molten salt energy storage system options through a thermodynamic analysis

P. Sabharwall; M. Green; S.J. Yoon; S.M. Bragg-Sitton; C. Stoots

2014-07-01T23:59:59.000Z

418

Cooling molten salt reactors using “gas-lift”  

SciTech Connect (OSTI)

This study briefly describes the selection of a type of two-phase flow, suitable for intensifying the natural flow of nuclear reactors with liquid fuel - cooling mixture molten salts and the description of a “Two-phase flow demonstrator” (TFD) used for experimental study of the “gas-lift” system and its influence on the support of natural convection. The measuring device and the application of the TDF device is described. The work serves as a model system for “gas-lift” (replacing the classic pump in the primary circuit) for high temperature MSR planned for hydrogen production. An experimental facility was proposed on the basis of which is currently being built an experimental loop containing the generator, separator bubbles and necessary accessories. This loop will model the removal of gaseous fission products and tritium. The cleaning of the fuel mixture of fluoride salts eliminates problems from Xenon poisoning in classical reactors.

Zitek, Pavel, E-mail: zitek@kke.zcu.cz, E-mail: klimko@kke.zcu.cz; Valenta, Vaclav, E-mail: zitek@kke.zcu.cz, E-mail: klimko@kke.zcu.cz; Klimko, Marek, E-mail: zitek@kke.zcu.cz, E-mail: klimko@kke.zcu.cz [University of West Bohemia in Pilsen, Univerzitní 8, 306 14 Pilsen (Czech Republic)

2014-08-06T23:59:59.000Z

419

Fluoride Salt-Cooled High-Temperature Reactor Development Roadmap  

SciTech Connect (OSTI)

Fluoride salt-cooled high-temperature reactors (FHRs) are an emerging reactor class with potentially advantageous performance characteristics and fully passive safety. This paper provides an overview of a technology development pathway for expeditious commercial deployment of first-generation FHRs. The paper describes the principal remaining FHR technology challenges and the development path needed to address the challenges. First-generation FHRs do not appear to require any technology breakthroughs, but will require significant technology development and demonstration. FHRs are currently entering early phase engineering development. As such, the development roadmap is not as technically detailed or specific as would be the case for a more mature reactor class. The higher cost of fuel and coolant; the lack of an approved licensing framework; the lack of qualified, salt-compatible structural materials; and the potential for tritium release into the environment are the most obvious issues that remain to be resolved.

Holcomb, David Eugene [ORNL] [ORNL; Flanagan, George F [ORNL] [ORNL; Mays, Gary T [ORNL] [ORNL; Pointer, William David [ORNL] [ORNL; Robb, Kevin R [ORNL] [ORNL; Yoder Jr, Graydon L [ORNL] [ORNL

2014-01-01T23:59:59.000Z

420

STAINLESS STEEL INTERACTIONS WITH SALT CONTAINING PLUTONIUM OXIDES  

SciTech Connect (OSTI)

Salt containing plutonium oxide materials are treated, packaged and stored within nested, stainless steel containers based on requirements established in the DOE 3013 Standard. The moisture limit for the stored materials is less than 0.5 weight %. Surveillance activities which are conducted to assess the condition of the containers and assure continuing 3013 container integrity include the destructive examination of a select number of containers to determine whether corrosion attack has occurred as a result of stainless steel interactions with salt containing plutonium oxides. To date, some corrosion has been observed on the innermost containers, however, no corrosion has been noted on the outer containers and the integrity of the 3013 container systems is not expected to be compromised over a 50 year storage lifetime.

Nelson, Z.; Chandler, G.; Dunn, K.; Stefek, T.; Summer, M.

2010-02-01T23:59:59.000Z

Note: This page contains sample records for the topic "nitrate salt central" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Dam constructions as sealing systems in rock salt  

SciTech Connect (OSTI)

Dam constructions represent an essential component of the multibarrier safety concept in the Federal Republic of Germany for a repository of radioactive waste in salt formations. They enhance safety during the operational phase as well as in the post operational phase of the repository. In the framework of a joint R and D-project between BGR, DBE and GSF the components of a suitable dam have been developed and will be constructed and tested in the GSF-Asse salt mine in Lower-Saxony. The aims of the investigation program, its realization and some results on the development of construction materials will be presented and discussed. Experiences gained during these tests in laboratory and in situ will be described.

Engelmann, H.J.; Bollingerfehr, W.; Fischer, H. [Deutsche Gesellschaft zum Bau und Betrieb von Endlagern fuer Abfallstoffe mbH, Peine (Germany)

1993-12-31T23:59:59.000Z

422

Effect of pore pressure on damage accumulation in salt  

SciTech Connect (OSTI)

Laboratory data acquired from two multistage, triaxial compression creep experiments are presented for bedded salt. The experiments were conducted to study the effect of pore pressure changes on the accumulation of damage (dilatant volumetric strain). The first experiment comprised five constant total stress tests in which the internal pore pressure was incremented during successive stages, while the externally applied axial and radial stresses were maintained constant. The second experiment comprised three constant effective stress tests in which the pore pressure and the externally applied axial and radial stresses were increased in equal increments in successive stages. Volumetric strain rates were determined both before and after the pore pressure changes were made in all tests. The data suggest pore pressure changes made during the constant total stress tests have a greater effect on salt dilation than do changes made during the constant effective stress tests.

PFEIFLE,T.W.; HURTADO,L. DIANE

2000-06-12T23:59:59.000Z

423

Sensitivity of storage field performance to geologic and cavern design parameters in salt domes.  

SciTech Connect (OSTI)

A sensitivity study was performed utilizing a three dimensional finite element model to assess allowable cavern field sizes in strategic petroleum reserve salt domes. A potential exists for tensile fracturing and dilatancy damage to salt that can compromise the integrity of a cavern field in situations where high extraction ratios exist. The effects of salt creep rate, depth of salt dome top, dome size, caprock thickness, elastic moduli of caprock and surrounding rock, lateral stress ratio of surrounding rock, cavern size, depth of cavern, and number of caverns are examined numerically. As a result, a correlation table between the parameters and the impact on the performance of a storage field was established. In general, slower salt creep rates, deeper depth of salt dome top, larger elastic moduli of caprock and surrounding rock, and a smaller radius of cavern are better for structural performance of the salt dome.

Ehgartner, Brian L.; Park, Byoung Yoon; Herrick, Courtney Grant

2010-06-01T23:59:59.000Z

424

Sensitivity of storage field performance to geologic and cavern design parameters in salt domes.  

SciTech Connect (OSTI)

A sensitivity study was performed utilizing a three dimensional finite element model to assess allowable cavern field sizes for strategic petroleum reserve salt domes. A potential exists for tensile fracturing and dilatancy damage to salt that can compromise the integrity of a cavern field in situations where high extraction ratios exist. The effects of salt creep rate, depth of salt dome top, dome size, caprock thickness, elastic moduli of caprock and surrounding rock, lateral stress ratio of surrounding rock, cavern size, depth of cavern, and number of caverns are examined numerically. As a result, a correlation table between the parameters and the impact on the performance of storage field was established. In general, slower salt creep rates, deeper depth of salt dome top, larger elastic moduli of caprock and surrounding rock, and a smaller radius of cavern are better for structural performance of the salt dome.

