National Library of Energy BETA

Sample records for nitrate salt central

  1. Project Profile: Advanced Nitrate Salt Central Receiver Power Plant |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Nitrate Salt Central Receiver Power Plant Project Profile: Advanced Nitrate Salt Central Receiver Power Plant Abengoa logo Abengoa, under the Baseload CSP FOA, will demonstrate a 100-megawatt electrical (MWe) central receiver plant using nitrate salt as the receiver coolant, thermal storage medium, and heat transport fluid in the steam generator. Approach Photo of two lit towers surrounded by much smaller blue flat plates that are mounted on the ground. The plan is to

  2. Baseload Nitrate Salt Central Receiver Power Plant Design Final Report

    SciTech Connect (OSTI)

    Tilley, Drake; Kelly, Bruce; Burkholder, Frank

    2014-12-12

    The objectives of the work were to demonstrate that a 100 MWe central receiver plant, using nitrate salt as the receiver coolant, thermal storage medium, and heat transport fluid in the steam generator, can 1) operate, at full load, for 6,400 hours each year using only solar energy, and 2) satisfy the DOE levelized energy cost goal of $0.09/kWhe (real 2009 $). To achieve these objectives the work incorporated a large range of tasks relating to many different aspects of a molten salt tower plant. The first Phase of the project focused on developing a baseline design for a Molten Salt Tower and validating areas for improvement. Tasks included a market study, receiver design, heat exchanger design, preliminary heliostat design, solar field optimization, baseline system design including PFDs and P&IDs and detailed cost estimate. The baseline plant met the initial goal of less than $0.14/kWhe, and reinforced the need to reduce costs in several key areas to reach the overall $0.09/kWhe goal. The major improvements identified from Phase I were: 1) higher temperature salt to improve cycle efficiency and reduce storage requirements, 2) an improved receiver coating to increase the efficiency of the receiver, 3) a large receiver design to maximize storage and meet the baseload hours objective, and 4) lower cost heliostat field. The second Phase of the project looked at advancing the baseline tower with the identified improvements and included key prototypes. To validate increasing the standard solar salt temperature to 600 °C a dynamic test was conducted at Sandia. The results ultimately proved the hypothesis incorrect and showed high oxide production and corrosion rates. The results lead to further testing of systems to mitigate the oxide production to be able to increase the salt temperature for a commercial plant. Foster Wheeler worked on the receiver design in both Phase I and Phase II looking at both design and lowering costs utilizing commercial fossil boiler manufacturing. The cost and design goals for the project were met with this task, but the most interesting results had to do with defining the failure modes and looking at a “shakedown analysis” of the combined creep-fatigue failure. A separate task also looked at improving the absorber coatings on the receiver tubes that would improve the efficiency of the receiver. Significant progress was made on developing a novel paint with a high absorptivity that was on par with the current Pyromark, but shows additional potential to be optimized further. Although the coating did not meet the emissivity goals, preliminary testing the new paint shows potential to be much more durable, and potential to improve the receiver efficiency through a higher average absorptivity over the lifetime. Additional coatings were also designed and modeled results meet the project goals, but were not tested. Testing for low cycle fatigue of the full length receiver tubes was designed and constructed, but is still currently undergoing testing. A novel small heliostat was developed through an extensive brainstorming and down select. The concept was then detailed further with inputs from component testing and eventually a full prototype was built and tested. This task met or exceeded the accuracy and structure goals and also beat the cost goal. This provides a significant solar field costs savings for Abengoa that will be developed further to be used in future commercial plants. Ultimately the $0.09/kWhe (real 2009 $) and 6,400 hours goals of the project were met.

  3. Waste Isolation Pilot Plant Nitrate Salt Bearing Waste Container...

    Office of Environmental Management (EM)

    Nitrate Salt Bearing Waste Container Isolation Plan Waste Isolation Pilot Plant Nitrate Salt Bearing Waste Container Isolation Plan The purpose of this document is to provide the ...

  4. Sandia Energy - Molten Nitrate Salt Initial Flow Testing is a...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nitrate Salt Initial Flow Testing is a Tremendous Success Home Renewable Energy News Concentrating Solar Power Solar Molten Nitrate Salt Initial Flow Testing is a Tremendous...

  5. Remediated Nitrate Salt Drums Safety Update | Department of Energy

    Office of Environmental Management (EM)

    Remediated Nitrate Salt Drums Safety Update Remediated Nitrate Salt Drums Safety Update Topic: Mr. Nickless, Environmental Management Los Alamos, Provided a presentation on the status of the Nitrate Salt waste at Los Alamos. More Documents & Publications Los Alamos National Laboratory TRU Waste Update Los Alamos National Laboratory Accident Investigation Board Corrective Action Plan Update Treatment of Remediated Nitrate Salts

  6. Nitrate Salt Surrogate Blending Scoping Test Plan

    SciTech Connect (OSTI)

    Anast, Kurt Roy

    2015-11-13

    Test blending equipment identified in the “Engineering Options Assessment Report: Nitrate Salt Waste Stream Processing”. Determine if the equipment will provide adequate mixing of zeolite and surrogate salt/Swheat stream; optimize equipment type and operational sequencing; impact of baffles and inserts on mixing performance; and means of validating mixing performance

  7. Treatment of Remediated Nitrate Salts | Department of Energy

    Energy Savers [EERE]

    Treatment of Remediated Nitrate Salts Treatment of Remediated Nitrate Salts Topic: Plan for remediation the nitrate salt waste from the 3706 campaign that is currently stored at Material Disposal Area G, presenter was David Funk, LANS. PDF icon Nitrate Salts - November 18, 2015 More Documents & Publications Accident Investigation Report Phase II Accident Investigation Report - Radiological Release Amount of Zeolite Required to Meet the Constraints Established by the Energetic Materials

  8. Corrosion of aluminides by molten nitrate salt

    SciTech Connect (OSTI)

    Tortorelli, P.F.; Bishop, P.S.

    1990-01-01

    The corrosion of titanium-, iron-, and nickel-based aluminides by a highly aggressive, oxidizing NaNO{sub 3}(-KNO{sub 3})-Na{sub 2}O{sub 2} has been studied at 650{degree}C. It was shown that weight changes could be used to effectively evaluate corrosion behavior in the subject nitrate salt environments provided these data were combined with salt analyses and microstructural examinations. The studies indicated that the corrosion of relatively resistant aluminides by these nitrate salts proceeded by oxidation and a slow release from an aluminum-rich product layer into the salt at rates lower than that associated with many other types of metallic materials. The overall corrosion process and resulting rate depended on the particular aluminide being exposed. In order to minimize corrosion of nickel or iron aluminides, it was necessary to have aluminum concentrations in excess of 30 at. %. However, even at a concentration of 50 at. % Al, the corrosion resistance of TiAl was inferior to that of Ni{sub 3}Al and Fe{sub 3}Al. At higher aluminum concentrations, iron, nickel, and iron-nickel aluminides exhibited quite similar weight changes, indicative of the principal role of aluminum in controlling the corrosion process in NaNO{sub 3}(-KNO{sub 3})-Na{sub 2}O{sub 2} salts. 20 refs., 5 figs., 3 tabs.

  9. Supplemental Cooling for Nitrate Salt Waste

    SciTech Connect (OSTI)

    Goldberg, Mitchell S.

    2015-08-19

    In July 2015, Los Alamos National Laboratory completed installation of a supplemental cooling system in the structure where remediated nitrate salt waste drums are stored. Although the waste currently is in a safe configuration and is monitored daily,controlling the temperature inside the structure adds another layer of protection for workers, the public,and the environment.This effort is among several layers of precautions designed to secure the waste.

  10. Waste Isolation Pilot Plant Nitrate Salt Bearing Waste Container

    Office of Environmental Management (EM)

    Nitrate Salt Bearing Waste Container Isolation Plan Prepared in Response to New Mexico ... (DOE) and Nuclear Waste Partnership LLC (NWP), collectively referred to as the Permittees. ...

  11. Molten Nitrate Salt Development for Thermal Energy Storage in...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    MOLTEN NITRATE SALT DEVELOPMENT FOR THERMAL ENERGY STORAGE IN PARABOLIC TROUGH SOLAR POWER SYSTEMS Robert W. Bradshaw and Nathan P. Siegel Sandia National Laboratories, PO Box 969 ...

  12. Nitrate Salt Bearing Transuranic Waste Container Monitoring | Department of

    Office of Environmental Management (EM)

    Energy Nitrate Salt Bearing Transuranic Waste Container Monitoring Nitrate Salt Bearing Transuranic Waste Container Monitoring This document was used to determine facts and conditions during the Department of Energy Accident Investigation Board's investigation into the radiological release event at the Waste Isolation Pilot Plant. Additional documents referenced and listed in the Phase 2 Radiological Release Event at the Waste Isolation Pilot Plant on February 14, 2014, report in Attachment

  13. Waste Isolation Pilot Plant Nitrate Salt Bearing Waste Container Isolation

    Broader source: Energy.gov (indexed) [DOE]

    Plan | Department of Energy The purpose of this document is to provide the Plan required by the New Mexico Environment Department Administrative Order 05-20001 issued on May 20, 2014 to the U. S. Department of Energy and Nuclear Waste Partnership LLC. The Order, at paragraph 22, requires the Permittees to submit a WIPP Nitrate Salt Bearing Waste Container Isolation Plan for identified nitrate salt bearing waste disposed in the Waste Isolation Pilot Plant underground disposal facility. PDF

  14. Denitration of High Nitrate Salts Using Reductants

    SciTech Connect (OSTI)

    HD Smith; EO Jones; AJ Schmidt; AH Zacher; MD Brown; MR Elmore; SR Gano

    1999-05-03

    This report describes work conducted by Pacific Northwest National Laboratory (PNNL), in conjunction with Idaho National Engineering and Environmental Laboratory (INEEL), to remove nitrates in simulated low-activity waste (LAW). The major objective of this work was to provide data for identifying and demonstrating a technically viable and cost-effective approach to condition LAW for immobilization (grout).

  15. Technical Area (TA)-54 Area G Nitrate-Salt Waste Container Response...

    Office of Environmental Management (EM)

    Technical Area (TA)-54 Area G Nitrate-Salt Waste Container Response Instructions Technical Area (TA)-54 Area G Nitrate-Salt Waste Container Response Instructions This document was...

  16. Engineering Options Assessment Report: Nitrate Salt Waste Stream Processing

    SciTech Connect (OSTI)

    Anast, Kurt Roy

    2015-11-18

    This report examines and assesses the available systems and facilities considered for carrying out remediation activities on remediated nitrate salt (RNS) and unremediated nitrate salt (UNS) waste containers at Los Alamos National Laboratory (LANL). The assessment includes a review of the waste streams consisting of 60 RNS, 29 aboveground UNS, and 79 candidate belowground UNS containers that may need remediation. The waste stream characteristics were examined along with the proposed treatment options identified in the Options Assessment Report . Two primary approaches were identified in the five candidate treatment options discussed in the Options Assessment Report: zeolite blending and cementation. Systems that could be used at LANL were examined for housing processing operations to remediate the RNS and UNS containers and for their viability to provide repackaging support for remaining LANL legacy waste.

  17. Engineering Options Assessment Report. Nitrate Salt Waste Stream Processing

    SciTech Connect (OSTI)

    Anast, Kurt Roy

    2015-11-13

    This report examines and assesses the available systems and facilities considered for carrying out remediation activities on remediated nitrate salt (RNS) and unremediated nitrate salt (UNS) waste containers at Los Alamos National Laboratory (LANL). The assessment includes a review of the waste streams consisting of 60 RNS, 29 above-ground UNS, and 79 candidate below-ground UNS containers that may need remediation. The waste stream characteristics were examined along with the proposed treatment options identified in the Options Assessment Report . Two primary approaches were identified in the five candidate treatment options discussed in the Options Assessment Report: zeolite blending and cementation. Systems that could be used at LANL were examined for housing processing operations to remediate the RNS and UNS containers and for their viability to provide repackaging support for remaining LANL legacy waste.

  18. Waste Isolation Pilot Plant Nitrate Salt Bearing Waste Container

    Office of Environmental Management (EM)

    Nitrate Salt Bearing Waste Container Isolation Plan Prepared in Response to New Mexico Environment Department Administrative Order 05-20001 Issued May 20, 2014 1.0 INTRODUCTION The purpose of this document is to provide the Plan required by the New Mexico Environment Department (NMED) Administrative Order 05-20001 (Order) issued on May 20, 2014 to the U. S. Department of Energy (DOE) and Nuclear Waste Partnership LLC (NWP), collectively referred to as the Permittees. The Order, at paragraph 22,

  19. WIPP Nitrate Salt Bearing Waste Container Isolation Plan Implementation Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nitrate Salt Bearing Waste Container Isolation Plan Implementation Update May 12, 2015 Panel 6 and Panel 7, Room 7 a. Rollback * Contamination Assessment-This prerequisite is complete and therefore status updates are no longer required. * Fixing/Decontamination Activities-Decontaminated equipment has been removed from Room 7 of Panel 7 to prepare for Room 7 closure activities. Remaining items in Panel 7, Room 7 include thirteen empty magnesium oxide racks, about 200 roof bolts, nine messenger

  20. Low-melting point inorganic nitrate salt heat transfer fluid

    DOE Patents [OSTI]

    Bradshaw, Robert W.; Brosseau, Douglas A.

    2009-09-15

    A low-melting point, heat transfer fluid made of a mixture of four inorganic nitrate salts: 9-18 wt % NaNO.sub.3, 40-52 wt % KNO.sub.3, 13-21 wt % LiNO.sub.3, and 20-27 wt % Ca(NO.sub.3).sub.2. These compositions can have liquidus temperatures less than 100 C; thermal stability limits greater than 500 C; and viscosity in the range of 5-6 cP at 300 C; and 2-3 cP at 400 C.

  1. Effect of composition on the density of multi-component molten nitrate salts.

    SciTech Connect (OSTI)

    Bradshaw, Robert W.

    2009-12-01

    The density of molten nitrate salts was measured to determine the effects of the constituents on the density of multi-component mixtures. The molten salts consisted of various proportions of the nitrates of potassium, sodium, lithium and calcium. Density measurements ere performed using an Archimedean method and the results were compared to data reported in the literature for the individual constituent salts or simple combinations, such as the binary Solar Salt mixture of NaNO3 and KNO3. The addition of calcium nitrate generally ncreased density, relative to potassium nitrate or sodium nitrate, while lithium nitrate decreased density. The temperature dependence of density is described by a linear equation regardless of composition. The molar volume, and thereby, density of multi-component mixtures an be calculated as a function of temperature using a linear additivity rule based on the properties of the individual constituents.

  2. Viscosity of multi-component molten nitrate salts : liquidus to 200 degrees C.

    SciTech Connect (OSTI)

    Bradshaw, Robert W.

    2010-03-01

    The viscosity of molten salts comprising ternary and quaternary mixtures of the nitrates of sodium, potassium, lithium and calcium was determined experimentally. Viscosity was measured over the temperature range from near the relatively low liquidus temperatures of he individual mixtures to 200C. Molten salt mixtures that do not contain calcium nitrate exhibited relatively low viscosity and an Arrhenius temperature dependence. Molten salt mixtures that contained calcium nitrate were relatively more viscous and viscosity increased as the roportion of calcium nitrate increased. The temperature dependence of viscosity of molten salts containing calcium nitrate displayed curvature, rather than linearity, when plotted in Arrhenius format. Viscosity data for these mixtures were correlated by the Vogel-Fulcher- ammann-Hesse equation.

  3. EP-AREAG-PLAN-1248, R.0 TA-54 Area G Nitrate-Salt Waste Container...

    Office of Environmental Management (EM)

    EP-AREAG-PLAN-1248, R.0 TA-54 Area G Nitrate-Salt Waste Container Response Instructions Effective Date: 5282014 The Responsible Manager has determined that the following...

  4. Technical Area (TA)-54 Area G Nitrate-Salt Waste Container Response

    Office of Environmental Management (EM)

    Instructions | Department of Energy Technical Area (TA)-54 Area G Nitrate-Salt Waste Container Response Instructions Technical Area (TA)-54 Area G Nitrate-Salt Waste Container Response Instructions This document was used to determine facts and conditions during the Department of Energy Accident Investigation Board's investigation into the radiological release event at the Waste Isolation Pilot Plant. Additional documents referenced and listed in the Phase 2 Radiological Release Event at the

  5. Analytical Chemistry and Materials Characterization Results for Debris Recovered from Nitrate Salt Waste Drum S855793

    SciTech Connect (OSTI)

    Martinez, Patrick Thomas; Chamberlin, Rebecca M.; Schwartz, Daniel S.; Worley, Christopher Gordon; Garduno, Katherine; Lujan, Elmer J. W.; Borrego, Andres Patricio; Castro, Alonso; Colletti, Lisa Michelle; Fulwyler, James Brent; Holland, Charlotte S.; Keller, Russell C.; Klundt, Dylan James; Martinez, Alexander; Martin, Frances Louise; Montoya, Dennis Patrick; Myers, Steven Charles; Porterfield, Donivan R.; Schake, Ann Rene; Schappert, Michael Francis; Soderberg, Constance B.; Spencer, Khalil J.; Stanley, Floyd E.; Thomas, Mariam R.; Townsend, Lisa Ellen; Xu, Ning

    2015-09-16

    Solid debris was recovered from the previously-emptied nitrate salt waste drum S855793. The bulk sample was nondestructively assayed for radionuclides in its as-received condition. Three monoliths were selected for further characterization. Two of the monoliths, designated Specimen 1 and 3, consisted primarily of sodium nitrate and lead nitrate, with smaller amounts of lead nitrate oxalate and lead oxide by powder x-ray diffraction. The third monolith, Specimen 2, had a complex composition; lead carbonate was identified as the predominant component, and smaller amounts of nitrate, nitrite and carbonate salts of lead, magnesium and sodium were also identified. Microfocused x-ray fluorescence (MXRF) mapping showed that lead was ubiquitous throughout the cross-sections of Specimens 1 and 2, while heteroelements such as potassium, calcium, chromium, iron, and nickel were found in localized deposits. MXRF examination and destructive analysis of fragments of Specimen 3 showed elevated concentrations of iron, which were broadly distributed through the sample. With the exception of its high iron content and low carbon content, the chemical composition of Specimen 3 was within the ranges of values previously observed in four other nitrate salt samples recovered from emptied waste drums.

  6. EMRTC Report RF 10-13: Application to LANL Evaporator Nitrate Salts

    Office of Environmental Management (EM)

    Amount of Zeolite Required to Meet the Constraints Established by the EMRTC Report RF 10-13: Application to LANL Evaporator Nitrate Salts 5/8/2012 LANL-Carlsbad Office Difficult Waste Team P2010-3306 Amount of Zeolite Required to Meet the Constraints Established by the EMRTC Report RF 10- 13: Application to LANL Evaporator Nitrate Salts 2 Purpose: The following document was developed in support of the Los Alamos National Laboratory Transuranic Program (LTP) by the LANL-Carlsbad Office, Difficult

  7. Options assessment report: Treatment of nitrate salt waste at Los Alamos National Laboratory

    SciTech Connect (OSTI)

    Robinson, Bruce Alan; Stevens, Patrice Ann

    2015-09-16

    This report documents the methodology used to select a method of treatment for the remediated nitrate salt (RNS) and unremediated nitrate salt (UNS) waste containers at Los Alamos National Laboratory (LANL). The method selected should treat the containerized waste in a manner that renders the waste safe and suitable for transport and final disposal in the Waste Isolation Pilot Plant (WIPP) repository, under specifications listed in the WIPP Waste Acceptance Criteria (DOE/CBFO, 2013). LANL recognized that the results must be thoroughly vetted with the New Mexico Environment Department (NMED) and the a modification to the LANL Hazardous Waste Facility Permit is a necessary step before implementation of this or any treatment option. Likewise, facility readiness and safety basis approvals must be received from the Department of Energy (DOE). This report presents LANL's preferred option, and the documentation of the process for reaching the recommended treatment option for RNS and UNS waste, and is presented for consideration by NMED and DOE.

  8. Options Assessment Report: Treatment of Nitrate Salt Waste at Los Alamos National Laboratory

    SciTech Connect (OSTI)

    Robinson, Bruce Alan; Stevens, Patrice Ann

    2015-12-17

    This report documents the methodology used to select a method of treatment for the remediated nitrate salt (RNS) and unremediated nitrate salt (UNS) waste containers at Los Alamos National Laboratory (LANL). The method selected should treat the containerized waste in a manner that renders the waste safe and suitable for transport and final disposal in the Waste Isolation Pilot Plant (WIPP) repository, under specifications listed in the WIPP Waste Acceptance Criteria (DOE/CBFO, 2013). LANL recognizes that the results must be thoroughly vetted with the New Mexico Environment Department (NMED) and that a modification to the LANL Hazardous Waste Facility Permit is a necessary step before implementation of this or any treatment option. Likewise, facility readiness and safety basis approvals must be received from the Department of Energy (DOE). This report presents LANL’s preferred option, and the documentation of the process for reaching the recommended treatment option for RNS and UNS waste, and is presented for consideration by NMED and DOE.

  9. Materials corrosion of high temperature alloys immersed in 600C binary nitrate salt.

    SciTech Connect (OSTI)

    Kruizenga, Alan Michael; Gill, David Dennis; LaFord, Marianne Elizabeth

    2013-03-01

    Thirteen high temperature alloys were immersion tested in a 60/40 binary nitrate salt. Samples were interval tested up to 3000 hours at 600%C2%B0C with air as the ullage gas. Chemical analysis of the molten salt indicated lower nitrite concentrations present in the salt, as predicted by the equilibrium equation. Corrosion rates were generally low for all alloys. Corrosion products were identified using x-ray diffraction and electron microprobe analysis. Fe-Cr based alloys tended to form mixtures of sodium and iron oxides, while Fe-Ni/Cr alloys had similar corrosion products plus oxides of nickel and chromium. Nickel based alloys primarily formed NiO, with chromium oxides near the oxide/base alloy interface. In625 exhibited similar corrosion performance in relation to previous tests, lending confidence in comparisons between past and present experiments. HA230 exhibited internal oxidation that consisted of a nickel/chromium oxide. Alloys with significant aluminum alloying tended to exhibit superior performance, due formation of a thin alumina layer. Soluble corrosion products of chromium, molybdenum, and tungsten were also formed and are thought to be a significant factor in alloy performance.

  10. Salt South Central Region Natural Gas Working Underground Storage (Billion

    Gasoline and Diesel Fuel Update (EIA)

    Cubic Feet) Salt South Central Region Natural Gas Working Underground Storage (Billion Cubic Feet) Salt South Central Region Natural Gas Working Underground Storage (Billion Cubic Feet) Year-Month Week 1 Week 2 Week 3 Week 4 Week 5 End Date Value End Date Value End Date Value End Date Value End Date Value 2010-Jan 01/01 159 01/08 123 01/15 91 01/22 102 01/29 108 2010-Feb 02/05 95 02/12 85 02/19 71 02/26 70 2010-Mar 03/05 63 03/12 71 03/19 80 03/26 89 2010-Apr 04/02 101 04/09 112 04/16 120

  11. Polyethylene encapsulatin of nitrate salt wastes: Waste form stability, process scale-up, and economics

    SciTech Connect (OSTI)

    Kalb, P.D.; Heiser, J.H. III; Colombo, P.

    1991-07-01

    A polyethylene encapsulation system for treatment of low-level radioactive, hazardous, and mixed wastes has been developed at Brookhaven National Laboratory. Polyethylene has several advantages compared with conventional solidification/stabilization materials such as hydraulic cements. Waste can be encapsulated with greater efficiency and with better waste form performance than is possible with hydraulic cement. The properties of polyethylene relevant to its long-term durability in storage and disposal environments are reviewed. Response to specific potential failure mechanisms including biodegradation, radiation, chemical attack, flammability, environmental stress cracking, and photodegradation are examined. These data are supported by results from extensive waste form performance testing including compressive yield strength, water immersion, thermal cycling, leachability of radioactive and hazardous species, irradiation, biodegradation, and flammability. The bench-scale process has been successfully tested for application with a number of specific problem'' waste streams. Quality assurance and performance testing of the resulting waste form confirmed scale-up feasibility. Use of this system at Rocky Flats Plant can result in over 70% fewer drums processed and shipped for disposal, compared with optimal cement formulations. Based on the current Rocky Flats production of nitrate salt per year, polyethylene encapsulation can yield an estimated annual savings between $1.5 million and $2.7 million, compared with conventional hydraulic cement systems. 72 refs., 23 figs., 16 tabs.

  12. EP-AREAG-PLAN-1248, R.0 TA-54 Area G Nitrate-Salt Waste Container Response Instructions

    Office of Environmental Management (EM)

    EP-AREAG-PLAN-1248, R.0 TA-54 Area G Nitrate-Salt Waste Container Response Instructions Effective Date: 5/28/2014 The Responsible Manager has determined that the following organizations' review/concurrence is required for the initial document and for major revisions a same type and level review is required. Review documentation is contained in the Document History File: EWMO Engineering LANL TRU Programs - Shipping and Safe Storage Disposition LANL TRU Programs - Drum Disposition Project LANL

  13. Nitrate reduction

    DOE Patents [OSTI]

    Dziewinski, Jacek J. (Los Alamos, NM); Marczak, Stanislaw (Los Alamos, NM)

    2000-01-01

    Nitrates are reduced to nitrogen gas by contacting the nitrates with a metal to reduce the nitrates to nitrites which are then contacted with an amide to produce nitrogen and carbon dioxide or acid anions which can be released to the atmosphere. Minor amounts of metal catalysts can be useful in the reduction of the nitrates to nitrites. Metal salts which are formed can be treated electrochemically to recover the metals.

  14. WIPP Nitrate Updates 2015

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    5 WIPP Nitrate Salt Bearing Waste Container Isolation Plan Implementation Update, July 23, 2015 Waste Isolation Pilot Plant EPA I.D. Number: NM4890139088-TSDF WIPP Nitrate Salt...

  15. Corrosion resistance of stainless steels during thermal cycling in alkali nitrate molten salts.

    SciTech Connect (OSTI)

    Bradshaw, Robert W.; Goods, Steven Howard

    2001-09-01

    The corrosion behavior of three austenitic stainless steels was evaluated during thermal cycling in molten salt mixtures consisting of NaNO{sub 3} and KNO{sub 3}. Corrosion tests were conducted with Types 316, 316L and 304 stainless steels for more than 4000 hours and 500 thermal cycles at a maximum temperature of 565 C. Corrosion rates were determined by chemically descaling coupons. Metal losses ranged from 5 to 16 microns and thermal cycling resulted in moderately higher corrosion rates compared to isothermal conditions. Type 316 SS was somewhat more corrosion resistant than Type 304 SS in these tests. The effect of carbon content on corrosion resistance was small, as 316L SS corroded only slightly slower than 316 SS. The corrosion rates increased as the dissolved chloride content of the molten salt mixtures increased. Chloride concentrations approximating 1 wt.%, coupled with thermal cycling, resulted in linear weight loss kinetics, rather than parabolic kinetics, which described corrosion rates for all other conditions. Optical microscopy and electron microprobe analysis revealed that the corrosion products consisted of iron-chromium spinel, magnetite, and sodium ferrite, organized as separate layers. Microanalysis of the elemental composition of the corrosion products further demonstrated that the chromium content of the iron-chromium spinel layer was relatively high for conditions in which parabolic kinetics were observed. However, linear kinetics were observed when the spinel layer contained relatively little chromium.

  16. WIPP Nitrate Updates 2014

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Update, December 4, 2014 Waste Isolation Pilot Plant EPA I.D. Number: NM4890139088-TSDF Jose R. FrancoCBFO and Robert L. McQuinnNWP dated December 5, 2014 WIPP Nitrate Salt...

  17. ,"Weekly Salt South Central Region Natural Gas Working Underground Storage (Billion Cubic Feet)"

    U.S. Energy Information Administration (EIA) Indexed Site

    Salt South Central Region Natural Gas Working Underground Storage (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Weekly Salt South Central Region Natural Gas Working Underground Storage (Billion Cubic Feet)",1,"Weekly","3/11/2016" ,"Release Date:","3/17/2016"

  18. Ferrocyanide Safety Project Dynamic X-Ray Diffraction studies of sodium nickel ferrocyanide reactions with equimolar nitrate/nitrite salts

    SciTech Connect (OSTI)

    Dodds, J.N. |

    1994-07-01

    Dynamic X-ray Diffraction (DXRD) has been to used to identify and quantify the solid state reactions that take place between sodium nickel ferrocyanide, Na{sub 2}NiFe(CN){sub 6}, and equimolar concentrations of sodium nitrate/nitrite, reactions of interest to the continued environmental safety of several large underground waste storage tanks at the Hanford site in eastern Washington. The results are supportive of previous work, which indicated that endothermic dehydration and melting of the nitrates take place before the occurrence of exothermic reactions that being about 300{degrees}C. The DXRD results show that a major reaction set at these temperatures is the occurrence of a series reaction that produces sodium cyanate, NaCNO, as an intermediate in a mildly exothermic first step. In the presence of gaseous oxygen, NaCNO subsequently reacts exothermally and at a faster rate to form metal oxides. Measurements of the rate of this reaction are used to estimate the heat release. Comparisons of this estimated heat release rate with heat transfer rates from a hypothetical ``hot spot`` show that, even in a worst-case scenario, the heat transfer rates are approximately eight times higher than the rate of energy release from the exothermic reactions.

  19. Advanced Thermal Storage for Central Receivers with Supercritical Coolants

    SciTech Connect (OSTI)

    Kelly, Bruce D.

    2010-06-15

    The principal objective of the study is to determine if supercritical heat transport fluids in a central receiver power plant, in combination with ceramic thermocline storage systems, offer a reduction in levelized energy cost over a baseline nitrate salt concept. The baseline concept uses a nitrate salt receiver, two-tank (hot and cold) nitrate salt thermal storage, and a subcritical Rankine cycle. A total of 6 plant designs were analyzed, as follows: Plant Designation Receiver Fluid Thermal Storage Rankine Cycle Subcritical nitrate salt Nitrate salt Two tank nitrate salt Subcritical Supercritical nitrate salt Nitrate salt Two tank nitrate salt Supercritical Low temperature H2O Supercritical H2O Two tank nitrate salt Supercritical High temperature H2O Supercritical H2O Packed bed thermocline Supercritical Low temperature CO2 Supercritical CO2 Two tank nitrate salt Supercritical High temperature CO2 Supercritical CO2 Packed bed thermocline Supercritical Several conclusions have been drawn from the results of the study, as follows: 1) The use of supercritical H2O as the heat transport fluid in a packed bed thermocline is likely not a practical approach. The specific heat of the fluid is a strong function of the temperatures at values near 400 C, and the temperature profile in the bed during a charging cycle is markedly different than the profile during a discharging cycle. 2) The use of supercritical CO2 as the heat transport fluid in a packed bed thermocline is judged to be technically feasible. Nonetheless, the high operating pressures for the supercritical fluid require the use of pressure vessels to contain the storage inventory. The unit cost of the two-tank nitrate salt system is approximately $24/kWht, while the unit cost of the high pressure thermocline system is nominally 10 times as high. 3) For the supercritical fluids, the outer crown temperatures of the receiver tubes are in the range of 700 to 800 C. At temperatures of 700 C and above, intermetallic compounds can precipitate between, and within, the grains of nickel alloys. The precipitation leads to an increase in tensile strength, and a decrease in ductility. Whether the proposed tube materials can provide the required low cycle fatigue life for the supercritical H2O and CO2 receivers is an open question. 4) A ranking of the plants, in descending order of technical and economic feasibility, is as follows: i) Supercritical nitrate salt and baseline nitrate salt: equal ratings ii) Low temperature supercritical H2O iii) Low temperature supercritical CO2 iv) High temperature supercritical CO2 v) High temperature supercritical H2O 5) The two-tank nitrate salt thermal storage systems are strongly preferred over the thermocline systems using supercritical heat transport fluids.

  20. BASIN ANALYSIS AND PETROLEUM SYSTEM CHARACTERIZATION AND MODELING, INTERIOR SALT BASINS, CENTRAL AND EASTERN GULF OF MEXICO

    SciTech Connect (OSTI)

    Ernest A. Mancini; Donald A. Goddard; Ronald K. Zimmerman

    2005-05-10

    The principal research effort for Year 2 of the project has been data compilation and the determination of the burial and thermal maturation histories of the North Louisiana Salt Basin and basin modeling and petroleum system identification. In the first nine (9) months of Year 2, the research focus was on the determination of the burial and thermal maturation histories, and during the remainder of the year the emphasis has basin modeling and petroleum system identification. Existing information on the North Louisiana Salt Basin has been evaluated, an electronic database has been developed, regional cross sections have been prepared, structure and isopach maps have been constructed, and burial history, thermal maturation history and hydrocarbon expulsion profiles have been prepared. Seismic data, cross sections, subsurface maps and related profiles have been used in evaluating the tectonic, depositional, burial and thermal maturation histories of the basin. Oil and gas reservoirs have been found to be associated with salt-supported anticlinal and domal features (salt pillows, turtle structures and piercement domes); with normal faulting associated with the northern basin margin and listric down-to-the-basin faults (state-line fault complex) and faulted salt features; and with combination structural and stratigraphic features (Sabine and Monroe Uplifts) and monoclinal features with lithologic variations. Petroleum reservoirs are mainly Upper Jurassic and Lower Cretaceous fluvial-deltaic sandstone facies and Lower Cretaceous and Upper Cretaceous shoreline, marine bar and shallow shelf sandstone facies. Cretaceous unconformities significantly contribute to the hydrocarbon trapping mechanism capacity in the North Louisiana Salt Basin. The chief petroleum source rock in this basin is Upper Jurassic Smackover lime mudstone beds. The generation of hydrocarbons from Smackover lime mudstone was initiated during the Early Cretaceous and continued into the Tertiary. Hydrocarbon expulsion commenced during the Early Cretaceous and continued into the Tertiary with peak expulsion occurring mainly during the Late Cretaceous.

  1. Batteries using molten salt electrolyte

    DOE Patents [OSTI]

    Guidotti, Ronald A. (Albuquerque, NM)

    2003-04-08

    An electrolyte system suitable for a molten salt electrolyte battery is described where the electrolyte system is a molten nitrate compound, an organic compound containing dissolved lithium salts, or a 1-ethyl-3-methlyimidazolium salt with a melting temperature between approximately room temperature and approximately 250.degree. C. With a compatible anode and cathode, the electrolyte system is utilized in a battery as a power source suitable for oil/gas borehole applications and in heat sensors.

  2. Central Characterization Program (CCP) TRU Nonconforming Item...

    Office of Environmental Management (EM)

    More Documents & Publications Results of Oxidizing Solids Testing Underground Flow Measurement and Particle Release Test Nitrate Salt Bearing Transuranic Waste Container Monitoring...

  3. Electrochemical cell having an alkali-metal-nitrate electrode

    DOE Patents [OSTI]

    Roche, M.F.; Preto, S.K.

    1982-06-04

    A power-producing secondary electrochemical cell includes a molten alkali metal as the negative-electrode material and a molten-nitrate salt as the positive-electrode material. The molten material in the respective electrodes are separated by a solid barrier of alkali-metal-ion conducting material. A typical cell includes active materials of molten sodium separated from molten sodium nitrate and other nitrates in mixture by a layer of sodium ..beta..'' alumina.

  4. Status of the direct absorption receiver panel research experiment: Salt flow and solar test requirements and plans

    SciTech Connect (OSTI)

    Tyner, C.E.

    1989-03-01

    The Panel Research Experiment (PRE) is the first large-scale solar test of the molten nitrate salt direct absorption receiver (DAR) concept. The purpose of the PRE is to demonstrate the engineering feasibility and practicality of the DAR. We will conduct the test at the Central Receiver Test Facility in Albuquerque in two phases: salt flow testing and solar testing. This is a working document to define PRE test objectives and requirements, document the test hardware design, and define test plans. 13 refs., 12 figs., 1 tab.

  5. Alkali metal nitrate purification

    DOE Patents [OSTI]

    Fiorucci, Louis C. (Hamden, CT); Morgan, Michael J. (Guilford, CT)

    1986-02-04

    A process is disclosed for removing contaminants from impure alkali metal nitrates containing them. The process comprises heating the impure alkali metal nitrates in solution form or molten form at a temperature and for a time sufficient to effect precipitation of solid impurities and separating the solid impurities from the resulting purified alkali metal nitrates. The resulting purified alkali metal nitrates in solution form may be heated to evaporate water therefrom to produce purified molten alkali metal nitrates suitable for use as a heat transfer medium. If desired, the purified molten form may be granulated and cooled to form discrete solid particles of purified alkali metal nitrates.

  6. Molten Salt Test Loop (MSTL) system customer interface document.

    SciTech Connect (OSTI)

    Gill, David Dennis; Kolb, William J.; Briggs, Ronald D.

    2013-09-01

    The National Solar Thermal Test Facility at Sandia National Laboratories has a unique test capability called the Molten Salt Test Loop (MSTL) system. MSTL is a test capability that allows customers and researchers to test components in flowing, molten nitrate salt. The components tested can range from materials samples, to individual components such as flex hoses, ball joints, and valves, up to full solar collecting systems such as central receiver panels, parabolic troughs, or linear Fresnel systems. MSTL provides realistic conditions similar to a portion of a concentrating solar power facility. The facility currently uses 60/40 nitrate %E2%80%9Csolar salt%E2%80%9D and can circulate the salt at pressure up to 40 bar (600psi), temperature to 585%C2%B0C, and flow rate of 44-50kg/s(400-600GPM) depending on temperature. The purpose of this document is to provide a basis for customers to evaluate the applicability to their testing needs, and to provide an outline of expectations for conducting testing on MSTL. The document can serve as the basis for testing agreements including Work for Others (WFO) and Cooperative Research and Development Agreements (CRADA). While this document provides the basis for these agreements and describes some of the requirements for testing using MSTL and on the site at Sandia, the document is not sufficient by itself as a test agreement. The document, however, does provide customers with a uniform set of information to begin the test planning process.

  7. Season and diurnal variations of peroxyacetyl nitrate (PAN) in a suburban area of central Italy and their relation with the meteorological conditions and the concentration of other photochemical oxidants and their precursors

    SciTech Connect (OSTI)

    Ciccioli, P.; Cecinato, A.; Brancaleoni, E.; Brachetti, A. )

    1988-09-01

    Peroxyacetyl nitrate (PAN), is a photochemical oxidant formed in the atmosphere when large amounts of hydrocarbons (HC) and NO{sub x} are emitted in air and exposed to the UV radiation coming from the sun. Its formation proceeds through the conversion of HC, mainly olefins, into aldehydes that, after oxidation into peroxyradicals, react with NO{sub 2} to give this gaseous pollutant. Although the amount of PAN in air represents a suitable index for measuring photochemical smog and photochemical episodes can easily be observed in many Italian cities, almost no data have been collected in their country. In this paper the authors present the results obtained during a two years monitoring campaign carried in a suburban area of Central Italy placed downwind to Rome. Seasonal and daily trends of PAN will be reported together with the meteorological parameters and the change in concentration of other photochemical oxidants (ozone), its precursors (HC and aldehydes) and some acidic species. The results indicate that PAN, formed within the city, is transported into site together with other oxidants.

  8. Customer interface document for the Molten Salt Test Loop (MSTL) system.

    SciTech Connect (OSTI)

    Pettit, Kathleen; Kolb, William J.; Gill, David Dennis; Briggs, Ronald D.

    2012-03-01

    The National Solar Thermal Test Facility at Sandia National Laboratories has a unique test capability called the Molten Salt Test Loop (MSTL) system. MSTL is a test capability that allows customers and researchers to test components in flowing, molten nitrate salt. The components tested can range from materials samples, to individual components such as flex hoses, ball joints, and valves, up to full solar collecting systems such as central receiver panels, parabolic troughs, or linear Fresnel systems. MSTL provides realistic conditions similar to a portion of a concentrating solar power facility. The facility currently uses 60/40 nitrate 'solar salt' and can circulate the salt at pressure up to 600psi, temperature to 585 C, and flow rate of 400-600GPM depending on temperature. The purpose of this document is to provide a basis for customers to evaluate the applicability to their testing needs, and to provide an outline of expectations for conducting testing on MSTL. The document can serve as the basis for testing agreements including Work for Others (WFO) and Cooperative Research and Development Agreements (CRADA). While this document provides the basis for these agreements and describes some of the requirements for testing using MSTL and on the site at Sandia, the document is not sufficient by itself as a test agreement. The document, however, does provide customers with a uniform set of information to begin the test planning process.

  9. Nonaqueous purification of mixed nitrate heat transfer media

    DOE Patents [OSTI]

    Fiorucci, Louis C.; Morgan, Michael J.

    1983-12-20

    A nonaqueous, in-line method for removing carbonate and hydroxide contamination from a molten mixed sodium nitrate/potassium nitrate heat transfer salt. The method comprises dissolving a stoichiometric quantity of anhydrous Ca(NO.sub.3).sub.2 in the melt whereby an insoluble CaCO.sub.3 and Ca(OH).sub.2 precipitate is formed. The precipitate can be removed by settling, filtration or floatation techniques.

  10. Ethylenediamine salt of 5-nitrotetrazole and preparation

    DOE Patents [OSTI]

    Lee, Kien-yin (Los Alamos, NM); Coburn, Michael D. (Los Alamos, NM)

    1985-01-01

    Ethylenediamine salt of 5-nitrotetrazole and preparation. This salt has been found to be useful as an explosive alone and in eutectic mixtures with ammonium nitrate and/or other explosive compounds. Its eutectic with ammonium nitrate has been demonstrated to behave in a similar manner to a monomolecular explosive such as TNT, and is less sensitive than the pure salt. Moreover, this eutectic mixture, which contains 87.8 mol % of ammonium nitrate, is close to the CO.sub.2 -balanced composition of 90 mol %, and has a relatively low melting point of 110.5 C. making it readily castable. The ternary eutectic system containing the ethylenediamine salt of 5-nitrotetrazole, ammonium nitrate and ethylenediamine dinitrate has a eutectic temperature of 89.5 C. and gives a measured detonation pressure of 24.8 GPa, which is 97.6% of the calculated value. Both the pure ethylenediamine salt and its known eutectic compounds behave in substantially ideal manner. Methods for the preparation of the salt are described.

  11. Molten salt lithium cells

    DOE Patents [OSTI]

    Raistrick, Ian D. (Menlo Park, CA); Poris, Jaime (Portola Valley, CA); Huggins, Robert A. (Stanford, CA)

    1983-01-01

    Lithium-based cells are promising for applications such as electric vehicles and load-leveling for power plants since lithium is very electropositive and light weight. One type of lithium-based cell utilizes a molten salt electrolyte and is operated in the temperature range of about 400.degree.-500.degree. C. Such high temperature operation accelerates corrosion problems and a substantial amount of energy is lost through heat transfer. The present invention provides an electrochemical cell (10) which may be operated at temperatures between about 100.degree.-170.degree. C. Cell (10) comprises an electrolyte (16), which preferably includes lithium nitrate, and a lithium or lithium alloy electrode (12).

  12. Molten salt lithium cells

    DOE Patents [OSTI]

    Raistrick, Ian D. (Menlo Park, CA); Poris, Jaime (Portola Valley, CA); Huggins, Robert A. (Stanford, CA)

    1982-02-09

    Lithium-based cells are promising for applications such as electric vehicles and load-leveling for power plants since lithium is very electropositive and light weight. One type of lithium-based cell utilizes a molten salt electrolyte and is operated in the temperature range of about 400.degree.-500.degree. C. Such high temperature operation accelerates corrosion problems and a substantial amount of energy is lost through heat transfer. The present invention provides an electrochemical cell (10) which may be operated at temperatures between about 100.degree.-170.degree. C. Cell (10) comprises an electrolyte (16), which preferably includes lithium nitrate, and a lithium or lithium alloy electrode (12).

  13. Molten salt lithium cells

    DOE Patents [OSTI]

    Raistrick, I.D.; Poris, J.; Huggins, R.A.

    1980-07-18

    Lithium-based cells are promising for applications such as electric vehicles and load-leveling for power plants since lithium is very electropositive and light weight. One type of lithium-based cell utilizes a molten salt electrolyte and is operated in the temperature range of about 400 to 500/sup 0/C. Such high temperature operation accelerates corrosion problems and a substantial amount of energy is lost through heat transfer. The present invention provides an electrochemical cell which may be operated at temperatures between about 100 to 170/sup 0/C. The cell is comprised of an electrolyte, which preferably includes lithium nitrate, and a lithium or lithium alloy electrode.

  14. Thermochemical nitrate destruction

    DOE Patents [OSTI]

    Cox, John L. (Richland, WA); Hallen, Richard T. (Richland, WA); Lilga, Michael A. (Richland, WA)

    1992-01-01

    A method is disclosed for denitrification of nitrates and nitrates present in aqueous waste streams. The method comprises the steps of (1) identifying the concentration nitrates and nitrites present in a waste stream, (2) causing formate to be present in the waste stream, (3) heating the mixture to a predetermined reaction temperature from about 200.degree. C. to about 600.degree. C., and (4) holding the mixture and accumulating products at heated and pressurized conditions for a residence time, thereby resulting in nitrogen and carbon dioxide gas, and hydroxides, and reducing the level of nitrates and nitrites to below drinking water standards.

  15. EMRTC Report RF 10-13: Application to LANL Evaporator Nitrate...

    Office of Environmental Management (EM)

    and recommendation. Conclusions: 1. Nitrate salts not yet remediated having no free liquid should be mixed with at least 1.2 volumes of Kitty LitterZeolite clay per...

  16. Ethylenediamine salt of 5-nitrotetrazole and preparation

    DOE Patents [OSTI]

    Lee, K.; Coburn, M.D.

    1984-05-17

    The ethylenediamine salt of 5-nitrotetrazole has been found to be useful as an explosive alone and in eutectic mixtures with ammonium nitrate and/or other explosive compounds. Its eutectic with ammonium nitrate has been demonstrated to behave in a similar manner to a monomolecular explosive such as TNT, and is less sensitive than the pure salt. Moreover, this eutectic mixture, which contains 87.8 mol% of ammonium nitrate, is close to the CO/sub 2/-balanced composition of 90 mol%, and has a relatively low melting point of 110.5 C making it readily castable. The ternary eutectic system containing the ethylenediamine salt of 5-nitrotetrazole, ammonium nitrate and ethylenediamine dinitrate has a eutectic temperature of 89.5 C and gives a measured detonation pressure of 24.8 GPa, which is 97.6% of the calculated value. Both the pure ethylenediamine salt and its known eutectic compounds behave in substantially ideal manner. Methods for the preparation of the salt are described.

  17. Thermochemical nitrate destruction

    DOE Patents [OSTI]

    Cox, J.L.; Hallen, R.T.; Lilga, M.A.

    1992-06-02

    A method is disclosed for denitrification of nitrates and nitrites present in aqueous waste streams. The method comprises the steps of (1) identifying the concentration nitrates and nitrites present in a waste stream, (2) causing formate to be present in the waste stream, (3) heating the mixture to a predetermined reaction temperature from about 200 C to about 600 C, and (4) holding the mixture and accumulating products at heated and pressurized conditions for a residence time, thereby resulting in nitrogen and carbon dioxide gas, and hydroxides, and reducing the level of nitrates and nitrites to below drinking water standards.