Ehgartner, Brian L. (Sandia National Laboratories, Albuquerque, NM); Park, Byoung Yoon

2009-03-01T23:59:59.000Z

425

Evaluation of potential crushed-salt constitutive models  

SciTech Connect (OSTI)

Constitutive models describing the deformation of crushed salt are presented in this report. Ten constitutive models with potential to describe the phenomenological and micromechanical processes for crushed salt were selected from a literature search. Three of these ten constitutive models, termed Sjaardema-Krieg, Zeuch, and Spiers models, were adopted as candidate constitutive models. The candidate constitutive models were generalized in a consistent manner to three-dimensional states of stress and modified to include the effects of temperature, grain size, and moisture content. A database including hydrostatic consolidation and shear consolidation tests conducted on Waste Isolation Pilot Plant and southeastern New Mexico salt was used to determine material parameters for the candidate constitutive models. Nonlinear least-squares model fitting to data from the hydrostatic consolidation tests, the shear consolidation tests, and a combination of the shear and hydrostatic tests produces three sets of material parameter values for the candidate models. The change in material parameter values from test group to test group indicates the empirical nature of the models. To evaluate the predictive capability of the candidate models, each parameter value set was used to predict each of the tests in the database. Based on the fitting statistics and the ability of the models to predict the test data, the Spiers model appeared to perform slightly better than the other two candidate models. The work reported here is a first-of-its kind evaluation of constitutive models for reconsolidation of crushed salt. Questions remain to be answered. Deficiencies in models and databases are identified and recommendations for future work are made. 85 refs.

Callahan, G.D.; Loken, M.C.; Sambeek, L.L. Van; Chen, R.; Pfeifle, T.W.; Nieland, J.D. [RE/SPEC Inc., Rapid City, SD (United States); Hansen, F.D. [Sandia National Labs., Albuquerque, NM (United States). Repository Isolation Systems Dept.

1995-12-01T23:59:59.000Z

426

Preliminary siting characterization Salt Disposition Facility - Site B  

SciTech Connect (OSTI)

A siting and reconnaissance geotechnical program has been completed in S-Area at the Savannah River Site in South Carolina. This program investigated the subsurface conditions for the area known as ``Salt Disposition Facility (SDF), Site B'' located northeast of H-Area and within the S-Area. Data acquired from the Site B investigation includes both field exploration and laboratory test data.

Wyatt, D.

2000-01-04T23:59:59.000Z

427

Generic effluent monitoring system certification for salt well portable exhauster  

SciTech Connect (OSTI)

Tests were conducted to verify that the Generic Effluent Monitoring System (GEMS), as it is applied to the Salt Well Portable Exhauster, meets all applicable regulatory performance criteria for air sampling systems at nuclear facilities. These performance criteria address both the suitability of the air sampling probe location and the transport of the sample to the collection devices. The criteria covering air sampling probe location ensure that the contaminants in the stack are well mixed with the airflow at the probe location such that the extracted sample represents the whole. The sample transport criteria ensure that the sampled contaminants are quantitatively delivered to the collection device. The specific performance criteria are described in detail in the report. The tests demonstrated that the GEMS/Salt Well Exhauster system meets all applicable performance criteria. Pacific Northwest National Laboratory conducted the testing using a mockup of the Salt Well Portable Exhauster stack at the Numatec Hanford Company`s 305 Building. The stack/sampling system configuration tested was designed to provide airborne effluent control for the Salt Well pumping operation at some U.S. Department of Energy (DOE) radioactive waste storage tanks at the Hanford Site, Washington. The portable design of the exhauster allows it to be used in other applications and over a range of exhaust air flowrates (approximately 200 - 1100 cubic feet per minute). The unit includes a stack section containing the sampling probe and another stack section containing the airflow, temperature and humidity sensors. The GEMS design features a probe with a single shrouded sampling nozzle, a sample delivery line, and sample collection system. The collection system includes a filter holder to collect the sample of record and an in-line detector head and filter for monitoring beta radiation-emitting particles.

Glissmeyer, J.A.; Maughan, A.D.

1997-09-01T23:59:59.000Z

428

Process Heat Exchanger Options for Fluoride Salt High Temperature Reactor  

SciTech Connect (OSTI)

The work reported herein is a significant intermediate step in reaching the final goal of commercial-scale deployment and usage of molten salt as the heat transport medium for process heat applications. The primary purpose of this study is to aid in the development and selection of the required heat exchanger for power production and process heat application, which would support large-scale deployment.

Piyush Sabharwall; Eung Soo Kim; Michael McKellar; Nolan Anderson

2011-04-01T23:59:59.000Z

429

Safe handling of TBP and nitrates in the nuclear process industry  

SciTech Connect (OSTI)

A laboratory and literature study was made of the reactions of tri-n-butyl phosphate (TBP) with nitric acid and nitrates. Its goal was to establish safe conditions for solvent extraction processes involving these chemicals. The damaging explosions at the Tomsk-7 PUREX plant in Russia graphically illustrated the potential hazard involved in such operations. The study has involved a review of prior and contemporary experiments, and new experiments to answer particular questions about these reactions. TBP extracts nitric acid and some metal nitrates from aqueous solutions. The resulting liquid contains both oxidant and reductant, and can react exothermically if heated sufficiently. Safe handling of these potentially reactive materials involves not only limiting the heat generated by the chemical reaction, but also providing adequate heat removal and venting. Specifically, the following recommendations are made to ensure safety: (1) tanks in which TBP-nitrate complexes are or may be present should be adequately vented to avoid pressurization. Data are supplied as a basis for adequacy; (2) chemically degraded TBP, or TBP that has sat a long time in the presence of acids or radiation, should be purified before use in solvent extraction; (3) evaporators in which TBP might be introduced should be operated at a controlled temperature, and their TBP content should be limited; (4) evaporator bottoms that may contain TBP should be cooled under conditions that ensure heat removal. Finally, process design should consider the potential for such reactions, and operators should be made aware of this potential, so that it is considered during training and process operation.

Hyder, M.L.

1994-07-01T23:59:59.000Z

430

Instrument Development and Measurements of the Atmospheric Pollutants Sulfur Dioxide, Nitrate Radical, and Nitrous Acid by Cavity Ring-down Spectroscopy and Cavity Enhanced Absorption Spectroscopy  

E-Print Network [OSTI]

A. , A method of nitrogen dioxide and sulphur dioxidedetermination of nitrogen dioxide and sulfur dioxide in theDOAS) have measured nitrogen dioxide (NO 2 ), nitrate

Medina, David Salvador

2011-01-01T23:59:59.000Z

431

Standard test method for isotopic abundance analysis of uranium hexa?uoride and uranyl nitrate solutions by multi-collector, inductively coupled plasma-mass spectrometry  

E-Print Network [OSTI]

Standard test method for isotopic abundance analysis of uranium hexa?uoride and uranyl nitrate solutions by multi-collector, inductively coupled plasma-mass spectrometry

American Society for Testing and Materials. Philadelphia

2008-01-01T23:59:59.000Z

432

Central Ferry-Lower Monumental  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc DocumentationP-Series to User Group and User ExecutiveCentral Activator Keeps theCentral Ferry

433

Central Facility Benefits from Improvements  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation Proposed New Substation SitesStanding Friedel Waves,TheoryParliament' |CentralCentral Air2

434

Membrane Treatment of Liquid Salt Bearing Radioactive Wastes  

SciTech Connect (OSTI)

The main fields of introduction and application of membrane methods for preliminary treatment and processing salt liquid radioactive waste (SLRW) can be nuclear power stations (NPP) and enterprises on atomic submarines (AS) utilization. Unlike the earlier developed technology for the liquid salt bearing radioactive waste decontamination and concentrating this report presents the new enhanced membrane technology for the liquid salt bearing radioactive waste processing based on the state-of-the-art membrane unit design, namely, the filtering units equipped with the metal-ceramic membranes of ''TruMem'' brand, as well as the electrodialysis and electroosmosis concentrators. Application of the above mentioned units in conjunction with the pulse pole changer will allow the marked increase of the radioactive waste concentrating factor and the significant reduction of the waste volume intended for conversion into monolith and disposal. Besides, the application of the electrodialysis units loaded with an ion exchange material at the end polishing stage of the radioactive waste decontamination process will allow the reagent-free radioactive waste treatment that meets the standards set for the release of the decontaminated liquid radioactive waste effluents into the natural reservoirs of fish-farming value.

Dmitriev, S. A.; Adamovich, D. V.; Demkin, V. I.; Timofeev, E. M.

2003-02-25T23:59:59.000Z

435

Transpiring wall supercritical water oxidation reactor salt deposition studies  

SciTech Connect (OSTI)

Sandia National Laboratories has teamed with Foster Wheeler Development Corp. and GenCorp, Aerojet to develop and evaluate a new supercritical water oxidation reactor design using a transpiring wall liner. In the design, pure water is injected through small pores in the liner wall to form a protective boundary layer that inhibits salt deposition and corrosion, effects that interfere with system performance. The concept was tested at Sandia on a laboratory-scale transpiring wall reactor that is a 1/4 scale model of a prototype plant being designed for the Army to destroy colored smoke and dye at Pine Bluff Arsenal in Arkansas. During the tests, a single-phase pressurized solution of sodium sulfate (Na{sub 2}SO{sub 4}) was heated to supercritical conditions, causing the salt to precipitate out as a fine solid. On-line diagnostics and post-test observation allowed us to characterize reactor performance at different flow and temperature conditions. Tests with and without the protective boundary layer demonstrated that wall transpiration provides significant protection against salt deposition. Confirmation tests were run with one of the dyes that will be processed in the Pine Bluff facility. The experimental techniques, results, and conclusions are discussed.

Haroldsen, B.L.; Mills, B.E.; Ariizumi, D.Y.; Brown, B.G. [and others

1996-09-01T23:59:59.000Z

436

Factors affecting total alkaloid and nitrate levels in pearl millet (Pennisetum americanum (L.) Leeke)  

E-Print Network [OSTI]

('gM University Co-Chairmen of Advisory Committee: Dr. Ethan C. Holt Dr. F. M. Roulette, Jr. P l 'lit (P ' t ' (L. )L k)g 'gt d drought stress in the summer of 1978 in East Texas became unpalat- able to grazing cattle. The unpalatable forage contained... as much as 460 ppm total alkaloid and. potentially toxic levels of nitrate (NO ). Several factors which may play a role in the accumula. tion of alkaloids and NO in pearl millet were investigated in these studies. The effect of drought stress, nitrogen...

Krejsa, Beverly Blohowiak

1981-01-01T23:59:59.000Z

437

In-Situ Silver Acetylide Silver Nitrate Explosive Deposition Measurements Using X-Ray Fluorescence.  

SciTech Connect (OSTI)

The Light Initiated High Explosive facility utilized a spray deposited coating of silver acetylide - silver nitrate explosive to impart a mechanical shock into targets of interest. A diagnostic was required to measure the explosive deposition in - situ. An X - ray fluorescence spectrometer was deployed at the facility. A measurement methodology was developed to measure the explosive quantity with sufficient accuracy. Through the use of a tin reference material under the silver based explosive, a field calibration relationship has been developed with a standard deviation of 3.2 % . The effect of the inserted tin material into the experiment configuration has been explored.

Covert, Timothy T.

2014-09-01T23:59:59.000Z

438

Using the central VAX cluster at ANL  

SciTech Connect (OSTI)

This report is a manual that discusses the following topics on the Central Vax Cluster at ANL: What the Central Vax Cluster is; how the Vax Cluster works; operational policies; getting started; using tapes; printing on the Vax Cluster; developing programs in VMS; using the X window system on the Central Vax Cluster; and using Central Vax Cluster file sharing services.

Caruthers, C.M.; Vote, S.L. [eds.; Lifka, D.A.; Raffenetti, R.C.

1992-08-01T23:59:59.000Z

439

Standard test method for isotopic analysis of hydrolyzed uranium hexafluoride and uranyl nitrate solutions by thermal ionization mass spectrometry  

E-Print Network [OSTI]

1.1 This method applies to the determination of isotopic composition in hydrolyzed nuclear grade uranium hexafluoride. It covers isotopic abundance of 235U between 0.1 and 5.0 % mass fraction, abundance of 234U between 0.0055 and 0.05 % mass fraction, and abundance of 236U between 0.0003 and 0.5 % mass fraction. This test method may be applicable to other isotopic abundance providing that corresponding standards are available. 1.2 This test method can apply to uranyl nitrate solutions. This can be achieved either by transforming the uranyl nitrate solution to a uranyl fluoride solution prior to the deposition on the filaments or directly by depositing the uranyl nitrate solution on the filaments. In the latter case, a calibration with uranyl nitrate standards must be performed. 1.3 This test method can also apply to other nuclear grade matrices (for example, uranium oxides) by providing a chemical transformation to uranyl fluoride or uranyl nitrate solution. 1.4 This standard does not purport to address al...