  18. Sandia Energy - Molten Salt Test Loop Melted Salt

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Salt Home Renewable Energy Energy News Concentrating Solar Power Solar Molten Salt Test Loop Melted Salt Previous Next Molten Salt Test Loop Melted Salt The Molten Salt Test...

  19. NITRATE DESTRUCTION LITERATURE SURVEY AND EVALUATION CRITERIA

    SciTech Connect (OSTI)

    Steimke, J.

    2011-02-01

    This report satisfies the initial phase of Task WP-2.3.4 Alternative Sodium Recovery Technology, Subtask 1; Develop Near-Tank Nitrate/Nitrite Destruction Technology. Some of the more common anions in carbon steel waste tanks at SRS and Hanford Site are nitrate which is corrosive, and nitrite and hydroxide which are corrosion inhibitors. At present it is necessary to periodically add large quantities of 50 wt% caustic to waste tanks. There are three primary reasons for this addition. First, when the contents of salt tanks are dissolved, sodium hydroxide preferentially dissolves and is removed. During the dissolution process the concentration of free hydroxide in the tank liquid can decrease from 9 M to less than 0.2 M. As a result, roughly half way through the dissolution process large quantities of sodium hydroxide must be added to the tank to comply with requirements for corrosion control. Second, hydroxide is continuously consumed by reaction with carbon dioxide which occurs naturally in purge air used to prevent buildup of hydrogen gas inside the tanks. The hydrogen is generated by radiolysis of water. Third, increasing the concentration of hydroxide increases solubility of some aluminum compounds, which is desirable in processing waste. A process that converts nitrate and nitrite to hydroxide would reduce certain costs. (1) Less caustic would be purchased. (2) Some of the aluminum solid compounds in the waste tanks would become more soluble so less mass of solids would be sent to High Level Vitrification and therefore it would be not be necessary to make as much expensive high level vitrified product. (3) Less mass of sodium would be fed to Saltstone at SRS or Low Level Vitrification at Hanford Site so it would not be necessary to make as much low level product. (4) At SRS less nitrite and nitrate would be sent to Defense Waste Processing Facility (DWPF) so less formic acid would be consumed there and less hydrogen gas would be generated. This task involves literature survey of technologies to perform the nitrate to hydroxide conversion, selection of the most promising technologies, preparation of a flowsheet and design of a system. The most promising technologies are electrochemical reduction of nitrates and chemical reduction with hydrogen or ammonia. The primary reviewed technologies are listed and they aredescribed in more detail later in the report: (1) Electrochemical destruction; (2) Chemical reduction with agents such as ammonia, hydrazine or hydrogen; (3) Hydrothermal reduction process; and (4) Calcination. Only three of the technologies on the list have been demonstrated to generate usable amounts of caustic; electrochemical reduction and chemical reduction with ammonia, hydrazine or hydrogen and hydrothermal reduction. Chemical reduction with an organic reactant such as formic acid generates carbon dioxide which reacts with caustic and is thus counterproductive. Treatment of nitrate with aluminum or other active metals generates a solid product. High temperature calcination has the potential to generate sodium oxide which may be hydrated to sodium hydroxide, but this is unproven. The following criteria were developed to evaluate the most suitable option. The numbers in brackets after the criteria are relative weighting factors to account for importance: (1) Personnel exposure to radiation for installation, routine operation and maintenance; (2) Non-radioactive safety issues; (3) Whether the technology generates caustic and how many moles of caustic are generated per mole of nitrate plus nitrite decomposed; (4) Whether the technology can handle nitrate and nitrite at the concentrations encountered in waste; (5) Maturity of technology; (6) Estimated annual cost of operation (labor, depreciation, materials, utilities); (7) Capital cost; (8) Selectivity to nitrogen as decomposition product (other products are flammable and/or toxic); (9) Impact of introduced species; (10) Selectivity for destruction of nitrate vs. nitrite; and (11) Cost of deactivation and demolition. Each technology was given a score from one

  20. Purification of alkali metal nitrates

    DOE Patents [OSTI]

    Fiorucci, Louis C. (Hamden, CT); Gregory, Kevin M. (Woodridge, IL)

    1985-05-14

    A process is disclosed for removing heavy metal contaminants from impure alkali metal nitrates containing them. The process comprises mixing the impure nitrates with sufficient water to form a concentrated aqueous solution of the impure nitrates, adjusting the pH of the resulting solution to within the range of between about 2 and about 7, adding sufficient reducing agent to react with heavy metal contaminants within said solution, adjusting the pH of the solution containing reducing agent to effect precipitation of heavy metal impurities and separating the solid impurities from the resulting purified aqueous solution of alkali metal nitrates. The resulting purified solution of alkali metal nitrates may be heated to evaporate water therefrom to produce purified molten alkali metal nitrate suitable for use as a heat transfer medium. If desired, the purified molten form may be granulated and cooled to form discrete solid particles of alkali metal nitrates.

  1. THERMODYNAMIC PROPERTIES OF MOLTEN NITRATE SALTS Joseph G. Cordaro

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the world as heat transfer fluids and phase change materials for concentrated solar power (CSP) production and storage. In order to design large production facilities,...

  2. Waste Isolation Pilot Plant Nitrate Salt Bearing Waste Container

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... bulkheads to the underground. The waist hoist equipment is currently undergoing cleaning (to remove soot from the February 5, 2014, fire) and inspections to ensure operability. ...

  3. WIPP Nitrate Salt Bearing Waste Container Isolation Plan Implementatio...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Waste Container Isolation Plan Implementation Update May 12, 2015 Panel 6 and Panel 7, Room 7 a. Rollback * Contamination Assessment-This prerequisite is complete and therefore...

  4. Stainless steel corrosion by molten nitrates : analysis and lessons learned.

    SciTech Connect (OSTI)

    Kruizenga, Alan Michael

    2011-09-01

    A secondary containment vessel, made of stainless 316, failed due to severe nitrate salt corrosion. Corrosion was in the form of pitting was observed during high temperature, chemical stability experiments. Optical microscopy, scanning electron microscopy and energy dispersive spectroscopy were all used to diagnose the cause of the failure. Failure was caused by potassium oxide that crept into the gap between the primary vessel (alumina) and the stainless steel vessel. Molten nitrate solar salt (89% KNO{sub 3}, 11% NaNO{sub 3} by weight) was used during chemical stability experiments, with an oxygen cover gas, at a salt temperature of 350-700 C. Nitrate salt was primarily contained in an alumina vessel; however salt crept into the gap between the alumina and 316 stainless steel. Corrosion occurred over a period of approximately 2000 hours, with the end result of full wall penetration through the stainless steel vessel; see Figures 1 and 2 for images of the corrosion damage to the vessel. Wall thickness was 0.0625 inches, which, based on previous data, should have been adequate to avoid corrosion-induced failure while in direct contact with salt temperature at 677 C (0.081-inch/year). Salt temperatures exceeding 650 C lasted for approximately 14 days. However, previous corrosion data was performed with air as the cover gas. High temperature combined with an oxygen cover gas obviously drove corrosion rates to a much higher value. Corrosion resulted in the form of uniform pitting. Based on SEM and EDS data, pits contained primarily potassium oxide and potassium chromate, reinforcing the link between oxides and severe corrosion. In addition to the pitting corrosion, a large blister formed on the side wall, which was mainly composed of potassium, chromium and oxygen. All data indicated that corrosion initiated internally and moved outward. There was no evidence of intergranular corrosion nor were there any indication of fast pathways along grain boundaries. Much of the pitting occurred near welds; however this was the hottest region in the chamber. Pitting was observed up to two inches above the weld, indicating independence from weld effects.

  5. Salt Selected (FINAL)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    * Salt is relatively easy to mine. * Rock salt heals its own fractures because of its plastic quality. That is, salt formations will slowly and progressively move in to fill...

  6. Salt Waste Processing Initiatives

    Office of Environmental Management (EM)

    Patricia Suggs Salt Processing Team Lead Assistant Manager for Waste Disposition Project Office of Environmental Management Savannah River Site Salt Waste Processing Initiatives 2 ...

  7. Plutonium nitrate bottle counter manual

    SciTech Connect (OSTI)

    Menlove, H.O.; Adams, E.L.; Holbrooks, O.R.

    1984-03-01

    A neutron coincidence counter has been designed for plutonium nitrate assay in large storage bottles. This assay system can be used in the reprocessing plant or in the nitrate-to-oxide conversion facility. The system is based on the family of neutron detectors similar to the high-level neutron coincidence counter. This manual describes the system and gives performance and calibration parameters for typical applications. 4 references, 11 figures, 9 tables.

  8. Electrolyte salts for power sources

    DOE Patents [OSTI]

    Doddapaneni, Narayan (10516 Royal Birkdale, NE., Albuquerque, NM 87111); Ingersoll, David (5824 Mimosa Pl., NE., Albuquerque, NM 87111)

    1995-01-01

    Electrolyte salts for power sources comprising salts of phenyl polysulfonic acids and phenyl polyphosphonic acids. The preferred salts are alkali and alkaline earth metal salts, most preferably lithium salts.

  9. Slime-busting Salt

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    past issues All Issues submit Slime-busting Salt A potential new treatment gets bacteria deep in their hiding places May 1, 2015 Slime-busting Salt Biofilms are made of...

  10. Process for reducing aqueous nitrate to ammonia

    DOE Patents [OSTI]

    Mattus, Alfred J. (Oak Ridge, TN)

    1993-01-01

    Powdered aluminum is added to a nitrate-containing alkaline, aqueous solution to reduce the nitrate and/or nitrite to ammonia and co-produce a sinterable ceramic product.

  11. Process for reducing aqueous nitrate to ammonia

    DOE Patents [OSTI]

    Mattus, A.J.

    1993-11-30

    Powdered aluminum is added to a nitrate-containing alkaline, aqueous solution to reduce the nitrate and/or nitrite to ammonia and co-produce a sinterable ceramic product. 3 figures.

  12. Salt Waste Processing Initiatives

    Office of Environmental Management (EM)

    Patricia Suggs Salt Processing Team Lead Assistant Manager for Waste Disposition Project Office of Environmental Management Savannah River Site Salt Waste Processing Initiatives 2 Overview * Current SRS Liquid Waste System status * Opportunity to accelerate salt processing - transformational technologies - Rotary Microfiltration (RMF) and Small Column Ion Exchange (SCIX) - Actinide Removal Process/Modular Caustic Side Solvent Extraction (ARP/MCU) extension with next generation extractant - Salt

  13. Ancient Salt Beds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Ancient Salt Beds Dr. Jack Griffith The key to the search for life on other planets may go through WIPP's ancient salt beds. In 2008, a team of scientists led by Jack Griffith, from the University of North Carolina, Chapel Hill, retrieved salt samples from the WIPP underground and studied them with a transmission electron microscopy lab at the Lineberger Comprehensive Cancer Center of the University of North Carolina School of Medicine. In examining fluid inclusions in the salt and solid halite

  14. Aksaray And Ecemis Faults - Diapiric Salt Relationships- Relevance...

    Open Energy Info (EERE)

    To The Hydrocarbon Exploration In The Tuz Golu (Salt Lake) Basin, Central Anatolia, Turkey Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article:...

  15. Dosimetry using silver salts

    DOE Patents [OSTI]

    Warner, Benjamin P.

    2003-06-24

    The present invention provides a method for detecting ionizing radiation. Exposure of silver salt AgX to ionizing radiation results in the partial reduction of the salt to a mixture of silver salt and silver metal. The mixture is further reduced by a reducing agent, which causes the production of acid (HX) and the oxidized form of the reducing agent (R). Detection of HX indicates that the silver salt has been exposed to ionizing radiation. The oxidized form of the reducing agent (R) may also be detected. The invention also includes dosimeters employing the above method for detecting ionizing radiation.

  16. Hydroxycarboxylic acids and salts

    DOE Patents [OSTI]

    Kiely, Donald E; Hash, Kirk R; Kramer-Presta, Kylie; Smith, Tyler N

    2015-02-24

    Compositions which inhibit corrosion and alter the physical properties of concrete (admixtures) are prepared from salt mixtures of hydroxycarboxylic acids, carboxylic acids, and nitric acid. The salt mixtures are prepared by neutralizing acid product mixtures from the oxidation of polyols using nitric acid and oxygen as the oxidizing agents. Nitric acid is removed from the hydroxycarboxylic acids by evaporation and diffusion dialysis.

  17. Molten salt electrolyte separator

    DOE Patents [OSTI]

    Kaun, T.D.

    1996-07-09

    The patent describes a molten salt electrolyte/separator for battery and related electrochemical systems including a molten electrolyte composition and an electrically insulating solid salt dispersed therein, to provide improved performance at higher current densities and alternate designs through ease of fabrication. 5 figs.

  18. Water purification using organic salts

    DOE Patents [OSTI]

    Currier, Robert P.

    2004-11-23

    Water purification using organic salts. Feed water is mixed with at least one organic salt at a temperature sufficiently low to form organic salt hydrate crystals and brine. The crystals are separated from the brine, rinsed, and melted to form an aqueous solution of organic salt. Some of the water is removed from the aqueous organic salt solution. The purified water is collected, and the remaining more concentrated aqueous organic salt solution is reused.

  19. Process for converting sodium nitrate-containing, caustic liquid radioactive wastes to solid insoluble products

    DOE Patents [OSTI]

    Barney, Gary S.; Brownell, Lloyd E.

    1977-01-01

    A method for converting sodium nitrate-containing, caustic, radioactive wastes to a solid, relatively insoluble, thermally stable form is provided and comprises the steps of reacting powdered aluminum silicate clay, e.g., kaolin, bentonite, dickite, halloysite, pyrophyllite, etc., with the sodium nitrate-containing radioactive wastes which have a caustic concentration of about 3 to 7 M at a temperature of 30.degree. C to 100.degree. C to thereby entrap the dissolved radioactive salts in the aluminosilicate matrix. In one embodiment the sodium nitrate-containing, caustic, radioactive liquid waste, such as neutralized Purex-type waste, or salts or oxide produced by evaporation or calcination of these liquid wastes (e.g., anhydrous salt cake) is converted at a temperature within the range of 30.degree. C to 100.degree. C to the solid mineral form-cancrinite having an approximate chemical formula 2(NaAlSiO.sub.4) .sup.. xSalt.sup.. y H.sub.2 O with x = 0.52 and y = 0.68 when the entrapped salt is NaNO.sub.3. In another embodiment the sodium nitrate-containing, caustic, radioactive liquid is reacted with the powdered aluminum silicate clay at a temperature within the range of 30.degree. C to 100.degree. C, the resulting reaction product is air dried eitheras loose powder or molded shapes (e.g., bricks) and then fired at a temperature of at least 600.degree. C to form the solid mineral form-nepheline which has the approximate chemical formula of NaAlSiO.sub.4. The leach rate of the entrapped radioactive salts with distilled water is reduced essentially to that of the aluminosilicate lattice which is very low, e.g., in the range of 10.sup.-.sup.2 to 10.sup.-.sup.4 g/cm.sup.2 -- day for cancrinite and 10.sup.-.sup.3 to 10.sup.-.sup.5 g/cm.sup.2 -- day for nepheline.

  20. Salt Repository Research,

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of Downtown Santa Fe. Begins 10 AM. Map will be provided Day 2 September 9 - Tuesday TM-behavior of salt 08:30-08:50 Update on the "Joint Project on Constitutive Laws benchmark"...

  1. Amine salts of nitroazoles

    DOE Patents [OSTI]

    Kienyin Lee; Stinecipher, M.M.

    1993-10-26

    Compositions of matter, a method of providing chemical energy by burning said compositions, and methods of making said compositions are described. These compositions are amine salts of nitroazoles. 1 figure.

  2. CRITICALITY SAFETY OF PROCESSING SALT SOLUTION AT SRS

    SciTech Connect (OSTI)

    Stephens, K; Davoud Eghbali, D; Michelle Abney, M

    2008-01-15

    High level radioactive liquid waste generated as a result of the production of nuclear material for the United States defense program at the Savannah River Site has been stored as 36 million gallons in underground tanks. About ten percent of the waste volume is sludge, composed of insoluble metal hydroxides primarily hydroxides of Mn, Fe, Al, Hg, and most radionuclides including fission products. The remaining ninety percent of the waste volume is saltcake, composed of primarily sodium (nitrites, nitrates, and aluminates) and hydroxides. Saltcakes account for 30% of the radioactivity while the sludge accounts for 70% of the radioactivity. A pilot plant salt disposition processing system has been designed at the Savannah River Site for interim processing of salt solution and is composed of two facilities: the Actinide Removal Process Facility (ARPF) and the Modular Caustic Side Solvent Extraction Unit (MCU). Data from the pilot plant salt processing system will be used for future processing salt at a much higher rate in a new salt processing facility. Saltcake contains significant amounts of actinides, and other long-lived radioactive nuclides such as strontium and cesium that must be extracted prior to disposal as low level waste. The extracted radioactive nuclides will be mixed with the sludge from waste tanks and vitrified in another facility. Because of the presence of highly enriched uranium in the saltcake, there is a criticality concern associated with concentration and/or accumulation of fissionable material in the ARP and MCU.

  3. Fundamental Properties of Salts

    SciTech Connect (OSTI)

    Toni Y Gutknecht; Guy L Fredrickson

    2012-11-01

    Thermal properties of molten salt systems are of interest to electrorefining operations, pertaining to both the Fuel Cycle Research & Development Program (FCR&D) and Spent Fuel Treatment Mission, currently being pursued by the Department of Energy (DOE). The phase stability of molten salts in an electrorefiner may be adversely impacted by the build-up of fission products in the electrolyte. Potential situations that need to be avoided, during electrorefining operations, include (i) fissile elements build up in the salt that might approach the criticality limits specified for the vessel, (ii) electrolyte freezing at the operating temperature of the electrorefiner due to changes in the liquidus temperature, and (iii) phase separation (non-homogenous solution). The stability (and homogeneity) of the phases can be monitored by studying the thermal characteristics of the molten salts as a function of impurity concentration. Simulated salt compositions consisting of the selected rare earth and alkaline earth chlorides, with a eutectic mixture of LiCl-KCl as the carrier electrolyte, were studied to determine the melting points (thermal characteristics) using a Differential Scanning Calorimeter (DSC). The experimental data were used to model the liquidus temperature. On the basis of the this data, it became possible to predict a spent fuel treatment processing scenario under which electrorefining could no longer be performed as a result of increasing liquidus temperatures of the electrolyte.

  4. Synthesis of a new energetic nitrate ester

    SciTech Connect (OSTI)

    Chavez, David E

    2008-01-01

    Nitrate esters have been known as useful energetic materials since the discovery of nitroglycerin by Ascanio Sobrero in 1846. The development of methods to increase the safety and utility of nitroglycerin by Alfred Nobel led to the revolutionary improvement in the utility of nitroglycerin in explosive applications in the form of dynamite. Since then, many nitrate esters have been prepared and incorporated into military applications such as double-based propellants, detonators and as energetic plasticizers. Nitrate esters have also been shown to have vasodilatory effects in humans and thus have been studied and used for treatments of ailments such as angina. The mechanism of the biological response towards nitrate esters has been elucidated recently. Interestingly, many of the nitrate esters used for military purposes are liquids (ethylene glycol dinitrate, propylene glycol dinitrate, etc). Pentaerythritol tetranitrate (PETN) is one of the only solid nitrate esters, besides nitrocellulose, that is used in any application. Unfortunately, PETN melting point is above 100 {sup o}C, and thus must be pressed as a solid for detonator applications. A more practical material would be a melt-castable explosive, for potential simplification of manufacturing processes. Herein we describe the synthesis of a new energetic nitrate ester (1) that is a solid at ambient temperatures, has a melting point of 85-86 {sup o}C and has the highest density of any known nitrate ester composed only of carbon, hydrogen, nitrogen and oxygen. We also describe the chemical, thermal and sensitivity properties of 1 as well as some preliminary explosive performance data.

  5. Energetic Material - Electro Nitration - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Electro Nitration Idaho National Laboratory Contact INL About This Technology Technology Marketing SummaryINL has developed an improved method of nitrating a nitro compound by oxidizing a chemical mediator in the presence of a voltage in order to produce an oxidizing agent. Then, the agent reacts with a nitro compound and ion source in a solution in order to form a geminaldinitro compound. The electrochemical synthesis of geminaldinitro results in the formation of a nitro compound that may be

  6. Process for the preparation of an energetic nitrate ester

    DOE Patents [OSTI]

    Chavez, David E; Naud, Darren L; Hiskey, Michael A

    2013-12-17

    A process for the preparation of an energetic nitrate ester compound and related intermediates is provided.

  7. Process for decomposing nitrates in aqueous solution

    DOE Patents [OSTI]

    Haas, Paul A. (Knoxville, TN)

    1980-01-01

    This invention is a process for decomposing ammonium nitrate and/or selected metal nitrates in an aqueous solution at an elevated temperature and pressure. Where the compound to be decomposed is a metal nitrate (e.g., a nuclear-fuel metal nitrate), a hydroxylated organic reducing agent therefor is provided in the solution. In accordance with the invention, an effective proportion of both nitromethane and nitric acid is incorporated in the solution to accelerate decomposition of the ammonium nitrate and/or selected metal nitrate. As a result, decomposition can be effected at significantly lower temperatures and pressures, permitting the use of system components composed of off-the-shelf materials, such as stainless steel, rather than more costly materials of construction. Preferably, the process is conducted on a continuous basis. Fluid can be automatically vented from the reaction zone as required to maintain the operating temperature at a moderate value--e.g., at a value in the range of from about 130.degree.-200.degree. C.

  8. --No Title--

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in the salt. Pictures of samples before and after exposure are below. Concentrated Solar Power (CSP) currently uses sodium potassium binary nitrate salts in central tower...

  9. Gas releases from salt

    SciTech Connect (OSTI)

    Ehgartner, B.; Neal, J.; Hinkebein, T.

    1998-06-01

    The occurrence of gas in salt mines and caverns has presented some serious problems to facility operators. Salt mines have long experienced sudden, usually unexpected expulsions of gas and salt from a production face, commonly known as outbursts. Outbursts can release over one million cubic feet of methane and fractured salt, and are responsible for the lives of numerous miners and explosions. Equipment, production time, and even entire mines have been lost due to outbursts. An outburst creates a cornucopian shaped hole that can reach heights of several hundred feet. The potential occurrence of outbursts must be factored into mine design and mining methods. In caverns, the occurrence of outbursts and steady infiltration of gas into stored product can effect the quality of the product, particularly over the long-term, and in some cases renders the product unusable as is or difficult to transport. Gas has also been known to collect in the roof traps of caverns resulting in safety and operational concerns. The intent of this paper is to summarize the existing knowledge on gas releases from salt. The compiled information can provide a better understanding of the phenomena and gain insight into the causative mechanisms that, once established, can help mitigate the variety of problems associated with gas releases from salt. Outbursts, as documented in mines, are discussed first. This is followed by a discussion of the relatively slow gas infiltration into stored crude oil, as observed and modeled in the caverns of the US Strategic Petroleum Reserve. A model that predicts outburst pressure kicks in caverns is also discussed.

  10. Salt Repository Research,

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    th US/German Workshop on Salt Repository Research, Design, and Operation Hotel Pullman Dresden Newa September 7 - 9, 2015 September 7- Monday 08:00-08:30 Registration 08:30-08:50 Welcome by the organizers T. Lautsch, DBE F. Hansen, SNL W. Steininger, PTKA 08:50-09:15 Welcome by BMWi U. Borak, BMWi 09:15-09:30 Welcome by USDOE N. Buschman, US DOE 09:30-10:00 NEA Salt Club J. Mönig, GRS SAFETY CASE ISSUES 10:00-10:30 WIPP recovery F. Hansen, SNL 10:30-11:00 Coffee break and photo event

  11. Salt Wells Geothermal Area | Open Energy Information

    Open Energy Info (EERE)

    Salt Wells Geothermal Area Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Salt Wells Geothermal Area Contents 1 Area Overview 2 History and Infrastructure 2.1 Salt...

  12. Sandia Energy - Molten Salt Test Loop Commissioning

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Energy News EC News & Events Concentrating Solar Power Solar Molten Salt Test Loop Commissioning Previous Next Molten Salt Test Loop Commissioning The Molten Salt...

  13. Actinide removal from spent salts

    DOE Patents [OSTI]

    Hsu, Peter C. (Pleasanton, CA); von Holtz, Erica H. (Livermore, CA); Hipple, David L. (Livermore, CA); Summers, Leslie J. (Livermore, CA); Adamson, Martyn G. (Danville, CA)

    2002-01-01

    A method for removing actinide contaminants (uranium and thorium) from the spent salt of a molten salt oxidation (MSO) reactor is described. Spent salt is removed from the reactor and analyzed to determine the contaminants present and the carbonate concentration. The salt is dissolved in water, and one or more reagents are added to precipitate the thorium as thorium oxide and/or the uranium as either uranium oxide or as a diuranate salt. The precipitated materials are filtered, dried and packaged for disposal as radioactive waste. About 90% of the thorium and/or uranium present is removed by filtration. After filtration, salt solutions having a carbonate concentration >20% can be dried and returned to the reactor for re-use. Salt solutions containing a carbonate concentration <20% require further clean-up using an ion exchange column, which yields salt solutions that contain less than 0.1 ppm of thorium or uranium.

  14. Metals removal from spent salts

    DOE Patents [OSTI]

    Hsu, Peter C. (Pleasanton, CA); Von Holtz, Erica H. (Livermore, CA); Hipple, David L. (Livermore, CA); Summers, Leslie J. (Livermore, CA); Brummond, William A. (Livermore, CA); Adamson, Martyn G. (Danville, CA)

    2002-01-01

    A method and apparatus for removing metal contaminants from the spent salt of a molten salt oxidation (MSO) reactor is described. Spent salt is removed from the reactor and analyzed to determine the contaminants present and the carbonate concentration. The salt is dissolved in water, and one or more reagents may be added to precipitate the metal oxide and/or the metal as either metal oxide, metal hydroxide, or as a salt. The precipitated materials are filtered, dried and packaged for disposal as waste or can be immobilized as ceramic pellets. More than about 90% of the metals and mineral residues (ashes) present are removed by filtration. After filtration, salt solutions having a carbonate concentration >20% can be spray-dried and returned to the reactor for re-use. Salt solutions containing a carbonate concentration <20% require further clean-up using an ion exchange column, which yields salt solutions that contain less than 1.0 ppm of contaminants.

  15. Engineering Database of Liquid Salt Thermophysical and Thermochemical Properties

    SciTech Connect (OSTI)

    Manohar S. Sohal; Matthias A. Ebner; Piyush Sabharwall; Phil Sharpe

    2010-03-01

    The purpose of this report is to provide a review of thermodynamic and thermophysical properties of candidate molten salt coolants, which may be used as a primary coolant within a nuclear reactor or heat transport medium from the Next Generation Nuclear Plant (NGNP) to a processing plant, for example, a hydrogen-production plant. Thermodynamic properties of four types of molten salts, including LiF-BeF2 (67 and 33 mol%, respectively; also known as FLiBe), LiF-NaF-KF (46.5, 11.5, and 52 mol%, also known as FLiNaK), and KCl-MgCl2 (67 and 33 mol%), and sodium nitrate-sodium nitrite-potassium nitrate (NaNO3NaNO2KNO3, (7-49-44 or 7-40-53 mol%) have been investigated. Limitations of existing correlations to predict density, viscosity, specific heat capacity, surface tension, and thermal conductivity, were identified. The impact of thermodynamic properties on the heat transfer, especially Nusselt number was also discussed. Stability of the molten salts with structural alloys and their compatibility with the structural alloys was studied. Nickel and alloys with dense Ni coatings are effectively inert to corrosion in fluorides but not so in chlorides. Of the chromium containing alloys, Hastelloy N appears to have the best corrosion resistance in fluorides, while Haynes 230 was most resistant in chloride. In general, alloys with increasing carbon and chromium content are increasingly subject to corrosion by the fluoride salts FLiBe and FLiNaK, due to attack and dissolution of the intergranular chromium carbide. Future research to obtain needed information was identified.

  16. Salt Lake City

    National Nuclear Security Administration (NNSA)

    perspective, this exercise allowed us to achieve a number of goals," said Central Region Director of Safety and Security Glen Buma. "We were able to evaluate the region's...

  17. Design considerations for concentrating solar power tower systems employing molten salt.

    SciTech Connect (OSTI)

    Moore, Robert Charles; Siegel, Nathan Phillip; Kolb, Gregory J.; Vernon, Milton E.; Ho, Clifford Kuofei

    2010-09-01

    The Solar Two Project was a United States Department of Energy sponsored project operated from 1996 to 1999 to demonstrate the coupling of a solar power tower with a molten nitrate salt as a heat transfer media and for thermal storage. Over all, the Solar Two Project was very successful; however many operational challenges were encountered. In this work, the major problems encountered in operation of the Solar Two facility were evaluated and alternative technologies identified for use in a future solar power tower operating with a steam Rankine power cycle. Many of the major problems encountered can be addressed with new technologies that were not available a decade ago. These new technologies include better thermal insulation, analytical equipment, pumps and values specifically designed for molten nitrate salts, and gaskets resistant to thermal cycling and advanced equipment designs.

  18. Project Profile: Long-Shafted Molten Salt Pump | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Long-Shafted Molten Salt Pump Project Profile: Long-Shafted Molten Salt Pump Pratt Whitney Rocketdyne logo Pratt & Whitney Rocketdyne (PWR), under the CSP R&D FOA, is validating the manufacturability of a large-scale molten salt receiver panel and then confirming its operation in prototypic solar flux. This work is an important step in reducing the LCOE from a central receiver solar power plant. Approach Image of PWR's design for an advanced molten salt receiver panel for a large

  19. Salt Repository Research,

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    on Salt Repository Research, Design, and Operation La Fonda Hotel Santa Fe, New Mexico September 7 - 11, 2014 Please join us Sunday September 7, 2014 for a welcome and reception at the La Fonda Hotel hosted by Sandia National Laboratories beginning at 6:00 PM. Day 1 Technical Agenda September 8 - Monday 08:00-08:45 Sign-in and distribution of meeting materials 08:45-09:45 Welcome addresses H.C. Pape (BMWi) US-DOE Offices Highlights of US/German Collaboration F. Hansen (SNL) W. Steininger (PTKA)

  20. EP-AREAG-G-FO-DOP-124 Nitrate Salt Bearing TRU Waste Container Monitoring.pdf

    Office of Environmental Management (EM)

  1. Electrolyte salts for nonaqueous electrolytes

    DOE Patents [OSTI]

    Amine, Khalil; Zhang, Zhengcheng; Chen, Zonghai

    2012-10-09

    Metal complex salts may be used in lithium ion batteries. Such metal complex salts not only perform as an electrolyte salt in a lithium ion batteries with high solubility and conductivity, but also can act as redox shuttles that provide overcharge protection of individual cells in a battery pack and/or as electrolyte additives to provide other mechanisms to provide overcharge protection to lithium ion batteries. The metal complex salts have at least one aromatic ring. The aromatic moiety may be reversibly oxidized/reduced at a potential slightly higher than the working potential of the positive electrode in the lithium ion battery. The metal complex salts may also be known as overcharge protection salts.

  2. Electrochromic salts, solutions, and devices

    DOE Patents [OSTI]

    Burrell, Anthony K. (Los Alamos, NM); Warner, Benjamin P. (Los Alamos, NM); McClesky,7,064,212 T. Mark (Los Alamos, NM)

    2006-06-20

    Electrochromic salts. Electrochromic salts of dicationic viologens such as methyl viologen and benzyl viologen associated with anions selected from bis(trifluoromethylsulfonyl)imide, bis(perfluoroethylsulfonyl)imide, and tris(trifluoromethylsulfonyl)methide are produced by metathesis with the corresponding viologen dihalide. They are highly soluble in molten quarternary ammonium salts and together with a suitable reductant provide electrolyte solutions that are used in electrochromic windows.

  3. Electrochromic Salts, Solutions, and Devices

    DOE Patents [OSTI]

    Burrell, Anthony K. (Los Alamos, NM); Warner, Benjamin P. (Los Alamos, NM); McClesky, T. Mark (Los Alamos, NM)

    2008-10-14

    Electrochromic salts. Electrochromic salts of dicationic viologens such as methyl viologen and benzyl viologen associated with anions selected from bis(trifluoromethylsulfonyl)imide, bis(perfluoroethylsulfonyl)imide, and tris(trifluoromethylsulfonyl)methide are produced by metathesis with the corresponding viologen dihalide. They are highly soluble in molten quarternary ammonium salts and together with a suitable reductant provide electrolyte solutions that are used in electrochromic windows.

  4. Electrochromic Salts, Solutions, and Devices

    DOE Patents [OSTI]

    Burrell, Anthony K. (Los Alamos, NM); Warner, Benjamin P. (Los Alamos, NM); McClesky, T. Mark (Los Alamos, NM)

    2008-11-11

    Electrochromic salts. Electrochromic salts of dicationic viologens such as methyl viologen and benzyl viologen associated with anions selected from bis(trifluoromethylsulfonyl)imide, bis(perfluoroethylsulfonyl)imide, and tris(trifluoromethylsulfonyl)methide are produced by metathesis with the corresponding viologen dihalide. They are highly soluble in molten quarternary ammonium salts and together with a suitable reductant provide electrolyte solutions that are used in electrochromic windows.

  5. Deep Eutectic Salt Formulations Suitable as Advanced Heat Transfer Fluids

    SciTech Connect (OSTI)

    Raade, Justin; Roark, Thomas; Vaughn, John; Bradshaw, Robert

    2013-07-22

    Concentrating solar power (CSP) facilities are comprised of many miles of fluid-filled pipes arranged in large grids with reflective mirrors used to capture radiation from the sun. Solar radiation heats the fluid which is used to produce steam necessary to power large electricity generation turbines. Currently, organic, oil-based fluid in the pipes has a maximum temperature threshold of 400 C, allowing for the production of electricity at approximately 15 cents per kilowatt hour. The DOE hopes to foster the development of an advanced heat transfer fluid that can operate within higher temperature ranges. The new heat transfer fluid, when used with other advanced technologies, could significantly decrease solar electricity cost. Lower costs would make solar thermal electricity competitive with gas and coal and would offer a clean, renewable source of energy. Molten salts exhibit many desirable heat transfer qualities within the range of the project objectives. Halotechnics developed advanced heat transfer fluids (HTFs) for application in solar thermal power generation. This project focused on complex mixtures of inorganic salts that exhibited a high thermal stability, a low melting point, and other favorable characteristics. A high-throughput combinatorial research and development program was conducted in order to achieve the project objective. Over 19,000 candidate formulations were screened. The workflow developed to screen various chemical systems to discover salt formulations led to mixtures suitable for use as HTFs in both parabolic trough and heliostat CSP plants. Furthermore, salt mixtures which will not interfere with fertilizer based nitrates were discovered. In addition for use in CSP, the discovered salt mixtures can be applied to electricity storage, heat treatment of alloys and other industrial processes.

  6. DOE - Office of Legacy Management -- Salt_Lake

    Office of Legacy Management (LM)

    Salt_Lake Salt Lake City Sites ut_map Salt Lake City Disposal Site Salt Lake City Processing Site Last Updated: 12/14

  7. Enhanced liquid-liquid anion exchange using macrocyclic anion receptors: effect of receptor structure on sulphate-nitrate exchange selectivity

    SciTech Connect (OSTI)

    Moyer, Bruce A; Sloop Jr, Frederick {Fred} V; Fowler, Christopher J; Haverlock, Tamara; Kang, Hyun Ah; Delmau, Laetitia Helene; Bau, Diadra; Hossain, Alamgir; Bowman-James, Kristin; Shriver, James A.; Gross, Mr. Dustin E.; Bill, Nathan; Marquez, Manuel; Lynch, Vincent M.; Sessler, Jonathan L.

    2010-01-01

    When certain macrocyclic anion receptors are added to a chloroform solution of the nitrate form of a lipophilic quaternary ammonium salt (methyltri-C8,10-ammonium nitrate, Aliquat 336N), the extraction of sulphate from an aqueous sodium nitrate solution via exchange with the organic-phase nitrate is significantly enhanced. Eight macrocycles were surveyed, including two derivatives of a tetraamide macrocycle, five derivatives of calix[4]pyrrole and -decafluorocalix[5]pyrrole. Under the hypothesis that the enhancement originates from sulphate binding by the anion receptors in the chloroform phase, it was possible to obtain reasonable fits to the sulphate distribution survey data based on the formation of 1:1 and 2:1 receptor:sulphate complexes in the chloroform phase. Apparent 1:1 sulphate-binding constants obtained from the model in this system fell in the range . Comparison of the results for the various anion receptors included in this study reveals that sulphate binding is sensitive to the nature of the substituents on the parent macrocycle scaffolds in a way that does not follow straightforwardly from simple chemical expectations, such as electron-withdrawing effects on hydrogen-bond donor strength.

  8. Plant salt-tolerance mechanisms

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Deinlein, Ulrich; Stephan, Aaron B.; Horie, Tomoaki; Luo, Wei; Xu, Guohua; Schroeder, Julian I.

    2014-06-01

    Crop performance is severely affected by high salt concentrations in soils. To engineer more salt-tolerant plants it is crucial to unravel the key components of the plant salt-tolerance network. Here we review our understanding of the core salt-tolerance mechanisms in plants. Recent studies have shown that stress sensing and signaling components can play important roles in regulating the plant salinity stress response. We also review key Na+ transport and detoxification pathways and the impact of epigenetic chromatin modifications on salinity tolerance. In addition, we discuss the progress that has been made towards engineering salt tolerance in crops, including marker-assisted selectionmore » and gene stacking techniques. We also identify key open questions that remain to be addressed in the future.« less

  9. Plant salt-tolerance mechanisms

    SciTech Connect (OSTI)

    Deinlein, Ulrich; Stephan, Aaron B.; Horie, Tomoaki; Luo, Wei; Xu, Guohua; Schroeder, Julian I.

    2014-06-01

    Crop performance is severely affected by high salt concentrations in soils. To engineer more salt-tolerant plants it is crucial to unravel the key components of the plant salt-tolerance network. Here we review our understanding of the core salt-tolerance mechanisms in plants. Recent studies have shown that stress sensing and signaling components can play important roles in regulating the plant salinity stress response. We also review key Na+ transport and detoxification pathways and the impact of epigenetic chromatin modifications on salinity tolerance. In addition, we discuss the progress that has been made towards engineering salt tolerance in crops, including marker-assisted selection and gene stacking techniques. We also identify key open questions that remain to be addressed in the future.

  10. Structural Interactions within Lithium Salt Solvates: Acyclic...

    Office of Scientific and Technical Information (OSTI)

    Structural Interactions within Lithium Salt Solvates: Acyclic Carbonates and Esters Citation Details In-Document Search Title: Structural Interactions within Lithium Salt Solvates: ...

  11. Operating Experience Level 2, Evaluation of Nitrate Bearing Transurani...

    Broader source: Energy.gov (indexed) [DOE]

    015 OE-2 2015-01: Evaluation of Nitrate Bearing Transuranic Waste Streams This Operating Experience Level 2 (OE-2) document provides actions to perform an evaluation of...

  12. Texas-Louisiana- Mississippi Salt Basin Greater Green River Basin

    Gasoline and Diesel Fuel Update (EIA)

    Texas-Louisiana- Mississippi Salt Basin Greater Green River Basin W. Gulf Coast Basin Appalachian Basin Wind River Basin Eastern Shelf NW Shelf Abo Sussex-Shannon Muddy J Mesaverde- Lance-Lewis Medina/Clinton-Tuscarora Bradford-Venango-Elk Berea-Murrysville Piceance Basin Bossier Williston Basin Ft Worth Basin Davis Bighorn Basin Judith River- Eagle Permian Basin Anadarko Basin Denver Basin San Juan Basin North-Central Montana Area Uinta Basin Austin Chalk Codell-Niobrara Penn-Perm Carbonate

  13. Use of tensiometer for in situ measurement of nitrate leaching

    SciTech Connect (OSTI)

    Li, K.; Reddy, M.R.

    1999-07-01

    In order to monitor nitrate leaching from non-point source pollution, this study used tensiometers to measure in situ nitrate concentration and soil-moisture potential. Instead of filling the tensiometers with pure water, the study filled the tensiometers with nitrate ionic strength adjuster (ISA, 1 M (NH{sub 4}){sub 2}SO{sub 4}). After the installation of the tensiometers at various depths along soil profiles, a portable pressure transducer was used to measure the soil moisture potential, and a nitrate electrode attached to an ion analyzer was used to measure the nitrate concentration in situ. The measurement was continuous and non-destructive. To test this method in the laboratory, eight bottles filled with pure sand were treated with known nitrate solutions, and a tensiometer was placed in each bottle. Measurements were taken every day for 30 days. Laboratory test showed a linear relationship between the known nitrate concentration and the tensiometer readings (R{sup 2} = 0.9990). Then a field test was conducted in a watermelon field with green manure mulch. Field data indicated a potential of nitrate leaching below the soil depth of 100 cm when crop uptake of nutrients was low.

  14. Method for improved decomposition of metal nitrate solutions

    DOE Patents [OSTI]

    Haas, P.A.; Stines, W.B.

    1981-01-21

    A method for co-conversion of aqueous solutions of one or more heavy metal nitrates is described, wherein thermal decomposition within a temperature range of about 300 to 800/sup 0/C is carried out in the presence of about 50 to 500% molar concentration of ammonium nitrate to total metal.

  15. Method for improved decomposition of metal nitrate solutions

    DOE Patents [OSTI]

    Haas, Paul A. (Knoxville, TN); Stines, William B. (Knoxville, TN)

    1983-10-11

    A method for co-conversion of aqueous solutions of one or more heavy metal nitrates wherein thermal decomposition within a temperature range of about 300.degree. to 800.degree. C. is carried out in the presence of about 50 to 500% molar concentration of ammonium nitrate to total metal.

  16. Ion Recognition Approach to Volume Reduction of Alkaline Tank Waste by Separation of Sodium Salts

    SciTech Connect (OSTI)

    Levitskaia, Tatiana G.; Lumetta, Gregg J.; Moyer, Bruce A.; Bonnesen, Peter V.

    2006-06-01

    The purpose of this research involving collaboration between Oak Ridge National Laboratory (ORNL) and Pacific Northwest National Laboratory (PNNL) is to explore new approaches to the separation of sodium hydroxide, sodium nitrate, and other sodium salts from high-level alkaline tank waste. The principal potential benefit is a major reduction in disposed waste volume, obviating the building of expensive new waste tanks and reducing the costs of low-activity waste immobilization. Principles of ion recognition are being researched toward discovery of liquid extraction systems that selectively separate sodium hydroxide and sodium nitrate from other waste components. The successful concept of pseudohydroxide extraction using fluorinated alcohols and phenols is being developed at ORNL and PNNL toward a greater understanding of the controlling equilibria, role of solvation, and of synergistic effects involving crown ethers. Studies at PNNL are directed toward new solvent formulation for the practical sodium pseudohydroxide extraction systems.

  17. ARRAYS OF BOTTLES OF PLUTONIUM NITRATE SOLUTION

    SciTech Connect (OSTI)

    Margaret A. Marshall

    2012-09-01

    In October and November of 1981 thirteen approaches-to-critical were performed on a remote split table machine (RSTM) in the Critical Mass Laboratory of Pacific Northwest Laboratory (PNL) in Richland, Washington using planar arrays of polyethylene bottles filled with plutonium (Pu) nitrate solution. Arrays of up to sixteen bottles were used to measure the critical number of bottles and critical array spacing with a tight fitting Plexiglas reflector on all sides of the arrays except the top. Some experiments used Plexiglas shells fitted around each bottles to determine the effect of moderation on criticality. Each bottle contained approximately 2.4 L of Pu(NO3)4 solution with a Pu content of 105 g Pu/L and a free acid molarity H+ of 5.1. The plutonium was of low 240Pu (2.9 wt.%) content. These experiments were sponsored by Rockwell Hanford Operations because of the lack of experimental data on the criticality of arrays of bottles of Pu solution such as might be found in storage and handling at the Purex Facility at Hanford. The results of these experiments were used to provide benchmark data to validate calculational codes used in criticality safety assessments of [the] plant configurations (Ref. 1). Data for this evaluation were collected from the published report (Ref. 1), the approach to critical logbook, the experimenters logbook, and communication with the primary experimenter, B. Michael Durst. Of the 13 experiments preformed 10 were evaluated. One of the experiments was not evaluated because it had been thrown out by the experimenter, one was not evaluated because it was a repeat of another experiment and the third was not evaluated because it reported the critical number of bottles as being greater than 25. Seven of the thirteen evaluated experiments were determined to be acceptable benchmark experiments. A similar experiment using uranyl nitrate was benchmarked as U233-SOL-THERM-014.

  18. Central American

    Office of Scientific and Technical Information (OSTI)

    LoS &rfos National hbOratorY is operated by the University of California for the United States Department of Energy under contract W-7405-ENG-36. Central American oergy-anci-Resource>i Geothermal Demonstration: DISCLAIMER This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency Thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or

  19. Production of chlorine from chloride salts

    DOE Patents [OSTI]

    Rohrmann, Charles A. (Kennewick, WA)

    1981-01-01

    A process for converting chloride salts and sulfuric acid to sulfate salts and elemental chlorine is disclosed. A chloride salt and sulfuric acid are combined in a furnace where they react to produce a sulfate salt and hydrogen chloride. Hydrogen chloride from the furnace contacts a molten salt mixture containing an oxygen compound of vanadium, an alkali metal sulfate and an alkali metal pyrosulfate to recover elemental chlorine. In the absence of an oxygen-bearing gas during the contacting, the vanadium is reduced, but is regenerated to its active higher valence state by separately contacting the molten salt mixture with an oxygen-bearing gas.

  20. CENTRAL FILES

    Office of Legacy Management (LM)

    / .- ~ _. ,- *-.* . . CENTRAL FILES +, a/ o(-t.z2-5 AlLO 1 Pab-FJr 3. 19% TYtxP REPaT To A&7bA cM.m rlmc)HA~ ON JANtJm 23, 1956 f. A. W~~~+Y, M.D. c. 1. 08huRann 8nd J. A. Hlaeririg ob3e8tilw of Trlpr in @ ttd~, (;rulw 2?), 1956, a ttip na nda to UM Crrrit &abw8tury, cword, Ohio. The purpow o? this trip u&a to aondwt the WMnd ti 8 #etia8 of indUrtF%al mgiene run~yr uhiah hre been Thwr8port ia 8 66mpondzLusofthe Amu4ll;rmtr forth&, rtsnyu@raaaderith~.~~M Alb8ugh,

  1. WIPP Shares Expertise with Salt Club Members

    Broader source: Energy.gov [DOE]

    EM’s Carlsbad Field Office (CBFO) participated in the second meeting of the Nuclear Energy Agency’s (NEA) Salt Club and the 4th U.S.-German Workshop on Salt Repository Research, Design & Operation in Berlin.

  2. Salt Wells Geothermal Project | Open Energy Information

    Open Energy Info (EERE)

    Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Development Project: Salt Wells Geothermal Project Project Location Information Coordinates 39.580833333333,...