American Society for Testing and Materials. Philadelphia

2005-01-01T23:59:59.000Z

440

Diffusion Welding of Alloys for Molten Salt Service - Status Report  

SciTech Connect (OSTI)

The present work is concerned with heat exchanger development for molten salt service, including the proposed molten salt reactor (MSR), a homogeneous reactor in which the fuel is dissolved in a circulating fluid of molten salt. It is an outgrowth of recent work done under the Next Generation Nuclear Plant (NGNP) program; what the two reactor systems have in common is an inherently safe nuclear plant with a high outlet temperature that is useful for process heat as well as more conventional generation The NGNP program was tasked with investigating the application of a new generation of nuclear power plants to a variety of energy needs. One baseline reactor design for this program is a high temperature, gas-cooled reactor (HTGR), which provides many options for energy use. These might include the conventional Rankine cycle (steam turbine) generation of electricity, but also other methods: for example, Brayton cycle (gas turbine) electrical generation, and the direct use of the high temperatures characteristic of HTGR output for process heat in the chemical industry. Such process heat is currently generated by burning fossil fuels, and is a major contributor to the carbon footprint of the chemical and petrochemical industries. The HTGR, based on graphite fuel elements, can produce very high output temperatures; ideally, temperatures of 900 C or even greater, which has significant energy advantages. Such temperatures are, of course, at the frontiers of materials limitations, at the upper end of the performance envelope of the metallic materials for which robust construction codes exist, and within the realm of ceramic materials, the fabrication and joining of which, on the scale of large energy systems, are at an earlier stage of development. A considerable amount of work was done in the diffusion welding of materials of interest for HTGR service with alloys such as 617 and 800H. The MSR output temperature is also materials limited, and is projected at about 700 C. (RR E) A different set of alloys, such as Alloy N and 242, are needed to handle molten salts at this temperature. The diffusion welding development work described here builds on techniques developed during the NGNP work, as applied to these alloys. There is also the matter of dissimilar metal welding, since alloys suitable for salt service are generally not suited for service in gaseous oxidizing environments, and vice versa, and welding is required for the Class I boundaries in these systems, as identified in the relevant ASME codes.

Denis Clark; Ronald Mizia

2012-05-01T23:59:59.000Z

Note: This page contains sample records for the topic "nitrate salt central" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Diffusion Welding of Alloys for Molten Salt Service - Status Report  

SciTech Connect (OSTI)

The present work is concerned with heat exchanger development for molten salt service, including the proposed molten salt reactor (MSR), a homogeneous reactor in which the fuel is dissolved in a circulating fluid of molten salt. It is an outgrowth of recent work done under the Next Generation Nuclear Plant (NGNP) program; what the two reactor systems have in common is an inherently safe nuclear plant with a high outlet temperature that is useful for process heat as well as more conventional generation The NGNP program was tasked with investigating the application of a new generation of nuclear power plants to a variety of energy needs. One baseline reactor design for this program is a high temperature, gas-cooled reactor (HTGR), which provides many options for energy use. These might include the conventional Rankine cycle (steam turbine) generation of electricity, but also other methods: for example, Brayton cycle (gas turbine) electrical generation, and the direct use of the high temperatures characteristic of HTGR output for process heat in the chemical industry. Such process heat is currently generated by burning fossil fuels, and is a major contributor to the carbon footprint of the chemical and petrochemical industries. The HTGR, based on graphite fuel elements, can produce very high output temperatures; ideally, temperatures of 900 °C or even greater, which has significant energy advantages. Such temperatures are, of course, at the frontiers of materials limitations, at the upper end of the performance envelope of the metallic materials for which robust construction codes exist, and within the realm of ceramic materials, the fabrication and joining of which, on the scale of large energy systems, are at an earlier stage of development. A considerable amount of work was done in the diffusion welding of materials of interest for HTGR service with alloys such as 617 and 800H. The MSR output temperature is also materials limited, and is projected at about 700 °C. (RR E) A different set of alloys, such as Alloy N and 242, are needed to handle molten salts at this temperature. The diffusion welding development work described here builds on techniques developed during the NGNP work, as applied to these alloys. There is also the matter of dissimilar metal welding, since alloys suitable for salt service are generally not suited for service in gaseous oxidizing environments, and vice versa, and welding is required for the Class I boundaries in these systems, as identified in the relevant ASME codes.

Denis Clark; Ronald Mizia; Piyush Sabharwall

2012-09-01T23:59:59.000Z

442

High-gravity central stars  

E-Print Network [OSTI]

NLTE spectral analyses of high-gravity central stars by means of state-of-the-art model atmosphere techniques provide information about the precursor AGB stars. The hydrogen-deficient post-AGB stars allow investigations on the intershell matter which is apparently exhibited at the stellar surface. We summarize recent results from imaging, spectroscopy, and spectropolarimetry.

Thomas Rauch

2006-07-11T23:59:59.000Z

443

LITERATURE SURVEY FOR GROUNDWATER TREATMENT OPTIONS FOR NITRATE IODINE-129 AND URANIUM 200-ZP-1 OPERABLE UNIT HANFORD SITE  

SciTech Connect (OSTI)

This literature review presents treatment options for nitrate, iodine-129, and uranium, which are present in groundwater at the 200-ZP-I Groundwater Operable Unit (OU) within the 200 West Area of the Hanford Site. The objective of this review is to determine available methods to treat or sequester these contaminants in place (i.e., in situ) or to pump-and-treat the groundwater aboveground (i.e., ex situ). This review has been conducted with emphasis on commercially available or field-tested technologies, but theoretical studies have, in some cases, been considered when no published field data exist. The initial scope of this literature review included only nitrate and iodine-I 29, but it was later expanded to include uranium. The focus of the literature review was weighted toward researching methods for treatment of nitrate and iodine-129 over uranium because of the relatively greater impact of those compounds identified at the 200-ZP-I OU.

BYRNES ME

2008-06-05T23:59:59.000Z

444

Uranyl nitrate pouring solution for producing nuclear fuel particles and a method for its preparation  

SciTech Connect (OSTI)

Sorbitol, or another polyalcohol such as erythritol, dulcitol or xylitol, is added to a solution containing uranyl nitrate which may also contain another heavy metal, such as thorium or plutonium, prior to preneutralization with ammonia in order to provide a highly viscous solution that can be preneutralized to a great extent without premature precipitation of uranium. The high viscosity makes possible the formation of favorably large drops when the solution is dripped into an ammonia containing bath for external gelification of the drops. According to the pouring apparatus used, the particles after washing, drying and sintering have a diameter between 0.6 and 1.5 mm. The polyalcohol is added to a hydrosol containing from 1.5 to 2 moles per liter of heavy metal, the polyalcohol being added until concentration of onethird mole of polyalcohol per mole of heavy metal is reached. In certain cases up to four moles of ammonium nitrate per liter are added. The solution so produced can be preneutralized with up to 90% of the amount of ammonia stoichiometrically necessary for T separation of uranium without the formation of any precipitate, preferably by first adding ammonia gas under strong stirring and then adding ammonium bicarbonate in excess, which decomposes to liberate ammonia to an extent determined by the temperature, which is to be precisely controlled. It is possible to obtain this way a solution of predetermined viscosity from which the excess ammonium bicarbonate can readily be separated.

Hein, K.

1983-05-24T23:59:59.000Z

445

The Self-Ignition Temperatures of Bitumen Mixtures Containing Transition Metal Nitrates  

SciTech Connect (OSTI)

Information is provided on the self-ignition temperature (SIT) of blown bitumen asphalt mixed with sodium nitrate and some chemicals that are added in the bituminization process to adjust pH and to immobilize the radioactive isotopes of Cs, Sr, and I. In each ignition temperature test, the prepared bitumen sample was heated at a constant rate of temperature increase, and the ignition point was measured. Among the tested chemicals added to the bitumen, Ni(NO{sub 3}){sub 2} shows a relatively large SIT decrease, and furthermore, the mixture of Ni(NO{sub 3}){sub 2} and AgNO{sub 3} has been shown to greatly lower the SIT of blown bitumen. It is suggested that, in general, segregation of these nitrates should be avoided in bituminization, and care should be taken in handling Ag in a Purex reprocessing plant from the viewpoint of waste treatment. Furthermore, the oxidation effects of Fe(NO{sub 3}){sub 3} were tested by measuring torque of the bitumen sample. It was confirmed that the addition of Fe(NO{sub 3}){sub 3} to bitumen rapidly oxidizes the bitumen and increases the viscosity of the bitumen mixture.

Okada, Ken; Nomura, Masao; Fujii, Yasuhiko [Tokyo Institute of Technology (Japan)

2000-01-15T23:59:59.000Z

446

Growth faults and salt tectonics in Houston diapir province: relative timing and exploration significance  

SciTech Connect (OSTI)

Oil and gas accumulation in Gulf Coast Tertiary strata is contolled mainly by regional growth faults and by salt-related structures. Salt forms the most prominent set of structures in the Houston diapir province of southeast Texas. Recent work in three study areas shows that the Tertiary growth-fault trends, so well displayed along strike to the south-west, continue through this salt basin as well, but they have been deformed by later salt movement. In the Katy area, seismic data disclose early (pre-Wilcox) salt pillows downdip of the Cretaceous reef trend. Salt stocks were injected upward from the pillows during Clayborne deposition, and were flanked by deep withdrawal basins and turtle structures. In Brazoria County, a major lower Frio growth-fault trend affecting the Houston delta system, was deformed by later salt domes, by a salt-withdrawal basin, and by a possible turtle structure at Chocolate Bayou. A productive geopressured aquifer exists in the salt-withdrawal basin bounded by the previously formed growth faults. In Jefferson County, in contrast, salt-tectonic activity and growth faulting appear to have been coeval. Early salt-cored ridges continued to rise throughout Frio deposition; growth faults occur both updip and downdip. Hydrocarbons accumulated over the salt domes in growth-fault anticlines and in stratigraphic traps. Recognition that shelf-margin growth faulting preceded the development of the present pattern of domes and basins has important implications for hydrocarbon exploration. Growth faults may be migration paths for hydrocarbons; furthermore, early formed traps, distorted by salt movement, may still be found to contain hydrocarbons.

Ewing, T.E.

1983-09-01T23:59:59.000Z

447

Large-scale dynamic compaction demonstration using WIPP salt: Fielding and preliminary results  

SciTech Connect (OSTI)

Reconsolidation of crushed rock salt is a phenomenon of great interest to programs studying isolation of hazardous materials in natural salt geologic settings. Of particular interest is the potential for disaggregated salt to be restored to nearly an impermeable state. For example, reconsolidated crushed salt is proposed as a major shaft seal component for the Waste Isolation Pilot Plant (WIPP) Project. The concept for a permanent shaft seal component of the WIPP repository is to densely compact crushed salt in the four shafts; an effective seal will then be developed as the surrounding salt creeps into the shafts, further consolidating the crushed salt. Fundamental information on placement density and permeability is required to ensure attainment of the design function. The work reported here is the first large-scale compaction demonstration to provide information on initial salt properties applicable to design, construction, and performance expectations. The shaft seals must function for 10,000 years. Over this period a crushed salt mass will become less permeable as it is compressed by creep closure of salt surrounding the shaft. These facts preclude the possibility of conducting a full-scale, real-time field test. Because permanent seals taking advantage of salt reconsolidation have never been constructed, performance measurements have not been made on an appropriately large scale. An understanding of potential construction methods, achievable initial density and permeability, and performance of reconsolidated salt over time is required for seal design and performance assessment. This report discusses fielding and operations of a nearly full-scale dynamic compaction of mine-run WIPP salt, and presents preliminary density and in situ (in place) gas permeability results.

Ahrens, E.H.; Hansen, F.D. [Sandia National Labs., Albuquerque, NM (United States). Nuclear Waste Technology Repository Isolation Systems

1995-10-01T23:59:59.000Z

448

Novel Molten Salts Thermal Energy Storage for Concentrating Solar Power Generation  

SciTech Connect (OSTI)

The explicit UA program objective is to develop low melting point (LMP) molten salt thermal energy storage media with high thermal energy storage density for sensible heat storage systems. The novel Low Melting Point (LMP) molten salts are targeted to have the following characteristics: 1. Lower melting point (MP) compared to current salts (<222ºC) 2. Higher energy density compared to current salts (>300 MJ/m3) 3. Lower power generation cost compared to current salt In terms of lower power costs, the program target the DOE's Solar Energy Technologies Program year 2020 goal to create systems that have the potential to reduce the cost of Thermal Energy Storage (TES) to less than $15/kWh-th and achieve round trip efficiencies greater than 93%. The project has completed the experimental investigations to determine the thermo-physical, long term thermal stability properties of the LMP molten salts and also corrosion studies of stainless steel in the candidate LMP molten salts. Heat transfer and fluid dynamics modeling have been conducted to identify heat transfer geometry and relative costs for TES systems that would utilize the primary LMP molten salt candidates. The project also proposes heat transfer geometry with relevant modifications to suit the usage of our molten salts as thermal energy storage and heat transfer fluids. The essential properties of the down-selected novel LMP molten salts to be considered for thermal storage in solar energy applications were experimentally determined, including melting point, heat capacity, thermal stability, density, viscosity, thermal conductivity, vapor pressure, and corrosion resistance of SS 316. The thermodynamic modeling was conducted to determine potential high temperature stable molten salt mixtures that have thermal stability up to 1000 °C. The thermo-physical properties of select potential high temperature stable (HMP) molten salt mixtures were also experimentally determined. All the salt mixtures align with the go/no-go goals stipulated by the DOE for this project. Energy densities of all salt mixtures were higher than that of the current solar salt. The salt mixtures costs have been estimated and TES system costs for a 2 tank, direct approach have been estimated for each of these materials. All estimated costs are significantly below the baseline system that used solar salt. These lower melt point salts offer significantly higher energy density per volume than solar salt – and therefore attractively smaller inventory and equipment costs. Moreover, a new TES system geometry has been recommended A variety of approaches were evaluated to use the low melting point molten salt. Two novel changes are recommended that 1) use the salt as a HTF through the solar trough field, and 2) use the salt to not only create steam but also to preheat the condensed feedwater for Rankine cycle. The two changes enable the powerblock to operate at 500°C, rather than the current 400°C obtainable using oil as the HTF. Secondly, the use of salt to preheat the feedwater eliminates the need to extract steam from the low pressure turbine for that purpose. Together, these changes result in a dramatic 63% reduction required for 6 hour salt inventory, a 72% reduction in storage volume, and a 24% reduction in steam flow rate in the power block. Round trip efficiency for the Case 5 - 2 tank “direct” system is estimated at >97%, with only small losses from time under storage and heat exchange, and meeting RFP goals. This attractive efficiency is available because the major heat loss experienced in a 2 tank “indirect” system - losses by transferring the thermal energy from oil HTF to the salt storage material and back to oil to run the steam generator at night - is not present for the 2 tank direct system. The higher heat capacity values for both LMP and HMP systems enable larger storage capacities for concentrating solar power.