  3. Solar central receiver systems comparative economics

    SciTech Connect (OSTI)

    Eicker, P J

    1980-04-01

    Several major conceptual design studies of solar central receiver systems and components have been completed in the last year. The results of these studies are used to compare the projected cost of electric power generation using central receiver systems with that of more conventional power generation. The cost estimate for a molten salt central receiver system is given. Levelized busbar energy cost is shown as a function of annual capacity factor indicating the fraction of the cost due to each of the subsystems. The estimated levelized busbar energy cost for a central receiver (70 to 90 mills per kilowatt hour) is compared with the levelized busbar energy cost for a new coal fired Rankine cycle plant. Sensitivities to the initial cost of coal and the delta fuel escalation are shown. (WHK)

  4. Brine Migration Experimental Studies for Salt Repositories

    Broader source: Energy.gov [DOE]

    Experiments were used to examine water content in Permian salt samples including impact of variation in thermal regime on water content of evaporites and other mineral species, behavior of brine inclusions in salt, and evolution of the gas/liquid brine/salt system.

  5. Decontamination of water using nitrate selective ion exchange resin

    DOE Patents [OSTI]

    Lockridge, J.E.; Fritz, J.S.

    1990-07-31

    A method for nitrate decontamination of water which involves passing the water through a bed of alkyl phosphonium anion exchange resin which has pendant alkyl groups of C[sub 3] or larger.

  6. Decontamination of water using nitrate selective ion exchange resin

    DOE Patents [OSTI]

    Lockridge, James E. (Ames, IA); Fritz, James S. (Ames, IA)

    1990-07-31

    A method for nitrate decontamination of water which involves passing the water through a bed of alkyl phosphonium anion exchange resin which has pendant alkyl groups of C.sub.3 or larger.

  7. Evaluation of Nitrate-Bearing Transuranic Waste Streams

    Energy Savers [EERE]

    OE-2: 2015-1 June 2015 Evaluation of Nitrate-Bearing Transuranic Waste Streams PURPOSE This Operating Experience Level 2 (OE-2) document provides actions to perform an evaluation...

  8. ARM - SGP Central Facility

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Central Facility SGP Related Links Virtual Tour Facilities and Instruments Central Facility Boundary Facility Extended Facility Intermediate Facility Radiometric Calibration...

  9. Molecular recognition of nitrated fatty acids by PPAR[gamma

    SciTech Connect (OSTI)

    Li, Yong; Zhang, Jifeng; Schopfer, Francisco J.; Martynowski, Dariusz; Garcia-Barrio, Minerva T.; Kovach, Amanda; Suino-Powell, Kelly; Baker, Paul R.S.; Freeman, Bruce A.; Chen, Y. Eugene; Xu, H. Eric

    2010-03-08

    Peroxisome proliferator activated receptor-{gamma} (PPAR{gamma}) regulates metabolic homeostasis and adipocyte differentiation, and it is activated by oxidized and nitrated fatty acids. Here we report the crystal structure of the PPAR{gamma} ligand binding domain bound to nitrated linoleic acid, a potent endogenous ligand of PPAR{gamma}. Structural and functional studies of receptor-ligand interactions reveal the molecular basis of PPAR{gamma} discrimination of various naturally occurring fatty acid derivatives.

  10. Molten Salt-Carbon Nanotube Thermal Energy Storage for Concentrating Solar Power Systems Final Report

    SciTech Connect (OSTI)

    Michael Schuller; Frank Little; Darren Malik; Matt Betts; Qian Shao; Jun Luo; Wan Zhong; Sandhya Shankar; Ashwin Padmanaban

    2012-03-30

    We demonstrated that adding nanoparticles to a molten salt would increase its utility as a thermal energy storage medium for a concentrating solar power system. Specifically, we demonstrated that we could increase the specific heat of nitrate and carbonate salts containing 1% or less of alumina nanoparticles. We fabricated the composite materials using both evaporative and air drying methods. We tested several thermophysical properties of the composite materials, including the specific heat, thermal conductivity, latent heat, and melting point. We also assessed the stability of the composite material with repeated thermal cycling and the effects of adding the nanoparticles on the corrosion of stainless steel by the composite salt. Our results indicate that stable, repeatable 25-50% improvements in specific heat are possible for these materials. We found that using these composite salts as the thermal energy storage material for a concentrating solar thermal power system can reduce the levelized cost of electricity by 10-20%. We conclude that these materials are worth further development and inclusion in future concentrating solar power systems.

  11. Coupled Thermal-Hydrological-Mechanical Processes in Salt, Hot Granular

    Office of Environmental Management (EM)

    Salt Consolidation, Constitutive Model and Micromechanics | Department of Energy Coupled Thermal-Hydrological-Mechanical Processes in Salt, Hot Granular Salt Consolidation, Constitutive Model and Micromechanics Coupled Thermal-Hydrological-Mechanical Processes in Salt, Hot Granular Salt Consolidation, Constitutive Model and Micromechanics The report addresses granular salt reconsolidation from three vantage points: laboratory testing, modeling, and petrofabrics. The experimental data 1)

  12. Thermophysical properties of reconsolidating crushed salt.

    SciTech Connect (OSTI)

    Bauer, Stephen J.; Urquhart, Alexander

    2014-03-01

    Reconsolidated crushed salt is being considered as a backfilling material placed upon nuclear waste within a salt repository environment. In-depth knowledge of thermal and mechanical properties of the crushed salt as it reconsolidates is critical to thermal/mechanical modeling of the reconsolidation process. An experimental study was completed to quantitatively evaluate the thermal conductivity of reconsolidated crushed salt as a function of porosity and temperature. The crushed salt for this study came from the Waste Isolation Pilot Plant (WIPP). In this work the thermal conductivity of crushed salt with porosity ranging from 1% to 40% was determined from room temperature up to 300oC, using two different experimental methods. Thermal properties (including thermal conductivity, thermal diffusivity and specific heat) of single-crystal salt were determined for the same temperature range. The salt was observed to dewater during heating; weight loss from the dewatering was quantified. The thermal conductivity of reconsolidated crushed salt decreases with increasing porosity; conversely, thermal conductivity increases as the salt consolidates. The thermal conductivity of reconsolidated crushed salt for a given porosity decreases with increasing temperature. A simple mixture theory model is presented to predict and compare to the data developed in this study.

  13. Analytical Characterization of the Thorium Nitrate Stockpile

    SciTech Connect (OSTI)

    Mattus, CH

    2003-12-30

    For several years, Oak Ridge National Laboratory (ORNL) has been supporting the Defense Logistics Agency-Defense National Stockpile Center with stewardship of a thorium nitrate (ThN) stockpile. The effort for fiscal year 2002 was to prepare a sampling and analysis plan and to use the activities developed in the plan to characterize the ThN stockpile. The sampling was performed in June and July 2002 by RWE NUKEM with oversight by ORNL personnel. The analysis was performed by Southwest Research Institute of San Antonio, Texas, and data validation was performed by NFT, Inc., of Oak Ridge, Tennessee. Of the {approx} 21,000 drums in the stockpile, 99 were sampled and 53 were analyzed for total metals composition, radiological constituents (using alpha and gamma spectrometry), and oxidizing characteristics. Each lot at the Curtis Bay Depot was sampled. Several of the samples were also analyzed for density. The average density of the domestic ThN was found to be 1.89 {+-} 0.08 g/cm{sup 3}. The oxidizer test was performed following procedures issued by the United Nations in 1999. Test results indicated that none of the samples tested was a Division 5.1 oxidizer per Department of Transportation definition. The samples were analyzed for total metals following the U.S. Environmental Protection Agency methods SW-846-6010B and 6020 (EPA 2003) using a combination of inductively coupled plasma--atomic emission spectroscopy and inductively coupled plasma--mass spectroscopy techniques. The results were used to compare the composition of the eight Resource Conservation and Recovery Act metals present in the sample (arsenic, barium, cadmium, chromium, lead, mercury, selenium, and silver) to regulatory limits. None of the samples was found to be hazardous for toxicity characteristics. The radiological analyses confirmed, when possible, the results obtained by the inductively coupled plasma analyses. These results--combined with the historical process knowledge acquired on the material and the results of previous tests--classified the ThN as low-level radioactive waste for disposal purposes. This characterization was necessary to continue the efforts associated with disposition of the material at the Nevada Test Site, Mercury, Nevada. With the current work presented in this report, the analytical characterization phase is completed for this source material stockpile.

  14. Salt restrains maturation in subsalt plays

    SciTech Connect (OSTI)

    Mello, U.T. ); Anderson, R.N.; Karner, G.D. . Lamont-Doherty Earth Observatory)

    1994-01-31

    The thermal positive anomaly associated with the top of salt diapirs has attracted significant attention in modifying the temperature structure and history of a sedimentary basin. Here the authors explore the role of the negative thermal anomaly beneath salt in modifying the maturation history of the source rocks in subsalt sediments. Organic matter maturation is believed to follow temperature dependent chemical reactions. Therefore, any temperature anomaly associated with salt masses affects the nearby maturation of potential source rocks. The level of maturity of source rocks close to salt diapirs will differ from that predicted based on regional trends. The impact of the thermal anomaly on a given point will depend on the duration and distance of the thermal anomaly to this particular point. Consequently, the maturation history of source rocks in salt basins is closely related to the salt motion history, implying that a transient thermal analysis is necessary to evaluate the sure impact on maturation of the thermal anomalies associated with salt diapirism. The paper describes vitrinite kinetics, salt in evolving basins, correlation of salt and temperature, salt dome heat drains, and restrained maturation.

  15. Ion Recognition Approach to Volume Reduction of Alkaline Tank Waste by Separation and Recycle of Sodium Hydroxide and Sodium Nitrate

    SciTech Connect (OSTI)

    Moyer, Bruce A.; Marchand, Alan P.; Bryan, Jeffrey C.; Bonnesen, Peter V.

    1999-06-01

    The objective of this research is to explore new liquid-liquid extraction approaches to the selective separation of major sodium salts from alkaline high-level wastes stored in underground tanks at Hanford, Savannah River, and Oak Ridge sites. Disposal of high level waste is horrendously expensive, in large part because the actual radioactive matter in the tanks has been diluted over 1000-fold by ordinary inorganic chemicals. Since the residual bulk chemicals must still undergo expensive treatment and disposal after most of the hazardous radionuclides have been removed, large cost savings will result from processes that reduce the overall waste volume. It is proposed that major cost savings can be expected if sodium hydroxide needed for sludge washing can be obtained from the waste itself, thus avoiding the addition of yet another bulk chemical to the waste and still further increase of the waste volume and disposal cost. Secondary priority is given to separating potassium an d abundant anions, including nitrate, nitrite, aluminate, and carbonate. Salts of these ions represent possible additional value for recycle, alternative disposal, or even use as commodity chemicals. A comprehensive approach toward understanding the extractive chemistry of these salts is envisioned, involving systems of varying complexity, from use of simple solvents to new bifunctional host molecules for ion-pair recognition. These extractants will ideally require no adjustment of the waste composition and will release the extracted salt into water, thereby consuming no additional chemicals and producing no additional waste volume. The overall goal of this research is to provide a scientific foundation upon which the feasibility of new liquid-liquid extraction chemistry applicable to the bulk reduction of the volume of tank waste can be evaluated.

  16. Electrolytic orthoborate salts for lithium batteries

    DOE Patents [OSTI]

    Angell, Charles Austen [Mesa, AZ; Xu, Wu [Tempe, AZ

    2009-05-05

    Orthoborate salts suitable for use as electrolytes in lithium batteries and methods for making the electrolyte salts are provided. The electrolytic salts have one of the formulae (I). In this formula anionic orthoborate groups are capped with two bidentate chelating groups, Y1 and Y2. Certain preferred chelating groups are dibasic acid residues, most preferably oxalyl, malonyl and succinyl, disulfonic acid residues, sulfoacetic acid residues and halo-substituted alkylenes. The salts are soluble in non-aqueous solvents and polymeric gels and are useful components of lithium batteries in electrochemical devices.

  17. Electrolytic orthoborate salts for lithium batteries

    DOE Patents [OSTI]

    Angell, Charles Austen; Xu, Wu

    2008-01-01

    Orthoborate salts suitable for use as electrolytes in lithium batteries and methods for making the electrolyte salts are provided. The electrolytic salts have one of the formulae (I). In this formula anionic orthoborate groups are capped with two bidentate chelating groups, Y1 and Y2. Certain preferred chelating groups are dibasic acid residues, most preferably oxalyl, malonyl and succinyl, disulfonic acid residues, sulfoacetic acid residues and halo-substituted alkylenes. The salts are soluble in non-aqueous solvents and polymeric gels and are useful components of lithium batteries in electrochemical devices.

  18. Granular Salt Summary: Reconsolidation Principles and Applications

    SciTech Connect (OSTI)

    Hansen, Frank; Popp, Till; Wieczorek, Klaus; Stührenberg, Dieter

    2014-07-01

    The purposes of this paper are to review the vast amount of knowledge concerning crushed salt reconsolidation and its attendant hydraulic properties (i.e., its capability for fluid or gas transport) and to provide a sufficient basis to understand reconsolidation and healing rates under repository conditions. Topics covered include: deformation mechanisms and hydro-mechanical interactions during reconsolidation; the experimental data base pertaining to crushed salt reconsolidation; transport properties of consolidating granulated salt and provides quantitative substantiation of its evolution to characteristics emulating undisturbed rock salt; and extension of microscopic and laboratory observations and data to the applicable field scale.

  19. Mechanochemical Preparation of Phosphonium Salts and Phosphorus...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ...olvent-free mechanochemical preparation method to prepare phosphonium salts and phosphorous ylides. The phosphorous ylides are then utilized in carrying out the solvent-free ...

  20. Noncentrosymmetric salt inclusion oxides: Role of salt lattices and counter ions in bulk polarity

    SciTech Connect (OSTI)

    West, J. Palmer; Hwu, Shiou-Jyh

    2012-11-15

    The synthesis and structural features of a newly emerged class of salt-inclusion solids (SISs) are reviewed. The descriptive chemistry with respect to the role of ionic salt and its correlation with bulk noncentrosymmetricity and polarity of the covalent oxide lattice in question is discussed by means of structure analysis. These unprecedented discoveries have opened doors to novel materials synthesis via the utilities of salt-inclusion chemistry (SIC) that are otherwise known as the molten-salt approach. The result of these investigations prove that the bulk acentricity, or cancellation of which, can be accounted for from the perspective of ionic and/or salt lattices. Highlights: Black-Right-Pointing-Pointer Synthesis and structure of newly emerged salt-inclusion solids are reviewed. Black-Right-Pointing-Pointer Salt lattice and its symmetry correlation with polar framework are discussed. Black-Right-Pointing-Pointer Preservation of acentricity is accounted for from the perspective of ionic and salt lattices.

  1. Savannah River Site - Salt Waste Processing Facility: Briefing on the Salt

    Energy Savers [EERE]

    Waste Processing Facility Independent Technical Review | Department of Energy Facility: Briefing on the Salt Waste Processing Facility Independent Technical Review Savannah River Site - Salt Waste Processing Facility: Briefing on the Salt Waste Processing Facility Independent Technical Review This is a presentation outlining the Salt Waste Processing Facility process, major risks, approach for conducting reviews, discussion of the findings, and conclusions. PDF icon Savannah River Site -

  2. Critical experiments with mixed plutonium-uranium nitrate solutions having

    Office of Scientific and Technical Information (OSTI)

    Pu:(Pu + U) ratios greater than 0.5 (Technical Report) | SciTech Connect Critical experiments with mixed plutonium-uranium nitrate solutions having Pu:(Pu + U) ratios greater than 0.5 Citation Details In-Document Search Title: Critical experiments with mixed plutonium-uranium nitrate solutions having Pu:(Pu + U) ratios greater than 0.5 × You are accessing a document from the Department of Energy's (DOE) SciTech Connect. This site is a product of DOE's Office of Scientific and Technical

  3. Electrochemical reduction of nitrate in the presence of an amide

    DOE Patents [OSTI]

    Dziewinski, Jacek J. (Los Alamos, NM); Marczak, Stanislaw (Los Alamos, NM)

    2002-01-01

    The electrochemical reduction of nitrates in aqueous solutions thereof in the presence of amides to gaseous nitrogen (N.sub.2) is described. Generally, electrochemical reduction of NO.sub.3 proceeds stepwise, from NO.sub.3 to N.sub.2, and subsequently in several consecutive steps to ammonia (NH.sub.3) as a final product. Addition of at least one amide to the solution being electrolyzed suppresses ammonia generation, since suitable amides react with NO.sub.2 to generate N.sub.2. This permits nitrate reduction to gaseous nitrogen to proceed by electrolysis. Suitable amides include urea, sulfamic acid, formamide, and acetamide.

  4. Explosive double salts and preparation

    DOE Patents [OSTI]

    Cady, Howard H. (Los Alamos, NM); Lee, Kien-yin (Los Alamos, NM)

    1984-01-01

    Applicants have discovered a new composition of matter which is an explosive addition compound of ammonium nitrate (AN) and diethylenetriamine trinitrate (DETN) in a 50:50 molar ratio. The compound is stable over extended periods of time only at temperatures higher than 46.degree. C., decomposing to a fine-grained eutectic mixture (which is also believed to be new) of AN and DETN at temperatures lower than 46.degree. C. The compound of the invention has an x-ray density of 1.61 g/cm.sup.3, explodes to form essentially only gaseous products, has higher detonation properties (i.e., detonation velocity and pressure) than those of any mechanical mixture having the same density and composition as the compound of the invention, is a quite insensitive explosive material, can be cast at temperatures attainable by high pressure steam, and is prepared from inexpensive ingredients. Methods of preparing the compound of the invention and the fine-grained eutectic composition of the invention are given.

  5. Molten Salt Power Tower Cost Model for the System Advisor Model (SAM)

    SciTech Connect (OSTI)

    Turchi, C. S.; Heath, G. A.

    2013-02-01

    This report describes a component-based cost model developed for molten-salt power tower solar power plants. The cost model was developed by the National Renewable Energy Laboratory (NREL), using data from several prior studies, including a contracted analysis from WorleyParsons Group, which is included herein as an Appendix. The WorleyParsons' analysis also estimated material composition and mass for the plant to facilitate a life cycle analysis of the molten salt power tower technology. Details of the life cycle assessment have been published elsewhere. The cost model provides a reference plant that interfaces with NREL's System Advisor Model or SAM. The reference plant assumes a nominal 100-MWe (net) power tower running with a nitrate salt heat transfer fluid (HTF). Thermal energy storage is provided by direct storage of the HTF in a two-tank system. The design assumes dry-cooling. The model includes a spreadsheet that interfaces with SAM via the Excel Exchange option in SAM. The spreadsheet allows users to estimate the costs of different-size plants and to take into account changes in commodity prices. This report and the accompanying Excel spreadsheet can be downloaded at https://sam.nrel.gov/cost.

  6. Solar Policy Environment: Salt Lake

    Broader source: Energy.gov [DOE]

    The overall objective of the “Solar Salt Lake” (SSL) team is to develop a fully-scoped city and county-level implementation plan that will facilitate at least an additional ten megawatts of solar photovoltaic (PV) installations in the government, commercial, industrial, and residential sectors by 2015. To achieve this aggressive goal, the program strategy includes a combination of barrier identification, research, and policy analysis that utilizes the input of various stakeholders. Coupled with these activities will be the development and implementation of pilot installations in the government and residential sectors, and broad outreach to builders and potential practitioners of solar energy products in the process. In this way, while creating mechanisms to enable a demand for solar, SSL will also facilitate capacity building for suppliers, thereby helping to ensure long-term sustainability for the regional market.

  7. Metal salt catalysts for enhancing hydrogen spillover

    SciTech Connect (OSTI)

    Yang, Ralph T; Wang, Yuhe

    2013-04-23

    A composition for hydrogen storage includes a receptor, a hydrogen dissociating metal doped on the receptor, and a metal salt doped on the receptor. The hydrogen dissociating metal is configured to spill over hydrogen to the receptor, and the metal salt is configured to increase a rate of the spill over of the hydrogen to the receptor.

  8. central | OpenEI Community

    Open Energy Info (EERE)

    central Home OpenEI Community Central Description: The central OpenEI community for students, scientists, researchers, enthusiasts, analysts and developers. central OpenEI town...

  9. Evaluation of Salt Coolants for Reactor Applications

    SciTech Connect (OSTI)

    Williams, David F

    2008-01-01

    Molten fluorides were initially developed for use in the nuclear industry as the high-temperature fluid fuel for the Molten Salt Reactor (MSR). The U.S. Department of Energy Office of Nuclear Energy is exploring the use of molten salts as primary and secondary coolants in a new generation of solid-fueled, thermal-spectrum, hightemperature reactors. This paper provides a review of relevant properties for use in evaluation and ranking of salt coolants for high-temperature reactors. Nuclear, physical, and chemical properties were reviewed, and metrics for evaluation are recommended. Chemical properties of the salt were examined to identify factors that affect materials compatibility (i.e., corrosion). Some preliminary consideration of economic factors for the candidate salts is also presented.

  10. Geothermal Literature Review At Salt Wells Area (Faulds, Et Al...

    Open Energy Info (EERE)

    Salt Wells Area (Faulds, Et Al., 2011) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Geothermal Literature Review At Salt Wells Area (Faulds,...

  11. Salt Lake City, Utah: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Salt Lake City, Utah: Energy Resources (Redirected from Salt Lake City, UT) Jump to: navigation, search Equivalent URI DBpedia Coordinates 40.7607793, -111.8910474 Show Map...

  12. DOE - Office of Legacy Management -- Penn Salt Manufacturing...

    Office of Legacy Management (LM)

    Salt Manufacturing Co Whitemarsh Research Laboratories - PA 20 FUSRAP Considered Sites Site: PENN SALT MANUFACTURING CO., WHITEMARSH RESEARCH LABORATORIES (PA.20) Eliminated from...

  13. Voluntary Protection Program Onsite Review, Parsons Corp., Salt...

    Office of Environmental Management (EM)

    Corp., Salt Waste Processing Facility Construction Project - May 2014 Voluntary Protection Program Onsite Review, Parsons Corp., Salt Waste Processing Facility Construction Project...

  14. Development of Molten-Salt Heat Trasfer Fluid Technology for...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Development of Molten-Salt Heat Trasfer Fluid Technology for Parabolic Trough Solar Power Plants ... Development of Molten-Salt Heat Transfer Fluid Technology for Parabolic Trough ...

  15. Magnetotellurics At Salt Wells Area (Bureau of Land Management...

    Open Energy Info (EERE)

    Salt Wells Area (Bureau of Land Management, 2009) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Magnetotellurics At Salt Wells Area (Bureau of...

  16. Assessment of Nuclear Safety Culture at the Salt Waste Processing...

    Office of Environmental Management (EM)

    Oversight Assessment of Nuclear Safety Culture at the Salt Waste Processing Facility ... Independent Oversight Assessment of Nuclear Safety Culture at the Salt Waste ...

  17. Salt Lake County, Utah: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Creek Valley, Utah Magna, Utah Midvale, Utah Millcreek, Utah Mount Olympus, Utah Murray, Utah Riverton, Utah Salt Lake City, Utah Sandy, Utah South Jordan, Utah South Salt...

  18. BLM Fact Sheet- Ormat Technologies Salt Wells Geothermal Energy...

    Open Energy Info (EERE)

    Ormat Technologies Salt Wells Geothermal Energy Project Jump to: navigation, search OpenEI Reference LibraryAdd to library Report: BLM Fact Sheet- Ormat Technologies Salt Wells...

  19. Isotopic Analysis- Fluid At Salt Wells Area (Shevenell & Garside...

    Open Energy Info (EERE)

    At Salt Wells Area (Shevenell & Garside, 2003) Exploration Activity Details Location Salt Wells Geothermal Area Exploration Technique Isotopic Analysis- Fluid Activity Date 2002 -...

  20. Compound and Elemental Analysis At Salt Wells Area (Shevenell...

    Open Energy Info (EERE)

    At Salt Wells Area (Shevenell & Garside, 2003) Exploration Activity Details Location Salt Wells Geothermal Area Exploration Technique Compound and Elemental Analysis Activity Date...

  1. Conceptual Model At Salt Wells Area (Faulds, Et Al., 2011) |...

    Open Energy Info (EERE)

    At Salt Wells Area (Faulds, Et Al., 2011) Exploration Activity Details Location Salt Wells Geothermal Area Exploration Technique Conceptual Model Activity Date 2011 Usefulness...

  2. Sandia Energy - Molten Salt Test Loop Pump Installed

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Energy News Concentrating Solar Power Solar Energy Storage Systems Molten Salt Test Loop Pump Installed Previous Next Molten Salt Test Loop Pump Installed The pump was...

  3. Independent Oversight Review, Savannah River Site Salt Waste...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    August 2013 Independent Oversight Review, Savannah River Site Salt Waste Processing Facility - August 2013 August 2013 Review of the Savannah River Site Salt Waste Processing...

  4. EIA - Natural Gas Pipeline Network - Salt Cavern Storage Reservoir...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Salt Cavern Underground Natural Gas Storage Reservoir Configuration Salt Cavern Underground Natural Gas Storage Reservoir Configuration Source: PB Energy Storage Services Inc.

  5. Examination of Liquid Fluoride Salt Heat Transfer

    SciTech Connect (OSTI)

    Yoder Jr, Graydon L

    2014-01-01

    The need for high efficiency power conversion and energy transport systems is increasing as world energy use continues to increase, petroleum supplies decrease, and global warming concerns become more prevalent. There are few heat transport fluids capable of operating above about 600oC that do not require operation at extremely high pressures. Liquid fluoride salts are an exception to that limitation. Fluoride salts have very high boiling points, can operate at high temperatures and low pressures and have very good heat transfer properties. They have been proposed as coolants for next generation fission reactor systems, as coolants for fusion reactor blankets, and as thermal storage media for solar power systems. In each case, these salts are used to either extract or deliver heat through heat exchange equipment, and in order to design this equipment, liquid salt heat transfer must be predicted. This paper discusses the heat transfer characteristics of liquid fluoride salts. Historically, heat transfer in fluoride salts has been assumed to be consistent with that of conventional fluids (air, water, etc.), and correlations used for predicting heat transfer performance of all fluoride salts have been the same or similar to those used for water conventional fluids an, water, etc). A review of existing liquid salt heat transfer data is presented, summarized, and evaluated on a consistent basis. Less than 10 experimental data sets have been found in the literature, with varying degrees of experimental detail and measured parameters provided. The data has been digitized and a limited database has been assembled and compared to existing heat transfer correlations. Results vary as well, with some data sets following traditional correlations; in others the comparisons are less conclusive. This is especially the case for less common salt/materials combinations, and suggests that additional heat transfer data may be needed when using specific salt eutectics in heat transfer equipment designs. All of the data discussed above were taken under forced convective conditions (both laminar and turbulent). Some recent data taken at ORNL under free convection conditions are also presented and results discussed. This data was taken using a simple crucible experiment with an instrumented nickel heater inserted in the salt to induce natural circulation within the crucible. The data was taken over a temperature range of 550oC to 650oC in FLiNaK salt. This data covers both laminar and turbulent natural convection conditions, and is compared to existing forms of natural circulation correlations.

  6. Ion Recognition Approach to Volume Reduction of Alkaline Tank Waste by Separation and Recycle of Sodium Hydroxide and Sodium Nitrate

    SciTech Connect (OSTI)

    Moyer, Bruce A.; Marchand, Alan P.

    2001-06-01

    Disposal of high-level nuclear waste is horrendously expensive, in large part because the actual radioactive matter in the tanks has been diluted over 1000-fold by ordinary inorganic chemicals. Treatment processes themselves can exacerbate the problem by adding further volume to the waste. Waste retrieval and sludge washing, for example, will require copious amounts of sodium hydroxide. If the needed sodium hydroxide could be separated from the waste and recycled, however, the addition of fresh sodium hydroxide could be avoided, ultimately reducing the final waste volume and associated disposal costs. The major objective of this research is to explore new liquid-liquid extraction approaches to the selective separation of sodium hydroxide from alkaline high-level wastes stored in underground tanks at the Hanford and Savannah River sites. Consideration is also given to separating potassium and abundant anions, including nitrate, nitrite, aluminate, and carbonate. Salts of these ions represent possible additional value for recycle, alternative disposal, or even use as commodity chemicals. A comprehensive approach toward understanding the extractive chemistry of these salts is envisioned, involving systems of varying complexity, from use of simple solvents to new bifunctional host molecules for ion-pair recognition. These extractants will ideally require no adjustment of the waste composition and will release the extracted salt into water, thereby consuming no additional chemicals and producing no additional waste volume. The overall goal of this research is to provide a scientific foundation upon which the feasibility of new liquid-liquid extraction chemistry applicable to the bulk reduction of the volume of tank waste can be evaluated.

  7. Ion Recognition Approach to Volume Reduction of Alkaline Tank Waste by Separation and Recycle of Sodium Hydroxide and Sodium Nitrate

    SciTech Connect (OSTI)

    Moyer, Bruce A.; Marchand, Alan P.

    2000-06-01

    Disposal of high- level waste is horrendously expensive, in large part because the actual radioactive matter in the tanks has been diluted over 1000-fold by ordinary inorganic chemicals. Treatment processes themselves can exacerbate the problem by adding further volume to the waste. Waste retrieval and sludge washing, for example, will require copious amounts of sodium hydroxide. If the needed sodium hydroxide could be separated from the waste and recycled, however, the addition of fresh sodium hydroxide could be avoided, ultimately reducing the final waste volume and associated disposal costs. The major objective of this research is to explore new liquid- liquid extraction approaches to the selective separation of sodium hydroxide from alkaline high-level wastes stored in underground tanks at the Hanford and Savannah River sites. Consideration is also given to separating potassium and abundant anions, including nitrate, nitrite, aluminate, and carbonate. Salts of these ions represent possible additional value for recycle, alternative disposal, or even use as commodity chemicals. A comprehensive approach toward understanding the extractive chemistry of these salts is envisioned, involving systems of varying complexity, from use of simple solvents to new bifunctional host molecules for ion-pair recognition. These extractants will ideally require no adjustment of the waste composition and will release the extracted salt into water, thereby consuming no additional chemicals and producing no additional waste volume. The overall goal of this research is to provide a scientific foundation upon which the feasibility of new liquid-liquid extraction chemistry applicable to the bulk reduction of the volume of tank waste can be evaluated.

  8. Central Plateau - Hanford Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Central Plateau Richland Operations Office Richland Operations Office River Corridor Central Plateau 200 Area B Plant Plutonium Finishing Plant Canyon Facilities Effluent Treatment Facility Environmental Restoration Disposal Facility Integrated Disposal Facility Liquid Effluent Retention Facility PUREX REDOX T Plant TRU Waste Treated Effluent Disposal Facility U Plant Waste Encapsulation and Storage Facility Waste Receiving and Processing Facility Groundwater Mission Support Newsroom Central

  9. Director, Salt Waste Processing Facility Project Office

    Broader source: Energy.gov [DOE]

    This position is located within The Department of Energy (DOE) Savannah River (SR) Operations Office, Salt Waste Processing Facility Project Office (SWPFPO). SR is located in Aiken, South Carolina....

  10. Salt Lake City- High Performance Buildings Requirement

    Broader source: Energy.gov [DOE]

    Salt Lake City's mayor issued an executive order in July 2005 requiring that all public buildings owned and controlled by the city be built or renovated to meet the requirements of LEED "silver"...

  11. Molten salt destruction of energetic waste materials

    DOE Patents [OSTI]

    Brummond, W.A.; Upadhye, R.S.; Pruneda, C.O.

    1995-07-18

    A molten salt destruction process is used to treat and destroy energetic waste materials such as high explosives, propellants, and rocket fuels. The energetic material is pre-blended with a solid or fluid diluent in safe proportions to form a fluid fuel mixture. The fuel mixture is rapidly introduced into a high temperature molten salt bath. A stream of molten salt is removed from the vessel and may be recycled as diluent. Additionally, the molten salt stream may be pumped from the reactor, circulated outside the reactor for further processing, and delivered back into the reactor or cooled and circulated to the feed delivery system to further dilute the fuel mixture entering the reactor. 4 figs.

  12. Molten salt destruction of energetic waste materials

    DOE Patents [OSTI]

    Brummond, William A. (Livermore, CA); Upadhye, Ravindra S. (Pleasanton, CA); Pruneda, Cesar O. (Livermore, CA)

    1995-01-01

    A molten salt destruction process is used to treat and destroy energetic waste materials such as high explosives, propellants, and rocket fuels. The energetic material is pre-blended with a solid or fluid diluent in safe proportions to form a fluid fuel mixture. The fuel mixture is rapidly introduced into a high temperature molten salt bath. A stream of molten salt is removed from the vessel and may be recycled as diluent. Additionally, the molten salt stream may be pumped from the reactor, circulated outside the reactor for further processing, and delivered back into the reactor or cooled and circulated to the feed delivery system to further dilute the fuel mixture entering the reactor.

  13. Salt Selection for the LS-VHTR

    SciTech Connect (OSTI)

    Williams, D.F.; Clarno, K.T.

    2006-07-01

    Molten fluorides were initially developed for use in the nuclear industry as the high temperature fluid-fuel for a Molten Salt Reactor (MSR). The Office of Nuclear Energy is exploring the use of molten fluorides as a primary coolant (rather than helium) in an Advanced High Temperature Reactor (AHTR) design, also know as the Liquid-Salt cooled Very High Temperature Reactor (LS-VHTR). This paper provides a review of relevant properties for use in evaluation and ranking of candidate coolants for the LS-VHTR. Nuclear, physical, and chemical properties were reviewed and metrics for evaluation are recommended. Chemical properties of the salt were examined for the purpose of identifying factors that effect materials compatibility (i.e., corrosion). Some preliminary consideration of economic factors for the candidate salts is also presented. (authors)

  14. Extraction of metals and/or metalloids from acidic media using supercritical fluids and salts

    DOE Patents [OSTI]

    Wai, Chien M.; Smart, Neil G.; Lin, Yuehe

    1998-01-01

    A method of extracting metalloid and metal species from a solid or liquid material by exposing the material to a fluid solvent, particularly supercritical carbon dioxide, containing a chelating agent is described. The chelating agent forms chelates that are soluble in the fluid to allow removal of the species from the material. In preferred embodiments, the extraction solvent is supercritical carbon dioxide and the chelating agent comprises a trialkyl phosphate, a triaryl phosphate, a trialkylphosphine oxide, a triarylphosphine oxide, or mixtures thereof. The method provides an environmentally benign process for removing contaminants from industrial waste. The method is particularly useful for extracting actinides from acidic solutions, and the process can be aided by the addition of nitrate salts. The chelate and supercritical fluid can be regenerated, and the contaminant species recovered, to provide an economic, efficient process.

  15. Extraction of metals and/or metalloids from acidic media using supercritical fluids and salts

    DOE Patents [OSTI]

    Wai, C.M.; Smart, N.G.; Lin, Y.

    1998-06-23

    A method is described for extracting metalloid and metal species from a solid or liquid material by exposing the material to a fluid solvent, particularly supercritical carbon dioxide, containing a chelating agent. The chelating agent forms chelates that are soluble in the fluid to allow removal of the species from the material. In preferred embodiments, the extraction solvent is supercritical carbon dioxide and the chelating agent comprises a trialkyl phosphate, a triaryl phosphate, a trialkylphosphine oxide, a triarylphosphine oxide, or mixtures thereof. The method provides an environmentally benign process for removing contaminants from industrial waste. The method is particularly useful for extracting actinides from acidic solutions, and the process can be aided by the addition of nitrate salts. The chelate and supercritical fluid can be regenerated, and the contaminant species recovered, to provide an economic, efficient process. 7 figs.

  16. Combined Utilization of Cation Exchanger and Neutral Receptor to Volume Reduction of Alkaline Tank Waste by Separation of Sodium Salts

    SciTech Connect (OSTI)

    Levitskaia, Tatiana G.; Lumetta, Gregg J.; Moyer, Bruce A.

    2004-03-29

    In this report, novel approaches to the selective liquid-liquid extraction separation of sodium hydroxide and sodium nitrate from high-level alkaline tank waste will be discussed. Sodium hydroxide can be successfully separated from alkaline tank-waste supernatants by weakly acidic lipophilic hydroxy compounds via a cation-exchange mechanism referred to as pseudo hydroxide extraction. In a multi-cycle process, as sodium hydroxide in the aqueous phase becomes depleted, it is helpful to have a neutral sodium receptor in the extraction system to exploit the high nitrate concentration in the waste solution to promote sodium removal by an ion-pair extraction process. Simultaneous utilization of an ionizable organic hydroxy compound and a neutral extractant (crown ether) in an organic phase results in the synergistic enhancement of ion exchange and improved separation selectivity due to the receptor's strong and selective sodium binding. Moreover, combination of the hydroxy compound and the crown ether provides for mutually increased solubility, even in a non-polar organic solvent. Accordingly, application of Isopar{reg_sign} L, a kerosene-like alkane solvent, becomes feasible. This investigation involves examination of such dual-mechanism extraction phases for sodium extraction from simulated and actual salt cake waste solutions. Sodium salts can be regenerated upon the contact of the loaded extraction phases with water. Finally, conditions of potential extraction/strip cycling will be discussed.

  17. Thermal Characterization of Molten Salt Systems

    SciTech Connect (OSTI)

    Toni Y. Gutknecht; Guy L. Fredrickson

    2011-09-01

    The phase stability of molten salts in an electrorefiner (ER) may be adversely affected by the buildup of sodium, fission products, and transuranics in the electrolyte. Potential situations that need to be avoided are the following: (1) salt freezing due to an unexpected change in the liquidus temperature, (2) phase separation or non-homogeneity of the molten salt due to the precipitation of solids or formation of immiscible liquids, and (3) any mechanism that can result in the separation and concentration of fissile elements from the molten salt. Any of these situations would result in an off-normal condition outside the established safety basis for electrorefiner (ER) operations. The stability (and homogeneity) of the phases can potentially be monitored through the thermal characterization of the salts, which can be a function of impurity concentration. This report describes the experimental results of typical salts compositions, which consist of chlorides of potassium, lithium, strontium, samarium, praseodymium, lanthanum, barium, cerium, cesium, neodymium, sodium and gadolinium chlorides as a surrogate for both uranium and plutonium, used for the processing of used nuclear fuels.

  18. Ion Recognition Approach to Volume Reduction of Alkaline Tank Waste by Separation of Sodium Salts

    SciTech Connect (OSTI)

    Moyer, Bruce A.; Marchand, Alan P.; Lumetta, Gregg J.

    2004-06-30

    In this project, now completing its third year of its second renewal period, a collaborative project involving Oak Ridge National Laboratory, Pacific Northwest National Laboratory, and the University of North Texas has been addressing outstanding questions regarding the separation of the bulk sodium constituents of alkaline tank waste. The principal potential benefit of this research is a major reduction in the volume of radioactive tank waste, obviating the building of expensive new tanks and reducing the costs of vitrification. As a general approach, principles of ion recognition are being explored toward discovery and basic understanding of liquid-liquid extraction systems that selectively separate sodium hydroxide and sodium salts from waste-like matrices. Questions being addressed pertain to applicable extraction equilibria and how extraction properties relate to extractant structure. Progress has included the elucidation of the promising concept of pseudo hydroxide extraction (PHE), demonstration of crown-ether synergized PHE, demonstration of combined sodium hydroxide/sodium nitrate separation, and synthesis of novel ditopic receptors for ditopic PHE. In future efforts (pending renewal), a thermochemical study of PHE relating extractant acidity to extraction strength is proposed, and this study will be extended to systems containing crown ethers, including proton-ionizable ones. A series of crown ethers will be synthesized for this purpose and to investigate the extraction of bulk sodium salts (e.g., nitrate, nitrite, and sulfate), possibly in combination with sodium hydroxide. Simple proof-of-principle tests with real tank waste at PNNL will provide feedback toward solvent designs that have desirable properties. In view of the upcoming milestone of completion of the second renewal period, this report will, in addition to providing a summary of the past year's progress, summarize all of the work completed since the start of this project.

  19. Ion Recognition Approach to Volume Reduction of Alkaline Tank Waste by Separation of Sodium Salts

    SciTech Connect (OSTI)

    Levitskaia, Tatiana G.; Lumetta, Gregg J.; Moyer, Bruce A.; Bonnesen, Peter V.

    2005-06-01

    The purpose of this research involving collaboration between Oak Ridge National Laboratory (ORNL) and Pacific Northwest National Laboratory (PNNL) is to explore new approaches to the separation of sodium hydroxide, sodium nitrate, and other sodium salts from high-level alkaline tank waste. The principal potential benefit is a major reduction in disposed waste volume, obviating the building of expensive new waste tanks and reducing the costs of low-activity waste immobilization. Principles of ion recognition are being researched toward discovery of liquid-liquid extraction systems that selectively separate sodium hydroxide and sodium nitrate from other waste components. The successful concept of pseudohydroxide extraction using fluorinated alcohols and phenols is being developed at ORNL and PNNL toward a greater understanding of the controlling equilibria, role of solvation, and of synergistic effects involving crown ethers. Synthesis efforts are being directed toward enhanced sodium binding by crown ethers, both neutral and proton-ionizable. Studies with real tank waste at PNNL will provide feedback toward solvent compositions that have promising properties.

  20. Ion Recognition Approach to Volume Reduction of Alkaline Tank Waste by Separation of Sodium Salts

    SciTech Connect (OSTI)

    Moyer, Bruce A.; Bonnesen, Peter V.; Custelcean, Radu; Delmau, Laetitia H.; Engle, Nancy L.; Kang, Hyun-Ah; Keever, Tamara J.; Marchand, Alan P.; Gadthula, Srinivas; Gore, Vinayak K.; Huang, Zilin; Sivappa, Rasapalli; Tirunahari, Pavan K.; Levitskaia, Tatiana G.; Lumetta, Gregg J.

    2005-09-26

    The purpose of this research involving collaboration between Oak Ridge National Laboratory (ORNL) and Pacific Northwest National Laboratory (PNNL) is to explore new approaches to the separation of sodium hydroxide, sodium nitrate, and other sodium salts from high-level alkaline tank waste. The principal potential benefit is a major reduction in disposed waste volume, obviating the building of expensive new waste tanks and reducing the costs of vitrification. Principles of ion recognition are being researched toward discovery of liquid-liquid extraction systems that selectively separate sodium hydroxide and sodium nitrate from other waste components. The successful concept of pseudo hydroxide extraction using fluorinated alcohols and phenols is being developed at ORNL and PNNL toward a greater understanding of the controlling equilibria, role of solvation, and of synergistic effects involving crown ethers. Synthesis efforts are being directed toward enhanced sodium binding by crown ethers, both neutral and proton-ionizable. Studies with real tank waste at PNNL will provide feedback toward solvent compositions that have promising properties.

  1. Electrolyte Solvation and Ionic Association. VI. Acetonitrile-Lithium Salt

    Office of Scientific and Technical Information (OSTI)

    Mixtures: Highly Associated Salts Revisited (Journal Article) | SciTech Connect Electrolyte Solvation and Ionic Association. VI. Acetonitrile-Lithium Salt Mixtures: Highly Associated Salts Revisited Citation Details In-Document Search Title: Electrolyte Solvation and Ionic Association. VI. Acetonitrile-Lithium Salt Mixtures: Highly Associated Salts Revisited Molecular dynamics (MD) simulations of acetonitrile (AN) mixtures with LiBF4, LiCF3SO3 and LiCF3CO2 provide extensive details about the

  2. Savannah River Site - Salt Waste Processing Facility Independent Technical

    Energy Savers [EERE]

    Review | Department of Energy Facility Independent Technical Review Savannah River Site - Salt Waste Processing Facility Independent Technical Review Full Document and Summary Versions are available for download PDF icon Savannah River Site - Salt Waste Processing Facility Independent Technical Review PDF icon Summary - Salt Waste Processing Facility Design at the Savannah River Site More Documents & Publications Savannah River Site - Salt Waste Processing Facility: Briefing on the Salt

  3. Low temperature oxidation using support molten salt catalysts

    DOE Patents [OSTI]

    Weimer, Alan W.; Czerpak, Peter J.; Hilbert, Patrick M.

    2003-05-20

    Molten salt reactions are performed by supporting the molten salt on a particulate support and forming a fluidized bed of the supported salt particles. The method is particularly suitable for combusting hydrocarbon fuels at reduced temperatures, so that the formation NO.sub.x species is reduced. When certain preferred salts are used, such as alkali metal carbonates, sulfur and halide species can be captured by the molten salt, thereby reducing SO.sub.x and HCl emissions.

  4. Hybrid solar central receiver for combined cycle power plant

    DOE Patents [OSTI]

    Bharathan, D.; Bohn, M.S.; Williams, T.A.

    1995-05-23

    A hybrid combined cycle power plant is described including a solar central receiver for receiving solar radiation and converting it to thermal energy. The power plant includes a molten salt heat transfer medium for transferring the thermal energy to an air heater. The air heater uses the thermal energy to preheat the air from the compressor of the gas cycle. The exhaust gases from the gas cycle are directed to a steam turbine for additional energy production. 1 figure.

  5. Hybrid solar central receiver for combined cycle power plant

    DOE Patents [OSTI]

    Bharathan, Desikan (Lakewood, CO); Bohn, Mark S. (Golden, CO); Williams, Thomas A. (Arvada, CO)

    1995-01-01

    A hybrid combined cycle power plant including a solar central receiver for receiving solar radiation and converting it to thermal energy. The power plant includes a molten salt heat transfer medium for transferring the thermal energy to an air heater. The air heater uses the thermal energy to preheat the air from the compressor of the gas cycle. The exhaust gases from the gas cycle are directed to a steam turbine for additional energy production.

  6. Chemistry control and corrosion mitigation of heat transfer salts for the fluoride salt reactor (FHR)

    SciTech Connect (OSTI)

    Kelleher, B. C.; Sellers, S. R.; Anderson, M. H.; Sridharan, K.; Scheele, R. D.

    2012-07-01

    The Molten Salt Reactor Experiment (MSRE) was a prototype nuclear reactor which operated from 1965 to 1969 at Oak Ridge National Laboratory. The MSRE used liquid fluoride salts as a heat transfer fluid and solvent for fluoride based {sup 235}U and {sup 233}U fuel. Extensive research was performed in order to optimize the removal of oxide and metal impurities from the reactor's heat transfer salt, 2LiF-BeF{sub 2} (FLiBe). This was done by sparging a mixture of anhydrous hydrofluoric acid and hydrogen gas through the FLiBe at elevated temperatures. The hydrofluoric acid reacted with oxides and hydroxides, fluorinating them while simultaneously releasing water vapor. Metal impurities such as iron and chromium were reduced by hydrogen gas and filtered out of the salt. By removing these impurities, the corrosion of reactor components was minimized. The Univ. of Wisconsin - Madison is currently researching a new chemical purification process for fluoride salts that make use of a less dangerous cleaning gas, nitrogen trifluoride. Nitrogen trifluoride has been predicted as a superior fluorinating agent for fluoride salts. These purified salts will subsequently be used for static and loop corrosion tests on a variety of reactor materials to ensure materials compatibility for the new FHR designs. Demonstration of chemistry control methodologies along with potential reduction in corrosion is essential for the use of a fluoride salts in a next generator nuclear reactor system. (authors)

  7. Characterization of the molten salt reactor experiment fuel and flush salts

    SciTech Connect (OSTI)

    Williams, D.F.; Peretz, F.J.

    1996-05-01

    Wise decisions about the handling and disposition of spent fuel from the Molten Salt Reactor Experiment (MSRE) must be based upon an understanding of the physical, chemical, and radiological properties of the frozen fuel and flush salts. These {open_quotes}static{close_quotes} properties can be inferred from the extensive documentation of process history maintained during reactor operation and the knowledge gained in laboratory development studies. Just as important as the description of the salt itself is an understanding of the dynamic processes which continue to transform the salt composition and govern its present and potential physicochemical behavior. A complete characterization must include a phenomenological characterization in addition to the typical summary of properties. This paper reports on the current state of characterization of the fuel and flush salts needed to support waste management decisions.

  8. SGP Central Facility

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Central Facility SGP Related Links Virtual Tour Facilities and Instruments Central Facility Boundary Facility Extended Facility Intermediate Facility Radiometric Calibration Facility Geographic Information ES&H Guidance Statement Operations Science Field Campaigns Visiting the Site SGP Fact Sheet Images Information for Guest Scientists Contacts SGP Central Facility The ARM Climate Research Facility deploys specialized remote sensing instruments in a fixed location at the site to gather

  9. Centralized Procurement Program

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Centralized Procurement Program What's New Who to Contact Current Products BOAs MOC Integrated Team Program Elements Future Products Welcome to the Carlsbad Field Office’s (CBFO) Centralized Procurement Program (CPP) Web Page. The purpose of the Centralized Procurement Program is to provide a standardized, economical system of acquisition and distribution of containers and equipment used for shipping Transuranic (TRU) Waste to the Waste Isolation Pilot Plant (WIPP). The program is available

  10. Real time in situ detection of organic nitrates in atmospheric aerosols

    SciTech Connect (OSTI)

    Rollins, Andrew W.; Smith, Jared D.; Wilson, Kevin R.; Cohen, Ronald C.

    2010-06-11

    A new field instrument is described that quantifies total particle phase organic nitrates. The instrument is based on the thermal dissociation laser induced fluorescence (TD-LIF) method that thermally converts nitrates to NO2 which is then detected by LIF. This instrument is unique in its ability to provide fast sensitive measurements of particle phase organic nitrates, without interference from inorganic nitrate. Here we use it to quantify organic nitrates in SOA generated from high-NOx photooxidation of limonene, a-pinene, D-3-carene, and tridecane. In these experiments the organic nitrate moiety is observed to be 6-15percent of the total SOA mass, depending on the organic precursor.

  11. Laser-induced breakdown spectroscopic study of ammonium nitrate plasma

    SciTech Connect (OSTI)

    Hanif, M.; Salik, M.; Baig, M. A.

    2013-12-15

    We present the optical emission studies of the ammonium nitrate plasma produced by the fundamental (1064 nm) and second (532 nm) harmonics of a Q-switched Nd: YAG laser. The target material was placed in front of the laser beam in an open atmospheric air. The spectrum reveals numerous transitions of neutral nitrogen. We have studied the spatial behavior of the plasma temperature (T{sub e}) and electron number density (N{sub e}) determined using the Boltzmann plot method and Stark broadened line profiles, respectively. Besides, we have studied the variation of the plasma parameters as a function of the laser irradiance.

  12. Brine flow in heated geologic salt.

    SciTech Connect (OSTI)

    Kuhlman, Kristopher L.; Malama, Bwalya

    2013-03-01

    This report is a summary of the physical processes, primary governing equations, solution approaches, and historic testing related to brine migration in geologic salt. Although most information presented in this report is not new, we synthesize a large amount of material scattered across dozens of laboratory reports, journal papers, conference proceedings, and textbooks. We present a mathematical description of the governing brine flow mechanisms in geologic salt. We outline the general coupled thermal, multi-phase hydrologic, and mechanical processes. We derive these processes' governing equations, which can be used to predict brine flow. These equations are valid under a wide variety of conditions applicable to radioactive waste disposal in rooms and boreholes excavated into geologic salt.

  13. Investigating In Situ Bioremediation Approaches for Sustained Uranium Immobilization Independent of Nitrate Reduction

    SciTech Connect (OSTI)

    Phelps, Tommy; Balkwill, David

    2006-06-01

    The daunting prospect of complete nitrate removal at DOE sites, such as the ERSP Oak Ridge Field Research Center (FRC), provides strong incentive to explore bioremediation strategies that will allow for uranium bioreduction and long-term stabilization in the presence of nitrate. The cost and effort required for complete nitrate removal from the FRC and similar DOE-contaminated sites may prove to be unworkable. For example, field tests of uranium bioreduction at the FRC have shown that nitrate levels rebound quickly and completely after cessation of active biostimulation.

  14. [Task 1.] Biodenitrification of low nitrate solar pond waters using sequencing batch reactors. [Task 2.] Solidification/stabilization of high strength and biodenitrified heavy metal sludges with a Portland cement/flyash system

    SciTech Connect (OSTI)

    Figueroa, L.; Cook, N.E.; Siegrist, R.L.; Mosher, J.; Terry, S.; Canonico, S.

    1995-09-22

    Process wastewater and sludges were accumulated on site in solar evaporation ponds during operations at the Department of Energy's Rocky Flats Plant (DOE/RF). Because of the extensive use of nitric acid in the processing of actinide metals, the process wastewater has high concentrations of nitrate. Solar pond waters at DOE/RF contain 300-60,000 mg NO{sub 3}{sup {minus}}/L. Additionally, the pond waters contain varying concentrations of many other aqueous constituents, including heavy metals, alkali salts, carbonates, and low level radioactivity. Solids, both from chemical precipitation and soil material deposition, are also present. Options for ultimate disposal of the pond waters are currently being evaluated and include stabilization and solidification (S/S) by cementation. Removal of nitrates can enhance a wastes amenability to S/S, or can be a unit operation in another treatment scheme. Nitrate removal is also a concern for other sources of pollution at DOE/RF, including contaminated groundwater collected by interceptor trench systems. Finally, nitrate pollution is a problem at many other DOE facilities where actinide metals were processed. The primary objective of this investigation was to optimize biological denitrification of solar pond waters with nitrate concentrations of 300--2,100 mg NO{sub 3}{sup {minus}}/L to below the drinking water standard of 45 mg NO{sub 3}{sup {minus}}/L (10 mg N/L). The effect of pH upon process stability and denitrification rate was determined. In addition, the effect Cr(VI) on denitrification and fate of Cr(VI) in the presence of denitrifying bacteria was evaluated.

  15. High Temperature Fluoride Salt Test Loop

    SciTech Connect (OSTI)

    Aaron, Adam M.; Cunningham, Richard Burns; Fugate, David L.; Holcomb, David Eugene; Kisner, Roger A.; Peretz, Fred J.; Robb, Kevin R.; Wilson, Dane F.; Yoder, Jr, Graydon L.

    2015-12-01

    Effective high-temperature thermal energy exchange and delivery at temperatures over 600°C has the potential of significant impact by reducing both the capital and operating cost of energy conversion and transport systems. It is one of the key technologies necessary for efficient hydrogen production and could potentially enhance efficiencies of high-temperature solar systems. Today, there are no standard commercially available high-performance heat transfer fluids above 600°C. High pressures associated with water and gaseous coolants (such as helium) at elevated temperatures impose limiting design conditions for the materials in most energy systems. Liquid salts offer high-temperature capabilities at low vapor pressures, good heat transport properties, and reasonable costs and are therefore leading candidate fluids for next-generation energy production. Liquid-fluoride-salt-cooled, graphite-moderated reactors, referred to as Fluoride Salt Reactors (FHRs), are specifically designed to exploit the excellent heat transfer properties of liquid fluoride salts while maximizing their thermal efficiency and minimizing cost. The FHR s outstanding heat transfer properties, combined with its fully passive safety, make this reactor the most technologically desirable nuclear power reactor class for next-generation energy production. Multiple FHR designs are presently being considered. These range from the Pebble Bed Advanced High Temperature Reactor (PB-AHTR) [1] design originally developed by UC-Berkeley to the Small Advanced High-Temperature Reactor (SmAHTR) and the large scale FHR both being developed at ORNL [2]. The value of high-temperature, molten-salt-cooled reactors is also recognized internationally, and Czechoslovakia, France, India, and China all have salt-cooled reactor development under way. The liquid salt experiment presently being developed uses the PB-AHTR as its focus. One core design of the PB-AHTR features multiple 20 cm diameter, 3.2 m long fuel channels with 3 cm diameter graphite-based fuel pebbles slowly circulating up through the core. Molten salt coolant (FLiBe) at 700°C flows concurrently (at significantly higher velocity) with the pebbles and is used to remove heat generated in the reactor core (approximately 1280 W/pebble), and supply it to a power conversion system. Refueling equipment continuously sorts spent fuel pebbles and replaces spent or damaged pebbles with fresh fuel. By combining greater or fewer numbers of pebble channel assemblies, multiple reactor designs with varying power levels can be offered. The PB-AHTR design is discussed in detail in Reference [1] and is shown schematically in Fig. 1. Fig. 1. PB-AHTR concept (drawing taken from Peterson et al., Design and Development of the Modular PB-AHTR Proceedings of ICApp 08). Pebble behavior within the core is a key issue in proving the viability of this concept. This includes understanding the behavior of the pebbles thermally, hydraulically, and mechanically (quantifying pebble wear characteristics, flow channel wear, etc). The experiment being developed is an initial step in characterizing the pebble behavior under realistic PB-AHTR operating conditions. It focuses on thermal and hydraulic behavior of a static pebble bed using a convective salt loop to provide prototypic fluid conditions to the bed, and a unique inductive heating technique to provide prototypic heating in the pebbles. The facility design is sufficiently versatile to allow a variety of other experimentation to be performed in the future. The facility can accommodate testing of scaled reactor components or sub-components such as flow diodes, salt-to-salt heat exchangers, and improved pump designs as well as testing of refueling equipment, high temperature instrumentation, and other reactor core designs.

  16. Toluene nitration in irradiated nitric acid and nitrite solution

    SciTech Connect (OSTI)

    Gracy Elias; Bruce J. Mincher; Stephen P. Mezyk; Jim Muller; Leigh R. Martin

    2011-04-01

    The kinetics, mechanisms, and stable products produced for the aryl alkyl mild ortho-para director - toluene, in irradiated nitric acid and neutral nitrite solutions were investigated using ?, and pulse radiolysis. Electron pulse radiolysis was used to determine the bimolecular rate constants for the reaction of toluene with different transient species produced by irradiation. HPLC with UV detection was primarily used to assess the stable reaction products. GC-MS and LC-MS were used to confirm the results from HPLC. Free-radical nitration reaction products were found in irradiated acidic and neutral media. In acidic medium, the ring substitution and side chain substitution and oxidation produced different nitro products. In ring substitution, nitrogen oxide radicals were added mainly to hydroxyl radical-produced cyclohexadienyl radical, and in side chain substitution they were added to the carbon-centered benzyl radical produced by H-atom abstraction. In neutral nitrite toluene solution, radiolytic ring nitration products approached a statistically random distribution, suggesting a free-radical reaction involving addition of the NO2 radical.

  17. Hybrid Molten Salt Reactor (HMSR) System Study

    SciTech Connect (OSTI)

    Woolley, Robert D; Miller, Laurence F

    2014-04-01

    Can the hybrid system combination of (1) a critical fission Molten Salt Reactor (MSR) having a thermal spectrum and a high Conversion Ratio (CR) with (2) an external source of high energy neutrons provide an attractive solution to the world's expanding demand for energy? The present study indicates the answer is an emphatic yes.

  18. Accelerators for Subcritical Molten-Salt Reactors

    SciTech Connect (OSTI)

    Johnson, Roland

    2011-08-03

    Accelerator parameters for subcritical reactors have usually been based on using solid nuclear fuel much like that used in all operating critical reactors as well as the thorium burning accelerator-driven energy amplifier proposed by Rubbia et al. An attractive alternative reactor design that used molten salt fuel was experimentally studied at ORNL in the 1960s, where a critical molten salt reactor was successfully operated using enriched U235 or U233 tetrafluoride fuels. These experiments give confidence that an accelerator-driven subcritical molten salt reactor will work better than conventional reactors, having better efficiency due to their higher operating temperature, having the inherent safety of subcritical operation, and having constant purging of volatile radioactive elements to eliminate their accumulation and potential accidental release in dangerous amounts. Moreover, the requirements to drive a molten salt reactor can be considerably relaxed compared to a solid fuel reactor, especially regarding accelerator reliability and spallation neutron targetry, to the point that much of the required technology exists today. It is proposed that Project-X be developed into a prototype commercial machine to produce energy for the world by, for example, burning thorium in India and nuclear waste from conventional reactors in the USA.

  19. Salt repository project closeout status report

    SciTech Connect (OSTI)

    1988-06-01

    This report provides an overview of the scope and status of the US Department of Energy (DOE`s) Salt Repository Project (SRP) at the time when the project was terminated by the Nuclear Waste Policy Amendments Act of 1987. The report reviews the 10-year program of siting a geologic repository for high-level nuclear waste in rock salt formations. Its purpose is to aid persons interested in the information developed during the course of this effort. Each area is briefly described and the major items of information are noted. This report, the three salt Environmental Assessments, and the Site Characterization Plan are the suggested starting points for any search of the literature and information developed by the program participants. Prior to termination, DOE was preparing to characterize three candidate sites for the first mined geologic repository for the permanent disposal of high-level nuclear waste. The sites were in Nevada, a site in volcanic tuff; Texas, a site in bedded salt (halite); and Washington, a site in basalt. These sites, identified by the screening process described in Chapter 3, were selected from the nine potentially acceptable sites shown on Figure I-1. These sites were identified in accordance with provisions of the Nuclear Waste Policy Act of 1982. 196 refs., 21 figs., 11 tabs.

  20. Energy Efficient Buildings, Salt Lake County, Utah

    SciTech Connect (OSTI)

    Barnett, Kimberly

    2012-04-30

    Executive Summary Salt Lake County's Solar Photovoltaic Project - an unprecedented public/private partnership Salt Lake County is pleased to announce the completion of its unprecedented solar photovoltaic (PV) installation on the Calvin R. Rampton Salt Palace Convention Center. This 1.65 MW installation will be one the largest solar roof top installations in the country and will more than double the current installed solar capacity in the state of Utah. Construction is complete and the system will be operational in May 2012. The County has accomplished this project using a Power Purchase Agreement (PPA) financing model. In a PPA model a third-party solar developer will finance, develop, own, operate, and maintain the solar array. Salt Lake County will lease its roof, and purchase the power from this third-party under a long-term Power Purchase Agreement contract. In fact, this will be one of the first projects in the state of Utah to take advantage of the recent (March 2010) legislation which makes PPA models possible for projects of this type. In addition to utilizing a PPA, this solar project will employ public and private capital, Energy Efficiency and Conservation Block Grants (EECBG), and public/private subsidized bonds that are able to work together efficiently because of the recent stimulus bill. The project also makes use of recent changes to federal tax rules, and the recent re-awakening of private capital markets that make a significant public-private partnership possible. This is an extremely innovative project, and will mark the first time that all of these incentives (EECBG grants, Qualified Energy Conservation Bonds, New Markets tax credits, investment tax credits, public and private funds) have been packaged into one project. All of Salt Lake County's research documents and studies, agreements, and technical information is available to the public. In addition, the County has already shared a variety of information with the public through webinars, site tours, presentations, and written correspondence.

  1. Completing Salt Waste Processing Facility is an EM Priority and...

    Office of Environmental Management (EM)

    Completing Salt Waste Processing Facility is an EM Priority and Key to SRS Cleanup Progress Completing Salt Waste Processing Facility is an EM Priority and Key to SRS Cleanup ...

  2. Accident Investigation of the February 5, 2014, Underground Salt...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    5, 2014, Underground Salt Haul Truck Fire at the Waste Isolation Pilot Plant, Carlsbad NM Accident Investigation of the February 5, 2014, Underground Salt Haul Truck Fire at the...

  3. BLM Fact Sheet- Vulcan Power Company Salt Wells Geothermal Energy...

    Open Energy Info (EERE)

    Vulcan Power Company Salt Wells Geothermal Energy Project Jump to: navigation, search OpenEI Reference LibraryAdd to library Report: BLM Fact Sheet- Vulcan Power Company Salt Wells...

  4. File:Salt2.pdf | Open Energy Information

    Open Energy Info (EERE)

    Salt2.pdf Jump to: navigation, search File File history File usage Metadata File:Salt2.pdf Size of this preview: 463 599 pixels. Other resolution: 464 600 pixels. Go to page...

  5. Method for preparing salt solutions having desired properties

    DOE Patents [OSTI]

    Ally, Moonis R. (Oak Ridge, TN); Braunstein, Jerry (Clinton, TN)

    1994-01-01

    The specification discloses a method for preparing salt solutions which exhibit desired thermodynamic properties. The method enables prediction of the value of the thermodynamic properties for single and multiple salt solutions over a wide range of conditions from activity data and constants which are independent of concentration and temperature. A particular application of the invention is in the control of salt solutions in a process to provide a salt solution which exhibits the desired properties.

  6. Workplace Charging Challenge Partner: Salt River Project | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Salt River Project Workplace Charging Challenge Partner: Salt River Project Workplace Charging Challenge Partner: Salt River Project The mission of Salt River Project's (SRP) Electric Vehicle Initiative is to encourage greater use of clean energy transportation. Under this program, SRP's headquarters received two Level 2 charging stations in 2010. When demand for workplace charging increased in 2012, SRP added eight Level 2 and five Level 1 charging stations for employee use.

  7. Project Profile: Modular and Scalable Baseload Molten Salt Plant Conceptual

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Design and Feasibility | Department of Energy Concentrating Solar Power » Project Profile: Modular and Scalable Baseload Molten Salt Plant Conceptual Design and Feasibility Project Profile: Modular and Scalable Baseload Molten Salt Plant Conceptual Design and Feasibility eSolar logo eSolar, under the Baseload CSP FOA, is designing a 100-MW, 75% capacity factor, molten salt power tower plant, based around a molten salt receiver and heliostat field module with a nominal thermal rating of 50

  8. Construction of Salt Waste Processing Facility (SWPF) | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy of Salt Waste Processing Facility (SWPF) Construction of Salt Waste Processing Facility (SWPF) Presentation from the 2015 DOE National Cleanup Workshop by Frank Sheppard, Project Manager, Parsons-SWPF. PDF icon Construction of Salt Waste Processing Facility (SWPF) More Documents & Publications Audit Report: OAS-L-15-09 Parsons Infrastructure & Technology Group, Inc., Consent Order Savannah River Site - Salt Waste Processing Facility Independent Technical Review

  9. Salt Waste Contractor Reaches Contract Milestone | Department of Energy

    Energy Savers [EERE]

    Salt Waste Contractor Reaches Contract Milestone Salt Waste Contractor Reaches Contract Milestone April 29, 2013 - 12:00pm Addthis Robert Brown, SRR tank farm operator, performs daily inspections of a salt disposition process facility. The inspections and improvement upgrades have resulted in continued successful operations. Robert Brown, SRR tank farm operator, performs daily inspections of a salt disposition process facility. The inspections and improvement upgrades have resulted in continued

  10. Savannah River Site Salt Waste Processing Facility Technology Readiness

    Energy Savers [EERE]

    Assessment Report | Department of Energy Salt Waste Processing Facility Technology Readiness Assessment Report Savannah River Site Salt Waste Processing Facility Technology Readiness Assessment Report Full Document and Summary Versions are available for download PDF icon Savannah River Site Salt Waste Processing Facility Technology Readiness Assessment Report PDF icon Summary - SRS Salt Waste Processing Facility More Documents & Publications Compilation of TRA Summaries Basis for Section

  11. Independent Oversight Review, Savannah River Site Salt Waste Processing

    Office of Environmental Management (EM)

    Facility - August 2013 | Department of Energy Salt Waste Processing Facility - August 2013 Independent Oversight Review, Savannah River Site Salt Waste Processing Facility - August 2013 August 2013 Review of the Savannah River Site Salt Waste Processing Facility Safety Basis and Design Development. This report documents the results of an independent oversight review of the safety basis and design development for the Salt Waste Processing Facility (SWPF) at the U.S. Department of Energy (DOE)

  12. Combinations of fluorinated solvents with imide salts or methide salts for electrolytes

    DOE Patents [OSTI]

    Tikhonov, Konstantin; Yip, Ka Ki; Lin, Tzu-Yuan; Lei, Norman; Guerrero-Zavala, Guillermo; Kwong, Kristie W

    2015-11-10

    Provided are electrochemical cells and electrolytes used to build such cells. The electrolytes include imide salts and/or methide salts as well as fluorinated solvents capable of maintaining single phase solutions at between about -30.degree. C. to about 80.degree. C. The fluorinated solvents, such as fluorinated carbonates, fluorinated esters, and fluorinated esters, are less flammable than their non-fluorinated counterparts and improve safety characteristics of cells containing these solvents. The amount of fluorinated solvents in electrolytes may be between about 30% and 80% by weight not accounting weight of the salts. Linear and cyclic imide salts, such as LiN(SO.sub.2CF.sub.2CF.sub.3).sub.2, and LiN(SO.sub.2CF.sub.3).sub.2, as well as methide salts, such as LiC(SO.sub.2CF.sub.3).sub.3 and LiC(SO.sub.2CF.sub.2CF.sub.3).sub.3, may be used in these electrolytes. Fluorinated alkyl groups enhance solubility of these salts in the fluorinated solvents. In some embodiments, the electrolyte may also include a flame retardant, such as a phosphazene, and/or one or more ionic liquids.

  13. SOLUTION MINING IN SALT DOMES OF THE GULF COAST EMBAYMENT

    SciTech Connect (OSTI)

    Griswold, G. B.

    1981-02-01

    Following a description of salt resources in the salt domes of the gulf coast embayment, mining, particularly solution mining, is described. A scenario is constructed which could lead to release of radioactive waste stored in a salt dome via inadvertent solution mining and the consequences of this scenario are analyzed.

  14. EIA - Natural Gas Pipeline Network - Salt Cavern Storage Reservoir

    Gasoline and Diesel Fuel Update (EIA)

    Configuration Salt Cavern Storage Reservoir Configuration About U.S. Natural Gas Pipelines - Transporting Natural Gas based on data through 2007/2008 with selected updates Salt Cavern Underground Natural Gas Storage Reservoir Configuration Salt Cavern Underground Natural Gas Storage Reservoir Configuration Source: PB Energy Storage Services Inc.

  15. Production of carboxylic acid and salt co-products

    DOE Patents [OSTI]

    Hanchar, Robert J.; Kleff, Susanne; Guettler, Michael V.

    2014-09-09

    This invention provide processes for producing carboxylic acid product, along with useful salts. The carboxylic acid product that is produced according to this invention is preferably a C.sub.2-C.sub.12 carboxylic acid. Among the salts produced in the process of the invention are ammonium salts.

  16. Combined Extraction of Cesium and Strontium from Akaline Nitrate Solutions

    SciTech Connect (OSTI)

    Delmau, Laetitia Helene; Bonnesen, Peter V; Engle, Nancy L; Haverlock, Tamara; Sloop Jr, Frederick {Fred} V; Moyer, Bruce A

    2006-01-01

    The combined extraction of cesium and strontium from caustic wastes can be achieved by adding a crown ether and a carboxylic acid to the Caustic-Side Solvent Extraction (CSSX) solvent. The ligand 4,4'(5')-di(tert-butyl)cyclohexano-18-crown-6 and one of four different carboxylic acids were combined with the components of the CSSX solvent optimized for the extraction of cesium, allowing for the simultaneous extraction of cesium and strontium from alkaline nitrate media simulating alkaline high level wastes present at the U.S. Department of Energy Savannah River Site. Extraction and stripping experiments were conducted independently and exhibited adequate results for mimicking waste simulant processing through batch contacts. The promising results of these batch tests showed that the system could reasonably be tested on actual waste.

  17. Analysis of Enriched Uranyl Nitrate in Nested Annular Tank Array

    SciTech Connect (OSTI)

    John D. Bess; James D. Cleaver

    2009-06-01

    Two series of experiments were performed at the Rocky Flats Critical Mass Laboratory during the 1980s using highly enriched (93%) uranyl nitrate solution in annular tanks. [1, 2] Tanks were of typical sizes found in nuclear production plants. Experiments looked at tanks of varying radii in a co-located set of nested tanks, a 1 by 2 array, and a 1 by 3 array. The co-located set of tanks had been analyzed previously [3] as a benchmark for inclusion within the International Handbook of Evaluated Criticality Safety Benchmark Experiments. [4] The current study represents the benchmark analysis of the 1 by 3 array of a series of nested annular tanks. Of the seventeen configurations performed in this set of experiments, twelve were evaluated and nine were judged as acceptable benchmarks.

  18. Hydroxylamine Nitrate Decomposition under Non-radiological Conditions

    SciTech Connect (OSTI)

    McFarlane, Joanna; Delmau, Laetitia Helene; DePaoli, David W.; Mattus, Catherine H.; Phelps, Clarice E.; Roach, Benjamin D.

    2015-07-01

    Hydroxylamine nitrate (HAN) is used to reduce Pu(IV) to Pu(III) in the separation of plutonium from uranium. HAN becomes unstable under certain conditions and has been known to explode, causing injury to humans including death. Hence, it is necessary to deactivate HAN once the reduction of plutonium is finished. This report reviews what is known about the chemistry of HAN and various methods to achieve a safe decomposition. However, there are areas where more information is needed to make a decision about the handling of HAN in reprocessing of nuclear fuel. Experiments have demonstrated a number of non-radiolytic ways to safely decompose HAN, including heating in HNO3, photolytic oxidation in the presence of H2O2, and the addition of a metal such as Fe(III) that will oxidize the HAN.

  19. Salt Lake City, Utah, Processing and Disposal Sites Fact Sheet

    Office of Legacy Management (LM)

    Salt Lake City, Utah, Processing and Disposal Sites This fact sheet provides information about the Uranium Mill Tailings Radiation Control Act of 1978 Title I processing site and disposal site at Salt Lake City, Utah. These sites are managed by the U.S. Department of Energy Office of Legacy Management. Locations of the Salt Lake City Processing and Disposal Sites Site Descriptions and History The former Salt Lake City processing site is located about 4 miles south-southwest of the center of Salt

  20. Climate Action Champions: Salt Lake City, UT | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Salt Lake City, UT Climate Action Champions: Salt Lake City, UT Salt Lake City, the capital of Utah, blends snowy mountain ranges with an urban downtown. Known historically as the “Crossroads of the West,” Salt Lake City today is a major economic center in the Great Basin and a hub of tourism. │ Photo courtesy of University of Utah Department of Mathematics. Salt Lake City, the capital of Utah, blends snowy mountain ranges with an urban downtown. Known historically as the

  1. Method to Reduce Molten Salt Penetration into Bulk Vitrification Refractory Materials

    SciTech Connect (OSTI)

    Bagaasen, L.M.; Hrma, P.R.; Kim, D.S.; Schweiger, M.J.; Matyas, J.; Rodriguez, C.P. [Pacific Northwest National Laboratory, Richland WA (United States); Witwer, K.S. [AMEC Nuclear Holdings Ltd., GeoMelt Division, Richland, WA (United States)

    2008-07-01

    Bulk vitrification (BV) is a process that heats a feed material consisting of glass-forming solids and dried low-activity waste (LAW) in a disposable refractory-lined metal box using electrical power supplied through carbon electrodes. The feed is heated to the point that the LAW decomposes and combines with the solids to generate a vitreous waste form. However, the castable refractory block (CRB) portion of the refractory lining has sufficient porosity to allow the low-viscosity molten ionic salt (MIS), which contains technetium (Tc) in a soluble form, to penetrate the CRB. This limits the effectiveness of the final waste form. This paper describes tests conducted to develop a method aimed at reducing the quantities of soluble Tc in the CRB. Tests showed that MIS formed in significant quantities at temperatures above 300 deg. C, remained stable until roughly 550 deg. C where it began to thermally decompose, and was completely decomposed by 800 deg. C. The estimated volume fraction of MIS in the feed was greater than 40%, and the CRB material contained 11 to 15% open porosity, a combination allowing a large quantity of MIS to migrate through the feed and penetrate the open porosity of the CRB. If the MIS is decomposed at temperatures below 300 deg. C or can be contained in the feed until it fully decomposes by 800 deg. C, MIS migration into the CRB can be avoided. Laboratory and crucible-scale experiments showed that a variety of methods, individually or in combination, can decrease MIS penetration into the CRB. Modifying the CRB to block MIS penetration was not deemed practical as a method to prevent the large quantities of MIS penetration seen in the full-scale tests, but it may be useful to reduce the impacts of lower levels of MIS penetration. Modifying the BV feed materials to better contain the MIS proved to be more successful. A series of qualitative and quantitative crucible tests were developed that allowed screening of feed modifications that might be used to reduce MIS penetration. These tests showed that increasing the specific surface area of the soil (used as the primary glass-forming solid in the baseline process) by grinding stopped MIS penetration nearly entirely for feeds that contained waste simulants with lower quantities of nitrate salts. Grinding soil significantly reduced MIS penetration in feeds with higher nitrate quantities, but it was necessary to add carbohydrates (sucrose or cellulose) to destroy a portion of the nitrate at low temperatures to reach the same low levels of MIS penetration seen for the lower nitrate feeds. Developing feeds to reduce MIS penetration in full-scale BV applications resulted in two additional refinements. Soil-grinding to the necessary levels proved to be difficult and expensive, so the fine soil was replaced with readily available fine-grained glass-forming minerals. Cellulose was shown to have less impact on dryer operation than sucrose and was chosen as the carbohydrate source to use in subsequent engineering- and full-scale tests. (authors)

  2. Stationary phase deposition based on onium salts

    DOE Patents [OSTI]

    Wheeler, David R. (Albuquerque, NM); Lewis, Patrick R. (Albuquerque, NM); Dirk, Shawn M. (Albuquerque, NM); Trudell, Daniel E. (Albuquerque, NM)

    2008-01-01

    Onium salt chemistry can be used to deposit very uniform thickness stationary phases on the wall of a gas chromatography column. In particular, the stationary phase can be bonded to non-silicon based columns, especially microfabricated metal columns. Non-silicon microfabricated columns may be manufactured and processed at a fraction of the cost of silicon-based columns. In addition, the method can be used to phase-coat conventional capillary columns or silicon-based microfabricated columns.

  3. Advanced heat exchanger development for molten salts

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Sabharwall, Piyush; Clark, Denis; Glazoff, Michael; Zheng, Guiqiu; Sridharan, Kumar; Anderson, Mark

    2014-12-01

    This study addresses present work concerned with advanced heat exchanger development for molten salt in nuclear and non nuclear thermal systems. The molten salt systems discussed herein use alloys, such as Hastelloy N and 242, which show corrosion resistance to molten salt at nominal operating temperatures up to 700°C. These alloys were diffusion welded, and the corresponding information is presented. Test specimens were prepared for exposing diffusion welds to molten salt environments. Hastelloy N and 242 were found to be weldable by diffusion welding, with ultimate tensile strengths about 90% of base metal values. Both diffusion welds and sheet materialmore » in Hastelloy N were corrosion tested in?58 mol% KF and 42 mol% ZrF4 at 650, 700, and 850°C for 200, 500, and 1,000 hours. Corrosion rates found were similar between welded and nonwelded materials, typically <10 mils per year. For materials of construction, nickel and alloys with dense nickel coatings are effectively inert to corrosion in fluorides, but not so in chlorides. Hence, additional testing of selected alloys for resistance to intergranular corrosion is needed, as is a determination of corrosion rate as a function of contaminant type and alloy composition with respect to chromium and carbon to better define the optimal chromium and carbon composition, independent of galvanic or differential solubility effects. Also presented is the division of the nuclear reactor and high temperature components per ASME standards, along with design requirements for a subcritical Rankine power cycle heat exchanger that has to overcome pressure difference of about 17 MPa.« less

  4. Advanced heat exchanger development for molten salts

    SciTech Connect (OSTI)

    Sabharwall, Piyush; Clark, Denis; Glazoff, Michael; Zheng, Guiqiu; Sridharan, Kumar; Anderson, Mark

    2014-12-01

    This study addresses present work concerned with advanced heat exchanger development for molten salt in nuclear and non nuclear thermal systems. The molten salt systems discussed herein use alloys, such as Hastelloy N and 242, which show corrosion resistance to molten salt at nominal operating temperatures up to 700°C. These alloys were diffusion welded, and the corresponding information is presented. Test specimens were prepared for exposing diffusion welds to molten salt environments. Hastelloy N and 242 were found to be weldable by diffusion welding, with ultimate tensile strengths about 90% of base metal values. Both diffusion welds and sheet material in Hastelloy N were corrosion tested in?58 mol% KF and 42 mol% ZrF4 at 650, 700, and 850°C for 200, 500, and 1,000 hours. Corrosion rates found were similar between welded and nonwelded materials, typically <10 mils per year. For materials of construction, nickel and alloys with dense nickel coatings are effectively inert to corrosion in fluorides, but not so in chlorides. Hence, additional testing of selected alloys for resistance to intergranular corrosion is needed, as is a determination of corrosion rate as a function of contaminant type and alloy composition with respect to chromium and carbon to better define the optimal chromium and carbon composition, independent of galvanic or differential solubility effects. Also presented is the division of the nuclear reactor and high temperature components per ASME standards, along with design requirements for a subcritical Rankine power cycle heat exchanger that has to overcome pressure difference of about 17 MPa.

  5. Parsons Salt Water Processing Facility Construction Project

    Office of Environmental Management (EM)

    Parsons Corporation Salt Waste Processing Facility Construction Project Report from the Department of Energy Voluntary Protection Program Onsite Review February 5-14, 2013 U.S. Department of Energy Office of Health, Safety and Security Office of Health and Safety Office of Worker Safety and Health Assistance Washington, DC 20585 Parsons Corporation SWPF Construction Project DOE-VPP Onsite Review February 2013 Foreword The Department of Energy (DOE) recognizes that true excellence can be

  6. Advanced heat exchanger development for molten salts

    SciTech Connect (OSTI)

    Sabharwall, Piyush; Clark, Denis; Glazoff, Michael; Zheng, Guiqiu; Sridharan, Kumar; Anderson, Mark

    2014-12-01

    This study addresses present work concerned with advanced heat exchanger development for molten salt in nuclear and non nuclear thermal systems. The molten salt systems discussed herein use alloys, such as Hastelloy N and 242, which show corrosion resistance to molten salt at nominal operating temperatures up to 700C. These alloys were diffusion welded, and the corresponding information is presented. Test specimens were prepared for exposing diffusion welds to molten salt environments. Hastelloy N and 242 were found to be weldable by diffusion welding, with ultimate tensile strengths about 90% of base metal values. Both diffusion welds and sheet material in Hastelloy N were corrosion tested in?58 mol% KF and 42 mol% ZrF4 at 650, 700, and 850C for 200, 500, and 1,000 hours. Corrosion rates found were similar between welded and nonwelded materials, typically <10 mils per year. For materials of construction, nickel and alloys with dense nickel coatings are effectively inert to corrosion in fluorides, but not so in chlorides. Hence, additional testing of selected alloys for resistance to intergranular corrosion is needed, as is a determination of corrosion rate as a function of contaminant type and alloy composition with respect to chromium and carbon to better define the optimal chromium and carbon composition, independent of galvanic or differential solubility effects. Also presented is the division of the nuclear reactor and high temperature components per ASME standards, along with design requirements for a subcritical Rankine power cycle heat exchanger that has to overcome pressure difference of about 17 MPa.

  7. 2015 VIII MECHANICAL BEHAVIOR OF SALT

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    VIII MECHANICAL BEHAVIOR OF SALT - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management Programs

  8. Salt Lake City | National Nuclear Security Administration

    National Nuclear Security Administration (NNSA)

    Salt Lake City | National Nuclear Security Administration Facebook Twitter Youtube Flickr RSS People Mission Managing the Stockpile Preventing Proliferation Powering the Nuclear Navy Emergency Response Recapitalizing Our Infrastructure Countering Nuclear Terrorism About Our Programs Our History Who We Are Our Leadership Our Locations Budget Our Operations Library Bios Congressional Testimony Fact Sheets Newsletters Press Releases Photo Gallery Jobs Apply for Our Jobs Our Jobs Working at NNSA

  9. Waste Isolation Pilot Plant Salt Decontamination Testing

    SciTech Connect (OSTI)

    Rick Demmer; Stephen Reese

    2014-09-01

    On February 14, 2014, americium and plutonium contamination was released in the Waste Isolation Pilot Plant (WIPP) salt caverns. At the request of WIPPs operations contractor, Idaho National Laboratory (INL) personnel developed several methods of decontaminating WIPP salt, using surrogate contaminants and also americium (241Am). The effectiveness of the methods is evaluated qualitatively, and to the extent possible, quantitatively. One of the requirements of this effort was delivering initial results and recommendations within a few weeks. That requirement, in combination with the limited scope of the project, made in-depth analysis impractical in some instances. Of the methods tested (dry brushing, vacuum cleaning, water washing, strippable coatings, and mechanical grinding), the most practical seems to be water washing. Effectiveness is very high, and it is very easy and rapid to deploy. The amount of wastewater produced (2 L/m2) would be substantial and may not be easy to manage, but the method is the clear winner from a usability perspective. Removable surface contamination levels (smear results) from the strippable coating and water washing coupons found no residual removable contamination. Thus, whatever is left is likely adhered to (or trapped within) the salt. The other option that shows promise is the use of a fixative barrier. Bartlett Nuclear, Inc.s Polymeric Barrier System (PBS) proved the most durable of the coatings tested. The coatings were not tested for contaminant entrapment, only for coating integrity and durability.

  10. Polymeric salt bridges for conducting electric current in microfluidic devices

    DOE Patents [OSTI]

    Shepodd, Timothy J. (Livermore, CA); Tichenor, Mark S. (San Diego, CA); Artau, Alexander (Humacao, PR)

    2009-11-17

    A "cast-in-place" monolithic microporous polymer salt bridge for conducting electrical current in microfluidic devices, and methods for manufacture thereof is disclosed. Polymeric salt bridges are formed in place in capillaries or microchannels. Formulations are prepared with monomer, suitable cross-linkers, solvent, and a thermal or radiation responsive initiator. The formulation is placed in a desired location and then suitable radiation such as UV light is used to polymerize the salt bridge within a desired structural location. Embodiments are provided wherein the polymeric salt bridges have sufficient porosity to allow ionic migration without bulk flow of solvents therethrough. The salt bridges form barriers that seal against fluid pressures in excess of 5000 pounds per square inch. The salt bridges can be formulated for carriage of suitable amperage at a desired voltage, and thus microfluidic devices using such salt bridges can be specifically constructed to meet selected analytical requirements.

  11. An Overview of Liquid Fluoride Salt Heat Transport Technology

    SciTech Connect (OSTI)

    Cetiner, Mustafa Sacit; Holcomb, David Eugene

    2010-01-01

    Liquid fluoride salts are a leading candidate heat transport medium for high-temperature applications. This report provides an overview of the current status of liquid salt heat transport technology. The report includes a high-level, parametric evaluation of liquid fluoride salt heat transport loop performance to allow intercomparisons between heat-transport fluid options as well as providing an overview of the properties and requirements for a representative loop. Much of the information presented here derives from the earlier molten salt reactor program and a significant advantage of fluoride salts, as high temperature heat transport media is their consequent relative technological maturity. The report also includes a compilation of relevant thermophysical properties of useful heat transport fluoride salts. Fluoride salts are both thermally stable and with proper chemistry control can be relatively chemically inert. Fluoride salts can, however, be highly corrosive depending on the container materials selected, the salt chemistry, and the operating procedures used. The report also provides an overview of the state-of-the-art in reduction-oxidation chemistry control methodologies employed to minimize salt corrosion as well as providing a general discussion of heat transfer loop operational issues such as start-up procedures and freeze-up vulnerability.

  12. Tank 37H Salt Removal Batch Process and Salt Dissolution Mixing Study

    SciTech Connect (OSTI)

    Kwon, K.C.

    2001-09-18

    Tank 30H is the receipt tank for concentrate from the 3H Evaporator. Tank 30H has had problems, such as cooling coil failure, which limit its ability to receive concentrate from the 3H Evaporator. SRS High Level Waste wishes to use Tank 37H as the receipt tank for the 3H Evaporator concentrate. Prior to using Tank 37H as the 3H Evaporator concentrate receipt tank, HLW must remove 50 inches of salt cake from the tank. They requested SRTC to evaluate various salt removal methods for Tank 37H. These methods include slurry pumps, Flygt mixers, the modified density gradient method, and molecular diffusion.

  13. Salt disposal of heat-generating nuclear waste.

    SciTech Connect (OSTI)

    Leigh, Christi D.; Hansen, Francis D.

    2011-01-01

    This report summarizes the state of salt repository science, reviews many of the technical issues pertaining to disposal of heat-generating nuclear waste in salt, and proposes several avenues for future science-based activities to further the technical basis for disposal in salt. There are extensive salt formations in the forty-eight contiguous states, and many of them may be worthy of consideration for nuclear waste disposal. The United States has extensive experience in salt repository sciences, including an operating facility for disposal of transuranic wastes. The scientific background for salt disposal including laboratory and field tests at ambient and elevated temperature, principles of salt behavior, potential for fracture damage and its mitigation, seal systems, chemical conditions, advanced modeling capabilities and near-future developments, performance assessment processes, and international collaboration are all discussed. The discussion of salt disposal issues is brought current, including a summary of recent international workshops dedicated to high-level waste disposal in salt. Lessons learned from Sandia National Laboratories' experience on the Waste Isolation Pilot Plant and the Yucca Mountain Project as well as related salt experience with the Strategic Petroleum Reserve are applied in this assessment. Disposal of heat-generating nuclear waste in a suitable salt formation is attractive because the material is essentially impermeable, self-sealing, and thermally conductive. Conditions are chemically beneficial, and a significant experience base exists in understanding this environment. Within the period of institutional control, overburden pressure will seal fractures and provide a repository setting that limits radionuclide movement. A salt repository could potentially achieve total containment, with no releases to the environment in undisturbed scenarios for as long as the region is geologically stable. Much of the experience gained from United States repository development, such as seal system design, coupled process simulation, and application of performance assessment methodology, helps define a clear strategy for a heat-generating nuclear waste repository in salt.

  14. Conceptual Design of a 100 MWe Modular Molten Salt Power Tower Plant

    SciTech Connect (OSTI)

    James E. Pacheco; Carter Moursund, Dale Rogers, David Wasyluk

    2011-09-20

    A conceptual design of a 100 MWe modular molten salt solar power tower plant has been developed which can provide capacity factors in the range of 35 to 75%. Compared to single tower plants, the modular design provides a higher degree of flexibility in achieving the desired customer's capacity factor and is obtained simply by adjusting the number of standard modules. Each module consists of a standard size heliostat field and receiver system, hence reengineering and associated unacceptable performance uncertainties due to scaling are eliminated. The modular approach with multiple towers also improves plant availability. Heliostat field components, receivers and towers are shop assembled allowing for high quality and minimal field assembly. A centralized thermal-storage system stores hot salt from the receivers, allowing nearly continuous power production, independent of solar energy collection, and improved parity with the grid. A molten salt steam generator converts the stored thermal energy into steam, which powers a steam turbine generator to produce electricity. This paper describes the conceptual design of the plant, the advantages of modularity, expected performance, pathways to cost reductions, and environmental impact.

  15. Supai salt karst features: Holbrook Basin, Arizona

    SciTech Connect (OSTI)

    Neal, J.T.

    1994-12-31

    More than 300 sinkholes, fissures, depressions, and other collapse features occur along a 70 km (45 mi) dissolution front of the Permian Supai Formation, dipping northward into the Holbrook Basin, also called the Supai Salt Basin. The dissolution front is essentially coincident with the so-called Holbrook Anticline showing local dip reversal; rather than being of tectonic origin, this feature is likely a subsidence-induced monoclinal flexure caused by the northward migrating dissolution front. Three major areas are identified with distinctive attributes: (1) The Sinks, 10 km WNW of Snowflake, containing some 200 sinkholes up to 200 m diameter and 50 m depth, and joint controlled fissures and fissure-sinks; (2) Dry Lake Valley and contiguous areas containing large collapse fissures and sinkholes in jointed Coconino sandstone, some of which drained more than 50 acre-feet ({approximately}6 {times} 10{sup 4} m{sup 3}) of water overnight; and (3) the McCauley Sinks, a localized group of about 40 sinkholes 15 km SE of Winslow along Chevelon Creek, some showing essentially rectangular jointing in the surficial Coconino Formation. Similar salt karst features also occur between these three major areas. The range of features in Supai salt are distinctive, yet similar to those in other evaporate basins. The wide variety of dissolution/collapse features range in development from incipient surface expression to mature and old age. The features began forming at least by Pliocene time and continue to the present, with recent changes reportedly observed and verified on airphotos with 20 year repetition. The evaporate sequence along interstate transportation routes creates a strategic location for underground LPG storage in leached caverns. The existing 11 cavern field at Adamana is safely located about 25 miles away from the dissolution front, but further expansion initiatives will require thorough engineering evaluation.

  16. Ab initio calculations of singlet and triplet excited states of chlorine nitrate and nitric acid

    SciTech Connect (OSTI)

    Grana, A.M.; Head-Gordon, M. |; Lee, T.J.

    1995-03-16

    Ab initio calculations of vertical excitations to single and triplet excited states of chlorine nitrate and nitric acid are reported, using the CIS, CIS(D), and CCSD methods. The effects of basis set composition and calculational methods are investigated. The nature of the electronic transitions are examined by decomposing the difference density into the sum of detachment and attachment densities. Counterparts for the three lowest singlet excited states of nitric acid survive relatively unperturbed in chlorine nitrate, while other low lying singlet states of chlorine nitrate appear to be directly dissociative in the CIO chromophore. These results suggest an assignment of the two main peaks in the experimental chlorine nitrate absorption spectrum. In addition, triplet vertical excitations and the lowest optimized triplet geometries of both molecules are studied. 70 refs., 2 figs., 6 tabs.

  17. USAID-Central Asian Republics Climate Activities | Open Energy...

    Open Energy Info (EERE)

    ourwork Country Kazakhstan, Uzbekistan, Turkmenistan, Kyrgyzstan, Tajikistan Central Asia, Central Asia, Central Asia, Central Asia, Central Asia References USAID Climate...

  18. FNAL central email systems

    SciTech Connect (OSTI)

    Schmidt, Jack; Lilianstrom, Al; Pasetes, Ray; Hill, Kevin; /Fermilab

    2004-10-01

    The FNAL Email System is the primary point of entry for email destined for an employee or user at Fermilab. This centrally supported system is designed for reliability and availability. It uses multiple layers of protection to help ensure that: (1) SPAM messages are tagged properly; (2) All mail is inspected for viruses; and (3) Valid mail gets delivered. This system employs numerous redundant subsystems to accomplish these tasks.