Reddy, Ramana G. [The University of Alabama] [The University of Alabama

2013-10-23T23:59:59.000Z

449

The effect of sources of nitrogen on nitrate formation and nitrogen uptake by cotton plants growing on Miller clay loam  

E-Print Network [OSTI]

that the temperature may affect the occurrence of nitrites. Same cultures incubated. at 24oC contained. much ni+rites snd little nitrates, while portions of the same cultures incubated at 3$oC contained nitrates but no nitrites. Cultures from sub-soil are more... criticism during the elaboration of the present work. Appreciation is extended. to Dx. H. E. Hampton, Chaixman of' the Hecognition is due tc Dx. V. M. Artecona and Nr. A. P. Cobra for committee, and. to Dr. A. G. Caldwell for help snd encouragement...

Marcos, Zilmar Ziller

1958-01-01T23:59:59.000Z

450

The influence of dose-rest cycles on the nitrate concentration of deep percolate below septic fields  

E-Print Network [OSTI]

in private water sup- plies in Morgan County, Missouri. J. Milk and Food Technology, 30: 224-225. 23. King, L. D. and H. D. Morris. 1972. Land disposal of liquid sewage sludge; the effect on soil nitrate. J. Environmental Quality, 1: 442-446. 34 24... septic- tank technology. J. Environmental Health, 3, 30: 250-262. 37 APPENDIX 0 ~O O I- CL IJ, I U O O O 20 16 12 8 4 20 I FEB. DOSE IO 20 ' 30 MAR. ~ OXYGEN NITRATE RESI 10 20 30 IO 20 30 10 20 APR . MAY JUNE DATE -120 100...

Allison, John Bryan

1976-01-01T23:59:59.000Z

451

Water Structure at the Air-Aqueous Interface of Divalent Cation and Nitrate Solutions Man Xu, Rick Spinney, and Heather C. Allen*  

E-Print Network [OSTI]

Water Structure at the Air-Aqueous Interface of Divalent Cation and Nitrate Solutions Man Xu, Rick, Columbus, Ohio 43210 ReceiVed: July 24, 2008; ReVised Manuscript ReceiVed: December 4, 2008 The water surface structure of aqueous magnesium, calcium, and strontium nitrate solutions with six to seven water

452

Characterization of bedded salt for storage caverns -- A case study from the Midland Basin, Texas  

SciTech Connect (OSTI)

The geometry of Permian bedding salt in the Midland Basin is a product of interaction between depositional facies and postdepositional modification by salt dissolution. Mapping high-frequency cycle patterns in cross section and map view using wireline logs documents the salt geometry. Geologically based interpretation of depositional and dissolution processes provides a powerful tool for mapping and geometry of salt to assess the suitability of sites for development of solution-mined storage caverns. In addition, this process-based description of salt geometry complements existing data about the evolution of one of the best-known sedimentary basins in the world, and can serve as a genetic model to assist in interpreting other salts.

Hovorka, Susan D.; Nava, Robin

2000-06-13T23:59:59.000Z

453

A mathematical model for investigating the mechanical behaviour of salt cavities  

SciTech Connect (OSTI)

Cavities in salt are widely used for the storage of natural gas and other substances. When used for the storage of gas, the pressure in the cavity may be reduced to well below the geostatic pressure in the surrounding salt. In these conditions the salt will creep and the shape and size of the cavity will change. The ability to predict these changes, and the effect they may have on the subsurface system is necessary for the efficient operation of the storage. British Gas has developed a mathematical model for investigating this mechanical behaviour of salt cavities. It is based on an extensive programme of experimental work to determine the rheological behaviour of the salt. This paper describes this model and shows how it has been used to solve a number of typical problems encountered in the planning and operation of salt cavities.

Lambert, G.M.S.; Creed, M.R.; Dean, F.; Leigh, M.J.

1988-01-01T23:59:59.000Z

454

Blending of Radioactive Salt Solutions in Million Gallon Tanks - 13002  

SciTech Connect (OSTI)

Research was completed at Savannah River National Laboratory (SRNL) to investigate processes related to the blending of radioactive, liquid waste, salt solutions in 4920 cubic meter, 25.9 meter diameter storage tanks. One process was the blending of large salt solution batches (up to 1135 - 3028 cubic meters), using submerged centrifugal pumps. A second process was the disturbance of a settled layer of solids, or sludge, on the tank bottom. And a third investigated process was the settling rate of sludge solids if suspended into slurries by the blending pump. To investigate these processes, experiments, CFD models (computational fluid dynamics), and theory were applied. Experiments were performed using simulated, non-radioactive, salt solutions referred to as supernates, and a layer of settled solids referred to as sludge. Blending experiments were performed in a 2.44 meter diameter pilot scale tank, and flow rate measurements and settling tests were performed at both pilot scale and full scale. A summary of the research is presented here to demonstrate the adage that, 'One good experiment fixes a lot of good theory'. Experimental testing was required to benchmark CFD models, or the models would have been incorrectly used. In fact, CFD safety factors were established by this research to predict full-scale blending performance. CFD models were used to determine pump design requirements, predict blending times, and cut costs several million dollars by reducing the number of required blending pumps. This research contributed to DOE missions to permanently close the remaining 47 of 51 SRS waste storage tanks. (authors)

Leishear, Robert A.; Lee, Si Y.; Fowley, Mark D.; Poirier, Michael R. [Savannah River National Laboratory, Aiken. S.C., 29808 (United States)] [Savannah River National Laboratory, Aiken. S.C., 29808 (United States)

2013-07-01T23:59:59.000Z

455

Blending Of Radioactive Salt Solutions In Million Gallon Tanks  

SciTech Connect (OSTI)

Research was completed at Savannah River National Laboratory (SRNL) to investigate processes related to the blending of radioactive, liquid waste, salt solutions in 4920 cubic meter, 25.9 meter diameter storage tanks. One process was the blending of large salt solution batches (up to 1135 ? 3028 cubic meters), using submerged centrifugal pumps. A second process was the disturbance of a settled layer of solids, or sludge, on the tank bottom. And a third investigated process was the settling rate of sludge solids if suspended into slurries by the blending pump. To investigate these processes, experiments, CFD models (computational fluid dynamics), and theory were applied. Experiments were performed using simulated, non-radioactive, salt solutions referred to as supernates, and a layer of settled solids referred to as sludge. Blending experiments were performed in a 2.44 meter diameter pilot scale tank, and flow rate measurements and settling tests were performed at both pilot scale and full scale. A summary of the research is presented here to demonstrate the adage that, ?One good experiment fixes a lot of good theory?. Experimental testing was required to benchmark CFD models, or the models would have been incorrectly used. In fact, CFD safety factors were established by this research to predict full-scale blending performance. CFD models were used to determine pump design requirements, predict blending times, and cut costs several million dollars by reducing the number of required blending pumps. This research contributed to DOE missions to permanently close the remaining 47 of 51 SRS waste storage tanks.