  19. the Central Basin Platform,

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    q / ~ ~ - ~ / o o f - - 2 3 - / % 8 Overview of the Structural Geology and Tectonics of the Central Basin Platform, Delaware Basin, and Midland Basin, West Texas and New Mexico T . Hoaka, K. Sundbergb, and P. Ortolevac a Kestrel Geoscience, LLC 9683 West Chatfield Avenue, Unit D Littleton, Colorado 80128 b Phillips Petroleum Company 252 Geoscience Building Bartlesville, Oklahoma 74003 c Laboratory for Computational Geodynamics Department of Chemistry Indiana University Bloomington, Indiana 47405

  20. Molecular dynamics study of saltsolution interface: Solubility and surface charge of salt in water

    SciTech Connect (OSTI)

    Kobayashi, Kazuya; Liang, Yunfeng E-mail: matsuoka@earth.kumst.kyoto-u.ac.jp; Matsuoka, Toshifumi E-mail: matsuoka@earth.kumst.kyoto-u.ac.jp; Sakka, Tetsuo

    2014-04-14

    The NaCl saltsolution interface often serves as an example of an uncharged surface. However, recent laser-Doppler electrophoresis has shown some evidence that the NaCl crystal is positively charged in its saturated solution. Using molecular dynamics (MD) simulations, we have investigated the NaCl saltsolution interface system, and calculated the solubility of the salt using the direct method and free energy calculations, which are kinetic and thermodynamic approaches, respectively. The direct method calculation uses a saltsolution combined system. When the system is equilibrated, the concentration in the solution area is the solubility. In the free energy calculation, we separately calculate the chemical potential of NaCl in two systems, the solid and the solution, using thermodynamic integration with MD simulations. When the chemical potential of NaCl in the solution phase is equal to the chemical potential of the solid phase, the concentration of the solution system is the solubility. The advantage of using two different methods is that the computational methods can be mutually verified. We found that a relatively good estimate of the solubility of the system can be obtained through comparison of the two methods. Furthermore, we found using microsecond time-scale MD simulations that the positively charged NaCl surface was induced by a combination of a sodium-rich surface and the orientation of the interfacial water molecules.

  1. In situ mobility of uranium in the presence of nitrate following

    Office of Scientific and Technical Information (OSTI)

    sulfate-reducing conditions (Journal Article) | DOE PAGES Published Article: In situ mobility of uranium in the presence of nitrate following sulfate-reducing conditions « Prev Next » Title: In situ mobility of uranium in the presence of nitrate following sulfate-reducing conditions Authors: Paradis, Charles J. ; Jagadamma, Sindhu ; Watson, David B. ; McKay, Larry D. ; Hazen, Terry C. ; Park, Melora ; Istok, Jonathan D. Publication Date: 2016-04-01 OSTI Identifier: 1237977 Grant/Contract

  2. Independent Oversight Assessment, Salt Waste Processing Facility Project -

    Office of Environmental Management (EM)

    January 2013 | Department of Energy Salt Waste Processing Facility Project - January 2013 Independent Oversight Assessment, Salt Waste Processing Facility Project - January 2013 January 2013 Assessment of Nuclear Safety Culture at the Salt Waste Processing Facility Project The U.S. Department of Energy (DOE) Office of Enforcement and Oversight (Independent Oversight), within the Office of Health, Safety and Security (HSS), conducted an independent assessment of nuclear safety culture at the

  3. Notice of Availability of Section 3116 Determination for Salt Waste

    Office of Environmental Management (EM)

    Disposal at the Savannah River Site | Department of Energy Notice of Availability of Section 3116 Determination for Salt Waste Disposal at the Savannah River Site Notice of Availability of Section 3116 Determination for Salt Waste Disposal at the Savannah River Site The Department of Energy (DOE) announces the availability of a section 3116 determination for the disposal of separated, solidified, low-activity salt waste at the Savannah River Site (SRS) near Aiken, South Carolina. PDF icon

  4. Salt Waste Processing Facility Fact Sheet | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Waste Management » Tank Waste and Waste Processing » Salt Waste Processing Facility Fact Sheet Salt Waste Processing Facility Fact Sheet Nuclear material production operations at SRS resulted in the generation of liquid radioactive waste that is being stored, on an interim basis, in 49 underground waste storage tanks in the F- and H-Area Tank Farms. PDF icon SWPF Fact Sheet More Documents & Publications Savannah River Site Salt Waste Processing Facility Technology Readiness Assessment

  5. Section 3116 Waste Determinationfor Salt Disposal at the Savannah River

    Office of Environmental Management (EM)

    Site, signed by Secretary of Energy, Samuel W. Bodman | Department of Energy Section 3116 Waste Determinationfor Salt Disposal at the Savannah River Site, signed by Secretary of Energy, Samuel W. Bodman Section 3116 Waste Determinationfor Salt Disposal at the Savannah River Site, signed by Secretary of Energy, Samuel W. Bodman PDF icon Section 3116 Waste Determinationfor Salt Disposal at the Savannah River Site, signed by Secretary of Energy, Samuel W. Bodman More Documents &

  6. Voluntary Protection Program Onsite Review, Salt Waste Processing Facility

    Energy Savers [EERE]

    Construction Project - February 2013 | Department of Energy Salt Waste Processing Facility Construction Project - February 2013 Voluntary Protection Program Onsite Review, Salt Waste Processing Facility Construction Project - February 2013 February 2013 Evaluation to determine whether Salt Waste Processing Facility Construction Project is continuing to perform at a level deserving DOE-VPP Star recognition. The Team conducted its review during February 5 - 14, 2013 to determine whether

  7. Voluntary Protection Program Onsite Review, Parsons Corp., Salt Waste

    Office of Environmental Management (EM)

    Processing Facility Construction Project - May 2014 | Department of Energy Corp., Salt Waste Processing Facility Construction Project - May 2014 Voluntary Protection Program Onsite Review, Parsons Corp., Salt Waste Processing Facility Construction Project - May 2014 May 2014 Evaluation to determine whether Parsons SWPF is performing at a level deserving DOE-VPP Star recognition PDF icon Voluntary Protection Program Onsite Review, Parsons Corp., Salt Waste Processing Facility Construction

  8. DOE Issues Salt Waste Determination for the Savannah River Site |

    Energy Savers [EERE]

    Department of Energy Salt Waste Determination for the Savannah River Site DOE Issues Salt Waste Determination for the Savannah River Site January 18, 2006 - 10:49am Addthis WASHINGTON, DC - The U.S. Department of Energy (DOE) today issued the waste determination for the treatment and stabilization of low activity salt-waste at the Savannah River Site allowing for significant reductions in environmental and health risks posed by the material. Stored in forty-nine underground tanks,

  9. Project Profile: Deep Eutectic Salt Formulations Suitable as Advanced Heat

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Transfer Fluids | Department of Energy Concentrating Solar Power » Project Profile: Deep Eutectic Salt Formulations Suitable as Advanced Heat Transfer Fluids Project Profile: Deep Eutectic Salt Formulations Suitable as Advanced Heat Transfer Fluids Halotechnics logo Halotechnics, under the Thermal Storage FOA, is conducting high-throughput, combinatorial research and development of salt formulations for use as highly efficient heat transfer fluids (HTFs). Approach Robotic high-throughput

  10. Project Profile: Novel Molten Salts Thermal Energy Storage for

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Concentrating Solar Power Generation | Department of Energy Novel Molten Salts Thermal Energy Storage for Concentrating Solar Power Generation Project Profile: Novel Molten Salts Thermal Energy Storage for Concentrating Solar Power Generation Alabama logo The University of Alabama, under the Thermal Storage FOA, is developing thermal energy storage (TES) media consisting of low melting point (LMP) molten salt with high TES density for sensible heat storage systems. Approach They will conduct

  11. Enterprise Assessments Salt Waste Processing Facility Construction Quality

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and Fire Protection Systems Follow-up Review at the Savannah River Site - January 2016 | Department of Energy Salt Waste Processing Facility Construction Quality and Fire Protection Systems Follow-up Review at the Savannah River Site - January 2016 Enterprise Assessments Salt Waste Processing Facility Construction Quality and Fire Protection Systems Follow-up Review at the Savannah River Site - January 2016 February 2016 Follow-up Review of the Salt Waste Processing Systems and Fire

  12. Salts of alkali metal anions and process of preparing same

    DOE Patents [OSTI]

    Dye, James L.; Ceraso, Joseph M.; Tehan, Frederick J.; Lok, Mei Tak

    1978-01-01

    Compounds of alkali metal anion salts of alkali metal cations in bicyclic polyoxadiamines are disclosed. The salts are prepared by contacting an excess of alkali metal with an alkali metal dissolving solution consisting of a bicyclic polyoxadiamine in a suitable solvent, and recovered by precipitation. The salts have a gold-color crystalline appearance and are stable in a vacuum at -10.degree. C. and below.

  13. Test Proposal Document for Phased Field Thermal Testing in Salt |

    Energy Savers [EERE]

    Department of Energy Test Proposal Document for Phased Field Thermal Testing in Salt Test Proposal Document for Phased Field Thermal Testing in Salt The document summarizes how a new round of staged thermal field testing will help to augment the safety case for disposal of heat generating nuclear waste in salt. The objectives of the proposed test plan are to: (1) address features, events, and processes (FEPs), (2) build scientific and public confidence, (3) foster international

  14. Salt Lake County Residential Solar Financing Study | Department of Energy

    Energy Savers [EERE]

    Salt Lake County Residential Solar Financing Study Salt Lake County Residential Solar Financing Study As part of our engagement with the National Renewable Energy Laboratories conducting the Salt Lake County Solar America Residential Finance Study, we have drafted this report summarizing the tools and mechanisms available for residential solar projects. These include the financial incentives available, possible financing models that could be used in the County, and a review of the

  15. Delivery system for molten salt oxidation of solid waste

    DOE Patents [OSTI]

    Brummond, William A. (Livermore, CA); Squire, Dwight V. (Livermore, CA); Robinson, Jeffrey A. (Manteca, CA); House, Palmer A. (Walnut Creek, CA)

    2002-01-01

    The present invention is a delivery system for safety injecting solid waste particles, including mixed wastes, into a molten salt bath for destruction by the process of molten salt oxidation. The delivery system includes a feeder system and an injector that allow the solid waste stream to be accurately metered, evenly dispersed in the oxidant gas, and maintained at a temperature below incineration temperature while entering the molten salt reactor.

  16. Independent Oversight Review, Savannah River Site Salt Waste Processing

    Energy Savers [EERE]

    Facility - April 2014 | Department of Energy Salt Waste Processing Facility - April 2014 Independent Oversight Review, Savannah River Site Salt Waste Processing Facility - April 2014 April 2014 Review of the Savannah River Site Salt Waste Processing Facility Construction Quality and Fire Protection Systems The U.S. Department of Energy (DOE) Office of Enforcement and Oversight (Independent Oversight), within the Office of Health, Safety and Security, conducted an independent review of the

  17. DOE - Office of Legacy Management -- Penn Salt Manufacturing Co Whitemarsh

    Office of Legacy Management (LM)

    Research Laboratories - PA 20 Salt Manufacturing Co Whitemarsh Research Laboratories - PA 20 FUSRAP Considered Sites Site: PENN SALT MANUFACTURING CO., WHITEMARSH RESEARCH LABORATORIES (PA.20) Eliminated from further consideration under FUSRAP Designated Name: Not Designated Alternate Name: Penn Salt Company PA.20-1 Location: Philiadelphia , Pennsylvania PA.20-1 Evaluation Year: 1987 PA.20-1 Site Operations: Conducted process studies for recovery of uranium from fluoride scrap. PA.20-1 Site

  18. Salt River Electric- Residential Energy Efficiency Rebate Programs

    Broader source: Energy.gov [DOE]

    Salt River Electric serves as the rural electric provider in Kentucky's Bullitt, Nelson, Spencer, and Washington counties. Residential customers are eligible for a variety of cash incentives for...

  19. Salt Lake City, Utah: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Salt Lake City, Utah: Energy Resources Jump to: navigation, search Equivalent URI DBpedia Coordinates 40.7607793, -111.8910474 Show Map Loading map... "minzoom":false,"mapping...

  20. Salt Wells Geothermal Energy Projects Environmental Impact Statement...

    Open Energy Info (EERE)

    Jump to: navigation, search OpenEI Reference LibraryAdd to library Web Site: Salt Wells Geothermal Energy Projects Environmental Impact Statement Abstract Abstract unavailable....

  1. Molten salt bath circulation design for an electrolytic cell

    DOE Patents [OSTI]

    Dawless, R.K.; LaCamera, A.F.; Troup, R.L.; Ray, S.P.; Hosler, R.B.

    1999-08-17

    An electrolytic cell for reduction of a metal oxide to a metal and oxygen has an inert anode and an upwardly angled roof covering the inert mode. The angled roof diverts oxygen bubbles into an upcomer channel, thereby agitating a molten salt bath in the upcomer channel and improving dissolution of a metal oxide in the molten salt bath. The molten salt bath has a lower velocity adjacent the inert anode in order to minimize corrosion by substances in the bath. A particularly preferred cell produces aluminum by electrolysis of alumina in a molten salt bath containing aluminum fluoride and sodium fluoride. 4 figs.

  2. Molten salt bath circulation design for an electrolytic cell

    DOE Patents [OSTI]

    Dawless, Robert K.; LaCamera, Alfred F.; Troup, R. Lee; Ray, Siba P.; Hosler, Robert B.

    1999-01-01

    An electrolytic cell for reduction of a metal oxide to a metal and oxygen has an inert anode and an upwardly angled roof covering the inert mode. The angled roof diverts oxygen bubbles into an upcomer channel, thereby agitating a molten salt bath in the upcomer channel and improving dissolution of a metal oxide in the molten salt bath. The molten salt bath has a lower velocity adjacent the inert anode in order to minimize corrosion by substances in the bath. A particularly preferred cell produces aluminum by electrolysis of alumina in a molten salt bath containing aluminum fluoride and sodium fluoride.

  3. BLM Approves Salt Wells Geothermal Energy Projects | Open Energy...

    Open Energy Info (EERE)

    Energy Projects Jump to: navigation, search OpenEI Reference LibraryAdd to library Web Site: BLM Approves Salt Wells Geothermal Energy Projects Abstract Abstract unavailable....

  4. Project Profile: Novel Molten Salts Thermal Energy Storage for...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Innovation Alabama's LMP molten salt is projected to have the following ... Lower melting point Higher energy density Lower power-generation cost This program aims to develop a ...

  5. Domestic Material Content in Molten-Salt Concentrating Solar...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Domestic Material Content in Molten-Salt Concentrating Solar Power Plants Craig Turchi, Parthiv Kurup, Sertac Akar, and Francisco Flores Technical Report NRELTP-5500-64429 August...

  6. Inexpensive, Nonfluorinated Anions for Lithium Salts and Ionic...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Electrolytes Inexpensive, Nonfluorinated Anions for Lithium Salts and Ionic Liquids for Lithium Battery Electrolytes 2010 DOE Vehicle Technologies and Hydrogen Programs Annual...

  7. Water Sampling At Salt Wells Area (Shevenell & Garside, 2003...

    Open Energy Info (EERE)

    Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Water Sampling At Salt Wells Area (Shevenell & Garside, 2003) Exploration Activity Details...

  8. Water Sampling At Salt Wells Area (Coolbaugh, Et Al., 2006) ...

    Open Energy Info (EERE)

    Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Water Sampling At Salt Wells Area (Coolbaugh, Et Al., 2006) Exploration Activity Details...

  9. Exploratory Well At Salt Wells Area (Bureau of Land Management...

    Open Energy Info (EERE)

    Bureau of Land Management, 2009) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Exploratory Well At Salt Wells Area (Bureau of Land Management,...

  10. Controlled Source Frequency-Domain Magnetics At Salt Wells Area...

    Open Energy Info (EERE)

    At Salt Wells Area (Montgomery, Et Al., 2005) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Controlled Source Frequency-Domain Magnetics At...

  11. Independent Oversight Review, Savannah River Site Salt Waste...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of the Savannah River Site Salt Waste Processing Facility Construction Quality and Fire Protection Systems The U.S. Department of Energy (DOE) Office of Enforcement and...

  12. Coupled Thermal-Hydrological-Mechanical Processes in Salt, Hot...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    pressure solution and dislocation creep, with both terms dependent on effective stress to account for the effects of porosity. This provides insight into granular salt...

  13. Radiometrics At Salt Wells Area (Henkle, Et Al., 2005) | Open...

    Open Energy Info (EERE)

    Henkle, Et Al., 2005) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Radiometrics At Salt Wells Area (Henkle, Et Al., 2005) Exploration Activity...

  14. Development Wells At Salt Wells Area (Nevada Bureau of Mines...

    Open Energy Info (EERE)

    (Nevada Bureau of Mines and Geology, 2009) Exploration Activity Details Location Salt Wells Geothermal Area Exploration Technique Development Drilling Activity Date 2005 - 2005...

  15. Sandia Energy - New Liquid Salt Electrolytes Could Lead to Cost...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Salt Electrolytes Could Lead to Cost-Effective Flow Batteries Chemical technologist Harry Pratt synthesizes a copper-based ionic liquid. (Photo by Randy Montoya) Sandia...

  16. Project Profile: Molten Salt-Carbon Nanotube Thermal Storage

    Broader source: Energy.gov [DOE]

    Texas Engineering Experiment Station (TEES), under the Thermal Storage FOA, created a composite thermal energy storage material by embedding nanoparticles in a molten salt base material.

  17. ENEL Salt Wells Geothermal Facility | Open Energy Information

    Open Energy Info (EERE)

    Salt Wells Geothermal Facility Sector Geothermal energy Location Information Location Churchill, NV Coordinates 39.651603422063, -118.49778413773 Loading map......

  18. Enterprise Assessments Review of the Savannah River Site Salt...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Review of the Savannah River Site Salt Waste Processing Facility Construction Quality and Startup Test Plans - June 2015 Enterprise Assessments Review of the Savannah River Site...

  19. Method for the production of uranium chloride salt

    DOE Patents [OSTI]

    Westphal, Brian R.; Mariani, Robert D.

    2013-07-02

    A method for the production of UCl.sub.3 salt without the use of hazardous chemicals or multiple apparatuses for synthesis and purification is provided. Uranium metal is combined in a reaction vessel with a metal chloride and a eutectic salt- and heated to a first temperature under vacuum conditions to promote reaction of the uranium metal with the metal chloride for the production of a UCl.sub.3 salt. After the reaction has run substantially to completion, the furnace is heated to a second temperature under vacuum conditions. The second temperature is sufficiently high to selectively vaporize the chloride salts and distill them into a condenser region.

  20. Enterprise Assessments Review of the Savannah River Site Salt...

    Broader source: Energy.gov (indexed) [DOE]

    Salt Waste Processing Facility Construction Quality and Startup Test Plans June 2015 Office of Nuclear Safety and Environmental Assessments Office of Environment, Safety and...

  1. Laboratory study of nitrate photolysis in Antarctic snow. I. Observed quantum yield, domain of photolysis, and secondary chemistry

    SciTech Connect (OSTI)

    Meusinger, Carl; Johnson, Matthew S. [Department of Chemistry, University of Copenhagen, Copenhagen (Denmark); Berhanu, Tesfaye A.; Erbland, Joseph; Savarino, Joel, E-mail: jsavarino@lgge.obs.ujf-grenoble.fr [Univ. Grenoble Alpes, LGGE, F-38000 Grenoble (France); CNRS, LGGE, F-38000 Grenoble (France)

    2014-06-28

    Post-depositional processes alter nitrate concentration and nitrate isotopic composition in the top layers of snow at sites with low snow accumulation rates, such as Dome C, Antarctica. Available nitrate ice core records can provide input for studying past atmospheres and climate if such processes are understood. It has been shown that photolysis of nitrate in the snowpack plays a major role in nitrate loss and that the photolysis products have a significant influence on the local troposphere as well as on other species in the snow. Reported quantum yields for the main reaction spans orders of magnitude apparently a result of whether nitrate is located at the air-ice interface or in the ice matrix constituting the largest uncertainty in models of snowpack NO{sub x} emissions. Here, a laboratory study is presented that uses snow from Dome C and minimizes effects of desorption and recombination by flushing the snow during irradiation with UV light. A selection of UV filters allowed examination of the effects of the 200 and 305nm absorption bands of nitrate. Nitrate concentration and photon flux were measured in the snow. The quantum yield for loss of nitrate was observed to decrease from 0.44 to 0.003 within what corresponds to days of UV exposure in Antarctica. The superposition of photolysis in two photochemical domains of nitrate in snow is proposed: one of photolabile nitrate, and one of buried nitrate. The difference lies in the ability of reaction products to escape the snow crystal, versus undergoing secondary (recombination) chemistry. Modeled NO{sub x} emissions may increase significantly above measured values due to the observed quantum yield in this study. The apparent quantum yield in the 200nm band was found to be ?1%, much lower than reported for aqueous chemistry. A companion paper presents an analysis of the change in isotopic composition of snowpack nitrate based on the same samples as in this study.

  2. Laboratory investigation of crushed salt consolidation and fracture healing

    SciTech Connect (OSTI)

    Not Available

    1987-01-01

    A laboratory test program was conducted to investigate the consolidation behavior of crushed salt and fracture healing in natural and artificial salt. Crushed salt is proposed for use as backfill in a nuclear waste repository in salt. Artificial block salt is proposed for use in sealing a repository. Four consolidation tests were conducted in a hydrostatic pressure vessel at a maximum pressure of 2500 psi (17.2 MPa) and at room temperature. Three 1-month tests were conducted on salt obtained from the Waste Isolation Pilot Plant and one 2-month test was conducted on salt from Avery Island. Permeability was obtained using argon and either a steady-state or transient method. Initial porosities ranged from 0.26 to 0.36 and initial permeabilities from 2000 to 50,000 md. Final porosities and permeabilities ranged from 0.05 to 0.19 and from <10/sup -5/ md to 110 md, respectively. The lowest final porosity (0.05) and permeability (<10/sup -5/ md) were obtained in a 1-month test in which 2.3% moisture was added to the salt at the beginning of the test. The consolidation rate was much more rapid than in any of the dry salt tests. The fracture healing program included 20 permeability tests conducted on fractured and unfractured samples. The tests were conducted in a Hoek cell at hydrostatic pressures up to 3000 psi (20.6 MPa) with durations up to 8 days. For the natural rock salt tested, permeability was strongly dependent on confining pressure and time. The effect of confining pressure was much weaker in the artificial salt. In most cases the combined effects of time and pressure were to reduce the permeability of fractured samples to the same order of magnitude (or less) as the permeability measured prior to fracturing.

  3. Central Multifamily Water Heating Systems

    Broader source: Energy.gov [DOE]

    The Building America Program is hosting a no-cost, webinar-based training on Central Multifamily Water Heating Systems. The webinar will focus the effective use of central heat pump water heaters...

  4. Central American resource studies

    SciTech Connect (OSTI)

    Van Eeckhout, E.; Laughlin, A.W.

    1989-01-01

    Los Alamos National Laboratory has been working with five Central American countries to assist in the development of their energy and mineral resources. Since 1985, mineral resources in Costa Rica, peat resources in Costa Rica and Panama, geothermal energy resources in Honduras and Guatemala, and geothermal field development in El Salvador and Costa Rica have been topics of study. This paper presents an overview of this work -- within these proceedings are papers that deal with specific aspects of each topic, and these will be duly noted. 15 refs., 4 figs.

  5. CENTRAL NEVADA-16 January

    Office of Legacy Management (LM)

    CENTRAL NEVADA-16 January 1970 UNITED STATES DEPARTMENT OF THE Dl"'TERIOR GEOLOGICAL SURVEY Federal Center. Denver. Colorado 80225 PRELIMINARY REPORT ON TliE GEOLOGIC EFFECTS OF THE FAULTLESS EVENT By ,'. USGS-474-65 F. A. McKeown. D. D. Dickey and W. L. Ellis ABSTRACT The Faultless event. an intermediate-yield nucl~ar explosion, produced fractures as much as thousands of feet in length, most of which are along preevent lineaments. Vertical displacements on the fractures are as much as

  6. CX-010503: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Baseload Nitrate Salt Central Receiver Power Plant Design CX(s) Applied: A9, B3.6, B5.17 Date: 06/03/2013 Location(s): Colorado, Colorado Offices(s): Golden Field Office

  7. CX-003201: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Baseload Nitrate Salt Central Receiver Power Plant DesignCX(s) Applied: A9Date: 08/04/2010Location(s): ColoradoOffice(s): Energy Efficiency and Renewable Energy, Golden Field Office

  8. Synthesis of permethyldodecaborate and paramagnetic dodecaborate salt

    DOE Patents [OSTI]

    Hawthorne, M. Frederick (Encino, CA); Peymann, Toralf (Los Angeles, CA)

    2002-01-01

    The dodecamethyl closo-borane dianion [closo-B.sub.12 (CH.sub.3).sub.12 ].sup.2- and anion [closo-B.sub.12 (CH.sub.3).sub.12 ].sup.- were synthesized and characterized. Dodecamethyl-closo dodecaborate (2-) was produced from [closo-B.sub.12 H.sub.12 ].sup.2-, using trimethylaluminum, and methyl iodide and modified Friedel-Crafts reaction conditions. The anion was produced from the dianion by chemical oxidation using ceric (4) ammonium nitrate in acetonitrile. The anion and dianion were both characterized by .sup.1 H and .sup.11 B NMR spectroscopy, high-resolution fast atom bombardment (FAB) mass spectrometry, cyclic voltammetry, and single-crystal X-ray diffraction. The "camouflaged" polyhedral borane anion [closo-B.sub.12 (CH.sub.3).sub.12 ].sup.2-, can be used as a precursor to materials that offer a broad spectrum of novel applications ranging from drug applications and supramolecular chemistry to use as a weakly-coordinating dianion.

  9. Exchange Reactions Between a Molten Salt and a Solution of Tri...

    Office of Scientific and Technical Information (OSTI)

    MERCURY COMPOUNDS; MINERAL ACIDS; MIXING; NICKEL; NICKEL COMPLEXES; NICKEL COMPOUNDS; NITRITES; NUMERICALS; OXALATES; POTASSIUM NITRATES; SEPARATION PROCESSES; SILICONES; SODIUM ...

  10. Disposal of NORM waste in salt caverns

    SciTech Connect (OSTI)

    Veil, J.A.; Smith, K.P.; Tomasko, D.; Elcock, D.; Blunt, D.; Williams, G.P.

    1998-07-01

    Some types of oil and gas production and processing wastes contain naturally occurring radioactive materials (NORM). If NORM is present at concentrations above regulatory levels in oil field waste, the waste requires special disposal practices. The existing disposal options for wastes containing NORM are limited and costly. This paper evaluates the legality, technical feasibility, economics, and human health risk of disposing of NORM-contaminated oil field wastes in salt caverns. Cavern disposal of NORM waste is technically feasible and poses a very low human health risk. From a legal perspective, there are no fatal flaws that would prevent a state regulatory agency from approving cavern disposal of NORM. On the basis of the costs charged by caverns currently used for disposal of nonhazardous oil field waste (NOW), NORM waste disposal caverns could be cost competitive with existing NORM waste disposal methods when regulatory agencies approve the practice.

  11. Technical review of Molten Salt Oxidation

    SciTech Connect (OSTI)

    Not Available

    1993-12-01

    The process was reviewed for destruction of mixed low-level radioactive waste. Results: extensive development work and scaleup has been documented on coal gasification and hazardous waste which forms a strong experience base for this MSO process; it is clearly applicable to DOE wastes such as organic liquids and low-ash wastes. It also has potential for processing difficult-to-treat wastes such as nuclear grade graphite and TBP, and it may be suitable for other problem waste streams such as sodium metal. MSO operating systems may be constructed in relatively small units for small quantity generators. Public perceptions could be favorable if acceptable performance data are presented fairly; MSO will likely require compliance with regulations for incineration. Use of MSO for offgas treatment may be complicated by salt carryover. Figs, tabs, refs.

  12. Uranyl nitrate-exposed rat alveolar macrophages cell death: Influence of superoxide anion and TNF ? mediators

    SciTech Connect (OSTI)

    Orona, N.S.; Tasat, D.R.

    2012-06-15

    Uranium compounds are widely used in the nuclear fuel cycle, military and many other diverse industrial processes. Health risks associated with uranium exposure include nephrotoxicity, cancer, respiratory, and immune disorders. Macrophages present in body tissues are the main cell type involved in the internalization of uranium particles. To better understand the pathological effects associated with depleted uranium (DU) inhalation, we examined the metabolic activity, phagocytosis, genotoxicity and inflammation on DU-exposed rat alveolar macrophages (12.5200 ?M). Stability and dissolution of DU could differ depending on the dissolvent and in turn alter its biological action. We dissolved DU in sodium bicarbonate (NaHCO{sub 3} 100 mM) and in what we consider a more physiological vehicle resembling human internal media: sodium chloride (NaCl 0.9%). We demonstrate that uranyl nitrate in NaCl solubilizes, enters the cell, and elicits its cytotoxic effect similarly to when it is diluted in NaHCO{sub 3}. We show that irrespective of the dissolvent employed, uranyl nitrate impairs cell metabolism, and at low doses induces both phagocytosis and generation of superoxide anion (O{sub 2}{sup ?}). At high doses it provokes the secretion of TNF? and through all the range of doses tested, apoptosis. We herein suggest that at DU low doses O{sub 2}{sup ?} may act as the principal mediator of DNA damage while at higher doses the signaling pathway mediated by O{sub 2}{sup ?} may be blocked, prevailing damage to DNA by the TNF? route. The study of macrophage functions after uranyl nitrate treatment could provide insights into the pathophysiology of uranium?related diseases. -- Highlights: ? Uranyl nitrate effect on cultured macrophages is linked to the doses and independent of its solubility. ? At low doses uranyl nitrate induces generation of superoxide anion. ? At high doses uranyl nitrate provokes secretion of TNF?. ? Uranyl nitrate induces apoptosis through all the range of doses tested.

  13. Voluntary Protection Program Onsite Review, Parsons Corporation Salt Waste

    Office of Environmental Management (EM)

    Processing Facility Construction Project - October 2015 | Department of Energy Corporation Salt Waste Processing Facility Construction Project - October 2015 Voluntary Protection Program Onsite Review, Parsons Corporation Salt Waste Processing Facility Construction Project - October 2015 October 2015 Parsons SWPF Construction Project will continue participating in the Department of Energy Voluntary Protection Program and be elevated to a Star participant. This report summarizes the results

  14. Alternative Waste Forms for Electro-Chemical Salt Waste

    SciTech Connect (OSTI)

    Crum, Jarrod V.; Sundaram, S. K.; Riley, Brian J.; Matyas, Josef; Arreguin, Shelly A.; Vienna, John D.

    2009-10-28

    This study was undertaken to examine alternate crystalline (ceramic/mineral) and glass waste forms for immobilizing spent salt from the Advanced Fuel Cycle Initiative (AFCI) electrochemical separations process. The AFCI is a program sponsored by U.S. Department of Energy (DOE) to develop and demonstrate a process for recycling spent nuclear fuel (SNF). The electrochemical process is a molten salt process for the reprocessing of spent nuclear fuel in an electrorefiner and generates spent salt that is contaminated with alkali, alkaline earths, and lanthanide fission products (FP) that must either be cleaned of fission products or eventually replaced with new salt to maintain separations efficiency. Currently, these spent salts are mixed with zeolite to form sodalite in a glass-bonded waste form. The focus of this study was to investigate alternate waste forms to immobilize spent salt. On a mole basis, the spent salt is dominated by alkali and Cl with minor amounts of alkaline earth and lanthanides. In the study reported here, we made an effort to explore glass systems that are more compatible with Cl and have not been previously considered for use as waste forms. In addition, alternate methods were explored with the hope of finding a way to produce a sodalite that is more accepting of as many FP present in the spent salt as possible. This study was done to investigate two different options: (1) alternate glass families that incorporate increased concentrations of Cl; and (2) alternate methods to produce a mineral waste form.

  15. Treatment of plutonium process residues by molten salt oxidation

    SciTech Connect (OSTI)

    Stimmel, J.; Wishau, R.; Ramsey, K.B.; Montoya, A.; Brock, J.; Heslop, M.; Wernly, K.

    1999-04-01

    Molten Salt Oxidation (MSO) is a thermal process that can remove more than 99.999% of the organic matrix from combustible {sup 238}Pu material. Plutonium processing residues are injected into a molten salt bed with an excess of air. The salt (sodium carbonate) functions as a catalyst for the conversion of the organic material to carbon dioxide and water. Reactive species such as fluorine, chlorine, bromine, iodine, sulfur, phosphorous and arsenic in the organic waste react with the molten salt to form the corresponding neutralized salts, NaF, NaCl, NaBr, NaI, Na{sub 2}SO{sub 4}, Na{sub 3}PO{sub 4} and NaAsO{sub 2} or Na{sub 3}AsO4. Plutonium and other metals react with the molten salt and air to form metal salts or oxides. Saturated salt will be recycled and aqueous chemical separation will be used to recover the {sup 238}Pu. The Los Alamos National Laboratory system, which is currently in the conceptual design stage, will be scaled down from current systems for use inside a glovebox.

  16. Parametric study of natural circulation flow in molten salt fuel in molten salt reactor

    SciTech Connect (OSTI)

    Pauzi, Anas Muhamad; Cioncolini, Andrea; Iacovides, Hector

    2015-04-29

    The Molten Salt Reactor (MSR) is one of the most promising system proposed by Generation IV Forum (GIF) for future nuclear reactor systems. Advantages of the MSR are significantly larger compared to other reactor system, and is mainly achieved from its liquid nature of fuel and coolant. Further improvement to this system, which is a natural circulating molten fuel salt inside its tube in the reactor core is proposed, to achieve advantages of reducing and simplifying the MSR design proposed by GIF. Thermal hydraulic analysis on the proposed system was completed using a commercial computation fluid dynamics (CFD) software called FLUENT by ANSYS Inc. An understanding on theory behind this unique natural circulation flow inside the tube caused by fission heat generated in molten fuel salt and tube cooling was briefly introduced. Currently, no commercial CFD software could perfectly simulate natural circulation flow, hence, modeling this flow problem in FLUENT is introduced and analyzed to obtain best simulation results. Results obtained demonstrate the existence of periodical transient nature of flow problem, hence improvements in tube design is proposed based on the analysis on temperature and velocity profile. Results show that the proposed system could operate at up to 750MW core power, given that turbulence are enhanced throughout flow region, and precise molten fuel salt physical properties could be defined. At the request of the authors and the Proceedings Editor the name of the co-author Andrea Cioncolini was corrected from Andrea Coincolini. The same name correction was made in the Acknowledgement section on page 030004-10 and in reference number 4. The updated article was published on 11 May 2015.

  17. Laboratory study of nitrate photolysis in Antarctic snow. II. Isotopic effects and wavelength dependence

    SciTech Connect (OSTI)

    Berhanu, Tesfaye A.; Erbland, Joseph; Savarino, Jol [Laboratoire de Glaciologie et Gophysique de lEnvironnement, CNRS, F-38041 Grenoble (France); Univ. Grenoble Alpes, LGGE, F-38041 Grenoble (France); Meusinger, Carl; Johnson, Matthew S. [Copenhagen Center for Atmospheric Research (CCAR), Department of Chemistry, University of Copenhagen, Copenhagen (Denmark); Jost, Rmy [Laboratoire de Interdisciplinaire de Physique (LIPHY) Univ. de Grenoble, Grenoble (France); Bhattacharya, S. K. [Research Center for Environmental Changes, Academia Sinica, Nangang, Taipei 115, Taiwan (China)

    2014-06-28

    Atmospheric nitrate is preserved in Antarctic snow firn and ice. However, at low snow accumulation sites, post-depositional processes induced by sunlight obscure its interpretation. The goal of these studies (see also Paper I by Meusinger et al. [Laboratory study of nitrate photolysis in Antarctic snow. I. Observed quantum yield, domain of photolysis, and secondary chemistry, J. Chem. Phys. 140, 244305 (2014)]) is to characterize nitrate photochemistry and improve the interpretation of the nitrate ice core record. Naturally occurring stable isotopes in nitrate ({sup 15}N, {sup 17}O, and {sup 18}O) provide additional information concerning post-depositional processes. Here, we present results from studies of the wavelength-dependent isotope effects from photolysis of nitrate in a matrix of natural snow. Snow from Dome C, Antarctica was irradiated in selected wavelength regions using a Xe UV lamp and filters. The irradiated snow was sampled and analyzed for nitrate concentration and isotopic composition (?{sup 15}N, ?{sup 18}O, and ?{sup 17}O). From these measurements an average photolytic isotopic fractionation of {sup 15}? = (?15 1.2) was found for broadband Xe lamp photolysis. These results are due in part to excitation of the intense absorption band of nitrate around 200 nm in addition to the weaker band centered at 305 nm followed by photodissociation. An experiment with a filter blocking wavelengths shorter than 320 nm, approximating the actinic flux spectrum at Dome C, yielded a photolytic isotopic fractionation of {sup 15}? = (?47.9 6.8), in good agreement with fractionations determined by previous studies for the East Antarctic Plateau which range from ?40 to ?74.3. We describe a new semi-empirical zero point energy shift model used to derive the absorption cross sections of {sup 14}NO{sub 3}{sup ?} and {sup 15}NO{sub 3}{sup ?} in snow at a chosen temperature. The nitrogen isotopic fractionations obtained by applying this model under the experimental temperature as well as considering the shift in width and center well reproduced the values obtained in the laboratory study. These cross sections can be used in isotopic models to reproduce the stable isotopic composition of nitrate found in Antarctic snow profiles.

  18. Central solar energy receiver

    DOE Patents [OSTI]

    Drost, M. Kevin (Richland, WA)

    1983-01-01

    An improved tower-mounted central solar energy receiver for heating air drawn through the receiver by an induced draft fan. A number of vertically oriented, energy absorbing, fin-shaped slats are radially arranged in a number of concentric cylindrical arrays on top of the tower coaxially surrounding a pipe having air holes through which the fan draws air which is heated by the slats which receive the solar radiation from a heliostat field. A number of vertically oriented and wedge-shaped columns are radially arranged in a number of concentric cylindrical clusters surrounding the slat arrays. The columns have two mirror-reflecting sides to reflect radiation into the slat arrays and one energy absorbing side to reduce reradiation and reflection from the slat arrays.

  19. Ion aggregation in high salt solutions. III. Computational vibrational spectroscopy of HDO in aqueous salt solutions

    SciTech Connect (OSTI)

    Choi, Jun-Ho; Lim, Sohee; Chon, Bonghwan; Cho, Minhaeng; Kim, Heejae; Kim, Seongheun

    2015-05-28

    The vibrational frequency, frequency fluctuation dynamics, and transition dipole moment of the OD stretch mode of HDO molecule in aqueous solutions are strongly dependent on its local electrostatic environment and hydrogen-bond network structure. Therefore, the time-resolved vibrational spectroscopy the OD stretch mode has been particularly used to investigate specific ion effects on water structure. Despite prolonged efforts to understand the interplay of OD vibrational dynamics with local water hydrogen-bond network and ion aggregate structures in high salt solutions, still there exists a gap between theory and experiment due to a lack of quantitative model for accurately describing OD stretch frequency in high salt solutions. To fill this gap, we have performed numerical simulations of Raman scattering and IR absorption spectra of the OD stretch mode of HDO in highly concentrated NaCl and KSCN solutions and compared them with experimental results. Carrying out extensive quantum chemistry calculations on not only water clusters but also ion-water clusters, we first developed a distributed vibrational solvatochromic charge model for the OD stretch mode in aqueous salt solutions. Furthermore, the non-Condon effect on the vibrational transition dipole moment of the OD stretch mode was fully taken into consideration with the charge response kernel that is non-local polarizability density. From the fluctuating OD stretch mode frequencies and transition dipole vectors obtained from the molecular dynamics simulations, the OD stretch Raman scattering and IR absorption spectra of HDO in salt solutions could be calculated. The polarization effect on the transition dipole vector of the OD stretch mode is shown to be important and the asymmetric line shapes of the OD stretch Raman scattering and IR absorption spectra of HDO especially in highly concentrated NaCl and KSCN solutions are in quantitative agreement with experimental results. We anticipate that this computational approach will be of critical use in interpreting linear and nonlinear vibrational spectroscopies of HDO molecule that is considered as an excellent local probe for monitoring local electrostatic and hydrogen-bonding environment in not just salt but also other confined and crowded solutions.

  20. Thermal Gradient Holes At Salt Wells Area (Bureau of Land Management...

    Open Energy Info (EERE)

    Salt Wells Area (Bureau of Land Management, 2009) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Thermal Gradient Holes At Salt Wells Area...

  1. Soil Sampling At Salt Wells Area (Henkle, Et Al., 2005) | Open...

    Open Energy Info (EERE)

    Salt Wells Area (Henkle, Et Al., 2005) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Soil Sampling At Salt Wells Area (Henkle, Et Al., 2005)...

  2. Slim Holes At Salt Wells Area (Combs, Et Al., 1999) | Open Energy...

    Open Energy Info (EERE)

    Salt Wells Area (Combs, Et Al., 1999) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Slim Holes At Salt Wells Area (Combs, Et Al., 1999)...

  3. Fluoroalkyl containing salts combined with fluorinated solvents for electrolytes

    DOE Patents [OSTI]

    Tikhonov, Konstantin; Yip, Ka Ki; Lin, Tzu-Yuan; Erickson, Michael Jason

    2015-04-21

    Provided are electrochemical cells and electrolytes used to build such cells. An electrolyte may include a fluoroalkyl-substituted LiPF.sub.6 salt or a fluoroalkyl-substituted LiBF.sub.4 salt. In some embodiments, at least one fluorinated alkyl of the salt has a chain length of from 1 to 8 or, more specifically, between about 2 and 8. These fluorinated alkyl groups, in particular, relatively large fluorinated alkyl groups improve solubility of these salts in fluorinated solvents that are less flammable than, for example, conventional carbonate solvents. At the same time, the size of fluoroalkyl-substituted salts should be limited to ensure adequate concentration of the salt in an electrolyte and low viscosity of the electrolyte. In some embodiments, the concentration of a fluoroalkyl-substituted salt is at least about 0.5M. Examples of fluorinated solvents include various fluorinated esters, fluorinated ethers, and fluorinated carbonates, such a 1-methoxyheptafluoropropane, methyl nonafluorobutyl ether, ethyl nonafluorobutyl ether, 1,1,1,2,2,3,4,5,5,5-decafluoro-3-methoxy-4-(trifluoromethyl)-pentane, 3-ethoxy-1,1,1,2,3,4,4,5,5,6,6,6-dodecafluoro-2-trifluoromethyl-hexane, and 1,1,1,2,3,3-hexafluoro-4-(1,1,2,3,3,3-hexafluoropropoxy)-pentane.

  4. Fast Thorium Molten Salt Reactors Started with Plutonium

    SciTech Connect (OSTI)

    Merle-Lucotte, E.; Heuer, D.; Le Brun, C.; Brissot, R.; Liatard, E.; Meplan, O.; Nuttin, A.

    2006-07-01

    One of the pending questions concerning Molten Salt Reactors based on the {sup 232}Th/{sup 233}U fuel cycle is the supply of the fissile matter, and as a consequence the deployment possibilities of a fleet of Molten Salt Reactors, since {sup 233}U does not exist on earth and is not yet produced in the current operating reactors. A solution may consist in producing {sup 233}U in special devices containing Thorium, in Pressurized Water or Fast Neutrons Reactors. Two alternatives to produce {sup 233}U are examined here: directly in standard Molten Salt Reactors started with Plutonium as fissile matter and then operated in the Th/{sup 233}U cycle; or in dedicated Molten Salt Reactors started and fed with Plutonium as fissile matter and Thorium as fertile matter. The idea is to design a critical reactor able to burn the Plutonium and the minor actinides presently produced in PWRs, and consequently to convert this Plutonium into {sup 233}U. A particular reactor configuration is used, called 'unique channel' configuration in which there is no moderator in the core, leading to a quasi fast neutron spectrum, allowing Plutonium to be used as fissile matter. The conversion capacities of such Molten Salt Reactors are excellent. For Molten Salt Reactors only started with Plutonium, the assets of the Thorium fuel cycle turn out to be quickly recovered and the reactor's characteristics turn out to be equivalent to Molten Salt Reactors operated with {sup 233}U only. Using a combination of Molten Salt Reactors started or operated with Plutonium and of Molten Salt Reactors started with {sup 233}U, the deployment capabilities of these reactors fully satisfy the condition of sustainability. (authors)

  5. Biological Redox Cycling Of Iron In Nontronite And Its Potential Application In Nitrate Removal

    SciTech Connect (OSTI)

    Zhao, Linduo; Dong, Hailiang; Kukkadapu, Ravi K.; Zeng, Qiang; Edelmann, Richard E.; Pentrak, Martin; Agrawal, Abinash

    2015-05-05

    Redox cycling of structural Fe in phyllosilicates provides a potential method to remediate nitrate contamination in natural environment. Past research has only studied chemical redox cycles or a single biologically mediated redox cycle of Fe in phyllosilicates. The objective of this research was to study three microbially driven redox cycles of Fe in one phyllosilicate, nontronite (NAu-2). During the reduction phase structural Fe(III) in NAu-2 served as electron acceptor, lactate as electron donor, AQDS as electron shuttle, and dissimilatory Fe(III)-reducing bacteria Shewanella putrefaciens CN32 as mediator in bicarbonate-buffered and PIPES-buffered media. During the oxidation phase, biogenic Fe(II) served an electron donor, nitrate as electron acceptor, and nitrate-dependent Fe(II)-oxidizing bacteria Pseudogulbenkiania sp. strain 2002 as mediator in the same media. For all three cycles, structural Fe in NAu-2 was able to reversibly undergo 3 redox cycles without significant reductive or oxidative dissolution. X-ray diffraction and scanning and transmission electron microscopy revealed that NAu-2 was the dominant residual mineral throughout the 3 redox cycles with some dissolution textures but no significant secondary mineralization. Mssbauer spectroscopy revealed that Fe(II) in bio-reduced samples likely occurred in two distinct environments, at edges and the interior of the NAu-2 structure. Nitrate was completely reduced to nitrogen gas under both buffer conditions and this extent and rate did not change with Fe redox cycles. Mssbauer spectroscopy further revealed that nitrate reduction was coupled to predominant/preferred oxidation of edge Fe(II). These results suggest that structural Fe in phyllosilicates may represent a renewable source to continuously remove nitrate in natural environments.

  6. Electrolyte materials containing highly dissociated metal ion salts

    DOE Patents [OSTI]

    Lee, Hung-Sui (East Setauket, NY); Geng, Lin (Coram, NY); Skotheim, Terje A. (Shoreham, NY)

    1996-07-23

    The present invention relates to metal ion salts which can be used in electrolytes for producing electrochemical devices, including both primary and secondary batteries, photoelectrochemical cells and electrochromic displays. The salts have a low energy of dissociation and may be dissolved in a suitable polymer to produce a polymer solid electrolyte or in a polar aprotic liquid solvent to produce a liquid electrolyte. The anion of the salts may be covalently attached to polymer backbones to produce polymer solid electrolytes with exclusive cation conductivity.

  7. Gradient zone boundary control in salt gradient solar ponds

    DOE Patents [OSTI]

    Hull, John R.

    1984-01-01

    A method and apparatus for suppressing zone boundary migration in a salt gradient solar pond includes extending perforated membranes across the pond at the boundaries, between the convective and non-convective zones, the perforations being small enough in size to prevent individual turbulence disturbances from penetrating the hole, but being large enough to allow easy molecular diffusion of salt thereby preventing the formation of convective zones in the gradient layer. The total area of the perforations is a sizable fraction of the membrane area to allow sufficient salt diffusion while preventing turbulent entrainment into the gradient zone.

  8. Electrolyte materials containing highly dissociated metal ion salts

    DOE Patents [OSTI]

    Lee, H.S.; Geng, L.; Skotheim, T.A.

    1996-07-23

    The present invention relates to metal ion salts which can be used in electrolytes for producing electrochemical devices, including both primary and secondary batteries, photoelectrochemical cells and electrochromic displays. The salts have a low energy of dissociation and may be dissolved in a suitable polymer to produce a polymer solid electrolyte or in a polar aprotic liquid solvent to produce a liquid electrolyte. The anion of the salts may be covalently attached to polymer backbones to produce polymer solid electrolytes with exclusive cation conductivity. 2 figs.