Leishear, Robert A.; Lee, Si Y.; Fowley, Mark D.; Poirier, Michael R.

2012-12-10T23:59:59.000Z

456

Identifying suitable "piercement" salt domes for nuclear waste storage sites  

SciTech Connect (OSTI)

Piercement salt domes of the northern interior salt basins of the Gulf of Mexico are being considered as permanent storage sites for both nuclear and chemically toxic wastes. The suitable domes are stable and inactive, having reached their final evolutionary configuration at least 30 million years ago. They are buried to depths far below the level to which erosion will penetrate during the prescribed storage period and are not subject to possible future reactivation. The salt cores of these domes are themselves impermeable, permitting neither the entry nor exit of ground water or other unwanted materials. In part, a stable dome may be recognized by its present geometric configuration, but conclusive proof depends on establishing its evolutionary state. The evolutionary state of a dome is obtained by reconstructing the growth history of the dome as revealed by the configuration of sedimentary strata in a large area (commonly 3,000 square miles or more) surrounding the dome. A high quality, multifold CDP reflection seismic profile across a candidate dome will provide much of the necessary information when integrated with available subsurface control. Additional seismic profiles may be required to confirm an apparent configuration of the surrounding strata and an interpreted evolutionary history. High frequency seismic data collected in the near vicinity of a dome are also needed as a supplement to the CDP data to permit accurate depiction of the configuration of shallow strata. Such data must be tied to shallow drill hole control to confirm the geologic age at which dome growth ceased. If it is determined that a dome reached a terminal configuration many millions of years ago, such a dome is incapable of reactivation and thus constitutes a stable storage site for nuclear wastes.

Kehle, R.

1980-08-01T23:59:59.000Z

457

Central collisions of heavy ions  

SciTech Connect (OSTI)

This report describes the activities of the Heavy Ion Physics Group at the University of California, Riverside from October 1, 1991 to September 30, 1992. During this period, the program focused on particle production at AGS energies, and correlation studies at the Bevalac in nucleus-nucleus central collisions. As part of the PHENIX collaboration, contributions were made to the Preliminary Conceptual Design Report (pCDR), and work on a RHIC silicon microstrip detector R D project was performed.

Fung, Sun-yiu.

1992-10-01T23:59:59.000Z

458

Method of preparing sodalite from chloride salt occluded zeolite  

DOE Patents [OSTI]

A method is described for immobilizing waste chloride salts containing radionuclides and hazardous nuclear material for permanent disposal starting with a substantially dry zeolite and sufficient glass to form leach resistant sodalite with occluded radionuclides and hazardous nuclear material. The zeolite and glass are heated to a temperature up to about 1000 K to convert the zeolite to sodalite and thereafter maintained at a pressure and temperature sufficient to form a sodalite product near theoretical density. Pressure is used on the formed sodalite to produce the required density.

Lewis, M.A.; Pereira, C.

1997-03-18T23:59:59.000Z

459

Method of preparing sodalite from chloride salt occluded zeolite  

DOE Patents [OSTI]

A method for immobilizing waste chloride salts containing radionuclides and hazardous nuclear material for permanent disposal starting with a substantially dry zeolite and sufficient glass to form leach resistant sodalite with occluded radionuclides and hazardous nuclear material. The zeolite and glass are heated to a temperature up to about 1000.degree. K. to convert the zeolite to sodalite and thereafter maintained at a pressure and temperature sufficient to form a sodalite product near theoretical density. Pressure is used on the formed sodalite to produce the required density.

Lewis, Michele A. (Naperville, IL); Pereira, Candido (Lisle, IL)

1997-01-01T23:59:59.000Z

460

Salt Waste Contractor Reaches Contract Milestone | Department of Energy  

Office of Environmental Management (EM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "of Energy Power.pdf11-161-LNG |September2-SCORECARD-01-24-13 Page 1 of 1 DepartmentSalt Waste

Note: This page contains sample records for the topic "nitrate salt central" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Salt Lake City Area Integrated Projects Power Sales Rate History  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administration the1 -the Mid-Infrared0 ResourceAwardsSafeguards and SecuritySafety Salt Lake City Area

462

Salt Wells, Eight Mile Flat | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 No revisionEnvReviewNonInvasiveExplorationUT-g Grant ofRichardton Abbey Wind Farm(CTIhinderProject SmartSalt

463

Salt Lake County, Utah: Energy Resources | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia:FAQ < RAPID Jump to: navigation, searchVirginiaRooseveltVI Solaris a city in Utah607793°, -111.8910474°Salt

464

ENEL Salt Wells Geothermal Facility | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 No revision has beenFfe2fb55-352f-473b-a2dd-50ae8b27f0a6 No revision has TypeGeothermalIIONELMARCO s r oENEL Salt

465

Inexpensive, Nonfluorinated Anions for Lithium Salts and Ionic Liquids for  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-UpHeatMulti-Dimensionalthe U.S.Indiana College ProvidesSteamLightingSalts and

466

Sandia National Laboratories: Molten-Salt Storage System  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administration the1 -theErik Spoerke SSLSMolten-Salt Storage System Areva Solar and Sandia Labs Join

467

Sandia National Laboratories: New Liquid Salt Electrolytes Could Lead to  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administration the1 -theErik Spoerke SSLSMolten-Salt Storage SystemAir ForceBoard of

468

Advanced Thermal Storage System with Novel Molten Salt: December 8, 2011 - April 30, 2013  

SciTech Connect (OSTI)

Final technical progress report of Halotechnics Subcontract No. NEU-2-11979-01. Halotechnics has demonstrated an advanced thermal energy storage system with a novel molten salt operating at 700 degrees C. The molten salt and storage system will enable the use of advanced power cycles such as supercritical steam and supercritical carbon dioxide in next generation CSP plants. The salt consists of low cost, earth abundant materials.

Jonemann, M.

2013-05-01T23:59:59.000Z

469

Method for immobilizing mixed waste chloride salts containing radionuclides and other hazardous wastes  

DOE Patents [OSTI]

The invention is a method for the encapsulation of soluble radioactive waste chloride salts containing radionuclides such as strontium, cesium and hazardous wastes such as barium so that they may be permanently stored without future threat to the environment. The process consists of contacting the salts containing the radionuclides and hazardous wastes with certain zeolites which have been found to ion exchange with the radionuclides and to occlude the chloride salts so that the resulting product is leach resistant.

Lewis, Michele A. (Naperville, IL); Johnson, Terry R. (Wheaton, IL)

1993-01-01T23:59:59.000Z

470

Lithium borate cluster salts as novel redox shuttles for overcharge protection of lithium-ion cells.  

SciTech Connect (OSTI)

Redox shuttle is a promising mechanism for intrinsic overcharge protection in lithium-ion cells and batteries. Two lithium borate cluster salts are reported to function as both the main salt for a nonaqueous electrolyte and the redox shuttle for overcharge protection. Lithium borate cluster salts with a tunable redox potential are promising candidates for overcharge protection for most positive electrodes in state-of-the-art lithium-ion cells.