  9. Sol-gel processing with inorganic metal salt precursors

    DOE Patents [OSTI]

    Hu, Zhong-Cheng

    2004-10-19

    Methods for sol-gel processing that generally involve mixing together an inorganic metal salt, water, and a water miscible alcohol or other organic solvent, at room temperature with a macromolecular dispersant material, such as hydroxypropyl cellulose (HPC) added. The resulting homogenous solution is incubated at a desired temperature and time to result in a desired product. The methods enable production of high quality sols and gels at lower temperatures than standard methods. The methods enable production of nanosize sols from inorganic metal salts. The methods offer sol-gel processing from inorganic metal salts.

  10. Experimental Investigation of Two-Phase Flow in Rock Salt

    SciTech Connect (OSTI)

    Malama, Bwalya; Howard, Clifford L.

    2014-07-01

    This Test Plan describes procedures for conducting laboratory scale flow tests on intact, damaged, crushed, and consolidated crushed salt to measure the capillary pressure and relative permeability functions. The primary focus of the tests will be on samples of bedded geologic salt from the WIPP underground. However, the tests described herein are directly applicable to domal salt. Samples being tested will be confined by a range of triaxial stress states ranging from atmospheric pressure up to those approximating lithostatic. Initially these tests will be conducted at room temperature, but testing procedures and equipment will be evaluated to determine adaptability to conducting similar tests under elevated temperatures.

  11. Reduction of Nitrate in Shewanella oneidensis depends on atypical NAP and

    Office of Scientific and Technical Information (OSTI)

    NRF systems with NapB as a preferred electron transport protein from CymA to NapA (Journal Article) | SciTech Connect Reduction of Nitrate in Shewanella oneidensis depends on atypical NAP and NRF systems with NapB as a preferred electron transport protein from CymA to NapA Citation Details In-Document Search Title: Reduction of Nitrate in Shewanella oneidensis depends on atypical NAP and NRF systems with NapB as a preferred electron transport protein from CymA to NapA In the genome of

  12. Engineering Evaluation of Proposed Alternative Salt Transfer Method for the Molten Salt Reactor Experiement for the Oak Ridge National Laboratory

    SciTech Connect (OSTI)

    Carlberg, Jon A.; Roberts, Kenneth T.; Kollie, Thomas G.; Little, Leslie E.; Brady, Sherman D.

    2009-09-30

    This evaluation was performed by Pro2Serve in accordance with the Technical Specification for an Engineering Evaluation of the Proposed Alternative Salt Transfer Method for the Molten Salt Reactor Experiment at the Oak Ridge National Laboratory (BJC 2009b). The evaluators reviewed the Engineering Evaluation Work Plan for Molten Salt Reactor Experiment Residual Salt Removal, Oak Ridge National Laboratory, Oak Ridge, Tennessee (DOE 2008). The Work Plan (DOE 2008) involves installing a salt transfer probe and new drain line into the Fuel Drain Tanks and Fuel Flush Tank and connecting them to the new salt transfer line at the drain tank cell shield. The probe is to be inserted through the tank ball valve and the molten salt to the bottom of the tank. The tank would then be pressurized through the Reactive Gas Removal System to force the salt into the salt canisters. The Evaluation Team reviewed the work plan, interviewed site personnel, reviewed numerous documents on the Molten Salt Reactor (Sects. 7 and 8), and inspected the probes planned to be used for the transfer. Based on several concerns identified during this review, the team recommends not proceeding with the salt transfer via the proposed alternate salt transfer method. The major concerns identified during this evaluation are: (1) Structural integrity of the tanks - The main concern is with the corrosion that occurred during the fluorination phase of the uranium removal process. This may also apply to the salt transfer line for the Fuel Flush Tank. Corrosion Associated with Fluorination in the Oak Ridge National Laboratory Fluoride Volatility Process (Litman 1961) shows that this problem is significant. (2) Continued generation of Fluorine - Although the generation of Fluorine will be at a lower rate than experienced before the uranium removal, it will continue to be generated. This needs to be taken into consideration regardless of what actions are taken with the salt. (3) More than one phase of material - There are likely multiple phases of material in the salt (metal or compound), either suspended through the salt matrix, layered in the bottom of the tank, or both. These phases may contribute to plugging during any planned transfer. There is not enough data to know for sure. (4) Probe heat trace - The alternate transfer method does not include heat tracing of the bottom of the probe. There is a concern that this may cool the salt and other phases of materials present enough to block the flow of salt. (5) Stress-corrosion cracking - Additionally, there is a concern regarding moisture that may have been introduced into the tanks. Due to time constraints, this concern was not validated. However, if moisture was introduced into the tanks and not removed during heating the tanks before HF and F2 sparging, there would be an additional concern regarding the potential for stress-corrosion cracking of the tank walls.

  13. Central Facility Benefits from Improvements

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the ARM SGP central facility near Lamont, Oklahoma: construction of an instrument maintenance facility, installation of an instrument to measure carbon dioxide flux, and...

  14. Building America Webinar: Retrofitting Central Space Conditioning...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Building America Webinar: Retrofitting Central Space Conditioning Strategies for ... Webinar: Retrofitting Central Space Conditioning Strategies for Multifamily Buildings

  15. Central and southern Africa

    SciTech Connect (OSTI)

    McGrew, H.J.

    1981-10-01

    Exploration in central and southern Africa continued to expand during 1980. The greatest concentration of activity was in Nigeria. However, there was considerable increase in the level of exploratory work in Cameroon and Congo. Significant new finds have been made in Ivory Coast. Geological and geophysical activity was carried out in 18 of the countries, with those in the western part having the largest share. Seismic work involved 225 party months of operation. Most of this time was spent on land, but marine operations accounted for 73,389 km of new control. Gravity and magnetic data were recorded during the marine surveys, and several large aeromagnetic projects were undertaken to obtain a total of 164,498 line km of data. Exploratory and development drilling accounted for a total of 304 wells and 2,605,044 ft (794,212 m) of hole. The 92 exploratory wells that were drilled resulted in 47 oil and gas discoveries. In development drilling 89% of the 212 wells were successful. At the end of the year, 27 exploratory wells were underway, and 34 development wells were being drilled for a total of 61. Oil production from the countries that this review covers was 918,747,009 bbl in 1980, a drop of about 9% from the previous year. Countries showing a decline in production were Nigeria, Gabon, Cabinda, and Zaire. Increases were recorded in Cameroon, Congo, and Ghana. A new country was added to the list of producers when production from the Belier field in Ivory Coast came on stream. 33 figures, 15 tables.

  16. Category:Salt Lake City, UT | Open Energy Information

    Open Energy Info (EERE)

    UT Jump to: navigation, search Go Back to PV Economics By Location Media in category "Salt Lake City, UT" The following 16 files are in this category, out of 16 total....

  17. Expected brine movement at potential nuclear waste repository salt sites

    SciTech Connect (OSTI)

    McCauley, V.S.; Raines, G.E.

    1987-08-01

    The BRINEMIG brine migration code predicts rates and quantities of brine migration to a waste package emplaced in a high-level nuclear waste repository in salt. The BRINEMIG code is an explicit time-marching finite-difference code that solves a mass balance equation and uses the Jenks equation to predict velocities of brine migration. Predictions were made for the seven potentially acceptable salt sites under consideration as locations for the first US high-level nuclear waste repository. Predicted total quantities of accumulated brine were on the order of 1 m/sup 3/ brine per waste package or less. Less brine accumulation is expected at domal salt sites because of the lower initial moisture contents relative to bedded salt sites. Less total accumulation of brine is predicted for spent fuel than for commercial high-level waste because of the lower temperatures generated by spent fuel. 11 refs., 36 figs., 29 tabs.

  18. Salt River Electric Coop Corp | Open Energy Information

    Open Energy Info (EERE)

    River Electric Coop Corp Jump to: navigation, search Name: Salt River Electric Coop Corp Place: Kentucky References: EIA Form EIA-861 Final Data File for 2010 - File1a1 EIA Form...

  19. Apparatus and method for making metal chloride salt product

    DOE Patents [OSTI]

    Miller, William E. (Naperville, IL); Tomczuk, Zygmunt (Homer Glen, IL); Richmann, Michael K. (Carlsbad, NM)

    2007-05-15

    A method of producing metal chlorides is disclosed in which chlorine gas is introduced into liquid Cd. CdCl.sub.2 salt is floating on the liquid Cd and as more liquid CdCl.sub.2 is formed it separates from the liquid Cd metal and dissolves in the salt. The salt with the CdCl.sub.2 dissolved therein contacts a metal which reacts with CdCl.sub.2 to form a metal chloride, forming a mixture of metal chloride and CdCl.sub.2. After separation of bulk Cd from the salt, by gravitational means, the metal chloride is obtained by distillation which removes CdCl.sub.2 and any Cd dissolved in the metal chloride.

  20. Salt Wells, Eight Mile Flat | Open Energy Information

    Open Energy Info (EERE)

    Eight Mile Flat Jump to: navigation, search OpenEI Reference LibraryAdd to library Web Site: Salt Wells, Eight Mile Flat Abstract Abstract unavailable. Author Nevada Bureau...

  1. Basis for Section 3116 Determination for Salt Waste Disposal...

    Office of Environmental Management (EM)

    WD-2005-001 January 2006 Basis for Section 3116 Determination for Salt Waste Disposal at ......... 28 4.0 THE WASTE DOES NOT REQUIRE PERMANENT ISOLATION IN A ...

  2. Salt Wells Geothermal Exploratory Drilling Program EA(DOI-BLM...

    Open Energy Info (EERE)

    Exploratory Drilling Program EA (DOI-BLM-NV-C010-2009-0006-EA) Jump to: navigation, search OpenEI Reference LibraryAdd to library Web Site: Salt Wells Geothermal Exploratory...

  3. Direct esterification of ammonium salts of carboxylic acids

    DOE Patents [OSTI]

    Halpern, Yuval (Skokie, IL)

    2003-06-24

    A non-catalytic process for producing esters, the process comprising reacting an ammonium salt of a carboxylic acid with an alcohol and removing ammonia from the reaction mixture. Selectivities for the desired ester product can exceed 95 percent.

  4. Project Profile: Modular and Scalable Baseload Molten Salt Plant...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    C. Moursund, D. Rogers; D. Wasyluk. "Conceptual Design of a 100 MWe Modular Molten Salt Power Tower Plant" in Proceedings of SolarPACES 2011, Granada Spain, September 20-23, 2011...

  5. Polyimide amic acid salts and polyimide membranes formed therefrom

    DOE Patents [OSTI]

    Ding, Yong; Bikson, Benjamin; Nelson, Joyce Katz; Macheras, James Timothy

    2004-04-06

    The invention relates to preparation and uses of novel polymeric materials, polyimide amic acid salts (PIAAS). The use of these materials for the fabrication of fluid separation membranes is further disclosed.

  6. Molten salt electrolyte battery cell with overcharge tolerance

    DOE Patents [OSTI]

    Kaun, Thomas D. (New Lenox, IL); Nelson, Paul A. (Wheaton, IL)

    1989-01-01

    A molten salt electrolyte battery having an increased overcharge tolerance employs a negative electrode with two lithium alloy phases of different electrochemical potential, one of which allows self-discharge rates which permits battery cell equalization.

  7. Development of Molten-Salt Heat Trasfer Fluid Technology for...

    Office of Environmental Management (EM)

    Solut ions f or Sustainability ABENGOA SOLAR Freeze Prot ect ion and Recovery Lessons Learned Salt f reeze point has an unexpect edly low impact on inst alled cost of t he...

  8. EM Gains Insight from Germany on Salt-Based Repositories

    Broader source: Energy.gov [DOE]

    KARLSRUHE and PEINE, Germany – EM officials recently took part in workshops in Germany to benefit from the exchange of research and experience operating salt-based repositories for radioactive waste.

  9. Surface Indicators of Geothermal Activity at Salt Wells, Nevada...

    Open Energy Info (EERE)

    of geothermal fluids. An example is provided by the Salt Wells geothermal system in Churchill County, Nevada, USA, where surface features define a 9-km-long area that matches the...

  10. BLM Approves Salt Wells Geothermal Plant in Churchill County...

    Open Energy Info (EERE)

    Plant in Churchill County Jump to: navigation, search OpenEI Reference LibraryAdd to library Web Site: BLM Approves Salt Wells Geothermal Plant in Churchill County Abstract...

  11. Oxidation of aqueous pollutants using ultrasound: Salt-induced enhancement

    SciTech Connect (OSTI)

    Seymour, J.D.; Gupta, R.B.

    1997-09-01

    Ultrasound can be used to oxidize aqueous pollutants; however, due to economic reasons, higher oxidation/destruction rates are needed. This study reports enhancements of reaction rates by the addition of sodium chloride salt. Using 20 kHz ultrasound, large salt-induced enhancements are observed--6-fold for chlorobenzene, 7-fold for p-ethylphenol, and 3-fold for phenol oxidation. The reaction rate enhancements are proportional to the diethyl ether--water partitioning coefficient of the pollutants. It appears that the majority of oxidation reactions occur in the bubble-bulk interface region. The addition of salt increases the ionic strength of the aqueous phase which drives the organic pollutants toward the bubble-bulk interface. A first order reaction rate equation is proposed which can represent the observed enhancement with a good accuracy. A new sonochemical-waste-oxidation process is proposed utilizing the salt-induced enhancement.

  12. PROJECT PROFILE: Salt Lake City Corporation (Solar Market Pathways)

    Broader source: Energy.gov [DOE]

    Title: Wasatch Solar Project Funding Opportunity: Solar Market PathwaysSunShot Subprogram: Soft CostsLocation: Salt Lake City, UTAmount Awarded: $600,000Awardee Cost Share: $164,645

  13. Liquid Salt Heat Exchanger Technology for VHTR Based Applications

    SciTech Connect (OSTI)

    Anderson, Mark; Sridhara, Kumar; Allen, Todd; Peterson, Per

    2012-10-11

    The objective of this research is to evaluate performance of liquid salt fluids for use as a heat carrier for transferring high-temperature process heat from the very high-temperature reactor (VHTR) to chemical process plants. Currently, helium is being considered as the heat transfer fluid; however, the tube size requirements and the power associated with pumping helium may not be economical. Recent work on liquid salts has shown tremendous potential to transport high-temperature heat efficiently at low pressures over long distances. This project has two broad objectives: To investigate the compatibility of Incoloy 617 and coated and uncoated SiC ceramic composite with MgCl2-KCl molten salt to determine component lifetimes and aid in the design of heat exchangers and piping; and, To conduct the necessary research on the development of metallic and ceramic heat exchangers, which are needed for both the helium-to-salt side and salt-to-process side, with the goal of making these heat exchangers technologically viable. The research will consist of three separate tasks. The first task deals with material compatibility issues with liquid salt and the development of techniques for on-line measurement of corrosion products, which can be used to measure material loss in heat exchangers. Researchers will examine static corrosion of candidate materials in specific high-temperature heat transfer salt systems and develop an in situ electrochemical probe to measure metallic species concentrations dissolved in the liquid salt. The second task deals with the design of both the intermediate and process side heat exchanger systems. Researchers will optimize heat exchanger design and study issues related to corrosion, fabrication, and thermal stresses using commercial and in-house codes. The third task focuses integral testing of flowing liquid salts in a heat transfer/materials loop to determine potential issues of using the salts and to capture realistic behavior of the salts in a small scale prototype system. This includes investigations of plugging issues, heat transfer, pressure drop, and the corrosion and erosion of materials in the flowing system.

  14. Molten salt heat transfer fluids and thermal storage technology.

    Office of Scientific and Technical Information (OSTI)

    (Conference) | SciTech Connect Molten salt heat transfer fluids and thermal storage technology. Citation Details In-Document Search Title: Molten salt heat transfer fluids and thermal storage technology. No abstract prepared. Authors: Glatzmaier, Greg [1] ; Siegel, Nathan Phillip + Show Author Affiliations (NREL) Publication Date: 2010-06-01 OSTI Identifier: 1020492 Report Number(s): SAND2010-3826C TRN: US201116%%508 DOE Contract Number: AC04-94AL85000 Resource Type: Conference Resource

  15. Inexpensive, Nonfluorinated Anions for Lithium Salts and Ionic Liquids for

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Lithium Battery Electrolytes | Department of Energy Anions for Lithium Salts and Ionic Liquids for Lithium Battery Electrolytes Inexpensive, Nonfluorinated Anions for Lithium Salts and Ionic Liquids for Lithium Battery Electrolytes 2010 DOE Vehicle Technologies and Hydrogen Programs Annual Merit Review and Peer Evaluation Meeting, June 7-11, 2010 -- Washington D.C. PDF icon es057_henderson_2010_p.pdf More Documents & Publications Inexpensive, Nonfluorinated (or Partially Fluorinated)

  16. Energy Department Completes Salt Coolant Material Transfer to Czech

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Republic for Advanced Reactor Research | Department of Energy Completes Salt Coolant Material Transfer to Czech Republic for Advanced Reactor Research Energy Department Completes Salt Coolant Material Transfer to Czech Republic for Advanced Reactor Research May 20, 2013 - 12:52pm Addthis News Media Contact (202) 586-4940 PRAGUE, CZECH REPUBLIC - The U.S. Department of Energy recently joined with the U.S. Embassy in Prague and the Czech Republic's Ministry of Industry and Trade to complete

  17. Structural Interactions within Lithium Salt Solvates: Acyclic Carbonates

    Office of Scientific and Technical Information (OSTI)

    and Esters (Journal Article) | SciTech Connect Structural Interactions within Lithium Salt Solvates: Acyclic Carbonates and Esters Citation Details In-Document Search Title: Structural Interactions within Lithium Salt Solvates: Acyclic Carbonates and Esters Solvate crystal structures serve as useful models for the molecular-level interactions within the diverse solvates present in liquid electrolytes. Although acyclic carbonate solvents are widely used for Li-ion battery electrolytes, only

  18. CAVERN ROOF STABILITY FOR NATURAL GAS STORAGE IN BEDDED SALT

    SciTech Connect (OSTI)

    DeVries, Kerry L; Mellegard, Kirby D; Callahan, Gary D; Goodman, William M

    2005-06-01

    This report documents research performed to develop a new stress-based criterion for predicting the onset of damage in salt formations surrounding natural gas storage caverns. Laboratory tests were conducted to investigate the effects of shear stress, mean stress, pore pressure, temperature, and Lode angle on the strength and creep characteristics of salt. The laboratory test data were used in the development of the new criterion. The laboratory results indicate that the strength of salt strongly depends on the mean stress and Lode angle. The strength of the salt does not appear to be sensitive to temperature. Pore pressure effects were not readily apparent until a significant level of damage was induced and the permeability was increased to allow penetration of the liquid permeant. Utilizing the new criterion, numerical simulations were used to estimate the minimum allowable gas pressure for hypothetical storage caverns located in a bedded salt formation. The simulations performed illustrate the influence that cavern roof span, depth, roof salt thickness, shale thickness, and shale stiffness have on the allowable operating pressure range. Interestingly, comparison of predictions using the new criterion with that of a commonly used criterion indicate that lower minimum gas pressures may be allowed for caverns at shallow depths. However, as cavern depth is increased, less conservative estimates for minimum gas pressure were determined by the new criterion.

  19. Sodium nitrate containing mixture for producing ceramic-glass-ceramic seal by microwave heating

    DOE Patents [OSTI]

    Blake, R.D.; Meek, T.T.

    1984-10-10

    A mixture for, and method of using such a mixture, for producing a ceramic-glass-ceramic seal by the use of microwave energy are disclosed, wherein the mixture comprises a glass sealing material, a coupling agent, and an oxidizer. The seal produced exhibits greater strength due to its different microstructure. Sodium nitrate is the most preferred oxidizer.

  20. EIS-0099: Remedial Actions at the Former Vitro Chemical Company Site, South Salt Lake, Salt Lake County, Utah

    Broader source: Energy.gov [DOE]

    The U.S. Department of Energy developed this statement to evaluate the environmental impacts of various scenarios associated with the cleanup of those residues remaining at the abandoned uranium mill tailings site located in South Salt Lake, Utah.

  1. Characterization of Organic Coatings on Hygroscopic Salt Particles and their Atmospheric Impacts

    SciTech Connect (OSTI)

    Zelenyuk, Alla; Ezell, Michael J.; Perraud, Veronique; Johnson, Stanley N.; Bruns, Emily; Yu, Yong; Imre, D.; Alexander, M. L.; Finlayson-Pitts, Barbara J.

    2010-03-30

    The photooxidation of ?-pinene in the presence of NO2, with and without added NaNO3 seed particles, has been studied in a large diameter flow tube. Particles formed by homogeneous nucleation and by condensation on the pre-existing seeds were sampled at various stages of the reaction, dried using four diffusion dryers, size selected at different mobility diameters (dm) using a differential mobility analyzer (DMA), and characterized with a single particle mass spectrometer (SPLAT II). It was found that homogeneously nucleated particles are spherical, have a density (?) of 1.25 0.02 g cm-3 ( 2 ?) and contain a significant amount of organic nitrates. The mass spectra of the low volatility products condensed on the NaNO3 seed particles were found to be virtually the same as in the case of homogeneous nucleation. The data show that the presence of even a submonolayer of organics on the NaNO3 particles causes water retention that leads to a decrease in particle density and that the amount of water retained increases with organic coating thickness. Thicker coatings appear to inhibit water evaporation from the particle seeds altogether. This suggests that in the atmosphere, where low volatility organics are plentiful, some hygroscopic salts will retain water and have different densities and refractive indices than expected in the absence of the organic coating. This water retention combined with the organic shell on the particles can potentially impact light scattering by these particles and activity as cloud condensation nuclei (CCN), as well as heterogeneous chemistry and photochemistry on the particles.

  2. LIFE Materails: Molten-Salt Fuels Volume 8

    SciTech Connect (OSTI)

    Moir, R; Brown, N; Caro, A; Farmer, J; Halsey, W; Kaufman, L; Kramer, K; Latkowski, J; Powers, J; Shaw, H; Turchi, P

    2008-12-11

    The goals of the Laser Inertial Fusion Fission Energy (LIFE) is to use fusion neutrons to fission materials with no enrichment and minimum processing and have greatly reduced wastes that are not of interest to making weapons. Fusion yields expected to be achieved in NIF a few times per day are called for with a high reliable shot rate of about 15 per second. We have found that the version of LIFE using TRISO fuel discussed in other volumes of this series can be modified by replacing the molten-flibe-cooled TRISO fuel zone with a molten salt in which the same actinides present in the TRISO particles are dissolved in the molten salt. Molten salts have the advantage that they are not subject to radiation damage, and hence overcome the radiation damage effects that may limit the lifetime of solid fuels such as TRISO-containing pebbles. This molten salt is pumped through the LIFE blanket, out to a heat exchanger and back into the blanket. To mitigate corrosion, steel structures in contact with the molten salt would be plated with tungsten or nickel. The salt will be processed during operation to remove certain fission products (volatile and noble and semi-noble fission products), impurities and corrosion products. In this way neutron absorbers (fission products) are removed and neutronics performance of the molten salt is somewhat better than that of the TRISO fuel case owing to the reduced parasitic absorption. In addition, the production of Pu and rare-earth elements (REE) causes these elements to build up in the salt, and leads to a requirement for a process to remove the REE during operation to insure that the solubility of a mixed (Pu,REE)F3 solid solution is not exceeded anywhere in the molten salt system. Removal of the REE will further enhance the neutronics performance. With molten salt fuels, the plant would need to be safeguarded because materials of interest for weapons are produced and could potentially be removed.

  3. A coarse-grained model with implicit salt for RNAs: Predicting 3D structure, stability and salt effect

    SciTech Connect (OSTI)

    Shi, Ya-Zhou; Wang, Feng-Hua; Wu, Yuan-Yan; Tan, Zhi-Jie

    2014-09-14

    To bridge the gap between the sequences and 3-dimensional (3D) structures of RNAs, some computational models have been proposed for predicting RNA 3D structures. However, the existed models seldom consider the conditions departing from the room/body temperature and high salt (1M NaCl), and thus generally hardly predict the thermodynamics and salt effect. In this study, we propose a coarse-grained model with implicit salt for RNAs to predict 3D structures, stability, and salt effect. Combined with Monte Carlo simulated annealing algorithm and a coarse-grained force field, the model folds 46 tested RNAs (?45 nt) including pseudoknots into their native-like structures from their sequences, with an overall mean RMSD of 3.5 and an overall minimum RMSD of 1.9 from the experimental structures. For 30 RNA hairpins, the present model also gives the reliable predictions for the stability and salt effect with the mean deviation ? 1.0 C of melting temperatures, as compared with the extensive experimental data. In addition, the model could provide the ensemble of possible 3D structures for a short RNA at a given temperature/salt condition.

  4. Assessment of the Use of Nitrogen Trifluoride for Purifying Coolant and Heat Transfer Salts in the Fluoride Salt-Cooled High-Temperature Reactor

    SciTech Connect (OSTI)

    Scheele, Randall D.; Casella, Andrew M.

    2010-09-28

    This report provides an assessment of the use of nitrogen trifluoride for removing oxide and water-caused contaminants in the fluoride salts that will be used as coolants in a molten salt cooled reactor.

  5. Azobenzene-based organic salts with ionic liquid and liquid crystalline properties

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Stappert, Kathrin; Muthmann, Johanna; Spielberg, Eike T.; Mudring, Anja -Verena

    2015-07-23

    Two sets of new azobenzene-based bromide salts are synthesized, and their thermal photochromic properties are studied. Both sets are based on the imidazolium cation. The first set (1) features a symmetric biscation where two imidazolium head groups (Im) with different alkyl chains (Cn) are connected to a central azobenzene unit (Azo): [Azo(C1-Im-Cn)2]; n = 6, 8, 10, 12, 14. The other one contains an n-alkyl-imidazolium cation (Cn-Im) bearing a terminal azobenzene unit (C1-Azo) substituted with an alkoxy chain (O-Cm) of either two (2) or six (3) carbon atoms: [C1-Azo-O-Cm-Im-Cn]; m = 2, n = 8, 10, 12 and m =more » 6, n = 8, 10, 12, 14, 16. For both cation classes, the influence of alkyl chains of varying length on the thermal phase behavior was investigated by differential scanning calorimetry (DSC) and polarizing optical microscopy (POM). For five compounds (Azo(-C1-Im-C12)2 (1d), Azo(-C1-Im-C12)2 (1e), C1-Azo-O-C2-Im-C10 (2b), C1-Azo-O-C2-Im-C12 (2c), and C1-Azo-O-C6-Im-C16 (3e)), the formation of a liquid crystalline phase was observed. The biscationic salts (1) are all comparatively high melting organic salts (180–240 °C), and only the two representatives with long alkylchains (C12 and C14) exhibit liquid crystallinity. The monocationic salts with an O–C2 bridge (2) melt between 140 and 170 °C depending on the alkyl chain length, but from an alkyl chain of 10 and more carbon atoms on they form a smectic A liquid crystalline phase. The representatives of the third set with a O–C6 bridge qualify as ionic liquids with melting points less than 100 °C. However, only the representative with a hexadecyl chain forms a liquid crystalline phase. Representative single crystals for all sets of cations could be grown that allowed for single crystal structure analysis. Together with small-angle X-ray scattering experiments they allow for a more detailed understanding of the thermal properties. As a result, through irradiation with UV-light (320–366 nm) all compounds undergo trans–cis isomerization, which reverses under visible light (440 nm).« less

  6. Alternative Fuels Data Center: Salt Lake City Fuels Vehicles With Natural

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Gas Salt Lake City Fuels Vehicles With Natural Gas to someone by E-mail Share Alternative Fuels Data Center: Salt Lake City Fuels Vehicles With Natural Gas on Facebook Tweet about Alternative Fuels Data Center: Salt Lake City Fuels Vehicles With Natural Gas on Twitter Bookmark Alternative Fuels Data Center: Salt Lake City Fuels Vehicles With Natural Gas on Google Bookmark Alternative Fuels Data Center: Salt Lake City Fuels Vehicles With Natural Gas on Delicious Rank Alternative Fuels Data

  7. Molten Salts for High Temperature Reactors: University of Wisconsin Molten Salt Corrosion and Flow Loop Experiments -- Issues Identified and Path Forward

    SciTech Connect (OSTI)

    Piyush Sabharwall; Matt Ebner; Manohar Sohal; Phil Sharpe; Thermal Hydraulics Group

    2010-03-01

    Considerable amount of work is going on regarding the development of high temperature liquid salts technology to meet future process needs of Next Generation Nuclear Plant. This report identifies the important characteristics and concerns of high temperature molten salts (with lesson learned at University of Wisconsin-Madison, Molten Salt Program) and provides some possible recommendation for future work

  8. CENTRAL PLATEAU REMEDIATION OPTIMIZATION STUDY

    SciTech Connect (OSTI)

    BERGMAN, T. B.; STEFANSKI, L. D.; SEELEY, P. N.; ZINSLI, L. C.; CUSACK, L. J.

    2012-09-19

    THE CENTRAL PLATEAU REMEDIATION OPTIMIZATION STUDY WAS CONDUCTED TO DEVELOP AN OPTIMAL SEQUENCE OF REMEDIATION ACTIVITIES IMPLEMENTING THE CERCLA DECISION ON THE CENTRAL PLATEAU. THE STUDY DEFINES A SEQUENCE OF ACTIVITIES THAT RESULT IN AN EFFECTIVE USE OF RESOURCES FROM A STRATEGIC PERSPECTIVE WHEN CONSIDERING EQUIPMENT PROCUREMENT AND STAGING, WORKFORCE MOBILIZATION/DEMOBILIZATION, WORKFORCE LEVELING, WORKFORCE SKILL-MIX, AND OTHER REMEDIATION/DISPOSITION PROJECT EXECUTION PARAMETERS.

  9. CENTRAL NEVPJJA SUPPLEMENTAL TEST AREA

    Office of Legacy Management (LM)

    r r r r r r t r r t r r r * r r r r r r CENTRAL NEVPJJA SUPPLEMENTAL TEST AREA ,FACILITY RECORDS 1970 UNITED STATES ATOMIC ENERGY COMMlSSION NEVADA OPERATIONS OFFICE LAS VEGAS, NEVADA September 1970 Prepared By Holmes & Narver. Inc. On-Continent Test Division P.O. Box 14340 Las Vegas, Nevada 338592 ...._- _._--_ .. -- - - - - - - .. .. - .. - - .. - - - CENTRAL NEVPJJA SUPPLEMENTAL TEST AREA FACILITY RECORDS 1970 This page intentionally left blank - - .. - - - PURPOSE This facility study has

  10. Effect of water in salt repositories. Final report

    SciTech Connect (OSTI)

    Baes, C.F. Jr.; Gilpatrick, L.O.; Kitts, F.G.; Bronstein, H.R.; Shor, A.J.

    1983-09-01

    Additional results confirm that during most of the consolidation of polycrystalline salt in brine, the previously proposed rate expression applies. The final consolidation, however, proceeds at a lower rate than predicted. The presence of clay hastens the consolidation process but does not greatly affect the previously observed relationship between permeability and void fraction. Studies of the migration of brine within polycrystalline salt specimens under stress indicate that the principal effect is the exclusion of brine as a result of consolidation, a process that evidently can proceed to completion. No clear effect of a temperature gradient could be identified. A previously reported linear increase with time of the reciprocal permeability of salt-crystal interfaces to brine was confirmed, though the rate of increase appears more nearly proportional to the product of sigma ..delta..P rather than sigma ..delta..P/sup 2/ (sigma is the uniaxial stress normal to the interface and ..delta..P is the hydraulic pressure drop). The new results suggest that a limiting permeability may be reached. A model for the permeability of salt-crystal interfaces to brine is developed that is reasonably consistent with the present results and may be used to predict the permeability of bedded salt. More measurements are needed, however, to choose between two limiting forms of the model.

  11. Vitrification of IFR and MSBR halide salt reprocessing wastes

    SciTech Connect (OSTI)

    Siemer, D.D.

    2013-07-01

    Both of the genuinely sustainable (breeder) nuclear fuel cycles (IFR - Integral Fast Reactor - and MSBR - Molten Salt Breeder Reactor -) studied by the USA's national laboratories would generate high level reprocessing waste (HLRW) streams consisting of a relatively small amount ( about 4 mole %) of fission product halide (chloride or fluoride) salts in a matrix comprised primarily (about 95 mole %) of non radioactive alkali metal halide salts. Because leach resistant glasses cannot accommodate much of any of the halides, most of the treatment scenarios previously envisioned for such HLRW have assumed a monolithic waste form comprised of a synthetic analog of an insoluble crystalline halide mineral. In practice, this translates to making a 'substituted' sodalite ('Ceramic Waste Form') of the IFR's chloride salt-based wastes and fluoroapatite of the MSBR's fluoride salt-based wastes. This paper discusses my experimental studies of an alternative waste management scenario for both fuel cycles that would separate/recycle the waste's halide and immobilize everything else in iron phosphate (Fe-P) glass. It will describe both how the work was done and what its results indicate about how a treatment process for both of those wastes should be implemented (fluoride and chloride behave differently). In either case, this scenario's primary advantages include much higher waste loadings, much lower overall cost, and the generation of a product (glass) that is more consistent with current waste management practices. (author)

  12. Method for making a uranium chloride salt product

    DOE Patents [OSTI]

    Miller, William E. (Naperville, IL); Tomczuk, Zygmunt (Lockport, IL)

    2004-10-05

    The subject apparatus provides a means to produce UCl.sub.3 in large quantities without incurring corrosion of the containment vessel or associated apparatus. Gaseous Cl is injected into a lower layer of Cd where CdCl.sub.2 is formed. Due to is lower density, the CdCl.sub.2 rises through the Cd layer into a layer of molten LiCl--KCL salt where a rotatable basket containing uranium ingots is suspended. The CdCl.sub.2 reacts with the uranium to form UCl.sub.3 and Cd. Due to density differences, the Cd sinks down to the liquid Cd layer and is reused. The UCl.sub.3 combines with the molten salt. During production the temperature is maintained at about 600.degree. C. while after the uranium has been depleted the salt temperature is lowered, the molten salt is pressure siphoned from the vessel, and the salt product LiCl--KCl-30 mol % UCl.sub.3 is solidified.

  13. Development of high temperature transport technology for LiCl-KCl eutectic salt in pyroprocessing

    SciTech Connect (OSTI)

    Lee, Sung Ho; Lee, Hansoo; Kim, In Tae; Kim, Jeong-Guk

    2013-07-01

    The development of high-temperature transport technologies for molten salt is a prerequisite and a key issue in the industrialization of pyro-reprocessing for advanced fuel cycle scenarios. The solution of a molten salt centrifugal pump was discarded because of the high corrosion power of a high temperature molten salt, so the suction pump solution was selected. An apparatus for salt transport experiments by suction was designed and tested using LiC-KCl eutectic salt. The experimental results of lab-scale molten salt transport by suction showed a 99.5% transport rate (ratio of transported salt to total salt) under a vacuum range of 100 mtorr - 10 torr at 500 Celsius degrees. The suction system has been integrated to the PRIDE (pyroprocessing integrated inactive demonstration) facility that is a demonstrator using non-irradiated materials (natural uranium and surrogate materials). The performance of the suction pump for the transport of molten salts has been confirmed.

  14. Injector nozzle for molten salt destruction of energetic waste materials

    DOE Patents [OSTI]

    Brummond, W.A.; Upadhye, R.S.

    1996-02-13

    An injector nozzle has been designed for safely injecting energetic waste materials, such as high explosives, propellants, and rocket fuels, into a molten salt reactor in a molten salt destruction process without premature detonation or back burn in the injection system. The energetic waste material is typically diluted to form a fluid fuel mixture that is injected rapidly into the reactor. A carrier gas used in the nozzle serves as a carrier for the fuel mixture, and further dilutes the energetic material and increases its injection velocity into the reactor. The injector nozzle is cooled to keep the fuel mixture below the decomposition temperature to prevent spontaneous detonation of the explosive materials before contact with the high-temperature molten salt bath. 2 figs.

  15. Injector nozzle for molten salt destruction of energetic waste materials

    DOE Patents [OSTI]

    Brummond, William A. (Livermore, CA); Upadhye, Ravindra S. (Pleasanton, CA)

    1996-01-01

    An injector nozzle has been designed for safely injecting energetic waste materials, such as high explosives, propellants, and rocket fuels, into a molten salt reactor in a molten salt destruction process without premature detonation or back burn in the injection system. The energetic waste material is typically diluted to form a fluid fuel mixture that is injected rapidly into the reactor. A carrier gas used in the nozzle serves as a carrier for the fuel mixture, and further dilutes the energetic material and increases its injection velocity into the reactor. The injector nozzle is cooled to keep the fuel mixture below the decomposition temperature to prevent spontaneous detonation of the explosive materials before contact with the high-temperature molten salt bath.

  16. Analytical methods for determining the reactivity of pyrochemical salts

    SciTech Connect (OSTI)

    Phillips, A.G.; Stakebake, J.L.

    1994-05-01

    Pyrochemical processes used for the purification of plutonium have generated quantities of residue that contain varying amounts of reactive metals such as potassium, sodium, calcium, and magnesium. These residues are currently considered hazardous and are being managed under RCRA because of the reactivity characteristic. This designation is based solely on process knowledge. Currently there is no approved procedure for determining the reactivity of a solid with water. A method is being developed to rapidly evaluate the reactivity of pyrochemical salts with water by measuring the rate of hydrogen generation. The method was initially tested with a magnesium containing pyrochemical salt. A detection limit of approximately 0.004 g of magnesium was established. A surrogate molten salt extraction residue was also tested. Extrapolation of test data resulted in a hydrogen generation rate of 4.4 mg/(g min).

  17. Central Electric Coop Inc | Open Energy Information

    Open Energy Info (EERE)

    Central Electric Coop Inc Place: Oregon Phone Number: 541-548-2144 Website: www.cec.coop Twitter: @CentralElectric Facebook: https:www.facebook.comCentralElectricCoop?frefnf...

  18. Salt transport extraction of transuranium elements from lwr fuel

    DOE Patents [OSTI]

    Pierce, R. Dean; Ackerman, John P.; Battles, James E.; Johnson, Terry R.; Miller, William E.

    1992-01-01

    A process of separating transuranium actinide values from uranium values present in spent nuclear oxide fuels which contain rare earth and noble metal fission products. The oxide fuel is reduced with Ca metal in the presence of CaCl.sub.2 and a Cu--Mg alloy containing not less than about 25% by weight Mg at a temperature in the range of from about 750.degree. C. to about 850.degree. C. to precipitate uranium metal and some of the noble metal fission products leaving the Cu--Mg alloy having transuranium actinide metals and rare earth fission product metals and some of the noble metal fission products dissolved therein. The CaCl.sub.2 having CaO and fission products of alkali metals and the alkali earth metals and iodine dissolved therein is separated and electrolytically treated with a carbon electrode to reduce the CaO to Ca metal while converting the carbon electrode to CO and CO.sub.2. The Ca metal and CaCl.sub.2 is recycled to reduce additional oxide fuel. The Cu--Mg alloy having transuranium metals and rare earth fission product metals and the noble metal fission products dissolved therein is contacted with a transport salt including Mg Cl.sub.2 to transfer Mg values from the transport salt to the Cu--Mg alloy while transuranium actinide and rare earth fission product metals transfer from the Cu--Mg alloy to the transport salt. Then the transport salt is mixed with a Mg--Zn alloy to transfer Mg values from the alloy to the transport salt while the transuranium actinide and rare earth fission product values dissolved in the salt are reduced and transferred to the Mg--Zn alloy.

  19. Salt transport extraction of transuranium elements from LWR fuel

    DOE Patents [OSTI]

    Pierce, R.D.; Ackerman, J.P.; Battles, J.E.; Johnson, T.R.; Miller, W.E.

    1992-11-03

    A process is described for separating transuranium actinide values from uranium values present in spent nuclear oxide fuels which contain rare earth and noble metal fission products. The oxide fuel is reduced with Ca metal in the presence of CaCl[sub 2] and a Cu--Mg alloy containing not less than about 25% by weight Mg at a temperature in the range of from about 750 C to about 850 C to precipitate uranium metal and some of the noble metal fission products leaving the Cu--Mg alloy having transuranium actinide metals and rare earth fission product metals and some of the noble metal fission products dissolved therein. The CaCl[sub 2] having CaO and fission products of alkali metals and the alkali earth metals and iodine dissolved therein is separated and electrolytically treated with a carbon electrode to reduce the CaO to Ca metal while converting the carbon electrode to CO and CO[sub 2]. The Ca metal and CaCl[sub 2] is recycled to reduce additional oxide fuel. The Cu--Mg alloy having transuranium metals and rare earth fission product metals and the noble metal fission products dissolved therein is contacted with a transport salt including MgCl[sub 2] to transfer Mg values from the transport salt to the Cu--Mg alloy while transuranium actinide and rare earth fission product metals transfer from the Cu--Mg alloy to the transport salt. Then the transport salt is mixed with a Mg--Zn alloy to transfer Mg values from the alloy to the transport salt while the transuranium actinide and rare earth fission product values dissolved in the salt are reduced and transferred to the Mg--Zn alloy. 2 figs.

  20. DWPF coupled feed flowsheet material balance with batch one sludge and copper nitrate catalyst

    SciTech Connect (OSTI)

    Choi, A.S.

    1993-09-28

    The SRTC has formally transmitted a recommendation to DWPF to replace copper formate with copper nitrate as the catalyst form during precipitate hydrolysis [1]. The SRTC was subsequently requested to formally document the technical bases for the recommendation. A memorandum was issued on August 23, 1993 detailing the activities (and responsible individuals) necessary to address the impact of this change in catalyst form on process compatibility, safety, processibility environmental impact and product glass quality [2]. One of the activities identified was the preparation of a material balance in which copper nitrate is substituted for copper formate and the identification of key comparisons between this material balance and the current Batch 1 sludge -- Late Wash material balance [3].

  1. Modular & Scalable Molten Salt Plant Design | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Modular & Scalable Molten Salt Plant Design Modular & Scalable Molten Salt Plant Design This presentation was delivered at the SunShot Concentrating Solar Power (CSP) Program Review 2013, held April 23-25, 2013 near Phoenix, Arizona. PDF icon csp_review_meeting_042313_tyner.pdf More Documents & Publications Advance Patent Waiver W(A)2011-018 SunShot Vision Study: February 2012 (Book), SunShot, Energy Efficiency & Renewable Energy (EERE) Abengoa-Tilley RevD

  2. Simulation of water transport in heated rock salt

    SciTech Connect (OSTI)

    Schlich, M.; Jockwer, N.

    1986-01-01

    This paper summarizes computer simulation studies on water transport in German rock salt. Based on JOCKWERS experimental investigations on water content and water liberation, the object of these studies was to select a water transport model, that matches the water inflow which was measured in some heater experiments in the Asse Salt Mine. The main result is, that an evaporation front model, with Knudsen-type vapor transport combined with fluid transport by thermal expansion of the adsorbed water layers in the non evaporated zone, showed the best agreement with experimental evidence.

  3. Materials and methods for stabilizing nanoparticles in salt solutions

    DOE Patents [OSTI]

    Robinson, David Bruce; Zuckermann, Ronald; Buffleben, George M.

    2013-06-11

    Sequence-specific polymers are proving to be a powerful approach to assembly and manipulation of matter on the nanometer scale. Ligands that are peptoids, or sequence-specific N-functional glycine oligomers, allow precise and flexible control over the arrangement of binding groups, steric spacers, charge, and other functionality. We have synthesized short peptoids that can prevent the aggregation of gold nanoparticles in high-salt environments including divalent salt, and allow co-adsorption of a single DNA molecule. This degree of precision and versatility is likely to prove essential in bottom-up assembly of nanostructures and in biomedical applications of nanomaterials.

  4. Central Iowa Energy | Open Energy Information

    Open Energy Info (EERE)

    navigation, search Name: Central Iowa Energy Place: Newton, Iowa Zip: 50208 Product: Biodiesel producers in Newton, Iowa. References: Central Iowa Energy1 This article is a...

  5. Ecole Centrale Paris | Open Energy Information

    Open Energy Info (EERE)

    Ecole Centrale Paris Jump to: navigation, search Name: Ecole Centrale Paris Place: France Sector: Services Product: General Financial & Legal Services ( Government Public sector...

  6. Central Plateau Principles Public Involvement Advice DETAILED...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    v0, 12914 Central Plateau Principles Public Involvement Advice DETAILED BACKGROUND Cleanup of Hanford's Central Plateau is expected to take another four decades or longer, and...

  7. South Central Electric Assn | Open Energy Information

    Open Energy Info (EERE)

    South Central Electric Assn Place: Minnesota Website: www.southcentralelectric.com Facebook: https:www.facebook.compagesSouth-Central-Electric-Association554997227953077...

  8. Vestas Central Europe | Open Energy Information

    Open Energy Info (EERE)

    Central Europe Jump to: navigation, search Name: Vestas Central Europe Place: Husum, Germany Zip: 25813 Sector: Wind energy Product: Husum-based subsidiary of Vestas Wind...

  9. Aqueous nitrate waste treatment: Technology comparison, cost/benefit, and market analysis

    SciTech Connect (OSTI)

    Not Available

    1994-01-01

    The purpose of this analysis is to provide information necessary for the Department of Energy (DOE) to evaluate the practical utility of the Nitrate to Ammonia and Ceramic or Glass (NAC/NAG/NAX) process, which is under development in the Oak Ridge National Laboratory. The NAC/NACx/NAX process can convert aqueous radioactive nitrate-laden waste to a glass, ceramic, or grout solid waste form. The tasks include, but are not limited to, the following: Identify current commercial technologies to meet hazardous and radiological waste disposal requirements. The technologies may be thermal or non-thermal but must be all inclusive (i.e., must convert a radionuclide-containing nitrate waste with a pH around 12 to a stable form that can be disposed at permitted facilities); evaluate and compare DOE-sponsored vitrification, grouting, and minimum additive waste stabilization projects for life-cycle costs; compare the technologies above with respect to material costs, capital equipment costs, operating costs, and operating efficiencies. For the NAC/NAG/NAX process, assume aluminum reactant is government furnished and ammonia gas may be marketed; compare the identified technologies with respect to frequency of use within DOE for environmental management applications with appropriate rationale for use; Assess the potential size of the DOE market for the NAC/NAG/NAX process; assess and off-gas issues; and compare with international technologies, including life-cycle estimates.

  10. Effect of Phosphate, Fluoride, and Nitrate on Gibbsite Dissolution Rate and Solubility

    SciTech Connect (OSTI)

    Herting, Daniel L.

    2014-01-29

    Laboratory tests have been completed with simulated tank waste samples to investigate the effects of phosphate, fluoride, and nitrate on the dissolution rate and equilibrium solubility of gibbsite in sodium hydroxide solution at 22 and 40{degrees}C. Results are compared to relevant literature data and to computer model predictions. The presence of sodium nitrate (3 M) caused a reduction in the rate of gibbsite dissolution in NaOH, but a modest increase in the equilibrium solubility of aluminum. The increase in solubility was not as large, though, as the increase predicted by the computer model. The presence of phosphate, either as sodium phosphate or sodium fluoride phosphate, had a negligible effect on the rate of gibbsite dissolution, but caused a slight increase in aluminum solubility. The magnitude of the increased solubility, relative to the increase caused by sodium nitrate, suggests that the increase is due to ionic strength (or water activity) effects, rather than being associated with the specific ion involved. The computer model predicted that phosphate would cause a slight decrease in aluminum solubility, suggesting some Al-PO4 interaction. No evidence was found of such an interaction.

  11. TREATMENT TESTS FOR EX SITU REMOVAL OF CHROMATE & NITRATE & URANIUM (VI) FROM HANFORD (100-HR-3) GROUNDWATER FINAL REPORT

    SciTech Connect (OSTI)

    BECK MA; DUNCAN JB

    1994-01-03

    This report describes batch and ion exchange column laboratory scale studies investigating ex situ methods to remove chromate (chromium [VI]), nitrate (NO{sub 3}{sup -}) and uranium (present as uranium [VI]) from contaminated Hanford site groundwaters. The technologies investigated include: chemical precipitation or coprecipitation to remove chromate and uranium; and anion exchange to remove chromate, uranium and nitrate. The technologies investigated were specified in the 100-HR-3 Groundwater Treatability Test Plan. The method suggested for future study is anion exchange.

  12. Molten-Salt-Based Growth of Group III Nitrides

    DOE Patents [OSTI]

    Waldrip, Karen E. (Albuquerque, NM); Tsao, Jeffrey Y. (Albuquerque, NM); Kerley, Thomas M. (Albuquerque, NM)

    2008-10-14

    A method for growing Group III nitride materials using a molten halide salt as a solvent to solubilize the Group-III ions and nitride ions that react to form the Group III nitride material. The concentration of at least one of the nitride ion or Group III cation is determined by electrochemical generation of the ions.

  13. Molten salt processing of mixed wastes with offgas condensation

    SciTech Connect (OSTI)

    Cooper, J.F.; Brummond, W.; Celeste, J.; Farmer, J.; Hoenig, C.; Krikorian, O.H.; Upadhye, R. ); Gay, R.L.; Stewart, A.; Yosim, S. . Energy Systems Group)

    1991-05-13

    We are developing an advanced process for treatment of mixed wastes in molten salt media at temperatures of 700--1000{degrees}C. Waste destruction has been demonstrated in a single stage oxidation process, with destruction efficiencies above 99.9999% for many waste categories. The molten salt provides a heat transfer medium, prevents thermal surges, and functions as an in situ scrubber to transform the acid-gas forming components of the waste into neutral salts and immobilizes potentially fugitive materials by a combination of particle wetting, encapsulation and chemical dissolution and solvation. Because the offgas is collected and assayed before release, and wastes containing toxic and radioactive materials are treated while immobilized in a condensed phase, the process avoids the problems sometimes associated with incineration processes. We are studying a potentially improved modification of this process, which treats oxidizable wastes in two stages: pyrolysis followed by catalyzed molten salt oxidation of the pyrolysis gases at ca. 700{degrees}C. 15 refs., 5 figs., 1 tab.

  14. Decommissioning of the Molten Salt Reactor Experiment: A technical evaluation

    SciTech Connect (OSTI)

    Notz, K.J.

    1988-01-01

    This report completes a technical evaluation of decommissioning planning for the former Molten Salt Reactor Experiment, which was shut down in December, 1969. The key issues revolve around the treatment and disposal of some five tons of solid fuel salt which contains over 30 kg of fissionable uranium-233 plus fission products and higher actinides. The chemistry of this material is complicated by the formation of elemental fluorine via a radiolysis reaction under certain conditions. Supporting studies carried out as part of this evaluation include (a) a broad scope analysis of possible options for storage/disposal of the salts, (b) calculation of nuclide decay in future years, (c) technical evaluation of the containment facility and hot cell penetrations, (d) review and update of surveillance and maintenance procedures, (e) measurements of facility groundwater radioactivity and sump pump operation, (f) laboratory studies of the radiolysis reaction, and (g) laboratory studies which resulted in finding a suitable getter for elemental fluorine. In addition, geologic and hydrologic factors of the surrounding area were considered, and also the implications of entombment of the fuel in-place with concrete. The results of this evaluation show that the fuel salt cannot be left in its present form and location permanently. On the other hand, extended storage in its present form is quite acceptable for 20 to 30 years, or even longer. For continued storage in-place, some facility modifications are recommended. 30 refs., 5 figs., 9 tabs.

  15. TGS measurements of pyrochemical salts at Rocky Flats

    SciTech Connect (OSTI)

    Mercer, D. J.; Hansen, J. S.; Lestone, J. P.; Prettyman, T. H.

    2001-01-01

    A new skid-mounted tomographic gamma scanner (TGS) was designed to assist in the decommissioning of Rocky Flats Building 37 1, This instrument was used to assay pyrochemical salts as a prerequisite for disposal at the Waste Isolation Pilot Plant (WIPP). The following paper discusses measurement challenges and results from the first year of operation of the instrument.

  16. Salt Lake City, Utah: Solar in Action (Brochure)

    SciTech Connect (OSTI)

    Not Available

    2011-10-01

    This brochure provides an overview of the challenges and successes of Salt Lake City, UT, a 2007 Solar America City awardee, on the path toward becoming a solar-powered community. Accomplishments, case studies, key lessons learned, and local resource information are given.

  17. Sample Results from Routine Salt Batch 7 Samples

    SciTech Connect (OSTI)

    Peters, T.

    2015-05-13

    Strip Effluent Hold Tank (SEHT) and Decontaminated Salt Solution Hold Tank (DSSHT) samples from several of the microbatches of Integrated Salt Disposition Project (ISDP) Salt Batch (Macrobatch) 7B have been analyzed for 238Pu, 90Sr, 137Cs, Inductively Coupled Plasma Emission Spectroscopy (ICPES), and Ion Chromatography Anions (IC-A). The results from the current microbatch samples are similar to those from earlier samples from this and previous macrobatches. The Actinide Removal Process (ARP) and the Modular Caustic-Side Solvent Extraction Unit (MCU) continue to show more than adequate Pu and Sr removal, and there is a distinct positive trend in Cs removal, due to the use of the Next Generation Solvent (NGS). The Savannah River National Laboratory (SRNL) notes that historically, most measured Concentration Factor (CF) values during salt processing have been in the 12-14 range. However, recent processing gives CF values closer to 11. This observation does not indicate that the solvent performance is suffering, as the Decontamination Factor (DF) has still maintained consistently high values. Nevertheless, SRNL will continue to monitor for indications of process upsets. The bulk chemistry of the DSSHT and SEHT samples do not show any signs of unusual behavior.

  18. BLENDING ANALYSIS FOR RADIOACTIVE SALT WASTE PROCESSING FACILITY

    SciTech Connect (OSTI)

    Lee, S.

    2012-05-10

    Savannah River National Laboratory (SRNL) evaluated methods to mix and blend the contents of the blend tanks to ensure the contents are properly blended before they are transferred from the blend tank such as Tank 21 and Tank 24 to the Salt Waste Processing Facility (SWPF) feed tank. The tank contents consist of three forms: dissolved salt solution, other waste salt solutions, and sludge containing settled solids. This paper focuses on developing the computational model and estimating the operation time of submersible slurry pump when the tank contents are adequately blended prior to their transfer to the SWPF facility. A three-dimensional computational fluid dynamics approach was taken by using the full scale configuration of SRS Type-IV tank, Tank 21H. Major solid obstructions such as the tank wall boundary, the transfer pump column, and three slurry pump housings including one active and two inactive pumps were included in the mixing performance model. Basic flow pattern results predicted by the computational model were benchmarked against the SRNL test results and literature data. Tank 21 is a waste tank that is used to prepare batches of salt feed for SWPF. The salt feed must be a homogeneous solution satisfying the acceptance criterion of the solids entrainment during transfer operation. The work scope described here consists of two modeling areas. They are the steady state flow pattern calculations before the addition of acid solution for tank blending operation and the transient mixing analysis during miscible liquid blending operation. The transient blending calculations were performed by using the 95% homogeneity criterion for the entire liquid domain of the tank. The initial conditions for the entire modeling domain were based on the steady-state flow pattern results with zero second phase concentration. The performance model was also benchmarked against the SRNL test results and literature data.

  19. Amended Record of Decision for the Savannah River Site Salt Processing...

    Office of Environmental Management (EM)

    33.8 million gallons (Mgal) of salt waste are currently stored in underground waste storage tanks at SRS. This waste, along with future salt waste forecasted to be sent to the...

  20. Sample results from the interim salt disposition program macrobatch 9 tank 21H qualification samples

    SciTech Connect (OSTI)

    Peters, T. B.

    2015-11-01

    Savannah River National Laboratory (SRNL) analyzed samples from Tank 21H in support of qualification of Macrobatch (Salt Batch) 9 for the Interim Salt Disposition Program (ISDP). This document reports characterization data on the samples of Tank 21H.

  1. ,"U.S. Natural Gas Salt Underground Storage Activity-Injects...

    U.S. Energy Information Administration (EIA) Indexed Site

    12:20:34 AM" "Back to Contents","Data 1: U.S. Natural Gas Salt Underground Storage Activity-Injects (MMcf)" "Sourcekey","N5440US2" "Date","U.S. Natural Gas Salt Underground...

  2. ,"U.S. Natural Gas Non-Salt Underground Storage Activity-Net...

    U.S. Energy Information Administration (EIA) Indexed Site

    AM" "Back to Contents","Data 1: U.S. Natural Gas Non-Salt Underground Storage Activity-Net (MMcf)" "Sourcekey","N5560US2" "Date","U.S. Natural Gas Non-Salt Underground...

  3. Corrosion in Very High-Temperature Molten Salt for Next Generation...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Corrosion in Very High-Temperature Molten Salt for Next Generation CSP Systems Corrosion in Very High-Temperature Molten Salt for Next Generation CSP Systems This presentation was ...

  4. Methods of producing sulfate salts of cations from heteroatomic compounds and dialkyl sulfates and uses thereof

    DOE Patents [OSTI]

    Friesen, Cody A.; Wolfe, Derek; Johnson, Paul Bryan

    2015-09-29

    Methods of preparing sulfate salts of heteroatomic compounds using dialkyl sulfates as a primary reactant are disclosed. Also disclosed are methods of making ionic liquids from the sulfate salts of the heteroatomic compound, and electrochemical cells comprising the ionic liquids.

  5. Neutrinoless Double Beta Decay in Light of SNO Salt Data (Journal...

    Office of Scientific and Technical Information (OSTI)

    Neutrinoless Double Beta Decay in Light of SNO Salt Data Citation Details In-Document Search Title: Neutrinoless Double Beta Decay in Light of SNO Salt Data In the SNO data from...

  6. BASIN ANALYSIS AND PETROLEUM SYSTEM CHARACTERIZATION AND MODELING, INTERIOR SALT BASINS, CENTRAL AND EASTERN GULF OF MEXICO

    SciTech Connect (OSTI)

    Ernest A. Mancini; Donald A. Goddard

    2005-08-01

    The principal research effort for Year 3 of the project is basin modeling and petroleum system identification, comparative basin evaluation and resource assessment. In the first six (6) months of Year 3, the research focus is on basin modeling and petroleum system identification and the remainder of the year the emphasis is on the comparative basin evaluation and resource assessment. No major problems have been encountered to date, and the project is on schedule.

  7. Basin Analysis and Petroleum System Characterization and Modeling, Interior Salt Basins, Central and Eastern Gulf of Mexico

    SciTech Connect (OSTI)

    Ernest A. Mancini

    2006-07-31

    The principal research effort for Year 1 of Phase 2 (Concept Demonstration) of the project is Smackover petroleum system characterization and modeling. The necessary software applications are in the process of being acquired to accomplish this work. No major problems have been encountered to date, and the project is on schedule.

  8. Basin Analysis and Petroleum System Characterization and Modelling, Interior Salt Basins, Central and Eastern Gulf of Mexico

    SciTech Connect (OSTI)

    Ernest A. Mancini

    2006-09-30

    The principal research effort for Year 1 of Phase 2 (Concept Demonstration) of the project is Smackover petroleum system characterization and modeling. The necessary software applications have been acquired to accomplish this work. No major problems have been encountered to date, and the project is on schedule.

  9. Basin Analysis and Petroleum System Characterization and Modeling, Interior Salt Basins, Central and Eastern Gulf of Mexico

    SciTech Connect (OSTI)

    Ernest A. Mancini

    2006-12-31

    The principal research effort for Year 1 of Phase 2 (Concept Demonstration) of the project is Smackover petroleum system characterization and modeling. The necessary software applications have been acquired to accomplish this work. No major problems have been encountered to date, and the project is on schedule.

  10. Summary - Salt Waste Processing Facility Design at the Savannah River Site

    Office of Environmental Management (EM)

    Salt Waste Processing Facility ETR Report Date: November 2006 ETR-4 United States Department of Energy Office of Environmental Management (DOE-EM) External Technical Review of the Salt Waste Processing Facility Design at the Savannah River Site (SRS) Why DOE-EM Did This Review The Salt Waste Processing Facility (SWPF) is intended to remove and concentrate the radioactive strontium (Sr), actinides, and cesium (Cs) from the bulk salt waste solutions in the SRS high-level waste tanks. The sludge

  11. Savannah River Site Salt Waste Processing Facility Technology Readiness Assessment Report

    Office of Environmental Management (EM)

    Savannah River Site Salt Waste Processing Facility Technology Readiness Assessment Report Kurt D. Gerdes Harry D. Harmon Herbert G. Sutter Major C. Thompson John R. Shultz Sahid C. Smith July 13, 2009 Prepared by the U.S. Department of Energy Washington, D.C. SRS Salt Waste Processing Facility Technology Readiness Assessment July 13, 2009 ii This page intentionally left blank SRS Salt Waste Processing Facility Technology Readiness Assessment July 13, 2009 iii SRS Salt Waste Processing Facility

  12. Synthesis of acid addition salt of delta-aminolevulinic acid from 5-bromo levulinic acid esters

    DOE Patents [OSTI]

    Moens, Luc (Lakewood, CO)

    2003-06-24

    A process of preparing an acid addition salt of delta-aminolevulinc acid comprising: a) dissolving a lower alkyl 5-bromolevulinate and hexamethylenetetramine in a solvent selected from the group consisting of water, ethyl acetate, chloroform, acetone, ethanol, tetrahydrofuran and acetonitrile, to form a quaternary ammonium salt of the lower alkyl 5-bromolevulinate; and b) hydrolyzing the quaternary ammonium salt with an inorganic acid to form an acid addition salt of delta-aminolevulinic acid.

  13. Electrodialysis-based separation process for salt recovery and recycling from waste water

    DOE Patents [OSTI]

    Tsai, Shih-Perng (Naperville, IL)

    1997-01-01

    A method for recovering salt from a process stream containing organic contaminants is provided, comprising directing the waste stream to a desalting electrodialysis unit so as to create a concentrated and purified salt permeate and an organic contaminants containing stream, and contacting said concentrated salt permeate to a water-splitting electrodialysis unit so as to convert the salt to its corresponding base and acid.

  14. Electrodialysis-based separation process for salt recovery and recycling from waste water

    DOE Patents [OSTI]

    Tsai, S.P.

    1997-07-08

    A method for recovering salt from a process stream containing organic contaminants is provided, comprising directing the waste stream to a desalting electrodialysis unit so as to create a concentrated and purified salt permeate and an organic contaminants-containing stream, and contacting said concentrated salt permeate to a water-splitting electrodialysis unit so as to convert the salt to its corresponding base and acid. 6 figs.

  15. Central Air Conditioning | Department of Energy

    Energy Savers [EERE]

    Central Air Conditioning Central Air Conditioning Central air conditioners circulate cool air through a system of supply and return ducts. | Photo courtesy of ©iStockphoto/DonNichols. Central air conditioners circulate cool air through a system of supply and return ducts. | Photo courtesy of ©iStockphoto/DonNichols. Central air conditioners circulate cool air through a system of supply and return ducts. Supply ducts and registers (i.e., openings in the walls, floors, or ceilings covered by

  16. DOE - Office of Legacy Management -- Central

    Office of Legacy Management (LM)

    Nevada Central Nevada Test Area (CNTA), Nevada, Site Key Documents and Links All documents are Adobe Acrobat files. pdf_icon Key Documents Fact Sheet 2014 Groundwater Monitoring Report Central Nevada Test Area, Corrective Action Unit 443 Closure Report Central Nevada Test Area Subsurface Corrective Action Unit 443 December 2014 Groundwater Sampling at the Central Nevada Test Area Internal links Central Nevada Test Area Document Archives Please be green. Do not print these documents unless

  17. Sample Results from the Interim Salt Disposition Program Macrobatch 6 Tank 21H Qualification Samples

    SciTech Connect (OSTI)

    Peters, T. B.; Fink, S. D.

    2012-12-11

    Savannah River National Laboratory (SRNL) analyzed samples from Tank 21H in support of qualification of Macrobatch (Salt Batch) 6 for the Interim Salt Disposition Project (ISDP). This document reports partial results of the analyses of samples of Tank 21H. No issues with the projected Salt Batch 6 strategy are identified.

  18. Sample Results From The Interim Salt Disposition Program Macrobatch 6 Tank 21H Qualification Samples

    SciTech Connect (OSTI)

    Peters, T. B.; Fink, S. D.

    2012-12-20

    Savannah River National Laboratory (SRNL) analyzed samples from Tank 21H in support of qualification of Macrobatch (Salt Batch) 6 for the Interim Salt Disposition Project (ISDP). This document reports partial results of the analyses of samples of Tank 21H. No issues with the projected Salt Batch 6 strategy are identified.

  19. Bases, Assumptions, and Results of the Flowsheet Calculations for the Decision Phase Salt Disposition Alternatives

    SciTech Connect (OSTI)

    Elder, H.H.

    2001-07-11

    The HLW salt waste (salt cake and supernate) now stored at the SRS must be treated to remove insoluble sludge solids and reduce the soluble concentration of radioactive cesium radioactive strontium and transuranic contaminants (principally Pu and Np). These treatments will enable the salt solution to be processed for disposal as saltstone, a solid low-level waste.

  20. DOE - Office of Legacy Management -- Tatum Salt Dome Test Site - MS 01

    Office of Legacy Management (LM)

    Tatum Salt Dome Test Site - MS 01 FUSRAP Considered Sites Site: Tatum Salt Dome Test Site (MS.01) Designated Name: Alternate Name: Location: Evaluation Year: Site Operations: Site Disposition: Radioactive Materials Handled: Primary Radioactive Materials Handled: Radiological Survey(s): Site Status: Also see Documents Related to Tatum Salt Dome Test Site

  1. Cold adaptation of the mononuclear molybdoenzyme periplasmic nitrate reductase from the Antarctic bacterium Shewanella gelidimarina

    SciTech Connect (OSTI)

    Simpson, Philippa J.L.; Codd, Rachel; School of Medical Sciences and Bosch Institute, University of New South Wales, New South Wales 2006

    2011-11-04

    Highlights: Black-Right-Pointing-Pointer Cold-adapted phenotype of NapA from the Antarctic bacterium Shewanella gelidimarina. Black-Right-Pointing-Pointer Protein homology model of NapA from S. gelidimarina and mesophilic homologue. Black-Right-Pointing-Pointer Six amino acid residues identified as lead candidates governing NapA cold adaptation. Black-Right-Pointing-Pointer Molecular-level understanding of designing cool-temperature in situ oxyanion sensors. -- Abstract: The reduction of nitrate to nitrite is catalysed in bacteria by periplasmic nitrate reductase (Nap) which describes a system of variable protein subunits encoded by the nap operon. Nitrate reduction occurs in the NapA subunit, which contains a bis-molybdopterin guanine dinucleotide (Mo-MGD) cofactor and one [4Fe-4S] iron-sulfur cluster. The activity of periplasmic nitrate reductase (Nap) isolated as native protein from the cold-adapted (psychrophilic) Antarctic bacterium Shewanella gelidimarina (Nap{sub Sgel}) and middle-temperature adapted (mesophilic) Shewanella putrefaciens (Nap{sub Sput}) was examined at varied temperature. Irreversible deactivation of Nap{sub Sgel} and Nap{sub Sput} occurred at 54.5 and 65 Degree-Sign C, respectively. When Nap{sub Sgel} was preincubated at 21-70 Degree-Sign C for 30 min, the room-temperature nitrate reductase activity was maximal and invariant between 21 and 54 Degree-Sign C, which suggested that Nap{sub Sgel} was poised for optimal catalysis at modest temperatures and, unlike Nap{sub Sput}, did not benefit from thermally-induced refolding. At 20 Degree-Sign C, Nap{sub Sgel} reduced selenate at 16% of the rate of nitrate reduction. Nap{sub Sput} did not reduce selenate. Sequence alignment showed 46 amino acid residue substitutions in Nap{sub Sgel} that were conserved in NapA from mesophilic Shewanella, Rhodobacter and Escherichia species and could be associated with the Nap{sub Sgel} cold-adapted phenotype. Protein homology modeling of Nap{sub Sgel} using a mesophilic template with 66% amino acid identity showed the majority of substitutions occurred at the protein surface distal to the Mo-MGD cofactor. Two mesophilic {r_reversible} psychrophilic substitutions (Asn {r_reversible} His, Val {r_reversible} Trp) occurred in a region close to the surface of the NapA substrate funnel resulting in potential interdomain {pi}-{pi} and/or cation-{pi} interactions. Three mesophilic {r_reversible} psychrophilic substitutions occurred within 4.5 A of the Mo-MGD cofactor (Phe {r_reversible} Met, Ala {r_reversible} Ser, Ser {r_reversible} Thr) resulting in local regions that varied in hydrophobicity and hydrogen bonding networks. These results contribute to the understanding of thermal protein adaptation in a redox-active mononuclear molybdenum enzyme and have implications in optimizing the design of low-temperature environmental biosensors.

  2. Summary - Salt Waste Processing Facility Design at the Savannah...

    Office of Environmental Management (EM)

    priority technical risks be addressed: Completion of further design without final geotechnical data potentially could result in requiring redesign of the PC-3 Central Process...

  3. Comparison of FTIR and Particle Mass Spectrometry for the Measurement of Paticulate Organic Nitrates

    SciTech Connect (OSTI)

    Bruns, Emily; Perraud, Veronique; Zelenyuk, Alla; Ezell, Michael J.; Johnson, Stanley N.; Yu, Yong; Imre, D.; Finlayson-Pitts, Barbara J.; Alexander, M. L.

    2010-02-01

    While multifunctional organic nitrates are formed during the atmospheric oxidation of volatile organic compounds, relatively little is known about their signatures in particle mass spectrometers. High resolution time-of-flight aerosol mass spectrometry (HR-ToF-AMS) was applied to NH4NO3, NaNO3 and isosorbide 5-mononitrate (IMN) particles, and to secondary organic aerosol (SOA) from NO3 radical reactions at 22 C and 1 atm in air with and pinene, 3-carene, limonene and isoprene. For comparison, single particle laser ablation mass spectra (SPLAT II) were also obtained for IMN and SOA from the pinene reaction. The mass spectra of all particles exhibit significant intensity at m/z 30, and for the SOA, weak peaks corresponding to various organic fragments containing nitrogen [CxHyNzOa]+ were identified using HR-ToF-AMS. The NO+/NO2+ ratios from HR-ToF-AMS were 10-15 for IMN and the SOA from the and pinene, 3-carene and limonene reactions, ~5 for the isoprene reaction, 2.4 for NH4NO3 and 80 for NaNO3. The N/H ratios from HR-ToF-AMS for the SOA were smaller by a factor of 2 to 4 than the -ONO2/C-H ratios measured using FTIR on particles impacted on ZnSe windows. While the NO+/NO2+ ratio may provide a generic indication of organic nitrates under some conditions, specific identification of particulate organic nitrates awaits further development of particle mass spectrometry techniques.

  4. Central exclusive production at RHIC

    SciTech Connect (OSTI)

    Adamczyk, Leszek; Guryn, W?odek; Turnau, Jacek

    2014-11-10

    The present status and future plans of the physics program of Central Exclusive Production (CEP) at RHIC are described. The measurements are based on the detection of the forward protons from the Double Pomeron Exchange (DPE) process in the Roman Pot system and of the recoil system of charged particles from the DPE process measured in the STAR experiments Time Projection Chamber (TPC). The data described here were taken using polarized proton-proton collisions at ps = 200 GeV. The preliminary spectra of two pion and four pion invariant mass reconstructed by STAR TPC in central region of pseudo-rapidity |#17;| < 1, are presented. Near future plans to take data with the current system at center-of-mass energy ps = 200 GeV and plans to upgrade the forward proton tagging sys- tem are presented. Also a possible addition of the Roman Pots to the sPHENIX detector is discussed.

  5. MRDIS Standalone Central Alarm Station

    Energy Science and Technology Software Center (OSTI)

    2012-09-12

    The MRDIS Standalone Central Alarm Station(MRDIS-CAS} is a software system for receiving, storing, and reviewing radiation data collected by the Mobile Radiation Detection and Identification System (MRDIS}, a mobile radiation scanning system developed for use in foreign ports for the DOE Megaports Initiative. It is designed to run on one of the on board computers in the MRDIS cab. It will collect, store, and display data from the MRDIS without the need for wireless communicationsmore » or centralized server technology. It is intended to be a lightweight replacement for a distributed Megaports communication system in ports where the necessary communications infrastructure does not exist for a full Megaports communications system.« less

  6. Central exclusive production at RHIC

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Adamczyk, Leszek; Guryn, W?odek; Turnau, Jacek

    2014-11-10

    The present status and future plans of the physics program of Central Exclusive Production (CEP) at RHIC are described. The measurements are based on the detection of the forward protons from the Double Pomeron Exchange (DPE) process in the Roman Pot system and of the recoil system of charged particles from the DPE process measured in the STAR experiments Time Projection Chamber (TPC). The data described here were taken using polarized proton-proton collisions at ps = 200 GeV. The preliminary spectra of two pion and four pion invariant mass reconstructed by STAR TPC in central region of pseudo-rapidity |#17;| more1, are presented. Near future plans to take data with the current system at center-of-mass energy ps = 200 GeV and plans to upgrade the forward proton tagging sys- tem are presented. Also a possible addition of the Roman Pots to the sPHENIX detector is discussed.less

  7. The CDF Central Analysis Farm

    SciTech Connect (OSTI)

    Kim, T.H.; Neubauer, M.; Sfiligoi, I.; Weems, L.; Wurthwein, F.; /UC, San Diego

    2004-01-01

    With Run II of the Fermilab Tevatron well underway, many computing challenges inherent to analyzing large volumes of data produced in particle physics research need to be met. We present the computing model within CDF designed to address the physics needs of the collaboration. Particular emphasis is placed on current development of a large O(1000) processor PC cluster at Fermilab serving as the Central Analysis Farm for CDF. Future plans leading toward distributed computing and GRID within CDF are also discussed.

  8. Conversion of actinide and RE oxides into nitrates and their recovery into fluids

    SciTech Connect (OSTI)

    Bondin, V.V.; Bychkov, S.I.; Efremov, I.G.; Revenko, Y.A.; Babain, V.A.; Murzin, A.A.; Romanovsky, V.N; Fedorov, Y.S.; Shadrin, A.Y.; Ryabkova, N.V.; Li, E.N.

    2007-07-01

    The conditions for uranium oxides completely convert into uranyl nitrate hexahydrate in nitrogen tetra-oxide media (75 deg. C, 0,5-3,0 MPa, [UO{sub x}]:[H{sub 2}O]:[NO{sub 2}]=1:8:6) were found out. The conversion of Pu contained simulator of oxide spent nuclear fuel of thermal reactors was successfully demonstrated. The possibility of uranium recovery up to 95% from TR SNF without plutonium separation from FP is practically showed, what corresponds with Non-proliferation Treaty. (authors)

  9. Domestic Material Content in Molten-Salt Concentrating Solar Power Plants

    SciTech Connect (OSTI)

    Turchi, Craig; Kurup, Parthiv; Akar, Sertac; Flores, Francisco

    2015-08-26

    This study lists material composition data for two concentrating solar power (CSP) plant designs: a molten-salt power tower and a hypothetical parabolic trough plant, both of which employ a molten salt for the heat transfer fluid (HTF) and thermal storage media. The two designs have equivalent generating and thermal energy storage capacities. The material content of the saltHTF trough plant was approximately 25% lower than a comparably sized conventional oil-HTF parabolic trough plant. The significant reduction in oil, salt, metal, and insulation mass by switching to a salt-HTF design is expected to reduce the capital cost and LCOE for the parabolic trough system.

  10. Process for the preparation of protected dihydroxypropyl trialkylammonium salts and derivatives thereof

    DOE Patents [OSTI]

    Hollingsworth, Rawle I. (Haslett, MI); Wang, Guijun (East Lansing, MI)

    2000-01-01

    A process for the preparation of protected dihydroxypropyl trialkylammonium salts, particularly in chiral form is described. In particular, a process for the preparation of (2,2-dimethyl-1,3-dioxolan-4-ylmethyl)trialkylammonium salts, particularly in chiral form is described. Furthermore, a process is described wherein the (2,2-dimethyl-1,3-dioxolan-4ylmethyl)trialkylammonium salts is a 2,2-dimethyl-1,3-dioxolan-4-ylmethyl trimethylammonium salt, preferably in chiral form. The protected dihydroxypropyl trialkylammonium salts lead to L-carnitine (9) when in chiral form (5).

  11. Modeling Coupled THM Processes and Brine Migration in Salt at High Temperatures

    SciTech Connect (OSTI)

    Rutqvist, Jonny; Blanco-Martin, Laura; Molins, Sergi; Trebotich, David; Birkholzer, Jens

    2015-09-01

    In this report, we present FY2015 progress by Lawrence Berkeley National Laboratory (LBNL) related to modeling of coupled thermal-hydrological-mechanical-chemical (THMC) processes in salt and their effect on brine migration at high temperatures. This is a combined milestone report related to milestone Salt R&D Milestone Modeling Coupled THM Processes and Brine Migration in Salt at High Temperatures (M3FT-15LB0818012) and the Salt Field Testing Milestone (M3FT-15LB0819022) to support the overall objectives of the salt field test planning.

  12. Photosensitive dissolution inhibitors and resists based on onium salt carboxylates

    DOE Patents [OSTI]

    Dentinger, Paul M.; Simison, Kelby L.

    2005-11-29

    A photoresist composition that employs onium salt carboxylates as thermally stable dissolution inhibitors. The photoresist composition can be either an onium carboxylate salt with a phenolic photoresist, such as novolac, or an onium cation protected carboxylate-containing resin such as an acrylic/acrylic acid copolymer. The onium carboxylate can be an onium cholate, wherein the onium cholate is an iodonium cholate. Particularly preferred iodonium cholates are alkyloxyphenylphenyl iodonium cholates and most particularly preferred is octyloxyphenyphenyl iodonium cholate. The photoresist composition will not create nitrogen or other gaseous byproducts upon exposure to radiation, does not require water for photoactivation, has acceptable UV radiation transmission characteristics, and is thermally stable at temperatures required for solvent removal.

  13. Structural Interactions within Lithium Salt Solvates: Acyclic Carbonates and Esters

    SciTech Connect (OSTI)

    Afroz, Taliman; Seo, D. M.; Han, Sang D.; Boyle, Paul D.; Henderson, Wesley A.

    2015-03-06

    Solvate crystal structures serve as useful models for the molecular-level interactions within the diverse solvates present in liquid electrolytes. Although acyclic carbonate solvents are widely used for Li-ion battery electrolytes, only three solvate crystal structures with lithium salts are known for these and related solvents. The present work, therefore, reports six lithium salt solvate structures with dimethyl and diethyl carbonate: (DMC)2:LiPF6, (DMC)1:LiCF3SO3, (DMC)1/4:LiBF4, (DEC)2:LiClO4, (DEC)1:LiClO4 and (DEC)1:LiCF3SO3 and four with the structurally related methyl and ethyl acetate: (MA)2:LiClO4, (MA)1:LiBF4, (EA)1:LiClO4 and (EA)1:LiBF4.

  14. Cooling molten salt reactors using gas-lift

    SciTech Connect (OSTI)

    Zitek, Pavel E-mail: klimko@kke.zcu.cz; Valenta, Vaclav E-mail: klimko@kke.zcu.cz; Klimko, Marek E-mail: klimko@kke.zcu.cz

    2014-08-06

    This study briefly describes the selection of a type of two-phase flow, suitable for intensifying the natural flow of nuclear reactors with liquid fuel - cooling mixture molten salts and the description of a Two-phase flow demonstrator (TFD) used for experimental study of the gas-lift system and its influence on the support of natural convection. The measuring device and the application of the TDF device is described. The work serves as a model system for gas-lift (replacing the classic pump in the primary circuit) for high temperature MSR planned for hydrogen production. An experimental facility was proposed on the basis of which is currently being built an experimental loop containing the generator, separator bubbles and necessary accessories. This loop will model the removal of gaseous fission products and tritium. The cleaning of the fuel mixture of fluoride salts eliminates problems from Xenon poisoning in classical reactors.

  15. Salt Producing Region Natural Gas Working Underground Storage (Billion

    Gasoline and Diesel Fuel Update (EIA)

    Cubic Feet) Salt Producing Region Natural Gas Working Underground Storage (Billion Cubic Feet) Salt Producing Region Natural Gas Working Underground Storage (Billion Cubic Feet) Year-Month Week 1 Week 2 Week 3 Week 4 Week 5 End Date Value End Date Value End Date Value End Date Value End Date Value 2006-Dec 12/29 101 2007-Jan 01/05 109 01/12 107 01/19 96 01/26 91 2007-Feb 02/02 78 02/09 63 02/16 52 02/23 54 2007-Mar 03/02 59 03/09 58 03/16 64 03/23 70 03/30 78 2007-Apr 04/06 81 04/13 80 04/20

  16. Nuclear Hybrid Energy Systems: Molten Salt Energy Storage

    SciTech Connect (OSTI)

    P. Sabharwall; M. Green; S.J. Yoon; S.M. Bragg-Sitton; C. Stoots

    2014-07-01

    With growing concerns in the production of reliable energy sources, the next generation in reliable power generation, hybrid energy systems, are being developed to stabilize these growing energy needs. The hybrid energy system incorporates multiple inputs and multiple outputs. The vitality and efficiency of these systems resides in the energy storage application. Energy storage is necessary for grid stabilizing and storing the overproduction of energy to meet peak demands of energy at the time of need. With high thermal energy production of the primary nuclear heat generation source, molten salt energy storage is an intriguing option because of its distinct properties. This paper will discuss the different energy storage options with the criteria for efficient energy storage set forth, and will primarily focus on different molten salt energy storage system options through a thermodynamic analysis

  17. Savannah River Site - Salt Waste Processing Facility Independent Technical Review

    Office of Environmental Management (EM)

    SALT WASTE PROCESSING FACILITY INDEPENDENT TECHNICAL REVIEW November 22, 2006 Conducted by: Harry Harmon, Team Lead Civil/Structural Sub Team Facility Safety Sub Team Engineering Sub Team Peter Lowry, Lead James Langsted, Lead George Krauter, Lead Robert Kennedy Chuck Negin Art Etchells Les Youd Jerry Evatt Oliver Block Loring Wyllie Richard Stark Tim Adams Tom Anderson Todd LaPointe Stephen Gosselin Carl Costantino Norman Moreau Patrick Corcoran John Christian Ken Cooper Kari McDaniel

  18. Fluorination utilizing thermodynamically unstable fluorides and fluoride salts thereof

    DOE Patents [OSTI]

    Bartlett, Neil (Orinda, CA); Whalen, J. Marc (Corning, NY); Chacon, Lisa (Corning, NY)

    2000-12-12

    A method for fluorinating a carbon compound or cationic carbon compound utilizes a fluorination agent selected from thermodynamically unstable nickel fluorides and salts thereof in liquid anhydrous hydrogen fluoride. The desired carbon compound or cationic organic compound to undergo fluorination is selected and reacted with the fluorination agent by contacting the selected organic or cationic organic compound and the chosen fluorination agent in a reaction vessel for a desired reaction time period at room temperature or less.

  19. Process Heat Exchanger Options for Fluoride Salt High Temperature Reactor

    SciTech Connect (OSTI)

    Piyush Sabharwall; Eung Soo Kim; Michael McKellar; Nolan Anderson

    2011-04-01

    The work reported herein is a significant intermediate step in reaching the final goal of commercial-scale deployment and usage of molten salt as the heat transport medium for process heat applications. The primary purpose of this study is to aid in the development and selection of the required heat exchanger for power production and process heat application, which would support large-scale deployment.

  20. Lithium Salt-doped, Gelled Polymer Electrolyte with a Nanoporous,

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Bicontinuous Cubic Architecture and High Room-temparature Ion Conductivity - Energy Innovation Portal Energy Storage Energy Storage Advanced Materials Advanced Materials Find More Like This Return to Search Lithium Salt-doped, Gelled Polymer Electrolyte with a Nanoporous, Bicontinuous Cubic Architecture and High Room-temparature Ion Conductivity University of Colorado Contact CU About This Technology Technology Marketing SummaryLi ion batteries have high energy density, high power delivery,

  1. Molten Salt Heat Transfer Fluid (HTF) - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Solar Thermal Solar Thermal Industrial Technologies Industrial Technologies Energy Storage Energy Storage Find More Like This Return to Search Molten Salt Heat Transfer Fluid (HTF) Sandia National Laboratories Contact SNL About This Technology Publications: PDF Document Publication Market Sheet (739 KB) Sandia&#39;s National Solar Thermal Test Facility Sandia's National Solar Thermal Test Facility Technology Marketing Summary Sandia has developed a heat transfer fluid (HTF) for use at

  2. Generic effluent monitoring system certification for salt well portable exhauster

    SciTech Connect (OSTI)

    Glissmeyer, J.A.; Maughan, A.D.

    1997-09-01

    Tests were conducted to verify that the Generic Effluent Monitoring System (GEMS), as it is applied to the Salt Well Portable Exhauster, meets all applicable regulatory performance criteria for air sampling systems at nuclear facilities. These performance criteria address both the suitability of the air sampling probe location and the transport of the sample to the collection devices. The criteria covering air sampling probe location ensure that the contaminants in the stack are well mixed with the airflow at the probe location such that the extracted sample represents the whole. The sample transport criteria ensure that the sampled contaminants are quantitatively delivered to the collection device. The specific performance criteria are described in detail in the report. The tests demonstrated that the GEMS/Salt Well Exhauster system meets all applicable performance criteria. Pacific Northwest National Laboratory conducted the testing using a mockup of the Salt Well Portable Exhauster stack at the Numatec Hanford Company`s 305 Building. The stack/sampling system configuration tested was designed to provide airborne effluent control for the Salt Well pumping operation at some U.S. Department of Energy (DOE) radioactive waste storage tanks at the Hanford Site, Washington. The portable design of the exhauster allows it to be used in other applications and over a range of exhaust air flowrates (approximately 200 - 1100 cubic feet per minute). The unit includes a stack section containing the sampling probe and another stack section containing the airflow, temperature and humidity sensors. The GEMS design features a probe with a single shrouded sampling nozzle, a sample delivery line, and sample collection system. The collection system includes a filter holder to collect the sample of record and an in-line detector head and filter for monitoring beta radiation-emitting particles.

  3. Transpiring wall supercritical water oxidation reactor salt deposition studies

    SciTech Connect (OSTI)

    Haroldsen, B.L.; Mills, B.E.; Ariizumi, D.Y.; Brown, B.G.

    1996-09-01

    Sandia National Laboratories has teamed with Foster Wheeler Development Corp. and GenCorp, Aerojet to develop and evaluate a new supercritical water oxidation reactor design using a transpiring wall liner. In the design, pure water is injected through small pores in the liner wall to form a protective boundary layer that inhibits salt deposition and corrosion, effects that interfere with system performance. The concept was tested at Sandia on a laboratory-scale transpiring wall reactor that is a 1/4 scale model of a prototype plant being designed for the Army to destroy colored smoke and dye at Pine Bluff Arsenal in Arkansas. During the tests, a single-phase pressurized solution of sodium sulfate (Na{sub 2}SO{sub 4}) was heated to supercritical conditions, causing the salt to precipitate out as a fine solid. On-line diagnostics and post-test observation allowed us to characterize reactor performance at different flow and temperature conditions. Tests with and without the protective boundary layer demonstrated that wall transpiration provides significant protection against salt deposition. Confirmation tests were run with one of the dyes that will be processed in the Pine Bluff facility. The experimental techniques, results, and conclusions are discussed.

  4. Sensitivity of storage field performance to geologic and cavern design parameters in salt domes.

    SciTech Connect (OSTI)

    Ehgartner, Brian L.; Park, Byoung Yoon

    2009-03-01

    A sensitivity study was performed utilizing a three dimensional finite element model to assess allowable cavern field sizes for strategic petroleum reserve salt domes. A potential exists for tensile fracturing and dilatancy damage to salt that can compromise the integrity of a cavern field in situations where high extraction ratios exist. The effects of salt creep rate, depth of salt dome top, dome size, caprock thickness, elastic moduli of caprock and surrounding rock, lateral stress ratio of surrounding rock, cavern size, depth of cavern, and number of caverns are examined numerically. As a result, a correlation table between the parameters and the impact on the performance of storage field was established. In general, slower salt creep rates, deeper depth of salt dome top, larger elastic moduli of caprock and surrounding rock, and a smaller radius of cavern are better for structural performance of the salt dome.

  5. PowerPoint Presentation

    Office of Environmental Management (EM)

    1950 1300 TRU Waste Progress * Surveillance & storage of remediated nitrate salt drums performed safely and compliantly * Preparations for the remediation of nitrate salts...

  6. Speciation model selection by Monte Carlo analysis of optical absorption spectra: Plutonium(IV) nitrate complexes

    SciTech Connect (OSTI)

    Berg, John M.; Veirs, D. Kirk; Vaughn, Randolph B.; Cisneros, Michael R.; Smith, Coleman A.

    2000-06-01

    Standard modeling approaches can produce the most likely values of the formation constants of metal-ligand complexes if a particular set of species containing the metal ion is known or assumed to exist in solution equilibrium with complexing ligands. Identifying the most likely set of species when more than one set is plausible is a more difficult problem to address quantitatively. A Monte Carlo method of data analysis is described that measures the relative abilities of different speciation models to fit optical spectra of open-shell actinide ions. The best model(s) can be identified from among a larger group of models initially judged to be plausible. The method is demonstrated by analyzing the absorption spectra of aqueous Pu(IV) titrated with nitrate ion at constant 2 molal ionic strength in aqueous perchloric acid. The best speciation model supported by the data is shown to include three Pu(IV) species with nitrate coordination numbers 0, 1, and 2. Formation constants are {beta}{sub 1}=3.2{+-}0.5 and {beta}{sub 2}=11.2{+-}1.2, where the uncertainties are 95% confidence limits estimated by propagating raw data uncertainties using Monte Carlo methods. Principal component analysis independently indicates three Pu(IV) complexes in equilibrium. (c) 2000 Society for Applied Spectroscopy.

  7. Diffusion Welding of Alloys for Molten Salt Service - Status Report

    SciTech Connect (OSTI)

    Denis Clark; Ronald Mizia; Piyush Sabharwall

    2012-09-01

    The present work is concerned with heat exchanger development for molten salt service, including the proposed molten salt reactor (MSR), a homogeneous reactor in which the fuel is dissolved in a circulating fluid of molten salt. It is an outgrowth of recent work done under the Next Generation Nuclear Plant (NGNP) program; what the two reactor systems have in common is an inherently safe nuclear plant with a high outlet temperature that is useful for process heat as well as more conventional generation The NGNP program was tasked with investigating the application of a new generation of nuclear power plants to a variety of energy needs. One baseline reactor design for this program is a high temperature, gas-cooled reactor (HTGR), which provides many options for energy use. These might include the conventional Rankine cycle (steam turbine) generation of electricity, but also other methods: for example, Brayton cycle (gas turbine) electrical generation, and the direct use of the high temperatures characteristic of HTGR output for process heat in the chemical industry. Such process heat is currently generated by burning fossil fuels, and is a major contributor to the carbon footprint of the chemical and petrochemical industries. The HTGR, based on graphite fuel elements, can produce very high output temperatures; ideally, temperatures of 900 C or even greater, which has significant energy advantages. Such temperatures are, of course, at the frontiers of materials limitations, at the upper end of the performance envelope of the metallic materials for which robust construction codes exist, and within the realm of ceramic materials, the fabrication and joining of which, on the scale of large energy systems, are at an earlier stage of development. A considerable amount of work was done in the diffusion welding of materials of interest for HTGR service with alloys such as 617 and 800H. The MSR output temperature is also materials limited, and is projected at about 700 C. (RR E) A different set of alloys, such as Alloy N and 242, are needed to handle molten salts at this temperature. The diffusion welding development work described here builds on techniques developed during the NGNP work, as applied to these alloys. There is also the matter of dissimilar metal welding, since alloys suitable for salt service are generally not suited for service in gaseous oxidizing environments, and vice versa, and welding is required for the Class I boundaries in these systems, as identified in the relevant ASME codes.

  8. Diffusion Welding of Alloys for Molten Salt Service - Status Report

    SciTech Connect (OSTI)

    Denis Clark; Ronald Mizia

    2012-05-01

    The present work is concerned with heat exchanger development for molten salt service, including the proposed molten salt reactor (MSR), a homogeneous reactor in which the fuel is dissolved in a circulating fluid of molten salt. It is an outgrowth of recent work done under the Next Generation Nuclear Plant (NGNP) program; what the two reactor systems have in common is an inherently safe nuclear plant with a high outlet temperature that is useful for process heat as well as more conventional generation The NGNP program was tasked with investigating the application of a new generation of nuclear power plants to a variety of energy needs. One baseline reactor design for this program is a high temperature, gas-cooled reactor (HTGR), which provides many options for energy use. These might include the conventional Rankine cycle (steam turbine) generation of electricity, but also other methods: for example, Brayton cycle (gas turbine) electrical generation, and the direct use of the high temperatures characteristic of HTGR output for process heat in the chemical industry. Such process heat is currently generated by burning fossil fuels, and is a major contributor to the carbon footprint of the chemical and petrochemical industries. The HTGR, based on graphite fuel elements, can produce very high output temperatures; ideally, temperatures of 900 C or even greater, which has significant energy advantages. Such temperatures are, of course, at the frontiers of materials limitations, at the upper end of the performance envelope of the metallic materials for which robust construction codes exist, and within the realm of ceramic materials, the fabrication and joining of which, on the scale of large energy systems, are at an earlier stage of development. A considerable amount of work was done in the diffusion welding of materials of interest for HTGR service with alloys such as 617 and 800H. The MSR output temperature is also materials limited, and is projected at about 700 C. (RR E) A different set of alloys, such as Alloy N and 242, are needed to handle molten salts at this temperature. The diffusion welding development work described here builds on techniques developed during the NGNP work, as applied to these alloys. There is also the matter of dissimilar metal welding, since alloys suitable for salt service are generally not suited for service in gaseous oxidizing environments, and vice versa, and welding is required for the Class I boundaries in these systems, as identified in the relevant ASME codes.

  9. Central Moloney: Order (2013-SE-4702)

    Broader source: Energy.gov [DOE]

    DOE ordered Central Moloney, Inc. to pay a $2,500 civil penalty after finding Central Moloney had manufactured and distributed noncompliant liquid-immersed distribution transformers in commerce in the U.S.

  10. West Central Soy | Open Energy Information

    Open Energy Info (EERE)

    Soy Jump to: navigation, search Name: West Central Soy Place: Iowa Product: Biodiesel producer based in Iowa, Owned bu a soy farmer coop References: West Central Soy1 This...