Chen, Z.; Liu, J.; Jansen, A. N.; Casteel, B.; Amine, K.; GirishKumar, G.; Air Products and Chemicals, Inc.

2010-01-01T23:59:59.000Z

471

Biochemical solubilization of toxic salts from residual geothermal brines and waste waters  

DOE Patents [OSTI]

A method of solubilizing metal salts such as metal sulfides in a geothermal sludge using mutant Thiobacilli selected for their ability to metabolize metal salts at high temperature is disclosed. The method includes the introduction of mutated Thiobacillus ferrooxidans and Thiobacillus thiooxidans to a geothermal sludge or brine. The microorganisms catalyze the solubilization of metal salts. For instance, in the case of metal sulfides, the microorganisms catalyze the solubilization to form soluble metal sulfates. 54 figs.

Premuzic, E.T.; Lin, M.S.

1994-11-22T23:59:59.000Z

472

Biochemical solubilization of toxic salts from residual geothermal brines and waste waters  

DOE Patents [OSTI]

A method of solubilizing metal salts such as metal sulfides in a geothermal sludge using mutant Thiobacilli selected for their ability to metabolize metal salts at high temperature is disclosed, The method includes the introduction of mutated Thiobacillus ferrooxidans and Thiobacillus thiooxidans to a geothermal sludge or brine. The microorganisms catalyze the solubilization of metal salts, For instance, in the case of metal sulfides, the microorganisms catalyze the solubilization to form soluble metal sulfates.

Premuzic, Eugene T. (East Moriches, NY); Lin, Mow S. (Rocky Point, NY)

1994-11-22T23:59:59.000Z

473

Levels of metals from salt marsh plants from Southern California, USA  

E-Print Network [OSTI]

sedimentary record of heavy metal pollution in the lagoon ofcapacity for heavy metals. Environmental Pollution, 146,heavy metals in experimental salt marsh ecosystems. Environmental Pollution,

Hoyt, Kimberly Ann

2009-01-01T23:59:59.000Z

474

Salt effect on the isobaric vapor-liquid equilibrium of the methyl acetate + methanol system  

SciTech Connect (OSTI)

The effect of sodium thiocyanate at constant salt mole fraction from 0.01 to 0.05 and at saturation on the vapor-liquid equilibrium (VLE) of methyl acetate + methanol has been studied at 101.32 kPa using a modified Othmer equilibrium still. The salt exhibited both salting-in and salting-out effects on the methyl acetate, the azeotrope being eliminated at saturation. The results were correlated using the extended UNIQUAC model of Sander et al. and the electrolytic NRTL model of Mock et al.

Iliuta, M.C.; Thyrion, F.C. [Louvain Univ., Louvain-la-Neuve (Belgium). Chemical Engineering Inst.] [Louvain Univ., Louvain-la-Neuve (Belgium). Chemical Engineering Inst.; Landauer, O.M. [Univ. Politehnica Bucharest (Romania)] [Univ. Politehnica Bucharest (Romania)

1996-07-01T23:59:59.000Z

475

Plane of nutrition as influencing reaction of breeding cows to high salt intake  

E-Print Network [OSTI]

of salt zvith 100 pounds w cottonseed iveal con- suzzed neazly tvvice as much cottonseed meal (2. F&5 pounds per day) as those hand-fod 1. 5 pounds o" either soybean pollots or cottonseed calzo daily and showed a somezvhat t-roster Sain as a... average exczetioz of salt by tizc con- trol covrs vvas 53. 57 dramas. Vlze no"ativo salt balance or !. roster cxcrotion of salt than intel e, :!c. r bo explsinod by the fact that this tz ial vras of s'i!ort duration ancl the covrs . vere somevrlzat...

Sells, Louis Vaughn

1951-01-01T23:59:59.000Z

476

Profile of teen mothers in a Salt Lake County school district;.  

E-Print Network [OSTI]

??The purpose of this descriptive study was to profile young women currently enrolled in a Salt Lake Count school district Young Parent Program. This profile… (more)

Wanlass, Bonnie J.

1999-01-01T23:59:59.000Z

477

Single-Well and Cross-Well Seismic At Salt Wells Area (Bureau...  

Open Energy Info (EERE)

Seismic At Salt Wells Area (Bureau of Land Management, 2009) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Single-Well and Cross-Well Seismic...

478

Site selection for the Salt Disposition Facility at the Savannah River Site  

SciTech Connect (OSTI)

The purpose of this report is to identify, assess, and rank potential sites for the proposed Salt Disposition Facility (SDF) at the Savannah River Site.

Bowers, J.A.

2000-01-03T23:59:59.000Z

479

Regulation of benthic algal and animal communities by salt marsh plants: Impact of shading  

E-Print Network [OSTI]

of marine wetland microalgae and photosyn- thetic bacteria:concentrating mechanisms in microalgae. Canadian Journal ofalterni?ora and benthic microalgae in salt marsh food webs:

Whitcraft, Christine R.; Levin, Lisa A.

2007-01-01T23:59:59.000Z

480

Williston Basin: An analysis of salt drilling techniques for brine-based drilling-fluid systems  

SciTech Connect (OSTI)

Williston Basin salt intervals, ranging in depth from 5,000 to 12,500 ft (1525 to 3810 m), have been responsible for widespread casing collapse because of the plastic movement of evaporites and the subsequent point loading of casing. This phenomenon is attributable to poor cement jobs across excessively eroded salt sections. A 2-year study led to the realization that this erosion is a function of not only salt dissolution but also the mechanical action of turbulent flow in the wellbore. A laminar flow regime can be realized and salt enlargement limited by careful control of annular flow rate, jet velocity, and drilling-fluid rheology.

Stash, S.M.; Jones, M.E.

1988-03-01T23:59:59.000Z

Note: This page contains sample records for the topic "nitrate salt central" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

Voluntary Protection Program Onsite Review, Salt Waste Processing Facility Construction Project- February 2013  

Broader source: Energy.gov [DOE]

Evaluation to determine whether Salt Waste Processing Facility Construction Project is continuing to perform at a level deserving DOE-VPP Star recognition.

482

Calculation of density and permeability of compacted crushed salt within an engineered shaft sealing system  

SciTech Connect (OSTI)

Crushed salt from the host Salado Formation is proposed as a sealing material in one component of a multicomponent seal system design for the shafts of the Waste Isolation Pilot Plant (WIPP), a mined geological repository for storage and disposal of transuranic radioactive wastes located near Carlsbad, New Mexico. The crushed salt will be compacted and placed at a density approaching 90% of the intact density of the host Salado salt. Creep closure of the shaft will further compact the crushed salt over time, thereby reducing the crushed-salt permeability from the initial state and creating an effective long-term seal. A structural model and a fluid flow model have been developed to provide an estimate of crushed-salt reconsolidation rate as a function of depth, time, and pore pressure. Model results are obtained in terms of crushed-salt permeability as a function of time and depth within the salt column. Model results indicate that average salt column permeability will be re