  11. SSL Demonstration: Central Park, New York City

    SciTech Connect (OSTI)

    2012-11-01

    GATEWAY program report brief summarizing an SSL pathway lighting demonstration in Central Park in New York City.

  12. Distributed trace using central performance counter memory

    DOE Patents [OSTI]

    Satterfield, David L.; Sexton, James C.

    2013-01-22

    A plurality of processing cores, are central storage unit having at least memory connected in a daisy chain manner, forming a daisy chain ring layout on an integrated chip. At least one of the plurality of processing cores places trace data on the daisy chain connection for transmitting the trace data to the central storage unit, and the central storage unit detects the trace data and stores the trace data in the memory co-located in with the central storage unit.

  13. Distributed trace using central performance counter memory

    DOE Patents [OSTI]

    Satterfield, David L; Sexton, James C

    2013-10-22

    A plurality of processing cores, are central storage unit having at least memory connected in a daisy chain manner, forming a daisy chain ring layout on an integrated chip. At least one of the plurality of processing cores places trace data on the daisy chain connection for transmitting the trace data to the central storage unit, and the central storage unit detects the trace data and stores the trace data in the memory co-located in with the central storage unit.

  14. J-1 APPENDIX J Central Plateau Facilities

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    J-1 APPENDIX J Central Plateau Facilities Purpose and Description Appendix J, Central Plateau Facilities, is focused on Central Plateau facilities that are anticipated to require a Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) response action for cleanup. The following information will be contained in Appendix J: Central Plateau facilities determined by the Tri-Parties, in accordance with the Graded Approach process described in Section 8 of the Action Plan, to

  15. Building America Webinar: Retrofitting Central Space Conditioning...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Building America Webinar: Retrofitting Central Space Conditioning Strategies for ... Building America Webinar: High Performance Enclosure Strategies: Part II, New Construction ...

  16. Building America Webinar: Retrofitting Central Space Conditioning...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Control strategies to improve hydronic space heating performance Building America Webinar: Retrofitting Central Space Conditioning Strategies for Multifamily Buildings - Control ...

  17. RingCentral Mailboxes | Department of Energy

    Energy Savers [EERE]

    Mailboxes RingCentral Mailboxes This is a list of each Departmental element's mailbox(es) used for RingCentral during a COOP event. Office spreadsheet icon RingCentral Mailboxes Responsible Contacts Bruce Murray HR Policy Advisor E-mail bruce.murray@hq.doe.gov Phone 202-586-3372 More Documents & Publications RingCentral User Guide Audit Report: IG-0845 Audit Report: OAS-L-15-01

  18. Building America Webinar: Retrofitting Central Space Conditioning

    Energy Savers [EERE]

    Strategies for Multifamily Buildings | Department of Energy Retrofitting Central Space Conditioning Strategies for Multifamily Buildings Building America Webinar: Retrofitting Central Space Conditioning Strategies for Multifamily Buildings The webinar on July 16, 2014, focused on improving the performance of central space conditioning systems in multifamily buildings. Presenters discussed hydronic heating strategies and the evaluation of thermostatically controlled radiator valves (TRVs).

  19. A study of the organic emission from a turbocharged diesel engine running on 12 percent hexyl nitrate dissolved in ethanol

    SciTech Connect (OSTI)

    Walde, N.; Westerholm, R.; Persson, K.-A.

    1984-01-01

    A highly rated turbocharged diesel engine adapted for an alternative fuel based on ethanol and hexyl nitrate has been investigated with respect to the emission of organic compounds in the exhausts. The adaption involves: ignition nozzles with larger holes, a change of injection timing and more fuel injected per stroke. Emissions were measured at four different driving modes ie, 1, 8, 10 and 12 respectively, in the California Cycle. The exhaust composition are different compared to conventional diesel emissions. The main part of the organic pollutants consists of unburned ethanol and hexyl nitrate, acetaldehyde being the most abundant aldehyde.

  20. Central Equatorial Pacific Experiment (CEPEX)

    SciTech Connect (OSTI)

    Not Available

    1993-01-01

    The Earth's climate has varied significantly in the past, yet climate records reveal that in the tropics, sea surface temperatures seem to have been remarkably stable, varying by less than a few degrees Celsius over geologic time. Today, the large warm pool of the western Pacific shows similar characteristics. Its surface temperature always exceeds 27[degree]C, but never 31[degree]C. Heightened interest in this observation has been stimulated by questions of global climate change and the exploration of stabilizing climate feedback processes. Efforts to understand the observed weak sensitivity of tropical sea surface temperatures to climate forcing has led to a number of competing ideas about the nature of this apparent thermostat. Although there remains disagreement on the processes that regulate tropical sea surface temperature, most agree that further progress in resolving these differences requires comprehensive field observations of three-dimensional water vapor concentrations, solar and infrared radiative fluxes, surface fluxes of heat and water vapor, and cloud microphysical properties. This document describes the Central Equatorial Pacific Experiment (CEPEX) plan to collect such observations over the central equatorial Pacific Ocean during March of 1993.

  1. Novel Molten Salts Thermal Energy Storage for Concentrating Solar Power Generation

    SciTech Connect (OSTI)

    Reddy, Ramana G.

    2013-10-23

    The explicit UA program objective is to develop low melting point (LMP) molten salt thermal energy storage media with high thermal energy storage density for sensible heat storage systems. The novel Low Melting Point (LMP) molten salts are targeted to have the following characteristics: 1. Lower melting point (MP) compared to current salts (<222C) 2. Higher energy density compared to current salts (>300 MJ/m3) 3. Lower power generation cost compared to current salt In terms of lower power costs, the program target the DOE's Solar Energy Technologies Program year 2020 goal to create systems that have the potential to reduce the cost of Thermal Energy Storage (TES) to less than $15/kWh-th and achieve round trip efficiencies greater than 93%. The project has completed the experimental investigations to determine the thermo-physical, long term thermal stability properties of the LMP molten salts and also corrosion studies of stainless steel in the candidate LMP molten salts. Heat transfer and fluid dynamics modeling have been conducted to identify heat transfer geometry and relative costs for TES systems that would utilize the primary LMP molten salt candidates. The project also proposes heat transfer geometry with relevant modifications to suit the usage of our molten salts as thermal energy storage and heat transfer fluids. The essential properties of the down-selected novel LMP molten salts to be considered for thermal storage in solar energy applications were experimentally determined, including melting point, heat capacity, thermal stability, density, viscosity, thermal conductivity, vapor pressure, and corrosion resistance of SS 316. The thermodynamic modeling was conducted to determine potential high temperature stable molten salt mixtures that have thermal stability up to 1000 C. The thermo-physical properties of select potential high temperature stable (HMP) molten salt mixtures were also experimentally determined. All the salt mixtures align with the go/no-go goals stipulated by the DOE for this project. Energy densities of all salt mixtures were higher than that of the current solar salt. The salt mixtures costs have been estimated and TES system costs for a 2 tank, direct approach have been estimated for each of these materials. All estimated costs are significantly below the baseline system that used solar salt. These lower melt point salts offer significantly higher energy density per volume than solar salt and therefore attractively smaller inventory and equipment costs. Moreover, a new TES system geometry has been recommended A variety of approaches were evaluated to use the low melting point molten salt. Two novel changes are recommended that 1) use the salt as a HTF through the solar trough field, and 2) use the salt to not only create steam but also to preheat the condensed feedwater for Rankine cycle. The two changes enable the powerblock to operate at 500C, rather than the current 400C obtainable using oil as the HTF. Secondly, the use of salt to preheat the feedwater eliminates the need to extract steam from the low pressure turbine for that purpose. Together, these changes result in a dramatic 63% reduction required for 6 hour salt inventory, a 72% reduction in storage volume, and a 24% reduction in steam flow rate in the power block. Round trip efficiency for the Case 5 - 2 tank direct system is estimated at >97%, with only small losses from time under storage and heat exchange, and meeting RFP goals. This attractive efficiency is available because the major heat loss experienced in a 2 tank indirect system - losses by transferring the thermal energy from oil HTF to the salt storage material and back to oil to run the steam generator at night - is not present for the 2 tank direct system. The higher heat capacity values for both LMP and HMP systems enable larger storage capacities for concentrating solar power.

  2. Central Solenoid Insert Technical Specification

    SciTech Connect (OSTI)

    Martovetsky, Nicolai N; Smirnov, Alexandre

    2011-09-01

    The US ITER Project Office (USIPO) is responsible for the ITER central solenoid (CS) contribution to the ITER project. The Central Solenoid Insert (CSI) project will allow ITER validation the appropriate lengths of the conductors to be used in the full-scale CS coils under relevant conditions. The ITER Program plans to build and test a CSI to verify the performance of the CS conductor. The CSI is a one-layer solenoid with an inner diameter of 1.48 m and a height of 4.45 m between electric terminal ends. The coil weight with the terminals is approximately 820 kg without insulation. The major goal of the CSI is to measure the temperature margin of the CS under the ITER direct current (DC) operating conditions, including determining sensitivity to load cycles. Performance of the joints, ramp rate sensitivity, and stability against thermal or electromagnetic disturbances, electrical insulation, losses, and instrumentation are addressed separately and therefore are not major goals in this project. However, losses and joint performance will be tested during the CSI testing campaign. The USIPO will build the CSI that will be tested at the Central Solenoid Model Coil (CSMC) Test Facility at the Japan Atomic Energy Agency (JAEA), Naka, Japan. The industrial vendors (the Suppliers) will report to the USIPO (the Company). All approvals to proceed will be issued by the Company, which in some cases, as specified in this document, will also require the approval of the ITER Organization. Responsibilities and obligations will be covered by respective contracts between the USIPO, called Company interchangeably, and the industrial Prime Contractors, called Suppliers. Different stages of work may be performed by more than one Prime Contractor, as described in this specification. Technical requirements of the contract between the Company and the Prime Contractor will be covered by the Fabrication Specifications developed by the Prime Contractor based on this document and approved by the Company and ITER. The Fabrication Specifications may reflect some national requirements and regulations that are not fully provided here. This document presents the ITER CSI specifications.

  3. Blending Of Radioactive Salt Solutions In Million Gallon Tanks

    SciTech Connect (OSTI)

    Leishear, Robert A.; Lee, Si Y.; Fowley, Mark D.; Poirier, Michael R.

    2012-12-10

    Research was completed at Savannah River National Laboratory (SRNL) to investigate processes related to the blending of radioactive, liquid waste, salt solutions in 4920 cubic meter, 25.9 meter diameter storage tanks. One process was the blending of large salt solution batches (up to 1135 ? 3028 cubic meters), using submerged centrifugal pumps. A second process was the disturbance of a settled layer of solids, or sludge, on the tank bottom. And a third investigated process was the settling rate of sludge solids if suspended into slurries by the blending pump. To investigate these processes, experiments, CFD models (computational fluid dynamics), and theory were applied. Experiments were performed using simulated, non-radioactive, salt solutions referred to as supernates, and a layer of settled solids referred to as sludge. Blending experiments were performed in a 2.44 meter diameter pilot scale tank, and flow rate measurements and settling tests were performed at both pilot scale and full scale. A summary of the research is presented here to demonstrate the adage that, ?One good experiment fixes a lot of good theory?. Experimental testing was required to benchmark CFD models, or the models would have been incorrectly used. In fact, CFD safety factors were established by this research to predict full-scale blending performance. CFD models were used to determine pump design requirements, predict blending times, and cut costs several million dollars by reducing the number of required blending pumps. This research contributed to DOE missions to permanently close the remaining 47 of 51 SRS waste storage tanks.

  4. Blending of Radioactive Salt Solutions in Million Gallon Tanks - 13002

    SciTech Connect (OSTI)

    Leishear, Robert A.; Lee, Si Y.; Fowley, Mark D.; Poirier, Michael R. [Savannah River National Laboratory, Aiken. S.C., 29808 (United States)] [Savannah River National Laboratory, Aiken. S.C., 29808 (United States)

    2013-07-01

    Research was completed at Savannah River National Laboratory (SRNL) to investigate processes related to the blending of radioactive, liquid waste, salt solutions in 4920 cubic meter, 25.9 meter diameter storage tanks. One process was the blending of large salt solution batches (up to 1135 - 3028 cubic meters), using submerged centrifugal pumps. A second process was the disturbance of a settled layer of solids, or sludge, on the tank bottom. And a third investigated process was the settling rate of sludge solids if suspended into slurries by the blending pump. To investigate these processes, experiments, CFD models (computational fluid dynamics), and theory were applied. Experiments were performed using simulated, non-radioactive, salt solutions referred to as supernates, and a layer of settled solids referred to as sludge. Blending experiments were performed in a 2.44 meter diameter pilot scale tank, and flow rate measurements and settling tests were performed at both pilot scale and full scale. A summary of the research is presented here to demonstrate the adage that, 'One good experiment fixes a lot of good theory'. Experimental testing was required to benchmark CFD models, or the models would have been incorrectly used. In fact, CFD safety factors were established by this research to predict full-scale blending performance. CFD models were used to determine pump design requirements, predict blending times, and cut costs several million dollars by reducing the number of required blending pumps. This research contributed to DOE missions to permanently close the remaining 47 of 51 SRS waste storage tanks. (authors)

  5. Transportation of pyrochemical salts from Rocky Flats to Los Alamos

    SciTech Connect (OSTI)

    Schreiber, S.B.

    1997-02-01

    Radioactive legacy wastes or residues are currently being stored on numerous Sites around the former Department of Energy`s (DOE) Nuclear Weapons Complex. Since most of the operating facilities were shut down and have not operated since before the declared end to the Cold War in 1993, the historical method for treating these residues no longer exists. The risk associated with continued storage of these residues will dramatically increase with time. Thus, the DOE was directed by the Defense Nuclear Facility Safety Board in its Recommendation 94-1 to address and stabilize these residues and established an eight year time frame for doing so. There are only two options available to respond to this requirement: (1) restart existing facilities to treat and package the residues for disposal or (2) transport the residues to another operating facility within the Complex where they can be treated and packaged for disposal. This paper focuses on one such residue type, pyrochemical salts, produced at one Complex site, the Rocky Flats Plant located northwest of Denver, Colorado. One option for treating the salts is their shipment to Los Alamos, New Mexico, for handling at the Plutonium Facility. The safe transportation of these salts can be accomplished at present with several shipping containers including a DOT 6M, a DOE 9968, Type A or Type B quantity 55-gallon drum overpacks, or even the TRUPACT II. The tradeoffs between each container is examined with the conclusion that none of the available shipping containers is fully satisfactory. Thus, the advantageous aspects of each container must be utilized in an integrated and efficient way to effectively manage the risk involved. 1 fig.

  6. Identifying suitable "piercement" salt domes for nuclear waste storage sites

    SciTech Connect (OSTI)

    Kehle, R.

    1980-08-01

    Piercement salt domes of the northern interior salt basins of the Gulf of Mexico are being considered as permanent storage sites for both nuclear and chemically toxic wastes. The suitable domes are stable and inactive, having reached their final evolutionary configuration at least 30 million years ago. They are buried to depths far below the level to which erosion will penetrate during the prescribed storage period and are not subject to possible future reactivation. The salt cores of these domes are themselves impermeable, permitting neither the entry nor exit of ground water or other unwanted materials. In part, a stable dome may be recognized by its present geometric configuration, but conclusive proof depends on establishing its evolutionary state. The evolutionary state of a dome is obtained by reconstructing the growth history of the dome as revealed by the configuration of sedimentary strata in a large area (commonly 3,000 square miles or more) surrounding the dome. A high quality, multifold CDP reflection seismic profile across a candidate dome will provide much of the necessary information when integrated with available subsurface control. Additional seismic profiles may be required to confirm an apparent configuration of the surrounding strata and an interpreted evolutionary history. High frequency seismic data collected in the near vicinity of a dome are also needed as a supplement to the CDP data to permit accurate depiction of the configuration of shallow strata. Such data must be tied to shallow drill hole control to confirm the geologic age at which dome growth ceased. If it is determined that a dome reached a terminal configuration many millions of years ago, such a dome is incapable of reactivation and thus constitutes a stable storage site for nuclear wastes.

  7. Central focus solar energy system

    SciTech Connect (OSTI)

    Findell, M.

    1982-02-23

    A central focus solar energy system consists of one or more arrays of mirrors, a receiver for each array, a sun tracker, a sun tracker sun acquisition device and a control unit. Mirrors of the arrays are subjected to two-axis control by electromechanical devices actuated by sun-tracking error signals generated by the sun tracker. Mirrors are thus oriented so as to cause reflections of the direct rays of the sun from all mirrors in an array to converge on a receiver at a common focus. Fixed (Principal) axes of mirror rotation are parallel to the fixed (Principal) axis of rotation of the sun tracker sensor making orientation of the system independent of the earth's spin axis. The system includes a ''vernier'' or fine adjustment control for positioning mirrors that supplements sun tracker controls.

  8. Central solar-energy receiver

    DOE Patents [OSTI]

    Not Available

    1981-10-27

    An improved tower-mounted central solar energy receiver for heating air drawn through the receiver by an induced draft fan is described. A number of vertically oriented, energy absorbing, fin-shaped slats are radially arranged in a number of concentric cylindrical arrays on top of the tower coaxially surrounding a pipe having air holes through which the fan draws air which is heated by the slats which receive the solar radiation from a heliostat field. A number of vertically oriented and wedge-shaped columns are radially arranged in a number of concentric cylindrical clusters surrounding the slat arrays. The columns have two mirror-reflecting sides to reflect radiation into the slat arrays and one energy absorbing side to reduce reradiation and reflection from the slat arrays.

  9. Melting of Uranium Metal Powders with Residual Salts

    SciTech Connect (OSTI)

    Jin-Mok Hur; Dae-Seung Kang; Chung-Seok Seo

    2007-07-01

    The Advanced Spent Fuel Conditioning Process (ACP) of the Korea Atomic Energy Research Institute focuses on the conditioning of Pressurized Water Reactor spent oxide nuclear fuel. After the oxide reduction step of the ACP, the resultant metal powders containing {approx} 30 wt% residual LiCl-Li{sub 2}O should be melted for a consolidation of the fine metal powders. In this study, we investigated the melting behaviors of uranium metal powders considering the effects of a LiCl-Li{sub 2}O residual salt. (authors)

  10. Tanzania wildcats to evaluate Jurassic Mandawa salt basin

    SciTech Connect (OSTI)

    Nagati, M.

    1996-10-07

    After 5 years of stagnant exploration in East Africa, Canadian independent Tanganyika Oil Co. of Vancouver, B.C., will drill two wildcats in Tanzania to evaluate the hydrocarbon potential of the coastal Jurassic Mandawa salt basin. Mita-1, spudded around Oct. 1, will be drilled to about 7,000 ft, East Lika-1 will be drilled in early December 1996 to approximately 6,000 ft. The two wells will test different structures and play concepts. The paper describes the exploration history, source rock potential, hydrocarbon shows, potential reservoir, and the prospects.

  11. Method of preparing sodalite from chloride salt occluded zeolite

    DOE Patents [OSTI]

    Lewis, Michele A. (Naperville, IL); Pereira, Candido (Lisle, IL)

    1997-01-01

    A method for immobilizing waste chloride salts containing radionuclides and hazardous nuclear material for permanent disposal starting with a substantially dry zeolite and sufficient glass to form leach resistant sodalite with occluded radionuclides and hazardous nuclear material. The zeolite and glass are heated to a temperature up to about 1000.degree. K. to convert the zeolite to sodalite and thereafter maintained at a pressure and temperature sufficient to form a sodalite product near theoretical density. Pressure is used on the formed sodalite to produce the required density.

  12. Method for removing semiconductor layers from salt substrates

    DOE Patents [OSTI]

    Shuskus, Alexander J. (West Hartford, CT); Cowher, Melvyn E. (East Brookfield, MA)

    1985-08-27

    A method is described for removing a CVD semiconductor layer from an alkali halide salt substrate following the deposition of the semiconductor layer. The semiconductor-substrate combination is supported on a material such as tungsten which is readily wet by the molten alkali halide. The temperature of the semiconductor-substrate combination is raised to a temperature greater than the melting temperature of the substrate but less than the temperature of the semiconductor and the substrate is melted and removed from the semiconductor by capillary action of the wettable support.

  13. Dilute acid/metal salt hydrolysis of lignocellulosics

    DOE Patents [OSTI]

    Nguyen, Quang A. (Golden, CO); Tucker, Melvin P. (Lakewood, CO)

    2002-01-01

    A modified dilute acid method of hydrolyzing the cellulose and hemicellulose in lignocellulosic material under conditions to obtain higher overall fermentable sugar yields than is obtainable using dilute acid alone, comprising: impregnating a lignocellulosic feedstock with a mixture of an amount of aqueous solution of a dilute acid catalyst and a metal salt catalyst sufficient to provide higher overall fermentable sugar yields than is obtainable when hydrolyzing with dilute acid alone; loading the impregnated lignocellulosic feedstock into a reactor and heating for a sufficient period of time to hydrolyze substantially all of the hemicellulose and greater than 45% of the cellulose to water soluble sugars; and recovering the water soluble sugars.

  14. Method of preparing sodalite from chloride salt occluded zeolite

    DOE Patents [OSTI]

    Lewis, M.A.; Pereira, C.

    1997-03-18

    A method is described for immobilizing waste chloride salts containing radionuclides and hazardous nuclear material for permanent disposal starting with a substantially dry zeolite and sufficient glass to form leach resistant sodalite with occluded radionuclides and hazardous nuclear material. The zeolite and glass are heated to a temperature up to about 1000 K to convert the zeolite to sodalite and thereafter maintained at a pressure and temperature sufficient to form a sodalite product near theoretical density. Pressure is used on the formed sodalite to produce the required density.

  15. SODIUM ALUMINOSILICATE FOULING AND CLEANING OF DECONTAMINATED SALT SOLUTION COALESCERS

    SciTech Connect (OSTI)

    Poirier, M; Thomas Peters, T; Fernando Fondeur, F; Samuel Fink, S

    2008-10-28

    During initial non-radioactive operations at the Modular Caustic Side Solvent Extraction Unit (MCU), the pressure drop across the decontaminated salt solution coalescer reached {approx}10 psi while processing {approx}1250 gallons of salt solution, indicating possible fouling or plugging of the coalescer. An analysis of the feed solution and the 'plugged coalescer' concluded that the plugging was due to sodium aluminosilicate solids. MCU personnel requested Savannah River National Laboratory (SRNL) to investigate the formation of the sodium aluminosilicate solids (NAS) and the impact of the solids on the decontaminated salt solution coalescer. Researchers performed developmental testing of the cleaning protocols with a bench-scale coalescer container 1-inch long segments of a new coalescer element fouled using simulant solution. In addition, the authors obtained a 'plugged' Decontaminated Salt Solution coalescer from non-radioactive testing in the MCU and cleaned it according to the proposed cleaning procedure. Conclusions from this testing include the following: (1) Testing with the bench-scale coalescer showed an increase in pressure drop from solid particles, but the increase was not as large as observed at MCU. (2) Cleaning the bench-scale coalescer with nitric acid reduced the pressure drop and removed a large amount of solid particles (11 g of bayerite if all aluminum is present in that form or 23 g of sodium aluminosilicate if all silicon is present in that form). (3) Based on analysis of the cleaning solutions from bench-scale test, the 'dirt capacity' of a 40 inch coalescer for the NAS solids tested is calculated as 450-950 grams. (4) Cleaning the full-scale coalescer with nitric acid reduced the pressure drop and removed a large amount of solid particles (60 g of aluminum and 5 g of silicon). (5) Piping holdup in the full-scale coalescer system caused the pH to differ from the target value. Comparable hold-up in the facility could lead to less effective cleaning and precipitation of bayerite solid particles. (6) Based on analysis of the cleaning solutions from the full-scale test, the 'dirt capacity' of a 40 inch coalescer for these NAS solids was calculated to be 40-170 grams.

  16. Structural Aspects of Hydrogen Bonding with Nitrate and Sulfate: Design Criteria for Polyalcohol Hosts

    SciTech Connect (OSTI)

    Hay, Benjamin P.; Dixon, David A.; Lumetta, Gregg J.; Vargas, Rubicelia; Garza, Jorge

    2004-01-01

    Organic hosts for oxyanion complexation can be constructed by combining two or more hydrogen bonding sites. The deliberate design of architectures for such hosts requires knowledge of the optimal geometry for the hydrogen bonds formed between the host and the guest. Important structural parameters include the O--H distance, the O--H-D angle, the X-O--H angle, and the X-O--H-D dihedral angle (H-D=hydrogen bond donor, X=any atom). This information can be obtained through the analysis of hydrogen bonding observed in crystal structures and electronic structure calculations on simple gas-phase complexes. In this chapter, we present an analysis of hydrogen bonding structural parameters for alcohol hydrogen donors and the oxygen atom acceptors in nitrate and sulfate.

  17. Thermal behavior of glassy phase stabilized ammonium nitrate (PSAN) thin films

    SciTech Connect (OSTI)

    Yeager, J. D.; Chellappa, R.; Singh, S.; Majewski, J.

    2015-06-01

    Ammonium nitrate (AN) is a high interest material because of its wide usage in propellants and explosives but can be difficult to handle from a formulation standpoint. It is soluble in many common solvents and has complex phase behavior. Here, we formulate phase stabilized AN (PSAN) films in a polymer matrix and characterize thermal and phase behavior using neutron reflectometry and ellipsometry. Our PSAN films are generally stable up to 160 C, though we observe small material loss between 60 and 100 C, which we attribute to solvent interactions with the PSAN. Crystallization of AN from supersaturated polymer is most common at thicker regions of the film, suggesting a critical nucleation thickness for the AN which can be avoided by making very thin films.

  18. Thermal behavior of glassy phase stabilized ammonium nitrate (PSAN) thin films

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yeager, J. D.; Chellappa, R.; Singh, S.; Majewski, J.

    2015-06-01

    Ammonium nitrate (AN) is a high interest material because of its wide usage in propellants and explosives but can be difficult to handle from a formulation standpoint. It is soluble in many common solvents and has complex phase behavior. Here, we formulate phase stabilized AN (PSAN) films in a polymer matrix and characterize thermal and phase behavior using neutron reflectometry and ellipsometry. Our PSAN films are generally stable up to 160 °C, though we observe small material loss between 60 and 100 °C, which we attribute to solvent interactions with the PSAN. Crystallization of AN from supersaturated polymer is mostmore » common at thicker regions of the film, suggesting a critical nucleation thickness for the AN which can be avoided by making very thin films.« less

  19. Characterization of bedded salt for storage caverns -- A case study from the Midland Basin, Texas

    SciTech Connect (OSTI)

    Hovorka, Susan D.; Nava, Robin

    2000-06-13

    The geometry of Permian bedding salt in the Midland Basin is a product of interaction between depositional facies and postdepositional modification by salt dissolution. Mapping high-frequency cycle patterns in cross section and map view using wireline logs documents the salt geometry. Geologically based interpretation of depositional and dissolution processes provides a powerful tool for mapping and geometry of salt to assess the suitability of sites for development of solution-mined storage caverns. In addition, this process-based description of salt geometry complements existing data about the evolution of one of the best-known sedimentary basins in the world, and can serve as a genetic model to assist in interpreting other salts.

  20. THE SENSITIVITY OF CARBON STEELS' SUSCEPTIBILITY TO LOCALIZED CORROSION TO THE PH OF NITRATE BASED NUCLEAR WASTES

    SciTech Connect (OSTI)

    BOOMER KD

    2010-01-14

    The Hanford tank reservation contains approximately 50 million gallons of liquid legacy radioactive waste from cold war weapons production, which is stored in 177 underground storage tanks. The tanks will be in use until waste processing operations are completed. The wastes tend to be high pH (over 10) and nitrate based. Under these alkaline conditions carbon steels tend to be passive and undergo relatively slow uniform corrosion. However, the presence of nitrate and other aggressive species, can lead to pitting and stress corrosion cracking. This work is a continuation of previous work that investigated the propensity of steels to suffer pitting and stress corrosion cracking in various waste simulants. The focus of this work is an investigation of the sensitivity of the steels' pitting and stress corrosion cracking susceptibility tosimulant pH. Previous work demonstrated that wastes that are high in aggressive nitrate and low in inhibitory nitrite are susceptible to localized corrosion. However, the previous work involved wastes with pH 12 or higher. The current work involves wastes with lower pH of 10 or 11. It is expected that at these lower pHs that a higher nitrite-to-nitrate ratio will be necessary to ensure tank integrity. This experimental work involved both electrochemical testing, and slow strain rate testing at either the free corrosion potential or under anodic polarization. The results of the current work will be discussed, and compared to work previously presented.

  1. Draft Genome Sequence for Microbacterium laevaniformans Strain OR221, a Bacterium Tolerant to Metals, Nitrate, and Low pH

    SciTech Connect (OSTI)

    Brown, Steven D; Palumbo, Anthony Vito; Panikov, Nikolai; Ariyawansa, Thilini; Klingeman, Dawn Marie; Johnson, Courtney M; Land, Miriam L; Utturkar, Sagar M; Epstein, Slava

    2012-01-01

    Microbacterium laevaniformans strain OR221 was isolated from subsurface sediments obtained from the Field Research Center (FRC) in Oak Ridge, TN. It was characterized as a bacterium tolerant to heavy metals such as uranium, nickel, cobalt, cadmium, as well as nitrate and low pH. We present its draft genome sequence.

  2. Method for immobilizing mixed waste chloride salts containing radionuclides and other hazardous wastes

    DOE Patents [OSTI]

    Lewis, Michele A. (Naperville, IL); Johnson, Terry R. (Wheaton, IL)

    1993-01-01

    The invention is a method for the encapsulation of soluble radioactive waste chloride salts containing radionuclides such as strontium, cesium and hazardous wastes such as barium so that they may be permanently stored without future threat to the environment. The process consists of contacting the salts containing the radionuclides and hazardous wastes with certain zeolites which have been found to ion exchange with the radionuclides and to occlude the chloride salts so that the resulting product is leach resistant.

  3. Method for immobilizing mixed waste chloride salts containing radionuclides and other hazardous wastes

    DOE Patents [OSTI]

    Lewis, Michele A.; Johnson, Terry R.

    1993-09-07

    The invention is a method for the encapsulation of soluble radioactive waste chloride salts containing radionuclides such as strontium, cesium and hazardous wastes such as barium so that they may be permanently stored without future threat to the environment. The process consists of contacting the salts containing the radionuclides and hazardous wastes with certain zeolites which have been found to ion exchange with the radionuclides and to occlude the chloride salts so that the resulting product is leach resistant.

  4. Biochemical solubilization of toxic salts from residual geothermal brines and waste waters

    DOE Patents [OSTI]

    Premuzic, E.T.; Lin, M.S.

    1994-11-22

    A method of solubilizing metal salts such as metal sulfides in a geothermal sludge using mutant Thiobacilli selected for their ability to metabolize metal salts at high temperature is disclosed. The method includes the introduction of mutated Thiobacillus ferrooxidans and Thiobacillus thiooxidans to a geothermal sludge or brine. The microorganisms catalyze the solubilization of metal salts. For instance, in the case of metal sulfides, the microorganisms catalyze the solubilization to form soluble metal sulfates. 54 figs.

  5. Biochemical solubilization of toxic salts from residual geothermal brines and waste waters

    DOE Patents [OSTI]

    Premuzic, Eugene T. (East Moriches, NY); Lin, Mow S. (Rocky Point, NY)

    1994-11-22

    A method of solubilizing metal salts such as metal sulfides in a geothermal sludge using mutant Thiobacilli selected for their ability to metabolize metal salts at high temperature is disclosed, The method includes the introduction of mutated Thiobacillus ferrooxidans and Thiobacillus thiooxidans to a geothermal sludge or brine. The microorganisms catalyze the solubilization of metal salts, For instance, in the case of metal sulfides, the microorganisms catalyze the solubilization to form soluble metal sulfates.

  6. Advanced Thermal Storage System with Novel Molten Salt: December 8, 2011 - April 30, 2013

    SciTech Connect (OSTI)

    Jonemann, M.

    2013-05-01

    Final technical progress report of Halotechnics Subcontract No. NEU-2-11979-01. Halotechnics has demonstrated an advanced thermal energy storage system with a novel molten salt operating at 700 degrees C. The molten salt and storage system will enable the use of advanced power cycles such as supercritical steam and supercritical carbon dioxide in next generation CSP plants. The salt consists of low cost, earth abundant materials.

  7. Effect of hydrotropic salts on phase relationships involving hydrocarbons, water, and alcohols

    SciTech Connect (OSTI)

    Ho, P.C.; Kraus, K.A.

    1980-01-01

    Hydrotropic salts, which can increase the solubility of organic materials in aqueous solutions, are useful to tertiary oil recovery. We have examined effects on solubility of hydrocarbons in water (with and without alcohols) through addition of inorganic hydrotropic salts, such as perchlorates, thiocyanates, and iodides - high in the usual Hofmeister series - and of organic salts such as short chain alkyl benzene sulfonates and other salts based on substituted benzene derivatives. Although the inorganic salts are relatively ineffective in increasing solubility of hydrocarbons in water, many of the organic salts are excellent hydrotropic agents for hydrocarbons. We have examined the phase relationships for several series of aromatic salts such as sulfonates, carboxylates and hydroxycarboxylates, as a function of alkyl-carbon substitution in three-component (hydrocarbon, salt, water) and in four-component (hydrocarbon, salt, alcohol, water) systems. We have also examined miscibility relationships for a given hydrotropic salt as the chain length of alkanes and alkyl benzenes is systematically varied. While miscibilities decrease with increase in chain length of the hydrocarbon, the hydrotropic properties in these systems increase rapidly with the number of alkyl carbons on the benzene ring of the salts and they are relatively insensitive to the type of charged group (sulfonate vs carboxylate) attached to the benzene ring. However, there were significant increases in hydrotropy as one goes from equally substituted sulfonates or carboxylates to salicylates. A number of salts have been identified which have much greater hydrotropic properties for hydrocarbons than such well-known hydrotropic materials as toluene and xylene sulfonates.

  8. Corrosion in Very High-Temperature Molten Salt for Next Generation CSP

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Systems | Department of Energy Corrosion in Very High-Temperature Molten Salt for Next Generation CSP Systems Corrosion in Very High-Temperature Molten Salt for Next Generation CSP Systems This presentation was delivered at the SunShot Concentrating Solar Power (CSP) Program Review 2013, held April 23-25, 2013 near Phoenix, Arizona. PDF icon csp_review_meeting_042413_garciadiaz.pdf More Documents & Publications Fundamental Corrosion Studies in High-Temperature Molten Salt Systems for

  9. Development of Molten-Salt Heat Trasfer Fluid Technology for Parabolic

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Trough Solar Power Plants | Department of Energy Development of Molten-Salt Heat Trasfer Fluid Technology for Parabolic Trough Solar Power Plants Development of Molten-Salt Heat Trasfer Fluid Technology for Parabolic Trough Solar Power Plants "This PowerPoint presentation was originally given by Dylan Grogan, principal investigator at Abengoa Solar, during a SunShot Initiative Concentrating Solar Power program review on April 24, 2013. The project, Development of Molten-Salt Heat

  10. Maintaining molten salt electrolyte concentration in aluminum-producing electrolytic cell

    DOE Patents [OSTI]

    Barnett, Robert J.; Mezner, Michael B.; Bradford, Donald R

    2005-01-04

    A method of maintaining molten salt concentration in a low temperature electrolytic cell used for production of aluminum from alumina dissolved in a molten salt electrolyte contained in a cell free of frozen crust wherein volatile material is vented from the cell and contacted and captured on alumina being added to the cell. The captured volatile material is returned with alumina to cell to maintain the concentration of the molten salt.

  11. Basis for Section 3116 Determination for Salt Waste Disposal at the

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Savannah River Site | Department of Energy Basis for Section 3116 Determination for Salt Waste Disposal at the Savannah River Site Basis for Section 3116 Determination for Salt Waste Disposal at the Savannah River Site The Secretary of Energy is making this 3116 Determination pursuant to Section 3116 of the Ronald W. Reagan National Defense Authorization Act for Fiscal Year 2005 (NDAA) [1]. This 3116 Determination concerns the disposal of separated, solidified low-activity radioactive salt

  12. Salt Waste Disposal at the Savannah River Site | Department of Energy

    Energy Savers [EERE]

    Salt Waste Disposal at the Savannah River Site Salt Waste Disposal at the Savannah River Site Section 3116 of the Ronald W. Reagan National Defense Authorization Act for Fiscal Year 2005 authorizes the Secretary of Energy, in consultation with the Nuclear Regulatory Commission, to reclassify certain waste from reprocessing spent nuclear fuel from high-level waste to low-level waste if it meets the criteria set forth in Section 3116. Currently, DOE SRS has prepared one final (salt waste) and is

  13. DOE - Office of Legacy Management -- Salt Lake City Vitro Chemical - UT

    Office of Legacy Management (LM)

    0-04 Vitro Chemical - UT 0-04 FUSRAP Considered Sites Site: Salt Lake City Vitro Chemical (UT.0-04 ) Designated Name: Alternate Name: Location: Evaluation Year: Site Operations: Site Disposition: Radioactive Materials Handled: Primary Radioactive Materials Handled: Radiological Survey(s): Site Status: Also see Salt Lake City, Utah, Processing Site Documents Related to Salt Lake City Vitro Chemical 2014 Annual Site Inspection and Monitoring Report for Uranium Mill Tailings Radiation Control

  14. Holy Name Central Catholic School Wind Turbine | Open Energy...

    Open Energy Info (EERE)

    Name Central Catholic School Wind Turbine Jump to: navigation, search Name Holy Name Central Catholic School Wind Turbine Facility Holy Name Central Catholic School Wind Turbine...

  15. Building America Webinar: Central Multifamily Water Heating Systems...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Multifamily Central Heat Pump Water Heating Building America Webinar: Central Multifamily Water Heating Systems - Multifamily Central Heat Pump Water Heating This presentation will ...

  16. Sustainable Energy Fund of Central Eastern Pennsylvania | Open...

    Open Energy Info (EERE)

    of Central Eastern Pennsylvania Jump to: navigation, search Logo: Sustainable Energy Fund of Central Eastern Pennsylvania Name: Sustainable Energy Fund of Central Eastern...

  17. Central Nevada Seismic Zone Geothermal Region | Open Energy Informatio...

    Open Energy Info (EERE)

    Central Nevada Seismic Zone Geothermal Region (Redirected from Central Nevada Seismic Zone) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Central Nevada Seismic Zone...

  18. Proceedings of 3rd US/German Workshop on Salt Repository Research, Design, and Operation

    Broader source: Energy.gov [DOE]

    The report provides summary and materials from the third U.S./German Workshop on Salt Repository Research, Design and Operation (held in New Mexico, October 2012).

  19. US/German Workshop on Salt Repository Research, Design and Operation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    following information: We have obtained the necessary DOE and Sandia approvals to start planning the 7 th USGerman Workshop on Salt Repository Research, Design, and Operation to...

  20. Ground Gravity Survey At Salt Wells Area (Bureau of Land Management...

    Open Energy Info (EERE)

    2009) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Ground Gravity Survey At Salt Wells Area (Bureau of Land Management, 2009) Exploration...

  1. Water Sampling At Salt Wells Area (Henkle, Et Al., 2005) | Open...

    Open Energy Info (EERE)

    Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Water Sampling At Salt Wells Area (Henkle, Et Al., 2005) Exploration Activity Details...

  2. Single-Well and Cross-Well Seismic At Salt Wells Area (Bureau...

    Open Energy Info (EERE)

    Seismic At Salt Wells Area (Bureau of Land Management, 2009) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Single-Well and Cross-Well Seismic...

  3. Process for improving the energy density of feedstocks using formate salts

    DOE Patents [OSTI]

    Wheeler, Marshall Clayton; van Heiningen, Adriaan R.P.; Case, Paige A.

    2015-09-01

    Methods of forming liquid hydrocarbons through thermal deoxygenation of cellulosic compounds are disclosed. Aspects cover methods including the steps of mixing a levulinic acid salt-containing feedstock with a formic acid salt, exposing the mixture to a high temperature condition to form hydrocarbon vapor, and condensing the hydrocarbon vapor to form liquid hydrocarbons, where both the formic acid salt and the levulinic acid salt-containing feedstock decompose at the high temperature condition and wherein one or more of the mixing, exposing, and condensing steps is carried out a pressure between about vacuum and about 10 bar.

  4. 2-M Probe At Columbus Salt Marsh Area (Kratt, Et Al., 2010) ...

    Open Energy Info (EERE)

    Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: 2-M Probe At Columbus Salt Marsh Area (Kratt, Et Al., 2010) Exploration Activity Details...

  5. Method of removal of heavy metal from molten salt in IFR fuel pyroprocessing

    DOE Patents [OSTI]

    Gay, Eddie C. (Park Forest, IL)

    1995-01-01

    An electrochemical method of separating heavy metal values from a radioactive molten salt including Li halide at temperatures of about 500.degree. C. The method comprises positioning a solid Li--Cd alloy anode in the molten salt containing the heavy metal values, positioning a Cd-containing cathode or a solid cathode positioned above a catch crucible in the molten salt to recover the heavy metal values, establishing a voltage drop between the anode and the cathode to deposit material at the cathode to reduce the concentration of heavy metals in the salt, and controlling the deposition rate at the cathode by controlling the current between the anode and cathode.

  6. Hazard evaluation for cutting tank 241-A-101 salt well casing

    SciTech Connect (OSTI)

    Board, B.D.

    1997-01-10

    This document identifies the hazards of using an abrasive water jet to add perforations to the salt well screen in tank 241-A-101.

  7. Radiolytic gas generation in salt cake technical task plan

    SciTech Connect (OSTI)

    Walker, D.D.; Crawford, C.L.; Bibler, N.E.

    1993-08-29

    High-level radioactive wastes are stored in large, steel tanks in the Savannah River Site Tank Farms. The liquid levels in these tanks are monitored to detect leakage of waste out of tanks or leakage of liquids into the tanks. Recent unexplained level fluctuations in high-level waste (HLW) tanks have caused High Level Waste Engineering (HLWE) to develop a program to better understand tank level behavior. Interim Waste Technology (IWT) has been requested by HLWE to obtain data which will lead to a better understanding of the radiolytic generations of gases in salt cake. The task described below will provide data from laboratory experiments with simulated wastes which can be used in tank level fluctuation modeling. The following experimental programs have been formulated to meet the task requirements of the customer: (A) determine whether radiolytically generated gas bubbles can be trapped in salt cake; (B) determine the composition of gases produced by radiolysis; (C) determine the yield of radiolysis gases as a function of radiation dose; (D) determine bubble distribution.

  8. Salt Repository Project shaft design guide: Revision 0

    SciTech Connect (OSTI)

    Not Available

    1987-12-01

    The Salt Repository Project (SRP) Shaft Design Guide (SDG) and the accompanying SRP Input to Seismic Design define the basic approach for developing appropriate shaft designs for a high-level nuclear waste repository in salt at a proposed site in Deaf Smith County, Texas. The SDG is based on current mining industry standards and practices enhanced to meet the special needs of an underground nuclear waste repository. It provides a common approach for design of both the exploratory and repository shafts. The SDG defines shaft lining and material concepts and presents methods for calculating the loads and displacements that will be imposed on lining structures. It also presents the methodology and formulae for sizing lining components. The SDG directs the shaft designer to sources of geoscience and seismic design data for the Deaf Smith County, Texas repository site. In addition, the SDG describes methods for confirming shaft lining design by means of computer analysis, and it discusses performance monitoring needs that must be considered in the design. 113 refs., 18 figs., 14 tabs.

  9. EIA - Natural Gas Pipeline System - Central Region

    Gasoline and Diesel Fuel Update (EIA)

    Central Region About U.S. Natural Gas Pipelines - Transporting Natural Gas based on data through 2007/2008 with selected updates Natural Gas Pipelines in the Central Region Overview | Domestic Gas | Exports | Regional Pipeline Companies & Links Overview Twenty-two interstate and at least thirteen intrastate natural gas pipeline companies (see Table below) operate in the Central Region (Colorado, Iowa, Kansas, Missouri, Montana, Nebraska, North Dakota, South Dakota, Utah, and Wyoming). Twelve

  10. DOE - Office of Legacy Management -- Central

    Office of Legacy Management (LM)

    Nevada Central Nevada Test Area (CNTA), Nevada, Site A Nevada Offsite centralmap The DOE Office of Legacy Management assumed responsibility for long-term surveillance and maintenance at the Central Nevada Test Area (CNTA) Site in 2008. The CNTA site requires routine inspection and maintenance, records-related activities, and stakeholder support. For more information about the CNTA site, view the fact sheet. Site Documents and Links Contact Us Central Nevada Test Area (CNTA) Site Mapping and

  11. Central Activator Keeps the Circadian Clock Ticking

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    utilizes an operational logic involving a central negative feedback loop that turns genes on and off rhythmically with a period of roughly 24 hours. The positive component of...

  12. Central Characterization Program (CCP), Acceptable Knowledge...

    Office of Environmental Management (EM)

    , Acceptable Knowledge Summary Report for Los Alamos National Laboratory, TA-55 Mixed Transuranic Waste Streams Central Characterization Program (CCP), Acceptable Knowledge Summary...

  13. Central Characterization Program (CCP) Acceptable Knowledge Documentat...

    Office of Environmental Management (EM)

    Acceptable Knowledge Documentation Central Characterization Program (CCP) Acceptable Knowledge Documentation This document was used to determine facts and conditions during the...

  14. Central Electronics Limited CEL | Open Energy Information

    Open Energy Info (EERE)

    Electronics Limited CEL Jump to: navigation, search Name: Central Electronics Limited (CEL) Place: Sahibabad, Uttar Pradesh, India Zip: 201010 Sector: Solar Product: String...

  15. Central Indiana Ethanol LLC | Open Energy Information

    Open Energy Info (EERE)

    Indiana Ethanol LLC Jump to: navigation, search Name: Central Indiana Ethanol LLC Place: Marion, Indiana Zip: 46952 Product: Ethanol producer developina a 151 mlpa plant in Marion,...

  16. Central Characterization Program (CCP) Transuranic Authorized...

    Office of Environmental Management (EM)

    Authorized Methods for Payload Control Central Characterization Program (CCP) Transuranic Authorized Methods for Payload Control This document was used to determine facts and...

  17. Central Wisconsin Elec Coop | Open Energy Information

    Open Energy Info (EERE)

    https:www.facebook.compagesCentral-Wisconsin-Electric-Cooperative268841143249085?refaymthomepagepanel Outage Hotline: 800-377-2932 References: EIA Form EIA-861 Final...

  18. East Central Electric Cooperative- Residential Rebate Program

    Broader source: Energy.gov [DOE]

    East Central Electric Cooperative offers rebates to residential customers to install energy-efficient ground source heat pumps, electric water heaters, and air conditioners. To qualify for the...

  19. Central Lincoln People's Utility District - Residential Energy...

    Broader source: Energy.gov (indexed) [DOE]

    electric Program Info Sector Name Utility Administrator Central Lincoln People(tm)s Utility District Website http:clpud.orgrebate-information State Oregon Program Type...

  20. Central Characterization Program (CCP) Transuranic Waste Characterizat...

    Office of Environmental Management (EM)

    Characterization Quality Assurance Project Plan Central Characterization Program (CCP) Transuranic Waste Characterization Quality Assurance Project Plan This document was used to...